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HomeMy WebLinkAboutNCD981927502_20031001_Geigy Chemical Corporation_FRBCERCLA FYR_Five-Year Review Report-OCRRegion 4 • £-1/f' ~vt'e.1J FIVE YEAR REVIEW FACT SHEET GEIGY CHEMICAL CORP. SITE • Aberdeen, Moore County, North Carolina October 2003 Where is the Geigy Chemical Site located? The Geigy Chemical Corporation Site is located just cast of the corporate limits of Aberdeen, North Carolina in southeastern Moore County. The one acre Site is bounded on the no11h by State Highway 211 and on the east by Domino Drive. The Aberdeen & Rockfish Railroad cuts through the Site where the former pesticide blending/mixing/bagging buildings stood. The property forms an elongated triangle with the highway and railroad forming the apex .. Site Background The Site operated as a pesticide blending and formula,ion facility by various operatoi·s from approximately I 947 to 1967, and by retail distributors of agricultural chemicals from 1967 until 1989. The pesticides DDT, toxaphene, and BHC were received in bulk at the Site, blended with clay and other ine11 matc1ials, repackaged, and sold. Pesticides were not manufactured at the Site but were formulated by dry mixing into a product suitable for local consumer use. EPA conducted an initial site investigation in March 1987. The Site was proposed for listing on the National Priorities List (NPL) in June 1988, and was officially placed on the NPL as of October 4, 1989. The Rccoid of Decision was issued in 1992 selecting u pump~and-trcatment system to remove pesticide contaminants from groundwater, and the contaminated soil was excavated and structures and their foundations were tom down and taken to an approved landfill. The previous owners took action to removed approximately 3,300 tons of contaminated soil and debris, and EPA removed approximately 6,935 tons of soil and debris. The contaminants of concern are; aldrin, BHC isomers, dieldrin, endrin, toxaphene, DDD, DDE, DDT and chlordane isomers. The · Site was covered with clean soil ,ind revegetated with native grass, plants and trees. The soil clean up actions were completed as of February 1997. The groundwater treatment system began operating in January 1997 and has currently treated approximately 30 million gallons of extracted groundwater from both the surficial and Upper Black Creek aquifers. Monitoring and sampling of groundwater has continued in order to characterize the migration pattern of the water in the Upper and Lower Black Creek aquifers. What is the purpose of a Five-year Review? The purpose of the review is to determine whether the remedy selected at a site is or remains protective of human health and the environment, identify issues/problems and recommend corrective action, if necessary. Why and when should a Five-year Review be conducted? As required by the Superfund law, when a remedial action is selected that results in hazardous substances, pollutants, or contaminants remaining at the site above levels that allow for unlimited use and unrestricted exposure, the lead agency shall review such action no less often than every five years after the initiation of the selected remedial action. [40 CFR §300.430(f)(4)(ii)] • • Since a groundwater treatment system was installed to treat contaminates in· groundwater, a five year review is required because contaminants are still being detected in the groundwater at the Site. The next five-year review should occur by September 2008. These five-year reviews will continue until the levels of contaminants drop to concentrations that allow unlimited use. Who conducts the review at a.fund-financed or enforce/llent lead site? EPA has the responsibility of either conducting the review or hiring a contractor or other agencies (i.e., U.S. Army Corps of Engineers) to perfotm studies, condµct investigations, and/or develop draft Five-Year Review reports. The U.S. Anny Corps of Engineers out of Wilmington, NC conducted the review for this Site between January 2003 through September 2003. The final report was completed, approved and signed in September 2003. The Corps was used to provide an unbiased assessment of the Site. In general, how was the assess/Ile/It of the protectiveness of the rellledy conducted? ► All relevant data, monitoring/sampling results of groundwater, Operation & Maintenance reports, Record of Decision, monthly discharge monitoring results, and other documents were reviewed. ► Since the clean up action of soil and debris was completed in 1997, based on a final inspection of the Site by EPA and the State of North Carolina Department of Environment and Natural Resources in I 998, the soil contaminant level goals established in the Record of Decision and Remedial Design have been met and no further soil remediation is required. ► Conducted a performance evaluation of the groundwater and treatment systems to detennine if the groundwater remedy is functioning as intended, if the exposure assumptions, toxicity data, clean up levels and remedial action objectives are still valid, and if other information has come to light that could question the protectiveness of the remedy. ► Prepared a written Five-Year Review document What did the assess/llent reveal about the rellledies? Based upon data from the past five years of operation, review of monitoring information, and general site conditions, the remedy implemented remains protective of human health and the environment because the on-going groundwater treatment clean up actions continue to remove contaminants of concern from the impacted areas. There have been no changes to the physical conditions of the Site or the adjacent land use that would affect the remedy. The review of documents, Applicable or Relevant & Approptiate Requirements (ARARs), risk assumptions, groundwater and monitoring well data, and the results of the Site inspection indicate, overall, that the groundwater remedy has functioned to this point as intended. No significant issues were noted during the five-year review of the remedial action components. _ What were the recommendations of the Five-Year Review? I. Fencing and signing of the Site as proposed in the documents of record have not been I J • • installed. Since the soil has already been cleaned up, this recommendation is no longer applicable. EPA should issue an ESD to eliminate this requirement. 2. The Site Groundwater Remediation Permit will expire in June 2004. Wording needs to be changed to renect that the treatment facility consists of seven recovery wells rather than five since the permit only covered five wells. 3. There is evidence that a plume of trichloroethene (TCE) from another source is starting to encroach into the Site treatment.area. This situation will continue to be monitored in order to recognize any impact from the TCE plume. How should the community be informed and involved? Activities should include notifying the public that the Five-Year Review will be conducted, contact citizens for their input, notify the public that the Review has been completed, and place a copy of the Review in the Site Information Repository. A display ad was placed in the local newspaper to notify the public that the Five-Year Review was being conducted. A number of citizens were interviewed by telephone during the review period. No one expressed any major concerns regarding the remedial action and its operations over the years at the Site. A copy of the completed questionnaires were placed in the back of the review document. A copy of the Five-Year Review was placed in the Information Repository located in the Aberdeen Town Hail, i 15 N. Poplar Street, Aberdeen, NC making it available to the public. This fact sheet was prepared summaiizing information in the 2003 Five-Year Review and mailed to people on the Site mailing list. A display ad was placed in the local newspaper to notify the public that a copy of the Fivc-Y car Review had been completed and is avai I able for reading in the r~pository. Have questions? If you have technical questions about the Five-Year Review document, please contact Jon Bornholm, EPA Remedial Project Manager at 1-800-435-9233, ext. 28820 or 404-542-8820. If you want copies of Site fact sheets or general Site information, please contact Diane Barrett, Community Involvement Coordinators at 1-800-435-9233, ext. 28489 or 404-562-8489. Want to read documents about the Site? Copies of all documents developed during the investigation and remediation of this Site have been placed in the Site Information Repository located in the: Aberdeen Town Hall 115 N. Poplar Street Aberdeen, NC 28315 (910) 944-1115 and the: EPA Record Center, 11th Floor 61 Forsyth Street, SW Atlanta, GA 30303 (404) 562-8946 • Site Mailing List If ymi want to change/conect/dclete your name from the Geigy Chemical Corp. Site mailing list, please complete the fonn below and return to Diane Barrett, Community Involvement Coordinator, USEPA, Waste Management Division, 61 Forsyth Strec.t, SW, 10th Floor, Atlanta, GA 30303. Name Address City, State, Zip Code Region 4 . Change □ U.S. Environmental Protection Agency 61 Forsyth Street, SW Atlanta, Georgia 30303-8960 Geigy Chemical Site Co1Tection □ Deletion □ 1-..i • Waste Management Division Diane Barrett, Community Involvement Cp · · Jon Bornholm, Site Remedial Project M HASCER $0.37 OCT 21 2003 US POSTAGE FIRST CLASS MAILED FROM 30303 011A0413CC1152 Official Business Penalty for Private Use $300 r 1r1~~J-~-[.~ . ~ ~ \VI ·ir·f::'\ j S/F .GEIG 13-~ r·---~ c;_;:__,i'.lc_ '· 71 n ! I RANDY MCELVEEN, PROJECT MANAGER llnl' ' [JJJ I 1 SUPER FUND SECTION, WASTE MGMT. DIV. i ! ! OCT 2 8 200 · j · ' NC DEPT OF ENVIRONMENT & NATURAi. RESOURCES u I . ' J ' 1601 MAIL SERVICE CENTER I --.-...C, RALEIGH NC 27699· 1601 ' ! __ S,UP~l3fUNn_ SECT1or,1 ----·---------1 • Five• Year Review Geigy Chemicc! Corp. (Aberdeen Plant), Aberdeen, NC Five-Year Review Report First Five-Year Review Report For Geigy Chemical Corp. (Aberdeen Plant) Aberdeen Moore County, North Carolina September 2003 Prepared By: US Army Corps of Engineers Wilmington District Wilmington, North Carolina Prepared For: Region 4 U.S. Environmental Protection Agency Atlanta, Georgia Sfp 3 0 . I / I ; • Five~Year Review Geigy Chemical Corp. (Aberdeen Plant), Aberdeen, NC Five-Year Review Report Table of Contents List of Acronyms .......................................................................................................................... iii Executive Summary ..................................................................................................................... iv Five-Year Review Summary Form ............................................................................................... i I. Introduction .............................................................................................................................. 1 II. Site Chronololgy ...................................................................................................................... 2 Ill. Background ............................................................................................................................ 2 A. Physical Characteristics .................................................................................................... 2 B. Land and Resource Use ..................................................................................................... 3 C. History of Contamination .................................................................................................. 4 D. Initial Response ................................................................................................................. 6 IV. Remedial Actions ................................................................................................................... 6 A. Remedy Selection ............................................................................................................. 6 B. Remedy Implementation ................................................................................................... 9 C. System Operations / O&M ................................................................................................ 9 V. Progress Since the Last Five-Year Review ......................................................................... 15 VI. Five-Year Review Process ................................................................................................... 15 VII. Five-Year Review Findings ............................................................................................... 15 A. Interviews ........................................................................................................................ 15 B. Site Inspection ................................................................................................................. 16 C. ARAR Review ................................................................................................................. 16 D. Changes in Exposure Pathways, Toxicity and Other Contaminant Characteristics ....... 17 E. Data Review .................................................................................................................... 17 VIII. Assessment ........................................................................................................................ 28 Question A: Is the remedy functioning as intended by the decision documents? ............... 28 Question B: Are the assumptions used at the time of the remedy selection still valid? ...... 28 Question C: Has any information come to light that could call into question the protectiveness of the remedy? ............................................................................................... 34 · IX. Issues ..................................................................................................................................... 35 X. Recommendations and Follow-up Actions ......................................................................... 35 1 • Five-Year Review Geigy Chemical Corp. (Aberdeen Plant), Aberdeen, NC XI. Protectiveness Statements ................................................................................................... 36 XII. Next Review ........................................................................................................ , ............... 36 List of Figures Figure 1. General Location ............................................................................................................................. 3 Figure 2. Specific Site Location ...................................................................................................................... 5 Figure 3. Flow Model of the Pump and Treat Sytem ............................................................................... 11 Figure 4. Monitoring Well and Sampling Locations ................................................................................. 12 Figure 5. Site Area Monitoring and Extraction Well Locations .............................................................. 13 Figure 6. Extraction System and Treatment Facility Diagram ................................................................ 14 List of Tables Table 1. Chronology of Events ...................................................................................................................... 2 Table 2. Soil Clean-up Standards ................................................................................................................... 7 Table 3. Groundwater Clean-up Standards .................................................................................................. 7 Table 4. Downgradient Groundwater Clean-up Standards ........................................................................ 8 Table 5. Surficial Aquifer BHC Isomer Concentrations in Groundwater Monitoring Wells 1990 - 2002 .......................................................................................................................................................... 19 Table 6. Upper Black Creek Aquifer Sampling Results 1998 to 2002, Exceedences of Performance Standards for BHC Isomers ................................................................................................................. 20 Table 7. Lower Black Creek .Aquifer Sampling Results 1998 to 2002, Exceedences of Performance Standards for BHC Isomers ......................... : ............... : ....................................................................... 20 Table 8. BHC-isomer Sampling Results for Surface Water Monitoring 1996 -2002 ......................... 22 Table 9. Trichloroethene (TCE) Concentrations in Groundwater Monitoring Wells 1991 to 2002.27 Table 10. Remedial Alternative Summary ...... : ............................................................................................ 30 Table 11. Recommendations and Follow-up Actions ............................................................................... 36 11 List of Acronyms • Five-Year Review Geigy Chemical Corp. (Aberdeen Pla11t), Aberdee11, NC AOC Administrative Order on Consent ARARs Applicable or Relevant and Appropriate Requirements BHC Benzene Hexachloride CENWO-HX-G Corps of Engineers Hazardous, Toxic and Radioactive Waste Center of CERCLA CERCLIS Expertise Comprehensive Environmental Response, Compensation, and Liability Act Comprehensive Environmental Response, Compensation, and Liability Information System CESA W-TS-PE Wilmington District, Corps of Engineers Environmental Resources CFR CRQL DOE DDT EPA FS HRS !AG Kg L Mg NCGWQS NCP NPL ppb ppm PRP RA RD RI ROD RPM SARA TCE TCL µg USACE WasteLAN Section Code of Federal Regulations Contract Required Quantitation Limit Dichlorodiphenyldichloroethylene Dichlorodiphenyltrichloroethane United States Environmental Protection Agency Feasibility Study Hazard Ranking System Interagency Agreement Kilogram Liter Milligram North Carolina Groundwater Quality Standards National Oil and Hazardous Substances Pollution Contingency Plan National Priorities List Parts Per Billion Parts Per Million Potentially Responsible Party Remedial Action Remedial Design Remedial Investigation Record of Decision Remedial Project Manager Superfund Amendments and Reauthorization Act of 1986 Trichloroethene Target Compound List Microgram United States Army Corps of Engineers The Regional database related to CERCLIS 111 • Five• Year Review Geigy Chemical Co,p. (Aberdeen Plant), Aberdeen, NC Executive Summary This report documents the first five-year policy review of the National Priorities List (NPL) site NCD981023260. The site, referred to as Geigy Chemical Corp. (Aberdeen Plant), is a former pesticide formulation and retail sales site located in Aberdeen, Moore County, North Carolina. The site is approximately one acre in size. Contaminants of concern originally associated with groundwater at the site are pesticides including aldrin, BHC isomers, dieldrin, endrin, toxaphene, and the solvent trichloroethene (ICE). Subsequent investigations showed that trichloroethene contamination was not a result of site activities and was therefore removed from the Site Target Contaminants List (TCL). There was also soil contamination involving the same pesticides listed for groundwater and the additional compounds, DDD, DOE, DDT, and chlordane isomers. These contaminants are the result of use of the site for pesticide formulation and blending and agricultural chemical sales from 1947 to 1989. In March 1988, an EPA Site Investigation.in support of the Hazard Ranking System (HRS) was conducted on the site. Isomers of BHC were found in groundwater samples from three municipal and two private wells. Based on the results of the site investigation, the site was proposed to the National Priorities List (NPL) in June 1988 and listing was finalized October 4, 1989. There were three removal actions associated with the site for soil remediation. The first two, conducted in 1989 and 1991, removed soils visibly contaminated and other debris from the site. Approximately 3,300 tons of soil and debris were removed for disposal in these two actions. Following the preparation and finalization of a Remedial Investigation/Feasibility Study, a Record of Decision (ROD) was signed August 27, 1992. The Remedial Action implemented by the ROD included demolition of the former warehouse foundation; excavation of the top foot of on-site soils contaminated above performance standards; off-site disposal of excavated soils as appropriate; extraction of groundwater from the surficial and Upper Black Creek aquifers; treatment of extracted groundwater via carbon adsorption; site restoration; and further sampling and analysis of the Upper Black Creek aquifer to determine extent of pesticide contamination and determine ifTCE found in two wells was site-related. The Remedial Action (RA) was implemented from September 1996 to February 1997. The RA included removal of concrete foundations and other debris totaling approximately 2,460 tons to a Subtitle D landfill; disposal of 4,475 tons of contaminated soils to a Subtitle C landfill; construction and installation of extraction wells and groundwater treatment facilities with an infiltration gallery for discharge of treated groundwater. The treatment system began operation in January 1997 and has currently treated approximately 30 million gallons of extracted groundwater from the surficial and_ Upper Black Creek aquifers. As required in the ROD, a downgradient investigation was conducted to determine the extent of pesticide plumes in the Upper and Lower Black Creek aquifers. The results of the investigation, reported in the Downgradient Groundwater Remedial Action Work Plan (RA WP), and the recommendations therein, were adopted by EPA through the issuance of the January 1998 Explanation of Significant Difference (ESD). The ESD established that the downgradient groundwater contaminant plume would be monitored as part of the overall site remedy. The • Five-Year Review Geig;; Chemical Corp. (Aberdeen Plant), Aberdeen, NC selected remedy for the downgradient area is monitored natural attenuation of the plume with the following contaminant concentration goals: alpha-, beta-, and delta-BHC 0.05 µg/L (micrograms per liter), and gamma-BHC 0.20 µg/L. There were several issues identified during the review process. None of the issues affect the assessment of the performance of the remedy. However, each should be addressed before the next five-year review. The issues are described as follows: 1. Fencing and signing of the site as proposed in the documents of record have not been accomplished. This proposal was prepared prior to completion of the soil remediation and may no longer be applicable. 2. The Site Groundwater Remediation Permit issued October I, 1999 and expiring June 30, 2004, needs to be changed to reflect that the treatment facilities consist of seven (7) recovery wells rather than the five ( 5) listed. 3. Evidence indicates encroachment of the off-site trichloroethene (TCE) contaminant plume into the site treatment area. Increasing TCE levels have shortened the life of carbon adsorption canisters in the treatment facility, however, the long-term effects of this change on the remedy are unknown. The remedial actions at the Geigy Chemical Corp. (Aberdeen Plant) site currently protect human health and the environment. The soil remediation for the site has been completed, and the pump-and-treat remediation of the groundwater contamination including monitoring is continuing. The trends of contaminant concentrations in groundwater both at the site and in the downgradient area appear to be downward. Performance standards for contaminants of concern are exceeded in the monitoring wells for the area under remedy implementation. To ensure long- term protectiveness of the selected site remedy, continued monitoring and operation of the groundwater treatment facility should continue. V • • Five-Year Review Gei!J Chemical Co,p. (Aberdeen Plant), Aberdeen, NC Five-Year Review Summary Form Five-Year Review Summary Form Site Identification Site Name: Gei0 " Chemical Com. (Aberdeen Plant) EPA ID: NCD98l927502 Reoion: 4 I State: NC I CitylCountv: Aberdeen/Moore ~~;;,i-Jr,;ii~~i.(~;~~tt.t1:J~&t!ri'Jvtlllii¥'raii121:1!YJ~~~~~SITEiST--A/f.US:L~~~fr,t:r~:iff:1xITt1~t~~J~~}~ff?¥J•:~g,?j~~~~~ NPL status: ✓ Final D Deleted n Other: Remediation Status: D Under Construction D Operating D Comnlete Multiole OUs?• D YES ✓ NO I Construction Completion Date: Seotember 27, 2000 Has site been put into reuse? D YES ✓ NO ~:!\~~~-~~\r2~$W~~~:&~J~~t~IRE~EW.'SY.A :nJS~~}~~f~~ .. \~?.:';!f:t@W~J-;i~fD~fl~\~~J.f~ Reviewinl! al!encv: ✓ EPA 0 State D Other: Author name: Stacv Samuelson . Author title: Biologist I Author affiliation: USACE, Wilmin~ton Di<liict Review oeriod:** 1103 -9/03 Datelsl of site inspection: Februarv 17, 2003 Type of review:*** 0 Statutory ✓ Policv Review number: ✓ l (first) 0 2 (second) D 3 (third) D Other ( snecifvl Triggering action:**** ✓ Other (soecifv) Prelimin·-Close-Out Renort Trinnerine action date: Julv 20, 1998 Due date (five vears after triooering action date): Julv 20, 2003 Five-Year Review Summary Form Issues: I. Fencing and signage for the site as proposed_ in the documents of record have not been implemented. 2. Site Groundwater Remediation Permit needs to be modified to reflect actual number of wells associated with the treatment facility. 3. Encroachment of the off-site trichloroethene (TCE) contaminant olume into the site treatment area. Recommendations and Follow-up Actions: 1. The need for fencing and signage of the site was negated by re~oval of the contaminated soils during the remedial action. No action should be taken. 2. The PRPs should update the Site Groundwater Remediation Permit when renewed in 2004. 3. Monitoring of the affect(s) of the TCE plume on the site remedy should continue, with close coordination bv all oarties. Protectiveness Statement(s): The remedy at the Geigy Chemical Corp. (Aberdeen Plant) Site is expected to be or is protective of human health and the environment, and in the interim, exposure pathways that could result in unacceptable risks are being controlled. The next Five-Year Review should be scheduled five years from the date of this Review, in "MONTH" 2008. Other Comments: None. • "OU" refers to operable unit. •• Review period should correspond to the actual start and end dates of the five•year review in WasteLAN. "' See Chapter I, Section 1.2 of EPA 540-R-01-007, Final June 2001 for further explanation. "" See Chapter I, Section 1.3 ofEPA 540-R-01-007, Final June 2001 for further explanation. Approved By: (i inston A. Smith ' 1'Director, Waste Management Division U.S. EPA Region 4 0 I. INTRODUCTION • Five-Year Review Geigy Chemical Corp. (Aberdeen Plant), Aberdeen, NC FIVE-YEAR REVIEW REPORT The United States Environmental Protection Agency (EPA) Region 4 has completed a five-year review of remedial actions implemented at the Geigy Chemical Corp. (Aberdeen Plant) site in Aberdeen, Moore County, North Carolina. The United States Army Corps of Engineers (USACE) conducted and provided technical assistance and analysis for the five-year review. The Environmental Resources Section, Planning and Environmental Branch, Technical Services Division of the Wilmington District, Wilmington, North Carolina provided the USACE lead for this review. The review was accomplished under EPA Work Authorization Form for Interagency Agreement (!AG) Number DW96945884A. The Wilmington District was supported in the conduct of the review by the USACE Hazardous, Toxic and Radioactive Waste Center of Expertise (CENWO-HX-G) located at the Omaha District, Nebraska. This review was conducted from January 2003 through September 2003. The report documents the results of that review. The purpose of five-year reviews is to determine whether the remedy at a site is or is e)(pected to be protective of human health and the environment. The methods, findings, and conclusions of reviews are documented in five-year review reports. In addition, five-year review reports identify issues found during the review, if any, and recommendations to address them. This review is a policy review. EPA must implement five-year reviews consistent with the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) and the National Oil and Hazardous Substance Contingency Plan (NCP). CERCLA § 12l(c), as amended states: If the President selects a remedial action that results in any hazardous substances, pollutants, or contaminants remaining at the site, the President shall review such remedial action no less often that each five years after the initiation of such remedial action to assure that human health and the environment are being protected by the remedial action being implemented. The NCP part 300.430(f)(4)(ii) of the Code of Federal Regulations (CFR) states: If a remedial action is selected that results in hazardous substances, pollutants, or contaminants remaining at the site above levels that allow for unlimited use and unrestricted exposure, the lead agency shall review such action no less often than every five years after the initiation of the selected remedial action. Although not required by statute, this review is being conducted in accordance with EPA policy. EPA conducts five-year reviews as a matter of policy at:(!) sites where no hazardous substances will remain above levels that allow unlimited use and unrestricted exposure after completion of remedial actions, but the cleanup levels specified in the Record of Decision (ROD) will require five or more years to attain; (2) sites addressed before Superfund Amendments and Reauthorization Act (SARA) at which the remedy,upon attainment of cleanup levels, does/will not allow unlimited use and unrestricted exposure; and (3) removal-only sites where hazardous substances remain onsite at levels that will not allow unlimited use and • Five-Year Review Geigy Chemical Corp. (Aberdeen Plant), Aberdeen, NC unrestricted exposure. This site has been reviewed because cleanup levels will require more than five years to attain. This is the first five-year review of the Geigy Chemical Corp. (Aberdeen Plant) site. The Site has been identified as requiring a "policy" five-year review, which must occur within 5 years after completion of construction. Completion of construction, as designated by signature of the Preliminary Close-Out Report occurred on July 20, 1998. This review will be placed in the EPA site files and local repository for the Geigy Chemical Corp. (Aberdeen Plant) site. The local repository is located at the Aberdeen Town Hall, 115 N. Poplar St., Aberdeen, NC 28315. II. SITE CHRONOLOGY Table 1 lists the chronology for selected events for the Geigy Chemical Corp. (Aberdeen Plant) site, as shown below. Table 1: Chronology of Events .~-~t§li: !i.t'.il,'llil{l,i\'t,;:f "1:,:J;iiii!,~;~:;.-: 1 $'.,:,•f-i:(( 11.:tr~~~t]'.;J< 11 EVE NTt~~~Lrt.,;11tf;~~l¼,'ttj1.\iA~_~1l ;r~~£';:,iii~1(iif.'~~ ·:~l1'.'. ~l-l.i.'./ ~Jlltf~;;~ DA TE.'"• ~Ti~V:)1~ Site leased bv several comoanies for oesticide formulation and retail sales. 1947 to 1989 EPA detected pesticides in surface and subsurface soils on the site. Januarv 1987 Site insncction conducted by the State. March 1987 Preliminarv site assessment. June 1987 Hazard Ranking System (HRS) evaluation. August 1987 Site oronoscd to be listed on the National Priorities List (NPL ). June 1988 Site added to National Priorities List (NPL). October 4, 1989 PRPs conducted a soil removal action. 462 tons of soil and debris removed. February 23, 1989 to December I 6, I 989 Administrative Order on Consent issued. January 23, 1991 Second soil removal action by PRPs. 2,841 tons of soil and debris removed. February 25, 1991 lo June I, 1991 Human Health Risk Assessment and Ecological Risk Assessment completed. March 13, 1992 PRP preparation of Remedial Investigation and Feasibility Study (RI/FS). December I 6, 1988 to August 27. 1992 Record of Decision (ROD) signed. August 27, 1992 Consent Decree for PRPs to conduct remedial desi1m/remedial action (RD/RA) July I 5, 1993 RA contract for construction of groundwater remediation system and removal of contaminated soil September I 996 and debris awarded bv PRPs. Pre-final inspection of soil remediation by EPA and State of North Carolina. January 15, 1997 Groundwater Remediation Svstem ooerational. January I 997 Final inspection of soil remediation by EPA and State of North Carolina. Februarv 26, 1997 Downgradient Groundwater Remedial Action Work Plan aonroved by EPA and NC DENR. November 1997 Exolanation of Significant DifTerences issued bv EPA. Januarv 1998 Preliminary Close-Out Report Julv 20, I 998 Additional monitoring well installation. Aoril 1998 Site insoection for the first five-vear review. February 18, 2003 III. BACKGROUND A. Physical Characteristics The Geigy Chemical Corp. (Aberdeen Plant) Site is located just to the east of the corporate limits of Aberdeen, North Carolina in southeastern Moore County (Figure 1 ). The Site 2 • ·Five-Year iVview Geigy Chemical Corp, (Aberdeen Plant), Aberdeen, NC is located on the Aberdeen and Rockfish Railroad right-of-way adjacent to Highway 211 and forms an elongated triangle with the highway and railroad forming the apex. The Geigy Site encompasses an area of approximately one acre that has been graded to be mostly level in nature (Figure 2). The site has topography typical of the Upper Coastal Plain physiographic region, with shallow water tables and low topographic relief. Soils in the area are classified as the Candor sand type that overlays unconsolidated sandy to clayey sediments. There are also an intermittent clay zone and several other clay lenses that divide the surficial groundwater aquifer from the Upper and Lower Black Creek aquifers in the area. Drainage from the site and predominant groundwater flow is to the west and northwest with both surface and subsurface runoff entering McFarlands Branch, Ray's Mill Creek, and Aberdeen Creek. B. Land and Resource Use Current land use of the area is rural residential and commercial in nature. The city of Aberdeen has approximately 3,400 residents. The Moore County area has grown approximately 18% in the last ten years and may continue to do so. Based on current levels of development of the area, it is not foreseen that there will be any major change in land-use in the future.· Figure 1. General Location N '· 3 • C. History of Contamination • Five-Year Review Geigy Chemical Co,p. (Aberdeen Plant), Aberdeen, NC The Geigy Site was leased for the formulation and retail sale of pesticides from 194 7 until its closure in 1989. Agricultural fertilizers in bulk and bagged form were also distributed from the site during its operational history. The pesticides DDT, toxaphene, and BHC were formulated for field use on-site by mixing with inert materials such as clay and repackaged for sale in the local agricultural market. An EPA Site Investigation was conducted in March 1988 in support of the Hazard Ranking System (HRS) evaluation of the site. Isomers of BHC were found in groundwater samples from five locations: three municipal wells and two private wells. 4 Figure 2. Specific Site Location l ABERDEEN POP. 3,578 I ) • i i i • J.tcFarlaltd'.~ Brondt .'\'5 1IJ 'i;' "'. ; 2072';_ 2073 / Sandhill~ . ...-(' of ChrTst " ? "" Five-Year &view Geigy Chemical_Co,p. (Aberdeen Plant), Aberdeen, NC -2074 ? -- --L 7 \ r--I --\ \ ,_ \_ SolJthem Pines City Limit I\.----Aberdeen City Limit I I <6> ~-t, Mt. Ledmon Holy C~ist <\. -- Geigy Chemical Corp. (Aberdeen Plant) Site N o ____ o_.1s -o,;3 Miles W+ E -..., ~ I / Basema Source: NCDOT Division of Hi hwa s-GIS Unit S 5 • • D. Initial Response • Five-Year Review Geigy Chemical Corp. (Aberdeen Plant), Aberdeen, NC As discussed briefly in Section C above, the Environmental Protection Agency (EPA) conducted a Site Investigation of the site in March 1988 in support ofa Hazard Ranking System (HRS) evaluation. The site was proposed to be included on the National Priorities List (NPL) in June 1988 and final designation was completed October 4, 1989. During that time, notice letters were sent to six companies: Ciba-Geigy Corp, Olin Corp, Kaiser Aluminum & Chemical Corp, Lebanon Chemical Corp, Aberdeen and Rockfish Railroad, and Columbia Nitrogen Corporation. The notice letters requested that the Potentially Responsible Parties (PRPs) conduct a Remedial Investigation and Feasibility Study (RJ/FS) for the site. An Administrative Order on Consent (AOC) was entered into by EPA and three of the PRPs (Ciba Geigy {currently Syngenta Crop Protection, Inc.}, Olin Corp, and Kaiser) for performance of the RI/FS on December 16, 1988. IV. REMEDIAL ACTIONS A. Remedy Selection The remedial actions in the Record of Decision (ROD) dated August 27, 1992, provided for remediation of contaminated soils and groundwater. The remedial actions identified in the ROD were as follows: Groundwater The groundwater remedy was targeted at removal of site-related contaminants in the groundwater through groundwater extraction and on-site treatment by chemical means and air stripping. The following activities were identified as being associated with this alternative: ♦ Contaminated groundwater would be extracted from within the Surficial and Upper Black Creek aquifer plume via extraction well(s) and piped to an on-site, aboveground treatment facility. ♦ Treatment would consist of carbon adsorption canisters to remove contaminants of concern. ♦ Final discharge of the effluent would be to either an on-site infiltration gallery or via connection to a Publicly Owned Treatment Works (POTW). ♦ Continued analytical monitoring of contaminants in groundwater. ♦ Further characterization of the Upper Black Creek aquifer to determine the extent of pesticide contamination. The remedy.for contaminated soils had the intent of permanently removing contamination in the soil through off-site disposal of contaminated soils. The following activities were identified as being associated with this alternative: 6 • Five• Year Review Gei!J Chemical Corp. (Aberdeen Plant), Aberdeen, NC ♦ Excavation of the top foot of soils exceeding cleanup standards identified in the ROD. ♦ Disposal of contaminated soils in a secure landfill or a fixed-base incinerator depending on their regulatory requirements. ♦ Confirmation sampling and analysis to ensure that remediation levels are attained. + Backfill of excavated areas with clean fill, regrading of site and revegetation with native grasses. Tables 2 and 3 show the clean-up standards for soil and groundwater under the ROD. Table 2. Soil Clean-Up Standards Soil Clean-U o Standards Contaminant Clean-up Standard (mg/Ko) Aldrin 0.113 Aloha-BHC 0.28 Beta-BHC 1.15 Delta-BHC NC Gamma-BHC 1.5 Oieldrin 0.13 Endrin Ketone NC Toxaphene 2.0 ODD 7.6 DDE 5.5 DDT 4.75 Gamma-Chlordane 1.43 Alpha-Chlordane 1.4 * Note: NC = Not Calculated. Table 3. Groundwater Clean-Up Standards Groundwater Clean-UP Standards Contaminant Groundwater Clean-Up Corresponding Risk Basis of Standard (µ!!IL) Level Goal Aldrin 0.05 5.0 X 10'0 CRQL Aloha-BHC 0.05-J J X 10'0 CROL Beta-BHC 0.05 4.0 X 10'' CROL Delta-BHC 0.05 ND CRQL Gamma-BHC 0.05 3.0 X 10·1 CRQL Dieldrin 0.1 8.3 x 10·0 CRQL Endrin Ketone 0.1 ND CRQL Toxaohene 1.0 6.7 X 10'0 NCGWOS CRQL -Contract Required Quantitation Limit NCGWQS -North Carolina Groundwater Quality Standards ND -Not Determined, Toxicity data unavailable, risk levels could not be calculated. 7 • • Five-Year Review Geigj Chemical Co,p. (Aberdeen Plant), Aberdeen, NC The soils removal remediation was completed in early 1997. Site restoration was conducted in January 1997. A final inspection by EPA and the State of North Carolina Division of Superfund occurred on February 26, 1997. Based on results of the pre-remedial design field investigation, showing the presence of pesticides in the Upper Black Creek aquifer, additional investigations of the downgradient areas were conducted. A Downgradient Groundwater Investigation Work Plan (Rust, 1995) was prepared and presented to the EPA and NCDENHR to determine type, distribution and concentration of pesticides in the downgradient areas. Field investigations for the downgradient groundwater studies were conducted from March to October 1995. Results of the investigation were reported in the Downgradient Investigation Summary Data Report dated March 1996. The PRPs and Agencies met in May of 1996 to discuss preparation of a remedial action plan for the downgradient area and agreed to develop a Remedial Action Work Plan (RA WP) that would evaluate the containment and attenuation of pesticide concentrations as a component of the remedial action for the downgradient area. The resulting RA WP, finalized in November 1997, has the following objectives: • reduce pesticide concentrations in downgradient groundwater to levels which are protective of human health and the environment; • ensure that Site-related pesticide concentrations in downgradient surface water and stream sediments are protective of human health and aquatic receptors; and • monitor drinking water supplies in the downgradient area to verify they are not adversely impacted. The RA WP defined the downgradient area as the portions of Upper and Lower Black Creek aquifers bounded by McFarland's Branch, Aberdeen Creek, Ray's Mill Creek, and Trough Branch. The surficial aquifer was excluded from the work plan. Data from the downgradient groundwater investigations revealed that the BHC isomers were the only target pesticides exceeding Federal or State drinking water standards or Site Performance Standards. As a result of the analyses, the goal of the down gradient remedial action is to reduce BHC isomer concentrations to levels below the North Carolina and Federal drinking water standards or, for alpha-, beta-, and delta-BHC, which do not have established drinking water standards, to levels below the groundwater Performance Standards listed in Table 3. The downgradient groundwater Performance Standards are listed in Table 4. Table 4. Downgradient Groundwater Clean-up Standards Contaminant Clean-up Standard ( u!!/L) Aloha-BHC 0.05 Beta-BHC 0.05 Delta-BHC 0.05 Gamma-BHC 0.20 The recommendations and proposed remedial Performance Standards for the downgradient groundwater in the RA WP were implemented by issuance of an Explanation of Significant Differences to the Remedial Action (ESD) in January of 1998. The different 8 0 • Five-Year Review Gew Chemical Co,p. (Aberdeen Pla11t), Aberdeen, NC performance standards for gamma-BHC (Lindane) between the site remedy (0.05 µg/L; Table 3) and the downgradient remedy (0.2 µg/L; Table 4) reflect a change in the North Carolina Groundwater Standards (Title 15A NCAC 2L .0202) between issuance of the ROD and ESD. B. Remedy Implementation There were three removal actions associated with the site for soil remediation. The first two, conducted in 1989 and 1991, removed soils visibly contaminated and other debris from the site. Approximately 3,300 tons of soil and debris were removed for disposal in these two actions. The 1989 removal action consisted of two phases. In the February 1989 phase, material removed was disposed of in the GSX landfill in Pinewood, South Carolina. The second phase in October 1989, resulted in soils being incinerated at the Therma!Kem facility in Rock Hill, South Carolina or being transported as hazardous waste to the Laidlaw Environmental Services Landfill (Formerly GSX Services) in Pinewood, South Carolina. During the 1991 removal, approximately 500 tons of soil were incinerated at the Rollins Facility in Deer Park, Texas. The remainder of the soil and debris removed were disposed ofat the Chemical Waste Management landfill in Carlyss, Louisiana. Following the preparation and finalization of a Remedial Investigation/Feasibility Study, a Record of Decision (ROD) was signed August 27, 1992. The Remedial Action implemented by the ROD included demolition of the former warehouse foundation; excavation of the top foot of on-site soils contaminated above performance standards; off-site disposal of excavated soils as appropriate; extraction of groundwater from the surficial and Upper Black Creek aquifers; treatment of extracted groundwater via carbon adsorption; site restoration; and further sampling and analysis of the Upper Black Creek aquifer to determine extent of pesticide contamination and determine if TCE found in two on-site wells was site-related. The Remedial Action (RA) was conducted from September 1996 to February 1997. The RA included removal of concrete foundations and other debris totaling approximately 2,460 tons to a Subtitle D landfill in Kernersville, North Carolina; and disposal of 4,475 tons of contaminated soils to a Subtitle C landfill in Pinewood, South Carolina; construction and installation of extraction wells and groundwater treatment facilities with an infiltration gallery for discharge of treated groundwater. The treatment system began operation in January 1997 and has currently treated approximately 30 million gallons of extracted groundwater from the surficial and Upper Black Creek aquifers. C. System Operations / O&M After completion of the remedial action in 1996, the site was revegetated with native species and planted long-leaf pines. Since establishment of vegetation, the site has not experienced erosion or other problems, but recent ice storms have necessitated the removal of some of the trees. Currently, the site is mowed twice a year to maintain a neat appearance along the right-of-way for NC 211. As required in the ROD and ESD, the PRPs have been operating a pump ai1d treat system for remediation of the surficial and Upper Black Creek Aquifers since January of 1997 and monitoring the downgradient areas since April of 1998. Figure 3 shows a conceptual flow model 9 0 • r'-.ive-Year Review Geigy Chemical Co,p. (Aberdeen Plant), Aberdeen, NC of the pump and treat system. Since commencement of groundwater treatment operations, Pinnacle Consulting Group of Greenville, South Carolina has had the treatment monitoring and O&M contract for the PRPs. Initial monitoring requirements called for quarterly sampling for the first three years followed by semi-annual sampling for an additional two years. Following submission of the Downgradient Remedy Summary Report to the State and EPA in 2001, it was agreed by all parties that annual monitoring could be undertaken. Therefore, the most recent round of monitoring well sampling occurred in October of 2002. Monitoring well and surface water sampling locations are shown in Figures 4 and 5. Wells that are currently sampled for monitoring are as follow: • Surficial Aquifer: MW-4S, MW-5S, MW-6S, MW-I0S; • Upper Black Creek Aquifer: MW-1 lD, MW-18D, MW-30D, MW-19D, MW-20D, MW- 22D, MW-23D, MW-24D, MW-25D, MW-26D, MW-35D, MW-29D, MW-34D; and o Lower Black Creek Aquifer: MW-22L, MW-25L, MW-27L, MW-37L, MW-40L, PZ-2, PZ-3, MW-28L, MW-3 IL, MW-38L, MW-39L, MW-32L, PZ-5, MW-36L. Figure 6 depicts the locations of the extraction system pipelines, treatment building, and infiltration galleries. Since initiation of operation of the pump and treat system in January 1997, there have been few problems or breakdowns of the system. In a phone conservation with Mr. Art Barnhardt ofNCDENR July 30, 2003, Mr. Samuelson was informed that there are no specific records for the site delineating percent downtime versus operating time. Mr. Barnhardt also indicated that the site treatment system has operated with what he considers as "normal" maintenance issues such as the occasional replacement of an extraction pump or activated carbon barrel train. The 1992 ROD forecast an estimated annual O&M cost of $50,000 per year of operation. As currently implemented the treatment and monitoring program costs approximately $48,000 -$50,000 annually to operate. The system has treated approximately 50 million gallons of groundwater, operating at a pumping rate of 15-18 gallons per minute. The infiltration gallery contains 3 laterals; each being 175 feet long. The distribution of flow within the gallery is determined by a preset timer that activates solenoid valves at the gallery header. The timer is set to direct flow to two of the laterals at a given time. It alternates flow among the three laterals on an 8-hour cycle. As operated, each lateral will receive an average of half of the effluent from for 16 hours and no flow for the following 8 hours. The flow cycle is as follows: First 8 hours: Flow to laterals I and 2; Next 8 hours: Flow to laterals 2 and 3; and Next 8 hours: Flow to laterals 3 and I. The change-out/longevity period for the carbon adsorption canisters was initially one year, but has shortened to a six month l!me period. It is suspected that this change is due to increasing levels of Trichloroethene (ICE) coming from up gradient of the site. No significant differences in O&M costs, as projected in the ROD and ESD, were identified. At this time, it is expected that operations will continue without modification or increased expense until remediation is complete. 10 • Five-Year Review Geigy Chemical Corp. (Aberdeen Plant), Aberdeen, NC Figure 3. Flow Model of the Pump and Treat System Extraction Wells (7) Equaliza1ion ·rank Carbon Adwrption Canis;cers; Carbon Adsorption Cunistcrs 11 ~loni101ing Discharr;i: It) lufillnition Gnllcric~ (2) Figure 4. Monitoring Well and Sampling Locations_ ·~~;1~> ' ~ ~ -· . -- MW-37L 0 MW-40L <:,l,SW-03 ~ MW-25D SW-10 MW-28L MUW-2 0 MW-27L 0 - 0 MUW-1 r'lve-Year Review Ge,:ry Chemical Co,p. (Aberdeen Plant), Aberdeen, NC Geigy Chemical Corp. (Aberdeen Plant) Remediation Program l!l Lower Black Creek Aquifer Monitoring Wells @ Upper Black Creek Aquifer Monitoring Wells o Surficial Aquifer Monitoring Wells lg) Extraction Wells <i? Surface Water Monitoring Points o Municipal water Wells 500 250 0 '"q MW-36L 500 ~000 MW-34D " W•19D 1,500 l~aet ~ MW-25L \ MW-26D © MW-22D 0 MW-22L MW-20D ., " MUW-4 rB " li'l r;;i 12 MW-35D SW-01~ @ MW-24D " MW-23D " 0 0 0 See Flgure5 • Figure S. Site Area Monitoring and Extraction Well Locations j MW-1!l0@, • PWC2D • PW-3D MW-1103 • PW-1D Geigy Chemical Corp. (Aberdeen Plant) Remediation Program Immediate Vicinity • Extraction Wells 0 Surficia/ Aquifer Moniton"ng Wells ~ Upper Black Creek Aquifer Monitoring Wells MW->OS 0 100 50 MV,.,S ·• • PW-15 • PW-2S MW-105 e 0 PW.JS MW-17S 0 0 100 13 MW-165 -~ 200 300 400 Five-Year Review Geigy Chemical Corp. (Aberdeen Plant), Aberdeen, NC MW-t6DQ MW-1700 500 Feet • • Figure 6. Extraction System and Treatment Facility Diagram F E D C B \ CXIST1NI. -•Ill ~~­ EXISTI)tG wnt. 1'011(1' PIEZCNCT[R ---· ---~ wru f1)IICt iwM -1. T0l'0 wo.f'l'lffl. IJf WOOLPDl1 C'OIIWI.TMTS &UlP Q!I ..CRloll. ~111 n.DWM l<UCH n. 1 ,.,, ~ <;ROI/ND COl<fa<I\. ntD TO ~ ~~rt l'LAHE Cl)Cf!Dl><An; =~ ~ l'U.l<U<CTR1C FU,llll!B W[R{ nn.r, l(lomncll OM ,._.y 111. t,n fY ..oou'UT c:o,:;,,&J~ :i.. ro11 TTl'ICAL TttHCH cross sa;ooN set ~ .. ..canu--c...u. 4.1.0C&.llOII Cr..::ctS$RO&Cs,,a,rl<CIITlll$plll,"1NI. IS _....,QU.~ i:x.o,;r UICATICM nJ.. !IC C)[lOIO'U<£D .. rn, F'E.ll ff C•l'l<U"5 •!Plt£5V<TATIVL roll ~ DCTA.l. S[t TTPICAl I.RAVO. IIO,ll!I C1t05S :!CCTI0II 011 OR,UID<G BH1•--C..<)<. A ... ..,. -IU -,,.,...,., L___ -- .,.._ .,.. 14 Five-Year Review Geigy Chemical Corp. (Aberdeen Plant), Aberdeen, NC .--· EXTRACTION ANO TREAHCENT SY.STU.I SIT£ LAYOUT (:V(IT Clll;IIIC,\L COl!F'OIIATIO!I sat ......,.__~ ....... ENVJRONM!Nf. I._U>I INFRASTRIJCT'JRE ---..... .., ,., ~:&"" 86619-C-02 ~-""' ... --.. ,-,,._......,,,._ F E D C E • • • V. Progress Since the Last Five-Year Review: .Five-Year Revie1v Geig;; Chemical Co,p. (Aberdeen Plan~. Aberdeen, NC · Since this is the first Five-Year Review Report, no other report is available and thus no progress is reportable. VI. FIVE-YEAR REVIEW PROCESS The five-year review process for the Geigy Chemical Corp. (Aberdeen Plant) site included telephone discussion/interviews with the EPA Remedial Project Manager (RPM), and the lead State agency. Also included, were a visit to the Aberdeen Town Hall, the public repository for the remedial action documents, and a site visit for familiarization with the remediation activities. A list of pertinent materials from the document repository and other sources is provided in Attachment 1. The following persons were members of the five-year review team: + Greg Mellema, Hazardous, Toxic, and Radioactive Waste Center of Expertise (CENWO-HX-G), Omaha, NE, for QA of document preparation. ♦ Phil Payonk, Wilmington District, Environmental Resources Section (CESA W-TS- PE). ♦ Stacy Samuelson, CESA W-TS-PE. VII. FIVE-YEAR REVIEW FINDINGS A. Interviews The following persons were interviewed regarding the activities and implementation of the remedial actions at the Geigy Site: Mr. Jon Bornholm, Remedial Proiect Manager, EPA Region 4: In several telephone conversations between Stacy Samuelson and Mr. Bornholm, several issues pertaining to the Geigy Site were identified. The concern for potential effects on the remedy due to the off-site TCE plume migration into the site area was identified. A second issue, full implementation of the Record of Decision in terms of fencing and signage at the site, was addressed as well. Additional discussion of these issues are provided in Sections IX, Issues, and X, Recommendations and Follow-up Actions. Mr. Randy McElveen, Environmental Engineer, North Carolina Department o(Environment and Natural Resources, Division o(Waste Management, Superfund Federal Remediation Branch: Stacy Samuelson, Wilmington District, made initial contact with Mr. McElveen through a telephone conversation. Mr. McElveen indicated that the State has no major issues with the site at this time. At the site visit, the issue of the off-site TCE plume was discussed in relation to the site remedy. The State has some concerns about the undefined source of that plume and its potential effects on the Geigy Site remedy. 15 • B. Site Inspection • Five-Year Review Geigy Chemical Co,p. (Aberdeen Plant), Aberdeen, NC A site inspection of the Geigy Site was conducted on February 18, 2003. Attending the site visit were: ♦ Randy McElveen, Environmental Engineer, North Carolina Department of Environment and Natural Resources, Division of Waste Management, SF Federal Remediation Branch. ♦ Jon Bornholm, Remedial Project Manager, Environmental Protection Agency, Region 4. ♦ Ray Horn, Olin Corporation. ♦ Harold Moats, Syngenta Crop Systems. ♦ Michael Sheehan, Pinnacle Consulting Group. ♦ Ted Volskay, Pinnacle Consulting Group. ♦ Ray Livermore, U.S. Army Corps of Engineers, Wilmington District. ♦ Phil Payonk, U.S. Army Corps of Engineers, Wilmington District. ♦ Stacy Samuelson, U.S. Army Corps of Engineers, Wilmington District. For documentation of the site visit, photos of the treatment facility and several extraction wells were taken and are attached as Attachment 2. The site area has not been re-developed since the source remedial action was completed in 1996. The area is currently vegetated with grasses and some long-leaf pines have been planted along the railroad right-of-way. Mr. Sheehan gave a brief historical overview of the activities and locations of facilities during the source remedial action and provided a tour of the pump-and- treat facility. C. ARAR Review In performing the five-year review for compliance with applicable or relevant and appropriate requirements (ARARs), only those ARARs addressing risk posed to human health or the environment (i.e., addressing the protectiveness of the remedy) were reviewed. This is in keeping with current EPA guidance on five-year reviews. Federal ARARs ♦ Federal Groundwater Classification -55 Federal Register (FR) Part 8733. ♦ Safe Drinking Water Act of 1986, as amended ( 40 USC § § 300) -40 CFR Part 141. ♦ Solid Waste Disposal Act (40 USC§ 6901 -6987)-40 CFR Part 261. ♦ EPA Regulations on Sole-Source Aquifers-40 CFR 149. State ARARs ♦ Identification and Listing of Hazardous Waste-!SA NCAC 13A.0006. ♦ North Carolina Drinking Water Act-General Statutes, Chapter 130A, Article IO. 16 • • Five-Year Review Geigy Chemical Co,p. (Aberdeen Plant), Aberdeen, NC ♦ North Carolina Water Quality Standards-15A NCAC 2B. ♦ North Carolina Groundwater Quality Standards-!SA NCAC 2L.0I00, 2L.0200, 2L.0300. The site appears to be in compliance with the ARARs identified in the ROD. There were no changes in the reviewed statutes and standards that would require changes in the remedy or management of the site. D. Changes in Exposure Pathways, Toxicity and Other Contaminant Characteristics No changes in the site conditions that affect exposure pathways were identified as part of the five-year review. There are no current or known changes planned in the land use and it is likely to remain rural residential immediately adjacent to the site. No new contaminants, sources, or routes of exposure were identified as part of this five-year review. There is no indication that hydrologic/hydrogeologic conditions are not adequately characterized. The rate of decrease of contaminant levels in groundwater is consistent with expectations, and the groundwater plume appears to be contained. This finding is supported by groundwater flow model simulations that were conducted by Olin Corporation and Syngenta Crop Protection to evaluate the site groundwater extraction system with respect to pesticide capture during the summer of 2003. Findings of the simulations were reported to EPA by letter report dated September 15, 2003 by the Pinnacle Consulting Group. Data from the Preliminary Design Report (Rust E&I, 1995) along with data from the monitoring program implemented in 1997 was analyzed for the simulations. Due to groundwater level and recharge rate fluctuations, three model iterations were run. The model runs were for minimum, average, and maximum extraction rates. Figures 5, 8 and 11 of the letter report show the predicted capture zone areas for the Upper Black Creek aquifer extraction wells (Attachment 3). The contaminants_ of concern in both groundwater and soils were reviewed in the EPA's Integrated Risk Information System (IRIS) for changes in toxicity. Review of the IRIS database revealed that toxicity and other factors for contaminants of concern have not changed with the exception of the soil contaminant chlordane. For that compound, the cancer slope factor decreased, and the reference dose increased. However, since the soil cleanup was based on cancer risk, this would have resulted in a slightly higher calculated soil cleanup value, and does not call into question the protectiveness of the remedy. E. Data Review Based on issues identified during document review, interviews and site inspection, the principal data reviewed were related to groundwater contaminant levels of the site and downgradient area. The main resource for review of data was the Downgradient Groundwater Remedial Action Work Plan, Geigy Chemical Corporation Site, Aberdeen, North Carolina (RA WP) (November 1997) and groundwater monitoring data provided by Pinnacle Consulting Group (October 2001). 17 • Soil Data • Five.Year Review Geigy Chemical Corp. (Aberdeen Plant), Aberdeen, NC Soil contamination data have not been collected since the completion of the Remedial Action. Performance Standards for soils were met or exceeded as a result of the remedial action and the results of final soil testing were reported in the Final Remedial Report For Soils (1997). Groundwater Data I Groundwater sampling data was reviewed for sampling events occurring from May 1998 to the present. Wells were sampled quarterly for three years and then semi-annually for the last two years. Samples were analyzed for organochlorine pesticides. Starting in 2003, with coordination with the EPA and State, monitoring will be conducted annually. Over the monitoring period, some wells have been abandoned or added and several, notably MW -11 D, MW-18D and MW-30D, were unable to be sampled due to drought conditions in the third quarter of 1998. Table 5 presents the detected values for BHC isomers in the surficial aquifer for wells in the current monitoring program. Graphical representation of the data for each well is presented in Attachment 4. Well MW-4S is probably not affected by the surficial aquifer extraction wells, but the other surficial monitoring wells are close enough to extraction wells to be influenced by them. The effect of the extraction wells influence on the surficial monitoring well results is not known. Of the compounds on the TCL, the BHC isomers were the most consistently detected over the sampling period. Most detected values exceed the site performance standards (Tables 3 and 4). 18 • Five-Year Review Ge1g)' Chemical Co,p. (Aberdeen Pla111), Aberdeen, NC Table 5. Surficial BHC Isomer Concentrations in Groundwater Monitoring Wells 1990 - 2002 Samnle Dnte aloha-BHC beta-BBC delta-BHC ~amma-BIIC (l,indnne} MW-4S 11/16/1990 I 3 6 0.5 MW-4S 12/8/1993 0.2B 2.1 4.7 0.066 MW-4S 12/3/1996 ND(l.25) 15 10 ND(I.25) MW-4S 4/16/1997 ND(0.25) B.6' 7. I ND(0.25) MW-4S 7/14/1997 0.16 6 7.2 0.1 MW-4S 10/1/1997 0.19 6.3 6.B ND(0.25) MW-4S 4/21/1998 ND(l.25) 16 ND(l.25) ND(l.25) MW-4S I 0/29/1998 ND(0.275) 4.2 2.8 ND(0.275) MW-4S 10/14/1999 ND(0.025) 0.36 0.23 ND(0.025) MW-4S I 0/13/2000 ND(0.125) 1.5 0.66 ND(0.125) MW-4S 10/10/200 I ND(0.025) 0.013 ND(0.025) ND(0.025) :rt· . -~~i;; ; ,~·1.' :··.e::·-:·_,-~_?,! ; ,. :., ~~'.~ _ _::·,: __ ;,_;-:· r:,.~~~,~~~.~~::·.: -' ., ' " " ~~-~:-'. . .')f,9~ ;,c~·-i . .... .. .,, ... ,,. ,'.\'-c"_:; .. ,, ,_, .. ,•. MW-5S 11/16/1990 5 12 12 5 MW-5S 12/9/1993 I.I 17 6.3 ND(0.l) MW-5S 12/3/1996 ND(l.25) 17 5.6 ND(l.25) MW-5S 4/16/1997 ND(0.l) 9.5 3.1 ND(0.5) MW-5S 7/14/1997 0.23 5 l.B 0.15 MW-5S 10/1/1997 0.16 3.9 1.3 ND(0.125) MW-5S 4/21/1998 ND(0.25) 2.5 0.59 0.05 MW-5S 10/29/1998 0.31 B.6 2 0.25 MW-5S 10/14/1999 ND(0.125) 1.4 0.7 ND(0.125) MW-5S 10/13/2000 0.047 3.2 1.4 ND(0.125) MW-5S 10/10/200! ND(0.125) 1.3 0.17 ND(0.125) '•'"" h•:••i'_ jt'~,. ·-i. _'.:'.:·_!>!~'f.i:A .. 1•::';-:·· ~~.;<•:Z. •,. n·-'· •" ' ..... (~~t~~•<~\ ·'' ·.:i:•'·-::-1:··1·,,_1•1; :,•, '.';, 1:i. :~/."'l-'.+;Jt:~~~ :·.: ·:;1'.\ ... _: ·.: .... . ---. .,.,, s MW-6S \ 1/16/1990 36 12 29 30 MW-6S 12/9/1993 7 .I 9.6 9.2 6 MW-6S 12/3/1996 2.1 5.8 2.5 1.5 MW-6S 4/16/1997 2.2 6.6 1.6 1.3 MW-6S 7/14/1997 I.I 4.1 0.81 0.77 MW-6S 10/1/1997 1.3 3.8 I 0.83 MW-6S 4/21/1998 2.9 6.6 6 2.4 MW-6S 10/29/1998 t.B 7. I 4.6 I. I MW-6S 10/14/1999 3.9 6.9 1B 2 MW-6S 10/13/2000 ND(0.025) ND(0.025) ND(0.025) ND(0.025) MW-6S 10/11/2001 3.5 10 15 0.91 '.""'Ji°· '_;y\\f '."¥:!l''.,;:;:~.\ii·: i;;t'!..1:il:?~';1}t." ,;,r~·t) ~~: ~:•~~::t;·:\}~;:;;.'}l(\;. ~ ~ /t1:,·='1~::::;;1#'1 c.:./~~-;;1 1~.,-,1;[,~t<'. <t• ~~,1--J'_,,";;J:'1;¥~~'!10 .:, ti, ':b.~ ;;1:'.-;'fJ. MW-10S 7/10/1991 2 25 2 0.B MW-10S 12/9/1993 ND(0.5) 14 0.79 ND(0.l\ MW-10S 12/3/1996 0.026 0.58 0.045 0.07 MW-10S 4/16/1997 ND(0.25) 5.2 ND(0.25) 0.BB MW-10S 7/15/1997 0.1 I 1.7 0.12 0.35 MW-10S I 0/l /1997 0.59 4.4 0.47 I MW-10S 4/21/1998 0.39 7 I .6 0.34 MW-10S 10/29/1998 0.085 4.5 0.41 0.11 MW-10S 10/14/1999 0.045 2.3 0.21 0.064 MW-10S 10/13/2000 ND(0.125) t.B 0.077 ND(0.125) MW-10S 10/23/2002 0.01 0.56 0.027 0.014 Note: ;"I,. on-Detect va \ues represent one-half of the detection Jim it. Values in bold denote detections exceeding performance standards (Table 3). 19 • • Five-Year Review Geigy Chemical Co,p. (Aberdeen Plant), Aberdeen, NC Tables 6 and 7 depict the concentration levels for the same compounds in the Upper Black Creek and Lower Black Creek aquifers. Graphical representation of the data for the Upper Black Creek Aquifer is found in Attachment 5 and the Lower Black Creek Aquifer in · Attachment 6. Table 6. Upper Black Creek Aquifer S11mpling Results 1998 to 2002 Excccdcnces of Performance Standards for BHC Isomers Well I 2Q9s I 3Q98 4Q98 1 t Q99 I 2Q99 3Q99 4Q99 I I Q00 2Q00 3Q00 I 4Q00 I tQ0t 4Q0I 2Q02 W e1IS·withil1'1tb"e' t'ifraC'tiollra'iid:fre'at'Oi"eri't'cap·tllr'e' i'Oii'e·,;lt\ :•_,:f ;., ""'"'•'' ~ , .. .,. ·-~\ :i, :r; .i-. ",I!'•; . ·: ;"t\!-i', _·1':, . > •. ,,•· ,.,_: MW-11D t NS t NS t t t t t t t t NS NS MW-18D t NS t NS t t t t t t t t t NS MW-30D t t t NS t t t t t t t t t NS 4Q02 ''"'.;;,\·~~ NS NS t MOriitOriiig ·w·e11S'.f1fr.are8 lli)dtr re med);· iinpltnitrit8:tio"n',~ --'·._; ,: "';. t": ~ . ,ii; •• · : .';l J. ,/: ... ',r '::<:<_ ::·.~ :: -'i' /:_,';(! ,·Y, . J-.: .. ,, .... , . -.. .. MW-190 A' A,B,G t t t t t t t A,G t A,D,G NS NS .:\IW-20D A' t t t t t t t t t t t t t MW-220 t t t t t t t t t t t t t t MW-23D t t A,B,D t t t t t t t t t t t MW-24D t B,G A,B,G t t t t A,B,G A,B,G t A,B,G t NS NS MW-25D ND ND ND t t B,D,G ND ND ND ND ND ND NS NS :\IW-26D t t t t t t ND t t t t t t t MW-350 t t t t t t t t t t t t t t Well ror assfssfu"ent of grOundW&ter'. quality__dOwngradie·nt'of tb·e Surficiftl nquifer,"Well M\\'.~33S ·::~·:_ ~.•:;.~-.( -., ' T I MW-3401 ND Well 2Q98 ND ND I B I B B B B B B I B B I Table 7. Lower Black Creek Aquifer Sampling Results 1998 to 2002 Excccdences of Performance Standards for BIIC Isomers 3Q98 4Q98 IQ99 2Q99 I 3Q99 I 4Q99 IQOO 2QOO JQOO 4QOO I !QOI NS NS 4QOI 2Q02 NS t t t NS NS t t ·:•, .. NS 4002 Sfntiriel .\\·tff for'.U""tr.·BiaCk.Creek /,..LoWel'iBlacli·creekAO.Uiferi Illtf:rface~;:·~~:;,; :1,:·-: ... :'.Ht~~--~,,.,~.,. : _: J ?~:iii£.:·::}~,;;·..,1 ;,L·)•,!f.i MW-22Li t I t t t I t I t t I t t t I t I t t t t M O iii tO r i i1 g ~w f!ll S: fo 'r. a· i-t a 'll rl d Cfr ., r'e"in e·d )' i lT1 p le m f: ii tiiti o·n":f'i:~-:;,j,j;W· ;~~.i_;;,1:;::;,J, ,i[li~~:;r't: 11~}1i:!:;!tii,1!}~; :it~~i~,)"r:,. ·1~, i'.w·l>:\, 1.,f,.: i'.-i1l~:~-;~ .~"1 t t t MW-2SL t t t t t t t t t t t t MW-27L t t t t t t t t t t t t t t t MW-31L t t t t t t t t t t t t t t t MW-37L t t A/G t t t t t t t t t t t t l\1W-40L t t t t t t t t t t t t t t t PZ-2 t t t t t t t t t t t t t t t PZ-3 t t t t t t t t t t t t t t t PZ-5 ND t BIG A/BIG A/B/G t t AIB/G t A/BIG t t t t A/BIG we us·, tO: for e·c·a st·' tT'iiii:I S: f O i. Ray'. s r M ill I Cree i.:;·•A li«iid ee 11 ~ C re e k,~·,rn d. M CF a r liiD d's. B r8 n Ch'~:;~;~ .. '.1'ih.,7r"J( .;;i-1;· !,~··11;-.; ,((;l'.;: :1;/( ,~:' / t PZ-2 t t t t t t t t t t t t t t PZ-5 ND t BIG A/BIG A/BIG t t AIB/G t A/BIG t t t t AIB/G MW-31L t t t t t t t t t t t t t t t SC.ii'tin·et:WCII' f(tf noithWi!f"d:ftsticidt inigiiition. an·d\fortCaSt Of co·nceiitr'atloD_trCn"ds In RBY!S,M ill Cre·ek"f:~>;;;'.~~•:tll:;:;t'.~~. I t MW-28L A' A t· I t I t t t t A/8 I t I B/D/G t I t t se-n tin·e1. W,ellf for ;noteri'tiiil' itiigriltiO'ii :or, p'tsticidfsTiito RaV: s'-l\-1 ill.Creek"' 1ind. AbCrdCCD .c reek-':.:,;'i_{:-., '::J:_~,~:~;: .A;,-;;:H A!.~~<.'.::·~~ MW-32L ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND MW-38L ND. t ND ND ND ND ND ND ND ND ND ND ND D ND MW-39L ND t ND ND ND ND ND ND ND ND ND ND ND ND ND se-n-ti ii'Cl .. w.eu if o l'j;T oW n. We II N 0) 2 :Fa.l'.\;fji]R.,;:,i.~t:·,U(.a;J\lJ;T,_~j;Jli:it~ik :~Eitiii,?t::-;;:s1i:siU!f.,,ilit:i'!i.:%~~~1.Ii'.\~1:;~;::~;;;~::i~~iiH~,;yt!1:,iit;i";-,!Llfil'.·!i~j;~ MW-36L ND I ND I ND ND ND I B I ND I ND I ND Notes: t Denotes all BHC isomers detected and exceeding perfonnance standards. ND loenotes non-detect for all BHC isomers. A -alpha-BHC, B -beta-BHC, D • deltn-BHC, G -gammn-BHC • Letter only denotes that compound detected exceeding performance standard, NS= Not Sampled. 20 ND I ND I ND ND ND ND • Five-Year Review Geigy Chemical Corp. (Aberdeen Plant), Aberdeen, NC Trends in the BHC isomer concentrations in downgradient groundwater are varied. Several wells (MW-34O, MW-36L, MW-38L, and MW-39L) indicate no trend (little change) for the 1998-2002 monitoring period. Monitoring well MW-35O decreased over the same monitoring period. BHC concentrations for wells MW-3 70 and MW-40L slightly increased. Data for the downgradient areas seem to reflect reductions in concentrations of contaminants for the remedy area monitoring wells. However, BHC isomer concentrations were consistently above perfonnance standards. Sentinel wells for Town Well No. 2 (MW-36L) and Ray's Mill and Aberdeen Creeks (MW-32L, MW-38L, and MW-39L) have only four instances of BHC- isomer detection during the monitoring period. Wells MW-38L and MW-39L had detection of all BHC-isomers in the third quarter 1998 sampling event; well MW-36L had detection ofbeta- BHC in third quarter 1999; and well MW-38L had detection of delta-BHC in second quarter 2002. Due to the hydrology of the area, the Upper and Lower Black Creek aquifers discharge to the following surface creeks: Aberdeen Creek, McFarland's Branch, Ray's Mill Creek, and Trough Branch. Surface water sampling for the BHC isomers has been conducted since 1996 at most of the sampling points shown on Figure 3. Table 8 lists sampling results for BHC-isomers from the downgradient surface water monitoring stations. Graphs of the data for the surface water san1pling sites are found in Attachment 7. 21 • • Five-Year &view Geigy Chemtcal Corp. (Aberdeen PlanJ, Aberdeen, NC Table 8. BHC-isomer Sampling Results for Surface Water Monitoring 1996 -2002 (:·· ?:\~Sitri;;.1". ~-: \~:s'li~ie o-~"tt:'. ~---~---:'-"~-.ri'-~, """.:'lilnl:ia~BHG, :' : i·H:ra;BJIC ~--: r1~~rtt'.....,.'J.~ :"'delta~BHC".. _:,·11.1;. ••,,·.:-,, ••>"11-',:'. ,,,;.;J;: 1 iiamm·ll-BHC.(Lin'danCl SW-01 6/4/1996 0.025 0.025 0.025 0.025 SW-01 4/29/1998 0.025 0.025 0.025 0.025 SW-01 7/20/1998 0.025 0.025 0.025 0.025 SW-01 10/28/1998 0.026 0.005 0.026 0.026 SW-01 1/12/1999 0.025 0.0069 0.025 0.025 SW-01 4/12/1999 0.025 0.025 0.025 0.025 SW-01 8/10/1999 0.029 0.007 0.029 0.029 SW-01-re 8/10/1999 0.028 0.0055 0.028 0.028 SW-01 10/12/1999 0.025 0.025 0.025 0.025 SW-01 2/2/2000 0.025 0.025 0.025 0.025 SW-01 4/11/2000 0.025 0.0049 0.025 0.025 SW-OJ 7/21/2000 0.025 0.025 0.025 0.025 SW-01 I 0/14/2000 0.025 0.011 0.025 0.025 SW-01 1/9/2001 0.025 0.025 0.025 0.025 SW-01 10/9/2001 0.025 0.025 0.025 0.025 SW-01 4/9/2002 0.019 0.017 0.019 0.019 SW-01 I 0/25/2002 0.025 0.025 0.025 0.025 ;•,•1·:·_-~:;/·i~~:· ,. :{;!·::~'.r:~}::;r-:~t ".', ;t ~ \!,' :;:,:;·::•;-: .. -:,:"/, ,···>.<··· .... ,,. ::/: ~-:.<·· '·:''.•!'j'(\ .. ~,:·0 ·:'/~:~'.:_r:. 1•'};\~ ';i-?il: .~! '!' l' ,•. j ,, : ,, ' ,.,,.,, SW-02 6/4/1996 0.052 0.085 0.097 0.059 SW-02 4129/1998 0.032 0.055 0.066 0.031 SW-02 7/20/1998 0.03 0.07 0.076 0.027 SW-02 10/28/1998 0.036 0.073 0.079 0.036 SW-02 1/12/1999 0.038 0.064 0.07 0.036 SW-02 4/12/1999 0.032 0.067 0.075 0.031 SW-02 8/10/1999 0.046 0.12 0.11 0.055 SW-02-re 8/10/1999 0.041 0.096 0.092 0.042 SW-02 I 0/12/1999 0.012 0.054 0.053 0.011 SW-02 2/2/2000 0.029 0.042 0.051 0.027 SW-02 4/11/2000 0.025 0.052 0.053 0.032 SW-02 7/20/2000 0.032 0,075 0.071 0.03 SW-02 10/11/2000 0.031 0.068 0.067 0.025 SW-02 1/9/2001 0.035 0.068 0.072 0.028 SW-02 10/9/2001 0.02 0.054 0.049 0.017 SW-02 4/9/2002 0.048 0.11 0.11 0.04 SW-02 7/17/2002 0.017 0.05 0.046 0.025 SW-02 10/25/2002 0.014 0.045 0.039 0.025 Values are in µg/L. Values in red exceed the remediation goals for the downgradient.area (Table 4). 22 • Table 8 continued: "':?~?Sii~\:·.:, ,., ... ,=.a,.•;,,..;,_,..i. -rt; 11: Sam-pie DntC~ _ i .. .,..~·-·~····--::...:.._• : .. ali>lia-BHC1 SW-03 6/4/1996 0.044 SW-03 4/29/1998 0.034 SW-03 7/20/1998 0.027 SW-03 10/28/1998 0.029 SW-03 1/12/1999 0.034 SW-03 4/12/1999 0.032 SW-03 8/10/1999 0.034 SW-03-re 8/10/1999 0.029 SW-03 10/12/1999 0.014 SW-03 2/2/2000 0.028 SW-03 4/11/2000 0.029 SW-03 7/20/2000 0.03 SW-03 10/11/2000 0.027 SW-03 1/9/2001 0.033 SW-03 10/9/2001 0.02 SW-03 4/9/2002 0.048 SW-03 7/17/2002 0.015 SW-03 10/25/2002 0.014 t~t\t; :?' .. ,? r;,~,_~, ;,i. fH-ii.'._4-'<: .. :;~,i; ~t)~{~ ~-·t::, .:_*1:l>_ , ... , ._-,;._. ··' .- SW-04 6/4/1996 0.025 SW-04 4/29/1998 0.011 SW-04 7/20/1998 0.013 SW-04 10/28/1998 0.0255 SW-04 1112/1999 0.0089 SW-04 4/12/1999 0.Q25 SW-04 8/10/1999 0.Q18 SW-04-re 8/10/1999 0.014 SW-04 10/12/1999 0.005 SW-04 2/2/2000 0.0087 SW-04 4/11/2000 0.017 SW-04 7/20/2000 0.015 SW-04 10/11/2000 0.025 SW-04 1/9/2001 0.QI SW-04 10/9/2001 0.017 SW-04 4/9/2002 0.028 SW-04 10/25/2002 0.01 Values are 111 µg/L. .~rt 81·1 C ~ 0.055 0.043 0.052 0.048 0.Q45 0.05 0.077 0.062 0.022 0.033 0.044 0.063 0.046 0.053 0.044 0.087 0.042 0.037 ,/:~Jt·.tt ·,;)~V 0.025 0.019 0.028 0.0255 0.016 0.021 0.048 0.033 0.0085 0.014 0.032 0.037 0.036 0.022 0.016 0.038 0.019 • Five-Year Review Geigy Chemical Corp. (Aberdeen Plant), Aberdeen, NC "· cf~1t':Bltf:, '.'.·,;~ ~imill:BiiC·cLirfd•urfe}·<"· 0.061 0.035 0.05 0.023 0.052 0.016 0.049 0.017 0.048 0.024 0.051 0.021 0.068 0.036 0.058 0.024 0.0215 0.0085 0.o35 0.019 0.045 0.02 0.054 0.021 0.043 0.015 0.056 0.019 0.041 0.011 0.088 0.031 0.036 0.025 0.029 0.Q25 ·}•::,.:. ,.. ,. ' Pt~ ;;1;~)~t~ Jt·f1.,{~':¾(1!'.h ·,: r;. -. 0.025 0.025 0.022 0.025 0.027 0.025 0.014 0.0255 0.018 0.025 0.019 0.025 0.042 0.Q25 0.03 0.025 0.008 0.Q25 0.014 0.025 0.031 0.Q25 0.024 0.025 0.033 0.Q25 0.016 0.025 0.018 0.025 0.036 0.019 0.015 0.025 Values in red exceed the remediation goals for the downgradient area (Table 4). 23 • Table 8 continued: :~. ·. : , SRe \:..: r·~s-:iri'ot~o;;r,· ~-f~ . ....,,, ·t -~,i, ::·alohii-BHC ·: SW-05 61411996 0,025 SW-05 712011998 0.012 SW-05 I 0/2811998 0.0255 SW-05 1/1211999 0.009 SW-05 411211999 0.025 SW-05 8/1011999 0.018 SW-05-re 8110/1999 0.014 SW-05 10/1211999 0.005 SW-05 21212000 0.0097 SW-05 411112000 0.018 SW-05 7/2012000 0.015 SW-05 1011112000 0.027 SW-05 1/912001 0.011 SW-05 101912001 0.017 SW-05 4/912002 0.027 SW-05 10125/2002 0.011 e/_ >:·r:-:: . .-~ :=~ .. ,."J~: .. ;.~{1:, ;•~~~-:·, ~l ;:': ,, ' SW-06 61411996 0.025 SW-06 4/2911998 0.012 SW-06 712011998 0.013 SW-06 10/28/1998 0.0082 SW-06 1/1211999 0.0082 SW-06 4112/1999 0.025 SW-06 6/1511999 0,028 SW-06 8/1011999 0.016 SW-06-re 8/1011999 0.017 SW-06 10/12/1999 0.0055 SW-06 21212000 0.0087 SW-06 4/1112000 0.017 SW-06 7120/2000 0.016 SW-06 1011112000 0.026 SW-06 1/912001 0.011 SW-06 10/912001 0.014 SW-06 4/912002 0,028 SW-06 10125/2002 0.0091 Values are in µg/L. •~.--,'•:t""""~~1, l 'b"etii-BHC · 0.025 0,028 0.015 0.015 0.02 0.043 0.033 0.009 0.014 0.032 0,035 0.039 0,025 0.016 0.033 0.018 'i?. .. , .... , ' ..... ' .. ,, 0.025 0.022 0.029 0.014 0.016 0.025 0.013 0.048 0.039 0.0085 0.014 0.034 0.036 0.04 0.016 0.022 0,035 0.024 • Five-Year Review Geigy Chemical Corp. (Aberdeen Plant), Aberdeen, NC -....... 'f.~,.;.;.;,.,_...,~ . .'delta-BHC·" h~,..::i:.~::,,; ... ~....:...·.-"•~' .. ,1 ~:J;:.-.. •;;n,. : .... eamma~BHC-(LmdanCY., !' 0.025 0,025 0,025 0.025 0.014 0.0255 0.016 0.025 0.02 0.025 0.039 0,025 0.028 0.025 0.008 0,025 0.013 0.025 0.033 0,025 0.024 0.025 0.037 0,025 0.017 0.025 0.02 0.025 0.034 0.018 0.014 0.025 ':··~~-x.:~,s---· ·? l!:.·,~--1~\)._;.f/: ./\'·_: (,. s'·;,•·' 'ii 0.025 0.025 0.023 0,025 0.029 0.025 0.011 0.027 0.016 0,025 0,025 0.025 0.012 0,028 0.039 0.025 0.037 0,025 0.008 0.025 0.011 0,025 0.029 0.025 0.024 0.025 0.036 0,025 0.016 0.025 0.024 0.025 0.036 0,018 0.013 0,025 Values in red exceed the remediation goals for the downgradient area (Table 4). 24 • Table 8 continued: )Ji;7Sfll~ ;;:[! t··~·;,.--: .... ~""~--i1'sllmll1e i>ate··:: -"'..,&"~-~ ;.:aibh·a':.BIICi' SW-07 6/4/1996 0.025 SW-07 4/29/1998 0.012 SW-07 7/20/1998 0.012 SW-07 10/28/1998 0.0265 SW-07 1/12/1999 0.0084 SW-07 4/12/1999 0.025 SW-07 8/10/1999 0.018 SW-07-re 8/10/1999 0.015 SW-07 10/12/1999 0.0055 SW-07 2/2/2000 0.0084 SW-07 4/11/2000 0.017 SW-07 7/20/2000 0.013 SW-07 10/11/2000 0.028 SW-07 1/9/2001 0.0097 SW-07 10/9/2001 0.015 SW-07 4/9/2002 0.028 SW-07 10/25/2002 0.01 I . "-.· '· ·. : "c'rc;: 'c. ':;c ,,' ,". . '. ' .. ,. . .,. -~ . : ... ',,, ... ' '., ,., ·-·- SW-08 614/1996 0.025 SW-08 4/2911998 0.013 SW-08 7/20/1998 0.014 SW-08 10128/1998 0.0088 SW-08 1/12/1999 0.0097 SW-08 4/1211999 0.025 SW-08 8/10/1999 0.018 SW-08-re 8110/1999 0.02 SW-08 10/12/1999 0.0065 SW-08 2/2/2000 0.01 SW-08 4/11/2000 0.022 SW-08 7/20/2000 0.018 SW-08 10/11/2000 0.035 SW-08 1/912001 0.01 I SW-08 1019/2001 0.021 SW-08 4/9/2002 0.031 SW-08 10/25/2002 0.014 Values are in µg/L. "1"•-~_.i.,.....;"~ •,tieta'BHC,. 0,025 0.019 0.028 0.016 0.016 0.019 0.057 0.036 0.009 0.0096 0.032 0,038 0.041 0.015 0.025 0.036 0.016 .. \\it·_. Y~/· 0.025 0.02 0.029 0.014 0.019 0.021 0.042 0.045 0.0105 0.Ql5 0.039 0.037 0.048 0.019 0.039 0.043 0.024 • Five-Year Review Geigy Chemical Co,p. (Aberdeen Plant), Aberdeen, NC ticlt~=-iiHG 1r. ..... ·.:'l!!4,:~,.,..f!•:-.l.~",:_..:·_ -~·;· ,i""fd'W "\//,ianiriia-BIIC (LhidllnC '-1,,k 0.025 0,025 0.022 0.025 0.027 0.025 0.016 0.0265 0.018 0.025 0.02 0.Q25 0.041 0.Q25 0.03 0.Q25 0.009 0.Q25 0.012 0.025 0.031 0.025 0.025 0.Q25 0.041 0.025 0.015 0.Q25 0.027 0.025 0.038 0.QJ8 0.015 0.025 ..• ,· .. . .,_, ' ... .~.' ·:;• :}L, . '. ~,:,: · .. ·,•.·-~-"·. • ,,,_," . . . 0.025 0.Q25 0.027 0.025 0.034 0.Q25 0.018 0.Q25 0.019 0.025 0.021 0.Q25 0.05 0.025 0,038 0.Q25 0.009 0.025 0.014 0.025 0.04 0.025 0.029 0.025 0.047 0.Q25 0.019 0,025 0.041 0,025 0.042 0,0]8 0.019 0.025 Values in red exceed the remediation goals for the downgradient area (Table 4). 25 • Table 8 continued: :,;.~rsitJ:~/ "'<->· ...... ..,,. <· ~-.:_:Sn'miile Dlltel.-· r_;·. _;; .. ,~_,;_:_ :.! alDha·-BHC J SW-09 61511996 0.025 SW-09 412911998 O.Q25 SW-09 712011998 0.025 SW-09 I 0128/1998 0.0255 SW-09 1/1211999 0.025 SW-09 4/1211999 0.025 SW-09 8/1011999 0.025 SW-09-re 8110/1999 0.025 SW-09 10/1211999 0.025 SW-09 21212000 0.025 SW-09 4/1112000 0.025 SW-09 712012000 0.025 SW-09 I 0111/2000 0.025 SW-09 1/912001 0.025 SW-09 10/9/2001 0.025 SW-09 4/912002 0.025 SW-09 10125/2002 0.025 ·i::·::rt·::r: :.t ~~-;~i':t;i:A:/ .. ;ti,\i,i: i :i',;,:. :~•L SW-10 4/2911998 0.025 SW-10 712011998 0.025 SW-10 10128/1998 0.0255 SW-10 1/12/1999 0.025 SW-10 411211999 O.Q25 SW-IO 8110/1999 O.Q28 SW-IO-re 8110/1999 0.025 SW-10 10/1211999 0.025 SW-10 2/212000 0.025 SW-10 411112000 0.025 SW-10 7120/2000 0.025 SW-10 !Oil 112000 0.025 SW-10 119/2001 0.025 ;:rf~,-~: .. t :l,, !: :::>'t, ~1~,'1•' !' -f ;;'.:i', it>;~~;;,:; ... ;. SW-II I 011211999 0.00495 SW-II 212/2000 0.0083 SW-11-2 21212000 0.0091 SW-11-2 4/1112000 0.016 SW-11-2 712012000 0.018 SW-11-2 I 0111/2000 0.027 SW-11-2 11912001 0.011 SW-11-2 10/9/2001 0.014 SW-11-2 419/2002 0.027 SW-11-2 I 0/25/2002 0.01 Values are m µg/L. •·..;._...s;__,_, •. ,,JJeta-BHC. · 0.025 0.025 0.025 0.0255 0.025 0.025 0.025 0.025 0.025 0.025 0.025 0.025 0.025 0.025 0.025 0.025 0.025 •i~-~'.-:~ id '..~i: ,~:: 0.025 0.025 0.0255 0.025 0.025 0.028 0.025 0.025 O.Q25 0.025 0.025 0.025 0.025 I c:•,:::•ir; ·.• , -,,,:•-·:,,,', 0.0085 0.014 0.014 0.031 0.043 0.04 O.Q18 0.026 0.034 0.016 • Five-Year Review GeigJ Chemical Corp. (Aberdeen Plant), Aberdeen, NC ~:d~r,'k:BHCr r-~\etn;·ma~BIIG-fLin\itii)~::h O.Q25 0.025 0.025 0.025 O.Q25 0.025 0.0255 0.0255 O.Q25 0.025 0.025 O.Q25 O.Q25 0.025 O.Q25 O.Q25 0.025 0.025 0.025 0.025 0.025 0.025 0.025 0.025 0.025 0.025 0.025 0.025 0.025 0.025 0.025 0.025 0.025 0.025 :,,,, .. \,~ii .•. ikii;: :.~<-':/:.; ... ::/~~ti_•:1;\.t·<::.1:':{;: 0.025 0.025 O.Q25 0.025 0.0255 0.0255 O.Q25 0.025 0.025 0.025 0.028 0.028 0.025 0.025 0.025 0.025 0.025 0.025 0.025 0.025 0.025 0.025 O.Q25 0.025 0.025 0.025 't.•./-: :,:-· :~. -· ., 1~:•i;\."\,t!(l£ :1 ;;~}\·1•\."i\iJ,;;·: i ·i.~ 0.0085 0.025 0.012 0.025 0.017 0.025 0.029 0.025 0.029 0.025 . 0.037 0.025 0.017 0.025 0.029 0.025 0.035 O.QJ8 0.012 0.025 Values in red exceed the remediation goals for the downgradient area (Table 4). 26 • • Five-Year Review Geigy Chemical Co,p. (Aberdeen Plant), Aberdeen, NC As a result of the downgradient investigations required by the ROD, and with the adoption of the ESD in 1998, it was determined that trichloroethene (TCE) was not a site related contaminant. As a result, monitoring and the downgradient groundwater clean-up standard for TCE was removed from the downgradient monitored natural attenuation remedy (Table 4). However, the ESD did not remove TCE from the groundwater remediation levels (performance standards) for the Geigy Site as listed in Table 3. Table 9 presents the data for monitoring wells that have been tested for TCE during the 1991 -2002 time period. Other wells in the monitoring program for the site have not been monitored for TCE levels and are not included in Table 9. Table 9. Trichloroethene (TCE) Concentrations in Groundwater Monitoring Wells 1991 to 2002 Trichloroethene (TCE) Concentrations in Groundwater Monitoring Wells 1991 -2002 ·-.-~ti\(,."/. ·1. ;·surfiCial A'riuirer ..::;.: :'..1.!1 ::;.~ '..;_·_ TCE Concentration Well DATE (µg/L) MWIOS 7/10/199! ND (!0\ MW-10S 12/3/1996 ND (5) MW-10S 4/16/1997 ND(5\ MW-10S 7/15/1997 ND(5) MW-10S 10/1/1997 NDtS\ MW-10S 4/21/1998 NDm MW-10S 10n91199s ND(I) MW-10S 10/14/1999 NDf]) MW-10S 10/13/2000 ND(!) MW-10S 10/11/2001 ND(I) MW-10S 10/23/2002 ND fl\ · .. :c'":1 ' ·,_ · .·f.".;,· · · ': '· ,:~ ~' ,. :: ;~".' :s·· ;:·,., ·•~ ... · ~·-,, ,,, MW-16S 12/3/1996 ND (5) MW-16S 4/!6/1997 NDtS\ MW-16S 7/14/1997 ND(5) MW-16S 10/1/1997 ND/5) MW-16S 4/21/1998 NDm MW-16S 10/29/1998 ND(l) MW-16S 10/14/1999 ND<l\ MW-16S 10/13/2000 ND (5) MW-16S 10/11/2001 ND (I) MW-16S 10/22/2002 ND(l) •t1: ,.}{~,!:c ::-1~.i/l;:>k~\r;:'.~(;'.Wit:%'"'.:·•i :,1 ·:1:,:ii~'.:': '1" MW-17S 12/3/1996 ND IS\ MW-17S 4/16/1997 ND(5) MW-17S 7/14/1997 ND(5) MW-17S 10/1/1997 1.1 MW-17S 4/21/1998 ND IS) MW-17S 10/29/1998 }.TI)(!) MW-17S 10/14/1999 ND(l) MW-17S 10/13/2000 ND(J) MW-17S 10/! 1/2001 ND(l) MW-17S 10/24/2002 ND/\\ :,. ,t::i ~;~·i,'j-~t)E•!'),\ t!t,:7ff'':.;;:~~t · ,,,,"~ .,,r: .. ,. MW-18S 12/3/1996 ND (5) MW-18S 4/16/1997 ND(S\ MW-18S 7/15/1997 ND(5) MW-18S 1011/1997 0.66 MW-18S 4/21/1998 ND (5\ MW-18S 10/29/1998 ND (I) MW0J8S 10/14/1999 ND(l) MW-18S 10/13/2000 ND(I) MW-18S 10/1112001 ND(I) MW-18S 10123/2002 ND (I) L:l. -.· .:r .,U iller Black Creek Arlllifer·\;', : ... : -.!! ~-· TCE Concentration Well DATE (µg/L) MW-16D 2/9/1994 200 MW-\6D 12/2/1996 230 MW-16D 4/16/1997 280 MW-16D 7/1411997 250 MW-16D 10/1/1997 260 MW-16D 4/21/1998 290 :-..1W-16D 10/29/1998 270 MW-16D 2/4/2000 290 MW-16D 10/1312000 E (260) MW-16D 10/10/2001 190 MW-16D l0/24/2002 160 A;c: ··•~--F··:; 1' ::!. .,_;.., :~ .' ,. ·V ,,':_::--~,,·:i ·, . MW-17D 2/9/1994 180 MW-17D 1212/1996 320 MW-170 4/16/1997 190 MW-170 7/14/1997 370 MW-17D 10/1/1997 350 MW-170 4/21/1998 320 MW-170 10/29/1998 350 MW-170 2/4/2000 330 MW-170 10/13/2000 290 MW-17D 10/24/2002 290 : ·-::~;.;:y•:,: · i;-.f:::i-,;;;;:t-· r,:41;:~J~i~E ·.t :i.~•l'-U:' :· .:~nir•~J'\ "1til ·''· ~i1:J.' MW-ISD 1/26/1994 ND(3) MW-18D 8/18/199S ND/I\ MW-18D 12/3/1996 ND (5) MW-ISD 4/16/1997 ND/5) MW-ISD 7/14/1997 1.3 MW-lBD 10/1/1997 1.6 MW-ISD 4/2l/l998 6.2 MW-18D J0/29/1998 4.2 MW-18D 10/14/1999 20 MW-IBD 10/14/2000 29 MW-18D 10/10/2001 46 MW-18D 10/22/2002 71 •:·:;~.i ..;':.J-,;.,-:1:..~1.;F;:i~·~t,:::·E:;5 3 i\~'. '.;r,•111. !.'''!~;··-::~:_;_;·. MW-30D ]0/14/2000 43 MW-30D 10/22/2002 66 Note: Values in µg/L, ND=-Non-detect. E-= Estimated value above instrument linear calibration range. Actual detection. 27 • Five-Year Review Geigy Chemical Co,p. (Aberdeen Plant), Aberdeen, NC TCE concentrations at wells MW-l 6D and MW-l 7D, which are at the eastern edge of the site area, are consistently two orders of magnitude (100 times) greater than the 2.8 µg/L performance standard. MW-l 8D, at the western edge of the area where groundwater is being extracted, consistently has TCE concentrations at one order of magnitude (10 times) the 2.8 ftg/L performance standard. The trend at MW-l 8D is one where TCE concentrations are increasing over time. Surficial aquifer monitoring wells, MW-l0S, MW-16S, MW-l 7S and MW-18S do not exhibit TCE concentrations above the performance standard. VIII. ASSESSMENT To assess the effectiveness of the remedy at the Geigy Chemical Corporation (Aberdeen Plant) Site, three basic questions are answered and discussed below: Question A: ls the remedy functioning as i11te11ded by the decision documents? For the Geigy Chemical Corp. (Aberdeen Plant) Site, the remedy for soil (source) contamination was completed in 1996, with the conclusion of soil and debris removal. Based on a final inspection of the site by EPA and the State ofNorth Carolina Division ofSuperfund in 1998, the soil contaminant level goals established in the ROD and RD have been met and no further soil remediation is required. The groundwater pump-and-treat system was placed on-line in January 1997 and has operated continuously since. The groundwater contamination trends attributable to the pump- and-treat remedy for the surficial and Upper Black Creek aquifers appear to be downward. The trends of contaminant concentrations in the downgradient groundwater are difficult to discern because of the low levels of contaminants present. At present, the monitoring data show that contaminant concentration levels of TCL compounds are consistently above performance level goals. Question B: Are the assumptions used at the time of the remedy selection still valid? The alternatives presented to address groundwater and soil contamination in the ROD, were originally evaluated using criteria set in the NCP, 40 CFR §300.430 (e)(9). The criteria are described below. Threshold Criteria 1. Overall Protection of Human Health and the Environment addresses how an alternative as a whole will protect human health and the environment. This includes an assessment of how the public health and the environment risks are properly eliminated, reduced, or controlled through treatment, engineering controls, or controls placed on the property to restrict access and (future) development. Deed restrictions are examples of controls to restrict development. 28 • • Five-Year Review Geigy Chemical Corp. (Aberdeen Plant), Aberdeen, NC 2. Compliance with Applicable or Relevant and Appropriate Requirements (ARARs) addresses whether or not a remedy complies with all state and federal environmental and public health laws and requirements that apply or are relevant and appropriate to the conditions and cleanup options at a specific site. If an ARAR cannot be met, the analysis of the alternative must provide the grounds for invoking a statutory waiver. Primary Balancing Criteria 3. Long-term Effectiveness and Permanence refers to the ability ofan alternative to maintain reliable protection of human health and the environment over time once the cleanup goals have been met. 4. Reduction of Toxicity, Mobility; or Volume are the three principal measures of the overall performance ofan alternative. The 1986 amendments to the Superfund statute emphasize that, whenever possible, EPA should select a remedy that uses a treatment process to permanently reduce the level of toxicity of contaminants at the site; the spread of contaminants away from the source of the contaminants; and the volume, or amount, or contamination at the site. 5. Short-term Effectiveness refers to the likelihood of adverse impacts on human health or the environment that may be posed during construction and implementation of an alternative until cleanup goals are achieved. 6. Implementability refers to the technical and administrative feasibility of an alternative, including the availability of materials and services needed to implement the alternative. 7. Cost includes the capital (up-front) cost of implementing an alternative, as well as the cost of operating and maintaining the alternative over the long-tern1, and the net present worth of both the capital and operation and maintenance costs. Modifying Criteria 8. State Acceptance addresses whether, based on its review of the Rl/FS and Proposed Plan, the State concurs with, opposes, or has no comments on the alternative EPA is proposing as the remedy for the site. 9. Community Acceptance addresses whether the public concurs with EPA's p,roposed plan. Community acceptance of this proposed plan will be evaluated based on comments received at the public meetings and during the public comment pe"riod. The evaluation criteria relate to the requirements of Section 121 ofCERCLA, 42 USC §9621, which determine the overall feasibility and acceptability of the remedy. Threshold criteria must be satisfied in order for a remedy to be eligible for selection. Primary balancing criteria are used to weigh major trade-offs· between remedies. State and community acceptance are modifying criteria formally taken into account after public comment is received on the 29 • • Five• Year Review Gei!)I Chemical Co,p. (Aberdeen Plant), Aberdeen, NC proposed plan. Table 10 summarizes the alternatives evaluated and discussion of the potential remedial alternatives to address soil and groundwater follow. Table 10. Remedial Alternative Summary Remedial Action Total Present Worth Costs (1992) Groundwater Alternative I A No Action $140,000 Alternative 1 B Long-term Monitoring of $1,630,000 Groundwater Alternative 2 Slurrv Wall and Cap $10,200,000 Alternative 3 Groundwater Extraction for $2,210,000 Remediation Levels; Carbon Adsorption; Discharge to POTW Soil Alternative I No Action $140,000 Alternative 2 Off-site Disposal Total Landfilling $600,000 Total Incineration $2,440,000 Alternative 3 Capping $275,000 Alternative 4 On-Site Thermal Desorption $700,000 Alternative 5 On-Site Incineration $1,327,100 · Ground Water Remediation The following alternatives were subjected to detailed analysis for groundwater remediation: Alternative lA: Alternative 1 B: Alternative 2: Alternative 3: No Action Long-term Monitoring of Groundwater Slurry Wall and Cap Groundwater Recovery and Treatment to Attain Remediation Levels Overall Protection o[Huma11 Health and the Environment Groundwater poses no risks to human health under current conditions. Under the future use condition the no action alternative would not address pesticide levels in groundwater and therefore would not be protective of human health. Alternative 2 would attain the remediation goals by containing groundwater in the uppermost aquifer and recovering groundwater in the second uppermost aquifer. Alternative 3 would attain the remediation goals by recovering 30 • • Five-Year Review Geigy Chemical Corp. (Aberdeen Plant), Aberdeen, NC groundwater in the uppermost and second uppermost aquifer. Therefore, Alternatives 2 and 3 would be protective of human health and the environment. Compliance With ARARs The no action alternative would not comply with ARARs. Alternative 2 would attain remediation levels outside of the slurry wall in the second uppermost aquifer and prevent · remediation levels from being exceeded off-site in the uppermost aquifer. Alternative 3 would · attain remediation levels in both aquifers. The cap in Alternative 2 would be designed to conform to RCRA performance standards. Construction of the groundwater re·covery, treatment and discharge systems for Alternatives 2 and 3 would satisfy action-specific ARARs. Discharge to an on-site infiltration gallery would comply with the substantive aspects of a NC Non- Discharge Permit. Long-term Effectiveness and Permanence Pesticide levels would decrease permanently through recovery outside of the slurry wall for Alternative 2 and in both aquifers in Alternative 3. Construction of a slurry wall under Alternative 2 would be complicated by the depths to the uppermost aquitard (up to 70 feet). The competence of the resulting connection would be verified through hydraulic and analytical monitoring of groundwater. Carbon adsorption is considered Best Available Treatment for pesticides in groundwater. Alternative 2 would be a permanent installation that would require review and maintenance indefinitely. Alternative 3 would be discontinued once the remediation levels were achieved. Reduction o(Toxicity. Mobility, and Volume Alternative 2 would reduce the mobility of pesticides in the uppermost aquifer through containment and reduce the volume of pesticides in the second uppermost aquifer through recovery. Alternative 3 would reduce the volume of pesticides in both aquifers through recovery and treatment and comply with the statutory preference for alternatives involving treatment. Short-term Effectiveness All of the alternatives can be implemented without significant risks to the community or on-site workers and without adverse environmental impacts. Construction schedules would be as follows: Alternative IA-None; Alternative 1B-I month; Alternative 2-8 months; and Alternative 3 - 3 months. Construction of Alternative 2 could not proceed until the rail line was rerouted, a potentially significant obstacle on an institutional basis. Implementability Alternatives I A, I B, and 3 would not pose significant concerns regarding implementation. Construction of the slurry wall for Alternative 2 would approach the limits of technical feasibility due to the required depths (up to 70 feet). Design of the treatment system for Alternatives 2 and 3 could not be conducted until discharge requirements were defined. 31 • • Five-Year Review Geigy Chemical Corp. (Aberdeen Plant), Aberdeen, NC Total present worth costs (1992) for the groundwater alternatives are presented in Table 10. Soil Remediation The following alternatives were developed for Site soils and were subjected to detailed analysis: Alternative I: Alternative 2: Alternative 3: Alternative 4: Alternative 5: No Action Off-Site Disposal Capping On-Site Thermal Desorption On-Site Incineration The evaluation of these alternatives is summarized below. Overall Protection o(Human Health and the Environment Potential risks due to Site soils under current and potential future conditions (residential scenario) are within the acceptable range ofrisk specified by the National Contingency Plan (NCP). Compliance with ARARs There are no Federal or State ARARs for pesticides in soils. Alternative 2 would comply with EPA's off-site policy and applicable land disposal restrictions. Alternative 3, consolidation of site soils and capping in place would not trigger any RCRA requirements. Alternatives 4 and 5 would comply with all applicable ARARs, including LDRs. Long-term Effectiveness and Permanence Alternative I would not be effective in reducing contaminant levels. Alternatives 2 and 4 would result in a permanent reduction in site risks. Alternative 3 could be effective in the long- term through regular maintenance of the cap, but a review of remedy would be required every five years since a cap is not considered a permanent remedy. Alternatives 4 and 5 would maintain reliable protection of human health and the environment over time once the remediation levels were achieved. 32 • Reduction o(Toxicity. Mobility. and Volume • Five-Year Review Geigy Chemical Co,p. (Aberdeen Plant), Aberdeen, NC Pesticide levels would remain unchanged for Alternative 1. Alternatives 2, 4 and 5 would reduce pesticide levels significantly. Alternative 3 would not reduce the volume, but would reduce the mobility and effective toxicity of the pesticides. Short-term Effectiveness All of the alternatives can be implemented without significant risks to on-site workers or the community and without adverse environmental impacts. Implementability No implementation is needed for the no action alternative. Off-site disposal to a RCRA- approved landfill and incinerator have been conducted successfully in the past at the Geigy Site. Construction of the cap would pose no significant difficulties. Alternatives 4 and 5 are implementable, however the low volume of contaminated soils requiring remediation renders these alternatives impractical at this site. Cost Total present worth costs (1992) for the soil remediation alternatives are presented in Table 10. Modifvi11g Criteria State and community acceptance are modifying criteria that were considered in selecting the remedial action. State Acceptance The State of North Carolina concurred with the selected remedy. Community Acceptance A proposed plan fact sheet was released to the public on March 26, 1992. The proposed plan public meeting was held on March 31, 1992. The public comment period on the proposed plan was held from March 26, 1992 to May 25, 1992. The letters, comments, and questions asked during the March 31st meeting and received during the comment period were attached to the ROD as a Responsiveness Summary. With the completion of the Downgradient Groundwater Remedial Action Work Plan in October 1997, the alternative of Monitored Natural Attenuation was implemented for the downgradient portion of the plume. The determination was based on the following factors: 33 • • Five-Year Review Geigy Ch,mim/ Co,p. (Aberdeen Plant), Aberdeen, NC o There were no receptors of untreated groundwater in the downgradient area. At the time there was one private well user in the area. All other residences and businesses are connected to the city water system. The private well had been sampled and the water was contaminated with pesticides. However, the PRPs installed a carbon filter on the well, and conducted periodic monitoring to ensure proper operation and maintenance. o The City of Aberdeen, by letter dated April 1997, informed EPA that the City would not install any municipal water supply wells in this downgradient area. o Groundwater discharge to surface water limits the further migration of the plume. Groundwater flow directions h~ve been identified to verify that the groundwater pesticide contamination plume is contained by the following creeks: McFarland's Branch, Aberdeen Creek, Ray's Mill Creek, and Trough Branch. • Pesticide concentrations in surface water do not currently pose a risk to human health or wildlife. The risk assessment for McFarland's Branch was updated based on the new sampling results and indicates that the risk associated with the downgradient plume is well below EPA's acceptable risk range of 104 to 10·6. • Groundwater modeling has shown that the concentrations of pesticides in this downgradient area will decrease in a time frame comparable to a pump-and-treat system. A groundwater flow model was used to simulate the perfonnance of six extraction wells in the downgradient plume area. The model was also used to estimate the extent and longevity of the groundwater plume under naturally-occurring conditions. The results of this modeling show that the plume would be remediated in 19 years under pump-and- treat conditions, and would be remediated in 25 years under natural conditions. The assumptions used for the remedy selection remain valid. The selection of extraction with activated carbon adsorption as the remedy for the surficial and Upper Black Creek aquifers is still valid as there have not been any changes to the assumptions made_ originally. The selection of monitored natural attenuation as the remedy for the downgradient area is still valid as conditions have not fundamentally changed. Based on the review, all appropriate measures and procedures were utilized at the time of the remedial action and continue to be in effect. Question C: Has any information come to light that could call into question the protectiveness of the remedy? Based on validated information provided in the documentation that was reviewed, there is no information to date that significantly questions the protectiveness of the remedy. Data collected since the conclusion of the source remedial action support the selection of extraction with treatment as the preferred method for groundwater remediation in the ROD. The data are also in support of selection of monitored natural attenuation as the preferred method of groundwater remediation in the downgradient area as selected in the ESD. The trends of contaminant concentrations in groundwater are generally downward. However, detections of 34 • • Five~Year Review Geigy Chemical Co,p. (Aberdeen Plant), Aberdeen, NC target contaminants are frequently in exceedance of performance standards for the site. Remedy implementation data to date provide no validated early indication ofpotential remedy failure. IX. ISSUES There are several problems or issues that have been identified during this review. Each is further discussed in the recommendations section of this report. 1. Fencing and signage for the site as proposed in the documents of record have not been installed. 2. Modification of the site Groundwater Remediation Discharge Permit to reflect actual number of recovery wells in use. 3. Extension of off-site trichloroethene (TCE) contaminant plume into site area and potential affects on remedy as implemented. Potential increases in TCE concentrations in the remedy and downgradient areas. X. RECOMMENDATIONS AND FOLLOW-UP ACTIONS The recommendations and follow-up actions associated with the issues found in this review are described below and are summarized in Table 9. Implementation of site fencing and signage as proposed in the Record of Decision should be analyzed. The proposal for fencing and signage was completed prior to remediation of the site soils. With removal of the contaminated soils, fencing the site may pose a greater public safety hazard than exists currently. It is recommended that EPA issue an ESD to eliminate the requirement for fencing and signage at the site. The current Groundwater Remediation Permit issued to the Site by the State does not reflect the treatment system as installed. The permit lists a total of five (5) recovery wells while the actual number of recovery wells in use is seven (7). As the current permit expires June 30, 2004, it is recommended that the PRPs update the information in the permit application for renewal. Change of the permit should only be editorial in nature and should not affect the operation or implementation of the treatment system. Extension of the off-site trichloroethene (TCE) contaminant plume into the site treatment area has been noted during ongoing monitoring of the remedy. The change-out period for activated carbon canisters has reduced from annually to semi-annually. Currently there are insufficient data to accurately predict whether the TCE plume will adversely affect the remedy as implemented or not. It is recommended that the EPA and State continue to pursue characterization of the source of the TCE and the PRPs continue their voluntary monitoring of wells in accordance with the Site Groundwater Remediation Permit. 35 • Five-Year Rtview Geigy Chemical Co,p. (Aberdeen P/a11t), Aberdeen, NC Table 11. Recommendations and Follow-up Actions i:-"~•"31Issiie(s)lr,i·,•: 1 ; RecOl11inelld8tiol1S/FollOW.--:, :· ;:rr;1i/t Party· ~'. •,i'.ii'lf .r~;,·Oversight"-.\•1 :' :-.1,Milcstone,Ji;~, ('''' Fono·w-iip· 1,,, '. .,'"i··r ..._ '; • .-.-.:"" ·; -.t<~•·,r,~, .-r -,r:,: 7'.{, 11 -~S:1r•.,,1>. ,'L '·,.,, ,.,. ;t~t Ag~·~'cY~fi\' ~.!'',''. it; ,; Date~ ~-:,,~-:~:-1 -~t; ); ··'· .-h ~ ·-.~•~ 11·1•1 :!£f,'1f{~(::\i,t~ , ': ~p· ;t''• up Actions c.'; • i~ti',"',J .·.1~1;Respons1ble;;:,-, ·. :·· Acti_ons_: 1Affec_tsj'.,, ·J,l" I l;-4-~-·' ,· ·-&J!"•';i.-1,; ,.,,., :f-·' f I •-"•• '~-.C~•'j"d'·••,ii • , .. r._ , •.·,tt.-.,,,,,.;i .. ,.,.,,,~,1, /ij:~(~{;~~t!~fo•e.~~!f ;' .. i-1tl',•:i"''"•i~tA··:r ''""''W'''f. 'l·"t,'il,,1 ,.1,ti,f;; ,\...r: [{I '''~t,:;•, :~J ;p'~ i:i :1,JJ,J."'i -~11;.J. ,,j :r,,"J~•· 'I.,··~ t;n~1·, ),;_, :.i ,-~ • l:\'1 ·,. r -,... ,,.,.,""-'.r,?4~·,'i:•·~ j';,: :;~ ~'::,~~~~~~i,::.~~il .'..~,f.,t\~~i~: :-:.:~/:\: i; '. ~:t\~:};., ·:.i$!'1;,,-'}~~~-, .~cft'. ~) . .i/-,/1?.:.·tll-::.:"1•.: '4.••_·,1·(Y/N) > _·,. Fencing and Fencing and signage should EPA EPA and State Before next N signage for the not be required as the site five-year review site 8.s proposed soils have been remediated. as required in the documents EPA should issue an ESD of record have to eliminate requirement for not been fencing and signage. imnlemented. Groundwater Update permit to reflect PRPs State Upon renewal N Remediation actual number of recovery of current Pennit docs not wells when renewed. permit-June cover all installed 30,2004 recoverv wells. Off-site Continued monitoring of PRP~ EPA and EPA and State Before next N trichloroethenc affect(s) on the site remedy. State five-year review contaminant or as required plume. XI. PROTECTIVENESS STATEMENTS The remedy at the Geigy Chemical Corp. (Aberdeen Plant) Site is expected to be or is protective of human health and the environment, and in the interim, exposure pathways that could result in unacceptable risks are being controlled. XII. NEXT REVIEW This is a site that requires five-year statutory reviews. EPA will conduct the next review within five years of the completion of this first five-year review report. The completion of this review as shown on the signature cover to this report is the trigger for the next five-year review. 36 • • Five-Year Review Geigy Chemical Co,p. (Aberdeen Pla11t), Aberdeen, NC ATTACHMENT 1 List of Documents Reviewed • • Five-Year Review Geigy Chemical Co,p. (Aberdeen Plant), Aberdeen, NC List of Documents Reviewed Geigy Chemical Corp. (Aberdeen Plant) Five-);' ear Review Rust Environment & Infrastructure. November 1993. Remedial Design Work Plan, Geigy Corporation Site, Aberdeen, North Carolina. Project No. 86619.200. Rust Environment & Infrastructure. November 1993. Sampling And Analysis Plan, Geigy Chemical Corporation Site, Aberdeen, North Carolina. Project No. 86619.210. Rust Environment & Infrastructure. February I 995. Downgradient Groundwater Investigation Work Plan, Geigy Chemical Corporation Site, Aberdeen, North Carolina. Rust Environment & Infrastructure. March I 996. Downgradient Investigation Data Summary Report, Geigy Chemical Corporation Site, Aberdeen, North Carolina. Volume I and 2. Project No. 33288.610. Rust Environment & Infrastructure. March 1996. Final Design Report, Geigy Chemical Corporation Site, Aberdeen, North Carolina. Project No. 86619.600. Rust Environment & Infrastructure. November 1997. Final Downgradient Groundwater Remedial Action Work Plan, Geigy Chemical Corporation Site, Aberdeen, North Carolina. Project No. 201165.10300. Sirrene Environmental Consultants. March I 6, 1992. Feasibility Study Report, Geigy Chemical . Corporation Site, Aberdeen, North Carolina. Sirrine Project No. G-1024.20. The Pinnacle Consulting Group. October 2001. Downgradient Remedy Summary Report, Geigy Chemical Corporation Site, Aberdeen, North Carolina. Project No. MAS0006l. The Potentially Responsible Parties (PRPs) for the Geigy Chemical Corporation Site. November, 1989. Remedial InvestigationJFeasibility Study Work Plan, Geigy Chemical Corporation Site, Aberdeen, North Carolina. Prepared by ERM-Southeast, Inc. The Potentially Responsible Parties (PRPs) for the Geigy Chemical Corporation Site. March 1992. Final Report -Remedial Investigation Study, Geigy Chemical Corporation Site, Aberdeen, North Carolina. Prepared by ERM-Southeast, Inc. U.S. Environmental Protection Agency, Waste Management Division. May I, 1989. Initial Soil Removal Report Task IO -RI/FS, Geigy Chemical Corp. Site, Aberdeen, North Carolina. Prepared by the Potentially Responsible Parties (PRPs) for the Geigy Chemical Corp. Site. U.S. Environmental Protection Agency, Region IV. March 24, 1992. Geigy Chemical Corp. Site NPL Site Administrative Record, Index and Volume I through 7. • ·• Five-Year Review Geigy Chemical Co,p. (Aberdeen Plant), Aberdeen, NC U.S. Environmental Protection Agency, Region IV. August 27, 1992. Record of Decision; Summary of Remedial Alternative Selection; Geigy Chemical Corporation Site, Aberdeen, Moore County, North Carolina. U.S. Environmental Protection Agency, Region IV. January 23, 1998. Explanation of Significant Differences to the Remedial Action, Geigy Chemical Corporation Site, Aberdeen, Moore County, North Carolina. U.S. Environmenial Protection Agency, Region IV. February 6, 1998. Geigy Chemical Corp. (Aberdeen Plant) Site (Explanation of Significant Differences) NPL Site Administrative Record, Index and Volume 1 through 3. U.S. Environmental Protection Agency, Region IV. July 21, 1998. Superfund Preliminary Close-Out Report, Geigy Chemical Corporation NPL Site, Aberdeen, North Carolina. • Five-Year &view Gei!!JI Chemfral Ci,p. (Aberdeen Pla111), Aberdeen, NC ATTACHMENT 2 Photos of Extraction System Installations All photos taken by Stacy Samuelson during Site visit February 18, 2003 • • • • Extraction well PW-3S 2 • • Controller box/panel for extraction well 3 • • View of extraction wells PW-2S and P\V-1 S from well PW-3S 4 • • rl ,' ' I.,· . i View of carbon adsorption canister banks 5 • Attachment 3 • Five-Year &view Gei!J Chemical Corp. (Aberdeen Plant), Aberdeen, NC Upper Black Creek Aquifer Extraction Well Capture Zones Close-Up: Min Q and Drawdown Contours EARTH©TECH A tyca INTERNA710NAL L7D. COMPANY , ;'..• ·-=-o·•!:· ,.- I Figure5 Geigy Site, North Carolina September 2003 • • Close-Up: Avg Q and Drawdown Contours 0 (J1 0 Figun, 8 EARTH@TECH A "tqr:::D INTFRNADONAL LTD. COMPANY Geigy Site, North Carolina Scptcrnbcr 2003 • Close-Up: Max Q and Drawdown Contours / > ,• / gi· . , . / ' / . lf'F~i~',cl'1~::S--.j.:t--../-~ . ., .// I ~'-.. ,.~ -. EARTH@TECH A 'tqca JNTERNAT10NAL LTD. COMA6.NY Figure 11 Geigy Siti:. North Carolina Septc:mbcr 2003 • • Attachment 4 • Five-Year Review Geigy Chemical Corp. (Aberdeen Plant), Aberdeen, NC Surficial Aquifer Graphs i • ·g i i 0 i ' i • 0 " " " " ,, " ,0 '" " " " ,, " ,0 • -•lpha-BHC -b•t1-BHC 1-d11!1-BHC -c;,-g1mm1-BHC M W-4S • Five-Year Review Geigy Chemical Corp. (Aberdeen Plant), Aberdeen, NC Mar-112 Mer-113 Mor-114 Mar-115 Mar-116 M ■r-117 M ■r-116 Mir-1111 Mar-00 Mar-01 Mar-02 Mar-03 MW-llS -•lph1-BHC -D&t1-8HC -dtU1-BHC -g•mma-BHC Mor-92 Mar-113 M ■r-114 Mar-95 Mar-116 Mtr-117 Mar-DB Mar-1111 M11-00 Mar-01 M u-02 M 11-03 '"~------------------------------------------------~ M W-6S " ,0 M or-81 Mor-9~ M ar-115 Mor-116 Mor-97 Id ■ r-116 1-">"•·0" C -b■tl•BHC -doll1-6HC -g•mmo•BHC Mor-119 Mor-00 Mar-01 MI r-03 ,0 ~ ,, • I ! ' ,, 0 • • Five~Year Review Geigy Chemical Corp. (Aberdeen Plant), Aberdeen, NC --1lph1-BHC -ID-bttt-BHC ~dlltt-BHC --g1mm1-BHC Attachment 5 • Five•Year Review Geigy Chemical Corp. (Aberdeen Plant), Aberdeen, NC Upper Black Creek Aquifer Graphs ,:1 / • • " " " " i ,0 I 1 u Jun•91 Jun•93 " -•lpho•BHC " -111-boll•BHC -d11l1-8HC -g1mm1-BKC " " i ,0 i 1 u Mu-95 ' .• ' . ,., 1 " ' ; J ... o., ... o., ~ u .,.11s MW -11 D Jun-94 MW -180 Mar-97 Mu-99 M W-19D l-1lph1-BHC !:-bet1-BHC I -delt1°8HC -Q-gam m 1-BHC . M ■r-98 • Five-Year Review Geigy Chemical Corp. (Aberdeen Plant), Aberdeen, NC Jun-01 Jun-02 ......, ...... .,., Mot-O1 Mu-03 M .,.01 M or-0 2 • Five-Year Review Geigy Chemical Corp. (Aberdeen Plant), Aberdeen, NC MW -20D -•lptia•BHC U f---<>---------------------------------------,-1il-bo1a-BHC -dtlt1-BHC " 1---,,,__ _ _,.,,,__ ________________________________ _.,-==•••em!!.Cmc•.::·'c"cocc_, ' ' , .. Mar-95 M 11-DO Mu-98 M 11-00 M ar-0 \ MW -2 2 D -•lpti1-0HC I----------------------------------------{--b•t•·DHC -d•1t1-BHC -a-;1mm1-BHC " M■r-03 i 1.2 +--------------------------------------------------1 1 1 0 o.a 0 ' , .. ,., l--------------------------------------....::::,,a,_-1 ' .. M ■r-98 M • ,.;g M er-00 Mu-02 M ar-0 3 MW-230 f--------------11=:=~~t:\~ H/ lf--------------------------------1 l-d1lt1-8HC I l--g1mm1·BHC u+.-------------------------------------------------1 o., , .. • • ... l!I ... MI r-97 M. ,.ea M or-89 Id• r•OO M 1,-0 1 MI r-02 ,.. ,.. u i " ' l , .. 0 , .. "' ,., Mar-95 " u " j " 1 i ~ "' , .. ,., ,., u " ' ' i " ~ I , .. 0 ,., '' ' ' - M ar-QS • I MW-240 1-■lph ■-SHC -bete-BHC 1-d•lta-BHC 1 -e>-oam m ■-BHC MI r,Q7 M u-98 I MW-250 l~•lph■-BHC -a-boto-BHC 1:--d ■lta-BHC I -11 ■mm,-BHC .,,_ M ir-117 M W-2 6 D _._,tph1-BHC -b■ll·BHC -dolt1-BHC -~111mm1-BHC - M _,.ge Mtr-118 M 11-119 . . . - Five-Year Review Geigy Chemical Corp. (Aberdeen Plant), Aberdeen, NC ~ . M ar-00 Mu-01 M ■r-02 . . . ~ M u-0 0 . - Mu-00 M ■r•0 1 Mu-02 M ■r-03 • " -alpha-BHC " . -beta-BHC -delt•·BHC --g•mm ■-BHC " " :;; ! 1 ,, • ! i 0 &--6-e-e-..;:::: M ar-96 MI r-i7 Mar-98 1-•lpha-BHC I ,.. l:b•II-BHC I --dllll-BHC --gamma-BHC ... ' • i u ~ ~ i 8 .. , "·' "·' .. , M u-90 M u-99 --•l~U·BHC I " 1---~•10-BHC I -00111-BHC ..,._..,mmo·BHC ,., . ... .. , - Mot-lH MW-JO D M er-9Q Mar-00 MW-340 - - MW-35D ~-"'-'=: M or-00 • Five-Year Review Geigy Chemical Corp. (Aberdeen Plant), Aberdeen, NC a....,----/ M • r-01 Mt r-02 M ar-03 ---Cll -- M ar-0 0 M lf•O 1 ' .,___ - M or-01 M • r-02 MI r-03 • Attachment 6 • Five-Year Review Geigy Chemical Co1p. (Aberdeen Plant), Aberdeen, NC Lower Black Creek Aquifer Graphs • " --+-alpha-BHC MW-22L --m-beta-BHC " -.-delta-BHC ~ gamma-BHC " 6 ,/I'-,• -, ~ - Mar-95 Mar-97 M■r-99 -alpht-B~ MW-25L -b•II-BHC " _..,__BHC -gorm11-BHC " . , . = = -----" -ff • Five-Year Review Geigy Chemical Corp. (Aberdeen Plant), Aberdeen, NC . -"-:,_ Mor-00 Mar-01 . . -._ . ;:~ A . ..... , ~ .0'~"--6 -- M.lr-01 •• r------------------------------------------------~ " i . -•lph1-BHC -ID-b1!1-BHC 1--------~-dolta-BHC -o-g1mm1-BHC MW•27L I •-~✓._?~_=-_-_-_-_-_-_-y=:::~;:::::::;.;:-\--, Mo r-95 M o,-90 Mar-00 M or-01 M ar-01 Mor-03 • " 1--•lp>o,BHC I -~••••·BHC _d,lta-BHC -g•m.,, • • B H C I ,. i I ... ,.g 7 ,. --+-otpt,o,BHC --·8HC " -do!UI-BHC --++-gan1rN1-BHC 'C " "w •?IL MW-31L ~. t>,....,. r. ',V // " " . . ~ --- MW .. l C • Five-Year Review Geigy Chemical Corp. (Aberdeen Plant), Aberdeen, NC M • r-0 0 ~-, , ~ -----. -. -~ Mlr--01 " " " i I i I ' . ,, .. , " " '" Mor-97 • I-"•"'·'"' I --.. lo-lHC .. , ...... ..... -::; -•lphe-BHC -0-oota-BHC d1lt1-BHC Dl:IO.-gam mo•B HC MW-JBL • Five-Year Review Geigy Chemical Corp. (Aberdeen Plant), Aberdeen, NC .r,,,11,BJ-Cfil,@],0=,~-@'l@]-~GJ-rio ---" '" Mer-96 Mor-99 Mar-00 Mar-01 M ar-0'2 M or-0~ " i I " i l " • 1:•lo~o-SHC I -~0011-!HC -•0111-!HC 1--oommo•!HC • " . •Ill • Five-Year Review Geigy Chemical Corp. (Aberdeen Plant), Aberdeen, NC c:::i>-t=il-CS>•C3J-~c:il-'3>•Ci)-E3J.•Cal-CSJ. CS)-G- M o r•I I ,. .,.,, u ... o 0 ".,.o, " . -•Ol 1-■lpno,UHC' I -••<o-BHC -d•lto-BHC 1-o•mmO•BHC • ~ /4 / --~ - II or· 0 1 M o r-0 2 • Attachment 7 • Five-Year Review Geigy Chemical Corp. (Aberdeen Plant), Aberdeen, NC Surface Water Sampling Graphs O.H .. , i 0.01 i 0,01 o.o, - 0 .,.11, 0.1 4 0.1 2 0.' i 0.08 i 1 0.08 u 0.0~ 0,02 Mor-95 0.14 0. 1 2 0.' i ,. 0.08 ' ; ! o.oe i u o.o, 0.02 MI r-95 1~•lpha-BHC --b•ta-6HC I 1:::~:~•~B•~~HC I SW -1 Mc F ■ rla n d 't Branch • Five-Year Review Geigy Chemical Co,p. (Aberdeen Plant), Aberdeen, NC ,~vc-v -"' = ,. u-91 Jul-91 Ooo-U ~,,.o, S •o·Ol Joo•O• SW ·2 -•lpha-BHC McF ■rl1nd'1 Branch --•11-BHC -d1ll1-BHC -g•mma-BHC M 11-91 MI r-97 M lt•98 MI r-99 Mu-00 M ar-0 1 M u-02 MI r-03 SW-3 -alpha-BHC McFarland's Branch --beta-BHC -delta-BHC -gamma-BHC "' M ar-96 Mar-97 M ar-98 Ma r-99 M ar-00 M ar-01 Mar-02 M 11-03 • 0 ., • -•lpha-BHC -·•"·BHC 0 .1 2 -f----------j-do In ·8 H C --g,mffl ■•BHC .. '-• o .oe '.,;_· w o.o e M or•t7 0.1' 0.\ 2 1-•lpha-BHC I -••11-eKc .-d,111-BHC 1--g,mm ■•BHC I 0 ., i ~ 0 .06 1 ' ! 0.0B . " o.o~ "' 0.02 M ar-11~ M 1 •·116 0.14 -alpha-BHC -bet•-BHC o., 2 1------------,-d e lta -B H C -~gamma-BHC 0.' i .,_ o.oe . • a I 0.06 • u 0.04 0.02 Mar-95 Mtr-96 M ar-97 SW -4 Aberdeen Creek SW -& Aberdeen Creek • Five-Year Review Geigy Chemical Corp. (Aberdeen Plant), Aberdeen, NC ~~ MI r-86 M or-119 SW-6 Aberdeen Creek M u-02 Ma/·03 • • Five.Year Review Geigy Chemical Corp. (Aberdeen Plant), Aberdeen, NC 0.1 4 SW-7 -•lph1-BHC Aberdeen Creek -~•l■-BHC 0.1 2 -dol\1-BHC \-o-g1mm1•BHC 0.' ii: a o.o e " 1 1 0.08 u 0,04 0 .02 M • r-9~ Ma r-99 Mor-97 M ir-9 6 M ar-99 M ar-00 M ar-0 1 M ar-02 M or-03 0.1 4 SW -8 -■lpn1-BHC Aberdeen Cretk -bo\1-BHC O.t 2 -d•lt1-BHC --1mmo-6HC 0.' i 0,08 I 0,08 u o.o• 0.02 Mor-U M or-9 f Mar-97 Mar-98 MI r-98 M or-00 M or-0\ M ar-02 M ot-03 o.,. SW -9 0 .1? 1-•lpno,BHC I Ra y'1 M Ill C r11k -b•1•·8HC 1=:::•~•.\\c I 0, i 0,01 I 0 ,01 0.0 < m-G-Ci>-Cil-1:SJ-[Sl,-S-G)-ClJ--~-C!l C C C 0.02 ' ... ••··· • i i • ! u 0.1( 0.12 1:--•lpha-BHC I -b1t1·8HC -dolto-BHC 1-iE>-gommo•BHC I ' ' 0,08 o.oe 0.04 SW -10 Ray'• MIIICr11k Control Location • Five~ Year Review Geigy Chemical Corp. (Aberdeen Plant}, Aberdeen, NC G>-G>-C:l-G--m--ffi-m--e--e-s--G>-CSl 0.02 Jun-97 Jun-98 Jun-0O Jun-O1 o.,. ~---------------------,------------------------------7 SW-11-2 Ab1rd11n Creek 0. I ~ " -•lpn1-8HC --l>•la-BHC 1----------1-dolll -e H C _..,_ omm•-BHC =_; ~ o.oa +--------------------------------------------------1 i i w o.oe +--------------------------------------------------1 .i MI r-00 ;' Jun:;.l0-03 10:05am From-RCRA T-446 P.001/003 F-284QP TO: • ? ~ t .. ~p ~ &vf! e; L-<a..,'f ~~ FAX TRANSMISSION FROM: Diane Barrett, Community Involvement Coordinator U. $. Environmental Protection Agency, Region 4 Economic Redevelopment & Community Involvement Branch ·· 61 Forsyth Street, SW, 10th Floor Atlanta, GA 30303 Phone: 1-800-435-9233 (404) 562-8489 ! FAX# (404) 562-8566 ~}, flcffh,,,,) DATE, · ~-w-,3 Nt'D NfJ , J,a.;J0-03 10:06am From-RCRA .iance Section +404 562 8. T-446 P.002/003 F-284 Diane Barrett 05/07 /03 08:08 PM Jon & Giezelle, To: Jon Bornholm/R4/USEPA/US, Giezelle Bennett/R4/USEPA/US, cc: cc: Subject; Aberdeen In conducting 5-year review community interviews I spoke with Hugh T. Hambrick@ 910-944-7368. He retired from the CORP Savannah, GA office and is an entomologist and familiar witn pesticides and chemicals. He is very concerned about the quality of their city water which comes from the various wells in Aberdeen. There is a city well approximately 2000 feet from his propoerty which he thin Ks could be contaminated due to land use in the area. He was very informative regarding the Farm Chemical area as well as the area surrounding the Giegy Site_ I don't know if any of the information that he gave me will be relevant to either site - you can decided for yourself. If interested, please give him a call. -··-Geigy Site: Mr_ Hambrick lives at 540 Shelton Drive, approximately three blocks from the Site. There is a space of land (30 acres+) that for years was an active farm that grew row crops. The gentleman that owned the land said that the used all kinds of chemicals on crops for years_ The land has in recent years been sold to A.P. Johnson who is in the process of developing the land into a subdivision. This property is bounded by Highway 211 on the south, Devonshire on the north, and the land extends to a wood line approx_ 200 feet from Mr_ Hambrick's pro'perty on the west. Mr. Hambrick's concern was that since this 30+ acres was a very active farm that used pesticides and other chemicals, could these chemicals be impacting the Geigy site or other groundwater aquifer areas? Since the state is trying to locate the origin/source of the TCE plume, could this 30 acres be a source area? The source could be the Crestline area, the metal company, or the asphalt plant. Aberdeen Pesticide, Farm Chemicals Site: Mr. Ham[:>rick in 1984 was considering purchasing the old 8-acre Page house and property which is behind Farm Chemical. He told me that there was a small airport & airstrip that would have been between the Farm Chemical Site and the Page property_ He seemed to have knowledge of past activities in the area behind Farm Chemical and the small industrial park area as well as a residential well next to the Twin Area. I wanted to give you two this information in the event it could have an impact on eitner or both sites. · Diane , J,neJ0-03 IO: 06am From-RCRA • anco Section +404 562 85. T-446 P.003/003 F-284 Michael Sheehan <msheehan@pinrongr p.com> To: Diane Barrett/R4/USEPA/US@EPA cc: Ray Horn <rjhom@corp.olin.com>, Harold Moats <harold.moats@syngenta.com>, Jon Bomholm/R4/USEPA/US@EPA 05/19/03 03:38 PM Please respond to msheehan Subjec;t Geigy Site • Telephone conversation with Matt Davis Diane: Ray Horn of Olin Corporation and Harold Moats of Syngenta Crop Protection asked me to contact Matt Davis, a near neighbor of the Geigy Site, following his recent comnrunication with you. I spoke with Matt today regarding the following items: 1. Site groundwater remediation. Matt simply wanted to know how progress on clean up of Site groundwater was proceeding. I told him that pesticide concentrations in Site groundwater were declining and that the extraction / treatment system had performed very well to date. Matt asked if the timeframe for Site clean up was snll on the order of20 years and I confirmed that under present circumstances, this would likely be the case. 2. Surrounding land use. Matt mentioned that some property immediately east of the Geigy Site treatment building was for sale and may be logged / developed as residential properties. He wanted to know if residential development of the properties, including the installation of multiple septic systeins, would affect our remedy. This issue has come up before and l told Matt that the construction of septic systems upg:radient of the Geigy Site would likely not have an adverse impact on the remedy. Matt is aware of the TCE site just upgradient of the Geigy Site, and that a TCE plume extends under the potential residential development. I told Matt that NCDENR and EPA are aware of the TCE plume and that future response actions to address that matter may or may not impact development of the property. Mart has been at his present home, located at the end of Domino Drive, for many years now. I believe he has enjoyed being surrounded by woods and simply wishes to maintain status quo. He did not express any concerns about the Geigy Site and seemed to appreciate the update. Call me if you have any questions. Regards, Michael A. Sheehan The Pinnacle Consulting Group, Inc. Suite200-8 200 East Camperdown Way Greenville, SC 29601 Office: 864.467.0811, ext. II 7 Cell: 864. 787.8162 ' Jun-10-03 09:58am From-RCRA iance Section +404 562 8 T-445 P.001 '----- • • f ~ 5"-1· ~ _,_ R~'-h -e..w . -?}j ~ .. ~ '<" ~ -o-'<--"~L PR01Jf'"' G-~ ~ c_.,~~'\.\CA\ S::ft'e-.> Pv-·bk-c :t=-\1\·,~~ ~ "j V / FAX TRANSMISSION FROM: by E-PA- Diane Barrett, Community Involvement Coordinator U. S. Environmental Protection Agency, Region 4 Economic Redevelopment & Community Involvement Branch -61 Forsyth Street, SW, 10th Floor Atlanta, GA 30303 Phone: 1-800-435-9233 (404) 562-8489 FAX # (404) 562-8566 TO: c ~-~ DATE: F 18; ;y.rtJ3 ;vc f" ;v f?-- Jun-10·03 09:58am From·RCRA .ianc, Section +404 562 8. 5-Year Review Questionnaire Site City/State Phone No. Date: -~---'-fi-=-(p ,,-.· -'-.)..{)=-ti~?., __ /rJa.u ;(: 'la(!, (},11 C l"'-' Name of Citizen Address How long have you lived near the Site? T-445 P 002 F-283 Are you familiar with EPA activities over the past years? ~.e.,, ~ ~ ~ t' f.u.,,,.., MfJ ~ y:;/4 Ct • Do you still have any concerns regarding EPA clean up activities of the Site~ L/a,41/4 ~pk· Over have you been pleased or displeased with EPA actions at this -'H.,_ -'--W+"Y t,.-~ Do you think you have been adequately informed about clean up activities at the Site? j,,;,) . Is there any information about the Site that you would like to share with us that would assist in our7):cevwsi~vit~ 1· Is there someone else that you would like to recommend we contact for more information? 6 Do you have any suggestions that EPA can implement to improve communication with the public? [A copy of the 5-year review will oe placed in the Site Information Repository file located in the Site lnfom,ation Repository at ________________________ _ 1nterv1ew conauctea by: ./ , A .,_;___,_,; ~ Date conducted : __ 01=-,,_l.,,,(,+/-"'6,,._2 ____ _ r I Jun-10·03 09:59am From·RCRA .ianc, Section +404 562 8. T-445 P.003/014 F-283 Site City/State Address 5-Year Review Questionnaire How long have you lived near the Site? . /,,;.,.J 1-4-u ~ M, m-a ,._,~ Are you familiar with EPA activities over the past years? ~ t!.LA-¾J) > -~~~~'-:izz~Tcr~~u~~~;Sj"---- Do you thin u have bee Is there any information about the Site that you would like to share with us that would assist in our Sff r review of site activities? @ , . _ . _ -#--¼ o -&-fl. ~ · #~ ~ 4ff?d 14P: or '/+4 '½4 Is there som ne else th_at you would like to d we contact for more information? ~ Do you have any suggestions that EPA can implement to improve communication with the public?,=:--,------------------------------ [A copy of the 5-year review will be placed in the Site Information Repository file located in the Site Information Repository at ________ ~---------------- Interview conducted by: tx'.i~._,, ~ Date conducted: S-/v (QJJ Jun-10·0! 09:59am From·RCRA ••nee Section +404 562 85. 5-Year Review Questionnaire Site City/State How long have you lived near the Site? Are you familiar with EPA activities over the past years? T-445 P.004/014 F-28! Do you still have any concerns regarding EPA clean up activities of the Site? 71t1YLL-'Pt:4!:~ Overal have you been pleased or displeased with EPA actions at this Site? ~ Do you think you have been adequately informed about clean up activities at the Site? ywl ~Yn-,!Pic: ~ ~qk{p ) Is there any information about the Site that you would like to share with us that would assist in our 5-year review of site activities? ~ '--Z]a-t: 4d•~ 1 ry omeone else that you would r e to recommend we contact for more information? ' ~ Do you have any suggestions that EPA can implement to improve communication with the pu~ d:1-i:bf¥if!!:!jtt ~~~:tr~~~~~ [A copy of the 5-year review will be placed in the Site Information Repository file located in the Stte Information Repository at ,£&ii, ,{. c: i 1tu::,. 7,.l, et Interview conducted by:! A~_,..)~- Date conducted : d: /f., /4,;o?: ~~-1-. -"-7-f-==-.,..,_ ___ _ Jun-10-03 09:59am From-RCRA .,nee Section +404 562 85. 5-Year Review Questionnaire Site ~ate Date: -~-~,,__,t'--,,'-' a-D_tJ_?i __ Name of Citizen Address T-445 P.005/014 F-283 /IJ/ f". ~ 11-. Do you live near the Site? If yes, how long? ---'?{_,._,_A-~--------------- Are you familiar with EPA activities over the past years? _...:a;~;iafir.oir2:r:'.=------------- ~</ w--v.-/ '?ryf nllf":'-e.J-4/e£.e What is your overall impression of the project? qri:" been pleased or displeased ~ith cleanup aC\ions at this Site? • Do you still have any concerns regarding EPA clean up activities of the Site? " -. ~ • Are you aware of any events, incidents, or activities at the site such as vandalism, trespassing, or em~ ency responses from local authorities? If so, please give details. __________ _ Is t ere someone else that you would like to recommend we contact for more information? fu..- Interview conducted by; :A~ ~ Date conducted : --'s;J.+z-"~r-Z-"03..,_ ____ _ Jun-I 0-03 10:00am From-RCRA .iance Section +404 562 8. Site City/State 5-Year Review Questionnaire. J. c~~ ~ . zttt~. Y). I?_. ;LJ-217 T-445 P.006/014 F-283 Date: ~ /4, J-4 o3 • Phone No. (o/frJ J 9#-(6 03 . , Name of Citizen L/ad.±t· ~ Address ~,~ How long have you lived near the Site? ,3fr~ ,:fr,..., ,tu.,r,,Ju ~ a,,,) £.tz:, Are you familiar with EPA activities over the past years? -"~~p_..,_)=:._ _______ _ Do yo · · · up activities of tt\e. Site? u 0} 7¾. Do you t ink you have been adequately informed about clean up activities at the Site? Is there any information about the Site that you would like to share with us that would assist in our 5-ear review of site activities? {Jl'--4~~'4-f!::.~~~-#:f:;~2.;fl...4,~~~=,-:::4!:.U....d&.'.:.Lk~~~e__.,,"7 . au_ ~-recommend we contact for more information? Do you have any suggestions that EPA can implement to improve communication with the public? ----r-r----,---,---:,----,-------------,..----.,------- c> -,,_,._, d}t,, ~ ~ (JV~ (A py of the 5-year review will be placed in the Site Information Repository file located in the Site Information Repository at------------------------- lmerview conduc1ed Dy: &~ ~· Date conducted : S/<t IA 3 I I Jun-10-03 10:00am From-RCRA .ance Section +404 562 85. 5-Year Review Questionnaire Site City/State T-445 P.007/014 F-283 Address How long have you lived near the Site? 40 -· ~ ~ /XfUl,,,V !kW ~~ Are you familiar with EPA activities over the past years? Do vou still have any concerns regarding EPA clean up activities of the Site? Overall, have you been pleased or displeased with EPA actions at this Site? '::1M,,? li/fe« .. J ti Do you think you have been adequately informed about clean up activities at the Site? _ . ~ ~ ~ U ,,ful;;, 0me~ ~ ~ :i ~ n---tl 11 . . I O ' ~ Is there any information about the Site that you would like to share with us that would assist in / o,c ~,.,.,~,~ of siW actMties? #2 " ~ Al J.....,_, ~~~~~ ~ /(/4-'£ I) Is ther. . someone else that you would like to recommend we contact for more information? (} Do you have any suggestions that EPA can implement to improve communication with the public? ---------------,-----------,---~--~ 11° -~th ~ 'ldr ,;,.,, vd:s +~ 4 jun-10-03 10:01am From-RCRA .ianco Section +404 562 85._ T-445 p 008/014 F-283 5-Year Review Questionnaire for Contractor/Site Manager@ Site City/State ~ (}_~(lr- Date: /'))O:v' '4 c)o o 3 'VMH-4 ill o-d;;J . Name Phone No. µ;;,;,) Address tise current status of construction (i.e., budget, schedule) ,,;t-H ~ ~ 1, Have any problems been encountered which required, or will require, changes to this remedial design or this ROD? ie,~ c~ ~fJ~-c:w;U-~d-i«~; ~ 4~ ~ «r41 ,,_,_e_) ~ '-u,-d_,( A Cu~ w YoJe /u-1~ a.~. Have arl\i problems or difficulties been encountered which have impacted construction progress or implementability? · Do you have any comments, suggestions, or recommendations regarding the project (i.e., design, construction documents, constructability, management, regulatory agencies, etc.)? Do you think the community as a whole has been pleased with Site operation that the clean up has been effective? -1,.~~---=~~~~~~(l.[,.!!:.!,!l;¥1:.Q;~,:.J;,.~~;;::__ · Interview conducted by -----'--~~J..,4..f.../..:::..._:.:;.:._-'-~....:....-....:.... ___________ _ Date conducted _ _.'1/b.__....,,=,-F.---"1$:.,t./....;:,)..;__tf..:j;___ Jun-10-03 IO: 01 am From-RCRA .ianc, Section +404 562 8. Site City/State Address 5-.Year Review Questionnaire ~~-~.tJ.C. o1W ) How long have you lived near the Site? Are you familiar with EPA activities over the past years? T-445 P.009/014 F-283 Do you still have any concerns regarding EPA clean up activities of the Site? ll Overal have you been pleased or displeased with EPA actions at this Site? Do yo¥~ you have been adequately informed about clean up activities at the Site? Is there any information about the Site that you would like to share with us that would assist in our 5-year review of site activities? 0 Is there someone else that you would like to recommend we contact for more information? Do you have any suggestions that EPA can implement to improve communication with the public? · ~ (A copy of the 5-year review will be placed in the Site Information Repository file located in the Site Information Repository at----,---------,--------,--------- U-<,.M. ~ ~~ ~/ ~ h...J6-~ /1-H<dl.~ ~,W~~-f 1nrerv1ew conouctea oy: J,<~ M-,AA,,uk Date conducted: ".S"/7 /tJ3 ' Jun-10-03 10:02am From-RCRA .iance Section +404 562 8. Site City/State Date: ¾ '? oL?£?3 Name of Citizen Address 5-Year Review Questionnaire ~ eL~&;;t/4, Phone No. '1b Im t;.t-. ud!sel" T-445 P 010/014 F-283 Do you live near the Site? If yes, how long? . ~.w y 6,Jf frt..t<4r 3/ Are you familiar with EPA activities over the past years? 1-k!::::' . . What is your overall impressi~n of the project? ~ ;id td/, Ct:iA.r.$, -,d,,,t;_, ~ ,9-;) a-r,...,,s,d ~ y,.,.,# 4+?icv e-41, %· ~~~ tf 4A e e <' 1f ◄ :%3 e L f/ ~{?It t tu(J 4 a11, have you been pleased or displeased with cleanup actions at this Site? ~~u c' u. What effects, if any, have site operations had on the surrounding community? A,, efl, ~-,, .. ' QA ea O½¾ Y~ a_.,.-o/--4 o/-:. Do you still have any concerns regarding EPA clean up activities of the Site? d Do you think you have been kept adequately informed about clean up actMties at the Site? ____ _ LJ.) Are you aware of any events, incidents, or activities at the site such as vandalism, trespassing, or emergency responses from local authorities? If so, please give details. ____________ _ D Is there someone else that you would like to recommend we contact for more information? Do you haye any suggestions that EPA.can implement to improve communication with the public? 'J),,.c ae7, 4-x-'t 'hLJ.) 1 =o . Interview conducted b~ A~ ~ Date conducted : 1,. :J..Ob 3 Jun-10-03 10:02am From-RCRA. iance Section +404 562 8. Date: Site City/State ~ Name of Citizen Address 5-Year Review Questionnaire ) T-445 P 011/014 F-283 Do you live near the Site? If yes, how long? ~~~.v.)~;--3~a!!....y,a..i:.e .taf!.:11=4-'::..._ __________ _ Are you familiar with EPA activities over the past years? ---la~~' .:!.,.a:;:.J ___________ _ What is your overall impression of the project? _ _./)""-"nJ,,-=""-'-----------~---- Overall, h ve you been pleased or displeased with Cleanup actions at this Site? -6--u What effects, if any, have site operatiO!)S had on the surrounding community? Ptdi<nf fef ' ~d~ .P1l-(¼'Si -w-a.:f:w Do y'.7:]~11 have any concerns regarding EPA clean up activities of the Site? Do you think you have been kept adequately informed about clean up activities at the Site? ____ _ ¼f": G,.,.. %1'::'. ~ ~'± ~ 764-::5 £~- Are you aware of any events, incidents, or activities at the site such as vandalism, trespassing, or ememency responses from local authorities? If so, please give details. __________ _ Is there someone else that you would like to recommend we contact for more information? 0 Do you have any suggestions that EPA can implement to improve communication with the public? Interview conducted by: ,A, ; ' '.J &A£tt Date conducted : _ __,s-;;"-L..z.Lz,_I d::..L,._ ____ _ Jun-10-03 10:02am From-RCRA .ianc, Section +404 562 8. T-445 P.012/014 F-283 5-Year Review Questionnaire for Govt. Officials Site City/State ~~.tCey- i Date: -Yrry..:....:...."-"4----L11""-· ,;1.J;""'t.B=-- Name Address What is your overall impression of t~e project? C ~ ~ ~ . Have there been routine communications or aotivities conduoted by your office regarding the Site? (Site visits, inspections, reporting activities, etc.) If so, please give purpose and results. ~ Have there be by your office? If so, please give details of the events and results. Do you feel well informed about the Site's activities and progress? _;µ...._=:::.. _______ _ Do you think clean up activities at the Site have had a positive or negative impact on the community? In what ways? ---·--~------------------------ f ffl~ ;,.J ~ d;Y£ru cfr ... J ¥ Do you have any comments, suggestions, or recommendations regarding the Site's management or operation? ------------------------------- 6- Interview conducted by __ ""ed;-=,~=-·='---'~=-=.:...;;....::.... _______ _,, ______ _ Date conducted __ 1h~~?c....c.,+-~z_,_,.;l=o~o_3~---- Jun-10-03 , .. ~:~3~m From-RCRA .,nca Section +~04 562 8 T-445 P 013/014 F-283 /<}M,',~-cff)J._ Ir~, 1.¼,,. 'h '6.,__,(Mt_. • ·• • ~ ~~1;11 -~ ~Year Aeview Questionn ire ~~~- Site City/State Name of Citizen Address Do you live near the Site? If yes, how long? L/.e-¥? ¥fX!£/li 3 '{&d)-~/1&'~ Are you familiar with EPA activities over the past years? ~ ~ ~ ~ . e&o z; ~ k-4-!!i ~ ,J), What !s your overall impression of the project? -'-""'-'-'-"-'-""-•-==--=-~.::;1~='--'==v=:--"'=.;.:;cC'ff=.::;__;':;F--;,;;....-- What effects, if any, have site operations had on the surrounding community? ________ _ Do you think yo~have been kept adequately informed about clean up activities at the Site?_· ___ _ ~ ~ ~ Are you aware of any events, incidents, or activities at the site such as vandalism, trespassing, or emergency responses from local authorities? If so, please give details, __________ _ Is there someone else that you would like to recommend we contact for more information? Do you have any suggestions that EPA can Implement to improve communication with the public? Interview conducted by:. __ _.A""'"',µ""'"'41""""/--'-b=¼d{_=e«::J..·-· _______________ _ Date conducted : -~tb~,--~~_...,;..,o ... g_3,..._ __ . ~ i : S'. ~ i~ i · -~ 'l f" 1 l ~1 J J ~1 f~\ ~ ~J I j~1 .j ~ -sf i.ij_ ~ • l ;i ~ J .;, :~ " , * ~ ' ~ t ~i J . -\,)~ ~ .,r, j ~ 'l ' = ' ~ . ~ ~ ~A-• / UNITED STATES ENVIRONMENTAL PROTECTION AGENCY REGION 4 b 'I~ ~~":i~ ATLANTA FEDERAL CENTER 61 Forsyth Street, S.W. ·,·\ Atlanta, Georgia 30303-3104 /: (, May 29, 2003 ;d / f • 4WD-NSMB I . ; ( f 1.• ' ~.! / Mr. Stacy Samuelson Environmental Resources Section/Wilmington District U.S. Army Corps of Engineers P.O. Box 1890 Wilmington, Notth Carolina 28402-1890 SUBJ: Compiled Comments on the Draft Five-Year Review Report for the Geigy Chemical Superfund Site in Aberdeen, Moore County, North Carolina Dear Mr. Samuelson: The U.S. Army CoqJs of Engineers (the "Corps") was tasked by the Environmental Protection Agency ("EPA") to conduct the first Five-Year Review for the above referenced Superfund Site. This effort was provided under EPA's Work Authorization Form for lntcragency Agreement Number DW96945884A. EPA felt that a third patty evaluation of the Remedial Action would provide the greatest benefit in the Five-Year Review process. The CoqJs submitted the draft report on April 24, 2003. Copies of this report were disseminated to Notth Carolina Department of Environment & Natural Resources (NCDENR), The Pinnacle Consulting Group, Inc. (the Potentially Responsible Parties' (PRPs) consultant), Giczcllc Bennett, previous Remedial Project Manager, Region 4 Office of Technical Services, and COM, Inc, (the Agency's oversight contractor) for review and comments. The Agency appreciates the CoqJs' efforts in developing this Draft Five-Y car Review Report and offers the following comments in an effo1t to improve the overall quality of the document. Below are the Agency's comments and enclosed are comments from NCDENR, dated May 28, 2003 and the PRPs, dated May 21, 2003. The majority of the Agency's comments fall into one of three categories: typos, requesting clarification, and requesting additional information/data to substantiate a statement/conclusion stated in the report. For your convenience all comments are referenced to a specific page and Section and/or table/figure of the. report, as applicable. The comments below use "strikeout" and "redline" for deleting or adding specific text, respectively. ·1n order to address all parties' concerns, the Agency requests the CoqJs develop responses to all comments. The CoqJs' response will be ~hared with all reviewers and will be the basis of future discussions on the Five-Year Review. After reviewing the comments, it may be advis:1ble to discuss any major issues via the telephone: The Agency also requests that after reviewing all s • • 2 comments, the Corps provide the Agency a time estimate for preparing responses to the comments as well as revising the Draft Five-Year Review document. Also enclosed are copies of the five-year review questionnaires the Agency filled out as part of our effort to interview a few citizens arou11d the Site. As can be seen, I redacted pertinent information about the person/people interviewed. These questionnaires should be incorporated into an appendix in the revised report and a reference to them should be made in Section Vil, Subsection A. Below are the Agency's comments. I. Move the signature block for the Waste Division Director to the end of "Summary Form Table" which is currently on page vii. 2. Signature block should look like the following: Winston A. Smith Director, Waste Management Division U.S. EPA Region 4 3. Page iii. List of Acronyms: Add "CRQL --Contract Required Quantitalion Limit". 4. Page iii, List of Acronyms: Add "NCGWQS Standards". North Carolina Groundwater Qual_ity . ,. , .. - 5. Page iii, List of Acronyms: "TCL" should read "Target Co11t,uni11ant Compoy_~1ci List". 6. Page iii, List of Acronyms: Add "HRS -Hazardous Ranking System" to the list. 7. Page iv, EXECUTIVE SUMMARY, first paragraph, first sentence: This five year review is policv, not statutory, meaning that unlimited use of the site will be allowed when the remediation is complelc. This is also why the trigger dale is the Preliminary Close-Out Report (PCOR) and not on-site construction. 8. Page iv, EXECUTIVE SUMMARY, fourth paragraph. first sentence: Please change this sentence to read as follows, " ... (RA) was eonduetcd _implemented from ... " 9. Page iv, EXECUTIVE SUMMARY, fifth paragraph, second sentence: Please_ch,a!]g<!,!his ~cntence to read as follows, " ... adopted by EPA through the issuance of :m ~h'" Janl!Ql)'. 1998 Explanation of Significant Difference (ESD) to the Rc1ncdial Action in Ja11t1my +998-.'' 10. Page v, EXECUTIVE SUMMARY, top of page: The acronym "µg/L" should be defined as this is the first time this acronym is used. • 3 11. Page v, EXECUTIVE SUMMARY, Issue #3, second sentence: Change this sentence to _,z:,-:-:_...-.-e. -----:"'-, ... ,-:-. ~~ad:;:;:p,2~7,ntiall~ cxtcnd_ing ti1nc to acl.1ice_c rented~ g?a1s fu£r~~~i.~-gih~ .. g·Q~~tiQf remediat10n. The impact 1s not a reduction m remediation of on-slle grou_ndwater, but the decreased life of the carbon filters. 12. Pages vi and vii, Five-Year Review Summary Form: Please format this table so that it fits on a single page along with the signature block at the bottom of the page (refer to comment# I above). 13. Page vi, Five-Year Review Summary Form, "Review Period" block: The dates in this block should read "l/03 -6/03". 14. Page vi, Five-Year Review Summary Form, "Datc(s) of Site Inspection" block: Please insert the date, February 17, 2003, into this block. 15. Page vi, Five-Year Review Summary Form, "Type of Review" block: This is a "Policy" review. Please delete all the other options as this will allow the length of the table to be reduced. 16. Page vi, Five-Year Review Summary Form, "Trigger Action" block: The "Other'' box should be checked and include "Preliminary Close-Out Report" for "(specify)" (refer to comment #7 above). Please delete all the other options as this will allow the length of the table to be reduced. 17. Page vii, Five-Year Review Summary Form, "Protectiveness Statement" block: Insert at end this block the following statement, _"The next Five-Year Review should be scheduled five years from the date of this Review, in "MONTH" 2008. The "MONTH" needs to reflect the month that this report will be signed by the Waste Division Director. 18. Page vii, Five-Year Review Summary Form: Insert at the end of this table another block entitle, "Other Comments" and type "None", if that is the case. 19. Page I, I. INTRODUCTION Section, third paragraph, first sentence: This review is "policy". A policy review requires a review five years after construction completion as mentioned here, a statutory review requires a review five years after construction start. "Although not required by statute, this review is being conducted in accordance with EPA policy. EPA conducts five-year reviews as a matter of policy at: ( I) sites where no hazardous substances will remain above levels that allow unlimited use and unrest1icted exposure after completion of remedial actions, but the cleanup levels specified in the Record of Decision (ROD) will require five or more years to attain; (2) sites addressed before Superfund Amendments and Reauthorization Act (SARA) at which the remedy, · upon attainment of cleanup levels, does/will not allow unlimited use and unrestricted exposure; and (3) removal-only sites where hazardous substances remain onsite at levels • 4 that will not allow unlimited use and unrestricted exposure. This site has been reviewed because cleanup levels will require more than five years to attain." 20. Page 1, Section I. INTRODUCTION, third paragraph, second sentence: Change this sentence to read, " ... five-year review's-consistent. .. " 21. Page 2, Section III. BACKGROUND: A figure should be included in this section providing the topography of the area. 22. Page 2, Section III. BACKGROUND, Subsection A., se,cond paragraph, second sentence: . Typo, should this sentence read, "The site has topology topog~ar.hy typical of the ... "? 23. Page 3, Section III. BACKGROUND, Subsection C, first paragraph, first sentence: This sentence states the years of operation were from 1947 to 1989. This is inconsistent with what is stated in Table 1 (page 2), the first row in this table states the years of operations were from 1947 to 1987. Please correct this contradiction. 24. Page 4, Figure 2: This figure needs a scale. 25. Page 5, Section IJI. BACKGROUND, Subsection D., second paragraph, last sentence: ls there any information available as to why only three PRPs enter into an Administrative Order on Consent with the Agency? If so, this information should be included in this paragraph. 26. Page 6, Table 3: Change this table as follows: Groundwater Clean-Up Standards• Contaminant Groundwater Clean-up Corresponding Risk Level Basis of Goal Standard (µg/L) Aldrin 0.05 5.0 X 10·6 CRQL Alpha-BHC 0.05 1.3 X 10·6 CRQL Beta-BHC 0.05 4.0 X 10·7 CRQL Delta-BHC 0.05 ND CRQL Gamma-BHC 0.05 3.0 X 10·7 CRQL Dieldrin 0.1 8.3 X 10"6 CRQL Endri n Ketone 0.1 ND CRQL Toxaphene I 6.7 X 10·6 NCGWQS · CRQL --Contract Required Quantitation Limit NCGWQS --North Carolina Groundwater Quality Standards ND --Not determined, Toxicity data unavailable, risk levels could not be calculated. • 5 27. Page 6, Table 3 and Page 7, Table 4: Table 3 presents a performance standard for gamma BHC of 0.05 µ.g/L and Table 4 presents a performance standard of 0.2 µ.g/L. Is this correct or is this a typo? If this is correct, then the text needs to explain why there are two different performance standards for gamma BHC. . 28. Page 8, -Section IV. REMEDIAL ACTIONS, Subsection B., first and second paragraph: Both of these paragraphs state that specific masses of soil and debris were removed from the Site: If known, the actual location of where this soil/debris was taken should be incorporated into these paragraphs. 29. Page 8, Section IV. REMEDIAL ACTIONS, Subsection B., first paragraph, last line: Change this line to read, " ... TCE found in two qn-site well was site-related." 30. Page 8, Section IV. REMEDIAL ACTIONS, Subsection C: This section or the previous section should include, at least, a process flow diagram for the groundwater treatment system. 31. Page 8, Section IV. REMEDIAL ACTIONS, Subsection C: Somewhere is this section a statement needs to be included stating how the vegetative cover is perfo1ming (i.e., the status of the vegetative cover/tress). 32. Page 8, Section IV. REMEDIAL ACTIONS, Subsection C., first paragraph, fourth sentence: Typo, change this sentence to read, " ... it was agree.cl by all parties ... " 33. Page 8, Section IV. REMEDIAL ACTIONS, Subsection C., first paragraph, fifth sentence: This sentence states, "Therefore, the last round of monitoring well sampling ... " is not a true statement. It might have been the "most recent" sampling, but monitoring well sampling will continue for quite some time at this Site. Please reword. 34. Page 8, Section IV. REMEDIAL ACTIONS, Subsection C., first paragraph: This section or the previous section should include. a figure showing the locations of the extraction wells and the treatment building, the associated piping, and the infiltration galleries. 35. Page.8,.Section IV. REMEDIAL ACTIONS, Subsection C., first paragraph: It is not clear from either the text or the figures referred to if all the points identified in these figures _are sampled each time. Text needs to be added identifying which monitoring points arc sampled on a regular basis. 36. Page 8, Section IV. REMEDIAL ACTIONS, Subsection C., first paragraph: Text is not clear in how the treated groundwater is discharged to the infiltration galleries. Is discharge directed to all of the infiltration galleries constantly or is the flow rotated between the infiltration galleries. • • 6 37. Page 8, Section IV. REMEDIAL ACTIONS, Subsection C., first paragraph, fourth sentence: This sentence mentions the submittal of a "five-year review" by,the PRPs' contractor. Was this a "five-year review" or was this a document entitled "Downgradient Remedy Summary Report, Geigy Chemical Corporation Site, Aberdeen, North Carolina?" Please correct, if necessary.· Refer to comment #tgb40 below. 38. Page 8, Section IV. REMEDIAL ACTIONS, Subsection C., second paragraph. first sentence: This sentence states, " ... there have been few problems or breakdowns of the system." Please elaborate and provide supporting data for this conc_lusion. What is meant by "few"? It may be helpful to use graphs/tables to show the daily pumping history. A calculation of percent downtime should be provided for the system as a whole as well as for each individual extraction well to support this conclusion. 39. Page 8, Section IV. REMEDIAL ACTIONS, Subsection C., second paragraph, sixth sentence: Why is it only suspected that increasing TCE levels have decreased the longevity of the carbon adsorption canisters? It would be helpful to include data that shows the concentrations of contaminants (TCE) entering the treatment system are increasing thereby decreasing the longevity of the carbon. 40. Page 8, Section IV. REMEDIAL ACTIONS, Subsection C., second paragraph, seventh sentence: Please elaborate on the signiricant variations that were projected in the ROD and ESD that have not occurred during O&M. 41. · Page 8, Section IV. REMEDIAL ACTIONS, Subsection C., second paragraph, last sentence: This sentence states, " ... unless off-site conditions necessitate changes." This is ambiguous. What does it mean? Off-site conditions will not negate the need for continued remediation on-site. The last sentence should be deleted or reworded. 42. Page 8, Section IV. REMEDIAL ACTIONS, Subsection C: This section or the previous section should include a figure showing the location of nearby municipal supply wells in relationship to the Site. 43. Page 9, Figure 3: This figure needs a scale. 44. Page 9, Figure 3: This figure would be enhanced if it showed the location of the Geigy Site. If possible, any municipal water-supply wells that are within the mapped area should also be shown. 45. Page 9, Figure 3 is small and is difficult to read. Some well labels fall over - roads/railroads or on each other and cannot be read. 46. Page 10, Figure 4: This (igure needs a scale. 7 47. Page JO, Figure 4 should show where the treatment building and infiltration gallery are located. 48. Page 11, Section V. PROGRESS SINCE THE LAST FIVE-YEAR REVIEW: This section states that this is the first five-ys:ar review and that ho other report is available. However, the fourth sentence on page 8, Section IV, Subsection C, first paragraph states, "Following the submission of a five-year review to the state and EPA in 2002 ... " Please clarify this contradiction. 49. Page 11, Section VII. FIVE-YEAR REVIEW FINDINGS, Subsection A, first sentence: Typo, change "Potter's Pits" to "Geigy". 50. Page 12, Section YU. FIVE-YEAR REVIEW FINDL'\/GS, Subsection B, fourth bullet: Typo, correct the spelling of Harold "Moats". 5 I. -Page 13, Section Vil FIVE-YEAR REVfEW FINDINGS, Subsection C, last paragraph, first sentence: This sentence states the following, 'The site appears to be in compliance with the ARARs identified in the ROD." This sentence means that the groundwater performance standards have been achieved the impacted aquifer has been restored. This is not CotTeCt. 52. Page 13, Section VII. FIVE-YEAR REVIEW FINDINGS, Subsection D, second sentence: Michael Sheenan, with The Pinnacle Consulting Group, Inc., recently informed the Agency that a portion of the prope11y was recently purchased and the new owner is contemplating logging the property. Please contact Mr. Sheenan to get an update. 53. Page 13, Section VII. FIVE-YEAR REVIEW FINDINGS, Subsection D, fifth sentence: This sentence makes the following statement, "and the groundwater plume appears to be contained". This report docs not provide any information or data that substantiates this statement. This conclusion is a key conclusion for this document and thus it needs to be thoroughly substantiated. It would be helpful if the following information was incorporated into the repot1: a) graphs showing expected and observed contaminant concentrat_ion trends at individual wells b) maps showing expected and observed contaminant plume extent and concentrations _ at various time intervals c) _maps showing observed water level contours for the various aquifers and the · extraction well capture zones d) a comparison of the surface water/sediment concentration data to standards. All of this data is necessary in order.to document adequate containment of the downgradient groundwater contamination by natural attenuation .. • • 8 54. Page 13, Section Vil. FIVE-YEAR REVIEW FINDINGS, Subsection D, sixth sentence: This sentence states, "Toxicity and other factors for contaminants of concern have not changed". This report does not provide any information or data that substantiates this statement. Was the information in EPA's Integrated Risk Information System (IRIS) or another data base checked. If so, then a statement needs to be incorporated into this paragraph, that states something like "after reviewing IRIS, it was determined that the toxicity and other factors for the contaminants of concern have not changed". This paragraph should also identify those contaminants that were checked in IRIS. 55. Page 13, Section VII. FIVE-YEAR REVIEW FINDINGS, Subsection E Groundwater Data, first paragraph, first sentence: Typo, this is an incomplete sentence. 56. Page 13, Section VII. FIVE-YEAR REVIEW FINDINGS, Subsection E Groundwater Data: The text of this subsection should indicate whether or not the surficial aquifer wells included in Table 5 are within the area of capture for the Geigy extraction wells (and thus concentrations from these wells may reflect not only natural attenuation of contaminants but indirect effects of ground-water withdrawals from the underlying upper Black Creek aquifer). 57. Page 13, Section VII. FIVE-YEAR REVIEW FINDINGS, Subsection E and Table 5 on page 14: It is not clear from either the text or the table if the wells listed in Table 5 are the only surficial wells being monitored. If there are other surficial well being monitored, then Table 5 needs to be expanded to incorporate these wells. 58. Page 14, Table 5: Table 5 includes an entry for MW-IOS dated 10/23/2002. The remainder of the wells have an October 200 I sample as the last entry, and the table indicates that the reported data arc from the period 1990 to 200 I. ls the I 0/23/2002 data point for MW-I0S correct? 59. Page I 5, Table 6 and 7: The Agency realizes that there is a lot of monitoring data availilblc and that these two tables attempt to condense this data into an easy to view format that gives a "Snapshot" of what is happening in the groundwater. However, as presented, the reader cannot tell if the levels of contaminants arc extremely high or just over performance standards in a particular well nor can the reader tell whether or not there arc any concentration trends in the listed wells. Tables similar to Table 5 should be included in the report for all wells sot.hat this type of information available. 60. Page 15, Table 6 and 7: It should be specified which of these wells is included in the "pump-and-treat" remedy and which arc in the "downgradicnt, MNA remedy." 61. Page 16, Section VII. FIVE-YEAR REVIEW FINDINGS, Subsection E, first paragraph: This brief discussion on BHC concentration trends omits a number of wells. Since the concentration trends or absence of trends is a prime indicator of remedy performance, there should be a complete discussion of all wells where there are or have been detections • • 9 of BHCs. Ideally this discussion would be accompanied by charts that show concentration trends over the period since monitoring of the remedy performance began. However, it is acceptable to only include a text discussion of the trends, provided that a comprehensive- tabular presentation of the available data is included in the five-year review·. As one element of the text discussion of BHC concentration trends, it would be useful to· provide a separate evaluation of the trends or lack of trends at monitoring wells that are outside of the area of capture for the extraction wells but in relatively close proximity to that area. Such a discussion should make a staiement about whether or not there are indications that operation of the extraction wells has demonstrably reduced contaminant mass flux into the area downgradient of ground-water capture by the extraction wells. 62. Page 16, Section VTI. FIVE-YEAR REVIEW FINDINGS, Subsection E, first paragraph, last sentence: This sentence states that no BHC isomers have been detected in the sentinel wells for Town Well No. 2 and Ray's Mill and Aberdeen Creeks .. However, according to Table 7, BHC isomers were detected sentinel wells MW-38L and MW39L. Please correct this contradiction. 63. Page 16, Section VII. FIVE-YEAR REVIEW FINDI_NGS, Subsection E, last paragraph: This paragraph is confusing. ls TCE a contaminant of concern for the Geigy Site? 64. Page l 7, Table 8: This Table presents TCE concentration data for some of the monitoring wells. Some explanation is needed in either the table or in related text that explains why this subset of wells is included in the table. 65. Page 17, Section VII. FIVE-YEAR REVIEW FINDINGS, Subsection E Groundwater Data: The text on this page discusses TCE contamination and identifies MW-ISD as being at " ... the western edge of the remedy area ... " This designation is somewhat misleading, as it suggests that no remedy is applicable to wells furthc"r west. lt would be better if the text read something like "MW-18D at the western edge of the area where ground water is being extracted ... " 66. · Page 18, Section Vill. ASSESSMENT, Question A: Having figure(s) that provide extent of plume with isotherms, figure(s) showing piezometric surface contours, figure(s) showing capture zones associated with the groundwater extraction system, graphs showing concentration trends in key wells would be helpful to show and verify the conclusions being stated in this section. 67. Page 18, Section Vill. ASSESSMENT, Question B, first sentence: This sentence states, "The assumptions used for the remedy ... " The "assumptions" should be listed in this paragraph. 68. Page 18, Section Vill. ASSESSMENT, Question C, third sentence: Typo, change this sentence to read, " ... support of selection of monitored natural attenuation ... " • • 10 69. Page 19, Section X. RECOMMENDATIONS AND FOLLOW-UP ACTIONS, last paragraph: This paragraph discusses the presence ofTCE, I don't know if it is appropriate to include this as a recommendation for the Geigy site since the Agency has already stated for the record that TCE is not a Site related contaminant, but the City of Aberdeen is concern about the presence of TCE because recent analytical data show that levels of TCE are rising in one municipal well and beginning detected in two other city wells in the vicinity. One recommendation may be to evaluate whether or not the existing groundwater extraction system is exasperating the spread ofTCE in the groundwater. 70. Page 19, Section X. RECOMMENDATIONS AND FOLLOW-UP ACTIONS: The ROD states 'The Geigy Site shall have a fence and proper warning signs posted in visible locations in order to provide site control where humans have access to the release." Since there is no longer a release of contamination from soil issue at the site, there is also no longer an issue of a fence being needed at the site. Hence, this issue and recommendation should be deleted. This recommendation may be changed to read for the Agency to issue an ESD to eliminate the requirement for fencing and posting signs. 71. Page 19, Section X. RECOMMENDATIONS AND FOLLOW-UP ACTIONS:-The discharge permit is a state issue, not a EPA/CERCLA issue. It is not really even needed since this is a Supcrfund site. Whether the pcnnit says 5 or 7 wells, as the text points out, docs not affect the operation or implementation of the treatment system. Should this item . be a recommendation? Again, the Agency appreciates the effo11s of the Corps in preparing this report. As stated above, the Agency requests that the Corps develop a response to all comments. Please inform the Agency when the Corps will be able to prepare responses to these comments and a time- frame for submitting a revised document. If you have any questions, I can be contacted at 404- 562-8820. Sincerely, _.,..,.,- . I c_/" t DrfVNI Jon Bornholm Remedial Project Manager Enclosures (3) I. Comments from the Geigy Chemical Corporation Site Committee (May 21, 2003) 2. Comments from NCDENR (May 28, 2003) 3. 5_-Year Review Questionnaires· . cc: Giezelle Bennett, EPA Tim Eggert, COM, Inc. Randy McElveen, NCDENR Bill O'Steen, EPA Michael Sheenan, The Pinnacle Consulting Group, Inc. • Geigy Chemical Corporation Site Aberdeen, North Carolina Committee Correspondence May 21, 2003 Mr. Jon Bomholm Remedial Project Manager USEPA Region IV, North Superfund Remedial Branch 61 Forsyth Street, SW I Ith Floor Atlanta:, GA 30303-3104 RE: Draft Five-Year Remedy Review Report Geigy Chemical Corporation Site Aberdeen, North Carolina Dear Jon: Thank you for providing Olin Corporation and Syngenta Crop Protection the opportunity to review the draft version of the Geigy Site five-year remedy review. We are pleased with the findings of the review and offer the following minor comments: I. Page 5, Section IV.A, second paragraph, first sentence: For accuracy, please revise the sentence to read "The groundwater remedy was targeted at removal of site-related contaminants in the groundwater through groundwater extraction and on-site treatment by carbon adsorption." 2. Page 8, Section IV.C, first paragraph, second sentence: For historical accuracy, please revise the sentence to read "The Pinnacle Consulting Group of Greenville, South Carolina currently has the treatment monitoring and O&M contract for the PRPs." 3. Page 12, Section VII.B, first paragraph, forth bullet: Change "Harold Mose, Syngenta Crop Systems" to "Harold Moats, Syngenta Crop Protection". 4. Page 19, Section X, third paragraph. The Companies will update the number of extraction wells listed in the Site Groundwater Remediation Permit. I • We look forward to the release of the final version of the five-year remedy review and continue to offer our assistance to EPA and NCDENR throughout this process. Ifwe can be of further help, please contact me at (423) 336-4675. Regards, ~~ Ray Hom Project Coordinator c: R. McElveen (NCDENR) H. Moats (Syngenta) H. Grubbs, Esq. (WCS&R) M. Sheehan (Pinnacle) 2 North Carolina • Department of Environment and Natural Resources Division of Waste Management Michael F. Easley, Governor William G. Ross Jr., Secretary Dexter R. Matthews, Director Mr. Jon Bornholm North Superfund Remedial Branch US EPA Region N May 28, 2003 61 Forsyth Street, Eleventh (11) Floor Atlanta, Georgia 30303-3104 • RE: Comments on the Draft Five-Year Review Rep011 Dated April 2003 Groundwater Remediation Geigy Chemical Corp. Site NCD 981 927 502 Aberdeen, Moore County, NC Dear Mr. Bornholm: The Draft Five-Year Review Repo11 for the Geigy· Chemical Corporation Site, a· Supe1fund Site, located in Aberdeen, Moore County, No11h Carolina has been received and reviewed by the N011h Carolina Superfund Section. The No11h Carolina Superfund . Section offers the following comments. General Comments: 1. The State reviewed this subject repo11 for technical accuracy and proper evaluation of the groundwater data and accurate communication of the investigation results and history and system operations. The State did not provide review of completeness of the Rep011 in terms of 5-Year Review guidance or procedure.· Specific Comments: 2. Item #3 on page v addresses the encroachment of the off-site trichloroethene (TCE) contaminant Plume. The TCE should not "extend time to achieve remedy goals." As long as the pesticides and TCE do not break through the carbon treatment system the extraction of pesticides should not be adversely affected by the presence of the TCE. If anything the TCE could help accelerate pesticides going into solution and ·thus extraction as well as enhance biodegradation by using up dissolved oxygen and creating a reduced or ·. anaerobic aquifer, Please clarify orremove this statement. 1646 Mail Service Center, Raleigh, North Carolina 27699-1646 Phone: 919-733-4996 \ FAX: 919-715-3605 \ Internet: www.enr.state.nc.us AN EQUAL OPPORTUNITY I AFFIRMATIVE ACTION EMPLOYER:,. 50% RECYCLED/ 10% POST CONSUMER PAPER • • 3. The second bullet on page 7 includes the following language. " ... surface water and steam sediments ... " Please correct the spelling of stream and re-proof-read the text of the report. There are other minor typos in the report. 4. The third paragraph on page 7 states the goal of the downgradient remedial action (RA) is to reduce the BHC isomers to the standards. This is a natural process that we have no control over at this site. Therefore, the actual goal of this RA is to assure continued natural degradation of BHC isomer·s to the standards and to confirm that the pesticide contaminant plume does not impact receptors over the long-term degradation process. If necessary we would enhance protection of receptors with additional protective measures such as treatment of groundwater at receptors, pump and treat or enhanced natural attenuation, etc. as required. 5. Correct spelling of Harold Moats name in the fourth diamond on page 12. 6. Tables 6 and 7 are not sufficient for proper evaluation and documentation of remedy protectiveness. New or additional Tables should be included in this report that provide real contaminant concentration data. The concentration ranges and areas of increasing contaminant concentration should also be included in the text of the report or tabulated. 7. Please provide some graphs of trend analysis for vaiious areas of the plume and for the total plume and total BHC isomers. It is especially important to ·include any wells or well clusters that are continuing to increase in concentration. 8. Some areas of the plume are orders of magnitude above the performance standards. Therefore, I would not state that "contaminant concentrations" are "extremely low". See the third paragraph on page 18. Please remove the word extremely from the statement. - If you have any questions or comments, please contact me, at (919) 733-2S0-l, extension 341. cc: Dave Lown, N.C. Superfund Section Sincerely, Randy McE!veen Environmental Engineer NC Superfond Section . ~ ~-tf'l2L I, , IMu_ 'h ~04\., • . • ~ ~ /L-fl. ~~. ~,. -~ -Y ar eview Questionn ire Site City/State ~G~~l:t,, Date: '.OJ1 + o2 ~ o 3 Name of Citizen . Address Do you live near the Site? If yes, how long?/ [f-eM.? ~-8 ~· -k-w I 1 f s"' Are you familiar with EPA activities over the past years? ~ ,,. ~ ~~ ·!:---~ ~ µ.-cf ,,-M ~ m. What _is your overall impression of the project? ... &."""-"-"....._,,,.1"''-'~=:....:;..-"'-~~;;;,~='---"~--"-..;;.;,;,--R-=---,;;t::..--- Over~ have you been pleased or displeased with cleanup actions at this Site? 1 ✓k+wt ~ ~ o.r@ 1414 =~ (1~1_¥ What effects, if any, have site operations had on the surrounding community? ________ _ Do ou still have any concerns re ardin EPA clean u activities of the Site? . ~ ~ ~~ CP>L • Do you think yo4, have been kept adequately informed about clean up activities at the Site? s-2~&~~~ Are you aware of any events, incidents, or activities at the site such as vandalism, trespassing, or emergency responses from local authorities? If so, please give details. __________ _ Is there someone else that you would like to recommend we contact for more information? Do you have any suggestions that EPA can implement to improve communication with the public? · Interview conducted by: ___ Ja..M<1.,,"'a-t'1&.✓ ... ·-k#~=:2&a:::i.. ________________ ...,... Date conducted: _· _1b'--'-'p"""-'?~-2"-"'oa"""3..._ __ • • 5-Year Review Questionnaire ~~Qjf-Site C~ate Date: -~--......,_,t...,,.~o-D_tJ_o __ Name of Citizen Address Do you live near the Site? If yes, how long?--~)'{_· _.,.._~A-~--------------- Are you familiar with EPA activities over the past years? ~M--' . What is your overall impression of the project? =ff ~-.w ?«fj• ay-.,v -~--#idz:;._e Overall, h been pleased or displeased with cleanup ac\ions at this Site? • • • Do you still have any con_cerns regarding EPA clean up activities of the Site? ,. ~ Are you aware of any events, incidents, or activities at the site such as vandalism, trespassing, or emergency responses from local authorities? If so, please give details. __________ _ Is t ere someone else that you would like to recommend we contact for more information? Do you have any suggestions that EPA can implement to improve communication with the public? }}~,~~~ ¼;1~~~~ ht1-rW, . ?'-'1& , . · . _ Interview conducted by: . · i,UµJ ~ · · · . Date conducted : Jj~lo · , • . . .· . . ·. . . ·. . • 5-Year Review Questionnaire Site City/State Date:~ Name of Citizen Address How long have-you lived ne_c1r the Site? . Are you familiar with EPA activities over the past years? Do you still have any concerns regarding EPA clean up activities of the Site? '11 p";\..-L-'-f»:4-t:~ . . Overal have you been pleased or displeased with EPA actions at this Site? ~ Do you think you have been adequately informed about clean up activities at the Site? . yw, ~~ curt11;&t--t,v Is there any information about the Site that you would like to share with us that would assist in our 5-year review of site activities? ~ . 7"/ttf= 41'~ 1, Is there <;>meone else that you would r e to recommend we contact for more information? /' nvt.t'-L Do you have any suggestions that EPA can implement to improve communication with the pu:c? . ~~flj!!J tt ~tt~J~* [A copy of the 5-year review will b placed in the Site Information Repository file located in the Site Information Repository at ai . Interview conducted by: ,/4 ·. A~~· Date conducted : ,r' & /4100 3 .. I I • 5-Year Review Questionnaire Site City/State Date: ~ ~,. Name of Citizen Address How long have you lived near the Site? Are you famiiiar with EPA activities over the past years? ~~ ~ ~ ~ . r J.u.,,-,.,; ,l,,-fJ ~ # C' - Do you still have any concerns regarding EPA clean up activities of the Site? 1)1; 1 dU P=4 #· Over have you been pleased or displeased with EPA actions at this -'IL,__ . ~ . ,7,.. ~ Do you think you have been adequately informed about clean up activities at the Site? . ~ . Is there any information about the Site that you would like to share with us that would assist in our½e~e>W:si~vi~ er . Is there someone else that you would like to.recommend we contact for. more information? Do you have any suggestions that EPA can implement to improve communication with the public? ------------------------------- [A copy of the 5-year review will be placed in the Site Information Repository file located in the Site Information Repository at-------,-----------'-----.....; ____ _ Interview conducted by: / , A ~ ~ Date conducted : S! (, J 0,3 · · I r . · • • 5-Year Review Questionnaire for Govt. Officials Site City/State ;;).I)~ . Date: ___,c_:_~f----"t Name Address ~!:;dtC1v· What is your overall impression of t~e project? _,(A""--"'.v""· ~-(jc,.7-. _.'tt.H/4=-::=a::.· -'~=c==-------- Have there been routine communications or activities conducted by your office regarding the Site? (Site visits, inspections, reporting activities, etc.) If so, please give purpose and results. Have there by your office? 1tT ~- ,<J.,W"(;"~~ a response~ If so, please give details of the events and results. ~ wd/4. Do you feel well informed about the Site's activities and progress? ~-.µ~=::::.,. _______ _ Do you think clean up activities at the Site have had a positive or negative impact on the community? In what ways? · r? µLt;;e) ~ ~ ;;t ''10?<? ('~ q:J-: Do you have any comments, suggestions, or recommendations regarding the Site's management or operation? ..;._ ______ ...;... ______________________ _ 710- Interview conducted by ---"v~c.:1::.·~=·c=:::....· .;,:·~::;..::::: . .:..::::.. ;.;_· _______________ _ Date conducted· fri 7 '.?; ploo.3 • 5-Year Review Questionnaire Site City/State Date: 1/n~ Name of Citizen Address l!m~f,)w ) Do you live near the Site? If yes, how long? _::,.~,-:.W=-J+-_3.::..e,.rJ_~,;µ.P..,fl..,&-.1/.l-':::;;.. __________ _ Are you familiar with EPA activities over the past Years? __ ....i.;\:&a~----------- What is your overall impression of the project? ---"~~-="'-·-•'-----------~---- Overall, h ve you been pleased r displeased with cleanup actions at this Site? . ·U . What effects, if any, have site operatioris had on the surrounding community? ....chJ=.11...!!-<~=-· c;;. 1cc:!!;:!...:.__ . ~-! UC)£µJ n--· u~ -~ Do y7:j~II have any concerns regarding EPA clean up activities of the Site? Do you think you have been kept adequately informed about clean up activities at the Site? ____ _ ?cef::: "--uy ~ ~'.t-~ a±p~ ~. Are you aware of any events, incidents, or activities at the site such as vandalism, trespassing, or emergency responses from local authorities? If so, please give details. ----'--------' . . Is there someone else that you would like to recommend we contact for more information? CJ Do you have any suggestions that EPA can implement to improve communication with the public? Interview co~ducted by: · f-'--> • u &-uft Date conducted : -5-/7/tJ . · $ • • • Site City/State Date: ¾ 4 c),.NJ 3 Name of Citizen Address • DoyouliveneartheSite?lfyes,howlong? 3w, bJf1~ ~ Ares,ou familiar w.J.!h EPA activities over the past years? ~ L,4--/ . _ What is your overall impression of the proje_ct? 1-kp ;id_ 't:Jt ~ -·,d.,_,t;__, Ut-:4: 6H) 07\ ,,d., ~ ~ 4,0tc.?1 & ~-~~~ ef 4:1& e.,, =-v1a1c:::2 a I '!l' ~,91',1-, IT<V D ~all, have you been pleased or displeased with cleanup actions at this Site? ~~uc+I-----: . . . What effects, if any, have site operations had on the surrounding community? '1n J,,_ '-tL:ttz;..J- a 6 1 4 OY} ~ ~ ".ey-,;:1-(/7..k '· Do you still have any concerns regarding EPA clean up activities of the Site? d Do you think you have _been kept adequately informed about clean up activities at the Site? ____ _ .LJ..) Are you aware of any events, incidents, or activities at the site such as vandalism, trespassing, or emergency responses from local authorities? If so, please give details. __________ _ 0 Is there someone else that you would like to recommend we contact for more information? d Do you have any suggestions that EPA.can implement to improve communication with the public? . 1]~ tcwA;f, c+-,,.T 'hl--dJ 1, -_ _ _ -_ _ Interview conducted by: __ ..,.J~:.:~:::· ="-· ----~.=.~c...=,;_ff;..:;,_ _______________ _ Date conducted : ---'-~'"""'--=,,-'---'7.,..1 .,,,.2,._.o'-"'0~3,__ __ • • 5-Year Review Questionnaire Site City/State Address How l9ng have you lived near the Site? Are you familiar with EPA activities over ihe past years? . Do you still have any concerns regarding EPA clean up activities of tt-ie Site? b Overal have you been pleased or displeased with EPA actions at this Site? TAC Do yo think you have been adequately informed about clean up activities at the Site? u) . . Is there any information about the Site that you would like to share with us that would assist in our 5-year review of site activities? 0 Is there someone else that you would like to recommend we contact for more information? 6 Do you have any suggestions that EPA can implement to improve communication with the public? --~--------------------------...:. __ [A copy of the 5-year review will be placed in the Site Information Repository file located in the Site Information Repository at • • . -. ~~~~4:~/~~6--.~~/~- lnterview conducted by: / · ,,&,<jW,..U ~-· · · · Date conducted: :S-. 1 /ii3 ' . • • ~" 5-Year Review Questionnaire for Contractor/Site Manager~ Site (i~ {I_~ ~ City/State 6 ~, 7'.t C. Date: f))q1 ;loo3 · Phone No. Name Address What is your overall impression of the project? f}?-t,r,«g a a~) ~;,' 'fi-d rrL-~ @~ La,t±t €!_flff, J&.4 ✓ ~. -~--¢. e current status of construction (i.e., budget, schedule) ~ Have any problems been encountered which required, or will require, changes to this remedial design or this ROD? ;e,€ c~ M!fj~~-1v-9J-t~.,d:~~,, ~ ,4 <kJJ ~ M-{:A U< o_) ~ '--Cu<L( --/4_ ~ /~U Y-41: '-(tx.,lil . ~ a_dc;,---. . V . Hav~ problems or difficulties been encountered which have impacted construction Rrogress or implementability? ~ -rc_c:./ ~) c.:,, /4u!LF~ ~ ~ ~· ~~ ~ t?JL-' -If~ J.-</?½z:tin_, ~ 41P~, . 0 . ·. , Do you have any comments, suggestions, or recommendations regarding the project (i.e., design, construction documents, constructabili~{, management, regulatory agencies, etc.)? Do you think the community as a whole ~as been pleased wi h Site operation that the clean up has been effective? -4=:..,.-~:.i:!!~L.::Z:~i-C~~{-1:..J~IZ1a.:.1:P..:.~'.!..:::.__ -~ ~ ·~ . ~·~ lnteNiew conducted by ------"-~=-·..c.~'--.:..:·-· _,1,-A __ v_v;tf-____________ _ Date conducted -~7fh~~Afl_,_,,__· ~j"",_,)._, <_1 J __ _ II ' • • 5-Year Review Questionnaire Site City/State Name of Citizen Address Phone No. How long have you lived near the Site? _ 4o -· &j/,-~ ~ /X...e..(l,,1/. ~ Are you familiar with EPA activities over the past years? ~u) . Do ,,ou still have any concerns regarding EPA clean up activities of the Site? Overall, have you been pleased or displeased with EPA actions at this Site? '---1~ /J fe,. 1 ' J Is there any information about the Site that you would like to share with us that would. assist in om sy:ac~•••• of';;:~~ .,,J_,_,,_ ±:f,,!"'1' ,,e,._ Yi(,.,..,,/!_ j_._._,_, ;;ll-A,= apo3F ~ wd. I) Is ther,e someone else that you would like to recommend we contact for more information?• cJ Do you have any suggestions that EF'A can implement to improve communication with the public? ------------------------------ ?70 ~{J#M,1/ ~ '-41-r ~ V~ +4k:! qu:f [A copy of the 5-year review will be plac d in the Site nformation Repository file located in the Site . Information Repository at · .· /ht:1f'eo-ck1)--/L t-_c;-rrf o/~ Interview conducted by: oJ,_.£....U ~ Date. conducted: .:r/7 /;u 0.3 · I I I l ,• I Site City/State Date: ~ /41 ,.,lo o3 Name of Citizen Address • 5-Yeair Review Questionnaire Phone No. How long have you lived near the Site? ,r,-lf'h'ld, ~ ~Ju-4 cv.i-i ~ 0 - Are you familiar with EPA activities over the past years? --'~'-!-=~=---------- Do you still have any concerns regar ·ng E lea up activities oft e Sit ? C· en pleased or dis e tr(J..Utf!Ul__ . Do you t ink you have been adequately informed about clean up activi_tie~ at the Site? ·"' Is there any information about the Site that you would l~to share with us that would assist in our 5-vear review of site activities? / 7' a/4..,J; -tu.d,,(_: recommend we contact for more information? 0 Do you have any suggestions that EPA can implement to improve communication with the public? -·--,--,----,---,----,-r----,-----------,-.,--------"/Lo -,u.-) ~ ~ ~-(fV ~ [A opy of the 5-year review will be placed in the Site Information Repository file located in the Site Information Repository at----~-----'-------------'----- Interview conducted by: ~-h4=~_· ___ ·_. ·------------- Date conducted: ,:f/9/tJ 3 · · I I 7 • • 5-Year Review Questionnaire Site City/State Date: ____,_M-..:7~&"-1/c...c_ cJ.c...co~o a'--_ Name of Citizen Address How long have you lived near the Site? . ? /4d /&_, ~ AA _k/"t>-a pJ /4k,lZ, Are you familiar with EPA activities over the past years? ---,~---------- Do yo~ sti I have any concerns regarding EP~n =ities of the -~ --1!:.~~~;ff,.~~~r--&,~~*--- Do you thin u have be Is there any information about the Site that you would like to share with us that would assist in our 5y'.1ar review of site activities? · . .L{<J -.-,4 ~ Y-k, #~ ~ ½ ~ /-4.1r Do you have any suggestions that EPA can implement to improve communication with the public? -=----------------------------- [A copy of the 5-year review will be placed in the Site Information Repository file located in the Site Information Repository at----,--·------------~--------,-- Interview conducted by:. · ~~ hJ Date conducted : s-' /(e ( o 3 ~ -North Carolina Department of Environment and Natural Resources Division of Waste Management Michael F. Easley, Governor William G. Ross Jr., Secretary Dexter R. Matthews, Director Mr. Jon Bomholm North Supcrfund Remedial Branch US EPA Region IV May 28, 2003 6 I Forsyth Street, Eleventh (11) Floor Atlanta, Georgia 30303-3104 RE: Comments on the Draft Five-Year Review Report Dated April 2003 Groundwater Remediation Geigy Chemical Corp. Site NCD 981 927 502 Aberdeen, Moore County, NC Dear Mr. Bomholm: The Draft Five-Year Review Report for the Geigy Chemical Corporation Site, a Superfund Site, located in Aberdeen, Moore County, North Carolina has been received and reviewed by the North Carolina Superfund Section. The North Carolina Superfund Section offers the following comments. General Comments: 1. The State reviewed this subject report for technical accuracy and proper evaluation of the groundwater data and accurate communication of the investigation results and history and system operations. The State did not provide review of completeness of the Report in terms of 5-Year Review guidance or procedure. Specific Comments: 2. Item #3 on page v addresses the encroachment of the off-site trichloroethene (TCE) contaminant Plume. The TCE should not "extend time to achieve remedy goals." As long as the pesticides and TCE do not break through the carbon treatment system the extraction of pesticides should not be adversely affected by the presence of the TCE. If anything the TCE could help accelerate pesticides going into solution and thus extraction as well as enhance biodegradation by using up dissolved oxygen and creating a reduced or anaerobic aquifer. Please clarify or remove this statement. 1646 Mail Service Center, Raleigh, North Carolina 27699-1646 Phone: 919-733-4996 \ FAX: 919-715-3605 \ Internet: ,vww.enr.state.nc.us AN EQUAL OPPORTUNITY\ AFFIRMATIVE ACTION EMPLOYER-50% RECYCLED/ 10% POST CONSUMER PAPER • 3. The second bullet on page 7 includes the following language. " ... surface water and steam sediments ... " Please correct the spelling of stream and re-proof-read the text of the report. There are other minor typos in the report. 4. The third paragraph on page 7 states the goal of the downgradient remedial action (RA) is to reduce the BHC isomers to the standards. This is a natural process that we have no control over at this site. Therefore, the actual goal of this RA is to assure continued natural degradation of BHC isomers to the standards and to confirm that the pesticide contaminant plume does not impact receptors over the long-term degradation process. If necessary we would enhance protection of receptors with additional protective measures such as treatment of groundwater at receptors, pump and treat or enhanced natural attenuation, etc. as required. 5. Correct spelling of Harold Moats name in the fourth diamond on page 12. 6. Tables 6 and 7 are not sufficient for proper evaluation and documentation of remedy protectiveness. New or additional Tables should be included in this report that provide real contaminant concentration data. The concentration ranges and areas of increasing contaminant concentration should also be included in the text of the report or tabulated. 7. Please provide some graphs of trend analysis for various areas of the plume and for the total plume and total BHC isomers. It is especially important to include any we11s or well clusters that are continuing to increase in concentration. 8. Some areas of the plume are orders of magnitude above the performance standards. Therefore, I would not state that "contaminant concentrations" are "extremely low". See the third paragraph on page 18. Please remove the word extremely from the statement. If you have any questions or comments, please contact me, at (919) 733-280 I, extension 341. ~ncerely, c (; A ~.~,t(~~1 cc: Dave Lown, N.C. Superfund Section Rand; ki~Elveen Environmental Engineer NC Superfund Section • Geigy Chemical Corporation Site Aberdeen, North Carolina Committee Correspondence May 21, 2003 Mr. Jon Bornholm Remedial Project Manager USEPA Region IV, North Superfund Remedial Branch 61 Forsyth Street, SW I Ith Floor Atlanta, GA 30303-3104 RE: Draft Five-Year Remedy Review Report Geigy Chemical Corporation Site Aberdeen, North Carolina Dear Jon: Thank you for providing Olin Corporation and Syngenta Crop Protection the opportunity to review the draft version of the Geigy Site five-year remedy review. We are pleased with the findings of the review and offer the following minor comments: I. Page 5, Section IV.A, second paragraph, first sentence: For accuracy, please revise the sentence to read 'The groundwater remedy was targeted at removal of site-related contaminants in the groundwater through groundwater extraction and on-site treatment by carbon adsorption." 2. Page 8, Section IV.C, first paragraph, second sentence: For historical accuracy,__please · --· ·-------------·-revise the sentence to read "The Pinnacle Consulting Group of Greenville, South Carolina currently has the treatment monitoring and O&M contract for the PRPs." 3. Page 12, Section VILB, first paragraph, forth bullet: Change "Harold Mose, Syngenta Crop Systems" to "Harold Moats, Syngenta Crop Protection". 4. Page 19, Section X, third paragraph. The Companies will update the number of extraction wells listed in the Site Groundwater Remediation Permit. I • We look forward to the release of the final version of the five-year remedy review and continue to offer our assistance to EPA and NCDENR throughout this process. If we can be of further help, please contact me at (423) 336-4675. Regards, --fih~ Ray Hom Project Coordinator c: R. McElveen (NCDENR) H. Moats (Syngenta) H. Grubbs, Esq. (WCS&R) M. Sheehan (Pinnacle) 2 • • May 5, 2003 Memorandum TO: FROM: RE: File Randy McElveen Environmental Engineer NC Superfund Section Geigy Chemical Meeting to Discuss the 5-Year Review with the EPA, PRPs and Contractor Groundwater Remediation Geigy Chemical Corp. Site NCD 981 927 502 Aberdeen, Moore County, NC On I 8 February 2003, a representative of the NC Superfund Section participated in a meeting at the Residence Inn in Aberdeen, NC to review and discuss the process of the 5-Year Review and remedy effectiveness for the Geigy Chemical Site located in Aberdeen, NC. Those participating in the meeting included Jon Bomholm, EPA Region IV, Representatives with the Corp of Engineers and the PRP representatives for Olin and Syngenta. We also completed a site reconnaissance with the Corp representatives in order to familiarize them with the site and groundwater plume area. cc: Dave Lown, N.C. Superfund Section • UNITED STATES ENVIRONMENTAL PROTECTION AGENCY REGION 4 ATLANTA FEDERAL CENTER 61 Forsyth Street, S.W. .:,:, Atlanta, Georgia 30303-310_4. ,,{:. '-'.,·· C • ' \./ April 28, 2003 , \~ . ,, ';-...·: \ 4WD-NSMB Mr. Randy McElveen North Carolina Department of Environment & Natural Resources/Superfund Section 40 l Oberlin Road Raleigh, North Carolina 27605 \ SUBJ: Review Draft Five-Year Review Report for the Geigy Superfund Site in Aberdeen, Moore County, North Carolina Dear Mr. McElveen: Enclosed is a copy of the above referenced report, dated April 24, 2003, for North Carolina Department of Environment and Natural Resources (NCDENR) review and Site file. This document was prepared for the Agency by U.S. Army Corps of Engineers. Please review this report. The Agency would appreciate receiving any comments or concerns on this document by Thursday, May 22, 2002. If the State is unable to submit comments on this document by this date, please advise the Agency as to when the State will be able to submit its comments/ concerns. If you have any questions, please contact me at 404-562-8820. Enclosure (1): Sincerely, f' k ~~ ✓ Jon K. Bornholm Remedial Project Manager 1. Draft Five-Year Review Report for the Geigy Superfund Site in Aberdeen, Moore County, North Carolina (April 24, 2003) RA • Draft Five-Year Review Report . First Five-Year Review Repot·t For Geigy Chemical Corp. (Aberdeen Plant) Site Aberdeen Approl'ed By: Director, Waste Dil'ision U.S. EPA Region 4 Moore County, North Carolina April 2003 Prepared By: US Army Corps of Engineers Wilmington District \Vilmington, North Carolina Prepared For: Region 4 U.S. Environmental Protection Agency A llanta, Georgia Date: April 24, 2003 • Draft Five-Year Revieu, Geigy Chemical Corp. (Aberdeen P/0111), Aberdeen, NC Five-Year Review Report Table of Contents List of Acronyms ............................................................ _. .............. ; .............................................. iii Executive Summary .......................................................................... : ............................... , .......... iv Five-Year Review Summary Form ............................. ~ ............................................................... vi I. Introduction .................................................................... -.... · .................................................... 1 II. Site Chronololgy ...................................................................................................................... 2 III. Background ............................................................................................................................ 2 A. Physical Characteristics .................................................................................................... 2 B. Land and Resource Use ......................................................................... : ........................... 3 C. History of Contamination .................................................................................................. 3 D. Initial Response ........................................... : .............. : .......... , ........................................... 5 IV. Remedial Actions ............................................. · ............................................................... : ...... 5 A. Remedy Selection ...................................... : ............................................................ , ......... 5 B. Remedy Implementation .............................................................................. '. .................... 8 C. System Operations/ O&M ............... : ................................................................................ 8 V. Progress Since the Last Five-Year Review ......................................................................... 11 VI. Five-Year Review Process ................................................................................................... 11 VII. Five-Year Review Findings ............................................................................................... 11 A. Interviews ........................................................................................................................ 11 B. Site Inspection ................................................................................................................. 1_2 C. ARAR Review ................................................................................................................. 12. D. Changes in Exposure Pathways, Toxicity and Other Contaminant Characteristics_ ....... 13 E. Data Review ................................................... , ............. : .................................................. 13 VIII.· Assessment .................................... : .................................................................................. : 18 Question A: Is the remedy functioning as intended by the decision documents? ............... 18 Question B: Are the assumptions used at the time of the remedy selection still valid? ...... 18 Question C: Has any information come to light that could call into question the protectiveness of the remedy? ................................. :····· .. ·· ............................. : ...................... 18 IX. Issues ................................... ;· ............................................................... : ............................... ;. 19 X. Recommendations and Follow-up Actions .............................. : .......................................... 19 • Draft Fi11e. Year Re1,ie1v Geigy Chemical Corp. (Aberdeen Plant), Aberdeen, NC XI. Protectiveness Statements ................................................................................................... 20 XII. Next Review ........................................................•............................................................... 20 List of Figures Figure 1. General Location ...... : ............................................................... : ...................................................... 3 Figure 2. Specific Site Location ..................... .-................................................................................................ 4 Figure 3. Monitoring Well and Sampling Locations ................................................................................... 9 . Figure 4. Site Area Monitoring and Extraction Well Locations ....................................... : ...................... 10 List of Tables Table 1. Chronology of Events ...................................................................................................................... 2 Table 2. Soil Clean-up Standards ................................................................................................................... 6 Table 3. Groundwater Clean-up Standards ............................................................................... .-.................. 6 Table 4. Downgradient Groundwater Clean-up Standards ....................................................................... 7 Table 5. Surficial Aquifer BHC Isomer Concentrations in Groundwater Monitoring Wells 1990 - 2001 ................................................................................................................................................ : ......... 14. Table 6. Upper Black Creek Aquifer Sampling Results 1998 to 2002, Exceedences of Perfonnance Standards for BHC Isomers .................................................................................. : .............................. 15 Table 7. Lower Black Creek Aquifer Sampling Results 1998 to 2002, Exceedences of Performance Standards for BHC Isomers ................................................................................................................. 15 Table 8. Tri.chloroethene (TCE) Concentrations in Groundwater Monitoring Wells 1991 to 2002. 17 . Table 9. Recommendations and Follow-up Actions ...................................................................... , .......... 20 11 • Drafl Five.Year Review Gei!J Chemical Co,p. (Aberdee11 P/0111), Aberdee11, NC List of Acronyms AOC Administrative Order on Consent ARARs Applicable or Relevant and Appropriate Requirements BHC Benzene Hexachloride CENWHO-HX-G Corps of Engineers Hazardous, Toxic arid Radioactive Waste Center of CERCLA .CERCLIS Expertise · Comprehensive Environmental Response, Compensation, and Liability Act Comprehensive Environmental R_esponse, Compensation, and Liability Information System CESA W-TS-PE Wilmington District, Corps of Engineers Environmental Resources. CFR DDE DDT EPA FS IAG Kg L Mg NCP NPL ppb ppm PRP RA RD . RI ROD RPM SARA TCE TCL µg USACE· WasteLAN Section Code of Federal Regulations Dichlorodiphenyldichloroethylene Dichlorodiphenyltrichloroethane United States Environmental Protection Agency Feasibility Study Interagency Agreement Kilogram Liter Milligram National Oil and Hazardous Substances· Pollution Contingency Plan National Priorities List Parts Per Billion Parts Per Million Potentially Responsible Party Remedial Action Remedial Design Remedial Investigation Record of Decision Remedial Project Manager Superfund Amendments and Reauthorization Act of 1986 Triehloroethene Target Contaminants List Microgram United States Army Corps of Engineers The.Regional database related to CERCLIS Ill Draft Five-Year Rtviem Geigy Ch,mica/ Carp. (Aberdeen Plant), Aberdeen, NC Executive Summary This report documents the ffrst five-year statutory review of the National Priorities List (NPL) site NCD981023260. The site, refeITed to as Geigy Chemical Corp. (Aberdeen Plant) Site, is a former pesticide formulation and retail sales site located in Aberdeen, Moore County, . North Carolina. The site is approximately one acre in size. Contaminants of concern originally associated with groundwater at the site are pesticides including aldrin, BHC isomers, dieldrin, endrin, toxaphene, and the solvent trichlorocthene (TCE). Subsequent investigations showed that trichloroethene contamination was not a result of site activities and was therefore removed from the Site Target Contaminants List (TCL). There was also soil contamination involving the same pesticides listed for groundwater and the additional compounds, DOD, ODE, DDT, and chlordane isomers. These contaminants are the result of use of the site for pesticide formulation and blending and agricultural chemical sales from i 947 to 1989. In March 1988, an EPA Site Investigation in support of the Hazard Ranking System (HRS) was conducted on the site. Isomers of BHC were found in groundwater samples from three municipal and two private wells. Based on the results of the site investigation, the site was proposed to the National Priorities List (NPL) in June 1988 and listing was finalized October 4, 1989. . . There were three removal actions associated with the site for soil remediation. The first two, conducted in 1989 and 1991, removed soils visibly contaminated and other debris from the. site. Approximately 3,300 tons of soil and debris were removed for disposal in these two actions. Following the preparation and finalization of a Remedial Investigation/Feasibility Study, a·Record of D~cision (ROD) was signed August 27, 1992. The Remedial Action implemented by the ROD included demolition of the former warehouse foundation; excavation of the top foot of on-site soils contaminated above performance standards; off-site disposal of excavated soils as appropriate; extraction of groundwater from the surficial and Upper Black Creek aquifers; treatment of extracted groundwater via carbon adsorption; site restoration; and further sampling and analysis of the Upper Black Creek aquifer to determine extent of pesticide contamination and determine if TCE found in two wells was site-related. The Remedial Action (RA) was conducted from September 1996 to February 1997. The RA included removal of concrete foundations and other debris totaling approximately 2,460 tons to a Subtitle D landfill; disposal of 4,475 tons of contaminated soils to a Subtitle C landfill; construction and installation of extraction wells and groundwater tre.atment facilities with an infiltration gallery for discharge of treated groundwater. The treatment system began operation in January 1997 and has currently treated approximately 30 million gallons of extracted groundwater from the surficial and Upper Black Creek aquifers. As required in the ROD, a downgradient investigation was conducted to determine the extent of pesticide plumes in the Upper and Lower Black Creek aquifers. The results of the investigation, reported in the Downgradient Groundwater Remedial ActioTi Work Plan (RA WP), and the recommendations therein, were adopted by EPA through issuance of an Explanation of Significant Differences (ESD) to the Remedial Action in January 1998. The ESD established that the downgradient groundwater contaminant plume would be monitored as pait of the overall IV • Draft Five-) ·ear Revie,v Geig Chemical Corp. (Aberdec11 P/11111), Aberdeen, NC site remedy. The selected remedy for the downgradient area is monitored natural attenuation of the plume with the following contaminant concentration goals: alpha-, beta-, and delta-BHC 0.05 µg/L, and gamma-BHC 0.20 µg/L. There were several issues identified during the review process. None of the issues affect the assessment of the performance of the remedy. However, each should be addressed before the next five-year review. The issues are described as follows: I. Fencing and signing of the site as proposed in the documents of record have not been accomplished. This proposal was prepared prior to completion of the soil remediation and may no longer be applicable. 2. The Site Groundwater Remediation Permit issued October 1, 1999 and expiring June 30, 2004, needs to be changed io reflect that the treatment facilities consist of seven (7) recovery wells rather than the five (5) listed. · 3. Evidence indicates encroachment of the off-site trichloroethene (TCE) contaminant plume into the site treatment area. Increasing TCE levels have shortened the life of carbon adsorption canisters in the treatment facility, potentially extending time to achieve remedy goals. The remedial actions at the Geigy Chemical Corp. (Aberdeen Plant) Site currently protect human health and the environment. The soil remediation for the site has been completed, and the pump-and-treat remediation of the groundwater contamination including monitoring is continuing. The trends of contaminant concentrations in groundwater both at the site and in the downgradient area appear to be downward. Performance standards for contaminants of concern . are exceeded in the monitoring wells for the area under remedy implementation. To ensure long- term protectiveness of the s_elected site remedy, continued monitoring and operation of the groundwater treatment facility should continue. V • Draft Five•Year R.tvie,v Geigy Ch;mical Corp. (Aberdeen Pla11tj, Aberdeen, NC Five-Year Review Summary Form Five-Year Review Summarv Form · Site Identification Site Name: Geigy Chemical Corp. (Aberdeen Plant) EPA ID: NCD981927502 Region: 4 I State: NC I City/County: Aberdeen/Moore ~~\''ff"l'~lt{'(i"~~flj;";,i\"°''W""~~~l' "f -' -' ' ~~1"1,1J»" ~il'a/'~-~im'~'it;~'tlt'"~~ :~~,..::.· :'¥i-:i;,.,..,h£1&. • u~ -.~·_Jl•£f: .. J!t.,',._ ~.-r.~.. -:~t, SITE;SJ'A,TUS~ · . ;: ,.:' .. ,.,:JJi,ij._ ~.f4' . ...--·.~., trt!t.: ; 1\ ..... :\1. ~-•' .wt-~ " NPL status: ✓ Final D Deleted D Other: Remediation Status: D Under Construction ✓ Operating D Complete Multiple OUs?* D YES ✓ NO I Construction Completion Date: Septen1ber 27, 2000 Has site been put into reuse? ✓ NO !Ykl.f~~~'i~~~1!11-'l'f:\',ir11,lM!2'~REMIEWJSTATUS~~{~~~i~fi/~:~f'&.~t~'iif+.~~ Reviewing agency: ✓ EPA D State D Other: Author name: Stacy Samuelson Author title: Biologist Author affiliation: USACE, Wilmington District Review period:** 4/03 -4/08 Date(s) of site inspection: Type of review:*** ✓ Statutory D Policy (D Post-SARA D Pre-SARA 0 NPL-Removal only D Non-NPL Remedial Action Site D NPL Stateffribe-lead ·o Regional Discretion) Review number: ✓ 1 (first) D 2 (second) D 3 (third) D Other (specify) Triggering action:**** D Actual RA On-site initiation by PRP ✓ Actual RA start at OU# 1 D Construction completion D Previous Five-Year Review Report D Other (specify) Triggering action date: July 20, 1998 Due date (five years after triggering action date): July 20, 2003 * "OU" refers to operable unit. ** Review period should correspond to the actual start and end dates of the five-year review in WasteLAN. *** See Chapter 1, Section 1.2 of EPA 540-R-01-007, Final June 2001 for further explanation. **** See Chapter 1, Section 1.3 of EPA 540-R-01-007, Final June 2001 for further explanation. Vl • • Draft Five-Year Review . GeigJ Chemical Co,p. (Aberdee11 P!a11t), Aberdee11, NC Five-Year Review Summary Form Issues: 1. Fencing and signage for the site as proposed in the documents of record have not been implemented. 2. Site Groundwater Remediation Permit needs to be modified to reflect actual number . of wells associated with the treatment facility. 3. Encroachment of the off-site trichloroethene (TCE) contaminant plume into the site treatment area. Recommendations and Follow-up Actions: I. The need for fencing and signage of the site was negated by removal of the contaminated soils during the remedial action. No action should be taken. 2. The PRPs should update the Site Groundwater Remediation Permit when renewed in 2004. 3. Monitoring of the affect(s) oft.he TCE plunie on the site remedy should continue, with close coordination by all parties. Protectiveness Statement(s): The remedy at the Geigy Chemical Corp. (Aberdeen Plant) Site is expected to be or is protective of human health and the environment, and in the interim, exposure pathways that ' could result in unacceptable risks are being controlled. Vil • I. INTRODUCTION • Draft Five•Year Rcvic"w Geigy Cbemfral Co,p. (Aberdeen P/0111), Aberdee11, NC FIVE-YEAR REVIEW REPORT The United States Environmental Protection Agency (EPA) Region 4 has completed a five-year review of remedial actions implemented at the Geigy Chemical Corp. (Aberdeen Plant) Site in Aberdeen, Moore County, North Carolina. The United States Army Corps of Engineers (USACE) conducted and provided technical assistance and analysis for the five-year review. The Environmental Resources Section, Planning and Environmental Branch, Technical Services Division of the Wilmington District, Wilmington, North Carolina provided the US ACE lead for this review. The review was accomplished under EPA Work Authorization Form for Interagency Agreement (TAG) Number DW96945884A. The Wilmington District was supported in the conduct of the review by the USACE Hazardous, Toxic and Radioactive Waste Center of Expel'tise (CENWO-HX-G) located at the Omaha District, Nebraska. This review was conducted from January 2003 through June 2003. The report documents the results of that review. The purpose of five-year reviews is to detemline whether the remedy at a site is or is. expected to be protective of human health and the environment. The methods, findings, and conclusions of reviews are documented in five-year review reports. In addition, five-year review reports identify issues found during the review, if any, and recommendations to address them. This review is a statutory review. EPA must implement five-year review consistent with the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) and the National Oil and Hazardous Substance Contingency Plan (NCP). CERCLA § 12l(c), as amended states: If the President" selects a remedial action that results in any hazardous substances, pollutants, or contaminants remaining at the site, the President shall review such remedial action no less often that each five years after the initiation of such remedial action to . assure that human health and the environment are being protected by the remedial action being implemented. The NCP part 300.430(f)(4)(ii) of the Code of Federal Regulations (CFR) states: If a remedial action is selected that results in hazardous substances, pollutants, or contaminants remaining at the site above levels that allow for unlimited use and unrestricted exposure, the lead agency shall review such action no less often than every five years after the initiation of the selected remedial action. This is the first five-year review of the Geigy Chemical Corp. (Aberdeen Plant) Site. The site has been identified as requiring a "statutory" five-year review, which must occur within 5 years after completion of construction. Completion of construction, as designated by signature of the Preliminary Close-Out Report occurred on July 20, 1998 . . This review will be placed in the EPA site files and local repository for the Geigy Chemical Corp. (Aberdeen Plant) Site. The local repository is located at the Aberdeen Town Hall, ll5 N. Poplar St., Aberdeen, NC 28315. 1 • • Draft Five-Year Revie1v Geigy Chemical Corp. (Aberdeen Plant), Aberdeen, NC II. SITE CHRONOLOGY Table I lists the chronology for selected events for the Geigy Chemical Corp. (Aberdeen Plant) site, as shown below. Table 1: Chronology of Events ;~J;S,~1;//f-~{&;;;~}ifi;~~}'ff~'(:,1$}::{:~··t,,:Lrt~:?(EVENTil;;1;~tirt.!i\~!?~Jrt:~(J;W~f.-:l'rit~ttiiil~;.1.•~;{i;~~;, t.~;:~11i!l?D A TE1~:;}-¢t$~ Site leased bv several comoanies for ocsticide formulation and retail sales. 1947 to 1987 EPA detected pesticides in surface and subsurface soils on the site. fanunry 1987 Site insoection conducted bv the State. March 1987 Preliminary site assessment. June I 987 Hazard Ranking System (HRS) evaluation. August 1987 Site orooosed to be listed on the National Priorities List (NPL). June 1988 Site added to National Priorities List (NPL). October 4. 1989 PRPs conducted a soil removal action. 462 tons of soil and debris removed. February 23, 1989 to December 16. I 989 Administrative Order on Consent issued. Januarv 23. 1991 Second soil removal action by PRPs. 2,841 tons of soil and debris removed. February 25, I 991 to June I. I 991 Human Health Risk Assessment and Ecological Risk Assessment completed. March 13, 1992 PRP preparation of Remedial Investigation and Feasibility Study (RI/FS). December 16, 1988 to August 27, 1992 Record of Decision (ROD) signed. Aueust 27. 1992 Consent Decree for PRPs to conduct remedial design/remedial action (RD/RA) July I 5, 1993 RA contract for construction of groundwater remediation system and removal of contaminated soil September 1996 and debris awarded bv PRPs. Pre•final inspection of soil remediation by EPA and State of North Carolina. January 15, 1997 Groundwater Remediation Svstem ooerational. Januarv 1997 Final inspection of soil i-emediation bv EPA and State of North Carolirla. February 26, 1997 Downgradient Groundwater Rem"edial Action Work Plan annroved by EPA and NC DENR. November 1997 Exolanation of Significant Differences issued bv EPA Januarv 1998 Preliminary Ciose•Out Report July 20, 1998 Additional monitoring well installation. April 1998 Site insoection for the first five.year review. Februarv 18, 2003 III. BACKGROUND A. Physical Characteristics The Geigy Chemical Corp. (Aberdeen Plant) Site is located just to the east of the corporate limits of Aberdeen, North Carolina in southeastern Moore County (Figure I). The site is located on the Aberdeen and Rockfish Railroad right-of-way adjacent to Highway 211 and forms an elongated t1iangle with the highway and railroad forming the apex. The Geigy Site encompasses an area of approximately one acre that has been graded to be mostly level in nature (Figure 2), The site has topology typical of the Upper Coastal Plain physiographic region, with shallow water tables and low topographic relief. Soils in the area are classified as the Candor sand type that overlays unconsolidated sandy to clayey sediments. There are also an intermittent clay zone and several other clay lenses that divide the surficial groundwater aquifer from the Upper and Lower Black Creek aquifers in the area. Drainage from the site and predominant groundwater flow is to the west and northwest with both surface and subsurface runoff entering McFarlands Branch, Ray's Mill Creek, and Aberdeen Creek. 2 • B. Land and Resource Use • Draft Five-Year Revie1v Geig)! Chemical Co,p. (Aberdeen Plant), Aberdeen, NC Current land use of the area is rural residential and commercial in nature. The city of Aberdeen has approximately 3,400 residents. The Moore County area has grown approximately 18 percent in the last ten years and may continue to do so. Based on current levels of development of the area, it is not foreseen that there will be any major change in land-use in the future. Figure 1. General Location C. History of Contamination The Geigy Site was leased for the formulation and retail sale of pesticides from 1947 until its closure in 1989. Agricultural fertilizers in bulk and bagged form were also distributed from the site during its operational history. The pesticides DDT; toxaphene, and BHC were formulated for field use on-site by mixing with inert materials such as clay and repackaged for sale in the local agricultural market. An EPA Site Investigation was conducted in March 1988 in support of the Hazard Ranking System (HRS) evaluation of the site. Isomers of BHC were found in groundwater samples from five locations: three municipal wells and two private wells. 3 Figure 2. Specific Site Location \ ABERDEEN FOP. 3,578' 11 4 ::,,... Drcift Fi11e-YearR111iew Geig-; Chemical Corp. (Aberde,11 Pla11!), Aberdew, NC --L. 7 \ r-- "1/z, t.lt. LGdmen Holy Ch. o t cnr 1~t 1!!§ Geigy Chemical Corp. (Aberdeen Plant) Site s • • • Draft Five-Year RevieJP Geigy Chemical Co,p. (Aberdeen Plant), Aberdeen, NC D. Initial Response As discussed briefly in Section C above, the Environmental Protection Agency (EPA) conducted a Site Investigation in March 1988 in support of a Hazard Ranking System (HRS) evaluation. The site was proposed to be included on the National Priorities List (NPL) in June 1988 and final designation was completed October 4, 1989. During that time, notice letters were sent to six companies: Ciba-Geigy Corp, Olin Corp, Kaiser Aluminum & Chemical Corp, Lebanon Chemical Corp, Aberdeen and Rockfish Railroad, and Columbia Nitrogen Corporation, The notice letters requested that the Potentially Responsible Parties (PRPs) conduct-a Remedial Investigation and Feasibiiity Study (RI/FS) for the site. An Administrative Order on Consent (AOC) was entered into by EPA and three of the PRPs (Ciba Geigy { currently Syngenta Crop Protection, Inc.), Olin Corp, and Kaiser) for performance of the RI/FS on December 16, 1988. IV. REMEDIALACTIONS A. Remedy Selection • The remedial actions in the Record of Decision (ROD) dated August 27, 1992, provided for remediation of contaminated soils and groundwater. The remedial actions identified in the ROD were as follows: Groundwater The groundwater remedy was targeted at removal of site-related contaminants in the groundwater through groundwater extraction and on-site treatment by chemical means and air stripping. The following activities were_ identified as being associated with this alternative: Soils ♦ Contaminated groundwater would be extracted from within the Surficial and Upper Black Creek aquifer plume via extraction well(s) and piped to an on-site, aboveground treatment facility. ♦ Treatment would consist of carbon adsorption canisters to remove contaminants of concern. ♦ Final discharge of the effluent would be to either an on-site infiltration gallery or via connection to a Publicly Owned Treatment Works (POTW). ♦ Continued analytical monitoring of contaminants in groundwater. ♦ Further characterization of the Upper Black Creek aquifer to determine the extent of pesticide contamination. The remedy for contaminated soils had the intent of permanently removing contamination in the soil through off-site disposal of contaminated soils. The following activities were identified as being associated with this alternative: 5 Draft Fivc-l~ear Rtview Geigy Chemical Co,p. (Aberdeen Plant), Aberdeen, NC ♦ Excavation of the top foot of soils exceeding cleanup standards identified in the ROD. ♦ Disposal of contaminated soils in a secure landfill or a fixed-base incinerator depending on their regulatory requirements. · · ♦ Confirmation sampling and analysis to ensure that remediation levels are attained. ♦ Backfill of excavated areas with clean fill, regrading of site and re vegetation with native grasses. Tables 2 and 3 show the clean-up standards for soil and groundwater under the ROD. Table 2. Soil Clean-Up Standards Soil Clean-Up Standards Contaminant Clean-up Standard (mg/Kg) Aldrin 0.113 Alpha-BBC 0.28 Beta-BBC I. I 5 Delta-BBC NC Gamma-BBC 1.5 Dieldrin 0.13 Endrin Ketone NC Toxaphene 2.0 DDD 7.6 DDE 5.5 DDT 4.75 Gamma-Chlordane 1.43 Alpha-Chlordane 1.4 * Note: NC= Not Calculated. Table 3. Groundwater Clean-Up Standards Groundwater Clean-Up Standards Contaminant · Clean-Up Standard (11°/L) Aldrin . 0.05· Alpha-BBC 0.05 Beta-BBC 0.05 Delta-BBC · 0.05 Gamma-BBC 0.05 Dieldrin 0.1 Endrin Ketone 0.1 Toxaphene 1.0 Trichloroethene 2.8 The soils removal remediation was completed in early 1997. Site restoration was conducted in January 1997. A final inspection by EPA an_d the State of North Carolina Division of Superfund occurred on February 26, 1997. 6 • Draft Five. Year Review Geig;, Chemical Co,p. (Aberdeen Plant), Aberdeen, NC Based on results of the pre-remedial design field investigation, showing the presence of pesticides in the Upper Black Creek aquifer, additional investigations of the downgradient areas were conducted. A Downgradient Groundwater Investigation Work Plan (Rust, 1995) was prepared and presented to the EPA and NCDENHR to determine type, distribution and concentration of pesticides in the down gradient areas. Field investigations for the downgradient groundwater studies were conducted from March to October 1995. Results of the investigation were reported in the Downgradient Investigation Summary Data Report _dated March 1996. The PRPs and agencies met in May of 1996, to discuss preparation of a remedial action plan for the downgradient area and agreed to develop a Remedial Action Work Plan (RA WP) that_ would evaluate the containment and attenuation of pesticide concentrations as a component of the remedial action for the downgradient area. The resulting RAWP, finalized in November 1997, has the following objectives: • reduce pesticide concentrations in downgradient groundwater to levels which are protective of human health and the environment; • ensure that site-related pesticide concentrations in downgradient surface water and steam sediments are protective of human health and aquatic receptors; _and· • monitor drinking water supplies in the downgradient area to verify they are not adversely_ impacted. The RA WP defined the down gradient area as the portions of Upper and Lower Black Creek aquifers bounded by McFarland's Branch, Aberdeen Creek, Ray's Mill Creek, and Trough · Branch. The surficial aquifer was excluded from the work plan. Data from the downgradient · groundwater investigations revealed that the BHC isomers were the only target pesticides exceeding Federal or State drinking water standards or Site Performance Standards. As a result of the analyses, the goal of the downgradient remedial action is to reduce BHC isomer concentrations to levels below the.North Carolina and Federal drinking water standards or, for alpha-, beta-, and delta-BHC, which do not have established drinking water standards, to levels below the groundwater Performance Standards listed in Table 3. The downgradient groundwater Perfom1ance Standards are listed in Table 4. Table 4. Downgradient Groundwater Clean-up Standards Contaminant Clean-up Standard (u!!IL) Aloha-BHC 0.05 Beta-BHC 0.05 Delta-BHC 0.05 Gamma-BHC 0.20 The recommendations and proposed remedial Performance Standards for the downgradient groundwater in the RAWP were implemented by issuance of an Explanation of Significant Differences to the Remedial Action (ESD) in January of 1998. 7 B. Remedy Implementation • Dnift five~Year Rtview Geij;y Chemical Corp. (Aberdem Plant), Aberdeen, NC There were three removal actions associated with the site for soil remediation. The first two, conducted in 1989 and 1991, removed soils visibly contaminated and other debris from the site. Approximately 3,300 tons of soil and debris were removed for disposal in these two actions. Following the.preparation and finalization of a Remedial Investigation/Feasibility Study, a Record of Decision (ROD) was signed August 27, 1992. The Remedial Action implemented by the ROD included demolition of the former warehouse foundation; excavation of the top foot of on-site soils contaminated above performance standards; off-site disposal of excavated soils as appropriate; extraction of groundwater from the surficial and Upper Black Creek aquifers; treatment of extracted groundwater via carbon adsorption; site restoration; and further sampling and analysis of the Upper Black Creek aquifer to determine extent of pesticide contamination and determine if TCE found in two wells was site-related. The Remedial Action (RA) was conducted from September 1996 to February 1997. The RA included removal of concrete foundations and other debris totaling approximately 2,460 tons to a Subtitle D landfill; disposal of 4,475 tons of contaminated soils to a Subtitle C landfill; construction and installation of extraction wells and groundwater treatment facilities with an infiltration gallery for discharge of treated groundwater. The treatment system began ·operation in January 1997 and has cmTently treated approximately 30 million gallons of extracted groundwater from the surficial and Upper Black Creek aquifers. · C. System Operations/ O&M As required in the ROD and ESD, the PRPs have been operating a puri1p and treat system for remediation of the surficial and Upper Black Creek Aquifers since January of 1997 and monitoring the downgradient areas since April of 1998. · Since commencement of groundwater treatment operations, Pinnacle Consulting Group of Greenville, South Carolina has had the treatment monitoring and O&M contract for the PRPs. Initial monitoring requirements called for quarterly sampling for the firsrthree years followed by semi-annual sampling for an additional two years. Following_ submission of a five-year review to the state and EPA in 2002, it was agree by all parties that annual monitoring could be undertaken. Therefore, the last round of monitoring well sampling occurred in October of 2002. Monitoring well and surface water · sampling locations are shown in Figures 3 and 4. Since initiation of operation of the pump and treat system in January 1997, there have been few problems or breakdowns of the system. The 1992 ROD forecast an estimated annual O&M cost of $50,000 per year of operation. As currently implemented the treatment and monitoring program costs approximately $48,000 -$50,000 annually to operate. The system has treated approximately 30 million gallons of groundwater, operating at a pumping rate of 15-18 gallons per minute. The change-out/longevity period for the carbon adsorption canisters was initially one year, but has shortened to a six month time period. It is suspected that this change is due to increasing levels of Trichloroethene (TCE) coming from up-gradient of the site. No significant variations in O&M as projected in the ROD and ESD were identified. It is expected that operations will continue without modification or increased expense unless off-site conditions necessitate changes. 8 Figure 3. Monitoring Well and Sampling Locations ♦ ♦ 0 MW-27L ., -02 ,,...,."" 9 j Draft Five-Year &view Geigy Chemical Corp. (Aberdeen P/a11t), Aberdeen, NC Geigy Chemical Corp. (Aberdeen Plant) Remediation !'rogram • Extraction Wells t~ Surficia/ Aquifer Monitoring Wells o Upper Black Creek Aquifer Monitoring Wells ~ Lower Black Creek Aquifer Monitoniig Wells ♦ Surface Water Monitoniig Points ~ 190. C,Mw-220 CMW-200 • Figure 4. Site Area Monitoring and Extraction Well Locations j QMW-18D ._., CMW-11D • PW-,0 Geigy Chemical Corp. (Aberdeen Ptm,t) Remediation Program Immetliate Vici11ity • Extraction Wells t!> Surficial Aquifer Monitoring Welfs ai Upper Black Creek Aquifer Monitoring Wells • PW-2' MW-105 e 0 P'N-lS UW-17$ 0 10 MW->OS " Draft Five-Year &view Geigy Chemical Corp. (Aberdeen Pla11t), Aberdee11, NC t•.MW-17D e • • V. Progress Since the Last Five-Year Review: • Draji Five-Year Rc:1iew GeigJ• Chemical Co,p. (Aberdeen Plant), Aberdeen, NC Since this is the first Five-Year Review Report, no other report is available and thus no progress is reportable. VI. FIVE-YEAR REVIEW PROCESS The five-year review process for the Geigy Chemical Corp. (Aberdeen Plant) site included telephone discussion/interviews with the EPA Remedial Project Manager (RPM), and the lead state agency. Also included, were a visit to the Aberdeen Town Hall, the public repository for the remedial action documents, and a site visit for familiarization with the remediation activities. A list of pertinent materials from the document repository and other sources is provided in Attachment 1. The following persons were members of the five-year review team: ♦ Greg Mellema, Hazardous, Toxic, and Radioactive Waste Center of Expertise (CENWO-HX-G), Omaha, NE ♦ 'Phil Payonk, Wilmington District, Environmental Resources Section (CESAW-TS-PE) ♦ Stacy Samuelson, CESAW-TS-PE VII. FIVE-YEAR REVIEW FINDINGS A. Interviews The following persons were interviewed regarding the activities and irriplementation of the remedial actions at the Potter's Pits Site: Mr. ]011 Bomholm, Remedial Proiect Manager. EPA Region 4: In several telephone conversations between Stacy Samuelson and Mr. Bornholm, several issues pertaining to the Geigy Site were identified. The concern for potential effects on the remedy due to the off-site TCE plume migration into the site area was identified. A second , issue, full implementation of the Record of Decision in terms of fencing and signage at the site, was addressed as well. Additional discussion of these issues are provided in Sections IX, Issues, and X, Recommendations and Follow-up Actions. Mr. Randv McElveen, Environmental Engineer, North Carolina Department of Environment and Natural Resources, Division of Waste Management, Super[und Federal Remediation Branch: Stacy Samuelson, Wilmington District, made initial contact with Mr. McElveen through a telephone conversation. Mr. McElveen indicated that the State has no major issues with the site at this time. At the site visit, the issue of the off-site TCE plume was discussed in relation to the site remedy. The State has some concerns about the undefined source of that plume and its potential effects on the Geigy Site remedy. 11 • B. Site Inspection · • Draft Five•1'~ear Rcvie,v Geigy Chemical Corp. (Abcrdee11 Pla11t), Aberdeen, NC A site inspection of the Geigy Site was conducted on Febrnary 18,.2003. Attending the site visit were: ♦ Randy McElveen, Environmental Engineer, North Carolina Department of Environment and Natural Resources, Division of Waste Management, SF Federal Remediation Branch. ♦ Jon Bornholm, Remedial Project Manager, Environmental Protection Agency, Region 4. ♦ · Ray Horn, Olin Corporation .. ♦ Harold Mose, Syngenta Crop Systems. ♦ Michael Sheehan, Pinnacle Consulting Group. ♦ Ted Volskay, Pinnacle Consulting Group. ♦ Ray Livermore, U.S. Army Corps of Engineers, Wilmington District. ♦ Phil Payonk, U.S. Army Corps of Engineers, Wilmington District. ♦ Stacy Samuelson, U.S. Army Corps of Engineers, Wilmington District. For documentation of the site visit, photos of the treatment facility and several extraction wells were taken and are attached as Attachment 2. The site area has not been re-developed since the source remedial action was completed in 1996. The area is currently vegetated with grasses and some long-leaf pines have been planted along the railroad right-of-way. Mr. Sheehan g<)ve a brief historical overview of the activities and locations of facilities during the source remedial action and provided a tour of the pump-and- treat facility. C. ARAR Review In performing the five-year review for compliance with applicable or relevant and appropriate requirements (ARARs), only those ARARs addressing risk posed to human health or· · the environment.(i.e., addressing the protectiveness of the remedy) were reviewed. This is in keeping with current EPA guidance on five-year reviews. Federal ARARs ♦ Federal Groundwater Classification -55 Federal Register (FR) Part 8733. ♦ Safe Drinking Water Act of 1986, as amended (40 USC§§ 300) -40 CFR Part 141. ♦ Solid Waste Disposal Act (40 USC§ 6901 -6987)-40 CFR Part 261. ♦ EPA Regulations on Sole-Source Aquifers -40 CFR 149. State ARARs ♦ Identification and Listing of Hazardous Waste -15A NCAC l 3A.0006. ♦ North Carolina Drinking Water Act-General Statutes, Chapter 130A, Article 10. 12 • Draft Five•Year Rcvie111 Geigy Chemical Co,p, (Aberdeen P/a11I}, Aberdeen, NC ♦ North Carolina Water Quality Standards-ISA NCAC 2B. ♦ North Carolina Groundwater Quality Standards -ISA NCAC 2L.0100, 2L.0200, 2L.0300. The site appears to be in compliance with the ARARs identified in the ROD. There were no changes in the reviewed statutes and standards that would require changes in t_he remedy or management of the site. D. Changes in Exposure Pathways, Toxicity and Other Contaminant Characteristics No changes in the site conditions that affect exposure pathways were identified as part of the five-year review. There are no current or known changes planned in the land use and it is likely to remain rural residential immediately adjacent to the site. No new contaminants, sources, or routes of exposure were identified as part of this five-year review. There is no indication that hydrologic/hydrogeologic conditions are not adequate] y characterized .. The rate of decrease of contaminant levels in groundwater is consistent with expectations, and the groundwater plume appears to be contained. Toxicity and other factors for contaminants of concern have not changed. E. Data Review As a result of issues identified in the document review, interviews and site inspection, the principal data reviewed related to soil and groundwater contaminant levels of the site and downgradient area. The main resource for review of data was the Downgradient Groundwater Remedial Action Work Plan, Geigy Chemical Corporation Site, Aberdeen, No1th Carolina (RA WP) (November 1997) and groundwater monitoring data provided by Pinnacle Consulting Group (October 2001). Soil Data Soil contamination data have not been collected since the completion of the Remedial Action. Performance Standards for soils were met or exceeded as a result of the remedial action and the results of final soil testing were reported in the Final Remedial Report For Soils (I 997). Groundwater Data Groundwater sampling data was reviewed for sampling events occurring from May I 998 to the present. Wells were sampled quai1erly for three years and then semi-annually for the last two years. Samples were analyzed for organochlorine pesticides. Starting in 2003, with coordination with the EPA and state, monitoring will be conducted annually. Over the monitoring period, some wells have been abandoned or added and several, notably MW-11D, MW,18D and MW-30D, were unable to be sampled due to drought conditions in the third . quarter of 1998. Table S presents the detected values for BHC isomers in the surficial aquifer. Of the compounds on the TCL, the BHC isomers were the most consistently detected over the . sampling period, Most detected values exceed the site performance standards (Tables 3 and 4). 13 Draji Fiue-"\lear &vie/II Geigy Chemical C01p. (Aberdeen Plant), Aberdeen, NC Table 5. Surficial BHC Isomer Concentrations in Groundwater Monitoring Wells 1990 - 2001 Sample Date alpha-HHC beta-BBC delta-Bl-IC ~amma-HHC (Lindane) MW-4S 11/16/1990 1 3 6 0.5 MW-4S 12/S/1993 0.28 2.1 4.7 0.066 MW-4S 12/3/1996 ND(l.25) 15 10 ND(J.?5) MW-4S 4/16/1997 ND(0.25) 8.6 7.1 ND(0.'>5) MW-4S 7/14/1997 0.16 6 7.2 0.1 MW-4S 1 0/111997 0.19 6.3 6.8 ND(0.25) MW-4S 4/21/1998 ND(l.25) ,16 ND(l.25) ND(l.25) MW-4S I 0/29/1998 ND(0.275) 4.2 2.8 ND(0.275) MW-4S I 0/14/1999 ND(0.025) 0.36. 0.23 ND(0.025) MW-4S I OIi 3/2000 ND(0.125) 1.5 0.66 ND(0.125) MW-4S I 0/1 0/200 I ND(0.025) 0.013 ND(0.025) ND(0.025) ~;f,!;,'r-!~~;_\ ~~~ t~..!l!l~ 11/rl\i'!LW~ ~~'.ll.ff m,,,,'ltA~~!iW,,1!!&~ MW-5S II /16/1990 5 12 12 5 MW-5S 12/9/1993 1.1 17 6.3 ND(0.5) MW-5S 12/3/1996 ND(l.25) 17 5.6 ND(l .25) MW-5S. 4/16/1997 ND(0.5) 9.5 3.1 ND\0.5) MW-5S 7/14/1997 0,23 5 1.8 0.15 MW-5S 10/1/1997 0.16 3.9 1.3 ND(0.125) MW-5S 4/21/1998 ND(0.25) 2.5 0.59 0.05 MW-5S I 0/29/1998 0.31 8.6 2 0.25 MW-5S 10/14/1999 ND(0.125) 1.4 0.7 ND(0.125) MW-5S I Oil 3/2000 0:047 3.2 1.4 ND(0.125) MW-5S 10/10/2001 ND(0.125) 1.3 0.17 ND(0.125) ~~ M.-!.f.~~'!f.-.ll ~~ !!!~Wilt ~ ~7~ti.~1/l MW-6S 11/16/1990 36 12 29 30 MW-6S 12/9/1993 7.1 9.6 9.2 6 MW-6S 12/3/1996 2.1 5.8 2.5 1.5 MW-6S 4/16/1997 2.2 6.6 1.6 1.3 MW-6S 7/1411997 1.1 4.1 0.81 0.77 MW-6S 10/1/1997 1.3 3.8 I 0.83 MW-6S 4/21/1998 2.9 6.6 6 2.4 MW-6S I 0/29/1998 1.8 7.1 4.6 1.1 MW-6S 10/14/1999 3.9 6.9 18 2 MW-6S 10/13/2000 ND(0.025) ND(0.025) ND(0.025) ND(0.025) MW-6S !0/11/200 I 3.5 10 · 15 0.91 ~t-.W&Mitl ~~~ ~~~'\l !ml~~ I~~~ ~~.!W.ii©1'Ai MW-10S . 7/10/1991 2 25 2 0.8 MW-IOS 12/9/1993 ND(0.5) 14 0.79 ND(0.5) MW-10S 12/3/1996 0.026 0.58 0.045 0.07 MW-10S 4/16/1997 ND(0.25) 5.2 ND(0.25) 0.88 MW-10S 7/15/1997 0.11 1.7 0.12 0.35 MW-IOS 10/1/1997 0.59 4.4 0.47 1 MW-10S 4/21/1998 0.39 7 1.6 0.34 MW-10S I 0/29/1998 0.085 4.5 . 0.41 0.11 MW-10S 10/14/1999 0.045 2.3 0.21 0.064 MW-10S I 0/13/2000 ND(0.125) 1.8 0.077 ND(0.125) MW-10S I 0/23/2002 0.01 0.56 0.027 0.014 Note: Non-Detect values represent one-half of the detection limit. Values in bold denote detections exceeding performance standards (Table 3). 14 • Draft Five-Year RevietP Geigy Chemical Corp. (Aberdeen P/011!}, Aberdem, NC Tables 6 and 7 depict the concentration levels for the same compounds in the Upper Black Creek and Lower Black Creek aquifers. Well 2Q98 Table 6. Upper Black Creek Aquifer Sampling Results 1998 to 2002 Excccdcnces of Performance Standards for BHC Isomers 3Q98 4Q98 l tQ99 I 2Q99 3Q99 I 4Q99 IQ00 2Q00 3Q00 4Q00 IQ0I 4Q0I 2Q02 4Q02 Wells°;Withiri':ttie"-e:xtraction'·and ireatlllCnt CaDtlli-C zOn·e~~-:;;~-~ ·1 ; r.'l:~.✓-:~\~-:."1 .. / ;,:~·•/ ~'"~tt:':i.:"1:-~t·,1-~ .. ~~::' ... A~:, ;;k-1;'<( ''.J';,~ MW-11D i NS T NS i T i i i i i T NS NS NS MW-18D i NS i NS i i i T i i T i T NS NS MW-30D T i T NS f i i i T i i i i NS T M Oiiilo-rin"1{W'C11s1ror ·arC:i ·un-der 'r·e1t1edf( iirlDteineiita'tioll:\.i ,;..;,!,_~ia1', -F,tr·1; ~ {:it:I;:.::,• -~f\\' "':· :\' .~.:2z;.::·;~·~t•::.·4"-;;' .. ~~\.-t.';, 1ff f~ .. :~ ,-i:f.· !~ MW-19D A' A.B.G i i i i i i f A,G T A.D,G NS NS NS MW-20D A' 1' T 1' 1' 1' i 1' 1' 1' i i 1' i 1' MW-220 i 1' i 1' i i i 1' 1' i 1' i 1' i i MW-23D T T A,B,D T i i i T i i i T i T T MW-24D T B,G A,B.G T T i T A.B,G A,B,G i A,B.G T NS NS NS MW-25D ND ND ND T T B,D.G ND ND ND ND ND ND NS NS NS MW-26D i T i T i T ND i 1' r. T i T i T MW-35D i T i i i i i T i i i i i i i .Well ror. aSse'sSme"nt Or l?·r·oUitd'watCl' ClllalitV d0Wni:ii-3die0t' Ot1h·e"" Siii-ficifllritciuifei-wCII • M .W ~33S ~;.:.."'!-~,-'i!.•'':},j'_';{:: ·;,1 .;,'.~ NS I MW-34D1 ND Well 2Q98 ND ND B B ., B B I B B B B B Table 7. Lower Black Creek Aquifer Sampling Results 1998 to 2002 Excecdcnces of Performance Standards for BHC Isomers 3Q98 I 4Q98 I tQ99 2Q99 3Q99 I 4Q99 IQ00 2Q00 I 3Q00 4QOOI IQ0I Sentillel .wCII for:Unne·r.Black~Creek / LoWCr:Black:cre·ek Ao'Uifl!rS11Uterfllce· _. -.. ''.' :;·;." '. ---.-. ...... MW-22L i I' i 1' i i i I i i I i I i i i Mooitorin wells·ror area·•under reniedf:iinple"iiien18tioii,' :_. .': ;)•..=~ ,· -~.·~~.-~\ -. ,, -!-! ..... C " MW-2SL i i t i T i T i i i i i MW-27L i i i i i i i i i i i i MW-31L i i i i i 1' i i i i i i MW-37L i i AIG i .; i i i i i i i MW-40L i i T i T i l i i i i i PZ-2 i i 1' i i i i i i i T T PZ-3 i t i i i i 1' i i i 1' i PZ-5 ND 1' BIG A/BIG A/B/G i i A/BIG i A/BIG i i NS NS 4Q0I 2Q02 4Q02 ·J,. ~-···;-; ."1 ;• -'• T I i i '. .. ~-~::.:.: .. · , ... -~ . -" i i i i i i i i i i 1' i i i i i i i i i i i i A/BIG .WCIIS to·rOi-eCii.Si•'.tiends fo'r·R3 ·_•S' Mill;Creek; 'AlierdeelliCi-e"ck:; 3l'ld!McF:i'rlti0d's1Br'aii.ch ~-:·, -:~-;)'( . -;: '\ ·.:.~ :'"-·:~".I.: -·-~I PZ-2 i i i i 1' i i i 1' i i i i i i PZ-5 ND T BIG A/BIG A/BIG i i A/BIG i A/BIG 1' i i i A/BIG MW-31L i 1' i i i i i T i i i i i i i Sentinel WCll'for noith'ward-peSticidC niigi-StiOn a·nd:rorCcast of con·cenlratiO"n'.trentls inrRay°!s Mill,_Creck\: ... :<. _ J. •• •, MW-28LI A' I A i i i i I i i I A/B I i B/D/G i i I i i SeOtillCl Wells' tOr,-oOteDiial ITli~ratioh" Or ·o·eStii:ide·s iri10:RaY •s··M m:creei.:· lliid" A beiaeeritcl'eek s··· . . -;-·' ~\ ·••:;>;:-" . MW-32L ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND MW-38L ND i ND ND ND ND ND ND ND ND ND ND ND ·D ND MW-39L ND i ND ND ND ND ND ND ND ND ND ND ND ND ND Seritinel..Wcli-'f{)f.TOwn ,Well No.-2 :;,:,~.'5-'c~. 1-f .!..~.'..~i'.,;hi;/5-';,::C~tc,.;;~:~~-/¼,;.,'f·'_i,.'f .t ,; ~ :oJ.:.; i~~-i ~ 1f:~~• ?~'£i:'f·:;;: ·"••'::'~1;2~?~-•-:-_:•: ,;,.• .r,~: MW-36LI ND I ND ND I ND I ND I B ND ND I ND ND ND I ND I ND I ND I ND Notes: i Denotes all BHC isomers detected and exceeding performance standards. ND Denotes non-detect for all BHC isomers. A. alpha-BHC. B. be1a-BHC. D. delta-BHC, G -gamma-BHC * Letter only denotes that compound detected exceeding performance srnndard, NS = Not Sampled. 15 • Draji Five.}~ear Rcvie1v Geigy Chemical Co,p. (Aberdee11 Pla11t), Aberdeen, NC Trends in the BHC isomer concentrations in downgradient groundwater are varied. Several wells (MW-34D, MW-36L, MW-38L, and MW-39L) indicate no trend (little change) for the 1998-2002 monitoring period. Monitoring well MW-35D decreased over the same monitoring period. BHC concentrations for wells MW-37D and MW-40L slightly increased. Data for the downgradient areas seem to_ reflect reductions in concentrations of co_ntaminants for the remedy area monitoring wells. However, BHC isomer concentrations were consistently above performance standards. Sentinel wells for Town Well No. 2 (MW-36L) and Ray's Mill and Aberdeen Creeks (MW-32L, MW-38L, and MW-39L) have consistently exhibited no detection of BHC isomers. · During the downgradient investigations and with the adoption of the ESD in 1998, it was determined that trich!oroethene (TCE) was not a site related contaminant. As a result, monitoring and the downgradient groundwater clean-up standard for TCE was removed from the remedy (Tabl_e 4). However, the ESD did not remove TCE from the groundwater remediation levels (performance standards) as listed in Table 3. 16 • Draft Five-Year &view G,i!J Chemical Co,p. (Aberdeen Plant), Aberdeen, NC Table 8. Trichloroethene (TCE) Concentrations in Groundwater Monitoring \Velis 1991 to 2002 Trichlo·roethcne (TCE) Concentrations in Groundwater Monitoring Wells 1991 -2002 & ½-f,.ff ,.:t~'.1';.~SU rfiChi \ ''A'ti u if crr.1;.~1.w.~.511~ TCE Conccnlr:1lion Well DATE l,1~/1...l MW 10S 711011991 ND {]OJ MW-IOS 1213/1 996 ND(.~) MW-10S 4/16/1997 ND (5), MW-10S 7/15/1997 ND (5) MW-IOS J0/l/l997 ND (5) MW-10S 4/2lf1998 ND (5) MW-10S I0/29/1998 NDII) MW-10S 10/1411999 ND(\) MW-10S I0/1312000 ND {I) MW-10S 10/11/2001 ND(l) MW-10S 10/23/2002 ND {I) w.;,lll\W.l,m;;,1si;;w.,:,,,,.r.11<v.1:>i<!".I--= MW-16S 1213/1996 ND (5) MW-16S 4/16/1997 ND (5) MW-16S 7/1411997 ND(S) MW-16S 10/1/1997 ND (5) MW-16S .m11199s ND{5) ·MW-16S 10129/1998 NO(ll MW-16S \0/14/1999 ND{l) MW-16S 10!1312000 ND(5) MW•l6S 10/1112001 ND(I) MW•16S 10/22/'1002 ND{I) ~cu~~.:-:tw~r>~~ MW-17S 12/311996 ND {5) MW-17S 4/1611997 ND (5) MW-17S 7/14/1997 ND(5) MW-17S 10/1/1997 I.I MW-17S 4121/1998 ND(S) MW-17S J0/2911998 ND (I) MW-17S 10/14/1999 ND{l) MW-17S 10113nooo ND (I) MW-l7S 10/11/2001 ND{l) MW-17S 10/24/'1002 ND(\) ~~~~~;:A~- MW-18S 12/311996 ND (5) MW•l8S 4/1611997 ND(5) MW-18S 7115/1997 ND (51 MW•ISS 10/1/1997 0.66 MW-18S 4/21/1998 ND (51 MW•lSS 10/29/1998 ND{I) MW-18S IOf\4/1999 ND(ll MW-JSS 10/13/1000 ND{l) MW-18S 1011112001 ND (I) MW-18S !0'23/2002 ND(l) -~_½-;.._~-t;.U ·,-ocr BliCk. Cn'Ck1 A"lliiirCi.f.~.IC~~ TCE Concenlration \\'ell DATE (11~/L) MW-16D 2/9/1994 200 MW-160 1212/1996 2J() MW-l6D 4/16/1997 280 MW-160 7/14/1997 250 MW-160 10/1/1997 260 MW-16D 4/21/1998 290 MW-16D 10f19/1998 270 MW-16D 2/4/2000 290. MW-16D 10113/2000 E (260) MW-160 10/JOnOOI 190 MW-16D 10/24/2002 160 -;~...,,..,_\¾\~'l'l-"1.,1!,:<ijJ~f.l;',5' MW-17D 219/1994 180 MW•l7D 12/l/1996 J20 MW-17D 4/16/1997 190 MW-170 7/14/1997 J70 MW-170 10/1/1997 350 MW-170 4/21/1998 3.:!0 MW-17D J0f29/1998 350 MW-17D 2/4/2000 330 MW•l7D 10/13/2000 290 MW-17D 10'24/2002 290 --~~--!Ill; MW-18D 1/26/1994 ND (3) MW-18D S/18/1995 ND(I) MW-18D 12/3/1996 ND{S) MW-18D 4/16/1997 ND{S) MW-18D 7/14/1997 1.3 MW-18D JOfl/1997 1.6 MW-18D 4rll/J998 6.2 MW-18D 10/29/1998 4.2 MW-18D 10/14/1999 20 MW-18D 10/14/2000 29 MW-18D 10/10/2001 46 MW-18D 10/22/2002 71 ~~"!b~.L~~:\1lvt'~1~ MW-30D 10/14/2000 43 MW-30D I 0/22/2002 I 66 Note: Values in µg/L, ND= Non-detect. E c Estimated value above ins1rument linear calibra1ion range. Actual detection. , TCE concentrations at wells MW-16D and MW-17D, which are at the eastern edge of the site area, are consistently two orders of magnitude (100 times) greater than the 2.8 µg/L performance standard. MW-18D at the western edge of the remedy area consistently has TCE concentrations at one order of magnitude (10 times) the 2.8 µg/L performance standard. The trend at MW-18D is one where TCE concentrations are increasing over time. Surficial aquifer monitoring wells, MW-10S, MW-16S, MW-17S and MW-18S do not exhibit TCE concentrations above the performance standard. 17 • VIII. ASSESSMENT • Draft Five.Year Revie1v Geigy Chemical Corp. (Aberdeen Plant), Aberdeen, NC To assess the effectiveness of the remedy at the Geigy Chemical Corporation (Aberdeen · Plant) Site, three basic questions are answered and discussed below: Question A: ls the remedy functioning as inte11ded by the decision documents? For the Geigy Chemical Corp. (Aberdeen Plant) Site, the remedy for soil (source) contamination was completed in 1996, with the conclusion of soil and debris removal. Based on a final inspection of the site by EPA and the State of North Carolina Division of Superfund in 1998, the soil contaminant level goals established in the ROD and RD have been met and no further soil remediation is required. · The ground""'.ater pump-and-treat system was placed on-line in January 1997 and has operated continuously since. The groundwater contamination trends attributable to the pump- and-treat remedy for the surficial and Upper Black Creek aquifers appear to be downward. The trends of contaminant concentrations in the down gradient groundwater are difficult to discern because of the extremely low levels of contaminants present. At present, the monitoring data show that contaminant concentration levels of TCL compounds are consistently above performance level goals. Question B: Are the assumptions used at the time of the remedy selection still valid? The assumptions used for the remedy selection remain valid. The selection of extraction with activated carbon adsorption as the remedy for the surficial and Upper Black Creek aquifers is·still vaJid as there have not been any changes to the assumptions made originally. The selection of monitored natural attenuation as the remedy for the downgradient area is still valid as conditions have not fundamentally changed. Based on the review, all appropriate measures and procedures were utilized at the time of the remedial action and continue to be in effect: Question C: Has any i11formatio11 come to light that could call into questio11 the protective11ess of the remedy? Based on validated information provided in the documentation that was reviewed,_there is no information to date that significantly questions the protectiveness of the remedy. Data collected sirice the conclusion of the source remedial action support the selection of extraction with treatment as the preferred method for groundwater remediation in the ROD. The data also support of selection of monitored natural attenuation as the preferred method of groundwater remediation in the downgradient area as selected in the ESD. The trends of contaminant · concentrations in groundwater are generally downward. However, detections of target contaminants are frequently in exceedance of performance standards for the site. Remedy implementation data to date provide no validated early indication of potential remedy failure. 18 IX. ISSUES • Draft Five-Year Review Gc1'jj Chemical Co,p. {Aberdeen P/011!), Aberdeen, NC There are several problems or issues that have been identified during this review. Each is further discussed in the recommendations section of this report. I. Fencing and sign age for the site as proposed in the documents of record have not been installed. 2. Modification of the site Groundwater Remediation Discharge Permjt to reflect actual number of recovery wells in use. 3. Extension of off-site trichloroethene (TCE) contaminant plume into site area and potential affects on remedy as implemented. Potential increases in TCE concentrations in the remedy and downgradient areas. X. RECOMMENDATIONS AND FOLLOW-UP ACTIONS The recommendations and follow-up actions associated with the issues found in this review are described below and are summarized in Table 5. Implementation of site fencing and signage as proposed in the Record of Decision should be analyzed.· The proposal for fencing and signage was completed prior to remediation of the site soils. With removal of the contaminated soils, fencing.the site may pose a greater public safety hazard than exists currently. It is recommended that EPA, the state, and PRPs leave the site "as is" rather than incurring additional expense for a questionable increase in reduction of potential for site-related exposure to contarrunants. The current Groundwater Remediation .Permit issued to the site by the state does not reflect the treatment system as installed. The permit lists a total of five (5) recovery wells while the actual number of recovery wells in use is seven (7). As the current permit expires June 30, 2004, it is recommended that the PRPs update the information in the permit application for renewal. Change of the permit should only be editorial in nature and should not affect the operation or implementation of the treatment system. Extension of the off-site trichloroethene (TCE) contaminant plume into the site treatment area has been noted during ongoing monitoring of the remedy. The change-out period for activated carbon canisters has reduced from annually to semi-annually. Currently there are insufficient data to accurately predict whether the TCE plume will adversely affect the remedy as- implemented or not. It is recommended that the EPA and state continue to pursue characte1ization of the source of the TCE and the PRPs continue their voluntary monitoring of wells in accordance with the Site Groundwater Remediation Permit. 19 I) • Draft Five• Year RevieJ1J Geigi• Chemical Coip. (Aberdeell Pialll}, Aberdeell, NC Table 9. Recommendations and Follow-up Actions 1:§/:.efc_IsS·lte(sYtt~m:_ .'~--.: :<:ReCOl1iinCil<liitiO'ns!F_ OUOW~\ ~~t_·~~Pit"rtJ?f~~:i;)t; W3'{0VCrSiilit_)!!:if '\ J~-MilCStO_ ifo·~_'1i~ :.i~l;.Follo_-,v.::up;~.{.~ .,.,,,.,-:-. ··•r"f•,....,_~,~r:.-..... {,3;.-~~i,"';i.-r.~'W!' .. Vi 7·'t-~---.. ,"<, --1~~ ·1r-··'"•..td,;;,:-.-"""<.-, -\v .v•;-.-~•·1•,:...----• ...,.-;:;;,.-,./:;, ·-. ,-•-crr.·-~t: • ,·v~--•-f;•.,;;,·,.-'-•· 1-.:.~.-:'l.' lf.:.l/}$'.i'~-,.}.?;~~,:_.-.i~,:-'-1~8'~ ;!t-,.\'t!-!t_··-¥.,up 'ActiODS·. ;.,1,":A }~' .. RCSponSibt~·::,:.~ ~-~~;:·2~•Aueifcy",J~~~; Date:,'G->tt;.r_~ •-:Adions:•AITect.s·~- ·;,.7i'.[-p~, .. ,,ii;~ig.~• .· }"7::QJi!-•',._\.::,~t;J;:_..;,.l,J,:i{ i~-,,,:,;~ '.,; ."":;";~··• 'n·~Or-J~..,.:i'' j i'J.; •·:11·'i r,.•~1;·A.\-;J..,...~"'I:;:. :..rt•X!l-'ri?t.··~·E_. ~-:·'p'"'"'l;~•,i..~-l:-,,~EM1.~ ',':,;~c;;·.· 1:"t"U.:"'f'l-•;'{J; .. '\,_s;,t,Ji·J:ic ... ~r-:..;; -r.7"~[,,· ,:-.~-• .o/. :;>,1~ " • \~-::I;_ "i ,:~ . .\l :¼·.~.i ::<G.'::f-'~.•.-, "fl-.. ~ f,'}.f~~,. 1=J.":l""f.i, f;"· roteC l\'Cne5.'i:\"\"i l'i";;;,,_. -·i;>S-·i,,>'' •, -,1,,~,;o,1;,,/,'-:,~ ;:;.,~.p ~,\..>,, · ',l/1lli~•"' · •••·ii, ·,. >i''~-•~f/,• -,i,,;, ~,,.,,-, ,\_,,$;i_i!. '"-''"'"" "'"·-,,,;-,<,< ii~)}_<J~ ~;:.:~'fi;l.·'.i'.~l;~;l~ ~f: }:':.?J~;;:;~~~-.~~~;; .. ,~-~~t~'::lli:?-I'.'.,i-~r:.t. iJ~\$Vf{{\.~.: .. ~~t'.k1-~~ <.?;:;¥r._~~ .. ,t}~}f.-_t:~~t :~~f~-1'._•(Y IN it:~'(~~}' Fencing and Fencing and signage should PR.Ps EPA and State. Before next N signage for the not be required as the site five-year review site as proposed soils have been remediated. as required in the documents of record have not been im lemented. Groundwater Remediation Permit does not cover all instalied recover wells. Off-site trichloroethene · contaminant lume. Update permit to reflect actual number of recovery wells when renewed .. . Continued monito1ing of affect(s).on the site remedy. PRPs PRPs, EPA and State XI. PROTECTIVENESS STATEMENTS State EPA and State Upo"n renewal of current perffilt -June 30.2004 Before next five-year review or as required N N The remedy at the Geigy Chemical Corp. (Aberdeen Plant) Site is expected to be or is protective of human health and the environment, and in the interim, exposure pathways that could result in unacceptable risks are being controlled. XII. NEXT REVIE,v This is a site that requires five-year statutory reviews. EPA will conduct the next review within five years of the completion of this first five-year review report. The completion of this review as shown on the signature cover to this rep01t is the trigger for the next five-year review. 20 • Apn"/24,2003 ATTACHMENT 1 List of Documents Reviewed Five-Year Revieiv G,;gi, Chemical Co,p. (Aberdeen P/0111), Aberdce11, NC List of Documents Reviewed Geigy Chemical Corp. (Aberdeen Plant) Five-Year Review Rust Environment & Infrastructure: November I 993. Remedial Design Work Plan, Geigy Corporation Site, Aberdeen, North Carolina. Project No. 86619.200. Rust Environment & Infrastructure. November 1993. Sampling And Analysis Plan, Geigy Chemical Corporation Site, Aberdeen, North Carolina. Project No. 86619.210. Rust Environment & Infrastructure. February 1995. Downgradient Groundwater Investigation Work Plan, Geigy Chemical Corporation Site, Aberdeen, North Carolina. Rust Environment & Infrastructure. March I 996. Down gradient Investigation Data Summary Report, Geigy Chemical Corporation Site, Aberdeen, North Carolina. Volume I and 2. Project . · No. 33288.610. Rust Environment & Infrastructure. March 1996. Final Design Report, Oeigy Chemical Corporation Site, Aberdeen, N01th Carolina.-Project No. 86619.600. Rust Environment & Infrastructure. November 1997. Final Downgradient Groundwater Remedial Action Work Plan, Geigy Chemical Corporation Site, Aberdeen, North Carolina. Project No. 201165.10300. Sirrene Environmental Consultants. March 16, 1992. Feasibility Study Report, Geigy Chemical Corporation Site, Aberdeen, North Carolina. Sirrine Project No. G-1024.20. The Pinnacle Consulting Group. October 2001. Downgradient Remedy Summary Report, Geigy Chemical Corporation Site, Aberdeen, North Carolina. Project No. MAS0006I. The Potentially Responsible Parties (PRPs) for the Geigy Chemical Corporation Site. November, 1989. Remedial Investigation/Feasibility Study Work Plan, Geigy Chemical Corporation Site, Aberdeen, North Carolina. Prepared by ERM.-Southeast, Inc. The Potentially Responsible Paities (PRPs) for the Geigy Chemical Corporation Site. March 1992. Final Report -Remedial Investigation Study, Geigy Chemical Corporation Site, Aberdeen, North Carolina. Prepared by ERM -Southeast, Inc. U.S. Environmental Protection Agency, Waste Management Division. May I, 1989. Initial Soil Removal Rep01t Task 10-RI/FS, Geigy Chemical Corp. Site, Aberdeen, North Carolina. Prepared by the Potentially Responsible Pa1ties (PRPs) for the Geigy Chemical Corp. Site. U.S. Environmental Protection Agency, Region IV. March 24, 1992. Geigy Chemical Corp. Site NPL Site Administrative Record, Index and Volume I through 7. • Five• Year Rtvie,v Geigy Ckmical Co,p. (Aberdee11 P/0111), Aberdee11, NC U.S: Environmental Protection Agency, Region IV. August 27, 1992. Record of Decision; Summary of Remedial Alternative Selection; Geigy C:hemical Corporation Site, Aberdeen, Moore County, North Carolina. U.S. Environmental Protection Agency, Region IV. January 23, 1998. Explanation of Significant Differences to the Remedial Action, Geigy Chemical Corporation Site, Aberdeen, Moore County, North Carolina. U.S. Environmental Protection Agency, Region IV. February 6, 1998. Geigy Chemical Corp. (Aberdeen Plant) Site (Explanation of Significant Differences) NPL Site Administrative Record; Index and Volume 1 through 3 . . U.S. Environmental Protection Agency, Region lV. July 21, 1998. Superfund Preliminary Close-Out Report, Geigy Chemical Corporation NPL Site, Aberdeen, North Carolina. • • Five-'fear &view G,igy Ch,mica/ Corp. (Aberd,ra P!aat),Aberdeea, NC ATTACHMENT2 Photos of Extraction System Installations Al.I photos taken by Stacy Samuelson during site visit February 18, 2003 • Equalization Tank • Equalization tank and transfer pump 1 • • ' -~ .. ~ >:_!11~--- • Extraction well PW•3S • 2 • • Controller box/panel for extraction well 3 • • • Detail of extraction well PW•3S • View of extraction wells PW-2S and PW-JS from well PW-3S 4 • • • • • • UNITED STATES ENVIRONMENTAL PROTECTION AGENCY 4WD-NSMB Mr. Stacy Samuelson REGION 4 . ATLANTA FEDERAL CENTER 61 Forsyth Street, S.W. Atlanta, Georgia 30303-3104 January 22, 2003 U.S. Anny Corps of Engineers/Wilmington District Environmental Resources Section P.O. Box 1890 Wilmington, NC 28402-1890 JAN 2 7 2003 SUBJ: Transmittal of Documents for Preparation of the Five-Year Review Report for the Geigy Superfund Site in Aberdeen, Moore County, North Carolina Dear Mr. Samuelson: Enclosed is a copy of the following documents: Record of Decision (ROD) (August 27, 1992) ,. •• ' I'••~'.•"• ... Explanation of Significant Difference (ESD) "(January 23, 1998) Superfund Preliminary Close-Out Report (PCOR) (July 20, 1998). Below is the address for the Administrative Record/lnfonnation Repository for the Site: Aberdeen Town Hall Poplar Street Aberdeen, North Carolina There may be limited information on the Remedial Design and Remedial Action aspects of this project at this location. If there are any other documents that you need in a timely fashion in order to write the Five-Year Review Report, please let me know. lf you have any questions, I can be contacted at 404-562-8820. Sincerely, . . Jl11 I~ ~if\0 ~----1/V . , . , fon K. Bomholm Remedial Project Manager • • Enclosures: (s) I. August 1992 ROD 2. January I 998 ESD 3. July 1998 PCOR cc: Randy McE!veen, NCDENR (w/o encl.) Ray Hom, Project Coordinator, Olin Corp. (w/o encl.)