NCD981927502_20001012_Geigy Chemical Corporation_FRBCERCLA RA_Tenth Event Third Quarter 2000 Downgradient Area Monitoring Report-OCR

/ • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • •
ip111J)t
R~CE/\tr-.-
ocr 162000
SUPEAFt.JNU 6tCTION
TENTH EVENT, THIRD QUARTER 2000
DOWNGRADIENT AREA MONITORING REPORT
Geigy Chemical Corporation
CERCLA Site
Aberdeen, North Carolina
OCTOBER 2000
THE PINNACLE CONSULTING GROUP
Providing Decision Support Through Knowledge and Technology
I • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • e • • • • • • • • • • • • 0
October 12, 2000
Ms. Giezelle Bennett
Remedial Project Manager
Geigy Chemical Corporation Site
Aberdeen, North Carolina
Committee Correspondence
USEPA Region IV, North Superfund Remedial Branch
I Ith Floor
61 Forsyth Street, SW
Atlanta, GA 30303-3104 VIA OVERNIGHT DEi JVERY
RE: Tenth Event, Third Quarter 2000 Downgradient Area Monitoring Report
Geigy Chemical Corporation CERCLA Site
Aberdeen, North Carolina
Dear Giezelle:
In accordance with the Downgradient Groundwater Remedial Action Work Plan (RA WP), please
find attached one copy of the analytical results for the second quarter 2000 downgradient area
monitoring event (the tenth in a series of twelve quarterly monitoring events scheduled for the
initial three years of the remedy). To facilitate your review, analytical data summary tables and
figures showing detected concentrations at sample locations are attached .
Samples for the third quarter monitoring event were collected July 20, 2000 through July 24, 2000 .
Monitoring results (Tables I and 2) indicate that the remedy continues to be protective of potential
human and ecological receptors. Findings that support this conclusion include:
I Jppcr Black Creek Aquifer
• Pesticide concentrations in monitoring wells located west of the groundwater extraction
system (i.e., in the downgradient area) remain comparable to levels found during previous
monitoring events. The lateral extent of pesticides exceeding groundwater performance
standards in the Upper Black Creek aquifer continues to be less than that observed during the
initial downgradient area groundwater-sampling event (June 1996 for wells PZ-5, MW-31L
and MW-32L; August 1995 for all other wells) .
• Beta-BHC was detected at an estimated concentration of 0.043 ug/1 (below the Site
groundwater beta-BHC performance standard) in the groundwater sample collected from
monitoring well MW-34D. No other TCL pesticides were detected in the sample collected
from this well.
• • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • •
• BHC isomer concentrations in monitoring wells located downgradient of the groundwater
extraction system are below the maximum BHC isomer concentrations forecasted for the Upper
Black Creek aquifer by the transport model (see Table 3) .
I awer Black Creek Aqnifer
• The extent of pesticides in the Lower Black Creek aquifer is similar to conditions reflected by
previous quarterly monitoring events and the baseline sampling event (June 1996 for wells
PZ-5, MW-31L and MW-32L; August 1995 for all other wells) .
• Pesticides were not detected in well MW-36L, which serves as a sentinel monitoring point
for Town Well No. 2 .
• Routine monitoring conducted by the Town of Aberdeen continues to demonstrate that Town
Well No. 2 meets Federal and State drinking water standards .
• With the exception of BHC isomer concentrations reported for monitoring well MW-27L,
BHC levels in the Lower Black Creek aquifer are near or below the maximum concentrations
forecasted by the transport model (see Table 4). Analytical results for monitoring wells
surrounding MW-27L (i.e., MW-22L, MW-25L, MW-28L, MW-36L, MW-37L and PZ-3)
indicate that the BHC levels observed at MW-27L are limited in extent and therefore are not
anticipated to affect the remedy duration or level of protection .
• Pesticides were not detected in sentinel wells MW-32L, MW-38L and MW-39L, which
adjoin Aberdeen and Ray's Mill Creeks .
Stream Surface Water
• Analytical results for sentinel wells MW-32L, MW-38L and MW-39L, which monitor the
Lower Black Creek aquifer prior to its discharge to surface water, indicate that pesticide
concentrations in groundwater at these locations are below analytical detection limits. These
results demonstrate that pesticides in downgradient area groundwater do not extend to
Aberdeen and Ray's Mill Creeks .
• Pesticides were not detected in surface water sample SW-01, collected at the head of
McFarland's Branch. Alpha, beta-, delta-and gamma-BHC were detected at McFarland's
Branch surface water locations SW-02 and SW-03. Concentrations of BHC isomers detected
at SW-02 and SW-03 are similar to previous quarterly monitoring levels. Results of all
isomers are within the range of surface water concentrations estimated for these locations by
the transport model (Table 3-10 of the RA WP) and are at levels that are protective of
potential human and ecological receptors .
• Estimated concentrations of alpha-, beta-and delta-BHC were detected in surface water
samples SW-04, SW-05, SW-06, SW-07, SW-08 and SW-11-2 from Aberdeen Creek .
Heptachlor and heptachlor epoxide were not detected in the surface water samples collected
from Aberdeen Creek. Reported concentrations of alpha-, beta-and delta-BHC isomers arc
within the range of surface water concentrations estimated for these locations by the transport
model (Table 3-10 of the RA WP). The concentrations are comparable to historical
monitoring results and are at levels that are protective of potential human and ecological
receptors .
• Pesticides were detected in Aberdeen Creek in an area that lies outside of the downgradient
extent of Site-related pesticides (i.e., surface water sample SW-08, located upstream of the
• • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • ·• • • • • • • • • • • • e • C
confluence with Ray's Mill Creek). This finding indicates the source of pesticides detected
in Aberdeen Creek is not Site-related .
• Pesticide concentrations are nearly identical among surface water samples collected from
Aberdeen Creek at locations downstream and upstream of the confluence with McFarland's
Branch, thereby indicating that the estimated levels of pesticides in Aberdeen Creek are not
attributable to Site conditions .
• Surface water and groundwater analytical results collectively reveal that the pesticides
detected in Aberdeen Creek are not Site-related .
• Pesticides were not detected in surface water samples collected from Ray's Mill Creek .
Private Well Smvey
• A survey to identify newly installed residential water supply wells was performed as part of the
quarterly monitoring event by driving each road in the downgradient area and conducting a
visual inspection of the properties to locate pump houses and/or well heads. No newly installed
private wells were identified .
If you require additional copies of the enclosed materials, or have any questions about the
monitoring results, please contact me at [phone] .
Regards,
Garland Hilliard
Project Coordinator
/Enclosure
c: R. McElveen (NCDENR)
T. Eggert (CDM)
H. Moats (Novartis)
H. Grubbs, Esq. (WCS&R)
B. Vinzant (Kaiser)
M. Sheehan (Pinnacle)
• • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • •
SUMMARY TABLES AND FIGURES
THIRD QUARTER 2000
DOWNGRADIENT AREA
•••••••••••••••••••••••••••••••••••••••••••••••••••••••
UPPER BLACK CREEK AQUIFER
Sampling Event
Sample ID
Date Collected
Performance
Pesticides (ug/L) Standard (ugl!,)
Aldrin 0.05 <
alpha-BHC 0.05
beta-BHC 0.05
delta-BHC 0.05
gamma-BHC (Lindane) 0.2
alpha-Chlordane --<
gamma-Chlordane --<
4,4'-DDD --<
4,4' -DDE --<
4,4'-DDT --<
Dieldrin 0.1 <
Endosulfan I --<
Endosulfan II --<
Endosulfan sulfate --<
Endrin --<
Endrin aldehyde --<
Endrin ketone 0.1
Heptachlor --<
Heptachlor epoxide --<
Methoxychlor --<
Toxaohene I <
Notes:
Detects shown in bold type.
Table 1
Third Quarter 2000
Downgradient Area Monitoring Results
Geigy Chemical Corporation Site
Aberdeen, North Carolina
3QOO 3QOO 3QOO
MW-11D MW-18D MW-19D
7/2412000 7/2412000 7122/2000
0.5 QI/ < 0.25 QI/ < 0.05 II
t~~¥~it~2] II f.~-.i~9_:r,111 0.031 JI/ ~~~-ie...,..-...., ,'."'S:lW ~~E_~}Jjll < 0.05 II
d11;,1" ~§i!J}~1JII < 0.05 II
~toiii!>!11 t/4~~~!// 0.037 JI/
0.5 II < 0.25 II < 0.05 II
0.5 II < 0.25 II < 0.05 II
I II < 0.5 II < 0.1 II
I // < 0.5 II < 0.1 II
I // < 0.5 II < 0.1 II
I II < 0.5 II < 0.1 II
0.5 II < 0.25 II < 0.05 II
I II < 0.5 II < 0.1 II
I // < 0.5 II < 0.1 II
I // < 0.5 II < 0.1 If
1 // < 0.5 If < 0.1 //
~w:~J/1 ~':f0.31\ JI/ < 0.1 II
0.5 II < 0.25 II < 0.05 II
0.5 II < 0.25 II < 0.05 II
5 II < 2.5 II < 0.5 II
20 II < 10 II < 2 II
Values exceeding downgradient groundwater performance standards indicated by shading.
I -Separates qualifiers added by the laboratory and qualifiers added as a result of validation.
J-Estimated value.
Q -Elevated reporting limit.
V -Reporting limit is elevated due to limited sample volume.
1 of 4
3QOO 3QOO 3QOO
MW-20D MW-22D MW-23D
712312000 7121/2000 7/2312000
< 0.25 QI/ < 0.056 VI/ < 0.05 II
~f'\}21" 10;361// ~0.tt~)II li~J11 U!;,'.0;621// ;:I,0:16]"
~.t9~~11 [~{o:~i11 ir'9L1!6.~t11 ~--i.;&"':%?]11 '?!,o:"1;7,11 0.19 II
< 0.25 II < 0.056 II < 0.05 II
< 0.25 II < 0.056 II < 0.05 II
< 0.5 II < 0.11 II < 0.1 II
< 0.5 II < 0.1 I // < 0.1 II
< 0.5 II < 0.1 I // < 0.1 II
< 0.5 II < 0.11 II < 0.1 II
< 0.25 II < 0.056 II < 0.05 II
< 0.5 II < 0.11 // < 0.1 II
< 0.5 II < 0.11 // < 0.1 II
< 0.5 II < 0.11 II < 0.1 //
< 0.5 II < 0.11 // < 0.1 //
< 0.5 II < 0.1 I // < 0.1 II
< 0.25 II < 0.056 II < 0.05 II
< 0.25 II < 0.056 II < 0.05 II
< 2.5 II < 0.56 II < 0.5 II
< 10 II -< 2.2 II < 2 II
•••••••••••••••••••••••••••••••••••••••••••••••••••••••
UPPER BLACK CREEK AQUIFER
Sampling E,•ent
Sample ID
Date Collected
Performance
Pesticides (ug/L) Standard {ug{!,)
Aldrin 0.05
alpha-BHC 0.05
beta-BHC 0.05
delta-BHC 0.05
gamma-BHC (Lindane) 0.2
alpha-Chlordane --
gamma-Chlordane --
4.4'-DDD --
4.4'-DDE --
4,4"-DDT --
Dieldrin 0.1
Endosulfan I --
Endosulfan JI --
Endosulfan sulfate --
Endrin --
Endrin aldehyde --
Endrin ketone 0.1
Heptachlor --
Heptachlor epoxide --
Methoxychlor --
Toxaohene I
Notes:
Detects shown in bold type.
Table I
Third Quarter 2000
Oowngradient Area i\1onitoring Resulti,
Geigy Chemical Corporation Site
Aberdeen, North Carolina
3QOO 3QOO 3Q00
MW-24D MW-25D MW-26D
7/23/2000 7/23/2000 7/22/2000
< 0.05 II < 0.05 II < 0.05 II
0.039 JI/ < 0.05 II 0.05 II
0.032 JI/ < 0.05 II 0.05 II
0.008 JI/ < 0.05 II 0.026 JI/
0.034 JI/ < 0.05 II 0.081 II
< 0.05 II < 0.05 II < 0.05 II
< 0.05 II < 0.05 II < 0.05 II
< 0.1 II < 0.1 II < 0.1 II
< 0.1 II < 0.1 II < 0.1 II
< 0.1 II < 0.1 II < 0.1 II
< 0.1 II < 0.1 II <· 0.1 II
< 0.05 II < 0.05 II < 0.05 II
< 0.1 II < 0.1 II < 0.1 II
< 0.1 II < 0.1 II < 0.1 II
< 0.1 II < 0.1 II < 0.1 II
< 0.1 II < 0.1 II < 0. I II
< 0.1 II < 0.1 II < 0.1 II
< 0.05 II < 0.05 II < 0.05 II
< 0.05 II < 0.05 II < 0.05 II
< 0.5 II < 0.5 II < 0.5 II
< 2 II < 2 II < 2 II
Values exceeding downgradient groundwater performance standards indicated by shading.
/ _ Separates qualifiers added by the laboratory and qualifiers added as a result of validation.
J-Estimated value.
Q -Elevated reporting limit.
V -Reporting limit is elevated due to limited sample volume.
2 of 4
3Q00 3Q00 3Q00
MW-30D MW-34D MW-35D
7/24/2000 7/23/2000 7/22/2000
< 0.25 QI/ < 0.05 II < 0.05 II
h:~~0~67J// < 0.05 II :,;;'>T6ITsi11
!FJh:~i" 0.043 JI/ t~l:M11" "i'~t:·--1-~ i\'}J;.(),55. II < 0.05 II 0.026 JI/
~~~ii~~j11 < 0.05 II 0.098 II
< 0.25 II < 0.05 II < 0.05 II
< 0.25 II < 0.05 II < 0.05 II
< 0.5 II < 0.1 // < 0.1 II
< 0.5 II < 0.1 // < 0.1 II
< 0.5 II < 0.1 II < 0.1 II
< 0.5 II < 0.1 II < 0.1 II
< 0.25 II < 0.05 II < 0.05 II
< 0.5 II < 0.1 II < 0.1 II
< 0.5 II < 0.1 II < 0.1 II
< 0.5 II < 0.1 II < 0.1 II
< 0.5 II < 0.1 II < 0.1 II
~i:'S~JII < 0.1 II < 0.1 II
< 0.25 II < 0.05 II < 0.05 II
< 0.25 II < 0.05 II < 0.05 II
< 2.5 II < 0.5 II < 0.5 II
< 10 II < 2 II < 2 //
•••••••••••••••••••••••••••••••••••••••••••••••••••••••
LOWER BLACK CREEK AQUIFER
Sampling Event 3Q00
Sample ID MW-22L
Date Collected 7121/2000
Performance
Pesticides (ug/L) Standard (ug&)
Aldrin 0.05 < 0.25 QI/ ~-tfill alpha-BHC 0.05 f;;;ff•2:S II u"--";l••.,...·
beta-BHC 0.05 i·f:t't.;SjJI
delta-BHC 0.05 f,~2;4j11
gamma-BHC (Lindane) 0.2 t:~-"~°$"' ,r-· 2;3111 •;11L-
alpha-Chlordane --< 0.25 II
gamma-Chlordane --< 0.25 II
4,4'-DDD --< 0.5 II
4.4'-DDE --< 0.5 II
4,4'-DDT --< 0.5 II
Dieldrin 0.1 < 0.5 II
Endosulfan I --< 0.25 II
Endosulfan II --< 0.5 II
Endosulfan sulfate --< 0.5 II
Endrin --< 0.5 II
Endrin aldehyde --< 0.5 II
Endrin ketone 0.1 < 0.5 II
Heptachlor --< 0.25 II
Heptachlor epoxide --< 0.25 II
Methoxychlor --< 2.5 II
Toxaphene I < IO II
Notes:
Detects shown in bold type.
Table I
Third Quarter 2000
Downgradient Area Monitoring Results
Geigy Chemical Corporation Site
Aberdeen, North Carolina
3Q00 3QOO
MW-2SL MW-27L
712312000 712112000
< 0.25 QI/ < I.I Q Vi/
,~.,.,3•4111 fEA'h1l11 ~-··· ~l\:411 ,a a,..,~ ',, 0;56 II r~i'.2 II rr~~'~ II ~~-~·1 ~;.\',.9,S II ,..;:_;:t-'.t.: ~-?_ II
< 0.25 II < I.I //
< 0.25 II < I.I //
< 0.5 II < 2.3 II
< 0.5 II < 2.3 II
< 0.5 II < 2.3 II
< 0.5 II < 2.3 II
< 0.25 II < I.I //
< 0.5 II < 2.3 II
< 0.5 II < 2.3 II
< 0.5 II < 2.3 II
< 0.5 II < 2.3 II
< 0.5 II < 2.3 II
< 0.25 II < I.I //
< 0.25 II < I.I //
< 2.5 II < I I II
< IO II < 46 II
Values exceeding downgradient groundwater performance standards indicated by shading.
/ -Separates qualifiers added by the laboratory and qualifiers added as a result of validation.
J-Estimated value.
Q -Elevated reporting limit.
V -Reporting limit is elevated due to limited sample volume.
3 of 4
3Q00 3Q00 3Q00 3Q00
MW-28L MW-31L MW-32L MW-36L
7123/2000 7122/2000 712312000 7122/2000
< 0.05 II < 0.5 QI/ < 0.25 II < 0.05 II
~9'.os~j11 "',1,;2:11 II ffi''".-e_ .... .J < 0.25 II < 0.05 II
0.033 JI/ < 0.25 II < 0.05 II
0.031 JI/ ~-i~1~l" 0.25 II 0.05 II ~!Ji" < <
0.063 II !;'°&~i;ils7!fl < 0.25 II < 0.05 II
< 0.05 II < 0.5 II < 0.25 II < 0.05 II
< 0.05 II < 0.5 II < 0.25 II < 0.05 II
< 0.1 II < I // < 0.5 II < 0.1 II
< 0.1 II < I // < 0.5 II < 0.1 II
< 0.1 II < I II < 0.5 II < 0.1 II
< 0.1 II < I II < 0.5 II < 0.1 //
< 0.05 II < 0.5 II < 0.25 II < 0.05 II
< 0.1 II < l II < 0.5 II < 0.1 II
< 0.1 II < I // < 0.5 II < 0.1 II
< 0.1 II < I // < 0.5 II < 0.1 II
< 0.1 II < I II < 0.5 II < 0.1 II
< 0.1 II < I // < 0.5 II < 0.1 II
< 0.05 II < 0.5 II < 0.25 II < 0.05 II
< 0.05 II < 0.5 II < 0.25 II < 0.05 II
< 0.5 II < 5 II < 2.5 II < 0.5 II
< 2 II < 20 II < 10 // < 2 II
•••••••••••••••••••••••••••••••••••••••••••••••••••••••
I OWER Bl ACK CREEK AQUIFER , , , ,
Sampling Event 3Q00
Sample ID MW-37L
Date Collected 7/22/2000
Performance
Pesticides (ug/L) Standard (ug&)
Aldrin 0.05 < 0.25 QI/
alpha-BHC 0.05 tt~~:6Jtt
beta-BHC 0.05
·-~,.... ,_,_. ! '·'):·0'361 II
delta-BHC 0.05 </',; .-,-1 Rt; 0.94 II ~,::2;1•11 gamma-BHC (Lindane) 0.2 .... < __ •• 1
alpha-Chlordane --< 0.25 II
gamma-Chlordane --< 0.25 II
4,4'-DDD --< 0.5 II
4,4'-DDE --< 0.5 II
4,4'-DDT --< 0.5 II
Dieldrin 0.1 < 0.5 II
Endosulfan I --< 0.25 II
Endosulfan II --< 0.5 II
Endosulfan sulfate --< 0.5 II
Endrin --< 0.5 II
Endrin aldehyde --< 0.5 II ' Endrin ketone 0.1 < 0.5 II
Heptachlor --< 0.25 II
Heptachlor epoxide --< 0.25 II
Methoxychlor --< 2.5 II
Toxaphene I < IO II
Notes:
Detects shown in bold type.
Table 1
Third Quarter 2000
Downgradient Area Monitoring Results
Geigy Chemical Corporation Site
Aberdeen, North Carolina
3Q00 3QOO 3Q00
MW-38L MW-39L MW-40L
7/2312000 7/23/2000 7/22/2000
< 0.05 II < 0.05 II < 0.25 QI!
< 0.05 II < 0.05 II ~II
0.05 II 0.05 II ~t~~i~J11 < <
0.05 II 0.05 II ~'"it:ll/1 < < = .. ,.. .......
< 0.05 II < 0.05 II !'',;(!;_~! II
< 0.05 II < 0.05 II < 0.25 II
< 0.05 II < 0.05 II < 0.25 II
< 0.l II < O.l II < 0.5 II
< 0.l II < O.l II < 0.5 II
< 0. l II < 0.1 II < 0.5 II
< 0.1 II < O.l II < 0.5 II
< 0.05 II < 0.05 II < 0.25 II
< O.l II < 0.1 II < 0.5 II
< O.l II < O.l II < 0.5 II
< O.l II < O.l II < 0.5 II
< O. l II < O.l II < 0.5 II
< 0.1 II < 0.l II < 0.5 II
< 0.05 II < 0.05 II < 0.25 II
< 0.05 II < 0.05 II < 0.25 II
< 0.5 II < 0.5 II < 2.5 II
< 2 II < 2 II < 10 II
Values exceeding downgradient groundwater performance standards indicated by shading.
I -Separates qualifiers added by the laboralory and qualifiers added as a result of validation.
J-Estimated value.
Q -Elevated reporting limit.
V -Reporting limit is elevated due to limited sample volume.
4 of 4
3Q00 3QOO 3Q00
PZ-2 PZ-3 PZ-5
7/2312000 7/22/2000 7/22/2000
< 0.1 QI! < 0.05 II < 0.05 II
~tjll ~@.;~111 f,1lo.iv, 11
t!',r-;· · '1 !!{ii(in ~I II
~0~~11 1.f~fii17t r,,_.i«J'4 II < 0.05 II 1¥:i:0J2 II ~t·1i''4 r 11 rfq;~J!I 1:±', -~. j
< 0.1 II < 0.05 II < 0.05 II
< 0.1 II < 0.05 II < 0.05 II
< 0.2 II < 0.1 II < 0.1 II
< 0.2 II < 0.l II < 0.l II
< 0.2 II < 0.1 II < 0.1 II
< 0.2 II < 0.1 II < 0.1 II
< 0.1 II < 0.05 II < 0.05 II
< 0.2 II < 0. l II < 0.l II
< 0.2 II < O.l II < 0. l II
< 0.2 II < O. l II < 0.1 II
< 0.2 II < O. l II < O. l II
< 0.2 II < O. l II < O.l II
< 0. l II < 0.05 II < 0.05 II
< 0.1 II < 0.05 II < 0.05 II
< l II < 0.5 II < 0.5 II
< 4 II < 2 II < 2 II
•••••••••••••••••••••••••••••••••••••••••••••••••••••••
SURFACE WATER McFarland's Branch
Sampling Event 3Q00 3Q00 3Q00
Sample ID SW-OJ SW-02 SW-03
Date Collected 7/22/2000 7/21/2000 7/21/2000
Pesticides (ug/L)
alpha-BHC ug/L < 0.05 II 0.032 JI/ 0.03 JI/
be1a-BHC ug/L < 0.05 If 0.075 II 0.063 II
delta-BHC ug/L < 0.05 II 0.071 // 0.054 II
gamma-BHC (Lindane) ug/L < 0.05 II 0.03 JI/ 0.021 JI/
Heptachlor ug/L < 0.05 II < 0.05 II < 0.05 II
Heptachlor epoxide ug/L < 0.05 II < 0.05 II < 0.05 II
Notes:
Detects shown in bold lype.
Values e:1;ceeding downgradient groundwater performance standards indicated by shading.
/-Separates qualifiers added by the labor.itory and qualifiers added as a result of validation.
J. Estimated value.
Table 2
Third Quarter 2000
Downgrndienl Area Monitor-ing Result,;
Geigy Chemical Corporation Sile
Aberdeen, North Carolina
Aberdeen Creek
3Q00 3Q00 3Q00 3Q00
SW-04 SW-05 SW-06 SW-07
7/21/2000 7/21/2000 7/21/2000 7/21/2000
0.015 JI/ 0.015 J// 0.016 JI/ 0.013 JI/
o.o:n 111 O.OJS JI/ 0.036 JI/ 0.038 JI/
0.024 JI/ 0.024 JI/ 0.024 Jf/ 0.025 JI/
< 0.05 II < 0.05 II < 0.05 II < 0.05 II
< 0.05 II < 0.05 II < 0.05 II < 0.05 II
< 0.05 II < 0.05 II < 0.05 ff < 0.05 II
I of I
Ray's Mill Creek
3Q00 3Q00 3Q00 3Q00
SW-08 SW-11-2 SW-09 SW-10
7/21/2000 7/21/2000 7/21/2000 7/21/2000
0.018 JI/ 0.018 j// < 0.05 II < 0.05 II
0.037 JI/ 0.043 JI/ < 0.05 II < 0.05 II
0.029 JI/ 0.029 JI/ < 0.05 II < 0.05 II
< 0.05 II < 0.05 II < 0.05 II < 0.05 II
< 0.05 II < 0.05 II < 0.05 II < 0.05 II
< 0.05 ff < 0.05 ff < 0.05 ff < 0.05 ff
•••••••••••••••••••••••••••••••••••••••••••••••••••••••
TABLEJ
ESTIMATED MAXIMUM CONCENTRATION TRE1''DS IN GROUNDWATER OVER TIME
UPPER BLACK CREEK AQUIFER
GEIGY CHEMICAL CORPORATION SITE
ABERDEEN, NORTH CAROLINA
O Years' 4 Years 10 Years 20 Years 30 Years
Alpha BHC
1.5 year Half-Life & Retardation Factor= 82 2.8 0.31 <ll.05 <ll.05 <ll.05
No Degradation & No Retaniation 3 2.8 1.39 0.67 O.o7 <ll.05
5 year Half-Life & Retardation Factor= g4 2.8 1.13 0.46 0.10 <ll.05
10 year Half-Life & Retardation Factor= 125 2.8 1.52 0.96 0.44 0.21
Beta BHC
1.5 year llalf-Life & Retardation Factor= 82 5.0 0.56 <ll.05 <ll.05 <ll.05
No Degradation & No Retardation 3 5.0 2.13 0.92 0.11 <ll.05
5 year Half-Life & Retardation Factor= g4 5.0 2.01 0.80 0.17 <ll.05
10 year Half-Life & Retardation Factor= 125 5.0 2.86 1.66 0.77 0.35
Delta BIIC
1.5 year Half-Life & Retardation Factor= 122 4.2 0.47 <ll.05 <ll.05 <ll.05
No Degradation & No Retardation 3 4.2 1.99 0.93 0.12 <ll.05
S year Half-Life & Retardation Factor= It 4.2 1.72 0.72 0.17 <ll.05
10 year Half-Life & Retardation Factor= 20-~ 4.2 2.30 1.47 0.70 0.33
Gamma BBC
1.5 year Half-Life & Retardation Factor= 5.32 2.8 0.30 <0.20 <ll.20 <ll.20
No Degradation & No Retardation 3 2.8 1.44 0.71 <ll.20 <ll.20
5 year Half-Life & Retardation Factor= 5.34 2.8 1.11 0.44 <ll.20 <ll.20
10 year Half-Life & Retardation Factor= 8.43 2.8 1.50 0.93 0.42 <ll.20
Notes:
1. Based on August 1995 sampling event. Maximum concentration measured in MW-11 D (alpha, delta, and gamma-Bl-IC) and
MW-18D (bcta-BHC).
2. Simulation results represent average adsorption properties and calculated half lives.
3. Sirrrulation results represent baseline conditions requested by EPA during 5/14/96 meeting.
4. Simulation results represent average adsorption properties and sensitivity analysis of halflives ( +200 percent).
5. Simulation results represent slowest anticipated concentration decrease with time (sensitivity analysis of adsorption ( +50-60
percent) and half lives (+550 percent)).
Retardation factors vary due to chemical-specific partition coefficients and range in {., values.
Page 1 of J
•••••••••••••••••••••••••••••••••••••••••••••••••••••••
TABLE4
ESTJMA TED MAXIMUM CONCENTRATION TRENDS IN GROUNDWATER OVER TIME
LOWER BLACK CREEK AQUIFER
GEIGY CHEMICAL CORPORATION SITE
ABERDEEN, NORTH CAROLINA
I O Years1 4 Years 10 Years
Alpha BHC
1.5 year Half-Life & Retardation Factor= 5.32 6.0 0.79 <0.05
No Degradation & No Retardation 3 6.0 3.33 1.70
5 year Half-Life & Retardation Factor= 5.34 6.0 2.89 1.062
10 year Half-Life & Retardation FaclOr = 6.35 6.0 3.88 2.21
Beta BHC
1.5 year Half-Life & Retardation Factor= 5.J2 2.10 0.25 <0.05
-No Degradation & No Retardation 3 2.10 0.99 0.58
5 year Half-Life & Retardation Factor= 5.34 2.10 0.94 0.35
10 year Half-Life & Retardation Factor= 6.35 2.10 1.26 0.73
Delta BHC
1.5 year Half-Life & Retardation Factor= 82 4.90 0.59 <0.05
No Degradation & No Retardation 3 4.90 2.44 1.37
5 year Half-Life & Retardation Factor:::: 84 4.90 2. 18 0.85
IO year Half-Life & Retardation Factor= 105 4.90 2.91 1.75
GammaBHC
1.5 year Half-Life & Retardation Factor= 3.82 5.0 0.57 <0.20
No Degradation & No Retardation 3 5.0 2.88 1.61
5 year Half-Life & Retardation Factor:;:: 3.84 5.0 2.088 0.81
IO year Half-Life & Retardation Factor== 4.55 5.0 2.83 1.66
Notes:
I. Based on August 1995 and June 1996 sampling events. Maximum concentration measured in MW-27L.
2. Simulation results represent average adsorption properties and calculated half lives.
3. Simulation results represent baseline conditions requested by EPA during 5/14/96 meeting.
4. Simulation results represent average adsorption properties and sensitivity analysis of half lives ( +200 percent).
5. Simulation results represent slowest anticipated concentration decrease with time (sensitivity analysis of adsorption
(+50-60 percent) and half lives (+550 percent)).
Retardation factors vary due to chemical-specific partition coefficients and range in foe values.
Page I of I
20 Years
<0.05
0.43
0.21
0.89
<0.05
0.25
0.06
0.27
<0.05
0.43
0.18
0.75
<0.20
0.41
0.16
0.68
30 Years I
<0.05
<0.05
<0.05
0.37
<0.05
0.06
<0.05
0.11
<0.05
0.080
<0.05
0.33
<0.20
<0.20
<0.20
0.28
e • • • • • • • • • • 8 • • • • • • • • • e • • • • • • • • ., • • @ • • • • • • • ., .,
= • • • • • • • • • •
FIGURE 1
DOWNGRADIENT REMEDIAL ACTION
TENTH EVENT, THIRD QUARTER 2000
UPPER BLACK CREEK AQUIFER MONITORING RES UL TS
Geigy Chemical Corporation Site
Aberdeen, North Carolina
s Monitoring Wells
Stream
Road
I----+--+---<-Railroad
Q Pond
@ Swamp
This map is a product of the Pinnacle Consulting Group. Reasonable efforts have been
made to ensure the accuracy of this map. The Pinnacle Consulting Group expressly
disclaims any responsibmty or liability 'Mth regard to the use of this map. The Pinnacle
Consulting Group promotes and recommends the independent vertlication of any data
contained on this map by the user of this map product .
Date: September 11, 2000
Creator: CDT g:\gis\projects\novartis\geigy\av _projects\quarter1y\3q00\uppen::reek.apr
) ..
f2,
HW·
. alpha-BHC
beta-BHC
delta-BHC
THE PINNA.CLE CONSULTING GROUP
... .... -....... ,. .... -....... ";.'"'
.x=-----~
Hl/·2
alpha-BHC
beta-BHC
delta-BHC
Concentrat on
0.36
0.36
0.57
ug L
gar.ma-BHC (lindanel 0. 29
oncentrat1on ug/L
0.05
0.05
0.026 JI/
0.081
0.1
a-BHC
a-BHC
lta-BHC
, -BHC (lindanel
0
. a lpha-BHC
. beta-BHC
-.:• delta-BHC
Concentration
0.69
0.62
0.92
·.-gairma-BHC (L1ndanel 0.67
0 .097
0.026 J//
0.098
0.1 0.2
HW· 190
alpha-BHC
amna-BHC {Lrnclanel
. r· :
' j .
HW-300 Concentration ug/l
· alpha-BHC 0.67
,: beta-BHC 3.5
delta-BHC 0.55
Endrrn ketone 0.4 J//
gar.ma-BHC( ,L_,_M_a_oe_l_0_._JS ___ _J
: HW· 180
alpha-BHC
beta-BHC
Concentration
ug/L
fiN-2-40
alpha-BHC
• beta-BHC
: delta-Bl-IC
delta-BHC
Endri n ketone
· gaima-BHC {lindane)
~ -~-. -....
J-
Concentration ug/l
0.039 J//
0.032 J//
0.0075 J//
gaITTna-BHC (Lrndanel 0.034 JI/
0.3 0.4 Miles
0.9i'
2.)
0 .Bl
0.31 JI/
0.86
(
HW-230
alpha-Bl-IC
beta-BHC
: delta-Bl-IC
Concentration ug/L
, garna-BHC (L1ndane)
0.29
0.16
0.062
0.19
' l l
.)
Concentration
2
8.1
1.6
:• Endr1n ketone 0.63 J//
··.; gar.rna-BHC (Lrndanel 0.86
I
....... ---------------------------------------------------------------------, • • • • • • • • • 9 • • • • • • • • • • • • • ~ • • • • t)
t)
t)
@) • • • • • • • • • • • • • • • • • • • •
HW·32L Concentration ug/L
Non-Detect
"·"' ,,. ,.,,. . ...~ ...... , .. (A ,_ ,._,. . . . . .
.•• _ ~'l;. ~ '•
. '
,~:. --~,. :
··: ~ .
(L 1ndane)
Concentration
2
0.45
1.1
.• gattr.ld-BHC (L1ndane) 0.85
0.1 0
PZ· Concentrat on ug
0.-16 aiDha-BHC
eta-BHC
elta-BHC
a11T11a-BHC (Lind
oncentrat on ug
0.1
0.1
0 16
0.2
alpha-BHC
beta-BHC
, delta-BHC
lfli'·2Bl Concentratton ug/L
aloha-BHC 0.058
0.033 JI/
0.031 J//
0. 063
Concentration ug/L
11
3.4
5.6
(llndane) 9.5
gamna-BHC (Lindane)
03 0.4 Miles
/
-22l
Concentration ug/L
oncentrat on ug l
2.5
1.5
2.4
(L rndane} 2.3
I
THE PINNACLE CONSULTING GROUP
Facility
~ro erty
FIGURE 2
DOWNGRADIENT REMEDIAL ACTION
TENTH EVENT, THIRD QUARTER 2000
LOWER BLACK CREEK AQUIFER MONITORING RESULTS
s
Geigy Chemical Corporation Site
Aberdeen, North Carolina
Monitoring Well Pond
Streams Swamp
Road
Railroad
This map is a product of the Pinnacle Consulting Group. Reasonable efforts have been
made to ensure the accuracy of this map. The Pinnacle Coosulting Group expressly
disclaims any responsibility or liability 'Mth regard to the use of this map. The Pinnacie
Consulting Group promotes and recommends the independent verification of any data
contained on this map by the user of this map product
Date: September 13, 2000
Creator: CDT g:\gislprojects\novartis\geigy\av_projec'..s\quarter1y\3q00\lowercreek.apr . .__ ______________________________________________________________________ _
•
. ...------------------------------------------------------------, • • • • • • • • • • • • • • • • • • • • e • • • • • • • e
f) • • • • • • • • • • • • ~ • • • • • • • • •
SW-08
alpha-BHC
beta-BHC
delta-BHC
SW-07
alpha-BHC
beta-BHC
delta-BHC
alpha-BHC
beta-BHC
delta-BHC
SW·OS
alpha-BHC
beta-BHC
delta-BHC
Concentrat1on ug/L
O.OlSJ//
0.035 J//
0.024 JI/
' \'
' ·,, ·P.aries. '.
l'.-~a1<e ··
Concentration ug/l
0.018 JI/
0.043 J/1
0.029 JI/
SW-02
v
ug/L
0.03 J//
0 .063
0 .054
0.021 J//
Concentr11tion ug/L
alpha-BHC 0.032 JI/ ·r beta-BHC 0.075
. ~ delta-BHC 0.071
,. gamna-BHC {L1ndane) 0.03 JI/ ··,:-
' :·
' ,•;, -
'
\
Concentration ug/l
0
0.1 O 0.1 0.2 0.3 0.4 Miles ---==i----====----====i
/
• THE PINNACLE CONSULTING GROUP
Facility
Pro~rty
FIGURE 3
DOWNGRADIENT REMEDIAL ACTION
TENTH EVENT, THIRD QUARTER 2000
SURFACE WATER MONITORING RESULTS
Geigy Chemical Corporation Site
Aberdeen, North Carolina
S Surface Water Sampling Locations
Streams Pond
Road Swamp
Railroad
This map is a product of U,e Pinnacle Consulting Group. Reasonable efforts have been
made to ensure the accuracy of this map. The ?innacle Coosulting Group expressly
disclaims any responsibility or liability with regard to the use of this map. The Pinnade
Consulting Group promotes and recommends the independent verification of any data
contained on this map by the user of this map product.
Date: September 13, 2000
Creator: CDT g:lgislprojects\novartis\geigyl.av_projects\quarter1y\3q00\surfacewater.apr
•L----------------------------------------------------------------
• • (j
Cl • • ct • • • • 0
0
0 e
e ., .,
t) • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • •
UPPER BLACK CREEK AQUIFER
GROUNDWATER MONITORING RESULTS
THIRD QUARTER 2000
DOWNGRADIENT AREA
• • • • • • 8 • 0
D
0
0
0
0
0
0 • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • •
Lat-Sample # ••• : GOG250288-006
Date Sampled ... : 07/23/00
Prep Date ...... : 07/27/00
Prep Batch ff ••• : 0209462
PINNACLE CONSOLTmG GROUP
Client Sample ID.: Mli-l.lD
GC Semivolatiles
Work Order ff ••• : DGR9G101
Date Received .. : 07/25/00
Analysis Date .. : 08/03/00
Matrix ......... : WATER
,
Dilution Factor: 10 Method ......... : SW846 8081A
PARAMETER RESULT
Aldrin ND Q
alpha-BBC 2.0
beta-BHC 8. l.
delta-BHC 1.6
gamma-BHC (Lindane) 0.86
alpha-Chlordane ND
gamma-Chlordane ND
Dieldrin ND
4,4'-DDD ND
4,4 1 -DDE ND
4, 4' -DDT ND
Endrin ND
Endrin aldehyde ND
Endrin ketone 0.63 J
Endosulfan I ND
Endosulfan II ND
Endosulfan sulfate ND
Heptachlor ND
Heptachlor epoxide ND
Methoxychlor ND
Toxaphene ND
PERCENT
SURROGATE RECOVERY
Decachlorobiphenyl 106
Tetrachloro-m-xylene 93
NOTE(S):
Q Elevated rcponing limit. The reporting limit is elevated due to high analytc levels .
J Estimated result. Result is '™ lhan RL .
REPORTING
LIMIT UNITS MDL
0.50 ug/L 0.060
0.50 ug/L 0.080
0.50 ug/L 0.040
0.50 ug/L 0.060
0.50 ug/L 0. l.O
0.50 ug/L 0.070
0.50 ug/L 0.080
1.0 ug/L 0.20
1.0 ug/L 0.050
1. 0 ug/L 0.15
1.0 ug/L 0.20
1.0 ug/L 0.20
1.0 ug/L 0.29
1.0 ug/L 0.24
0.50 ug/L 0.10
1.0 ug/L 0.20
1. 0 ug/L 0.33
0.50 ug/L 0.070
0.50 ug/L 0.080
5.0 ug/L 0.40
20 ug/L 14
RECOVERY
LIMITS
(10 -146) t
(43 -110)
• • 0 • ct • • • • D
0
0
0
0
0 • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • •
PINNACLE CONSULTING GROUP
Client Sample ID: MW-18D
GC Semivolatiles
Lot-sample# ... : G0G250288-004 Work Order# ... : DGR9El01 Matrix ......... :
Date Sampled ... : 07 /23/00 Date Received .. : 07/25/00
Prep Date ...... : 07/27/00 Analysis Date .. : 08/03/00 / Prep Batch # ... : 0209462
Dilution Factor: 5 Method ••....... : SW846 8081A
PARAMETER RESULT
Aldrin ND Q
alpha-BHC 0.97
beta-BHC 2.7
delta-BHC 0.81
gamma-BHC (Lindane) 0.86
alpha-Chlordane ND
gamma-Chlordane ND
Dieldrin ND
4,4 1 -DDD ND
4,4'-DDE ND
4,4'-DDT ND
Endrin ND
Endrin aldehyde ND
Endrin ketone 0.31 J
Endosulfan I ND
Endosulfan II ND
Endosulfan sulfate ND
Heptachlor ND
Heptachlor epoxide ND
Methoxychlor ND
Toxaphene ND
PERCENT
SURROGATE RECOVERY
Decachlorobiphenyl 106
Tetrachloro-m-xylene 86
NOTE (SJ:
Q Elevated reporting limit. The reponing limit is elev.ated due IO h.igh .:malytc levels .
J Estimated result. Result is less than RL,
REPORTING
LIMIT UNITS MDL
0.25 ug/L 0.030
0.25 ug/L 0.040
0.25 ug/L 0.020
0.25 ug/L 0.030
0.25 ug/L 0.050
0.25 ug/L 0.035
0.25 ug/L 0.040
0.50 ug/L 0.10
0.50 ug/L 0.025
0.50 ug/L 0.075
0.50 ug/L 0. 10
0.50 ug/L 0.10
0.50 ug/L 0 .14
0.50 ug/L 0.12
0.25 ug/L 0.050
0.50 ug/L 0.10
a.so ug/L 0.16
0.25 ug/L 0.035
0.25 ug/L 0.040
2.5 ug/L 0.20
10 ug/L 7.0
RECOVERY
LIMITS
(10 -146) I
(43 -110)
WATER
• ct • • • • • • • • • • • • ct • 0
0
0
0
0
0
0
0
0
0
0
0
0 • • • • .,
• • • ., ., ., • • • • • • • • • • • • • • •
Lot-Sample# ... : GOG250283-012
Date Sampled ... : 07/21/00
Prep Date ...... : 07/27/00
Prep Batch# ... : 0209449
Dilution Factor: 1
PARAMETER
Aldrin
alpha-BHC
beta-BHC
delta-BHC
gamma-BHC (Lindane)
alpha-Chlordane
gamma-Chlordane
Dieldrin
4,4'-DDD
4, 4' -DDE
4,4 1 -DDT
Endrin
Endrin aldehyde
Endrin ketone
Endosulfan I
Endosulfan II
Endosulfan sulfate
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
SURROGATE
Decachlorobiphenyl
Tetrachloro-m-xylene
NOTE(S):
J Estimated rczulL Rcsuil is less llw, RL .
PINNACLE CONSULTING GROUP
Client Sample ill: MW-19D
GC Semivolatiles .
Work Order# ... : DGR8Ml01
Date Received .. : 07/25/00
Analysis Date .. : 08/03/00
Matrix ......... : WATER
Method ......... : SW846 8081A
REPORTING
RESULT LIMIT UNITS MDL ·'"''
ND 0.050 ug/L 0.0060
0.031 J 0.050 ug/L 0.0080
ND 0.050 ug/L 0. 004 0
ND 0.050 ug/L 0.0060
0.037 J 0.050 ug/L 0.010
ND 0.050 ug/L 0.0070
ND 0.050 ug/L 0.0080
ND 0.10 ug/L 0. 020
ND 0.10 ug/L 0.0050
ND 0.10 ug/L 0.015
ND 0.10 ug/L 0.020
ND 0.10 ug/L 0.020
ND 0.10 ug/L 0.029
ND 0.10 ug/L 0.024
ND 0.050 ug/L 0.010
ND 0 .10 ug/L 0.020
ND 0.10 ug/L 0.033
ND 0.050 ug/L 0.0070
ND 0.050 ug/L 0.0080
ND a.so ug/L 0.040
ND 2.0 ug/L l. 4
PERCENT RECl)VERY
RECOVERY LIMITS
56 (10 146)
62 (43 -110)
• • • • 0 • • • • • • 0
0 • • 0
0
0
0
0
0
0
0
0
0
0
0 • • • • • • • • • t) • • • I)
I)
I) • • • • • • • • • • •
Lot-Sample II. .. :
Date Sampled ... :
Prep Date ...... :
Prep Batch ff ••• :
Dilution Factor:
PARAMETER
Aldrin
alpha-BHC
beta-BBC
delta-BBC
GOG250288-003
07/22/00
07/27/00
0209462
5
gamma-BBC (Lindane)
alpha-Chlordane
gamma-Chlordane
Dieldrin
4, 4 1 -DDD
4,4 1 -DDE
4,4'-DDT
Endrin
Endrin aldehyde
Endrin ketone
Endosulfan I
Endosulfan II
Endosulfan sulfate
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
SURROGATE
Decachlorobiphenyl
Tetrachloro-m-xylene
NOTE(S):
PINNACLE CONSOLTING GROUP
Client Sample ID: MW-20D
GC Semivolatiles
Work Order# ... : DGR9Cl01
Date Received .. : 07/25/00
Analysis Date .. : 08/03/00
Matrix ......... : WATER
Method ......... : SW846 8081A
REPORTING
RESULT LIMIT UNITS MDL
ND Q 0.25 ug/L 0.030
0.69 0.25 ug/L 0.040
0.62 0.25 ug/L 0.020
0.92 0.25 ug/L 0.030
0.67 0.25 ug/L 0.050
ND 0.25 ug/L 0.035
ND 0.25 ug/L 0. 040
ND 0.50 ug/L 0.10
ND 0.50 ug/L 0.025
ND a.so ug/L 0.075
ND 0.50 ug/L 0.10
ND 0.50 ug/L 0.10
ND 0.50 ug/L 0 .14
ND 0.50 ug/L 0.12
ND 0.25 ug/L 0.050
ND 0.50 ug/L 0.10
ND 0.50 ug/L 0.16
ND 0.25 ug/L 0.035
ND 0.25 ug/L 0.040
ND 2.5 ug/L 0.20
ND 10 ug/L 7. 0
PERCENT RECOVERY
RECOVERY LIMITS
110 (10 -146)
85 (43 110) ,, -
Q Elevated reporting limit. The rcponing limit is elevated due t0 high an.alyte lc...els .
• • 0 • • • • • 0 • • 0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0 • • • • • .,
• • • • • • • • • • • • • • • • • • • • • •
Lat-Sample# ... : G0G220162-012
Date Sampled ... : 07/20/00
Prep Date ...... : 07/26/00
Prep Batch# ... : 0208179
Dilution Factor: l
PARAMETER
Aldrin
alpha-BHC
beta-BHC
delta-BHC
ganuna-BHC (Lindane)
alpha-Chlordane
gamma-Chlordane
Dieldrin
4, 4' -DOD
4,4'-DDE
4,4'-DDT
Endrin
Endrin aldehyde
Endrin ketone
Endosulfan I
Endosulfan II
Endosulfan sulfate
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
SURROGATE
Decachlorobiphenyl
Tetrachloro-m-xylene
NOTE (S) :
PINNACLE CONSULTING GROUP
Client Sample ID: MW-22D
GC Semivolatiles
Work Order# ... : DGN9Wl01
Date Received .. : 07/22/00
Analysis Date .. : 08/11/00
Matrix ......... : WATER
Method ......... : SW846 8081A
REPORTING
RESULT LIMIT UNITS MDL
ND V 0.056 ug/L 0.0060
0.36 0.056 ug/L 0.0080
0.36 0.056 ug/L 0.0040
0.57 0.056 ug/L 0.0060
0.29 0.056 ug/L 0.010
ND 0.056 ug/L 0.0070
ND 0.056 ug/L 0.0080
ND 0 .11 ug/L 0.020
ND 0 .11 ug/L 0.0050
ND 0.11 ug/L 0.015
ND 0.11 ug/L 0.020
ND 0 .11 ug/L 0.020
ND 0 .11 ug/L 0.029
ND 0 .11 ug/L 0.024
ND 0.056 ug/L 0.010
ND 0 .11 ug/L 0.020
ND 0 .11 ug/L 0.033
ND 0.056 ug/L 0.0070
ND 0.056 ug/L 0.0080
ND 0.56 ug/L 0.040
ND 2.2 ug/L 1.4
PERCENT RECOVERY
RECOVERY LIMITS
53 (10 -146)
64 (43 -110)
V Elcv1m:d rt:porting limit. The rcponing limit is ckv:itc:d due to limittd sample: volume .
• • • • • • • 8
0 • • 0
0
0
0
0
0
0
0
0
0 e
0
0
0
0 • • • • • • • • • • • • • • • • • • • • • • • • • • • • •
Lot-Sample IL .. , GOG250283-014
Date Sampled ... , 07/22/00
Prep Date ...... : 07/27/00
Prep Batch It ••• : 0209449
Dilution Factor: 1
PARAMETER
Aldrin
alpha-BBC
beta-BHC
delta-BHC
gamma-BHC (Lindane)
alpha-Chlordane
gamma-Chlordane
Dieldrin
4, 4' -DDD
4,4'-DDE
4,4 1 -DDT
Endrin
Endrin aldehyde
Endrin ketone
Endosulfan I
Endosulfan II
Endosulfan sulfate
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
SURROGATE
Decachlorobiphenyl
Tetrachloro-m~xylene
PINNACLE CONSULTING GROUP
Client Sample ID, MW-23D
GC Semivolatiles
Work Order II ... , DGR8Ql01 Matrix ......... , WATER
Date Received .. : 07/25/00
Analysis Date .. : 08/04/00
Method ......... : SW846 8081A
REPORTING
RESULT LIMIT UNITS MDL
ND 0.050 ug/L 0.0060
0.29 0.050 ug/L 0.0080
0.16 0.050 ug/L 0.0040
0.062 0.050 ug/L 0.0060
0. 19 0.050 ug/L 0.010
ND 0.050 ug/L 0.0070
ND 0.050 ug/L 0.0080
ND 0.10 ug/L 0.020
ND 0.10 ug/L 0.0050
ND 0.10 ug/L 0.015
ND 0.10 ug/L 0.020
ND 0.10 ug/L 0.020
ND 0.10 ug/L 0.029
ND 0.10 ug/L 0.024
ND 0.050 ug/L 0.010
ND 0.10 ug/L 0.020
ND 0.10 ug/L 0.033
ND 0.050 ug/L 0.0070
ND 0.050 ug/L 0.0080
ND 0.50 ug/L 0.040
ND 2.0 ug/L 1.4
PERCENT RECOVERY
RECOVERY LIMITS
87 (10 -146)
59 (43 -110)
• • • G
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0 • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • •
Lot-Sample# ... : GOG250288-008
Date Sampled ... : 07/22/00
Prep Date __ .... : 07/27/00
Prep Batch ll ... : 0209462
Dilution Factor: 1
PARAMETER
Aldrin
alpha-BHC
beta-BHC
delta-BHC
gamma-BHC (Lindane)
alpha-Chlordane
gamma-Chlordane
Dieldrin
4,4'-DDD
4,4 1 -DDE
4,4' -DDT
Endrin
Endrin aldehyde
Endrin ketone
Endosulfan I
Endosulfan II
Endosulfan sulfate
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
SURROGATE
Decachlorobiphenyl
Tetrachloro-m-xylene
NOTE (S) ,
J EstimalCd rcsulL R~ult ~ k:;:o; than RL .
PINNACLE CONSULTING GROUP
Client Sample ID: MW-24D
GC Semivolatiles
Work Order# ... , DGR9N101
Date Received .. : 07/25/00
Analysis Date .. , 08/03/00
Matrix ......... ; WATER
Method ......... ' SW846 8081A
REPORTING
RESULT LIMIT UNITS MDL
ND 0.050 ug/L 0.0060
0.039 J 0.050 ug/L 0.0080
0.032 J 0.050 ug/L 0.0040
0.0075 J 0.050 ug/L 0.0060
0.034 J 0.050 ug/L 0.010
ND 0.050 ug/L 0.0070
ND 0.050 ug/L 0.0080
ND 0.10 ug/L 0.020
ND 0.10 ug/L 0.0050
ND 0.10 ug/L 0.015
ND 0 .10 ug/L 0. 020
ND 0 .10 ug/L 0.020
ND 0.10 ug/L 0.029
ND 0.10 ug/L 0.024
ND 0.050 ug/L 0.010
ND 0.10 .ug/L 0.020
ND 0.10 ug/L 0.033
ND 0.050 ug/L 0.0070
ND 0.050 ug/L 0.0080
ND 0.50 ug/L 0. 040
ND 2.0 ug/L 1.4
PERCENT RECOVERY
RECOVERY LIMITS
101 (10 146)
71 (43 -110)
• • • • • • • • • • • 0
0
0
0
0
0
0
0
0 e ., ., • • • • • • • • • • • f)
f) • • • • • • • • • • • • • • • • •
Lot-Sample # ... : GOG250288-002
Date Sampled •.. : 07/22/00
Prep Date ...... : 07/27/00
Prep Batch fl ••. : 0209462
Dilution Factor: l
PARAMETER
Aldrin
alpha-BHC
beta-BHC
delta-BHC
gamma-BHC (Lindane)
alpha-Chlordane
gamma-Chlordane
Dieldrin
4, 4' -DDD
4,4'-DDE
4,4'-DDT
Endrin
Endrin aldehyde
Endrin ketone
Endosulfan I
Endosulfan II
Endosulfan sulfate
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
SURROGATE
Decachlorobiphenyl
Tetrachloro-m-xylene
PINNACLE CONSULTING GROUP
Client Sample ID: MW-25D
GC Semivolatiles
Work Order # ... : DGR9Al0l Matrix ......... : WATER
Date Received .. : 07/25/00
Analysis Date .. : 08/03/00 ✓
Method ......... : SW846 8081A
REPORTING
RESULT LIMIT UNITS MDL
ND 0.050 ug/L 0.0060
ND 0.050 ug/L 0.0080
ND 0.050 ug/L 0. 004 0
ND 0.050 ug/L 0.0060
ND 0.050 ug/L 0.010
ND 0.050 ug/L 0,0070
ND 0.050 ug/L 0.0080
ND 0.10 ug/L 0.020
ND 0.10 ug/L 0.0050
ND 0.10 ug/L 0.015
ND 0.10 ug/L 0.020
ND 0.10 ug/L 0.020
ND 0.10 ug/L 0.029
ND 0.10 ug/L 0.024
ND 0.050 ug/L 0.010
ND 0.10 ug/L 0.020
ND 0.10 ug/L 0.033
ND 0.050 ug/L 0.0070
ND 0.050 ug/L 0.0080
ND 0.50 ug/L 0.040
ND 2.0 ug/L l. 4
PERCENT RECOVERY
RECOVERY LIMITS
28 (10 -146) I 70 (43 -110)
(t • • • • • • • 0 • G
0 • 0
0
0
0
0
0
0
0
0
0
0
0
0
0 .,
t)
t)
t)
t)
t)
t)
f)
I)
I)
I)
f) • • • • • • • • • • • • • • • •
Lat-Sample# ... : GOG250283-009
Date sampled ... : 07/21/00
Prep Date ...... : 07 /27 /00
Prep Batch# ... : 0209449
Dilution Factor: l
PARAMETER
Aldrin
alpha-BBC
beta-BBC
delta-BBC
gamma-BBC (Lindane)
alpha-Chlordane
gamma-Chlordane
Dieldrin
4,4'-DDD
4,4'-DDE
4,4'-DDT
Endrin
Endrin aldehyde
Endrin ketone
Endosulfan I
Endosulfan II
Endosulfan sulfate
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
SURROGATE
Decachlorobiphenyl
Tetrachloro-m-xylene
NOTE (S) :
J Estima1ed result. Resul1 is less than RL .
PINNACLE CONSULTDIG GROUP
Client Sample ID: MW-26D
GC Semivolatiles
Work Order# ... : DGR8J101
Date Received .. : 07/25/00
Analysis Date .. : 08/04/00
Matrix ......... : WATER
Method ......... : SW846 8081A
REPORTING
RESULT LIMIT UNITS MDL
ND 0.050 ug/L 0.0060
0.050 0.050 ug/L 0.0080
0.050 0.050 ug/L 0.0040
0.026 J 0.050 ug/L 0.0060
0.081 0.050 ug/L 0.010
ND 0.050 ug/L 0.0070
ND 0.050 ug/L 0.0080
ND 0.10 ug/L 0.020
ND 0.10 ug/L 0.0050
ND 0.10 ug/L 0. 015
ND 0.10 ug/L 0.020
ND 0.10 ug/L 0. 020
ND 0 .10 · ug/L 0.029
ND 0.10 ug/L 0.024
ND 0.050 ug/L 0.010
ND 0.10 ug/L 0.020
ND 0.10 ug/L 0.033
ND 0.050 ug/L 0.0070
ND 0.050 ug/L 0.0080
ND 0.50 ug/L 0. 040
ND 2.0 ug/L 1.4
PERCENT RECOVERY
RECOVERY LIMITS
90 (10 -146)
66 (43 -110)
• . ~----------------------
• 0
0
Lot-Sample# ... : GOG250288-005
Date Sampled ... : 07/23/00
Prep Date ...... : 07/27/00
Prep Batch# ... : 0209462
PINNACLE CONSULTING GROUP
Client Sample ID: MW-30D
GC Sernivolatiles
Work Order# ..• : DGR9Fl01
Date Received .. : 07/25/00
Analysis Date .. : 08/03/00
-tri>c ......... : WATER
/
0
0 a
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Dilution Factor: 5 Method ......... : SW846 8081A
• 0 • • • • • • • • • • • • • • • • • • • • • • • • • • • • •
PARAMETER RESULT
Aldrin ND Q
alpha-BHC 0.67
beta-BHC 3.5
delta-BHC 0.55
gannoa-BHC (Lindane) 0.35
alpha-Chlordane ND
gamma-Chlordane ND
Dieldrin ND
4,4 1 -DDD ND
4,4 1 -DDE ND
4,4 1 -DDT ND
Endrin ND
Endrin aldehyde ND
Endrin ketone 0.40 J
Endosulfan I ND
Endosulfan II ND
Endosulfan sulfate ND
Heptachlor ND
Heptachlor epoxide ND
Methoxychlor ND
Toxaphene ND
PERCENT
SURROGATE RECOVERY
Decachlorobiphenyl 112
Tetrachloro-m-xylene 89
NOTE (S) :
Q Elevated reporting limit. 1bc reporting limit is elevated due to high ana!yte levels .
J Estimated result. Re£Ult is less (ruin RL
REPORTING
LIMIT UNITS MDL
0.25 ug/L 0.030
0.25 ug/L 0.040
0.25 ug/L 0.020
0.25 ug/L 0.030
0.25 ug/L 0.050
0.25 ug/L 0.035
0.25 ug/L 0. 040
a.so ug/L 0.10
0.50 ug/L 0.025
0.50 ug/L 0.075
0.50 ug/L 0.10
0.50 ug/L 0.10
0.50 ug/L 0.14
0.50 ug/L 0.12
0.25 ug/L 0.050
0.50 ug/L 0.10
0.50 ug/L 0.16
0.25 ug/L 0.035
0.25 ug/L 0.040
2.5 ug/L 0.20
10 ug/L 7.0
RECOVERY
LIMITS
(10 -146) I (43 -llO)
• • • • • • • e
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0 • • e • • • • • • • • • • • • • • • • • • • • • • • •
Lot-Sample# ... : GOG250283-0l3
Date Sampled ... : 07/22/00
Prep Date ...... : 07/27/00
Prep Batch# ... : 0209449
Dilution Factor: 1
PARAMETER
Aldrin
alpha-BHC
beta-BBC
delta-BHC
gamma-BHC (Lindane)
alpha-Chlordane
gamma-Chlordane
Dieldrin
4, 4' ·DDD
4, 4' ·DDE
4,4'-DDT
Endrin
Endrin aldehyde
Endrin ketone
Endosulfan I
Endosulfan II
Endosulfan sulfate
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
SURROGATE
Decachlorobiphenyl
Tetra,chloro-m-xylene
NOTE(S):
J Estl.Jt111ted rcsulL Result U le.u thnn RL.
PINNACLE CONSULTING GROUP
Client Sample ID: Ml'l-34D
GC Semivolatiles
Work Order# ... : DGR8Pl0l
Date Received .. : 07/25/00
Analysis Date .. : 08/03/00
Matrix ......... , WATER
Method ......... , SWB46 8081A
REPORTING
RESULT LIMIT UNITS MDL
ND 0.050 ug/L 0.0060
ND 0.050 ug/L 0.0080
0.043 J 0.050 ug/L 0. 0040
ND 0.050 ug/L 0.0060
ND 0.050 ug/L 0.010
ND 0.050 ug/L 0.0070
ND 0.050 ug/L 0.0080
ND 0.10 ug/L 0.020
ND 0.10 ug/L 0.0050
ND 0.10 ug/L 0.015
ND 0.10 ug/L 0.020
ND 0.10 ug/L 0. 020
ND 0.10 ug/L 0.029
ND 0.10 ug/L 0.024
ND 0.050 ug/L 0.010
ND 0.10 ug/L 0.020
ND 0.10 ug/L 0.033
ND 0.050 ug/L 0.0070
ND 0.050 ug/L 0. 008 0
ND 0.50 ug/L 0.040
ND 2.0 ug/L l. 4
PERCENT RECOVERY
RECOVERY LIMITS
75 (10 -146)
60 (43 -110)
• • • • 0 • G • G
G ..
G
G
G
0
0
0
0
0
0
0
0
0
0 • 0 • • • • • • • • I)
I)
I)
I) • • • • • • • • • • • • • • • • •
Lot-Sample# ... : GOG220162-015
Date Sampled ... : 07/21/00
Prep Date ...... : 07/26/00
Prep Batch# ... : 0208179
Dilution Factor: 1
PARAMETER
Aldrin
alpha-BHC
beta-BHC
delta-BHC
gamma-BHC (Lindane)
alpha-Chlordane
gamma-Chlordane
Dieldrin
4, 4' -ODD
4,4' -DOE
4,4'-DDT
Endrin
Endrin aldehyde
Endrin ketone
Endosulfan I
Endosulfan II
Endosulfan sulfate
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
SURROGATE
Decachlorobiphenyl
Tetrachloro-m-xylene
NOTE (S) :
J Estimated rcsulL Result is less than RL .
PINNACLE CONSULTING GROUP
Client Sample ID: MW-35D
GC Semivolatiles
Work Order# ... : DGNA1101
Date Received .. : 07/22/00
Analysis Date .. : 08/11/00
Matrix ......... : WATER
Method ......... : SW846 8081A
REPORTING
RESULT LIMIT UNITS MDL
ND 0.050 ug/L 0.0060
0.15 0. 050 ug/L 0.0080
0.097 0.050 ug/L 0. 0040
0.026 J 0.050 ug/L 0.0060
0.098 0.050 ug/L 0.010
ND 0.050 ug/L 0.0070
ND 0.050 ug/L 0.0080
ND 0.10 ug/L 0.020
ND 0.10 ug/L 0.0050
ND 0.10 ug/L 0.015
ND 0.10 ug/L 0.020
ND 0.10 ug/L 0.020
ND 0.10 ug/L 0.029
ND 0.10 ug/L 0.024
ND 0.050 ug/L 0.010
ND 0.10 ug/L 0.020
ND 0.10 ug/L 0.033
ND 0.050 ug/L 0.0070
ND 0.050 ug/L 0.0080
ND 0.50 ug/L 0.040
ND 2.0 ug/L 1.4
PERCENT RECOVERY
RECOVERY LIMITS
67 (10 -146)
62 (43 -· 110)
(t • • ct • C, • 0
0
0
0 • e
e • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • •
LOWER BLACK CREEK AQUIFER
GROUNDWATER MONITORING RESULTS
THIRD QUARTER 2000
DOWNGRADIENT AREA
• • • 0 • e ., .,
• • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • , . • • • • • •
Lot-Sample# ... : GOG220162-013
Date Sampled ... : 07/20/00
Prep Date ...... : 07/26/00
Prep Batch# ... : 0208179
Dilution Factor: 5
PARAMETER
Aldrin
alpha-BHC
beta-BHC
delta-BHC
gamma-BHC (Lindane)
alpha-Chlordane
gamma-Chlordane
Dieldrin
4, 4 1 -DDD
4,4'-DDE
4, 4' -DDT
Endrin
Endrin aldehyde
Endrin ketone
Endosulfan I
Endosulfan II
Endosulfan sulfate
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
SURROGATE
Decachlorobiphenyl
Tetrachloro-m-xylene
NarE (S) :
• Surrog11tc recovery is outside stated control limits .
PINNACLE CONSULTING GROUP
Client Sample ID: MW-22L
GC Semivolatiles
Work Order# ... : DGN9Xl01
Date Received.·.: 07 /22/00
Analysis Date .. : 08/11/00
Matrix ......... : WATER
Method ......... : SW846 8081A
REPORTING
RESULT LIMIT UNITS MDL
ND Q 0.25 ug/L 0.030
2.5 0.25 ug/L 0.040
1.5 0.25 ug/L 0.020
2.4 0.25 ug/L 0.030
2.3 0.25 ug/L 0.050
ND 0.25 ug/L 0.035
ND 0.25 ug/L 0.040
ND a.so ug/L 0.10
ND a.so ug/L 0.025
ND a.so ug/L 0.075
ND a.so ug/L 0.10
ND 0.50 ug/L 0.10
ND a.so ug/L 0.14
ND 0.50 ug/L 0.12
ND 0.25 ug/L 0.050
ND a.so ug/L 0.10
ND a.so ug/L 0 .16
ND 0.25 ug/L 0.035
ND 0.25 ug/L 0.040
ND 2.5 ug/L 0.20
ND 10 ug/L 7.0
PERCENT RECOVERY
RECOVERY LIMITS
80 (10 -146)
42 • (43 -llO) o"
Q Elevated rcponing limiL The reponing limit is elevated due to high analytc levels .
ct
8 • 0
0
0
0
0 • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • •
Lat-Sample # ... : GOG250283-005
Date Sampled ... : 07/22/00
Prep Date ...... : 07/27/00
Prep Batch# ... : 0209449
Dilution Factor: 5
PARAMETER
Aldrin
alpha-BBC
beta-BBC
delta-BBC
gamma-BBC (Lindane)
alpha-Chlordane
gamma-Chlordane
Dieldrin
4,4' -DDD
4, 4 1 -DDE
4,4'-DDT
Endrin
Endrin aldehyde
Endrin ketone
Endosulfan I
Endosulfan II
Endosulfan sulfate
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
SURROGATE
Decachlorobiphenyl
Tetrachloro-m-xylene
NOTE(S):
PINNACLE CONSULTING GROUP
Client Sample ID: MW-25L
GC Semi.volatiles
Work Order # ... : DGR8El01
Date Received .. : 07/25/00
Analysis Date .. : 08/04/00
Matrix ......... : WATER
Method .•....... : SW846 8081A
REPORTING
RESULT LIMIT UNITS MDL
ND Q 0.25 ug/L 0.030
3.4 0.25 ug/L 0.040
0.56 0.25 ug/L 0.020
1.2 0.25 ug/L 0.030
2.9 0.25 ug/L 0.050
ND 0.25 ug/L 0.035
ND 0.25 ug/L 0.040
ND 0.50 ug/L 0.10
ND 0.50 ug/L 0.025
ND 0.50 ug/L 0.075
ND 0.50 ug/L 0.10
ND 0.50 ug/L 0.10
ND 0.50 ug/L 0.14
ND 0.50 ug/L 0.12
ND 0.25 ug/L 0.050
ND 0.50 ug/L 0.10
ND 0.50 ug/L 0.16
ND 0.25 ug/L 0.035
ND 0.25 ug/L 0.040
ND 2.5 ug/L 0.20
ND 10 ug/L 7.0
PERCENT RECOVERY
RECOVERY LIMITS
113 (10 -146)
76 (43 -110)
Q Eleva1ed reporting limit. The rcponing limit is e!eva!OO due co high analytc levels .
Cl • • 0
0
0
0 • • • .,
• • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • •
PINNACLE CONSULTING GROUP
Client Sample ID: MW-27L
GC Semivolatiles
Lot-Sample lt ... : G0G220162-014 Work Order lt ... : DGNA0101 Matrix ......... : WATER
Date Sampled ... : 07/20/00 Date Received._: 07/22/00
Prep Date ...... : 07/26/00 Analysis Date .. : 08/11/00
Prep Batch lt ... : 0208179
Dilution Factor: 20 Method ......... : SW846 8081A
REPORTING
PARAMETER RESULT LIMIT
Aldrin ND Q,V 1.1
alpha-BBC 11 1.1
beta-BBC 3.4 1.1
delta-BBC 5.6 1.1
ganuna-BBC (Lindane) 9.5 1.1
alpha-Chlordane ND 1.1
gamma-Chlordane ND 1.1
Dieldrin ND 2.3
4,4'-DDD ND 2.3
4,4' -DDE ND 2.3
4, 4' -DDT ND 2.3
Endrin ND 2.3
Endrin aldehyde ND 2.3
Endrin ketone ND 2.3
Endosulfan I ND 1.1
Endosulfan II ND 2.3
Endosulfan sulfate ND 2.3
Heptachlor ND 1.1
Heptachlor epoxide ND 1.1
Methoxychlor ND 11
Toxaphene ND 46
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Decachlorobiphenyl 0.0 SRD ,"" (10 146)
Tetrachloro-m-xylene 0.0 SRD (43 -110)
NOTE (S):
SRO The surrogate recovery was not calculated because the extract wns diluted beyond the ability w quan1itatc 11, recovery .
Q Elevated rcponing limit. TI1c reporting limit is el,;vatcd due lo high analyte levels .
V Ekv:ncd reporting limil. The reporting limit is elevated due lo limited sample volume .
UNITS MDL
ug/L 0.12
ug/L 0.16
ug/L 0.080
ug/L 0.12
ug/L 0.20
ug/L 0.14
ug/L 0.16
ug/L 0.40
ug/L 0.10
ug/L 0.30
ug/L 0. 4 0
ug/L 0.40
ug/L 0.58
ug/L 0.48
ug/L 0.20
ug/L 0.40
ug/L 0.66
ug/L 0.14
ug/L 0.16
ug/L 0.80
ug/L 28
G
0
0 ., .,
• • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • •
Lot-Sample ·11 ••• : G0G250288-001
Date Sampled ... : 07/22/00
Prep Da.te ...... : 07/27/00
Prep Batch II ... : 0209462
Dilution Factor: 1
PARAMETER
Aldrin
alpha-BHC
beta-BBC
delta-BBC
ganuna-BHC (Lindane)
alpha·Chlordane
gamma-Chlordane
Dieldrin
4, 4 '-ODD
4,4'-DDE
4,4 1 -DDT
Endrin
Endrin aldehyde
Endrin ketone
Endosulfan I
Endosulfan II
Endosulfan sulfate
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
SURROGATE
Decachlorobiphenyl
Tetrachloro·m·xylene
NOTE{S):
J Estimated resull. Re.suit is less than RL
PINNACLE CONSOLTING GROUP
Client sample ID: MW-28L
GC Semivolatiles
work Order ff ••• : DGR97101 Matrix ......... : WATER
Date Received .. : 07/25/00
Analysis Date .. : 08/03/00
Method ....•..•. : SW846 8081A
REPORTING
RESULT LIMIT UNITS MDL
ND 0.050 ug/L 0.0060
0.058 0.050 ug/L 0.0080
0.033 J 0.050 ug/L 0. 0040
0.031. J 0.050 ug/L 0.0060
0.063 0.050 ug/L O.Ol.O
ND 0.050 ug/L 0.0070
ND 0.050 ug/L 0.0080
ND 0. l.O ug/L 0.020
ND 0.10 ug/L 0.0050
ND 0.10 ug/L 0.015
ND 0.10 ug/L 0.020
ND 0.10 ug/L 0.020
ND 0.10 ug/L 0.029
ND 0.10 ug/L 0.024
ND 0.050 ug/L 0.010
ND 0.10 ug/L 0.020
ND 0.10 ug/L 0.033
ND 0.050 ug/L 0.0070
ND 0.050 ug/L 0.0080
ND 0.50 ug/L 0. 040
ND 2.0 ug/L 1.4
PERCENT RECOVERY
RECOVERY LIMITS
99 (10 . 146)
74 {43 -110)
• • G
0
0
0
0 e • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • •
Lot-Sampl.e ll. .. : GOG250283-001
Date Sampled ... : 07/21/00
Prep Date ...... : 07/27/00
Prep Batch # ... : 0209449
Dilution Factor: 10
PARAMETER
Aldrin
alpba-BHC
beta-BHC
delta-BHC
gamma-BHC (Lindane)
alpha-Chlordane
gamma-Chlordane
Dieldrin
4,4'-DDD
4, 4 '-DDE
4 1 4 1 -DDT
Endrin
Endrin aldehyde
Endrin ketone
Endosulfan I
Endosulfan II
Endosulfan sulfate
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
SURROGATE
Decachlorobiphenyl
Tetrachloro-m-xylene
NOTE (S) :
PINNACLE CONSOLTING GROUP
Cl.ient Sampl.e ID: MW-31.L
GC Semivolatiles
Work Order # ••• : DGR88101PR
Date Received .. : 07/25/00
Analysis Date .. : 08/04/00
Matrix ......... : WATER
Method ..•...... : SW846 8081A
REPORTING
RESULT LIMIT UNITS MDL
ND Q 0.50 ug/L 0.060
2.7 0.50 ug/L 0.080
0.82 0.50 ug/L 0. 040
1.5 0.50 ug/L 0.060
1. 7 0.50 ug/L 0. l.O
ND 0.50 ug/L 0.070
ND 0.50 ug/L 0.080
ND 1. 0 ug/L 0.20
ND 1.0 ug/L 0.050
ND 1.0 ug/L 0.15
ND 1. 0 ug/L 0.20
ND 1. 0 ug/L 0.20
ND 1.0 ug/L 0.29
ND 1.0 ug/L 0.24
ND 0.50 ug/L 0.10
ND 1. 0 ug/L 0.20
ND 1.0 ug/L 0.33
ND 0.50 ug/L 0.070
ND 0.50 ug/L 0.080
ND 5.0 ug/L 0.40
ND 20 ug/L 14
PERCENT RECOVERY
RECOVERY LIMITS
92 (10 -146)
76 (43 -llO)
Q Elevated reponiog limit. The reporting limit is elevated due 10 high amlyte levels .
• • 0 • • • • • • • • • • • • • • • • 0
0
0
0 • • • • • • • • • • • • • • • • • • • • • • • • • • • • • •
Lot-Sample# ... : GOG250288-007
Date Sampled ... : 07/22/00
Prep Date ...... : 07/27/00
Prep Batch# ... : 0209462
PINNACLE CONSULTING GROUP
Client Sample ID: MW-32L
GC Semivolatiles
Work Order# ... : DGR9J101
Date Received .. : 07/25/00
Analysis Date .. : 08/03/oo·
Matrix ......... : WATER
Dilution Factor: 5 Method •........ : SW846 8081A
PARAMETER RESULT
Aldrin ND
alpha-BHC ND
beta-BHC ND
delta-BHC ND
gamma-BHC (Lindane) ND
alpha-Chlordane ND
gamma-Chlordane ND
Dieldrin ND
4,4'-DDD ND
4,4'-DDE ND
4,4'-DDT ND
Endrin ND
Endrin aldehyde ND
Endrin ketone ND
Endosulfan I ND
Endosulfan II ND
Endosulfan sulfate ND
Heptachlor ND
Heptachlor epoxide ND
Methoxychlor ND
Toxaphene ND
PERCENT
SURROGATE RECOVERY
Decachlorobiphenyl 54
Tetrachloro-m-xylene 114 * c,"
NOTE (S) :
* Surrogace recovery is ouuide st.:ua:i COIUrol limits .
The surrog:itc recoYery in the sample is outside eorirol limits due 10 confirmed mauix c:ffea .
Elevated reporting limits. The reporting limits are elevated due to matrix interference .
REPORTING
LIMIT UNITS MDL
0.25 ug/L 0.030
0.25 ug/L 0.040
0.25 ug/L 0.020
0.25 ug/L 0.030
0.25 ug/L 0.050
0.25 ug/L 0.035
0.25 ug/L 0.040
0.50 ug/L 0 .10
0.50 ug/L 0.025
0.50 ug/L 0.075
0.50 ug/L 0.10
0.50 ug/L 0.10
a.so ug/L 0.14
0.50 ug/L 0.12
0.25 ug/L 0.050
0.50 ug/L 0.10
0.50 ug/L 0.16
0.25 ug/L 0.035
0.25 ug/L 0. 040
2.5 ug/L 0.20
10 ug/L 7.0
RECOVERY
LIMITS
(10 -146)
(43 -110)
Q
0
0
0 ., .,
• • • • • • • • • • Cl • • • 0
0
0 • .,
• .,
• • • • • • • • • • • • • • • • • • • • • • • • • • • •
Lot-Sample # ... : GOG250283-003
Date Sampled ... : 07/21/00
Prep Date ...... : 07/27/00
Prep Batch # ••. : 0209449
Dilution Factor: l
PARAMETER
Aldrin
alpha-BHC
beta-BHC
delta-BHC
gamma-BHC (Lindane)
alpha-Chlordane
gamma-Chlordane
Dieldrin
4, 4 1 -DDD
4,4 1 -DDE
4,4 1 -DDT
Endrin
Endrin aldehyde
Endrin ketone
Endosulfan I
Endosulfan II
Endosulfan sulfate
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
SURROGATE
Decachlorobiphenyl
Tetrachloro-m-xylene
PINNACLE CONSDLTING GROUP .
Client Sample ID: MW-36L
GC Semivolatiles
Work Order # •.. : DGR8Al01 Matrix ........• : WATER
Date Received .. : 07/25/00
Analysis Date .. : 08/03/00
Method ••••.•.•• : SW846 8081A
REPORTING
RESULT LIMIT UNITS MDL
ND 0.050 ug/L 0.0060
ND 0.050 ug/L 0.0080
ND 0.050 ug/L 0.0040
ND 0.050 ug/L 0.0060
ND 0.050 ug/L 0.010
ND 0.050 ug/L 0.0070
ND 0.050 ug/L 0.0080
ND 0.10 ug/L 0.020
ND 0.10 ug/L 0.0050
ND 0.10 ug/L 0.015
ND 0.10 ug/L 0.020·
ND 0.10 ug/L 0.020
ND 0.10 ug/L 0.029
ND 0.10 ug/L 0.024
ND 0.050 ug/L 0.010
ND 0.10 ug/L 0.020
ND 0.10 ug/L 0.033
ND 0.050 ug/L 0.0070
ND 0.050 ug/L 0.0080
ND 0.50 ug/L 0.040
ND 2.0 ug/L 1.4
PERCENT RECOVERY
RECOVERY LIMITS
92 (10 -146)
67 (43 -110)
0
0
0
0 • • • • • • • • • • • • • • • • 0
0 • 8
8 • • • • • • • • • • • • • • • • • • • • • • • • • • • • • •
Lot-Sample # ... : GOG250283-011
Date Sampled ... : 07/21/00
Prep Date .....• : 07/27/00
Prep Batch# ... : 0209449
Dilution Factor: 5
PARAMETER
Aldrin
alpha-BBC
beta-BBC
delta-BHC
gamma-BBC {Li.ndane)
alpha-Chlordane
gamma-Chlordane
Dieldrin
4 1 4 1 -DDD
4,4'-DDE
4,4'-DDT
Endrin
Endrin aldehyde
Endrin ketone
Endosulfan I
Endosulfan II
Endosulfan sulfate
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
SURROGATE
Decachlorobiphenyl
Tetrachloro-m-xylene
NOTB{SJ:
PINNACLE CONSULTING GROOP
Client Sample ID: MW-37L
GC Semivolatiles
Work Order# ... : DGRBL101
Date Received .. : 07/25/00
Analysis Date .. : 08/04/00
Matrix ......... : WATER
Method ......... : SWB46 8081A
REPORTING
RESULT LIMIT UNITS MDL
ND Q 0.25 ug/L 0.030
2.6 0.25 ug/L 0.040
0.36 0.25 ug/L 0.020
0.94 0.25 ug/L 0.030
2. l. 0.25 ug/L 0.050
ND 0.25 ug/L 0.035
ND 0.25 ug/L 0.040
ND 0.50 ug/L 0.10
ND 0.50 ug/L 0.025
ND a.so ug/L 0.075
ND 0.50 ug/L 0.10
ND 0.50 ug/L 0.10
ND 0.50 ug/L 0.14
ND 0.50 ug/L 0.12
ND 0.25 ug/L 0.050
ND 0.50 ug/L 0.10
ND 0.50 ug/L 0.16
ND 0.25 ug/L 0.035
ND 0.25 ug/L 0.040
ND 2.5 ug/L 0.20
ND 10 ug/L 7.0
PERCENT RECOVERY
RECOVERY LIMITS
109 (10 -l.4 6)
65 (43 -110)
Q Elevated reporting limit. The reponing limi1 is elevated due 10 high :uulyae levels .
0
0
0
0
0
0
0 • • • • • • • • • • • • • • • • • • • • • 0
0
0
0
0 • • • • • • • • • • • • • • • • • • • • • •
Lot-Sample# ... : GOG250283-006
Date Sampled ... : 07/22/00
Prep Date ...... : 07/27/00
Prep Batch # ... : 0209449
Dilution Factor: 1
PARAMETER
Aldrin
alpha-BHC
beta-BHC
delta-BHC
gamrna-BHC (Lindane)
alpha-Chlordane
gamma-Chlordane
Dieldrin
4,4 1 -DDD
4,4 1 -DDE
4, 4' -DDT
Endrin
Endrin aldehyde
Endrin ketone
Endosulfan I
Endosulfan II
Endosulfan sulfate
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
SURROGATE
Decachlorobiphenyl
Tetrachloro-m-xylene
PINNACLE CONSULTING GROOP
Client Sample ID: MW-38L
GC Semivolatiles
Work Order# ... : DGR8Fl01 Matrix ......... : WATER
Date Received .. : 07/25/00
Anal.ysis Date .. : 08/03/00
Method ......... : SW846 8081A
REPORTING
RESULT LIMIT UNITS MDL
ND 0.050 ug/L 0.0060
ND 0.050 ug/L 0.0080
ND 0.050 ug/L 0.0040
ND 0.050 ug/L 0.0060
ND 0.050 ug/L 0.010
ND 0.050 ug/L 0.0070
ND 0.050 ug/L 0.0080
ND 0.10 ug/L 0.020
ND 0.10 ug/L 0.0050
ND 0.10 ug/L 0.015
ND 0.10 ug/L 0.020
ND 0.10 ug/L 0.020
ND 0.10 ug/L 0.029
ND 0.10 ug/L 0.024
ND 0.050 ug/L 0.010
ND 0.10 ug/L 0.020
ND 0.10 ug/L 0.033
ND 0.050 ug/L 0.0070
ND 0.050 ug/L 0.0080
ND 0.50 ug/L 0.040
ND 2.0 ug/L 1. 4
PERCENT RECOVERY
RECOVERY LIMITS
61 (10 -146)
68 (43 -110)
0
0
0
0
0 • • • • • • • • • • • • • • • • D
0
0 • • f)
f) • • • • • • • • • • • • • • • • • • • • • • • • • • •
Lot-Sample# ... : GOG250283-007
Date Sampled .•. : 07/22/00
Prep Date ...... : 07/27/00
Prep Batch# ... : 0209449
Dilution Factor: 1
PARAMETER
Aldrin
alpha-BHC
beta-BHC
delta•BHC
gamma-BHC (Lindane)
alpha-Chlordane
gamma-Chlordane
Dieldrin
4, 4 • -DDD
4,4 1 -DDE
4,4'-DDT
Endrin
Endrin aldehyde
Endrin ketone
Endosulfan I
Endosulfan II
Endosulfan sulfate
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
SURROGATE
Decachlorobiphenyl
Tetrachloro-m-xylene
PINNACLE CONSULTING GROUP
Client Sample ID: MW-39L
GC' Semivolatiles
Work Order# ... : DGR8Gl01
Date Received .. : 07/25/00
Analysis Date .. : 08/03/00
Matrix ......... : WATER
Method ......... : SW84 6 8081A
REPORTING
RESULT LIMIT UNITS MDL
ND 0.050 ug/L 0.0060
ND 0. 050 ug/L 0.0080
ND 0.050 ug/L 0.0040
ND 0.050 ug/L 0.0060
ND 0.050 ug/L 0.010
ND 0.050 ug/L 0. 007 0
ND 0.050 ug/L 0.0080
ND 0.10 ug/L 0.020
ND 0.10 ug/L 0.0050
ND 0.10 ug/L 0.015
ND 0.10 ug/L 0. 020
ND 0.10 ug/L 0.020
ND 0.10 ug/L 0.029
ND 0.10 ug/L 0.024
ND 0.050 ug/L 0.010
ND 0.10 ug/L 0. 020
ND 0.10 ug/L 0.033
ND 0.050 ug/L 0.0070
ND 0.050 ug/L 0.0080
ND 0.50 ug/L 0.040
ND 2.0 ug/L 1.4
PERCENT RECOVERY
RECOVERY LIMITS
103 (10 . 146)
75 (43 . 110)
• • 0
0
0 • • • • • • • • • • • • • e
0
0
0 .,
• • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • •
Lot-Sample # ... : G0G250283-010
Date Sampled ... : 07/21/00
Prep Date ...... : 07/27/00
Prep Batch # ... : 0209449
Dilution Factor: 5
PARAMETER
Aldrin
alpha-BHC
beta-BHC
delta-BHC
garnma-BHC (Lindane)
alpha-Chlordane
gamma-Chlordane
Dieldrin
4,4' -DDD
4,4'-DDE
4,4 1 -DDT
Endrin
Endrin aldehyde
Endrin ketone
Endosulfan I
Endosulfan II
Endosulfan sulfate
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
SURROGATE
Decachlorobiphenyl
Tetrachloro-m-xylene
NOTE (S) :
PINNACLE CONSULTING GROUP
Client Sample ID: MW-40L
GC Semivolatiles
Work Order # ... : DGRBK101
Date Received .. : 07/25/00
Analysis Date .. : 08/04/00
Matrix ......... : WATER
Method ......•.. : SW846 8081A
REPORTING
RESULT LIMIT UNITS MDL
ND Q 0.25 ug/L 0.030
2.0 0.25 ug/L 0.040
0.45 0.25 ug/L o. 020
1.1 0.25 ug/L 0.030
0.85 0.25 ug/L 0.050
ND 0.25 ug/L 0.035
ND 0.25 ug/L 0.040
ND 0.50 ug/L 0.10
ND 0.50 ug/L 0.025
ND 0.50 ug/L 0.075
ND 0.50 ug/L 0.10
ND 0.50 ug/L 0.10
ND 0.50 ug/L 0 .14
ND 0.50 ug/L 0.12
ND 0.25 ug/L 0.050
ND 0.50 ug/L 0.10
ND 0.50 ug/L 0.16
ND 0.25 ug/L 0.035
ND 0.25 ug/L 0.040
ND 2.5 ug/L 0.20
ND 10 ug/L 7.0
PERCENT RECOVERY
RECOVERY LIMITS
110 (10 -14 6)
74. (43 -110)
Q Elevated reponing limit. The reporting limit is elevated due 10 high analytc levels .
• 0
0
e • • • • • • • • • • • • • G
Q
0
0
0 • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • •
PINNACT.E CONSULTING GROUP
Client Sample ID: PZ-2
GC Semivolatiles
Lot-Sample# ... : G0G250283-008 Work Order # ... : DGRBHl0l Matrix ......... : WATER
Date Sampled ... : 07/22/00 Date Received. _ : 07/25/00
Prep Date ...... : 07/27/00 .Analysis Date .. : 08/04/00
Prep Batch # ••• : 0209449
Dilution Factor: 2 Method ...•..... : SW846 8081A
REPORTING
PARAMETER RESULT LIMIT UNITS MDL
Aldrin ND Q 0.10 ug/L 0.012
alpba-BHC 0.92 o.io ug/L 0.0l.6
beta-BBC 0.24 O.l.0 ug/L 0.0080
delta-BHC 0.40 O.l.O ug/L O.0l.2
gamma-BBC (Lindane) 0.82 0.l.0 ug/L 0.020
alpha-Chlordane ND 0.10 ug/L 0. 014
gamma-Chlordane ND 0.10 ug/L 0.016
Dieldrin ND 0.20 ug/L 0.040
4,4'-DDD ND 0.20 ug/L 0.010
4,4' -DDE ND 0.20 ug/L 0.030
4,4'-DDT ND 0.20 ug/L 0. 04 0
Endrin ND 0.20 ug/L 0. 04 0
Endrin aldehyde ND 0.20 ug/L 0.058
Endrin ketone ND 0.20 ug/L 0.048
Endosulfan I ND 0.10 ug/L 0.020
Endosulfan II ND 0.20 ug/L 0. 040
Endosulfan sulfate ND 0.20 ug/L 0.066
Heptachlor ND 0.10 ug/L 0.014
Heptachlor epoxide ND 0.10 ug/L 0.016
Methoxychlor ND 1.0 ug/L 0.080
Toxaphene ND 4.0 ug/L 2.8
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Decachlorobiphenyl 92 (10 -146)
Tetrachloro-m-xylene 70 (43 -110)
NOTE (S) :
Q Elevated reporting limit. The reporting limit is clevatcd due to hi&,h analyte levels .
G
G • • • • I) • • • • • • • • • • • • • 0
0
0 • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • •
Lot-Sample # .•. : GOG250283-004
Date Sampled ... : 07/21/00
Prep Date ...... : 07/27/00
Prep Batch # •.. : 0209449
Dilution Factor: 1
PARAMETER
Aldrin
alpha-BBC
beta-BHC
delta-BHC
gamma-BHC (Lindane)
alpha-Chlordane
gamma-Chlordane
Dieldrin
4,4 1 -DDD
4,4'-DDE
4,4'-DDT
Endrin
Endrin aldehyde
Endrin ketone
Endosulfan I
Endosulfan II
Endosulfan sulfate
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
SURROGATE
Decachlorobiphenyl
Tetrachloro-m-xylene
PINNACLE CONSULTING GROUP
Client Sample ID: PZ-3
GC Semivolatiles
Work Ord"'r # •.. : DGR8Cl01
Date Received .. : 07/25/00
Analysis Date .. : 08/04/00
Matrix .•....... : WATER
Method ......... : SW846 8081A
REPORTING
RESULT "LIMIT UNITS MDL
ND 0.050 ug/L 0.0060
0.46 0.050 ug/L 0.0080
0.10 0.050 ug/L 0.0040
O.l.6 0.050 ug/L 0.0060
0.41 0.050 ug/L O.Ol.O
ND 0.050 ug/L 0.0070
ND 0.050 ug/L 0.0080
ND 0.10 ug/L 0.020
ND 0.10 ug/L 0.0050
ND 0.10 ug/L 0.015
ND 0.10 ug/L 0.020
ND 0.10 ug/L 0.020
ND 0.10 ug/L 0.029
ND 0.10 ug/L 0.024
ND 0.050 ug/L 0.010
ND 0.10 ug/L 0.020
ND 0.10 ug/L 0.033
ND 0.050 ug/L 0.0070
ND 0.050 ug/L 0.0080
ND 0.50 ug/L 0.040
ND 2.0 ug/L 1.4
PERCENT RECOVERY
RECOVERY LIMITS
84 (10 -146)
64 (43 -llO)
0
0
0
0 ., ., ., ., • ., • • • • • • • • • • • • Cl • G • • 0
0
0
0 • ., ., ., .,
• • • • • • • • • • • • • • • • • • •
Lot-Sample It ... : G0G250283-002
Date Sampled ... : 07/21/00
Prep Date ...... : 07/27/00
Prep Batch # ••• : 0209449
Dilution Factor: 1
PARAMETER
Aldrin
alpha-BHC
beta-BHC
delta-BHC
gamma-BHC (Lindane)
alpha-Chlordane
gamma-Chlordane
Dieldrin
4, 4 1 -DOD
4, 4' -DDE
4,4 1 -DDT
Endrin
Endrin aldehyde
Endrin ketone
Endosulfan I
Endosulfan II
Endosulfan sulfate
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
SURROGATE
Decachlorobiphenyl
Tetrachloro-m-xylene
PINNACLE CONSULTING GROUP
Client Sample ID: PZ-5
GC Sernivolatiles
Work Order It ... : DGR89101 Matrix ......... : WATER
Date Received .. : 07/25/00
Analysis Date .. : 08/04/00
Method ••....•.• : SW846 8081A
REPORTING
RESULT LIMIT UNITS MDL
ND 0.050 ug/L 0.0060
0.12 0.050 ug/L 0.0080
0.074 0.050 ug/L 0. 0040
ND 0. 050 ug/L 0.0060
0.23 0.050 ug/L 0.010
ND 0.050 ug/L 0.0070
ND 0.050 ug/L 0.0080
ND 0.10 ug/L 0.020
ND 0.10 ug/L 0.0050
ND 0.10 ug/L 0.015
ND 0.10 ug/L 0.020
ND 0.10 ug/L 0.020
ND 0.10 ug/L 0.029
ND 0.10 ug/L 0.024
ND 0.050 ug/L 0.010
ND 0.10 ug/L 0.020
ND 0.10 ug/L 0.033
ND 0. 050 ug/L 0.0070
ND 0.050 ug/L 0.0080
ND 0.50 ug/L 0.040
ND 2.0 ug/L 1.4
PERCENT RECOVERY
RECOVERY LIMITS
59 (10 -146)
69 (43 -110)
t) • • • • • • • • • • • • • • • • • • • • • • • • • • • • • Cl
Cl
Cl
9
9
9
0
0
0
0
0
0 • • t) .,
• t) • ., • • • • •
STREAM SURFACE WATER MONITORING RESULTS
THIRD QUARTER 2000
DOWNGRADIENT AREA
• • e
e e
e • • • • • • • • • • • • • • • • • • • • • • • • • • • • G
G • 0
0
0
0
0 • • e e • • • • • • e • •
Lot-Sample# ... : GOG220162-001
Date Sampled ... : 07/21/00
Prep Date ...... : 07/26/00
Prep Batch# ... : 0208179
Dilution Factor: 1
PARAMETER
alpha-BHC
beta-BHC
delta-BHC
gamma-BHC (Lindane)
Heptachlor
Heptachlor epoxide
SURROGATE
Decachlorobiphenyl
Tetrachloro-m-xylene
PINNACLE CONSULTING GROUP
Client Sample ID: SW-01
GC Semivolatiles
Work Order# ... : DGN9Gl01
Date Received .. : 07/22/00
Analysis Date .. : 08/11/00
Matrix ......... : WATER
Method ......... : SW846 8081A
REPORTING
RESULT LIMIT UNITS MDL
ND 0.050 ug/L 0.0080
ND 0.050 ug/L 0.0040
ND 0.050 ug/L 0.0060
ND 0.050 ug/L 0.010
ND 0.050 ug/L 0.0070
ND 0.050 ug/L 0.0080
PERCENT RECOVERY
RECOVERY LIMITS
51 (10 . 146)
59 (43 -110)
0
0 • G
G • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • 0
0
0
0
e
0
G
G • • • • • • • • • • • •
Lot-Sample# ... : G0G220162-001
Date Sampled ... : 07/21/00
PINNACLE CONSULTING GROUP
Client Sample ID: SW-01
General Chemistry
Work Order# ... : DGN9G
Date Received .. : 07/22/00
Matrix ......... : WATER
PREPARATION-PREP
,cPARAM==E"-'T,_,E,.:_R,...._ ____ -"R:.::E::c:S.::.UL:.T:...__ .:..:RL=---.::UN=IT;;S"---:.cM:.::Ec:.T.:..:HO.::.D"------ANALYSIS DATE BATCH #
Non-Filterable Solid ND 5.0 mg/L MCAWW 160.2 07/25/00 0207431
(Residue)
Di·lution Factor: 1 MDL ............ : 5.0
• • • • • • ., .,
• • • • • • • • • • • • • • • • • • • • • • • • • • • • • 0
0
0
0
0
0
0 • • • • • • .,
• • • •
Lot-Sample# ... : GOG220162-002
Date Sampled ... : 07/20/00
Prep Date ...... : 07/26/00
Prep Batch# ... : 0208179
Dilution Factor: 1
PARAMETER
alpha-BHC
beta-BHC
delta-BHC
gamma-BHC (Lindane)
Heptachlor
Heptachlor epoxide
SURROGATE
Decachlorobiphenyl
Tetrachloro-m-xylene
NOTE (SJ:
J Estim11ted mulL Re!!ull is less lhan RL .
PINNACLE CONSULTING GROUP
Client Sample ID: SW-02
GC Semivolatiles
Work Order# ... : DGN9Jl01
Date Received .. : 07/22/00
Analysis Date .. : 08/11/00
Matrix ......... : WATER
Method ......... : SW846 8081A
REPORTING
RESULT LIMIT UNITS MDL
0.032 J 0.050 ug/L 0.0080
0. 075 0.050 ug/L 0.0040
0.071 0.050 ug/L 0.0060
0.030 J 0.050 ug/L 0.010
ND 0.050 ug/L 0.0070
ND 0.050 ug/L 0. 008 0
PERCENT RECOVERY
RECOVERY LIMITS
48 (10 146)
66 (43 -110)
0
0
0 • • • • • • • • • • • • • • • • • • • • • • • • • • • ct
ct
(t
(t
G
G
G
0
0
0
0
8
8 • • • • • • • • • • • •
PINNACLE CONSULTING GROUP
Client Sample ID: SW-02
General Chemist:cy
Lot-Sample# ... : GOG220162-002 Work Order# ... : DGN9J Matrix ......... : WATER
Date Sampled ... : 07/20/00 Date Received .. : 07/22/00
~PARAM'-"-"=E~T~E~R'------RESULT
Non-Filterable Solid ND
(Residue)
PREPARATION-PREP
'-'RL=---~UN"-'I'--'T=S __ M~E~T=H=O=D'------ANALYSIS DATE BATCH #
5.0 rng/L MCAWW 160.2 07/25/00 0207431
Dilution Factor: 1 MDL •.•......... : 5.0
0 • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • 0
0
0
0
0
0
0 • • • • • • • • • • • • •
Lot-Sample # ... : GOG220162-003
Date Sampled ... : 07/20/00
Prep Date ...... : 07/26/00
Prep Batch# ... : 0208179
Dilution Factor: 1
PARAMETER
alpha-BHC
beta-BHC
delta-BHC
gannna-BHC (Lindane)
Heptachlor
Heptachlor epoxide
SURROGATE
Decachlorobiphenyl
Tetrachloro-m-xylene
NOTE (S) :
J Estimated result. Result is Je59 than RL.
PINNACLE CONSULTING GROUP
Client Sample ID: SW-03
GC Semivolatiles
Work Order # ... : DGN9Kl01 Matrix ......... : WATER
Date Received .. : 07/22/00
Analysis Date .. : 08/11/00
Method ......... : SW846 8081A
REPORTING
RESULT LIMIT UNITS MDL
0.030 J 0.050 ug/L 0. 0080
0.063 0.050 ug/L 0. 0040
0.054 0.050 ug/L 0.0060
0.021 J 0.050 ug/L 0.010
ND 0.050 ug/L 0.0070
ND 0.050 ug/L 0.0080
PERCENT RECOVERY
RECOVERY LIMITS
40 (10 146)
73 (43 -110)
• • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • Cl
Cl
Cl
G
G
G
0
0
0
0
0 • 8 e • • • • •
PINNACLE CONSULTING GROUP
Client Sample ID: SW-03
General Chemistry
Lot-Sample# ... : GOG220162-003 Work Order# ... : DGN9K Matrix ......... : WATER
Date Sampled ... : 07/20/00 Date Received .. : 07/22/00
PARAMETER RESULT
Non-Filterable Solid ND
(Residue)
PREPARATION-PREP
~RL~--~UN=IT=S~--c,M,,_ETH:.!.!>Oc=:D _____ ANALYSIS DATE BATCH #
5. 0 mg/L MCAWW 160 .2 07/25/00 0207431
Dilution Factor: 1 MDL ............ : 5.0
• • • • • • • • ., ., ., ., ., • • • • • • • • • • • • • • • • • • • • • • Cl
Cl • • • • • • 0
0
0
0 • • f) • • • ., .,
Lot-Sample# ... : G0G220162-004
Date Sampled ... : 07/20/00
Prep Date ...... : 07/26/00
Prep Batch# ... : 0208179
Dilution Factor: 1
PARAMETER
alpha-BHC
beta-BHC
delta-BHC
gamma-BHC (Lindane)
Heptachlor
Heptachlor epoxide
SURROGATE
Decachlorobiphenyl
Tetrachloro-m-xylene
NarE(S):
J Estimated ItSUlt. Result U less than RL .
PINNACLE CONSULTING GROUP
Client Sample ID: SW-04
GC Semivolatiles
Work Order# ... : DGN9L101
Date Received .. : 07/22/00
Analysis Date .. : 08/11/00
Matrix ......... : WATER
Method ......... : SW846 8081A
REPORTING
RESULT LIMIT UNITS MDL
0.015 J 0.050 ug/L 0.0080
0.037 J 0.050 ug/L 0.0040
0.024 J 0.050 ug/L 0.0060
ND 0.050 ug/L 0.010
ND 0.050 ug/L 0.0070
ND 0.050 ug/L 0.0080
PERCENT RECOVERY
RECOVERY LIMITS
46 (10 -146)
71 (43 -110)
e
e • • • • • • • • .,
• • • t)
t)
t)
t)
t)
t)
t) ., ., • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • G
G
Lot-Sample# ... : G0G220162-004
Date Sampled ... : 07/20/00
PARAMETER RESULT
Non-Filterable Solid ND
(Residue)
PINNACLE CONSULTING GROUP
Client Sample ID: SW-04
General Chemistry
Work Order# ... : DGN9L
Date Received .. : 07/22/00
Matrix ......... : WATER
PREPARATION-PREP
~RL~--=UN=IT=S~--,:_M'='Ec,_T;_;H,cOD,:_ _____ ANALYSIS DATE BATCH #
5.0 mg/L MCAWW 160.2 07/25/00 0207431
Dilution Factor: 1 MDL ............ : 5.0
0
0
0
G
G
G • • t)
t)
t) ., • • • • • • • • • • • • • • • • • • • • • • • • 0 • 0
0
0
0
G • • • • ., ., • • • • • •
Lot-Sample# ... : GOG220162-005
Date Sampled ... : 07/20/00
Prep Date ...... : 07/26/00
Prep Batch# ... : 0208179
Dilution Factor: 1
PARAMETER
alpha-BHC
beta-BHC
delta-BHC
gamma-BHC (Lindane)
Heptachlor
Heptachlor epoxide
SURROGATE
Decachlorobiphenyl
Tetrachloro-m-xylene
NOTE (S):
J Estimated result. Rcsull is less than RL .
PINNACLE CONSULTING GROUP
Client Sample ID: SW-05
GC Semivolatiles
Work Order# ... : DGN9Ml01
Date Received .. : 07/22/00
Analysis Date .. : 08/11/00
Matrix ......... : WATER
Method ......... : SW846 8081A
REPORTING
RESULT LIMIT UNITS MDL
0.015 J 0.050 ug/L 0.0080
0.035 J 0.050 ug/L 0.0040
0.024 J 0.050 ug/L 0.0060
ND 0.050 ug/L 0.010
ND 0.050 ug/L 0.0070
ND 0.050 ug/L 0.0080
PERCENT RECOVERY
RECOVERY LIMITS
61 (10 146)
72 ( 4 3 -110)
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0 • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • •
Lot-Sample# ... : G0G220162-005
Date Sampled ... : 07/20/00
~PARAM==E~T~E~R:._ ____ RESULT
Non-Filterable Solid ND
(Residue)
PINNACLE CONSULTING GROUP
Client Sample ID: SW-05
General Chemistry
Work Order# ... : DGN9M
Date Received .. : 07/22/00
Matrix ......... : WATER
PREPARATION-PREP
"'RL=---~UN=IT~S~--~ME~TH=O=.:D,_ _____ ANALYSIS DATE BATCH #
5.0 mg/L MCAWW 160.2 07/25/00 0207431
Dilution Factor: 1 MDL ............ : 5.0
• 0
0
0
0 • ., • ., .,
• ., • • • • • • • • • • • • 0
0
0 • • • ., .,
• • • • • • • • • • • • • • • • • • • • • • •
Lot-Sample# ... : GOG220162-006
Date Sampled ... : 07/20/00
Prep Date ...... : 07 /26/00
Prep Batch# ... : 0208179
Dilution Factor: l
PARAMETER
alpha-BHC
beta-BHC
delta-BHC
gamma-BHC (Lindane)
Heptachlor
Heptachlor epoxide
SURROGATE
Decachlorobiphenyl
Tetrachloro-m-xylene
NOTE (S) :
J Estimated rcsulL Result U less than RI.,
PINNACLE CONSULTING GROUP
Client Sample ID: SW-06
GC Semivolatiles
Work Order# ... : DGN9Nl01
Date Received .. : 07/22/00
Analysis Date .. : 08/11/00
Matrix ......... : WATER
Method ......... : SW846 8081A
REPORTING
RESULT LIMIT UNITS MDL
0.016 J 0.050 ug/L 0.0080
0.036 J 0.050 ug/L 0.0040
0.024 J 0.050 ug/L 0.0060
ND 0.050 ug/L 0.010
ND 0.050 ug/L 0.0070
ND 0.050 ug/L 0.0080
PERCENT RECOVERY
RECOVERY LIMITS
59 (10 146)
74 (43 -110)
0
0
0
e
G
G
G
G • • • • • • • • • • • • • • • • • • • 0
0
0
0 e
e • e • .,
• • • • • • • • • • • • • • • • • •
Lot-Sample# ... : G0G220162-006
Date Sampled ... : 07/20/00
PINNACLE CONSOLTING GROUP
Client Sample ID: SW-06
General Chemistry
Work Order# ... : DGN9N
Date Received .. : 07/22/00
Matrix ......... : WATER
PREPARATION-PREP
~PARAM==E~T~E=R~---,---,-_R_ES~UL~T~_ ,:cRL,,___ __ ,,UN=IT.:.cS::_ __ :..;Mc:::E__,_TH::.O:cD::_ _____ ANALYSIS DATE BATCH #
Non-Filterable Solid ND 5.0 mg/L MCAWW 160.2 07/25/00 0207431
(Residue)
Dilution Factor: l MDL.· ........... : 5.0
0
0
0 • e • • • • • • • • • • • • • • • • • • • • • • 0 • • 0 • • • • • • • • • • • • • • • • • • • • • • • •
Lot-Sample# ... : G0G220162-007
Date Sampled ... : 07/20/00
Prep Date ...... : 07 /26/00
Prep Batch# ... : 0208179
Dilution Factor: 1
PARAMETER
alpha-BHC
beta-BHC
delta-BHC
gamma-BHC (Lindane)
Heptachlor
Heptachlor epoxide
SURROGATE
Decachlorobiphenyl
Tetrachloro-m-xylene
NaI'E (S) :
J E:itimatcd rcsulL Result i:s less than RL .
PINNACLE CONSULTING GROUP
Client Sample ID: SW-07
GC Semivolatiles
Work Order# ... : DGN9P101
Date Received .. : 07/22/00
Analysis Date .. : 08/11/00
Matrix ......... : WATER
Method ......... : SW846 8081A
REPORTING
RESULT LIMIT UNITS MDL
0. 013 J 0.050 ug/L 0.0080
0.038 J 0.050 ug/L 0.0040
0.025 J 0.050 ug/L 0.0060
ND 0.050 ug/L 0.010
ND 0.050 ug/L 0.0070
ND 0.050 ug/L 0. 008 0
PERCENT RECOVERY
RECOVERY LIMITS
65 (10 -146)
73 (43 -110)
0
0
0
0 • • • G ., .,
t> .,
• • • • • • • • • • • • • • • • • • • 0
0
0
0
0
0
0
e • • .,
• • • • • • • • • • • • •
PINNACLE CONSULTING GROUP
Client Sample ID: SW-07
General Chemistry
Lot-Sample# ... : G0G220162-007 Work Order# ... : DGN9P Matrix ......... : WATER
Date Sampled ... : 07/20/00 Date Received .. : 07/22/00
PARAMETER RESULT
Non-Filterable Solid ND
(Residue}
PREPARATION-PREP
'-"RL"-----o:UN:=IT'°-'S=----'-'M=-ET'°'H"'O""D'------ANALYSIS DATE BATCH #
5.0 mg/L MCAWW 160.2 07/25/00 0207431
Dilution Factor: 1 MDL ............ : 5.0
0
0
0
0
G • • • • • • • • • • • • • • • • • • • C)
C)
G
G
0
0
G • G • • • • • • • • • • • • • • • • • • • • • •
Lot-Sample# ... : G0G220162-008
Date Sampled ... : 07/20/00
Prep Date ...... : 07 /26/00
Prep Batch# ... : 0208179
Dilution Factor: 1
PARAMETER
alpha-BHC
beta-BHC
delta-BHC
gamma-BHC (Lindane)
Heptachlor
Heptachlor epoxide
SURROGATE
Decachlorobiphenyl
Tetrachloro-m-xylene
NCITE (S) :
J Estim11lCd result. Result is lc:ss than RL.
PINNACLE CONSULTING GROUP
Client Sample ID: SW-08
GC Semivolatiles
Work Order# ... : DGN9Ql01
Date Received .. : 07/22/00
Analysis Date .. : 08/11/00
Matrix ......... : WATER
Method ......... :. SW846 8081A
REPORTING
RESULT LIMIT UNITS MDL
0.01.8 J 0.050 ug/L 0.0080
0.037 J 0.050 ug/L 0.0040
0.029 J 0.050 ug/L 0.0060
ND 0.050 ug/L 0.010
ND 0.050 ug/L 0.0070
ND 0.050 ug/L 0.0080
PERCENT RECOVERY
RECOVERY LIMITS
49 (10 -146)
69 (43 -110)
• 0
0
0 e e
e • • • • • • • • • • • • • • • • • • • • 0
0
0
8
e e • • • • • • • • • • • • • • • • • • • • • •
Lot-Sample# ... : G0G220162-008
Date Sampled ... : 07/20/00
PINNACLE CONSULTING GROUP
Client Sample ID: SW-08
General Chemistry
Work Order# ... : DGN9Q
Date Received .. : 07/22/00
Matrix ......... : WATER
PREPARATION-PREP
c.PARAM==E~T~E~R~-----~R=E=SUL=T~_ ~R=L __ .~UN_IT_S~--_M_ETH_O_D ______ ANALYSIS DATE BATCH #
Non-Filterable Solid ND 5.0 'mg/L MCAWW 160.2 07/25/00 0207431
(Residue)
· Dilution Factor: 1 MDL ............ : 5.0
0
0
0
0
0
0
0 e • • • • • • • • • • • • • • • • • • • • • • • • • Cl
Cl
Cl • • 0
0
0
0
0
0 • • • • • • • • • • •
Lot-Sample# ... : G0G220162-009
Date Sampled ... : 07/20/00
Prep Date ...... : 07 /26/00
Prep Batch# ... : 0208179
Dilution Factor: 1
PARAMETER
alpha-BHC
beta-BHC
delta-BHC
gamma-BHC (Lindane)
Heptachlor
Heptachlor epoxide
SURROGATE
Decachlorobiphenyl
Tetrachloro-m-xylene
PINNACLE CONSULTING GROUP
Client Sample ID: SW-O9
GC Semivolatiles
Work Order# ... : DGN9Rl01
Date Received .. : 07/22/00
Analysis Date .. : 08/11/00
Matrix ......... : WATER
Method ......... : SW846 8081A
REPORTING
RESULT LIMIT UNITS MDL
ND 0.050 ug/L 0. 0080
ND 0.050 ug/L 0.0040
ND 0.050 ug/L 0.0060
ND 0.050 ug/L 0.010
ND 0.050 ug/L 0.0070
ND 0.050 ug/L 0.0080
PERCENT RECOVERY
RECOVERY LIMITS
36 (10 -146)
62 (43 -110)
0
0
0
0
0
0
0
0
0 • I) • • • • • • • • • • • • • • • • • • • • C, • • G • • • 0
0
0
0
0 ., ., ., • • • • • • • • •
Lot-Sample# ... : GOG220162-009
Date Sampled ... : 07/20/00
ECP~ARAM=c::cE,e_Tc-'E:,,R:,_ _____ RESULT
Non-Filterable Solid ND
(Residue)
PINNACLB CONSULTING GROUP
Client Sample ID: SW-09
General Chemistry
Work Order# ... : DGN9R
Date Received .. : 07/22/00
Matrix ......... : WATER
PREPARATION-PREP
"'RL,,_ __ .,,UN.=c.IT"-'S"---c,M.::E.:.T,..,_HO:c:cD::...... _____ ANALYSIS DATE BATCH # .
5,0 mg/L MCAWW 160.2 07/25/00 0207431
Dilution Factor: ·1 MDL ...•••.••.•. : 5.0
• Cl • 0 • 0 • 0 • • • • • • • • • • • • • • • • • • • ct
ct
0
0
0
0 • • • • • • • • • • • • • • • • • • • • • •
Lot-Sample# ... : GOG220162-010
Date Sampled ... : 07/20/00
Prep Date ...... : 07/26/00
Prep Batch# ... : 0208179
Dilution Factor: 1
PARAMETER
alpha-BHC
beta-BHC
delta-BHC
gamma-BHC (Lindane)
Heptachlor
Heptachlor epoxide
·SURROGATE
Decachlorobiphenyl
Tetrachloro-m-xylene
PINNACLll CONSULTING GROUP
Client Sample ID: SW-10
GC Semivolatiles
Work Order# ... : DGN9Tl01
Date Received .. : 07/22/00
Analysis Date .. : 08/11/00
Matrix ......... : WATER
Method ......... : SW846 8081A
REPORTING
RESULT LIMIT UNITS MDL
ND 0.050 ug/L 0.0080
ND 0.050 ug/L 0.0040
ND 0.050 ug/L 0. 0060
ND 0.050 ug/L 0.010
ND 0.050 ug/L 0.0070
ND 0.050 ug/L 0.0080
PERCENT RECOVERY
RECOVERY LIMITS
42 ( 10 -146)
58 ( 43 -110)
• • • 0
0
0 • 0 • • • • • • • • • • • • • • (I • • • • 0
0
0
0 • • • ., • • • • • • • • • • • • • • • • • • • •
PINNACLE CONSULTING GROUP
Client Sample ID: SW-10
General Chemistry
Lot-Sample# ... : G0G220162-010 Work Order# ... : DGN9T Matrix ......... : WATER
Date Sampled ... : 07/20/00 Date Received .. : 07/22/00
~PARAMc=:=E~T~ER"'-----RESULT
Non-Filterable Solid ND
(Residue)
PREPARATION-PREP
!!R::.L __ -"'UN"-'I=--'T'-"'S __ ,:,M::.ETH=Oe:D:__ ____ ANALYSIS DATE BATCH #
5.0 mg/L MCAWW 160.2 07/25/00 0207431
Dilution Factor: 1 MDL ............ : 5.0
0
0
0 • • • • • • • • I)
I) • • • • • • • • • • • • • • • • • • • • • 0
0
0 • • 0 • • • • • I) • • • • • • • • •
Lot-Sample# ... : G0G220162-0ll
Date Sampled ... : 07/20/00
Prep Date ...... : 07/26/00
Prep Batch# ... : 0208179
Dilution Factor: 1
PARAMETER
alpha-BHC
beta-BHC
delta-BHC
gamma-BHC (Lindane)
Heptachlor
Heptachlor epoxide
SURROGATE
Decachlorobiphenyl
Tetrachloro-m-xylene
NOTE (S):
J E!itimated result. Result is less than RL .
PINNACLE CONSULTING GROUP
Client Sample ID: SW-11-2
GC Semivolatiles
Work Order# ... : DGN9Vl01
Date Received .. : 07/22/00
Analysis Date .. : 08/11/00
Matrix ......... : WATER
Method ......... : SW846 8081A
RESULT
0.018 J
0. 043 J
0. 029 J
ND
ND
ND
PERCENT
RECOVERY
56
86
REPORTING
LIMIT
0.050
0.050
0.050
0.050
0.050
0.050
RECOVERY
LIMITS
(10 -146)
(43 -110)
UNITS MDL
ug/L 0.0080
ug/L 0.0040
ug/L 0.0060
ug/L 0.010
·ug/L 0.0070
ug/L 0.0080
• 0
0
0
0
0
0
0
0
0
0 • t)
t) • • • • • • • • • • • • • • • • • • • 0
0
0
0 • • t) • • • • • • • • • • • • • • •
Lot-Sample# ... : G0G220162-011
Date Sampled ... : 07/20/00
PARAMETER RESULT
Non-Filterable Solid ND
(Residue)
PINNACLE CONSULTING GROUP
Client Sample ID: SW-11-2
General Chemistry
Work Order# ... : DGN9V Matrix ......... : WATER
·. Date Received .. : 07 /22/00
PREPARATION-PREP
:.:R:.L __ "'UN"-I=-T""S=----~M=E~TH"-O~D=-------ANALYSIS DATE BATCH #
5.0 mg/L MCAWW 160.2 07/25/00 0207431
Dilution Factor: l MDL ............ : s.o