NCD986232379_20000501_Greshams Lake Industrial Park_FRBCERCLA RI_Phase I Remedial Investigation Work Plan - Appendix E Vol. 2-OCR

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PHASE I REMEDIAL INVESTIGATION WORK PLAN
FOR
GRESHAM'S LAKE SITE
GRESHAM'S LAKE ROAD
RALEIGH, NORTH CAROLINA
APPENDIX E -PREVIOUS SITE ENVIRONMENTAL INVESTIGATIONS
VOLUME II
Report of Findings Site No. 29 -REA Construction Company
Appendix E and F
Geraghty & Miller -May 1997
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APPENDIXE
IN-SITU HYDRAULIC CONDUCTIVITY (SLUG) TESTS
g:\aproject\ncdol\ncOJ60.042\uport\rq,orC.doc\l).1,.iay-97
GERAGHTY c? MILLER, INC 0
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1.
0.1
0.01 L..l......1....l..L-'--.L.....J---L__L._J._..L_L__l......1...---'-...L-L-l__L-L_J._.L.....J__L_j__J
0. 4. 8. 12. 16. 20.
Time (min)
MW1 SLUG OUT
Data Set: G:\APROJECT\NCDOT\NC0360.042\S LUGTEST\MW-1 OUT.AQT
Date: 12/13/96 Time: 09:50:09
PROJECT INFORMATION
Company: Geraghty & Miller
Client: NCDOT
Project: NC0360.042
Test Well: MW-1 --Test Date: 11/01/96
AQUIFER DATA
Saturated Thickness: 10. ft Anisotropy Ratio (Kz/Kr): 1. --
WELL DATA
Initial Displacement: 1.435 ft Water Column Height: 5.75 ft
Casing Radius: 0.083 ft Wellbore Radius: 0.333 ft --
Screen Length: 10. ft -
SOLUTION
Aquifer Model: Unconfined K = 0.0008136 cm/sec
Solution Method: Bouwer-Rice y0 =1.364ft
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1.
~ <I= ~ -C Q)
E a, 0.1 u C\l
C.
"' i:5
0.01
= 0
0 = 0 =
==
0
0.001 L...l---'--'--'-.L_..;'---'--'--'-...L.,_.!....--1---L-'-_j_.!....--1___L_J__j_.L.....J___L_L_j
0. 4. 8. 12. 16. 20.
Time (min)
MW-2 SLUG OUT
Data Set: G:\APROJECnNCDOnNC0360.042\SLUGTESnMW-2OUT.AQT
Date: 12/13/96 Time: 09:51:00
PROJECT INFORMATION
Company: Geraght:z, & Miller
Client: NCDOT
Project: NC0360.042
Test Well: MW-2 --Test Date: 11/01/96
AQUIFER DATA
Saturated Thickness: 10. ft Anisotropy Ratio (Kz/Kr): 1. --
WELL DATA
Initial Displacement: 1.519 ft Water Column Height: 7 .28 ft
Casing Radius: 0.083 ft Wellbore Radius: 0.333 ft --
Screen Length: 10. ft
SOLUTION
Aquifer Model: Unconfined K = 0.0003719 cm/sec
Solution Method: Bouwer-Rice y0 = 1.399 ft --
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g -C Q)
E a, 0.1 u "' a.
1/)
i5
0.01
0. 4.
= CD
D
8. 12.
Time (min)
MW1 SLUG IN
D
16. 20.
Data Set: G:\APROJECT\NCDOT\NC0360. 042\SLUGTEST\MW-1 IN .AQT
Date: 12/13/96 Time: 09:49:37
PROJECT INFORMATION
Company: Geraght:i: & Miller
Client: NCDOT
Project: NC0360.042
Test Well: MW-1 --Test Date: 11/01/96
AQUIFER DATA
Saturated Thickness: 10. ft Anisotropy Ratio (Kz/Kr): 1. --
WELL DATA
Initial Displacement: 0.377 ft Water Column Height: 5. 75 ft
Casing Radius: 0.083 ft Wellbore Radius: 0.333 ft --
Screen Length: ,!Q, ft
SOLUTION
Aquifer Model: Unconfined K = 7.144E-05 cm/sec
Solution Method: Bouwer-Rice yo = o.3708 ft
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g -c:: Ql E
~
Ol
c..
"' i:5
1.
0.1
0.01
0.
DO
0
0
0
0
0
0
ODO
ODO
4. 8. 12. 16. 20.
Time (min)
MW-2 SLUG IN
Data Set: G:\APROJECT\NCDOT\NC0360.042\SLUGTEST\MW-2IN.AQT
Date: 12/13/96 Time: 09:50:33
PROJECT INFORMATION
Company: Geraght:i-& Miller
Client: NCDOT
Project: NC0360.042
Test Well: MW-2 --Test Date: 11/01/96
AQUIFER DATA
Saturated Thickness: 10. ft Anisotropy Ratio (Kz/Kr): 1. --
WELL DATA
Initial Displacement: 0.953 ft Water Column Height: 7.28 ft
Casing Radius: 0.083 ft Wellbore Radius: 0.333 ft ----
Screen Length: 10. ft
SOLUTION
Aquifer Model: Unconfined K = 0.0004269 cm/sec
Solution Method: Bouwer-Rice y0 = 1.243 ft --
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1.
~ ii= --C:
Ql
E 0.1 Ql u 0 <Cl
ci. 0 ., 0
l5 0
0
0.01
0.001 '----'--'--'--'--'--'--'--'-....L.....-'--L......JO-'--'--'-L-1--'--'--'-L....l--1._L.....J
0. 6. 12. 18. 24. 30.
Time (min)
MW-3 SLUG IN
Data Set: G:\APROJECT\NCDOT\NC0360.042\SLUGTEST\MW-3IN.AQT
Date: 12/13/96 Time: 09:51 :25
PROJECT INFORMATION
Company: Geraght~ & Miller
Client: NCDOT
Project: NC0360.042
Test Well: MW-3 --Test Date: 11/01/96
AQUIFER DATA
Saturated Thickness: 10. ft Anisotropy Ratio (Kz/Kr): 1. -
WELL DATA
Initial Displacement: 1.378 ft Water Column Height: 8.68 ft
Casing Radius: 0.083 ft Wellbore Radius: 0.333 ft --
Screen Length: 10. ft
SOLUTION
Aquifer Model: Unconfined K = 0.0001998 cm/sec
Solution Method: Bouwer-Rice y0 · = 1.54 ft
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1.
~ ¢:: ~ 0 -C: 0
Q) 0
E 0.1 Q) u <CJ a. "' i5
0.01
0.001 '--'~---'---'---'--'--'---'--'--'---'--'--'--L-J.---'--'---'--'--J........l---l._l__l__J
0. 6. 12. 18. 24. 30.
Time (min)
MW-3 SLUG OUT
Data Set: G:\APROJECT\NCDOT\NC0360.042\SLUGTEST\MW-3OUT.AQT
Date: 12/13/96 Time: 09:51:56
PROJECT INFORMATION
Company: Geraght}' & Miller
Client: NCDOT
Project: NC0360.042
Test Well: MW-3
Test Date: 11/01/96
AQUIFER DATA
Saturated Thickness: 10. ft Anisotropy Ratio (Kz/Kr): 1. -
WELL DATA
Initial Displacement: 1.114 ft Water Column Height: 8.68 ft
Casing Radius: 0.083 ft Wellbore Radius: 0.333 ft --
Screen Length: 10. ft
SOLUTION
Aquifer Model: Unconfined K = 7.091E-05 cm/sec
Solution Method: Bouwer-Rice y0 = 1.063 ft --
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APPENDIXF
LABORATORY ANALYTICAL DATA REPORTS
g:\aprojcct\ncdotw:<ll60.04Zveport\rcpora.doc\13-Mly•97
GERAGHTY & MlLLER, INC.
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PARADIGM ANALYTICAL LABORATORIES, INC.
2627 Northchase Parkway S.E.
Wilmington, North Carolina 28405
[phone]
Mr. Fred Rash
Geraghty & Miller
2840 Plaza Place
Raleigh,NC 27612
Report Number: G149-2,3,4,5
Fax [phone]
Client Project Name : Greshams Lake #29
Dear Mr. Rash :
Date 6-14-96
Enclosed are the results of the analytical services performed under the
referenced project. Copies of this report and supporting data will be retained in
our files for a period of five years in the event they are required for future
reference. Any samples submitted to our laboratory will be retained for a
maximum of thirty (30) days from date of this report unless other arrangements
are requested.
If there are any questions about the report or the services performed during this
project, please call for assistance. We will be happy to answer any questions or
concerns which you may have.
Thank you for using Paradigm Analytical Labs for your analytical service
projects. We look forward to working with you again on any additional needs
which you may have.
Sincerely,
Paradigm AnalY!ical Laboratories
meQ Uoo
Laboratory Director
Mark Randall
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PAR.\DIGM ANALYTICAL LABORATORIES, INC.
2627 Northchase Parkway S.E.
Wilmington. North Carolina 28405
[phone]
Mr. Mark Radeke
Geraghty & Miller
2840 Plaza Place
Raleigh,NC 27612
Fax [phone]
Response to Data Validation Comments
Report# 149-2,3,4,5 & 6,7
8021
Date 6-20-96
1) Method blank sample associated with field samples analyzed on 5-22-96 is
attached (VBLK052196).
2) See attached for acceptance limits for actual values and as percent recovery
data for 8021 MS/MSD. RPO limits for 8021 MS/MSD are 30%. The MS/MSD
are reported as both actual concentrations as well percent recovered in the
original report. LCS QC percent recovery limits for 8021 are 60-140% pending
development of new limits.
3) See attached for surrogate QC limits. The same limits are used for the 8021
soil and water pending development of separate limits for the waters.
4) Attached is the corrected master sample list.
5) See attached revised dilution log for case narrative for project 149-6. This
revision relfects the dilution of sample 10567.
6230D
1) See attached for the acceptance limits as actual values and percent recovery
data for 6230D MS/MSD. RPO limits for 6230D MS/MSD are 30%. The MS/MSD
and LCS are reported as both actual concentrations as well. as percent
recovered in the original report. The LCS acceptance limits for recovery are 60-
140%.
2) Samples associated with initial and continuing calibration data.
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PARADIGM ANAL\TICAL LABORATORIES, INC.
Project # 6 & 7
Batch 060396 Initial Calibration Curve
Continuing Calibration -060396
Associated Samples: 10616, 10620, 10622, 10623, 10624
Continuing Calibration -060496
Associated Samples: 10619,10621
Project # 3 & 5
Sincerely,
Batch 052196 Initial Calibration Curve
Continuing Calibration -052296
Associated Samples: 10321, 10322, 10323, 10419, 10420
Batch 052396 Initial Calibration Curve
Continuing Calibration -052396
Associated Samples: 10317,10318, 10324, 10418
Paradigm Analytical Laboratories
Yvl\ O ~
Laboratory Director
Mark Randall
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SURROGATES:
BLANKS:
PARADIGM ANALYTICAL LABORATORIES, INC.
CASE NARRATIVE FOR PROJECTS 149-2,3,4,5
LTO # 20755
149-2 all within acceptance criteria
149-3 all within acceptance criteria
149-4 all within acceptance criteria
149-5 all within acceptance criteria
149-2,3,4,5
All compounds BQL.
MATRIX SPIKES/MATRIX SPIKE DUPLICATES:
8021
149-2 & 4
6230D
MS/MSD
All compounds within recovery acceptance criteria.
All compounds within RPO criteria (30%)
MS/MSD spiked at 20 ppb
149-3 & 5
MS/MSD
1 compound failed recovery acceptance
4 compounds failed RPO acceptance (30%)
LCS
All compounds within acceptance criteria.
MS/MSD/LCS spiked at 5 ppb
HOLDING TIME:
DILUTIONS:
COMMENTS:
All samples analyzed within holding time
8021 MS/MSD analyzed out of hold time. ( Per client request)
149-2 No dilutions necessary
149-3 Sample 10418 -Hall side diluted 2x due to high target cmpds.
149-4 No dilutions necessary
149-5 No dilutions necessary
All reported results were qualitatively confirmed by GC/MS.
- --

-

-
--------------Samples
G149-2 SS-3-10 10310 B021-SO
G149-2 ss 4-4 10311 B021-S0
G149-2 ss 4-10 10312 B021-SO
G149-2 SS-2-4 10313 8021-SO
G149-2 EB-01-SS 10314 B021-WA
G149-2 REP-01-SS 10315 B021-S0
G149-2 TB-01-(5I15I96) 10316 B021-WA
G149-3 J3B020 10317 62300-WA
G149-3 J38019 1031B 62300-WA
G149-3 J3B019-MS 10319 62300-WA
G149-3 J38019-MSD 10320 62300-WA
G149-3 REP-01-MW 10321 62300-WA
G149-3 EB-01-MW 10322 62300-WA
G149-3 PW 10323 62300-WA
G149-3 TB-01(5I15I96) 10324 62300-WA
G149-4 SS-5-4 103B6 8021-SO
G149-4 SS-5-10 10387 B021-SO
G149-4 SS-6-4 1038B 8021-SO
G149-4 SS-5-10MS 103B9 8021-S0
G149-4 SS-5-10MSD 10390 B021-SO
G149-4 TB-02 5117196 10391 B021-WA
G149-5 GW-1 10418 62300-WA
G149-5 EB-01-GW 10419 62300-WA
G149-5 TB-02-5I17/96 10420 62300-WA
Date Printed 06/20/96
Paga 1
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Project # 149-6
Project #149-7
PARADIGM ANALYTICAL LABORATORIES, INC.
Dilutions
Sample ID Dilution
Hall PIO
10567 1x 125x
10568 1x 10x
10571 1x 125x
10573 1x 500x
10575 10x 125x
10579 1x 125x
10619 20x 5x
-10621 25x 1x
10622 25x 1x
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PARADIGM ANALYTICAL LABORATORIES, INC.
1,4-Dichlorobutane
Trifluorotoluene
Surrogate Recovery Umits
6230D
85-120%
85-122%
8021
83-123%
84-122%
I PARADIGi\I ANALYTICAL LABORATORIES. INC.
Results for Volatiles
I by GC 8021
Client Sample ID: SS-1-2 Analyzed By: RNP
I
Client Project ID: NC0360.041, GRESHAMS LAKE #29 Date Collected: 05/15/96
Lab Sample ID: 10307 Date Received: 05/16/96
Lab Project ID: G149-2 %Solids: 89.5 Matrix: Soil
I Compound Date Quantitation Result
Analyzed Dilution Limit (ug/KG) (ug/KG)
I Benzene 5/29/96 1 1.1 SOL
Bromobenzene 5/29/96 2.2 SOL
I Bromochloromethane 5/29/96 1 .1 SOL
Bromodichloromethane 5/29/96 1 .1 SOL
Bromoform 5/29/96 1 2.2 SOL
I Bromomethane 5/29/96 1 2.2 SOL
n-Butylbenzene 5/29/96 1 1.1 SOL
sec-Butyl benzene 5/29/96 1 1.1 BOL
I tert-Butylbenzene 5/29/96 1 1.1 SOL
Carbon tetrachloride 5/29/96 1 1.1 BOL
Chlorobenzene 5/29/96 1 1.1 SOL
Chloroethane 5/29/96 1 1. 1 SOL
I Chloroform 5129/96 1 1.1 SOL
Chloromethane 5/29/96 1 1.1 SOL
2-Chlorotoluene 5/29/96 1 1.1 SOL
I 4-Chlorotoluene 5/29/96 1 2.2 SOL
Dibromochloromethane 5/29/96 1 1.1 BQL
1,2-Dibromo-3-chloropropane 5/29/96 1 1.1 SOL
I 1 ,2-Dibromoethane (EDS) 5/29/96 1 1.1 SOL
Dibromomethane 5/29/96 1 1.1 SOL
1 ,2-Dichlorobenzene 5/29/96 1 1.1 SOL
I 1,3-Dichlorobenzene 5/29/96 1 1.1 BOL
1,4-Dichlorobenzene 5/29/96 1 1.1 SOL
Dichlorodifluoromethane 5i29/96 1 1.1 SOL
I 1 , 1-Dichloroethane 5/29/96 1 1.1 SOL
1,2-Dichloroethane 5/29/96 1 1.1 SOL
1 , 1-Dichloroethene 5/29/96 1 1.1 SOL
cis-1,2-Dichloroethene 5/29/96 1 1.1 SOL
I trans-1,2-Dichloroethene 5/29/96 1 1.1 SOL
1,2-Dichloropropane 5/29/96 1 1.1 SOL
2,2-Dichloropropane 5/29/96 1 2.2 SOL
I cis-1,3-Dichloropropane 5/29/96 1 1.1 SOL
trans-1,3-Dichloropropane 5/29/96 1 1.1 SOL
Diisopropyl ether (DIPE) 5/29/96 1 1.1 SOL
I Ethylbenzene 5/29/96 1 1.1 SOL
Hexachlorobutadiene 5/29/96 1 1.1 SOL
lsopropylbenzene 5/29/96 1 1.1 SOL
I p-lsopropyltoluene 5/29/96 1 1.1 SOL
Methyl-tert butyl ether (MTBE) 5/29/96 1 1.1 BOL
Methylene Chloride 5/29/96 1 5.6 SOL
I Naphthalene 5/29/96 1 1.1 SOL
n-Propylbenzene 5/29/96 1 1.1 SOL
I Flags:
SOL= Below Ouantitation Limit
r.i ... ,.." ~ "'' ..,
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PARADIGM Ai\ALYTICAL LABORATORIES, l!\C.
Results for Volatiles
by GC 8021
Client Sample ID: SS-1-2 Analyzed By: RNP
Client Project ID: NC0360.041, GRESHAMS LAKE #29 Date Collected: 05/15/96
Lab Sample ID: 10307 Date Received: 05/16/96
Lab Project ID: G149-2 %Solids: 89.5 Matrix: Soil
Compound
Styrene
1, 1, 1,2-Tertrachloroethane
1, 1,2,2-Tertrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1 , 1 , 1-Trichloroethane
1, 1,2-Trichloroethane
Trichloroethene
Trichlorofluromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl Chloride
m/p-Xylene
o-Xylene
Surrogate Spike Recoveries
1 ,4-Dichlorobutane
Trifluorotoluene
Date
Analyzed
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
Dilution
1
1
1
1
1
1
1
1
1
1
1
1
1
Spike
Added
40
40
Quantitation
Limit (ug/KG)
2.2
1.1
1.1
1.1
1.1
1.1
1.1
1.1
1.1
1.1
1.1
2.2
1.1
2.2
1.1
2.2
2.2
Spike
Result
37
40
Result
(ug/KG)
BOL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
SOL
BQL
BQL
BQL
Percent
Recovered
92
100
Comments:
All values corrected for dilution and %solids.
Reviewed By: tvy,-..,
Flags:
BQL = Below Quantitation Limit
I PARADIGM ANALYTICAL LARORATORIES, INC.
Results for Volatiles
I by GC 8021
Client Sample ID: SS-1-10 Analyzed By: RNP
Client Project ID: NC0360.041, GRESHAMS LAKE #29 Date Collected: 05/15/96 I Lab Sample ID: 10308 Date Received: 05/16/96
Lab Project ID: G149-2 %Solids: 86.6 Mairix: Soil
I Compound Date Quantitation Result
Analyzed Dilution Limit (ug/KG) (ug/KG)
I Benzene 5/29/96 1 1.2 BQL
Bromobenzene 5/29/96 1 2.3 BQL
I Bromochloromethane 5/29/96 1 1.2 BQL
Bromodichloromethane 5/29/96 1 1.2 BQL
Bromoform 5/29/96 1 2.3 BQL
I Bromomethane 5/29/96 1 2.3 BQL
n-Butylbenzene 5/29/96 1 1.2 BQL
sec-Butylbenzene 5/29/96 1.2 BQL
tert-Butylbenzene 5/29/96 1 1.2 BQL I Carbon tetrachloride 5/29/96 1 1.2 BQL
Chlorobenzene 5/29/96 1 1.2 BQL
Chloroethane 5/29/96 1.2 BQL
I Chloroform 5/29/96 1.2 BQL
Chloromethane 5/29/96 1 1.2 BQL
2-Chlorotoluene 5/29/96 1 1.2 BQL
I 4-Chlorotoluene 5/29/96 1 2.3 BQL
Dibromochloromethane 5/29/96 1 1.2 BQL
1,2-Dibromo-3-chloropropane 5/29/96 1 1.2 BQL
I 1,2-Dibromoethane (EDS) 5/29/96 1.2 BQL
Dibromomethane 5/29/96 1 1.2 BQL
1,2-Dichlorobenzene 5/29/96 1 1.2 BQL
I 1,3-Dichlorobenzene 5/29/96 1 1.2 BQL
1 ,4-Dichlorobenzene 5/29/96 1 1.2 BQL
Dichlorodifluoromethane 5/29/96 1 1.2 BQL
1, 1-Dichloroethane 5/29/96 1 1.2 BQL I 1,2-Dichloroethane 5/29/96 1 1.2 BQL
1 , 1-Dichloroethene 5/29/96 1 1.2 BQL
cis-1,2-Dichloroethene 5/29/96 1 1.2 BQL
I trans-1,2-Dichloroethene 5/29/96 1 1.2 BQL
1,2-Dichloropropane 5/29/96 1.2 BQL
2,2-Dichloropropane 5/29/96 1 2.3 BQL
I cis-1,3-Dichloropropane 5/29/96 1 1.2 BQL
trans-1,3-Dichloropropane 5/29/96 1 1.2 BQL
Diisopropyl ether (DIPE) 5/29/96 1 1.2 BQL
I Ethylbenzene 5/29/96 1 1.2 BQL
Hexachlorobutadiene 5/29/96 1 1.2 BQL
lsopropylbenzene 5/29/96 1 1.2 BQL
I p-lsopropylloluene 5/29/96 1 1.2 BQL
Methyl-tert butyl ether (MTBE) 5/29/96 1 1.2 BQL
Methylene Chloride 5/29/96 1 5.8 BQL
Naphthalene 5/29/96 1 1.2 BQL I n-Propylbenzene 5/29/96 1 1.2 BQL
I Flags:
BQL = Below Quantitation Limit
D..,,..,.. " ..,, ..,
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PARADIGM ANALYTICAL LABORATORIES, li\C.
Results for Volatiles
by GC 8021
Client Sample ID: SS-1-10 Analyzed By: RNP
Client Project ID: NC0360.041, GRESHAMS LAKE #29 Date Collected: 05/15/96
Lab Sample ID: 10308 Date Received: 05/16/96
Lab Project ID: G149-2 %Solids: 86.6 Matrix: Soil
Compound
Styrene
1 , 1 , 1 ,2-Tertrachloroethane
1, 1,2,2-Tertrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1, 1, 1-Trichloroethane
1 , 1 ,2-Trichloroethane
Trichloroethene
Trichlorofluromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
.Vinyl Chloride
m/p-Xylene
o-Xylene
Surrogate Spike Recoveries
1,4-Dichlorobutane
Trifluorotoluene
Date
Analyzed
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
Dilution
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
Spike
Added
40
40
Quantitation
Limit (ug/KG)
2.3
1.2
1.2
1.2
1.2
1.2
1.2
1.2
1.2
1.2
1.2
2.3
1.2
2.3
1.2
2.3
2.3
Spike
Result
38
40
Result
(ug/KG)
BQL
BQL
BQL
BQL
BQI:.
BQL
BQL
BQL
BQL
BQL
BQL
.BQL
BQL
BQL
BQL
BQL
BQL
Percent
Recovered
95
100
Comments:
All values corrected for dilution and %solids.
Reviewed By: )INh.
Flags:
BQL = Below Quantitation Limit
I PARADIGi\1 ANALYTICAL LABORATORIES. INC.
Results for Volatiles
I by GC 8021
Client Sample ID: SS-3-4 Analyzed By: RNP
I Client Project ID: NC0360.041, GRESHAMS LAKE #29 Date Collected: 05/15/96
Lab Sample ID: 10309 Date Received: 05/16/96
Lab Project ID: G149-2 %Solids: 85.0 Matrix: Soil
I Compound Date Quantitation Result
Analyzed Dilution Limit (ug/KG) (ug/KG)
I Benzene 5129/96 1 1.2 BQL
Bromobenzene 5/29/96 1 2.4 BQL
I Bromochloromethane 5/29/96 1 1.2 BQL
Bromodichloromethane 5129/96 1 1.2 BQL
Bromoform 5/29/96 2.4 BQL
I Bromomethane . 5/29/96 2.4 BQL
n-Butylbenzene 5129/96 1 1.2 BQL
sec-Butylbenzene 5129/96 1 1.2 BQL
I tert-Butylbenzene 5129/96 1 1.2 BQL
Carbon tetrachloride 5129/96 1 1.2 BQL
Chlorobenzene 5129/96 1 1.2 BQL
I Chloroethane 5129/96 1 1.2 BQL
Chloroform 5/29/96 1 1.2 BQL
Chloromethane 5129/96 1 1.2 BQL
2-Chlorotoluene 5129/96 1 1.2 BQL
I 4-Chlorotoluene 5129/96 1 2.4 BQL
Dibromochloromethane 5129/96 1.2 BQL
1 ,2-Dibrnmo-3-chloropropane 5129/96 1 1.2 BQL
I 1 ,2-Dibromoethane (EDB) 5129/96 1 1.2 BQL
Dibromomethane 5/29/96 1 1.2 BQL
1,2-Dichlorobenzene 5/29/96 1 1.2 BQL
I 1,3-Dichlorobenzene 5129/96 1 1.2 BQL
1,4-Dichlorobenzene 5129/96 1 1.2 BQL
Dichlorodifluoromethane 5/29/96 1 1.2 BQL
I 1, 1-Dichloroethane 5129/96 1 1.2 BQL
1 ,2-Dichloroethane 5/29/96 1 1.2 BQL
1 , 1-Dichloroethene 5/29/96 1 1.2 BQL
I cis-1,2-Dichloroethene 5/29/96 1 1.2 BQL
trans-1,2-Dichloroethene 5129/96 1, 1.2 BQL
1,2-Dichloropropane 5129/96 1 1.2 BQL
2,2-Dichloropropane 5129/96 1 2.4 BQL
I cis-1,3-Dichloropropane 5129/96 1 1.2 BQL
trans-1,3-Dichloropropane 5/29/96 1 1.2 BQL
Diisopropyl ether (DIPE) 5129/96 1 1.2 BQL
I Ethyl benzene 5/29/96 1 1.2 BQL
Hexachlorobutadiene 5/29/96 1 1.2 BQL
lsopropylbenzene 5/29/96 1 1.2 BQL
I p-lsopropyltoluene 5/29/96 1 1.2 BQL
Methyl-tert butyl ether (MTBE) 5/29/96 1 1.2 BQL
Methylene Chloride 5/29/96 1 5.9 BQL
I Naphthalene 5/29/96 1 1.2 BQL
n-Propylbenzene 5/29/96 1 1.2 BQL
I Flags:
BQL = Below Quantitation Limit
,...., ---., -, ...
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PARADIGM Ai\AL\TICAL LABORATORIES. li\C.
Client Sample ID: SS-3-4
Results for Volatiles
byGC 8021
Client Project ID: NC0360.041, GRESHAMS LAKE #29
Lab Sample ID: 10309
Lab Project ID: G149-2 %Solids: 85.0
Compound
Styrene
1, 1, 1,2-Tertrachloroethane
1, 1,2,2-Tertrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1, 1, 1-Trichloroethane
1, 1,2-Trichloroethane
Trichloroethene
Trichlorofluromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl Chloride
m/p-Xylene
o-Xylene
Surrogate Spike Recoveries
1,4-Dichlorobutane
Trifluorotoluene
Date
Analyzed
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
Dilution
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
Spike
Added
40
40
Comments:
All values corrected for dilution and %solids.
Flags:
SOL = Below Ouantitation Limit
Analyzed By: RNP
Date Collected: 05/15/96
Date Received: 05/16/96
Matrix: Soil
Quantitation
Limit (ug/KG)
2.4
1.2
1.2
1.2
1.2
1.2
1.2
1.2
1.2
1.2
1.2
2.4
1.2
2.4
1.2
2.4
2.4
Spike
Result
38
40
Result
(ug/KG)
SOL
SOL
SOL
SOL
SOL
SOL
SOL
SOL
SOL
SOL
SOL
SOL
SOL
SOL
SOL
BOL
SOL
Percent
Recovered
95
100
Reviewed By: tvvh.
I PARADIGl\1 A!\AL\TICAL LABORATORIES. I!\C.
Results for Volatiles
I by GC 8021
Client Sample ID: SS-3-10 Analyzed By: RNP
Client Project ID: NC0360.041, GRESHAMS LAKE #29 Date Collected: 05/15/96
I Lab Sample ID: 10310 Date Received: 05/16/96
Lab Project ID: G149-2 %Solids: 90.4 Matrix: Soil
I Compound Date Quantitation · Result
Analyzed Dilution Limit (ug/KG) (ug/KG)
I Benzene 5/29/96 1 1.1 BQL
Bromobenzene 5/29/96 1 2.2 BQL
I Bromochloromethane 5/29/96 1 1 .1 SOL
Bromodichloromethane 5/29/96 1 1.1 BQL
Bromoform 5/29/96 1 2.2 BQL
I Bromomethane 5/29/96 1 2.2 BQL
n-Butylbenzene 5/29/96 1 1.1 BQL
sec-Butylbenzene 5/29/96 1 1.1 BQL
tert-Butylbenzene 5/29/96 1 1.1 BQL
I Carbon tetrachloride 5/29/96 1 1.1 BOL
Chlorobenzene 5/29/96 1 1 .1 BQL
Chloroethane 5/29/96 1 1 .1 .BOL
I Chloroform 5.129/96 1 1.1 BQL
Chloromethane 5/29/96 1 1. 1 BQL
2-Chlorotoluene 5/29/96 1 1.1 BQL
I 4-Chlorotoluene 5/29/96 1 2.2 BQL
Dibromochloromethane 5/29/96 1 1.1 BQL
1,2-Dibromo-3-chloropropane 5/29/96 1 . 1.1 BQL
I 1,2-Dibromoethane (EDB) 5/29/96 1 1.1 BQL
Dibromomethane 5/29/96 1 1. 1 BQL
1,2-Dichlorobenzene 5/29/96 1 1.1 BQL
I 1,3-Dichlorobenzene 5/29/96 1 1.1 BOL
1 ,4-Dichlorobenzene 5/29/96 1 1.1 BQL
Dichlorodinuoromethane 5/29/96 1 1.1 BOL
1, 1-Dichloroethane 5/29/96 1 1.1 BQL
I 1,2-Dichloroethane 5/29/96 1 1.1 BQL
1, 1-Dichloroethene 5/29/96 1.1 BQL
cis-1,2-Dichloroethene 5/29/96 1 1.1 BQL
I trans-1,2-Dichloroethene 5/29/96 1 1.1 BQL
1,2-Dichloropropane 5/29/96 1 1.1 BQL
2,2-Dichloropropane 5/29/96 1 2.2 BQL
I cis-1,3-Dichloropropane 5/29/96 1 1.1 BOL
trans-1,3-Dichloropropane 5/29/96 1 1.1 BQL
Diisopropyl ether (DIPE) 5129/96 1 1.1 BQL
I Ethylbenzene 5/29/96 1 1.1 BQL
Hexachlorobutadiene 5/29/96 1 1.1 BQL
lsopropylbenzene 5/29/96 1 1.1 BQL
I p-lsopropyltoluene 5/29/96 1 1.1 BQL
Methyl-tert butyl ether (MTBE) 5/29/96 1 1.1 BOL
Methylene Chloride 5/29/96 1 5.5 BQL
Naphthalene 5/29/96 1 1.1 BQL
I n-Propylbenzene 5/29/96 1 1.1 BQL
I Flags:
BQL = Below Quantitation Limit
P~ne 1 of 2
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PARADIGi\l ANALYTICAL LABORATORIES, INC.
Results for Volatiles
by GC 8021
Client Sample ID: SS-3-10
Client Project ID: NC0360.041, GRESHAMS LAKE #29
Lab Sample ID: 10310
Lab Project ID: G149-2
Compound
Styrene
1, 1, 1,2-Tertrachloroethane
1, 1,2,2-Tertrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1, 1, 1-Trichloroethane
1, 1,2-Trichloroethane
Trichloroethene
Trichlorofluromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl Chloride
m/p-Xylene
o-Xylene
Surrogate Spike Recoveries
1,4-Dichlorobutane
Trifluorotoluene
Comments:
%Solids: 90.4
Date
Analyzed
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
Dilution
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
Spike
Added
40
40
All values corrected for dilution and %solids.
Flags:
BQL = Below Quantitation Limit
Analyzed By: RNP
Date Collected: 05/15/96
Date Received: 05/16/96
Matrix: Soil
Quantitation
Limit (ug/KG)
2.2
1.1
1.1
1.1
1.1
1.1
1.1
1.1
1.1
1.1
1.1
2.2
1.1
2.2
1.1
2.2
2.2
Spike
Result
39
40
Result
(ug/KG)
BQL
BQL
BQL
BOL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BOL
BQL
BQL
BQL
BQL
Percent
Recovered
98
100
Reviewed By: )'V'n-,.,
PROP. 2 of 2
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PARADIGi\1 ANALYTICAL LABORATORIES, INC.
Flags;
Client Sample ID: SS 4-4
Results for Volatiles
by GC 8021
Client Project ID: NC0360.041, GRESHAMS LAKE #29
Lab Sample ID: 10311
Lab Project ID; G149-2 %Solids: 82.5
Compound
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
Dibromochloromethane
1,2-Dibromo-3-chloropropane
1,2-Dibromoethane (EDS)
Dibromomethane
1 ,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1 , 1-Dichloroethane
1,2-Dichloroethane
1 , 1-Dichloroethene
cis-1,2-Dichloroethene
trans-1 ,2-Dichloroethene
1,2-Dichloropropane
2,2-Dichloropropane
cis-1,3-Dichloropropane
trans-1,3-Dichloropropane
Diisopropyl ether (DIPE)
Ethyl benzene
Hexachlorobutadiene
lsopropylbenzene
p-lsopropyltoluene
Methyl-tert butyl ether (MTBE)
Methylene Chloride
Naphthalene
n-Propylbenzene
Date
Analyzed
5129/96
5129/96
5129/96
5129/96
5129/96
5129/96
5129/96
5/29/96
5129/96
5129/96
5129/96
5129/96
5129/96
5129/96
5129/96
5129/96
5129/96
5129/96
5129/96
5129/96
5129/96
5129/96
5129/96
5129/96
5129/96
5129/96
5129/96
5129/96
5129/96
5129/96
5129/96
5129/96
5129/96
5129/96
5129/96
5129/96
5129/96
5129/96
5129/96
5129/96
5129/96
5129/96
Dilution
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
BQL = Below Quantitation Limit
Analyzed By: RNP
Date Collected: 05/15/96
Date Received: 05/16/96
Matrix: Soil
Quantitation
Limit (ug/KG)
1.2
2.4
1.2
1.2
2.4
2.4
1.2
1.2
1.2
1.2
1.2
1.2
1.2
1.2
1.2
2.4
1.2
1.2
1.2
1.2
1.2
1.2
1.2
1.2
1.2
1.2
1.2
1.2
1.2
1.2
2.4
1.2
1.2
1.2
1.2
1.2
1.2
1.2
1.2
6.1
1.2
1.2
Result
(ug/KG)
BQL
SOL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
SOL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
Pa9e 1 of 2
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PARADIGi\1 Ai\AL\TICAL LABORATORIES, l'.\C.
Client Sample ID: SS 4-4
Results for Volatiles
by GC 8021
Client Project ID: NC0360.041, GRESHAM$ LAKE #29
Lab Sample ID: 10311
Lab Project ID: G149-2 %Solids: 82.5
Compound
Styrene
1, 1, 1,2-Tertrachloroethane
1, 1,2,2-Tertrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1, 1, 1-Trichloroethane
1, 1,2-Trichloroethane
Trichloroethene
Trichlorofluromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl Chloride
m/p-Xylene
o-Xylene
Surrogate Spike Recoveries
1,4-Dichlorobutane
Trifluorotoluene
Date
Analyzed
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
Dilution
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
Spike
Added
40
40
Comments:
All values corrected for dilution and %solids.
Flags:
BQL = Below Quantitation Limit
Analyzed By: RNP
Dale Collected: 05/15/96
Date Received: 05/16/96
Matrix: Soil
Quantitation
Limit (ug/KGJ
2.4
1.2
1.2
1.2
1.2
1.2
1.2
1.2
1.2
1.2
1.2
2.4
1.2
2.4
1.2
2.4
2.4
Spike
Result
38
40
Result
(ug/KGJ
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BOL
BQL
BQL
BQL
BQL
BQL
BOL
BQL
BQL
BQL
Percent
Recovered
95
100
Reviewed By: tw>x:
Paae 2 of 2
I PARADIGM ANALYTICAL LABORATORIES. l:\C.
Results for Volatiles
I by GC 8021
Client Sample ID: SS 4-10 Analyzed By: RNP
Client Project ID: NC0360.041, GRESHAMS LAKE #29 Date Collected: 05/15/96
I Lab Sample ID: 10312 Date Received: 05/16/96
lab Project ID: G149-2 %Solids: 78.1 Matrix: Soil
I Compound Date Quantitation Result
Analyzed Dilution limit (ug/KG) (ug/KG)
I Benzene 5/29/96 1 1.3 BQL
Bromobenzene 5/29/96 2.6 BQL
I Bromochloromethane 5/29/96 1.3 BQL
Bromodichloromethane 5/29/96 1 1.3 BQL
Bromoform 5/29/96 1 2.6 BQL
I Bromomethane 5/29/96 1 2.6 BQL
n-Butylbenzene 5/29/96 1 1.3 BQL
sec-Butyl benzene 5/29/96 1.3 BQL
tert-Butylbenzene 5/29/96 1 1.3 SOL I Carbon tetrachloride 5/29/96 1 1.3 BQL
Chlorobenzene 5/29/96 1.3 BQL
Chloroethane 5129/96 1 1.3 BQL
I Chloroform 5/29/96 1 1.3 BQL
Chloromethane 5129/96 1 1.3 BQL
2-Chlorotoluene 5/29/96 1 1.3 BQL
I 4-Chlorotoluene 5/29/96 1 2.6 SOL
Dibromochloromethane 5/29/96 1 1.3 BQL
1,2-Dibromo-3-chloropropane 5129/96 1 1.3 BQL
I 1 ,2-Dibromoethane (EDS) 5/29/96 1 1.3 BQL
Dibromomethane 5/29/96 1 1.3 BQL
1 ,2-Dichlorobenzene 5/29/96 1 1.3 BQL
I 1,3-Dichlorobenzene 5/29/96 1 1.3 BQL
1,4-Dichlorobenzene 5129/96 1 1.3 BQL
Dichlorodifluoromethane 5/29/96 1 1.3 BQL
1 , 1-Dichloroethane 5129/96 1 1.3 BQL I 1,2-Dichloroethane 5/29/96 1 1.3 BQL
1, 1-Dichloroethene 5/29/96 1 1.3 BQL
cis-1 ,2-Dichloroethene 5/29/96 1 1.3 BQL
I trans-1,2-Dichloroethene 5/29/96 1.3 BQL
1 ,2-Dichloropropane 5/29/96 1.3 BQL
2,2-Dichloropropane 5/29/96 1 2.6 BQL
I cis-1,3-Dichloropropane 5/29/96 1 1.3 BQL
trans-1,3-Dichloropropane 5/29/96 1 1.3 BQL
Diisopropyl ether (DIPE) 5/29/96 1 1.3 BQL
I Ethyl benzene 5/29/96 1 1.3 BQL
Hexachlorobutadiene 5129/96 1 1.3 BQL
lsopropylbenzene 5129/96 1 1.3 BQL
I p-lsopropyltoluene 5129/96 1 1.3 BQL
Methyl-tert butyl ether (MTBE) 5/29/96 1 1.3 BQL
Methylene Chloride 5/29/96 1 6.4 BQL
Naphthalene 5129/96 1 1.3 BQL I n-Propylbenzene 5129/96 1 1.3 BQL
I Flags:
BQL = Below Quanlilalion Limit
C~nn -f nf ')
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PARADIG:\I ANALYTICAL LABORATORIES, 1\C.
Client Sample ID: SS 4-10
Results for Volatiles
by GC 8021
Client Project ID: NC0360.041, GRESHAMS LAKE #29
Lab Sample ID: 10312
Lab Project ID: G149-2 %Solids: 78.1
Compound
Styrene
1, 1, 1,2-Tertrachloroethane
1, 1,2,2-Tertrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1, 1, 1-Trichloroethane
1, 1,2-Trichloroethane
Trichloroethene
Trichlorofluromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl Chloride
m/p-Xylene
a-Xylene
Surrogate Spike Recoveries
1,4-Dichlorobutane
Trifluorotoluene
Date
Analyzed
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
Dilution
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
Spike
Added
40
40
Comments:
All values corrected for dilution and %solids.
Flags:
BQL = Below Quantitation Limit
Analyzed By: RNP
Date Collected: 05/15/96
Date Received: 05/16/96
Matrix: Soil
Quantitation
Limit (ug/KG)
2.6
1.3
1.3
1.3
1.3
1.3
1.3
1.3
1.3
1.3
1.3
2.6
1.3
2.6
1.3
2.6
2.6
Spike
Result
38
40
Result
(ug/KG)
BOL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
Percent
Recovered
95
100
Reviewed By: Mo:-:::
D~no ') nf ')
I PARADIGi\l A!\AL\TICAL LABORATORIES. l!\C.
Results for Volatiles
I by GC 8021
Client Sample ID: SS-2-4 Analyzed By: RNP
Client Project ID: NC0360.041, GRESHAM$ LAKE #29 Date Collected: 05/15/96
I Lab Sample ID: 10313 Date Received: 05/16/96
Lab Project ID: G149-2 %Solids: 95.6 Matrix: Soil
I Compound Date Quantitation Result
Analyzed Dilution Limit (ug/KG) (ug/KG)
I Benzene 5/29/96 1 1 BQL
Bromobenzene 5/29/96 1 2.1 BQL
I Bromochloromethane 5/29/96 1 1 BQL
Bromodichloromethane 5/29/96 1 1 BQL
Bromofonn 5/29/96 2.1 BQL
I Bromomethane 5/29/96 1 2.1 BQL
n-Butylbenzene 5/29/96 1 1 BQL
sec-Butylbenzene 5/29/96 1 1 BQL
tert-Butylbenzene 5/29/96 1 1 BQL I Carbon tetrachloride 5/29/96 1 BQL
Chlorobenzene 5/29/96 1 1 BQL
Chloroethane 5/29/96 1 1 BQL
I Chlorofonn 5/29/96 1 1 BQL
Chloromethane 5/29/96 1 1 BOL
2-Chlorotoluene 5/29/96 1 1 BQL
I 4-Chlorotoluene 5/29/96 1 2.1 BQL
Dibromochloromethane 5/29/96 1 BQL
1 ,2-Dibromo-3-chloropropane 5/29/96 1 1 BQL
I 1 ,2-Dibromoethane (EDB) 5/29/96 1 1 BQL
Dibromomethane 5/29/96 1 1 BQL
1,2-Dichlorobenz_ene 5/29/96 1 1 BQL
I 1,3-Dichlorobenzene 5/29/96 1 1 BQL
1 ,4-Dichlorobenzene 5/29/96 1 1 BQL
Dichlorodifluoromethane 5/29/96 1 1 BQL
1, 1-Dichloroethane 5/29/96 1 1 BQL I 1,2-Dichloroethane 5/29/96 1 1 BQL
1, 1-Dichloroethene 5/29/96 1 1 BQL
cis-1,2-Dichloroethene 5/29/96 1 1 BQL
I trans-1,2-Dichloroethene 5/29/96 1 1 BQL
1,2-Dichloropropane 5/29/96 1 1 BQL
2,2-Dichloropropane 5/29/96 1 2.1 BQL
I cis-1,3-Dichloropropane 5/29/96 1 1 BQL
trans-1,3-Dichloropropane 5/29/96 1 1 BQL
Diisopropyl ether (DIPE) 5/29/96 1 1 BQL
I Ethylbenzene 5/29/96 1 1 BQL
Hexachlorobutadiene 5/29/96 1 1 BQL
lsopropylbenzene 5/29/96 1 1 BQL
I p-lsopropyltoluene 5/29/96 1 1 BQL
Methyl-tert butyl ether (MTBE) 5/29/96 1 1 BQL
Methylene Chloride 5/29/96 1 5.2 BQL
I Naphthalene 5/29/96 1 1 BQL
n-Propylbenzene 5/29/96 1 1 BQL
I Flags:
BQL = Below Quantitation Limit
o .......... ◄ ,.,, ..,
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PARADIGM ANALYTICAL LABORATORIES. INC.
Results for Volatiles
by GC B021
Client Sample ID: SS-2-4
Client Project ID: NC0360.041, GRESHAM$ LAKE #29
Lab Sample ID: 10313
Lab Project ID: G 149-2
Compound
Styrene
1, 1, 1,2-Tertrachloroethane
1, 1,2,2-Tertrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1, 1, 1-Trichloroethane
1, 1,2-Trichloroethane
Trichloroethene
Trichlorofluromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl Chloride
m/p-Xylene
o-Xylene
Surrogate Spike Recoveries
1,4-Dichlorobutane
Trifluorotoluene
Comments:
%Solids: 95.6
Date
Analyzed
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
Dilution
1
1
1
1
1
1
1
1
1
1
1
1
Spike
Added
40
40
All values corrected for dilution and %solids.
Flags:
BQL = Below Quantitation Limit
Analyzed By: RNP
Date Collected: 05/15/96
Date Received: 05/16/96
Matrix: Soil
Quantitation
Limit (ug/KGJ
2.1
1
1
1
1
1
1
1
1
1
1
2.1
1
2.1
1
2.1
2.1
Spike
Result
35
40
Result
(ug/KGJ
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
Percent
Recovered
87
100
Reviewed By: l"M::-<
o~no ., ,-,.f.,
I PARADIGM ANALYTICAL LABORATORIES. INC.
Results for Volatiles
I by GC 8021
Client Sample ID: EB-01-SS Analyzed By: RNP
Client Project ID: NC0360.041, GRESHAMS LAKE #29 Date Collected: 05/15/96
I Lab Sample ID: 10314 Date Received: 05/16/96
Lab Project ID: G149-2 Matrix: Water
I Compound Date Quantitation Result
Analyzed Dilution Limit (ug/L) (ug/L)
I Benzene 5122/96 1 BQL
Bromobenzene 5122/96 1 2 BQL
I Bromochloromethane 5122/96 1 BQL
Bromodichloromethane 5122/96 1 BQL
Bromoform 5/22/96 1 2 BQL
Bromomethane 5122/96 1 2 BQL I n-Butylbenzene 5122/96 1 1 BQL
sec-Butylbenzene 5122/96 1 1 BQL
tert-Butylbenzene 5122/96 1 1 BQL
I Carbon tetrachloride 5122/96 1 1 BQL
Chlorobenzene 5122/96 1 1 BQL
Chloroethane 5122/96 1 1 BQL
I Chloroform 5122/96 1 1 BQL
Chloromethane 5122/96 1 1 BQL
2-Chlorotoluene 5122/96 1 1 BQL
I 4-Chlorotoluene 5122/96 1 2 BQL
Dibromochloromethane 5122/96 1 1 BQL
1 ,2-Dibromo-3-chloropropane 5122/96 1 1 BQL
I 1 ,2-Dibromoethane (EDB) 5122/96 1 1 BQL
Dibromomethane 5122/96 1 1 BQL
1 ,2-Dichlorobenzene 5/22/96 1 1 BQL
I 1,3-Dichlorobenzene 5/22/96 1 1 BQL
1,4-Dichlorobenzene 5122/96 1 1 BQL
Dichlorodifluoromethane 5122/96 1 1 BQL
1, 1-Dichloroethane 5122/96 1 1 BQL
I 1,2-Dichloroethane 5122/96 1 1 BQL
1 , 1-Dichloroethene 5122/96 1 1 BQL
cis-1,2-Dichloroethene 5122/96 1 1 BQL
I trans-1 ,2-Dichloroethene 5122/96 1 1 BQL
1 ,2-Dichloropropane 5/22/96 1 1 BQL
2,2-Dichloropropane 5/22/96 1 2 BQL
I cis-1,3-Dichloropropane 5/22/96 1 1 BOL
trans-1,3-Dichloropropane 5/22/96 1 1 BQL
Diisopropyl ether (DIPE) 5122/96 1 1 BQL
I Ethyl benzene 5122/96 1 1 BQL
Hexachlorobutadiene 5122/96 1 1 BQL
lsopropylbenzene 5122/96 1 1 BQL
I p-lsopropyltoluene 5/22/96 1 1 BQL
Methyl-tert butyl ether (MTBE) 5122/96 1 1 BQL
Methylene Chloride 5122/96 1 5 BQL
Naphthalene 5122/96 1 1 BQL I n-Propylbenzene 5122/96 1 1 BQL
I Flags:
BQL = Below Quantitation Limit
Paoe 1 of 2
I PARADIGM ANALYTICAL LABORATORIES, Ii\C.
Results for Volatiles
I by GC 8021
Client Sample ID: EB-01-SS Analyzed By: RNP
ClientProject ID: NC0360.041, GRESHAMS LAKE #29 Date Collected: 05/15/96
I Lab Sample ID: 10314 Date Received: 05/16/96
Lab Project ID: G149-2 Matrix: Water
I Compound Date Quantitation Result
Analyzed Dilution Limit (ug/L) (ug/L)
I Styrene 5/22/96 1 2 BQL
1, 1, 1,2-Tertrachloroethane 5/22/96 1 1 BQL
I 1, 1,2,2-Tertrachloroethane 5/22/96 1 1 BQL
Tetrachloroethene 5/22/96 1 BQL
Toluene 5/22/96 1 BQL
I 1,2,3-Trichlorobenzene 5/22/96 1 1 BQL
1,2,4-Trichlorobenzene 5/22/96 1 1 BQL
1, 1, 1-Trichloroethane 5/22/96 1 1 BQL
1, 1,2-Trichloroethane 5/22/96 1 BQL
I Trichloroethene 5/22/96 1 1 BQL
Trichlorofluromethane 5/22/96 1 1 BQL
1,2,3-Trichloropropane 5/22/96 1 2 BQL
I 1,2,4-Trimethylbenzene 5/22/96 1 1 BQL
1,3,5-Trimethylbenzene 5/22/96 1 2 BQL
Vinyl Chloride 5/22/96 1 1 BQL
I m/p-Xylene 5/22/96 1 2 BQL
a-Xylene 5/22/96 1 2 BQL
I Surrogate Spike Recoveries Spike Spike Percent
I Added Result Recovered
1,4-Dichlorobutane 40 36 90
Trifluorotoluene 40
I
40 100
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I Comments:
All values corrected for dilution.
Reviewed By: /wh,
I
I Flags:
BQL = Below Quanlitation Limit
P~nt'.lo? nf?
I PARADIGM A!\ALYTICAL LABORATORIES. l!\C.
Results for Volatiles
I by GC 8021
Client Sample ID: REP-01-SS Analyzed By: RNP
Client Project ID: NC0360.041, GRESHAMS LAKE #29 Date Collected: 05/15/96
I Lab Sample ID: 10315 Date Received: 05/16/96
Lab Project ID: G149·2 %Solids: 80.1 Matrix: Soil
I Compound Date Quantilation Result
Analyzed Dilution Limit (ug/KG) (ug/KG)
I Benzene 5/29/96 1 1.2 BQL
Bromobenzene 5/29/96 1 2.5 BQL
I E)romochloromethane 5/29/96 1 1.2 BQL
Bromodichloromethane 5/29/96 1 1.2 BQL
Bromoform 5/29/96 1 2.5 BQL
I
Bromomethane 5/29/96 2.5 BQL
n-Butylbenzene 5/29/96 1 1.2 BQL
sec-Butyl benzene 5/29/96 1 1.2 BQL
tert-Butylbenzene 5/29/96 1 1.2 BQL
I Carbon tetrachloride 5/29/96 1 1.2 BQL
Chlorobenzene 5/29/96 1.2 BQL
Chloroethane 5/29/96 1 1.2 BQL
I Chloroform 5/29/96 1 1.2 BQL
Chloromethane 5/29/96 1 1.2 BQL
2-Chlorotoluene 5/29/96 1 1.2 BQL
I 4-Chlorotoluene 5/29/96 1 2.5 BQL
Dibromochloromethane 5/29/96 1 1.2 BQL
1 ,2-Dibromo-3-chloropropane 5/29/96 1 1.2 BQL
I 1 ,2-Dibromoethane (EDS) 5/29/96 1.2 BQL
Dibromomethane 5/29/96 1 1.2 BQL
1,2-Dichlorobenzene 5/29/96 1 1.2 BQL
1,3-Dichlorobenzene 5/29/96 1 1.2 BQL
I 1,4-Dichlorobenzene 5/29/96 1 1.2 BQL
Dichlorodi0uoromethane 5/29/96 1 1.2 BQL
1 , 1-Dichloroethane 5/29/96 1 1.2 BQL
I 1,2-Dichloroethane 5/29/96 1.2 BQL
1, 1-Dichloroethene 5/29/96 1 1.2 BQL
cis-1,2-Dichloroethene 5/29/96 1 1.2 BQL
I trans-1,2-Dichloroethene 5/29/96 1 1.2 BQL
1,2-Dichloropropane 5/29/96 1 1.2 BQL
2,2-Dichloropropane 5/29/96 1 2.5 BQL
I cis-1,3-Dichloropropane 5/29/96 1 1.2 BQL
trans-1,3-Dichloropropane 5/29/96 1 1.2 BQL
Diisopropyl ether (DIPE) 5/29/96 1 1.2 BQL
I Ethylbenzene 5/29/96 1 1.2 BQL
Hexachlorobutadiene 5/29/96 1 1.2 BQL
lsopropylbenzene 5/29/96 1 1.2 BQL
I p-lsopropyltoluene 5/29/96 1 1.2 BQL
Methyl-tert butyl ether (MTBE) 5/29/96 1 1.2 BQL
Methylene Chloride 5/29/96 1 6.2 BQL
Naphthalene 5/29/96 1 1.2 BQL
I I n-Propylbenzene 5/29/96 1 1.2 BQL
I Flags:
BQL = Below Quanlilation Limit
Page 1 of 2
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PARADIGl\1 Ai\ALYTICAL LABORATORIES. I1\C.
Results for Volatiles
by GC 8021
Client Sample ID: REP-01-SS
Client Project ID: NC0360.041, GRESHAM$ LAKE #29
Lab Sample ID: 10315
Lab Project ID: G149-2
Compound
Styrene
1 , 1 , 1 ,2-Tertrachloroethane
1 , 1 ,2,2-Tertrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1, 1, 1-Trichloroethane
1 , 1 ,2-Trichloroethane
Trichloroethene
Trichlorofluromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl Chloride
m/p-Xylene
o-Xylene
Surrogate Spike Recoveries
1,4-Dichlorobutane
Trifluorotoluene
Comments:
%Solids: 80.1
Date
Analyzed
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
Dilution
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
Spike
Added
40
40
All values corrected for dilution and %solids.
Flags:
SOL = Below Ouantitation Limit
Analyzed By: RNP
Date Collected: 05/15/96
Date Received: 05/16/96
Matrix: Soil
Quantitation
Limit ( ug/K G)
2.5
1.2
1.2
1.2
1.2
1.2
1.2
1.2
1.2
1.2
1.2
2.5
1.2
2.5
1.2
2.5
2.5
Spike
Result
36
40
Result
(ug/KG)
SOL
SOL
SOL
SOL
SOL
SOL
SOL
SOL
SOL
SOL
SOL
SOL
SOL
SOL
SOL
SOL
SOL
Percent
Recovered
90
100
Reviewed By: fw>::::::
Page 2 of 2
I PARADIGM A!\ALYTICAL LABORATORIES, l'\C.
Results for Volatiles
I
by GC 8021
Client Sample ID: TB-01-(5/15/96) Analyzed By: RNP
Client Project ID: NC0360.041, GRESHAMS LAKE #29 Date Collected: 05/15/96
I Lab Sample ID: 10316 Date Received: 05/16/96
Lab Project ID: G149-2 Matrix: Water
I Compound Date Quantitation Result
Analyzed Dilution Limit (ug/L) (ug/L)
I Benzene 5/22/96 1 1 BQL
Bromobenzene 5/22/96 1 2 BQL
I Bromochloromethane 5/22/96 1 1 BQL
Bromodichloromethane 5/22/96 1 BQL
Bromoform 5/22/96 2 BQL
Bromomethane 5/22/96 2 BQL
I n-Butylbenzene 5/22/96 1 BQL
sec-Butylbenzene 5/22/96 1 1 BQL
tert-Butylbenzene 5/22/96 1 1 BQL
I Carbon tetrachloride 5/22/96 1 1 BQL
Chlorobenzene 5/22/96 1 1 BQL
Chloroethane 5122/96 1 BQL
I Chloroform 5/22/96 1 BQL
Chloromethane 5/22/96 1 1 BQL
2-Chlorotoluene 5/22/96 1 1 BQL
I 4-Chlorotoluene 5/22/96 1 2 BQL
Dibromochloromethane 5/22/96 1 1 BQL
1,2-Dibromo-3-chloropropane 5/22/96 1 BQL
I 1,2-Dibmmoethane (EDB) 5/22/96 1 BQL
Dibromomethane 5/22/96 1 BQL
1,2-Dichlorobenzene 5/22/96 1 1 BQL
1,3-Dichlorobenzene 5/22/96 1 1 BQL
I 1,4-Dichlorobenzene 5/22/96 1 1 BQL
DichlorodiHuoromethane 5/22/96 1 1 BQL
1, 1-Dichloroethane 5/22/96 1 1 BQL
I 1,2-Dichloroethane 5/22/96 1 1 BQL
1, 1-Dichloroethene 5/22/96 1 1 BQL
cis-1,2-Dichloroethene 5/22/96 1 1 BOL
I trans-1,2-Dichloroethene 5/22/96 1 1 BQL
1,2-Dichloropropane 5/22/96 1 1 BQL
2,2-Dichloropropane 5/22/96 1 2 BQL
I cis-1,3-Dichloropropane 5/22/96 1 1 BQL
trans-1,3-Dichloropropane 5/22/96 1 1 BQL
Diisopropyl ether (DIPE) 5/22/96 1 1 BQL
I Ethylbenzene 5/22/96 1 1 BQL
Hexachlorobutadiene 5/22/96 1 1 BQL
lsopropylbenzene 5122/96 1 1 BQL
p-lsopropyltoluene 5/22/96 1 1 BQL I Methyl-tert butyl ether (MTBE) 5/22/96 1 BQL
Methylene Chloride 5/22/96 1 5 BQL
Naphthalene . 5/22/96 1 1 BQL
I n-Propylbenzene 5/22/96 1 1 BQL
I Flags:
BQL = Below Quantitation Limit
Page 1 of 2
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PARADIG1-1 Ai\ALYTICAL LABORATORIES. li\C.
Results for Volatiles
by GC 8021
Client Sample ID: TB-01-(5/15/96)
Client Project ID: NC0360.041, GRESHAMS LAKE #29
Lab Sample ID: 10316
Lab Project ID:. G149-2
Compound
Styrene
1, 1, 1,2-Tertrachloroethane
1, 1,2,2-Tertrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1 , 1, 1-Trichloroethane
1 , 1,2-Trichloroethane
Trichloroethene
Trichlorofluromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl Chloride
m/p-Xylene
o-Xylene
Surrogate Spike Recoveries
1,4-Dichlorobutane
Trifluorotoluene
Comments:
All values corrected for dilution.
Flags:
BQL = Below Quantitation Limit
Date
Analyzed
5/22/96
5/22/96 ·
5/22/96
5/22/96
5/22/96
5/22/96
5/22/96
5/22/96
5/22/96
5/22/96
5/22/96
5/22/96
5/22/96
5/22/96
5/22/96
5/22/96
5/22/96
Dilution
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
Spike
Added
40
40
Analyzed By: RNP
Date Collected: 05/15/96
Date Received: 05/16/96
Matrix: Water
Quantitation
Limit (ug/L)
2
1
1
1
1
1
1
1
1
1
1
2
1
2
1
2
2
Spike
Result
36
41
Result
(ug/L)
BQL
BQL
BQL
BOL
BQL
BOL
BQL
BQL
BQL
BOL
BQL
BQL
BQL
BOL
BOL
BQL
BOL
Percent
Recovered
90
102
Reviewed By: l'1/?:-::
Page 2 of 2
I PARADIGM ANALYTICAL LABORATORIES, l:\C.
Results for Volatiles
I by GC 8021
Client Sample ID: SS-5-4 Analyzed By: RNP
Client Project ID: Greshams Lake #29 Date Collected: 05/17/96
I Lab Sample ID: 10386 Date Recefved: 05/18/96
Lab Project ID: G149-4 %Solids: 94. 7 Matrix: Soil
I Compound Date Quantitation Result
Analyzed Dilution Limit (ug/KG) (ug/KG)
I Benzene 5/29/96 . 1 1 BQL
Bromobenzene 5/29/96 1 2.1 BQL
Bromochloromethane 5/29/96 1 BQL I Bromodichloromethane 5/29/96 1 1 BQL
Bromoform 5/29/96 1 2.1 BOl..
Bromomethane 5/29/96 1 2.1 BQL
I n-Butylbenzene 5/29/96 1 1 BQL
sec-Butylbenzene 5/29/96 1 1 BQL
tert-Butylbenzene 5/29/96 1 1 BQL
I Carbon tetrachloride 5/29/96 1 1 BQL
Chlorobenzene 5/29/96 1 1 BOL
Chloroethane 5/29/96 1 1 BQL
I Chloroform 5/29/96 1 1 BOL
Chloromethane 5129/96 1 BOL
2-Chlorotoluene 5/29/96 1 1 BQL
I 4-Chlorotoluene 5129/96 1 2.1 BQL
Dibromochloromethane 5/29/96 1 1 BQL
1,2-Dibromo-3-chloropropane 5129/96 1 1 BQL
I 1,2-Dibromoethane (EDB) 5129/96 1 1 BQL
Dibromomethane 5/29/96 1 1 BQL
1,2-Dichlorobenzene 5/29/96 1 1 BQL
1,3-Dichlorobenzene 5129/96 1 1 BQL I 1,4-Dichlorobenzene 5/29/96 1 1 BQL
Dichlorodifluoromethane 5/29/96 1 1 BQL
1 , 1-Dichloroethane 5/29/96 1 1 BOL
I 1,2-Dichloroethane 5129/96 1 1 BQL
1 , 1-Dichloroethene 5129/96 1 1 BOL
cis-1 ,2-Dichloroethene 5/29/96 1 1 BQL
I trans-1,2-Dichloroethene 5/29/96 1 1 BQL
1,2-Dichloropropane 5/29/96 1 1 BQL
2,2-Dichloropropane 5/29/96 1 2.1 BQL
I cis-1,3-Dichloropropane 5/29/96 1 1 BQL
trans-1,3-Dichloropropane 5129/96 1 1 BQL
Diisopropyl ether (DIPE) 5/29/96 1 1 BQL
I Ethylbenzene 5129/96 1 1 BQL
Hexachlorobutadiene 5129/96 1 1 BQL
lsopropylbenzene 5129/96 1 1 BQL
p-lsopropyltoluene 5129/96 1 1 BQL
I Methyl-tert butyl ether (MTBE) 5129/96 1 1 BQL
Methylene Chloride 5129/96 1 5.3 BQL
Naphthalene 5129/96 1 1 BQL
I n-Propylbenzene 5129/96 1 1 BQL
I Flags:
BQL = Below Quantitation Limit
Page 1 of 2
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PARADIGM ANAL\TICAL LABORATORIES. Ii\C.
Client Sample ID: SS-5-4
Results for Volatiles
by GC 8021
Client Project ID: Greshams Lake #29
Lab Sample ID: 10386
Lab Project ID: G149-4 %Solids: 94.7
Compound
Styrene
1, 1, 1,2-Tertrachloroethane
1, 1,2,2-Tertrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1, 1, 1-Trichloroethane
1, 1,2-Trichloroethane
Trichloroethene
Trichlorofluromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl Chloride
m/p-Xylene
o-Xylene
Surrogate Spike Recoveries
1,4-Dichlorobutane
Trifluorotoluene
Date
Analyzed
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
· 5/29/96
Dilution
1
1
1
1
1
1
1
1
1
1
1
1
1
1
Spike
Added
40
40
Comments:
All values corrected for dilution and %solids.
Flags:
BQL = Below Quantitation Limit
Analyzed By: RNP
Date Collected: 05/17/96
Date Received: 05/18/96
Matrix: Soil
Quantitation
Limit (ug/KG)
2.1
1
1
1
1
1
1
1
1
1
1
2.1
1
2.1
1
2.1
2.1
Spike
Result
38
40
Result
(ug/KG)
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BOL
Percent
Recovered
95
100
Reviewed By: f\w:\,
Page 2 of 2
I PARADIGM ANAUTICAL LABORATORIES. Ii'C.
Results for Volatiles
I
by GC 8021
Client Sample ID: SS-5-10 Analyzed By: RNP
Client Project ID: Greshams Lake #29 Date Collected: 05/17 /96
I Lab Sample ID: 10387 Date Received: 05/18/96
Lab Project ID:. G149-4 %Solids: 77.8 Matrix: Soil
-
D Compound Date Quantitation Result
Analyzed Dilution Limit (ug/KG) (ug/KG)
I Benzene 05/29/96 1 1.3 BQL
Bromobenzene 05/29/96. 1 2.6 BQL
I Bromochloromethane 05/29/96 1.3 BQL
Bromodichloromethane 05/29/96 1 1.3 BQL
Bromoform 05/29/96 1 2.6 BQL
Bromomethane 05/29/96 1 2.6 BQL I h-Butylbenzene 05/29/96 1 1.3 BQL
sec-Butylbenzene 05/29/96 1 1.3 BQL
tert-Butylbenzene 05/29/96 1 1.3 BQL
I Carbon tetrachloride 05/29/96 1 1.3 BQL
Chlorobenzene 05/29/96 1 1.3 BQL
Chloroethane 05/29/96 1 1.3 BQL
I Chloroform 05/29/96 1 1.3 BQL
Chloromethane 05/29/96 1 1.3 BQL
2-Chlorotoluene 05/29/96 1 1.3 BQL
I 4-Chlorotoluene 05/29/96 1 2.6 BQL
Dibromochloromethane 05/29/96 1 1.3 BQL
1,2-Dibromo-3-chloropropane 05/29/96 1 1.3 BQL
I 1,2-Dibromoethane (EDB) 05/29/96 1 1.3 BQL
Dibromomethane 05/29/96 1 1.3 BQL
1,2-Dichlorobenzene 05/29/96 1 1.3 BQL
1,3-Dichlorobenzene 05/29/96 1 1.3 BQL I 1,4-Dichlorobenzene 05/29/96 1 1.3 BQL
Dichlorodifluoromethane 05/29/96 1 1.3 BQL
1 , 1-Dichloroethane 05/29/96 1 1.3 BQL
I 1,2-Dichloroethane 05/29/96 1 1.3 BQL
1, 1-Dichloroethene 05/29/96 1 1.3 BQL
cis-1,2-Dichloroethene 05/29/96 1 1.3 BQL
I trans-1 ,2-Dichloroethene 05/29/96 1 .1.3 BQL
1,2-Dichloropropane 05/29/96 1 1.3 BQL
2,2-Dichloropropane 05/29/96 1 2.6 BQL
I cis-1,3-Dichloropropane 05/29/96 1 1.3 BQL
trans-1,3-Dichloropropane 05/29/96 1 1.3 BOL
Diisopropyl ether (DIPE) 05/29/96 1 1.3 BQL
I Ethylbenzene 05/29/96 1 1.3 BQL
Hexachlorobutadiene 05/29/96 1 1.3 BQL
lsopropylbenzene 05/29/96 1 1.3 BQL
I p-lsopropyltoluene 05/29/96 1 1.3 BQL
Methyl-tert butyl ether (MTBE) 05/29/96 1 1.3 BQL
Methylene Chloride 05/29/96 1 6.4 BQL
Naphthalene 05/29/96 1 1.3 BQL
I n-Propylbenzene 05/29/96 1 1.3 BQL
I Flags:
BQL = Below Quantitation Limit
Pa~e 1 of 2
0
0
a
u
D
n
a
u
B
u
u
u
E
E
PARADIGM A:\AL\TICAL LABORATORIES. l'\C.
Client Sample ID: SS-5-10
Results for Volatiles
by GC 8021
Client Project ID: Greshams Lake #29
Lab Sample ID: 10387
Lab Project ID: G149-4
Compound
Styrene
1, 1, 1,2-Tertrachloroethane
1 , 1,2,2-Tertrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1, 1, 1-Trichloroethane
1, 1,2-Trichloroethane
Trichloroethene
Trichlorofluromethane
1.2,3-Trichloropropane
1.2.4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl Chloride
m/p-Xylene
a-Xylene
Surrogate Spike Recoveries
1,4-Dichlorobutane
Trifluorotoluene
Comments:
%Solids: 77.8
Date
Analyzed
05/29/96
05/29/96
05/29/96
05/29/96
05/29/96
05/29/96
05/29/96
05/29/96
05/29/96
05/29/96
05/29/96
05/29/96
05/29/96
05/29/96
05/29/96
05/29/96
05/29/96
Dilution
1
1
1
1
1
1
1
1
1
1
1
1
1
1
Spike
Added
40
40
All values corrected for dilution and %solids.
Flags:
BQL = Below Quanlitation Limit
Analyzed By: RNP
Date Collected: 05/17/96
Date Received: 05/18/96
Matrix: Soil
Quantitation
Limit (ug/KG)
2.6
1.3
1.3
1.3
1.3
1.3
1.3
1.3
1.3
1.3
1.3
2.6
1.3
2.6
1.3
2.6
2.6
Spike
Result
37
40
Result
(ug/KG)
BQL
BQL
BQL
BQL
BQL
BQL
BQL
1.9
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
Percent
Recovered
92
100
Reviewed By: l\l,'h,.
PHoe 2 of 2
I PARADIGM ANALYTICAL LABORATORIES. INC.
Results for Volatiles
I Client Sample ID: SS-6-4
by GC 8021
Analyzed By: RNP
Client Project ID: Greshams Lake #29 Date Collected: 05/17 /96
I Lab Sample ID: 10388 Date Received: 05/18/96
Lab Project ID: G149-4 %Solids: 92.8 Matrix: Soil
I Compound Date Quantitation Result
Analyzed Dilution Limit (ug/KG) (ug/KG)
I Benzene 05/29/96 1 1 .1 BQL
Bromobenzene 05/29/96 1 2.2 BQL
I Bromochloromethane 05/29/96 1 1.1 BQL
Bromodichloromethane 05/29/96 1 1.1 BQL
Bromoform 05/29/96 1 2.2 BQL
Bromomethane 05/29/96 2.2 BQL
I n-Butylbenzene 05/29/96 1 1.1 BQL
sec-Butylbenzene 05/29/96 1 1.1 BQL
tert-Butylbenzene 05/29/96 1.1 BQL
I Carbon tetrachloride 05/29/96 1 1.1 BQL
Chlorobenzene 05/29/96 1 1.1 BQL
Chloroethane 05/29/96 1 1.1 BQL
I Chloroform 05/29/96 1 1.1 BQL
Chloromethane 05/29/96 1 1.1 BQL
2-Chlorotoluene 05/29/96 1 1.1 BQL
I 4-Chlorotoluene 05/29/96 1 2.2 BQL
Dibromochloromethane 05/29/96 1 1.1 BQL
1,2-Dibromo-3-chloropropane 05/29/96 1 1.1 BQL
I 1,2-Dibromoethane (EDB) 05/29/96 1 1.1 BQL
Dibromomethane 05/29/96 1 1.1 BQL
1,2-Dichlorobenzene 05/29/96 1 1.1 BQL
1,3-Dichlorobenzene 05/29/96 1 1.1 BQL
I 1,4-Dichlorobenzene 05/29/96 1 1.1 BQL
DichlorodiOuoromethane 05/29/96 1 1.1 BQL
1, 1-Dichloroethane 05/29/96 1.1 BQL
I 1,2-Dichloroethane 05/29/96 1 1.1 BQL
1, 1-Dichloroethene 05/29/96 1 1.1 BQL
cis-1,2-Dichloroethene 05/29/96 1.1 BQL
I trans-1,2-Dichloroethene 05/29/96 1 1.1 BQL
1 ,2-Dichloropropane 05/29/96 1 1.1 BQL
2,2-Dichloropropane 05/29/96 1 2.2 BQL
I cis-1,3-Dichloropropane 05/29/96 1 1.1 BQL
trans-1,3-Dichloropropane 05/29/96 1 1.1 BQL
Diisopropyl ether (DIPE) 05/29/96 1 1.1 BQL
I Ethylbenzene 05/29/96 1 1.1 BQL
Hexachlorobutadiene 05/29/96 1 1.1 BQL
lsopropylbenzene 05/29/96 1 1.1 BQL
p-lsopropyltoluene 05/29/96 1 1.1 BQL
I Methyl-tert butyl ether (MTBE) 05/29/96 1.1 BQL
Methylene Chloride 05/29/96 1 5.4 BQL
Naphthalene 05/29/96 1 1.1 BQL
I n-Propylbenzene 05/29/96 1 1.1 BQL
I Flags:
BQL = Below Quantitation Limit
Page 1 of 2
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PARADIGM ANALYTICAL LABORATORIES, INC.
Client Sample ID: SS-6-4
Results for Volatiles
by GC 8021
Client Project ID: Greshams Lake #29
Lab Sample ID: 10388
Lab Project ID: G149-4 %Solids: 92.8
Compound
Styrene
1, 1, 1,2-Tertrachloroethane
1, 1,2,2-Tertrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1, 1, 1-Trichloroethane
1, 1,2-Trichloroethane
Trichloroethene
Trichlorofluromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl Chloride
m/p-Xylene
o-Xylene
Surrogate Spike Recoveries
1,4-Dichlorobutane
Trifluorotoluene
Date
Analyzed
05/29/96
05/29/96
05/29/96
05/29/96
05/29/96
05/29/96
05/29/96
05/29/96
05/29/96
05/29/96
05/29/96
05/29/96
05/29/96
05/29/96
05/29/96
05/29/96
05/29/96
Dilution
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
Spike
Added
40
40
Comments:
All values corrected for dilution and %solids.
Flags:
BQL = Below Quantitation Limit
Analyzed By: RNP
Date Collected: 05/17/96
Date Received: 05/18/96
Matrix: Soil
Quantitation
Limit (ug/KG)
2.2
1.1
1.1
1.1
1.1
1.1
1.1
1.1
1.1
1.1
1.1
2.2
1.1
2.2
1.1
2.2
2.2
Spike
Result
36
40
Result
(ug/KG)
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BOL
BQL
BQL
BQL
BQL
BQL
BQL
BOL
Percent
Recovered
90
100
Reviewed By: ~
Page 2 of 2
I PARADIGM ANALYTICAL LABORATORIES. INC.
Results for Volatiles
I
by GC 8021
Client Sample ID: TB-02 5/17/96 Analyzed By: RNP
Client Project JD: Gresh ams .Lake #29 Date Collected: 05/17/96
I Lab Sample ID: 10391 Date Received: 05/18/96
Lab Project ID: G149-4 Matrix: Water
I Compound Date Quantitation Result
Analyzed Dilution Limit (ug/L) (ug/L)
I Benzene 5/30/96 1 BQL
Bromobenzene 5/30/96 2 BQL
Bromochloromethane 5/30/96 1 BQL
I Bromodichloromethane 5/30/96 1 1 BQL
Bromoform 5/30/96 1 2 BQL
Bromomethane 5/30/96 2 BQL
I n-Butylbenzene 5/30/96 1 1 BQL
sec-Butylbenzene 5/30/96 1 1 BQL
tert-Butylbenzene 5/30/96 1 1 BQL
I Carbon tetrachloride 5/30/96 1 1 BQL
Chlorobenzene 5/30/96 1 1 BQL
Chloroethane 5/30/96 1 1 BQL
I Chloroform 5/30/96 1 1 BQL
Chloromethane 5/30/96 1 1 BQL
2-Chlorotoluene 5/30/96 1 1 BQL
I 4-Chlorotoluene 5/30/96 1 2 BQL
Dibromochloromethane 5/30/96 1 1 BQL
1,2-Dibromo-3-chloropropane 5/30/96 1 1 BQL
1 ,2-Dibromoethane (EDS) 5/30/96 1 1 BQL I Dibromomethane 5/30/96 1 1 BQL
1,2-Dichlorobenzene 5/30/96 1 1 BQL
1,3-Dichlorobenzene 5/30/96 1 1 BQL
~ 1 ,4-Dichlorobenzene 5/30/96 1 1 BQL
Dichlorodifluoromethane 5/30/96 1 1 BQL
1, 1-Dichloroethane 5/30/96 1 1 BQL g 1,2-Dichloroethane 5/30/96 1 1 BQL
1, 1-Dichloroethene 5/30/96 1 1 BQL
cis-1,2-Dichloroethene 5/30/96 1 1 BQL
I trans-1,2-Dichloroethene 5/30/96 1 1 BQL
1,2-Dichloropropane 5/30/96 1 1 BQL
2,2-Dichloropropane 5/30/96 1 2 BQL
0 cis-1,3-Dichloropropane 5/30/96 1 1 BQL
trans-1,3-Dichloropropane 5/30/96 1 1 BQL
Diisopropyl ether (DIPE) 5/30/96 1 1 BQL
a Ethylbenzene 5/30/96 1 1 BQL
Hexachlorobutadiene 5/30/96 1 1 BQL
lsopropylbenzene 5/30/96 1 1 BQL
p-Jsopropyltoluene 5/30/96 1 1 BQL 0 Methyl-tert butyl ether (MTBE) 5/30/96 1 1 BQL
Methylene Chloride 5/30/96 1 5 BQL
Naphthalene 5/30/96 1 1 BQL
I n-Propylbenzene 5/30/96 1 1 BQL
8 Flags:
BQL = Below Quantitation Limit
Page 1 of 2
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PARADIGM ANALYTICAL LABORATORIES. I\'C.
Results for Volatiles
by GC 8021
Client Sample ID: TB-02 5/17/96
Client Project ID: Greshams Lake #29
Lab Sample ID: 10391
Lab Project .ID: G 149-4
Compound
Styrene
1, 1, 1,2-Tertrachloroethane
1, 1,2,2-Tertrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1, 1, 1-Trichloroethane
1, 1,2-Trichloroethane
Trichloroethene
Trichlorofluromethane
1,2,3-Trichloropropane
1,2.4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl Chloride
m/p-Xylene
a-Xylene
Surrogate Spike Recoveries
1,4-Dichlorobutane
Trifluorotoluene
Date
Analyzed
5/30/96
5/30/96
5/30/96
5/30/96
5/30/96
5/30/96
5/30/96
5/30/96
5/30/96
5/30/96
5/30/96
5/30/96
5/30/96
5/30/96
5/30/96
5/30/96
5/30/96
Comments:
All values corrected for dilution.
Flags:
BQL = Below Quantitation Limit
Dilution
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
Spike
Added
40
40
Analyzed By: RNP
Date Collected: 05/17/96
Date Received: 05/18/96
Matrix: Water
Quantitation
Limit (ug/L)
2
1
1
1
1
1
1
1
1
1
1
2
1
2
1
2
2
Spike
Result
39
40
Result
(ug/L)
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BOL
BQL
Percent
Recovered
98
100
Reviewed By: IN'::::
Page 2 of 2
I PARADIGM ANALYTICAL LABORATORIES, INC.
I Results for Volatiles
by GC 8021
Client Sample ID: VBLK052196 Analyzed By: RNP
I Client Project ID: NC0360.041, GRESHAMS LAKE #29 Date Collected: Not applicable
Lab Sample ID: None Assigned Date Received: Not applicable
Lab Project ID: ~149-2 Matrix: Water
I
Compound Date Quantitation Result
~ Analyzed Dilution Limit (ug/L) (ug/L)
Benzene 5/21/96 1 1.0 BQL
I Bromobenzene 5/21/96 1 2.0 BQL
Bromochloromethane -5/21/96 1 1.0 BQL
Bromodichloromethane 5/21/96 1 1.0 BQL
I
Bromoform 5/21/96 1 2.0 BQL
Bromomethane 5/21/96 1 2.0 BQL
n-Butylbenzene 5/21/96 1 1.0 BQL
sec-Butylbenzene 5/21/96 1 1.0 BQL I tert-Butylbenzene 5/21/96 1 1.0 BQL
Carbon tetrachloride 5/21/96 1 1.0 BQL
Chlorobenzene 5/21/96 1 1.0 BQL u Chloroethane 5/21/96 1 1.0 BQL
Chloroform 5/21/96 1 1.0 BQL
Chloromethane 5/21/96 1 1.0 BQL
I 2-Chlorotoluene 5/21/96 1 1.0 BQL
4-Chlorotoluene 5/21/96 1 2.0 BQL
Dibromochloromethane 5/21/96 1 1.0 BQL
I 1 ,2-Dibromo-l-chloropropane 5/21/96 1 1.0 BQL
1,2-Dibromoethane (EDS) 5/21/96 1 1.0 BQL
Dibromomethane 5/21/96 1 1.0 BQL
I 1,2-Dichlorobenzene 5/21/96 1 1.0 SOL
1,3-Dichlorobenzene 5/21/96 1 1.0 BQL
1 .4-Dichlorobenzene 5/21/96 1 1.0 SOL
n Dichlorodifluoromethane 5/21/96 1 1.0 BQL
1, 1-Dichloroethane 5/21/96 1 1.0 BQL
1,2-Dichloroethane 5/21/96 1 1.0 BQL
1, 1-Dichloroethene 5/21/96 1 1.0 BQL ~ cis-1,2-Dichloroethene 5/21/96 1 1.0 BQL
trans-1 ,2-Dichloroethene 5/21/96 1 1.0 BQL
1 ,2-Dichloropropane 5/21/96 1 1.0 BQL
I 2,2-Dichloropropane 5121/96 1 2.0 BQL
cis-1,3-Dichloropropene 5/21/96 1 1.0 BQL
trans-1,3-Dichloropropene 5/21/96 1 1.0 BQL
I Diisopropyl ether (DIPE) 5/21/96 1 1.0 BQL
Ethylbenzene 5/21/96 1 1.0 BQL
Hexachlorobutadiene 5/21/96 1 1.0 BQL
m lsopropylbenzene 5/21/96 1 1.0 BQL
p-lsopropyltoluene 5/21/96 1 1.0 BQL
Methyl-tert butyl ether (MTBE) 5/21/96 1 1.0 SOL
E Methylene Chloride 5/21/96 1 5.0 BQL
Naphthalene 5/21/96 1 1.0 BQL
n-Propylbenzene 5/21/96 1 1.0 BQL
I Flags:
,...., -,-',, -': -.. ' . __ .,
I
I
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I
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I
m
0
I
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PARADIGM ANAL)'T!CAL LABORATORIES, INC.
Results for Volatiles
by GC 8021
Client Sample ID: VBLK052196
Client Project ID: NC0360.041, GRESHAMS LAKE #29
Lab Sample ID: None Assigned
Lab Project ID: G149-2
Compound
Styrene
1, 1, 1 ,2-Tertrachloroethane
1, 1,2,2-Tertrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1, 1, 1-Trichloroethane
1, 1,2-Trichloroethane
Trichloroethene
Trichlorofluromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl Chloride
m/p-Xylene
a-Xylene
Surrogate Spike Recoveries
1,4-Dichlorobutane
Trifluorotoluene
Date
Analyzed
5/21/96
5/21/96
5/21/96
5/21/96
5/21/96
5/21/96
5/21/96
5/21/96
5/21/96
5/21/96
5/21/96
5/21/96
5/21/96
5/21/96
5/21/96
5/21/96
5/21/96
Dilution
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
Spike
Added
40
40
Comments:
Flags:
All values corrected for dilution.
Associated sample: 10314 and 10316.
Analyzed By: RNP
Date Collected: Not applicable
Date Received: Not applicable
Matrix: Water
Quantitation
Limit (ug/L)
2.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
2.0
1.0
2.0
1.0
2.0
2.0
Spike
Result
36
40
Result
(ug/L)
BQL
BQL
SOL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
Percent
Recovered
90
100
Reviewed By: f'Mv
I PARADIGM ANALYTICAL LABORATORIES. l'\C.
Results for Volatiles
I
by GC 8021
Client Sample ID: VBLK052996 Analyzed By: RNP
Client Project ID: NC0360.041, Site No. 29 Date Collected: Not applicable
I Lab Sample ID: None assigned Date Received: Not applicable
Lab Project ID: G149-2 %Solids: 100.0 Matrix: Soil' ·
I Compound Date Quantitation Result
Analyzed Dilution Limit (ug/KG) (ug/KG)
I Benzene 5/29/96 1 1 BQL
Bromobenzene 5/29/96 1 2 BQL
0 Bromochloromethane 5/29/96 1 1 BOL
Bromodichloromethane 5/29/96 1 1 BOL
Bromofonm 5129/96 1 2 BOL
Bromomethane 5/29/96 1 2 BQL
I n-Butylbenzene 5/29/96 1 1 BQL
sec-Butylbenzene 5/29/96 1 1 BQL
tert-Butylbenzene 5/29/96 1 1 BQL
I Carbon tetrachloride 5/29/96 1 1 SOL
Chlorobenzene 5/29/96 1 1 BQL
Chloroethane 5/29/96 1 1 BQL
I Chlorofonm 5/29/96 1 1 BQL
Chloromethane 5129/96 1 1 BQL
2-Chlorotoluene 5/29/96 1 1 BQL
I 4-Chlorotoluene 5/29/96 1 2 BQL
Dibromochloromethane 5129/96 1 1 BQL
1,2-Dibromo-3-chloropropane 5/29/96 1 1 BQL
I 1,2-Dibromoethane (EDS) 5/29/96 1 BQL
Dibromomethane 5/29/96 1 1 BQL
1,2-Dichlorobenzene 5/29/96 1 1 BQL
I 1,3-Dichlorobenzene 5/29/96 1 1 BQL
1,4-Dichlorobenzene 5/29/96 1 1 BQL
Dichlorodifluoromethane 5/29/96 1 1 BQL
1, 1-Dichloroethane 5/29/96 1 1 BQL
I 1,2-Dichloroethane 5/29/96 1 1 BQL
1, 1-Dichloroethene 5/29/96 1 1 BQL
cis-1 ,2-Dichloroethene 5129/96 1 1 BQL
I trans-1,2-Dichloroethene 5/29/96 1 1 BQL
1,2-Dichloropropane 5/29/96 1 1 BQL
2,2-Dichloropropane 5/29/96 1 2 BQL
I cis-1,3-Dichloropropane 5/29/96 1 1 BQL
trans-1,3-Dichloropropane 5/29/96 1 1 BQL
Diisopropyl ether (DIPE) 5129/96 1 1 BQL
I Ethylbenzene 5/29/96 1 1 BQL
Hexachlorobutadiene 5/29/96 1 1 BQL
lsopropylbenzene 5129/96 1 1 BQL
I p-lsopropyltoluene 5/29/96 1 1 BQL
Methyl-tert butyl ether (MTBE) 5129/96 1 1 BQL
Methylene Chloride 5/29/96 1 5 BQL
Naphthalene 5129/96 1 1 BQL
I n-Propylbenzene 5/29/96 1 1 BQL
I Flags:
BQL = Below Quantitation Limit
O~r,c 1 nf ')
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PARADIGM ANALYTICAL LABORATORIES, INC.
Results for Volatiles
byGC 8021
Client Sample ID: VBLK052996
Client Project ID: NC0360.041, Stte No. 29
Lab Sample ID: None assigned
Lab Project ID: G149-2 %Solids: 100.0
Compound
Styrene
1, 1, 1,2-Tertrachloroethane
1, 1,2,2-Tertrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1, 1, 1-Trichloroethane
1, 1,2-Trichloroethane
Trichloroethene
Trichlorofluromethane
1,2,3-Trichloropropane
1,2.4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl Chloride
m/p-Xylene
o-Xylene
Surrogate Spike Recoveries
1,4-Dichlorobutane
Trifluorotoluene
Date
Analyzed
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
Dilution
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
Spike
Added
40
40
Comments:
All values corrected for dilution and %solids.
Flags:
SOL = Below Ouantitation Limit
Analyzed By: RNP
Date Collected: Not applicable
Date Received: Not applicable
Matrix: Soil
Quantitation
Limit (ug/KG)
2
1
1
1
1
1
1
1 ·
1
1
1
2
1
2
1
2
2
Spike
Result
36
40
Result
(ug/KG)
SOL
SOL
SOL
SOL
BOia
BOL
SOL
SOL
SOL
SOL
SOL
BOL
SOL
BOL
SOL
SOL
BOL
Percent
Recovered
90
100
Reviewed By: /I.lib,
I PARADIGM ANALYTICAL LABORATORIES, INC.
Results for Volatiles
I by GC 8021
Client Sample ID: VBLK060496 Analyzed By: RNP
Client Project ID: Greshams Lake #29 Date Collected: Not applicable
I Lab Sample ID: None assigned Date Received: Not applicable
Lab Project ID: G149-4 %Solids: 100.0 Matrix: Soil
I Compound Date Quantitation Result
Analyzed Dilution Limit (ug/KG) (ug/KG)
I Benzene 5/29/96 1 1 SOL
Bromobenzene 5/29/96 1 2 SOL
I Bromochloromethane 5/29/96 1 1 SOL
Bromodichloromethane 5/29/96 1 1 SOL
Bromoform 5/29/96 1 2 SOL
I Bromomethane 5/29/96 2 SOL
n-Butylbenzene 5/29/96 1 SOL
sec-Butyl benzene 5/29/96 1 SOL
tert-Butylbenzene 5/29/96 1 1 SOL
I Carbon tetrachloride 5/29/96 1 1 SOL
Chlorobenzene 5/29/96 1 1 SOL
Chloroethane 5/29/96 1 1 SOL
I Chloroform 5/29/96 1 1 SOL
Chloromethane 5/29/96 1 1 SOL
2-Chlorotoluene 5/29/96 1 1 SOL
I 4-Chlorotoluene 5/29/96 1 2 SOL
Dibromochloromethane 5/29/96 1 1 SOL
1,2-Dibromo-3-chloropropane 5/29/96 1 1 SOL
I 1,2-Dibromoethane (EDS) 5/29/96 1 1 SOL
Dibromomethane 5/29/96 1 1 SOL
1,2-Dichlorobenzene 5/29/96 1 1 SOL
I 1,3-Dichlorobenzene 5/29/96 1 1 SOL
1 ,4-Dichlorobenzene 5/29/96 1 1 SOL
Dichlorodifluoromethane 5/29/96 1 1 SOL
1, 1 '.Dichloroethane 5/29/96 1 1 SOL
I 1,2-Dichloroethane 5/29/96 1 1 SOL
1, 1-Dichloroethene 5/29/96 1 1 SOL
cis-1,2-Dichloroethene 5/29/96 1 1 SOL
I trans-1,2-Dichloroethene 5/29/96 1 1 SOL
1,2-Dichloropropane 5/29/96 1 SOL
2,2-Dichloropropane 5/29/96 1 2 SOL
I cis-1,3-Dichloropropane 5/29/96 1 1 SOL
trans-1,3-Dichloropropane 5/29/96 1 1 SOL
Diisopropyl ether (DIPE) 5/29/96 1 1 SOL
I Ethylbenzene 5/29/96 1 1 SOL
Hexachlorobutadiene 5/29/96 1 1 SOL
lsopropylbenzene 5/29/96 1 1 SOL
I p-lsopropyltoluene 5/29/96 1 1 SOL
Methyl-tert butyl ether (MTBE) 5/29/96 1 1 SOL
Methylene Chloride 5/29/96 1 5 SOL
Naphthalene 5/29/96 1 1 SOL
I n-Propylbenzene 5/29/96 1 1 SOL
I Flags:
SOL = Below Ouanlitalion Limit
Pane 1 of 2
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PARADIGM ANAL\TICAL LABORATORIES. INC.
Results for Volatiles
by GC 8021
Client Sample ID: VBLK060496
Client Project ID: Greshams Lake #29
Lab Sample ID: None assigned
Lab Project ID: -G149-4 %Solids: 100.0
Compound
Styrene
1, 1, 1,2-Tertrachloroethane
1, 1,2,2-Tertrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1, 1, 1-Trichloroethane
1, 1,2-Trichloroethane
Trichloroethene
Trichlorofluromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl Chloride
m/p-Xylene
o-Xylene
Surrogate Spike Recoveries
1.4-Dichlorobutane
Trifluorotoluene
Date
Analyzed
5/29/96
5/29/96 ·
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
5/29/96
Dilution
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
Spike
Added
40
40
Comments: ·
All values corrected for dilution and %solids.
Flags:
BQL = Below Quantitation Limit
Analyzed By: RNP
Date Collected: Not applicable
Date Received: Not applicable
Matrix: Soil
Quantitation
Limit (ug/KG)
2
1
1
1
1
1
1
1
1
2
1
2
1
2
2
Spike
Result
35
41
Result
(ug/KG)
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
Percent
Recovered
87
102
Reviewed By: lw'h.,.
P::,no ? nf ')
I PARADIGM ANALYTICAL LABORATORIES. I:\ C.
Results for Volatiles
I
by GC 8021
Client Sample ID: VBLK061096 Analyzed By: RNP
I
Client Project ID: Greshams Lake #29 Date Collected: Not applicable
Lab Sample ID: None assigned Date Received: Not applicable
Lab Project ID: G149-4 %Solids: 100.0 Matrix: Soil
I Compound Date Quantitation Result
Analyzed Dilution Limit (ug/KG) (ug/KG)
I Benzene 06/10/96 1 BQL
Bromobenzene 06/10/96 1 2 BQL
I Bromochloromethane 06/10/96 1 1 BQL
Bromodichloromethane 06/10/96 1 1 BOL
Bromoform 06/10/96 1 2 BQL ·
I Bromomethane 06/10/96 1 2 BOL
n-Butylbenzene 06/10/96 1 1 BQL
sec-Butylbenzene 06/10/96 1 1 BOL
I tert-Butylbenzene 06/10/96 1 1 BOL
Carbon tetrachloride 06/10/96 1 1 BQL
Chlorobenzene 06/10/96 1 1 BQL
I Chloroethane 06/10/96 1 1 EiOL
Chloroform 06/10/96 1 1 BQL
Chloromethane 06/10/96 1 1 BOL
I 2-Chlorotoluene 06/10/96 1 1 BOL
4-Chlorotoluene 06/10/96 1 2 BQL
Dibromochloromethane 06/10/96 1 1 BOL
I 1,2-Dibromo-3-chloropropane 06/10/96 1 1 BQL
1,2-Dibromoethane (EDB) 06/10/96 1 1 BOL
Dibromomethane 06/10/96 1 1 BOL
I 1,2-Dichlorobenzene 06/10/96 1 1 BOL
1,3-Dichlorobenzene 06/10/96 1 1 BOL
1,4-Dichlorobenzene 06/10/96 1 1 BQL
I Dichlorodifluoromethane 06/10/96 1 1 BQL
1, 1-Dichloroethane 06/10/96 1 1 BQL
1,2-Dichloroethane 06/10/96 1 1 BOL
I 1, 1-Dichloroethene 06/10/96 1 1 BQL
cis-1,2-Dichloroethene 06/10/96 1 1 BOL
trans-1,2-Dichloroethene 06/10/96 1 1 BQL
I 1,2-Dichloropropane 06/10/96 1 1 BQL
2,2-Dichloropropane 06/10/96 1 2 BQL
cis-1,3-Dichloropropane 06/10/96 1 1 BOL
I trans-1, 3-Dichloropropane 06/10/96 1 1 BQL
Diisopropyl ether (DIPE) 06/10/96 1 1 BQL
Ethylbenzene 06/10/96 1 1 BQL
I Hexachlorobutadiene 06/10/96 1 1 BOL
lsopropylbenzene 06/10/96 1 1 BQL
p-lsopropyltoluene 06/10/96 1 1 BOL
I Methyl-tert butyl ether (MTBE) 06/10/96 1 1 BQL
Methylene Chloride 06/10/96 1 5 BQL
I Flags:
BQL = Below Quantitation Limit Page 1 of 2
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PARADIGi\I ANALYTICAL LABORATORIES. l!\C.
Results for Volatiles
by GC 8021
Client Sample ID: VBLK061096
Client Project ID: Greshams Lake #29
Lab Sample ID: None assigned
Lab Project ID: G149-4 %Solids: 100.0
Compound
Naphthalene
n-Propylbenzene
Styrene
1, 1, 1,2-Tertrachloroethane
1, 1,2,2-Tertrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1, 1, 1-Trichloroethane
1, 1,2-Trichloroethane
Trichloroethene
Trichlorofluromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl Chloride
m/p-Xylene
a-Xylene
Surrogate Spike Recoveries
1,4-Dichlorobutane
Trifluorotoluene
Date
Analyzed
06/10/96
06/10/96
06/10/96
06/10/96
06/10/96
06/10/96
06/10/96
06/10/96
06/10/96
06/10/96
06/10/96
06/10/96
06/10/96
06/10/96
06/10/96
06/10/96
06/10/96
06/10/96
06/10/96
Dilution
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
Spike
Added
40
40
Comments:
Flags:
All values corrected for dilution and %solids.
Associated samples: 10389 and 10390.
BQL = Below Quantitation Limit
Analyzed By: RNP
Date Collected: Not applicable
Date Received: Not applicable
Matrix: Soil
Quantitation
Limit (ug/KG)
1
1
2
1
1
1
1
1
1
1
1
1
2
1
2
1
2
2
Spike
Result
39
40
Result
(ug/KG)
BQL
BOL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BOL
BQL
BQL
BQL
BQL
Percent
Recovered
98
100
Reviewed By: ('/'0-\...
Pa;ie 2 of 2
I PARADIGM ANALYTICAL LABORATORIES, INC.
Results for Volatiles
I by GC 8021
Client Sample ID: VBLK053096 Analyzed By: RNP
I
Client Project ID: Greshams Lake #29 Date Collected: Not applicable
Lab Sample ID: None assigned Date Received: Not applicable
Lab Project ID:-G149-4 Matrix: Water
I Compound Date Quantitation Result
Analyzed Dilution Limit (ug/L) (ug/L)
I Benzene 5/30/96 1 1 BQL
Bromobenzene 5/30/96 · 1 2 BQL
I Bromochloromethane 5/30/96 1 1 BQL
Bromodichloromethane 5/30/96 1 1 BQL
Bromoform 5/30/96 1 2 BQL
I Bromomethane 5/30/96 1 2 BQL
n-Butylbenzene 5/30/96 1 1 BQL
sec-Butylbenzene 5/30/96 1 1 BQL
I
tert-Butylbenzene 5/30/96 1 1 BQL
Carbon tetrachloride 5/30/96 1 1 BQL
Chlorobenzene 5/30/96 1 1 BQL
Chloroethane 5/30/96 1 BQL
I Chloroform 5/30/96 1 1 BQL
Chloromethane 5/30/96 1 1 BQL
2-Chlorotoluene 5/30/96 1 1 BQL
I 4-Chlorotoluene 5/30/96 1 2 BQL
Dibromochloromethane 5/30/96 1 1 BOL
1,2-Dibromo-3-chloropropane 5/30/96 1 1 BQL
I 1, 2-Dibromoethane (EDB) 5/30/96 1 1 BQL
Dibromomethane 5/30/96 1 1 BQL
1 ,2-Dichlorobenzene 5/30/96 1 1 BQL
I 1,3-Dichlorobenzene 5/30/96 1 1 BQL
1,4-Dichlorobenzene 5/30/96 1 1 BQL
Dichlorodifluoromethane 5/30/96 1 1 BQL.
I 1, 1-Dichloroethane 5/30/96 1 1 BQL
1,2-Dichloroethane 5/30/96 1 1 BQL
1, 1-Dichloroethene 5/30/96 1 1 BQL
cis-1,2-Dichloroethene 5/30/96 1 1 BQL
I trans-1,2-Dichloroethene 5/30/96 1 1 BQL
1,2-Dichloropropane 5/30/96 1 1 BQL
2,2-Dichloropropane 5/30/96 2 BQL
I cis-1,3-Dichloropropane 5/30/96 1 1 BOL
trans-1,3-Dichloropropane 5/30/96 1 1 BQL
Diisopropyl ether (DIPE) 5/30/96 1 1 BQL
I Ethylbenzene 5/30/96 1 1 BQL
Hexachlorobutadiene 5/30/96 1 1 BQL
lsopropylbenzene 5/30/96 1 1 BQL
I p-lsopropyltoluene 5/30/96 1 1 BQL
Methyl-tert butyl ether (MTBE) 5/30/96 1 1 BQL
Methylene Chloride 5/30/96 1 5 BQL
I Naphthalene 5/30/96 1 1 BQL
n-Propylbenzene 5/30/96 1 1 BQL
' ,_
I Flags:
BQL = Below Quantitation Limit
Page 1 of 2
I PARADIG'\,I ANAL\TICAL LABORATORIES. INC.
Results for Volatiles
I by GC 8021
Client Sample ID: VBLK053096 Analyzed By: RNP
Client Project ID: Greshams Lake #29 Date Collected: Not applicable
I Lab Sample ID: None assigned Date Received: Not applicable
Lab Project ID: G149-4 Matrix: Water
I Compound Date Quantitation Result
Analyzed Dilution Limit (ug/L) (ug/L)
I Styrene 5/30/96 1 2 BQL
1 , 1, 1,2-Tertrachloroethane 5/30/96 1 1 BQL
I 1, 1,2,2-Tertrachloroethane 5/30/96 1 1 BQL
Tetrachloroethene 5/30/96 1 1 BQL
Toluene 5/30/96 1 1 BOL
1,2,3-Trichlorobenzene 5/30/96 1 1 BQL
I 1,2,4-Trichlorobenzene 5/30/96 1 1 BQL
1, 1, 1-Trichloroethane 5/30/96 1 1 BQL
1, 1,2-Trichloroethane 5/30/96 1 1 BQL
I Trichloroethene 5/30/96 1 1 BQL
Trichlorofluromethane 5/30/96 1 1 BQL
1,2,3-Trichloropropane 5/30/96 1 2 BQL
I 1,2,4-Trimethylbenzene 5/30/96 1 1 BQL
1,3,5-Trimethylbenzene 5/30/96 1 2 BQL
Vinyl Chloride 5/30/96 1 1 BQL
I m/p-Xylene 5/30/96 1 2 BQL
o-Xylene 5/30/96 1 2 BQL
I Surrogate Spike Recoveries Spike Spike Percent
Added Result Recovered I 1,4-Dichlorobutane 40 37 92
Trifluorotoluene 40 40 100
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I Comments:
All values corrected for dilution.
Reviewed By: MP\...
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I Flags:
BQL = Below Quantitation Limit
Paae 2 of 2
I PARADIGM Ai\ALYTICAL LABORATORIES. li\C.
Batch MS/MSD Results for Volatiles
I
by GC 8021
Client Sample ID: NA Analyzed By: WML
Client Project ID: Greshams Lake #29 Date Collected: 5/17/96
I Lab Sample ID: 10387, 10389, 10390 Date Received: 5/17/96
Lab Project ID: G149-4 %Solids: 77.8 Matrix: Soil
I Compound Result MS MSD
(ug/KG) Result % Rec. Result %Rec. RPO
I Benzene BQL 16 80 16 82 2,1
Bromobenzene BQL 16 80 18 90 11.8
Bromochloromethane BQL 17 85 18 92 8.0
I Bromodichloromethane BQL 16 80 18 88 9.8
Bromoform BQL 16 80 17 87 8.1
Bromomethane BQL 15 ·75 13 64 16
I n-Butylbenzene BQL 17 85 16 79 7.9
sec-Butyl benzene BQL 16 80 16 81 1.6
tert-Butylbenzene BQL 17 85 17 86 1.3
Carbon tetrachloride BQL 8 42 8 42 1.9
I Chlorobenzene BOL 18 90 18 89 0.7
Chloroethane BQL 14 70 14 69 1.5
Chloroform BQL 18 90 17 87 3.2
I Chloromethane BQL 15 75 15 77 2.7
2-Chlorotoluene BQL 18 90 18 92 2.0
4-Chlorotoluene BQL 18 90 19 93 3.3
Dibromochloromethane BQL 17 85 19 93 9.3
I 1 ,2-Dibromo-3-chloropropane BQL 18 90 19 94 4.0
1,2-Dibromoethane (EDB) BQL 16 80 18 90 11
Dibromomethane BQL 16 80 18 90 11.8
I 1,2-Dichlorobenzene BQL 18 90 19 93 2.8
1,3-Dichlorobenzene BQL 18 90 19 93 3.3
1,4-Dichlorobenzene BQL 18 90 18 92 2.0
I Dichlorodifluoromethane BQL 25 125 21 106 16
1 , 1-Dichloroethane BQL 17 85 18 88 3.6
1,2-Dichloroethane BQL · 17 85 19 94 11
1, 1-Dichloroethene BQL 16 80 16 81 1.6
I cis-1,2-Dichloroethene BQL 16 80 16 80 0.0
trans-1,2-Dichloroethene BQL 16 80 17 83 3.7
1,2-Dichloropropane BQL 16 80 17 85 6.4
I 2,2-Dichloropropane BQL 8 42 8 42 0.3
cis-1,3-Dichloropropane BQL 17 85 18 90 5.2
trans-1,3-Dichloropropane BQL 17 85 19 94 9.8
Diisopropyl ether BQL 17 85 17 87 2.4
I Ethylbenzene BQL 16 80 16 82 2.6
Hexachlorobutadiene BQL 15 75 16 82 9.3
lsopropylbenzene BQL 17 85 17 84 0.8
I p-lsopropyltoluene BQL 16 80 17 84 4.4
Methyl-tert butyl ether BQL 16 80 16 80 0.3
Methylene Chloride BQL 17 85 18 91 6.5
I Naphthalene BQL 14 70 15 74 4.9
n-Propylbenzene BQL 17 85 17 84 1.1
Styrene BQL 17 85 17 85 0.2
1, 1, 1,2-Tertrachloroethane BQL 17 85 18 91 7.0
I 1 , 1,2,2-Tertrachloroethane BQL 8 42 9 45 8.3
I Flags:
BQL = Below Quantitation Limit
Page 1 of 2
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PARADIGM ANALYTICAL LABORATORIES, INC.
Batch MS/MSD Results for Volatiles
by GC 8021
Client Sample ID: NA
Client Project ID: Greshams Lake #29
Lab Sample ID: 10387, 10389, 10390
Lab Project ID: G149-4 %Solids: 77.8
Compound Result MS
(ug/KG) Result
Tetrachloroethene BQL 9
Toluene BQL 16
1,2,3-Trichlorobenzene BQL 19
1,2,4-Trichlorobenzene BQL 18
1, 1, 1-Trichloroethane BQL 16
1 , 1 ,2-Trichloroethane BQL 16
Trichloroethene BQL 16
Trichlorofluromethane BQL 14
1,2,3-Trichloropropane BQL 17
1,2,4-Trimethylbenzene BQL 17 .
1,3,5-Trimethylbenzene BQL 16
Vinyl Chloride BQL 15
m/p--Xylene BQL 33
o-Xylene BQL 17
Comments:
All values corrected for dilution and %solids.
Analysis exceeded holding time.
Flags:
BQL = Below Quantitation Limit
% Rec.
43
80
95
90
80
80
80
70
85
85
80
75
83
85
Analyzed By: WML
Date Collected: 5/17 /96
Date Received: 5/17/96
Matrix: Soil
MSD
Result % Rec.
9 43
16 82
17 86
18 92
16 79
17 87
17 85
14 70
18 90
17 85
16 82
15 74
34 84
17 85
Reviewed By: W:::
RPD
0.8
2.7
10
2.5
1.6
8.4
5.6
0.4
6.0
0.3
3.0
1.3
1.5
0.2
Page 2 of 2
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PARADIGM ANALYTICAL LABORATORIES, INC.
Control Limits for
Matrix Spike/ Matrix Spike Duplicate
Method: 8021 Low Soil Limits
20oob spike Pen:ent
Compound Lower Uooer Lower ,_,
Benzene 11.00 29,00 55.01 145.0
Bromobenzene 11.92 28.08 59.60 -140.4
Brcmochforomethane 14.32 25.68 71.58 128.4
Bromodlchloromethane 11.88 28.12 59.38 140.6
Bromoform 12.30 27.70 61.51 138.5
Bromomethane 8.55 3U5 42.73 157.3
n-Butyfoenzene 8.67 31.33 43.34 156.7
sec-Butylbenzene 5.01 34.99 25.05 175.0
tert-Butylbenzene 9.21 30,79 46.05 154.0
Carbon tetrachloride 4.81 35,19 24.06 175.9
Chlorobenzene 6.92 33.08 34.61 166.4
Chloroethane 7.83 32.17 . 39.13 160.9
Chloroform 10.07 29.93 50.36 1-49.6
Chloromethane D 39.88 >O 199.4
2-Chlorotoluene 3.23 36.n 16.14 183.9
4-Chlorototuene 4.06 35.94 20.28 179.7
Oibromochloromethane 12.33 27.67 61.67 138.3
1,2-Dlbromo-3-chloropropane 11.14 28.86 55.71 144.3
1,2-Dlbromoelhane (EDB) 13.09 26.91 65.44 134.6
Dibromomethane 14.09 25.91 70.47 129.5
1,2-Dichlorobenzene 4.32 35.68 21.59 178.4
1,3-Dlchlorobenzene 4.19 35.81 20.94 179.1
1,4-Dlchlorobenzene 5.58 34.42 27.88 172.1
Dlchlorodlfluoromethane 8.75 31.25 43.74 156.3
1 , 1-Dichloroethane 11.12 28.88 55.61 144.4
1,2-Dlchloroethane 14.86 25.14 74.28 125.7
1 , 1-Dlchloroethene 8.48 31.52 42.41 157.6
cis-1,2-Dlchloroethene 12.75 27.25 63.73 136.3
lrans-1,2-Dichloroelhene 8.76 31.24 43.81 15o.2
1,2-Dichloropn,pane . 11.96 28.04 59.78 140.2
2,2-Dichloropropane 4.81 35.19 24.06 175.9
cis-1,3-Dlchloropropene 8.31 31.69 41.53 158.5
trans-1,3-Dlchloropropene 11.53 28.47 57.67 142.3
Dlisopropyl ether 13,82 26.18 69.08 130,9
Ethyl benzene 8.58 31.42 42.92 157.1
Hexachlorobutadiene 1.63 38.37 8.17 191.8
lsopropylbenzene 7.87 32.13 39,33 160.7
p-lsopropylloluene 8.40 31.60 41.98 158.0
Methy!-lert butyt ether 4.36 35.64 21.78 178.2
Methylene Chloride D 67.07 >O 335.3
Naphthalene 8.04 31.96 40.21 159.8
n-Propylbenzene 7.78 32.22 38.91 .161.1
Styrene D 42.79 >O 213.9
1, 1, 1,2-Tertrachloroelhane 8.06 31.94 40.29 159.7
1, 1,2,2-T ertrachloroethane D 52.n >O 263.8
T etrachloroethene 8.79 31.21 43.96 156.0
Toluene 10.08 29.92 50.42 1-49.6
1,2,3-Trichlorobenzene 6.23 34.n 26.16 173.8
1 ,2,4-Trichlorobenzene 3.90 36.10 19.49 180.5
1, 1, 1-Trichloroelhane 7.06 32.94 35.32 164.7
1, 1,2-Trichloroelhane 13.53 26.47 67.67 132.3
Trichloroelhene 8.17 31.83 40.83 159.2
Trichlorofluromethane 5.40 34.60 27.01 173.0
1,2,3-Trichloropropane • 11.92 28.08 59.60 140.4
1,2,4-Trimelhyfbenzene 7.08 32.92 35.39 164.6
1,3,5-Trimelhyfbenzene 5.51 34.49 27.54 172.5
Vinyl Chloride 10.57 29.43 52.83 147.2
m/p-Xylene 17.19 62.81 42.98 157,0
erXylene __ 12.63 27.37 .63.14 136.9
I PARAD!Gi\1 ANAL\TICAL LABORATORIES. INC.
Results for Volatiles
I by GC 62300
Client Sample ID: J38020 Analyzed By: RNP
Client Project ID: NC0360.041, Site No. 29 Date Collected: 05/15/96
I Lab Sample ID: 10317 Date Received: 05/16/96
Lab Project ID: G149-3 Matrix: Water
I Compo\Jnd Date Quantitation Result
Analyzed Dilution Limit (ug/L) (ug/L)
I Benzene 5/23/96 1 0.5 BQL
Bromobenzene 5/23/96 1 0.5 BQL
I Bromochloromethane 5/23/96 0.5 BQL
Bromodichloromethane 5/23/96 0.5 BQL
Bromofonn 5/23/96 1 0.5 BQL
I Bromomethane 5/23/96 1 0.5 BQL
n-Butylbenzene 5/23/96 0.5 BQL
sec-Butylbenzene 5/23/96 0.5 BQL
tert-Butylbenzene 5/23/96 1 0.5 BQL
I Carbon tetrachloride 5/23/96 1 0.5 BQL
Chlorobenzene 5/23/96 1 0.5 BQL
Chloroethane 5/23/96 1 0.5 BQL
I Chlorofonn 5/23/96 1 0.5 BQL
Chloromethane 5/23/96 1 0.5 BQL
2-Chlorotoluene 5/23/96 1 0.5 BQL
I 4-Chlorotoluene 5/23/96 1 0.5 BQL
Dibromochloromethane 5/23/96 1 0.5 BQL
1,2-Dibromo-3-chloropropane 5/23/96 1 0.5 BQL
I 1,2-Dibromoethane (EDB) 5/23/96 1 0.5 BQL
Dibromomethane 5/23/96 1 0.5 BQL
1,2-Dichlorobenzene 5/23/96 1 0.5 BQL
I 1,3-Dichlorobenzene 5/23/96 1 0.5 BQL
1,4-Dichlorobenzene 5/23/96 1 0.5 BQL
Dichlorodinuoromethane 5/23/96 1 0.5 2
I 1, 1-Dichloroethane 5/23/96 1 0.5 1
1,2-Dichloroethane 5/23/96 1 0.5 BQL
1, 1-Dichloroethene 5/23/96 1 0.5 BQL
cis-1,2-Dichloroethene 5/23/96 1 0.5 8
I trans-1,2-Dichloroethene 5/23/96 1 0.5 BQL
1,2-Dichloropropane 5/23/96 1 0.5 BQL
2,2-Dichloropropane 5/23/96 1 0.5 BQL
I cis-1,3-Dichloropropane 5/23/96 1 0.5 BQL
trans-1,3-Dichloropropane 5/23/96 1 0.5 BQL
Diisopropyl ether 5/23/96 1 0.5 BQL
I Ethylbenzene 5/23/96 1 0.5 BQL
Hexachlorobutadiene 5/23/96 1 0.5 BQL
lsopropylbenzene 5/23/96 1 0.5 BQL
I p-lsopropyltoluene 5/23/96 1 0.5 BQL
Methyl-tert butyl ether 5/23/96 1 0.5 3
Methylene Chloride 5/23/96 1 0.5 BQL
I Naphthalene 5/23/96 1 0.5 BQL
n-Propylbenzene 5/23/96 1 0.5 BQL
I Flags:
BQL = Below Quantitation Limit
P::inj:I 1 nf?
I PARADIGM ANALYTICAL LABORATORIES. INC.
Results for Volatiles
I by GC 62300
Client Sample ID: J38020 Analyzed By: RNP
Client Project ID: NC0360.041, Site No. 29 Date Collected:· 05/15/96
I Lab Sample ID: 10317 Date Received: 05/16/96
Lab Project ID: G149-3 Matrix: Water
I Compound Date Quantitation Result
Analyzed Dilution Limit (ug/L) (ug/L)
I Styrene 5/23/96 1 0.5 BOL
1 , 1 , 1 ,2-Tertrachloroethane 5/23/96 1 0.5 BQL
I 1, 1,2,2-Tertrachloroethane 5/23/96 1 0.5 BQL
Tetrachloroethene 5/23/96 1 0.5 2
Toluene 5/23/96 1 0.5 BQl
I 1,2,3-Trichlorobenzene 5/23/96 1 0.5 BQL
1,2,4-Trichlorobenzene 5/23/96 0.5 BQL
1 , 1 , 1-Trichloroethane 5/23/96 1 0.5 BQL
1, 1,2-Trichloroethane 5/23/96 1 0.5 BQL
I Trichloroethene 5/23/96 1 0.5 4
Trichloronuromethane 5/23/96 1 0.5 2
1,2,3-Trichloropropane 5/23/96 1 0.5 _BQL
I 1,2,4-Trimethylbenzene 5/23/96 0.5 BQL
1,3,5-Trimethylbenzene 5/23/96 0.5 BQL
Vinyl Chloride 5/23/96 1 0.5 2
I m/p-Xylene 5/23/96 1 0.5 BQL
a-Xylene 5/23/96 1 0.5 BQL
I
I Surrogate Spike Recoveries Spike Spike Percent
Added Result Recovered
1,4-Dichlorobutane 5 4.8 96 I TriOuorotoluene 5 4.9 98
I
I
I
I Comments:
All values corrected for dilution.
I Reviewed By: Mlh-
I Flags:
BQL = Below Quanlilation Limit
P:::in~ ? nf 'J
I PARADIGM ANALYTICAL LABORATORIES. INC.
Results for Volatiles
I by GC 62300
Client Sample ID: J38019 Analyzed By: RNP
Client Project ID: NC0360.041, Site No. 29 Date Collected: 05/15/96
I Lab Sample ID: 10318 Date Received: 05/16/96
Lab Project ID: G149-3 Matrix: Water
I Compound Date Quantitation Result
Analyzed Dilution Limit (ug/L) (ug/L)
I Benzene 5/23/96 1 0.5 BQL
Bromobenzene 5/23/96 1 0.5 BQL
I Bromochloromethane 5/23/96 1 0.5 BQL
Bromodichloromethane 5/23/96 1 0.5 BQL
Bromoform 5/23/96 0.5 BQL
I Bromomethane 5/23/96 1 0.5 BQL
n-Butylbenzene 5/23/96 1 0.5 BQL
sec-Butylbenzene 5/23/96 1 0.5 BQL
tert-Butylbenzene 5/23/96 1 0.5 BQL
I Carbon tetrachloride 5/23/96 1 0.5 BQL
Chlorobenzene 5/23/96 1 0.5 BQL
Chloroethane 5/23/96 1 0.5 BQL
I Chloroform 5/23/96 1 0.5 BQL
Chloromethane 5/23/96 1 0.5 BQL
2-Chlorotoluene 5/23/96 1 0.5 BQL
I 4-Chlorotoluene 5/23/96 1 0.5 BQL
Dibromochloromethane 5/23/96 1 0.5 BQL
1,2-Dibromo-3-chloropropane 5/23/96 1 0.5 BQL
I 1,2-Dibromoethane (EDB) 5/23/96 0.5 BQL
Dibromomethane 5/23/96 1 0.5 BQL
1,2-Dichlorobenzene 5/23/96 1 0.5 BQL
I 1,3-Dichlorobenzene 5/23/96 1 0.5 BQL
1,4-Dichlorobenzene 5/23/96 1 0.5 BQL
Dichlorodifluoromethane 5/23/96 1 0.5 BQL
I 1 , 1-Dichloroethane 5/23/96 1 0.5 2
1,2-Dichloroethane 5/23/96 1 0.5 BQL
1, 1-Dichloroethene 5/23/96 1 0.5 1
cis-1,2-Dichloroelhene 5/23/96 1 0.5 2
I trans-1 ,2-Dichloroethene 5/23/96 1 0.5 BQL
1,2-Dichloropropane 5/23/96 1 0.5 BQL
2,2-Dichloropropane 5/23/96 1 0.5 BQL
I cis-1 ,3-Dichloropropane 5/23/96 1 0.5 BQL
trans-1,3-Dichloropropane 5/23/96 1 0.5 BQL
Diisopropyl ether 5/23/96 1 0.5 BQL
I Elhylbenzene 5/23/96 1 0.5 BQL
Hexachlorobutadiene 5/23/96 0.5 BQL
lsopropylbenzene 5/23/96 1 0.5 BQL
I p-lsopropyltoluene 5/23/96 1 0.5 BQL
Methyl-tert butyl ether 5/23/96 1 0.5 BQL
Methylene Chloride 5/23/96 1 0.5 BQL
I Naphthalene · 5/23/96 1 0.5 BQL
n-Propylbenzene 5/23/96 1 0.5 BQL
I Flags:
BQL = Below Quantitation Limit
P~nj'.I, 1 nf?
I PARADIGM A!\ALYTICAL LABORATORIES, I i\C.
Results for Volatiles
by GC 62300
I Client Sample ID: J38019 Analyzed By: RNP
Client Project ID: NC0360.041, Site No. 29 Date Collected: 05/15/96
I Lab Sample ID: 10318 Date Received: 05/16/96
Lab Project ID: G149-3 Matrix: Water
I Compound Date Quantitation Result
Analyzed Dilution Limit (ug/L) (ug/L)
I Styrene 5/23/96 1 0.5 BQL
1, 1, 1,2-Tertrachloroethane 5/23/96 1 0.5 BQL
1, 1,2,2-Tertrachloroethane 5/23/96 1 0.5 BQL
I Tetrachloroethene 5/23/96 1 0.5 2
Toluene 5/23/96 1 0.5 BQL
1,2,3-Trichlorobenzene 5/23/96 1 0.5 BQL
I ·1,2,4-Trichlorobenzene 5/23/96 1 0.5 BQL
1, 1, 1-Trichloroethane 5/23/96 1 0.5 1
1, 1,2-Trichloroethane 5/23/96 1 0.5 BQL
I Trichloroethene 5/23/96 1 0.5 4
Trichlorofluromethane 5/23/96 1 0.5 BQL
1,2,3-Trichloropropane 5/23/96 1 0.5 BQL
I 1,2,4-Trimethylbenzene 5/23/96 1 0.5 BQL
1,3,5-Trimethylbenzene 5/23/96 1 0.5 BQL
Vinyl Chloride 5/23/96 1 0.5 BQL
I m/p-Xylene 5/23/96 1 0.5 BQL
a-Xylene 5/23/96 . 1 0.5 BQL
I
Surrogate Spike Recoveries Spike Spike Percent
I Added Result Recovered
1 ,4-Dichlorobutane 5 4.5 90
I Trifluorotoluene 5 4.9 98
I
I
I
I Comments:
All values corrected for dilution.
Reviewed By: NY!::::
I
I Flags:
BQL = Below Quantitation Limit
Page 2 of 2
I PARADIGM ANALYTICAL LABORATORIES. INC.
Results for Volatiles
by GC 62300
I Client Sample ID: REP-01-MW Analyzed By: RNP
Client Project ID: NC0360.041, Site No. 29 Date Collected: 05/15/96
I Lab Sample ID: 10321 Date Received:· 05/16/96
Lab Project ID: G149-3 Matrix: Water
I Compound Date Quantitation Result
Analyzed Dilution Limit (ug/L) (ug/L)
I Benzene 5/23/96 1 0.5 BQL
Bromobenzene 5/23/96 0.5 BQL
I Bromochloromethane 5/23/96 0.5 BQL
Bromodichloromethane 5/23/96 1 0.5 BOL
Bromoform 5/23/96 1 0.5 BQL,_
Bromomethane 5/23/96 1 0.5 BQL
I n-Butylbenzene 5/23/96 1 0.5 BQL
sec-Butylbenzene 5/23/96 1 0.5 BQL
tert-Butylbenzene 5/23/96 1 0.5 BQL
I Carbon tetrachloride 5/23/96 1 0.5 BOL
Chlorobenzene 5/23/96 1 0.5 BQL
Chloroethane 5/23/96 1 0.5 BQL
I Chloroform 5/23/96 1 0.5 BOL
Chloromethane 5/23/96 1 0.5 BQL
2-Chlorotoluene 5/23/96 1 0.5 BQL
I 4-Chlorotoluene 5/23/96 1 0.5 BQL
Dibromochloromethane 5/23/96 1 0.5 BQL
1,2-Dibromo-3-chloropropane 5/23/96 1 0.5 BQL
I 1,2-Dibromoethane (EDB) 5/23/96 1 0.5 BQL
Dibromomethane 5/23/96 1 0.5 BQL
1,2-Dichlorobenzene 5/23/96 1 0.5 BQL
1,3-Dichlorobenzene 5/23/96 1 0.5 BQL
I 1,4-Dichlorobenzene 5/23/96 1 0.5 BQL
DichlorodiOuoromethane 5/23/96 1 0.5 5
1, 1-Dichloroethane 5/23/96 1 0.5 BQL
I 1,2-Dichloroethane 5/23/96 1 0.5 BQL
1, 1-Dichloroethene 5/23/96 1 0.5 BQL
cis-1,2-Dichloroethene 5/23/96 1 0.5 10
I trans-1,2-Dichloroethene 5/23/96 1 0.5 BQL
1,2-Dichloropropane 5/23/96 1 0.5 BQL
2,2-Dichloropropane 5/23/96 1 0.5 BQL
I cis-1,3-Dichloropropane 5/23/96 1 0.5 BQL
trans-1,3-Dichloropropane 5/23/96 1 0.5 BQL
Diisopropyl ether 5/23/96 1 0.5 BQL
I Ethyl benzene 5/23/96 1 0.5 BQL
Hexachlorobutadiene 5/23/96 1 0.5 BQL
lsopropylbenzene 5/23/96 1 0.5 BQL
I p-lsopropyltoluene 5/23/96 1 0.5 BOL
Methyl-tert butyl ether 5/23/96 1 0.5 1
Methylene Chloride 5/23/96 1 0.5 BQL
Naphthalene 5/23/96 1 0.5 BQL
I n-Propylbenzene 5/23/96 1 0.5 BQL
I Flags:
BQL = Below Quantitation Limit
Page 1 of 2
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l'ARADIGi\l ANALYTICAL LABORATORIES. 11\C.
Results for Volatiles
by GC 62300
Client Sample ID: REP-01-MW
Client Project ID: NC0360.041, Site No. 29
Lab Sample ID: 10321
Lab Project ID: G149-3
Compound
Styrene
1, 1, 1,2-Tertrachloroethane
1, 1,2,2-Tertrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1, 1, 1-Trichloroethane
1, 1,2-Trichloroethane
Trichloroethene
Trichlorofluromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl Chloride
m/p-Xylene
a-Xylene
Surrogate Spike Recoveries
1,4-Dichlorobutane
Trifluorotoluene
Comments:
All values corrected for dilution.
Flags:
BQL = Below Quantitation Limit
Date
Analyzed
5/23/96
5/23/96
5/23/96
5/23/96
5/23/96
5/23/96
5/23/96
5/23/96
5/23/96
5/23/96
5/23/96
5/23/96
5/23/96
5/23/96
5/23/96
5/23/96
5/23/96
Dilution
1
1
1
1
1
1
1
1
1
1
1
Spike
Added
5
5
Analyzed By: RNP
Date Collected: 05/15/96
Date Received: 05/16/96
Matrix: Water
Quantitation Result
Limit (ug/L) (ug/L)
0.5 BOL
0.5 BQL
0.5 BQL
0.5 1
0.5 BQL
0.5 BQL
0.5 BQL
0.5 BQL
0.5 BQL
0.5 5
0.5 0.6
0.5
0.5
0.5
0.5
0.5
0.5
Spike
Result
4.5
5
BQL
BQL
BQL
1
BQL
BQL
Percent
Recovered
90
100
Reviewed By: __ _
Page 2 of 2
I PARADIGM ANALYTICAL LABORATORIES. I!\C.
Results for Volatiles
by GC 62300
I Client Sample ID: EB-01-MW Analyzed By: RNP
Client Project ID: NC0360.041, Site No. 29 Date Collected: 05/15/96
I Lab Sample ID: 10322 Date Received: 05/16/96
Lab Project ID:_G149-3 Matrix: Water
I Compound Date Quantitation Result
Analyzed Dilution Limit (ug/L) (ug/L)
I Benzene 5/23/96 1 0.5 SOL
Bromobenzene 5/23/96 1 0.5 SOL
Bromochloromethane 5/23/96 1 0.5 SOL
I Bromodichloromethane 5/23/96 1 0.5 SOL
Bromoform 5/23/96 1 0.5 SOL
Bromomethane 5/23/96 1 0.5 SOL
I n-Butylbenzene 5/23/96 0.5 SOL
sec-Butylbenzene 5/23/96 1 0.5 SOL
tert-Butylbenzene 5/23/96 1 0.5 0.6
I Carbon tetrachloride 5/23/96 1 0.5 SOL
Chlorobenzene 5/23/96 1 0.5 SOL
Chloroethane 5/23/96 1 0.5 SOL
I Chloroform 5/23/96 1 0.5 SOL
Chloromethane 5/23/96 1 0.5 SOL
2-Chlorotoluene 5/23/96 1 0.5 SOL
I 4-Chlorotoluene 5/23/96 1 0.5 SOL
Dibromochloromethane 5/23/96 1 0.5 SOL
1,2-Dibromo-3-chloropropane 5/23/96 1 0.5 SOL
1,2-Dibromoethane (EDS) 5/23/96 1 0.5 SOL I Dibromomethane 5/23/96 1 0.5 BOL
1,2-Dichlorobenzene 5/23/96 1 0.5 BOL
1,3-Dichlorobenzene 5/23/96 1 0.5 BOL
I 1,4-Dichlorobenzene 5/23/96 1 0.5 SOL
Dichlorodifluoromethane 5/23/96 1 0.5 SOL
1, 1-Dichloroethane 5/23/96 1 0.5 BOL
I 1,2-Dichloroethane 5/23/96 1 0.5 .SOL
1, 1-Dichloroethene 5/23/96 1 0.5 SOL
cis-1,2-Dichloroethene 5/23/96 1 0.5 BOL
I trans-1 ,2-Dichloroethene 5/23/96 1 0.5 SOL
1 ,2-Dichloropropane 5/23/96 1 0.5 SOL
2,2-Dichloropropane 5/23/96 1 0.5 SOL
I cis-1,3-Dichloropropane 5/23/96 1 0.5 BOL
trans-1,3-Dichloropropane 5/23/96 1 0.5 SOL
Diisopropyl ether 5/23/96 1 0.5 SOL
I Ethylbenzene 5/23/96 1 0.5 1
Hexachlorobutadiene 5/23/96 1 0.5 BOL
lsopropylbenzene 5/23/96 1 0.5 0.7
p-lsopropyltoluene 5/23/96 1 0.5 SOL
I Methyl-tert butyl ether 5/23/96 1 0.5 BOL
Methylene Chloride 5/23/96 1 0.5 1
Naphthalene 5/23/96 1 0.5 BOL
I n-Propylbenzene 5/23/96 1 0.5 SOL
I Flags:
SOL = Below Ouantitation Limit
Page 1 of 2
I PARADIGM ANALYTICAL LABORATORIES, Ii\C.
Results for Volatiles
I Client Sample ID: EB-01-MW
by GC 62300
Analyzed By: RNP
Client Project ID: NC0360.041, Site No. 29 Date Collected: 05/15/96
I Lab Sample ID: 10322 Date Received: 05/16/96
Lab Project ID: G149-3 Matrix: Water
I Compound Date Quantitation Result
Analyzed Dilution Limit (ug/L) (ug/L)
I Styrene 5/23/96 1 0.5 1
1, 1, 1,2-Tertrachloroethane 5/23/96 1 0.5 SOL
1, 1,2,2-Tertrachloroethane 5/23/96 1 0.5 SOL
I Tetrachloroethene 5/23/96 1 0.5 SOL
Toluene 5/23/96 1 0.5 SOL
1,2,3-Trichlorobenzene 5/23/96 1 0.5 SOL
I 1,2,4-Trichlorobenzene 5/23/96 1 0.5 SOL
1, 1, 1-Trichloroethane 5/23/96 1 0.5 SOL
1, 1,2-Trichloroethane 5/23/96 1 0.5 SOL
I Trichloroethene 5/23/96 1 0.5 SOL
Trichlorofluromethane 5/23/96 1 0.5 SOL
1,2,3-Trichloropropane 5/23/96 1 0.5 SOL
I 1,2,4-Trimethylbenzene 5/23/96 1 0.5 SOL
1,3,5-Trimethylbenzene 5/23/96 1 0.5 1
Vinyl Chloride 5/23/96 1 0.5 0,5
I m/p-Xylene 5/23/96 1 0.5 SOL
o-Xylene 5/23/96 1 0.5 SOL
I
Surrogate Spike ·Recoveries Spike Spike Percent
I Added Result Recovered
1,4-Dichlorobutane 5 4.8 96
I Trifluorotoluene 5 5 100
I
I
I
I Comments:
All values corrected for dilution.
Reviewed By: lN>::::
I
I Flags:
SOL = Below Ouantitation Limit
Page 2 of 2
I PARADIGM Ai\ALYTICAL LABORATORIES, li\C.
Results for Volatiles
by GC 62300
I Client Sample ID: PW Analyzed By: RNP
Client Project ID: NC0360.041, Site No. 29 Date Collected: 05/15/96
I Lab Sample ID: 10323 Date Received: 05/16/96
Lab Project ID: G149-3 Matrix: Water
I Compound Date Quantitation Result
Analyzed Dilution Limit (ug/L) (ug/L)
I Benzene 5/23/96 1 0.5 2
Bromobenzene 5/23/96 1 0.5 BQL
Bromochloromethane 5/23/96 0.5 BOL I Bromodichloromethane 5/23/96 1 0.5 BQL
Bromoform 5/23/96 1 0.5 SOL
Bromomethane 5/23/96 1 0.5 BQL
I n-Butylbenzene 5/23/96 1 0.5 2
sec-Butyl benzene 5/23/96 0.5 0.6
tert-Butylbenzene 5/23/96 1 0.5 1
I Carbon tetrachloride 5/23/96 1 0.5 BQL
Chlorobenzene 5/23/96 1 0.5 19
Chloroethane 5/23/96 1 0.5 BQL
I Chloroform 5/23/96 1 0.5 BQL
Chloromethane 5/23/96 1 0.5 BQL
2-Chlorotoluene 5/23/96 1 0.5 BQL
I 4-Chlorotoluene 5/23/96 1 0.5 BQL
Dibromochloromethime 5/23/96 1 0.5 BQL
1,2-Dibromo-3-chloropropane 5/23/96 1 . 0.5 BQL
1,2-Dibromoethane (EDS) 5/23/96 1 0.5 BQL I Dibromomethane 5/23/96 1 0.5 BQL
1 ,2-Dichlorobenzene 5/23/96 1 0.5 1
1,3-Dichlorobenzene 5/23/96 1 0.5 0.9
I 1 ,4-Dichlorobenzene 5/23/96 1 0.5 5
Dichlorodifluoromethane 5/23/96 1 0.5 10
1 , 1-Dichloroethane 5/23/96 1 0.5 0.8
I 1,2-Dichloroethane 5123/96 1 0.5 BQL
1, 1-Dichloroethene 5123/96 1 0.5 BQL
cis-1,2-Dichloroethene 5123/96 1 0.5 2
I trans-1,2-Dichloroethene 5/23/96 1 0.5 BQL
1,2-Dichloropropane 5/23/96 1 0.5 BQL
2,2-Dichloropropane 5/23/96 1 0.5 BQL
I cis-1.3-Dichloropropane 5/23/96 1 0.5 BQL
trans-1,3-Dichloropropane 5/23/96 1 0.5 BQL
Diisopropyl ether 5/23/96 1 0.5 1
Ethylbenzene 5/23/96 1 0.5 0.9 I Hexachlorobutadiene 5/23/96 1 0.5 BQL
lsopropylbenzene 5/23/96 1 0.5 1
p-lsopropyltoluene 5/23/96 1 0.5 2 ~ Methyl-tert butyl ether 5/23/96 1 0.5 2
Methylene Chloride 5/23/96 1 0.5 BQL
Naphthalene 5/23/96 1 0.5 BQL
~ n-Propylbenzene 5123/96 1 0.5 BQL
i Flags:
BQL = Below Quantitation Limit
Page 1 of 2
I PARADIGM ANALYTICAL LABORATORIES, l!\C.
Results for Volatiles
I
by GC 6230D
Client Sample ID: PW Analyzed By: RNP
Client Project ID: NC0360.041, Site No. 29 Date Collected: 05/15/96
I Lab Sample ID: 10323 Date Received: 05/16/96
Lab Project ID: G149-3 Matrix: Water
I Compound Date Quantitation Result
Analyzed Dilution Limit (ug/L) (ug/L)
I Styrene 5/23/96 1 0.5 BQL
1, 1, 1,2-Tertrachloroethane 5/23/96 1 0.5 BQL
1, 1 ,2,2-Tertrachloroethane 5/23/96 1 0.5 BQL I Tetrachloroethene 5/23/96 1 0.5 2
Toluene 5/23/96 1 0.5 1
1,2,3-Trichlorobenzene 5/23/96 1 0.5 BQL I 1,2,4-Trichlorobenzene 5/23/96 1 0.5 1
1, 1, 1-Trichloroethane 5/23/96 1 0.5 BQL
1, 1,2-Trichloroethane 5/23/96 1 0.5 BQL
I Trichloroethene 5/23/96 1 0.5 1
Trichlorofluromethane 5/23/96 1 0.5 3
1,2,3-Trichloropropane 5/23/96 0.5 BQL
I 1,2,4-Trimethylbenzene 5/23/96 1 0.5 BQL
1,3,5-Trimethylbenzene 5/23/96 1 0.5 BQL
Vinyl Chloride 5/23/96 1 0.5 1
I m/p-Xylene 5/23/96 1 0.5 2
a-Xylene 5/23/96 1 0.5 0.6
I_
Surrogate Spike Recoveries Spike Spike Percent
I Added Result Recovered
1,4-Dichlorobutane 5 4.5 90
I Trifluorotoluene 5 5 100
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I Comments:
All values corrected for dilution.
I Reviewed By:)\.Vh,,
I Flags:
BQL = Below Quantitation Limit
Paoe 2 of 2
I PARADIG~I AI\AL\TICAL LABORATORIES, l:\C.
Results for Volatiles
I
byGC 62300
Client Sample ID: TB-01 (5/15/96) Analyzed By: RNP
Client Project ID: NC0360.041, Site No. 29 Date Collected: 05/15/96
I Lab Sample ID: 10324 Date Received: 05/16/96
Lab Project ID: G149-3 Matrix: Water
I Compound Date Quantitation Result
Analyzed Dilution Limit (ug/L) (ug/L)
I Benzene 5/23/96 1 0.5 BQL
Bromobenzene 5/23/96 1 0.5 BQL
I Bromochloromethane 5/23/96 1 0.5 BQL
Bromodichloromethane 5/23/96 1 0.5 BOL
Bromoform 5/23/96 1 0.5 BQL
Bromomethane 5/23/96 1 0.5 BQL
I n-Butylbenzene 5/23/96 1 0.5 BQL
sec-Butylbenzene 5/23/96 1 0.5 BQL
tert-Butylbenzene 5/23/96 0.5 BQL
I Carbon tetrachloride 5/23/96 1 0.5 BQL
Chlorobenzene 5/23/96 1 0.5 BQL
Chloroethane 5/23/96 1 0.5 BQL
I Chloroform 5/23/96 1 0.5 BQL
Chloromethane 5/23/96 1 0.5 BQL
2-Chlorotoluene 5/23/96 1 0.5 BOL
I 4-Chlorotoluene 5/23/96 1 0.5 BQL
Dibromochloromethane 5/23/96 1 0.5 BQL
1,2-Dibromo-3-chloropropane 5/23/96 1 0.5 BQL
I 1,2-Dibromoethane (EDB) 5/23/96 1 0.5 BQL
Dibromomethane 5/23/96 1 0.5 BQL
1,2-Dichlorobenzene 5/23/96 1 0.5 BQL
I
1,3-Dichlorobenzime 5/23/96 1 0.5 BQL
1,4-Dichlorobenzene 5/23/96 1 0.5 BQL
Dichlorodinuoromethane 5/23/96 1 0.5 BQL
1, 1-Dichloroethane 5/23/96 1 0.5 BQL
I 1,2-Dichloroethane 5/23/96 1 0.5 BQL
1, 1-Dichloroethene 5/23/96 1 0.5 BQL
cis-1 ,2-Dichloroethene 5/23/96 1 0.5 BQL
I trans-1,2-Dichloroethene 5/23/96 1 0.5 BQL
1 ,2-Dichloropropane 5/23/96 1 0.5 BQL
2,2-Dichloropropane 5/23/96 1 0.5 BQL
I cis-1,3-Dichloropropane 5/23/96 1 0.5 BQL
trans-1,3-Dichloropropane 5/23/96 1 0.5 BQL
Diisopropyl ether 5/23/96 1 0.5 BQL
I Ethylbenzene 5/23/96 1 0.5 BQL
Hexachlorobutadiene 5/23/96 1 0.5 BQL
lsopropylbenzene 5/23/96 1 0.5 BQL
I p-lsopropyltoluene 5/23/96 1 0.5 BQL
Methyl-tert butyl ether 5/23/96 1 0.5 BQL
Methylene Chloride 5/23/96 1 0.5 BQL
I Naphthalene 5/23/96 1 0.5 BQL
n-Propylbenzene 5/23/96 1 0.5 BQL
I Flags:
BQL = Below Quantitation Limit
Paoe 1 of 2
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PARADIGM Ai\ALYTICAL LABORATORIES, INC.
Results for Volatiles
by GC 62300
Client Sample ID: TB-01 (5/15/96)
Client Project ID: NC0360.041, Site No. 29
Lab Sample ID: 10324
Lab Project ID: G149-3
Compound
Styrene
1, 1, 1,2-Tertrachloroethane
1. 1,2,2-Tertrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1, 1, 1-Trichloroethane
1, 1,2-Trichloroethane
Trichloroethene
Trichlorofluromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl Chloride
m/p-Xylene
o-Xylene
Surrogate Spike Recoveries
1,4-Dichlorobutane
Trifluorotoluene
Comments:
All values corrected for dilution.
Flags:
SOL = Below Quantitation Limit
Date
Analyzed
5/23/96
5/23/96
5/23/96
5/23/96
5/23/96
5/23/96
5/23/96
5/23/96
5/23/96
5/23/96
5/23/96
5/23/96
5/23/96
5/23/96
5/23/96
5/23/96
5/23/96
Dilution
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
Spike
Added
5
5
Analyzed By: RNP
Date Collected: 05/15/96
Date Received: 05/16/96
Matrix: Water
Quantitation
Limit (ug/L)
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
Spike
Result
4.6
5
Result
(ug/L)
SOL
SOL
SOL
SOL
SOL
SOL
SOL
SOL
SOL
SOL
SOL
SOL
SOL
SOL
SOL
SOL
SOL
Percent
Recovered
92
100
Reviewed By: (\/11"--
Pace 2 of 2
I PARADIGM ANALYTICAL LABORATORIES, INC.
Results for Volatiles
I by GC 62300
Client Sample ID: GW-1 Analyzed By: RNP
Client Project ID: Greshams Lake #29 Date Collected: 05/17/96
I Lab Sample ID: 10418 Date Received: 05/18/96
Lab Project ID: G149-5 Matrix: Water
I Compound Date Quantitation Result
Analyzed Dilution Limit (ug/L) (ug/L)
I Benzene 5/23/96 1 0.5 BQL
Bromobenzene 5/23/96 0.5 BQL
I Bromochloromethane 5/23/96 2 1 BQL
Bromodichloromethane 5/23/96 2 1 BQL
Bromoform 5/23/96 2 1 BQL
I Bromomethane 5/23/96 2 1 BQL
n-Butylbenzene 5/23/96 1 0.5 1
sec-Butylbenzene 5/23/96 1 0.5 1
tert-Butylbenzene 5/23/96 1 0.5 BQL I Carbon tetrachloride 5/23/96 2 1 BQL
Chlorobenzene 5/23/96 2 1 BQL
Chloroethane 5/23/96 2 1 BQL
,I Chloroform 5/23/96 2 1 BQL
Chloromethane 5/23/96 2 1 BQL
2-Chlorotoluene 5/23/96 1 0.5 BQL
I 4-Chlorotoluene 5/23/96 1 0.5 BQL
Dibromochloromethane 5/23/96 2 1 BQL
1,2-Dibromo-3-chloropropane 5/23/96 2 1 BQL
I_ 1,2-Dibromoethane (EDB) 5/23/96 2 1 BQL
Dibromomethane 5/23/96 2 1 BQL
1 ,2-Dichlorobenzene 5/23/96 2 1 BQL
I 1,3-Dichlorobenzene 5/23/96 2 1 BQL
1 ,4-Dichlorobenzene 5/23/96 2 1 BQL
Dichlorodifluoromethane 5/23/96 2 1 BQL
1, 1-Dichloroethane 5/23/96 2 1 2
I 1,2-Dichloroethane 5/23/96 2 1 BQL
1 , 1-Dichloroethene 5/23/96 2 1 8
cis-1,2-Dichloroethene 5/23/96 2 1 BQL
I trans-1,2-Dichloroethene 5/23/96 2 1 BQL
1,2-Dichloropropane 5/23/96 2 1 BQL
2,2-Dichloropropane 5/23/96 2 1 BQL
I cis-1,3-Dichloropropane 5/23/96 2 1 BQL
trans-1,3-Dichloropropane 5/23/96 2 1 BQL
Diisopropyl ether 5/23/96 1 0.5 0.7
I Ethylbenzene 5/23/96 1 0.5 BQL
Hexachlorobutadiene 5/23/96 2 1 BQL
lsopropylbenzene 5/23/96 1 0.5 BQL
I p-lsopropyltoluene 5/23/96 1 0.5 BQL
Methyl-tert butyl ether 5/23/96 1 0.5 BQL
Methylene Chloride 5/23/96 2 1 1
Naphthalene 5/23/96 1 0.5 2 I n-Propylbenzene 5/23/96 1 0.5 BQL
I Flags:
BQL = Below Quantitation Limit
Paoe 1 of 2
I PARADIGM ANALYTICAL LABORATORIES, INC.
Results for Volatiles
I
byGC 6230D
Client Sample ID: GW-1 Analyzed By: RNP
Client Project ID: Greshams Lake #29 Date Collected: 05/17/96
I Lab Sample ID: 10418 Date Received: 05/18/96
Lab Project ID: G149-5 Matrix: Water
I Compound Date Quantitation Result
Analyzed Dilutfon Limit (ug/L) (ug/L)
I Styrene 5/23/96 1 0.5 BQL
1, 1, 1,2-Tertrachloroethane 5/23/96 2 1 BQL
I
1, 1,2,2-Tertrachloroethane 5/23/96 2 1 BQL
Tetrachloroethene 5/23/96 2 1 4
Toluene 5/23/96 1 0.5 1
1,2,3-Trichlorobenzene 5/23/96 2 1 BQL
I 1,2,4-Trichlorobenzene 5/23/96 2 1 BQL
1, 1, 1-Trichloroethane 5/23/96 2 1 34
1, 1,2-Trichloroethane 5/23/96 2 1 BQL
I Trichloroethene 5/23/96 2 1 2
Trichlorofluromethane 5/23/96 2 1 BQL
1,2,3-Trichloropropane 5/23/96 2 1 BQL
I 1,2,4-Trimethylbenzene 5/23/96 1 0.5 BOL
1,3,5-Trimethylbenzene 5/23/96 1 0.5 BQL
Vinyl Chloride 5/23/96 2 1 BQL
I m/p-Xylene 5/23/96 1 0.5 0.9
a-Xylene 5/23/96 1 0.5 BQL
I
I
Surrogate Spike Recoveries Spike Spike Percent
Added Result Recovered
1,4-Dichlorobutane 5 4.7 94 ,, Trifluorotoluene 5 5.2 104
I
I
I
I Comments:
All values corrected for dilution.
Reviewed Bv: W!\,,
I
I Flags:
BQL = Below Quantitation Limit
Page 2 of 2
I PARADIGM ANALYTICAL LABORATORIES, INC.
Results for Volatiles
I
byGC 6230D
Client Sample ID: EB-01-GW Analyzed By: RNP
Client Project ID: Gresh ams Lake #29 Date Collected: 05/17/96
I Lab Sample ID: 10419 Date Received: 05/18/96
Lab Project ID: G149-5 Matrix: Water
I Compound Date Quantitation Result
Analyzed Dilution Limit (ug/L) (ug/L)
I Benzene 5/23/96 1 0.5 BQL
Bromobenzene 5/23/96 1 0.5 BQL
I Bromochloromethane 5/23/96 1 0.5 BQL
Bromodichloromethane 5/23/96 1 0.5 BQL
Bromoform 5/23/96 1 0.5 BQL
Bromomethane 5/23/96 1 0.5 BQL
I n-Butylbenzene 5/23/96 1 0.5 BQL
sec-Butyl benzene 5/23/96 1 0.5 BQL
tert-Butylbenzene 5/23/96 1 0.5 BQL
I Carbon tetrachloride 5/23/96 1 0.5 BQL
Chlorobenzene 5/23/96 1 0.5 BQL
Chloroethane 5/23/96 1 0.5 BQL
I Chloroform 5/23/96 1 0.5 BQL
Chloromethane 5/23/96 1 0.5 BQL
2-Chlorotoluene 5/23/96 1 0.5 BQL
I 4-Chlorotoluene 5/23/96 1 0.5 BQL
Dibromochloromethane 5/23/96 1 0.5 BQL
1,2-Dibromo-3-chloropropane 5/23/96 1 0.5 BQL
I 1,2-Dibromoethane (EDB) 5/23/96 1 0.5 BQL
Dibromomethane 5/23/96 1 0.5 BQL
1,2-Dichlorobenzene 5/23/96 1 0.5 BQL
I 1,3-Dichlorobenzene 5/23/96 1 0.5 BQL
1,4-Dichlorobenzene 5/23/96 1 0.5 BQL
Dichlorodifluoromethane 5/23/96 1 0.5 BQL
1, 1-Dichloroethane 5/23/96 1 0.5 BQL
I 1,2-Dichloroethane 5/23/96 1 0.5 BQL
1, 1-Dichloroethene 5/23/96 1 0.5 BQL
cis-1,2-Dichloroethene 5/23/96 1 0.5 BQL
I trans-1,2-Dichloroethene 5/23/96 1 0.5 BQL
1,2-Dichloropropane 5/23/96 1 0.5 BQL
2,2-Dichloropropane 5/23/96 1 0.5 BQL
I cis-1,3-Dichloropropane 5/23/96 1 0.5 BQL
trans-1,3-Dichloropropane 5/23/96 1 0.5 BQL
Diisopropyl ether 5/23/96 1 0.5 BQL
I Ethyl benzene 5/23/96 1 0.5 0.7
Hexachlorobutadiene 5/23/96 1 0.5 BQL
lsopropylbenzene 5/23/96 1 0.5 BQL
I p-lsopropyltoluene 5/23/96 1 0.5 BQL
Methyl-tert butyl ether 5/23/96 1 0.5 BQL
Methylene Chloride 5/23/96 1 0.5 2
Naphthalene 5/23/96 1 0.5 BQL
I n-Propylbenzene 5/23/96 1 0.5 BQL
I Flags:
BQL = Below Quantitation Limit
Paoe 1 of 2
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PARADIGM ANALYTICAL LABORATORIES. INC.
Results for Volatiles
byGC 62300
Client Sample ID: EB-01-GW
Client Project ID: Greshams Lake #29
Lab Sample ID: 10419
Lab Project ID: G149-5
Compound
Styrene
1, 1, 1,2-Tertrachloroethane
1.1 ,2,2-Tertrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1, 1, 1-Trichloroethane
1, 1,2-Trichloroethane
Trichloroethene
Trichlorofluromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl Chloride
m/p-Xylene
a-Xylene
Surrogate Spike Recoveries
1,4-Dichlorobutane
Trifluorotoluene
Comments:
Date
Analyzed
5/23/96
5/23/96
5/23/96
5/23/96
5/23/96
5/23/96
5/23/96
5/23/96
5/23/96
5/23/96
5/23/96
5/23/96
5/23/96
5/23/96
5/23/96
5/23/96
5/23/96
All values corrected for dilution.
Flags:
BQL = Below Quantitation Limit
Dilution
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
Spike
Added
5
5
Analyzed By: RNP
Date Collected: 05/17/96
Date Received: 05/18/96
Matrix: Water
Quantitation
Limit (ug/L)
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
Spike
Result
4.4
5.1
Result
(ug/L)
BQL
BQL
BQL
BQL
BO~
BQL
BQL
BOL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
Percent
Recovered
88
102
Reviewed By: l'M\'-'-'-'-.,___
Page 2 of 2
I PARADIGM ANALYTICAL LABORATORIES, Ii'\C.
Results for Volatiles
I
by GC 62300
Client Sample ID: TB-02-5/17/96 Analyzed By: RNP
Client Project ID: Greshams Lake #29 Date Collected: 05/17/96
I Lab Sample ID: 10420 Date Received: 05/18/96
Lab Project ID: G149-5 Matrix: Water
I Compound Date Quantitation Result
Analyzed Dilution Limit (ug/L) (ug/L)
I Benzene 5123/96 1 0.5 SOL
Bromobenzene 5/23/96 1 0.5 BQL
I Bromochloromethane 5/23/96 1 0.5 BQL
Bromodichloromethane 5/23/96. 0.5 BQL
Bromoform 5123/96 1 0.5 BQL
Bromomethane 5123/96 1 0.5 BQL
I n-Butylbenzene 5123/96 1 0.5 BQL
sec-Butylbenzene 5123/96 0.5 BQL
tert-Butylbenzene 5/23/96 0.5 BQL
I Carbon tetrachloride 5/23/96 1 0.5 BQL
Chlorobenzene 5/23/96 1 0.5 BQL
Chloroethane 5/23/96 1 0.5 BQL
I Chloroform 5/23/96 1 0.5 BQL
Chloromethane 5123/96 1 0.5 SOL
2-Chlorotoluene 5123/96 1 0.5 BQL
I 4-Chlorotoluene 5/23/96 1 0.5 BQL
Dibromochloromethane 5/23/96 1 0.5 BQL
1,2-Dibromo-3-chloropropane 5/23/96 1 0.5 BQL
I 1 ,2-Dibromoethane (EDS) 5/23/96 1 0.5 BQL
Dibromomethane 5123/96 1 0.5 BQL
1 ,2-Dichlorobenzene 5123/96 1 0.5 BQL
1,3-Dichlorobenzene 5123/96 1 0.5 BQL ·1 1,4-Dichlorobenzene 5/23/96 1 0.5 BQL
Dichlorodifluoromethane 5/23/96 1 0.5 BQL
1, 1-Dichloroethane 5/23/96 1 0.5 BQL
•· 1,2-Dichloroethane 5/23/96 1 0.5 BQL
1 , 1-Dichloroethene 5/23/96 1 0.5 BQL
cis-1,2-Dichloroethene 5/23/96 1 0.5 BQL
I trans-1,2-Dichloroethene 5/23/96 1 0.5 BQL
1 ,2-Dichloropropane 5/23/96 1 0.5 BQL
2,2-Dichloropropane 5/23/96 1 0.5 BQL
I cis-1,3-Dichloropropane 5/23/96 1 0.5 BQL
trans-1,3-Dichloropropane 5/23/96 1 0.5 BQL
Diisopropyl ether 5123/96 1 0.5 BQL
I Ethylbenzene 5123/96 1 0.5 BQL
Hexachlorobutadiene 5/23/96 1 0.5 BQL
lsopropylbenzene 5/23/96 1 0.5 BQL
p-lsopropyltoluene 5/23/96 1 0.5 BQL I Methyl-tert butyl ether 5/23/96 1 0.5 BQL
Methylene Chloride 5/23/96 1 0.5 BQL
Naphthalene . 5/23/96 1 0.5 BQL
I n-Propylbenzene 5/23/96 1 0.5 BQL
I Flags:
BQL = Below Quantitation Limit
Page 1 of 2
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PARADIGM ANAL \TICAL LABORATORIES, INC.
Results for Volatiles
byGC 6230D
Client Sample ID: TB-02-5/17/96
Client Project ID: Greshams Lake #29
Lab Sample ID: 10420
Lab Project ID: G149-5
Compound
Styrene
1, 1, 1,2-Tertrachloroethane
1, 1,2,2-Tertrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
· 1,2,4-Trichlorobenzene
1, 1, 1-Trichloroethane
1, 1,2-Trichloroethane
Trichloroethene
Trichlorofluromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl Chloride
m/p-Xylene
o-Xylene
Surrogate Spike Recoveries
1,4-Dichlorobutane
Trifluorotoluene
Comments:
All values corrected for dilution.
Flags:
BQL = Below Quantitation Limit
Date
Analyzed
5/23/96
5/23/96
5/23/96
5/23/96
5/23/96
5/23/96
5/23/96
5/23/96
5/23/96
5/23/96
5/23/96
5/23/96
5/23/96
5/23/96
5/23/96
5/23/96
5/23/96
Dilution
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
Spike
Added
5
5
Analyzed By: RNP
Date Collected: 05/17 /96
Date Received: 05/18/96
Matrix: Water
Quantitation
Limit (ug/L)
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
Spike
Result
4.4
5.1
Result
(ug/L)
BQL
BQL
BQL
BQL
BOL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
Percent
Recovered
88
102
Reviewed By: \>Jh.."'u:.,. __
Page 2 of 2
I PARADIGM ANALYTICAL LABORATORIES. l!\C.
· Results for Volatiles
I by GC 62300
Client Sample ID: VBLK052296 Analyzed By: WML
Client Project ID: NC0360.041, Site No. 29 Date Collected: Not applicable
I Lab Sample ID: None assigned Date Received: Not applicable
Lab Project ID: G149-2 Matrix: Water
I Compound Date Quantitation Result
Analyzed Dilution Limit (ug/L) (ug/L)
I Benzene 5/22/96 1 0.5 BQL
Bromobenzene 5/22/96 1 0.5 BQL
I Bromochloromethane 5/22/96 1 0.5 BQL
Bromodichloromethane 5/22/96 1 0.5 BQL
Bromoform 5/22/96 1 0.5 BQL
Bromomethane 5/22196 1 0.5 BQL I n-Butylbenzene 5/22/96 1 0.5 BQL
sec-Butylbenzene 5/22/96 1 0.5 BQL
tert-Butylbenzene 5/22/96 1 0.5 BQL
I Carbon tetrachloride 5/22/96 1 0.5 BQL
Chlorobenzene 5/22/96 1 0.5 BQL
Chloroethane 5/22/96 1 0.5 _BQL
I Chloroform 5/22/96 1 0.5 BQL
Chloromethane 5/22/96 1 0.5 BQL
2-Chlorotoluene 5/22/96 1 0.5 BQL
I 4-Chlorotoluene 5/22196 1 0.5 BQL
Dibromochloromethane 5/22/96 1 0.5 BQL
1,2-Dibromo-3-chloropropane 5/22/96 1 0.5 BQL
I 1,2-Dibromoethane (EDB) 5/22196 1 0.5 BQL
Dibromomethane 5/22/96 1 0.5 BQL
1 ,2-Dichlorobenzene 5/22/96 1 0.5 BQL
1,3-Dichlorobenzene 5/22/96 1 0.5 BQL I 1 ,4-Dichlorobenzene 5/22/96 1 0.5 BQL
Dichlorodifluoromethane 5/22196 1 0.5 BQL
1 , 1-Dichloroethane 5/22/96 1 0.5 BQL
I 1,2-Dichloroethane 5/22/96 1 0.5 BQL
1 , 1-Dichloroethene 5/22/96 1 0.5 BQL
cis-1,2-Dichloroethene 5/22196 1 0.5 BQL
I trans-1,2-Dichloroethene 5/22/96 1 0.5 BQL
1,2-Dichloropropane 5/22196 1 0.5 BQL
2,2-Dichloropropane 5/22/96 1 0.5 BQL
I cis-1 , 3-Dichloropropane 5/22196 1 0.5 BQL
trans-1,3-Dichloropropane 5/22/96 1 0.5 BQL
Diisopropyl ether 5/22196 1 0.5 BQL
I Ethylbenzene 5/22/96 1 0.5 BQL
Hexachlorobutadiene 5/22/96 1 0.5 BQL
lsopropylbenzene 5/22/96 1 0.5 BQL
I p-lsopropyltoluene 5/22196 1 0.5 BQL
Methyl-tert butyl ether 5/22/96 1 0.5 BQL
Methylene Chloride 5/22/96 1 0.5 BQL
Naphthalene 5/22196 1 0.5 BQL
I n-Propylbenzene 5/22196 1 0.5 BQL
I Flags:
BQL = Below Quantitation Limit
Paoe 1 of 2
I PARADIGM ANALYTICAL LABORATORIES. l!\C.
Results for Volatiles
I byGC 6230D
Client Sample ID: VBLK052296 Analyzed By: WML
Client Project ID: NC0360.041, Site No. 29 Date Collect"ed: Not applicable
I Lab Sample ID: None assigned Date Received: Not applicable
Lab Project ID: G149-2 Matrix: Water
I Compound Date Quantitation Result
Analyzed Dilution Limit (ug/L) (ug/L)
I Styrene 5/22/96 0.5 BQL
1, 1, 1,2-Tertrachloroethane 5/22/96 1 0.5 BQL
I 1, 1,2,2-Tertrachloroethane 5/22/96 1 0.5 BQL
Tetrachloroethene 5/22/96 1 0.5 BQL
Toluene 5/22/96 1 0.5 BQL
1,2,3-Trichlorobenzene 5/22/96 1 0.5 BQL I 1,2,4-Trichlorobenzene 5/22/96 1 0.5 BQL
1, 1, 1-Trichloroethane 5/22/96 1 0.5 BQL
1, 1,2-Trichloroethane 5/22/96 1 0.5 BQL
I Trichloroethene 5/22/96 1 0.5 BQL
Trichlorofluromethane 5/22/96 1 0.5 BQL
1,2,3-Trichloropropane 5/22/96 1 0.5 BQL
I 1,2,4-Trimethylbenzene 5/22/96 1 0.5 BQL
1,3,5-Trimethylbenzene 5/22/96 1 0.5 BQL
Vinyl Chloride 5/22/96 1 0.5 BQL
I m/p-Xylene 5/22/96 1 0.5 BQL
a-Xylene 5/22/96 1 0.5 BQL
I
I Surrogate Spike Recoveries Spike Spike Percent
Added Result Recovered
1,4-Dichlorobutane 5 4.8 96
I Trifluorotoluene 5 5 100
I
I
I
I Comments:
All values corrected for dilution.
I Reviewed By: fWh
I Flags:
BQL = Below Quantitation Limit
Paae 2 of 2
I PARADIGM ANAL\TICAL LABORATORIES. li\C.
Results for Volatiles
I by GC 62300
Client Sample ID: VBLK052296 Analyzed By: RNP
I
Client Project ID: Greshams Lake #29 Date Collected: Not applicable
Lab Sample ID: None assigned Date Received: Not applicable
Lab Project ID: G149-5 Matrix: Water
I Compound Date Quantitation Result
Analyzed Dilution Limit (ug/L) (ug/L)
I Benzene 5/22/96 1 0.5 BQL
Bromobenzene 5/22/96 1 0.5 BQL
I Bromochloromethane 5122/96 1 0.5 BQL
Bromodichloromethane 5122/96 1 0.5 BQL
Bromoform 5/22/96 1 0.5 BQL
I Bromomethane 5/22/96 1 0.5 BQL
n-Butylbenzene 5/22/96 1 0.5 BQL
sec-Butylbenzene 5122/96 1 0.5 BQL
tert-Butylbenzene 5/22/96 1 0.5 BQL I Carbon tetrachloride 5/22/96 1 0.5 BQL
Chlo'robenzene 5/22/96 1 0.5 BQL
Chloroethane 5/22/96 1 0.5 BQL
I Chloroform 5/22/96 1 0.5 BQL
Chloromethane 5/22/96 1 0.5 BQL
2-Chlorotoluene 5/22/96 1 0.5 BQL
I 4-Chlorotoluene 5/22/96 1 0.5 BOL
Dibromochloromethane 5122/96 1 0.5 BOL
1,2-Dibromo-3-chloropropane 5122/96 1 0.5 BQL
I 1 ,2-Dibromoethane (EDB) 5122/96 1 0.5 BQL
Dibromomethane 5122/96 1 0.5 BQL
1,2-Dichlorobenzene 5122/96 1 0.5 BQL
I 1,3-Dichlorobenzene 5122/96 1 0.5 BQL
1 ,4-Dichlorobenzene 5/22/96 1 0.5 BQL
Dichlorodifluoromethane 5/22/96 1 0.5 BQL
I 1, 1-Dichloroethane 5/22/96 1 0.5 BQL
1,2-Dichloroethane 5122/96 1 0.5 BQL
1, 1-Dichloroethene 5122/96 1 0.5 BQL
cis-1 ,2-Dichloroethene 5122/96 1 0.5 BQL I trans-1,2-Dichloroethene 5122/96 1 0.5 BQL
1,2-Dichloropropane 5/22/96 1 0.5 BQL
2,2-Dichloropropane 5/22/96 1 0.5 BQL
I cis-1,3-Dichloropropane 5122/96 1 0.5 BQL
trans-1,3-Dichloropropane 5/22/96 1 0.5 BQL·
Diisopropyl ether 5122/96 1 0.5 BQL
I Ethylbenzene 5122/96 1 0.5 BQL
Hexachlorobutadiene 5/22/96 1 0.5 BQL
lsopropylbenzene 5/22/96 1 0.5 BQL
I p-lsopropyltoluene 5/22/96 1 0.5 BQL
Methyl-tert butyl ether 5122/96 1 0.5 BQL
Methylene Chloride 5/22/96 1 0.5 BQL
I Naphthalene 5/22/96 1 0.5 BQL
n-Propylbenzene 5/22/96 1 0.5 BQL
I Flags:
BQL = Below Quantitation Limit
D~n~ 1 "'f 'J
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D
PARADIGM ANADTICAL LABORATORIES. 11\C.
Results for Volatiles
byGC 62300
Client Sample ID: VBLK052296
Client Project ID: Greshams Lake #29
Lab Sample ID: None assigned
Lab Project ID: G149-5
Compound
Styrene
1 , 1, 1,2-Tertrachloroethane
1 , 1,2,2-Tertrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1, 1, 1-Trichloroethane
1, 1,2-Trichloroethane
Trichloroethene
Trichlorofluromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl Chloride
m/p-Xylene
a-Xylene
Surrogate Spike Recoveries
1,4-Dichlorobutane
Trifluorotoluene
Date
Analyzed
5/22/96
5/22/96
5/22/96
5/22/96
5/22/96
5/22/96
5/22/96
5/22/96
5/22/96
5/22/96
5/22/96
5/22/96
5/22/96
5/22/96
5/22/96
5/22/96
5/22/96
Dilution
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
Spike
Added
5
5
Comments:
All values corrected for dilution.
Associated samples: 10420, 10418, and 10419.
Flags:
BQL = Below Quantitation Limit
Analyzed By: RNP
Date Collected: Not applicable
Date Received: Not applicable
Matrix: Water
Quantitation
Limit (ug/L)
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
Spike
Result
4.8
5
Result
(ug/L)
BQL
BQL
BQL
BQL
BQL
BQL
SOL
BOL
BQL
BOL
BOL
BOL
BOL
BQL
BQL
BOL
BQL
Percent
Recovered
96
100
Reviewed By: l':'Y?::,
Paoe 2 of 2
I PARADIGM ANALYTICAL LABORATORIES. INC.
Results for Volatiles
I by GC 6230D
Client Sample ID: VBLK052396 Analyzed By: RNP
Client Project ID: Greshams Lake #29 Date Collected: Not applicable
I Lab Sample ID: None assigned Date Received: Not applicable
Lab Project ID: G149-5 Matrix: Water
I Compound Date Quantitation Result
Analyzed Dilution Limit (ug/L) (ug/L)
I Benzene 5/23/96 1 0.5 BQL
Bromobenzene 5/23/96 1 0.5 BQL
I Bromochloromethane 5/23/96 0.5 BQL
Bromodichloromethane 5/23/96 0.5 BQL
Bromoform 5/23/96 1 0.5 BQL
I Bromomethane 5123/96 1 0.5 BQL
n-Butylbenzene 5/23/96 1 0.5 BQL
sec-Butylbenzene 5123/96 1 0.5 SOL
tert-Butylbenzene 5/23/96 1 0.5 BQL
I Carbon tetrachloride 5123/96 1 0.5 BQL
Chlorobenzene 5123/96 1 0.5 SOL
Chloroethane 5123/96 1 0.5 BQL
I Chloroform 5/23/96 1 0.5 BQL
Chloromethane 5123/96 1 0.5 SOL
2-Chlorotoluene 5/23/96 1 0.5 BQL
I 4-Chlorotoluene 5123/96 1 0.5 BQL
Dibromochloromethane 5/23/96 1 0.5 BQL
1,2-Dibromo-3-chloropropane 5/23/96 1 0.5 BQL
I 1,2-Dibromoethane (EDS) 5123/96 1 0.5 BQL
Dibromomethane 5123/96 1 0.5 BQL
1 ,2-Dichlorobenzene 5123/96 1 0.5 BQL
I 1,3-Dichlorobenzene 5/23/96 1 0.5 BQL
1 ,4-Dichlorobenzene 5/23/96 1 0.5 BQL
Dichlorodifluoromethane 5/23/96 1 0.5 BQL
1, 1-Dichloroethane 5/23/96 1 0.5 BQL
I 1 ,2-Dichloroethane 5/23/96 1 0.5 BQL
1, 1-Dichloroethene 5/23/96 1 0.5 BQL
cis-1,2-Dichloroethene 5123/96 1 0.5 BQL
I trans-1,2-Dichloroethene 5123/96 1 0.5 SOL
1,2-Dichloropropane 5123/96 1. 0.5 BQL
2,2-Dichloropropane 5123/96 1 0.5 BQL
I cis-1,3-Dichloropropane 5/23/96 1 0.5 BQL
trans-1,3-Dichloropropane 5/23/96 1 0.5 BQL
Diisopropyl ether 5123/96 1 0.5 BQL
I Ethyl benzene 5/23/96 1 0.5 BQL
Hexachlorobutadiene 5/23/96 1 0.5 BQL
lsopropylbenzene 5/23/96 1 0.5 BQL
I p-lsopropyltoluene 5/23/96 1 0.5 BQL
Methyl-tert butyl ether 5123/96 1 0.5 BQL
Methylene Chloride 5/23/96 1 0.5 BQL
I Naphthalene 5/23/96 1 0.5 BQL
n-Propylbenzene 5/23/96 1 0.5 BQL
I Flags:
BQL = Below Quantitalion Limit
Pan~ 1 nf?
I PARADIGM ANALYTICAL LABORATORIES, li\C.
Results for Volatiles
by GC 62300
I Client Sample ID: VBLK052396 Analyzed By: RNP
Client Project ID: Greshams Lake #29 Date Collected: Not applicable
I Lab Sample ID: None assigned Date Received: Not applicable .
Lab Project ID: G149-5 Matrix: Water
I Compound Date Quantitation Result
Analyzed Dilution Limit (ug/L) (ug/L)
I Styrene 5/23/96 1 0.5 SOL
1, 1, 1,2-Tertrachloroethane 5/23/96 1 0.5 SOL
I 1 , 1 ,2,2-Tertrachloroethane 5/23/96 1 0.5 SOL
Tetrachloroethene 5/23/96 1 0.5 SOL
Toluene 5/23/96 1 0.5 SOL
1,2,3-Trichlorobenzene 5/23/96 1 0.5 BQL
I 1,2,4-Trichlorobenzene 5/23/96 1 0.5 SOL
1,1,1-Trichloroethane 5/23/96 1 0.5 SOL
1, 1,2-Trichloroethane 5/23/96 1 0.5 SOL
I Trichloroethene 5/23/96 1 0.5 SOL
Trichlorofluromethane 5/23/96 1 0.5 SOL
1,2,3-Trichloropropane 5/23/96 1 0.5 SOL
I 1,2,4-Trimethylbenzene 5/23/96 1 0.5 SOL
1,3,5-Trimethylbenzene 5/23/96 1 0.5 SOL
Vinyl Chloride 5/23/96 1 0.5 SOL
I m/p-Xylene 5/23/96 1 0.5 SOL
a-Xylene 5/23/96 1 0.5 SOL
I
I
Surrogate Spike Recoveries Spike Spike Percent
Added Result Recovered
1 ,4-Dichlorobutane 5 4.5 90
I Trifluorotoluene 5 5 100
I
I
I
I Comments:
All values corrected for dilution.
Associated sample: 10418. Reviewed By: Wfr,,
I
I Flags:
SOL= Below Ouantitation Limit
Page 2 of 2
I PARADIGM ANAL\TICAL LABORATORIES. INC.
Results for Volatiles
I by GC 6230D
Client Sample ID: VBLK052396 Analyzed By: WML
I
Client Project ID: NC0360.041, Site No. 29 Date Collected: Not applicable
Lab Sample ID: None assigned Date Received: Not applicable
Lab Project ID: G149-3 Matrix: Water
I Compound Date Quantitation Result
Analyzed Dilution Limit (ug/L) (ug/L)
I Benzene 5/23/96 1 0.5 BOL
Bromobenzene 5/23/96 1 0.5 BQL
I Bromochloromethane 5/23/96 1 0.5 BQL
Bromodichloromethane 5/23/96 1 0.5 BQL
Bromoform 5/23/96 1 0.5 BQL
I Bromomethane 5/23/96 1 0.5 BQL
n-Butylbenzene 5/23/96 1 0.5 BQL
sec-Butylbenzene 5/23/96 1 0.5 BQL
I
tert-Butylbenzene 5/23/96 1 0.5 BQL
Carbon tetrachloride 5/23/96 1 0.5 BQL
Chlorobenzene 5/23/96 1 0.5 BQL
Chloroethane 5/23/96 1 0.5 BQL
I Chloroform 5/23/96 1 0.5 BQL
Chloromethane 5/23/96 1 0.5 BQL
2-Chlorotoluene 5123/96 1 0.5 BQL
I 4-Chlorotoluene 5123/96 1 0.5 BQL
Dibromochloromethane 5123/96 1 0.5 BQL
1,2-Dibromo-3-chloropropane 5/23/96 1 0.5 BQL
I 1,2-Dibromoethane (EDB) 5/23/96 1 0.5 BQL
Dibromomethane 5/23/96 1 0.5 BQL
1 ,2-Dichlorobenzene 5/23/96 1 0.5 BQL
I 1,3-Dichlorobenzene 5/23/96 1 0.5 BOL
1,4-Dichlorobenzene 5/23/96 1 0.5 BQL
Dichlorodifluoromethane 5/23/96 1 0.5 BQL
I 1, 1-Dichloroethane 5/23/96 1 0.5 BQL
1,2-Dichloroethane 5/23/96 1 0.5 BQL
1 , 1-Dichloroethene 5123/96 1 0.5 BQL
cis-1 ,2-Dichloroethene 5/23/96 1 0.5 BQL
I trans-1,2-Dichloroethene 5/23/96 1 0.5 BQL
1,2-Dichloropropane 5/23/96 1 0.5 BQL
2,2-Dichloropropane 5/23/96 1 0.5 BQL
! I cis-1,3-Dichloropropane 5/23/96 1 0.5 BQL
trans-1,3-Dichloropropane 5/23/96 1 0.5 BQL
Diisopropyl ether 5/23/96 1 0.5 BQL
I Ethylbenzene 5/23/96 1 0.5 BQL
Hexachlorobutadiene 5123/96 1 0.5 BQL
lsopropylbenzene 5/23/96 1 0.5 BQL
I p-lsopropyltoluene 5/23/96 1 0.5 BQL
Methyl-tert butyl ether 5/23/96 1 0.5 BQL
Methylene Chloride 5/23/96 1 0.5 BQL
I Naphthalene 5/23/96 1 0.5 BOL
n-Propylbenzene 5/23/96 1 0.5 BQL
I Flags:
BQL = Below Quantitation Limit
Paae 1 of 2
I PARADIGM ANAL \TICAL LABORATORIES, INC.
Results for Volatiles
I byGC 62300
Client Sample ID: VBLK052396 Analyzed By: WML
Client Project ID: NC0360.041, Site No. 29 Date Collected: Not applicable
I Lab Sample ID: None assigned Date Received: Not applicable
Lab Project ID: G149-3 Matrix: Water
I Compound Date Quantitation Result
Analyzed Dilution Limit (ug/L) (ug/L)
I Styrene 5/23/96 1 0.5 BQL
1, 1, 1,2-Tertrachloroethane 5/23/96 1 0.5 BQL
I 1, 1 ,2,2-Tertrachloroethane 5/23/96 1 0.5 BQL
Tetrachloroethene 5/23/96 1 0.5 BQL
Toluene 5/23/96 1 0.5 BQL
I 1,2,3-Trichlorobenzene 5/23/96 1 0.5 BQL
1,2,4-Trichlorobenzene 5/23/96 1 0.5 BQL
1, 1, 1-Trichloroethane 5/23/96 1 0.5 BQL
1, 1,2-Trichloroethane 5/23/96 1 0.5 BQL
I Trichloroethene 5/23/96 1 0.5 BQL
Trichlorofluromethane 5/23/96 1 0.5 BQL
1,2,3-Trichloropropane 5/23/96 1 0.5 BQL
I 1,2,4-Trimethylbenzene 5/23/96 1 0.5 BQL
1,3,5-Trimethylbenzene 5/23/96 1 0.5 BQL
Vinyl Chloride 5/23/96 1 0.5 BQL
I m/p-Xylene 5/23/96 1 0.5 BQL
a-Xylene 5/23/96 1 0.5 BQL
I
I Surrogate Spike Recoveries Spike Spike Percent
Added Result Recovered
1,4-Dichlorobutane 5 4.5 90
I Trifluorotoluene 5 5 100
I
I
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I Comments:
All values corrected for dilution.
I Reviewed By: fl\ll--.
I
I Flags:
I
BQL = Below Quantitation Limit
Paae 2 of 2
I PARADIGM ANALYTICAL LABORATORIES. Ii\C.
Batch MS/MSD Results for Volatiles
I
by GC 6230D
Client Sample ID: J38019 Analyzed By: RNP
Client Project ID: NC0360.041, Site No. 29 Date Collected: 5/15/96
I Lab Sample ID: 10318 Date Received: 5/16/96
Lab Project ID: G149-3 Matrix: Water
I Compound Result MS MSD
(ug/L) Result 'lo Rec. Result 'lo Rec. RPO
I Benzene SOL 6.4 128 5.3 106 18
Bromobenzene SOL 6.3 126 5 100 23
I Bromochloromethane BOL 6 120 4.6 92 27
Bromodichloromethane SOL 5.5 110 5.2 105 4.9
Bromotorm SOL 3.2 64 3.1 62 2.9
I Bromomethane BOL 2.7 54 2.7 54 0.6
n-Butylbenzene SOL 5.1 102 5.1 102 0.5
sec-Butylbenzene SOL 5.6 112 5.6 112 0.1
tert-Butylbenzene SOL 5.8 116 5.8 116 0.4
I Carbon tetrachloride SOL 7.5 150 5.4 109 32 ..,_
Chlorobenzene SOL 6.4 128 6 120 6.2
Chloroethane SOL 4.8 96 4.1 82 15
I Chloroform SOL 6.6 132 5 99 28
Chloromethane SOL 3.5 70 2.5 50 34-lf-
2-Chlorotoluene SOL 6.2 124 5.9 118 5
I 4-Chlorotoluene SOL 6.5 130 5.7 113 14
Dibromochloromethane SOL 5.8 116 5.5 110 5.1
1.2-Dibromo-3-chloropropane BOL 6.5 130 4.9 98 28
I 1,2-Dibromoethane (EDS) SOL . 6.2 124 5.8 115 7.4
Dibromomethane SOL 6.1 122 5.7 113 7.6
1,2-Dichlorobenzene BOL 6.2 124 5.8 115 7.4
I 1,3-Dichlorobenzene SOL 6.2 124 5.7 113 9.1
1,4-Dichlorobenzene SOL 6.5 130 5.9 118 9.7
Dichlorodifluoromethane SOL 8.6 172 7.4 147 16
1, 1-Dichloroethane 2 4.1 82 4.8 96 16
I 1,2-Dichloroethane SOL 6.8 137 5.2 105 26
1, 1-Dichloroethene 1 7 140 6 119 16
cis-1,2-Dichloroethene 2 5.4 108 3.7 74 38+
I trans-1,2-Dichloroethene SOL 7.5 150 6.4 129 15
1,2-Dichloropropane SOL 7.1 142 5.6 112 24
2,2-Dichloropropane SOL 7.4 148 5.7 114 26
I cis-1 ,3-Dichloropropane BOL 7.3 146 6.8 136 7
trans-1.3-Dichloropropane BOL 6.5 130 6.2 123 5.3
Diisopropyl ether SOL 5.5 110 4.6 92 18
I Ethylbenzene SOL 7.2 144 5.9 118 20
Hexachlorobutadiene SOL 6.2 124 6.2 124 0.1
lsopropylbenzene BOL 5.6 112 5.9 118 5.1
I p-lsopropyltoluene BOL 5.2 104 5.2 104 0.2
Methyl-tert butyl ether SOL 6.1 122 10 100 20
Methylene Chloride BOL 6.2 124 5.3 106 16
I Naphthalene SOL 5.5 110 6.6 132 18
n-Propylbenzene SOL 5.8 116 5.9 118 1.4
I Flags:
SOL = Below Ouantitation Limit
Paoe 1 of 2
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PARADIGM ANALYTICAL LABORATORIES. INC.
Batch MS/MSD Results for Volatiles
by GC 62300
Client Sample ID: J38019 Analyzed By: RNP
Client Project ID: NC0360.041, Site No. 29 Date Collected: 5/15/96
Lab Sample ID: 10318 Date Received: 5/16/96
Lab Project ID: G149-3 Matrix: Water
Compound Result MS MSD
(ug/L) Result % Rec. Result % Rec.
Styrene BQL 5.5 110 6.6 132
1, 1, 1,2-Tertrachloroethane BQL 5.8 116 5.5 110
1, 1,2,2-Tertrachloroethane BQL 6.3 126 5 100
Tetrachloroethene 2 4.7 94 4.1 82
Toluene BQL 6.8 136 5.6 112
1,2,3-Trichlorobenzene BQL 6.2 124 6 121
1,2,4-Trichlorobenzene BQL 6.2 124 5.7 115
1, 1, 1-Trichloroethane 1 7.2 144 5.1 103
1, 1,2-Trichloroethane BQL 6.5 130 6.2 124
Trichloroethene 4 7 140 4.8 97
Trichlorofluromethane BQL 6.2 124 5.2 103
1,2,3-Trichloropropane BQL 6.3 126 5 100
1,2,4-Trimethylbenzene BQL 5.5 110 5.4 108
1,3,5-Trimethylbenzene BQL 5.5 110 5.6 111
Vinyl Chloride BQL 7.1 142 6.5 130
m/p-Xylene BQL 14 140 11.6 116
o-Xylene BQL 5.9 118 5.3 105
Comments:
All values corrected for dilution.
Reviewed By: ['!W\,
Flags:
BQL = Below Quantitalion Limit
RPD
18
5.1
23
13
19
2.5
7.9
34 ~
4.7
,37
18
23
2.3
1.2
8.5
19
11
Page 2 of 2
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PARADIGM ANALYTICAL LABORATORIES, INC.
Control Limits for
Matrix Spike I Matrix Spike Duplicate
Method: 62300 Limits
5nnb soike Perant
Compound Lower U"""r Lower •-r
Benzene 2.28 7.72 -45.69 154.3
Bromobenzene 3.27 6.73 65.39 134.6
Bromochlorcmethane 3.12 6.88 62.39 137.6 -Bromodlchloromethane 2.66 7.34 53.28 146.7
Bromoform 3.13 6.87 62.60 137A
Bromomethane 1.17 8.83 23.38 176.6
n-Butylbenzene D 12.34 >0 246.8
sec-Butytbenzene 0.50 9.50 9.92 190.1
tert-Butylbenzene 0.59 9A1 11.81 188.2
Carbon tetrachloride D 11.96 >0 239.2
Ch lore benzene 2.07 7.93 41.48 158.5
Chloroelhane 2.08 7.92 41.64 158.4
Chloroform 3.10 6.90 61.99 138.0
Chloromethane 3.55 6.45 71.07 128.9
2-Chlorotoluene D 9.89 >0 197.8
4-Chlorotoluene 0.81 9.19 16.27 183.7
Dlbromochloromelhane 3.17 6.83 63.33 136.7
1.2-Dibromo-3-chloropropane 3.53 6.47 70.51 129.5
1.2-Dibromoethane (EDB) 3.07 6.93 61A7 138.5
Dibromomethane 3.53 6.47 70.69 129.3
1,2-Dlchlorobenrene 2.02 7.98 40.50 159.5
1,3-Dlchlorobenrene 1.26 8.74 25.15 174.9
1,4-Dlchlorobenz-ene 1.16 8.84 23.29 176.7
Dichlorodifluoromethane D 10.73 >0 214.6
1, 1-Dlchloroethane 1.63 8.37 32.59 167A
1,2-Dichloroethane 2.55 7A5 50.92 149.1
1 , 1-Dlchloroelhene 0.86 9.14 17.29 182.7
cis-1,2•0ichkJroethene ·D 10.23 >O 204.6
trans-1,2-llichloroethene 1.26 8.74 25.14 174.9
1,2-Dlchloropropane 1.91 8.09 38.27 161.7
2,2-Dichloropropane D 11.96 >O 239.2
cis-1,3-Dichloropropene 2A2 7.58 48.47 151.5
trans-1,3-Dlchloropropene 2.98 7.02 59,65 140.3
Dlisopropyl ether 3.20 6.80 64.03 136.0
Ethyl benzene 1.33 8.67 26.66 173.3
Hexachlorobutadiene D 12.84 >0 256.8
lsopropylbenzene 0.80 9.20 16,07 183,9
p-lsopropyltolUene D 12.39 >0 247.9
Methyl-lert bulyt ether 0.27 9.73 6.47 194.5
Methylene Chloride 3.48 6.52 69.57 130.4
Naphthalene 2.02 7.98 40.49 159.5
n-Propylbenzene 0.83 9,17 16.62 _ 183.4
Styrene 0.74 9.26 14.82 185.2
1,1,1,2-Tertrachloroethane 2.20 7.80 44.03 156.0
1, 1,2,2-T ertrachloroethane D 12.06 >0 241.2
T etrachloroethene D 12.42 >0 248.5
Toluene 1.37 8.63 27.31 172.7
1,2,3-Trichlorobenzene 1.11 8.89 22.23 177.8
1,2,4-Trichlorobenzene 1.39 8.61 27.83 172.2
1 , 1 , 1-T richloroethane 0.90 9.10 18.02 182.0
1, 1,2-Trichloroethane 3.04 6.96 60.77 139.2
Trichlorcethene 2.78 7.22 55.67 144.3
Trichlorofluromethane 1.54 8.46 30.71 169.3
1,2,3-Tri~ne 3.27 8.73 66.39 134.6
1,2.4-Trimethylbenzene 1.53 U7 30.64 169.4 .
1,3,5-Trimethylbenzene 1.31 8.69 26.19 173.8
Vinyl Chloride 0.96 9.06 18.93 181.1
mlp-Xylene 2.88 17.12 57.57 171.2
o-Xylene 1.95 8.05 38.99 161.0
I PARADIGM ANALYTICAL LABORATORIES. INC.
Results for Volatiles
by GC 6230D
I Client Sample ID: LCS052296 Analyzed By: RNP
Client Project ID: NC0360.041, Site No. 29 Date Collected: Not applicable
I Lab Sample ID: None assigned Date Recejved: Not applicable
Lab Project ID: G149-3 Matrix: Water
I Compound Date Quantitation Result
Analyzed Dilution Limit (ug/L) (ug/L) %Rec.
I Benzene 5/22196 . 1 0.5 5.6 112
Bromobenzene 5/22196 1 0.5 6.8 136
Bromochloromethane 5/22196 1 0.5 5.6 112
I Bromodichloromethane 5122196 1 0.5 5.5 110
Bromoform 5122196 1 0.5 5.4 108
Bromomethane 5122196 1 0.5 3.4 68
I n-Butylbenzene 5/22196 1 0.5 5.9 118
sec-Butylbenzene 5/22196 1 0.5 6.3 126
tert-Butylbenzene 5/22196 1 0.5 6.2 124
I Carbon tetrachloride 5/22196 1 0.5 5.2 104
Chlorobenzene 5122196 1 0.5 6.2 124
Chloroethane 5/22196 1 0.5 4.2 84
I Chloroform 5/22196 1 0.5 . 5.8 116
Chloromethane 5/22196 1 0.5 4.3 86
2-Chlorotoluene 5/22196 1 0.5 5.7 114
I 4-Chlorotoluene 5/22196 1 0.5 6.1 122
Dibromochloromethane 5122196 1 0.5 5.8 116
1,2-Dibromo-3-chloropropane 5122196 1 0.5 6.2 124
1 ,2-Dibromoethane (EDB) 5122196 1 0.5 5.9 118
I Dibromomethane 5122196 1 0.5 6.0 120
1,2-Dichlorobenzene 5122196 1 0.5 5.9 118
1,3-Dichlorobenzene 5122196 1 0.5 5.7 114
I 1,4-Dichlorobenzene 5122196 1 0.5 6.1 122
Dichlorodifluoromethane 5/22196 1 0.5 6.1 122
1, 1-Dichloroethane 5/22196 1 0.5 4.1 82
I 1 ,2-Dichloroethane 5/22196 1 0.5 6.2 124
1, 1-Dichloroethene 5122196 1 0.5 5.9 118
cis-1,2-Dichloroethene 5/22196 1 0.5 5.2 104
I lrans-1 ,2-Dichloroelhene 5122196 1 0.5 5.9 118
1 ,2-Dichloropropane 5/22196 1 0.5 6.1 122
2,2-Dichloropropane 5/22196 1 0.5 5.2 104
I cis-1,3-Dichloropropane 5/22196 1 0.5 6.2 124
trans-1,3-Dichloropropane 5/22196 1 0.5 6.0 120
Diisopropyl ether (DIPE) 5122196 1 0.5 5.3 106
Ethyl benzene 5/22196 1 0.5 6.2 124
I Hexachlorobutadiene 5122196 1 0.5 5.7 114
lsopropylbenzene 5122196 1 0.5 6.2 124
p-lsopropyltoluene 5122196 1 0.5 6.0 120
I Methyl-tert butyl ether (MTBE) 5122196 1 0.5 4.9 98
Methylene Chloride 5122196 1 0.5 6.1 122
Naphthalene 5122196 1 0.5 5.7 114
I n-Propylbenzene 5122196 1 0.5 6.4 128
I Flags:
BQL = Below Quantitation Limit
Page 1 of 2
I PARADIGM A!\ALYTICAL LABORATORIES. 11\C.
Results for Volatiles
byGC 62300
I Client Sample ID: LCS052296 Analyzed By: RNP
Client Project ID: NC0360.041, Site No. 29 Date Collected: Not applicable
I Lab Sample ID: None assigned Date Received: Not applicable
Lab Project ID: G149-3 Matrix: Water
I Compound Date Quantitation Result
Analyzed Oilutfon Limit (ug/L) (ug/L) %Rec.
I Styrene 5/22/96 1 0.5 6.5 130
1, 1 , 1,2-Tertrachloroethane 5/22/96 1 0.5 6.3 126
1, 1,2,2-Tertrachloroethane 5/22/96 1 0.5 5.7 114
I Tetrachloroethene 5/22/96 1 0.5 5.8 116
Toluene 5/22/96 1 0.5 5.9 118
1,2,3-Trichlorobenzene 5/22/96 1 0.5 6.2 124
I 1,2,4-Trichlorobenzene 5/22/96 1 0.5 6.4 128
1, 1, 1-Trichloroethane 5/22/96 1 0.5 6.0 120
1, 1,2-Trichloroethane 5/22/96 1 0.5 6.2 124
I Trichloroethene 5/22/96 1 0.5 5.8 116
Trichlorofluromethane 5/22/96 1 0.5 4.8 96
1,2,3-Trichloropropane 5/22/96 1 0.5 6.8 136
I 1,2,4-Trimethylbenzene 5/22/96 1 0.5 6.3 126
1,3,5-Trimethylbenzene 5/22/96 1 0.5 6.3 126
Vinyl Chloride 5/22/96 1 0.5 6.0 120
I m/p-Xylene 5/22/96 1 0.5 12.0 120
a-Xylene · 5/22/96 1 0.5 6.5 130
I Surrogate Spike Recoveries Spike Spike Percent
Added Result Recovered
I 1,4-Dichlorobutane 5.0 5.0 100
Trifluorotoluene 5.0 5.0 100
I
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Comments:
I All values corrected for dilution.
Reviewed By: [1Y?'\
I
I · Flags:
BQL = Below Quantitation Limit
Page 2 of 2
I PARADIGM ANALYTICAL LABORATORIES, INC.
Response Factor Report
' I Method: 6230D Water Batch: 052196
H1: 023F0201.D P1: 023R0201.D
I H2: 024F0201.D P2: 024R0201.D
H3: 025F0201.D P3: 025R0201.D
H4: 026F0201.D P4: 026R0201 .D -
I HS: 027F0201.D PS: 027R0201.D
Compound 1 2 3 4 5 Avg. ¾RSD
I Benzene 1.419 1.161 1.014 1.186 1.389 1.234 13.71
Bromobenzene 0.504 0.396 0.376 0.358 0.397 0.406 14.07
Bromochloromethane 0.594 0.669 0.7 0.744 0.879 0.717 14.73
I Bromodichloromethane 1.352 1.128 1.127 1.201 1.313 1.224 8.53
Bromoform 0.105 0.13 0.187 0.140 30,04
Bromomethane 0.129 0.134 0.156 0.139 10.20
I n-Butylbenzene 1.240 0.724 0.641 1.357 1.313 1.055 32.58
sec-Butyl benzene 0.768 0.396 0.361 0.803 0.733 0.612 35.11
tert-Butylbenzene 0.743 0.395 0.363 0.736 0.697 0.587 32.53
Carbon tetrachloride 4.672 3.639 2.992 3.87 3.657 3.766 16.03 I Chlorobenzene 0.781 0.528 0.473 0.678 0.675 0.627 19.88
Chloroethane 0.994 1.008 0.812 0.915 0.969 0.939 8.47
Chloroform 2.602 2.474 2.142 2.055 2.246 2.304 9.93
I Chloromethane 0.699 0.608 0.498 0.527 0.581 0.583 13.43
2-Chlorotoluene 0.820 0.608 0.498 0.527 0.581 0.607 20.87
4-Chlorotoluene 0.836 0.487 0.757 0.661 0.685 21.93
I Dibromochloromethane 0.477 0.491 0.524 0.597 0.665 0.551 14.31
1,2-Dibromo-3-chloropropane 0.084 0.045 0.053 0.062 0.061 27.79
1,2-Dibromoethane (EDB) 0.418 0.408 0.385 0.452 0.504 0.434 10.61
I Dibromomethane 0.389 0.378 0.383 0.427 0.486 0.413 11.01
1,2-Dichlorobenzene 0.863 0.556 0.475 0.803 0.738 0.687 24.03
1,3-Dichlorobenzene 0.988 0.592 0.5 0.892 0.834 0.761 27.12
I 1,4-Dichlorobenzene 1.121 0.669 0.58 1.074 0.945 0.878 27.61
Dichlorodifluoromethane 0.582 0.434 0.495 0.476 0.497 12.53
1 , 1-Dichloroethane 1.971 2.019 1.802 1.857 1.916 1.913 4.54
1 ,2-Dichloroethane 1.175 1.117 1.087 1.075 1.112 1.113 3.49 I 1 , 1-Dichloroethene 1.881 1.698 1.437 1.727 1.626 1.674 9.68
cis-1 ,2-Dichloroethene 3.175 3.023 2.575 2.617 2.801 2.838 9.11
trans-1 ,2-Dichloroethene 2.075 1.944 1.702 1.834 1.805 1.872 7.62
I 1,2-Dichloropropane 2.135 1.701 1.385 1.399 1.373 1.599 20.62
2,2-Dichloropropane 4.672 3.639 2.992 3.87 3.657 3.766 16.03
cis-1,3-Dichloropropane 1.141 0.935 0.931 1.015 1.117 1.028 9.61
I trans-1,3-Dichloropropane 0.665 0.586 0.568 0.619 0.688 0.625 8.17
Diisopropyl ether 0.415. 0.404 0.39 0.402 0.502 0.423 10.78
Ethylbenzene 1.042 0.679 0.595 1.013 1.028 0.871 24.83
I Hexachlorobu1adiene 1.769 1.515 1.296 1.527 15.50
lsopropylbenzene 0.739 0.427 0.757 0.729 0.663 23.76
p-lsopropyltoluene 1.528 0.897 1.6 1.564 1.397 23.97
I Methyl-tert butyl ether 1.283 1.177 1.091 1.297 1.464 1.262 11.14
Methylene Chloride 2.026 1.716 1.607 1.727 1.769 10.16
Naphthalene 0.246 0.154 0.263 0.314 0.244 27.27
I
n-Propylbenzene 0.903 0.503 0.928 0.873 0.802 25.03
I Page 1 of 2
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PARADIGM Al'\AL\TICAL LABORATORIES. 1!\C.
Response Factor Report
Method: 6230D Water Batch: 052196
H1: 023F0201.D P1: 023R0201 .D
H2: 024F0201.D P2: 024R0201 .D
H3: 025F0201.D P3: 025R0201 .D
H4: 026F0201.D P4: 026R0201 .D
HS: 027F0201.D PS: 027R0201 .D
Compound 1 2 3 4 5 Avg.
Styrene 1.958 1.346 1.178 1.841 1.773 1.619
1, 1, 1,2-Tertrachloroethane 2.022 1.703 1.529 1.76 1.789 1.761
1, 1,2,2-Tertrachloroethane 0.636 0.584 0.562 0.719 0.792 0.659
Tetrachloroethene 3.730 2.586 2.183 2.868 2.631 2.800
Toluene 1.243 0.858 0.775 1.1 1.195 1.034
1,2,3-Trichlorobenzene 0.690 0.458 0.334 0.731 0.72 0.587
1,2,4-Trichlorobenzene 0.839 0.508 0.388 0.795 0.739 0.654
1.1.1-Trichloroethane 2.556 2.279 1.909 2.122 2.108 2.195
1, 1,2-Trichloroethane 1.528 1.214 0.961 0.88 0.899 1.096
Trichloroethene 2.509 1.866 1.633 1.95 1.991 1.990
Trichlorofluromethane 2.085 1.756 1.441 1.794 1.711 1.757
1.2.3-Trichloropropane 0.504 0.396 0.376 0.358 0.397 0.406
1,2.4-Trimethylbenzene 0.969 0.727 0.502 1.003 0.994 0.839
1,3,5-Trimethylbenzene -2.252 1.388 1.18 2.292 2.254 1.873
Vinyl Chloride 1.393 1.261 1.044 1.142 1.181 1.204
m/p-Xylene 2.350 1.798 1.329 2.317 2.323 2.023
o-Xylene 1.958 1.346 1.178 1.841 1.773 1.619
¾RSD
20.89
10.07
14.61
20.55
20.08
30.65
29.97
10.98
25.16
16.16
13.06
14.07
26.24
28.99
10.89
22.33
20.89
Page 2 of 2
I Calibration Report
==-··-----.---------------------------------------------------------------------
l ata File Name
perator
C:\HPCHEM\1\DATA\052196\027R0201.D
RNP Page Number l
27
1 I rument HALL/PID Vial Number
I~ ,.,le Name VSTD025 Injection Number
un Time Bar Code:
cquired on 22
Report Created on: 22
l ast Recalib on : 22
ultiplier : 1
I
Pk#
1 I
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2
3
5
6
7
8
9
RT
3.555
5.807
7.176
7.989
8.839
9.855
10.175
10.596
11.143
Lvl
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
6
1
2
3
May 96
May 96
May 96
µg/L
1.0
2.0
5.0
10.0
25.0
1.0
2.0
5.0
10.0
25.0
2.0
4.0
10.0
20.0
.so. 0
1. 0
2.0
5.0
10.0
25.0
1. 0
2.0
5.0
10.0
25.0
1. 0
2.0
5.0
10.0
25.0
1.0
2.0
5.0
10.0
25.0
5.0
5.0
5.0
5.0
5.0
5.0
1. 0
2.0
5.0
07:16
12:36
12:35
AM
PM
PM
Sequence Line
Instrument Method:
Analysis Method
Sample Amount
ISTD Amount
2
502 HAL.MTH
502 PID.MTH
0
5
Calibration Table
Amt/Area
8.6879e-005
8.6438e-oos
9.2641e-005
8.0601e-005
6.6102e-005
3.9538e~oos
4.3856e-005
4.9011e-005
3.8548e-005
3.2451e-oos
2.2944e-005
2.4886e-005
2.7349e-005
2.2294e-005
1.9138e-oos
3.5444e-005
3.6274e-oos
3.8285e-D05
3.5997e-005
2.7893e-005
2.7161e-005
2.8245e-005
3 .·109e-005
2.8109e-005
2.2538e-005
2.7309e-005
3.6283e-005
4.1256e-005
2.6992e-005
2.5278e-005
1. 037e-005
1.2617e-005
1.4712e-005
1.2191e-005
1.008Be-005
9.1979e-006
9.1544e-006
9.3225e-006
9.0367e-006
8.7578e-006
8.4115e-006
2.0087e-005
2.4856e-005
2.B078e-005
Ref Istd I# Name
1 (H) Vinyl chloride
1 (H) 1,1-Dichloroethe ...
1 MTBE (H) t-12DCE
1 DIPE
l (H) c-12dce
1 (H) ~1-Diclpropene
1 Benzene
ISTD 1 * Fluorobenzene *
1 (H) Trichloroethene
4 .Lu . u .1. • .::::,.::.,"':tc-u ,.J_, 12 May 96 12:36 PM page 2
ethod: C:\HPCHEM\l\METHODS\502 PID.MTH
I 5 25.0 l.7377e-005
10 11.565 6 5.0 2.657le-005 1 $ a,a,a-Trifluorotol ...
12.551 1 1.0 7.8448e-005 1 (H) c-13pene
I 2 2.0 8.7632e-005
3 5.0 9.1006e-005
4 ·10. 0 7.835e-005
5 25.0 6.17le-005
I 12 13.031 1 1.0 l.1835e-005 1 Toluene
2 2.0 l.7069e-005
3 5.0 l.9254e-005
I 4 10.0 l.3142e-005
5 25.0 l.1722e-005
13 13.371 1 1.0 7.8515e-005 1 (H) t-13pene
I 2 2.0 8.89e-005
3 5.0 8.9452e-005
4 10.0 7.827e-005
5 25.0 6.138le-005
I 14 13.839" 1 1.0 2.7508e-005 1 (H) Tetrachloroethen ...
2 2.0 4.1928e-005
3 5.0 4.5519e-005
I 4 10.0 2.514e-005
5 25.0 2.5195e-005
15 15.128 1 1. 0 l.4629e-005 1 (H) Chlorobenzene
I 2 2.0 2.0548e-005
3 5.0 2.214le-005
4 10.0 l.4523e-005
I 5 25.0 l.2902e-005
15.278 1 1.0 l.4127e-005 1 Ethylbenzene
2 2.0 2.1587e-005
3 5.0 2.5068e-005
I 4 10.0 l.4269e-005
5 25.0 l.3634e-005
17 15.453 1 2.0 l.2523e-005 1 rn-Xylene ; p-Xylene
I 2 4.0 l.6292e-005
3 10.0 2.2453e-005
4 20.0 1. 2479e-005
I
5 50.0 1. 2065e-005
18 16.069 1 2.0 l.503e-005 1 o-Xylene Styrene
2 4.0 2.1762e-005
3 10.0 2.533le-005
I 4 20.0 1. 5703e-005
5 50.0 l.5809e-005
19 16.609 1 1.0 l.9916e-005 1 Isopropylbenzene
I 2 2.0 3.4276e-005
3 5.0 3.8402e-005
4 10.0 l.9108e-005
I 5 25.0 l.9217e-005
20 17.094 1 1. 0 1. 7878e-005 1 (H) Brornobenzene
2 2.0 2.5213e-005
3 5.0 2.7893e-005
I 4 10.0 l.7797e-005
5 25.0 1. 5558e-005
1 17.240 1 1.0 l.6297e-005 1 n-Propylbenzene
I 2 2.0 2.9144e-005
3 5.0 3.3417e-005
4 10.0 l.558e-005
I 5 25.0 l.6042e-005
22 17.385 1 1. 0 l.5277e-005 1 (H) 2Cltoluene
L ,. . u L, •.... -....,~~ -. -t May 96 12:36 PM
page 3
thod: C:\HPCHEM\l\METHODS\502 PID.MTH
I 3 5.0 2.8684e-005
4 10.0 l.5128e-005
5 25.0 l.4523e-005
I 17.513 1 2.0 l.307le-005 1 135-Trimethylbenz
2 4.0 2.1108e-005
3 10.0 2.5272e-005
4 20.0 l.2615e-005
I 5 50.0 l.2436e-005
24 18.011 1 1.0 l.9798e-005 1 tert-Butylbenzene
2 2.0 3.7llle-005
I 3 5.0 4.104le-005
4 10.0 l.9636e-005
5 25.0 2.0l0le-005
I 25 18.088 1 1. 0 l.5186e-005 1 1~4-Trimethylbenzene
2 2.0 2.0159e-005
3 5.0 2.9693e-005
4 10.0 l.44lle-005
I 5 25.0 l.4103e-005
26 18.350 1 1. 0 l.9168e-005 1 sec-Butylbenzene
2 2.0 3.7014e-005
I 3 5.0 4.1266e-005
4 10.0 l.8017e-005
5 25.0 l.9122e-005
I 27 18.549 1 2.0 l.9263e-005 1 p-Isopropyltoluene , ...
2 4.0 3.2673e-005
3 10.0 3.7403e-005
I
4 20.0 l.8072e-005
5 50.0 l.7924e-005
J 18.677 1 1.0 l.888le-005 1 (H) 14dcb
2 2.0 2.845e-005
I 3 5.0 3.3872e-005
4 10.0 l.7288e-005
5 25.0 l.6748e-005
I 29 19.219 1 2.0 2.3742e-005 1 n-Butylbenzene ; (H) ...
2 4.0 4.0466e-005
3 10.0 4.652le-005
I
4 20.0 2.1317e-005
5 50.0 2.1338e-005
30 21.776 1 1. 0 4.2952e-005 1 (H) 124-Triclbenzene
2 2.0 7.2383e-005
I 3 5.0 9.8822e-005
4 10.0 3.B00le-005
5 25.0 3.4964e-005
I 31 22.034 1 1. 0 3.8257e-005 1 (H) Hexaclbutadiene
2 2.0 7.1346e-005
3 5.0 9.0763e-005
I
4 10.0 3.5794e-005
5 25.0 3.7558e-005
32 22.166 1 1.0 5.9746e-005 1 Naphthalene
2 2.0 9.4924e-005
I 3 5.0 l.0613e-004
4 10.0 5.507le-005
5 25.0 4.4597e-005
I ..l 22.549 1 1.0 5.4744e-005 1 (H) 123Triclbenzene
2 2.0 8.2164e-005
3 5.0 l.0384e-004
I 4 10.0 4.B623e-005
:,
12 May 96 12:36 PM
etbod: C:\HPCHEM\l\METHODS\502_PID.MTH
I
1. _e:
I 8021 HALL 5mL
Reference window:
Ion-reference window:
nits of amount:
Multiplier:
CF uncal peaks :
STD# to adjust uncal peaks:
ample Amount:
I
I
I
I
I
I
I
I
I
I
I
I
I
I#
1
Amount
5.0
Fit: Linear
Origin: Force
Calibration Settings
5.000 %
5.000 %
µg/L
1.0
0.0
0
0.0
Sample ISTD Information
Multilevel Information
page 4
==-==----======---=-------------------
I= Internal Standard Report
--.----·_-----===------------------------------------------------------------=
,,,rata File Name
~perator
C:\HPCHEM\l\DATA\052196\025R0201.D
RNP Page Number
. ·.rument HALL/PID Vial Number
c. .,ile Name VSTD005 Injection Number
11Run Time Bar Code:
•cquired on 22
Report Created on: 22
111-ast Recalib on 22
rultiplier 1
May 96
May 96
May 96
06:14
12:33
12:33
AM
PM
PM
i&;ig. 2 in C:\HPCHEM\l\DATA\052196\025R0201.D
Sequence Line
InBtrument Method:
Analysis Method
Sample Amount
ISTD Amount
1
25
1
2.
502 HAL.MTH
502 PID.MTH
0
5
•1et Time Area Type Width Ref# µg/L Name 1-------1------------1----1-----1-----1--------1------------------------------1
3.559 53972 PV 0.098 1 5.529 (H) Vinyl chloride
5.811 102019 BV 0.086 1 3.826 (H) 1,1-Dichloroethene
7.178 365648 PV 0.074 1 10.464 MTBE ; (H) t-12DCE I
7.991 130600 BV 0.087 1 5.634 DIPE
8.840 160823 BV 0.063 1 5.284 (H) c-12dce
9.855 121195 PV 0.061 1 4.146 (H) 11-Diclpropene
10.175 339854 PV 0.060 1 4.506 Benzene I
10.596 536337 VV 0.058 1-I 5.000 * Fluorobenzene *
11.143 178073 BV 0.055 1 4.303 (H) Trichloroethene
11.565 171969 BV 0.059 1 5.064 $ a,a,a-Trifluorotoluene $ I
12.550 54941 PV 0.048 1 5.445 (H) c-13pene
13.030 259685 PV 0.051 1 4.042 Toluene
13.371 55896 VV 0.046 1 5.428 (H) t-13pene I
13.838 109845 VV 0.052 1 3.726 (H) Tetrachloroethene
I 5.126 225825 PV 0.046 1 4.000 (H) Chlorobenzene
.5.276 199461 VV 0.048 1 3.538 Ethylbenzene
15.450 445378 VV 0.050 1 7.010 m-Xylene; p-Xylene
I 16.069 394768 VV 0.060 1 7.578 o-Xylene ; Styrene
16.607 130203 VV 0.051 1 3.272 Isopropylbenzene
· 17.092 179255 BV 0.045 1 3.911 (H) Bromobenzene
I
I
I
I
17.238 149623 VV 0.048 1 3.047 n-Propylbenzene
17.383 174313 VV 0.048 1 3.364 (H} 2Cltoluene
17.510 395698 VV 0.071 1 6.397 135-Trimethylbenz (H) 4Cltol
18.010 121829 VV 0.051 1 3.119 tert-Butylbenzene
18.087 168388 VV 0.048 1 3.138 124-Trimethylbenzene
18.349 121166 VV 0.053 1 2.874 sec-Butylbenzene
18.545 267361 VV 0.069 1 6.254 p-Isopropyltoluene ; (H) 13dcb
18. 676 147614 VV O. 046 1 3. 392 (H) 14dcb
19.251 214954 VV 0.090 1 6.013 n-Butylbenzene ; (H) 12dcb
21.773 50596 PV 0.041 1 2.175 (H) 124-Triclbenzene
22.031 55089 PV 0.053 1 2.405 (H) Hexaclbutadiene
22.163 47114 VV 0.045 1 2.483 Naphthalene
22.546 48153 BB 0.046 1 2.134 (H) 123Triclbenzene
•===---=.==-==================================--================================
I
I
I
w w ~ m rn ✓ m I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
0 0 0 0 0 0 0 0
m m m m m m m m
0 ..,.-'-....__._...Jtr--'-~-'--t ~'-'--1t~. ~~~~t_.__,_~~L..,__,-----'-"-_l____c._~.._:tw,___._,_~
m
f-'
0
f-'
m
w
0
w
lnata File r-ffi.me
Operator
•
Instrument :
Sample Name :
P· · Time Bar Code:
, .1ired on :
IRepor~ Created on:
Last Recalib on :
I
Multiplier
JU
t::===============~-.....;-------Mi.1'-,-ffil-H-7,178
t:========--{\IP[ 7.991
l:==========------{H) c-12d<e 8840
t==========------------IH) TricMoroe\~ne 11.143
t;;;;=f!,m,=========-----------4 o.o.o-Trilluorotolul.'ne S 11.565
\,==-------IIH) c-\Jpe,e 12.550
H) 1-13ptne 11371
H) lelrochloroelhent 11838
.. 5.126
H B10 er.e 17.092
4-/HHS...+J.Sto
124-Trimelhylbt'nzene 18.087
olue,e: (H) \Jdcb 18.545
l:=============----,,-lljjyll,"1•"'; (H) 12d<b 19.251
19.992
20.486
2.992
C:\HPCHEM\l\DATA\052196\025R0201.D
RNP Page Number
HALL/PID Vial Number
VSTD005 Injection Number
22
22
22
1
May 96
May 96
May 96
06:14
12:33
12:33
AM
PM
PM
Sequence Line
Instrument Method:
Analysis Method
Sample Amount
!STD Amount
1
25
1
2
502 HAL.MTH
502 PID.MTH
0
5
I Internal Standard Report
===-======-===========-=====-==-==--==-----------------------------------------
liata File Name
lperator
. ·rument
s ,ile Name t un Time Bar Code:
cquired on
Report Created on:
a,ast Recalib on
a,iultiplier
C:\HPCHEM\l\DATA\052196\024R0201.D
RNP Page Number
HALL/PID Vial Number
VSTD002 Injection Number
22·May 96
22 May 96
22 May 96
1
05:43
12:34
12:33
AM
PM
PM
Sequence Line
Instrument Method:
Analysis Method
Sample Amount
ISTD Amount
rig. 2 in C:\HPCHEM\l\DATA\052196\024R0201.D
1
24
1
2
502 HAL.MTH
502 PID.MTH
0
5
11-et Time Area Type Width Ref# µg/L Name
1-------1------------1----1-----1-----1--------1----------------------------1
. 3.553 23138 PV 0.091 1 2.266 (H) Vinyl chloride
I... 5.812 45604 PV 0.081 1 1.981 (H) 1,1-Dichloroethene
7.181 160730 BB 0.074 1 4.451 MTBE; (H) t-12DCE
7.994 55136 BV 0.088 l 1.862 DIPE
I 8.841 70810 PV 0.064 l 2.091 (H) c-12dce
9.855 55123 PV 0.062 1 1.978 (H) 11-Diclpropene
10.176 158520 PB 0.061 l 1.842 Benzene
I 10.595 546187 BV 0.059 1-I 5.000 * Fluorobenzene *
11.141 80464 W 0.055 1 1.987 (H) Trichloroethene
11.563 171515 BV 0.060 l 4.960 $ a,a,a-Trifluorotoluene $
I 12.547 22823 BV 0.049 1 1.938 (H) c-13pene
13.027 117170 BV 0.052 l 1.858 Toluene
13.367 22497 W 0.046 1 1.800 (H) t-13pene
I
I
I
I
I
13.834 47700 VB 0.051 1 1.800 (H) Tetrachloroethene
S.123 97332 BV 0.046 l 1.791 (H) Chlorobenzene
.o.272 92649 W 0.049 1 1.841 Ethylbenzene
15.447 245514 VB 0.050 1 4.070 m-Xylene; p-Xylene
16.064 183808 BV 0.060 1 3.712 a-Xylene; Styrene
16.604 58350 BV 0.051 1 1.786 Isopropylbenzene
17.087 79325 BV 0.046 1 1.784 (H) Bromobenzene
17.234 68625 W 0.049 l 1.722 n-Propylbenzene
17.378 93451 W 0.050 1 1.950 (H) 2Cltoluene
17.506 189498 W 0.075 1 3.527 135-Trimethylbenz (H) 4Cltol
18.005 53893 W 0.050 1 1.694 tert-Butylbenzene
18.082 99212 W 0.049 1 1.991 124-Trimethylbenzene
18.344 54034 W 0.053 1 1.621 sec-Butylbenzene
18. 541 122425 W o. 070 1 3. 317 p-Isopropyltoluene ; (H) 13dcb
18.671 70300 W 0.047 1 1.748 (H) 14dcb
19. 245 98849 W 0. 074 1 3. 223 n-Butylbenzene ; (H) 12dcb
21.767 27631 PV 0.045 1 1.381 (H) 124-Triclbenzene
22.026 28032 W 0.055 1 1.325 (H) Hexaclbutadiene
22.157 21070 W 0.046 1 1.195 Naphthalene
22.540 24342 PB 0.048 1 1.094 (H) 123Triclbenzene
I===============================================================================
I
I
I
0
m
[\)
0
m
w ~ m m ✓
0 0 0 0 0
m m m m m
[lJ
0
m
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
0 ,-'--'----"-'~~L..L....c-'-'--~f ~· -'-"-'-1.f~~~----'--'-~~----'--'-...Lf ~~----'-'-~
m
H) V,'¥ chlor<le l.55J
,150
,898
c:==--iH) 1,1-Mloroelbeee 5811
'" 0
'" m
[\)
0
[\)
lata File Jllme
Operator
~
nstrument :
ample Name :
· Time Bar Code:
' Jired on :
~eport Created on:
'last Recalib on :
Multiplier
I
.178
.715
i::========------<11B[: (H) 1-11DC[ 7.181
t===-OIP[ 7.99<
t====---/IH)c-11dce88•1
P===-----iH} lrichloroethene 11.141
\;::Au=======---------S o,o.o-lr~loorololuf.'ne S 11.563
l==---iH) c-lJper, 11.5'7
i~~~~~~~;:::::::---loluene 11027 l!sii>Joene 1JJ67
H) lelrochloroelhene 1183-4
J;:1=
6
.3=
80
=======------------.-Xyltne: 51yrene \6.064
F"""==------ls,opro~ben1f.'nt 16.&W
~ 17 O]J_
/i'5;~lhylbenz; (H) Kttol 17.506
124-TrYllt\lTf{benzffle 18.082
.fflcopylloh,,rre: (H) lldcb 18.5'1
~~====--n-Bulylbenzene: (H) 11dcb 19.245
10.06
l1i~,~~~:Zi%l!161
H) 1231riclbfn1tne-22.S.0
C:\HPCHEM\1\DATA\052196\024R0201.D
RNP Page Number
HALL/PID Vial Number
VSTD002 Injection Number
22
22
22
1
May
May
May
96
96
96
05:43
12:34
12:33
AM
PM
PM
Sequence Line
Instrument Method:
Analysis Method
Sample Amount
ISTD Amount
1
24
1
2
502 HAL.MTR
502 PID.MTH
0
5
---------------==----------------------
I Internal Standard Report ·
---------.-----==-=------------------------------------------------------------
tata File Name
perator
C:\HPCHEM\l\DATA\052196\023R0201.D
RNP Page Number
_. -:-ument HALL/PID Vial Number
Sc. .Le Name VSTDOOl Injection Number
lun-Time Bar Code:
cquired on 22
Report Created on: 22
l ast Recalib on 22
ultiplier 1
May 96
May 96
May 96
05:12
12:34
12:34
AM
PM
PM
Sequence Line
Instrument Method:
Analysis Method
Sample Amount
ISTD Amount
1
23
1
2
502 HAL.MTH
502 PID.MTH
0
5
~!~·Tfm!~_c,\~:;~EM\l~~~:~i~~~~:~~~!R~!~~LD---[-___________ Name _____________
1
3.548 11510 BV 0.079 1 1.072 (H) Vinyl chloride
5.809 25292 PV 0.081 1 1.413 (H) 1,1-Dichloroethene
7.179 87169 PV 0.073 1 2.326 MTBE; (H) t-12DCE I
7.991 28214 BV 0.084 1 0.760 DIPE
8.841 36817 PV 0.063 1 0.956 (H) c-12dce
9.856 36618 PV 0.062 1 1.373 (H) 11-Diclpropene I
10.176 96432 PV 0.060 1 0.968 Benzene
I 10.596 543601 PV 0.058 1-I 5.000 * Fluorobenzene *
11.143 49783 BV 0.055 1 1.272 (H) Trichloroethene
11.564 175086 PV 0.060 1 5.087 $ a,a,a-Trifluorotoluene $
1 12.550 12747 BV 0.050 1 0.906 (H) c-13pene
13.030 84492 PV 0.051 1 1.351 Toluene
13.372 12736 VV 0.047 1 0.852 (H) t-13pene
13.838 36353 PV 0.051 1 1.463 (H) Tetrachloroethene
·.128 68356 BV 0.046 l· 1.312 (H) Chlorobenzene
,.277 70785 VV 0.047 1 1.501 Ethylbenzene I
15.451 159700 VV 0.048 1 2.816 m-Xylene; p-Xylene
I 16.070 133065 PV 0.059 1 2.803 o-Xylene; Styrene
i6.608 50210 BV 0.051 1 1.640 Isopropylbenzene
17.093 55935 BV 0.046 1 1.310 (H) Bromobenzene
17.238 61359 VV 0.049 1 1.647 n-Propylbenzene I 17.384 65458 VV 0.047 1 1.461 (H) 2Cltoluene
17.511 153007 VV 0.069 1 3.064 135-Trimethylbenz (H) 4Cltol
18.010 50510 VV 0.051 1 1.652 tert-Butylbenzene
18.087 65851 VV 0.048 1 1.433 124-Trimethylbenzene
18.349 52169 VV 0.052 1 1.647 sec-Butylbenzene I
I
18. 549 103823 VV O. 070 1 3. 016 p-Isopropyltoluene ; (H) 13dcb
18.676 52963 VB 0.046 1 1.391 (H) 14dcb
19. 21 7 84241 PV O. 070 1 2. 979 n-Butylbenzene ; (H) 12dcb
21.772 23282 BV 0.047 1 1.300 (H) 124-Triclbenzene
I. 22.030 26139 VV 0.054 1 1.316 (H) Hexaclbutadiene
22.162 16738 VV 0.045 1 1.112 Naphthalene
22.545 18267 PB 0.047 1 0.959 (H) 123Triclbenzene
I
I
I
N w ~ m m ~
0 0 0 0 0 0
m m ro ro ro ro
CD
0
ffi
I
I
I
I
I
I
I
I
I
I
I
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I
I
I
+' +' +' +' 0 -r-~---'---r'-_,_____---'--'--'-'~c__L_-'---"--~..L.....--'----'-.........L--'---'-~--L.,-'-'~Lo._~_c_L_,_____~
m
f-'
0
f-'
m
N
0
N lata File r4Jl.me
Operator
~
nstrument :
ample Name :
· Time Bar Code :
t .ired on :
eport Created on:
ast Recalib on :
Multiplier
I
1.676
t:=====~---UTB[: (HI l-11DC[ l.179
c==-OIP[ 7.991
\==--{H) c-12ike 8.841
l===---ilH) lrichklroethefll' 11.143
t==========--------'S o.o.o-Trifluornlolueflt' S 11.5~
)5.118 -Xyler.e: p-Xylene 15.~51
l:======-=-------.-x,...: ~f'"' 16070
19.981
1.156
C:\HPCHEM\l\DATA\052196\023R0201.D
RNP Page Number
HALL/PID Vial Number
VSTD00l Injection Number
22
22
22
1
May
May
May
96
96
96
05:12
12:34
12:34
AM
PM
PM
Sequence Line
Instrument Method:
Analysis Method
Sample Amount
ISTD Amount
1
23
1
2
502 HAL.MTR
502 PID.MTH
0
5
I . Internal Standard Report
=---------==-=====-================---------------=----------------==------===
-
ata File Name
perator
rument
C:\HPCHEM\1\DATA\052196\026R0201.D
RNP Page Number
HALL/PID Vial Number
-:
~ ... ,;le Name VSTDOlO Injection Number
un Time Bar Code:
cquired on 22
Report Created on: 22
R,ast Recalib on : 22
aiultiplier : 1
May 96
May 96
May 96
06:45
12:35
12:35
AM
PM
PM
ll3ig. 2 in C:\HPCHEM\1\DATA\052196\026R0201.D
Sequence-Line
Instrument Method:
Analysis Method
Sample Amount
ISTD Amount
1
26
l
2
502 HAL.MTH
502 PID.MTH
0
5
~et Time Area Type Width Ref# µg/L Name
l-------1------------1----1-----1-----1--------1-----------------------------1
I
I
I
I
I
I
I
I
I
I
3.549 124067 PV 0.087 1 11.489 (H) Vinyl chloride
5.809 259415 PV 0.085 1 9.568 (H) 1,1-Dichloroethene
7.178 897092 VV 0.075 1 23.384 MTBE ; (H) t-12DCE
7.990 277803 VV 0.089 1 11.894 DIPE
8.840 355759 BV 0.064 1 11.192 (H) c-12dce
9.856 370475 PV 0.062 1 11.955 (H) 11-Diclpropene
10.176 820280 VV 0.061 1 11.260 Benzene
10.597 553299 VV 0.059 1-I 5.000 * Fluorobenzene *
11.144 511772 VV 0.055 1 11.828 (H) Trichloroethene
11.566 175108 VV 0.060 1 4.999 $ a,a,a-Trifluorotoluene $
12.552 127633 BV 0.049 1 12.188 (H) c-13pene.
13.032 760946 PV 0.051 1 11.715 Toluene
13.373 127762 VV 0.047 1 12.208 (H) t-13pene
13.840 397767 VV 0.052 1 12.879 (H) Tetrachloroethene
, .129 688579 BV O. 04 7 1 12. 042 (H) Chlorobenzene
. .:i.279 700837 VV 0.049 1 .12.066 Ethylbenzene
15.453 1602672 VV 0.050 1 24.456 m-Xylene; p-Xylene
16.071 1273624 VV 0.060 1 23.695 o-Xylene; Styrene
16.610 523339 VV 0.052 1 12.441 Isopropylbenzene
17.095 561878 VV 0.046 1 12.211 (H) Bromobenzene
17.241 641835 VV 0.049 1 12.673 n-Propylbenzene
17.386 661038 VV 0.048 1 12.435 (H) 2Cltoluene
17. 515 1585469 VV O. 075 1 25. 266 135-Trimethylbenz ; (H) 4Cltol
18.013 509265 VV 0.051 1 12.636 tert-Butylbenzene
18.090 693900 VV 0.049 1 12.670 124-Trimethylbenzene
18.352 555046 VV 0.053 1 12.990 sec-Butylbenzene
18. 552 1106684 VV o. 071 1 26. 032 p-Isopropyltoluene ; (H) 13dcb
18.679 578428 VV 0.046 1 13.225 (H) 14dcb
19. 220 938235 VV O. 074 1 26. 727 n-Butylbenzene ; (H) 12dcb
21.778 263152 PV 0.046 1 13.901 (H) 124-Triclbenzerie
22.036 279373 VV 0.053 1 14.981 (H) Hexaclbutadiene
22.168 181582 VV 0.047 1 12.264 Naphthalene
22.551 205663 VV 0.047 1 13.207 (H) 123Triclbenzene
•===============================================================================
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
0
()l
1--'
0
1--'
()l
10
0
i-'
0
lb
10
Lata File rJll.me
Operator
■~nstrument
a,;ample Name
P Time Bar Code: C Jired on :
report Created on:
Last Recalib on :
Multiplier I .
19.765
10.!90
<.661
10
0
lb
(;j
0
(i)
~
,, ,... ()l
0 0
(i) (i)
f
(j) ✓
0 0
(D (D
It" ' 'I' .
l o.o.o-lrilluorotoluene S 11.566
H) c-lJpen, 11.551
H) 1-1 Jpe,. 1 JJ)J
op
C:\HPCHEM\1\DATA\052196\026R0201.D
RNP Page Number
HALL/PID Vial Number
VSTD0l0 Injection Number
01
0
(D
f.
iclbenzl'ne 22.551
22. May 96
22 May 96
22 May 96
06:45
12:35
12:35
AM
PM
Sequence Line
Instrument Method:
1
26
1
2
502 HAL.MTH
502 PID.MTH
0 PM
1
Analysis Method
Sample Amount
ISTD Amount 5
'
. Internal Standard Report
=-=·------=======-=-=========-========------------=--=-------==---====-----===
Jta File Name
erator
,ument
C:\HPCHEM\l\DATA\052196\027R0201.D
RNP Page Number
HALL/PID Vial Number
t le Name VSTD025 Injection Number
n Time Bar Code:
cquired on 22
Report Created on: 22
last Recalib on
lultiplier
May-96
May 96
22 May 96
1
07:16
12:36
12:36
AM
PM
PM
Sequence Line
Instrument Method:
Analysis Method
Sample Amount
ISTD Amount
1
27
1
2
51)2 HAL.MTH
502 PID .1",TI!
0
5
~!~·Tfm!~_c,\::;~EM\l~~~:~i~~~~~~~~;R~~~~LD ___
1
____________ Name _____________
1
I 3.555 378205 PV 0.093 1 25.392 (H) Vinyl chloride
5.807 770385 BV 0.087 1 25.349 (H) 1,1-Dichloroethene
7.176 2612624 PV 0.074 1 50.608 MTBE; (H) t-12DCE
7.989 896279 VV 0.087 1 25.513 DIPE
I 8.839 1109231 PV 0.063 1 25.453 (H) c-12dce
9.855 988996 PV 0.062 1 25.118 (H) 11-Diclpropene
10.175 2478203 VV 0.061 1 25.413 Benzene
1 10.596 570923 VV 0.060 1-I 5.000 * Fluorobenzene *
11.143 1438696 VV 0.055 1 25.233 (H) Trichloroethene
11.565 181957 VV 0.061 1 5.034 $ a,a,a-Trifluorotoluene $
I 12.551 405123 BV 0.049 1 25.478 (H) c-13pene
13.031 2132807 VV 0.051 1 25.243 Toluene
13.371 407293 VV 0.046 1 25.482 (H) t-13pene
13.839 992266 VV 0.052 1 24.944 (H) Tetrachloroethene
I .128 1937733 BV 0.047 1 25.234 (H) Chlorobenzene
,.278 1833605 VV 0.049 1 25.079 Ethylbenzene
15.453 4144091 VV 0.050 1 50.138 m-Xylene ; p-Xylene
I 16.069 3162688 VV 0.060 1 49.905 o-Xylene; Styrene
16.609 1300929 VV 0.052 1 24.948 Isopropylbenzene
17.094 1606924 VV 0.046 1 25.273 (H) Bromobenzene
I 17.240 1558415 VV 0.049 1 24.892 n-Propylbenzene
17.385 1721447 VV 0.047 1 25.082 (H) 2Cltoluene
17. 513 4020683 VV 0. 075 1 50. 008 135-Trimethylbenz ; (H) 4Cltol
18.011 1243722 VV 0.051 1 24.907 tert-Butylbenzene
I 18.088 1772727 VV 0.048 1 25.042 124-Trimethylbenzene
18.350 1307363 VV 0.053 1 24.811 sec-Butylbenzene
18.549 2789496 VV 0.070 1 49.965 p-Isopropyltoluene ; (H) 13dcb
I 18.677 1492739 VV 0.045 1 25.040 (H) 14dcb
19. 219 2343216 VV 0. 076 1 49. 913 n-Butylbenzene ; (H) 12dcb
21.776 715026 BV 0.046 1 25.171 (H) 124-Triclbenzene
I 22.034 665644 VV 0.053 1 24.854 (H) Hexaclbutadiene
22.166 560575 VV 0.047 1 25.429 Naphthalene
22.549 599947 VV 0.049 1 25.320 (H) 123Triclbenzene
I==============-==-==--==-=--=-=================================================
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
0
(JI
I-"
(JI
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0
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5.310
l\6!
21651
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(,,J
0
ro
if'
if' (JI (j) ✓
0 0 0 0
ro m ro 0
,I:. I
o.o.o-lrifl11orotoluene S 11.565
lnata File
[\)
J&me C:\HPCHEM\1\DATA\052196\027R0201.D
Operator RNP Page Number
•
Instrument : HALL/PID Vial Number
Sample Name : VSTD025 Injection Number
R· · Time Bar Code:
l iired on : 22
•Report Created on: 22
Last Recalib on : 22
Multiplier 1
I
May 96
May 96
May 96
AM 07:16
12:36 PM
12:36 PM
Sequence Line
Instrument Method:
Analysis Method
Sample Amount
!STD Amount
(lJ
0
ro
1
27
1
2
502 HAL.MTH
502 PID.MTH
0
5
f ================= =======================-==-==-=======~----
-

-
..
. Calibration Report
1-a File Name
,--.or
n, c1ment t ple Name
Time Bar Code:
,cquired on
C:\HPCHEM\l\DATA\052196\023F0201.D
RNP Page Number
HALL/PID Vial Number
VSTD00l Injection Number
Sequence Line
Instrument Method:
l
23
l
2
22 May 96
May 96
May 96
'
port Created on: 22
st Recalib on : 22
05:12
11:58
11:57
AM
AM
AM
Analysis Method
Sample Amount
ISTD Amount
502 HAL.MTH
502 HAL.MTH
0
·!ultiplier
I
I
I
2
I 3
I
4
I
I 5
I
6
I
I 7
I
8
I
I 9
I
RT
3.070
3.384
3.577
4.195
4.365
4.840
5.832
6.740
7.206
Lvl
l
2
3
4
5
l
2
3
4
5
l
2
3
4
5
l
2
3
4
5
l
2
3
4
5
l
2
3
4
5
l
2
3
4
5
l
2
3
4
5
l
2
3
4
l
µg/L
1.0
2.0
5.0
10.0
25.0
1.0
2.0
5.0
10.0
25.0
1.0
2.0
5.0
10.0
25.0
1.0
2.0
5.0
10.0
25.0
1.0
2.0
5.0
10.0
25.0
l. 0
2.0
5.0
10.0
25.0
1.0
2.0
5.0
10.0
25.0
1.0
2.0
5.0
10.0
25.0
1.0
2.0
5.0
10.0
5
Calibration Table
Amt/Area
6.528e-006
8.0l77e-006
l.0492e-005
8.8983e-006
8.5664e-006
6.6476e-006
7.6809e-006
9.1543e-006
Ref Istd I# Name
8.349e-006
7. 0l94e-006
3.3373e-006
3.7034e-006
4.3645e-006
3.8559e-006
3.4538e-006
3.5987e-00S
3.4972e-00S
2.927le-005
l.5703e-005
l.0l65e-005
4.6775e-006
4.632le-006
S.6112e-006
4.8128e-006
4.2114e-006
2.2298e-006
2.6594e-006
3.163e-006
2.454le-006
2.3848e-006
2.470Be-006
2.7502e-006
3.1716e-006
2.5489e-006
2.5103e-006
2.0059e-006
2.3044e-006
2.656e-006
2.7387e-006
2.363le-006
2.240le-006
2.4013e-006
2.6777e-006
2.4007e-006
l Dichlorodifluorometh ...
l Chloromethane
l Vinyl chloride
l Bromomethane
l Chloroethane
l Trichlorofluorometha ...
l 1,1-Dichloroethene
l Methylene chloride
l t-1,2-Dichloroethene
I 'i 25. o 2.2607e-006
May 9f 11:58 AM page 2
=thod: C:\HPCHEM\l\METHODS\502 HAL.MTH
110 7.917 1 1.0 2.3586e-006 1 1,1-Dichloroethane
2 2.0 2.3124e-006
3 5.0 2.5295e-006
I 4 10.0 2.3702e-006
5 25.0 2.1297e-006
11 8.857 1 2.0 2.9282e-006 1 c-12Diclethene 22D ...
I 2 4.0 3.0887e-006
3 10.0 3.5401e-006
4 20.0 3.3636e-006
112 5 50.0 2.9136e-006
9.241 1 1. 0 7.B258e-006 1 Brornochlorornethane
2 2.0 6.9739e-006
3 5.0 6.5112e-006
I 4 10.0 5.9206e-006
5 25.0 4.6418e-006
13 9.371 1 1.0 l.786le-006 1 Chloroform
I 2 2.0 l.8874e-006
3 5.0 2.1279e-006
4 10.0 2.1417e-006
I 5 25.0 l.8166e-006
14 9.626 1 1.0 l.8184e-006 1 1,1,1-Trichloroethan ...
2 2.0 2.0486e-006
3 5.0 2.3875e-006
I 4 10.0 2.074e-006
5 25.0 l.9362e-006
15 9.875 1 2.0 l.9898e-006 1 Carbon Tetracl 22D ...
I 2 4.0 2.5659e-006
3 10.0 3.0463e-006
4 20.0 2.2752e-006
I 5 50.0 2.2315e-006
16 10.241 1 1.0 3.9546e-006 1 1,2-Dichloroethane
2 2.0 4.1809e-006
3 5.0 4.1918e-006
I 4 10.0 4.0959e-006
5 25.0 3.67le-006
17 11.164 1 1.0 l.8523e-006 1 Trichloroethene
I 2 2.0 2.502le-006
3 5.0 2.790le-006
4 10.0 2.257le-006
I 5 25.0 2.0499e-006
18 11.501 1 1. 0 2.1769e-006 1 1,2-Dichloropropane
2 2.0 2.7446e-006
I
3 5.0 3.2904e-006
4 10.0 3.146le-006
5 25.0 2.9719e-006
19 11. 705 1 1.0 l.1953e-005 1 Dibrornornethane
I 2 2.0 1.234le-005
3 5.0 l.1906e-005
4 10.0 l.0315e-005
I 5 25.0 8.3906e-006
20 ll.928 l 1.0 3.439e-006 1 Brornodichlorornethane
2 2.0 4 .14le-006
I 3 5.0 4.045e-006
4 10.0 3.666e-006
5 25.0 3.1068e-006
21 12.570 1 1.0 4.073le-006 1 c-1,3-Dichloropropen ...
I 2 2.0 4.994e-006
3 5.0 4.8953e-006
4 10. 0 4.3348e-006 12 May 96 11:58 AM page 3
ethcd: C:\HPCHEM\l\METHODS\502 HAL.MTH
I 5 25.0 3.6522e-006
~"2 13.392 1 l. 0 6.99lle-006 1 t-1,3-Dichloropropen ...
2 2.0 7.9742e-006
I 3 5.0 8.0266e-006
4 10.0 7.1095e-006
5 25.0 5.9313e-006
I 23 13.535 1 5.0 2.9052e-006 ISTD 1 * ~romochloropropane ...
2 5.0 2.918le-006
3 5.0 2.8483e-006
I
4 5.0 2.7512e-006
5 5.0 2.5503e-006
6 5.0 l.3509e-006
24 13.661 1 1.0 3.042le-006 1 1,1,2-Trichloroethan ...
I 2 2.0 3.8458e-006
3 5.0 4.7418e-006
4 10.0 5.005le-006
I 5 25.0 4.5383e-006
25 13.857 1 2.0 2.4927e-006 1 Tetraclethane 13Di. ..
2 4.0 3.6115e-006
I
3 10.0 4.1758e-006
4 20.0 3.0693e-006
5 50.0 3.1016e-006
26 14.269 1 1. 0 9.7482e-006 1 Dibromochloromethane
I 2 2.0 9.5045e-006
3 5.0 8.6893e-006
4 10.0 7.3746e-006
I 5 25.0 6.1366e-006
14.441 1 1.0 l.1118e-00S 1 1,2-Dibromoethane (E ...
2 2.0 l.1433e-005
I 3 5.0 l.1827e-005
4 10.0 9.7287e-006
5 25.0 8.1022e-006
28 15.147 1 1. 0 5.9534e-006 1 Chlorobenzene
I 2 2.0 8.836le-006
3 5.0 9.6437e-006
4 10.0 6.4894e-006
I 5 25.0 6.0487e-006
29 15.273 1 1.0 2.2993e-006 1 1,1,1,2-Tetrachloroe ...
2 2.0 2.7412e-006
I 3 5.0 2.9803e-006
4 10.0 2.5012e-006
5 25.0 2.2B12e-006
30 16.436 1 1.0 4.4377e-005 1 Bromoform
I 2 2.0 3.6034e-005
3 5.0 2.4369e-005
4 10.0 l.B656e-005
I 5 25.0 l.1B63e-005
31 16.803 6 5.0 3.6852e-006 1 $ 1,4-Dichlorobutane ...
32 17.122 1 l. 0 7.3114e-006 1 1,1,2,2-Tetrachloroe ...
I 2 2.0 7.9986e-006
3 5.0 8.1094e-006
4 10.0 6.1182e-006
5 25.0 5.1502e-006
I 33 17.175 1 2.0 l.B433e-005 1 Bromobenzene 123tr .. ·.
2 4.0 2.3564e-005
3 10.0 2.4246e-005
I 4 20.0 2.46lle-005
5 so.a 2.0552e-005
34 17.403 1 1.0 5.6713e-006
I May 9G 11:58 AM
_thoc: C:\HPCHEM\l\METHODS\502 HAL.MTR
.1 L.-\..,J.J..LU.l..u-..u,.1.. ..... '-••-
page 4
I 2 2.0 9.1196e-006
3 5.0 l.0859e-005
4 10.0 6.143e-006
135 5 25.0 6.347le-006
17.570 1 1.0 5.560le-006 1 4-Chlorotoluene
2 2.0 9.5886e-006
I 3 5.0 1. 2288e-005
4 10.0 5.818e-006
5 25.0 6.169le-006
136 18.558 1 1. 0 4.7065e-006
2 2.0 7.8828e-006
3 5.0 9.1143e-006
1 1,3-Dichlorobenzene
4 10.0 4.9325e-006
I 3-7
5 25.0 4.8934e-006
18.696 1 1.0 4.1463e-006 1 1,4-Dichlorobenzene
2 2.0 6.9809e-006
I 3 5.0 7.8628e-006
4 10.0 4.0975e-006
5 25.0 4.3176e-006
I 38 19.279 1 1.0 5.3869e-006
2 2.0 8.3916e-006
3 5.0 9.597e-006
1 1,2-Dichlorobenzene
4 10.0 5.485le-006
I 5 25.0 5:5258e-006
39 20.517 1 1.0 5.5363e-005 1 1,2-Dibromo-3-chloro ...
2 2.0 l.0408e-004
I 3 5.0 8.6382e-005
4 10.0 7.1538e-005
5 25.0 4.415e-005
I 40 21.793 1 1.0 5.5402e-006
2 2.0 9.1959e-006
3 5.0 l. l 745e-005
1 1,2,4-Trichlorobenze ...
4 10.0 5.5356e-006
I 5 25.0 5.5225e-006
41 22.053 1 1.0 2.6275e-006 1 Hexachlorobutadiene
2 2.0 5.117le-006
~ 3 5.0 6.1329e-006
4 10.0 2.9053e-006
5 25.0 3.1482e-006
I ! 42 22.567 1 1.0 6.7338e-006
2 2.0 l.0188e-005
3 5.0 l.3627e-005
1 1,2,3-Trichlorobenze ...
4 10.0 6.0226e-006
I 5 25.0 5.6696e-006
Calibration Settings
llitle:
BG21 HALL 5mL
(teference window: 5.000 %
· -reference window: 5.000 % If .s of amount: µg/L
ultiplier: 1.0
F uncal peaks: 0.0
ISTD# to adjust uncal peaks: 0
.Sample Amount: 0.0
I May 96 11:58 AM
thc::1: C:\HPCHEM\l\METHODS\502_HAL.MTH
I
I
I
I
I
I
I
I
I
1.
I
I
I
I
I
I
I
I
I#
1
Amount
5.0
Fit: Linear
Origin: Force
Sample ISTD Information
Multilevel Information·
page 5
( -=--=--~~ternal Standard Report
-==· ===========================================================================
l;ta File Name C:\HPCHEM\l\DATA\052196\026F0201.D
. · ~a tor RNP Page Number 1
I rument HALL/PID Vial Number 26
,a,11ple Name VSTDOlO Injection Number 1
un Time Bar Code: Sequence Line 2
Acquired on 22 May 96 06:45 AM Instrument Method: 502 HAL.MTH
leport Created on: 22 May 96 11:51 AM Analysis Method 502 HAL.MTH
ast Recalib on : 22 May 96 11:51 AM Sample Amount 0
ultiplier : 1 ISTD Amount 5
ll,ig. 1 in C:\HPCHEM\l\DATA\052196\026F0201.D
~et Time Area Type Width Ref# µg/L Name
l-------l------------l----l-----l-----1--------1------------------------------I
I 3.054 · 1123806 VV 0.094 1 11.506 Dichlorodifluoromethane
3.372 1197751 VV 0.082 1 20.097 Chloromethane
3.570 2593420 VV 0.109 1 17.330 Vinyl chloride
I 4.177 636807 VV 0.078 1 12.902 Bromomethane
4.362 2077793 VV 0.112 1 17.705 Chloroethane
4.837 4074774 VV 0.103 1 19.520 Trichlorofluoromethane
5.829 3923185 VV 0.101 1 11.114 1,1-Dichloroethene
I 6.733 3651346 VV 0.085 1 11.821 Methylene chloride
7.200 4165411 VV 0.079 1 11.692 t-1,2-Dichloroethene
7.922 4219063 VV 0.089 1 11.785 1,1-Dichloroethane
I 8.853 5945964 VV 0.076 1 22.995 c-12Diclethene; 22Diclpropane
9.240 1689022 VV 0.059 1 11.494 Bromochloromethane
9.371 4669121 VV 0.060 1 11.373 Chloroform
I 9.629 4821626 VV 0.070 1 11.175 1,1,1-Trichloroethane
,.872 8790555 VV 0.075 1 25.195 Carbon Tetracl; 22Diclpropane
i0.239 2441495 VV 0.074 1 12.579 1,2-Dichloroethane
11.166 4430438 VV 0.052 1 10.759 Trichloroethene
I 11.502 3178582 VV 0.062 1 11.819 1,2-Dichloropropane
11.695 969420 VV 0.054 1 10.935 Dibromomethane
11.925 2727774 VV 0.060 1 12.588 Bromodichloromethane
I 12.570 2306916 VV 0.056 1 13.053 c-1,3-Dichloropropene
13.391 1406572 VV 0.053 1 11.975 t-1,3-Dichloropropene
13.535 1817370 VV 0.065 1-I 5.000 * Bromochloropropane *
I 13.667 1997978 VV 0.062 1 12.505 1,1,2-Trichloroethane
13.859 6516049 VV 0.068 1 26.577 Tetraclethane; 13Diclpropane
14.261 1356011 VV 0.054 1 12.159 Dibromochloromethane
14.430 1027890 VV 0.065 1 14.147 1,2-Dibromoethane (EDB) I 15.147 1540984 VV 0.047 1 11.953 Chlorobenzene
15.274 3998098 VV 0.063 1 12.261 1,1,1,2-Tetrachloroethane
16. 412 ·536019 VV O. 057 1 11. 568 Bromoform
I 16.806 638450 VV 0.056 1 4.792 $ 1,4-Dichlorobutane $
17.117 1634469 VV 0.048 1 17.795 1,1,2,2-Tetrachloroethane
17.175 812655 vv 0.052 1 15.676 Bromobenzene; 123triclpropane
I 17.405 1627859 VV 0.056 1 12.793 2-Chlorotoluene
17.571 1718802 VV 0.054 1 13.353 4-Chlorotoluene ·
18.559 2027356 VV 0.052 1 12.188 1,3-Dichlorobenzene
18.697 2440542 VV 0.052 1 14.246 1,4-Dichlorobenzene I 19.280 1823132 vv 0.055 1 13.350 1,2-Dichlorobenzene
~o.516 139785 vv 0.062 1 10.624 1,2-Dibromo-3-chloropropane
L.796 1806491 vv 0.052 1 13.885 1,2,4-Trichlorobenzene
I 22.056 3441981 VV 0.064 1 14.340 Hexachlorobutadiene
22.569 1660406 vv 0.059 1 14.122 1,2,3-Trichlorobenzene
I============================-===================--=============================
I
I
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I
I
I
I
I
I
I
I
I
I
I
0
(Jl
I-'
(Jl
[\)
0
I Data File imme
Operator
I Instrument
Sample Name
f Time Bar Code:
1 h • .iired on :
Report Created on:
Last Recalib on :
1 Multiplier
[\) if' (l) OJ I-'
0 0 0 0 0
ffi ffi ffi ro ffi
Q1 Ql
. hlorodilluorOfflf!hone 1054
h romelhane 1 7 chloride 1570
'1 roethone 062
richlo1oflooromethone 4.8}7
t-;::::==========------+"H<": hlmoelhene 5.829
trylt>ne chloride 6.733
Oictiloroelhene 7.200
l':::==============-->:+-,,;,,.,,,.1hone 7.922
I-'
[\) -~
ffi ro
(l)
. SJ
richloroelhone . ~sofmm 9.Jlf
· hlorot>lhone 10.239
1.2-0ictdoropropone 11.502
romome ne romodichloromethone 11.925
f-:;:c======-----------<-1.3-0ictiloropropene 12.570
b==--omolorm 16.H2
1.4-0<hlc,obufone I 16 806
18.088
"' ,?1W~ochloroethone 17.117
• "' S1!1,e6e'Gb11
l!lllo\ll,l;,'I,, 18.697
b===----------J+-l);c·: hloobenzeoe 19.180
19.671
I J-Oib1omo-J-chlorop1opo,e 20.516
~~~~~~;:;;;:;;::;;;:::;;;;;;;;;;;;;;:=::::!:::!!!frics!!hl!!;o<0~b~en!!.,en~e.ll~f.l'2!96~__.., r ochloiobutodiene 22.056
r;o===--------+1+ Trichlorobenzene 22.569
C:\HPCHEM\l\DATA\052196\026F0201.D
RNP Page Number
HALL/PID Vial Number
VSTD0l0 Injection Number
22
22
22
1
May
May
May
96
96
96
06:45
11:51
11:51
AM
AM
AM
Sequence Line
Instrument Method:
Analysis Method
Sample Amount.
ISTD Amount
1
26
1
2
.166
502 HAL.MTH
502 HAL.MTH
0
5
-----------------------1-. Inter;;l St;;d;;d Report
================--==============-=---==-=-=--=----==========================--
11;ata File Name C:\HPCHEM\l\DATA\052196\027F0201.D
r-1"."ator RNP Page Number 1
I .rument HALL/PID Vial Number 27
~ample Name VSTD025 Injection Number 1
un Time Bar Code: Seguence Line 2
cquired on 22 May 96 07:16 AM Instrument Method: 502 HAL.MTH
leport Created on: 22 May 96 11:52 AM Analysis Method 502 HAL.MTH
ast Recalib on : 22 May 96 11:52 AM Sample Amount 0
ultiplier : 1 ISTD Amount 5
9,ig. 1 in C:\HPCHEM\l\DATA\052196\027F0201.D
la<.et Time Area Type Width Ref# µg/L Name
l-------l------------l----l-----l-----1--------1------------------------------I
I 3.059 2918362 PV 0.098 1 24.872 Dichlorodifluoromethane
3.381 3561576 VV 0.084 1 25.203 Chloromethane
I
I
I
I
I
I
••
I
I
I
I
I
3.577 7238341 VV 0.110 1 25.053 Vinyl chloride
4.172 2459463 VV 0.106 1 25.696 Bromomethane
4.356 5936319 VV 0.121 1 25.115 Chloroethane
4.836 l.0483E+007 VV 0.099 1 24.859 Trichlorofluoromethane
5.825 9958925 VV 0.087 1 ~4.837 1,1-Dichloroethene
6.731 l.05791E+007 VV 0.081 1 25.213 Methylene chloride
7.194 l.10586E+007 VV 0.085 1 24.970 t-1,2-Dichloroethene
7.908 l.17385E+007 VV 0.089 1 25.107 1,1-Dichloroethane
8.853 l.71607E+007 VV 0.071 1 50.409 c-12Diclethene; 22Diclpropane
9.238 5385791 VV 0.060 1 25.377 Bromochloromethane
9.369 l.37622E+007 VV 0.065 1 25.257 Chloroform
9.625 l.29121E+007 VV 0.075 1 25.025 1,1,1-Trichloroethane
.873 2.24065E+007 VV 0.069 1 49.770 Carbon Tetracl; 22Diclpropane
L0.239 6810147 VV 0.062 1 25.087 1,2-Dichloroethane
11.162 l.21957E+007 VV 0.057 1 25.110 Trichloroethene
11.501 8412133 VV 0.073 1 24.997 1,2-Dichloropropane
11.691 2979509 VV 0.064 1 25.282 Dibromomethane
11.922 8046786 VV 0.064 1 25.218 Bromodichloromethane
12.569 6845173 vv 0.058 1 25.234 c-1,3-Dichloropropene
13.390 4214925 VV 0.050 1 25.263 t-1,3-Dichloropropene
13.534 1960527 VV 0.060 1-I 5.000 * Bromochloropropane *
13.668 5508639 VV 0.053 1 25.153 1,1,2-Trichloroethane
13.859 l.61208E+007 VV 0.083 1 49.657 Tetraclethane; 13Diclpropane
14.260 4073916 VV 0.052 1 25.260 Dibromochloromethane
14.425 3085588 VV 0.068 1 25.228 1,2-Dibromoethane (EDB)
15.147 4133144 VV 0.048 1 25.012 Chlorobenzene
15.271 l.0959E+007 VV 0.063 1 25.117 1,1,1,2-Tetrachloroethane
16.408 2107479 VV 0.058 1 25.745 Bromoform
16.805 774500 VF 0.058 1 5.388 $ 1,4-Dichlorobutane $
17.113 4854193 MF 0.049 1 25.293 1,1,2,2-Tetrachloroethane
17.183 2432837 FM 0.054 1 50.435 Bromobenzene; 123triclpropane
17.403 3938836 FV 0.052 1 24.739 2-Chlorotoluene
17.571 4052473 VV 0.056 1 24.655 4-Chlorotoluene
18.558 5108925 VV 0.048 1 24.863 1,3-Dichlorobenzene
18.695 5790240 vv 0.055 1 24.694 1,4-Dichlorobenzene
19.280 4524213 VV 0.054 1 24.803 1,2-Dichlorobenzene
~o.513 566251 vv 0.101 1 25.735 1,2-Dibromo-3-chloropropane
_.795 4526909 vv 0.052 1 24.834 1,2,4-Trichlorobenzene
22.052 7941146 vv 0.065 1 24.660 Hexachlorobutadiene
22.568 4409513 vv 0.059 1 24.987 1,2,3-Trichlorobenzene
I User Modified
'
-ta File Name
erator .
strument
Sample Name
C:\HPCHEM\l\DATA\052196\027F0201.D
RNP Page Number
HALL/PID Vial Number
t n Time Bar Code:
VSTD025 Injection Number
,.. .. ired on 22
~ :t Created on: 22
■ast Recalib on 22
■ultiplier 1
May 96
May 96
May 96
07:16
11:52
11:52
AM
AM
AM
Sequence Line
Instrument Method:
Analysis Method
Sample Amount
ISTD Amount
2
27
1
2
502 HAL.MTH
502 HAL.MTH
0
5
1======= .=============--===================================--==--==-=--====--==
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I
I
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· "hloromethone 1381
. m" ( 17? :hlo10l"thone 056
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1omome ne 11.
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... lluui 14.'tLJ
~romoiorm 16.408
t 1.4-0ichlorobulone S 16.805
. "
l 1-Dibromo-3-chlo1opropone 20.51 J
C:\HPCHEM\1\DATA\052196\027F0201.D
RNP Page Number
HALL/PID Vial Number
..
f-'
l\l
(D
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-_577
..
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-
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. -
..
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VSTD025 Injection Number
F Time Bar Code:
11\.~~uired on : 22
!l<eport Created on: 22
May 96
May 96
May 96
07:16
11:53
11:52
AM
AM
AM
Sequence Line
Instrument Method:
Analysis Method
Sample Amount
ISTD Amount Last Recalib on 22
rultiplier 1
.
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502 HAL.MTH
502 HAL.MTH
0
5
'
=====-=-====-------=-=-------=-=========================================-=====
Internal Standard Report
-================-==-===================-==-==---=-==-=---------=--=-=---=-==--
:1ata File Name
r -ator
C:\HPCHEM\1\DATA\052196\025F0201.D
RNP Page Number 1
25
1
2
1 .rument HALL/PID Vial Number
l ample Name
un Time Bar Code:
VSTD005 Injectio~ Number
Sequence Line
Instrument Method: Acquired on 22 May 96
May 96
May 96
06:14
11:53
11:53
AM 502 HAL.MTH
502-HAL.MTH
0
(
eport Created on: 22
ast Recalib on : 22
ultiplier : 1
AM
AM
Analysis Method
Sample Amount
ISTD Amount 5
.ig. 1 in C:\HPCHEM\1\DATA\052196\025F0201.D
"-et Time Area Type Width Ref# µg/L Name
l-------!------------l----l-----l-----l--------1------------------------------1
I 3.069 476574 PV 0.097 1 4.729 Dichlorodifluoromethane
3.390 546190 VV 0.079 1 5.069 Chloromethane
••
I
I
I
I
I
I
I
I
I
I
I
3.586 1145603 VV 0.116 1 5.037 Vinyl chloride
4.188 170819 VV 0.075 1 3.775 Bromomethane
4.367 891077 VV 0.100 1 4.887 Chloroethane
4.838 1580762 VV 0.105 1 4.698 Trichlorofluoromethane
5.833 1576508 BV 0.093 1 4.420 1,1-Dichloroethene
6.733 1882553 PV 0.092 1 5.094 Methylene chloride
7.197 1867248 VV 0.086 1 4.824 t-1,2-Dichloroethene
7.913 1976661 VV 0.090 1 4.860 1,1-Dichloroethane
8.853 2824787 VV 0.07_7 1 9.635 c-12Diclethene ; 22Diclpropane
9.240 767911 VV 0.057 1 4.728 Bromochloromethane
9.368 2349747 VV 0.068 1 4.946 Chloroform
9.621 2094199 VV 0.083 1 4.540 1,1,1-Trichloroethane
1 .872 3282643 VV 0.076 1 8.390 Carbon Tetracl; 22Diclpropane
~0.238 1192818 VV 0.070 1 5.107 1,2-Dichloroethane
11.162 1792081 VV 0.058 1 4.193 Trichloroethene
11.501 1519583 VV 0.069 1 4.941 1,2-Dichloropropane
11.697 419957 VV 0.055 1 4.671 Dibromomethane
11.924 1236079 VV 0.067 1 4.796 Bromodichloromethane
12.568 1021393 VV 0.056 1 4.670 c-1,3-Dichloropropene
13.389 622931 VV 0.047 1 4.591 t-1,3-Dichloropropene
13.533 1755410 VV 0.055 1-I 5.000 * Bromochloropropane *
13.666 1054456 VV 0.055 1 5.042 1,1,2-Trichloroethane
13.856 2394766 VV 0.074 1 7.987 Tetraclethane; 13Diclpropane
14.262 575417 VV 0.054 1 4.519 Dibromochloromethane
14.431 422750 VV 0.067 1 4.637 1,2-Dibromoethane (EDB)
15.145 518474 VV 0.047 1 3.786 Chlorobenzene
15.268 1677696 VV 0.064 1 4.397 1,1,1,2-Tetrachloroethane
16.413 ·205175 BV 0.050 1 4.255 Bromoform
16.803 631119 VV 0.052 1 4.904 $ 1,4-Dichlorobutane $
17.116 616565 VV 0.046 1 4.081 1,1,2,2-Tetrachloroethane
17.173 412440 VV 0.048 1 9.810 Bromobenzene; 123triclpropane
17.402 460460 VV 0.051 1 3.310 2-Chlorotoluene
17.568 406906 VV 0.047 1 2.999 4-Chlorotoluene
18.556 548591 PV 0.046 1 3.136 1,3-Dichlorobenzene
18.6~4 635903 VV 0.053 1 3.169 1,4-Dichlorobenzene
19.277 520995 VV 0.051 1 3.395 1,2-Dichlorobenzene
'0.507 57882 PV 0.063 1 4.568 l,2-Dibromo-3-chloropropane
~.794 425707 VV 0.050 1 2.814 1,2,4-Trichlorobenzene
22.050 815269 VV 0.065 1 2.585 Hexachlorobutadiene
22.568 366931 VV 0.055 1 2.819 1,2,3-Trichlorobenzene
I================================================-======================
=
=
=
=
=
=
=
=

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Lata File lme
Operator
■Instrument
Bsample Name
r Time Bar Code:
p-~~ired on :
■Report Created on:
Last Recalib on :
.Multiplier
{\) .[, (j)
0 0 0
ro ro ro
(Ji
l,l,M,,. 061
t;:::===---Trichb'olluoro~lhone 4.838
l:::=====--1.1-D<hlo,oehen< 5.8JJ
r::======---1-,. chklrHJe 6.JJJ
r:::====---++· .2-D<hklroelhene 7.197
r::======---+,!-D<hloroelhooe 7.91]
D<hloroelm 1 D.2JB
(!I
0
ro
(Ji
1 romome hane
richloroe!hef'lt' 11.\62
.2-Dichloropropone 11.501
modichlorometncne 11.924
l==-----e-1.3-Dichloropropene 12.568
f';:====!;himi'°"":t111-l.5..UIL-+.+,, ,1)-Telroihklroelhone 15.268
18.086
D<hlrxobulone I 16.BOJ
,;~IIJT6
saaa::==i~l~!11!!'1~\6
b=----1.2-Dichlorobtnzene 19.277
11-Dibiomo-)-chloroprGPCJl'lf 20.507
~;;::;::;;;;;;:::1:1.2:!.,'-:ll~•~i1,,~~11!oso
t=--11.3-lrichlorobenltnt 22.568
'-' f..l
0 {\)
ro ro
Q)
lelrocl : 22Diclpropane 9.872
C:\HPCHEM\l\DATA\052196\025F0201.D
RNP Page Number
HALL/PID Vial Number
VSTD005 Injection Number
22
22
22
1
May
May
May
96
96
96
06:14
11:53
11:53
AM
AM
AM
Sequence Line
Instrument Method:
Analysis Method
Sample Amount
ISTD Amount
1
25
1
2
f..l
" ,..
ro
Q)
502 HAL.MTH
502 HAL.MTH
0
5
l . -----~~~ernal Standard Report -=----
----------------------------------,-------------------------------------------
lii>ata File Name
1::ir-~ator
C:\HPCHEM\l\DATA\052196\024F0201.D
RNP Page Number 1
24
1
2
I. rument
ll'ample Name
If-Un Time Bar Code:
HALL/PID Vial Number
VSTD002 Injection Number
Sequence Line
Instrument Method: Acquired on 22 May 96
May 96
May 96
05:43 AM 502 HAL.MTH
502 HAL.MTH
0
'
eport Created on: 22
ast Recalib on : 22
ultiplier : 1
11:57 AM
11:57 AM
Analysis Method
Sample Amount
ISTD Amount 5
11:,ig. 1 in C:\HPCHEM\l\DATA\052196\024F0201.D
~et Time Area Type Width Ref# µg/L Name
l-------l------------l----l-----l-----1--------1------------------------------I
I 3.065 249448 BV 0.093 1 2.417 Dichlorodifluoromethane
3.385 260386 VV 0.089 1 2.591 Chloromethane
I
I
I
I
I
I
I
I
I
I
I
I
3.575 540037 VV 0.108 1 2.477 Vinyl chloride
4.220 57189 VV 0.091 1 2.612 Bromomethane
4.361 431765 VV 0.112 1 2.533 Chloroethane
4.843 752048 VV 0.103 1 2.312 Trichlorofluoromethane
5.833 727217 VB 0.092 1 2.108 1,1-Dichloroethene
6.736 867913 BV 0.079 1 2.361 Methylene chloride
7.203 832879 VV 0.075 1 2.197 t-1,2-Dichloroethene
7.917 864884 VV 0.085 1 2.224 1,1-Dichloroethane
8.857 1295028 BV 0.083 1 4.665 c-12Diclethene; 22Diclpropane
9.240 286783 VV 0.063 1 2.317 Bromochloromethane
9.369 1059647 VV 0.074 1 2.333 Chloroform
q.624 976273 VV 0.083 1 2.190 1,1,1-Trichloroethane
.874 1558888 VV 0.074 1 4.216 Carbon Tetracl; 22Diclpropane
i0.242 478365 VV 0.064 1 2.161 1,2-Dichloroethane
11.159 799341 VV 0.060 1 2.128 Trichloroethene
11.502 728706 VV 0.072 1 2.261 1,2-Dichloropropane
11.698 162057 VV 0.058 1 2.312 Dibromomethane
11.925 482980 VV 0.057 1 2.221 Bromodichloromethane
12.567 400484 VV 0.054 1 2.214 c-1,3-Dichloropropene
13.384 250809 VV 0.051 1 2.233 t-1,3-Dichloropropene
13.530 1713429 VV 0.056 1-I 5.000 * Bromochloropropane *
13.661 520054 VV 0.061 1 2.298 1,1,2-Trichloroethane
13.854 1107580 VV 0.072 1 3.849 Tetraclethane; 13Diclpropane
14.262 210427 VV 0.056 1 2.156 Dibromochloromethane
14.430 174936 vv 0.070 1 2.365 1,2-Dibromoethane (EDB)
15.139 226344 VV 0.050 1 2.049 Chlorobenzene
15.264 729602 VV 0.062 1 2.106 1,1,1,2-Tetrachloroethane
16.422 55504 BV 0.073 1 2.460 Bromoform
16.799 601670 VV 0.050 1 4.790 $ 1,4-Dichlorobutane $
17.111 250043 VV 0.052 1 2.166 1,1,2,2-Tetrachloroethane
17.168 169753 VV 0.059 1 4.525 Bromobenzene; 123triclpropane
17.398 219309 VV o.051 1 1.901 2-Chlorotoluene
17.563 208582 VV 0.059 1 1.915 4-Chlorotoluene
18.550 253718 PV 0.052 1 1.905 1,3-Dichlorobenzene
18.692 286495 VV 0.056 1 1.818 1,4-Dichlorobenzene
19.273 238332 BV 0.050 1 1.936 1,2-Dichlorobenzene
-~.509 19216 VV 0.064 1 2.691 1,2-Dibromo-3-chloropropane
.. 789 217488 vv 0.059 1 1.979 1,2,4-Trichlorobenzene
22.047 390846 vv 0.107 1 1.666 Hexachlorobutadiene
22.562 196311 VV 0.059 1 · 2.135 1,2,3-Trichlorobenzene
·---------------=--===-------======= _=========================================--
I
I
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0
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Operato:i::
l nst.rumeut
ample Name
R Time Bar Code:
if,, ~ired on :
.. eport. Created on:
Last. Recalib on
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/\l if,
0 0
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ichlo10difluorome1hone 1065
r94"1h mi~'/R9,?~; j1!,'j5
,,µi.J51
b=-irichlorofluoromet~ 4.84)
i:::==-,. .. l-Ddllo1oelheoe I.Ill
l::::===-4'elhyler< chbile 6.7)6
I::==--+ 1)-0<hlo<oriher< 7.20)
l::===-+.1-0<hlo,orilo< 7.917
0)
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l20iclethene : 22DiclDIO{)Onl' 8.857
• !,Wm .J69 \l .1.1-,iclil&oet ne 9. 4 l)on ehocl · 220iclproporre 9.874
1.2-Dichlof0t>lhont 10.242 10.611
U-DicNorobulone S 16.799
'~'l'wrfflrurn16B
,l,i~h~IBl!Rl!II! I!~
l;J.-Oich!orobenzene 1917)
11-0ibromo-3-chloropropont 20.509
1;=...:.::·2;:_.4-!<il':'oc'°l:l\',\\t~~Jl~i4)
1.3-hichlorobtnWlt' 22.562
(lJ f-' f-'
0 0 /\l
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Ql 0)
C:\HPCHEM\l\DATA\052196\024F0201.D
RNP Page Number
HALL/PID Vial Number
VSTD002 Inject.ion Number
22
22
22
1
May
May
May
96
96
96
05:43
11:57
11:57
AM
AM
AM
Sequence Line
Instrument. Met.hod:
Analysis Met.hod
Sample Amount
ISTD Amount
1
24
1
2
f-'
.µ.
ro
Ql
502 HAL.MTR
502 HAL.MTR
0
5
. . Internal Standard Report I =================================================~-------
---===================================-=--------------
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
l ta File Name
r-ator
C:\HPCHEM\l\DATA\052196\023F0201.D
RNP Page Number
Ir ·ument
8J.1..,,,1e Name
HALL/PID Vial Number
VSTDOOl Injection Number
lain Time Bar Code:
Acquired on 22
l port Created on: 22
st Recalib on : 22
ultiplier : 1
May 96
May 96
May 96
05:12
11:59
11:58
AM
AM
AM
lig. 1 in C:\HPCHEM\l\DATA\052196\023F0201.D
Sequence -Line
Instrument Method:
Analysis Method
Sample Amount
ISTD Amount
1
23
1
2
502 HAL.MTH
502 HAL.MTH
0
s
et Time Area Type Width Ref# µg/L Name
.. l-------1------------1----1-----1-----1--------1------------------------
-
-
-
-
-
-
1

I 3.070 153187 VV 0.102 1 1.230 Dichlorodifluoromethane
3.384 150430 VV 0.101 1 1.458 Chloromethane
3.577 299646 VV 0.128 1 1.288 Vinyl chloride
I 4 .195 27787 VV O .101 1 2. 281 Bromomethane
4.365 213789 VV 0.113 1 1.305 Chloroethane
4.840 448465 VV 0.116 1 1.254 Trichlorofluoromethane
I 5.832 404734 VB 0.097 1 1.122 1,1-Dichloroethene
6.740 498528 BV 0.071 1 1.239 Methylene chloride
7.206 446405 VV 0.068 1 1.097 t-1,2-Dichloroethene
7.917 423972 VV 0.083 1 1.117 1,1-Dichloroethane
I. 8.857 683015 VV 0.076 1 2.516 c-12Diclethene; 22Diclpropane
9.241 127783 VV 0.060 1 1.480 Bromochloromethane
9.371 559870 VV 0.070 1 1.248 Chloroform
I q.626 549923 VV 0.076 1 1.201 1,1,1-Trichloroethane
.875 1005108 VV 0.073 1 2.657 Carbon Tetracl; 22Diclpropane
~J.241 252871 VV 0.064 1 1.121 1,2-Dichloroethane
I 11.164 539856 VV 0.060 1 1.487 Trichloroethene
. 11.501 459374 VV 0.099 1 1.161 1,2-Dichloropropane
11.705 83664 VV 0.069 1 1.508 Dibromomethane
11. 928 290780 VV O. 069 1 1. 449 Bromodichloromethane
I 12. 570 245514 VV O. 058 1 1. 500 c-1, 3-Dichloropropene
13.392 143038 VV 0.048 1 1.481 t-1,3-Dichloropropene
13.535 1721042 VV 0.057 1-I 5.000 * Bromochloropropane *
I 13.661 328722 VV 0.062 1 1.173 1,1,2-Trichloroethane
13.857 802355 VV 0.073 1 2.714 Tetraclethane; 13Diclpropane
14.269 102583 VV 0.066 1 1.442 Dibromochloromethane
14.441 89942 VV 0.080 1 1.499 1,2-Dibromoethane (EDB)
I 15.147 167971 VV 0.051 1 1.630 Chlorobenzene
15.273 434920 VV 0.060 1 1.339 1,1,1,2-Tetrachloroethane
16.436 ·22534 PV 0.129 1 2.071 Bromoform
I 16.805 617960 VV 0 .. 049 1 4.898 $ 1,4-Dichlorobutane $
17.122 136773 VV 0.052 1 1.584 1,1,2,2-Tetrachloroethane
17.175 108499 VV 0.057 1 2.845 Bromobenzene ; 123triclpropane
I 17.403 176327 VV 0.056 1 1.574 2-Chlorotoluene ·
17.570 179852 VV 0.053 1 1.673 4-Chlorotoluene
18.558 212471 VV 0.049 1 1.713 1,3-Dichlorobenzene
18.696 241177 VV a.ass 1 1.585 1,4-Dichlorobenzene
I 19.279 185637 VV 0.056 1 1.592 1,2-Dichlorobenzene
·. "0.517 18063 VV 0.095 1 2.400 1,2-Dibromo-3-chloropropane
c.793 180498 VV 0.056 1 1.781 1,2,4-Trichlorobenzene
I .02.053 380586 VV 0.089 1 l._699 Hexachlorobutadiene
22.567 148505 VV 0.060 1 1.878 1,2,3-Trichlorobenzene
0
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0
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(Jl
.....
0
.....
(Jl
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0
[\)
File iJlime
Operator
■Instrument
ltsamole Name
R Time Bar Code:
IA~.~ired on :
Report Created on:
Last Recalib on
.Multiplier
P6,lr.l~ 4.365
r:::===..;,;, hlorofluoromelhol"ll' 4.840
t;:::===-lc,1-0ichloroelhene 5.832
t::====----iJ,elhyle,. cho,oe 6710
t::====----1-1.2-Dichloroethene 7.206
t::====--1.1-Mo,oet'°"' 7.917
20iclelhene : 220ic~ropone 8.857
0.61'
'" . hJo,olo,m 9.l71 : ... 1-iricMoroethone 9.626
11-Dichloroe\hont> 10.241
· hloroeth.ene I 1.1~
· ·1i0ir,~opro~ 11.501
n omoo'ichlorome1~ 11.928
1::==-----<.-1,3-Dichloropropene 12.570
lelrocl : 22Dic1Dropone 9.875
etroclethot'M!: 13Dicloropone 11857
~==::±:l·:~iil!e!!1!JB1~6
1::=---1.2-0icMoroben1ene 19.279
11-Dibromo-J-chlo1oproc,one 20.517
~~;;:;;:::;-ll;:.•~-!_!!Tric~hl~,o~b~~h~%JJ~ne 22.0SJ
b,---4.2,J-lricMorobenzt>ne 22.567
H-Dichlorobuione S 16.805
C:\HPCHEM\l\DATA\052196\023F0201.D
RNP Page Number
HALL/PID Vial Number
VSTD00l Injection Number
22· May
22 May
22 May
1
96
96
96
05:12
11:59
11:58
AM
AM
AM
Sequence Line
Instrument Method:
Analysis Method
Sample Amount.
ISTD Amount
1
23
1
2
502 HAL.MTR
502_HAL.MTH
0
5
I
I
I
I
,1
I
I
I
I
I
I
I
I
I
I
I
I
I
I
PARADIGM ANALYTICAL LABORATORIES, INC.
Continuing Calibration Report
ICal Date: 052196
CCal Date 052296
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butyl benzene
tert-Butvlbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
Dibromochloromethane
1,2-Dibromo-3-chloropropane
1,2-Dibromoethane IEDBl
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1, 1-Dichloroethane
1,2-Dichloroethane
1 , 1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
2,2-Dichloropropane
cis-1,3-Dichloropropane
trans-1,3-Dichloropropane
Diisooropyl ether
Ethvlbenzene
Hexachlorobutadiene
lsooroovlbenzene
<>-lsooropyltoluene
Methvl-tert butyl ether
Methvlene Chloride
Naohthalene
n-Proovlbenzene
Stvrene
1, 1, 1,2-Tertrachloroethane
1, 1,2,2-Tertrachloroethane
Curve QCCK
1.234 1.103
0.406 0.472
0.717 0.708
1.224 1.148
0.140 0.184
0.139 0.196
1.055 1.099
0.612 0.640
0.587 0.608
3.766 3.244
0.627 0.650
0.939 0.746
2.304 2.124
0.583 0.410
0.607 0.672
0.685 0.703
0.551 0.541
0.061 0.060
0.434 0.408
0.413 0.390
0.687 0.758
0.761 0.842
0.878 0.958
0.497 0.590
1.913 1.786
1.113 1.063
1.674 1.543
2.838 2.786
1.872 1.749
1.599 1.356
3.766 3.244
1.028 0.997
0.625 0.624
0.423 0.395
0.871 0.882
1.527 1.358
0.663 0.628
1.397 1.335
1.262 1.138
1.769 1.670
0.244 0.237
0.802 0.770
1.619 1.712
1.761 -1.758
0.659 1.149
Page 1
%0
11.2
-15.0
1.4
6.4
-26.9
-33.7
-4.1
-4.5
-3.5
14.9
-3.6
23.0
8.1
34.9
-10.2
-2.5
1.7
1.4
6.1
5.7
-9.9
-10.1
-8.7
-17.0
6.9
4.6
8.1
1.9
6.8
16.5
14.9
3.1
0.1
6.8
-1.3
11.7
5.4
4.5
10.4
5.7
3.1
4.1
-5.5
0.2
-54.3
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PARADIGM ANALYTICAL LABORATORIES, INC.
Continuing Calibration Report
Tetrachloroethene 2.800 2.671 4.7
Toluene 1.034 0.984 5.0
1,2,3-Trichlorobenzene 0.587 0.635 -7.9
1,2,4-Trichlorobenzene 0.654 0.734 · -11.6
1, 1, 1-Trichloroethane 2.195 1.977 10.4
1 , 1 ,2-Trichloroethane 1.096 1.004 8.8
Trichloroethene 1.990 1.806 9.7
Trichlorofluromethane 1.757 1.442 19.7
1,2,3-Trichloroorooane 0.406 0.472 -15.0
1,2,4-Trimethvlbenzene 0.839 0.828 1.3
1,3,5-Trimethvlbenzene 1.873 1.943 -3.6
Vinyl Chloride 1.204 1.047 13.9
m/p-Xylene 2.023 2.000 1.2
a-Xylene 1.619 1.712 -5.5
Page 2
I . ------------~~~~~nal Standard Report---
=============~===========================-==--================================
l ata File Name
p~~ator
C:\HPCHEM\l\DATA\032096\040R0201.D
WML Page Number
I cument HALL/PID Vial Number
'
a, .. ple Name QCCK005 Injection Number
un Time Bar Code:
cquired on 21
leport Created on: 21
ast Recalib on : 14
ultiplier : 1
Mar
Mar
MAR
96 02:16 PM
96 02:46 PM
96 09:08 AM
Sequence Line
Instrument Method:
Analysis Method
Sample Amount
ISTD Amount
1
40
1
2
502 HAL.MTH
502 PID.MTH
0
5
I. ig. 2 in C:\HPCHEM\l\DATA\032096\040R0201.D .
et Time Area Type Width Ref# µg/L Name
l-------1------------1----1-----I-----I--------I-----------------------------\
I 4. 4 03 52164 BB O. 092 1 4. 979 (H) Vinyl chloride
7.761 159311 BV 0.130 1 4.799 (H) 1,1-Dichloroethene
10.025 399186 BB 0.095 1 9.907"MTBE; (H) t-12DCE
11.307 112404 VB 0.107 1 5.242 DIPE
Ii~:~~~ i~!~;~ ~: g:g~~ i ~:~~i l~l ~~~~f~~propene
14.162 343656 BV 0.068 1 4.663 Benzene
I 14.700 479650 VV 0.065 1-I 5.000 * Fluorobenzene *
15.381 214559 BV 0.060 1 4,323 (H) Trichloroethene
15.909 135905 BV 0.067 1 5.024 $ a,a,a-Trifluorotoluene $
I 17.057 51109 BV 0.053 1 4.972 (H) c-13pene
17.627 291063 BV 0.055 1 4.090 Toluene
18. 010 50874 VV O. 051 1 5. 033 (H) t-13pene
I ,q.569 148859 VB 0.055 1 3.904 (H) Tetrachloroethene
.017 235859 BV 0.050 1 3.914 (H) Chlorobenzene
~u.198 239826 VV 0.052 1 3.548 Ethylbenzene
I 20.396 497136 VB 0.053 1 6.466 m-Xylene; p-Xylene
21.083 369733 BV 0.060 1 6.430 o-Xylene; Styrene
21.694 162731 BV 0.055 1 2.876 Isopropylbenzene
22.222 213970 BV 0.058 1 4.696 (H) Bromobenzene
I 22.397 155948 VV 0.052 1 2.303 n-Propylbenzene
22.551 172204 VV 0.051 1 2.773 (H) 2Cltoluene
22. 715 355669 VV O. 080 1 4. 680 135-Trimethylbenz ; (H) 4Cltol
I 23.256 120706 PV 0.055 1 2.266 tert-Butylbenzene
. 23.340 124833 VV 0.051 1 1.930 124-Trimethylbenzene
23.635 99957 VV 0.056 1 1.627 sec-Butylbenzene
23. 83 7 214 713 VV O. 072 1 1. 630 p-Isopropyltoluene ; (H) 13dcb
I 23. 986 112050 VB O. 048 1 2. 426 (H) 14dcb
' 24. 616 · 146694 PB O. 074 1 3 .101 n-Butylbenzene ; (H) 12dcb
27.420 21252 BV 0.050 1 1.421 (H) 124-Triclbenzene
27.722 34411 PV 0.057 1 0.803 (H) Hexaclbutadiene
27.844 13909 VV 0.048 1 1.467 Naphthalene I
28.271 17488 BV 0.049 1 1.373 (H) 123Triclbenzene
l=alibration table contains at least one peak with amt= O
,-==============================================--=============================
I
I
I-
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I
I
,..
0
-1\)
0
(.J
0
,..
0
rn
I\)
0
rn
f:::::==-{H) Yonyl chlorido 4.40)
(.J
0
rn
,I,
0
rn
()1
0
rn
Ol
0
rn
-J
0
rn
(II
0
rn
t::=================-------4'18[: (HI l-121JC[ 10.025
~====--01'[ 11.l07
t:========--=--(H) c-12dc• 12.406
H) II -Di:tp,op,ne I l. 767
F=========------------{IH) Trichloroelhene 15.l81
t::======------1 o.~o-Triluorololone I 15.909
l==~---{H) c-l)p,ne 17.057
H) I-lll)ene 1&010
Cltol 12.715
.. 2i.i.o tc-But lf"l'olone : (H) lldcb 2ltl7
l=======------.-Bulylberu"": (H) 12dcb 24.616
H) 1 4-w~~~411l22
l=--{IH) 12llrderu"" 28171
'
=~====~=======================================================================
. , . · , Internal Standard Report
=============================================--======================-=--======
a:iata File Name
a-_,.,--"l'.:"ator
C:\HPCHEM\l\DATA\032096\040F0201.D
WML Page Number 1
40
1
2
1 .rument
if3ample Name
HALL/PID Vial Number
QCCK005 Injection Number
Sequence Line
Instrument Method:
9l-un Time Bar Code:
502 HAL.MTH
502 HAL.MTH
0
Acquired on 21 Mar
Mar
MAR
96 02:16 PM
96 02:46 PM
96 11:59 AM
~
eport Created on: 21
ast Recalib on : 21
ultiplier : 1
Analysis_Method
Sample Amount
ISTD Amount 5
asig. 1 in C:\HPCHEM\l\DATA\032096\040F0201.D
·--et Time Area Type Width Ref# µg/L Name l-------l------------l----l-----l-----1--------1------------------------------I
I 3.707 · 2460309 BV 0.077 1 4.759 Dichlorodifluoromethane
I
I
4.130 3908674 W 0.067 1 5.022 Chloromethane
4.429 3485657 W 0.087 1 5.151 Vinyl chloride
5.268 1550236 W 0.085 1 4.995 Bromomethane
5.547 2757783 W 0.090 1 3.776 Chloroethane
6.260 8450084 PV 0.111 1 4.587 Trichlorofluoromethane
7.782 9248041 BV 0.107 1 4.695 1,1-Dichloroethene
9.290 l.08159E+007 BV 0.088 1 0.828 Methylene chloride
10.043 9335509 W 0.078 1 4.476 t-1,2-Dichloroethene
11.101 9259743 BV 0.084 1 4.929 1,1-Dichloroethane
I 12.424 l.53045E+007 BV 0.081 1 9.397 c-12Diclethene; 22Diclpropane
• 12.930 3718730 W 0.063 1 5.342 Bromochloromethane
13.125·1.06745E+007 w 0.066 1 2.209 Chloroform
I '3.448 l.09894E+007 W 0.074 1 4.437 1,1,1-Trichloroethane
,.785 l.73885E+007 W 0.067 1 8.474 Carbon Tetracl; 22Diclpropane
i4.221 4378825 W 0.061 1 5.401 1,2-Dichloroethane
15.402 9763901 BV 0.062 1 4.063 Trichloroethene I 15.796 6157576 W 0.058 1 4.990 1,2-Dichloropropane
16.016 1991767 W 0.055 1 5.496 Dibromomethane
16.303 5247065 W 0.054 1 3.578 Bromodichloromethane
I-17.076 4518406 PV 0.056 1 4.940 c-1,3-Dichloropropene
18.028 2951959 BV 0.051 1 4.784 t-1,3-Dichloropropene
18.187 8214056 W 0.062 1-I 5.000 * Bromochloropropane *
I 18.342 3946150 W 0.056 1 5.375 1,1,2-Trichloroethane
18.592 l.18767E+007 W 0.063 1 7.738 Tetraclethane; 13Diclpropane
19.020 2177024 W 0.053 1 4.541 Dibromochloromethane
I
I
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I
I
19.206 1515167 W 0.058 1 5.450 1,2-Dibromoethane (EDB)
20.035 2738402 W 0.049 1 3.754 Chlorobenzene
20.174 6749178 W 0.052 1 4.475 1,1,1,2-Tetrachloroethane
21.443 066546 BV 0.052 1 1.784 Bromoform
21.886 2017069 W 0.053 1 4.471 $ 1,4-Dichlorobutane $
22.236 4445479 W 0.074 1 12.539 Bromobenzene; 123triclpropane
22.297 * not found* 1 1,1,2,2-Tetrachloroethane
22.569 2153654 W 0.053 1 2.901 2-Chlorotoluene
22.754 1899178 W 0.050 1 2.754 4-Chlorotoluene
23.855 2367740 BV 0.048 1 2.285 1,3-Dichlorobenzene
24.005 2329567 W 0.052 1 2.369 1,4-Dichlorobenzene
24.650 1906339 W 0.052 1 2.746 1,2-Dichlorobenzene
~6.001 214069 w 0.057 1 3.873 1,2-Dibromo-3-chloropropane
7.443 824941 W 0.052 1 1.369 1,2,4-Trichlorobenzene
27.J41 2429611 W 0.055 1 0.826 Hexachlorobutadiene
28.292 671496 W 0.055 1 1.373 1,2,3-Trichlorobenzene
.Calibration table contains at least one peak with amt= 0
Jt
I.
I
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I
all calibrated peaks were found
I
I
I 0
I
I
I
I
I "" -0
I
I
I_
I
I
[\) -I 0
I
I
I l
I
I
1' w
0
-
[\)
0
111
()l
~.291
I,
'>14.718
/
ITTJ46
'LU.UO
~1).311
15.100
'
()l
0)
0
111
()l . ()l
-ichlorodifluo1omethalt 1707
··iny1 ctbi:lt 4.429
'
0
111
Ql
·hloromethone 4.130
""
[\)
111
Ql Ql
"romomethone s.ai S4 7 ... ot!hor.e 5.
Trichlorofluorome1hone 6.260
, 1-0ichloroe\hene 7.782
-
"c·-··h'·r·--11.---1" "1" ~,.
'' ',
1.2-0ichloroethone 14.221
---
-.. _-
lbromom!ttu-.e 1n_ulo -=
-.. --.,;75
' l_,_,_u_
,-0,
·U~ I lllllll'fflili"""'I""' 19.010 .... - 1 omoe rlUl1"
"""" --. ---..
:,omoform 21.443 I 1,H,chlolobuln I 11.111!6
"romoben1ene: 123\riclpropone 22.236
~-....,.;;l,Q\W'l~ 21.569
. ,,Lil,lli6liliw'l'I e!§55
....;1-0ichkwobenzene 24.650
::=-1.2-0ibromo-J-chlo,opropone 26.001
1.2,4-Trichbfobenztnt 27.40 .. xochlorobutadifne 27.741 e 11.3-T1ictilorobtniene 28.292
I PARADIGM ANALYTICAL LABORATORIES, INC.
Response Factor Report
I Method: 6230D Water Batch: 052396
I H1: 003F0101.D P1: 003R0101.D
H2: 004F0101.D P2: 004R0101.D
H3: OOSF0101.D P3: OOSR0101.D
I H4: 006F0101.D P4: 006R0101.D
HS: 007F0101.D PS: 007R0101.D
Compound 1 2 3 4 5 Avg. o/oRSD
I Benzene 0.971 0.948 0.732 1.055 1.483 1.038 26.60
Bromobenzene 0.383 0.375 0.275 0.317 0.384 0.347 14.12
Bromochloromethane 0.464 0.634 0.47 0.699 0.862 0.6,26 26.72
I Bromodichloromethane 0.952 1.013 0.793 1.096 1.349 1.041 19.72
Bromoform 0.081 0.12 0.203 0.326 0.182 59.62
Bromomethane 0.105 0.088 0.213 0.135 50.29
I n-Butylbenzene 1.094 1.001 0.794 1.188 1.702 1.156 29.28
sec-Butyl benzene 0.633 0.578 0.707 1.018 0.734 26.75
tert-Butylbenzene 0.587 0.554 0.656 0.942 0.685 25.79
I Carbon tetrachloride 3.552 4.1 2.65 3.67 4.335 3.662 17.70
Chlorobenzene 0.621 0.587 0.449 0.638 0.745 0.608 17.54
Chloroethane 0.671 0.687 0.493 0.739 1.009 0.720 25.90
I Chloroform 2.001 2.307 1.515 1.911 2.296 2.006 16.24
Chloromethane 0.372 0.346 0.26 0.332 0.551 0.372 29.02
2-Chlorotoluene 0.346 0.332 0.551 0.410 29.85
I 4-Chlorotoluene 0.639 0.575 0.476 0.703 0.786 0.636 18.63
Dibromochloromethane 0.375 0.405 0.367 0.527 0.643 0.463 25.76
1,2-Dibromo-3-chloropropane 0.032 0.022 0.027 0.027 18.30
1,2-Dibromoethane (EDB) 0.334 0.319 0.3 0.418 0.494 0.373 21.77
I Dibromomethane 0.224 0.288 0.245 0.379 0.284 24.24
1,2-Dichlorobenzene 0.711 0.627 0.504 0.718 0.835 0.679 18.05
1,3-Dichlorobenzene 0.829 0.745 0.586 0.816 0.998 0.795 18.77
I 1,4-Dichlorobenzene 0.935 0.837 0.681 0.951 1.082 0.897 16.62
Dichlorodifluoromethane 0.507 0.336 0.477 0.639 0.490 25.39
1, 1-Dichloroethane 1.470 1.561 1.149 1.72 1.98 1.576 19.49
I 1,2-Dichloroethane 0.947 1.13 0.803 0.99 1.081 0.990 12.84
1, 1-Dichloroethene 1.429 1.732 1.152 1.622 1.936 1.574 18.99
cis-1,2-Dichloroethene 2.945 3.419 2.207 2.8 3.436 2.961 17.13
I trans-1 ,2-Dichloroethene 1.556 1.845 1.276 1.744 2.07 1.698 17.67
1,2-Dichloropropane 1.697 1.61 1.038 1.282 1.403 1.406 18.73
2,2-Dichloropropane 3.552 4.1 2.65 3.67 4.335 3.662 17.70
I cis-1,3-Dichloropropane 0.924 0.884 0.703 0.978 1.108 0.920 16.04
trans-1,3-Dichloropropane 0.542 0.514 0.447 0.586 0.738 0.565 19.27
Diisopropyl ether 0.325 0.315 0.252 0.334 0.472 0.340 23.73
Ethylbenzene 0.807 0.773 0.602 0.906 1.3 0.878 29.66
I Hexachlorobutadiene 1.830 1.334 1.079 1.491 1.721 1.491 20.18
lsopropylbenzene 0.590 0.563 0.436 0.669 0.565 17.12
p-lsopropyltoluene 1.273 1.182 0.938 1.402 2.02 1.363 29.67
I Methyl-tert butyl ether 1.022 0.992 0.775 1.108 1.555 1.090 26.37
Methylene Chloride 1.846 1.195 1.459 1.777 1.569 19.18
Naphthalene 0.290 0.221 0.175 0.233 0.333 0.250 24.62
I n-Propylbenzene 0.730 0.693 0.83 1.199 0.863 26.85
I
Paae 1 of 2
I
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I
PARADIGM ANALYTICAL LABORATORIES, INC.
Response Factor Report
Method: 62300 Water Batch: 052396
H1: 003F0101.D P1: 003R0101.D
H4: 004F0101.D P2: 004R0101.D
H3: 005F0101.D P3: 005R0101.D
H4: 006F0101.D P4: 006R0101.D
HS: 007F0101.Q PS: 007R0101.D
Compound 1 2 3 4 5 Avg.
Styrene 1.554 1.478 1.151 1.68 2.393 1.651
1, 1, 1,2-Tertrachloroethane 1.603 1.502 1.27 1.576 1.855 1.561
1, 1,_2,2-Tertrachloroethane 0.595 0.536 0.513 0.697 0.869 0.642
Tetrachloroethene 3.088 2.776 2.126 2.646 3.185 2.764
Toluene 0.891 0.861 0.663 0.976 1.386 0.956
1,2,3-Trichlorobenzene 0.852 0.546 0.422 0.639 0.776 0.647
1,2,4-Trichlorobenzene 0.864 0.64 0.522 0.732 0.864 0.725
1 , 1, 1-Trichloroethane 1.933 2.402 1.514 1.972 2.403 2.045
1, 1,2-Trichloroethane 1.314 1.046 0.759 0.825 0.91 0.971
Trichloroethene 1.894 2.204 1.409 1.894 2.242 1.929
Trichlorofluromethane 1.377 1.482 1.064 1.589 2.052 1.513
1,2,3-Trichloropropane 0.383 0.375 0.275 0.317 0.384 0.347
1,2,4-Trimethylbenzene 0.805 0.737 0.582 0.872 1.249 0.849
1.3,5-Trimethylbenzene 1.844 1.73 1.356 2.025 2.894 1.970
Vinyl Chloride 0.986 1.146 0.731 1.001 1.301 1.033
m/p-Xylene 1.827 1.74 1.361 2.041 2.912 1.976
o-Xylene 1.554 1.478 1.151 1.68 2.393 1.651
o/oRSD
27.75
13.47
22.64
15.18
27.91
26.73
20.34
18.23
22.62
17.32
23.77
14.12
29.21
29.02
20.47
29.24
27.75
'
========= = ===-=-==-===-===================-=========================-======
• · . · Calibration Report
lta File Name 1' tor
C:\HPCHEM\1\DATA\052396\007F0101.D
RNP Page Number 1
7
1
1
:n_ .~·ument
&mple Name
HALL/PID Vial Number
VSTD025 Injection Number
11m Time Bar Code:
,cquired on 23
l port Created on: 23
st Recalib on : 23
1ultiplier 1
I 3
I
4
I
I 5
I
I
I
I
I
I
I
6
7
8
9
RT
3.058
3.372
3.570
4.171
4.356
4.817
5.802
6.706
7.179
Lvl
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
·5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
May 96
May 96
May 96
µg/L
1.0
2.0
5.0
10.0
25.0
1.0
2.0
5.0
10.0
25.0
1.0
2.0
5.0
10.0
25.0
1.0
2.0
5.0
10.0
25.0
1.0
2.0
5.0
10.0
25.0
1.0
2.0
5.0
10.0
25.0
1.0
2.0
5.0
10.0
25.0
1.0
2.0
5.0
10.0
25.0
1.0
2.0
5.0
10.0
12:44 PM
01:37 PM
01:35 PM
Calibration
Amt/Area
8.5386e-006
8.9044e-006
1.3483e-005
9.4916e-006
6.4383e-006
1.0527e-005
1.3049e-005
l.7408e-005
1.3635e-005
7.4701e-006
3.9729e-006
3.941e-006
6.1938e-006
4.5247e-006
3.1621e-006
3.7254e-005
5.1617e-005
8.752e-005
2.1234e-005
9.0296e-006
5.84e-006
6.5733e-006
9.1828e-006
6.1261e-006
4.0745e-006
2.8455e-006
3.0482e-006
4.2543e-006
2.8498e-006
2.0039e-006
2.7429e-006
2.6078e-006
3.9296e-006
2.792e-006
2.1243e-006
2.3193e-006
2.4476e-006
3.7877e-006
3.1044e-006
2.314e-006
2.5181e-006
2.449e-006
3.5496e-006
2.5969e-006
Table
Sequence Line
Instrument Method:
Analysis Method
Sample Amount
ISTD Amount
502 HAL.MTH
502 HAL.MTH
0
5
Ref Istd I# Name
1 Dichlorodifluorometh ...
1 Chloromethane
1 Vinyl chloride
1 Bromomethane
1 Chloroethane
1 Trichlorofluorometha ...
1 1,1-Dichloroethene
1 Methylene chloride
1 t-1,2-Dichloroethene
I s 25. o l.9874e-006
May 96 01:37 PM page 2
,ethod: C:\HPCHEM\l\METHODS\502 HAL.MTR
110 7.891 1 1.0 2.6658e-006 1 1,1-Dichloroethane
2 2.0 2.8944e-006
3 5.0 3.9392e-006
I 4 10.0 2.6329e-006
5 25.0 2.0773e-006
11 8.832 1 2.0 2.6617e-006 1 c-12Diclethene 22D ...
I 2 4.0 2.6428e-006
3 10.0 4.1029e-006
4 20.0 3.2347e-006
112 5 50.0 2.3942e-006
9.218 1 1. 0 8.4527e-006 1 Bromochloromethane
2 2.0 7.1277e-006
I 3 5.0 9.6367e-006
4 10.0 6.4814e-006
5 25.0 4.7719e-oo6
13 9.351 1 1.0 l.9584e-006 1 Chloroform
I 2 2.0 l.9582e-006
3 5.0 2.988e-006
4 10.0 2.3697e-006
114 5 25.0 l.7912e-006
9.605 1 1.0 2.0269e-006 1 1,1,1-Trichloroethan ...
2 2.0 l.8806e-006
I 3 5.0 2.9913e-006
4 10.0 2.2956e-006
5 25.0 l.7115e-006
15 9.853 1 2.0 2.2065e-006 1 Carbon Tetracl 22D ...
I 2 4.0 2.2036e-006
3 10.0 3.4169e-006
4 20.0 2.4674e-006
I 16
5 so.a 1. 8977e-006.
10.220 1 1.0 4.137le-006 1 1,2-Dichloroethane
2 2.0 3.9984e-006
I 3 5.0 5.6386e-006
4 10.0 4.5725e-006
5 25.0 3.8055e-006
17 11.144 1 1.0 2.0696e-006 1 Trichloroethene
I 2 2.0 2.0497e-006
3 5.0 3.2129e-006
4 10.0 2.3904e-006
I 5 25.0 l.8347e-006
18 11.479 1 1. 0 2.3097e-006 1 1,2-Dichloropropane
2 2.0 2.8055e-006
I 3 5.0 4.363e-006
4 10.0 3.5329e-006
5 25.0 2.931e-006
19 11.669 1 1.0 l.7498e-005 1 Dibromomethane
I 2 2.0 1.5666e-005
3 5.0 l.8483e-005
4 10.0 1.1937e-005
I 5 25.0 · 8 .4139e-006
20 11.905 1 1. 0 4.1175e-006 1 Bromodichloromethane
2 2.0 4.4592e-006
I 3 5.0 5.712le-006
4 10.0 4.1312e-006
5 25.0 3.0481e-006
21 12.553 1 1.0 4.2424e-006 1 c-1,3-Dichloropropen ...
I 2 2.0 5.1084e-006
3 5.0 6.4369e-006
I 4 10. o 4.6286e-006
May 96 · 01:37 PM · page 3
,jethod: C;: \HPCHEM\l \METHODS\502 HAL.MTR
I 5 25.0 3.7109e-006
13.373 1 1.0 7.2337e-006 1 t-1,3-Dichloropropen ...
2 2.0 8.7894e-006
I 3 5.0 l.013e-005
4 10.0 7.7276e-006
5 25.0 5.5722e-006 123 13.518 1 5.0 2.4493e-006 ISTD 1 * Bromochloropropane ...
2 5.0 :.C.8237e-006
3 5.0 2.8299e-006
I 4 5.0 2.8299e-006
5 5.0 2.5706e-006
6 5.0 2.8299e-006 124 13.651 1 1.0 2.9833e-006 1 1,1,2-Trichloroethan ...
2 2.0 4.3182e-006
3 5.0 5.9656e-006
4 10.0 5.4877e-006
125 5 25.0 4.518e-006
13.841 1 2.0 2.5378e-006 1 Tetraclethane 13Di ...
2 4.0 3.255le-006
I 3 10.0 4.2603e-006
4 20.0 3.4224e-006
5 50.0 2.5826e-006 126 14.247 1 1.0 l.045e-005 1 Dibromochloromethane
2 2.0 l.116e-005
3 5.0 l.2342e-005
4 10.0 8.5893e-006
I 5 25.0 6.393e-006
14.407 1 1.0 l.1748e-005 1 1,2-Dibromoethane (E ...
2 2.0 l.4155e-005
I 3 5.0 1. 507le-0.05
4 10.0 l.0822e-005
5 25.0 8.3276e-006 I 28 15.133 1 1.0 6.3063e-006 1 Chlorobenzene
2 2.0 7.6953e-006
3 5.0 l.0077e-005
4 10.0 7.0988e-006
I 29
5 25.0 5.5196e-006
15.260 1 1.0 2.444e-006 1 1,1,1,2-Tetrachloroe ...
2 2.0 3.0078e-006
I 3 5.0 3.5664e-006
4 10.0 2.8729e-006
5 25.0 2.217le-006
I 30 16.394 ·1 1.0 9.0373e-005 1 Bromoform
2 2.0 5.6008e-005
3 5.0 3.7855e-005
4 10.0 2.2347e-005
I 5 25.0 l.2598e-005
31 16.810 1 0.0 0.0 1 $ 1,4-Dichlorobutane ...
6 5.0 7.4272e-006
I 32 17.108 1 1. 0 6.584e-006 1 1,1,2,2-Tetrachloroe ...
2 2.0 B.4266e-006
3 5.0 8.8195e-006
I 4 10.0 6.5007e-006
5 25.0 4.7317e-006
33 17.154 1 2.0 2.0456e-005 1 Bromobenzene 123tr ...
2 4.0 2.407le-005
I 3 10.0 3.2948e-005
4 20.0 2.8575e-005
I May 96
5 50.0 2.1425e-005
01:37 PM page 4
!et hod: C:\HPCHEM\l\METHODS\502_HAL.MTH
134 17.391 1 1. 0 5.7725e-006 1 2-Chlorotoluene
2 2.0 7.8552e-006
3 5.0 9.6779e-006
I 4 10.0 6.7257e-006
5 25.0 5.2182e-006
35 17.559 1 1.0 6.1364e-006 1 4-Chlorotoluene
I 2 2.0 7.8623e-006
3 5.0 9. 5025e-006
4 10.0 6.4383e-006
036 5 25.0 5.2359e-006
18.546 1 1.0 4.726le-006 1 1,3-Dichlorobenzene
2 2.0 6.0608e-006
I 3 5.0 7. 73 O 9e-006
4 10.0 5.550le-006
5 25.0 4.122e-006
37 18.681 1 1. 0 4.1894e-006 1 1,4-Dichlorobenzene
I 2 2.0 5.400le-006
3 5.0 6.6468e-006
4 10.0 4.7614e-006
I 38
5 25.0 3.7998e-006
19.268 1 1. 0 5.5094e-006 1 1,2-Dichlorobenzene
2 2.0 7.202e-006
I 3 5.0 8.9817e-006
4 10.0 6.3038e-006
5 25.0 4.9263e-006
39 20.502 1 1. 0 l.2257e-004 1 1,2-Dibromo-3-chloro ...
I 2 2.0 2.0493e-004
3 5.0 l.648le-004
4 10.0 9.539e-005
I 40
5 25.0 4.658le-005
21.784 1 1. 0 4.5336e-006 1 1,2,4-Trichlorobenze ...
2 2.0 7.0538e-006
I 3 5.0 8.6663e-006
4 10.0 6.1885e-006
5 25.0 4.762le-006
41 22.047 1 1. 0 2.1413e-006 1 Hexachlorobutadiene
I 2 2.0 3.3865e-006
3 5.0 4.1949e-006
4 10.0 3.0367e-006
I 5 25.0 2.3898e-006
42 22.556 1 1.0 4.599le-006 1 1,2,3-Trichlorobenze ...
2 2.0 8.2794e-006
I 3 5.0 l.073e-005
4 10.0 7.0812e-006
5 25.0 5.3026e-006
I Calibration Settings
Title:
I 8021 HALL 5mL
Re ~ence window: 5.000 %
'c ~eference window: 5.000 %
nits of amount: µg/L
ultiplier: 1. 0 CF uncal peaks: 0.0
STD# to adjust uncal peaks: 0
ample Amount: 0.0
'
========================--============================================-===-==
· Internal Standard Report
,=======---=====================================-======-=-----=====----===-----
'
ta File Name
·tor
C:\HPCHEM\l\DATA\052396\003F0101.D
RNP Page Number
:n .ument HALL/PID Vial Number
l mple Name VSTDOOl Injection Number
n Time Bar Code:
\cquired on 23
lport Created on: 23
st Recalib on : 23
ltiplier : 1
May 96
May 96
May 96
AM 10:04
01:29 PM
01:29 PM
l g. 1 in C:\HPCHEM\l\DATA\052396\003F0101.D
Sequence Line
Instrument Method:
Analysis Method
Sample Amount
!STD Amount
1
3
1
1
502 HAL.MTH
502 HAL.MTH
0
5
t Time Area Type Width Ref# µg/L Name l-------l------------l----l-----l-----1--------1------------------------------I
I 3.079 117116 BV 0.081 1 0.891 Dichlorodifluoromethane
3.399 94990 VV 0.097 1 1.090 Chloromethane
3.582 251707 VV 0.111 1 1.064 Vinyl chloride
I 4.205 26843 VV 0.104 1 2.242 Bromomethane
4.370 171234 VV 0.097 1 1.088 Chloroethane
4.826 351432 VB 0.104 1 0.984 Trichlorofluoromethane
5.810 364581 BB 0.075 1 0.938 1,1-Dichloroethene I 6.721 431167 BV 0.079 1 0.999 Methylene chloride
7.188 397128 VB 0.073 1 0.905 t-1,2-Dichloroethene
7.898 375115 BB 0.078 1 0.935 1,1-Dichloroethane
I 8.834 751409 BV 0.075 1 2.408 c-12Diclethene; 22Diclpropane
9.225 118305 VV 0.051 1 1.384 Bromochloromethane
9.356 510626 VV 0.060 1 1.072 Chloroform
I 611 493371 VV 0.063 1 1.008 1,1,1-Trichloroethane
.862 906408 VV 0.067 1 2.259 Carbon Tetracl; 22Diclpropane
10.230 241717 VV 0.063 1 0.986 1,2-Dichloroethane
11.150 493·175 VV O. 060 1 1. 285 Trichloroethene
lrl.490 432958 VV 0.083 1 0.962 1,2-Dichloropropane
11.703 57150 VV 0.070 1 1.289 Dibromomethane
11.913 242865 VV 0.063 1 1.252 Bromodichloromethane
·112.560 235718 VV 0.058 1 1.373 c-1,3-Dichloropropene
13.384 138241 PV 0.049 1 1.364 t-1,3-Dichloropropene
13.522 2041383 VV 0.060 1-I 5.000 * Bromochloropropane *
113.658 335199 VV 0.062 1 1.013 1,1,2-Trichloroethane
13.849 788087 VV 0.069 1 2.397 Tetraclethane; 13Diclpropane
14.255 95690 VV 0.077 1 1.344 Dibromochloromethane
114.432 85121 VV 0.081 1 1.391 1,2-Dibromoethane (EDB)
15.139 158571 VV 0.049 1 1.477 Chlorobenzene
15.261 409165 VV 0.054 1 1.187 1,1,1,2-Tetrachloroethane
16.413 11065 BV 0.094 1 1.957 Bromoform
I 16.798 696317 PV 0.049 1 0.000 $ 1,4-Dichlorobutane $
17.113 151883 VV 0.055 1 1.551 1,1,2,2-Tetrachloroethane
17.169 97770 VV 0.044 1 2.443 Bromobenzene; 123triclpropane
I 17.396 173236 VV 0.054 1 1.432 2-Chlorotoluene
17.564 162962 VV 0.051 1 1.482 4-Chlorotoluene
18.553 211593 VV 0.049 1 1.591 1,3-Dichlorobenzene
. 118.692 238696 VV 0.051 1 1.459 1,4-Dichlorobenzene
19.275 181509 VF 0.050 1 1.460 1,2-Dichlorobenzene
.530 8158 MM 0.063 1 2.033 1,2-Dibromo-3-chloropropane
_.792 220578-VV 0.055 1 1.803 1,2,4-Trichlorobenzene
I 22.053 467015 VV 0.066 1 1.730 Hexachlorobutadiene
22.565 217434 VV 0.058 1 2.023 1,2,3-Trichlorobenzene
tlibration table contains at least one peak with amt= o
'
ta File Name
erator
:nstrument
C:\HPCHEM\l\DATA\052396\003F0101.D
RNP Page Number
HALL/PID Vial Number
VSTD00l Injection Number
I. mp:;_7 Name
n Time Bar Code:
·red on 23
ie •. t Created on: 23
1st Recalib on : 23
ltiplier : 1
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Modified
May 96
May 96
May 96
10:04
01:29
01:29
AM
PM
PM
Sequence Line
Instrument Method:
Analysis Method
Sample Amount
ISTD Amount
2
3
1
1
502 HAL.MTH
502 HAL.MTH
0
5
f\)
0
rn
,p.
0
rn
(J)
0
(I
Ill
0
rn
0
rn
f-0
f\)
rn
f-0
,p.
rn
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
0 T--'-~~~~--1-~~i...__.~__._JL...._~.,_____L_~~~Qlr:._._~_.__L
lata File
()l
f-0
0
f-0
()l
f\)
0
f\)
i4Jlme
l erator
strument
,..~le Name
Rt :ime Bar Code:
.1-l)i:hlo,oe\htne l.810
t;=---1<,:ho,oelhtne 11.150-
li.rJ!!lbky1'fRII" I 1.490 1 ro rO~Jfilo,o~ 11.913
-1,3-Dichloroproptnt 12.560
1.-l=llflliNIMl'alllt I§~
IJ·Oi:hiolobe"l.-. 19.275
IJ-Dibromo-3-chlorop,Ol)IJle 20.530
F-,...;;·::.:2·'4· t~~~::t~ ll~si
1,2.J-fr(hlorobenltne 22.565
C:\HPCHEM\l\DATA\052396\003F0101.D
RNP Page Number
HALL/PID Vial Number
VSTD00l Injection Number
t 4uired on : 23
port Created on: 23
Last Recalib on 23
rltiplier 1
May 96
May 96
May 96
10:04
01:29
01:29
AM
PM
PM
Sequence Line
Instrument Method:
Analysis Method
Sample Amount
!STD Amount
1
3
1
1
C
Ill
rn
'"j
..,.
Hi ..,.
rn
0..
502 HAL.MTH
502 HAL.MTH
0
5
'
===========-----------------==-=====-========================================
· Internal Standard Report
--========================================-====-=========-====-====-=----------
t ta File Name
'l.tor
C:\HPCHEM\l\DATA\052396\004F0101.D
RNP Page Number 1
4
1
1
Ir. _·ument
liampl 7 Name
a.in Time Bar Code:
HALL/PID Vial Number
VSTD002 Injection Number
Sequence Line
Instrument Method: Acquired on 23 May 96
May 96
May 96
10:35
01:30
01:30
AM
PM
PM
502 HAL.MTH
502 HAL.MTH
0 leport Created on: 23
ast Recalib on : 23
ultiplier : 1
Analysis Method
Sample Amount
ISTD Amount 5
lig. 1 in C:\HPCHEM\l\DATA\052396\004F0101.D
et Time Area Type Width Ref# µg/L Name
J.-.3.089l------224608IBV--I0.08ll-l---l---2.148IDichlorodifluoromethane-------l I 3.415 153266 VV 0.090 1 1.917.Chloromethane
I
I
I
I
3.597 507490 VV 0.104 1 2.223 Vinyl chloride
4.214 38747 VV 0.092 1 2.473 Bromomethane
4.381 304259 VV 0.097 1 2.012 Chloroethane
4.840 656118 VB 0.100 1 2.002 Trichlorofluoromethane
5.828 766934 BB 0.076 1 2.171 1,1-Dichloroethene
6.729 817125 BV 0.082 1 2.233 Methylene chloride
7.194 816673 VV 0.070 1 2.122 t-1,2-Dichloroethene
7.912 690986 VV 0.070 1 1.955 1,1-Dichloroethane
8.851 1513559 BV 0.072 1 5.022 c-12Diclethene; 22Diclpropane
9.236 280595 VV 0.067 1 2.304 Bromochloromethane
9.369 1021359 VV 0.067 1 2.284 Chloroform
-.622 1063492 VV 0.069 1 2.330 1,1,1-Trichloroethane
.871 1815181 VV 0.075 1 4.619 Carbon Tetracl; 22Diclpropane
10.240 500196 VV 0.058 1 2.158 1,2-Dichloroethane
I 11. 162 975759 VV O. 056 1 2. 432 Trichloroethene
. 11.506 712873 VV 0.073 1 2.116 1,2-Dichloropropane
11.704 127667 VV 0.057 1 2.110 Dibromomethane
11.926 448510 VV 0.066 1 2.112 Bromodichloromethane
I 12.570 391512 VV 0.053 1 2.147 c-1,3-Dichloropropene
13.393 227547 PV 0.057 1 2.125 t-1,3-Dichloropropene
13.537 1770719 VV 0.057 1-I 5.000 * Bromochloropropane *
I 13.667 463152 VV 0.061 1 2.021 1,1,2-Trichloroethane
13.859 1228836 VV 0.068 1 4.164 Tetraclethane; 13Diclpropane
14.269 179216 VV 0.056 1 2.061 Dibromochloromethane
I 14.436 141290 VV 0.063 1 2.092 1,2-Dibromoethane (EDB)
15.151. 259899 VV 0.053 1 2.225 Chlorobenzene
15.271 664937 VV 0.058 1 2.032 1,1,1,2-Tetrachloroethane
16.436 35709 BV 0.063 1 2.367 Bromoform
I 16.807 599130 VV 0.050 1 0.000 $ 1,4-Dichlorobutane $
17.120 237342 VV 0.050 1 2.176 1,1,2,2-Tetrachloroethane
17.178 166177 VV 0.058 1 4.361 Bromobenzene; 123triclpropane
I 17.406 254608 VV 0.057 1 2.087 2-Chlorotoluene
17.569 254378 vv 0.052 1 2.148 4-Chlorotoluene
18.563 329991 BV 0.046 1 2.250 1,3-Dichlorobenzene
I 18.701 370365 VV 0.048 1 2.108 1,4-Dichlorobenzene
19.286 277701 PV 0.055 1 2.117 1,2-Dichlorobenzene
'.525 9759 BB 0.045 1 2.305 1,2-Dibromo-3-chloropropane
.. 802 283535 BV 0.055 1 2.242 1,2,4-Trichlorobenzene
I 22.056 590579 VV 0.061 1 2.162 Hexachlorobutadiene
22.573 241563 vv 0.056 1 2.272 1,2,3-Trichlorobenzene
falibration table contains at least one peak with amt= 0
I. ta File Name
erator
:Cnstrument
C:\HPCHEM\l\DATA\052396\004F0101.D
RNP Page Number
HALL/PID Vial Number
I" mple Name VSTD002 Injection Number
n Time Bar Code:
·.red on 23
~~ ~t Created on: 23 t st Recalib on 23
ltiplier 1
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
May 96
May 96
May 96
10:35
01:30
01:30
AM
PM
PM
Sequence Line
Instrument Method:
Analysis Method
Sample Amount
ISTD Amount
2
4
1
1
502 HAL.MTH
502_HAL.MTH
0
5
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
lata File
-(Jl
f--'
0
f--'
(Jl
[\J
0
[\J
iJ&me
lperator
nstrument
aTTinle Name
R1 ~ime Bar Code:
l cc;w.ired on :
eport· Created on:
Last Recalib on
lultiplier
[\J
0
m
if'
0
m
ichlorod~luoromethont 1089
hkH , l~iM lil597
!,!,,l,~181
t;:::=~-+1;ichlorolluo1ornelhone HtO
t:::==--1.1-0<hkroolh<"' l.818
t:::==--<1,,lhyle<, chlo<Kle 6.m
t:::==---4-11-ll<hlo<ool""" 7.191
t:::==--1.1-0<hkrc,lho<, 7.911
Ol
0
m
t:=====--~-10.:lelh<"' : 110<ipropon, 8.81 I
[D
0
m
· · -rc~i n9fei1oct 22Diclpropone 9.871
10.61)
1 romo
1,1-o.:hlolool""" 10.110
ichmoet~ne 11.162
1;:j,l-llcJ/jl'"''P"" 11.506
orNxfteh~r&ntlhone 11.926
~--<-1.l-0ichkr.,.,o,,. 12570
1,1-li<hlorobuloot I 16.BOl lll!<"1ffil!ll>opof. ll()J 75
~111\SIIII\! \j-~
t:===1~,iiflilBtsli!!li!R! l!lol
l-Dic:hlorot>P111~ 19186
f:==~~·1a:.·
1·...::1,11,· h;,ift."i&'l'JJfl201s
1.3-lrichlorobenitne 22.573
0
m
f--'
[\J
m
C:\HPCHEM\l\DATA\052396\004F0101.D
RNP Page Number
HALL/PID Vial Number
VSTD002 Injection Number
23
23
23
1
May
May
May
96
96
96
10:35
01:30
01:30
AM
PM
PM
Sequence Line
Instrument Method:
Analysis Method
Sample Amount
ISTD Amount
1
4
1
1
f--'
502 HAL.MTR
502 HAL.MTR
0
5
'
=======--================---=================================================
· Internal Standard Report
&ita File Name ~ ,tor
C:\HPCHEM\l\DATA\052396\005F0101.D
RNP Page Number 1
5
1
1
Ir. _·ument HALL/PID Vial Number
t mpl7 Name VSTD005 Injection Number
n Time Bar Code:
Acquired on
leport Created on: 23
ast Recalib on : 23
Multiplier : 1
23 May
May
May
96
96
96
11:06
01:30
AM
PM
01 :30 PM
Sequence Line
Instrument Method:
Analysis Method
Sample Amount
ISTD Amount
502 HAL.MTH
502 HAL.MTH
0
5
'
ig. 1 in C:\HPCHEM\l\DATA\052396\005F0101.D
et Time Area Type Width Ref# µg/L Name
1--\------I --1 \----1---I -------1
3.085 370832 BV 0.085 1 3.790 Dichlorodifluoromethane
3.401 287217 VV 0.085 1 3.434 ~hloromethane
I
I
I
I
3.601
4.206
4.385
4.849
5.832
6.737
7.202
7.918
8.857
9.248
9.374
.627
.879
10.243
1 11..1.66
11.506
11.701.
11.929 1 12.574
13.396
13.538
1 13.670
13.862
14.270
I 14. 432
15.151
1.5.275
I 16. 423
16.810
17.123
17.180
I 17.409
17.575
18.562
I 18. 700
19.283
. 520
I _. 799
·22.055
22.573
807258 VV
57130 VV
544498 VV
11.75283 VB
1.272382 BV
1320072 BV
1408625 VV
1269300 VB
2437323 BV
518849 VV
1673362 VV
1671520 VV
2926646 VV
886740 VV
1556221 VV
1146011 VV
2.70512 VV
875331 VV
776775 VV
493571 VV
1766849 VV
838141 VV
2347277 VV
405128 VV
331.759 VV
496183 VV
1401.958 VV
1.32082 PV
673201 VV
566925 VV
303504 VV
516641 VV
526177 VV
646752 BV
752238 VV
556689 VV
30338 BV
576949 BV
1191928 VV
465964 VV
0.094 1
0.079 1
0.098 1
0.098 1
0.086 1
0.085 1
0.076 1
0.087 1
0.071 1
0.057 1
0.076 1
0.077 1
0.072 1
0.066 1
0.067 1
0.066 1
0.059 1
0.063 1
0.052 1
0.046 l.
0.061 1-I
0.057 1
0.069 1
0.052 1
0.065 1
0.050 1
0.063 1
0.049 1
0.054 1
0.050 1
0.057 1
0.051 1
0.052 1
0.051 1
0.055 1
0.051 1
0. 049 1
0.049 1
0.063 1
0.052 1
3.690 Vinyl chloride
2.979 Bromomethane
3.513-Chloroethane
3.623 Trichlorofluoromethane
3.785 1,1-Dichloroethene
3.931 Methylene chloride
3.890 t-1,2-Dichloroethene
3.721 1,1-Dichloroethane
8.360 c-12Diclethene; 22Diclpropane
3.820 Bromochloromethane
3.942 Chloroform
3.868 1,1,1-Trichloroethane
7.589 Carbon Tetracl; 22Diclpropane
4.043 1,2-Dichloroethane
3.887 Trichloroethene
3.876 1,2-Dichloropropane
3.741 Dibromomethane
3.868 Bromodichloromethane
3.933 c-1,3-Dichloropropene
4.059 t-1,3-Dichloropropene
5.000 * Bromochloropropane *
4.227 1,1,2-Trichloroethane
8.052 Tetraclethane; 1.3Diclpropane
3.842 Dibromochloromethane
3.963 1,2-Dibromoethane (EDB)
3.825 Chlorobenzene
4.049 1,1,1,2-Tetrachloroethane
3.800 Bromoform
5.000 $ 1,4-Dichlorobutane $
4.086 1,1,2,2-Tetrachloroethane
8.113 Bromobenzene; 123triclpropane
3.806 2-Chlorotoluene
3.767 4-Chlorotoluene
3.809 1,3-Dichlorobenzene
3.765 1,4-Dichlorobenzene
3.741 1,2-Dichlorobenzene
3.592 1,2-Dibromo-3-chloropropane
3.780 1,2,4-Trichlorobenzene
3.922 Hexachlorobutadiene
3.499 1,2,3-Trichlorobenzene
falibration table contains at least one peak with amt= O
I. ta File Name
erator
.nstrument
C:\HPCHEM\1\DATA\052396\005F0101.D
RNP Page Number
HALL/PID Vial Number
f, mple Name VSTD005 Injection Number
n Time Bar Code:
· · red on 23
<~ .t Created on: 23
ai·st Recalib on 23
a.i1tiplier 1
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
May 96
May 96
May 96
11:06
01:30
01:30
AM
PM
PM
Sequence Line
Instrument Method:
Analysis Method
Sample Amount
ISTD Amount
2
5
1
1
502 HAL.MTH
502 HAL.MTH
0
5
[\) .i,. (l) (lJ I-" I-" I-"
0 0 0 0 0 [\) >fi
ro ro ro ro ro ro ro
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
0 ,'--~-,-'----()1 ~~___,(Jl~-'--'___L~..__._--1-~~i........___.___,__Jc:__._~_,___I_Ql
I
I-"
0
I-"
(JI
[\)
0
[\)
~me Data File
a:,perator
ai:nstrument
s~ -,le Name
l Time Bar Code:
cqui:r:ed on
eport Created on:
Last Recalib on
.Multiplier
. hlorodifluoromt'lhone 1085
hlo,o i:l'!i,~\?,l J.60l
1!11ii11J.i6uas
r:::==~-Trichlorofluororre0o'lt o•9
i:::====-4.+-D<hloroeli.nt 5.811
r::====---W.lhylor, clrbwJ< 6.7J7
r::====---+-+1-11<1 .... lt,,, 7.101
t:===~--+.1. -0.\;ooe\haot 7.918
-12Diclelhene ; 220iclpropone 8.857
i"lllo9~1.l. , • -ic roe ne 9.627 ocbon ielroct : 220iclpropone, 9.879
1-Dichlo<oelm 10.m
1 romome ne
oelhene 11.166
1-llidm<OOI°""' 11.506
<! ...... hoot 11.919
b===----<-1.l-llidm<oorop,ne 11.571
romofo,in 16.•23
18.097
i~fjf~':oblo, I 16.810
0~y1.IM1J
F-sa====:!8.· c~~ \%.l1iJli
t=~---+ .. 1-Dchlorobonl.,. 19.181
19.687
11-Dibromo-3-chloropropone 20.520
b=~--1.1.J-Tr<hlorobonl.,. 11.SJJ
hlorop,opone , 115311
letroclethane : 130iclj)fot)Ol'le 13.862
C:\HPCHEM\l\DATA\052396\005F0101.D
RNP Page Number
HALL/PID Vial Number
VSTD005 Injection Number
23
23
23
1
May
May
May
96
96
96
11:06
01:31
01:30
AM
PM
PM
Sequence Line
Instrument Method:
Analysis Method
Sample Amount
ISTD Amount
1
5
1
1
502 HAL.MTH
502 HAL.MTH
0
5
'
========================================================================-====
· Internal Standard Report
lita File Name ~ 'tor
C:\HPCHEM\l\DATA\052396\006F0101.D
RNP Page Number
en _·ument
'3.mple Name
HALL/PID Vial Number
VSTDOlO Injection Number
"1n Time Bar Code:
'l.cquired on : 23
le,port Created on: 23
!list Recalib on : 23
V!ultiplier 1
May 96
May 96
May 96
11:37
01:35
01-: 35
AM
PM
PM
lig. 1 in C:\HPCHEM\l\DATA\052396\006F0101.D.
Sequence Line
Instrument Method:
Analysis Method
Sample Amount
ISTD Amount
1
6
1
1
502 HAL.MTH
502 HAL.MTH
0
5
'!ret Time Area Type Width Ref# µg/L Name
.j.--;~~;~l-----i~~;~~~l;;--1~~~~~1-~---1--~~~;~~l~i~hi;;;aifi~;;;;~~h~~~-------1
I 3.394 733420 VV 0.083 1 7.394 Chloromethane
3.593 2210088 VV 0.096 1 9.192 Vinyl chloride
4.205 470949 VV 0.073 1 7.643 Bromomethane
4.376 1632358 VV 0.110 1 8.766 Chloroethane I
4.836 3509061 VV 0.102 1 9.869 Trichlorofluoromethane
5.825 3581683 PV 0.091 1 10.248 1,1-Dichloroethene
6.730 3221238 VV 0.087 1 9.039 Methylene chloride
7.187 3850718 VV 0.077 1 10.019 t-1,2-Dichloroethene I
7.913 3798133 VV 0.077 1 9.674 1,1-Dichloroethane 1· 8.855 6182914 VV 0.073 1 20.215 c-12Diclethene; 22Diclpropane
9.241 1542880 VV 0.063 1 9.015 Bromochloromethane
9.380 4219947 VV 0.063 1 9.136 Chloroform
I . 625 4356134 VV O. 081 1 9. 721 1, 1, 1-Trichloroethane
. .875 8105650 VV 0.070 1 20.491 Carbon Tetracl; 22Diclpropane
10.245 2186971 VV 0.065 1 9.418 1,2-Dichloroethane
I 11.169 4183471 VV 0.057 1 9.860 Trichloroethene
11.508 2830524 VV 0.070 1 9.597 1,2-Dichloropropane
11.701 837750 VV 0.056 1 8.991 Dibromomethane
11.930 2420626 VV 0.058 1 9.203 Bromodichloromethane I 12.574 2160473 VV 0.054 1 9.473 c-1,3-Dichloropropene
13.395 1294066 VV 0.048 1 9.291 t-1,3-Dichloropropene
13.540 1766818 VV 0.054 1-I 5.000 * Bromochloropropane *
1 13.672 1822246 VV 0.054 1 9.347 1,1,2-Trichloroethane
13. 864 5843 807 VV O. 062 1 20. 348 Tetraclethane ; 13_Diclpropane
14.266 1164242 VV 0.052 1 9.019 Dibromochloromethane
I 14. 432 924032 VV O. 063 1 9. 243 1, 2-Dibromoethane (EDB)
15.150 1408680 VV 0.049 1 9.939 Chlorobenzene
15.269 3480767 VV 0.074 1 9.410 1,1,1,2-Tetrachloroethane
I 16.416 447481 VV 0.053 1 7.888 Bromoform
16.809 627023 VV 0.053 1 1.727 $ 1,4-Dichlorobutane $
17.120 1538289 VV 0.054 1 9.538 1,1,2,2-Tetrachloroethane
I 17.177 699924 VV 0.048 1 17.441 Bromobenzene; 123triclpropane
17.406 1486840 VV 0.055 1 10.646 2-Chlorotoluene
17.572 1553202 VV 0.054 1 10.800 4-Chlorotoluene
18.561 1801762 VV 0.047 1 10.142 1,3-Dichlorobenzene
I 18.698 2100235 VV 0.055 1 10.347 1,4-Dichlorobenzene
19.281 1586340 VV 0.057 1 10.136 1,2-Dichlorobenzene
.513 104833 vv 0.057 1 7.316 1,2-Dibromo-3-chloropropane
I .. 798 1615888 VV 0.052 1 10.211 1,2,4-Trichlorobenzene
22.052 3293048 VV 0.063 1 11.265 Hexachlorobutadiene
22.571 1412198 VV 0.057 1 9.562 1,2,3-Trichlorobenzene
f:alibration table contains at least one peak with amt= O
l ta File Name
_ erator
:nstrumerit
C:\HPCHEM\l\DATA\052396\006F0101.D
RNP Page Number
HALL/PID Vial Number
I. mpie Name VSTD0l0 Injection Number
n Time Bar Code:
\c ·red on 23
I~ -·t Created on: 23
st Recalib on : 23
ltiplier : 1
May 96
May 96
May 96
11:37
01:35
01:35
AM
PM
PM
Sequence Line
Instrument Method:
Analysis Method
Sample Amount
IS'I'D Amount
2
6
1
1
502 HAL.MTH
502 HAL.MTH
0
5
1-==========================================================================
=
-
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I 0
I
I
I ()1 -
I
I -
I
I
I ,...
()1 -
-1
I
-
I
I
I Data File
-fl)
Jlime
Cperator
nstrument
;-,le Name
-
f Time Bar Code:
cquired on :
eport Created on:
Last Recalib on
rultiplier
fl)
0
(b
()1
'.6s\\1
,,
/
>1'-
0
(b
()l
Ol
0
(b
()l '
-hlorodif~fg11"°"' l.076
"hlorOll'lt'lhone . 94 chlofide 3.593
._.,n~ lo1oelhone 4.376
-,
-
(D
0
(b
()1
-
0
(b
(ll
hlorolkaomethone 4.836
'' oelheoe 5.815
chloride 6.JJO
11-D<hloroelheoe 7.187
1,1-0<hloroelhooe 7.913
--'
(1)
. rm 9 le9s ,1,1-lricnioroe 9. , _
>=10.599
,1-Di:~oelhooe 10.m
romorr, nt IL./UI lorol)l'opone 11.508
""°'hloromelhooe I 1.9JO ,
-,.-1,J-Oichloropropene 12.574
r,,"' -' '-' o1 mill .
. .• -,~.,,...,.;;.r1rtll!!'~~fflho"' 1'.166 . "' ._ " ---... -Mrochloroethone 15.269
16.101 :,omoform 16.416
! 1.4-0ichkuobutonet 16.809_. 1,~wm_m 17,110
-lii!llf, 71
•18.091 •-~•ita'e!lr' 18.561
1-D<hlo<obonl"' 19.181
19.675
6-1J-Oibromo-J-chlorop1opone 20.513
1.2.4-lri.:~obeniene 21.798
I/
xochlo1obulodit>ne 22.052
'1.3-lrichlorobenzene 22.511
Jill
C:\HPCHEM\1\DATA\052396\006F0101.D
RNP Page Number
HALL/PID Vial Number
VSTD0l0 Injection Number
-•
23
23
23
1
May
May
May
96
96
96
11:37
01:36
01:35
AM
PM
PM
Sequence Line
Instrument Method:
Analysis Method
Sample Amount ·
ISTD Amount
1
6
1
1
(1)
-
ne 11.169
502 HAL.MTH
502 HAL.MTR
0
5
I May 96 01:37 PM
ethod: C:\HPCHEM\1\METHODS\502_HAL.MTH
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I#
1
Amount
5.0
Fit: Linear
Origin: Force
Sample ISTD Information
Multilevel Information
page 5
'
ta File Name
·tor
C:\HPCHEM\l\DATA\052396\007F0101.D
RNP Page Number
n. ument
l mpl7 Name
HALL/PID Vial Number
VSTD02 5 Injection -Number
n Time Bar Code:
,cquired on 23
•
port Created on: 23
st Recalib on : 23
!ultiplier 1
May
May
May
96 12:44
96 01:37
96 . 01:37
PM
PM
PM
l g. 1 in C:\HPCHEM\l\DATA\052396\007F0101.D
Sequence Line
Instrument Method:
Analysis Method
Sample Amount
ISTD Amount
1
7
1
1
502 HAL.MTR
502 HAL.MTR
0
5
. t Time Area Type Width Ref# µg/L Name
i-------1------------1----1-----1-----1--------1------------------------------1
I. 3.058 3883014 BV 0.083 1 25.683_Dichlorodifluoromethane
3.372 3346659 vv 0.085 1 26.023 Chloromethane
3,570 7906025 VV 0.085 1 25.639 Vinyl chloride
I 4.171 2768671 vv 0.096 1 26.279 Bromomethane
4.356 6135703 VV 0.083 1 25.699 Chloroethane
4.817 l.24757E+007 VV 0.094 1 25.595 Trichlorofluoromethane
I 5.802 l.17684E+007 vv 0.089 1 25.457 1,1-Dichloroethene
6.706 l.08036E+007 VV 0.081 1 25.538 Methylene chloride
7.179 l.25793E+007 vv 0.066 1 25.441 t-1,2-Dichloroethene
7.891 l.20348E+007 VV 0.080 1 25.363 1,1-Dichloroet~ane
I 8.832 2.08835E+007 VV 0.071-1 51.078 c-12Diclethene; 22Diclpropane
9.218 5239010 VV 0.055 1 25.482 Bromochloromethane
9.351 l.39573E+007 VV 0.059 1 25.494 Chloroform
605 l.46073E+007 VV 0.074 1 25.520 1,1,1-Trichloroethane
.853 2.63476E+007 VV 0.075 1 50.899 Carbon Tetracl; 22Diclpropane
10.220 6569435 VV 0.062 1 25.267 1,2-Dichloroethane
I 11.144 l.36264E+007 VV 0.055 1 25.460 Trichloroethene
11.479 8529459 VV 0.061 1 25.336 1,2-Dichloropropane
11.669 2971262 VV 0.055 1 25.543 Dibromomethane
I 11.905 8201784 VV 0.058 1 25.494 Bromodichloromethane
12.553 6736859 VV 0.050 1 25.329 c-1,3-Dichloropropene
13.373 4486572 VV 0.049 1 25.531 t-1,3-Dichloropropene
13.518 1945083 VV 0.057 1-I 5.000 * Bromochloropropane *
I 13.651 5533483 VV 0.051 1 25.364 1,1,2-Trichloroethane
13.841 l.93601E+007 VV 0.061 1 50.971 Tetraclethane; 13Diclpropane
14.247 3910517 VV 0.052 1 25.442 Dibromochloromethane
I 14.407 3002060 VV 0.060 1 25.379 1,2-Dibromoethane (EDB)
15.133 4529296 VV 0.044 1 25.402 Chlorobenzene
15.260 l.12758E+007 VV 0.057 1 25.409 1,1,1,2-Tetrachloroethane
16.394 1984487 VV 0.059 1 25.854 Bromoform I 16.792 788934 VF 0.060 1 8.080 $ 1,4-Dichlorobutane $
17.108 5283561 MF 0.054 1 25.495 1,1,2,2-Tetrachloroethane
17.154 2333669 FM 0.050 1 51.023 Bromobenzene; 123triclpropane
I 17.391 4790960 FV 0.048 1 25.402 2-Chlorotoluene
17.559 4774707 VV 0.045 1 25.289 4-Chlorotoluene
18.546 6064980 VV 0.048 1 25.496 1,3-Dichlorobenzene
1 18.681 65.79366 VV 0.050 1 25.340 1,4-Dichlorobenzene
19.268 5074764 VV 0.046 1 25.387 1,2-Dichlorobenzene
·.502 536695 VV 0.055 1 26.102 1,2-Dibromo-3-chloropropane
__ 784 5249815 PV 0.051 1 25.438 1,2,4-Trichlorobenzene I 22.047 l.04612E+007 VV 0.055 1 25.398 Hexachlorobutadiene
22.556 4714701 VV 0.054 1 25.515 1,2,3-Trichlorobenzene
falibration table contains at least one peak with amt= O
.l;a File Name
rat:or
"st:rumerit.
3ample Name
C:\RPCREM\l\DATA\052396\007F0101.D
RNP Page Number
HALL/PID Vial Number
VSTD025 Injection Number
.,n Time Bar Code:
. '" 'red on 23
~~ t Created on: 23
May 96
May 96
23 May 96
1
12:44 PM
01: 37 PM
01: 37 PM
Sequence Line
Instrument Method:
Analysis Method
Sample Amount
ISTD Amount: 1st: Recalib on
lt:iplier
'er Modified
2
7
1
1
502 HAL.MTR
502 HAL.MTR
0
5
==----------------===-============-==-----------==============================-
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
(Jl
I-'
0
I-'
(Jl
I\]
0
I\]
File i:-illme
Operator Instrument
amole Name
0
R Time Bar Code:
l c~~ired on :
eport Created on:
Last Recalib on
fultiplier
0
m
ichlorod~luoromethone 1058
I\]
0
m
loi me!honl> )J7l ITTyl chloride 1570
tho"' Woett,o,.. 056
[,J
0
m
T,ichlorofluoromeltione •.817
l:;:;:;:,:::=======---+.H;,t,lloroe\he"' 5.802
. \JI
471 F-=========----11,!!,j•"' clrtotile 6.706
l':;:::=========-----+-+.,-!lic. lnoett,e,.. 7.179
l':;:::=========----1,1-!lichlon•lm 7.891
(Jl
0
m
. 22Diclpropone 8.832
C
'fl
m
>j
, , ro:hloroet~rgt!\I~ 9.l51
Mloroelho"' 10.210
10.584
1ichloroethene 11.144
1.2-0icllloroprop(ft 11.479 , omome ronoor:lnomtlm t t.905
~-==-=--------c-lJ-!lichlor.,. ...... 1235)
f=---ll<.omoform 16.394
1,4-Dichlorobulone S 16.792
18.07)
:ifa=t~i""' 17,108
F-='=-""""========l=l. ,ilislSS!III!~ II.Mi
l';====-------11-Dichlorobenzene 19.268
19.656
: w-Oibromo-3-cl'lloropropone 20.502
1.260
~~~~~;;;;;;===;;;;t•l:::· :,:_-l!!!r<~hlor~o~be~01~•"'!_;2~1.~ljµ~fflt r, hlorobulod•"' 22.047
l'==~-----+,,J-Trichlorobenzene-22.556
l.111
m:
4.600
C:\HPCHEM\1\DATA\052396\007F0101.D
RNP Page Number
HALL/PID Vial Number
VSTD025 Injection Number
23
23
23
1
May
May
May
96
96
96
12:44
01:37
01:37
PM
PM
PM
Sequence Line
Instrument Method:
Analysis Method
Sample Amount
ISTD Amount
1
7
1
1
502 HAL.MTH
502 HAL.MTH
0
5
•======~==·==========-===================--=---====-===-=======================
■ . . Calibration Report
iata File Name
c ·a tor
L.~ crument :
ISample Name :
Run Time Bar Code:
C:\HPCHEM\1\DATA\052396\007R0101.D
RNP Page Number
HALL/PID Vial Number
VSTD025 Injection Number
1
7
1
1
Acquired on : 23 May 96
May 96
May 96
12: 44 PM
01:42 PM
PM
Sequence Line
Instrument Method: 502 HAL.MTH
502 PID.MTH
0 •
Report Created on: 23
Last Recalib on : 23
Multiplier
I
.Pk# l
I
2
I
I 3
I
I
I
I
I
I
I
I
I
I
4
5
6
7
8
9
RT
3.554
5.783
7.154
7.968
8.820
9.837
10.157
10.578
11.125
Lvl
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
6
1
2
3
1
µg/L
1. 0
2.0
5.0
10.0
25.0
1.0
2.0
5.0
10.0
25.0
2.0
4.0
10.0
20.0
50.0
1. 0
2.0
5.0
10.0
25.0
1.0
2.0
5.0
10.0
25.0
1.0
2.0
5.0
10.0
25.0
1.0
2.0
5.0
10.0
25.0
5.0
5.0
5.0
5.0
5.0
5.0
1. 0
2.0
5.0
01:41
Analysis Method
Sample Amount
ISTD Amount 5
Calibration Table
Amt/Area
1.3057e-004
1.396le-004
1. 7795e-004
l.2078e-004
8.5139e-005
2.8662e-005
4.5343e-005
5.8424e-005
3.7525e-005
2.7759e-005
.3 .2071e-005
3.3696e-005
4.3708e-005
3.0559e-005
2.1487e-005
5.0449e-005
5.2996e-005
6.7119e-005
5.0629e-005
3. 53 98e-005
3.7671e-005
3.9604e-005
5.1926e-005
3.7374e-005
2.6221e-005
3.9757e-005
4.2077e-005
5.5087e-005
3.635e-005
2.5145e-005
1.6882e-005
l.7635e-005
2.3127e-005
1. 6051e-005
1.1266e-005
1.024e-005
1.0446e-005
1.0581e-005
1.05Ble-005
1.0444e-005
8.4115e-006
2.8564e-005
3.006Be-005
3.9482e-005
Ref Istd I# Name
1 (H) Vinyl chloride
1 (H) 1,1-Dichloroethe ...
1 MTBE (H) t-12DCE
1 DIPE
1 (H) c-12dce
1 (H) 11-Diclpropene
1 Benzene
ISTD 1 * Fluorobenzene *
1 (H) Trichloroethene
13 4 10.0 2.6409e-005
May 96-. 01: 42 PM page 2
Method: C:\HPCHEM\l\METHODS\502 PID.MTH
I 5 25.0 l.Bl6e-005
11.553 1 0.0 0.0 1 $ a,a,a-Trifluorotol ...
I 6 5.0 2.657le-005
11 12.535 1 1.0 l.OB54e-004 1 (H) c-13pene
2 2.0 l.1834e-004
3 5.0 l.4614e-004
I 4 10.0 1. 05Be-004
5 25.0 7.1348e-005
12 13.015 1 1.0 l.B385e-005 1 Toluene
I 2 2.0 1. 9402e-005
3 5.0 2.5539e-005
4 10.0 l.7343e-005
I 5 25.0 l.2055e-005
13 13.356 1 1.0 l.122le-004 1 (H) t-13pene
2 2.0 l.2017e-004
3 5.0 l.4696e-004
I 4 10.0 l.068le-004
5 25.0 7.102Be-005
14 13.823 1 1.0 3.7677e-005 1 (H) Tetrachloroethen ...
I 2 2.0 4.09Ble-005
3 5.0 5.2653e-005
4 10.0 3.4575e-005
I 5 25.0 2.3243e-005
15 15.114 1 1.0 l.9777e-005 1 (H) Chlorobenzene
2 2.0 2.1274e-005
3 5.0 2.7584e-005
I 4 10.0 1. 915le-005
5 25.0 l.325le-005
16 15.264 1 1. 0 2.0299e-005 1 Ethylbenzene
I 2 2.0 2.1626e-005
3 5.0 2.812e-005
4 10.0 1. B688e-005
I
5 25.0 l.2855e-005
17 15.439 1 2.0 l.7941e-005 1 m-Xylene ; p-Xylene
2 4.0 1. ~21e-005
3 10.0 2.4871e-005
I 4 20.0 l.6586e-005
5 50.0 1.1478e-005
18 16.058 1 2.0 2.1083e-005 1 o-Xylene ; Styrene
I 2 4.0 2.261e-005
3 10.0 2. 9411e-005
4 20.0 2.0159e-005
5 50.0 l.3967e-005
I 19 16.596 1 1. 0 2.7783e-005 1 Isopropylberizene
2 2.0 2.97e-005
3 5.0 3.8792e-005
I 4 10.0 2.5291e-005
5 25.0 1. 7315e-005
20 17.081 1 1.0 2.3745e-005 1 (H) Bromobenzene
I 2 2.0 2.6265e-005
3 5.0 3.3716e-005
4 10.0 2.3583e-005
5 25.0 1.6098e-005
I 21 17.228 1 1.0 2.2457e-005 1 n-Propylbenzene
2 2.0 2.4127e-005
3 5.0 3.108e-005
I 4 10.0 2.04e-005
5 25.0 l.3932e-005
I 22 17.373 1 1.0 2.1402e-005 1 (H) 2Cltoluene
23 May 96. 01:42 PM page 3
Method: C:\HPCHEM\1\METHODS\502 PID.MTH
I 2 2.0 2.291Be-005
3 5.0 2.9754e-005
4 10.0 2.002Be-005
I 5 25.0 1. 3759e-005
23 17.501 1 2.0 l.777e-005 1 135-Trimethylbenz
2 4.0 l.932e-005
I 3 10.0 2.4964e-005
4 20.0 1.6722e-005
5 50.0 1.1547e-005
I 24 18.000 1 1.0 2.7902e-005 1 tert-Butylbenzene
2 2.0 3.0173e-005
3 5.0 3.9414e-005
4 10.0 2.5816e-005
I 5 25.0 l.7741e-005
25 18.077 1 1.0 2.034Be-005 1 124-Trimethylbenzene
2 2.0 2 .2671e-005.
I 3 5.0 2.9069e-005
4 10.0 1.9403e-005
5 25.0 1.3376e-005
26 18.340 1 1.0 2.5876e-005 1 sec-Butylbenzene
I 2 2.0 2.8902e-005
3 5.0 3.685Be-005
4 10.0 2.3933e-005
I 5 25.0 1.6417e-005
27 18.540 1 2.0 2.5737e-005 1 p-Isopropyltoluene I • • •
2 4.0 2.8287e-005
I 3 10.0 3.6089e-005
4 20.0 2.4144e-005
5 50.0 1.6547e-005
28 18.667 1 1.0 2.5585e-005 1 (H) 14dcb
I 2 2.0 2.8674e-005
3 5.0 3.6241e-005
4 10.0 2.4561e-005
I 5 25.0 1.6891e-005
29 19.207 1 2.0 2.9943e-005 1 n-Butylbenzene (H) ...
2 4.0 3.3407e-005
I 3 10.0 4.2639e-005
4 20.0 2.85e-005
5 50.0 1.9636e-005
30 21.766 1 1. 0 4.5629e-005 1 (H) 124-Triclbenzene
I 2 2.0 6.3356e-005
3 5.0 7.5885e-005
4 10.0 5.266e-005
I 5 25.0 3.5716e-005
31 22.024 1 1. 0 3.9713e-005 1 (H) Hexaclbutadiene
2 2.0 5.6445e-005
I 3 5.0 7.2376e-005
4 10.0 4.7387e-005
5 25.0 3.2589e-005
32 22.155 1 1.0 5.6432e-005 1 Naphthalene
I 2 2.0 7.5487e-005
3 5.0 9.6743e-005
4 10.0 7.279e-005
I 5 25.0 5.024e-005
33 22.539 1 1. 0 4.7601e-005 1 (H) 123Triclbenzene
2 2.0 6.9779e-005
I 3 5.0 9. 3499e-005
4 10.0 6.7092e-005
I
'
· 5 25.0 4.5066e-005
3 May 96 01:42 PM
ethod: C:\HPCHEM\l\METHODS\502 PID.MTH
I
l it le:
8021 HALL 5mL
'
eference window:
on-reference window:
nits of amount:
lultiplier:
F uncal peaks:
STD# to adjust uncal peaks:
Sample Amount:
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I#
1
Amount
5.0
Fit: Linear
Origin: Force
Calibration Settings
5.000 %
5.000 %
µg/L
1. 0
0.0
0
0.0
Sample ISTD Information
Multilevel Information
page 4
(
==========================-===================================----===---======
_ _ Internal Standard Report
-----.---------------------------------------------------------=----=----======
fa:>ata File Name
•--rater
~rument
113ampl7 Name IJ<.un Time Bar Code:
C:\HPCHEM\l\DATA\052396\003R0101.D
RNP Page Number
HALL/PID Vial Number
VSTD00l Injection Number
Sequence Line
Instrument Method:
1
3
1
1
Acquired on 23 May
May
May
96
96
96_
10:04
01:39
01:39
AM
PM
PM
Analysis Method
Sample Amount
ISTD Amount
502 HAL.MTH
502 PID.MTH
0 l eport Created on: 23
ast Recalib on : 23
ultiplier : 1 5
-.Sig. 2 in C:\HPCHEM\l\DATA\052396\003R0101.D _
IIRet Time Area Type Width Ref# µg/L Name l-------l------------l----l-----l-----1--------1------------------------------I
I l.558 7659 PB 0.080 1 1.449 (HI Vinyl chloride
5.787 34890 VV 0.112 1 1.976 (HI 1,1-Dichloroethene
7 .157 62361 BB 0. 074 1 2. 932 "MTBE ; (H) t-12DCE
I
I
I
I
I
I
I
I
I
7.972 19822 BB 0.087 1 1.540 DIPE
8.823 26545 BB 0.064 1 1.513 (H) c-12dce
9.841 25153 BB 0.062 1 1.527 (H) 11-Diclpropene
10.162 59236 BB 0.060 1 1.521 Benzene
10.583 488264 BB 0.058 1-I 5.000 * Fluorobenzene *
11.130 35009 BB 0.055 1 1.578 (HI Trichloroethene
11.553 155276 EV 0.060 1 0.000 $ a,a,a-Trifluorotoluene $
12.540 9213 EV 0.049 1 1.642 (H) c-13pene
13.020 54391 BB 0.050 1 1.618 Toluene
13.362 8912 EV 0.045 1 1.630 (HI t-13pene
13.828 26542 PB 0.052 1 1.580 (HI Tetrachloroethene
S.119 50564 EV· 0.047 1 1.709 (H) Chlorobenzene
i5.268 49264 VV 0.049 1 1.657 Ethylbenzene
15.442 111478 VB 0.048 1 3.152 m-Xylene; p-Xylene
16.062 94864 BB 0.058 1 2.908 o-Xylene; Styrene
16.601 35993 EV 0.051 1 1.689 Isopropylbenzene
17.086 42115 EV 0.046 1 1.777 (HI Bromobenzene
17.232 44529 VV 0.048 1 1.698 n-Propylbenzene
17.376 46724 VV 0.047 1 1.675 (HI 2Cltoluene
17.506 112548 VV 0.075 1 3.445 135-Trimethylbenz ; (HI 4Cltol
18.004 35840 VV 0.051 1 1.706 tert-Butylbenzene
18.081 49145 VV 0.049 1 1.683 124-Trimethylbenzene
18.343 38645 VV 0.052 1 1.706 sec-Butylbenzene
18. 544 77709 PV 0. 071 1 3. 506 p-Isopropyltoluene ; (H) 13dcb
18.671 39085 VV 0.045 1 1.716 (H) 14dcb
19. 212 66794 PV 0. 073 1 3. 580 n-Butylbenzene ; (H) 12dcb
21.771 21916 VV 0.046 1 2.139 (H) 124-Triclbenzene
22.029 25181 vv 0.060 1 1.942 (HI Hexaclbutadiene
22.161 17721 VV 0.045 1 2.270 Naphthalene
22.544 21008 PV 0.049 1 2.253 (HI 123Triclbenzene
.Calibration table contains at least one peak with amt= 0
I
I
I
0
0
Ill
[0
0
Ill
(,J
0
Ill
()1
0
m
,L
(j)
0
m
✓
0
Ill
,L
(lJ
0
Ill
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
o ..... ~~,....._.~-'--'----'----'~~~'-'--~~-'--'-~~-'-'-~~--'-'~~-"-'-'--~-----"--~
()1
,..
0
,..
()1
[0
0
I Data File ~me
Operator
D Instrument
Sample Name
r Time Bar Code:
,uired on I Report Created on:
Last Recalib on
Multiplier
I
H) V"'YI ch•<ide 1558
H) 1, l-Oichloroethene 5. 787
t==~--iH) c-11dce 8813
H) 11-0ic:lpropene 9.W
nzene 10.162
t===---jH) T1ichlo1oeth,e,ne 11.130
!::========--------'I o.o.o-Trifluorotofuene I 11.553
'n's\!!"' IJ.361
F---iH) Tetrochloroethene 13.828
~~~~;;;;:;;;;3JJ/&fJ!flflP~ll'ff!B~l5~.l~t9:._• ---m t:: -Xylene: p-Xylene 15.U2
l====~=-----<>-Xylene: Styrene 16.062
1.161
C:\HPCHEM\l\DATA\052396\003R0101.D
RNP Page Number
HALL/PID Vial Number
VSTD00l Injection Number
23
23
23
1
May 96
May 96
May 96
10:04
01:39
01:39
AM
PM
PM
Sequence Line
Instrument Method:
Analysis Method
Sample Amount
ISTD Amount
1
3
1
1
502 HAL.MTH
502 PID.MTH
0
5
•
===========================-==--------==--====-====---=========================
.. Internal Standard Report
IData File Name
r-,rator
~rument
1Sampl7 Name
Run Time Bar Code:
C:\HPCHEM\1\DATA\052396\004R0101.D
RNP Page Number
HALL/PID Vial Number
VSTD002 Injection Number
1
4
1
1
Acquired on 23
•
Report Created on: 23
Last Recalib on : 23
May 96
May 96
May. 96
10:35
01:40
01:40
AM
PM
PM
Sequence Line
Instrument Method:
Analysis t'.lethod
Sample Amount
ISTD Amount
502 HAL.MTH
502 PID.MTH
0
Multiplier : 1 5
lsig. 2 in C:\HPCHEM\1\DATA\052396\004R0101.D
Ret Time Area Type Width Ref# µg/L Name
l-------l------------l----l-----l-----1--------1-----------------------"------I
I 3. 574 -14326 PV 0. 087 1 2 .119 (H) Vinyl chloride -
5.803 44108 BV 0.086 1 2.307 (H) 1,1-Dichloroethene
I
I
I
I
I
I
I
I
I
I
I
I
I
7.173 118710 BV 0.073 1 4.374 MTBE ; (H) t-12DCE
7.985 37739 BV 0.085 1 2.246 DIPE
8.837 50499 BV 0.063 1 2.255 (H) c-12dce
9.854 47532 BV 0.062 1 2.204 (H) 11-Diclpropene
10.175 113411 PV 0.059 1 2.267 Benzene
10.596 478649 BV 0.057 1-I 5.000 * Fluorobenzene *
11.143 66516 VB 0.054 1 2.253 (H) Trichloroethene
11. 565 152185 BV 0.061 1 0.241 $ a,a,a-Trifluorotoluene $
12.551 16901 BV 0.049 1 2.278 (H) c-13pene
13.032 103080 PV 0.051 1 2.293 Toluene
13.373 16643 BV 0.045 1 2.264 (H) t-13pene
13.839 48804 BV 0.051 1 2.177 (H) Tetrachloroethene
,.130 94012 BV 0.046 1 2.332 (H) Chlorobenzene
.1.5. 279 92479 w 0.048 1 2.296 Ethylbenzene
15.453 208226 w 0.048 1 4.562 m-Xylene ; p-Xylene
16.073 176914 BV 0.058 1 4.358 o-Xylene ; Styrene
16.611 67339 BV 0.051 1 2.285 Isopropylbenzene
17.096 76146 BV 0.046 1 2.367 (H) Bromobenzene
17.242 82896 w 0.048 1 2.290 n-Propylbenzene
17.387 87266 w 0.047 1 2.341 (H) 2Cltoluene
17.514 207035 w 0.069 1 4.645 135-Trimethylbenz ; (H) 4Cltol
18.014 66284 w 0.051 1 2.287 tert-Butylbenzene
18.091 88218 w 0.047 1 2.326 124-Trimethylbenzene
18.353 69198 w 0.051 1 2.242 sec-Butylbenzene
18.552 141407 w 0.070 1 4.629 p-Isopropyltoluene ·; (H) 13dcb
18.681 69749 w 0.044 1 2.271 (H) 14dcb
19.221 119737 BB 0.068 1 4.655 n-Butylbenzene ; (H) 12dcb
21.779 31567 PV 0.043 1 2.451 (H) 124-Triclbenzene
22.037 35433 w 0.053 1 2.259 (H) Hexaclbutadiene
22.169 26495 w 0.045 1 2.613 Naphthalene
22.552 28662 PB 0.047 1 2.533 (H) 123Triclbenzene
Calibration table contains at least one peak with amt= 0
==============================-=-=---------------------------------------------
0
0
ffi
[\)
0
ffi
(.J
0
ffi
()1
0
ffi
Ol
0
ffi
-,j
0
ffi
[D
0
ffi
iL
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
o+-~---'-+___j__J~~_[_L___j__J~'----'-~---'-'-___,_____~_.__J..._~___j__J_L_'----'-~--'--"~'----'---1-L~
()1
f-0
0
f-0
()1
[\)
0
lnata File :me
Operator
•
Instrument :
Sample Name :
F · Time Bar Code:
, uired on : I Report Created on:
Last Recalib on :
I
Multiplier
H) Vinyl chloride 3.57'
.176
.284
t==--ilHI 1.1-D<hloro,11,,. 5.803
l::=:=====----18[: (HI 1-110C[ 7.173
~~-{ IP[ 7.981
t===--iHI c-11dc• 8.837
l===-----iH) Trichloroelhene 11.143
i:========--------!S o.o.o-lr~luoro\oluene l 11.565
14.408
11.IJO ne: p-X~e11e 15.453
t=========-----------0-x,.,.: s,~.,,. 16013
1====-----..js,opropylbenzene 16.611
H
131-1<""1",ibenz : (HI <Cltol 17.514
1l!Jl" thylbenzent 18.091
ec-B• be,,.,. 18. -~opropyl,....: (H) 1Jdcb 18.111
l::=======----8,1~benzen,: (HI 11dcb 19111
IU~J~'l'l'o)\779
----!H] 123iriclbenzeoe 22.552
11,3
C:\HPCHEM\1\DATA\052396\004R0101.D
RNP Page Number
HALL/PID Vial Number
VSTD002 Injection Number
23
23
23
1
May 96
May 96
May 96
10:35
01:40
01:40
AM
PM
PM
Sequence Line
Instrument Method:
Analysis Method
Sample Amount
ISTD Amount
1
4
1
1
502 HAL.MTH
502 PID.MTH
0
5
•
========== =========================================================-====--===-
.. Internal Standard Report
•Data File Name
r 'rator
trument
C:\HPCHEM\l\DATA\052396\005R0101.D
RNP Page Number
HALL/PID Vial Number
1
5
1
1
'
Sample Name
Run Time Bar Code:
VSTD005 Injection Number
SeEJUence Line
Instrument Method: 502 HAL.MTH
502 PID.MTH
0
Acquired on 23
I Report Created on: 23
Last Recalib on : 23
Multiplier : 1
May 96
May 96
May 96
11:06
01:41
01:40
AM
PM
PM
Analysis Method
Sample Amount
!STD Amount 5
lsig. 2 in C:\HPCHEM\l\DATA\052396\005R0101.D
Ret Time Area Type Width Ref# µg/L Name
l-------l------------l----l----0 1-----1--------1------------------------------I
I 3.578 28097 PV 0.088 1 3.575 IHI Vinyl chloride
5.811 85582 BV 0.087 1 3.983 (HI 1,1-Dichloroethene
7.181 228791 BV 0.073 1 7.410 MTBE ; (HI t-12DCE
I 7.993 74495 BV 0.084 1 3.800 DIPE
8.844 96290 BB 0.063 1 3.790 (HI c-12dce
9.860 90766 PV 0.061 1 3.621 (HI 11-Diclpropene
I
I
I
I
I
I
I
I
10.181 216200 PB 0.060 1 ·3.751 Benzene
10.602 472532 BB 0.058 1-I 5.000 * Fluorobenzene *
11.148 126640 BB 0.055 1 3.648 (HI Trichloroethene
11.570 149045 BV 0.060 1 4.982 $ a,a,a-Trifluorotoluene $
12.555 34213 BV 0.049 1 3.805 (HI c-13pene
13.035 195780 BB 0.050 1 3.699 Toluene
13.376 34024 BV 0.045 1 3.805 (HI t-13pene
13.843 94961 BB 0.051 1 3.568 (HI Tetrachloroethene
5.132 181263 BV 0.046 1 3.738 (HI Chlorobenzene
15.281 177808 VV 0.048 1 3.669 Ethylbenzene
15.456 402071 VB 0.048 1 7.302 m-Xylene; p-Xylene
16.075 340011 BV 0.058 1 7.474 o-Xylene; Styrene
16.613 128893 BV 0.051 1 3.607 Isopropylbenzene
17.098 148299 BV 0.045 1 3.745 (H) Bromobenzene
17.244 160875 VV 0.048 1 3.635 n-Propylbenzene
17.389 168042 VV 0.047 1 3.671 (H) 2Cltoluene
17.517 400570 VV 0.074 1 7.309 135-Trimethylbenz ; (HI 4Cltol
18.015 126858 VV 0.051 1 3.616 tert-Butylbenzene
18.092 172006 VV 0.047 1 3.627 124-Trimethylbenzene
18.354 135657 VV 0.052 1 3.583 sec-Butylbenzene
18.555 277090 VV 0.070 1 7.289 p-Isopropyltoluene ; (HI 13dcb
18.682 137965 VB 0.045 1 3.581 (H) 14dcb
19. 222 234527 VB O. 068 1 7. 272 n-Butylbenzene ; (H) 12dcb
21.779 65889 BV 0.045 1 3.647 (H) 124-Triclbenzene
22.037 69084 PV 0.053 1 3.533 (HI Hexaclbutadiene
22.169 51683 VB 0.044 1 3.816 Naphthalene
22.552 53477 BB 0.046 1 3.629 (H) 123Triclbenzene
I Calibration table contains at least one peak with amt= 0
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
()l
I-'
()l
f'J
0
0
iData File J1me
Operator
[I Instrument
lJ Sample Name
r Time Bar Code:
!1 i Jired on :
flReport Created on:
Last Recalib on :
n Multiplier
0
m
.171
f'J
0
m
H) Vinyl chloride 1578
Gl
0
m
t;::;;;:c===---{H) 1,1-Mornelhe,e 5.811
.109
.714
()l
0
m
Ol
0
m
✓
0
m
\::============-------<18[: (H) 1-12DC[ 7.181
t::====--Of[ 7.99J
t:=====------{'H) c-12dce 884'
F=======-------{H] lrichloroelhene 11.148
i;::ff"1r======--------I o.o.o-lr~luorotoluer.e I ! 1.570
CD
0
m
ec-Bul lbt>nze 124-lrimelhylbenzene 18,092
oh,,. : (HI 1 Jocb 18.511
l:==============-------,-8u1ylbeoze,e: (H) 12dcb 19.222
J.160
H 1/1,_Tjic1beoz,8jf1.779 P ~1lwiene fl.
H) 1231ricfbenzer.e 22.552
C:\HPCHEM\l\DATA\052396\005R0101.D
RNP Page Number
HALL/PID Vial Number
VSTD005 Injection Number
23-
23
23
1
May 96
May 96
May 96
11:06
01:41
01:40
AM
PM
PM
Sequence Line
Instrument Method:
Analysis Method
Sample Amount
ISTD Amount
1
5
1
1
502 HAL.MTR
502 PID.MTH
0
5
•
==========·==================-=-=========--------==============================
._ Internal Standard Report _
IData File Name
r ,ator
C:\HPCHEM\l\DATA\052396\006R0101.D
RNP Page Number 1
6
1
1
.:rument HALL/PID Vial Number
•
Sample Name
Run Time Bar Code:
VSTD0l0 Injection Number
Sequence Line
Instrument Method: Acquired on 23
IReport Created on: 23
Last Recalib on : 23
Multiplier : 1
May 96
May 96
May 96
11:37
01:41
Q.J.:41
AM
PM
PM
Analysis Method
Sample Amount
ISTD Amount
502 HAL.MTH
502 PID.MTH
0
5
lsig. 2 in C:\HPCHEM\l\DATA\052396\006R0101.D
Ret Time Area Type Width Ref# µg/L Name
1-------1------------1----1-----1-----1--------1------------------------------1
I 3. 570 . 82797 PV 0. 086 1 8 .114 (H) Vinyl chloride
5.806 266489 VV 0.089 1 10.649 (H) 1,1-Dichloroethene
I
I
I
I
I
I
I
I
I
7.177
7.990
8.842
9.860
10.181
10.601
11.149
11.571"
12.557
13.037
13.377
'3. 844
5.132
15.281
15.456
16.074
16.613
17.097
17.243
17.388
17.516
18.014
18.091
18.353
18.554
18.680
19.220
21.779
22.037
22.169
22.552
654478 BB
197515 BV
267569 BV
275106 PV
623016 VV
472559 VV
378660 VV
149052 VV
94516 BV
576613 BV
93622 VV
289222 VB
522166 BV
535098 VV
1205858 VV
992105 VV
395393 VV
424034 VV
490194 VV
499309 VV
1196004 VV
387356 VV
515384 VV
417829 VV
828364 VV
407147 VV
701752 VV
189897 BV
211029 VV
137381 VV
149048 VV
0.073
0.086
0.063
0.062
0.060
0.058
0.055
0.060
0.049
0.051
0.046
0.051
0.046
0.048
0.049
0.058
0.051
0.045
0.048
0. 047
0.074
0.051
0.048
0.052
0.070
0.045
0.073
0.045
0.053
0.045
0.046
1
1
1
1
1
1-I
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
17.420 MTBE ; (H) t-12DCE
8.059 DIPE
8.496 (H) c-12dce
9.310 (H) 11-Diclpropene
8.731 Benzene
5.000 * Fluorobenzene *
8.998 (H) Trichloroethene
4.982 $ a,a,·a-Trifluorotoluene $
8.353 (H) c-13pene
9.126 Toluene
8.288 (H) t-13pene
9.587 (H) Tetrachloroethene
9.091 (H) Chlorobenzene
9.581 Ethylbenzene
19.123 m-Xylene ; p-Xylene
19.980 o-Xylene ; Styrene
9.841 Isopropylbenzene
8.972 (H) Bromobenzene
10.054 n-Propylbenzene
9.533 (H) 2Cltoluene
19.373 135-Trimethylbenz ; (H) 4Cltol
9.987 tert-Butylbenzene
9.554 124-Trimethylbenzene
10.166 sec-Butylbenzene
19. 362 p-lsopropyltoluene ; (H) 13dcb
9.183 (H) 14dcb
19.461 n-Butylbenzene; (H) 12dcb
9.007 (H) 124-Triclbenzene
10.064 (H) Hexaclbutadiene
8.500 Naphthalene
8.575 (H) 123Triclbenzene
I Calibration table contains at least one peak with amt= 0
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I Data File
Operator
()l
I-'
0
I-'
()l
[\)
0
[\)
JAme
I Instrument
Sample Name
F Time Bar Code:
0
Ill
1.991
[\)
0
Ill
[;)
0
Ill
,fl.
0
Ill
()l
0
Ill
I})
0
Ill
✓
0
Ill
(ll
0
Ill
t::=========-----OIIP[ 7.990
t==============-------------1,H) c-11dce 8841
19.996
10.490
S o.o,o-lr~luorololuene S 11.571
H) 1-1Ji,oe ll.377
op
C:\HPCHEM\l\DATA\052396\006R0101.D
RNP Page Number
HALL/PID Vial Number
·clpropene 9.860
-jriclben,eoc11179 Hexoc b0001ene (l.037
VSTD0l0 Injection Number
1
6
1
1
I ; 1ired on : 23
Report Created on: 23
Last Recalib on : 23
1 Multiplier 1
May 96
May 96
May 96
11: 37
01:41
01:41
AM
PM
PM
Sequence Line
Instrument Method:
Analysis Method
Sample Amount
ISTD Amount
502 HAL.MTH
502 PID.MTH
0
5
'
========== =-=======================-==============================-===========
, · Internal Standard Report ·
------·-------======---========-=-------==-------===-=============---=====------
IData File Name
0--ca tor
.rument
C:\HPCHEM\l\DATA\052396\00'lR0101.D
RNP Page Number
HALL/PID Vial Number
1
7
1
1 •
Sample Name
Run Time Bar Code:
VSTD025 Injection Number
Sequence Line
~nstrument Method: 502 HAL.MTH
502 PID.MTH
0
Acquired on 23
IReport Created on: 23
Last Recalib on : 23
Multiplier : 1
May 96
May 96
May 96
12:44 PM
01:42 PM
01 :42 PM
Analysis Method
Sample Amount
ISTD Amount 5
•
Sig. 2 in C:\HPCHEM\l\DATA\052396\007R0101.D
Ret Time Area Type Width Ref# µg/L Name 1-------l------------l----l-----l-----l--------1------------------------------1
I 3.554 293636 PV 0.079 1 25.730 (H) Vinyl chloride
5.783 900615 BV 0.085 1 25.683 (H) 1,1-Dichloroethene
7.154 2327039 BV 0.072 1 51.478 MTBE; (H) t-12DCE
I 7.968 706262 VV 0.086 1 25.752 DIPE
8.820 953450 BV 0.062 1 25.748 (H) c-12dce
9.837 994252 PV 0.062 1 25.763 (H) 11-Diclpropene
10.157 2219158 VV 0.060 1 25.743 Benzene
10.578 478761 VV 0.059 1-I 5.000 * Fluorobenzene *
11.125 1376633 VV 0.055 1 25.774 (H) Trichloroethene I
11.548 152475 VV 0.061 1 -1.586 $ a,a,a-Trifluorotoluene $
12.535 350393 BV 0.049 1 25.806 (H) c-13pene
13.015 2073842 BV 0.051 1 25.759 Toluene
13.356 351975 VV 0.046 1 25.826 (H) t-13pene I
73.823 1075571 VV 0.051 1 25.808 (H) Tetrachloroethene
i .114 1886589 BV 0 .. 046 1 25. 767 (H) Chlorobenzene
~5.264 1944735 VV 0.049 1 25.772 Ethylbenzene I
15.439 4356026 VV .0.049 1 51.524 m-Xylene; p-Xylene
.16.058 3579813 VV 0.059 1 ·51.529 o-Xylene; Styrene
16.596 1443801 VV 0.051 1 25.779 Isopropylbenzene I
17.081 1553007 VV 0.045 1 25.791 (H) Bromobenzene
17. 228 1 794368 VV 0. 049 1 . 25. 782 n-Propylbenzene
17.373 1816964 VV 0.047 1 25.776 (H) 2Cltoluene
17.501 4330222 VV 0.069 1 51.535 135-Trimethylbenz ; (H) 4Cltol I
18.000 1409138 VV 0.051 1 25.775 tert-Butylbenzene
18.077 1869065 VV 0.047 1 25.770 124-Trimethylbenzene
18.340 1522792 VV 0.052 1 25.775 sec-Butylbenzene
18. 540 3021762 VV 0. 071 1 51. 556 p-Isopropyltoluene ; (H) 13dcb
I
18.667 1480086 VV 0.045 1 25.774 (H) 14dcb
19. 207 2546380 VV 0. 067 1 51. 541 n-Butylbenzene ; (H) 12dcb
21.766 699972 BV 0.045 1 25.809 (H) 124-Triclbenzene
22.024 767118 VV 0.052 1 25.796 (H) Hexaclbutadiene
22.155 497613 VV 0.045 1 25.801 Naphthalene
22.539 554743 VV 0.046 1 25.861 (H) 123Triclbenzene·
I
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I calibration table contains at least one peak with amt= 0
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11.979
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.
. S o,o,o-Trifloorotoluene S 11.~8
.
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.... :.1
~l.647
14.500
I Data File
. l\l
i-ffime C:\HPCHEM\l\DATA\052396\007R0101.D
Operator RNP Page Number
I Instrument :
Sample Name :
r Time Bar Code:
HALL/PID Vial Number
VSTD025 Injection Number
Sequence Line
Instrument Method:
I . Jired on : 23
kc~ort Created on: 23
Last Recalib on : 23
I
Multiplier 1
May 96
May 96
May 96
12: 44 PM
01:42 PM
01:42 PM
Analysis Method
Sample Amount
ISTD Amount
1
7
1
1
502 HAL.MTH
502 PID.MTH
0
5
I
I
I
I
I
I
I
I
I
I
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I
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I
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I
I
PARADIGM ANALYTICAL LABORATORIES, INC.
Continuing Calibration Report
ICal Date: 052396
CCal Date 052396
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butvlbenzene
sec-Butvlbenzene
tert-Butvlbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
Dibromochloromethane
1,2-Dibromo-3-chloropropane
1,2-Dibromoethane IEDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1 ,4-Dichlorobenzene
Dichlorodifluoromethane
1, 1-Dichloroethane
1,2-Dichloroethane
1, 1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloroorooane
2,2-Dichloroorooane
cis-1,3-Dichloroorooane
trans-1,3-Dichlorooropane
Diisooronvl ether
Ethvlbenzene
Hexachlorobutadiene
lsopronvlbenzene
D-lsooronvltoluene
Methvl-tert butvl ether
Methvlene Chloride
Naphthalene
n-Pronvlbenzene
Stvrene
1, 1, 1,2-Tertrachloroethane
1, 1,2,2-Tertrachloroethane
Curve QCCK
1.038 1.064
0.347 0.338
0.626 0.698
· 1.041 1.115
0.182 0.186
0.135 0.251
1.156 1.236
0.734 0.716
0.685 0.654
3.662 3.857
0.608 0.657
0.720 0.933
2.006 2.197
0.372 0.396
0.410 0.691
0.636 0.720
0.463 0.525
0.027 0.047
0.373 0.396
0.284 0.340
0.679 0.760
0.795 0.881
0.897 1.037
0.490 0.493
1.576 1.801
0.990 1.085
1.574 1.723
2.961 3.210
1.698 1.906
1.406 1.386
3.662 3.857
0.920 1.017
0.565 0.599
0.340 0.340
0.878 0.906
1.491 1.930
0.565 0.664
1.363 1.432
1.090 1.127
1.569 1.655
0.250 0.315
0.863 0.829
1.651 1.703
1.561 .1.759
0.642 0.708
Page 1
%0
-2.5
2.6
-11.0
-6.9
-1.9
-60.0
-6.7
2.5
4.6
-5.2
-7.7
-25.8
-9.1
-6.1
-51.1
-12.5
-12.5
-53.4
-6.0
-17.9
-11.3
-10.3
-14.5
-0.7
-13.3
-9.1
-9.0
-8.1
-11.6
1.4
-5.2
-10.1
-5.7
0.1
-3.2
-25.6
-16.2
-5.0
-3.3
-5.3
-22.8
4.0
-3.1
-11.9
-9.7
I
I
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PARADIGM ANAL)TICAL LABORATORIES, INC.
Continuing Calibration Report
Tetrachloroethene 2.764 2.949 -6.5
Toluene 0.956 0.989 -3.5
1,2,3-Trichlorobenzene 0.647 0.975 -40.5
1,2,4-Trichlorobenzene 0.725 1.004 -32.4
1, 1, 1-Trichloroethane 2.045 2.244 -9.3
1, 1,2-Trichloroethane 0.971 0.925 4.8
Trichloroethene 1.929 2.083 -7.7
Trichloroflurornethane 1.513 1.708 -12.1
1,2,3-Trichloroorooane 0.347 0.338 2.6
1,2,4-Trirnethvlbenzene 0.849 0.880 -3.6
1,3,5-Trirnethvlbenzene 1.970 2.043 -3.7
Vinvl Chloride 1.033 1.087 -5.1
rn/n-Xvlene 1.976 2.045 -3.4
o-Xvlene 1.651 . 1.703 -3.1
Page 2
•==============================-===== ·====· ============================-=-====
.I · Internal Standard Report
lata File Name C:\HPCHEM\l\DATA\052396\008F0101.D
~ ~tor RNP Page Number
L ,:-ument HALL/PID Vial Number
t mpl7 Name QCCK020 Injection Number
1
8
1
n Time Bar Code: Sequence Line 1
hcquired on : 23 May 96 01:28 PM Instrument Method: 502 HAL.MTH
502 HAL.MTH
0 leport Created on: 23 May 96 01:56 PM Analysis Method
last Recalib on : 23 May 96 01:55 PM Sample Amount
Multiplier 1 ISTD Amount 5
'
ig. 1 in C:\HPCHEM\l\DATA\052396\008F0101.D .
et Time Area Type Width Ref# ~g/L Name
_.--;~~~~l------~~~;;~1;;--l~~~;~l-~---l---~~~~~l~i~ti~;~aiti~~;~~;~h~~;-------I
I 3.393 456215 VV 0.069 1 5.228 Chloromethane
I
I
I
I
3.581 1253146 VV 0.105 1 5.245 Vinyl chloride
4.195 289751 VV 0.074 1 5.395 Bromomethane
4.358 1075213 VV 0.105 1 5.947 Chloroethane
4.818 1968073 VB 0.091 1 5.368 Trichlorofluoromethane
5.804 1985587 BV 0.096 1 5.344 1,1-Dichloroethene
6.709 1907747 PV 0.087 1 5.365 Methylene chloride
7.171 2196926 VV 0.077 1 5.462 t-1,2-Dichloroethene
7.888 2076101 VV 0.091 1 5.453 1,1-Dichloroethane
8.830 3699192 VV 0.081 1 10.940 c-12Diclethene; 22Diclpropane
9.221 804807 VV 0.058 1 5.194 Bromochloromethane
9.346 2532532 VV 0.074 1 5.522 Chloroform
'.603 2586651 VV 0.080 1 5.483 1,1,1-Trichloroethane
.857 4445233 VV 0.060 1 10.524 Carbon Tetracl; 22Diclpropane
10.220 1249938 VV 0.074 1 5.479 1,2-Dichloroethane
I 11.143 2400849 VV 0.056 1 5.414 Trichloroethene
11.483 1597293 VV 0.067 1 5.271 1,2-Dichloropropane
11.681 391980 VV 0.057 1 4.848 Dibromomethane
11.907 1285448 VV 0.059 1 5.171 Bromodichloromethane I 12.553 1172390 VV 0.057 1 5.378 c-1,3-Dichloropropene
13.374 689909 VV 0.049 1 5.129 t-1,3-Dichloropropene
13.517 1844000 VV 0.057 1-I 5.000 * Bromochloropropane *
I 13.649 1066050 VV 0.062 1 5.254 1,1,2-Trichloroethane
13.840 3398859 VV 0.074 1 10.808 Tetraclethane; 13Diclpropane
14.247 605602 VV 0.051 1 5.223 Dibromochloromethane
I. 14.415 456564 VV 0.068 1 5.026 1,2-Dibromoethane (EDB}
15.130 757217 VV 0.047 1 5.291 Chlorobenzene
15.252 2026983 VV 0.061 1 5.517 1,1,1,2-Tetrachloroethane
· 16.400 214221 VV 0.051 1 4.929 Bromoform I .16.790 650246 VV 0.050 1 5.000 $ 1,4-Dichlorobutane $
I
I
I
17.102 815827 VV 0.052 1 5.201 1,1,2,2-Tetrachloroethane
17.158 389432 VV 0.048 1 10.141 Bromobenzene; 123triclpropane
17.389 795989 VV 0.050 1 5.300 2-Chlorotoluene
17.555 830046 VV 0.051 1 5.419 4-Chlorotoluene
18.544 1015021 VV 0.048 1 5.405 1,3-Dichlorobenzene
18.681 1195690 VV 0.052 1 5.594 1,4-Dichlorobenzene
19.266 876392 VV 0.051 1 5.437 1,2-Dichlorobenzene
•.500 54136 vv 0.056 1 4.900 1,2-Dibromo-3-chloropropane
_.783 1157682 VV 0.057 1 6.661 1,2,4-Trichlorobenzene
22.042 2223939 vv 0.060 1 6.366 Hexachlorobutadiene
22.563 1011632 MM 0.055 1 6.610 1,2,3-Trichlorobenzene
.Calibration table contains at least one peak with amt= O
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
-()1
~ata File
f-'
0
f-'
()1
(\)
0
(\)
~me
Eperator
nstrument
?mule Name
R Time Bar Code:
lt~~uired on :
eport Created on:
Last Recalib on
rultiplier
(\)
0
m
,I,
0
m
· hlorod~luoromelhone 1068
hlor I ~ l.581
lol,11,ane U58
(l)
0
m
ichlorolluoromethone (818
r,::~===---+.Hli<hio,oelhene 5.804
.150
OJ
0
m
t:::=====----<"1"rlent chlorile 6.709
t:::=====-------1-1]-D<hioloelhe"' 7.171
t:::=====---'c+-D<hloroe\hane 7.888
0
m
f-'
(\)
m
f-'
rbon h>t10cl : 220iclpropone 9.857
D<hioloelhol< ID.120
11-D<hloro~opone 11.483
romodkhbromelhcme 11.907
i==-------1.3-0ichloropropene 12.553
omome I.
18.077
rormfoon 16.400 I l,4-D<hiolobtno"' I l6.790 2;~1~r,sa 1.101
-~~8!iMJ \~s
1::==-====:±\;,li, 'm/l!S~!Plnl~B'alt
b=-----, l-D<hlorobonzeno 19.166
19,666
1 l-0..ono-J-chlorOl'ooone 10.500
richloroelhene 11.143
~;m~;;;;:;;;;;;;===~· :::-1~,,~hlor~o~bo!!!_nz•~ne~1!_!,;l.~78~l -lie r iochlorobutodiene 22.042
ffle!&a-----41,3-lrichhiobel\lene 22.558
l.485
C:\RPCREM\l\DATA\052396\008F0101.D
RNP Page Number
HALL/PID Vial Number
QCCK020 Injection Number
23
23
22
1
May
May
MAY
96
96
96
01:28 PM
01:53 PM
11:59 AM
Sequence Line
Instrument Method:
Analysis Method
Sample Amount
!STD Amount
1
8
1
1
502 HAL.MTR
502 HAL.MTR
0
5
I=========================-================================================--==
_ -· Internal Standard Report
lata File Name C:\HPCHEM\l\DATA\052396\008R0101.D "r 'itor RNP Page Number 1
I: .7.J.ment HALL/PID Vial Number 8
l a, .. ple Name QCCK020 Injection Number 1
un Time Bar Code: Sequence Line 1
Acquired on 23 May 96 01:28 PM Instrument Method: 502 HAL.MTR
l·eport Created on: 23 May 96 01:54 PM Analysis Method 502 PID.MTH
, ast Recalib on : 23 MAY 96 01:42 PM Sample Amount o
Multiplier 1 ISTD Amount 5
l ig. 2 in C:\HPCHEM\l\DATA\052396\008R0101.D .
et Time Area Type Width Ref# µg/L Name
-,l-------l------------l----1-----1-----l--------1------------------------------1
I .3.559 42811 PV 0.087 1 4.945 (H) Vinyl chloride
5.783 141167 W 0.088 1 5.057. (H) 1,1-Dichloroethene
7 .153 350778 BB O. 073 1 10. 059 MTBE ; {H) t-12DCE
7.968 105662 BV 0.086 1 4.946 DIPE
8.819 144326 BB 0.063 1 5.013 (H) c-12dce
9.837 146192 PV 0.061 1 5.034 (H) 11-Diclpropene I
I-10 .157 331021 PV O. 060 1 5. 001 Benzene
10.578 497838 VB 0.058 1-I 5.000 * Fluorobenzene *
11.125 201275 BV a.ass 1 5.015 (H) Trichloroethene
11.548 155127 W 0.060 1 4.922 $ a,a,a-Trifluorotoluene $
I: 12.534 52035 BV 0.049 1 5.055 (H) c-13pene
13.014 307781 W 0.051 1 5.025 Toluene
13.356 51752 W 0.046 1 5.056 (H) t-13pene
I -~.822 153657 VB 0.051 1 5.010 (H) Tetrachloroethene
.112 283717 PV 0.047 1 5.062 {H) Chlorobenzene
iS.262 281852 W 0.049 1 4.993 Ethylbenzene
I-15.437 636236 W 0.049 1 10.007 m-Xylene; p-Xylene
16.056 530028 W 0.059 1 10.035 a-Xylene; Styrene
16.595 206676 W 0.051 1 4.978 Isopropylbenzene
I·. 17. 079 228430 W O. 046 1 5. 009 (H) Bromobenzene
17.226 258012 W 0.048 1 4.998 n-Propylbenzene
17.370 265519 W 0.047 1 5.011 (H) 2Cltoluene
17. 499 635759 W O. 074 1 10. 041 135-Trimethylbenz ; (H) 4Cltol
I 17. 997 203465' W O. 051 1 4. 993 tert-Butylbenzene
18.075 273930 W 0.048 1 5.021 124-Trimethylbenzene
18.337 222768 W 0.052 1 5.055 sec-Butylbenzene ·
I 18. 538 445687 W o. 071 1 10 .116 p-Isopropyltoluene ; (H) 13dcb
. 18.664 _ 220340 W 0.045 1 5.071 (H) 14dcb
19.205 384643 W 0.073 1 10.254 n-Butylbenzene ; (H) 12dcb
I 21.765 I28649 W 0.046 1 5.877 (H) 124~Triclbenzene
22.024 134444 W 0.054 1 5.668 (H) Hexaclbutadiene
22. 155 97998 W o. 045 1 6. 034 Naphthalene
22.539 119073 W 0.047 1 6.521 (H) 123Triclbenzene
lalibration table contains at least one peak with amt= 0
.,~=============================================================================
I
m
0
ro
[\)
0
ro
Gl
0
ro
~
0
ro
(JI
0
ro
0)
0
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-J
0
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[ll
0
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I
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0 ,'-'---'-'----t---'-~~---'---'-~~~'-'-'--'-'-~--'-'--'e-'-_._l._~~'--'----'~----'~-'---'-'-
Data File
(JI
f-'
0
f-'
(JI
[\)
0
[\)
r-ffime
Eperator
· nstrument
aJTiole Name
.R, rime Bar Code:
1.991
\:================-=---------<,!llf-,-f+i)-1-i,OC[ l.lSJ
t::::====-----OIP[ 7.988
~======------''-1H) c-lldce 8.819
H) 11-Dicl~ope" 9.837
~=======--=------------IH)'Tr~hloroethene 11.125
t=f!lnl=====---------l o.o.o-Tr~luorololuene S 11.5-48
H) c-llpeoe 115~
H) 1-lJpeoe ll.356
H) Tel1och\o,oe\her, ll.811
1\l.7i!o
16.371
16.80
profr,'ibenzene 16.595
19.981
l't. ".ldJ;,;.1'{iW'I"" 11.765
H) lll11iclbenzeoe 11539
1.988
C:\HPCHEM\l\DATA\052396\00BR0l0l.D
RNP Page Number
HALL/PID Vial Number
QCCK020 Injection Number
1
8
1
1
t c~~ired on : 23
eport Created on: 23
Last Recalib on 23
May
May
MAY
96 01:28 PM
96 01:54 PM
96 01:42 PM
Sequence Line
Instrument Method:
Analysis Method
Sample Amount
!STD Amount
502 HAL.MTR
502 PID.MTH
0
rultiplier 1 5
I
I
I
I
I
I
I,
I
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I
I
I
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I
1.
I
I
PARADIGi\1 Ai\AL\TICAL LABORATORIES. I1\C.
MS/MSD Control Limits
Method: 8021 Low Soil
Limits
Compound Lower Upper
Benzene 11.0 29.0
Bromobenzene 11.9 28.1
Bromochloromethane 14.3 25.7
Bromodichloromethane 11.9 28.1
Bromoform 12.3 27.7
Bromomethane 8.5 31.5
n-Butylbenzene 8.7 31.3
sec-Butyl benzene 5.0 35.0
tert-Butylbenzene 9.2 30.8
Carbon tetrachloride 4.8 35.2
Chlorobenzene 6.9 33.1
Chloroethane 7.8 32.2
Chloroform 10.1 29.9
Chloromethane D 39.9
2-Chlorotoluene 3.2 36.8
4-Chlorotoluene 4.1 35.9
Dibromochloromethane 12.3 27.7
1,2-Dibromo-3-chloropropane 11.1 28.9
1,2-Dibromoethane (EDB) 13.1 26.9.
Dibromomethane 14.1 25.9
1,2-Dichlorobenzene-4.3 35_7
1,3-Dichlorobenzene 4.2 35.8
1 ,4-Dichlorobenzene 5.6 34.4
Dichlorodifluoromethane 8.7 31.3
1, 1-Dichloroethane 11.1 28.9
1,2-Dichloroethane 14.9 25.1
1, 1-Dichloroethene 8.5 31.5
cis-1,2-Dichloroethene 12.7 27.3
trans-1,2-Dichloroethene 8.8 31.2
1,2-Dichloroeroeane 12.0 28.0
2,2-Dichloropropane 4.8 35.2
cis-1,3-Dichloropropane 8.3 31.7
trans-1,3-Dichloropropane 11.5 28.5
Diisopropyl ether 13.8 26.2
Eth;tlbenzene 8.6 31.4
Hexachlorobutadiene 1.6 38.4
lsopropylbenzene 7.9 32.1
p-lsopropyltoluene 8.4 31.6
Methyl-tert butyl ether 4.4 35.6
Methtlene Chloride D 67.1
Naphthalene 8.0 32.0
P,ioe 1 of 2
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PARADIGM ANALYTICAL LABORATORIES. INC.
MS/MSD Control Limits
Method: 8021 Low Soil
Limits
Compound Lower Upper
n-Propylbenzene 7.8 32.2
Styrene D 42.8
1, 1, 1,2-Tertrachloroethane 8.1 31.9
1, 1,2,2-Tertrachloroethane D 52.8
Tetrachloroethene 8.8 31.2
Toluene 10.1 29.9
1,2,3-Trichlorobenzene 5.2 34.8
1,2,4-Trichlorobenzene 3.9 36.1
1, 1, 1 • Trichloroethane 7.1 32.9
1, 1,2• Trichloroethane 13.5 26.5
Trichloroethene 8.2 31.8
Trichlorofluromethane 5.4 34.6
1,2,3-Trichloropropane 11.9 28.1
1,2,4-Trimeth~lbenzene 7.1 32.9
1,3,5-Trimethylbenzene 5.5 34.5
Vinyl Chloride 10.6 29.4
m/p,-Xylene 17.2 62.8
o-Xylene 12.6 27.4
D = Detected Page 2 of 2
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PARADIGM ANAUTICAL LABORATORIES, INC.
MS/MSD Control Limits
Method: 6230D 25ml purge
Limits
Compound Lower Upper
Benzene 2.3 7.7
Bromobenzene 3.3 6.7
Bromochloromethane 3.1 6.9
Bromodichloromethane 2.7 7.3
Bromoform 3.1 6.9
Bromomethane 1.2 8.8
n-Butylbenzene D 12.3
sec-Butylbenzene 0.5 9:5
tert-Butylbenzene 0.6 9.4
Carbon tetrachloride D 12.0
Chlorobenzene 2.1 7.9
Chloroethane 2.1 7.9
Chloroform 3.1 6.9
Chloromethane 3.6 6.4
2-Chlorotoluene D 9.9
4-Chlorotoluene 0.8 9.2
Dibromochloromethane 3.2 6.8
1,2-Dibromo-3-chloropropane 3.5 6.5
1 ,2-Dibromoethane (EDB) 3.1 6.9
Dibromomethane 3.5 6.5
1,2-Dichlorobenzene 2.0 8.0
1,3-Dichlorobenzene 1.3 8.7
1,4-Dichlorobenzene 1.2 8.8
Dichlorodifluoromethane D 10.7
1, 1-Dichloroethane. 1.6 8.4
1,2-Dichloroethane 2.5 7.5
1, 1-Dichloroethene 0.9 9.1
cis-1 ,2-Dichloroethene D 10.2
trans-1,2-Dichloroethene 1.3 8.7
1,2-Dichloropropane 1.9 8.1
2,2-Dichloropropane D 12.0
cis-1,3-Dichloropropane 2.4 7.6
trans-1,3-Dichloropropane 3.0 7.0
Diisopropyl ether 3.2 6.8
Ethylbenzene 1.3 8.7
Hexachlorobutadiene D 12.8
lsopropylbenzene 0.8 9.2
p-lsopropyltoluene D 12.4
Methyl-tert butyl ether 0.3 9.7
Methylene Chloride 3.5 6.5
D = Detected Page 1
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PARADIGM ANALYTICAL LABORATORIES, INC.
MS/MSD Control Limits
Naphthalene 2.0 8.0
n-Propylbenzene 0.8 9.2
Styrene 0.7 · 9.3
1, 1, 1,2-Tertrachloroethane 2.2 7.8
1, 1,2,2-Tertrachloroethane D 12.1
Tetrachloroethene D 12.4
Toluene 1.4 8.6
1,2,3-Trichlorobenzene 1.1 8.9
1,2,4-Trichlorobenzene 1.4 8.6
1, 1, 1-Trichloroethane 0.9 9.1
1 , 1 ,2-Trichloroethane 3.0 7.0
Trichloroethene 2.8 7.2
Trichlorofluromethane 1.5 8.5
1,2,3-Trichloropropane 3.3 6.7
1,2,4-Trimethylbenzene 1.5 8.5
1,3,5-Trimethylbenzene 1.3 8.7
Vinyl Chloride 0.9 9.1
mlp-Xylene 2.9 17.1
o-Xylene 1.9 8.1
D = Detected Page2
j'\tion for each compound and internal standard. and calculate
tJponse factors (RF) for each compound as follows:
~ere:
RF= (A,) (C,.)
(A.) (C,)
A. = response for compound to be measured.
I A., = response for internal standard,
C,, = concentration of internal standard. and
C, = concentration of compound to be measured.
'
Use average RF if RSD is less than 35%. Check calibration
procedure of~ 5b3) below. using calibration acceptance cri-
ria found in Table 6210:IV.
· 3) Calibration check-Verify working calibration curve. cal-
l ration factor. or RF on each working day by analyzing a QC
eek sample[~ 4i)] according to sample analysis procedure. For
:ach compound. compare the response (Q) with the correspond-lg calibration acceptance criteria (Table 6210:IV). If the re-
INDIVIDUAL ORGANIC COMPOUNDS (6000)
sponses for all compounds of interest fall within the designated
ranges. sample analysis may begin. NoTE: Because of the large
number of compounds. there is a substantial probability that one'
or more will not meet the calibration acceptance criteria when
all compounds are analyzed. If any individual Q falls outside the
range. repeat test only for those compounds that failed to meet
the calibration acceptance ·criteria. If the response does not fall
within the range in this second test, prepare a new calibration
curve, calibration factor. or RF for that compound.
d. Sample analysis: Adjust purge gas (nitrogen or helium) flow
rate to 40 mL /min. Attach trap inlet to purging device and set
purge and trap system to purge (Figure 6210:3). Open syringe
valve on purging device sample introduction needle.
Let sample come to ambient temperature before introducing
it into the syringe. Remove plunger from a 5-mL syringe and
attach a closed syringe valve. Open sample bottle (or standard)
and carefully pour sample into syringe barrel to just shon of
overflowing. Replace syringe plunger and compress sample. Open
syringe valve and vent any residual air, while adjusting sample
TABLE 6210:JV. CALIBRATION AND QC ACCEPTANCE CRITERIA• f"o,._ fo'.l.300
I Range
lor Q
Compound f'-8/L
lenzene 12.8-27.2
romodichloromethane 13.1-26.9
Bromoform 14.2-25.8
~romomethane 2.8-37.2
tetrachloride 14.6-25.4
. .i>enzene 13.2-26.8
Chloroc1hane 7.6-32.4
~Chloroethylvinyl ether D-44.8
hloroform .13.5-26.5
hloromethane D-40.8
Dibromochloromethane 13.5-26.5 o .2·Dichlorobenzcne 12.6-27.4
-.3-Dichlorobenzene 14.6-25.4
.4-Dichlorobenzene 12.6-27.4
l .l-Dichloroe1hane 14.5-25.5 E .2-Dichloroethane 13.6-26.4
. l -Dichloroethcne 10.1-29.9
rans-1.2-Dichlorocthcnc 13.9-26.1
1.2-Dichloropropanc 6.8-33.2
·i·l.3-Dichloropropene 4.8-35.2
rans-1.3-Dichloropropcne 10.0-30.0
thyl benzene 11.8-28.2
Methylene chloride 12.1-27.9 I{ .2.2-Tetrachloroethane 12.1-27.9
etrachlorocthcnc 14.7-25.3
oluene I 14.9-25.1
1.1. l-Trichlorocthane 15.0-25.0 It 1.2-Trichloroethane 14.2-25.8
ric!Jioroethene 13.3-26.7
Tricf:i:;ro.fJucromethane 9.6-30.4
Vinyl c'Aw.mi-0.8-39.2
• Q -ama:mr3'ion measured in QC check sample.
!. • slaodard dewia\ion of four recovery mcasuremcnls.
• averaic recovery Df four recovery measurements .
..., pcrccnl rc'COvtry measured.
Limit Ran.le for Range
for s X for P. P,
µg/L gll <;;
6.9 15.2-26.0 37-151
6.4 10.1-28.0 35-155
5.4 11.4-31.1 45-169
17.9 D-41.2 D-242
5.2 17.2-23.5 70-140
6.3 16.4-27.4 37-160
11.4 8.4-40.4 14-230
25.9 D-50.4 D-305
6.1 13.7-24.2 51-138
19.8 D-45.9 D-273
6.1 13.8-26.6 53-149
7.1 11.8-34.7 18-190
5.5 17.0-28.8 59-15f>
7.1 11.8-34.7 18-190
5.1 14.2-28.5 59-155
6.0 14.3-27.4 49-t55
9.1 3.7-42.3 D-234
5.7 13.6-28.5 54-156
13.8 3.8-36.2 D-210
15.8 1.0-39.0 D-:!27
l0.4 7.6-32.4 17-t83
7.5 17.4-26.7 37-162
7.4 D-41.0 D-221
7.4 13.5-27.2 46-157
5.0 17.0-26.6 64-148
4.8 16.6-26.7 47-t50
4.6 13.7-30. 1 52-f62
5.5 14.3-27.t 52-t50
6.6 18.6-27.6 71-157
10.0 8.9-31.5 17-181
20.0 D-43.5 D-251
Cri1cria calculaled assuming a QC check snmple concrnmnion of 20 µ~L . . . I • dclcctcd; result must be greater than zero.
NOTE-These crilcria arc based dircclly on the mclhod performance data in Table 6:=!111:VI. Where nccc:ssary. the hmus for recovery were broadened to a~sun:
applicabilily of 1he limils 10 conccntra1ions below 1hosc used to develop Table 61 IU:VI.
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JJa!Eni·ironm rri·irti
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------iiiiil ---... Laboratory Task Order No.~ CHAIN-OF-CUSToDv"llcdl!le
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Project Number ,J c..o ?..60. 041 I SAMPLE BOTTLE / CONTAINER DESCRIPTION I
Project Location s,-k No. 2'] (t,JCDo"t) Jo]/
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Laboratory Task Order No.1 °}5~ CHAIN-OF-CUSTODY RECORD Page_ _01_[_
a heldemq company
Project Number N c..a3,loo. 041 I SAMPLE BOTTLE / CONTAINER DESCRIPTION I
Project location S1'k No. 23 ( N rDc"t") ../;; '9 .:c.o f'
Laboratory _e Ag A\) I C, ti' ✓ ,:y.
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TOTAL
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Dale I I Time Yes No N/A
□ Lab Courier. □ Other ----===c----SPEc1Fv .. ,.,,,
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Envir, .ntal Services C, ~Cj-t-j = --

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Laboratory Task Order No, __ _
Project Number N l. c, ::,G.0 · o '--\ ~ I SAMPLE BOTTLE / CONTAINER DESCRIPTION I
Project location C, n;~ ht..-..!! L.. t-c. tiZ,1
Laboratory P "-c--"<.. d r 1 "'-
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Total No. ol Bottles/ 7 Containers
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Received by: 'fn -IJ I/ -J ,, u Organization: f,._. -

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,v ___ ,... u .-l" :J Date r I ve. 1 c. Time 1'2 Lor:: le!I "'-No NIA
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Special Instructions/Remarks: C::::<; -.c,-/fJ MC. Ck,:;,-, ' c.. ·-<>-~•·" ,,:p, ,__ -...Lor <. r -5 -(V • I"' "tH, r. ,' k.e, p. C • p
Deliverv Method: D In Person ~ Common Carrier _,r'---'-e..""c{q__cJl,LFxr.:,,,ev ___ _ D Lab Courier □ Other ---=::c----SPec,FY
==-----------Laboratory Task Order No~:\-rr 'CHAIN-OF-CUSTODY RECORD Page_
(ch)M '/'fl,,
Project Number N C. 6 :, (,, 0 · 0 L\ I
Project location G--rcsh,.~:, Lc-k~ tj 2.9
Laboratory V'i. C-"<-J ,-1 V\.
Sampler(s)/ Afliliation M t) G-f IV!
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SAMPLE IDENTITY Code
SAMPLE BOTTLE / CONTAINER DESCRIPTION
TOTAL
~ 1-'s~s_-_s=--.llol!//J~+-'S:___+r:<::;/. -=='
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Sample Code: L = Liquid; S = Solid; A = Air
Relinquished by: '' -,-{, t, Y / l/r--v e (
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Organization: -/~ -<•<> c.,/,, T'I { v11,·1 /-, ,--Organization:
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Special Instructions/Remarks: C:: S -'> ftl I"\ c._ !'." Mc; '
& .,,.ef 6 if 'f 7 ,l L 5 ff' L/ () (;, C-:> . . -' . .
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Total No. ol Bollles/
Containers
Date S I 17 I 'l&Time /l( lflf
Date 1 1 Time _____ _
Date I Time _____ _
Date 1 I Time
Seal Intact?
(Y,is/No N/A
Seal Intact?
Yes No N/A
D Lab Courier D Other _______ _
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-~-"'!AGI"" -A .. & ~1' ·R. INC.
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-·-Laboratory Task Order No 2o '+S::S CHAIN-OF--CUSTODV RECORD Page_
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Project Number Nc.. o 360, n'=l I I SAMPLE BOTTLE / CONTAINER DESCRIPTION
Project Location frr:r:s Mv:i.S k,}e #Z.9 u f:>1
Laboratory p C\. \ Q, d I ~ V)
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Laboralory Task Order Nn2 o :J £5 CHAIN-OF-CUSTODY RECORD Page_
c1 heldem~ company
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Project Number Nl-o36Q, nt..1 I . I &\MPLE BOTTLE I CONTAINER DESCRIPTION
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SPf(:TrY
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PARADIGM ANAL\TICAL LABORATORIES, INC.
2627 Northchase Parkway S.E.
Wilmington, North Carolina 28405
[phone]
Mr. Fred Rash
Geraghty & Miller
2840 Plaza Place
Raleigh,NC 27612
Report Number: 8149-42
Fax [phone]
Client Project Number: NC0.360.042
Project Location: Raleigh, NC
LTO Number: 20153
Dear Mr. Rash :
Date 10-18-96
Enclosed are the results of the analytical services performed under the
referenced project. Copies of this report and supporting data will be retained in
our files for a period of five years in the event they are required for future
reference. Any samples submitted to our laboratory . will be retained for a
maximum of thirty (30) days from date of this report unless other arrangements
are requested.
If there are any questions about the report or the services performed during this
project, please call for assistance. We will be happy to answer any questions or
concerns which you may have.
Thank you for using Paradigm Analytical Labs for your analytical service
projects. We look forward to working with you again on any additional needs
which you may have.
Sincerely,
Paradigm Analytical Laboratories
\Y\.Jl QJ,,QJ
Laboratory Director
Mark Randall
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PARADIGM ANALYTICAL LABORATORIES, INC.
CASE NARRATIVE FOR PROJECTS 149-42
LTO # 20153
SURROGATES:
149-42
All within acceptance criteria
.BLANKS:
149-42
All blanks -all compounds BQL
MATRIX SPIKES/MATRIX SPIKE DUPLICATES:
149-42
8260 MS/MSD
7 compound failed acceptance criteria for recovery.
1 compounds failed RPO acceptance criteria (30%) .
LCS
0 compound failed acceptance criteria
HOLDING TIME:
All samples analyzed within holding time
DILUTIONS:
See attached
COMMENTS:
---------
· PAL Proi#.i'_ Client Sample ID: CDC /Proj 10 _: _ _![Lab 10;: :. :Report .... :, ' Analyses~--
G149-42 29MW-1
G f,iij:42 29MW-2
G149-42 29MW-3
G f,ig.42 J38□ 19
G149-42. J38020
(;!_49-4~ __ ,J38022 ___ -·
G_!~~~? .•. JJ3~019MS __ _
G149-42 IJ38019MSD
Gi49~i-· [REP:oi-Gw
Gi4s:,i2 .. iTB-019i3cii!ii;
G149-42 1EB-01-GW .
NC0360.042 15536 8260B 8260B-WA
---NC0360.04i ___ ·15537 8260B 82608-WA
NC0360.042 ... .. .. 15538 82608 --82608-WA
Nco:iso.o,i2 .... -15539 82608. a26os:WA ... -
Nco:i'150:042 .... · · 15540 82608 -a26os-wA · -· -
NC0360.042 -15541 82608 82608-WA
NC0360 042 -15542 82608 . 82608-WA
. NC0360.042 --·· -i 5543 82608 82608-WA
NC0:360.042 ----· 15544 '82608 82608-WA --.
NC0360.042 -j 5545 82608--~ --· 8260B-WA ..
NC0360.042 . 15546 8260B-. 8260B-WA
---lilll ----Logir . pies
Date Printed 10/5/96
Page 1
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PARADIGM ANALYTICAL LABORATORIES, INC.
SAMPLES AND ASSOCIATED BLANKS
SAMPLE ID
15536
15537
15538
15539
15540
15541
15544
15545
15546
ASSOCIATED BLANK
82608
VBLK100496
VBLK100496
VBLK101196
VBLK100496
VBLK101096
VBLK101096
VBLK100496
VBLK100496
VBLK100496
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SAMPLE ID
15538
PARADIGM ANAL\TICAL LABORATORIES, l'\C.
DILUTIONS 149-42
82608
X12.5
I PARADIGM ANALYTICAL LABORATORIES. INC.
Results for Volatiles
I
byGCMS 8260
Client Sample ID: 29MW-1 Date Analyzed: 10/4/96
Client Project ID: NC0360.042 Analyzed By: RNP
I Lab Sample ID: 15536 Date Collected: 9/30/96
Lab Project ID: G149-42 Date Received: 10/1/96
Matrix: Water Dilution: 1.0
I Compound Quantitation Result
Limit (ug/L) (ug/L)
Acetone 25 BQL
I Acrolein 50 BQL
Acrylonitrile 50 BQL
Benzene 1 BQL
I Bromobenzene BQL
Bromochloromethane BQL
Bromodichloromethane BQL
Bromoform 1 BQL
I Bromomethane 1 BQL
2-Butanone 25 BQL
n-Butylbenzene BQL
I sec-Butyl benzene 1 BQL
tert-Butylbenzene 1 BQL
Carbon disulfide BQL
Carbon tetrachloride 1 BQL
I Chlorobenzene 1 BQL
. Chloroethane 1 BQL
2-Chloroethyl vinyl ether 5 BQL
Chloroform 1 1
I Chloromethane 1 BQL
2-Chlorotoluene BQL
4-Chlorotoluene 1 BQL
I Dibromochloromethane 1 BQL
1,2-Dibromo-3-chloropropane 5 BQL
Dibromomethane 1 BQL
1,2-Dibromoethane (EDB) BQL
I 1,2-Dichlorobenzene BQL
1, 3-Dichlorobenzene 1 BQL
1,4-Dichlorobenzene 1 BQL
I trans-1, 4-Dichloro-2-butene 5 BQL
1, 1-Dichloroethane BQL
1, 1-Dichloroethene SQL
1,2-Dichloroethane BQL
I cis-1,2-Dichloroethene 1 BQL
trans-1,2-dichloroethene 1 BQL
1,2-Dichloropropane 1 BQL
I 1, 3-Dichloropropane BQL
2,2-Dichloropropane 1 BQL
1, 1-Dichloropropene 1 BQL
cis-1,3-Dichloropropene 1 BQL
I trans-1,3-Dichloropropene 1 BQL
Dichlorodifluoromethane 5 BQL
Diisopropyl ether (DIPE) 1 BQL
I Ethyl benzene 1 BQL
Hexachlorobutadiene 1 BQL
2-Hexanone 5 BQL
lodomethane BQL
I lsopropylbenzene 1 BQL
Reviewed by:"""-,.
I Flags: BQL = Below Quantitation Limit Page 1
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PARADIGM ANAL\TICAL LABORATORIES. INC.
Client Sample ID: 29MW-1
Client Project ID: NC0360.042
Lab Sample ID: 15536
Lab Project ID: G149-42
Matrix: Water
Compound
4-lsopropyltoluene
Methylene chloride
4-Methyl-2-pentanone
Methyl-tert-butyl ether (MTBE)
Naphthalene
n-Propyl benzene
Styrene
1, 1, 1,2-Tetrachloroethane
1, 1,2,2-Tetrachloroethane
T etrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2, 4-Trichlorobenzene
Trichloroethene
1, 1, 1-Trichloroethane
1, 1,2-Trichloroethane
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2, 4-Trimethylbenzene
1, 3, 5-Trimethylbenzene
Vinyl acetate
Vinyl chloride
m-,p-Xylene
a-Xylene
Surrogate Spike Recoveries
Compound
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-dB
Comments:
Results for Volatiles
byGCMS 8260
Quantitation
Limit (ug/L)
1
5
5
1
1
1
1
-1
1
1
1
1
1
1
1
1
1
1
2
1
Spike
Added
(ug/L)
5
5
5
All results are corrected for dilution.
Flags: BQL = Below Quantitation Limit
Date Analyzed: 10/4/96
Analyzed By: RNP
Date Collected: 9/30/96
Date ~eceived: 10/1/96
Dilution: 1.0
Result
(ug/L)
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
Surrogate
Result %Rec
(ug/L)
5 100
4.8 96
4.9 98
Reviewed by: Mt½
Page 2
I PARADIGM ANALYTICAL LABORATORIES. l'\C.
Results for Volatiles
I Client Sample ID: 29MW-2
byGCMS 8260
Date Analyzed: 10/4/96
Client Project ID: NC0360.042 Analyzed By: RNP
I Lab Sample ID: 15537 Date Collected: 9/30/96
Lab Project ID: G149-42 Date Received: 10/1/96
Matrix: Water Dilution: 1.0
I Compound Quantitation Result
Limit (ug/L) (ug/L)
Acetone 25 BQL
I Acrolein 50 BQL
Acrylonitrile 50 BQL
Benzene 1 BQL
Bromobenzene 1 BQL
I Bromochloromethane 1 BQL
Bromodichloromethane 1 BQL
Bromoform 1 BQL
I Bromomethane 1 BQL
2-Butanone 25 BQL
n-Butylbenzene BQL
sec-Butylbenzene BQL
I tert-Butylbenzene 1 BQL
Carbon disulfide 1 BQL
Carbon tetrachloride BQL
I Chlorobenzene 1 BQL
Chloroethane 1 BQL
2-Chloroethyl vinyl ether 5 BQL
Chloroform BQL
I Chloromethane BQL
2-Chlorotoluene 1 BQL
4-Chlorotoluene 1 BQL
I Dibromochloromethane 1 BQL
1,2-Dibromo-3-chloropropane 5 BQL
Dibromomethane 1 BQL
1,2-Dibromoethane (EDB) 1 BQL
I 1,2-Dichlorobenzene BQL
1,3-Dichlorobenzene 1 BQL
1,4-Dichlorobenzene 1 BQL
I . trans-1,4-Dichloro-2-butene 5 BQL
1, 1-Dichloroethane BQL
1, 1-Dichloroethene 1 4
1,2-Dichloroethane 1 BQL
I cis-1,2-Dichloroethene 1 BQL
trans-1,2-dichloroethene 1 BQL
1,2-Dichloropropane 1 BQL
I 1,3-Dichloropropane 1 BQL
2,2-Dichloropropane 1 BQL
1, 1-Dichloropropene 1 BQL
cis-1,3-Dichloropropene 1 BQL
I trans-1,3-Dichloropropene 1 BQL
Dichlorodifluoromethane 5 BQL
Diisopropyl ether (DIPE) 1 BQL
I Ethyl benzene 1 BQL
Hexachlorobutadiene 1 BQL
2-Hexanone 5 BQL
lodomethane 1 BQL
I lsopropylbenzene 1 BQL
Reviewed by: fiM"::
I Flags: BQL = Below Quantitation Limit Page 1
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PARADIGM ANALYTICAL LABORATORIES, li\C.
Client Sample ID: 29MW-2
Client Project ID: NC0360.042
Lab Sample ID: 15537
Lab Prolect ID: G149-42
Matrix: Water
Compound
4-lsopropyltoluene
Methylene chloride
4-Methyl-2-pentanone
Methyl-tert-butyl ether (MTBE)
Naphthalene
n-Propyl benzene
Styrene
1, 1, 1,2-Tetrachloroethane
1, 1,2,2-T etrachloroethane
Tetrachloroethene
Toluene
1,2, 3-Trichlorobenzene
1,2,4-Trichlorobenzene
Trichloroethene
1, 1, 1-Trichloroethane
1, 1,2-Trichloroethane
Trichlorofluoromethane
1,2, 3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl acetate
Vinyl chloride
m-,p-Xylene
o,Xylene
Surrogate Spike Recoveries
Compound
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-dB
Comments:
Results for Volatiles
byGCMS 8260
Quantitation
Limit (ug/L)
1
5
5
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
2
Spike
Added
(ug/L)
5
5
5
All results are corrected for dilution.
Flags: BOL = Below Quantilalion Limit
Date Analyzed: 10/4/96
Analyzed By: RNP
Date Collected: 9/30/96
Date Received: 10/1/96
Dilution: 1.0
Result
(ug/L)
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BOL
6
19
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
Surrogate
Result %Rec
(ug/L)
4.9 98
4.8 96
4.8 96
Reviewed by: l\M...
Page 2
I PARADIGM ANALYTICAL LABORATORIES, INC.
Results for Volatiles
I byGCMS 8260
Client Sample ID: 29MW-3 Date Analyzed: 10/11/96
Client Project ID: NC0360.042 Analyzed By: RNP
I Lab Sample ID: 15538 Date Collected: 9130/96
Lab Project ID: G149-42 Date Received: 10/1/96
Matrix: Water Dilution: 12.5
I Compound Quantitation Result
Limit (ug/L) (ug/L)
Acetone 310 BQL
I Acrolein 620, BQL
Acrylonitrile 620 BQL
Benzene 12 BQL
I Bro mo benzene 12 BQL
Bromochloromethane 12 BQL
Bromodichloromethane 12 BQL
Bromoform 12 BQL
I Bromomethane 12 BQL
2-Butanone 310 BQL
n-Butylbenzene 12 BQL
I sec-Butylbenzene 12 BQL
tert-Butylbenzene 12 BQL
Carbon disulfide 12 BQL
Carbon tetrachloride 12 BQL
I Chlorobenzene 12 BQL
Chloroethane 12 BQL
2-Chloroethyl vinyl ether 62 BQL
Chloroform 12 BQL
I Chloromethane 12 BQL
2-Chlorotoluene 12 BQL
4-Chlorotoluene 12 BQL
I Dibromochloromethane 12 BQL
1,2-Dibromo-3-chloropropane 62 BQL
Dibromomethane 12 BQL
1,2-Oibromoethane (EDB) 12 BQL
I 1, 2-Dichlorobenzene 12 BQL
1,3-Dichlorobenzene 12 BQL
1,4-Dichlorobenzene 12 BQL
I trans-1, 4-Oichloro-2-butene 62 BQL
1, 1-Dichloroethane 12 BQL
1, 1-Dichloroethene 12 44
1,2-Dichloroethane 12 BQL
I cis-1,2-Dichloroethene 12 BQL
trans-1,2-dichloroethene 12 BQL
1,2-Dichloropropane 12 BQL
I 1, 3-Oichloropropane 12 BQL
2,2-Dichloropropane 12 BQL
1, 1-Dichloropropene 12 BQL
cis-1,3-Dichloropropene 12 BQL
I trans-1,3-Dichloropropene 12 BQL
Dichlorodifluoromethane 62 BQL
Oiisopropyl ether (DIPE) 12 BQL
I Ethylbenzene 12 BQL
Hexachlorobutadiene 12 BQL
2-Hexanone 62 BQL
lodomethane 12 BQL
I lsopropylbenzene 12 BQL
Reviewed by: fV.A-
I Flags: BQL = Below Quantitation Limit Page 1
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PARADIGM Ai\AL\1ICAL LABORATORIES, INC.
Client Sample ID: 29MW-3
Client Project ID: NC0360.042
Lab Sample ID: 15538
Lab Project ID: G149-42
Matrix: Water
Compound
4-lsopropyltoluene
Methylene chloride
4-Methyl-2-pentanone
Methyl-tert-butyl ether (MTBE)
Naphthalene
n-Propyl benzene
Styrene
1, 1, 1,2-Tetrachloroethane
1, 1,2,2-Tetrachloroethane
T etrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
Trichloroethene
1, 1, 1-Trichloroethane
1, 1,2-Trichloroethane
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1, 3,5-Trimethylbenzene
Vinyl acetate
Vinyl chloride
m-,p-Xylene
a-Xylene
Surrogate Spike Recoveries
Compound
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-dB
Comments:
Results for Volatiles
byGCMS 8260
Quantitation
Limit (ug/L)
12
62
62
12
12
12
12
12
12
12
12
12
12
12
12
12
12
12
12
12
12
12
25
12
Spike
Added
(ug/L)
5
5
5
All results are corrected for dilution.
Flags: BQL = Below Quantitation Limit
Date Analyzed: 10111196
Analyzed By: RNP
Date Collected: 9130196
Dale Received: 1011/96
Dilution: 12.5
Result
(ug/L)
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
160
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
Surrogate
Result %Rec
(ug/L)
4.2 84
4.6 92
4.4 88
Reviewed by: trvb,,-
Page2
I PARADIGM Al\ALYTICAL LABORATORIES, INC.
Results for Volatiles
I byGCMS 8260
Client Sample ID: J38Q19 Date Analyzed: 10/4/96
Client Project ID: NC0360.042 Analyzed By: RNP
I Lab Sample ID: 15539 Date Collected: 9/30/96
Lab Project ID, G149-42 Date Received: 10/1/96
Matrix: Water Dilution: 1.0
I Compound Quantltation Result
Limit (ug/L) (ug/L)
Acetone 25 BQL
I Acrolein 50 BQL
Acrylonitrile 50 BQL
Benzene BQL
Bromobenzene 1 BQL
I Bromochloromethane 1 BQL
Bromodichloromethane 1 BQL
Bromoform 1 BQL
I Bromomethane 1 BQL
2-Butanone 25 BQL
n-Butylbenzene 1 BQL
sec-Butyl benzene 1 BQL
I tert-Butylbenzene 1 BQL
Carbon disulfide BQL
Carbon tetrachloride BQL
I Chlorobenzene BQL
Chloroethane 1 BQL
2-Chloroethyl vinyl ether 5 BQL
Chloroform 1 BQL
I Chloromethane 1 BQL
2-Chlorotoluene BQL
4-Chlorotoluene 1 BQL
I Dibromochloromethane 1 BQL
1,2-Dibromo-3-chloropropane 5 BQL
Dibromomethane 1 BQL
1,2-Dibromoethane (EDB) 1 BQL
I 1,2-Dichlorobenzene 1 BQL
1,3-Dichlorobenzene 1 BQL
1,4-Dichlorobenzene 1 BQL
I trans-1,4-Dichloro-2-butene 5 BQL
1, 1-Dichloroethane 1 BQL
1, 1-Dichloroethene 1 BQL
1,2-Dichloroethane 1 BQL
I cis-1,2-Dichloroethene 1 BQL
trans-1,2-dichloroethene 1 BQL
1,2-Dichloropropane BQL
I 1, 3-Dichloropropane 1 BQL
2,2-Dichloropropane 1 BQL
1, 1-Dichloropropene BQL
cis-1,3-Dichloropropene 1 BQL
I trans-1, 3-Dichloropropene 1 BQL
Dichlorodifluoromethane 5 BQL
Diisopropyl ether (DIPE) 1 BQL
I Ethylbenzene 1 BQL
Hexachlorobutadiene 1 BQL
2-Hexanone 5 BQL
lodomethane 1 BQL
I lsopropylbenzene BQL
Reviewed by: 11/"---
I Flags: BQL = Below Quantitation Limit Page 1
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PARADIGM ANALYTICAL LABORATORIES, INC.
Results for Volatiles
byGCMS 8260
Client Sample ID: J38Q19 Date Analyzed: 10/4/96
Client Project ID: NC0360.042 Analyzed By: RNP
Lab Sample ID: 15539 Date Collected: 9/30/96
Lab Project ID: G149-42 Date Received: 10/1/96
Matrix: Water Dilution: 1.0
Compound Quantitation Result
Limit (ug/L) (ug/L)
4-lsopropyltoluene 1 BQL
Methylene chloride 5 BQL
4-Methyl-2-pentanone 5 BOL
Methyl-tert-butyl ether (MTBE) 1 BQL
Naphthalene 1 BQL
n-Propyl benzene BQL
· Styrene BQL
1, 1, 1,2-T etrachloroethane BQL
1, 1,2,2-T etrachloroethane BQL
T etrachloroethene BQL
Toluene BQL
1,2,3-Trichlorobenzene BQL
1,2,4-Trichlorobenzene 1 BQL
Trichloroethene 1 2
1, 1, 1-Trichloroethane 1 BQL
1, 1,2-Trichloroethane 1 BQL
Trichlorofluoromethane 1 BQL
1,2,3-Trichloropropane 1 BQL
1,2,4-Trimethylbenzene 1 BQL
1,3,5-Trimethylbenzene 1 BQL
Vinyl acetate BQL
Vinyl chloride 1 BQL
m-,p-Xylene 2 BQL
a-Xylene BQL
Surrogate Spike Recoveries Spike Surrogate
Added Result %Rec
Compound (ug/L) (ug/L)
Bromofluorobenzene 5 4.9 98
1,2-Dichloroethane-d4 5 4.8 96
Toluene-dB 5 4.8 96
Comments:
All results are corrected for dilution.
Reviewed by: fW"-:
Flags: BQL = Below Quantitation Limit Page2
I PARADIGM AI\ALYTICAL LABORATORIES. 11\C.
Results for Volatiles
I byGCMS 8260
Client Sample ID: J38Q20 Date Analyzed: 10/10/96
Client Project ID: NC0360.042 Analyzed By: RNP
I Lab Sample ID: 15540 Date Collected: 9/30/96
Lab Project ID: G149-42 Date Received: 10/1/96
Matrix: Water Dilution: 1.0
I Compound Quantitation Result
Limit (ug/L) (ug/L)
Acetone 25 BQL
I Acrolein 50 BQL
Acrylonitrile 50 BQL
Benzene 2
I Bromobenzene BQL
Bromochloromethane BQL
Bromodichloromethane BQL
Bromolorrn BQL
I Bromome·!hane 1 BQL
2-Butanone 25 BQL
n-Butylbenzene 1 BQL
sec-Butylt-enzene 1 BQL
' tert-Butylbenzene 1 BQL
Carbon di,;ulfide BQL
Carbon tetrachloride BQL
I Chlorobenzene BQL
Chloroethane 1 BQL
2-Chloroethyl vinyl ether 5 BQL
Chloroform 1 BQL
I Chloromethane 1 BQL
2-Chlorotoluene 1 BQL
4-Chlorotoluene 1 BQL
I Dibromochloromethane 1 BQL
1,2-Dibromo-3-chloropropane 5 BQL
Dibromomethane 1 BQL
1,2-Dibromoethane (EDB) 1 BQL
I 1,2-Dichlornbenzene BQL
1, 3-Dichlornbenzene BQL
1,4-Dichlo, obenzene 1 BQL
I trans-1,4-Dichloro-2-butene 5 BQL
1, 1-Dichlo,oethane 1 BQL
1, 1-Dichloroethene · 1 BQL
1,2-Dichloroethane 1 BQL
I cis-1, 2-Dichloroethene 1 3
trans-1,2-dichloroethene 1 BQL
1,2-Dichloropropane 1 BQL
i 1, 3-Dichloropropane 1 BQL
2,2-Dichloropropane 1 BQL
1, 1-Dichloropropene 1 BQL
cis-1,3-Dichloropropene 1 BQL
I Ira ns-1, 3-Dichloropropene 1 BQL
Dichlorodifiuoromethane 5 BQL
Diisopropyl ether (DIPE) 1 BQL
I Ethylbenze,,e 1 BQL
Hexachlorobutadiene 1 BQL
2-Hexanoni~ 5 BQL
lodometha11e 1 BQL
I lsopropylb.,nzene 1 BQL
Reviewed by: t:vh-;
I Flags: BQL = Below Qllantitation Limit Page 1
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PARADIGM Al\ALYTICAL LABORATORIES, INC.
Client Sample ID: J38Q20
Client Project ID: NC0360.042
Lab Sample ID: 15540
Lab Project ID:. G149-42
Matrix: Water
Compound
4-lsopropyltoluene
Methylene chloride
4-Methyl-2-pentanone
Methyl-tert-butyl ether (MTBE)
Naphthalene
n-Propyl benzene
Styrene
1, 1, 1,2-Tetrachloroethane
1, 1,2,2-Tetrachloroethane
T etrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
Trichloroethene
1, 1, 1-Trichloroethane
1, 1,2-Trichloroethane
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl acetate
Vinyl chloride
m-,p-Xylene
o-Xylene
Surrogate Spike Recoveries
Compound
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-dB
Comments:
Results for Volatiles
byGCMS 8260
Quantitation
Limit (ug/L)
1
5
5
1
1
1
1
1
1
1
1
2
Spike
Added
(ug/L)
5
5
5
All results are corrected for dilution.
Flags: BQL = Below Quanlitation Limit
Date Analyzed: 10/10/96
Analyzed By: RNP
Date Collected: 9/30/96
Date Received: 10/1/96
Dilution: 1.0
Result
(ug/L)
BQL
BQL
BQL
9
2
BQL
BQL
BQL
BQL
BQL
3
BQL
BQL
2
BQL
BQL
BQL
BQL
2
BQL
BQL
BQL
2
1
Surrogate
Result %Rec
(ug/L)
4.3 86
4.3 86
4.4 88
Reviewed by: 'fw>:-.:::
Page2
I PARADIGM ANALYTICAL LABORATORIES, INC.
Results tor Volatiles
I byGCMS 8260
Client Sample ID: J38Q22 Date Analyzed: 10/10/96
Client Project ID: NC0360.042 Analyzed By: RNP
I Lab Sample ID: 15541 Date Collected: 9/30/96
Lab Project ID: G149-42 Date Received: 10/1/96
Matrix: Water Dilution: 1.0
I Compound Quantitation Result
Limit (ug/L) (ug/L)
Acetone 25 BQL
I Acrolein 50 BQL
Acrylonitrile 50 BQL
Benzene 2
I Bromobenzene BQL
Bromochloromethane BQL
Bromodichloromethane BQL
Bromoform 1 BQL
I Bromomethane 1 BQL
2-Butanone 25 BQL
n-Butylbenzene 1 BQL
I sec-Butyl benzene 1 BQL
tert-Butylbenzene 1 BQL
Carbon disulfide 1 BQL
Carbon tetrachloride 1 BQL
I Chlorobenzene 1 BQL
Chloroethane 1 BQL
2-Chloroethyl vinyl ether 5 BQL ,, Chloroform 1 BQL
Chloromethane BQL
2-Chlorotoluene BQL
4-Chlorotoluene BQL
I Dibromochloromethane 1 BQL
1,2-Oibromo-3-chloropropane 5 BQL
Dibromomethane 1 BQL
1,2-Dibromoethane (EDB) 1 BQL
I 1,2-Dichlorobenzene BQL
1, 3-Dichlorobenzene 1 BQL
1,4-Dichtorobenzene 1 BQL
I trans-1,4-Dichloro-2-butene 5 BQL
1, 1-Dichloroethane 1 BQL
1, 1-Dichloroethene BQL
1,2-Dichloroethane BQL
I cis-1,2-Dichloroethene 1 13
trans-1,2-dichloroethene 1 BQL
1,2-Dichloropropane 1 BQL
I 1, 3-Dichloropropane BQL
2,2-Dichloropropane 1 BQL
1, 1-Dichloropropene 1 BQL
cis-1,3-Dichloropropene BQL
I trans-1,3-Dichloropropene 1 BQL
Dichlorodifluoromethane 5 BQL
Oiisopropyl ether (DiPE) 1 BQL
I Ethylbenzene 1 2
Hexachlorobutadiene 1 BQL
2-Hexanone 5 BQL
lodomethane 1 BQL
I lsopropylbenzene 1 BQL
Reviewed by: I':"'::::
I Flags: BQL = Below Quantilation Limit Page 1
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PARADIGM ANALYTICAL LABORATORIES, INC.
Client Sample ID: J38Q22
Client Project ID: NC0360.042
Lab Sample ID: 15541
Lab Project ID: G149-42
Matrix: Waler
Compound
4-lsopropyltoluene
Methylene chloride
4-Methyl-2-pentanone
Melhyl-lert-butyl ether (MTBE)
Naphthalene
n-Propyl benzene
Styrene
1, 1, 1,2-T etrachloroelhane
1, 1,2,2-T etrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
Trichloroelhene
1, 1, 1-Trichloroethane
1, 1,2-Trichloroethane
Trichlorofluoromethane
1,2, 3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl acetate
Vinyl chloride
m-, p-Xylene
o-Xylene
Surrogate Spike Recoveries
Compound
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-dB
Comments:
Results for Volatiles
byGCMS 8260
Quantitation
Limit (ug/L)
1
5
5
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
2
1
Spike
Added
(ug/L)
5
5
5
All results are corrected for dilution.
Flags: BQL = Below Quantitalion Limit
Date Analyzed: 10110196
Analyzed By: RNP
Date Collected: 9130196
Date Received: 1011196
Dilution: 1.0
Result
(ug/L)
BQL
BQL
BQL
BQL
4
BQL
BQL
BQL
BQL
BQL
15
BQL
BQL
1
BQL
BQL
BQL
BQL
5
3
BQL
9
9
6
Surrogate
Result %Rec
(ug/L)
4.8 96
4.4 88
4.4 88
Reviewed by: IYi',,,e
Page 2
I PARADIGM ANALYTICAL LABORATORIES, INC.
Results for Volatiles
I byGCMS B260
Client Sample ID: REP-01-GW Date Analyzed: 10/4/96
Client Project ID: NC0360.042 Analyzed By: RNP
I Lab Sample ID: 15544 Date Collected: 9/30/96
Lab Project ID: G149-42 Date Received: 10/1/96
Matrix: Water Dilution: 1.0
I Compound Quantitation Result
Limit (ug/L) (ug/L)
Acetone 25 BQL
I Acrolein 50 BQL
Acrylonitrile 50 BQL
Benzene 1 BQL
I Bromobenzene 1 BQL
Bromochloromethane 1 BQL
Bromodichloromethane 1 SOL
Bromoform 1 BQL
I Bromomethane 1 BQL
2-Butanone 25 BQL
n-Butylbenzene 1 BQL
I sec-Butyl benzene 1 BQL
tert-Butylbenzene BQL
Carbon disulfide BQL
Carbon tetrachloride BQL
I Chlorobenzene BQL
Chloroethane 1 BQL
2-Chloroethyl vinyl ether 5 BQL
I Chloroform 1 1
Chloromethane BQL
2-Chlorotoluene BQL
4-Chlorotoluene 1 BQL
I_ Dibromochloromethane 1 BQL
1,2-Dibromo-3-chloropropane 5 BQL
Dibromomethane 1 BQL
1,2-Dibromoethane (EDS) 1 BQL I 1,2-Dichlorobenzene 1 BQL
1,3-Dichlorobenzene 1 BQL
1,4-Dichlorobenzene 1 BQL
I trans-1,4-Dichloro-2-butene 5 BQL
1, 1-Dichloroethane 1 BQL
1, 1-Dichloroethene 1 BQL
1,2-Dichloroethane 1 BQL I cis-1,2-Dichloroethene BQL
trans-1,2-dichloroethene BQL
1,2-Dichloropropane BQL
I 1,3-Dichloropropane 1 BQL
2,2-Dichloropropane 1 BQL
1, 1-Dichloropropene 1 BQL
cis-1, 3-Dichloropropene 1 BQL
I trans-1,3-Dichloropropene 1 BQL
Dichlorodifluoromethane 5 BQL
Diisopropyl ether (DIPE) 1 BQL
I Ethylbenzene BQL
Hexachlorobutadiene 1 BQL
2-Hexanone 5 BQL
lodomethane 1 BQL
I lsopropylbenzene 1 BQL
Reviewed by: tw>-..,
ti Flags: BQL = Below Quanrnation Limit Page 1
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PARADIGM ANALYTICAL LABORATORIES, Ii\C.
Client Sample ID: REP-01-GW
Client Project ID: NC0360.042
Lab Sample ID: 15544
Lab Project ID: G149-42
Matrix: Water
Compound
4-lsopropyltoluene
Methylene chloride
4-Methyl-2-pentanone
Methyl-tert-butyl ether (MTBE)
Naphthalene
n-Propyl benzene
Styrene
1, 1, 1,2-Tetrachloroethane
1, 1,2,2-Tetrachloroethane
T etrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
Trichloroethene
1, 1, 1-Trichloroethane
1, 1,2-Trichloroethane
Trichlorofluoromethane
1,2, 3-Trichloropropane
1, 2, 4-T ri methyl benzene
1, 3, 5-Trimethylbenzene
Vinyl acetate
Vinyl chloride
m-, p-Xylene
a-Xylene
Surrogate Spike Recoveries
Compound
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-dB
Comments:
Results for Volatiles
byGCMS 8260
Quantitation
Limit (ug/L)
1
5
5
1
1
1
1
1
1
1
1
1
1
1
1
1
2
1
Spike
Added
(ug/L)
5
5
5
All results are corrected for dilution.
Flags: BQL = Below Quantitation Limit
Date Analyzed: 10/4/96
Analyzed By: RNP
Date Collected: 9/30/96
Date Received: 10/1/96
Dilution: 1.0
Surrogate
Result
(ug/L)
5
4.8
4.9
Result
(ug/L)
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
%Rec
100
96
98
Reviewed by: ½,.
Page2
I PARADIGM Al\ALYTICAL LABORATORIES, INC.
Results for Volatiles
I byGCMS 8260
Client Sample ID: TB-01 9/30/96 Date Analyzed: 10/4/96
I
Client Project ID: NC0360.042 Analyzed By: RNP
Lab Sample ID: 15545 Date Collected: 9/30/96
Lab Project ID: G149-42 Date Received: 10/1 /96
Matrix: Water Dilution: 1.0
I Compound Ouantitation Result
Limit (ug/L) (ug/L)
I Acetone 25 BQL
Acrolein 50 BQL
Acrylonitrile 50 BQL
Benzene BQL
I 13romobenzene BQL
Bromochloromethane BQL
Bromodichloromethane BQL
I Bromoform 1 BQL
Bromomethane 1 BQL
2-Butanone 25 BQL
n-Butylbenzene BQL
I sec-Butylbenzene 1 BQL
tert-Butylbenzene 1 BQL
Carbon disulfide BQL
I Carbon tetrachloride BQL
Chlorobenzene BQL
Chloroethane BQL
I 2-Chloroethyl vinyl ether 5 BQL
Chloroform BQL
Chloromethane 1 BQL
2-Chlorotoluene BQL
I 4-Chlorotoluene BQL
Dibromochloromethane BQL
1,2-Dibromo-3-chloropropane 5 BQL
I Dibromomethane BQL
1,2-Dibromoethane (EDB) 1 BQL
1,2-Dichlorobenzene 1 BQL
I
1,3-Dichlorobenzene BQL
1,4-Dichlorobenzene BQL
trans-1,4-Dichloro-2-butene 5 BQL
1, 1-Dichloroethane BQL
B 1, 1-Dichloroethene BQL
1,2-Dichloroethane BQL
cis-1,2-Dichloroethene 1 BQL n trans-1,2-dichloroethene 1 BQL
1,2-Dichloropropane BQL
1,3-Dichloropropane 1 BQL
2,2-Dichloropropane 1 BQL u 1, 1-Dichloropropene BQL
cis-1,3-Dichloropropene 1 BQL
trans-1,3-Dichloropropene 1 BQL
I Dichlorodifluoromethane 5 BQL
Diisopropyl ether (DIPE) BQL
Ethyl benzene BQL
Hexachlorobutadiene 1 BQL I
Reviewed by: lWb-::
I Flags: BQL = Below Quantitation Limit Page 1
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PARADIGM Ar\AL\TICAL LABORATORIES, li\C.
Client Sample ID: TB-01 9/30/96
Client Project ID: NC0360.042
Lab Sample ID: 15545
Lab Project ID: G149-42
Matrix: Water
Compound
2-Hexanone
lodomethane
lsopropylbenzene
4-lsopropyltoluene
Methylene chloride
4-Methyl-2-pentanone
Methyl-tert-butyl ether (MTBE)
Naphthalene
n-Propyl benzene
Styrene
1, 1, 1,2-Tetrachloroethane
1, 1,2,2-T etrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
Trichloroethene
1, 1, 1-Trichloroethane
1, 1,2-Trichloroethane
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl acetate
Vinyl chloride
m-,p-Xylene
a-Xylene
Surrogate Spike Recoveries
Compound
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-dB
Comments:
All results are corrected for dilution.
Flags: BQL = Below Quantitation Limit
Results for Volatiles
byGCMS 8260
Quantitation
Limit (ug/L)
5
1
5
5
f
1
1
1
1
2
1
Spike
Added
(ug/L)
5
5
5
Date Analyzed: 10/4/96
Analyzed By: RNP
Date Collected: 9/30/96
Date Received: 10/1/96
Dilution: 1.0
Result
(ug/L)
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BOL
BQL
BQL
BQL
BOL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
Surrogate
Result ¾Rec
(ug/L)
5 100
4.8 96
4.8 96
Reviewed by: f:,V),_.
Page 2
I PARADIGM ANAL\TICAL LABORATORIES, INC.
Results for Volatiles
I by GCMS 8260
Client Sample ID: EB-01-GW Date Analyzed: 10/4/96
I Client Project ID: NC0360.042 Analyzed By: RNP
Lab Sample ID: 15546 Date Collected: 9/30/96
Lab Project ID: G149-42 Date Received: 10/1/96
Matrix: Water Dilution: 1.0
I Compound Quantitatio_n Result
Limit (ug/L) (ug/L)
I Acetone 25 BQL
Acrolein 50 BQL
Acrylonitrile 50 BQL
Benzene BQL
I Bromobenzene BQL
Bromochloromethane BQL
Bromodichloromethane BQL
I Bromoform BQL
Bromomethane BQL
2-Butanone 25 BQL
I n-Butylbenzene 1 BQL
sec-Butylbenzene 1 BQL
tert-Butylbenzene 1 BQL
Carbon disulfide BQL
I Carbon tetrachloride BQL
Chlorobenzene BQL
Chloroethane BQL
I 2-Chloroethyl vinyl ether 5 BQL
Chloroform 1 BQL
Chloromethane BQL
2-Chlorotoluene 1 BQL I 4-Chlorotoluene 1 BQL
Dibromochloromethane 1 BQL
1,2-Dibromo-3-chloropropane 5 BQL
m Dibromomethane 1 BQL
1,2-Dibromoethane (EDB) BQL
1,2-Dichlorobenzene BQL
D 1,3-Dichlorobenzene 1 BQL
1 ,4-Dichlorobenzene 1 BQL
trans-1,4-Dichloro-2-butene 5 BQL
1, 1-Dichloroethane BQL
D 1, 1-Dichloroethene BQL
1,2-Dichloroethane BQL
cis-1,2-Dichloroethene BQL
I trans-1,2-dichloroethene 1 BQL
1,2-Dichloropropane BQL
1,3-Dichloropropane 1 BQL
2,2-Dichloropropane 1 BQL I 1, 1-Dichloropropene BQL
cis-1,3-Dichloropropene BQL
trans-1,3-Dichloropropene BQL
I Dichlorodifluoromethane 5 BQL
Diisopropyl ether (DIPE) BQL
Ethylbenzene 1 BQL
I Hexachlorobutadiene 1 BQL
Reviewed by: '-""-" I Flags: BQL = Below Quantitation Limit Page 1
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PARADIGM ANAL\TICAL LABORATORIES, INC.
Client Sample ID: EB-01-GW
Client Project ID: NC0360.042
Lab Sample ID: 15546
Lab Project ID: G149-42
Matrix: Water
Compound
2-Hexanone
lodomethane
lsopropylbenzene
_ 4-lsopropyltoluene
Methylene chloride
4-Methyl-2-pentanone
Methyl-tert-bu1yl ether (MTBE)
Naphthalene
n-Propyl benzene
Styrene
1, 1, 1,2-Tetrachloroethane
1, 1,2,2-Tetrachloroethane
T etrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
Trichloroethene
1, 1, 1-Trichloroethane
1, 1,2-Trichloroethane
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl acetate
Vinyl chloride
m-,p-Xylene
o-Xylene
· Surrogate Spike Recoveries
Compound
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-dB
Comments:
All results are corrected for dilution.
Flags: BQL = Below Quantitation Limit
Results for Volatiles
byGCMS 8260
Quantitation
Limit (ug/L)
5
5
5
1
1
1
1
2
Spike
Added
(ug/L)
5
5
5
Date Analyzed: 10/4/96
Analyzed By: RNP
Date Collected: 9/30/96
Date Received: 10/1/96
Dilution: 1.0
Result
(ug/L)
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BOL
BQL
BQL
BOL
BQL
BQL
BOL
BOL
BQL
BQL
BQL
BQL
BOL
BOL
BQL
BQL
BQL
BQL
BQL
BOL
Surrogate
Result ¾Rec
(ug/L)
4.8 96
5.1 102
5 100
Reviewed by: I'."?:--
Page 2
I PARADIGM ANALYTICAL LABORATORIES, INC.
Results for Volatiles
I byGCMS 8260
Clienl Sample ID: VBLK101196 Date Analyzed: 10/11/96
Client Project ID: NC0360.042 Analyzed By: RNP
I Lab Sample ID: NA Date Collected: NA
Lab Project ID: G149-42 Date Received: NA
Matrix: Water Dilution: 1.0
I Compound Quantitation Result
Limit (ug/L) (ug/L)
Acetone 25 BQL
I Acrolein 50 BQL
Acrylonitrile 50 BQL
Benzene 1 BQL
I Bromobenzene 1 BQL
Bromochloromethane 1 BQL
Bromodichloromethane 1 BQL
Bromoform 1 BQL
I Bromomethane 1 BQL
2-Butanone 25 BQL
n-Butylbenzene 1 BQL
I sec-Butyl benzene 1 BQL
tert-Butylbenzene 1 BQL
Carbon disulfide 1 BQL
Carbon tetrachloride 1 BQL
I Chlorobenzene 1 BQL
Chloroethane 1 BQL
2-Chloroethyl vinyl ether 5 BQL
Chloroform 1 BQL -Chloromethane 1 BQL
2-Chlorotoluene 1 BQL
4-Chlorotoluene 1 BQL
I Dibromochloromethane 1 BQL
1,2-Dibromo-3-chloropropane 5 BQL
Dibromomethane 1 BQL
1,2-Dibromoethane (EDB) 1 BQL I 1,2-Dichlorobenzene 1 BQL
1,3-Dichlorobenzene 1 BQL
1,4-Dichlorobenzene 1 BQL
0 trans-1, 4-Dichloro-2-butene 5 BQL
1, 1-Dichloroethane 1 BQL
1, 1-Dichloroethene 1 BQL
1,2-Dichloroethane 1 BQL I cis-1,2-Dichloroethene 1 BQL
trans-1,2-dichloroethene 1 BQL
1,2-Dichloropropane 1 BQL • 1, 3-Dichloropropane 1 BQL
2,2-Dichloropropane 1 BQL
1, 1-Dichloropropene 1 BQL
cis-1,3-Dichloropropene 1 BQL
I trans-1,3-Dichloropropene 1 BQL
Dichlorodifluoromethane 5 BQL
Diisopropyl ether (DIPE) 1 BQL
I Ethylbenzene 1 BQL
Hexachlorobutadiene 1 BQL
2-Hexanone 5 BQL
lodomethane 1 BQL
I lsopropylbenzene 1 BQL
Reviewed by: ),½,,,
I Flags: BQL = Below Quantitation Limit Page 1
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PARADIGM ANALYTICAL LABORATORIES. INC.
Client Sample ID: VBLK101196
Client Project ID: NC0360. 042
Lab Sample ID: NA
Lab Project ID: G149-42
Matrix: Water
Compound
4-lsopropyltoluene
Methylene chloride
4-Methyl-2-pentanone
Methyl-tert-butyl ether (MTBE)
Naphthalene
n-Propyl benzene
Styrene
1, 1, 1,2-Tetrachloroethane
1, 1,2,2-T etrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
Trichloroethene ·
1, 1, 1-Trichloroethane
1, 1,2-Trichloroethane
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1, 3, 5-T rimethylbenzene
Vinyl acetate
Vinyl chloride
m-,p-Xylene
a-Xylene
Surrogate Spike Recoveries
Compound
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-dB
Comments:
Results for Volatiles
byGCMS 8260
Quantitation
Limit (ug/l)
1
5
5
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
2
Spike
Added
(ug/L)
5
5
5
All results are corrected for dilution.
Flags: BQL = Below Quantitation Limit
Date Analyzed: 10/11/96
Analyzed By: RNP
Date Collected: NA
Date Received: NA
Dilution: 1.0
Surrogate
Result
(ug/L)
4.6
4.5
4.6
Result
(ug/L)
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
%Rec
92
90
92
Reviewed by: k-
Page 2
I PARADIGM ANALYTICAL LABORATORIES, 11\C.
Results for Volatiles
I byGCMS 8260
Client Sample ID: VBLK101096 Date Analyzed: 10/10/96
Client Project ID: NC0360.042 Analyzed By: RNP
I Lab Sample ID: NA Date Collected: NA
Lab Project ID:. G149-42 Date Received: NA
Matrix: Water Dilution: 1.0
I Compound Quanlltatlon Result
Limit (ug/L) (ug/L)
Acetone 25 BQL
I Acrolein 50 BQL
Acrylonitrile 50 BQL
Benzene 1 BQL
I Bromobenzene 1 BQL
Bromochloromethane 1 BQL
Bromodichloromethane 1 BQL
Bromoform 1 BQL
I Bromomethane 1 BQL
2-Butanone 25 BQL
n-Butylbenzene 1 BQL
I sec-Butylbenzene 1 BQL
tert-Butylbenzene 1 BQL
Carbon disulfide BQL
Carbon tetrachloride 1 BQL
I Chlorobenzene 1 BQL
Chloroethane 1 BQL
2-Chloroethyl vinyl ether 5 BQL
I Chloroform 1 BQL
Chloromethane 1 BQL
2-Chlorotoluene 1 BQL
4-Chlorotoluene 1 BQL
I Dibromochloromethane 1 BQL
1,2-Dibromo-3-chloropropane 5 BQL
Dibromomethane 1 BQL
m
1,2-Dibromoethane (EDB) 1 BQL
1,2-Dichlorobenzene 1 BQL
1,3-Dichlorobenzene 1 BQL
1,4-Dichlorobenzene 1 BQL g trans-1,4-Dichloro-2-butene 5 BQL
1, 1-Dichloroethane 1 BQL
1, 1-Dichloroethene 1 BQL
1,2-Dichloroethane 1 BQL u cis-1,2-Dichloroethene 1 BQL
trans-1,2-dichloroethene 1 BQL
1,2-Dichloropropane 1 BQL
m 1,3-Dichloropropane 1 BQL
2,2-Dichloropropane 1 BQL
1, 1-Dichloropropene 1 BQL
cis-1,3-Dichloropropene 1 BQL
I trans-1,3-Dichloropropene 1 BQL
Dichlorodifluoromethane 5 BQL
Diisopropyl ether (DIPE) 1 BQL
I Ethyl benzene 1 BQL
Hexachlorobutadiene 1 BQL
2-Hexanone 5 BQL
lodomethane 1 BQL
I lsopropylbenzene 1 BQL
Reviewed by: w>--
I Flags: BQL = Below Quantilation Limit Page 1
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PARADIGM ANALYTICAL LABORATORIES. INC.
Client Sample ID: VBLK101096
Client Project ID: NC0360.042
Lab Sample ID: NA
Lab Project ID: G149-42
Matrix: Water
Compound
4-lsopropyltoluene
Methylene chloride
4-Methyl-2-pentanone
Methyl-tert-butyl ether (MTBE)
Naphthalene
n-Propyl benzene
Styrene
1, 1, 1,2-Tetrachloroethane
1, 1,2,2-Tetrachloroethane
T etrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
Trichloroethene
1, 1, 1-Trichloroethane
1, 1,2-Trichloroethane
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3, 5-Trimethylbenzene
Vinyl acetate
Vinyl chloride
m-,p-Xylene
o-Xylene
Surrogate Spike Recoveries
Compound
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-dB
Comments:
Results for Volatiles
byGCMS 8250
Quantitation
Limit (ug/L)
1
5.
5
1
1
1
1
1
1
1
1
1
1
1
1
1
2
1
Spike
Added
(ug/L)
5
5
5
All results are corrected for dilution.
Flags: BQL = Below Quantitation Limit
Date Analyzed: 10/10/96
Analyzed By: RNP
Date Collected: NA
Date Received: NA
Dilution: 1. O
Surrogate
Result
(ug/L)
4.1
4.6
4.4
Result
(ug/L)
BQL
BQL
BQL
BQL
BQL
BQL
BQl
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
¾Rec
82
92
88
Reviewed by: 11,.yL.
Page2
I PARADIGM ANALYTICAL LABORATORIES. I!'sC.
Results for Volatiles
I byGCMS 8260
Client Sample ID: VBLK100496 Date Analyzed: 10/4/96
Client Project ID: NC0360.042 Analyzed By: RNP
I Lab Sample ID: NA Date Collected: NA
Lab Project ID: G149-42 Date Received: NA
Matrix: Water Dilution: 1.0
I Compound Quantitation Result
Limit (ug/L) (ug/L)
Acetone 25 BQL
I Acrolein 50 BQL
Acrylonitrile 50 BQL
Benzene BQL
I Bromobenzene BQL
Bromochloromethane 1 BQL
Bromodichloromethane 1 BQL
Bromoform 1 BQL
I Bromomethane 1 BQL
2-Butanone 25 SOL
n-Butylbenzene SOL
I sec-Butyl benzene 1 BOL
tert-Butylbenzene 1 BOL
Carbon disulfide SOL
Carbon tetrachloride SOL
I Chlorobenzene SOL
Chloroethane 1 SOL
2-Chloroethyl vinyl ether 5 SOL
I Chloroform 1 SOL
Chloromethane 1 BOL
2-Chlorotoluene 1 SOL
4;Chlorotoluene 1 BOL
I Dibromochloromethane 1 SOL
1,2-Dibromo-3-chloropropane 5 SOL
Dibromomethane 1 SOL
I 1,2-Dibromoethane (EDB) 1 SOL
1,2-Dichlorobenzene 1 BOL
1,3-Dichlorobenzene 1 BOL
1,4-Dichlorobenzene 1 SOL
I trans-1,4-Dichloro-2-butene 5 SOL
1, 1-Dichloroethane BOL
1, 1-Dichloroethene BOL
1,2-Dichloroethane 1 BOL I cis-1,2-Dichloroethene 1 SOL
trans-1,2-dichloroethene 1 SOL
1,2-Dichloropropane 1 SOL
I 1, 3-Dichloropropane 1 BOL
2,2-Dichloropropane 1 SOL
1, 1-Dichloropropene 1 SOL
cis-1,3-Dichloropropene 1 BOL 0 trans-1, 3-Dichloropropene 1 SOL
Dichlorodifluoromethane 5 BOL
Diisopropyl ether (DIPE) 1 BOL u Ethylbenzene 1 SOL
Hexachlorobutadiene 1 BOL
2-Hexanone 5 SOL
lodomethane 1 BOL
I lsopropylbenzene 1 BOL
Reviewed by: lwc,.
I Flags: BOL = Below Ouantitation Limit . Page 1
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PARADIGM ANALYTICAL LABORATORIES. INC.
Client Sample ID: VBLK100496
Client Project ID: NC0360.042
Lab Sample ID: NA
Lab Project ID: G149-42
Matrix: Water
Compound
4-lsopropyltoluene
Methylene chloride
4-Methyl-2-pentanone
Methyl-tert-butyl ether (MTBE)
Naphthalene
n-Propyl benzene
Styrene
1, 1, 1,2-Tetrachloroethane
1, 1,2,2-T etrachloroethane
T etrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
Trichloroethene
1, 1, 1-Trichloroethane
1, 1,2-Trichloroethane
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1 , 3, 5-T ri methylbenzene
Vinyl acetate
Vinyl chloride
m-, p-Xylene
a-Xylene
Surrogate Spike Recoveries
Compound
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-dB
Comments:
Results for Volatiles
byGCMS 8260
Quantltation
Limit (ug/L)
1
5
5
1
1
1
1
1
1
1
1
1
1
1
1
1
2
1
Spike
Added
(ug/L)
5
5
5
All results are corrected for dilution.
Flags: BQL = Below Quantitation Limit
Date Analyzed: 10/4/96
Analyzed By: RNP
Date Collected: NA
Date Received: NA
Dilution: 1.0
Surrogate
Result
(ug/L)
4.3
5.3
5
Result
(ug/L)
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
%Rec
86
106
100
Reviewed by: Wb.-
Page2
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PARADIGM ANALYTICAL LABORATORIES, INC.
Client Sample ID: J38019
Client Project ID: NC0360.042
Lab Sample ID: 15539
Lab Project ID· G149-42
Analyzed By: CKC
:sample
acetone BQL
acrolein BQL
acrylonitrile BQL
benzene BQL
bro mo benzene BQL
bromochtoromethane BQL
bromodichloromethane BQL
bromoform BOL
bromomethane BQL
2-butanone BQL
n-butylbenzene BQL
sec-butylbenzene BQL
tert-butylbenzene BQL
Carbon disulfide BQL
carbon tetrachloride BQL
chlorobenzene BQL
chloroethane BQL
2-chloroethyl vinyl ether BQL
chloroform BQL
chloromethane BQL
2-chlorotoluene BQL
4-chlorototuene BQL
dlbromochloromethane BQL
1,2-dibromo-3-chloropropane BQL
1,2-dibromomethane BQL
dibromomethane . BQL
1,2-dichlorobenzene BQL
1,3-dichlorobenzene BQL
1,4-dichlorobenzene BQL
trans-1,4-Dichloro-2-butene BQL
dichlorodifluoromethane BQL
1, 1-dichloroethane BQL
1,2-dichloroethane BOL
1, 1-dichloroethene BQL
cis-1,2-dichloroethene BOL
trans-1,2-dichloroethene BQL
1,2-dichloropropane BOL
1,3-dichloropropane BQL
2,2-dichloropropane BQL
1, 1-dichloropropene BQL
cis-1,3-dichloropropene BQL
trans-1,3-dichloropropene BQL
Diisopropyl BQL
ethylbenzene BQL
hexachlorobutadiene BQL
2-hexanone BQL
lodomethane BQL
isopropylbenzene BQL
4-isopropyltoluene BOL
Methyl-tert-butyl ether BQL
Results for MS/MSD
by GC/MS 8260
::sp1Kea ... ~
25 99.4
100 174.3
100 112.4
5 97.2
5 84.2
5 79.8
5 83.7
5 75.7 •
5 119.3
25 82.1
5 118.4
5 115.8
5 115.4
5 110.3
5 100.9
5 91.9
5 111.0
25 0.0 •
5 90.6
5 109.2
5 97.0
5 102.7
5 78_.3 •
5 81.2
5 79.6 •
5 81.0
5 83.4
5 92.5
5 89.2
5 79.6
5 105.8
5 109.7
5 83.6
5 107.4
5 97.5
5 106.7
5 86.4
5 82.7
5 96.9
5 104.4
5 81.9
5 79.0
5 89.2
5 104.2
5 107.4
25 85.0
5 85.0
5 110.9
5 114.3
5 85.4
Page 1
Date Analyzed: 09/14/96
Date Collected: 09/30/96
Date Received: 10/01/96
Matrix: Water-
Limits
on~u Lower Upper
110.0 75.8 124
192.2 >O 225
121.5 76.0 124
113.7 50.9 149
96.0 74.7 125
95.5 78.1 122
99.0 80.9 119
90.0 79.8 120
120.2 54.8 145
88.6 73.6 126
111.1 69.2 131
118.4 74.3 126
119.9 71.8 128
128.2 64.7 135
117.5 75.0 125
106.2 74.2 126
125.4 72.6 127
0.0 • >O 124
105.7 79.6 120
127.5 59.1 141
105.2 73.7 126
110.7 73.2 127
91.5 80.7 119
84.6 80.4 120
92.4 82.3 118
98.7 77.2 123
93.4 77.1 123
101.2 75.6 124
98.9 73.5 126
89.3 63.9 136
120.6 71.1 129
125.7 65.6 134
98.7 80.9 119
125.3 72.0 128
113.4 72.0 128
125.0 68.0 132
103.3 79.6 120
93.9 80.3 120
106.9 73.9 126
121.4 74.2 126
98.2 79.0 121
96.0 76.2 124
96.3 85.0 115
114.6 45.1 155
110.7 65.6 134
96.2 72.3 128
110.7 67.7 132
115.6 76.0 124
120.5 72.7 127
100.6 77.3 123
Limit
~ru Max.
10.2 30
9.8 30
7.7 30
15.6 30
1 :i.1 30
18.0 30
16.8 30
17.3 30
0.7 30
7.6 30
6.3 30
2.2 30
3.8 30
15.0 30
15.2 30
14.3 30
12.1 30
NA . 30
15.4 30
15.5 30
8.1 30
7.5 30
15.5 30
4.1 30
14.8 30
19.7 30
11 .2 30
9.0 30
10.4 30
11.5 30
13.1 30
13.6 30
16.6 30
15.4 30
15.1 30
15.8 30
17.9 30
12.6 30
9.8 30
15.1 30
18.1 30
19.5 30
7.7 30
9.6 30
3. 1 30
12.4 30
26.3 30
4.1 30
5.3 30
16.3 30
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PARADIGM ANALYTICAL LABORATORIES, lt'iC.
Results for MS/MSD
by GC/MS 8260
Client Sample ID: J38Q19
Client Project ID: NC0360.042
Lab Sample ID: 15539
Lab Project tD· G149-42
Analyzed By: CKC
:sample
methylene chloride BQL
4-methyl-2-penta none BQL
naphthalene BQL
n-propyl benzene BQL
styrene BQL
1, 1, 1,2-tetrachloroethane BQL
1, 1,2,2-tetrachloroethane BQL
tetrachloroethene BQL
toluene BQL
1,2,3-trichlorobenzene BQL
1,2,4-trichlorobenzene BQL
1.1, 1-trichloroethane BQL
1, 1,2-trichloroethane BQL
trichloroethene 1.5
trichlorofluoromethane BQL
1,2,3-trichloropropane BQL
1,2,4-trimethylbenzene BQL
1,3,5-trimethylbenzene BQL
Vinyl acetate BQL
vinyl chloride .BQL
m/p-xylene BQL
a-xylene BQL
Comments:
Splkecl MS
5 87.0
25 83.9
5 82.6
5 113.5
5 91.7
5 87.7
5 90.5
5 109.8
5 100.7
5 68.6 •
5 76.3
5 103.2
5 79.5 •
5 99.0
5 108.6
5 137.4
5 102.1
5 108.2
5 86.3 •
5 105,8
10 107.1
5 99.6
Concentrations are on column amounts.
Flags:
• = Out of limits.
NA = Not applicable
BQL = Below quantitation limit.
Page 2
Date Analyzed: 09/14/96
Date Collected: 09/30/96
Date Received: 10/01/96
Matrix· Water
Limits
m,>u Lower Upper
103.7 76.3 124
94.8 81.0 119
104.8 65.7 134
119.1 75.0 125
100.2 78.4 122
101.3 77.6 122
104.7 . 65.8 134
121.2 69.8 130
118.2 38.0 162
82.2" 73,0 127
84.3 71.8 128
119.1 75.8 124
93,7 79.9 120
119.7 33.7 166
121.5 73.5 127
143.1 26.2 174
112.5 46.8 153
117.5 73,8 126
95.2 86.4 114
122.5 70.2 130
111.7 16.2 184
106.4 25.0 175
Reviewed By: \u:::-
Limit
HPD Max.
17.5 30
12.2 30
23.7 30
4.8 30
8.8 30
14.5 30
14.5 30
9.9 30
16.0 30'
18.0 30
9.9 30
14.3 30
16.4 30
18.9 30
11.2 30
4.1 30
9.7 30
8.2 30
9.9 30
14,7 30
4.2 30
6.6 30
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PARADIGM ANALYTICAL LABORATORIES, INC.
Results for Labortory Control Spike (LCS)
by GCIMS 8260
Client Sample ID: LCS101196
Client Project ID: NC0360.042
Lab Sample ID: None assigned
Lab Project ID: G149-42
Analyst ·RNP
acetone
acrolein
acrylonitrile
benzene
bromobenzene
bromochloromethane
bromodichloromethane
bromoform
bromomethane
2-butanone
n-butylbenzene
sec-butylbenzene
tert-butylbenzene
carbon disulfide
carbon tetrachloride
chlorobenzene
chloroethane
2-chloroethyl vinyl ether
chloroform
chloromethane
2-chlorototuene
4-chlorotoluene
dibromochloromethane
1,2-dibromo-3-chloropropane
1,2-dibromomethane
dibromomethane
1,2-dichlorobenzene
1,3-dichlorobenzene
1,4-dichlorobenzene
trans-1,4-dichloro-2-butene
dichlorodifluoromethane
1, 1-dichloroethane
1,2-dichloroethane
1, 1-dichloroethene
cis-1,2-dichloroethene
trans-1,2-dichloroethene
1,2-dichloropropane
1,3-dichloropropane
2,2-dichloropropane
1, 1-dichloropropene
cis-1.3-dichloropropene
trans-1,3-dichloropropene
diisopropyl ether
ethylbenzene
hexachlorobutadiene
2-hexanone
lodomethane
isopropylbenzene
4-isopropyltoluene
methyl-tert-butyl ether
Spiked
25
50
50
5
5
5
5
5
5
25
5 -5
5
5
5
5
5
25
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
25
5
5
5
5
Page 1
Date Collected: Not applicable
Date Received: Not applicable
Date Analyzed: 10/11/96
Matrix: Water
Limits
LCS Lower Upper
95.7 36.7 142
165.8 >0 218
238.5 >0 317
107.1 76.3 120
92.7 80.3 104
92.0 77.1 104
97.5 79.3 . 105
90.1 62.8 104
97.4 >0 183
98.8 55.4 116
111.2 60.2 124
107.3 72.2 119
108.8 72.3 120
115.5 71.8 134
107.7 72.1 116
98.0 74.1 119
112.4 74.6 140
16.9 >0 77
99.8 81.0 107
105.9 32.5 137
99.6 77.4 107
103.6 75.8 111
89.2 78.0 97
86.5 43.3 107
91.7 77.5 105
97.4 72.5 107
92.6 73.1 102
98.3 72.6 107
95.7 77.6 102
76.1 >0 151
113.5 63.0 124
104.7 81.6 111
97.3 79.9 105
116.7 64.6 130
103.3 79.3 112
113.5 73.1 123
98.3 76.4 111
90.9 78.5 105
104.0 73.3 115
109.9 74.1 119
96.0 78.5 104
96.2 68.1 104
92.5 83.0 104
107.8 76.2 120
51.3 62.0 119
96.2 57.0 116
94.1 6.0 143
108.8 72.9 120
109.7 67.8 122
94.2 81.2 100
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PARADIGM ANALYTICAL LABORATORIES, INC.
Client Sample ID:
Client Project ID:
Lab Sample ID:
Lab Project ID:
Results for Labortory Control Spike (LCS)
by GC/MS 8260
LCS101196
NC0360.042
None assigned
G149-42
Date Collected: Not applicable
Date Received: Not applicable
Date Analyzed: 10/11/96
Matri,c: Water
Analyst RNP Limits
Spiked LCS Lower Upper
methylene chloride 5 99.6 75.9 111
4-methyl-2-pentanone 25 95.9 61.5 114
naphthalene 5 109.4 >0 175
n-propyl benzene 5 109.1 71.1 120
~tyrene 5 98.8 77.15 106
1, 1.1,2-tetrachloroethane 5 97.3 75.2 115
1, 1,2,2-tetrachloroethane 5 104.1 67.6 113
tetrach1oroethene 5 106.4 75.5 127
toluene 5 117.1 62.9 133
1,2,3-trichlorobenzene 5 87.2 >0 146
1,2,4-trichlorobenzene 5 86.9 >0 147
1, 1, 1-trichloroethane 5 106.6 76.3 115
1, 1,2-trichtoroethane 5 91.8 78.0 104
trichloroethene 5 106.5 79.9 117
trichlorofluoromethane 5 111.4 66.2 123
1,2.3-trichloropropane 5 109.2 >0 158
1,2,4-trimethylbenzene 5 106.5 72.3 116
1,3,5-trimethylbenzene 5 109.1 70.1 120
vinyl acetate 5 96.3 75.1 106
vinyl chloride 5 114.3 65.4 126
m/p-xylene 10 108.4 74.7 119
a-.xylene 5 105.5 75.9 116
Comments:
Concentration values are on column amount.
Flags:
~ = Out of limits.
NA = Not applicable
Reviewed By: ~
Page 2
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PARADIGM ANALYTICAL LABORATORIES, INC.
SURROGATE RECOVERY LIMITS
62300 8021
1,4-Dichlorobutane 85-120% 83-123%
Trifiuorotoluene 85-122% 84-122%
Bromofiuorobenzene
1,2-Dichloroethane-d4
Toluene-dB
601
87-11"3%
68-132%
82-118%
82-116%
.. GE.TY-
. 0>'& MILLEP '"JC -a;; --..
· lfEnriranm,nl fen Laboratory Task Order No. 2-o (, G
■ he.. Jmpany
:'roject Number d1~6 0 • oc../_z
Project Location 'fZCr /4,.,: f fi AJ (_
Laboratory ,?.,. r.,,, df • <f I""'
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SAMPLE IDENTI'TY
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Code
TH-o I 1 A,176 1,--
t'R-o l-1 ~lj 1
Datemme
Sampled Lab ID
Sample Code: L = Liquid; S = Solid; A = Air
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~HAIN-OF-CUSTODY RECORD
SAMPLE BOTTLE / CONTAINER DESCRIPTION
-·-Page__L
Total No of Bottles/
Containers .
~; 1111
lOTAL
4
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4
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Relinquished by: '" "t'C'• e,,, «,/ I),,,, Vd Organization: . C ,-"L .L.J 4 /11\.1 II"./ Date o/ 1;,'t1'11J: Time /7-:;>i> ~ Intact?
~No N/A Received by: • '" " • • • • • • Organization: IA-L-' Date · 10 I I I 'ft I? Time II : OS:
Relinquished by: __________ Organization: _________ _
Received by: Organization:
Special Instructions/Remarks: -rc_.F,x c+-c.. ? '?l-1 h ~ 7 / U I 6
Deliverv Method: □ In Person
Date_.,L,_..L1_Time, _____ _
Date t 1 · · Time_· ____ _
Seal Intact?
Yes No N/A
D Lab Courier D Other----~---SPECIFY