NCD986190239_19961004_Cherokee Oil_SERB PA SI_Integrated Preliminary Assessment Site Inspection Volume I - Text and Appendices-OCR

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STATE OF
NORTH CAROLINA
Department of Environment, Health,
and Natural Resources
Division Waste Management
Superfund Section
INTEGRATED PRELIMINARY ASSESSMENT/SITE INSPEC71ON
Cherokee Oil Company
NCD 980 799 019
Charlotte, Mecklenburg Co.,NC
Reference No. 06174
October 1996
Douglas Moore
Environmental Engineer
Di_vision Waste Management
S11perfu11d Section
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State of North Carolina
Department of Environment,
Health and Natural Resources
Division of Waste Management
James B. Hunt, Jr., Governor
Jonathan B. Howes, Secretary
William L. Meyer, Director
Ms. Cindy Gurley
NC CERCLA Project Officer
U.S. EPA Region IV
Atlanta Federal Building
100 Alabama St., SW
Atlanta, Georgia 30303-3140
AVA
DEHNR
October 4, 1996
Subj.: Integrated Preliminary Assessment/Site Inspection (PNSI)
Cherokee Oil Company Site
1201 Berryhill Road
Charlotte, Mecklenburg Co., NC
US EPA ID: NCD 980 799 019
Dear Ms. Gurley:
Enclosed is the Intergrated P NSI report completed by the NC Superfund Section for the Cherokee
Oil Company site (US EPA ID: NCD 980 799 019). Cherokee Resources, a waste oil recycling company,
operated the 0.7 acre site located approximately 1.0 mile north of downtown Charlotte from around 1988 to
1994. Cherokee Resources used the warehouse and site as a waste oil processing facility. Cherokee also used
the site as an unpermitted storage facility housing drums, above-ground tanks, underground tanks, vats, tanker
trailers and roll-offs containing hazardous substances. The former operator and current owner of the facility
has been sentenced to 5 I months active imprisonment for conspiracy to violate the federal Clean Water Act
by illegally discharging hazardous substances to the city se:Ver.
Initial investigations by the US EPA revealed that the site posed an imminent fire and explosion hazard
to neighboring businesses and residents. Between November 1994 and December 1995, the US EP_A
Emergency Response and Removal Branch conducted an extensive removal action at the site that included
removal of2,856 drums, two tanker trailers, three 20,000 gallon underground storage tanks, six 30,000 gallon
above-ground storage tanks, six 10,000 gallon above-ground storage tanks, several roll-offs and over 70,000
gallons of free-standing oily waste and sludge from three containment areas.
The NC Superfund Section conducted an Integrated Preliminary Assessment/Site Inspection (P NSI)
to gather data necessary to evaluate the need for further CERCLA remedial action at this site.
P.O. Box 27687,
Raleigh, North Carolina 27611-7687
Voice 919-733-4996
FAX [phone]
An Equal Opportunity Affirmative Action Employer
50% recycled/1 O"h post-consumer paper
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Letter to Ms. Gurley
Integrated PA/SI -Cherokee Oil Co.
October 4, 1996
Page 2.
Soil, surface water and sediment samples were collected by EPA contractors OHM Materials
Corporation and NC Superfund Section personnel and analyzed for volatile organics, semi-volatile organics
including PCB's and pesticides, inorganics and TCLP-metals to characterize the types of contaminants
deposited at the site and their potential migration pathways. Additional information was collected to confirm
the target populations and environments potentially at risk from the site.
Although no groundwater sampling was conducted at the site, the threat to groundwater users is
considered minimal since there are no drinking water wells within 1.75 miles of the site. No releases of any
hazardous substances were found in the surface water sample collected from the unnamed tributary to Stewarts
Creek. An elevated concentration of chromium was found in the sediment sample collected at a storm sewer
outfall which drains the site. However, chromium was not found at elevated levels in on-site soil samples.
Elevated levels of acetone, cis-1,2-dichloroethene and tetrachloroethene were identified in a surface
water sample collected 75 feet upstream of the confluence of the UT and Stewarts Creek. All three
contaminants were identified in source samples collected at the site. However, no releases of these
contaminants were identified in the surface water and sedimerit samples collected below the storm sewer outfall
in the UT, or in the surface water and sediment samples collected below the confluence of the UT and Stewarts
Creek. Based on the analytical results, a release via overland runoff from the site to surface water impacting
the nearest fishery could not be established. Therefore, the threat posed by the site to surface water targets
is minimal.
No evidence of current air releases were established from the site. Soil on the site and along the
overland drainage path remains contaminated with volatile organics, semi-volatile organics and inorganic
compounds. Many of these source areas contain levels of contamination that exceed the published EPA human
health-based benchmarks for soil exposure. However, the soil exposure threat is minimal since the onsite and
offsite sources are securely fenced, there are currently no onsite workers, and the areas of offsite contamination
are inaccessible to offsite workers and trespassers. However, these areas may require assessment and possible
remediation should they become active in the future.
Based on the lack of groundwater and soil exposure targets and the lack of a threat to surface water
targets, the NC Superfund Section recommends that no further CERCLA remedial action is warranted at this
site and that the site be assigned a "No Further Remedial Action Planned" status.
Sincerely,
/}a{.c,f:,,:,·/!J-L{{~<...---.__
Douglas Moore
Environmental Chemist
NC Superfund Section
INTEGRATED PRELlMlNARY ASSESSMENT/SITE INSPECTION
Cherokee Oil Company
NCD 980 799 019
Charlotte, Mecklenburg Co., Ne··
Reference No. 06174
October 4, 1996
Superfund Section
Division of Waste Management
North Carolina Department of Environment, Health
and Natural Resources
Pr~~ared by:
l . ~&-· -6:l~ . ;f,,/1,...,., :, ,..,,:,i . ...... cr-'-"'--
Douglas Moore
Environmental Chemist
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Pa_t DeRosa
Site Evaluation & Removal
I B~anch Head
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TABLE OF CONTENTS
EXECUTIVE SUMMARY
1.0 INTRODUCTION ............................................... 1
2.0 SITE DESCRIPTION ............................................ 1
2.1 Site Location . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1
2.2 Site Description ........................... : . . . . . . . . . . . . . . . . 1
2.3 Operational History ......................................... 4
2.4 Regulatory History .......................................... 5
3.0 WASTE/SOURCE SAMPLING .................................... 7
3 .1.1 Containment Area # 1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7
3.1.2 Containment Area #2 ...... · ................................. 13
3. I. 3 Containment Area#3 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13
3.1.4 UST Area ................................................ 18
3.1.5 Overland Drainage Area ..................................... 20
3 .2 Conclusions .............................................. 20
4.0 GROUNDWATER PATHWAY ................................... 21
4.1 Hydrogeology ............................................ 21
4.2 Targets ................................................. 22
4 .3 Sample Locations . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22
4 .4 Analytical Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 23
4.5 Conclusions ............................................. 23
5.0 SURFACE WATER PATHWAY ........ · .......................... 23
5.1 Hydrology ................................................ 23
5.2 Targets .................................................. 23
5.3 Sample Locations .......................................... 25
5. 5 Conclusions .................... , . . . . . . . . . . . . . . . . . . . . . . . . . 26
6.0 SOIL EXPOSURE AND AIR PATHWAYS .......................... 28
6.1 Physical Conditions ......................................... 28
6.2 Soil and Air Targets ........................................ 28
6.3 Soil Sample Locations ....................................... 29
6.4 Soil Analytical Results ....................................... 29
6.5 Air Monitoring ............................................ 29
6.6 Conclusions ............................................... 29
7.0 SUMMARY AND CONCLUSIONS .................... : ........... 30
APPENDIX A
APPENDIXB
REFERENCES
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LIST OF TABLES
Table 1 A. Analytical Data -March 1996 Source Samples, p. 1 . . . . . . . . . . . . . . . . . 10
Table 1 A. Analytical Data -March 1996 Source Samples, p. 2 . . . . . . . . . . . . . . . . . 11
Table 1 A. Analytical Data -March 1996 Source Samples, p. 3 . . . . . . . . . . . . . . . . . 12
Table 1 B. Analytical Data -Containment Area #3 Soil Samples, p. 1 15
Table 1 B. Analytical Data -Containment Area #3 Soil Samples, p. 2
Table 1 B. Analytical Data -Containment Area #3 Soil Samples, p. 3
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Table 1 C. Analytical Results Summary -Underground Storage Tank Soil Samples . 19
Table 2 Groundwater Population Within a 4 mile radius . . . . . . . . . . . . . . . . . . . . 23
Table 3 Surface Water Analytical Results ............................... 27
Table 4 Residential Population . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 29
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Figure I
Figure 2
Figure 3
Figure 4
LIST OF FIGl}RES
Topographic Site Map ........................................ 2
Site Layout Map . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3
Source Sample Location Map . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9
Site Drainage Map . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 24
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EXECUTIVE SUMMARY
Cherokee Resources, a waste oil recycling company, operated the 0.7 acre site located
approximately 1.0 mile north of downtown Charlotte from around 1988 to 1994. Cherokee
Resources used the warehouse and site as a waste oil processing facility. Cherokee also used the site
as an unpermitted storage facility housing drums, above-ground tanks, underground tanks, vats,
tanker trailers and roll-offs containing hazardous substances. The former operator and current owner
of the facility has been sentenced to 51 months active imprisonment for conspiracy to violate the
federal Clean Water Act by illegally discharging hazardous substances to the city sewer.
Initial investigations by the US EPA revealea that the site posed an imminent fire and
explosion hazard to neighboring businesses and residents. Between November 1994 and December
1995, the US EPA Emergency Response and Removal Branch conducted an extensive removal action
at the site that included removal of2,856 drums, two tanker trailers, three 20,000 gallon underground
storage tanks, six 30,000 gallon above-ground storage tanks, six 10,000 gallon above-ground storage
tanks, several roll-offs and ove~ 70,000 gallons of free-standing oily waste and sludge from three
containment areas.
The NC Superfund Section conducted an Integrated Preliminary Assessment/Site Inspection
(P NSI) to gather data necessary to evaluate the need for further CERCLA remedial action at this
site. Soil, surface water and sediment samples were collected by EPA contractors OHM Materials
Corporation and NC Superfund Section personnel and analyzed for volatile organics, semi-volatile
organics including PCB's and pesticides, inorganics and TCLP-metals to characterize the types of
contaminants deposited at the site and their potential migration pathways. Additional information was
collected to confirm the target populations and environments potentially at risk from the site.
Although no groundwater sampling was conducted at the site, the threat to groundwater users
is considered minimal since there are no drinking water wells within I. 75 miles of the site. No
releases of any hazardous substances were found in the surface water sample collected from _the
unnamed tributary to Stewarts Creek. An elevated concentration of chromium was found in the
sediment sample collected at a storm sewer outfall which drains the site. However, chromium was
not found at elevated levels in or-site soil samples.
Elevated levels of acetone, cis-1,2-dichloroethene and tetrachloroethene were identified in a
surface water sample collected 75 feet upstream of the confluence of the UT and Stewarts Creek.
All three contaminants were identified in source samples collected at the site. However, no releases
of these contaminants were identified in the surface water and sediment samples collected below the
storm sewer outfall in the UT, or in the surface water and sediment samples collected below the
confluence of the UT and Stewarts Creek. Based on the analytical results, a release via overland
runoff from the site to surface water impacting the nearest fishery could not be established.
Therefore, the threat posed by the site to surface water targets is minimal.
No evidence of current air releases were established from the site. Soil on the site and along
the overland drainage path remains contaminated with volatile organics, semi-volatile organics and
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inorganic compounds. Many of these source areas contain levels of contamination that exceed the
published EPA human health-based benchmarks for soil exposure. However, the soil exposure threat
is minimal since the onsite and offsite sources are securely fenced, there are currently no onsite
workers, and the areas of offsite contamination are inaccessible to offsite workers and trespassers.
However, these areas may require assessment and possible remediation should they become active
in the future.
Based on the lack of groundwater and soil exposure targets and the lack of a threat to surface
water targets, the NC Superfund Section recommends that no further CERCLA remedial action is
warranted at this site and that the site be assigned a "No Further Remedial Action Planned" status.
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1.0 INTRODUCTION
Under authority of the Comprehensive Environmental Response, Compensation, and Liability
Act of 1980 (CERCLA) and the Superfund Amendments and Reauthorization Act of 1986 (SARA),
the NC Superfund Section conducted an integrated Preliminary Assessment/ Site Inspection (P NSI)
at the Cherokee Oil Company site (NCD 980 799 019), 1201 Berryhill Road, Charlotte, Mecklenburg
County, North Carolina. The purpose of this assessment was to collect information concerning
conditions at the site sufficient to assess the threat posed to human health and the environment and
to determine the need for additional CERCLNSARA or other appropriate action. The scope of the
investigation included review of available file information, a comprehensive target survey, onsite ·
reconnaissances (August & December, 1995), interviewing neighbors and collecting environmental
samples (March 1996).
2.0 SITE DESCRIPTION
2.1 Site Location
The Cherokee Oil Company site (Cherokee) is located at 1201 Berryhill Road, Charlotte,
Mecklenburg County, North Carolina (Fig. 1) .. The coordinates for the site are 35° 14' 19.0" North
Latitude and 080° 52' 30.0" West Longitude (Ref. 1). To reach the site from Raleigh, travel south
on Interstate 85 to Charlotte, turn right offl-85 at exit 34 and head southeast on Freedom Road
(Highway 27) approx. 1.5 miles towards downtown Charlotte to Berryhill Road. Turn left onto
Berryhill Road and travel north for 0.2 miles. The entrance to the site is located on the right (Fig.
1 ).
The two year-twenty four hour rainfall for Mecklenburg County averages 3. 5 inches (Ref. 2).
Normal annual total precipitation averages 44 inches, while mean annual lake evaporation averages
40 inches, therefore, net annual precipitation averages· 4.0 inches near the site (Ref. 3).
2.2 Site Description
The total area of the site is 0.71 acres (Ref. 4). The site is located between Melton's Tire
Service to the north, Suburban Propane to the east, an abandoned railroad spur to the south and
Berryhill Road to the west (Fig. 2). The surrounding area is used for residential and light industrial
purposes (Ref. 4, Photo 1 ).
Structures on the site included a large rectangular aluminum-sided warehouse surrounded by
an asphalt and concrete parking lot (Photo 2); a concrete loading dock covered by an aluminum roof
on the south end of the warehouse (Photo 3); six 30,000 gallon above-ground storage tanks along
the east wall of the warehouse and loading dock (Photo 3); three, unlined, 3-4 foot tall, concrete
block retaining walls along the east side of the warehouse and loading dock; two square steel vats on
the loading dock (Photo 4) and three underground storage tanks located at a fuel station (Photo 3),
southwest of the warehouse near Berryhill Road. Many of these structures were removed as part of
an EPA removal action. The former site layout is presented in Figure 2 ..
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IEPA Drum Staging Area
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S . · Layout Map
Cherokee Oil Company 111 Berryhill Road
C r!ottc, Mecklenburg Co., N.C.
u~-~PA ID: NCD 980 799 019 . ' Nl"';ot to Scale
!v _) Drawn By: D. Moore (Aug. 1996)
D
'I";:' Fence
.. Overland Drainage P.athway
-Underground Product Distribution Line
I..,_,_ Abandoned Railroad Line
-, Existing Concrete Wall
· -7 Former Concrete Wall
-----=,.. Underground Storm Sewer.
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The remainder of the site is covered with bare soil. The site is surrounded by a chain link
fence containing three entrance gates and topped with concertina and barbed wire (Photos 2, 3; Fig.
2).
The site slopes to the south and southeast from Berryhill Road toward an abandoned railroad
spur along the southern boundary of the property (Figs. 1, 2). A drainage ditch along the railroad
spur intercepts the main site runoff and directs it east to a storm grate. A leaky containment wall
allowed runoff to enter Suburban Propane's property east and southeast of the site (Ref. 6; Photos
5, 6). The site runoff crossed Suburban's property and was intercepted by two other storm grates;
one located in the center of an asphalt parking lot east of the site (Photo 5) and another southeast of
the site between Suburban Propane's office building and the railroad spur (Ref. 6; Fig. 2). Runoff
from spills onto Berryhill Road are intercepted by a storm grate located southwest of the site on the
east side of Berryhill Road (Fig. 2).
All of the above mentioned storm drains are connected by an underground storm sewer pipe
which was shown to carry runoff south through Suburban Propane and Goodwill Industries properties
parallel with Berryhill Road to a junction with a 48 inch storm sewer line at Freedom Road (Ref. 5;
Fig. 4). The storm sewer directs runoff southeast along the south side of Freedom Road for roughly
400 feet to a junction with another 48 inch storm sewer line in front of the D&C Appliances (2100
Freedom Road). The 48 inch line directs runoff south between the E.F. Lombardi Company (2101
Freedom Road) and United Stationers (1949 Freedom Road) buildings to an outfall on an unnamed
tributary of Stewarts Creek (Fig. 4; Photo 7).
2.3 Operational History
According to tax records,'the warehouse was constructed in 1938 (Ref. 4). The site has been
successively owned by City Service Company (I 938-1958) (Ref. 5, p. 6), · Arkansas Fuel Oil
Company (1958-?) (Ref. 7), American Mineral Spirits Company (? -1961), The Pure Oil
Company and Union Oil Co (through merger of Pure Oil Company) (1961-1977), Spurrier Oil
' Company (1977-1983), Gene W. and Billie M. Hartsell (1983), Centennial, Inc. (1983-1987), and
Gene W. and Billie M. Hartsell (1988-present) (Ref. 7).
City Service reportedly operated a fuel distribution facility at the site. Later, City Service
reportedly converted to mineral spirits and chlorinated solvents storage and distribution (Ref. 5, p.
6). The American Mineral Spirits Company is believed to have used the site for storage and
distribution of mineral spirits. The Arkansas Fuel Oil Company, Pure Oil Company and Union Oil
Company are believed to have used the site for storage and distribution of petroleum products.
Chemicals which may have been associated with prior operations at the site include petroleum
products (gasoline, oil, diesel fuel, etc ... ), mineral spirits, alcohols, chlorinated solvents and cleaning
solvents. Wastes associated with prior operations could include spent or off-spec petroleum
products, tank bottoms, spent or off-spec mineral spirits, alcohols or chlorinated solvents.
A fuel station identified in Figure 2 was used to dispense products from three underground
storage tanks located near the southwest corner of the site. ,·
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Gene W. Hartsell and/or Keith Eidson have operated the site under the following company
names: Spurrier Oil Company (1977-1983) (Ref 7), \centennial Inc. (1975-1979), Southtec (1979-
1983), Cherokee Oil Company (1983-1987) and Ch~rokee Resources (I 988-1995) (Ref 8, 9).
Cherokee Resources, a waste oil recycling clmpany, operated the site from approximately
1988 to 1994. Cherokee Resources used the wareh6use and site as a waste oil processing facility·
(Ref 10, p. 2). Cherokee also used the site as an uhpermitted temporary storage facility housing
drums, above-ground tanks, underground tanks, Jats, tanker trailers and roll-offs containing
polychlorinated biphenyls, flammable solids and liqui~s, strong acids and bases, hazardous organic
compounds, hazardous inorganic compounds, waste oil\and sludges (Ref 10, p. 3). A total of2,856
drums were found at the site inside and outside the wariehouse with incompatible waste ty_pes stored
adjacent to each other. A large volume of oily liquid and sludge were reported in three containment
basins on the site and overland migration was visible froin these areas to neighboring properties (Ref
10, p. 1,3).
2.4 Regulatory History
The Cherokee Oil Company's compliance record between 1985-1990 is summarized in the
Mecklenburg County Department of Environmental Prdtection (MCDEP) enforcement report. The
report documents violations of North Carolina Gene}al Statutes §143-215.83, §143-215.84 and
§ 143-215.85 by Cherokee Resources, Inc., for unlawfJl discharges of oil onto the ground and into
surface waters of the State, failure to restore those are1s affected by the oil discharges, and failure
to immediately notify the Department (Ref 6). In February 1990, a Notice of Violation (NOV) letter
was issued to Cherokee Resources by the North Carolina Division of Environmental Management -
Mooresville Regional Office (MRO) in response to con1ditions observed by MCDEP in early 1990
(Ref 6, p. 2). \
Investigations by the Charlotte-Mecklenburg County Utilities Division (CMUD) in December
1990 led to the discovery of a drum-filled warehouse operkted by Cherokee Resources at 925 South
Summit Avenue (Ref 11). The Summit Avenue site\ was referred to local, state and federal
authorities as a potential hazardous waste site. In July 1991, a criminal investigation was conducted . I
by the US EPA Hazardous Waste Section, the US EPA €riminal Investigation Division, the Office
of the Federal Bureau oflnvestigation (FBI), and several s~pport agencies (Ref 10, p. 3). A search
warrant was served to the operator of the Berryhill R6ad facility, and a site investigation was
conducted at both locations. EPA subsequently determine~ that the Summit Avenue location posed
an imminent and substantial endangerment to the publid health, or welfare, or the environment.
I Between August 1991 and March 1993, the US EPA Emergency Response and Removal Branch
~-RRB) conducted an extensive removal action at th~ Sol~th Summit Avenue location (Ref 10, p.
As a result of the criminal investigations, Keith N rland Eidson, Gene Wesley Hartsell and
Theodore Karl Glauser were indicted on charges of conspira y to violate the federal Clean Water Act
regulations by illegally disposing of and otherwise handling wastewaters in violation of permit
I limitations (Ref 12). On June 29, 1994, Keith Norland Eidson and Gene Wesley Hartsell were
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convicted of conspiracy to violate the federal Clean Water Act regulations. On October 17, 1994,
Eidson and Hartsell were each sentenced to 51 months active imprisonment at the Seymour Johnson
Air Force Base in Goldsboro, North Carolina (Ref. 13).
In January 1994, the North Carolina Department of Environment, Health and Natural
Resources (NCDEHNR) requested that the EPA ERRB evaluate the Berryhill Road site for a possible
removal action (Ref. 10, p. 5). A removal site evaluation conducted by ERRB on August 26-27,
1994 concluded that the Berryhill Road site posed an imminent and substantial endangerment to
public health, or welfare, or the environment (Ref. 10, p 6). Between November 1994 and December
1995, EPA conducted a extensive removal action at the Cherokee Resource's Berryhill Road location
(Refs. 5, 16).
Due to the lack of space at the Berryhill Road site, EPA negotiated an access agreement with
Mr. Gene Miller, allowing EPA to conduct the removal activites on the grass-covered lot that he
owns at the intersection ofTuckaseegee and Berryhill Roads, directly across Berryhill Road from the
site (marked as "EPA Drum Staging Area" on Fig. 2). Drums removed from the Cherokee site were
temporarily staged on the Miller property, where they were opened and tested, then segregated based
on compatibility, manifested and shipped offsite to RCRA approved disposal facilities (Ref. 5, p. 2;
Photo 8).
Following completion of the removal activites, EPA scraped the top 3 to 4 inches of topsoil
from the drum staging area on the Miller property and tested it for hazardous substances. EPA
determined that the soil was not hazardous and subsequently used the soil to backfill and grade the
Berryhill Road site. EPA then collected five composite soil samples from the surface soil at the Miller
property (Ref. 40). The results found detectable levels for the following organic compounds:
tetrachloroethene, toluene, ethylbenzene, xylenes, 1,4-dichlorobenzene, 2-methylnaphthalene, ·
phenanthrene, tluoranthene, pyrene, butylbenzyl phthalate, bis(2-ethylhexyl) phthalate, chrysene, and
benzo(b )tluoranthene (Ref. 5, p. 2; Ref._ 18). None of these above-listed contaminants were found at
concentrations exceeding their respective EPA human health-based benchmarks for soil exposure or
the March 1996 North Carolina Inactive Sites Branch soil remediation goals.
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Arsenic was the only inorganic substance detected in all five grid samples at levels exceeding
the health-based EPA soil exposure benchmarks and State Inactive Sites Branch soil remediation
goals. But, since EPA did not collect a background soil sample to represent typical metals
concentrations, it can not be determined whether the levels were significantly above naturally
occurring background levels. Additionally, since arsenic was found in low levels (<2 ppm) in bulked
waste samples from the site, and no elevated arsenic concentrations were detected in on-site soil
samples, the arsenic detected in soil on the Miller property does not appear to be attributable to the
operation or cleanup of the Cherokee Oil Company site. Therefore, based upon the low levels of
organic contaminants and the implication that the arsenic levels found on the Miller property may
have been a pre-existing condition, the Miller property is not considered a source associated with the
Cherokee Oil Company site.
EPA On Scene Coordinator Steve Spurlin concluded that no significant contamination
remained on the property (Ref 40). EPA then backfilled and reseeded the Miller property with 3 to
4 inches of clean topsoil (Ref 14, p. 2; Ref 40; Photo 9).
On August 9, 1995, NC Superfund Section personnel conducted an initial on-site
reconnaissance at the Cherokee Oil Company site on Berryhill Road to document site conditions and
to meet with the US EPA On-Scene Coordintor (OSC) Steve Spurlin regarding on-going removal
actions by EPA (Ref 5). NC Superfund Section personnel returned to the site on March 6 and 13,
1996 following completion of the removal action (Ref 16). At that time, the Section collected
environmental and source samples to document residual on site containment, off-site contaminant
migration and to assess the need for further remedial action under CERCLNSARA.
3.0 WASTE/SOURCE SAMPLING
Following completion of the removal action by the US EPA, five areas of residual soil
contamination were identified at the Cherokee Resources Berryhill Road site. These areas include
the former locations of three concrete-walled above-ground spill contaminment basins (Areas #1, #2
and #3), the former underground storage tank area, and contaminated soils in the overland drainage
pathway from the site. The sources are shown in Figure 2.
3.1.l Containment Area #1
Containment Area # 1 was a concrete-walled containment structure located at the south end
of the loading dock at the main warehouse building on the site (Fig. 2). Prior to the removal action,
the area reportedly contained 13-28 inches of oily liquids and sludges. This above-ground basin
measured 61 feet long, by 26 feet wide, or 1,586 square feet in area. No surface cover or liner was
in place (Ref. 5) EPA pumped an estimated 17,842 gallons of oily liquid and sludges from the
containment basin, tested the material for hazardous categorization, then manifested and shipped the
waste off-site to RCRA-approved disposal facilities (Ref 5, attachment 5). EPA then removed the
concrete walls
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and excavated the visibly contaminated soils from the bottom of the basin, and backfilled the basin
to grade with several feet of clean soil (Ref. 14).
Prior to backfilling, EPA collected one surficial composite soil sample from the bottom of the
excavation (CO-WS-16) and a second composite soil sample at 3 feet below the bottom of the
excavation (CO-WS-17). Both samples were shipped to AquaChem Environmental Laboratories of
Pineville, NC for VOC analysis per method 8240, SVOC analyses per method 8270 and totals
analyses of 8 RCRA metals (Ref 15).
AquaChem Labs identified acetone (420 ug/kg), 2-hexanone (140 ug/kg), ethylbenzene (55
ug/kg), toluene (74 ug/kg), total xylenes ( 480 ug/kg), 2-methylnaphthalene (3,900 ug/kg), bis (2-
ethylhexyl) phthalate (41,000 ug/kg), naphthalene (2,400 ug/kg) and phenanthrene (1,700 ug/kg) in
the surficial soil sample, and acetone (320 ug/kg), ethylbenzene (150 ug/kg), toluene (2,300 ug/kg),
total xylenes (1,350 ug/kg), 2-methylnaphthalene (930 ug/kg), bis(2-ethylhexyl)phthalate (16,000
ug/kg) and napthalene (1,000 ug/kg) at 3 feet below the bottom of the excavation. Several metals
were reported above the detection limit, but no background soil sample was collected for comparison
(Ref. 15).
On March 6, 1996, NC Superfund Section staff augered 2.5-3.0 feet below the existing
backfill grade and collected a soil sample (CO-002-SB) of the bottom of the former excavation at
containment basin # I to verify the previous soil sample results and characterize any potential pesticide
or metals contamination (Fig. 3; Photo 10). A subsurface soil sample (CO-001-SB) was collected
at 2.5-3.0 feet deep from a grass lot on the Miller property west of the EPA drum staging area,
approximately 500 feet northwest of the site (Fig. 3). This soil sample, collected from the same soil
profile and type as the soil sample collected at the site, was used to represent typical background
conditions for area soils. Both samples were submitted to the State Laboratory of Public Health for
VOC analyses per method 8240, SVOC analyses per method 8270, PCB/Pesticide analyses per
method 8080 and totals and TCLP metals analyses (Ref 16; Fig. 3).
As shown in Table IA, acetone (102 ug/kg), 1,1-dichloroethane (6 ug/kg), cis-1,2-
dichloroethene (32 ug/kg), I, I, I-trichloroethane (9 ug/kg), trichloroethene (31 ug/kg), toluene (309
ug/kg), tetrachloroethene (386 ug/kg); chlorobenzene (I 1 ug/kg), ethyl benzene (234 ug/kg), total
xylenes (I, 116 ug/kg), I, 4-dichlorobenzene (20 ug/kg), 1,2-dichlorobenzene ( 51 ug/kg), naphthalene
(467 ug/kg), phenanthrene (1,467 ug/kg), fluoranthene (3,600 ug/kg), pyrene (5,933 ug/kg), chrysene
(2,267 ug/kg), benzo(b)fluoranthene (2,067 ug/kg), benzo(a)pyrene (3,150 ug/kg), indeno(l,2,3-
cd)pyrene (1,700 ug/kg), benzo(g,h,i)perylene (4,133 ug/kg), 2-methylnaphthalene (5,833 ug/kg),
dibutyl phthalate (I, 133 ug/kg), butyl benzyl phthalate (8,000 ug/kg), bis(2-ethylhexyl)phthalate
(30,333 ug/kg) and di-n-octyl phthalate (7,833 ug/kg) were detected at 2.5-3.0 feet below grade in
the former containment basin #1. No PCB's, pesticides or elevated total metals were identified in the
subsurface soil sample. None of the TCLP results exce!!ded their current respective RCRA §261.24
standards for toxicity characteristic (Appendix A; Table IA; Ref. 41).
Of the compounds listed above, benzo(b)fluoranthene, benzo(a)pyrene and indeno(l,2,3-
cd)pyrene were detected in the subsurface soil sample CO-002-SB at concentrations that exceeds
their August I 996 EPA human health-based soil exposure screening benchmarks of 880 ug/kg, 88
ug/kg and 880 ug/kg, respectively (Ref 17).
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\
. CO-00!-SL (background surface soil) i D
{ co-oo,,ss ,-,-"" ~ ,,_,_, '"'' \J
CO-004-SL (surface soil)--C:::=¥:.\ \ : ,---':
CO-003-SB (@ 2.5-}.0 fei°') ~ I
CO-WS-28(UST#8@!0-l2feet)~"1 \ \ J
CO-WS-31 (UST#7@ IO-l2fcct) _j \_._1 ;---(\ 1
CO-WS-38(UST#7@10-12fect) i Oft).<.:= _I
. . CO-002-SB (@ 25-3· ee 1-----
Figure 3.
Source Sample Location Map
Cherokee Oil Company
120 I Berryhill Road
Charlotte, Mecklenburg Co., N.C.
US EPA ID: NCO 980 799 019
Map Not to Scale
Map Drawn By: D. Moore (Aug. 1996)
Soil Samples
\ \
Contaminant
Acetone
Methylene Chloride
1, 1-Dichloroethane
2-Butanone
Cis-1,2-Dichloroethene
Chloroform
1, 1, 1-Trichloroethane
Benzene
1, 2-Dichloroethane
Trichloroethene
Bromodichloromethane
Toluene
1, 1,2-Trichloroethane
2-Hexanone
Tetrachloroethene
Chlorobenzene
Ethvl Benzene
Xvlene(s)
1,4-Dichlorobenzene
1, 2-Dichlorobenzene
Methyl-tert-butvl ether
~-~ 111111 ----- - --- - - - - - ---_.
Units CO-001-SL CO-001-SB
UQ/ka <20.0 5J,C
ua/ka < 5.0 7J,C
ua/ka < 5.0 BDL
ua/ka < 20.0 BDL
ua/ka < 5.0 BDL
ua/ka < 5.0 BDL
ua/ka < 5.0 BDL
ua/ka < 5.0 BDL
ua/ka < 5.0 BDL
ua/ka < 5.0 BDL
ua/ka < 5.0 BDL
ua/ka < 5.0 BDL
ua/ka < 5.0 BDL
ua/ka < 10.0 BDL
ua/ka < 5.0 BDL
ua/ka < 5.0 BDL
ua/ka < 5.0 BDL
ua/ka < 5.0 BDL
ua/kQ < 5.0 BDL
ua/ka < 5.0 BDL
ua/ka < 5.0 BDL
Table lA.
Cherokee Oil Company
Charlotte, Mecklenburg County, N.C.
US EPA ID: NCD 980 799 019
Analytical Data -March 1996 Source Samples
CO-002-SB CO-003-SB CO-004-SL CO-005-SL
!IIIB!l02:J!~■l:i<l BIJOo!ffH -227.!JIB BDL
BDL 3J,C BDL BDL I-■6-l ■-9.■-2J BDL
6J 5J 18J BDL
1-3~ trace trace BDL
BDL trace trace BDL
-■-,■II! HI 2J trace BDL
4J 2J !IIIB!6■-BDL
trace BDL trace BDL
■1111!1:l-lJ trace BDL
BDL BDL trace BDL -309-■-27■11! -111/Za• BDL
BDL trace BDL BDL
BDL BDL 4J BDL
-3'861111! :■ trace ■-Z■II! BDL -m trace BDL BDL
trace ■1!12'1■11! BDL
'lo■-4J -1:251111! BDL
BDL BDL BDL
trace trace BDL
BDL lll!ll5■11! trace BDL
10
CO-OJ6-SL EPA Soil Stds (mQ/ka).
BDL 7,800 (RfD)
2J,C 85 (CPF)
BDL 7,800 (RfD)
BDL 47,000 (RfD)
BDL 780 (RfD)
BDL 100 (CPF)
BDL none issued
BDL 22 (CPF)
BDL 7.0 CCPF)
BDL 58 CCPF)
BDL l 0 (CPF)
BDL l 6,000 (RfD)
BDL 11 (CPF)
BDL none issued
BDL 12 (CPF)
BDL 1,600 (RfD)
BDL 7,800 (RfD)
BDL 160,000 (RfD)
BDL 27 (CPF)
BDL 7,000 (RfD)
BDL none issued
3, ;J / • 03
?1-/.J'
(, '(r, ! (, 'l-
/•l /, o < 7 $.
2,~/ •O/i
'?to /s-.s-
Contaminant Units
Naphthalene uo/ko
Acenaohth, lene uo/ko
Acenaohthene ua/ko
Fluorene ua/ka
Phenanthrene ua/ka
Anthracene ua/ka
Fluoranthene ua/ka
Pyrene ua/ka
Benz( a)anthracene ua/ka
Chrysene uq/ka
Benzo(b )ftuoranthene uq/kq
Benzo(a)pyrene uq/kq '
lndeno(l,2,3-cd)ovrene uq/kq
Dibenzo(a.h)anthracene UQ/kq
Benzor a,h, i)oerylene UQ/kq
Dibenzofuran uo/ko
2-methvlnaohthalene uo/ko
Dibutvlohthalate uo/ko
Butvl Benzvl Phthalate uo/ko
Bis(2-ethvlhe)(\/l)nhthalat, uo/ko
Di-n-octy I phthalate ua/ka
PCB 1254 ma/ka
-~----------------
CO-001-SL CO-001-SB
< 330,0 BDL
< 330.0 BDL
< 330,0 BDL
< 330,0 BDL
< 330,0 BDL
<330.0 BDL
< 330.0 BDL
< 330,0 BDL
< 330,0 BDL
< 330,0 BDL
< 1650.0 BDL
< 1650.0 BDL
< 1650.0 BDL
< 1650.0 BDL
< 1650,0 BDL
< 330,0 BDL
< 330.0 BDL
< 330,0 BDL
< 330.0 BDL .
< 330,0 BDL
< 330,0 BDL
< 0,1 < 0,1
Table lA.
Cherokee Oil Company
Charlotte. Mecklenburg County, N.C.
US EPA ID: NCD 980 799 019
Analytical Data -March 1996 Source Samples
CO-002-SB CO-003-SB CO-O:J4-SL CO-005-SL
--4o7-llll4G0llll 330 K 330 K
BDL -3o7-330 K 330 K
330 K 330 K 330 K BDL
330 K 330 K 330 K BDL
-l!'ll6:?--583-lilllif333irll 330 K
330K !Jillll67,--667-330K
ey ' 500'11 Bll0IOOO'II Bllll~U033-;
5)9 333'11 III31'333'11 f' . "" jro)-
BDL Bl'l2;6o7Jill BDL }7:50-__ ,26 irll'4f333!11 1111'61'000'11 6/53'3-
-2TOo 7r,7,33Jlli III601000'II -1~!23
-3!'150-'90011 t ' . . B112.1f6o711 2;03
IBltlllrZO\..llirll IIIS0:$33'11 Bll,90;6o7II l2T6oZ
BDL III24!533lll •21:2133311 BDL
--4~1:33-!1160180011 •128f667B '11112,11200-
330 K 330 K 330 K 330 K
IIIII5YBS3-!illl!'-2o7Jill 330 K 330K
-l~l:'33Blirll BDL Bll61oo78 BDL
-8!G00J!IIJII! BDL Bll'30]667BI BDL
IIIll30}33'3-Bl9l500!11 Bll03}33311 -t97533-
-7,!BS3IIIII BDL BDL BDL
< 0,1 < 0.1 < 0.1 < 0,1
11
CO-OJ6--SL EPA Soil Stds (mo/km.
330 K 3,100 (RfD)
330 K none issued
BDL 4,700 (RfD)
BDL 3,100 (RfD)
330 K none issued
330 K 23,000 (RfD)
-7J:J0-3. 100 (RfD)
!illljl 00irll 2,300 (RfD)
BDL 0.88 (CPF)
BDL 88 (CPF)
Bl'll¾900.III 0.88 (CPF)
!1113:21 0.088 (CPF)
!1115!26 0.88 (CPF)
BDL 0.088 (CPF)
llfl'.2,f433lll none issued
BDL none issued
BDL none issued
BDL 7,800 (RfD)
BDL 16.000 (RfD)
Bl5~133irll 46 (CPF)
BDL 1,600 (RfD)
_1,111-0.083 (CPF)
--... - - - - - ----- - - - -_1_,
IF' · Contaminant Units CO-001-SL CO-001-SB
Arsenic mc/ka 2.8 4.4
CLP-Arsenic mo/L <0.01 <0.01
Barium mo/ka 124 68
CLP-Barium mq/L 0.59 0.44
Cadmium mq/ka < 10.0 < 10.0
CLP-Cadmium mall <0.05 <0.05
Chromium ma/ka 22 30
TCLP-Chromium mall <0.05 <0.05
Coooer mglka 34 52
CLP-Conner mall <0.05 <0.05
Lead mulka 36 20
CLP-Lead mall <0.10 <0.10
Mercury malka <0.1 < 0.1
CLP-Mercury moll <0.01 <0.01
Selenium malka < 1.0 < 1.0
CLP-Selenium mqll <0.005 <0.005
Sliver mplka < 10.0 < 10.0
Table lA.
Cherokee Oil Company
Charlotte, Mecklenburg County, N.C.
US EPA ID: NCD 980 799 019
Analytical Data -March 1996 Source Samples
CO-002-SB CO-003-SB CO-004-SL CO-005-SL
2.6 2 2.5 2.9
<0.01 <0.01 <0.01 < 0.01
82 124 140 63
0.75 1.27 0.67 0.43
< 10.0 < 10.0 < 9.8 < 9.8
<0.05 <0.05 <0.05 <0.05
30 38 55 16
<0.05 <0.05 <0.05 <0.05
62 46 55 55
<0.05 <0.05 <0.05 <0.05
58 20 25011 I 111190
<0.10 <0.10 0,211111!. ii! < 0. l 0
< 0.1 < 0.1 0ft12-Bil < 0. l
<0.01 <0.01 <0.01 <0.01
< 1.0 < 1.0 < 1.0 < 1.0
<0.005 <0.005 <0.005 <0.005
< 10.0 < 10.0 < 9.8 < 9.8
CO-006-SL EPA Soil Stds.
2.9 0.43 ma/ka CCPF)
<0.01 5.0 ma/l (I CLP Umit)
57 5,500 ma/ka (RID)
0.49 l 00.0 ma/L (TCLP)
<9.8 39 ma/ka (RfD)
<0.05 l .0 ma/L ( I CLP Limit)
41 390 mq/kq (RID)
<0.05 5.0 mq/l (l CLP Limit)
37 none issued
<0.05 none issued
,lW-400.0 malka (EPA)
<0.10 5.0 moll (TCLP Limit)
< 0.1 23 ma/ka (RID)
<0.01 0.2 mall (TCLP Limit)
< 1.0 390 mq/kg (RID)
< 0.005 l .0 mgll CTCLP)
<9.8 390 malka (RID)
CLP-Silver moll <0.05 <0.05 <0.05 <0.05 < 0.05 < 0.05 < 0.05 5.0 ma/L (TCLP)
Zinc ma/kp 56 62 92 44 WO-w{}-29'-23,000 malka (RID)
CLP-Zinc ma/L 0.07 · 0.12 0.32 0.09 1!!~7?1-'-'i1'76'.I-~ 2r";?IJ['. • none issued
Shading indicates >I= 3 x background, or> background, 1f bkgd. = ND BDL = Below Detection Um1t
_____ _ouJd.indicates-a-concentration in excess of applicable EPA soil exposure or TCLP regulatory standards. J = estimated concentration
CPF -refers to the August l 'l, 1996 EPA SCDM Cancer Risk Screening Concentration standard (Ref. 17). C = possible lab contaminant
RfD -refers to the August l \', 1996 EPA SCDM Reference Dose Screening Concentration standard (Ref. 17).
EPA -refers to the EPA soil lead guidance level (Ref. 42). ··
TCLP -refers to the Toxicity Charactertstic Leaching Procedure as outlined in NCAC Title 15A, Chapter 13A, Appendix IL Method 131 l.
TCLP Umit -refers to the TCLP regulatory standard (NCAC, Ttile 15A. Chapter 13A. Subpart C, section 261.24, table I). (see Ref. 41 ).
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3.1.2 Containment Area #2
Containment Area #2 was located at the southeast corner of the main warehouse building
(Fig. 2). This was a concrete-walled structure surrounding\ six above-ground storage tanks,
apparently as a spill control measure (Ref. 5; Photo 11). Pnior to the removal, the structure
reportedly contained 12-18 inches of oily liquids and sludges and bccupied an area of approximately
3,088 square feet (Ref. 5, attachment 5). There was no surface co~er or liner in place at containment
area #2 (Ref. 14). During the emergency removal action, EPA puniped approximately 30, I 08 gallons
of the oily liquids and sludges from the basin, tested the materials\for hazardous categorization, and
then manifested and shipped the materials off-site to RCRA aBproved disposal facilities (Ref. 5,
attachment 5). EPA then removed the basin walls and excavated the visibly contaminated soils from ~~e bottom of the basin, and backfilled the basin to grade with sej~eral feet of clean soil (Ref. 14, p.
On March 6, 1996, NC Superfund Section staff auger d 2.5-3.0 feet below the existing
I backfill grade and collected a subsurface soil sample, (CO-003-SB) from the bottom of the former
excavation at containment basin #2 to characterize any remainirig contamination (Photo 12). The
sample was submitted to the State Laboratory of Public Health fot VOC analyses per method 8240,
SVOC analyses per method 8270, PCB/pesticide analyses per Jethod 8080 and totals and TCLP
metals analyses (Ref. 16; Fig. 3). j
As shown in Table IA, acetone (106 ug/kg), toluene (27 ug/kg), methyl-tert-butyl ether (5
ug/kg), napthalene (400 ug/kg), acenaphthylene (367 ug/kg), phe anthrene (583 ug/kg), anthracene
I
( 467 ug/kg), fluoranthene (I 8,500 ug/kg), pyrene (21,333 ug/kg), benz( a )anthracene (2,667 '-!g/kg),
chrysene (4,333 ug/kg), benzo(b)fluoranthene (37,733 ug/kg),\ benzo(a)pyrene (56,900 ug/kg),
indeno(l,2,3-cd)pyrene (50,333 ug/kg), dibenzo(a,h)anthracene (24,533 ug/kg), benzo(g,h,i)perylene
(60,800 ug/kg), 2-methylnaphthalene (1,267 ug/kg) and bis(2-e\hylhexyl)phthalate (9,500 ug/kg)
were detected at 2.5-3.0 feet below grade at containment area #2) No PCB's, pesticides or elevated
metals were identified in the subsurface soil sample. None of\the TCLP results exceeded their
respective RCRA §261.24 standards for toxicity characteristic (Appendix A; Table IA; Ref. 41) .
. I Of the compunds listed above, benzo(a)anthracene, benzo(b)fluoranthene, benzo(a) pyrene, I
indeno(l,2,3-cd)pyrene and dibenzo(a,h)anthracene were detected in the subsurface soil sample CO-
003-SB at concentrations that exceed their August 1996 EPA ~uman health-based soil screening
I • benchmarks of 880 ug/kg, 880 ug/kg, 88 ug/kg, 880 ug/kg, and 88 ug/kg, respectively (Ref. 17).
3.1.3 Containment Area #3
Containment Area #3 was a concrete-walled structure ocated directly east of the main
warehouse (Fig. 2; Photo 13). Prior to the removal, this containmcint basin reportedly contained 16-,
24 inches of oily liquids and sludges. The area of this basin was 2,440 square feet (Ref. 5, attachment
5). There was no surface cover or liner in place at containment areal#3 (Ref. 14) .During the removal
action, EPA pumped approximately 24,339 gallons of the oily liquids and sludges from the basin, I
tested the materials for hazardous categorization, manifested an1 shipped the materials off-site to
RCRA approved disposal facilities (Ref. 5, attachment 5). EPA left the concrete walls intact and
excavated a small quantity of the visibly contaminated_ soils from the bottom of the basin (Ref. 14,
16). EPA left inaccessible residual soil contamination in place at this area.
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Prio, , o comple<iog <he ,emoeal ,o<loo, EPA ooll~.J foo, ooll sampl~ of <he resldo,1
' contamination at Containment Area #3. The four soil sample locations are described below and
designated on Figure I of Appendix B. A 5-point composite sample (CO-SS-0 I) was collected from
surficial soil within the containment basin. A subsurface soil sample (CO-SB-03) was collected from
the 1-1.5 foot deep soil profile at the center of the composite soil sample CO-SS-01. Another
subsurface soil sample (CO-SB-04) was collected from the 3-3.5 foot deep soil profile at the center
of the composite soil sample CO-SS-01. EPA collected an additional 5-point composite soil sample
(CO-SS-02) from the crawlspace under the decking of the maiti building. The soil samples were
shipped to Kiber Environmental Services, Inc. of Atlanta, Geoigia for VOC analyses per method
8260, SVOC analyses per methods 8270A and 3550, total PCB's: analyses per methods 3550, 3665
and 8080 and Total RCRA metals analyses per methods 305 I, 7470 and 60 JOA (Appendix B; Table
IB).
The analytical results from the soil sampling of containment area #3 detected elevated
concentrations of acetone, benzene, 2-butanone, l;I-dichlordethane, ethylbenzene, methylene
I • chloride, 4-methyl-2-pentanone, tetrachloroethene, toluene, I, I, I-trichloroethane, trichloroethene,
xylenes, bis(2-ethylhexyl)phthalate, butyl benzyl phthalate, di-n-butyl phthalate, di-n-octyl phthalate,
phenanthrene and pyrene. Although metals were detected in th~ soil samples, no background soil
sample was collected for comparison. The sample results are sumrrlarized in Table IB (Appendix B).
On March 6, 1996, NC Superfund Section staff collected a iurficial soil sample (CO-004-SL)
from visibly contaminated surface soil remaining in the former Containment Area #3 to verify the
previous soil sample results and characterize any potential pesticidb or metals contamination (Fig. 3;
Photo 14). A surficial background soil sample (CO-001-SL) was ccillected at 0-6 inches from a grass
lot on the Miller property west of the EPA drum staging area, apJroximately 500 feet northwest of ' the site (Fig. 3; Photo 15). Both samples were submitted to the State Laboratory of Public Health I for VOC analyses per method 8240, SVOC analyses per method 8270, PCB/pesticide analyses per
• I method 8080 and totals and TCLP metals analyses (Ref 16; Fig. G).
. I As shown m Table IA, acetone (227 ug/kg), benzene (6 ug/kg), toluene (I, 170 ug/kg), ' tetrachloroethene (7 ug/kg), ethyl benzene (27 ug/kg), total xylenes ~125 ug/kg), phenanthrene (1,333
ug/kg), anthracene (667 ug/kg), fluorantherie (10,000 ug/kg), pyrene (31,333 ug/kg), chrysene I (16,000 ug/kg), benzo(b)fluoranthene (60,000 ui/kg), benzo(a)pyrene (121,667 ug/kg),
indeno(l,2,3-cd)pyrene (190,667 ug/kg), dibenzo(a,h)arithracene (212,333 ug/kg),
benzo(g,h,i)perylene (128,667 ug/kg), dibutylphthalate (6,667 ug/kg), butyl benzyl phthalate (130,667
' ug/kg), bis(2-ethylhexyl)phthalate (703,333 ug/kg), lead (250 mg/kg), mercury (0.12 mg/kg) and zinc
(600 mg/kg) were detected in the surface soil sample collected at d:ontainment Area #3. Leachable
concentrations of lead (0.2 mg/I) and zinc (4.77 mg/I) were detedted in this sample (Appendix A;
Table IA). None of the TCLP metals results exceeded the RC:r1 §261.24 standards for toxicity
characteristic (Appendix A; Table IA; Ref. 4 !).
Of the compounds listed above, benzo(b)fluoranthene, benzo(a)pyrene, indeno(l,2,3-
cd)pyrene, dibenzo(a,h)anthracene, and bis(2-ethylhexyl)phthalate were detected in surficial soil
I
sample CO-004-SL at concentrations that exceed their August 1996 EPA human health-based soil
screening benchmarks of880 ug/kg, 88 ug/kg, 880 ug/kg, 88 ug/k 1 and 46,000 ug/kg, respectively
(Ref. I 7).
14
-~~~---------------
-Acetone
Benzene
2-Butanone (MEK)
-1 )-Dichloroethane
Ethylbenzene
Methylene Chloride
4°Methyl~2-Pentanone
Tetrachloroethene
-Toluene
TABLE JB.
CHEROKEE OIL -BERRYHILL SITE
ANALYTICAL DATA
SOIL SAMPLES
VOLATILES (ug/kg)
140 91 1540E
22 SJ 3.9J
ND ND 110
100
ND
25
19 3:9J ND ND
44 3.7J 6J ND
220B 210B. 6.4BJ 4.2BJ
75 46 39 4.5J
110 7.lJ 2.2J ND
290 96. 27 ND
-1,1,1-Trichloroethane 6.4J ND ND ND
CONTAINMENT AREA #3 __
ND
ND
ND
ND
ND
4.5J
ND
ND
ND
ND ,)
-------ii-Trichlorethene, ____ --+--8.81--f-----1,1)---+---'2-,-2--1---,..--5:6F---l------tJ-n----\l-----------
Xylene,. total 500 24 25 ND ND
Notes: ND -Not Detected
B -The compound was present in the laboratory blank
J -Estimated value; the concentration was below the practical quantitation limit (PQL).
E -Estimated value; the concentration exceeded the calibration range of the instrument.
15.
·--.&SZ-
- ---- - -~ l!!!!I -----liiilliiil -----
TABLE lB. --: --..
CHEROKEE OIL -BERRYHILL SITE CONTAINMENT AREA #3
ANALYTICAL DATA
SOIL SAMPLES
SEMIVOLATILES (ug/kg)
bis(2-Ethylhexyl)phthalate 44000J 87000 4100 1400
Buty lbenzy lphthalate ND · SOOOJ N.D ND
Di-n-butylphthalate ND ND !!OJ 89J
Di-n-octylphthalate 2300J 5300J 67J ND
Phenanthrene ND 3900J ND ND
Pyrene ND 3100J ND ND
Notes: ND -Not Detected
J -Estimated value; the concentration was below the practical quantitation limit (PQL).
' 16,
-------------------
Arsenic ND
Barium 220B
Cadmium 17
Chromium 130
Lead 290
Mercury ND
Selenium ND
Silver ND
-----

-
TABLE lB. • ..
CHEROKEE OIL -BERRYHILL SITE
ANALYTICAL DATA
SOIL SAMPLES
RCRA METALS (mg/kg)
ND ND
200B 300B
l.4J 2.2J
42 39
79 28
ND ND
5.9J 16J
ND ND
CONTAINMENT AREA #3 .
ND ND
65B 0.003]
ND ND
47 ND
24 ND
ND ND
ND ND
ND ND
------Note:,··.---NB ----Not-Betecttecl--------------------------------------
B -The analyte was present in the laboratory blank
J -Estimated value; the concentration was below the practical quantitation limit (PQL).
, 17.
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3.1.4 UST Area
A fuel station was located at the southwest corner of the1 site near Berryhill Road (Photo 3;
Fig. 2). During the EPA removal action, the fuel station was demolished and three underground
I storage tanks (designated UST's #7, #8, and #9) were removed. EPA reported that a distribution line
running from the loading dock to the underground storage tank :leaked an oily waste to the subsoil
under the concrete pad at the refueling island. The oily subsoil Jas scraped to visibly clean soil and
• I
shipped offsite to an approved RCRA disposal facility (Ref. 14; Fig. 2).
EPA pumped the liquids from th~ US T's, tested the matlrials for hazardous catgorization,
manifested and shipped the materials off-site to approved RCI}A disposal facilities. Due to the
quantity of sludges remaining within the tanks, EPA removed the US T's, cleaned out the sludges,
manifested and shipped the sludges off-site to approved RCRA 6isposal facilities. The tanks were
then cut up and removed from the site. The base of the excavati6n was approximately 14 feet deep
(Ref. 14, p. 3).
Approximately 100 cubic yards of soil from the UST excavation was stockpiled by EPA on ' the site. On December 04, 1995, a soil sample of the stockpile (CO-WS-38) was submitted to
Savannah Laboratories for VOC analyses per method 8240 and !svoc analyses per method 8270.
No metals analyses were requested. The soil sample exhibited elev~ted concentrations of 2-butanone
• I (20,000 ug/kg), toluene (7,400 ug/kg), ethylbenzene (2,800 ug/kg), xylenes (1,700 ug/kg), 2-
methylnaphthalene (10,000 ug/kg), diethylphthalate (18,000 ugYkg), di-n-butyl phthalate (36,000 ' ug/kg), butylbenzyl phthalate (93,000 ug/kg) and bis(2-ethylhexyl)phthalate (120,000 ug/kg). (Ref.
I 14, p. 2, Ref. 18). Of the compounds listed above, bis(2-ethylhexyl)phthalate was the only compound
identified at a concentration that exceeds its August 1996 EPA human health-based soil screening
• I benchmark of 46 mg/kg (or 46,000 ug/kg) (Ref. 17; Table IO; Fig. 3). The soil stockpile was
reportedly used to regrade the site (Ref. 14).
EPA also collected two subsurface soil confirmation samples from underneath UST #7 (CO-
WS-31) and UST #8 (CO-WS-28) (Ref. 17; Fig. 3). The soil samJies were submitted to AquaChem
Environmental Laboratories of Pineville, NC for VOC analyses per 1method 8240 and SVOC analyses I per method 8270. No metals analyses were requested. The saTple results for CO-WS-31. found
elevated levels of ethylbenzene (44 ug/kg), toluene (19 ug/kg), xylenes (226 ug/kg), di-n-butyl
phthalate (9,754 ug/kg), butyl benzyl phthalate (24,568 ug/kg) and ~is(2-ethylhexyl)phthalate (38,541
I ug/kg) from the soil sample taken underneath UST #7 (Ref. 19; 1[able 1 C). The soil sample results
for CO-WS-28 found elevated levels of benzene (95 ug/kg), ethylbenzene (170 ug/kg), I
tetrachloroethene (I 75 ug/kg), toluene (45 ug/kg), total xylenes (500 ug/kg), bis(2-
' ethylhexyl)phthalate (3,592 ug/kg), and butyl benzyl phthalate (3,355 ug/kg) from the soil sample
taken underneath UST #8 (Ref. 20; Table 1 C). EPA backfilled tlie excavation with topsoil scraped
from the removal drum staging area, located at the Miller prope~y across Berryhill Road from the
site (Ref. 14). None of the contaminant concentrations found in subsurface soil samples from
underneath UST #7 or UST #8 exceed their respective EPA hhman health-based soil screening
benchmarks (Ref. 17; Table 1 C; Fig. 3).
No additional soil samples were collected from the USTI area during the March 1996 NC
Superfund Section sampling trip, since the excavation had been bacl<filled. The base of the excavation
I is estimated to be approximately 30 feet long by 20 feet wide, or 600 square feet. There are no liners
or leachate collection systems in place at the UST excavation are1 (Ref. 14, p. 2, 3).
18
-------------------
Table lC.
.,
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Analytical Results Summary-Underground Storage Tank Soil Samples
Cherokee Oil Company -Charlotte. N.C.-NCD 980 799 019.
Contaminant CO-WS-31 UST #7 CO-WS-38 UST #7 ile EPA S . ds.
Benzene ND DL 22
Eth I benzene \Iii . · 1800-7,8
Tetrachloroethene ND DL 12
Toluene l9B ?l!OO-16.
Total X lenes _.5 Q2 7,00-160, lf'-"-'-=..:..:.L.=..=------'='-='---4===== l, 2-Dichlorobenzene N · f5
ND = Not Detected; NA= Not Analysed; BDL = Below Detection Limit.
Shading indicates elevated concentrations;
Bold represents highest levels found in remaining UST excavation soil confirmation samples.
CPF -refers to August 19, 1996 EPA SCDM Cancer Risk Screening Concentration standard (Ref. 17).
RfD -refers to August 19, 1996 EPA SCDM Reference Dose Screening Concentration standard (Ref. 17).
19 I.
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3.1.5 Overland Drainage Area
Prior to closure of the Cherokee Oil facility, Mee lenburg County Department of
Environmental Protection (MCDEP) received numerous complaints from neighbors about discharges
I from the site running across downgradient properties. In January 1990, MCDEP videotaped one such
discharge of a waste oil originating at the southeast comer of the si/e near Containment Area #I. The
discharge ran overland for 75-100 feet along two drainage featur~s between the southwest corner of ' the adjacent Suburban Propane property and the spur line, where it was subsequently intercepted by
storm grates #2 arid #3 (Fig. 2). The combined surface area of both drainage features is 200 feet long
by 20 feet wide, or 4,000 square feet. There are no liners, run-ora or run-off prevention.systems or
leachate collection systems in place along the overland drainagetrea (Ref. 5, p .6).
On March 6, 1996, NC Superfund Section staff collected two surficial soil grab samples to
assess the impact to soils from both drainage features and documbnt contaminant migration off site.
A surficial soil sample (CO-005-SL) was collected from 0-12 incH soil profile from the railroad spur ' drainage ditch that connects the southeast comer of the Cherokee site to storm grate #3 (Ref. 16; Fig.
3; Photo 16). A second surficial soil sample (CO-006-SL) wa! collected from the 0-12 inch soil
profile at the southwest corner of the Suburban Propane building. I Both soil samples were submitted
to the State Laboratory of Public Health for VOC analyses per r1ethod 8240, SVOC analyses per
method 8270, PCB/pesticides per method 8080 and total and TCLP metals analyses (Ref. I 6; Fig.
3).
No VOC's were identified in either of the two surficial soil samples (Appendix A; Table IA).
As shown in Table IA, tluoranthene (4,033 ug/kg), pyrene (5,000 ug/kg), benz(a)anthracene (6,750
ug/kg), chrysene (6,533 ug/kg), benzo(b)tluoranthene (14,233 ug/kg), lienzo(a)pyrene (12,033
ug/kg), indeno(J,2,3-cd)pyrene (12,667 ug/kg), benzo(g,h,ijperylene (21,200 ug/kg), bis(2-
ethylhexyl)phthalate (19,533 ug/kg) and zinc (totals: 630 mg/kgl TCLP: 6.76 mg/I) were detected
in the drainage ditch surficial soil sample (CO-005-SL). Elevated lbvels oftluoranthene (700 ug/kg),
pyrene (I, I 00 ug/kg), benzo(b )tluoranthene (1,900 ug/kg), benio(a)pyrene (3,217 ug/kg), indeno
(1,2,3-cd)pyrene (5,267 ug/kg), benzo(g,h,i)perylene (12,433 hglkg), bis(2-ethylhexyl)phthalate
(5,133 ug/kg), PCB-1254 (1.ll mg/kg), lead (160 mg/kg) and zi~c (total: 290 mg/kg, TCLP: 2.78
mg/I) were detected in the surficial soil sample CO-006-SL colle~ed at the southwest corner of the
Suburban Propane building (Appendix A; Table IA). ~uburban 1ropane was subsequently notified
of the soil sample analytical results (Ref. 21 ).
'
Of the compound listed in the previous paragraph, benzo(b)tluoranthene, benzo(a)pyrene, and
indeno(l,2,3-cd)pyrene were identified in the surficial soil samplbs CO-005-SL and CO-006-SL in
excess of their August 1996 EPA human health-based soil scree~ing benchmarks of880 ug/kg, 88
ug/kg and 880 ug/kg, respectively (Ref. I 7). PCB-1254 was idbntified in the surficial soil ~ample
CO-006-SL in excess of its August 1996 EPA human health-based !oil screening benchmark of0.083
mg/kg (or 83 ug/kg) (Ref. 17) and benzo(a)anthracene was detectbd in the surficial soil sample CO-
005-SL in excess of it's August 1996 EPA human health-based soil I creening benchmark of 880 ug/kg
(Ref. 17).
3.2 Conclusions
The analytical results demonstrate releases of numerous •ERCLA hazardous substances to
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\
.,,n,;,1 '"' sobsmfaee ,o;ls • ,he Chernkee 0;1 Comp'"y J Amoog <he'"""" pre,ioosly
outlined, acetone, anthracene, benzene, benzo(a)anthracene, benio(a)pyrene, benzo(g,h,i)perylene,
benzo(b )fluoranthene, bis(2-ethylhexyl)phthalate, butyl benzyl phthalate, chrysene, di-n-butyl
phthalate, dibenzo(a,h)anthracene, ethyl benzene, fluorantherie, indeno(l,2,3-cd)pyrene, lead,
mercury, PCB-1254, phenanthrene, pyrene, tetrachloroethene, t~luene, total xylenes and zinc were
detected within 2 feet of the surface. Of the compounds listed above, benzo(a)anthracene, I
benzo(b )fluoranthene, benzo(a)pyrene, indeno( I ,2,3-cd)pyrene, dibenzo(a,h)anthracene, and bis(2-
ethylhexyl)phthalate and PCB-1254 were detected in excess oftheir respective August 1996 EPA
human health-based soil screening benchmarks. l
Acenaphthylene, acetone, anthracene, benzene, ben o(a)anthracene, benzo(a)pyrene, I benzo(b )fluoranthene, benzo(g,h,i)perylene, bis(2-ethylhexyl)phthalate, butyl benzyl phthalate,
chlorobenzene, chrysene, dibenzo(a,h)anthracene, di-n-butyl plithalate, di-n-octyl phthalate, 1,2-,
dichlorobenzene, 1,4-dichlorobenzene, I, 1-dichloroethane, cis-1,2-dichloroethylene, ethyl benzene,
fluoranthene, indeno(l,2,3-cd)pyrene, 2-methylnaphthalene, n~phthalene, phenanthrene, pyrene,
tetrachloroethene, toluene, I, I, I-trichloroethane, trichloroethylehe and total xylenes were detected
I in several source areas at depths greater than 2 feet below the surface at the site. Of the compounds
listed above, benzo(a)anthracene, benzo(b)fluoranthene, benzo(a) p~rene, indeno(l,2,3-cd)pyrene and
dibenzo( a,h)anthracene were detected in excess of their respective August 1996 EPA human health-
based soil screening benchmarks.
4.0
4.1
GROUNDWATER PATHWAY
Hydrogeology
Mecklenburg County is located in the Charlotte Belt of the Piedmont Physiographic Province
(Ref 22). This area is typically underlain by three zones; (1) a reg· lith zone (2) a transition zone and
I (3) an underlying fractured crystalline bedrock. The regolith zone is composed of saprolite ( clay rich
residual materials derived from inplace weathering of bedrock), all~vium (deposits of unconsolidated
sediments by streams and rivers) and soil (the uppermost layer referred to as the natural medium for
plant growth) (Ref 23). Measurements of the hydraulic conductivity for the regolith zone saprolite
at the nearby GE-Charlotte site averaged 3.2 x 10·• cm/sec (Refl 24). The transition zone is where
the unconsolidated material grades into bedrock consisting Jrimarily of saprolite and partially
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weathered bedrock (Ref 23). The fractured bedrock has a crystalline texture with numerous closely
spaced fractures near the bedrock surface. Fracture frequency ahd size decrease with depth due to
increasing lithostatic pressure (Ref 23). The bedrock of the Charlqtte belt under the site is composed
primarily of pinkish gray, massively to weakly foliated, granitic rock containing hornblende (Ref 22).
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Groundwater is recharged by rainfall which is stored in the regolith zone and gradually
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percolates into the transition and fractured bedrock zones (Ref. 23). Both the transition zones and
I the fractured bedrock zones can be used as transfer zones for groundwater. However, most wells
are cased beyond the transition zone into bedrock (Ref 23). The/fractures in the bedrock can act as
conduits which serve to transfer water to discharge points such as wells (Ref 23).
Based upon regional well logs, the regolith zone averageJ 5 to 60 feet thick depending upon
topography (Ref. 23, p. 12). The transition zone averages aboul 15 feet thick. Fractured bedrock
wells do not usually extend beyond 400 feet (Ref 23). Measurements of groundwater levels in 1988 I . at the nearby GE-Charlotte site ranged from 27 to 35 feet below land surface (Ref 25).
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Groundwater flow would be expected to follow gravity and topography from areas of high to low
elevation indicating that groundwater flow for the site would be exp:ected to flow south and southeast
towards the unnamed tributary to Stewarts Creek and Stewarts • reek. Groundwater at the nearby
GE-Charlotte site reported flows to south-southeast (Ref. 24).
4.2 Targets
A majority of residents within a 4 mile radius of the site ely on drinking water drawn from
surface water intakes located on Lake Norman and Mountain I Island Lake and operated by the
Charlotte Mecklenburg Utilities Department (CMUD). Both intakes are located upstream of the site
on a separate branch of the Catawba River (Ref. 26). CMUD opJrates lines that extend over a four
mile radius of the site and most residents have access to city wat'er (Fig. 1 ).
In 1991, a groundwater use survey within a 0.5 mile radiJ of the site was conducted as part
I of an investigation of the GE-Charlotte site, located less than 0.1 miles north of the site (Ref. 5,
attachment 2). A subsequent review of the CMUD water line maps by Superfund Section personnel
in 1996 confirmed that no residents were identified within a 0.5 mile radius of the site who were not
tapped into the CMUD municipal water system (Ref. 5, p.12). The nearest known private
groundwater well is located approximately 3.2 miles northwest of the site at 158 Pinebrook Drive
(Ref. 27; Fig. I). There are 43 houses within a 3-4 mile radiuslthat have groundwater wells in an
area between Old Mt. Holly Road and Paw Creek (Ref. 27; Figil)
There are five community wells located within a 4.0 mil radius of the subject site; Mineral
Springs MHP within a 1-2 mile radius; Juniper Drive Water Systedi and Farmington within a 2-3 mile I
radius; and Trexler Park and Parkwood MHP within a 3-4 mile radius (Ref. 27; Fig. 1). The Mineral I Springs MHP community well represents the nearest known drinking water well to the site (Ref. 27). I
The total groundwater population served by both private groun1water and public community wells
within a 4 mile radius is presented below in Table 2.
Table 2.
Groundwater Population within a 4 mile radius I .
11H!~r-1~11!~;1!t~1, !~!;:~::,! 1~~~!v:;f ~l1! !~ i11~,~~!:l~l::;:~!11 !:r!et;t ei!l~~!I !ilW?t?~1!1t!~M~
1.0 -2.0 miles 0 0 Mineral Sprinos 108 108
2.0 -3.0 miles 0 0 Juniper Drive 94 203
Fmmington 109
3.0 -4.0 miles 43 108 Trexler Park I 114
Parkwood MHP 157
379
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There are curr. ently no wellhead protection areas designated wit[in Mecklenburg County (Ref. 28).
4.3 Sample Locations
No groundwater samples were collected during the March 1996 NC Superfund Section Site
Inspection sampling trip since no groundwater users were iden 1ified within a 0.5 mile radius of the
site.
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4.4 Analytical Results
No groundwater samples were collected during the Site Inspection.
4.5 Conclusions
A release to groundwater is suspected based upon past disposal practices, the conte11ts and
conditions of the underground storage tanks, visible observation and analytical data indicating surface
and subsurface soil contaminatiqn at the site ( as deep as 14 feet below land surface), the relatively
shallow depth to groundwater (27 to 35 feet below land surface), physical characteristics of certain
contaminants spilled at the site such as mobility and water solubility, and the moderate conductivity
of the regolith and saprolite. However, the threat posed to groundwater users is minimal since no
groundwater users were identified within 1.75 miles of the site during the investigation.
5.0 SURFACE WATER PATHWAY
5.1 Hydrology
The site is not located within any floodplain category (Ref 29). Runoff from the Cherokee
Oil Company site is carried via a storm sewer south through Suburban Propane and Goodwill
Industries properties parallel with Berryhill Road to a junction with a 48 inch storm sewer line at
Freedom Road (Figs. 2, 4). The storm sewer directs runoff southeast along the south side of
Freedom Road for roughly 400 feet to a junction with another 48 inch storm sewer line in front of
theD&C Appliances (2100 Freedom Road). The 48 inch line directs runoff south between the E.F.
Lombardi Company (2101 Freedom Road) and United Stationers (1949 Freedom Road) buildings
to an outfall on an unnamed tributary of Stewarts Creek (Fig. 4; Ph9to 7). The total overland
distance from the site to the outfall is approximately 3,200 feet (Fig. 1 ). The outfall marks the
probable point of entry (PPE) of site runoff to surface water.
Beginning at the outfall, the unnamed tributary to Stewarts Creek (UT) flows southeast for
0.4 miles to a confluence with Stewarts Creek (Fig. 1 ). The mean annual flow of the unnamed
tributary to Stewarts Creek is 1.67 cubic feet per second (cfs) (Ref 30). Stewarts Creek flows south
for 0.4 miles to a confluence with Irwin Creek. Stewarts Creek has a mean annual flow of 12.65 cfs.
Irwin Creek flows south and southwest for 3.8 miles to a confluence with Sugar Creek. Irwin Creek
has a mean annual flow of28.6 cfs. Sugar Creek flows primarily south and southeast to the ,end of
the 15 mile surface water pathway. Sugar Creek has a mean annual flow of 76.34 cfs (Ref 30).
5.2 Targets
No surface water intakes are located within 15 miles downstream of the site (Ref 26). · Most
residents of Charlotte are served by CMUD which operates surface water intakes on Lake Norman
and Mountain Island Lake reservoirs, upstream of the site on the Catawba River (Ref 26). Residents
not served by the municipal system obtain drinking water from private or public wells (Ref 27).
Stewarts Creek, Irwin Creek and Sugar Creek are used for recreational fishing (Ref 31 ).
23
11!!!!1 -,' ---1!!!!i. 1m1 -.ill --llll!II -liiil --... 1i1i1 111111
Figure 4.
/ ,Site Drainage Map
l showing surface water sample locations
c Cherokee Oil Company.
1201 Berryhill Road
Charlotte, Mecklenburg Co., N.C.
US EPA ID: NCO 980 799 019
(Adapted from Charlotte Engineering Dept Storm Sewer Maps) ~~i'rr:---;------j:--'7
7 Map Scale reduced from original, . . . ·
µ,~~~=H::;+µ~~~,
690
691.7
r--
.PARKIN --+---
□ Open Storm Grates
....._. Underground Storm Sewer Lines
6 Surface Water/Sediment Samples
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Aquatic species commonly caught in these creeks include Largemouth Bass, Bream, Sunfish and
Catfish (Ref 3 I).
The closest documented point where fish are taken for consumption is approximately 0.4 mile
downstream from the PPE near the confluence of the UT and Stewarts Creek (Ref 31; Photo 17).
According to the National Wetland Inventory maps, a linear palustrine forested wetland
borders the entire 0.4 mile segment of the UT to Stewarts Creek (Ref 32). Soil Conservation Service
maps and hydric soils index reports identify the soil type as monacan, a soil type which has hydric
inclusions capable of supporting wetland vegetation (Refs. 33, 34). At the request of the NC
Superfund Section, Mr. Steven Lund of the Army Corps of Engineers Office in Asheville visited the
area. Mr. Lund determined that there are currently no identifiable wetlands along either side of the
UT to Stewarts Creek downstream to the confluence with Stewarts Creek (Ref. 35). The nearest
downstream wetland has approximately 0.1 miles of frontage along Irwin Creek, located
approximately 4.6 miles downstream of the subject site near the confluence oflrwin and Sugar Creek
(Ref 32, attachment). A total of5.5 miles of wetland frontage were calculated along the entire 15
mile surface water pathway (Ref 32).
Based upon review of the NC Natural Heritage Program maps, two observations of the state
endangered mussel Lasmigona Decorata, otherwise known as the Carolina Heelsplitter, were
identified within 15 miles downstream of the site (Ref 36). Last known observations for the Carolina
Heelsplitter were in the l 870's (Ref 3 7). A survey of the drainages for endangered mussels was
conducted in the mid 1980's by Brunswick College professor Eugene Keferl. Professor Keferl
confirmed by telephone that his study found no observations of the Carolina Heelsplitter in Irwin or
Sugar Creek along the 15 mile downstream surface water pathway (Ref 38).
5.3 Sample Locations
On March 6, 1996, three discrete surface water and sediment samples were collected from
the UT to Stewarts Creek to determine whether there had been a release from the site (Ref. 16; Fig.
4). A background surface water (CO-001-SW) and sediment sample (CO-001-SD) were collected
from a point on the UT approximately 50 feet upstream of the storm sewer outfall (Photo 18). A
surface water (CO-002-SW) and sediment sample (CO-002-SD) were collected at the PPE from a
pool below the storm sewer outfall to establish a release to surface water (Photo 7). A Surface water
(CO-003-SW) only a sediment sample (CO-003-SD) was collected from a small drainage ditch that
receives runoff from businesses along Thrift Road to serve as a control sample for attribution
purposes (Photo 19). On March 6, Stewarts Creek was too swollen from recent rains to collect any
environmental samples (Ref. 16; Photo 20).
The NC Superfund Section personnel returned to the site on March 13, I 996, and collected
two surface water and sediment samples from Stewarts Creek to complete the sampling efforts. A
background surface water (CO-004-SW) and sediment sample (CO-004-SD) were collected from a
point approximately 70-75 feet upstream of the confluence of the UT and Stewarts Creek to establish
natural background conditions (Photo 21). A surface water (CO-005-SW) and sediment sample (CO-
005-SD) were collected approximately 10 feet below the confluence of the UT and Stewarts Creek
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to determine whether a release to the nearest fishery had occurred (Ref I 6; Photo 22).
5.4 Analytical Results
Surface water and sediment samples collected on March 6 and 13, 1996 by NC Superfund
Section personnel were submitted to the State Laboratory of Public Health for volatile organics
(VOC), semi-volatile organics (SVOC), metals and polychlorinated biphenyls (PCB) and pesticides
analyses. The analytical results for surface water and sediment samples are summarized in Table 3
and copies of the lab results are included in Appendix A. The sample locations are presented on
Figure 4.
Compared to the background surface water sample from the UT (CO-00 I-SW), no release
ofVOC's, SVOC's, Metals, PCB's or Pesticides were identified in the surface water sample (CO-002-
SW) collected below the storm sewer outfall. Compared to the background sediment sample from
the UT (CO-001-SD), no release of VOC's, SVOC's, PCB's or Pesticides were identified in the
sediment sample (CO-002-SD) collected below the storm sewer outfall. However, chromium (22
mg/kg) was detected in the downstream sediment sample (CO-002-SD) at levels considered
significantly above the background sample. Compared to the background sediment (CO-001-SD)
sample from theUT, elevated concentrations ofPCB-1260 (10.68 mg/kg) and lead (210 mg/kg) were
identified in the control sediment sample (CO-003-SD) collected from the drainage ditch that receives
runoff from Thrift Road (Appendix A).
Compared to the background surface water sample.(CO-004-SW) and sediment sample (CO-
004-SD), no elevated concentrations ofVOC's, SVOC's, Metals, PCB's or Pesticides were identified
in the surface water (CO-005-SW) or sediment sample (CO-005-SD), collected below the confluence
of the UT and Stewarts Creek. Of particular note, the background surface water sample (CO-004-
SW) collected from Stewarts Creek exhibited elevated concentrations of acetone (225 ug/1), cis-1,2-
dichloroethene (5 ug/1), and tetrachloroethene (7 ug/1). However, none of these contaminants were
identified in the downstream surface water sample (CO-005-SW).
5.5 Conclusions
A release of hazardous substances from the site to the UT of Stewarts Creek was not
established in the downstream surface water and sediment samples (CO-002-SW and CO-002-SD).
Although chromium was detected at elevated levels in the downstream sediment sample, no elevated
chromium levels were identified in the onsite source or overland runoff soil samples. Elevated levels
of PCB's and lead were identified in the control sample taken from a drainage ditch approximately
75 feet south of the merge of Thrift and Freedom Roads. This drainage ditch primarily directs runoff
from businesses along Thrift Road to the UT (Fig. 4). Since the Cherokee Oil Company site does
not drain to Thrift Road, it is not considered a source for the contaminants found in the control
sample. Nonetheless, these contaminants were not detected in the downstream surface water (CO-
005-SW) or sediment samples (CO-005-SD) collected below the confluence of the UT and Stewarts
Creek.
Elevated levels of acetone, cis-1,2-dichloroethene and tetrachloroethene were identified in a
26
--- --- - - -- - ---
Table 3.
Cherokee 011 Company-1201 Berryhill Road-Charlotte, Mecklenburg Co., NC (EPA ID: NCD 980 799 019)
Surface Water Analytical Results
- -
~Unnomed,frtrwffl'ffll.to~stewarts·Creek~~{'D;ffl W1f:1%t®f$¼~S1ewart'l·Crffk~~
Background Re180$8 Background Release Control Background Release Background Release
Com....,..,. •nds Units CO-O:Jl-5\1/ co-roz-sw CO-OJI-SD CO-OJ2-S[J CO-003-SD CO-OJ4-SW CO-005-SW CD-004-50 CO-OJ&SD
Acetone = 4.0J,C <20.0 <:20.0 ND ND fffl/]225 'J~WJmj ND 7.0J ND
l, 1-Dtchloroelhene ~b <:5.0 ND <:5.0 BDL ND BDL ND ND ND
Methv1ene Chl011de = <:5.0 ND 3.0J,C ND l.OJ,C <:5.0 ND ND ND
l, 1-Dlchloroethane ~h <:5.0 ND BDL ND BDL BDL ND: ND ND
Cls-1,2-Dlchloroethene <:5.0 ND <:5.0 I.OJ ND ~S§.fal BDL ND ND
Chloroform = <:5.0 ND <:5.0 ND ND 1.0 J BDL ND ND
Benzene = <5.0 ND <:5.0 BDL ND <5.0 ND ND ND
r1chloroethene = <:5.0 ND BDL l.OJ ND 1.0J ND ND ND
Bromodlchloromethone = <5.0 ND <:5.0 ND ND BDL ND ND ND
4-methvf.2-""""tanone = < 10 ND < 10 ND ND BDL ND ND ND
oluene -< 5.0 ND <5.0 ND ND BDL ND ND ND
etrachloroethene -1.0 J ,, BDL I.OJ I.OJ ND -7-BDL ND ND
Chlorobenzene -<5.0 ND <5.0 ND BDL BDL ND ND ND
c:"'"'ene <5.0 ND <5.0 ND ND BDL ND ND ND
1.2 Dlchlorobenzene BDL <5.0 <:5.0 ND ND BDL ND ND ND
J = Estimated value, C"' Possible lob Contaminant. BDL "' Detected at o concentration Below the Detection limit. ND "' Not Detected
Dlbutvl ""'lhotote = < 10 ND <330 ND ND BDL BDL <330 ND
Butvl ben~,j ohlholote ,-< 10 ND <330 ND ND BDL BDL <330 ND
Bis r2-ethv1hev,.,f\ ""'tholote ,-< 10 BDL <330 ND ND BDL BDL <330 ND
BDL = Detected at a concentration Below the Detection Umlt
PCB's -~ NA NA <0.Gl ND PCB]2tlffl0: NA NA <0.01 ND
Endrln ,~ NA NA <0.01 ND ND NA NA < O.Ql ND
Undone ,~ NA NA <0.02 ND ND NA NA <0.02 ND
Methoxvchlor ,~ NA NA < 1.0 ND ND NA NA < 1.0 ND
oxontiene ,~ NA NA <2.0 ND ND NA NA < 2.0 .. ND
Chlordane ,~ NA NA <0.2 ND ND NA NA <0.2 ND
Heotochlor ,~ NA NA <0.l ND ND NA NA <0.1 ND
Heotochlor E""xlde ,~ NA NA <0.l ND ND NA NA <0.1 ND
NA"' Not Analysed
ABenlc ,= < O.Ol ND <2.0 ND 20 <0.0l ND < 1.9 ND
Barium ,~ 0.□7 0.08 32 BO 7D 0.06 0.07 55 58
Cadmium ,~ < O.CXJ2 ND < 10.0 ND ND <0.002 ND <9.B ND
Chromium . ,~ <0.0l ND <10.0 -22!J!B ~25~ 0.02 0.011 29 30
Con..-,.,,r ,~ <0.05 ND 32 4B 43 <0.05 ND 25 20
Lead ,~ 0.007 0.009 < 20.0 ND ~2-40·~ <0.005 ND <20 ND
Mercurv ,~ < o.ocos ND <0.1 ND ND < O.COJS ND <0.1 ND
Se!enfum ,~ <0.005 ND < 1.0 ND ND <0.005 ND < 1.0 ND
Sliver <0.05 ND < 10.0 ND ND <0.05 ND <9.8 ND
nc <0.05 ND 2B 4B 86 <0.05 ND 35 34
ND"' Not Detected
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surface water sample collected approximately 75 feet upstream of the confluence of the UT and
Stewarts Creek. All three contaminants were identified in source samples collected at the site.
However, no releases of these contaminants were identified in the surface water (CO-002-SW) and
sediment release samples (CO-002-SD) collected at the PPE below the storm sewer outfall in the UT,
or in the surface water (CO-0050SW) and sediment release samples (CO-005-SD) collected below
the confluence of the UT and Stewarts Creek. The source of these contaminants could not be
established from the analytical results. Nonetheless, assuming these contaminants could be attributed
to sources at the site, the overall impact to the nearby fishery is minimal since these contaminants
.exhibit a low bioaccumulation.
Based on the analytical results, a release via overland runoff from the site to surface water
impacting the nearest fishery could not be established. Therefore, the threat posed by the site to
surface water targets is considered minimal.
6.0 SOIL EXPOSURE AND AIR PATHWAYS
6.1 Physical Conditions
The facility property is surrounded by a chain link fenced topped with concertina wire (Photos
2, 3). The site slopes generally to the south and southeast (Fig. 1). There is an aluminum sided
warehouse near the center of the site. The western third of the site is covered by asphalt and concrete
in an open area between Berryhill Road and the warehouse. The remaining two-thirds of the site to
east and south of the warehouse are primarily bare soil (Fig. 2).
The soil type for the site is listed as Urban Land, which consists of areas where more than 85
% of the surface area is covered with asphalt, concrete, buildings or other impervious cover. Urban
Land soil has typically been cut, filled and graded, and the natural characteristics of the native soil
have been altered or destroyed (Ref. 33). The exposed soil at the site is a yellow-red to dark red,
sandy clay, intermixed with gravel. The soil has a low organic content and little vegetation was noted
at the source areas. The source areas do not have surface caps to prevent human contact with
contaminated soils (Refs. 5, 16).
6.2 Soil and Air Targets
There are currently no workers onsite (Ref. 16). Suburban Propane operates a maintenance
garage that employs several workers on it's property east of the site, within 200 feet of contaminated
soil along the overland drainage pathway (Ref. 5, 16; Fig. 3). No schools, daycare facilities or
residences are on and within 200 feet of established areas of soil contamination (Ref. 5). The site is
bordered by light industrial and business properties. The nearby population estimates are presented
below in Table 4 (Ref. 39). The closest residence is located approximately 0.1 mile northwest of the
site near the intersections of Thrift, Tuckaseegee and Berryhill Roads (Ref. 16; Fig. 1 ). The nearest
wetland is located 4.6 miles downstream of the site in Irwin Creek (Ref. 32). No other sensitive
environments, critical habitats, endangered or threatened species could be identified within a 4.0 mile
radius of the site (Ref. 36).
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Table 4.
Residential Population
0-0.25 mile 786
0.25 -0.50 mile 1,396
0.50 -1.0 mile 8,815
1.0 -2.0 miles 24,582
2.0 -3.0 miles 36,343
3.0 -4.0 miles 35,143
6.3 Soil Sample Locations
Since contaminated soil has been considered the source remaining at the site, soil sample
locations are the same as those identified in Section 3.1 of this report titled "Waste/Source -Sample
Locations".
6.4 Soil Analytical Results
Soil analytical results are the same as the analytical results presented in section 3 .2 of this
report titled "Waste/Source O Analytical Results" (Appendix A; Tables IA, IB, IC).
Benzo(a)anthracene, benzo(b)fluoranthene, · benzo(a)pyrene, indeno(l ,2,3-cd)pyrene,
dibenzo(a,h)anthracene, and bis(2-ethylhexyl)phthalate and PCB-1254 were detected within the top
two foot soil profile in excess of their respective August 1996 EPA human health-based soil screening
benchmarks.
6.5 Air Monitoring
Air monitoring was conducted during previous investigations by the USEPA and their
Technical Assistance Team (TAT) contractor. Air monitor results indicated elevated levels of volatile
compounds in drums within the warehouse and combustible gases within the above-ground and
underground storage tanks, prior to the removal. During the March 6, 1996 post-removal sampling
event, the NC Superfund Section monitored ambient air and boreholes with an HNu while collecting
subsurface soil samples. Several elevated readings above ambient background were detceted in the
sample boreholes during the sampling event. However, no elevated readings were detected in the
ambient air I foot above the sample boreholes (Ref. I 6).
6.6 Conclusions
The site is located in an industrialized and densely populated urban setting of northwest
Charlotte. The closest residences are located approximately 0.1 miles northwest of the site and
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107,065 people are estimated to live within a 4.0 mile radius of the site. Since the major sources of
potential air releases have been removed as of December 1995, the consequent threat posed by these
sources has also been removed. Residual levels of volatile organic compounds were detected in
onsite soil samples and in air monitoring of the sample boreholes. However, no elevated levels of
volatile compounds were found /n the ambient air I foot above the sample borehole.
Elevated levels of VOC's, SVOC's and metals were identified in onsite soils.
Benzo(b)fluoranthene, benzo(a)pyrene, indeno(l,2,3-cd)pyrene, dibenzo(a,h)anthracene and bis (2-
ethylhexyl) phthalate were identified in onsite soils at concentrations that exceed their respective EPA
human health-based soil screening benchmarks. The threat of exposure from these contaminants is
diminished since there are no workers on the site, there are no residents within 200 feet of the site
and the site is securely fenced and padlocked. Should the site conditions change in the future,
additional assessment may be required.
Additionally, elevated levels of numerous SVOC's and metals were identified in offsite soils
collected from two ditches that receive runoff from the Cherokee Oil site and direct it across the
Suburban Propane property to storm grates #2 and #3. Benzo(a) anthracene, benzo(b)fluoranthene,
benzo(a)pyrene, indeno(I,2,3-cd)pyrene and PCB-1254 were identified in these ditch samples at
concentrations that exceed their respective EPA human health-based soil screening benchmarks. At
the time of the investigation, there were several workers in the Suburban Propane garage within 200
feet of these contaminated soils. I-/'owever, the threat of exposure is diminished because the overland
drainage pathway is fenced and relatively inaccessible, no residents are located within 200 feet of the
contaminated soils, and the thick covering of vines and briers in the drainage ditches prevent workers
from contacting the contaminated soils. Should the site conditions change in the future, additional
assessment may be required.
7.0 SUMMARY AND CONCLUSIONS
The Cherokee Oil Company Integrated Preliminary Assessment/Site Inspection (Integrated
PA/SI) was conducted to gather data necessary to evaluate the need for further CERCLA remedial
action at this site. Soil, surface water and sediment samples were collected by EPA contractors OHM
Material Corporation and NC Superfund Section personnel and analysed for volatile organics, semi-
volatile organics including PCB's and pesticides, inorganics and TCLP-metals to characterize the
types of contaminants deposited at the site and their potential migration pathways. Additional
information was collected to confirm the target populations and environments potentially at risk from
the site.
A release to groundwater is suspected based upon past disposal practices, the contents and
conditions of the underground storage tanks, visible observation and analytical data indicating surface
and subsurface soil contamination at the site, the relatively shallow depth to groundwater, physical
characteristics of certain contaminants spilled at the site such as mobility and water solubility, and the
moderate conductivity of the regolith and saprolite. However, the threat posed to groundwater users
is minimal since no groundwater users were identified within I. 75 miles of the site during the
investigation.
No releases of any hazardous susbtances were_ found in the surface water sample collected
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from the unnamed tributary to Stewarts Creek, downstream of the storm sewer outfall that drains the
site. An elevated concentration of chromium was found in the sediment sample collected at a storm
sewer outfall where site runoff enters the unnamed tributary. However, chromium was not found at
elevated levels in on-site or overland runoff soil samples.
Elevated levels of PCB's and lead were identified in the control sample taken from a drainage
ditch approximately 75 feet south of the merge of Thrift and Freedom Roads. This drainage ditch
primarily receives runoff from businesses along Thrift Road (Fig. 4). Since the Cherokee Oil
Company site does not drain to Thrift Road, it is not considered to be the source for the contaminants
found in the control sample. No PCB's or lead were detected is surface water or sediment samples
collected downstream of the drainage ditch in Stewarts Creek.
Elevated levels of acetone, cis-1,2-dichloroethene and tetrachloroethene were identified in a
surface water sample collected 75 feet upstream of the confluence of the UT and Stewarts Creek.
All three contaminants were identified in source samples collected at the site. However, no releases
of these contaminants were identified in the surface water and sediment samples collected below the
storm sewer outfall in the UT, or in the surface water and sediment release samples collected below
the confluence of the UT and Stewarts Creek. In addition, these three compounds do not exhibit a
significant enough bioaccumulation to impact the nearby fishery.
Based on the analytical results, a release via overland runoff from the site to the nearest
fishery could not be established. Therefore, the threat posed by the site to surface water targets is
considered minimal.
Since the major sources of potential air releases were removed by EPA as of December I 995,
the consequent threat posed by these sources has also been removed. Residual levels of volatile
organic compounds were detected in onsite soil samples and in air monitoring of the sample
boreholes. However, no elevated levels of volatile compounds were found in the ambient air I foot
above the sample boreholes.
Elevated levels of VOC's, SVOC's and metals were identified in onsite soils.
Benzo(b)fluoranthene, benzo(a)pyrene, indeno(l ,2,3-cd)pyrene, dibenzo(a,h)anthracene and bis(2-
ethylhexyl)phthalate were identified in onsite soils at concentrations that exceed their respective EPA
human health-based soil screening benchmarks. The threat of exposure to these contaminants is
diminished since there are no workers on the site, and the site is securely fenced and padlocked.
Should the site conditions change in the future, additional assessment may be required.
Additionally, elevated levels of numerous SVOC's and metals were identified in offsite soils
collected from two ditches that receive runoff from the Cherokee Oil site and direct it across the
Suburban Propane property to storm grates #2 and #3. Benzo( a )anthracene, benzo(b )fluoranthene,
benzo(a)pyrene, indeno(l,2,3-cd)pyrene and PCB-1254 were identified in these ditch samples at
concentrations that exceed their respective EPA human health-based soil screening benchmarks. At
the time of the investigation, there were several workers in the Suburban Propane garage within 200
feet of these contaminated soils. However, the threat of exposure is diminished because the overland
drainage pathway is fenced, relatively inaccessible and the heavy vegetation in the drainage ditches
prevent workers from contacting the contaminated soils. Again, should the site conditions change
in the future, additional assessment may be required.
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Based upon the above assessment, the NC Superfund Section does not believe the site
warrants further CERCLA action at this time and recommends that a "No Further Remedial Action
Planned" status be assigned to the site.
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I.
2.
3.
4.
5.
6.
7.
8.
9.
Cherokee Oil Company Site
NCO 980 799 019
Photographs
Aerial photo showing the Cherokee Oil site. North Carolina Department of
Transportation. February 13, 1981.
Panoramic photograph of Cherokee Oil Company site from northwest entrance at
Berryhill Road, facing northeast to southeast. Photo taken during the August 9,
1995 NC Superfund Section Preliminary Assessment on-site reconnaissance.
Panoramic photograph of Cherokee Oil Company site from the southwest corner
at Berryhill Road, facing northeast to east. Two large concrete pyramid-type
structures at left center of photo mark the location of a former fuel station. Three
of six large above-ground storage tanks visible in center of photo. Photo taken
during the August 9, 1995 NC Superfund Section Preliminary Assessment on-site
reconmussance.
Two large steel vats at the loading dock. Photo taken during the August 9, 1995
NC Superfund Section PA on-site reconnaissance.
Stained asphalt indicates one of the overland runoff pathways from containment
area #3 across the Suburban Propane parking lot. Photo taken during the August
9, 1995 NC Superfund Section PA on-site reconnaissnace.
Stained soil at the southeast corner of the site indicates another overland runoff
pathway from containment area # I to the spur line drainage ditch. Photo taken
during the August 9, 1995 NC Superfund Section PA on-site reconnaissance.
A storm sewer outfall into the unnamed tributary of Stewarts Creek, located below
the E.F. Lombardi Company. This is the probable point of entry of site runoff to
surface water. NC Superfund Section personnel collected surface water and
sediment samples CO-002-SW/CO-002-SD at this point on March 6, 1996.
The EPA removal action in progress at the Miller property. Drums staged on the
Miller property were segregated based upon compatibility, securely fenced and
surrounded by a earthen containment wall. To the right, EPA contractors opened
the drums and bulked the contents inside the large white roll-off container prior to
off-site shipment. Photo taken during the August 9, 1995 NC Superfund Section
PA on-site reconnaissance.
The Miller property following the EPA removal action. Approximately 3-4
inches of topsoil was scraped and tested before being removed from this area.
EPA then shipped in and replaced the topsoil with clean fill and reseeded prior to
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10.
II.
12.
13.
. 14.
15.
16.
17.
18.
demobilizing from the site. Photo taken during the December 20, 1995 NC
Superfund Section on-site reconnaissance.
NC Superfund Section personnel collecting subsurface soil sample CO-002-SB
from former containment area #1. Soil was stained ash-gray to black. Photo
taken during the March 6, 1996 NC Superfund Section sampling trip.
Above-ground storage tanks and basin at containment area #2. Oil stains on the
walls and footings show the approximate level of free-standing oily water and
sludge removed from the basin by EPA. Photo taken during the August 6, 1995
NC Superfund Section on-site reconnaissance.
NC Superfund Section personnel collecting subsurface soil sample CO-003-SB
from former containment area #2. Soil was a dark red clay that exhibited an
iridescent sheen. Photo taken during the March 6, 1996 NC Superfund Section
sampling trip.
The conditions of former Containment Area #3. Oil stains on the concrete pilings
of the decking show the depth of free-standing oily water and sludge that was
removed from the basin by EPA. Photo taken during the December 20, 1995 NC
Superfund Section on-site reconnaissance.
NC Superfund Section personnel collecting surface soil sample CO-004-SL from
containment area #3. Surface soil contains a 2 inch surface layer of black-stained
organic material. Photo taken during the March 6, 1996 NC Superfund Section
sampling trip.
NC Superfund Section personnel collecting background surface soil sample CO-
001-SL from grass-covered residential lot behind Miller, Sherrill and Blake, CPA
offices on Tuckaseegee Road. Soil sample is a dark red clay. Photo taken during
the March 6, 1996 NC Superfund Section sampling trip.
NC Superfund Section personnel collecting surface soil sample CO-005-SL from
intermittent drainage ditch that connects the Cherokee Oil Company site to storm
grate #3. Photo taken during the March 6, 1996 NC Superfund Section sampling
trip.
Fishing line on the bank of Stewarts Creek at the confluence of the unnamed
tributary. Photo taken during the March I 3, I 996 NC Superfund Section follow-
up sampling trip.
NC Superfund Section personnel collecting upstream surface water/sediment
samples CO-00 I-SW /CO-00 I-SD on the unnamed tributary to Stewarts Creek.
Photo taken during the March 6, I 996 NC Superfund Section sampling trip.
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19.
20.
21.
22.
Storm water drainage ditch connecting Thrift Road and Freedom Drive to the
unnamed tributary to Stewarts Creek. Sediment sample CO-003-SD collected
from this ditch during the March 6, 1996 NC Superfund Section sampling trip.
Stewarts Creek on March 6, 1996. Due to the rain swollen conditions, surface
water and sediment samples from Stewarts Creek were postponed until March 13,
1996.
Stewarts Creeks on March 13, 1996. NC Superfund Section personnel collected
upstream surface water and sediment samples CO-004-SW /CO-004-SD at this
point. Photo taken during the March 13, I 996 NC Superfund Section follow-up
sampling trip.
NC Superfund Section personnel collecting surface water and sediment samples
CO-005-SW/CO-005-SD at the confluence of the unnamed tributary to Stewarts
Creek and Stewarts Creek. Photo taken during the March 13, 1996 NC Superfund
Section follow-up sampling trip.
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Photo I: Harry Zinn collecting subsurface soil sample
CO-002-SB from 2.5 -3.0 foot depth at former
containment area #J,. Soil was stained ash-gray to black.
Photo taken from south comer of Cherokee Oil Co. site
far.ino-nnr:th ?../6/QF,
t::"''. : ; . : ,, l -" '\ )L-\. ' D
Photo 6: A storm sewer outfall into the UT to Stewarts
Creek, located below the E.F. Lon1b~rdi Co~pany. This
.. marks the probable point of entry of runoff from the
Cherokee Oil Co. site to surface water. 3/6/96.
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Photo 7: Harry Zinn collecting
background

surface soil
sample CO-001-SL

from grass-cover
e
d

residential lot
behind Miller, Sherrill and Blake, CPA offices on
Tuckaseeg
e
e

Road. Soil sample is dark red clay.
'>,/f,/Q(..
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a ~
-:: J-~ -,;·-1 ! .. :-. :-r--.
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1+ ,-
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. ~-, __ _ ---. ~-·--
--
Photo 2: Harry Zinn collecting subsurface soil sample
CO-003-SB from 2.5-3.0 foot depth at former
containment area #2. Soil was dark red clay that
exhibited a iridescent sheen. Photo taken from south
Pnrl.nf rhP.mk'PP. n;1 rn ,ilP. farina nnrth 1/f./Q(i
Photo 6: Harry Zinn collecting surface soil sample C0-
,005:sc from intermittent drainage ditch that·connects
the Cherokee Oil Co. sote to the storm sewer. Photo
taken from abandoned railroad spur line behind
"nh11rh~n Pronrml"' far.1na northwP:.:.t 1/h/Qh
< ' "" . 14 •·_,_.•~~--.-= . 'h j · ..... 0 -i-~~~·-'~}~_ ;:. . ·y_:(' . ii, , "',
Photo 3: Harry Zinn collecting surficial soil sample CO-
004-SL from 0-6 inch profile at containment area#:&.
Surface soil is stained bl::tck and contains a 2 inch layer
of organic material. Photo taken from rear of Cherokee-.
Oil rn w~rPhnll~f>. far.lno north M::lrr.h h 1 QQh
~_.,.,,.,..,-..Jll!I!!.!:::,;·~ . ' . /
~
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Photo 5: Jeanette Stanley collecting the upstream
surface water sample CO-00 I-SW on the UT to Stewarts
Creek. Cherokee Oil Co. 3/6/96. . .
. , ,., ""''' ,,,.., .. •, , ' ,-.~
Photo I:
Storm Water drainage from Thrift Road and
Freedom Drive to the UT to Stewarts Creek.
Sediment sample CO-003-SD collected at this
lnratinn Msrr.h 6 I ()()1,
I ,,
' '
•·. '
Photo 7: Stewarts Creek from the Morehead Street
bridge facing north towards the Freedom Drive bridge ..
Due to the rain swollen conditions, surface
water/sediment samples from this area were postponed
'" 1/J 1/Qf;
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2.
3.
4.
5.
6.
7.
8.
9.
Cherokee Oil Company Site
NCD 980 799 019
Photographs
.i
Aerial photo showing the Cherokee Oil site. North Carolina Department; of
Transportation. February 13, 1981.
Panoramic photograph of Cherokee Oil Company site from northwest entrance at
Berryhill Road, facing northeast to southeast. Phot9 taken during the August 9,
1995 NC Superfund Section Preliminary Assessment on-site reconnaissance.
Panoramic photograph of Cherokee Oil Company site from the southwest corner
at Berryhill Road, facing northeast to east. Two large concrete pyramid-type
structures at left center of photo mark the location of a former fuel station. Three
of six large above-ground storage tanks visible in center of photo. Photo taken
during the August 9, 1995 NC Superfund Section Preliminary Assessment on-site
reconnatssance.
Two large steel vats at the loading dock. Photo taken during the August 9, I 995
NC Superfund Section PA on-site reconnaissance.
Stained asphalt indicates one of the overland runoff pathways from containment
area #3 across the Suburban Propane parking lot. Photo taken during the August
9, 1995 NC Superfund Section PA on-site reconnaissnace.
Stained soil at the southeast corner of the site indicates another overland runoff
pathway from containment area # I to the spur line drainage ditch. Photo taken
during the August 9, 1995 NC Superfund Section PA on-site reconnaissance.
A storm sewer outfall into the unnamed tributary of Stewarts Creek, located below
the E.F. Lombardi Company. This is the probable point of entry of site runoff to
surface water. NC Superfund Section personnel collected surface water and
sediment samples CO-002-SW/CO-002-SD at this point on March 6, 1996.
The EPA removal action in progress at the Miller property. Drums staged on the
Miller property were segregated based upon compatibility, securely fenced and
surrounded by a earthen containment wall. To the right, EPA contractors opened
the drums and bulked the contents inside the large white roll-off container prior to
off-site shipment. Photo taken during the August 9, 1995 NC Superfund Section
PA on-site reconnaissance. '-
The Miller property following the EPA removal action. Approximately 3-4
inches of topsoil was scraped and tested before being removed from this area.
EPA then shipped in and replaced the topsoil with clean fill and reseeded prior to
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demobilizing from the site. Photo taken during the December 20, 1995 NC
Superfund Section on-site reconnaissance.
NC Superfund Section personnel collecting subsurface soil sample CO-002-SB
from former containment area # I. Soil was stained ash-gray to black. Photo
taken during the March 6, 1996 NC Superfund Section sampling trip.
Above-ground storage tanks and basin at containment area #2. Oil stains on the
walls and footings show the approximate level of free-standing oily water and
sludge removed from the basin by EPA. Photo taken during the August 6, 1995
NC Superfund Section on-site reconnaissance.
NC Superfund Section personnel collecting subsurface soil sample CO-003-SB
from former containment area #2. Soil was a dark red clay that exhibited an
iridescent sheen. Photo taken during the March 6, 1996 NC Superfund Section
sampling trip.
The conditions of former Containment Area #3. Oil stains on the concrete pilings
of the decking show the depth of free-standing oily water and sludge that was
removed from the basin by EPA. Photo taken during the December 20, 1995 NC
Superfund Section on-site reconnaissance.
NC Superfund Section personnel collecting surface soil sample CO-004-SL from
containment area #3. Surface soil contains a 2 inch surface layer of black-stained
organic material. Photo taken during the March 6, 1996 NC Superfund Section
sampling trip.
NC Superfund Section personnel collecting background surface soil sample CO-
00 !-SL from grass-covered residential lot behind Miller, Sherrill and Blake, CPA
offices on Tuckaseegee Road. Soil sample is a dark red clay. Photo taken during
the March 6, I 996 NC Superfund Section sampling trip.
NC Superfund Section personnel collecting surface soil sample CO-005-SL from
intermittent drainage ditch that connects the Cherokee Oil Company site to storm
grate #3. Photo taken during the March 6, 1996 NC Superfund Section sampling
trip.
Fishing line on the bank of Stewarts Creek at the confluence of the unnamed
tributary. Photo taken during the March 13, 1996 NC Superfund Section follow-
up sampling trip.
NC Superfund Section personnel collecting upstream surface water/sediment
samples CO-001-SW/CO-001-SD on the unnamed tributary to Stewarts Creek.
Photo taken during the March 6, 1996 NC Superfund Section sampling trip.
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Stonn water drainage ditch connecting Thrift Road and Freedom Drive to the
unnamed tributary to Stewarts Creek. Sediment sample CO-003-SD collected
from this ditch during the March 6, 1996 NC Superfund Section sampling trip.
Stewarts Creek on March 6, 1996. Due to the rain swollen conditions, surface
water and sediment samples from Stewarts Creek were postponed until March I 3,
1996.
Stewarts Creeks on March 13, 1996. NC Superfund ~ection personnel collected
upstream surface water and sediment samples CO-004-SW /CO-004-SD at this
point. Photo taken during the March 13, 1996 NC Superfund Section follow-up
sampling trip.
NC Superfund Section personnel collecting surface water and sediment samples
CO-005-SW /CO-005-SD at the confluence of the unnamed tributary to Stewarts
Creek and Stewarts Creek. Photo taken during the March 13, I 996 NC Superfund
Section follow-up sampling trip.
--I
.. ~----1!1!!!!11 --a 11!!1!1!!!1 11!!!11 -. ---
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N.f..:. Dcp<:rtmcni oi Environment,
i ii:.-..lth, i: i✓at<Jr:il Resources
Solid Waslc Man::igc.n;icnt Division
SAlv!PLE ANALY:,IS REQlJEST 51:dc ;_~1b0r.tto1y o( Pubiic !lc::dth
P.O. nm 2&).rJ, 3()6 N. \Viln1in1;ton _Slrc.:l
R.alcibh, N01th Camlinn 2,7611
Site Number CO·OO!·SL 03/06/% 1501 GRAB
Cheiokee Oil Company, NC DOUG HOORE • · f Number _______ ~----------
Name of Site BACKGROUND SURFACE SOIL
-ESD LAB EXT /PEST Soil
2 Collected By _________ _
Agency: Hazardous Waste Solid Waste .Lsuperfund
Sample Type
Environmental Concentrate Comments
_Solid (5) __ Ground water (1)
__ Surface water (2)
✓soil (3)
__ Liquid (6) ___________ _
_ Sludge (7) ___________ _
.
Other (4) Other (8)
Organic Chemistry
Parameter
P&T:GC/MS
V Acid:B/N Ext.
MTBE
Results(mg/1)
✓ fcP.,'• /ro;nt:-11Jff'---. ___ _
Inorganic Chemistry
Parameter
Arsenic
Rcsulls(mg/1) (mg/kg)
--Barium
Cadmium --Chloride
Chromium = ENCfl:?./tl <::.o,/~ -Copper 'Pe£Jj_ < o.f o~;
_ /-iAldA//c -<:4,~ _ Fluoride
~d... -<: I -t:,·_:... • Iron
~ -''&11€ < ~ ,.. _T -Lead
(½/Jr,:,t:/AN't: -<O, Manganese
-:t·1•~-·-~-'r;;'Aij. 'J'/:,~'A'lf,/4tJ.f!J'"~~S:0>!2,-;1~·'.JaOLl1I __ lvlcrcury
7i.¥"Al'A/,,e&;x7>(/Ac<o, · u __ Nitrate ~ Selenium
Radiochemistry
l1;irn111etcr
__ Gross Alpha
Gross Beta
Results (PCi/1)
!vlicrobiology
Results (Col/lOOml)
-------
--Silver
Sulfates
Zinc --__ pH
__ Conductivity
TDS --
TOC
--·----
TCLP Compounds
I11organic Compounds
Arsi..:nic --n,uium
Cadmium --Chromium --Lead --
--Mercury
Scknium --Silver
Rcsults(mg/1)
-----------------
·------------------
Organic Cnmpounds
bcn7.cnc, --carbon tctr::ichloride
Results(mg/1)
---------chlordane
ch\orobcnzcnc --
chloroform
o-crcsol --m-crcsol --
--p·crcsol
cresol
__ 1,4-dichlorobcn:;.cnc ______ _
__ 112-dichlorocthanc
__ 1,1-dichloroethylcne ______ _
__ 214-dinitrotolucnc.
__ hcptachlor
hcxJchlorobcnzcnc
hc.xach l orobut ad icnc ---------hcx.'.lch!orocl hanc ----methyl ethyl ketone
nitrobcnzenc --
--pcntachlorophenol
__ pyridine
__ tclrachlorocthylcne
__ trichlorocthylcnc
__ 2,,1,S-tricl1lorophcnol
2, 4 ,6-trich lorophenol
__ vinyl chloride
cndrin
lindanc ----1"i',cthm,)1Ch!or
__ tox::iphcnc
2<!-1)
7: '-Tl' (S" ' __ .. , ,,.J • ,. :ex;
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,. :-..:.,c. l>.:p:..:1-,;ncnt of Environment, SAMPLE Ai',ALYSIS HEQUES~ECEIVED Sw" l,ib<>~"iffilif. ·
. ' i i.;::lth, & Na(ur;il Resources:
S·::lid Wa:-tc Man.11:cn)Cnl Division
]',(1. !lox 28(}-;'7, 30'.) i<. \Vilmir.gton Stn:ct
APR O 8 1996 11..,ki.h,' NO<ih C,n,li,rn 27611
Site Number ~-
Name of Site
C0-001-SL 03/06/96 1501 GRAB
Cherokee Oil Company, NC
BACKGROUND SURFACE SOIL
ESD LAB VOA Soil
1
.. DOUG MOORE
1u-1t ualc Loi1cctcd Time Collected By _________ _ ---------------------
Agency: Hazardous Waste Solid Waste /supcrfm1d TCLP Compounds -·7
------
Sample Type liiorg:rnic Compo:rncl.s Rcsults(mg/1)
_Environmcnt::il Concentrate Comm~nts Arsenic --Barium ----
Ground \Valer (1) _ Solid (5) Cadmium ----Chromium --. __ Surface waler (2) __ Liquid (6) Lead --
/ Soil (3)
--Mercury
Sludge (7) Sc.kniurn --Silver --Other (4) Other (8) --· --
--
--Organic Chemistry Inorganic Chemistry ---·
P,1rarnefer Rcsults(mg/1) Parameter Rcsults(mg/1) (mg/kg) Organic Co:i1p0:1nc!s Rcsulis(mg/li
_':'.'.::'i'&T:GC/MS Arsenic benzene ----Acid:R/N Ext. Barium carbon tL:tr:J.ch!o:-idc -----·-
MTJ3E Cadmium chlordane ------
Chloride chiorobenzcnc ------
Chromium chloroform --------
--__ Copper o-crcso! --Fluoride m-crcscl ------
·--Iron p-crcsol ----Lead ere.so! ·-----
----?\1 angancsc 1,4-dichlorobcnzcnc --
--__ i\1crcury --1,2-dich!oroct hanc
Nitrate 1, 1-dieh loroet hylcn c ··-----Selenium 2,4-dinitroto!ucnc. ----Silver hcptachlor ----
Radiochemistry Sulfates hcxach lo robcn?.1.:,nc ----Zinc h c.x:lch lorobu l ;i cl ic n c ----
P;irnmetcr Results (PCi/1) --pH --hcx:1chloroc th a nc
____ Cross Alpha Conductivity methyl ethyl ketone ----Clross Bclc\ TDS nitrobcnzcnc --·· ----
TOC pentachlorophcnol : ;
-------pyridiHc -----
l\'licrobiology ----let rach loroct hylc.m.:
trichlor octh ylc 11c --Pararnctcr He.suH.s (Col/ I 00ml) 2, 4,5-trich lorophcn o l ----
-----2, 4,6-t richlorophcnol --
-------vinyl chloride
cndrin --
q'(, /~'#cport,(,)' ) 3~ 7 ,,/ .,r-/U&L.('. 7 ___ lindane
D:\tc. Rccci\·cd mc.tl1oxycl1lor
Date RcUeu_ff!p//?' b
-1ox:1plicnc:
Dal,:: E.xtr~ictc.:d --2,t.-D .. 7'5TP(S'1 '
3-1 J -q(Q 71,(,.1,r' 961144 •·,'', -, l.".'l'.X)
f);ilc ;-\ n:i!y;,cd L:ih Number y~_// ~ 0--o/'~_f__L~_i._--
'·, I ',; ":.:')I (I.',.,,;.,.,! 1 /':: ', .. ~---
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;--..'.(.:. Department of Environment,
! lcalth, J.: Natural Rcsour-:cs
So!id Waste :,.~aP.abC!l)Cnt Divi.~ion
SAMPLE ANALYSIS REQUE~;T State Labor.itoc)' o( l'•Jbli,: l lc:i.lt!1
!'.0. Box 280-17, 30<) N. Wi1rninr,to:\ _Slrcct
H.a!r.ii;h, t':orth Cnrclinii 2_761 l
Sile Number C0-002-SB 03/06/96 1150 GRAB
Cherok·ee. Oil Company' HC· DOUG ·"OORE
: Number ------------------
Name of Site SUBSURFACE SOIL AREA II . -ESD lAB VOA Subsurface Soil Hl-----------------~---
Collected By_ co-4 ____ ....,, ... , ..... ....'.,i .. 0dcd ___________ Time ______ _
Agency: Hazardous Waste Solid Waste V Superfund TCLP Compounds ·------··--
Sample Type Inorganic Compounds l<csults(mg/1)
Environ men ta I Concentrate Comments Arsenic --Barium --Ground \Valer (1) ___ Solid (5) Cadmium -----Chromium , --
. __ Surface water (2) _ Liquid (6) Lead --
✓soil (3)
--Mercury
_ Sludge (7) Selenium ---··· Silver --_ Other (4) _ Other (8) --
--
--
Organic Chemistry Inorganic Chemistry --
Parameter Rcsults(mg/1) Parameter Rcsulls(mg/1) (mg/kg) Organic Compounds Results (rng/1)
✓r&T:GC/MS Arsenic benzene ----
--Acid:B/N Ext. Barium carbon tetrJch\oridc ----MTBE Cadmium chlordane ------Chloride ch!orobcnzcnc ------Chromium chloroform ------
--Copper o-crcsol ----Fluoride m-crcsol ------Iron p-crcsol ----' Lead crcsol ------
----lvfangancsc --1,4-dichlorobcnzcnc
--__ lvfcreury 1,2-dichloroct h ane --
--Nitrate __ 1,1-dichloroethylcnc --Selenium 2,4-dinitrotolucnc. ----Silver hcptachlor ----
Radiochemistry Sulfates hcx.:ichlorobcnzcnc ----Zinc hexach !orobut ad icne ----l);iraml'.tt;r Results (l'Ci/1) --pl-! hcxachlorocthanc --__ Gross Alpha --Conductivity methyl ethyl ketone --Gross Beta TDS ni(robenzcnc ------TOC __ pentachlorophcnol . , --pyridine ----
ivlicrobiology ----tel rach loroct hylene
--__ trichlorocthylcnc
Parameter Results (Col/lOOrnl) 2,•i,5-trich lorophcnol ----2, 4,G-t richlorophc,,ol ------
----vinyl chloride --cndrin --
Date Received 3~1:: qC:, '¼//tk Reported by
lindanc. --
--mcthoxychior
tc1xc1pbcnc --Dale Exti":ictcd Date Reported 2,,:-D --
3-iJ.-9& 77.w~ 961146 2-'1,5-TP (Si!·:cx)
D,1tc A n:i!;(1.cd Lah Numbc.r --!lil'\-,\'Jl (){c.-.·:c•·,: 'J/'·/\·1
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i',.'.(. !).cpnrtmcnt of En1,ironmcnt,
i kill th, & N2tur.1l Resources
Solid Waslr. Mt1nagcn)cnt Division
SAMPLE ANALYSIS REQUEST
Site Number C0-002-SB 03/06/96 ll50 GRAB
Cherokee Oil Company, HC DOUG MOORE°
•1 Number
Stale L.-1bor.ito1y o( Public I lcai:h
P.O. Box 280-17, 306 N. Wilmingtor. Street
Raleigh, North Carolirrn '2761 l
------------------
Name of Site SUBSURFACE SOIL AREA II
-ESD LAB EXT/PEST Subsurface-Soil ·'·-----------------~---
Collected By_ co-5 ; _____ ,cd ___________ Timc ______ _
Agency: Hazardous Waste Solid Waste ✓ Superfund
Sample Type
Environmental Concentrate Comments
~-Ground water (1) __ Soli<l (5)
. __ Surface water (2)
V Soil (3)
_ Liquid (6) ___________ _
_ Sludge (7) ___________ _
_ Other (4) _ Other (8)
Organic Chemistry
Results(rng/1)
Radiochemistry
P.irameter Results (PCi/1)
__ Gross Alpha ______ _
Gross Beta
!I'! icro biology
Results (Col/100ml)
Inorganic Chemistry
Parameter
Arsenic
Rcsults(mg/1) (mg/kg)
--
--Baril!m
Cadmicr.1 --Chloride
Chromium ----Copper
--
Fluoride
Iron
Lead
__ Manganese
__ Mercury
Nitrate
Selenium --Silver --Sulfates
Zinc --__ pH
__ Conductivity
TDS --
TOC
TCLP Compounds
Inorganic Compounds
Arsenic
--Barium
Cadmium·
Chromi.um
Lead
__ Mercury
Selenium --
Silver
Organic Compounds
benzene --carbon tetrachloride
Results(mg/1)
Results(mg/1)
---------chlordane --chlorobenzenc, --chloroform --o-crcsol --m-crcsol --
--p-cresol
crcsol --__ 1,4-dichlorobcnzcnc
__ 1,2-dichlorocthane
__ 1,1-dichloroethylcnc ______ _
__ 2,4-dinitrotoluene.
__ heptachlor
hcx.1chlorobcnzcnc
hcxachlorobut ad icnc -------~-l1cxacl1loroclha,1c ----methyl ethyl ketone
nitrobcnzcnc ----pentachlorophcnol
__ pyridine
__ tctracl,lorocthylcnc
__ trichlorocthylcnc
2, 4,5-trichlorophrno 1
2, 4 ,6-trichl orophcnol
__ ,1nyl chloride
cndrin
lind::nc
__ rncthoxych!or
__ toxaphcni..:
'211t-D
__ 2,.,,5-TP (Si! ,n)
---------
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t'--'.C. Department of En·.rironmcnt,
\ lcnlth, & Natural Resources
Solid Waste Managcn1cnt Division
SAMPLE ANALYSIS REQUEST
Site Number
Name of Site
C0-001-SB 03/06/96 1515 GRAB
Cherokee Oil Company, NC· DOUG HOORE
BACKGROUND SUBSURFACE SOIL .,II : ,_;1· ESD· LAB VOA Subsurface Soil
-,1 , ~umber
' '
.'· .;1tc L.aborJ\01)' of l'ublic HcJlth
r.O. !';ox 2W.17, 30S N. v..:i!mington _Street
R,1!cigh, North CarollnR .2.7611
------------------
co-7 Collected By __________ _ ~ ,d Time ------------------
Agency: Hazardous Waste Solid Waste V Superfund TCLP Compounds ------
Sample Type Inorganic Compounds Rcsults(mg/1)
Environmental Concentrate Comments Arsenic --Barium --
Ground water (1) _Solid (5) Cadmium ----Chromium --. __ Surface water (2) _Liquid (6) Lead --Mercury --✓soil (3) _ Sludge (7) Selenium --Silver --
_ Other (4) _ Other (8) --
--
--
Organic Chemistry Inorganic Chemistry --
Pam meter Results(mg/1) Paramet~r Results(mg/1) (mg/kg) Organic Compounds Results(mg/1)
V:.P&T:GC/MS Arsenic benzene ----
__ Acid:B/N Ext. Barium carbon tetrachloride ----MTBE Cadmium chlordane --· ----Chloride chlorobcnzenc ------
Chromium chloroform ·------. Copper o-crcsol ------fluoride m-crcsol ------
--Iron p-crcsol ----Lead crcsol ------
----J\1angancsc --1, 4-<lich!orobcnzcnc
--__ Mercury --1 ,2-dichlorocthanc
Nitrate 1, 1-d ichloroet hylcne ------Selenium 2,4-dinitrotolucnc _ ----Silver heptachlor ----Radiochemistry Sulfates hcx:1chlorobcnzcnc ----.... Zinc hcxach lorobutad icne ----Para1nekr Results (PCi/1) pH hcx.:.tchloroc l ha 11c ----__ Gross Alpha __ Conductivity --methyl ethyl ketone
c; ross Beta TDS nitrobcnzcnc ------
TOC pcntachlorophcnol . , ------
----pyridine
l'vl i cro biology ----tel ra chloroeth ylcne
-· __ trichlorocthylcnc --Parameter Results (Col/100111I) 2, 11,5-lricl1 lorophc110i ----2,4,6-tr i chlorophcnol ------,inyl chloride ------cndrin --
3-7-?f> U/t;[;f!;Rcportcd by
lindanc
D:llc Rtccivcd
--
--rncthoxych!or
tox,1phcnc --Date Exlr:icu.:d Dale Reported 2,,!.j) --
Dale ;\ n~ilyzcJ .3 -I 8-9 IR. 7J I,()-L:ih Number 961148 2,i,5-TP (Si!·:cx)
--!"II 1<.: 1.1')1 (:/, .. _·ic,-,1 ·JiiJ;\
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i',,',C. Dcp::i_rtmcnt of Environment,
l lc::ilth, & Natur::i.\ Resources
Solid Waste Man:lbcn~cnt Division
SAMPLE ANALYSIS REQUEST
Site Number
Name of Site
C0-001-SB 03/06/96 1515 GRAB
Cherokee Oil Company, NC DOUG MOORE
BACKGROUND SUBSURFACE SOIL
ESD LAB -EXT/PEST Subsurface Soil
· Ntimbcr
Stat<: l.ab0rat-:ry uf l'iib;i:; lk:.lth
f.(1. Box 2SQ.17, 3C<; N. Wilmington _Street
Ralciih, North Cn1o!ina 276li
------------------
co-8 Collected By __________ _ uiHc 1.....u11e.cted Time -----------------------
Agency: Hazardous Waste Solid Waste V Superfund
Sample Type
Environmental Concentrate Comments
_ Solid (5) __ Ground water (1)
__ Surface water (2) _ Liquid (6) ___________ _
✓soil (3)
_ Other (4)
_ Sludge (7) ___________ _
_ Other (8)
Organic Chemistry
Parameter Results(mg/1)
Radiochemistry
1\irameler
__ Gross Alpha
Gross Beta
Results (PCi/1)
!Vl icrobiology
Parameter Results (Col/100111!)
Inorganic Chemistry
Parameter Results(mg/1) (mg/kg)
Arsenic
Barium --Cadmium --Chloride
Zinc
__ pH
__ Conductivity
TDS --TOC
TCLP Compounds
Inorganic Compounds
Arsenic
--Barium
Cadmium
Chromium
Lead
__ Mercury
Selenium --Silver
Organic Compounds
benzene
carbon tctr;:ichloridc
Results(mg/1)
Rcsults(rng/1)
----------chlordane
chlorobcnzcnc --chloroform
o-crcsol
m-crcsol --
--p-crcsol
crcsol --l, 4-d i chlorobcnzcnc --1,2-dichloroct hanc --1, 1-dichlorocthylcnc --2/1-dinitrotolucnc. --
--heptachlor
hcx3chlorobcnzcnc --hcxachlorobu tad icn c --hcxJchlorocthanc ----methyl ethyl ketone
nitrobcnzcnc ----pcntachlorophcnol
__ pyridin~ ·
__ tctrachloroclhylenc
trichlorocth ylc nc = 2,,t,5-trichlorophcnol
__ 2,4,6-trichlorophcnol
__ ,inyl chloride
endrin --lincbnc
__ rncthoxyChlor
__ tox.::phcnc
2,·1-D
2,4,5-TI' (Si!·.,cx)
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N.C. J),:p~,1.mcnt o[ Envi1onmcnL
i ic;1l:h, ,~ \-.ialural Resources
Solid Waste Managc!l)cnt Division
SAMPLE ANALYSIS REQUEST Stale L.aborJ!Dr)' o(Public !lcal1h
r.o. Box 280-17, 306 N. Wilrnington /;ll'Ci'.;
R,1\ci~;h, North Carolina 2_7(, t I
Sile Number C0-003-SB 03/06/96 1240 GRAB
Cherokee Oil-Company, NC· DOUG MOORE
SUBSURFACE SOIL AREA 12
· Number _______________ _
Name of Sile ESD LAB VOA Subsurface Soil
co-10 Collected By ___________ _
Agency: Hazardous Waste Solid Waste v"' Supcrfun<l TCL!' Cori1pounds -----
Sample Type Inorganic Compounds Rcsulls(rng/1)
Environ rn en ta I Concentrate Comments Arsenic --Barium --
__ Ground waler (l) _ Solid (5) Cadmium --Chromium --
. __ Surface waler (2) _ Liquid (6) Lead --
/ Soil (3)
--Mercury
Sludge (7) Selenium --Silver --_ Other (4) Other (8) --
--
·--
Organic Chemistry Inorganic Chemistry --
Pam meter Rcsults(rng/1) Parameter Rcsults(mg/1) (mg/kg) Organic Compounds Rcsults(mg/1)
V-:-r&TGC/MS Arsenic benzene ----
--Acid:B/N Ext. Barium carbon lctrJchloridc ----MTJ3E Cadmium chlordane ------Chloride chlorobcnzcnc ------Chromium chloroform ------
--__ Copper o-crcsol --Fluoride m-crcsol ------
--Iron p-crcsol ----Lead crcsol ------
--__ Manganese 1 ,4-dichlorobcnzcnc --
--__ Mercury 1)-dicblorocthanc --Nitrate 1, 1-dichloroethylcne ------Selenium 2,4-dinilrotoluene. ----Silver hcptachlor ----
Radiochemistry Sulfates hcxachlorobcnzcnc ----Zinc hex:i.chlorobut adicnc ----
Paramett:r l(csulls (PCi/1) pH hcx::i.chlorocthanc ----
__ Gross Alpha --Conductivity methyl ethyl ketone --Cross Bela TDS nitrobcnzcnc ------TOC ___ pcntachlorophcnol . , --
--. --pyridine
fVl i c rob i o Io gy ----tctrach lorocl h ylcnc
trichloroct h y!cnc --P.ir:1r11ckr Results (Col/lO0ml) __ 2,4,5-trichlorophcnol --70 4,6-l richlorophcnol -------,onyl chloride ------cndrin --
Date Rcccivcd __ ~ 1--f,6 /uf:rtt.rcpurtcd by
lindanc --mclhoxyC:hior ---
loxctphcnc --Dale E.xtr:ictcd D;1lc RcportcU 2,ri-D --
3-t8-9w nw-961150 __ 2,1,5-TP (Si! .-ex)
Dale ,t-\n~i!rLcd Lab Number ----ill'<-: l\<JO /11,.,_.;,,.,: ')/'/;\,
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N.C. 1'lcpartr<1cr1: of En,..ironmcnt,
i lc:ilth, l.:. Natural Resources
Solid Waste Mc1n:igcn:_cnt Division
SluvTPLE ANALYSIS REQUEST S!alr, l,.nbor.itocy nl" l'ublic Health
P.O. D'.Jx 28.!}17, 306 N. Wilmington _Street
R.alcit:h, North Caro!in11 2,7611
Site Number C0-003-SB 03/06/96 1240 GRAB . '.,
-Cherokee Oil Company, NC • DOUG MOORE .
.. , , . Number _________________ _
SUBSURFACE SOIL AREA 12
Na 111 e of Site_ ESD LAB -EXT/PEST Subsurface Soil. . 1 ' '•, "-----------------~~--
co-11 Collected By __________ _ ____ ~:::.,~ ....,..; .. ..:.. ... lcd ___________ Timc ______ _
Agency: Hazardous Waste Solid Waste V Superfund TCLP Compounds ------
Sample Type Inorganic Compo11nd.s Rcsults(111g/l)
Environmental Concentrate Comments Arsenic --Barium. --
__ Groundwater (1) Solid (5) Cadmium --Chromium --
. __ Surface water (2) Liquid (6) Lead --Mercury
v'Soil (3)
--
_ Sludge (7) Selenium --Silver --
_ Other (4) Other (8) --
--
--
Organic Chemistry Inorganic Chemistry --
Parameter Results(mg/1) Parameter Rcsulls(mg/1) (mg/kg) Organic Compounds Rcsults(mg/1)
P&T:GC/MS Arsenic benzene ----
VAcid:B/N Ext. Barium carbon lctrachloridc ----MTJ3E Cadmium chlordane ----✓ r'c.13'</l'emC-f1Jc5 Chloride chlorobenzcnc ----_ -Z,C8s -< 0,/ orpt'\ Chromium chloroform ----= -~010' __ Copper o-crcsol --== ~= ~ ~o'..:z-f.t'J! Fluoride m-crcsol ----~f=;,.JJ -",...o</,/'I_,'...:....... lron p-crcsol 7~:::~~------~-· Lead crcsol ----·--· __ Manganese 1, 4-dichlorobcnzene --__ · 7i_€r-,,.r?. -~ ✓ · --<.::::,, ~ A . --,--Mercury --112-dichloroet hanc
Ve; ,,_ ~ /p-.,pjiPxti/E<J//p_--Nitrate 1, 1-dich lorocth ylcnc
I 17 ' --Selenium 214-<linitrotolucnc. ----Silver heptachlor ----
Racliochcmistry Sulfates hcxachlorol1cnzc11c ----.... Zinc l1cx;1chlorobl1tadic11c ----1\iraml'.tt.:r Results (l'Ci/1) pH hcxach!orocthanc ----__ Gross Alpha __ Concluctivity methyl ethyl ketone --
Gross Beta TDS nitrobcnzcnc ------TOC pcn!achlorophcnol ' ----
--__ pyridine
l'vlicrobiology ----tel rachloroethylenc
trich lorocthylenc ----
Parameter Results (Col/1001111) 2, ,f ,5-trich lorophcnol ----2, 4 ,6-t richloro phenol ----
--vinv! chloride ----, cndrin --
Date Received 3-7---£(,, W~Reportcd by
lincbnc ---m:.:thoxychior --Pte/t.'ut 3-1;,-1<,, ,iJJ --· toxnphcm:.
Dale Extracicd,J.;Jl-91~~)atc Reported 2;:-D
__ 2,,t5-TP (Si!·;cx)
;~
1
':'.,\~:1;:r:~,~!i~ 3-.2/-9~#ah Number 961151 ---
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N.C. D.cpartrncnt of Environmcrit,
i'Ic.il:h, l._ Natur:il Resources
Soiid Waste Man.1gcn_1cnt Division
SAMPLE ANALYSIS REQUEST
Site Number C0-004-SL 03/06/96 1205 GRAB
Cherokee Oil Company; NC -DOUG HOORE
Name of Site . STAINEO SURFACE SOIL AREA 13
-ESD-LAB VOA· Soil
Number
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State. L.nhorJtOr)' of l'ublic i lc:ilth
P.O. :3ox 28(}l?, 306 N. Wilmington _Street
Raleigh, North Carol,in11 2,7611
------------------
co-13_ Collected By_· _________ _ Cd Time . ------------------
Agency: Hazardous Waste Solid Waste v Supcrfund TCLP Coh1pounds
---------
Sample Type Inorganic Componnds · Rcsults(mg/1)
Environmental Concentrate Comments Arsenic --Barium --Ground water --(1) ___ Solid (S) Cadmium --Chromium --
. __ Surface water (2) Liquid (6) Lead --
VSoil (3)
--Mercury
Sludge (7) Selenium --Silver --
_ Other (4) _ Other (8) --
--
--Organic Chemistry Inorganic Chemistry --
Parameter Rcsults(mg/1) Parameter Results (mg/1) (mg/kg) Organic Compounds Results(mg/1)
.. VP&T:GC/MS Arsenic bcn7.cnc ----
__ Acid:B/N Ext. Barium carbon ll:trachloridc ----MTI3E Cadmium chlordane ------Chloride chlorobcnzcne ------Chromium chloroform ------
--Copper o-crcsol ----Fluoride m-crcsol ------Iron p-cresol ------Lead crcsol ------
----Manganese --1 ,4-dichlorobcnzcnc
----Mercury --1,2-dichlorocthane
Nitrate I, 1-Jichloroethylcne ------Selenium 214-dinitrotolucnc _ ----Silver hcptachlor ----Rad iochemistr)' Sulfates hcx.1chlorobcnzcnc ----
Zinc hcxachlorobutadic nc ----
Parameter l(esults (!'Ci/I) pH hcx..1chloroct h anc ----__ Gross Alpha --Conductivity --methyl ethyl ketone
Gross Beta TDS nitrobcnzcnc ------TOC pcnlachlorophenol .. . , ----pyridine ----!vlicrobiology ----tel racl, lorocth ylcne
trichlorocthylcnc ----Puran1dcr Results (Col/100111I) 2, 4)5-tricl1lorophcno I ----2, 4 ,6-t rich!oropl1c11rJI ------vinyl chloride ------endrin --
3~7-11{, ~Reported by
lindanc
D:1tc 'Received --mcthoxychlor --tox;1pbcnc --
Date L:.xtr:1clcd Dair: Reported 2,t..l) --
96115_2
__ 2,•l,5-TP (Si! ;ex)
Dale: A11:i!y1.cd 3-/6-C/ U -,1 /,IJL:,l, Number -~------!'ii"~ 110) I / 1/, ... ;._.,.,i 'J /!!1 \
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N.·C. Department of Environmc,i:,
i lcalth, & Natural Resources
Solid Waste Managcn;cnt Division
0AMPLE ANALYSIS REQUEST
Site Number
Name of Site
C0-004-SL 03/06/96 1205 GRAB
-· Cherokee Oil Company, NC
STAINEO SURFACE SOIL AREA 13
ESD LAB EXT/PEST·· Soil·
DOUG. HOORE
State Lnbor.:ilory or Public H.:::llth
l'.O. 11ox 28{}l7, 306 N. Wilmington .. Strcct
Raleigh, North Caroline. 2_7611
co-14 Collected By _________ _ :d ___________ Timc ______ _
Agency: Hazardous Waste Solid Waste ._,..,.. Superfund TCLP Compounds ------
Sample Type Inorganic Compounds Rcsults(mg/1)
Environmental Concentrate Comments Arsenic --Bariun1 --__ Ground water (1) _Solid (5) Cadmium --Chromium --. __ Surface water (2) _ Liquid (6) Lead --Mercury --
V Soil (3) _ Sludge (7) Selenium ---Silver --
_ Other (4) _ Other (8) --
--
--
Organic Chemistry Inorganic Cheinistry --
Parameter Results(mg/1) Parameter Rcsults(mg/1) (mg/kg) Organic Compounds Rcsults(mg/1)
_P&T:GC/MS Arsenic benzene -----
,/' Acid:B/N Ext. Barium carbon tetrachloride ----·M~i"BE Cadmium chlordane
7 .IJ;ef&/p~c,~ ----Chloride chlorobenzcnc ----_ PCBi < o, to 4>--· Chromium chloroform --
GM'&tK ·<o* __ Copper o-cresol --
Fluoride m-crcsol = Lh.;d,1(£ <o,~ ----_1!!.efA.,xycA/4e <: /, 0 ~ Iron p-crc.sol ----
_,ii'1fA/l!l0./E -<:,2,0/'fU" . Lead crcsol ----~ ~a.,;zoffni __ Manganese l ,4-dichlorobcnzcnc --;]f;o-&,Ml,ne <0, IP~ __ Mercury 1,2-dichloroethanc
12ftU/4A!.,fo-ox. ·J-.,_-; n. -Nitrate __ l,l-dicl1loroethylcne ,, Selenium 2,4-dinitrotolucnc. ----Silver --__ heptachlor
Racliochemislt)' Sulfates hcxJchlorobcnzcnc ----
Zinc he.xii ch lorobu tad icnc ----
P,1rnmekr Results (l'Ci/1) pH hcxachlorocthane ----__ Gross Alpha --Conductivity --methyl ethyl ketone
Gross Beta TDS nitrobcnzcnc ------TOC pcntachlorophenol . ,
----
--__ p)Tidinc
iv! icrobiology ----t ctrachloroc t hylenc
--__ trichloroethylcnc
Para111eter Results (Col/l00ml) 2, 4,5• trich I orophcnol --
--__ 2,4,6-trichlorophcnol --
----__ vinyl chloride
endrin --
3::7-f.G ~l.eported by
!incbnc
D:iic Received --mcthoxych]or --pce;p,d 3·/:i-%.-1/, tox:iphcn::: --
D;itc Extracted 3-·11-9(, SA,/Y6_ Date Reported 2,,:.1)
J3JJ/t PC8'5-¥/Esr 961153 2,4,5-TP (Si!:•cx)
l);,tc An"!tiedJ.::aJ-% .3~dl-'1_61,ffLah Number
1\11-.: 1,1,11 (l,•~··1,·,·,1 71•;~ --
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N.C. Department of Environment,
! !t:nlth, & NaturJl Resources
Solid Waste Man::igc~cnt Di\ision
SAMPLE ANAi.oYSIS REQUEST
Site Number C0-005-SL 03/06/96 1430 GRAB Number
Stale Labor.1tO[y of l'ublic Hc:i!th
P.O. nox 28~7, J.C,6 N. Wilminpon _Sl1::ct
R.alciih, North f~.nrr:i!inil 2761i
------------------
Name of Site
Cnerokee Oil Collipfny' NC" DOUG-MOORE
SURFACE SOIL IN DRAINAGE DITCH
ESD LAB ·-VOA Soil ·
,, ____________________ _
co-16 Collected By __________ _ . · .. cd Time -----------
Agency: Hazardous Waste Solid Waste .,-/ Superf-und TCLP Compounds ------
Sample Type Inorganic Compounds Rcs11lts(111g/!)
Environmental Concentrate Comments Arsenic --
I Barium --
Ground water (1) _ Solid (5) Cadmium ------Chromium --__ Surface water (2) · _ Liquid (6) Lead --
/soil (3) --Mercury
_ Sludge (7) Selenium --Silver --_ Other (4) Other (8) --
--
--Organic Chemistry Inorganic Chemistry --
Parnmetcr Results(mg/1) Parameter Results (mg/!) (mg/kg) Organic Compounds Results(mg/1)
/P&T:GC/MS Arsenic benzene ----__ Acid:B/N Ext. Barium carbon tetrachloride ----MTBE Cadmium chlordane ------Chloride chlorobcnzcnc ------Chromium chloroform ------
--Copper o-cresol ----Fluoride m-crcsol ----
--Iron __ p-crcsol --Lead crtsol ------
----J\1anganesc --1,4-dich l orobcnzcnc
----Mercury 1,2-dichlorocthanc --Nitrate !, l-dicl1loroethylcnc ------Selenium 2,4-dinilrotolucnc. ----Silver heptachlor ----Radiocl1ernist11 Sulfates hcxachlorobcnzene ----
Zinc hexach l orobu tad icnc ----(l'Ci/1) Parameter Results pH hcxach loroct ha nc ----__ Gross Alpha --Conductivity methyl ethyl ketone --Gross Beta TDS nitrobcnzcnc ------
TOC pcntachlorophcnol .. . , ----, pyridine ----Microbiology ----lctrachloroel h ylcnc
trichlorocthylenc ----Parameter Results (Col/lO0ml) 211t,5-trich lorop h cnol --
----__ 2,4,6-trichlorophenol
------,inyl chloride
cndrin --
J-?-'/f, tY:jAAReported by
!ind,inc
Date Received --
--rni.:thoxychlor
toxa phcnc
D~itl: E.xtr·actcd --Dale Reported 2,,1.D --
Dale /\ n:t!vLcd 3-18-9 (J, 77/.JJ 961154
2,,:,5-TP (Si!;cx)
L:1b Number
!'\!!'~ 1:,;1 /E, .... ;, .. 0/i)]\ ------
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N.C. [1,:p;Htrncnt of Environment,
·1 lcallh, ~~ Natura\ Resources
Solid Waste Man:igcn:icnt Division
SAMPLEANA1;YS!S REQUEST State: 1:---ibor-atory of Public !-lc:i.lth
r.o. Dax 2SG-·.\7, 306 N. Wilmir.gton Strc:cl
R.alcigh, North Carolina. 2_7611
C0-005-SL 03/06/96 1430 GRAB
Site Number __ . • Cherokee Oil Company, NC-'. -DOUG KOORE . ' ,Number _________________ _
SURFACE SOIL IN DRAINAGE DITCH
Name of Site ESO LAB EXT/PEST Soil
co-17
Collected By _________ _ ___ , .. cd ___________ Timc ______ _
Agency: Hazardous Waste Solid Waste ....'.:'.'.'.'.Su per fun d TCLP Compounds ------
Sample Type Inorganic Compounds Rcsults(mg/1)
Environmental Concentrate Comments Arsenic --Barium --
Ground water (1) _ Solid (5) Cadmium ----Chromium --. __ Surface water (2) _ Liquid (6) Lead --Mercury --v Soil (3) Sludge (7) Selenium --Silver --_ Other (4) _ Other (8) --
--
--
Organic Chemistry Inorganic Chcrnistry --
Parnmetcr Rcsults(mg/1) Parameter Results (mg/I) (mg/kg) Organic Compounds Rcsults(mg/1)
P&T:GC/MS Arsenic benzene v Acid:B/N Ext. ----Barium carbon tetrachloride ----MTBE Cadmium chlordane
7 Ft8!,/Par,e,DF".r ----Chloride chlorobenzcnc -----PC'B.i-<o. . -Chromium chloroform ------__ £/ilcl~1't.l "<17./0' .!. -· Copper o-cresol
-L,',,/c/AN€ <c~-.,f• ----·-_, Fluoride m-crcsol ----~,,,.,,,..,,.,.~ Iron p-cresol ----
-~_JfEN'e-<:: Lead crcsol ----
~<O, Manganese 1,4-dichlorobcnzcnc ----J'f!&d&AL -<'0, __ Mercury --1,2-dichloroethane
~•" rf_ Nitrate I, 1-dichloroethylenc , ----,, Selenium 2,4-dinitrololucnc _ ----Silver ----hcptachlor
Radiochemistry Sulfates hcxachlorobenzene ----Zinc hcxachlorohut adicne ----Paramckr Results (l'Ci/1) --pH hcxachlorocthanc --__ Gross Alpha __ Conductivity --methyl ethyl ketone
Gross Beta TDS nitrobcnzcnc ------
TOC pcntacl,lorophenol . ' ----pyridi11c ----
ivlicrobiology ----tel ra chlorocth ylcne
trich loroct hylc nc ----Par:1mctcr Results (Cul/lOOml) 2, 4 ,5-trich lorophcno 1 ----2, 4 ,6-trichlorophcnol ------
------vinyl chloride
cndrin --
Date Rccci,:ecl 3-7-ffo t~ Reported by
lincbnt. --
--rncthoxych!or
f!!,B/fn 3-,,a-% ~ --to:cipbcnc
Date Extracted '?-11-91, :,A,_M_ \),rte Rcporiccl 2,1:-D
6AJI/ ,PU] 51"..-=br . 961155 · o, S TP (S"·Tx) .. , ',--' '" ,,
Date 1\na!y-,e4:~ 3-:l/-'l~f' L,h Number
!)! !'; \l')] (i/.r·:;<;c,: )/1 --
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t<.C. .Dcpartn,c:nt of Envl:onmcnt,
·1 lt.;;1l1h, i t<atur:i\ Rcrnurccs
Solid Waste Man:igcmcnt Division
SA.MPLE ANALYSIS REQUEST
Si:c Number
Name of Site
C0-006-SL 03/06/96 1415 GRAB
Cherokee Oil Company,· NC DOUG HOORE
SURFACE SOIL NEAR NW CORNER OF SUB. PROP
ESO LAB VOA _ Soil ,tit ~ -
co-19
. lumber
St;itc L.aborato1y of l'ub\i-.:: Hc:ilth
P.O. Bo:i: 280-17, YYi N. Wilmington .Strc:t
Ralcif;h, North Ca1uli11il .. 27611
-----------------
Collected By __________ _ , ________ ._.·'· d Time . ._," -------------------------
Agency: Hazardous Waste Solid Waste / Superfun<l TCLP Compounds
------
Sample Type Inorganic Compounds Rcsulls(mg/lj
Environmental Concentrate Comments Arsenic --Barium --
Ground water (1) __ Solid (5) Cadmium ----Chromium --. __ Surface waler (2) Liquid (6) Lead --
.,/Soil (3) --Mercury
_ Sluc!gc (7) Sclc.nium ---··· Silver --_ Other (4) _ Other (8) --
--
--
Organic Chemistry Inorganic Chemistry --
Parameter Rcsu l ls (mg/I) Parameter Rcsulls(mg/1) (mg/kg) Organic Compounds Results(mg/1)
~P&TGC/MS Arsenic benzene ----Acid:B/N Ext. Barium carbon lclrachloridc ------
MTBE Cadmium chlordane ------
Chloride chlorobenzcnc --· ----Chromium chloroform ------
--__ Copper O•crcsol --Fluoride m·crcsol ------
--lron p-crcsol ----
. Lead crcsol ------
----Manganese --1, 4-dich lorobcnzcnc
--__ Mercury --l )•dichloroct hanc
Nitrate 1, 1-dichloroethylenc ------Selenium 2,4•dinilroto!ucnc. ----Silver ----hcptachlor
Radiochemistry Sulfates bex:,chlorobcnzcnc ----
···--Zinc hexach lorobu l :i<l icnc ----Paramett.:r l{esults (!'Ci/I) pl-! hcxachloroct h :, nc ----__ Gross Alpha --Conduclivity methyl ethyl ketone --
Ci ross Beta TDS nitrobcnzcnc ------TOC pcnlachlorophcnol .. . , ----P}Tidinc ----!vlicrnbiology ----tctrach lorocth ylcnc
trichloroethylcnc ----Par;__imctcr Results (Col/ I 00ml) 2, •1,5·trichloro phcno I ----2, 4 ,6-trichlorophenol ·-----
------vinyl chloride
cndrin --
3 -]-9(, ~cportcd by
lincl:lnc
Date Rccci\"cd --
--mcthoxychlor
; tox:--1phcm: --
/);ilc E.xlr:iclcd Date Reported 2,,;. D --
3-/'f3 -Cj (I) 7'7W-L:,h ~umber 961156 __ 2,4,5-TI' (Si! :ex)
Dale ,"'.n,,!yzcd --!\ii<; "'ll•'.1 (ll~••i•.-,•,: lf()I~
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N.C. .t),paitmcr,: of [n,,,ironmcnt,
·1 !callh, & Nalur::i\ Resources
Solid Waste Man;:.~cr'!ent Division
SAMPLE ANALYSIS REQUEST
Site Number
Name of Site
C0-006-SL 03/06/96 1415 GRAB
Cherokee Oil Company, NC -DOUG KOORE
SURFACE SOIL NEAR NW CORNER OF SUB. PROP
ESO LAB EXT/PEST SoiL_
co-20 Collected By __________ _
Agency: Hazardous Waste Solid Waste -----
Sample Type
·• :'-lumber
✓ Superfund
Environmental Concentrate Comments
__ Ground waler (1) _ Solid (5)
__ Surface waler (2) __ Liquid (6)
✓Soil (3) _ Sludge (7)
_ Other (4) _ Other (8)
Organic Chemistry Inorganic Chemistry
Para,nctcr Rcsults(mg/1) Parameter Results (mg/I) (mg/kg)
P&T:GC/MS Arsenic
✓Acid:B/N Ext. --Barium --MTJ3E Cadmium
✓ Fl:BYP~nuz:e. --Chloride ----pc,ej-j.fSo/) /, ~M Chromium --
--51c/,,:/I/ <~o.;p '4C',,.. Copper --
_ L,'A/d,-,NE <p.,.:io~ Fluoride --~ _.,_,.,o/k,c ~ Iron --
_»XA/!Bl;NE ~. Lead --_Ee;:;:,~~~-/.~ . --Manganese
__ Mercury
Y?°&!<'/41,Mt'f@7,X/d,,:-<d,/~-Nitrate --Selenium --Silver --Racliocl1emistr)' --Sulfates
Zinc --Parameter Results (!'Ci/I) pH --__ Gross Alpha --Conductivity
c; ros.s Beta TDS ----TOC --
--lV!icrobiology --
--Parameter Results (Col/ 100ml) --
----
----
Received .::J-7-Cf,6 /Jd:Pzcporlcd 1,y Date
fe.A/tl,-<-t 3·11:·9r;, ,,1-8
/);1lc ExtractcJ 3-IQ-9!,S/l. Date Reported
Date Anal•pc,/Jt. Pee;,,. ;;_or 961157 _..;,'-;?7~_'(;:"//,PL:th Number
lll ,,; 11'1 I /II,•.;.,,, )/'
Stale Lnborntory uf Public Hc::il!h
P.O. Box 2&).17, 306 N. Wilmington._Stn::cl
R.alcig.h, North Caroiina 2_7611
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TCLP Compounds
lnorg~nic c·ompounds Rcsulls(mg/1)
Arsenic --Barium --Cadmium --Chromium --Lead --Mercury --Selenium --Silver --
--
--
--
--
Organic Compounds Rcsults(mg/1)
bcn?.cnc --carbon lclrachloridc --chlordane --cblorobcnzcnc --chloroform --o-crcsol --m-crcsol --
--p-crcsol
crcsol --1,4-dich\01 obenzcnc --1,2-di ch loroct bane
__ 1,1-dichloroclhylene
2/1-dinitrotolucnc. --
--heplachlor
hcxachlorobcnzcnc --hex a ch lorobu lad icnc --hcx:1ch !oroctha nc --methyl ethyl ketone --nitrobcnzcnc --
--penlachlorophenol . ,
--p)Tidine
tetra ch loroel hylene --__ trichloroelhylcnc
2111,5-trich Iara phenol --2, 4,6 ·l ri chlorophcnol --
--vinyl chloride
cndrin --linchnc --mcthoxych)or ---to.x2.phcnc --2,,:.1) --2,ci,5-Tl' (Sil·,,c,)
---
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l\'.C. Department of Emironmcn!,
·! lc:ilth, & Natur3I Resources
Solid Waste Managcn:icnt Division
SAiv!PLE ANALYSIS REQUEST 5t;ilc ; __ ;,or..i.wry of Public Hc:ilth
· P.O. Box 280-\'J, 306 N. Wilmington .Street
l?..:!kigh, Nozth Carolina 27611
Site Number co-001-sD 03/06/96 1420 GRAB
Cherokee Oil Company, NC DOUG HOORE
BACKGROUND SEDIMENT IN UT TO STEWARTS CR
Number-'------------------
Name of Site ESD LAB VOA Sediment
Collected By _____ c_o_-____ 2 2 '' : ' : _.cd Time ------------------.
Agency: Hazardous Waste Solid Waste ~ Superfund TCLP Compounds -----
Sample Type Inorganic Compounds Results(mg/1)
Environmental Concentrate Comments Arsenic --Barium --
Ground water (1) _ Solid (5) Cadmium ----Chromium --
__ Surface water (2) Liquid (6) Lead --
--Mercury
_ Soil (3) _ Sludge (7) Selenium --Silver
✓Other (4~
--
_ Other (8) --
( Sedi .. e.,r --
--
Organic Chemistry Inorganic Chemistry --
Parameter Rcsults(mg/1) Parameter Results (mg/I) (mg/kg) Organic Compounds Results (mg/I)
/r&T:GC/MS Arsenic benzene ----Acid:B/N Ext. Barium carbon tetrachloride ------MTBE Cadmium chlordane ------Chloride chlorobcnzcnc ------Chromium chloroform ------
--__ Copper o-crcsol --Fluoride m-crcsol ------Iron p-crcsol ------Lead crcsol -------Manganese . 1, 4-dichlorobenzcne ------
--__ Mercury --1,2-dichloroct bane
Nitrate 1, 1-dichlorocthylcnc ------Selenium __ 2)4-dinitrotolucnc. --
Silver · __ hcptachlor --
Radiochemistry Sulfates hcxachlorobcnzcnc ----
Zinc hexach I orobu tad ienc ----Parameter Results (PCi/1) pH hcx.Jchloroctham:. ----__ Gross Alpha __ Conductivity --methyl ethyl ketone
Cross Beta TDS nitrobcnzcnc ------TOC pcntachlorophcnol .. . ' ----
----pyridine
[\'! icro biology ----tctrachlorocthylcnc
--__ lrichlorocthylcnc
Par:1rnctcr Results (Col/100ml) 2/1,5-trichlorophcno! _. ' •" -----
2, 4,6-t richlorophcnol '' ·, ------
------vinyl chloride
cndrin --
3~7 -q~ 1111-1f2 Reported by
lindanc
Date Received
--mcthO\Ji:hlor --tox.1pbt:nc --Date E.xtractu! Date Reported 2,"-D
3-JC,-q(p 9611SS
__ 2,,1,5-TP (Sil·:cx)
Date /\n;ily?cd 77 llrLah Number --1 ·1 I ! ,; 11 ') I ( I,' r,,.:c,-,, 1 /'!I\
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i\.C. Department of Environment,
.j [calth, & Natur::il Rcso_urccs
Solid Waste Managcrrycnt Division
SAMPLE ANALYSIS REQUEST
Site Number
Name of Site
co-001-so 03/06/96 1420 GRAB
"Cherokee Oil Company, NC DOUG MOORE
BACKGROUND SEDIMENT IN UT TO STEWARTS CR
ESD LAB EXT /PEST Sediment
co-23 Collected By _________ _
Agency: Hazardous Waste Solid Waste ------
Sample Type
. t: ·. Number
V Superfund
Environmental Concentrate Comments
Ground water (1) --_ Solid (5)
Surface water (2). --_Liquid (6)
--Soil (3) _ Sludge (7) .
✓ Other (4) _ Other (8)
(_s.,4,;.,..,.t-")
Organic Chemistry Inorganic Chemistry
Parameter Results(mg/1) Parameter Results(mg/1) (mg/kg)
_ P&T:GC/MS Arsenic --v Acid:B/N Ext. --Barium
.MTBE Cadmium
V pa3'.s/ffsT1c,bE> --Chloride --_ "['l'E f,-<o, /Of!m Cbromium --~ <"0,10' __ Copper
-~£ ~o.~$ Fluoride --Iron ..J1f. ;_ -eA/,A,. < I ,o, ---r.,5 -sg. t7 P,Rm Lead --..../2, · -< 0, rl~,o/'M --Manganese
_JJ_E. . <,p./~ ¥M --Mercury
~x.,-,.;,<dJ.?--~. Nitrate
v, Selenium . --Silver --
Radiochemistry --Sulfates
··---Zinc --Parameter Results (l'Ci/1) --pH
__ Gross Alpha --Conductivity
Gross Beta TDS ----TOC --
--l'vlicrobiology . --
---Parameter Hcsults (Col/100ml) --
----
----
Date Received 3~ 7-Cff, 1Vef"_ltfRcportcd oy
fc,R,(/!14 3-l'3-1Gk I
Dale l:xlr:iclcd 3-lQ-9kSA Date Reported
61.Jlf "le77,PeBJ'
;;,';~C,;~'.1~;;':''..~~3~;?/_-f~~ I .ah Number
961159
State [,nbordtG,, of l'ub:ic l!co.lth
i'.O. Box 180-17, 3,(1/.; 1-,;. Wilmington _Street
Ra!cibh, North Caroli nil.. 2_761 l
-----------------
TCLP Compounds
Inorganic Compounds Rcsults(mg/1)
Arsenic --Barium --Cadmium --Chromium --Lead --
--Mercury
Selenium ---Silver --
--
--
--
--
Organic Compounds Rcsults(mg/1)
benzene --carbon tetrachloride --chlordane --ch!orobcnzcnc --chloroform --o-cresol --m-crcsol • --
--p-cresol
crcsol --1,4-dichlorobcnzcnc --1,2-dichloroet ha ne --1, 1-dichloroet h ylcne --2,4-dinitrotoluene. --
--heptachlor
hexachlorobenzcne --hcxnch lorobu tad icnc --hcx3chlorocthane --methyl ethyl ketone --nitrobcnzenc --
--pcntachlorophenol . '
pyridine --
tetrachlorocthylcne --trichlorocthylcne --21
1115-tric hi orophcnol --2, 4,6-trichlorophenol --
--,1nyl chloride
cndrin --lindanc --mcthox)1Ch!or --
toxc.phcnc --2,1i-D
__ 2,r.,5-TP (Silv-cx)
--
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N.C. Dcp;,i"tn,,;nt of Environment,
i !cnlth, & Natural Resources
Solid Waste Ma1rngcrncnt Oi\ision
/+CL
SAMPLE ANALYSIS REQUEST State L.nbor.1tory o{ l'ublic H~:ilth.
P.O. nox 280-17, 306 N. Wilm:ngton _Strc.:l
Raleigh, North Caroli nil 2_761 t
Site Number co-001-sw 03/06/96 1430 IGRAB
Cherokee Oil -Company, NC DOUG HOORE
BACKGROUND SURFACE WATER IN UT TO STUART
lumber _________________ _
Name of Site ESD LAB VOA Surface Water
CO-· 2S
' '. Collected By _________ _ . ·d Time -------------------
Agency: Hazardous Waste Solid Waste ✓ Superfund TCLP Compounds ---------
Sample Type Inorganic Compounds Rcsults(mg/lj
Environmental Concentrate Comments Arsenic --Barium --__ Ground water (1) _ Solid (5) Cadmium --Chromium
-✓ Surface water (2)
--
Liquid (6) Lead --__ Mercury
_ Soil (3) _ Sludge (7) Selenium --Silver --_ Other (4) _ Other (8) --
--
--
Organic Chemistry Inorganic Chemistry --
Parameter Results (mg/I) Parameter Res ul ls (mg/l)(mg/kg) Organic Compounds Rcsults(mg/1)
VF&T:GC/MS Arsenic bent.enc ----__ Acid:B/N Ext. Barium carbon tctr.:ichloridc ----MTBE Cadmium chlordane ------Chloride chlorobenzene ------Chromium chloroform ------
--__ Copper o-cresol --Fluoride m-crcsol ------
--Iron p-cresol ----Lead crcsol ------
--__ Manganese 114-dichlorobcnzcnc --
--__ Mercury J ,2-dichlorocthanc
--Nitrate __ 1,1-dichloroethylene --Selenium 2)4-dinitroto!uenc. ----Silver __ heptachlor --Radiochemistry Sulfates hexachlorobenzcne ----Zinc hcx<ichlorobut adicnc ----
Parameler Kcsults (l'Ci/1) pH h1.:x3chlorocthanc ----__ Gross Alpha --Conductivi~y --methyl ethyl ketone
Gross Beta TDS nitrobcnzcnc ------TOC __ pentachlorophenol ' --
----pyridine
l\'licrobiology ----tetrachlorocth ylcne
--__ trichloroethylenc
Par·ameter Hcsults (Col/lOOml) 2, 4,5-trichloropheno I --2,4,6-t richlorophcnol ----
----__ ,inyl chloride
endrin --lindanc
2) -7-<j(, ,1,(/l!q /!!P,eportcd by Date Received --mctho:...-ych!or
I --tox:iphcnc --Dall: E.xtr:.icti.:d Date Reported 2,11-D
3-,;;l-1(p nur 961160 2,•1,5-TP (Si! :ex)
Dale Anct!t1.cd L:1h Number --t\ I i,; 1 I Ill (I.',-..· .. ,t ")/111,
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t-).C. D.cp;ir"tn1<.:nt oi En\-irv:,mcnl,
i i<;;i\lh, i Natur;i! Re.mu recs
Solid Waste Mar.agc.rr:icnt Division
SAMPLE ANALYSIS REQUEST Stale Lnbor,uory of Public Health
P.O. nox 280-17, 306 N. Wi!min,:ton _Sln:ct
Raleigh, North CaJ?lin!I,. 2_7611
Site Number
co-001-sw 03/06/96 1430 GRAB -Cherokee Oil Company, NC _ DOUG MOORE · ·,,, Number _______________ _
BACKGROUND SURFACE WATER IN UT TD STUART
Name of Sile ESD LAB... EXT __ 0~G __ Surface·water
co-26
Collected By __________ _ 11...1rr ____ Uctlc:; ;._:u11~-:Lc<l ___________ Timc ______ _
Agency: Hazardous Waste Solid Waste / Superfund TCLP Compounds ------
Sample Type Inorganic Compounds Rcsults(mg/1)
Environmental Concentrate Comments Arsenic --Barium --
Ground waler (1) _Solid (5) Cadmium --Chromium
. V Surface water (2)
--
_ Liquid (6) Lead --Mercury --
_ Soil (3) _ Sludge (7) Selenium ---··· Silver --
Other (4) _ Other (8) --
--
--
Organic Chemistry Inorganic Chemistry --
Parameter Results(mg/1) Parameter Results(mg/1) (mg/kg) Organic Compounds Results(mg/1)
P&T:GC/MS Arsenic benzene
7 Acid:B/N Ext. ----
Barium carbon lclrachloride ----
MTBE Cadmium chlordane ----~..., 'I __:___ •«p;;;:s~'f,i;:s Chloride chlorobenzenc ----Chromium chloroform ----
--__ Copper o-cresol --Fluoride m-crcsol ------
--Iron p-cresol ----Lead crcsol ------
--__ Manganese 114-dichlorobcnzcnc --
--__ Mercury 1,2-dichlorocthane --Nitrate 1,1-dicl,loroclhylene ------Selenium 2)4-dinitrotolucnc. ----
Silver __ hcplachlor --
Radiochemistry Sulfates hcx.1chlorobcnzcnc ----Zinc hexach lorobu lad i enc ----
Parnmckr Results (PCi/1) pH hcx:1chlorocthanc ----
__ Gross Alpha __ Conductivity methyl ethyl ketone --
Gross Beta TDS nitrobcnzcnc ------TOC pentachlorophenol . , ----pyridine ----ii'! i c rob i o Io gy ----tel raehloroelh ylcnc
trichloroelhylenc ----Parameter Results (Col/100ml) 2, ,J,5-trichlorophenol --2, 4 ,6-trichlorophcnol ----
----__ ,inyl chloride
cndrin --
Date Rcccived~<.eporled by
lindanc --
--mcthoxych!or
tOX8 rhcnc --/);l[c Extr:ictc.:d 3-6-q~ 5A,'rvC,-Date Reporled 2,,1.1) --
Date ,\11:ilyzed _;}J-/S ✓'f{,,(3J)_ 961161 __ 2,4,5-TI' (Si!·;ex)
L:1\i Nurnbc.r --! )I''-: \11)1 filr·.·;~,·,1 ·1 /':11
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N.C. Department of Environment;
·1 lcalth, & Natural Resources
Solid Waste Managc.n:icnt Division
SAJ\'1PLE ANALYSIS REQUEST
Site Number C0-002-SD 03/06/96 1340 GRAB .. • J Cherokee Oil Company; NC DOUG HOORE. Numbc.1
SEDIMENT AT PPE IN UT TO STEWART'S CRK.
Name of Site -ESD-LAB •· VOA Sediment
State Lnb1)r.ito1y o[ Public l-lcalth
f'.0. Box 2W-l7, 306 N. Wilmington_.Strcct
Raleigh, No1th C..aro!inil. 27611
------------------
co-28_ Collected By _________ _ ....,..,,v ..... v!,".._lcd Tinie -----------------------
Agency: Hazardous Waste Solid Waste V Superfund TCLP Corilpounds ------
Sample Type Inorganic Compounds Rcsults(mg/1)
Enviror1mental Concentrate Comments Arsenic --Barium --__ Ground water (1) _ Solid (5) Cadmium --Chromium --. _-_ Surface waler (2) _ Liquid (6) Lead --Mercury --
_Soil (3) _ Sludge (7) Selenium --Silver
✓ Other (4) --Other (8) --{~. -...,:,.d--') --
--Organic Chemistry Inorganic Chemistry --
Parameter Resulls(rng/1) Parameter Results(mg/1) (mg/kg) Organic Compounds Results(rng/1)
v'J'&T:GC/MS Arsenic benzene ----Acid:B/N Ext. Barium carbon tetrachloride ------MTBE Cadmium chlordane ------Chloride chlorobenzcnc ------Chromium chloroform ------
--Copper o-cresol --,--
Fluoride m-crcsol ------Iron p-crcsol ------Lead crcsol ------
----Manganese --l ,4-dichlorobcnzcnc
--__ Mercury --1,2-dich lo roe I bane
Nitrate 1, l-dic\1loroe1hylcnc ------Selenium 2,4-dinitrotolucnc _ ----Silver heplachlor ----Radiochemistry Sulfates hexachlorobenzene ----Zinc · hexach!orobutadicne ----l(esults (l'Ci/1) l1arameter pH hcx3chlorocthanc ----__ Gross Alpha --Conductivity --methyl ethyl ketone
Gross Bela TDS nitrobcnzcnc ------
TOC penlachlorophcnol . ,
----
----pyridine
/vii cro biology ----tetrachloroethylcne
trichlorocl h ylcnc --Par:itllcter Results (Col/lO0ml) --__ 2,415-trichlorophcnol
2, 4,6-t rich I orophenol ------
------vinyl chloride
cndrin --lindanc 3-7-Y~ Reported by Date Received --met ho\)'Ch lor --toxaphcnc --l);1lc !:.xtr:ict<.:d Dale Rcporicd 2,r,-D --
3-I 9 -9 /.p_ ii ur 961162 __ 2,,1,5-TP (Si: :ex)
Date ;-\n:dyzcd Lah Number --I \I 1,: 111)1 fl/,._,;e,.,, 1 /1)1 \
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t'-.'.C. Department of Environment,
! lcalth, &. Natural Resources
Solid Waste Managcn)Cnt Division
SAMPLE ANALYSIS REQUEST
Site Number
Name of Site
C0-002-SD 03/06/96 1340 GRAB
· Cherokee Oil Company ,NC -DOUG HOORE
SEO!HENT AT PPE IN UT TO STEWART'S CRK.
ESD LAB .EXT /PEST Sediment
Number
State L.abordto1y or Public lk:1i1h
P.O. Box 2S0-17, 30<) N. Wilmington ~lrccl
R,1.lc.igh, North Carolina 2_7611
-------------------
co-29
Collected By _________ _ ., .eel Time ------------------
Agency: Hazardous Waste Solid Waste V Superfund TCLP Compounds ------
Sample Type Inorganic Compounds Rcsults(mg/1)
Environmental Concentrate Comments Arsenic --Barium --__ Groundwater _(l) _·Solid (5) Cadmium --Chromium --. __ Surface water (2) Liquid (6) Lead --Mercury --
Soil (3) Sludge (7) Selenium --Silver
/ Other (4) --_ Other (8) --
{ ;Se,1.; ... _+ ') --
--
Organic Chemistry Inorganic Chemistry --
Parnrnetcr Results(mg/1) Parameter Results (mg/I) (mg/kg) Organic Compounds Results(mg/1)
_P&T:GC/MS Arsenic benzene ----./' Acid:B/N Ext. Barium carbon tetrachloride ----MTBE Cadmium chlordane 7 1t=.a~/PEYsne.1bEs
----chlorobenzcn·c Chloride ----
--Pea's: <::.o,Jo~ Chromium· chloroform ----
--EN(l',Ri,A/ ~ 0.10,,I'"' Copper o-cresol ----bAlmiAIE <: 0. ,;:i.o-:.___. Fluoride m-crcsol
'7Yfrl.Ao~ , ~"" <: ~, 0 L(~ ----
Iron p-cresol ----1oXA ,,(,1 EN€--<:-.?, _. -Lead· cresol
-/JA/i? -. ----
<!:" "'0~ -.... Manganese 1, 4-dicb lorobcnzene
_:Jf cpt,?cAh ,e ,c::'r> I I ,I ----__ Mercury --1)-dichlorocthanc
~/',,/t:<o.' 1:1---Nitrate 1, 1-dichloroet hylcne ----,, Selenium 21 4-din itrotolucnc ----Silver heptachlor ----
Radiochemistl)' Sulfates hcxachlorobcnzcnc ----Zinc hexach !orobu tad icnc ----Jlarameter Results (l'Ci/1) pH hcxachloroct ha nc ----__ Gross Alpha --Conductivity --methyl ethyl ketone
Gross Beta TDS nitrobcnzcnc ------TOC pcntachloropbenol ,
----pyridine ----
1Ylicrobiology ----tel racbloroetb ylene
--__ trichloroethylcne
Parameter Results (Col/l00ml) 2, 4,5-tricbloropbcno I ----2,4,6-t richloropben ol ------vinyl chloride ------endrin --lindanc
.3-7-</{, ~ #J Reported by Date T\::::ccivcd
--rnc(hoxych!or
7 --
/'U?!P..w' '3-1? -% :4[!. --tox.1phcnc
Date 10:xtrilclcd 3-/:)-9(, SA Date Reported 2,'l-D
1JjJ1f f'(!,B~><~ --
961163 __ 2,.1,5-TP (Si!·:e,)
'.~il,e/~ ~·~ l:':~~j~pL" h N11111 bcr --
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N.C. l~'P"'"""' o[ Emironmcnt, SAMPLE ANALYSIS REQUL.3T
i lcallh, & Natural Resources
Solid Waste Man;igcn)Cnt Diviidon
Stale L:iborntory of Public Health
P.O. Box 280-\7, 306 N. Wilmington __ Slrcc!
Raleigh, North Cnro!ina 27611
Site Number C0-002-SW 03/06/96 1350 GRAB
Cherokee Oil Company, NC DOUG HOORE
SURFACE WATER BELOW PPE IN UT TO STEWART
·, Number _________________ _
Name of Site ESO LAB VOA Surface Water
co-31
Collected By -----------_____ -·-, ____ .. ed ___________ Timc ______ _
Agency: Hazardous Waste Solid Waste V Superfund TCLP Compounds ------
Sample Type Inorganic Compounds Rcsults(mg/1)
Environmental Concentrate Comments Arsenic --Barium --Ground water (1) _ Solid (5) Cadmium ----
. Vsurface water (2).
Chromium --
_Liquid (6) Lead --Mercury --
_· Soil (3) _ Sludge (7) Selenium -----Silver --Other (4) _ Other (8) --
--
--
Organic Chemistry Inorganic Chemistry --
P✓l1etcr Rcsults(mg/1) Parameter Resull.s(mg/1) (mg/kg) Organic Compounds Rcsults(mg/1)
_P&T:GC/MS Arsenic benzene ----
--Acid:B/N Ext. Barium carbon tetrachloride ----'MTBE Cadmium chlordane ------
Chloride . chlorobenzcne ------Chromium chloroform ------
--__ Copper o-crcsol --Fluoride m-crcsol ------
--Iron p-crcsol ----Lead crcsol ------
----Manganese 1,4-dichlorobcnzcnc --
----Mercury 1,2-dichlorocth anc --
--Nitrate 1, 1-dichloroethylcnc ----Selenium 2,4-dinitrotoluenc. ----Silver heptachlor ----
Radiochemistry Sulfates hcxachlorobenzcnc ----.... Zinc hcxach lorobu tad icnc ----Parameter Results (f'Ci/1) pH hcx.1chlorocthane ----
--Gross Alpha __ Conductivity --methyl ethyl ketone
Gross Beta TDS nitrobcnzcnc ------TOC pentachlorophcnol ' ----
----pyridine
J'vl i cro biology ----tct rachloroet hylcnc
trichlorocthylcnc ----Pan.11nctcr Results (Col/JOOml) 2, 4,5-trich lorophcnol ----
------2, 4 ,6-trichlorophcnol
------,snyl chloride
cndrin --
'J.--]~<!f, ~de,Rcportcd by
lindanc
Date Received --mcthoxych!or --tox.:phcnc --Dale Extracted Date Reported 2,n-D --
.3-J ;;J.-9 {(, 71UJ" Lab Number 961164 --2,1,5-TP (Si!·,cx)
Dale Analyzed ---I)! ::i '.i!'Ji (l\ui::r:rl 2/91)
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N.C. Dcpnrtment of Environment;
i lcalth, & Natural Resources
SoliJ Waste Managen:icnt Division
SAMPLE ANALYSIS REQUEST
Site Number
Name of Site
co-002-sw 03/06/96 1310 GRAB
· Cherokee Oil Company, NC· DOUG HOORE
SURFACE WATER BELOW PPE IN UT TO STEWART
ESD LAB EXT· ORG Surface Water-
:Number
St.itc Laboratory of Public Hc::i\th
P.O. nox 280-17, 305 N. Wilmington _S!rccl
R.alcigh, North Carolini1_ 27611
------------------
CO-32 Collected By _________ _ __ '..._ .. ed ___________ Time ______ _
Agency: Hazardous Waste Solid Waste V Superfund TCLP Compounds ------
Sample Type Inorganic Compounds Rcsults(mg/1)
Environmental Concentrate Comments Arsenic --Barium --Ground waler (1) _ Solid (5) Cadmium ----Chromium
. .,/" Surface water (2) --_ Liquid (6) Lead --
--Mercury
_· Soil (3) _ Sludge (7) Selenium --Silver --Other (4) _ Other (8) --
--
--Organic Chemistry Inorganic Chemistry --
Parameter Results(mg/1) Pam meter Results(mg/1) (mg/kg) Organic Compounds Rcsults(mg/1)
P&T:GC/MS Arsenic benzene
7 Acid:B/N Ext. ----Barium carbon lelracbloridc ----MTBE Cadmium chlordane ------~ Chloride chlorobenzcnc --
ll~N '9t. ----
--Chromium chloroform • ----
--__ Copper o-crcsol --Fluoride rn-crcsol ------
--lron p-crcsol ----Lead crcsol ------
----Manganese l, 4-dichlorobenzcne --
----Mercury 1,2-dicbloroct bane --
--Nitrate 1, 1-dichlorocthylcne ----Selenium 2/1-dinitrotolucnc. ----Silver heplachlor ----Radiochemistry Sulfates hcxachlorobcnzcnc ----.... Zinc hexach lorobu tad icnc ----(!'Ci/I) Parameter Rc,ults pH hcxachlorocl hanc ----__ Gross Alpha --Conductivity --methyl ethyl· ketone
Gross Beta TDS nitrobcnzc.nc ------TOC pentachlorophcnol . , ----
--__ pyridine
l'Vl i c rob i o Io gy --tclrachloroclhylcne --
--trichloroelhylcne
Parameter Results (Col/lOOml) 21 415-trichlororhcnol ----
----2, 4,6-trichlorophcnol
----= 11nyl chloride
cndrin --lindanc.
Dcttc T(cccivcd :J~J--'/,{, ~Reported by
--rncthoxychlor --
--!oxi1phcnc
Date [xlractcd .:3:8-91• SA, h/G:___ 0'1lc Reported --2/1-D
J~tf ~'Jt:,,JL) 961165 __ 2,4,5-TP (Si!·,cx)
D,!lc An~ilyLcd Lab Number --11 I I 'i J l fl\ ( l·'.c·.-i:;r:<l n·n \
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N.C. Depnrimcnt of Enviro,1mcnt; ·
·1 k::illh, & Natur:il Resources
So:id Waste 1\ian:ii:;cn:icnt Oivisi~n
S1,.MPLE ANALYSIS REQUEST State l...nbora101y of Public I lcJi",h
P.O. Box ?.S0-17, 306 N. Wilmington Stn:i:t
R.alcibh, ·N~11h. C.O:rolina · 27011
Sile Number C0-003-SD 03/06/96 1230 GRAB 1-;
Cherokee Oil Company, NC . DOUG MOORE
SEDIMENT AT DRAINAGE CULVERT BETWEEN PPE
Number _________________ _
Name of Sile ESD LAB VOA Sediment
Collected By _____ c_o_-____ 3 4 · .:d Time ------------------
Agency: Hazardous Waste Solid Waste V Superfund TCLP Compounds ------
Sample Type Inorganic Compounds Rcsults(mg/1)
Environmental Concentrate Comments Arsenic --Barium --
Ground water (1) _Solid (5) Cadmium ----Chromium --
. __ Surface water (2) _ Liquid (6) Lead --
--Mercury
_ Soil (3) Sludge (7) Selenium --.
Silver
✓other (4) Other (8) --
--
{~al,-...~") --. --
; Or"anic Chemistry Inorganic Chemistry b --
P✓i1eter Rcsults(mg/1) Parameter Resulls(mg/1) (mg/kg) Organic Compounds Rcsults(rng/1)
_P&T:GC/MS Arsenic benzene ----_ Acid:B/N Ext. Barium carbon tetrachloride ----"MTBE Cadmium chlordane ------Chloride chlorobenzcnc ------
Chromium chloroform ------
--Copper o-crcsol ----Fluoride m-crcsol ------
--lron p-crcsol ----Lead crcsol ------
----Manganese --1,4-d ich !orobcnzcnc
--__ Mercury --1,2-dichloroethane
Nitrate I, 1-dichlorocthylene ------Selenium 214-dinitroto!uenc. ----Silver heptachlor ----
Radiochemistry Sulfates hcx.1chlorobcnzcnc ----Zinc hcxach l orobu lad i enc ----l';irameler Results (PCi/1) pH hcxachlorocthanc ----__ Gross Alpha --Conductivity --methyl ethyl ketone
Gross Beta TDS nitrobcnzcnc ------TOC pcntachlorophenol . ,
----
----pyridine
!Vlicrobiology ----tclr a ch loroelh ylenc
--__ trichloroelhylcnc
l';ir:1n1eter Results (Col/100ml) __ 211t,S-trichloropl1cno! --2, 4 ,6-tri chlorophenol ------
------,onyl chloride
cndrin --Ii ncl:uJG 3-J-C/?::> ~#:!Reported IJy D:itc R('.cci,·cd
--
--mcthoxych\or
I --tox.Jphc.nc
[);i(c E:xlr:1clcd Dale Reported 2,'i-D
3-/Cf-9(p71W-
__ 2,•l,5-TP (Si!·:cx)
0;1lc i\n:ilyzcd L:1b Number 9611£6 ---~ ---------! ) 11 '; \ 1 lj] ( !•'., .... ;•,:,·d ·'/()I',
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N.C. l.)cpartnicnt of Environment,
·, [c;i!th, & Natural Resources
Solid Waste Managcn)Cnt Oivisi?n
SAMPLE A.;-l'ALYSIS REQUEST Stale l...nbor.1tory of Public Health
P.O. nox 281}17, 306 N. Wilmington _Street
Raleigh, North Carolina ..2,7611
Site Number C0-003-SD 03/06/96 1230 GRAB 1. ·a
Cherokee Oil Company, NC · DOUG MOORE.
Number _________________ _
Name of Site SEOIHENT AT DRAINAGE CULVERT BETWEEN PPE
ESO LAB EXT /PEST Sediment
co-35 Collected By __________ _
Agency: Hazardous Waste Solid Waste / Superfund
Sample Type
Environmental Concentrate Comments
__ Ground water (1) __ Solid (5)
. Surface water (2) Liquid (6) ___________ _
_ Soil (3)
✓ Other (4)
('¼L,'-~J
_ Sludge (7) ___________ _
Other (8) ___________ _
Organic Chemistry
Results(mg/1)
Radiochemistry
····---------------'
Parameter Results (l'Ci/1)
__ Gross Alpha ______ _
Gross Beta
rv1 icro bio I ogy
Parameter Results (Col/1001111)
Inorganic Chernistry
Parameter Results(mg/1) (mg/kg)
--
--
--
Arsenic
Barium
Cadmium
Chloride
Chromium
Copper
Fluoride
Iron
Lead
__ Manganese
__ Mercury
Nitrate
Selenium
Silver --
Sulfates
Zinc
__ pl-I
__ Conductivity
TDS --TOC
TCLP Compounds
Inorganic Compouncls
Arsenic
Barium
Cadmium --Chromium
Lead
__ Mercury
Selenium
Silver
Organic Compounds
benzene
carbon tetrachloride
Rcsults(mg/1)
Rcsults(mg/1)
---------chlordane
chlorobcnzcnc --chloroform
o-crcsol --m-crcsol ----p-crcsol
crcsol
__ 1,4-dichlorobcnzcnc ______ _
__ 1,2-dichlorocthanc
__ 1,l•dichloroethylene ______ _
__ 214-dinilrotolucnc _
__ heptachlor
hcxachlorobcnzcnc --hcxc1ch 1 orobut adicnc --hcx:ichloroc! h anc --methyl ethyl ketone --nitrobcnzenc --
--pentacl,lorophcnol
--\l)Tidinc
__ tetrachlorocthylcnc
__ trichloroethylcnc
__ 21 ,11S-tricl1 loropl1cnol
7,4,6· 1 rich] oro phenol
__ vinyl chloride
cndrin
lindanc
__ mcthoxych!or
__ tox;;phcnc
2,,,.1)
__ 2,·1,5-Tl' (Si!:cx)
'
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n
D
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f/CL ~,-..-,,,/, 4 l'/1-:1 41:1
N.C. Department of En,..ironmcnt,
i lcnlth, & Natura! Resources
Solid Waste Manngcmcnt Divisi~n
SAMPLE ANALYSIS ,::EQUEST
Site Number C0-007-TB 03/06/96 1330 GRAB Number
Cherokee Oil Company, NC · DOUG MOORE
Name of Site TRIP BLANK
ESD LAB YOA · · Water
Collected By co-3? .cd
Agency: Hazardous Waste Solid Waste ✓ Superl'und ---------
Sample Type
Environmental Concentrate Comments
__ Ground waler (1) _ Solid (5) Tr•p /3/e,,,.,k .
. Surface waler (2) _ Liquid (6)
_ Soil (3) _· _ Sludge (7)
/ Other (4) _ Other (8)
o,,....,,.,,. Fr,ee Jvqk.,)
Organic Chemistry Inorganic Chemistry
Paramctl.'.r Results (mg/I) Parameter Results (mg/I) (mg/kg)
✓ P&T:GC/MS Arsenic --
--Acid:ll/N Ext. Barium --MTBE Cadmium ----Chloride ----Chromium ----
--__ Copper
Fluoride ----Iron ----Lead ----
--__ Manganese
--__ Mercury
Nitrate ----Selenium --Silver --Radiochemistry --Sulfates
Zinc --Parameter Results (l'Ci/1) --pH
__ Gross Alpha __ Conductivity
Gross Beta TDS ----TDC --
--
IV!icrnbiology --
--Par;11netcr Results (Col/1001111) --
----
----
J_,.-J---'f b$./J)ff Reported by Date. Rccci\·cd
.7
Date Extracted Date Reported
Dale ;\n:ilyLcd 3-/;;J. -C,(p 77l.(.rL,h N11111b<or 961168
1)1!'-: ll')l (1-'r·::-~,-d "1/'!1',
Scat,: LnborJLoiy o( Public I lc:1llh
F.(). Box ?.S-(}17, 306 N. Wilmington _Slrccl
Raleigh, North Carolina 27611
Time
TCLP Compounds
Inorganic Cmnpouncls Resulls(mg/1)
Arsenic --Barium --Cadmium --Chromium --Lead --Mercury --Selenium ---··
Silver --
--
--
--
--
Organic Compounds Results(mg/1)
benzene --carbon tetrachloride --chlordane --chlorobcnzenc --chloroform --o-cresol --m-crcsol --
--p-crcsol
crcsol --1,4-dich lorobcnzcnc --1,2-dichloroct han(;. --1, 1-dichloroethylcnc --__ 214-dinitrotolucnc.
__ hcptachlor
hexachlorobenzcne --
he:G1ch lo robu! ad icnc --hcx::ichlorocthanc --methyl ethyl ketone --nitrobcnzcnc --
--pentachlorophenol . '
--pyridine
let rach loroeth ylcnc --trichlorncthylcnc
2, /4,5-trichlorophcno I --2, 4 ,6-t richlorophcnol
--vinyl chloride
cndrin --lindanc --mcthoxyChlor --tox.1phenc --2,/4.[) --_ 2,,t,5-Tl' (Si! ;ex)
--
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REGION: IV . PROJ. LEADER:' DOUG HOORE
. ACTIVqY: SI
PROJECT ID:
REGION: IV COHPANY: SUPERFUND
SPILL ID:
SITE NAHE: Cherokee Oil Company·
CITY, STATE: Charlotte/Hecklenburg, NC
DATE SHIPPED: I I CARRIER:
AIRBILL:
SHIPPED TO:
ATTN:
PHONE:
LAB
SUPERFUND
CHAIN-OF-CUSTODY RECORD
I SAHPLE ID STATION DESCRIPTION MATRIX DATE/TIME SAMPLER
C0-001-SB Background Subsurface soil Subsurface Soil 03-06/1515 DOUG MOORE
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( 4) co-7, 7, 8, 8 VOA(2), EXT/PEST(2) C0-001-SD Background sediment in UT to Stewarts Cr Sediment ( 4) co-22, 22, 23, 23 VOA(2), EXT/PEST(2)
C0-001-SL ta}kground Surface Soil Soil 4 -1, 1, 2, 2 VOA(2), EXT/ E 1(2)
C0-001-SW Background surface water in UT to Stuart Surface Water 03-06/1430 DOUG RUMFORD
( 4) CO-2S, 25, 26, 26 VOA( 2), EXT ORG( 2) C0-002-SB Subsurface Soil Area #I Subsurface Soil 03-06/1150 DOUG HOORE
03-06/1420 DOUG RUHFORD
03-06/1501 DOUG MOORE
(4) co-4, 4, 5, 5 VOA(2), EXT/PEST(2) C0-002-SD Se1iment at PPE in UT to Stewart's erk. Sediment
VOA(2l, EXT/~!s1f~j 28, 28, 29, 29
co-Ooi-SW Surface water below PPE in UT to Stewart Surface Water 03-06/1350 DOUG RUMFORD (4) co-31, 31, 32, 32 VOA(2), EXT ORG(2)
C0-003-SB Subsurface soil Area 12 Subsurface Soil 03-06/1240 DOUG HOORE (4) co-10, 10, 11, 11 VOA( 2), EXT /PEST( 2)
C0-003-SD te1iment at drainage culvert between PPE Sediment 4 co-34, 34, 35, 35 VOA(2), EXT/ E 1\2) C0-004-SL Stainea Surface Soil Area 13 Soil (4) co-13, 13, 14, 14 VOA( 2), EXT /PEST( 2)
03-06/1340 DOUG RUMFORD
03-06/1230 DOUG RUMFORD
03-06/1205 DOUG HOORE
C0-005-SL Surface soil in drainage ditch Soil
(4) co-16, 16, 17, 17 VOA(2l, EXT/PEST(2) C0-006-SL Surface soil near NW corner of Sub. Prop Soil
( ) (4) co-19, 19, 20, 20 VOA 2 , EXT/PEST\2/ C0-007-TB Trip Bank Water ( 2) co-37, 37 VOA(2)
03-06/1430 DOUG HOORE
03-06/1415 DOUG MOORE
03-06/1330 DOUG RUMFORD
White -LAB Copy for Return to Samplers Yellow· LAB Copy Pink· Sampler's Copy Gold -Extra Copy
., . . '
)i,,·ision··of-Solid \Vastt:. Manageme'nt
~up~rfund .Section I Hazardous \\'aste Section
1 Solid Waste Section
~)r·ganttS i_:il.1: ,,,,r
Inorganics Lab: __ _
I CHAIN OF CUSTODY RECORD .
\ liroject Name: Cher,,free b/1 (c,.,pr,,y
~ite JD # (NCO#) NCI> '180 79"1 011
iit°cation: ,th,t,-/o-#., JI{~~,-,.,~ a,
.clclress: t-:i.o / Ekrryl.,'// l?D,od
ample Types: Soil --"----
AIC
Water v
Sampled by: ]) . ,,,,..,,,,€
Sampler ID NC SvPePFoAJb ~Ecnol\J
Telephone: ( 9t'I )----'-7-=3-=3c.,-_21!,=-c-o.,_/-°'.ic.:.--=.3.:..:1 s=----
Da te Sampled :_---'3=-</.'--'t,'--'/'-'-'9<."----------
Time Sampled:
Waste 0th er Su/,;,..e.,,J--------
(em arks: _____________________________________ _
'. lielci Sample t!o-I co-:. co-'1-co-.5 co-7 co-B Ct>-/0
umbers CfP-11 co-t3 co-tr Cc)-/(. Co-/? rt>-11 C,:, -'2.0
co-,z Co-7-3 C.6 -LS" co-u Co-2-~ co-21 C6-31
Co -32.. C0-3't Co-3S co-37
, Relinquished by: ~.e.;, /?,.al~ Date:p,Mi; Time: . /y !;2. P--
. ,ccdccd by -d'~"i:., C ~$ ..... Da<e --Time ff: z{· ..
• (Signature) ·
! i Relinquished by:_________________ Date:___ Time:~·-----
i I (Signature) . : -' .. ____ . --------------------------------------------------------------------------. --------------------------------. --------------------.-----.
Received by: Date: ___ _ Time: -----~
(Signature)
Relinquished by:_________________ Date:___ Time: ____ _
I · (Signature) . · .
----• ,. _______ ---------------• -----------.--• ---------------. r.~ --------------------------------. -------· ----------. ------. --------------------
Date: ___ _ Time:_· ____ _
(/\:\COCR.FRM)
I
----1 STATE UBORATORY OF PUBLIC HEALTH
PO BOX 28047 -306 N. WILMINGTON ST., RALEIGH, NC 27611
I ORGANIC CHEMlCAL ANALYSIS
I PURGEABLE COMPOUNDS LAB NO q/p I I 4-'t q lo JI '-I CD
FIELD NO I co-+
I COMPOUND TYPE ( 3 ) ( .3 )
M~S)~ 'pp pprn ~ib) pprr: (oPb -I CHLORO~HAN!: JO LL I
VIN'TL Cill.ORID!: 10
I BROMOKETHAXE ;;__O
cm.oRO!':I'HANE 10
I TRlcm.0ROP'LUOROMJrrRA.~ ,o "\
AC!:TOin: ::20 Io.;;>. J"
I 1.1-DICHLOROETHEI'R: 5 I l
tOOO~
METHTIZ!m CRl..ORIDIC
I CAR.BOl'I' DIS1J1.TIDIC
TRAffS-1.l•DICHLORO £'TBZ."I'!; ' /
I ACK?I.ONTrRIL>: ;;;}.D \ I
5 (p l,l•DICHLORO&THAl'fE
I 2-BUTAKOl'B ;)_C> (oJ
CIB-1.2--DICHLOROtrm:NE 5 3;2.
CHLOROFORM lL-
1.1.l·TIUCHLOROETHAZ'm 9
CAR.BOl'I n:I'JV.CHl.ORIDE LL--
= lfJ
l,:l•Dlcm.oROenlAlB 1 -fl ~
I TRICHLORO~ 31
1.!1-DICHLOROPR.OPAJ'rE LL
m BROIIOOICHl.OROJO:rB.,\Nl; ' I
' I ~
I
m
c-Po~, .. L.IS LA0 ca..rns1'-111"flno1J OR BAc.f::.frRcuND,
J -E■ti=at•d va1u•
X -Actua1 value ie known to b• l••• than value given.
L -Actual va1ue i• known to b. greater than value g-iven.
9&//1./-6
co-7
( 3)
/ppb)pprn ,~
.., I
.5 J,l.
/)
.J/
7 J,(..
U-
,I
'if.D 1/50 qu, 115:l_
c.0-10 co-13
( 3 ) ( 3)
'{JP t,},prr. lppb)pp,n
IA 11
' I I I
ID (J) :r ;J.;;_7 :r
I~ I '
J,
3 :f,(..
,
\/ I/
CJ ;; j
5:r ) 9J :r
+ra.Le... L I I l I l
+-nu.~ frcu.e....
d, :J -/--rn,P
I l LL
;;i. J (JJ
LL fYnrP
/T +nxe..,
(.,L-LL
~ -1--rnrp
C' -Kat•ri&.l waa ana.ly:c•d t.or but net dot•ct•d. Th• number i• th• llil:t.i:mzm J)et•ction Lim.it.
JD. -Bot analyz•d. II 1/ -T•ntativ• identification. II 'i_t -ca""P0"1'\D _Ra.lf'\E>L.'f·OETECT'l'\6L£ o>JLY 1N H1<rt-1 c.oNCt:NTl<AllcN5,
✓-SMIPu~, Hl&Hl.'/ QILu.TE D, MDL'"' Do NOT P,PPL.'{. D DEHNR 3065-0 (10/93)
(J)
q(()J/.5Lf
Co -I <.t,
( -3 )
"ppbJ R'.JiT1
{J.__
'\ /
PORGCOM.ORG
STATE LABORATORY OF PUBLIC HEALTH I
I PO BOX 28047. 306 N. WILMINGTON ST., RALEIGH, NC 27611
ORGANIC CHEMICAL ANALYSIS
I Pl/RGEABLE COMPOIJMJS LAB NO q (o // i.J.L/. 9~1 ,.4w q{_p/140 q01150 Cl(.D/(6;2_
FIELD NO I CO-if co-7 co-,D Co-13
r COMPOIJMl TYPE ( .3) ( 3 l ( ) ( 3 ) ( 3 )
I
fp~f)5 (i,pb)f'pm / o<Jb'}ptt1 '(ipb~)pf"'1 ~pbJpprn rfpb)ppm
D rBROMOM..ETHAN!: 5 LL-/.,L / ' , I I
4-METHTL-2-nnuom:: ,o
I CIS-1.3-DICHI..OROPRQP!;NE 5 , I ,i,, ,v
TOLtJEl'l'E 3oC/ ;;27 //rO
I ~l.3-DlCHLOROPROPE:f?: I , u__ I '
~ 1,1.l.l·TETRACHI.OROETBAl'fE
I 1,1,2-TRICBLOROETBA.lf!: ' / frace... ' I/
2-R!::%.Al'l'OKE JO ' I I , Jf jl/
I Trr1lACHI..OROE'TlIE?B 5 3'o(i, -I-race.-7
DIBROIIOCHLOROKETHA1f?: I ' I ' LL
I ETHTI.r.n; DIBROMIDE J/ ,/ /
CHLORO~ I I fra.c,e_
1.1.1.2-Tl:nt.ACHl.OR.O!:TB'.Nr!: LL LL.. ' /
ETHYL BEff:ZZKE ,;i:31 t--rn c.e.. ;;), '7
:nu:,r,:s It 11.D tfJ JJ.5
"""""" ' I /1 LA-1
BROKOFOR.K /0
TRA!ffl..1,4-DICHLORO-'l.-Bl1T'EffE io
1,2,~TIUCHLOROPROPAZ'(E -5 ·, /
• 1,4--DICBLOROBE~ ;;).O ' 'I ' I/
1,2-DICHLOROBE~ • I 51 -J..vcue.. +ra.Le.-
1,2-DIBROMO--S--CKI.OROPROPANE ,;lE> lL-U-LL
VINYL AJ:r!ATE ;;uJO J/ ,I/
M~fhu/.+-b•J. / " 5 . / ,I; \ / s +rQLP ' /
I
...
Jl~rl.-"c~,.J.o~::,
1
!' (!JIG (-) {f) 8 (r) (+)
5ub:,h'fufed ben-zpne·
I C • pc,,;,.,eLE. 1-f\0 Cc>JnltJ.t>-lATl<>N c,R BAciac,-Rou"1D.
J -Satimated value .
IC -J.c:tual valu• ia known to be le•• than valu• given.
L -J.c:tual value ia kc.own to ba greater than valu• given.
I U -Material was ana.ly:ed for but not detect■d. The numbar ia tho Minimum. :0.tact:ion Limit ..
D. -Hot analy:ed.
1/ -Tentative identification.
2/ -COMl'Olli-!Dc 5'ELIP.6LY oe-recrooLE Cl\lLY //J t-116-H (OtJ(€NT1<ATJorJ5,
V·SA/\-IPLI:'. H16-HLY 1)1Ll.tTED, f,,IDLLo t>o ~ APPLY, g DEHNR 3068-0 (10/93)
9wlt.51
CCJ•Jl.o
( ,3)
V,,pb)ppm
I I
·, I
PURGCOM.ORG
'' --I srATE LABORATORY OF PUBLIC HEALTH
PO BOX 28047 -306 N. WILMINGTON sr •• RAIEIGH. NC 27611
I ORGANIC CHEMICAL ANALYSIS
l'URGJ::Allu: COMPOUNDS LAB NO • C/w I I 51.c cu..oll5B
FIELD NO c.o-,ct Co -(}.;;)..
I COMPOUND TTI'E ( 3) ( '-I )
M~~5 I/ ~b' (""b ppb pprn pprr1.
I CHLOROMETHA....-Z: JO / j . 1
VL'fTL CHLORIDE IQ
I BROMOIIETHAl'fE ;;;__O
CHLOROETHAN!: JO
I TRlCHLOROn.:uOROM?;'TIL\l'f?: JO
ACETO!<E ;10
I
1.1-DICBLORO~m; 5
JODOIIEt"HAl'O!: , / ·, r
Jiillt'THTU;:B CHLORIDE J J',C.. 3::r,c..
I CARBO?!' DISUU'1DE I ' 1 '
TllAff&-1,2-D ICm.QRO ~ff . /
I ACRTLOirmm.>: ;;}.D •/
5 +race.. 1,1-DICBLORO!:THAKE
2--BOTAl'l'Ol'l'E :l.D ' '
CIS-l~DICHLOROtrHE?n! 5
CHLOROFOR.K
1.1.l·TIUCHLOROETBAl'l'E
CARBO?f TrrRACHLORIDE
=m:
1.2-DICBl.ORO!:'I'HAl'fZ ' I.
I TKICHLOROr:TJ!.BfE +rnrp
1.2-DICBLOROPROPAJB I '
I BROIIODICHl.OROHETHAN'!; . , ' v },
B
I C-.Po,,,,,e._.. LAEi U>NTl'\"11t1Rnol\J oR BAcJ::.6-Rcul'JD.
J -E ■timated value
JC -Actua.l v&lu• i

■

Jcnown to b• 111■■ than value given..
L -Actual Ta.lue i

■

known to be greater than valu• siiven.
qlRIIIJD
co-,;i.5
( .::2.)
"ppbJpprn
l l
' I
4 :r,c..
LL-
,
'
., 7
l'.l(c I 14'~ 9 Co I I iDLf
co-,,29 C0-3/
( + ) ( ,;;J.-)
/p p b ;p p rr. /ppb ppm
LL LL
' I
+race...
L.L.
;i. :s,c..
LL
I'/
,:r
I I
,[/
f-(llN".
LL
1-::r
u_ -"/ ' I/
U -Ka.terial wa■ an.a.ly:i::ed for but not dot ■ct■d. 'l'h• number i• the Minil:mm. Detection Limit.
J5l1 -Sot analy:z:ed. II 1/ -'l'■ntativ• identification. U ~/ -C.O""Po-.!'lo _RU-lf\BL'f ·OEH:cr,r0L£ o>JLY IN H l(rt-l (O/'JCCNTRATICN'5,
✓-SAMPLC 1-\l&HL'/ QILl<TED. ~DL'" Do NOT APf'L.'{.
I DEHNR 3065-0 (10/93)
qloll(o(o
Ca-3f
( if )
,:opb 1-1?iT1
I J . I
'/
I -:s,c...
J
' I
+race__
IJ
' I
PORGCOM.ORG
srATE LABORATORY OF PUBLIC HEALTH I
I PO BOX 28047 -306 N. WILMINGTON sr., RALEIGH, NC 27611
ORGANIC CHEMICAL ANALYSIS
r PURGEABLE COMPOUNDS LAB NO q Co II 5 Cc, q(ol(50
FIELD NO CO-IC/ Co-;J..:;)...
t (3) ( 4-) I COMPOUND TYPE
I
tff.5 ,;.,Db )ppm "ppb) f' p111
omROMOH.!:l"BA!fE 5 I I l,L_
4--METB'TL-2-P?::NTANONE ,o
I Cts-1.3-DICHLOROPROnNE 5
TOLUE?fE
I TRAI'IS-1.3--DJCHLOROPR.On~
1,1.l,l-n:nt.ACHLOROr:TRAl'fl:
I l, 1,2--TIUCHl.OROETHA. 'fl: ' /
2-Bz:xMQ!(l; JO ' I
I T7:I'RACBLOROETHltzm 5 1::r
DIBR0U.OCHLOR0wrrBA.."R: LL
I ETBTI.Z1n: DmROMIDE
cm.oROBr.fZ!:l'B
1,1,1.2--TETRACHLOR.OnHA:B
I ETHYL BDIZE?fE
=-
STTIU:l<E -/1
BROKOJ'OR.11 JO
TRAl'fS-1.4-DICHLOR0-2-BtJ'IZ?n; io
1,l,3-TlUCHI.OR0PROPA1l£ 5
I 1,4--DICHLOROBEKZXN'E
1.2-DICHLOROBE?fZ&"f?; . I;
.J 1,2-DtBROMO-~HLOR.OPR.OPA,?0; ,!)_e)
. VINYL ACETATE ;;,..c;o
,-lefh,_,/-t-bu-1-.,J efhe, 5 I
-/
' il
I Hydroc.a rbon::5 I:'. ®/€) (D~~~ A
oub6h'+t.ifed benu, l,5
I C • po,;,o,eLE. L-F\S CCNTl'\IJ.1"1AT\Or,l oR 'BfKl<(rKOUMD,
J -Eatimat■d value
Jt -l.ctual value i

■

>en.own to be le•• than value given.
L -Actual value i• mown to b• greater than value given.
96> 11 lll 0
Co -.;1.5
( ,;l.. l
(iipfi)pprn
I I
/ ' I :r
I •
. ,
tt!o.re. v
, I
,7
B
9(JJ/ {6,_.2 9CD I I &,'f
co-;J..6 co -3 /
( if l ( ,2 )
(pPb ppm (fpb'f)pm
I LL
'\ I . /
I :r +rnrP
LA-/ J
· I/ ' I
C-J e
I l1 -llatoria1 was anal~od tor but not detected. Th• number i• the Minimum. Detection Limit. •
?D. -l!iJot &llAlyzod.
1/ -~ontative idontitication.
11 -CCMl'OIUJO, REL.tP.eL.y 0€1f'Cf'.ffi3LE ClllL'( IN HIG-H coNC£NTRATiON5.
,/ -SA/llPLc H16-H LY 1)1 LuTEo, ,'l DL'o llo Jllaf" APPL'/. I DEHNR 8068-0 (10/93)
(0
q(D 1/(JJ&
co~.3+
( if l
;ppl:i ppm
l,L,
' I
+rne,:,
I ,
' I
(-
PURGCOM.ORG
----I STATE I.ABORATORY OF PUBLIC HEALTH
PO BOX 28047 -306 N. WILMINGTON ST., RALEIGH. NC 27611
I ORGANIC CHEMICAL ANALYSIS
PURGEABu: COMPOUMJS LAB NO Cl li> 11 lo B
FIELD NO lo-37
COMPOUND TYPE C 1-/, l ( l ( l ( l ( l
I M ~:,S5 ,,ppb)ppm ~b)pprr. fppb)pprn f?pti}pprr: fpb)ppm (110b
I CHLOROMETHAN!: JO L-L-
VINTI. CHLORIDJI; 10
I BROMOIIETB.A1B d.0
Clll.OROETHANE 10
JO ' i
I TRICHLOROFUl'OROJO:rHA,."fE
ACETO In< ;;}_Q 3 :r,c..
I
1.1-DICHI.OROETBE?R; 5 U-
IOOOJ0;'1'HAN'E
JD:I'HYIZ:B cm.oRIDE
I CARBON DISUUID!;
TRAl'fS..-1.l•DICHLOROr:n!L'f!: ,i
I ACK!Ullffl'RIU: ;;;!.D
5 1.1-DICHLORO&THAl'l'E
I :1-BUTA!'l'Ol'IE :l..D
CS-1.2--DICHLOROrT'Hl:NE 5
I CHLOROFORK
1.1.l•TIUCHI.OROaHAJrE
CARBOl'f n:T'RACHLORIDE
BElTZE1B
1,:1-DICBLOROeTRAlrl:
TRICHI.OROE'I'B.cl"E
1.2-DICHLOROPROPAJB
BROIIODICHLOROIIE"rB.Ala ' I \ /
I
-C .poo,,,,, ..... LAB =""'"''"""nolJ CR BACl:.u-Rcu"-lD.
J -E■tima.ted va.l.u•
X -Actual valu■ i• known to b• l••• than value given.
L -Actual Ta.1u■ i• known to be greater than value given. I
O' -Kat■rial waa analy:■d tor but 110t detected. 'l'h• number
l!D. -Sot a.naly.■d. I 1/ -T■ntativ• identification.
I.1 -c:ai'\!'01.u,ip Ra.lf\BL'f·OETl,crl'leU:: o>JLY 1N H1er1-1
V-SA>IPL1" Hl&HI..'/ 01~u.T5D. MDL'~ Do NOT APPL'(. R DEHNR 3065-0 (10/93)
i

■

th■ M!J:u:zmm t>et ■ction Lim.it.
C.oNC£NTl<AlloN5,
( l
(ppb )~-pm
PORGCOM.ORG
I
I
I
f
I
' ' .
PURGEABU: COMPOUNDS
COMPOUJVD
STATE LABORATORY OF PUBLIC HEALTH
PO BOX 28047 ~ 306 N. WILMINGTON ST •• RALEIGH. NC 27611
ORGANIC CHEMICAL ANALYSIS
LAB NO qwl /lc,f,
FIELD NO co-37
TYPE ( '+ ) ( ) ( ) ( ) ( )
rr,~rt V ppb ppb ppm ppb fPb ppm
I
ppb ppm pp1t1 ppm
DrBROMO~ 5 I I
4-M'.ETHTI.-2-nNTANONE ,o
I CIS--1,3-DICHLOROPRQP!;NE 5
TOLtlL'l'E
I TRA.rrS-1,.3-DlCHLOROPROP!!N?:
1.1.:1.2· T'ETRACHLOROETBNfE
I 1.1.~ TRICBLOROETHA.."fl: ' I/
l,-H?;XA11QN'E JO
I Tl:tR.ACm.ORO!:TB::ER 5
DIBROMOCHL0ROKET'B,\l'1;
I ~ DIBROMIDE
cm.oROBEl"IZElm
1.1.1.2-T'rI'RACHLORO?:THNfE
I ETRTL Bl!21':ZZK!:
=-
I = ' I
BROIIOJ'ORJI JO
TR.AffS.,1,4-DICHLORO-l-BtJT?;l'fE io
1,2,~TJUCHLOROPROPAl'IE !5
I 1.4-D1CHI.OROBE1'JZX?B
1.2-DICHLOROBENZz:N?; ' I
J
1,2-0IBROMO-:,..CHLOROPR.OPANE ,;i_t)
VINTLACZ;TATE ;00
M.e+lu./-t-bt.tlv/ e.-fher 5 ,/
I llydrocarhon:5 ,, -. c-) ' ', __ ,n-'J
6ub5fitlt/tQ b<'/JZHIJ I
I C -po,;,-,el.E I-R6 CoNU=\MIJ..lATI0l\l aR BRCI-G-KOUIJI).
J -Eati.m.at■d value
JC -J.ctual va.lu• i• Jcnown to b• l••• th.an value givan.
L -Actual valu• i

■

known to b• 11r■atar than valu■ given.
-
U -Material was ana.ly:::r:ed for but not d■t ■ct ■d. Th• number i■ th• Mi.nimum Dat•~i011 Lim.it.
D ?D. -Sot ana.lped.
1/ -Tentative identification.
""i_t -COMPol.li,!O-RELIP.6LY 0f:tf:Cf'.ffi:,LE tl<JLY JN t-llG-H cor-JCtNTRAT/olJ.:;,
,/-SAMPLE: H16-HLY l)ILI.J.TED. MDL'o l)o J\x7i APPL.'/. B DEHNR 3068-0 (10/93)
( l
ppb ppm
PURGCOM.ORG
• ,• I •
STATE .LABORATORY OF PUBLIC HEALTH I
I P.O. BOX 28047 -306 N .. WILHINGTON, ST., RALEIGH, N.C. 27611
ORGANIC CHEHICAL ANALYSIS
BASE/NEUTRAL AND ACID LAB NO q/,,//t./\ Q/,1//fl-•, <-I lo I /'-P1 Cfl.i I I"> I
EXTRACTABLES FIELD# ..::J /lo-S-co-.,, e.o-J r
COMPOUND TYPE ( ,J) ( .? ) ( ..':l 1 ( 31
UNITS ·m>M ua/kq ._,/ j/kQ) rura un/kq' ut!Qua/ka
Jnitrosodimethvlamine /fl/;;,~,. I -I,( -IA -I A--
s (2-eh loroethvl l ether
-chlor=henol
henol I 3-dichlorobenzene
4-dichlorobenzene
1 2-dichlorobenzene I s<2-ehloroi .,\)ether
•xach loroethane
N-nitroso-di-n-nroovlamine
~obenzene
horone
-nitrnnhenol
2 4-dimethvlohenol
Is (2-eh 1 oroethoxvlmethane
4-dichloroohenol / I
1 2.4 trichlorobenzene ' ' I
hthalene /.I . ,, I 1./() 0
xachlorobutadiene IA.-i,<.-
4-ehloro-m-cresol
xachlorocvcl"""ntadiene
4 6-trichloroohenol /
-ehloronaohthalene '
acenanhthvlene -< of
limethvl ohthalate I ,.,
6-dinitrotoluene " L,t.-
acenaohthene ,:3c,ic ~:?Ok'."
4-dinitr=henol S0//t,,50 (/1..-(A_.
,.4-dinitrotoluene /l'tl '1'10 I I I
4-nit~henol S"O/Jt..i:o ' ! 1 uorene I0/~30 -/' OK --s ()I::
-ehlo~henvlohenvlether 1~ (..,1.....,
iethvl ohthalate "' 4,6-dinitro--O-Cresol 'rO •u ~,-,
iohenvlamine /01330
zobenzene
4--braroohenvlohenvlether
exachlorobenzene , I ,
ntach lornnheno 1 .SOll&.S"O ' '
ohenanthrene IA/ ,~ ~~-/,L, t,·, 5". , -s
nthracene I '? 2~,.. Ut. ·1 I ibutvl nhthalate . I J,/.3 / 1,/4-
luoranthene , ~.l.oo I y ',OD
m1)L . ,
I -Estimated value. H,.o/sou ...
-Actual value is known to be less than value given.
L -Actual value is known to be greater than value given.
C/~/1.5 ~.
,10-111
( ~ 1
iw, .. n/ka'
l -
/
'3::>,n V
IA...-
/
' -1 ~n IC
IA-
v-
~ ➔nl:::
1.,,(--,
' -s ,olL
IA.-
/
I
J ~ -~~
't .,.-,
In I aC, I
Jr.. non ,
-Haterial was analyzed for but not detected. The nurber
-Not analyzed.
is the 11ininun Detection Limit. m"JJL -----Tentative identification.
_ -On NRDC List of Priority Pollutants.
I
CD
'j'{pl /-. --,
[10-/ 7
( ~\ .. "n/ka)
" -
, .
=:l AV
-

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'i::: Qic
IA---
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' -1. iLJ{
2/,1/ ~-
v<--+, n"I ·~ ,
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STATE LABORATORY Of PUBLIC HEALTH
P.O. BOX 28047 -306 N. WILMINGTON, ST., RALEIGH, N.C. 27611
ORGANIC CHEMICAL ANALYSIS
BASE/NEUTRAL ANO ACIO LAB~ Cl/A I I ,I., l,//n 1 / lL '7 Q/,.1/il.y u,.,, ..,-1
EXTRACT ABLES F!ELO # _-, r'l""l-, r'O o· /7 ~ ./ /
aJl1POONO TYPE ( ~' ( '31 (J) (31
UNITS 1-~ua/ka :: ,;;·/kn .. , /kn h · '" .. n/ko 7
•"Tl'ff1'::'l'I
nvrene /0/~=in J ,., 0 -4 -<f I --,JJ_~ ....
benzidine I <n l,1.<o -, IA vL.
butvl benzvl nhthalate 101.=i=io Q' nOO v<--
benz(a)anthracene vL-.:;., 1.r.7
chr\lsene .I, ,;? -i_/,, I ,£2:.'-S
3. 3-di ch lorobenz i dine so/1,:,,,;n 'V-, "
bis(2-ethvlhexv1'0 hthalate 10/?30 ..;>o '..(.,,, Cl \-UV
di-n-octvl nhthalate 10/.J~o 7 ,lj -~-:.: '7 1/4-
benzo(blfluoranthene So'·· ,, , -~ , ,, "7 c.;7.7.:i~
benzo(klfluoranthene , IA_ .',
benzo(a l nvrene 3.t S"V ""'· •oo
indeno( 1 2 3-cdl0 --rene ,.'700 < . ':? 3
dibenzo(a h)anthracene / , 1,,(.-/ -"' •,:2,~
benzo(a h i1=rvlene ' I/ '-1. / Cl,~ '\ I ~: <'.)0 , ,
aniline <a/,, II.. Ill. -vL-I -VL-
benzoic acid
benzvl alcohol , /
4-ch 1 oroan i 1 i ne .. , \ I ~
dibenzofuran I" /'7-'ln ~~ol:::'. ~, oK..
2-<rethvln•nhthalene .., x'-11 I " IA7
2-<rethvlnhenol , ' J I
4-<rethvlohenol ~•,.
2-nitroaniline S'o/1 1-<o
3-ni troani 1 ine
4-nitroani 1 ine / , . ,
2 4.5-trichloroohenol \/ I " "I / '/ ' I
----
1-J V /\POC, /1/' ~ OLJ_<, . ..J-I (-) { +-1 (-} ( --,-J
'
m1)L
J -Estimated value. H2.0/ Seit.
K -Actual value is known to be less than value given.
-Tfnl/">. <
l'o-/U
( --S l
-L·~ • /ka ..,,_2.,,,:..,:
,',
130,1.1., ', /t.nQO
'vt--
Fl/J~ ~2;,i;
I; __.
1 Bo, ooD
'l,C
/.J.J l.(p 7 ,,,,o 1.& 7
.:1, :i 3 -~
1:2-.' "1J,11
t,A.-
,
' -s z DY
-::i-:v,t::
I
I
' .,........,.
( ..J-)
l -Actual value is known to be greater than value given.
U -llaterial was analyzed for but not detected. The numer is the MinimJTI Detection Limit. ~
NA -Not analyzed.
1/ -TenWtive identification.
~/ -On NROC List of Priority Pollutants.
C//4//'-<'
PO-J, ,--3,
-~ /kn""\
~000
,· I • -
l-'---
/ • f'57)
t •. ,z~
'I,,<-
JC/.'->-<'4
I,<-,c::r z-<-<
UL-i,). ,, "';[ :;;;: -;,4 1.1.7 ,, ,
..:J 1,2..00 ,
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~
STATE LABORATORY OF PUBLIC HEALTH I
I P.O. BOX 28047 -306 N. _WILMINGTON, ST,, RALEIGH, N,C, 27611
ORGANIC CHEMICAL ANALYSIS
BASE/NEUTRAL AND ACID LAB NO ,q1~11_.c;·/ Cf I,, I l "i '-f
EXTRACT ABLES FIELD# l"o-?.l'J t"'rJ -2-. -;.i
aJl1POUND TYPE ( cs) ( l/)
UNITS ~;;-a/ka' ,= ,oa/ko
'nitrosodimethvlamine /0/ ..... ,, IA-l-t__
s(2-chloroethvllether
i -ch l orrviheno 1
henol I 3-<li ch lorobenzene
4-<lichlorobenzene
1 2-<lichlorobenzene
lt(2-chloroisonrnnvl )ether
xach loroethane
N-nitroso-<li-n..,..roovlamine
1 itrobenzene
l<00horone
-nitrt'Y"lhenol
2 4-<limethvlohenol
fis(2-chloroethoxvlmethane
4-<lichloroohenol I
1.2.4-trichlorobenzene ' hthalene :}-QK._ •
exachlorobutadiene uL--
4-chloro-m-cresol
~ exachlorocvcl,..,,,ntadiene
,.4 6-trichloroohenol I
-chloron>nhthalene '
acenanhthvlene ~-() ,::_
limethvl ohthalate A~
6-<linitrotoluene
acenaohthene ,
4-<li ni t~heno 1 SO//~<io
4-<linitrotoluene /1'113.'IO
4-nit~henol <"O I, ,_,:o
I 1 uorene /0/ '1:?0
-chlo~henvlohenvlether
iethvl ohthalate ,,
4 6-<linitro...o-cresol 11,,5"0 .<iOI
iohenvlamine /(J/330
zobenzene
4-bron-oohenvlohenvlether
exachlorobenzene ~ I
ntachloroohenol .SO/Jt,,:fO "
ohenanthrene //7/ ?30 73D,c
I nthracene -s~oi:::.
ibutvl ohthalate l.,A-I
luoranthene ' i, 7nn ' ml)L
11, -Estimated value. fl,.o/SOIL. ~ -Actual value is known to be less than value given.
L -Actual value is known to be greater than value given.
("//4///2 I
{',o-li,,
( ..;z_)
11d11'-·-
(A-
/
' I
Cf/,, I I IA CC{
,r'o-z.q
(i.f-l
1llmtua/ko
IA
/
'
'7"h/ll~,
/7(')-=?..1
(_i,I, )
uo/ l " ~·
L/4-
/
\
-llaterial was analyzed for but not detected. The nUTDer
-Not analyzed.
is the Hininun Detection Limit. m'])L -----Tentative identification.
_ -On NRIJC List of Priority Pollutants.
I
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,r'o-~....-
( t.J..,
. rn,,i.V .. n/ka)
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BASE/NEUTRAL AND ACID
EXTRACT ABLES
OJMPOUND
nvrene
benzidine
butvl benzvl ohthalate
benz(a)anthracene
chrvsene
3 .3-dich lorobenzidi ne
bis(2-ethvlhexvllnhthalate
di-n-octvl nhthalate
benzo(blfluoranthene
benzofklfluoranthene
benzo(a\nvrene
i ndeno ( 1 2 3-<:dl ""rene
dibenzo(a.h)anthracene
benzo(n h. i ).....,,rvlene
aniline
benzoic acid
benzvl alcohol
4-<:h 1 oroan i 1 i ne
dibenzofuran
2-rrethvlnaohthalene
2-rrethvlnhenol
4-ffl!thvlohenol
2-nitroa.ni 1 ine
3-nitroa.niline
4-nitroani line
2. 4 5-tri ch lorooheno l
1-t 'f', /) y 0( ~ -,,-;: • ) ',
STATE LABORATORY OF PUBLIC HEALTH
P.O. BOX 28047 -306 N. WlLMlNGTON, ST., RALEIGH, N.C. 21611
ORGANIC CHEMICAL ANALYSIS
LAB NO '-1/4 J/~'7 Cl(pf/ r-, q/4///,,/ ~·-f
FIELD# r"o-? ,, r· e7-,,l ~ ~0-7 1,,, o-J-'-f
TYPE ( ~) r '-1. l ( .-.!) ( Y. l
UNITS _·-.J..,J I ---/kn •-n.LIA,o/kn) v;,n/1'..~n .-...v.·-/kol
/0/~'<l'I I Irv"\ ~ , A-,;;
,n /11.<o , ,t .
101.:r'?o
I . I
SOI /£,, ,;r, '
io1 ?3o _.,_ I 3 ~
IO/.s~o 'LA-
S'O ,.,.r~ /, '100
u<-
3.21 7
,:;' ? l,,"7
, (../4.... / / I
' l'7 if:;(;;;!, '
I
<o ,. u..-iA---1 A _ IA-
.. ,
10/zu,
I
,,.
S'o"1-,:;o
I I , I
\/ • ' ' ' -~ ---
-r/ r _J,, J ( J r-; ( -} -
m1H ..
J -Estimated value. H;;,.OI Scl'-
K -Actual value is known to be less than value given.
'l'h//h"
l'O-::Z..:i
(__J)
un/ l 1,""1ul
(,,(_...
,
' /01--'
l/--
,
'
LA-
.
,
' -
r-J
l -Actual value is known to be greater than value given. U -Material was analyzed for but not detected. The nurber 1s the Minil1lJI\ Detection Limit. ~
NA -Not analyzed.
1/ -Tentative identification.
~I -On NROC List of Priority Pollutants.
,,, . 7
C'o--:-,_-
r ~'
~,I' ·/k,;,.
u--
1
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CA_.-
' 7 --
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I N.C;'.'Jcp::inmCnt of Environment,
! lc:.ilth, & Natural Rc.soun.:cs
Solid WastC Minagcmcnt Di\,;sion
State Laboratory of Public Health
i'.O. Box 2S(}t7, 306 N. Wilmington Street
Raleigh, North Carolina 27611
I Site Number A/Cl> '1&; ?"!"! OIC/ Field Sam plef\fJibtr_2_19_9_6-"'tJ.,_/.,_?""'"6_,q-__,B,c__ _____ _
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Name of Site C:/4urok,e. tJ,i' CoAfDa,t V ~I
Site L~J~\./1?,\:.~~J)~Jt,, Rd;, fAi!frlc fl<.,, Ne..
Collected By -p. M..,,u-JD# ____ Date Collected ,'1/~rcl-, /'iJ1 t91t:,
Agency:, Hazardous Waste Solid Waste _c__Superfund TCLP Compounds
------
Sample Type Inorganic Compounds Rcsults(mg/1)
Environmental Concentrate Comments Arsenic --Barium --co-oo'f -sw __ Ground water (1) _ Solid (5) . Cadmium --Chromium --L Surface water (2) _ Liquid (6) Lead --__ Mercury
Soil (3) _ Sludge (7) Selenium ---Silver --
_ Other (4) _ Other (8)
--
--
Organic Chemistry Inorganic Chemistry --
Parumctcr Rcsults(mg/1) Parameter Results(mg/1) (mg/kg) Organic Compounds Results (rrrg/1)
✓r&T:GC/MS Arsenic benzene ----
Acid:B/N Ext. Barium carbon tetrachloride ------
MTBE Cadmium chlordane ------Chloride chlorobcnzcnc ------Chromium chloroform ------
--__ Copper o-cresol --Fluoride rn-crcsol ------Iron __ p-crcsol ----Lead crcsol ------
--__ Manganese --1,4-dichlorobcnzene
--__ Mercury __ 1,2-dichloroethanc
Nitrate __ 1,1-dichloroethylcnc ----Selenium 2,4-dinitrololuenc --Silver __ heplachlor --Radiochemistry Sulfates hexachlorobenzcnc ; ----
···--Zinc hcxachlorobutadicnc · ----
Parameter Results (PCi/1) _pH hcxachloroclhanc --
--Gross Alpha __ Conductivity __ methyl ethyl ketone
Gross Beta TDS nitrobcnzcnc ------TOC __ pentachlorophenol --__ pyridine --Microbiology --__ tetrachloroethylene
__ trichloroethylenc --
Parameter Results (Col/100111!) __ 2,4,5-trichlorophcnol --_._2,4,6-trichlorophenol ----__ vinyl chloride ----cndrin --
Report~) /} //1,/r/ ,t 7 lindane
Date Received 5-/1:/_-'j_{,_,b, __ mcthoxychlor ,, loxaphcne
Dale Rc~d t/-tJI---
Date Extracted ?~ 2,4-D --
3-;;t) -'Ho "111..u 961328
2,4,5-TP (Sil·,cx)
Date Analyzed Lab Number ~u12e,-'16 Zr 5?
nil<..: 111)1 /11,·vic,·rt ?/!/1\
Purpose: Enforcement and compliance with the N.C. Solid and Hazardous \Va~te Mar:iagcmenL Rules.
Preparation: A sample analyses request form must be completed for each type of evaluation requested (e.g., inorganic,
organic, microbiology) radiochemistry). For .sampling conditions which require more than one (1) container'
(i.e., ground or surfacc·water) _a sample label must be affixed to one pf the containe,s,,.The c~llector must
then write the site and .sample number on the duplicate container. · · ·· · · ··
'. . ' ~ .. .,
Do not submit an analysis request form without any parameters indicatCd:
'
Equivalent measurements: ppm = 11g/ml = mg/I = µg/g = mg/kg
ppb = /lg/I = 11g/1000g = /lg/kg
DEFINITIONS/INSTRUCTIONS
Site Number -A unique twelve-digit site/location identifier (i.e., the EPA identification number).
Field Sample Number -A unique six-digit sample identifier which·is pre-printed on the sample label.
Name of Site -Name of facility, landfill, etc.
Site Locution -City and county.
Collected By -Name and staff identification number of collector.
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Date and Time Collected -Self-explanatory. I
Environmental - A sample of a naturally occurring substance such as ground water, surface water, or soils which may 1 be contaminated.
Concentrate - A sample of a waste, including but not limited to, sludges, resins, treatment cfOuents, or drummCd
wastes.
Comments Lists details ·regarding sample or sample point (e.g., sample location, well number, phase separation,
and/or odors.
Inorganic Chemistry -Check ( ✓ ) the desired parameters lo be analyzed. If not listed, enter the
clement/compound in the space pro,,dcd.
Organic Chemistry Check ( / ) the desired parameters to be analyzed. If not listed, enter the
clement/compound in the space provided.
TCLP Compounds Check ·c ✓ ) the desired parameters to be analyzed. If nol listed, enter the
element/compound in the space l"o,,ded. TCLP can only be performed on solid or semi-
solid samples. For totals of the inorganic parameters, check ( ✓ ) the corresponding
parameter under Inorganic Chemistry.
Microbiology and Radiochemistry -Contact the Raleigh office prior to sampling either of these.
Distribution:
Disposition:·
1. Send or deliver the original to the Stale Laboratory of Public Health.
.2. The Lab then sends a copy (with results) to the Solid Waste Management Division.
3. The Solid Waste Management Division sends a copy lo the field person or collector.
This form may be destroyed in accordance with the Environmental Health, Solid and Hazardous Waste
Section of the Records Disposition.Schedule as published by the North Carolina Division of Archives and
History
Additional forms may be ordered from: Solid \Vastc Management Division
Hazardous Waste Section
P.O. Box 27687
Raleigh, NC 27611
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N.C-., Dcp:.irtr,'1cnt of Environment,
lic.ilth, & Natura! Resources
Solid WastC Management Division
·SAMPLE ANALYSIS REQUEST State 1-"bonHo')' of l'obli, ll'"lth
P.O. Box 28047, 306 N. Wilminr,1on Str~ct
', Ralci&,h,.North Carolina 27611
, . ~ • , ! '"I.
!' ' /
FieldSampleNumber,.,. Olt/~,?-1 · .. Sile Number /..IC.]) 9&; 7'7'"f 0/'j
Name of Site C/2urok,e. CJ,'/ {o,.,p,z,,v ~;
. -. . . -. ·' ,.
Site Location /20/ l3uryl.1"// JQ.d.,
'. ' . ,
Collected By' p. M...,.e.£ JD# Time /K:;J.3
Agency: Hazardous Waste Solid Waste _c_Superfund TCLP Compounds
------
Sample Type Inorganic Compounds Rcsulls(mg/1)
Environmental Concentrate Comments Arsenic --Barium
Co-oo'I -s ,v --
Ground water (1) _Solid (5) Cadmium
----Chromium --
Surface water (2) " _ Liquid (6) Lead
----
--Mercury
_ Soil (3) _ Sludge (7) Selenium --Silver --
_ Other (4) _ Other (8) --
--
--
Organic Chemistry Inorganic Chemistry --
Parnmctcr Rcsulls(mg/1) Parameter Rcsults(mg/1) (mg/kg) Organic Compounds Rcsults(mg/1)
P&T:GC/MS Arsenic . benzene
✓ Acid:B/N Ext. ----
Barium carbon tetrachloride ----
MTBE Cadmium chlordane ------Chloride chlorobcnzcnc ------Chromium chloroform ------
--__ Copper o-cresol --Fluoride m~crcsol ------
--Iron p-cresol ----
Lead . crcsol ------
----Manganese --1,4-dichlorobenzene
----Mercury 1,2-dichloroet bane
--Nitrate --i,1-dichloroethylenc
----
Selenium 2, 4-dinitrotol uene ----Silver heptachlor ----
Radiochemistry Sulfates hexachlorobenzcne ----
···--·-Zinc hcxach lorobu t adicnc ----
Parameter Results (PCi/1) --pH hcxachlorocthane
--Gross Alpha --Conductivity __ methyl ethyl ketone
Gross Beta TDS nitrobcnzcnc ------
TOC pentachlorophenol ----
----pyridine
Microbiology ----tctrachloroethylenc
trichloroethy(cne ----
Parameter Results (Col/lOOml) __ 2,4,5-trichlorophcnol --
----_._2,4,6-trichlorophcnol
----vinyl chloride --cndrin --lindanc
Date Received "'3 -(.!f_ -i'G/42 Reported by __ mcthoxychlor
toxnphcnc --
D,tte Extracted "<-16-q(o SI>. Dale Rcporlcd
9610~9
2,4-J)
Dale An,tlyccd J-){p-9& {3[)
__ 2,'i,5-TP (Sil·,ex)
Lab Number --
Purpose:_
Prcparatiofl:·
Enforcement and compliance \\~th the N.C. Solid and 1-Iazarciou~ \Va~tc Management Rules. .
A -~~rriple analys~s request·form must be completed for each type of evaluation r~qucstc'.<l ie:g,; 'i,i~rga·~:-~t:, .. , I
organic, micr~biology, radiochemistry). For sampling conditions which require more th~~ ·oq·t(i/'20ni'aiil'~r· .,·:,.
(i.e., ground or_ surface water) a sample label must _be affixed to one of the conta)ners,:.:'fh~ c~llcct?r _m_~l ..•
then write the site an<l sample number on the duplicate contamcr. · .-•·. ·.• .. __
•• >; ··,.\"•. • •• ·.,.
Do· not submit an an.alysis req~~sl form \\ithoul any parameters indicated.'· .. · ··. \ --···
Equivalent measurements: ppm = pg/ml = mg/I ~ pg/g = mg/kg
ppb = pg/1 = pg/IOOOg = pg/kg
DEFINITIONS/INSTRUCTIONS
Site Number -A unique twelv_e-digit site/location identifier (i.e., the EPA identification number).
Field Sample Number - A ~niquc six-digit sample identir,er i<hi~h is' pre-printed on the sample label.
Name of Site -Name of facility, landfill, etc.
Site Location • City and county.
Collected Tiy -Name and staff identification number of collector.
Date and Time Collected . Self-explanatory.
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Environmental -A sample of a naturally occurring substance such as ground water, surface water, or soils which may 1.
be contamipated. ,.
Concentrate -A sample of a waslc, including but not limited to, sludges, resins, treatment efnucnts, or dru"inincd
wastes. m.'.:
Comments Lists details regarding sample or sample point (e.g., sample location, well number, phase separation, '
and/or odors. . . ~-m--
Inorganic Chemistry -Check ( ✓ ) the desired parameters to be analyzed. If not listed, enter the·
clement/compound in the space prmidcd.
Organic Chemistry Check ( / ) the desired parameters to be analyzed. If not listed, enter the
element/compound in the space provided.
TCLP Compounds Check ( ✓ ) the desired parameters lo be analyzed. If not listed, enter the
clement/compound in the space provided. TCLP can only be performed on solid or semi-
solid sam pies. For totals of the inorganic parameters, check ( ✓ ) the corresponding
paramcler under Inorganic Chemistry.
Microbiology and Radiochemistry• Contact the Raleigh office prior to sampling either of these.
Distribution:
Disp_osition:
1. Send or deliver the original lo the Stale Laboratory of Public Health.
2. The Lab then sends a copy (with results) to the Solid Waste Management Division.
3. The Solid Waste Management Division sends a copy to the field person or collector.
This form may be destroyed in accordance with the Environmental Health, Solid and Haz.ardous Waste
Section of the Records Disposition Schedule as published by the North Carolina Division of Archives and
History
Additional rorrns may be ordered from: Solid \VJ.ste MJ.nagcmcnt Division
Hazardou~ \Vastc Section
P.O. Box 27687
Raleigh, NC 276_1 l . ,
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'R--es~ I,, plf ;i. ,,., / t : / I+ Cl,..
I N.~: Dcpart,\\Cnt o[ Environmcn,, SAMPLE ANALYSIS REQUEST
! !callh, & Natural Resources .
Solid WastC. Management D_ivision
Stale 1:.aboratory of Public 1-lcalth
P.O. Box 28(}17, 306 N. Wilmington Street·
Ralci&h, North Carolina 27611
"·.' • . . ' ., ,,/;j Jl."
' ; 'f ' :., ' • . • I Site Number . AICP·: 9&, 7"t"f 0/Cf ' Fie['d Sample-Number ___ __,,,O,_/,...'l-'--'6_5"_o __ , ,_,._,_·,_· ----
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Name of Site C/4u-okee. {),/ {o,.,1.>a,, v ~1
Collected By' 7J. M...,,e.e JD# Date Collected ,#11rcA n1, 19'?&.
. .
Agency: Hazardous Waste Solid Waste __c__Superfund TCLP Compounds
------
Sample Type Inorganic Compounds Rcsults(mg/1)
Environment~) Concentrate Comments Arsenic --Barium --CtJ-t!JOS -SIM __ Ground water (1) _Solid (5) Cadmium --Chromium --
.15__ Surface water (2) _ Liquid (6) Lead --Mercury --
Soil (3) _ Sludge (7) Selenium --. Silver --
_ Other (4) _ Other (8) .. --
--
--
Organic Chemistry Inorganic Chemistry --
Parameter Rcsults(mg/1) Parameter Results (mg/I) (mg/kg) Organic Compounds Rcsults(mg/1)
✓P&T:GC/MS Arsenic benzene ----
_ Acid:B/N Ext. Barium carbon tetrachloride ----
MTBE Cadmium chlordane ------Chloride chlorobcnzcnc ------Chromium chloroform ------
--__ Copper o-cresol --
Fluoride m-crcsol ------Iron p-crcsol ------Lead cresol ------
--__ Manganese --1,4-dichlorobenzene
--__ Mercury --1,2-dichloroethane
Nitrate __ 1,1-dichloroethylcne ----Selenium 2,4-di nit rolol ucnc --Silver __ heptachlor --
Radiochemistry Sulfates hcxachlorobcnzcnc ----
···---Zinc hcxachlorobutadicnc • ----Parameter Results (PCi/1) pH hexachlorocthane
__ Gross Alpha ----
__ Conductivity __ methyl ethyl ketone
Gross Beta TDS nilrobcnzcnc ------TOC __ pentachlorophcnol --__ pyridine --Microbiology --__ tctrachloroethylene
__ trichlorocthyfcnc --Parameter Results (Col/l00ml) __ 2,4,5-lrichlorophenol --
. _._2,4,6-trichlorophcnol ----__ vinyl chloride ----cndrin --lindanc --
Octtc Received ~ -LL/-··1C;_k!3 Reported by rncthoxychlor
' --1ox,1phcnc --
Date Extracted Date Reported 2;1-D --
3 iU _q (j! ,1,ur 961330 __ 2,4,5-TP (Sil·1cx)
Date Analyzed Lab Number --
Prcparatiorl:
Enforcement and compliance \\1th the N.C. Solid and Ha7.ardous W_aste Management Rules.
· A samp\e'analyses request form must be completed for each type of evaluation requested (c:g.; in~-rg:•~ic;·· :.,I
organic, microbiology1 radiochemistry). For sampling conditions which' rcquirC mor·c 'tha~ or}_e (i.) 'COnt"atne/ ·<..:,,
.(i.e., gro~nd ?r·surfacc water) :a sample label must be affixed to,one of the con_ta_iners:.''.·The coHcc_tor 111_uf .. 1
then wr.ite the site and sample number on the duplicate ~ontarncr. · .-· . •. ·. ,/ '.. · · ·
Do not submit an analysis request forn1 "1lhout any parameters in"dicatcd.
Equivalent measurements: ppm = µg/ml = mg/I ;, µg/g = mg/kg
ppb = pg/I = µg/lOOOg = 1ig/kg
DEFINITIONS/INSTRUCTIONS
Site Number -A unique twelve-digit site/location identifier (i.e., the EPA identification number).
Field Sample Number -A unique six-digit sample identific·r ·which· is pre-printed on the sample label.
Name of Site -Nam_e of facility, landtill, etc.
Site Locution -City and county.
Collected By -Name and staff identification number of collector.
Date and Time Collected -Self-expla11atory.
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Environmental -A sample ?_[ a naturally occurring substance such as ground water, surface water, or soils which may n··
be contaminated. .,.,. ·
Concentrate -A sample of a waste, incluc~ing but not limited to, sludges, resins, treatment cfOuents, or drurri._1:1cd • ..
wastes. U."
Comments Lists details regarding sample or sample point (e.g., sample location, well number, phase separation, · '·
and/or odors. ··· g·.
Inorganic Chemistry -Check ( ✓ ) the desired parameters to be analyzed. If not listed, enter the
clement/compound in the space prm1ded. m·
Organic Chemistry Check ( / ) the desired parameters to be analyzed. If not_ listed, enter the
element/compound in the space provided.
TCLP Compounds Check ( ✓ ) the desired parameters to be analyzed. If not listed, enter the
element/compound in the space pro,1ded. TCLP can only be performed on solid or semi-
solid samples. For totals of the inorganic parameters, check ( ✓ ) the corresponding
par<;1.mctcr under Inorganic Chemistry.
Microbiology and Radiochemistry -Contact the Raleigh orficc prior to sampling either of these.
Distribution:
Disposition:
1. Send or deliver the original.to the Stale Laboratory of Public Health.
2. The Lab then sends a copy (with results) to the Solid Waste Management Division.
3. The Solid Waste Management Division sends a copy to the field person or collector.
This form may be destroyed in accordance "1th the Environmental Health, Solid and Hazardous Waste
Section of the Records Disposition Schedule as published by the North Carolina Division of Archives and
History
Additional forms m;iy be ordered from: Solid \Vastc M~rnagcrncnt Division
Hazardous \Vastc Section
P.O. !lox 27687
Raleigh, NC 27611 . ~ .
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· SAMPLE ANALYSIS REQUEST Stale l...aboratory of Public lica\th
P.O. Box 280-17, 306 N. Wilmington Street
Ralcii.h, North Carolina 27611
" •~.) I I '.'j
N.c·. ·Dcpar;n)cnt of Environment,
ticalih, & Natur:11 RCsoun:cs
Solid W_astC Mru~agcmcnt Divisi?-n
(\> ·.-: . '· ! :·
Field Sanip!e' N~~~er_• --·~•--· .,,C)c...c..!_,C/_,t'--!>~/c__ __ ·--''' _____ _ Sile Number , )1/C.J>: 9eo 71'? 0/C/
r1•;,
Sile ~cation /20/ /xrry41't1 !Jel._, Cl,.,,ylc ll<. ,, A/C.
Collected By' 7). /11...,,e.;,
Agency: Hazardous Waste Solid Waste .J'!__Superfund
Sample Type
Environmental Concentrate Comments
_ Solid (5) __ Ground water (1)
L Surface waler (2)
_ Soil (3)
_ Liquid (6) ___________ _
_ Sludge (7) ___________ _
_ Other (4) Other (8)
Organic Chemistry Inorganic Chemistry
Parnmetcr
P&T:GC/MS
Results(mg/1) Parameter Results(mg/1) (mg/kg)
' Arsenic --✓ Acid:B/N Ext. Barium --MTBE Cadmium --Chloride --Chromium --__ Copper
Fluoride --Iron ----------Lead --__ Manganese
__ Mercury
Nitrate --Selenium --Silver --Radiochemistry Sulfates --.... ,,------------'----4 Zinc --
Paramctcr Results (l'Ci/1) _pH
__ Gross Alpha --------__ Conductivity ______ _
Gross Bela TDS --
TOC
Microbiology
1----------------1
Paran1etcr Results (Col/l00ml)
Date Received 3-/i/--q (pJe, Reported by _________ __c
Date Extracted 3-18-9<.,, SA
Dale Analyzed 3-,J.,l,-'J(p g,n
Dale Reported
Lab Number
---------9G1331
Time //':o.:,
TCLP Compounds
]norganic Compounds
Arsenic
Barium --Cadmium
Chromium --Lead
Results(mg/1)
__ Mercury
__ Selcniur~1
Silver --·--------
Organic Compounds
benzene --carbon tetrachloride
Resulls(rug/1)
---------
chlordane --chlorobcnzcnc --chloroform --o-cresol --m~crcsol --
--p-cresol
cresol --__ 1,4-dichlorobcnzene ______ _
1,2-diehloroelh ane
__ 1,1-dichloroethylcne ______ _
__ 2,4~dinitrotolucnc
__ heplachlor
hcxachlorobcnzcnc --hexachlorobutadiene · ---------
hexachloroelhane ----methyl ethyl ketone ______ _
nitrobcnzcnc ----pentachlorophenol
__ pyridine
__ telrachloroelhylcne
__ trichloroethylcne
__ 2,4,5-trichlorophcnol
_._2,4,6-trichlorophenol
__ vinyl chloride
Cndrin --lindanc ----melhoxychlor
__ toxnpbcnc
_2,4-D
2,4,5-TP (Si\-,cx)
PuqJOse:
Pr~parati~~:
Enforcement and compliance with the N.c.·solid and Hazardous \Va~tc Ma1~agcment Rules.
A sample analyses request form must be .completccl for each type of evaluation rcqueN6'd (?:g,; Jn4tgani~i.''' I
organic1 microbiology1 radiochemistry). For sampling conditions which rcquirC inorc than oq·C (1) ·Conlainc/
(i.e., ground.or '.urfacc water)··a sample label must .b.e affixed to o.nc of the con .. taincrs,":,Th'::.c~\(cctor m~.s..t. ,I
then wntc the site and snmple number on the duplicate con tamer. __ • ·. · . ·
. . Do ·not submit an analysis' req~esl for~1 without any parameters indicated .
Equivalent measurements: ppm = /lg/ml = mg/I = /lg/g = mg/kg
ppb = Jig/I = /lg/lOOOg = Jig/kg
DEFINITIONS/INSTRUCTIONS
Site Nurnuer -A unique twelv.e-digit site/location identifier (i.e., the EPA identification nu·mbcr).
Field Sample Number -A unique six-digit sample idcntifi,,r which is pre-printed on the sample label.
Name of Site -Name of facility, landfill, etc.
Site Location -City and county.
Collected Tiy -Name and staff identification number of collector.
Date and Time Collected -Self-cxplan'atory.
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Environmental -A sample ?fa naturally occurring substance such as ground water, surface water, or soils which may n·· i
be contarm~atcd. ., ·
Concentrate· -A sample of a waste, including but not limited to, sludges, resins, treatment effluents, or drum1:1cd g.:i
wastes. : , ·
' ·'
Comments Lists details regarding sample or sample point (e.g., sample location, well number, phase separation, "
and/or odors. . • 1:
. Inorganic Chemistry -Check ( ✓ ) the desired parameters lo be analyzed. If not listed, enter the
element/compound in the. space provided.
Organic Chemistry -Check ( ./ ) the desired parameters to be anaiyzed. If not listed, enter the
clement/compound in the space provided.
TCLP Compounds Check.(✓ ) the desired parameters to be analyzed. If not listed, enter the
element/compound in the space provided. TCLP can only be performed on solid or semi-
solid samples. For totals of the inorganic parameters, check ( ✓ ) the corresponding
parameter under Inorganic Chemistry.
Microbiology and Radiochcmistr·y -Contact the Raleigh office prior lo sampling either of these .
.
Distribution:
Disposition:
1. Send or deliver the original lo the State Laboratory of Public Health.
.2, The Lab then sends a copy (with results) to the Solid Waste Management Division.
3. The Solid Waste Management Division sends a copy to the field person or collector.
This form may be destroyed in acCordancc·with the Environmental r--Icallh1 Solid and Hazardous Waste
Section of the Records Disnosition Schedule as·published by the North Carolina Division of Archives and
History
1\cidilional forms may be ordered from: Solid \Vastc Management Division
Hazardous \Vastc Section
P.O. !lox 27G87
Raleigh, NC .27611
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N.C. Ocp:i
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nlncnt of Environment,
lic<lllh,.& Natural Resources
Solid Was.iC Managcrncnt Division -. . l .: ·. \
Name of Site Clu::.rok,e. {),/
SAMPLE.ANALYSIS REQUEST
{o,.,_,, (/
~'/
State Laboratory of l'ublic !lcalth
P.O. Bo.-.: 28047, 305 N. Wilmington S!rcct
\ . Ralci&h, North Carolina 2761'1 . . . . ' . ':; :,
Collected By' 7J. /11...,# JD# ____ Date Collected ,#,ircA 1;11 19'16,
Agency: Hazardous Waste Solid Waste _c__:Supcrfund
Sample Type
Environmental Concentrate Comments
_ Solid (5) __ Ground water (1)
__ Surface water (2)
_ Soil (3)
_ Liquid (6) __________ _
_ Sludge (7) __________ _
)( Other (4)
(sd,..-1-")
_Other(8) __________ _
Organic Chemistry Inorganic Chemistry
Parameter Rcsults(mg/1) Parameter Resulls(mg/1) (mg/kg)
✓ P&T:GC/MS
_ Acid:B/N Ext.
MTBE
---------------
Radiochemistry
Paramete.1: Results (!'Ci/I)
__ Gross Alpha _______ _
Gross Beta
Microbiology
Parameter Results (Col/1001111)
Date Received ':,-(l/-9(,,113
Arsenic
Barium --Cadmium --Chloride
Chromium ----Copper
Fluoride
Iron --Lead
__ Manganese
__ Mercury
Nitrate
Selenium --Silver
Sulfates
Zinc
_pl-I
__ Conductivity
TDS --TOC
Reported by _________ _
D:ilc Extracted _________ Date Reported ________ _
Dale Analyzed .3-~ -'i(p-rlW-Lab Number 96133;(!
TCLP Compounds
Inorganic Compounds
Arsenic
Barium --Cadmium
Chromium --Lead
__ Mercury
Selenium
Results(mg/1)
------------Silver
Organic Compounds
benzene
carbon tetrachloride
Results(mg/1)
----------
--
--
chlordane
chlorobcnzenc
chloroform
o-cresol
m-crcsol
--p-cresol
crcsol ----1,4-dichiorobenzenc ______ _
1,2-dichlorocthanc
__ 1,1-dichloroethylcne ______ _
__ 2,4-dinitrotolucnc
__ hcptachlor
hcxachlorobcnzenc --hexachlorobutadienc • ---------hcxachlorocthanc --_._ methyl ethyl ketone
nitrobcnzcnc ----pcntachlorophcnol
__ pyridine
__ ·tctrachloroethylcnc
__ trichlorocthyi'cnc
__ 214,5-trichlorophcnol ______ _
__ 2,4,6-trichlorophenol ______ _
__ vinyl chloride
c.ndrin --linclanc
__ mcthoxychlor
__ tox,ipbcnc
2,•l-D
_· ·_ 2,4,5-TP (Sil·,cx)
Purpose: Enforccm~nt and .:::ompliancc with the ·N.C. Solid and-Hazardous \Vastc Management Rules.
Prepaf'atioil: · A Sarrl."ple:analyses request form must bc·complctcd for eai;:h type of cvaluatiOn· rcqucs_tCd-(e:g., inorga·ni;;
organic, microbiolot,,y, radiochemistry). For sampling conditi'ons which r·e.quire morc•·th~n ·of}c (1) container
(i.e., ground o"r surface water) a sample label must be affixed to one of _the containers_.,-. The co[lcctor must I
then write the site and s~tmple· number on the duplicate ~Qfltaincr.. · · · '•. ·
I
Do· not submit an analysis request for~, without any parameters-indicated." ·.,
Equivalent measurements: ppm = pg/ml = mg/I = pg/g = mg/kg
ppb = pg/! = pg/lOOOg = 1,g/kg
DEFINITIONS/INSTRUCTIONS
Site Number -A unique twelve-digit site/location identifier (i.e., the EPA identification number).
Field Sample Number -A unique six-digit sample identifier wi,ich.is pre-printed on the sample label.
Name of Site -Name of facility, landfill, etc.
Site Location -City and county.
Collected By -Name and staff identification number of collector.
Date and Time Collected -Self-explanatory.
.,
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E
D
Environmental -A sample of a naturally occurring substance such as ground waler, surface water, or soils which mayo,·
be contammated. . . · . . . .
Concentrate -:a:;;/lc of-a waste, including but not limited lo, sludges, resins, treatment effluents, or drumm~d U)
Comments Lists details regarding sample or sample point (e.g., sample location, well number, phase separation, -· ·
and/or odors. . ··-a.
Inorganic Chemistry -Check ( ✓ )" the desired parameters lo be analyzed. If not listed, enter the·
element/compound in the space provided. m
Organic Chemistry
TCLP Compounds
Check ( / ) the desired parameters to be analyzed. If not listed, enter the
element/compound in the space provided.
Check ( ✓ ) the desired parameters lo be analyzed. If not listed, enter the
I
element/compound in the space provided. TCLP can only be performed on solid or semi-I
solid samples. For totals of the inorganic parameters, check ( ✓ ) the corresponding
parameter under Inorganic Chemistry.
Microbioi"ogy and Radiochemistry -Contact the Raleigh office prior lo sampling either of these.
Distribution;
Disposition:
l. Send or deliver the original lo the State Laboratory of Public Health.
2. The Lab then sends a copy (with results) to the Solid Waste Management Division.
3. The Solid Waste Management Division sends a copy lo the field person or collector.
This form mc1y be destroyed in accordance v,,.1th the Environmental Health1 Solid and Haz.ardous Waste
Section of the Records Disposition Schedule as published by the North Carolina Division of Archives and
History
Additional for ms may be ordered frorn: Solid \VJslc Management Division
Hazardous \Vastc Section
P.O. Box 27687
Raleigh, NC 27Gll . I>' ,, •••
. ...,,. • --·""· ., i.~
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N:C.-f?cfla'rtmcnt of Environment, SAMPLE ANALYSIS REQUEST . . State Laboratory of Ptlblic ! lcahh
P.O. Box 28047, 306 N._.Wilffiington Street • llc~llh, & Natllral Resources ,, ' .)•:;·, / .... .-,··,. -.. ·:. ' Solid.\1/astc Management D1v1S1on ,,,, .. ~: \:,-? ,:-.. ,,, : ,J.: 4 -•~t-•. \ , . ;,;_:, . .,. . i' ;,:'.. ,::.,;':;;~;;;;:~t~\/;:;{l}:t,l,~t: N~r:h C.roEiJ 2;~!1;
Field Sa,nplc1Nu'mber',<','i::,,:.o.1,\1"~,~,!,;;, J.. , .
. :, ,:) ,._:.~.(,!':)'.(,,-?I:•,::',''.';•~', :;:~:/•'.::.<': .. t ...
Sile ~cation /U/ &;rryt.,1/ /Q.d., ~,.;.10 l>t. /JC..
Collected By' 'P .. M'°",e.e
Agency: Hazardous Waste Solid Waste -2:::__:superfund
Sample Type
Environmental Concentrate Comments
_ Ground water (1) __ Solid (5) Co-ot>'f-Sb
_ Surface water (2) __ Liquid (6) ___________ _
_ Soil (3)
..!__ Other (4)
( ~,.c1. ~)
_ Sludge (7) ___________ _
_ Other (8)
Organic Chemistry Inorganic Chemistry
Results (mg/I) Parameter Results(mg/1) (mg/kg)
Radiochemistry
····----~-----------j
Pam meter Results (l'Ci/1)
__ Gross Alpha ______ _
Gross Beta
iv! icrobiology
Pc1rarnctcr Results (Col/l00ml)
--
--
--
Arsenic
Barium
Cadmium
Chloride
Chromium
--Copper
--
--
--
--
--
--
--
--
Fluoride
Iron
Lead
Manganese
Mercury
Nitrate
Selenium
Silver
Sulfates
Zinc·
__ pH
__ Conductivity
TDS --TOC
,, ,· ·:, . . , . . . ,
Time / f?: 15'
TCLP Compounds
Inorganic Compounds :
--
--
----
--
Arsenic
Barium
Cadmium
Chromium
Lead
Mercury
Selenium
Silver
Organic Compounds
benzene --carbon tetrachloride
Results(mg/1)
Results(mg/1)
---------
--
--
chlordane
chlorobenzene
chloroform
o-cresol
m-crcsol
--p-crcsol
crcsol ----1,4-dichlorobcnzene _____ _
__ 1,2-dichlorocthanc
__ 1,1-dichlorocthylcne _____ _
2, 4-di ni trot ol uene
__ hcptachlor
hcxachlorobcnzcnc --hexachlorobutadiene • ---------hcxachloroelhanc --
--methyl ethyl ketone -----~
nitroben7,cnc ----pcnlachlorophcnol
__ pyridine
__ tclrachlorocthylene
__ trichlorocthylenc
__ 2,4,5-trichlorophcnol
_._2,4,6-trichlorophcnol
__ vinyl chloride
--
cndrin
lindanc
--mcthoxychlor
__ to;,.:;iphtnc.
2,4-D
_· _ 2,4,5-TP (Sil·1cx)
l'urpoSe:. EnTorc..:m~nl and ·Complianc_c \viq1· the ·N.C. ·solid and-Hazardous ~Vastc Management Rules. · .
~,::>·;, .
A: :anipli,'~nalyses ~cquest form must be completed for each type of evaluation rcqussfod: (c:g::ino~i;;ruc; I Pre I )ri t'h'ti, ~Tl:··_-
. ' • . ' . . . . • ' ' ......... ~ . . . ' ,. ~ , • ... i· . organic,.-micro_biolo&'Y, radiochemistry). Fof Sampling."conditions which rcquirC fll:Orc th~n-OD_C ·(1) "'Conlalncr
(i,c:, ?i~,u~d-or ~urfa.ce w.at~r) ~jamp/~,l\lpe!,i?~~t .be affixed to qpc of,the,con/ainers.,,,The_ c,zl\cctor m_usl
then wnte.thc site and snmple number on·thc duphcatc.contamer,," . · -.. · -.. . . . ·
···:,\.,, .. ·._·~\;~:.,,.,~-... ·.-."'..•, ... _:;-..• ,-. ' .;:,. ,.·;,.,;. __ ..... ·.• .. ,• .
. .. -~ .. ~-Dci"riot-submit an arialy;is request fcir'ni without any parametcrs,indicaicd.' <. •.
...c·,. Equivalent measurements:_
''1, I
ppn; = µg/ml = mg/1= µg/g = mg/kg
ppb "' µg/1 = µg/lfXXJg = pg/kg , , ,
DEFINITIONS/INSTRUCTION_S
Site Number -A unique twelve-digit site/location identifier (i.e., the EPA identification nuniber),
Field Sample Number -A unique six-digit sample identifie'r which is pre-printed on the sample label.
· Name of Site • Nam_e of facility, landfill, etc,
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I
I
I
Site Location -City and county.
Collected Dy -Name and staff idcnlilication number of collector.
Date and Time Collected · Self-explanatory.
Environmental• A sample of a naturally occurring substance such as ground water, ,surface water, or soils iyhich 1·
be contaminated.
Concentrate -A sample of a waste, including but not.limited to, sludges, resins, treatment cfnuents, or dJummc'fl _,
wastes. · · · .' U '.
:... ·•
Comments Lists details regarding sample or sample point-(c.g., sample location, well number, phase {eparatil,.
and/or odors, · · -
Inorganic Chemistr-y -Check ( ✓ ) the desired parameters lo be analyzed. If.not listed, enter the
element/compound in the space provided.
Organic .Chemistry -Check ( / ) the desired parameters to be analyzccL If not listed, enter the
clement/compound in the space provided. ' '
D
g
TCLP Compounds Check ( ✓ ) the desired parameters lo be analyzed, If not listed, enter the
element/compound in the space provided. TCLP can only be performed on solid or scmitl
solid samples. For totals of the inorganic parameters, check ( ✓ ) the corresponding · [I
parameter under Inorganic Chemistry.
Microbiology nnd Radiochemistry -Contact the Raleigh office prior to sampling either of these.
Distribution: l. Send or ,deliver the original to the Stale Laboratory of Public Health.
2. The Lab thon sends a copy (with results) to the ·Solid Waste Management Division.
3. The Solid Waste Management Division sends a copy to the ricld person or collector. I
Disposition: This rorm m,iy be destroyed in accordance with the .Environmcnt;:t! Hcalth, Solid and Hazardous-Waste I
Section of the Records Disposition Schedule as published by the North Carolina Division of Archives and
History ·
Additional forms may be ordered from: Solid \Vaslc tvL.;nagcmcnt Division
Hazardous \Vastc Section
P.O. Box 27G87
Raleigh, NC 27611
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• ,<,C, Department o[ Environment, SAMPLE ANALYSIS REQUEST State Labornto,y o[ P,01;, Health
I ,lc~~.thy_\~· .. N~t~_r,~.l r.:sou~~c-~.,: .. '· . ,:~. 1 _ · • : P .0. Box 28047, '305 N. 'Wilmington SI reel .
Solid Waste Management OJVISIOn : .. '.:;_:.t, .. ,t,··.-.··,•,~·'.· :,::,\,'..~.~·,;},·,:~.· •. ·, ",", •. ·;,,r; .,h ·/},-,u•,;' 'i-;.1 ·rr):: ·•f.~:'! I' -;;_,,,Ralc;gh, Nor;h Carohry~. ?,7§f1 . :.·,.,z,~-.-\;;.;':•.,· .. .,.} i~·~;: ·:~i.-?_1 .--..·:· y,, ·,,'. 1;1:-~ ... -,, .:!i•'' ... " ,i. k,, 1:.,, .,·,1,,:. : . :. h "l· ~ ... , '
Sit~ 0~~'6dr ''X~c}/9'&,'-i'l&f' ·ci/t:f • ., ,,<i:· ,,,; ·,,Fie.id Sin~plcNu'mber•-''i1, ' 0/,qt, ','tfi :, .
• ' • • • ' ",· • ' • • >· ( • • ;, • °! •· ! ';', • '.· ; l' '-(~ •:• ., ·:.I!•·•
Collected By' 7'. M.,,.,e.c JD#~ ___ Datc Collected ,Al/,trd, l".!1 1916-Ti.me fi.'oo
Agency: Hazardous Waste ---Solid Waste ---__c__Superfund TCLP Compounds
Sample Type Inorganic Compounds Rcsults(mg/l,
Environmental Concentrate Comments Arsenic --Barium co-oo:r-.s b --
Ground water (1) _ Solid (5) Cadmium --Chromium --
•Surface water (2) _ Liquid (6) Lead --Mercury --
_ Soil (3) _ Sludge (7) Selenium --Silver --
~ Other ( 4) _ Other (8).
{54/i~) ----
Organic Chemistry Inorganic Chemist!)' --
Parnmcter Results(mg/1) Parameter Results(mg/1) (mg/kg) Organic Compounds Results(mg/1
vP&T:GC/MS Arsenic benzene ----
_ Acid:B/N Ext. Barium carbon tetrachloride ----
MTBE Cadmium chlordane ------Chloride chlorobcnzcnc ----Chromium chloroform ------
--__ Copper o-cresol --
Fluoride m-crcsol ------Iron p-,cresol ------Lead cresol ------Manganese 1,4-dichlorobcnzene ------
--__ Mercury 1,2-d ichloroe.t hane --
Nitrate 1, 1-d ichloroet hylcne ------
Selenium 2,4-dinit rot ol u enc ----Silver __ heptachlor --Radiochemistry Sulfates hexachlorobenzene ----
···-··-Zinc hexachlorobutaclicnc · ----Parameter Results (!'Ci/I) pH hcxachloroct hanc
__ Gross Alpha ----
__ Conductivity methyl ethyl ketone --
Gross Beta TDS nitrobcnzcnc ------TOC __ pcntachlorophenol --__ pyridine --
Microbiology ----tetrachloroet hylcnc
__ trichlorocthylcnc --Parameter Results (Col/1001111) __ 2,4,5-trichlorophcnol --_._2,4,6-trichlorophcnol ----__ vinyl chloride ----cndrin --lindanc --
Date Rcccived_3-/L/-?t, 48 Reported by --mcthoxychlor
A~~ l•rucl --tox;,phenc
Dcitc [1l11ie1Lcl 3-::.J;;:2-CJlo ""flu.f Date Reported 2,<1-D
----~-961334 --_· _ ?.,·1,5-TP (Sil·,c:x)
" "
\,:.,PGrposc:. · EnTorccm~nt and Compliance Wllh. the N.G.,-Solid and-Hazardous \Va~tc .Management Rules. . .
\,;ci;J;;Uon>. A' ,·~~~1/t~·~aiyses request ;or;~ must be completed for ea~h type of evaluation:;c,fu~:;:ci (~ii:iri~:i~~~i:I
' • • ' . . . ' ,' . '' . •-' • . . . ~ ·,: •,t •. • {'. ··••.;:·•...:,. ,,:·, .•. ,., •• '~f. .. o_ _,.,_,,, • organic,. m1crob1ology, radiochemistry). For samplmg-cond1t10ns which requ.1re 111ore than one· (1) con tamer
~ --Ji.e' gr~µf\d or ~urface wat.sr) a .~ample 1~_):,pl::11 .• pst _be affixed to 011!', of ,t~1\i:org\1icr.~.,,;T,he ":~)\~ciq~ 1?.UI
. then·wnte.the site and sample number on the duplicate:contarncr..· --·~· · .. ---:-·· ....... •.· : .. -. -·
. . . ' . . . . ' . -.. ',· ~ . .
"· -~ !"~-;,,· o/n~·t ~1'.o~nit an analysis re~-~~st f~r~ ·\1/i;h·o·ut anyparametersindidt°ci· r:_ .. ·.. , .. ,\<:c
.. cc Equivalent measurements: pp,; = 11g/ml = mg/I ;, µg/g = mg/kg
ppb = µg/1 = µg/lOOOg = µg/kg
' . I ' . •
DEFINITIONS/INSTRUCTIONS
Site Number -A unique twelve-digit site/l_ocalion identifier (i.e., the EPA identification 'numher).
Field Sample Numb.er -A unique six-digit sample identifier which is .pre•prinled on the sample label.
Name of Site -Name of facility, landful, etc.
Sile Location -City and ·county.
Collected Ily .-Name and staff identification number of collector.
Date and Time Collected -Self-explanatory.
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·Environnicntal - A sample ?fa naturally occurring substance such as ground water, surface water, .or soils 't_Yhich , .. !
be contarmnated. ·,
Concentrate -A sample of a waste, including but not limited to, sludges, resins, treatment effluents, or drumme~ ·
Comments
wastes. · · ·· .. -,
--
Lists details regarding sample or sample point (e.g., sample location, well number, phase separation;
and/or odors. I"
Inorganic Chemistry -Check ( / ) the desired parameters lo be analyzed. If not listed, enter the
element/compound in the space provided. I Organic Chemistry -Check ( / ) the desired parainelers lo be anal1Led.
clement/compound in the space provided.
If not listed, enter the
TCLP Compounds I Check ( / ) the desired parameters lo be analyzed. If not listed, enter the
clement/compound in the space provided. TCLP.can only be performed on solid or semi.
solid.samples. For totals of the inorganic parameters, check ( / ) the corresponding ·
parameter under In.organic Chemistry. ·
Microbioloi;y and Radiochemistry -Contact the Raleigh office prior to sampling either of these.
Distribution: l. Send or deliver the original lo the Stale Laboratory of Public Health.
2. The Lab then sends a copy (with results) to the Solid Waste Management Division.
3. The Solid \Vastc Management Division sends a copy to· the field person or co!!cctor.
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I
Disposition: This form may be destroyed in accordance with the Environmental Health, Solid and Ba,.ardous Waste I
Section or the Records Disposition Schedule as published by the North Carolina Division of Archives and
History ·
AUdilionnl forms 111:iy be ordcr·cc! from: So!id \Va.stc M:rnagcmcnl Division
Haz~1rduu.s Vh1stc Section
P.O. l3ox 27G87
Raleigh, NC 27611
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State Lnbonitory of Ptiblic Health -·N.C. -DcJ):inmcnt of Environment, SAMPLE ANALYSIS REQl)EST
P.O. Box 28047, 305 N. Wilmington S1rcc1
,•,~ • ✓:..,~J: · .1, ,' • i:.; -;·~1) :,:-:· ,:..,.·.r1·,i'•' .• -;: :;;{i~R..alcig"h, North Caroliria. 276fl • ·1 !ca\th .& Natural Resources. _ Soiid'\v~·~•t,/MiiJg~w;~nt 6i~1i0r{ '• 1·~ 1· . ·• .. ~'l!,;/i:.'.:' :'.-·' :::1-: ,, __ .·
·_, :iF::·•~;>_: .. ,;~·:,\:~\};n'fra_:_";_.,;.,.~-i:~,;/.!;i;·~;-,:id;;,· . ' ' :.· ::: . ···: ··•.~;1;:~-; ,;r;~.,__,-,,, __ :.-11;.~·:.1.1 ·~r . .-::-;: ,:. <;t ··. • :·'•rf 1L·-I.i1::----~:.
. ~-. sit6 t~~it~'r '''';..'icE ; q~;:/''-i"'"'. 0-✓1 · , -._.· Fi°cld Sample'Nu·mbd ,:,(i:>c,. l'q,t:,~ST-.-,!;,,,.,r ·
. ,, :.;: -:,_"!':'., :,,,;.,:";r'!,_~,,n;.:.:.'>-· .. ;-;_.',:,f.::;•(;:·(:-,:
Name of Site C:hu-ok,r~. CJ,/ Co,.,ca,, v ~7
Sile_ L~cation /20/ &rryl.1"1/ -~d.,, C-1,,.,,-1,, f,{,. • ,Ve..
. ' , . ,._,,'.,\ r:. ; . . . •
Collected By' 7). M...,,e.e JD#~--Dale Collected ,ll/11;,.et, i3119'?(, Time / e-·. oo
Agency: Hazardous Waste Solid Waste --- ---
_c_ Superfund
Sample Type
Environmental Concentrate Comments
_ Ground water (1) _ Solid (5)
_ Surface water (2) __ Liquid (6) ___________ _
Soil (3) _ Sludge (7) _________ _
-1':__ Other (4)
{(;e,,I,"~)
_ Other (8)
Organic Chemistry
Parnmcter Rcsults(mg/1)
Inorganic Chemistry
Parameter
Arsenic
Results(mg/1) (mg/kg)
P&T:GC/MS
✓ Acid:B/N Ext. === Barium
MTBE Cadmium ;/ ~-u,· · ·. ______ =Chloride
__ 'S" <o,/0-~ Chromium
__ £ti. tr1N' <O,// ~--__ Copper
/ ,;.y,.,1..,NF < O, -Fluoride
,.. ·o·· /~ </.cJ-,.i......t --Iron
~--' ~"ENG <:" I · =Lead
~, -' ' .1.,,, .1~ -<.Cl .. .X.e,_,..,.,,._ Manganese
~e; , ,, · <::·o,/o.,'117,,...'-Mercury
11f'2I"',,,f,I/ .c;;o.·" 6~0,/i' ---Ni.tratc
' • -Sdcnium
Radiochemistry
···-----------------'--~
Parameter
__ Gross Alpha
Gross Beta
Results (PCi/l)
JV! i c rob i o Io gy
Parameter Results (Col/lO0ml)
--Silver
Sulfates
Zinc
__ pH
__ Conductivity
TDS --
TOC
TCLP Compounds
Inorganic Compounds
Arsenic
Barium --
--Cadmi~im
Chromil1m
Lead
__ Mercury
__ Selenium
Silver
Organic Compounds
benzene --carbon tetrachloride
Rcsults(mg/1)
Results(rug/1)
---------
chlordane --chlorobcnzene --chloroform --o-cresol --m-crcsol --
--p-cresol
crcsol ----1,4-dich\orobenzcne ______ _
__ 1,2-dichlorocthane
__ 1,1-dichloroethylcne ______ _
__ 2,4~dinitrotolucnc
__ heptachlor
hcxachlorObcnzcnc --hexachlorobutadienc • ----~-hexachloroet hane ---·-methyl ethyl ketone ______ _
nitrobcnzenc ----pentachlorophenol
__ pyridine
__ tetrachloroethylcnc
__ trichlorocthylcne
__ 2,4,5-trichlorophcnol
_._2,4,6-trichlorophcnol
__ vinyl chloride
--
cndrin
lindanc
--mcthoxychlor
__ tox:1phe.nc
__ 2:l-D
. _· ._. 2,,1,.5-TP (Sil·,cx)
,-.
_Purpose: Enforcement a1i'd con;pliance with the N.C. Solid and Hazardous. Waste Management Rules. · ·
. ,/. :-,.:" -,.... .
l\cpi,rati?n:'
then wnte the site and snmple number on the duphcate CQntarner .. · ·-.·• , .. •··~.: -.• ,-. . ...
. _;, ~~~p1{l~aljs~s icque~·t for~1 ~1ust be completed for. each type of evaluation rcqti~~iia {c-g/inoi~a:c,I
organic, microbiology, radiochemistry). For sampling ·conditions which require mor(·itian ·oni/(1.f2on1liiiier'
(i.e., gr~~n.•d ~r ~urf~.ce _w_a_t<:.r\:• .. sample l~pfl,~~st _be af. fixed to one of,_t_.~p,co.11.,ta. iner_,~-i,The_ c?J~ecto:,.~,~-1·
::: .. •,.·1 \:.'~~--~ ..• ,,,~ .. ;;:•. "\.•, __ ::, :. ,. r
"
.. Do not submit an analysis request form without any parameters,indicaicd:•':·:. ·
" ... •, ~.
Eq ui valcn t :measurem e·rits: ' ppm = µg/ml = mg/I·= µg/g = mg/kg
ppb. = pg/I = pg/lOOOg = pg/kg
DEFINITIONS/INSTRUCTIONS
Sile Number• A uniq~e t_welve'digit sile/l_ocalion identifier (i.e., the EPA identification nu·mber).
Field Sample Number - A unique six-digit s;inplc identifier which is .pre-printed on the sample label.
Name of Site • Name of'facility, landfill, etc.
Site Locution • City and county.
Collected By -Name and staff identification number of collector.
Date and Time Collected -Self,explanalory.
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Environmental - A sample o.f a naturally occurring substance such as ground water, surface water, or soils ,which '
be contaminated: '. ·..:
t Concentrate • A sample of·a waste, including but not limited lo, sludges, resins, treatment effluents, or µrummeil::._.
wastes. · U··
Comments Lists details regarding sample or sample point (e.g., sample location, we·ll number, phase·scparation, ·
and/or odors. . ·. . -m
Inorganic Chemistry -Check ( ,/ ) the desired parameters lo be analyzed. If not !isled, enter the
clement/compound in the space provided.
Organic Chemistry Check ( ./ ) the desired parameters to be analyLed.
element/compound in the space provided.
If 1iot listed, enter the
TCLP Compounds I
Check ( ./ ) the desired parameters lo be analyzed. If not listed, enter the
element/compound in the space provided. TCLP can only be performed on solid or semi.
solid samples. For totals of the inorganic parameters, check ( ✓ ) the corresponding ·
parameter under Jn·organic Chemistry.
Microbiology and Radiochemistry -Contact the Raleigh o[ftcc prior to sampling either of these. I
I
Distribution:
Disposition:
l. Send or deliver tlie original lo the Stale Laboratory of Public Health.
.2. The Lab then sends a copy (with results) lo the Solid Waste Management Division.
3. The Solid Waste Management Division sends a copy lo.the 11eld person or collector.
This_ rorm may be destroyed in accordance with the Envirnnmenlal Health, Solid and Ha,.ardous Waste I
Section of the Records Dis11os,t1on Schedule as published by the North Carolina D1v1s1on of Archives and
History
/\ddition,il forms may be ordered fro1~1: Solid \V::istc Management Division
Hazardous \Vastc Section I
I P.O. Box 27687
Raleigh, NC ,:n_6,1),.!
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N.C.Dcpanmcnt of Environment, SAMPLE ANALYSIS REQUEST_ Stale Laboratory of Public Health
P.O. Box 28047, 306 N. Wilmington Str,:ct
·.-:,:; !,d'~}" , '• ,. ··:: [f;)";, • .-,_;•,_ ~. ·: ·,;,.-,R.alciih, North CofO!ina 276l'l .,, !!ca1Jh11~.Natu.r:::a,l R:~sou~~c~ ... •.\ ·!-·~ ,· .... ,· _ .... Solid·:w-a·stc·Managc~Cnt Di~S.i6n'·•. '. ·.:-..·;-~•;q· ',i' 1 ;'.:;_,"
. {,;:_·::.,•',;,:_... _:,{it-.:-~-: '.i• )~··1,k_'i;\i:: •. , : .. \'.,: :-/-:\:_;:;(!,: ... . . . ·.• , .. 1
_,.,,'f-1;/,'( ;_,.f.:>, \·') ·(~;\, ·~::t'.·~;1\ ::, •. : 1: ·;,, :J ; i )L,
Sile JG;'t;~'; ''';{1t::JS''9icJ''79~ ·. 0/7' •·• : . Field· Sample' Nu'mbfr_,,_;· (~'-;::..•• ~--.=O_;l:....'fL"::...:.S7_(,,_:_•·: ;;_i: ·::..: ----'-----
,.. _-;~--,',.·-·.: ;·;,·,11.:; ,.,,,.; •·,· :: ,·.
'Sile ~cation /ZP/ &rr'lt.,11_ R,f;, Cl,,.,.-1,, Inc.,, /JC.
Collected By' ;D .. M.,.,,ec
Agency: Hazardous Waste Solid Waste ~Superfund TCLP Compounds
------
Sample Type Inorga:1ic Compounds Results(mg/1)
Environmental Concentrate Comments Arsenic --Barium --frtp s,-.,.,_ __ Ground waler (1) _ Solid (5) Cadmium --Chromium --
Surface water (2) _ Liquid (6) Lead --__ Mercury
_ Soil (3) _ Sludge (7) Selenium --Silver --
£ Other (4) f _ Other (8) ..
---rr ;p i3/t1-,w (__ --
,...c---
Organic Chemistry Inorganic Chemistry --
Parnmctcr Rcsults(mg/1) Parameter Rcsults(mg/1) (mg/kg) Organic Compounds Rcsults(mg/1)
/r&T:GC/MS Arsenic benzene ----
Acid:B/N Ext. Barium carbon lelrnchloride
MTBE
----
Cadmium chlordane ------Chloride ehlorobenzene ------Chromium chloroform ------
--__ Copper o-eresol --Fluoride m-crcsol ------Iron __ p-eresol ----Lead cresol ------
--__ Manganese 1,4-dichlorobcnzenc --
--__ Mercury 1,2,di chloroelhane --
Nitrate __ 1,1-dichloroethylene ----Selenium 2, 4-di n ilrot ol ucne ----Silver __ heplachlor --Radiochemistry Sulfates hexachlorobenzene ----
····--·· Zinc hcxach 1 orobu l ;1 cl icnc --
Para mete,: --Results (PCi/1) pH hcxachlorocth:rnc ----
__ Gross Alpha __ Conductivity __ methyl ethyl ketone
Gross Bela TDS nitrobcnzcnc ------TOC __ pentachlorophenol --__ pyridine --
Microbiology --__ telrachloroethylene
__ trichloroethylene --Parameter Results (Col/lO0ml) __ 2,11,5-tri'chlorophcnol --_._·_2,'1,6-trichloro phenol ----__ vinyl chloride ----cndrin --lindanc --
D<1tc Received 3-t'!-C/_t, AA Reported by __ rncthoxYchlor
D:,lc ~,~)J~d __ tox:-1phcnc
3-cJ I -9 (p ,tW" Dalc Reported 2,4-D ·--
·-961336 _·_ 2,'\,5-TP (Sil·,cx)
" ., •.-·
, Purpose: Enforcement and Compliance \vilh the .N.C. ·solid and-.Haz.ardous. \Vaste' .Mai1:Jg1.:.mcnt Rules.
l'r'qi,;;htion:·' A s~~~1/~~alyses request form must be complctecl for toaci; type of evaluation rcrfti~5.t,c'dJe:f;;1:;ga(1il
organic, microbiolo1,,y, radiochemistry). For sampling-conditions which require more th-an orie· (1)' ·cori'Caiiier
.... (i.e., gi~u_:1.tor ~urface_,;at<cr); a .~amp_le, !~)if\ '!'~st _be affixed to_ qn.c 9f1t.~p_ i:onf_ainert, ,The c~J':~ctq
0
r .';1'u1·
then write the site and snmple number on-the duplicate contarner.. :·. · ·· · ·· -•··.·: . · . . . . .. -. . . . . ' . .. .
••• ,, ~--, ' \_."' • <. :·,.,. • • :•, • ·-.,_·:: • ,. ' •
-. Do· not-submit an a~alysis request form without any parameters-indicated.
· -· EquivalcnCmeasur~me.nts: ppm .. = )lg/ml = mg/J ·:C )lg/g = mg/kg
ppb = )lg/l = )lg/10<:iJg: = 11g/kg
DEFINITIONS/INSTRUCTIONS
· Site Number -A unique twclv_e-digit site/location identifier (i.e., the EPA identification nu:mbcr).
Field Sample Number -A unique six-digit sample identifis,r which is pre-.printed on the sample labeL
Name of Site -Name of facility, land!ill, etc.
Site Locution -City and county.
Collected By -Name and staff identification number of collector.
Date and Time Collected -Sclf,explanatory.
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I
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D
Environmental -A sample?.[ a naturally occurring substance such as ground water, surface water) or·soils which '
be contammated. _ ·
. --
Concentrate -A sample of a waste, including b.ut not limited to1 sludges, resins, treatment effluents, or drurpmcd,...
wastes. . · II
.. . r_ .. II:·•~
Comments Lists details regarding sample or sample point (e.g., sample location, well number, phase separation,
and/or" odors. I
Inorganic Chem is tr)' -· Check ( / ) the desired parameters to be analyzed. If not listed: enter the
clement/compound in the space provided. I Organic_ Chemistry Check ( / ) the desired parameters to be analy-,ed.
clement/compound in the space provided.
If not listed, enter the
TCLP Compounds I Check ( / ) the desired parameters to be analyzed. If not listed, enter the
element/compound in the space provided. TCLP-can only be performed on solid or scm·,
solid samples. For totals of the inorganic parameters, check ( / ) the corresponding
parameter under Inorganic Chemistry.
Microbiology and Radiochemistry -Contact the Raleigh or!icc prior to sampling either of these. I
I
Distribution:
Disposition:
l. Send or deliver the original to the State Laboratory of Public Health.
2. The Lab then sends a copy (1vitb results) to the Solid Waste Management Division.
3. The Solid Waste Management Division sends a copy to,the r,cld person or collector.
This_ form may be destroyed in accordance with the Environmental Health, _Solid and Hazardous Waste I
Section of the Records Disposition Schedule as published by the North Carolina Division of Archives and
History
1\ddilional forms may be ordered from: Solid \Va.stc lvl3nagcrncnl Division
Hazardous \Vastc. Section I
I F.O. !Jox ?.7687
Ralc_igh, NC ?.76,11 .,
'iC-DEHNR
')ivision .of Solid \Vaste Managcmt'.nt
fol:·Super'rund Section
D Hazardous Waste Section
D Solid Waste Section
~rganics Lab: V
Inorganics Lab: __ _
CHAIN OF CUSTODY RECORD
Sampled by: 7) .,Moon.,,
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Project Name: O.e-r./u::e t:'J,f u,..f'"'"I
Site ID# (NCD#) Net:, 'iSo 791 01'1
Location: , ;). c, t f3eir,vt.., n Ro-I
Sampler ID NC SuPe'f'.r=vAl'b rec.no...i
Telephone:_(9,<t) 73:;,,-zso,. "-· 31:,-
Date Sampled: MareJ.. 1:1,1~qr. Address: CJ,.i:,_ ../o 1-1-«-, M~'-6vrg Co I 1-)C
Time Sampled: I
Sample Types: Soil ------Water v --=---Waste -----
I. Remarks: --------------------------------------
1 ======================================
I : Field Sample o,qr,'tB
' Numbers 019,s-s
019653
I~-------------------
11 ::~~;:;:,t:;dby• jgG~················~;~: :~~. ~;;; ;;//; ........ . g : (Signature) .
!
; Relinquished by:. ____ ~-----------1:
11
1 ·· Received by:. _________________ _
II . (Signature)
(Signature)
·Date: __ _
Date: ___ _
Time: ____ _
Time:. ____ _
Relinquished by:. ________________ _
I -------------------------------··---------------------------·------------------------------------------------------------------------------------
(Signature)
Date: __ _ Time: -----
i I· Received by: Date: ___ _ Time: ____ _
1 Results Reporte-8:
I
---1 co
STATE UBORATORY OF PUBLIC HEALTH
PO BOX 28047 -306 N. WILMINGTON ST., RALEIGH. NC 27611
I ORGANIC CHEMICAL ANALYSIS
np Q(\ T, · bl k..
PURGEABU: COJ!IPOUNDS LAB NO q(o 13;).f:'i 9ul330 q<,,3a;2. 9lD133!./-C!j(o/ 331.p
FIELD NO I q(p'ffo Jq(o50 i 9 Ii> 5.;i t9v54 )q(Q5(D
I COJ!IPOUND TYPE ( .,;z ) ( ;;i..) ( 4) ( 4) ( 4 ) ( )
M~S)~ 'ppb pprn 'pri b ppm 'ppb' }pin ppli pprr. {ppb ppm ppb (DPb ~-p;n
I CHLOROHl:THAK£ J..O 11_ (.,L. 11 U-I 1 I
VINYL CHLORIDE 10
I BROMOIIETHAN'E ,1,O
CHLOROETHAN'E 10
JO ·/ /
I TlUCHLOROn.O'OROIL?:rRAl'fE '
AC!:TOrni: ,;;i.o .;2;;2. 5 .::r ,..,J
1. 1-DICHl.OROrt'H!:?'1?; 5 +rnre_ U-
I tOOOIO:Tl!A1'l"E I J
laTHTIZ:'l'E CHLORIDE
I CAR.BON DISULFIDE
TRAl'f'S-1.%-DICHI.ORO rrHJ!:."fE /
ACR?UllflTlULl; ;,21) •(
l.l-DICHLORO.sT1L\lfl'; 5 .J--r l"'I ,-e.,,
~BOTMOlB .;2D LL '
CIS-l~DICHI.ORO~ 5 5 +rnrP
CBLOROP"ORK /0 -./-r,--ir P ✓
l.l.l•TRlCHLOROETBA1m / J / A -
CARBOll' TEl'llACfil.ORIDE
I ,wm;rn,:
l,!1-DICHLORO~ ' I
I TRlCHLORO~ ,✓
1.2-DICHLOROPROPAKE LL-
I BROMODICHLOROHETHA.la ' / +r-au'' \ I , I \ I '
I
c-.Po,,,_,,.._., LAB CC>ITl'\f<l1t-lFIT1oi-J OR BAc.r:::.6-R.cu"-ID,
I J -Xati.matad val.u•
JC -Actual. valu• i• Jcnown to be l••• than valu• given.
L -Actual value i• 1co.own to be gr•ater than valu■ given.
U -llat■rial waa ana.lpad tor but not detactad. 'l'h• number ia th■ Mini.mum. o.taction Lim.it.
NA -Sot: analy:•d.
I 1/ -T•ntativ• identification.
JI -C.Or,.\Pe>\41SO Rl:.Llf\Bl-'f ·OE:T'Eefl'\01.E. o>JL'/ IN H 1<,-H C.oNcoiTRffTlcN'S,
V-SAI-IPL1'!. 1-ll&H~'/ 01Lu.TED. MDL'~ Do NOT APf'L'{. I DEBNR 3065-0 (10/93) PURGCOM.ORG
~:..-;..-~------~
srATE LABORATORY OF PUBLIC HEALTH I
I PO BOX 28047 -306 N. WILMINGTON sr •• RALEIGa NC 27611
ORGANIC CHEMICAL ANALYSIS
f PURGEABLE COMPOUNDS UBNO 9tol3JB qG,133o
FIELD NO 19 lP1H3 190~
I COMPOUND TYPE ( ;;,L ) (,;l...)
fi,~rj,s 1-ppb ppm 'ppb f prr1
DrBROM.OMETl!AN?; 5 LL I I
4-METHTL-2-P'Ern"ANONE ,o +-race.!..,-
I Cts-1.~-DICHLOROPROP'EN'E 5 LL
TOL~ +rctrP_
I TR.Al'IS-1.3-DICHLOROPRDP'E:r?: I
1.1.2.l•Tl:I'RACHLOROrI"BAm:
~ l.l.2--TRlcm.DROE'TRA1'fE .
/0 V ' 7 2--BEXAl'l'ON'E
I T?;TRACfil.OROJ!:'TBZ?ff 5 ~ +-r l"I r .a -
DIBROIIOCHLORO~ I l LL.-
I r:nrn.E?fE DIBROMIDE ·:t
cm.oaonr.ar;;rn; I --7P '
I
1.1.1..2-n:nv.cm.oR.orrHME I
rnrTI. BEZ'l'ZE?"fl:
== I/
sn,u;,,-,: ' I -hrn ,-c,
BROIIOFOIUI /0 I
TRA!ffl..l,4-DICHLOR0-2.-BUT%N'E <to
1,2,:S-TRICHLORO PROP AI'll: !5
I l,4-DtCHLOROBE1'Z!l'CE ' ;
1.2-DICBLOROBE?f'ZEN!: ' ; .L-rr, r P
J l,2•DIBROM0-3-CHI.0ROPROPAN'K ,;le) l'
VINTL Al:ETAT'E ;;).()0 .I/ ' I
I
I C -P=1e1.c Lf\El Cc>JTR>J.1>-IAnol\l oR Bfl~l<<,t<OU1'!1).
J -Sstimat•d valu•
JC -1ctual va1u• i• known to be le•• than value given.
L -Actual value i• known to be greater th.an value giv.n.
q(_p 133:J
/9 (£J6J.
c.'-1->
Lf,, i!,') p prr1
/ J
' I/
"Tri'o bl ):: .
9(;133'-/-qu,133(£)
l9LP5't 19&'5(£!
( i.; . ) ( 1-I-)
{ppb pprn ,..-(Pb 'opm
/ I 11 .
\ I/ ,I/
I U -Katerial was analy:r;ed for but not d•t•ct•d. Th• number i• th• M~ Det■etion Limit •.
JD. -5ot analyzed.
1/ -·Tentative identification.
Ii -c:aMPouiJ D, RE Ll~SLY 0€11:Cf'.ffi:,LE tNLY /N t-114-H coNC£1'lTRAT1otJ.:;,
,/-SAl'lPLlo Hl6-HLY DILllTED. MDL'-o l>o tJoT"' APPL'/. I DEHNR 3068-0 (10/93)
( )
ppb ppm
PURGCOM.ORG
STATE LABORATORY Of PUBLIC HEALTH I
I P.O. BOX 28047 -306 N .. WILMINGTON, ST., RALEIGH, N.C. 27611
ORGANIC CHEMICAL ANALYSIS
BASE/NEUTRAL AND ACID LAB NO '-F/n/ -'>;;;i. '"1' ...,,,,,,~.~ I ~tn I -{ '? -', U./..,o<;l.,
EXTRACT ABLES FIELD# /CJ I. (/, <t' /t:/(d \ "/ /y-/,,.'>..3 /9t', <.',
alHPOUND TYPE ( ..:z ) ( <><) ( IJ-) ( •f)
UNITS uo/1~ uo/1' .. . .,,,,;. uo/ko ,u,;-1-} un/ko
nitrosodirrethvlamine ,,,, ::n,,., ,, I A IA
s (2-ch 1 oroethv l l ether
-chlormhenol
I encl
3-dichlorobenzene
4-dichlorobenzene
l 2-dichlorobenzene
s (2-<:h loroi <nnrnnvl lether
xach 1 oroethane
N-nltroso--<11-n....nr<Y'lvlamlne
lobenzene
hcrone
t~henol
2 4-dirrethvlohenol
lisf2-<:hloroethcxvlrrethane
4-di ch loroohenol
l 2 4-trichlorobenzene
lt!hthalene
achlorobutadiene
-
4-<:hloro-m-cresol f :"ch 1 orocvc 1 ~ntad i ene
4 6-trichloroohenol
-<:hloron>nhthalene
acenanhthvlene
lirrethvl ohthalate
,.6-dinitrotoluene
acenanhthene
.,4-dinitroohenol ;,,,.so SO/
, .4-di ni.troto luene u, 'l'lO
4-n i trooheno 1 l,O/tt.<:o
1
luorene /0/:/30
l--<'.h 1 oroohenvl ohenvl ether
iethvl ohthalate ,,
4.6-dinitro-o--cresol -ra ~,
iohenvlamine /()1'330
zobenzene
4-braroohenvlohenvlether
ltxach 1 orobenzene ,
ntachlo~henol s-0/11.5"0
ohenanthrene //1/330 I I
1 nthracene I
ibutvl ohthalate I 0/C. JOI" I /
1 uoranthene ' LA--l,A-
m1>L
I = Estim.1ted value. H,.o/S0/1-
-Actual value is known to be less than value given.
L -Actual value is known to be greater than value given.
( )
uo/1 .. n/ko
-Material was analyzed for but not detected. The nurber
-Not analyzed.
is the 11ininun Detection Limit. mXJL -----Tentative identification.
_ -On NRDC List of Priority Pollutants.
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un/ l un/ko
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STATE LABORATORY OF PUBLIC HEALTH
P.O. BOX 28047 -306 N. WILMINGTON, ST., RALEIGH, N.C. 27611
ORGANIC CHEMICAL ANALYSIS
BASE/NEUTRAL ANO ACIO LAB NO '-1lol3.).4 l//,,/3 ~ I 771;; I ~-1 3 0/.. / ~ '.l,
EXTRACT ABLES FIELO # Ir.JI,</~ /q /_ ..-, I'll .::-"< /"ff/ <, .)
aJl1f'(XJN0 TYPE r,..J ) r -;;, l ( t., ) (L !)
UNITS rua/ I ~-"·-.. n/J'\,~ .. /ka ,-.,.v ,n/ka,
"'"rene /0/~30 ,, -lA..-, (A_.: I -
benzidine ,11/1160 t/L--v<--
butvl benzvl nhthalate /0/3'10 JOV IO t'
benz(a)anthracene IA--LA-
chrvsene .,, r I,
3.3-dichlorobenzldine 'It.. '>J'J so, v' "y
bis(2-ethvlhexvllohthalate 10/330 fOt' I O ""
di-n--0etvl nhthalate 1/0/.130 ,,. IA-
benzo(blfl uoranthene so ✓d-..
benzofklfluoranthene
benzo(a)nvrene
indeno(l 2 3-cdlnvrene
dibenzo(a.hlanthracene , , I I
benzo(a h i 1=rvlene ' ' ' I \
aniline ro ,. L lA. I lA----LA-
benzoic acid
benzvl alcohol
4-chloroaniline .. ~
dibenzofuran /() 1.33c.
2-methvl=nhthalene
2-methvlnhenol
4-methvloheool ,,
2-nitroani 1 ine s-oht-<o
3-nitroani line
4-ni troani 1 ine I / / /
2.4.5-trichloroohenol ~:, \ ' I \ I/
, '
mJ)t..
J -Estimated value. H2.0/ Seit.
K -Actual value is known to be less thdn value given.
L -Actual value is known to be greater than value given.
U -llaterial was analyzed for but not detected. The nuroer is the Minirrun Detection Limit.
NA -Not analyzed.
1/ -Tentative identification.
~/ -On NROC List of Priority Pollutants.
( ) ( )
,nf 1· ••-/kn · -/ 1 ""/ka .
fl'lJ)t.. -
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~toION: IV , PROJ._ L,EADER: DOUG MOORE·
. ACTIVITY: SI
REGION: IV COMPANY: SUPERFUND
SPILL IO:
SUPERFUND
CHAIN-OF-CUSTODY RECORD
PROJECT ID:
SITE NAME: Cherokee Oil Company
CITY, STATE: Charlotte/Mecklenburg, NC
DATE SHIPPED: I I
AIRBILL:
SHIPPED TO:
ATTN:
PHONE:
LAB SAMPLE ID STATION --------------------------------------C0-001-SB
HET ALS( 2) C0-001-SD
HETALS( 2) C0-001-SL
HETALS(2) C0-001-SW
HETALS(2) C0-002-SB
HETALS(2) C0-002-SD
METALS(2) co-002-sw
METALS(2J C0-003-S
METALS( 2) C0-003-SD
METALS(2) C0-004-SL
METALS(2) C0-005-SL
METALS( 2) C0-006-SL
METALS(2~ C0-007-P
HETALS( 2)
CARRIER:
DESCRIPTION MATRIX DATE/TIHE SAHPLER
RECEIVED
MAY 2 21996
SUPERFUND SECTION
==============-==-=-=-=====-============ =============== =------------=---======== Background Subsurface soil Subsurface Soil 03-06/1515 DOUG HOORE
(2) co-9, 9
Background sediment in UT to Stewarts Cr 5ediment ( 2) co-24, 24
Background Surface Soil
(2) -3, 3
Soil
Background surface water in UT to Stuart 5urface Water ( 2) co-27, 27
03-06/1410 DOUG RUHFORD
03-06/1501 DOUG HOORE
03-06/1430 DOUG RUMFORD
Subsurface Soil Area #I
(2) co-6, 6 Subsurface Soil 03-06/1150 DOUG HOORE
Sediment at PPE in UT to Stewart's Crk. 5ediment 03-06/1340 DOUG RUHFORD (2) co-30, 30
Surface water below PPE in UT to Stewart Surface Water 03-06/1350 DOUG RUHFORD (2) co-33, 33
Subsurface soil Area 12 (2) co-12, 12 Subsurface Soil 03-06/1240 DOUG MOORE
Sediment at drainage culvert between PPE Sediment ( 2) co-36, 36
Stained Surface Soil Area 13 (2) co-15, 15 Soil
Surface soil in drainage ditch
(2) co-18, 18 Soil
Surface soil near NW corner of Sub. Prop Soil (2) co-21, 11
Preserv. Blank (1) co-38, 38 Water
03-06/1130 DOUG RUMFORD
03-06/1105 DOUG HOORE
03-06/1430 DOUG MOORE
03-06/1415 DOUG MOORE
03-07/1130 DOUG HOORE
I White -LAB Copy for Return to Samplers Yellow -LAB Copy Pink -Sampler's Copy Gold -Extra Copy
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t'!.C. D.cpanc:;cnt c,( Environr:1cnt,
! k:ilth, & i',':il11r.1! Resources:
SAiY!PLE ANALYSIS REQ,JEST
Sc-lid W:istc Man.!gc~cnt Di,,.ision
Site Number
Name of Site
CO·OO!·SL 03/06/96 1501 GRAB
Cherokee Oil Company, NC
BACKGROUND SURFACE SOIL
ESD LAB ME1ALS Soil
DOUG MOORE Numbt:r
S1Jtc Labo:-.i.tor/ v( Publi( 1-lc:.ilth
P.O. Box 2W.l7, J.C'6 N. Wilmington _Street
R.a!ci~h, North Carolina 27611
------------------
Collected By_
3 e.d 1',·n,c _ ___ ,_, ... ,.., ..... vu,.;.1..L ___________ _ _____ _
Ageacy: Hazardous Waste Solid Waste V Superfund TCLP Compounds
------
Sample Type Inot-g~rnic Compounds Rcsults(mg/1)
Environmc11ta! Concen{rate Comments V Arsenic -<c-~1
✓Barium Cl .;,9 --
Ground water (1) _ Solid (5) ✓Cadmium ...::.o ,a5 --V Chromium ""'-O.u5
Surface water (2) _ Liquid (6) vLead ..(.C) .. ·\a --
✓soil (3)
~ercury -<.c,cJ
_ Sludge (7) v Selenium _"!5-tJw,~c1
v""S i h• c r .(.o. o5
Other (4) _ Other (8) . ,/' l<2f'f'.~• ..£....c .. c.'1 ~ °2-l"1V Q-◊-, --
--
Organic Chemistry Inorganic Chemistry --
Parameter Results(mg/1) Parameter Rcsults~)(mg/kg) Organic Compounds Results(mg/1)
P&T:GC/MS v" Arsenic ;;l.8 benzc,1c --VBarium
--
Acid:B/N Ext. ) di q carbon Letrachloride ----MTBE V-Cadmium -<-He! chlordane ------Chloride ch!orobcnzcnc ------
--V---Chromium J.'.J chloroform --
--V--Coppcr .3':\ o-cresol --Fluoride m-crcsol ------
--Jron p-cresol ----
--..,,-Lead '] C:, crcsol ----
----Manganese --1, 4-dichlorobcnzene
--.......-Mercury < D., I --1,2-dichloroethane
Nitrate 1, 1-dichloroethylcne ------vSelcnium ... , 2/1-dinitrotolucnc. --vSilver .,_ 'I 0 --hcptachlor
Rad iochcmistry Sulfates -hexochlorobcnzene ----···-✓Zinc 5~ hex;ich lo robu t :1 d ic.nc ----P,1rn11u.:ter Results (l'Ci/1) pH hcx:ich loroct ha ne ----
__ Gross Alpha __ Conductivity --methyl ethyl ketone
Gross Beto TDS nitrobcnzcnc -------TOC pentachlorophcnol . , ----
----pyridine
!l'licrobiology ----tel rach lo roe t hylcne
trichloroethylcnc -----P,1rar11etcr Results (Col/1001111) --__ 2,4,5-trichlorophcnol
2, 4 ,6,t richlorophcnol ------
------vinyl chloride
cndrin --lind:inc. --· Date 1'.ccci>.crl ---· Rcpnrlcd by --c1cthoxych!or
--to:c::phl'.nc
Dale 1:.x:.r:1ctcd D:1tc Rcp,irlcci_J.1-~,~lli 2,rt-D
GOJ~:14 1-•,!, • IG 2'5Tl'(S1., .. ) __ ,'', • , L,,C,'.
I){! ( C ,'\ 1i :i l )"/.Cd ·--·----··· ·•····•·· ----L;1h N11mhcr --·--·--·--·----------· ------------·------------------------•·------'': '<; ~ •.•
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l'\.C. D.cpartmcnt of Environment,
· ! (c.'.lllh, & f\.'atura! Resources
Solid Waste Managcn:icnt Division
SANll'LI~ ANA.LYSIS REQUEST
Site Number
Name of Site
C0-002-SB 03/06/96 1150 GRAB
Cherokee Oil Company, NC OOUG MOORE
SUBSURFACE SOIL AREA II
ESO LAB METALS Subsurface Soil
Number
Stalc L1bor,uory of Public Hc:i.lth
P.(l. 11::ix 2.S0-:7, 306 N. Wilmington _S1rcct
R.alcit:h, North Carolina 27611
------------------
Collected By_
co-6 ______ .ed ___________ Time ______ _
Agency: Hazardous Waste Solid Waste ✓ Superfund TCLP Compounds ---------
Sample Type 1/anic ~ornpo11nris Rcsults(mg/1)
Environmental Concentrate Comments Arscrnc .<!.,:, •• cl
-;:?" Barium 0.15
__ Ground water (1) _ Solid (5) vCadrnium --<-a ,o':J
✓."Chromium L-...o .. c,5
__ Surface water (2) _ Liquid (6) ...J:'.:'.'.:' Le ad "'--0-\0
vl'-frrcury ..e:. C,, Q\
V Soil (3) _ Sludge (7) 1,/"Selcnium -~c. .. ec~·
V Silver <o ... Q.5
_ Other (4) _ Other (8) 7 C.,,t¥-r-~c~cQ ✓ .,&_rl"' c.·3~
--
Organic Chemistry Inorganic Chemistry --
Parnmeter Results(mg/1) Parameter Results~ (mg/kg) Organic Compounds Rcsults(mg/1)
__ P&T:GC/MS ~ Arsenic J _<,_ benzene --
--Acid:ll/N Ext. vllarium 8:Z carbor, tetrachloride ----
MTBE ,./Cadmium 410 chlordane ----Chloride chlorobenzenc --VChromium --30 chloroform --✓copper --
--l.2. o-crcsol --Fluoride m-crcsol ------
--Jron p-crcsol
✓Lead S' &' --
--crcsol ----
--Manganese 1,4-d ich lor obcnzenc --,,/Mercury --C: o. I 1,2-di chlo roct hane --Nitrate 1, 1-dichloroethyicne --VSclenium
--...:. 1 2)4-dinitroto!ucnc . --........-Silver <...\Q heptachlor ----Radiochemistry Sulfates -hcx3.chlorobcnzcne
.;;-zinc
--...• "12. hcxach !orobut ad ienc --
Parameti.:r Results (l'Ci/1) --pl-! hcxachlorocthanc --__ Gross Alpha --Conductivity --methyl ethyl ketone
Gross Beta TDS nitrobcnzcnc ------TOC __ pentachlorophcno! .. --
----pyridine
l\-1 icrobiology --__ tctrachloroethylcnc
--__ trichlorocthylcnc
Parameter Results (Col/100111\) --__ 2,1\ ,5-trich lorophcno I
----__ 2,4,6-trichiorophcnol
------vinyl chloride
endrin --l i ri d.:i.nc. --Dale Rccci\·cd Reported by mclhoxyd1!or --
to:c:iphcnc ---Dale [;..:lrJclcd Dale Rcpor Led 2,,:-D ---on11-1s Ml,R-1PTb "'\Tr(S"···· --,.,-,,. -, ,, ,c.<J
D,dc r\n:ily.1.c.d Lah Number ·----------------. ··--······ ···--· ··-·····--··-----·----1·1! ::; ,: .i (i·'.:.:·-;·:, ·: ~ .1 J\'
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.N.C. Clt:partmcnt of Env-ironmcnt,
1 ic:ilth, & Nalur:i! Resource~
Solid Waste Managc~cnt Division
SA.tvlPLE ANALYSIS REQUEST
Sile Number CO·OOl·SB 03/06/96 1515 GRAB Number
Name of Site
Cherokee Oil Company, NC DOUG MOORE
BACKGROUND SUBSURFACE SOIL
ESD LAB METALS Subsurface Soil
co-9 Collected By -----------
Agency: Hazardous Waste Solid Waste V Supcrfund -----
Sample Type
Environmental Concentrate Comments
__ Ground water (1) _ Solid (5)
--Surface water (2) _ Liquid (6)
✓soil (3) Sludge (7)
_ Other (4) Other (8)
Organic Chemistry Inorganic Chemistry
Parameter Results(mg/1) Parameter Resu!Lib; g;lll1!f:. 6/kg)
P&T:GC/MS / Arsenic 'L:':l --/Barium --Acid:B/N Ext. lc8 --MTBE ✓Cadmium ""-\Cl ----Chloride ----V Chromium 3o --
--V---coppcr 5 .'.}.
Fluoride ----Iron ----'J.n ,,,---Lead --
----Manganese
--V" Mercury < D, i Nitrate ----.__,...Selenium ~,
V---Silvcr ..:, I 0 ---Radiochemistry Sulfates ---.... V---Zinc (,_ 2.
Paramelt.:r Results (PCi/1) --pH
__ Gross Alpha __ Conductivity
Gross Beta TDS ----TOC --
--lVl i cro biology --
--Par:.imcler Results (Col/J00ml) --
----
----
Date Rccci·:cd Repented by
D:tlt.: t:xtractcd D;1tc Rmortcd . ~• 0 B 96 _ :011 ~S-t ,Hi\
Dr!lc: A11:1!y·1.cd LJh Number --·----------------· ----··--------·-· 1"11 .... ~ ''): ! .. ' .. , -
Sc.1tc L.ab?r,l.lory o( Pu~.,~ H:::d1h
P.O. no, l&J.:7, 3C~ "<. Wilm,c,gton Stccc:
R.a!cibh, Nert~ Carolina 27611
------------------
. TCLP Compounds
. Inorganic Compounds Rcsults(mg/1)
vArscnic 4c.c/
✓Barium o-"14 --v Cadmium L.O. ~25
~ Chromium ..,(o .. oS
,._.,,-Le ad L..0-,o
V---Mercury ...:::. ~--.::::::)
✓Selenium __ .L... c. ccS
V---Silver .L...o ... a.5
/ (',,~~v ,..,__ 0 -<::, :;i
✓-z.~,. b . 1 -;;,..._
--
--
Organic Compounds Results(mg/i)
bcn?.cnc --carbon tetrachloride --ciilor-dane --chlorobcnzcne --chloroform --o-cresol --rn-crcsol --
--p-crcsol
crcsol --1,4-dichlorobcnzcne --1,2-dich lorocthanc --1, 1-dichloroethylcnc --2,4-dinilrotolucnc . --
--heplaehlor
hexachlorobenzcnc --hcx,1ch !orobu lad ic nc --hcx:ichlorocl hanc --methyl ethyl ketone
--nitrobenZenc --
--penlachlorophcnol . '
--pyridine
tetrachlorocthylcne --
t richlo roct hylcnc --2, •\ ,5-tric hlorophcnol --2, 4 ,6-t richlorophcnol --
--,inyl chloride
cndrin --linr.lanc --rncthoxych!or --tox:!ph:..:11:..: --2,t.-D -·-2,•l,5-TP (Si!·:c.x)
-------·····--------···--·• --·· ------·
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.~'.C. Dcpc1rtrncnt of E:1vi:0,1mcnc,
! !c::ilth, & Natura\ Resources
Solid Waste ManJgc~cr.t Division
SAMPLE ANALYSIS REQUEST State L1bor..itory o( Public Hc~lth
P.O. nox 2SO•l7, 306 N. Wilmington .Strc~:
Raleigh, North Carolina 27611
Site Number C0-003-SB 03/06/96 1240 GRAB
Cherokee Oil Company, NC DOUG MOORE
Number _________________ _
Name of Site SUBSURFACE SOIL AREA 12
-ESD LAB METALS Subsurface Soil
co-12 Collected By _________ _ .ed Time ------------------
Agency: Hazardous Waste Solid Waste /superfund TCLP Compounds ------
Sample Type Inorganic Compounds Rcsults(mg/1)
Environmental Concentrate Comments v Arsenic ~C-C i --V Barium \ .. :l,J
Ground water (1) _ Solid (5) ~ Cadmium -<-o-c,S --~Chromium L.Q. s;-_n
Surface water (2) Liquid (6) ✓Lead -<'... t, -\ 0 ----V-Mercury --t.. c.c1
VSoil (3) Sludge (7) vSclenium -.l...c.,c--Qs; v Silver ..<:...0-05
_ Other (4) _ Other (8) .,,,.-&ef!_&,/ L..c.,c~
v -;2.,-,,., b • c:f'l --
--Organic Chemistry Inorganic Chemistry --
Parameter Results(mg/1) Parameter Rcsult:IJ rn'li (mg/kg) Organic Compounds Results(mg/1)
_F&T:GC/MS ✓ Arsenic ;), bcnzcn:: ----__ Acid:B/N Ext. ✓ Barium 'J, '-\ carbon tetrachloride ----MTBE v' Cadmium -<-IQ chlordane ------Chloride ch!orobenzcne ----✓Chromium --:~8 chloroform --
--v Copper l.\t'a o-crcsol --
fluoride m-crcsol ------
--Iron p-crcsol ----.,.-Lead ~)_ (\ crcsol ----
----Manganese --1, 4-dich lorobcnzenc
--vMcrcury c o, i --1,2-dich loroeth a nc
--Nitrate __ 1, 1-dichloroethylcnc --
vSclenium ~1 2/4-dinitroto!uenc. --V-Silver ... hcptachlor ..:_ l~ -----Radiochemistry Sulfates -hcxachlorobenzene --✓zinc -'4i::l hc.xach lorobut ad icnc ----
P,irameter Results (PCi/1) pH hcxachlorocthane ----__ Gross Alpha __ Conductivity --methyl ethyl ketone
Gross Beta TDS nitrobcnzcnc ------
TOC __ pentachlorophcnol ' ----
----p)Tidinc
!vlicrobiology ----tel r a chloroc th ylcne
--__ trichlorocthylcnc
Para111cler Results (Col/l00ml) --__ 2)4,5-trichlorophcno!
----__ 2,4,6-trichlorophcnol
------,inyl chloride
enUrin --lindanc. --O:ltc Rc:cc:ivcci Reported by --mcthm:ych!or
tox:ipk:nc --D,1tc !:xtr:1Clcd Date Reported 2,tl-D
001~-1•;rrf;:1f 8 Y 6 2 •' \-Tf' (,''··n) --,',· •-'".
Dale f\n:i!y-.(cd L1l1 Number ----------------------· ·--------------~--·-•---------''\: : <.; 1: ij' :,•.-. : ... ,; ·_:,•.···
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! knllh, & Natural Resources
Solid Waste Man:igcn:icnt Di\ision
SA.tv1PL:C: ANALYSIS REQUEST
Sile Number
Name of Site
C0-004-SL 03/06/96 1205 GRAB
Cherokee Oil Company, NC DOUG HOORE
STAINED SURFACE SOIL AREA 13
ESD LAB METALS Soil
Number
St:1:c L.1bor.i.to1y of Public Hc:ilth
r.O. Box 2.so-:1, 3{Xi N. Wilmi:igton _Sln:ct
R.alcil;h, North Caro!ine. 27611
------------------
Collected By
co-15 .e<l Time ------------------------------
Agency: Hazardous Waste Solid Waste ✓ Superfund TCLP Compounds ---------
Sample Type lnoq;anic Compouncl.s Resulls(mg/lj
Environmental Concentrate Comments ✓ Arsenic -<'..c cl --
✓ Barium t) .. Cr
__ Ground waler (1) _ Solid (5) V Cadmium <C.,Q s-
vChromium < 0-(2\
Surface water (2) _ Liquid (6) ,_.,..--Le ad b, 1.o ----
/soil (3)
.....---r,,f e r cu ry L... a .oJ
_ Sludge (7) V-Sclcnium < c.cc5 --vSilvcr < Q' t> \
_ Other (4) _ Other (8) ✓ ~,c..--< O, ,, :cl
v---z,;.., LL, 1~
--
Organic Chemistry Inorganic Chemistry --
Parameter Rcsults(mg/1) Parameter Res11lti.t(_ g;\'4(mg/kg) Organic Compounds Results(mg/1)
___ P&T:GC/MS V Arsenic ,J.5 benzene --__ Acid:B/l\ ExL vBarium
'" 0
carbon tctrnch!oride --MTBE ✓Cadmium L_C\.6 chlordane ------Chloride chlorobcnzcnc ----✓Chromium --5·5 chloroform --
--✓Copper ,5,5 o-crcsol --Fluoride m-crcsol ------
--Iron p-crcsol ----✓Lead ' • r' crcsol ----,I,.) 0 --
--__ Manganese . --1, 4-dichlorobcnzcnc
--..----1-1 er cu ry 6-l'J... --112-dich lorocthJnc
Nitrate 1, 1-dichloroethylcne ------vSelcnium ~, 2,4-dinitrotolucnc.
,;.---Silver --
L. 9.8 -heptachlor ----Radiochemistry Sulfates -hcxachlorobcnzcnc ----,.,....-Zinc l,,. cc hexach lorobu I ad i c ne --Parameter l{csulls (PCi/1) pH hcx::ichloroclhJ.nc ----__ Gross Alpha --Conductivity --methyl ethyl ketone
Gross Beta TDS nitrobcnzenc ------TOC __ pcntachlorophcnol ' --
----pyridine
tvl ic rn biology --let rachlorocth ylcnc --
--__ trichlorocih)-lcne
Parc.11netcr Results (Col/lOOml) 214,5-trich loro ph cnol --
----__ 2,4,6-trichlorophenol
------,inyl chloride
endrin --lindanc --D.itc R:cci1:cd Reported by --rncthm,)1chlor
tox:!phcn:.: --D,llc Ext r ;ictcd Date Rcpi)rtcd 2,•1-D --nn11.~,-'Jlf}J! 8 9/i __ 2,4,5-TI' (Si!·:cx) -l),,tc .:\n:1\y-1.•:,d Lah Number ----·---·---·----·---·---------------------t • ' J '. ~ ·'.
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!\.C. Dcpn1trncnt of Environment,
! lcJlth, & ;\'atur:;l Resources
Solid Waste M:1n:1gcrT_lC)"t Division
SANlPLE ANALYSIS REQU,£ST
Site Number C0-005-SL 03/06/96 1430 GRAB
Cherokee Oil Company, NC
SURFACE SOIL IN DRAINAGE DITCH
Name of Site_ ESD LAB HETALS Soil
DOUG HOORE Number
St:itc !_.1b0:-ato1y of Publii: Hc:1l1h
P.O. Oox 2&}!7, ].C() N. Wilmingto:"i _St:-c~l
Raleigh, North Carolina 27611
------------------'-
co-18
Collected By _________ _ ,V(l~,._, '--'v111.,1.LCd Time ----------------------
Agency: Hazardous Waste Solid Waste V Superfund TCLP Compounds -----
Sample Type Inorganic Compounds Results(mg/1)
Environmcntnl Concentrate Comments v Arsenic <c.cl --v Barium (l, L[ i
__ Groundwater (1) _ Solid (5) ~ Cadmium < Q, C! :;-
vCbromium < C,, QS-
__ Surface water (2) _ Liquid (6) ✓Lead < o, Lo
Vsoil (3)
v !Acrcury .L,:,,_c}
_ Sludge (7) LSclenium -· .-:..c.cc:'.;i
v Silver < ci. a,C
_ Other (4) _ Other (8) ✓-~r :C:: o, o 1
✓ -z,-,,,,,,. £, 76
--
Organic Chemistry Inorganic Chemistry --
Parnmctcr Rcsults(mg/1) Parameter Rest• ltz .. if (mg/kg) Oq~anic Compounds Results(mg/1)
_P&T:GC/MS ✓ Arsenic benzene --__ Acid:B/N Ext. __....-Barium Gz:'J carbon lctracbloridc --.MTBE ✓Cadmium -'-9,8 chlordane ------Chloride ch!orobenzcnc ------✓Chromium 11.c chloroform ----
--V-Copper 55 o-cresol --Fluoride rn-crcsol ------
--Iron p-crcsol --1D --
--vLead ere.sol --
----Manganese --I, 4-dichlo robcnzenc ..
--v Mercury < 0, I --1,2-dichlorocl hanc
Nitrate I, 1-dichloroelhylcnc ------.,--Selenium .-<.' 214-dinitroto!ucnc. --vSilver .-,:, 9 .8 -heptachlor ----
Radiochemistry Sulfates -hcxachlorobcnzcne ----.,_.,,.✓7.: i n C (.:: 3,--, hcxach lornbu I ad icne --Paramder Results (!'Ci/I) pH hcx:ichloroclhane ----__ Gross Alpha __ Concluctivily __ methyl ethyl ketone
Gross Beta TDS nitrobcnzcnc ----TOC __ pcnlachlorophenol : ~ --
----pyridine
l\-licrobiology --tctrach lorocthylenc --
--__ trichlorocthylcne
Par.:imder Resulls (Col/lOOml) __ 2,<1,5-tric h lorop hcno I --2, 4 ,6-trichlorophcnol ------
------,inyl chloride
cndrin --lindanc. --Dale Rccci-.cd Reported by 10,cthoxychior --
--tox::pbcn:..:
Dale ExLr~ictcd Dale lj..-rrtc:d "-ftKJ 2,,:.[)
8 96 --\ • '1 ~ f"•1 111 I o,; S Tl' 'S" , ··) J :.:i "'~ ~-.. .I '' . •·, '' -~' '• , C,\
D;l!c ,'-\11:1\·.,.cJ L1h Numhc.r --~---··· ------------------------~--· ----~------------; 'I I•.: ~ • lr'"
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~-C. C.cpnrtmcnt of En,,,in:>nmcn!,
! !callh, & Natural Resources
Solid Waste Man::igc1T)Cnt Division
SA1\1PLE ANALYSIS REQUEST
Site Number
Name of Site
C0-006-SL 03/06/96 1415 GRAB
Cherokee Oil Company, NC DOUG MOORE
SURFACE SOIL NEAR NW CORNER OF SUB. PROP
ESD LAB METALS Soil
Number
State 1. .. ,boratory of Public HcJith
P.C. Dax 2S047, 306 N. Wilming1on _Street
Raleigh, North Carolina 27611
--------------
co-21 Collected By _________ _ cd T~e -------------------
Agency: Hazardous Waste Solid Waste ✓ Superfund TCLP Compounds ------
Sample Type Inorganic Compounds Results(mg/1)
Environmental Concentrate Comments VArscnic .(c_ol
✓Barium [), yq --
Ground water (1) Solid (5) ✓ Cadmium < ' --C, c, C.-
v·cnromium <o,oC:-
__ Surface water (2) _ Liquid (6) ✓Lead < (i, It, --
/ Soil (3)
✓Mercury L.. C •= \
_ Sludge (7) ✓~Selenium ""-D~ce:...5
v Silver < Q' ,; -\
Other (4) _ Other (8) ✓<"ff',.-
-;:7 "2-irr e-
.( Q, Q" -;; ,7: 8
--
Organic Chemistry Inorganic Chemistry --
Pura meter Results(mg/1) Parameter Restdts,'3 gj4; (mg/kg) Or-ganic Compounds Results(mg/!)
P&T:GC/MS V Arsenic ;J,.9 bc.izcnc --✓Barium --
--Acid:B/N Ext. 57 ca,bon tetrachloride --
MTBE .,;/Cadmium --L. 9.8 chlocdane --Chloride chlorobcnzcnc ------✓ Chromium '-'t 1 chloroform ----
--..,.,...-Copper 37 o-cresol --Fluoride m-crcsol ------
--Iron p-cresol --76 --
--,.,.,.-i__,ead {I crcsol ----
--__ Manganese 1,4-dichlorobcnzcnc < o, I --
--v-'1'-krcury 1,2-dich loroethanc --Nitrate I 1, 1-dich loroeth ylene ------✓Selenium -<'' 2,4-dinitrotoluenc _ --✓silver ..c:.9.s -heptachlor ----
Radiochemistry Sulfates -hexachlorobenzcne --vZinc ,1'90 hexach lorobu tad icn e ----Parameter Results (PCi/1) pH hexachloroet bane ----__ Gross Alpha Conducti,oty methyl ethyl ketone ----Gross Beta TDS nitrobcnzenc ------TOC pentachlorophcnol . , ----
----pyridine
!VI icrobiology ----tctrachloroet h ylcne
--__ lrichlorocthylcnc
Parameter Results (Col/I00ml) --__ 2,4,5-trichlorophcnol
2, 4 ,6-t rich loco phenol ------,inyl chloride ------endrin --lind:inc --Date Rccc,•.cd Reported by r,-.:::thoxych!or --tc;,:::phl'.nc --[\ilc [xt1-~1ucd Date Reported 2_.:. I) o o J rtso-111,n-% --
? •' 5-TP (S""c..-) --~.,' . \,,"
Dale Ari:1!y-1.cd L1h Nurnhu --·----··----~-----··----·-··-----·------·----; \ ! "•: '1,: 1 ,' ;; •' ': ,.,.
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f-:.C. Dcpnrtmcn! oi Environment,
J !t:.:lth, & Natural Resources
Solid Waste Managcr:.icnt Division
SA.MPLE ANALYSIS REQUEST
Site Number CO·OOl·SD 03/06/96 1420 GRAB Number
Cherokee Oil Company, NC DOUG MOORE
Name of Site BACKGROUND SEDIMENT IN UT TO STEWARTS CR
-ESD LAB METALS Sediment
co-24 Collected By _________ _
Agency: Hazardous Waste Solid Waste ___ Superfund -----
Sample Type
Environmental Concentrate Comments
Ground water (1) --_ Solid (5)
. __ Surface water (2) _ Liquid (6)
--Soil (3) _ Sludge (7)
/ Other (4) _ Other (8)
{ :Se,J(,.,-r ")
Organic Chemistry Inorganic Chemistry
Parameter Results(mg/1) Parameter Results~mg/kg)
_P&T:GC/MS V Arsenic ~,,'.1 --__ Acid:B/N Ext. vBarium ,3:),
MTBE ✓Cadmium <10 ----Chloride --vChromium L.. ,o --
--✓Copper .3.;;,
Fluoride ----Iron ----
--v-1.ead < ✓ () --
. __ Manganese --
--v'1v!ercury .. < 0, i
Nitrate --VSclenium L.. l
✓silver -<'...1C --Radiochemistry Sulfates -
V"L,inc ;J.S --P;irarnctcr Results (PCi/1) pH --__ Gross Alpha --Conductivity
Gross Beta TDS ----TOC --
--!vl ic ro bio Io gy --
--Parameter Results (Col/!O0ml) --
----
----
Ot'\tc Received Reported by
Date. E:-:lr:tCltC Date Rcr,.oJtccl rl:r';R-B g b 01JJ4S2. · " , ·
l);l[c i\n;ily·l.cr_'. Lah Number -·--------------·---------------I '; I'; .1; ,; 1 ( :.:r-::
Stale L.abor.itory of Publi.: ·. ;cJilh
P.O. Box 2S0,17, 305 N. \1/ilmington .Strc:~\
Raleigh, North Carolina 27611
------------------
TCLP Compounds
Inorganic Compot!ncls Resulls(mg/1)
Arsenic --Barium --Cadmium --Chromium --Lead --
--Mercury
Selenium --Silver --
--
--
--
--
Orbanic Compounds Results(mg/1)
bcn7.cnc --carbon lctrachlori<le --chlo, dane --chlorobcnzenc --chloroform --o·crcsol --m-crcsol --
--p•crcsol
cresol --1.4-dichlorobcnzene --1,2-dich lorocthanc --l, l•dichloroethylenc --214-dinitrotolucnc. --
--heptachlor
hcxachlorobcnzcne --hex;ich lo rob u tad icne --hcx;ichloroethanc --__ methyl ethyl ketone
nitrobcnzcnc --__ pcntachlorophenol . ,
--PJTidinc
tctrachloroc th ylcne --__ trichloroeth)'icnc
__ 2,·1.5·trichlorophcnol
2, 4.6•tri chlorophcnol --
--vinyl chloride
cndrin --lind:rnc --r-;s,~thm,)1ch!or --to:r:::phcnc --2.•l-D --__ 2::.5.TP (Si!·,cx)
--------------·--
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N.c. Department of En\ironmcnt,
I li..:.iith, & Natur;il Resources
Solid \Vaslc Manlgcn:icnt OiV1sion
SAMPLE ANALYSIS REQUEST St:itc !..abor.itory o( Public Hclllh
r.o. Oox 2&}17, X/i N. Wilmington _Slrt.Cl
R.atciih, North Carolina 27611
Sile Number co-002-so 03106/96 1340 GRAB
Cherokee Oil Company, NC DOUG MOORE
SEDIMENT Al PPE IN UT TO STEWART'S CRK.
'lumber _________________ _
Name of Site ESD LAB METALS Sediment
co-30 Collected By _________ _ :d Time -----------------
Agency: Hazardous Waste Solid Waste ✓ Superfund TCLP Compounds ------
Sample Type Inorganic Compounds Rcsul ts (mg/I)
Environmental Concentrate Comments Arsenic --Barium --
Ground water (1) _ Solid (5) Cadmium ----Chromium --Surface water (2) _ Liquid (6) Lead ----Mercury --
Soil (3) _ Sludge (7) Selenium -----··· Silver
/ Other (4) _ Other (8)
--
--{5d,.rYU,<,(I-I --
--
Organic Chemistry Inorganic Chemistry --
Parrimcter Results (mg/I) Parameter Rcsults~(mg/kg) Organic Compounds Results(mg/1)
_P&T:GC/MS VArsenic -< ~ benzene --Acid:B/N Ext. v"Barium 8-b carbon tetrachloride ----MTBE .......--Cadmium -"--)0 chlordane ------Chloride chlorobenzcnc ------
.....-Chromium J..~ chloroform ----
--...---copper '4 ~ o-cresol --Fluoride m-crcsol ------
--Iron p-crcsol ----
--.,.-Lead ( J ,; crcsol ----
----Manganese --1,4-dichlorobenzene
--✓Mercury < ,0,/ --1,2-dichloroct h ane
Nitrate 1, 1-dichloroethylene ------v'"'Selcnium .L,\ 2,4-dinitroto!uenc.
...,_.-S il v e r --~,o heptachlor ----
Radiochemistry Sulfates -hexachlorobcnzcne ----.... VZinc "'I 5 hcxachlorobut ad icne ----
P,iramcler Results (PCi/1) pH hcxachlorocthanc ----__ Gross Alpha __ Conductivity --methyl ethyl ketone
Gross Beta TDS nitrobcnzenc ------T0C pentachlorophenol .. . , ----
----pyridine
!l'!icrobiology ----tetrachloroe th ylcnc
--__ trichloroethylcne
Parameter Results (Col/1001111) 2, 4,5-trichlorophcnol ----2, 4,6-trichlorophcnol ------
------,,nyl chloride
cndrin --lindanc --D:1!c l<.c:cci\·cd Reported by --rncthoxych!or
toxziphcnc --
D:1tc l:xtr:1ctcd D:1lc. Rclorlcd 2,,:.1) on, ~r:T-Mf,'l 8 96 --
• : J ··•.;,_,._J;f.; I \/', __ 2,,1,5-TP (Si!·:cx)
D:llc ;\rn!y·,1.cd Lah Number· ·--··-----------':: I\ 1 !'i \ (!·'.-" : .• ,'. _l_f'!.
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i'-'.C. l)·cpnttmcnt of Environmc:nt,
! !t;a\th, & Natural Resources
Solid Waste Managcn:cnl Di\isi~n
SAMPLE Al'\,-LYSIS REQUEST
Site Number
Name of Sile
C0-003-SD 03/06/96 1230 GRAB
Cherokee Oil Company, NC DOUG HOORE
SEO!HENT AT DRAINAGE CULVERT BETWEEN PPE
ESO LAB METALS Sediment
Number
Stale Labor,Hoiy of Public Hc~!th
P.O. Gox. 2&0-:7, 306 N. Wilming!on _Street
J\lllcigh, North Carolina 276tl
------------------
co-36
u..--rr uaLe 1._.ouccted Time -----------------------Collected By _________ _
Agency: Hazardous Waste Solid Waste / Superfund TCLP Compounds ------
Sample Type Inoq~anic Compounds Rcsults(mg/1)
Environmental Concentrate Comments Arsenic --Barium --
__ Groundwater (1) _ Solid (5) Cadmium --Chromium --
__ Surface water (2) Liquid (6) Lead --Mercury --
_ Soil (3) _ Sludge (7) Selenium --Silver
/ Other (4)
--
Other (8) --
(!.uJ;,...,._--f--) --
--
Organic Chemistry Inorganic Chemistry --
Parameter Resulls(mg/1) Parameter Rcsults~)(mg/kg) Organic Compounds Rcsults(mg/1)
_P&T:GC/MS _L_ Arsenic ;;I. D ben7.cnc --__ Acid:B/N Ext. __.l<'.'.'.:Barium 'lo carbon tetrachloride --MTBE vCadmium <9.8 chlordane ----Chloride chlorobenzcnc ----✓chromium ,.;1.5 chloroform ----
--✓Copper :':\ 5 o-crcsol --Fluoride m-crcsol ------
--Iron p-crcsol ----
--_vLcad J,_ l/c) crcsol --
--__ Manganese 1, ,\-dich lorobcnzene
,. --
--_JL'.-M er cu ry < ()' i --1,2-d ich loroet h anc
Nitrate 1, 1-dichlorocthylcne ------V""Selcnium ...l.l 214-dinitrotolucnc. --,......-Silver --,<9.g_ __ heptachlor
Radiochemistry Sulfates -hexachlorobenzcne ----V-Zinc B <,;, --hc.xach !orob u t adicnc --Paramder Results (PCi/1) pH h c,'c:i.chloroct ha nc ----__ Gross Alpha __ Conductivity --methyl ethyl ketone
Gross Beta TDS nitrobcnzcnc ------TOC pcntachlorophcnol : ;
----
·----pyridine
Microbiology ----tclrachloroc th ylcne
trichlo roet h ylc 11 c ----Par·;.:imetcr Results (Col/!OOml) 2, ,1 ,5-trichlorophcno I --2, 4 ,6-t rich] orophcnol ----
--vinvl chloride ----,
cndrin --lindanc --D:11c Rcccivcrl Rcpcrtcd by rncthuxych)or --tox::phcnc --
D;i{c E:-.:lr:.icttd Date Rcponnl 2,•1-D
00'1'15.1-M°i'if?7rY 6 --__ 2,,1,5-lT (Si!,cx)
Dc\lc ,:\ru!y-.:.cJ --·-L:'lh Number
,·,; ,,; l .··.-:;-·:;-,~:--··-·------·-------------------·· -·--·-__ ., ---·-----------------·------
')ivi_~~ion of Solid \Vaste.-Managcmcn: ., _ _,,,,.; . lnorg;1nics Lab: ,__..
!t Superfund Section l[j :/{zardr.1s \Vaste Section
D Sc1!id '.,V:1.ste Section
I
I CHAIN OF CUSTODY RECORD
RECEIVE"'"'
APR 111996
SUPER FUND SECTIO.
I Project Name: C!ie_rc/s.ce O,'/ u:,,.,,ou,,... Sampled by: l>. M,,o,u:
Site JD # (NCD#) NCD ?Bo 79"1 0/'l Sampler ID lie SvPeFFoAJ.b !:'€cno,v
Location: c.1,,,,..10-#w, /I{ e ,./,. I .c«, u ~ a,, IJC Telephone:_( 91'1) 733 -2e.01 ,,c 315 I Address: /":l-0 I &rrvl./// ~DA</ Date Sampled: 3/~/9t. r Time Sampled:
m Sample Types: Soil ......--Water v Waste Other ~;.,,-.}--
n Remarks:
' Fielc: Sample co-5 Co-'7 Co-'1 u-rz. w-tS co-16 cc-z/ I Numbers co --z.'f-CP-2-1 co -3o Cc-33 CO -31, Co-~f,
'
, Relinquished by: Al~ ILl/4(,_. . Date: -:.?,,h/'fc. Time: /C,-.~ tr
1 (Sign, ture)
J"Z~ceived by: S)c•1~· I 0--· e . Date:~;-,J'.'il._.. Time: l'i ·.,a
(Signature)
i Relinquished by: Date: Time:. I (Signature) .
. ---··-------------------------------------------------------------------------------· -------------~ -------~ -----------------------------------
Received by: Date: Time: .
I (Signature)
I Relinquished by: Date: Time: 1 · (Signature)
--. ------------------------------------------,------------------. ,., .. ---------------------------------------_. --------------------------------------
:, Received by: Date: Time:
(Signature) ·
I . It~ ,. • ' ('• • -~;(jl "//./.. LL.'' ., . ., ..
: Results Reported: ~. ,> Date:Jf'~ 1efr:: Time: --I ···.. . (Sig11a !Lire) .. --ii" ..
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(A\COCF .. FRM)
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N.c. D,pnrtmcn< or Environmcn,: SA.tvlPLI~ ANALYSIS REQUEST
! lc:J.llh, & Natural Resources
Solid Waste ManJgcmcnt Di\/1.<;ion
Sta:c f,.,,boratory of Public Health
r.o. I3ox 2so-n, 306 N. Wilmington _Strc~l
Ralcibh,1North Carolina 2_7611
co-001-sw 03/06/96 1430 GRAB
Site Number Cherokee Oil Company, NC DOUG HOORE Number _______________ _
BACKGROUND SURFACE WATER IN UT TO STUART
Name of Site_ ESD LAB METALS Surface Water
co-27
Collected By___________ _ ___ ~""' ~"··--led ___________ Time ______ _
Agency: Hazardous Waste Solid Waste V Supcrfund
Sample Type
Environmental Concentrate Comments
_ Solid (5) __ Ground water (1)
. ✓ Surface water (2)
_ Soil (3)
_ Liquid (6) __________ _
_ Sludge (7) __________ _
_ Other (4) _ Other (8)
Organic Chemistry Inorganic Chemistry
Parameter
_P&T:GC/MS
__ Acid:B/N Ext.
Results(mg/1) Parameter v Arsenic
✓Barium
✓Cadmium
Results(mg/Cbr (I BJ
L.D.p \
a.n7
MTBE
Chloride
✓ Chromium L.o _ o 1
✓Copper L.c, -cS
Fluoride
Iron --......-Lead
__ Manganese
V--Mcreury
Nitrate
✓Selenium
!---------------~ V-Silver
Radiochemistry Sulfates
Parameter
✓Zinc
Results (PCi/1) __ pH
__ Gross Alpha
Gross Beta
Microbiology
P;ir:.imcter Results (Col/l00ml)
__ Conductivity
TDS
TOC
Date Received _________ Reported by _________ _
L~h Number
, , , t, 7,,,, It, ... , , ••
TCLP Compounds
Inorganic Compounds
Arsenic --Barium
Cadmium --Chromium --Lead ----Mercury
Selenium --Silver
Organic Compounds
benzene --carbon tetrachloride
Rcsults(mg/1)
Results(mg/1)
---------chlordane
chlorobenzenc --chloroform
o-crcsol
m-crcsol --
--p-cresol
ere sol --1, 4-dichlorobenzcnc --1,2-<l i chloroct h anc --1, 1-dichlorocthylcnc --2,4-dinitrotolucne. --
--heptachlor
hcxJch !orobcnzcnc --hexach lorobu l nd icnc --hcxJchloroc l ha ne --
--methyl ethyl ketone
nitrobcnzcnc --
--pcntachlorophcnol
--pyridine
__ tetrachlorocthylcnc
__ trichlorocthylcnc
__ 2,4,5-tricl1!oropl1cnol
__ 2, 4 ,6-t richlorophcnol
__ 11nyl chloride
cndrin --!indanc
__ rncthoxychlor
__ tox::iphcn::
2.o-D
__ 2,•l,5-Tl' (Si!·:cx)
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.,,....,, ..,.., IU r••--~ ~e,,rv-<S( Tl:1-p,,.. ~
i~.C. Dt.:partmcnt of Environment, SA1v!PLE A..NALYSIS REQUEST
I Ico.llh, & Natur:-11 Resources
S.9\id WasLc Managc~cnt Division
Site Number
Name of Site
co-002-sw 03/06/96 13so GRAB
Cherokee Oil Company, NC DOUG MOORE
SURFACE WATER BELOW PPE IN UT TO STEWART
ESD LAB METALS Surface Water
Number
Scale f.Aboratory o( Public Hc:ihh
P.O. Oox 280-17, 305 N. Wilmington ~!reel
Ra.!cigh, North Carolina 2,7611
------------------
co-33 Collected By _________ _ __________ ed Time ----------------------
Agency: Hazardous Waste Solid Waste V Superfund TCLP Compounds -----
Sample Type Inorganic Compounds Rcsults(mg/1)
Environmental Concentrate Comments Arsenic --Barium --
Ground waler (1) _ Solid (5) Cadmium ----Chromium ✓Surface water (2)
--
_Liquid (6) Lead --Mercury --
Soil (3) _ Sludge (7) Selenium ------·· Silver --_ Other (4) _ Other (8) --
--
--
Organic Chemistry Inorganic Chemistry --
Parameter Results(mg/1) Parameter Rcsu I Ls (mg,").i ~!,1 gi, Organic Compounds Rcsults(mg/1)
_P&T:GC/MS v Arsenic ..(o.c.1 benzene --__ Acid:B/N Ext. ✓ Barium a.08 carbon tetrachloride --
MTBE ✓Cadmium < c,_e,c, '.J.., chlordane ------
Chloride chlorobenzene ------✓Chromium .C:...Q--D\ chloroform ----
--v'"Co p per L..D-D5 o-crcsol --Fluoride m-crcsol ------
--Iron p-crcsol ----
--vLcad D-Do9 crcsol --
----Manganese --1,4-dich lorobenzcnc
--✓Mercury <' o. QQQ (---1,2-dichlorocl hanc
Nitrate l, 1-dichlorocthylcne ----✓Selenium L...O-oo..5 2,4-dinitrotoluenc. --✓silver hcplachlor ""--o~o~ ----
Radiochemistry Sulfates hcx.;1chlorobcnzcne --./zinc o.c5 hex;ichlorobut 3cJicnc ----Parameter Results (PCi/1) pH hcxachloroethane ----__ Gross Alpha --Conductivity --methyl ethyl ketone
Gross Beta TDS nitrobcnzcnc ------TOC pcnlachlorophenol . ' ----
----pyridlnc
!V!icrobiology ----tclrachloroeth ylenc
--__ trichloroelhylenc
Parameter Results (Col/!00ml) 2, 4,5-tricl1lorophcnol ----2, 4 ,6-t richlorophenol ------
------,onyl chloride
endrin --lindanc --Date Rccci,,.cd Reported by --mclhoxych!or
tox;-iphcnc --Dale Exlr:1clcd Dye f·'J,>o,i:J"<l 2:1-D ·, rr ' -5 ~•0-s 96 --1-• ~J~J I /Jih ' 2,.;,5-TP (Si!·;cx) --Dale An;iltLCd L;:ib Number -----~-----------·---I l l I "i _l: '/ l ( i·'. .·.i·:,:,:
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··1'.C. Department of En-...ironmcnt,
l !callh, & i\'alural Resources
,Solid Wa.~lc Managcn)Cnt Divisi~:>n
SAMPLE ANALYSIS REQUE~; t'
Site Number C0-007-PB 03/07/96 1130 GRAB
Cherokee Oil Company, NC
Name of Site PRESERV. BLANK
-ESD LAB METALS Water
Number DOUG MOORE
St:itc Labor..it01)· of Public Hc:i.l\h
P.O. nox J.S()..17, 306 N. Wilmington Street
Rli!cit,h, 1North Cnrolina · 27611
------------------
Collected By _____ c_o_-____ 3 8 .cd Time ------------------
Agency: Hazardous Waste Solid Waste ✓ Superfund TCLP Compounds -----
Sample Type Inorganic CompouncLs Results(mg/1)
Environmental Concentrate Comments Arsenic --Barium --
__ Ground waler (1) _ Solid (5) Cadmium --Chromium --
Surface water (2) _ Liquid (6) Lead ----
--Mercury
_Soil (3) _ Sludge (7) Selenium --Silver
✓ Other (4) _ Other (8) --
--
toef,..;~ Jl,_t>) --
--
Organic Chemistry Inorganic Chemistry --
Parameter Results(mg/1) Parameter Resulls(mg/1)_. g,'I gl Organic Compounds Results(mg/1)
_P&T:GC/MS v Arsenic L.. p .. o\ benzene ----_ Acid:B/N Ext. ,.,-Barium Cl.c,?, carbon tetrachloride ----
MTBE v"" Cadmium "-. 0 • C> C• 'J. chlordane ----
Chloride chlorobenzcnc ------✓Chromium .i... D ~(_~\ chloroform ----
--...-copper -<'.0-D.!5 o-crcsol --Fluoride m-crcsol ------
--Iron p-crcsol ----✓Lead L...o;oo5 crcsol ----
----Manganese 1, 4-dich lorobcnzcnc
<Q,Qoc ~ --
--..-Mercury --1,2-dichloroct hanc
Nitrate 1, 1-dichloroethylcnc ----
..,--selenium L...D.c-o,S 214-dinitrotolucnc _ --✓-Silver L...o.o5 heplachlor ----Radiochemistry Sulfates hexachlorobcnzcne --
v"L.inc .... L..D_ o.5 hexach lorobu lad irnc ----Parameter Results (PCi/1) pH hcxachloroclhanc ----__ Gross Alpha __ Conducti,ity --methyl ethyl ketone
Gross Beta TDS nitrobcnzcnc ------TOC pentachlorophcnol . --, ----
----ryridinc
/vi icro biology ----tel rachlorocth ylcnc
trichloroelhylcnc ----Pararnder Results (Col/lO0ml) 2,ct,5-trich lorophcnol ----21 ,1 ,6-tri chloro phenol ------1inyl chloride ------cndrin --lind:HlC --DJtc Rccci,,·cci Reported by ---r~1~thoxychior
--lOXJphcnc.
Dale Extracted I),,, Cm !,;'stl -!'11 R __ g_g_ I 2,-:.1) G .. i-. .r,, . v· --•. ',J • ? -1 5-TP (S:1··cx) ----', . , ....
[);de ;-\n~i!yzcd ·---L1h Number -------------------➔---·------------I 1: I'' ,:,;j (I,'., ... ·:-''),' ::·:
lhi-~~ 1-r, f' H :i ,,., I 5o % 1-N6:1,
I /-/.C. Dq,"anmcnt of Envitonmcnt, SA.MPLE ANALYSIS REQUEST
I !c:ilth, & Natural Resources
Solid Waste Management DivisiOn
Seate l...aborat0ry of Public Health
P.O. 0ox 28047, 306 N. Wilmington Street
Ralcig.h, North Carolina 27611
Rr==f"'Et . Field Sample Number __ o=-:../=.C,__:1....:;;l_c...·5'=-'J _ _.::_V_,E,,. . .!..nL· _· ___ _
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Collected By' "P. M.,.,,e,c JD#
Agency: Hazardous Waste Solid Waste J:.___superfund ----
Sample Type
Environmental Concentrate Comments
Ground water (1) _Solid (5) CO -tJO~-SW
'/. Surface water (2) _ Liquid (6)
_ Soil (3) Sludge (7)
_ Other (4) _ Other (8)
Organic Chemistry Inorganic Chemistry
Parameter Results(rng/1) Parameter Results (mg/!\ (□rn {~g)
_P&T:GC/MS v" Arsenic "'-O.CJI
vBarium Acid:B/N Ext. (), 0/.---,,...-1:a dm i urn MTBE -'--o .. oo~ --Chloride --✓Chromium o .o;;).0 --✓Copper <. o, o C --Fluoride ----Iron ----/Lead ,,,!.. o.,ac1.S --
--__ Manganese
/Mercury . -(. u. Q o L'S---Nitrate ----vSelenium -<.O.oo5
✓Silver (o. o' --Radiochemistry Sulfates --< o, o..( ·----.,_/Zinc
Pam meter Results (PCi/1) pH --
Gross Alpha --Conductivity --Gross Bela TDS ----TOC --
--Microbiology --
--Parameter Results (Col/JO0ml) --
----
----
Date Received Reported by
D:..ilc Extracted Date Reported _1.l_j_~'i-rl( fy'-rn-,J--:J ~i1 :::,:·:. ,,_~1 \':b
0;1(c ,1\n:dv1.ctl L:1h ~umber
..
.·
TCLP Compounds
Inorganic Compounds Rcsults(mg/1)
Arsenic --Barium --Cadmium --Chromium --Lead --Mercury --Selenium --Silver --.. --
--
--
--
Organic Compounds Results(mg/1)
benzene --carbon tetrachloride --chlordane --chlorobcnzene --chloroform --o-cresol --m-crcsol --
--p-crcsol
cresol --1, 4-dichlorobcnzcnc --1,2-dichloroeth ane --1, 1-dichloroet hylcnc --2,4-di nitrotol u enc
__ heptachlor
hexachlorobenzcne --hcxach lorobu t adiene --hcxachloroethane --__ methyl ethyl ketone
nitrobcnzcnc --__ penlachlorophenol
--pyridine
__ tetrachloroethylcne
__ trichloroethylcnc
__ 21415•trichlorophcnol
_._2,4,6-trichJorophcnol
__ vinyl chloride
cn<lrin --lindanc --mcthoxychlor ..
--toxaphcnc --2,4-D --_ 2,4,5-TP (Sil·,cx)
----
I 1\'.C. Dcpinmcnt of En"vironmcnt,
1 lc.illh, & Natural Resources
Solid WastC:. Man:igcmcnt Division
SAMPLE ANALYSIS REQUEST State Laboratory of Public Hcahh
P.O. 0ox 28047, 306 N. Wilmington Street
Raleigh, North Carolina 27611
I Site Numbcr_~A_IC._.D __ 9_'!0 __ 7_'1_'1 __ o_/_'l ____ _ Field Sample Number ___ -'-0--'-/-"'-C,_'}-'--;l----'-(, ______ _
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Name of Site Chu-ok~e {),1/ {o,.,.c4,, v ~/
Collected By' 7). M.,.,,e.c ID# Date Collected ,#,.,-et, f';I 1 /9'?1', Time /K :05
.
Agency:. Hazardous Waste Solid Waste j:__Superfund TCLP Compounds
----
Sample Type Inorganic Compounds Results(mg/1)
Environmental Concentrate Comments Arsenic --Barium --C'o-oo~-sw Ground water (1) _ Solid (5) Cadmium
----Chromium --L Surface water (2) _ Liquid (6) Lead --
.. __ Mercury
_ Soil (3) _ Sludge (7) Selenium ---Silver --
_ Other (4) _ Other (8) --
--
--
Organic Chemistry Inorganic Chemistry --
Parameter Results(mg/1) Parameter Results(mg/') ( ~, n @l Organic Compounds Results(mg/1)
-P&T:GC/MS v Arsenic .L.....0-A \ benzene --
--Acid:B/N Ext. v Barium 0, o }-carbon tetrachloride --
MTBE ✓Cadmium L..0-00 'J. chlordane ------
Chloride chlorobenzcnc ----
--vChromium 0-0)) chloroform --
-vCopper <o.o.c o-cresol --
Fluoride m-cresol ------
--Iron p-crcsol
--V--Lead ,L_ D ·_ c, c, :;5 crcsol --
__ Manganese .. 1,4-dichlorobenzcnc ----
vMcrcury ( C), 0 0 {J.f. -1,2-dichloroethane ----
--Nitrate __ 1,1-dichloroethylcnc --v' Selenium "'-D. c,c,!:, --2,4-di nitrotol uenc
✓Silver < o .. Q,~ __ heptachlor
Radiochcmi-stry Sulfates hcxachlorobcnzcne --< 0, oS---
✓Zinc hexach lorobut ad ienc
Parameter: ----
Results (!'Ci/I) pH hcxachlorocthane ----
--Gross Alpha --Conductivity __ methyl ethyl ketone
Gross Beta TDS nitrobcnzcnc
------
--TOC __ pcntachlorophenol
--__ pyridine
Microbiology --__ tctrachlorocthylenc
--__ trichlorocthylcnc
P..iramctcr Results (Col/100111!) __ 2,4,5-trichlorophcnol --
----_._2,4,6-trichlorophcnol
----__ vinyl chloride
cndrin --lindanc --
Date Received Reported by __ mcthoxychlor
--tox;iphcnc
D~itc Extracted Dcilc Rc~orted 2:1-D /1 I • ,-ZT~~'-1 s ·Jb --. .!.. :;·.' ·_y 1i1'.1 J. __ 2,4,5-TP (Sil·:cx)
l1:it(: .,\11:ilv1.cd Lih Number ----
~r.-d ./.., ~H-' o,.,/!.o % /#Jf;3_
I . R.C Dcpartmcot of Envin:mment, SAMPLE A.t"IALYSIS REQUEST
I k;,ilth, & Natural Resources
State Laboratory of l'ublii: Health.
P.O. Box 280-17, 306 N. Wilmington Street
Raleigh, North Carolina 27611
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Solid WastC Management Division
Site Number AICJJ 9eo 7"1''1 0/'f Field Sam plc N urnber ___ -=O'--'-/ r,,"'-q'-'-;i._9.,_ ______ _
Name of Site C:/4urok,e. C),1/ {c,,.,~,, t/ ~; Site L~cation /201 &rryl11i'/ tQ.d._, ~,.,-1,, 111:.,, /Jc..
Collected By• -p. M.,.,,,ec ID# ____ Date Collected ,'lf,i,,-c.l, 1~119'?6 Time t?0 5o
Agency:. Hazardous Waste Solid Waste _J:___superfund TCLP Compounds
------
Sample Type Inorganic Compounds Results(mg/1)
Environmental Concentrate Comments Arsenic --Barium --
Ground water (1) _ Solid (5) R-e~e.rv,.J,;,.,:. 13/cu.k... Cadmium --Chromium --
__ Surface water (2) _ Liquid (6) Lead --__ Mercury
_ Soil (3) _ Sludge (7) Selenium ---· Silver --
_JL Other ( 4) _ Other (8) --
--
. --
Organic Chemistry Inorganic Chemistry --
Pam meter Results(mg/1) Parameter Results(mg,") ( bl '.) g) Organic Compounds Results(rng/1)
_P&T:GC/MS ✓ Arsenic Lo.ol benzene ----
_ Acid:B/N Ext. ~ Barium < o. {) ( carbon tetrachloride --
MTBE i,,-Cadmiurn .L.o .. c..ol. chlordane ----
Chloride chlorobenzene ------..... Chromium .,,_ 0 pl chloroform ----
. vCopper <o,o.~ o-cresol ----
Fluoride m-crcsol ------
--Iron __ p-cresol
--,.,..--Lead ,<. c,' -0 Q~ cresol ----
--__ Manganese 1,4-dichlorobcnzcne <a, oo(\ s.' --
--......-Mercury 1,2-dich loroet hane --
--Nitrate __ 1,1-dichloroethylene
.......-Selenium Lo,po5 2, 4-dinit rota! ucnc --
......-Silver ,( Q, C-S::: __ heptachlor --
Radiochemistry Sulfates -hexachlorobenzene --< {),() > --
····-.,....-zinc hexachlorobu tad iene ----
Parameter Results (PCi/1) pH hcxachlorocthane ----
__ Gross Alpha --Conductivity __ methyl ethyl ketone
Gross Beta TDS nitrobcnzcnc ------
TOC __ pcntachlorophenol --
--__ pyridine
Microbiology --__ lelrachlorocthylcne
--__ trichloroethylene
Pura meter Results (Col/JO0ml) __ 2,4,5-trichlorophcnol --
----_._·_2,4,6-trichlorophenol
----__ vinyl chloride
cn<lrin --lindanc --
Date Received Reported by __ mclhoxychlor
toxJphenc --
Dale l:xlraclc<l Dale Reported 2,4-D
"·(I • ·""JTl'T' ,_, 1 0 ,, G --
•,.. .' ·:, ',(. ~••. 'I'.'· .. :. ' f __ 2,'1,5-TP (Sil·:cx)
l):itr· An;1k11:d Lah Number
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"IC-IJ1'.,11Nf( 0rganics i_.:il.1: ----,'Ji'fisic,~ of Solid \Vastt Management I f4 Supcrfllnd Section
Inorganics Lab:_~
D Hazardous \Vaste Section
1 D Solid Waste Section
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CHAIN OF CUSTODY RECORD .
RECEIVFf")
MAY 2 21996
0Ut"ERFUND SECTION
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Project Name: a,,,,,.,,k.,e Od Cc"t"e1 "''l
Site ID# (NCD#) Nl-b 99-u 7 q 'i 01 q
Loca tion:__.1-=zo=-c1,___,,e,.,"-,.."-ry1<!ft"'''-'. 11'.,L_R,,.,,o.,,_ttgcl ___ _
Ad dress :--.:C.t.=:::" .-:..:l::::o.,_U'-'":J../-"M"'aj,j,=.,.,..""-"i,._.....,.,.,9~eo.,_,,.,,.c,N'-'C.'-----
Soil
Sampled by: 'D.Mootu?
Sampler ID /if£ S uP.3µ,,-,,wf> rec..770..;
Telephone:_(.ifi) 7'33-2-801 , " . .3,S
Date Sampled: f-1,tr-t(,. 131 t'l'H
Time Sampled:
Sample Types: ------\Yater V ----=---Waste · Other S'4{ ;~ -----
Remarks: ------------------------------------_; ____________ _
'
I : Field Sample O f(,'j'J..5' 011,q';l(,
Numbers
I! .
! Relinquished by:_.&J~~!.a..JG,L,(Lk!..n!~'----------Date: 3/,'f:ft/, Time: /3 '. 07 I ! (Sign ure) · 1 1
. : ---. --. -.-----.. ---------------------------------------------------------------------------------------------------------------------------------
: Received by: ~" ..,., Q . Date:~ J<t4, Time: 13 · o 7 I '(s\gnature)
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' Relinquished by:. _______________ _
a! (Signature)
Date: __ _ Time:. ____ _
g I Received by:
(Signature)
Date:. ___ _ Time:. ____ _
Relinquished by: _______________ _ m (Signature)
Date:. __ _ Time:. ____ _
--------------------------------·----------------------------------------------------------------------------------------------------------------
Date: ___ _ Time: -----
n Results Reported:
(Signature)
Date: lJil'"17c Time:. ___ _
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N.C. Department of Environment,
llcalth, & N;i.tura,l Resources
Solid ~,~·stC. f'-1a~agc.in_c~t Divis_i~ii
SAMPLE ANALYSIS REQUEST Stale L11bora1ory of Public Health
P.O. Box 28047, 306 N. Wilmington Street
, .. R.alcii,h, North Caroli~a 2761'1
Field Sample Number_· ___ ._C>_./_C._9_J.-' ..• -'-'7_· ______ _
Name of Site Cliu-okre. (),1/ {o,.,pq,, v , ]
Collected Bf 7' · M.,,,,eE JD# Date Collected µ,,;..ct, /?1 1911,. Time / f?: 15
Agency: Hazardous Waste -----Solid Waste ~Superfund TCLP Compounds
Sample Type Inorganic Compounds Results(mg/1;
Environment81 Concentrate Comments Arsenic --Barium --w-oo'f-Sb _ Ground water (1) _ Solid (5) Cadmium --Chromium --
Surface water (2) _ Liquid (6) Lead --__ Mercury
_ Soil (3) _ Sludge (7) Selenium --Silver --
_'f_ Other (4) _ Other (8) --
{5ul-~) --
--
Organic Chemistry Inorganic Chemistry --
Parnmeter Results(mg/1) Parameter Results~ (mg/kg) Organic Compounds Results(mg/1:
--P&T:GC/MS V Arsenic -< \ .9 benzene --
_ Acid:B/N Ext. ✓Barium 5"' carbon tetrachloride --• :J --·
MTBE ✓Cadmium -'..9.8 chlordane ----Chloride chlorobenzene ------v Chromium ~ "I chloroform ----
--,_,...--Copper ri,5 o-cresol --
Fluoride m-crcsol ------
--Iron __ p-cresol --<'Jo --✓Lead crcsol ----
--__ Manganes'e 1, 4-dichlorobcnzene --
--vMercury < C•, I 1,2-d ichloroel h ane --
Nitrate __ 1,1-dichloroethylene
--V-Selenium -<:.\ 2,4-d i nitrotol uene --
v'Silver L.., .5 -__ heptachlor --Radiochemistry Sulfates hexachlorobcnzenc ----
····--..-----Zinc 35 hexachlorob u tad ienc ----
Parameter Results (PCi/1) pH hcxachloroel hane
__ Gross Alpha
----
__ Conductivity __ methyl ethyl ketone
Gross Bela TDS nitrobcnzcnc ------TOC pcnlachlorophenol ----__ pyridine --Microbiology --__ tetrachloroelhylene
__ trichlorocthyfcne --Parameter Results (Col/lO0ml) __ 2,4,5-trichlorophcnol --_._2,4,6-trichlorophenol ----__ ,onyl chloride
----cndrin --r-r,-•~~ ~ ;~ r• .. :~l~.)')t '.1 .' ...... L ~ • 1. lindanc
D,11c Received
--
Reported by __ mcthoxych!or
, __ tox;1phc.nc
l);,tc Extrac(c:{I D;itc RcponcJ 2,•\.I) -·---· 2,,1,.\-TI' (Sil·,cx)
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1"'.C. Department of Environment,
I lc.ilth & Natural Resources
Solid. w~·s.iC Managc~cnt Division . ·. . . ' . . '. . ·. . . . ~ .
SAMPLE ANALYSIS REQUEST State Laboratory o( P~blic llc:ilth
P.O. !1ox 28047, 306 N. Wilmington Sire.ct
, , .. , R.a!cig.h, North Carolina 2761'1 .·,•:• . . ',: .
Sile Number /1/C../J r.;ec, . 7"'1"! 011 · . Field Sample Number __ __:0::...:../ =.(._'1_··_:;i_8'-",--'-·, _______ _
Name of Site Chu-ok,re. {),/ WMpqH v , /
ID# ____ Dalc Collected µ-,;,.,,;, l'1119'?(,, Time 16: oo
Agency: Hazardous Waste Solid Waste __c___Superfund TCLP Compounds
----. -
Sample Type Inorganic Compounds Results(mg/1)
Environmental Concentrate Comments Arsenic --Barium --
__ Groundwater (1) _ Solid (5) OJ-OCS"-Sb Cadmium --Chromium --
__ Surface water (2) _ Liquid (6) Lead --
--Mercury -
_ Soil (3) _ Sludge (7) Selenium --Silver --
_L__ Other (4) _ Other (8) --
{seJ, ~) --
--
Organic Chemistry Inorganic Chemistry --
Pam meter Results(mg/1) Parameter Resu" d. @:~(mg/kg) Organic Compounds Results(mg/J,
--P&T:GC/MS / Arsenic --<. ?i benzene ----
Acid:B/N Ext. ✓Barium .58 carbon tetrachloride ----MTBE ,,..,-Cadmium 4\C chlordane ------Chloride chlorobcnzene ------V-Chromium .3 ,Cl chloroform ----...---Copper ~a o-cresol ----Fluoride m~crcsol ------
--Iron p-cresol --<Jc, --..,,-Lead crcsol ------
--__ Manganese --1, 4-d ichlorobenzene
--v Mercury < Cl, i 1,2-d ich loroet bane --
Nitrate ' 1, 1-dichloroet hylcne ------..,.,-selenium "'-' 2, 4-d initrol ol uene
. ..,--Silver --...,_, c, -. __ heptachlor
Radiochemistry Sulfates hcxach lor.oben zene ----
···-----........-Zinc 3.1..) hexach I orob u tad iene ----
Parameter Results (PCi/1) pl-! hexachloroclhane ----
--Gross Alpha __ Conductivity methyl ethyl ketone --Gross Bela TDS nitrobenzcnc ------TOC pentachlorophenol ----
--pyridine --
Microbiology --__ telrachlorocthylcne
__ trichloroethyfenc --Parameter Results (Col/lOOml) __ 2,4,5-trichlorophcnol ---_._2,4,6-trichlorophenol ----__ vinyl chloride ----cndrin --rn .,-,, ... r:r> 1 ~ ,, , linclanc
I • :.' •• L'._:;: , ... \.:.. /b --Date Rccci·:cd Reported by rncthoxychlor --
__ tox:-iphcnc
D:1lc [x(radcd D;1lc Reported 2,'1-D -----2,1,5-TI' (Sil .-,x)
" i,_, ' ' ' •.•
L.J
-----~---le------1-------~0---~S--O°]--'--------~--
/~ ,:Z;· ,,G)
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TO: FILE
FROM: Paula C. MacLaren
Analytical Coordinator
THRU: W. Scott Butterfield 4t,,;J I}
T ATL, Region IV
SUBJECT: Cherokee Oil/ Berryhill Site Analytical Data
TDD# 04-9503-LO0l-0468
DATE: 05 April 1995
Kiber Environmental Services, Inc. laboratory analyzed four soil samples taken at the Cherokee
Oil/ Berryhill Site on 13 March 1995 for the following parameters:
volatiles
semivolatiles
PCBs
RCRA metals
The analytical report was received within the required two week period.
All sample analysis hold times were met.
The laboratory blank showed trace methylene chloride and barium contamination. Their
concentrations have been presented in the attached data summary.
A matrix spike was performed on sample CO-SB-04.
The volatile matrix spike showed all percent recoveries within the QA/QC guideline of 80 % to
120%. The matrix spike duplicate showed two out of five percent recoveries below the 80%
recommendation. Analytical precision showed four out of five relative percent differences
(RPD) within the QA/QC guideline of 20% RPD. All surrogate and laboratory control sample
percent recoveries were within method QC limits. ·
Roy F. Weston, Inc.
FEDERAL PROGRAMS DIVISION
In Association with Foster Wheeler USA Corporation, Resource Applications, Inc., C.C. Johnson & Malhotra, P.C.,
R.E. Sarrlera Associates, and GRB Environmental Services, Inc.
. The, semivolatile matrix spike showed eight out of eleven percent recoveries below 80 % ,
ho\Y~ver all were within method QC limits. The matrix spike duplicate showed similar results .
. -:~Analytical. precision was within the 20% RPD. All surrogate and laboratory control sample
. 'i,,erce'nt ·recoveries were within method QC limits. .. -
· The PCB niatrix spike/ matrix spike duplicate percent recoveries were within the QA/QC
recommendation of 80% to 120% with l % RPD. Surrogates, if not diluted out, and laboratory
control sample percent recoveries were within method QC limits. ·
The RCRA · metals laboratory control sample recoveries were all within laboratory method .
specified range.
No PCBs were detected in any of the samples. Note elevated PCB detection limits on samples
CO-SS-01, CO-SS-02 and CO-SB-03.
Note elevated semivolatile detection limits on samples CO-SS-01 and CO-SS-02. :;~~ ~~·: ··. ' ,, . . .
---·i•• .. . .
A summary of the sample data can be found on the following pages.
cc. Steve Spurlin
Terry Ryland
. .. :: ...... "'
t . . . '
CHEROKEE OIL -BERRYHILL SITE· ,',, ·
ANALYTICAL DATA ,·
SOIL SAMPLES
Acetone 140 91 1540E 100 ND )
Benzene 22 SJ 3.9J ND ND
2-Butanone (MEK) ND ND 110 25 ND
1, 1-Dichloroethane 19 3:9J ND ND ND
Ethylbenzene 44 3.7J 6J ND ND
Methylene Chloride 220B . 210B 6.4BJ 4.2BJ 4.51
4-Methyl-2-Pentanone 75 46 39 4.5J ND
Tetrachloroethene 110 7.lJ 2.2J ND ND
· Toluene 290 96. 27 ND ND
1, 1, I-Trichloroethane 6.4J ND ND ND ND .. . I '---'
Trichlorethene 8.8J ND 2.2J 5.6J ND
Xylene, total 500 24 25 ND ND
Notes: ND -Not Detected
B -The compound was present in the laboratory blank
: -J -Estimated_va1ue; the.concentration was below the practical.quantitation limit (PQL).
E -Estimated value; the concentration exceeded the calibration: range of the instrument.
--· -- - -----
CHEROKEE OIL -BERRYHILL SITE ,,
. -'ANALYTICAL DATA ":
SOIL SAMPLES
,
bis(2-Ethylhexyl)phthalate 44000] 87000 4100 1400
Butylbenzylphthalate ND · 5000] N.D ND
Di-n-butylphthalate ND ND llOJ 89J
Di-n-octylphthalate 2300J 5300J 67J ND
Phenanthrene ND 3900J ND ND
Pyrene ND 3100J ND ND
Notes: ND -Not Detected
J -Estimated value; the concentration was below the practical quantitation limit (PQL).
l!lla 1!111& =iii lliiiil lliilll liiiiiil ._ .. .. L .... -.i -ztr liililli.
't :.
_ 1·t.' ·,',''. , .
.'' '.
CHEROKEE OIL -BERRYHILL SITE ";
' :ANALY'fICAL DATA, 0 /~•f/1,.i ::\; ·
. SOIL SAMPLES . !' . .//',..:.·
RCRA METALS (mg/kg) · 0
•. 1 , · •.
Arsenic ND ND ND ND ND . ·. l
Barium 220B 200B 300B 65B 0.003J
Cadmium 17 l.4J 2.2J ND ND
Chromium 130 42 39 47 ND
Lead 290 79 28 24 ND
Mercury ND . ND ND ND ND
Selenium ND. 5.9J 16J ND ND
Silver ND ND ND ND ND
. Notes: ND -Not Detected
B . -The analyte was present in the laboratory blank .
J -Estimated value; the concentration was below the practical quantitation limit (PQL).
:, :
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KIBER ENVIRONMENTAL SERVICES, INC.
·• ... ANALYTICAL CASE NARRATIVE
Roy F. Weston -Cherokee Oil
1236 -503034
Four soil samples were received for analysis on March 17, 1995 at 1020 hours. The
Environmental Protection Agency (EPA) sampling procedures require soil samples to be ..
preserved at 4°C ± 2°C. The samples arrived at 5.5 °C. '
The requested analyses and corresponding methods were as follows:
Total Volatiles SW-846 Method" 8260
' Total Semivolatiles SW-846 Methods: 3550 and
, .. 8270A I
Total Volatiles
Analysis
Total Polychlorinated
biphenyls (PCBs)
Total RCRA Metals
SW-846 Methods: 3550,
3665 proposed, and 8080
SW-846 Methods: 3051,
7470 and 6010A
A matrix interference may have been affecting the internal standard area recoveries
for samples CO-SS-01 and CO-SS-02, as noted below._: There were no further
analytical difficulties noted during the analyses. ·
Quality Control
The quality control analyses included the following: blank, blank spike, matrix spike,
and matrix spike duplicate. The quality control results were within the method ·:
specified limits except for the following:
1. The internal standard area recoveries for 1,4°difluorobenzene and
chlorobenzene-d5 for sample CO-SS-01 were below 50 % of those in the daily
calibration. However, the surrogates were within the method specified limits.
A matrix interference is suspected.
1
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(_::\, ··.:.. .:1
KIBER ENVIRONMENTAL SERVICES, INC.
Total Volatiles continued
ANALYTICAL CASE NARRATIVE
Roy F. Weston - Cherokee Oil
1236 -503034
Quality Control continued
2. The internal standard area recoveries for bromochloromethane, 1,4-
difluorobenzene, and chlorobenzene-d5 for sample CO-SS-02 were below 50%
of those in the daily calibration. However, the surrogates were within the
method specified limits. A matrix interference is suspected. ; .
3. The relative percent differences between the matrix spike and matrix spike
duplicate analyses for 1, 1-dichloroethene and trichloroethene were outside the
method specified limits.
The sample selected for the matrix spike and matrix spike duplicate analyses was CO-
SB-04.
Total Semivolatiles
Analysis
Samples CO-SS-01, CO-SS-02, and CO-SB-03 required dilution due to the nature of ·
the sample matrices. There were no further analytical difficulties noted during the
analyses.
Quality Control .
The quality control analyses included the following: two extraction blanks, two
extraction blank spikes, one extraction blank spike duplicate, one matrix spike, and
one matrix spike duplicate. The quality control results were within the method
specified limits except for the following:
1. The extraction blank spike recovery for 2,4-dinitrotoluene was outside the
method specified limits for both extraction blank spikes and the extraction
blank spike duplicate.
2. The recovery for 2,4-dinitrotoluene was outside the method specified limits for
the matrix spike and matrix spike duplicate analyses.
2
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KIBER ENVIRONMENTAL SERVICES, INC.
ANALYTICAL CASE NARRATIVE
Roy F. Weston -Cherokee Oil
1236 -503034
Total Semivolatiles continued
Quality Control continued
. -·
The sample selected for the matrix spike and matrix spike duplicate analyses was CO-
SB-04.
Total Polychlorinated Biphenyls (PCBs)
Analysis
Samples CO-SS-01, CO-SS-02, and CO-SB-03 required dilution due to the nature of
the sample matrices. There were no further analytical difficulties noted during the
analyses.
. Quality Control
The quality control analyses included the following: an extraction blank, extraction
blank spike, matrix spike and matrix spike duplicate. The quality control results were
within the method specified limits except for the following:
1. The surrogates for samples CO-SS-01, CO-SS-02, and CO-SB-03 were unable
to be determined due to the dilution necessary for analysis.
i
I '
The sample selected for the matrix spike and matrix spike duplicate analyses was CO-
SB-04.
Total RCRA Metals
Analysis
There were no analytical difficulties noted during the analyses.
Quality Control
· The quality control analyses included the following: preparation blank, laboratory
control standard, replicate, matrix spike, and serial dilution. The results were within
the method specified limits except for the following:
3
KIBER ENVIRONMENTAL SERVICES, INC. ,.~=;:t-~~-r·: " :: •·,: ANALYTICAL CASE NARRATIVE· .
Roy F. Weston -Cherokee Oil
1236 -503034
Total RCRA Metals continued
Quality Control continued
1. The matrix spike recoveries for chromium and lead were outside the method
specified limits. However, the post-digestion spike recoveries for these
elements were within the method limits. The matrix spike recoveries are likely
affected by sample nonhomogeneity and/or matrix interference .
...
The replicate recoveries for chromium and lead were oµtside the method
'specified limits. Sample nonhomogeneity is suspected.
The ·sample seiected for the matrix spike, replicate, and serial dilution may not be
. ·. representative of the samples in the Cherokee Oil study .
. • r..,.
4
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KWEB ENVIRONMENTAL SERVICES.)NC.
rl L==========V=O=LA=TIL=E=RE=SU=L=T=S=====c=========illll r ,,-SW-846-8260 II
'
CUentName:RoyF. Weston Lab Sample ID: 503034-1
Project Name/#: Cherokee Oil/1236 Matrix: Soil
Date Received:03/17 /95 % Solids: 81.2 .I Date Sampled:03/13/95 Initial Wt/Vol: 5.05 g r Client Samnle #: CO-SS-01 Final Wt/Vol: 5.00 o
' ' ' ' ' ' ' ' I
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CASNumber
II
Compound Name
I
67-64-1 Acetone
71-43-2 Benzene
75-27-4 Bromodichloromethane .
75-25-2 Bromoform
74-83-9 Bromomethane
78-93-3 2-Butanone(Methyl ethyl ketone)
75-15-0 Carbon disulfide
56-23-5 · Carbon tetrachloride
108-90-7 Chlorobenzene
75-00-3 Chloroethane
67-66-3 Chloroform
74-87'3 Chloromethane
124-48-1 Dibromochloromethane
75-34-3 1, 1-Dichloroethane
107-06-2 1,2-Dichloroethane
75-35-4 1, 1-Dichloroethene
540-59-0 1,2-Dichloroethene (total)
78-87-5 1,2-Dichloropropane
10061-01-5 • cis-1,3-Dichloropropene
10061-02-6 trans-1,3-Dichloropropene
100-41-4 Ethylbenzene
591-78-6 2-Hexanone
75-09-2 Methylene chloride
108-10-1 4-Methvl-2-pentanone (MIBK)
100-42-5 . Styrene
79-34-5 1, 1,2,2-Tetrachloroethane
127-18-4 Tetrachloroethene
108-88-3 Toluene
71-55-6 I, I, I-Trichloroethane
79-00-5 1, 1,2-Trichloroethane
79-01-6 Trichloroethene
108-05-4 Vinvl acetate
75-01-4 Vinvl chloride
1330-20-7 Xvlene (total)
Note:
E = Concentration exceeds calibration range (results estimated)
J = Estimated value (less than PQL but greater than zero)
Dilution
Factor
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1
1
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5
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B = Analyte found in blank (possible/probable blank contamination)
J
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Aru,Jysl,
II Date
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
Result 1~6 ug/kg
140 12
22 12
BQL 12
BQL 12
BOL 12
BQL 12
BQL 12
BQL 12
BQL 12
BQL 12
BQL 12
BOL 12
BQL 12
19 12 ' BQL 12
BQL 12
BQL 12
BQL 12
BQL 12
BQL 12
44 12
BQL 12
220 12 B
75 12
BQL 12
BQL 12
110 12
290 61
6.4 12 J
BQL 12
8.8 12 J
BQL 12
BQL 12
500 12
BQL = Below Quantitafion Limit
PQL = Practical Quantitation Limit
NA = Not Applicable
I
1<"'-r.SC\ •:':_·J r>h
KIBER ENVIRONMENTAL SERVICES, INC,
VOLATILE SURROGATE RECOVERIES . ,,
SW-846-8260 • · · · . -.---
Client Name: Roi F. Weston
Project Name/#: ChJ.okee Oil/I 236
I
Lab Sample ID::.': · . 503034-1
Date Received:03/J,7 /95
I Date Sampled:03/J,3/95
Client Samo le#: colss-O I
Matrix:
% Solids:
Initial WIN ol:
Final WIN ol:
Soil
81.2
5.05 g
5.00 •
I ~urrogat< Compound II ~~r;b II ~~t II LI~'i-rs I o/, I Not< I
,,_ ______ 1~,2~l·_D_ic_hl_o_roe_· fu_an_e-_d_4 ______ _,~0_3/_2_1/_95__,,1 ___ 5_0 __ ~1,1---7_0-_1_2_1---<§§Re,:o
6
v
9
ery §
I Toluene-d8 03/21/95 _ 50 _ 84-138
Bromofluorobenzene 03/21/95 50
• = S111Togate(s) out of QC Limits (see case narrative) ;
D = Diluted out
'
{_') C:, •;,.. •··.•·
KJBER ENVIRONMENTAL SERVICES. INC.
.. ,l=======Sc======V=O=LA~T=IL=E=RE=S=U=L=T=S============~I r ,.= SW-846-8260
' '
Client Name: Roy F. Weston
Project Name/#: Cherok6e Oil/1236
. I
Date Rccclved:03/17 /95
I
Date Sampled:03/13/95
I
Client Samnle #: CO-SS-02
Lab Sample ID:
Matrix:
% Solids:
Initial Wt/Vol:
Final Wt/Vol:
503034-2
Soil
85.4
5.02 g
5.00 o
' II!= =C=AS=N=wn=b=••=~II; ==·~\ ==Co=m=p•=wi=d N=am=•=====l:l==D:.=u;:=:;~I~ ==Anal=D•=;';=ls==l:i=I ===;._=ul=;==lllp =u~=QL=:J=\i=I N=o=te=(II
67-64-1 I Acetone 1 03/21/95 91 12 .I 71-43-2 I Benzene 1 03/21/95 8 r 75-27-4 I Bromodichloromethane I 03/21/95 BQL
12 J
12
'
75-25-2 I Bromoform I 03/21/95 BQL
74-83-9 I Bromomethane 1 03/21/95 BQL
12
12
78-93-3 2-Butanone(Methvl ethvl ketone) I 03/21/95 BQL
'
75-15-0 I Carbon disulfide I 03/21/95 BQL
56-23-5 I Carbon tetrachloride I 03/21/95 BQL
12
12
12
108-90-7 I Chlorobenzene I 03/21/95 BQL 12
75-00-3 I Chloroethane 1 03/21/95 BQL 12
.. 67-66-3 I Chloroform I 03/21/95 BQL r 74-87-3 I Chloromethane I 03/21/95 BQL
12
12
124-48-1 I Dibromochloromethane I 03/21/95 BQL 12 .I 75-34-3 I 1,1-Dichloroethane I 03/21/95 3.9 r 107-06-2 I 1,2-Dichloroethane I 03/21/95 BQL
12 J
12
75-35-4 I 1,1-Dicbloroethene I 03/21/95 BQL 12 .I 540-59-0 I 1,2-Dichloroethene (total) I 03/21/95 BQL r 78-87-5 I 1,2-Dichloroorooane I 03/21/95 BQL
12
12
10061-01-5 I · cis-1,3-Dichloropropene I 03/21/95 BQL 12
'
10061-02-6 I trans-1,3-Dichloropropene . I 03/21/95 BQL
100-41-4 I Ethylbenzene 1 03/21/95 3.7
12
12 J
591-78-6 I 2-Hexanone I 03/21/95 BQL 12
'
75-09-2 I Methvlenechloride I 03/21/95 210
108-10-1 4-Methvl-2-pentanone (MIBK) I 03/21/95 46
12 B
12
100-42-5 I Styrene I 03/21/95 BQL 12
'
79-34-5 I 1,1,2,2-Tetrachloroethane I 03/21/95 BQL
127-18-4 I Tetrachloroethene I 03/21/95 7.1
12
12 J
108-88-3 I Toluene I 03/21/95 96 12
I 71-55-6 I 1,l,1-Trichloroethane . I 03/21/95 BQL
79-00-5 I 1,1,2-Trichloroethane I 03/21/95 BQL
12
12
79-01-6 I Trichloroethene 1 03/21/95 BQL 12
.
· 108-05-4 I · Vinvl acetate I 03/21/95 BQL
75-01-4 I Vinyl chloride I 03/21/95 BQL
12
12
1330-20-7 I Xvlene (total\ I 03/21/95 24 12
I
I
I
Note: I
E = Concentration exceeds calibration range (results estimated)
J = Estimated value (less\than PQL but greater than zero)
B = Analyte found in blarik (possible/probable blank contamination)
BQL = Below Quantitation Limit
PQL = Practical Quantitation Limit
NA= Not Applicable
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Client Name: Roy F. Weston
O.D ~
KJRER ENVIRONMENTAL SERVICES, INC,
VOLATILE SURROGATE RECOVERIES
··· ·· SW-846-8260
. Lab Sample ID: . . -I . •
Project Name/#: Cherokee Oil/1236 . I
Matrix:
Date Received:03/17 /95
I
Date Sampled:03/13/95
I
Client Samnle#: CO-SS-02
% Solids:
Initial Wt/Vol:
Final Wt/Vol:
503034-2 ·
Soi!'
85.4
5.02 g
5.00 g
\ Sw=gate Compound 11 "';:;:b II ~:n, II LI~~S I Rec~~ery I Note I
I l1,2-Dichloroethane-d4 03/21/95 §§ 70-121 8E§ I Toluene-d8 03/21/95 0 84-138 ll--------'--==:.:....:=----------1>=0.:::3/2=1/"'9~5 0 >---5-9--1-13 _ ___, S . I Bromofluorobenzene ..
I
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11
11
11
11
1·•
1•
• = Surrogate(s) out of QC Limits (see case narrative) .,
D = Diluted out
I .~ r:-, 1-~I l~"I KTRRR ENVIRONMENTAL SERVICES; INC •.
I ,l=============V=O=LA=T=IL=E=RE=S=U=L=T=S=============sl I ,= SW-846-8260
' I
' ' ' ' ' ' ' ' ' ' I
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Client Name: Roy F. Weston
Project Name/#: Cherokee Oil/1236
Date Received:03/17 /95
Date Sampled:03/13/95
Client Samnle #: CO-SB-03
CASNwnber
II
Compound Name •
67-64-1 Acetone
71-43-2 ' Benzene
75-27-4 Bromodichloromethane
75-25-2 Bromoform
74-83-9 Bromomethane
78-93-3 2-Butanone(Methvl ethvl ketone)
75-15-0 Carbon disulfide
56-23-5 Carbon tetrachloride
108-90-7 Chlorobenzene
75-00-3 Chloroethane
67-66-3 Chloroform
74-87-3 Chloromethane
124-48-1 Dibromochloromethane
75-34-3 I, 1-Dichloroethane
107-06-2 1,2-Dichloroethane
75-35-4 I , 1-Dichloroethene .
540-59-0 1,2-Dichloroethene (total)
78-87-5 1,2-Dichloroorooane
10061-01-5 cis-1,3-Dichloropropene
10061-02-6 trans-1,3-Dichloropropene
100-41-4 Ethyl benzene
591-78-6 2-Hexanone
75-09-2 Methvlene chloride
108-10-1 4-Methvl-2-nentanone (MIBK)
100-42-5 Styrene
79-34-5 I, 1,2,2-Tetrachloroethane
127-18-4 Tetrachloroethene
108-88-3 Toluene
71-55-6 I, I, I-Trichloroethane
79-00-5 I, 1,2-Trichloroethane
79-01-6 Trichloroethene
108-05-4 Vinvl acetate
75-01-4 Vin,! chloride
1330-20-7 Xvlene (total)
Note:
I
E = Concentration exceeds calibration range (results estimated)
J = Estimated value (less than PQL but greater than zero)
Dilution
Factor
5
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
' I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
B = Analyte found in blank (possible/probable blank contamination)
I
Lab Sample ID:
Matrix:
% Solids:
Initial Wt/Vol:
Final Wt/Vol:
Analysis
II Date
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95 .
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
503034-3
Result
ug/kg
. 1540
3.9
BQL
BQL
BQL
110
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
6
3.6
6.4
39
BQL
BQL
2.2
27
BOL
BQL
2.2
BQL
BQL
25
Soil
77.3
5.13 g
5.00 Q
J~EJ
63 E
13 J
13
13
13
13
13
13
13
13
. 13
13
13
13 ,
13
13
13
13
13
13
13 J
13 J
13 BJ
13
13
13
13 J
13
13
13
13 J
13
13
13
BQL = Below Quanlitation Limit
PQL = Practical Quantitation Limit
NA = Not Applicabl,,
•
KTBER ENVIRONMENTAL SERVICES, INC.
VOLATILE SURROGATE RECOVERIES. __
SW-846-8260 -·
. ' .
I
I I l:======================================sl I
I
Client Name: Roy F. Weston
Project Name/#: Cherokee Oil/1236
Date Recelved:03/17 /95
Date Sampled:03/13/95
Client Sample#: CO-SB-03
Lab Sample ID: ..
Matrix,-~-
% Solids:·
Initial Wt/Vol:
Final WilV ol:
503034-3·
Soil
77.3 ·
5.13 g
5.00 R
I I Surro:au Compound II ~~~b II ~!nt II LI~~S I % I Nou I
1
,__ _______ J~,_2-_D_ic_hl_o_ro_e_th_m1_e_-_d4 _______ +0_3_/_2_1/_95__,§3 70-121 §§Reco
6
v
9
ery § .I Toluene-d8 03/21/95 0 1---84_-_13_8 _ _, r Bromofluorobenzene 03/21/95 O 59-113
* = Surrogate(s) out of QC Limits (see case narrative)
D ; Diluted out
I
c~>1 n ·.; :.-·., \~I '
KJREB ENVIRONMENTAL SERVICES;INc,
VOLATILE RESULTS
SW-846-8260
Client Name: Roy F. Weston
Project Name/#: Cherokee Oil/1236
Date Received:03/17 /95
Lab Sample ID:
Date Sampled:03/13/95
Client Samole #: CO-SB-04
CASNumber
II
Compowad Name
I
67-64-1 Acetone
71-43-2 Benzene
75-27-4 Bromodichloromethane.
75-25-2 Bromoform ·
74-83-9 Bromomethane
78-93-3 2-Butanone(Methyl ethyl ketone)
75-15-0 Carbon disulfide
56-23-5 Carbon tetrachloride
108-90-7 Chlorobenzene
75-00-3 Chloroethane
67-66-3 Chloroform
74-87-3 Chloromethane
124-48-1 Dibromochloromethane
75-34-3 l , 1-Dichloroethane
107-06-2 1,2-Dichloroethane
75-35-4 I, 1-Dichloroethene
540-59-0 1,2-Dichloroethene (total)
78-87-5 1,2-Dichloropropane
10061-01-5 · cis-1,3-Dichloropropene
10061-02-6 trans-1,3-Dichloropropene
100-41-4 Ethylbenzene
591-78-6 2-Hexanone
75-09-2 Methylene chloride
108-10-1 4-Methyl-2-oentanone (MIBK)
100-42-5 Styrene
79-34-5 1, 1,2,2-Tetrachloroethane
127-18-4 Tetrachloroethene
108-88-3 Toluene
71-55-6 1,1,I-Trichloroethane .
79-00-5 1, 1,2-Trichloroethane
79-01-6 Trichloroethene
108-05-4 Vinyl acetate
75-01-4 Vinyl chloride
1330-20-7 Xylene (total)
Note.
E = Concentration exceeds calibration range (results estimated)
J = Estimated value (less than PQL but greater than zero)
Dilution
Factor
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
B = Analyte found in blank (possible/probable blank contamination)
I
Matrix:
% Solids:
Initial Wt/Vol:
Final Wt/Vol:
Analysis
II Date
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95.
03/21/95
03/21/95
03/21/95
503034-4
Soil
78.7
5.01 g
5.00 2
Re.suit l~EJ ug/kg
JOO 13
BQL 13
BQL 13
BQL 13
BQL 13
25 13
BQL 13
BQL 13
BQL 13
BQL 13
BQL 13
BQL 13
BQL 13
BQL 13 ,
BQL 13
BQL 13
BQL 13
BQL 13
BQL 13
BQL 13
BQL 13
BQL 13
4.2 13 BJ
4.5 13 J
BQL 13
BQL 13
BQL 13
BQL 13
BQL 13
BQL 13
5.6 13 J
BQL 13
BQL 13
BQL 13
BQL = Below Quantitation Limit
PQL = Practical Quantitation Limit
NA= Not Applicable
' n a
KIBER ENVIRONMENTAL SERVICES; INC,
rl ,l==========v=o=LA=T=IL=E=s=u=RR=o=G=A=T=E=RE=c=o=VE=RIE==s==========:i Ir ,.= SW-846-8260
' '
Client Name: Roy F. Weston
Project Name/#: Cherokee Oil/I 236
Date Received:03/17 /95
Date Sampled:03/13/95
Client Samole #: CO-SB-04
Lab Sample ID:
Matrix:
% Solids:
Initial Wt/Vol:
Final Wt/Vol:
503034-4
Soil
78.7
5.01 g
5.00 g
' 1,1 ========S=urro=e=•=t.=C=om=p=o=un=d========sl,l=An=D=~=;';=ls=l::=I ==~=P=:!=t==(l,I ==L=I=~=iT=S==sl: =I=l•=;~=:•=ry=sl Not. I
l,2-Dichloroethane-d4 03/21/95 §§ 70-121 ~2 § .I ,>-________ T_o_lu_en_e-0_8 _________ ,00_3_/2_1_~---<5 0 ,__8_4-_1_3_8_~ 1
9
0
5
9 r Bromofluorobenzene 03/21/95 0 59-113 .I • = Surrogate(s) out of QC Limits (see case narrative) r D = Diluted out
I
' ' ' ' ' ' i
I
I
I
I
I
-.·.
KIBER ENVIRONMENTAL SERVICES, INC,
QUALITY CONTROL VOLATILE RESULTS
SW-846-8260
Client Name: Roy F. Weston
Project Name/#: Cherokee Oil/1236
Date Received: NA
Date Sampled: NA
Client Samole #: NA
CASNumber II Compound Name I
67-64-1 Acetone
71-43-2 Benzene
75-27-4 Bromodichloromethane
75-25-2 Bromoform.
74-83-9 Bromomethane
78-93-3 2-ButanonefMethyl ethyl ketone)
75-15-0 Carbon disulfide
56-23-5 Carbon tetrachloride
108-90-7 Chlorobenzene
75-00-3 Chloroethane
67-66-3 Chloroform
74-87;3 Chloromethane
124-48-1 Dibromochloromethane
75-34-3 I, 1-Dichloroethane
107-06-2 1,2-Dichloroethane
75-35-4 l, 1-Dichloroethene
540-59-0 1,2-Dichloroethene (total)
78-87-5 1,2-Dichloroorooane
10061-01-5 · cis-1,3-Dichloropropene
10061-02-6 trans-1,3-Dichloropropene
100-41-4 Ethyl benzene
591-78-6 2-Hexanone
75-09-2 Methylene chloride
108-10-1 4-Methyl-2-pentanone (MIBK)
100-42-5 Styrene
79-34-5 1, 1,2,2-Tetrachloroethane
127-18-4 Tetrachloroethene
108-88-3 Toluene
71-55-6 I, I, I-Trichloroethane .
79-00-5 l, 1,2-Trichloroethane
79-01-6 T richloroethene
108-05-4 Vinyl acetate
75-01-4 Vinyl chloride
1330-20-7 Xylene (total)
Note.
E = Concentration exceeds calibration range (results estimated)
J = Estimated value (less than PQL but greater than zero)
Dilutton
Factor
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
B = Analyte found in blank (possible/probable blank contamination)
Lab Sample ID:
Matrix:
% Solids:
Initial Wt/Vol:
Final Wt/Vol:
I Arullysls II Dau
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
503034-B ·. ·
Soil
NA
5.00 g
5.00 g
Result IU&JEJ ugikg
BQL 10
BQL 10
BQL 10
BQL 10
BQL 10
BQL 10
BQL 10
BQL , 10
BQL 10
BQL . '10
BQL 10
BQL 10
BQL 10
BQL 10 ,
BQL 10
BQL . 10
BQL 10
BQL : 10 ·
BQL 10
BQL 10
BQL 10
BQL 10
4.5 '10 J
BQL 10
BQL 10
BQL 10
BQL 10
BQL 10
BQL 10
BQL 10
BQL 10
BQL 10
BQL 10
BOL 10
BQL = Below Quantii:ation Limit
PQL = Practical Quar,.titation Limit
NA= Not Applicable
'
/-~. C.· \)"3 \·'::1
KIBEB ENVIRONMENTAL SERVICES, INC,
.I L==========v=o=LA='l='IL=E=s=u=RR=o=G=A=T=E=RE=c=o=VE=RIE==s==========il r ,.--SW-846-8260
' '
Client Name: Roy F. Weston
Project Name/#: Cherokee Oil/1236
Date Received: NA
Date Sampled: NA
Client Samnle #: NA
Lab Sample ID:
Matrix:
% Solids:
Initial Wt/Vol:
Final Wt/Vol:
503034-B .
Soil
NA
5.00 g
5.00 ,
' I Surroeau Compound II ~i.b II ~!nt II LI~iTs II Rec';very I Nou I
1,2-Dichloroethane-d4 03/21/95 ~ 70-121 ~H
' le---------B-ro-:-=--:=~.:::~:=~=-:~--=~=~-e-n_e __ ------~l>=-~3=3~-=2.:.::~-=--:~=-a~>---:-::-:-~-~--''~D
• = Surrogate(s) out of QC Limits (see case narrative)~
' ' ' ' ' ' I
f
I
I
I
I
I
D = Diluted out
/:7""" ...... , 1°:·,, ;'
,.---:-:,
:_·~-~ ~-J
' KTBER ENVIRONMENTAL SERVICES, INC.
' Quality Control Results
'
,l===============B~l~an~k~S~p~i~ke~(B~S)===============il '"' SW-846-8260 < --
Client Name: Roy F. Weston Lab Sample ID: 503034-BS
'
Project Name/#: Cherokee Oil/1236 Matrix: Soil
Date Received: NA % Solids: NA
Date Sampled: NA Initial Wt/Vol: 5.00 g
' Client Samnle #: NA Final Wt/Vol: 5.00 o
' ' ' ' ' ' ' ' ' I
I
I
I
I
I
Compound
1,1-Dichloroethene
Trlchloroethene
Benze~e
Toluene
Chlorobenzene
• = QC outside limits
D = Diluted out
I
BLANK SPIKE(BS)
Splk, Blank BS
Concentration Concentration Concentration ,
Added ualka u·"•-
50.0 0.0 31.92
50.0 0.0 38.63
50.0 0.0 39.84
50.0 0.0 44.93
50.0 0.0 48.76
BS Recovery E] % Lhnlts
Recoverv %
64 59-172
77 62-137
80 66-142
90 59-139
98 60-133
I
I
I
,:--.
'.,·t:.1
KIBER ENVIRONMENTAL SERVICES, INC,
Qualitll Control Results I
Matrix Spike(MS) & Matrix Spike Duplicate(MSD)
SW-846-8260 .-·
Client Name: Roy F. Weston Lab Sample ID: 503034-4MS,MSD
Project Name/#: Cherokee Oil/1236 Matrix: Soil
Date Received:03/17 /95 % Solids: 78.7
Date Sampled:03/13/95 Initial Wt/Vol: 5.11 g
Client Samole #: CO-SB-04 Final Wt/Vol: 5.00 g
MATRIX SPIKE(MS)
I
Sp= ~ample
I Co•::tio,n I
"'" Kecovery B Compound Concentration Concentration % Limits
Added •·"'· Recoverv %
1,1-Dkhloroethene 62.16 0.00 71.39 Ill 59-172
Trlchloroethene 62.16 5.45 50.68 82 62-137
Benzene 62.16 0.00 50.54 81 66-142
Toluene 62.16 0.00 63.37 102 59-139
Chlorobenzene 62.16 0.00 65.21 105 60-133
Initial Wt/Vol: 5.06 g
Compound
1,1-Dichloroethene
Trlchloroethene
Benzene
Toluene
Chlorobenzene
• = QC outside limits
D = Diluted out
**=Batch QC Results
I
.
MATRIX SPIKE DUPLICATE(MSD)
Sp= .
I Con=tion II
MSD
Concentration %
Added Recovery
62.16 56.41 91
62.16 42.48 68
62.16 47.79 77
62.16 57.84 93
62.16 60.56 97
II ;;D I
..,~ B Limits
RPD °lo Recove'""
23.4 14 59-172 •
17.6 14 62-137 •
5.6 11 66-142
9.1 13 59-139
7.4 13 60-133
I c, f::1 .. :·~
KIBER ENVIRONMENTAL SERVICES.INC,
.J I SEMIVOLATILE RESULTS Ir l:C==============c:S~W~-8~4~6-=35=5=0=/8=27=0=A==============~
I Client Name: Roy F. Weston Lab Sample ID: 503034-1
03/24/95
81.2
2.19 g
2.00 ml
NA
· Project Name/#: Cherokee Oil/1236 Date Extracted:··
Date Sampled:03/13/95 % Solids:
I Date Receivcd:03/17 /95 Initial Wt/Vol:•
Matrix: Soil Final Vol:
Client Samnle #: CO-SS-0 I Clea nun/#:
I
I
I
I
I
I
' ' ' ' I
I
I
I
I
I CASNumber II Compound Name
83-32-9 Accnaphthene
208-96-8 Accnaphthylene
120-12-7 Anthraccne
56-55-3 Benzo(a)anthraccne
205-99-2 Benzo(b )lluoranthene
207-08-9 Benzo(k)lluoranthene
65-85-0 Benzoic acid
191-24-2 Benzo(g,h,i)perylene
193-39-5 Benzo(a)pvrene
100-51-6 Ben7Vl alcohol
111-91-1 . bis(2-Chloroethoxv)methane
111-44-4 bis(2-Chloroethyl)ether
108-60-1 bis(2-Chloroisopropyl)ether
117-81-7 bis(2-Ethylhexyl)phthalate
101-55-3 4-Bromophenvl-phenvlether
85-68-7 Butvlben7Vlphthalate
106-47-8 4-Chloroaniline
59-50-7 4-Chloro-3-methylphenol
91-58-7 2-Chloronaphthalene
95-57-8 2-Chlorophenol
7005-72-3 · 4-Chloronhenvl-phenvlether
218-01-9 Chrvsene
53-70-3 Dibenz(a,h)anthracene
132-64-9 Dibenzofuran
84-74-2 Di-n-butylphthalate ·
95-50-1 1,2-Dichlorobenzene
541-73-1 1,3-Dichlorobenzene
106-46-7 1,4-Dichlorobenzene
91-94-1 3,3'-Dichlorobenzidene
120-83-2 2,4-Dichlorophenol
84-66-2 Diethvlohthalate
105-67-9 2,4-Dimethvlohenol
131-11-3 Dimethvlnhthalate
Note:
E = Concentration exceeds calibration range (results estimated)
J = Estimated value (less than PQL but greater than zero)
I
B = Analyte found in blank (possible/probable blank contamination)
Dilution I Factor
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
Arudysls II Result
Date uelk,
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94' BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 44000
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BOL
BQL = Below Quantitation Limit
PQL = Practical Quantitation Limit
NA= Not Applicable
1~8i
56000
:56000
56000
56000
56000
56000
56000
56000
56000
56000
56000
56000
56000
56000 , J
56000
56000
56000
56000
56000
56000
56000
56000
56000
56000
56000
56000
56000
56000
56000
56000
56000
56000
56000
' r ·1 r"c'':) ,---. ' i· !. -,
KTRER ENVIRONMENTAL SERVICES: INC,
rl I SEMIVOLATILE RESULTS r l!===============S~W~-8~4~6-~35=5~0~/8~27~0~A~============~I
I Client Name: Roy F. Weston Lab Sample ID: 503034-1
. Project Name/#: Cherokee Oil/1236 Date Extracted: 03/24/95
Date Sampled:03/13/95 % Solids: 81.2
'
Date Received:03/17 /95 Initial WIN ol: 2. I 9 g
Matrix: Soil Final Vol: 2.00 ml
Client Samnle #: CO-SS-01 Cleanup/#: NA ' ~=============='=============!.
I CASNwnber II Compound Name I DUutlon I Analysls II Result IWEJ II Factor
f
I
' ' ' ' ' f
' I
I
I·
I
I
534-52-1 4,6-Dinitro-2-methylphenol
51-28-5 2,4-Dinitrophenol
121-14-2 2,4-Dinitrotoluene
606-20-2 2,6-Dinitrotoluene
117-84-0 Di-n-octvlphthalate
206-44-0 Fluoranthene
86-73-7 Fluorene
118-74-1 Hexachlorobenzene
87-68-3 Hexachlorobutadiene
77-47-4 Hexachlorocyclopentadiene
67-72-1 Hexachloroethane
193-39-5 Indeno(J ,2,3-cd)pyrene
78-59-1 Isophorone
91-57-6 2-Methylnaphthalene
95-48-7 2-Methylphenol
106-44-5 4-Methylphenol
91-20-3 Naphthalene
88-74-4 2-Nitroaniline
99-09-2 3-Nitroaniline
100-01-6 4-Nitroaniline
98-95-3 Nitrobenzene
88-75-5 2-Nitroohenol
100-02-7 4-Nitrophenol
86-30-6 N-Nitrosodiphenylamine
621-64-7 N-Nitroso-di-n-propylamine
87-86-5 Pentachlorophenol
85-01-8 Phenanthrene
108-95-2 Phenol
129-00-0 Pyrene
120-82-1 1,2,4-Trichlorobenzene
95-95-4 2,4,5-Trichlorophenol
88-06-02 2 4 6-Trichloroohenol
Note:
E = Concentration exceeds calibration range (results estimated)
J = Estimated value (less than PQL but greater than zero)
B = Analyte found in blank (possible/probable blank contamination)
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
Date u,11<,
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 2300
03/24/94 BQL
03/24/94' BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BOL
BQL = Below Quantitation Limit
PQL = Practical Quantitation Limit
NA= Not Applicable
56000
56000
56000
56000
56000 J
56000
56000
56000
56000
56000
56000
56000
56000
56000
56000
56000
56000
56000
56000
56000
56000
56000
56000
56000
56000
56000
56000
56000
56000
56000
56000
56000
I f':'1 «:?)
KT;a'ER ENVIRONMENTAL SERVICEs;'rnc •
.J I SEMIVOLATILE RESULTS r · · SW-846-3550/8270A la====================================================;I I
I
I
I
' I
f
I
' ' f
' ' I
I
I
D
I
Client Name: Roy F. Weston
. Project Name/#: Cherokee Oil/1236
Date Sampled:03/13/95
Date Received:03/17 /95
Matrix: Soil
Client Sample#: CO-SS-01
Surrogate Compound
2-Fluorophenol
Phenol-d6
Nitrobenzene-d5
2-Fluorobiohenvl
2,4,6-Tribromophenol
Ternhenvl-dl4
• = Surrogate(s) out of QC Limits (see case narrative)
D = Diluted out
1§1
03/24/94
03/24/94
03/24/94
03/24/94
03/24/94
03/24/94
Lab Sample ID:
Date Extracted,-···
% Solids:
Initial Wt/Vol:
Final Vol:
Cleanun/#:
SpU..
II Amount
112468
112468
56234
56234
112468
56234
503034-1 .
03/24/95
81.2
2.19 g
2.00 ml
NA
QC ¾
LIMITS I Recovery
25-121 44
24-113 67
23-120 58
30-115 81
19-122 79
I 8-137 54
I Nou I
I c, p,
KIBER ENVIRONMENTAL SERVICES~ iNC,
.. I SEMIVOLATILE RESULTS \1 r SW-846-3550/8270A -1
l:=c=============~~=======~=====L==s ==m=====50=3=03=4=.2====~1· I Client Name: Roy F. Weston ab ample :
Project Name/#: Cherokee Oil/1236 Date Extracted: 03/24/95 II
Date Sampled:03/13/95 % Solids: 85.4
'
Date Received:03/17 /95 Initial Wt/Vol: 2.21 g
Matri:I: Soil Final Vol: 2.00 ml
Client Sam le#: CO-SS-02 Cleanu /#: NA ,~~===~===============!I
I
CASNumber
II
Compound Name
I Dilution I Analysis
II
Result IW8 I
I
I
I
I
I
' ' ' ' I
I
B
B
83-32-9 Acenaphthene
208-96-8 · Acenaphthylene
120-12-7 Anthracene
56-55-3 Benzo(a)anthracene
205-99-2 Benzo(b )fluoranthene
207--08-9 Benzo(k)fluoranthene
65-85-0 Benzoic acid
191-24-2 Benzo(g,h,i)perylene
193-39-5 Benzo(a)nvrene
100-51-6 Benzvl alcohol
111-91-1 bis(2-Chloroetho"")methane
111-44-4 bis(2-Chloroethyl)ether
108-60-1 . bis(2-Chloroisopropyl)ether
117-81-7 bis(2-Ethylhexyl)phthalate
101-55-3 4-Bromoohenyl-ohenvlether
85-68-7 Butvlben7Vlohthalate
106-47-8 4-Chloroaniline
59-50-7 4-Chloro-3-methylphenol
91-58-7. 2-Chloronaphthalene
95-57-8 2-Chlorophenol
7005-72-3 ·4-Chloroohenvl-ohenvlether
. 218--01-9 Chrvsene
53-70-3 Dibenz(a,h)anthracene
132-64-9 Dibenzofuran
84-74-2 Di-n-butylphthalate
95-50-1 1,2-Dichlorobenzene
541-73-1 1,3-Dichlorobenzene
106-46-7 1,4-Dichlorobenzene
91-94-1 3 ,3 '-Dichlorobenzidene
120-83-2 2,4-Dichlorophenol
84-66-2 Diethylphthalate
105-67-9 2,4-Dimethylohenol
131-11-3 Dimethvlohthalate
Note:
E = Concentration exceeds calibration range (results estimated)
J = Estimated value (less than PQL but greater than zero)
B = Anaiyte found in blank (possible/probable blank contamination)
Factor
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
Dat. ug/ke
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/9,4 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
. 03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 87000
03/24/94 BQL
03/24/94 5000
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BOL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BOL
BQL = Below Quantitation Limit
PQL = Practical Quantitation Limit
NA= Not Applicable
53000
53000
53000
53000
53000
53000
53000
53000
53000
53000
53000
53000
53000
53000
53000
53000 J
53000
53000
53000
53000
53000
53000
53000
53000
53000
53000
53000
53000
53000
53000
53000
53000
53000
0 ,;. , I
KTBER ENVIRONMENTAL SERVICES, lNC.
I
SEMNOLATILE RESULTS I SW-846-3550/8270A ·
Client Name: Roy F. Weston Lab Sample ID: 503034-2
Project Name/#: Cherokee Oil/1236 Date Extracted: 03/24/95
Date Sampled:03/13/95 % Solids: 85.4
Date Received:03/17 /95 Initial Wt/Vol: 2.21 g
Matrix: Soil Final Vol: 2.00 ml
Client Samnle #: CO-SS-02 Cleanun/#: NA
I CASNumber II Compound Name I DUution I Analysis II ResuJt IW8 Factor Dato ••llo!
534-52-1 4,6-Dinitro-2-methylphenol 5 03/24/94 BQL 53000
51-28-5 2,4-Dinitrophenol 5 03/24/94 BQL 53000
121-14-2 2,4-Dinitrotoluene . 5 03/24/94 BQL 53000
606-20-2 2,6-Dinitrotoluene 5 . 03/24/94 BQL 53000
117-84-0 Di-n-octvlohthalate 5 03/24/94 5300 53000 J
206-44-0 Fluoranthene 5 03/24/94 BQL 53000
86-73-7 Fluorene 5 03/24/94 ' BQL 53000
118-74-1 Hexachlorobenzene 5 03/24/94 BQL 53000
87-68-3 Hexachlorobutadiene 5 03/24/94 BQL 53000
77-47-4 Hexachlorocvclooentadiene 5 03/24/94 BQL ·53000
67-72-1 Hexachloroethane 5 03/24/94 BQL 53000
193-39-5 Indeno( 1,2,3-cd)pyrene 5 03/24/94 BQL 53000
78-59-1 Isophorone 5 03/24/94 BQL 53000
91-57-6 2-Methylnaphthalene 5 03/24/94 BQL 53000
95-48-7 2-Methvlnhenol 5 03/24/94 BOL 53000
I 106-44-5 4-Methvlohenol 5 03/24/94 BQL 53000
91-20-3 · Naohthalene 5 03/24/94 BQL 53000
88-74-4 2-Nitroaniline 5 03/24/94 BQL 53000
I 99-09-2 3-Nitroaniline 5 03/24/94 BQL 53000
100-01-6 4-Nitroaniline 5 03/24/94 BQL 53000
98-95-3 Nitrobenzene 5 03/24/94 BQL 53000
88-75-5 2-Nitroohenol 5 03/24/94 BQL 53000
'
100-02-7 4-Nitroohenol 5 03/24/94 BQL 53000
86-30-6 N-Nitrosodiphenylamine 5 03/24/94 BQL 53000
621-64-7 N-Nitroso-di-n-propylamine 5 03/24/94 BQL 53000
'
87-86-5 Pentachloronhenol 5 03/24/94 BQL 53000
· 85-01-8 Phenanthrene 5 03/24/94 3900 53000 J
I 108-95-2 Phenol 5 03/24/94 BQL 53000
129-00-0 Pvrene 5 03/24/94 3l00 53000 J
120-82-1 1,2,4-Trichlorobenzene 5 03/24/94 BOL 53000
95-95-4 2,4,5-Trichlorophenol 5 03/24/94 BQL 53000
88-06-02 2 4 6-Trichloronhenol 5 03/24/94 BOL 53000 I Note:
I
I
I
E = Concentration exceeds calibration range (results estimated)
J = Estimated value (less than PQL but greater than zero)
B = Analyte found in blank (possible/probable blank contamination)
BQL = Below Quantitation Limit
PQL = Practical Quantitation Limit
NA= Not Applicable
' (?~ (?,
KIBRR ENVIRONMENTAL SERVICES'.'.tNc.
I I SEMIVOLATILERESULTS r SW-846-3550/8270A la================================================ 503034-2 ,
03/24/95
85.4
2.21 g
2.00 ml
NA
I
I
' ' ' ' ' I
' ' ' f
I
I
I
I
I
I
Client Name: Roy F. Weston .
Project Name/#: Cherokee Oil/1236
Date Sampled:03/13/95
Date Received:03/17 /95
Matrix: Soil
Client Sam le#: CO-SS-02
SWTOeate Compound
2-Fluorophenol
· Phenol-d6
Nitrobenzene-d5
2-Fluorobiphenyl
2,4,6-Tribromophenol
· Terohenvl-dl4
• = Surrogate(s) out of QC Limits (see case narrative)
D = Diluted out
1§1
03/24/94
03/24/94
03/24/94
03/24/94
03/24/94
03/24/94
Lab Sample ID:
Date Extracted:
% Solids:
Initial Wt/Vol:
Final Vol:
Cleanu /#:
Spike
II Amount
105969
105969
52985
52985
105969
52985
QC 1 · o/, E LIMITS : Reco:ery
25-121 62
24-113 71
23-120 61
30-115 86
19-122 86
18-137 51
I ,cc-,\ c'\ i ... ) (:./;
KIBER ENVIRONMENTAL SERVICES:\INC.
I I SEMIVOLATILERESULTS
l~==================SW==-8=4=6-=3=55=0=/8=2=70=A=====================\I
I CUent Name: Roy F. Weston Lab Sample ID: 503034-3
. Project Name/#: Cherokee Oil/1236 Date Extracted:· 03/21/95
I
I
I
I
I
I
n
D
D
I
I
I
I
I
I
Date Sampled:03/13/95 % SoUds: · 77 .3
Date Received:03/17 /95 Initial Wt/Vol: 30.77 g
Matrix: Soil Final Vol: 1.00 ml
CUent Samnle #: CO-SB-03 Cleanun/#: NA
CASNumbcr II Compound Name I DUutton I Analysis II Result IWEJ Factor Date u"'1<,
83-32-9 Acenaphthene
208-96-8 Acenaphthylene
120-12-7 Anthracene
56-55-3 Benzo(a)anthracene
205-99-2 Benzo(b )fluoranthene
207-08-9 Benzo(k)fluoranthene
65-85-0 Benzoic acid
191-24-2 Benzo(g,h,i)perylene
193-39-5 Benzo(a)nvrene
100-51-6 Ben7VI alcohol
111-91~1 bis(2-Chloroethoxv)methane
111-44'.4 bis(2-Chloroethyl)ether
108-60-1 bis(2-Chloroisopropyl)ether
117-81-7 bis(2-Ethylhexyl)phthalate
101-55-3 4-BromophenY.l-phenylether
85-68-7 Butylbenzvlphthalate
106-47-8 4-Chloroaniline
59-50-7 4-Chloro-3-methylphenol
91-58-7 2-Chloronaphthalene
95-57-8 2-Chlorophenol
7005-72-3 · 4-Chlorophenyl-phenylether
218-01-9 Chrvsene
· 53-70-3 Dibenz(a,h)anthracene
132-64-9 Dibenzofuran
84-74-2 Di-n-butylphthalate
95-50-1 1,2-Dichlorobenzene
541-73-1 1,3-Dichlorobenzene
106-46-7 1,4-Dichlorobenzene
91-94-1 3,3'-Dichlorobenzidene
120-83-2 2,4-Dichlorophenol
84-66-2 . Diethylphthalate
105-67-9 2,4-Dimethylphenol
131-11-3 Dimethvlohthalate
Note:
E = Concentration exceeds calibration range (results estimated)
J = Estimated value (less than PQL but greater than zero)
B = Analyte found in blank (possible/probable blank contamination)
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
03/22/94 BQL
03/22/94 BQL
03/22/94 . BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 ' BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 4l00
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 110
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
BQL = Below Quantitation Limit
PQL = Practical Quantitation Limit
NA= Not Applicable
2100
2l00
2100
2l00
2100
2100
2100
2100
2100
2100
2100
2100
2100
2100
2l00
2l00
2100
2100
· 2l00
2100
2100
2100
2100
2l00
2l00 J
2l00
2l00
2l00
2l00
2l00
2l00
2100
2100
I KIBER ENVIRONMENTAL SERVICES. INC,
I I SEMIVOLATILE RESULTS
l!===============S=W===-8=4=6=-3=5=50=/=82=7=0=A==================sl
I
I
I
I
I
I
I
I
I
I
I
Client Name: Roy F. Weston
Project Name/#: Cherokee Oil/I 236
Date Sampled:03/13/95
Date Received:03/17 /95
Matrix: Soil
Client Samnle #: CO-SB-03
CASNumbcr II Compound Name
534-52-1 4,6-Dinitro-2-methylphenol
51-28-5 2,4-Dinitrophenol
121-14-2 2,4-Dinitrotoluene
606-20-2 2,6-Dinitrotoluene
117-84-0 Di-n-octvlohthalate
206-44-0 Fluoranthene
86-73-7 F!uorene
118-74-1 Hexachlorobenzene
87~8-3 Hexachlorobutadiene
77-47-4 Hexachlorocvclooentadiene
67-72-1 Hexachloroethane
193-39-5 lndeno(l ,2,3-cd)pyrene
78-59-1 Isophorone
91-57~ 2-Methylnaphthalene
95-48-7 2-Methv)ohenol
106-44-5 4-Methvlohenol
91-20-3 Nanhtha!ene
88-74-4 2-Nitroaniline
99-09-2 3-Nitroaniline
100-01~ 4-Nitroaniline
98-95-3 Nitrobenzene
88-75-5 2-Nitroohenol
100-02-7 4-Nitroohenol
86-30~ N-Nitrosodiphenylamine
621~4-7 N-Nitroso-di-n-propylamine
87-86-5 Pentachloroohenol
85-01-8 Phenanthrene
108-95-2 Phenol
129-00-0 Pvrene
120-82-1 1,2,4-T richlorobenzene
95-95-4 2,4,5-Trichlorophenol
88-06-02 2 4 6-Trichloronhenol I Note:
E = Concentration exceeds calibration range (results estimated)
J = Estimated value (less than PQL but greater than zero)
I Dilution
Factor
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
B = Analyte found in blank (possible/probable blank contamination)·.
I
I
Lab Sample ID:
Date Extracted:
% Solids:
Initial Wt/Vol:
Final Vol:
Clea nun/#:
503034-3
03/21/95
77.3
30.77 g
1.00 ml
NA
Analyst, II Result 1~8 Date u"'1<1,
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 67
03/22/94 BQL
03/22/94' BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BOL
BQL = Below Quantitation Limit
PQL = Practical Quantitation Limit
NA= Not Applicable
2100
2100
2100
2100
2100 J
2100
· 2100
2100
2100
2100
2100
2100
2100
2100
2100
· 2100
2100
2100
2100
2100
2100
2100
2100
2100
2100
2100 .
2100
2100
2100
2100
2100
2100
I (}:)1 (t;;J
KJREB ENVIRONMENTAL SERVICES, INC.
I I SEMIVOLATILERESULTS
l~================S=W==-8=4=6-=3=55=0=/8=27=0=A===================~I Ii Client Name: Roy F. Weston Lab Sample ID: 503034-3 ·,
II Project Name/#: Cherokee Oil/1236 Date Extracted: 03/21/95
Date Sampled:03/13/95 % Solids: 77 .3
Date Received:03/17 /95 Initial Wt/Vol: 30.77 g g Matrix: Soil Final Vol: 1.00 ml
Client Samole #: CO-SB-03 Cleanun/#: NA
I
I
I
I
Surroeate Compowid
2-Fiuorophenoi
Phenol-d6
· Nitrobenzene-d5
2-Fluorobiohenvi
2,4,6-Tribromoohenol
Terohenvl-dl4 .. I • = Surrogate(s) out of QC Luruts (see case narrative)
II D = Diluted out
n
D
u
H
I
I
I
I
1§1 Spike
II
QC
Amount LIMITS
03/22/94 8409 25-121
03/22/94 · 8409 24-113
03/22/94 4204 23-120
03/22/94 4204 30-115
' 03/22/94 8409 19-122
03/22/94 4204 18-137
I
'lo
Recovery
62
80 -
80
95
88
131
I Note I
I (:) (; :>
KIBER ENVIRONMENTAL SERVICES/INC,
I I SEMIVOLATILE RESULTS
H===============S=W=-=8=46=-3=5=5=0/=82=7=0=A===c===========c=======:I
D Client Name: Roy F. Weston Lab Sample ID: 503034-4
D
D
I
I
I
I
I
I
I
I
I
I
I
I
I
I
.Project Name/#: Cherokee Oil/1236 Date Extracted: 03/21/95
Date Sampled:03/13/95 % Solids: 78.7
· Date Received:03/17/95 Initial Wt/Vol: 30.91 g
Matrix: Soil Final Vol: 1.00 ml
Client Samole #: CO-SB-04 Clcanun/#: NA
CASNumber II Compound N~e I Dilution I Analysb II Result l~B Factor Dat, ul!ik.e
83-32-9 Acenaphthene
208-96-8 Acenaphthylene
120-12-7 Anthracene
56-55-3 Benzo(a)anthracene
205-99-2 Benzo(b )fluoranthene
207-08-9 Benzo(k)fluoranthene
65-85-0 Benzoic acid
191-24-2 Benzo(g,h,i)perylene
193-39-5 Benzo(a)nvrene
100-51-6 Benzvl alcohol
111-91-1 bis(2-Chloroethoxv)methane
111-44-4 bis(2-Chloroethyl)ether
108-60-1 bis(2-Chloroisopropyl)ether
117-81-7 bis(2-Ethylhexyl)phthalate
101-55-3 4-Bromophenv,l-phenvlether
85-68-7 Butylbenzvlphthalate
106-47-8 4-Chloroaniline
59-50-7 4-Chloro-3-methylphenol
91-58-7 · 2-Chloronaphthalene
95-57-8 2-Chlorophenol
7005-72-3 · 4-Chlorophenvl-phenvlether
218-01-9 Chrvsene
53-70-3 Dibenz( a,h)anthracene
132-64-9 Dibenzofuran
84-74-2 . Di-n-butylphthalate
95-50-1 1,2-Dichlorobenzene
541-73-1 1,3-Dichlorobenzene
106-46-7 1,4-Dichlorobenzene
91-94-1 3,3'-Dichlorobenzidene
120-83-2 2,4-Dichlorophenol
84-66-2 . Diethylphthalate
105-67-9 2,4-Dimethylphenol
131-11-3 Dimethvlohthalate
Note:
E = Conc_entration exceeds calibration range (results estimated)
J = Estimated value (less than PQL but greater than zero)
B = Analyte found in blank (possible/probable blank contamination)
I
I
I .
I
I
I
I
I
I
I
I
I
I
I
I
l
I
l
l
I
I
I
I
l
I
I
I
l
l
I
I
I
I
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 ' BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BOL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 1400
· 03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 89
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BOL
03/22/94 BQL
03/22/94 BOL
BQL = Below Quantitation Limit
PQL = Practical Quantitation Limit
NA = Not Applicable
410
410
410
410
410
410
410
410
410
410
410
410
410
410
410
· 410
410
410
410
410
410
410
410
410
410 J
410
410
410
410
410
410
410
410
I KJREB ENVIRONMENTAL SERVICES, INC,
m
I
SEMIVOLATILE RESULTS
SW-846"3550/8270A
I
la==c=u=·e=n=t =N=am=e,=R=o=y=F=. =w=e=st=on==========================La=b=S=a=m=p=Je=ID=,===so=3=0=3=4_=4========sl
. Project Name/#: Cherokee Oil/1236 Date Extracted: 03/21/95
Date Sampled:03/13/95 ¾ Solids: 78.7
Date Received:03/17/95 Initial Wt/Vol: 30.91 g
Matrix: Soil Final Vol: 1.00 ml
Client Sample#: CO-SB-04 Cleanun/#: NA
I
I
I
CASNurnber
II
Compound Name I Dilution
Factor I
Aru,Jysls.
II Result [~8 Date uglkt:
I
I
I
I
I
I
I
I
I
I
534-52-1
51-28-5
121-14-2
606-20-2
117-84-0
206-44-0
86-73-7
118-74-1
87-68-3
77-47-4
67-72-1
193-39-5
78-59-1
91-57-6
95-48-7
106-44-5
91-20-3
88-74-4
99-09-2
100-01-6
98-95-3
88-75-5
100-02-7
86-30-6
621-64-7
87-86-5
85-01-8
108-95-2
129-00-0
120-82-1
95-95-4
4,6-Dinitro-2-methylphenol
2,4-Dinitrophenol
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Di-n-octylphthalate
F!uoranthene
. Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocvclooentadiene
Hexachloroethane
Indeno(J ,2,3-cd)pyrene
!sophorone
2-Methylnaphthalene
2-MethyJphenol
4-Methy!phenol
Naphthalene .
2-Nitroaniline
3-Nitroaniline
4-Nitroaniline
Nitrobenzene
2-Nitrophenol
4-Nitrophenol
N-Nitrosodiphenylamine
N-Nitroso-di-n-propylamine
Pentachlorophenol
Phenanthrene
Phenol
Pvrene
1,2,4-Trichlorobenzene
2,4,5-Trichlorophenol
88-06-02 2.4.6-Trichloroohenol I Note:
I
I
I
E = Concentration exceeds calibration range (results estimated)
J = Estimated value (less than PQL but greater than zero)
B = Analyte found in blank (possible/probable blank contamination)
I
I
I
I
I
I
I
I
I
. I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94' BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BOL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
. 03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL.
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BOL
BQL = Below Quantitation Limit
PQL = Practical Quantitation Limit
NA = Not Applicable
410
4IO
4IO
410
410
410
410
410
4IO
410
410
410
410
4IO
4IO
· 410
410
410 .
410
4IO
410
410
410
410
410
410
410
410
410
410
410
410
D (}> (:0)
KJRER ENVIRONMENTAL SERVICES, INC,
I SEMNOLATILE RESULTS
SW-846-3550/8270A
I CUent Name: Roy F. Weston Lab Sample ID:
Project Name/#: Cherokee Oil/1236 Date Extracted:
Date Sampled:03/13/95 % Solids:
I Date Received:03/17 /95 Initial Wt/Vol:
Matrix: Soil Final Vol:
Client Sample#: CO-SB-04 Cleanuo/#:
•1 Surror;ate Compound 1§1 Spike
II Amount
I 2-Fluorophenol 03/22/94 8222
Phenol-d6 03/22/94 8222
Nitrobenzene-d5 . 03/22/94 4111
I 2-Fluorobiphenyl 03/22/94 4111
2,4,6-Tribromoohenol 03/22/94 8222
Terohenvl-d14 03/22/94 4111
I•= Surrogate(s) out of QC Linuts (see case narrative)
D = Diluted out · ·
I
I
I
I
I
I
I
I
I
I
I
503034-4
..
03/21/95
78.7
30.91 g
LOO ml
NA
QC
I
% [:] LIMITS Recovery
25-12 I 56
24-113 61
23-120 66
30-115 67
I 9-122 83
18-137 92
I
I
I
n
D
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Client Name: Roy F. Weston
8 A
KfiEB ENVIRONMENTAL sERYJCEs: iNc.
QUALITY CONTROL SEMIVOLATILE RESULTS
SW-846-3550/8270A
Lab Sample ID:
Project Name/#: Cherokee Oil/1236 Date Extracted:
Date Sampled: NA ¾ Solids:
Date Received: NA Initial Wt/Vol:
Matrix: Soi_! Final Vol:
Client Samnle #: Method Blank Cleanun/#:
503034-EB
03/21/95
NA
30.00 g
1.00 ml
NA
CASNumber II Compowid Name I DUution I Analysis II Result IWEJ Factor Date u""'2
83-32-9 Acenaphthene
208-96-8 Acenaphthylene
120-12-7 Anthracene
56-55-3 Benzo(a)anthracene
205-99-2 Benzo(b )fluoranthene
207-08-9 Benzo(k)fluoranthene
65-85-0 Benzoic acid
191-24-2 Benzo(g,h,i)pervlene
193-39-5 Benzo(a)ovrene
100-51-6 B=7Vl alcohol
111-91-1 bis(2-Chloroethoxv)methane
111-44-4 bis(2-Chloroethyl)ether ·
108-60-1 bis(2-Chloroisopropyl)ether
117-81-7 bis(2-Ethylhexyl)phthalate.
101-55-3 4-Bromoohenvl-ohenvlether
85-68-7 Butvlba1,vlohthalate
106-47-8 4-Chloroaniline
59-50-7 4-Chloro-3-methylphenol
91-58-7 2-Ch!oronaphthalene
95-57-8 2-Chlorophenol
7005-72-3 • 4-Chloroohenvl-ohenvlether
218-01-9 Chrvsene
53-70-3 Dibenz(a,h)anthracene
132-64-9 Dibenzofuran
84-74-2 Di-n-butylphthalate
95-50-1 1,2-Dichlorobenzene
541-73-1 1,3-Dichlorobenzene
106-46-7 1,4-Dichlorobenzene
91-94-1 3,3'-Dichlorobenzidene ·
120-83-2 2,4-Dichlorophenol
84-66-2 . Diethylphthalate
105-67-9 2,4-Dimethvlphenol
131-11-3 Dimethvlnhthalate
Note:
E = Concentration exceeds calibration range (results estimated)
J = Estimated value (less than PQL but greater than zero)
B = Analyte found in blank (possible/probable blank contamination)
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I .
I
I
I
I
I
I
I
I
I
I
03/22/94 BQL
03/22/94 BQL
03/22/94 BOL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 ' BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BOL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
· 03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 . BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 27
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BOL
BQL = Below Quantitation Limit
PQL = Practical Quantitation Limit
NA= Not Applicable
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330 J
330
330
330
330
330
330
330
330
D
Client Name: Roy F. Weston
w Fl)
KIBER ENVIRONMENTAL SERVICES, INC,
QUALITY CONTROL SEMIVOLATILE RESULTS
SW-846-3550/8270A
Lab Sample ID:
Project Name/#: Cherokee Oil/1236 Date Extracted:
Date Sampled: NA % Solids:
Date Received: NA Initial WtN ol:
Matrix: Soil Final Vol:
Client Samnle #: Method Blank Cleanun/#:
503034-EB
03/21/95
NA
30.00 g
1.00 ml
NA
D
I
B
I CASNumber II Compound Name , I DUutlon
Factor I Analyst, II Result IC::JB Date u<ikf
I
I
I
I
I
I
I
534-52-1
51-28-5
121-14-2
606-20-2
117-84-0
206-44-0
86-73-7
118-74-1
87-68-3
77-47-4
67-72-1
193-39-5
78-59-1
91-57-6
95-48-7
106-44-5
91-20-3
88-74-4
99-09-2
100-01-6
98-95-3
88-75-5
100-02-7
86-30-6
621-64-7
87-86-5
85-01-8
108-95-2
129-00-0
120-82-1
95-95-4
4,6-Dinitro-2-methylphenol
2,4-Dinitrophenol
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Di-n-octvlnhthalate
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocvclooentadiene
Hexachloroethane
lndeno(l ,2,3-cd)pyrene
Isophorone
2-Methylnaphthalene
2-Methvlohenol
4-Methvlnhenol
Naohthalene
2-Nitroaniline
3-Nitroaniline
4-Nitroaniline
Nitrobenzene
2-Nitroohenol
4-Nitroohenol
N-Nitrosodiphenylamine
N-Nitroso-di-n-propylamine
Pentachloroobenol.
Phenanthrene
Phenol
Pvrere
1,2,4-T richlorobenzene
2,4,5-Trichlorophenol
88-06-02 2 4 6-Trichloronhenol I Note:
I
I
I
E = Concentration exceeds calibration range (results estimated)
J = Estimated value (less than PQL but greater than zero)
B = Analyte found in blank (possible/probable blank contamination)
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
; I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 ' BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BOL
03/22/94 BOL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BQL
03/22/94 BOL
BQL = Below Quantitation Limit
PQL = Practical Quantitation Limit
NA= Not Applicable
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
I
g
g
I
I
I
I
A f)
KTRER ENVIRONMENTAL SERVICES, INC,
QUALITY CONTROL SEMIVOLATILE RESULTS
SW-846-3550/8270A
. Client Name: Roy F. Weston Lab Sample ID:
·. Project Name/#: Cherokee Oil/1236 Date Extracted:
Date Sampled: NA % Solids:
Date Received: NA Initial Wt/Vol:
. '
Matrix: Soil Final Vol:
Client Sample#: Method Blank Cleanun/#:
Surro2ate Compound 1§1 SpU..
II Amount
2-Fluorophenol 03/22/94 6667
Phenol-d6 03/22/94 6667
Nitrobenzene-d5 03/22/94 3333
2-Fluorobiphenvl · 03/22/94 3333
2,4,6-Tribromophenol 03/22/94 6667
· T=henvl-dl4 03/22/94 3333
II • = Surrogate(s) out of QC Limits (see case narrative)
II D = Diluted out · ·.
I
0
I
n
D
I
I
I
I
D
503034-EB
03/21/95
NA
30.00 g
1.00 ml
NA
QC
I
% I Note I LIMITS Recovery
25-121 67
24-113 66
23-120 71
30-115 71
19-122 82
18-137 88
I
I
D
D
D
I
H
D
D
H
D
I
I
m
I
I
Client Name: Roy F. Weston
J<IBEB ENVIRONMENTAL SERVICES; INC,
QUALITY CONTROL SEMIVOLATILE RESULTS
SW-846-3550/8270A
Lab Sample ID:
Project Name/#: Cherokee Oil/1236 Date Extracted:
Date Sampled: NA % Solids:
Date Received: NA Initial Wt/Vol:
Matrix: Soil Final.Vol:
Client Sample#: Method Blank Cleanuo/#:
503034-EB2
03/24/95
NA
2.00 g
2.00 ml
NA
CASNumbcr II Compound Name I DUutton I Annlysls II Result IC::JEJ Factor Date ue/k2
83-32-9 Acenaphthene
208-96-8 Acenaphthylene
120-12-7 Anthracene
56-55-3 Benzo(a)anthracene
205-99-2 Benzo(b )fluoranthene
207-08-9 Benzo(k)fluoranthene
65-85-0 .. Benzoic acid
191-24-2 Benzo(g,h,i)perylene
193-39-5 Benzo(a)ovrene
100-51~ Beozvl alcohol
111-91-1 bis(2-Chloroethoxv)methane
111-44-4 bis(2-Chloroethyl)ether
108~0-l. bis(2-Chloroisopropyl)ether
117-81-7 bis(2-Ethylhexyl)phthalate
101-55-3 4-Bromophen~l-ohenvlether
85~8-7 Butvlb.-n,v(ohthalate
106-47-8 4-Chloroaniline
59-50-7 4-~hloro-3-methylphenol
91-58-7 2-Chloronaphthalene
95-57-8 2-Chlorophenol
7005-72-3 · 4-Chlorophenyl-phenylether
218-01-9 Chrvsene
53-70-3 Dibenz(a,h)anthracene
132~4-9 Dibenzofuran
84-74-2 Di-n-butylphthalate
95-50-1 1,2-Dichlorobenzene
541-73-1 1,3-Dichlorobenzene
106-46-7 1,4-Dichlorobenzene
91-94-1 3,3'-Dichlorobenzidene
120-83-2 2,4-Dichlorophenol
84~6-2 Diethvlohthalate
105~7-9 2,4-Dimethylphenol
131-11-3 Dimethvlnhthalate
Note:
E = Concentration exceeds calibration range (results estimated)
J = Estimated value (less than PQL but greater than zero)
B = Analyte found in blank (possible/probable blank contamination)
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94' BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 B"L
BQL = Below Quantitation Limit
PQL = Practical Quantitation Limit
NA= Not Applicable
10000
10000
10000
10000
10000
10000
10000
10000
10000
10000
10000
10000
10000
10000
10000
10000
10000
10000
10000
10000
10000
10000
10000
10000
10000
10000
10000
10000
10000
10000
10000
10000
10000
I
I
I
I
H
D
I
D
D
I
I
I
I
I
I
I
I
I
I
Client Name: Roy F. Weston
(?, (:;)
KIBER ENVIRONMENTAL SERVICES; INC,
QUALITY CONTROL SEMIVOLATILE RESULTS
SW-846-3550/8270A
Lab Sample ID:
Project Name/#: Cherokee Oil/1236 Date Eitracted:
Date Sampled: NA % Solids:
Date Received: NA Initial Wt/Vol:
Matrix: Soil Final Vol:
Client Samole #: Method Blank . Cleanun/#:
503034-EB2
03/24/95
NA
2.00 g
2.00 ml
NA
CASNumber II Compound Name I DUuUon I Aru,lysls II Result ICiJEJ Factor Dal< ug/ke
534-52-1 4,6-Dinitro-2-methylphenol
51-28-5 2,4-Dinitrophenol
121-14-2 2,4-Dinitrotoluene ·
606-20-2 2,6-Dinitrotoluene
117-84-0 Di-n-octylphthalate
206-44-0 Fluoranthene
86-73-7 Fluorene
118-74-1 Hexachlorobenzene
87-68-3 Hexachlorobutadiene
77-47-4 Hexachlorocvclooentadiene
67-72-1 Hexachloroethane
193-39-5 Indeno(l ,2,3-cd)pyrene
78-59-1 Isophorone
91-57-6 2-Methylnaphthalene
95-48-7 2-Methvlohenol
106-44-5 4-Methylphenol
91-20-3 Naphthalene
88-74-4 2-Nitroaniline
99-09-2 3-Nitroaniline
100-01-6 4-Nitroaniline
98-95-3 Nitrobenzene
88-75-5 2-Nitrophenol
100-02-7 4-Nitrophenol
86-30-6 N-Nitrosodiphenylamine
621-64-7 N-Nitroso-di-n-propylamine
87-86-5 . Pentachloroohenol
85-01-8 Phenanthrene
108-95-2 Phenol
129-00-0 Pvrene
120-82-1 1,2,4-Trichlorobenzene
95-95-4 2;4,5-Trichlorophenol
88-06-02 2 4 6-Trichloronhenol
Note:
E = Concentration exceeds calibration range (results estimated)
J = Estimated value Qess than PQL but greater than zero)
B = Analyte found in blank (possible/probable blank contamination)
1
1
1
I
1
1
1
1
I
I
I
I
1
1
1
1
1
1
1
I
1
I
1
1
I
I
1
1
I
I
I
I
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 ' BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BQL
03/24/94 BOL
BQL = Below Quantitation Limit
PQL = Practical Quantitation Limit
NA= Not Applicable
10000
10000
10000
10000
10000
10000
10000
10000
10000
10000
10000
10000
10000
10000
10000
10000
10000
10000
10000
10000
10000
10000
10000
10000
10000
10000
10000
10000
10000
10000
10000
10000
n
n
n
D
I
~ ~ ( · 1 G fJ
KfiEB ENVIRONMENTAL SERVICE~(iNc,
QUALITY CONTROL SEMIVOLATILE RESULTS
SW-846-3550/8270A ··
Client Name: Roy F. Weston Lab Sample ID:
. Project Name/#: Cherokee Oil/1236 Date Extracted: --·
Date Sampled: NA % Solids:
Date Received: NA Initial Wt/Vol:
Matrix: Soil Final Vol:
Client Samole #: Method Blank Cleanun/#:
Surro2ate Compound 1§1 Spike
II Amowit
2-Fluorophenol 03/24/94 100000
Phenol-d6 03/24/94 100000
Nitrobenzene-d5 03/24/94 50000
2-Fluorobiphenyl 03/24/94 50000
2,4,6-Tribromophenol 03/24/94 100000
Ternbenvl-d14 03/24/94 50000
D • = Surrogate(s) out of QC Limits (see case narrative)
D = Diluted out
u
D
D
I
I
I
I
I
I
I
503034-EB2
03/24/95
NA
2.00 g .
2.00 ml
NA
QC
I
% I N?u Ii LIMITS Recovery
25-121 62 ' !
24-113 59
23-120 · 64 I
' 30-115 67 I
19-122 75 I
18-137 41 i
I
I
g
g
g
I
D
D
D
I
I
I
I
I
I
I
I
I
(:) A
Kiij~R ENVIRONMENTAL SEBYJCES, /~t;
Qualitv Control Results
Blank Spike(BS).
SW-846-8270A ·
Client Name: Roy F. Weston Lab Sample ID: 503034-BSI
Project Name/#: Cherokee Oil/1236 Matrix: Soil
Date Sampled: NA Date Extracted: 03/21/95
Date Received: NA Initial Wt/Vol: 30.00 g
Client Sample#: NA Final Vol: LOO ml
Cleanuo/#: NA
BLANK SPIKE{BS)
I :Spike I Co•:::Uon II C••::;uon IC::J Compound ConcentratJon
Added
Phenol
2-Chlorophcnol
1,4-DichJorobcnz.enc
N-Nitroso-di-n-propylaminc
1,2,4-Trichlorobcnzeoc
4-Chl.oro-3-mcthytphenol
Acenaphthcnc
4-Nitrophcnol
2,4-Dinitrotolumc
Pcntachlorophcnol .....,,
• = QC outside limits
D = Diluted out
6667
6667
3333
3333
3333
6667
3333
6667
3333
6667
3333
0 4045 61
0 4866 73
0 2707. 81
0 3073 · ' 92
0 2533 76
0 4862 73
0 2744 82
0 6611 99
0 3340 100
0 6144 92
0 2739 82
I
I
Kecovcty B Limits
¾
25-90
24-102
27-104
40-126
37-107
25-103
30-137
10-114
27-89 •
16-109
34-142 ,
I
I
I
g
I
n
I
I
D
D
H
u
D
u
I
I
I
I
I
I
I
(::J'J (0
KTBER ENVIRONMENTAL SERVICES. INC,
Quality Control Results
Blank Spike(BS) & Blank Spike Duplicate(BSD)
SW-846-8270A
Client Name: Roy F. Weston Lab Sample ID: 503034-BS,BSD
Project Name/#: Cherokee Oil/1236 Matrix: Soil
Date Sampled: NA Date Extracted: 03n4l95
Date Received: NA Initial Wt/Vol: 2.00 g
Client Sample#: NA Final Vol: 2.00 ml
Cleanun/#: NA
BLANK SPIKE(BS)
I
Spike
I Co•~=U•n II Co•::;uon I□ K=>"")'
Compound Concentntlon Limits
Added ¾
Phenol
2~orophenol
1,4-Dichlorobenztnc
N-Nitroso-di-n-propylaminc
1,2,4-Trichiorobenztnc
4-Chloro-3-mcthytphenol
Acenaphthenc
4-Nitrophenol
2,4-Dinitrotoluenc
Pcntachlorophenol ~-,
Compound
Phenol
2-ch1orophenol
1,4-DichJorobcnmtc
N-Nitr0$0-di-n-propyhminc
1,2.4-Trichlorobenztnc
4-Chloro-3-mcthylphenol
Acc:naphthenc
4-Nitrophenol
2,4-Dinitroto1ucnc
PentachJorophenol ........
• = QC outside limits
D = Diluted out
I·
100000 0 4947S
100000 0 59580
50000 0 29675
50000 0 40545
50000 0 3186S
100000 0 64005
50000 0 35700
100000 0 87830
50000 0 4932S
100000 0 100210
50000 0 33610
BLANK SPIKE DUPLICATE(BSD)
~pike
I Con=Uon II Concentratlon
Added
100000 42000
100000 49745
50000 25090
50000 36850
50000 27880
100000 58395
50000 34090
100000 91675
50000 51370
100000 10177S
50000 3S14S
Initial Wt/Vol:
Final Vol:
2.00 g
2.00 ml
BSD lc:J •t.
Recove!l'.
42 16.3
so 18.0
so 16.7
74 ' 9.S
56 13.3
. ss 9.2
68 4.6
92 4.3
103 4.1
102 1.5
70 4.5
49 25-90
60 24-102
59 27-104
SI 40-126
64 37-107
64 25-103
71 30-137
88 10-114
99 27-89
100 16-109
67 34-142
..,.._.
Limits
RPD •t• Recoverv
25 25-90
25 24-102
25 27-104
25 40-126
25 37-107
25 25-103
25 30-137
25 10-114
25 27-89
25 16-109
25 34-142
I
B
•
B
•
I
I I
g
u
D
I I
D
B
n
I
I
I
I
I
I
I
I
I
A I~ \:\:.-.... ' t_·~)
KIBER ENVIRONMENTAL SERVICES, INC.
Qualiti'. Control Results
Matrix Spike(MS) & Matrix Spike Duplicate(MSD)
SW-846-8270A
Client Name: Roy F. Weston Lab Sample ID: 503034-4MS,MSD
Projed Name/#: Cherokee Oil/1236 Matrix: Soil
Dale Sampled:03/13/94 Dale Extracted: 03/21/95
Dale Received:03/17/94 Initial Wt/Vol: 30.43 g
Client Sample#: CO-SB--04 Final Vol: 1.00 ml
Cleanun/#: NA
MATRIX SPIKE(MS)
II sp&c
II ":S II C••::tion I ov=
Compound Concentntlon ConcentnUon ¾
Added Recoverv
Phenol 83Sl 0 4S46 S4
2-Chlorophcnol 8351 0 5382~ 64
1,4-Dichlorobcnz.cnc 4176 0 2963 71
N-Ni~c 4176 0 3179 76
1,2,4-Trichlorobcnzcnc 4176 0 2816 67
4-0iloro-3-mcthylpbenol 8351 0 S78S 69
Accnaphthcnc 4176 0 3236 78
4-Nitrophenol 83S1 0 7920 9S
2, 4-Dinitrotolucnc 4176 0 4001 96
Pentachlorophcnol 8351 0 7349 88
""-c 4176 0 3240 78
MATRIX SPIKE DUPLICATE(MSD)
Compound
Phenol
2-Chlorophcnol
1,4-Dichlorobcnz.cnc
N-Nitroso-di-n-propytaminc
1,2,4-Trichlorobcnzcnc
4-Chloro-3-mcthylphcnol
Accnaphthenc
4-Nitropbenol
2,4-Dinitrotolucnc
Pentachlorophenol .......
• = QC outside _limits
D = Diluted out
II Spike II ConcentraUon -
Added
8443
8443
4221
4221
4221
8443
4221
8443
4221
8443
4221
Con=ti•n II
4550
5454
3038
31S0
28S8
S921
32S8
8185
402S
7446
3207
Initial Wt/Vol:
Final Vol:
30.10 g
1.00 ml
MSD IW ¾ .
Rtto~ I
S4 1.0
6S 0.2
72 1.4
7S 2.0
68 0.4
70 1.2
77 0.4
91 2.2
95 o.s
88 0.2
76 2.1
RPO
2S
2s
2S
2S
2S
2S
2S
2S
2S
2S
2S
I
Kct-OV<O)" E] Umlts
¾
25-90
24-102
27-104
40-126
37-107
25-103
30-137
10-114
27-89 •
16-109
34-142
"-' E] Limits
•t• Recoverv
25-90
24-102
27-104
40-126
37-107
25-103
30-137
10-114
27-89 •
16-109
34-142
I
D
D
D
I
D
D
H
B
H
u
I
I
I
E
I
I
I
I
I
G? . CJ> KTBER ENVIRONMENTAL SERVICES, INC,
Polychlorinated biphenyls (PCBs) RESULTS
SW-846-3550/8080
Client Name: Roy F. Weston
Project Name/#: Cherokee Oil/1236
Date Sampled:03/13/95
Date Received:03/17 /95
Matrix: Soil
Client Samnle #: CO-SS-0 I
CASNwnber II Compound Name
12674-11-2 Aroclor 1016
11104-28-2 Aroclor 1221
11141-16-5 Aroclor 1232
53469-21-9 Aroclor 1242
12672-29-6 Aroclor 1248
I 1097-69-1 Aroclor 1254
I 1096-82-5 Aroclor 1260
Note:
I Dilution
Factor
20
20
20
20
20
20
20
E = Concentration exceeds calibration range (results estimated)
J = Estimated value Qess than PQL but greater than MDL)
I
B = Analyte found in blank (possible/probable blank contamination)
Lab Sample ID:
Date Extracted:
% Solids:
Initial Wt:
Final Vol:
503034-1
' -03/20/95
81.2
30.40 g
10.00 ml
Cleanuo/#: Sulfuric Acid/ 3665-Pronosed
Analysis II Date
·03/22/95
03/22/95
03/22/95
03/22/95
03/22/95 . ,
03/22/95
03/22/95
Result ICiJEJ ue/kf
BQL 810
BQL 1600
BnL 810
BQL 810
BQL 810
BQL 810
BOL 810
BQL = Below Quantitation Limit
PQL = Practical Quantitation Limit
NA= Not Applicable
n
I
D
0
D
0
B
I
I
I
I
I
I
I
I
I
I
I
I
I
I
(;: N -.. ~-
KTRER ENVIRONMENTAL SERVICES, INC,
Polychlorinated biphenyls (PCBs) SURROGATE RECOVERIES .
. ---. SW-846-3550/8080 .
. • 0, Client Name: Roy F. Weston
Proi~ct Name/#: Cherokee Oil/I 236
Date Sampled:03/13/95
Dai; Received:03/17 /95 ... '
· • Matrix: Soil
Lab Sample ID: 503034-1
Date Extracted: ----· 03/20/95
% Solids:
Initial Wt:
Final Vol:
81.2
30.40 g
10.00 ml
I .
Client Sample#: CO-SS-0 I Cleanup/#: Sulfuric Acid/ 3665-Prooosed
... · Surrozate Compound
Tetrachloro-m-~lene
• = Swrogate(s) out of QC Luruts (see case narrative)
D = Diluted out
. ::-.:: :.i,,, ........... -
•• , : t;; •• ,_: -~
· i .. 1;t :t: '~ ":-
--,.;·f.::\r .. ~:-:~\ __
1§1
1103122195 11
Splk,
II
QC
I
%
Amount LIMITS RecOve'ry
162 II 60-150 II 0
!
[:]
IITJ
D
D
H
D
I
B
I
D
I
I
I
I
I
I
I
I
I
c~ ·(D
TQRER ENVIRONMENTAL SERVICES, INC,
Polychlorinated biphenyls (PCBs) RESULTS
SW-846-3550/8080
Client Name: Roy F. Weston
Project Name/#: Cherokee Oil/1236
Date Sampled:03/13/95
Date Received:03/17 /95
Matrix: Soil
Client Sample#: CO-SS-02
CASNwnber II Compound Name
12674-11-2 Aroclor 1016
II !04-28-2 Aroclor I 221
11141-16-5 Aroclor 1232
53469-21-9 Aroclor 1242
12672-29-6 Aroclor 1248
I 1097-69-1 Aroclor 1254
11096-82-5 Aroclor 1260
Note:
I Dilution
Factor
50
50
50
50
50
50
50
E = Concentration exceeds calibration range (results estimated)
J = Estimated value (less than PQL but greater than MDL)
I
B = Analyte found in blank (possible/probable blank contamination)
L~b Sample ID:
Date Extracted:
% Solids:
503034-2
. 03/20/95
85.4
Initial Wt: 30.19 g
Final Vol: I0.00 ml
Cleanup/#: Sulfuric Acid/ 3665-Proposed
Anlllysls II Dat.
03/22/95
03/22/95
03/22/95
03/22/95
03/22/95
03/22/95
03/22/95
Result IC::JEJ n•lk.e
BQL 1900
BQL 3900
BQL 1900
BQL 1900
BQL 1900
BQL 1900
BQL 1900
BQL = Below Quantitation Limit
PQL = Practical Quantitation Limit
NA= Not Applicable
D
D
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
(C:.J r:J)
KIBER ENVIRONMENTAL SERVICE}{ INC,
Polychlorinated biphenyls (PCBs) SURROGATE RECOVERIES
SW-846-3550/8080, -
Client Name: Roy F. Weston
Project Namel#: Cherokee Oil/1236
Date Sampled:03/13/95
Date Received:03/17 /95
Matrix: Soil
Client Samole #: CO-SS-02
Lab Sample ID:
Date E1tracted:
% Solids:
Initial Wt:
Final Vol:
503034-2
··-. 03/20/95
85.4
30.19 g
l0.00 ml
Cleanup/#: Sulfuric Acid/ 3665-Prooosed
II ~~b II !:t II LI~~S I R,,::,ry I Note I
l~=====T=e=1r=ac=;hlc;,o=ro=-=m=-xy=1c=en=e=======;1cclocc'3/='22cc/cc'95c=,1rl ==3'"gccg===,11r==6oc=_c;,15'"oc====,II' ==;oc====,11 Ju
Surrogate Compound
• = Surrogate(s) out of QC Limits (see case narrative)
D = Diluted out
, .
I
I
H
I
I
I
I
I
I
I
I
I
I
I
I
I
I
tJ;) P, , ~-.·.. l.:; ··.J
KTRER ENVIRONMENTAL SERVICES~ 'rnc,
Polychlorinated biphenyls (PCBs) RESULTS
SW-846-3550/8080
Client Name: Roy F. Weston
Project Name/#: Cherokee Oil/I 236
Date Sampled:03/13/95
Date Received:03/17 /95
Matrix: Soil
Client Sample#: CO-SB-03
CASNwnber II Conipound Name
12674-11-2 Aroclor 1016
11104-28-2 Aroclor 1221
11141-16-5 Aroclor 1232
53469-21-9 Aroclor 1242
12672-29-6 Aroclor 1248
11097-69-1 Aroclor 1254
11096-82-5 Aroclor 1260
Note:
I DUution
Factor
10.
JO
10
10
JO
10
JO
E = Conceotration exceeds calibration range (results estimated)
J = Estimated value (less than PQL but greater than MDL)
I
B = Analyte found in blank (possible/probable blank contamination)
Lab Sample ID:
Date Extracted:
% Solids:
Initial Wt:
Final Vol:
503034-3
"03/20/95
77.3
30.56 g
10.00 ml
Cleanup/#: Sulfuric Acid/ 3665-Prooosed
Aruuy,b II Dau
03/22/95
03/22/95
03/22/95
03/22/95
03/22/95 ·
03/22/95
03/22/95
Result IWEJ uelk,
BQL 420
BQL 850
BQL 420
BQL 420
BQL 420
BQL 420
BOL 420
BQL = Below Quantitation Limit
PQL = Practical Quantitation Limit
NA= Not Applicable
e
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
A @ KIBEB ENVIRONMENTAL sERVIcE'i{'INc.
Polychlorinated biphenyls (PCBs) SURROGATE RECOVERIES
SW-846-3550/8080 -· , .. , -; .. • . .
Client Name: Roy F. Weston
Project Name/#: Cherokee Oil/I 236
Date Sampled:03/13/95
L~b Sample_ID:_ ,: •. ;.5030,34-3 < .. , -.: ..
Date Received:03/17/95
Matrix: Soil
Client Sample#: CO-SB-03
Surroe:aU Compound
Tetrachloro-m-29'lene
• = Swrngate(s) out of QC Luruts (see case narrative)
D = Diluted out
l~I
11m,22195 11
Date Extracted: ·•---03/20/95
% Solids:
Initial Wt:
Final Vol:
! · · 77.3
30.56 g
10.00 ml
Cleanup/#: Sulfuric Acid/ 3665-Prooosed
Spike II QC I o/ •. ,
Amount LIMITS Recovei-y
85 II 60-150 II 0
•.'
'· -
. '
I ' ;
\
I Nou I
ICQJ
I
u
D
H
u
D
I
I
I
I
I
I
I
I
I
I
I
I
~R ENVIRONMENTAL SERVICEYrnc.
Polychlorinated biphenyls (PCBs) RESULTS
SW-846-3550/8080-
Client Name: Roy F. Weston
Project Name/#: Cherokee Oil/I 236
Date Sampled:03/13/95
Date Rcceived:03/17 /95
Matrix: Soil
Client Samole #: CO-SB-04
CASNumber II Compound Naine
12674-11-2 Aroclor 1016
11104-28-2 Aroclor 1221
11141-16-5 Aroclor 1232 .
53469-21-9 Aroclor 1242
12672-29-6 Aroclor 1248
11097-69-1 Aroclor 1254
I 1096-82-5 Aroclor 1260
Note:
I Dilution
Fador
I
I
I
I
I
I
I
E = Concentration exceeds calibration range (results estimated)
J = Estimated value Qess than PQL but greater than MDL)
I
B = Analyte found in blank {possible/probable blank contamination)
Lab Sample ID: 503034-4
Date Extracted: ····-03/20/95
% Solids: 78. 7
Initial Wt:
Final Vol:
30.07 g
10.00 ml
Cleanup/#: Sulfuric Acid/ 3665-Pronosed
Analysis
Date
03/21/95
03/21/95
03/21/95
03/2 J/95
03/21/95 .· ,
03/21/95
03/21/95
II Result IC:iJEJ ue/ke
BQL 42
BQL 85
BQL 42
BQL 42
BQL 42
BQL 42
BQL 42
_.. BQL = Below Quantitation Limit
PQL = Practical Quantitation Limit
NA= Not Applicable
I
I
D
D
n
I
I
I
I
I
I
I
I
I
I
I
I
I
K(RER ENVIRONMENTAL SERVICES, INC.
---i -~r. · ::,. ·;;:. ... ,.~.:-~olychlorinated biphenyls (PCBs) SURROGATE RECOVERIES
SW-846-3550/8080 . .
',_qlent Name: Roy F. Weston
P,.;,je~t.Name/#: Cherokee Oil/1236
Date Sampled:03/13/95
Dai~· Received:03/17 /95
.. •. Matrix: Soil
· Lab Sampl~ ID:
Date Extracted:
¾ Solids:
503034-4
.. -• 03/20/95
78.7
Initial Wt: 30.07 g
Final Vol: 10.00 mi
Client Samnle #: CO-SB-04 Cleanup/#: Sulfuric Acid/ 3665-Pronosed
II Surro~•te Compound II ~~~b II !!1 II LI~~TS I Rcc~very I Note I
1"1 ========Te=tr=a=chl=o=r=o-=m=-xy=ie=n=e ======a11(0=3=,2=1=,9=5~1~1 ==s=.s===a11(==6=0=-1=s=o="'1:"1 =,=1 =3 =all=:]
• = Surrogate(s) out of QC Limits (see case narrative)
D = Diluted out
,,..-,
'· ..
.. ,,..
·! .-~··:.·,
' ·,
I
D
0
B
I
I
I
I
I
I
I
I
I
I
I
I
I
I
() (4
KTBER ENVIRONMENTAL SERVICE·s;:INC,
.. _--:-
-~ I.••·•
...... :~·· !,;• •.-· .
QUALITY CONTROL Polychlorinated biphenyls (PCBs) RESULTS
SW-846-3550/8080
. ,_:;,' <;_~ent Name: Roy F. Weston
Project Name/#: Cherokee Oil/I 236
: . Date Sampled: NA --:·· •·•-·
: Date Received: NA
Matrix: Soil
Client Sample#: NA
· CASNumbt:r II
12674-11-2
JI 104-28-2
11141-16-5
53469-21-9
· · 12672-29-6
11097-69-1
:.'. JI 096-82-5
Note:. --·
Compound Name
Aroclor 1016
Aroclor 1221
Aroclor 1232
Aroclor 1242
Aroclor 1248
Aroclor 1254
Aroclor 1260
I DUutlori
Fador
1
1
I
1
I
1
1
.: __ E = Concentration exceeds calibration range (results estimated)
J = Estimated value (less than PQL but greater than MDL)
I
B.= Analyte found in blank (possible/probable blank contamination)
Lab Sample ID: Q5032003
Date Extracted: ·· 03/20/95
% Solids: NA
Initial Wt: 30.00 g
Final Vol: 10.00 ml
Cleanun/#: Sulfuric Acid/ 3665-Prooosed
Analysis II Date
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
03/21/95
Result IC::J8 uwk2
BQL 33
BQL 67
BQL 33
BQL 33
BQL 33
BQL 33
BOL 33
BQL = Below Quantitation Limit
PQL = Practical Quantitation Limit
NA= Not Applicable
I
m
D
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
KIBER ENY[RONMENTAL SERVICES, INC,
Polychlorinated biphenyls (PCBs) SURROGATE RECOVERIES
SW-846-3550/8080 ·
Client Name: Roy F. Weston
Project Name/#: Cherokee Oil/1236
Date Sampled: NA
Date Received: NA
Matrix: Soil
Lab Sample ID:
Date Extracted:
¾ Solids:
Initial Wt: ·
Final Vol:
Q5~32003
--··03/20/95
NA
30.00 g
10.00 ml
Client Sample#: NA Cleanun/#: Sulfuric Acid/ 3665-Prooosed
Surrogate Compound 1§1 Spike
II
QC
I
'I,
Amount LIMITS Recovery EJ
Tetrachloro-m-xylene 103/21/951 6.7
11
60-150 1rna Decachlorobi~hentl 03/21/95 6.7 I 60-150 .. • = Surrogate(s) out of QC Luruts (see case narrative).
D = Diluted out
. •.
I
KIBER ENVIRONMENTAL SERVICES, INC,
H Quality Control Results
I ID~~~~
B li============c=.c========S=W==-='8=46=-=35=5=0/==8=08=0=·=======:c=="'=='=========1I
Client Name: Roy F. Weston Lab Sample ID: Q5032004EBS
D
I
I
I
I
I
I
I
I
I
I
I
I
Project Name/#: Cherokee Oil/1236 Matrb: •. Soil
Date Sampled: NA Date Extracted: 03/20/95
Date Received: NA Initial Wt: 30.00 g
Client Sample#NA Final Vol: 10.00 ml
Cleanuo/#: Sulfuric Acid/ 3665-Pronosed
I Compound
I Aroclor 1254
• = QC outside luruts
D = Diluted out
I
II
Sp,-
ConcentnUon
Added
66.667
BLANK SPIKE(BS)
I C••:::••• II
I 0 11
C••=U•n 11 ::.
Kecovery
: Reeovo,v
Umlll
¾
58.008 II 87 II 39-154
.
B
II I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
0 p;,
KIBER ENVIRONMENTAL SERVTCEs;·1Nc.
Batch Quality Control Results
,• .. . . Matrix Spike(MS) & Matrix Spike Duplicate(MSD)
SW-846-3550/8080
Client Name: Roy F. Weston Lab Sample ID: 503034-4
Project Name/#: Cherokee Oil/1236 Date Extracted: 03/20/95
Date Sampled:03/13/95 % Solids: 78.7
Date Received:03/17/95 Initial Wt: 30.13 g
Matrix: Soil Final Vol: 10.00 ml
Client Sample#: CO-SB--04 pH of Leachate: NA
Cleanun/#: Sulfuric Acid/ 3665-Pro~~sed
Compound
Aroclor 1254
Compound
Arodor 1254
• = QC outside limits
D = Diluted out
II II
I
II
Spike
Concentration
Added
84.344
. .sp,-
ConcentnUon
Added
82.913
MA TRIX SPIKE (MS)
I ~ample I Co•::;tlon IC!J --ifecovery
ConcentnUon . Limits
•·"'· %
I 0 I 70.766 II
Initial Wt/Vol:
Final Vol:
MATRIX SPIKE DUPLICATE (MSD)
I Con:;:tlon II ,MSO I~ %
Reco~
II 68.871 II 83 II 1.0 II
84 II 39-154
30.65 g
10.00 ml
"" Limits
RPO --ii •;• Recoverv
25 II 39-154
I
B
II I
B
II I
I
u
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
r.3-:1 '·'. :_·~·i'
KIBER ENVIRONMENTAL SERVICES, INC.
RCRA METALS RESULTS
SW-846-3051/6010A :
· Client Name: Roy F. Weston
Project Name/#: Cherokee Oil/1236
Date Samj>led:03/13/95
Date Received:03/17 /95
Matrix: Soil
Client Sample#: CO-SS-01
CASNumber II Analyte Name
7429-38-2 Arsenic (As)
7440-39-3 Bariwn (Ba)
7440-43-9 Cadmiwn (Cd)
7440-47-3 Chromiwn (Cr)
7439-92-1 Lead (Pb)
7439-97-6 Mercury (Hg)
7782-49-2 Seleniwn (Se)
7440-22-4 Silver (Ao'
Note:
I Dilution
Factor
5
I
1
I
I
I
I
I
E = Concentration exceeds calibration range (results estimated)
J = Estimated value (less than PQL but greater than MDL)
I
Lab Sample ID:
Date Digested:
% Solids:
I Initial Vol:
Final Vol:
Analysis II Date
03/20/95
03/20/95
03/20/95
03/20/95
03/20/95
03/20/95
. 03/20/95
03/20/95
B = Analyte found in blank (possible/probable blank contamination)
,
'
503034-1
03/17/95
81.2
0.53 ml
50.00 ml
Result IWEJ mg/ke
BQL 65
220 23 B
17 2,8
130 1.2
290 14
BQL 0.52
BQL 20
BOL 1.2
BQL = Below Quantitation Limit
PQL = Practical Quantitation Limit
NA= Not Applicable
I
D
I I
m
I
I
I
I
'
I
I
I·
I
I
11
I
r?~ (S)
KJRER ENVIRONMENTAL SERVICES, 1NC.
RCRA METALS RESULTS
SW-846-3051/6010A
C~ent Name: Roy F. Weston
Project Name/#: Cherokee Oil/1236
Date Sampled:03/13/95
Date Received:03/17 /95
Matrix: Soil
Client Sample#: CO-SS-02
· CASNumber II Analyte Name
7429-38-2 Arsenic (As)
7440-39-3 Barium (Ba)
7440-43-9 Cadmium (Cd)
7440-47-3 Chromium (Cr)
7439-92-1 Lead (Pb)
7439-97-6 Mercury (Hg)
7782-49-2 Selenium (Se)
7440-22-4 Silver /A0 •
Note:
I Dilution
Factor
5
I
I
I
I
I
I
I
·E = Concentratio~ exceeds calibration range (results estimated)
J = Estimated value (less than PQL but greater than MDL)
I
Lab Sample ID:
Date Digested:
% Solids:
Initial Vol:
Final Vol:
Analysis II Date
03/20/95
03/20/95
03/20/95
03/20/95
03/20/95
03/20/95
03/20/95
03/20/95
B = Analyte fouod in blank (possible/probable blank contamination)
,
503034-2
03/17/95
85.4
0.52 ml
50.00 ml
Result -IWEJ m•lki!
BQL 63
200 23 B
1.4 2.7 J
42 1.1
79 14
BQL 0.52
5.9 19 J
BnL 1.1
BQL = Below Quantitation Limit
PQL = Practical Quantitation Limit
NA= Not Applicable
D
D
I
B
I
I
I
I
I
I
I
1,
I
I
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KTRER ENVIRONMENTAL SERVICES, INC.
RCRA METALS RESULTS
SW-846-3051/6010A
Client Name: Roy F. Weston
Project Name/#: Cherokee Oil/1236
Date Sampled:03/13/95
Date Received:03/17 /95
Matrix: Soil
Client Samnle #: CO-SB-03
CASNumber·
II
Analyte N11me
7429-38-2 Arsenic (As)
7440-39-3 Barium (Ba)
7440-43-9 Cadmium (Cd)
7440-47-3 Chromium (Cr)
7439-92-1 Lead (Pb)
7439-97-6 Mercwy(Hg)
7782-49-2 Selenium (Se)
7440-22-4 Silver (Au\
Note:
I Dilution
Factor
5
I
I
I
I
I
I
I
E = Concentration exceeds calibration range (results estimated)
J = Estimated value (less than PQL but greater than MDL)
I
Lab Sample ID:
Date Digested:
% Solids:
Initial Vol:
Final Vol:
Analysis II Date
03/20/95
03/20/95
03/20/95
03/20/95
03/20/95
03/20/95
03/20/95
03/20/95
B = Analyte found in blank (possible/probable blank contamination)
I
503034-3 .. ·
03/i?/95
77.3
0.49 ml
50.00 ml
Result l~EJ m~
BQL 74
300 26 B
2.2 3.2 J
39 1.3
28 16
BQL 0.52 .
16 22 J
BOL 1.3 .
BQL = Below Quantitation Limit
PQL = Practical Quantitation Limit
NA= Not Applicable
0
D
B
I
I
I
I
I
I
I
I
I
I
I
..
KIBER ENVIRONMENTAL SERVICES, INC.
RCRA METALS RESULTS
SW-846-3051/60iOA ·:
Client Name: Roy F. Weston
Project Name/#: Cherokee Oil/I 236
Date Sampled:03/13/95
Date Received:03/17 /95
Matrix: Soil
Client Sample#: CO-SB-04
CASNumber· II Anal)te Name
7429-38-2 Arsenic (As)
7440-39-3 Bariwn (Ba)
7440-43-9 Cadmiwn (Cd)
7440-47-3 Chromiwn (Cr)
7439-92-1 Lead (Pb)
7439-97-6 Mercury (Hg)
7782-49-2 Seleniwn (Se)
7440-22-4 Silver (Aol
Note:
I Dilution ii
Factor
5
I
I
I
I
I
I
I
E = Concentration exceeds calibration range (results estimated)
J = Estimated value (less than PQL but greater than MDL)
Lab Sample ID:
Date Digested:
% Solids:
Initial Vol:
Final Vol:
Analysis II Date
03/20/95
03/20/95
03/20/95
03/20/95
03/20/95
03/20/95
03/20/95
03/20/95
B = Analyte found in blank (possible/probable blank contamination)
'
503034-4
03/17/95
78.7
0.53 ml
50.00 ml
Result IWEJ m•lki!
BQL 67
65 24 B
BQL 2.9
47 1.2
24 15
BQL 0.52
BQL 20
BOL 1.2
BQL = Below Quantitation Limit
PQL = Practical Quantitation Limit
NA= Not Applicable
I -
D
n
I
m
I
I
I
I
'
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••
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@ (~
KTBER ENVIRONMENTAL SERVICES, INC.
QUALITY CONTROL RCRA METALS RESULTS
SW-846-3051/6010A ·
. , :· Client Name: Roy F. Weston -··. Hf~·•· -
P_roject_Name/#: Cherokee Oil/1236
: Dai·.; Sampled: NA .·:·~:-.r..~~
Date Received: NA
Matrix: Soil
Client Samnle #: NA
-··· II CASNwnber
7429-38-2
7440-39-3
7440-43-9
7440-47-3
7439-92-1
7439-97-6
. 7782-49-2
7440-22-4
Note:.,.fyf,.
Analyte Name
Arsenic (As)
Barium (Ba)
Cadmium (Cd)
Chromium (Cr)
Lead (Pb)
Mercury (Hg)
Selenium (Se)
Silver /An\
I DilutJon
Factor
I
I
I
I
I
I
I
I
·. E = Concentratio_n exceeds calibration range (results estimated)
J = Estimated value (less than PQL but greater than MDL)
I
Lab Sample ID:
Date Digested:
% Solids:
Initial Vol:
Final Vol:
II Analysis
Date
03/20/95
03/20/95
03/20/95
03/20/95
03/20/95
03/20/95
03/20/95
03/20/95
' B = Analyte found in blank (possible/probable blank contan\ination) . '(.
PBS0317A
03il 7/95
NA
45.00 ml
50.00 ml
IWB Result
ml!ikf
BQL 0.12
0.003 0.22 J
BQL 0.03
BQL 0.01
BQL 0.14
BQL 0.52
BQL 0.19
BQL . 0.01
BQL = Below Quantitation Lintit
PQL = Practical Quantitation Limit
NA= Not Applicable
.,
I '
I
I
1,
I
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(~ ~ .·, .. ::·.) 1..,:··:_'··.i
'krnER ENVIRONMENTAL SERVICES\Nc.
Quality Control Results
Laboratory Control Sample (LCS)
SW-846-3051/6010A .
Client Name: Roy F. Weston Lab Sample ID: LCSS0317A
Project Name/#: Cherokee Oil/1236
Date Sampled: NA
Date Received: NA
Client Sami>le # NA
Matrix:
Date Digested:
Initial Wt:
Final Vol:
LABO RA TORY CONTROL SAMPLE (LCS)
I
,u=,•'
I Co•:;:tion AnaJ)1C Concentnllon
Added (mallla)
Arsenic (As) 128 0
Barium (Ba) 276 0.003
Cadmium (Cd) 102 0
Chromium (Cr) 154 0
Lead (Pb) 147 0
Mercury (Hg) 0.5 0
Selenium (Se) IOI 0
Silver (Ao) 92.5 0
Note:
• = QC outside limits
B = Analyte found in blank (possible/probable blank contamination)
Standard ID: Environmental Resource Associates, lnorganics In Soil, lot# 221
II Con::;Uon
66
280
70 , ,
48
110
0.47
45
77
·,I
Soil
03/17/95
0.50 g
50.00 ml
I B Acceptable
Limits
32-97
213-415 B
41-114
34-80
69-179 ..
0.37-0.63 .. 24-70
34-125
I
IJ l;cl ================~Q~u~a~l;;ity~C~o;;n;;t~ro~l~R;,;e~s~u;;It~s~===============~I ■ I Replicate Sample
I " SW-846-3051/6010A
"-: ·:. Client Name: Roy F. Weston I P~ojeci Name/#: Cherokee Oil/1236
Dale Sampled: NA
I
I
I
I
I
I
I
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I
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' I
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Note:
Date Received: NA
Matrix: Soil
Client Samole #: NA
I
Sample Replicate
Target Analyte Concentration Concentration
m•"'• m•"'•
Arsenic (As) 10 167
Bariwn(Ba) 205 210
Cadmiwn (Cd) 3.8 2.4
Chromiwn (Cr) 79 51
Lead (Pb) 363 3278
Mercury (Hg) 0 0
Seleniwn (Se) 0 0
Silver (Ao\ 0.90 13
• = QC outside limits
B = Analyte found in blank (possible/probable blank contamination)
J = Estimated value (less than PQL but greater than MDL)
NA= Not Applicable
Lab Sample ID: 503030-lR
03/17/95
89.8
0.49 g
50.00 ml
.
Date Digested:
% Solids:
Initial Wt:
Final Vol:
Relative Percent
Difference
/RPO\
NA
2.8
NA
, 44
160
NA
'NA
NA
I\.CCCplable B RPDLimits
%
25
25 B
25 J
25 •
25 •
25
25
25
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KIBER ENVIRONMENTAL SERVICES. INC,
Quality Control Results
Matrix Spike (MS)
SW-846-3051/6010A
Client Name: Roy F. Weston Lab Sample ID: 503030-IMS
Project Name/#: Cherokee Oil/1236 Matrix:
Date Sampled: NA Date Extracted:
Date Received: NA Initial WtNol:
Client Samnle # NA Final Vol:
MA TRIX SPIKE (MS)
Note:
I
•v~• Sample
Compound Concentration Concenln.tlon
Added fm-n·-' m-"·-
Arsenic (As) 428 10.24
Barium (Ba) 428.3 204.65
Cadmium (Cd) 10.71 3.81
Chromium (Cr) 42.83 79.25
Lead (Pb) 107.1 341.32
Mercw-y (lfa) 0.50 0
Selenium (Se) 428.3 0
. Silver!A0 ' 10.71 0.90
• = QC_ outside limits
B = Analyte found in blank (possible/probable blank contamination)
D = Diluted out
Standard ID: Spike-I lot# 6-88AS .
I C••:±tion
421.66
614.72
13.04
100.80
~
487.51
0.49
422.41
10.68
Soil
03/17/95
0.52 g
50.00 ml
I
MO
%
Recoverv
96
96
86
50
137
97
99
91
I
I
Recovery B Limits
%
75-125
75-125 B
75-125
. 75-125 •
75-125 •
75-125
75-125
75-125
C•:-:~~~~~fr;.,.,.,,~ ... ~-•-•;-~·--.. ...-• • ,-·• • -i~s: __ :m~-rAL-·Ec--t>.GE----:!:-;--REGION 4 TAT llh, :-r4l tKPRoJ. Nq. ~ I PR9JECT NAME:. _ .-• ·----~-__ . .'\",t'c;", .~ !&·, ·.. (_ V)<? ro k"=..;, o.; I -, .. 'Yi'.~= .-.z.i; __ .". • . • • . •
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pate/Time ~oceived by: (_~_ignarure!_
-RO,...TAL-ICEliiii'SIO--'
COLLEG~TIOiTim"AD _ -
ATHENS; GEORGIA 30613
_REMARKS/TAG NUMBERS . .
. " 12¾ ; S23')3'i
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References 1 through 42 appear in Volume II
UNITE ST TE
DEPA TMENT OF TH
GEOLOGIC L SU
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ACGURAG IMH' RD T IS A
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