NCD981927502_19931101_Geigy Chemical Corporation_FRBCERLA SPD_Health and Safety Plan-OCR

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HEAL TI-I AND SAFETY PLAN
. GEIGY CHEMICAL CORPORATION SITE
ABERDEEN, NORTI-1 CAROLINA
NOVEMBER 1993
PREPARED BY:
RUST ENVIRONMENT & INFRASTRUCTURE
RUST E&I PROJECT NO. 86619.220
HltGtJVt.U
DEC O o 1993
SUPERF/INn SECIJON
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HEALTH AND SAFETY PLAN REVIEW SHEET
Project Code: 86619.220
Please sign and date.
PREPARED BY:
CIH/RHSS REVIEW BY:
QUALITY CONTROL REVIEW BY:
SITE HSO REVIEW BY:
PRE-SITE BRIEFING RECEIVED BY*:
RUST E&I Contractor(s)
* Signature documents that Site workers have received a pre-Site briefing.
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TABLE OF CONTENTS
Section Page
1.0 COORDINATION AND RESPONSIBILITY ......................... 1-1
2.0 SITE DESCRIPTION . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-1
3.0 PROJECT DESCRIPTION . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3-1
4.0 HAZARD ASSESSMENT . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4-1
5.0 QUALITATIVE RISK ANALYSIS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5-1
6.0 ENVIRONMENTAL MONITORING .............................. 6-1
7.0 PERSONAL PROTECTIVE EQUIPMENT (PPE) ..................... 7-1
8.0 COLD/HEAT EXPOSURE ..................................... 8-1
9.0 ACCIDENT PREVENTION . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9-1
10.0 STANDARD OPERATING SAFETY PROCEDURES AND CONTROLS .... 10-1
11.0 DECONTAMINATION CONTROL MEASURES ..................... 11-1
12.0 EMERGENCY PROCEDURES .................................. 12-1
13.0 TRAINING OF PERSONNEL ................................... 13-1
14.0 MEDICAL SURVEILLANCE .................................... 14-1
15.0 RECORDKEEPING .......................................... 15-1
APPENDIX A DAILY SIGN-IN/OUT LOG
APPENDIX B
APPENDIX C
APPENDIX D
APPENDIX E
WORK ZONE ENTRY AND EXIT LOG
RESPIRATORY USE LOG
ATMOSPHERIC MONITORING LOG
HASP FIELD MODIFICATION FORM
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Table No.
Table 4.1
Table 11.1
Figure No.
Figure 1-1
Figure 1-2
Figure 12-1
LIST OF TABLES
Description
Inhalation Exposure Limits
Minimum Decontamination Layout For Level C
Protection and Equipment
LIST OF FIGURES
Description
Location Map
Site Plan
Hospital Location map
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1.0 COORDINATION AND RESPONSIBILl'IY
RUST E&I is responsible for all Site health and safety concerns for our personnel
associated with hazardous and toxic materials as defined in 29 CFR 1910.120 (Hazardous
Waste Operation and Emergency Response). Contractors will be responsible for developing
a plan establishing procedures for the safe means and methods of all drilling and any other
construction operations. In addition, all contractor personnel must comply with 29 CFR
1926 (Construction Standards).
The Project Manager must not allow work to begin at the Site until this Site-specific Health
and Safety Plan has been provided to all field personnel. Before visiting the Site, all
personnel must attend a Site-specific briefing session, to be conducted by the RUST E&I
Regional Health and Safety Specialist (RHSS) or his/her designee, on the potential Site
hazards and specific requirements of this Health and Safety Plan (HASP), including training
in the proper function and operation of all monitoring and personal protective equipment.
All Site personnel must provide a written statement documenting full compliance with 29
CFR 1910.120. The overall responsibility for the health and safety of RUST E&I project
personnel lies with the RUST E&I Project Manager: The Site Health and Safety Officer
(HSO) and the senior RUST E&I representative continually on Site during any Site activity
will be responsible for ensuring that the Site-specific Health and Safety Plan is complied
with during Site operations. The Site HSO shall be certified in First Aid/CPR and be
continuously present during Site operations. If there is any question whether an unplanned
occurrence on Site may compromise health and safety, the HSO has the authority to
interrupt operations and to remove all personnel from the area. If practical, the RHSS and
Project Manager should be consulted before any operation is interrupted. If work is stopped
due to any health and safety concern, immediate attention should be given by health and
safety personnel, working in cooperation with the Project Manager, to identify and correct
the cause of concern as quickly as possible. Any such incident should be fully documented
by the Site HSO in a report to the RHSS and Project Manager. In the event of a work
stoppage, the client must be notified as soon as possible, and kept appraised of progress in
resolving the incident until normal operations are resumed. '
Geigy HASP November 5, 1993
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I NOTE: EMERGENCY CONTACT NUMBERS MAY BE FOUND ON PAGE 12-4 OF
I THIS HEALTH AND SAFETY PLAN. ALL HEALTH AND SAFETY FORMS
MUST BE SUBMITTED AT THE END OF PROJECT ACTIVITIES.
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I Geib'Y HASP November 5, 1993
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-N-
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0UA0RANGL£ LOCATION
\CJOOEl::::E<::SOC:::::=::::1::iooocaaaaaaaai'eiooo===':ioooeaaaaaaaaa'oooa::::==5000E:=eeiii6000c:::=:::57000. r((T
E3=====35::::,=3:=aa,:=:EO :==ee:=:=:==ee:==ee==SI KlLQM(T(R
CONTOUR INTER.V.AL 10 FEET
Ill 119ENVIRONMENT & l~IDI INFRASTRUCTURE
FIGURE 1-1
LOCATION MAP
GEIGY CHEMICAL CORPORATION SITE
ABERDEEN,NORTHCAROLINA
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_,,.,., ... ~
-"'"/ _,,,,~ .... ·
NOTES,
---~ ,,s ... ,,,., .. -~--·
,,o "-"'--~=_,..,.•·-· ~ • .._ ......
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TOPO MAPPING BY WOOLPERT CONSULTANTS BASED ON
AERIAL PHOTOGRAPHY FLOWN MARCH 26. 1989 WITH
GROUND CONTROL TIED TO THE STATE PLANE COORDINATE
SYSTEM.
PLANJMITRIC FEATURES WERE FIELD IDENTIF"IED
ON MAY 18, 1989 BY WOOLPERT CONSULTANTS.
150' 300' 450' oc=======i=======:Jc=======i
N:\86619\6619GH01.0WG
· ...... , .. _.,,_
···--...... -.,...._
·------~ -., __ ··._. ___ _
"~
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'·-·
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455(_ ..
... _..ENVIRONMENT &
l~U> I OORASfRUCTURE
LEGEND
PAVED ROAD
DIRT ROAD RAILROAD
FENCE
PROPERTY LINE
INDEX CONTOUR
PREVIOUS EXCAVATION
FIGURE 1-2
SITE PLAN
GEIGY CHEMICAL CORPORATION SITE
ABERDEEN. NORTH CAROLINA
CAR
PORT
l ETAL SHED
' ·---\
AREA
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2.0 SITE DESCRIPTION
The Geigy Chemical Corporation Site ("Site") is located one-half mile east of Aberdeen on
State Highway 211 in Moore County, North Carolina (Figure 1-1). The Site is vacant and
bound by Highway 211 to the north, the Aberdeen & Rockfish Railroad to the south, and
the Allred property to the east. The former area of active use at the. Site comprised
approximately one acre. The Site contains partial concrete foundations from two former
warehouses, a small office building, a concrete tank pad, storage tanks for purge water, and
a decontamination pad (Figure 1-2).
The Site was operated as a pesticide blending and formulation facility by various operators
from approximately 1947 to 1967 and by retail distributors of agricultural chemicals from
1968 to 1989. The pesticides DDT, toxaphene, and BHC were received in bulk at the Site,
blended with clay and other inert materials, repackaged, and sold. Pesticides were not
manufactured at the Site but were formulated by dry mixing into a product suitable for local
consumer use. During normal formulation activities, there were occasional incidental losses
to the Site soils.
Soil removal actions were conducted in 1989 and 1991. Approximately 3,071 tons of
contaminated soil and 460 tons of debris have been removed from the Site and properly
disposed of. All Site facilities ( except for the office building) have been demolished. A
portion of the concrete pads under the former warehouses remains at the Site. Currently,
the Site is unoccupied and fenced.
Analytical parameters for soil and groundwater samples collected during the Remedial
Investigation (RI) included volatile and semi-volatile organic compounds, metals,
polychlorinated biphenyls (PCBs), and pesticides. Copper, lead, and zinc were within
background concentrations. BHC isomers and toxaphene were the most prevalent
pesticides. Trichloroethene (TCE) was detected in the second uppermost aquifer but no
other media. Air was found to be not impacted by the Site.
Pesticides are the only compounds exceeding Performance Standards in surficial soils (0 -
1 foot depth). Toxaphene is the most prevalent pesticide, with concentrations ranging from
November 5, 1993
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below detection to 130 mg/kg. Toxaphene governs the removal of soils for all but three of
the 72 locations that exceed the Performance Standards given in the Record of Decision.
Maximum groundwater concentrations for pesticides were found in shallow monitoring wells.
The BHC isomers (alpha, beta, gamma, and delta) were the most prevalent pesticides, with
maximum concentrations around 30 ug/1.
The nature and extent of contamination at the Site has been characterized through a
two-phase Remedial Investigation (ERM; March 1992). This information was used to
develop a baseline risk assessment to determine possible public health risks and potential
impacts to environmental receptors (Clement International Corporation, March 13, 1992).
Potential remedial alternatives were developed and evaluated in the Feasibility Study
(Sirrine Environmental Consultants, March 1992). More complete descriptions of the Site
physiographic, hydrologic, geologic, demographic, ecological, and natural resource features
are presented in the Remedial Investigation and Feasibility Study reports.
Geigy HASP November 5, 1993
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I 3.0 PROJECT DESCRIPTION
I Pre-design field activities to be conducted at the Site include:
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• water level measurements
• aquifer testing
•
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•
•
installation of additional monitoring wells
sampling of groundwater wells
sampling of groundwater using direct push technology
determination of allowable infiltration rates
soil sampling (0 - 1 foot)
surveying
More detailed descriptions of the pre-design field activities are presented in the Draft
Remedial Design Work Plan (RUST E&I, August 1993) and the Draft Sampling and
Analysis Plan (RUST E&I, August 1993). ·
Geib'Y HASP November 5, 1993
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4.0 HAZARD ASSESSMENT
Site history indicates the potential for all personnel involved in intrusive activities to be
exposed to a variety of pesticides and trichloroethene (TCE). Table 4.1 presents a variety
of exposure limits applicable to workplace exposures. The American Conference of
Governmental Industrial Hygienist (ACGIH) Threshold Limit Values (TLVs) for the work
environment are given for airborne exposures. Two TL V standards are presented, if
available, for each chemical. The Time Weighted Average (TWA) is the time-weighted
average concentration for a normal 8-hour day and a 40-hour work week, to which nearly
all workers may be repeatedly exposed, day after day, without adverse effect. The Short-
Term Exposure Limit (STEL) is a 15-minute time-weighted average exposure that should
not be exceeded at any time during a work day even if the 8-hour TWA is within the TLV.
Exposures above the TLV-TWA up to the STEL should not be longer than 15 minutes and
should not occur more than four times per day. There should be at least 60 minutes
between successive exposures in this range. Also presented, when available, is the
Occupational Safety and Health Administration (OSHA) Permissible Exposure Limit (PEL).
The PEL values are presented either as an 8-hour TWA, Ceiling (Ceil) limit, and/or a peak
limit (maximum concentration above the ceiling limit for an 8-hour shift). The ceiling value
indicates the upper limit of acceptable excursions above the TWA except for a maximum
peak value that may be allowed for a specific duration within an 8-hour or shorter increment
as indicated. The Immediately Dangerous to Life and Health (IDLH) value represents a
maximum concentration from which one could escape within 30 minutes without any escape-
impairing symptoms or any irreversible health · effects. Other relevant health-based
information that applies to this health and safety plan or to the employee's right-to-know
is discussed in the following toxicity summaries for the identified contaminants.
Geigy HASP November 5, 1993
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CHLORINATED HYDROCARBON PESTICIDES
(Chlordane, DDD, DDT, Dieldrin, Heptachlor, Lindane and Toxaphene)
The chlorinated hydrocarbon pesticides are very persistent in the environment. Absorption
occurs most efficiently through ingestion. Routes of exposure include ingestion, skin contact
and· inhalation. These compounds act as depressant or stimulant of the central nervous
system. Mild poisoning may result in dizziness, nausea, abdominal pain and vomiting.
Chronic poisoning will include the mild signs followed by severe irritability, convulsions and
possible coma. Seizures may be extremely violent. In severe cases, the convulsions may be
continuous, with elevated body temperatures, unconsciousness, labored breathing, rapid
heart beat and eventually death.
Geigy HASP November 5, 1993
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TRICHLOROETHYLENE
(CHCLCCl..,i, Ethylene Trichloride, Ethinyl Trichloride, Trichloroethene, TCE)
Trichloroethylene is a colorless, nonflammable, non-corrosive liquid with the "sweet odor"
characteristic of some chlorinated hydrocarbons. Decomposition of trichloroethylene, due
to contact with hot metal or ultraviolet radiation, forms products including chlorine gas,
hydrogen chloride, and phosgene. Dichloroacetylene may be formed from the reaction of
alkali with trichloroethylene. TCE is primarily us_ed as a solvent in vapor degreasing. Also
it is used for extracting caffeine from coffee, as a dry cleaning agent, and as a chemical
intermediate in the production of pesticides, waxes, gums, resins, tars, paints, varnishes, and
specific chemicals such as chloroacetic acid.
Exposure to trichloroethylene vapor may cause irritation of the eyes, nose, and throat. The
liquid, if splashed in the eyes, may cause burning, irritation and damage. Repeated or
prolonged skin contact with the liquid may cause dermatitis. Acute exposure to
trichloroethylene depresses the central nervous system exhibiting such symptoms as
headache, dizziness, vertigo, tremors, nausea and vomiting, irregular heart beat, sleepiness,
fatigue, blurred vision, and intoxication similar to that of alcohol. Unconsciousness and
death have been reported. Alcohol may make the symptoms of trichloroethylene
overexposure worse. If alcohol has been cpnsumed, the overexposed worker may become
flushed. TCE addiction and peripheral neuropathy have been reported. Recent reports
indicate that exposure to trichloroethylene may induce liver tumors in mice.
TLV:
PEL:
IDLH:
DESCRIPTION:
SOLUBILITY:
FLASH POINT:
IONIZATION POTENTIAL:
VAPOR PRESSURE:
LEL:
UEL:
RESPIRATOR CARTRIDGE
BREAKTHROUGH TIME:
HNu SENSITIVITY:
OVA SENSITIVITY:
Geigy HASP
50 ppm TWA, 200 ppm STEL
100 ppm TWA, 200 ppm Ceil, 300 ppm 5 min/2 hr Peak
1,000 ppm, Carcinogen
Colorless liquid with a chloroform-like odor
0.1%
None
9.47 eV
58 mm Hg @ 20°C
11%
41%
55 minutes at 1,000 ppm
89% with a 10.2 eV lamp
70%
4-3
November 5, 1993
--- ----------- - - --
CONTAMINANT TLV-TWA
Chlordane 0.5 mg/m 3
ODD NE
DDT 1 mg/m 3
Dieldrin 0.25 mg/m 3
Heptachlor 0.05 mg/m 3
Lindane 0.5 mg/m 3
Toxaphene 0.5 mg/m 3
Trichloroethylene 50 ppm
CA -Carcinogen
NE -Not Established
RF -Respirable Fraction
TD -Total Dust
Peak - 5 minute/2 hour
Skin -Notation indicating skin contact hazard
Geigy HASP
TABLE 4.1
INHALATION EXPOSURE LIMITS
TLV-STEL PEL-TWA
Skin 0.5 mg/m 3
NE NE
1 mg/m 3
Skin 0.25 mg/m 3
Skin, CA 0.5 mg/m 3
Skin 0.5 mg/m 3
1 mg/m 3, Skin 0.5 mg/m 3
200 ppm 100 ppm
PEL-STEL
Skin
NE
Skin
Skin
Skin
Skin
1 mg/m 3, Skin
200 ppm, Ceil
300 ppm, Peak
November 5, 1993
IDLH
500 mg/m 3, CA
NE
Carcinogen
450 mg/m 3, CA
700 mg/m 3, CA
1,000 mg/m 3
NE
1,000 ppm, CA
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5.0 QUALITATIVE RISK ANALYSIS
Inhalation, ingestion and contact pathways may be associated with all soil sampling, drilling,
and groundwater monitoring activities. During drilling and groundwater sampling, workers
may be at risk to chemical contamination. During dusty conditions, Site personnel may be
at an increased risk of exposure. If personal protective clothing or gloves receive rips, cuts
or tears during Site activity, personnel may be at risk to contact hazards. In this case,
personnel must decontaminate immediately and replace damaged personal protective
clothing. Avoid skin contact at all times. Support personnel may be exposed from
improperly decontaminated equipment and/or samples.
During all intrusive operations, procedures and protective equipment must be utilized to
reduce the risks associated with drilling operations and Site contaminants of concern. Toxic
gases may place Site personnel in an IDLH atmosphere. Environmental monitoring will be
conducted at the Site during all Site intrusive operations.
Proper use of industrial hygiene and personal protective equipment accompanied by sound
hygiene practices outlined in this HASP will minimize the potential risks at this Site.
However, failure of equipment or an individual to adhere to guidelines outlined in this
document may increase the potential risk.
Geigy HASP November 5, 1993
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6.0 ENVIRONMENTAL MONITORING
During all Site intrusive operations, the Site HSO must monitor environmental conditions
for combustibles and toxics. Sampling will be conducted at the Site with a combustible gas
and organic vapor direct reading instrument.
At a maintained reading of 35 ppm in the breathing zone, all personnel must wear a half-
mask respirator equipped with organic vapor/HEPA (GMA-H) combination cartridges.
Full-face respirators with organic vapor/HEPA combination cartridges are required for
breathing zone concentrations exceeding 350 ppm and/or during dusty or splash conditions.
At or above breathing zone concentrations of 700 ppm, personnel must upgrade respiratory
protection to include supplied-air full-face systems in the pressure demand mode equipped
with a 5 minute escape bottle. The Site HSO will evacuate the area at or above breathing
zone or source concentrations exceeding 770 ppm.
If levels exceed 10% of the LEL, Site personnel will evacuate the area due to the risk of
explosion. After 15 minutes to allow vapors to dissipate, the Site HSO will return for
additional readings. Flammable readings will be collected while approaching the source.
For levels remaining at or above 10% LEL, the Site evacuation order will remain in effect.
The Site HSO must notify the RUST E&I RHSS prior to using dilution ventilation systems.
NOTE
Geib')' HASP
If respiratory protection is upgraded to supplied-air or evacuation occurs, the
Site HSO must notify the RUST E&I RHSS immediately.
Novcmher 5, 1993
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6.0 ENVIRONMENTAL MONITORING
During all Site intrusive operations, the Site HSO must monitor environmental conditions
for combustibles and toxics. Sampling will be conducted at the Site with a combustible gas
and organic vapor direct reading instrument.
At a maintained reading of 35 ppm in the breathing zone, all personnel must wear a half-
mask respirator equipped with organic vapor/HEPA (GMA-H) combination cartridges.
Full-face respirators with organic vapor /HEPA combination cartridges are required for
breathing zone concentrations exceeding 350 ppm and/ or during dusty or splash conditions.
At or above breathing zone concentrations of 700 ppm, personnel must upgrade respiratory
protection to include supplied-air full-face systems in the pressure demand mode equipped
with a 5 minute escape bottle. The Site HSO will evacuate the area at or above breathing
zone or source concentrations exceeding 770 ppm.
If levels exceed 10% of the LEL, Site personnel will evacuate the area due to the risk of
explosion. After 15 minutes to allow vapors to dissipate, the Site HSO will return for
additional readings. Flammable readings will be collected while approaching the source.
For levels remaining at or above 10% LEL, the Site evacuation order will remain in effect.
The Site HSO must notify the RUST E&I RHSS prior to using dilution ventilation systems.
NOTE
Geigy HASP
If respiratory protection is upgraded to supplied-air or evacuation occurs, the
Site HSO must notify the RUST E&I RHSS immediately.
November 5, 1993
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7.0 PERSONAL PROTECTIVE EQUIPMENT (PPE)
At a minimum, all Site personnel shall wear tyvek protective clothing and neoprene steel-toe
boots while in the exclusion zone. During dusty conditions, full-face respirators equipped
with organic vapor/HEPA (GMA-H) combination cartridges are mandatory. This upgrade
would provide better respiratory protection and maximum eye protection. Chemical
resistant gloves must be worn during all intrusive activities, sample handling and decon
procedures. If free-product or splash conditions exist, saranex suits and full-face respiratory
protection is required. During activity within 50 feet of all heavy equipment ( e.g., drill rigs),
the Site HSO will collect sound level measurements. If sound level measurements exceed
90 dBA, hearing protection is mandatory. Hearing protection shall be worn within 50 feet
of all high noise sources. All RUST E&I personnel are enrolled in a hearing conservation
program. Hard hat use is mandatory during all drilling activity and when other overhead
hazards exist. The following items must be available to all personnel ( except where noted
as stand-by):
•
•
•
•
•
•
•
Tyvek Suits/Saranex Suits
Neoprene Boots (Steel Toe)
Nitrile Gloves
First-Aid Kit(s)/Bloodborne
Pathogen Kit(s)
Hearing Protection
Hard Hats
Fire Extinguishers
Geigy HASP
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•
•
•
•
•
•
•
Half-mask/Full-face Respirators
Supplied-Air Respirators (stand-by)
Organic Vapor /HEP A cartridges
(GMA-H)
Decon Sprayer
Drink Cooler
Eyewash Stations
Dust Goggles
November 5, 1993
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8.0 COLD/HEAT EXPOSURE
a. Cold Exposure
The human body is designed to function at a certain internal temperature. When the body
temperature falls, the body compensates for the heat loss by increasing its rate of
metabolism. Fatal exposures to cold among workers have almost always resulted from
exposures involving failure to escape from low environmental air temperatures or from
immersion in low temperature water. The single most important aspect of life-threatening
hypothermia is the fall in the deep core temperature of the oody. The deep core
temperature should not fall below 36°C (98.6°F). Lower body .temperatures will likely
result in .reduced mental alertness, reduction in rational decision-making capability, loss of
consciousness, or death.
Mild to severe pain in the extremities may be the first early warning of cold exposure.
During exposure to cold, maximum severe shivering develops when the body core
temperature has fallen to 35°C (95°F). Useful physical and mental work is limited when
severe shivering occurs. Since prolonged cold exposure at temperatures well above freezing
can lead to dangerous hypothermia, whole body protection must be provided. If work
activities are performed in temperatures below 40°F, adequate insulating clothing to
maintain core temperature must be worn by all workers. All workers should be aware of
the effect of wind chill on exposed skin. The higher the wind speed, the lower the perceived
air temperature in the work area.
b. Heat Exposure
When the body temperatures rises, the body seeks to dissipate the excess heat. The
disorders due to heat stress are heat cramps, heat exhaustion, and heat stroke. Heat cramps
are painful spasms which occur in the muscles of workers who sweat profusely in the heat
and drink large quantities of water, but fail to replace the body's lost salts and electrolytes.
Heat exhaustion is characterized by extreme weakness or fatigue, dizziness, nausea, and
headache. In serious cases, a worker may vomit or lose consciousness. The skin is clammy
and moist, complexion pale or flushed, and the body temperature can be normal or slightly
Geigy HASP November 5, 1993
8-1
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higher than normal. Treatment consists of rest in a cool place and replacement of body
water lost by perspiration. Mild cases may recover spontaneously with this treatment.
Severe cases may require care for several days. There are no permanent effects.
Heat stroke is caused by the breakdown of the body's heat regulating mechanism. The skin
is very dry and hot with a red or bluish appearance. Unconsciousness, mental confusion,
or convulsions may occur. Without quick and adequate treatment, the result can be death
or permanent brain damage. Medical assistance should be given quickly. The person
should be moved to a cool place. Body heat should be reduced artificially by soaking the
person's clothes with water and fanning them. The following steps may be taken to reduce
heat stress, as directed by the Site HSO:
• Acclimate the body
• Drink more liquids to replace body water lost during sweating
• Increase salt consumption (salt tablets are not recommended)
•
•
•
Wear personal cooling devices
Wear supplied air suits or respirators equipped with a vortex tube that cools the air
being supplied
Count pulse rate during a 30-second period as early as possible in the rest break. If
the heart rate exceeds 110 beats per minute at the beginning of the rest break,
shorten the next work cycle by one-third and keep the rest break the same. If the
heat rate still exceeds 110 beats per minute at the next rest break, shorten the
following work cycle by one-third
Geigy HASP November 5, 1993
8-2
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9.0 ACCIDENT PREVENTION
Instructing respective employees in safe work practices and emergency procedures is the
responsibility of the RUST E&I HSO. Adherence to the Health and Safety Plan, standard
safety operating procedures and practices described below shall be required of Site
personnel to minimize the risk of accidents resulting in injury or excessive chemical
exposure.
Gcibry HASP i\'ovcmbcr 5, 1993
9-1
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10.0 STANDARD OPERATING SAFETY PROCEDURES AND CONTROLS
The following general operating procedures shall be followed by all Site personnel. These
precautionary measures are designed to reduce the risks of inadvertent or accidental
chemical exposure or injury during on-site operations.
a. Personal Precautions
•
•
•
•
•
•
•
Geigy HASP
Be familiar with standard operating safety procedures and adhere to all
instructions and requirements in the Site safety plan.
Eating, drinking, chewing gum or tobacco, smoking, or any pradice that
increases the probability of hand-to-mouth transfer and ingestion of material
is prohibited in the exclusion zone. However, a supply of cold water and
disposable cups will be located in the decontamination area such that
employees will have access to water with only removal of gloves, hat, and
respirator where used.
Contact lenses shall not be worn in the exclusion zone .
Hands and face must be thoroughly washed upon leaving the work area .
Whenever decontamination procedures for outer garments are in effect, the
entire body should be thoroughly washed as soon as possible after the
protective garment is removed.
No facial hair which interferes with a satisfactory respirator fit of the
mask-to-face-seal is allowed on personnel required to wear respirators.
Avoid contact with contaminated or suspected contaminated surfaces .
Whenever possible, avoid walking through puddles, pools, mud, etc. Avoid
kneeling or sitting on the ground, equipment or drums.
Personal articles shall be prohibited in the exclusion zone .
November 5, 1993
10-1
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b.
• Medicine and alcohol can exacerbate the effects from exposure to toxic
chemicals. Alcoholic beverage intake should be minimized or avoided on off
work hours during field operations. Prescribed drugs should not be taken by
personnel on Site operations where the potential for absorption, inhalation,
or ingestion of toxic substances exists unless specifically approved by a
qualified physician. Do not work when ill.
• Be alert to potential health and safety hazards, as described in this Health
and Safety Plan.
Operational Requirements
•
•
•
•
•
•
•
All personnel going on-site shall be familiar with this HASP and adequately
trained and thoroughly briefed on anticipated hazards, equipment to be worn,
safety practices to be followed, emergency procedures, and communications.
Respiratory protective devices and/ or protective clothing appropriate to the
designated levels of protection shall be worn by all personnel going into areas
designated for wearing protective equipment.
Personnel on-site shall use the buddy system .
Visual and/or voice contact shall be maintained between pairs on-site. Entry
team members shall remain close together to assist each other during
emergencies.
During continual operations, on-site workers shall act as safety backup to each
other. Off-site personnel shall provide emergency assistance.
Personnel should practice unfamiliar operations prior to doing the actual
procedure.
Entrance and exit locations shall be designated and emergency escape routes
delineated. The following warning signals shall be used when necessary:
Geib'Y HASP November 5, 1993
10-2
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C.
Hand gripping throat ............ .
Grip partner's wrist or
both hands at waist ..... , ..... , ..
Hands on top of head , .......... ,
Thumbs up ................... .
Thumbs down ......... , .... , , ..
Can't breathe
Leave area immediately
Need assistance
OK, I am all right, I understand
No, negative
• Communications shall be maintained between field team members at all
times, The nearest telephone to Site activities will be located in order to
facilitate emergency response communications.
• Wind indicators visible from the work location should be identified before
commencing operations.
• Personnel and equipment m the contaminated area shall be minimized,
consistent with effective Site-operations.
• Decontamination procedures for leaving a contaminated area shall be
followed. Hands and face shall be washed prior to work breaks and eating.
Work areas and decontamination procedures have been established based on
expected Site conditions (See Section 11 ).
• Report all injuries or work related illnesses to the Site HSO or supervisor as
soon as possible.
Adherence to Buddy System
No field operation is without some degree of risk. For this reason, a minimum of two
people must be assigned to all task locations and must stay within voice contact at all times,
Gcih'Y HASP November 5, 1993
10-3
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11.0 DECONTAMINATION CONTROL MEASURES
a. Decontamination Procedures
Safe personal hygiene practices are discussed in Section 10, Standard Operating Safety
Procedures and Controls. Decontamination requirements shall be established by the Site
HSO. Personnel and portable field equipment decontamination shall be carried out. When
working, care should be taken to avoid contamination of equipment (particularly
instruments) whenever possible.
Monitoring instruments and protective equipment shall be decontaminated if the equipment
has been in contact with the ground or splashed with contaminated water, mud or other
material. Equipment decontamination solution shall consist of detergent and water. Rinse
solution shall be potable water. All decontamination and rinse solutions shall be disposed
on Site under the supervision of the Site HSO. Decontamination of equipment and ancillary
tools and sampling devices shall consist of removal of contaminated soil and mud, and steam
cleaning. All vehicles and equipment shall be cleaned before relocation to and use at any
other sampling Site or work area. All disposable PPE and equipment shall be placed into
an impermeable bag or wrapped in plastic sheeting.
A minimum decontamination layout for Level C protection and equipment can be found in
Table 11. 1. Decontamination procedures are presented in Table 11. 1.
NOTE: All personnel subject to decontamination should shower daily as soon as possible
after their work shift.
b. Medical Emergencies
For physical injuries, first-aid treatment shall be given at the Site, depending upon the
seriousness of the injury. (All first-aid/CPR responders will comply with the OSHA
Bloodborne Pathogen Standard 29 CFR 1910.1030). The victim should undergo
decontamination, if necessary, unless such procedures interfere with necessary treatment.
Geig)' HASP November 5, 1993
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In life-threatening situations care shall be instituted immediately. Protective clothing shall
be removed or cut away if this will not cause delays, interfere with treatment, or aggravate
the problem. If contaminated protective clothing cannot be removed, wrap the victim in
clean materials to help prevent contamination of medical personnel and ambulances.
For chemical exposure emergencies, decontamination procedures shall be followed unless
severe medical problems requiring life sustaining measures are evident.
C. First-Aid
In the event of injury, the emergency shall be handled according to the procedures described
in the Emergency Procedures Section. First-aid/blood borne pathogen kits shall be
maintained at the control access point between the decontamination and support zones and
in support vehicles.
If the victim cannot be safely moved from the contamination area, first-aid necessary to
stabilize the victim for safe transport shall be administered at the accident location.
Appropriate decontamination of all clothing and equipment shall be followed upon leaving
the contaminated area.
Geigy HASP November 5, 1993
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Decon
Procedures
Station 1:
Station 2:
Station 3:
Gcibry HASP
TABLE 11.1
Minimum Decontamination Layout
For Level C Protection and Equipment
Station 1 Station 2 Station 3 Station 4 Station 5
Equipment PPE and PPE and PPE Hand and·
Drop Other Other Disposal Face Wash
Equipment Equipment
Wash Rinse
Equipment needed to perform decontaminarion
Plastic Sheet Station 4: 20-30 Gallon Trash Can,
Disposal Bag
Wash tub, Decon Solution, Station 5: Field table, 5 gal water
Long-handled soft-bristled cooler or carboy, soap,
scrub brush towels
Wash tub, rinse water, long•
handled soft-bristled scrub
brush
November 5, 1993
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12.0 EMERGENCY PROCEDURES
Some risk of personal injury or chemical exposure is inherent in hazardous waste Site
activities. These risks and the effects of unpredictable events such as injury, chemical
exposure, fire or explosion shall be minimized by:
• Adhering to good work practices,
• Using personal protective equipment appropriate for existing field conditions,
• Performing adequate monitoring of individuals and ambient field conditions, and
• Staying alert both to personal performance and to that of co-workers.
An emergency situation is considered to exist if:
• Any member of the field crew is injured in an accident,
• Any member of the field crew experiences or exhibits any adverse effects or
symptoms of cheinical exposure, and
• . Safety monitoring indicates Site conditions more hazardous than anticipated or that
an immediate danger to life or health exists.
a. · General Emergency Procedures
• In the event that any member of the field crew experiences any adverse
effects or symptoms of exposure while on the scene, the entire field crew shall
immediately halt work and act according to the instructions provided by the
Site HSO.
• The discovery of any condition that would suggest the existence of a situation
more hazardous than anticipated, shall result in the evacuation of the field
team and re-evaluation of the hazard and the level of protection required.
• In the event that an accident occurs, the Site HSO is to complete an Accident
Report. Follow-up action shall be taken to correct the situation that caused
the accident.
Geigy HASP November 5, 1993
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• The Project Coordinator must be notified of all Site emergencies .
b. Personal Injul)'
Site personnel are trained in American Red Cross first-aid procedures and shall administer
appropriate first-aid treatment, including CPR, in emergency situations. The following
general emergency procedures shall be carried out in the event of injul)':
C.
1. Notify the Site HSO of the incident.
2. If the victim can be moved safely, remove from the contaminated zone to the
decontamination zone using established entry/ exit points.
3.
4.
Administer first-aid.
Transport victim to nearest hospital or emergency medical center or call for
ambulance transport, as appropriate.
NOTE: The Site HSO shall direct the removal of injured personnel from the
contaminated zone and shall approve any necessary deviation from
established decontamination procedures. Such deviation shall be based
upon the severity or life-threatening nature of the injury.
5. Notify the RUST E&I RHSS of the incident and describe the emergency
response actions taken.
Chemical Exposure
Before entering the contaminated zone, all Site personnel shall be thoroughly acquainted
with the types of toxic/hazardous chemicals present and their potential concentrations. The
following general procedures shall be followed for chemical exposure emergencies:
1.
Geigy HASP
Move the victim from the immediate area of exposure or contamination,
taking precautions to prevent additional exposure of other individuals.
November 5, 1993
12-2
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d.
2.
3.
4.
Notify the Site HSO of the exposure incident.
If the victim can be moved safely, proceed to the decontamination zone
through established control points.
Decontaminate clothing or remove if safe to do so.
•
•
For skin or eye contact, thoroughly wash affected areas with water
(eyes should be flushed for at least 15 minutes).
For inhalation exposure, ensure that victim has adequate fresh air.
5. Administer additional first-aid treatment as appropria_te.
6. Transport victim to nearest hospital or emergency medical center or call for
ambulance transport as appropriate.
NOTE: The Site HSO shall direct the removal of injured personnel from the
contaminated zone and shall approve any necessary deviation from
established decontamination procedures. Such deviation shall be
based upon the security or life-threatening nature of the injury.
7. Notify the RHSS of the incident and describe the emergency response actions
taken.
Fire or Explosion
· In the event of a fire or explosion:
1. Immediately evacuate injured personnel and leave the area,
2. Administer first-aid as appropriate,
3. Notify emergency services, and
4. Notify the RUST E&I HSO.
Geigy HASP November 5, 1993
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e. Primary Emergency Contacts
The appropriate contact(s) from the following list shall be made for all emergency
situations. A telephone is located in the office building at the Site.
CALL 911 FOR ALL EMERGENCIES
Contact
Police
Fire/Rescue
Moore County Regional Hospital
Telephone
[phone]
[phone]
[phone]
For ambulance, fire or police contacts, give the name of State Highway 211 and the nearest
intersection. A map to the Moore County Regional Hospital is presented in Figure 12-1.
A copy of the map to the hospital will be maintained within each vehicle used by field
personnel. In the event no telephone can-be reached, Channel 9 can be accessed with a
Citizens' Band (CB) Radio for emergency assistance.
Notify the client contact and the RUST E&I RHSS after primary emergency contacts have
been made. The PPE Manager should be contacted if unforeseen circumstances require the
immediate procurement of additional personal protective equipment.
Attending emergency physicians should be given the telephone number of the RUST E&I
Medical Director to obtain immediate access to an employee's medical records and for -'
consultation purposes.
The telephone numbers of these secondary contacts are listed below:
Project Contact
Lorraine Miller
Geigy HASP
Olin Corporation
(Project Coordinator)
Telephone
[phone]
12-4.
November 5, 1993
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Secondary Contacts (continued)
Harold E. Moore II
RUST E&I RHSS
(Greenville Operations)
Eric Olson
RUST E&I Equipment Procurement
Dr. J.W. McPhail
RUST E&I Medical Director
Geigy HASP
12-5
[phone] (8 am -5 pm)
[phone] (After Hours)
[phone]
[phone]
November 5, 1993
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MOORE COUNTY
REGIONAL HOSPITAL
fis? ~
PINEHURST
I'll ... ENVIRONMENT &
l~U:>I INFRASTRUCTURE
1
ABERDEEN
Aberdeen and
Rockfish Railine
GEIGY
SITE
t
N
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NOTTO SCALE
Figure 12-1
Hospital Location Map
Geigy Chemical Corporation
Aberdeen, North Carolina
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13.0 TRAINING OF PERSONNEL
In order to be in compliance with OSHA regulations, all personnel, whose duties include
participation in job-related field activities, must be able to document "a minimum of 40
hours of initial instruction, 8-hour refresher training, 8-hour course for site supervisors, and
a minimum of three days of actual field experience under the direct supervision of a trained,
experienced supervisor."
Site-specific training shall be carried out by the Site HSO prior to entering the Site. This
shall consist of a review of the specific hazards of concern, risks, symptoms of exposure and
an overview of the HASP to include delineation of work zones, .access, decontamination
protocols, safety procedures and emergency contacts.
Geigy HASP November 5, 1993
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14.0 MEDICAL SURVEILLANCE
RUST E&I is providing medical smveillance support for numerous ongoing operations. The
Medical Surveillance Program is the core element of the RUST E&I Health and Safety Plan
that provides for employee assurance as well as liability protection. The intent of this
program is to detect deleterious consequences of occupational exposure to hazardous
substances and physical stresses, particularly those associated with the work environment at
hazardous waste Sites. The Surveillance Program is designed to monitor specific
physiological conditions and mechanisms that may be affected by non-episodic exposure as
well as to provide acute or episodic medical care as needed.
All Site personnel will have had a pre-employment physical examination conducted by an
occupational health physician and, on the basis of this examination, will have been certified
as being fit for duty on potentially hazardous sites.
Unscheduled medical examinations will be conducted, however, in the unlikely event of
unusual exposures or accidents.
All medical records are maintained with the RUST E&I Medical Director and are
accessible, within the limits of the Privacy Act, through written requests to the RUST E&I
RHSS.
Geigy HASP November 5, 1993
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15.0 RECORDKEEPING
RUST E&I shall maintain logs and reports sufficient to document the implementation and
execution of the personnel protection program. This documentation shall consist of medical
surveillance files, training files, daily logs and accident reports.
Medical Surveillance
Confidential medical surveillance files are maintained by the RUST E&I RHSS. These files
document employee participation in the medical surveillance program and fitness to work
on hazardous sites. The RUST E&I Medical Director maintains medical records. Access
to these files and records is controlled by the RHSS.
Training
Documentation of employee training is maintained in RUST E&I Health and Safety files
under the direction of the RUST E&I RHSS. These files document employee attendance,
level of training and follow-up or refresher instruction.
Work Logs
Daily work logs shall be maintained by the Site HSO. Copies of daily logs shall be
forwarded to the Contracting Officer on request. The daily log shall contain:
• Date,
• Area(s) or site(s) worked,
• List of employees by area and hours exposed,
• Personal protective equipment utilized by employees,
• Results of monitoring tests,
• Waste materials removed from work area(s),
• List of equipment decontaminated, and
• Description of special or unusual events or incidents, including all first aid treatments
not otherwise reportable.
Geigy HASP November 5, 1993
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Any incident resulting in a work stoppage shall be fully documented in a report prepared
by the Site HSO and submitted to the RUST E&I RHSS.
Accident Reporting
In addition to descriptions in the daily log and work stoppage reports, any accident and/or
chemical exposure incident shall be investigated, analyzed and documented in an accident
investigation report submitted to the RUST E&I RHSS. This process shall be applicable
to both RUST E&I and all subcontractors. These reports, prepared by the Site HSO in
consultation with the RUST E&I RHSS, shall contain a full description and analysis of the
incident, including exposure work-hours and a log of occupational injuries and illnesses
(OSHA Form 200 or equivalent as prescribed by 29 CFR 1904).
Formal accident reports shall be prepared for any diagnosed illness or injuries that result
in a lost work day or fatality. The accident report shall identify all contributing causes and ·
recommend future hazard control measures to reduce the risk of recurrence.
Site personnel are responsible for reporting all injuries as soon as possible to the Site HSO
or the RUST E&I RHSS. The Site HSO must notify the Project Coordinator of all Site
emergencies.
Geigy HASP November 5, 1993
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Geigy HASP
APPENDIX A
DAILY SIGN-IN/OUT LOG
November 5, 1993
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Mr ENVIRONMENT& I INFRASTRUCTURE
TIME
IN OUT NAME
DAILY SIGN-IN/OUT LOG
PROJECT:----------
PROJECT LOCATION:-------
PROJECT NO.:---------
SITE SAFETY OFFJCER:------
DATE: -----------
PAGE NO.:------~---
FlRM PURPOSE ON-SITE
Note: This fom1 is lO be completed on a daily basis by all personnel working on lhc site.
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Geigy HASP
APPENDIX B
WORK ZONE ENTRY AND EXIT LOG
November 5, 1993
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rM llrlJII ENVIRONMENT & 1'-U> II INFRASTRUCTURE
TIME
IN OUT NAMHFIRM
WORK ZONE ENTRY AND EXIT LOG
PROJECT:----------
PROJECT NO.:---------
SITE SAFETY OFFICER:------
DATE: -----------
SITE HNU/OV A READINGS . LEVEL PPE
LOCATION ON BREATHING ZONE) ffilC/B)
-
Nore: lliis fonn is to be comp!clcd on a daily b.-:isis by all on-Sile personnel working within 3 work zone.
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Gcib'Y HASP
APPENDIX C
RESPIRATOR USE LOG
November 5, 1993
---------ftlllrl' ENVIRONMENT & ----------l~U> I INFRASTRUCTURE
Employee Name:-------------------
Clicnl/Projut Site: ---
Date(!)
Totals
Pmjcct Number
Time in Respirator
(Hours)
RUST E&J RECORD OF
RESPIRATORY WEAR (OSHA RECORD)
Page __ of __
Weck Ending __j__J __
Employee No.: ------------Expense Code 76
Instrument Reading (2)
(HNUorOVA) Type f R 0
Expense Type 119
Subcontract Code
Office
cspirntor (3) Use Only
Comments: ------------'-------------------------~-------------
Notes:
(I) Record on a daily ha.sis
(2) If worn because of dusty conditions -Note "Dusty Conditions" (3) Level C or !l Site Snfely Officer Approval
Atwch to Timeshcct nnd Forward lo Corporate Accounting on a Weekly Basis
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Gcib'Y HASP
APPENDIX D
ATMOSPHERIC MONITORING LOG
November 5, 1993
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ftl lrl' ENVIRONMENT &
ll"U:> I INFRASTRUCTURE ATMOSPHERIC MONITORING LOG
FIELD HEAL TH AND SAFETY
Page __ of __
Date __ ~ _ _,_ __
Circle: Sun Mon Tue Wed Thu Fri Sat
Site:----------------------Project No.:---------
Site Safety Officer: -------------------------------
Action Levels: D 0,---l>· C 0---D B □---!> (Stop work. call in for instructions)
(Check box and write in levels for upgrade)
Task/Equipment.: ______________________________ _
Weather: ---------------------------------
Time OVA HNu 02 LEL H2S Comments: Duration of Readings,
PPM PPM % % PPM Upgrades, Location, etc.
Additional Comments:------------------------------
Signature: __________________ _
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Geib'Y I !ASP
APPENDIX E
HASP FIELD MODIFICATION FORM
November 5, 1993
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• l'M 11r1' ENVIRONMENT &
lfl.Ull II INFRASTRUCTURE
HEAL TH AND SAFETY PLAN
FIELD MODIFICATION FORM
PAGE NO. Or-
l'ROJITT: ______________________________ _
PROJECT LOCATION:---------------------------
PROJECT NO.:------------------------------
SITE SAfETY OFFICER: --------------------------
RELD MODIFICATION TO HASP· _______________________ _
PREPARED BY:-------,-----------------------SITE SAFETY OFFICER DA TE
ACCEPTED BY:-----------------------------DATE RUST E&l FIELD MANAGER
ACCEPTEDBY:-----------------------------DATE CONTRACTOR REPRESENTATIVE (IF APPLICABLE)
APPROVED BY ____________________________ _
RUST E&I REGIONAL HEALTH AND SAFETY SPECIALIST OR
ALTERNATE HASP REVlEWER
DATE
NOTE: Field Modifications lO 1-IASP's must be discussed with llic RUST E&l RHSS or CHSM with subscqucnl
wrinen approval. Secure approval through fax.. ·