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HomeMy WebLinkAboutNCD981927502_19920801_Geigy Chemical Corporation_FRBCERCLA ROD_Record of Decision - Summary of Remedial Alternative Selection-OCRI I I I -I I I I I I I I I I I I I I I RECORD OF DECISION SUMMARY OF REMEDIAL ALTERNATIVE SELECTION GEIGY CHEMICAL CORPORATION SITE ABERDEEN, MOORE COUNTY NORTH CAROLINA PREPARED BY: U.S. ENVIRONMENTAL PROTECTION AGENCY REGION IV ATLANTA, GEORGIA RECBVEO AUG 31 1992 SUPERFUNDGION D D I I I I I I I I I I I I I I II -• DECLARATION FOR THE RECORD.OF DECISION SITE NAME AND LOCATION Geigy Chemical Corporation Aberdeen, Moore County, North Carolina STATEMENT OF BASIS AND PURPOSE This decision document presents the selected remedial action for the Geigy Chemical Corporation Superfund Site in Moore County, North Carolina, chosen in accordance with the Comprehensive Environmental Response, Compensation, and Liability Act of 1980, as amended by the Superfund Amendments and Reauthorization Act of 1986 and, to the extent practicable, the National Contingency Plan. This decision is based on the administrative record file for this Site. The State of North Carolina concurrs with the selected remedy. .ASSESSMENT OF THE SITE Actual or threatened releases of hazardous substances from this Site, if not addressed by implementing the response action selected in this Record of Decision, may present an imminent and substantial endangerment to public health, welfare, or the environment. DESCRIPTION OF THE SELECTED REMEDY This remedy addresses the principle threat posed by this Site. The major threat is the contaminated groundwater emanating from beneath the Site. This remedial action will also address soil contamination. The major components of the selected remedy include: GROUNDWATER Extraction of groundwater across the Site in the upper aquifer and the second uppermost aquifer that is contaminated above Maximum Contaminant Levels or the North Carolina Groundwater Standards, whichever are more protective; On-site treatment of extracted groundwater via carbon adsorption to remove contaminants; Discharge of treated groundwater to the local POTW or an infiltration gallery. The discharge location will be determined in the Remedial Design; and D I I I I I I I I I I I I I SOIL Continued analytical monitoring for contaminants in groundwater. Demolition of former warehouse foundation; Disposal at a municipal or secure landfill; Excavation of the top foot of on-site soils contaminated above the performance standards; TCLP testing of the stockpile of contaminated soil to determine final disposition; Off-site incineration of contaminated soils that fail the TCLP test; Off-site disposal in an approved hazardous waste landfill of contaminated soils that pass the TCLP test; Backfilling, grading and revegetation of excavated area; ADDITIONAL SAMPLING AND MONITORING Additional sampling and analyses of the second uppermost aquifer to determine the extent of pesticide contamination, and to determine if the trichloroethylene (TCE) found in two wells is site-related. Until it is proven that the TCE is not site-related, it will be assumed that the TCE is site-related and thus, it will be included as a contaminant of concern. STATUTORY DETERMINATIONS The selected remedy is protective of human health and the environment, complies with Federal and State requirements that are legally applicable or relevant and appropriate to the remedial action, and is cost-effective. This remedy utilizes permanent solutions and alternative treatment technology to the maximum extent practicable, and satisfies the statutory preference for remedies that employ treatment that reduces toxicity, mobility, or volume as a principal element. Since this remedy may result in hazardous substances remaining on-site above health based levels, a review will be conducted within five years after commencement of remedial action to ensure that the remedy continues to provide adequate protection of human health and the environment. I Gc;riWz,Yrl~ 1,4,,\Greer C. Tidwell r·Regional Administrator Date I I I I I I B I I I I I I I I I I I TABLE OF CONTENTS SECTION PAGE NO. I. SITE NAME, LOCATION AND DESCRIPTION ......... . 1-1 II. III. IV. v. VI. VII. A. Introduction. . . ............. 1-1 B. Site Description ................... 1-1 C. Topography . . . . . . . . . . . . . : . . . . . . . . 1-1 D. Geology . . . . . . . . . . . . . . . . . . . . . . . 1-1 E. Surface Water ..................... 1-4 F. Hydrology . . . . . 1-4 G. Meteorology . . . . 1-4 H. Demography and Land Use 1-5 I. Utilities . . . . . 1-5 SITE HISTORY AND ENFORCEMENT ACTIVITIES A. Site History . . . . . . . . . . . . B. Previous Investigations ............... . c. Enforcement Activities ............... . HIGHLIGHTS OF COMMUNITY PARTICIPATION. SCOPE AND ROLE OF RESPONSE ACTION WITHIN SITE STRATEGY SUMMARY OF SITE CHARACTERISTICS A. Groundwater ....... . B. Initial Removal Activity C. Soil Investigation .. D. 1991 Removal ..... E. Sediment Investigation 2-1 2-1 2-1 2-2 3-1 4-1 5-1 5-1 5-3 5-3 5-9 5-9 SUMMARY OF SITE RISKS .................. 6-1 A. Contaminants of Concern 6-1 B. Exposure Assessment. . 6-1 C. Toxicity Assessment . . 6-5 D. Risk Characterization Summary 6-7 E. Environmental (Ecological) Risk 6-10 F. Soil Remediation ................... 6-10 APPLICABLE OR RELEVANT AND APPROPRIATE REQUIREMENTS (ARARS) A. Action-Specific ARARs . B. Location-Specific ARARs -i- 7-1 . . . 7-1 I I I I I I I I I I I I I I I I I I I TABLE OF CONTENTS (CONT'D) SECTION PAGE NO. C. Chemical Specific ARARs ............. . Groundwater ......... . Maximum Contaminant Levels NC Groundwater Standards Soils . . . . . . . . . . . . ( MCLs) . . . . . . . . 7-9 7-9 7-9 7-9 7-14 VIII. DESCRIPTION OF ALTERNATIVES ... 8-1 IX. A. REMEDIAL ALTERNATIVES TO ADDRESS GROUNDWATER CONTAMINATION B. 1. No Action . . . . . . . . . . . . . . . . . . 8-1 2. Slurry Wall and Cap ............... 8-4 3. Groundwater Recovery to Attain Remediation Levels 8-5 REMEDIAL ALTERNATIVES TO ADDRESS i. No Action . . . . 2. Off-Site Disposal . . . . 3. Capping . . . . . . . . . . 4. On-Site Thermal Desorption 5. On-Site Incineration . . . SOIL . . . . . . . CONTAMINATION . . . . . . . . . . . . . . . . . . . . . . . . 8-6 8-6 8-7 8-7 8-8 8-9 SUMMARY OF COMPARATIVE ANALYSIS OF ALTERNATIVES . . . . 9-1 9-2 9-4 9-4 9-4 9-4 9-5 9-5 9-5 A. B. C. GROUNDWATER REMEDIATION ............... . Overall Protection of Human Health & the Environment . Compliance with ARARs ............... . Long-term Effectiveness and Permanence ; . Reduction of Toxicity, Mobility, or Volume Short-term Effectiveness Implementability Cost . . . . . . . . . . •' . SOIL REMEDIATION . . . . . . . . . . . . . . . . . . . Overall Protection of Human Health & the Environment . Compliance with ARARs ............... . Long-term Effectiveness and Permanence .. Reduction of Toxicity, Mobility, or Volume Short-term Effectiveness Implementability. Cost . . . . . . . . . . MODIFYING CRITERIA . . . . . . . . . . . . . . . . . . State Acceptance .. Community Acceptance ................ . -ii- 9-5 9-5 9-6 9-6 9-6 9-6 9-6 9-6 9-6 9-7 9-7 I I I I I n I I I I I I I I I I I I I TABLE OF CONTENTS (CONT'D) SECTION PAGE NO. x. XI. SELECTED REMEDY . . . . . . . . . . . . . . . . . . . . A. Groundwater Remediation ............ . B. Soil Remediation C. Cost ..................... . STATUTORY DETERMINATIONS ... . . . . . . Protection of Human Health and the Environment Compliance with ARARs ............... . Cost-Effectiveness ............... . Utilization of Permanent Solutions and Alternative Treatment Technologies or Resource Recovery Technologies to the Maximum Extent Practicable Preference for Treatment as a Principal Element XII. DOCUMENTATION OF SIGNIFICANT CHANGE. APPENDIX A -TABLES OF ANALYTICAL RESULTS APPENDIX B -RESPONSIVENESS SUMMARY -iii- 10-1 10-1 10-4 10-5 11-1 11-1 11-1 11-1 11-2 11-2 12-1 D m LIST OF FIGURES I FIGURE PAGE NO. I 1 Site Location Map. . . . . . . . . . . . . . . . 1-2 2 Site Map . . . . . . . . . . . . . . . . . . . . 1-3 I 3 4 5 Phase 1 Groundwater Sampling Locations ...... 5-2 Phase 2 Groundwater Sampling Locations ...... 5-4 Feb. 1989 Removal Locations . . 5-5 I 6 7 8 Phase 1 Soil Sampling Locations . . . 5-7 Phase 2 Soil Sampling Locations .......... 5-8 Phase 4 Soil Sampling Locations .......... 5-10 9 1991 Removal Locations .............. 5-11 D 10 11 Sediment Sampling Locations ............ 5-13 Conceptual Flow Diagram for Groundwater Treatment .10-3 I I I I I I I I I I I -iv- I B I I TABLE I 1 I 2 3 D 4 5 I 6 I 7 8 I 9 10 11 I 12 I 13 14 15 16 I 17 18 6-1 I 6-2 6-3 6-4 6-5 I 7-1 7-2 7-3 I 7-4 7-5 8-1 8-2 I 9-1 I I I LIST OF TABLES PAGE NO. Phase 1 Groundwater Analytical Results Volatiles and Semi-Volatiles Phase 1 Groundwater Analytical Results Pesticides Phase 1 Groundwater Analytical Results Metals Phase 2 Groundwater Analytical Results Volatiles Phase 2 Groundwater Analytical Results Pesticides Phase 1 Soil Analytical Results .. Volatiles and Semi-Volatiles Phase 1 Soil Analytical Results Metals Phase 1 Soil Analytical Results .. Pesticides Phase 2 Soil Analytical Results .. Background Soil Analytical Results ......... . Phase 3 Soil Analytical Results . Pesticides and Metals Phase 3 Soil Analytical Results . Volatiles and Semi-Volatiles Soil Boring Analytical Results ........... . Phase 4 Soil Analytical Results .... . 1991 Post Removal Soil Analytical Results Phase 1 Sediment Analytical Results Phase 2 Sediment Analytical Results . Phase 3 Sediment Analytical Results • Contaminants of Concern ...... . Toxicity Criteria for Contaminants of Concern Total Risks Associated with Current Land-Use ..... Total Risks Associated with Future Land-Use Soil Remediation Levels ..... Potential Action-Specific ARARs. Potential Location-Specific ARARs Potential Chemical-Specific ARARs Groundwater ARARs ....... . Groundwater Remediation Levels .......... . Groundwater Remediation Technologies Considered .. . Soil Remediation Technologies Considered ...... . Remedial Alternatives Summary ........... . -v- A-1 A-2 A-3 A-5 A-6 A-7 A-8 A-10 A-11 A-18 A-19 A-24 A-25 A-~6 A-28 A-31 A-34 A-38 6-2 6-6 6-8 6-9 6-12 7-2 7-6 7-10 7-13 7-15 8-2 8-3 9-3 I I I I I D I I I I I I I I I I I I I DECISION SUMMARY I. SITE NAME, LOCATION AND DESCRIPTION A. Introduction The Geigy Chemical Corporation Site ( Geigy Site) is located just east of the corporate city limits of Aberdeen, North Carolina on Highway 211 in southeastern Moore County ( Figure 1). The Site was operated as a pesticide blending and formulation facility from approximately 1947 to 1967 and was operated by retail distributors of agricultural chemicals from 1968 to 1989. B. Site Description The Geigy Site is an approximately one-acre parcel located on the Aberdeen and Rockfish Railroad right-of-way. The property is in the form of an elongated triangle between, Highway 211 and the railroad, with the highway and railroad intersecting at the apex of the triangle. The Site is currently vacant and consists of foundations from two former warehouses, an office concrete tank pad (Figure 2). partial concrete building, and a At the east end of the former warehouse buildings is an on-site w~ter supply well. The well water was probably used for process operations, lavoratories, showers, and on-site drinking water. C. Topography The Site is in the Sandhills physiographic province, characterized by rolling hill underlain by well-drained, . unconsolidated sands. Site elevations range from approximately 460 to 480 feet above mean sea level (MSL). The Site is essentially flat. D. Geology Generally, the geology under the Site consists of unconsolidated sedimentary rocks which were deposited on top of crystalline basement rocks. The thickness of the sedimentary rocks in the Aberdeen area is approximately 200 to 250 feet. The surface geology consists of .coastal Plain sediments, crystalline rocks of the Piedmont province, and Triassic basin rocks. 1-1 -liiiiilil liiliil liiiii iiliil -!!!!! I!!!!!!!! f 1-2 I I I I • I I I I I I I I I I I 1. ~ ' ! i 0 6 ', '' 1 I : ,' \.r-~--> --~ ill!/ ' ' ' l., ! I ]I : I ' ' ~ ,Ii 0 ; • 1 I 1 I I I / ' I . [D :.; :...: -~ :.... :.... :r, ' '"" I t B R I I I I I g n H I I I I I I Site soils are of the Candor series and are deep, excessively drained sandy soils (e.g., sand, silty sand, loamy sand, sandy loam). E. Surface Water There is no surface water at the Site. are dry except during storm events. storms is rapidly absorbed into the vicinity of the Site. Drainage ditches at the Site Surface water runoff during well-drained soils in the F. Hydrogeology Three aquifers Creek ( second aquifer. underlie uppermost), the Site: the shallow and Upper Cape Fear (uppermost), Black (third uppermost) The uppermost aquifer (shallow aquifer) receives rainfall infiltration. Approximate depth to groundwater in the uppermost aquifer at the Site is 35 to 45 feet. Saturated thickness at and near the Site ranges from one to 18 feet with an average saturated thickness and hydraulic conductivity beneath the Site of 12 and 2.8 feet/day, respectively. Potentiometric data from the shallow monitoring wells indicate groundwater flow from the eastern and western portions of the Site meet in an elongated zone of convergence. East of the convergence zone, groundwater flows west and northwest and west of the convergence zone, groundwater flow is predominantly to the east-southeast. The Black Creek confining unit is between the surficial aquifer and the second uppermost aquifer. Average thickness and hydraulic conductivity of the second uppermost aquifer are 40 feet and 28 feet/day, respectively. This aquifer serves as the primary source of potable groundwater in the Aberdeen area. Groundwater flow in the second uppermost aquifer is generally north westerly. The Upper Cape Fear confining unit over the Upper Cape Fear aquifer. uppermost aquifer ranges from 10 overlies the crystalline bedrock. is generally to the northwest. G. Meteorology (approximately 60 feet thick) is In the Aberdeen area, the third to 20 feet thick and directly Groundwater flow in this aquifer I Average daily maximum temperature is 90 degrees F. in July and I I 1-4 u I I I I I I I I I I I I I I I I I I average daily minimum is 30 degrees F. in January. Average annual precipitation is 48 inches. Precipitation is fairly uniform year-round, ranging from three to five inches per month. H. Demography and Land Use The Site is bordered to the north by Route 211, to the south by a wooded area and to the west by Route 211 and the Aberdeen and Rockfish railroad. A residential property borders the east. A farm is located to the southeast of the site while the property immediately north on the opposite side of Route 211 is used for commercial purposes. A housing development is located 1/4 mile to the northwest of the site. Moore County occupies a total area of 672 square miles and has an estimated population of 59,013 (1990 census). Approximately 2700 people live in Aberdeen. Within 0 - 1 mile of the site, there are 355 families and a total of 1,208 people with a median age of 34 years. Approximately 132 people or 11% of the population within the 0 - 1 mile radius are between the ages of 7 to 13 years. I. Utilities Electricity, telephone, natural gas, and city water are available at the Site. Moore County sewerage connection is not available at the Site but is available within a half of a mile. 1-5 I I I I I I I I I I I I I I I I I I I II. SITE HISTORY AND ENFORCEMENT ACTIVITIES A. Site History The Geigy Site has been leased and operated by various companies since approximately 1947. From approximately 1947 to 1967, the Site was leased by several companies for pesticide formulation and retail sales. Since 1968, the Site has been used by retail distributors of agricultural chemicals, mainly fertilizers. The most recent occupant, Lebanon Chemical Corporation, operated a farm service center on the Site for retail distribution of agricultural pesticides and fertilizers. The Site is currently unoccupied; however, the Aberdeen and Rockfish Railroad which traverses the southern portion of the Site is still active. Known operators at the Site and approximate dates of operation are as follows: * White & Peele ( 1947-1948) * Blue Fertilizer (1948-1949) * Geigy Chemical Corporation (now Ciba-Geigy) (1949-1955) * Olin-Matheison Corporation (now Olin Corp) (1956-1967) * Columbia Nitrogen Corporation ( 1968) * Kaiser Aluminum & Chemical Corporation (1969-1984) * Lebanon Chemical Corporation (now Kaiser-Estech Corp) (1985-1989) Agricultural fertilizers, both liquid and dry, in bulk and bagged form, have been distributed from the facility at various times du1:ing the operating history. Micronutrients, such as copper and zinc, were added to fertilizers in small quantities (i.e. 0.05% to 0.3%) to increase the quality and yield of crops. The pesticides DDT, toxaphene, and BHC were known to have been formulated on-site. Technical grade DDT, toxaphene, and BHC were shipped in bags or barrels to Aberdeen. The technical grade pesticide was blended with clay or other inert materials to form a usable product and repackaged for sale to · local cotton and tobacco growing markets. Pesticides were not manufactured at the Site, but rather only formulated (i.e., blended) into a product suitable for local consumer use. B. PREVIOUS INVESTIGATIONS An EPA Site Investigation (SI) was conducted in March purpose of the SI was to collect soil and water samples the Hazard Ranking System (HRS) evaluation. 1988. The to support Isomers of BHC off-site locations: were detected in five groundwater samples two private wells and three of the municipal from 2-1 I I I I I I I I I I I I I I I I I I wells. Lead was detected in concentrations exceeding the drinking water standards in two private wells. Lead was not detected in the on-site groundwater sample. The· Site therefore work. was regraded by the railroad after this investigation, the soil sample locations were not relied upon for future c. Enforcement Activities There is no information of any past enforcement actions or violation citings at the Site. In addition, no known inspections by the North Carolina Department of Environmental Management (DEM) or the Department of Natural Resources ( DNR) oc_curred. The Geigy Chemical National Priorities October 4, 1989. Corporation Site was proposed for inclusion on the List (NPL) in June 1988 and became final on In March 1988, EPA sent notice letters to the following companies: 1. Ciba-Geigy Corp 2. Olin Corp 3. Kaiser Aluminum & Chemical Corp 4. Lebanon Chemical Corp 5. Aberdeen and Rockfish Railroad 6. Columbia Nitrogen Corporation The letters requested that the PRPs conduct a Remedial Investigation and Feasibility Study (RI/FS) for the Site. The notice letters also informed the PRPs of their potential liability for past costs. On December 16, 1988, EPA entered into an Administrative Order on Consent (AOC) wherein three of the PRPs, Ciba Geigy, Olin, and Kaiser, agreed to perform the RI/FS. The AOC was amended on January 23, 1991 to include the removal and proper disposal of contaminated soils containing toxaphene greater than 500 mg/kg and/or lindane at 100 mg/kg. 2-2 u I I I I I I I I I I I I I I I III. HIGHLIGHTS OF COMMUNITY PARTICIPATION Pursuant to CERCLA Sl13(K)(2)(Bl(i-v) and §117, the RI/FS Report and the Proposed Plan for the Geigy Site were released to the public for comment on March 26, 1992. These documents were made available to the public in the administrative record located in an information repository maintained at the EPA Docket Room in Region IV and at the Aberdeen Town Hall in Aberdeen, North Carolina. The notice of availability for these documents was published in the Pilot Newspaper (Southern Pines) and in the Moore County Citizen News (Aberdeen) on March 26, 1992. A public comment period on the documents was held from March 26, 1992 to April 24, 1992. Due to several requests, the public comment period was extended to May 25, 1992. Notice of this extension was placed in both newspapers on April 23, 1992. A copy of the notice was mailed to the public. In addition, a public meeting was held on March 31, 1992. At this meeting, representatives from EPA answered questions about problems at the site and the remedial alternatives under consideration. Other community relations activities included: * Issuance of a Fact Sheet on the RI/FS process in May 1990. * An availability session to address citizen concerns in June 1990. * Issuance of a Fact Sheet on the RI results in December 1991. * Issuance of a Fact Sheet on the Proposed Plan in March 1992. 3-1 I I I I I I I I I I I I I I I I I IV. SCOPE AND ROLE OF RESPONSE ACTION WITHIN SITE STRATEGY The intent of future risks threat posed contemplated identified at this remedial action presented in this at this Site. This remedial action by contamination at the Site. This for the Site. No other operable this Site. 4-1 ROD is to reduce will remove the is the only ROD units have been I I I I a D I I I I I I I I I I I I I V. SUMMARY OF SITE CHARACTERISTICS The RI at the Geigy Site included the characterization of groundwater, soil and sediment contamination. Surface water samples were not collected because there are no nearby surface water bodies. In addition, two removals (in three phases) were conducted during the RI. Results of these removals will be summarized below. A. Groundwater Investigation The groundwater investigation was conducted in two phases. In the first phase, ten groundwater monitoring wells were installed: six (MW-lS through MW-6S) in the shallow aquifer; three (MW-1D, MW-4D, and MW-6D) in the intermediate aquifer; and one in the deep aquifer. In addition, the water supply well was also included in the investigation (Figure 3). The sampling was conducted in November 1990. Analytical parameters included field parameters (pH, temperature, specific conductance), Target Compound List (TCL) volatiles, semivolatiles, and pesticides and Target Analyte List (TAL) metals. The results of the volatile and semi-volatile analyses is shown in Table 1, Appendix A. Acetone was found in three wells, but is believed to be a laboratory contaminant because acetone was also found in the blank samples. Xylene and bis(2-ethylhexyl)phthalate were each found in only one well at 4J ug/1 and 7J 1:g/l respectively. The compound 1,2,4-trichlorobenzene was found n two wells, MW-SS and MW-6S, at 4J ug/1 and SJ ug/1 respectively. Trichloroethene was found in two deep wells, MW-4D and MW-6D, at 200 ug/1 and 11 ug/1 respectively. The pesticide results are shown in Table 2, Appendix A. As indicated, pesticides were detected in all the shallow wells except MW-lS, which is a background well. Pesticides were not detected in the intermediate or deep wells. Gamma-BHC (lindane) was the most prevalent, ranging in concentration from 0.4 ug/1 to 30 ug/1. The Maximum Contaminant Level (MCL) for gamma-BHC is 0.2 ug/1. Toxaphene was found in three wells in concentrations up to 10 ug/1. The MCL for toxaphene is 3 ug/1. Results of the metal analyses are summarized in Table 3, Appendix A. The secondary drinking water standard for iron (300 ug/1) was exceeded in six wells including both upgradient wells (MW-lS and M W-1 D). Copper was detected in the water supply well at a concentration of 1,180 ug/1 which is above the secondary drinking water standard of 1000 ug/1. The MCL for lead of 50 ug/1 was exceeded in the water supply well at 51B ug/1. None of the other wells contained lead above the MCL or the CERCLA cleanup level of 15 ug/1. 5-1 --- ...... --...... ....... 1 .... - ,z-1 ~c • \r£nt 1c cUN-~nvu1 ,.,......,U'l ....... I ,. tl.w'lllAII.JC( tC') ..,._.,11 .. UH-~1l W,llH wt't'\-1 WlU. l!!!!!!I • ... , .... --------~ t,.------' ' I S:C: • IOID ...... L--/ ' .... .,.__.., SC • ZII .... ,., 'I • 11.I L[LLND .,._ .. \C • lOO .... 4.l l • 11.1 fl\,-1,\& ~ ~ g,IIUIIIL vU-1.. MW ... J+t,. V M:Ullllli ,_.u. ..-,aa -AU- t>l ·l() ~ ,a,.llflA .-,Al~ IJ\il- ~ ~ F ll:IIKI•: ·1 l'il-";1-. I ,:KOIINl>WATEK '.;AMl'il NC 1.rn:1\T IONS I I I I I I I I I I I I I I I I I I I Based on the results of the first phase of groundwater sampling, the investigation expanded laterally. Six monitoring wells were installed in areas downgradient of the existing monitoring well system in the shallow aquifer (MW-7S through MW-l0S, MW-12S and MW-13S). In addition, three monitoring wells were installed in the intermediate aquifer (MW-11D, MW-14D, and MW-15D) (Figure 4). Two of the intermediate wells, MW-14D and MW-15D, were installed to try to determine if the trichloroethene found in wells MW-4D and MW-6D, was coming from an upgradient source. In addition, two private wells were also sampled. Monitor wells MW-7S through MW-l0S, MW-12S, MW-13S, MW-11D, MW-14D, and MW-15D were analyzed for TCL pesticides and volatile organics. Wells MW-1D, MW-4D, PZ-1, and the two private wells, Allred and PMP, were analyzed for TCL volatiles only. The results of the TCL volatile analyses is presented in Table 4, Appendix A. The compounds 2-butanone, 1,1, 1-trichloroethane, 4-methyl-2-pentanone, and toluene were found in only one well, the PMP well, at concentrations below MCLs. Trichloroethene was found in the two private wells as well as monitoring wells MW-4D, MW-6D and PZ-1. The two upgradient deep wells, MW-14D and MW-15D, did not contain any trichloroethene. The TCL pesticide results are shown in Table s, Appendix A. Pesticides were found in two wells, MW-l0S and MW-11D. B. Initial Removal Activity The initial site reconnaissance in January 1989 identified obvious areas of pesticide contamination in surface soils near the warehouse loading doors and railroad dock. The removal was conducted in two phases, one in February 1989 and the other in·. October 1989 (Figure 5). Visually contaminated soils were sent to a landfill in South Carolina for disposal as hazardous waste. In addition, railroad ties were removed from the Area C spur track and were disposed with the soils. A total of 462 tons of waste were disposed. On March 1, 1989, a ban was issued by the Governor of South Carolina which precluded the disposal of any hazardous waste from North Carolina in South Carolina. Once the ban was lifted, the remainder of visually contaminated soils were removed. In October 1989, 227 additional tons of contaminated soils were shipped to South Carolina. C. Soil Investigation The soils investigation was conducted in four phases. Phase 1 provided a definition of potential Site-specific parameters for soils (TCL pesticides, copper, lead, zinc); Phase 2 defined the horizontal extent of contamination; Phase 3 delineated the vertical extent of 5-3 ;-----------· I I . . ! ' . i I C I I I I I I I I I I B I I I I I I ------------------- DOOR 5 LU~ DOOR 6 WAREHOUSE B LEGEND DOOR J DOOR 2 WAREHOUSE A WJN RAILROAD TRACK ~ AREAS DESIGNATED FOR REMOVAL • DOOR 1 0 JO 60 SCALE IN fECT FIC:IIHE '> FE»HIIAHY ANII oC'l'Ol/1-:H I <JH'J REMOVAi. 1.111:AT IONS I I I I I I I I I I I I I I I I I I I contamination; and Phase 4 provided additional information to complete the data set. The Phase 1 soil sampling locations "are shown on Figure 6. The volatile and semi-volatile results are given in Table 6, Appendix A. Acetone was found in all the samples, but was also found in the associated blank. Benzoic Acid was found in three samples ranging in concentrations from 360J ug/kg to 3600J ug/kg. The metals results are shown in Table 7, Appendix A. Most of the metal concentrations were within the range of the concentrations detected in the background sample (SS-04). Pesticides were detected in all the samples. Total DDT was the most prevalent compound found. Toxaphene was found in three samples, with concentrations ranging up to 400,000 ug/kg (Table 8, Appendix A). For the Phase 2 soils investigation, a forty-foot grid was established over the Site as shown in Figure 7. The samples were analyzed for TCL pesticides, along with copper, lead, and zinc. Analytical results are given in Table 9, Appendix A. Toxaphene and DDT were the most prevalent compounds found during this phase. In addition, two background soil samples, SS-121 and SS-122, were obtained north and east of the Site. Analytical results are given in Table 10, Appendix A. For Phase 3, the analytical results were reviewed to determine which sample locations contained significant concentrations of Site specific parameters. The term significant was defined as a soil concentration level of 10 mg/kg or greater total BHC, total DDT, or toxaphene. Sample grid locations exhibiting concentrations between 10 mg/kg and 100 mg/kg were resampled at two-foot and five-foot depth intervals. Sample grid locations with concentrations greater than 100 mg/kg were sampled at two, five, and ten-foot depth intervals. Table 11, Appendix A shows the analytical results for the sample locations that contained pesticides. Twenty samples at the two-foot depth contained pesticide constituents. Of those, only three samples contained a significant total pesticide concentration; SS-51-2 (SO mg/kg), SS-58-2 (32 mg/kg), and SS-100-2 (24 mg/kg). Pesticides were detected in 11 samples at a depth of five feet. Noteworthy is sample SS-73-5, which contained a total pesticide concentration of 302 mg/kg. Four samples contained pesticides at the ten-foot interval. Sample SS-76-10 contained the highest total pesticide level at 6 mg/kg. The samples were also analyzed for TCL volatile and semi-volatile compounds. Table 12, Appendix A shows the results of these analyses. 5-6 I I I I I I I I I I I I I I I I I I I 1l -00 lli] tJ I l i ~ I I • I ..J ' f I '0/ Ir \ \ : I I I I l f I X -. ~ ·~ ~ --< ------ -\ -- EJ - - u-n • liiii - tlllJrl; -CilNl'I°" JllU ~ ~ ................. ••• • I- .. l ___...,u1 - ,, I I I I '' PIIASE l f!GURE 7 SOIL SAl'll'LlNG LOCATI• I I I H I I I I I I I I I I I I I I I For the Phase 4 investigation, sampling was conducted to further delineate the extent of contamination. During the Site investigation conducted in 1988, soil samples were collected near an old foundation located south of the Geigy property line. Previous use of the foundation site and its original purpose are unknown. The results of the study indicated isomers of BHC and toxaphene at a depth of 22 feet below ground surface. Samples were collected near this foundation at the following depth intervals: 0-1 foot, 5-7 feet, 10-12 feet, 15-17 feet, and 20-22 feet. The analytical results are presented in Table 13, Appendix A. The surface sample contained the highest concentration of total pesticides. The Phase 4 sampling locations are shown in Figure 8. To further define the horizontal extent of contamination, additional samples were collected. The sampling locations are shown in Figure 8 and the analytical results are given in Table 14, Appendix A. Sample SS-58-20S contained the highest concentration of total pesticides at 290 mg/kg. Other samples with noteworthy total pesticide concentrations include SS-61-20S (6 mg/kg), SS-62-20S (9 mg/kg), SS-63-20S (73 mg/kg), and SS-91-l0N (32 mg/kg). D. 1991 Removal In accordance with an amendment to the Consent Order, the warehouse superstructures, pump house, and contaminated soils were removed from the Geigy Site during March and April of 1991. The removal limits were 500 mg/kg toxaphene and 100 mg/kg gamma-BHC. The excavated areas are shown on Figure 9 and the post-removal sampling results are shown in Table 15, Appendix A. A total of approximately 2000 tons of soil were removed from the Site. E. Sediment Investigation The sediment investigation was conducted in three phases. The first phase was performed to define the horizontal extent of contamination. The next phase included the collection of samples at one and two-foot depth intervals as. well as samples downgradient of the first phase samples that contained significant concentrations of pesticides. The last phase consisted of samples collected at the two, five, and ten foot depth at locations exhibiting significant concentrations of pesticides in surface soils. There are no surface water bodies on-site. The nearest perennial surface water body is Aberdeen Creek located approximately 4,000 - 5,000 feet west of the Site. The ditches convey stormwater runoff from the highway, railroad, and the Site, and are normally dry. 5-9 - - ---- - ..... fS'la.i•ltD l"IICPulr, lM - :J fo.aGA ... '" - ......... en-1 h111-1l 1u111,.r, 1un. l.OCAl&Oll ~-·'°"''""'-DtllNIAIUJNJ ,uw .. w \IMIAII 1 ......... , ,oc ... nQ,11..-111111, .. u,o 1,,LIAIUI\ 11<1 .. l'-'ID Ol,toL.._. OUJtlt1·Al"lilll. l't'II ltll•UVAI IJIUolf• • II I i1 I• iu1, 11 .. IHl, 5-10 I -iiil EJ . .. -1:.:-....,l___:_-- }(Atl &H Hl I FICIIKF H 1!!!11!1 l'IIA~iE 11 SOIi. ~;AMl'I.INC I.OCATlilf ---- • 0 e (,) l · l - -· . ., sul<fACC SOIL/lll\Rltll, I \\LAIIIIN;') Sl UlMl.NI SJ'\M''I IHI, I\\\ J\\11111'. 5-11 t· 1 - \ l·l " •.1 iH I J/1 I I I I - \ I!!!! !·l M M !!!9 0 ~ F!O!HF (j ! ,;IJ \ KLMt 1V /\t. UlCAT I ON~~ I I • I I I I D D D I I I I I I The first surface to from the collected increased deposited Figure 10. phase sediment samples were collected from the ground a maximum depth of one-foot. Sample OSD-28 was collected surface to a depth of 1.5 feet and sample OSD-29 was from the same location at a depth of 1.5 to 3 feet. The depth sampling was due to the presence of sediments at these locations. All sediment samples are shown in Analytical results are given in Table 16, Appendix A. The same pesticides that were found· in the soil samples were also found in the sediment samples, namely, the BHC isomers, the DDT isomers and toxaphene. Samples that contained noteworthy amounts of total pesticides include SD-1 (36 mg/kg), SD-2 (14 mg/kg), SD-3 (21 mg/kg), SD-6 (50 mg/kg), SD-8 (17 mg/kg), SD-13 (23 mg/kg), SD-19 (19 mg/kg), SD-20 (16 mg/kg), SD-21 (17 mg/kg), OSD-24 (72 mg/kg), OSD-27 (77 mg/kg), OSD-28 (30 mg/kg), and OSD-29 (55 mg/kg). Toxaphene concentrations ranged from not detected to 400,000 ug/kg. Also noteworthy is the concentration of DDT in Sample OSD-24 at 44,000 ug/kg and in sample OSD-27 at 52,000 ug/kg. Sample results for the next phase of the sediments investigation are presented in Table 1 7, Appendix A. These samples, taken down to a depth of 2. 5 feet, still contained contaminants. Samples that contained noteworthy amounts of total pesticides include S D-1-1.5 ( 12 mg/kg), SD-6-1.5 (64 mg/kg), SD-9-2.5 (144 mg/kg), SD-11-1.5 (76 mg/kg), SD-11-2.5 (16 mg/kg), SD-12-1.5 (71 mg/kg), SD-12-2.5 (15 mg/kg), SD-21-1.5 (30 mg/kg), OSD-27-1.5 (29 mg/kg), OSD-27-2.5 (7 mg/kg), OSD-28-5 (5 mg/kg), and OSD-43-0.5 (52 mg/kg). In the final phase, two, five, and ten foot samples were collee;ted from four sample locations SD-10, SD-11, SD-12 and SD-14. These sample locations exhibited surface pesticide concentrations greater than 500 mg/kg prior to the 1991 removal. Total pesticide concentrations on the whole, were lower than the shallow samples. Sample locations 12 and 14 showed significant amounts of contamination (Table 18, Appendix A). 5-12 -l!!!!!!!!!!I Ill! l!!!!!I li!li:I == 11,;11;1 - wooos IIIOOOS Llc.lND •ll--11 -Ila .. u, IU(-_, --I.JI, 5-13 iiii liliil ' I - -c:)-("_' ______ _ ... ~ • ..... • l .J 'I --- Fl<:IIHE 10 SEil i MENT SAMl'I. I NG I.OCAT I /IN:: I I I I I I I I I I I I g I I VI, SUMMARY OF SITE RISKS The Geigy Site is releasing contaminants into the environment. The Baseline Risk Assessment Report presents the results of a comprehensive risk assessment that addresses the potential threats to public health and the environment posed by the Site under current and future conditions assuming that no remedial actions take place and that no restrictions are placed on future use of the Site. The Baseline Risk Assessment report consists of the following sections: identification of chemicals of potential concern; toxicity assessment; human exposure assessment, risk characterization; and environmental assessment. All sections are summarized below. A. Contaminants of Concern Data collected during the RI were reviewed and evaluated to determine the contaminants of concern at the Site which are most likely to pose risks to public health. These contaminants were chosen for each environmental media sampled. Once these contaminants of concern were identified, exposure concentrations in each media were estimated. The maximum concentrations detected were compared to the calculated 95% confidence level of the arithmetic average of all samples, and the lower of these values was chosen as the estimated exposure concentration. Table 6-1 identifies the contaminants of concern and the reasonable maximum exposure (RME) concentration in each media sampled which was analyzed in the risk assessment. B. Exposure Assessment The exposure assessment identified potential pathways and routes for contaminants of concern. Two overall exposure conditions were evaluated. The first was the current land use condition, which considers the site as it currently exists. The second was the future land use condition, which evaluates potential risks that may be associated with any probable change in site use assuming no remedial action occurs. The exposure pathways that were evaluated under current land use conditions were: * Incidental ingestion of chemicals in on-site and off-site surface soil/sediment by an older child trespasser (8-13 years), 6-1 I I I I I I I I I I I I I D I D D D • TABLE 6-1 CONTAMINANTS OF CONCERN AND EXPOSURE CONCENTRATIONS FOR ALL ENVIRONMENTAL MEDIA EXPOSURE POINT CONCENTRATIONS FOR OFF-SITE SURFACE SOIL/SEDIMENT BETA-BHC 540 4,4'-DDD 25,000 4,4'-DDE 6,600 4,4'-DDT 52,000 DIELDRIN 12 TOXAPHENE 190,000 EXPOSURE POINT CONCENTRATIONS FOR ON-SITE SURFACE SOIL/SEDIMENT 540 25,000 6,600 52,000 12 190,000 I;( ·•••·>··.·•••••••••ffiM'.iw•·••·••7 .:.-:-.. ALDRIN 4.5 5.9 ALPHA-BHC 130 . 1,500 BETA-BHC 270 2,000 GAMMA-BHC 120 840 BENZOIC ACID 3,700 3,600 ALPHA-CHLORDANE 42 45 GAMMA-CHLORDANE 49 49 4,4'-DDD 3,700 15,000 4,4'-DDE 2,000 11,000 4,4'-DDT 9,000 54,000 DIELDRIN 250 1,500 TOXAPHENE 37,000 220,000 6-2 I I I I I I I I I g g 0 D u D D I I I . TABLE 6-1 (CONT) CONTAMINANTS OF CONCERN AND EXPOSURE CONCENTRATIONS FOR ALL ENVIRONMENTAL MEDIA EXPOSURE POINT CONCENTRATIONS FOR GROUNDWATER ALDRIN 2.0E-01 ALPHA-BHC 3.6E+0l BETA-BHC 2.SE+0l DELTA-BHC 2.9E+0l GAMMA-BHC 3.0+01 BIS(2-ETHYLHEXYL)PHTHALATE 6.4E+00 DIELDRIN l.2E+00 4,4'-DDE l.0E-01 ENDRIN KETONE 3.7E+00 HEPTACHLOR EPOXIDE 3.0E-01 TOXAPHENE 5.9E+00 TRICHLOROETHENE l.8E+02 1,2,4-TRICHLOROBENZENE 5.0E+O0 6-3 4.0E-01 3.6E+Ol 2.SE+0l 2.9E+0l 3.0E+0l 7.0E+00 2.0E+0O 2.0E-01 4.0E+00 3.0E-01 9.6E+00 l.8E+02 5.0E+00 I I I I g D D I I I I I B I I I I I I * * * * * Dermal surface years), absorption of chemicals in on-site and off-site soil/sediment by an older child trespasser (8-13 Inhalation of volatilized surface soil/sediment chemicals by an older child trespasser (8-13 years), Inhalation of volatilized surface soil/sediment chemicals by a merchant north of the site, Inhalation of volatilized surface soil sediment chemicals by a nearby child resident ( 1-6 years) and a nearby adult resident northeast of the site, Inhalation of chemicals in wind blown dust particles by a nearby child resident (1-6 years) and a nearby adult resident northeast of the site. * Inhalation of chemicals in wind blown dust particles by a nearby merchant north of the site. The exposure pathways that were evaluated under future land use conditions were: * * * * * Incidental ingestion of on-site surface soils/sediment by future on-site adult and child (1-6 years) residents and by a future on-site merchant, Dermal absorption soils/sediments by years) residents and to surface child ( 1-6 of chemicals absorbed future on-site adult and by a future on-site merchant, Ingestion of groundwater by future on-site adult and child (1-6 years) residents and by a future on-site merchant, Inhalation of volatile organic chemicals · while showering with groundwater by a future on-site adult and child ( 1-6 years) residents, Dermal absorption of groundwater by future residents, and chemicals while showering with on-site adult and child ( 1-6 years) * Inhalation of volatilized surface soil/sediment chemicals by future on-site adult and child (1-6 years) residents, and by future on-site merchants. For ingestion of residents and 120 assumed to work 5 soil, an exposure frequency of 170 days/yr for days/yr for merchants was assumed. (A merchant is days/wk, 50 wks/yr (2 weeks subtracted for 6-4 I I m I D I I I I I I I I I I I I I I vacation), minus 9 days for federal holidays and is to spend half of that time outside. Values for adult and child residents are based on 5 days/wk during the warmer months, April through October, and 1 day/wk during November through March). The exposure duration used was 6 years for a child, 30 years for an adult, and 25 years for a merchant. For ingestion of groundwater, an exposure frequency of 350 days/yr for residents and 241 days/yr for merchants was assumed. An ingestion rate of one liter per day was used for a child resident and an adult merchant. An ingestion rate of two liters per day was used for an adult resident. C. Toxicity Assessment Under current EPA guidelines, the likelihood of adverse effects to occur in humans from carcinogens and noncarcinogens are considered separately. These are discussed below. Table 6-2 summarizes the toxicity criteria for the contaminants of concern. Carcinogens EPA uses a ·weight of evidence system to classify a chemical's potential to cause cancer in humans. All evaluated chemicals fall into one of the following categories: Class A Known human carcinogen; Class B -probable human carcinogen, Bl means there is limited human epidemiological evidence and B2 means there is sufficient evidence in animals and inadequate or no evidence in humans; Class C Possible human carcinogen; Class D Not classifiable as to human carcinogenicity; and Class E -Evidence of noncarcinogenicity for humans. Cancer slope factors have been developed by EPA for estimating excess lifetime cancer risks associated with exposure to potentially carcinogenic chemicals. Slope factors, which are expressed in units of (kg-day/mg), are multiplied by t,he estimated intake of a potential carcinogen, in mg/kg-day, to provide an upper-bound estimate of the excess lifetime cancer risk associated with exposure at that intake level. The term "upperbound" reflects the conservative estimate of the risks calculated from the slope factor. Use of this approach makes underestimation of the actual cancer risk highly unlikely. Cancer potency factors are derived from the results of human epidemiological studies or chronic animal bioassays to which animal-to-human extrapolation and uncertainty factors have been applied. Noncarcinogens Reference doses (RfDs) have been developed by EPA for indicating the potential for adverse health effects from exposure to chemicals 6-5 TABLE 6-2 TOXICITY CRITERIA FOR CONTAMINANTS OF CONCERN CARCINOGENIC TARGET ORAL CHEMICAL CLASSIFICATION ORAL SF INHALATION SF ORGAN RfD Aldrin B2 1. 7E+0l 1. 7E+0l LIVER 3E-05 Alpha-BHC B2 6.3E+00 6.3E+00 LIVER Beta-BHC C l.BE+00 1. BE+00 LIVER Delta-BHC D Gamma-BHC B2/C l.3E+00 LIVER 3E-04 Benzoic Acid 4E+00 Bis(2-ethylhexyl) B2 l.4E-02 LIVER 2E-02 phthalate Alpha-Chlordane B2 l.3E+00 l.3E+00 LIVER 6E-05 Gamma-Clordane B2 l.3E+00 1. 3E+00 LIVER 6E-05 4,4'-DDD B2 2.4E-01 LIVER 4,4'-DDE B2 3.4E-01 LIVER 4,4'-DDT B2 3.4E-01 3.4E-01 LIVER SE-04 Dieldrin B2 l.6E+0l l.6E+0l LIVER SE-05 4-Methyl-2-SE-02 pentanone Toxaphene B2 l.lE+00 l.lE+00 LIVER 1,2,4-Trichloro-D lE-03 benzene UNITS RfD -mg/kg-day SF -(mg/kg-day)-l 6-6 I I I I u I • I I I I I I I I I I I exhibiting noncarcinogenic effects. RfDs, which are expressed in units of mg/kg-day, are estimates of lifetime daily exposure levels for humans, including sensitive individuals. Estimated intakes of chemicals from environmental media can be compared to the RfD. RfDs are derived from human epidemiological studies or animal studies to which uncertainty factors have been applied. These uncertainty factors help ensure that the RfDs will not underestimate the potential for adverse noncarcinogenic effects to occur. D. Risk Characterization To quantitatively assess the risks from the Geigy Site, the chronic daily intakes (CDI) were combined with the health effects criteria. For potential carcinogens, excess lifetime upperbound cancer risks were obtained by multiplying the estimated CDI for each chemical by its cancer slope factor. The total upperbound excess lifetime cancer risk for each pathway was obtained by summing the ~hemical-specific risk estimates. A cancer risk level of 1 x 10-represents an upper bound probability of one in one million that an individual could develop cancer due to exposure to the potential carcinogen under the specified exposure conditions. Significant contributors to the exceedance of the cancer risk levels were toxaphene, dieldrin, and DDT. Potential risks for noncarcinogens are presented as the ratio of the CDI to the reference dose for each chemical. The sum of the ratios of all chemicals under consideration is called the hazard index. The hazard index is useful as a reference point for gauging the potential effects of environmental exposures to complex mixtures. In gene:ral, a hazard index value greater than 1.0 indicates that the potential exists for adverse health effects to occur from the assumed exposure pathways and durations, and that remedial action may be warranted for the site. Significant contributors to the exceedance of LO for the HI were barium, manganese, mercury, vanadium, and zinc. Tables 6-3 and 6-4 summarize the quantitative estimates of risk under the current and future land use scenario for each target population respectively. Currently, the site is vacant, and a current consumer of contaminated ground water from the site has not been identified. The total cancer risks for current land use ranged from lE-06 to 9E-08. For future land use, it was assumed that the site would be used for residential purposes. The total cancer risks were in the lE-03 range. For non-cancer risk, the baseline of 1 for the HI was exceeded for ingestion of surficial groundwater. 6-7 I I I I I D D I I I I I I I I I I I TABLE 6-3 TOTAL RISKS ASSOCIATED WITH CURRENT LAND-USE CONDITIONS Area/Pathlliay Ingestion of Surface Soil/Sediment Dermal Absorption from Surface Soil/Sediment Inhalation of Volatile Chemicals Released from Surface Soil/Sediment Inhalation of Oust Particulates Total Cancer Risk Area/Pat~ay Ingestion of Surface Soil/Sediment Dermal Absorption from Surface Soil/Sediment Inhalation of Volatile Chemicals Released fra11 Sur1ace Soil/Sediment Inhalation of Oust P1rtieul1tn Caru:er Risk Due to All Chemicals On-Site Older C!'lild Trescasser (8-13 yrs> 7.0E-07 4.0E-07 2.0E-08 1E·06 OH·Sit! Older Child (8-13 yrs) 2.CE-06 9E-06 Off·Si-;e Adul, Merc-:iant 6.0E-07 6.0E-10 6E-07 OH-Site Adult Resiaent 9.0E-08 1.0E-10 9E-08 Noncancer Ri5k Due to All Chemicals On·Site Older Child Off-Site Tresoasser Older Child (8-13 yrs) (8-13 yrs) 4.0E-03 4. □E-02 l-OE-02 1.0E-02 (al <•> ---<•> ---<•> Off-Site Adult ~ei-enant (,1) ---(I) Off-Site Adult Resident (1) ---(I) (a) No inhalation toxicity cr;teria were available to assess noncarcincgenic risks. a Not evaluated. 6-8 Off·Si~e 'fou,g Child il:es i ::ent C,·6 Y!"Sl 1.□E-07 8.00E-11 1E-07 Off-Site Young Child Resident C1·!i yrs) ( a) ---(a) I I I I u I I I I g I I I I I I I I TABLE 6-4 TOTAL RISKS ASSOCIATED WITH FUTURE LAND-USE CONDITIONS Cancer 11:isk: Oue to All Chemicals Area/Dathway Surface Soil/Sediment: Ingestion of Surface Soil/ Sediment Oennal Absorption frca Surface Soil/Sediment Inhalation of Chmi;cals Released fri::m Surface Soil/Sediment Groundwater: Ingestion of Surficial groundwater Inhalation of Volatiles white Shower; ng Dermal Absorption of Chemicals while Showering Total Cancer Risk Child 11:esioent JE-05 4E·06 1E·06 2!·03 JE·OS 2E·06 2E·Ol Adult Resioent 1E·OS 1E·06 9E·07 4E·Ol 4E·08 6E·06 4E·Ol Merchant 6E•07 6E•07 1E·Ol 1E-Ol Noncancer R i sic Due to All Chemicals Area/Pathway Surface Soil/Sec:Hant: Ingestion of Surface soil/ Sediment Dermal Absor-ption frca Surface Soil/Sediment Child Resident 2E·01 2E·02 Inhalation of Chem;cals Released ···Ca) fraa Surface Soil/SedtMnt GrO\.ndw■ter: 1ngution of 5urf;cial gr°'-l'di,ater lrlltlttlan o1 Volatiles wllt It SIi-ring > I liver= 8.9 kidney• 6.5 7E-05 Dermal Absor-pt; an of Ch1111i cal s while Showring 1E-02 Adult Resident 2E·02 1E·OJ >1 liver•4.1 kidney : 3.2 1E·OS SE·OJ (a) No iMal1t;on toaicity criteria wre available to assess nonc:arcinogenic riska. • This pathway wu not evaluated. 6-9 Merchant 6E·Ol 9E·Ol ···(a) >I liver• 1.2 (kict,ey • 1.0) I I I I I I 0 I I I I I g I I I I I I E. Environmental (Ecological} Risk The vegetative community at the site is dominated by native grasses, which were planted following a previous removal action. Other herbaceous species which occur infrequently and along the perimeter of the site include poison ivy, cinquefoil, honeysuckle, passionflower, great ragweed, and goldenrod. A stand of bamboo occurs in the northeast corner of the site and a small number of pine trees occur in the eastern and western portions of the site. Terrestrial plants may be exposed to chemicals of concern in soil as a result of direct contact with subsequent plant uptake via the roots. No data are available on the toxicity of the chlorinated insecticides of concern on natural vegetation. The ·data that are available suggest that phytotoxic effects are likely to occur only at very high soil concentrations. The site is not expected to support extensive wildlife populations, given its small size, the limited diversity of the vegetative community, and the availability of higher quality habitat in adjacent areas. Resident vertebrate species of the site are likely limited to small mammals such as voles and other field mice. Some snakes and lizards also could occur at the site. Other wildlife species could occasionally use the site while foraging. Terrestrial wildlife exposures via the ingestion of food that has accumulated pesticides from the site are not likely to be significant. None of the chemicals of potential concern accumulate extensively in vegetation and therefore, significant exposure in the herbivorous species that may inhabit the site is unlikely. Some accumulation in soil invertebrates is possible and therefore ani.Jr?als that feed on these organisms could be exposed to chemicals in the food. The degree to which chemicals in soils · at the site could be bioaccumulated is unknown. Red-cockaded woodpeckers (a State and federal listed endangered species) which live in colonies located within one mile of the site are unlikely to be affected by chemicals in soil at the site. These woodpeckers feed on insects in trees, and generally do not feed below the understory layer. F. Soil Remediation Table 6-4 shows the estimated upperbound total carcinogenic risk posed by soil contaminants under a future 5esidential exposure scenario. The calculated risk· level of 3 x 10-is based on soils contaminated at the level of the site-wide average being ingested by a child. ( The site-wide soil data was used to develop a reasonable maximum exposure (RME) which is the 95% upper confidence limit of the samples arithematic average). 6-10 I I I I I • I D I I I I I I I -• I The future residential risk could have been calculated based on an assumption that a residence was placed at the site of the highest contaminant concentraton detected (sample SS-06) in the sampling program. The assumption in this case would be that a child was constantly exposed to this higher valfe. This assumption gives an estimated upperbound risk of ( 4.4 x 10-) . Soil Cleanup levels have been calculated at the 10-6 risk level based on direct exposure residential assumptions. The health-based soil cleanup levels are identified in Table 6-5. Table 6-5 also indicates the maximum concentration of each contaminant found at the site . 6-11 g D I I I I I I I I I I 1. I I. I I I I TABLE 6-5 SOIL REMEDIATION LEVELS ALDRIN 14 0.113 ALPHA-BHC 21 0.28 BETA-BHC 4.1 1.15 DELTA-BHC 1.9 NC GAMMA-BHC 3.2 1.5 DIELDRIN 9.7 0.13 ENDRIN KETONE 0.28 NC TOXAPHENE 450 2.0 DDD 28 7.6 DDE 11 5.5 DDT 54 4.75 GAMMA-CHLORDANE 0.049 1.43 ALPHA-CHLORDANE 0.045 1.4 NC -Not Calculated 6-12 1.0 X lOE-6 1.0 X lOE-6 l.OX lOE-6 l.OX lOE-6 l.OX lOE-6 l.OX lOE-6 1.0 X lOE-6 -1.0 X lOE-6 l.OX lOE-6 / 1.0 X lOE-6 / 1.0 X lOE-6 1.0 X lOE-6 l.OX lOE-6 I I I I g 0 I I I I I I I I I I I I I VII. APPLICABLE OR RELEVANT AND APPROPRIATE REQUIREMENTS (ARARs) Section 121(d) of CERCLA, as amended by SARA, requires that remedial actions comply with requirements or standards set forth under Federal and State environmental laws. The requirements that must be complied with are those that are applicable or relevant and appropriate to the (1) potential remedial actions, (2) location, and (3) media-specific chemicals at the Site. This Section examines the cleanup criteria associated with the contaminants found and the environmental media contaminated. A. Action-Specific ARARs Action-specific requirements set controls or restrictions on the design, performance, and other aspects of implementation of specific remedial activities. Because action-specific ARARs apply to discrete remedial activities, their evaluation will be discussed in greater detail in Section VIII. A retained alternative must conform to all ARARs unless a statutory waiver is involved. B. Location-Specific ARARs Location-specific ARARs must consider Federal, State, and local requirements that reflect the physiographical and environmental characteristics of the Site or the immediate area. Remedial actions may be restricted or precluded depending on the location characteristics of the site and the resulting requirement. A listing of potential location-specific ARARs and their consideration towards the Site is given in Table 7-1 Federal classification guidelines for groundwater are as follows: * Class I: Groundwater that is irreplaceable with no alternative source or is ecologically vital; * Class II: A -Groundwater currently used for drinking water; B -Groundwater potentially available for drinking water; * Class III: Groundwater not considered a potential source of drinking water due to natural contamination or insufficient yield. The uppermost aquifer at the Site is considered Class IIB and the second uppermost aquifer is considered Class IIA. State classification guidelines are based on best usage (NCAC 2L.0201). The uppermost and second uppermost aquifers are therefore considered Class GA groundwater under the State system. 7-1 I I I m g D D I I I I I B I R I I I I VII. APPLICABLE OR RELEVABT ABD APPROPRIATE REQUIREMENTS (ARARs) Section 12l(d) of CERCLA, as amended by SARA, requires that remedial actions comply with requirements or standards set forth under Federal and State environmental laws. The requirements that must be complied with are those that are applicable or relevant and appropriate to the ( 1) potential remedial actions, (2) location, and ( 3) media-specific chemicals at the Site. This Section examines the cleanup criteria associated with the contaminants found and the environmental media contaminated. A. Action-Specific ARARs Action-specific requirements set controls or restrictions on the design, performance, and other aspects of implementation of specific remedial activities. Potential action-specific ARARs are shown in Table 7-1. B. Location-Specific ARARs Location-specific ARARs must consider Federal, State, and local requirements that reflect the physiographical and environmental characteristics of the Site or the immediate area. Remedial actions may be restricted or precluded depending on the location characteristics of the site and the resulting requirement. A listing of potential location-specific ARARs is given in Table 7-2. Federal classification guidelines for groundwater are as follows: * Class I: Groundwater that is irreplaceable with no alternative source or is ecologically vital; * Class II: A -Groundwater currently used for drinking water; B -Groundwater potentially available for drinking water; * Class III: Groundwater not considered a potential source of drinking water due to natural contamination or insufficient yield. The uppermost aquifer at the Site is considered Class IIB and the second uppermost aquifer is considered Class IIA. State classification guidelines are based on best usage (NCAC 2L.0201). The uppermost and second uppermost aquifers are therefore considered . Class GA groundwater under the State system. 7-1 -a1i ---1!1!!!1 11111 ml a; 1iii11ii1 lilliil -I!!!!! 1!!11111;1 =:I r:ail liiiiil liiii - .. STANDARD, RBQUTRBMEN'l', CRITERIA, OR LIMITATION RCRA, AS AMENDED Identification of Hazardous Waste Treatment· of Hazardous Wastes in a Unit Requirements for Generation, Storage, Transportation, and Disposal of Hazardous Waste Land Disposal Ban and Restrictions TABLE 7-1 POTENTIAL ACTION-SPECIFIC ARARS SOILS AND GROUNDWATER CITATION DESCRIPTION 40 use Sect 1609 et seq 40 USC Sect 6901 et seq 40 CFR 261 Federal requirements for classification and identification of hazardous wastes 40 CFR 264.601 Rules and requirements for the 40 CFR 265.400 treatment of hazardous wastes 40 CFR 263 Regulates storage, transportation, 40 CFR 264 and operation of hazardous waste generators. 40 CFR 268.10-12 Disposal of contaminated soil and 40 CFR 268 (Subpart D) debris resulting from CERCLA response actions are subject to federal and disposal prohibitions. Establishes treatment standards for hazardous wastes. 7-2 TABLE 7 -1 (CONT) STANDARD, REQUIREMENT, CITATION DESCRIPTION CRITERIA,. ORJ,IMITATION CLEAN WATER ACT (CWA) 33 USC Sect 1251-1376 Requires Use of Best 40 CFR 122 Use of best available technology Available Treatment economically achievable is Technology (BACT) required to control discharge of toxic pollutants to POTW National Pollutant Discharge 40 CFR 122 Subpart C Use of best available technology Elimination System Permit economically achievable for toxic Regulations pollutants discharged to a POTW. Discharge must be Consistent 40 CFR 122 Discharge must comply with EPA- with the Requirements of a approved Water Quality Management Water Quality Management Plan. Plan Approved by EPA Superfund Amendments and 42 USC Sect 9601 et Discharge must comply with Federal Reauthorization Act (SARA) seq Water Quality Criteria Discharge must not increase Section 121 Selected remedial action must contaminant concentrations (d) (2) (B) (ii) establish a standard of control to in offsite surface water maintain surface water qua·lity. 7-3 TABLE 7-1 (CONT) STANDARD, REQOI~;··· CITATION DESCRIPTION CRITERIA, OR LIMITATION CLEAN AIR ACT Air Use Approval 40 CFR 60 (Subpart A) Requires notification and performance testing by owner or operator. Particulate Discharge 40 CFR 60 (Subpart B) Defines limitations for Limitations and Performance · particulate emissions, test Testing methods, and monitoring requirements for incinerators SAFE DRINKING WATER ACT Maximum Contaminant Level 40 CFR 142 EPA has also established Maximum Goals 50 FR 46936 Contaminant Level Goals (MCLGs). (November 13, 1985) The nonenforceable standards are based on health criteria. The MCLGs are goals for the nation's water supply. Primary Maximum Contaminant 40 CFR 142 Primary MCL are adopted for the Levels protection of human health but include an analysis of feasibility and cost of attainment. 7-4 ---._ 1!111 1B1!1 _. ,_ 11111 a; liail liliil -l!l!I 1!!!!!1 ==i m= r:;;;; liiiliiil TABLE 7-1 (CONT) :-: .. · ;-····,•,•,:'·_ STANDARD, REQUJ:REMENT, CITATION DESCRIPTION CRITERIA, OR.LIMITATION STATE North Carolina Water Quality NCAC-15A-2B Surface Water quality standards Standards North Carol1na Groundwater NCAC-15A-2L Groundwater quality standards, Standards regulates injection wells Wastewater Discharge to NCAC-15A-2H Regulates surface water discharge Surface Waters and discharges to POTW. North Carolina Hazardous NCAC-15A-13A Siting and design requirements for Waste Management Rules hazardous waste TSDs. North Carolina Sedimentation NCAC-15A-4 Requirements for prevention of Control Rules sedimentation pollution. North Carolina Air Pollution NCAC-15A-2D Air pollution control air quality Control Requirements and emissions standards. 7-5 TABLE 7-2 POTENTIAL LOCATION-SPECIFIC ARARS I SITE FEATURE/LOCATION_ I CITATION I DESCRIPTION I Within 61 meters (200 ft) of a 40 CFR 264 .18 (a) New treatment, storage, or ' fault displaced in Holocene disposal of hazardous waste time prohibited; applies to RCRA hazardous waste, treatment, storage, or disposal. Within 100-year floodplain 40 CFR 264.18 (b) Facility must be designed, constructed, operated, and maintained to avoid washout: applies to RCRA hazardous waste treatment, storage or disposal. Within floodplain Protection of floodplains ( 40 Action to avoid adverse CFR 6, Appendix A) ; Fish and effects, minimize potential Wildlife Coordination Act (16 harm, restore and preserve USC 661 ·et seg): 40 CFR 6.302; natural and beneficial values; Floodplains Executive Order (EO applies to action that will 11988) occur in a floodplain, i.e., lowlands, and relatively flat areas adjoining inland and coastal waters and other flood prone areas. Within area where action may National Historical Requires that action be taken -cause irreparable harm loss or Preservation Act (16 USC to recover and preserve destruction of significant Section 469) ; 36 CFR Part 65 artifacts when alteration of artifacts terrain threatens significant scientific, prehistorical, historical, or archaeological data. 7-6 I SITE FEATURE/LOCATION • I Critical habitat upon which endangered species or threatened species depends Wetlands Wetlands TABLE 7-2 (CONT) POTENTIAL LOCATION-SPECIFIC ARARS CITATION Endangered Species Act of 1973 (16 use 1531 et seg) : 50 CFR Part 200, 50 CFR Part 402: Fish and Wildlife Coordination Act (16 USC 661 et seg); 33 CFR Parts 320-330 Clean Water Act Section 404; 40 CFR Part 230, 33 CFR Parts 320- 330. 40 CFR-Part 6, Appendix A 7-7 I DESCRIPTION I ' If endangered or threatened species are present, action must be taken to conserve endangered or threatended species, including consultation with the Dept of Interior. For wetlands as defined by US Army Corps of Engineers regulations, must take action to prohibit discharge of dredged or fill material into wetlands without permit. For action involving construction of facilities or management of property in wetlands, action must be taken to avoid adverse effects, minimize potential harm and perserve and enhance wetlands to the extent possible. I SITE FEATURE/LOCATION Wilderness Area Within area affecting national wild, scenic or recreational rivers Classification and potential use of an aquifer Construction within State highway system right-of-way. Construction within a railroad right-of-way ----------I!!!!! 111!!!!!!1 l!!l!!1 I!!!!!!! TABLE 7-2 (CONT) POTENTIAL LOCATION-SPECIFIC ARARS I CITATION I DESCRIPTION Wilderness Act (16 use For federally-owned area designated as wilderness 1131 et seg:); 50 CFR area, the area must be administered in such 35.1 et seg:. manner as will leave it unimpaired as wilderness and to preserve its wilderness. Wild and Scenic Rivers For activities that affect any of the rivers Act (16 use 1271 et specified in section 1271 (a); must avoid taking seg:) :section 7 (a) ; 40 or assisting in action that will have direct CFR 6.302(e) adverse effect on scenic river. Guidelines for GW Consider Federal and State aquifer Classification, EPA GW classifications in the assessment of remedial Protection Strategy response objectives. and NCAC-15A NCAC, Subchapter 2E, Written permission from the NC DOT is required Section .0420, for construction on state highway right-of-ways. Construction Within Right of Way Federal Railroad Permission from the Railroad prior to Administrative, Tel. construction withing their right-of way. Conversation 9/4/91. 7-8 I I D I I I I I I I I I I I I I I I I c. Chemical-Specific ARARs Chemical-specific ARARs are concentration limits in the environment promulgated by government agencies. Health-based site-specific levels must be developed for chemicals or media where such limits do not exist and there is a concern with their potential health or environmental impacts. Potential chemical-specific ARARs are shown in Table 7-3 and are discussed by media below. Groundwater Groundwater ARARs will be evaluated with respect to the uppermost and second uppermost aquifers at the · Site. Potential ARARs for groundwater include Maximum Contaminant Levels (MCLs), North Carolina Drinking Water Standards, and North Carolina Groundwater Standards. Maximum Contaminant Levels (MCLs) The National Oil and Hazardous Substances Pollution Contingency Plan (NCP) states that MCLs, established under the Safe Drinking Water Act (SOWA), are potentially relevant and appropriate groundwater standards for groundwater that is a current or potential source of drinking water (40 CFR S300.430 (e)(2)(i){A)). The groundwater in the uppermost aquifer is a potential source of drinking water and the groundwater in the second uppermost aquifer is a current source of drinking water, therefore, MCLs will be considered the primary remediation goal. MCLs and proposed MCLs are provided in Table 7-4. In addition, the table presents the maximum groundwater concentration for a particular chemical and its associated sampling location as determined by the RI. North Carolina Drinking Water and Groundwater Standards North Carolina drinking water standards are essentially identical to the SOWA MCLs established by the EPA (Table 7-4). North Carolina Groundwater Standards (North Carolina Administrative Code (NCAC) Title 15A, Chapter 2, Subchapter 2L) are for Class GA groundwater, best usage as a source of drinking water. As seen in Table 7-4, the North Carolina Groundwater Standards for gamma-BHC and toxaphene are below the CERCLA Contract Required Quantitation Limit ( CRQL). The CRQL is the chemical-specific level that a·laboratory must be able to routinely and reliably detect and quantitate in a specified sample. In such cases, the North Carolina Groundwater Standard defers to the quantitation limit as the maximum allowable concentration ( 15 NCAC 2L Section .0202(b)). In addition to the listed standards, Section .0202(c) specifies that substances which are not naturally occurring and for which no standard is specified shall not be permitted in detectable concentrations. Therefore, since pesticides are considered man-made and not naturally occurring, the North Carolina Groundwater Standard is the quantitation limit. 7-9 l!!!!l!I I!!!!!! !!!!I I!!!!! TABLE 7-3 POTENTIAL CHEMICAL-SPECIFIC ARARS . STANDARD, REQUIREMENT, CITATION DESCRIPTION CRITERIA, OR LIMITATION. Safe Drinking water Act 40 use Sect 300 National Primary Drinking 40 CFR Part 141 Established health-based standards Water Standards for public water systems (MCLs) National Secondary Drinking 40 CFR Part 143 Establishes welfare-based Water Standards standards for public water systems (secondary MCLs) Maximum Contaminant Level Pub.L No 99-399,100 Establishes drinking water quality Goals Stat. 642 (1986) goals set at levels of no known or anticipated adverse health effect. Clean Water Act 33 use sect 1251-1376 Water Quality Criteria 40 CFR Part 131 Sets criteria for water quality based on toxicity to aquatic organisms and human health. RCRA, as amended 42 use 6905, 6912, 6924, 6925 RCRA Groundwater Protection 40 CFR Part 264 Provides for gw protection standards, general monitoring requirements and technical requirements. Dept of Transportation 49 use 1801 Regulates off-site transportation Hazardous Materials of specific hazardous chemicals Transportation Act and wastes. 7-10 !II!! 1B! al 111111 -1111111 m:; 1111!1 al lillil ;aa liilE liill .. --!!!!!!!!I l!!!!!l!!!I I!!!!!!! . ··.·•,.· ,.·. ·':'• . STANDARD, REQUTRBMBNT; CRJ:TERIA, OR LIMITATION. RCRA SWMU Requirements Solid Waste Disposal Act Land Disposal CERCLA Clean Air Act National Primary and Secondary Ambient Air Quality Standards Occupational Safety and Health Administration National Emissions Standards for Hazardous Air Pollutants TABLE 7-3 (CONT) POTENTIAL CHEMICAL-SPECIFIC ARARS ·CITATION DESCRIPTION . 40 CFR Part 254.3-4 Provides for protection of gw at solid waste management unit. 42 USC 6901 et seq 40 CFR Part 268 Established a timetable for restriction of land disposal of hazardous waste. 42 USC 9601 et seq. Provides for response to hazardous substances released into the environment and the cleanup of inactive hazardous waste disposal sites. 40 USC 1857 40 CFR Part 50 Sets primary and secondary air standards at levels to protect public health and welfare. 29 CFR 1910 Part Provides safety rules for handling 120 specific chemicals for site workers during remedial activities. 40 CFR Part 61 Provides emissions standard for hazardous air pollutants for which no ambient air quality standard exists. 7-11 11111 ma 1111111 11111 lliiil a.a aa llliil liliiiil ----illii . ··. .-:-· STANDARD, REQUJ"R~; > ·.·. CRITERIA, OR LIMITATION • STATE NC Water Quality Control Standards NC Drinking Water Act NC Drinking Water and Groundwater Standards NC Solid and Hazardous waste Management Act NC Comprehensive Environmental Response Act TABLE 7-3 (CONT) POTENTIAL CHEMICAL-SPECIFIC AR.ARS .. . CITATION DESCRIPTION 15A NCAC 2B Establishes water quality requirements applicable to all surface waters of NC which protect publich health and the environment. 130A NCAC 311-327 Regulates water systems within the State which supply drinking water that may affect the public health. 15A NCAC Chapter 2L Establishes groundwater classification and water quality standards. 130 A NCAC 130A 310.1-310.23 7-12 - I I I I I I I I PESTICIDE ALDRIN ALPHA-BHC BETA-BHC DELTA-BHC GAMMA-BHC DIELDRIN ENDRIN KETONE TOXAPHENE TRICHLOROETHENE MAX.GW CONC. 0.1 36 25 29 30 2 4 10 200 TABLE 7-4 GROUNDWATER ARARs SDWA NORTH MCL CAROLINA DWS NA NA NA NA NA NA NA NA 0.2 0.2 NA NA NA NA 3 3 5 5 NORTH CAROLINA GWQS NA NA NA NA 0.0265 NA NA 0.031 2.8 I Concentrations are given in ug/1 SDWA MCL -Safe Drinking Water Act Maximum Contaminant Level. North Carolina DWS -NC Drinking Water Standards I North Carolina GWQS -NC Groundwater Quality Standards CRQL -Contract Required Quanititation Limit CERCLA CRQL 0.05 0.05 0.05 0.05 0.05 0.1 0.1 1. 0 1.0 I MCL for Gamma-BHC currently is 4 ug/1, New MCL (0.2) effective July 30, 1992 I I I I I I NA -Not Available 7-13 I I I I I I I I I I I I I I I I I I I Groundwater remediation levels are provided in Table 7-5. Soils There are no promulgated Federal or State standards applicable for contaminants in soils at the Site. 7-14 D R m I I m I I I I I I I I I I I I I TABLE 7-5 GROUNDWATER REMEDIATION LEVELS MAXIMUM GW GROUNDWATER CORRESPONDING BASIS OF PESTICIDE CONCENTRATION REMEDIATION RISK LEVEL GOALS (UG/L} LEVEL (UG/L} ALDRIN 0.1 0.05 5. 0 X l0E-6 CRQL ALPHA-BHC 36 0.05 1. 3 x l0E-6 CRQL BETA-BHC 25 0.05 4.0 X l0E-7 CRQL DELTA-BHC 29 0.05 ND CRQL GAMMA-BHC 30 0.05 3.0 x l0E-7 CRQL DIELDRIN 2 0.1 8.3 X l0E-6 CRQL ENDRIN KETONE 4 0.1 ND CRQL TOXAPHENE 10 1.0 6.7 x l0E-6 CRQL TRICHLOROETHENE 200 2.8 1.0 X l0E-6 NCGWQS CRQL -Contract Required Quanititation Limit NCGWQS North Carolina Groundwater Quality Standards ND -Not Determined, Toxicity data unavailable, risk levels could not be calculated. 7-15 D I I I u u I I I I I I I I I I VIII. DESCRIPTION OF ALTERNATIVES Tables 8-1 and 8-2 summarize the technologies considered for remediating the groundwater and soil contamination, respectively, at the Geigy Site. These tables also provide the rationale as to why certain technologies were not retained for further consideration after the initial screening. A. Remedial Alternatives to Address Groundwater Contamination The following alternatives were developed to address groundwater contamination at the site: Alternative lA: No Action Alternative 1B: Long-term Monitoring of Site Groundwater Alternative 2: Slurry Wall and Cap Alternative 3: Groundwater Pump and Treat to Attain Remediation Levels The remedial response actions to address groundwater contamination are discussed below. Alternative lA: No Action No activities would be conducted on Site groundwater under this alternative. Existing monitoring wells would be retained as is for potential use, although no groundwater monitoring is included under this alternative. This alternative represents a true no action alternative. A review of remedy would be conducted every five years. This based be no alternative involves no capital costs. Operating costs are on the review of Site conditions every five years. There would maintenance costs. Total Construction Costs - Present Worth O & M Costs Total Present Worth Costs - $ 0 $140,000 $140,000 Alternative 1B: Long-term Moµitoring of Groundwater This alternative involves long-term monitoring of groundwater. Four additional monitoring wells would be constructed in the second uppermost aquifer. Sampling would be twice a year with analyses for pesticides in the uppermost aquifer and pesticides and TCE in the 8-1 TABLE 8-1 I GROUNDWATER REMEDIATION TECHNOLOGIES CONSIDERED I I I I I I TECHNOLOGY GROUNDWATER RECOVERY Extraction Well Interception Trenches/ Subsurface Drains No Action GROUNDWATER TREATMENT Air Stripping Activated Carbon Adsorption Sorptive Resins Chemical Oxidation (UV-Ozone) Biological Treatment Land Treatment I GROUNDWATER DISCHARGE I I Horizontal Infiltration Gallery Injection Wells Surface Water Discharge POTW I GROUNDWATER CONTAINMENT I I I I I Slurry Wall, Capping and Well Point Extraction STATUS 8-2 Retained Retained Retained Rejected Retained Rejected Retained Rejected Rejected Retained. Rejected Rejected Retained Retained REASON Effectiveness Effectiveness/ Reliability Effectiveness Effectiveness Provisionally Depending on Application Rates Not permittable Not cost effective I I TABLE 8-2 I SOIL REMEDIATION TECHNOLOGIES CONSIDERED I I I I I I I I I TECHNOLOGY DIRECT TREATMENT Land Treatment Bioreactor supercritical CO2 Extraction Critical Fluid Solvent Extraction Best Process Supercritical Water Oxidation Soil Washing Stabilization/Solidification Transportable Incineration Thermal Desorption Classification IN-SITU TREATMENT Soil Vapor Extraction Enhanced Biodegradation Soil Flushing Vitrification I OFF-SITE TREATMENT I I I I I I Commercial Landfilling Commercial Incineration CONTAINMENT Capping On-Site Landfill No Action STATUS Rejected Rejected Rejected Rejected Rejected Rejected Rejected Rejected Retained Retained Retained Rejected Rejected Rejected Rejected Retained Retained Retained Re'jected Retained 8-3 REASON/NOTES Effectiveness Effectiveness/ Implementability Not a Demonstrated Technology Not a Demonstrated Technology Not a Demonstrated Technology Not a Demonstrated Technology Not Demonstrated Under Similar Site Conditions/Implementation Effectiveness Soil Only Soil Only Treatability Testing Required Effectiveness Effectiveness Effectiveness Not Fully Developed Soil and Foundation Debris Soil Only Soil and Foundation Debris Implementation Soil and Foundation Debris I D D I I I I I I I I I I I I I I second uppermost aquifer. Deed restrictions on future uses of the property would also be included. Since wastes would remain at the Site, a review of this alternative would be conducted every five years as required by SARA. Capital costs include the construction of four additional monitoring wells. Operating costs include periodic sampling of selected monitoring wells, chemical analyses, reporting and review of the Site conditions every five years. Monitoring costs are based on a period of 30 years. Maintenance costs would include inspection of the monitoring wells. Total Construction Costs Present Worth O & M Costs Total Present Worth Costs - Alternative 2 -Slurry Wall and Cap .$ 130,000 $1,500,000 $1,630,000 This alternative would involve construction of an interconnected slurry wall and cap system to contain Site groundwater. The slurry wall would be keyed into the uppermost aquitard. The cap would prevent infiltration from entering the slurry wall enclosure and creating an outward hydraulic gradient. Extraction wells would be located outside of the slurry wall in the uppermost and second uppermost aquifer. Slurry wall construction would involve excavating a trench under slurry to depths ranging from 45 to 70 feet. Excavations to these depths approaches the limits of technical feasibility and wculd require special excavation equipment with extended reach capability. Permeability of the slurry wall would be lE-07 cm/sec. The slurry wall could be constructed using the. hie-polymer method, however, actual construction methods would be determined during the Remedial Design. The length of the circumferential slurry wall would be approximately 40 to 70 feet. Width of the slurry wall would be approximately three feet. A low permeability cap would be constructed above the perimeter of the slurry wall· to minimize infiltration within the slurry wall. The cap would consist of a compacted sub-base of common and select fill, 60-mil HDPE liner, drainage net, filter fabric, soil cover and vegrjation. Permeability of the cap would be approximately 1 x 10-cm/s. The area of the cap would be approximately 3 acres. The cap would be tied into the slurry wall to form an integral unit. Drainage swales would be constructed along the cap perimeter to control surface run-on and direct cap run-off. A security fence would be constructed along the perimeter of the cap to deter unauthorized access. 8-4 D I I I I I I I I I I I I I I I B I I Groundwater recovery within the slurry wall would be accomplished using well point extraction. Groundwater recovery would be necessary to maintain a hydraulic differential across the slurry wall which would restrict groundwater migration outward from the slurry wall. The slurry wall would have no effect upon groundwater in the second uppermost aquifer. Groundwater recovery would be implemented outside of the cap/slurry wall system for groundwater exceeding the remediation levels using groundwater extraction. One recovery well would be placed in the uppermost aquifer and two recovery wells would be placed in the second uppermost aquifer. Treatment of contaminants would be by carbon adsorption. Disposal options for the treated groundwater are the POTW and an on-site infiltration gallery. Actual disposal requirements would be determined during the RD. Since compound residuals would remain, review of the effectiveness and protectiveness of this alternative every five years would be required by SARA. Total Construction Costs Present Worth O & M Costs Total Present Worth Costs - $ 8,400,000 S 1.800,000 $10,200,000 Alternative 3 -Groundwater Recovery to Attain Remediation Levels This alternative involves the recovery of groundwater such that the remediation levels would be attained. Contamination would be removed through extraction wells placed in the uppermost and second uppermost aquifers and reduced through treatment by activated carbon. Discharge of the treated water would be either to the Moore Cocnty POTW or to an on-site infiltration gallery. The proposed extraction system would approximately nine recovery wells; seven two in the second uppermost aquifer. involve the installation of in the uppermost aquifer and Carbon adsorption is considered to be the best available technology for the removal of pesticides from water. The treatment system would involve two carbon adsorption canisters in series, to maximize carbon usage and provide protection against breakthrough. A standard canister would be expected to last approximately two years. Spent carbon would only be sent to a RCRA TSD facility in full compliance with its Part B permit, in accordance with EPA's off-site policy. Discharge of the treated groundwater would be to the Moore County POTW or to an on-site infiltration gallery. Discharge to the POTW would require construction of a force main to the nearest manhole, approximately 1/2 mile away. Construction requirements for an infilt~tion gallery are based on a nominal application rate of 0.5 gpd/ft . The actual method of discharge and operating parameters would be established during RD. 8-5 I I I I I I I I I I I I I • I I Further characterization will be conducted in the second uppermost aquifer to determine the extent of pesticide contamination and to attempt to determine the source and extent of TCE contamination. If the source of the TCE cannot be determined, it will be assumed that the TCE is site-related. This characterization will be conducted during the pre-design activities associated with groundwater remediation. To achieve this, the installation of four additional groundwater monitoring wells in the second uppermost aquifer is included in the cost estimate. Actual requirements would be established during the RD. Costs for this alternative are based on discharge to the POTW, would have both higher construction and operating costs discharge to an infiltration gallery. Costs are based remediation period of thirty years. Total Construction Costs Present Worth O & M Costs Total Present Worth Costs - $ 710,000 $1.500,000 $2,210,000 B. Remedial Alternatives to Address Soil Remediation The response actions to address soil remediation are: Alternative 1 -No Action Alternative 2 -Off-Site Disposal Alternative 3 -Capping Alternative 4 -On-Site Thermal Desorption Alternative 5 -On-Site Incineration Each of the soil remediation alternatives is described below. Alternative 1 -No Action which than on a In this alternative, no soil remedial activities would occur. There are no construction costs. Operating costs would involve a review of the remedy every five years. Total Construction Costs Present Worth O & M Costs Total Present Worth Costs - 8-6 $ 0 $140,000 $140,000 I I B H I I I I I I I I I I I I _I Alternative 2 -Off-Site Disposal This alternative would involve the excavation and off-site disposal of the top foot of soils exceeding the remediation levels. Soils would be taken to either a secure landfill or a fixed-based incinerator, depending on their regulatory disposition. Composite samples would be collected from stockpiles and analyzed by the TCLP. The entire stockpile would then be disposed according to its composite TCLP analysis. Soils failing the toxicity characteristic leaching procedure (TCLP) test would be considered hazardous by characteristic and incinerated to satisfy land disposal restrictions (LOR). Soils passing the TCLP would be sent to a RCRA-approved landfill. Confirmation sampling would be conducted to ensure that remediation levels are attained. Excavated areas would then be covered with clean fill and vegetated with a perennial grass. This• alternative would also involve the demolition of the building foundation. Concrete debris should be · acceptable for disposal at a municipal landfill. Actual disposal requirements would be determined during Remedial Design following confirmation testing. Implementation time would depend on the number of crews involved but should be approximately three months. Construction costs associated with this alternative include mobilization, excavation, earth work, disposal (landfill and/or incineration), material and labor. There would be no operating costs. To provide the greatest allowance for potential remediation costs, it was assumed that all soils (approximately 1000 cubic ya:!:ds) went either to a secure landfill (lowest cost) or to an incinerator (highest cost). The greatest likelihood is tli.at a portion of the soils would fail TCLP and be sent · to an incinerator while the remainder would be sent to a secure landfill. By presenting the costs of both extremes, the actual remedial costs would likely fall somewhere in the range. Demolition of the building foundation and disposal at a municipal landfill is included within both ends of the estimate. Total Construction Costs Present Worth O & M Costs Total Present Worth Costs Landfilling $600,000 0 $600,000 Alternative 3 -Cappingr----- Incineration $2,440,000 0 $2,440,000 This alternative involves construction and, operation of an engineered cover to deny human access to those Site soils exceeding the remediation levels. The cap would be constructed of a non-woven 8-7 I I I g I R I I I I I I I I I I I I I polypropylene geomembrane impregnated and sealed with an asphalt overlay. This design would have long-term durability with a minimal amount of maintenance. Drainage swales would be constructed along the cap perimeter to control surface run-on and direct cap run-off. A security fence would be constructed along the perimeter of the cap to deter unauthorized access. Deed restrictions would be included in the implementation of this alternative as a secondary control measure to prevent uses of the Site that could reduce the effectiveness of the remedial measures. Periodic inspections would be required to check for erosion, settling, and conditions of the drainage system. An established inspection and maintenance schedule would be implemented following construction and continued for as long as chemical residuals remained at the Site. Demolition of the building foundation would be required under this alternative to gain access to some of the underlying soils. Disposal of the foundation debris would be at a municipal landfill. Implementation time would depend on the number of crews involved but should be approximately two months. Construction costs associated with this alternative include mobilization, excavation, grading, earth work, materials, labor, demolition and disposal. Operating costs include maintenance of the cap and review of the Site remedy every five years. Maintenance costs include periodic inspections and grounds keeping. Total Construction Costs -Present Worth O & M Costs Total Present Worth Costs - $ 95,000 -$180,000 $275,000 Alternative 4 -On-Site Thermal Desorption In this alternative, soils exceeding the remediation levels would be excavated and treated utilizing low temperature thermal technology. The treated soil will be returned to its original location. The low temperature thermal treatment will volatilize the organic contaminants at a temperature generally less than 1000 degrees F. The off-gases will be captured and treated to prevent the release of contaminants into the environment. Treatment of the soils will continue until remediation levels are attained and the soil can pass the TCLP test for toxaphene and gamma-BHC. Demoltion and disposal of the building foundation would be required to gain access to underlying soils. The treatment selected to treat Off-gases will vary with the vendor selected, but will normally consists of one of the following systems: (1) thermal oxidation in a secondary thermal oxidation chamber similar to incinerators; or ( 2) condensing and concentrating the organics into a significantly smaller mass for further 8-8 I g I 0 D D I I I I I I treatment (incineration); or (3) passing the off-gases through activated carbon to adsorb in the contaminants and then regenerating the carbon. For cost estimation purposes, the last treatment option (carbon adsorption) was used. The volume of contaminated soil is below what the Agency feels is a sufficient amount of contaminated soil to attract the interest of qualified vendors to implement an on-site remedy. However, to provide a cost comparison with the other alternatives the following assumptions were made and a probable cost derived. The estimated amount of soil to be treated is low (approximately 1,000 cubic yards), the treatment unit utilized would probably be small; the magnitude of a pilot-scale operation. Assuming a process rate of 2.5 tons per hour, the actual treatment time is estimated to be approximately one month. The planning, materials screening and handling will require a approximately four to six additional months. This alternative may also require implementation of a treatability study, which would add an additional twelve months to the estimated time to implement this alternative. Implementation time for this alternative will be approximately two years, with a total cost as shown below. Total Construction Costs - Present Worth O & M Costs Total Present Worth Costs- Alternative 5 -On-Site Incineration $700,000 $700,000 0 Incineration is a thermal treatment technology which util.i.zes elevated temperatures to destroy or detoxify hazardous waste. Under this alternative, contaminated soil and debris would be incinerated on-site. Residual ash from the incinerator would be redeposited on-site and covered with clean fill. The ash would have to pass the TCLP before depositing to ensure that the ash is non-hazardous. Incineration is considered the Best Demonstrated Available Technology (BOAT) for halogenated organic compounds, which includes most of the pesticides found at the Site. The contaminated soil will be excavated, homogenized and sized, incinerated, tested, and disposed back on-site. Any process wastewater or scrubber blowdown sludge will be treated by reinjection into the incinerator. The incinerator and air pollution control unit will be operated so that: An operating temperature in the kiln of 1,800 degrees F is maintained at all times to ensure that any volatile and 8-9 I n 0 R I I I I I I I I I I I I I I I I semi-volatile organic constituents in the waste stream are driven out of the ash and that the fixed carbon remaining in the ash is minimized; An operating temperature in the afterburner of 2,000 degrees Fis maintained at all times to oxidize and destroy all remaining organic substances prior to exiting the afterburner and entering the pollution control system; The incinerator must achieve a destruction and removal efficiency (DRE) of 99.99% for all designated principal organic hazardous constituents (POHC); and The air pollution control system will achieve performance standards of ( 1) hydrogen chloride of less than 4 lb/h~ and ( 2) particulate matter of less than 0.08 grains per day ft in the exhaust gas corrected oxygen content. Because this is considered an "on-site" CERCLA response action, no state, local, or federal permits are necessary. Operation of the incineration unit will be in compliance with RCRA regulations. Demolition and disposal of the building foundation would be required to gain access to underlying soils. On-site incineration is similar to on-site thermal desorption with regard to practicality of implementation for such a small amount of soil. For those reasons on-site incineration is not considered a viable alternative. For sake of cost comparison, several assumptions were made and a relative cost was derived for this option, whicl'. is shown below. Total Constructon Cost -$1,327,100 Present Worth O & M Cost -0 Total Present Worth Cost -$1,327,100 8-10 D I I I I I I I I I I I I I I I I IX. SUMMARY OF COMPARATIVE ANALYSIS OF ALTERNATIVES The remedial alternatives to address groundwater and soil contamination were evaluated using the nine evaluation criteria as set forth in the NCP, 40 CFR §300.430 (e)(9). A brief description of each of the nine evaluation criteria is provided below. THRESHOLD CRITERIA 1. 2. Overall Protection of Human Health and the Environment addresses how an alternative as a whole will protect human health and the environment. This includes an assessment of how the public health and the environment risks are properly eliminated, reduced, or controlled through treatment, engineering controls, or controls placed on the property to restrict access and (future) development. Deed restrictions are examples of controls to restrict development. Compliance with Applicable or Relevant and Appropriate Requirements /ARARs) addresses whether or not a remedy complies with all state and federal environmental and public health laws and requirements that apply or are relevant and appropriate to the conditions and cleanup options at a specific site. If an ARAR cannot be met, the analysis of the alternative must provide the grounds for invoking a statutory waiver. PRIMARY BALANCING CRITERIA 3. Long-term Effectiveness and · Permanence refers to the ability of an alternative to maintain reliable protection of human health and the environment over time once the cleanup goals have been met. 4. 5. Reduction of Toxicity. Mobility, or Volume are the three principal measures of the overall performance of an alternative. The 1986 amendments to the Superfund statute emphasize that, whenever possible, EPA should select a remedy that uses a treatment process to permanently reduce the level of toxicity of contaminants at the site; the spread of contaminants away from the source of contaminants; and the volume, or amount, of contamination at the site. Short-term Effectiveness refers to the likelihood of adverse impacts on human health or the environment that may be posed during the construction and implementation of an alternative until cleanup goals are achieved. 9-1 I I I I I I I R I I I I I I I I I I 6. 7. Imolementability refers to the technical and administrative feasibility of an alternative, including the availability of materials and services needed to implement the alternative. Cost includes the capital (up-front) cost of implementing an alternative, as well as the cost of operating and maintaning the alternative over the long-term, and the net present worth of both the capital and operation and maintenance costs. MODIFYING CRITERIA a. 9. State Acceptance addresses whether, based on its review of the RI/FS and Proposed Plan, the State concurs with, opposes, or has no comments on the alternative EPA is proposing as the remedy for the Site. Community Acceotance addresses whether the public concurs with EPA's proposed plan. Community acceptance of this proposed plan will be evaluated based on comments received at the public meetings and during the public comment period. These evaluation criteria relate directly to requirements in Section 121 of CERCLA 42 USC Section 9621, which determine the overall feasibility and acceptability of the remedy. Threshold criteria must be satisfied in order for a remedy to be eiligible for selection. Primary balancing criteria are used to weigh major trade-offs between remedies. State and community acceptance are modifying criteria formally taken into account after public comment is received on the proposed plan. Table 9-1 provides a summary of all the alternatives along with the 'total present worth costs. The evaluation of the potential remedial alternatives to address soil and groundwater were developed as follows. A. Ground Water Remediation The following alternatives were subjected to detailed analysis for groundwater remediation: Alternative lA: No Action Alternative 1B: Long-term Monitoring of Groundwater Alternative 2: Alternative 3: Slurry Wall and Cap Groundwater Recovery and Treatment to Attain Remediation Levels 9-2 I I I I I I I I I I I I I I I I I I I GROUNDWATER Alternative lA Alternative 1B Alternative 2 Alternative 3 SOIL Alternative 1 Alternative 2 Alternative 3 Alternative 4 Alternative 5 TABLE 9-1 REMEDIAL ALTERNATIVES SUMMARY REMEDIAL ACTION No Action Long-term Monitoring of Groundwater Slurry Wall and Cap Groundwater Extraction for Remediation Levels; Carbon Adsorption; Discharge to POTW No Action Off-Site Disposal Total Landfilling Total Incineration Capping On-Site Thermal Desorption On-Site Incineration 9-3 TOTAL PRESENT WORTH COSTS $140,000 $1,630,000 $10,200,000 $2,210,000 $140,000 $600,000 $2,440,000 $275,000 $700,000 $1,327,100 I I I I I I I I I I I I I I I I I I I Overall Protection of Human Health and the Environment Groundwater poses no risks to human health under current conditions. Under the future use condition the no action alternative would not address pesticide levels in groundwater and therefore would not be protective of human health. Alternative 2 would attain the remediation goals by containing groundwater in the uppermost aquifer and recovering groundwater in the second uppermost aquifer. Alternative 3 would attain the remediation goals by recovering groundwater in the uppermost and second uppermost aquifer. Therefore, Alternatives 2 and 3 would be protective of human health and the environment. Compliance With ARARs The no action alternative would not comply with ARARs. Alternative 2 would attain remediation levels outside of the slurry wall in the second uppermost aquifer and prevent remediation levels from being exceeded off-site in the uppermost aquifer. Alternative 3 would attain remediation levels in both aquifers. The cap in Alternative 2 would be designed to conform to RCRA performance standards. Construction of the groundwater recovery, treatment and discharge systems for Alternatives 2 and 3 would satisfy action-specific ARARs. Discharge to an on-site infiltration gallery would comply with the substantive aspects of a NC Non-Discharge Permit. Long-term Effectiveness and Permanence Pesticide levels would decrease permanently through recovery outside of the slurry wall for Alternative 2 and in both aquifers in Alternative 3. Construction of a slurry wall under Alternative 2 would be complicated by the depths to the uppermost aquitard (up to 7 0 feet). The competence of the resulting connection would be verified through hydraulic and analytical monitoring of groundwater. Carbon adsorption is considered Best Available Treatment for pesticides in groundwater. Alternative 2 would be a permanent installation that would require review and maintenance indefinitely. Alternative 3 would be discontinued once the remediation levels were achieved. Reduction of Toxicity, Mobility, and Volume Alternative 2 would reduce the mobility of pesticides in the uppermost aquifer through containment and reduce the volume of pesticides in the second uppermost aquifer through recovery. Alternative 3 would reduce the volume of pesticides in both aquifers through recovery and treatment and comply with the statutory preference for alternatives involving t.reatment. 9-4 I I I I I I I I I I I I I I I I I I I Short-term Effectiveness All of the alternatives can be implemented without significant risks to the community or on-site workers and without adverse environmental impacts. Construction schedules would be as follows: Alternative lA -None; Alternative 1B -1 month; Alternative 2 - 8 months; and Alternative 3 -3 months. Construction of Alternative 2 could not proceed until the rail line was rerouted, a potentially· significant obstacle on an institutional basis. Implementability Alternatives lA, 1B, and 3 would not pose significant concerns regarding implementation. Construction Alternative 2 would approach the limits of to the required depths (up to 70 feet). system for Alternatives 2 and 3 could discharge requirements were defined. Cost of the slurry wall for technical feasibility due Design of the treatment not be conducted until Total present worth costs for the groundwater alternatives are presented in Table 29. B. Soil Remediation The following alternatives were developed for Site soils and were subjected to detailed analysis: Alternative 1: No Action Alternative 2: Off-Site Disposal Alternative 3: Capping Alternative 4: On-Site Thermal Desorption Alternative 5: On-Site Incineration A summary of the evaluation of these alternatives is presented below. Overall Protection of Human Health and the Environment Potential risks due to Site soils under current and potential future conditions (residential scenario) are within the acceptable range of risk specified by the National Contingency Plan (NCP). 9-5 I I I I I I I I I I I I I I I I I Compliance with ARARs There are no Federal or State ARARs for pesticides in soils. Alternative 2 would comply with EPA's off-site policy and applicable land disposal restrictions. Alternative 3, consolidation of Site soils and capping in place would not trigger any RCRA requirements. Alternatives 4 and 5 would comply with all applicable ARARs, including LDRs. Long-term Effectiveness and Permanence· Alternative 1 would not be effective in reducing contaminant levels. Alternatives 2 and 4 would result in a permanent reduction in Site risks. Alternative 3 could be effective in the long term through regular maintenance of the cap, but a review of remedy would be required every five years since a cap is not considered a permanent remedy. Alternatives 4 and 5 would maintain reliable protection of human health and the environment over time once the remediation levles were achieved. Reduction of Toxicity. Mobility, and Volume Pesticide levels would remain unchanged for Alternative 1. Alternatives 2, 4 and 5 would reduce pesticide levels significantly. Alternative 3 would not reduce the volume, but would reduce the mobility and effective toxicity of the pesticides. §.b,ort-term Effectiveness All of the alternatives can be implemented without significant r::.sks to on-site workers or the community and without adverse environmental impacts. Implementability No implementation is needed for the no action alternative. Off-site disposal to a RCRA-approved landfill and incinerator have been conducted successfully in the past at the Geigy Site. Construction of the cap would pose no significant difficulties. Alternatives 4 and 5 are implementable, however the low volume of contaminated soils requiring remediation renders these alternatives impractical at this site. Total present worth costs foi:: the soil remediation alternatives are presented in Table 9-1. C. Modifying Criteria State and community acceptance are modifying criteria that shall be considered in selecting the remedial action. 9-6 I D m I I I I I I I I I I I R I I I I State Acceptance The State of North Carolina concurs with the selected remedy. Community Acceptance A proposed plan fact sheet was released to the public on March 26, 1992. The proposed plan public meeting was held on March 31, 1992. The public comment period on the proposed plan was held from March 26, 1992 to May 25, 1992. The letters, comments, and questions asked during the March 31st meeting and received during the comment period . are summarized in the attached Responsiveness Summary. 9-7 D I I I I I I I I I I I I I • D I I I X. THE SELECTED REMEDY section 121 of CERCLA, as amended, 42 u.s.c. §9621, and the National Oil and Hazardous Substance Pollution Contingency Plan (NCP) establish a variety of requirements relating to the selection of the remedial action under CERCLA. Having applied the evaluation criteria to the groundwater and soil remediation alternatives, EPA has selected the following remedy for the Geigy Site. Groundwater Remediation Alternative 3 -Recovery and Treatment of all Site Groundwater exceeding Groundwater Remediation Levels using Carbon Adsorption Soil Remediation Alternative 2 -Off-Site ''Disposal of Soils exceeding Soil Remediation Levels A. Groundwater Remediation The treatment technology selected for remediation of the contaminated groundwater shall consist of a groundwater extraction and treatment systems. An overall monitoring program shall be developed and implemented for the Site. Groundwater contaminated above the remediation levels indicated in Table 7-2 shall be extracted across the entire Site. Extraction will continue until the remedia-::ion levels are achieved Actual design of the extraction system shall be established during the Remedial Design. For costing purposes, nine recovery wells (seven in the uppermost aquifer and two in the second uppermost aquifer) have been anticipated. Treated ground water shall be discharged to the Moore County Publicly Owned Treatment Works (POTW) or an infiltration gallery. The treated groundwater shall meet Moore County POTW preliminary discharge requirements. Discharge to the POTW will require the construction of a force ma'in to the nearest manhole, approximately 1/2 mile away. Actual discharge and operating parameters shall be established during the Remedial Design. The treatment system shall •involve at least two carbon adsorption canisters in series, to maximize carbon usage and provide protection against breakthrough. Breakthrough of the carbon will be monitored as part of the annual operation and maintenance requirements. The spent carbon shall be shipped offsite for destruction, disposal or reactivation. The most cost efficient option will be identified and selected. Actual treatment requirements shall be determined during the Remedial Design and will be dependent on the final discharge limits. 10-1 I I I I I I I I I I I I I I I I n The conceptual flow diagram for groundwater treatment is presented. in Figure 11. The groundwater treatment shall involve the follow1.ng elements: manifolding of the extraction well piping to the treatment system; concentration equalization; carbon adsorption canisters; transfer pumps; flow measurement and sampling; and discharge line to the Moore County POTW. Construction of the extraction wells including well head. equipment installation is estimated to take 1 to 1-1/2 months with minimal disruption of Highway 211 traffic. Further characterization shall be conducted in the second uppermost aquifer to determine the extent of pesticide contamination and to determine the source and extent of trichloroethene contamination. For costing purposes, the installation of four additional groundwater monitoring wells in the second uppermost aquifer have been included. Actual monitoring requirements shall be established during the Remedial Design to determine if the trichloroethene is Site-related. All site-related TCE shall be remediated through groundwater extraction and activated carbon treatment. Until it is proven otherwise TCE is considered a site related contaminant, and. shall be treated as an contaminant of concern. The goal of this remedial action is to restore groundwater to its beneficial use as a drinking water source. Based on information obtained during the RI and on a careful analysis of all remedial alternatives, EPA and the State of North Carolina believe that the selected remedy will achieve this goal. It may become apparent, during implementation or operation of the· ground water extraction system and its modifications, that contaminant levels have· ceased to decline and are remaining constant at levels higher than the remediation level over some portion of the contaminated plume. In such a case, the system performance standards and/or the remedy may be reevaluated. The selected remedy will include groundwater extraction for an estimated period of 30 years, during which time the system's performance will be carefully monitored on a regular basis and adjusted as warranted by the performance data collected during operation. 10-2 Pesticides = IO lb/yr Extraction Wells (9) Equalization Tank . - , '' ... Monitoring ► ~ -Discharge to .-.. I I -I I - ~ Moore ' '>. ' County ~ ' POT\V or Q ~ 20 gpm Carbon On-Site Adsoq~tion Infiltration Gallery Figure I I Groundwater Treatment Flow Diagram IO -3 I I I I I I I I I I I I I I I I I I Modifications may include any or all of the following: * alternating pumping· at wells to eliminate stagnation points; * pulse pumping to allow aquifer equilibration and to allow adsorbate contaminants to partition into groundwater; * installation of additional extraction wells to facilitate or accelerate remediation of the contaminant plume; and * at individual attained, and discontinued. wells where remediation levels have been after analytical confirmation, pumping may be To ensure that remediation levels continue to be maintained, the aquifer will be monitored at those wells where pumping has ceased initially every year following discontinuation of groundwater extraction. This monitoring will be incorporated into an overall Site monitoring program which will be fully delineated in the Operations and Maintenance portion of the Remedial Design. If it is determined, on the basis of the preceding criteria and the system performance data, that certain portions of the aquifer cannot be restored to their beneficial use, all of the following measures involving long-term management may occur, for an indefinite period of time, as a modification of the existing system; a) engineering controls such as physical barriers, or long-term gradient control provided by low level pumping, as containment measures; b) chemical-specific ARARs will be those portions of the aquifer impracticability of achieving further waived for the cleanup of based on the technical containment reduction; c) institutional controls will be provided and maintained to restrict access to those portions of the aquifer which remain above health-based goals, since this aquifer is classified as a potential drinking water source; d) continued monitoring of specified wells; and e) periodic re-evaluation of groundwater restoration. remedial technologies for The decision to invoke any or all of these measures may be made during a periodic review of the remedial action, which will occur at intervals of at least every five years, in accordance with CERCLA 121( c). To ensure State and public involvement in this decision at this Site, any changes from the remediation goals identified in this ROD will be formalized in either an' Explanation of Significant Difference document or an Amendment to this Record of Decision, thereby providing an opportunity for State and public comment. 10-4 I I I I I I I I I I I I I I I I I Soil Remediation The treatment technology selected for remediation of pesticide contaminated soils at the Geigy Site is off-site disposal. The top foot of soil exceeding the remediation levels in Table 6-5, shall be excavated and stock-piled on-site. Composite samples shall be collected from the stockpiles and analyzed using the toxicity characteristic leaching procedure (TCLP), and taken to either a secure landfill or a fixed-base incinerator, depending on their regulatory requirements. Soils failing the (TCLP) test shall be considered hazardous by characteristic and incinerated to satisfy land disposal restrictions (LDR). Soils passing the TCLP shall be sent to a RCRA-approved landfill. Confirmation sampling shall be conducted to ensure that remediation levels are attained. Excavated areas shall then be covered with clean fill and vegetated with a perennial grass. The building foundations shall be demolished and the concrete debris shall be disposed of at a municipal landfill. Actual disposal requirements shall be determined during Remedial Design following confirmation te'sting. The Geigy Site shall have a fence and proper warning signs posted in visible locations in order to provide site control where humans have access to the release. C. Performance Standards Performance standards are. defined as any applicable or relevant and appropriate standards/ requirements, cleanup goals and/or levels, or remediation goals and/or levels to be achieved by the remedial action. The performance levels to be attained by the Geigy remedial action are specified in the following tables: Groundwater Remediation Levels Soil Remediation Levels Table 7-5 Table 6-5 All treatment and disposal of soils shall comply with relevant and appropriate requirements (ARARs). construction and operation of the groundwater treatment be conducted in accordance with all ARARs. See Section of potential ARARs. D. Cost applicable or The design, system shall 7 for a list The total present worth cost for the entire remedial action will range between $2,810,000 and $4,650,000. 10-5 I I I I I I I I I I I I I I I I I XI. STATUTORY DETERMIBATIONS Under its legal authorities, EPA's primary responsibility at Superfund sites is to undertake remedial actions that achieve adequate protection of human health and the environment. In addition, Section 121 of CERCLA, 42 u.s.c. §9621, establishes several other statutory requirements and preferences. These specify that when complete, the selected remedial action for this site must comply with · applicable or relevant and appropriate environmental standards established under Federal and State environmental laws unless a statutory waiver is justified. The selected remedy also must be cost-effective and utilize permanent solutions and alternative treatment technologies or resource recovery technologies to the maximum extent practicable. Finally, the statute includes a preference for remedies that employ treatment that permanently and significantly reduce the volume, toxicity, or mobility of hazardous wastes as their principal element. The following sections discuss how the selected remedy meets these statutory requirements. Protection of Human Health and the Environment The selected remedy will permanently treat the groundwater and soil and remove or minimize the potential risk associated with the wastes. Dermal, ingestion, and inhalation contact with Site contaminants would be eliminated. Compliance with ARARs The selected remedy will comply with all Federal and State applicable or relevant and appropriate chemical-, location-, and action-specific requirements (ARARs). Groundwater remediation levels (Table 7-2) would be met at the Site under this alternative. Discharge of groundwater to the POTW would comply with the MCSSA sewer use ordinance. There are no Federal selected remedy will LDRs. Cost Effectiveness or State ARARs for pesticides in soils. The comply with all applicable ARARs, including The selected groundwater and soil remediation technologies are more cost-effective than the other acceptable alternatives considered. The selected remedies provide greater benefit for the cost because they permanently treat the waste. 11-1 I u m I B I I I I I I I I I I I I Utilization of Permanent Solutions and Alternative Treatment Technologies or Resource Recovery Technologies to the Maximum Extent Practicable The selected remedy represents the maximum extent to which permanent solutions and treatment can be practicably· utilized for this action. Of the alternatives that are protective of human health and the environment and comply with ARARs, EPA and the State have determined that the selected remedy provides the best balance of trade-offs in terms of long-term effectiveness and permanence; reduction in toxicity, mobility, or volume achieved through treatment; short-term effectiveness, implementability, and cost; State and community acceptance, and the statutory preference for treatment as a principal element. Preference for Treatment as a Principle Element The preference for treatment is somewhat satisfied by the use of off-site disposal which emcompasses incineration for the soils containing characteristic hazardous waste and land disposal for the residual soils at an approved RCRA landfill. Groundwater meets the treatment preference with the use of carbon adsorption to treat contaminated groundwater at the Site. The principal threats at the Site will be mitigated by use of these treatment technologies. 11-2 I D D D I w I I B I I I I I I I I I XII. Documentation of Significant Change Based on c?mments received during the comment period, the Agency no longer believes the preferred alternative presented in the proposed plan (Alternative 4 -On-Site Thermal Desorption for soil) provides the most appropriate balance among the alternatives with respect to the nine evaluation criteria. Information available to the Agency suggests that alternative 2, Off-site Disposal, presented in the proposed plan provides the best balance of trade-offs. The Agency has selected off-site disposal of the contaminated soil in conjunction with Groundwater Pump and Treat System as the final remedy. More specifically, the practicality of on-site treatment at this site has been greatly reduced. The main reason for this is the reduction of soil requiring treatment. The originally estimated amount of 2,200 cubic yards of contaminated soil has been reduced to 1,000 cubic yards. This present volume of contaminated soil is below what the Agency feels is a sufficient amount of contaminated soil to attract the interest of qualified vendors to implement an on-site remedy. The Agency's initial volume estimate of contaminated soil was the result of a conservative approach. The original estimate considered the risk to human health based on future excavation at the site that could bring contaminated subsurface soil to the surface and thereby cause adverse health or environmental effects by direct contact. Further evaluation of the data revealed that under any scenario the contamination in the subsurface soils posed no threat to human health or the environment when brought to the surface and distributed. This evaluation also revealed that excavation of surface soil to the depth of one foot would provide adequate protection of human health and the environment. This remedy is comment period the State. in accord with the concerns expressed during by the affected community, responsible parties, 12-1 the and I I I I I I I I I I · APPENDIX A I I I I I I I I I COMPOUND WSW 1S ACETONE ND 108 XYLENE ND 4J 1,2,4-ND ND TRICHLOROBENZENE 81S(2-ETHYLHEXYL) ND ND PHTHALATE TRICHLOROETHENE ND ND TABLE 1 PHASE 1 GROUNDWATER ANALYTICAL RESULTS VOLATILES AND SEMI-VOLATILES (PPB) NELL NUMBER 1D. 2S 3S 4S 4D 5S 1308 ND 1008 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 4J ND ND 7J ND ND ND ND ND ND ND 200 ND 8 -Detected in Blank at Similar Concentrations J -Quantitative Estimate ND-Not Detected A-I l!!lll!!!I 1!!!!!113 6S 6D PZ-1 ND ND ND ND ND ND 5J ND ND ND ND ND ND 11 ND --------- ·•· < COMPOUND· WSW ALPHA-BHC ND BETA-BHC ND DELTA-BHC ND GAMMA-BHC ND ALDRIN ND DIELDRIN ND ENDRIN KETONE ND TOXAPHENE ND J -QUANTITATIVE ESTIMATE ND-NOT DETECTED .. · 1S ND ND ND ND ND ND ND ND TABLE 2 PHASE 1 GROUNDWATER ANALYTICAL RESULTS PESTICIDES (PPB) WELL NUMBER lD 2S 3S 4S 4D 5S ND 3 1 1 ND 5 ND 5 0.7 3 ND 12 ND 4 0. 1 6 ND 12 ND 3 0.4 0.5 ND 5 ND ND ND 0. 1 ND 0.4J ND ND ND 0.2 ND 0.4J ND 0.4 ND 0.2 ND 0.BJ ND 10 0.BJ 5 ND ND 6S 6D PZ-1 36 ND ND 12 ND ND 29 ND ND 30 ND ND ND ND ND ND ND ND 0.6J ND ND ND ND ND ----- ·••(){ \ ' COMPOUND . •· WSW -·-1S ALUMINUM ND 172 ARSENIC NO ND BARIUM -3 .18 13.38 CADMIUM 5.4 NO CALCIUM 531 438 CHROMIUM ND 4.8 COBALT ND 18 COPPER 1180 NO IRON 4790J 955J LEAD 51B ND 'I'ABLE 3 PHASE 1 GROUNDWATER ANALYTICAL RESULTS METALS (PPB) WELL NUMBER 10 2S 3S 4S 40 5S 7620 17100 8660 1040 3650 972 2.28 NO ND ND 2.68 ND 25.88 284 78.6 13.48 22.18 15.68 ND ND ND ND 5.9 5.3 3370 37600 26500 918 4410 2650 9.5 ND 4.3 6.5 ND NO 22.7 ND ND ND ND ND ND ND 23.9 ND ND NO 4280J 84.3J 36.7J 3290J 2180J ND 10.2 1.8B 2.1B ND 9.2 ND e -Detected in Blank at Similar Concentrations J -Quantitative Estimate ND-Not Detected A-3 6S 60 PZ-1 46.3 214 2570 ND ND 2.0 156 13.28 31. OB 7.6 ND ND 49800 1010 7640 ND ND ND ND ND 25 ND ND 14.9 ND 76.9J 1750J 1.4B ND 2.08 ·,···.: -·:· :-· ·,: . . ·.-·:·:.:. COMPOUND WSW 1S MAGNESIUM 2468 4818 MANGANESE 42.2 13.3 MERCURY ND ND POTASSIUM ND 706 SELENIUM ND ND SILVER ND ND SODIUM 2010 8150 VANADIUM ND ND ZINC 936 19.7 TABLE 3 (CONT'D) PHASE 1 GROUNDWATER ANALYTICAL RESULTS METALS (PPB) .. WELL NUMBER 10 2S 3S 4S 40 5S 1540 14200 3800 745 1410 1610 91.2J 104 61. 2J 11.28 118J 16.08 ND ND ND ND ND ND 875 71400 21900 1010 ND 3200 2.2 ·1. 2 1. 2 ND 2.5 ND NO ND 10.6B ND ND ND 4620J 12000 9120J 6030J 5070J 4270J ND ND ND 38 ND ND 69.3 236 243 11. 9 37.1 43.8 B -Detected in Blank at Similar Concentrations J -Quantitative Estimate ND-Not Detected A-4 6S 60 PZ-1 18100 620 1120 44.0J 14. 7B 157J l.OJ ND NO 160000 869 881 2.4 ND 1.0 ND ND NO I2900J 2780J 13600 15.4 ND NO 579 32.4 43.9 .... ---------_ ..... _ ---11!!1 --= 111111 - .•· ·.. \ i ···· .. · .. COHPOUNI) •·. :_;;· ,-=. -.:· • <4D METHYLENE CHLORIDE ND ACETONE ND 2-BUTANONE ND 1,1,l-ND TRICHLOROETHANE TRICHLOROETHENE 160 4-METHYL-2-ND PENTANONE TOLUENE ND TABLE 4 PHASE 2 GROUNDWATER ANALYTICAL RESULTS VOLATILES (PPB) WELL NUMBER 6D 8S PZ-1 14D 15D ALLRED ND ND ND ND ND ND ND 4B 20B 19B 59B 9B ND ND ND ND ND ND ' ND ND ND ND ND ND 47 ND BJ ND ND 72 ND ND ND ND ND ND ND ND ND ND ND ND B - J - ND- Detected in Blank at Similar Concentrations Quantitative Estimate Not Detected A-5 PMP lB 21B 15 lJ 360 2 ,J 2J -------------!1!!!!1!1-- . ' . . .-. COMPOUND 7S ALPHA-BHC ND BETA-BHC ND DELTA-BHC ND GAMMA-BHC ND HEPTACHLOR EPOXIDE ND DIELDRIN ND 4,4'-DDE ND ENDRIN KETONE ND TABLE 5 PHASE 2 GROUNDWATER ANALYTICAL RESULTS PESTICIDES (PPB) WELL NUMBER es 9S l0S llD 12S 13S ND ND 2 16 ND ND ND ND 25 7 ND ND ND ND 2 4 ND ND ND ND 0.8J 11 ND ND ND ND 0.2J ND ND ND ND ND 2 0.3 ND ND ND ND 0.2J ND ND ND ND ND 4 0.4J ND ND B -Detected in Blank at Similar Concentrations J -Quantitative Estimate ND-Not Detected A-6 14D ND ND ND ND ND ND ND ND 15D USGS-02 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ....... ·.··.·~ : \ ·• COMPOUHD . . ACETONE BENZOIC ACID B -Dete TABLE 6 PHASE l SOIL ANALYTICAL RESULTS VOLATILES & SEMI-VOLATILES (PPB) k\/ ..... SOIL SAMPLE · ss.:.01 SS-03 SS-04 SS-05 188 308 18B 12B 3600J ND 200J ND A-7 SS-06 SS-09 168 68 ND 360J ··t)}/\!?c ::::":: I i.i · :-:::•:.· COMl'OUND : _::{,:/_:)\'?. •·•··)t••·asLo·1· .. : , . ALUMINUM 7650 ARSENIC 2.0J BARIUM 22.7 BERYLLIUM 0.09 CADMIUM ND CALCIUM 687 CHROMIUM 6.8 COPPER 9.9B IRON 6050 TABLE 7 PHASE 1 SOIL ANALYTICAL RESULTS METALS (PPM) SOIL SAMPLE . . ·SS-03 SS-04 SS-05 8590 9630 3580 0. 91J 2.4J ND 9.7 21. 7 5.9 ND ND ND ND ND 0.92 5540 1108 11200 9.1 5.7 2.0 6.2B 8.lB 3.3B 6870 7080 2400 B -Detected in Blank at Similar Concentrations J -Quantitative Estimate ND-Not Detected A-8 SS-06 SS-09 6950 1820 0.72J 0.84J 5.8 14. 3 0.62J ND 0.87 ND 4780 4750 3.9 2.8 6.9B 8.08 4670 2810. ··•.•</Y <:<:·: "\)J;:::<_f:;\:-_.,_,; ·_ . :' ; ,::' '. -~.' ': ••, ' COMPOUlfD t ····:_;/•:·-: ·•:?),'"<•i·· ... •···. ss-01 .. LEAD 92.4 MAGNESIUM 97.58 MANGANESE 33.9J MERCURY ND POTASSIUM 243 SELENIUM 0.388 SODIUM 24.08 VANADIUM 9.7 ZINC 46.2 PHASE SS-03 4.6 1850 II.OJ ND 327 ND 31.68 11.4 25.58 TABLE 7 (CONT'D) 1 SOIL ANALYTICAL METALS (PPM) RESULTS SOIL SAMPLE SS-04 SS-05 74.0 13.7 208 5130 13.7J 18.5J 0.188 ND 314 234 0.948 0.438 38.98 28.88 9.6 ND 38.3 52.8 B -Detected in Blank at Similar J -Quantitative Estimate Concentrations ND-Not Detected A-9 SS-06 SS-09 9.4 24.0 2330 2000 16.IJ 29J ND ND ND 221 ND 0.568 18.48 30.38 5.9 ND 78.3 70.7 ----------- TABLE 8 PHASE l SOIL ANALYTICAL RESULTS PESTICIDES (PPB) COMPO~<···· / Ii•· ···<·) .· < •· - SOIL Yss-oi . •·· .. c:. "· r • '.• SS-03 SS-04 ' . -· ·.-:, ' ALPHA-BBC ND 7500C ND BETA-BBC ND 3300C ND GAMMA-BBC ND BI0J ND ALDRIN ND I600C ND DIELDRIN ND . I300J ND 4,4'-DDE 90 4200C 770J 4,4'-DDD 24 4700C 680J 4,4'-DDT 85 20000C 3500JC TOXAPBENE 340 ND B -Detected in Blank at Similar Concentrations J -Quantitative Estimate ND-Not Detected ND SAMPLE SS-05 2200C 2900C ND ND ND 2500 II000C 25000C 120000c --- SS-06 SS-09 ND ND 4100JC ND ND ND 13000C ND 9400C ND 7900J 350 30000C 390 49000C 11100 400000C ND -------------- . -:-·.' :./ -··.::--::. COMPOUND . . . ij$;_;20 ss:,.21 · ALDRIN 5.9J ND DIELDRIN 13J ND 4,4'-DDE 58 110 4,4'-DDD 69 93 4,4'-DDT 250J 360J TOXAPHENE 1500 1800 COPPER 16.9 12.1 LEAD 207J 67. 4J ZINC 139J 169J Pesticides results given in ppb Metals results given in ppm J -Quantitative Estimate ND-Not Detected TABLE 9 PHASE 2 SOIL ANALYTICAL RESULTS .. SOIL SAMPLE SS-22 SS-23 SS-24 SS-25 SS-26 ND ND ND ND 5.9J ND ND llJ ND ND 130 24 58 540 14J 62 BJ 22 780 ND 250J 32J 40J 3300 9.4J 1300 ND 810 5600 ND 32.1 7.6 27.4 14.9 20.5 41.0 25. 4J 29.8J 113J 33.2J 732 98.5J 37.3J lOOJ 21.8J A-11 SS-27 SS-28 SS•29 ND ND ND ND ND ND 83J 110 120 48J 40 48 130J l30J l70J 860 850 920 6.3 29.8 6.8 94.6J 35.6J 66.4J 69.2J I8.2J 41. lJ --------- TABLE 9 (CONT'D) PHASE 2 SOIL ANALYTICAL RESULTS . -. :::·.::•.-·:::. l~i.•.· ''//\/St QOKl>OUlfl:! \i\_;\\·:· uLio ·/r.,: ... -. ,:,-.·=,::_.-, :-··-. . -.:. >SS-31 BETA-BHC ND ND 4,4'-DDE 23 160 4,4'-DDD 13J 87 4,4'-DDT 30J 260J TOXAPHENE 490 1300 COPPER 6.7 I 9.1 LEAD 13.2J 40.0J ZINC 14.9 52.2 Pesticides results given in ppb Metals results given in ppm J -Quantitative Estimate ND-Not Detected . SOIL SAKPLB ... SS-32 SS-34 SS-35 SS-36 ND ND 28J ND 49 280J 610J 960J 22 74J 320J 360J 59J 360J 590J 1300J 430 NO 3300 ND 9.0 32.4 13.3 37.7 32. lJ 46.5 44.lJ 69.7J 24.0 102 27.7 63.8 A-12 11!!!!!1 !!!!I ·•.•··-'·· SS-37 SS-38 SS-39 ss.J,o ND ND ND ND 6.0J 220 190 85 8.7J 99 69J 83 23J 170J 220J 300J ND ND ND 920 4.4 5.7 ]9.0 4.9 120J 18.5J 27.6 82.0 36.5 19.8 49.l 28.9 -- --- .·· \~····. COHPOU!IIO.· ..•• i ssfil4.ti .ss~,2•.··· ALPHA-BHC ND ND BETA-BHC ND ND DIELDRIN ND ND 4,4'-DDE 180 170 4,4'-DDD so 55 4;4'-DDT 210J 150 TOXAPHENE 760J 740J COPPER 9.9 25.6 LEAD 45.4 43.1 ZINC 28.0 62.9 Pesticides results given in ppb Metals results given in ppm J -Quantitative Estimate ND-Not Detected TABLE 9 (CONT'D) PHASE 2 SOIL ANALYTICAL RESULTS SOIL SAMPLE SS-43 SS-44 SS-45 SS-46 SS-47 ND ND ND ND ND ND ND 4.9J 120J ND ND ND ND ND ND 470 140J 140 1600J OOOJ 360 BOJ 54 1500J 660J 2800J 210J lBOJ 5200J 1600J 2300 llOOJ 860 llOOOJ 8000J 3.7 16.9 18.7 ND 16.1 96.0 40;4 25.0 76.2 22.7 40.7 30.2 32.0J 42.7 17.7B A-13 liliiii - i',>'.r.·• .,··· .. SS-49 SS-50 ss.,.51 330J ND ND lSOJ ND ND ND ND 390J lOOOJ 370J 550J I 1900J 580J 2000J 4900J IOOOJ 3000J 15000J 5BOOJ 18000J 4.3B 14 .5 24.1 65.5 22.7 26.4J 130 33.7J 45.4 -------. -- - l!!!!l!!I . .,. !fit·. .. · .. ( :· . COMPOUND· ss::s2/. ssL53). <ss:54 . ALPHA-BHC ND ND ND BETA-BHC ND 5.9J ND DELTA-BHC ND ND ND GAMMA-BHC ND ND ND DIELDRIN ND ND ND 4,4'-DDE 34 120 460J 4,4'-DDD 32 220 430J 4,4'-DDT 62J 340J 740J TOXAPHENE 400 3600 4100J COPPER 4.1 4.1 16.7 LEAD 6.9J 16.2J 21.lJ ZINC l.6J 46.1 8. 4J Pesticides results given in ppb Metals results given in ppm J -Quantitative Estimate ND-Not Detected TABLE 9 (CONT'D) PHASE 2 SOIL ANALYTICAL RESULTS . . .. .· SOIL SAMPLE SS-56 . SS-57 . SS-58 SS-59 ND ND 75J ND 43J ND 220J ND ND ND 33J ND ND ND 41J ND ND 1500J ND ND 800J 7300 4100J 1600J 830J 5700J 5700J 1200J lOOOJ 8900J 9000JC 2300J 5400J 37000J 83000J 14000J 21.9 11. 1 18.3 10.9 33.2J 32.3 33.7 38.0J 7.7J 26.0J 16.7J 25.BJ A-14 - ·.·.~ ... _. .. SS-60 SS-61 · ssif121 ND ND ND 60J ND ND ND ND ND ND ND ND ND ND ND 670J 3000J 4000J 730J 3500J 4800J lOOOJ 7800JC 8200JC 9300J 54000J 59000J 20.1 17.9 21.7 24.SJ 26.3J 29.9J 23. 2J 7.0J 5. 4J - - -------- ~ COMPOUNO ····.·•-:--,•,.-...:' .. :-:::·:-.,.-:,v--:·· :.-.,.:-..... ' ···.••·•ss.::,3r •· SS-67 ALPHA-BBC ND ND BETA-BBC ND 62J DELTA-BBC ND ND GAMMA-BBC ND ND 4,4'-DDE 4400J 560J 4,4'-DDD 6100J 660J 4,4'-DDT llOOOJC llOOJ TOXAPBENE 130000J lOOOOJ COPPER 21.6 19.3 LEAD 37.0J 21.8J ZINC 12.6J 2.lJ Pesticides results given in ppb Metals results given in ppm J -Quantitative Estimate ND-Not Detected TABLE 9 (CONT'D) PHASE 2 SOIL ANALYTICAL RESULTS SOIL SAMPLE SS-68 SS-71 SS-82 SS-83 ND ND ND ND ND ND ND ND ND ND ND ND ND NO ND ND 32J 2300J 160 41 14J 6100J 320 110 27J 19000JC 830 310 250J 54000J 3600 510 5.3 7.8 15.5 6.2 10.6J 23.0J 336J 222J ND 76.4J 99.]J 49.7J A-15 ... · .,•·. . ::·-·,:· .. ·• SS-84 SS-85 ss..:97 ss ... se ND ND ND 91 ND 65J ND 380 ND ND NO 69 ND ND NO 46J I 120J 390 250J 530 210 710 570J 1200 550 1900 1500J 2400 1900 2900 4300J 8800 6.9 9.0 5.8 5.6 125 47.3J 13.]J 24.4J 35.4J 56.6J 11 lJ 26.9J - - - - --liiiiii -- - - - - ----------- :,-•Ir > . ,--: COMPOUND <i: }i '@•• .- <:~ f'! SS-90 ALPHA-BHC 130J ND BETA-BHC 260 750J DELTA-BHC 54J ND GAMMA-BHC 51J ND DIELDRIN ND ND 4,4'-DDE 660 1400J 4,4'-DDD 360 3800J 4,4'-DDT 4300 9300JC ALPHA-CHLORDANE ND ND GAMMA-CHLORDANE ND ND TOXAPHENE 8700 26000J COPPER 5.2B 19.3 LEAD 14.9J 25.8J ZINC 15.6J 77.2J Pesticides results given in ppb Metals results given in ppm J -Quantitative Estimate ND-Not Detected TABLE 9 (CONT'D) PHASE 2 SOIL ANALYTICAL RESULTS SOIL SAMPLE SS-92 SS-93 SS-94 SS-95 ND 360J ND ND 180J 1500J 53J 5. lJ ND ND ND ND . ND ;_ .--ND ND ND ND ND ND 22J llOOJ 5900J 320 120J 2400J 12000JC 590 160J 3900J 38000JC 1600 460J ND ND ND 45J ND ND ND 49J 35000J 78000J 3900 1500 5.6 9.7 33.7 5.6 26.4J 87. lJ 22.3J 72.5J 51.SJ 43.lJ 24.6J 43.9J Ac-I 6 ·; SS-96 SS-97 ss-ioj\ ND ND ND ND 5.SJ ND ND ND ND ND ND ND ND ND ND 3.7J 65 1800J 7.7J 100 3300J 25 300 68000JC ND ND ND ND ND ND ND 850 2 lO_OOJ 3.38 6.9 9.4 ll.8J 84.3J 198J 7.68-51.0J 121J ----1!1111 == -liiii iiiii --- - - I U··-ct\ .··· /--:<~: . . COlU'OUND ss41 · w 0:ies~1os ALPHA-BHC ND ND BETA-BHC NO ND -DELTA-BHC ND ND GAMHA-BHC SlJ ND HEPTACHLOR ND ND ALDRIN ND ND DIELDRIN ND ND 4,4'-DDE JOOJ 870J 4,4'-DDD 590J 2600J 4,4'-DDT 1300J 5700J TOXAPHENE 7100J 18000J COPPER 4.1 3.5B LEAD 32.4J 9.3J ZINC 47.7J 12.0J Pesticides results given in ppb Metals results given in ppm J -Quantitative Estimate ND-Not Detected TABLE 9 (CONT'D) PHASE 2 SOIL ANALYTICAL RESULTS SOIL SAMPLE SS-106 SS-107 ss-110 SS-114 ND ND ND ND ND ND 520J 62J ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 920J 130 5800J ND 1800J 260 15000JC 480 4900J 660 41000JC 760 18000J 2100 130000J 4700 7.3 14.8 29.6 4.1 23.6J 188J 53.6J 5.2J 60.SJ 102J 219J 14.4J A-17 ----·- . ·•·· ·••·· \ .· .• <:< : :.<·· < ··.·.: .·:··:·:.;·:,::::: ,:· .. -':'(· \: 1 SS-115 SS-117 ss.;11, ·.·· ND ND 130J 130J 130J 970J ND ND llOJ ND ND llOJ ND ND 190J 60J 44J 350J ND ND 630J 180J 230J 790J BOOJ 900J 3300J 1600J 1700J 3800J 8500J 18000J 34000J 4.0 ND 5.9 6.6J 3.9J 3.2J 12.9J 18.SJ 82.6J · TABLE 10 BACKGROUND SOIL SAMPLES ANALYTICAL RESULTS SOIL SAMPLE COMPOUND ss-121 4,4'-DDE 75 4,4'-000 32 4,4'-DDT 110 TOXAPHENE 260 ALUMINUM 2660 ARSENIC ND BARIUM 1.2B CALCIUM 105 CHROMIUM 2.7 COPPER ND IRON 1640 LEAD 7.6J MAGNESIUM 83.3B MANGANESE 12.7 NICKEL ND SELENIUM 0.23 SODIUM 90.2 VANADIUM ND ZINC 15,3J Pesticides results given in ppb Metals results given in ppm J -Quantitative Estimate ND-Not Detected ss-122 76 22 74 180 2140 0.71 8,9 907 2.1 2.7 1380 20,0J 158 20.2 3.4B ND 50,3B 3.2 20, SJ B -Detected in Blank at Similar Concentrations A-18 I I I I I I I I I I I I I I I I I I I TABLE 11 PHASE 3 SOIL ANALYTICAL RESULTS ... COMPOUND. > . is:it,1i+2'· SS-49~2 ALPHA-8HC ND ND 8ETA-8HC 12 ND DELTA-8HC ND ND GAMMA-8HC ND ND DIELDRIN ND ND 4,4'-DDE 130 58 4,4'-DDD ND ND 4,4'-DDT 180 170 ENDRIN KETONE ND ND TOXAPHENE 1000 810 COPPER 5.4 7.0 LEAD 3.78 8.408 ZINC 9.0 17.3 Pesticides results given in ppb Metals results given in ppm J -Quantitative Estimate ND-Not Detected SOIL SS-51-2 SS-58-2 ND llOJ 510C 180J ND 120J ND 78J ND 280J 2500C lOOOJC 1400C 1300JC 0000c 5400JC ND ND 38000C 24000JC 17.7 14.9 27.58 25.7 57.9 22.4 B -Detected in Blank at Similar ConcentLations C -Confirmed by GC/MS SAMPLE SS-65-2 ND 36 42 ND 49 ND ND ND ND 330 9.4 9.0 11.7 A-19 SS-67-2 ND ND ND ND ND ND NO 190 ND 460 5.7 7.9 3.4 . > > . ·. ,, .. SS-69-2 SS-71-2 ND 210C 67J 400C ND 33 lJJ 45 ND 36 ND 74 ND NO NO 4JOC NO 280 260J 1400 2.9 4.28 4.5 2.4 6.3B 5.98 ----------------.. TABLE 11 (CONT'D) PHASE 3 SOIL ANALYTICAL RESULTS . . -="' SOIL COMPOUND .. :) 81*, SS-72-5 SS-73-5 SS-76-5 ALPHA-BHC ND ND BF;TA-BHC 19 59 DELTA-BHC ND ND GAMMA-BHC ND ND ALDRIN ND ND DIELDRIN ND ND 4,4'-DDE ND 32 4,4'-DDD ND ND 4,4'-DDT ND 56 METHOXYCHLOR ND ND TOXAPHENE ND 200 COPPER 8.2 8.1 LEAD 2.9 3.5 ZINC 10.4 17.2 Pesticides results given in ppb Metals results given in ppm J -Quantitative Estimate ND-Not Detected 12000c 2100C 1900C 1500C 1600C 3400C ND ND ND ND 280000C 8.5 6.1 16.6 B -Detected in Blank at Similar Concentrations C -Confirm~d by GC/MS ND ND ND ND ND ND 100 270 2600C 180 3400 8.8 4.5B 8.1B SAMPLE SS-76-10 SS-90-2 SS-90-5 ND 89J ND ND 180J 11 ND 59J ND ND 48J ND ND ND ND ND 32J ND 59 ND ND 230 ND ND 3300C ND ND .. 110 ND ND 1900 310J 2200 3.7 1.5 2.8 2.3B 2.0J 3.50J 3.2B IO.I 3.1 A-20 .. . . . . ss .. ,1;2, 1600C 820C 890C 360C ND ND 370C 630C 3000C ND ND 3.0 2.6 4.2 ------------l!l!!!!!I l!!!!!!I TABLE 11 (CONT'D) PHASE 3 SOIL ANALYTICAL RESULTS . , ... ·.·. ... \ . COMPOUND •. D ;!a;9,;:J5. SS-91-10 ALPHA-BHC HD ND BETA-BHC 31 18 DELTA-BHC 18 ND GAMMA-BHC ND ND HEPTACHLOR ND ND ALDRIN ND ND DIELDRIN ND ND 4,4'-DDE ND ND 4,4'-DDD ND ND 4,4'-DDT ND ND TOXAPHENE ND ND COPPER 6.3 3. 68 LEAD 4.8 2.08 ZINC 7.8 6.0 Pesticides results given in ppb Metals results given in ppm J -Quantitative Estimate ND-Not Detected SS-92-2 24 12 ND 11 ND ND ND ND ND ND ND 1.18 1.28 3.58 B -Detected in Blank at Similar Concentrations C -Confirmed by GC/MS SOIL SAMPLE SS-92-5 SS-93-2 SS-99-2 46 ND ND 38 27 ND 23 ND ND 21 ND ND ND ND 48 ND ND 130 ND ND 250 ND 69 27 ND 44J ND 53 340 370 440 810 ND 6.4 2. 408 1. 7 4.7 5 .40 68.9J 8.7 6.70 10.5 A-21 liiiiiiil . iili ··. :) .,.,.• -. -· ·:::-:: SS-100-2 ss~100 .. 5 1200C 11 ND 48 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 7600C 140 15000C ND 3.3 7.6 40. 1 4.8 49.7 21.3 -- - ---------1!!!!1 . COMPOUND i( ~--• .. • .. ····•· ...•. ··· . .·. . ss:--101-;.:r ss-101..;s BETA-BHC 43J 50 4,4'-0DE NO ND 4,4'-000 NO ND 4,4'-DDT 18J 42 TOXAPHENE 300 220 COPPER 1.28 5.1 LEAD 1.58 3.8 ZINC 5.0 7. 1 Pesticides results given in ppb Metals results given in ppm J -Quantitative Estimate ND-Not Detected TABLE 11 (CONT'D) PHASE 3 SOIL ANALYTICAL RESULTS SOIL SAMPLE SS-103-2 SS-105-2 SS-109-2 ND 12 1600C 36J 30 570C NO ND ND 160J 230 ND 560J 1400 ND 8.5 6.9 11.8 2.9B 1. 98 27.6 7.2 10.5 76.2 B -Detected in Blank at Similar Concentrations C -Confirmed by GC/MS A-22 == liiiiill!I liiiiiiii ss-110-2. SS-110-5 ND ND 31 27 89 92C 950C 500C 1100 1000 11. 5 7.7 4.2 4. 7 10.2 12.8 - - - - - --------I!!!!!! 1!!!19 -== lliiiiiiil iiii TABLE 11 (CONT'D) PHASE 3 SOIL ANALYTICAL RESULTS ,,, ..... . tijsl;;iio-10 BETA-BHC ND DELTA-BHC ND 4,4'-DDT 55 TOXAPHENE ND COPPER 16.6 LEAD 2.2 ZINC 11. 7 Pesticides results given in ppb Metals results given in ppm J -Quantitative Estimate ND-Not Detected SOIL SAMPLE SS-112-2 SS-113-10 26 16 ND 54 ND ND ND ND 2.0 9. 1 2.3 4.8J 4.8 12.2 B -Detected in Blank at Similar Concentrations C -Confirmed by GC/MS A-23 SS-116-5 lJJ ND ND ND 10.2 4.5 11.5 - --------- -111!!!1 !!!!!I 1!11 == ;;;a liiliil liiiii . liiiiiil TABLE 12 PHASE 3 SOIL ANALYTICAL RESULTS VOLATILES AND SEMI-VOLATILES (PPB) ·•.·. < •• . • i\•·/·. +·· .. ·• . .:• ... . . COMPOUND .· . SS-48-5 SS-48-10 METHYLENE CHLORIDE 17B ACETONE 180B BIS(2-ETHYLHEXYL) 59J PHTHALATE J -Quantitative Estimate ND-Not Detected 18B 29B 60J SOIL SAMPLE SS-63-5 SS-63-10 39B 35B 42B 35B ND ND B -Detected in Blank at Similar Concentrations A-24 SS-66-5 21B 11B ND SS-113-10 28B 41B 68J - - --· - ------ --· ------ TABLE 13 SOIL BORING ANALYTICAL RESULTS ·.:·.-;:::/:::. 1v•··· : . : COMPOUN~ .. y··•<•·•·· :?/-: . 0'-1' SB 4,4'-DDE 21 4,4'-DDD 8. 4J ENOOSULFAN SULFATE ND 4,4'-DDT 28 COPPER 3. 9B LEAD 21.5 ZINC 7.1 Pesticides results given in ppb Metals results given in ppm J -Quantitative Estimate ND-Not Detected 5_B 5'-7' ND ND llJ ND 2.5B 3.2S 2. 28 B -Detected in Blank at Similar Concentrations SOIL SAMPLE SB 10'-12' ND ND l 7J ND ND 4.2 2.8B A-25 SB 15'-17' SB 20•-22• ND ND ND ND 22 24 ND ND 3.6B ND 2.2 2.0 1. 7B ND -------------------- TABLE 14 PHASE 4 SOIL ANALYTICAL RESULTS (PPB) .. :• .,.·,.::•:-.:,\,:,:: :·-- .· .. -.--- .. CONPOUNl) SS-58-20S ALPHA-BHC BETA-BHC DELTA-BHC GAMMA-BHC DIELDRIN 4,4'-DDE 4,4'-DDD 4,4'-DDT TOXAPHENE J -Quantitative Estimate ND-Not Detected lSOOC 2000C 840C 620C ND llOOOC ND 54000C 220000c S5-61-20S 13 27 ND ND ND lOOOC 26 lOOOC 3900 B -Detected in Blank at Similar Concentrations C -Confirmed by GC/MS A-26 SOIL SAMPLE SS-62-205 SS-63-205 ND ND ND 640C ND ND ND ND ND ND 1400C 1300C ND ND 2000C 6700C 5200C 64000C 55:..54 20S ND 160 ND ND 130 380 ND 400 ND ------------------- TABLE 14 (CONT'D) PHASE 4 SOIL ANALYTICAL RESULTS (PPB) ···:-· -· COJU>OUND .· .· · .. ·.·····> ·• ss,;.66-20s BETA-BHC DELTA-BHC GAMMA-BHC 4,4'-DDE 4,4'-DDD 4,4'-DDT TOXAPHENE J -Quantitative Estimate ND-Not Detected 290C 150 55 660C ND 620C ND SS-91-lON 850C ND ND 640C lOOOC 14 oooc . 15000C B Detected in Blank at Similar Concentrations C -Confirmed by GC/MS SOIL SAMPLE SS-92-lON 230C ND ND 000c 300 4600C ND A-27 SS-93-lON ND ND ND 480 NO 1500C 3800 SS-93-20E 16 ND ND lUO 30 440 . 1900 - - - - --------------- TABLE 15 1991 POST-REMOVAL SOIL ANALYTICAL RESULTS ., /.:·.:,.,,,.,, ,., ... SOIL SAMPLE COMPO(JNl> /A ii ,: :· . B C ·o E F G H I J ALPHA-BHC 130 99 170 27 70 960 69 3800 64 28 BETA-BHC 45 45 ND 21 33 180 65 610 61 55 DELTA-BHC 120 250 150 52 67 230 250 540 46 110 GAMMA-BHC 54 140 ND 30 39 260 120 390 ND 20 HEPTACHLOR ND ND ND ND 18 500 43 490 ND 18 ALDRIN ND ND 480 ND 270 3300 140 1300 ND 43 ENDOSULFAN I ND ND ND ND ND NO NO NO NO 18 4,4'-000 ND ND ND ND NO 860 NO 750 ND ND ENOOSULFAN ND ND NO NO NO 2000 NO NO NO 44 SULFATE 4,4'-DDT 1i;o· 52 ND ND 87 NO 170 5800 77 ND TOXAPHENE 1200 490 56000 ND 6500 110000 1800 42000 1200 2600 ND -Not Detected A-28 - - - - - - -_,_ ---------- TABLE 15 (CONT'D) 1991 POST-REMOVAL SOIL ANALYTICAL RESULTS .-,, :_' '' SOIL SAMPLE COMl'OUND .. .•· . . .. ·· . K : ·-.. , :· ·:· <SS-48 SS-64 SS-66 SS-69 SS-73 SS-76 SS-91 SS-98 SS-99 ALPHA-BHC 46 130 ND 18 72 ND 210 21000 170 200 BETA-BHC 87 160 130 71 870 ND 420 4100 780 280 DELTA-BHC 150 ND ND 500 970 ND 410 ND 150 130 GAMMA-BHC 45 ND ND ND ND ND ND 3200 190 ND HEPTACHLOR 28 ND ND ND ND ND ND 250 25 330 ALDRIN 78 ND ND ND ND ND 230 760 ND 4400 HEPTACHLOR ND ND ND ND ND ND ND ND 21 ND EPOXIDE DIELDRIN ND ND ND ND 61 ND ND ND 4 I ND - 4,4'-DDE ND 670 ND ND ND ND 320 1100 ND ND 4,4'-DDD ND 610 290 ND ND ND 650 770 ND 260 4,4'-DDT ND 5100 570 ND ND ND 12000 10000 230 llOO TOXAPHENE 3600 22000 16000 440 2600 7600 18000 27000 2200 6900 ND -Not Detected A-29 ------------------- TABLE 15 (CONT'D) 1991 POST-REMOVAL SOIL ANALY'I'ICAL RESUL'l'S COMPOUND SS-108 ALPHA-BHC 19 BETA-BHC 240 DELTA-BHC 48 GAMMA-BHC ND ALDRIN ND DIELDRIN 53 4,4'-DDE 52 4,4'-DDD 120 4,4'-DDT 330 TOXAPHENE 6400 J -Quantitative Estimate ND-Not Detected SS-113 220 190 130 50 ND ND ND ND 71 ND SOIL SAMPLE SD-9 SD-12 SD-14 ND ND ND ND 150 ND ND ND ND ND ND ND ND ND ND ND 270 ND ND ND ND ND ND ND 82J 860 ND ·2 200J 35000 5500 A-30 SD-15 ND 92 ND ND 25 120 ND ND 170 4000 ------- ... :c;,.i ' . . · .. '' COMPOUND. . ,· .. -. J.so..'.1 ALPHA-BHC ND BETA-BHC llOJ DELTA-BHC . ND GAMMA-BHC ND 4,4'-DDE 1000 4,4'-DDD 2800 4,4'-DDT 3900J TOXAPHENE 28000 J -Quanititative Estimate ND-Not Detected --- ----- TABLE 16 PHASE 1 SEDIMENT ANALYTICAL RESULTS (PPB) SOIL SAMPLE SD-2 SD-3 SD-4 ND ND ND ND ND ND ND ND ND ND ND ND 420J 760J 63J 1200J 2300 14J 1800J 4300 54J 11000 14000 ND A-31 SD-6 ND ND ND ND 970J 4500J 4800J 40000J - SD-7 SD-8 ND :T4J 4.4J 300J ND 24J ND 52J 79 220J 5:3 llOOJ 84 1400J 540 14000J - - - --- - - -------.. --l!!!!!!J . cc ; ·-::=:-, ·:·· ... COMPOUND SD-13 ALPHA-BHC ND BETA-BHC 94J 4,4'-DDE ll00J 4,4'-DDD I400J 4,4'-DDT 2400J TOXAPHENE 18000J -J Quantitative Estimate ND-Not Detected PHASE 1 SD-18 ND ND 410 290 440 2200 TABLE 16 (CONT'D) SEDIMENT ANALYTICAL RESULTS (PPB) SOIL SAMPLE SD-19 SD-20 SD-21 46J ND ND lJ0J 43J ND 3200J 2400J 570J lS00J 980J 1600 2700J 2400J 2300 11000 9700 13000 A-32 OSD-21 0SD-22 ND ND ND ND llJ 1500J 9.2J 1900 33 4400 ND ND --- - - -------- - - ---I!!!!!!!! COMPOUND OSD-23 DIELDRIN ND 4,4'-DDE 29 4,4'-DDD 13J 4,4'-DDT 73 TOXAPHENE 200 J -Quantitative Estimate ND-Not Detected PHASE 1 OSD-24 ND 6600J 21000 44000 ND TABLE 16 (CONT'D) SEDIMENT ANALYTICAL RESULTS (PPB) SOIL SAMPLE OSD-25 OSD-26 OSD-27 ND 12J ND 900J 77 ND 1400J 28 25000 3700 80 52000 ND 280 ND A-33 OSD-28 OSD-29 1.5-3' ND ND 890J 1700J 2600 4600 5300 13000 21000 36000 ------------------- ... ····). i ' CO!U'OUND .. so-1-1. s ALPHA-BHC ND BETA-BHC ND GAMMA-BHC ND 4,4' ODE 340 4,4'-DDD 410 4,4'-DDT 3700C TOXAPHENE aoooc ND -Not Detected C ~ Confirmed by GC/MS .· TABLE 17 PHASE 2 SEDIMENT ANALYTICAL RESULTS (PPB) SOIL SAMPLE s0-1-2.s SD-3-1.5 SD-3-2.5 SD-6-1.5 ND ND ND 540C ND 15 ND 580C ND ND ND 510 100 ND 34 ND ND ND ND ND 1400C 61 130 4200C ND 540 920 58000C A-34 SD-8-1,5 SD 8 2.5 ND blD- ND 21 ~D ND ND ND ND ND - 190 68 2800 1200 ------ .· ·. COMPOUND ... SD-9-2.5 ALPHA-BHC ND BETA-BHC ND DELTA-BHC ND HEPTACHLOR 470C DIELDRIN ND 4,4'-DDE ND 4,4'-DDD ND 4,4'-DDT 14000C TOXAPHENE 130000C ND -Not Detected C -Confirmed by GC/MS ---- TABLE 17 (CONT'D) PHASE 2 SEDIMENT ANALYTICAL RESULTS (PPB) SOIL SAMPLE SD-10-1.5 SD-10-2.5 SD-11-1. 5 SD-11-2.5 ND ND 260C ND ND ND 730C ND ND ND 150 ND ND ND ND ND ND ND 1600C 180 ND ND 270 ND ND ND 970C ND ND ND 4400C 370 4600 1300 6B000C 15000C A-35 0 -l!!!!!!I - SD-12-1.5 SD-12-2.5 ND ND ND ND ND ND ND ND ND ND ND ND ll00C 250 l0O0C ND 69000c 15000C - - - - - - - ----------l!!!!!!I !El .. · .. ·.• ..... :·. ·: : ... . . COMl'OUND .. SD-13-1.5 4,4'-DDE ND 4,4'-DDD ND 4,4'-DDT ND TOXAPHENE 180 ND -Not Detected C -Confirmed by GC/MS PHASE 2 TABLE 17 (CONT'D) SEDIMENT ANALYTICAL RESULTS (PPB) SOIL SAMPLE SD-19-1.5 . SD-21-1.5 SD-21-2.5 SD 41-0.5 40 ND ND 170 ND ND ND ND 23 4000C 470 180 ND 26000C 4000 2300 A-36 OSD 24-1.5 OSD-24-2.5 ND ND ND ND 460C ND 2700 790 I ---------- - . i __ -i. . .. . . .. .. -_ -.,. ·- TABLE 17 (CONT'D) PHASE 2 SEDIMENT ANALYTICAL RESULTS (PPB) --.- SOIL SAMPLE COMPOUND OSD-27-· OSD-27-OSD-28-OSD-28-OSD-30-OSD-30-1.5 2.5 4.0 5.0 1.5 2.5 ALPHA-BHC ND ND ND 12 ND ND BETA-BHC ND ND ND 26 ND ND . HEPTACHLOR ND ND ND ND ND ND DIELDRIN 320 110 ND ND ND ND 4,4'-DDE 100 ND ND 50 45 ND ENDRIN 140J ND ND ND ND ND 4,4'-DDD 230J ND 41 97 ND ND 4,4'-DDT 3700C llOOC 180 560C 140 ND TOXAPHENE 25000C 6200C 920 4200 1100 1200 ND -Not Detected C -Confirmed by GC/MS A-37 --1!!!!19 OSD-42-OSD-43- 0.5 0.5 I ND ND ND 540JC ND ND ND ND 150 390J --ND ND ND ND 580C 7200JC 1300 44000JC == -----iiiil liiii .., liiiiiil iiil .•.. j/··· . ,··, 'i°.:.'· .. ·. COMPOUND · so--io+/ .s0-10.,. >< 2 . .. •: 5:.,, .... ALPHA-BHC ND ND BETA-BHC ND ND DELTA-BHC NO NO GAMMA-BHC NO NO HEPTACHLOR NO NO EPOXIDE OIELDRIN NO NO 4,4'-00T 35 NO ENDRIN NO ND KETONE TOXAPHENE 600 200 J -Quantitative Estimate NO-Not Detected C -Confirmed by GC/MS . . ' TABLE 18 PHASE 3 SEDIMENT ANALYTICAL RESULTS (PPB) SOIL SAMPLE sD.,.11-SD-11- S D - 1 2 - SD-12-S0-14-2 5 2 5 2 ND NO 190J NO NO 41 NO 160J 43 10 NO NO 60J NO ND NO ND 53J ND ND NO NO ND ND 15 100 32J ND NO 65 NO NO ND NO NO NO NO NO NO 29 1900 3200J 6900JC NO 5200C A-38 Ill!! II!!!! SD-14-SD-14- 5 10 ND NO NO ND NO ND ND ND 16J ND -- NO 72J NO 240J NO NO 8500JC 7900JC I I I I I I I I APPENDIX B I I I I I I I I I I I I I I I I I I I I I I I I I I I I RESPONSIVENESS SUMMARY GEIGY CHEMICAL CORPORATION SITE ABERDEEN, MOORE COUNTY, NORTH CAROLINA A public comment period was held from March 26, 1992 through May 25, 1992 to receive comments from the public on the Proposed Remedial Action Plan, and EPA's preferred remedial alternative for the Geigy Site. A public meeting for the Geigy Site was conducted on March 31, 1992 at 7:00 pm at the American Legion Hall in Aberdeen, North Carolina. The public meeting was attended by EPA staff, state regulatory representatives, local regulatory representatives, potentially responsible parties, arid area residents. The purpose of the public meeting was to present and discuss the findings of the RI/FS and to apprise meeting participants of the EPA's preferred remedial alternative for the Geigy Site. Comments received during the public meeting are swnmarized in Part 1 of this Responsiveness Swnmary. In addition to the comments made at the public meeting, written comments were received from area residents and the potentially responsible parties. Part 2 of this Responsiveness Swnmary includes a brief swnmary of these written comments and EPA' s response. PART 1 SUMMARY OF COMMENTS RECEIVED DURING THE PUBLIC MEETING 1.1 Comment: An area resident asked what was in the drums presently located on-site. EPA Response: 1.2 Comment: EPA Response: The drums contain water that was removed from the wells prior to sampling activities, water used for decontamination, and soil from drilling the wells. An area resident asked if the groundwater would be treated until it was okay to put in the sewer system. After the analyzed. the POTW achieved. groundwater has been treated, it will be The water will not be discharged into until the remediation levels have been 1 I I I I I I I I I I I I I I I I I I I 1. 3 Comment: An area resident stated that North Carolina has been shipping waste out-of-state for years, and thought it was about time that North Carolina started taking care of its own. 1. 4 Comment: An area resident asked if we could clean up the Geigy waste with the Aberdeen Pesticide Site waste. EPA Response: While the Geigy and Aberdeen Sites do have similar wastes, the companies responsible for the contamination at these sites are different. The Geigy and Aberdeen Sites are also separate sites on the National Priorities List. If the contaminated soil from the Geigy Site is transported to the Aberdeen Site and a spill or similar situation were to occur, then the companies who were not previously involved with the Aberdeen Site would then be liable at that Site as well. 1.5 Comment: A corporate representative asked what was the main criteria for choosing thermal desorption. EPA Response: 1.6 Comment: EPA Response: 1.7 Comment: EPA Response: 1.8 Comment: Thermal desorption is an innovative technology that has shown on a limited basis that it is effective in treating pesticides in soil. It meets the statutory requirement for permanent remedies that utilize treatment technologies to the maximum extent practicable. It also reduces the volume, toxicity and mobility of the contaminants. An area resident asked how long it would take to complete the thermal desorption. Once the remedial design is contractor is chosen, the actual take approximately two months. completed and a processing should An area resident asked whether there were any on-site· treatment technologies that don't involve thermal desorption or incineration. We currently are not aware of any on-site treatment technologies other than thermal desorption and incineration that effectively treat pesticides. An area resident asked if thermal desorption had been tested.· 2 I I I I I I I I I I I I I I I I I I I EPA Response: 1.9 Comment: EPA Response: 1.10 Comment: EPA Response: 1.11 Comment: EPA Response: Thermal desorption has been tested on the treatment of pesticides on a small-scale. Two other sites in Region IV have selected this alternative for the treatment of pesticides. These sites are ahead of the Geigy Site in the remedial process. All information gathered on those sites will be utilized for the Geigy Site. An area resident asked what sort of criteria EPA reviews to qualify thermal desorption units. The thermal desorption units will be evaluated on their ability to meet the requirements of the EPA. approved remedial design. An area resident asked if thermal desorption was the only on-Site method that EPA considered. EPA also considered on-site incineration. This will be utilized if thermal desorption proves ineffective or if costs of thermal desorption prove prohibitive. An area resident asked why wasn't vitrification considered. in-situ In-situ vitrification was considered, but was rejected. This alternative would not be a permanent remedy, and.site restrictions would have to be placed on the property indefinitely to limit site activities. In addition, availability cf vendors for this process are limited. PART 2 WRITTEN COMMENTS RECEIVED DURING THE PUBLIC COMMENT PERIOD 2.1 Comment: A PRP stated that the recommended remediation proposed by EPA represented a failure by EPA to use scarce funds in a responsible and productive manner. No action should be taken at this Site. EPA Response: Cost was considered when EPA chose the selected alternatives. However, before cost is considered, the alternative must be protective of human health or the environment. The no-action alternative does not meet this basic criteria. 3 I I I I I I I I I I I I I I I I I I I 2.2 Comment: The PRPs stated that the Aberdeen community had not had sufficient opportunity to evaluate and consider the information in the RI/FS and the proposed plan. The comment period should be extended. EPA Response: The original 30-day public comment period was extended an additional 30 days. 2. 3 Comment: The PRPs stated that the space requirements for implementing on-site thermal treatment exceed available area at the Geigy Site. EPA Response: Space requirements are typically less than SO feet by 150 feet for a thermal desorption unit. One vendor contacted has a small unit designed to handle treatment of low volumes of soil that requires only 50 feet by 50 feet. Therefore, the site should be adequate to accommodate the thermal desorption unit, decon and staging areas. Command trailers and other support necessary may have to be located on adjacent property. 2.4 Comment: Thermal desorption is an unproven technology with significant implementation difficulties. EPA Response: Thermal desorption is considered to be an innovative technology. While full-scale application of this technology has not been implemented, a recent treatability study for the Arlington Blending Site was successful in treating pesticides down to levels similar to those required at the Geigy Site. This study also showed that air emissions were within all regulatory limits. 2.5 Comment: Should thermal desorption be unsuccessful, on-site incineration would have even greater implementation difficulties. EPA Response: On-site incineration was chosen as a contingency remedy because it is a proven technology for the effective and complete treatment of pesticides in soils. Considerations would have to be given for the availability of a pilot-scale incineration unit. Even though there would be more regulatory requirements for an incinerator ( air emissions, monitoring, trial burn, etc.); these would be taken into account during the design and bidding of the system. 4 I I I I I I I I I I I I I I I I I I I 2.6 Comment: Testing and Design of will significantly greatest potential groundwater. the thermal treatment remedy delay remediation of the source of risks, site EPA Response: While the design of a thermal treatment system may indeed require more time than a design for off-site disposal, the time differential is not significant enough to eliminate the consideration of the preference for on-site treatment. As mentioned previously, both the Aberdeen Site and the Arlington Blending Site in Region IV are utilizing thermal desorption for the treatment of pesticides in soil. Results of studies from these two sites can provide valuable information for use at the Geigy Site, thus reducing the amount of time necessary to design the system. 2.7 Comment: The volume of soil to be treated is insufficient to mobilize qualified contractors. EPA Response: The question of whether a contractor is "qualified" or not would have to based on their bid proposal and past experience. EPA does not make determinations of qualification based on limited information about a contractor. While vendors with full-scale thermal desorption units often specify a minimum of 5,000 -10,000 cubic yards to warrant mobilization at costs up to $600,000 for mobilization, other vendors with smaller units will mobilize for soil volumes as small as 2,500 cubic yards at a cost of ·$250,000 for mobilization. Eliminating thermal desorption from consideration at this site for this reason would not be justified. 2. 8 Comment: The evaluation of preferred remedies by EPA is insufficient and inconsistent with requirements of the NCP. Noise from the unit will be significant, and will adversely affect neighboring residences. EPA Response: All of the alternatives presented in the proposed plan were evaluated equally using the nine criteria. EPA's decision on a remedy is based on this evaluation. If, during operation of the thermal desorption unit, it is determined that 24 hour per day operation is adversely affecting the surrounding community, adjustments can be made to the number of hours per day that the unit operates. 5 I I I I I I I I I I I I I I I 2.9 Comment: EPA Response: Alternative significant and was not 2 (Off-Site Disposal) offers advantages for overall site remediation given full consideration. EPA considered off-site disposal as an option for remediating the soils at the Geigy Site. EPA' s initial selection of on-site thermal desorption was chosen to best utilize permanent solutions via alternative treatment technologies to the maximum extent practicable. As a result of the reduction of contaminated soil requiring treatment the selected remedy has been changed to off-site disposal. A complete discussion of the reasons warranting the change from thermal desorption to off-site disposal is located in Section 12 of the Record of Decision. 6 I I I I I I I I I I I I I I I I I ABERDEEN, NORTH CAROLINA MOORE COUNTY - - - - - - - - - - - - - -X U.S. ENVIRONMENTAL PROTECTION AGENCY GEIGY CHEMICAL CORPORATION SUPERFUND SITE - - - - - - - - - - - - - -X PUBLIC HEARING * * * March 31, 1992 7:oo p.m. * * * At the American Legion Hall 209 East Main Street Aberdeen, North Carolina * * * Reported by: Sonja L. Reeves Professional Court Reporter 3460 Hastings Drive Fayetteville, North Carolina 28311 (919)488-4641 * * * I I I I I I I I I I I I I I I I I I I 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 A P P E A R A N C ~ ~ Diane Barrett -NC community Relations Coordinator Giezelle Bennett -Remedial Project Manager Tony Able -Groundwater Expert Solomon Pollard -Risk Assessment Expert * * * * * * £ B Q s:; ~ ~ ~ I li g ~ 2 DIANE BARRETT: Ladies and gentlemen, my name is Diane Barrett. I am the Community Relations coordinator for the State of North Carolina, and I want to welcome you here tonight for this public meeting. I would like to introduce our panel. Giezelle Bennett is our Project Manager for the Geigy Site. Tony Able is the Groundwater Expert. Solomon Pollard is the Risk Assessment Expert. Tonight we are here to meet on the Geigy Chemical superfund Site. This is a public comment period meeting. We have a court reporter who is taking all of the proceedings of the meeting, and they will appear in the information composite here in Aberdeen. I hope there is no confusion regarding the purpose of this meeting tonight, because there are three different activities going on by the EPA here in the Aberdeen area. There is the Aberdeen Pesticide Site. There is also the Crestline water line that's being put in here down beyond the Geigy Site. Of course, this meeting tonight is on the Geigy Site I I I I I I I I I I I I I I I I I I I 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 itself. If there are any questions regarding the other two Sites, I will be glad to address those after the meeting. 3 I'll just briefly go over this. How many of you have been at a Superfund meeting before? Most everybody. Superfund is a very long process, as most of you do know, and at the moment we are in step number five, as the overlay displays. We have received the results from the remedial investigation and the feasibility study and now we are presenting to the public these findings, as well as the various alternatives and the one the EPA prefers. So this is why we are here, to give you these results and to let you make comments to us about what you prefer. This 30-day comment period will end April the 24th. During the public comment period time we have, if citizens request, the opportunity for an extension, a 30-day extension to that public comment period if it is needed. After the public comment period has ended, we take all comments from this meeting and any written comments and those are all reviewed and every consideration given to those statements, and then a decision is made as to which alternative the agency would prefer to have utilized to clean up the site. This is called a record of decision. With that record of decision is also the responsiveness report which is our statement of all the comments that have been made and our response to those. This is also placed in the composite, which I I 1 I 2 3 I 4 I 5 6 I 7 I 8 9 I 10 I 11 12 I 13 I 14 15 I 16 I 17 18 I 19 I 20 21 I 22 I 23 24 I 25 I 4 is down in the town hall in Aberdeen. After that point, the agency starts negotiating with the PRP's, after the record decision has been signed, to see who will pay for the work to be done as far as remedial design and implementation of that activity. Then once that is done, we have a remedial design that is drawn up and then remedial action. So we have still have a little bit to go. We are about a little over halfway as far as the various phases. During any of this time period should there be more contaminants found, we can have emergency removal if those contaminants cause an immediate threat or anything like that to the population. Also we have technical assistance that is available to citizens at the Superfund Site. Since that pretty well covers what I am going to say, I am going to turn the meeting over now to Giezell,e Bennett, the Project Manager. GIEZELLE BENNETT: Good evening. I'm Giezelle Bennett and I'm the Project Manager for this Site. It is my responsibility as Project Manager to make sure that the project runs smoothly and is coordinated with the various federal and state agencies as well as to communicate to the public. I'm going to present the findings now of our remedial investigation and feasibilty study. This is a site location map which shows the location of the Geigy Site. As you can see, it is located east of Aberdeen on Route 211. It was operated as a I I 1. I I I I I I I I I I I I I I I I 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 pesticide blending and formulation facility from 1947 to 1967, and as a retail distributor of agriculture chemicals from 1968 to 1989. The Site is bordered on one side by Highway 211 and pretty much on the other side by the Aberdeen and Rockfish Railroad. The Site is about one acre in size and is currently vacant. It was placed on the NFL in 1989. 5 In December of 1988 three of our potentially responsible parties signed a consent order to perform the work needed at the Site. One of the first things that they did was to remove visually contaminated soils from the Site. This figure depicts the areas where those soils were removed. A total of 689 tons of contaminated soil were removed from the Site before the investigation even began. During remedial investigation, extensive soil sampling was done to determine the horizontal and vertical extent of the soil contamination at the site. As you can see, it is pretty well covered on site as well as some outside of the property line. Based on those sample results, a second removal was done. This removal removed approximately 200 tons of soil from the Site. You can see the areas where those were removed. This table shows the maximum soil concentrations that were left at the Site after the second removal, and it also shows EPA soil remediation goals for the Site. These clean up goals are based on direct contact with the soils, and are based I I I I I I I I I I I I I I I I I I I 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 on the fact that somebody may in the future live on the Site. This is our most conservative approach. 6 This figure shows generally the areas that still need cleaning up. In most areas it is limited to a foot. In some areas it can be down to as far as ten feet. An investigation of the groundwater was also performed. Wells were put in both the shallow aquifer, which is designated by the "S", and a deeper aquifer, which is designated by a "D". As you can see, there is city well number four there. It is the city well used for municipal drinking. It has been closed now, and those other wells are United States Geological Service w.ells. They are doing a study in the area. This figure shows the general direction of groundwater flow. As you can see, groundwater appears to be flowin9 toward the center of the Site, west from the east side and east from the west side. And the deeper aquifer, the limited amount of monitoring wells we have show that the water is flowing in the north, northwesterly direction. This figure is kind of busy but it shows the contamination that was found in each of the wells. As you can see, the contamination is basically in the shallow aquifer. As you can see, most of the shallow aquifers are contaminated. The deeper aquifers or the background wells are clean. Two wells on Site contain trichloroethene, and we found pesticides in only one of the deeper wells, which is south of the site, number I I I I I I I I I I I I I I I I I I I 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 7 11-0. If you can't see these--! know I am going pretty fast through these--all of these are in your handout that was at the door, so you can look on that to see the actual numbers. This one shows the maximum groundwater concentrations that were found in any given well, and it shows our groundwater remediation goals or clean-up goals that we want to do for the Site. Now, these are based on North Carolina groundwater standards. These are the remedial alternatives and their present worth cost that we considered. As you can see, we looked at a wide range of alternatives for both groundwater, from no action to complete groundwater extraction and clean up. In the soil we looked at from no action to off-Site landfilling and incineration, to capping to on-Site treatment alternatives. Now, once we had those alternatives, these are the criteria the EPA uses for determining which alternative to pick. There are nine of them.· They go from overall protection of human health and environment, which means that first of all, the alternative has to reduce risk to the people and the environment around it. Second, it has to comply with all federal and state laws. We also consider cost. We consider how it can be implemented. Will it take a lot of technical and administrative things to do? How fast can it be implemented? The short term effectiveness is during the clean-up how it is going to affect the community and workers I I I . I I I I I I I I I I I I I I I I 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 around it. Long term effectiveness is the permanence of it. Once we finish, will the Site be clean? Will we be finished with it? 8 One of the three things that we consider are it has to reduce the toxicity of the contaminant, the mobility, and preferably the volume of the contaminants that are left at the Site. Of course, we have to have acceptance by the state and acceptance by the community that the remedial action takes place in. This chart shows the alternative the EPA would prefer to conduct at this Site. Alternative three for groundwater remediation, which is complete groundwater extraction to attain remediation levels; carbon adsorption. For soil remediation we are looking at on-Site thermal desorption. This shows a conceptual flow diagram for how the groundwater treatment would work. The groundwater would be extracted through wells, put into a tank, go through the treatment system of carbon adsorption. We would monitor it to make sure it met all the clean-up levels, and then we would discharge it. For thermal desorption you would have to excavate the soil, get rid of anything oversized that couldn't fit into the machine, do the thermal treatment of it. You would have your clean soil coming off this way and your gases or your contaminants here and then those would be cleaned as well either I I I I I I I I I I I I I I I I I I I 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 9 through spent carbon, like you see here or a number of different alternatives. It just depends on the vendor that you choose. And that concludes my talk. DIANE BARRETT: Since we have made our presentation, now we are going to open the floor up for public comment. This is your time. One thing I would like you to do, please, when you do make a statement, come to the microphone, pronounce your name and spell the last name for our court reporter so that she can get it accurately. • • • CURT RICHARDS: I do have a few prepared comments to make this evening. My name ~s curt Richards and I work for Olin Corporation. Tonight I appear before you to express the opinions of CIBA-GEIGY Corporation, Kaiser Aluminum and Chemical Corporation, and Olin corporation. CIBA-GEIGY, Kaiser, and Olin have been working together to investigate and clean up the Geigy Site in an environmentally appropriate and safe manner. We have recently completed the remedial investigation, the feasibility study and the risk assessment for the Site. During this process, the companies collected and analyzed over 300 soil samples and installed and sampled 15 groundwater monitoring wells. Also during this process, over 3500 tons of contaminated soil and building debris were removed from the Site. These removals greatly reduced the volume and concentration of I I I I I I I I I I I I I I I I I I I 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 contaminants remaining in the on-Site soils, thereby minimi the potential for contamination movement or direct contacts The removals, the remedial investigation, the feasibi study, and the risk assessment, conducted under the oversigh the U.S. EPA, were entirely funded by the three companies at cost exceeding three million dollars. The feasibility study evaluates the possible remedies that could be used to clean up the Site. The EPA has propose preferred alternative of pumping and treatment for groundwatei contamination and on-Site thermal desorption for soil clean-uF with incineration as a backup technology. CIBA-GEIGY, Kaiser, and Olin support the EPA's preferre, alternative of pumping and treatment for the groundwater clean-up. Pesticides have been found in the groundwater at the Site. A pump and treat system using activated carbon is proven technology for removal of pesticides from groundwater. The discharge of treated groundwater to the Moore County sewer system would comply with pre-treatment requirements and have no impact on the receiving facility. The pump and treat system could be in place within three months after the design is complete. However, Olin, CIBA-GEIGY, and Kaiser do not support the EPA's proposed preferred alternative of on-Site thermal desorption for the soil clean-up with incineration as a backup technology. We do not support the alternative because of the I I I I I I I I I I I I I I I I I I I 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 11 four following reasons: Technology. First of all, thermal desorption is an undemonstrated technology for the treatment of pesticide contaminated soil. The EPA has stated that the preferred remedy would involve some testing to verify that the clean up goals can be reached. Testing will take time and the technology may not reach the clean-up goals; further delaying the clean-up of the Site. Quantity. The second reason is the quantity of contaminated soil involved. It is not large enough to justify on-Site soil treatment. The EPA states that because there are no federal or state clean-up standards for contamination in soil, clean-up goals are established to reduce soil contamination to within an acceptable risk range group. A risk assessment performed on the Geigy Site identified 650 cubic yards of contaminated soil that should be removed based upon a reasonable health based risk assessment. Even if the quantities are greater, quantities of less than 10,000 cubic yards would not be considered for on-Site treatment by most capable contractors. Space. The .third reason why we do not support the proposed alternative is the space needed for on-Site soil treatment. There is not enough area at the. Geigy Site to perform any on-Site soil treatment. The treatment unit would have to be located on neighboring property not involved in the I I I I I I I I I I I I I I I I I I I 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 12 clean-up of the Site. Time. The fourth and perhaps the most important reason why we do not support the alternative is the time that would be required should the EPA require us to use on-Site thermal desorption as the soil clean-up remedy. The EPA has stated implementation of two months. We believe that that number does not reflect the time involved for treatability studies, mobilization and trial of the thermal desorption equipment, as well as the actual soil processing time. We estimate that this time period would likely exceed one year and perhaps exceed two. Therefore, CIBA-GEIGY, Kaiser, and Olin all support alternative two, off-Site disposal for the soil clean-up remedy. This alternative would involve the excavation and off-Site disposal of contaminated soils exceeding the clean-up goals. The contaminated soil will be taken to either a fully approved out-of-state secure landfill or an out-of-state incinerator if needed. This alternative would be the most community-friendly alternative because it could be completed in a far shorter time frame, two months, than the EPA proposed alternative of on-site thermal desorption .. It would not involve untested technology. It would not require the use of any surrounding property, and best of all, it would meet all of the soil clean-up goals in the shortest time frame. This remedy is fully consistent with the soil removals I I I I I I I I I I I I I I I I I I I 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 13 conducted previously at the Geigy Site. Those removals were completed with very little environmental or community impact. This final action for the Geigy Site can be handled in the same way, quickly and efficiently by selecting the off-Site disposal alternative. CIBA-GEIGY, Kaiser, and Olin have worked with the EPA in the clean-up of the Geigy Site in an environmentally appropriate and safe manner. We wish to continue in that manner and request that the EPA use an environmentally appropriate clean-up remedy for this Site based upon the facts involved with this Site. I encourage the citizens of Aberdeen to voice their support for the alternative of off-Site treatment and disposal and encourage the EPA to listen. Thank you for your attention. We will be submitting additional written comment to the EPA within the comment period. * * * DIANE BARRETT: Anybody else want to make a statement or ask questions? The floor is open. * * * PHYLLIS KALK: My name is Phyllis Kalk, K-a-1-k. I am the Chairman of the.Natural Resources Unit of the League of Women Voters of Moore County. I would like to ask two questions and then make a statement. First question is, there are some drums that are on the eastern end of the Site, and they are probably about as tall as this chair. I think there are I I I I I I I I I I I I I I I I I I I 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 14 probably about 15 or 20 of them. What is in those? * * * GIEZELLE BENNETT: That was left from the remedial investigation and that's just decontamination water and soil from drilling the wells and things. That's going to be disposed V of pretty soon. * * * PHYLLIS KALK: My next question was, when you showed the thing about the water and you said that after it came out of the wells that you would treat the water. If the water is not to your standards will you just keep treating it until it is okay to put in the sewer system? * * * GIEZELLE BENNETT: Right. We aren't going to discharge it until it meets those clean-up rules that were in that table. * * * PHYLLIS KALK: As to Mr. Richards' comment about alternative two, my only comment about that is that North Carolina has been shipping their junk to other states for many years, and I think it would be real nice if we started taking care of our own. Thank you. * * * DIANE BARRETT: Any others statements? * * * RICK JOHNSON: My name is Rick Johnson. I'm the I I I I I I I I I ~. I I I I I I 8 I I 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 15 President of Moore Forest Local Environmental Group. I really just looked over this this evening, so I'm not real up on everything, but I just want to say that the organization that we represent, we are opposed to thermal desorption and incineration of any kind, but we are also opposed to taking materials off-Site for treatment. And so we are in sort of a dilemma here. We don't have an alternative. We haven't come up with one yet. We don't have an alternative yet but what we would like to see is some type of technology that can treat hazardous waste on-Site without burning it and putting it into our atmosphere. Thermal desorption might be the answer but we believe you at least have to dechlorinate. It seems like there ought to be a way--a feasible way of treating those two compounds on-Site without having to move it across state lines or anywhere else. * * * DIANE BARRETT: Are there any other questions or statements? * * * PHYLLIS KALK: I know you told us you didn't want to talk about the other four Sites on the other side of the highway, but the reason I am asking you about them is, have you thought about would it be at all feasible to wait until you're going to clean up the other four Sites and take the contaminated soil from the I I 1 I 2 3 I 4 I 5 6 I 7 I 8 9 I 10 I 11 12 I 13 I 14 15 I 16 I 17 18 I 19 I 20 21 I 22 I 23 24 I 25 I 16 211 Site and take it and clean it up at the same time you clean up those other four Sites? Is that at all feasible? * * * GIEZELLE BENNETT: Well, we aren't looking at that at this time. One of the main reasons is most clean-ups are going to be performed by the responsible parties that are responsible for the waste at each of those Sites and some of them are the same but some of them are different. So when you start mixing waste like that then you start mixing liability as well, so it opens up a whole lot of other questions and concerns. * * * BILL SHELLER: My name is Bill Sheller and I'm with OHM Corporation. What was the main criteria for thermal desorption as the alternative choice? * * * GIEZELLE BENNETT: Well, like I said, we have nine criteria. First, it has to reduce the risk to the public. But one of the main things we consider is in North Carolina they encourage, as much as possible, on-Site treatment of waste. I don't know, maybe the person from the state would like to talk to that. But in ad_dition to that this is the alternative that was picked at the Aberdeen Site as well. That Site is about nine months to a year ahead of this one so some of the treatability tests and stuff that they do will apply to this Site. I I I I I I I I I I I I I I I I I I I 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 * * * RICK JOHNSON: How long are we talking before anything actually gets done if we do it through thermal desorption? * * * 17 GIEZELLE BENNETT: What you are looking at is we have to wait until the public comment period is over until we issue our record decision. After that we go onto negotiations with the responsible parties in order to do the work, and that can take anywhere from four to six months. Then after that, they have to design the treatment system, which takes about a year. So you are looking at probably about a year-and-a-half before anything starts no matter which alternative we pick. * * * RICK JOHNSON: No matter which, so even if we went with Olin Chemical Company's suggestion it would be still a year-and-a-half to two years. * * * DIANE BARRETT: Any other statements or comments anybody wants to make? * * * CLAUDIA MADE: My name is Claudia Made. I spoke with Mr. Richards earlier today and we explored something. If the PRP's have their preferred method of cleaning it up, he said they would move it out of state, out of the compact states, and I wonder if he could elaborate a little bit about that, what I I I I I I I I I I I I I I I I I I D 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 18 advantage that might be. * * * CURT RICHARDS: We have been told that there is some concern in the State of North Carolina in regard to the compact, some of you that know what that is. There are several states that got together and said we will divide up how we handle our hazardous waste. If you do this then we will do this for you. Well, North Carolina has not lived up to some of their obligations, and so they have basically been thrown out of the compact. We are looking to take the soils outside of that region in order to avoid any conflict/within the group of states, and that would be our intention by the way. * * * RICK JOHNSON: Could you tell us, Curt, how quickly the clean-up would occur if you had your way of doing it? * * * CURT RICHARDS: I can't answer that. There are some technical people in the room. * * * JIMMY CLOONAN: My name is Jim Cloonan. If off-Site disposal were to be.selected as the remedy for the Site, I can't speak directly for them, but I believe the negotiation period might be quicker than was indiciated by the EPA. The design period would be much less involved and would be more along the lines of preparing work plans that would be similar to those I I I I I I I I I I I I I I I I I I I 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 19 conducted at the Site rather than trying to design three separate phases. Time wise, I think once the negotiations were done we could have a contract within two months and the removal would take another month. I think for thermal desorption or incineration the designed time frame--we have just been selected to do another thermal desorption design--that period would be about three years following negotiations with the EPA. * * * BRUCE NICHOLSON: My name is Bruce Nicholson and I'm with the State of North Carolina Superfund section, and it is the responsibility of the Superfund Section to perform the state's oversight for Superfund sites. I'm here today to gauge what the community interests are on this site. Some comment has been made about the state's policy· for preference for on-Site treatment. There are really two reasons for that policy. The most important one is that it be demonstrated that the technology chosen be protective of public health. Once that is satisfied, then the State of North Carolina would prefer on-Site treatment technology to off-Site disposal. Given that statement of the current policy, if there is any questions about that, I would be happy to take them. * * * HOMER GRUBBS: My name is Homer Grubbs and I'm also I I I I I I I I I I I I I I I I I I I 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 20 associated with CIBA-GEIGY. Wouldn't impracticability in terms of putting a desorber on the site which is too small to accommodate it, plus the time frame indicated also, play into those factors under the state's policy? * * * BRUCE NICHOLSON: There certainly could be a situation where Site space constraints could cause the technology to be more expensive. I think the key point for protectiveness of the public health are the results of the treatability study and there are issues to be worked out and question about that. * * * RICK JOHNSON: Are there any on-Site treatment technologies that don't involve thermal desorption or incineration? * * * GIEZELLE BENNETT: I don't know. It may be. It's just that we don't know about them for this Site, and they were not considered in our alternatives that we looked at. * * * PHYLLIS KALK: Have you tested the thermal desorption? Was there a Site in the northeast somewhere that you were going to test? Do you know if that has been tested yet? * * * GIEZELLE BENNETT: No. I don't know, but like I said, it was chosen in Aberdeen and Aberdeen is about nine months to a I I I I I I I I I I I I I I I I I I I 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 21 year ahead of this one so all the results of those tests, we'll definitely look at for this Site. * * * BRUCE NICHOLSON: Also, for the record, I would like to state although it does state in the fact sheet here that the state has absolutely concurred with the proposed plan, official concurrence has not been given. That is given at the stage where the decision is signed, so that's one of the reasons why I'm here tonight to understand what the community interests are. So all that goes into our final decision process. * * * UNIDENTIFIED SPEAKER: You had mentioned depending on what vendor, what sort of criteria would the EPA look at to qualify thermal desorption units? What sort of design criteria, whether it be a good design or a bad design? GIEZELLE BENNETT: Well, they would have to be able to demonstrate, I suppose, that they are able to perform the work per the design that was approved by EPA. From what I understand, there are a number of different ways to treat the gases that come off the soil, and that depends on the vendor. Some use carbon to absorb the gases. Some break it down and put it in a liquid and dispose of that liquid, so we didn't want to pick one of those and then limit the number of people who may be able to do. the work. * * * I I I I I I I I I I I I I I I I I I I 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 22 PAGE BURNS: My name is Page Burns and I have two questions. Thermal desorption was the only choice that you showed up there as your way of handling the on-Site contamination. That was the only on-Site method that you were considering? * * * GIEZELLE BENNETT: The other was on-Site incineration. That's a proven technology that has been used in the past. What we have said is if for some reason the thermal desorption is shown that it doesn't work or if the cost skyrockets, you know, if it comes down to only one person and he charges a million dollars for it or something so cost is prohibited, then we will fall back on on-Site incineration. * * * PAGE BURNS: I think it was at one of the other meetings I was at in Aberdeen, they were talking about in-situvitrification as an option that they were considering, and their problem with that was, one, that that was supposedly very expensive when compared to thermal desorption, but it seems like if you have a space problem and, of course, on-Site removal that CIBA-GEIGY was talking about is very expense, would that be an option that would solve the Site spacing problem as well as, you know, dealing with concerns about moving the contamination out of the state? Why wasn't that considered? * * * I I I I I I I I I I I I I I I I I I I 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 23 GIEZELLE BENNETT: As far as the in-situvitrification, I think that was considered. I don't really remember why it was thrown out for this Site particularly. One thing is when you do a treatment like in-situvitrification then you always have restrictions on what can be done on that property. When you do something like on-Site thermal desorption you are saying, "All right. Now, we can have a child come on here." It is clean until somebody else comes along and contaminates it. You know, we consider that a very permanent remedy without any holds or bars on it. I don't know as far as the space thing for thermal desorption. You know, we'll have to look at that during the remedial design. * * * DIANE BARRETT: Well, if there are no more statements or questions, we thank you for coming. Thank you for providing your comments. (The hearing was concluded at 7:45 p.m.) * * * * * * ~ ' ' ·1 I I I I I I I I I I I t I ,- I I I 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 5-9 STATE OF NORTH CAROLINA COUNTY OF CUMBERLAND 24 I, Sonja L. Reeves, a Notary Public in and for the state of North Carolina, duly commissioned and authorized to administer oaths and to take and certify depositions and hearings, do hereby certify that the hearing was reported by me verbatim and then reduced to typewritten form as set forth .in the preceding pages; that the foregoing is a true and correct transcript of said proceedings to the best of my ability and understanding; that I am not related to any of the parties to this action; that I am not interested in the outcome of this case; that I am not of counsel or in the employ of any of the parties to this action .. IN WITNESS WHEREOF, I have hereunto set my hand and affixed my official notarial seal this 1st day of April, 1992. My commission expires: September 28, 1994