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HomeMy WebLinkAboutNCD981927502_19910501_Geigy Chemical Corporation_FRBCERLA FS_Addendum to the RI FS Work Plan-OCRI I I I I I I I I I I I I I I I I I I ADDENDUM TO THE RI/FS WORK PLAN GEIGY CHEMICAL CORPORATION SITE ABERDEEN, NC Task 12 -Ground Water Investigation 12.1 Monitoring Network Based on the results of the initial hydrogeologic investigation conducted at the site, an expanded ground water assessment program is necessary to further characterize the hydrogeologic conditions and contaminant distribution at the site and vicinity. As part of this expanded assessment program, seven shallow monitoring wells (Wells MW-7S through MW-13S) will be installed to further delineate the lateral extent of site-specific contaminants and to evaluate the presence of regional contaminants in the uppermost (water table) '• aquifer (Figure 1).' The seven shallow monitoring wells will be located in off-site areas to the north and south which are downgradient or potentially downgradient of the limits of the existing monitoring well network. As an additional task, two deep on-site monitoring wells (MW-14D and MW-15D) will be installed within the intermediate aquifer at the locations shown in Figure 1. These wells will be located in the eastern portion of the site in areas which are upgradient of the existing monitoring well network. In addition to attempting to delineate the areal extent of contaminants, the locations of the seven shallow monitoring wells will also provide supplemental information on stratigraphy and the lateral continuity of the uppermost aquitard. The well borings will be drilled to the top of this aquitard. The seven shallow monitoring wells will also provide water level data which will be used to determine the ground water flow pattern in the vicinity of the site. In particular, the shallow monitoring well locations will provide an expanded network of water level data points that is needed to determine ground water flow directions around the topographic divide at the site. Three of the shallow monitoring wells (MW-7S, MW-8S, MW- 9S) will be installed north of the site at positions which are located north of this topographic I I I I I I I I I I I I I I I I I I I divide. These wells will serve to define ground water flow and to assess potential contaminant migration to the north of the site. In the event a northwest component of ground water flow exists at the site, these monitoring wells would be positioned downgradient of existing wells MW-2S and MW-3S, where shallow ground water contamination has been detected, and the east end of former Warehouse A, where potential source areas of contaminated soil were located. The four shallow monitoring wells to be installed south of the site (MW-10S, MW-11S, MW- 12S and MW-13$) will allow a determination of the ground water flow pattern associated with a topographic basin in that area. The axis of the topographic basin, located approximately 200 feet south of the railroad tracks, may coincide with a ground water divide. This divide is anticipated to parallel another probable ground water divide located directly beneath the site. Thus, for the area located south of the railroad tracks and north the topographic basin, the ground water flow direction in the shallow aquifer is anticipated to be to the south or southwest. The ground water flow direction in the shallow aquifer located south of the topographic basin is anticipated to be to the northwest. The proposed southernmost monitoring well (MW-11 S) would therefore allow an assessment of ground water quality south of the topographic basin. The two deep monitoring wells (MW-14D and MW-15D) will be installed in order to better understand upgradient site boundary conditions and to assist U.S. EPA in determining the source of the regional presence of trichloroethene in the intermediate aquifer. The location of these wells in relation to existing wells MW-1 D, MW-4D and MW-6D will enable the calculation of the hydraulic gradient and ground water flow direction within the intermediate aquifer near the eastern site boundary. The shallow monitoring wells are anticipated to be drilled by the hollow-stem auger method. The deep monitoring wells are anticipated to be drilled by hollow-stem and/or mud-rotary methods. Except as noted below, the drilling methods, well construction, and well development procedures will be the same as for the initial monitoring well drilling program as described in Section 12 of the RI/FS Work Plan. Soil cuttings generated during the I I I I I I I I I I I I I I I I I I I installation of monitoring wells will be containerized and stored on-site pending the results of analyses for site-specific parameters. The newly installed shallow monitoring wells will be sampled and analyzed for Target Compound List (TCL) pesticides and volatile organic compounds. Where appropriate, selected wells from USGS well cluster GS-02-02 will be sampled for TCL pesticides. The ground water sampling procedures in Section 12 will be followed. Ground water samples will be collected from the shallow monitoring wells in accordance with Section 12.1 o of the RI/FS Work Plan. The two newly installed deep monitoring wells will be sampled and analyzed for TCL pesticides and volatile organic compounds. In order to further evaluate whether the detection of trichloroethane in Phase I RI monitoring wells MW-4D and MW-6D is site related, ground water samples will be collected from well PZ-1, existing D-series monitoring wells, and the Allred and Powder Metals Products wells. The Allred and Powder Metal Products wells are located hydraulically upgradient of the site. Ground water samples from the above wells will be collected in accordance with Section 12.10 of the RI/FS Work Plan and analyzed for TCL volatile organic compounds. A summary of the proposed ground water analytical program for this phase of the RI is presented in Table 1. -... ---- - - ---- TABLE 1 GEIGY CHEMICAL CORPORATION SITE RI (PHASE 4, STEP 2) ABERDEEN, NORTH CAROLINA PROPOSED GROUNDWATER ANALYTICAL PROGRAM SAMPLE LOCATION MW-10 MW-4D MW-6D PZ-1 MW-7S MW-BS MW-9S MW-10S . MW-11S MW-12S MW-13S MW-14D MW-15D USGS well cluster GS-02 Allred well Powder Metals Products well NOTES AQUIFER Intermediate Intermediate Intermediate Deep Shallow Shallow Shallow Shallow Shallow Shallow Shallow Intermediate Intermediate To be determined To be determined To be determined SCHEDULED ANALYSIS TCL volatile organic compounds TCL volalile organic compounds TCL volatile organic compounds TCL volalile organic compounds TCL volatile organic compounds & pesticides TCL volatile organic compounds & pesticides TCL volatile organic compounds & pesticides TCL volatile organic compounds & pesticides TCL volalile organic compounds & pesticides TCL volatile organic compounds & pesticides TCL volalile organic compounds & pesticides TCL volatile organic compounds & pesticides TCL volalile organic compounds & pesticides TCL pesticides TCL volatile organic compounds TCL volatile organic compounds . 1. Above listing excludes equipment rlnsate, lleld blank, trip blank, matrix spike and matrix spike duplicate samples. 2. Inclusion ol site specific metals In sample analyses is pending U.S. EPA review of split sample data. - - --- COMMENTS Existing RI monitoring well Existing RI monitoring well Existing RI monitoring well Existing production zone well Proposed Phase 4 RI monitoring well Proposed Phase 4 RI monitoring well Proposed Phase 4 RI monitoring well Proposed Phase 4 RI monitoring well Proposed Phase 4 RI monitoring well Proposed Phase 4 RI monitoring well Proposed Phase 4 RI monitoring well Proposed Phase 4 RI monitoring well Proposed Phase 4 RI monitoring well Speclllc well to be determined - Sample collection dependent upon access approval Sample collection dependenl upon access approval - I I I I I I I I I I I I I I I I I I I PROPOSED WELL NUMBER MW-7S MW-8S MW-9S MW-10S MW-11S • • • • • • • • • • • Proposed Monitoring Wells Geigy Chemical Corp. Site Aberdeen, North Carolina FUNCTION Delineate shallow aquifer pesticide plume in the area located potentially downgradient (west and northwest) of existing monitoring well network. Evaluate groundwater flow pattern in the area between existing monitoring well network and Municipal Well #4 (near nose of topographic divide). Delineate shallow aquifer pesticide plume in the area located potentially downgradient (northwest and north) of MW-2S and Warehouse B. Evaluate groundwater flow pattern on north side of topographic divide located along Hwy. 211. Delineate shallow aquifer plume in the area located potentially downgradient of Warehouse A and Warehouse B. Evaluate groundwater flow pattern on north side of topographic divide located along Hwy. 211. Delineate shallow aquifer pesticide plume in the area located downgradient (southwest) of MW-4S and east end of Warehouse A. Evaluate groundwater flow pattern south of site . Delineate southern limit of shallow aquifer pesticide plume. Evaluate groundwater flow pattern on south side of topographic basin located south of site. Monitor quality . of groundwater potentially flowing toward topographic basin from the south or southeast. I I I I I I I I I I I I I I I I I I I PROPOSED WELL NUMBER MW-12S MW-13S MW-14D MW-15D Notes: Proposed Monitoring Wells (Cont.) Geigy Chemical Corp. Site Aberdeen, North Carolina FUNCTION • Delineate shallow aquifer pesticide plume in the area located downgradient (southwest) of MW-5S, MW-6S and Warehouse B. • Evaluate groundwater flow pattern south of site. • Assess potential affects on groundwater resulting from former operations at off-site foundation structure. • Delineate shallow aquifer pesticide plume in the area located potentially downgradient (west and southwest) of existing monitoring well network. • Evaluate groundwater flow pattern in the area between the existing monitoring well network and Municipal Well #4 (Near nose of topographic divide). • Delineate intermediate aquifer TCE plume along upgradient site boundary. • Evaluate groundwater flow pattern in intermediate aquifer. • Delineate intermediate aquifer TCE plume along upgradient site boundary. • Evaluate groundwater flow pattern in Intermediate aquifer. In addition to the groundwater quality and water level monitoring functions, the proposed monitoring well borings will further characterize the lateral extent of the aquitard. The intermediate wells will also determine the thickness of the aquitard. ------ - - - - - - - -- --- RI/FS Schedule -Phase 4 Geigy Chemical Corporation Site 1991 1991 Mardi April Ma7 June Jul1 August September October November December Janu.,, February Man:h April TASKS 12a. Submit Proposed Addendum to ■-· Wort Plan for Phase 2 GW Srudy 12b. EPA Review of Addendum Mum 5 -April 17 12c. Finali7.e Addendum to Wort Plan -April II -Moy 2 12d. Obtain Well Pennill end April I B • Juno I Access Agn,emenll 12e. Install Monitor Wells• June3-July9 12f. Develon Wells lunD 10 .July 16 12g. Sample Wells -July 22 · 26 12h. Laboratory Analysis of Samples July 29 . August 19 12i. Data Validation . _,._ August 19 -September 9 16a. Submit Draft RI Reoort I October 14 16b. EPA Review of Draft RI Octobcrl5-NovcmbcrlS 16c. Submit Draft FS • Novcmber6 16d. EPA Review of Draft FS Nov~ 7 -December 4 16e. Submit Response to EPA --N~cmber 19 · Docembcr9 Commenll on Draft RI J6f. EPA Review of RI Response 16g. Submit Response to EPA Commenll on Draft FS 16h. Submit Draft RI . 16i. EPA Review ofFS Response 16j. Submit Draft Final FS 16k. Public Comment Period 161. Public Meeting 16m. Submit Final FS (If Necessarv)•• • Drilling schedule contingent upon completion of soil removal activity per consent order. •• Assumes proposed scope of work generates all required data. . -Dccanber 13 · 23 Dccembet 2 · Jamwy 3 --December 24 -January 6 _ Deoember 30 -January 13 ....L. January 20 -Febnwy 5 February 12 -~ 9 ■ fdmwy 12 Much 27 · April 6 -- - ------------------- • I TABLE -- GROUND WATER FIELD PARAMETER DATA GEIGY CHEMICAL CORPORATION SITE ···•MONITORWELLLOCATION \ I• /.· CpNDUCTIVI~./ ····••· < pH •• . • . < .·• ··•· ·•• > · Ii. ii (umhos/cm). •• • (itct, units) MW-1S 45 6.85 MW-10 18 5.8 ... ::· .. :·-::·::.,--_:--.•·:--.·-·.-:-:-.-:·-.-·-· . :·:··::·-:·,:·. ::-·=.'':•, -··. • :.// • . :\. ·. I. • . :· MW-2S 886 4.01 . : :.,-;-_:_ ,:.-. : ... ,. _ .. :·, ,-, : .''-, MW-3S 516 6.8 MW-4S 50 4.58 . ,·•, . :,;-·. • . ·_.-__ . . . -:-: MW-40 33 6.81 I •'• _-._ .·_ .· .-· . MW-5S 87 4.26 ··-. :-·-·- : .. .. MW-6S 1740 3.82 . , ... .· . .. · MW-60 · 18 5.72 .. _: .. · PZ-1 77 6.77 . WSW 17 5.57 > TEMPERATURE 1 ·•··•··· (degreeJ c;e~tigractJ). .· 16.5 17.0 i/f/.···•<.:: .· •... ·•: ........... ::-:.-··.•· 20.1 18.0 18.7 19.5 17.7 . {> ..... •• •. ·:· iO :_ i 19.0 17.0 18.5 18.0 - - --- >1.~ MONITOR WELL CONSTRUCTION DETAIJS GEIGY CHEMICAL CORPORATION SITE ABERDEEN, NORTH CAROLINA •.: •· .:.: i. ·. ·•> · ·· GROUND LEVEL· •TOP .OF. CASING; .... •TOTAL WELL WELL .x [)ATE COMPLETED . §1..EVATION . ELEVATION > ) ..•..•...•.... •··D(ttE_.· .• PTb···gHI).··.·· • .· • • •::, .. ·· · ···· ....... ,.)(tt.·msl}: > •: I//.:'· (ft. msQ ·•.·· · .•. ---- MW-1 S 8-2-90 481.4 484.04 63.4 0-10 51.3-61.3 430.1-420.1 . ·. '' . . ··.,:,, . · . MW-1D 10-8-90 482.0 484.83 109.3 0-7,0-65 87.1-107.1 394.9-374.9 _-.·-. . ._, .. ... . MW-2S 8-10-90 472.7 475.52 55.5 0-10 43.3-53.3 429.4-419.4 .. .. MW-3S 8-7-90 459.7 462.26 42.0 0-10 29.8-39.8 429.9-419.9 .. ·-;:_·_,:.::". . ·. ·: :, :'.i':-. ·: .. 1--·: .>.':-• .:. · ·. ,: .... •·•· ... I· .=·' .. _. : .. .=._:·:·:.L::::.:c·::.-:-,, ·:::_:-<I::·:.-:::·:::--_._, .. , ...... •-=·<':/::.:, :: MW-4S 8-22-90 470.8 473.47 39.3 0-10 27.2-37.2 443. 6-433. 6 . • ... MW-4D 9-25-90 470.8 473.99 95.2 0-9,0-52 73.0-93.0 397.8-377.8 . -· ·. -· . . . . ._,· .. · •• • . . MW-5S 8-17-90 468.2 471.34 44.3 0-10 32.1-42.1 436.1-426. 1 . · ·.·• •.. ·.-.-. . MW-6S 8-14-90 462.1 464.71 44.4 0-10 32.2-42.2 429.9-419.9 ·. . · .. .. MW-6D 9-18-90 462.6 465.49 89.1 0-9,0-48 66.9-86.9 395.7-375.7 .. . . PZ-1 10-4-90 462.7 465.65 132.7 0-10,0-50,0-99 110.5-130.5 352.2-332.2 NOTES: msl = mean sea level bgl = below ground level - I I I I I I I I I I I I I I I I I I •• DRAFT GROUND WATER ELEVATION DATA GEIGY CHEMICAL CORPORATION SITE ABERDEEN, NORTH CAROLINA MW-4O 473.99 10-29-90 75.43 398.56 11-6-90 75.25 11-7-90 75.40 11-9-90 75.32 11-13-90 75.54 12-12-90 75.37 1-4-91 75,67 . •,· MW-5S 471.34 10-30-QO 40.32 11-6-90 40.15 11-7-90 40.15 11-9-90 40.11 11-13-90 40.10 12-12-90 4-0.04 1-4-91 4-0.28 . MW--6S 464.71 10-29-90 41.55 11-6-90 41.50 11-7-90 41.50 11-9-90 41.47 11-13-90 41.43 12-12-90 41.28 1-4-91 41.44 ····:-,.·_.,• . -·y, . , . MW-6D 465.49 10-29-90 68.85 11-6-90 68.75 11-7-90 68.92 11-9-90 73.21 11-13-90 68.98 12-12-90 68.85 ,_ 4-91 69.03 .... : : ". ,. : . ,·,;': .. · .·. • .. ,, ... : ·•., ... PZ-1 465.65 10-29-90 71.86 11-7-90 70.85 11-9-90 70.81 11-13-90 70.88 12-12-90 10.n ,_ 4-91 70.95 :-. ,,. :···:• .• ... ~ I...:- WSW 481.89 11-13-90 85.67 toe = top of casing msl = mean sea level WSW = on-site water supply well --= instrument error, no data collected 398.74 398.59 398.67 398.45 398.62 398.32 .. 431.02 431.19 431.19 431.23 431.24 431.30 431.06 423.16 423.21 423.21 423.24 423.28 423.43 423.27 .. ' . 396.64 396.74 396.57 - 396.51 396.64 396.46 ' 393.79 394.80 394.84 394.n 394.88 394.70 •••, ·.· .. :, '• .. . .. . ·::·:., ·•,•, 396.22 ... , .. :, ' I I I I I I I I I I I I I I I I I I I w~y· TOP OF CASING ELEVATION ... :..-. ' . ·.. . .::·.:,-·. (ft." msl) MW-1S 484.04 .:· MW-1D 484.83 . . .. MW-2S 475.52 . .• . MW-3S 462.26 DRAFT GROUND WATER ELEVATION DATA GEIGY CHEMICAL CORPORATION SITE ABERDEEN, NORTH CAROLINA DATE OF MEASUREMENT . DEPTH TO WATER :, I•: ... -: ... ,:::· . ··•···. ·• 1.:·,_:: ... '(rfb81~tOC). 10-30-90 48.15 11-6-90 48.05 11-7-90 48.00 11-9-90 47.88 11-13-90 47.96 12-12-90 47.87 1-4-91 48.09 .:,· .. 10-30-90 85.73 11-6-90 85.73 11-7-90 85.90 11-9-90 90.21 11-13-90 86.08 12-12-90 85.98 1-4-91 86.08 . ·.· 10-29-80 50.02 11-6-90 50.94 11-7-90 49.90 11-9-90 49.86 11-13-90 49.84 12-12-90 49.71 1-4-91 49.93 10-29-90 38.69 11-6-90 38.87 11-7-90 38.65 11-9-90 38.62 11-13-90 38.60 12-12-90 38.38 1-4-91 38.49 .-.: .. ,-.-::;::-.· .. • .. .• . ::· . MW-4S 473.47 10-30-90 38.44 11-6-90 38.25 11-7-90 38.20 11-9-90 38.12 11-13-90 38.18 12-12-90 38.03 ,_ 4-91 38.39 N?TEtt<· << <.•··•) < . i.. <.· / .·. ':-'·· ._·,:··:;.,. . , ... ,.,.,-,,:., )i >\ .......... · .. toe = top of casing msl = mean sea level WSW = on-site water supply well --= instrument error, no data collected ·• WATER LEVEL·ELEVATION ·1iiOmsl) 435.89 435.99 436.04 436.16 436.08 436.17 435.95 399.10 399.10 398.93 - 398.75 398.85 398.75 .· 425.50 424.58 425.62 425.66 425.68 425.81 425.59 423.57 423.59 423.61 423.64 423.66 423.88 423.n 435.03 435.22 435.27 435.35 435.29 435.44 435.08 I I I I I I I I I I I I I I I I I I I DRAFT SUMMARY OF WELL DEVELOPMENT STATUS GEIGY CHEMICAL CORPORATION SITE ABERDEEN,NC TOTAL ·••• W~~L. ·. . \'.OLUME ... ·•·. EVACUATED·· • • .. NUMBER (GALLONS) 1S 204 465 WATERCL.ARl1Y . . DURING. NO'{EMBER 1990 ·. SAMPLING · CLEAR I I I I I I I I I I I I I I I I I I I DRAFT SUMMARY OF SLUG TEST RESULTS GEIGY CHEMICAL CORP. SITE, ABERDEEN, NC MONITOR WELL 1.D. SHALLOW WELLS MW-1S MW-2S MW-3S MW-5S MW-6S INTERMEDIATE WELLS MW-10 MW-6D DEEP WELL PZ-1 HYDRAULIC CONDUCTIVITY (cm/sac) 8.0 E-04 2.2 E-03 2.5 E-03 1.0 E-02 3.3 E-03 K (shallow) a 3.8 E-03 2.7 E-03 9.1 E-03 K (int)• 5.9 E-03 1.5 E-03 Hydraulic Conductivities calculated by Chapuis (1989) Method. cm/sac a centimeters per second K = average hydraulic conductivity Slug tests conducted 12-12-90 and 1-4-91 by ERM-Southeast. For MW-4S and MW-4D, water levels recovered almost immediately during test. Unable to obtain enough water level measurements for hydraulic conductivity calculations. ----- - DRAFT SAMPLE ID: AGS-GW-WSW AGS-GW-10 LAB NUMBER: EA117 ERIH COMMENT 6: WA.TEA SUPPl Y WELL ~·····•'' wm~iy~:~i;;;~i'ISl!;'+? :1: ~··•· ALPHA-BHC BETA-BHC OELTA-BHC GAMMA-BHC HEPTACHLOA ALDRIN HEPTACHLOA EPOXIOE ENDOSULFAN I OIELDAIN 4.4'-0DE ENDAIN ENDOSULFAN II "·•·-ooo ENDOSULFAN SULFATE 4.4'-ODT METHOX'l'CHLOA ENOAIN KETONE ALPHA-CHLORDANE GAMMA-CHLORDANE TOXAPHENE AROCLOA-1016 AROCLOA-1221 AAOCLOA-1232 AROCLOR-1242 AAOCLOR-1248 AAOCLOR-1254 AAOCLOR-1260 NOTES: AESUL TS IN UGfL (PPS) J .. THIS RESULT IS A OUANTIT A TIVE EST NO CONCENTRATION ENTERED FOR ANAL YTES NOT DETECTED --- GEIGY CHEMICAL CORPORATION SITE GROUND WATER SAMPLING RE SUL TS OF PESTICIDES ANAL 't'6ES NOVEMBER 13-18, IWQO -- - -- --- AGS-GW-1S AGS-GW-2S AOS-GW-3S AGS-GW-45 AGS-GW-4D AGS-GW-5S AGS-GW--6S AGS-GW-GD ~GS-GW-PZ-1 AGS-GW-7S ERl\'IO ER.200 ER193 ER201 ERIH ER202 EA203 ER192 ER195 ER191 BLIND $PUT -!l~''.~l; ·_"c,. 'II ~Q{Y' ,;,"?_;·.:.C,'::).''.._·.,_.,, ·:-. .·· {\:-',,,, ,_,,_,;, \-; }).\.::· .~ . ,· ; C;._ ;'•> i••::,,.; -:• ,., ,., " ,., 38 .. , ... 33 " " 39 ,., 55 " ,. 2.8 0.37 0 53 .. JO 0,11 0.39 J 0 22 0.39J 0.36 --0 23 0.77 J 0 58 J 9.6 0.79 J •• - -... ---- - DRAFT SAMPLE ID: AGS-TB-1114 AGS-TB-1115 LAB NUMBER: ER189 ER196 COMMENTS: TRIP BLANK TRIP BLANK lil!llil!;I ALPHA-BHC BETA-BHC DELTA-BHC GAMMA-BHC HEPTACHLOA ALDRIN HEPTACHLOR EPOXIDE ENDOSULFAN I DIELOAIN 4,4'-DDE ENDRIN ENDOSULFAN II 4,4'-DDO ENDOSULFAN SULFATE 4,4'-DDT METHOXYCHLOA ENDRIN KETONE ALPHA-CHLORDANE GM.AMA-CHLORDANE TOXAPHENE AROCLOA-1016 AAOCLOA-1221 AROCLOR-1232 AAOCLOA-1242 AAOCLOR-1248 AROCLOA-1254 AAOCLOA-1260 NOTES: RE SUL TS IN UG/L (PPB) J = THIS RESULT IS A OUANTIT ATIVE NO CONCENTRATION ENTERED FOR ANALYTES NOT DETECTED ---- GEIGY CHEMICAL CORPORATION SITE GROUND WATER SAMPLING RESULTS OF PESTICIDES ANALYSES NOVEMBER 13-16. 1990 AGS-TB-1116 AGS-RBP-1116 AGS-RBB-1116 ER204 EA205 EA206 TRIP BLANK RINSE BLANK RINSE BLANK --- - - -- AGS-GW-70 AGS-GW-9S EA198 ER199 EPA QA SAMPLE EPA QA SAMPLE 0.84 0.72 0.85 1.0 0.81 ------ SAMPLE ID: AGS-OW-WSW AGS-OW-10 LAB NUMBER: EA187 ER118 COMMENTS: nATER SUPPLY WELL - AOs-GW-1S ERlliMl --- DRAFT GEIGY CHEMICAL CORPORATION SITE GROUND WATER SAMPLING METALS DATA NOVEMBER 13-UI. 1ggo AGS-GW-26 AGs-GW-3S AOS-OW-tS ER200 EA1113 ER201 - - --- - - AOS-GW-40 AGS-GW-5S AOS-GW-8S AGS-GW-80 GS-GW-PZ-1 AGS-GW-78 EA1114 EA202 ER203 ER1'12 ER1115 ERUII BLIND SPLIT OF GW-1S ALUMINUM 7920 172 B 17100 1680 1040 3650 872 40 3 B 214 2570 1718 ANTIMONY ARSENIC 2.2B 268 28 3.58 BARIUM 3.1 B 25,18 13.38 "' 78.6B 13.48 22.18 15.8B 1568 13.2B 318 8.18 BERYLLIUM CADMIUM , .• ,. 6.3 76 CALCIUM 6318 33708 4388 37000 moo 918B 4410B 28508 411800 1010B 7040 3898 CHROMIUM 11.58 "-' a 4.3 B 058 COBALT 22.78 18.08 258 COPPER 1180 23.11 B 14.98 IRON mo 4280 ... 8'4.38 38.7B 3290 2180 78.118 1750 550 LEAD " 10.2 1.88 2.1B a.2 1.48 28 2.88 MAGNESIUM 2488 15408 ,.,,e 1<1200 38008 7458 14108 19108 18100 15208 11208 .... MANGANESE 42.2 Ql.2 13 38 10, 151.2 11.28 118 16 .... 14.78 157 g_g9 MERCURY 1 NICKEL POTASSIUM 8758 109 e 71'00 21000 1010 32008 100000 , .. 8 111 e 7,149 SELENIUM 2.28 1.28 1.28 2 58 2.48 18 3.78 SILVER 106 5.38 SODIUM 2010B 4620B 8150 12000 9120 0030 5070 4270B 12900 2780B 13600 7560 THALLIUM 1.28 VANADIUM 388 15.48 ZINC a36 ... , 19.78 230 2'3 11.QB 37.1 43.B "' 32.4 43.Q 15.B B CYANIDE .·,,'!,'•''" •,--:;,1::.=;•:'" :;::> . ."i .. :··· .. ,, , .... : · .. -~.:,: : ,:-: ' . ,•,· ~ _ .. ·: .. :-:. :·-,:,•:,·: ·=···· .; ,;··:=:.: .. · .. ' d ·' _ ....... · . •·•· '':•.: NOTES: RESULTS IN UGfl (ppb) 8 • THIS RESULT IS QUANTITATIVELY INVALID SINCE THE ANAL YTE WAS ALSO DETECTED IN A LAB BLANK AT A SIMILAR CONCENTRATION NO CONCENTRATION ENTERED FOR ANAL YTES NOT DETECTED - ------------- SAMPLE ID: AGS-TB-1114 LAB NUMBER: ER189 - - ---- - DRAFT GEIGY CHEMICAL CORPORATION SITE GROUND WATER SAMPLING METALS DATA NOVEMBER 13-16, 1990 AGS-TB-1115 AGS-TB-1116 AGS-RBP-1116 AGS-RBB-1116 AGS-GW-8S ER196 ER204 ER205 ER206 EA197 - - AGS-GW-70 ER198 COMMENTS: TRIP BLANK TRIP BLANK TRIP BLANK RINSE BLANK RINSE BLANK EPA QA SAMPLE EPA QA SAMPLE CONSTITUENT ALUMINUM 100000 807 ANTIMONY 143 ARSENIC 21.4 BARIUM 4.8 B 132 B BERYLLIUM 17.2 CADMIUM 4.5 B 4.9 B 7.3 11.5 CALCIUM CHROMIUM 4.1 B 22 COBALT 39.2 B COPPER 52.4 IRON 23 B 94800 427 LEAD 13.9 MAGNESIUM 85.5 B 645 B MANGANESE 3.2 B 2.5 B 2.7 B 3.6 B 3B 25.4 MERCURY 3.0 NICKEL 34.7 B POTASSIUM NA 781 B 675 B SELENIUM 13.8 SILVER 12.8 4.2 B SODIUM THALLIUM 13.6 VANADIUM 34.5 B 20.9 B 51.7 ZINC 32.4 13.4 B 18.1 B 35.9 16.0 B 20.7 47.00 CYANIDE 39.9 NOTES: RESULTS IN UG/L (PPB) B • THIS RESULT IS QUANTITATIVELY INVALID SINCE THE ANAL YTE WAS ALSO DETECTED IN A LAB BLANK AT A SIMILAR CONCENTRATION. 1 • METALS NOT ANALYZED DUE TO INCORRECT PRESERVATION. NO CONCENTRATION ENTERED FOR ANALYTES NOT DETECTED. -- AGS-GW-9S (1) EA199 EPA QA SAMPLE I~ SAMl'I..EID: LAI NUMBEJ;: COMMENTS: co,amru,;,,r CHLO&OMETHANE 11.0MOMETHANE V1NYL Clll-OIIIOE CIQ.oaOETHANE METirn.ENE CJtLOIIIDE ACETONE CA.alON DISUUU>E I.I-DICHLO&O£THEJ'IE I, 1-DIClllOIIOETHANE I .2-DICHLOIIO£TIIENE(TOT .'1.l CHLOIIOFOIIM I .l-DICIQ.OIIOETHANE l·IIJJANONE I, I. I -nlCHLOI.OETHANE CAA80N TTI'J:ACHLOIIIOE VINYL ACETATE POMODICIQ.OI.M:ETHANE 1.2 DICHLOI.ONOPANE CIS-1,J-OICHI..OIIOPflOl'ENE RICHI..OI.OETHENE DIPOMOCKLOI.OMETHANE 1.1, 2-TltlCIQ.OIIOE'HIANE IENZENE TaANS-1.J-OICtll.DaO"-Ol'ENE 11.0MOFOI.M 4-METHYL-2-PENTANONE 2-HEXANONE ttnAClil.OROETHENE 1.1, 2, 2-TEfa.ACIQ.OI.OETHANE TOLUENE CHLOIWIENZENE ETHl1.IENZENE STYltENE XYL.ENE (TOTA.LI NOTES: 1.ESULTS IN UGll. (ppl>I -- - -- AGS-OW•WSW AGS--OW-10 AGS-<iW-IS U:111 Htlll El\90 WATU SUPP'LY WELL "" '" ... DRAFT GEIGY CIIEMICA.L CORPORATION SITT Gl:OUND WATEJI SAMN.ING 1.ESULU OF VOLA.Tll.ES AHAl.VSEl f,IOVEMBEJI ll -16, 1990 AGS--OW-JS AGJ-GW-lS AGS--OW--<15 moo Ul9l "'" ,.,, I -THIS •E.Stn.T IS QU,.NlITATIVEl.Y INVALID SINCETllE ANALYTE WAS AUO DETI:'.CTED 1111 A L-\8 BLANK AT A SIMILAR CONl..'EN"RATION , _ nus RESULT IS A QUANTITATIVE UT. NO CONCENnATION ENTUED FOIi. Al'IALYTES 1"0T DETECTED -- - -- - - -- AG5--0W_.O AGS---GW·H AGS-GW-U AGS-GV/10 AGS-GW-,-Z-1 AGS--OW-1$ El.JU ERlOl ER20l EltltJ Elt19J E.l.191 IUHO S"-IT OfGW•IS , .. 11.0 " ----- - SAM"-EID: AGS TB•III• Ll.l NUMIEJI: U:119 COMMENTS: U.ll'Bl.ANK CONSTITUENT CHtOI.OMETHANE U0"40METHANE VINYL CHLOI.IDE CIILOIOETIIANE METHYUNE CHlOalDE ACETONE CAIION DISULFIDE 1.1-DICIILOI.OFTllENE I.I -DICll10f.0£THANE 1.l ·DICHLOl.0£TIIENE(f0T A.LI CHLOI.OFOltM I. 2 -DICHLOl.0£THANE l-lUTANONE l. I, 1-TlllClll.OllOETHANE CAIION TcnACHLOI.IDE VINYL ACETATE BIOMODIClll.OltME'lliANE U DICHLOI.O"-Ol'ANE CIS -1. J-DICIILOI.OPROftNE "D.IClllOltOETIIEr,lE DIIIJ.OMOCHLOI.OMETH.ANE I. 1.l· TIIICHLOltOETIIANE BENZENE TRANS-1. l-DICHlo«OPROPENE BIOMOfOIIM 4-MITllYL 2-PENTANOl'IE l HEXANONE f£TtAC1U..OI.OETIIENE 1.1 . l. 2 • TETRACIQ_Ol.0£THANE TOUJENE CHLOI.OBENZENE ETHnaENZENE SfYJ:ENE XYLENE (TOTAU NOlE.S, RES UL TS IN UGIL (rpbl AGS·U·llll U.196 RIP Bl.Ar,lk ----- DRAFT· GEIGY Cl(EMICA.l. COlf'OI.ATION sn'E CAOUNDWATU SAMl'l.lNG ltESllt.TS OF VOLHll.E.S AN,\U'SES NOVEMIEII. IJ • 16, 1990 AGS•Tl-11" AGS-llP-1116 UllM u:10, DIP IU.NK PUMP JINSE al.ANK AGS-lH-1116 AGS--GW-10 El11'.l6 EJU91 ...... EPA QA SAMPLE IINSE 111.ANK .. "" .. " ., " " ., " ,. " ., B • THIS IESULT IS QUANTITATIVELY INVALIO SINCE THE ANALYTE WAS ALSO DETECIEO IN A.LAS Bl.ANK 14.T A. SIMILAR CONCENTRATION I -THIS lt£5UL TIS A QUA.NHTATIVli i:S"T. NO CONCENTI.ATION ENTEUO FOR ANAI.YTES NOT Ol:.IEClT.0 ----- AGS-c;W-9$ "'" EPA QA SAMl't...£ --- SAMPI..E ID: LA8NUM8ER: COUMENTIII: CONSfflUENT PHENOi. 8'912-CHl.OAOETHYl)ETHER 2~HlOAOf'HEHOl. 1.~0A06ENZENE 1,4-0ICHI..OA06EHZENE BENZVl. ALCOHOl 1.2~0A08EHZENE 2-UETHYLPtlEHOl. BIS{2-CHl.OAOISOPAOPYl)ETHER 4-METHYLPHENOl. N-HITAOS0-06-H--PROPYt...AMINE HEXACN..OAOETHAHE Nl'TROBENZEME '"°"""""" 2-NITAOf'HENOl. 2,,t...l)IM£THYlPHENOl. BEHZOIC ACIO 819(2-CHI.OAOETHOXYJMETHANE 2.4-0ICHI..OAOPHENOl. 1.2,4--TRICHl.OA06ENZENE NAPffi"HALENE 4-CHl.Ofle».NlllHE HEXACH..OA08UTADIENE 4--Cttl.C>A0-4--METHnPHENOt. 2-METHYLNAPffi"HAl.ENE HEXACHLOAOCYCI.OPENT ADIENE 2,4.e-lRICHlOAOPHENOt. 2,4.6-TRICHlOROPHENOl. 2-CHl.OROHAPHTHAI.ENE 2-NITROANll.lNE DIMETHY1.PHTl1Al..ATE ACENAPHTH'l'\.ENE 2,a-.OJHTTROTOl.lJENE NOTES: RESULTS IN UOll <P9,bl J,. nus AESlA.T 15 AOUAHTITATIVE EST. -.. --- DRAFT GEIGY OIEMICAL COIIPOI.ATION SITE OAOUHD WATER SAMPI..INQ AES\A.TS OF SEUl-1/0l.ATll.E ANAl.VSES NOVEMBER 13 -10, \!KIO AOS..OW-WSW AOS-OW-10 AQS-OW-111 AOS-OW-29 A09-QW-3S AOS-Ow ... a ER181 EAIO& ERHIIO '""" EAUl3 """' WAlERSUPP\.V """ NO CONCENTRATION ENTERED FOR ANAL VTE SNOT DETECTED - - --.. --- - AOS-OW__.O AOS-OW-65 AOS-OW-..a9 AOS-QW--00 A09-QW-PZ-1 AOS-OW-711 EAHM """' """' EA18'2 EA1116 EAlltl Bl.lNDSPUT OFOW-15 ., " ----- SAMPlE ID: AOS-TB-1114 AOS-TB--1116 LAB NUMBER: EA11!18 ER190 COMMENTS: TRIP BLANK TRIP BLANK ·CONSTITUENT ' .· PHENOL 815(2-CHLOROETHYL)ElHER 2-CHLOROPHENOl 1,3-0ICHLOROBENZENE 1,4-DICHLOROBENZENE BENZVL ALCOHOL 1,2-0ICHlOAOBENZENE 2-METHYLPHENOL BIS(2-CHLOROtSOPAOPVL)ETHER 4-METHYlPHENOL N-NITROSO-ot-N-PROPYL.AMINE HEXACHLOROETHANE NITAOOENZENE ISOPHORONE 2-NITROPHENOL 2,4-rnMETHVlPHENOL BENZOIC ACID 01S(2-CHLOROETHOXV)METHANE 2.4-0ICHLOROPHENOl 1,2,4-TRICHLOROBENZENE NAPHTHAl.ENE 4-CHLOROANlllNE HEXACHLOROBUTAOIENE 4-CHLOR0-3-METHYLPHENOL 2-METHYLNAPHTHALENE HEXACHLOROCYctOPENTAOIENE 2,4,8-T RICHL ORO PHENOL 2,4,6-T RICHLOFIOPHENOL 2-CHLOAONAPHTHALENE 2•NITROANILINE DIMETHYlPHTHALATE ACENAPHTHYlENE 2,8-DINITROTOLUENE NOTES: AESUL TS IN UO/l (ppb) J • THl9 RESULT IS A QUANTITATIVE EST. NO CONCENTRATION ENTERED FOR ANAL YTE NOT DETECTED - - - DRAFT GEIGY CIIEMICAL CORPORATION SITE GROUND WA 1 EA SAMPUNO RESULTS OF SEMI-VOlATILE ANALYSES NOVEMBER 13 -US, 1i90 AOS-TB-1118 AOS-RBP-1118 AOS-RBB-1118 ER2<M ER20S ER200 TRIP BLANK PUMP BAILER AfNSE BLANK RINSE BLANK . -- ------ AOS-OW-70 AOS--OW-GS ER198 EA1119 EPA QA SAMPLE EPA QA SAMPLE . 113 ,. 32 73 .. 27 •• 30 ----SMIPl.EO: LAB NUMBER: COMMENTS: CONSTITU£NT 3-NfTROANlt.lH( ACENAPHlHEHE 2,4-DINITAOPHENOl 4-HfTAOPHENOl Dl8ENZOFURAN 2,4-DINITROTCX.UENE DIEHM_PHTHAL.ATE 4-CHl.OROf'HENYl-PHENYlETHER FLUOAENE 4-NITROAHILINE 4, ... 0INITR0-2-METHYLPt1ENOl. N-NfTROSOOIPHENYt.AMINE (1) 4-IIROMOPHENYL-PHENVlETHER H0lACHLOROBENZENE PENTACHLOAOf>HENOL PENAHTHRENE ANTHAACENE DI-H-BUTYLPHTHAL.A TE FLUOAANTHENE PYRENE BUTYlBENlYLPHTHAL.ATE 3.3' -OIC ... OAOBENZIOINE BENlO(A)ANTHAACENE Ctl'IYSENE 81$('2-ETHYLHEXVllf'HTHALATE D1-H--OCTYLPHTHALA TE 8ENZ0(8)Fll.lOAANTHENE 8ENZO(K)FLUOAANTHENE BENZO(.-,)PYRENE INOENO(l,2.3-GDIPYRENE DIBENZ(A.H)ANTHRACENE BENZO(O.H,l)f>EAVLENE NOTES: AESUlTS IN 00/l. (ppb) J • THIS RESULT IS A QUANTITATIVE EST. ---.. --AQS-GW-INSW Aas-OW-ID AOS-OW-15 ER191 ER1n ERIIIO WATER SUPPt.V wm DRAFT OEIOV CHEMICAL COAPOAATK>N SITE OROUNOWATERSAMPt.lNO RESULTS OF SEMI-VOLATILE ANALYSES NOVEMBER 13 -111, 111'110 AOS--,-OW-2S AOS-OW--3S AOS-OW--'S '"""' ER\93 '"''" . ,, NO CONCENTRATION ENTERED FOR ANAL YTE SNOT DETECTED --- ------AOS-OW--tO AOS---OW-6.5 AOS-GW~ AOS--OW--eD AOS-OW-PZ-1 AOS-OW-78 ER194 '""'' '"''" ERIW ERllll!i ERIIII BLIND SPLIT Of' OW-15 --- -- - - SAMPLE 10: AOS...TB-1114 lABNUMBER: ER188 COMMENTS: TRlPBlAHK :r:::;(:,:> ,., ;·::-,: .-~~i~-~~,_;\:;_-:- 3-NrTROANILINE ACENAPHTHENE 2,4-DINITROPHENOL 4-NITROPHENOL DIBENZOfURAN 2,4-0tNITROTOlUENE DIETHVLPHTHALATE 4-CHLOAOPHENVl-PHENYLETHER FLUORENE 4-NITROANILINE 4,8-0INITR0-2-METHVLPHENOL N-NITAOSOOIPHENYlAMINE (1) 4-BROMOPHENYL-PHENYLETHER HEXACHLOROBENZENE PENTACHLOAOPHENOL PENANTHRENE ANTHRACENE D1-N-BUTYLPHTHALATE FLUORANTHENE PYRENE BUTYlBENZVLPHTHALATE 3,3'-0ICHLOROBENZIDINE BENZO(A)ANTHRACENE CHRYSENE BIS(2-ETHYLHEXYL)PHTHAL.ATE 01-N-OCTVLPHTHALA TE BENZO(B)FLUORANTHENE BENZO(K)FLUORANTHENE BENZO(A)PYRENE INOENO(t,2,3-CO)PVRENE OIBENZ(A,H)ANTHRACENE BENZO(G.H,l}PERYLENE NOTES: RE SUL TS IN UG/l (ppb) J • THIS AESUL T 19 A QUANTITATIVE EST. NO CONCENTRA TK>N ENTERED FOR AN"l vre NOT DETECTED -- - --- AOS-TB-1116 ERllile TRIP BlANI( DRAFT OEIOY CHEMICAL CORPORATION SITE OROUND WATER SAMPLINQ RE SUL TS OF SEMI-VOU. TILE ANALYSES NOVEMBER 13-18, 1i90 AOS-TB-1118 AOS-RBP-1118 AG9-RBB-1tl8 ER204 ER20S ER20e TRIP BLAI« PUMP BAILER RINSE BLANK RINSE Bl.ANK . ·.: .. .. _: :.--: .-_· .>\\.< . ., ., -- --- AOS-OW-70 AOS-OW-89 ER1ee ER199 EPA QA SAMPLE EPA QA SAMPLE 30J 34 ,. 52 27 ,. " I I n 460 I 450 I I I 420 410 I 400 I ~ ...J U) :le t 390 z 0 .= ~ 380 I ...J w 370 I 360 I I I 320 I 310 I JOO I 290 WEST A CITY OF ABERDEEN MUNICIPAL WE:..L #4 i I USGS WELL CLUSTER (GS-02-02) I ! I I I j ' RR HWY. 211 ~ ___ _,_ _____ ,..,. _________ ---_. -_;__...:...: ::---·--,;__ - - - ' -L ' I t!l 384 PZ-1 RR MW-GS MW-60 I ~T~_u-_- 1-cu:r · • ........ MW-5S .......... ·.·. _;..,,,;_· 436.1 RR "LOO'S[ '!ti .«Dll.llil C/Jfll",C . Sil.TY .1r1C1 CLA.YET rM: TO .. ··---~~ ······~·· ........ --VERY STIFT SUCHTI. T -ID=44.:r SNar a.J,T . . . 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C3ttl>ID t.f'l'l:RICIST AGUl1UI> ~ !EEi' IO<ITtR \IEl.l, CTl!IRD l.PPERKIST AGUl1UI) la Et.£VAT111< CDITtl.ll (TT, ICSU· , GRDUND YATER ELEVATIDN MAP UPPERMDST AQUIFER DATA m I ECTED 11/13/90 THE GEIGY CHEMICAL CORPORATION SITE ABERDEE~ NORTH CAROLINA ? --? / . • .. DRAFT mGJ. ERM-SOUTHEAST, INC