NCD986187094_20100301_Reasor Chemical Company_FRBCERCLA LTRA_Limited Soil Groundwater Assessment February - March 2010-OCR

UNITED ST ATES ENVIRONMENT AL PROTECTION AGENCY
REGION 4
61 Forsyth Street, S.W.
Atlanta, Georgia 30303
MEMORANDUM
SUBJECT:
FROM:
Review of Soil & Groundwater Report
Castle Hayne School Data
Reasor Chemical Site
Kevin Koporec, Toxicologist // IY/C.,
Technical Support Section (-----f__.'.-.-,
Superfund Support Branch -----------
THROUGH: Glenn Adams, Chief
Technical Support Section
Superfund Support Branch
TO: Samantha Urquhart-Foster, RPM
Superfund Remedial & Site Evaluation Branch
March 1. 2010
Per your request, I have reviewed the DRAFT Report of Limited Soil and
Groundwater Assessment, Castle Hayne School Campus, Castle Hayne, North Carolina
(ECS Carolinas, February 10, 2010). You also specifically requested us to evaluate the risks
posed to students and staff at the schools where the samples were taken.
BACKGROUND
This sampling investigation was for soil and groundwater on school grounds that are adjacent to
the Reasor Chemical Superfund site. There was concern that, if the contamination was on the
school grounds, people at the school might be exposed to chemical levels that would cause
unacceptable health risks. The submiited draft report compares the reported sample data to
North Carolina state levels for both soil and groundwater.
' .
2
SCREENlNG AND ASSESSMENT OF SOIL DATA
Comparing the reported soil data (Tables I, 2) to EPA health risk based Regional Screening
Levels (RSLs) for residential soil (EPA 2009), there are exceedances for Benzo[a]pyrene and
other polycyclic aromatic hydrocarbons [PAI-ls], and for Arsenic. The reported level of
Benzo[a]pyrene in samples HA-6, HA-20 (2,620 and 699 ug/kg, respectively) exceed the
residential soil RSL of 15 ug/kg. The reported levels of Arsenic in all samples exceed the RSL
of0.4 mg/kg (rounded from 0.39). Based on this risk based screening, Benzo[a]pyrene (and
other potentially carcinogenic PAI-Is that EPA groups together with Benzo[aJpyrene) and arsenic
are retained for further evaluation.
Arsenic in soil-The reported concentrations of arsenic from the school campus soil samples
range from 0.53 to 6.0 mg/kg. Based on our cancer risk range (10-6 to 104 ) and default exposure
assumptions, soil arsenic concentrations of up to 40 mg/kg are considered protective for a
residential (i.e., unrestricted land use) scenario. The reported arsenic concentrations in the
school soil data are all less than 40 mg/kg, and thus are acceptable for unrestricted human
exposure.
PAHs in soil-Based on the reported data from the 11/11/09 sampling effort, the only sample
with PAI-I detections was HA-6. On 01/06/10, more samples were taken around this same area
to better define the P AH contamination. The on! y sample from this effort reporting detections of
PAI-Is was HA-20, the same area as HA-6. In order to assess the risks, I have calculated the
benzo[ a ]pyrene-equivalent (BAP-eq) based on the application of the relative potency values for
all seven PAH compounds considered to be carcinogenic (EPA 2000, 1993).
Chemical RPV Sample HA-6 SamoleHA-20
Benzo[a]nvrene 1.0 2620 699
Benzo( a ]anthracene 0.1 2840 670
Benzo(b lfluoranthene 0.1 3570 1020
Benzo[k ]fluoranthene 0.01 1190 429
Chrvsene 0.001 3070 789
Dibenz[ ah]anthracene 1.0 435 415U
lndeno[ 123-cd]ovrene 0.1 1660 415U
BAP-eo 3900 I 100
RPV-relative potency value (compared to Bcnzo[a]pyrene) (EPA 2()()(), 1993).
BAP-eq -BenzolaJpyrene equivalent concentration, rounded to two significant figures.
U-flagged values are the reporting limit (RL) for a non-detect result. One-half the RL used as the proxy
concentration in BAP-eq calculation.
All com:entrations are in units of ug/kg.
The PAI-I concentrations from the school campus soil samples are all non-detect with the
exception of the HA-6/HA-20 location. The calculated BAP-eq values for HA-6 and HA-20 are
3900 and I 100 ug/kg, respectively, as shown in the table above. Since these samples were taken
at different times from the same location, it is appropriate to average the two values; the average
BAP-eq of these two samples is 2500 ug/kg.
3
Based on the EPA cancer risk range (10-6 to 10-4) and default exposure assumptions, soil BAP-eq
concentrations of up to 1500 ug/kg are considered protective for a residential (i.e., unrestricted
land use) scenario. The average BAP-eq concentration from the area of HA-6/HA-20 of 2500
ug/kg exceeds 1500 ug/kg, and thus would not be acceptable for unrestricted human exposure.
Since this area is a schoolyard rather than a residential yard, it is appropriate to adjust the
exposure parameters to match those of current receptors. The current receptors for the
schoolyard soil are staff members (teachers, administrators, other staff) and students.
Assuming staff members at the school to be current receptors, we can compare to our default
industrial/commercial worker scenario since we already have established RSLs. The exposure
parameters assumed for the default worker scenario exposure to soil are all appropriate for
school staff with the possible exception of the exposure frequency (EF). The EF for a school
staff member may be lower than the RSL default assumption since they may not work at the
school 50 weeks per year. Thus leaving the EF at the default of 50 weeks per year would be a
conservative assumption. Also the incidental soil ingestion rate of 100 mg/d (assumes an
outdoor worker) may be conservative if the school-staff member works primarily indoors on
some or most days. Therefore we can state that the industrial soil RSLs would be protective for
this receptor. The industrial soil remedial goals recommended for benzo[aJpyrene are the RSL
adjusted to the cancer risk range: 200-20,000 ug/kg. Since the BAP-eq levels are within this
range, the risk threshold is not exceeded, and no unacceptable risks are estimated for the school
staff member receptor.
Assuming a school aged child to be a current receptor for the schoolyard soil, and using the RSL
calculator, an appropriate risk based concentration for BAP-eq can be derived. Starting with the
residential RSL assumptions, the following exposure inputs are changed in order to assess a
school-aged child.
Exposure Frequency (EF) = 250 d/y
(conservatively assumes the child continues to visit this same location in the schoolyard 5 days
per week throughout the school year and the summer break)
Exposure Duration (ED) = 12 yrs (assumes child visits site area from ~ge 6 to age 18)
Soil Ingestion Rate (IR)= l 00 (assumes younger child, under age 6, does not have daily contact)
Body Weight (BW) = 45 kg (older child)
Running the RSL calculator with these assumptions gives a risk-based range for this school aged
child receptor of 130 ug/kg (risk= 10-6) to 13,000 ug!kg (risk= 10-4) for BAP-eq. Since all the
calculated BAP-eq based on site sample data ( 1100, 3900) are within this range, there are no
detections outside EPA's risk range for this receptor.
.
4
GROUNDWATER DATA SCREEN
The report includes analytical data based on groundwater samples collected from the schoolyard
area in October 2006, November 2007, and November 2009.
From review of the groundwater data and comparing to health based standards and RSLs,
arsenic, chromium, and iron are chemicals of potential concern. The Iron levels are bolded in the
table based on comparison to the secondary MCL (EPA 2006) (not health based); nonetheless,
one detection of iron (65.2 mg/L) does exceed the health-based tap water RSL of 26 mg/L (EPA
2009).
These apparent contamination levels should be considered in relation to the Reasor site or other
possible source(s).
There is no mention of current groundwater users in the area; since the sampled groundwater is
from monitoring wells, rather than drinking water wells, I am assuming that there are no current
groundwater users in the immediate area. The report should probably clarify the exact purpose
of the groundwater portion of the investigation.
SUMMARY AND CONCLUSIONS
Since the reported schoolyard soil data exceeded risk based screening levels for arsenic and
polycyclic aromatic hydrocarbons [P AHs ], adjustments to the risk based levels were done to
assess the actual receptors for this site area. On this site specific basis, the soil concentrations
are all found to be within the EPA excess cancer risk range of 10·6 to 10·4•
This site specific assessment is conservative (i.e., health protective) in using maximum reported
concentrations and upper bound exposure assumptions [assumes the same person goes back to
some hotspot area 250 days per year for 12 years of school (student) or 250 days per year for 25
years of work (staff)].
5
References:
EPA 1989. Risk Assessment Guidance for Superjimd, Volume/, Human Health Evaluation
Manual, Part A. Interim Final, EPA OERR, December 1989.
EPA 1993. Provisional Guidance for Quantitative Risk Assessment of Polycyclic Aromatic
Hydrocarbons, EPN600/R-93/089. EPA Office of Research and Development, July 1993.
EPA 2009. Regional Screening Levels for Chemical Contaminants at Superfund Sites
[http://www.epa.gov/reg3hwmd/risk/human/rb-concentration_table/index.htm], updated
December 2009.
EPA 2006. 2006 Edition of the Drinking Water Standards and Health Advisories, Office of
Water, U.S. Environmental Protection Agency, August 2006, EPN822-R-06-013
[http://www.epa.gov/waterscience/criteria/drinki ng/]
Feel free to contact me if you need further help at 2-8644.
Reasor School Soil Data Mar2010.doc
. . BA NCDENR
North Carolina Department of Environment and Natural Resources
Division of Waste Management
Beverly Eaves Perdue
Governor
Dexter R. Matthews
Director
Ms. Samantha Urquhart-Foster
Remedial Project Manager
Superfund Remedial & Site Evaluation Branch
U.S. Environmental Protection Agency, Region 4
Sam Nunn -Atlanta Federal Center
61 Forsyth Street, S.W.
Atlanta, GA 30303
March 1, 2010
RE: Draft Report of Limited Soil and Groundwater Assessment
Castle Hayne School Campus & Reasor Chemical NPL Site
Castle Hayne, New Hanover County, North Carolina
NCD 911278631
Dear Ms. Urquhart-Foster:
Dee Freeman
Secretary
The North Carolina Department of Environment and Natural Resources (NC DENR) Superfund Section
has received the Draft Report of Limited Soil and Groundwater Assessment for the Castle Hayne School
Campus/Reasor Chemical Site. The NC DENR Superfund Section has reviewed this document and
offers the following attached comments.
The NC DENR Superfund Section appreciates the opportunity to comment on this document. If
you have any questions or comments, please feel free to contact me at [phone] or at
[e-mail].
Attachment
1646 Mail Service Center, Raleigh, North Carolina 27699-1646
Phone: [phone] I FAX: [phone] I Internet: www.wastenotnc.org
An Equal Opportunity\ Affirmative Ac~on Employer
Sincerely, ~1]~~1,14-,,·
David B. Mattison
Environmental Engineer
NC DENR Superfund Section
Ms. Samantha Urquhart-Foster
Draft Post Removal Site Control Plan (Revision 1)
LCP-HoltraChem Site .
NCD 911 278 631
March 1, 2010
Page 1
Draft Post Removal Site Control Plan (Revision 1)
REASOR CHEMICAL NPL SITE
February 23, 20 I 0
TO: David Mattison
FROM: David Lilley
RE: Comments on the Draft Report of Limited Soil and Groundwater Assessment, Castle Hayne
School Campus, 44 I 6 Castle Hayne Road, Castle Hayne, NC
February 10, 2010
Arsenic and carcinogenic polynuclear aromatic hydrocarbons (cPAHs) were detected in the soil
at levels that exceeded the Inactive Hazardous Sites Branch Preliminary Soil Remediation Goals
(IHSB PSRGs). Iron, arsenic, and cPAHs exceeded the IHSB Protection of Groundwater SRGs.
Since the shallowest monitoring well (TMW-2W) was 3.71 feet below ground surface and
nobody is using the groundwater in this area, this discussion will be concerned only with the
risks posed by direct contact with soil.
Arsenic was detected in 11/12 soil samples. Arsenic levels in five of these samples exceeded the
THSB PSRG of 4.4 mg/kg, with the highest concentration being 6 mg/kg. Arsenic poses both
carcinogenic and non-carcinogenic risks; the PSRG is calculated based on arsenic's non-
carcinogenic properties. The PSRG values are calculated to be protective for unrestricted site
use. In addition, the PSRGs are calculated assuming there are a total of five non-carcinogenic
Ms. Samantha Urquhart-Foster
Draft Post Removal Site Control Plan (Revision l)
LCP-HoltraChem Site
NCD 911278631
March 1, 2010
Page 2
chemicals that all cause the same health effect. In order to determine what the site specific
screening value is if only one chemical of concern is present, the PSRG is multiplied by 5. In
this case, 4.4 mg/kg x 5 = 22 mg/kg arsenic in the soil would be the value IHSB would consider
acceptable for unrestricted site use. None of the.sample results exceeded this value. The highest
conce~tration of arsenic found on the site (6 mg/kg) corresponds to a carcinogenic risk of 1.5 in
100,000, which is considered acceptable risk for residences and commercial facilities with child
occupants, such as schools and daycares.
Sample HA-6 showed elevated levels of cPAHs. A comparison of these concentrations vs. the
PSRGs shows that the carcinogenic risk posed by the cP AHs (2.5 in I_ 0,000) exceeds the
acceptable cancer risk of I in I 0,000. To further evaluate the cPAH distribution on this site,
fifteen samples were collected on the field where the elevated cPAH concentrations were found,
including a sample collected in the area ofHA-6 (HA-20). HA-20 was the only sample where
cPAJ-ls were detected, suggesting the cPAHs are fairly localized. Concentrations detected in the
_second round of sampling were lower than the first, with a cancer risk within acceptable levels
(5.8 in I 00,000).
PREPARED FOR
NEW HANOVER COUNTY SCHOOLS
FEBRUARY 10, 2010
Mr. Edward J. Anderson
New Hanover County Schools
641 O Carolina Beach Road
Wilmington, North Carolina 28412
Reference: Report of Limited Soil and Groundwater Assessmenyt.,.'.lt> •• ~ " Castle Hayne School Campus _,.,, • . . ' 4416 Castle Hayne Road ,,4·:'·.:.->,
Castle Hayne, New Hanover County, North Carolina-. y~
February 10, 2010
ECS Project Number 22-12493E -~, "'¾t
Dear Mr. Anderson: L ·~ ,
ECS Carolinas, LLP (ECS) is pleased to provide ';c{ti:with ~,results of oufi:~ited Soil and ,. ,.~. ,,tr ~ ~ ,,;r Groundwater Assessment for the above referenced property!'ECS' services were conducted in
accordance with the services outlined in ECS Proposals·-22~3197 dated October 21, 2009 and
22-13438 dated January 5, 2010. ECS,aP.preciates the dpportunity to provide our services to
you. If there are questions regarding this',report, or a ne'ed:'for further information, please
contact us at [phone]. ''?,."~;-<':'>,:~ ''<•;~·
',•)•·•':!-... ;;;,'" lf/S.;1'::;,,...._ 11
Respectfully submitted, ~ .. ' .-'t _,[) -><·,~~
,t&-•t• '-v/~ 'P
ECS CAROLINAS, LALP. ·q-. ..:i,J;~ \ .. ,,?;... ,-:; ~) --.,,,.,.'-,_ \ .• .' '\\..?
~:.1-;,. l,1 Ct>; ., .. \./:,,,, _,;";-:~~··~·~~!,
Amy C Conchas'REM~ ''c;"if,~•.•.:.~"11''":'J;z: . ... ...• .!,,._. ...... !!.,ht. ·..:'-~ .. Environmental•Department-Manager, .. AK. "'''·' ·' c,_~;,,._ ""o-,... ~-'....... " ~~~ '~,ii.' 'jf y~
. ~~ : ... \ .,
Stephen J. Gos~eli~ P.G. \;,,
Principal Geologist,:~,~ :::,'
NC Licensed GeologLst,#1445;.1
~:J~0:!-j?
Report of Limited Soil and Groundwater Assessment
Castle Hayne School Campus
4416 Castle Hayne Road
Castle Hayne, New Hanover County, North Carolina
ECS Project Number 22-12493E
February 10, 2010
TABLE OF CONTENTS
1. BACKGROUND INFORMATION ................................ : ............................................ 1
2. SOIL ASSESSMENT ............................................................................................... 2
3. GROUNDWATER ASSESSMENT .......................................................................... 4
4. CONCLUSIONS AND RECOMMENDATIONS ....................................................... 5
5.
f.,..f'.'\..
QUALIFICATIONS OF REPORT ..................................... s'~,·.·.::-.. ............................. 7
FIGURES
TABLES
,,/.~' .
,1:A/~'J)i. -f.,_-.' -....; ... , '·r ~,,,, .._
Figure 1 -Site Location Map ~ ~¾_ '\:~
Figure 2 -Historic Sample Locati"jjon Map,."-'"-f'"';... er ...,_ ,•U· ':t Figure 3 -Site Plan <ff' ~~•~
Figure 4 -Overview Sample L?c/iti,~>n Map~ >i'{~t~-<
Figure 5 -PAH Sample Locat1on·t;,1ap ri> i>"
Figure 6 -Potentiometric Surface Map,._. .r. _c· ,:•
"'-o"-~':Y
~'<:.,.
\"',. sl:i;J~ Table 1 -Soil Analytical.Data v.,
Table 2 -Soil Analytica'i(Data~P .. /?.Hs °"'::. ,.f' ')" .,,-•• ·,,:.-"'..., •j
Table 3 -Groundwater Analyt/ical·D~-~;,,,.,, ,;F i j/""'!,:,C::,v_ •.
APPENDIX ~ ~-\ ;/ ~r.·· ~oJ,i/-,;~~;• · "' •• Boring,~6gs~1\ '-.
Laboratory Data;Sheets and Chain of Custody Record
Regulaio'ry Corresponde .. nc. e y"t °'\;;o~ j;_'h-, • ,;;';,c,. ~o-J;ilJ-.~-"i,,o;_;;,, ,-•~•".~,:-~.~ ~ .A"!~-';b,. ~ -n..:..'.;,:_ •'l!_·<..•••>•P ~,'2,~•r/i;:b. ,Q';. •~
~;-~Q;~"~ ~-.
/4'f -~,.'!:,. .· ~{~; ... ,,4' ?~' :9-;"-t ~,' o? .,, ., -. .. •. 9;1
)~ .,;J 'V'
Report of Limited Soil and Groundwater Assessment
Castle Hayne School Campus
4416 Castle Hayne Road
Castle Hayne, New Hanover County, North Carolina
ECS Project Number 22-12493E
February 10, 2010
1, BACKGROUND INFORMATION
The site is the Castle Hayne elementary and middle school campus located at 4416 Castle Hayne
Road in Castle Hayne, New Hanover County, North Carolina (Figure 1 ). An EPA Superfund site
(Reasor Chemical) is located approximately 800 feet south of the site. Previous groundwater
assessments at the site conducted by ECS did not identify chemicals of concern (COCs)
associated with the Reasor Chemical site in groundwater beneath the site. The locations of the
previous groundwater samples are shown on Figure 2.
Ai,
As discussed in ECS's Report of Limited Groundwater Assessmentrdated November 10, 2006,
ECS project number 22-12493B, ECS installed seven temporary,groundwater monitoring wells at
the site in October 2006 to evaluate the site groundwater for impacis'from surrounding properties,
especially the southern adjacent Superfund site. With the exce"P,iion c.if~~Jls which were intended to
evaluate the groundwater nearest the Superfund site, the'.lo_c,ations of tli~_l?,9rings were randomly
chosen to provide general coverage of the site focusing"onttie site boundaries and the interior of
the site. ECS did not observe obvious potential COJ1t.'.i0inant sgurces on the''sjle;Q!:,Jlong the site
boundaries. Groundwater samples collected from'fou_f,~lls (~i' through TW~5):were analyzed
for volatile organic compounds (VOCs) and semi-volatile·organic•compounds (SVOCs). Laboratory
analysis of the groundwater sample collected from well TW~t~6e northwestern site well) detected a
trace amount of 4-isopropyltoluene at a concentration of 1.23;µg/l. Groundwater samples collected . "•':l... ... -.. . from wells TW-6 and VE-1, which were a,stiallow and deep welhlocated along the southern site
boundary, closest to the Superfund site, \.vere··analyzed for ~bl~tilif and semi-volatile organic
compounds, priority pollutant metals and pes~~id'es·.:.;--i:D~,~mple{contained low levels of metals
which were below the applicable NCAC~2L,.yGrouhd1:Y!c!ter Standards. Therefore; these
concentrations are not considereo;·reportable concentration~a'fid are not regulated. Based on the
results of the groundwatefsamplirfg\ECS did n'o\identify contaminant concentrations exceeding
the NCAC 2L Ground~ater.'Standarct} \;\,_,,, ~~ t\" ,,,;' .~•rl>. ;*~ I~ In October through December-2007f,ECS"performed'additional groundwater sampling at the site, as
...,ic'.J"~ ~·~''• -~·-,, ... ,~ .. " discussed in IJ;i.~'.Letl~['/30E,P,_Ort of~o,undwater-Study dated November 9, 2007 and Letter Report of
Well SamRling· dated '0ecember 31,2007, (ECS project number 22-12493C). The additional
groundW,ll_!~r~ampling inciu~~~ the '1n:;,_t.<!U.ation and sampling in October 2007 of a groundwater
monitoring'we!l:_and irrigatio~_ater supply well to a depth of approximately 65 feet below ground
surface and "screened from a ~epth of 25 to 65 feet below ground surface. The irrigation well
sample was an'aiyied for bacteriological constituents (fecal coliform and total coliform), inorganics
(chloride, alkalinityJt'nyoride,)h"ardness, aluminum, arsenic, lead, copper, iron, manganese,
magnesium, pH, hardrie§s, diss'olved iron, thallium, and zinc), nitrate/nitrite, voes by EPA Method
621 OD and SVOCs by°tEPA Method 625. The monitoring well samples were analyzed for
aluminum, thallium, arseriTc, and pH. Laboratory analysis of the groundwater sample collected from
the monitoring well (MW-1) indicated the presence of aluminum at 1.5 mg/I with a pH of 8.00. Other
target compounds were not identified above the laboratory detection limits in the groundwater
collected from MW-1. Aluminum was not identified in the irrigation well sample. However, total iron
and manganese were identified above established standards. Other compounds identified (fluoride,
chloride, pH at 7.96, iron and magnesium) either were identified below established standards or
there are not established standards for the compound. The monitoring well was re-sampled in
November and December 2007 for aluminum, thallium and arsenic. The results of the re-sampling
1
Report of Limited Soi/ and Groundwater Assessment
Castle Hayne School Campus
4416 Castle Hayne Road
Castle Hayne, New Hanover County, North Carolina
ECS Project Number 22-12493E
February 10, 2010
identified an aluminum concentration of 1.54 mg/I in November 2007 and 0.363 mg/I in December
2007. Arsenic and thallium were not detected in the resampling events.
Since the prior sampling events, the site has been developed with an elementary and middle
school, as shown on Figure 3. ECS was requested to conduct further assessment at the site in an
effort to determine whether site soils and groundwater have been impacted with the chemicals of
concern associated with the Reasor Chemical site.
,.f.,.._,. ,.,,.-,.,,._ 2. SOIL ASSESSMENT ,:.r....--~
November 2009 Assessment ,,l:z_
Soil samples were collected at locations determined by£,New',Hanover County Schools
personnel and ECS professionals. The sample locations were chosen~n an attempt to identify
potential impacts associated from the southern Reasor,.Ctlemical 'site.,and potential surface
contact by student, visitors and school personnel to sitetsu}flcial soils. tt\'ii:].§ample locations are
sh=onFigure4. / ~
The soil assessment was performed on Novtil~1,1, 2~9~by an ECS '~r;6tessional. The
weather consisted of temperatures ranging from 55 td'6.5lf.ahre~heit and heavy rain. The soil
assessment consisted of advancement of twelve soil borings using a decontaminated hand
auger to a depth of 18 inches below 9!Pl:1,Q? surface. P}l~r;t~ initiating the first boring and
between each subsequent boring, the hana:aug1c;,. was decontafTlin<Jted using an alquanox soap
mixture and distilled water. Soil samples w'ere'collected in apprdxii'nate six inch increments and
transferred into a new, clean resealable bag"{half full):f Approximately ten minutes after the time
of collection, the bag was open_ed slightly and;th~.probe"of,a:i')li'oto ionization detector (PID) was
inserted to measure volatileii'o,'ganic vapors.'\IJi'e meter Io! the PID was monitored and the
reading recorded. The r.~§ordelP(9.1responses ar,e presented on the boring logs included in the
Appendix. .fi.e;~ s~1 'l\ _ __,, ~--, ~~-~ !,~, ~';.',:..-
~;,,~ j.,L,,._ /j,"'
Based_ on field -~e~e'."ationsf<j,r;i,d'-'Rl[)~~-il}?i~gs, the soil samples did not display _obvious
IndIcat1ons o!,<;1mpacts,..,,Therefore,,,_the SOll'-,from the top 12 inches from each boring was
submitted for'labor~toryt'.analysis'.'?),The soil samples were placed in laboratory prepared
containers~u'sing a new pair~of disposable nitrile gloves for each sample. Each container was
labeled/ahcl'/placed in a cool~r contalning ice to maintain the samples at approximately 4°
Celsius. Th~~oil1amples were\then •shipped via overnight express delivery to Pace Analytical
Laboratories, lric'.?i_(Pace) in 'Huntersville, North Carolina for chemical analysis. A chain of
custody was maint~ih~d and is.included in the Appendix. The soil samples were analyzed for
voes using EPA Method 8260, SVOCs using EPA method 8270, total metals (aluminum,
antimony, arsenic, chr6riliuri{ copper, iron, lead, nickel, thallium and zinc) using EPA method
1610 and 2,3,7,8-TCDDJ'.is'ing EPA Method 1613.
The results of the soil analysis are summarized in Table 1. The soil results were compared to
the North Carolina Department of Environment and Natural Resources (NCDENR) Inactive
Hazardous Sites Branch (IHSB) Preliminary Soil Remediation Goals (SRGs) and Protection of
Groundwater Soil Remediation Goals. The analysis for VOCs identified toluene in samples HA-
5 and HA-6 and p-isopropyltoleuene in sample HA-6. The concentrations of VOCs were below
the SRGs. The analysis for SVOCs identified concentrations of polycyclic aromatic
hydrocarbons (PAHs) in sample HA-6 at concentrations exceeding the preliminary and
protection of groundwater SRGs. The analysis for 2,3,7,8-TCDD did not identify concentrations
2
Report of Limited Soil and Groundwater Assessment
Castle Hayne School Campus
4416 Castle Hayne Road
Castle Hayne, New Hanover County, North Carolina
ECS Project Number 22-12493E
February 10, 2010
above the laboratory detection levels in the soil samples collected. The analysis for total metals
identified aluminum, chromium, iron, lead, nickel and zinc in the twelve samples collected. The
aluminum, chromium, lead, nickel and zinc concentrations did not exceed the SRGs. The iron
concentration exceeded the protection of groundwater SRG in all twelve samples collected but
did not exceed the preliminary SRG in the samples. Arsenic was detected in the majority of the
soil samples with concentrations from HA-2, HA-3, HA-7, HA-9 and HA-11 exceeding the
preliminary SRG and HA-2 and HA-9 also exceeding the protection of groundwater SRG.
Beryllium, copper and thallium were detected in some of the samples; however, the
concentrations were below the SRGs. Antimony was not detected, in the soil samples. The
analytical results are included in the Appendix. 1/(·\,,
/
January 2010 Assessment /2.;:,,,
Based on the results of the November 2009 sampling';ifvciii:1:y;hich identified elevated
concentrations of PAHs in sample HA-6, additional sampling was pe_rf9_rmed in the vicinity of
HA-6 to determine the general extent of PAH impacted;soil.-,Jlie samplei@~tions are shown on
Figure 5. LP' ~g,.'),.
Li..?~~ '?,, "\~Th,..~ The soil assessment was performed on January•5;,_,201 0 oy_,an ECS professional. The soil
assessment consisted of advancement of fifteen soilr\:J.o_Ji(lg·s~using a deco'ntaminated hand
auger to a depth of approximately 12 inches below grou~\l_,surface, below the sod located on
the field. Prior to initiating the first boring,and between each-;subsequent boring, the hand auger
was decontaminated using an alquanox~soap. mixture and· distilled water. Soil samples were
collected in approximate six inch incremehis''ancl:transferred intc:i~a>°fiew, clean resealable bag
(half full). Approximately ten minutes after,ihe timeJ'af-collection:·1he bag was opened slightly
and the probe of a photo ionization detecto~\ (P)Qi""'waszi!:1.~~rted to measure volatile organic
vapors. The meter of the,8,IQ,2,~3!S monitoredr/iiid the reading recorded. The recorded PIO
responses are presentedbon· tne•ooring logs included in the''Appendix.
(l·' ye) -~
Based on field obslr;;~\[~ns and}PJD reading~\the soil samples did not display obvious
indications of impacts. The'·s_9.i_l,,.~~riipi~t~t~~~_%.CE!'d in laboratory prepared containers using a
new pair of disposable,nitrile gloves for'each'sample. Each container was labeled and placed in
a cooler contairiinificel,!o}maintai~the samples at approximately 4° Celsius. The soil samples
were then<,shipped via ciiielnight e~pre~delivery to Pace in Huntersville, North Carolina for
chemic~Jfa[i}ilysis. A chain"iif,°l':_ustod/,~}s maintained and is included in the Appendix. The soil
samples wef~
0
nalyzed for P~_ljp usir191EPA method 8270.
. ~"' 'I: ,1 The results of thiisqi[ analysisi'are summarized in Table 2. The soil results were compared to
the North Carolin~Departme-n''t of Environment and Natural Resources (NCDENR) Inactive
Hazardous Sites Bran"c!)',;(ll;IS.B) Preliminary Soil Remediation Goals (SRGs) and Protection of
Groundwater Soil Remediation Goals. The analysis for voes identified toluene in samples HA-
5 and HA-6 and p-isopropyltoleuene in sample HA-6. Soil sample HA-20, which was collected in
the approximate location of HA-6, exhibited concentrations of PAHs exceeding the preliminary
and protection of groundwater SRGs. The analytical results are included in the Appendix.
Additionally, based on the results of the November 2009 sampling event, which identified
elevated concentrations of arsenic and iron in the soil samples, three background soil samples
(B-1, B-2, and B-3) were collected to determine the background metals concentrations of the
site soils. The three background soil samples were collected from undisturbed areas of the site,
as shown on Figure 4. The soil samples were placed in laboratory prepared containers using a
new pair of disposable nitrile gloves for each sample. Each container was labeled and placed in
3
Report of Limited Soil and Groundwater Assessment
Castle Hayne School Campus
4416 Castle Hayne Road
Castle Hayne, New Hanover County, North Carolina
ECS Project Number 22-12493E
February 10, 2010
a cooler containing ice to maintain the samples at approximately 4° Celsius. The soil samples
were then shipped via overnight express delivery to Pace in Huntersville, North Carolina for
chemical analysis. A chain of custody was maintained and is included in the Appendix. The soil
samples were analyzed for total metals (aluminum, antimony, arsenic, chromium, copper, iron,
lead, nickel, thallium and zinc) using EPA method 1610.
The background soil samples did not show elevated concentrations of arsenic or iron. Arsenic
was not detected in two of the three soil samples, and the third soil sample contained a
concentration of 0.41 mg/kg. The concentrations detected at the sit~.[n November 2009 ranged
from below detection limit to 6.0 mg/kg. Iron was detected in the-.background soil samples at
concentrations ranging from 250 to 438 mg/kg, which is less than".ttie coifcentrations detected in
November 2009, which ranged from 395 to 5,130 mg/kg. The.Jesuits of the soil analysis are
summarized in Table 2. The analytical results are included in1he Appendix. "" -~~~ ~ ~ ·· ..
3. GROUNDWATER ASSESSMENT 10.-~
1\,,... ... ~~1;1, ,r,t-7 .;-i:O•\, '
Groundwater samples were collected at locations,dEi'termined, by New Han6;/er-·County Schools
personnel and ECS professionals. The sample•lo~ation~ we~~_c_hosen in an a\t"empt to identify
potential impacts associated from the southern Reasor:_§:hemical"site. The sample locations are
shown on Figure 4. -~~-b:t; ;,,._ ·'!:. 'Wj'7t,.__ }.~,
The groundwater assessment was performed on Novemtier:~,16 and 17, 2009 by an ECS
professional. The weather consisted of temperatures ranging'-frtim-,'60 to 65° Fahrenheit and
sunny. On November 16, 2009, four temporary-groundwater mo'niioring wells were installed at
the site using a geoprobe operated by a North,Caroifna:ifcensed' driller with Mid Atlantic Drilling, v·, '-"' ""<":•"•" Inc. The groundwater moni\gf.fil91,'!".ells were insJ<]lled to a d!2pth of 20 feet below ground surface
(bgs) and consisted of 1,9.Jeet ofi.1.;ibfh PVC scr~~n at the bottom of the well followed by 10 feet
of 1-inch PVC riser abov~_,Jhe scr~~.fl-Well sand\was placed from a depth of 20 feet to 8 feet
bgs, followed by one'to'two.feet ofi_bentonite. Ttie,temporary wells were developed following
installation. The b=g logs''fc:it,~~~~ell~ ?f~~~ludecl in the Appendix.
-dfi:,;~'1?:"!,-.. ~~ ~"""-9.WJ? Three of theftempora[YJ,wells (ifMW-1W, TMW-2W and TMW-3W) were placed along the
southern pro'perty boundaryi':closestjo,th~Reasor Chemical site. Temporary well TMW-4W was
placed n6ftt\)of well TMW-1.W},in order_;to ·determine the groundwater flow direction. The depth
to water w'a1~measured ancl}\the to\i".of-casing was measured on November 17, 2009 to
determine the~groun.dwater \f[9w direction. The depth to groundwater and groundwater
elevations were me"asured asjihdicated below. The top-of-casing for TMW-1 W was given an
arbitrary elevation of~~ttfe remaining measurements were referenced to this point.
·--Well E>epth to Groundwater (feet) Groundwater Elevation (feet)
TMW-1W .. 4.27 95.73
TMW-2W 3.71 93.96
TMW-3W 8.88 89.39
TMW-4W 7.91 90.59
Based on the ·groundwater elevation measurements, temporary well TMW-1W appears to be
upgradient of the remaining three wells with groundwater flow to the north-northeast towards an
on-site wetland area located within the central portion of the site. A potentiometric surface map
depicting measured groundwater flow is included as Figure 5.
4
Report of Limited Soil and Groundwater Assessment
Casile Hayne School Campus
4416 Castle Hayne Road
Castle Hayne, New Hanover County, North Carolina
ECS Project Number 22-12493E
February 10, 2010
On November 17, 2009, the four temporary groundwater monitoring wells were developed using
a peristaltic pump and disposable tubing. The wells were developed until sediment was no
longer visible in the water and the water appeared to be clear. Field measurements for pH,
conductivity and temperature were measured after development and prior to sampling.. The
field measurements are listed below.
Well Temoerature (C0 \ oH (SU) Conductivitv (mS/cm)
TMW-1W 20.8 4.08 -· 1.03
TMW-2W 21.0 5.14 J!;J ?,,., 0.13
TMW-3W 21.8 4.55 ,r.?!. 0.17
TMW-4W 20.0 5.57 ,r.JA',_9,'.¼-, 0.19 -~~ .,,,~
Based on the field measurement, the shallow groundwater. a;,the sit~\s':acidic (i.e., less than 7) .
.5.!;;:,.,',. -• "'"°.,,_ J:j',.,,,..-~ ~0,'? ~
Following purging, groundwater samples were collected using low fl6w ... techniques with a
peristaltic pump and disposable tubing. The saiTlples were placed in lati6ratory prepared
containers using a new pair of disposable nitrile gloves for eich sample. Ea'ch' container was
labeled and placed in a cooler containing ice to m'ai~tairr.-tlie-~samples at"•approximately 4°
Celsius. The samples were then shipped via overnight ~!ci:iress delivery to Pace in Huntersville,
North Carolina for chemical analysis. A chain of custody was~maintained and is included in the
Appendix. The samples were analyzed ior:vocs using EPA"Method 8260, SVOCs using EPA
method 8270, total metals (aluminum, aniirhon•,(arsenic, chrorriilim', copper, iron, lead, nickel,
thallium and zinc) using EPA m_ ethod 1610 ~nd 2,3~8]J;CDD usih'g EPA Method 1613.
\\ /? . -~<J-"""""
Following sampling, the temporary, wells were 'properly ~ri~~ned by a North Carolina certified
well driller. 4,f/,,.' ~t~ \\ ·
•• ,.o, 1~~ ~\
<fY "'"''"-' ••')• • V ... A The results of the groundwater analysis are s(jmmarized in Table 2. The results of the
groundwater analysis identified.,,ito'fi!concentrations exceeding the NCAC 2L groundwater
standard in eacn,oMhe four''temporary0mc.i'nitoring well groundwater samples. Arsenic was
identified iQ,fgrouncttfo~~~ample~TMW-3W-at a concentration exceeding the NCAC 2L
groundw?t~( standard. Th~:~ralyticai"r~~ults are attached. ,._, .,, ' '\So,> ,, .. ,:,,;
• -,-·" 1;0" '"? ECS proposlci~)\l, collect a grq0ndwatljr sample from the former on-site irrigation water supply
well; however,\1P,9.~ arrival at'tt.t\e site, it was determined that the former on-site irrigation well
was previously aba.Q?~~ned. J/
~~CONCLUSIONS AND RECOMMENDATIONS
The site is the Castle HZe elementary and middle school campus located at 4416 Castle Hayne
Road in Castle Hayne, New Hanover County, North Carolina. An EPA Superfund site (Reasor
Chemical) is located approximately 800 feet south of the site. Previous groundwater assessments
at the site conducted by ECS did not identify COCs associated with the Reasor Chemical site. ECS
was requested to conduct further assessment at the site in an attempt to determine whether site
soils and groundwater have been impacted with the COC associated with the Reasor Chemical
site.
5
Report of Limited Soi/ and Groundwater Assessment
Castle Hayne School Campus
4416 Castle Hayne Road
Castle Hayne, New Hanover County, North Carolina
ECS Project Number 22-12493E
February 10, 2010
ECS collected surficial soil samples throughout the site to assess the surface soils for COCs. The
soil sampling identified concentrations of PAHs in sample HA-6 and HA-20 exceeding the
preliminary and protection of groundwater SRGs. These soil samples were collected from the
center of the elementary school play field. Additional soil samples collected within the play field
did not identify elevated PAH concentrations, signifying a localized area of contamination. The
compounds identified appear to be from a petroleum release, possibly occurring during site
development.
The surficial soils were also analyzed for metals and compared .. Jo three background soil
samples. Iron was detected in each of the soil samples at concenfrations ranging from 250
mg/kg in the background soil sample to 5,130 mg/kg from soil sample HA-11 collected behind
the elementary school. These concentrations exceed the protection of groundwater SRG but
not the preliminary SRG. Arsenic was detected in the,.~iljority~of the soil samples with
concentrations from HA-2, HA-3, HA-7, HA-9 and HA-1,1_ ex,:eeding{the_ preliminary SRG and
HA-2 and HA-9 also exceeding the protection of grour1d,wate,t SRG. Arse0,:~as detected in one
of the three background soil samples at a concen\ration of 0.41 mg/kg. 'f,h,e soil samples with
elevated arsenic concentrations also contained !')lev_,ated iroQ concentration~.!3ased on the
locations of the elevated metals concentrations,0it\ich1are scattered through6ut:the school site,
it appears that the soil type with elevated metals conc~ntratioris-cJiffer from the?soil type located
in undisturbed areas of the site. However, ECS did not 'iafnji_fy a source of contamination which
would cause elevated metal concentrations. Therefore;':E<::S believes the elevated metals . ...,,.,,...,_ .,. -"-concentrations are naturally occurring in those-soils. ~~-'.-\-. •--~~.',,~ ~.,. :-,-,:1' ~ 5{!'-,, ""'y
The results of the groundwater analysis identifi;~1'ii~iLconcentr~ii~ns exceeding the NCAC 2L
groundwater standard in each of the four 'temRorary,monitoring well groundwater samples.
Arsenic was identified in grq~~-d.w_a,ter sample T-~W-3W at'~):oncentration exceeding the NCAC
2L groundwater standa~d,1Ai:laiti6_\13J.lly, the groundwater samples contained a pH ranging from
4.08 to 5.57. The ,.42.cJi:ljp grour51water could, be contributing to the elevated metals
concentrations from naturally occurring metals i~ttie site soils. Based on the groundwater .,.,_ c.. j..-•._ ' ';, elevation measurements, tern~9,.r:_a_ry_;i'f:'~J~,;J~W:JY,., appears to be upgradient of the remaining
three wells with.m9undwater flowito tne-nortl]'northeast towards an on-site wetland area located
within the centi'al"poitioiZ'of, the ~ite\--_, J!{ ,, .. :'.'.\. '{IS~
Based 9n{(he ,assessme~:;~€!, site \¼i"1s~nd groundwater did not contain COC specific to the
Reasor Chemical site. Hov1ever, soi( concentrations of PAHs were identified at the site
indicative of a"p~troleum releiiie. Additionally, iron and arsenic were identified in both the site
soils and groundwater at concehtrations exceeding the NCDENR regulatory standard. These
concentrations werefreviewed:oy a toxicologisUrisk assessor with the NCDENR and the EPA to
determine the risk as'1r6tiatea\.vith these concentrations as they pertain to potential interactions
with children. The are;a~tof PAH impacted soil is covered with sod and therefore the risk
associated with contact,with PAH impacted soils is minimal. Due to the lack of additional metals
identified at elevated concentrations on the site, the risk associated with contact with arsenic
and iron impacted soils is minimal. Copies of the risk assessment correspondence are included
in the appendix.
Based on the assessment, ECS recommends performing additional soil sampling in the vicinity
of HA-6 and HA-20 to delineate the area of PAH impacted soil. ECS does not recommend
additional assessment of the elevated metal concentrations due to a minimal assessed risk and
lack of identified site source. ECS recommends a copy of this report be submitted to the
NCDENR.
6
Report of Limited Soil and Groundwater Assessment
Castle Hayne School Campus
4416 Castle Hayne Road
Castle Hayne, New Hanover County, North Carolina
ECS Project Number 22-12493E
February 10, 2010
5, QUALIFICATIONS OF REPORT
The activities and evaluative approaches used in this assessment are consistent with those
normally employed in soil and groundwater assessment projects of this type. Our evaluation of
site conditions has been based on our understanding of the site project information and the data
obtained during our field activities.
7
Approximate Scale 1 in.= 1,200ft. FIGURE 1: SITE LOCATION MAP
Contour Interval= 5 ft.
Source: USGS, Castle Hayne, North Carolina Quadrangle 1970
Report of Limited Assessment
Castle Hayne School Campus
4416 Castle Hayne Road
Castle Hayne, North Carolina
ECS Project No. 22-12493E
February 2010
FIGURE 2: HISTORIC SAMPLE LOCATION MAP
Approximate Scale: 1 in. = 400 ft. Source: New Hanover Coun,ty GIS 2004 Aerial Photograph.
Report of Limited Assessment
Castle Hayne School Campus
4416 Castle Hayne Road
Castle Hayne, North Carolina
ECS Project No. 22-12493E
February 201 O
Approximate Scale: Not To Scale FIGURE 3: SITE PLAN
Report of Limited Assessment ~[b
Castle Hayne School Campus
1
f!: [;,,
4416 Castle Hayne Road :l.!l !b.!1.[Fl
Castle Hayne, North Carolina
<CAil::/. <011..U lll!IA!El
ECS Project No. 22-12493E
February 2010
FIGURE 4: OVERVIEW SAMPLE LOCATION MAP
Approximate Scale: Not To Scale
Report of Limited Assessment
Castle Hayne School Campus
4416 Castle Hayne Road
Castle Hayne, North Carolina
ECS Project No. 22-12493E
February 201 O
I-
® Soil Samples
®
HA-27
HA-24
®
HA-21
®
HA-18
®
HA-15
®
®
HA-26
HA-23
®
HA-6/
HA-20
®
HA-17
®
HA-14
®
®
HA-25
HA-22
®
HA-19
®
HA-16
®
HA-13
®
FIGURE 5: PAH SAMPLE LOCATION MAP
Approximate Scale: 1 inch = 60 feet
Report of Limited Assessment
Castle Hayne School Campus
4416 Castle Hayne Road
Castle Hayne, North Carolina
ICAll:i.<C!>IL.UIMA/S
ECS Project No. 22-12493E
February 2010
FIGURE 6: POTENTIOMETRIC SURFACE MAP
Approximate Scale: Not To Scale
Report of Limited Assessment
Castle Hayne School Campus
4416 Castle Hayne Road
Castle Hayne, North Carolina
ECS Project No. 22-12493E
February 2010
TABLE 1 • SOIL ANALITICAL DATA
CASTLE HAYNE SCHOOL CAMPUS
4416 CASTLE HAYNE ROAD
CASTLE HAYNE, NORTH CAROLINA
ECS PROJECT NO. 22-124930
IHSB
Location HA-1 HA-2 HA-3 HA-4 HA-5 HA-6 ·HA-7 HA-8 HA-9 HA-10 HA-11 HA-12 B-1 B-2 B-3 Prellminary IHSB Protection of
Date 11/11109 11/11/09 11/11/09 11/11/09 11/11/09 11/11/09 11/11/09 11111/09 11/11109 11111/09 11/11/09 11/11109 1/6110 1/6/10 1/6/10 SRG Groundwater SRG
voes U"~" u u u u u u u , . u u u u u u un/J(n un/J(n u
Toluene BDL BDL BDL BDL 94.7 28.5 BDL BDL BDL BDL BDL BDL NA NA NA 9,800 No Standard
p-lsonropvltoluene BDL BDL BDL BDL BDL 19.2 BDL BDL BDL BDL BDL BDL NA NA NA No Standard No Standard
Acetone BDL BDL BDL BDL BDL BDL BDL BDL BDL 127 BDL BDL NA NA NA 12.000,000 2,800·
Remaining voe coca BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL NA NA NA Varies Varies
Seml-VOCs-u u u u u u ""~" u u u u u u u u
Acenanhthene BDL BDL BDL BDL BDL 501 BDL BDL BDL BDL BDL BDL NA NA NA 680,000 10,000
Anthracene BDL BDL BDL BDL BDL 668 BDL BDL BDL BDL BDL BDL NA NA NA 3.400,000 87,000
Benzo(a)anthracene BDL BDL BDL BDL BDL 2,840 BDL BDL BDL BDL BDL BDL NA NA NA 150 220
Benzo(b)pyrene BDL BDL BDL BDL BDL 2.620 BDL BDL BDL BDL BDL BDL NA NA NA 15 75
Benzolb)flouranthene BDL BDL BDL BDL BDL 3,570 BDL BDL BDL BDL BDL BDL NA NA NA 150 770
Benzo(o,h)oervlene BDL BDL BDL BDL BDL 1,850 BDL BDL BDL BDL BDL BDL NA NA NA No Standard 11,000,000
Benzo/k)fluoranthene BDL BDL BDL BDL BDL 1,190 BDL BDL BDL BDL BDL BDL NA NA NA 1,500 7,500
Chrvsene BDL BDL BDL BDL BDL 3.070 BDL BDL BDl BDL BDL BDL NA NA NA 15,000 23,000
Oibenzla,hlanthracene BDL BDL BDL BDL BDL 435 BDL BDL BDL BDL BDL BDL NA NA NA 15 250
Flouranthene BDL BDL BDL BDL BDL 6,060 BDL BDL BDL BDL BDL BDL NA NA NA 460,000 400.000
lndeno(1,2, 3-cd )pvrene BDL BDL BDL BDL BDL 1.660 BDL BDL BDL BDL BDL BDL NA NA NA 150 2,600
Phenanthrene BDL BDL BDL BDL BDL 3,240 BDL BDL BDL BDL BDL BDL NA NA NA No Standard 88,000
Pyrene BDL BDL BDL BDL BDL 5.080 BDL BDL BDL BDL BDL BDL NA NA NA 340,000 290,000
Remaining Semi• voe BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL NA NA NA Varies Varies
Dioxin ng/kg ••" pg/I pg/I pg/I ••" pg/I ••" . pgn ••" ••" pg/I pg/I pg/J pg/I mg/kg_ mg/kg
2,3,7,8-TCDD BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL NA NA NA 0.001 0.00000064
Metals mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg ma/kg mg/kg mg/kg mg/kg '
Aluminum 918 1,460 1.260 522 4,100 1,830 1,190 1,290 1,000 1,770 1.150 1,400 2,190 600 2,250 15,000 No Standard
Antimonv BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 6.2 No Standard
Arsenic 0.39 5.8 4.7 BDL 0.54 0.89 4.7 2.0 6.0 1.4 4.5 0.53 BDL BDL 0.41 4.4 5.4
Bervllium BDL 0.63 0.35 BDL BDL BDL 0.32 0.22 0.2 0.21 0.2 BDL NA NA NA 32 No Standard
Chromium 1.2 3.6 4.5 0.71 3.3 1.9 3.0 2.9 35 3.9 3.1 1.6 2.1 0.94 2.4 280 No Standard
Copoer BDL 0.66 0.51 0.51 BDL 0.73 BDL BDL 0.37 BDL BDL BDL BDL BDL BDL 630 700
Iron (total) 395 4,400 4,320 399 542 822 3,820 4,030 4,520 2,760 5,130 643 438 250 434 11,000 150
Lead 4.7 2.0 1.4 3.2 3.7 4.3 1.9 2.2 1.7 1.8 25 2.6 4.5 6.0 3.8 400 270
Nickel 0.42 3.7 4.1 0.57 0.82 0.56 4.3 2.3 1.1 1.9 2.3 0.55 BDL BDL BDL 300 130
Thallium BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 1.0 No Standard
Zinc 1.1 9.8 11.5 2 0.98 2.7 9.6 4.3 4.7 4.7 6.9 2.0 BDL BDL BDL 4600 No Standard
voes = Volatile Organic Cornpouns NA = Not Analyzed SOL = Below Detection Limit
' -EPA Region 9 drinking water standard COC = Chemicals of Concern Red Number= Exceeds Preliminary SRG
lHSB = Inactive Hazardous Sites Branch SRG = Soil Remediation Goal Bold Number= exceeds Protection of Groundwater SRG
TABLE 2 -SOIL ANALITICAL DATA -PAHs
CASTLE HAYNE SC.HOOL CAMPUS
4416 CASTLE HAYNE ROAD
CASTLE HAYNE~ NORTH CAROLINA
ECS PROJECT NO. 22-12493E
IHSB IHSB Protection
Location HA_. HA-13 HA-14 HA-15 HA-16 HA-17 HA-18 HA-19 Preliminary of Groundwater
Date 11/11/09 1/6/10 1/6/10 1/6/10 1/6/10 1/6/10 1/6/10 1/6/10 SRG SRG
PAHs u UQ!kQ ""'"" u u u u-~-um•n
Acenaphthene 501 SDL SDL SDL SDL SDL SDL SDL 680,000 10,000
Anthracene 668 SDL SDL SOL SDL SDL SDL SDL 3,400,000 87,000
Benzo(a)anthracene 2,840 SOL SDL SDL SDL SDL BDL SDL 150 220
Benzo(b)pyrene 2,620 SDL SDL SDL SDL SDL BDL SDL 15 75
Benzo(b)flouranthene 3,570 SDL SDL SDL SDL SDL BDL SDL 150 770
Benzo(g,h)perylene 1,850 SDL SDL SDL SDL SDL BDL SDL No Standard 11,000,000
Benzo(k)fluoranthene 1,190 SDL SDL SDL SDL SDL SDL SDL 1,500 7,500
Chrysene 3,070 SDL SDL SDL SDL SDL SDL SDL 15,000 23,000
Dibenz(a,h)anthracene 435 SDL SDL SOL BDL SDL SDL SDL 15 250
Flouranthene 6,060 SDL SDL SOL SDL SDL SDL SDL 460,000 400,000
lndeno(1,2,3-cd)pvrene 1,660 SDL SDL SOL BDL SDL SDL SDL 150 2,600
Phenanthrene 3,240 SDL SDL SDL SDL SDL SDL SDL No Standard 88,000
Pyrene 5,080 SDL SDL SDL SDL SDL SDL SDL 340,000 290,000
Remaining PAHss SDL SDL SDL SDL SDL SDL SDL SDL Varies Varies
Location HA-20 HA-21 HA-22 HA-23 HA-24 HA-25 HA-26 HA-27 Preliminary of Groundwater
Date 1/6/10 1/6/10 116/10 1/6/10 1/6/10 1/6/10 1/6/10 1/6/10 SRG SRG
PAHs u ualkr:J ualka um•n u u unlkn ""'"" Acenaphthene SDL SOL SDL SDL NA SDL SDL SDL 680,000 10,000
Anthracene SDL SOL SDL SDL NA SDL SDL SDL 3,400,000 87,000
Benzo(a)anthracene 670 SDL SDL SDL NA SDL SDL SDL 150 220
Benzo(b)pyrene 699 SOL SDL SDL NA SDL SDL SDL 15 75
Benzo(b)flouranthene 1,020 SOL SDL SDL NA SDL SDL SDL 150 770
Benzo(g,h)perylene SDL SDL SDL SDL NA SDL SOL SOL No Standard 11,000,000
Benzo(k)fluoranthene 429 SDL SOL BDL NA SOL SOL SOL 1,500 7,500
Chrysene 789 SOL SOL SOL NA SDL SOL SOL 15,000 23,000
Dibenz(a,h)anthracene SDL SOL SOL SOL NA SOL SOL SOL 15 250
Flouranthene 1360 SOL SOL SOL NA SDL SOL SOL 460,000 400,000
lndeno(1,2,3-cd)pvrene SDL SOL SDL SOL NA SOL SOL SOL 150 2,600
Phenanthrene 794 SOL BOL SOL NA SOL SOL SOL No Standard 88,000
Pvrene 1,230 SOL SOL SOL NA SDL SOL SOL 340,000 290,000
Remaining PAHss SOL SOL SOL BOL NA SOL SOL SOL Varies Varies
BDL = Below Detection Limit SRG = Soil Remediation Goal Red Number = Exceeds Preliminary SRG
IHSB = Inactive Hazardous Sites Branch Bold Number= exceeds Protection of Groundwater SRG
TABLE 3. GROUNDWATER ANALITICAL DATA
CASTLE HAYNE SCHOOL CAMPUS
4416 CASTLE HAYNE ROAD
CASTLE HAYNE, NORTH CAROLINA
ECS PROJECT NO. 22-12493D
NeAe 2L Groundwater -Location TW-1 TW-2 TW-3 TW-4 TW-5 TW-6 VE-1 IW-1 MW-1 MW-1 TMW-1W TMW-2W TMW-3W TMW-4W Standard
Date 10f11f06 10/11106 10111/06 10111106 10111/06 10123106 10/23106 11/2107 1112/07 1217/07 11117/09 11117109 11/17/09 11/17/09
voes """ ug/1 """ """ """ mg/I .mg/I ug/1 """ ug/1 """ ug/1. """ """ """ ehloromethane BDL BDL BDL BDL BDL BDL BDL BDL NA NA BDL BDL BDL 1.5 3
4-lsonronultoluene 1.23 BDL BDL BDL BDL BDL BDL BDL NA NA BDL BDL BDL BDL NE
Remaining voe eoes BDL BDL BDL BDL BDL BDL BDL BDL NA NA BDL BDL BDL BDL Varies
Sem/.VOCs ugn """ , ug/1 """ ug/1 mg/I mg/I · ug/I ug/1 . """ ug/1 """ """ ug/1 ug/1
Semi . voe cocs BDL BDL BDL BDL BDL BDL BDL BDL NA NA BDL BDL BDL BDL Varies
Dioxin .pg/I pgn pg/I pgn pgn pgn pg/I pg/I pgn pg/I pgn pgn pgn pg/I pg/I
2,3,7,8-TCOO NA NA NA NA NA NA NA NA NA NA BDL BDL BDL NA 0.2
Pesticides mg/I mg/I mg/I mg/I mg/I I mg/I mg/I mg/I mg/I mgn mg/I mg/I mg/I mgn mg/I
Pesticide COCs NA NA NA NA NA BDL BDL NA NA NA NA NA NA NA Varies
Inorganic Parameter mgn mg/I mg/I mgn me/I I mg/I mo/I mgn rria/1 mg/I mo/I mg/I mg/I mgn mg/I.
Alkalinitv NA NA NA NA NA NA NA 234 NA NA NA NA NA NA NE
Fecal Coliform NA NA NA NA NA NA NA <1 NA NA NA NA NA NA NE
Fluoride NA NA NA NA NA NA NA 0.1 NA NA NA NA NA NA 2.0
Nitrite NA NA NA NA NA NA NA <.02 NA NA NA NA NA NA 1.0
Total Colifonn NA NA NA NA NA NA NA <1 NA NA NA NA NA NA 0.01
Chloride NA NA NA NA NA NA NA 7.96 NA NA NA NA NA NA 250
Nitrate NA NA NA NA NA NA NA <0.300 NA NA NA NA NA NA 10
Hardness NA NA NA NA NA NA NA 231 NA NA NA NA NA NA NE
pH NA NA NA NA NA NA NA 7.96 8.00 NA 4.08 5.15 4.55 5.57 6.5-8.5
Metals mg/I mg/I mg/I mg/I mg/I mg/I mg/I mgn mg/I mg/I mg/I mg/I mg/I mgn mgn
Aluminum NA NA NA NA NA NA NA <0.200 1.54 0.363 18.000 3.06 0.619 6.090 37•
Antimony NA NA NA NA NA BDL BDL NA NA NA BDL BDL BDL BDL 0.015"
Arsenic NA NA NA NA NA BDL BDL BDL BDL BDL 0.0097 BDL 0.0180 BDL 0.01
Bervlllum NA NA NA NA NA BDL BDL NA NA NA 0.004 BDL BDL BDL 0.037"
Cadmium NA NA NA NA NA BDL · BDL NA NA NA NA NA NA NA 0.002
Chromium NA NA NA NA NA 0.014 0.013 NA NA NA 0.0078 0.0067 BDL 0.0116 0.01
Copper NA NA NA NA NA BDL BDL BDL NA NA BDL BDL BDL BDL 1.0
Iron (total) NA NA NA NA NA NA NA 2.00 NA NA 65.200 6.480 19.300 9.600 0.3
Iron (disolvedl NA NA NA NA NA NA NA 1.86 NA NA NA NA NA NA NE
Lead NA NA NA NA NA 0.0059 0.0053 BDL NA NA BDL BDL BDL 0.006 0.015
Mannesium NA NA NA NA NA NA NA 1.58 NA NA BDL BDL BDL BDL NE
Manoanese NA NA NA NA NA NA NA 0.0913 NA NA BDL BDL BDL BDL 0.05
Mercurv NA NA NA NA NA BDL BDL NA NA NA NA NA NA NA 0.001
Nickel NA NA NA NA NA BDL BDL NA NA NA 0.0430 0.0053 BDL BDL 0.1
Selinium NA NA NA NA NA BDL BDL NA NA NA NA NA NA NA 0.05
Silver NA NA NA NA NA BDL BDL NA NA NA NA NA NA NA 0.02
Thallium NA NA NA NA NA BDL BDL BDL BDL BDL BDL BDL BDL BDL 0.0024"
Zinc NA NA NA NA NA BDL 0.044 <0.0200 NA NA 0.0687 BDL BDL 0.0185 1
VOCs -Volatile Ornanic Comnouns • -EPA Rec ion 9 drinking water standard NE -Not Established NA -Not Anatvzed CDC Chemicals of Concern
CLIENT JOB#
New Hanover County Schools 22-12493D
BORING#
HA-1
PROJECT NAME
Castle Hayne School Campus
ARCHITECT-ENGINEER
Amy Conchas
SITE LOCATION
Holly Shelter Road, Castle Hayne, New Hanover County, North Carolina
w u z
w ;" '2 DESCRIPTION OF MATERIAL a. ~
~ "' >-g 0 "' w w w
le J J > a. a. 0 a. ::a :1 '2 u w "' w Cl "' (lj '= "' APPROXIMATE ELEVATION : •• FEET ABOVE MSL
Black organic sand -
-Grey sand
ss 24 Brown and red fine sand, some silt and organics -
-
-ss 24 -
-s_
ss 24 -
-ss 24 -
-ss 24 -
10
-
-ss 24 -
-
-ss 24 -
15 _
ss 24 -
-
-ss 24 -
-
-ss 24 -20
SHEET
1 OF 1
-
---
~
I-
~
~
~
~
I-
~
I-
I-
~
I-
I-
~
~
I-
~
~
~
~
~
~
~
I-
I-
I-
I-
I-
I-
I-
I-
I-
I-
I-
I-
I-
J w~ FID > C W-" READINGS J. cr:..2~ (ppm)
UJ .8 8 ~o~
~~:, -·
0.0
0.0
0.0
THE STRATIFICATION LINE REPRESENTS THE APPROXIMATE BOUNDARY LINE BETWEEN SOIL lYPES IN-SITU. THE TRANSITION MAY BE GRADUAL.
DATE INSTALLED I RIG TYPE I FOREMAN I DRILUNG METHOD NOTES
11 /11 /09 Hand Auaer Amv Conchas Hand Auaer
CLIENT JOB# BORING# SHEET
New Hanover County Schools 22-12493D HA-2 1 OF 1 '"
~~ PROJECT NAME ARCHITECT-ENGINEER
Castle Hayne School Campus Amy Conchas
..._',/,I. 1 1111.IP
SITE LOCATION
Holly Shelter Road, Castle Hayne, New Hanover County, North Carolina <C~IJ:;l.<Clll.Olis!I~~
w " z ...,
w lo '2 DESCRIPTION OF MATERIAL w~ FID a. = > C
i'= U) >-w.a READINGS □ a: ..., . s w w w a::: ..Q ...... (ppm) :i: J J ii w •• >-a. a. >-n o a. ~ " -" <( QI~ w ~;§ w :s:~ ~ 0 U) a: APPROXIMATE ELEVATION : •• FEET ABOVE MSL -·
Brown sand, fill 0.4 --Brown and grey sand, fill 0.6 --ss 24 Brown sand and black organics, organic odor 0.4 -r-
r-
----ss 24 -r-
r-
--5_ r-ss 24 --r-
----ss 24 --
-
--
--ss 24 --10 -
--
--ss 24 --
-
----ss 24 -r----15 -r-ss 24 -------ss 24 -r-----r-
-ss 24
20 r--
THE STRATIFICATION LINE REPRESENTS THE APPROXIMATE BOUNDARY LINE BETWEEN SOIL TYPES IN-SITU. THE TRANSITION MAY BE GRADUAL.
DATE INSTALLED I RIG TYPE I FOREMAN I DRILLING METHOD NOTES
11/11/09 Hand AuQer Amy Conchas Hand AuQer
CLIENT JOB# BORING# SHEET
New Hanover County Schools 22-124930 HA-3 1 OF 1 '"
~ PROJECT NAME ARCHITECT-ENGINEER ' Castle Hayne School Campus Amy Conchas ~-
1 r!a.11.1? SITE LOCATION
Holly Shelter Road, Castle Hayne, New Hanover County, North Carolina <C:A~(O)ILOIJ\!IA~
w u J z
w fO '2 DESCRIPTION OF MATERIAL UJ ~ FID o_ ~ >c
~ "' >-UJ .. READINGS g 1S "' J. w w w er; .2 ~ (ppm) I J J > UJ •• e-o_ o_ 0 S-Do o_ " ~'2 u ~ii{! w ;ii w :': • a 0 C/Jc "' APPROXIMATE ELEVATION: •• FEET ABOVE MSL ~-
Tan and brown sandy fill 0.0 --Tan and brown sandy fill 0.0 --ss 24 Tan and brown sandy fill 0.0 -----
--ss 24 -f-
f-
5-f--f-ss 24 -f-
f-
-f-
-f-ss 24 -f-
f-
-f-
-ss 24 f-
--10 -
--
--ss 24 --
-
--
--ss 24 ---
--15 _ -ss 24 --
f-
-f-
-f-ss 24 -f-
f-
-f-
-ss 24 f-
20 -f-
f-
THE STRATIFICATION LINE REPRESENTS THE APPROXIMATE BOUNDARY LINE BElWEEN SOIL TYPES IN-SITU. THE TRANSITION MAY BE GRADUAL
DATE INSTALLED I RIG TYPE I FOREMAN I DRILLING METHOD. NOTES
".11/11/09 Hand Auqer Amv Conchas Hand Auqer
CLIENT JOB# BORING# SHEET
New Hanover County Schools 22-124930 HA-4 1 OF 1 '" -
~:~, PROJECT NAME ARCHITECT-ENGINEER
Castle Hayne School Campus Amy Conchas C -~ -11.11.1?
SITE LOCATION
Holly Shelter Road, Castle Hayne, New Hanover County, North Carolina <c:~~@11..mM~~
w u _, z
w ;<: c DESCRIPTION OF MATERIAL UJ ~ FID a. ~ > C "' UJ., i'c 0 >-_, . READINGS g 0: w w w ffi ~ a> (ppm) I _, _, i'i f-a. a. ,_ ~ 0 a. ::; ::; -u <(iii~ w "' ;1j:.§_ w :s: .l!! :J □ "' 0: APPROXIMATE ELEVATION : •• FEET ABOVE MSL -·
Grass and organics 0.3 -'-
-Tan sandy '-0.4
ss 24 Tan sandy 0.4 -'-
'-
-~
-'-
-ss 24 '-
'-
'-
5_ '-ss 24 '-
'-
-'-
-'-
-ss 24 '--
-'-
-~
-ss 24 ~ 10 '-
-'-
-~
-ss 24 '-
'-
-'-
--'-ss 24 '-
~
-'-15 _ '-ss 24 -'-
~
-~ --~
-ss 24 '-
'--~
-'--ss 24 '-20 '-
THE STRATIFICATION LINE REPRESENTS THE APPROXIMATE BOUNDARY LINE BETWEEN SOIL TYPES IN-SITU. THE TRANSITION MAY BE GRADUAL
DATE INSTALLED l RIGlYPE l FOREMAN I DRILLING METHOD NOTES
11/11/09 Hand Auaer Amv Conchas Hand Auaer
CLIENT JOB# BORING# SHEET
New Hanover County Schools 22-12493D HA-5 1 OF 1 '"
~ I
PROJECT NAME ARCHITECT-ENGINEER
Castle Hayne School Campus Amy Conchas ~ l!..l!..[F) SITE LOCATION --Holly Shelter Road, Castle Hayne, New Hanover County, North Carolina <C~IF:l.<O>ll..mM&l>\$,'l
w " ..., z
w ;o c DESCRIPTION OF MATERIAL UJ ~ FID a. ~ > C
i'.: "' >-UJ .,, READINGS g o 0: ..., .
w w w 0:: .Q ,...._ (ppm) :x: ..., ..., ii UJ •• >-a. a. >-~ 0 a. ~ " -" <{ ai ~ w iJ5 §, w ,: • a Cl "' 0: APPROXIMATE ELEVATION: .. FEET ABOVE MSL ,e, •
-Black organics soil 0.1 ~
-Black organic soil ~ 1.0
-ss 24 Black organic soil' .._ 16.8
~
-~ .._ ss 24 -~
~
-5_ -ss 24 .._ .._
-~
-~ ss 24 .._
~
-~
-~ ss 24 -~ 10 ~
-~
-~ ss 24 -~
~
-.._
ss 24
.._ .._
~
-.._
15 _ .._ ss 24 -~
~
-~
-~ ss 24 -~
~
-~
ss 24 ~
-~ 20 ~
THE STRATIFICATION LINE REPRESENTS THE APPROXIMATE BOUNDARY LINE BElWEEN SOIL TYPES IN-SITU. THE TRANSITION MAY BE GRADUAL
DATE INSTALLED l RIG TYPE l FOREMAN I DRILLING METHOD NOTES
_11/11/09 Hand Auaer Amv Conchas Hand Auaer
CLIENT JOB# BORING# SHEET
New Hanover County Schools 22-12493D HA-6 1 OF 1 '"
~ I
PROJECT NAME ARCHITECT-ENGINEER
Castle Hayne School Campus Amy Conchas ==--[L[L[f) SITE LOCATION
Holly Shelter Road, Castle Hayne, New Hanover County, North Carolina Cffe<.l)':2_©)11..0IMffe<.~
w (.) z -' w ;! '2 DESCRIPTION OF MATERIAL w~ FID "-~ >c
/:: <I> >-W-" READINGS 5 □ a: -' . w w w 0:::..2-(ppm) I J J ei w•• >-"-"-f--D 0 "-:;; :;; -(.) <( ~ ~ w <{ ~;§ w :;: • a 0 <I> a: APPROXIMATE ELEVATION:•• FEET ABOVE MSL ~-
Organic top soil 0.0 --White and brown silty sand 1.2 --ss 24 Black organic s·and, organic odor 1.0 --
-
--
--ss -24 f---
f---
5-f----f---ss 24 -f---
f---
-f---
-f---ss 24 -f---
f---
-f---
--ss 24 --10 -
--
--ss 24 --
-
--
--ss 24 --
-
--15 --ss 24 --
f---
-f---
-f---ss 24 -f---
f----f---
-ss 24 f---
20-f---
f---
THE STRATIFICATION LINE REPRESENTS THE APPROXIMATE BOUNDARY LINE BElWEEN SOIL TYPES IN-SITU. THE TRANSITION MAY BE GRADUAL.
DATE INSTALLED I RIG TYPE I FOREMAN I DRILLING METHOD NOTES
11/11/09 Hand Auqer Amy Conchas Hand Auoer
CLIENT
New Hanover County Schools
PROJECT NAME
Castle Hayne School Campus
SITE LOCATION
JOB#
22-12493D
BORING#
HA-7
ARCHITECT-ENGINEER
Amy Conchas
Holly Shelter Road, Castle Hayne, New Hanover County, North Carolina
w " z
w '° ~ DESCRIPTION OF MATERIAL a. "' 1:: >-g i:i 0: w w w
,: .J .J i, >-a. a. a. " " -" w "" c:i.g w 0 "' a: APPROXIMATE ELEVATION : •• FEET ABOVE MSL
Black and brown fine sand -
. Grey and brown sand
ss 24 Grey and brown sand -
-
-ss 24 -
-s_
ss 24 -
-
-ss 24 -
-ss 24 -10
-
--ss 24 -
-
-ss 24 -
-15 _
ss 24
-
-ss 24 -
-
-ss 24 -20
SHEET
1 OF 1
-
-
-
-
-
~
~
~
~
~
~
~
'-
~
~
'-
'-
~
'-
'-
~
'-
~
~
~
~
~
'-
~
~
'-
~
'-
'-
~
'-
'-
~
~
L_
.J w~ FID > C w.!! READINGS .J • ffi~Q) (ppm) >-~ 0
<( ai {! ~~~
0.0
0.0
0.0
THE STRATIFICATION LINE REPRESENTS THE APPROXIMATE BOUNDARY LINE BETWEEN SOIL lYPES IN-SITU. THE TRANSITION MAY BE GRADUAL.
L DATE INSTALLED I RIG lYPE I FOREMAN I DRILLING METHOD NOTES
11111/09 Hand Auoer Amv Conchas Hand Auoer
CLIENT
New Hanover County Schools
PROJECT NAME
Castle Hayne School Campus
SITE LOCATION
JOB#
22-12493D
BORING#
ARCHITECT-ENGINEER
Amy Conchas
HA-8
Holly Shelter Road, Castle Hayne, New Hanover County, North Carolina
w u z w ;o ,§, DESCRIPTION OF MATERIAL 0. "' i= □ >-g "' w w w
I -' -' > I-0. 0. 0 0. " "-u w <( ;:; ;§ w 0 "' "' APPROXIMATE ELEVATION: •• FEET ABOVE MSL
Brown sand fill -
-Brown grey sand
ss 24 Brown grey sand -
-
-ss 24 -
-s_
ss 24 -
-
-ss 24 -
'-
-ss 24 -
10
-
-ss 24 -
-ss 24 -
-15 _
ss 24
-
ss 24 -
-
-ss 24 -20
SHEET
1 OF 1
-
-
-
-
-
-
~
~
~
~
~
~
'--
~
~
'--
~
~
'--
'--
~
~
~
~
'--
~
~
'--
~
~
'--
~
'--
'--
~
~
~
~
~
~
-' w~ FID > C w-" -' . READINGS a:: .Q .-. (ppm) w •• I-~ 0
<C CD~ 3: .l!! ::I -·
0.0
0.9
1.6
THE STRATIFICATION LINE REPRESENTS THE APPROXIMATE BOUNDARY LINE BETWEEN SOIL TYPES IN-SITU. THE TRANSITION MAY BE GRADUAL
DATE INSTALLED I RIG TYPE · 1 FOREMAN I DRILLING METHOD NOTES
11 /11 /09 Hand Auaer Amv Conchas Hand Aun er
CLIENT JOB# BORING# SHEET
New Hanover County Schools 22-124930 HA-9 1 OF 1 '"
'fL{R', PROJECT NAME ARCHITECT-ENGINEER
Castle Hayne School Campus Amy Conchas .
' [1[1[p
SITE LOCATION
Holly Shelter Road, Castle Hayne, New Hanover County, North Carolina C~~(O)ll.Dlll!I~~
w u __, z
w ;:: 2 DESCRIPTION OF MATERIAL Wu FID a. ~ > C
~ "' >-w" READINGS 1S 0: __, . "' w w w c::: .Q,....., (ppm) I J J > w •• >-a. a. 0 >-~ 0 a. " " -u <( ai .g w <( ~ ,§_ w ;: . , 0 "' 0: APPROXIMATE ELEVATION: •• FEET ABOVE MSL ,e, •
Light brown sand, fill 0.3 --Light brown sand, fill -0.1 ss 24 Light brown sand, fill 0.2 --
~
. ~
-~
-ss 24 ~
~
-~ s_ ~ ss 24 -~
~
-\-
-~
-ss 24 ~
\-
-\-
-~ ss 24 \-10 \-
-\-
ss 24 --~
~
-~
-~
-ss 24 ~
\-
-~ 15 _
~ ss 24 -~
\-
\-
ss 24 \-
-~
~
-\-
-~
-ss 24 ~ 20
~
THE STRATIFICATION LINE REPRESENTS THE APPROXIMATE BOUNDARY LINE BElWEEN SOIL TYPES IN-SITU. THE TRANSITION MAY BE GRADUAL.
DATE INSTALLED I RIG lYPE ! FOREMAN I DRILLING METHOD NOTES
11/11/09 Hand Auner Amv Conchas Hand Auner
CLIENT JOB# BORING# SHEET
New Hanover County Schools 22-12493D HA-10 1 OF 1 ..
' t~~ PROJECT NAME ARCHITECT-ENGINEER ~-~
Castle Hayne School Campus Amy Conchas j!Jl ~I
:i l!.l!.tF' SITE LOCATION
Holly Shelter Road, Castle Hayne, New Hanover County, North Carolina ~~~@11..alJl!I~~
w u -' z
w " "2 DESCRIPTION OF MATERIAL w~ FID t-C >c 0. "' w-" ~ >-READINGS g 1S "' -' ' w w w ffi~~ (ppm) I ~ ~ > t-0. 0. 0 t-D 0 0. ::; ::;_ u <( 1u ~ w " ;% :§ w ,: • a D "' "' APPROXIMATE ELEVATION:•• FEET ABOVE MSL ~-
-Tan and grey sand, fill ~ 0.0
. Black organic, silty sand, organic sewer odor -0.2
ss 24 Black organic, silty sand 1.2 --
-
... -
--ss 24 --
~
-~
5_ ~
-ss 24 '-
~
-'-
-'-ss 24 -~
'--'-
-~ ss 24 ~ 10 '-
-~
ss 24 '-
-~
~
-'-
-~ ss 24 -~
'-
'-15 _
~ ss 24 '-
~
-~
-~ ss 24 -~
~
-'--~ ss 24 -~ 20 '--
THE STRATIFICATION LINE REPRESENTS THE APPROXIMATE BOUNDARY LINE BETWEEN SOIL TYPES IN-SITU. THE TRANSITION MAY BE GRADUAL.
DATE INSTALLED l RIG TYPE I FOREMAN I DRILLING METHOD NOTES
11/11/09 Hand Auner Amv Conchas Hand Auner
CLIENT JOB# BORING# SHEET
New Hanover County Schools 22-12493D HA-11 1 OF 1 '"
t1~ PROJECT NAME ARCHITECT-ENGINEER
Castle Hayne School Campus Amy Conchas 181: ' ...... [bf.bl?
SITE LOCATION " Holly Shelter Road, Castle Hayne, New Hanover County, North Carolina c~~(O)ll..alNI~®
w (J z -'
w ;o '2 DESCRIPTION OF MATERIAL w~ FID >• n. "' = W-" ~ >-READINGS g i5 a: -' . w w w 0::: ..Q --(ppm) :c ~ ~ > w •• ' t-n. n. 0 t-~ u n. " ;! c (J ~-a;~ w <( w ~~;;: 0 "' I.I)= a: APPROXIMATE ELEVATION: •• FEET ABOVE MSL
Orange sand fill 0.0 -I-
-Orange and grey sand I-0.0
ss 24 Black organic sand 0.0 I-
I-
-I-
--I-ss 24 I-
I-
-I-
5_ I-ss 24 -I-
I-
-I-
--ss 24 --
I-
-I-
-I-
-ss 24 I-10 I-
I-
-I-ss 24 -I-
I-
-I-
-I-
-ss 24 I-
I-
-I-15 _ I-
ss 24 -I-
I-
-I-
-I-ss 24 -I-
I-
-I-
-I-ss 24 I-20 I-
THE STRATIFICATION LINE REPRESENTS THE APPROXIMATE BOUNDARY LINE BElWEEN SOIL TYPES IN-SITU. THE TRANSITION MAY BE GRADUAL
DATE INSTALLED l RIG TYPE I FOREMAN -1 DRILLING METHOD NOTES
11111109 Hand Auner Amv Conchas Hand Auner
CLIENT
New Hanover County Schools
PROJECT NAME
Castle Hayne School Campus
SITE LOCATION
JOB#
22-12493D
BORING#
HA-12
ARCHITECT-ENGINEER
Amy Conchas
Holly Shelter Road, Castle Hayne, New Hanover County, North Carolina
w L) z
w "' '2 DESCRIPTION OF MATERIAL "->--~
i= "' >-g ci 0: w w w
I ~ _, > >--"-"-0 "-" " -L) w "' :}jg w c:, "' 0: APPROXIMATE ELEVATION : •• FEET ABOVE MSL
Grey and black fine sand -
-Grey and black fine sand ss 24 Black organic soil .
-
--ss 24
-
5_
ss 24 -
-
-ss 24 --
-
-ss 24 -10
-
-ss 24 -
-
-ss 24 -
-15 _
ss 24 -
-
-ss 24 -
-·
-ss 24 -20
SHEET
1 OF 1
-
-
-
-
-
---
C-
C-
~
C-
~
~
C-
~
~
~
~
~
~
~
C-
C-
~
~
C--
~
~
~
~
~
~
C-
C-
C-
C-
C-
~
_, w~ FID > C w" READINGS _, .
0::: .Q ~ (ppm) w •• f-Du
<{ ai ~ 3: .l!! :, -· 0.0
1.0
2.9
THE STRATIFICATION LINE REPRESENTS THE APPROXIMATE BOUNDARY LINE BElWEEN SOIL TYPES IN-SITU. THE TRANSITION MAY BE GRADUAL
DATE INSTALLED l RIG TYPE I FOREMAN l DRILLING METHOD NOTES
11/11/09 Hand Auaer Amv Conchas Hand Auaer
CLIENT
New Hanover County Schools
JOB#
22-12493D
BORING#
TMW-
1W
PROJECT NAME
Castle Hayne School Campus
ARCHITECT-ENGINEER
Amy Conchas
SITE LOCATION
Holly Shelter Road, Castle Hayne, New Hanover County, North Carolina
DESCRIPTION OF MATERIAL
APPROXIMATE ELEVATION:•• FEET ABOVE MSL
-
-_ ss 24 Black organic sandy silt
-
-_ ss 24 Black sand and silt
5_
ss 24 Black and brown silt
-
-ss 24 Black and brown silty sand to grey clay, wet
-
-_ ss 24 Grey clay with sandy silt
10 -f------l--+-~
-
-_ ss 24 Grey sand, slight clay, saturated
-
ss 24 Grey and brown sand, wet
-15 _
ss 24 Grey sandy clay, wet -
-
-_ ss 24 Grey and brown sand, some clay
-
_ ss 24 Grey and brown sand, some clay
20 -1.--__J_-----'--
SHEET
1 OF 1
-
-
-
-
:!_4.27
,,
FID
READINGS
(ppm)
THE STRATIFICATION LINE REPRESENTS THE APPROXIMATE BOUNDARY LINE BETWEEN SOIL TYPES IN-SITU. THE TRANSITION MAY BE GRADUAL
I-DATE INSTALLED l RIG TYPE I FOREMAN I DRILUNG METHOD NOTES
11/16/09 GeoProbe MAD, Inc. Direct Push
CLIENT JOB# BORING# SHEET
New Hanover County Schools 22-12493D TMW-1 OF 1 '"
2W ~~~I PROJECT NAME ARCHITECT-ENGINEER
Castle Hayne School Campus Amy Conchas \!0: .
. 1 11.llJP SITE LOCATION
Holly Shelter Road, Castle Hayne, New Hanover County, North Carolina \CUJ\.[Fl@II..OIMUJ\.~
w L) z J
w ;o I DESCRIPTION OF MATERIAL w~ FID >c 0. "' w.,, /: >-READINGS g □ a: J. w w w 0:::.9,...._ (ppm) :c J J ei w•• >-0. 0. r-Du 0. " " -L) <((I)~ w <( ~_§ w s: .!: :, 0 "' a: APPROXIMATE ELEVATION:•• FEET ABOVE MSL -·
-~
-~ ss 24 Black organic soil --
-Brown sand ----
-ss 24 Light brown sand, moist -_ ~3.71
--s_ ~
-ss 24 Grey sand, moist
~
~ .._
-~
-ss 24 Grey fine sand, moist ~ .._ .._
-~ ss 24 -Grey clay ~
10 .._
-~
-~
-ss 24 Grey clay ~
~
~
-~
-ss 24 Grey clay, wet ~ .._
-~ 15 _ ~
-ss 24 Grey clay, wet ~ .._
-.._
-.._
-ss 24 Grey clay, wet ~
~
-~
-~
-ss 24 Grey clay, wet ~ 20 ~
THE STRATIFICATION LINE REPRESENTS THE APPROXIMATE BOUNDARY llNE BElWEEN SOIL: TYPES IN-SITU. THE TRANSITION MAY BE GRADUAL.
DATE INSTALLED I RIG TYPE I FOREMAN I DRILLING METHOD NOTES
11/16/09 GeoProbe MAD, Inc. Direct Push
CLIENT JOB# BORING# SHEET
New Hanover County Sc_hools 22-12493D TMW-1 OF 1 ..
3W
~-
PROJECT NAME ARCHITECT-ENGINEER
Castle Hayne School Campus Amy Conchas .
I [1[1.[p
SITE LOCATION .
Holly Shelter Road, Castle Hayne, New Hanover County, North Carolina Cti\~@11..D !Mti\®
w
<.) ~ ,z
w lo ~ DESCRIPTION OF MATERIAL w~ FID a. > C
i'c: "' >-W-" READINGS g □ 0: ~. w w w a:. .Q ....... (ppm) :,: J J > w •• f-a. a. 0 ,-~ u a. " ~c: <.) <{ w ~ w "' w ~~~ " "' Cf)~ 0: APPROXIMATE ELEVATION:•• FEET ABOVE MSL
----ss 24 Black organic soil -f----' -f-ss 24 Grey sand ---
5----ss 24 Grey sand with some yellow fine sand --
-
--
--ss Grey fine sand, moist -24 -
-Yellow sand, wet --'I' 8.88 ---ss 24 -Brown clay -10 f-
~ --f-ss 24 Grey clay ----f-
--ss 24 Grey clay ---
15 = f-
f-ss 24 Grey sandy clay I --
-
--
--ss 24 Grey silty clay, wet --
-
--
-_:_ ss 24 Sandy clay, wet --20 -
THE STRATIFICATION LINE REPRESENTS THE APPROXIMATE BOUNDARY LINE BETWEEN SOIL lYPES IN-SITU. THE TRANSITION MAY BE GRADUAL
DATE INSTALLED I RIG TYPE I FOREMAN \ DRILLING METHOD NOTES
11/16/09 GeoProbe MAD, Inc. Direct Push
CLIENT BORING#
New Hanover County Schools
JOB#
22-124930 TMW-
4W
PROJECT NAME
Castle Hayne School Campus
ARCHITECT-ENGINEER
Amy Conchas
SITE LOCATION
Holly Shelter Road, Castle Hayne, New Hanover County, North Carolina
w L) z
w ;:: 2 DESCRIPTION OF MATERIAL <L ~
i!: "' >-g 0 0: w w w
I J J > .... <L <L 0 <L ! :, -L) w ~,§. w " 0: APPROXIMATE ELEVATION:•• FEET ABOVE MSL
-
-ss 24 Brown sand -
-
-ss 24 Brown fine sand -
5--ss 24 Brown fine sand -
-
-ss 24 Grey fine sand, some clay -
. -
-ss -24 Grey and dark grey clay with some silt, saturated
10
-
-Grey clay with some silt ss 24 -Grey silty sand
-
-ss -24 Grey silty sand, some clay, wet
15 --ss 24 Grey silty sand, some clay -
-
-ss 24 No recovery -
-
-ss
20 -
24 No recovery
SHEET
1 OF 1
J w~ >c W-"
J.
0::'...2~ w •• .... ~ 0
<( qi~ :s: .& ::, -·
-
-
-
-
-
-
-
-
-
---I-
I-
I-1' 7.91
I--
I--I-
I-
I-
I-
-
-
-
-
-
-
--
-
-
-
-
-
----I-
'"
FID
READINGS
(ppm)
THE STRATIFICATION LINE REPRESENTS THE APPROXIMATE BOUNDARY LINE BElWEEN SOIL TYPES IN-SITU. THE TRANSITION MAY BE GRADUAL
DATE INSTALLED I RIG TYPE I FOREMAN I DRILLING METHOD NOTES 0.11/16/09 GeoProbe MAD, Inc. Direct Push
CLIENT JOB# BORING# SHEET
New Hanover County Schools 22-12493E HA-13 1 OF 1 '"
~r-:u1(1ff\ PROJECT NAME ARCHITECT-ENGINEER
Castle Hayne School Campus Amy Conchas }~ '\:;),
1.c--~ [1.[1.!P
SITE LOCATION
Holly Shelter Road, Castle Hayne, New Hanover County, North Carolina C~!J';2.@ll..D ll\!I~~
w " J z w < c DESCRIPTION OF MATERIAL UJ~ FID I-~ > C a. "' W-" ~ >-READINGS g 0 0: J. w w w a::: .Q ~ (ppm) ,: J J > UJ •• >-a. a. 0 I-~ u a. " " -" <( Q.1 ~ w < ~,§, w ~~~ 0 "' 0: APPROXIMATE ELEVATION : •• FEET ABOVE MSL
-C-
-Black organic soil -1.7
-ss 24 C-
C-
---C-
-ss 24 C---C-5_ C-ss 24 -C-
---ss 24 ------· -ss 24 -10 ------ss 24 C-
C-
---ss 24 C----15 _ -ss 24 -------ss 24 ------C-
-ss 24 C-20 -
THE STRATIFICATION LINE REPRESENTS THE APPROXIMATE BOUNDARY LINE BETWEEN SOIL lYPES IN-SITU. THE TRANSITION MAY BE GRADUAL.
DATE INSTALLED l RIG TYPE j FOREMAN j DRILLING METHOD NOTES
01/06/2010 Hand Auaer Amv Conchas Hand Auaer
CLIENT JOB# BORING# SHEET
New Hanover County Schools 22-12493E HA-14 1 OF 1 '"
~ I
PROJECT NAME ARCHITECT-ENGINEER
Castle Hayne School Campus Amy Conchas '~ ', ' [!.r!a,[p
SITE LOCATION
Holly Shelter Road, Castle Hayne, New Hanover County, North Carolina CA~@l1.0IMA~
w '-' --' z
w ;o c' DESCRIPTION OF MATERIAL UJ ~ FID C >c 0. "' w.e ~ i5 >---' . READINGS € "' w w w ffi ·fa, (ppm) I J J > >-0. 0. 0 f-DU 0. :i " -'-' <( 'i,; ~ w ~ :§ w ,: • a Cl "' "' APPROXIMATE ELEVATION : •• FEET ABOVE MSL '-.
--
-Black organic silty soil -2,1
-ss 24 I-
I-
-I-
-I-
-ss 24 I-
I-
-I-5_ I-
-ss 24 I-
I-
- -I-
I-.
-ss 24 I-
I-
-I-
-I-
-ss 24 I-
10 I-
---I-
-ss 24 I-
I-
I-
-I-
-ss 24 I-
I-
I-
15 _ I-ss 24 -I-
I-
-I-
-I-
-ss 24 I-
I-
-I-
I-ss 24 I-20 I-
THE STRATIFICATION LINE REPRESENTS THE APPROXIMATE BOUNDARY LINE BElWEEN SOIL lYPES IN-SITU. THE TRANSITION MAY BE GRADUAL
L DATE INSTALLED l RIG lYPE l FOREMAN I DRILLING METHOD NOTES
01/06/2010 Hand Auaer Amv Conchas Hand Auaer
CLIENT JOB# BORING# SHEET
New Hanover County Schools 22-12493E HA-15 1 OF 1 '"
~I
PROJECT NAME ARCHITECT-ENGINEER
Castle Hayne School Campus Amy Conchas .
I [Lil.IP SITE LOCATION
Holly Shelter Road, Castle Hayne, New Hanover County, North Carolina (Cji\[l':((O)ll.U~j!:,.®
w " z --'
w >' C DESCRIPTION OF MATERIAL w~ FID a_ ~ > C
1:: "' >-w-" READINGS g i5 0: --' . w w w a: .Q ~ (ppm) I --' --' 6 w •• f-a_ a_ >-~ 0 a_ ::; ~c " ,c( 'ij~ w "' w ~~~ C, "' (/) = 0: APPROXIMATE ELEVATION: •• FEET ABOVE MSL
---Black organic soil -1.5 -ss 24 --
-
--
--ss 24 --
-
--5 --ss 24 ----1--
-1--ss 24 --1--
-1--
-1--
-ss 24 1--10 1--
-1--
-1--ss 24 ---
--
--ss 24 --
-
15 ----ss 24 --
-
--
-i-ss 24 -1--
1--
-1--
--ss 24 -1--20 1--
THE STRATIFICATION LINE REPRESENTS THE APPROXIMATE BOUNDARY LINE BElWEEN SOIL TYPES IN-SITU. THE TRANSITION MAY BE GRADUAL
DATE INSTALLED I RIG TYPE I FOREMAN I DRILLING METHOD NOTES
.01/06/2010 Hand Auqer Amv Conchas Hand Auaer
JOB# BORING# SHEET
CLIENT '"
New Hanover County Schools 22-12493E HA-16 1 OF 1
tJ~~. PROJECT NAME ARCHITECT-ENGINEER
Castle Hayne School Campus Amy Conchas '.. 11.fl.[p
SITE LOCATION
Holly Shelter Road, Castle Hayne, New Hanover County, North Carolina (C,;ji\lJ::l.<O)IJ..0 INJ,;ji\~
w Ll -' z
w '° 2 DESCRIPTION OF MATERIAL w~ FID a. ~ > C
~ "' >-w-" READINGS g 0 0: -' . w w w a:: _Q ,...._ (ppm) :I: -' -' > w •• I-a. a. 0 I-D 0 a. ~ ~c Ll <( ai ~ w w ?; .l!! ::J " "' Cl),.:;:. 0: APPROXIMATE ELEVATION : •• FEET ABOVE MSL -·
-f-Black organic soil 1.9 --ss 24 -f-
f-
---ss f-24 f--
-
5----ss 24 --
-
--
--ss 24 --
-
--
--ss 24 --10 -----ss 24 -f-
f-
-f-
-ss f-24 -t---f-15 _
t-ss 24 -f-
t-
---f-ss 24 -----
--ss 24
20 --
-
THE STRATIFICATION LINE REPRESENTS THE APPROXIMATE BOUNDARY LINE BETWEEN SOIL lYPES JN-SJTU. THE TRANSITION MAY BE GRADUAL
DATE INSTALLED I RIG lYPE I FOREMAN I DRILLING METHOD NOTES
01/06/2010 Hand Auqer Amv Conchas Hand Auqer
CLIENT JOB# BORING# SHEET
New Hanover County Schools 22-12493E HA-17 1 OF 1 ..
t~:~~~[p PROJECT NAME ARCHITECT-ENGINEER
Castle Hayne School Campus Amy Conchas
SITE LOCATION
Holly Shelter Road, Castle Hayne, New Hanover County, North Carolina <CA~~ILOIMA~
w u ~ z w
"' I DESCRIPTION OF MATERIAL Wu FID > C 0. "' W-" ~ >-READINGS g o 0: ~. w w w a::: .Q ....... (ppm) I ~ ~ 1) w •• >-0. 0. >-~ u 0. ~ ~c u <Qi~ w w ~~~ D "' (/) = 0: APPROXIMATE ELEVATION: •• FEET ABOVE MSL
'---Black organic soil 1.5 --ss 24 --
-
--
--ss 24 ----f-5 f--ss 24 -f-
f-
-f-
-f-
-ss 24 f-
f-
-f-
--ss 24 --10 -
--
--ss 24 --
-
----ss 24 ---
15 = -f-ss 24 -f-
f-
-f-
-f-ss 24 --f-
-f-
-ss 24 --f-20 f-
THE STRATIFICATION LINE REPRESENTS THE APPROXIMATE BOUNDARY LINE BETWEEN SOIL TYPES IN-SITU. THE TRANSITION MAY BE GRADUAL
DATE INSTALLED I RIG lYPE I FOREMAN I DRILLING METHOD NOTES
01/06/2010 Hand Auaer Amv Conchas Hand Auaer
CLIENT JOB# BORING# SHEET
New Hanover County Schools 22-12493E HA-18 1 OF 1 '"
~I
PROJECT NAME ARCHITECT-ENGINEER
Castle Hayne School Campus Amy Conchas .
. [L[l.tp
SITE LOCATION -Holly Shelter Road, Castle Hayne, New Hanover County, North Carolina CA~cO>IL.Oii"11A~
w " -' z w ;o c' DESCRIPTION OF MATERIAL w~ FID 0. ~ >• ~ "' >-w" READINGS € i5 "' -' . w w w 0::: _g ---(ppm) "' J J > w •• >-0. 0. 0 e-D u 0. " ~c " <( io ~ w " w s: J!! ::l 0 "' en-:: "' APPROXIMATE ELEVATION : •• FEET ABOVE MSL -·
--Black organic soil 2.0 -~ ss 24 -I-
~
-~
-I-ss 24 I--
~
5-I--I-ss 24 -I----
--ss 24 --
-
----ss 24 --10 -
----ss 24 -I-
~
-I-
-I-ss 24 I--
~
15 -~ -I-ss 24 -I-
-
--
--ss 24 ---
--
--ss 24 --20 -
THE STRATIFICATION llNE REPRESENTS THE APPROXIMATE BOUNDARY LINE BElWEEN SOIL TYPES IN-SITU. THE TRANSITION MAY BE GRADUAL.
DATE INSTALLED I RIG TYPE l FOREMAN I DRILLING METHOD NOTES
-.01/06/2010 Hand Auqer Amy Conchas Hand Auqer
CLIENT JOB# BORING# SHEET
New Hanover County Schools 22-12493E HA-19 1 OF 1 '"
r
PROJECT NAME ARCHITECT-ENGINEER ~~I Castle Hayne School Campus Amy Conchas
--~ 1 [l.[!..[p
SITE LOCATION
Holly Shelter Road, Castle Hayne, New Hanover County; North Carolina CA!Rl.<011..ll!MA~
w 0 J z
w ;, '2 DESCRIPTION OF MATERIAL w~ FID n. C > C "' w-" /: i5 >-J. READINGS §: "' w w w a:: .52 ---(ppm) :r J J > W..2:8 >--n. n. 0 ~ ai ~ n. " " -0 w ::; ;Ji;§ w ~.l!!:::, Q "' APPROXIMATE ELEVATION : •• FEET ABOVE MSL -·
-I-
-Black organic soil -0.7
ss 24 -
-
--
-ss 24 --I-
I-s_ I-ss 24 . I-
I-
-I-
-I-ss 24 I-
I-
-I-
-I-ss 24 -I-10 I-
-I-
-I-ss 24 I-
I-
-I-
-I-ss 24 I-
I-
-I-15 _ I-
ss 24 -I-
I-
-I-
-I-ss 24 . I-
I-
-I-
-I-ss 24
I-20 I-
THE STRATIFICATION LINE REPRESENTS THE APPROXIMATE BOUNDARY LINE BETWEEN SOJL TYPES IN-SITU. THE TRANSITION MAY BE GRADUAL.
I... DATE INSTALLED l RIG TYPE l FOREMAN I DRILLING METHOD NOTES
01/06/2010 Hand Auaer Amv Conchas Hand Auaer
CLIENT JOB# BORING# SHEET
New Hanover County Schools 22-12493E HA-20 1 OF 1 '"
~!
I
PROJECT NAME ARCHITECT-ENGINEER
Castle Hayne School Campus Amy Conchas ,_, '
1 r.!.ll.r.P SITE LOCATION
Holly Shelter Road, Castle Hayne, New Hanover County, North Carolina CA~(O)ILOIJl!JA~
w tJ z ~
w '° ~ DESCRIPTION OF MATERIAL w~ FID a. > C
/: "' >-w,, READINGS € o C: ~. w w w c::: .Q ...... (ppm) ;,: J J 6 w •• >-a. a. t-~" a. :! :, -tJ 4'. Q)~ w ;Jj §, w 3;:2 => 0 "' C: APPROXIMATE ELEVATION : •• FEET ABOVE MSL -·
--Black organic soil 0.7 --ss 24 ---
--
--ss 24 --
-
--5_ -ss 24 --
i-
-i-
-i-ss 24 -i-
i-
-i-
-i-ss 24
10 -i-
i-
-i-
-i-ss 24 -i-
t---
--
--ss 24 --
-
--15 --ss 24 --
-
--
--ss 24 ----i-
-t---ss 24
20 -t---
i-
THE STRATIFICATION LINE REPRESENTS THE APPROXIMATE BOUNDARY LINE BElWEEN SOIL TYPES IN-SITU. THE TRANSITION MAY BE GRADUAL.
DATE INSTALLED ! RIG TYPE I FOREMAN ! DRILLING METHOD NOTES
.01/06/2010 Hand Auaer Amv Conchas Hand Auger
CLIENT
New Hanover County Schools
PROJECT NAME
Castle Hayne School Campus
SITE LOCATION
JOB#
22-12493E
BORING#
ARCHITECT-ENGINEER
Amy Conchas
HA-21
Holly Shelter Road, Castle Hayne, New Hanover County, North Carolina
w
0 z w <{ '2 DESCRIPTION OF MATERIAL a. .... ~
~ "' >-
5 0 "' w w w
J: J J > .... a. a. 0 a. "' :,;_ 0 w <{ ~ :§, w D "' "' APPROXIMATE ELEVATION : •• FEET ABOVE MSL
-
-Black organic soil
ss 24 -
-
-ss 24 -
-5_
ss 24 -
-
-ss 24 -
-ss 24 -10
-
-ss 24 -
-
-ss 24 -
15 _
ss 24 -
-
-ss 24 -
-
. ss 24
20
SHEET
1 OF 1
-
-
-
---
~
~
~
~
'-
~
'-
~
~
'-
'-
~
~
'-
~
~
~
~
'-
~
~
~
'-
~
'-
~
~
~
~
~
~
'-
~
~
J w~ > C W3
J. a:: .Q ~ w •• f--Du
<{ Q) ~ 3: ~ iii
FID
READINGS
(ppm)
0.7
THE STRATIFICATION LINE REPRESENTS THE APPROXIMATE BOUNDARY LINE BETWEEN SOIL TYPES IN-SITU. THE TRANSITION MAY BE GRADUAL.
L DATE INSTALLED I RIG TYPE I FOREMAN I DRILLING METHOD NOTES
01/06/2010 Hand Auaer Amv Conchas Hand Auner
CLIENT
New Hanover County Schools
PROJECT NAME
Castle Hayne School Campus
SITE LOCATION
JOB#
22-12493E
BORING#
HA-22
ARCHITECT-ENGINEER
Amy Conchas
Holly Shelter Road, Castle Hayne, New Hanover County, North Carolina
w <.) z
w " '2 DESCRIPTION OF MATERIAL a. C
~ "' >-g □ a: w w w
I .J .J > >-a. a. 0 a. " " -<.) w <( ;'}j;§ w D "' a: APPROXIMATE ELEVATION : •• FEET ABOVE MSL
-
-Black organic soil ss 24 -
-
-ss 24 -
-5_
ss 24 -
-ss 24 -
-
-ss 24 -
10
-
.. ss 24 -
-
-ss 24 -
-15 _
ss 24
..
ss 24 -
-
-ss 24 -20
SHEET
1 OF 1
~
~
~
~
~
~
~
~
~
~
~
~ .._
~
~
~ .._
~ .._ .._
~ .._
~
~
~
~
~
~ .._
~ .._
~ .._ .._
~ .._ .._
~
~
~
.J Wu > C
UJ " .J •
e::: .Q ---UJ •• >-~ u
<( Q) ~ ~~ :J -·
FID
READINGS
(ppm)
1.5
THE STRATIFICATION LINE REPRESENTS THE APPROXIMATE BOUNDARY LINE BElWEEN SOIL TYPES IN-SITU. THE TRANSITION MAY BE GRADUAL.
L DATE INSTALLED I RIG TYPE I FOREMAN I DRILLING METHOD NOTES
.01/06/2010 Hand Auaer Amv Conchas Hand Auaer
CLIENT JOB# BORING# SHEET
New Hanover County Schools 22-12493E HA-23 1 OF 1 '" '.ibss~~ PROJECT NAME ARCHITECT-ENGINEER 1 ' rri' Castle Hayne School Campus Amy Conchas J._ ! ' . '
) t!a,[b[p
SITE LOCATION
Holly Shelter Road, Castle Hayne, New Hanover County, North Carolina <C~!Fl.<O>IL.llli\!l~~
w u z J
w ;, c DESCRIPTION OF MATERIAL w~ FID 0. C > C
i'c "' >-wE READINGS g ci "' J. w w w O::'. .Q --(ppm) r J J > w •• f-0. 0. 0 f-DU 0. " " -u <( ai ~ w <{ :}j §. w ~2 :l " "' "' APPROXIMATE ELEVATION : •• FEET ABOVE MSL -.
--Black organic soil -0.8
ss 24 --
-
~ -
--
-ss 24 ~
~
-~ 5_ ~
ss 24 -~
~
-I-
-~ ss 24 -~
I-
-~
I-
-ss 24 I-10 ~
I-
-I-ss 24 --
I-
-I-
-~
-ss 24 I-
I-
-~ 15 _
~
-ss 24 I-
I-
-I-
ss 24 I-
-I-
I-
I-
-I-
-ss 24 I-20
~
THE STRATIFICATION LINE REPRESENTS THE APPROXIMATE BOUNDARY LINE BETWEEN SOIL TYPES IN-SITU. THE TRANSITION MAY BE GRADUAL
DATE INSTALLED l RIG TYPE I FOREMAN l DRILLING METHOD NOTES
01/06/2010 Hand Au□er Amv Conchas Hand Au□ er
CLIENT JOB# BORING# SHEET
New Hanover County Schools 22-12493E HA-24 1 OF 1 '"
~l'ni1~ PROJECT NAME ARCHITECT-ENGINEER ! l.i, ' t
Castle Hayne School Campus Amy Conchas Lli ~Al i 11.11.lP SITE LOCATION
Holly Shelter Road, Castle Hayne, New Hanover County, North Carolina <CA!f;l.(0)11..U!Mffi'i..~
w <.} J z
w ;,: '2 DESCRIPTION OF MATERIAL w~ FID "-C > C
~ "' >-W-" READINGS g i5 "' J.
w w w a::: _Q ~ (ppm) :c J J > w •• >--"-"-0 f-~ u "-" ~c <.} <( w ~ w "" w s: ~ ~ 0 "' (/)C. "' APPROXIMATE ELEVATION: •• FEET ABOVE MSL
--Black organic soil 14.5 --ss 24 --
I-
-~
-ss I--24 I-
~
5-I--I-ss 24 -I-
I-
-~
--ss 24 --
-
--
--ss 24 --10 -
--
--ss 24 --
I -
----ss 24 -I-
~
-~ 15 _
I-ss 24 -~
~
-~
-~ ss 24 -I-
~
-~
-, ss 24 I-.
20 -I-
-
THE STRATIFICATION LINE REPRESENTS THE APPROXIMATE BOUNDARY LINE BElWEEN SOIL TYPES IN-SITU. THE TRANSITION MAY BE GRADUAL.
DATE INSTALLED ! RIGTYPE I FOREMAN I DRILLING METHOD NOTES
01/06/2010 Hand AuQer Amy Conchas Hand AuQer
CLIENT JOB# BORING# SHEET
New Hanover County Schools 22-12493E HA-25 1 OF 1 '"
,ic ""'~ PROJECT NAME ARCHITECT-ENGINEER
"
Castle Hayne School Campus Amy Con'chas ' [!.[!.[p SITE LOCATION
Holly Shelter Road, Castle Hayne, New Hanover County, North Carolina Cdi\~<tl>II..Dll\!ldi\®
w Ll --' z w ;o '2 DESCRIPTION OF MATERIAL UJ ~ FID a_ ~ > C
i':: "' >-UJ .!!! READINGS g i5 0: --' . w w w ffi~G> (ppm) :,: --' --' > I-a_ a_ 0 ,_~o a_ :,; :,; -Ll <( ai ~ w ;f; ~,§, w s: • 0 C, 0: APPROXIMATE ELEVATION : •• FEET ABOVE MSL "' .
-~
-Black organic soil -0.2 ss 24 --
-
--
--ss 24 ---
I-s_ ~ ss 24 I-
~
-I-
ss 24 I-
-~
~
-I-
-~
-ss 24 ~ 10 ~
-~
-~ ss 24 -~
~
-I-
ss 24 I-
I-
~
-I-15 _ I-ss 24 -~
~
-~
-~ ss 24 -~
~
-~
-~ ss 24 -~ 20 I-
THE STRATIFICATION LINE REPRESENTS THE APPROXIMATE BOUNDARY LINE BElWEEN SOIL TYPES IN-SITU. THE TRANSITION MAY BE GRADUAL
l... DATE INSTALLED I RIG TYPE I FOREMAN I DRILLING METHOD NOTES
01/06/2010 Hand Auaer Amv Conchas Hand Auaer
CLIENT JOB# BORING# SHEET
New Hanover County Schools 22-12493E HA-26 1 OF 1 '"
'
PROJECT NAME ARCHITECT-ENGINEER l~L.~! Castle Hayne School Campus Amy Conchas ' ,
[!.[!.!? SITE LOCATION
Holly Shelter Road, Castle Hayne, New Hanover County, North Carolina e~ll':l.<0>11..a 11\!1~~
w
() z J
w .,: '2 DESCRIPTION OF MATERIAL w~ FID "-= >" ~ "' >-w-" READINGS € 15 a: J. w w w a::: _g .-. (ppm) I J J > w •• >-"-"-0 >-n o "-" " -() <( ai ~ w < ~;§, w s: -21 ::, 0 "' a: APPROXIMATE ELEVATION : •• FEET ABOVE MSL -·
-~
-Black organic soil ~ 1,4
ss 24 -~
-
--
--ss 24 --
-
--s_ -ss 24 -~
~
-"-
~ ss 24 -~
"-
---"-
-~
-ss 24 ~ 10 "-
-~
-"-ss 24 -~
~
~
-~ ss 24 -~
~
~ 15 _
~
-ss 24 "-
~
-~
-~ ss 24 -~
~
-~
-~ ss 24 -~ 20
~
THE STRATIFICATION LINE REPRESENTS THE APPROXIMATE BOUNDARY LINE BElWEEN SOIL TYPES IN-SITU. THE TRANSITION MAY BE GRADUAL.
DATE INSTALLED I RIG TYPE I FOREMAN I DRILLING METHOD NOTES
01/06/2010 Hand Auoer Amv Conchas Hand Auner
CLIENT JOB# BORING# SHEET
New Hanover County Schools 22-12493E HA-27 1 OF 1 '"
'IJ:i /U~ PROJECT NAME ARCHITECT-ENGINEER i-r:• ((\\
Castle Hayne School Campus Amy Conchas !":-31~ '\':\1
SITE LOCATION
..... r r!..11.IP
Holly Shelter Road, Castle Hayne, New Hanover County, North Carolina <Cffe.l.~©Jll..mi'<!lffe.l.®
w u z _,
w ;, c DESCRIPTION OF MATERIAL w~ FID 0. = >" /: "' >-w-" READINGS g 0 "' _, .
w w w a:: s ---(ppm) I J J > w~~ >--0. 0. 0 0. " " -u '~ai~ w <( ~Ji w ~2::, 0 "' "' APPROXIMATE ELEVATION : •• FEET ABOVE MSL -·
--
-Black organic soil -0.8
ss 24 --
-
--
-~ ss 24 '-
'-
-'-s_ '-ss 24 -'-
'-
-'-
-'-
-ss 24 '-
'-
-'-
-'-ss 24 -~ 10 '-
-~
-~ ss 24 -'-
'-
-'-
-'-ss 24 '-
'-
-'-15 _ '-ss 24 -'-
'--'-
-'-ss 24 -'-
~
~
-'-
-ss 24 '-20 '-
THE STRATIFICATION LINE REPRESENTS THE APPROXIMATE BOUNDARY LINE BE1WEEN SOIL TYPES IN-SITU. THE TRANSITION MAY BE GRADUAL.
DATE INSTALLED 7-RIGTYPE I FOREMAN I DRILLING METHOD NOTES C 01/06/2010 Hand Auaer Amv Conchas Hand Auaer
CLIENT JOB# BORING# SHEET
New Hanover County Schools 22-12493E B-1 1 OF 1 ,. ..
~ I
PROJECT NAME ARCHITECT-ENGINEER
Castle Hayne School Campus Amy Conchas
SITE LOCATION [!,.t!_.[F>
Holly Shelter Road, Castle Hayne, New Hanover County, North Carolina C,:;,\~<0>11..0 ll\!l,:;,\$il
w <.) _, z
w <( "2 DESCRIPTION OF MATERIAL w~ FID 0. ... ~ > C
1:: "' >-w-" READINGS g iS 0: _, .
w w w a:: .Q ---(ppm) I ~ ~ > w •• ... 0. 0. 0 ... ~ 0 0. " " -<.) <( ai ~ w <( ~ c§ w ~.l!! :::J 0 "' 0: APPROXIMATE ELEVATION : •• FEET ABOVE MSL -·
--Black organic soil -0.6
ss 24 --
-
--
--ss 24 --
'-
-~ s_ '-ss 24 -~
'--~
-~
-ss 24 '-
~
-~
-~ ss 24 -~ 10 ~
-'-
ss 24 ~
-~
'-
-~
-~
-ss 24 '-
~
-~ 15 _ ~
ss 24 -~
~
~
-~ ss 24 -'-
'-
-~
-~
-ss 24 '-20 ~
THE STRATIFICATION LINE REPRESENTS THE APPROXIMATE BOUNDARY LINE BETWEEN SOIL TYPES IN-SITU. THE TRANSITION MAY BE GRADUAL.
DATE INSTALLED l RIG TYPE l FOREMAN l DRILLING METHOD NOTES
_01/06/2010 Hand Auaer Amv Conchas Hand Auaer
CLIENT JOB# BORING#
New Hanover County Schools
PROJECT NAME
Castle Hayne School Campus
SITE LOCATION
22-12493E
ARCHITECT-ENGINEER
Amy Conchas
B-2
Holly Shelter Road, Castle Hayne, New Hanover County, North Carolina
w u z
w ;, "2 DESCRIPTION OF MATERIAL "-= ~ V) >-g i5 0: w w w :,; --' --' i, ,_ "-"-"-"' "' -u w "' ~;§ w □ V) 0: APPROXIMATE ELEVATION:•• FEET ABOVE MSL
-
-Mucky soil, edge of wetland ss 24 -
-
ss 24 -
-s_
ss 24 -
-
. ss 24 -
-
-ss 24 -10
--ss 24
-
-ss 24 -
15 _
ss 24 -
-
-ss 24 -
-
ss 24 -20
SHEET
1 OF 1
~
~ ._ ._
~ ._ ._ ._
._ ._
-
'-
'-
f-
f-
'-
'-
~
~
~
~
~ ._ ._
'-._ ._
f-
f-._
'-
~
~
'-._
~
~ ._
f-
'-
--' w~ > C w-" --' .
0::: ..Q --w •• ,_ ~ 0
<( w ~
;: • a ~-
FID
READINGS
(ppm)
0.3
THE STRATIFICATION LINE REPRESENTS THE APPROXIMATE BOUNDARY LINE BETWEEN SOIL TYPES IN-SITU. THE TRANSITION MAY BE GRADUAL
DATE INSTALLED l RIG TYPE l FOREMAN I DRILLING METHOD NOTES
01/06/2010 Hand Auaer Amv Conchas Hand Auoer
CLIENT JOB# BORING# SHEET
'New Hanover County Schools 22-12493E B-3 1 OF 1 ,.
~~I PROJECT NAME ARCHITECT-ENGINEER Ir\: i'R . '
Castle Hayne School Campus Amy Conchas \~ '. ~ . . 1 [!_[!_[?
SITE LOCATION
Holly Shelter Road, Castle Hayne, New Hanover County, North Carolina C~~(O)ll..UINI~~
w " z J
w ;! I DESCRIPTION OF MATERIAL Wu FID >c a. "' w" ~ 0 >-J. READINGS € "' w w w ffi ~ Q) (ppm) le J J > a. a. 0 t-D 0 a. " ~ '2 " <( iii{! w "' w $. 0 0 "' (/)V "' APPROXIMATE ELEVATION : •• FEET ABOVE MSL '=-•
--Black organic soil I-13.0
ss 24 -I-
, I-
-I-
-I-ss 24 I-
I-
-I-
5_ I-
ss 24 -I-
I-
-I-
-I-
-ss 24 I-
I-
-I-
-I-ss 24 --10 I-
-I-
-I-ss 24 I-
I-
-I-
-I-
-ss 24 I-
I-
-I-15 _ I-ss 24 -I-
I-
I-
ss 24 I-
-I-
I-
I-
-I-ss 24 I-20 I-
THE STRATIFICATION LINE REPRESENTS THE APPROXIMATE BOUNDARY LINE BETWEEN SOIL TYPES IN-SITU. THE TRANSITION MAY BE GRADUAL
DATE INSTALLED l RIGTYPE I FOREMAN l DRILLING METHOD NOTES
01/06/2010 Hand Auaer Amv Conchas Hand Auaer
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Paco Analytical Sorvicos, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
December 08, 2009
Ms. Amy Conchas
ECS
7211 Ogden Business Park
Suite 201
Wilmington, NC 28411
RE: Project: CASTLE HAYNE 22-124930
Pace Project No.: 9257759
Dear Ms. Conchas:
Enclosed are the analytical results for sample{s) received by the laboratory on November 18, 2009.
The results relate only to the samples included in this report. Results reported herein conform to the
most current NELAC standards, where applicable, unless otherwise narrated in the body of the
report.
Inorganic Wet Chemistry and Metals analyses were performed at our Pace Asheville laboratory and
Organic testing was performed at our Pace Huntersville laboratory unless otherwise footnoted. All
Microbiological analyses were performed at the laboratory where the samples were received.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
0sUc~/1zf~I
Ashley Nifong
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
~Q,.'.':'-'':;,9~ 11Be~c;;
Page 1 of 32
Project: CASTLE HAYNE 22-12493D
Pace Project No.: 9257759
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Charlotte Certification IDs
9800 Kincey Ave. -Ste 100 Huntersville, NC 28078
Connecticut Certification#: PH-0104
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2225 Riverside Dr.
CERTIFICATIONS
Asheville, NC 28804
[phone]
Michigan Certification#: 9911
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REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in fun,
without the written consent of Pace Analytical Services, Inc ..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704 )875-9092
Page 2 of 32
Project: CASTLE HAYNE 22-124930
Pace Project No.: 9257759
Lab ID Sample ID
9257759001 TMW-1W
9257759002 TMW-2W
9257759003 TMW-3W
9257759004 TMW-4W
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
SAMPLE ANALYTE COUNT
Method
EPA6010
EPA 8270
EPA 8260
EPA6010
EPA8270
EPA 8260
EPA 6010
EPA8270
EPA 8260
EPA6010
EPA 8270
EPA8260
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
Analysts
JMW
EAO
MCK
JMW
EAO
MCK
JMW
EAO
MCK
JMW
EAO
MCK
Paco Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704 }875-9092
Analytes
Reported Laboratory
11 PASI-A
71 PASl-O
63 PASI-C
11 PASI-A
71 PASl-O
63 PASI-C
11 PASI-A
71 PASl-O
63 PASI-C
11 PASI-A
71 PASl-O
63 PASI-C
Page 3 of 32
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
{828)254-7176
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704}875-9092
Project: CASTLE HAYNE 22-12493D
Pace Project No.: 9257759
Sample: TMW-1W
Parameters
6010 MET ICP
Aluminum
Antimony
Arsenic
Beryllium
Chromium
Copper
Iron
Lead
Nickel
Thallium
Zinc
8270 MSSV Semivolatile Organic
1,2,4-Trichlorobenzene
1,2-Dichlorobenzene
1,2-Diphenylhydrazine
1,3-Dichlorobenzene
1,4-Dichlorobenzene
1-Methylnaphthalene
2,4,5-Trichlorophenol
2,4,6-Trichtorophenol
2,4-Dichlorophenol
2.4-Dimethylphenol
2.4-Dinitrophenol
2,4-Dinitrotoluene
2,6-Dinitrotoluene
2-Chloronaphthalene
2-Chlorophenol
2-Methylnaphthalene
2-Methylphenol(o-Cresol)
2-Nitroaniline
2-Nitrophenol
3&4-Methylphenol(m&p Cresci)
3,3'-Dichlorobenzidine
3-Nitroaniline
4,6-Dinitro-2-methylphenol
4-Bromophenylphenyl ether
4-Chloro-3-methylphenol
4-Chloroaniline
4-Chlorophenylphenyl ether
4-Nitroaniline
4-Nitrophenol
Acenaphthene
Acenaphthy!ene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Date: 12/08/2009 04:23 PM
LablD: 9257759001 Collected: 11/17/09 11:00 Received; 11/18/09 09:30 Matrix: Water
Results Units Report Limit DF Prepared Analyzed CAS No.
Analytical Method: EPA 6010 Preparation Method: EPA 3010
18000 ug/L
ND ug/L
9.7 ug/L
4.0 ug/L
7.8 ug/L
ND ug/L
65200 ug/L
ND ug/L
43.0 ug/L
ND ug/L
68.7 ug/L
Analytical Method: EPA 8270
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
100
5.0
5.0
1.0
5.0
5.0
50.0
5.0
5.0
10.0
10.0
5.1
5.1
5.1
5.1
5.1
5.1
4.1
2.1
2.1
5.1
20.6
2.1
2.1
5.1
5.1
5.1
5.1
5.1
5.1
10.3
10.3
5.1
20.6
5.1
20.6
5.1
5.1
4.1
20.6
5.1
5.1
5.1
5.1
1.0
11/19/09 14:20 11/20/0919:08 7429-90-5
11/19/09 14:20 11/20/09 19:08 7440-36-0
11/19/09 14:20 11/20/09 19:08 7440-38-2
11/19/09 14:20 11/20/09 19:08 7440-41-7
11/19/0914:20 11/20/09 19:08 7440-47-3
11/19/09 14:20 11/20/0919:08 7440-50-8
11/19/09 14:20 11/20/09 19:08 7439-89-6
11/19/09 14:20 11/20/09 19:08 7439-92-1
11/19/09 14:20 11/20/09 19:08 7440-02-0
11/19/09 14:20 11/20/09 19:08 7440-28-0
11/19/09 14:20 11/20/0919:08 7440-66-6
11/20/09 15:23 12/02/09 00:34 120-82-1
11/20/09 15:23 12/02/09 00:34 95-50-1
11/20/09 15:23 12/02/09 00:34 122-66-7
11/20/09 15:23 12/02/09 00:34 541-73-1
11/20/09 15:23 12/02/09 00:34 106-46-7
11/20/09 15:23 12/02/09 00:34 90-12-0
11/20/0915:23 12/02/09 00:34 95-95-4
11/20/09 15:23 12/02/09 00:34 88-06-2
11/20/09 15:23 12/02/09 00:34 120-83-2
11/20/09 15:23 12/02/09 00:34 105-67-9
11/20/09 15:23 12/02/09 00:34 51-28-5
11/20/09 15:23 12/02/09 00:34 121-14-2
11/20/0915:23 12/02/09 00:34 606-20-2
11/20/09 15:23 12/02/09 00:34 91-58-7
11/20/09 15:23 12/02/09 00:34 95-57-8
11/20/09 15:23 12/02/09 00;34 91-57-6
11/20/09 15:23 12/02/09 00:34 95-48-7
11/20/09 15:23 12/02/09 00:34 88-74-4
11/20/09 15:23 12/02/09 00:34 88-75-5
11/20/09 15:23 12/02/09 00:34
11/20/0915:23 12/02/09 00:34 91-94-1
11/20/09 15:23 12/02/09 00:34 99-09-2
11/20/09 15:23 12/02/09 00:34 534-52-1
11/20/09 15:23 12/02/09 00:34 101-55-3
11/20/09 15:23 12/02/09 00:34 59-50-7
11/20/09 15:23 12/02/09 00:34 106-47-8
11/20/09 15:23 12/02/09 00:34 7005-72-3
11/20/09 15:23 12/02/09 00:34 100-01-6
11/20/09 15:23 12/02/09 00:34 100-02-7
11/20/09 15:23 12/02/09 00:34 83-32-9
11/20/09 15:23 12/02/09 00:34 208-96-8
11/20/09 15:23 12/02/09 00:34 120-12-7
11/20/09 15:23 12/02/09 00:34 56-55-3
11/20/09 15:23 12/02/09 00:34 50-32-8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
.. -:,'f i"",._
11□eklC,,
Qual
Page 4 of 32
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville. NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: CASTLE HAYNE 22-12493D
Pace Project No.: 9257759
Parameters ,
8270 MSSV Semivolatile Organic
Benzo(b)fluoranthene
Benzo(g, h, i)perylene
Benzo(k)fluoranthene
Butylbenzylphthalate
Chrysene
Di-n-butylphthalate
Di-n-octylphthalate
D ibenz( a, h )a nth racene
Dibenzofuran
Diethylphthalate
Dimethylphthalate
Fluoranthene
Fluorene
Hexachloro-1,3-butadiene
Hexachlorobenzene
Hexachlorocyclopentadiene
Hexachloroethane
lndeno( 1,2,3-cd)pyrene
lsophorone
N-Nitroso-di-n-propylamine
N-Nitrosodimethylamine
N-Nitrosodiphenylamine
Naphthalene
Nitrobenzene
Pentachlorophenol
Phenanthrene
Phenol
Pyrene
bis(2-Chloroethy1) ether
bis(2-Chloroisopropyl) ether
bis(2-Ethylhexy1)phthalate
Nitrobenzene-d5 (S)
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
Phenol-dB (S)
2-Fluorophenol (S)
2.4,6-Tribromophenol {S)
8260 MSV Low Level
Acetone
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Date: 12/08/2009 04:23 PM
LablD: 9257759001 Collected: 11/17/09 11:00 Received: 11/18/09 09:30 Matrix: Water
Results Units ------
Analytical Method: EPA 8270
ND ug/L
ND ug/L
ND u9/L
ND ug/L
ND ug/L
ND ug/L
ND u9/L
ND ug/L
ND ug/L
ND ug/L
ND u9/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND u9/L
52 %
62 %
79 %
21 %
32 %
63 %
Analytical Method: EPA 8260
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
Report Limit
2.1
5.1
4.1
5.1
5.1
5.1
5.1
2.1
5.1
5.1
5.1
5.1
5.1
2.1
1.0
5.1
5.1
2.1
5.1
4.1
2.1
5.1
5.1
4.1
20.6
5.1
5.1
5.1
4.1
5.1
5.1
10-110
18-110
10-123
10-110
18-110
10-110
25.0
1.0
1.0
1.0
1.0
1.0
5.0
5.0
OF Prepared Analyzed CAS No.
11120109 15:23 12102109 00:34 205-99-2
11120109 15:23 12102109 00:34 191-24-2
11120109 15:23 12102109 00:34 207-08-9
11120109 15:23 12102109 00:34 85-68-7
11120109 15:23 12102109 00:34 218-01-9
1112010915:23 12102109 00:34 84-74-2
11120109 15:23 12102109 00:34 117-84-0
11120109 15:23 12102109 00:34 53-70-3
11120109 15:23 12102109 00:34 132-64-9
11120109 15:23 12102109 00:34 84-66-2
11120109 15:23 12102109 00:34 131-11-3
11120/0915:23 12102109 00:34 206-44-0
11120109 15:23 12102109 00:34 86-73-7
11120109 15:23 12/02109 00:34 87-68-3
11120109 15:23 12102109 00:34 118-74-1
1112010915:23 12102109 00:34 77-47-4
11120109 15:23 12102109 00:34 67-72-1
11120109 15:23 12102109 00:34 193-39-5
11120109 15:23 12102109 00:34 78-59-1
11120109 15:23 12102109 00:34 621-64-7
1112010915:23 12102109 00:34 62-75-9
11/20/09 15:23 12/02/09 00:34 86-30-6
11/20/09 15:23 12/02/09 00:34 91-20-3
11120109 15:23 12102109 00:34 98-95-3
11120109 15:23 12/02109 00:34 87-86-5
11120109 15:23 12102109 00:34 85-01-8
11/20109 15:23 12102109 00:34 108-95-2
1112010915:23 12102109 00:34 129-00-0
11/20/09 15:23 12/02/09 00:34 111-44-4
11120109 15:23 12102109 00:34 108-60-1
11/20/09 15:23 12/02/09 00:34 117-81-7
11120109 15:23 12102109 00:34 4165-60-0
11/20/09 15:23 12/02/09 00:34 321-60-8
11/20/09 15:23 12/02/09 00:34 1718-51-0
11120109 15:23 12102109 00:34 13127-88-3
11120109 15:23 12102109 00:34 367-12-4
11120109 15:23 12102109 00:34 118-79-6
11/27/09 02:23 67-64-1
11127/09 02:23 71-43-2
11127109 02:23 108-86-1
11/27/09 02:23 74-97-5
11/27/09 02:23 75-27-4
11/27/09 02:23 75-25-2
11127109 02:23 74-83-9
11127109 02:23 78-93-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
.?1/~-~~'"~ 11nelao'\
Qual
Page 5 of 32
Pace Analytical Services, Inc.
2225 Riverside Dr.
' ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704 )875-9092
Project: CASTLE HAYNE 22-124930
Pace Project No.: 9257759
Sample: TPJIW-1W LablD: 9257759001 Collected: 11/17/09 11:00 Received: 11/18/09 09:30 Matrix: Water
Parameters Results Units Report Limit OF Prepared Analyzed GAS No. Qual
8260 MSV Low Level Analytical Method: EPA 8260
Carbon tetrachloride NO ug/L 1.0 11/27/09 02:23 56-23-5
Chlorobenzene ND ug/L 1.0 11/27/09 02:23 108-90-7
Chloroethane NO ug/L 1.0 11/27/09 02:23 75-00-3
Chloroform ND ug/L 1.0 11 /27 /09 02:23 67-66-3
Chloromethane ND ug/L 1.0 11127/09 02:23 74-87-3
2-Chlorotoluene ND ug/L 1.0 11/27/09 02:23 95-49-8
4-Chlorotoluene ND ug/L 1.0 11 /27 /09 02:23 106-43-4
1,2-0ibromo-3-chloropropane ND ug/L 3.0 11/27/09 02:23 96-12-8
Dibromochloromethane ND ug/L 1.0 11/27/09 02:23 124-48-1
1,2-0ibromoethane (EOB) ND ug/L 1.0 11/27/09 02:23 106-93-4
Dibromomethane ND ug/L 1.0 11/27/09 02:23 74-95-3
1,2-Dichlorobenzene ND ug/L 1.0 11/27/09 02:23 95-50-1
1,3-0ichlorobenzene ND ug/L 1.0 11/27/09 02:23 541-73-1
1.4-Dichlorobenzene NO ug/L 1.0 11/27/09 02:23 106-46-7
Dichlorodifluoromethane ND ug/L 1.0 11/27/09 02:23 75-71-8
1, 1-Dichloroethane ND ug/L 1.0 11/27/09 02:23 75-34-3
1,2-Dichloroethane ND ug/L 1.0 11/27/09 02:23 107-06-2
1, 1-Dichloroethene ND ug/L 1.0 11 /27 /09 02:23 75-35-4
cis-1,2-Dichloroethene ND ug/L 1.0 11/27/09 02:23 156-59-2
trans-1,2-0ichloroethene NO ug/L 1.0 11/27/09 02:23 156-60-5
1,2-Dichloropropane ND ug/L 1.0 11/27/09 02:23 78-87-5
1,3-Dichtoropropane NO ug/L 1.0 11/27/09 02:23 142-28-9
2,2-Dichloropropane ND ug/L 1.0 11127 /09 02:23 594-20-7
1, 1-Dichloropropene ND ug/L 1.0 11127 /09 02:23 563-58-6
cis-1,3-DichloroPropene ND ug/L 1.0 11/27/09 02:23 10061-01-5
trans-1,3-0ichloropropene ND ug/L 1.0 11/27/09 02:23 10061-02-6
Diisopropyl ether ND ug/L 1.0 11/27/09 02:23 108-20-3
Ethylbenzene ND ug/L 1.0 11 /27 /09 02:23 100-41-4
Hexach!oro-1,3-butadiene ND ug/L 1.0 11/27/09 02:23 87-68-3
2-Hexanone ND ug/L 5.0 11/27/09 02:23 591-78-6
p-lsopropy1toluene NO ug/L 1.0 11/27/09 02:23 99-87-6
Methylene Chloride ND ug/L 2.0 11 /27109 02:23 75-09-2
4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 11/27/09 02:23 108-10-1
Methyl-tert-butyl ether ND ug/L 1.0 11/27/09 02:23 1634-04-4
Naphthalene ND ug/L 1.0 11 /27 /09 02:23 91-20-3
Styrene ND ug/L 1.0 11 /27 /09 02;23 100-42-5
1, 1, 1,2-Tetrachloroethane ND ug/L 1.0 11/27/09 02:23 630-20-6
1, 1,2,2-Tetrachloroethane ND ug/L 1.0 11/27/09 02:23 79-34-5
Tetrachloroethene ND ug/L 1.0 11/27/09 02:23 127-18-4
Toluene ND ug/L 1.0 11/27/09 02:23 108-88-3
1,2,3-Trichlorobenzene NO ug/L 1.0 11 /27 /09 02:23 87-61-6
1,2,4-Trichlorobenzene ND ug/L 1.0 11 /27 /09 02:23 120-82-1
1, 1, 1-Trichloroethane ND ug/L 1.0 11/27/09 02:23 71-55-6
1, 1,2-Trichloroethane NO ug/L 1.0 11/27/09 02:23 79-00-5
Trichloroethene ND ug/L 1.0 11/27/09 02:23 79-01-6
Trichlorofluoromethane ND ug/L 1.0 11 /27 /09 02:23 75-69-4
1,2,3-T richloropropane ND ug/L 1.0 11 /27109 02:23 96-18-4
Date: 12/08/2009 04:23 PM REPORT OF LABORATORY ANALYSIS Page 6 of 32
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
-·«ir·· 11ne e:;
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704 )875-9092
Project: CASTLE HAYNE 22-124930
Pace Project No.: 9257759
Sample: TMW-1W
Parameters
8260 MSV Low Level
Vinyl acetate
Vinyl chloride
m&p-Xylene
a-Xylene
4-Bromofluorobenzene (S)
Dibromofluoromethane (S)
1,2-Dichloroethane-c:14 (S)
Toluene-dB (S)
Date: 12/08/2009 04:23 PM
LablD: 9257759001 Collected: 11/17/0911:00 Received: 11/18/09 09:30 Matrix: Water
Results Units Report Limit DF Prepared
Analytical Method: EPA 8260
ND ug/L 2.0
ND ug/L 1.0
ND ug/L 2.0
ND ug/L 1.0
96 % 87-109
100 % 85-115
97 % 79-120
100 % 70-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
Analyzed CAS No.
11/27/09 02:23 108-05-4
11/27/09 02:23 75-01-4
11/27 /09 02:23 1330-20-7
11/27/09 02:23 95-47-6
11/27/09 02:23 460-00-4
11/27/09 02:23 1868-53-7
11/27/09 02:23 17060-07-0
11/27/09 02:23 2037-26-5
Qual
Page 7 of 32
Paco Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: CASTLE HAYNE 22-12493D
Pace Project No.: 9257759
Sample: TMW-2W
Parameters
6010 MET ICP
Aluminum
Antimony
Arsenic
Beryllium
Chromium
Copper
Iron
Lead
Nickel
Thallium
Zinc
8270 MSSV Semivolatile Organic
1,2,4-Trichlorobenzene
1,2-Dichlorobenzene
1,2-Diphenylhydrazine
1,3-Dichlorobenzene
1,4-Dichlorobenzene
1-Methylnaphthalene
2,4,5-Trichlorophenol
2, 4, 6-T rich lorophenol
2,4-Dichlorophenol
2,4-Dimethylphenol
2,4-Dinitrophenol
2,4-Dinitrotoluene
2,6-Dinitrotoluene
2-Chloronaphthalene
2-Chlorophenot
2-Methylnaphthalene
2-Methylphenol(o-Cresol)
2-Nitroaniline
2-Nitrophenol
3&4-Methy1phenot(m&p Cresol)
3,3'-Dichlorobenzidine
3-Nitroaniline
4,6-Dinitro-2-methylphenol
4-Bromophenylphenyl ether
4-Chloro-3-methylphenol
4-Chloroaniline
4-Chlorophenylphenyl ether
4-Nitroaniline
4-Nitrophenol
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Date: 12/08/2009 04:23 PM
LablD: 9257759002 Collected: 11/17/0914:15 Received: 11/18/09 09:30 Matrix: Water
Results Units Report Limit DF Prepared Analyzed CAS No.
Analytical Method: EPA6010 Preparation Method: EPA3010
3060 ug/L
ND ug/L
ND ug/L
ND ug/L
6.7 ug/L
ND u9/L
6480 ug/L
ND ug/L
5.3 ug/L
ND ug/L
ND ug/L
Analytical Method: EPA 8270
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug!L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug!L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
NO ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
100
5.0
5.0
1.0
5.0
5.0
50.0
5.0
5.0
10.0
10.0
5.2
5.2
5.2
5.2
5.2.
5.2
4.2
2.1
2.1
5.2
20.8
2.1
2.1
5.2
5.2
5.2
5.2
5.2
5.2
10.4
10.4
5.2
20.8
5.2
20.8
5.2
5.2
4.2
20.8
5.2
5.2
5.2
5.2
1.0
11/19/09 14:20 11/20/09 19:12 7429-90-5
11/19/09 14:20 11/20/09 19:12 7440-36-0
11/19/09 14:20 11/20/09 19:12 7440-38-2
11/19/09 14:20 11/20/09 19:12 7440-41-7
11/19/09 14:20 11/20/09 19:12 7440-47-3
11/19/09 14:20 11/20/09 19:12 7440-50-8
11/19/09 14:20 11/20/09 19:12 7439-89-6
11/19/09 14:20 11/20/09 19:12 7439-92-1
11/19/09 14:20 11/20/09 19:12 7440-02-0
11/19/09 14:20 11/20/0919:12 7440-28-0
11/19/09 14:20 11/20/0919:12 7440-66-6
11/20/09 15:23 12/02/09 01:04 120-82-1
11/20/09 15:23 12/02/09 01:04 95-50-1
11/20/09 15:23 12/02/09 01:04 122-66-7
11/20/09 15:23 12/02/09 01:04 541-73-1
11/20/09 15:23 12102109 01:04 106-46-7
11/20/0915:23 12102/09 01:04 90-12-0
11/20/09 15:23 12102/09 01:04 95-95-4
11/20/09 15:23 12102109 01:04 88-06-2
11/20/0915:23 12/02109 01:04 120-83-2
11/20/09 15:23 12/02/09 01:04 105-67-9
11/20/09 15:23 12/02109 01:04 51-28-5
11/20/09 15:23 12/02/09 01:04 121-14-2
11/20/09 15:23 12/02/09 01:04 606-20-2
11/20/0915:23 12/02/09 01:04 91-58-7
11/20/09 15:23 12/02/09 01:04 95-57-8
11/20/09 15:23 12/02/09 01 :04 91-57-6
11/20/09 15:23 12102/09 01:04 95-48-7
11/20/09 15:23 12102109 01:04 88-74-4
11/20/09 15:23 12/02/09 01:04 88-75-5
11/20/09 15:23 12/02109 01:04
11/20/09 15:23 12/02/09 01 :04 91-94-1
11/20/09 15:23 12/02/09 01:04 99-09-2
11/20/09 15:23 12/02/09 01:04 534-52-1
11/20/0915:23 12/02/09 01:04 101-55-3
11/20/09 15:23 12/02/09 01 :04 59-50-7
11/20/09 15:23 12/02/09 01:04 106-47-8
11/20/09 15:23 12/02/09 01:04 7005-72-3
11/20/09 15:23 12102/09 01:04 100-01-6
11/20/09 15:23 12102/09 01:04 100-02-7
11/20/09 15:23 12102109 01:04 83-32-9
11/20/09 15:23 12/02/09 01 04 208-96-8
11/20/0915:23 12/02/09 01:04 120-12-7
11/20/09 15:23 12/02/09 01 :04 56-55-3
11/20/09 15:23 12/02/09 01:04 50-32-8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, 1nc ..
~o,:.~-'c-.L~. ~"-:.-·1 iS ~~~ 11neld.C\",
Oual
Page 8 of 32
Pace Analytical Sorvicos, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: CASTLE HAYNE 22-12493D
Pace Project No.: 9257759
Sample: TMW-2W LablD: 9257759002 Collected: 11/17/09 14:15 Received: 11/18/09 09:30 Matrix: Water
Parameters Results Units Report Limit OF Prepared Analyzed GAS No. Qual
8270 MSSV Semivolatile Organic Analytical Method: EPA8270
Benzo(b)fluoranthene ND ug/L 2.1 11/20/09 15:23 12/02/09 01:04 205-99-2
Benzo(g, h, i)pery Jene ND ug/L 5.2 11120109 15:23 12102109 01:04 191-24-2
Benzo(k)fluoranthene ND ug/L 4.2 11120109 15:23 12102109 01:04 207-08-9
Butylbenzylphthalate ND ug/L 5.2 11120109 15:23 12102109 01:04 85-68-7
Chrysene ND ug/L 5.2 11120109 15:23 12102109 01:04 218-01-9
Di-n-butylphthalate ND ug/L 5.2 11120109 15:23 12/02109 01 :04 84-74-2
Di-n-octylphthalate ND ug/L 5.2 11120109 15:23 12/02/09 01:04 117-84-0
Dibenz(a,h)anthracene ND ug/L 2.1 11120109 15:23 12/02109 01 :04 53-70-3
Dibenzofuran ND ug/L 5.2 11120/09 15:23 12102109 01:04 132-64-9
Oiethylphthalate ND ug/L 5.2 1112010915:23 12102109 01:04 84-66-2
Dimethylphthalate ND ug/L 5.2 11120109 15:23 12/02/09 01:04 131-11-3
Fluoranthene ND ug/L 5.2 11120109 15:23 12/02/09 01 :04 206-44-0
F!uorene ND ug/L 5.2 11120109 15:23 12/02/09 01:04 86-73-7
Hexachloro-1,3-butadiene ND ug/L 2.1 11120109 15:23 12/02/09 01:04 87-68-3
Hexachlorobenzene ND ug/L 1.0 11/20/0915:23 12/02109 01:04 118-74-1
Hexachlorocyclopentadiene ND ug/L 5.2 11120/09 15:23 12102/09 01 :04 77-47-4
Hexachloroethane ND ug/L 5.2 11120/09 15:23 12/02/09 01:04 67-72-1
lndeno(1,2,3-cd)pyrene ND ug/L 2.1 11120109 15:23 12/02/09 01 :04 193-39-5
lsophorone ND ug/L 5.2 11120109 15:23 12/02/09 01:04 78-59-1
N-Nitroso-di-n-propylamine ND ug/L 4.2 11 /20/09 15:23 12/02109 01:04 621-64-7
N-Nitrosodimethytamine ND ug/L 2.1 11120109 15:23 12102109 01:04 62-75-9
N-Nitrosodiphenylamine ND ug/L 5.2 11120109 15:23 12102109 01:04 86-30-6
Naphthalene ND ug/L 5.2 11120109 15:23 12/02109 01 :04 91-20-3
Nitrobenzene ND ug/L 4.2 11120109 15:23 12/02/09 01:04 98-95-3
Pentachlorophenol ND ug/L 20.8 11120109 15:23 12102109 01:04 87-86-5
Phenanthrene ND ug/L 5.2 11 /20/09 15:23 12102109 01:04 85-01-8
Phenol ND ug/L 5.2 11120109 15:23 12102109 01:04 108-95-2
Pyrene ND ug/L 5.2 11/20/09 15:23 12102109 01:04 129-00-0
bis(2-Chloroethyl) ether ND ug/L 4.2 11/20/09 15:23 12102109 01:04 111-44-4
bis(2-Chloroisopropyl) ether ND ug/L 5.2 11120109 15:23 12/02109 01 :04 108-60-1
bis(2-Ethyfhexyl)phthalate ND ug/L 5.2 11120109 15:23 12102109 01 :04 117-81-7
Nitrobenzene-d5 (S) 66 % 10-110 11120109 15:23 12102109 01:04 4165-60-0
2-Fluorobiphenyl (S) 75 % 18-110 11120109 15:23 12/02/09 01:04 321-60-8
Terphenyl-d14 (S) 79 % 10-123 11/20/09 15:23 12102109 01:04 1718-51-0
Phenol-d6 (S) 25 % 10-110 11/20/09 15:23 12102109 01:04 13127-88-3
2-Fluorophenol (S) 37 % 18-110 11120/09 15:23 12102109 01 :04 367-12-4
2,4,6-Tribromophenol (S) 71 % 10-110 11120109 15:23 12102109 01 :04 118-79-6
8260 MSV Low Level Analytical Method: EPA 8260
Acetone ND ug/L 25.0 11/27/09 02:46 67-64-1
Benzene ND ug/L 1.0 11127109 02:46 71-43-2
Bromobenzene ND ug/L 1.0 11127109 02:46 108-86-1
Bromochloromethane ND ug/L 1.0 11127109 02:46 74-97-5
Bromodichloromethane ND ug/L 1.0 11127109 02:46 75-27-4
Bromoform ND ug/L 1.0 11/27/09 02:46 75-25-2
Bromomethane ND ug/L 5.0 11/27/09 02:46 74-83-9
2-Butanone (MEK) ND ug/L 5.0 11/27/09 02:46 78-93-3
Date: 12/08/2009 04:23 PM REPORT OF LABORATORY ANALYSIS Page 9 of 32
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
~°-t:-!b,
,•'' l la:°""• t,ne C\;
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: CASTLE HAYNE 22-12493D
Pace Project No.: 9257759
Sample: TMW-2W LablD: 9257759002 Collected: 11/17/09 14:15 Received: 11/18/09 09:30 Matrix: Water
Parameters Results Units Report Umlt DF Prepared Analyzed CAS No. Qual
8260 MSV Low Level Analytical Method: EPA8260
Carbon tetrachloride ND ug/L 1.0 11/27/09 02:46 56-23-5
Chlorobenzene ND ug/L 1.0 11/27/09 02:46 108-90-7
Chtoroethane ND ug/L 1.0 11/27/09 02:46 75-00-3
Chloroform ND ug/L 1.0 11/27/09 02:46 67-66-3
Chloromethane ND ug/L 1.0 11/27/09 02:46 74-87-3
2-Chlorotoluene ND ug/L 1.0 11 /27 /09 02:46 95-49-8
4-Chlorotoluene ND ug/L 1.0 11/27/09 02:46 106-43-4
1,2-Dibromo-3-chloropropane ND ug/L 3.0 11/27/09 02:46 96-12-8
Dibromochloromethane ND ug/L 1.0 11/27/09 02:46 124-48-1
1,2-Dibromoethane (EDB) ND ug/L 1.0 11/27/09 02:46 106-93-4
Dibromomethane ND ug/L 1.0 11/27/09 02:46 74-95-3
1,2-Dichlorobenzene ND ug/L 1.0 11/27/09 02:46 95-50-1
1,3-Dichlorobenzene ND ug/L 1.0 11/27/09 02:46 541-73-1
1,4-Dichlorobenzene ND ug/L 1.0 11/27/09 02:46 106-46-7
Dichlorodifluoromethane ND ug/L 1.0 11 /27 /09 02:46 75-71-8
1 , 1-Dichloroethane ND ug/L 1.0 11/27/09 02:46 75-34-3
1,2-Dichloroethane ND ug/L 1.0 11/27/09 02:46 107-06-2
1, 1-Dichtoroethene ND ug/L 1.0 11/27/09 02:46 75-35-4
cis-1,2-0ichloroethene ND ug/L 1.0 11/27/09 02:46 156-59-2
trans-1,2-Dichloroethene ND ug/L 1.0 11/27/09 02:46 156-60-5
1,2-Dichloropropane ND ug/L 1.0 11/27/09 02:46 78-87-5
1,3-Dichloropropane ND ug/L 1.0 11/27/09 02:46 142-28-9
2,2-Dichloropropane ND ug/L 1.0 11/27/09 02:46 594-20-7
1, 1-Dichloropropene ND ug/L 1.0 11/27/09 02:46 563-58-6
cis-1,3-Dichloropropene ND ug/L 1.0 11/27/09 02:46 10061-01-5
trans-1,3-Dichloropropene ND ug/L 1.0 11/27/09 02:46 10061-02-6
Diisopropyl ether ND ug/L 1.0 11/27/09 02:46 108-20-3
Ethylbenzene ND ug/L 1.0 11/27/09 02:46 100-41-4
Hexachloro-1,3-butadiene ND ug/L 1.0 11/27/09 02:46 87-68-3
2-Hexanone ND ug/L 5.0 11/27/09 02:46 591-78-6
p-lsopropyltoluene ND ug/L 1.0 11/27/09 02:46 99-87-6
Methylene Chloride ND ug/L 2.0 11/27/09 02:46 75-09-2
4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 11/27/09 02:46 108-10-1
Methyl-tert-butyl ether ND ug/L 1.0 11/27/09 02:46 1634-04-4
Naphthalene ND ug/L 1.0 11/27/09 02:46 91-20-3
Styrene ND ug/L 1.0 11/27/09 02:46 100-42-5
1, 1, 1,2-Tetrachloroethane ND ug/L 1.0 11/27/09 02:46 630-20-6
1, 1,2,2-Tetrachloroethane ND ug/L 1.0 11/27/09 02:46 79-34-5
Tetrachloroethene ND ug/L 1.0 11/27/09 02:46 127-18-4
Toluene ND ug/L 1.0 11/27/09 02:46 108-88-3
1,2,3-Trichlorobenzene ND ug/L 1.0 11 /27 /09 02:46 87-61-6
1,2,4-T richlorobenzene ND ug/L 1.0 11/27/09 02:46 120-82-1
1, 1, 1-Trichloroethane ND ug/L 1.0 11/27/09 02:46 71-55-6
1, 1,2-Trichloroethane ND ug/L 1.0 11/27/09 02:46 79-00-5
Trichtoroethene ND ug/L 1.0 11/27/09 02:46 79-01-6
Trichlorofluoromethane ND ug/L 1.0 11/27/09 02:46 75-69-4
1,2,3-Trichloropropane ND ug/L 1.0 11/27/09 02:46 96-18-4
Date: 12/08/2009 04:23 PM REPORT OF LABORATORY ANALYSIS Page 10 of 32
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc .. «~-;1nelac1,
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
(828)254•7176
Paco Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875•9092
Project: CASTLE HAYNE 22-12493D
Pace Project No.: 9257759
Sample: TMW-2W
Parameters
8260 MSV Low Level
Vinyl acetate
Vinyl chloride
m&p-Xylene
a-Xylene
4-Bromofluorobenzene (S)
Dibromofluoromethane (S)
1,2-Dichloroethane-d4 (S)
Toluene--da (S)
Date: 12/08/2009 04:23 PM
LablD: 9257759002 Collected: 11/17/09 14:15 Received: 11/18/09 09:30 Matrix: Water
Results Units Report Limit DF Prepared
Analytical Method: EPA 8260
ND ug/L 2.0
ND ug/L 1.0
ND ug/L 2.0
ND ug/L 1.0
97 % 87-109
97 % 85-115
94% 79-120
100 % 70-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, !nc ..
~~«~~~~~ r,nelaei,
Analyzed GAS No.
11/27/09 02:46 108-05-4
11/27/09 02:46 75-01-4
11/27/09 02:46 1330-20-7
11127/09 02:46 95-47-6
11/27/09 02:46 460-00-4
11/27 /09 02:46 1868-53-7
11/27/09 02:46 17060-07-0
11/27/09 02:46 2037-26-5
Qual
Page 11 of 32
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(7D4 )875-9092
Project: CASTLE HAYNE 22-12493D
Pace Project No.: 9257759
Sample: TMW-3W LablD: 9257759003 Collected: 11/17/09 13:45 Received: 11/18/09 09:30 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Quat
6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3010
Aluminum 619 ug/L 100 11/19/09 14:20 11120109 19:16 7429-90-5
Antimony ND ug/L 5.0 11119109 14:20 11120/0919:16 7440-36-0
Arsenic 18.0 ug/L 5.0 11119109 14:20 11/20109 19:16 7440-38-2
Beryllium ND ug/L 1.0 11119109 14:20 11120109 19:16 7440-41-7
Chromium ND ug/L 5.0 11119109 14:20 11120109 19:16 7440-47-3
Copper ND u9/L 5.0 11119109 14:20 11/20/09 19:16 7440-50-8
Iron 19300 ug/L 50.0 11119109 14:20 11120109 19:16 7439-89-6
Lead ND ug/L 5.0 11119109 14:20 11120109 19:16 7439-92-1
Nickel ND ug/L 5.0 1111910914:20 11120109 19:16 7440-02-0
Thallium ND ug/L 10.0 11119109 14:20 11120109 19:16 7440-28-0
Zinc ND ug/L 10.0 11119109 14:20 11120109 19:16 7440-66-6
8270 MSSV Semivolatile Organic Analytical Method: EPA 8270
1,2,4-Trichlorobenzene ND ug/L 5.1 11120/0915:23 12/02/09 01:33 120-82-1
1,2-Dichlorobenzene ND ug/L 5.1 11120109 15:23 12102109 01:33 95-50-1
1,2-Diphenylhydrazine ND ug/L 5.1 11120/09 15:23 12102109 01 :33 122-66-7
1,3-Dichlorobenzene ND ug/L 5.1 11120109 15:23 12102109 01 :33 541-73-1
1,4-Dichlorobenzene ND ug/L 5.1 11120109 15:23 12102109 01:33 106-46-7
1-Methylnaphthalene ND, ug/L 5.1 1112010915:23 12102109 01:33 90-12-0
2,4,5-Trichlorophenol ND ug/L 4.1 11120109 15:23 12102/09 01:33 95-95-4
2 ,4, 6-T rich lorophenol ND ug/L 2.1 11120109 15:23 12102109 01 :33 88-06-2
2,4-Dichlorophenol ND ug/L 2.1 11120109 15:23 12102109 01:33 120-83-2
2,4-Dimethylphenol ND ug/L 5.1 11/20/09 15:23 12102109 01:33 105-67-9
2.4-Dinltrophenol ND ug/L 20.5 1112010915:23 12102109 01:33 51-28-5
2,4-Dinitrotoluene ND ug/L 2.1 11/20/0915:23 12102109 01:33 121-14-2
2,6-Dinitrototuene ND ug/L 2.1 11120109 15:23 12/02109 01:33 606-20-2
2-Chloronaphthalene ND ug/L 5.1 11120109 15:23 12102109 01 :33 91-58-7
2-Chlorophenol ND ug/L 5.1 11/20109 15:23 12102109 01 :33 95-57-8
2-Methylnaphthalene ND ug/L 5.1 11120109 15:23 12/02109 01:33 91-57-6
2-Methylphenol(o-Cresol) ND ug/L 5.1 11120109 15:23 12102109 01:33 95-48-7
2-Nitroaniline ND ug/L 5.1 11120109 15:23 12102109 01:33 88-74-4
2-Nitrophenol ND ug/L 5.1 11120/09 15:23 12102109 01:33 88-75-5
3&4-Methylphenol(m&p Cresci) ND ug/L 10.3 11120109 15:23 12102109 01:33
3,3'-Dichlorobenzidine ND ug/L 10.3 11120109 15:23 12102109 01 :33 91-94-1
3-Nitroaniline ND ug/L 5.1 11120109 15:23 12102109 01 :33 99-09-2
4,6-Dinitro-2-methylphenol ND ug/L 20.5 11120109 15:23 12102109 01:33 534-52-1
4-Bromophenylphenyl ether NO ug/L 5.1 1112010915:23 12102109 01:33 101-55-3
4-Chloro-3-methylphenol ND ug/L 20.5 11120/09 15:23 12102109 01:33 59-50-7
4-Chloroaniline ND ug/L 5.1 11120109 15:23 12102109 01:33 106-47-8
4-Chlorophenylphenyl ether ND ug/L 5.1 11/20/09 15:23 12/02/09 01 :33 7005-72-3
4-Nitroaniline ND ug/L 4.1 11/20/09 15:23 12102109 01:33 100-01-6
4-Nitrophenol ND ug/L 20.5 11120109 15:23 12102109 01:33 100-02-7
Acenaphthene ND ug/L 5.1 11120109 15:23 12/02/09 01:33 83-32-9
Acenaphthylene ND ug/L 5.1 11120109 15:23 12102109 01:33 208-96-8
Anthracene ND ug/L 5.1 11 /20/09 15:23 12/02/09 01:33 120-12-7
Benzo(a)anthracene ND ug/L 5.1 11120109 15:23 12102/09 01:33 56-55-3
Benzo(a)pyrene ND ug/L 1.0 11120109 15:23 12102/09 01:33 50-32-8
Date: 12108/2009 04:23 PM REPORT OF LABORATORY ANALYSIS Page 12 of 32
This report shall not be reproduced, except in full.
without the written consent of Pace Ana!ytiC31 Services, Inc ..
7.:..'!_.',{f!~ •• _.-1 la v. 11ne c,
Pace Analytical Services, Inc.
2225 Riverside Or.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: CASTLE HAYNE 22-124930
Pace Project No.: 9257759
Sample: TMW-3W LablD: 9257759003 Collected: 11/17/09 13:45 Received: 11/18/09 09:30 Matrix: Water
Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual
8270 MSSV Semivolatile Organic Analytical Method: EPA 8270
Benzo(b )fluoranthene ND ug/L 2.1 11/20/09 15:23 12/02/09 01:33 205-99-2
Benzo(g, h,i)perylene ND ug/L 5.1 11/20/0915:23 12/02/09 01:33 191-24-2
Benzo(k)fluoranthene ND ug/L 4.1 11/20/09 15:23 12/02/09 01:33 207-08-9
Butyfbenzylphthalate NO ug/L 5.1 11/20/09 15:23 12/02/09 01:33 85-68-7
Chrysene NO ug/L 5.1 11/20/09 15:23 12/02/09 01 :33 218-01-9
Di-n-butylphthalate ND ug/L 5.1 11/20/09 15:23 12/02/09 01:33 84-74-2
Di-n-octylphthalate ND ug/L 5.1 11/20/09 15:23 12102/09 01:33 117-84-0
Dibenz{a, h)anthracene ND ug/L 2.1 11120/0915:23 12102/09 01:33 53-70-3
Dibenzofuran NO ug/L 5.1 11120109 15:23 12102109 01:33 132-64-9
Oiethylphthalate ND ug/L 5.1 11120109 15:23 12/02109 01:33 84-66-2
Dimethylphthalate NO ug/L 5.1 11/20/09 15:23 12/02/09 01 :33 131-11-3
Fluoranthene ND ug/L 5.1 11120109 15:23 12/02109 01:33 206-44-0
Fluorene ND ug/L 5.1 11120109 15:23 12/02/09 01:33 86-73-7
Hexachloro-1,3-butadiene ND ug/L 2.1 11/20/0915:23 12102109 01:33 87-68-3
Hexachlorobenzene NO ug/L 1.0 1112010915:23 12102109 01:33 118-74-1
Hexachlorocyclopentadiene ND ug/L 5.1 11120109 15:23 12/02/09 01:33 77-47-4
Hexachloroethane ND ug/L 5.1 11120109 15:23 12/02109 01 :33 67-72-1
lndeno(1,2,3-cd)pyrene ND ug/L 2.1 11120109 15:23 12/02/09 01 :33 193-39-5
lsophorone ND ug/L 5.1 11120109 15:23 12/02/09 01 :33 78-59-1
N-Nitroso-di-n-propyfamine • ND ug/L 4.1 11/20/09 15:23 12102109 01:33 621-64-7
N-Nitrosodimethy1amine ND ug/L 2.1 11120/09 15:23 12/02109 01:33 62-75-9
N-Nilrosodiphenylamine ND ug/L 5.1 11120109 15:23 12102109 01:33 86-30-6
Naphthalene ND ug/L 5.1 11/20/09 15:23 12/02109 01:33 91-20-3
Nitrobenzene ND ug/L 4.1 11 /20/09 15:23 12102109 01:33 98-95-3
Pentachlorophenol NO ug/L 20.5 11120109 15:23 12/02/09 01:33 87-86-5
Phenanthrene ND ug/L 5.1 11/20/09 15:23 12/02/09 01:33 85-01-8
Phenol ND ug/L 5.1 11120109 15:23 12/02/09 01 :33 108-95-2
Pyrene ND ug/L 5.1 11/20/09 15:23 12/02/09 01 :33 129-00-0
bis{2-Chloroethyl) ether ND ug/L 4.1 11/20/09 15:23 12102/09 01:33 111-44-4
bis(2-Ch!oroisopropyl) ether ND ug/L 5.1 11120109 15:23 12102109 01:33 108-60-1
bis(2-Ethylhexy1)phthalate ND ug/L 5.1 11/20/09 15:23 12/02/09 01:33 117-81-7
Nitrobenzene-d5 (S) 60 % 10-110 11120109 15:23 12102/09 01:33 4165-60-0
2-Ftuorobiphenyl (S) 68 % 18-110 11120/09 15:23 12/02/09 01 :33 321-60-8
Terphenyl-d14 (S) 87 % 10-123 11/20/09 15:23 12/02/09 01:33 1718-51-0
Phenol-d6 (S) 25 % 10-110 11/20109 15:23 12102109 01:33 13127-88-3
2-Fluorophenol (S) 37 % 18-110 1112010915:23 12/02/09 01:33 367-12-4
2,4,6-Tribromophenol (S) 66 % 10-110 11/20/0915:23 12102109 01:33 118-79-6
8260 MSV Low Level Analytical Method: EPA 8260
Acetone ND ug/L 25.0 11127109 03:10 67-64-1
Benzene ND ug/L 1.0 11127109 03:10 71-43-2
Bromobenzene ND ug/L 1.0 11/27/09 03:10 108-86-1
Bromochloromethane ND ug/L 1.0 11/27/09 03:10 74-97-5
Bromodich!oromethane NO ug/L 1.0 11127109 03:10 75-27-4
Bromoform ND ug/L 1.0 11127109 03:10 75-25-2
Bromomethane ND ug/L 5.0 11127109 03:10 74-83-9
2-Butanone (MEK) NO ug/L 5.0 11127109 03:10 78-93-3
Date: 12/08/2009 04:23 PM REPORT OF LABORATORY ANALYSIS Page 13 of 32
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
K·<-if~. ,•' ~ ~--tine c,;
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: CASTLE HAYNE 22-124930
Pace Project No.: 9257759
Sample: TMW-3W LablD: 9257759003 Collected: 11/17/09 13:45 Received: 11/18/09 09:30 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed GAS No. Qual
8260 MSV Low Level Analytical Method: EPA8260
Carbon tetrachloride ND ug/L 1.0 11127/09 03:10 56-23-5
Chlorobenzene ND ug/L 1.0 11127109 03:10 108-90-7
Chloroethane ND ug!L 1.0 11127109 03:10 75-00-3
Chloroform ND ug/L 1.0 11127109 03:10 67-66-3
Chtoromethane ND ug!L 1.0 11127109 03:10 74-87-3
2-Chlorotoluene ND ug/L 1.0 11127109 03:10 95-49-8
4-Chlorotoluene ND u9/L 1.0 11127109 03:10 106-43-4
1,2-Dibromo-3-chloropropane ND ug/L 3.0 11127109 03:10 96-12-8
Dibromochloromethane ND u9/L 1.0 11127109 03:10 124-48-1
1,2-Dibromoethane (EDS) ND ug/L 1.0 11127109 03:10 106-93-4
Dibromomethane ND ug/L 1.0 11127109 03:10 74-95-3
1,2-Dichlorobenzene ND ug/L 1.0 11/27/09 03:10 95-50-1
1,3-Dichlorobenzene ND ug/L 1.0 11127109 03:10 541-73-1
1,4-Dichlorobenzene ND ug/L 1.0 11127109 03:10 106-46-7
Dichlorodifluoromethane ND ug/L 1.0 11127109 03:10 75-71-8
1, 1-Dichloroethane ND ug/L 1.0 11127109 03:10 75-34-3
1,2-Dichloroethane ND ug/L 1.0 11127109 03:10 107-06-2
1.1-Dichloroethene ND ug/L 1.0 11127109 03:10 75-35-4
cis-1,2-Dichloroethene ND ug/L 1.0 11127109 03:10 156-59-2
trans-1,2-Dichloroethene ND ug/L 1.0 11127109 03:10 156-60-5
1,2-Dichloropropane ND ug/L 1.0 11127109 03:10 78-87-5
1,3-Dichloropropane ND ug/L 1.0 11127109 03:10 142-28-9
2,2-Dichloropropane ND ug/L 1.0 11/27/09 03:10 594-20-7
1, 1-Dichloropropene ND ug/L 1.0 11127109 03:10 563-58-6
cis-1,3-Dichloropropene ND ug/L 1.0 11/27/09 03:10 10061-01-5
trans-1,3-Dichloropropene ND ugtl 1.0 11/27/09 03:10 10061-02-6
Diisopropyl ether ND ug/L 1.0 11127/09 03:10 108-20-3
Ethylbenzene ND ug/L 1.0 11/27/09 03:10 100-41-4
Hexachloro-1,3-butadiene ND ug/L 1.0 11/27/09 03:10 87-68-3
2-Hexanone · NO ug/l 5.0 11/27/09 03:10 591-78-6
p-lsopropyltoluene ND ug/L 1.0 11/27/09 03:10 99-87-6
Methylene Chloride ND ug/L 2.0 11/27/09 03:10 75-09-2
4-Methyt-2-pentanone (MIBK) ND ug/L 5.0 11/27/09 03:10 108-10-1
Methyl-tert-butyl ether ND ug/L 1.0 11/27/09 03:10 1634-04-4
Naphthalene ND ug/L 1.0 11/27/09 03:10 91-20-3
Styrene ND ug/L 1.0 11/27/09 03:10 100-42-5
1 , 1, 1,2-Tetrachloroethane ND ug/L 1.0 11127/09 03:10 630-20-6
1, 1,2,2-Tetrachloroethane ND ug/L 1.0 11127109 03:10 79-34-5
Tetrachloroethene ND ug/L 1.0 11/27/09 03:10 127-18-4
Toluene ND ug/L 1.0 11/27/09 03:10 108-88-3
1,2,3-Trichlorobenzene ND ugfl 1.0 11/27/09 03:10 87-61-6
1,2,4-Trichlorobenzene ND ug/L 1.0 11127/09 03:10 120-82-1
1, 1, 1-Trichloroethane ND ug/L 1.0 11127/09 03:10 71-55-6
1, 1,2-Trichloroethane ND ug/L 1.0 11127/09 03:10 79-00-5
Trichloroethene ND ug/L 1.0 11/27/09 03:10 79-01-6
T richlorofluorornethane ND ug/l 1.0 11/27/09 03:10 75-69-4
1,2,3-Trichloropropane ND ug/l 1.0 11/27/09 03:10 96-18-4
Date: 12/08/2009 04:23 PM REPORT OF LABORATORY ANALYSIS Page 14 of 32
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc .. ~«_c~~" 21nelac:, . --,.
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704 }875-9092
Project CASTLE HAYNE 22-12493D
Pace Project No.: 9257759
Sample: TMW-3W
Parameters
8260 MSV Low Level
Vinyl acetate
Vinyl chloride
m&p-Xylene
a-Xylene
4-Bromofluorobenzene (S)
Dibromofluoromethane (S)
1,2-Dich1oroethane-d4 (S)
Toluene-dB (S)
Date: 12/08/2009 04:23 PM
LablD: 9257759003 Collected: 11/17/09 13:45 Received: 11/18/09 09:30 Matrix: Water
Results Units Report Limit DF Prepared
Analytical Method: EPA 8260
ND ug/L 2.0
ND ug/L 1.0
ND ug/L 2.0
NO ug/L 1.0
95 % 87-109
98 % 85-115
95 % 79-120
100 % 70-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc,.
Analyzed CAS No.
11/27/09 03:10 108-05-4
11127/09 03:10 75-01-4
11/27/09 03:10 1330-20-7
11/27/09 03:10 95-47-6
11/27/09 03:10 460-00-4
11/27/09 03:10 1868-53-7
11/27/09 03:10 17060-07-0
11/27/09 03:10 2037-26-5
Qual
Page15of32
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704 )875-9092
Project: CASTLE HAYNE 22-12493D
Pace Project No.: 9257759
Sample: TMW-4W LablD: 9257759004 Collected: 11/17/09 09:30 Received: 11/18/09 09:30 Matrix: Water
Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual
6010 MET ICP Analytical Method: EPA6010 Preparation Method: EPA3010
Aluminum 6090 ug/L 100 11119109 14:20 11120109 19:20 7429-90-5
Antimony ND ug/L 5.0 · 11119109 14:20 11120109 19:20 7440-36-0
Arsenic ND ug/L 5.0 11/19/09 14:20 11/20109 19:20 7440-38-2
Beryllium NO ug/L 1.0 11119109 14:20 11120109 19:20 7440-41-7
Chromium 11.6 ug/L 5.0 11/19/09 14:20 11120109 19:20 7440-47-3
Copper ND ug/L 5.0 11/19/09 14:20 1112010919:20 7440-50-8
Iron 9600 ug/L 50.0 11/19/0914:20 11120109 19:20 7439-89-6
Lead 6.0 ug/L 5.0 11119109 14:20 11120109 19:20 7439-92-1
Nickel ND ug/L 5.0 11/19/09 14:20 11/20/09 19:20 7440-02-0
Thallium ND ug/L 10.0 11/19/09 14:20 11120109 19:20 7440-28-0
Zinc 18.5 ug/L 10.0 11119109 14:20 11120109 19:20 7440-66-6
8270 MSSV Semivolatile Organic Analytical Method: EPA 8270
1,2.4-Trichlorobenzene ND ug/L 5.2 11120109 15:23 12102109 02:03 120-82-1
1,2-Dichlorobenzene ND ug/L 5.2 11/20/09 15:23 12102109 02:03 95-50-1
1,2-Diphenylhydrazine ND ug/L 5.2 11120109 15:23 12102109 02:03 122-66-7
1,3-Dichlorobenzene ND ug/L 5.2 11120109 15:23 12102109 02:03 541-73-1
1,4-Dichlorobenzene ND ug/L 5.2 11/20/0915:23 12102109 02:03 106-46-7
1-Methylnaphthalene ND ug/L 5.2 11120/09 15:23 12/02/09 02:03 90-12-0
2,4,5-T richlorophenol ND ug/L 4.2 11/20/09 15:23 12/02/09 02:03 95-95-4
2,4,6-Trichlorophenol ND ug/L 2.1 11120109 15:23 12/02/09 02:03 88-06-2
2,4-Dichlorophenol ND ug/L 2.1 11120109 15:23 12102109 02:03 120-83-2
2,4-Dimethylphenol ND ug/L 5.2 11/20/09 15:23 12102109 02:03 105-67-9
2.4-Dinitrophenol ND ug/L 20.9 11120/09 15:23 12102109 02:03 51-28-5
2,4-Dinltrotoluene ND ug/L 2.1 11120109 15:23 12102109 02:03 121-14-2
2,6-Dinltrotoluene ND ug/L 2.1 11120109 15:23 12102/09 02:03 606-20-2
2-Chloronaphthalene ND ug/L 5.2 11120109 15:23 12102109 02:03 91-58-7
2-Chlorophenol ND ug/L 5.2 11120109 15:23 12102109 02:03 95-57-8
2-Methylnaphthalene ND ug/L 5.2 11/20/09 15:23 12102109 02:03 91-57-6
2-Methylphenol(o-Cresol) ND ug/L 5.2 11/20/09 15:23 12102109 02:03 95-48-7
2-Nitroaniline ND ug/L 5.2 11120109 15:23 12102109 02:03 88-74-4
2-Nitrophenol ND ug/L 5.2 11/20/09 15:23 12/02/09 02:03 88-75-5
3&4-Methylphenol(m&p Cresol) ND ug/L 10.4 11/20/0915:23 12102109 02:03
3,3'-Dichlorobenzidine ND ug/L 10.4 11120109 15:23 12102/09 02:03 91-94-1
3-Nitroaniline ND ug/L 5.2 11120109 15:23 12102/09 02:03 99-09-2
4,6-Dinitro-2-methylphenol ND ug/L 20.9 11120109 15:23 12102/09 02:03 534-52-1
4-Bromophenylphenyl ether ND ug/L 5.2 11120109 15:23 12102109 02:03 101-55-3
4-Chloro-3-methylphenol ND ug/L 20.9 11/20/09 15:23 12102109 02:03 59-50-7
4-Chloroaniline ND ug/L 5.2 11/20/09 15:23 12102109 02:03 106-47-8
4-Chlorophenylphenyl ether ND ug/L 5.2 11/20/09 15:23 12102109 02:03 7005-72-3
4-Nitroani!ine ND ug/L 4.2 11120109 15:23 12102109 02:03 100-01-6
4-Nitrophenol ND ug/L 20.9 11120109 15:23 12102109 02:03 100-02-7
Acenaphthene ND ug/L 5.2 11120109 15:23 12/02/09 02:03 83-32-9
Acenaphthylene NO ug/L 5.2 11120109 15:23 12/02109 02:03 208-96-8
Anthracene NO ug/L 5.2 11/20/09 15:23 12/02/09 02:03 120-12-7
Benzo(a)anthracene ND ug/L 5.2 11/20/09 15:23 12102109 02:03 56-55-3
Benzo(a)pyrene ND ug/L 1.0 11120109 15:23 12102109 02:03 50-32-8
Date: 12/08/2009 04:23 PM REPORT OF LABORATORY ANALYSIS Page 16 of 32
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
,~~~---~~~ ,•-71 la •,, 11ne c,,
Paco Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704 )875-9092
Project: CASTLE HAYNE 22-124930
Pace Project No.: 9257759
Sample: TMW-4W LablD: 9257759004 Collected: 11/17/09 09:30 Received: 11/18/09 09:30 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8270 MSSV Semivolatile Organic Analytical Method: EPA8270
Benzo(b)fluoranthene ND ug/l 2.1 11120/09 15:23 12102109 02:03 205-99-2
Benzo(g,h,i)perylene ND ug/L 5.2 11/20/09 15:23 12102109 02:03 191-24-2
Benzo(k)fluoranthene ND ug/l 4.2 11/20/09 15:23 12102109 02:03 207-08-9
Butylbenzylphthalate ND ug/L 5.2 11/20/09 15:23 12102/09 02:03 85-68-7
Chrysene ND ug/L 5.2 11 /20/09 15:23 12/02/09 02:03 218-01-9
Di-n-butylphthalate ND ug/l 5.2 11/20/09 15:23 12/02/09 02:03 84-74-2
Di-n-octylphthalate ND ug/L 5.2 11/20/09 15:23 12/02/09 02:03 117-84-0
Dibenz(a,h )anthracene ND ug/L 2.1 11/20/0915:23 12/02/09 02:03 53-70-3
Dibenzofuran NO ug/l 5.2 11/20/09 15:23 12/02/09 02:03 132-64-9
Diethylphthalate ND ug/L 5.2 11/20/09 15:23 12/02/09 02:03 84-66-2
Dimethylphthalate ND ug/L 5.2 11 /20/09 15:23 12102109 02:03 131-11-3
Fluoranttiene ND ug/L 5.2 11/20/09 15:23 12102/09 02:03 206-44-0
Fluorene NO ug/L 5.2 11/20/09 15:23 12/02/09 02:03 86-73-7
Hexachloro-1,3-butadiene ND ug/l 2.1 11/20/09 15:23 12102/09 02:03 87-68-3
Hexachlorobenzene ND ug/L 1.0 11/20/09 15:23 12102/09 02:03 118-74-1
Hexachlorocyclopentadiene ND ug/l 5.2 11 /20/09 15:23 12/02109 02:03 77-47-4
Hexachloroethane ND ug/L 5.2 11/20/09 15:23 12102109 02:03 67-72-1
lndeno(1,2,3-cd)pyrene ND ug/L 2.1 11/20/09 15:23 12102/09 02:03 193-39-5
lsophorone ND ug/l 5.2 11/20/09 15:23 12/02/09 02:03 78-59-1
N-Nitroso-di-n-propylamine ND ug/l 4.2 11/20/09 15:23 12/02/09 02:03 621-64-7
N-Nitrosodimethylamine NO ug/l 2.1 11/20/09 15:23 12/02/09 02:03 62-75-9
N-Nitrosodiphenylamine ND ug/L 5.2 11/20/09 15:23 12/02/09 02:03 86-30-6
Naphthalene ND ug/L 5.2 11/20/09 15:23 12102109 02:03 91-20-3
Nitrobenzene NO ug/L 4.2 11/20/09 15:23 12102/09 02:03 98-95-3
Pentachlorophenol ND ug/L 20.9 11/20/09 15:23 12/02/09 02:03 87-86-5
Phenanthrene ND ug/l 5.2 11/20/09 15:23 12102109 02:03 85-01-8
Phenol ND ug/L 5.2 11/20/09 15:23 12102109 02:03 108-95-2
Pyrene ND ug/L 5.2 11/20/09 15:23 12/02/09 02:03 129-00-0
bis(2-Chloroethyl) ether ND ug/L 4.2 11/20/09 15:23 12/02/09 02:03 111-44-4
bis(2-Chtoroisopropyl) ether ND ug/L 5.2 11/20/0915:23 12/02/09 02:03 108-60-1
bis{2-Ethylhexyl)phthalate ND ug/L 5.2 11/20/09 15:23 12/02/09 02:03 117-81-7
Nitrobenzene-d5 (S) 34 % 10-110 11 /20/09 15:23 12/02/09 02:03 4165-60-0
2-Fluorobiphenyl {S) 43 % 18-110 11 /20/09 15:23 12/02/09 02:03 321-60-8
Terphenyl-d14 (S) 59 % 10-123 11/20/09 15:23 12/02/09 02:03 1718-51-0
Phenol-d6 (S) 16 % 10-110 11/20/09 15:23 12102109 02:03 13127-88-3
2-Fluorophenol (S) 22 % 18-110 11/20/09 15:23 12102109 02:03 367-12-4
2,4,6-Tribromophenol (S) 40 % 10-110 11/20/09 15:23 12102109 02:03 118-79-6
8260 MSV Low Level Analytical Method: EPA8260
Acetone ND ug/L 25.0 11/27/09 03:34 67-64-1
Benzene ND ug/L 1.0 11/27/09 03:34 71-43-2
Bromobenzene ND ug/L 1.0 11/27/09 03:34 108-86-1
Bromochtoromethane ND ug/L 1.0 11127/09 03:34 74-97-5
Bromodichloromethane ND ug/L 1.0 11/27/09 03:34 75-27-4
Bromoform ND ug/L 1.0 11/27/09 03:34 75-25-2
Bromomethane ND ug/L 5.0 11 /27 /09 03:34 74-83-9
2-Butanone (MEK) ND ug/L 5.0 11/27/09 03:34 78-93-3
Date: 12/08/2009 04:23 PM REPORT OF LABORATORY ANALYSIS Page 17 of 32
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services. Inc ..
.. -Pf-'~~--i1ne c;
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. s_uite 100
Huntersville, NC 28078
[phone]
Project:
Pace Project No.:
CASTLE HAYNE 22-124930
9257759
Sample: TMW-4W LablD: 9257759004 Collected: 11/17/09 09:30 Received: 11/16/09 09:30 Matrix: Water
Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual
8260 MSV Low Level Analytical Method: EPA8260
Carbon tetrachloride ND ug/L 1.0 11/27/09 03:34 56-23-5
Chlorobenzene ND ug/L 1.0 11/27/09 03:34 108-90-7
Chloroethane ND ug/L 1.0 11/27/09 03:34 75-00-3
Chloroform ND ug/L 1.0 11/27/09 03:34 67-66-3
Chloromethane 1.5 ug/L 1.0 11/27/09 03:34 74-67-3
2-Chlorotoluene ND ug/L 1.0 11/27/09 03:34 95-49-8
4-Chlorotoluene NO ug/L • 1.0 11/27/09 03:34 106-43-4
1,2-Dlbromo-3-chloropropane ND ug/L 3.0 11/27/09 03:34 96-12-8
Dibromochloromethane ND ug/L 1.0 11/27/09 03:34 124-46-1
1,2-Dibromoethane (EDB) ND ug/L 1.0 11127 /09 03:34 106-93-4
Dibromomethane ND ug/L 1.0 11/27/09 03:34 74-95-3
1,2-Dichlorobenzene ND ug/L 1.0 11/27/09 03:34 95-50-1
1,3-Dichlorobenzene ND ug/L 1.0 11/27/09 03:34 541-73-1
1,4-0ichlorobenzene ND ug/L 1.0 11/27/09 03:34 106-46-7
Oichlorodifluoromethane ND ug/L 1.0 11 /27 /09 03:34 75-71-6
1, 1-Dichloroethane NO ug/L 1.0 11/27/09 03:34 75-34-3
1,2-Dichloroethane ND ug/L 1.0 11/27/09 03:34 107-06-2
1, 1-Dichloroethene ND ug/L 1.0 11/27/09 03:34 75-35-4
cis-1,2-Dichloroethene ND ug/L 1.0 11/27/09 03:34 156-59-2
trans-1,2-Dichloroethene ND ug/L 1.0 11/27/09 03:34 156-60-5
1,2-Dichloropropane ND ug/L 1.0 11/27/09 03:34 78-87-5
1,3-Dichloropropane ND ug/L 1.0 11/27/09 03:34 142-28-9
2,2-Dichloropropane ND ug/L 1.0 11/27/09 03:34 594-20-7
1, 1-Dichloropropene ND ug/L 1.0 11/27/09 03:34 563-58-6
cis-1,3-Dichloropropene ND ug/L 1.0 11/27/09 03:34 10061-01-5
trans-1,3-Dichloropropene ND ug/L 1.0 11/27/09 03:34 10061-02-6
Oiisopi--opyl ether ND ug/L 1.0 11/27/09 03:34 108-20-3
Ethylbenzene ND ug/L 1.0 11/27/09 03:34 100-41-4
Hexachloro-1,3-butadiene ND ug/L 1.0 11/27/09 03:34 87-68-3
2-Hexanone NO ug/L 5.0 11/27/09 03:34 591-78-6
p-lsopropyltoluene ND ug/L 1.0 11/27/09 03:34 99-87-6
Methylene Chloride ND ug/L 2.0 11/27/09 03:34 75-09-2
4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 11 /27 /09 03:34 108-10-1
Methyl-tert-butyl ether ND ug/L 1.0 11127/09 03:34 1634-04-4
Naphthalene ND ug/L 1.0 11/27/09 03:34 91-20-3
Styrene ND ug/L 1.0 11/27/09 03:34 100-42-5
1, 1, 1,2-Tetrachloroethane NO ug/L 1.0 11/27/09 03:34 630-20-6
1, 1,2,2-Tetrachloroethane ND ug/L 1.0 11/27/09 03:34 79-34-5
Tetrachloroethene ND ug/L 1.0 11/27/09 03:34 127-18-4
Toluene ND ug/L 1.0 11/27/09 03:34 108-88-3
1,2,3-Trichlorobenzene ND ug/L 1.0 11/27/09 03:34 87-61-6
1,2,4-Trichlorobenzene ND ug/L 1.0 11 /27 /09 03:34 120-82-1
1, 1, 1-Trichloroethane ND ug/L 1.0 11 /27 /09 03:34 71-55-6
1, 1,2-Trichloroethane ND ug/L 1.0 11/27/09 03:34 79-00-5
Trichloroethene ND ug/L 1.0 11/27/09 03:34 79-01-6
Trichlorofluoromethane ND ug/L 1.0 11/27/09 03:34 75-69-4
1,2,3-Trichloropropane ND ug/L 1.0 11/27/09 03:34 96-18-4
Date: 12/06/2009 04:23 PM REPORT OF LABORATORY ANAL)'.SIS Page 18 of 32
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
~sf~~~~~
0,nelac· '. -\,
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project CASTLE HAYNE 22-124930
Pace Project No.: 9257759
Sample: TMW-4W
Parameters
8260 MSV Low Level
Vinyl acetate
Vinyl chloride
m&p-Xylene
a-Xylene
4-Bromofluorobenzene (S)
Dibromofluoromethane (S)
1,2-Dichloroethane-d4 (S)
Toluene-dB (S)
Date: 12/08/2009 04:23 PM
LablD: 9257759004 Collected: 11/17/09 09:30 Received: 11/18/09 09:30 Matrix: Water
Results Units Report Limit DF Prepared
Analytical Method: EPA6260
ND ug/L 2.0
ND ug/L 1.0
ND ug/L 2.0
ND ug/L 1.0
98 % 67-109
98 % 65-115
97 % 79-120
100 % 70-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc .. .. ~«·\~~ .... ?1nelaei,
Analyzed CAS No.
11/27/09 03:34 106-05-4
11/27/09 03:34 75-01-4
11/27/09 03:34 1330-20-7
11/27/09 03:34 95-47-6
11/27/09 03:34 460-00-4
11/27/09 03:34 1666-53-7
11/27/09 03:34 17060-07-0
11/27/09 03:34 2037-26-5
Qual
Page 19 of 32
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
{828)254-7176
QUALITY CONTROL DATA
Project: CASTLE HAYNE 22-12493D
Pace Project No.: 9257759
QC Batch: MPRP/5416 Analysis Method:
QC Batch Method: EPA 3010 Analysis Description:
Associated Lab Samples: 9257759001, 9257759002, 9257759003, 9257759004
METHOD BLANK: 368870 Matrix: Water
Associated Lab Samples: 9257759001, 9257759002, 9257759003, 9257759004
Blank Reporting
EPA 6010
6010 MET
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704 )875-9092
Parameter Units Result Limit Analyzed Qualifiers
Aluminum ug/L ND 100 11/20/09 17:42
Antimony ug/L ND 5.0 11/20109 17:42
Arsenic ug/L ND 5.0 . 11120109 17:42
Beryllium ug/L ND 1.0 11120109 17:42
Chromium ug/L ND 5.0 11120109 17:42
Copper ug/L ND 5.0 11120109 17:42
Iron ug/L ND 50,0 11/20/09 17:42
Lead ug/L ND 5.0 11120109 17:42
Nickel ug/L ND 5.0 11/20/09 17:42
Thallium ug/L ND 10.0 11120109 17:42
Zinc ug/L ND 10.0 11/20/09 17:42
LABORATORY CONTROL SAMPLE: 368871
Spike LCS LCS % Rec
Parameter Units Cone. Result %Rec Limits Qualifiers
Aluminum ug/L 5000 4860 97 80-120
Antimony ug/L 500 491 98 80-120
Arsenic ug/L 500 473 95 80-120
Beryllium ug/L 500 485 97 80-120
Chromium ug/L 500 483 97 80-120
Copper ug/L 500 473 95 80-120
Iron ug/L 5000 4970 99 80-120
Lead ug/L 500 475 95 80-120
Nickel ug/L 500 482 96 80-120
Thallium ugfl 500 454 91 80-120
Zinc ug!L 500 485 97 80-120
MATRIX SPIKE SAMPLE: 368872
9257850001 Spike MS MS % Rec
Parameter Units Result Cone. Result %Rec Limits Qualifiers
Aluminum ug!L 5170 5000 10900 114 75-125
Antimony ug/L ND 500 494 99 75-125
Arsenic ug!L 2.7J 500 481 96 75-125
Beryllium ug/L 0.36J 500 489 98 75-125
Chromium ug!L 4.4J 500 487 97 75-125
Copper ug/L 19.7 500 496 95 75-125
Iron ug/L 6290 5000 10900 93 75-125
Lead ug/L 7.8 500 476 94 75-125
Nickel ug/L 2.5J 500 481 96 75-125
Thallium ug/L ND 500 451 90 75-125
Date: 12/08/2009 04:23 PM REPORT OF LABORATORY ANALYSIS Page 20 of 32
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
i?{"'~,. 11oelao;
Project CASTLE HAYNE 22-124930
Pace Project No.: 9257759
MATRIX SPIKE SAMPLE: 368872
Pace Analytical Services, Inc.
2225 Riverside Dr.
QUALITY CONTROL DATA
Asheville, NC 28804
[phone]
Parameter Units .
9257850001
Result
Spike
Cone.
MS
Result
MS
%Rec
Zinc ug/L
SAMPLE DUPLICATE: 368873
Parameter Units
Aluminum ug/L
Antimony ug/L
Arsenic ug/L
Beryllium u9/L
Chromium ug/L
Copper ug/L
Iron ug/L
Lead ug/L
Nickel ug/L
Thallium ug/L
Zinc ug/L
Date: 12/08/2009 04:23 PM
15.8 500 497
9257850002 Dup
Result Result RPO
8970 8880
ND ND
3.1J 3.2J
0.30J .31J
6.6 6.6
13.9 13.5
9750 9550
20.4 20.2
5.2 5.7
ND ND
311 306
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc .. _.}'ti¾-. i10e1<1C1;
96
Qualifiers
3
2
11
2
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704}875-9092
%Rec
Limits
75-125
Qualifiers
Page 21 of 32
Project: CASTLE HAYNE 22-12493D
Pace Project No.: 9257759
QC Batch: MSSV/1372
QC Batch Method: EPA 8270
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Analysis Method: EPA8270
Analysis Description: 8270 Water MSSV
Associated Lab Samples: 9257759001, 9257759002, 9257759003,9257759004
METHOD BLANK: 20724 Matrix: Water
Associated Lab Samples: 9257759001,9257759002,9257759003,9257759004
Blank Reporting
Parameter Units" Result Limit Analyzed Qualifiers
1,2,4-Trichlorobenzene ug/L ND 5.0 12/01/09 18:39
1,2-Dichlorobenzene ug!L ND 5.0 12/01/09 18:39
1,2-Diphenylhydrazine ug/L ND 5.0 12/01/09 18:39
1,3-Dichlorobenzene ug/L ND 5.0 12/01/09 18:39
1,4-Dichtorobenzene ug/L ND 5.0 12/01/09 18:39
1-Methylnaphthalene ug/L ND 5.0 12/01/0918:39
2, 4, 5-T rich lorophenol ug/L ND 4.0 12/01/09 18:39
2,4,6-Trichlorophenol ug/L ND 2.0 12/01/09 18:39
2,4-Dichlorophenol ug/L ND 2.0 12/01/09 18:39
2,4-Dimethylphenol ug/L ND 5.0 12/01/09 18:39
2,4-Dinitrophenol ug/L ND 20.0 12/01/09 18:39
2,4-Dinitrotoluene ug/L ND 2.0 12/01/0918:39
2,6-Dinitrotoluene ug/L ND 2.0 12/01/09 18:39
2-Chloronaphthalene ug/L ND 5.0 12/01/09 18:39
2-Chtorophenol ug/L ND 5.0 12/01/09 18:39
2-Methylnaphthalene ug/L ND 5.0 12/01/09 18:39
2-Methylphenol(o-Cresol) ug/L ND 5.0 12/01/09 18:39
2-Nltroaniline ug/L ND 5.0 12/01/0918:39
2-Nitrophenol ug/L ND 5.0 12/01/09 18:39
3&4-Methylphenol(m&p Cresol) ug/L ND 10.0 12/01/09 18:39
3,3'-Dichlorobenzidine ug/L ND 10.0 12/01/09 18:39
3-Nitroaniline ug/L ND 5.0 12/01/09 18:39
4,6-Dinitro-2-methylphenol ug/L ND 20.0 12/01/09 18:39
4-Bromophenylphenyl ether ug/L ND 5.0 12/01/09 18:39
4-Chtoro-3-methylphenol ug/L ND 20.0 12/01/0918:39
4-Chloroaniline ug/L ND 5.0 12/01/0918:39
4-Chlorophenylphenyl ether ug/L ND 5.0 12/01/09 18:39
4-Nitroaniline ug/L ND 4.0 12/01/09 18:39
4-Nitrophenol ug/L ND 20.0 12/01/09 18:39
Acenaphthene ug/L ND 5.0 12/01/09 18:39
Acenaphthylene ug/L ND 5.0 12/01/0918:39
Anthracene ug/L ND 5.0 12/01/09 18:39
Benzo(a)anthracene ug/L ND 5.0 12/01/09 18:39
Benzo(a)pyrene ug/L ND 1.0 12/01/09 18:39
Benzo(b)fluoranthene ug/L ND 2.0 12/01/09 18:39
Benzo(g, h, i)perylene ug/L ND 5.0 12/01/09 18:39
Ben zo( k )fluora nthene ug/L ND 4.0 12/01/09 18:39
bis(2-Chloroethyl) ether ug/L ND 4.0 12/01/09 18:39
bis(2-Chloroisopropyl) ether ug/L ND 5.0 12/01/09 18:39
bis(2-Elhylhexyl)phthalate ug/L ND 5.0 12/01/09 18:39
Butylbenzylphlhalate ug/L ND 5.0 12/01/09 18:39
Chrysene ug/L ND 5.0 12/01/09 18:39
Di-n-butylphthalate ug/L ND 5.0 12/01/09 18:39
Date: 12/08/2009 04:23 PM REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
?~°..;~~ .--7~0-tine C:',
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704 )875-9092
Page 22 of 32
Project: CASTLE HAYNE 22-12493D
Pace Project No.: 9257759
Pace Analytical Services, Inc.
2225 Riverside Dr.
QUALITY CONTROL DATA
Asheville, NC 28804
[phone]
METHOD BLANK: 20724
Associated Lab Samples:
Matrix: Water
9257759001,9257759002,9257759003,9257759004
Blank Reporting
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704 )875-9092
Parameter Units Result Limit Analyzed Qualifiers
Di-n-octylphthalate
Dibenz(a,h)anthracene
Dibenzofuran
Diethylphthalate
Dimethylphthalate
Fluoranthene
Fluorene
Hexachloro-1,3-butadiene
Hexachlorobenzene
Hexachlorocyclopentadiefle
Hexachloroethane
lndeno(1,2,3-cd)pyrene
lsophorone
N-Nitroso-di-n-propylamine
N-Nitrosodimethytamine
N-Nitrosodiphenylamine
Naphthalene
Nitrobenzene
Pentachlorophenol
Phenanthrene
Phenol
Pyrene
2,4,6-Tribromophenol ($)
2-Fluorobiphenyl (S)
2-Fluorophenol (S)
Nitrobenzene-dS (S)
Phenol--d6 (S)
Terphenyl-d14 (S)
LABORATORY CONTROL SAMPLE:
Parameter
1,2,4-Trichtorobenzene
1,2-Dichlorobenzene
1,2-Diphenylhydrazine
1,3-Dichlorobenzene
1,4-Dichlorobenzene
1-Methylnaphthalene
2,4,5-Trichlorophenol
2 ,4. 6-T rich lorop henol
2,4-Dichlorophenol
2,4-Dimethylphenol
2,4-Dinitrophenol
2,4-Dinitroto!uene
2,6-Dinitrotoluene
Date: 12/08/2009 04:23 PM
ug/L
ug/L
ug/_L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%
%
%
%
%
%
20725
Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ND 5.0 12101/0918:39
NO 2.0 12/01/09 18:39
NO 5.0 12101/09 18:39
ND 5.0 12101/09 18:39
NO 5.0 12101/0918:39
ND 5.0 12/01/09 18:39
NO 5.0 12101/09 18:39
ND 2.0 12101/09 18:39
NO 1.0 12/01/09 18:39
ND 5.0 12/01/09 18:39
NO 5.0 12/01/09 18:39
ND 2.0 12/01/09 18:39
ND 5.0 12/01/09 18:39
NO 4.0 12101/09 18:39
ND 2.0 12101/09 18:39
NO 5.0 12/01/0918:39
ND 5.0 12/01/09 18:39
NO 4.0 12101/09 18:39
ND 20.0 12101/09 18:39
NO 5.0 12/01/0918:39
ND 5.0 12/01/0918:39
NO 5.0 12101/0918:39
67 10-110 12/01/09 18:39
70 18-110 12101/09 18:39
36 18-110 12101/09 18:39
66 10-110 12/01/09 18:39
27 10-110 12/01/09 18:39
89 10-123 12101/0918:39
Spike LCS LCS %Rec
Cone. Result %Rec Limits
50 39.5 79 39.9-89.2
50 34.2 68 34.6-90.5
50 35.8 72 49.3-114.4
50 35.2 70 33.5-89.2
50 35.7 71 40.1-84.5
50 39.4 79 28.7-112.9
50 47.0 94 51.1-111.7
50 44.5 89 40.6-113.7
50 41.1 82 46.1-100.4
50 36.4 73 43-103.2
50 43.4 87 10-131.1
50 50.1 100 62.4-110.1
50 47.9 96 61.5-106.3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
Qualifiers
Page 23 of 32
Project: CASTLE HAYNE 22-12493D
Pace Project No.: 9257759
LABORATORY CONTROL SAMPLE: 20725
Parameter Units
2-Chloronaphthalene ug/L
2-Chlorophenol ug/L
2-Methylnaphthalene ug/L
2-Methylphenol(o-Cresol) ug/L
2-Nitroaniline ug/L
2-Nitrophenol ug/L
3&4-Methylphenol(m&p Cresci) ug/L
3,3'-Dichlorobenzidine ug/L
3-Nitroaniline ug/L
4,6-Dinitro-2-methylphenol ug/L
4-Bromophenylphenyl ether ug/L
4-Chloro-3-methylphenol ug/L
4-Chloroaniline ug/L
4-Chlorophenylphenyl ether ug/L
4-Nitroaniline ug/L
4-Nitrophenol ug/L
Acenaphthene ug/L
Acenaphthylene ug/L
Anthracene ug/L
Berizo(a)anthracene ug/L
Benzo(a)pyrene ug/L
Benzo(b)fluoranthene ug/L
Benzo(g, h, i )perylene ug/L
Benzo(k)fluoranthene ug/L
bis(2-Chloroethyl) ether ug/L
bis(2-Chloroisopropyl) ether ug/L
bis{2-Ethylhexyl)phthalate ug/L
Butylbenzylphthalate ug/L
Chrysene ug/L
Di-n-butylphtha1ate ug/L
Di-n-octylphthatate ug/L
Dibenz(a,h)anthracene ug/L
Dibenzofuran ug/L
Diethylphthalate ug/L
Dimethylphlhatate ug/L
Fluoranthene ug/L
Fluorene ug/L
Hexachloro-1,3-butadiene ug/L
Hexachlorobenzene ugtl
Hexachlorocyclopentadiene ug/L
Hexachloroethane ug/L
lndeno(1,2,3-cd)pyrene ug/L
lsophorone ug/L
N-Nitroso-di-n-propylamine ug/L
N-Nitrosodimethylamine ug/L
N-Nitrosodiphenylamine ug/L
Naphthalene ug/L
Nitrobenzene ug/L
Date: 12/08/2009 04:23 PM
Pace Analytical So,vices, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Spike LCS LCS %Rec
Cone. Result %Rec Limits
50 37.4 75 44.4-97.8
50 33.8 68 36.3-94.9
50 39.6 79 24.4-123.8
50 34.2 68 38.1-94.5
50 42.4 85 60.2-107.2
50 41.2 82 41.8-100.6
50 33.9 68 37.8-93.5
50 43.1 86 35.6-111.3
50 36.4 73 36.7-122.3
50 48.8 98 18.5-129.6
50 44.9 90 57.6-107.6
50 41.1 82 53.9-107.8
50 38.7 77 49.5-97.9
50 44.4 89 55.8-97.6
50 42.7 85 53.1-109.4
50 17.3J 35 10-88.9
50 40.6 81 58.1-93.8
50 37.9 76 53.2-99.3
50 44.2 88 43.9-117.6
50 43.1 86 56.9-102
50 47.0 94 66.5-106.2
50 46.7 93 66.5-103.3
50 43.6 87 65.1-108
50 47.6 95 64.2-105.2
50 33.2 66 38.4-99
50 32.5 65 36.8-95.3
50 44.1 88 59.1-109.3
50 42.1 84 54.4-107.2
50 44.1 88 54.2-103.6
50 42.5 85 66.5-108.2
50 46.0 92 48.4-114
50 43.9 88 60.1-112.6
50 41.0 82 55.1-97.3
50 42.5 85 64.3-105.1
50 44.4 89 62.5-103.6
50 45.0 90 52.9-116.1
50 41.9 84 60.3-97.3
50 41.3 83 34.3-96.9
50 42.7 85 55.7-112.1
50 34.9 70 26.4-83.9
50 32.8 66 35-87.6
50 44.3 89 66.1-107.8
50 38.2 76 44.1-108.3
50 40.6 81 12.4-127.6
50 18.0 36 11.3-84.9
50 43.9 88 19.3-136.6
50 38.1 76 30-95.4
50 33.7 67 27.8-109
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
~-Pf·~~~ tlnelac;,
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Qualifiers
Page 24 of 32
Project: CASTLE HAYNE 22-124930
Pace Project No.: 9257759
LABORATORY CONTROL SAMPLE: 20725
Parameter Units
Pentachlorophenol ug/L
Phenanthrene ug/L
Phenol ug/L
Pyrene ug/L
2,4,6-Tribromophenol (S) %
2-Fluorobiphenyl (S) %
2-Fluorophenol (S) %
Nitrobenzene-dS (S) %
Phenol-d6 (S) %
Terphenyl-d14 (S) %
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 20726
9257577001
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Spike LCS LCS % Rec
Cone. Result %Rec Limits
50 42.3 85 10-159
50 43.6 87 19.9-138.2
50 16.5 33 10-74.6
50 44.4 89 18-134.1
82 10-110
76 18-110
45 18-110
67 10-110
31 10-110
90 10-123
20727
MS MSD
Spike Spike MS MSD MS MSD
Paco Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Qualifiers
%Rec
Parameter Units Result Cone. Cone. Result Result %Rec %Rec Limits RPD Qual
1,2,4-Trichlorobenzene ug/L ND 52.1 50 32.1 31.2 62 62 39.9-89. 3
1,2-Dichlorobenzene ug/L ND 52.1 50 28.8 26.5 55 53 34.6-90. 8
1,2-Diphenylhydrazine ug/L ND 52.1 50 32.6 30.6 63 61 49.3-114 6
1,3-Dichlorobenzene ug/L ND 52.1 50 28.2 27.1 54 54 33.5-89. 4
1,4-Dichlorobenzene ug/L ND 52.1 50 28.1 26.6 54 53 40.1-84. 6
1-Methylnaphthalene ug/L ND 52.1 50 33.4 31.1 64 62 28.7-112 7
2,4,5-Trichlorophenol ug/L ND 52.1 50 40.3 36.7 77 73 51.1-111 9
2,4,6-Trichlorophenol ug/L ND 52.1 50 41.4 37.1 80 74 40.6-113 11
2,4-Dichlorophenol ug/L ND 52.1 50 34.8 32.7 67 65 46.1-100 6
2,4-Dimethylphenol ug/L ND 52.1 50 25.9 28.5 50 57 43-103.2 10
2,4-Dinitrophenol ug/L ND 52.1 50 40.2 38.1 77 76 10-131.1 5
2,4-Dinitrotoluene ug/L ND 52.1 so 44.3 43.0 85 86 62.4-110 3
2,6-Dinitrotoluene ug/L ND 52.1 50 42.4 38.9 81 78 61.5-106 9
2-Chloronaphthalene ug/L ND 52.1 50 33.5 29.8 64 60 44.4-97. 11
2-Chlorophenol ug/L ND 52.1 50 30.2 28.9 58 58 36.3-94. 4
2-Methylnaphthalene ug/L ND 52.1 50 32.8 31.0 63 62 24.4-123 6
2-Methylphenol{o-Cresol) ug/L ND 52.1 50 30.0 28.2 58 56 38.1-94. 6
2-Nitroaniline ug/L ND 52.1 50 36.7 34.8 70 70 60.2-107 5
2-Nitrophenol ug/L ND 52.1 50 32.3 32.0 62 64 41.8-100 .9
3&4-Methylphenol(m&p ug/L ND 52.1 so 35.6 31.2 68 62 37.8-93. 13
Cresol)
3,3'-Dichlorobenzidine ug/L ND 52.1 50 35.6 41.9 68 84 35.6-111 16
3-Nitroaniline ug/L ND 52.1 50 22.6 30.6 43 61 36.7-122 30
4,6-Dinilro-2-methylphenol ug/L ND 52.1 50 46.0 42.6 88 85 18.5-129 8
4-Bromophenylphenyl ether ug/L ND 52.1 50 40.6 38.0 78 76 57.6-107 7
4-Chloro-3-melhylphenol ug/L ND 52.1 50 33.6 34.9 65 70 53.9-107 4
4-Chloroaniline ug/L ND 52.1 50 4.2J 27.1 8 54 49.5-97. MO
4-Chlorophenylphenyl ether ug/L ND 52.1 50 39.6 35.8 76 72 55.8-97. 10
4-Nitroaniline ug/L ND 52.1 50 37.4 37.8 72 76 53.1-109 1
4-Nitrophenol ug/L ND 52.1 50 34.0 31.5 65 63 10-88.9 8
Acenaphthene ug/L ND 52.1 50 36.4 32.4 70 65 58.1-93. 12
Acenaphthylene u9/l ND 52.1 50 33.3 31.9 64 64 53.2-99. 4
Date: 12/08/2009 04:23 PM REPORT OF LABORATORY ANALYSIS Page 25 of 32
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc,.
~,,,/<;f-'·"~ .... ;,nelac11
P·~· Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: CASTLE HAYNE 22-12493D
Pace Project No.: 9257759
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 20726 20727
MS MSD
9257577001 Spike Spike MS MSD MS
Parameter Units
Anthracene ug/L
Benzo(a)anthracene ug/L
Benzo(a)pyrene ug/L
Benzo(b )fluoranthene ug/L
Benzo(g,h,i)perylene ug/L
Benzo(k)fluoranthene ug/L
bis(2-Chloroethyl) ether ug/L
bis(2-Chloroisopropyl) ether ug/L
bis(2-Ethylhexyl)phthalate ug/L
Butylbenzylphthalate ug/L
Chrysene ug/L
Di-n-butylphthalate ug/L
Di-n-octylphthalate ug/L
D ibenz( a, h )a nth racene ug/L
Dibenzofuran ug/L
Diethylphthalate ug/L
Dimethylphthalate ug/L
Fluoranthene ug/L
Fluorene ug/L
Hexachloro-1,3-butadiene ug/L
Hexachlorobenzene ug/L
Hexachlorocyclopentadiene ug/L
Hexachloroethane ug/L
lndeno( 1,2,3-cd)pyrene ug/L
lsophorone ug/L
N-Nitroso-di-n-propylamine ug/L
N-Nitrosodimethylamine ug/L
N-Nitrosodiphenylamine ug/l
Naphthalene ug/L
Nitrobenzene ug/L
Pentachlorophenol ug/L
Phenanthrene ug/L
Phenol ug/L
Pyrene ug/L
2,4,6-Tribromophenol (S) %
2-Fluorobiphenyl ($) %
2-Fluorophenol ($) %
Nitrobenzene-d5 (S) %
Phenol-dB (S) %
Terphenyl-d14 (S) %
Date: 12/08/2009 04:23 PM
Result Cone. Cone. Result Result %Rec
ND 52.1 50 41.6 36.6
ND 52.1 50 42.0 40.9
ND 52.1 50 43.5 44.5
ND 52.1 50 42.8 42.1
ND 52.1 50 41.6 41.0
ND 52.1 50 44.4 44.6
ND 52.1 50 26.6 24.5
ND 52.1 50, 26.3 26.7
ND 52.1 50 42.3 42.1
ND 52.1 50 41.3 41.0
ND 52.1 50 43.4 42.2
ND 52.1 50 41.5 39.4
ND 52.1 50 44.7 42.9
ND 52.1 50 41.9 41.9
ND 52.1 50 37.3 34.9
ND 52.1 50 40.0 38.7
ND 52.1 50 39.2 38.0
ND 52.1 50 42.9 41.3
ND 52.1 50 36.5 34.7
ND 52.1 50 34.B 32.5
ND 52.1 50 39.0 35.7
ND 52.1 50 29.9 27.0
ND 52.1 50 26.7 26.5
ND 52.1 50 42.5 41.6
ND 52.1 50 31.2 30.0
ND 52.1 50 33.5 30.8
ND 52.1 50 18.4 17.2
ND 52.1 50 40.4 37.3
ND 52.1 50 31.2 29.7
ND 52.1 50 28.2 27.3
ND 52.1 50 40.6 39.3
ND 52.1 50 40.3 38.2
ND 52.1 50 25.8 22.6
ND 52.1 50 45.0 42.9
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, lnc ..
80
81
83
82
80
85
51
50
81
79
83
80
86
81
72
77
75
82
70
67
75
57
51
82
60
64
35
78
60
54
78
77
50
86
66
62
47
56
51
82
Paco Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704 )875-9092
MSD %Rec
%Rec Limits RPO Qual -----
73 43.9-117 13
82 56.9-102 3
89 66.5-106 2
84 66.5-103 2
82 65.1-108
89 64.2-105 .4
49 38.4-99 8
53 36.8-95. 1
84 59.1-109 .3
82 54.4-107 .8
84 54.2-103 3
79 66.5-108 5
86 48.4-114 4
84 60.1-112 .008
70 55.1-97. 7
77 64.3-105 3
76 62.5-103 3
83 52.9-116 4
69 60.3-97. 5
65 34.3-96. 7
71 55.7-112 9
54 26.4-83. 10
53 35-87.6 .7
83 66.1-107 2
60 44.1-108 4
62 12.4-127 9
34 11.3-84. 7
75 19.3-136 8
59 30-95.4 5
55 27.8-109 3
79 10-159 3
76 19.9-138 5
45 10-74.6 13
86 18-134.1 5
70 10-110
59 18-110
48 18-110
57 10-110
45 10-110
86 10-123
Page 26 of 32
Project: CASTLE HAYNE 22-12493D
Pace Project No.: 9257759
QC Batch: MSV/9129
QC Batch Method: EPA 8260
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Analysis Method: EPA 8260
Analysis Description: 8260 MSV Low Level
Associated Lab Samptes: 9257759001, 9257759002, 9257759003,9257759004
METHOD BLANK: 370472 Matrix: Water
Associated Lab Samples: 9257759001,9257759002,9257759003, 9257759004
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
1, 1, 1,2-Tetrachloroethane ug/L ND 1,0 11126109 22:47
1, 1, 1-Trichloroethane ug/L ND 1,0 11126109 22:47
1, 1,2,2-Tetrachloroethane ug/L ND 1,0 11126109 22:47
1, 1,2-Trichloroethane ug/L ND 1.0 11126109 22:47
1, 1-Dichloroethane ug/L ND 1.0 11126109 22:47
1, 1-Dichloroethene ug/L ND 1.0 11126109 22:47
1, 1-Dichloropropene ug/L ND 1.0 11/26/09 22:47
1,2,3-Trichlorobenzene ug/L ND 1.0 11126109 22:47
1,2,3-Trichloropropane ug/L ND 1,0 11126109 22:47
1,2,4-Trichlorobenzene ug/L ND 1.0 11/26/09 22:47
1,2-Dibromo-3-chloropropane ug/L ND 3.0 11/26/09 22:47
1,2-Dibromoethane (EDS) ug/L ND 1.0 11/26/09 22:47
1,2-Dichtorobenzene ug/L ND 1.0 11126109 22:47
1,2-Dichloroethane ug/L ND 1.0 11126109 22:47
1,2-Dichloropropane ug/L ND 1,0 11/26/09 22:47
1,3-Oichlorobenzene ug/L ND 1.0 11126109 22:47
1,3-Dichloropropane ug/L ND 1.0 11126109 22:47
1,4-Dichlorobenzene ug/L ND 1,0 11/26/09 22:47
2,2-Dichloropropane ug/L ND 1,0 11126109 22:47
2-Butanone (MEK) ug/L ND 5.0 11/26/09 22:47
2-Chlorotoluene ug/L ND 1.0 11126109 22:47
2-Hexanone ug/L ND 5,0 11126109 22:47
4-Chlorotoluene ug/L ND 1.0 11126109 22:47
4-Methyl-2-pentanone_ (MIBK) ug/L ND 5,0 11/26/09 22:47
Acetone ug/L ND 25.0 11126109 22:47
Benzene ug/L ND 1,0 11/26/09 22:47
Bromobenzene ug/L ND 1.0 11/26/09 22:47
Bromochloromethane ug/L ND 1.0 11126109 22:47
Bromodichloromethane ug/L ND 1.0 11/26/09 22:47
Bromoform ug/L ND 1.0 11/26/09 22:47
Bromomethane ug/L ND 5.0 11126109 22:47
Carbon tetrachloride ug/L ND 1.0 11/26/09 22:47
Chlorobenzene ug/L ND 1.0 11/26/09 22:47
Chloroethane ug/L ND 1.0 11/26/09 22:47
Chloroform ug/L ND 1.0 11/26/09 22:47
Chloromethane ug/L ND 1,0 11/26/09 22:47
cis-1,2-Dichloroethene ug/L ND 1.0 11126109 22:47
cis-1,3-Dichloropropene ug/L ND 1.0 11/26/09 22:47
Dibromochloromethane ug/L ND 1.0 11 /26/09 22:4 7
Dibromomethane ug/L ND 1.0 11/26/09 22:47
Dichlorodifluoromethane ug/L ND 1.0 11/26/09 22:47
Diisopropyl ether ug/L ND 1.0 11126109 22:47
Ethylbenzene ug/L ND 1,0 11/26/09 22:47
Dale: 12/08/2009 04:23 PM REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
,., •<co~
iHelj:~;;
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704}875-9092
Page 27 of 32
Paco Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: CASTLE HAYNE 22-12493D
Pace Project No.: 9257759
METHOD BLANK: 370472 Matrix: Water
Associated Lab Samples: 9257759001, 9257759002, 9257759003, 9257759004
Blank Reporting
Paco Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Parameter Units Result Limit Analyzed Qualifiers
Hexachloro-1,3-butadiene ug/L ND 1.0 11126109 22:47
m&p-Xylene ug/L ND 2.0 11/26109 22:47
Methyl-tert-butyl ether ug/L ND 1.0 11126109 22:47
Methylene Chloride ug/L ND 2.0 11126109 22:47
Naphthalene ug/L ND 1.0 11126109 22:47
a-Xylene ug/L ND 1.0 11126109 22:47
p-tsopropyltoluene ug/L ND 1.0 11126109 22:47
Styrene ug/L ND 1.0 11/26/09 22:47
Tetrachloroethene ug/L ND 1.0 11126109 22:47
Toluene ug/L ND 1.0 11126109 22:47
trans-1,2-Dichloroethene ug/L ND 1.0 11126109 22:47
trans-1,3-Dichloropropene ug/L ND 1.0 11126109 22:47
Trichloroethene ug/L ND 1.0 11/26109 22:47
T richlorofluoromethane ug/L ND 1.0 11/26109 22:47
Vinyl acetate ug/L ND 2.0 11126109 22:47
Vinyl chloride ug/L ND 1.0 11126109 22:47
1,2-Dichloroethane-d4 (S) % 98 79-120 11126109 22:47
4-Bromofluorobenzene (S) % 98 87-109 11/26/09 22:47
Dibromofluoromethane (S) % 99 85-115 11126109 22:47
Toluene-dB (S) % 101 70-120 11126109 22:47
LABORATORY CONTROL SAMPLE: 370473
Spike LCS LCS %Rec
Parameter Units Cone. Result %Rec Limits Qualifiers
1, 1, 1,2-Tetrachloroethane ug/L 50 58.7 117 83-125
1, 1, 1-Trichloroethane ug/L 50 55.9 112 80-129
1, 1,2,2-Tetrachloroethane ug/L 50 54.4 109 73-127
1, 1,2-Trichloroethane ug/L 50 57.9 116 77-123
1, 1-Dichloroethane ug/L 50 56.7 113 76-129
1, 1-Dichloroethene ug/L 50 58.0 116 78-146
1, 1-Dichloropropene ug/L 50 61.4 123 79-134
1,2,3-Trichlorobenzene ug/L 50 56.6 113 70-150
1,2,3-Trlchloropropane ug/L 50 53.0 106 72-125
1,2,4-Trichlorobenzene ug/L 50 56.0 112 68-127
1,2-Dibromo-3-chloropropane ug/L 50 52.1 104 65-128
1,2-Dibromoethane (EDB) ug/L 50 57.7· 115 81-125
1,2-Dichlorobenzene ug/L 50 55.6 111 82-126
1,2-Dich!oroethane ug/L 50 56.4 113 72-126
1,2-Dichloropropane ug/L 50 59.5 119 80-127
1,3-Dichlorobenzene ug/L 50 54.3 109 82-124
1,3-Dichloropropane ug/L 50 55.2 110 79-124
1,4-Dichlorobenzene ug/L 50 53.8 108 79-125
2,2-Dichloropropane ug/L 50 52.4 105 58-140
2-Butanone (MEK) ug/L 100 117 117 50-134
2-Chlorotoluene ug/L 50 53.1 106 81-126
Date: 12/08/2009 04:23 PM REPORT OF LABORATORY ANALYSIS Page 28 of 32
This report shall not be reproduced, except in lull,
without the written consent of Pace Analytical Services, Inc,.
~~«-~~~ F1□elac\;
Project: CASTLE HAYNE 22-12493D
Pace Project No.: 9257759
LABORATORY CONTROL SAMPLE: 370473
Parameter Units
2-Hexanone ug/L
4-Chlorotoluene ug/L
4-Methyl-2-pentanone (MIBK) ug/L
Acetone ug/L
Benzene ug/L
Bromobenzene ug/L
Bromochloromethane ug/L
Bromodichloromethane ug/L
Bromoform ug/L
Bromomethane ug/L
Carbon tetrachloride ug/L
Chlorobenzene ug/L
Chloroethane ug/L
Chloroform ug/L
Chloromethane ug/L
cis-1,2-Dichloroethene ug/L
cis-1,3-Dichloropropene ug/L
Dibromochloromethane ug/L
Dibromomethane ug/L
Dichlorodifluoromethane ug/L
Diisopropyl ether ug/L
Ethylbenzene ug/L
Hexachloro-1,3-butadiene ug/L
m&p-Xylene ug/L
Methyl-tert-butyl ether ug/L
Methylene Chloride ug/L
Naphthalene ug/L
a-Xylene ug/L
p-lsopropyltoluene ug/L
Styrene ug/L
Tetrachloroethene ug/L
Toluene ug/L
trans-1,2-Dichloroethene ug/L
trans-1,3-Dichloropropene ug/L
Trichtoroethene ug/L
Trich\orofluoromethane ug/L
Vinyl acetate ug/L
Vinyl chloride ug/L
1,2-Dichloroethane-d4 (S) %
4-Bromofluorobenzene (S) %
Dibromofluoromethane (S) %
Toluene-dB (S) %
Date; 12/08/2009 04:23 PM
Pace Analytical Services, lnc.
2225 Riverside Dr.
Asheville, NC 28804
{828)254-7176
QUALITY CONTROL DATA
Spike LCS LCS
Cone. Result % Rec
100 103 103
50 56.5 113
100 108 108
100 94.1 94
50 55.6 111
50 54.2 108
50 56.5 113
50 54.3 109
50 48.6 97
50 66.8 134
50 54.8 110
50 54.1 108
50 53.3 107
50 56.1 112
50 49.8 100
50 57.5 115
50 54.4 109
50 49.0 98
50 58.7 117
50 36.0 72
50 56.9 114
50 55.1 1,10
50 52.6 105
100 114 114
50 49.9 100
50 56.6 113
50 49.2 98
50 55.6 111
50 56.6 113
50 57.3 115
50 52.5 105
50 55.8 112
50 54.8 110
50 60.1 120
50 57.8 116
50 49.5 99
100 109 109
50 50.1 100
96
99
101
100
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
%Rec
Limits
58-138
82-126
70-131
50-146
78-128
81-127
73-124
81-125
71-125
50-150
81-137
82-126
69-140
77-129
54-139
76-133
76-127
77-125
77-125
50-150
74-131
80-127
78-145
82-127
71-130
67-133
52-136
83-124
73-122
80-130
78-128
76-126
78-134
75-125
79-127
76-148
50-150
67-143
79-120
87-109
85-115
70-120
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Qualifiers
Page 29 of 32
Project: CASTLE HAYNE 22-12493D
Pace Project No.: 9257759
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 370616
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
370617
MS MSD
9257759002 Spike Spike MS MSD MS
Parameter Units
1, 1-Dichloroethene ug/L
Benzene ug/L
Chlorobenzene ug/L
Toluene ug/L
Trichloroethene ug/L
1,2-Dichloroethane-d4 (S) %
4-Bromoftuorobenzene (S) %
Dibromoftuoromethane (S) %
Toluene-dB (S) %
Date: 12/08/2009 04:23 PM
Result Cone. Cone. Result Result %Rec
NO 100 100 134 130
ND 100 100 121 119
NO 100 100 119 116
ND 100 100 119 118
ND 100 100 125 122
;
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
_.,;;" '/:,"""'--,'10eld.e,;
134
121
119
119
125
94
97
97
99
MSD
% Rec
130
119
116
118
122
91
96
93
98
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
%Rec
Limits RPO Oual -----
60-150 3
74-136 2
79-135 3
73-131 1
73-131 2
79-120
87-109
85-115
70-120
Page 30 of 32
QUALIFIERS
Project: CASTLE HAYNE 22-124930
Pace Project No.: 9257759
DEFINITIONS
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Paco Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704 }875-9092
OF -Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of
the sample aliquot, or moisture content.
ND -Not Detected at or above adjusted reporting limit.
J -Estimated concentration above the adjusted method detection limit and below the adjusted r~porting limit.
MDL -Adjusted Method Detection Limit.
S -Surrogate
1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate% recovery and RPO values.
LCS(D) -Laboratory Control Sample (Duplicate)
MS(D) -Matrix Spike (Duplicate)
DUP -Sample Duplicate
RPO -Relative Percent Difference
NC -Not Calculable.
Pace Analytical is NELAP accredited. Contact your Pace PM for the current list of accredited analytes.
U -Indicates the compound was analyzed for, but not detected.
LABORATORIES
PASI-A
PASI-C
PASl-0
Pace Analytical Seivices -Asheville
Pace Analytical Seivices -Charlotte
Pace Analytical Seivices -Ormond Beach
ANALYTE QUALIFIERS
MO Matrix spike recovery and/or matrix spike duplicate recovery was outside iaboratory control limits.
Date: 12/08/2009 04:23 PM REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
,~Ye-if~ .• ,•1/' l::.C ~--f1□eld.C\o
Page 31 of 32
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville. NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704 )875-9092
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: CASTLE HAYNE 22-12493D
Pace Project No.: 9257759
Lab ID Sample ID
9257759001 TMW-1W
9257759002 TMW-2W
9257759003 TMW-3W
9257759004 TMW-4W
9257759001 TMW-1W
9257759002 TMW-2W
9257759003 TMW-3W
9257759004 TMW-4W
9257759001 TMW-1W
9257759002 TMW-2W
9257759003 TMW-3W
9257759004 TMW-4W
Date: 12/08/2009 04:23 PM
QC Batch Method QC Batch
EPA 3010 MPRP/5416
EPA 3010 MPRP/5416
EPA3010 MPRP/5416
EPA 3010 MPRP/5416
EPA8270 MSSV/1372
EPA8270 MSSV/1372
EPA 8270 MSSV/1372
EPA 8270 MSSV/1372
EPA 8260 MSV/9129
EPA8260 MSV/9129
EPA8260 MSV/9129
EPA 8260 MSV/9129
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc .. . -«~--;'1□eldC\',
Analytical
Analytical Method Batch
EPA6010 ICP/5022
EPA 6010 ICP/5022
EPA6010 ICP/5022
EPA6010 ICP/5022
EPA8270 MSSV/1135
EPA 8270 MSSV/1135
EPA 8270 MSSV/1135
EPA 8270 MSSV/1135
Page 32 of 32
ace Analytical'"
www.pacelabs.com
Report Prepared for:
Ashley Nifong
PAS! Charlotte
9800 Kincey Ave.
Huntersville NC 28078
REPORT OF
LABORATORY
ANALYSIS FOR
TCDD
Report Prepared Date:
December 7, 2009
Report No ..... 10117532_ 1613
Pace Analytical Services, Inc.
1700 Elm Street
Minneapolis. MN 55414
Phone: [phone]
Fax: [phone]
Report Information:
Pace Project#: 10117532
Sample Receipt Date: 11/19/2009
Client Project#: 9257759 ECS
Client Sub PO#: N/A
State Cert #: 27700
Invoicing & Reporting Options:
The report provided has been invoiced as a Level 2
2,3,7,8-TCDD Report. I fan upgrade of this report
package is requested, an additional charge may he
applied.
Please review the attached invoice for accuracy and
forward any questions to Scott Unze, your Pace
Project Manager.
This report has been reviewed by:
fr lt-y
December 08, 2009
Scott Unzc, Project Manager
[phone]
[phone] (fax)
[e-mail]
Report of Laboratory Analysis
This report should not be reproduced, except in full,
without the written consent of Pace Analytic.ii Services, Inc.
The results relate only to the samples included in this report.
Page 1 of 16
DISCUSSION
Pace Analytical Services, Inc.
1700 Elm Street
Minneapolis, MN 55414
Phone: [phone]
Fax: [phone]
This report presents the results from the analyses performed on four samples submitted by a
representative of PASl Charlotte. The samples were analyzed for the presence or absence of
2,3,7,8-tetrachlorodibenzo-p-dioxin (2,3,7,8-TCDD) using a modified version of USEPA Method 1613B.
The reporting limits were set to correspond to the lowest calibration point and a nominal 1-Liter sample
amount.
The recoveries of the isotopically-labeled TCDD internal standard in the sample extracts ranged from
88-92%. All of the labeled standard recoveries obtained for this project were within the target ranges
specified in Method 1613B. Also, since the quantification of the native TCDD was based on isotope
dilution, the data were automatically corrected for recovery and accurate values were obtained.
A laboratory method blank was prepared and analyzed with the sample batch as part of our routine quality
control procedures. The results show that 2,3,7,8-TCDD was not detected, indicating that the sample
processing steps were free of background levels of this congener.
Laboratory spike samples were also prepared using clean water that had been fortified with native
standard material. The results show that the spiked native TCDD was recovered at 97-99%, with a
relative percent difference of 2.0%. These results indicate high degrees of accuracy and precision for
these determinations. Matrix spikes were not prepared with the sample batch.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Report No ..... 10117532_1613 Page 2 of 16
Authority
Alabama
Alaska
Arizona
Arkansas
California
Colorado
Connecticut
EPA Region 5
EPA Region 8
Florida (NELAP
Georgia (DNR)
Guam
Hawaii
Idaho
Illinois
Indiana
Indiana
Iowa
Kansas
Kentucky
Louisiana
Maine
Maryland
Michigan
Minnesota
Mississippi
™
Minnesota Laboratory Certifications
Certificate # Authority
40770 Montana
MN00064 Nebraska
AZ0014 Nevada
88-0680 New Jersey (NE
01155CA New Mexico
MN00064 New Yorl< (NEL
PH-0256 North Carolina
WD-15J North Dakota
8TMS-Q Ohio
E87605 OhioVAP
959 Oklahoma
08-004r Oregon (ELAP)
SLD Oregon (OREL
MN00064 Pennsylvania
200012 Saipan
South Carolina
C-MN-01 Tennesee
368 Tennessee
E-10167 Texas
90062 Utah (NELAP)
LA0900016 Virginia
2007029 Washington
322 West Virginia
9909 Wisconsin
027-053-137 Wyoming
MN00064
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Report No ..... 10117532_ 1613
Pace Analytical Services, Inc.
1700 Elm Street -Suite 200
Minneapolis, MN 55414
Tel: [phone]
Fax: [phone]
Certificate #
92
MN00064_2000
MN002
MN00064
11647
27700
R-036
4150
CL101
D9922
MN200001-005
MN200001-005
68-00563
MP0003
74003001
2818
02818
T104704192-08
PAM
00251
C755
9952C
999407970
8TMS-Q
Report No ..... 10116940
Page 3 of 16
Appendix A
Sample Management
Report No ..... 10117532_ 1613 Pace Analytical Services, Inc. Page 4 of 16
Chain of Custody
;:ol°'
.gi~ o---:
'.:; Workorder. 9257759 Workorder Name:CASTLE HAYNE 22-124930
Ashley Nifong c Pace Analytical Services, Inc.
-9800 Kincey Ave., Suite 100
:: Huntersville, NC 28078
~ Phone [phone] t Fax [phone]
2 TMW-'ZW
3 TMW-3W
4 TMW-4W
5
Transfers Released By
Pace Analytical Minnesota
1700 Elm Street SE
Suite 200
Minneapolis, MN 55414
Phone [phone]
11/17/200914:15 9257759002 Water
11/17/2009 13:45 9257759003 Water
11/17/2009 09:30 9257759004 Water
Date/Time =teceived By
Cooler Temoerature on Receiot i.ll °C I Custodv Seal Y or /NI
-0 Q)
(Q
(l)
(J1
0 -~
Wednesday, November 18. 200910:58:30 AM
(
J"2eAnalyticaf 0
( _,/1 a1.,1 .--com
' Owner Received Date: 11/18/2009 Results Requested By: 12/1/2009
a
14
c;J
I-
OC> .
c--C') .
N LAB USE ONLY
X
"J_ X
2-X
-:z_ X
Ll 11 I'?
Oatemme
I Received on Ice /yJ or N I Samoles Intact fy) or N
FMT-ALL-C-002rev.00 24March2009 Page 1 of 1
pooAnalytk;8( , s~mple (::onclition Upon Receipt
Client Name: _....:.~.==....i:IY~C:..:-c;..._ __ Project # ___.l .... D .... I \--"'] 2£.,....__.,,____
'
Courier: D Fed Ex D UPS D ,IISPS Q Client D Commer<>lal D Pace Other
Traoklng #: /,51':/-c:5Z/'-1D-/L/oo
Cuotody Seat on Cooter/Box Prennl: D yes p:f no Seals Intact D yes D no
Paoklng Material: D Bubble Wrap ,i'eubble Sage D None D Other ____ Temp Blank: Yee ...:.__ No L
((4i _,) &fa □ Thermometer Used eea ue.S! or 1 429 Type of Ice: · t Blue None Samples on Ice, ooolln~ oroceaa ha, begun
7.L[ Blologloal Tissue la Frozen: voa Date and lnltl~n Cooler Temperature No contents: -////
Temp ehould be above freoz!ng to 6°C Commenta: ' I
Ctialn of Custnrtv Present: rl,y .. □No ONIA 1.
Chaln·of Cuetortv FIiied Out •I] Vea □No □NIA 2.
Chain of cue1nr1v Aellnnulshed:
,
U Yeo □No ON/A 3.
Samoler Name & ""'nature on COC: □Vos ..Go □NIA 4.
Samoles Arrived wffhln Hold Time: OOY•• □No □NIA 5.
Short Hold Time Anatvala l<72hr\: OV08 □No n,(,A 8.
Rlllll Turn Al'ound Ttme : □Voe ru,,, □NIA 7.
SUfflclent Volume: r£ .. /□No □NIA 8.
Corr90! Containers Used: ~BB □No □NIA 9.
-Pace Containers Used: 'ctea □No □NIA
Containers lntaot: lllYoo □No □NIA 10. . □Voe ONo i:lkA FIitered volume received for Dissolved testa 11.
fves □No ,
Sample Labels match COC: □NIA 12.
-Includes date/llme/10/Anatvels Matrix: I ~-rl'
All conlalnera needing acidlbaH prttruvaUon have been □Yea □No ?NIA 13. □ HNOO □ H2S04 0 No0H □ HCI
cheaked. NoncomoUanoe aro noted In 13.
All oontalner• needing .,..,..tvatlon are found to be In rfaA
Sempll
compliance wtth EPA recommendallon. □Yee □No
E>coeptlona: VOA,ColffOffll, TOO, on and araa99, WI-DAO (Water. □Yes r/No lnl~alwhon Lot# of added
oomplotad preHrvatlve
Samoles checked lor dechlorination: □Yea □No "A 14.
Head""""-" In VOA Viale ( >6mm\: ov .. □No ,., .. 15.
Trip Blank Present: ov .. □No 'JA 18.
Trip Blank Custody Seals Present □Voe □No 1,,,tA -Pace Trlo Blank Lot ll Ill ourchased\:
Cllent NotHlcatlon/ Reaolullon:
Pereon Contacted: t,(+v-'¼. Ct. Date/Time: II/ 14 /, 'I
Froid Cata Required? y / N
Comments/Rseoludon: ___________ "---------------------------
Project Manager Review: Date: /' / µ to -f .
Note: Whenever there Is a discrepancy e.ffooUng North Carolina compllance samples, a copy of thta form wm be sent to the~t,linm ~. Inc.
F·L213Rov.OO, 05Aug2009 1700 Elm Slreet SE, SuHo 200, Mlnneapolla, MN 55414
Report No ..... 10117532_ 1613 Page 6 of 16
ace Analvtical™
Reporting Flags
A = Reporting Limit based on signal to noise
B = Less than 1 Ox higher than method blank level
C = Result obtained from confirmation analysis
D = Result obtained from analysis of diluted sample
E = Exceeds calibration range
I = Interference present
J = Estimated value
Nn = Value obtained from additional analysis
p = PCDE Interference
R = Recovery outside target range
s = Peak saturated
u = Analyte not detected
V = Result verified by confirmation analysis
X = %D Exceeds limits
y = Calculated using average of daily RFs
* = See Discussion
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc. Report No ..... 10117532_1613
Pace Analytical Services, Inc.
1700 Elm Street -Suite 200
Minneapolis, MN 55414
Tel: [phone]
Ear 612-697-6444
Report No ..... 10116940
Page 7 of 16
Appendix B
Sample Analysis Summary
Report No ..... 10117532_1613 Pace Analytical Services, Inc. Page 8 of 16
Pace Analytical Services, Inc.
1700 Elm Street -Suite 200
Minneapolis, MN 55414
-ace Analvtical· Tel: [phone]
Fax·6J2-60Z-6444
Client's Sample ID
Lab Sample ID
Filename
Injected By
Total Amount Extracted
% Moisture
Dry Weight Extracted
ICALID
CCal Filename(s)
Method Blank ID
Native
Isomers
2,3,7,8-TCDD
Method 1613B Sample Analysis Results
Client -PASI Charlotte
TMW-1W
9257759001
U91204A_10
AE
960 ml
NA
NA
U91029
U91203A_14
BLANK-22788
Cone EMPC
pg/L pg/L
ND
RL
pg/L
10
Matrix
Dilution
Collected
Received
Extracted
Analyzed
Water
NA
Internal
Standards
2,3,7,8-TCDD-13C
Recovery Standard
1,2,3,4-TCDD-13C
Cleanup Standard
2,3,7,8-TCDD-37Cl4
11/17/2009 11:00
11/19/2009 09:34
12/03/2009 10:40
12/04/2009 16:15
ng's
Added
2.00
2.00
0.20
Cone= Concentration (Totals include 2,3,7,8-substituted isomers).
EMPC = Estimated Maximum Possible Concentration
ND= Not Detected
NA = Not Applicable
NC = Not Calculated RL = Reporting Limit.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Percent
Recovery
92
NA
88
Report No ..... 10117532_ 1613 Page 9 of 16
Pace Analytical Services, Inc.
1700 Elm Street-Suite 200
Minneapolis, MN 55414
ace Analvtica(" Tel: [phone]
Fax-612-607-6444
Client's Sample ID
Lab Sample ID
Filename
Injected By
Total Amount Extracted
% Moisture
Dry Weight Extracted
ICALID
CCal Filename(s)
Method Blank ID
Native
Isomers
2,3,7,8-TCDD
Method 1613B Sample Analysis Results
Client -PASI Charlotte
TMW-2W
9257759002
U91204A_11
AE
958 ml
NA
NA
U91029
U91203A_14
BLANK-22788
Cone EMPC
pg/L pg/L
ND
RL
pg/L
10
Matrix
Dilution
Collected
Received·
Extracted
Analyzed
Water
NA
Internal
Standards
2,3,7,8-TCDD-13C
Recovery Standard
1,2,3,4-TCDD-13C
Cleanup Standard
2,3,7,8-TCDD-37Cl4
11/17/2009 14:15
11/19/2009 09:34
12/03/2009 10:40
12/04/2009 17:04
ng's
Added
2.00
2.00
0.20
Cone= Concentration (Totals include 2,3,7,8-substituted isomers).
EMPC = Estimated Maximum Possible Concentration
ND= Not Detected
NA = Not Applicable
NC= Not Calculated RL = Reporting Limit.
REPORT OF. LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Percent
Recovery
88
NA
86
Report No ..... 10117532_ 1613 Page 10 of 16
ace Analvtica("
Client's Sample ID
Lab Sample ID
Filename
Injected By
Total Amount Extracted
% Moisture
Method 1613B Sample Analysis Results
Client -PASI Charlotte
TMW-3W
9257759003
U91204A_06
AE
964 ml
NA
Water
NA
Pace Analytical Services, Inc.
1700 Elm Street -Suite 200
Minneapolis, MN 55414
Tel: [phone]
Ear 612-607-6444
Dry Weight Extracted
ICALID
CCal Filename(s)
Method Blank ID
NA
U91029
U91203A_14
BLANK-22788
Matrix
Dilution
Collected
Received
Extracted
Analyzed
11/17/2009 13:45
11/19/2009 09:34
12/03/2009 10:40
12/04/2009 12:59
Native Cone EMPC RL
Isomers pg/L pg/L pg/L
2,3,7,8-TCDD ND 10
Cone= Concentration (Totals include 2,3,7,8-substituted isomers).
EMPC = Estimated Maximum Possible Concentration
RL = Reporting Limit.
Internal
Standards
2,3,7,8-TCDD-13C
Recovery Standard
1,2,3,4-TCDD-13C
Cleanup Standard
2,3,7,8-TCDD-37Cl4
ND= Not Detected
NA= Not Applicable
NC = Not Calculated
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
. without the written consent of Pace Analytical Services, Inc.
Report No ..... 10117532_ 1613
ng's
Added
2.00
2.00
0.20
Percent
Recovery
91
NA
91
Page 11 of 16
Pace Analytical Services, Inc.
1700 Elm Street-Suite 200
Minneapolis, MN 55414
ace Analvtica(" Tel: [phone]
Fax· 612-607-6444
Client's Sample ID
Lab Sample ID
Filename
Injected By
Total Amount Extracted
% Moisture
Dry Weight Extracted
ICALID
CCal Filename(s)
Method Blank ID
Native
Isomers
2,3,7,8-TCDD
Method 1613B Sample Analysis Results
Client -PASI Charlotte
TMW-4W
9257759004
U91204A_07
AE
969ml
NA
NA
U91029
U91203A_14
BLANK-22788
Cone EMPC
pg/L pg/L
ND
RL
pg/L
10
Matrix
Dilution
Collected
Received
Extracted
Analyzed
Water
NA
Internal
Standards
2,3,7,8-TCDD-13C
Recovery Standard
1,2,3,4-TCDD-13C
Cleanup Standard
2,3,7,8-TCDD-37Cl4
11/17/2009 09:30
11/19/2009 09:34
12/03/2009 10:40
12/04/2009 13:48
ng's
Added
2.00
2.00
0.20
Cone= Concentration (Totals include 2,3,7,8-substituted isomers).
EMPC = Estimated Maximum Possible Concentration
ND= Not Detected
NA= Not Applicable
NC = Not Calculated RL = Reporting Limit.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Percent
Recovery
88
NA
87
Report No ..... 10117532_ 1613 Page12of16
ace Analvtica{"
Method 1613B Blank Analysis Results
Lab Sample ID BLANK-22788
Filename U91203A_07
Total Amount Extracted 958 ml
ICALID U91029
CCal Filename(s) U91203A_03
Native Cone EMPC RL
Isomers pg/L pg/L pg/L
2,3,7,8-TCDD ND 10
Cone= Concentration (Totals include 2,3,7,8-substituted isomers).
EMPC::: Estimated Maximum Possible Concentration
RL = Reporting Limit
Matrix
Dilution
Extracted
Analyzed
Injected By
Internal
Standards
2,3,7,8-TCDD-13C
Recovery Standard
1,2,3,4-TCDD-13C
Cleanup Standard
2,3,7,8-TCDD-37Cl4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc. Report No ..... 10117532_1613
Pace Analytical Services, Inc.
1700 Elm Street -Suite 200
Minneapo_lis, MN 55414
Tel: [phone]
Fax: [phone]
Water
NA
12/03/2009 10:40
12/03/2009 22:51
BAL
ng's Percent
Added Recovery
2.00 90
2.00 NA
0.20 91
Page 13 of 16
ace Analvtica("
Pace Analytical Services, Inc.
1700 Elm Street -Suite 200
Minneapolis, MN 55414
Tel: [phone]
Fax· 612-697-6444
Method 1613B Laboratory Control Spike Results
Lab Sample ID
Filename
Total Amount Extracted
ICALID
CCal Filename
Method Blank ID
Compound
2,3,7,8-TCDD
2,3,7,8-TCDD-37Cl4
2,3,7,8-TCDD-13C
LCS-22789
U91203A_12
963 ml
U91029
U91203A_03
BLANK-22788
Cs
10
10
100
Cs= Concentration Spiked (ng/ml)
Cr = Concentration Recovered (ng/ml)
Rec. ;:: Recovery (Expressed as Percent)
Cr
9.9
8.6
90
Control Limit Reference: Method 1613, Table 6, 10/94 Revision
R :;; Recovery outside of control limits
Nn = Value obtained from additional analysis
* = See Discussion
Matrix
Dilution
Extracted
Analyzed
Injected By
Lower
Limit
7.3
3.7
25.0
Water
NA
12/03/2009 10:40
12/04/2009 02:49
BAL
Upper %
Limit Rec.
14.6 99
15.8 86
141.0 90
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc. Report No ..... 10117532_1613 Page 14 of 16
ace Analvtica("
·Pace Analytical Services, Inc.
1700 Elm Street-Suite 200
Minneapolis, MN 55414
Tel: [phone]
Fax-612-697-6444
Method 1613B Laboratory Control Spike Results
Lab Sample ID
Filename
Total Amount Extracted
ICALID
CCal Filename
Method Blank ID
LCSD-22790
U91203A_13
991 ml
U91029
U91203A_03
BLANK-22788
Matrix
Dilution
Extracted
Analyzed
Injected By
Water
NA
12/03/2009 10:40
12/04/2009 03:38
BAL
Lower Upper %
Compound Cs.
2,3,7,8-TCDD 10
2,3,7,8-TCDD-37C\4 10
2,3,7,8-TCDD-13C 100
Cs = Concentration Spiked (ng/ml)
Cr= Concentration Recovered (ng/ml)
Rec. ;: Recovery (Expressed as Percent)
Cr
9.7
8.5
85
Control Limit Reference: Method 1613, Table 6, 10/94 Revision
R = Recovery outside of control limits
Nn = Value obtained from additional analysis
* = See Discussion
Limit Limit
7.3 14.6
3.7 15.8
25.0 141.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Report No ..... 10117532_ 1613
Rec.
97
85
85
Page 15 of 16
ace Analvtica("
Method 1613B
Pace Analytical Services, Inc.
1700 Elm Street-Suite 200
Minneapolis, MN 55414
Tel: [phone]
fax· §12-§07-§444
Spike Recovery Relative Percent Difference (RPD) Results
Client
Spike 1 ID
Spike 1 Filename
Compound
2,3,7,8-TCDD
PASI Charlotte
LCS-22789
U91203A_12
%REC= Percent Recovered
Spike 1
%REC
99
Spike 2ID
Spike 2 Filename
Spike 2
%REC
97
RPO = The difference between the two values divided by the mean value
LCSD-22790
U91203A_13
%RPO
2.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Report No ..... 10117532_ 1613 Page16of16
/~eAnalytica/' • I o,
CHAIN-OF-CUSTODY/ Analytical Request Document
The Chain-of-Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately.
www.p1c11 -~-
Section A Section B Section C Page; I of \
Required Client Information: Required Project Information: Invoice Information: 1336369 Compa~y~4i ~\\I'll, LLP R,port To, rT< (c.ra\(NlS Atteo~. , I' N't" Y'O-.S
Ad~,u OtVtlrl l~\l(IAi'l,I\ {_c.1117 Copy To: Comp~~•r/l/'O i /{la• UP REGULATORY AGENCY
L,.J\"" ,-;;:. ' Al(. ~<ell II Addra"?Z II ,..,_ ,ti9t'\fu,=~ r NPDES r GROUND WATER r DRINKING WATER
Email To:MOl\'r IA \lllKTWd .& Purchase Order No.: Pec:e Quote -Raterenee· r UST r RCRA r OTHER
Priffo\'\l.0.(.-9 1 \t/ Ve(lQ CP.i-1,l,6f, Prnjoci N,m., Co.*\€ Ho,J A '1_ Pace Project Site Location Manager; /\JC. R(Nfl.lesRid Due Date/TAT:5~ dwJ Project Numberr.:::t.:\ \ ;).y <n n Pece Pro!Me #: ~~3 -1.C :.. STATE:
·:.~-~qli8sted Analysis Filtered (Y/N) -Section D Matrix Codes i 5: Z·
RequlredCt~nt ln!ormauon M~IBI! I ~QOE :,; COLLECTED PraseNatives '►• • 0 Drinking Water OW ' u Ii ~·-"' r '} ~ ! Water WT ~ " & . u ~ Waste Weter WW COMPOSITE COMPOSITE u ~ a m STAAT '"""""" • { I= N [ Product p ' ~ w -~ ,-.-, 8 i .,,
SoiVSolid SL ! ~ 15 .,. "" 925'7'759 SAMPLE ID OU OL " u "' a "' ' • " " ~ ,..,. WP ~ w . ., ,I.-{ C
(A-Z, 0-9 / ,-) w z ·~, -~ -·c
AJ, AR Cl w ~ ~ al ' 'f .Q
Semple IDs MUST BE UNIQUE Tissue TS 0 ~ , ri,;· a -Id:: i . ~ ~
t I" ~ 'I ()
00,,c OT <.) z ~ oo Ji .. ~ "l w 0 • Q C t+ . ,_ • <.) Kl O .., ~ " "' " ~ ~ :,: " . ~ ~ii £ g 1 ~
i :,; :,; "-5. en o 0 V) ~ '~ ".". ·a w ;jj < 0 C o Z (j • m' ti ~ • " DATE TIME om TIME "' .. ::, :,: :,: :,: z z " ... I' 0: Pace Project No./ Lab 1.0.
1 ,.-," w-u.J u,f (,. \1\..-w 11·.nt.l 8 >< II ~-~-~ )( } ) )( ',,: 'x-.._ x "DI ,, '
-1 AAW-t. J T ?:\S" I ·.~~ I 2 ~-2..
3 1---r'Ml ,1-• vJ I :'{S I .. I I 003 .
4 ,1" Iv\,\ A I -L\ \..0 .~ . q-.s;i f }l•· I L,--oo<.f --~?
5
• ..
··•
7 :~'.:~
-:":
8 V-
' ~:£,
10 ~'t,
11 :,{} :(.,_:.
12 ':'.' .. -
ADDmONAL COMMENTS RELINQiJISHED BY_ I AF°FILl~1l~N )::' ~ '• :}r:~Atf;};j ~:.)i~'E·~-Iii ;tt:~-~~~f.r!DJY.C~f~~r_1_0N. DATE TIME SAMPLE CONDITIONS
.
st,~) ('1.,-. (, . ,._~ /c;;(_s l\ \ pjc,'.I 6:cc l I , 1\\ iM. I 'I w.\ n.\ lr.-,rP \\ \\'i,\t',C G-:21"\ '"'-I y (\ '1
() I I \ I
SAMPLER NAME AN[) s'ic;NA riJREi"" •. •,: ,_,_ . • ii ORIGINAL . p C -,,. '--, •-'-.; . _.,' ' .. ·'~ ,_ ' .. .. .. o-t 8 z C 1i ~ £-
PRINT Name of SAMPLER: ~ / l Of'\(._W:,. <; .z
0 -~ C. ~ al s is E . .
SIGNATURE of SAMPLER:0-),1(s =• I DATE Signed \ d I "'.f-CJj ~ ~~ u~ ~
' (MM/00/YY): ~ "' "' -Important Note. By sigrung this IOtTTI you ere accepting paa,'1 NET 30 day payment 1erms and agfNlng to late charges of 1.5% per monlh for aoy lnYOlces not paid wlthln 30 da~. F-ALL-Q-020rev.07, 15-May-2007
CI i en t Na me: _.c""'(;"""C:,....,____,,,( ..... n~ro...,_~..,_,\"'-(\i:,,;~,,_;S,:,..._ Pro j eel #
. C~urier: ~d Ex O UPS D USPS O C:iert O Ccmmecc,al O Pace. 017 __ _
Custod•1 Seal on Cooler!Box Pres~nt: D y~s Gr" no Seals fr,t3ct: B';-es O no
Packing Material: 0 Bubble Wrap E'jB~bble Bags O None Oother ----Thermometer Used· T060 Type of Ice: ~ Blue s. \0 ·• . .,
Cccler Tar.i~erature · Biological Tissue is Frozen: Y~s No NIA Date and Initials of pe;s.:,n examininc\
contencs: ~~ \'.'i,-~~-c
NonP ffs~mpli=>S or. ice. caol'1ng process has begun
Temp shouk! '::le above free=i.1g to 5"C Comments:
Chain of Custody Present ~s 0No □NIA 1,
•.'· -~ C'nain of Cus'icdy Filled Out: ., 0Nv ON!.J. 2:·
Chain of Custody Relinquished: ~-0No 0WA 3.·
Sampler Name & Signalure on COC:: .. · .ISYes 0No □NIA 4· . •. •· ~ .. Samples Arrived within Hold Time: □No □NIA st
Short Hold Time Analysis (<72hr): ~\. ·□Yes ~ ON/A 60:
0Yes ~o
·' Rush Turn Around Time Requested: □NIA 7.'
Sufficient Volume: . ~ 0No □NIA 8 :n" "'"' .. l{\/l . me-'to\S ro *\ ~ l'\o..," \\
Correct Containers Used·. . ig<,; 0No ON/A 9., •.
•Pace Containers Used: ig(.', ONo· □NIA
Containers Intact ~s 0No □NIA 10:· • .
Filtered volume received for Oiss0lved.tests OYes 0No . s;;;;,, H.
Sfi'o
.
12° \ • \e<:e..~..J~ -'K-\? b\CI.(\ K. c.""° I"°\$ I'\~ Sample Labels match COC: OYes □NIA
•Includes date/time/ID/Analysis .Matrix: .·°" c.oc___ -\Ni ·1-\\(_L All containers needing preserva!ion have beer) checked .. Yes 0No ON/A 13.':
All containers needing preservation are found 1·0 be in g{,, □No □NIA .. compliance with EPA recommendation. -··
excep1ions·. VOA, coli/orm, T0C, 0&G, WI-ORO (water) OYes 0No Initial when completed
Samples checked for dechlorination:· . (9"Yes 0No ONIA 14.
Headspace in VOA Vials ( >6mm): □Yes ~ □NIA 15.
Trip Blank Present: 19¼, 0No . □NIA 16.
Trip Blank Custody Seals Present ~ □No ON/A
Pace Trip Blank Loi# (if purchased): NIA
Client Notification/ Resolution: Field Data Required? Y / N N/A
Person Contacted: ______________ Date/Time:
Comments/ Resolution: -------------------------
Project Manager Review:
Note: Whenever there is a discrepancy affectina North Cartilin:i r:nmnli;rnrn <:e,mnln.:: ., ,.,., ..... ,.,f 1h;~ ,..,,_ .•. :11 '--•• -• ,_ ,L -.,_ .... ,..._ •• ,.
ace Analytical'"
www.pacelabs.com
Report Prepared for:
Ashley Nifong
PAS! Charlotte
9800 Kincey Ave.
Huntersville NC 28078
REPORT OF
LABORATORY
ANALYSIS FOR
TCDD
Report Prepared Date:
November 30, 2009
Report No ..... 10116961_1613
Pace Analytical Services, Inc.
1700 Elm Street
Minneapolis, MN 55414
Phone: [phone]
Fax: [phone]
Report Information:
Pace Project #: 10116961
Sample Receipt Date: 11/13/2009
Client Project#: 9257362
Client Sub PO#: N/A
State Cert#: 27700
Invoicing & Reporting Options:
The report provided has been invoiced as a Level 2
2,3,7,8-TCDD Report. I fan upgrade of this report
package is requested, an additional charge may be
applied.
Please review the attached invoice for accuracy and
forward any questions to Nate Habte, your Pace
Project Manager.
This report has been reviewed by:
N~l \+~-
November 30, 2009
Nate Hable, Project Manager
[phone]
(6 I 2) 607-6444 (fax)
[e-mail]
\ll ACCof/
0-1
'),, 1-C'
'-' -'-' ~ < - -::i:
Report of Laboratory Analysis
This report should not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
The results relate only to the samples included in this report.
Page 1 of 25
DISCUSSION
Pace Analytical Services, Inc.
1700 Elm Street
Minneapolis, MN 55414
Phone: [phone]
Fax: [phone]
This report presents the results from the analyses performed on twelve samples submitted by a
representative of Pace Analytical Services, Inc. The samples were analyzed for the presence or absence
of 2,3,7,8-tetrachlorodibenzo-p-dioxin (2,3,7,8-TCDD) using a modified version of USEPA Method 16138.
The reporting limits were set to correspond to the lowest calibration point and a nominal 10-gram sample
amount.
The recoveries of the isotopically-labeled TCDD internal standard in the sample extracts ranged from
72-96%. All of the labeled standard recoveries obtained for this project were within the target ranges
specified in Method 16138. Also, since the quantification of the native TCDD was based on isotope
dilution, the data were automatically corrected for recovery and accurate values were obtained.
A laboratory method blank was prepared and analyzed with the sample batch as part of our routine quality
control procedures. The results show that 2,3,7,8-TCDD was not detected, indicating that the sample
processing steps were free of background levels of this congener.
Laboratory and matrix spike samples were also prepared with the sample batch using clean sand or
sample matrix that had been fortified with native standard materials. The results show that the spiked
native compounds were recovered at 95-102%, with a relative percent difference of 3.7%. These results
indicate high degrees of accuracy and precision for these determinations.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Report No ..... 10116961_:_1613 Page 2 of 25
Authority
Alabama
Alaska
Arizona
Arkansas
California
Colorado
Connecticut
EPA Region 5
EPA Region 8
Florida (NELAP
Georgia (DNR)
Guam
Hawaii
Idaho
Illinois
Indiana
Indiana
Iowa
Kansas
Kentucky
Louisiana
Maine
Maryland
Michigan
Minnesota
Mississippi
Minnesota Laboratory Certifications
Certificate # Authority
40770 Montana
MN00064 Nebraska
AZ0014 Nevada
88-0680 New Jersey (NE
01155CA New Mexico
MN00064 New York (NEL
PH-0256 North Carolina
WD-15J North Dakota
8TMS-Q Ohio
E87605 OhioVAP
959 Oklahoma
08-004r Oregon (ELAP)
SLD Oregon (OREL
MN00064 Pennsylvania
200012 Saipan
South Carolina
C-MN-01 Tennesee
368 Tennessee
E-10167 Texas
90062 Utah (NELAP)
LA0900016 Virginia
2007029 Washington
322 West Virginia
9909 Wisconsin
027 -053-137 Wyoming
MN00064
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Report No ..... 10116961_1613
J
Pace Analytical Services, lnc.
1700 Elm Street -Suite 200
Minneapolis, MN 55414
Tel: [phone]
Fax: [phone]
Certificate #
92
MN00064_2000
MN002
MN00064
11647
27700
R-036
4150
CL101
D9922
MN200001-005
MN200001-005
68-00563
MP0003
74003001
2818
02818
T104704192-08
PAM
00251
C755
9952C
999407970
8TMS-Q
Page 3 of 25
Appendix A
Sample Management
Report No ..... 10116961_1613 Pace Analytical Services, Inc. Page 4 of 25
Chain of Custody
;o
CD -0 0
~orkorder: 9257362 Workorder Name:CASTLE HAYNE 22-124930
Ashley Nifong
2
3
4
5
6
7
8
9
ace Analytical Services, Inc.
800 Kincey Ave., Suite 100
untersville, NC 28078
hone [phone]
ax [phone]
HA-1
HA-2
HA-3
HA-4
HA-5
HA-6
HA-7
HA-8
HA-9
10 HA-10
11 HA-11
12 HA-12
Pace Analytical Minnesota
1700 Elm Street SE
Suite 200
Minneapolis, MN 55414
Phone [phone]
11/11/2009 10:30 9257362001 Solid
11/11/200909:15 9257362002 Solid
11/11/2009 09:00 9257362003 Solid
11/11/2009 11 :45 9257362004 Solid
11/11/2009 11:30 , 9257362005 Solid
11/11/2009 13:00 9257362006 Solid
11/11/2009 13:30 9257362007 Solid
11/11/2009 14:30 9257362008 Solid
11/11/2009 09:30 9257362009 ' Solid
11/11/2009 10:45 9257362010 Solid
11/11/2009 12:30 9257362011 Solid
11/11/200914:00 9257362012 Solid
r~·
Owner Received Date: 11/12/~009 Results Requested By: 11/23/2009
triiP.tiiSe"i:ved[COfitilifi'eisJf-..
LAB USE ONLY
X
X
X
X
X
X
X
X
X
X
X
~i:R;--5tV~\c'1li_t~f{fo~Y~~1.tE•\~f~&l~fWfi'~'-:~~~~;~~~~.Jr~~~~~;@;:;_~ ~,J.~~C_Qriffiiems~G:~~~
Transfers
2
3
CD
(J1
9,
erature on Recei
-h;'ursday, November 12, 2009 3:44:02 PM
or N or N
FMT-ALL-C-002rev.OO 24March2009 Page 1 o~ 1
Sample Condition Upon Receipt
Client Name: \),re/ ,0 r < Project # \:QI I 1--961
Courier: fli F~d ExJ;).UPS D .USPS 0 0.cp9nt D Commerclal D Pace Other ___ _
Track1n6 l;;:;{;{fr ZP/Q-tJS lb
Custody Seal on Cooler/Box Present D yes µI' no Seals Intact: D yes O no
Pocking Materlal: 0 Bubble Wrap cf Bubble Bags 0 Nano D Other ____ Temp Blank: Yes __ No/
Th ef-1'~ ermometer Uaed 80344042 r 179 Type of Ice: 8 ue one Samples on Ice, cooling process has: begun
Cooler Temperature --{ -~ Blologloal Tissue Is Frozen: v .. No 0
:n~:~~/,.mf}~J/P('
9
Temp should be aboVe ~eezing to e•c Commenta:
@ Bl N □
Chain of CUstodv Present: !!'iv .. □No □NIA 1.
Chain of cuatnrn, Filled Out: 'f1'ves □N0 □NIA 2.
Chain of Custodv Relln"' •!shed: i/ves □No □NIA 3.
Samoler Name & Slanature on COC: ov .. 12lNo □NIA 4.
5amoles Arrtved wflhln Hold Time: 11'fv .. □No □NIA 5.
Short Hold Time Analvsls 1<72hrl: □Yoo □No .M!wA 6.
Rush Turn Around T--ed: □Yes~ □NIA 7.
Sufficient Volume: }Zf{ea □No □NIA 8.
Correct Containers Used: /l'.fves □No □NIA 9.
-Paoe Containers Used: /2v .. □No □NIA
Conlalnera Intact: zfv .. □No □NIA 10.
Filtered volume reoelved for Dissolved lasts □Vos □No 00A 11.
Sample Labels match COC:
Matrlx: 5/
,6ves □No □NIA 12.
-Includes date/llme/10/Analvsls
All contafne,u needing acid/base preservation have been □Yes □No /NIA O HN03 □ H2S04 □ NaOH □ HCI
checked. Noncomnllance are noted In 13. 13.
All container& needing preservation ere found to be In □Yes □No ,t{N/A
Samp#
compliance with EPA recommendaUon.
Exceptions: VOA.Cotifonn. TOO, OU and arease, Wl•OAO (wate( □Yea ~ lniUal when Lot# of added
completed --' pre.::;ervattvo
Samoles cheokod far dechlorination: □Yes □No CiNIA 14.
Head= In VOA Vlals ( :>6mm): ov.. □No · l,!N/,_ 15.
Trlp Blank Present: □Yee □No "NIA 16.
Trlp Blank Custody Seals Present □v .. □No ~A -Paoe Trip Blank Lot# (ff ourchaSGd):
Client Notification/ Resolution: Field Data Required? y I N
Person Contacted: :A;; \o_ \:;'!; Y) , jV J fr~ Date/Time: ______ _
Comments/ Resolution:__,....,.-,.-,-----:--v---,------------------------
\ C> -
----:=-::910'o"';~:t;-f';;>-~~~t:;,-;-J:"';;~~~i'fff:::C:-rn::i~~~Wi~!...Wd.
Project Manager Review: --------~~;:s:J:_ _______ _;_
Note: Whenever there is a discrepancy affecting North Carolina compllance samples, a copy c,t this form will be sont to the~/',&al seti.l!la, Inc.
F·L213Rev.OO, 05Aug2009 1700 Elm Street SE, Suite 200, Minneapolis, MN 55414
Report No ..... 10116961_1613 Page 6 of 25
aceAnalvtical"
Reporting Flags
A = Reporting Limit based on signal to noise
B = Less than 1 Ox higher than method blank level
C = Result obtained from confirmation analysis
D = Result obtained from analysis of diluted sample
E = Exceeds calibration range
I =: Interference present
J = Estimated value
Nn = Value obtained from additional analysis
p = PCDE Interference
R = Recovery outside target range
s = Peak saturated
u = Analyte not detected
V = Result verified by confirmation analysis
X = %D Exceeds limits
y = Calculated using average of daily RFs
* = See Discussion
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Report No ..... 10116961_1613
Pace Analytical Services, Inc.
1700 Elm Street • Suite 200
Minneapolis, MN 55414
Tel: [phone]
Far 612-§07-§444
Page 7 of 25
Appendix B
Sample Analysis Summary
Report No ..... 10116961_1613 Pace Analytical Services, Inc. Page 8 of 25
ace Analytical·
Client's Sample ID
Lab Sample ID
Filename
Injected By
Total Amount Extracted
% Moisture
Method 1613B Sample Analysis Results
Client -PASI Charlotte
HA-1
9257362001
U91128A_11
BAL
11.5 g
17.6
Solid
NA
Pace Analytical Services, Inc.
1700 Elm Street -Suite 200
Minneapolis, MN 55414
Tel: 612-607-H00
Fax· 612-697-6444
Dry Weight Extracted
ICALID
CCal Filename(s)
Method Blank ID
9.49 g
U91029
U91128A_02
BLANK-22591
Matrix
Dilution
Collected
Received
Extracted
Analyzed
11/11/2009 10:30
11/13/2009 09:35
11/23/2009 20:00
11/28/2009 21:07
Native
Isomers
2,3,7,8-TCDD
Cone
ng/Kg
ND
EMPC
ng/Kg
RL
ng/Kg
1.0
Cone= Concentration (Totals include 2,3,7,8-substituted isomers).
EMPC = Estimated Maximum Possible Concentration
RL = Reporting Limit.
Internal
Standards
2,3,7,8-TCDD-13C
Recovery Standard
1,2,3,4-TCDD-13C
Cleanup Standard
2,3,7,8-TCDD-37Cl4
ND= Not Detected
NA = Not Applicable
NC = Not Calculated
Results reported on a dry weight basis and are valid to no more than 2 significant figures.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Report No ..... 10116961_1613
ng's
Added
2.00
2.00
0.20
Percent
Recovery
81
NA
81
Page 9 of 25
ace Analvtica("
Client's Sample ID
Lab Sample ID
Filename
Injected By
Total Amount Extracted
% Moisture
Method 16138 Sample Analysis Results
Client -PASI Charlotte
HA-2
9257362002
F91126A_08
BAL
11.4 g
12.1
Solid
NA
Pace Analytical Services, Inc.
1700 Elm Street-Suite 200
Minneapolis, MN 55414
Tel: [phone]
Fax· §12-§07-6444
Dry Weight Extracted
ICALID
CCal Filename(s)
Method Blank ID
10.1 g
F91106
F91125B 15
BLANK-22591
Matrix
Dilution
Collected
Received
Extracted
Analyzed
11/11/2009 09:15
11/13/2009 09:35
11/23/2009 20:00
11/26/2009 13:48
Native Cone EMPC RL
Isomers ng/Kg ng/Kg ng/Kg
2,3,7,8-TCDD ND 1.0
Cone= Concentration (Totals include 2,3,7,8-substituted isomers).
EMPC = Estimated Maximum Possible Concentration
RL = Reporting Limit.
Internal
Standards
2,3,7,8-TCDD-13C
Recovery Standard
1,2,3,4-TCDD-13C
Cleanup Standard
2,3,7,8-TCDD-37Cl4
ND = Not Detected
NA = Not Applicable
NC = Not Calculated
Results reported on a dry weight basis and are valid to no more than 2 significant figures.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Report No ..... 10116961_1613
ng's
Added
2.00
2.00
0.20
Percent
Recovery
85
NA
80
Page 10 of 25
ace Analvtica("
Client's Sample ID
Lab Sample ID
Filename
Injected By
Total Arnau nt Extracted
% Moisture
Method 1613B Sample Analysis Results
Client -PASI Charlotte
HA-3
9257362003
U91128A_12
BAL
11.3 g
11.4
Solid
NA
Pace Analytical Services, Inc.
1700 Elm Street -Suite 200
Minneapolis, MN 55414
Tel: [phone]
Ear s12-607-§444
Dry Weight Extracted
ICALID
CCal Filename(s)
Method Blank ID
9.98g
U91029
U91128A_02
BLANK-22591
Matrix
Dilution
Collected
Received
Extracted
Analyzed
11/11/2009 09:00
11/13/2009 09:35
11/23/2009 20:00
11/28/2009 21:56
Native Cone EMPC RL
Isomers ng/Kg ng/Kg ng/Kg
2,3,7,8-TCDD ND 1.0
Cone= Concentration (Totals include 2,3,7,8-substituted isomers).
EMPC = Estimated Maximum ·Possible Concentration
RL = Reporting Limit.
Internal
Standards
2,3,7,8-TCDD-13C
Recovery Standard
1,2,3,4-TCDD-13C
Cleanup Standard
2,3,7,8-TCDD-37C14
ND = Not Detected
NA= Not Applicable
NC = Not Calculated
Results reported on a dry weight basis and are valid to no more than 2 significant figures.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Report No ..... 10116961_1613
ng's
Added
2.00
2.00
0.20
Percent
Recovery
81
NA
79
Page 11 of 25
ace Analvtica("
Client's Sample ID
Lab Sample ID
Filename
Injected By
Total Amount Extracted
% Moisture
Method 1613B Sample Analysis Results
Client -PASI Charlotte
HA-4
9257362004
F91126A_10
BAL
11.7 g
34.6
Solid
NA
Pace Analytical Services, Inc.
1700 Elm Street -Suite 200
Minneapolis, MN 55414
Tel: [phone]
Fax· 612-607-6444
Dry Weight Extracted
ICALID
CCal Filename(s)
Method Blank ID
7.64 g
F91106
F91125B_15
BLANK-22591
Matrix
Dilution
Collected
Received
Extracted
Analyzed
11/11/2009 11 :45
11/13/2009 09:35
11/23/2009 20:00
11/26/2009 15:23
Native Cone EMPC RL
Isomers ng/Kg ng/Kg ng/Kg
2,3,7,8-TCDD ND 1.0
Cone= Concentration (Totals include 2,3,7,8-substituted isomers).
EMPC = Estimated Maximum Possible Concentration
RL = Reporting Limit.
Internal
Standards
2,3,7,8-TCDD-13C
Recovery Standard
1,2,3,4-TCDD-13C
Cleanup Standard
2,3,7,8-TCDD-37Cl4
ND= Not Detected
NA = Not Applicable
NC = Not Calculated
Results reported on a dry weight basis and are valid to no more than 2 significant figures.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Report No ..... 10116961_1613
ng's
Added
2.00
2.00
0.20
Percent
Recovery
84
NA
80
Page 12 of 25
ace Analvtica(·
Client's Sample ID
Lab Sample ID
Filename
Injected By
Total Amount Extracted
% Moisture
Method 1613B Sample Analysis Results
Client -PAS\ Charlotte
HA-5
9257362005
F91126A_11
BAL
14.0 g
20.5
Solid
NA
Pace Analytical Services, Inc.
1700 Elm Street-Suite 200
Minneapolis, MN 55414
Tel: [phone]
Ffl)C §12-§97-§444
Dry Weight Extracted
ICALID
CCal Filename(s)
Method Blank ID
11.2 g
F91106
F91125B_15
BLANK-22591
Matrix
Dilution
Collected
Received
Extracted
Analyzed
11/11/2009 11 :30
11/13/2009 09:35
11/23/2009 20:00
11/26/2009 16:10
Native Cone EMPC RL
Isomers ng/Kg ng/Kg ng/Kg
2,3,7,8-TCDD ND 1.0
Cone= Concentration (Totals include 2,3,7,8-substituted isomers).
EMPC = Estimated Maximum Possible Concentration
RL = Reporting limit.
Internal
Standards
2,3,7,8-TCDD-13C
Recovery Standard
1,2,3,4-TCDD-13C
Cleanup Standard
2,3,7,8-TCDD-37Cl4
ND= Not Detected
NA = Not Applicable
NC = Not Calculated
Results reported on a dry welght basis and are valid to no more than 2 significant figures.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Report No ..... 10116961_1613
ng's
Added
2.00
2.00
0.20
Percent
Recovery
83
NA
78
Page 13 of 25
-ace Analvtica("
Client's Sample ID
Lab Sample ID
Filename
Injected By
Total Amount Extracted
% Moisture
Method 1613B Sample Analysis Results
Client -PASI Charlotte
HA-6
9257362006
U91128A_13
BAL
12.6 g
16.3
Solid
NA
Pace Analytical Services, Inc.
1700 Elm Street -Suite 200
Minneapolis, MN 55414
Tel: [phone]
Ear 612-607-6444
Dry Weight Extracted
ICALID
CCal Filename(s)
Method Blank ID
10.6 g
U91029
U91128A_02
BLANK-22591
Matrix
Dilution
Collected
Received
Extracted
Analyzed
11/11/2009 13:00
11/13/2009 09:35
11/23/2009 20:00
11/28/2009 22:45
Native
Isomers
2,3,7,8-TCDD
Cone
ng/Kg
ND
EMPC
ng/Kg
RL
ng/Kg
1.0
Cone= Concentration (Totals include 2,3,7,8-substituted isomers).
EMPC = Estimated Maximum Possible Concentration
RL = Reporting Limit.
Internal
Standards
2,3,7,8-TCDD-13C
Recovery Standard
1,2,3,4-TCDD-13C
Cleanup Standard
2,3,7,8-TCDD-37Cl4
ND= Not Detected
NA= Not Applicable
NC= Not Calculated
Results reported on a dry weight basis and are valid to no more than 2 significant figures.
R = Recovery outside target range
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent.of Pace Analytical Services, Inc.
Report No ..... 10116961_1613
ng's
Added
2.00
2.00
0.20
Percent
Recovery
96
NA
91
Page 14 of 25
ace Analvtica(·
Client's Sample ID
Lab Sample ID
Filename
Injected By
Total Amount Extracted
% Moisture
Method 1613B Sample Analysis Results
Client -PASI Charlotte
HA-7
9257362007
U91128A_14
BAL
11.7 g
17.0
Solid
NA
Pace Analytical Services, Inc.
1700 Elm Street -Suite 200
Minneapolis, MN 55414
Tel: [phone]
Fax· 612-697-6444
Dry Weight Extracted
!CALIO
CCal Filename(s)
Method Blank ID
9.68g
U91029
·U91128A_02
BLANK-22591
Matrix
Dilution
Collected
Received
Extracted
Analyzed
11/11/2009 13:30
11/13/2009 09:35 ,
11/23/2009 20:00
11/28/2009 23:33
Native Cone EMPC RL
lsOmers ng/Kg ng/Kg ng/Kg
2,3,7,8-TCDD ND 1.0
Cone= Concentration (Totals include 2,3,7,8-substituted isomers).
EMPC = Estimated Maximum Possible Concentration
RL = Reporting Limit.
Internal
Standards
2,3,7,8-TCDD-13C
Recovery Standard
1,2,3,4-TCDD-13C
Cleanup Standard
2,3, 7,8-TCDD-37Cl4
ND = Not Detected
NA = Not Applicable
NC = Not Calculated
Results reported on a dry weight basis and are valid to no more than 2 significant figures.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full.
without the written consent of Pace Analytical Services, Inc.
Report No ..... 10116961_1613
ng's
Added
2.00
2.00
0.20
Percent
Recovery
80
NA
75
Page 15 of 25
ace Analvtica("
Client's Sample ID
Lab Sample ID
Filename
Injected By
Total Amount Extracted
% Moisture
Method 1613B Sample Analysis Results
Client -PASI Charlotte
HA-8
9257362008
U91128A_15
BAL
11.3 g
14.2
Solid
NA
Pace Analytical Services, Inc.
1700 Elm Street -Suite 200
Minneapolis, MN 55414
Tel: [phone]
Fax-612-607-6444
Dry Weight Extracted
ICALID
CCal Filename(s)
Method Blank ID
9.69g
U91029
U91128A 02
BLANK-22591
Matrix
Dilution
Collected
Received
Extracted
Analyzed.
11/11/2009 14:30
11/13/2009 09:35
11/23/2009 20:00
11/29/2009 00:22
Native Cone EMPC RL
Isomers ng/Kg ng/Kg ng/Kg
2,3,7,8-TCDD ND 1.0
Cone= Concentration (Totals include 2,3,7,8-substituted isomers).
EMPC = Estimated Maximum Possible Concentration
RL = Reporting Limit.
Internal
Standards
2,3,7,8-TCDD-13C
Recovery Standard
1,2,3,4-TCDD-13C
Cleanup Standard
2,3,7,8-TCDD-37Cl4
NO = Not Detected
NA= Not Applicable
NC= Not Calculated
Results reported on a dry weight basis and are valid to no more than 2 significant figures.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Report No ..... 10116961_1613
ng's
Added
2.00
2.00
0.20
Percent
Recovery
82
NA
82
Page 16 of 25
ace Analvtica(·
Client's Sample ID
Lab Sample ID
Filename
Injected By
Total Amount Extracted
% Moisture
Method 1613B Sample Analysis Results
Client -PASI Charlotte
HA-9
9257362009
U91126B_05
BAL
10.7 g
13.0
Solid
NA
Pace Analytical Services, Inc.
1700 Elm Street -Suite 200
Minneapolls, MN 55414
Tel: 612"'607-1700
Fax· 612-697-6444
Dry Weight Extracted
ICALID
CCal Filename(s)
Method Blank ID
9.31 g
U91029
U91126A_16
BLANK-22591
Matrix
Dilution
Collected
Received
Extracted
Analyzed
11/11/2009 09:30
11/13/2009 09:35
11/23/2009 20:00
11/26/2009 23:52
Native Cone EMPC RL
Isomers ng/Kg ng/Kg ng/Kg
2,3,7,8-TCDD ND 1.0
Cone= Concentration (Totals include 2,3,7,8-substituted isomers).
EMPC = Estimated Maximum Possible Concentration
RL = Reporting Limit.
Internal
Standards
2,3,7,8-TCDD'.13c
Recovery Standard
1,2,3,4-TCDD-13C
Cleanup Standard
2,3,7,8-TCDD-37Cl4
ND= Not Detected
NA= Not Applicable
NC = Not Calculated
Results reported on a dry weight basis and are valid to no more than 2 significant figures.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc Report No ..... 10116961 1613
ng's
Added
2.00
2.00
0.20
Percent
Recovery
76
NA
76
Page 17 of 25
ace Analvticat·
Client's Sample ID
Lab Sample ID
Filename
Injected By
Total Amount Extracted
% Moisture
Method 1613B Sample Analysis Results.
HA-10
9257362010
U91126B_06
BAL
13.0 g
16.2
Client -PASI Charlotte
Solid
NA
Pace Analytical Services, Inc.
1700 Elm Street -Suite 200
Minneapolis, MN 55414
Tel: [phone]
Ear 612-607-6444
Dry Weight Extracted
ICALID
CCal Filename(s)
Method Blank ID
10.9 g
U91029
U91126A 16
BLANK-22591
Matrix
Dilution
Collected
Received
Extracted
Analyzed
11/11/2009 10:45
11/13/2009 09:35
11/23/2009 20:00
11/27/2009 00:42
Native
Isomers
2,3,7,8-TCDD
Cone
ng/Kg
ND
EMPC
ng/Kg
RL
ng/Kg
1.0
Cone= Concentration (Totals include 2,3,7,8-substituted isomers).
EMPC = Estimated Maximum Possible Concentration
RL = Reporting Limit.
Internal
Standards
2,3,7,8-TCDD-13C
Recovery Standard
1,2,3,4-TCDD-13C
Cleanup Standard
2,3,7,8-TCDD-37Cl4
ND= Not Detected
NA= Not Applicable
NC = Not Calculated
Results reported on a dry weight basis and are valid to no more than 2 significant figures.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc
Report No ..... 10116961 1613
ng's
Added
2.00
2.00
0.20
Percent
Recovery
79
NA
79
Page 18 of 25
ace Analvtica("
Client's Sample ID
Lab Sample ID
Filename
Injected By
Total Amount Extracted
% Moisture
Method 1613B Sample Analysis Results
Client -PASI Charlotte
HA-11
9257362011
U91126B_07
BAL
13.0 g
19.1
Solid
NA
Pace Analytical Services, Inc.
1700 Elm Street -Suite 200
Minneapolis, MN 55414
Tel: [phone]
fax· §12-§97-§444
Dry Weight Extracted
ICALID
CCal Filename(s)
Method Blank ID
10.5 g
U91029
U91126A_16
BLANK-22591
Matrix
Dilution
Collected
Received
Extracted
Analyzed
11/11/2009 12:30
11/13/2009 09:35
11/23/2009 20:00
11/27/2009 01:30
Native Cone EMPC RL
Isomers ng/Kg ng/Kg ng/Kg
2,3,7,8-TCDD ND 1.0
Cone= Concentration (Totals include 2,3,7,8-substituted isomers).
EMPC = Estimated Maximum Possible Concentration
RL = Reporting Limit.
Internal
Standards
2,3, 7,8-TCDD-13C
Recovery Standard
1,2,3,4-TCDD-13C
Cleanup Standard
2,3,7,8-TCDD-37Cl4
ND= Not Detected
NA= Not Applicable
NC = Not Calculated
Results reported on a dry weight basis and are valid to no more than 2 significant figures.
REPORT OF LABORATORY ANALYSIS
This-report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Report No ..... 10116961_ 1613
ng's
Added
2.00
2.00
0.20
Percent
Recovery
72
NA
79
Page 19 of 25
ace Analvtica("
Client's Sample ID
Lab Sample ID
Filename
Injected By
Total Amount Extracted
% Moisture
Method 1613B Sample Analysis Results
Client -PASI Charlotte
HA-12
9257362012
U91126B_08
BAL
12.3 g
17.7
Solid
NA
Pace Analytical Services, Inc.
HOO Elm Street -Suite 200
Minneapolis, MN 55414
Tel: [phone]
Fax-612-607-6444
Dry Weight Extracted
ICALID
CCal Filename(s)
Method Blank ID
10.2 g
U91029
U91126A_16
BLANK-22591
Matrix
Dilution
Collected
Received
Extracted
Analyzed
11/11/2009 14:00
11/13/2009 09:35
11/23/2009 20:00
11/27/2009 02:19
Native Cone EMPC RL
Isomers ng/Kg ng/Kg ng/Kg
2,3, 7,8-TCDD ND 1.0
Cone= Concentration (Totals include 2,3,7,8-substituted isomers).
EMPC = Estimated Maximum Possible Concentration
RL = Reporting Limit
Internal
Standards
2,3,7,8-TCDD-13C
Recovery Standard
1,2,3,4-TCDD-13C
Cleanup Standard
2,3,7,8-TCDD-37Cl4
ND = Not Detected
NA = Not Applicable
NC = Not Calculated
Results reported on a dry weight basis and are valid to no more than 2 significant figures.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Report No ..... 10116961_ 1613
ng's
Added
2.00
2.00
0.20
Percent
Recovery
82
NA
81
Page 20 of 25
ace Analvtical·
Method 1613B Blank Analysis Results
Lab Sample ID BLANK-22591
Filename U91128A_08
Total Amount Extracted 10.0 g
ICALID U91029
CCal Filename(s) U91128A_02
Native Cone EMPC RL
Isomers ng/Kg ng/Kg ng/Kg
2,3,7,8-TCDD ND 1.0
Cone;:: Concentration (Totals include 2,3,7,8-substituted isomers).
EMPC = Estimated Maximum Possible Concentration
RL :;; Reporting Limit
Matrix
Dilution
Extracted
Analyzed
Injected By
Internal
Standards
2,3,7,8-TCDD-13C
Recovery Standard
1,2,3.4-TCDD-13C
Cleanup Standard
2,3,7,8-TCDD-37Cl4
Results reported on a dry weight basis and are valid to no more than 2 significant figures.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Report No ..... 10116961_1613
Pace Analytical Services, Inc.
1700 Elm Street-Suite 200
Minneapolis, MN 55414
Tel: [phone]
Fax· 612-607-6444
Solid
NA
11/23/2009 20:00
11/28/2009 18:41
BAL
ng's Percent
Added Recovery
2.00 82
2.00 NA
0.20 79
Page 21 of 25
ace Analvtica("
Pace Analytical Services, Inc.
1700 Elm Street -Suite 200
Minneapolis, MN 55414
Tel: [phone]
fax· 612-607-6444
Method 1613B Laboratory Control Spike Results
Lab Sample ID
Filename
Total Amount Extracted
ICALID
CCal Filename
Method Blank ID
Compound
2,3,7,8-TCDD
2,3,7,8-TCDD-37Cl4
2,3, 7,8-TCDD-13C
LCS-22592
F91126A_01
10.0g
F91106
F91125B_15
BLANK-22591
Cs
10
10
100
Cs= Concentration Spiked (ng/ml)
Cr = Concentration Recovered (ng/ml)
Rec. = Recovery (Expressed as Percent)
Cr
9.5
7.6
79
Control Limit Reference: Method 1613, Table 6, 10/94 Revision
R = Recovery outside of control limits
Nn = Value obtained from additional analysis
* = See Discussion
Matrix
Dilution
Extracted
Analyzed
Injected By
Lower
Limit
7.3
3.7
25.0
Solid
NA
11123/2009 20:00
11/26/2009 08:16
BAL
Upper %
Limit Rec.
14.6 95
15.8 76
141.0 79
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc
Report No ..... 10116961 1613 Page 22 of 25
ace Analvtica("
Pace Analytical Services, Inc.
1700 Elm Street -Suite 200
Minneapolis, MN 55414
Tel: [phone]
Fax-612-607-6444
Client's Sample ID
Lab Sample ID
Filename
Total Amount Extracted
ICALID
CCal Filename(s)
Method Blank ID
Native
Isomers
2,3,7,8-TCDD
Qs = Quantity Spiked
Method 1613B Blank Analysis Results
Client -PASI Charlotte
HA-1-MS
9257362001-MS
F91126A_02
11.6 g
F91106
F91125B_15
BLANK-22591
Qs Qm %
(ng) (ng) Rec,
0.20 0.20 98
Qm = Quantity Measured
Solid
NA
Matrix
Dilution
Extracted
Analyzed
Injected By
11/23/2009 20:00
11/26/2009 09:04
BAL
Internal
Standards
2,3,7,8-TCDD-13C
1,2,3,4-TCDD-13C
2,3,7,8-TCDD-37Cl4
ng's Percent
Added Recovery
2.00 83
2.00 NA
0.20 80
Rec. ;::; Recovery (Expressed as Percent)
Results reported on a dry weight basis and are valid to no more than 2 significant figures.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc
Report No ..... 10116961 1613 Page 23 of 25
Pace Analytical Services, Inc.
1700 Elm Street -Suite 200
Minneapolis, MN 55414
ace Analvtica(" Tel: [phone]
Ear 612-607·6444
Client's Sample ID
Lab Sample ID
Filename
Total Amount Extracted
ICALID
CCal Filename(s)
Method Blank ID
Native
Isomers
2,3,7,8-TCDD
Qs = Quantity Spiked
Method 1613B Blank Analysis Results
Client -PASI Charlotte
HA-1-MSD
9257362001-MSD
F91126A_03
11.7 g
F91106
F91125B_15
BLANK-22591
Qs Qm %
(ng) (ng) Rec.
0.20 0.20 102
Qm = Quantity Measured
Solid
NA
Matrix
Dilution
Extracted
Analyzed
Injected By
11/23/2009 20:00
11/26/2009 09:51
BAL
Internal
Standards
2,3,7,8-TCDD-13C
1,2,3,4-TCDD-13C
2,3,7,8-TCDD-37Cl4
ng's Percent
Added Recovery
2.00 77
2.00 NA
0.20 77
Rec. = Recovery (Expressed as Percent)
Results reported on a dry weight basis and are valid to no more than 2 significant figures.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Report No ..... 10116961_1613 Page 24 of 25
Pace Analytical Services, Inc.
1700 Elm Street -Suite 200
Minneapolis, MN 55414
ace Analvtica(" Tel: [phone]
Fax: [phone]
Client Sample ID
Lab Sample ID
MS ID
MSDID
Analyte
2;3,7,8-TCDD
Definitions
MS = Matrix Spike
HA-1
9257362001
9257362001-MS
9257362001-MSD
Sample Cone.
ng/Kg
0.000
MSD = Matrix Spike Duplicate
Om = Quantity Measured
Qs = Quantity Spiked
% Rec. = Percent Recovery
RPO = Relative Percent Difference
NA= Not Applicable
NC = Not Calculated
Report No ..... 10116961_ 1613
Method 1613 Spike Sample Results
Client -PASI Charlotte
Sample Filename
MS Filename
MSD Filename
MS/MSD Qs
(ng)
MSQm
(ng)
0.20 0.20
COD = Chlorinated dibenzo-p-dioxin
GDF= Chlorinated dibenzo-p-furan
T = Tetra
Pe= Penta
Hx = Hexa
Hp= Hepta
0 = Octa
U91128A 11
F91126A-02
F91126A=03
MSDQm
(ng)
0.20
RPD
3.7
Ory Weights
Sample Amount
MS Amount
MSDAmount
9.49 g
9.6 g
9.7 g
Background Subtracted
MS % Rec. MSD % Rec.
98 102
Page 25 of 25
RPD
3.7
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
December 04, 2009
Ms. Amy Conchas
ECS
7211 Ogden Business Park
Suite 201
Wilmington, NC 28411
RE: Project: CASTLE HAYNE 22-124930
Pace Project No.: 9257362
Dear Ms. Conchas:
Enclosed are the analytical results for sample(s) received by the laboratory on November 12, 2009.
The results relate only to the samples included in this report. Results reported herein conform to the
most current NE LAC standards, where applicable, unless otherwise narrated in the body of the
report.
Inorganic Wet Chemistry and Metals analyses were performed at our Pace Asheville laboratory and
Organic testing was performed at our Pace Huntersville laboratory unless otherwise footnoted. All
Microbiological analyses were performed at the laboratory where the samples were received.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Oslicy1f 4SI
Ashley Nifong
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
.. ~1'f_!·~~~ .. 11nelact,
Page 1 of 81
Project: CASTLE HAYNE 22-12493D
Pace Project No.: 9257362
Ormond Beach Certification IDs
Nevada Certification: FL NELAC Reciprocity
Michigan Certification#: 9911
New Jersey Certification #: FL 765
New York Certification #: 11608
North Carolina Certification#: 12710
Pennsylvania Certification#: 68-547
Puerto Rico Certification#: FL01264
Tennessee Certification#: TN02974
Texas Certification: FL NELAC Reciprocity
Virginia Certification#: 00432
Wyoming Certification: FL NELAC Reciprocity
8 East Tower Circle Ormond Beach, FL 32174
Montana Certification #: Cert 007 4
Mississippi Certification: FL NELAC Reciprocity
Charlotte Certification IDs
Connecticut Certification#: PH-0104
Florida/NELAP Certification#: E87627
Kentucky UST Certification#: 84
Louisiana/LELAP Certification #: 04034
New Jersey Certification#: NC012
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification#: 5342
North Carolina Wastewater Certification #: 12
Asheville Certification IDs
Florida/NELAP Certification #: E87648
Connecticut Certification#: PH-0106
Massachusetts Certification#: M-NC030
New Jersey Certification#: NC011
North Carolina Bioassay Certification #: 9
North Carolina Drinking Water Certification#: 37712
North Carolina Wastewater Certification #: 40
Pennsylvania Certification#: 68-03578
Pace Analytical Services, Inc.
2225 Riverside Dr.
CERTIFICATIONS
Asheville, NC 28804
[phone]
Alabama Certification #: 41320
Arizona Certification #: AZ0735
Colorado Certification: FL NELAC Reciprocity
Connecticut Certification#: PH 0216
Florida Certification #: E83079
Georgia Certification#: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Kansas Certification#: E-10383
Kentucky Certification #: 90050
Louisiana Certification#: LA090012
Maine Certification#: FL 1264
Massachusetts Certification #: M-FL 1264
New Hampshire Certification#: 2958
Pennsylvania Certification#: 68-00784
South Carolina Certification#: 990060001
South Carolina Drinking Water Cert.#: 990060003
Tennessee Certification#: 0401 O
Virginia Certification#: 00213
9800 Kincey Ave. -Ste 100 Huntersville, NC 28078
West Virginia Certification#: 357
South Carolina Bioassay Certification #: 99030002
South Carolina Certification#: 99030001
Tennessee Certification #: 2980
Virginia Certification#: 00072
West Virginia Certification#: 356
2225 Riverside Dr. Asheville, NC 28804
Louisiana/LELAP Certification#: 03095
REPORT OF LABORATORY ANALYSIS
This report shall not be r"'eproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
. s0tie,,_,,_,_
11□eldCr,
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 81
Project: CASTLE HAYNE 22-124930
Pace Project No.: 9257362
Lab ID Sample ID
9257362001 HA-1
9257362002 HA-2
9257362003 HA-3
9257362004 HA-4
9257362005 HA-5
9257362006 HA-6
9257362007 HA-7
9257362008 HA-8
9257362009 HA-9
9257362010 HA-10
Pace Analytical Services, Inc.
2225 Riverside Or.
SAMPLE ANALYTE COUNT
Asheville, NC 28804
[phone]
Method Analysts
ASTM 0297 4-87 KOF
EPA 6010 JMW
EPA8260 OLK
EPA8270 EAO
ASTM 0297 4-87 KOF
EPA 6010 JMW
EPA8260 OLK
EPA8270 EAO
ASTM 0297 4-87 KOF
EPA 6010 JMW
EPA8260 OLK
EPA8270 EAO
ASTM 0297 4-87 KOF
EPA 6010 JMW
EPA8260 OLK
EPA8270 EAO
ASTM 0297 4-87 KOF
EPA 6010 JMW
EPA 8260 OLK
EPA 8270 EAO
ASTM 02974-87 KOF
EPA6010 JMW
EPA 8260 OLK
EPA 8270 EAO
ASTM 0297 4-87 KOF
EPA6010 JMW
EPA 8260 OLK
EPA 8270 EAO
ASTM 02974-87 KOF
EPA6010 JMW
EPA8260 OLK
EPA 8270 EAO
ASTM 02974-87 KOF
EPA6010 JMW
EPA 8260 OLK
EPA 8270 EAO
ASTM 0297 4-87 KOF
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
._.,-ff~.c~~~,. 11nelac1;
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Analytes
Reported Laboratory
PASI-C
11 PASI-A
71 PASI-C
72 PASl-0
PASI-C
11 PASI-A
71 PASI-C
72 PASl-0
PASI-C
11 PASI-A
71 PASI-C
72 PASl-0
PASI-C
11 PASI-A
71 PASI-C
72 PASl-0
PASI-C
11 PASJ-A
71 PASI-C
72 PASl-0
PASI-C
11 PASI-A
71 PASI-C
72 PASl-0
PASI-C
11 PASI-A
71 PASI-C
72 PASl-0
PASI-C
11 PASI-A
71 PASI-C
72 PASl-0
PASI-C
11 PASI-A
71 PASI-C
72 PASl-0
PASI-C
Page 3 of 81
Project: CASTLE HAYNE 22-124930
Pace Project No.: 9257362
Lab ID Sample ID
9257362011 HA-11
9257362012 HA-12
Paco Analytical Services, Inc.
2225 Riverside Dr.
SAMPLE ANALYTE COUNT
Asheville, NC 28804
[phone]
Method Analysts
EPA6010
EPA 8260
EPA 8270
ASTM 02974-87
EPA6010
EPA 8260
EPA8270
ASTM 02974-87
EPA6010
EPA 8260
EPA 8270
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
-•~"'-'{.'-',,
.,:,1/) ·~ 1<>~ 11nek:1C\,
JMW
OLK
EAO
KOF
JMW
OLK
EAO
KOF
JMW
OLK
EAO
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704 )875-9092
Analytes
Reported Labo_ratory
11 PASI-A
71 PASI-C
72 PASl-0
PASI-C
11 PASI-A
71 PASI-C
72 PASl-0
PASI-C
11 PASI-A
71 PASI-C
72 PASl-0
Page 4 of 81
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, lnc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: CASTLE HAYNE 22-12493D
Pace Project No.: 9257362
Sample: HA-1 LablD: 9257362001 Collected: 11/11/09 10:30 Received: 11/12/09 09:10 Matrix: Solid
Results reported on a "dry-weight" basis
Parameters
6010 MET ICP
Aluminum
Antimony
Arsenic
Beryllium
Chromium
Copper
Iron
Lead
Nickel
Thallium
Zinc
8270 MSSV Full List Microwave
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b )fluoranthene
Benzo(g, h, i)peryle ne
Benzo(k)fluoranthene
4-Bromophenylphenyl ether
Butylbenzylphthalate
4-Chloro-3-methylphenol
4-Chloroanlline
bis(2-Chloroethoxy)methane
bis(2-Chloroethyl) ether
bis(2-Chloroisopropyl) ether
2-Chloronaphthalene
2-Chlorophenol
4-Chlorophenylphenyl ether
Chrysene
D iben z( a, h )a nth racene
Dibenzofuran
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
3, 3'-Dichlorobenzidine
2,4-Dichlorophenol
Diethylphthalate
2,4-Dimethylphenol
Dimethylphthalate
Di-n-butylphthalate
4,6-Dinitro-2-methylphenol
2,4-Dinitrophenol
2,4-Dinitrotoluene
Date: 12/04/2009 11 :18 AM
Results Units Report Limit DF Prepared
Analytical Method: EPA 6010 Preparation Method: EPA 3050
918 mg/kg 7.9 11/16/09 11:05
ND mg/kg 0.39 11/16/09 11:05
0.39 mg/kg 0.39 11/16/0911:05
ND mg/kg 0.079 11/16/0911:05
1.2 mg/kg 0.39 11/16/09 11:05
ND mg/kg 0.39 11/16/09 11:05
395 mg/kg 3.9 11/16/09 11:05
4.7 mg/kg 0.39 11/16/09 11:05
0.42 mg/kg 0.39 11/16/09 11:05
ND mg/kg 0.79 11/16/0911:05
1.1 mg/kg 0.79 11/16/09 11:05
Analytical Method: EPA8270
ND ug/kg 32.6 11/18/09 14:09
ND ug/kg 32.6 11/18/09 14:09
ND ug/kg 32.6 11/18/09 14:09
ND ug/kg 32.6 11/18/09 14:09
ND ug/kg 32.6 11/18/09 14:09
ND ug/kg 32.6 11/18/09 14:09
ND u9/k9 32.6 11/18/09 14:09
ND ug/kg 32.6 11/18/09 14:09
ND ug/kg 168 11/18/09 14:09
ND ug/kg 168 11/18/09 14:09
ND ug/kg 661 11/18/09 14:09
ND ug/kg 168 11/18/09 14:09
ND ug/kg 168 11/18/09 14:09
ND ug/kg 168 11/18/09 14:09
ND ug/kg 168 11/18/09 14:09
ND ug/kg 168 11/18/09 14:09
ND ug/kg 168 11/18/09 14:09
ND ug/kg 168 11/18/09 14:09
ND ug/kg 32.6 11/18/09 14:09
ND ug/kg 32.6 11/18/09 14:09
ND ug/kg 168 11/18/09 14:09
ND ug/kg 168 11/18/09 14:09
ND ug/kg 168 11/18/09 14:09
ND ug/kg 168 11/18/09 14:09
ND ug/kg 661 11/18/09 14:09
ND ug/kg 168 11/18/09 14:09
ND ug/kg 168 11/18/09 14:09
ND ug/kg 168 11/18/09 14:09
ND ug/kg 168 11/18/09 14:09
ND ug/kg 168 11/18/09 14:09
ND ug/kg 661 11/18/09 14:09
ND ug/kg 661 11/18/09 14:09
ND ug/kg 168 11/18/09 14:09
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
~.,7f'·"~~~~ ?1nelaei,
Analyzed CAS No.
11/18/09 15:06 7429-90-5
11/18/0915:06 7440.-36-0
11/18/09 15:06 7440-38-2
11/18/09 15:06 7440-41-7
11/18/09 15:06 7440-47-3
11/18/09 15:06 7440-50-8
11/18/0915:06 7439-89-6
11/18/0915:06 7439-92-1
11/18/09 15:06 7440-02-0
11/18/09 15:06 7440-28-0
11/18/09 15:06 7440-66-6
11/25/09 16:09 83-32-9
11/25/09 16:09 208-96-8
11/25/09 16:09 120-12-7
11 /25/09 16:09 56-55-3
11125/09 16:09 50-32-8
11/25/09 16:09 205-99-2
11/25/09 16:09 191-24-2
11/25/0916:09 207-08-9
11/25/09 16:09 101-55-3
11 /25/09 16:09 85-68-7
11/25/09 16:09 59-50-7
11125/09 16:09 106-47-8
11/25/09 16:09 111-91-1
11/25/09 16:09 111-44-4
11/25/09 16:09 108-60-1
11/25/09 16:09 91-58-7
11/25/09 16:09 95-57-8
11/25/09 16:09 7005-72-3
11 /25/09 16:09 218-01-9
11 /25/09 16:09 53-70-3
11/25/09 16:09 132-64-9
11/25/09 16:09 95-50-1
11/25/0916:09 541-73-1
11/25/09 16:09 106-46-7
11 /25/09 16:09 91-94-1
11/25/09 16:09 120-83-2
11/25/09 16:09 84-66-2
11/25/09 16:09 105-67-9
11/25/09 16:09 131-11-3
11/25/09 16:09 84-74-2
11/25/09 16:09 534-52-1
11/25/09 16:09 51-28-5
11/25/09 16:09 121-14-2
Qual
L3
L3
L3
L3
Page 5 of 81
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
{828)254-7176
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
{704)875-9092
Project: CASTLE HAYNE 22-12493D
Pace Project No.: 9257362
Sample: HA-1 LablD: 9257362001 Collected: 11/11/09 10:30 Received: 11/12/09 09:10 Matrix: Solid
Results reported on a "dry-weight" basis
Parameters
8270 MSSV Full List Microwave
2,6-Dinitrotoluene
Di-n-octylphthalate
1,2-Diphenylhydrazine
bis(2-Ethylhexyl)phthalate
Fluoranthene
Fluorene
Hexachloro-1,3-butadiene
Hexachlorobenzene
Hexachlorocyclopentadiene
Hexachloroethane
lndeno(1,2,3-cd)pyrene
lsophorone
1-Methylnaphthalene
2-Methylnaphthalene
2-Methylphenol(o-Cresol)
3&4-Methylphenol(m&p Cresol)
Naphthalene
2-Nitroaniline
3-Nitroaniline
4-Nitroaniline
Nitrobenzene
2-Nitrophenol
4-Nitrophenol
N-Nitrosodimethylamine
N-Nitroso-di-n-propylamine
N-Nitrosodiphenylamine
Pentachloropheno1
Phenanthrene
Phenol
Pyrene
1,2,4-Trichlorobenzene
2,4,5-Trichlorophenol
2 ,4, 6-T rich lorophenol
Nitrobenzene-d5 ($)
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
Phenol-c:16 (S)
2-Fluorophenol (S)
2,4,6-Tribromophenol (S)
8260/50~5A Volatile Organics
Acetone
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Date: 12/04/2009 11: 18 AM
Results Units Report Limit DF Prepared
Analytical Method: EPA 8270
ND ug/kg 168 11/18/0914:09
ND ug/kg 168 11/18/0914:09
ND ug/kg 168 11/18/09 14:09
ND ug/kg 168 11/18/09 14:09
, ND ug/kg 32.6 11/18/09 14:09
ND ug/kg 32.6 11/18/09 14:09
ND ug/kg 168 11/18/0914:09
ND ug/kg 168 11/18/09 14:09
ND ug/kg 661 11/18/09 14:09
ND ug/kg 168 11/18/09 14:09
ND ug/kg 32.6 11/18/09 14:09
ND ug/kg 168 11/18/09 14:09
ND ug/kg 32.6 11/18/0914:09
ND ug/kg 32.6 11/18/09 14:09
ND ug/kg 168 11/18/09 14:09
ND ug/kg 168 11/18/09 14:09
ND ug/kg 32.6 11/18/09 14:09
ND ug/kg 168 11/18/09 14:09
ND ug/kg 168 11/18/0914:09
ND ug/kg 168 11/18/0914:09
ND ug/kg 168 11/18/09 14:09
ND ug/kg 168 11/18/09 14:09
ND ug/kg 168 11/18/09 14:09
ND ug/kg 168 11/18/09 14:09
ND ug/kg 168 11/18/09 14:09
ND ug/kg 168 11/18/09 14:09
ND ug/kg 661 11/18/0914:09
ND ug/kg 32.6 11/18/09 14:09
ND ug/kg 168 11/18/09 14:09
NO ug/kg 32.6 11/18/09 14:09
ND ug/kg 168 11/18/09 14:09
ND ug/kg 168 11/18/0914:09
ND ug/kg 168 11/18/0914:09
71 % 10-110 11/18/0914:09
72 % 18-110 11/18/09 14:09
84 % 10-123 11/18/09 14:09
69 % 10-110 11/18/09 14:09
70 % 18-110 11/18/09 14:09
75 % 10-110 11/18/09 14:09
Analytical Method: EPA 8260
ND ug/kg 98.7
ND ug/kg 4.9
ND ug/kg 4.9
ND ug/kg 4.9
ND ug/kg 4.9
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
_.,;fl"-::,,
;'1□eldC1\
Analyzed CAS No.
11/25/09 16:09 606-20-2
11/25/09 16:09 117-84-0
11/25/09 16:09 122-66-7
11/25/09 16:09 117-81-7
11/25/09 16:09 20641-0
11/25/09 16:09 86-73-7
11/25/09 16:09 87-68-3
11/25/09 16:09 118-74-1
11/25/09 16:09 77-47-4
11/25/09 16:09 67-72-1
11/25/09 16:09 193-39-5
11/25/09 16:09 78-59-1
11/25/0916:09 90-12-0
11/25/09 16:09 91-57-6
11/25/09 16:09 95-48-7
11/25/09 16:09
11/25/09 16:09 91-20-3
11/25/09 16:09 88-74-4
11/25/09 16:09 99-09-2
11/25/09 16:09 100-01-6
11/25/09 16:09 98-95-3
11/25/09 16:09 88-75-5
11/25/09 16:09 100-02-7
11/25/09 16:09 62-75-9
11/25/09 16:09 621-64-7
11/25/09 16:09 86-30-6
11/25/09 16:09 87-86-5
11/25/09 16:09 85-01-8
11/25/09 16:09 108-95-2
11/25/09 16:09 129-00-0
11/25/09 16:09 120-82-1
11/25/0916:09 95-95-4
11/25/09 16:09 88-06-2
11/25/09 16:09 4165-60-0
11/25/09 16:09 321-60-8
11/25/09 16:09 1718-51-0
11/25/09 16:09 13127-88-3
11/25/09 16:09 367-12-4
11 /25/09 16:09 118-79-6
11/13/09 16:21 67-64-1
11/13/09 16:21 71-43-2
11/13/09 16:21 108-86-1
11/13/09 16:21 74-97-5
11/13/09 16:21 75-27-4
Qual
L1
L3
Page 6 of 81
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Paco Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: CASTLE HAYNE 22-12493D
Pace Project No.: 9257362
Sample: HA-1 LablD: 9257362001 Collected: 11/11/09 10:30 Received: 11/12/09 09:10 Matrix: Solid
Results reported on a "dry-weight" basis
Parameters Results Units Report Limit OF Prepared Analyzed GAS No. Qua1
826D/5035A Volatile Organics Analytical Method: EPA8260
Bromoform ND ug/kg 4.9 11/13/09 16:21 75-25-2
Bromomethane ND ug/kg 9.9 11/13/09 16:21 74-83-9
2-Butanone (MEK) ND ug/kg 98.7 11/13/09 16:21 78-93-3
n-Butylbenzene ND ug/l<g 4.9 11/13/09 16:21 104-51-8
sec-Butylbenzene ND ug/kg 4.9 11/13/0916:21 135-98-8
tert-Butylbenzene ND ug/kg 4.9 11/13/09 16:21 98-06-6
Carbon tetrachloride ND ug/kg 4.9 11/13/09 16:21 56-23-5
Chlorobenzene ND ug/kg 4.9 11/13/09 16:21 108-90-7
Chloroethane ND ug/kg 9.9 11/13/09 16:21 75-00-3
Chloroform ND ug/kg 4.9 11/13/09 16:21 67-66-3
Chloromethane ND u9/l<g 9.9 11/13/09 16:21 74-87-3
2-Chlorotoluene ND ug/kg 4.9 11/13/09 16:21 95-49-8
4-Chlorotoluene ND ug/kg 4.9 11/13/09 16:21 106-43-4
1,2-Dibromo-3-chloropropane ND ug/kg 4.9 11/13/09 16:21 96-12-8
Oibromochloromethane ND ug/kg 4.9 11/13/09 16:21 124-48-1
1,2-Dibromoethane (EOB) ND ug/kg 4.9 11/13/09 16:21 106-93-4
Dibromomethane ND u9/l<g 4.9 11/13/0916:21 74-95-3
1,2-Dichlorobenzene ND ug/kg 4.9 11/13/09 16:21 95-50-1
1,3-Dichlorobenzene NO ug/kg 4.9 11/13/09 16:21 541-73-1
1,4-0ichlorobenzene ND ug/kg 4.9 11/13/09 16:21 106-46-7
Dichlorodifluoromethane ND ug/kg 9.9 11/13/09 16:21 75-71-8
1, 1-0ichloroethane ND ug/kg 4.9 11/13/09 16:21 75-34-3
1,2-Dichloroethane ND ug/kg 4.9 11/13/09 16:21 107-06-2
1, 1-0ichloroethene ND ug/kg 4.9 11/13/09 16:21 75-35-4
cis-1,2-Dichloroethene ND ug/kg 4.9 11/13/0916:21 156-59-2
trans-1,2-Dichloroethene ND ug/kg 4.9 11/13/0916:21 156-60-5
1,2-Dichloropropane ND ug/kg 4.9 11/13/09 16:21 78-87-5
1,3-0ichloropropane ND ug/kg 4.9 11/13/09 16:21 142-28-9
2,2-0ichloropropane ND ug/kg 4.9 11/13/09 16:21 594-20-7
1, 1-Dichloropropene ND ug/kg 4.9 11/13/09 16:21 563-58-6
cis-1,3-0ichloropropene ND ug/kg 4.9 11/13/09 16:21 10061-01-5
trans-1,3-0ichloropropene ND ug/kg 4.9 1· 11/13/09 16:21 10061-02-6
Diisopropyl ether ND ug/kg 4.9 11/13/09 16:21 108-20-3
Ethylbenzene ND ug/kg 4.9 11/13/09 16:21 100-41-4
Hexachloro-1,3-butadiene ND ug/kg 4.9 11/13/09 16:21 87-68-3
2-Hexanone ND ug/kg 49.3 11/13/0916:21 591-78-6
lsopropylbenzene (Cumene) ND ug/kg 4.9 11/13/09 16:21 98-82-8
p-lsopropyltoluene ND ug/kg 4.9 11/13/0916:21 99-87-6
Methylene Chloride NO ug/kg 19.7 11/13/09 16:21 75-09-2
4-Methyl-2-pentanone (MIBK) ND ug/kg 49.3 11/13/0916:21 108-10-1
Methyl-tert-butyl ether ND ug/kg 4.9 11/13/09 16:21 1634-04-4
Naphthalene ND ug/kg 4,9 11/13/0916:21 91-20-3
n-Propylbenzene ND ug/kg 4.9 11/13/0916:21 103-65-1
Styrene ND ug/kg 4.9 11/13/09 16:21 100-42-5
1, 1, 1,2-Tetrachloroethane ND ug/kg 4.9 11/13/09 16:21 630-20-6
1, 1,2,2-Tetrachloroethane ND ug/kg 4.9 11/13/09 16:21 79-34-5
Date: 12/04/2009 11:18AM REPORT OF LABORATORY ANALYSIS Page 7 of 81
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
7:.=_!:'.;~ ,•' l la '• ,1□e o, ·-. ,.
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704 )875-9092
Project: CASTLE HAYNE 22-124930
Pace Project No.: 9257362
Sample: HA-1 LablD: 9257362001 Collected: 11/11/09 10:30 Received: 11/12/09 09:10 Matrix: Solid
Results reported on a "dry-weight" basis
Parameters
8260/5035A Volatile Organics
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1, 1, 1-Trichloroethane
1, 1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl acetate
Vinyl chloride
Xylene (Total)
m&p-Xylene
a-Xylene
Dibromofluoromethane (S)
Toluene-d8 (S)
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Percent Moisture
Percent Moisture
Date: 12/04/2009 11:18AM
Results Units Report Limit DF Prepared
Analytical Method: EPA 8260
ND ug/kg 4.9
ND ug/kg 4.9
ND uglkg 4.9
ND ug/kg 4.9
ND ug/kg 4.9
ND ug/kg 4.9
ND ug/kg 4.9
ND ug/kg 4.9
ND uglkg 4.9
ND ug/kg 4.9
ND ug/kg 4.9
ND ug/kg 49.3
ND ug/kg 9.9
ND ug/kg 9.9
ND ug/kg 9.9
ND ug/kg 4.9
104 % 79-116
97 % 88-110
95 % 74-115
97 % 69-121
Analytical Method: ASTM D2974-87
17.6 % 0.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
,• •Ceo• ~,,.:1-1·~~~~ f1□elao;
Analyzed GAS No.
11113109 16:21 127-18-4
11113109 16:21 108-88-3
11113109 16:21 87-61-6
11113109 16:21 120-82-1
11/13109 16:21 71-55-6
11113109 16:21 79-00-5
11113109 16:21 79-01-6
11113109 16:21 75-69-4
11113109 16:21 96-18-4
11113109 16:21 95-63-6
11/13109 16:21 108-67-8
11/13109 16:21 108-05-4
11113109 16:21 75-01-4
1111310916:21 1330-20-7
11113109 16:21 1330-20-7
11113109 16:21 95-47-6
11113109 16:21 1868-53-7
11113109 16:21 2037-26-5
11113/0916:21 460-00-4
1111310916:21 17060-07-0
11117109 08:54
Qual
Page 8 of 81
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704}875-9092
Project: CASTLE HAYNE 22-12493D
Pace Project No.: 9257362
Sample: HA-2 LablD: 9257362002 Collected: 11/11/09 09:15 Received: 11/12/09 09:10 Matrix: Solid
Results reported on a "dry-weight" basis
Parameters
6010 MET ICP
Aluminum
Antimony
Arsenic
Beryllium
Chromium
Copper
Iron
Lead
Nickel
Thallium
Zinc
8270 MSSV Full List Microwave
Acenaphthene
Acenaphthylene
Anthracene
Benzo{a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo{g,h, i)perylene
Benzo{k)fluoranthene
4-Bromophenylphenyl ether
Butylbenzylphthalate
4-Chloro-3-methylphenol
4-Chloroaniline
bis{2-Chloroethoxy)methane
bis(2-Chloroethyl) ether
bis{2-Chloroisopropyl) ether
2-Chloronaphthalene
2-Chlo_rophenol
4-Ch!orophenylphenyl ether
Chrysene
Dibenz{a, h)anthracene
Dibenzofuran
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
3,3'-Dichlorobenzidine
2,4-Dich!orophenol
Diethylphthalate
2,4-Dimethylphenol
Oimethylphthalate
Di-n-butylphthalate
4,6-Dinitro-2-methylphenol
2,4-Dinitrophenol
2,4-Dinitrotoluene
Date: 12/04/2009 11 :18 AM
Results Units Report Limit OF Prepared
Analytical Method: EPA 6010 Preparation Method: EPA 3050
1460 mg/kg 8.5 11116109 11:05
ND mg/kg 0.42 11116109 11:05
5.8 mg/kg 0.42 11/16/09 11:05
0.63 mg/kg 0.085 11/16/09 11:05
3.6 mg/kg 0.42 11/16/09 11:05
0.66 mg/kg 0.42 11/16/09 11:05
4400 mg/kg 4.2 11116/09 11:05
2.0 mg/kg 0.42 11/16/0911:05
3.7 mg/kg 0.42 11/16/0911:05
ND mg/kg 0.85 11/16/09 11:05
9.8 mg/kg 0.85 11/16/09 11:05
Analytical Method: EPA 8270
ND ug/kg 32.8 11/18/09 14:09
ND ug/k.9 32.8 11/18/09 14:09
ND ug/kg 32.8 11/18/09 14:09
ND ug/kg 32.8 11/18/09 14:09
ND ug/kg 32.8 11/18/09 14:09
ND ug/kg 32.8 11/18/09 14:09
ND ug/kg 32.8 11/18/0914:09
ND ug/kg 32.8 11/18/0914:09
ND ug/kg 169 11/18/09 14:09
ND ug/kg 169 11118109 14:09
ND ug/kg 666 11/18/09 14:09
ND ug/kg 169 11/18/09 14:09
ND ug/kg 169 11/18/09 14:09
ND ug/kg 169 11/18/0914:09
ND ug/kg 169 11/18/09 14:09
ND ug/kg 169 11/18/09 14:09
ND ug/kg 169 11118/09 14:09
ND ug/kg 169 11/18/09 14:09
ND ug/kg 32.8 11/18/09 14:09
ND ug/kg 32.8 11/18/09 14:09
ND ug/kg 169 11/18/09 14:09
ND ug/kg 169 1111810914:09
ND ug/kg 169 11/18/09 14:09
ND ug/kg 169 11/18/09 14:09
NO ug/kg 666 11/18/09 14:09
ND ug/kg 169 11/18/09 14:09
ND ug/kg 169 11/18/09 14:09
ND ug/kg 169 11/18/09 14:09
ND ug/kg 169 11/18/09 14:09
ND ug/kg 169 11/18109 14:09
NO ug/kg 666 11/18/09 14:09
ND ug/kg 666 11/18/09 14:09
ND ug/kg 169 11/18/09 14:09
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
,~~~-~r~ ,•-/1 jj ··-i1De Cl'\
Analyzed GAS No.
11118109 15:09 7429-90-5
11118109 15:09 7440-36-0
11118/09 15:09 7440-38-2
11/18/0915:09 7440-41-7
11 /18/09 15:09 7440-47-3
11/18/09 15:09 7440-50-8
11118/09 15:09 7439-89-6
11118/09 15:09 7439-92-1
11118/09 15:09 7440-02-0
11/18/09 15:09 7440-28-0
11/18/09 15:09 7440-66-6
11/25/09 17:38 83-32-9
11/25/09 17:38 208-96-8
11/25/09 17:38 120-12-7
11/25/09 17:38 56-55-3
11/25/09 17:38 50-32-8
11125/09 17:38 205-99-2
11/25/09 17:38 191-24-2
11/25/09 17:38 207-08-9
11/25/09 17:38 101-55-3
11125/0917:38 85-68-7
11/25/09 17:38 59-50-7
11/25/09 17:38 106-47-8
11/25/09 17:38 111-91-1
11125/09 17:38 111-44-4
11/25/09 17:38 108-60-1
11/25/09 17:38 91-58-7
11/25/09 17:38 95-57-8
11/25/09 17:38 7005-72-3
11/25/09 17:38 218-01-9
11/25/09 17:38 53-70-3
11/25/09 17:38 132-64-9
11/25/09 17:38 95-50-1
11125109 17:38 541-73-1
11/25/09 17:38 106-46-7
11/25/09 17:38 91-94-1
11/25/09 17:38 120-83-2
11/25/09 17:38 64-66-2
11/25/09 17:38 105-67-9
11125/09 17:38 131-11-3
11/25/09 17:38 84-74-2
11/25/09 17:38 534-52-1
11/25/09 17:38 51-28-5
11/25/09 17:38 121-14-2
Oual
L3
L3
L3
L3
Page 9 of 81
Paco Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704 }875-9092
Project CASTLE HAYNE 22-12493D
Pace Project No.: 9257362
Sample: HA-2 LablD: 9257362002 Collected: 11/11/09 09:15 Received: 11/12/09 09:10 Matrix: Solid
Results reported on a "dry-weight" basis
Parameters
8270 MSSV Full List Microwave
2,6-Dinitrotoluene
Di-n-octylphthalate
1,2-Diphenylhydrazine
bis(2-Ethylhexyl)phthalate
Fluoranthene
Fluorene
Hexachloro-1,3-butadiene
Hexachlorobenzene
Hexachlorocyclopentadiene
Hexachloroethane
lndeno(1,2,3-cd)pyrene
lsophorone
1-Methylnaphthalene
2-Methylnaphthalene
2-Methylphenol(o-Cresol)
3&4-Methylphenot(m&p Cresol)
Naphthalene
2-Nitroaniline
3-Nitroaniline
4-Nitroaniline
Nilrobenzene
2-Nitrophenol
4-Nitrophenol
N-Nitrosodimethylamine
N-Nitroso-di-n-propylamine
N-Nitrosodiphenylamine
Pentachlorophenol
Phenanthrene
Phenol
Pyrene
1,2,4-Trichlorobenzene
2,4,5-Trichlorophenol
2,4,6-Trichlorophenol
Nitrobenzene-d5 (S)
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
Phenol-dB (S)
2-Fluorophenol (S)
2,4,6-Tribromophenol (S)
8260/5035A Volatile Organics
Acetone
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Date: 12/04/2009 11: 18 AM
Results Units Report Limit DF Prepared
Analytical Method: EPA8270
ND ug/kg 169 11/18/09 14:09
ND ug/kg 169 11/18/09 14:09
ND ug/kg 169 11/18/09 14:09
ND ug/kg 169 11/18/09 14:09
ND ug/kg 32.8 11/18/09 14:09
ND ug/kg 32.8 11/18/09 14:09
ND ug/kg 169 11/18/09 14:09
ND ug/kg 169 11/18/09 14:09
NO ug/kg 666 11/18/09 14:09
ND ug/kg 169 11/18/09 14:09
ND ug/kg 32.8 11/18/09 14:09
ND ug/kg 169 11/18/09 14:09
ND ug/kg 32.8 11/18/09 14:09
ND ug/kg 32.8 11/18/09 14:09
ND ug/kg 169 11/18/09 14:09
ND ug/kg 169 11/18/0914:09
ND ug/kg 32.8 11/18/0914:09
ND ug/kg 169 11/18/09 14:09
ND ug/kg 169 11/18/09 14:09
ND ug/kg 169 11/18/09 14:09
ND ug/kg 169 11/18/09 14:09
ND ug/kg 169 11/18/09 14:09
ND ug/kg 169 11/18/0914:09
ND ug/kg 169 11/18/09 14:09
ND ug/kg 169 11/18/09 14:09
ND ug/kg 169 11/18/09 14:09
ND ug/kg 666 11/18/09 14:09
NO ug/kg 32.8 11/18/09 14:09
ND ug/kg 169 11/18/09 14:09
ND ug/kg 32.8 11/18/09 14:09
ND ug/kg 169 11/18/09 14:09
ND ug/kg 169 11/18/09 14:09
NO ug/kg 169 11/18/09 14:09
74 % 10-110 11/18/09 14:09
75 % 18-110 11/18/09 14:09
87 % 10-123 11/18/0914:09
75 % 10-110 11/18/09 14:09
73 % 18-110 11/16/09 14:09
80 % 10-110 11/18/09 14:09
Analytical MethOd: EPA8260
ND ugikg 89.7
ND ug/kg 4.5
ND ug/kg 4.5
ND ug/kg 4.5
ND ug/kg 4.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
~s~f---c~~~ 11nelac\;
Analyzed CAS No. Qual
11/25/09 17:38 606-20-2
11/25/09 17:38 117-84-0
11/25/09 17:38 122-66-7
11/25/09 17:38 117-81-7
11/25/09 17:38 206-44-0
11/25/09 17:38 86-73-7
11/25/09 17:38 87-68-3
11/25/0917:38 118-74-1
11/25/09 17:38 77-47-4
11/25/09 17:38 67-72-1
11/25/09 17:38 193-39-5
11/25/09 17:38 78-59-1
11/25/09 17:38 90-12-0
11/25/09 17:38 91-57-6
11/25/09 17:38 95-48-7
11/25/09 17:38 L1
11/25/09 17:38 91-20-3
11/25/09 17:38 88-74-4
11/25/09 17:38 99-09-2
11/25/09 17:38 100-01-6 L3
11/25/09 17:38 98-95-3
11/25/09 17:38 88-75-5
11/25/09 17:38 100-02-7
11/25/09 17:38 62-75-9
11/25/09 17:38 621-64-7
11/25/09 17:38 86-30-6
11/25/09 17:38 87-86-5
11/25/09 17:38 85-01-8
11/25/09 17:38 108-95-2
11/25/09 17:38 129-00-0
11/25/09 17:38 120-82-1
11/25/09 17:38 95-95-4
11/25/09 17:38 88-06-2
11/25/09 17:38 4165-60-0
11/25/09 17:38 321-60-8
11/25/0917:38 1718-51-0
11/25/09 17:38 13127-88-3
11/25/09 17:38 367-12-4
11/25/09 17:38 118-79-6
11/13/09 16:39 67-64-1
11/13/09 16:39 71-43-2
11/13/09 16:39 108-86-1
11/13/09 16:39 74-97-5
11/13/09 16:39 75-27-4
Page 10of81
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704 )875-9092
Project: CASTLE HAYNE 22-12493D
Pace Project No.: 9257362
Sample: HA-2 LablO: 9257362002 Collected: 11/11/09 09:15 Received: 11/12/09 09:10 Matrix: Solid
Results reported on a "dry-weight" basis
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Oual
8260/SOJSA Volatile Organics Analytical Method: EPA 8260
Bromoform ND ug/kg 4.5 11113109 16:39 75-25-2
Bromomethane ND ug/kg 9.0 11113109 16:39 74-83-9
2-Butanone (MEK) ND ug/kg 89.7 11/13/09 16:39 78-93-3
n-Butylbenzene ND ug/kg 4.5 1111310916:39 104-51-8
sec-Butylbenzene ND ug/kg 4.5 11/13/09 16:39 135-98-8
tert-Butylbenzene ND ug/kg 4.5 11113109 16:39 98-06-6
Carbon tetrachloride ND ug/kg 4.5 11/13109 16:39 56-23-5
Chlorobenzene ND ug/kg 4.5 11113109 16:39 108-90-7
Chloroethane ND ug/kg 9.0 11113109 16:39 75-00-3
Chloroform ND ug/kg 4.5 11113/0916:39 67-66-3
Chloromethane ND ug/kg 9.0 11113109 16:39 74-87-3
2-Chlorotoluene ND ug/kg 4.5 11113109 16:39 95-49-8
4-Chlorotoluene ND ug/kg 4.5 11113109 16:39 106-43-4
1,2-Dibromo-3-chloropropane ND ug/kg 4.5 11113109 16:39 96-12-8
Dibromochloromethane NO ug/kg 4.5 11113109 16:39 124-48-1
1,2-Dibromoethane (EDB) ND ug/kg 4.5 1111310916:39 106-93-4
Dibromomethane ND ug/kg 4.5 11113109 16:39 74-95-3
1,2-Dichlorobenzene ND ug/kg 4.5 11113/09 16:39 95-50-1
1,3-Dichlorobenzene ND ug/kg 4.5 11113109 16:39 541-73-1
1,4-Dichlorobenzene ND ug/kg 4.5 11/13/09 16:39 106-46-7
Dichlorodifluoromethane ND ug/kg 9.0 11113109 16:39 75-71-8
1, 1-Dichloroethane ND ug/kg 4.5 11113109 16:39 75-34-3
1,2-Dichloroethane ND ug/kg 4.5 1111310916:39 107-06-2
1 , 1-Dichloroethene ND ug/kg 4.5 1111310916:39 75-35-4
cis-1,2-Dichloroethene ND ug/kg 4.5 11/13/09 16:39 156-59-2
trans-1,2-Dichloroethene ND ug/kg 4.5 11113109 16:39 156-60-5
1,2-Dichloropropane ND ug/kg 4.5 11113109 16:39 78-87-5
1,3-Dichloropropane ND ug/kg 4.5 11/13/09 16:39 142-28-9
2,2-Dichloropropane ND ug/kg 4.5 11113109 16:39 594-20-7
1 , 1-Dich)oropropene ND ug/kg 4.5 11113109 16:39 563-58-6
cis-1,3-Dichloropropene ND ug/kg 4.5 11/13/09 16:39 10061-01-5
trans-1,3-Dichloropropene ND ug/kg 4.5 11113109 16:39 10061-02-6
Diisopropyl ether ND ug/kg 4.5 11113109 16:39 108-20-3
Ethylbenzene ND ug/kg 4.5 11113109 16:39 100-41-4
Hexachloro-1,3-butadiene ND ug/kg 4.5 11113/09 16:39 87-68-3
2-Hexanone ND ug/kg 44.9 11113/09 16:39 591-78-6
lsopropylbenzene (Cumene) ND ug/kg 4.5 11113109 16:39 98-82-8
p-lsopropyltoluene ND ug/kg 4.5 11113109 16:39 99-87-6
Methylene Chloride ND ug/kg 17.9 11113109 16:39 75-09-2
4-Methyl-2-pentanone (MlBK) ND ug/kg 44.9 11/13/09 16:39 108-10-1
Methyl-tert-butyl ether NO ug/kg 4.5 11/13/09 16:39 1634-04-4
Naphthalene ND ug/kg 4.5 11/13/09 16:39 91-20-3
n-Propylbenzene ND ug/kg 4.5 11/13/09 16:39 103-65-1
Styrene ND ug/kg 4.5 11113109 16:39 100-42-5
1, 1, 1,2-Tetrachloroethane ND ug/kg 4.5 11113109 16:39 630-20-6
1, 1,2,2-Tetrachloroethane ND ug/kg 4.5 11/13/09 16:39 79-34-5
Date: 12/04/2009 11 :18 AM REPORT OF LABORATORY ANALYSIS Page 11 of 81
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
,~.'.!--"·~~-
,_Q1/1 la ~~~ itne C\,
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
{828)254-7176
Paco Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
{704}875-9092
Project: CASTLE HAYNE 22-12493D
Pace Project No.: 9257362
Sam pie: HA-2 LablD: 9257362002 Collected: 11/11/09 09:15 Received: 11112/09 09:10 Matrix: Solid
Results reported on a "dry-weight" basis
Parameters
826015035A Volatile Organics
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2.4-Trichlorobenzene
1, 1, 1-Trichloroethane
1, 1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-T rimethylbenzene
1,3,5-Trimethylbenzene
Vinyl acetate
Vinyl chloride
Xylene (Total)
m&p-Xy1ene
o-Xylene
Di~romofluoromethane (S)
Toluene-dB (S)
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Percent Moisture
Percent Moisture
Date: 12/04/2009 11 :18 AM
Results Units Report Limit OF Prepared
Analytical Method: EPA8260
ND ug/kg 4.5
ND u9/k9 4.5
ND ug/kg 4.5
ND ug/kg 4.5
ND ug/kg 4.5
ND u9/k9 4.5
ND ug/kg 4.5
ND u9/k9 4.5
ND ug/kg 4.5
ND ug/kg 4.5
ND ug/kg 4.5
ND ug/kg 44.9
ND ug/kg 9.0
ND u9/k9 9.0
ND ug/kg 9.0
ND ug/kg 4.5
96 % 79-116
97 % 88-110
89 % 74-115
85 % 69-121
Analytical Method: ASTM D2974-87
12.1 % 0.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
~Q«,~~~ 1,oelac,
Analyzed GAS No. Qual
11/13/09 16:39 127-18-4
11/13/09 16:39 108-88-3
11/13/09 16:39 87-61-6
11/13/09 16:39 120-82-1
11/13/09 16:39 71-55-6
11/13/0916:39 79-00-5
11/13/0916:39 79-01-6
11/13/09 16:39 75-69-4
11/13/09 16:39 96-18-4
11/13/09 16:39 95-63-6
11/13/0916:39 108-67-8
11/13/0916:39 108-05-4
11/13/09 16:39 75-01-4
11/13/09 16:39 1330-20-7
11/13/09 16:39 1330-20-7
11/13/09 16:39 95-47-6
11/13/09 16:39 1868-53-7
11/13/09 16:39 2037-26-5
11/13/09 16:39 460-00-4
11/13/0916:39 17060-07-0
11/17/09 08:54
Page 12 of 81
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875--9092
Project: CASTLE HAYNE 22-12493D
Pace Project No.: 9257362
Sample: HA-3 LablD: 9257362003 Collected: 11/11/09 09:00 Received: 11/12/09 09:10 Matrix: Solid
Results reported on a "dry-weight" basis
Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual
6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050
Aluminum 1260 mg/kg 8.8 11116109 11:05 11118109 15:14 7429-90-5
Antimony ND mg/kg 0.44 11116109 11:05 11118109 15:14 7440-36-0
Arsenic 4.7 mg/kg 0.44 11/16/09 11:05 11/18/09 15:14 7440-38-2
Beryllium 0.35 mg/kg 0.088 1111610911:05 11118109 15:14 7440-41-7
Chromium 4.5 mg/kg 0.44 11/16/0911:05 11/18/0915:14 7440-47-3
Copper 0.51 mg/kg 0.44 11116109 11:05 11118109 15:14 7440-50-8
Iron 4320 mg/kg 4.4 11/16/09 11:05 11/18/09 15:14 7439-89-6
Lead 1.4 mg/kg 0.44 11/16/09 11:05 11/18/09 15:14 7439-92-1
Nickel 4.1 mg/kg 0.44 11/16/09 11:05 11118109 15:14 7440-02-0
Thallium ND mg/kg 0.88 11116109 11:05 11/18/09 15:14 7440-28-0
Zinc 11.5 mg/kg 0.88 1111610911:05 11118109 15:14 7440-66-6
8270 MSSV Full List Microwave Analytical Method: EPA8270
Acenaphthene ND ug/kg 37.1 11118109 14:09 11125109 18:08 83-32-9
Acenaphthylene ND ug/kg 37.1 11118/0914:09 11125109 18:08 208-96-8
Anthracene ND ug/kg 37.1 1111810914:09 11/25/09 18:08 120-12-7
Benzo(a)anthracene ND uglkg 37.1 11118109 14:09 11125/0918:08 56-55-3
Benzo(a)pyrene ND ug/kg 37.1 11118109 14:09 11125/09 18:08 50-32-8
Benzo(b)fluoranthene ND ug/kg 37.1 11/18/09 14:09 11125109 18:08 205-99-2
Benzo(g, h, i )perylene ND ug/kg 37.1 11/18/09 14:09 11/25/09 18:08 191-24-2
Benzo(k)fluoranthene ND ug/kg 37.1 11/18/09 14:09 11/25/09 18:08 207-08-9
4-Bromophenylphenyl ether ND ug/kg 191 11118/0914:09 11125109 18:08 101-55-3
Butylbenzylphtha!ate ND ug/kg 191 11/18/09 14:09 11/25/09 18:08 85-68-7
4-Chloro-3-methylphenol ND ug/kg 754 11/18/09 14:09 11/25/09 18:08 59-50-7
4-Chloroaniline ND ug/kg 191 11/18/09 14:09 1112510918:08 106-47-8 L3
bis(2-Chloroethoxy)methane ND ug/kg 191 11/18/09 14:09 11/25/09 18:08 111-91-1
bis(2-Chloroethyl) ether ND ug/kg 191 11/18/09 14:09 11/25/09 18:08 111-44-4
bis(2-Chtoroisopropyl) ether ND ug/kg 191 11/18/09 14:09 11125109 18:08 108-60-1
2-Chloronaphthalene ND ug/kg 191 11118/09 14:09 11/25/09 18:08 91-58-7
2-Chlorophenol ND uglkg 191 11118109 14:09 1112510918:08 95-57-8
4-Chlorophenylphenyl ether ND ug/kg 191 11/18/09 14:09 11125109 18:08 7005-72-3
Chrysene ND ug/kg 37.1 11118109 14:09 11125109 18:08 218-01-9
Dibenz(a,h )anthracene ND ug/kg 37.1 11/18/0914:09 11/25/09 18:08 53-70-3
Dibenzofuran ND uglkg 191 11118/09 14:09 11/25/09 18:08 132-64-9 L3
1,2-Dichlorobenzene ND ug/kg 191 11/18/09 14:09 11125109 18:08 95-50-1 L3
1,3-Dichlorobenzene ND ug/kg 191 11118109 14:09 11125/0918:08 541-73-1 L3
1.4-Dichlorobenzene ND ug/kg 191 11/18/09 14:09 11/25/09 18:08 106-46-7
3,3'-Dichlorobenzidine ND ug/kg 754 11/18/09 14:09 11 /25/09 18:08 91-94-1
2,4-Dichlorophenol ND ug/kg 191 11/18/09 14:09 11 /25/09 1 8:08 120-83-2
Diethylphthalate ND ug/kg 191 11/18/09 14:09 11 /25/09 18:08 84-66-2
2,4-Dimethylphenol ND ug/kg 191 11/18/09 14:09 11125109 18:08 105-67-9
Dimethylphthalate ND ug/kg 191 11/18/09 14:09 11/25/09 18:08 131-11-3
Di-n-butylphthalate ND ug/kg 191 11/18/09 14:09 11/25/09 18:08 84-74-2
4,6-Dinitro-2-methytphenol ND ug/kg 754 11/18/09 14:09 11/25/09 18:08 534-52-1
2,4-Dinitrophenol ND ug/kg 754 11118109 14:09 11/25/09 18:08 51-28-5
2,4-Dinitrotoluene ND ug/kg 191 11/18/09 14:09 11/25/09 18:08 121-14-2
Date: 12/04/200911:18AM REPORT OF LABORATORY ANALYSIS Page 13 of 81
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
,,,:\'"';t_"""--?1nelao.,
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Paco Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project CASTLE HAYNE 22-12493D
Pace Project No.: 9257362
Sample: HA-3 LablO: 9257362003 Collected: 11/11/09 09:00 Received: 11/12/09 09:10 Matrix: Solid
Results reported on a ndry-weightn basis
Parameters
8270 MSSV Full List Microwave
2,6-Dinitrotoluene
Di-n-octylphthalate
1,2-Diphenylhydrazine
bis(2-Ethylhexyl)phthalate
Fluoranthene
Fluorene
Hexachloro-1,3-butadiene
Hexachlorobenzene
Hexachlorocyclopentadiene
Hexachloroethane
1ndeno(1,2,3-cd)pyrene
lsophorone
1-Methylnaphthalene
2-Methylnaphthalene
2-Methylphenol(o-Cresol)
3&4-Methylphenol(m&p Cresci)
Naphthalene
2-Nitroaniline
3-Nitroaniline
4-Nitroaniline
Nitrobenzene
2-Nitrophenol
4-Nitrophenol
N-Nitrosodimethylamine
N-Nitroso-di-n-propylamine
N-Nitrosodiphenylamine
Pentachlorophenol
Phenanthrene
Phenol
Pyrene
1,2,4-Trichlorobenzene
2,4,5-Trichlorophenot
2,4,6-Trichlorophenol
Nitrobenzene-d5 (S)
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
Phenol-d6 (S)
2-Fluorophenol (S)
2,4,6-Tribromophenol (S)
826015035A Volatile Organics
Acetone
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Date: 12/04/2009 11: 18 AM
Results Units Report Limit OF Prepared
Analytical Method: EPA 8270
ND ug/kg 191 11/18/09 14:09
ND u9/k9 191 11/18/0914:09
ND ug/kg 191 11/18/09 14:09
ND u9/k9 191 11/18/09 14:09
ND ug/kg 37.1 11/18/09 14:09
ND u9/k9 37.1 11/18/09 14:09
ND ug/kg 191 11/18/09 14:09
ND u9/k9 191 11/18/09 14:09
ND ug/kg 754 11/18/09 14:09
ND ug/kg 191 11/18/09 14:09
ND ug/kg 37.1 11/18/09 14:09
ND ug/kg 191 11/18/09 14:09
ND ug/kg 37.1 11/18/0914:09
ND ug/kg 37.1 11/18/09 14:09
ND ug/kg 191 11/18/09 14:09
ND ug/kg 191 11/18/09 14:09
ND ug/kg 37.1 11/18/09 14:09
ND ug/kg 191 11/18/09 14:09
ND ug/kg 191 11/18/09 14:09
ND ug/kg 191 11/18/09 14:09
ND ug/kg 191 11/18/09 14:09
ND ug/kg 191 11/18/09 14:09
ND ug/kg 191 11/18/09 14:09
ND ug/kg 191 11/18/09 14:09
ND ug/kg 191 11/18/09 14:09
ND ug/kg 191 11/18/09 14:09
ND ug/kg 754 11/18/09 14:09
ND ug/kg 37.1 11/18/09 14'.09
ND ug/kg 191 11/18/09 14:09
ND ug/kg 37.1 11/18/09 14:09
ND ug/kg 191 11/18/09 14:09
ND ug/kg 191 11/18/09 14:09
ND ug/kg 191 11/18/09 14:09
69 % 10-110 11/18/09 14:09
68 % 18-110 11/18/09 14:09
77 % 10-123 11/18/09 14:09
67 % 10-110 11/18/09 14:09
70 % 18-110 11/18/09 14:09
65 % 10-110 11/18/09 14:09
Analytical Method: EPA 8260
ND ug/kg 98.8
ND ug/kg 4.9
ND ug/kg 4.9
ND ug/kg 4.9
ND ug/kg 4.9
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
. tif-'·~l;,_~~ .. ?,□elac;
Analyzed CAS No. Qual
11/25/09 18:08 606-20-2
11/25/09 18:08 117-84-0
11/25/09 18:08 122-66-7
11 /25/09 18:08 117-81-7
11 /25/09 18:08 206-44-0
11/25/09 18:08 86-73-7
11/2 5/09 18: 08 87-68-3
11/25/09 18:08 118-74-1
11 /25/09 18:08 77-47-4
11 /25/09 18:08 67-72-1
11/25/09 18:08 193-39-5
11/25/09 18:08 78-59-1
11/25/09 18:08 90-12-0
11/25/09 18:08 91-57-6
11/25/0918:08 95-48-7
11125/09 18:08 L3
11 /25/09 18:08 91-20-3
11/25/09 18:08 88-74-4
11/25/09 18:08 99-09-2
11/25/09 18:08 100-01-6 L3
11/25/09 18:08 98-95-3
11/25/0918:08 88-75-5
11/25/09 18:08 100-02-7
11/25/09 18:08 62-75-9
11/25/09 18:08 621-64-7
11/25/0918:08 86-30-6
11 /25/09 1 8:08 87-86-5
11125/09 18:08 85-01-8
11/25/09 18:08 108-95-2
11 /25/09 18:08 129-00-0
11/25/09 18:08 120-82-1
11/25/09 18:08 95-95-4
11/25/09 18:08 88-06-2
11/25/09 18:08 4165-60-0
11/25/0918:08 321-60-8
11/25/09 18:08 1718-51-0
11/25/09 18:08 13127-88-3
11 /25/09 18:08 367-12-4
11/25/09 18:08 118-79-6
11/13/09 17:16 67-64-1
11/13/09 17:16 71-43-2
11/13/09 17:16 108-86-1
11/13/09 17:16 74-97-5
11/13/09 17:16 75-27-4
Page 14 of 61
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: CASTLE HAYNE 22-12493D
Pace Project No.: 9257362
Sample: HA-3 LablD: 9257362003 Collected: 11/11/09 09:00 Received: 11/12/09 09:10 Matrix: Solid
Results reported on a "dry-weight" basis
Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qua1
826015035A Volatile Organics Analytical Method: EPA 8260
Bromoform ND ug/kg 4.9 11/13/09 17:16 75-25-2
Bromomethane ND ug/kg 9.9 11/13/0917:16 74-83-9
2-Butanone (MEK) ND ug/kg 98.8 11/13/09 17:16 78-93-3
n-Butylbenzene ND ug/kg 4.9 11/13/09 17:16 104-51-8
sec-Butylbenzene ND ug/kg 4.9 11/13/09 17:16 135-98-8
tert-Butylbenzene ND ug/kg 4.9 11/13/09 17:16 98-06-6
Carbon tetrachloride ND ug/kg 4.9 11/13/09 17:16 56-23-5
Chlorobenzene ND ug/kg 4.9 11/13/0917:16 108-90-7
Chloroethane ND ug/kg 9.9 11/13/09 17:16 75-00-3
Chlorofonn ND u9/k9 4.9 11/13/09 17:16 67-66-3
Chloromethane ND ug/kg 9.9 11/13/09 17:16 74-87-3
2-Chlorotoluene ND ug/kg 4.9 11/13/09 17:16 95-49-8
4-Chlorotoluene ND ug/kg 4.9 11/13/09 17:16 106-43-4
1,2-Dibromo-3-chloropropane ND u9/k9 4.9 11/13/09 17:16 96-12-8
Dibromochloromethane ND ug/kg 4.9 11/13/0917:16 124-48-1
1,2-Dibromoethane (EDB) ND ug/kg 4.9 11/13/09 17:16 106-93-4
Dibromomethane ND ug/kg 4.9 11/13/09 17:16 74-95-3
1,2-Dichlorobenzene ND ug/kg 4.9 11/13/09 17:16 95-50-1
1,3-Dichlorobenzene ND ug/kg 4.9 11/13/09 17:16 541-73-1
1,4-Dichlorobenzene ND ug/kg 4.9 11/13/09 17:16 106-46-7
Dichlorodifluoromethane ND ug/kg 9.9 11/13/09 17:16 75-71-8
1, 1-Dichloroethane ND u9/k9 4.9 11/13/09 17:16 75-34-3
1,2-Dichloroethane ND ug/kg 4.9 11/13/09 17:16 107-06-2
1, 1-Dichloroethene ND u9/k9 4.9 11/13/09 17:16 75-35-4
cis-1,2-Dichloroethene ND ug/kg 4.9 11/13/0917:16 156-59-2
trans-1,2-Dichloroethene ND ug/kg 4.9 11/13/0917:16 156-60-5
1,2-Dichloropropane ND ug/kg 4.9 11/13/09 17:16 78-87-5
1,3-Dichloropropane ND ug/kg 4.9 11/13/09 17:16 142-28-9
2,2-Dichloropropane ND u9/k9 4.9 11/13/09 17:16 594-20-7
1, 1-Dichloropropene ND ug/kg 4.9 11/13/0917:16 563-58-6
cis-1,3-Dichloropropene ND ug/kg 4.9 11/13/09 17:16 10061-01-5
trans-1,3-Dichloropropene ND ug/kg 4.9 11/13/09 17:16 10061-02-6
Diisopropyl ether ND ug/kg 4.9 11/13/09 17:16 108-20-3
Ethyl benzene ND ug/kg 4.9 11/13/09 17:16 100-41-4
Hexachloro-1,3-butadiene ND ug/kg 4.9 11/13/09 17:16 87-68-3
2-Hexanone ND ug/kg 49.4 11/13/09 17:16 591-78-6
lsopropylbenzene (Cumene) ND ug/kg 4.9 11/13/09 17:16 98-82-8
p-lsopropyltoluene ND ug/kg 4.9 11/13/0917:16 99-87-6
Methylene Chloride ND ug/kg 19.8 11/13/09 17:16 75-09-2
4-Methyl-2-pentanone (MIBK) ND ug/kg 49.4 11/13/09 17:16 108-10-1
Methyl-tert-butyl ether ND ug/kg 4.9 11/13/09 17:16 1634-04-4
Naphthalene ND ug/kg 4.9 11/13/09 17:16 91-20-3
n-Propylbenzene ND ug/kg 4.9 11/13/09 17:16 103-65-1
Styrene ND ug/kg 4.9 11/13/0917:16 100-42-5
1, 1, 1,2-Tetrachloroethane ND ug/kg 4.9 11/13/09 17:16 630-20-6
1, 1,2,2-Tetrachloroethane ND ug/kg 4.9 11/13/09 17:16 79-34-5
Date: 12/04/2009 11: 18 AM REPORT OF LABORATORY ANALYSIS Page 15 of 81
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
. s\''it"• ?1□e Ci',
Paco Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704 )875-9092
Project: CASTLE HAYNE 22-124930
Pace Project No.: 9257362
Sample: HA-3 LablD: 9257362003 Collected: 11/11/09 09:00 Received: 11/12/09 09;10 Matrix: Solid
Results reported on a "dry-weight" basis
Parameters
8260/5035A Volatile Organics
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1, 1, 1-Trichloroethane
1, 1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl acetate
Vinyl chloride
Xylene (Total)
m&p-Xylene
a-Xylene
Dibromofluoromethane (S)
Toluene-dB (S)
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Percent Moisture
Percent Moisture
Date: 12/04/2009 11:18AM
Results Units Report Limit OF Prepared
Analytical Method: EPA 8260
ND ug/kg 4.9
ND ug/kg 4.9
ND ug/kg 4.9
ND ug/kg 4.9
ND ug/kg 4.9
ND ug/kg 4.9
ND ug/kg 4.9
ND ug/kg 4.9
ND ug/kg 4.9
ND ug/kg 4.9
ND ug/kg 4.9
ND ug/kg 49.4
ND ug/kg 9.9
ND ug/kg 9.9
ND ug/kg 9.9
ND ug/kg 4.9
102 % 79-116
94 % 88-110
86 % 74-115
97 % 69-121
Ancllytical Method: ASTM 02974-8"(
11.4 % 0.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
~Q-9f1·t~~~ 11ne1c10\
Analyzed CAS No. Qual
11/13/09 17:16 127-18-4
11/13/09 17:16 108-88-3
11/13/0917:16 87-61-6
11/13/0917:16 120-82-1
11/13/09 17:16 71-55-6
11/13/09 17:16 79-00-5
11/13/09 17:16 79-01-6
11/13/09 17:16 75-69-4
11/13/09 17:16 96-18'4
11/13/09 17:16 95-63-6
11/13/09 17:16 108-67-8
11/13/09 17:16 108-05-4
11/13/09 17:16 75-01-4
11/13/09 17:16 1330-20-7
11/13/09 17:16 1330-20-7
11/13/0917:16 95-47-6
11/13/09 17:16 1868-53-7
11/13/0917:16 2037-26-5
11/13/09 17:16 460-00-4
11/13/09 17:16 17060-07-0
11/17/09 08:54
Page 16 of 81
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704 )875-9092
Project: CASTLE HAYNE 22-12493D
Pace Project No.: 9257362
Sample: HA-4 LablD: 9257362004 Collected: 11/11/09 11:45 Received: 11/12/09 09:10 Matrix: Solid
Results reported on a "dry-weight" basis
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050
Aluminum 522 mg/kg 10.2 11/16109 11:05 11/16/09 15:16 7429-90-5
Antimony ND mg/kg 0.51 1111610911:05 11118109 15:18 7440-36-0
Arsenic ND mg/kg 0.51 11116109 11:05 11118109 15:18 7440-38-2
Beryllium ND mg/kg 0.10 11/16/09 11:05 11118109 15:18 7440-41-7
Chromium 0.71 mg/kg 0.51 11116109 11:05 11118109 15:18 7440-47-3
Copper 0.51 mg/kg 0.51 11/1610911:05 11/16/09 15:18 7440-50-8
Iron 399 mg/kg 5.1 1111610911:05 1111810915:18 7439-89-6
Lead 3.2 mg/kg 0.51 11116109 11:05 11118109 15:18 7439-92-1
Nickel 0.57 mg/kg 0.51 11116109 11:05 11118109 15:18 7440-02-0
Thallium ND mg/kg 1.0 11/16/09 11:05 11/16/09 15:16 7440-28-0
Zinc 2.0 mg/kg 1.0 11116109 11:05 11118109 15:18 7440-66-6
6270 MSSV Full List Microwave Analytical Method: EPA 8270
Acenaphthene ND ug/kg 50.3 11118109 14:09 11125109 18:38 83-32-9
Acenaphthylene ND ug/kg 50.3 11/16/09 14:09 11/25109 18:38 208-96-8
Anthracene ND ug/kg 50.3 11118109 14:09 11125109 18:38 120-12-7
Benzo(a)anthracene ND ug/kg 50.3 11/18/09 14:09 11/25/09 18:36 56-55-3
Benzo(a)pyrene ND ug/1<g 50.3 11118109 14:09 11125109 18:38 50-32-8
Benzo(b)fluoranthene ND ug/kg 50.3 11/16/09 14:09 11/25/09 18:38 205-99-2
Benzo(g, h, i )perylene ND ug/1<g 50.3 11118/09 14:09 11/25109 1 8:38 191-24-2
Benzo(k)fluoranthene ND ug/kg 50.3 11/16/09 14:09 11/25/09 18:38 207-08-9
4-Bromophenylphenyl ether ND ug/kg 259 11/16/09 14:09 11125109 18:38 101-55-3
Butylbenzylphthalate ND ug/kg 259 11118109 14:09 11125/09 18:38 85-68-7
4-Chloro-3-methylphenol ND ug/kg 1020 11/18/09 14:09 11/25/09 18:38 59-50-7
4-Chloroaniline ND ug/kg 259 11118/09 14:09 11125109 18:38 106-47-8 L3
bis(2-Chloroethoxy)methane ND ug/kg 259 11118/09 14:09 11 /25/09 18:38 111-91-1
bis(2-Chloroethyl) ether ND uglkg 259 11/18/09 14:09 11125109 18:38 111-44-4
bis(2-Chloroisopropyl) ether ND ug/kg 259 11/18/09 14:09 11125109 18:38 108-60-1
2-Chloronaphthalene ND ug/kg 259 11118109 14:09 11/25/09 18:38 91-58-7
2-Chlorophenol ND ug/kg 259 11118/09 14:09 11125/09 18:38 95-57-8
4-Chlorophenylphenyl ether ND ug/kg 259 11/18/09 14:09 11/25/09 18:36 7005-72-3
Chrysene ND ug/kg 50.3 11/18/09 14:09 11/25/09 18:38 218-01-9
Dibenz(a,h)anthracene ND ug/kg 50.3 11/18/09 14:09 11/25/09 18:38 53-70-3
Dibenzofuran ND ug/kg 259 11118109 14:09 11125109 18:38 132-64-9 L3
1,2-Dichlorobenzene ND ug/kg 259 11/18/09 14:09 11/25/09 18:38 95-50-1 L3
1.3-Dichlorobenzene ND ug/kg 259 11/18/09 14:09 11125109 1 8:38 541-73-1 L3
1,4-Dichlorobenzene ND ug/kg 259 11/18/09 14:09 11125109 1 8:38 106-46-7
3,3'-Dich!orobenzidine ND ug/kg 1020 11/18/09 14:09 11/25/09 18:38 91-94-1
2,4-Dichlorophenol ND ug/kg 259 11/18/09 14:09 11/25/09 18:38 120-83-2
Diethytphthalate ND ug/kg 259 11/18/09 14:09 11/25/09 18:38 84-66-2
2,4-Dimethylphenol ND ug/kg 259 11/18/09 14:09 11125/09 18:38 105-67-9
Dimethylphthalate ND ug/kg 259 11/18/09 14:09 11/25/09 18:38 131-11-3
Di-n-butylphthalate ND ug/kg 259 11/18/09 14:09 11 /25/09 18:38 84-74-2
4,6-Dinitro-2-methylphenol ND ug/kg 1020 11/18/09 14:09 11/25/09 18:38 534-52-1
2,4-Dinitrophenol ND ug/kg 1020 11/18/09 14:09 11/25/09 18:38 51-28-5
2,4-Dinitrotoluene ND ug/kg 259 11/18/09 14:09 11125109 18:38 121-14-2
Date: 12/04/2009 11 :18 AM REPORT OF LABORATORY ANALYSIS Page 17of81
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
K'fZ""-:., 11nelaci,
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704}875-9092
Project: CASTLE HAYNE 22-12493D
Pace Project No.: 9257362
Sample: HA-4 LablD: 9257362004 Collected: 11/11/09 11:45 Received: 11/12/09 09:10 Matrix: Solid
Results reported on a "dry-weight" basis
Parameters
8270 MSSV Full List Microwave
2,6-Dinitrotoluene
Di-n-octytphthalate
1,2-Diphenylhydrazine
bis(2-Ethylhexyl)phthalate
Fluoranthene
Fluorene
Hexachloro-1,3-butadiene
Hexachlorobenzene
Hexachlorocyclopentadiene
Hexachloroethane
lndeno(1,2,3-cd)pyrene
lsophorone
1-Methylnaphthalene
2-Methylnaphthalene
2-Methylphenol(o-Cresol)
3&4-Methylphenol(m&p Cresci)
Naphthalene
2-Nitroaniline
3-Nitroaniline
4-Nitroaniline
Nitrobenzene
2-Nitrophenol
4-Nitrophenol
N-Nitrosodimethylamine
N-Nitroso-di-n-propylamine
N-Nitrosodiphenylamine
Pentachlorophenol
Phenanthrene
Phenol
Pyrene
1,2,4-Trichlorobenzene
2,4,5-Trichlorophenol
2,4,6-Trichlorophenol
Nitrobenzene-d5 (S)
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
Phenol-dB (S)
2-Fluorophenol (S)
2,4,6-Tribromophenol (S)
8260/5035A Volatile Organics
Acetone
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Date: 12/04/2009 11: 18 AM
Results Units Report Limit DF Prepared
Analytical Method: EPA8270
ND ug/kg 259 11/18/09 14:09
ND ug/kg 259 11/18/09 14:09
ND ug/kg 259 11/18/09 14:09
ND ug/kg 259 11/18/0914:09
ND ug/kg 50.3 11/18/09 14:09
ND ug/kg 50.3 11/18/09 14:09
ND ug/kg 259 11/18/09 14:09
ND ug/kg 259 11/18/09 14:09
ND ug/kg 1020 11/18/09 14:09
ND ug/kg 259 11/18/0914:09
ND u9/k9 50.3 11/18/0914:09
ND ug/kg 259 11/18/09 14:09
ND u9/k9 50.3 11/18/09 14:09
ND ug/kg 50.3 11/18/09 14:09
ND ug/kg 259 11/18/09 14:09
ND ug/kg 259 11/18/09 14:09
ND ug/kg 50.3 11/18/0914:09
ND ug/kg 259 11/18/09 14:09
ND ug/kg 259 11/18/09 14:09
ND ug/kg 259 11/18/09 14:09
ND ug/kg 259 11/18/09 14:09
ND ug/kg 259 11/18/09 14:09
ND ug/kg 259 11/18/0914:09
ND ug/kg 259 11/18/09 14:09
ND ug/kg 259 11/18/09 14:09
ND ug/kg 259 11/18/09 14:09
ND ug/kg 1020 11/18/09 14:09
ND ug/kg 50.3 11/18/09 14:09
ND ug/kg 259 11/18/09 14:09
ND ug/kg 50.3 11/18/09 14:09
ND ug/kg 259 11/18/09 14:09
ND ug/kg 259 11/18/09 14:09
ND ug/kg 259 11/18/09 14:09
73 % 10-110 11/18/0914:09
75 % 18-110 11/18/09 14:09
72 % 10-123 11/18/09 14:09
68 % 10-110 11/18/09 14:09
69 % 18-110 11/18/09 14:09
75 % 10-110 11/18/09 14:09
Analytical Method: EPA8260
ND ug/kg 124
ND ug/kg 6.2
ND ug/kg 6.2
ND ug/kg 6.2
ND ug/kg 6.2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, lnc,. ··""~-. ,•1/'l ~ ,•, s11□e1<1C\i
Analyzed GAS No. Qual
11/25/09 18:38 606-20-2
11/25/09 18:38 117-84-0
11/25/09 18:38 122-66-7
11/25/09 18:38 117-81-7
11/25/09 18:38 206-44-0
11 /25/09 18:38 86-73-7
11/25/09 18:38 87-68-3
11/25/09 18:38 118-74-1
11/25/09 18:38 77-47-4
11/25/09 18:38 67-72-1
11/25/09 18:38 193-39-5
11/25/09 18:38 78-59-1
11/25/09 18:38 90-12-0
11/25/09 18:38 91-57-6
11/25/09 18:38 95-48-7
11/25/09 18:38 L3
11/25/09 18:38 91-20-3
11/25/09 18:38 88-74-4
11/25/09 18:38 99-09-2
11 /25/09 18:38 100-01-6 L3
11/25/09 18:38 98-95-3
11/25/09 18:38 88-75-5
11/25/09 18:38 100-02-7
11/25/09 18:38 62-75-9
11/25/09 18:38 621-84-7
11 /25/09 18:38 86-30-6
11/25/0918:38 87-86-5
11 /25/09 18:38 85-01-8
11/25/09 18:38 108-95-2
11/25/09 18:38 129-00-0
11/25/09 18:38 120-82-1
11/25/09 18:38 95-95-4
11/25/09 18:38 88-06-2
11/25/09 18:38 4165-60-0
11 /25/09 18:38 321-60-8
11 /25/09 1 8:38 1718-51-0
11/25/09 18:38 13127-88-3
11/25/09 18:38 367-12-4
11/25/09 18:38 118-79-6
11/13/0917:34 ,67-64-1
11/13/09 17:34 71-43-2
11/13/09 17:34 108-86-1
11/13/09 17:34 74-97-5
11/13/09 17:34 75-27-4
Page 18 of 81
Pace Analytical Services, lnc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: CASTLE HAYNE 22-12493D
Pace Project No.: 9257362
Sample: HA-4 LablD: 9257362004 Collected: 11/11/09 11:45 Received: 11/12/09 09:10 Matrix: Solid
Results reported on a "dry-weight" basis
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260/5035A Volatile Organics Analytical Method: EPA8260
Bromoform ND ug/l<g 6.2 11/13/09 17:34 75-25-2
Bromomethane ND ug/kg 12.4 11/13/09 17:34 74-83-9
2-Butanone (MEK) ND ug/kg 124 11/13/0917:34 78-93-3
n-Butylbenzene ND ug/kg 6.2 11/13/09 17:34 104-51-8
sec-Butylbenzene ND ug/kg 6.2 11/13/09 17:34 135-98-8
tert-Butylbenzene ND ug/kg 6.2 11/13/09 17:34 98-06-6
Carbon tetrachloride ND ug/kg 6.2 11/13/09 17:34 56-23-5
Chlorobenzene ND ug/l<g 6.2 11/13/09 17:34 108-90-7
Chloroethane ND ug/kg 12.4 11/13/09 17:34 75-00-3
Chloroform ND ug/kg 6.2 11/13/09 17:34 67-66-3
Chloromethane ND ug/kg 12.4 11/13/09 17:34 74-87-3
2-Chlorotoluene ND ug/kg 6.2 11/13/09 17:34 95-49-8
4-Chlorotoluene ND ug/kg 6.2 11/13/09 17:34 106-43-4
1,2-Dibromo-3-chloropropane ND ug/kg 6.2 11/13/09 17:34 96-12-8
Dibromochloromethane ND ug/kg 6.2 11/13/09 17:34 124-48-1
1,2-Dibromoethane (EDB) ND ug/kg 6.2 11/13/09 17:34 106-93-4
Dibromomethane ND ug/kg 6.2 11/13/09 17:34 74-95-3
1,2-Dichlorobenzene ND ug/kg 6.2 11/13/09 17:34 95-50-1
1,3-Dichlorobenzene ND ug/kg 6.2 11/13/09 17:34 541-73-1
1,4-Dichlorobenzene ND ug/kg 6.2 11/13/09 17:34 106-46-7
Dichlorodifluoromethane ND ug/kg 12.4 11/13/09 17:34 75-71-8
1, 1-Dichloroethane ND ug/kg 6.2 11/13/09 17:34 75-34-3
1,2-Dichloroethane ND ug/kg 6.2 11/13/0917:34 107-06-2
1, 1-Oichloroethene ND ug/kg 6.2 11/13/09 17:34 75-35-4
cis-1,2-Dichloroethene ND ug/kg 6.2 11/13/09 17:34 156-59-2
trans-1,2-Dichloroethene NO ug/kg 6.2 11/13/09 17:34 156-60-5
1,2-Dichloropropane ND ug/kg 6.2 11/13/09 17:34 78-87-5
1,3-Oichloropropane ND ug/kg 6.2 11/13/0917:34 142-28-9
2,2-Dichloropropane ND ug/kg 6.2 11/13/09 17:34 594-20-7
1, 1-Oichtoropropene ND ug/kg 6.2 11/13/09 17:34 563-58-6
cis-1,3-Dichloropropene ND ug/kg 6.2 11/13/09 17:34 10061-01-5
trans-1,3-Oichloropropene ND ug/kg 6.2 11/13/09 17:34 10061-02-6
Diisopropyl ether ND ug/kg 6.2 11/13/09 17:34 108-20-3
Ethylbenzene ND ug/kg 6.2 11/13/09 17:34 100-41-4
Hexachloro-1,3-butadiene ND ug/kQ 6.2 11/13/09 17:34 87-68-3
2-Hexanone NO ug/kg 62.0 11/13/09 17:34 591-78-6
lsopropylbenzene (Cumene) ND ug/kg 6.2 11/13/09 17:34 98-82-8
p-lsopropyltoluene ND ug/kg 6.2 11/13/09 17:34 99-87-6
Methylene Chloride ND ug/kg 24.8 11/13/09 17:34 75-09-2
4-Methyl-2-pentanone (MlBK) ND ug/kg 62.0 11/13/09 17:34 108-10-1
Methyl-tert-butyl ether ND ug/kg 6.2 11/13/09 17:34 1634-04-4
Naphthalene ND ug/l<g 6.2 11/13/09 17:34 91-20-3
n-Propylbenzene ND ug/kg 6.2 11/13/09 17:34 103-65-1
Styrene ND ug/kg 6.2 11/13/09 17:34 100-42-5
1, 1, 1,2-Tetrachloroethane ND ug/kg 6.2 11/13/09 17:34 630-20-6
1, 1,2,2-Tetrachloroethane ND ug/kg 6.2 11/13/09 17:34 79-34-5
Date: 12/04/2009 11 :18 AM REPORT OF LABORATORY ANALYSIS Page 19 of 81
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
7.:.!-'·,~ o'lla", m1e 01
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
(828)254•7176
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: CASTLE HAYNE 22·124930
Pace Project No.: 9257362
Sample: HA-4 LablD: 9257362004 Collected: 11/11/09 11:45 Received: 11/12/09 09:10 Matrix: Solid
Results reported on a "dry-weight" basis
Parameters
826015035A Volatile Organics
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1, 1, 1-Trichloroethane
1, 1.2-Trichloroethane
Trichloroethene
T rich lorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl acetate
Vinyl chloride
Xylene (Total)
m&p-Xylene
o-Xylene
Dibromofluoromethane (S)
Toluene-de (S)
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Percent Moisture
Percent Moisture
Date: 12/04/2009 11: 16 AM
Results Units Report Limit DF Prepared
Analytical Method: EPA 8260
ND ug/kg 6.2
NO ug/kg 6.2
ND ug/kg 6.2
ND ug/kg 6.2
ND ug/kg 6.2
NO ug/kg 6.2
ND ug/kg 6.2
ND ug/l<g 6.2
ND ug/kg 6.2
NO ug/kg 6.2
ND ug/kg 6.2
ND ug/kg 62.0
ND ug/kg 12.4
NO ug/kg 12.4
ND ug/kg 12.4
ND ug/kg 6.2
93 % 79-116
99 % 88-110
91 % 74-115
69 % 69-121
Analytical Method: ASTM 02974-67
34.6 % 0.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full.
without the written consent of Pace Analytical Services, Inc ..
~~?r-~~~~~ ?tnelac1,
Analyzed CAS No. Qual
11/13/09 17:34 127-18-4
11/13/09 17:34 108-88-3
11/13/0917:34 87-61-6
11/13/09 17:34 120-82-1
11/13/09 17:34 71-55-6
11/13/09 17:34 79-00-5
11/13/09 17:34 79-01-6
11/13/09 17:34 75-69-4
11/13/09 17:34 96-18-4
11/13/09 17:34 95-63-6
11/13/09 17:34 108-67-8
11/13/09 17:34 108-05-4
11/13/09 17:34 75-01-4
11/13/09 17:34 1330-20-7
11/13/09 17:34 1330-20-7
11/13/09 17:34 95-47-6
11/13/09 17:34 1868-53-7
11/13/09 17:34 2037-26-5
11/13/09 17:34 460-00-4
11/13/0917:34 17060-07-0
11/17/09 06:55
Page 20 of 81
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
(828)254• 7176
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: CASTLE HAYNE 22-124930
Pace Project No.: 9257362
Sample: HA-5 LablD: 9257362005 Collected: 11/11/09 11:30 Received: 11/12/09 09:10 Matrix: Solid
Results reported on a .. dry-weight .. basis
Parameters
6010 MET ICP
Aluminum
Antimony
Arsenic
Beryllium
Chromium
Copper
Iron
Lead
Nickel
Thallium
Zinc
8270 MSSV Full List Microwave
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fiuoranthene
Benzo(g, h, i )perylene
Benzo(k)fiuoranthene
4-Bromophenylphenyl ether
Butylbenzylphthalate
4-Chloro-3-methylphenol
4-Chloroaniline
bis(2-Chloroethoxy)methane
bis(2-Chloroethyl) ether
bis(2-Chloroisopropyl) ether
2-Chloronaphthalene
2-Chlorophenol
4-Chlorophenylphenyl ether
Chrysene
Dibenz{a, h)anthracene
Dibenzofuran
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
3,3'-Dichlorobenzidine
2,4-Dichlorophenol
Diethylphthalate
2,4-Dimethy1phenol
Dimethylphthalate
Di-n-butylphthalate
4,6-Dinitro-2-methylphenol
2,4-Dinitrophenol
2,4-0initrotoluene
Date: 12/04/2009 11: 18 AM
Results Units Report Limit DF Prepared
Analytical Method: EPA 6010 Preparation Method: EPA 3050
4100 mg/kg 8.7 11/16/09 11:05
ND mg/kg 0.44 11/16/09 11:05
0.54 mg/kg 0.44 11/16/09 11:05
ND mg/kg 0.087 11/16/0911:05
3.3 mg/kg 0.44 11/16/09 11:05
ND mg/kg 0.44 11/16/09 11:05
542 mg/kg 4.4 11/16/99 11:05
3.7 mg/kg 0.44 11/16/0911:05
0.82 mg/kg 0.44 11/16/0911:05
ND mg/kg 0.87 11/16/09 11:05
0.98 mg/kg 0.87 11/16/09 11:05
Analytical Method: EPA8270
ND ug/kg 41.2 11/18/09 14:09
ND ug/kg 41.2 11/18/09 14:09
ND ug/kg 41.2 11/18/0914:09
ND ug/kg 41.2 11/18/09 14:09
ND ug/kg 41.2 11/18/09 14:09
ND ug/kg 41.2 11/18/09 14:09
ND ug/kg 41.2 11/18/09 14:09
ND ug/kg 41.2 11/18/09 14:09
ND ug/kg 212 11/18/09 14:09
ND ug/kg 212 11/18/09 14:09
ND ug/kg 837 11/18/09 14:09
ND ug/kg 212 11/18/09 14:09
ND ug/kg 212 11/18/09 14:09
ND ug/kg 212 11/18/09 14:09
ND ug/kg 212 11/18/0914:09
ND ug/kg 212 11/18/09 14:09
ND ug/kg 212 11/18/09 14:09
ND ug/kg 212 11/18/09 14:09
ND ug/kg 41.2 11/18/09 14:09
ND ug/kg 41.2 11/18/09 14:09
ND ug/kg 212 11/18/09 14:09
ND ug/kg 212 11/18/09 14:09
ND ug/kg 212 11/18/09 14:09
ND ug/kg 212 11/18/09 14:09
ND ug/kg 837 11/18/09 14:09
ND ug/kg 212 11/18/09 14:09
ND ug/kg 212 11/18/09 14:09
ND ug/kg 212 11/18/0914:09
ND ug/kg 212 11/18/09 14:09
ND ug/kg 212 11/18/0914:09
ND ug/kg 837 11/18/09 14:09
ND u9/kg 837 11/18/09 14:09
ND ug/kg 212 11/18/09 14:09
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
~~YFC~~~ 11nelaei,
Analyzed CAS No.
11/18/09 15:21 7429-90-5
11/18/09 15:21 7440-36-0
11/18/09 15:21 7440-38-2
11/18/09 15:21 7440-41-7
11/18/09 15:21 7440-47-3
11/18/09 15:21 7440-50-8
11/18/09 15:21 7439-89-6
11/18/09 15:21 7439-92-1
11/18/09 15:21 7440-02-0
11/18/09 15:21 7440-28-0
11/18/0915:21 7440-66-6
11/25/09 19:08 83-32-9
11/25/09 19:08 208-96-8
11/25/09 19:08 120-12-7
11/25/09 19:08 56-55-3
11/25/09 19:08 50-32-8
11 /25/09 19:08 205-99-2
11/25/09 19:08 191-24-2
11/25/09 19:08 207-08-9
11/25/09 19:08 101-55-3
11/25/09 19:08 85-68-7
11/25/09 19:08 59-50-7
11/25/09 19:08 106-47-8
11/25/09 19:08 111-91-1
11/25/09 19:08 111-44-4
11/25/09 19:08 108-60-1
11/25/09 19:08 91-58-7
11/25/09 19:08 95-57-8
11/25/09 19:08 7005-72-3
11125/09 19:08 218-01-9
11/25/09 19:08 53-70-3
11/25/09 19:08 132-64-9
11/25/09 19:08 95-50-1
11/25/09 19:08 541-73-1
11/25/09 19:08 106-46-7
11/25/09 19:08 91-94-1
11 /25/09 19:08 120-83-2
11/25/09 19:08 84-66-2
11/25/09 19:08 105-67-9
11/25/09 19:08 131-11-3
11/25/09 19:08 84-74-2
11/25/09 19:08 534-52-1
11/25/09 19:08 51-28-5
11/25/0919:08 121-14-2
Qual
L3
L3
L3
L3
Page 21 of 81
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: CASTLE HAYNE 22-12493D
Pace Project No.: 9257362
Sample: HA-5 LablD: 9257362005 Collected: 11/11/09 11:30 Received: 11/12/09 09:10 Matrix: Solid
Results reported on a "dry-weight" basis
Parameters
8270 MSSV Full List Microwave
2,6-Dinitrotoluene
Di-n-octylphthalate
1,2-Diphenylhydrazine
bis(2-Ethylhexyl)phthalate
Fluoranthene
Fluorene
Hexachloro-1,3-butadiene
Hexachlorobenzene
Hexachlorocyclopentadiene
Hexachloroethane
lndeno( 1,2,3-cd)pyrene
lsophorone
1-Methylnaphthatene
2-Methylnaphthalene
2-Methylphenol(o-Cresol)
3&4-Methylphenol(m&p Cresci)
Naphthalene
2-Nitroaniline
3-Nitroaniline
4-Nitroaniline
Nitrobenzene
2-Nitrophenol
4-Nitrophenol
N-Nitrosodimethylamine
N-Nitroso-di-n-propylamine
N-Nitrosodiphenylamine
Pentachlorophenol
Phenanthrene
Phenol
Pyrene
1,2,4-Trichlorobenzene
2,4,5-Trichlorophenol
2,4,6-Trichlorophenol
Nitrobenzene-d5 ($)
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
Phenol-d6 ($)
2-Fluorophenol ($)
2,4,6-Tribromophenol (S)
8260/SOJSA Volatile Organics
Acetone
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Date: 12/04/2009 11 :18 AM
Results Units Report Limit OF Prepared
Analytical Method: EPA8270
ND ug/kg 212 11/18/09 14:09
ND ug/kg 212 11/18/09 14:09
ND ug/kg 212 11/18/09 14:09
ND ug/kg 212 11/18/09 14:09
ND ug/kg 41.2 11/18/0914:09
ND ug/kg 41.2 11/18/09 14:09
ND ug/kg 212 11/18/09 14:09
ND ug/kg 212 11/18/09 14:09
ND ug/kg 837 11/18/09 14:09
ND ug/kg 212 11/18/09 14:09
ND ug/kg 41.2 11/18/09 14:09
ND ug/kg 212 11/18/09 14:09
ND ug/kg 41.2 11/18/09 14:09
NO ug/kg 41.2 11/18/09 14:09
ND ug/kg 212 11/18/09 14:09
ND ug/kg 212 11/18/09 14:09
ND ug/kg 41.2 11/18/0914:09
ND ug/kg 212 11/18/09 14:09
ND ug/kg 212 11/18/09 14:09
ND ug/kg 212 11/18/09 14:09
ND ug/kg 212 11/18/09 14:09
ND ug/kg 212 11/18/09 14:09
ND ug/kg 212 11/18/09 14:09
ND ug/kg 212 11/18/09 14:09
ND ug/kg 212 11/18/09 14:09
ND ug/kg 212 11/18/09 14:09
ND ug/kg 837 11/18/09 14:09
ND ug/kg 41.2 11/18/09 14:09
ND ug/kg 212 11/18/09 14:09
ND ug/kg 41.2 11/18/09 14:09
ND ug/kg 212 11/18/09 14:09
ND ug/kg 212 11/18/09 14:09
ND ug/kg 212 11/18/0914:09
72 % 10-110 11/18/09 14:09
75 % 18-110 11/18/0914:09
77 % 10-123 11/18/09 14:09
70 % 10-110 11/18/09 14:09
70 % 18-110 11/18/0914:09
76 % 10-110 11/18/09 14:09
Analytical Method: EPA 8260
ND ug/kg 101
ND ug/kg 5.0
ND ug/kg 5.0
ND ug/kg 5.0
ND ug/kg 5.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
Analyzed CAS No. Qual
11/25/0919:08 606-20-2
11 /25/09 19:08 117-84-0
11 /25/09 19:08 122-66-7
11/25/09 19:08 117-81-7
11 /25/09 19:08 206-44-0
11/25/09 19:08 86-73-7
11/25/09 19:08 87-68-3
11/25/09 19:08 118-74-1
11 /25/09 19:08 77-47-4
11/25/09 19:08 67-72-1
11 /25/09 19:08 193-39-5
11/25/09 19:08 78-59-1
11/25/09 19:08 90-12-0
11/25/09 19:08 91-57-6
11/25/0919:08 95-48-7
11/25/0919:08 L1
11 /25/09 19:08 91-20-3
11 /25/09 19:08 88-74-4
11/25/09 19:08 99-09-2
11/25/09 19:08 100-01-6 L3
11/25/09 19:08 98-95-3
11/25/09 19:08 88-75-5
11/25/09 19:08 100-02-7
11/25/0919:08 62-75-9
11/25/09 19:08 621-84-7
11/25/09 19:08 86-30-6
11/25/09 19:08 87-86-5
11/25/09 19:08 85-01-8
11/25/0919:08 108-95-2
11/25/09 19:08 129-00-0
11 /25/09 19:08 120-82-1
11 /25/09 19:08 95-95-4
11/25/09 19:08 88-06-2
11/25/09 19:08 4165-60-0
11 /25/09 19:08 321-60-8
11 /25/09 19:08 1718-51-0
11/25/09 19:08 13127-88-3
11/25/09 19:08 367-12-4
11/25/09 19:08 118-79-6
11/15/0910:50 67-64-1
11/15/0910:50 71-43-2
11/15/09 10:50 108-86-1
11/15/09 10:50 74-97-5
11/15/09 10:50 75-27-4
Page 22 of 81
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704 )875-9092
Project CASTLE HAYNE 22-124930
Pace Project No.: 9257362
Sampl~: HA-5 LablD: 9257362005 Collected: 11/11/09 11:30 Received: 11/12/09 09:10 Matrix: Solid
Results reported on a "dry-weight" basis
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
826015035A Volatile Organics Analytical Method: EPA 8260
Bromoform ND ug/kg 5.0 11/15/09 10:50 75-25-2
Bromomethane ND ug/kg 10.1 11/15/09 10:50 74-83-9
2-Butanone (MEK) ND ug/kg 101 11/15/09 10:50 78-93-3
n-Butylbenzene ND ug/kg 5.0 11115/09 10:50 104-51-8
sec-Butylbenzene NO ug/kg 5.0 11/15/09 10:50 135-98-8
tert-Butylbenzene ND ug/kg 5.0 11/15/09 10:50 98-06-6
Carbon tetrachloride ND ug/kg 5.0 11/15/09 10:50 56-23-5
Chlorobenzene ND ug/kg 5.0 11/15/09 10:50 108-90-7
Chloroethane NO ug/kg 10.1 11/15/09 10:50 75-00-3
Chloroform ND ug/kg 5.0 11/15/0910:50 67-66-3
Chloromethane ND ug/kg 10.1 11/15/09 10:50 74-87-3
2-Chlorototuene ND ug/kg 5.0 11/15/09 10:50 95-49-8
4-Chlorotoluene ND ug/kg 5.0 11/15/09 10:50 106-43-4
1,2-0ibromo-3-chloropropane NO ug/kg 5.0 11/15/09 10:50 96-12-8
Dibromochloromethane ND ug/kg 5.0 11/15/09 10:50 124-48-1
1,2-Dibromoethane (EDB) ND ug/kg 5.0 11/15/09 10:50 106-93-4
Dibromomethane ND ug/kg 5.0 11/15/0910:50 74.95.3
1,2-Dichlorobenzene ND ug/kg 5.0 11/15/09 10:50 95-50-1
1,3-Dichlorobenzene ND ug/kg 5.0 11/15/09 10:50 541-73-1
1,4-Dichlorobenzene NO ug/kg 5.0 11/15/09 10:50 106-46-7
Dichlorodifluoromethane ND ug/kg 10.1 11/15/09 10:50 75-71-8
1, 1-Dichloroethane ND ug/kg 5.0 11/15/09 10:50 75-34-3
1,2-Dichloroethane ND ug/kg 5.0 11/15/0910:50 107-06-2
1, 1-Dichloroethene ND ug/kg 5.0 11/15/09 10:50 75-35-4
cis-1,2-Dichloroethene ND ug/kg 5.0 11/15/09 10:50 156-59-2
trans-1,2-Dichloroethene ND ug/kg 5.0 11/15/09 10:50 156-60-5
1,2-Dichloropropane ND ug/kg 5.0 11/15/09 10:50 78-87-5
1,3-Dichloropropane ND ug/kg 5.0 11/15/09 10:50 142-28-9
2,2-Dichloropropane NO ug/kg 5.0 11/15/09 10:50 594-20-7
1, 1-Dichloropropene ND ug/kg 5.0 11/15/09 10:50 563-58-6
cis-1,3-Dichloropropene ND ug/kg 5.0 11/15/09 10:50 10061-01-5
trans-1,3-Dichloropropene ND ug/kg 5.0 11/15/09 10:50 10061-02-6
Diisopropyl_ether ND ug/kg 5.0 11/15/09 1 0:50 108-20-3
Ethylbenzene ND ug/kg 5.0 11/15/0910:50 100-41-4
Hexachloro-1,3-butadiene ND ug/kg 5.0 11/15/09 1 0:50 87-68-3
2-Hexanone ND ug/kg 50.5 11/15/09 10:50 591-78-6
lsopropylbenzene (Cumene) ND ug/kg 5.0 11/15/09 10:50 98-82-8
p-lsopropyltoluene ND ug/kg 5.0 11/15/09 10:50 99-87-6
Methylene Chloride ND ug/kg 20.2 11/15/09 10:50 75-09-2
4-Methyl-2-pentanone (MIBK) ND ug/kg 50.5 11 /15/09 10:50 108-10-1
Methyl~tert-butyl ether ND ug/kg 5.0 11/15/09 10:50 1634-04-4
Naphthalene ND ug/kg 5.0 11/15/09 1 0:50 91-20-3
n-Propylbenzene ND ug/kg 5.0 11/15/09 10:50 103-65-1
Styrene ND ug/kg 5.0 11/15/09 10:50 100-42-5
1, 1, 1,2-Tetrachloroethane ND ug/kg 5.0 11/15/09 10:50 630-20-6
1, 1,2,2-Tetrachloroethane ND ug/kg 5.0 11/15/09 10:50 79-34-5
Date: 12/04/2009 11: 18 AM REPORT OF LABORATORY ANALYSIS Page 23 of 81
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
'" '<Co~ ~~7r-~~~~ ?1□e Ci,
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: CASTLE HAYNE 22-124930
Pace Project No.: 9257362
Sample: HA-5 LablD: 9257362005 Collected: 11/11/09 11:30 Received: 11/12/09 09:10 Matrix: Solid
Results reported on a "dry-weight .. basis
Parameters
8260/5035A Volatile Organics
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trich1orobenzene
1, 1, 1-T richloroethane
1, 1,2-Trlchloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl acetate
Vinyl chloride
Xylene (Total)
m&p-Xylene
a-Xylene
Dibromofluoromethane (S)
Toluene-dB (S)
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Percent Moisture
Percent Moisture
Date: 12/04/2009 11: 16 AM
Results Units Report Limit OF Prepared
Analytical Method: EPA 8260
ND ug/kg 5.0
94.7 ug/kg 5.0
ND ug/kg 5.0
ND ug/kg 5.0
ND u9/k9 5.0
ND ug/kg 5.0
ND u9/kg 5.0
ND ug/kg 5.0
ND ug/k9 5.0
ND ug/kg 5.0
ND ug/kg 5.0
ND ug/kg 50.5
ND u9/kg 10.1
ND ug/kg 10.1
ND ug/kg 10.1
ND ug/kg 5.0
99 % 79-116
97 % 88-110
96 % 74-115
95 % 69-121
Analytical Method: ASTM D2974-67
20.5 % 0.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
~~¾_!_'ts~~~
?1ne1c1C1,
Analyzed GAS No. Qua!
11/15/09 10:50 127-18-4
11/15/09 10:50 108-88-3
11/15/09 10:50 87-61-6
11/15/09 10:50 120-82-1
11/15/09 10:50 71-55-6
11/15/09 10:50 79-00-5
11/15/0910:50 79-01-6
11/15/09 10:50 75-69-4
11/15/09 10:50 96-18-4
11/15/09 10:50 95-63-6
11/15/09 10:50 108-67-8
11/15/09 10:50 108-05-4
11/15/09 10:50 75-01-4
11/15/0910:50 1330-20-7
11/15/09 10:50 1330-20-7
11/15/09 10:50 95-47-6
11/15/09 10:50 1868-53-7
11/15/09 10:50 2037-26-5
11/15/09 10:50 460-00-4
11/15/09 10:50 17060-07-0
11/17/09 08:55
Page 24 of 81
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Paco Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704 )875-9092
Project: CASTLE HAYNE 22-124930
Pace Project No.: 9257362
Sample: HA-6 LablD: 9257362006 Collected: 11/11/09 13:00 Received: 11/12/09 09:10 Matrix: Solid
Results reported on a "dry-weight" basis
Parameters Results Units Report Limit OF Prepared Analyzed GAS No. Qual
6010 MET ICP Analytical Method: EPA6010 Preparation Method: EPA 3050
Aluminum 1830 mg/kg 11.1 11/16/09 11:05 11/18/0915:25 7429-90-5
Antimony ND mg/kg 0.55 11/16/09 11:05 11/18/0915:25 7440-36-0
Arsenic 0.89 mg/kg 0.55 11/16/09 11:05 11/18/09 15:25 7440-38-2
Beryllium ND mg/kg 0.11 11/16/0911:05 11/18/09 15:25 7440-41-7
Chromium 1.9 mg/kg 0.55 11/16/09 11:05 11/18/09 15:25 7440-47-3
Copper 0.73 mg/kg 0.55 11/16/09 11:05 11/18/09 15:25 7440-50-8
Iron 622 mg/kg 5.5 11/16/09 11:05 11/18/09 15:25 7439-89-6
Lead 4.3 mg/kg 0.55 11/16/09 11:05 11/18/09 15:25 7439-92-1
Nickel 0.56 mg/kg 0.55 11/16/09 11:05 11/18/0915:25 7440-02-0
Thallium ND mg/kg 1.1 11/16/09 11:05 11/18/09 15:25 7440-28-0
Zinc 2.7 mg/kg 1.1 11/16/0911:05 11/18/09 15:25 7440-66-6
8270 MSSV Full List Microwave Analytical Method: EPA 8270
Acenaphthene 501 ug/k.g 392 10 11/18/09 14:09 11/25/09 19:38 83-32-9
Acenaphthylene ND ug/k.g 392 10 11/18/09 14:09 11/25/09 19:38 208-96-8
Anthracene 668 ug/kg 392 10 11/18/09 14:09 11/25/09 19:38 120-12-7
Benzo(a)anthracene 2840 ug/k.g 392 10 11/18/0914:09 11/25/09 19:38 56-55-3
Benzo(a)pyrene 2620 ug/kg 392 10 11/18/0914:09 11/25/09 19:38 50-32-8
Benzo(b )fluoranthene 3570 ug/k.g 392 10 11/18/0914:09 11125/09 19:38 205-99-2
Benzo(g, h, i)peryle ne 1850 ug/k.g 392 10 11/18/09 14:09 11/25/0919:38 191-24-2
Benzo(k)fluoranthene 1190 ug/kg 392 10 11/18/09 14:09 11/25/09 19:38 207-08-9
4-Bromophenylphenyl ether ND ug/k.g 2020 10 11/18/09 14:09 11 /25/09 19:38 101-55-3
Butylbenzylphthalate ND ug/k.g 2020 10 11/18/09 14:09 11 /25/09 19:38 85-68-7
4-Chloro-3-methylphenol ND ug/k.g 7960 10 11/18/09 14:09 11/25/09 19:38 59-50-7
4-Chloroaniline ND ug/kg 2020 10 11/18/0914:09 11/25/09 19:38 106-47-8 L3
bis(2-Chloroethoxy)methane ND ug/kg 2020 10 11/18/09 14:09 11/25/09 19:38 111-91-1
bis(2-Chloroethyl) ether ND ug/k.g 2020 10 11/18/09 14:09 11/25/09 19:38 111-44-4
bis(2-Chloroisopropyl) ether ND ug/kg 2020 10 11/18/09 14:09 11/25/09 19:38 108-60-1
2-Chloronaphthalene ND ug/kg 2020 10 11/18/09 14:09 11 /25/09 19:38 91-58-7
2-Chlorophenol ND ug/kg 2020 10 11/18/09 14:09 11/25/09 19:38 95-57-8
4-Chlorophenylphenyl ether ND ug/kg 2020 10 11/18/09 14:09 11/25/09 19:38 7005-72-3
Chrysene 3070 ug/kg 392 10 11/18/09 14:09 11/25/09 19:38 218-01-9
Dibenz(a, h )anthracene 435 ug/kg 392 10 11/18/09 14:09 11/25/09 19:38 53-70-3
Dibenzofuran ND ug/kg 2020 10 11/18/0914:09 11/25/09 19:38 132-64-9 L3
1,2-Dichlorobenzene ND ug/kg 2020 10 11/18/09 14:09 11/25/09 19:38 95-50-1 L3
1,3-Dichlorobenzene ND ug/kg 2020 10 11/18/09 14:09 11/25/09 19:38 541-73-1 L3
1,4-Dichlorobenzene ND ug/k.g 2020 10 11/18/09 14:09 11/25/09 19:38 106-46-7
3,3'-Dichlorobenzidine ND ug/kg 7960 10 11/18/09 14:09 11/25/09 19:38 91-94-1
2,4-Dichlorophenol ND ug/kg 2020 10 11/18/09 14:09 11 /25/09 19:38 120-83-2
Diethylphthalate ND ug/k.g 2020 10 11/18/09 14:09 11/25/09 19:38 64-66-2
2,4-Dimethylphenol ND ug/kg 2020 10 11/18/09 14:09 11/25/09 19:38 105-67-9
Dimethylphthalate ND ug/kg 2020 10 11/18/09 14:09 11/25/09 19:38 131-11-3
Di-n-butylphthalate ND ug/kg 2020 10 11/18/09 14:09 11/25/09 19:38 84-74-2
4,6-Dinitro-2-methytphenol ND ug/k.g 7960 10 11/18/0914:09 11/25/09 19:38 534-52-1
2,4-Dinitrophenol ND ug/kg 7960 10 11/18/09 14:09 11/25/09 19:38 51-28-5
2,4-Dinitrotoluene ND ug/kg 2020 10 11/18/0914:09 11/25/09 19:38 121-14-2
Date: 12/04/2009 11:18AM REPORT OF LABORATORY ANALYSIS Page 25 of 81
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
~ .. ?f~-~~~~ ;1nelao;
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875--9092
Project: CASTLE HAYNE 22-124930
Pace Project No.: 9257362
Sample: HA-6 LablD: 9257362006 Collected: 11/11/09 13:00 Received: 11/12/09 09:10 Matrix: Solid
Results reported on a "dry-weight" basis
Parameters
8270 MSSV Full List Microwave
2,6-0initrotoluene
Di-n-octylphthalate
1,2-Diphenylhydrazine
bis{2-Ethylhexyl)phthalate
Fluoranthene
Fluorene
Hexachloro-1,3-butadiene
Hexachlorobenzene
Hexachlorocyclopentadiene
Hexachloroethane
lndeno{1,2,3-cd)pyrene
lsophorone
1-Methylnaphthalene
2-Methylnaphthalene
2-Methylphenol{o-Cresol)
3&4-Methylphenol{m&p Cresci)
Naphthalene
2-Nitroaniline
3-Nitroaniline
4-Nitroaniline
Nitrobenzene
2-Nitrophenol
4-Nitrophenol
N-Nitrosodir:nethylamine
N-Nitroso-di-n-propylamine
N-Nitrosodiphenylamine
Pentachlorophenol
Phenanthrene
Phenol
Pyrene
1,2,4-Trichlorobenzene
2,4,5-Trichlorophenol
2,4,6-Trichlorophenol
Nitrobenzene-d5 ($)
2-Fluorobiphenyl ($)
Terphenyl-d14 {S)
Phenol-d6 (S)
2-Fluorophenol (S)
2,4,6-Tribromophenol {S)
826015035A Volatile Organics
Acetone
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Date: 12/04/2009 11 :18 AM
Results Units
Analytical Method: EPA 8270
ND ug/kg
NO ug/kg
ND ug/kg
ND ug/kg
6060 ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
1660 ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
NO ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
NO ug/kg
ND ug/kg
3240 ug/kg
ND ug/kg
5080 ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
66 %
75 %
81 %
68 %
68 %
72 %
Analytical Method: EPA 8260
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
Report limit
2020
2020
2020
2020
392
392
2020
2020
7960
2020
392
2020
392
392
2020
2020
392
2020
2020
2020
2020
2020
2020
2020
2020
2020
7960
392
2020
392
2020
2020
2020
10-110
18-110
10-123
10-110
18-110
10-110
104
5.2
5.2
52
5.2
DF Prepared
10 11/18/09 14:09
10 11/18/09 14:09
10 11/18/09 14:09
10 11/18/09 14:09
10 11/18/09 14:09
10 11/18/09 14:09
10 11/18/09 14:09
10 11/18/09 14:09
10 11/18/09 14:09
10 11/18/09 14:09
10 11/18/09 14:09
10 11/18/09 14:09
10 11/18/09 14:09
10 11/18/09 14:09
10 11/18/09 14:09
10 11/18/09 14:09
10 11/18/09 14:09
10 11/18/09 14:09
10 11/18/09 14:09
10 11/18/09 14:09
10 11/18/09 14:09
10 11/18/09 14:09
10 11/18/0914:09
10 11/18/09 14:09
10 11/18/09 14:09
10 11/18/09 14:09
10 11/18/09 14:09
10 11/18/09 14:09
10 11/18/09 14:09
10 11/18/09 14:09
10 11/18/09 14:09
10 11/18/09 14:09
10 11/18/09 14:09
10 11/18/09 14:09
10 11/18/09 14:09
10 11/18/09 14:09
10 11/18/09 14:09
10 11/18/09 14:09
10 11/18/09 14:09
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in lull,
without the written consent of Pace Analytical Services, Inc ..
~q7?_•<~~"~ ;'1nelac\,
Analyzed GAS No. Qual
11/25/09 19:38 606-20-2
11/25/09 19:38 117-84-0
11/25/09 19:38 122-66-7
11/25/0919:38 117-81-7
11 /25/09 19:38 206-44-0
11 /25/09 19:38 86-73-7
11 /25/09 19:38 87-68-3
11/25/09 19:38 118-74-1
11/25/09 19:38 77-47-4
11/25/09 19:38 67-72-1
11/25/09 19:38 193-39-5
11 /25/09 19:38 78-59-1
11/25/09 19:38 90-12-0
11/25/09 19:38 91-57-6
11/25/09 19:38 95-48-7
11/25/09 19:38 L1
11/25/09 19:38 91-20-3
11/25/0919:38 88-74-4
11 /25/09 19:38 99-09-2
11 /25/09 19:38 100-01-6 L3
11/25/09 19:38 98-95-3
11/25/09 19:38 88-75-5
11/25/09 19:38 100-02-7
11 /25/09 19:38 62-75-9
11/25/09 19:38 621-84-7
11/25/09 19:38 86-30-6
11/25/0919:38 87-86-5
11/25/09 19:38 85-01-8
11/25/09 19:38 108-95-2
11/25/09 19:38 129-00-0
11125/09 19:38 120-82-1
11/25/0919:38 95-95-4
11 /25/09 19:38 88-06-2
11 /25/09 19:38 4165-60-0
11 /25/09 19:38 321-60-8
11/25/09 19:38 1718-51-0
11/25/09 19:38 13127-88-3
11/25/09 19:38 367-12-4
11/25/09 19:38 118-79-6
11/15/09 11:08 67-64-1
11/15/09 11:08 71-43-2
11/15/09 11:08 108-86-1
11/15/09 11:08 74-97-5
11/15/09 11:08 75-27-4
Page 26 of 81
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: CASTLE HAYNE 22-12493D
Pace Project No.: 9257362
Sample: HA-6 LablD: 9257362006 Collected: 11/11/09 13:00 Received: 11/12/09 09:10 Matrix: Solid
Results reported on a "dry-weight" basis
Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual
826015035A Volatile Organics Analytical Method: EPA 8260
Bromoform ND ug/kg 5.2 11/15/0911:08 75-25-2
Bromomethane ND uglkg 10.4 11/15/09 11:08 74-83-9
2-Butanone (MEK) ND ug/kg 104 11/15/0911:08 78-93-3
n-Butylbenzene ND uglkg 5.2 11/15/09 11:08 104-51-8
sec-Butylbenzene NO uglkg 5.2 11/15/09 11:08 135-98-8
tert-Butylbenzene ND ug/kg 5.2 11/15/09 11:08 98-06-6
Carbon tetrachloride ND uglkg 5.2 11/15/09 11:08 56-23-5
Chlorobenzene ND ug/kg 5.2 11/15/09 11:08 108-90-7
Chloroethane ND ug/kg 10.4 11/15/09 11:08 75-00-3
Chloroform ND ug/kg 5.2 11/15/09 11:08 67-66-3
Chloromethane ND uglkg 10.4 11/15/09 11:08 74-87-3
2-Chlorotoluene ND uglkg 5.2 11/15/0911:08 95-49-8
4-Chlorotoluene ND ug/kg 5.2 11/15/0911:08 106-43-4
1,2-Dibromo-3-chloropropane ND uglkg 5.2 11/15/0911:08 96-12-8
Dibromochloromethane ND uglkg 5.2 11/15/09 11:08 124-48-1
1,2-Dibromoethane (EDB) NO ug/kg 5.2 11/15/09 11:08 106-93-4
Dibromomethane ND uglkg 5.2 11/15/09 11:08 74-95-3
1,2-Dichlorobenzene ND ug/kg 5.2 11/15/09 11:08 95-50-1
1,3-Dichlorobenzene ND uglkg 5.2 11/15/0911:08 541-73-1
1,4-Dichlorobenzene ND uglkg 5.2 11/15/09 11:08 106-46-7
Dichlorodifluoromethane ND ug/kg 10.4 11/15/09 11:08 75-71-8
1, 1-Dichloroethane ND uglkg 5.2 11/15/09 11:08 75-34-3
1,2-Dichloroethane ND ug/kg 5.2 11/15/09 11:08 107-06-2
1, 1-Dichloroethene ND uglkg 5.2 11/15/09 11:08 75-35-4
cis-1,2-Dichloroethene ND ug/kg 5.2 1 11/15/09 11:08 156-59-2
trans-1,2-Dichloroethene ND ug/kg 5.2 1 11/15/0911:08 156-60-5
1,2-Dichloropropane NO uglkg 5.2 11/15/0911:08 78-87-5
1,3-Dichloropropane ND uglkg 5.2 11/15/09 11:08 142-28-9
2,2-Dichtoropropane ND uglkg 5.2 11/15/09 11:08 594-20-7
1, 1-Dichloropropene ND ug/kg 5.2 11/15/0911:08 563-58-6
cis-1,3-Dichloropropene ND uglkg 5.2 11/15/0911:08 10061-01-5
trans-1,3-Dichloropropene ND ug/kg 5.2 11/15/09 11:08 10061-02-6
Diisopropyl ether ND uglkg 5.2 11/15/09 11:08 108-20-3
Ethylbenzene ND uglkg 5.2 11/15/0911:08 100-41-4
Hexachloro-1,3-butadiene ND uglkg 5.2 11/15/09 11:08 87-68-3
2-Hexanone NO uglkg 52.1 11/15/09 11:08 591-78-6
tsopropylbenzene (Cumene) ND ug/kg 5.2 11/15/09 11:08 98-82-8
p-lsopropylloluene 19.2 uglkg 5.2 11/15/09 11:08 99-87-6 10
Methylene Chloride NO ug/kg 20.8 11/15/09 11:08 75-09-2
4-Methyl-2-pentanone (MIBK) ND ug/kg 52.1 11/15/09 11:08 108-10-1
Methyl-tert-butyl ether NO uglkg 5.2 11/15/0911:08 1634-04-4
Naphthalene NO ug/kg 5.2 11/15/09 11:08 91-20-3
n-Propylbenzene NO uglkg 5.2 11/15/09 11:08 103-65-1
Styrene ND ug/kg 5.2 11/15/09 11:08 100-42-5
1, 1, 1,2-Tetrachloroethane ND ug/kg 5.2 11/15/09 11:08 630-20-6
1, 1,2,2-Tetrachloroethane NO uglkg 5.2 11/15/09 11:08 79-34-5
Date: 12/04/2009 11: 18 AM REPORT OF LABORATORY ANALYSIS Page 27 of 81
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc .. .. Q«-·~~~ .... 11oelac1,
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704 )875-9092
Project:
Pace Project No.:
CASTLE HAYNE 22-12493D
9257362
Sample: HA-6 LablD: 9257362006 Collected: 11/11/09 13:00 Received: 11/12/09 09:10 Matrix: Solid
Results reported on a .. dry.weight" basis
Parameters
8260/5035A Volatile Organics
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1, 1, 1-Trichloroethane
1.1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1.3,5-T rimethylbenzene
Vinyl acetate
Vinyl chloride
Xylene (Total)
m&p-Xy1ene
a-Xylene
Dibromofluoromethane (S)
Toluene-dB (S)
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Percent Moisture
Percent Moisture
Date: 12/04/2009 11 :18 AM
Results Units Report Limit OF Prepared
Analytical Method: EPA8260
ND ug/kg 5.2
28.5 ug/kg 5.2
ND ug/kg 5.2
ND ug/kg 5.2
ND ug/kg 5.2
ND ug/kg 5.2
ND ug/kg 5.2
ND ug/kg 5.2
ND ug/kg 5.2
ND ug/kg 5.2
ND ug/kg 5.2
ND ug/kg 52.1
ND ug/kg 10.4
ND ug/kg 10.4
ND ug/kg 10.4
ND ug/kg 5.2
99 % 79-116
96 % 88-110
82 % 74-115
93 % 69-121
Analytical Method: ASTM 02974-87
16.3 % 0.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
Analyzed CAS No. Qual
11/15/0911:08 127-18-4
11/15/09 11:08 108-88-3
11/15/09 11:08 87-61-6
11/15/09 11:08 120-82-1
11/15/09 11:08 71-55-6
11/15/09 11:08 79-00-5
11/15/09 11:08 79-01-6
11/15/09 11:08 75-69-4
11/15/0911:08 96-16-4
11/15/0911:08 95-63-6
11/15/0911:08 108-67-8
11/15/09 11:08 108-05-4
11/15/09 11:08 75-01-4
11/15/09 11:08 1330-20-7
11/15/09 11:08 1330-20-7
11/15/09 11:08 95-47-6
11/15/0911:08 1868-53-7
11/15/09 11:08 2037-26-5
11/15/09 11:08 460-00-4
11/15/09 11:08 17060-07-0
11/17/09 08:55
Page 28 of 81
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704 )875-9092
Project: CASTLE HAYNE 22-124930
Pace Project No.: 9257362
Sample: HA-7 LablD: 9257362007 Collected: 11/11/09 13:30 Received: 11/12/09 09:10 Matrix: Solid
Results reported on a "dry-weight" basis
Parameters
6010 MET ICP
Aluminum
Antimony
Arsenic
Beryllium
Chromium
Copper
Iron
Lead
Nickel
Thallium
Zinc
8270 MSSV Full List Microwave
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g, h, i)perylene
Benzo(k)fluoranthene
4-Bromophenylphenyl ether
Butylbenzylphthalate
4-Chloro-3-methylphenol
4-Chloroaniline
bis(2-Chloroethoxy)methane
bis(2-Chloroethy1) ether
bis(2-Chloroisopropyl) ether
2-Chloronaphthalene
2-Chlorophenol
4-Chlorophenylphenyl ether
Chrysene
D ibenz( a, h )a nth racene
Dibenzofuran
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
3,3'-Dichlorobenzidine
2,4-Dichlorophenol
Diethylphthalate
2,4-Dimethylphenol
Dimethylphthalate
Di-n-butylphthalate
4,6-Dinitro-2-methylphenol
2,4-Dinitrophenol
2,4-Dinitrotoluene
Date: 12/04/200911:18AM
Results Units Report Limit OF Prepared
Analytical Method: EPA 6010 Preparation Method: EPA 3050
1190 mg/kg 8.9 1111810915:10
ND mg/kg 0.44 1111810915:10
4.7 mg/kg 0.44 11/18109 15:10
0.32 mg/kg 0.089 11118109 15:10
3.0 mg/kg 0.44 11118109 15:10
ND mg/kg 0.44 11/18/0915:10
3820 mg/kg 4.4 1111810915:10
1.9 mg/kg 0.44 1111810915:10
4.3 mg/kg 0.44 11118109 15:10
ND mg/kg 0.89 11118109 15:10
9.6 mg/kg 0.89 11118109 15:10
Analytical Method: EPA8270
ND ug/kg 39.6 11/18/0914:09
ND ug/kg 39.6 11118109 14:09
ND ug/kg 39.6 11/18109 14:09
ND ug/kg 39.6 11118109 14:09
ND ug/kg 39.6 11118109 14:09
ND ug/kg 39.6 11118109 14:09
ND ug/kg 39.6 11/18/09 14:09
ND ug/kg 39.6 11118/09 14:09
ND uglkg 204 1111810914:09
ND ug/kg 204 11118109 14:09
ND ug/kg 804 11118109 14:09
ND ug/kg 204 11/18/09 14:09
ND ug/kg 204 11118109 14:09
ND ug/kg 204 11/18/09 14:09
ND ug/kg 204 11/18/0914:09
ND ug/kg 204 11/18/09 14:09
ND ug/kg 204 11118109 14:09
ND ug/kg 204 11/18/09 14:09
ND ug/kg 39.6 11/18/09 14:09
ND ug/kg 39.6 11118109 14:09
ND ug/kg 204 11118109 14:09
ND ug/kg 204 11/18/09 14:09
ND ug/kg 204 11/18/09 14:09
ND ug/kg 204 11/18/09 14:09
ND ug/kg 804 11118/09 14:09
ND ug/kg 204 11118109 14:09
ND ug/kg 204 11/18/09 14:09
. ND ug/kg 204 11/18/09 14:09
ND ug/kg 204 11/18/09 14:09
ND ug/kg 204 11/18/09 14:09
ND ug/kg 804 11/18/09 14:09
ND ug/kg 804 11/18/09 14:09
ND ug/kg 204 11/18/09 14:09
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
,~o~-~~•
~--~1/1 .~ "'' ....... ,10€1<1C1,
Analyzed CAS No.
11119/09 15:57 7429-90-5
11119109 15:57 7440-36-0
11119109 15:57 7440-38-2
11119109 15:57 7440-41-7
11119109 15:57 7440-47-3
11119/09 15:57 7440-50-8
11119109 15:57 7439-89-6
11/19109 15:57 7439-92-1
11/19109 15:57 7440-02-0
11119109 15:57 7440-28-0
11119109 15:57 7440-66-6
11/25/09 20:08 83-32-9
11/25109 20:08 208-96-8
11125109 20:08 120-12-7
11125109 20:08 56-55-3
11125109 20:08 50-32-8
11125109 20:08 205-99-2
11/25/09 20:08 191-24-2
11125/09 20:08 207-08-9
11125/09 20:08 101-55-3
11125109 20:08 85-68-7
11125109 20:08 59-50-7
11/25/09 20:08 106-47-8
11125109 20:08 111-91-1
11/25/09 20:08 111-44-4
11/25/09 20:08 108-60-1
11125109 20:08 91-58-7
11125109 20:08 95-57-8
11125109 20:08 7005-72-3
11125109 20:08 218-01-9
11125109 20:08 53-70-3
11125109 20:08 132-64-9
11125109 20:08 95-50-1
11125109 20:08 541-73-1
11125109 20:08 106-46-7
11125/09 20:08 91-94-1
11125/09 20:08 120-83-2
11125109 20:08 84-66-2
11125109 20:08 105-67-9
11125109 20:08 131-11-3
11 /25/09 20:08 84-74-2
11125109 20:08 534-52-1
11125109 20:08 51-28-5
11/25/09 20:08 121-14-2
Qual
PB
L3
L3
L3
L3
Page 29 of 81
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: CASTLE HAYNE 22-124930
Pace Project No.: 9257362
Sample: HA-7 LablD: 9257362007 Collected: 11/11/09 13:30 Received: 11/12/09 09:10 Matrix: Solid
Results reported on a "dry-weight" basis
Parameters
8270 MSSV Full List Microwave
2,6-0initrotoluene
Di-n-octylphthalate
1,2-Diphenylhydrazine
bis(2-Ethylhexyl)phthalate
Fluoranthene
Fluorene
Hexachloro-1,3-butadiene
Hexachlorobenzene
Hexachlorocyclopentadiene
Hexachloroethane
lndeno(1,2,3-cd)pyrene
lsophorone
1-Methylnaphthalene
2-Methylnaphthalene
2-Methytphenol(o-Cresol)
3&4-Methylphenol(m&p Cresol)
Naphthalene
2-Nitroaniline
3-Nitroaniline
4-Nitroaniline
Nitrobenzene
2-Nitrophenol
4-Nitrophenol
N-Nitrosodimethylamine
N-Nitroso-di-n-propylamine
N-Nitrosodiphenylamine
Pentachlorophenol
Phenanthrene
Phenol
Pyrene
1,2,4-Trichlorobenzene
2,4,5-Trichlorophenol
2,4,6-Trichlorophenol
Nitrobenzene-d5 (S)
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
Phenol--d6 (S)
2-Fluorophenol (S)
2,4,6-Tribromophenol (S)
826015035A Volatile Organics
Acetone
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Date: 12/04/200911:18AM
Results Units Report Limit DF Prepared
Analytical Method: EPA8270
NO ug/kg 204 11/18/09 14:09
ND ug/kg 204 11/18/09 14:09
NO ug/kg 204 11/18/09 14:09
ND u9/kg 204 11/18/0914:09
NO ug/kg 39.6 11/18/09 14:09
ND ug/kg 39.6 11/18/09 14:09
NO ug/kg 204 11/18/09 14:09
ND ug/k9 204 11/18/09 14:09
NO ug/kg 804 11/18/09 14:09
ND ug/kg 204 11/18/09 14:09
ND ug/kg 39.6 11/18/09 14:09
ND ug/kg 204 11/18/09 14:09
ND ug/kg 39.6 11/18/09 14:09
ND ug/kg 39.6 11/18/09 14:09
ND ug/kg 204 11/18/09 14:09
ND ug/kg 204 11/18/09 14:09
ND ug/kg 39.6 11/18/09 14:09
ND ug/kg 204 11/18/09 14:09
ND ug/kg 204 11/18/09 14:09
ND ug/kg 204 11/18/09 14:09
ND ug/kg 204 11/18/09 14:09
ND ug/kg 204 11/18/09 14:09
ND ug/kg 204 11/18/09 14:09
ND ug/kg 204 11/18/09 14:09
ND ug/kg 204 11/18/09 14:09
ND ug/kg 204 11/18/09 14:09
ND ug/kg 804 11/18/0914:09
ND ug/kg 39.6 11/18/09 14:09
ND ug/kg 204 11/18/0914:09
ND ug/kg 39.6 11/18/09 14:09
ND ug/kg 204 11/18/09 14:09
ND ug/kg 204 11/18/09 14:09
ND ug/kg 204 11/18/09 14:09
62 % 10-110 11/18/09 14:09
62 % 18-110 11/18/09 14:09
62 % 10-123 11/18/09 14:09
58 % 10-110 11/18/09 14:09
59 % 18-110 11/18/09 14:09
63 % 10-110 11/18/09 14:09
Analytical Method; EPA 8260
ND ug/kg 92.2
ND ug/kg 4.6
ND ug/kg 4.6
NO ug/kg 4.6
ND ug/kg 4.6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
~Qef·~~~~ 11nelaei,
Analyzed CAS No. Qual
11 /25/09 20:08 606-20-2
11/25/09 20:08 117-84-0
11/25/09 20:08 122-66-7
11/25/09 20:08 117-81-7
11/25/09 20:08 206-44-0
11 /25/09 20:08 86-73-7
11/25/09 20:08 87-68-3
11/25/09 20:08 118-74-1
11/25/09 20:08 77-47-4
11/25/09 20:08 67-72-1
11/25/09 20:08 193-39-5
11/25/09 20:08 78-59-1
11 /25/09 20:08 90-12-0
11 /25/09 20:08 91-57-6
11/25/09 20:08 95-48-7
11/25/09 20:08 L1
11/25/09 20:08 91-20-3
11/25/09 20:08 88-74-4
11/25/09 20:08 99-09-2
11 /25/09 20:08 100-01-6 L3
11 /25/09 20:08 98-95-3
11 /25/09 20:08 88-75-5
11 /25/09 20:08 100-02-7
11/25/09 20:08 62-75-9
11/25/09 20:08 621-64-7
11/25/09 20:08 86-30-6
11/25/09 20:08 87-86-5
11/25/09 20:08 85-01-8
11 /25/09 20:08 108-95-2
11 /25/09 20:08 129-00-0
11 /25/09 20:08 120-82-1
11/25/09 20:08 95-95-4
11/25/09 20:08 88-06-2
11/25/09 20:08 4165-60-0
11/25/09 20:08 321-60-8
11 /25/09 20:08 1718-51-0
11 /25/09 20:08 13127-88-3
11 /25/09 20:08 367-12-4
11/25/09 20:08 118-79-6
11/13/09 16:58 67-64-1
11/13/09 16:58 71-43-2
11/13/09 16:58 108-86-1
11/13/09 16:58 74-97-5
11/13/09 16:58 75-27-4
Page 30 of 81
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704 )875-9092
Project CASTLE HAYNE 22-12493D
Pace Project No.: 9257362
Sample: HA-7 LablD: 9257362007 Collected: 11/11/09 13:30 Received: 11/12/09 09:10 Matrix: Solid
Results reported on a "dry-weight" basis
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260/5035A Volatile Organics Analytical Method: EPA6260
Bromoform ND ug/kg 4.6 11 /13/09 16:56 75-25-2
Bromomethane ND ug/kg 9.2 11/13/09 16:56 74-63-9
2-Butanone (MEK) ND ug/kg 92.2 11/13/09 16:56 76-93-3
n-Butylbenzene ND ug/kg 4.6 11/13/09 16:58 104-51-6
sec-Butylbenzene ND ug/kg 4.6 11/13/09 16:56 135-96-6
tert-Butylbenzene ND ug/kg 4.6 11/13/09 16:56 96-06-6
Carbon tetrachloride ND ug/kg 4.6 11/13/09 16:56 56-23-5
Chlorobenzene ND ug/kg 4.6 11/13/09 16:56 106-90-7
Chloroethane ND ug/kg 9.2 11/13/09 16:56 75-00-3
Chloroform ND ug/kg 4.6 11/13/09 16:56 67-66-3
Chloromethane ND ug/kg 9.2 11/13/09 16:56 74-67-3
2-Chlorotoluene ND ug/kg 4.6 11/13/09 16:56 95-49-6
4-Chlorotoluene ND ug/kg 4.6 11/13/09 16:58 106-43-4
1,2-Dibromo-3-chloropropane ND ug/kg 4.6 11/13/09 16:56 96-12-6
Dibromochloromethane ND ug/kg 4.6 11/13/09 16:58 124-46-1
1,2-Dibromoethane (EDB) ND ug/kg 4.6 11/13/09 16:56 106-93-4
Dibromomethane ND ug/kg 4.6 11/13/09 16:56 74-95-3
1,2-Dichlorobenzene ND ug/kg 4.6 11/13/09 16:56 95-50-1
1,3-Dichlorobenzene ND ug/kg 4.6 11/13/09 16:58 541-73-1
1,4-Dichlorobenzene ND ug/kg 4.6 11/13/09 16:58 106-46-7
Dichlorodifluoromethane ND ug/kg 9.2 11/13/09 16:56 75-71-6
1, 1-Dichloroethane ND ug/kg 4.6 11/13/09 16:58 75-34-3
1,2-Dichloroethane ND ug/kg 4.6 11/13/0916:56 107-06-2
1, 1-Dichloroethene ND ug/kg 4.6 11/13/09 16:56 75-35-4
cis-1,2-Dichloroethene ND ug/kg 4.6 11/13/09 16:56 156-59-2
trans-1,2-Dichloroethene ND ug/kg 4.6 11/13/09 16:58 156-60-5
1,2-Dichloropropane ND ug/kg 4.6 11/13/09 16:56 76-67-5
1,3-Dichloropropane ND ug/kg 4.6 11/13/09 16:56 142-26-9
2,2-Dichloropropane ND ug/kg 4.6 11/13/09 16:58 594-20-7
1, 1-Dichloropropene ND ug/kg 4.6 11/13/09 16:56 563-56-6
cis-1,3-Dichloropropene ND ug/kg 4.6 11/13/09 16:58 10061-01-5
trans-1,3-Dichloropropene ND ug/kg 4.6 11/13/09 16:58 10061-02-6
Diisopropyl ether ND ug/kg 4.6 11/13/09 16:58 108-20-3
Ethylbenzene ND ug/kg 4.6 11/13/09 16:58 100-41-4
Hexachloro-1,3-butadiene ND ug/kg 4.6 11/13/09 16:56 67-66-3
2-Hexanone ND ug/kg 46.1 11/13/09 16:58 591-76-6
lsopropylbenzene (Cumene) ND ug/kg 4.6 11/13/09 16:58 96-62-6
p-lsopropyltoluene ND"ug/kg 4.6 11/13/0916:56 99-67-6
Methylene Chloride ND ug/kg 16.4 11/13/0916:56 75-09-2
4-Methyl-2-pentanone (MIBK) ND ug/kg 46.1 11/13/09 16:56 106-10-1
Methyl-tert-butyl ether ND ug/kg 4.6 11/13/09 16:56 1634-04-4
Naphthalene ND ug/kg 4.6 11/13/09 16:56 91-20-3
n-Propylbenzene ND ug/kg 4.6 11/13/09 16:56 103-65-1
Styrene ND ug/kg 4.6 11/13/09 16:58 100-42-5
1, 1, 1,2-Tetrachloroethane ND ug/kg 4.6 11/13/09 16:56 630-20-6
1, 1,2,2-Tetrachloroethane ND ug/kg 4.6 11/13/09 16:56 79-34-5
Date: 12/04/2009 11: 18 AM REPORT OF LABORATORY ANALYSIS Page 31 of 81
This report shall not be reproduced, except in full.
without the written consent of Pace Analytical Services, Inc ..
,?\'"~--11ne C\l
Pace Analytical Sorvices, Inc.
2225 Riverside Or.
ANALYTICAL RESULTS
Asheville, NC 28804
{828)254-7176
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704 )875-9092
Project: CASTLE HAYNE 22-12493D
Pace Project No.: 9257362
Sample: HA-7 LablD: 9257362007 Collected: 11/11/09 13:30 Received: 11/12/09 09:10 Matrix: Solid
Results reported on a "dry-weight" basis
Parameters
8260/5035A Volatile Organics
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1, 1, 1-Trichloroethane
1, 1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl acetate
Vinyl chloride
Xylene (Total)
m&p-Xylene
a-Xylene
Oibromofluoromethane (S)
Toluene-dB (S)
4-Bromofluorobenzene (S)
1,2-0ichloroethane-d4 (S)
Percent Moisture
Percent Moisture
Date: 12/04/2009 11: 18 AM
Results Units Report Limit DF Prepared
Analytical Method: EPA8260
ND ug/kg 4.6
ND ug/kg 4.6
ND ug/kg 4.6
ND ug/kg 4.6
ND ug/kg 4.6
ND ug/kg 4.6
ND ug/kg 4.6
ND ug/kg 4.6
ND ug/kg 4.6
ND ug/kg 4.6
ND ug/kg 4.6
ND ug/kg 46.1
ND ug/kg 9.2
ND ug/kg 9.2
ND ug/kg 9.2
ND uQ/kg 4.6
109 % 79-116
94 % 88-110
76 % 74-115
95 % 69-121
Analytical Method: ASTM 02974-87
17.0 % 0.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
~ef-,~~ tlnelac;,
Analyzed CAS No. Oual
11/13/09 16:58 127-18-4
11/13/09 16:58 108-88-3
11/13/09 16:58 87-61-6
11/13/09 16:58 120-82-1
11/13/09 16:58 71-55-6
11/13/09 16:58 79-00-5
11/13/09 16:58 79-01-6
11/13/0916:58 75-69-4
11/13/09 16:58 96-18-4
11/13/09 16:58 95-63-6
11/13/09 16:58 108-67-8
11/13/09 16:58 108-05-4
11/13/09 16:58 75-01-4
11/13/09 16:58 1330-20-7
11/13/09 16:58 1330-20-7
11/13/09 16:58 95-47-6
11/13/09 16:58 1868-53-7
11/13/09 16:58 2037-26-5
11/13/09 16:58 460-00-4
11/13/09 16:58 17060-07-0
11/17/09 08:56
Page 32 of 81
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704 )875-9092
Project: CASTLE HAYNE 22-12493D
Pace Project No.: 9257362
Sample: HA-8 LablD: 9257362008 Collected: 11/11/09 14:30 Received: 11/12/09 09:10 Matrix: Solid
Results reported on a ndry-weightn basis
Parameters
' 6010 MET ICP
Aluminum
Antimony
Arsenic
Beryllium
Chromium
Copper
Iron
Lead
Nickel
Thallium
Zinc
8270 MSSV Full List Microwave
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b )fluoranthene
Benzo(g, h, i)perylene
Benzo(k)fluoranthene
4-Bromophenylphenyl ether
Butylbenzylphthalate
4-Chloro-3-methylphenol
4-Chloroaniline
bis(2-Chloroethoxy)methane
bis(2-Chloroethyl) ether
bis(2-Chloroisopropyl) ether
2-Chloronaphthalene
2-Chlorophenol
4-Chlorophenylphenyl ether
Chrysene
Dibenz( a, h )a nth racene
Dibenzofuran
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
3,3'-Dichlorobenzidine
2,4-0ichlorophenol
Diethylphthalate
2,4-Dimethylphenol
Dimethylphthalate
Di-n-butylphthalate
4,6-Dinitro-2-methylphenol
2,4-Dinitrophenol
2,4-Dinitrotoluene
Date: 12/04/2009 11: 18 AM
Results Units Report Limit DF Prepared
Analytical Method: EPA 6010 Preparation Method: EPA 3050
1290 mg/kg 6.5 11116/09.15:10
ND mg/kg 0.33 11116109 15:10
2.0 mg/kg 0.33 11116109 15:10
0.22 mg/kg 0.065 11116109 15:10
2.9 mg/kg 0.33 11/18/09 15:10
ND mg/kg 0.33 11116109 15:10
4030 mg/kg 3.3 11/18/09 15:10
2.2 mg/kg 0.33 11116/0915:10
2.3 mg/kg 0.33 11/18/09 15:10
ND mg/kg 0.65 11116109 15:10
4.3 mg/kg 0.65 11116109 15:10
Analytical Method: EPA6270
ND uglkg 37.6 11116/09 14:09
ND ug/kg 37.6 11116109 14:09
ND ug/kg 37.6 11116109 14:09
ND ug/kg 37.6 11116109 14:09
ND ug/kg 37.6 11116109 14:09
ND ug/kg 37.6 11/1610914:09
ND ug/kg 37.6 11/16109 14:09
ND ug/kg 37.6 11116109 14:09
ND ug/kg 195 11116109 14:09
ND ug/kg 195 11116109 14:09
ND uglkg 766 11/18/09 14:09
ND ug/kg 195 11/18/09 14:09
ND ug/kg 195 11116109 14:09
ND uglkg 195 11/18/0914:09,
ND ug/kg 195 11/18/0914:09
ND ug/kg 195 11/16109 14:09
ND ug/kg 195 11116109 14:09
ND ug/kg 195 11/18/09 14:09
ND ug/kg 37.6 11116/0914:09
ND ug/kg 37.6 11/18/09 14:09
ND ug/kg 195 11/18/09 14:09
ND ug/kg 195 11116109 14:09
ND ug/kg 195 11/18/09 14:09
ND ug/kg 195 11/18/09 14:09
ND ug/kg 766 11116109 14:09
ND ug/kg 195 11/18/09 14:09
ND ug/kg 195 11/18/09 14:09
ND ug/kg 195 11116109 14:09
ND ug/kg 195 11116109 14:09
ND ug/kg 195 11116/09 14:09
ND ug/kg 766 11116109 14:09
ND ug/kg 766 11116109 14:09
ND ug/kg 195 11116109 14:09
REPORT OF LABORATORY ANALYSIS
This report shalt not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc .. .. ~«-oc~e~~ .. ?rnelac1;
Analyzed GAS No.
11119109 16:02 7429-90-5
11119109 16:02 7440-36-0
11119/0916:02 7440-36-2
11/19109 16:02 7440-41-7
11119109 16:02 7440-47-3
11119109 16:02 7440-50-8
11/19/09 16:02 7439-89-6
11119109 16:02 7439-92-1
11/19109 16:02 7440-02-0
11119109 16:02 7440-26-0
11119109 16:02 7440-66-6
11125/09 20:36 63-32-9
11/25109 20:36 206-96-8
11125109 20:36 120-12-7
11125109 20:36 56-55-3
11125109 20:36 50-32-6
11125109 20:36 205-99-2
11125109 20:36 191-24-2
11125109 20:36 207-06-9
11125109 20:36 101-55-3
11/25/09 20:36 65-66-7
11125109 20:36 59-50-7
11/25/09 20:38 106-47-8
11125109 20:36 111-91-1
11125109 20:36 111-44-4
11/25/09 20:38 108-60-1
11125/09 20:36 91-56-7
11125109 20:36 95-57-6
11125109 20:36 7005-72-3
11125109 20:36 216-01-9
11/25/09 20:36 53-70-3
11125109 20:36 132-64-9
11/25/09 20:38 95-50-1
11/25/09 20:38 541-73-1
11125109 20:36 106-46-7
11125109 20:36 91-94-1
11/25/09 20:38 120-83-2
11/25/09 20:38 64-66-2
11125109 20:36 105-67-9
11125109 20:36 131-11-3
11/25/09 20:38 84-74-2
11/25109 20:36 534-52-1
11125109 20:36 51-28-5
11125109 20:36 121-14-2
Oual
PB
L3
L3
L3
L3
Page 33 of 81
Pace Analytical Services, lnc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: CASTLE HAYNE 22-12493D
Pace Project No.: 9257362
Sample: HA-8 LablD: 9257362008 Collected: 11/11/09 14:30 Received: 11/12/09 09:10 Matrix: Solid
Results reported on a "dry-weight" basis
Parameters
8270 MSSV Full List Microwave
2,6-Dinitrotoluene
Di-n-octylphthalate
1,2-Diphenylhydrazine
bis(2-Ethylhexyl)phthalate
Fluoranthene
Fluorene
Hexachloro-1,3-butadiene
Hexachlorobenzene
Hexachlorocyclopentadiene
Hexachloroethane
lndeno(1,2,3-cd )pyrene
lsophorone
1-Methylnaphthalene
2-Methylnaphthalene
2-Methylphenol(o-Cresol)
3&4-Methylphenol(m&p Cresci)
Naphthalene
2-Nitroaniline
3-Nitroaniline
4-Nitroaniline
Nitrobenzene
2-Nitrophenol
4-Nitrophenol
N-Nitrosodimethylamine
N-Nitroso-di-n-propylamine
N-Nitrosodiphenylamine
Pentachlorophenol
Phenanthrene
Phenol
Pyrene
1,2,4-T richlorobenzene
2,4,5-Trichlorophenol
2,4,6-Trichlorophenol
Nitrobenzene-d5 (S)
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
Phenol-<16 (S)
2-Fluorophenol (S)
2,4,6-Tribromophenol (S)
8260/5035A Volatile Organics
Acetone
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Date: 12/04/2009 11 :18 AM
Results Units Report Limit OF Prepared
Analytical Method: EPA 8270
ND ug/kg 195 11/18/09 14:09
ND ug/kg 195 11/18/09 14:09
ND ug/kg 195 11/18/09 14:09
ND ug/kg 195 11/18/09 14:09
ND ug/kg 37.8 11/18/09 14:09
ND ug/kg 37.8 11/18/09 14:09
ND ug/kg 195 11/18/09 14:09
ND ug/kg 195 11/18/09 14:09
ND ug/kg 768 11/18/09 14:09
ND ug/kg 195 11/18/09 14:09
ND ug/kg 37.8 11/18/09 14:09
ND ug/kg 195 11/18/09 14:09
ND ug/kg 37.8 11/18/09 14:09
ND ug/kg 37.8 11/18/09 14:09
ND ug/kg 195 11/18/09 14:09
ND ug/kg 195 11/18/09 14:09
ND ug/kg 37.8 11/18/09 14:09
ND ug/kg 195 11/18/09 14:09
ND ug/kg 195 11/18/09 14:09
ND u91K9 195 11/18/0914:09
ND ug/kg 195 11/18/09 14:09
ND u91K9 195 11/18/09 14:09
ND ug/kg 195 11/18/09 14:09
ND ug/kg 195 11/18/09 14:09
ND ug/kg 195 11/18/09 14:09
ND u91K9 195 11/18/09 14:09
ND ug/kg 768 11/18/09 14:09
ND ug/kg 37.8 11/18/09 14:09
ND ug/kg 195 11/18/09 14:09
ND ug/kg 37.8 11/18/09 14:09
ND ug/kg 195 11/18/09 14:09
ND ug/kg 195 11/18/09 14:09
ND ug/kg 195 11/18/09 14:09
75 % 10-110 11/18/09 14:09
77 % 18-110 11/18/09 14:09
86 % 10-123 11/18/09 14:09
73 % 10-110 11/18/09 14:09
74 % 18-110 11/18/09 14:09
83 % 10-110 11/18/0914:09
Analytical Method: EPA 8260
ND ug/kg 90.1
ND ug/kg 4.5
ND ug/kg 4.5
ND ug/kg 4.5
ND ug/kg 4.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc .. «'~-lnelac;;
Analyzed GAS No. Qual
11/25/09 20:38 606-20-2
11 /25/09 20:38 117-84-0
11/25/09 20:38 122-66-7
11/25/09 20:38 117-81-7
11/25/09 20:38 206-44-0
11/25/09 20:38 86-73-7
11/25/09 20:38 87-68-3
11 /25/09 20:38 118-74-1
11/25/09 20:38 77-47-4
11/25/09 20:38 67-72-1
11/25/09 20:38 193-39-5
11/25/09 20:38 78-59-1
11/25/09 20:38 90-12-0
11 /25/09 20:38 91-57-6
11 /25/09 20:38 95-48-7
11/25/09 20:38 L1
11/25/09 20:38 91-20-3
11/25/09 20:38 88-74-4
11/25/09 20:38 99-09-2
11/25/09 20:38 100-01-6 L3
11/25/09 20:38 98-95-3
11/25/09 20:38 88-75-5
11 /25/09 20:38 100-02-7
11/25/09 20:38 62-75-9
11/25/09 20:38 621-64-7
11/25/09 20:38 86-30-6
11125/09 20:38 87-86-5
11/25/09 20:38 85-01-8
11/25/09 20:38 108-95-2
11/25/09 20:38 129-00-0
11/25/09 20:38 120-82-1
11/25/09 20:38 95-95-4
11/25/09 20:38 88-06-2
11/25/09 20:38 4165-60-0
11/25/09 20:38 321-60-8
11/25/09 20:38 1718-51-0
11/25/09 20:38 13127-88-3
11/25/09 20:38 367-12-4
11/25/09 20:38 118-79-6
11/15/09 13:35 67-64-1
11/15/09 13:35 71-43-2
11/15/09 13:35 108-86-1
11/15/09 13:35 74.97.5
11/15/09 13:35 75-27-4
Page 34 of 81
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: CASTLE HAYNE 22-124930
Pace Project No.: 9257362
Sample: HA-8 LablD: 9257362008 Collected: 11/11/0914:30 Received: 11/12/09 09:10 Matrix: Solid
Results reported on a ndry-weightn basis
Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual
8260/5035A Volatile Organics Analytical Method: EPA8260
Bromoform ND u9/k9 4.5 11/15/0913:35 75-25-2
Bromomethane ND u9/k9 9.0 11/15/09 13:35 74-83-9
2-Butanone (MEK) ND ug/kg 90.1 11/15/09 13:35 78-93-3
n-Butylbenzene ND u9/k9 4.5 11/15/09 13:35 104-51-8
sec-Butylbenzene ND ug/kg 4.5 11/15/09 13:35 135-98-8
tert-Butylbenzene ND ug/kg 4.5 11/15/09 13:35 98-06-6
Carbon tetrachloride ND ug/kg 4.5 11/15/09 13:35 56-23-5
Chlorobenzene NO ug/kg 4.5 11/15/09 13:35 108-90-7
Chloroethane NO ug/kg 9.0 11/15/09 13:35 75-00-3
Chloroform ND ug/kg 4.5 11/15/09 13:35 67-66-3
Chtoromethane ND ug/kg 9.0 11/15/09 13:35 74-87-3
2-Chlorotoluene ND ug/kg 4.5 11/15/09 13:35 95-49-8
4-Chlorotoluene ND ug/kg 4.5 11/15/09 13:35 106-43-4
1,2-Dibromo-3-chloropropane ND ug/kg 4.5 11/15/09 13:35 96-12-8
Oibromochloromethane ND ug/kg 4.5 11/15/0913:35 124-48-1
1,2-Dibromoethane (EOB) NO ug/kg 4.5 11/15/09 13:35 106-93-4
Dibromomethane ND ug/kg 4.5 11/15/09 13:35 74-95-3
1,2-Dichlorobenzene ND ug/kg 4.5 11/15/09 13:35 95-50-1
1,3-Dichlorobenzene ND u9/k9 4.5 11/15/09 13:35 541-73-1
1,4-Dichlorobenzene ND ug/kg 4.5 11/15/09 13:35 106-46-7
Dichlorodifluoromethane ND u9/k9 9.0 11115/09 13:35 75-71-8
1, 1-Dichloroethane ND ug/kg 4.5 11/15/09 13:35 75-34-3
1,2-Dichloroethane ND ug/kg 4.5 11/15/09 13:35 107-06-2
1, 1-Oichloroethene ND ug/kg 4.5 11/15/09 13:35 75-35-4
cis-1,2-Dichloroethene ND ug/kg 4.5 11/15/09 13:35 156-59-2
trans-1,2-Oichloroethene NO ug/kg 4.5 11/15/09 13:35 156-60-5
1,2-Dichloropropane NO ug/kg 4.5 11/15/09 13:35 78-87-5
1,3-Dichloropropane NO ug/kg 4.5 11/15/09 13:35 142-28-9
2,2-Dichloropropane NO ug/kg 4.5 11/15/09 13:35 594-20-7
1, 1-Oichloropropene ND ug/kg 4.5 11/15/09 13:35 563-58-6
cis-1,3-Dichloropropene NO ug/kg 4.5 11/15/09 13:35 10061-01-5
trans-1,3-Dichloropropene ND ug/kg 4.5 11/15/09 13:35 10061-02-6
Diisopropyl ether ND ug/kg 4.5 11/15/09 13:35 108-20-3
Ethylbenzene ND ug/kg 4.5 11/15/09 13:35 100-41-4
Hexachloro-1,3-butadiene ND ug/kg 4.5 11/15/09 13:35 87-68-3
2-Hexanone ND ug/kg 45.0 11/15/09 13:35 591-78-6
lsopropylbenzene (Cumene) ND ug/kg 4.5 11/15/09 13:35 98-82-8
p-tsopropyltoluene NO ug/kg 4.5 11/15/09 13:35 99-87-6
Methylene Chloride ND ug/kg 18.0 11/15/09 13:35 75-09-2
4-Methyl-2-pentanone (MIBK) ND ug/kg 45.0 11/15/09 13:35 108-10-1
Methyl-tert-butyl ether ND ug/kg 4.5 11/15/09 13:35 1634-04-4
Naphthalene ND ug/kg 4.5 11/15/09 13:35 91-20-3
n-Propylbenzene ND ug/kg 4.5 11/15/09 13:35 103-65-1
Styrene ND ug/kg 4.5 11/15/09 13:35 100-42-5
1, 1, 1,2-Tetrachloroethane ND ug/kg 4.5 11/15/09 13:35 630-20-6
1, 1,2,2-Tetrachloroethane ND ug/kg 4.5 11/15/09 13:35 79-34-5
Date: 12/04/2009 11: 18 AM REPORT OF LABORATORY ANALYSIS Page 35 of 81
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
. {PF~~~ .. ?1nelac1;
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: CASTLE HAYNE 22-124930
Pace Project No.: 9257362
Sample: HA-8 LablD: 9257362008 Collected: 11/11/09 14:30 Received: 11/12/09 09:10 Matrix: Solid
Results reported on a "dry-weight" basis
Parameters
826015035A Volatile Organics
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1, 1, 1-Trichloroethane
1, 1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1 ,2,4-T rimethylbenzene
1,3,5-Trimethylbenzene
Vinyl acetate
Vinyl chloride
Xylene (Total)
m&p-Xylene
a-Xylene
Dibromofluoromethane (S) ·
Toluene-dB (S)
4-Bromofluorobenzene (S)
1,2-Dich1oroethane-d4 (S)
Percent Moisture
Percent Moisture
Date: 12/04/2009 11 :18 AM
Results Units Report Limit DF Prepared
Analytical Method: EPA 8260
ND ug/kg 4.5
ND u9/k9 4.5
ND ug/kg 4.5
ND u9/k9 4.5
ND ug/kg 4.5
ND ug/kg 4.5
ND uglkg 4.5
ND ug/kg 4.5
ND u9/k9 4.5
ND ug/kg 4.5
ND uglkg 4.5
ND ug/kg 45.0
ND ug/kg 9.0
ND ug/kg 9.0
ND ug/kg 9.0
ND ug/kg 4.5
100 % 79-116
96 % 88-110
96 % 74-115
92 % 69-121
Analytical Method: ASTM D2974-87
14.2 % 0.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
,.'ff"°t;,"""---;,/neldC\,
Analyzed CAS No. Qual
11/15/09 13:35 127-18-4
11/15/09 13:35 108-88-3
11/15/09 13:35 87-61-6
11/15/09 13:35 120-82-1
11/15/09 13:35 71-55-6
11/15/09 13:35 79-00-5
11/15/09 13:35 79-01-6
11/15/09 13:35 75-69-4
11/15/0913:35 96-18-4
11/15/09 13:35 95-63-6
11/15/09 13:35 108-67-8
11/15/09 13:35 108-05-4
11/15/09 13:35 75-01-4
11/15/09 13:35 1330-20-7
11/15/0913:35 1330-20-7
11/15/09 13:35 95-47-6
11/15/09 13:35 1868-53-7
11/15/09 13:35 2037-26-5
11/15/09 13:35 460-00-4
11/15/09 13:35 17060-07-0
11/17/09 08:56
Page 36 of 81
Pace Analytical Sorvicos, Inc.
2225 Riverside Or.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, lnc.
9800 Kincey Ave. Suite 100
Huntersville. NC 28078
(704 }875-9092
Project: CASTLE HAYNE 22-12493D
Pace Project No.: 9257362
Sample: HA-9 LablD: 9257362009 Collected: 11/11/09 09:30 Received: 11/12/09 09:10 Matrix: Solid
Results reported on a "dry-weight" basis
Parameters
6010 MET ICP
Aluminum
Antimony
Arsenic
Beryllium
Chromium
Copper
Iron
Lead
Nickel
Thallium
Zinc
8270 MSSV Full List Microwave
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b )fluoranthene
Benzo(g, h, i )perylene
Benzo(k)fluoranthene
4-Bromophenylphenyl ether
Butylbenzylphthalate
4-Chloro-3-methylphenol
4-Chloroaniline
bis(2-Chloroethoxy)methane
bis(2-Chloroethyl) ether
bis(2-Chloroisopropyl) ether
2-Chloronaphthalene
2-Chlorophenol
4-Chlorophenylphenyl ether
Chrysene
Dibenz(a,h )anthracene
Dibenzofuran
1,2-Dichlorobenzene
1,3-Dichtorobenzene
1,4-Dichlorobenzene
3,3'-Dichlorobenzidine
2,4-Di<=:hlorophenol
Diethylphthalate
2,4-Dimethylphenol
Dimethylphthalate
Di-n-butylphthalate
4,6-Dinitro-2-methylphenol
2,4-Dinitrophenol
2,4-Dinitrotoluene
Date: 1210412009 11:18AM
Results Units Report Limit OF Prepared
Analytical Method: EPA6010 Preparation Method: EPA3050
1000 mg/kg 7.5 11118109 15:10
ND mg/kg 0.37 1111810915:10
6.0 mg/kg 0.37 11118109 15:10
0.20 mg/kg 0.075 11118109 15:10
3.5 mg/kg 0.37 11118109 15:10
0.37 mg/kg 0.37 11118109 15:10
4520 mg/kg 3.7 1111810915:10
1.7 mg/kg 0.37 11118109 15:10
1.1 mg/kg 0.37 11118109 15:10
ND mg/kg 0.75 11118109 15:10
4.7 mg/kg 0.75 11118109 15:10
Analytical Method: EPA 8270
ND uglkg 37.7 11118109 14:09
ND ug/kg 37.7 11118109 14:09
ND ug/kg 37.7 11118109 14:09
ND ug/kg 37.7 11118109 14:09
ND ug/kg 37.7 1111810914:09
ND ug/kg 37.7 11118109 14:09
ND ug/kg 37.7 11/18/09 14:09
ND ug/kg 37.7 11/18/09 14:09
ND ug/kg 194 11118109 14:09
ND ug/kg 194 11/18/09 14:09
ND ug/kg 765 11/18/0914:09
ND ug/kg 194 11118109 14:09
ND uglkg 194 11/18/09 14:09
ND ug/kg 194 11/18/09 14:09
ND ug/kg 194 11118109 14:09
ND uglkg 194 11/18/09 14:09
ND ug/kg 194 11118109 14:09
ND ug/kg 194 11118109 14:09
ND ug/kg 37.7 11/18/09 14:09
ND ug/kg 37.7 11118109 14:09
ND ug/kg 194 11118109 14:09
ND ug/kg 194 11118109 14:09
ND ug/kg 194 11118109 14:09
ND ug/kg 194 11118109 14:09
ND ug/kg 765 11/18/09 14:09
ND ug/kg 194 1111810914:09
ND ug/kg 194 11118109 14:09
ND ug/kg 194 11/18/09 14:09
ND ug/kg 194 11118109 14:09
ND uglkg 194 11118109 14:09
ND ug/kg 765 11/18/09 14:09
ND ug/kg 765 11118109 14:09
ND ug/kg 194 11118109 14:09
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services. Inc ..
.. 1/f-'iS"'--?1□ek1Ci,
Analyzed CA$ No.
11119109 16:06 7429-90-5
11/19/09 16:06 7440-36-0
11119109 16:06 7440-38-2
11119109 16:06 7440-41-7
11119/0916:06 7440-47-3
11119109 16:06 7440-50-8
11119109 16:06 7439-89-6
11119109 16:06 7439-92-1
11119109 16:06 7440-02-0
11119109 16:06 7440-28-0
1111910916:06 7440-66-6
11125109 21:08 83-32-9
11125109 21:08 208-96-8
11125109 21:08 120-12-7
11125109 21:08 56-55-3
11125109 21:08 50-32-8
11125109 21:08 205-99-2
11125109 21:08 191-24-2
11125109 21:08 207-08-9
11125/09 21:08 101-55-3
11125/09 21:08 85-68-7
11125109 21:08 59-50-7
11125109 21 :08 106-47-8
11125109 21:08 111-91-1
11125109 21:08 111-44-4
11125109 21:08 108-60-1
11125109 21:08 91-58-7
11125109 21:08 95-57-8
11125109 21 :08 7005-72-3
11125109 21:08 218-01-9
11125109 21:08 53-70-3
11125109 21:08 132-64-9
11125109 21:08 95-50-1
11125109 21:08 541-73-1
11125109 21:08 106-46-7
11/25/09 21:08 91-94-1
11125109 21:08 120-83-2
11125109 21:08 64-66-2
11125109 21 :08 105-67-9
11125109 21:08 131-11-3
11125109 21:08 84-74-2
11125109 21:08 534-52-1
11125109 21:08 51-28-5
11125109 21:08 121-14-2
Qual
P8
L3
L3
L3
L3
Page 37 of 81
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, 1nc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704 )875-9092
Project: CASTLE HAYNE 22-12493D
Pace Project No.: 9257362
Sample: HA-9 LablD: 9257362009 Col!ecied: 11/11/09 09:30 Received: 11/12/09 09:10 Matrix: Solid
Results reported on a "dry-weight" basis
Parameters
8270 MSSV Full List Microwave
2,6-Dinitrotoluene
Di-n-octylphthalate
1,2-Diphenylhydrazine
bis(2-Ethylhexy1)phthatate
Fluoranthene
Fluorene
Hexachloro-1,3-butadiene
Hexachlorobenzene
He~achlorocyc1opentadiene
Hexachloroethane
lndeno( 1,2,3-cd)pyrene
lsophorone
1-Methylnaphthalene
2-Methylnaphthatene
2-Methylphenol(o-Cresol}
3&4-Methylphenol(m&p Cresci)
Naphthalene
2-Nitroaniline
3-Nitroaniline
4-Nitroaniline
Nitrobenzene
2-Nitrophenol
4-Nitrophenol
N-Nitrosodimethylamine
N-Nitroso-di-n-propylamine
N-Nitrosodiphenylamine
Pentachlorophenol
Phenanthrene
Phenol
Pyrene
1,2,4-Trichlorobenzene
2,4,5-T richlorophenot
2,4,6-Trichlorophenol
Nitrobenzene-d5 (S)
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
Pheno/-d6 (S)
2-Fluorophenol (S)
2,4,6-Tribromophenol (S)
826D/5035A Volatile Organics
Acetone
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Date: 12/04/2009 11:18AM
Results Units Report.Limit DF Prepared
Analytical Method: EPA 8270
NO ug/kg 194 11/18/09 14:09
ND ug/kg 194 11/18/09 14:09
ND ug/kg 194 11/18/09 14:09
ND ug/kg 194 11/18/09 14:09
ND u9lk9 37.7 11/18/09 14:09
ND ug/kg 37.7 11/18/09 14:09
ND ug/kg 194 11/18/09 14:09
ND ug/kg 194 11/18/0914:09
NO ug/kg 765 11/18/09 14:09
ND ug/kg 194 11/18/09 14:09
ND u9lk9 37.7 11/18/09 14:09
ND ug/kg 194 11/18/09 14:09
ND ug/kg 37.7 11/18/09 14:09
ND ug/kg 37.7 11/18/0914:09
NO ug/kg 194 11/18/09 14:09
ND ug/kg 194 11/18/09 14:09
ND ug/kg 37.7 11/18/09 14:09
ND ug/kg 194 11/18/09 14:09
ND ug/kg 194 11/18/09 14:09
ND ug/kg 194 11/18/09 14:09
ND ug/kg 194 11/18/09 14:09
ND u9/k9 194 11/18/09 14:09
ND ug/kg 194 11/18/09 14:09
ND ug/kg 194 11/18/09 14:09
ND ug/kg 194 11/18/09 14:09
ND ug/kg 194 11/18/0914:09
ND ug/kg 765 11/18/09 14:09
NO ug/kg 37,7 11/18/09 14:09
ND ug/kg 194 11/18/09 14:09
ND ug/kg 37.7 11/18/09 14:09
ND ug/kg 194 11/18/09 14:09
ND ug/kg 194 11/18/09 14:09
ND ug/kg 194 11/18/09 14:09
73 % 10-110 11/18/09 14:09
79 % 18-110 11/18/09 14:09
89 % 10-123 11/18/09 14:09
75 % 10-110 11/18/09 14:09
70 % 18-110 11/18/09 14:09
87 % 10-110 11/18/09 14:09
Analytical Method: EPA 8260
ND ug/kg 119
ND ug/kg 6.0
ND ug/kg 6.0
ND ug/kg 6.0
ND ug/kg 6.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Analyzed CAS No. Qual
11/25/09 21:08 606-20-2
11/25/09 21:08 117-84-0
11/25/09 21 :08 122-66-7
11/25/09 21 :08 117-81-7
11/25/09 21:08 206-44-0
11/25/09 21:08 86-73-7
11/25/09 21:08 87-68-3
11/25/09 21 :08 118-74-1
11/25/09 21 :08 77-47-4
11/25/09 21:08 67-72-1
11/25/09 21:08 193-39-5
11/25/09 21:08 78-59-1
11/25/09 21:08 90-12-0
11/25/09 21 :08 91-57-6
11/25/09 21 :08 95-48-7
11/25/09 21:08 L3
11/25/09 21:08 91-20-3
11/25/09 21:08 88-74-4
11/25/09 21:08 99-09-2
11/25/09 21:08 100-01-6 L3
11/25/09 21:08 98-95-3
11/25/09 21:08 88-75-5
11/25/09 21:08 100-02:7
11/25/09 21:08 62-75-9
11/25/09 21 :08 621-64-7
11/25/09 21 :08 86-30-6
11/25/09 21:08 87-86-5
11/25/09 21 :08 85-01-8
11/25/09 21 :08 108-95-2
11/25/09 21:08 129-00-0
11/25/09 21:08 120-82-1
11/25/09 21:08 95-95-4
11/25/09 21:08 88-06-2
11/25/09 21 :08 4165-60-0
11/25/09 21 :08 321-60-8
11/25/09 21:08 1718-51-0
11/25/09 21:08 13127-88-3
11/25/09 21:08 367-12-4
11/25/09 21 :08 118-79-6
11/15/09 13:53 67-64-1
11/15/09 13:53 71-43-2
11/15/09 13:53 108-86-1
11/15/09 13:53 74-97-5
11/15/09 13:53 75-27-4
Page 38 of 81
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: CASTLE HAYNE 22-12493D
Pace Project No.: 9257362
Sample: HA-9 LablO: 9257362009 Collected: 11/11/09 09:30 Received: 11/12/09 09:10 Matrix: Solid ·
Results reported on a "dry-weight" basis
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
826015035A Volatile Organics Analytical Method: EPA8260
Bromoform ND ug/kg 6.0 11/15/0913:53 75-25-2
Bromomethane ND ug/kg 11.9 11/15/09 13:53 74-83-9
2-Butanone (MEK) ND ug/kg 119 11/15/09 13:53 78-93-3
n-Butylbenzene ND ug/kg 6.0 11/15/09 13:53 104-51-8
sec-Butylbenzene ND ug/kg 6.0 11/15/09 13:53 135-98-8
tert-Butylbenzene ND ug/kg 6.0 11/15/09 13:53 98-06-6
Carbon tetrachloride ND ug/kg 6.0 11/15/09 13:53 56-23-5
Chlorobenzene ND ug/kg 6.0 11/15/09 13:53 108-90-7
Chloroethane ND ug/kg 11.9 11/15/09 13:53 75-00-3
Chloroform ND ug/kg 6.0 11/15/09 13:53 67-66-3
Chloromethane ND ug/kg 11.9 11/15/09 13:53 74-87-3
2-Chlorotoluene ND ug/kg 6.0 11/15/09 13:53 95-49-8
4-Chlorotoluene ND ug/kg 6.0 11 /15/09 13:53 106-43-4
1,2-Dibromo-3-chtoropropane ND ug/kg 6.0 11/15/09 13:53 96-12-8
Oibromochloromethane ND ug/kg 6.0 11/15/09 13:53 124-48-1
1,2-Dibromoethane (EDS) ND ug/kg 6.0 11115/09 13:53 106-93-4
Dibromomethane ND ug/kQ 6.0 11/15/09 13:53 74-95-3
1,2-Dichlorobenzene ND ug/kg 6.0 11/15/0913:53 95-50-1
1,3-Dichlorobenzene ND ug/kg 6.0 11/15/09 13:53 541-73-1
1,4-Dichlorobenzene ND ug/kg 6.0 11/15/09 13:53 106-46-7
Oic~lorodifluoromethane ND ug/kg 11.9 11/15/09 13:53 75-71-8
1, 1-Dichloroethane ND ug/kg 6.0 11/15/09 13:53 75-34-3
1,2-Dichloroethane ND ug/kg 6.0 11/15/09 13:53 107-06-2
1, 1-Dichloroethene ND ug/kg 6.0 11/15/09 13:53 75-35-4
cis-1,2-Dichloroethene ND ug/kg 6.0 11/15/09 13:53 156-59-2
trans-1,2-Dichloroethene ND ug/kg 6.0 11/15/09 13:53 156-60-5
1,2-Dichloropropane ND ug/kg 6.0 11/15/09 13:53 78-87-5
1,3-0ichloropropane ND ug/kg 6.0 11/15/09 13:53 142-28-9
2,2-Dichloropropane ND ug/kg 6.0 11/15/09 13:53 594-20-7
1, 1-Dichloropropene ND ug/kg 6.0 11/15/09 13:53 563-58-6
cis-1,3-Dichloropropene ND ug/kg 6.0 11/15/0913:53 10061-01-5
trans-1,3-0ichloropropene NO ug/kg 6.0 11/15/09 13:53 10061-02-6
Oiisopropyl ether NO ug/kg 6.0 11/15/09 13:53 108-20-3
Ethylbenzene ND ug/kg 6.0 11/15/09 13:53 100-41-4
Hexachloro-1,3-butadiene ND ug/kg 6.0 11/15/09 13:53 87-68-3
2-Hexanone ND ug/kg 59.5 11/15/09 13:53 591-78-6
lsopropylbenzene (Cumene) NO ug/kg 6.0 11/15/09 13:53 98-82-8
p-lsopropyltoluene ND ug/kg 6.0 11/15/09 13:53 99-87-6
Methylene Chloride ND ug/kg 23.8 11/15/09 13:53 75-09-2
4-Methyl-2-pentanone (MIBK) ND ug/kg 59.5 11/15/09 13:53 108-10-1
Methyl-tert-butyl ether ND ug/kg 6.0 11/15/09 13:53 1634-04-4
Naphthalene ND ug/kg 6.0 11/15/09 13:53 91-20-3
n-Propylbenzene ND ug/kg 6.0 11/15/09 13:53 103-65-1
Styrene ND ug/kg 6.0 11/15/09 13:53 100-42-5
1, 1, 1,2-Tetrachloroethane ND ug/kg 6.0 11/15/09 13:53 630-20-6
1, 1,2,2-Tetrachloroethane ND ug/kg 6.0 11/15/09 13:53 79-34-5
Date: 12/04/200911:18AM REPORT OF LABORATORY ANALYSIS Page 39 of 81
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
~o__'.!.!.<_g~~.
,:,'/'1 ~ ~~~ 11ne ei,
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704 )875-9092
Project: CASTLE HAYNE 22-12493D
Pace Project No.: 9257362
Sam pie: HA-9 LablD: 9257362009 Collected: 11/11/09 09:30 Received: 11/12/09 09:10 Matrix: Solid
Results reported on a "dry-weight" basis
Parameters
826015035A Volatile Organics
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1, 1, 1-Trichtoroethane
1, 1,2-T richloroethane
Trichloroethene
T richloroftuoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl acetate
Vinyl chloride
Xylene (Total)
m&p-Xylene
a-Xylene
Dibromofluoromethane (S)
Toluene-dB (S)
4-Bromoftuorobenzene (S)
1,2-Dichtoroethane-d4 ($)
Percent Moisture
Percent Moisture
Date: 12/04/2009 11: 18 AM
Results Units Report Limit OF Prepared
Analytical Method: EPA8260
ND ug/kg 6.0
ND ug/kg 6.0
ND ug/kg 6.0
ND ug/kg 6.0
ND ug/kg 6.0
ND ug/kg 6.0
ND ug/kg 6.0
ND ug/kg 6.0
ND ug/kg 6.0
ND ug/kg 6.0
ND ug/kg 6.0
ND ug/kg 59.5
ND ug/kg 11.9
ND ug/kg 11.9
ND ug/kg 11.9
ND ug/kg 6.0
107 % 79-116
99 % 88-110
93 % 74-115
91 % 69-121
Analytical Method: ASTM D2974-87
13.0 % 0.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
~~.:..'!-'"..:::~~. l/1 I~~" .. m1eldC1\
Analyzed CAS No. Qual
11/15/09 13:53 127-18-4
11/15/09 13:53 108-88-3
11/15/0913:53 87-61-6
11 /15/09 13:53 120-82-1
11 /15/09 13:53 71-50-6
11/15/09 13:53 79-00-5
11/15/09 13:53 79-01-6
11/15/09 13:53 75-69-4
11/15/0913:53 96-18-4
11/15/0913:53 95-63-6
11 /15/09 13:53 108-67-8
11/15/09 13:53 108-05-4
11/15/09 13:53 75-01-4
11/15/09 13:53 1330-20-7
11/15/0913:53 1330-20-7
11/15/0913:53 95-47-6
11 /15/09 13:53 1868-53-7
11 /15/09 13:53 2037-26-5
11/15/09 13:53 460-00-4
11/15/09 13:53 17060-07-0
11 /17/09 08:56
Page 40 of 81
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704 }875-9092
Project: CASTLE HAYNE 22-124930
Pace Project No.: 9257362
Sample: HA-10 LablD: 9257362010 Collected: 11/11/09 10:45 Received: 11/12/09 09:10 Matrix: Solid
Results reported on a "dry-weight" basis
Parameters
6010 MET ICP
Aluminum
Antimony
Arsenic
Beryllium
Chromium
Copper
Iron
Lead
Nickel
Thallium
Zinc
8270 MSSV Full List Microwave
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b )fluoranthene
Benzo( g, h, i)pe rylene
Benzo(k)fluoranthene
4-Bromophenylphenyl ether
Butylbenzylphthalale
4-Chloro-3-methylphenol
4-Chloroaniline
bis(2-Chloroethoxy)methane
bis(2-Chloroethyl) ether
bis(2-Chloroisopropyl) ether
2-Chloronaphthalene
2-Chlorophenol
4-Chlorophenylphenyl ether
Chrysene
D ibe nz( a, h )anthracene
Dibenzofuran
1,2-Dichlorobenzene
1,3-Dich1orobenzene
1,4-Dichlorobenzene
3,3'-Dichlorobenzidine
2,4-Dichlorophenol
Diethylphthalate
2,4-Dimelhylphenol
Dimethylphthalate
Di-n-butylphthalate
4,6-Dinitro-2-methylphenol
2,4-Dinitrophenol
2,4-Dinitrotoluene
Date: 12/04l200911:18AM
Results Units Report Limit OF Prepared
Analytical Method: EPA6010 Preparation Method: EPA3050
1770 mg/kg 7.6 11/18/09 15:10
ND mg/kg 0.38 11/18/09 15:10
1.4 mg/kg 0.38 11/18/09 15:10
0.21 mg/kg 0.076 11/18/09 15:10
3.9 mg/kg 0.38 11/18/09 15:10
ND mg/kg 0.38 11/18/09 15:10
2760 mg/kg 3.8 11/18/09 15:10
1.8 mg/kg 0.38 11/18/09 15:10
1.9 mg/kg 0.38 11/16/09 15:10
ND mg/kg 0.76 11/18/09 15:10
4.7 mg/kg 0.76 11/16/09 15:10
Analytical Method: EPA 8270
ND ug/kg 39.1 11/18/09 14:09
ND ug/kg 39.1 11/18/09 14:09
ND ug/kg 39.1 11/18/09 14:09
ND uglkg 39.1 11/18/09 14:09
ND ug/kg 39.1 11/18/09 14:09
ND uglkg 39.1 11/16/09 14:09
ND u9/k9 39.1 11/18/0914:09
ND ug/kg 39.1 11/18/09 14:09
ND ug/kg 202 11/18/09 14:09
ND ug/kg 202 11/18/09 14:09
ND ug/kg 794 11/18/09 14:09
ND ug/kg 202 11/18/09 14:09
ND ug/kg 202 11/18/09 14:09
ND ug/kg 202 11/16/0914:09
ND ug/kg 202 11/18/09 14:09
ND ug/kg 202 11/18/09 14:09
ND ug/kg 202 11/18/09 14:09
ND uglkg 202 11118/09 14:09
ND uglkg 39.1 11/18/09 14:09
ND uglkg 39.1 11/16/09 14:09
ND uglkg 202 11/18/09 14:09
ND ug/kg 202 11/18/09 14:09
ND ug/kg 202 11/18/09 14:09
ND ug/kg 202 11/18/09 14:09
ND uglkg 794 11/18/09 14:09
ND ug/kg 202 11/18/09 14:09
ND uglkg 202 11/18/09 14:09
ND ug/kg 202 11/18/09 14:09
ND ug/kg 202 11/18/09 14:09
ND ug/kg 202 11/16/0914:09
ND ug/kg 794 11/18/09 14:09
ND ug/kg 794 11/18/09 14:09
ND ug/kg 202 11/18/09 14:09
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
~Q~f~-~~~~
?1□ekl.C1,
Analyzed CAS No.
11/19/09 16:10 7429-90-5
11/19/09 16:10 7440-36-0
11/19/09 16:10 7440-38-2
11/19/09 16:10 7440-41-7
11/19/09 16:10 7440-47-3
11/19/0916:10 7440-50-8
11/19/09 16:10 7439-89-6
11/19/09 16:10 7439-92-1
11/19/09 16:10 7440-02-0
11/19/09 16:10 7440-28-0
11/19/09 16:10 7440-66-6
11/25/09 21:38 83-32-9
11/25/09 21:38 208-96-8
11/25/09 21:38 120-12-7
11/25/09 21:38 56-55-3
11/25/09 21:38 50-32-8
11/25/09 21:38 205-99-2
11/25/09 21:38 191-24-2
11/25/09 21:38 207-08-9
11/25/09 21:38 101-55-3
11/25/09 21:38 85-68-7
11/25/09 21:38 59-50-7
11/25/09 21:38 106-47-8
11/25/09 21:38 111-91-1
11/25/09 21:38 111-44-4
11/25/09 21:38 108-60-1
11/25/09 21:38 91-58-7
11/25/09 21:38 95-57-8
11/25/09 21:38 7005-72-3
11/25/09 21:38 218-01-9
11/25/09 21:38 53-70-3
11/25/09 21 :38 132-64-9
11/25/09 21:38 95-50-1
11/25/09 21 :38 541-73-1
11/25/09 21:38 106-46-7
11/25/09 21:38 91-94-1
11/25/09 21:38 120-83-2
11/25/09 21:38 84-66-2
11/25/09 21:38 105-67-9
11/25/09 21:38 131-11-3
11/25/09 21:38 84•74-2
11/25/09 21:38 534-52-1
11/25/09 21:38 51-28-5
11/25/09 21:38 121-14-2
Qual
PB
L3
L3
L3
L3
Page41 of81
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville. NC 28078
[phone]
Project: CASTLE HAYNE 22-12493D
Pace Project No.: 9257362
Sample: HA-10 LablD: 9257362010 Collected: 11/11/09 10:45 Received: 11/12/09 09:10 Matrix: Solid
Results reported on a "dry-weight" basis
Parameters
8270 MSSV Full List Microwave
2,6-Dinitrotoluene
Di-n-octylphthalate
1,2-Diphenylhydrazine
bis(2-Ethylhexyl)phthalate
Fluoranthene
Fluorene
Hexachloro-1,3-butadiene
Hexachlorobenzene
Hexachlorocyclopentadiene
Hexachloroethane
lndeno(1,2, 3--cd)pyrene
lsophorone
1-Methylnaphthalene
2-Methylnaphthalene
2-Methylphenol(o-Cresol)
3&4-Methylphenol(m&p Cresol)
Naphthalene
2-Nitroaniline
3-Nitroaniline
4-Nitroaniline
Nitrobenzene
2-Nitrophenol
4-Nitrophenol
N-Nitrosodimethylamine
N-Nitroso-di-n-propylamine
N-Nitrosodiphenylamine
Pentachlorophenol
Phenanthrene
Phenol
Pyrene
1,2,4-Trichtorobenzene
2,4,5-Trichlorophenol
2,4,6-Trichlorophenol
Nitrobenzene-d5 (S)
2-Ftuorobiphenyl (S)
Terphenyl-d14 (S)
Phenol-d6 (S)
2-Fluorophenol (S)
2,4,6-Tribromophenol (S)
8260/5035A Volatile Organics
Acetone
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Date: 12/04/2009 11:18AM
Results Units Report Limit DF Prepared
Analytical Method: EPA 8270
ND ug/kg 202 11/18/09 14:09
ND ug/kg 202 11/18/09 14:09
ND ug/kg 202 11/18/09 14:09
ND ug/kg 202 11/18/09 14:09
ND ug/kg 39.1 11/16/0914:09
ND ug/kg 39.1 11/18/09 14:09
ND ug/kg 202 11/18/09 14:09
ND ug/kg 202 11/18/09 14:09
ND ug/kg 794 11/16/09 14:09
ND ug/kg 202 11118109 14:09
ND ug/kg 39.1 11/18/09 14:09
ND ug/kg 202 11/18/09 14:09
ND ug/kg 39.1 11/18/09 14:09
ND ug/kg 39.1 11/18109 14:09
ND ug/kg 202 11/18/09 14:09
ND ug/kg 202 11/18/09 14:09
ND ug/kg 39.1 11118109 14:09
ND ug/kg 202 11/16/09 14:09
ND ug/kg 202 11/18/09 14:09
ND ug/kg 202 11/18/09 14:09
ND ug/kg 202 11/18/09 14:09
ND ug/kg 202 11/16/09 14:09
ND ug/kg 202 11/18/09 14:09
ND ug/kg 202 11/18/09 14:09
ND ug/kg 202 11/18/09 14:09
ND ug1<;g 202 11/16/09 14:09
ND ug/kg 794 11/16/09 14:09
NO ug/kg 39.1 11/18/09 14:09
ND ug/kg 202 11/18/09 14:09
ND ug/kg 39.1 11/18/09 14:09
ND ug/kg 202 11/18/09 14:09
ND ug/kg 202 11/18/09 14:09
ND ug/kg 202 11/18/09 14:09
71 % 10-110 11/18/09 14:09
76 % 18-110 11/18109 14:09
83 % 10-123 11/18/09 14:09
70 % 10-110 11/16/09 14:09
70 % 16-110 11/18/09 14:09
84 % 10-110 11/16/09 14:09
Analytical Method: EPA 8260
127 ug/kg 78.7
ND ug/kg 3.9
ND ug/kg 3.9
ND ug/kg 3.9
ND ug/kg 3.9
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in !ult,
without the written consent of Pace Analytical Services, Inc ..
.. -:>'{~~--11nek1C1,
Analyzed CAS No. Qual
11/25/09 21:36 606-20-2
11/25/09 21 :38 117-84-0
11/25/09 21:38 122-66-7
11/25/09 21:38 117-81-7
11/25/09 21:38 206-44-0
11/25/09 21 :38 86-73-7
11/25/09 21:38 87-68-3
11/25/09 21:38 116-74-1
11/25/09 21:38 77-47-4
11/25/09 21:38 67-72-1
11/25/09 21:38 193-39-5
11/25/09 21 :38 78-59-1
11/25/09 21:38 90-12-0
11/25/09 21:38 91-57-6
11/25/09 21:38 95-48-7
11/25/09 21:38 L3
11/25/09 21:38 91-20-3
11/25/09 21 :38 88-74-4
11/25/09 21 :38 99-09-2
11/25/09 21 :38 100-01-6 L3
11/25/09 21:38 98-95-3
11/25/09 21:38 88-75-5
11/25/09 21:38 100-02-7
11/25/09 21:36 62-75-9
11/25/09 21:38 621-64-7
11/25/09 21:38 86-30-6
11/25/09 21:38 87-86-5
11/25/09 21:38 85-01-8
11/25/09 21:38 108-95-2
11/25109 21 :38 129-00-0
11/25/09 21:38 120-82-1
11/25/09 21:38 95-95-4
11/25/09 21 :38 88-06-2
11/25/09 21 :38 4165-60-0
11125/09 21:38 321-60-8
11/25/09 21 :38 1718-51-0
11/25/09 21:38 13127-88-3
11/25/09 21 :38 367-12-4
11/25/09 21:38 118-79-6
11/16109 16:10 67-64-1 C9
11/16/09 16:10 71-43-2
11/16/09 16:10 108-86-1
11/16/09 16:10 74.97.5
11/16/09 16:10 75-27-4
Page 42 of 81
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: CASTLE HAYNE 22-124930
Pace Project No.: 9257362
Sample: HA-10 LablD: 9257362010 Collected: 11/11/09 10:45 Received: 11/12/09 09:10 Matrix: Solid
Results reported on a "dry-weight" basis
Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual
8260/5035A Volatile Organics Analytical Method: EPA 8260
Bromoform ND u9/k9 3.9 11/16/09 16:10 75-25-2
Bromomethane ND ug/kg 7.9 11/16/09 16:10 74-83-9
2-Butanone (MEK) ND ug/kg 78.7 11/16/09 16:10 78-93-3
n-Butylbenzene ND u9/k9 3.9 11/16/09 16:10 104-51-8
sec-Butylbenzene ND ug/kg 3.9 11/16/09 16:10 135-98-8
tert-Butylbenzene ND ug/kg 3.9 11/16/09 16:10 98-06-6
Carbon tetrachloride ND ug/kg 3.9 11/16/09 16:10 56-23-5
Chlorobenzene ND ug/kg 3.9 11/16/09 16:10 108-90-7
Chloroethane ND u9/k9 7.9 11/16/09 16:10 75-00-3
Chloroform ND ug/kg 3.9 11/16/09 16:10 67-66-3
Chloromethane ND ug/kg 7.9 11/16/09 16:10 74-87-3
2-Chlorotoluene ND ug/kg 3.9 11/16/09 16:10 95-49-8
4-Chlorotoluene ND ug/kg 3.9 11/16/09 16:10 106-43-4
1,2-Dibromo-3-chloropropane ND ug/kg 3.9 11/16/09 16:10 96-12-8
Dibromochloromethane ND ug/kg 3.9 11/16/09 16:10 124-48-1
1,2-Dibromoethane (EDS) ND ug/kg 3.9 11/16/09 16:10 106-93-4
Dibromomethane ND ug/kg 3.9 11/16/09 16:10 74-95-3
1,2-Dichlorobenzene ND ug/kg 3.9 11/16/09 16:10 95-50-1
1,3-Dichlorobenzene ND u9/k9 3.9 11/16/09 16:10 541-73-1
1,4-Dichlorobenzene ND ug/kg 3.9 11/16/09 16:10 106-46-7
Dichlorodifluoromethane ND ug/kg 7.9 11/16/09 16:10 75-71-8
1, 1-Dichloroethane ND ug/kg 3.9 11/16/09 16:10 75-34-3
1,2-Dichloroethane ND ug/kg 3.9 11/16/09 16:10 107-06-2
1, 1-Dichtoroethene ND ug/kg 3.9 11/16/09 16:10 75-35-4
cis-1,2-Dichloroethene ND ug/kg 3.9 11/16/09 16:10 156-59-2
trans-1,2-Dichloroethene ND ug/kg 3.9 11/16/09 16:10 156-60-5
1,2-Dichloropropane ND ug/kg 3.9 11/16/09 16:10 78-87-5
1,3-Dichloropropane ND u9/k9 3.9 11/16/09 16:10 142-28-9
2,2-Dichloropropane ND ug/kg 3.9 11/16/09 16:10 594-20-7
1, 1-Dichloropropene ND ug/kg 3.9 11/16/09 16:10 563-58-6
cis-1,3-Dichloropropene ND ug/kg 3.9 11/16/09 16:10 10061-01-5
trans-1,3-Dichloropropene ND ug/kg 3.9 11/16/09 16:10 10061-02-6
Diisopropyl ether ND ug/kg 3.9 11/16/09 16:10 108-20-3
Ethyl benzene ND ug/kg 3.9 11/16/09 16:10 100-41-4
Hexachloro-1,3-butadiene ND ug/kg 3.9 11/16/09 16:10 87-68-3
2-Hexanone ND ug/kg 39.4 11/16/09 16:10 591-78-6
lsopropylbenzene (Cumene) ND ug/kg 3.9 11/16/09 16:10 98-82-8
p-lsopropyltoluene ND ug/kg 3.9 11/16/09 16:10 99-87-6
Methylene Chloride ND ug/kg 15.7 11/16/09 16:10 75-09-2
4-Methyl-2-pentanone (M1BK) ND ug/kg 39.4 11/16/09 16:10 108-10-1
Methyl-tert-butyl ether ND ug/kg 3.9 11/16/09 16:10 1634-04-4
Naphthalene ND ug/kg 3.9 11/16/09 16:10 91-20-3
n-Propy!benzene ND ug/kg 3.9 11/16/09 16:10 103-65-1
Styrene ND u9/k9 3.9 11/16/09 16:10 100-42-5
1, 1, 1,2-Tetrachloroethane ND u9/k9 3.9 11/16/09 16:10 630-20-6
1, 1,2,2-Tetrachloroethane ND ug/kg 3.9 11/16/09 16:10 79-34-5
Date: 12/04/2009 11: 18 AM REPORT OF LABORATORY ANALYSIS Page 43 of 81
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc .. «"'~, inelac;;
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project CASTLE HAYNE 22-12493D
Pace Project No.: 9257362
Sample: HA-10 LablD: 9257362010 Collected: 11/11/09 10:45 Received: 11/12/09 09:10 Matrix: Solid
Results reported on a "dry-weight" basis
Parameters
826015035A Volatile Organics
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1, 1, 1-Trichtoroethane
1, 1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
. Vinyl acetate
Vinyl chloride
Xylene (Total)
m&p-Xylene
a-Xylene
Dibromofluoromethane (S)
Toluene-dB ($)
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Percent Moisture
Percent Moisture
Date: 12/04/2009 11 : 18 AM
Results Units Report Limit DF Prepared
Analytical Method: EPA 8260
ND ug/kg 3.9
ND ug/kg 3.9
ND ug/kg 3.9
ND ug/kg 3.9
ND ug/kg 3.9
ND ug/kg 3.9
ND ug/kg 3.9
ND ug/kg 3.9
ND ug/kg 3.9
ND ug/kg 3.9
ND ug/kg 3.9
ND ug/kg 39.4
ND ug/kg 7.9
ND ug/kg 7.9
ND ug/kg 7.9
ND ug/kg 3.9
102 % 79-116
101 % 88-110
98 % 74-115
103 % 69-121
Analytical Method: ASTM D2974-87
16.2 % 0.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
~q-Pf~;s~ .. ~
11ne1c10;
Analyzed CAS No. Qual
11/16/09 16:10 127-18-4
11/16/09 16:10 108-88-3
11/16/09 16:10 87-61-6
11/16/09 16:10 120-82-1
11/16/09 16:10 71-55-6
11/16/09 16:10 79-00-5
11/16/09 16:10 79-01-6
11/16/0916:10 75-69-4
11/16/09 16:10 96-18-4
11/16/09 16:10 95-63-6
11/16/09 16:10 108-67-8
11/16/09 16:10 108-05-4
11/16/0916:10 75-01-4
11/16/09 16:10 1330-20-7
11/16/09 16:10 1330-20-7
11/16/09 16:10 95-47-6
11/16/09 16:10 1868-53-7
11/16/0916:10 2037-26-5
11/16/09 16:10 460-00-4
11/16/09 16:10 17060-07-0
11/17/09 08:57
Page 44 of 81
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704 )875-9092
Project: CASTLE HAYNE 22-12493D
Pace Project No.: 9257362
Sample: HA-11 Lab ID: 9257362011 Collected: 11/11/09 12:30 Received: 11/12/09 09:10 Matrix: Solid
Results reported on a "dry-weight" basis
Parameters
6010 MET ICP
Aluminum
Antimony
Arsenic
Beryllium
Chromium
Copper
Iron
Lead
Nickel
Thallium
Zinc
8270 MSSV Full List Microwave
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g, h, i )perylene
Benzo(k)fluoranthene
4-Bromophenylphenyl ether
Butylbenzylphthalate
4-Chloro-3-methylphenol
4-Chloroaniline
bis(2-Chloroethoxy)methane
bis(2-Chloroethyl) ether
bis(2-Chloroisopropyl) ether
2-Chloronaphthalene
2-Chlorophenol
4-Chlorophenylphenyl ether
Chrysene
Dibenz(a, h)anthracene
Dlbenzofuran
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
3,3'-Dichlorobenzidine
2,4-Dichlorophenol
Diethylphthalate
2,4-Dimethylphenol
Dimethylphthalate
Di-n-butylphthalate
4,6-Dinitro-2-methylphenol
2,4-Dinitrophenol
2,4-0lnitrotoluene
Date: 12/04/2009 11:18AM
Results Units Report Limit OF Prepared
Analytical Method: EPA 6010 Preparation Method: EPA 3050
1150 mg/kg 9.7 11/18/09 15:10
ND mglkg 0.48 11/18/0915:10
4.5 mg/kg 0.48 11/18/09 15:10
0.20 mg/kg 0.097 11/18/09 15:10
3.1 mg/kg 0.48 11/18/09 15:10
ND mg/kg 0.48 11/18/09 15:10
5130 mg/kg 4.8 11/18/09 15:10
2.5 mg/kg 0.48 11/18/09 15:10
2.3 mg/kg 0.48 11/18/09 15:10
ND mg/kg 0.97 11/18/09 15:10
6.9 mg/kg 0.97 11/18/09 15:10
Analytical Method: EPA8270
ND ug/kg 40.1 11/18109 14:09
ND ug/kg 40.1 11/18/09 14:09
ND ug/kg 40.1 11/18/09 14:09
ND ug/kg 40.1 11/18/09 14:09
ND ugll<g 40.1 11/18/0914:09
ND ug/kg 40.1 11/18/09 14:09
ND ug/kg 40.1 11/18/09 14:09
ND ug/kg 40.1 11/18/09 14:09
ND ug/kg 207 11/18/09 14:09
ND ug/kg 207 11/18/0914:09
ND ug/kg 815 11/18/09 14:09
ND ug/kg 207 11/18/09 14:09
ND ug/kg 207 11/18/09 14:09
ND ug/kg 207 11/18/09 14:09
NO ug/kg 207 11/18/09 14:09
NO ug/kg 207 11/18/09 14:09
ND ug/kg 207 11/18109 14:09
ND ug/kg 207 11/18/09 14:09
ND ug/kg 40.1 11/18/09 14:09
ND ug/kg 40.1 11/18/09 14:09
ND ug/kg 207 11/18/09 14:09
ND ug/kg 207 11/18/09 14:09
ND ug/kg · 207 11/1810914:09
ND ug/kg 207 11/18109 14:09
ND ug/kg 815 11/18/09 14:09
ND ug/kg 207 11/18/09 14:09
ND ug/kg 207 11/18/09 14:09
ND ug/kg 207 11/18/09 14:09
ND ug/kg 207 11/18109 14:09
ND ug/kg 207 11/18/09 14:09
ND ug/kg 815 11/18/09 14:09
NO ug/kg 815 11/18/09 14:09
NO ug/kg 207 11/18/09 14:09
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
~Q«·K~~~ 11nelact,
Analyzed GAS No.
11/19/09 16:14 7429-90-5
11/19/0916:14 7440-36-0
11/19/09 16:14 7440-38-2
11/19/09 16:14 7440-41-7
11/19/09 16:14 7440-47-3
11/19/09 16:14 7440-50-8
11/19/09 16:14 7439-89-6
11/19/09 16:14 7439-92-1
11/19/09 16:14 7440-02-0
11/19/09 16:14 7440-28-0
11/19/09 16:14 7440-66-6
11/25109 22:08 83-32-9
11/25/09 22:08 208-96-8
11/25/09 22:08 120-12-7
11/25/09 22:08 56-55-3
11/25/09 22:08 50-32-8
11/25/09 22:08 205-99-2
11 /25/09 22:08 191-24-2
11/25/09 22:08 207-08-9
11/25/09 22:08 101-55-3
11/25/09 22:08 85-68-7
11/25/09 22:08 59-50-7
11/25/09 22:08 106-47-8
11/25/09 22:08 111-91-1
11/25/09 22:08 111-44-4
11/25/09 22:08 108-60-1
11/25109 22:08 91-58-7
11/25109 22:08 95-57-8
11/25/09 22:08 7005-72-3
11 /25/09 22:08 218-01-9
11 /25/09 22:08 53-70-3
11/25/09 22:08 132-64-9
11/25/09 22:08 95-50-1
11/25109 22:08 541-73-1
11/25109 22:08 106-46-7
11 /25/09 22:08 91-94-1
11/25/09 22:08 120-83-2
11/25/09 22:08 84-66-2
11/25/09 22:08 105-67-9
11/25/09 22:08 131-11-3
11/25/09 22:08 84-74-2
11/25/09 22:08 534-52-1
11/25/09 22:08 51-28-5
11/25/09 22:08 121-14-2
Qual
PB
L3
L3
L3
L3
Page 45 of 81
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704 )875-9092
Project: CASTLE HAYNE 22-12493D
Pace Project No.: 9257362
Sample: HA-11 LablD: 9257362011 Collected: 11/11/09 12:30 Received: 11/12/09 09:10 Matrix: Solid
Results ~ported on a "dry-weight"' basis
Parameters
8270 MSSV Full List Microwave
2,6-Dinitrotoluene
Di-n-octy1phtha1ate
1,2-Diphenylhydrazine
bis(2-Ethylhexyl)phthatate
Fluoranthene
F1uorene
Hexachloro-1,3-butadiene
Hexachlorobenzene
Hexachlorocyclopentadiene
Hexachloroethane
tndeno(1,2,3-cd)pyrene
lsophorone
1-Methylnaphthatene
2-Methylnaphthalene
2-Methylphenol(o-Cresol)
3&4-Methylphenol(m&p Cresci)
Naphthalene
2-Nitroanitine
3-Nitroaniline
4-Nitroaniline
Nitrobenzene
2-Nitrophenol
4-Nitrophenol
N-Nitrosodimethylamine
N-Nitroso-di-n-propylamine
N-Nitrosodiphenylamine
Pentachlorophenol
Phenanthrene
Phenol
Pyrene
1,2,4-Trichlorobenzene
2,4,5-Trichlorophenol
2,4,6-Trichlorophenol
Nitrobenzene-d5 (S)
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
Phenol-dB (S)
2-Fluorophenol (S)
2,4,6-Tribromophenol (S)
826D/5035A Volatile Organics
Acetone
Benzene
Bromobenzene
Bromochloromethane
Bromodich/oromethane
Date: 12/04/200911:18AM
Results Units Report Limit DF Prepared
Analytical Method: EPA 6270
ND ug/kg 207 11/16/09 14:09
ND ug/kg 207 11/16/09 14:09
ND ug/kg 207 11/16/09 14:09
ND ug/kg 207 11/18/0914:09
ND ug/kg 40.1 11/16/09 14:09
ND ug/kg 40.1 11/18/09 14:09
ND ug/kg 207 11/18/09 14:09
ND ug/kg 207 11/16/09 14:09
ND ug/kg 615 11/16/09 14:09
ND ug/kg 207 11/16/09 14:09
ND ug/kg 40.1 11/16/09° 14:09
ND ug/kg 207 11/16/09 14:09
ND ug/kg 40.1 11/16/09 14:09
NO ug/kg 40.1 11/16/09 14:09
ND ug/kg 207 11/16/09 14:09
ND ug/kg 207 11/16/09 14:09
ND ug/kg 40.1 11/16/09 14:09
NO ug/kg 207 11/16/09 14:09
ND ug/kg 207 11/16/09 14:09
ND ug/kg 207 11/16/0914:09
NO ug/kg 207 11/18/09 14:09
ND ug/kg 207 11/16/0914:09
NO ug/kg 207 11/16/09 14:09
NO ug/kg 207 11/18/09 14:09
NO ug/kg 207 11/18/09 14:09
ND ug/kg 207 11/16/09 14:09
ND ug/kg 615 11/16/09 14:09
ND ug/kg 40.1 11/18/09 14:09
NO ug/kg 207 11/18/09 14:09
ND ug/kg 40.1 11/16/09 14:09
ND ug/kg 207 11/16/09 14:09
ND ug/kg 207 11/16/09 14:09
ND ug/kg 207 11/18/0914:09
74 % 10-110 11/16/09 14:09
75 % 16-110 11/18/09 14:09
77 % 10-123 11/16/09 14:09
70 % 10-110 11/16/091409
74 % 18-110 11/18/09 14:09
81 % 10-110 11/18/09 14:09
Analytical Method: EPA6260
ND ug/kg 96.3
ND ug/kg 4.6
ND ug/kg 4.6
ND ug/kg 4.6
ND ug/kg 4.6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
_pf-'-'~, lnelac;-,
Analyzed CAS No. Quat
11 /25/09 22:06 606-20-2
11/25/09 22:06 117-64-0
11/25/09 22:06 122-66-7
11/25/09 22:06 117-81-7
11/25/09 22:06 206-44-0
11 /25/09 22:06 66-73-7
11125/09 22:08 67-66-3
11/25/09 22:06 118-74-1
11/25/09 22:06 77-47-4
11/25/09 22:06 67-72-1
11/25/09 22:06 193-39-5
11 /25/09 22:06 76-59-1
11 /25/09 22:06 90-12-0
11/25/09 22:06 91-57-6
11/25/09 22:08 95-48-7
11/25/09 22:06 L3
11/25/09 22:06 91-20-3
11 /25/09 22:06 88-74-4
11/25/09 22:06 99-09-2
11/25/09 22:06 100-01-6 L3
11/25/09 22:08 96-95-3
11/25/09 22:06 66-75-5
11/25/09 22:06 100-02-7
11125/09 22:08 62-75-9
11125/09 22:08 621-64-7
11 /25/09 22:06 66-30-6
11/25/09 22:08 67-66-5
11/25/09 22:08 65-01-6
11/25/09 22:06 106-95-2
11/25/09 22:06 129-00-0
11125/09 22:06 120-62-1
11 /25/09 22:06 95-95-4
11/25/09 22:08 66-06-2
11/25/09 22:06 4165-60-0
11 /25/09 22:08 321-60-6
11/25/09 22:06 1716-51-0
11/25/09 22:08 13127-66-3
11/25/09 22:06 367-12-4
11/25/09 22:08 118-79-6
11/15/09 14:30 67.-64-1
11/15/09 14:30 71-43-2
11/15/09 14:30 106-66-1
11/15/09 14:30 74-97-5
11/15/09 14:30 75-27-4
Page 46 of 81
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: CASTLE HAYNE 22-124930
Pace Project No.: 9257362
Sample: HA-11 LablD: 9257362011 Collected; 11/11/09 12:30 Received: 11/12/09 09:10 Matrix: Solid
Results reported on a ndry-weight" basis
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260/5035A Volatile Organics Analytical Method: EPA 8260
Bromoform ND ugll<g 4.8 11115109 14:30 75-25-2
Bromomethane ND ug/kg 9.6 11/15/09 14:30 74-83-9
2-Butanone (MEK) ND ug/kg 96.3 11115109 14:30 78-93-3
n-Butylbenzene ND ug/kg 4.8 11115109 14:30 104-51-8
sec-Butylbenzene ND ug/kg 4.8 1111510914:30 135-98-8
tert-Butylbenzene ND ug/kg 4.8 11/15/0914:30 98-06-6
Carbon tetrachloride ND ug/kg 4.8 11115/09 14:30 56-23-5
Chlorobenzene ND ug/kg 4.8 11/15/09 14:30 108-90-7
Chloroethane ND ug/kg 9.6 11115109 14:30 75-00-3
Chloroform ND ug/kg 4.8 11115109 14:30 67-66-3
Chloromethane ND ug/kg 9.6 11115/0914:30 74-87-3
2-Chlorotoluene ND ug/kg 4.8 11/15/09 14:30 95-49-8
4-Chlorotoluene ND ugll<g 4.8 11115109 14:30 106-43-4
1,2-Dibromo-3-chloropropane ND ug/kg 4.8 11115109 14:30 96-12-8
Dibromochloromethane ND ug/kg 4.8 11/15/09 14:30 124-48-1
1,2-Dibromoethane (EDB) ND ug/kg 4.8 11/15/09 14:30 106-93-4
Dibromomethane ND ug/kg 4.8 11115/0914:30 74-95-3
1,2-Dichlorobenzene ND ug/kg 4.8 11/15/09 14:30 95-50-1
1,3-Dichlorobenzene ND ug/kg 4.8 11/15109 14:30 541-73-1
1,4-Dichlorobenzene ND ug/kg 4.8 11/15/09 14:30 106-46-7
Dichlorodifluoromethane ND ug/kg 9.6 11/15/09 14:30 75-71-8
1, 1-Dichloroethane ND ug/kg 4.8 11/15/09 14:30 75-34-3
1,2-Dichloroethane ND ug/kg 4.8 11/15/0914:30 107-06-2
1, 1-Dichloroethene ND ug/l<g 4.8 11/15/09 14:30 75-35-4
cis-1,2-Dichloroethene ND ug/kg 4.8 11/15/09 14:30 156-59-2
trans-1,2-Dichloroethene ND ug/kg 4.8 11/15/09 14:30 156-60-5
1,2-Dichloropropane ND ug/kg 4.8 11/15/09 14:30 78-87-5
1,3-Dichloropropane ND ug/kg 4.8 11/1510914:30 142-28-9
2,2-Dichloropropane ND ug/l<g 4.8 11/15/09 14:30 594-20-7
1, 1-Dichloropropene ND ug/kg 4.8 11/15/09 14:30 563-58-6
cis-1,3-Dichloropropene ND ug/kg 4.8 11/15/09 14:30 10061-01-5
trans-1.3-Dichloropropene ND ug/kg 4.8 11/15/0914:30 10061-02-6
Diisopropyl ether ND ug/kg 4.8 11/15/09 14:30 108-20-3
Ethyl benzene ND ug/kg 4.8 11/15/09 14:30 100-41-4
Hexachloro-1,3-butadiene ND ug/kg 4.8 11/15/09 14:30 87-68-3
2-Hexanone ND ug/kg 48.1 11/15/09 14:30 591-78-6
lsopropylbenzene (Cumene) ND ug/kg 4.8 11/15/09 14:30 98-82-8
p-lsopropyltoluene ND ug/kg 4.8 11/15/09 14:30 99-87-6
Methylene Chloride ND ug/kg 19.3 11/15/09 14:30 75-09-2
4-Methyl-2-pentanone (MlBK) ND ug/kg 48.1 11/15/09 14:30 108-10-1
Methyl-tert-butyl ether ND ug/kg 4.8 11/15/09 14:30 1634-04-4
Naphthalene ND ugll<g 4.8 11/15/09 14:30 91-20-3
n-Propylbenzene ND ug/kg 4.8 11/15/09 14:30 103-65-1
Styrene ND ug/kg 4.8 11/15/09 14:30 100-42-5
1, 1, 1,2-Tetrachloroethane ND ug/kg 4.8 11/15/09 14:30 630-20-6
1, 1,2,2-Tetrachloroethane ND ug/kg 4.8 11/15/09 14:30 79-34-5
Date: 12/04/2009 11 :18 AM REPORT OF LABORATORY ANALYSIS Page 47 of 81
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
~~?f-'·~~~~ 11nelae:;
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
{828)254-7176
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704 )875-9092
Project: CASTLE HAYNE 22-12493D
Pace Project No.: 9257362
Sample: HA-11 LablD: 9257362011 Collected: 11/11/09 12:30 Received: 11/12/09 09:10 Matrix: Solid
Results reported on a "dry-weight" basis
Parameters
8260/5035A Volatile Organics
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-T richlorobenzene
1, 1, 1-Trichloroethane
1, 1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl acetate
Vinyl chloride
Xylene {Total)
m&p-Xylene
a-Xylene
Dibromofluoromethane (S)
Toluene-d8 {S)
4-Bromofluorobenzene {S)
1,2-Dichloroethane-d4 {S)
Percent Moisture
Percent Moisture
Date: 12/04/2009 11: 18 AM
Results Units Report Limit DF Prepared
Analytical Method: EPA 8260
ND ug/kg 4.8
ND ug/kg 4.8
ND ug/kg 4.8
ND u9/k9 4.8
ND ug/kg 4.8
ND ug/k9 4.8
ND ug/kg 4.8
ND ug/kg 4.8
ND ug/kg 4.8
ND ug/kg 4.8
ND ug/kg 4.8
ND ug/kg 48.1
ND ug/kg 9.6
ND ug/kg 9.6
ND ug/kg 9.6
ND ug/kg 4.8
106 % 79-116
93 % 88-110
75 % 74-115
98 % 69-121
Analytical Method: ASTM D2974-87
19.1 % 0.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, lnc ..
Analyzed CAS No. Qual
11/15/09 14:30 127-18-4
11/15/09 14:30 108-88-3
11/15/09 14:30 87-61-6
11/15/09 14:30 120-82-1
11/15/09 14:30 71-55-6
11/15/09 14:30 79-00-5
11/15/09 14:30 79-01-6
11/15/09 14:30 75-69-4
11/15/09 14:30 96-18-4
11/15/09 14:30 95-63-6
11/15/0914:30 108-67-8
11/15/09 14:30 108-05-4
11/15/09 14:30 75-01-4
11/15/09 14:30 1330-20-7
11/15/09 14:30 1330-20-7
11/15/09 14:30 95-47-6
11/15/09 14:30 1868-53-7
11/15/09 14:30 2037-26-5
11/15/09 14:30 460-00-4
11/15/0914:30 17060-07-0
11/17/09 08:57
Page 48 of 81
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Paco Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
{704 )875-9092
Project: CASTLE HAYNE 22-12493D
Pace Project No.: 9257362
Sample: HA-12 LablD: 9257362012 Collected: 11/11/0914:00 Received: 11/12/09 09:10 Matrix: Solid
Results reported on a "dry-weight'" basis
Parameters
6010 MET ICP
Aluminum
Antimony
Arsenic
Beryllium
Chromium
Copper
Iron
Lead
Nickel
Thallium
Zinc
8270 MSSV Full List Microwave
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b )fluoranthene
Benzo(g, h,i)perylene
Benzo(k)fluoranthene
4-Bromophenylphenyl ether
Butylbenzylphthalate
4-Chloro-3-methylphenol
4-Chloroaniline
bis(2-Chloroethoxy)methane
bis(2-Chloroethyl) ether
bis(2-Chloroisopropyl) ether
2-Chloronaphthalene
2-Chlorophenol
4-Chlorophenylphenyl ether
Chrysene
D ibe nz( a, h )a nth racene
Dibenzofuran
1,2-Dichlorobenzene
1,3-0ichlorobenzene
1,4-Dichlorobenzene
3,3'-Dichlorobenzidine
2,4-Dichlorophenol
Oiethylphthalate
2,4-Dimethylphenol
Dimethylphthalate
Di-n-butylphthalate
4,6-Dinitro-2-methylphenol
2,4-Dinitrophenol
2,4-Dinitrotoluene
Date: 12/04/2009 11:18AM
Results Units Report Limit OF Prepared
Analytical Method: EPA6010 Preparation Method: EPA3050
1400 mg/kg
ND mg/kg
0.53 mg/kg
ND mg/kg
1.6 mg/kg
ND mglkg
643 mg/kg
2.6 mg/kg
0.55 mg/kg
ND mg/kg
2.0 mg/kg
Analytical Method: EPA 8270
ND ug/kg
ND ug/kg
ND uglkg
ND ug/kg
ND ug/kg
ND uglkg
ND ug/kg
ND uglkg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
NO ug/kg
ND ug/kg
NO ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
8.3
0.42
0.42
0.083
0.42
0.42
4.2
0.42
0.42
0.83
0.83
398
398
398
398
398
398
398
398
2050
2050
8090
2050
2050
2050
2050
2050
2050
2050
398
398
2050
2050
2050
2050
8090
2050
2050
2050
2050
2050
8090
8090
2050
11/18/09 15:10
11/18/09 15:10
11/18/09 15:10
11/18/09 15:10
11/18/09 15:10
11/18/0915:10
11/18/09 15:10
11/18/09 15:10
11/18/09 15:10
11/18/09 15:10
11/18/09 15:10
10 11/18/09 14:09
10 11/18/09 14:09
10 11/18/09 14:09
10 11/18/0914:09
10 11/18/09 14:09
10 11/18/09 14:09
10 11/18/09 14:09
10 11/18/09 14:09
10 11/18/09 14:09
10 11/18/0914:09
10 11/18/09 14:09
10 11/18/09 14:09
10 11/18/09 14:09
10 11/18/09 14:09
10 11/18/09 14:09
10 11/18/09 14:09
10 11/18/09 14:09
10 11/18/09 14:09
10 11/18/09 14:09
10 11/18/09 14:09
10 11/18/09 14:09
10 11/18/09 14:09
10 11/18/09 14:09
10 11/18/09 14:09
10 11/18/09 14:09
10 11/18/09 14:09
10 11/18/09 14:09
10 11/18/09 14:09
10 11/18/09 14:09
10 11/18/09 14:09
10 11/18/09 14:09
10 11/18/09 14:09
10 11/18/09 14:09
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without tile written consent of Pace Analytical Services, Inc.,
.:-Yr'·~~~~ r1nelae:,
Analyzed CAS No.
11/19/0916:18 7429-90-5
11/19/09 16:18 7440-36-0
11/19/09 16:18 7440-38-2
11/19/09 16:18 7440-41-7
11/19/09 16:18 7440--47-3
11/19/09 16:18 7440-50-8
11/19/09 16:18 7439-89-6
11/19/09 16:18 7439-92-1
11/19/09 16:18 7440-02-0
11/19/09 16:18 7440-28-0
11/19/09 16:18 7440-66-6
11/25/09 22:38 83-32-9
11/25/09 22:38 208-96-8
11/25/09 22:38 120-12-7
11/25/09 22:38 56-55-3
11/25/09 22:38 50-32-8
11125/09 22:38 205-99-2
11/25/09 22:38 191-24-2
11/25/09 22:38 207-08-9
11/25/09 22:38 101-55-3
11/25/09 22:38 85-68-7
11/25/09 22:38 59-50-7
11 /25/09 22:38 106-47-8
11/25/09 22:38 111-91-1
11/25/09 22:38 111-44--4
11 /25/09 22:38 108-60-1
11 /25/09 22:38 91-58-7
11/25/09 22:38 95-57-8
11/25/09 22:38 7005-72-3
11/25/09 22:38 218-01-9
11/25/09 22:38 53-70-3
11/25/09 22:38 132-64-9
11/25/09 22:38 95-50-1
11/25/09 22:38 541-73-1
11/25/09 22:38 106-46-7
11/25/09 22:38 91-94-1
11 /25/09 22:38 120-83-2
11/25/09 22:38 84-66-2
11/25/09 22:38 105-67-9
11/25/09 22:38 131-11-3
11/25/09 22:38 84-74-2
11/25/09 22:38 534-52-1
11/25/09 22:38 51-28-5
11/25/09 22:38 121-14-2
Qual
PB
L3
L3
L3
L3
Page 49 of 81
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704 )875-9092
Project: CASTLE HAYNE 22-12493D
Pace Project No.: 9257362
Sample: HA-12 LablD: 9257362012 Collected: 11/11/09 14:00 Received: 11/12/09 09:10 Matrix: Solid
Results reported on a "dry-weight" basis
Parameters
8270 MSSV Full List Microwave
2,6-Dinitrotoluene
Di-n-octylphthalate
1,2-Diphenylhydrazine
bis{2-Ethylhexyl)phthalate
Fluoranthene
Fluorene
Hexachloro-1,3-butadiene
Hexachlorobenzene
Hexachlorocyclopentadiene
Hexachloroethane
lndeno(1,2,3-cd)pyrene
1sophorone
1-Methylnaphthalene
2-Methytnaphthalene
2-Methylphenol(o-Cresol)
3&4-Methylphenol{m&p Cresol)
Naphthalene
2-Nitroaniline
3-Nitroaniline
4-Nitroaniline
Nitrobenzene
2-Nitrophenol
4-Nitrophenol
N-Nitrosodimethylamine
N-Nitroso-di-n-propylamine
N-Nitrosodiphenylamine
Pentachlorophenol
Phenanthrene
Phenol
Pyrene
1,2,4-Trichlorobenzene
2,4,5-Trichlorophenol
2 ,4, 6-T richlorophe nol
Nitrobenzene-d5 (S)
2-Fluorobiphenyt ($)
Terphenyl-d14 (S)
Phenol-dB (S)
2-Fluorophenol (S)
2,4,6-Tribromophenol (S)
826015035A Volatile Organics
Acetone
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Date: 12/04/2009 11: 18 AM
Results Units
Analytical Method: EPA8270
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/k.g
ND ug/k.g
ND ug/k.g
ND u9/1<9
ND ug/kg
ND ug/kg
ND ug/k.g
ND u9/k9
ND ug/kg
ND ug/kg
ND ug/kg
ND ug/k.g
ND ug/kg
ND ug/kg
ND ug/k.g
ND ug/kg
ND ug/kg
ND u9/k9
ND ug/kg
ND ug/kg
ND ug/kg
ND u9/1<9
ND ug/kg
ND u9/1<9
ND ug/kg
NO ug/kg
ND ug/kg
61 %
70 %
78 %
59 %
67 %
65 %
Analytical Method: EPA 8260
ND ug/kg
ND ug/kg
NO ug/kg
ND ug/kg
ND ug/kg
Report Limit
2050
2050
2050
2050
398
398
2050
2050
8090
2050
398
2050
398
398
2050
2050
398
2050
2050
2050
2050
2050
2050
2050
2050
2050
8090
398
2050
398
2050
2050
2050
10-110
18-110
10-123
10-110
18-110
10-110
93.3
4.7
4.7
4.7
4,7
OF Prepared
10 11118109 14:09
10 1111810914:09
10 11118109 14:09
10 11118109 14:09
10 11/18/09 14:09
10 11/18109 14:09
10 11/18/0914:09
10 11/18109 14:09
10 11118/09 14:09
10 11/18/09 14:09
10 11/18/09 14:09
10 11118/09 14:09
10 1111810914:09
10 11118/09 14:09
10 11/18/09 14:09
10 11/18/09 14:09
10 11/18/0914:09
10 11118109 14:09
10 11/18/09 14:09
10 11/18/09 14:09
10 11/18/09 14:09
10 11/18/09 14:09
10 11/18/0914:09
10 11/18/09 14:09
10 11118/09 14:09
10 11118/09 14:09
10 11/18/09 14:09
10 11/18/09 14:09
10 11/18/0914:09
10 11118/0914:09
10 11/18/09 14:09
10 11118/09 14:09
10 11/18/09 14:09
10 11/18109 14:09
10 11/18109 14:09
10 11118/09 14:09
10 11/18/09 14:09
10 11/18/09 14:09
10 11/18/09 14:09
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
,,,;sf"~~"-IcneldC\"a
Analyzed CAS No. Oual
11/25109 22:38 606-20-2
11125109 22:38 117-84-0
11/25109 22:38 122-66-7
11125109 22:38 117-81-7
11/25/09 22:38 206-44-0
11/25109 22:38 86-73-7
11/25/09 22:38 87-68-3
11 /25/09 22:38 118-74-1
11/25/09 22:38 77-47-4
11/25/09 22:38 67-72-1
11/25/09 22:38 193-39-5
11/25/09 22:38 78-59-1
11 /25/09 22:38 90-12-0
11/25/09 22:38 91-57-6
11/25/09 22:38 95-48-7
11/25/09 22:38 L3
11/25109 22:38 91-20-3
11125/09 22:38 88-74-4
11/25/09 22:38 99-09-2
11/25/09 22:38 100-01-6 L3
11/25/09 22:38 98-95-3
11/25/09 22:38 88-75-5
11125/09 22:38 100-02-7
11/25/09 22:38 62-75-9
11125/09 22:38 621-64-7
11/25/09 22:38 86-30-6
11/25/09 22:38 87-86-5
11/25/09 22:38 85-01-8
11/25/09 22:38 108-95-2 IS
11/25109 22:38 129-00-0
11/25/09 22:38 120-82-1
11/25/09 22:38 95-95-4
11/25/09 22:38 88-06-2
11/25/09 22:38 4165-60-0
11125/09 22:38 321-60-8
11/25/09 22:38 1718-51-0
11/25/09 22:38 13127-88-3
11/25/09 22:38 367-12-4
11/25/09 22:38 118-79-6
11/15/09 14:48 67-64-1
11/15/0914:48 71-43-2
11/15/09 14:48 108-86-1
11/15/09 14:48 74-97-5
11/15/09 14:48 75-27-4
Page 50 of 81
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
(828)254•7176
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: CASTLE HAYNE 22-12493D
Pace Project No.: 9257362
Sample: HA-12 LablD: 9257362012 Collected: 11/11/09 14:00 Received: 11/12/09 09:10 Matrix: Solid
Results reported on a "d,y-weight" basis
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260/5035A Volatile Organics Analytical Method: EPA8260
Bromoform ND ug/kg 4,7 11/15/09 14:48 75-25-2
Bromomethane ND ug/kg 9.3 11/15/0914:48 74-83-9
2-Butanone (MEK) ND ug/kg 93.3 11/15/09 14:48 78-93-3
n·Butylbenzene ND ug/kg 4.7 11/15/09 14:48 104-51-8
sec-Butylbenzene ND ug/kg 4.7 11/15/09 14:48 135-98-8
tert-Butylbenzene ND ug/l<g 4,7 11/15/0914:48 98-06-6
Carbon tetrachloride ND ug/kg 4.7 11/15/09 14:48 56-23-5
Chlorobenzene ND ug/kg 4,7 11/15/09 14:48 108-90-7
Chloroethane ND ug/kg 9.3 11/15/09 14:48 75-00-3
Chloroform ND ug/kg 4.7 11/15/09 14:48 67-66-3
Chloromethane ND ug/kg 9.3 11/15/09 14:48 74-87-3
2-Chlorotoluene ND ug/kg 4.7 11/15/0914:48 95-49-8
4-Chlorotoluene ND ug/l<g 4,7 11/15/09 14:48 106-43-4
1,2•Dibromo--3-chloropropane ND ug/kg 4.7 11/15/09 14:48 96-12-8
Dibromochloromethane ND ug/l<g 4,7 11/15/09 14:48 124-48-1
1,2-Dibromoethane (EDS) ND ug/kg 4.7 11/15/09 14:48 108-93-4
Oibromomethane ND ug/l<g 4,7 11/15/0914:48 74-95-3
1,2-Dichlorobenzene ND ug/kg 4.7 11/15/0914:48 95-50-1
1,3·Dichlorobenzene ND ug/kg 4.7 11/15/09 14:48 541-73-1
1,4-Dichlorobenzene ND ug/kg 4.7 11/15/09 14:48 106-46-7
Dichlorodifluoromethane ND ug/kg 9.3 11/15/09 14:48 75-71-8
1, 1-Dichloroethane ND ug/kg 4.7 11/15/0914:48 75-34-3
1,2-Dichloroethane NO ug/kg 4,7 11/15/09 14:48 107-06-2
1, 1-Dichloroethene ND ug/kg 4.7 11/15/09 14:48 75-35-4
cis-1,2-0ichloroelhene ND ug/kg 4.7 11/15/09 14:48 156-59-2
trans-1,2-Dichloroethene ND ug/kg 4.7 11/15/09 14:48 158-60-5
1,2-Dichloropropane ND ug/kg 4,7 11/15/0914:48 78•87-5
1,3-Dichloropropane ND ug/kg 4.7 11/15/09 14:48 142-28-9
2,2-Dichloropropane ND ug/kg 4.7 11/15/09 14:48 594-20-7
1, 1-Dichloropropene ND ug/kg 4.7 11/15/09 14:48 563-58-6
cis-1,3-Dichloropropene ND ug/kg 4.7 11/15/09 14:48 10061-01-5
trans-1,3-Dichtoropropene ND ug/kg 4.7 11/15/09 14:48 10061-02-6
Oiisopropyl ether ND ug/kg 4.7 11/15/09 14:48 108-20-3
Ethylbenzene ND ug/kg 4.7 11/15/09 14:48 100-41-4
Hexachloro--1,3•butadiene ND ug/kg 4.7 11/15/09 14:48 87-68-3
2-Hexanone ND ug/kg 46.7 11/15/09 14:48 591-78-6
lsopropylbenzene (Cumene) ND ug/kg 4.7 11/15/09 14:48 98-82-8
p•lsopropyltoluene ND ug/kg 4.7 11/15/09 14:48 99-87-6
Methylene Chloride ND ug/kg 18.7 11/15/09 14:48 75-09-2
4-Methyl•2-pentanone (MIBK) ND ug/kg 46.7 11/15/09 14:48 108-10-1
Methyl-tert-butyJ ether ND ug/kg 4.7 11/15/0914:48 1634-04-4
Naphthalene ND ug/kg 4,7 11/15/0914:48 91-20-3
n-PropyJbenzene ND ug/kg 4.7 11/15/09 14:48 103-65-1
Styrene ND ug/kg 4.7 11/15/09 14:48 100-42-5
1, 1, 1,2-Tetrachloroethane ND ug/l<g 4.7 11/15/09 14:48 630-20-6
1, 1,2,2-Tetrachloroethane ND ug/kg 4,7 11/15/09 14:48 79-34-5
Date: 12/04/2009 11: 18 AM REPORT OF LABORATORY ANALYSIS Page 51 of 81
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
~~YF~~"~ r1nelac,;
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704}875-9092
Project: CASTLE HAYNE 22-124930
Pace Project No.: 9257362
Sample: HA-12 Lab!D: 9257362012 Collected: 11/11/0914:00 Received: 11/12/09 09:10 Matrix: Solid
Results reported on a "dry-weight" basis
Parameters
826D/5035A Volatile Organics
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trlchlorobenzene
1, 1, 1-Trichloroethane
1, 1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichtoropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl acetate
Vinyl chloride
Xylene (Total)
m&p-Xylene
a-Xylene
Dibromofluoromethane (S)
Toluene-d8 (S)
4-Bromofluorobenzene (S)
1,2-0ichloroethane-d4 (S)
Percent Moisture
Percent Moisture
Date: 12/04/2009 11: 18 AM
Results Units Report limit OF Prepared
Analytical Method: EPA8260
ND ug/kg 4.7
ND ug/kg 4.7
ND ug/kg 4.7
ND ug/kg 4.7
ND ug/kg 4.7
ND ug/kg 4.7
ND ug/kg 4.7
ND ug/kg 4.7
ND ug/kg 4.7
ND ug/kg 4.7
ND ug/kg 4.7
ND ug/kg 46.7
ND ug/kg 9.3
ND ·ug/kg 9.3
ND ug/kg 9.3
NO ug/kg 4.7
101 % 79-116
99 % 88-110
93 % 74-115
98 % 69-121
Analytical Method: ASTM 02974-87
17.7 % 0.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
iA'" '~--11 nelaei,
Analyzed CAS No. Qual
11/15/09 14:48 127-18-4
11/15/09 14:48 108-88-3
11/15/09 14:48 87-61-6
11/15/09 14:48 120-82-1
11/15/0914:48 71-55-6
11/15/09 14:48 79-00-5
11/15/09 14:48 79-01-6
11/15/09 14:48 75-69-4
11/15/09 14:48 96-18-4
11/15/09 14:48 95-63-6
11/15/09 14:48 108-67-8
11/15/09 14:48 108-05-4
11/15/09 14:48 75-01-4
11/15/09 14:48 1330-20-7
11/15/09 14:48 1330-20-7
11/15/09 14:48 95-47-6
11/15/0914:48 1868-53-7
11/15/09 14:48 2037-26-5
11/15/09 14:48 460-00-4
11/15/09 14:48 17060-07-0
11/17/09 08:57
Page 52 of 81
Project: CASTLE HAYNE 22-12493D
Pace Project No.: 9257362
QC Batch: MPRP/5396
QC Batch Method: EPA 3050
Pace Analytical Sorvicos, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Analysis Method:
Analysis Description:
EPA6010
6010 MET
Associated Lab Samples: 9257362007, 9257362008, 9257362009, 9257362010, 9257362011, 9257362012
METHOD BLANK: 367175 Matrix: Solid
Associated Lab Samples: 9257362007, 9257362008, 9257362009, 9257362010, 9257362011, 9257362012
Blank Reporting
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704}875-9092
Parameter Units Result Limit Analyzed Qualifiers
Aluminum
Antimony
Arsenic
Beryllium
Chromium
Copper
lron
Lead
Nickel
Thallium
Zinc
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
LABORATORY CONTROL SAMPLE: 367176
Parameter Units
Aluminum mg/kg
Antimony mg/kg
Arsenic mg/kg
Beryllium mg/kg
Chromium mg/kg
Copper mg/kg
Iron mg/kg
Lead mg/kg
Nickel mg/kg
Thallium mg/kg
Zinc mg/kg
MATRIX SPIKE SAMPLE: 367177
Parameter Units
Aluminum mg/kg
Antimony mg/kg
Arsenic mg/kg
Beryllium mg/kg
Chromium mg/kg
Copper mg/kg
Iron mg/kg
Lead mg/kg
Nickel mg/kg
Thallium mg/kg
Date: 12/04/2009 11: 18 AM
ND 10.0 11119109 14:05
ND 0.50 11119109 14:05
ND 0.50 11119109 14:05
ND 0.10 11119109 14:05
ND 0.50 11/19/09 14:05
ND 0.50 11/19/09 14:05
5.0 5.0 11119109 14:05
ND 0.50 11/19109 14:05
ND 0.50 11119109 14:05
ND 1.0 11119109 14:05
ND 1.0 11119109 14:05
Spike LCS LCS %Rec
Cone. Result %Rec Limits Qualifiers
500 476 95 80-120
50 48.1 96 80-120
50 45,7 91 80-120
50 46.0 92 80-120
50 45.8 92 80-120
50 46,0 92 80-120
500 475 95 80-120
50 45.9 92 80-120
50 46.1 92 80-120
50 43.9 88 80-120
50 46.4 93 80-120
9257166050 Spike MS MS %Rec
Result Cone. Result % Rec Limits Qualifiers
11900 541 22800 2002 75-125 MO
ND 54.1 31.6 58 75-125 MO
ND 54.1 45.8 84 75-125
0.14 54.1 48.8 90 75-125
7.2 54.1 55.3 89 75-125
3.4 54.1 55.0 95 75-125
15100 541 14600 -89 75-125 MO
16.7 54.1 63.1 86 75-125
1.1 54.1 47.9 87 75-125
ND 54,1 41.2 76 75-125
REPORT OF LABORATORY ANALYSIS Page 53 of 81
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
,.:Y~ J/J la: •e, f,□e C1,
Project: CASTLE HAYNE 22-12493D
Pace Project No.: 9257362
MATRIX SPIKE SAMPLE: 367177
Parameter Units
Zinc mg/kg
SAMPLE DUPLICATE: 367178
Parameter Units
Aluminum mg/kg
Antimony mg/kg
Arsenic mg/kg
Beryllium mg/kg
Chromium mg/kg
Copper mg/kg
Iron mg/kg
Lead mg/kg
Nickel mg/kg
Thallium mg/kg
Zinc mg/kg
Date: 12/04/2009 11:18AM
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
9257166050
Result
5.0
9257166050
Spike
Cone.
54.1
Dup
MS
Result
55.0
MS
%Rec
92
Result Result RPO Qualifiers
11900 11800
NO ND
ND .47J
0.14 0.14 3
7.2 5.6 24 R1
3.4 2.9 18
15100 13500 11
16.7 16.6 1
1.1 1.1 8
ND ND
5.0 4.7 6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
%Rec
Limits
75-125
Qualifiers
Page 54 of 81
Project: CASTLE HAYNE 22-124930
Pace Project No.: 9257362
QC Batch: MSV/9016
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Analysis Method: EPA 8260
QC Batch Method: EPA 8260 Analysis Description: 8260 MSV 5035A Volatile Organics
Associated Lab Samples: 9257362001, 9257362002, 9257362003, 9257362004, 9257362007
METHOD BLANK: 366098 Matrix: Solid
Associated Lab Samples: 9257362001,9257362002, 9257362003,9257362004, 9257362007
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
1, 1, 1,2-Tetrachloroethane ug/kg ND 5.0 11/13/09 09:38
1, 1, 1-Trichloroethane ug/kg ND 5.0 11/13/09 09:38
1, 1,2,2-Tetrachloroethane ug/kg ND 5.0 11/13/09 09:38
1, 1,2-Trichloroethane ug/kg ND 5.0 11/13/09 09:38
1.1-Dichloroethane ug/kg ND 5.0 11/13/09 09:38
1 , 1-Dichloroethene ug/kg ND 5.0 11/13/09 09:38
1, 1-Dichloropropene ug/kg ND 5.0 11/13/09 09:38
1,2, 3-Trichlorobenzene ug/kg ND 5.0 11/13/09 09:38
1,2,3-Trichloropropane ug/kg ND 5.0 11/13/09 09:38
1,2,4-Trichlorobenzene ug/kg ND 5.0 11/13/09 09:38
1,2,4-Trimethylbenzene ug/kg ND 5.0 11/13/09 09:38
1,2-Dibromo-3-chloropropane ug/kg ND 5.0 11/13/09 09:38
1,2-Dibromoethane (EDS) ug/kg ND 5.0 11/13/09 09:38
1,2-Oichlorobenzene ug/kg ND 5.0 11/13/09 09:38
1,2-Dichloroethane ug/kg ND 5.0 11/13/09 09:38
1,2-Dichloropropane ug/kg ND 5.0 11/13/09 09:38
1,3,5-Trimethylbenzene ug/kg ND 5.0 11/13/09 09:38
1,3-Dichlorobenzene u9/kg ND 5.0 11/13/09 09:38
1,3-Dichloropropane ug/kg ND 5.0 11/13/09 09:38
1,4-Oichlorobenzene ug/kg ND 5.0 11/13/09 09:38
2,2-Dichloropropane ug/kg ND 5.0 11/13/09 09:38
2-Butanone (MEK) ug/kg ND 100 11/13/09 09:38
2-Chlorotoluene ug/kg ND 5.0 11/13/09 09:38
2-Hexanone ug/kg ND 50.0 11/13/09 09:38
4-Chlorotoluene ug/kg ND 5.0 11/13/09 09:38
4-MethyJ-2-pentanone (MIBK) ug/kg ND 50.0 11/13/09 09:38
Acetone ug/kg ND 100 11/13/09 09:38
Benzene ug/kg ND 5.0 11/13/09 09:38
Bromobenzene ug/kg ND 5.0 11/13/09 09:38
Bromochloromethane ug/kg ND 5.0 11/13/09 09:38
Bromodichloromethane ug/kg ND 5.0 11/13/09 09:38
Bromoform ug/kg ND 5.0 11/13/09 09:38
Bromomethane ug/kg ND 10.0 11/13/09 09:38
Carbon tetrachloride ug/kg ND 5.0 11/13/09 09:38
Chlorobenzene ug/kg ND 5.0 11/13/09 09:38
Chloroethane ug/kg ND 10.0 11/13/09 09:38
Chloroform ug/kg ND 5.0 11/13/09 09:38
Chloromethane ug/kg ND 10.0 11 /13/09 09:38
cis-1,2-Dlchloroethene ug/kg ND 5.0 11/13/09 09:38
cis-1,3-Dichloropropene ug/kg ND 5.0 11/13/09 09:38
Dibromochloromethane ug/kg ND 5.0 11/13/09 09:38
Dibromomethane ug/kg ND 5.0 11/13/09 09:38
Dichlorodifluoromethane ug/kg ND 10.0 11/13/09 09:38
Date: 12/04/2009 11:18AM REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
?~-~·+ ,•' l la V, ,,ne o• . . . -,.
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704 }875-9092
Page 55 of 81
Project CASTLE HAYNE 22-124930
Pace Project No.: 9257362
Pace Analytical Services, Inc.
2225 Riverside Dr.
QUALITY CONTROL DATA
Asheville, NC 28804
[phone]
METHOD BLANK: 366098 Matrix: Solid
Associated Lab Samples: 9257362001, 9257362002, 9257362003, 9257362004, 9257362007
Blank Reporting
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704 )875-9092
Parameter Units Result Limit Analyzed Qualifiers
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
tsopropylbenzene (Cumene)
m&p-Xylene
Methyl-tert-butyl ether
Methylene Chloride
n-Butylbenzene
n-Propylbenzene
Naphthalene
o-Xylene
p-lsopropyltoluene
sec-Butylbenzene
Styrene
tert-Butylbenzene
Tetrachtoroethene
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl acetate
Vinyl chloride
Xylene (Total)
1,2-Dichloroethane-d4 (S)
4-Bromofluorobenzene ($)
Dibromofluoromethane (S)
Toluene-dB (S)
LABORATORY CONTROL SAMPLE:
Parameter
1, 1, 1,2-Tetrachloroethane
1, 1, 1-Trichloroethane
1, 1,2,2-Tetrachloroethane
1, 1,2-Trichloroethane
1, 1-Dichloroethane
1, 1-Dich!oroethene
1, 1-Dichloropropene
1,2,3-Trichlorobenzene
1,2,3-Trichloropropane
1,2,4-Trichlorobenzene
1,2,4-Trimethylbenzene
1,2-Dibromo-3-chloropropane
1,2-Oibromoethane (EDB)
Date: 12/04/2009 11:18AM
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
%
%
%
%
366099
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
Units
ND 5.0 11/13/09 09:38
ND 5.0 11/13/09 09:38
ND 5.0 11/13/09 09:38
ND 5.0 11/13/09 09:38
ND 10.0 11/13/09 09:38
ND 5.0 11/13/09 09:38
ND 20.0 11/13/09 09:38
ND 5.0 11/13/09 09:38
ND 5.0 11/13/09 09:38
ND 5.0 11/13/09 09:38
ND 5.0 11/13/09 09:38
ND 5.0 11/13/09 09:38
ND 5.0 11/13/09 09:38
ND 5.0 11/13/09 09:38
ND 5.0 11/13/09 09:38
ND 5.0 11/13/09 09:38
ND 5.0 11/13/09 09:38
ND 5.0 11/13/09 09:38
ND 5.0 11/13/09 09:38
ND 5.0 11/13/09 09:38
ND 5.0 11/13/09 09:38
ND 50.0 11/13/09 09:38
ND 10.0 11/13/09 09:38
ND 10.0 11/13/09 09:38
91 69-121 11/13/09 09:38
99 74-115 11/13/09 09:38
97 79-116 11/13/09 09:38
101 88-110 11/13/09 09:38
Spike LCS LCS %Rec
Cone. Result %Rec
50 58.3 117
50 52.9 106
50 63.3 127
50 59.0 118
50 55.8 112
50 55.4 111
50 61.3 123
50 52.9 106
50 59.3 119
50 54.7 109
50 63.9 128
50 53.2 106
50 60.6 121
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
~ithout the written consent of Pace Analytical Services, Inc ..
~~«~·~~~~ ;1ne1<10,
Limlts
75-137
70-140
74-133
79-129
72-139
69-154
74-138
71-150
74-135
68-150
70-130
65-146
77-136
Qualifiers
Page 56 of 81
Project: CASTLE HAYNE 22-12493D
Pace Project No.: 9257362
LABORATORY CONTROL SAMPLE: 366099
Parameter Units
1,2-Dichlorobenzene ug/kg
1,2-Dichloroethane ug/kg
1,2-Dichloropropane ug/kg
1,3,5-Trimethylbenzene ug/kg
1,3-Dichlorobenzene ug/kg
1,3-Dichloropropane ug/kg
1,4-Dichlorobenzene ug/kg
2,2-Dichloropropane ug/l<g
2-Butanone (MEK) ug/kg
2-Chlorotoluene ug/kg
2-Hexanone ug/kg
4-Chlorotoluene ug/kg
4-Methyl-2-pentanone (MIBK) ug/kg
Acetone ug/kg
Benzene ug/kg
Bromobenzene ug/kg
Bromochloromethane ug/kg
Bromodichloromethane ug/kg
Bromoform ug/kg
Bromomethane ug/kg
Carbon tetrachloride ug/kg
Chlorobenzene ug/kg
Chloroethane ug/kg
Chloroform ug/kg
Chloromethane ug/kg
cis-1,2-Dichloroethene ug/kg
cis-1,3:Dichloropropene ug/kg
Dibromochloromethane ug/kg
Dibromomethane ug/kg
Dichlorodifluoromethane ug/kg
Diisopropyl ether ug/kg
Ethylbenzene ug/kg
Hexachloro-1,3-butadiene ug/kg
lsopropylbenzene (Cumene) ug/kg
m&p-Xylene ug/kg
Methyl-tert-butyl ether ug/kg
Methylene Chloride ug/kg
n-Butylbenzene ug/kg
n-Propylbenzene ug/kg
Naphthalene ug/kg
a-Xylene ug/kg
p-lsopropyltoluene ug/kg
sec-Butylbenzene ug/kg
Styrene ug/kg
tert-Butylbenzene ug/kg
Tetrachloroethene ug/kg
. Toluene ug/kg
trans-1,2-Dichloroethene ug/kg
Date: 12/04/200911:18AM
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Spike LCS LCS % Rec
Cone. Result %Rec Limits
50 61.2 122 75-141
50 52.1 104 74-134
50 59.4 119 77-138
50 64.0 128 65-128
50 60.1 120 76-133
50 60.6 121 79-132
50 58.5 117 75-137
50 52.6 105 73-137
100 101 101 61-138
50 60.9 122 73-138
100 110 110 58-159
50 64.0 128 75-136
100 110 110 74-139
100 95.1J 95 58-150
50 54.2 108 71-140
50 62.7 125 72-144
50 57.0 114 78-133
50 51.8 104 78-133
50 56.4 113 74-132
50 64.0 128 63-184
50 54.3 109 73-143
50 59.1 118 77-137
50 47.7 95 68-146
50 56.5 113 75-137
50 57.3 115 54-143
50 61.9 124 71-143
50 59.4 119 76-133
50 54.7 109 77-131
50 53.9 108 63-184
50 58.8 118 36-173
50 50.3 101 68-144
50 59.3 119 69-141
50 52.6 105 70-152
50 63.8 128 77-143
100 118 118 72-138
50 50.2 100 2-138
50 44.6 89 69-136
50 62.9 126 65-128
50 66.7 133 72-139
50 57.4 115 61-138
50 61.4 123 74-137
50 62.9 126 66-128
50 65.1 130 72-140
50 63.1 126 76-137
50 64.0 128 68-141
50 60.2 120 72-136
50 57.3 115 69-139
50 50.5 101 72-144
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
?~CJ~ ,·11ac--,,ne o, • - -Ji
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Qualifiers
Page 57 of 81
Project: CASTLE HAYNE 22-124930
Pace Project No.: 9257362
LABORATORY CONTROL SAMPLE:
Parameter
trans-1,3-0ichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl acetate
Vinyl chloride
Xylene (Total)
1,2-0ichloroethane-d4 (S)
4-Bromofluorobenzene (S)
Oibromofluoromethane {S)
Toluene-d8 (S)
MATRIX SPIKE SAMPLE:
Parameter
1, 1-0ichloroethene
Benzene
Chlorobenzene
Toluene
Trichloroethene
1,2-Dichloroethane-d4 (S)
4-Bromofluorobenzene (S)
Oibromofluoromethane (S)
Toluene-d8 (S)
SAMPLE DUPLICATE: 366376
Parameter
1, 1, 1,2-Tetrachloroethane
1, 1, 1-Trichloroethane
1, 1,2,2-T~trachloroethane
1, 1,2-Trichloroethane
1, 1-0ichloroethane
1, 1-Dichtoroethene
1, 1-Dichloropropene
1,2,3-Trichlorobenzene
1,2,3-Trichloropropane
1,2,4-Trichlorobenzene
1,2,4-Trimethylbenzene
1,2-0ibromo-3-chl~ropropane
1,2-Dibromoethane (EDB)
1,2-Dichlorobenzene
1,2-Dichtoroethane
1,2-Dichloropropane
1.3,5-Trimethylbenzene
1,3-0ichlorobenzene
Date: 12/04/2009 11:18AM
366099
Units
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
%
%
%
%
366377
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
%
%
%
%
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg,
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
u9/kg
ug/kg
Units
Units
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Spike LCS LCS
Cone. Result % R~c
50 57.8 116
50 56.8 114
50 49.9 100
100 117 117
50 52.9 106
150 179 120
87
100
102
101
9257166010 Spike MS
Result Cone. Result
ND 54.6 70.2
ND 54.6 70.6
ND 54.6 72.4
ND 54.6 68.3
ND 54.6 72.5
9257392001 Dup
Result Result RPO
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
ND ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Jnc ..
~s~-~~~~ ;'1001<10,
%Rec
Limits
73-135
75-136
69-144
50-150
61-145
73-138
69-121
74-115
79-116
88-110
MS
% Rec
129
129
133
125
133
88
95
92
97
Qualifiers
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
' (704 )875-9092
Qualifiers
%Rec
Limits Qualifiers
33-158
46-143
29-159
38-145
70-130 MO
69-121
74-115
79-116
88-110
Page 58 of 81
Project: CASTLE HAYNE 22-12493D
Pace Project No.: 9257362
SAMPLE DUPLICATE: 366376
Parameter Units
1,3-Dichloropropane ug/kg
1,4-Dichlorobenzene ug/kg
2,2-Dichloropropane ug/kg
2-Butanone (MEK) ug/kg
2-Chlorotoluene ug/kg
2-Hexanone ug/kg
4-Chtorotoluene ug/kg
4-Methyl-2-pentanone (MIBK) ug/kg
Acetone ug/kg
Benzene ug/kg
Bromobenzene ug/kg
Bromochloromethane ug/kg
Bromodichtoromethane ug/kg
Bromoform ug/kg
Bromomethane ug/kg
Carbon tetrachloride ug/kg
Chlorobenzene ug/kg
Chloroethane ug/kg
Chloroform ug/kg
Chloromethane ug/kg
cis-1,2-Dichloroethene ug/kg
cis-1,3-Dichloropropene ug/kg
Dibromochloromethane ug/kg
Dibromomethane ug/kg
Dichlorodifluoromethane ug/kg
Diisopropyl ether ug/kg
Ethylbenzene ug/kg
Hexachloro-1,3-butadiene ug/kg
lsopropylbenzene (Cumene) ug/kg
m&p-Xylene ug/kg
Methyl-tert-butyl ether ug/kg
Methylene Chloride ug/kg
n-Butylbenzene ug/kg
n-Propylbenzene ug/kg
Naphthalene ug/kg
o-Xylene ug/kg
p-lsopropyltoluene ug/kg
sec-Butylbenzene ug/kg
Styrene ug/kg
tert-Butylbenzene ug/kg
Tetrachloroethene ug/kg
Toluene ug/kg
trans-1,2-Dichloroethene ug/kg
trans-1,3-Dichloropropene ug/kg
Trichloroethene ug/kg
Trichlorofluoromethane ug/kg
Vinyl acetate ug/kg
Vinyl chloride ug/kg
Date: 12/04/2009 11 :18 AM
Pace Analytical Services, Inc.
2225 Riverside Or.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
9257392001 Dup
Result Result RPO Qualifiers
ND ND
ND ND
ND ND
ND ND
NO NO
ND ND
NO NO
ND ND
NO ND
ND ND
NO ND
ND ND
ND ND
NO ND
ND ND
NO ND
ND ND
ND NO
ND ND
NO NO
ND ND
NO NO
ND ND
ND ND
ND ND
ND ND
ND ND
ND NO
ND ND
ND ND
ND ND
NO NO
ND ND
ND ND
ND NO
ND ND
ND NO
ND ND
ND NO
ND ND
ND NO
NO NO
ND ND
ND ND
ND ND
NO NO
NO NO
ND ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
Q7f~-~~ Jlnelac;,
Pace Analytical Services, lnc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704}875-9092
Page 59 of81
Project: CASTLE HAYNE 22-124930
Pace Project No.: 9257362
SAMPLE DUPLICATE: 366376
Parameter Units
Xylene (Total) ug/kg
1,2-Dichloroethane-d4 (S) %
4-Bromofluorobenzene (S) %
Dibromofluoromethane {S) %
Toluene-de (S) %
Date: 12/04/200911:18AM
Paco Analytical Sorvicos, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
9257392001 Dup
Result Result RPO
ND ND
70 70 26
94 93 24
88 86 23
94 98 28
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced. except in full,
without the written consent of Pace Analytical Services, fnc .. ,,1'ri~c-,;1nekl.Cil
Qualifiers
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 60 of 81
Project CASTLE HAYNE 22-12493D
Pace Project No.: 9257362
QC Batch: MSSV/1360
QC Batch Method: EPA 8270
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Analysis Method: EPA8270
Analysis Description: 8270 Solid MSSV Microwave
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704 )875-9092
Associated Lab Samples: 9257362001, 9257362002, 9257362003, 9257362004, 9257362005, 9257362006, 9257362007, 9257362008,
9257362009,9257362010,9257362011,9257362012
METHOD BLANK: 19929 Matrix: Solid
Associated Lab Samples: 9257362001, 9257362002, 9257362003, 9257362004, 9257362005, 9257362006, 9257362007, 9257362008,
9257362009,9257362010,9257362011, 9257362012
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
1,2,4-Trichlorobenzene ug/kg ND 170 11125109 15:09
1,2-Dichlorobenzene ug/kg ND 170 11125109 15:09
1,2-Diphenylhydrazine ug/kg ND 170 11125109 15:09
1,3-Dichlorobenzene ug/kg ND 170 1112510915:09
1,4-Dichtorobenzene ug/kg ND 170 1112510915:09
1-Methylnaphthalene ug/kg ND 33.0 11125109 15:09
2 ,4, 5-Trich lorophenol ug/kg ND 170 11/25109 15:09
2,4,6--Trichlorophenol ug/kg ND 170 11125109 15:09
2,4-Dichlorophenol ug/kg ND 170 11125109 15:09
2,4-Dimethylphenol ug/kg ND 170 11125109 15:09
2,4-Dinitrophenol ug/kg ND 670 1112510915:09
2,4-Dinitrotoluene ug/kg ND 170 11125109 15:09
2,6-Dinitrotoluene ug/kg ND 170 11125109 15:09
2-Chloronaphthalene ug/kg ND 170 11125109 15:09
2-Chlorophenol ug/kg ND 170 11125109 15:09
2-Methylnaphthalene ug/kg ND 33.0 11125109 15:09
2-Methylphenol(o-Cresol) ug/kg ND 170 11125/09 15:09
2-Nitroaniline ug/kg ND 170 11125/09 15:09
2-Nitrophenol ug/kg ND 170 11125109 15:09
3&4-Methylphenol(m&p Cresol) ug/kg ND 170 11125109 15:09
3,3'-Dichlorobenzidine ug/kg ND 670 11/25/09 15:09
3-Nitroaniline ug/kg ND 170 11125/0915:09
4,6-Oinitro-2-methylphenol ug/kg ND 670 11125109 15:09
4-Bromophenylphenyl ether ug/kg ND 170 11125109 15:09
4-Chloro-3-methylphenol ug/kg ND 670 11125109 15:09
4-Chloroaniline u9/kg ND 170 11/25/09 15:09
4-Chlorophenylphenyl ether ug/kg ND 170 11/25/09 15:09
4-Nitroaniline ug/kg ND 170 11125109 15:09
4-Nitrophenol ug/kg ND 170 11/25/09 15:09
Acenaphthene ug/kg ND 33.0 11/25/0915:09
Acenaphthylene ug/kg ND 33.0 11125109 15:09
Anthracene ug/kg ND 33.0 11/25/09 15:09
Benzo(a)anthracene ug/kg ND 33.0 11125109 15:09
Benzo(a)pyrene ug/kg ND 33.0 11125109 15:09
Benzo(b )fluoranthene ug/kg ND 33.0 11125109 15:09
Benzo(g,h, i)perylene ug/kg ND 33.0 11125109 15:09
Benzo(k)fluoranthene ug/kg ND 33.0 11125109 15:09
bis(2-Chloroethoxy)methane ug/kg ND 170 11125/09 15:09
bis(2-Chloroethyl) ether ug/kg ND 170 11125109 15:09
bis(2-Chloroisopropyl) ether ug/kg ND 170 11125109 15:09
bis(2-Ethylhexyl)phthalate ug/kg ND 170 11/25/09 15:09
Date: 12/04/2009 11:18AM REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
. -?f~-~~ .. -{nelac;~ ·--,,
Page 61 of 81
Project CASTLE HAYNE 22-12493D
Pace Project No.: 9257362
METHOD BLANK: 19929
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Matrix: Solid
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Associated Lab Samples: 9257362001,9257362002,9257362003,9257362004, 9257362005, 9257362006, 9257362007,9257362008,
9257362009,9257362010,9257362011, 9257362012
Parameter
Butylbenzylphthalate
Chrysene
Di-n-butylphthalate
· Di-n-octylphthatate
Dibenz(a,h)anthracene
Dibenzofuran
Diethylphthalate
Dimethytphthalate
Fluoranthene
Fluorene
Hexachloro-1,3-butadiene
Hexachlorobenzene
Hexachlorocyclopentadiene
Hexachloroethane
lndeno(1,2,3-cd)pyrene
lsophorone
N-Nitroso-di-n-propylamine
N-Nitrosodimethylamine
N-Nitrosodiphenylamine
Naphthalene
Nitrobenzene
Pentachlorophenol
Phenanthrene
Phenol
Pyrene
2,4,6-Tribromophenol (S)
2-Fluorobiphenyl (S)
2-Fluorophenol (S)
Nitrobenzene-d5 (S)
Phenol-d6 (S)
Terphenyl-d14 (S)
LABORATORY CONTROL SAMPLE:
Parameter
1,2,4-Trichlorobenzene
1,2-Dichlorobenzene
1,2-Diphenylhydrazine
1,3-Dichlorobenzene
1,4-Dichlorobenzene
1-Methylnaphthalene
2,4,5-Trichlorophenol
2,4,6-Trichlorophenol
2,4-Dichlorophenol
Date: 12/04/2009 11: 18 AM
Units
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
%
%
%
%
%
%
19930
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
Units
Blank Reporting
Result Limit Analyzed Qualifiers
ND 170 11/25/0915:09
ND 33.0 11 /25/09 15:09
ND 170 11 /25/09 15:09
ND 170 11/25/09 15:09
ND 33.0 11/25/0915:09
ND 170 11/25/0915:09
ND 170 11 /25/09 15:09
ND 170 11 /25/09 15:09
ND 33.0 11/25/09 15:09
ND 33.0 11/25/09 15:09
ND 170 11/25/0915:09
ND 170 11/25/0915:09
ND 670 11/25/09 15:09
ND 170 11/25/09 15:09
ND 33.0 11/25/09 15:09
ND 170 11/25/09 15:09
ND 170 11/25/09 15:09
ND 170 11/25/09 15:09
ND 170 11/25/09 15:09
ND 33.0 11 /25/09 15:09
ND 170 11/25/09 15:09
ND 670 11/25/09 15:09
ND 33.0 11/25/09 15:09
ND 170 11/25/0915:09
ND 33.0 11/25/09 15:09
76 10-110 11125/09 15:09
75 18-110 11/25/09 15:09
73 18-110 11/25/09 15:09
71 10-110 11/25/09 15:09
76 10-110 11/25/09 15:09
82 10-123 11/25/0915:09
Spike LCS LCS %Rec
Cone. Result %Rec Limits
1640 1340 81 55.2-104,2
1640 1340 82 46.8-80.1 L3
1640 1570 96
1640 1340 81 46.4-80.6 L3
1640 1310 80 37.4-86.7
1640 1410 86 20,7-121.7
1640 1540 93 58.1-101.3
1640 1570 96 46,2-106
1640 1410 86 47.1-102
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
~-?r·-"~~~ ?lnelac;\
Qualifiers
Page 62 of 81
Project CASTLE HAYNE 22-12493D
Pace Project No.: 9257362
LABORATORY CONTROL SAMPLE: 19930
Parameter Units
2,4-Dimethylphenol ug/kg
2,4-Dinitrophenol ug/kg
2,4-Dinitrotoluene ug/kg
2,6-Dinitroto1uene uglkg
2-Chloronaphthalene ug/kg
2-Chlorophenol uglkg
2-Methylnaphthalene ug/kg
2-Methylphenol(o-Cresol) ug/kg
2-Nitroaniline ug/kg
2-Nitropheno1 ug/kg
3&4-Methylphenol(m&p Cresci) ug/kg
3,3'-Dichlorobenzidine ug/kg
3-Nitroaniline ug/kg
4,6-Dinitro-2-methylphenol ug/kg
4-Bromophenylphenyl ether ug/kg
4-Chloro-3-methylphenol ug/kg
4-Chloroaniline ug/kg
4-Chlorophenylphenyl ether ug/kg
4-Nitroaniline ug/kg
4-Nitrophenol ug/kg
Acenaphthene ug/kg
Acenaphthylene ug/kg
Anthracene ug/kg
Benzo(a)anthracene ug/kg
Benzo(a)pyrene ug/kg
Benzo(b )fluoranthene ug/kg
Benzo(g,h, i)perylene ug/kg
Benzo(k)~uoranthene ug/kg
bis(2-Chloroethoxy)methane ug/kg
bis(2-Chloroethyl) ether Ug/kg
bis(2-Chloroisopropyl) ether ':IQ/kg
bis(2-Ethylhexyl)phthalate ug/kg
Butylbenzylphthalate ug/kg
Chrysene ug/kg
Di-n-butylphthalate ug/kg
Di-n-octylphthalate ug/kg
Dibenz(a,h)anthracene ug/kg
Dibenzofuran ug/kg
Diethylphthalate ug/kg
Dimethylphthalate ug/kg
Fluoranthene ug/kg
Fluorene ug/kg
Hexachloro-1,3-butadiene ug/kg
Hexachlorobenzene ug/kg
Hexachlorocyclopentadiene ug/kg
Hexachloroethane ug/kg
lndeno(1,2,3-cd)pyrene ug/kg
lsophorone ug/kg
Date: 12/04/200911:18AM
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Spike LCS LCS %Rec
Cone. Result %Rec Limits
1640 1420 86 54.1-109.9
1640 1460 89 57.6-108
1640 1600 97 62.7-99.2
1640 1530 93 53.2-110.8
1640 1470 90 49.8-101
1640 1380 84 48.2-85.3
1640 1450 88 20.9-121.3
1640 1420 86 53.2-93.1
1640 1520 93 64.2-102.8
1640 1420 87 35-142.5
1640 1470 89 50.1-87 L1
1640 1390 85 51.7-91.9
1640 1530 93 64.9-102.5
1640 1570 95 49.2-104.9
1640 1530 93 61-96.5
1640 1520 92 63.4-98.7
1640 1810 110 54.8-90.6 L3
1640 1520 92 55.1-97.6
1640 1620 99 48.6-95.1 L3
1640 1670 102 27.1-112
1640 1520 93 22-124.1
1640 1500 91 22.7-127.8
1640 1610 98 23.8-117
1640 1460 89 25.7-125
1640 1500 91 25.5-126.9
1640 1500 91 24.9-132.8
1640 1490 91 28.1-134.9
1640 1520 92 30.1-135.6
1640 1500 91 51-93.2
1640 1340 81 50.3-86.8
1640 1340 82 43.1-87.3
1640 1520 92 10-238.8
1640 1470 89 55.5-116
1640 1480 90 25.9-129.8
1640 1590 97 63.2-102.6
1640 1510 92 56.5-119.9
1640 1510 92 28.1-136
Pace Analytical Services, Inc.
9800 KinceyAvei. Suite 100
Huntersville, NC 28078
{704}875-9092
Qualifiers
1640 1490 91 44-89.3 L3
1640 1550 94 64.9-94.9
1640 1520 92 55.3-94.5
1640 1600 97 27.6-129.1
1640 1540 94 22.1-134.4
1640 1310 80 23.8-97.1
1640 1560 95 43.5-98.2
1640 973 59 37.1-91.2
1640 1340 82 50.9-110.2
1640 1510 92 27.4-134
1640 1420 86 54.7-91.2
REPORT OF LABORATORY ANALYSIS Page 63 of 81
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
ri'\"¾ §1~---f1□e Ct,
Project: CASTLE HAYNE 22-12493D
Pace Project No.: 9257362
LABORATORY CONTROL SAMPLE: 19930
Parameter Units
N-Nitroso-di-n-propylamine ug/kg
N-Nitrosodimethylamine ug/kg
N-Nitrosodiphenylamine ug/kg
Naphthalene ug/kg
Nitrobenzene ug/kg
Pentachlorophenol u9/k9
Phenanthrene ug/kg
Phenol ug/kg
Pyrene ug/kg
2,4,6-Tribromophenol (S) %
2-Fluorobiphenyl (S) %
2-Fluorophenol (S) %
Nitrobenzene-d5 (S) %
Phenol-d6 (S) %
Terphenyl-d14 (S) %
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 19931
9257362001
Paco Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Spike LCS LCS %Rec
Cone. Result %Rec Limits
1640 1380 64 60.7-96.7
1640 1320 80 50.7-89.6
1640 1560 95 53.8-112.6
1640 1380 84 19.8-116.2
1640 1330 81 54.6-87.7
1640 1740 106 35.6-133.1
1640 1570 95 27.7-128.9
1640 1440 88 49.3-102.8
1640 1460 89 27.7-128.9
95 10-110
85 18-110
81 18-110
85 10-110
86 10-110
86 10-123
19932
MS MSD
Spike Spike MS MSD MS MSD
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Qualifiers
%Rec
Parameter Units Result Cone. Cone. Result Result %Rec %Rec Limits RPO Qual -----
1,2,4-Trichtorobenzene ug/kg ND 1660 1660 1290 1200 78 73 55.2-104 7
1,2-Dichlorobenzene ug/kg ND 1660 1660 1220 1170 74 70 46.8-80. 5
1,2-Diphenylhydrazine ug/kg ND 1660 1660 1430 1450 86 88
1,3-Dichlorobenzene ug/kg ND 1660 1660 1230 1160 74 70 46.4-80. 5
1,4-Dichlorobenzene ug/kg ND 1660 1660 1220 1180 74 72 37.4-86. 3
1-Methylnaphthalene ug/kg ND 1660 1660 1320 1300 79 79 52.1-93
2,4,5-Trichlorophenol ug/kg ND 1660 1660 1370 1380 82 83 58.1-101 1
2,4,6-Trichlorophenol ug/kg ND 1660 1660 1480 1400 89 84 46.2-106 6
2,4-Dichlorophenol ug/kg ND 1660 1660 1310 1270 79 77 47.1-102 4
2,4-Dimethylphenol ug/kg ND 1660 1660 1340 1280 81 77 54.1-109 4
2,4-Dinitrophenol ug/kg ND 1660 1660 1610 1430 97 86 57.6-108 12
2,4-Dinitrotoluene ug/kg' ND 1660 1660 1470 1410 88 85 62.7-99. 4
2,6-Dinitrotoluene ug/kg ND 1660 1660 1400 1400 84 85 53.2-110 .3
2-Chloronaphthalene ug/kg ND 1660 1660 1370 1290 83 78 49.8-101 6
2-Chlorophenol ug/kg ND 1660 1660 1270 1220 76 74 48.2-85. 4
2-Methylnaphthalene ug/kg ND 1660 1660 1330 1270 80 77 51.8-92. 5
2-Methylphenol(o-Cresol) u9/k9 ND 1660 1660 1290 1220 78 74 53.2-93. 6
2-Nitroaniline ug/kg ND 1660 1660 1400 1390 85 84 64.2-102 1
2-Nitrophenol ug/kg ND 1660 1660 1320 1270 79 76 35-142.5 4
3&4-Methylphenol(m&p ug/kg ND 1660 1660 1380 1280 83 77 50.1-87 7
Cresol)
3,3'-Dichlorobenzidine ug/kg ND 1660 1660 1200 1340 72 81 51.7-91. 11
3-Nitroaniline ug/kg ND 1660 1660 1370 1410 83 85 64.9-102 3
4,6-Dinitro-2-methytphenol ug/kg ND 1660 1660 1520 1380 91 83 49.2-104 9
4-Bromophenylphenyl eth~r ug/kg ND 1660 1660 1410 1390 85 84 61-96.5 2
4-Ch1oro-3-methylphenol ug/kg ND 1660 1660 1390 1350 83 82 63.4-98. 3
4-Chloroaniline ug/kg ND 1660 1660 1240 1280 74 77 54.8-90. 4
Date: 12/04/2009 11:18AM REPORT OF LABORATORY ANALYSIS Page 64 of 81
This report shall not be reproduced. except in full,
without the written consent or Pace Analytical Services, Inc ..
~~::.!_C,;J;~
_.'/1 la: •-, 11ne 01
12~-Pace Analytical Services, Inc. Pace Analytical Services, Inc.
2225 Riverside Or. 9800 Kincey Ave. Suite 100
Asheville, NC 28804 Huntersville, NC 28078
I [phone] (704 )875-9092
QUALITY CONTROL DATA
Project: CASTLE HAYNE 22-12493D
Pace Project No.: 9257362
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 19931 19932
MS MSD
9257362001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Cone. Cone. Result Result %Rec %Rec Limits RPO Qual -----
4-Chlorophenylphenyl ether ug/kg ND 1660 1660 1400 1370 84 83 55.1-97. 2
4-Nitroaniline u9/1<9 ND 1660 1660 1400 1380 85 84 48.6-95.
4-Nitrophenol ug/kg ND 1660 1660 1430 1410 86 85 27.1-112 1
Acenaphthene u9/k9 ND 1660 1660 1430 1330 86 81 55.6-94. 7
Acenaphthylene ug/kg ND 1660 1660 1390 1320 84 80 57.6-94 5
Anthracene ug/kg ND 1660 1660 1420 1400 86 84 63.5-98. 2
Benzo(a)anthracene ug/kg ND 1660 1660 1310 1430 79 86 57.3-101 9
Benzo(a)pyrene ug/kg ND 1660 1660 1330 1440 80 87 68.5-98. 8
Benzo(b)fluoranthene ug/kg ND 1660 1660 1270 1390 76 84 66.7-98. 10
Benzo(g, h, i)perylene ug/kg ND 1660 1660 1320 1420 79 86 70-130 8
Benzo(k)fluoranthene ug/kg ND 1660 1660 1390 1430 84 87 68.5-99. 3
bis(2-Chloroethoxy)methane ug/kg ND 1660 1660 1330 1300 80 78 51-93.2 2
bis(2-Chloroethyl) ether u9/1<9 ND 1660 1660 1230 1230 74 74 50.3-86. .1
bis(2-Chloroisopropyl) ether ug/kg ND 1660. 1660 1250 1230 75 74 43.1-87. 2
bis(2-Ethylhexyl)phthalate ug/kg ND 1660 1660 1340 1480 81 89 10-238.8 10
Butylbenzylphthalate ug/kg ND 1660 1660 1320 1450 80 88 55.5-116 9
Chrysene ug/kg ND 1660 1660 1320 1430 79 86 52.9-104 8
Di-n-butylphthalate ug/kg ND 1660 1660 1450 1440 88 87 63.2-102
Di-n-octylphthalate ug/kg ND 1660 1660 1350 1500 81 90 56.5-119 10
Dibenz(a, h)anthracene ug/kg ND 1660 1660 1330 1420 80 86 58.1-100 6
Dibenzofuran ug/kg ND 1660 1660 1360 1340 82 81 44-89.3
Diethylphthalate ug/kg ND 1660 1660 1430 1410 86 85 64.9-94.
Dimethylphthalate ug/kg ND 1660 1660 1420 1380 86 83 55.3-94. 3
Fluoranthene ug/kg ND 1660 1660 1450 1420 87 86 60-99.7 2
Fluorene ug/kg ND 1660 1660 1430 1360 86 82 61.2-97. 5
Hexachloro-1,3-butadiene ug/kg ND 1660 1660 1250 1180 75 71 23.8-97. 6
Hexachlorobenzene ug/kg ND 1660 1660 1400 1400 84 84 43.5-98. .3
Hexachlorocyclopentadiene ug/kg ND 1660 1660 1170 1000 71 61 37.1-91. 15
Hexachloroethane ug/kg ND 1660 1660 1260 1140 76 69 50.9-110 10
lndeno(1,2,3-cd)pyrene ug/kg ND 1660 1660 1340 1420 80 86 49-102.7 6
lsophorone ug/kg ND 1660 1660 1330 1300 80 79 54.7-91. 2
N-Nitroso-di-n-propylamine ug/kg ND 1660 1660 1350 1240 81 75 60.7-96. 9
N-Nitrosodimethytamine ug/kg ND 1660 1660 1180 1140 71 69 50.7-89. 3
N-Nitrosodiphenylamine ug/kg ND 1660 1660 1430 1380 86 84 53.8-112 3
Naphthalene ug/kg ND 1660 1660 1260 1220 76 74 53.9-103 3
Nitrobenzene ug/kg ND 1660 1660 1250 1210 75 73 54.6-87. 3
Pentachlorophenol ug/kg ND 1660 1660 1750 1540 105 93 35.6-133 13
Phenanthrene ug/kg ND 1660 1660 1440 1420 87 86 48.2-98. 1
Phenol ug/kg ND 1660 1660 1270 1270 77 77 49.3-102 .6
Pyrene ug/kg ND 1660 1660 1320 1440 80 87 21.3-106 9
2,4,6-Tribromo'phenol (S) % 86 81 10-110
2-Fluorobiphenyl (S) % 78 75 18-110
2-Fluoropheno1 (S) % 73 72 18-110
Nitrobenzene-d5 (S) % 78 78 10-110
Phenol-d6 ($) % 78 75 10-110
Terphenyl-d14 (S) % 77 85 10-123
Date: 12/04/2009 11: 18 AM REPORT OF LABORATORY ANALYSIS Page 65 of 81
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
~~«·\.~~~ 11nelac11
Project: CASTLE HAYNE 22-124930
Pace Project No.: 9257362
Pace Analytical Services, Inc.
2225 Riverside Dr.
QUALITY CONTROL DATA
Asheville, NC 28804
[phone]
QC Batch: PMST/2882 Analysis Method: ASTM D2974-87
QC Batch Method: ASTM 02974-87 Analysis Description: Dry WeighUPercent Moisture
Paco Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Associated Lab Samples: 9257362001, 9257362002, 9257362003, 9257362004, 9257362005, 9257362006, 9257362007, 9257362008,
9257362009,9257362010, 9257362011, 9257362012
SAMPLE DUPLICATE: 366337
Parameter Units
Percent Moisture %
SAMPLE DUPLICATE: 366338
Parameter Units
Percent Moisture %
Date: 12/04/2009 11:18AM
9257466008 Dup
Result Result
29.3 29.9
9257339001 Dup
Result
24.7
Result
24.1
RPO
RPO
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc .. .?«.<~~~ 11nelacr,
Qualifiers
2
Qualifiers
3
Page 66 of 81
Project: CASTLE HAYNE 22-12493D
Pace Project No.: 9257362
QC Batch: MSV/9017
QC Batch Method: EPA 8260
Associated Lab Samples: 9257362005, 9257362006
Paco Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Analysis Method:
~natysis Description:
EPA8260
8260 MSV 5035A Volatile Organics
METHOD BLANK: 366100 Matrix: Solid
Associated Lab Samples: 9257362005, 9257362006
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
1, 1, 1,2-Tetrachloroethane ug/kg ND 5.0 11/15/0910:13
1, 1, 1-T richloroethane ug/kg ND 5.0 11/15/09 10:13
1, 1,2,2-Tetrachloroethane ug/kg ND 5.0 11/15/09 10:13
1, 1,2-Trichloroethane ug/kg ND 5.0 11/15/09 10:13
1, 1-Dichloroethane ug/kg ND 5.0 11/15/09 10:13
1.1-Dichloroethene ug/kg ND 5.0 11/15/09 10:13
1, 1-Dichloropropene ug/kg ND 5.0 11/15/09 10:13
1,2,3-T richlorobenzene ug/kg ND 5.0 11/15/09 10:13
1,2,3-Trichloropropane ug/kg ND 5.0 11/15/09 10:13
1,2,4-Trichlorobenzene ug/kg ND 5.0 11/15/09 10:13
1,2,4-Trimethylbenzene ug/kg ND 5.0 11/15/09 10:13
1,2-Dibromo-3-chloropropane ug/kg ND 5.0 11/15/09 10:13
1,2-Dibromoethane (EDB) ug/kg ND 5.0 11/15/0910:13
1,2-Dichtorobenzene ug/kg ND 5.0 11/15/09 10:13
1,2-Dichloroethane ug/kg ND 5.0 11/15/09 10:13
1,2-Dichloropropane ug/kg ND 5.0 11/15/09 10:13
1,3,5-T rimethylbenzene ug/kg ND 5.0 11/15/09 10:13
1,3-Dichlorobenzene ug/kg ND 5.0 11/15/09 10:13
1,3-Dichloropropane ugikg ND 5.0 11/15/09 10:13
1,4-Dichlorobenzene ug/kg ND 5.0 11/15/0910:13
2,2-Dic~loropropane ug/kg ND 5.0 11/15/09 10:13
2-Butanone (MEK) ug/kg ND 100 11/15/09 10:13
2-Chlorotoluene ug/kg ND 5.0 11/15/09 10:13
2-Hexanone ug/kg ND 50.0 11/15/09 10:13
4-Chlorotoluene ug/kg ND 5.0 11/15/09 10:13
4-Methyl-2-pentanone (MIBK) ug/kg ND 50.0 11/15/09 10:13
Acetone ug/kg ND 100 11/15/0910:13
Benzene ug/kg ND 5.0 11/15/0910:13
Bromobenzene ug/kg ND 5.0 11/15/0910:13
Bromochloromethane ug/kg ND 5.0 11/15/09 10:13
Bromodichloromethane ug/kg ND 5.0 11/15/09 10:13
Bromoform ug/kg ND 5.0 11/15/09 10:13
Bromomethane ug/kg ND 10.0 11/15/09 10:13
Carbon tetrachloride ug/kg ND 5.0 11/15/09 10:13
Chlorobenzene ug/kg ND 5.0 11/15/09 10:13
Chloroethane ug/kg ND 10.0 11/15/09 10:13
Chloroform ug/kg ND 5.0 11/15/09 10:13
Chloromethane ug/kg ND 10.0 11/15/0910:13
cis-1,2-Dichloroethene ug/kg ND 5.0 11/15/09 10:13
cis-1,3-Dichloropropene ug/kg ND 5.0 11/15/09 10:13
Dibromochloromethane ug/kg ND 5.0 11/15/09 10:13
Dibromomethane ug/kg ND 5.0 11/15/09 10:13
Dichlorodifluoromethane ug/kg ND 10.0 11/15/09 10:13
Date: 12/04/2009 11: 18 AM REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
,,•"-"~
.•1/J la ·--?1ne Ci',
Paco Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704 }875-9092
Page 67 of 81
Project: CASTLE HAYNE 22-124930
Pace Project No.: 9257362
METHOD BLANK: 366100
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Matrix: Solid
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704 )875-9092
Associated Lab Samples: 9257362005,9257362006
Parameter
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
lsopropylbenzene (Cumene)
m&p-Xylene
Methyl-tert-butyl ether
Methylene Chloride
n-Butylbenzene
n-Propylbenzene
Naphthalene
o-Xylene
p-lsopropyltoluene
sec-Butylbenzene
Styrene
tert-Butylbenzene
Tetrachloroethene
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl acetate
Vinyl chloride
Xylene (Total)
1,2-Dichloroethane-c:14 (S)
4-Bromofluorobenzene (S)
Dibromofluoromethane (S)
Toluene-c:18 (S)
LABORATORY CONTROL SAMPLE:
Parameter
1, 1, 1,2-Tetrachloroethane
1, 1, 1-Trichloroethane
1, 1,2,2-Tetrachloroethane
1, 1,2-Trichloroethane
1, 1-Dichloroethane
1, 1-Dichloroethene
1, 1-Dichloropropene
1,2,3-Trichlorobenzene
1,2,3-Trichloropropane
1,2,4-Trichlorobenzene
1,2,4-Trimethylbenzene
1,2-Dibromo-3-chloropropane
1,2-Dibromoethane (EDB)
Date: 12/04/2009 11: 18 AM
Units
ug/kg
ug/kg
u9/k9
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
%
%
%
%
366101
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
Units
Blank Reporting
Result Limit Analyzed Qualifiers
ND 5.0 11/15/09 10:13
ND 5.0 11/15/09 10:13
ND 5.0 11/15/0910:13
ND 5.0 11/15/09 10:13
ND 10.0 11/15/09 10:13
ND 5.0 11/15/09 10:13
ND 20.0 11/15/09 10:13
ND 5.0 11/15/09 10:13
NO 5.0 11/15/09 10:13
ND 5.0 11/15/09 10:13
NO 5.0 11/15/09 10:13
ND 5.0 11/15/09 10:13
NO 5.0 11/15/09 10:13
ND 5.0 11/15/09 10:13
ND 5.0 11/15/09 10:13
ND 5.0 11/15/09 10:13
ND 5.0 11/15/09 10:13
ND 5.0 11/15/09 10:13
ND 5.0 11/15/0910:13
NO 5.0 11/15/09 10:13
ND 5.0 11/15/09 10:13
ND 50.0 11/15/09 10:13
NO 10.0 11/15/09 10:13
ND 10.0 11/15/0910:13
89 69-121 11/15/09 10:13
96 74-115 11/15/09 10:13
96 79-116 11/15/09 10:13
99 88-110 11/15/09 10:13
Spike LCS LCS % Rec
Cone. Result %Rec
50 60.9 122
50 55.3 111
50 61.6 123
50 59.1 118
50 55.7 111
50 55.3 111
50 63.0 126
50 53.5 107
50 57.3 115
50 56.0 112
50 64.3 129
50 52.3 105
50 62.7 125
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
~~f.!i~~~r
f,neldCi'c
Limits
75-137
70-140
74-133
79-129
72-139
69-154
74-138
71-150
74-135
68-150
70-130
65-146
77-136
Qualifiers
Page 68 of 81
Project: CASTLE HAYNE 22-124930
Pace Project No.: 9257362
LABORATORY CONTROL SAMPLE: 366101
Parameter Units
1,2-Dichlorobenzene ugtkg
1,2-Dichloroethane ug/kg
1,2-Dichloropropane ug/kg
1,3,5-Trimethylbenzene ug/kg
1,3-Dichlorobenzene ug/kg
1,3-Dich1oropropane ug/kg
1,4-Dichlorobenzene ug/kg
2,2-Dichloropropane ug/kg
2-But<!-none (MEK) ug/kg
2-Chlorotoluene ug/kg
2-Hexanone ug/kg
4-Chlorotoluene ug/kg
4-Methyl-2-pentanone (MIBK) ug/kg
Acetone ug/kg
Benzene ug/kg
Bromobenzene ug/kg
Bromochloromethane ug/kg
Bromodichloromethane ug/kg
Bromoform ug/kg
Bromomethane ug/kg
Carbon tetrachloride ug/kg
Chlorobenzene ug/kg
Chloroethane ug/kg
Chloroform ug/kg
Ch1oromethane ug/kg
cis-1,2-Dichloroethene ug/kg
cis-1,3-Dichloropropene ug/kg
Dibromochloromethane ug/kg
Dibromomethane ug/kg
Dichlorodifluoromethane ug/kg
Diisopropyl ether ug/kg
Ethylbenzene ug/kg
Hexachloro-1,3-butadiene ug/kg
lsopropylbenzene (Cumene) ug/kg
m&p-Xylene ug/kg
Methyl-tert-butyl ether ug/kg
Methylene Chloride ug/kg
n-Butylbenzene ug/kg
n-Propylbenzene ug/kg
Naphthalene ug/kg
a-Xylene ug/kg
p-lsopropyltoluene ug/kg
sec-Butyl benzene ugtkg
Styrene ug/kg
tert-Butylbenzene ug/kg
Tetrachloroethene ug/kg
Toluene ug/kg
trans-1,2-Dichloroethene ug/kg
Date: 12/04/2009 11: 18 AM
Paco Analytical Services, 1nc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Spike LCS LCS %Rec
Cone. Result %Rec Limits
50 58.6 117 75-141
50 55.1 110 74-134
50 62.4 125 77-138
50 63.4 127 65-128
50 61.5 123 76-133
50 62.3 125 79-132
50 59.2 118 75-137
50 56.0 112 73-137
100 101 101 61-138
50 59.4 119 73-138
·100 108 108 58-159
50 63.0 126 75-136
100 104 104 74-139
100 96.4J 96 58-150
50 59.4 119 71-140
50 60.7 121 72-144
50 58.2 116 78-133
50 54.0 108 78-133
50 56.2 112 74-132
50 70.2 140 63-184
50 59.1 118 73-143
50 60.7 121 77-137
50 49.4 99 68-146
50 58.7 117 75-137
50 59.8 120 54-143
50 62.0 124 71-143
50 58.9 118 76-133
50 56.3 113 77-131
50 56.6 113 63-184
50 65.5 131 36-173
50 48.3 97 68-144
50 61.8 124 69-141
50 54.0 108 70-152
50 62.9 126 77-143
100 123 123 72-138
50 50.4 101 2-138
50 43.7 87 69-136
50 61.1 122 65-128
50 65.1 130 72-139
50 55.5 111 61-138
50 63.3 127 74-137
50 63.4 127 66-128
50 65.0 130 72-140
50 63.8 128 76-137
50 63.4 127 68-141
50 61.7 123 72-136
50 58.7 117 69-139
50 51.7 103 72-144
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
. P¾~•-c'-~~~ m1elac1,
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Qualifiers
Page 69 of 81
Project: CASTLE HAYNE 22-12493D
Pace Project No.: 9257362
LABORATORY CONTROL SAMPLE: 366101
Parameter Units
trans-1,3-Dichloropropene ug/kg
Trich1oroethene ug/kg
Trichlorofluoromethane ug/kg
Vinyl acetate ug/kg
Vinyl chloride ug/kg
Xylene {Total) ug/kg
1,2-Dichloroethane--d4 (S) %
4-Bromofluorobenzene (S) %
Dibromofluoromethane {S) %
Toluene-dB {$) %
Date: 12/04/2009 11 :18 AM
Pace Analytical Services, lnc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Spike LCS LCS
Cone. Result %Rec
50 57.2 114
50 60.7 121
50 51.3 103
100 115 115
50 55.7 111
150 186 124
89
96
97
98
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
~~->\~-'-i'¾~,
fcOeldC\o
%Rec
Limits
73-135
75-136
69-144
50-150
61-145
73-138
69-121
74-115
79-116
88-110
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Qualifiers
Page 70 of 81
Project: CASTLE HAYNE 22-124930
Pace Project No.: 9257362
QC Batch: MSV/9045
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Analysis Method: EPA8260
QC Batch Method: EPA 8260 Analysis Description: 8260 MSV 5035A Volatile Organics
Associated Lab Samples: 9257362008, 9257362009, 9257362010, 9257362011, 9257362012
METHOD BLANK: 366830 Matrix: Solid
Associated Lab Samples: 9257362008,9257362009, 9257362010,9257362011, 9257362012
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
1, 1, 1,2-Tetrachloroethane ug/kg ND 5.0 11115109 10:32
1, 1, 1-T richloroethane ug/kg ND 5.0 11115/09 10:32
1, 1,2,2-Tetrachloroethane ug/kg ND 5.0 11115109 10:32
1, 1,2-Trichloroethane ug/kg ND 5.0 11115109 10:32
1, 1-Oichloroethane ug/kg ND 5.0 11/15109 10:32
1, 1-Dichloroethene ug/kg ND 5.0 11115109 10:32
1, 1-0ichloropropene ug/kg ND 5.0 11115109 10:32
1,2,3-T richlorobenzene u9/kg ND 5.0 11115109 10:32
1,2,3-Trichloropropane ug/kg ND 5.0 11/15/0910:32
1,2,4-Trichlorobenzene ug/kg ND 5.0 11115109 1 0:32
1,2,4-Trimethylbenzene ug/kg ND 5.0 11/15109 10:32
1,2-Oibromo-3-chloropropane ug/kg ND 5.0 11115109 10:32
1,2-Oibromoethane (EOB) ug/kg ND 5.0 11115109 10:32
1,2-0ichlorobenzene ug/kg ND 5.0 11115109 10:32
1,2-Dichloroethane ug/kg ND 5.0 11115109 10:32
1,2-Dichloropropane ug/kg ND 5.0 11115109 10:32
1,3,5-Trimethylbenzene ug/kg ND 5.0 11115109 10:32
1,3-Dichlorobenzene ug/kg ND 5.0 11/15109 10:32
1,3-Oichloropropane ug/kg ND 5.0 11115109 10:32
1,4-Dichlorobenzene ug/kg ND 5.0 11115109 10:32
2,2-0ichloropropane ug/kg ND 5.0 11/15/09 10:32
2-Butanone (MEK) ug/kg ND 100 11115109 10:32
2-Chlorotoluene ug/kg ND 5.0 11115109 10:32
2-Hexanone ug/kg ND 50.0 11/15/09 10:32
4-Chlorotoluene ug/kg ND 5.0 11/15109 10:32
4-Methyl-2-pentanone (MIBK) ug/kg ND 50.0 11/15109 10:32
Acetone ug/kg ND 100 11115109 10:32
Benzene ug/kg ND 5.0 11115109 10:32
Bromobenzene ug/kg ND 5.0 11115109 10:32
Bromochloromethane ug/kg ND 5.0 11/15/09 10:32
Bromodichloromethane ug/kg ND 5.0 11/15/09 10:32
Bromoform ug/kg ND 5.0 11115109 10:32
Bromomethane ug/kg ND 10.0 11115109 10:32
Carbon tetrachloride ug/kg ND 5.0 11/15/09 10:32
Chlorobenzene uglkg ND 5.0 11115109 10:32
Chloroethane ug/kg ND 10.0 11115/0910:32
Chloroform ug/kg ND 5.0 11115109 10:32
Chloromethane ug/kg NO 10.0 11115109 10:32
cis-1,2-Dichloroethene ug/kg ND 5.0 11115109 10:32
cis-1,3-Dichloropropene ug/kg. ND 5.0 1111510910:32
Dibromochloromethane ug/kg NO 5.0 11115109 10:32
Dibromornethane ug/kg ND 5.0 11115109 10:32
Dichlorodifluoromethane ug/kg ND 10.0 11115109 10:32
Date: 12/04/200911:18AM REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
Q?!,!·~,, ?ioelac;,
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 71 of 81
Project: CASTLE HAYNE 22-12493D
Pace Project No.: 9257362
Pace Analytical Services, Inc.
2225 Riverside Dr.
QUALITY CONTROL DATA
Asheville, NC 28804
[phone]
METHOD BLANK: 366830 Matrix: Solid
Associated Lab Samples: 9257362008, 9257362009, 9257362010, 9257362011, 9257362012
Blank Reporting
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704 )875-9092
Parameter Units Result · Limit Analyzed Qualifiers
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
lsopropylbenzene (Cumene)
m&p-Xylene
Methyl-tert-butyl ether
Methylene Chloride
n-Butylbenzene
n-Propylbenzene
Naphthalene
a-Xylene
p-lsopropyltoluene
sec-Butyl benzene
Styrene
tert-Butylbenzene
Tetrachloroethene
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl acetate
Vinyl chloride
Xylene (Total)
1,2-Dichloroethane-d4 (S)
4-Bromofluorobenzene (S)
Dibromofluoromethane (S)
Toluene-dB (S)
LABORATORY CONTROL SAMPLE:
Parameter
1, 1, 1,2-Tetrachloroethane
1, 1, 1-Trichloroethane
1, 1,2,2-Tetrachloroethane
1, 1,2-Trichloroethane
1, 1-Dichloroethane
1, 1-Dichloroethene
1, 1-Dichloropropene
1,2,3-Trichlorobenzene
1,2,3-Trichloropropane
1,2,4-Trichlorobenzene
1,2,4-T rimethylbenzene
1,2-Dibromo-3-chloropropane
1,2-Dibromoethane (EDB)
Date: 12/04/200911:18AM
ug/kg
ug/kg
ug/kg
ug/kg
ug/k.g
ug/kg
ug/kg
ug/kg
ug/k.g
ug/k.g
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/k.g
ug/k.g
ug/kg
ug/kg
%
%
%
%
366831
ug/k.g
ug/kg
ug/kg
ug/kg
ug/kg
ug/k.g
ug/k.g
ug/kg
ug/kg
ug/kg
ug/kg
ug/k.g
ug/kg
Units
ND 5.0 11/15/09 10:32
ND 5.0 11/15/09 10:32
ND 5.0 11/15/09 10:32
ND 5.0 11/15/09 10:32
ND 10.0 11/15/09 10:32
ND 5.0 11/15/09 10:32
ND 20.0 11/15/09 10:32
ND 5.0 11/15/09 10:32
ND 5.0 11/15/09 10:32
ND 5.0 11/15/09 10:32
ND 5.0 11/15/09 10:32
ND 5.0 11/15/09 10:32
ND 5.0 11/15/09 10:32
ND 5.0 11/15/09 10:32
ND 5.0 11/15/09 10:32
ND 5.0 11/15/09 10:32
ND 5.0 11/15/09 10:32
ND 5.0 11/15/0910:32
ND 5.0 11/15/09 10:32
ND 5.0 11/15/09 10:32
ND 5.0 11/15/09 10:32
ND 50.0 11/15/09 10:32
ND 10.0 11/1510910:32
ND 10.0 11/1510910:32
85 69-121 11/15109 10:32
98 74-115 11/15109 10:32
96 79-116 11/15109 10:32
99 88-110 11/1510910:32
Spike LCS LCS %Rec
Cone. Result %Rec
50 58.4 117
50 54.0 108
50 59.3 119
50 57.8 116
50 54.3 109
50 54.6 109
50 62.1 124
50 56.6 113
50 55.5 111
50 58.7 117
50 64.9 130
50 54.3 109
50 59.7 119
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
Limits
75-137
70-140
74-133
79-129
72-139
69-154
74-138
71-150
74-135
68-150
70-130
65-146
77-136
Qualifiers
Page 72 of 81
Project: CASTLE HAYNE 22-124930
Pace Project No.: 9257362
LABORATORY CONTROL SAMPLE: 366831
Parameter Units
1,2-Dichlorobenzene ug/kg
1,2-Dichloroethane ug/kg
1,2-Dichloropropane ug/kg
1,3,5-Trimethylbenzene ug/kg
1,3-Dichlorobenzene ug/kg
1,3-Dichloropropane ugil<g
1,4-Dichlorobenzene ug/kg
2,2-Dichloropropane ug/kg
2-Butanone (MEK) ug/kg
2-Chlorotoluene ug/kg
2-Hexanone ug/kg
4-Chlorotoluene ug/kg
4-Methyl-2-pentanone (MIBK) uglkg
Acetone ug/kg
Benzene ug/kg
Bromobenzene ug/kg
Bromochloromethane ug/kg
Bromodichloromethane ug/kg
Bromoform ug/kg
Bromomethane ug/kg
Carbon tetrachloride ug/kg
Chlorobenzene ug/kg
Chloroethane ug/kg
Chloroform ug/kg
Chloromethane ugil<g
cis-1,2-Dichloroethene ug/kg
cis-1,3-Dichloropropene ug/kg
Dibromochloromethane ug/kg
Dibromomethane ug/kg
Dichlorodifluoromethane ug/kg
Diisopropyl ether ug/kg
Ethylbenzene ug/kg
Hexachloro-1,3-butadiene ug/kg
lsopropylbenzene (Cumene) ug/kg
m&p-Xy1ene uglkg
Methyl-tert-butyl ether ug/kg
Methylene Chloride ug/kg
n-Butylbenzene ug/kg
n-Propylbenzene ug/kg
Naphthalene ug/kg
a-Xylene ug/kg
p-lsopropyltoluene ug/kg
sec-Butyl benzene ug/kg
Styrene ug/kg
tert-Butylbenzene ug/kg
Tetrachloroethene ug/kg
Toluene · ug/kg
trans-1,2-Dichloroethene ug/kg
Date: 12/04/2009 11:18AM
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Spike LCS LCS % Rec
Cone. Result %Rec Limits
50 59.4 119 75-141
50 54.3 109 74-134
50 60.2 120 77-138
50 63.7 127 65-128
50 60.8 122 76-133
50 59.7 119 79-132
50 59.2 118 75-137
50 54.8 110 73-137
100 94J 94 61-138
50 60.1 120 73-138
100 101 101 58-159
50 64.4 129 75-136
100 100 100 74-139
100 97.6J 98 58-150
50 57.7 115 71-140
50 60.8 122 72-144
50 57.8 116 78-133
50 52.4 105 78-133
50 54.1 108 74-132
50 68.7 137 63-184
50 57.2 114 73-143
50 58.3 117 77-137
50 49.5 99 68-146
50 57.1 114 75-137
50 59.6 119 54-143
50 60.4 121 71-143
50 56.8 114 76-133
50 53.0 106 77-131
50 55.3 111 63-184
50 65.8 132 36-173
50 46.9 94 68-144
50 59.4 119 69-141
50 56.2 112 70-152
50 61.4 123 77-143
100 117 117 72-138
50 49.4 99 2-138
50 43.7 87 69-136
50 62.5 125 65-128
50 65.5 131 72-139
50 58.0 116 61-138
50 58.8 118 74-137
50 62.8 126 66-128
50 65.1 130 72-140
50 60.6 121 76-137
50 63.8 128 68-141
50 59.2 118 72-136
50 57.5 115 69-139
50 50.9 102 72-144
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
«\.~ ''la"• 11ne Ci,
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Qualifiers
Page 73 of 81
Project: CASTLE HAYNE 22· 12493D
Pace Project No.: 9257362
LABORATORY CONTROL SAMPLE: 366831
Parameter
trans-1,3·Dichloropropene
T richloroethene
Trichlorofluoromethane
Vinyl acetate
Vinyl chloride
Xylene (Total)
1,2•Dichloroethane·d4 (S)
4·Bromofluorobenzene (S)
Dibromofluoromethane (S)
Toluene-dB (S)
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
%
%
%
%
Units
MATRIX SPIKE SAMPLE: 366941
Parameter
1, 1 •Dichloroethene
Benzene
Chlorobenzene
Toluene
T richloroethene
1,2·Dichloroethane--d4 (S)
4•Bromofluorobenzene (S)
Dlbroi"nofluoromethane (S)
Toluene•d8 (S)
SAMPLE DUPLICATE: 366942
Parameter
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
%
%
%
%
1, 1, 1,2·Tetrachloroethane ug/kg
1,1,1-Trichloroethane ug/kg
1, 1,2,2.Tetrachloroethane ug/kg
1, 1,2·Trichloroethane ug/kg
1, 1·Dichloroethane ug/kg
1, 1-Dichloroethene ug/kg
1, 1-Dichloropropene ug/kg
1,2,3•Trichlorobenzene ug/kg
1,2,3-Trichloropropane ug/kg
1,2,4•Trichlorobenzene ug/kg
1,2,4•Trimethytbenzene ug/kg
1,2·Dibromo-3·chloropropane ug/kg
1,2-Dibromoethane (EDB) ug/kg
1,2-Dichlorobenzene ug/kg
1,2•Dichloroethane ug/kg
1,2•Dichloropropane ug/kg
1,3,S•Trimethylbenzene ug/kg
1,3•Dichlorobenzene ug/kg
Date: 12/04/2009 11:18AM
Units
Units
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
(828)254•7176
QUALITY CONTROL DATA
Spike LCS LCS
Cone. Result % Rec
50 56.2 112
50 59.0 118
50 51.3 103
100 116 116
50 55.4 111
150 176 117
89
95
99
98
9257362008 Spike MS
Result Cone. Result
ND 44.3 29.1
ND 44.3 23.4
ND 44.3 12.7
ND 44.3 17.1
ND 44.3 19.2
9257504002 Dup
Result Result RPO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
,._~~c~• 11Re1al-;,,
% Rec
Limits
73-135
75-136
69· 144
50-150
61·145
73-138
69-121
74-115
79-116
88-110
MS
%Rec
66
53
29
39
43
115
95
106
102
Qualifiers
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704 )875-9092
Qualifiers
%Rec
Limits Qualifiers
33-158
46-143
29-159
38-145
70-130 M3
59.121
74-115
79-116
88-110
Page 74 of 81
Project CASTLE HAYNE 22-124930
Pace Project No.: 9257362
SAMPLE DUPLICATE: 366942
Parameter
1,3-Dichloropropane
1,4-Dichlorobenzene
2,2-Dichloropropane
2-Butanone (MEK)
2-Chlorotoluene
2-Hexanone
4-Chlorotoluene
4-Methyl-2-pentanone (MlBK)
Acetone
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
cis-1,2-Dichloroethene
cis-1,3-Dichloropropene
Dibromoch1oromethane
Dibromomethane
Dichlorodifluoromethane
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
lsopropylbenzene (Cumene)
m&p-Xylene
Methyl-tert-butyl ether
Methylene Chloride
n-Butylbenzene
n-Propylbenzene
Naphthalene
a-Xylene
p-lsopropyltoluene
sec-Butylbenzene
Styrene
tert-Butylbenzene
Tetrachloroethene
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl acetate
Vinyl chloride
Date: 12/04/2009 11 :18 AM
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
Units
Pace Analytical Services, Inc.
2225 Riverside Or.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
9257504002 Dup
Result Result RPD
ND
ND
ND
ND
ND
ND
ND
ND
ND
3.1J
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
3.1J
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
4.8
ND
ND
ND
ND
ND
ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
~Q«-~~~~ 11nelao,
Qualifiers
Pace Analytical Sorvices, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704 )875-9092
Page 75 of 81
Project: CASTLE HAYNE 22-124930
Pace Project No.: 9257362
SAMPLE DUPLICATE: 366942
Parameter
Xylene (Total)
1,2-Dichloroethane--04 (S)
4-Bromofluorobenzene (S)
Dibromofluorom~thane (S)
Toluene--08 (S)
Date: 12/04/2009 11:18AM
ug/kg
%
%
%
%
Units
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
9257504002
Result
Dup
Result RPO
ND
105
101
108
101
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
.... ,:-f'\"""•"• 11nelact,
Qualifiers
Paco Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 76 of 81
Project: CASTLE HAYNE 22-12493D
Pace Project No.: 9257362
QC Batch: MPRP/5385
QC Batch Method: EPA 3050
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Analysis Method:
Analysis Description:
EPA 6010
6010 MET
Associated Lab Samples: 9257362001, 9257362002, 9257362003, 9257362004, 9257362005, 9257362006
METHOD BLANK: 365829 Matrix: Solid
Associated Lab Samples: 9257362001, 9257362002, 9257362003, 9257362004, 9257362005, 9257362006
Blank Reporting
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875--9092
Parameter Units Result Limit Analyzed Qualifiers
Aluminum
Antimony
Arsenic
Beryllium
Chromium
Copper
Iron
Lead
Nickel
Thallium
Zinc
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
LABORATORY CONTROL SAMPLE: 365830
Aluminum
Antimony
Arsenic
Beryllium
Chromium
Copper
Iron
Lead
Nickel
Thallium
Zinc
Parameter
MATRIX SPIKE SAMPLE:
Aluminum
Antimony
Arsenic
Beryllium
Chromium
Copper
Iron
Lead
Nickel
Thallium
Parameter
Date: 12/04/2009 11:18AM
Units
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
365831
Units
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg.
mg/kg
mg/kg
mg/kg
ND 10.0 11/17/09 18:02
ND 0.50 11/17/0918:02
ND 0.50 11/17/09 18:02
ND 0.10 11/17/09 18:02
ND 0.50 11/17/09 18:02
ND 0.50 11/17/09 18:02
ND 5.0 11/17/09 18:02
ND 0.50 11/17/09 18:02
ND 0.50 11/17/09 18:02
ND 1.0 11/17/09 18:02
ND 1.0 11/17/09 18:02
Spike LCS LCS % Rec
Cone. Result %Rec
500 503 101
50 50.4 101
50 47.8 96
50 50.2 100
50 51.1 102
50 48.5 97
500 519 104
50 48.7 97
50 50.4 101
50 46.2 92
50 49.5 99
9257166012 Spike MS
Result Cone. Result
14100 530 29300
0.90 53 33.6
2.8 53 50.3
0.25 53 53.5
17.3 53 77.6
5.8 53 62.9
22100 530 21300
13.0 53 60.1
1.3 53 51.7
ND 53 42.6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
.?-pf-·-,~~~ 11nelaei,
Limits
80-120
80-120
80-120
80-120
80-120
80-120
80-120
80-120
80-120
80-120
80-120
MS
%Rec
2879
62
90
101
114
108
-146
89
95
80
Qualifiers
%Rec
Limits Qualifiers
75-125 MO
75-125 MO
75-125
75-125
75-125
75-125
75-125 MO
75-125
75-125
75-125
Page 77 of 81
Project: CASTLE HAYNE 22-12493D
Pace Project No.: 9257362
MATRIX SPIKE SAMPLE: 365831
Parameter Units
Zinc mg/kg
SAMPLE DUPLICATE: 365832
Parameter Units
Aluminum mg/kg
Antimony mg/kg
Arsenic mg/kg
Beryllium mg/kg
Chromium mg/kg
Copper mg/kg
Iron mg/kg
Lead mg/kg
Nickel mg/kg
Thallium mg/kg
Zinc mg/kg
Date: 12/04/2009 11:18AM
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
9257166012
Result
10.6
9257166013
Spike
Cone.
53
Dup
MS
Result
68.0
MS
% Rec
108
Result Result RPD Qualifiers
20700 19000 9
1.2 0.82 38 R1
3.9 3.4 13
0.30 0.28 6
18.9 17.1 10
6.4 5.8 10
19500 15000 26 R1
12.4 10.7 15
1.7 1.7
ND ND
10.6 10.1 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.,
,,1'{'-f;,~--
;'/DeldCi,
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
% Rec
Limits
75-125
Qualifiers
Page 78 of 81
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville. NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALIFIERS
Project: CASTLE HAYNE 22-124930
Pace Project No.: 9257362
DEFINITIONS
OF -Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of
the sample aliquot, or moisture content.
ND -Not Detected at or above adjusted reporting limit.
J -Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
S -Surrogate
1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPO values.
LCS(O) -Laboratory Control Sample (Duplicate)
MS(D) -Matrix Spike (Duplicate)
DUP -Sample Duplicate
RPO -Relative Percent Difference
NC -Not Calculable.
Pace Analytical is NE LAP accredited. Contact your Pace PM for the current list of accredited analytes.
U -Indicates the compound was analyzed for, but not detected.
LABORATORIES
PASI-A
PASI-C
PASl-0
Pace Analytical Services -Asheville
Pace Analytical Services -Charlotte
Pace Analytical Services -Ormond Beach
ANALYTE QUALIFIERS
C9 Common Laboratory Contaminant.
10 The internal standard response was outside the laboratory acceptance llmlts confirmed by reanalysis. The results
reported are from the most QC compliant analysis.
IS The internal standard response is below criteria. Results may be biased high.
L 1 Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated
samples may be biased high.
L3 Analyte recovery in the laboratory control sample (LCS) exceeded QC limits. Analyte presence below reporting limits in
associated samples. Results unaffected by high bias.
MO Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.
M3 Matrix spike recovery was outside laboratory control limits due to matrix interferences.
PB Analyte was detected in the method blank. All associated samples had concentrations of at least ten times greater than
the blank or were below the reporting limit.
R1 RPO value was outside control limits.
Date: 12/04/2009 11 :18 AM REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
7.::-'-~·· ldelac;,
Page 79 of 81
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Paco Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704 )875-9092
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: CASTLE HAYNE 22-124930
Pace Project No.: 9257362
Analytical
Lab ID Sample ID ac Batch Method QC Batch Analytical Method Batch
9257362001 HA-1 EPA6270 MSSV/1360 EPA 6270 MSSV/1125
9257362002 HA-2 EPA 6270 MSSV/1360 EPA 6270 MSSV/1125
9257362003 HA-3 EPA 6270 MSSV/1360 EPA6270 MSSV/1125
9257362004 HA-4 EPA6270 MSSV/1360 EPA6270 MSSV/1125
9257362005 HA-5 EPA6270 MSSV/1360 EPA6270 MSSV/1125
9257362006 HA-6 EPA6270 MSSV/1360 EPA 6270 MSSV/1125
9257362007 HA-7 EPA 6270 MSSV/1360 EPA 6270 MSSV/1125
9257362006 HA-8 EPA 6270 MSSV/1360 EPA6270 MSSV/1125
9257362009 HA-9 EPA6270 MSSV/1360 EPA6270 MSSV/1125
9257362010 HA-10 EPA6270 MSSV/1360 EPA6270 MSSV/1125
9257362011 HA-11 EPA 6270 MSSV/1360 EPA 6270 MSSV/1125
9257362012 HA-12 EPA 6270 MSSV/1360 EPA 6270 MSSV/1125
9257362001 HA-1 EPA 3050 MPRP/5365 EPA6010 ICP/4996
9257362002 HA-2 EPA 3050 MPRP/5365 EPA6010 ICP/4996
9257362003 HA-3 EPA 3050 MPRP/5365 EPA 6010 ICP/4996
9257362004 HA-4 EPA 3050 MPRP/5365 EPA6010 ICP/4996
9257362005 HA-5 EPA 3050 MPRP/5365 EPA6010 ICP/4996
9257362006 HA-6 EPA 3050 MPRP/5365 EPA 6010 ICP/4996
9257362001 HA-1 EPA6260 MSV/9016
9257362002 HA-2 EPA6260 MSV/9016
9257362003 HA-3 EPA6260 MSV/9016
9257362004 HA-4 EPA 6260 MSV/9016
9257362007 HA-7 EPA 6260 MSV/9016
9257362005 HA-5 EPA6260 MSV/9017
9257362006 HA-6 EPA6260 MSV/9017
9257362001 HA-1 ASTM 0297 4-67 PMST/2662
9257362002 HA-2 ASTM 0297 4-87 PMST/2682
9257362003 HA-3 ASTM 02974-87 PMST/2882
9257362004 HA-4 ASTM 02974-87 PMST/2862
9257362005 HA-5 ASTM 02974-87 PMST/2882
9257362006 HA-6 ASTM 0297 4-87 PMST/2882
9257362007 HA-7 ASTM 0297 4-87 PMST/2882
9257362006 HA-8 ASTM 0297 4-87 PMST/2882
9257362009 HA-9 ASTM 02974-87 PMST/2882
9257362010 HA-10 ASTM 02974-87 PMST/2662
9257362011 HA-11 ASTM 02974-67 PMST/2662
9257362012 HA-12 ASTM 02974-87 PMST/2662
9257362006 HA-8 EPA6260 MSV/9045
9257362009 HA-9 EPA 6260 MSV/9045
9257362010 HA-10 EPA 8260 MSV/9045
9257362011 HA-11 EPA8260 MSV/9045
9257362012 HA-12 EPA6260 MSV/9045
9257362007 HA-7 EPA3050 MPRP/5396 EPA6010 ICP/5011
9257362006 HA-8 EPA 3050 MPRP/5396 EPA 6010 ICP/5011
9257362009 HA-9 EPA 3050 MPRP/5396 EPA6010 ICP/5011
9257362010 HA-10 EPA 3050 MPRP/5396 EPA 6010 ICP/5011
Date: 12/04/2009' 11: 18 AM REPORT OF LABORATORY ANALYSIS Page 80 of 81
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
,• •coo~ ~QK·~e~~--fine c11
. , Paco Analytical Services, Inc.
2225 Riverside Dr. _
Asheville, NC 28804
[phone]
Paco Analytical Services, Inc .
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704 }875-9092
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: CASTLE HAYNE 22-12493D
Pace Project No.: 9257362
Lab ID Sample ID
9257362011 HA-11
9257362012 HA-12
Date: 12/04/2009 11:18AM
QC Batch Method QC Batch
EPA 3050 MPRP/5396
EPA 3050 MPRP/5396
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
._Q?f.!_<~~"~ ttnelac1,
Analytical
Analytical Method Batch
EPA6010 ICP/5011
EPA 6010 ICP/5011
Page 81 of 81
/~eAnalyticat·
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CHAIN-OF-CUSTODY/ Analytical Request Document
The Chain-of-Custody ls a LEGAL DOCUMENT. All relevant fields must be completed accurately.
Section A Section B Section C Page: J of
Required Client lnfonnatioo: R•qulr9d Project Information: Invoice Information: CompaoyGc.<.. rl'l-ro\Vlos L.l r Raport fa /tM I/ U'.J /\(I,.~ < _ EC<.. 1336371
Copy To: I REGULATORY AGENCY
vllc:>r
e~"1'0..J..~b-~il'-1 "'
rQ/"J. ◄ !_urchase Order No.:
Project Name: r I} c;,.\ ' e_
Requested Due DatefTAT: , . 1.,. .. .,.\(),.__,.\ Projact N,mba<e 'd, '.:I. _ \ d, 4 q :i, i
AddraHI j \II {l,.,_1r, /"J ,trJ t' J\ rt'
P-Ouote l...J
Reference:
Pace Projeci
Manager:
PaceProfile#: ,,;J +()°3-/.,.
r NPDES
r UST
Site Location
STATE:
r GROUND WATER r DRINKING WATER
r RCRA ,;;;,, OTHER
NC
~ :.(;-R,(fUisted Analysls Fllt8red {YIN)
Sec::tlon D
Required Client Information
SAMPLE ID
(A·Z, 0-91,-)
Sample IDs MUST BE UNIQUE
12 't·I./
ADDmONAL COMMENTS
Matrill Coc:IH
MAIBIX I COPE
Drinking Water OW
Water WT
Waste Water \NV\/
Product P
SolVSoBd SL
Oil OL
V.,p, WP
Air AR
Tissue TS
Other OT
ORIGINAL
j 0: ~ s 0 f '/ u .. • ' ~ ! " ~ w Q w
0 ~
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5 b
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5 G-
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COLLECTED PreseNatives
z 0
COMPOSITE COMPOSITE G START ENOJG~ w ~ "' u a: ~ w < z ~ ~ u ~ • w z ~ ~ g w 0 • :r ~ ~ '-' ~a 0 ~ ~ ~ u. ~ C. "' -0"' < 0 C N z (.) ... 16 DATE TIME DATE TIME "' ~ ::, :c :c :c zz
u\11 111'. :it) :f-l\ ~ ll
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.l Ill I)' i:a -:l I' ..\ \ "
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PRINT N•m• of SAMPLER: A-"' .. '"'(\, I C'
SIGNATURE of SAMPLER: / ~ / r "' I.
•important Nota: By signing 1h11 form you are accepting Pa~•• NET 30 day payment terms and egteelng to late charges of 1.5% per month for any~ not paid within 30 daya.
I_/
, .
• DATE
u
DATE Slgood \ (I\ \C) ,._,-jMM/0D/YY), \ I 'I
TIME
z i Clf)cyr?:,VJ 1-,
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(, 7 ,
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SAMPLE CONomONS
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F-ALL-0--020rev.07, 15-May-2007
;:;,,-, .
/ ,,d'ceAnalytical ;-Client Name:W &!roht/t1 5 Project#
C~urier: ~ Ex O UPS O USPS O Client O ymmercial O Pace 0~---
Custody Seal on Cooler/Box Present: 0 yes [Z( no Seals intac!: ~ yes D no
Packing Material: 0 Bubble Wrap ~le Bags · 0 None Oother
Thermometer Used T060 Type -~f Ice· @ Blue _N_o_n_e __
Cooler Temperature· ,"2,,-, 3 Biological Tissue is Frozen: Yes No NIA Date and lnitifri°~/4-7 e / contents:1/ / o· l~ Temp should be above freezing to s·c / Comments: . -Chain of Custody Present: ~es 0No 0NfA 1.
Chain of Custody Filled Out: ~s ·□No □N_!A 2.
Chain of Custody Relinquished: i;a<,, 0No □NIA 3.
Sampler Name & Signature on COC: ~s.,.ONo ON/A 4.
Samples Arrived within Hold Time: E'°fye, 0No 0NtA 5.
Short Hold Time Analysis (<72hr): a,., 0'No □NIA 6.
Rush Turn Around Time Requested: □-~es :~o □NIA 7.
Sufficient Volume: O~e~ 0No □NIA 8. /l,J~1(}0, !WP, J.._r for /.IA/c.,
Correct Containers Used: ~□No □NIA 9. I
'.
-Pace Containers Used: . es 0No-□NIA
Containers Intact: ~s·:·□No □NIA 10.
Filtered volume received for Dissolved tests Ov~s..;,·□No 121'.i/A 11.
Sample Labels match C0C: fiJ1i; '□No □NIA 12. ii o? l.--Includes date/lime/ID/Analysis Matrix: ··5
Al! containers needing preservation have been checked.
@(es . ·□No □NIA 13.
Al! containers needinQ preservation are found to be in ·~ -□No □NIA compliance with EPA.recommendation. -exceptions: VOA, coliform. TOC, O&G. WI-ORO (water) □Yes PNo Initial when completed
Samples checked for dechlorination:· OYes 0No 0NIA 14.
Headspace in VOA Vials ( >6mm): □Yes 0No 0N1A 15.
Trip Blank Present: □Yes □No z 16.
Trip Blank Custody Seals Present □Yes bNo NIA
Pace Trip Blank Loi# (if purchased): NIA
Client Notification/ Resolution: Field Data Required? Y -/ N N/A
Person Contacled: Date/Time: -------------Comments/ Resolution: --------------------------------------
Project Manager Review: Tu)
Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DE HNR Certification Office ( i.e out of hold, incorrect preservative, out of temp. incorrect containers)
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
January 27, 2010
Ms. Amy Conchas
ECS
7211 Ogden Business Park
Suite 201
Wilmington, NC 28411
RE: Project: Castle Hayne 22-12493E
Pace Project No.: 9260782
Dear Ms. Conchas:
Enclosed are the analytical results for sample(s) received by the laboratory on January 06, 2010.
The results relate only to the samples included in this report. Results reported herein conform to the
most current NE LAC standards, where applicable, unless otherwise narrated in the body of the
report.
Inorganic Wet Chemistry and Metals analyses were performed at our Pace Asheville laboratory and
Organic testing was performed at our Pace Huntersville laboratory unless otherwise footnoted. All
Microbiological analyses were performed at the laboratory where the samples were received.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Osu~j---~~I
Ashley Nifong
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Jnc ..
~~1~i~~~
?1 ne1c1.ei;
Page 1 of 31
Project: Castle Hayne 22-12493E
Pace Project No.: 9260782
Charlotte Certification IDs
Connecticut Certification #: PH-0104
Florida/NELAP Certification#: E87627
9800 Kincey Ave. -Ste 100 Huntersville, NC 28078
West Virginia Certification#: 357
Virginia Certification#: 00213
Tennessee Certification#: 04010
South Carolina Drinking Water Cert. #: 990060003
South Carolina Certification#: 990060001
Asheville Certification IDs
Connecticut Certification #: PH-0106
2225 Riverslde Dr. Asheville, NC 28804
Virginia Certification#: 00072
Tennessee Certification#: 2980
South Carolina Certification#: 99030001
South Carolina Bioassay Certification #: 99030002
Pennsylvania Certification#: 68-03578
North Carolina Wastewater Certification#: 40
Pace Analytical Services, Inc.
2225 Riverside Dr.
CERTIFICATIONS
Asheville, NC 28804
[phone]
Pennsylvania Certification #: 68-00784
North Carolina Wastewater Certification#: 12
North Carolina Field Services Certification#: 5342
North Carolina Drinking Water Certification#: 37706
New Jersey Certification#: NC012
Louisiana/LELAP Certification #: 04034
Kentucky UST Certification #: 84
North Carolina Drinking Water Certification#: 37712
North Carolina Bioassay Certification #: 9
New Jersey Certification#: NC011
Massachusetts Certification #: M-NC030
Louisiana/LELAP Certification#: 03095
Florida/NELAP Certification #: E87648
West Virginia Certification#: 356
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 31
Project: Castle Hayne 22-12493E
Pace Project No.: 9260782
Lab ID Sample ID
9260782001 HA13
9260782002 HA14
9260782003 HA15
9260782004 HA16
9260782005 HA17
9260782006 HA18
9260782007 HA19
9260782008 HA20
9260782009 HA21
9260782010 HA22
9260782011 HA23
9260782012 HA24
9260782013 HA25
9260782014 HA26
9260782015 HA27
9260782016 B1
9260782017 B2
9260782018 B3
Pace Analytical Services, Inc.
2225 Riverside Dr.
SAMPLEANALYTE COUNT
Asheville, NC 28804
{828)254-7176
Method Analysts
EPA8270 SH
ASTM D297 4-87 JMM
EPA 8270 SH
ASTM D297 4-87 JMM
EPA8270 SH
ASTM D2974-87 JMM
EPA 8270 SH
ASTM D297 4-87 JMM
EPA8270 SH
ASTM D297 4-87 JMM
EPA 8270 SH
ASTM D297 4-87 JMM
EPA8270 SH
ASTM D297 4-87 JMM
EPA 8270 SH
ASTM D297 4-87 JMM
EPA8270 SH
ASTM D297 4-87 JMM
EPA 8270 SH
ASTM D2974-87 JMM
EPA 8270 SH
ASTM D2974-87 JMM
EPA8270 SH
ASTM D2974-87 JMM
EPA 8270 SH
ASTM 0297 4-87 JMM
EPA8270 SH
ASTM D2974-87 JMM
EPA 8270 SH
ASTM D297 4-87 JMM
EPA6010 EWS
ASTM D2974-87 JMM
EPA6010 EWS
ASTM D297 4-87 JMM
EPA6010 EWS
ASTM D2974-87 JMM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
-· )'f ~""'--?1ne C\;
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Analytes
Reported Laboratory
24 PASI-C
PASI-C
24 PASI-C
PASI-C
24 PASI-C
PASI-C
24 PASI-C
PASI-C
24 PASI-C
PASI-C
24 PASI-C
PASI-C
24 PASI-C
PASI-C
24 PASI-C
PASI-C
24 PASI-C
PASI-C
24 PASI-C
PASI-C
24 PASI-C
PASI-C
24 PASI-C
PASI-C
24 PASI-C
PASI-C
24 PASI-C
PASI-C
24 PASI-C
PASI-C
10 PASI-A
PASI-C
10 PASl·A
PASI-C
10 PASI-A
PASI-C
Page 3 of 31
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace An~lytical Services, Inc.
9800 Kincey Ave. Suite 100 ,
Huntersville, NC 28078
[phone]
Project: Castle Hayne 22-12493E
Pace Project No.: 9260782
Sample: HA13 LablD: 9260782001 Collected: 01/06/1011:00 Received: 01/06/10 16:15 Matrix: Solid
Results reported on a .. dry-weight .. basis
Parameters
8270 MSSV Microwave
Acenaphthene
Acenaphthylene
Anthracene
Benzo{a)anthracene
Benzo(a)pyrene
Benzo{b )ftuoranthene
Benzo{g, h, i )perylene
Benzo{k)ftuoranthene
Chrysene
Dibenz{a,h)anthracene
Fluoranthene
Fluorene
I ndeno(1,2,3-cd)pyrene
1-Methylnaphthalene
2-Methylnaphthalene
Naphthalene
Phenanthrene
Pyrene
Nitrobenzene-d5 (S)
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
Phenol-dB {S)
2-Fluorophenol (S)
2,4,6-Tribromophenol (S)
Percent Moisture
Percent Moisture
Date: 01/27/2010 03:08 PM
Results Units Report Limit OF Prepared
Analytical Method: EPA 8270 Preparation Method: EPA 3546
ND ug/kg 412 01/11/10 09:00
ND ug/kg 412 01/11/10 09:00
ND ug/kg 412 01/11/10 09:00
ND ug/kg 412 01/11/10 09:00
ND ug/kg 412 01/11/10 09:00
ND ug/kg 412 01/11/10 09:00
ND ug/kg 412 01/11/10 09:00
ND ug/kg 412 01/11/10 09:00
ND ug/kg 412 01/11/10 09:00
ND ug/kg 412 01/11/10 09:00
ND ug/kg 412 01/11/10 09:00
ND ug/kg 412 01/11/10 09:00
ND ug/kg 412 01/11/10 09:00
ND ug/kg 412 01/11/10 09:00
ND ug/kg 412 01/11/10 09:00
ND ug/kg 412 01/11/10 09:00
ND ug/kg 412 01/11/10 09:00
ND ug/kg 412 01/11/10 09:00
20 % 30-150 01/11/10 09:00
22 % 46-120 01/11/10 09:00
27 % 38-108 01/11/10 09:00
19 % 35-120 01/11/10 09:00
19 % 24-120 01/11/10 09:00
28 % 44-136 01/11/10 09:00
Analytical Method: ASTM 02974-87
20.0 % 0.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
~Q-?f~-~~~ .. i1nelao,
Analyzed CAS No.
01/21/10 03:41 83-32-9
01/21/10 03:41 208-96-8
01/21/10 03:41 120-12-7
01/21/10 03:41 56-55-3
01/21/10 03:41 50-32-8
01/21/10 03:41 205-99-2
01/21/10 03:41 191-24-2
01/21/10 03:41 207-08-9
01/21/10 03:41 218-01-9
01/21/10 03:41 53-70-3
01/21/10 03:41 206-44-0
01/21/10 03:41 86-73-7
01/21/10 03:41 193-39-5
01/21/10 03:41 90-12-0
01/21/10 03:41 91-57-6
01/21/10 03:41 91-20-3
01/21/10 03:41 85-01-8
01/21/10 03:41 129-00-0
01/21/10 03:41 4165-60-0
01/21/10 03:41 321-60-8
01/21/10 03:41 1718-51-0
01/21/10 03:41 13127-88-3
01/21/10 03:41 367-12-4
01/21/10 03:41 118-79-6
01/08/10 17:27
Quat
so
so
so
so
so
so
Page 4 of 31
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
{828)254-7,176
Paco Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Castle Hayne 22-12493E
Pace Project No.: 9260782
Sample: HA14 LablD: 9260782002 Collected: 01/06/10 11:05 Received: 01/06/10 16:15 Matrix: Solid
Results reported on a "dry-weight" basis
Parameters
8270 MSSV Microwave
Acenaphthene
Acenaphthytene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g, h, i )perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
lndeno(1,2,3-cd)pyrene
1-Methylnaphthalene
2-Methylnaphthalene
Naphthalene
Phenanthrene
PYrene
Nitrobenzene-d5 (S)
2-Fluorobiphenyl (S)
Terphenyl-d1~ (S)
Phenol-d6 (S)
2-Fluorophenol (S)
2,4,6-Tribromophenol (S)
Percent Moisture
Percent Moisture
Date: 01/27/2010 03:08 PM
Results Units Report Limit DF Prepared
Analytical Method: EPA 8270 Preparation Method: EPA 3546
ND ug/kg 399 01/11/10 09:00
ND ug/kg 399 01/11110 09:00
ND ug/kg 399 01111110 09:00
ND ug/kg 399 01111110 09:00
ND ug/kg 399 01111110 09:00
ND ug/kg 399 01111110 09:00
ND ug/kg 399 01111110 09:00
ND ug/kg 399 01111110 09:00
NO ug/kg 399 01111/10 09:00
ND ug/kg 399 01111110 09:00
ND ug/kg 399 01111110 09:00
ND ug/kg 399 01111110 09:00
ND ug/kg 399 01111110 09:00
ND ug/kg 399 01111110 09:00
ND ug/kg 399 01111110 09:00
ND uglkg 399 01111110 09:00
ND ug/kg 399 01/11110 09:00
ND ug/kg 399 01/11110 09:00
23 % 30-150 01111/10 09:00
29 % 46-120 01111110 09:00
28 % 38-108 01111110 09:00
23 % 35-120 01111110 09:00
19 % 24-120 01111110 09:00
31 % 44-136 01111110 09:00
Analytical Me_thod: ASTM 02974-87
17.3 % 0.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
~.-1-f.!·~~~
?1neld.ei;
Analyzed CAS No.
01/21/10 04:07 83-32-9
01121110 04:07 208-96-8
01121110 04:07 120-12-7
01/21110 04:07 56-55-3
01/21110 04:07 50-32-8
01121/10 04:07 205-99-2
01/21/10 04:07 191-24-2
01121110 04:07 207-08-9
01/21110 04:07 218-01-9
01/21110 04:07 53-70-3
01/21110 04:07 206-44-0
01/21110 04:07 86-73-7
01121110 04:07 193-39-5
01121110 04:07 90-12-0
01/21110 04:07 91-57-6
01121110 04:07 91-20-3
01/21/10 04:07 85-01-8
01/21110 04:07 129-00-0
01121110 04:07 4165-60-0
01/21110 04:07 321-60-8
01121110 04:07 1718-51-0
01/21110 04:07 13127-88-3
01/21110 04:07 367-12-4
01/21/10 04:07 118-79-6
01/08/10 17:27
Qual
so
so so
so
so
so
Page 5 of 31
Paco Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
I Paco Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Castle Hayne 22-12493E
Pace Project No.: 9260782
Sample: HA15 LablD: 9260782003 Collected: 01/06/10 11:10 Received: 01/06/10 16:15 Matrix: Solid
Results reported on a "dry-weight" basis
Parameters
8270 MSSV Microwave
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h, i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
lndeno(1,2,3-cd)pyrene
1-Methylnaphthalene
2-Methylnaphthalene
Naphthalene
Phenanthrene
Pyrene
Nitrobenzene-d5 (S)
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
Phenol-ci6 (S)
2-Fluorophenol (S)
2,4,6-Tribromophenot (S)
Percent Moisture
Percent Moisture
Date: 01/27/2010 03:08 PM
Results Units Report Limit DF Prepared
Analytical Method: EPA8270 Preparation Method: EPA 3546
ND ug/kg 432 01/11/10 09:00
ND ug/kg 432 01/11/10 09:00
ND ug/kg 432 01/11/10 09:00
ND ug/kg 432 01/11/10 09:00
ND ug/kg 432 01/11/10 09:00
ND ug/kg 432 01/11/10 09:00
ND u9/1<g 432 01/11/10 09:00
ND ug/kg 432 01/11/10 09:00
ND ug/kg 432 01/11/10 09:00
ND ug/kg 432 01/11/10 09:00
ND ug/kg 432 01/11/10 09:00
ND ug/kg 432 01/11/10 09:00
ND ug/kg 432 01/11/10 09:00
ND ug/kg 432 01/11/10 09:00
ND ug/kg 432 01/11/10 09:00
ND ug/kg 432 01/11/10 09:00
ND ug/kg 432 01/11/10 09:00
ND ug/kg 432 01/11/10 09:00
27 % 30-150 01/11/10 09:00
31 % 46-120 01/11/10 09:00
27 % 38-108 01/11/10 09:00
26 % 35-120 01/11/10 09:00
22 % 24-120 01/11/10 09:00
36 % 44-136 01/11/10 09:00
Analytical Method: ASTM D2974-87
23.6 % 0.10
REPORT OF LABORATORY ANALYSIS
This report sh8II not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
,~?-'-c,t._~,,
,•'/ 1 ,::, ❖-?1□eldC\l
Analyzed CAS No.
01/21/10 04:34 83-32-9
01/21/10 04:34 208-96-8
01/21/10 04:34 120-12-7
01/21/10 04:34 56-55-3
01/21/10 04:34 50-32-8
01/21/10 04:34 205-99-2
01/21/10 04:34 191-24-2
01/21/10 04:34 207-08-9
01/21/10 04:34 218-01-9
01/21/10 04:34 53-70-3
01/21/10 04:34 206-44-0
01/21/10 04:34 86-73-7
01/21/10 04:34 193-39-5
01/21/10 04:34 90-12-0
01/21/10 04:34 91-57-6
01/21/10 04:34 91-20-3
01/21/10 04:34 85-01-8
01/21/10 04:34 129-00-0
01/21/10 04:34 4165-60-0
01/21/10 04:34 321-60-8
01/21/10 04:34 1718-51-0
01/21/10 04:34 13127-88-3
01/21/10 04:34 367-12-4
01/21/10 04:34 118-79-6
01/08/10 17:28
Qual
so
so
so
so
so
so
Page 6 of 31
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Castle Hayne 22-12493E
Pace Project No.: 9260782
Sample: HA16 Lab ID: 9260782004 Collected: 01/06/10 11:15 Received: 01/06/10 16:15 Matrix: Solid
Results reported on a "dry-weight" basis
Parameters
8270 MSSV Microwave
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b )fluoranthene
Benzo(g, h, i )perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
lndeno(1,2,3-cd)pyrene
1-Methylnaphthalene
2-Methylnaphthalene
Naphthalene
Phenanthrene
Pyrene
Nitrobenzene-c:15 (S)
2-Fluorobiphenyl (S)
Terphenyl-c:114 (S)
Phenol-d6 (S)
2-Fluorophenol (S)
2,4,6-Tribromophenol (S)
Percent Moisture
Percent Moisture
Date: 01/27/2010 03:08 PM
Results Units Report Limit DF Prepared
Analytical Method: EPA8270 Preparation Method: EPA 3546
ND ug/kg 413 01/11110 09:00
ND ug/kg 413 01111110 09:00
ND ug/kg 413 01111110 09:00
ND ug/kg 413 01111110 09:00
ND ug/kg 413 01111110 09:00
ND ug/kg 413 01111110 09:00
ND ug/kg 413 01111110 09:00
ND ug/kg 413 01111110 09:00
ND ug/kg 413 01/11/10 09:00
ND ug/kg 413 01111110 09:00
ND uglkg 413 01111110 09:00
ND ug/kg 413 01/11/10 09:00
ND ug/kg 413 01111/10 09:00
ND ug/kg 413 01111110 09:00
ND ug/kg 413 01111110 09:00
ND ug/kg 413 01/11110 09:00
ND ug/kg 413 01111110 09:00
ND ug/kg 413 01111110 09:00
25 % 30-150 01111110 09:00
27 % 46-120 01111110 09:00
24 % 38-108 01/11/10 09:00
21 % 35-120 01111110 09:00
22 % 24-120 01/11110 09:00
28 % 44-136 01/11/10 09:00
Analytical Method: ASTM D2974-87
20.0 % 0.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services. Inc ..
Analyzed GAS No.
01121110 05:01 83-32-9
01121110 05:01 208-96-8
01121110 05:01 120-12-7
01121/10 05:01 56-55-3
01121/10 05:01 50-32-8
01121110 05:01 205-99-2
01121110 05:01 191-24-2
01121110 05:01 207-08-9
01/21/10 05:01 218-01-9
01121110 05:01 53-70-3
01121110 05:01 206-44-0
01121110 05:01 86-73-7
01121110 05:01 193-39-5
01121110 05:01 90-12-0
01/21110 05:01 91-57-6
01121110 05:01 91-20-3
01/21110 05:01 85-01-8
01121110 05:01 129-00-0
01121110 05:01 4165-60-0
01121110 05:01 321-60-8
01121110 05:01 1718-51-0
01121110 05:01 13127-88-3
01/21/10 05:01 367-12-4
01121110 05:01 118-79-6
01/08/10 17:28
Qua!
so
so
so
so
so
so
Page 7 of 31
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704 )875-9092
Project: Castle Hayne 22-12493E
Pace Project No.: 9260782
Sample: HA17 LablO: 9260782005 Collected: 01/06/10 11:20 Received: 01/06/10 16:15 Matrix: Solid
Results reported on a "dry-weight" basis
Parameters
8270 MSSV Microwave
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)ftuoranthene
Benzo(g, h, i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
lndeno(1,2,3-cd)pyrene
1-Methylnaphthalene
2-Methylnaphthalene
Naphthalene
Phenanthrene
Pyrene
Nitrobenzene-dS (S)
2-Fluorobiphenyl ($)
Te,phenyl-d14 (S)
Phenol-d6 (S)
2-Fluorophenol (S)
2,4,6-Tribromophenol (S)
Percent Moisture
Percent Moisture
Date: 01/27/2010 03:08 PM
Results Units Report Limit OF Prepared
Analytical Method: EPA 8270 Preparation Method: EPA 3546
ND ug/kg 416 01111/10 09:00
ND u9/1<9 416 01111110 09:00
ND ug/kg 416 01/11110 09:00
ND ug/kg 416 01111110 09:00
ND ug/kg 416 01111110 09:00
ND u9/1<9 416 01111110 09:00
ND ug/kg 416 01111110 09:00
ND ug/kg 416 01111110 09:00
ND u911<9 416 01111110 09:00
ND ug/kg 416 01111110 09:00
ND ug/kg 416 01111/10 09:00
ND ug/kg 416 01111110 09:00
ND ug/kg 416 01111110 09:00
ND ug/kg 416 01111110 09:00
ND ug/kg 416 01/11/10 09:00
ND ug/kg 416 01111110 09:00
ND ug/kg 416 01111110 09:00
ND u9lk9 416 01111110 09:00
23 % 30-150 01111110 09:00
26 % 46-120 01/11/10 09:00
25 % 38-108 01111110 09:00
22 % 35-120 01111110 09:00
20 % 24-120 01111110 09:00
28 % 44-136 01111110 09:00
Analytical Method: ASTM D2974-87
20.8 % 0.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
~~?ri~~~ ?11Jekl.Cl,
Analyzed CAS No.
01121110 05:28 83-32-9
01121110 05:28 208-96-8
01121110 05:28 120-12-7
01/21/10 05:28 56-55-3
01121110 05:28 50-32-8
01/21110 05:28 205-99-2
01/21110 05:28 191-24-2
01121110 05:28 207-08-9
01121110 05:28 218-01-9
01121110 05:28 53-70-3
01/21110 05:28 206--44-0
01121110 05:28 86-73-7
01121110 05:28 193-39-5
01/21/10 05:28 90-12-0
01/21/10 05:28 91-57-6
01121110 05:28 91-20-3
01121110 05:28 85-01-8
01121110 05:28 129-00-0
01/21110 05:28 4165-60-0
01/21/10 05:28 321-60-8
01121110 05:28 1718-51-0
01/21110 05:28 13127-88-3
01121110 05:28 367-12-4
01/21/10 05:28 118-79-6
01108110 17:28
Qual
so
so
so
so
so
so
Page 8 of 31
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project:
Pace Project No.:
Castle Hayne 22-12493E
9260782
Sample: HA18 LablD: 9260782006 Collected: 01/06/10 11:25 Received: 01/06/10 16:15 Matrix: Solid
Results reported on a "dry-weight" basis
Parameters
8270 MSSV Microwave
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g, h, i )pe rylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
lndeno(1,2,3-cd)pyrene
1-Methylnaphthalene
2-Methylnaphthalene
Naphthalene
Phenanthrene
Pyrene
Nitrobenzene-dS (S)
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
Pheno1-d6 (S)
2-Fluorophenol (S)
2,4,6-Tribromophenol (S)
Percent Moisture
Percent Moisture ·
Date: 01/27/2010 03:08 PM
Results Units Report Limit DF Prepared
Analytical Method: EPA 8270 Preparation Method: EPA 3546
ND ug/kg 456 01/11/10 09:00
ND ug/kg 456 01/11/10 09:00
ND ug/kg 456 01/11/10 09:00
ND ug/kg 456 01/11/10 09:00
ND ug/kg 456 01/11/10 09:00
ND ug/kg 456 01/11/10 09:00
ND ug/kg 456 01/11/10 09:00
ND ug/kg 456 01/11/10 09:00
ND ug/kg 456 01/11/10 09:00
ND ug/kg 456 01/11/10 09:00
ND ug/kg 456 01/11/10 09:00
ND ug/kg 456 01/11/10 09:00
ND ug/kg 456 01/11/10 09:00
ND ug/kg 456 01/11/10 09:00
ND ug/kg 456 01/11/10 09:00
ND ug/kg 456 01/11/10 09:00
ND ug/kg 456 01/11/10 09:00
ND ug/kg 456 01/11/10 09:00
0% 30-150 01/11/10 09:00
0% 46-120 01/11/10 09:00
0% 38-108 01/11/10 09:00
0% 35-120 01/11/10 09:00
0% 24-120 01/11/10 09:00
0% 44-136 01/11/10 09:00
Analytical Method: ASTM D2974-87
27.6 % 0.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
. {?'f.!rs~~~ ..
i1□ek1C\\
Analyzed CAS No.
01/21/10 05:54 83-32-9
01/21/10 05:54 208-96-8
01/21/10 05:54 120-12-7
01/21/10 05:54 56-55-3
01/21/10 05:54 50-32-8
01/21/10 05:54 205-99-2
01/21/10 05:54 191-24-2
01/21/10 05:54 207-08-9
01/21/10 05:54 218-01-9
01/21/10 05:54 53-70-3
01/21/10 05:54 206-44-0
01/21/10 05:54 86-73-7
01/21/10 05:54 193-39-5
01/21/10 05:54 90-12-0
01/21/10 05:54 91-57-6
01/21/10 05:54 91-20-3
01/21/10 05:54 85-01-8
01/21/10 05:54 129-00-0
01/21/10 05:54 4165-60-0
01/21/10 05:54 321-60-8
01/21/10 05:54 1718-51-0
01/21/10 05:54 13127-88-3
01/21/10 05:54 367-12-4
01/21/10 05:54 118-79-6
01/08/10 17:28
Qual
1g
1g
1g
1g
1g
1g
Page 9 of 31
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704 }875-9092
Project: Castle Hayne 22-12493E
Pace Project No.: 9260782
Sample: HA19 LablD: 9260782007 Collected: 01/06/10 11:30 Received: 01/06/10 16:15 Matrix: Solid
Results reported on a "dry-weight" basis
Parameters
8270 MSSV Microwave
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b )fluoranthene
Benzo(g, h, i )perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
lr1deno(1,2,3-cd)pyrene
1-Methylnaphthalene
2-Methylnaphthalene
Naphthalene
Phenanthrene
Pyrene
Nitrobenzene-d5 (S)
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
Phenol-dB (S)
2-Fluorophenol (S)
2,4,6-Tribromophenol (S)
Percent Moisture
Percent Moisture
Date: 01/27/2010 03:08 PM
Results Units Report Limit OF Prepared
Analytical Method: EPA 8270 Preparation Method: EPA 3546
ND ug/kg 405 01/11/10 09:00
ND ug/kg 405 01/11/10 09:00
ND ug/l<.g 405 01/11/10 09:00
ND ug/l<.g 405 01/11/10 09:00
ND ug/kg 405 01/11/10 09:00
ND ug/kg 405 01/11/10 09:00
ND ug/kg 405 01/11/10 09:00
ND ug/kg 405 01/11/10 09:00
ND ug/kg 405 01/11/10 09:00
ND ug/kg 405 01/11/10 09:00
ND ug/kg 405 01/11/10 09:00
ND ug/kg 405 01/11/10 09:00
ND ug/kg 405 01/11/10 09:00
ND ug/kg 405 01/11/10 09:00
ND ug/kg 405 01/11/10 09:00
ND ug/kg 405 01/11/10 09:00
ND ug/kg 405 01/11/10 09:00
ND ug/kg 405 01/11/10 09:00
19 % 30-150 01/11/10 09:00
21 % 46-120 01/11/10 09:00
21 % 38-108 01/11/10 09:00
17 % 35-120 01/11/10 09:00
16 % 24-120 01/11/10 09:00
24 % 44-136 01/11/10 09:00
Analytical Method: ASTM D2974-67
18.5 % 0.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of PaceAnalytica! Services. Inc,.
~~F\.~~ ?loelaci1
Analyzed CAS No. Qual
01/21/10 06:21 83-32-9
01/21/10 06:21 208-96-8
01/21/10 06:21 120-12-7
01/21/10 06:21 56-55-3
01/21/10 06:21 50-32-8
01/21/10 06:21 205-99-2
01/21/10 06:21 191-24-2
01/21/10 06:21 207-08-9
01/21/10 06:21 218-01-9
01/21/10 06:21 53-70-3
01/21/10 06:21 206-44-0
01/21/10 06:21 86-73-7
01/21/10 06:21 193-39-5
01/21/10 06:21 90-12-0
01/21/10 06:21 91-57-6
01/21/10 06:21 91-20-3
01/21/10 06:21 85-01-8
01/21/10 06:21 129-00-0
01/21/10 06:21 4165-60-0 so
01/21/10 06:21 321-60-8 so
01/21/10 06:21 1716-51-0 so
01/21/10 06:21 13127-88-3 so
01/21/10 06:21 367-12-4 so
01/21/10 06:21 118-79-6 so
01/08/10 17:28
Page 10 of 31
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Castle Hayne 22-12493E
Pace Project No.: 9260782
Sample: HA20 LablD: 9260782008 Collected: 01/06/10 11:35 Received: 01/06/10 16:15 Matrix: Solid
Results reported on a "dry-weight" basis
Parameters
8270 MSSV Microwave
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b )fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
lndeno( 1,2,3-cd)pyrene
1-Methylnaphthalene
2-Methylnaphthalene
Naphthalene
Phenanthrene
Pyrene
Nitrobenzene-dS (S)
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
Phenol-d6 (S)
2-Fluorophenol (S)
2,4,6-Tribromophenol (S)
Percent Moisture
Percent Moisture
Date: 01/27/2010 03:08 PM
Results Units Report Limit DF Prepared
Analytical Method: EPA 8270 Preparation Method: EPA 3546
ND ug/kg 415 01/11/10 09:00
ND ug/kg 415 01/11/10 09:00
ND ug/kg 415 01/11/10 09:00
670 ug/kg 415 01/11/10 09:00
699 ug/kg 415 01/11/10 09:00
1020 ug/kg 415 01/11/10 09:00
ND ug/kg 415 01/11/10 09:00
429 ug/kg 415 01/11/10 09:00
789 ug/kg 415 01/11/10 09:00
ND ug/kg 415 01/11/10 09:00
1360 ug/kg 415 01/11/10 09:00
ND ug/kg 415 01/11/10 09:00
ND ug/kg 415 01/11/10 09:00
ND ug/kg 415 01/11/10 09:00
ND ug/kg 415 01/11/10 09:00
ND ug/kg 415 01/11/10 09:00
794 ug/kg 415 01/11/10 09:00
1230 ug/kg 415 01/11/10 09:00
23 % 30-150 01/11/10 09:00
27 % 46-120 01/11/10 09:00
26 % 38-108 01/11/10 09:00
20 % 35-120 01/11/10 09:00
19 % 24-120 01/11/10 09:00
29 % 44-136 01/11/10 09:00
Analytical Method: ASTM D297 4-87
20.5 % 0.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
'" '°"o• .. ~1½:~~ .... trn=o;
Analyzed CAS No.
01/21/10 06:48 83-32-9
01/21/10 06:48 208-96-8
01/21/10 06:48 120-12-7
01/21/10 06:48 56-55-3
01/21/10 06:48 50-32-8
01/21/10 06:48 205-99-2
01/21/10 06:48 191-24-2
01/21/10 06:48 207-08-9
01/21/10 06:48 218-01-9
01/21/10 06:48 53-70-3
01/21/10 06:48 206-44-0
01/21/10 06:48 86-73-7
01/21/10 06:48 193-39-5
01/21/10 06:48 90-12-0
01/21/10 06:48 91-57-6
01/21/10 06:48 91-20-3
01/21/10 06:48 85-01-8
01/21/10 06:48 129-00-0
01/21/10 06:48 4165-60-0
01/21/10 06:48 321-60-8
01/21/10 06:48 1718-51-0
01/21/10 06:48 13127-88-3
01/21/10 06:48 367-12-4
01/21/10 06:48 118-79-6
01/08/10 17:28
Qual
so
so
so
so
so
so
Page 11 of 31
Paco Analytical Sorvicos, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Castle Hayne 22-12493E
Pace Project No.: 9260782
Sample: HA21 LablD: 9260782009 Collected: 01/06/10 11:40 Received: 01/06/10 16:15 Matrix: Solid
Results reported on a "dry-weight" basis
Parameters
8270 MSSV Microwave
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b )fluoranthene
Benzo(g,h, i)perylene
Benzo(k)fluoranthene
Chrysene
D ibenz( a, h )a nth race ne
Fluoranthene
Fluorene
lndeno(1,2,3-cd)pyrene
1-Methylnaphthalene
2-Methylnaphthalene
Naphthalene
Phenanthrene
Pyrene
Nitrobenzene-dS (S)
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
Phenol-dB (S)
2-Fluorophenol (S)
2,4,6-Tribromophenol (S)
Percent Moisture
Percent Moisture
Date: 01/27/2010 03:08 PM
Results Units Report Limit OF Prepared
Analytical Method: EPA8270 Preparation Method: EPA 3546
ND ug/kg 404 01/11/10 09:00
ND ug/kg 404 01/11/10 09:00
ND ug/kg 404 01/11/10 09:00
ND ug/kg 404 01/11/10 09:00
ND ug/kg 404 01/11/10 09:00
ND ug/kg 404 01/11/10 09:00
ND ug/kg 404 01/11/10 09:00
ND ug/kg 404 01/11/10 09:00
ND ug/kg 404 01/11/10 09:00
ND ug/kg 404 01/11/10 09:00
ND ug/kg 404 01/11/10 09:00
ND ug/kg 404 01/11/10 09:00
ND ug/kg 404 01/11/10 09:00
ND ug/kg 404 01/11/10 09:00
ND ug/kg 404 01/11/10 09:00
ND ug/kg 404 01/11/10 09:00
ND ug/kg 404 01/11/10 09:00
ND ug/kg 404 01/11/10 09:00
27 % 30-150 01/11/10 09:00
28 % 46-120 01/11/10 09:00
28 % 38-108 01/11/10 09:00
24 % 35-120 01/11/10 09:00
25 % 24-120 01/11/10 09:00
33 % 44-136 01/11/10 09:00
Analytical Method: ASTM 0297 4-87
18.3 % 0.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
~«-~~~~ 11nelact,
Analyzed CAS No. Qua!
01/21/10 07:14 83-32-9
01/21/10 07:14 208-96-8
01/21/10 07:14 120-12-7
01/21/10 07:14 56-55-3
01/21/10 07:14 50-32-8
01/21/10 07:14 205-99-2
01/21/10 07:14 191-24-2
01/21/10 07:14 207-08-9
01/21/10 07:14 218-01-9
01/21/10 07:14 53-70-3
01/21/10 07:14 206-44-0
01/21/10 07:14 86-73-7
01/21/10 07:14 193-39-5
01/21/10 07:14 90-12-0
01/21/10 07:14 91-57-6
01/21/10 07:14 91-20-3
01/21/10 07:14 85-01-8
01/21/10 07:14 129-00-0
01/21/10 07:14 4165-60-0 so
01/21/10 07:14 321-60-8 so
01/21/10 07:14 1718-51-0 so
01/21/10 07:14 13127-88-3 so
01/21/10 07:14 367-12-4
01/21/10 07:14 118-79-6 so
01/08/10 17:28
Page 12 of 31
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, lnc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Castle Hayne 22-12493E
Pace Project No.: 9260782
Sam pie: HA22 LablD: 9260782010 Collected: 01/06/10 11:45 Received: 01/06/10 16:15 Matrix: Solid
Results reported on a "dry-weight" basis
Parameters
8270 MSSV Microwave
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g, h, i )pe rylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a, h )anthracene
Ftuoranthene
Fluorene
lndeno(1,2,3-cd)pyrene
1-Methylnaphthalene
2-Methylnaphthalene
Naphthalene
Phenanthrene
Pyrene
Nitrobenzene-d5 (S)
2-Fluorobiphenyl (S)
Terphenyl-d14 ($)
Phenol-<l6 (S)
2-Fluorophenol (S)
2,4,6-Tribromophenol (S)
Percent Moisture
Percent Moisture
Date: 01/27/2010 03:08 PM
Results Units Report Limit OF Prepared
Analytical Method: EPA 8270 Preparation Method: EPA 3546
ND ug/kg 397 01/11/10 09:00
ND ug/kg 397 01/11/10 09:00
ND ug/kg 397 01/11/10 09:00
ND ug/kg 397 01/11/10 09:00
ND ug/kg 397 01/11/10 09:00
ND ug/kg 397 01/11/10 09:00
ND ug/kg 397 01/11/10 09:00
ND ug/kg 397 01/11/10 09:00
ND ug/kg 397 01/11/10 09:00
ND ug/kg 397 01/11/10 09:00
ND ug/kg 397 01/11/10 09:00
ND ug/kg 397 01/11/10 09:00
ND ug/kg 397 01/11/10 09:00
ND ug/kg 397 01/11/10 09:00
ND ug/kg 397 01/11/10 09:00
ND ug/kg 397 01/11/10 09:00
ND ug/kg 397 01/11/10 09:00
ND ug/kg 397 01/11/10 09:00
26 % 30-150 01/11/10 09:00
28 % 46-120 01/11/10 09:00
28 % 36-106 01/11/10 09:00
24 % 35-120 01/11/10 09:00
24 % 24-120 01/11/10 09:00
33 % 44-136 01/11/10 09:00
Analytical Method: ASTM D2974-87
17.0 % 0.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
. {?f,!·~~~~ m1e1c1e,;
AnalyzE!d CAS No. Qual
01/21/10 07:41 63-32-9
01/21/10 07:41 206-96-6
01/21/10 07:41 120-12-7
01/21/10 07:41 56-55-3
01/21/10 07:41 50-32-6
01/21/10 07:41 205-99-2
01/21/10 07:41 191-24-2
01/21/10 07:41 207-06-9
01/21/10 07:41 216-01-9
01/21/10 07:41 53-70-3
01/21/10 07:41 206-44-0
01/21/10 07:41 66-73-7
01/21/10 07:41 193-39-5
01/21/10 07:41 90-12-0
01/21/10 07:41 91-57-6
01/21/10 07:41 91-20-3
01/21/10 07:41 65-01-6
01/21/10 07:41 129-00-0
01/21/10 07:41 4165-60-0 so
01/21/10 07:41 321-60-6 so
01/21/10 07:41 1716-51-0 so
01/21/10 07:41 13127-66-3 so
01/21/10 07:41 367-12-4
01/21/10 07:41 116-79-6 so
01/06/10 17:29
Page 13 of31
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Castle Hayne 22-12493E
Pace Project No.: 9260782
Sample: HA23 LablD: 9260782011 Collected: 01/06/10 11:50 Received: 01/06/10 16:15 Matrix: Solid
Results rep~rted on a "dry-weight" basis
Parameters
8270 MSSV Microwave
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b )fluoranthene
Benzo(g, h, i )perylene
Benzo{k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
lndeno( 1,2,3-cd)pyrene
1-Methylnaphthalene
2-Methylnaphthalene
Naphthalene
Phenanthrene
Pyrene
Nitrobenzene-d5 (S)
2-Fluorobiphenyl {S)
Terphenyl-d14 {S)
Phenol-dB (S)
2-Fluorophenol (S)
2,4,6-Tribromophenol (S)
Percent Moisture
Percent Moisture
Date: 01/27/2010 03:08 PM
Results Units Report Limit DF Prepared
Analytical Method: EPA 8270 Preparation Method: EPA 3546
ND ug/kg 387 01/14/10 10:30
ND ug/kg 387 01/14/10 10:30
ND ug/kg 387 01/14/10 10:30
ND ug/kg 387 01/14/10 10:30
ND ug/kg 387 01/14/10 10:30
ND ug/kg 387 01/14/10 10:30
ND ug/kg 387 01/14/10 10:30
ND ug/kg 387 01/14/10 10:30
ND ug/kg 387 01/14/10 10:30
ND ug/kg 387 01/14/10 10:30
ND ug/kg 387 01/14/10 10:30
ND ug/kg 387 01/14/10 10:30
ND ug/kg 387 01/14/10 10:30
ND ug/kg 387 01/14/10 10:30
ND ug/kg 387 01/14/10 10:30
ND ug/kg 387 01/14/10 10:30
ND ug/kg 387 01/14/10 10:30
ND ug/kg 387 01/14/10 10:30
26 % 30-150 01/14/10 10:30
30 % 46-120 01/14/10 10:30
37 % 38-108 01/14/10 10:30
27 % 35-120 01/14/10 10:30
22 % 24-120 01/14/10 10:30
47 % 44-136 01/14/10 10:30
Analytical Method: ASTM 02974-87
14.7 % 0.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
Analyzed CAS No. Qual
01/19/10 07:50 83-32-9
01/19/10 07:50 208-96-8
01/19/10 07:50 120-12-7
01/19/10 07:50 56-55-3
01/19/10 07:50 50-32-8
01/19/10 07:50 205-99-2
01/19/10 07:50 191-24-2
01/19/10 07:50 207-08-9
01/19/10 07:50 218-01-9
01/19/10 07:50 53-70-3
01/19/10 07:50 206-44-0
01/19/10 07:50 86-73-7
01/19/10 07:50 193-39-5
01/19/10 07:50 90-12-0
01/19/10 07:50 91-57-6
01/19/10 07:50 91-20-3
01/19/10 07:50 85-01-8
01/19/10 07:50 129-00-0
01/19/10 07:50 4165-60-0 S1
01/19/10 07:50 321-60-8 S1
01/19/10 07:50 1718-51-0 S1
01/19/10 07:50 13127-88-3 S1
01/19/10 07:50 367-12-4 S1
01/19/10 07:50 118-79-6
01/08/10 17:29
Page 14 of 31
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project:
Pace Project No.:
Castle Hayne 22-12493E
9260782
Sample: HA24 LablD: 9260782012 Collected: 01/06/10 11:55 Received: 01/06/10 16:15 Matrix: Solid
Results reported on a "dry-weight" basis
Parameters
8270 MSSV Microwave
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b )fluoranthene
Benzo(g, h, i)pery lene
Benzo(k)fluoranthene.
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
lndeno(1,2,3-cd)pyrene
1-Methylnaphthalene
2-Methylnaphthalene
Naphthalene
Phenanthrene
Pyrene
Nitrobenzene-d5 (S)
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
Phenol-dB (S)
2-Fluorophenol (S)
2,4,6-Tribromophenol (S)
Percent Moisture
Percent Moisture
Date: 01/27/2010 03:08 PM
Results Units Report Limit OF Prepared
Analytical Method: EPA8270 Preparation Method: EPA 3546
ND ug/kg 424 01/14/10 10:30
, ND ug/kg 424 01/14/10 10:30
ND ug/kg 424 01/14/10 10:30
ND ug/kg 424 01/14/10 10:30
ND ug/kg 424 01/14/10 10:30
ND ug/kg 424 01/14/10 10:30
ND ug/kg 424 01/14/10 10:30
ND ug/kg 424 01/14/10 10:30
ND ug/kg 424 01/14/10 10:30
ND ug/kg 424 01/14/10 10:30
ND ug/kg 424 01/14/10 10:30
ND ug/kg 424 01/14/10 10:30
ND ug/kg 424 01/14/10 10:30
ND ug/kg 424 01/14/10 10:30
ND ug/kg 424 01/14/10 10:30
ND ug/kg 424 01/14/10 10:30
ND ug/kg 424 01/14/10 10:30
ND ug/kg 424 01/14/10 10:30
47 % 30-150 01/14/10 10:30
49 % 46-120 01/14/10 10:30
43 % 38-108 01/14/10 10:30
47 % 35-120 01/14/10 10:30
41 % 24-120 01/14/10 10:30
54 % 44-136 01/14/10 10:30
Analytical Method: ASTM D2974-67
22.2 % 0, 10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.\_
iPF'~~~ i,nelaci;
Analyzed CAS No. Qual
01/19/10 08:17 83-32-9
01/19/10 08:17 208-96-8
01/19/10 08:17 120-12-7
01/19/10 08:17 56-55-3
01/19/10 08:17 50-32-8
01/19/10 08:17 205-99-2
01/19/10 08:17 191-24-2
01/19/10 08:17 207-08-9
01/19/10 08:17 218-01-9
01/19/10 08:17 53-70-3
01/19/10 08:17 206-44-0
01/19/10 08:17 86-73-7
01/19/10 08:17 193-39-5
01/19/10 08:17 90-12-0
01/19/10 08:17 91-57-6
01/19/10 08:17 91-20-3
01/19/10 08:17 85-01-8
01/19/10 08:17 129-00-0
01/19/10 08:17 4165-60-0
01/19/10 08:17 321-60-8
01/19/10 08:17 1716-51-0
01/19/10 08:17 13127-88-3
01/19/10 08:17 367-12-4
01/19/10 06:17 118-79-6
01/08/10 17:29
Page 15 of 31
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Castle Hayne 22-12493E
Pace Project No.: 9260782
Sample: HA25 LablD: 9260782013 Collected: 01/06/10 12:00 Received: 01/06/10 16:15 Matrix: Solid
Results reported on a "dry-weight" basis
Parameters
8270 MSSV Microwave
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b )fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
lndeno(1,2,3-cd)pyrene
1-Methylnaphthalene
2-Methylnaphthalene
Naphthalene
Phenanthrene
Pyrene
Nitrobenzene-d5 (S)
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
Phenol-d6 (S)
2-Fluorophenol (S)
2,4,6-Tribromophenol (S)
Percent Moisture
Percent Moisture
Date: 01/27/2010 03:08 PM
Results Units Report Limit DF Prepared
Analytical Method: EPA 8270 Preparation Method: EPA 3546
ND ug/kg 400 01/14/10 10:30
ND ug/kg 400 01/14/10 10:30
ND ug/kg 400 01/14/10 10:30
ND ug/kg 400 01/14/10 10:30
ND ug/kg 400 01/14/10 10:30
ND u9/kg 400 01/14/10 10:30
ND ug/kg 400 01/14/10 10:30
ND ug/kg 400 01/14/10 10:30
ND ug/kg 400 01/14/10 10:30
ND ug/kg 400 01/14/10 10:30
ND ug/kg 400 01/14/10 10:30
ND ug/kg 400 01/14/10 10:30
ND ug/kg 400 01/14/10 10:30
ND ug/kg 400 01/14/10 10:30
ND ug/kg 400 01/14/10 10:30
ND ug/kg 400 01/14/10 10:30
ND ug/kg 400 01/14/10 10:30
ND ug·/kg 400 01/14/10 10:30
40 % 30-150 01/14/10 10:30
45 % 46-120 01/14/10 10:30
37 % 38-108 01/14/10 10:30
40 % 35-120 01/14/10 10:30
33 % 24-120 01/14/10 10:30
51 % 44-136 01/14/10 10:30
Analytical Method: ASTM D2974-87
17.4 % 0.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
~g::.:~~ •
..:,1/l I~~ ..... 11neldC1;
Analyzed GAS No. Qual
01/19/10 08:43 83-32-9
01/19/10 08:43 208-96-8
01/19/10 08:43 120-12-7
01/19/10 08:43 56-55-3
01/19/10 08:43 50-32-8
01/19/10 08:43 205-99-2
01/19/10 08:43 191-24-2
01/19/10 08:43 207-08-9
01/19/10 08:43 218-01-9
01/19/10 08:43 53-70-3
01/19/10 08:43 206-44-0
01/19/10 08:43 86-73-7
01/19/10 08:43 193-39-5
01/19/10 08:43 90-12-0
01/19/10 08:43 91-57-6
01/19/10 08:43 91-20-3
01/19/10 08:43 85-01-8
01/19/10 08:43 129-00-0
01/19/10 08:43 4165-60-0
01/19/10 08:43 321-60-8 S1
01/19/10 08:43 1718-51-0 S1
01/19/10 08:43 13127-88-3
01/19/10 08:43 367-12-4
01/19/10 08:43 118-79-6
01/08/10 17:40
Page 16 of 31
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Paco Analytical Sorvices, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704}875-9092
Project: · Castle Hayne 22-12493E
Pace Project No.: 9260782
Sample: HA26 LablD: 9260782014 Collected: 01/06/10 12:05 Received: 01/06/10 16:15 Matrix: Solid
Results reporled on a "dry-weight" basis
Parameters
8270 MSSV Microwave
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b )fluoranthene
Benzo(g, h, i)pery lene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
lndeno(1,2,3-cd)pyrene
1-Methylnaphthalene
2-Methylnaphthalene
Naphthalene
Phenanthrene
Pyrene
Nitrobenzene6'15 {S)
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
Phenol-d6 (S)
2-Fluorophenol (S)
2.4.6-Tribromophenol (S)
Percent Moisture
Percent Moisture
Date: 01/27/2010 03:08 PM
Results Units Report Limit DF Prepared
Analytical Method: EPA8270 Preparation Method: EPA 3546
ND ug/kg 400 01/14/10 10:30
ND ug/kg 400 01/14/10 10:30
ND ug/kg 400 01/14/10 10:30
ND ug/kg 400 01/14/10 10:30
ND ug/kg 400 01/14/10 10:30
ND ug/kg 400 01/14/10 10:30
ND ug/kg 400 01/14/10 10:30
ND ug/kg 400 01/14/10 10:30
ND ug/kg 400 01/14/10 10:30
ND ug/kg 400 01/14/10 10:30
ND ug/kg 400 01/14/10 10:30
ND ug/kg 400 01/14/10 10:30
ND ug/kg 400 01/14/10 10:30
ND ug/kg 400 01/14/10 10:30
ND ug/kg 400 01/14/10 10:30
ND ug/kg 400 01/14/10 10:30
ND ug/kg 400 01/14/10 10:30
ND ug/kg 400 01/14/10 10:30
49 % 30-150 01/14/10 10:30
54 % 46-120 01/14/10 10:30
47 % 38-108 01/14/10 10:30
48 % 35-120 01/14/10 10:30
41 % 24-120 01/14/10 10:30
59 % 44-136 01/14/10 10:30
Analytical Method: ASTM D2974-87
17.6 % 0.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced. except in full,
without the written consent of Pace Analytical Services, Inc ..
Analyzed GAS No. Oual
01/19/10 09:10 83-32-9
01/19/10 09:10 208-96-8
01/19/10 09:10 120-12-7
01/19/10 09:10 56-55-3
01/19/10 09:10 50-32-8
01/19/10 09:10 205-99-2
01/19/10 09:10 191-24-2
01/19/10 09:10 207-08-9
01/19/10 09:10 218-01-9
01/19/10 09:10 53-70-3
01/19/10 09:10 206-44-0
01/19/10 09:10 86-73-7
01/19/10 09:10 193-39-5
01/19/10 09:10 90-12-0
01/19/10 09:10 91-57-6
01/19/10 09:10 91-20-3
01/19/10 09:10 85-01-8
01/19/10 09:10 129-00-0
01/19/10 09:10 4165-60-0
01/19/10 09:10 321-60-8
01/19/10 09:10 1718-51-0
01/19/10 09:10 13127-88-3
01/19/10 09:10 367-12-4
01/19/10 09:10 118-79-6
01/08/10 17:41
Page 17 of 31
Pace Analytical Services, Inc.
2225 Riverside Or.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Castle Hayne 22-12493E
Pace Project No.: 9260782
Sample: HA27 LablD: 9260782015 Collected: 01/06/10 12:10 Received: 01/06/10 16:15 Matrix: Solid
Results reported on a "dry-weight" basis
Parameters"
8270 MSSV Microwave
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo{g, h,i)perylene
Benzo{k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
lndeno{1,2,3-cd)pyrene
1-Methylnaphthalene
2-Methylnaphthalene
Naphthalene
Phenanthrene
Pyrene
Nitrobenzene-d5 (S)
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
Phenol-dB {S)
2-Fluorophenol (S)
2,4,6-Tribromophenol (S)
Percent Moisture
Percent Moisture
Date: 01/27/2010 03:08 PM
Results Units Report Limit OF Prepared
Analytical Method: EPA 8270 Preparation Method: EPA 3546
ND ug/kg 438 01/14/10 10:30
ND u9/\(9 438 01/14/10 10:30
ND ug/kg 438 01/14/10 10:30
ND ug/kg 438 01/14/10 10:30
ND ug/kg 438 01/14/10 10:30
ND ug/kg 438 01/14/10 10:30
ND ug/kg 438 01/14/10 10:30
ND ug/kg 438 01/14/10 10:30
ND ug/kg 438 01/14/10 10:30
ND ug/kg 438 01/14/10 10:30
ND u9/\(9 438 01/14/10 10:30
ND ug/kg 438 01/14/10 10:30
ND u9/k9 438 01/14/10 10:30
ND u9/\(9 438 01/14/10 10:30
ND ug/kg 438 01/14/10 10:30
ND ug/kg 438 01/14/10 10:30
ND u9/\(9 438 01/14/10 10:30
ND ug/kg 438 01/14/10 10:30
46 % 30-150 01/14/10 10:30
46 % 46-120 01/14/10 10:30
37 % 38-108 01/14/10 10:30
47 % 35-120 01/14/10 10:30
42 % 24-120 01/14/10 10:30
56 % 44-136 01/14/10 10:30
Analytical Method: ASTM D2974-87
24.7 % 0.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Jnc ..
,-Pri"'--e'10ek1C1,
Analyzed CAS No. Qual
01/19/10 09:36 83-32-9
01/19/10 09:36 208-96-8
01/19/10 09:36 120-12-7
01/19/10 09:36 56-55-3
01/19/10 09:36 50-32-8
01/19/10 09:36 205-99-2
01/19/10 09:36 191-24-2
01/19/10 09:36 207-08-9
01/19/10 09:36 218-01-9
01/19/10 09:36 53-70-3
01/19/10 09:36 206-44-0
01/19/10 09:36 86-73-7
01/19/10 09:36 193-39-5
01/19/10 09:36 90-12-0
01/19/10 09:36 91-57-6
01/19/10 09:36 91-20-3
01/19/10 09:36 85-01-8
01/19/10 09:36 129-00-0
01/19/10 09:36 4165-60-0
01/19/10 09:36 321-60-8
01/19/10 09:36 1718-51-0 so
01/19/10 09:36 13127-88-3
01/19/10 09:36 367-12-4
01/19/10 09:36 118-79-6
01/08/10 17:41
Page 18 of 31
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Castle Hayne 22-12493E
Pace Project No.: 9260782
Sample: B1 LablD: 9260782016 Collected: 01/06/10 12:15 Received: 01/06/10 16:15 Matrix: Solid
Results reported on a "dry-weight" basis
Parameters
6010 MET ICP
Aluminum
Antimony
Arsenic
Chromium
Copper
Iron
Lead
Nickel
Thallium
Zinc
Percent Moisture
Percent Moisture
Date: 01/27/2010 03:08 PM
Results Units Report Limit OF Prepared
Analytical Method: EPA6010 Preparation Method: EPA 3050
2190 mg/kg 11.3 01/11/10 11:11
ND mg/kg 0.57 01/11/10 11:11
ND mg/kg 0.57 01/11/10 11:11
2.1 mg/kg 0.57 01/11/10 11:11
ND mg/kg 0.57 01/11/10 11:11
438 mg/kg 5.7 01/11/10 11:11
4.5 mg/kg 0.57 01/11/10 11:11
ND mg/kg 0.57 01/11/1011:11
ND mg/kg 1.1 01/11/10 11:11
ND mg/kg 1.1 01/11/10 11:11
Analytical Method: ASTM D2974-87
23.9 % 0.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Se.vices, Inc ..
Analyzed CAS No.
01/12/10 13:10 7429-90-5
01/12/10 13:10 7440-36-0
01/12/10 13:10 7440-38-2
01/12/10 13:10 7440-47-3
01/12/10 13:10 7440-50-8
01/12/10 13:10 7439-89-6
01/12/10 13:10 7439-92-1
01/12/10 13:10 7440-02-0
01/12/10 13:10 7440-28-0
01/12/10 13:10 7440-66-6
01/08/10 17:41
Qual
Page 19 of 31
Paco Analytical Servicos, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Ashevi!!e, NC 28804
(828)254• 7176
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704 )875-9092
Project: Castle Hayne 22-12493E
Pace Project No.: 9260782
Sample: 82 LablD: 9260782017 Collected: 01/06/10 13:30 Received: 01/06/10 16:15 Matrix: Solid
Results reported on a "dry-weight" basis
Parameters
6010 MET ICP
Aluminum
Antimony
Arsenic
Chromium
Copper
Iron
Lead
Nickel
Thallium
Zinc
Percent Moisture
Percent Moisture
Date: 01/27/2010 03:08 PM
Results Units Report Limit DF Prepared
Analytical Method: EPA 6010 Preparation Method: EPA 3050
600 mg/kg 6.7 01/11/10 11:11
ND mg/kg 0.34 01/11/10 11:11
ND mg/kg 0.34 01/11/10 11:11
0.94 mg/kg 0.34 01/11/10 11:11
ND mg/kg 0.34 01/11/10 11:11
250 mg/kg 3.4 01/11/10 11:11
6.0 mg/kg 0.34 01/11/10 11:11
ND mg/kg 0.34 01/11/10 11:11
ND mg/kg 0.67 01/11/10 11:11
ND mg/kg 0.67 01/11/10 11:11
Analytical Method: ASTM D2974-87
24.7 % 0.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
Analyzed CAS No.
01/12/10 13:18 7429-90-5
01/12/10 13:18 7440-36-0
01/12/10 13:18 7440-38-2
01/12/10 13:18 7440-47-3
01/12/10 13:18 7440-50-8
01/12/10 13:18 7439-89-6
01/12/10 13:18 7439-92-1
01/12/10 13:18 7440-02-0
01/12/10 13:18 7440-28-0
01/12/10 13:18 7440-66-6
01/08/10 17:41
Qual
Page 20 of 31
Pace Analytical Services, Inc.
2225 Riverside Dr.
ANALYTICAL RESULTS
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 t<;inceyAve. Suite 100
Huntersville, NC 28078
(704}875-9092
Project: Castle Hayne 22-12493E
Pace Project No.: 9260782
Sample: B3 LablD: 9260782018 Collected: 01/06/10 14:00 Received: 01/06/10 16:15 Matrix: Solid
Results reported on a "dry-weight" basis
Parameters
6010 MET ICP
Aluminum
Antimony
Arsenic
Chromium
Copper
Iron
Lead
Nickel
Thallium
Zinc
Percent Moisture
Percent Moisture
Date: 01/27/2010 03:08 PM
Results Units Report Limit OF Prepared
Analytical Method: EPA6010 Preparation Method: EPA 3050
2250 mg/kg 8.3 01/11/10 11:11
ND mg/kg 0.41 01/11/10 11:11
0.41 mg/kg 0.41 01/11/10 11:11
2.4 mg/kg 0.41 01/11/10 11:11
ND mg/kg 0.41 01/11/10 11:11
434 mg/kg 4.1 01/11/10 11:11
3.8 mg/kg 0.41 01/11/10 11:11
ND mg/kg 0.41 01/11/10 11:11
ND mg/kg 0.83 01/11/10 11:11
ND mg/kg 0.83 01/11/10 11:11
Analytical Method: ASTM 0297 4-87
16.3 % 0.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
,r,"~~c,
i1ne1c1c\;
Analyzed GAS No.
01/12/10 13:26 7429-90-5
01/12/10 13:26 7440-36-0
01/12/10 13:26 7440-38-2
01/12/10 13:26 7440-47-3
01/12/10 13:26 7440-50-8
01/12/10 13:26 7439-89-6
01/12/10 13:26 7439-92-1
01/12/10 13:26 7440-02-0
01/12/10 13:26 7440-28-0
01/12/101.3:26 7440-66-6
01/08/10 17:41
Oual
Page 21 of 31
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Castle Hayne 22-12493E
Pace Project No.: 9260782
QC Batch: MPRP/5654 Analysis Method:
QC Batch Method: EPA 3050 Analysis Des_cription:
Associated Lab Samples: 9260782016, 9260782017, 9260782018
METHOD BLANK: 388874 Matrix: Solid
Associated Lab Samples: 9260782016,9260782017,9260782018
Blank Reporting
EPA 6010
6010 MET
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704 )875-9092
Parameter Units Result Limit Analyzed Qualifiers
Aluminum
Antimony
Arsenic
Chromium
Copper
Iron
Lead
Nickel
Thallium
Zinc
LABORATORY CONTROL SAMPLE:
Aluminum
Antimony
Arsenic
Chromium
Copper
Iron
Lead
Nickel
Thallium
Zinc
Parameter
MATRIX SPIKE SAMPLE:
Aluminum
Antimony
Arsenic
Chromium
Copper
Iron
Lead
Nickel
Thallium
Zinc
Parameter
Date: 01/27/2010 03:08 PM
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
388875
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
Units
388876
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
Units
ND 10.0 01/12/10 13:02
ND 0.50 01/12/10 13:02
ND 0.50 01/12/10 13:02
ND 0.50 01/12/10 13:02
ND 0.50 01/12/10 13:02
ND 5.0 01/12/10 13:02
ND 0.50 01/12/10 13:02
ND 0.50 01/12/10 13:02
ND 1.0 01/12/10 13:02
ND 1.0 01/12/10 13:02
Spike LCS LCS %Rec
Cone. Result %Rec
500 462 92
50 47.1 94
50 45.1 90
50 45.9 92
50 46.1 92
500 480 96
50 45.5 91
50 46.4 93
50 44.0 BB
50 45.5 91
9260782016 Spike MS
Result Cone. Result
2190 432 2890
ND 43.2 43.2
ND 43.2 41.6
2.1 43.2 44.1
ND 43.2 43.7
438 432 872
4.5 43.2 45.5
ND 43.2 42.B
NO 43.2 39.9
ND 43.2 42.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full.
without the written consent of Pace Analytical Services, Inc .. ,.«i'¾., ?1nek1C1,
Limits
80-120
80-120
80-120
80-120
80-120
80-120
80-120
80-120
80-120
80-120
MS
%Rec
164
99
95
97
100
100
95
98
92
96
Qualifiers
%Rec
Limits Qualifiers
75-125 M1
75-125
75-125
75-125
75-125
75-125
75-125
75-125
75-125
75-125
Page 22 of 31
Project:
Pace Project No.:
Castle Hayne 22-12493E
9260782
SAMPLE DUPLICATE: 388877
Parameter Units
Aluminum mg/kg
Antimony mg/kg
Arsenic mg/kg
Chromium mg/kg
Copper mg/kg
Iron mg/kg
Lead mg/kg
Nickel mg/kg
Thallium mg/kg
Zinc mg/kg
Date: 01/27/2010 03:08 PM
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
9260782017 Dup
Result Result RPO
600 571
ND ND
ND .34J
0.94 0.96
ND :17J
250 265
6.0 6.6
ND .21J
ND ND
ND 1.4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
. ->'r'i~--11neld.c\',
Qualifiers
5
2
6
9
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704 )875-9092
Page 23 of 31
Project: Castle Hayne 22-12493E
Pace Project No.: 9260782
QC Batch: OEXT/9013
QC Batch Method: EPA 3546
Pace Analytical Services, Inc.
2225 Riverside Or.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Analysis Method: EPA 8270
Analysis Description: 8270 Solid MSSV Microwave
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Associated Lab Samples: 9260782001, 9260782002, 9260782003, 9260782004, 9260782005, 9260782006, 9260782007, 9260782008,
9260782009,9260782010
METHOD BLANK: 388837 Matrix: Solid
Associated Lab Samples: 9260782001, 9260782002, 9260782003, 9260782004, 9260782005, 9260782006, 9260782007, 9260782008,
9260782009, 9260782010
Parameter
1-Methylnaphthalene
2-Methylnaphthalene
Acenaphthene
Acenaphthy1ene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g, h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
lndeno(1,2,3-cd)pyrene
Naphthalene
Phenanthrene
Pyrene
2,4,6-Tribromophenol (S)
2-Fluorobiphenyl (S)
2-Fluorophenol (S)
Nitrobenzene-d5 (S)
Phenol-dB (S)
Terphenyl-d14 (S)
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
%
%
%
%
%
%
LABORATORY CONTROL SAMPLE & LCSD:
Parameter
1-Methylnaphthalene ug/kg
2-Methylnaphthalene ug/kg
Acenaphthene ug/kg
Acenaphthylene ug/kg
Anthracene ug/kg
Benzo(a)anthracene ug/kg
Benzo(a)pyrene ug/kg
Benzo(b )fluoranthene ug/kg
Benzo(g, h, i )perylene ug/kg
Benzo(k)fluoranthene ug/kg
Chrysene ug/kg
Dibenz(a, h)anthracene ug/kg
Date: 01/27/2010 03:08 PM
Blank Reporting
Units Result Limit Analyzed Qualifiers
ND 330 01/21/10 00:06
ND 330 01/21/10 00:06
ND 330 01/21/10 00:06
ND 330 01/21/10 00:06
ND 330 01/21/10 00:06
ND 330 01/21/10 00:06
ND 330 01/21/10 00:06
ND 330 01/21/10 00:06
ND 330 01/21/10 00:06
ND 330 01/21/10 00:06
ND 330 01/21/10 00:06
ND 330 01/21/10 00:06
ND 330 01/21/10 00:06
ND 330 01/21/10 00:06
ND 330 01/21/10 00:06
ND 330 01/21/10 00:06
ND 330 01/21/10 00:06
ND 330 01/21/10 00:06
46 44-136 01/21/10 00:06
38 46-120 01/21/10 00:06 so
35 24-120 01/21/10 00:06
35 30-150 01/21/10 00:06
37 35-120 01/21/10 00:06
53 38-108 01/21/10 00:06
388838 388839
Spike LCS LCSD LCS LCSD % Rec Max
Units Cone. Result Result %Rec %Rec Limits RPO RPO Qualifiers
1670 753 798 45 48 50-150 6 30 LO
1670 749 794 45 48 50-150 6 30 LO
1670 761 808 46 48 50-150 6 30 LO
1670 764 812 46 49 50-150 6 30 LO
1670 787 839 47 50 50-150 6 30 LO
1670 766 811 46 49 50-150 6 30 LO
1670 753 806 45 48 50-150 7 30 LO
1670 745 796 45 48 50-150 7 30 LO
1670 767 808 46 48 24-117 5 30
1670 784 837 47 50 50-150 7 30 LO
1670 779 835 47 50 50-150 7 30 LO
1670 786 858 47 51 17-128 9 30
REPORT OF LABORATORY ANALYSIS Page 24 of 31
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
'" '<Co~ iJ-r~~,-~ i1nelaei,
P~~-Pace Analytical Services, Inc. Pace Analytical Services, Inc.
2225 Riverside Dr. 9800 Kincey Ave. Suite 100
Asheville, NC 28804 Huntersville, NC 28078
[phone] (704}875-9092
QUALITY CONTROL DATA
Project: Castle Hayne 22-12493E
Pace Project No.: 9260782
LABORATORY CONTROL SAMPLE & LCSD: 388838 388839
Spike LCS LCSD LCS LCSD % Rec Max
Parameter Units Cone. Result Result %Rec % Rec Limits RPD RPD Qualifiers
Fluoranthene ug/kg 1670 BOO 855 48 51 50-150 7 30 LO
Fluorene ug/kg 1670 780 835 47 50 50-150 7 30 LO
I ndeno( 1,2, 3--cd )pyrene ug/kg 1670 771 833 46 50 19-128 8 30
Naphthalene ug/kg 1670 712 775 43 46 50-150 8 30 LO
Phenanthrene . ug/kg 1670 770 819 46 49 50-150 6 30 LO
Pyrene ug/kg 1670 766 785 46 47 50-150 2 30 LO
2,4,6-Tribromophenol (S) % 46 49 44-136
2-Fluorobiphenyl (S) % 43 44 46-120 so
2-Fluorophenol (S) % 41 47 24-120
Nitrobenzene-d5 {S) % 40 44 30-150
Phenol-dB (S) % 44 48 35-120
Terphenyl-d14 (S) % 45 46 38-108
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 388840 388841
MS MSD
9260469011 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Cone. Cone. Result Result %Rec % Rec Limits RPD Qual
1-Methytnaphthalene ug/kg
2-Methylnaphthalene ug/kg
Acenaphthene ug/kg
Acenaphthylene ug/kg
Anthracene ug/kg
Benzo(a)anthracene ug/kg
Benzo(a)pyrene ug/kg
Benzo(b)fluoranthene ug/kg
Benzo(g, h, i )perylene ug/kg
Benzo(k)fluoranthene ug/kg
Chrysene ug/kg
Dibenz(a,h)anthracene ug/kg
Fluoranthene ug/kg
Fluorene ug/kg
lndeno(1,2,3-cd)pyrene ug/kg
Naphthalene ug/kg
Phenanthrene ug/kg
Pyrene ug/kg
2,4,6-Tribromophenol (S) %
2-Fluorobiphenyl (S) %
2-Fluorophenol (S) %
Nitrobenzene-d5 (S) %
Phenol-d6 (S) %
Terphenyl-d14 (S) %
Date: 01/27/2010 03:06 PM
ND 2060 2060 958 1000
ND 2060 2060 955 983
ND 2060 2060 952 1030
ND 2060 2060 961 1040
ND 2060 2060 950 1050
ND 2060 2060 888 965
ND 2060 2060 856 942
ND 2060 2060 814 938
ND 2060 2060 904 948
ND 2060 2060 893 923
ND 2060 2060 896 993
ND 2060 2060 923 996
ND 2060 2060 925 1030
ND 2060 2060 964 1050
ND 2060 2060 904 972
ND 2060 2060 937 930
ND 2060 2060 926 1020
ND 2060 2060 870 956
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc .. .. ze~,-11nelao1
47 49 50-150 5 MO
46 48 50-150 3 MO
46 50 50-150 8 MO
47 51 50-150 8 MO
46 51 50-150 10 MO
43 47 50-150 8 MO
42 46 50-150 10 MO
40 46 50-150 14 MO
44 46 50-150 5 MO
43 45 50-150 3 MO
44 48 50-150 10 MO
45 48 50-150 8 MO
45 50 50-150 11 MO
47 51 50-150 9 MO
44 47 50-150 7 MO
46 45 50-150 1 MO
45 49 50-150 9 MO
42 46 50-150 9 MO
44 52 44-136
43 45 46-120 so
43 43 24-120
43 43 30-150
43 45 35-120
36 40 38-108 so
Page 25 of 31
Project:
Pace Project No.:
Castle Hayne 22-12493E
9260782
QC Batch: OEXT/9043
QC Batch Method: EPA 3546
Pace Analytical Services, Inc.
2225 Riverside Or.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Analysis Method: EPA 8270
Analysis Description: 8270 Solid MSSV Microwave
Associated Lab Samples: 9260782011, 9260782012,9260782013,9260782014,9260782015
METHOD BLANK: 390396 Matrix: Solid
Associated Lab Samples: 9260782012,9260782014,9260782015
Blank Reporting
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Parameter Units Result Limit Analyzed Qualifiers
1-Methylnaphthalene ug/kg ND 330 01/15/10 17:37
2-Methylnaphthalene ug/kg ND 330 01/15/10 17:37
Acenaphthene ug/kg ND 330 01/15/10 17:37
Acenaphthylene ug/kg ND 330 01/15/10 17:37
Anthracene ug/kg ND 330 01/15/10 17:37
Benzo(a)anthracene ug/kg NO 330 01/15/10 17:37
Benzo(a)pyrene ug/kg ND 330 01/15/10 17:37
Benzo(b )fluoranthene ug/kg ND 330 01/15/10 17:37
Benzo(g, h, i )perylene ug/kg ND 330 01/15/10 17:37
Benzo(k)fluoranthene ug/kg ND 330 01/15/10 17:37
Chrysene ug/kg ND 330 01/15/10 17:37
Dibenz(a, h)anthracene ug/kg NO 330 01/15/10 17:37
Fluoranthene ug/kg ND 330 01/15/10 17:37
Fluorene ug/kg ND 330 01/15/10 17:37
lndeno( 1,2,3-cd)pyrene ug/kg ND 330 01/15/10 17:37
Naphthalene ug/kg NO 330 01/15/10 17:37
Phenanthrene ug/kg ND 330 01/15/10 17:37
Pyrene ug/kg ND 330 01/15/10 17:37
2,4,6-Tribromophenol (S) % 73 44-136 01/15/10 17:37
2-Fluorobiphenyl (S) % 62 46-120 01/15/10 17:37
2-Fluorophenol (S) % 62 24-120 01/15/10 17:37
Nitrobenzene-d5 (S) % 64 30-150 01/15/10 17:37
Phenol-dB (S) % 71 35-120 01/15/10 17:37
Terphenyl-d14 (S) % 65 38-108 01/15/10 17:37
LABORATORY CONTROL SAMPLE & LCSD: · 390397 390398
Spike LCS LCSO LCS LCSD % Rec Max
Parameter Units Cone. Result Result % Rec %Rec Limits RPO RPO Qualifiers ----
1-Methylnaphthalene ug/kg 1670 1100 1320 66 79 50-150 18 30
2-Methylnaphthalene ug/kg 1670 1080 1290 65 77 50-150 17 30
Acenaphthene ug/kg 1670 1310 1460 79 BB 50-150 11 30
Acenaphthylene ug/kg 1670 1220 1400 73 84 50-150 14 30
Anthracene ug/kg 1670 1240 1380 74 83 50-150 11 30
Benzo(a)anthracene ug/kg 1670 1290 1370 77 82 50-150 6 30
Benzo(a)pyrene ug/kg 1670 1220 1390 73 84 50-150 13 30
Benzo(b)fluoranthene ug/kg 1670 1220 1430 73 86 50-150 16 30
Benzo(g, h, i )perylene ug/kg 1670 1470 1910 88 115 24-117 26 30
Benzo(k)fluoranthene ug/kg 1670 1270 1460 76 88 50-150 14 30
Chrysene ug/kg 1670 1210 1360 72 82 50-150 12 30
Dibenz( a, h )a nth racene ug/kg 1670 1410 1770 84 106 17-128 23 30
Fluoranthene ug/kg 1670 1220 1470 73 88 50-150 19 30
Date: 01/27/2010 03:08 PM REPORT OF LABORATORY ANALYSIS Page 26 of 31
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services. Inc .. _.rf-'fr--fine C1,
p,~!J!_~· Pace Analytical Services, Inc. Pace Analytical Services, Inc.
2225 Riverside Dr. 9800 Kincey Ave. Suite 100
Asheville, NC 28804 Huntersville, NC 28078
[phone] [phone]
QUALITY CONTROL DATA
Project: Castle Hayne 22-12493E
Pace Project No.: 9260782
LABORATORY CONTROL SAMPLE & LCSD: 390397 390398
Spike LCS LCSD LCS LCSD %Rec Max
Parameter Units Cone. Result Result %Rec %Rec Limits RPD RPD Qualifiers
Fluorene ug/kg 1670 1270 1380 76 83 50-150 9 30
lndeno(1,2,3-cd)pyrene ug/kg 1670 1420 1800 85 108 19-128 24 30
Naphthalene ug/kg 1670 1060 1320 63 79 50-150 22 30
Phenanthrene u9/k9 1670 1310 1390 78 84 50-150 6 30
Pyrene ug/kg 1670 1270 1280 76 77 50-150 30
2,4,6-Tribromophenol (S) % 72 87 44-136
2-Fluorobiphenyl (S) % 66 77 46-120
2-Fluorophenol (S) % 49 65 24-120
Nitrobenzene-d5 (S) % 56 74 30-150
Phenol-<16 (S) % 57 72 35-120
Terphenyl-d14 (S) % 71 74 38-108
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 390399 390400
MS MSD
9261097001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Oual
1-Methylnaphthalene ug/kg
2-Methylnaphthalene ug/kg
Acenaphthene ug/kg
Acenaphthylene ug/kg
Anthracene ug/kg
Benzo(a)anthracene ug/kg
Benzo(a)pyrene ug/kg
Benzo(b)fluoranthene ug/kg
Benzo(g, h, i )perylene ug/kg
Benzo(k)fluoranthene ug/kg
Chrysene ug/kg
Oibenz(a,h )anthracene ug/kg
Fluoranthene ug/kg
Fluorene ug/kg
lndeno( 1,2,3-cd)pyrene ug/kg
Naphthalene ug/kg
Phenanthrene ug/kg
Pyrene ug/kg
2,4,6-Tribromophenol (S) %
2-Fluorobiphenyl (S) %
2-Fluorophenol (S) %
Nitrobenzene-d5 (S) %
Phenol-d6 (S) %
Terphenyl-d14 (S) %
Date: 01/27/2010 03:08 PM
ND 1990 1990 1360 1220
ND 1990 1990 1350 1210
ND 1990 1990 1400 1380
ND 1990 1990 1390 1370
ND 1990 1990 1430 1470
ND 1990 1990 1340 1560
ND 1990 1990 1360 1390
ND 1990 1990 1500 1520
ND 1990 1990 1160 1380
ND 1990 1990 1400 1310
ND 1990 1990 1410 1470
ND 1990 1990 1280 1400
ND 1990 1990 1430 1470
ND 1990 1990 1400 1430
ND 1990 1990 1240 1400
ND 1990 1990 1270 1100
ND 1990 1990 1400 1440
ND 1990 1990 1410 1520
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent ol Pace Analytical Services, Inc ..
.. ~7F 0·{-t_!.e~,.~ ?,nelao,
69 62 50-150 11
68 61 50-150 12
71 69 50-150 2
70 69 50-150 1
72 74 50-150 3
68 79 50-150 15
69 70. 50-150 2
76 77 50-150 1
59 70 50-150 18
71 66 50-150 7
71 74 50-150 4
65 71 50-150 9
72 74 50-150 3
71 72 50-150 2
62 70 50-150 12
64 55 50-150 14
71 73 50-150 3
71 77 50-150 8
68 70 44-136
64 62 46-120
56 48 24-120
60 52 30-150
61 51 35-120
66 74 38-108
Page 27 of 31
Project: Castle Hayne 22-12493E
Pace Project No.: 9260782
QC Batch: PMST/2970
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Analysis Method: ASTM D297 4-87
QC Batch Method: ASTM 02974-87 Analysis Description: Dry Weight/Percent Moisture
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
. Huntersville, NC 28078
(704 )875-9092
Associated Lab Samples: 9260782001, 9260782002, 9260782003, 9260782004, 9260782005, 9260782006, 9260782007, 9260782008,
9260782009,9260782010,9260782011,9260782012
SAMPLE DUPLICATE: 388232
Parameter Units
Percent Moisture %
SAMPLE DUPLICATE: 388233
Parameter Units
Percent Moisture %
Date: 01/27/2010 03:08 PM
9260769003 Dup
Result Result
7.7 8.2
9260782012 Dup
Result
22.2
Result
21.7
RPD
RPD
REPORT OF LABORATORY ANALYSIS
This report shall not be r8produced, except in lull,
without the written consent of ~ace Analytical Services, Inc ..
~«<~~~ .. --;1 nelao,
Qualifiers
6
Qualifiers
2
Page 28 of 31
Project: Castle Hayne 22-12493E
Pace Project No.: 9260782
QC Batch: PMST/2971
Paco Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Analysis Method: ASTM D2974-87
QC Batch Method: ASTM 02974-87 Analysis Description: Dry Weight/Percent Moisture
Associated Lab Samples: 9260782013, 9260782014, 9260782015, 9260782016, 9260782017, 9260782018
SAMPLE DUPLICATE: 388234
Parameter Units
Percent Moisture %
SAMPLE DUPLICATE: 388235
Parameter Units
Percent Moisture %
Date: 01/27/2010 03:08 PM
9260782013 Dup
Result
17.4
Result
17.2
9260831008 Oup
Result Result
18.1 18.3
RPD
RPD
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
Qualifiers
Qualifiers
Pace Analytical Sorvicos, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704 )875-9092
Page 29 of 31
Paco Analytical Sorvicos, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Paco Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704}875-9092
QUALIFIERS
Project Castle Hayne 22-12493E
Pace Project No.: 9260782
DEFINITIONS
DF -Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of
the sample aliquot. or moisture content.
ND -Not Detected at or above adjusted reporting limit.
J -Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
S -Surrogate
1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate% recovery and RPD values.
LCS(D) -Laboratory Control Sample (Duplicate)
MS(D) -Matrix Spike (Duplicate)
DUP -Sample Duplicate
RPD -Relative Percent Difference
NC -Not Calculable.
Pace Analytical is NELAP accredited. Contact your Pace PM for the current list of accredited analytes.
U -Indicates the compound was analyzed for, but not detected.
LABORATORIES
PASI-A
PASI-C
Pace Analytical Services -Asheville
Pace Analytical Services -Charlotte
BATCH QUALIFIERS
Batch: MSSV/3282
[1] The Internal Standard responses for all samples in this batch are within Acceptance Criteria but are biased high due to
concentration of the stock IS that was used to spike the samples. Subsequently the high IS response caused the
surrogate and target compound concentrations to be biased low and all results should be considered to be estimated.
The samples were not re-extracted due to the length of time that they are out of Hold. The samples were reanalyzed
under a new calibration on 012310 and yielded similar results.
ANALYTE QUALIFIERS
1 g Surrogate Not Detected
LO Anatyte recovery in the laboratory control sample (LCS) was outside QC limits.
MO Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
SO Surrogate recovery outside laboratory control limits.
S1 Surrogate recovery outside laboratory control limits (confirmed by re-analysis).
Date: 01/27/2010 03:08 PM REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
Page 30 of 31
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704 )875-9092
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: Castle Hayne 22-12493E
Pace Project No.: 9260782
Lab ID Sample ID
9260782016 B1
9260782017 B2
9260782018 B3
9260782001 HA13
9260782002 HA14
9260782003 HA15
9260782004 HA16
9260782005 HA17
9260782006 HA18
9260782007 HA19
9260782008 HA20
9260782009 HA21
9260782010 HA22
9260782011 HA23
9260782012 HA24
9260782013 HA25
9260782014 HA26
9260782015 HA27
9260782001 HA13
9260782002 HA14
9260782003 HA15
9260782004 HA16
9260782005 HA17
9260782006 HA18
9260782007 HA19
9260782008 HA20
9260782009 HA21
9260782010 HA22
9260782011 HA23
9260782012 HA24
9260782013 HA25
9260782014 HA26
9260782015 HA27
9260782016 B1
9260782017 B2
9260782018 B3
Date: 01/27/2010 03:08 PM
QC Batch Method QC Batch
EPA 3050 MPRP/5654
EPA 3050 MPRP/5654
EPA3050 MPRP/5654
EPA 3546 OEXT/9013
EPA 3546 OEXT/9013
EPA 3546 OEXT/9013
EPA3546 OEXT/9013
EPA3546 OEXT/9013
EPA3546 OEXT/9013
EPA3546 OEXT/9013
EPA 3546 OEXT/9013
EPA 3546 OEXT/9013
EPA 3546 OEXT/9013
EPA3546 OEXT/9043
EPA3546 OEXT/9043
EPA3546 OEXT/9043
EPA 3546 OEXT/9043
EPA 3546 OEXT/9043
ASTM D297 4-87 PMST/2970
ASTM D297 4-87 PMST/2970
ASTM ·0297 4-87 PMST/2970
ASTM D2974-87 PMST/2970
ASTM D297 4-87 PMST/2970
ASTM D297 4-87 PMST/2970
ASTM D2974-87 PMST/2970
ASTM D2974-87 PMST/2970
ASTM D297 4-87 PMST/2970
ASTM D2974-87 PMST/2970
ASTM D2974-87 PMST/2970
ASTM D2974-87 PMST/2970
ASTM D2974-87 PMST/2971
ASTM D2974-87 PMST/2971
ASTM D297 4-87 PMST/2971
ASTM D297 4-87 PMST/2971
ASTM D297 4-87 PMST/2971
ASTM D2974-87 PMST/2971
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc ..
,/J-f-'c~~<'r ?,nelaei,
Analytical
Analytical Method Batch
EPA 6010 ICP/5232
EPA 6010 ICP/5232
EPA6010 ICP/5232
EPA 8270 MSSV/3282
EPA 8270 MSSV/3282
EPA 8270 MSSV/3282
EPA 8270 MSSV/3282
EPA8270 MSSV/3282
EPA8270 MSSV/3282
EPA8270 MSSV/3282
EPA 8270 MSSV/3282
EPA 8270 MSSV/3282
EPA 8270 MSSV/3282
EPA8270 MSSV/3275
EPA8270 MSSV/3275
EPA8270 MSSV/3275
EPA 8270 MSSV/3275
EPA 8270 MSSV/3275
Page 31 of 31
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CHAIN-OF-CUSTODY/ Analytical Request Document
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Page: I of ~ Section A Section B Section C
Required Cllent Information: Required Project Information: Invoice lnfom,etion: 1322798 Company: f'" ( S (' =c \11'<1• RoportT~ ,I C/'llv_~<; -?CS Attention: ~LJ {J1N'_W',_\
1ti\ Oacu.~ q,., u,"p '2. 01 Copy To: I Company Name:; C, ~ cc,CY'\\1/'A, ~EG.ULATORY AGENCY
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SlGNATUREofSAMPLER:/ ~ (~ DATE Signed I, (!! g~ u. E I ZolO ~ • • (MM/DDlYY): --"lmpo,tant Note: By signing 11'11$ fonn you are accepting Pace's NET 30 ~Y payment term$ •rid agreeing to late charges of 1.5% per moolh for any in~ not paid within 30 dsys. F-All-Q-020rev.07. 15-Mav-2007
aeAnalytica/'
CHAIN-OF-CUSTODY/ Analytical Request Document
The Cha!n-of-Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately.
www.p1e1l1bl.com
Section A Section B Section C Page: ?.. of r ,J..
Required Client Information: Required Project Information: Invoice Information: 1322799 Report fa Rt-,,..u Ull\d,\.Q .. j
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Wasta Water W'-N
Product P
SoiVSolld SL
Oil OL
Wipe WP
Air AR
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-...1:t~t....:t:__ _____ --I----J-1--l--l-----+--l-----J---~li~: 1~0Hl-+-W+-+l----l-+l----l----l''' , v n,es "
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' '7
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---~:---------Ht+t---''---t---'--t---t--~'-"2~-t--l-+-+tt+-H+-t-1H")H4~-¥'-11?-1'?1-+H-+-++------'~1"'~--l f---!c!--:!:----------r+--1-t-1+---+--t-+--t,--'"l":;.:;;~~HH-++H++--H+-l~jH'-l:~"'-l-'~"'f'~'Y-'-:X:,"f-f'+-H--+-+-+-+------~f<,JY\""~ +,.__-l +---'---------+.J-t-'-t--t---+--=4'-"''--+-t-=t-'+--1H--t-++-+-l'•+l-l..$~~~~1-1-.../.....11-1----_!d0.Dl~L-l
;3;.,\ 7 +-----------------+-+---+---f---+---+---+-t---f-t-+-+++--+-+-l;:.:?1-++-+-+-+--+-+f-+-+--+-f-+-+-------------1 ~~;· •
9
+-----------------+-+---+---f---+---+---+-t---l-t-+-+++--+-+-lffl-++-+-+-+--+-+f-+-+-+-l-+--+-------------1
10 .. ,;< +-----------------1--+-l---+---+---+---+-+-+-+-+-+-+-+-++-l:.::,,_+--+--+-+-<-+-+--+--+-+~>---.... -+------------< f: 11 +---------------i-+--+---+---t---+---t-+--t-++-+-+-+-+-H 1--+-+-+-+-+-+-+-+-+-+-+-+--+-----------l 12
ADDITIONAL COMMENTS -DATE TIME SAMPLE CONDITIONS
€CS I \t; he) u
y\ I \. r\ '
ORIGINAL
PRINT Nam• of SAMPLER: ~ l f (("if\(, V\,a. ~
SIGNATUREofSAMPLER: (~( &10_1',;) DATE Signed \i, 12..
(MM/DDIYY], I lb 010
p C § 0-i'§z ., 1i ~
~ ·Sc. iii a:;;:: E al~ 8 nj -!'! "' • "' "Important Note: By slgl\ing this form )'01,11111 accecillrlg P11ca's NET 30 day pi,ymerit 1enns etld agreeing to late charges of 1.5% PIii' monlh for any i:l~I paid w11111n 30 days.. F-AI I -0...n?n,.,,, n7 1 r:;.u ... ,, 'll'V'I.,.
Client Name:....,E(....,_·=S==-------Project# 9Jw O]Js-;;z
c~urier: ~~ Ex O UPS O USPS O Clionl O Commercial O Pace 0lher ----Gpti(fri"a.J
Custod:; Seal on Cooler/Box Present: 0 yes ~ no Seais ir.t3C!: ~s 0 no
Packina Material: 0 Bubble Wrap ~ble Sags O None OOther ___ _
Thermometer Used T060 Type of lce:S Blue None ~mp!es on ice coolin~ ;:irocess has begun
Cooler Temperatt2re · C).l\' 6ic:osica\ Tissue is 'i=rozen: Yes Ne NJ;... Date and Initials oi pers.)n examining
contents::J"('(\ffi 1-J-lO T~mp shc:.:id be above freezing to o·c . Ccr.;r.:ents:
Chain of Custody Present: iS!1.s □.'Jo 0NtA 1.
Chain of Cuslody Filled Qui: ~s 0No □NIA 2. ,, < .
Chain of Custody Relinquished: .;:,. 0No ON/A 3.
SamplE!r Name & Signature on COG: ';;I,; 0No ON/A 4. . . ., ~□No ,, ., Samples Arrived within Hold Time: □NIA 5. •. •,
Short Hold Time Analysis (<72hr): OYes ~.□NIA 6. ,, ,,
~ ,. Rush Turn Around Time Requested: OYes □NIA 7.
Sufficient Volume: ICl½s 0No □NIA 8. .
. Correct Containers Used: ~es 0No' □NIA 9,
•Pace Containers Used: ifv:, 0No, ON/A
s?es
. Containers Intact: 0No ON/A 10, .
Filtered vo!unie received for Ois:5olved les!s □Yes 0No ~A 11. '
Sample Labels .match C0C: ~s 0No ON/A 12.
•Includes date/time/ID/Analysis Matrix:
All containers needing preservation have been checked .. □Yes 0No ifN1A 13.
All containers needin9 preservation are found to be in □Yes 0No ~IA .. compliance with EPA recommen·dal(on.
'--
exceptions: VOA, co!ilorm. TDC, O&G. WI-ORO {water) 0Yes 0No 1n·1tiaf when completed
.Samples checked for dechlorination:· □Yes 0No 12i'NIA 14.
Head space in VOA Vials ( >6mm): 0Yes 0No· GN1A 15.
· Trip Blank Present: 0Yes □No ffi!A 16,
Trip Blank Custody Seal~ Present □Yes □No DfuA
Pace Trip Blank Lot# (if purchased): NIA
Client Notification/ Resolution: Field Data Required? Y / N I NIA Person Contacted: ______________ Dateffime:
Comments/ Resolution:----------------------------------------
Project Manager Review: QµJ Date:---=-;.)/-'--'-~/~/ D_
'-Joie: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this lorm wilt be sen! lo the North Carolina DEHNR :ertification Of/ice ( Le out of hold. incorrect preservative, out of temp, incorrect containers)