NCD981475932_19981106_FCX Inc. (Washington Plant)_FRBCERCLA SPD_DOT Soil Stockpile - Dioxin Report-OCR

CHEMICAL rNVIRONMENTAL TECTLOGY. INC .
• ENVIRONMENTAL ANALYTICAL SERVICES '-:f\~JQ)
NC DOT
801 SUMMIT AVE.
GREENSBORO, NC 27405
ATTN, CHRIS NIVER
re, ENCLOSED DIOXIN REPORT
Dear Mr. NIVER,
NOVEMBER 6, 1998.
RECEIVED
NOV 12 1998
SUPERFUND SECTION
Enclosed you will find the original Dioxin report for the sample
received 10/13/98, sample ID SS FCX-4, project name FCX SOIL AT WASHINGTON DOT
YARD. Please feel free to contact me if you have any questions.
P.O. Box 12298 • Research Triangle Park, NC 27709
Telephone [phone]
Sincerely,
jcMu, //, -I-¥½,._)
Terrie H. Litzenberger
Laboratory Director
Shipping: 102-A Woodwinds Industrial Court • Cary, NC 27511
Fax[phone]
CHEMICAL ~NVIRONMENTAL TEC.LOGY, !NC.
ENVIRONMENTAL ANAL YT/CAL SERVICES
FINAL REPORT OF ANALYSES
NC DOT
801 SUMMIT AVE. REPORT DATE, 11/06/98
GREENSBORO, NC 27405-
Attn, CHRIS NIVER
FCX SOIL/ WASHINGTON DOT YARD #9.6700094
SAMPLE NUMBER-152098 SAMPLE ID-SS FCX-1
DATE SAMPLED-10/13/98
DATE RECEIVED-10/13/98 SAMPLER-ROBERT ELLIS
TIME RECEIVED-1610 DELIVERED BY-ROBERT ELLIS
Page 1 of 4 PROJECT NAME , SOIL
ANALYSIS
PERCENT SOLIDS
METHOD
2540G
VOLATILE ORGANIC CMPNDS -SOIL 8021
BENZENE 8021
BROMOBENZENE 8021
BROMOCHLOROMETHANE 8021
BROMODICHLOROMETHANE 8021
BROMOFORM 8021
BROMOMETHANE 8021
n-BUTYLBENZENE 8021
sec-BUTYLBENZENE 8021
tert-BUTYLBENZENE 8021
CARBON TETRACHLORIDE 8021
CHLOROBENZENE 8021
CHLOROETHANE 8021
CHLOROFORM 8021
CHLOROMETHANE 8021
2-CHLOROTOLUENE 8021
4-CHLOROTOLUENE 8021
DIBROMOCHLOROMETHANE 8021
1,2-DIBROM0-3-CHLOROPROPANE 8021
1,2-DIBROMOETHANE 8021
SAMPLE
DATE
PREP
BY
ANALYSIS
DATE
10/15/98
10/15/98
BY
SAMPLE MATRIX-SO
TIME SAMPLED-1145
RECEIVED BY-CGE
RESULT UNITS
CGE 93.0 NA
ALT
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
PQL
P.O. Box 12298 • Research Triangle Park, NC 27709
Telephone [phone]
Shipping: 102-A Woodwinds Industrial Court • Cary, NC 27511
Fax[phone]
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
CHEMICAL 9"ENVIRONMENTAL TECI-1J>LOGY, INC.
ENVIRONMENTAL ANAL YT/CAL SERVICES
Page 2 of 4 PROJECT NAME
CONTINUATION OF DATA FOR SAMPLE NUMBER
ANALYSIS METHOD
DIBROMOMETHANE 8021
1,2-DICHLOROBENZENE 8021
1,3-DICHLOROBENZENE 8021
1,4-DICHLOROBENZENE 8021
DICHLORODIFLUOROMETHANE 8021
1,1-DICHLOROETHANE 8021
1,2-DICHLOROETHANE 8021
1,1 DICHLOROETHENE 8021
cis-1,2-DICHLOROETHENE 8021
trans-1,2-DICHLOROETHENE 8021
1,2-DICHLOROPROPANE 8021
1,3-DICHLOROPROPANE 8021
2,2-DICHLOROPROPANE 8021
1,1-DICHLOROPROPENE 8021
cis-1,3-DICHLOROPROPENE 8021
trans-1,3-DICHLOROPROPENE 8021
ETHYLBENZENE 8021
HEXACHLOROBUTADIENE 8021
ISOPROPYLBENZENE 8021
p-ISOPROPYLTOLUENE 8021
METHLYENE CHLORIDE 8021
NAPHTHALENE 8021
n-PROPYLBENZENE 8021
STYRENE 8021
1,1,1,2-TETRACHLOROETHANE 8021
1,1,2,2-TETRACHLOROETHANE 8021
TETRACHLOROETHENE 8021
TOLUENE 8021
1,2,3-TRICHLOROBENZENE 8021
1,2,4-TRICHLOROBENZENE 8021
1,1,1-TRICHLOROETHANE 8021
P.O. Box 12298 • Research Triangle Park. NC 27709
Telephone [phone]
' SOIL
152098
SAMPLE
DATE
PREP ANALYSIS
BY DATE BY RESULT UNITS PQL
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug"/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
Shipping: 102-A Woodwinds Industrial Court • Cary, NC 27511
Fax[phone]
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
CHEMICAL 9ENVIRONMENTAL TECI-9JLOGY, INC.
ENVIRONMENTAL ANAL YT/CAL SERVICES
Page 3 of 4 PROJECT NAME ' SOIL
CONTINUATION OF DATA FOR SAMPLE NUMBER 152098
SAMPLE PREP ANALYSIS
ANALYSIS METHOD DATE BY DATE BY RESULT UNITS PQL
1,1,2-TRICHLOROETHANE 8021
TRICHLOROETHENE 8021
TRICHLOROFLUOROMETHANE 8021
1,2,3-TRICHLOROPROPANE 8021
1,2,4-TRIMETHYLBENZENE 8021
1,3,5-TRIMETHYLBENZENE 8021
VINYL CHLORIDE 8021
o-XYLENE 8021
m,p-XYLENES 8021
ISOPROPYL ETHER (IPE) 8021
METHYLTERT-BUTYLETHER (MTBE) 8021
SURROGATE a 8021
SURROGATE b 8021
PESTICIDES/PCB'S 8080 SOIL 8080
ALDRIN 8080
ALPHA-BHC 8080
BETA-BHC 8080
DELTA-BHC 8080
GAMMA-BHC 8080
CHLORDANE 8080
4, 4 1 -ODD 8080
4, 4' -ODE 8080
4, 4' -DDT 8080
DEILDRIN 8080
ENDOSULFAN 1 8080
ENDOSULFAN II 8080
ENDOSULFAN SULFATE 8080
ENDRIN 8080
ENDRIN ALDEHYDE 8080
HEPTACHLOR 8080
HEPTACHLOR EPOXIDE 8080
P.O. Box 1 2298 • Research Triangle Park, NC 27709
Telephone [phone]
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
99.9 percent
98.8 percent
10/19/98 AEK 10/31/98 ALT
< 100 ug/kg
< 100 ug/kg
< 100 ug/kg
< 200 ug/kg
< 100 ug/kg
3280 ug/kg
< 200 ug/kg
< 200 ug/kg
< 200 ug/kg
< 40 ug/kg
< 200 ug/kg
< 200 ug/kg
< 1400 ug/kg
< 120 ug/kg
< 400 ug/kg
< 100 ug/kg
< 1600 ug/kg
Shipping: 102-A Woodwinds Industrial Court • Cary, NC 27511
Fax[phone]
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
100
100
100
200
100
400
200
200
200
40
200
200
1400
120
400
100
1600
CHEMICAL W,NVIRONMENTAL TECr-w:>LOGY, INC.
ENVIRONMENTAL ANAL YT/CAL SERVICES
Page 4 of 4 PROJECT NAME ' SOIL
CONTINUATION OF DATA FOR SAMPLE NUMBER 152098
SAMPLE PREP ANALYSIS
ANALYSIS METHOD DATE BY DATE BY RESULT UNITS PQL
METHOXYCHLOR 8080 < 1000 ug/kg
TOXAPHENE 8080 < 4800 ug/kg
PCB-1016 8080 < 1000 ug/kg
PCB-1221 8080 < 1000 ug/kg
PCB-1232 8080 < 1000 ug/kg
PCB-1242 8080 < 1000 ug/kg
PCB-1248 8080 < 1000 ug/kg
PCB-1254 8080 < 2000 ug/kg
PCB-1260 8080 < 2000 ug/kg
PQL = Practical Quantitation Limit
Results followed by the letter J are estimated concentrations.
All results for soil and sludge samples are reported on a dry weight basis as required
by the NC DEM Laboratory Certification Section. Wet Weight Concentration=
(dry weight cone.) (percent solids) /100.
NC DENR CERTIFICATIONS, DWQ -96; PUBLIC WATER SUPPLY -37724
LABORATORY DIRECTOR Jut,tu ~-k.f,'if/2, ,!
P.O. Box 12298 • Research Triangle Park. NC 27709
Telephone [phone]
Shipping: 102-A Woodwinds Industrial Court • Cary, NC 27511
Fax[phone]
1000
4800
1000
1000
1000
1000
1000
2000
2000
CHEMICAL ~NVIRONMENTAL TEC.LOGY, INC.
ENVIRONMENTAL ANAL YT/CAL SERVICES
FINAL REPORT OF ANALYSES
NC DOT
801 SUMMIT AVE.
GREENSBORO, NC 27405-
Attn, CHRIS NIVER
REPORT DATE, 11/06/98
FCX SOIL/ WASHINGTON DOT YARD #9.6700094
SAMPLE NUMBER-152099 SAMPLE ID-SS FCX-2
DATE SAMPLED-10/13/98
DATE RECEIVED-10/13/98 SAMPLER-ROBERT ELLIS
TIME RECEIVED-1610 DELIVERED BY-ROBERT ELLIS
Page 1 of 4 PROJECT NAME , SOIL
ANALYSIS
PERCENT SOLIDS
METHOD
2540G
VOLATILE ORGANIC CMPNDS -SOIL 8021
BENZENE 8021
BROMOBENZENE 8021
BROMOCHLOROMETHANE 8021
BROMODICHLOROMETHANE 8021
BROMOFORM 8021
BROMOMETHANE 8021
n-BUTYLBENZENE 8021
sec-BUTYLBENZENE 8021
tert-BUTYLBENZENE 8021
CARBON TETRACHLORIDE 8021
CHLOROBENZENE 8021
CHLOROETHANE 8021
CHLOROFORM 8021
CHLOROMETHANE 8021
2-CHLOROTOLUENE 8021
4-CHLOROTOLUENE 8021
DIBROMOCHLOROMETHANE 8021
l,2-DIBROM0-3-CHLOROPROPANE 8021
1,2-DIBROMOETHANE 8021
SAMPLE
DATE
PREP
BY
ANALYSIS
DATE
10/15/98
10/15/98
BY
SAMPLE MATRIX-SO
TIME SAMPLED-1150
RECEIVED BY-CGE
RESULT UNITS
CGE 93.4 NA
ALT
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
PQL
P.O. Box 12298 • Research Triangle Park. NC 27709
Telephone [phone]
Shipping; 102-A Woodwinds Industrial Court · Cary, NC 27511
Fax[phone]
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
CHEMICAL e£NVIRONMENTAL TECTLOGY, INC.
ENVIRONMENTAL ANAL YT/CAL SERVICES
Page 2 of 4 PROJECT NAME
CONTINUATION OF DATA FOR SAMPLE NUMBER
ANALYSIS METHOD
DIBROMOMETHANE 8021
1,2-DICHLOROBENZENE 8021
1,3-DICHLOROBENZENE 8021
1,4-DICHLOROBENZENE 8021
DICHLORODIFLUOROMETHANE 8021
1,1-DICHLOROETHANE 8021
1,2-DICHLOROETHANE 8021
1,1 DICHLOROETHENE 8021
cis-1,2-DICHLOROETHENE 8021
trans-1,2-DICHLOROETHENE 8021
1,2-DICHLOROPROPANE 8021
1,3-DICHLOROPROPANE 8021
2,2-DICHLOROPROPANE 8021
1,1-DICHLOROPROPENE 8021
cis-1,3-DICHLOROPROPENE 8021
trans-1,3-DICHLOROPROPENE 8021
ETHYLBENZENE 8021
HEXACHLOROBUTADIENE 8021
ISOPROPYLBENZENE 8021
p-ISOPROPYLTOLUENE 8021
METHLYENE CHLORIDE 8021
NAPHTHALENE 8021
n-PROPYLBENZENE 8021
STYRENE 8021
1,1,1,2-TETRACHLOROETHANE 8021
1,1,2,2-TETRACHLOROETHANE 8021
TETRACHLOROETHENE 8021
TOLUENE 8021
1,2,3-TRICHLOROBENZENE 8021
1,2,4-TRICHLOROBENZENE 8021
1,1,1-TRICHLOROETHANE 8021
P.O. Box 12298 • Research Triangle Park. NC 27709
Telephone [phone]
' SOIL
152099
SAMPLE
DATE
PREP ANALYSIS
BY DATE BY RESULT UNITS PQL
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
Shipping: 102-A Woodwinds Industrial Court • Cary, NC 27511
Fax[phone]
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
CHEMICAL '9£NVIRONMENTAL TEC.LOGY, INC.
ENVIRONMENTAL ANAL YT/CAL SERVICES
Page 3 of 4 PROJECT NAME : SOIL
CONTINUATION OF DATA FOR SAMPLE NUMBER 152099
SAMPLE PREP ANALYSIS
ANALYSIS METHOD DATE BY DATE BY RESULT UNITS PQL
1,1,2-TRICHLOROETHANE 8021
TRICHLOROETHENE 8021
TRICHLOROFLUOROMETHANE 8021
1,2,3-TRICHLOROPROPANE 8021
1,2,4-TRIMETHYLBENZENE 8021
1,3,5-TRIMETHYLBENZENE 8021
VINYL CHLORIDE 8021
a-XYLENE 8021
m,p-XYLENES 8021
ISOPROPYL ETHER (IPE) 8021
METHYLTERT-BUTYLETHER (MTBE) 8021
SURROGATE a 8021
SURROGATE b 8021
PESTICIDES/PCB'S 8080 SOIL 8080
ALDRIN 8080
ALPHA-BHC 8080
BETA-BHC 8080
DELTA-BHC 8080
GAMMA-BHC 8080
CHLORDANE 8080
4, 4' -DDD 8080
4, 4' -DDE 8080
4,4'-DDT 8080
DEILDRIN 8080
ENDOSULFAN 1 8080
ENDOSULFAN II 8080
ENDOSULFAN SULFATE 8080
ENDRIN 8080
ENDRIN ALDEHYDE 8080
HEPTACHLOR 8080
HEPTACHLOR EPOXIDE 8080
P.O. Box 12298 • Research Triangle Park, NC 27709
Telephone [phone]
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
95.7 percent
98.7 percent
10/19/98 AEK 10/31/98 ALT
< 100 ug/kg
< 100 ug/kg
< 100 ug/kg
< 200 ug/kg
< 100 ug/kg
10,200 ug/kg
< 200 ug/kg
< 200 ug/kg
< 200 ug/kg
< 40 ug/kg
< 200 ug/kg
< 200 ug/kg
< 1400 ug/kg
< 120 ug/kg
< 400 ug/kg
< 100 ug/kg
< 1600 ug/kg
Shipping: 102-A Woodwinds Industrial Court • Cary, NC 27511
Fax[phone]
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
100
100
100
200
100
400
200
200
200
40
200
200
1400
120
400
100
1600
CHEMICAL '9tNVIRONMENTAL TEC.LOGY, INC.
ENVIRONMENTAL ANAL YT/CAL SERVICES
Page 4 of 4 PROJECT NAME ' SOIL
CONTINUATION OF DATA FOR SAMPLE NUMBER 152099
SAMPLE PREP ANALYSIS
ANALYSIS METHOD DATE BY DATE BY RESULT UNITS PQL
METHOXYCHLOR 8080 < 1000 ug/kg
TOXAPHENE 8080 < 4800 ug/kg
PCB-1016 8080 < 1000 ug/kg
PCB-1221 8080 < 1000 ug/kg
PCB-1232 8080 < 1000 ug/kg
PCB-1242 8080 < 1000 ug/kg
PCB-1248 8080 < 1000 ug/kg
PCB-1254 8080 < 2000 ug/kg
PCB-1260 8080 < 2000 ug/kg
PQL = Practical Quantitation Limit
Results followed by the letter J are estimated concentrations.
All results for soil and sludge samples are reported on a dry weight basis as required
by the NC DEM Laboratory Certification Section. Wet Weight Concentration=
(dry weight cone.) (percent solids)/100.
NC DENR CERTIFICATIONS, DWQ -96; PUBLIC WATER SUPPLY -37724
LABORATORY DIRECTOR Jvw.t -f..;fx{~~
P.O. Box 12298 • Research Triangle Park, NC 27709
Telephone (919) 467•3090
Shipping: 102-A Woodwinds lndusmal Court • Cary, NC 27511
Fax[phone]
1000
4800
1000
1000
1000
1000
1000
2000
2000
CHEMICAL ~NVIRONMENTAL TECJ-9=>LOGY, INC.
ENVIRONMENTAL ANALYTICAL SERVICES
FINAL REPORT OF ANALYSES
NC DOT
801 SUMMIT AVE.
GREENSBORO, NC 27405-
Attn, CHRIS NIVER
REPORT DATE, 11/06/98
FCX SOIL/ WASHINGTON DOT YARD #9.6700094
SAMPLE NUMBER-152100 SAMPLE ID-SS FCX-3
DATE SAMPLED-10/13/98
DATE RECEIVED-10/13/98 SAMPLER-ROBERT ELLIS
TIME RECEIVED-1610 DELIVERED BY-ROBERT ELLIS
Page 1 of 4 PROJECT NAME , SOIL
ANALYSIS
PERCENT SOLIDS
METHOD
2540G
VOLATILE ORGANIC CMPNDS -SOIL 8021
BENZENE 8021
BROMOBENZENE 8021
BROMOCHLOROMETHANE 8021
BROMODICHLOROMETHANE 8021
BROMOFORM 8021
BROMOMETHANE 8021
n-BUTYLBENZENE 8021
sec-BUTYLBENZENE 8021
tert-BUTYLBENZENE 8021
CARBON TETRACHLORIDE 8021
CHLOROBENZENE 8021
CHLOROETHANE 8021
CHLOROFORM 8021
CHLOROMETHANE 8021
2-CHLOROTOLUENE 8021
4-CHLOROTOLUENE 8021
DIBROMOCHLOROMETHANE 8021
1,2-DIBROMO-3-CHLOROPROPANE 8021
1,2-DIBROMOETHANE 8021
SAMPLE
DATE
PREP
BY
ANALYSIS
DATE
10/15/98
10/15/98
BY
SAMPLE MATRIX-SO
TIME SAMPLED-1205
RECEIVED BY-CGE
RESULT UNITS
CGE 90.0 NA
ALT
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
PQL
P.O. Box 12298 • Research Triangle Park, NC 27709
Telephone [phone]
Shipping: 102-A Woodwinds Industrial Court • Cary, NC 27511
Fax [phone]
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
CHEMICAL .ENVIRONMENTAL TECI--9JLOGY, INC.
ENVIRONMENTAL ANAL YT/CAL SERVICES
Page 2 of 4 PROJECT NAME
CONTINUATION OF DATA FOR SAMPLE NUMBER
ANALYSIS METHOD
DIBROMOMETHANE 8021
1,2-DICHLOROBENZENE 8021
1,3-DICHLOROBENZENE 8021
1,4-DICHLOROBENZENE 8021
DICHLORODIFLUOROMETHANE 8021
1,1-DICHLOROETHANE 8021
1,2-DICHLOROETHANE 8021
1,1 DICHLOROETHENE 8021
cis-1,2-DICHLOROETHENE 8021
trans-1,2-DICHLOROETHENE 8021
1,2-DICHLOROPROPANE 8021
1,3-DICHLOROPROPANE 8021
2,2-DICHLOROPROPANE 8021
1,1-DICHLOROPROPENE 8021
cis-1,3-DICHLOROPROPENE 8021
trans-1,3-DICHLOROPROPENE 8021
ETHYLBENZENE 8021
HEXACHLOROBUTADIENE 8021
ISOPROPYLBENZENE 8021
p-ISOPROPYLTOLUENE 8021
METHLYENE CHLORIDE 8021
NAPHTHALENE 8021
n-PROPYLBENZENE 8021
STYRENE 8021
1,1,1,2-TETRACHLOROETHANE 8021
1,1,2,2-TETRACHLOROETHANE 8021
TETRACHLOROETHENE 8021
TOLUENE 8021
1,2,3-TRICHLOROBENZENE 8021
1,2,4-TRICHLOROBENZENE 8021
1,1,1-TRICHLOROETHANE 8021
P.O. Box 12298 • Research Triangle Park, NC 27709
Telephone [phone]
' SOIL
152100
SAMPLE
DATE
PREP ANALYSIS
BY DATE BY RESULT UNITS PQL
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
Shipping· 102-A Woodwinds Industrial Court • Cary, NC 27511
Fax[phone]
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
CHEMICAL 9ENVIRONMENTAL TECI-1tJLOGY, INC.
ENVIRONMENTAL ANAL YT/CAL SERVICES
Page 3 of 4 PROJECT NAME ' SOIL
CONTINUATION OF DATA FOR SAMPLE NUMBER 152100
SAMPLE PREP ANALYSIS
ANALYSIS METHOD DATE BY DATE BY RESULT UNITS PQL
1,1,2-TRICHLOROETHANE 8021
TRICHLOROETHENE 8021
TRICHLOROFLUOROMETHANE 8021
1,2,3-TRICHLOROPROPANE 8021
1,2,4-TRIMETHYLBENZENE 8021
1,3,5-TRIMETHYLBENZENE 8021
VINYL CHLORIDE 8021
o-XYLENE 8021
m,p-XYLENES 8021
ISOPROPYL ETHER (IPE) 8021
METHYLTERT-BUTYLETHER (MTBE) 8021
SURROGATE a 8021
SURROGATE b 8021
PESTICIDES/PCB'S 8080 SOIL 8080
ALDRIN 8080
ALPHA-BHC 8080
BETA-BHC 8080
DELTA-BHC 8080
GAMMA-BHC 8080
CHLORDANE 8080
4, 4' -ODD 8080
4,4' -ODE 8080
4, 4' -DDT 8080
DEILDRIN 8080
ENDOSULFAN 1 8080
ENDOSULFAN II 8080
ENDOSULFAN SULFATE 8080
ENDRIN 8080
ENDRIN ALDEHYDE 8080
HEPTACHLOR 8080
HEPTACHLOR EPOXIDE 8080
P.O. Box 12298 • Research Triangle Park. NC 27709
Telephone [phone]
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
100 percent
96.7 percent
10/19/98 AEK 10/31/98 ALT
< 100 ug/kg
< 100 ug/kg
< 100 ug/kg
< 200 ug/kg
< 100 ug/kg
4890 ug/kg
< 200 ug/kg
< 200 ug/kg
< 200 ug/kg
< 40 ug/kg
< 200 ug/kg
< 200 ug/kg
< 1400 ug/kg
< 120 ug/kg
< 400 ug/kg
< 100 ug/kg
< 1600 ug/kg
Shipping: 102-A Woodwinds Industrial Court • Cary, NC 27511
Fax{919)467-3515
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
100
100
100
200
100
400
200
200
200
40
2GO
200
1400
120
400
100
1600
CHEMICAL '9ENVIRONMENTAL TEC.LOGY, INC.
ENVIRONMENTAL ANAL YT/CAL SERVICES
Page 4 of 4 PROJECT NAME ' SOIL
CONTINUATION OF DATA FOR SAMPLE NUMBER 152100
SAMPLE PREP ANALYSIS
ANALYSIS METHOD DATE BY DATE BY RESULT UNITS PQL
METHOXYCHLOR 8080 < 1000 ug/kg
TOXAPHENE 8080 < 4800 ug/kg
PCB-1016 8080 < 1000 ug/kg
PCB-1221 8080 < 1000 ug/kg
PCB-1232 8080 < 1000 ug/kg
PCB-1242 8080 < 1000 ug/kg
PCB-1248 8080 < 1000 ug/kg
PCB-1254 8080 < 2000 ug/kg
PCB-1260 8080 < 2000 ug/kg
PQL = Practical Quantitation Limit
Results followed by the letter J are estimated concentrations.
All results for soil and sludge samples are reported on a dry weight basis as required
by the NC DEM Laboratory Certification Section. Wet Weight Concentration=
(dry weight cone.) (percent solids)/100.
NC DENR CERTIFICATIONS, DWQ -96; PUBLIC WATER SUPPLY -37724
LABORATORY DIRECTOR c90tcl, &-~'-~
P.O. Box 12298 • Research Triangle Park, NC 27709
Telephone [phone]
Shipping: 102-A Woodwinds lndus1rial Court • Cary. NC 27511
Fax[phone]
1000
4800
1000
1000
1000
1000
1000
2000
2000
EIE Chemical i Environmental Technology, Inc.
102-A Woodwinds Industrial Ct. Cary, NC 27511 CHAIN OF CUSTODY Page_/ ot__L
[phone] FAX: [phone]
cueNr I\ 1 , .._,__ ·-. NAME: ~ \,_. \""\n I Turnaround Time: == ~-~-aj 8ol S.u.M\'••i\ /\v<?_ S,,:L ¼-2.. LJRush (1 week)· l----_.,.,c.:::::::~::...::".=~'------~'....::::-..,2_'""-'Jl"'=_=-..f=----l D Rush (48 hours)"
6rc..a.f\S tx,,o ,NC... '21-L/oS □Rush (24hours)"
'-..
GJ
PROJECT NO: PROJECT NAME:
A ~ So.i,\ (n \-Wc_s\·,"'°~"-l)o1 Y,,~~)_ ~~~n u•:I £{i{.h ~l>e:~T; NAM~\ I iS
Cl co
GET Tl. ; TIME •11~1PL TYPE SAMPtE f cr' SAMPLE # DATp, COM GRAB SAMPLE l.D. MATRIX CO,..TAIN£P.S
I
'---0.J
/.::)
ANALYSES REQUIRED /
.
Bill TO:
ADDRESS: tioT
PURCHASE q
ORDER NO: 1 . C:, =i Ooo9 ~
/
PRESERVED IN FIELD O PRESERVATIVES
PRESERVED IN LAB O ~ 0 RECEIVED ON ICE il<:J !¾! i5 c/i 6 0 0 0 0 roro{/)z0
Z(f)<(zz'III REMARKS
X
X
X
X
~f-'---j-------,---\-+--f--------t--+-+-l--+---l--------l--+-+--------l--+-----,i--+--+--+----1----1
REUNO.YISl.lED BY (Sigriature) DATE I TIME RECEIVED BY (Signature) RELINQUISHED BY (Signature) DATE TIME RECEIVED BY (Signature)
~l,/bt\ \ c;J!(~v--, '
ic:({';/'ffj ltbfO •
REI INOUISHED BY (Signature)
V
ADDITIONAL INSTRUCTIONS:
Fcrwc,r~ L\ .,\~:\ ,c,·\<11 Cc, i>r
\c:a.sul+s l C.i,t;<:, }.'.i:Je.,, ~ Rush work requires lahoratory npproval prior to sample submission. Additional ch 1rgcs may apply. ~-------------'---------'
DATE I TIME DATI I TIME
lifi 'ii, Vi \ b ~ L 0
11/10/1998 17: 38 9103344149 't cx-w.,i,_,1J--,...PAGE 01
• C,oP ~2-0/~0o
NCDOT -Safety &
Loss Control
• 801 Summit Avenue, Greensboro, NC 27455
FAX
To:
I 4c.....6t;:A/.f.
Phone: f/p 3 '3 -) 8 O I ,X 3 ,50
Fax phone: '?t?/733-</SI /
CC:
Date: /;/ro fe8
I I
Nwnber of pages including cover sheet:
From:
Thomas C Niver, P.G,, CHMM
Phone: [phone]
fax phone: [phone]
REMARKS: D Urgent For your review D Reply ASAP □ Please com1nent
,
11/10/lggg 17:38 Sl0334414S PAGE B2
CHEMICA .. ENVIRONMENT AL TE~OLOGY, !NC.
ENVIRONMENTAL. ANAL YT/CAL SERVICES
NC DOT
801 SUMMIT AVE.
GREENSBORO, NC 27405
ATTN, CHRIS NIVER
re, ENCLOSED DIOXIN REFORT
Dear Mr. NIVER:
NOVEMBER 6, 1998.
Enclosed you will find the original Dioxin report for the sample
received 10/13/98, sample ID SS FCX-4, project name FCX SOIL AT WASHINGTON DOT
YARD. Please feel free to contact me if you have any question9.
P.O. Bo,.. 12298 • Research Triangle Park. NC 27709
-:-.,,,t,,,,t,,,,,., rQ11;:.1 Ar--,.·inan
Sincerely,
~ If, /_ ~A_/
Terrie H. Litzenberger
La~oratory Director
ShiJ,:)ping• 102.A. Woodwinds lndu5trial Court • Cary, NC 27511
~-~1q1q14R7-1S1S
11/10/lSSB 17:38 Sl03344l ~S PAGE 03
ENVIRONMENTAL ANAL YT/CAL SERVICES
. l'lNAL REPORT OF ANALYSES
NC DOT
B01 SUMMIT AVE.
GREENSBORO, NC 27405-
Attn, CHRIS NIVER
REPORT DATE, 11/06/98
FCX SOIL/ WASHINGTON DOT YARD #9.6700094
SAMPLE NUMBER-152098 SAMPLE ID· SS FCX-1
DATE SN'1PLED-10/13/98
DATE RECEIVED-10/13/9B SAMPLER-ROBERT ELLIS
TIME RECEIVED-1610 DELIVERED BY-ROBERT ELLIS
Page l of ~ PROJECT NAME , SOIL
A:,ALYS!S
PERCENT SOLIDS
METHOD
2540G
VOLATILE ORGAl-lIC CMPNDS -SOIL 8021
BENZENE 8021
BROMOBE!,ZENE 8 0 2J.
BROMOCHLOROMETHANE 8021
BROMODICHLOROMETHANE 8021
BROMOFORM 8021
BROMOMETHANE 8021
n-BUTYLBENZENE 8021
sec-EUTYLBENiENE 8021
tert-BUTYLBENZENE 8021
CARBON TETRACHLORIDE 8021
CHLORDBENZENE 8021
CHLOROETHANE 8021
CHLOROFORM 8021
CHLOROMETHANE 8021
2-CHLOROTOLUENE 8021
4-CHLOROTOLUENE 8021
DIBROMOCHLOROMETHANE 8021
1,2-DIEROMO-3-CHLOROPROPANE 8021
1,2-DIBROMOETHANE 8021
SAMPLE
DATE
PREP
BY
ANALYSIS
DATE
10/15/98
10/15/98
BY
SAMPLE MATRIX-SO
TIME SAMPLED-1145
RECEIVED BY-CGE
RESULT UNITS
CGE 93.0 NA
ALT
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< s.o ug/kg
< 5.0 ug/ks
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5,0 ug/kg
< s.o ug/ks
< 5.0 ug/kg
< 5.0 ug/kg
PQL
~.O, BOif t.2298 • Roi.uarch Triangle Pork, NC 27709
t"lo.:,l"lc,,"le (919) 4E 7-3090
Shippini;r 1 02-A WoOd1oYinds lr\i;!.,i:Wi61 Co1.,1n · C.,,ty, NC 27~ 11
F•sl919)4o7,351S
5.0
5.0
5.0
5.0
5.0
5.0
5.0
s.o
5 .o
5 .o
5. 0
5 .0
5 .0
5.0
5.C
5.C
5.C
s.c
5.C
11/10/1998 17: 38 srn33441 ag PAGE 04
CHEMICA. ENVIRONMENTAL TE~OLOGY, INC.
ENVIRONM6NTAL ANAL YT/CAL SERVICES
?age 2 of 'i PROJECT NA.t'VJE : SOIL
CONTINUATION Of DATA FOR SAMPLE NUMBER
ANALYSIS METHOD
D!BROMOMET!WJE 8021
l.2-DICHLOROBENZENE 8021
1,3-DICHLOROBENZENE 8021
1,4-DICHLOROBENZENE 8021
DICHLORODIFLUOROMET!WJE 8021
1,1-DICHLOROETHANE -8021
1,2-DICHLOROETHANE B021
1,1 DICHLOROETHENE 8021
cis-1,2-DICHLOROETHENE 8021
trans-1,2-DICHLOROETHENE 8021
1,2-D!CHLOROPROPANE 8021
1,3-DICHLOROPROPANE 8021
2,2-DICHLOROPROPANE 8021
l,1-DICHLOROPROFENE 8021
cis-1,3-DICHLOROPROPENE 8021
trans-1,3-DICHLOROPROPEN~ 8021
ETHYLBENZENE 8021
HEXACHLOROBUTADIENE 8021
ISOPROPYLBENZENE 8021
p-ISOPROPYLTOLUENE son
METHLYENE CHLORIDE 8021
NAPHTHALENE 6021
:.-PROPYLBENZ.El',"E 8021
STYRENE 8021
l,l,l,2-TETRACHLOROET!WJE 6021
l,l,2,2-TETAACHLOROET!WJE 6021
TETRACHLOROETHENE 8021
TOLUENE 8021
1,2,3-TRICHLOROBENZENE 8021
1,2,4-TRICHLOROBENZENE 8021
1,1,1-TRICHLOROETHANE 8021
P.O Bo• 12298 • Res.earch Triangle Park, NC 27709
·;,.,1.«,,>i<'l.-,ro ,1) l ~ I 4h 7. ?.\,rt;')
152098
SAMPLE
DATE
PREP ANALYsrs
BY DATE BY RESULT UNITS PQL
< s.o ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5 0 'Jg/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< s.o ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< s.o ug/kg
< 5.0 ug/kg
Shi~ping; 102-.A. Woodwinds Industrial Cour: • Cary, NC 27511
Fa;,,; 19~ 9l <107-3515
5.0
5.0
5.0
5.0
5,0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5,0
5.0
5.0 s.o
11/10/lSSB 17:38 910334<1l 4S PAGE 05
CHEMICA1'_ ENVIRONMENTAL TE~OLOGY, INC.
ENVIRONMENTAL ANAL YT/CAL $1:RVICES
Page 3 of 4 PROJECT NAME : SOIL
CONTINl.iATJ:ON OF DATA FOR SAMPLE NlJMBER J.52098
SAMPLE PREP ANALYSIS
A.'IALYSIS METHOD DATE BY DATE BY RESULT UNITS PQL
1,1,2-TRICHLOROETHJ\NE 8021 < s.o ug/kg 5.0
TRICHLOROETHENE 8021 < s.o ug/kg 5.0
TRICHLOROFLUOROMET!IANE 8021 < 5.0 ug/kg s.o
1,2,3-TRICHLOROPROPA.'IE 8021 < 5.0 ug/kg 5.0
l,2,'l-TRIMETHYLBENZENE 8021 < 5.0 ug/kg 5.0
1,3,5-TRIMETHYLBENZENE 8021 < 5.0 ug/kg 5.0
VINYL CHLORIDE eon < 5.0 ug/kg 5.0
o-XYLEtJ'E 8021 < 5.0 ug/kg s.o
m,p-XYLENES 8021 < s.o ug/kg 5.0
ISOPROPYL ETHER (UE) 8021 < 5.0 ug/kg s.o
METHYLTERT-BUTYLETHER (MTBE) 8021 < 5.0 ug/kg 5.0
SURROGATE a 8021 99.9 percent
SURROGATE b 8021 98.8 pe:r:ce:nt
PESTICIDES/PCB'S 8080 SOIL 8080 10/19/98 AEK 10/31/98 ALT
ALDRIN 8080 < 100 ug/kg 10 0
ALl?HA-SHC 8080 < 100 ug/kg 100
BETA-BHC BOBO < 100 ug/kg 100
DELTA-BHC 8080 < 200 ug/kg 200
GAMMA-BHC 8080 < 100 ug/kg 100
CHLORDANE 8080 3280 ug/kg 400
4, 4' -DDD 8080 < 200 ug/kg 200
4,4'-DDE 8080 < 200 ug/kg 200
4, 4 1 -DDT 8080 < 200 ug/kg 200
DEJ:LDRHl 8080 < 40 ug/kg 40
EtIDOST.JLFAN 1 8080 < 200 ug/kg 200
ENDOSULFA.i.'\I II 8080 < 200 ug/kg 200
ENDOSULFAN SULFATE 8080 < )-400 ug/kg HOO
EN'DRIN 8080 < · 120 ug/kg 120
ENDRIN ALDEHYDE 8080 < 400 ug/kg 400
HEPTACHLOR 8080 < 10 0 ug/kg 100
HEPTACHLOR EPOXIDE 8080 < 1600 ug/kg 1600
Shipping· 102-A Woodwinds (nduttri.:il Coun • Carv, NC 2751 l
1111011ggs 17:38 9103344149 PAGE 05
CHEMlCAA ENVlH.ONMENTAL TEcfitNOLOGY, INC.
ENVIRONMENTAL ANAL YT/CAL SERVICES
Page 4 ot 4 PROJECT NAME , SOIL
CONTINUATION OF DAT,-. FOR SAMPLE NUMBER 152098
SAMPLE PREP .'-NALYSIS
AN/\LYSIS METHOD DATE BY DATE BY RESULT UNITS PQL
METHOXYCHLOR 8080 < 1000 ug/kg
TOXAPHENE 8080 < 4800 ug/kg
PCB-1016 8080 < 1000 ug/kg
PCB-1221 8080 < 1000 ug/kg
PCB-1232 8080 < 1000 ug/kg
PCB-1242 8080 < 1000 ug/kg
PCB-1248 BOBO < 1000 ug/kg
PCB-1254 8080 < 2000 ug/kg
PCB-1260 80 8 0 < 2000 ug/kg
PQL = Practical Quantitation Limit
Results followed by the letter J are estimated concentrations.
All results for soil and sludge samples are reported on a dry weight basis as required
by the NC DEM Laboratory Certification Section. Wet Weight Concentration=
(dry weight cone.) (percent solids)/100.
NC DENl< CERTIFICATIONS, D,/Q -96; PUBLIC WATER SUPPLY -3 7724
LABORATORY DIRECTOR d/'lt1,(_f -&:t;j..,/4 ~'91/2, _!
.".0. Box 12298 • P:eH8(Ch irillr"l91'tl PtHk, NC 27709
·, .. 1._. .... .,.,.,_,..., ,:i; n, ,., . .., ..,,., ... ,..., Shipping: 102-A Woodwinds Industrial Court • Cary, NC 27511
Cnw/010\~~~-~~1~
1000
,; 8 0 0
1000
1000
1000
1000
1000
2000
2000
11/10/1998 17:38 9103344149 PAGE 07
CHEMICA. ENVIRONMENTAL TE~OLOGY, lNC.
ENVIRONMENTAL ANAL YT/CAL SERVICES
FINAL REPORT OF ANALYSES
:-iC DOT
801 SUMMIT AVE,
GREENSBORO, NC 27405-
Attn, CHRIS NIVER
REPORT DATE, 11/06/98
FCX SOIL/ WASHINGTON DOT YARD #9,6700094
SAMPLE NUMBER· 152099 SAMPLE ID-SS FCX-2
DATE SAMPLED-10/13/98
DATE RECEIVED-10/13/98 SAMPLER-ROBERT ELLIS
TIME RECEIVED-1610 DELIVERED BY-ROBERT ELLIS
Page l of 4 PROJECT NAME , SOIL
ANALYSIS
PERCENT SOLIDS
METHOD
2540G
VOLATILE ORGANIC CMPNDS -SOIL 8021
BENZENE 8021
BROMOBENZENE 8021
BROMOCHLOROMETHANE 8021
BROMODICHLOROMETHANE 8021
BROMOFORM 8021
BROMOMETHANE 8021
n-BUTYLBENZENE 8021
sec-BUTYLBENZENE 6021
tert-BUTYLBENZENE 8021
CARBON TETRACHLORIDE 8021
CHLOROBENZENE 8021
CHLOROETHANE 8021
CHLOROFORM 8021
CHLOROMETHANE 8021
2-CHLOROTOLUENE 8021
4-CHLOROTOLUENE 8021
DIBROMOCHLOROMETHANE 8021
1,2-DIBROM0-3-CHLOROPROPANE 8021
1,2-DIBROMOETHANE 8021
SA.i'.'IPLE
DATE
PREP
BY
ANALYSIS
DATE
10/15/98
10/15/98
8Y
SAMPLE MATRIX-SO
TIME SAMPLED· 1150
RECEIVED BY-CGE
RESULT UNITS
CGE 93.4 NA
ALT
< 5.0 ug/kg
< 5,0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5,0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5,0 ug/i<g
< 5.0 ug/i<g
< 5,0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5,0 ug/kg
< 5 0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
PQL
P.O. Box 12298 • Fht$e&rcri Trlangle Park, NC 27709
T1Jler,rmno /i}13) -467-3090
Shipping: 1O2-A Woodwind:i lnduatrial Court • Cary, NC 27511
Fax 1919) -467-3515
5 .10
s .:o
5 ,10
5.0
s.o
5 .,0
5 ,10
5.0
5.0
5.0
5.0
5 ,10
5 ,10
5 .'0
5.0
5 .10
5 ,10
s ;o
5,0
l l /10/1 998 l 7: 38 9103344149 PllGE 08
CHEMICAa ENVIRONMENTAL TE~OLOGY, INC.
ENVIRONMENTAL ANALYTICAL ,SERVICES
?age 2 of ~ PROJECT NAME
CONTINlJATION OF DATA FOR SAt-lPLE ?-.'UMBER
ANP.LYSIS METHOD
DrnROMOMETHANE 8021
1,2-DICHLOROBENZENE 8021
1,3-DICHLOROBENZENE 802).
l,4-DICHLOROBENZENE 8021
DICHLORODIFLUOROMETHANE 8021
l,l-DICHLOROETHANE 802),
1,2-DICHLOROETHANE 8021
1,1 DICHLOROETHENE: 8021
cis-1,2-DICHLOROETHENE 8021
trans-1,2-DICHLOROETHENE 8021
1,2-DICHLOROPROP/\NE 8021
1.3-DICHLOROPROPANE 8021
2,2-DICHLOROPROPANE 8021
1,1-DICHLOROPROPENE 8021
cis-1,3-DICHLOROPROPENE 8021
trane-l,3-DICHLORDPROPENE 8021
ETHYLBENZENE 802l
HEXACHLOROBUTADIENE 8021
ISOPROPYLBENZENE 8021
p-ISOPROPYLTOLUENE 8021
M!lTHLYENE CHLORIDE 8021
NAPHTHALENE 8021
n-FROFYLBENZENE 8021
STYRENE 8021
l.l,l,2-TETAACHLOROETHANE 8021
1,1,2,2-TETRACHLOROETHANE 8021
TETRACHLOROETHENE 8021
TOLUENE 8021
1,2,3-TRICHLOROBENZENE 8021
l,2.~·TRICHLOROBENZE:NE 8021
1,1,l-TRICHLOROETHANE 8021
P,0. Box 12298 • Fl1J3ear::;h Triangle Park., NC 27709
f11l,1:ihonA fR '. ~; tif,7,.'':IOQ()
SOIL
152099
SAMPLE
DATE
PRE!? ANALYSIS
BY DATE BY RESULT UNITS PQL
< s.o 1.19/kg
< 5.0 ug/kg
< 5.0 ug/kg
< s.o ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5 0 \lg/kg
< 5.0 ug/kg
< 5.0 ug/kg
< s.o ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< s.o ug/kg
< 5.0 ug/kg
< 5.0 \lg/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/i<g
< 5.0 ug/i<g
< 5 0 ug/kg
< 5.0 ug/kg
< s.o ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
Shipping: 102-A Woodwind& ll"ld1,,1s\rial Co:.irt • C~ry, NC 27511
FB~ 1919l 46'.i·3G15
i 5!0
S '. 0
s:o ' 5 '. 0 s,o
5,0
s 1o
5,0
5.0
5:0
' 5.0
5.0
5 ! 0
5.0
5 .' 0
5 .' 0
5.0 s,o
S .! 0
5.0
5.0
S .: C
5.'C
5 .. C
5.C
5. C
5 , C
5.C
5. C
s .!c
5. C
11/10/1998 17:38 910334414S PAGE 09
CHEMICAA ENVIRONMENTAL TE~OLOGY, INC.
ENVIRONMENTAL ANALYTICAL SERVICES
Page 3 of 1 PROJECT NAME ; SOIL
CONTINUATION OF DATA FOR SAMPLE NUMBER 152099
SAMPLE J?REP ANALYSIS
ANALYSIS METHOD DATE BY DATE BY RESULT UNITS PQL
1,1,2-TR!CHLOROETHANE 8021
TRICHLOROETHENE 8021
TRICHLOROFLUOROMETHANE 8021
1,2,3-TRICHLOROPROPANE 8021
1,2,4-TRIMETHYLBENZENE 8021
l,3,5-TR!METHYLBENZENE 8021
VINYL CHLORIDE 8021
o-XYLENE 8021
m,p-XYLENES 8021
ISOPROPYL ETHER (!PE) 8021
METHYLTERT-BUTYLETHER (MTBE) 8021
SURROGATE a 8021
SURROGATE b 8021
PESTICIDES/PCB'S 8080 SOIL 8080 ).0/19/98
ALDRIN 8080
ALPHA-BHC 8080
BETA·BHC 8080
DELTA-BllC 8080
GA.:ViMA-BHC BOBO
CHLORDANE BOBO
4, 4 ' -DDD 8060
4 r 4' -DDE 8080
4, 4 1 -DOT 8080
DEILDRIN 8080
ENDO SULFA.'>; 1 8080
ENDOSULFAfl •T ,, 8080
ENDOSULFAN SULFATE 8080
ENCRIN B080
ENDRIN ALDEHYDE 8080
HEPTACHLOR BOBO
HEPTACHLOR BPOXJDE B080
P.O Ao-r 122£+0 • Flf?tft!!rcr. Tri-,:,9le ~llfl<, NC .27709
T,.:,..,-,, --,n • n, ,. a 7 '""''"'
< 5,0 ug/kg
< 5.0 ug/kg
< 5,0 ug/kg
< 5.0 ug/kg
< 5,0 ug/kg
< 5,0 ug/kg
< s.o ug/kg
< S,O ug/kg
< s.o ug/kg
< 5.0 ug/kg
< 5,0 ug/kg
95.7 perceni:
98.7 percent
AEK 10/31/98 ALT
< 100 ug/kg
< 100 ug/kg
< J, 0 0 ug/kg
< 200 ug/kg
< 100 ug/kg
10,200 ug/kg
< 200 ug/kg
< 200 ug/kg
< 200 ug/kg
< 40 ug/kg
< 200 ug/kg
< 200 ug/kg
< 1400 ug/kg
< 120 ug/kg
< 4 00 ug/kg
< 100 ug/kg
< 1600 ug/kg
Shipoin9: 102·A Woodwinds Industrial Co1.Jfi • C~rv. NC 27511
r:,.,,1Q1Q14~"')'.-.,:;11:.
' 5 -:O s ,. .u
5 -:O
S .'0
5 .iD
5.0
5 I• ··Y 5 .,o
s .,a
5 ,10
s. :a
-
100
100 ' 10 .□
200
100
1op
200
200
200
,;□
200
200
1400 ' 120
400
100
1600
'
11/10/1998 17:38 9103344149 PAGE 18
CHEMICA. ENVIRONMENTAL TE.OLOGY, lNc.
£NVIRONMENTAL ANAL YT/CAL SERVICES
Pase 4 of 4 PROJECT NA/-lE SOIL
CON'l:INUATION OF DATA FOR SAMPLE NUMBER l52099
SAMPLE PREP A ... 'r<.JALYSIS
ANALYSJ:S METHOD DATE BY DATE BY RESULT iJNITS PQL
METHOXYCHLOR 8080 < 1000 ug/kg
TOXAPHENE 8080 < 4800 ug/kg
PC!l-1016 8080 < 1000 ug/kg
PCB-1221 8080 < 1000 ug/kg
PCB-1232 8080 < 1000 ug/ks
PCB-1242 8080 < 1000 ug/kg
PCB-1248 8080 < 1000 ug/kg
PCE-12S, 8080 < 2000 ug/kg
PCB-1<60 8080 < 2000 ug/kg
?QL ~ Practical Quantitation Limit
Results followed by the letter J are estimated concentrations.
All results for soil and sludge samples are reported on a dry weight basis as required
by the NC DEM Laboratory--·Certification Section. Wet Weight Concentration =
(dry weigh:: cone,) lpercene solids) /100.
NC DENR CERTIFICATIONS: DWQ · 96; PUBLIC WATER SUPPLY · 37724
LABORATORY DIRECTOR Jvw.t ~~
P.O. Bo-: 12298 • Ae,earcii Triangle Park.. NC 27709
T .. 1,...,1"1,..,,..., 101 C.1 <'1k'7 •. "H'1QI",
Shipping: 102-A woodvv;nds lndvs1ri~I Coun • C~ry, NC 27511
~8~1919)467-3515
1000
4800
1000
lOOO
1000
1000
1000
2000
2 00 0
11/lB/1998 17:38 91033441 G9 PAGE 11
CHEMlCA. ENVlKONMENTAL Tr:t9NuLOGY, lNC.
€NVIRONM£NTAI.. ANAL YT/CAL S£RV/C£S
FINAL REPORT OF ANALYSES
NC DOT
801 SUMMIT AVE,
GREENSBORO, NC 27405-
Attn; CHRIS NIVER
REPORT DATE, 11/06/98
FCX SOIL/ WASHINGTON DOT YARD #9.670009~
SAMPLE NUMBER· 152100
DATE SAMPLED-10/13/98
DATE RECEIVED· 10/13/98
TIME RECEIVED· 1610
Page 1 of 4
SAMPLE ID· SS FCX·3
SAMPLER· ROBERT ELLIS
DELIVERED BY· ROBERT ELLIS
PROJECT N/>.ME SOIL
SA.i'<lPLE PREP
ANALYSIS METHOD DATE BY
PERCENT SOLIDS 2S40G
VOLATILE ORGANIC CMPNDS -SOIL 8021
SENZENE 8021
BROMOBENZENE 8021
BROMOCHLOROMETHANE 8021
BROMODICHLOROMETHANE 8021
BROMOFORM 8021
BROMOMETHANE 8021
n·BtrrYLBENZENE 8021
sec-BUTYLBENZENE 9021
tert-BlITYLBENZENE 8021
CA.~BON TETRACHLORIDE 8021
CHLOROBENZENE 8021
CHLOROETHANE 8021
CHLOROFOR!~ 8021
CHLOROMETHANE 8021
2·CHLOROTOLU8NE 8021
4•CHLOROTOLUENE 8021
DIBROMOCHLOROMETHA.~E 8021
l,2·DIEROM0·3-CHLOROPROPANE 8021
1 , 2 -D IBROMOETHANE 802).
ANALYSIS
DATE
10/15/98
10/15/99
BY
SAMPLE MATRIX· SO
TIME SAMPLED-1205
RECEIVED BY-CGE
RESULT UNITS
CGE 90.0 NA
ALT
< 5,0 ug/kg
< s.o ug/kg
< 5,0 ug/kg
< 5.0 ug/kg
< 5.0 c.g/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5,0 ug/kg
< s.o ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< s.o ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< s.o ug/kg
< 5.0 ug/kg
PQL
~.O. Box 1 2298 • Research Triangle Perk. NC 27709
·rnt.,,...1-,,.,..,., ,01..:.1 ,s.,;:·1.·tnon
S~lDi:,ing: 102-A Woodwinds lndwmial Court • Cary. NC 27511
~A~/01014~?.~~1~
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5. o
s.o
5.0
5.0
5,0
5. 0
s.o
5.0
5.0 s.o
1111011ggs 17:38 PAGE 12
CHt:MlCAa ENVlRONMENTAL TEt9NOLOGY, lNc.
ENVIRONMENTAL ANAL YT/CAL SERVICES
Page 2 of 4 PROJECT NAME , SOIL
CONTINUATION OF DATA FOR SAMPLE NUMBER 152100
SAMPLE
ANALYSIS METHOD DA'.l'E
DIBROMOMETHANE B021
1,2-DICHLOROBENZENE 8021
1,3-D!CHLOROBENZENE 8021
l,4-DICHLOROBENZENE 8021
DICHLORODIFLUOROMETHANE 8021
1,1-DICHLOROETHANE 8021
1,2-DICHLOROETHANE 8021
1,1 DICHLOROETHENE 8021
ClS·l,2-DICHLOROETHENE 8021
trans-1,2-DICHLOROETHENE 802).
1,2-DICHLOROPROPANE 8021
l,3-DICHLOROPROPANE 802).
2,2-DICHLOROPROPANE 8021
1,1-DICHLOROPROPENE 8021
cis-1,3-D!CHLOROPROPENE 8021
trans-1,3-DICHLOROPROPENE 8021
ETHYLBENZENE son
HEXACHLOROBUTADIENE 8021
ISOPROPYLBENZENE 8021
p·ISOPROPYLTOLUENE 8021
METHLYENE CHLORIDE 8021
NAPHTHALENE 8021
r.-PROPYLBENZENE 8021
STYRENE 8021
1, 1, 1, 2 -TETRACHLOROET!'.ANJ;: 8021
l,l,2,2·TETRACHLOROETHANE 8021
TETRACHLOROETHENE 8021
TOl.UENE 8021
1,2,3-TRICHLOROBENZENE 8021
1,2,4-TRICHLOROBENZENE 8021
1,1,1-TRICHLOROETHANE 8021
~.O, Ar;H1 12298 • Rr,,rnarch Triangle Pnr~, NC 27709 .,._ ' --.. - --,,.. ' .-. ... ~.., .............
PREP ANALYSIS
BY DATE SY RESULT UNITS PQL
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< s.o ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< s.o 'Jg/kg
< s.o ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< s.o ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< s.o ug/k9
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
Shipr,ing· 102-A Woodwinds Industrial Couri • CMv, NC 27511
l=nw IQ i g\ t.~7-'.Hi 1 !;
5 0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
s.o
5.0
5.0
s.o
5.0
5.0
s.o
5.0
s.o
5.0
5.0
5.0
5.0
5.0
5.0
s.o
5.0
5.0
5 0
5.0
5.0
11/10/1998 17:38 9103344149 PAGE 13
CHEMICA. ENVIRONMENTAL TE.OLOGY, !NC.
ENVIRONMENTAL ANAL YT/CAL SERVICES
Page 3 of 4 l?ROJECT NAME SOIL
CONTINUATION OF DATA FOR SAMPLE NUMBER 152100
A."!ALYSIS METHOD
1,1,2-TRICHLOROETHANE 8021
TRICHLOROETHENE son
TRICHLOROfLUOROMETf!ANE 8021
1,2,3-TRICHLOROPROPA.~E 8021
1,2,4-TRIMETHYLBENZENE 8021
1.3,5-TR!METHYLBENZENE 8021
VINYL CHLORIDE .8021
o-XYLE~E eon
m, p-XYL!lNES 8021
ISOPROPYL ETHER IIPE) 8 021
METHYLTERT-BUTYLETHER (MTBE) 8021
SURROGATE: " 902),
SURROGATE b 8021
PESTICIDES/PCB'S 8080 SOJ:L 8080
ALDRIN 6080
ALPHA-BHC 8080
BETA-BHC 8080
DELTA-BHC 9080
GAMMA-BHC 6080
CHLORDANE 8080
4, 4 1 -ODD 6080
4, 4' -ODE 8080
4,4'-DDT 8080
DEILDRIN 8080
ENDOSULFA.'l l 9090
ENDOSULFAN II 8060
ENDOSULFAN SULFATE 8080
E1'WRIN 8080
ENDRIN ALDEHYDE 8080
HEPTACHLDR 8080
HEl?T-ACHLOR El?OXIDE 8080
P 0. Box 1 2298 • Research Triangle, Peirk,. NC 27709
r ,.1,,., ,-,, ,,,. /41 P\ I:. h '7 •. lrlQO
SAMPLE PREP P.NALYSIS
DATE BY DATE BY RESULT lJN'ITS
< 5.0 \.lg/kg
< s.o ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< s.o ug/kg
< 5.0 ug/kg
< 5.0 ug/kg
< s.o u9/kg
< 5.0 ug/kg
< 5.0 \.lg/kg
< 5.0 ug/kg
100 percent
96.7 percent
10/19/98 AEK 10/31/98 Af.T
< 100 ug/kg
< 100 ug/kg
< 100 ug/kg
< 200 ug/kg
< 100 ug/kg
4890 \.lg/kg
< 200 ug/kg
< 200 ug/kg
< 200 ug/kg
< 40 ug/kg
< 200 ug/kg
< 200 ug/kg
< 1400 ug/kg
< 120 ug/kg
< 400 ug/kg
< 100 ug/kg
< 1600 ug/kg
Shipping: 102-A Woodvv1nds lrid1,1s1~ial Covrt · CtHY, NC 27511
Fax(919)467,3S1S
s.o
5.0
5.0
5.0
s.o
5.0
5.0
5.0
5.0
5.0
5.0
100
100
100
200
100
40C
20C
20C
20(
4C
20C
20C
140(
l L l
40(
10(
16 0(
11/10/1998 17:38 9103344149 PAGE 14
CHEMICAA ENVIRONMENTAL TEca~oLOGY, INC.
ENVIRONMENTAL ANAL YT/CAL Sl:RV/Cl:S
Page 4 of 4 PROJECT NAME , SOIL
CONTINUATION OF DATA FOR SAMPLE N'JMBER 152100
SAMPLE PREP A1-TALYSIS
ANALYSIS METHOD O.l\TE BY DATE BY RESULT UNITS PQL
METHOXYCHLOR 8080 < 1000 ug/kg
TOXAPHENE 8080 < 4800 ug/kg
PCB-1016 8080 < 1000 ug/kg
PCB· 1221 8080 < 1000 ug/kg
PCB-1232 8080 < 1000 ug/kg
PCB-1242 6080 < 1000 ug/kg
PCB-1248 8080 < 1000 ug/kg
PCB-1254 8080 < 2000 ug/kg
PCB-1260 8080 < 2000 ug/kg
PQL ~ Practical Quantitatian Limit
Results followed by the letter J are estimated concentrations.
Ali re~ults for soil and sludge samples are reported on a dry weight basis as ~equired
by the NC DEM Laboratory Certification Section. Wet Weight Concentration~
(dry weight cone.) (percent solids) /100.
NC OENR CERTIFICATIONS, DWQ -96; PUBLIC WATER SUPPLY -37724
LABORATORY DIRECTOR ~-6.-~y
P.O Box 1 7.298 • Rttseerch Triangle Park. NC 27709
"ft-•1uchr:.no W 19i t.G"J.:~oso
Shipping: 102-A Wooeh,,..inc,,: 1ndu-s1riel Cour: • Cary, ,\'C 27511
Fax(919!467-J5i5
1000
4800
1000
1000
1000
1000
1000
2000
2000
w
(')
<I fl_
(D
("} .. r---
rl
(D
CJ' CJ'
rl
' "' rl
' •4
rl
Chemical , Environmental Technology, Inc.
102-A Woodwinds Industrial Ct. Cary, NC 27511 CHAIN OF CUSTODY Page~/ of_l_
[phone] FAX: [phone]
I ANALYSES REOUIAED I
CLIENl I\.\(_ \'\1)\
Bill /J Med C,,~ ~JAME: '"··••=~"m• I TO: b: \\
Normal (2 weeks) 11.DDRESS· S, ,, ;L, ¼-2-~ Rush {1 week)'
AODRE.SS
8 0 l s l'""" .. J /\v.: bvT Y\j1
b.rc.,,_ f\S boi·o . t---J c_
D Rush (48 hours)•
'ZtL/0 ':, D Rush (24 hows)· ¼
A-Tf.NTION·ch. . N ,v<-,
PHONE:t3j0; ~-~'-j-'j2 l·S '-
r '~ FAX S>b !, ~ '-/-'11 '-l"j GJ 2v"
PROJECT N-0: PROJECT l~A.ME: I 0 <)-; / PURCHASE /. le,=! Ooo9~ ~ ~\ ('\\-W,._-:,\..,,.l\,,"" boT y,,r~)___ :::0 ORDER NO:
I"""''°"• sac
□ PRESERVATIVES LZ~"' ,,, a PR TED NAP.IE
PRESERVED IN LAB D 0
7 ---// a, o 0 ,.,zJ~ t,:.cl:,.,_, -\-_:, -Fll,5 RECEIVED ON ICE ~ w a: I 0 ci' z 0 (/) 0 0 (/) 0
CET 1f / ~A')PU I'IPE 0 "' "' r z
SAMPLE# DAT TIME SAMPLE 1.D. $~I.IPL( • !> z <fl z z I I
cou GRAB P,LI.TR(( C0-.1Ji',lFS REMARKS <C
i5"2o98 rct~fl I lu~, D< SS Fcx -I s,.\ \ rx X IX
/(tu11 \ 5;:, X SS FC.->< -'-s.,J \ IX X. X lo/M: I "
~t-10D ldfz/il ·1-05 \ p X ss f-C.X-3 Sc.I I I)< X X
lc-./f!!r, , ..
11. r IX SS FC>c -l{ So·,~ I IX ~
I )...qoe-, -1 C-__ A Vo',
F EUNq~.HS!.IED_ BY (Sig: ,aJure) DATE TIME RECEWED BY (S.gna!ure} RELINQUISHED BY (Signalure) DATE TIME RECEIVED BY (Signature)
FJ,f ~~~l BY Ys:!n~~~)
!c{t•-/r,H .lbfO
DATE TIME REC£1VE()FDR u.AtlRATORY BYc DAT, TIME AOOlTIONAL INSTHUCTIONS; '1 "-«c.l•r /;,,./ L,' ' [~µJl . lq, ~ ,y I b <,to !=cruJ,.r,'; '-' ,Ll: \ . .._,,, "I C:ci:>1
' .., .. -.... \?...«<;ullsl {:hr>,, ' N: Je.,. "Ru-,h we11l;: rt:quirci. !;Lht)r:1lm)' approval prior to ,:1mplc <iutimi-...;ion . . -\clr.Ji1ion;1J ch Lrp.:., m~1y apply.
11/10/1998 17: 38
TLI Project:
Client Sample:
Client Project:
: SpecificAnalytes"
2.3. 7 ,8-TCDD
1.2.3. 7,8-PeCDD
1,2.3.4, 7.8-KxCDP
l,2,3,6,7,8-HxCDD
1,2.3. 7.8,9-HxCDD
1,2.3.4,6,7,8-HpCDD
UJ,4,6,7,8,9-0CDD
2.3,7,8-TCDF
1,2.3. 7,8-PeCDF
2.3,4, 7,~-PeCDF
1,2.3.-1. 7,8-HxCDF
1,2,3,6, 7,8-HxCOF
2.3.4,6, 7,8-HxCDF
1.2.3. 7.8,9-HxCDF
1.2.J.4,6, 7,8-HpCDF
1,2.3,4. 7,8,9-HpCDF
1.2,3.4.6.7 .8.9-0CDF
Total TCDD
Tol.'.ll PeCOO
Tow.l HxCDD
Towl HpCDD
Total TCDF
Total PeCDF
Tol.'.ll HxCDF
Tol.'.ll HpCDF
9i03344149
46942
SSFCX-4
n/a
PAGE 15
Method 8280-A PCDD/PCDF Analysis (b)
Analysis File: VI84100
Matrix: SOIL
PCDDIPCDF SUMMARY REPORT
\Y'con:pb)'C'.:)!tou ~: ii\!il\/sia'n:pbj/f Ii!\:\l[!~/lf iif ir~~~~]il~j
1
fi~il!ijiI~f ;:;!J'.i ·
~ ~.~~ ~ . ... ...... :]1:/ t~~~~S:'.ie ;'1/nEl/ .
ND 0.03 ND :,/i· '{f' .. , ,.,
ND 0.03 ND ' . DL-The.deleclioii limit of the ·.
~/j ~.~ ~ {\ ; ~~t~hcit~'.t,a in'the
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.10
ND
l',1)
ND
22
ND
ND
ND
ND
0.0)
0.02
0.02
0.02
0,02
0,02
0.03
0.03
0.03
0.05
0,01
O.D3
0.03
0.04
O.Ql
0.02
0.02
0.03
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Page I of I
L : ~1a/4k -The coJ~ntrlt;o~ of the··-·· ..
method blaril(.
.. ND -(Non-Detect) The ··
. concentration ot the.analyte
is less than the detection
limit.
128A..PSR v\ O!, LARS 6.!I 07
Triangl11 Laboratories, lnc.s
801 Caprtola Drive • Durham, North Carolina 27713
Phone: [phone] • Fax: [phone]
Printed: 13:08 10/19/9B
62
ll/l~/1998 17:38 91 □3344149
TLI Project:
Client Sample:
Client Project:
Sample Matrix:
TL! ID:
Sample Size:
Dry Weight:
GC Column:
2.3, 7,8-TCDD
1.2.3.7,8•PeCDD
1.2.3,4,7,8-HxCDD
l.2.3,6,7,8-HxCDD -
l,2,3,7,8,9-HxCDD
l ,2,3,4,6, 7 ,8-HpCDD
1,2,3,4,6,7,8,9-0CDD
2.3,7,8-TCDF
. I ,2.3. 7 ,8-PeCDF
2,3.4,7.8,PeCDF
l ,2.3.4,7.8-HxCDF
l ,2,3.6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1.2,3.7,8,9-HxCDF
l.2,3,4.6,7.8-HpCDF
l.2,3.4, 7 .8.9-HpCDF
l ,2,3,4,6,7,8,9-0CDF
Tot::t.l TCDD
Tut.a.I PeCDD
Tullll HxCDD
Tot.a.I HpCDD
Tot.a.I TCDF
Total PeCDF
Tot::t.l HxCDF
Toi.al HpCDF
46942
SSFCX-4
n/a
SOIL
220·51·1
10.190 g
9.222 g
DB-5
Triangle Laboratories, lnc.o,
ND
ND
ND
ND
ND
0.97
18.3
ND
ND
ND
ND
ND
ND
ND
ND
ND
0. 10
ND
ND
2.2
ND
ND
ND
Pi'.IGE 1 7
Method 8280-A PCDD/PCDF Analysis (b)
Analysis File: V184100
Date Received: 10/15/98 Spike File: SP828AS0
Date Extracted: 10/15/98 !Cal: V85O12A
Date Analyzed: 10/17/98 ConCal: V183500
Dilution Factor: n/a % Moisture: 9.5
Blank File: Vl83700 % Lipid: n/a
Analyst ALW % Solids: 90.5
0.01
003
003
O.Q3
0.03
l09 32:42 1 ~
0.86 35:05
0.01
0.02
0.02
0.02
0.02
002
0.03
0.03
0.03
L02 35: 12 J -
0 18
0 0.03
0 0.03
2
0 0.04
0 0.02
0 0.02
0 0.03
Pagel of 2
801 Caprtola Drive • Durham, North Carolina 2TT13
Phone: [phone] • Fax: [phone]
Printed: 13:08 10/19/98
11/10/1998 17: 38
TLI Project:
Client Sample:
"C,,-2,3.7,8-TCDF
"Ci:-2.3.7.8-TCDD
"C,:-1,2.3.6, 7.8-HxCDD
"C.,• l,2,3.4.6. 7,8-HpCDF
"C ,,. l. 2.3.4,6. 7 ,8. 9-OCDD
"CL.-2.3.7,8-TCDD
"Ci:-1,2,3,4-TCDD
"Ci:· l ,2,3, 7,8,9-HxCDD
5103344149
46942
SSFCX-4
4.1
4,6
4,7
8,8
9.2
2.0
PAGE 18
Method 8280-A PCDD/PCDF Analysis (b)
Analysis File: VI84100
75,7 15%-150%
84.4 25%·150%
87.4 25%-150%
81.2 25%-150%
85.0 25%-150%
72.8 25%-150%
0.79
0 81
l.30
1.07
1.00
O.~O
l.32
21:50
22:36
30:05
31:55
35:05
22:37
22:24
30:21
Data Reviewer: ------------'it+'-.:.. 10/19/98
Page 2 of2 I~~ vl,OL LAR.56,ll.0"7
Triangle Laboratories, Inc."'
801 Caphola Drive• Durtiam, North Carolina 27713
Phone: [phone] • Fax: [phone]
Printed: 13:08 10/19/98
CA
11/10/1998 17:38 9103344149
TLI Project:
Client Sample:
Client Project:
Sample Matrix:
TL! ID:
Sample Size:
Dry Weight:
GC Column:
2.3.7.8-TCDD
1.2,3. 7 .8-PcCDD
1.2,3,4, 7,8-HxCDD
l.2.3.6.7.8-HxCDD
1.2.3, 7 ,8,9-HxCDD
1.2.3,-l.6, 7.8-HpCDD
!.2.3.4.6.7,8,9-OCDD
2..1.7.8-TCDF
l,2J,7,8-PeCDF
2.3A, 7,8-PcCDF
l.2.3.4.7 .8-HxCDF
1,2.3.6.7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2.3, 7,8,9-HxCDF
l.2,3.4,6. 7,8-HpCDF
1.2.3.4. 7 ,8,9-HpCDF
l.2.3.4.6.7.3,9-OCDF
46942
SSFCX-4
n/a
SOIL
220-51-1
10.190 g
9.222 g
DB-5
ND
ND
ND
ND
ND
0.97
18.3
ND
ND
ND
ND
ND
NO
ND
ND
ND
0.10
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor:
Blank File:
Analyst:
X I.
X 0.5
X 0 I
X 0.1
X 0. l
X 0.01
10/15/98
10/15/98
10/17/98
1
Vl83700
ALW
=
=
=
=
=
=
X 0.001 =
X 0.1 =
X 0.05 =
X 05 =
X 0.1 =
X 0.1 =
X 0.l =
X 0 l =
X 0.01 =
X O.Ql =
X 0.001 =
PAGE 19
~
Toxicity Equivalents Report
Analysis File: Vl84100
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
0.0097
0.0183
0.000 I 0
SPSZSAS0
VS5O12A
V183500
9.5
n/a
90.5
Total 2,3,7,8-TCOO Toxicity (1989 ITF) Equivalents: 0.0281 ppb
(1) Detection Limits not. used in calculations.
Note: 100% of EM PCs are used in the calculations.
Trlangla l,,aboratorlos, Inc."
801 Caphola Drive • Durham. North Carolina 27713
Phone: (919) 544°5729 • Fax: [phone]
Page l of I GRY _ T6P ~LO'). Mil.£5 ~.!6 D
Printed: 13: 19 10/19/96
65
Tlfil[lillFJJl~ [!L;JJin
CASE NARRATIVE
Analysis of Samples for the Presence of
Polychlorinated Dibenzo-p-Dioxins and Dibenzofurans by
High-Resolution Chromatography/ Low-Resolution Mass Spectrometry
Method 8280A Rev. 1 (12/96)
Date: October 19, 1998
Client ID: Chemical & Environmental Technology
P.O. Number: 10446
TLI Project Number: 46942
This report should only be reproduced in full. Any partial reproduction of this report requires permission from
Triangle Laboratories. Inc.
Rev. I 0/9/98
Triangle Laboratories, Inc.
801 Capitola Drive P.O. Box 13485
Durham, NC 27713-4411 Research Triangle Park, NC 27709-3485
919-544-5729 Fax# [phone]
1
Triangle Laboratories, In.
Case Narrative
Overview
• October 19, 1998
46942
The sample and any associated QC samples were extracted and analyzed according to
procedures described in SW846 Method 8280A (l 2/96). Any particular difficulties
encountered during the sample handling by Triangle Laboratories will be discussed in the
QC Remarks section below. This report contains results from only the 8280A
dioxin/furan analysis of the soil sample.
Sample Extraction
The soil sample has been extracted with toluene. Twenty percent of the final extract was
processed through cleanup procedures prior to analysis.
The cleanup of extracts may include the use of bulk acid/base washes, and acid silica, basic
silica, activated alumina, and carbon column liquid chromatography.
Sample Analysis
A five point initial calibration curve was analyzed on each instrument used for sample
analysis. Calibration ranges are listed below and are based on sample size. A continuing
calibration check and a column performance evaluation are analyzed at the beginning of
each twelve hour period of sample analysis. A sensitivity check is analyzed at the end of
each twelve hour period of sample analysis.
Compounds
TCDD/TCDF
PeCDD/PeCDF
HxCDD/HxCDF
HpCDD/HpCDF
OCDD/OCDF
Calibration Ranges
Solid (10 g sample) Water (IL sample)
ppb (µg/Kg)
l-20
2.5-50
5-100
ppt (ng/L)
10-200
25-500
50-1000
ppb (µg/L)
0.0 l-0.2
0.025-0.5
0.05-1.0
2
Triangle Laboratories, In.
Case Narrative • October 19, 1998
46942
Some of the labeled standards used in the analysis have ion fragments with the same mass
as the quantitation mass of some of the analytes. These lower mass fragments appear as
peaks or 'breakthrough' in the analyte channels. This can often be witnessed in the cases
of 11C1,-TCDF internal standard appearing in the TCDD analyte channels, 11C,,-HxCDD
internal and recovery standards appearing in the HpCDF analyte channels, and 13C,z-
HpCDF internal standard appearing in the HpCDD analyte channels. For most of the
above situations, the interfering peaks due to the labeled standards lie outside the retention
time window of the analyte. In the case of TCDD/fCDF, the interferences usually lie
within the retention time window. Whenever breakthrough peaks occur from the labeled
standards, these peaks are reported as EMPCs, and may be considered artifacts from the
labeled standards. This is a limitation caused by the use of low-resolution mass
spectromet1y, recommended in the method.
Quality Control Samples
A laboratory method blank, identified as the TLI Blank, was prepared along with the
sample. One such sample per 20 field samples or less of a given matrix is prepared.
The quality control range for internal and clean-up standard percent recoveries is 25-150
percent. The ratio of signal to noise for all standards must be greater than ten to one.
Quality Control Remarks
The release of this particular set of Chemical & Environmental Technology analytical data
by Triangle Laboratories was authorized by the Quality Control Chemist who has
reviewed each sample data package individually following a series of inspections/reviews.
When applicable, general deviations from acceptable QC requirements are identified below
and comments are made on the effect of these deviations upon the validity and reliability
of the results. Specific QC issues associated with this particular project are:
Sample receipt: One soil sample was received from Chemical & Environmental
Technology at 2 °C in good condition on October 15, 1998 and was stored in a
refrigerator at 4 °C until the time of extraction.
Sample Preparation Laboratory: None
Mass Spectrometry: None
Data Review: The internal and cleanup standard recoveries for the sample and associated
blank are within the QC limits of25-150 percent and meet ten to one signal to noise
criteria in all cases.
Other Comments: No 2,3,7,8-substituted target analytes were detected in the TLI Blank
above the target detection limit (TDL).
Triangle Laboratories, Inl)
Case Narrative • October 19, 1998
46942
By our interpretation, the analytical data in this project are valid based on the guidelines
of SW846 Method 8280A (12/96). Any specific QC concerns or problems have been
discussed in the QC Remarks section of this case narrative with emphasis on their effect
on the data. Should Chemical & Environmental Technology have any questions or
comments regarding this data package, please feel free to contact our Customer Service
Representative at (9 I 9)-544-5729.
For Triangle Laboratories, Inc.,
Released by,
2~°'--~
So..~ .... L-. A. 1-1 J b t)v-.('~
Report Preparation Chemist
The total number of pages in the data package is : /0 /
4
Triangle Laboratories, Ini,)
Case Narrative
Sample Calculations:
• October 19, 1998
46942
Analyte Concentration The concentration or amount of any analyte is calculated using the
following expression:
C<ai = --------------------
Ap * RF<n> * W
Where:
C<a> is the concentration or amount of a given analyte,
A0 is the sum of the integrated current for the characteristic ions of the analyte,
Ap is the sum of the integrated current of the characteristic ions of the corresponding
internal standard,
Qp represents the amount of internal standard added to the sample before extraction,
RF,,,> is the analyte relative response factor from the continuing calibration (ccal) and,
Wis the sample weight or volume
Detection Limits The detection limit reported for a target analyte that is not detected or
presents an analyte response that is less. than 2.5 times the background level is calculated
by using the following expression. The detection limits represent the maximum possible
concentration of a target analyte that could be present without being detected.
2.5 * (H) * Qp
DL<a> = --------------------------
Hp* RF1,> * W
Where:
Qp , RFc,> , and W are defined above,
2.5 is the minimum response required for a GC signal,
H is the sum heights of noise of the characteristic ions,
Hp is the sum of the heights of the corresponding internal standards
5
Triangle Laboratories, In.
Case Narrative
Data Flags
• October 19, 1998
46942
In order to assist with data interpretation, data qualifier flags are used on the final reports.
Please note that all data qualifier flags are subjective and are applied as consistently as
possible. Each flag has been reviewed by two independent Chemists and the impact of the
data qualifier flag on the quality of the data discussed above. The most commonly used
flags are:
A 'B' flag is used to indicate that an analyte has been detected in the laboratory method
blank as well as in an associated field sample. The 'B' flag is used only when the
concentration of analyte found in the sample is less than 20 times that found in the
associated blank. This flag denotes possible contribution of background laboratory
contamination to the concentration or amount of that analyte detected in the field sample.
An 'E' flag is used to indicate a concentration based on an analyte to internal standard
ratio which exceeds the range of the calibration curve. Values which are outside the
calibration curve are estimates only.
An 'I' flag is used to indicate labeled standards have been interfered with on the GC
column by coeluting, interferent peaks. The interference may have caused the standard's
area to be overestimated. All quantitations relative to this standard, therefore, may be
underestimated.
A 'J' flag is used to indicate a concentration based on an analyte to internal standard ratio
which is below the calibration curve. Values which are outside the calibration curve are
estimates only.
A 'PR' flag is used to indicate that a GC peak is poorly resolved. This resolution problem
may be seen as two closely eluting peaks without a reasonable valley between the peak
tops, overly broad peaks, or peaks whose shapes vary greatly from a normal distribution.
The concentrations or amounts reported for such peaks are most likely overestimated.
A 'Q' flag is used to indicate the presence of QC ion instabilities caused by quantitative
interferences.
An 'RO' flag is used to indicate that a labeled standard has an ion abundance ratio that is
outside of the acceptable QC limits, most likely due to a coeluting interference. This may
have caused the percent recovery of the standard to be overestimated. All quantitations
versus this standard, therefore, may be underestimated.
6
Triangle Laboratories, In.
Case Narrative • October 19, 1998
46942
An 'S' flag indicates that the response of a specific PCOO/PCOF isomer has exceeded the
normal dynamic range of the mass spectrometer detection system. The corresponding
signal is saturated and the reported analyte concentration is a 'minimum estimate'. When
the 'S' qualifier is used in the reporting of 'totals', there is saturation of one (not
necessarily from a specific isomer) or more saturated signals for a given class of
compounds. Results for saturated analytes are reported as greater than the upper
calibration limit.
A 'U' flag is used to indicate that a specific isomer cannot be resolved from a large, co-
eluting interferent GC peak. The specific isomer is reported as not detected as a valid
concentration cannot be determined. The calculated detection limit, therefore, should be
considered an underestimated value.
A 'V' flag is used to indicate that, although the percent recovery of a labeled standard may
be below a specific QC limit, the signal-to-noise ratio of the peak is greater than ten-to-
one. The standard is considered reliably quantifiable. All quantitations derived from the
standard are considered valid as well.
An 'X' flag is used to indicate that a polychlorodibenzofuran (PCOF) peak has eluted at
the same time as the associated diphenyl ether (OPE) and that the OPE peak intensity is at
least ten percent of the total PCOF peak intensity. Total PCOF values are flagged 'X' if
the total OPE contribution to the total PCOF value is greater than ten percent. All PCOF
peaks that are significantly influenced by the presence of OPE peaks are either reported as
"estimated maximum possible concentration (EMPC) values without regard to the isotopic
abundance ratio, or are included in the detection limit value depending on the analytical
method.
7
TRIANGLE LABO RA TORIES, INC.
LIST OF CERTIFICATIONS AND ACCREDITATIONS
ENVIRONMENTAL
American Association for Laboratory Accreditation. Accredidation pending. Certificate
Number 0226-01. Accreditation for technical competence in Environmental Testing. (Including Waste Water, Sol/Haz Waste, Pulp/Paper, and Air Matrices) Parameters are AOXITOX, and Dioxin/Furan. Method 1613 for Drinking Water Currently re-applying ..
State of Alabama, Department of Environmental Management. Expires December 31, 1998. Laboratory I.D. # 40950. Dioxin in drinking water.
State of Alaska, Department of Environmental Conservation. Expires December 21, 1998. Certificate number OS-006-98. Dioxin in drinking water.
State of Arizona, Department of HeaJth Services. Expires May 26, 1998. Certificate #AZ0423. Drinking Water for Dioxin, Dioxin in WW and S/H Waste. Currently appying for renewal.
State of Arkansas. Department of Pollution Control and Ecology. Expires February 19, 1999. Pulp/paper, soil, water, and Hazardous Waste for Dioxin/Furan; AOXITOX, Volatiles, Semi-volatiles, and Metals.
State of California. Department of Health Services. Expires August 31, 1999. Certificate #1922. Selected Metals in Waste Water; Volatiles, Semi-volatiles, and Dioxin/furan in WW and Sol/Haz Waste. Dioxin in drinking water.
State of Connecticut, Department of Health Services. Expires September 30, 1999. Registration # PH-0117. Dioxin in drinking water.
Delaware HeaJtb and Social Services. Expires December 31, 1998. Certificate #NC 140.
Dioxin in drinking water.
Florida Department ofHeaJtb and Rehabilitative Services. Expires June 30, 1998. Dioxin in SDW. Drinking Water ID HRS# 87424. Pending new certificate.
Triangle Laboratories, Inc.
801 •capita/a Drive P.O. Box 13485 Revisod8/J/98du
y: certific\certlist. mem Durham, NC 27713-4411 Research Triangle Park, NC 27709-3485 919-544-5729 Fax# [phone]
8
•
Hawaii Department of Health. Expires March I, 1999. Dioxin in drinking water. "Accepted"
status for regulatory purposes.
Idaho Department of Health and Welfare. Expires December 31, 1998. Dioxin in drinking
water.
State of Kansas, Department of Health and Environment. Expires January 31, 1999.
Method 1613 for drinking water. ID #'s -Drinking water and/or pollution control -E-10215.
Solid or Hazardous Waste -E-101209.
Commonwealth of Kentucky, Department for Environmental Protection.
Expires December 31, 1998. ID#90060. Dioxin in drinking water.
Maryland Department of Health and Mental Hygiene. Expires September 30, 1998.
Certification #235 Drinking water by Method 1613A. Currently applying for renewal.
State of Michigan, Department of Public Health. Expires June 30, 1999. Drinking water by
Method 1613. Current certification is extended, based on New York certificate renewal.
Mississippi State Department of Health. No expiration date. Dioxin in drinking water.
Montana Department of Health and Environmental Services. Expires December 31, 1998.
Dioxin in drinking water.
State of New Jersey, Department of Environmental Protection and Energy. Expires June 30,
1998. Extended until July 31, 1998 per letter dated May 29, 1998. ID #67851. BNAs and
Volatiles. Dioxin in drinking water. Currently applying for renewal.
State of New Mexico, Environment Department. Still certified, awaiting information from
A2LA Dioxin in drinking water.
New York State Department of Health. Received updated certificates. ID #I 1026.
Environmental Analyses of potable water, non-potable Water, Solid and Hazardous Waste.
Method 1613 in DW.
State of North Carolina, Department of Environment Health and Natural Resources
Expires. August 31, 1998. Certificate# 37751. Dioxin in drinking water.
State of North Carolina, Department of Environment, Health, and Natural Resources,
Division of Environmental Management. Expires December 31, 2000. Certificate# 485 .
. __ Metals, pesticides & PCBs, semi-volatiles and volatiles; TCLP.
Remod 613198 dss
y:certific\certlist.mem
9
•
North Dakota State Department of Health and Consolidated Laboratories. Expires
December 31, 1998. Certificate# R-076. Effective October 4, 1993. Dioxin in drinking water.
Oklahoma Department of Environmental Quality. Expires August 31, 1998. Laboratory
#9612. Dioxin by 1613A, 8290 and 8280. Submitted renewal application 7/1.
State of South Carolina, Department of Health and Environmental Control. Expires
June 30, 1998. Extended August 31, 1999. Certificate number #99040001 (drinking water).
Expires August 31, 1999. Certificate number #99040002 (other parameters). Dioxin/Furans,
BNA, Volatiles, and PCBs/pesticides under Clean Water Act, 2,3,7,8-TCDD for Drinking Water,
and Organic extractables for Solid and Hazardous Waste.
State of Tennessee. Department of Environment and Conservation. Expires
February 5, 1999. ID #02992. Method 1613 Drinking water only.
U.S. Department of Agriculture Soil Permit. Expires September 30, 200 I. Permit No. S-
3790. Under the authority of the Federal Plant Pest Act, permission is granted to receive foreign
soil samples for use in laboratory analysis.
U.S. Army Corps of Engineers. Expires October 19, 1999. Validated to perform analyses for
the Fort Belvoir, VA (Contract Number DACAJ l-97-D-0029), Vint Hill Farms Station, Vint Hill,
VA (Contract Number DACAJ l-95-D-0083), and Selma Pressure Treating Superfund Site,
Selma, CA (Contract number DACW45-94-D-0054).
U.S. EPA Region V. Expires November 14, 1999. Dioxin in drinking water.
U.S. EPA Region VIlI, for the State of Wyoming. Expires November 12, 1998. Dioxin in
drinking water.
State of Utah, Department of Health. Expires May 30,2000. Certificate Number E-166.
Certification for the following parameters: Semi-Volatiles and Volatiles under RCRA; Volatiles
under Clean Water Act; Dioxin/furans by Method 8280; Drinking water for Dioxin by Method
1613; Metals including Mercury and Microwave Digestion.
Commonwealth of Virginia, Department of General Services, Division of Consolidated
Laboratory Services. Expires June 30, 1999. ID# 00341. Dioxin in drinking water.
State of Washington, Department of Ecology. Expires September 11, 1998. Lab
Accreditation Number C067. Scope of Accreditation applies to water analyses for
R8'M8CI 8/3198 ~
y: certific\certl ist. mem
10
• •
Polychlorinated Dibenzo-p-dioxins and Polychlorinated Dibenzofurans, BNA Extr (Semivolatile)
Organics and Purgeable (Volatile) Organics.
State of Washington, Department of Health. Expires April 30, 1999. Dioxin in drinking
water. Lab I.D. 129.
State of West Virginia, Department of Health. Expires December 31, 1998. Certificate No.
9923(C). Dioxin in drinking water.
State of Wisconsin, Department of Natural Resources. Expires August 31, 1998. Laboratory
ID Number 999869530. Certification for the following categories of Organics: Purgeable,
Base/Neutral, Acid, PCBs, and Dioxin. Expires November 14, 1999. Laboratory ID 999869530.
Dioxin in drinking water.
PHARMACEUTICAL
Drug Enforcement Agency (DEA). Expires November 30, 1998. Registration number
RT0l 195835. Controlled substance registration for schedules l,2,3,3N,4,5.
N.C. Department of Human Resources. Expires October 31, 1998. Registration number
NC-PT 0000 0031. North Carolina controlled substances registration. Application submitted for
renewal.
Food & Drug Administration (FDA) Registration. Expires June 1998. ID #'s 001500
1053481. Annual registration of drug establishment.
OTHER
Clinical Laboratory Improvement Amendments (CLIA) Registration. Expires May 30,
1999. ID# 34D07051-23. Department of Health & Human Services, Health Care Financing
Administration.
U.S. EPA Large Quantity Hazardous Waste Generator. No expiration date. EPA ID
#NCD982156879. Permit indicates that the laboratory is a large generator of hazardous waste.
North Carolina General License for Radiation Protection. No expiration date. No License.
032-875-OG. The general license applies only to radioactive material contained in devices which
have been manufactured and labeled in accordance with specific requirements.
Revised 8/3198 dso
y:certific\certlist.mem
11
i)
DOCU1.,!ENT
I CONTROL \;___ __ ____;
Trtang1a ub:i.Af "inc.
sat C ► 1 -'e l'lrM P.C. llar 13Gf Olirftam. !IC zn1:J-U11 n cA n....., Fa1r. ~
91$-0ff5729 Fa#919 sec 5191
..
,: 12
I CLIENT CHAIN OF CUSTODY SAMPLER'S SIGNATURE Quote 0711070116
From (1): Chemical & Environmental Technology Contact: Link 11-uower Analysis Wanted (2): Total Number of
102A Woodwinds Indus. Court Phone, 919 / 467-3090
0
Containersl
Cary, NC 27511 Faxc 919/467-t:15 0 CD ' .... 0 Project (1): dioxin in soil P.O.#(!) ] 0 'f-~ I-M ' Turn Around Time < I-N
0 0 0 (In Calendar Days),
CD 0) 0)
NorMA./ (CET01 /UN) If the data will be reported to a state agency, which one? __ N N N CD CD CD
Sample ID (3) Date I Time Preservation (4) Matrix Sample Amt. I)( Remarks
55 Fc.'f-_-4-)b 113
I Mt l~'./0 ,!_lfoc__ Sui I 'fl tlie,J-rJJ 5,,--J;,._
I
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-7'/ --. Io 1¥/'li /b:, ~ -' ·v ,,,-,
Received for Laboratory By/Signature I Date/Time Send Samples to: Triangle Laboratories, Inc.
o(tslfl a/,, -dlwtn -
I~ o ?).,4,,
Directions: " ' (!) Provide and/or correct client and project information.
(2) Verify analysis, check approriate boxes for each sample.
Attn: Sample Custodian
801 Capitola Drive
Durham, NC 27713 USA
Phone: [phone] • Fax: [phone]
(3) Enter the sample ID to be used when reporting the samples.
(4) Please indicate _the preservation used for each sample.
I
1: ~?}o ,--CU-a t_o_d_y-Se_a_l ____ P_r_e_e_en_t_/_l_n_t a-c-,---S,~m~p~l~e-S~e-Ta 1:: ~~~: e~BORATOR I ES• JUC. --LOG IN RECORD/CHA Iii ~I!: I C~!:~~;r•t-Nu~,-,i,~e~,-~,~6~94~2------------'7"'~8-oo~k-,,II
U U Chain of Custody Present Container. .. : Intact I Client: CETOl -Chemical &. Environmental Technology I/
II Sample Tags Absent I 220 R
,i I], .. ,;
" 'I
'
II Sample Tag Numbers: Not Listed on Chain of Custody \
II SHO Forms N/A Date Received 10/15/98 I By Page 11
11---------------------------------+-------+------'--~'U;t,q,'/A,L..tJZ,-1 II
H lee Chest ICE Temp 2.0 C Carrier and Number UPS 51 I\
li================~==-,===..=====r=-k--,===,,--a!-==r==~===s--..b--\
[ITLI Number ...... Client Sample ID ................... Matrix I To LAB I To STORAGE I To LAB To STORAGE I To LAB To STORAGE[ To LAB To STORAGE I DISPOSED I]
1\mR/H:CPM. . .Client COC ID., .... • Location ...... -1 Date/Init I Date/Init I Date/Init. Date/Init I Date/Jnit Oale/Init I Date/Init Date/In it I Date/Init II
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liMr:ANGLE LABORATORIES, INC. •
SAMPLE T~CKING AND PROJECT MANAGEMENT"'l!"'ORM
-------------------------ADMINISTRATIVE
TLI Proj#: 46942-Samples: 1
INFORMATION-------------------------
TurnAround.: 21 Day(s)
Prod Code: D66011 Matrix.: SOIL Hold Time .. : 30 Day(s)
DetectLim: 1 ppb Type ... : B Start Date.: 10/15/98
Recvd .. : 10/15/98 Ship By .... : 11/03/98
DWL Due Dt.: 10/28/98
Analyte List.: Tetra -Octa
Method ....... : 8280A Tetra-Octa Dioxin/Furan
Client Proj .. :
Client ....... : Chemical & Environmental Technology (CETOl)
P.O. No ...... : 10446 Collect Dt/Trn: 10/13/98 12:10
919/467-3090
919/467-3515
Contact ...... : Arun Schendrikar Phone ........ :
Proj. Mgr .... : Fax .......... :
Sample Origin:
-------------------SPECIAL INSTRUCTIONS/ QA REQUIREMENTS-------------------
Prespike Standard: n/a
Extraction Exp ... : 11/12/98
---------------------------REPORTING REQUIREMENTS---------------------------
Reporting Format: Report Option II
See MILES for Instructions/Communications.
Completed
Reviewed b ,:..______, L..__'3 "-f~J-.-
DATE:
DATE:
~8
J0//5J'77 (PMGT0197
I
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713 Printed: 14:49 10/15/98
Phone: [phone] • Fax: [phone]
15
•------------------------------------------•-----------------------------------------•---------------------------------------•
TRIANGLE LABORATORIES. INC. PAGE 1 OF l
Dioxin Sample Preparation Tracking & Management Fann
Project: 46942 Client: Chemical & Environmental Technology (CET0ll
•----------------------------------------------------------------------------------------------------------------------------~-;---•
I Solvenc<s) /Acid (s), To/,,m~ I ,';7'1/-I ,% Method, 8280A Tetra-Octa Dioxin/Furan Matrix, s;, _ I
I Lot. Numbers: Y!-to )qf.f)Vp I ~~--I ----Extraction Date: /d I .:d.[) ~ I
~: :::::: 100 :: ::::: ~:5000 ::;:: ;-----i,-;;---~;-~---;-------------;~~:~::;-:
MS Spike, 250 µl cone, 0.1000 ng/µl I 6161/T i 6:J.9S-IV I ~ I _____ !Spike• I
I LCS Spike, 250 µl cone, 0.1000 ng/µl I s:z.sc,. J: I ~-/77;( I ~ I -----I " ID I
'.-~~~-~:'.~::_~~'._:'._::::: __ ~'.:'.'.~-:~~:'. _______ ·---------•--------'. i_ ;;S-;g:; ;~;g: t ;1 ;~: ; ; : ":::rl
I I TLI / I GROSS I SAMPLE I !..Z ' ~ I / 7 , ~ I J.:J... , ~ I I Time
IS~ crdl SAMPLE / CLIENT I WEIGHT I SIZE IO~ng/µl l CJ,/ ng/µl l~ng/µ1 I __ ng/µl I Cone.
I ID / SAMPLE ID I Before After I 9 / ml I / vc? µl I :iro µl I (OP µl I ___ µl I Vol.
'.'.'.'. ___ !_:::_::~~----~~'.-~:'.'.~-~'.:~_! ____ ~ ___ !_~----~~ol.f_'. _____ f?c_~_'.v~~------'.-------µ __ '. _____________ '.5'.
I I 220-51-1 . I I I I I \•' I I (Any Leftl
I 001 I ssFCJ<-< I ,t<;-7,,:;·6' I j IO I 1( C -z_ I < I q , I t£J}no I •------•------------------------------•---__ : _ --._:?-ff,,:,__,_,_ :/.7 __ • __ -------------------------•-------'JM----·-------------•--------•
I I I I I I I I I Any Left I
I I I I yes/no I
IAny Left.I
! yes/no I
·------♦----------------·-····-····-•-♦·-··---•-♦••·-··---•···-··•-♦••········-······---------------------------------·-·-···--·----♦
I ..
I
(Any !..eftl
I yes/no I
\Any Leftl
I yes/no I
•---·-·•----···-----··-·-·---·--··--··+·---··-·-•-----·--·•-----·--•-------------♦---·-···-·•-•♦-••·······-·····-····-··---•··-···--•
IAny Leftl
I yes/no I
•-·--•-♦--··--·----·--···-··-·---·--··•··--··---•------·--•······--+-·-·----···-·•·---·-····-••+-••--·-··---·•-·---·--·-·-·•·····---•
--1
!Any Leftl
I yes/no I
♦-•··•-♦•--··--···--··--··--··-·····•-+···------•------•-•+----··•-♦-••··········•···--·-·--···+-••·-···-··--•-----····-·-·+·--·····•
IAny Leftl
I yes/no I
·-·---·+·-·-·--·-···--··-----·····----•---·-·-----·---··•-♦-·-·--··•-·--·--··----•·---·----·---♦-------------♦•-----··----·+-··--····
!Any Leftl
I yes/no I
+··-···•-------··--·----·-·----·-----·+---··----•·---··•--♦•----·--•···----------•····---·-----•·----------•-♦----·-·-·-··-+·------·•
Gross weight of sample container+ sample before/after aliquot removal.
Co""'encs~,., .s;;,.eL 114<-f-L/4:./ /41# ?xm::r::
1>11.-1/J OCnM J fn/4--e-, ,k'c:z. l~U0s
I ~4'&°? £'.!? -;:tJ{:z_ -"'/11::lr& Initials Date _/_/_ I
•-----------------------------------------------------------------------------------------------------------------------------------1
I Initials of both SPIKER AND OBSERVER must be entered. XXXXX • Gross Weight not provided for WATER Samples. I
+••---------·---·--·--·········-····-······-·--------------··--·---··--··-········---------··-·----·----·-·-REV 05/27/97 (PSTMF 7)•-•
1G
I • I
!
I
PAGE 1 OF l
+--------------------------------------~-------------------------------------------------------------------------------+
j TRIANGLE LABORATORIES, INC.
I DIOXIN SAMPLE EXTRACTION and CLEANUP TRACKING FORM
I TLI Project No.: 46942
1=====3=============+========+========+========+========+========+=====~ =====+========+========+========+========I
i.:'.'..::'.: .. ::: ... !.i ..... !.~ .. 2 .... !J ... : .. ~~; ... J.,§: ... ! ........ ! ........ ! ........ i
!:~::ii::·:::::·:::~f ;i::· __ ::\1'':i'1~:\:1~:\~~~t:::i:'
01
t:\i::::::::l::::::::l::::::::!
I
I
!-------------------+--------+--------+--------+--------+--------+--------+--------+--------+--------+--------+--------\
1-------------------+--------+--------+--------+--------+--------+--------+--------+--------+--------+--------+-~------1 I.
1-------------------+--------+--------+--------+--------+--------+--------+--------+--------+--------+--------+--------I
1-------------------+--------+--------+--------+--------+--------+--------+--------+--------+--------+--------+--------I
1-------------------+--------+--------+--------+--------+--------+--------+--------+--------+--------+--------+--------I
Enter the procedure number below into the box at the top of each column to signify the step performed.
Initial and date each sample for each numbered procedure performed.
iL ..... PROCEDURE .... SOP.# .. v .. DETAILS (circle) ty EXTRACTION ~ _.:l.._ Time On/~ : G-0 Time Off /0 : 0-C,
Soxhlet /Jar/ Sep Funnel/ Steam Dist/ Cont LL/ ASE/ Waste Dilution
I ~SPIKE AFTER EXT'N
I @no TRIDECANE
I ~ROTOVAP
Lot# re--:L ' I . 1 · 12+,
4 0mL / l 0mL / ~
I 5) COMBINE
I @□rV./LIP. DETERM. == ~ 50\-/,qt SmL/20mL Other
J ~ SOLVENT EXCHANGE p_so-0 ne Lot#'-1 Bvq«o Heptane Lot-#~~~~---
1 60:LEANUP n--, 1 SP 260 / DSP 225 / DSP 115 / DSP 215 / DSP 267 /
I ~SFER c/...:1E',..
I 10) ADDITIONAL CLEANUP __ Mod. CSP 260 / DSP 225 / DSP 115 / DSP 215 / CSP 267
! 11) FINAL TRANSFER
Other
/ DSP260 (10g)
Comments: -----------------------------------------------I I
17
Date: 10/15/98
Time: 16:57
Sample
# crd TLI_Number. customer.Sample.Id.
f---
00
000
001
TLI Blank
220-51-1
End of Report
TLI Solid Blank
SSFCX-4
Wet
Init. NaOH Adj.
pH. mL .. pH.l.
n/a n/a n/a
n/a n/a n/a
TRIANGLE LABORATORIES, INC.
Lab Extraction and Observations
Project: 46942
H2S04 Adj.
mL. pH. 2. Appearance. Color ..
n/a n/a Na2S04
n/a n/a norm. text. brown
PRDPERC v4.01
Page: l
Odor ... Val. Entered.By ...... Date .... Time .... S
0 CARROLL
dirt 0 CARROLL
10/15/98 16:57:18 F
10/15/98 16:57:18 F
•
Date: 10/17/98
Time: 08:16
Sample Empty
~ crd Vial.Wt
001 14.8785
14. 8785
14.8785
14.8785
Wet Vial Dry Vial
Weight ... Weight ...
22.0670 21.3806
22.0670 21.3855
22.0670 0.0000
0.0000 0.0000
Percent Moisture/Solid Summary
TRIANGLE LABORATORIES, INC.
Percent Moisture/Solid Calculations
Project: 46942
Entered. By ...... Date .... Time ....
PENDERGRAFT 10/16/98 10:57:43
BAILEY 10/16/98 06:19:39
THORNE 10/15/98 15:39:20
THORNE 10/15/98 15:29:58
•
\Moist
9.5
\Solid
90.5
PRDPERC v4.0l
Page: 1
Valid Weight Target
From ..... -To ....... Weight.
10.6077-11.4917 11.0497
TLI.MILES.ID .... TLI.Number .. Client.Id Number ......... \Moist \Solid ExtrctWt DryWtEqu RPO ..
46942--001 220-51-1 SSFCX-4 9.5 90.5 10.190 9.222
••• End of Report •••
• PAGE 1 OF 1
+-------------------------~----------------------------------------------------+
TRIANGLE LABORATORIES, INC.
Transfer Chain-of-Custody Form
Project 46942
Transfer From: DWLI5 To: OMSSS
Released by:
r!//Dials .. Dlb~fr~1i
Accepted by: /?.,J 10 ! I? I .5X_
Time ...
~,?JD
Jh__: JO
+------------------------------------------------------------------------------+
MILES. ID. . . . . . . . TLI No. . . . . . Cust. Id ................. .
46942-
..,-(5942-
-000
-001
TLI Blank
220-51-i"
TLI Solid Blank
SSFCX-4
+-------------------------------------------------------XfrCOC (Rev 11/01/94)--+
Additional comments or instructions:
20
Method: 8280A Tetra-Octa Dioxin/Furan
Required Detection Limit: l ppb
1ST COLUMN
• TRIANGLE LABORATORIES, INC.
HR GC/HRMS ANALYSIS
SAMPLE INFORMATION
2ND COLUMN
PAGE l OF 1
+-------------------+
! PROJECT: 46942
RS Cone:
20 µl ~ 0.5 NG/µl
TLI I I GC/MS FILENAME !CONFIRM !CONFIRM FILENAME IUSF-RS
I COLUMN, l)i:1'5 I I COLUMN,___ I VOLUME
IUSF-RS !ANALYSIS
!S#.crdj SAMPLE ID /
I I
CLIENT
SAMPLE ID
I INIT. I COMMENTS
I I I ISOLN IO IDATE
•----------------------------------------------------------------------------------------------------------&----------------------•
I I TLI Blank I I I I ~ kA~d o/Y<,"(:f'1A I
I ooo I TLI Solid Blank I YJ:,?,?/700 I I I ~I I
•-----------------------------------------------------------------------------------------------------------------------------------+
1 I 220-s1-1 I I I ;l0.4:f. I -;efw I
1001 1 ss•cx-• 1 YI<i;'-/-:Joo 1 1 1 lDilosA 1 ,oJ,,fjt 1
♦-----------------------------------------------------------------------------------------------------------· ·--------------------♦
I I I I
I I I
♦-----------------------------------------------··-------------------·-----··-·-·----··-----·--··----·---··-·--·······-·---····-----♦
--------···-·------------····--·-·-···----··----··--··--··-·--·--·-···-··--···---·-----··-·····--··--·--·-··--··-······--·-------·--•
♦-----···--··-·---··-··---···-·---·----·-----·-·-··-·------·--·-·-··-------·--·--·--------------··-··-------·---·--··-------·--·-·•-♦
♦---····---·····-··--··--·-·-·--··----·--·---·----··-··--·-------·-··-----------·--------·----------··--·-----·-------·---·-------··•
♦••-·-·----·--·-----------·---·----·--··------·-----·---·--------·---··------------------------------------------------------·------♦
♦-•--------------------------------·--------------------------------------------------------------------------·---------------------♦
Comments: Type: B
Spike File: SPB2BASO
Amt u: Extract: 20t
•-----··------------------------------------·-------------·------·--------------·----------------·----------REV 03/07/95 (PSTI'1F 6)--+
21
Triangle Laboratories, Inc.
Run Log
Acquisition
Column Tvoe Column# Analysis' Method GC Method' Find DBs' Other'
nos "x '7 ;;i 9<. 3 <J JJ. IA ~ol'60 )Jj,A. ,v/A µJA
Standards
Internal/ Surro ate/ Recove
~-f ~{•'Hi£ ' -·" "'"t /JIA-;V//J-~, __j ~A , ',,._ -/, 1 /J. ll> JI~ /c,,g (p I [;SA Q .tb..._t o. <
Internal/ Surro ate/ Recove Anal le
..., ~eunH
Extract/ Sample volume ~ ml
-, Sli,iatura, ' Date 1
' • nate .. Time .. Prolect Samole# Client ID Filename oH' Ooerator/Date Backuu ~-Comments .. • C
b/11,/ria Jl~f.t ql~IJ'i!X 00 I q /lo~?, X (Oo 1) YI~a1 I fu 10/ tul'i'l fu
'
, ~;>,;i~ Cj//o;J\? )( OD;;:) 9/tR~Y ( Oo;;i) y, i-;).i . 1, . G,1 u5A.~ °8d'80A l<.S-100 .<© 1oj,1,/5s f)3,,, , I/A I '°'" .-, ',l.-,c,~ • ')n v-ridc, !Az.J 1v/1u/2~ ·-' . ---WI ...
to}~,. 1'l,;S 4uFJ1 '3 tL! 'oltMJ:. ITLl S...;/ ol,.-K.. VT'8o0
' ,II.,} , c/ IC<~ r
10/11/, TL1. LC.S -, LILCS /fj
/)() !>9. 1/~91'6 ,,~ ' ~ _,.,,, VJ: g-:i, I •-'-'l I I LJ r
/JJ:Z I i!&C)19, TLl LCSb •LI , r",")\ V.I 83;;:>. • :;J.;10--;;J,-/ bl
' /JJ.DS'° L11.c,9 I 9i 1--r-, --• ,,~ I 51 /r, n'7 o :;i:f'_J. C} " 'l-r 'i? ".>,, "", I I
\
l~n/,i o:zt/1 ,'1//l /Qo17 '2?;;>\?04 Cc..1 Vs. 8oLi /4..J 1ol,~hr1. /4.J a~-, . Jt1,,J 10/n I "Ii
,of,1m ,.., ';I/, J.LIA W1'1C. '5s' ;;i 'i3o A CC "'-v, l?3S" ../h,. / D/11 /c,'£ .JJ...1 Cxx,d. ~ 10/t?/</'tj
.. ,~i1h1 ri?it fl/A utusA -J 8.;18oA es-,oo "Y:!~3&, -,hw JD)11!R N
• Volatile Data Only " Transcribed Data "' . Dated Signature/Initials Required Page 51 • SRVR◄IIAP'MSRL'LRRUNLOG.DOC ( 11>'1 6197)
I\J w
Triangle Laboratories, Inc.
Run Log
Acquisition
ColumnTvne Column# Analvsis' Method GC Method' Find DBs· Other•
f\i:,S "l 0 -;; r; ---;., t.J ;V/A )s;,} '60 /'-I //I )I/A NIA-
Standards
internal/ Surro ate/ Recove Anal e
..., ~eunlt
Extract/ Sample volume ~ ml
lllf a • ''f'1
}J IA ;/;/, _/,-,A / --'i /, '1./,./., ,,Jr,/4'l lo/lo, A flo.,.'; r',j "'5·-' t1 /VIA
CJ ' . . Sl!Jl•"• "-. • DaleT T .
)ate .. Time .. Proiect Samole# Client ID Filename oH' Ooerator/Date Backuo Proc Comments .. ' :9I=
'o/,1m, 11,~ 't~139A ..Ji,,_ l I c/ t ik 9. /4.J
feshe>ot Gc,1)D _v;, en.
TL r ~la.., r TL 1 2>1A-r V, 9, ~ '7 -1:n...J JD} '1 /7 g
'
1,J 11/.r,. I lJ 5"i TLL Lr5:, -YL.I LC"-I ,11 5?:>. 8 l;Jz.J
'
/0/11/11 o')o,'i ' , 'TU Lrc.."t\ TLT LC ', I'\ Vr.l?39 1,1w
lo/,7/~ j/;J;) ~9:,Cf /l ,::>--v,. <f?-IA 9?; -I</ ~-P-.M ', BtJa ::2 I Y-l 'i(L.Ji) iw
<.)
10/nk ;;;a; JJt,'1 I-/~ .;J.;>O·"°I -I ~S FC"i.-W VT 'i? '-I I . .Ai .. )
10/,1k .J::i:i.J.9. 1&9 ':>-, ;;i 1L..r ro/n-' /LL ,:,/,,-/<__ vr x>'-l'l. Al,.) .-
11,1h1, .,J,,; l ~3:Xt :f[.J. LC C::.. ,LI Le~ \tr SN:,_
l°J,J,i oo:,t Ti T LC~l'-1CT I CC..../\ vT '644-
'o/i#n &05'1:. I _-,...,..,_yJ-1 '-J1S10-1 v, 'ii<./<:"
, . I \
'°lishrt L/ I., °' :J ;;i Ji~, b/,-,/4~ & ..
Dl't I :J,;;io-<./t -.:i, l/lSJl-1 YJ'ist..j L,
'
• Volatile Data Only •• Transcribed Data •·• Dated Signature/Initials Required Page 52 • SRVR◄IIAPIMSRL'LIIRUNLOO.DOC (10/16'97)
Column Tvne Column# Analysis"
DbS" >?'7'.::Jq53tj JJ/A
Standards
Internal/ Internal I Surra ate / Recove
Volatile Data Only
SRVR41\AP>MSRL'LRRUNLOG.OOC (10/16197)
fl 11
Client ID
t -LI '2,
s
•• Transcribed Data
Triangle Laboratories, Inc.
Run Log
Acquisition
Method GC Method" Find DBs" Other•
'3~%0 N//j i--1/lt N/A
Clrde unit
Anal e Extract/ Sample volume :2 @ ml
Filename
Gcoo1. ~ IO I
•
Jt-
'/.J.8
... Dated Signature/Initials Required Page~
SAMPLE
DATA
Triangle Laboratorles, Inc.
801 Cap/11:1/a Drive P.O. Box 13485
Dur/ram, NC ZTl13-4411 Resarch Triangle Parle, NC Z7709-3485
91~ Fa I 91~541 5'91
25
TLI Project:
Client Sample:
Client Project:
46942
TLI Blank
n/a
Method 8280-A PCDD/PCDF Analysis (b)
Analysis File: VI83700
Matrix: Na2S04
PCDDIPCDF SUMMARY REPORT
2.3, 7 ,8-TCDD ND 0.01
1,2,3,7,8-PcCDD ND 0.02
1,2,3,4, 7 ,8-HxCDD ND 0.03
1,2,3,6,7,8-HxCDD ND 0.03
1.2,3,7,8,9-HxCDD ND 0.02
1.2.3,4.6,7,8-HpCDD ND 0.03
1.2.3.4,6,7,8,9-OCDD ND 0.06
2,3,7,8-TCDF ND 0.008
1,2,3, 7,8-PeCDF ND 0.01
2,3,4, 7 ,8-PcCDF ND 0.01
1,2,3,4, 7 ,8-HxCDF ND 0.02
1,2.3,6,7,8-HxCDF ND 0.02
2.3.4.6. 7 ,8-HxCDF ND 0.02
1,2.3, 7.8,9-HxCDF ND 0.02
1,2.3,4,6,7,8-HpCDF ND 0.03
1,2.3.4,7 ,8,9-HpCDF ND 0.03
1,2,3.4.6.7,8,9-OCDF ND 0.05
Total Analytes . . Ci>ric. (ppb) •. DL {ppb)
To1,u TCDD ND 0.01
Total PcCDD ND 0.02
To1,u HxCDD ND 0.02
Toutl HpCDD ND 0.03
TowTCDF ND 0.008
To1.1J PeCDF ND 0.01
Tow HxCDF ND 0.02
To1,u H pCD F ND 0.03
Triangle Laboratories, lnc.,i
801 Capitola Drive• Durham, North Carolina 27713
Phone: {919) 544-5729 • Fax: [phone]
Page I of 1
-:.·:-·.,., ..
·•··.· Jff :"+i;~ a~t~tiibrii1rnitbfihe .· ·
·••>···••··••·<t······•····•· •·I~~fsi~~tt'.~_th}.hc> .: .· \/ r>
· Bl~~k ~ The c6ni;nJi~tibn 6fthe .• ..
. rriethod blank: ·· .
. . . . . : .
. · ND -{N6~'.bet~cfrhe ..
· cciricentration of .the analyte
is less than the detection
limit.
8::SA_PSR vt.Ol. LARS 6.11.(17
Printed: 13:06 10/19/98
26
TLI Project:
Client Sample:
Client Project:
Sample Matrix:
TL! ID:
Sample Size:
Dry Weight:
GC Column:
2.3.7.8-TCDD
1,2,3,7,8-PcCDD
1.2.3,4.7,8-HxCDD
1,2,3,6.7,8-rlxCDD
1.2.3.7,8,9-HxCDD
1.2.3.4.6. 7 .8-HpCDD
1,2.3,4.6,7.8.9-0CDD
2.3.7.8-TCDF
1,2,3.7.8-PcCDF
2,3,-1.7,8-PeCDF
1.2.3,-1, 7 .8-HxCDF
1.2.3,6.7.8-HxCDF
2,3,4,6.7,8-1-ixCDF
1,2.3. 7,8,9-HxCDF
1.2,3.4.6. 7 .8-HpCDF
1.2,3,4, 7 ,8, 9-HpCDF
1,2,3.4,6.7,8,9-0CDF
Tot:tl TCDD
Total PeCDD
To~'ll HxCDD
Total HpCDD
Total TCDF
ToL'.ll PcCDF
ToL'.ll HxCDF
Total 1-ipCDF
46942
TLI Blank
n/a
Na2504
TLI Blank
10.160 g
n/a
DB-5
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Triangle Laboratories, Inc.~
Method 8280-A PCDD/PCDF Analysis (b)
Analysis File: Vl83700
Date Received: I I Spike File: SP828AS0
Date Extracted: 10/15/98 ICal: V85O12A
Date Analyzed: 10/17/98 ConCal: VI83500
Dilution Factor: n/a % Moisture: n/a
Blank File: VI83700 % Lipid: n/a
Analyst: ALW % Solids: n/a
0.01
0.02
0.03
0,03
0.02
0.03
0.06
0.008
0.Dl
0.Dl
0.02
0.02
0.02
0.02
0.03
0.03
0.05
0 1.7
0 0.02
0 0.02
0 0.03
0 0.04
0 0.Dl
0 0.02
0 0.03
Page I of2 lf:SA_PSR vJ.01, LARS 6.11.07
801 Capitola Drive• Durham, North Carolina 27713
Phone: [phone] • Fax: [phone]
Printed: 13:06 10/19/98
27
TLI Project:
Client Sample:
"C,,-2,3,7 ,8-TCDF
13C,,-2,3,7 ,8-TCDD
13C,,-l.2,3,6, 7 ,8-HxCDD
"C,,-l,2,3,4,6,7,8-HpCDF
"C,,-1,2,3,4,6, 7 ,8,9-OCDD
37CL-2,3,7,8-TCDD
"C i:-1.2.3.4-TCDD
"Ci:-l,2,3,7,8,9-HxCDD
46942
TLI Blank
3.8
4.0
4.1
6.8
6.4
2.0
Method 8280-A PCDD/PCDF Analysis (b)
Analysis File: Vl83700
77.8
80.8
82.4
69.1
64.6
80.2
25%-150%
25%-150%
25%-150%
25%-150%
25%-150%
25%-150%
0.80
0.79
1.20
1.05
0.98
0.80
1.26
21:51
22:37
30:05
31:56
35:05
22:38
22:25
30:22
Data Reviewer: ___________ :£_µ._,_ 10/19198
Triangle Laboratories, Inc.,.
801 Capitola Drive• Durham, North Carolina 27713
Phone: [phone] • Fax: [phone]
Page 2 of2 8:,SA_PSR vl.01. LARS 6,l 1.07
Printed: 13:06 10/19/98
28
TLI Project:
Client Sample:
Client Project:
Sample Matrix:
TL! ID:
Sample Size:
Dry Weight:
GC Column:
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3, 7 ,8,9-HxCDD
I,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-0CDD
2,3, 7,8-TCDF
1,2,3, 7 ,8-PeCDF
2,3,4, 7 ,8-PeCDF
1.2.3,4,7,8-HxCDF
1,2.3,6, 7 .8-HxCDF
2,3,4,6,7,8-HxCDF
1.2.3. 7,8,9-HxCDF
1.2.3.4,6.7,8-HpCDF
1,2,3,4, 7 ,8,9-HpCDF
1,2,3,4,6,7,8,9-0CDF
46942
TLI Blank
n/a
Na2SO4
TLI Blank
10.160 g
n/a
DB-5
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor:
Blank File:
Analyst:
X I.
X 0.5
X 0.1
X 0.1
X 0.1
X 0.01
10/15/98
10/15/98
10/17/98
1
Vl83700
ALW
=
=
=
=
=
X 0.001 =
X 0.1
X 0.05 =
X 0.5 =
X 0.1 =
X 0.1 =
X 0.1 =
X 0.1 =
X 0.01 =
X 0OI =
X 0.!JO 1 =
Toxicity Equivalents Report
Analysis File: Vl83700
Spike File:
!Cal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SP828A50
V85O12A
VI83500
n/a
n/a
n/a
Total 2,3,7,8-TCDD Toxicity (1989 ITF) Equivalents: 0. ppb
(1) Detection Limits not used in calculations.
Note: 100% of EM PCs are used in the calculations.
Triangle Laboratories, Inc."'
801 Capitola Drive • Durham, North Carolina 2n13
Phone: [phone] • Fax: [phone]
Page 1 of 1 GRY _TEP vi.OJ, MILES -1.16.13
Printed: 13:19 10/19/98
29
Data Review By:
Page No.
10/19/98
compound/
1
3g \11,:~ Calculated Noise Area, • 53.53
Listing of VI83700B.dbf
Matched GC Peaks/ Ratio/ Ret. Time
H_Z .... QC Log Omit Why .. RT. OK Ratio Total.Area ... Area.Peak..l .. Area.Peak..2 .. Rel.RT Compound.Name .. ID .. Flags.
TCDF
304-306
304-306
13Cl2-TCDF
316-318
316-318
TCDD
320-322
320-322
37Cl-TCDD
328
K
328
13C12-TCOO
332-334
332-334
PeCDF
HO-342
D
HO-342
DC NL
oc WL
oc WL
oc WL
DC WL
oc ',IL
DC WH
DC WH
DC WH
DC WH
DC WH
0.65-0.89
22:26 RO 1.57
Peak
0.65-0.89
21:51 0.80
Peak
638.00
638.00
77,769.00
77,769.00
390.00
34,504.00
Above: TCDF I TCDD Follows
0.65-0.89
21:51 RO 5.46
Peak
18:41
18;54
19:48
20:31
20:36
22:02
22:08
22:21
22:38
22: 53
23:38
23:46
24:04
24:07
4 Peaks
22:25
22:37
2 Peaks
0.65-0.89
o. ao
0.79
22,608.00
22,608.00
0.00
175.00
116.00
112.00
156.00
106. 00
119. 00
147. 00
114 .00
27,943 .00
126 .00
121 .00
156.00
101 .00
106 00
28,323 .00
72.508.00
56,095.00
128,603.00
19,111.00
0.00
119. 00
147.00
114. 00
27,943.00
32,246.00
24,775.00
0.830-1.088
248.00 1.027
0.820-1.105
43,265.00 1.000 13C12-2378-TCDF ISO
0.871-1.051
3,497.00 0.966
0. 954-0.999
0.826
0.336
0. 875
0.907
0. 9ll
0. 974
0 979
0. 988
1.001 37Cl-TCOD
1.01.2
1. 045
.051
.064
.066
0.965-1.016
CLS
40,262.00 0.991 13Cl2-1234-TCOD RSl
31,320.00 1.000 13Cl2-2378-TCDD !Sl
-----------------------Above: TCDD / PeCDF Follows---------------------
1. 32-1. 78 1.085-1.265
DC WL 23:38 RO 34. 59 69,640.00 1. 082
D SN 26:35 RO 3.67 616.00 1.217 23478-PeCDF AN
DC WH 27:51 RO 0.93 292. 00 1. 275
0 Peaks 0.00
----------------------Above: PeCDF / PeCDD Follows---------------------
J
Triangle Laboratories, Inc.® Analytical Services Division
801 Cap~ola Drive• Durham, North Carolina 27713 Printed: 13:07 10/19/98
Phone: [phone] • Fax: {919) 544-5491
30
Page No.
10/19/98
Compound/
2 Listing of
Matched GC
41iiii~·700B. dbf
~s I Ratio / Ret, Time •
M_Z .... QC.Log Omit Why .. RT. OK Ratio Total.Area ... Area.Peak.! .. Area.Peak.2 .. Rel.RT Compound.Name .. ID .. Flags.
PeCDD
356-358
356-358
HxCDF
374-376
374-376
HxCDD
390-392
390-392
0
0
0
0
0
0
0
0
0
0
0
0
l3Cl2-HxCDD
402-404
402-404
l3Cl2-HpCDF
420-422
4:'.:0-422
HpCOD
424-426
424-426
.32-1.78
DC WH 27:36 RO l.19
0 Peaks
316.00
0.00
Above: PeCOO / HxCDF Follows
l.05-1.43
0 SN 29:38 RO l.46 278. 00
0 SN 29:45 RO 2.73 597.00
0 SN 29:53 RO 0.96 206.00
0 SN 30:09 l.22 229.00
0 SN 30:16 RO 0.80 290.00
0 SN 30:21 RO 0.73 295.00
0 SN 30: 31 RO 3.30 486.00
0 SN 30:46 RO 2.04 1,655.00
DC WH 30: 56 RO l. 62 9,791.00
0 Peaks 0.00
----------------------Above: HxCDF I HxCDD Follows
1.05-l . 43
DC WL 28: 3l RO 2.63 403.00
0 SN 29:36 RO o. 54 -03.00
0 SN 29:50 l. 32 453 .00
0 SN 29:59 RO 0. 79 730. 00
0 SN 30:06 RO 2.10 918. 00
0 Peaks 0 .00
. 05-l.43
29 :44 RO 0.-H 436,00 126.00
29 :48 RO l. 78 412. 00 264. 00
29 :56 RO 0.72 565.00 237.00
29:58 RO 0. 19 632. 00 102. 00
30:05 l. 20 28,980.00 15,798.00
30: l3 l.19 320.00 174.00
30:15 RO 0.99 265.00 132. 00
30:22 l.26 36,962.00 20,627.00
30:30 RO 0.34 431.00 ll0.00
30:46 RO 0.15 2,306.00 293.00
lO Peaks 71,309.00
l.104-l.217
l.220
0.884-0.964
0.928
0. 932
0.936 234678-HxCDF
0.944
0.948
0.950
0.956
0. 963
0. 969
---------------------
0. 954-l. 013
0. 948
0.984
0.992
0.997 123478-HxCDD
l . 00 l 123678-HxCDD
0.967-1.033
3l0 . 00 0. 988
148. 00 0. 991
328.00 0 .995
530.00 0 .996
l3 .182 .00 . 000 l3Cl2-HxCDD
146. 00 l. 004
133.00 l.006
678
16,335.00 l.009 l3Cl2-HxCOO 789
321.00 l.014
2,013.00 l. 023
----------------------Above: HxCDO / HpCOF Follows---------------------
0.994-1.005
AN
AN
AN
IS2
RS2
31:56
l Peak
0.88-l.20
l.05 56,221.00
56,221.00
28,780.00 27,441.00 l.000 l3Cl2-HpCOF 678 IS)
----------------------Above: HpCDF / HpCDD Follows---------------------
0.88-l.20
DC WL 31:56 RO 3.43
O Peaks
17,464.00
0,00
.063-l.103
l.061
Triangle Laboratories, Inc.® Analytical Services Division
801 Capijola Drive • Durham, North Carolina 27713 Printed: 13:07 10/19/98
Phone: [phone] • Fax: [phone]
31
Page No.
10/19/98
Compound/
) Listing of
Matched GC
IA100B.cil:>f
~s / Ratio / Rat. Time •
M_Z .... QC.Log Omit Why .. RT. OK Ratio Total.Area ... Area.Peak.! .. Area.Peak.2 .. Rel.RT Compound.Name .. ID .. Flags.
----------------------Above. HpCDD / octa-coo and COF Follows----------
OCDF
442-444 D
D
442-444
OCDD
458-460 D
458-460
13C12-0CDD
470-472
M
D
D
D
SN
SN
0
SN
0
11
Column Description ...
34:58
35:24
Peaks
35: 33
Peaks
34:57
35:05
35:14
35:23
35:27
35: 33
3 5: 3 9
35: 49
35: 55
36: 00
36: 24
Peaks
M_i -Nominal Ion Mass(esl
.. RT. -Retention Time (mm:ss)
Rat.l -Ratio of M/M~2 Ions
0.76-1.02 0.886-1.114
RD 0.69 312.00 0. 997
RD 0.65 277 .00 1.009
0.00
0.76-1.02 0. 996-1. 005
RO 2.18 499. 00 1.013
0 .00
0 .76-1.02 0.996-1.005
RO 1.09 340.00 177. 00 163.00 0.996
0.98 20,352.00 10,072.00 10,280.00 1.000 13C12-0COO
RO 1. 78 769.00 492.00 277.00 1. 004
RO 6.04 901.00 773.00 128.00 1. 009
RO 1. 63 557. 00 345.00 212.00 l . 010
RO 1.10 432.00 226.00 206.00 .013
RO 2.51 576.00 412. 00 164.00 . 016
RO 1. 65 992. 00 617 .00 375.00 . 021
RO 3.50 ,106.00 860. 00 246.00 l.024
RO 3.54 985.00 768. 00 217. 00 l.026
RO 3.01 l,090 00 313 .00 272. 00 .038
28.100.00
"Why-Code Description. QC Log Oesc ..
wt-Below Retention Time Window A-Peak Added
WH-Above Retention Time ~indow
SN-Below Signal to Noise Level
K-Peak
□-Peak
Kept
Deleted
OK -RO~Ratio Outside Limits <M-Below Method Detection Limit
Rel.RT-Relative Retention Time NL-Channel Specific Noise Level
T-Time
M-Peak
Changed
Area Changed
N-Name Changed
X-Ether Interference
••• End of Report•••
IS4
Triangle Laboratories, Inc.® Analytical Services Division
801 Cap~ola Drive • Durham, North Carolina 27713 Printed: 13:07 10/19/98
Phone: [phone] • Fax: [phone]
\. 32
Data File: /chem/V.i/10-17-98.b/VI837.d
Report Date: 17-0ct-19. 19:55 • Page 1
TRIANGLE LABORATORIES, INC.
Data file
Lab. Id. :
SEMI-VOLATILE QUANTITATION
/chem/V.i/10-17-98.b/VI837.d
REPORT
Inj Date :
Operator :
Smp Info :
Misc Info:
Comment
TLI #46939A
17-0CT-98 19:12
ALW
TLI #46939A TLI BLANK
TLI BLANK
Method /chem/V.i/10-17-98.b/8280.m
Meth Date 17-0ct-1998 16:38
Cal Date : 27-JUL-98 10:47
Als bottle: 2
Oil Factor: 1.000
Integrator: HP RTE
Sample Type: mm5
No Target Compounds Detected.
/)L _ Arco._-=-(/ 'J) ( c')i./-'7" 5 1r--31 :i a o)
( &9 8'7 t-"i!/12:>?i)
Autotune Date: 12-0ct-98 08:51:1
Inst ID: V.i
Cal File: Vh485.d
Target Version: Target 2.20
Compound Sublist: all.sub
33
Abundance
100
911
96
94
Triangle Labs Inc.
Run Sat Oct 17 19:12:25 1998
Ion 320.00 amu from V1837.d
N Ill a,
N
92 3----,---,-----,-,#-i-AA-IIH--!h----AA-AA-l-lr--tft+-1---
90
88
116 ~.l.......lW..__Ji--41-,.----1-L---~-'-.l...-.''---'-'-'---
84
82
80
Abundance
100
98
96
94
92
00
B8
86
84
82
80
20.0
Triangle Labs Inc.
21.0
Ion 322.00 amu from V1837.d
N Ill a,
;::;
22.0
q
23.0 24.0
w
U1
Run Sat Oct 17 19:12:25 1998
Ion 304.00 amu from Vl837.d
Abundance Triangle Labs Inc.
TetraCDF
m M
200 ... ..;
150
100
50
0
Ion 306.00 amu from Vl837.d
Abundance Triangle Labs Inc.
200
150
100
50
0--'r--~~~--~~-~~~--.....-~--.....-~--.....-~--.....-~--.....-~-..--.....-~-..--~~~
1B.O 19.0 20.0 21.0 22.0 23.0 24.0
w
0)
Abundance
14000
12000
10000
0000
6000
4000
2000
0
Abundance
14000
12000
10000
0000
6000
4000
2000
0
10.0
Run Sat Oct 17 19:12:25 1998
Ion 316.00 amu from V1837.d
Triangle Labs Inc.
13C12-2378-TCDF IS
., M ...
"' ... ., M
N a, N Ill -
Ion 310.00 amu from Vl837.d
Triangle Labs Inc.
10.0 20.0 21.0
N "' ., -
N "' ii! Ill £;: N
N £ ,._ "' ... ,._ -Ill <O a,
N N N ..; MM M
N "' ., -
.,
M M
22.0 23.0 24.0
Run Sat Oct 17 19:12:25 1998
Ion 243.00 amu from V1837.d
Abundance Triangle Labs Inc.
soo TCDF-COCI/Ether
... M
CD "' 400 ., "'
N i' "' i
300 "' ... M ... CD ... M ... "' N ... N
"" M ... CD
200
., ., "' N M
100
0
Ion 376.00 amu from Vl837.d
Abundance Triangle Labs Inc.
soo
400
300
200
100
0
18.0 19.0 20.0 21.0 22.0 23.0 24.0
w
00
Abundance
7000
6000
5000
4000
3000
2000
1000
0
Abundance
7000
6000
5000
4000
3000
2000
1000
0
Triangle labs Inc.
Triangle labs Inc.
20.0
Run Sat Oct 17 19:12:25 1998
Ion 320.00 amu from Vl837 .d
TetraCDD
N
"' ., -
;;;
M
Ion 322.00 amu from Vl837.d
N "' ., -
21.0 22.0 23.0 24.0
w
CD
Abundance
10000
9000
BOO()
7000
6000
5000
4000
3000
2000
1000
Triangle Labs Inc.
Run Sat Oct 17 19:12:25 1998
Ion 259.00 amu from V1837.d
TCDD-COCl/37CI-TCDD Cleanup Std
0)
"' ., ... N co
M
N
'" ., 05---.....C:'-'-------------------ili..l---__tji.J-L!l.l... ___ .L.1:1.JL-!IILL.-
Abundance
10000
9000
8000
7000
6000
5000
4000
3000
2000
1000
Triangle Labs Inc.
... "' ., g "'
Ion 328.00 amu from V1837.d
N NU> "' ... 0) _., MM ... "'"' o-NN
"' "' M
0)
M "' "'
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N
... "" N CD .,,... co ... 0-
M M .;.;
o~====:::;=:!::;::!:::!:;:==;=::;:=~~=:;=~~=;:::=:;::===~~~~~~=::::==!:~~~ a, a, 0) --
18.0 19.0 20.0 21.0 22.0 23.0 24.0
Run Sat Oct 17 19:12:25 1998
Ion 332.00 amu from Vlll37.d
Abundance Triangle Labs Inc.
14000 13C12-1234-TCDD RS/13C12-2378-TCDD IS
12000
N N
10000 ... N N
"' 8000 N N
6000
4000
M R ... ... II)
2000 0 Ill
,._ ,._
N CD 0
N N N N M
0
Ion 334.00 amu from V1837.d
Abundance Triangle Labs Inc.
14000
N N 12000 ...
N N N
10000 "' N N
8000
6000
4000
2000
0
22.0 22.2 22.4 22.6 22.8 23.0 ,·
Abundance Triangle Labs Inc.
25000 ....
N "' M
20000
15000
10000
5000 "' "' "' ...
0
Abundance Triangle Labs Inc.
25000
20000
15000
10000
5000 .... "' N ;:; "' "' ,.; ... .... .;. .;.
0
24.0 25.0
Run Sat Oct 17 19:12:251998
Ion 340.00 amu from Vl837.d
PeCDF
N 01 -
Ion 342.00 amu from Vl837.d
N ;;; ....
In 01
vi vi
26.0
.... .... In
"'
'{·
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N -
In "'
"' "'
In ~ 01 ., .,
....
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27.0 28.0
Abundance
300
200
100
0
Abundance
300
200
100
Triangle Labs Inc.
Triangle Labs Inc.
M 8
1/)
N
Run Sat Oct 17 19:12:25 1998
Ion 277.00 amu from V1837.d
PeCDF-COCI/Ether
Ion 410.00 amu from V1837.d
"' .... 0
16 ....
1/) .;
N
....
"' ....
0 CD .... ... N .;
o----,---r---,--r----r--,---r-"'r'--.---,---.---r-.--.--,,---.--r---.---,--..------.---.--"""T""-
24.0 25.0 26.0 27.0 28.0
A w Abundance j 1200 1000 BOO 600 400-1 200 0 Abundance j 1200 1000 BOO 600 400 200 0 M ., ., M 8 Triangle Labs Inc . ...... ~~ U1 l!l ... II) M Triangle Labs Inc. 25.0 a, M II) a, "' ., II) "' ,-. Run Sat Oct 17 19:12:25 1998 Ion 356.00 amu from V1837.d PeCDD ,-. ... u, N a, 0 0 en "' i Ion 358.00 amu from Vl837.d 26.0 ... ... "' "' N ... a, ,-. ., N a, "' ... 0 27.0 "' a, ... M II) ., -a, ~ Lfl Lil u, N "' ., II) "' "' "' ,-.
~ J:>, Abundance 2000 1800 1800 1400 1200 1000 000 800 400 :l 200 0 Abundance 2000 1800 1800 1400 1200 1000 BOO Trtangle Labs Inc. ., Triangle Labs Inc. .. M "' .. "' .. M 0 "" N Run Sat Oct 17 10:12:25 1008 Ion 374.00 amu from Vl837.d HexaCDF Ion 378.00 amu from Vl837 .d N ... 8001 400 ~;;:~ ~ u, ID ,._ ~--'-r-, ----.--: --.-~------r, -·=:-----.-----,:-::=r--.---~ -~-,--· ~-· 3----.-·: ._~ ---,ai -----rg ------.-r--.------~, -31.0 28.0 20.0 30.0
~ CJl Abundance , 6000 5000 4000 ~ 3000-3 2000-3 ... -MO 0 -1000µ.; 0 Abundance ~ 6000 5000 4000 3000 2000-::i .... 1~~ ·~ 28.0 Triangle Labs Inc. .... ., g ~ CD ~ ~ ., a, M ., .... ., Triangle Labs Inc. V Ill N .... ... M a, Ill R ~ --N ;::; a, ., M "' Run Sat Oct 17 19:12:25 1998 Ion 311.00 amu from Vl837.d H><CDF-COCI/Ether ., --Ill ... a, "' Lil N ~ U> Ill Ill • Ill a, a, a, 8 .... -N 0 • ~ ~ t") Ion 446.00 amu from V1837.d ., U> M ....... ., a, "' M 2 .... ~ e;g Ill N 0 M .... ., 29.0 g a, (D MMQ'° .... ., ., N "' i;Uil ., -N N c,q-0> ,-..N N .... ... Ma, m moo -N M ;;: Ill ........ "' oo ~ ... ...: .. 30.0 31.0
Abundance Trlangle Labs Inc.
3000
2000
(Q g CD CD a, ~ M CD CD
(Q 0, a, 0 .,;
CD
0
Abundance Trlangle Labs Inc.
3000
2000
1000
O>
"' .;
0
28.5 29.0
Run Sat Oct 17 19:12:25 1998
Ion 390.00 amu from VIB37.d
HexaCDD
CD M ... ;;; "' CD ,.._ N "' ~ M ... ...
.,; .,;
N
Ion 392.00 amu from Vl837.d
N ... a,
(Q ,.._
.,; .,;
29.5
CD O> N N ... M ...
M (Q a, (Q
0, ,.._ 0 CD a,
N
"'
M ...
"' .,;
N
30.0 30.5
Abundance
10000
8000
6000
4000
2000
0
Abundance
10000
8000
6000
4000
2000
29.8
T r1angle Labs Inc.
II)
N ,.._
Triangle Labs Inc.
II) II) N ,.._ ,.._ ,.._
29.8
M
"' a,
~ ii!
"' "' "' "'
Run Sat Oct 17 19:12:251998
Ion 402.00 amu from Vl837.d
13C12-HKCDD 678 IS/13C12-HKCDD 789 RS
,.._ ,.._
0
-... ... N N
Ion 404.00 amu from V1837.d
M
"' "'
30.0 302
N "' M
g
N
"' M
g
30.4
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M
"' g
30.8
... ,.._
"' "' ,.._ ,.._
... "' ,.._
30.8
.s::..
00
Abundance
800
700
800
500
400
300
200
100
0
Abundance
800
700
600
500
400
300
200
100
0
31.5
M ii!
Triangle Labs Inc.
Triangle Labs Inc.
.,
M
0)
32.0
N N
Run Sat Oct 17 19:12:25 1998
Ion 408.00 amu from V1837.d
HeptaCDF
Ion 410.00 amu from V1837.d
32.5
N 0) .,
N M
33.0
"' N
33.5
A
c.o
Abundance
14000
12000
10000
8000
6000
4000
2000
0
Abundance
14000
12000
10000
8000
6000
4000
2000
0
31.50
Triangle Labs Inc.
Triangle Labs Inc.
31.60 31.70
Run Sat Oct 17 19:12:25 1998
Ion 420.00 amu from VIB37.d
31.80
13C12-HpCDF 678 IS .,
M O>
M
N
0
N
Ion 422.00 amu from Vl837.d
31.90
.,
M
O>
32.00 32.10 32.20 32.30 32.40
"' 0
Abundance
1000
1600
1400
1200
1000
BOO
800
400
200
0
Abundance
1000
1600
1400
1200
1000
BOO
600
400
200
Triangle Labs Inc.
Triangle Labs Inc.
N ,.._
Run Sat Oct 17 19:12:25 1998
Ion 345.00 amu from V1837.d
HpCDF-COCI/Ether
M ,.._
:::; i 5!
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~ N M
M
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<D g
"'
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M ...
0
M M
0---'-'-y--,-.----.--.------r----.---,--.------,-----.----r---r----,-~----.--~-~~-~---
31.5 32.0 32.5 33.0 33.5
CJl
~
Abundance
7000
6000
5000
4000
3000
2000
1000
Triangle Labs Inc.
.,
M
"'
Run Sat Oct 17 19:12:25 1998
Ion 424.00 amu from VIB37.d
HeptaCDD
o.:l----J..L-~----------------------------
Abundance
7000
6000
5000
4000
3000
2000
Ion 426.00 amu from VIB37.d
Triangle Labs Inc.
'1000
o.:1====.=!~=~=:::::!:;:=============================
31.8 32.0 32.2 32.4 32.6 32.8 33.0 332
(Jl
l'v
Abundance
250
200
150
100
50
0
Abundance
250
200
150
100
50
Triangle Labs Inc.
~
"' .;
Triangle Labs Inc.
...
1/) "' ...
Run Sat Oct 17 19:12:25 1998
Ion 442.00 amu from Vl837.d
OCDF
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Ion 444.00 amu from V1837.d
.,;
o--1-..-.---...--.--.--.--.---...--r--.--,.....,..--.--.--.--.---...--.--.--.--.---...-.-..-.---...--r--.--.----r---,----.-..-.---...-.-~---...~...-..-.---...--.--.--~~...-
34.80 34.90 35.00 35.10 3520 35.30 35.40 35.50 35.60 35.70
(
CJ! w
Abundance
2500
2000
1500
1000
500
0
Abundance
2500
2000
1500
1000
500
0
Triangle Labs Inc.
.... ... 0 .... .... 8 C0 M .... .,
Triangle Labs Inc.
34.80 34.90 35.00
Run Sat Oct 17 19:12:25 1998
Ion 379.00 amu from V1837.d
OCDF-COCI/Ether
,M lil
Ill
i N .,; M Ill ., ., .... ... Ill
M ., ., M -., N .,; .,; -.,; .,;
Ion 514.00 amu from V1837.d
35.10 35.20 35.30 35.40 35.50 35.tlO 35.70
CJT ..:a.
Abundance
500
400
300
200
100
0
Abundance
500
400
300
200
100
0
Triangle Labs Inc.
Triangle Labs Inc.
., .,
"' ...
34.IIO 34.90 35.00
Run Sat Oct 17 19:12:251998
Ion 458.00 amu from Vl837.d
OCDD
...
Ill Ill
"' .,
M .,;
Ion 460.00 amu from Vl837.d
... ... ... "' ... Ill
5l Ill
"' Ill M .,; M N M .,; "' M M
M .,;
M
35.10 35.20 35.30 35.40 35.50 35.BO 35.70
(J1 :J1 Abundance :; 5000 4000:i 3000-3 ,._ 2000-3 M CD .. 1000 0 Abundance 7000 6000 ~ 5000-3 4000 3000 2000:i 1000.:::i 0 ' 34B Triangle Labs Inc. ., ., 0 "' '7 I I I \ CD a, g ...... CD M g u, CD N a, a, ·-...... • . .c:l C") Triangle Labs Inc. ., CD 0 "' M ' I \ a, ;:: M "' N ' 35.0 35.2 Run Sat Oct 17 19:12:25 1998 Ion 470.00 amu from V1837.d 13C12-0CDD IS N ... ., M ... "' g "' ... "' ,._ ,._ N a, N M (D " r;; "' ,._ ~ .,; "' a, CD ., ~ ~ LI! .,; ~ ~ M M .,; . . "' M .,; l!?lfl_C") M Ion 472.00 amu from Vl837.d M N M CD ... ,._ ... ., "' en N 0 -CD "' ,._ "' ,._ "' N g N 8i ... ;:; ;;: ,._ ... .; -"' M ... "' CD ,._ "' ... 35.4 35.6 35.8 36.0 36.2 36.4 36.6
,,,,,,,lchem/V.i/10-17-9?.,;p/VI837.P.Pr
,,,,,,,Mass,Area,h,m,s,a9Jht
JQ4, I I I I
,390,0,22,26,89
306, , , , ,
,248,0,22,25,52
Jl6, t t t t
,135,0,20,16,30
,169,0,20,57,30
,141,0,21,17,39
,140,0,21,32,43
,34504,0,21,51,8764
,115,0,22,25,34
,208,0,22,36,61
,148,0,22,47,58
,123,0,23,11,36
,131,0,23,34,31
,133,0,23,39,46
,144,0,23,58,45
318, , , , ,
,43265,0,21,51,11253
,332,0,22,20,78
320 t I I I I
,19111,0,21,51,4920
,123,0,22,19,33
3 22 t t I I I
,3497,0,21,51,929
259, , , , ,
,103,0,18,36,20
,109,0,21,52,20
,107,0,22,38,40
,262,0,22,53,88
,307,0,23,38,76
,102,0,23,55,36
328,,,,,
,175,0,18,41,31
,116,0,18,54,40
,112,0,19,48,30
,156,0,20,31,40
,106,0,20,36,31
,119,0,22,2,34
,147,0,22,8,40
,114,0,22,21,33
,27943,0,22,38,7114
,126,0,22,53,40
,121,0,23,38,58
,156,0,23,46,43
,101,0,24,4,35
,106,0,24,7,64
JJ2, t I I I
,213,0,22,6,90
,143,0,22,10,46
,183,0,22,15,70
,32246,0,22,25,8371
,24775,0,22,37,6987
,340,0,22,52,92
,170,0,23,4,79
334, , , , ,
,40262,0,22,25,10439
,31320,0,22,37,8733
J4Q, I I I I
,67683,0,23,38,20727
,179,0,24,40,38
,119,0,26,11,37
,484,0,26,35,146
,143,0,26,54,40
•
5fi
,'141,0,27,51,40
342, I I I I
,1957,0,23,38,567
,163,0,24,26,30
, 120, 0, 24, 46, 37
,140,0,25,34,43
,212,0,25,59,44
,211,0,26,32,68
,132,0,26,37,67
,129,0,27,3,78
,174,0,27,9,64
,106,0,27,12,75
,123,0,27,16,68
,244,0,27,29,80
,202,0,27,34,77
,151,0,27,49,43
277, , , , ,
,328,0,23,39,92
,102,0,23,57,31
,100,0,24,27,19
, 177, 0, 25, 53, 44
,240,0,26,34,83
,402,0,27,5,125
,123,0,27,14,36
,137,0,27,29,45
,222,0,27,45,35
,212,0,27,55,82
,114,0,28,l,63
410, , , , ,
,217,0,25,0,108
356, I I I I
,174,0,24,53,64
,104,0,25,0,33
, 165, o, 25, 12, 53
,202,0,25,15,91
,273,0,25,21,64
,324,0,25,32,59
,105,0,25,37,46
,108,0,25,41,108
,219,0,25,45,93
,148,0,25,57,60
,171,0,26,1,57
,111,0,26,5,60
,128,0,26,7,79
,121,0,26,14,70
,208,0,26,16,79
,253,0,26,25,82
,463,0,26,31,134
, 135, 0, 26, 36, 68
,340,0,26,48,121
,703,0,26,56,140
,548,0,27,3,96
,143,0,27,12,84
,187,0,27,26,114
,488,0,27,31,120
,172,0,27,36,92
,562,0,27,46,161
358, , , , ,
,103,0,26,39,49
, 177, 0, 27, 19, 48
,144,0,27,34,52
,154,0,27,41,41
374, , , , ,
,130,0,28,7,27
,115,0,28,56,37
,101,0,29,2,58
•
57
,122,0,29,27,30
,165,0,29,38,45
,437,0,29,45,131
,101,0,29,53,40
,126,0,30,9,52
,129,0,30,16,56
,124,0,30,21,46
,373,0,30,31,112
,152,0,30,35,77
,167,0,30,38,104
,1111,0,30,46,211
,6056,0,30,56,793
376,. , , , ,
,104,0,29,34,40
, 113, 0, 29., 38, 50
,160,0,29,45,64
,105,0,29,53,42
,169,0,29,59,47
,103,0,30,10,37
,161,0,30,15,59
, 171, o, 30, 20, 64
,113,0,30,30,69
,340,0,30,43,113
,544,0,30,47,249
,909,0,30,51,375
,3735,0,30,55,496
311, , , , ,
,125,0,28,2,44
,293,0,28,6,66
,122,0,28,13,65
,193,0,28,17,112
,510,0,28,21,128
,343,0,28,29,133
,286,0,28,34,149
,132,0,28,40,75
,402,0,28,47,203
,244,0,28,50,135
,617,0,28,55,169
,131,0,29,0,89
,165,0,29,4,131
,315,0,29,8,190
,228,0,29,15,150
,348,0,29,32,209
,432,0,29,35,178
,872,0,29,39,259
,1412,0,29,58,366
446, , , , ,
,153,0;28,1,86
,138,0,28,8,59
,181,0,28,11,85
, 128, 0, 28, 15, 68
,420,0,28,44,85
,156,0,28,48,63
,252,0,28,56,57
,156,0,29,2,85
, 110, 0, 29, 12, 49
,197,0,29,22,58
,169,0,29,30,63
,113,0,29,34,67
,125,0,29,36,61
,105,0,29,46,56
,198,0,29,50,62
,669,0,29,56,174
,314,0,30,0,130
,401,0,30,3,122
,289,0,30,6,125
•
58
,265,0,30,11,107
,120,0,30,14,58
,126,0,30,20,64
,430,0,30,25,88
,464,0,30,35,158
,119,0,30,44,54
,101,0,30,47,74
,877,0,30,57,182
,348,0,31,2,114
,121,0,31,5,68
J9Q, I I I I
,292,0,28,31,92
,441,0,28,40,87
,160,0,28,56,74
,186,0,28,59,69
,119,0,29,5,46
,203,0,29,12,87
,154,0,29,22,62
,226,0,29,25,71
,160,0,29,29,73
,150,0,29,33,102
,152,0,29,36,49
,258,0,29,50,89
,142,0,29,54,142
,322,0,29,59,136
,622,0,30,6,160
,259,0,30,10,103
,627,0,30,20,186
,277,0,30,26,141
392, , , , ,
,111,0,28,31,42
,281,0,29,38,56
,195,0,29,48,47
,408,0,29,57,94
,296,0,30,4,138
,305,0,30,13,87
,3149,0,30,31,550
,8626,0,30,45,1198
4 02, , , , ,
,126,0,29,44,52
,264,0,29,48, 7.2
,237,0,29,56,69
,102,0,29,58,79
,15798,0,30,5,6246
,174,0,30,13,80
,132,0,30,15,43
,20627,0,30,22,7919
,110,0,30,30,58
,150,0,30,41,89
,293,0,30,46,180
,239,0,30,48,145
404, , , , ,
,310,0,29,44,136
,148,0,29,47,81
,328,0,29,54,92
,530,0,30,0,176
,13182,0,30,5,5001
,146,0,30,12,72
,133,0,30,15,50
,338,0,30,18,146
,16335,0,30,22,6381
,284,0,30,27,96
,321,0,30,30,138
,320,0,30,37,300
,2013,0,30,46,311
408, , , , ,
• •
,490,0,31,36,111
,156,0,32,7,96
,103,0,32,14,53
,122,0,32,23,66
,412,0,32,54,113
,154,0,33,16,80
410, , , , ,
,124,0,31,56,36
420, , , , ,
,28780,0,31,56,11070
, 179, 0, 32, 1,107
422, I I I I
,27441,0,31,56,10815
345, , , , ,
,347,0,32,22,188
,388,0,32,26,140
,311,0,32,30,157
480, , , , ,
,245,0,32,1,68
,192,0,32,10,53
, 157, o, 32, 18, 63
,150,0,32,26,49
,203,0,32,43,63
,558,0,32,55,102
,169,0,33,3,62
424, , , , ,
,13521,0,31,56,5396
426, , , , ,
,3943,0,31,56,1643
442, , , , ,
,127,0,34,58,35
,109,0,35,24,47
444, , , , ,
, 185, 0, 34, 57, 63
,168,0,35,24,36
458, , , , ,
,108,0,35,23,30
,342,0,35,33,98
4 60, , , , ,
,153,0,34,59,35
,392,0,35,14,127
,162,0,35,20,67
,711,0,35,30,184
,157,0,35,33,105
,279,0,35,40,123
470, , , , ,
,286,0,34,50,143
,597,0,34,54,175
,177,0,34,57,177
,228,0,34,59,173
,11913,0,35,5,4060
,492,0,35,14,134
, 364, o, 35, 18,142
,773,0,35,23,215
,345,0,35,27,231
,428,0,35,30,195
,226,0,35,33,166
,412,0,35,39,246
,654,0,35,46,299
,617,0,35,49,224
,860,0,35,55,314
,768,0,36,0,411
,519,0,36,15,285
,818,0,36,24,292
472, , , , ,
,163,0,34,58,59
•
60
,10541,0,35,5,4055
,277,0,35,14,75
, 128, o, 35, 22, 67
,212,0,35,27,77
,206,0,35,34,67
,164,0,35,39,113
,311,0,35,43,84
,375,0,35,48,125
,246,0,35,56,85
,217,0,36,1,99
,207,0,36,3,107
,320,0,36,9,158
,233,0,36,19,73
,272,0,36,25,141
,428,0,36,29,95
,134,0,36,33,66
,121,0,36,37,82
EOF
•
6t
CHEMICAL .ENVIRONMENT AL TEC~LOGY, lNC.
ENVIRONMENTAL ANALYTICAL SERVICES
METHOD REFERENCES
Federal Register, Vol. 59, 40 CFR Part 136.3, January 31, 1994
--Metals, lnorganics, and Organics for groundwater and wastewater
Federal Register, Vol. 56, 40 CFR Parts 141-143, January 30, 1991
--Metals, lnorganics, and Organics for drinking water
"Groundwater Section Guidelines for the Investigation and Remediation of Soils and
Groundwater", NCDEHNR, DEM, March 1993.
--High Fraction Hydrocarbon and Low Fraction Hydrocarbon for groundwater and soil
SW-846, Third Edition, Revision I, July 1992
--lnorganics and Organics in soil or sludges. Metals in soil, sludge, or groundwater.
(Metals in groundwater are digested by Method 3030C, Standard Methods, 18th Edition)
40 CFR Part 261, Appendix II and Ill
--Toxic Characteristic Leaching Procedure
Standard Methods, 18th Edition, 1992
--Total and Fecal Coliform in wastewater, streams, and lakes
P.O. Box 12298 • Research Triangle Park. NC 27709
Teleohone (9191467-3090
Shipping: 102-A Woodwinds Industrial Court • Cary, NC 27511
F;11-. 19191467-3515
t , @I;'._·:
0
.::· ••• :: '·~11~~1. ,~.-if~t;t~i~~~tiQzUe~l( .. ,~~~:r,::,:,·:· .: :::,; ;t:;1'.fji
TLI Project: 46942 -Method 8280-A PCDD/PCDF Analysis (b)
Client Sample: SSFCX-4 Analysis File: VI84100
Client Project: n/a Matrix: SOIL
PCDDIPCDF SUMMARY REPORT
Specific Arialytes \
2.3.7.8-TCDD
1.2.3. 7.8-PeCDD
1.2,3.4, 7.8-HxCDD
1,2.3,6,7,8-HxCDD
1.2.3, 7,8,9-HxCDD
1.2.3.4,6,7,8-HpCDD
1.2.3.4.6.7.8.9-OCDD
2.3.7.8-TCDF
1.2.3.7.8-PeCDF
2.3,4.7.8-PeCDF
1.2.3.-1. 7.8-HxCDF
1.2.3.6. 7.8-HxCDF
2.3.-1.6. 7.8-HxCDF
1.2.3.7.8.9-HxCDF
1.2.3.4,6,7,8-HpCDF
1.2.3.-1. 7.8.9-HpCDF
1.2.3,4,6, 7 .8,9-OCDF
ND 0.01 ND
ND 0.03 ND
ND 0.03 ND
ND 0.03 ND
ND 0.03 ND
0.97 0.04 ND
18.3 0.06 ND
ND 0.01 ND
ND 0.02 ND
ND 0.02 ND
ND 0.02 ND
ND 0.02 ND
ND 0.02 ND
ND 0.03 ND
ND 0.03 ND
ND 0.03 ND
0.10 0.05 ND
Total Analytes ..
·. ·•·•·· co ii 6: (ppb j [)l •• (ppb) \····•
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
Triangle Laboratories, Inc.®
ND
ND
ND
2.2
ND
ND
ND
ND
0.01
0.03
0.03
0.04
0.01
0.02
0.02
0.03
801 Cap~ola Drive• Durham, North Carolina 2TT13
Phone: [phone] • Fax: [phone]
Page I of I
·e·co ra 1ono t
pnfsii ..
5
ichoanwn.al_Y1_· .. • .. •:. e in theii
u ·::.: : :.:::"\:-:.:::.':'·.-·
.. fJf '.~:j:,i:iJ~li~itbtt~~--( ·.
> specifi~ irialyte in the
•· Uri~s shown: .· ···•
. i ~larik ~ The conc~nl;~tionof the
method blank. ·
· •. ND -(Non-Detect) The
concentration of the.analyte
. is less than the detection .
Jim~.
8:!8A_PSR vl.01. L\RS 6.11.07
Printed: 13:08 10/19/98
62
TLI Project:
Client Sample:
Client Project:
Sample Matrix:
TL! ID:
Sample Size:
Dry Weight:
GC Column:
2.3.7.8-TCDD
1.2.3.7.8-PeCDD
1.2.3.4. 7 ,8-HxCDD
1.2.3,6,7.8-HxCDD
l.2.3.7,8,9-HxCDD
1,2,3.4.6. 7 ,S-1-lpCDD
1,2,3,4,6,7,S,9-OCDD
2.3.7.8-TCDr
1.2.3. 7 ,8-PeCDF
2,3.4, 7 .8-PeCDF
1.2.3.4, 7 .8-1-lxCDF
1.2,3.6,7,8-1-lxCDF
2.3.4.6,7 .8-1-lxCDr
1,2,3, 7,8,9-1-lxCDr
1,2,3,4,6,7,8-1-lpCDF
1,2,3,4,7,8,9-!-lpCDF
1.2,3,4,6,7,8,9-OCDF
Toutl TCDD
Tow PcCDD
Tow HxCDD
TowHpCDD
TowTCDF
Tow PeCDF
Tow HxCDF
Tow HpCDF
46942
SSFCX-4
n/a
SOIL
220-51-1
10.190 g
9.222 g
DB-5
Triangle Laboratories, lnc.o,
ND
ND
ND
ND
ND
0.97
18.3
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.10
ND
ND
2.2
ND
ND
ND
Method 8280-A PCDD/PCDF Analysis (b)
Analysis File: VI84100
Date Received: 10/15/98
Date Extracted: 10/15/98
Date Analyzed: 10/17/98
Dilution Factor: n/a
Blank File:
Analyst:
0
0
0
2
0
0
0
0
0.01
0.03
0.03
0.03
0.03
0.01
0.02
0.02
0.02
0.02
0.02
0.03
0.03
0.03
VI83700
ALW
0.03
0.03
0.02
0.02
0.03
Page 1 of 2
1.8
0.04
Spike File:
!Cal:
ConCal:
% Moisture:
% Lipid:
% Solids:
1.09
0.86
1.02
SP828A50
V85O12A
VI83500
9.5
n/a
90.5
32:42
35:05
35: 12
J_
J_
828A_PSR vl.01, LARS 6.11.07
801 Caprtola Drive• Durham, North Carolina 27713
Phone: [phone] • Fax: [phone]
Printed: 13:08 10/19/98
63
TLI Project:
Client Sample:
"Ci:-2,3,7,8-TCDF
13Ci:-2,3.7.8-TCDD
"Ci:-1,2,3,6,7,8-HxCDD
13Ci:-l.2.3,4,6,7 ,8-HpCDF
13Ci:-l.2.3,4.6. 7,8,9-OCDD
"CL-2.3,7,8-TCDD
"Ci:-1.2.3,4-TCDD
13Ci:-l.2.3,7,8.9-HxCDD
46942
SSFCX-4
4.1
4.6
4.7
8.8
9.2
2.0
Method 8280-A PCDD/PCDF Analysis (b)
Analysis File: VI84100
75.7 25%-150%
84.4 25%-150%
87.4 25%-150%
81.2 25%-150%
85.0 25%-150%
72.8 25%-150%
0.79
0.81
1.30
1.07
1.00
0.80
132
21:50
22:36
30:05
31:55
35:05
22:37
22:24
30:21
Data Reviewer: ___________ 'Jt-l-'--'-10/19/98
Triangle Laboratories, Inc . .,
801 Capttola Drive• Durham, North Carolina 27713
Phone: [phone] • Fax: [phone]
Page 2 of 2 8:::SA__PSR vl.01.LARS6.11.07
Printed: 13:08 10/19/98
TLI Project:
Client Sample:
Client Project:
Sample Matrix:
TL! ID:
Sample Size:
Dry Weight:
GC Column:
2,3. 7.8-TCDD
1.2.3. 7 .8-PeCDD
1.2.3.4.7.8-HxCDD
1.2.3.6. 7 .8-HxCDD
1.2.3.7.8,9-HxCDD
1 .2.3.-l.6. 7 .8-HpCDD
1.2.3.-1,6.7.8.9-OCDD
2.3. 7.8-TCDF
1.2.3. 7 .8-PcCDF
2.3.4. 7.8-PcCDF
1.2.3.-l. 7 .8-HxCDF
1.2.3.6. 7 .8-HxCDF
2,3.4.6.7.8-HxCDF
1.2.3. 7.8.9-HxCDF
1.2.3.4.6.7.8-HpCDF
1.2.3.4.7.8.9-HpCDF
1.2.3.4.6.7.8.9-OCDF
46942
SSFCX-4
n/a
SOIL
220-51-1
10.190 g
9.222 g
DB-5
ND
ND
ND
ND
ND
0.97
18.3
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.10
Date Received: 10/15/98
Date Extracted: 10/15/98
Date Analyzed: 10/17/98
Dilution Factor: 1
Blank File: Vl83700
Analyst: ALW
X I. =
X 0.5 =
X 0.1 =
X 0.1 =
X 0.1 =
X 0.01 =
X 0.001 =
X 0.1 =
X 0.05 =
X 0.5 =
X 0.1 =
X 0.1 =
X 0.1 =
X 0.1 =
X 0.01 =
X 0.01 =
X 0.()() 1 =
Toxicity Equivalents Report
Analysis File: VI84100
Spike File:
!Cal:
ConCal:
% Moisture:
% Lipid:
% Solids:
0.0097
0.0183
0.00010
SP828A50
V85O12A
Vl83500
9.5
n/a
90.5
Total 2,3,7,8-TCDD Toxicity (1989 ITF) Equivalents: 0.0281 ppb
(1) Detection Limits not used in calculations.
Note: 100% of EMPCs are used in the calculations.
Triangle Laboratories, Inc."
801 Cap~ola Drive • Durham. North Carolina 27713
Phone: [phone] • Fax: [phone]
Page I of I GRY_TEF ~I.OJ. MILES4.l6.J3
Printed: 13:19 10/19/98
65
Data Review By:
Page No.
10/19/98
Compound/
• Calculated Noise Area: 63.90
Listing of VI84100B.dbf
Matched GC Peaks/ Ratio/ Ret. Time
M_Z. QC.Log Omit Why .. RT. OK Ratio Total.Area ... Area.Peak.l .. Area.Peak.2 .. Rel.RT Compound.Name .. IO. Flags.
TCDF
304-306
304-306
13Cl2-TCDF
316-318
316-318
TCDD
320-322
320-322
37Cl-TCDD·
328
K
328
l3C12-TCDO
332-334
332-334
PeCOF
340-342
340-342
Pecoo
356-358
356-358
HxCDD
390-392 D
0.65-0.89
22:24 RO 1.89
Peak
622.00
622.00
407.00
0.830-1.088
215.00 1.026
0.820-1.105
21:50
Peak
0.65-0.89
o. 79 74,169.00
74,169.00
32,646.00 41,523.00 1.000 l3Cl2-2378-TCDF ISO
Above: TCDF / TCDD Follows
0. 65-0.89
21:50 RO 5.50 22.297 .00
Peak 22,297 .00
DC NL 0 00
DC WL 20:52 126 .00
DC WL 21:06 144 .00
21:42 122.00
22: 10 132.00
22: J7 24.888.00
DC WH 22:56 154.00
DC WH 23: 11 226.00
3 Peaks 25,142.00
0.65-0.89
22:24 0.80 71,123.00
22:36 0.81 57,527.00
DC WH 23:02 RO l. 46 29B.00
2 Peaks 128,650.00
-----------------------Above: TCDD I
1.32-1.78
DC WL 23:37 RO 36.85
0 Peaks
22,635.00
0.00
18,867.00
0.00
122.00
132. 00
24,888.00
31,629.00
25,708.00
PeCOF Follows
0.871-1.051
3,430. 00 0.966
0. 954-0. 999
0.923
o. 934
0.960
0. 981
1.001 37Cl-TCDD
l. 015
1.026
0.965-1.016
39,494.00 0.991 13Cl 2-123 4-TCDD
31,819.00 1. 000 l 3C 12-2 3 78-TCDD
1. 019
---------------------
1.085-1.265
l. 082
----------------------Above: PeCOF / PeCDD Follows---------------------
1. 32-1. 78
DC WH 27:51 RO 1.23
O Peaks
319. 00
0.00
1.104-1.217
1.232
----------------------Above: PeCDD / HxCDD Follows---------------------
D
.05-1.43
SN 28:53 RO 0.46 361.00
0.954-1.013
0.960
CLS
RSl
ISl
J
Triangle Laboratories, Inc.® Analytical Services Division
801 Capijola Drive• Durham, North Carolina 2n13 Printed: 13:09 10/19/98
Phone: [phone] • Fax: [phone]
I., 66
Page No.
10/19/98
Compowid/
2 Listing of V.00B.dbf • Matched GC Peaks/ Ratio/ Ret. Time
M_Z. QC Log Omit Why .. RT. OK Ratio Total.Area ... Area.Peak.l .. Area.Peak.2 .. Rel.RT Compound Name .. ID .. Flags.
D
390-392
l3Cl2-HxCDD
402-404
402-404
HpCOF
408-410 D
408-410
13Cl2-HpCOF
420-422
420-422
HpCDD
4::4-426
424-426
OCDF
442-444 M
442-444
ocoo
458-460
458-460
13C12-0CDD
470-472
470-472
D SN 29:30 RO 0.69
DC WH 30:46 RO 4.64
0 Peaks
.05-1.43
30:05 l. 30
30: 21 1. 32
30:31 1. 24
30:44 RO 0.05
4 Peaks
407.00
660.00
o.oo
30,167.00
36,302.00
360.00
3,177.00
70,006.00
17,040.00
20,650.00
199.00
158. 00
0.981
1.023
0.967-1.033
13,127.00 1.000 13C12-HxCDD
15,652.00 l.009 13C12-HxCDD
161.00 1.014
3,019.00 1.022
678
789
----------------------Above: HxCDD / HpCDF Follows---------------------
D
0. 88-1. 20
SN 31:55 RO 2.21
0 Peaks
0.88-1.20
597.00
0.00
0.994-1.040
1.000 1234678-HpCOF
0.994-1.005
1S2
RS2
AN
31:55 1.07 64,815.00
64,815.00
33,475.00 31,340 00 1.000 13Cl2-HpCOF 678 IS]
Peak
----------------------Above: HpCDF / HpCDD Follows---------------------
0.88-1 . 20 l.063-1.103
DC WL 31: 55 RO 3. 54 20,742 .00 . 061
32:09 1.07 5,042 .00 2,611.00 2,431.00 . 069
32:42 1. 09 3,365 .00 2,013.00 1.852.00 .087 1234678-HpCDD
2 Peaks 8.907. 00
----------------------Above; HpCDD I Octa-COO and CDF Follows----------
0. 76-1.02
35:12 1.02
1 Peak
0. 76-1.02
35:05 0. 86
Peak
0 . 76-1.02
35:05 1.00
1 Peak
334.00
334.00
46,410.00
46,410.00
26,302.00
26,302.00
169.00
21,430.00
13,126.00
0.886-1.114
165.00 1.003 OCDF
0.996-1.005
24,980.00 1. 000 OCDD
0.996-1.005
13 .176. 00 1.000 13Cl2-0COD
J
AN J
AN J
AN
1S4
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive• Durham, North Carolina 2n13 Printed: 13:09 10/19/98
Phone: [phone] • Fax: [phone] G7
Page No.
10/19/98
Compound/
3 Listing of V.OOB.dbf • Matched GC Peaks/ Ratio/ Ret. Time
M_Z. QC Log Omit Why .. RT. OK Ratio Total.Area ... Area.Peak.l .. Area.Peak.2 .. Rel.RT Compound.Name .. ID .. Flags.
Column Description .. "Why" Code Description ......... QC Log Desc.
M_Z -Nominal Ion Mass (es)
.RT. -Retention Time (mm:ss}
Rat.l -Ratio of M/M+2 Ions
WL-Below Retention Time Window
WH-Above Retention Time Window
SN-Below Signal to Noise Level
OK -RO=Ratio Outside Limits <M-Below Method Detection Limit
Rel.RT-Relative Retention Time NL-Channel Specific Noise Level
••• End of Report***
Triangle Laboratories, Inc.® Analytical Services Division
801 Capijola Drive• Durham, North Carolina 27713
Phone: [phone] • Fax: [phone]
A-Peak Added
K-Peak Kept
D-Peak Deleted
T-Tirne Changed
M-Peak Area Changed
N-Name Changed
X-Ether Interference
Printed: 13:09 10/19/98
68
Data File: /chem/V.i/1&1-7-98.b/VI841.d
Report Date: 17-0ct-19W 22:48 •
TRIANGLE LABORATORIES, INC.
SEMI-VOLATILE QUANTITATION
/chem/V.i/10-17-98.b/VI841.d
REPORT
Page 1
Data file
Lab. Id.
Inj Date
Operator
Smp Info
Misc Info
Comment :
TLI#46942
17-OCT-98 22:05
ALW
Autotune Date: 12-Oct-98 08:51:1
Inst ID: V.i
TLI#46942 SSFCX-4
220-51-1
Method /chem/V.i/10-17-98.b/8280.m
Meth Date 17-0ct-1998 16:38
Cal Date 27-JUL-98 10:47
Als bottle: 6
Dil Factor: 1.000
Integrator: HP RTE
Sample Type: mm5
No Target Compounds Detected.
Cal File: Vh485.d
Target Version: Target 2.20
compound Sublist: all.sub
bL-Areo___"'-(1%J(~s'7o'6-t-31'619)
C 7J~ g + 8iGilo)
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98
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94
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90
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Triangle Labs Inc.
Triangle Labs Inc.
Run Sat Oct 17 22:05:41 1998
Ion 304.00 amu from Vl841.d
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12000
"'
10000
M CD
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8000
6000
4000 • ,.._ "' ~ N "' M
2000 in ... "' l6 ...... CD O> -... M ..; .,;.
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N
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8000
6000
4000
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2000 CD N
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0
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400
300
200
100
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Abundance
400
300
200
Triangle Labs Inc.
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Abundance Triangle Labs Inc.
TetraCDD
6000 "' M a,
5000 ;:.
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3000
2000 •
1000
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4000
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9000
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7000
8000
5000
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3000
2000
1000
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Abundance
9000
8000
7000
8000
5000
4000
3000
2000
1000
0
18.0
Triangle Labs Inc.
Triangle Labs Inc.
19.0 20.0
Run Sat Oct 17 22:05:41 1998
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12000
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8000
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8000 io
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6000
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1000 ,.,:
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200
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Triangle Labs Inc.
Triangle Labs Inc.
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300
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200
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500
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200
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Triangle Labs Inc.
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12000
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6000
4000
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12000
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8000
6000
4000
2000
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6000
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4000
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,,,,,,,/chem/V.i/10-17-a.bfVI841.RPI'
,,,,,,,Mass,Area,h,m,s,~ght
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3 06 t t t t t
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316, , , , ,
,160,0,21,31,37
,32646,0,21,50,8334
,100,0,22,36,36
,123,0,22,44,49
,113,0,22,46,44
,493,0,23,49,98
,126,0,23,57,32
,109,0,24,10,39
318, , , , ,
,41523,0,21,50,10703
,107,0,22,17,30
320 t t t I I
,18867,0,21,50,4786
J 22 t I t I t
,3430,0,21,50,794
,103,0,23,33,35
259,,,,,
,104,0,21,58,25
,124,0,22,52,48
J 28 t t t t t
,126,0,20,52,21
,144,0,21,6,55
, 122, 0, 21, 42 ,.42
,132,0,22,10,57
,24888,0,22,37,6565
,154,0,22,56,38
,226,0,23,11,41
332, , , , ,
,112,0,22,3,61
,175,0,22,6,89
,111,0,22,11,46
,138,0,22,18,46
,31629,0,22,24,8183
,25708,0,22,36,7238
,268,0,22,45,117
,162,0,22,52,69
, 117, 0, 22, 58, 57
,177,0,23,2,72
3 34, , , , ,
,39494,0,22,24,10431
,31819,0,22,36,8966
, 121, o, 23, 1, 27
J4Q f t t t I
,22037,0,23,37,6638
,140,0,27,7,38
J42, I I I I
,598,0,23,38,186
,117,0,26,31,46
,102,0,27,46,44
,146,0,27,52,36
,110,0,28,0,38
277, , , , ,
,178,0,26,13,43
,139,0,27,4,34
410, , , , ,
,279,0,25,1,90
356, , , , ,
,108,0,24,53,37
•
92
,116,0,25,0,46
,114,0,25,33,59
,147,0,25,48,44
,114,0,26,7,73
,100,0,26,25,47
,424,0,26,31,126
,141,0,26,49,50
,143,0,26,53,58
,294,0,27,2,72
,114,0,27,9,61
,104,0,27,11,62
,244,0,27,19,50
,178,0,27,39,85
,176,0,27,51,99
3 58, , , , ,
,112,0,25,53,27
,143,0,27,50,30
311, , , , ,
,170,0,28,15,70
,176,0,28,19,57
,102,0,28,30,68
,192,0,28,33,65
,166,0,28,37,82
,467,0,28,46,109
,219,0,28,52,68
,245,0,28,58,86
,235,0,29,1,70
,181,0,29,5,51
,121,0,29,13,101
,299,0,29,18,72
,116,0,29,24,57
,160,0,29,33,79
,146,0,29,41,96
,127,0,29,43,66
,142,0,29,46,97
,223,0,29,53,60
,346,0,30,5,91
,205,0,30,21,109
,112,0,30,24,43
,235,0,30,50,94
,179,0,30,59,109
,172,0,31,2,56
446, , , , , .
,180,0,28,4,71
,198,0,28,8,84
,388,0,28,16,68
,181,0,28,23,55
,165,0,28,28,68
,127,0,28,31,103
,319,0,28,38,61
,209,0,28,43,52
,140,0,28,52,95
,231,0,28,57,86
,196,0,29,0,76
,420,0,29,3,104
,202,0,29,17,64
,226,0,29,20,84
, 13 2, 0, 29, 2 6, 60
,224,0,29,30,60
,135,0,29,41,70
,242,0,29,46,100
,364,0,29,53,118
,287,0,29,56,105
,205,0,30,2,97
,138,0,30,5,73
,183,0,30,14,78
• •
93
,224,0,30,22,79
,152,0,30,25,91
,129,0,30,36,60
,9511,0,30,48,1081
390, , , , ,
,169,0,28,30,47
,113,0,28,53,58
,231,0,29,18,61
,166,0,29,30,58
,130,0,29,43,42
,146,0,29,54,48
,228,0,30,14,48
,543,0,30,46,143
392, , , , ,
,248,0,28,53,71
,241,0,29,31,82
,102,0,29,48,38
,316,0,30,21,58
,136,0,30,29,66
,110,0,30,37,44
,117,0,30,44,40
402,,,,,
,101,0,29,48,18
,17040,0,30,5,7414
,20650,0,30,21,8622
,199,0,30,31,41
,158,0,30,44,39
404, I t I t
,100,0,29,41,26
,157,0,29,54,42
,13127,0,30,5,6001
,15652,0,30,21,6607
,161,0,30,33,54
,3019,0,30,46,448
408, , , , ,
,446,0,31,38,213
,108,0,31,44,43
,411,0,31,55,89
,149,0,32,14,75
,144,0,32,32,37
,156,0,32,47,43
,116,0,33,21,46
410 I I I I I
,186,0,31,55,71
420, , , , ,
,33475,0,31,55,15054
422 I t I t I
,31340,0,31,55,13781
,1248,0,32,9,494
424, , , , ,
,16172,0,31,55,7171
,2611,0,32,9,1092
,2013,0,32,42,797
426, , , , ,
,4570,0,31,55,1944
,2431,0,32,9,1011
,1852,0,32,42,725
442,,,,,
,212,0,35,12,54
444, , , , ,
,170,0,35,11,47
458, I t t I
,21430,0,35,5,7680
460, , , , ,
,347,0,34,51,66
,716,0,34,59,165
• •
94
,24980,0,35,5,9201
,142,0,35,30,39
4 70, , , , ,
,13126,0,35,5,4261
,100,0,35,37,23
4 72, , , , ,
,13176,0,35,5,4732
EOF
• •
95
lon 442.00 amu from VI841.d
Peak# Ret Time
1 35.205
Type
MM
• Width
0.117
Area
169.00
• start Time
35.155
End Time
35.272
===========================-===================-============================
Ion 444.00 amu from VI841.d
Peak# Ret Time
1 35.189
Type
MM
Width
0.100
Area
165.00
Start Time
35.155
End Time
35.256
96
c.o
·-J
Ion 442.00 amu from Vl841.d
Run at 10:05 PM EDT on Sat Oct 17. 1998
Abundance
1'10
120
100
80
60
40
20 • 0
Ion 444.00 amu from Vl841.d
Abundance
140
120
100
80
60
40
20
0 • ~-,--,---,----,----,--,-----,----,---,--,--,---~----.-,--,---,-----,---.---,---,,----,---,--,---,,---~---,-
34.4 34.6 34.8 35.0 35.2 35.4
Time (min.)
•
CALIBRATION
DATA
Triangle Laboratories, Inc.
801 Capitola Drive P.O. Box 13485
Durham, NC 27713-4411 Res«1rr:h Triangle Parle, NC Z77rJ9.3485
919-544-5729 Fax II 919-544-5491
98
TRIANGLE L.\BORATORIES, WC:.
Initial Calil:lration SUmnary for V'B5012A
Analysis Date .... : 10/12/98 • Method ...... :
Instrument ....... : V
Analytes RF SD \RSD RT RT/LO
2378-TCDF l.059 0.021 2\ 21:54 17 :53
TOTAL TCDF l.059
2378-TCDD 1.157 0.036 H 22:39 18:39
TOTAL TCDD l. 157
12378-PeCDF 0.744 0.015 2\ 25:56 22:53
23478-PeCDF 0.763 0.000 0\ 26:40
TOTAL PeCDF 0.744
12378-PeCDD 0.596 0.020 3\ 26:59 23:39
TOTAL PeCDD 0. 596
123478-HxCDF l.194 0,000 0\ 29:22 24:57
123678-HxCDF l.224 0.035 3% 29:26
234678-HxCDF l. 160 0.000 0\ 29:56
12 3 7 8 9-HxCDF l. 069 0,000 0\ 30:36
TOTAL HxCDF l. 069
123478-HxCDD 0.817 0.000 0\ 30:04 27:07
123678-HxCDD 0.927 0.018 2\ 30:07
123789-HxCDD 0.924 ·o. ooo 0\ 30:24
TOTAL HxCDD 0.817
1234678-HpCDF 0.872 0.010 1\ 31:57 28:57
1234789-HpCDF 0.739 0.000 0\ 33:05
TOTAL HpCDF 0.739
1234678-HpCDD 0.696 0.025 4% 32:44 31:07
TOTAL HpCDD 0.696
OCDF l. 415 0.046 3% 35: 14 JL07
OCDD 1. 075 0.027 3% 35:07 31 :07
Other Standards R_F SD \RSD RT RT/LO
37Cl-TCDD l. 02:. 0,000 0\ 22:42 20:39
Internal Standards RF SD \RSD RT RT/LO
1JC12-2J 7 8-TCDF 1. 447 0.067 S\ 21:53 19:53
1JC12-237 8-TCDD l. DJS 0.045 4% 22:39 20:39
13C12-HxCDD 678 0.980 0.038 4% 30:07 29:07
llC12-HpCDF 678 1.161 0.042 4% ll:57 29:57
1JC12-0CDD 0, 415 0.005 1\ 35:07 33:07
Recovery Standards RF SD \RSD RT RT/LO
13Cl2-12J4-TCDD l.000 0.000 0\ 22:27
llC12-HxCDD 789 l. 000 0.000 0\ 30:23
... End of Report . ..
Page 1
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 2n13
Phone: {919) 544-5729 • Fax: {919) 544-5491
RT/HI
25:53
26:39
30:53
31:39
32:57
35:07
36:57
39:07
39:07
39:07
RT/HI
24:39
RT/HI
23:53
24:39
ll:07
33:57
37: 07
RT/HI
Date: 10/11/98
828A •
Ratiol Ratio2 N
0.772 5
0.772 5
0. 776 5
0,776 5
l.574 5
l.582 1
l. 578 5
l. 584 5
l. 584 5
l.256 1
l.251 5
l.263 1
l.247 1
l.252 5
l. 281 1
l. 250 5
1.241 1
l. 255 5
1.024 5
1.03) 1
l. 024 5
1.055 5
1.055 5
0. 914 5
0.386 5
Rati.ol Ratio2 N
1
Ratiol Racio2 N
0.301 5
0.799 5
1. 292 5
1.063 5
0.922 5
Ratiol Ratio2 N
0.803 5
1.288 5
Printed: 17:06 10/11/98
99
Date: 10/19/98 TRIANGLE .ORATORIES OF RTF, INC. • Continui Calibration for VI83500
Analysis Date .... : 10/17/98 Method ...... : 828A
Operator ......... : ALW Instrument .. : V
Init Calibration.: V85012A Std.Cone .... :
!Cal Date ........ : 10/12/98
Analyte Sumnary !Cal
Name RF Ratio RT RT Rel. RT RF
1&2 Lo/High
2378-TCDF 1. 052 0.78 18:12 21: 56 1.0008 1. 059
23:51
TOTAL TCDF 1.052 0.78 1. 059
2378-TCDD 1. 163 0.77 19:46 22:41 1.0000 1.157
23:51
TOTAL TCDD 1.163 0. 77 1.157
12378-PeCDF 0.738 1. 55 23:47 25:57 1.1840 0.744
27:44
2347.S-PeCDF 0.708 1. 55 26:40 1. 2167 0. 763
TOTAL PeCDF 0.708 1. 55 0.744
12378-PeCDD 0.596 1. 58 25:02 27: 01 1.1910 0.596
27:37
TOTAL PeCDD 0.596 1. 58 0.596
123478-HxCDF 1. 193 l. 25 28: 15 29:22 0. 9187 1.194
30:49
123678-HxCDF 1. 237 1. 24 29:27 0. 9213 1. 224
234678-HxCDF 1. 159 1. 24 29:56 0. 93 64 1.160
123789-HxCDF 1. 038 1. 24 30:36 0. 9572 1.069
TOTAL HxCDF 1.038 1.25 1. 069
123478-HxCDD 0.831 1. 26 28:45 30:04 0. 9978 0.817
30: 31
123678-HxCDD 0.908 1.26 30:08 1. 0000 0.927
123789-HxCDD 0. 915 1. 26 30:24 1. 0088 0.924
TOTAL HxCDD 0.831 1.26 0.817
123"4678-HpCDF 0.877 1.02 31:47 31:58 1. 0000 0. 872
33:14
1234789-HpCDF 0.806 1.02 33:05 1.0349 0.739
TOTAL HpCDF 0.806 1. 02 0.739
1234678-HpCDD 0. 714 1. 04 32:01 32:46 1.0874 0.696
33:15
Page 1
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive• Durham, North Carolina 27713
Phone: [phone] • Fax: [phone]
0.50
Delta
RF %D
-0.007 -0.7%
-0.007
0.006 0.5%
0.006
-0.006 -0.8%
-0.055 -7.3%
-0.036
0.000 0.0%
0.000
-0.001 -0 .1\
0. 013 l. 1%
-0.001 -0.1%
-0.031 -2.9%
-0.031
0.014 1. 8%
-0.019 -2.1\
-0.009 -1. 0%
0.014
0.005 0.6%
0.067 9.0%
0.067
0. 018 · ·2.6%
Printed: 09:48 10/19/98
100
Dac:e: 10/19/98 TRIANGLE riTORIES OF RTP, INC.
Continuin alibration for VI83SOO
TOTAL HpCDD 0.714 1. 04
OCDF 1. 393 0. 92 31:07 35,14 1.0033
39:07
OCDD 1. 048 0.89 34,58 35,08 1.0005
35:18
Other Standard Sumnary
Name RF Ratio RT RT Rel. RT
1&2 Lo/High
37Cl-TCDD 0.961 21,39 22:42 1.0007
22:40
Internal Standard Surrrnary
Name RF Ratio RT RT Rel. RT
1&2 Lo/High
l 3C 12-23 7 8-TCDF 1. 378 0. 8_0 17,58 21,55 1. 0000
24, 13
13C12-2378-TCDD 0.958 0.78 21, 53 22,41 1. 0000
23:03
13C12-HxCDD 678 0.951 1. 29 29,08 30,08 1. 0000
31,08
1JC12-HpCDF 678 1. 100 1.06 31,47 31,58 1. 0000
32,07
13C12-0CDD 0. 426 0.93 34:58 35,07 1.0000
35, 18
Recovery Standard Sunmary
Name RF Ratio RT RT Rel. RT
1&2 Lo/High
l3Cl2-12J4-TCDD 1.000 0.81 21,53 22,29 0. 9912
23:03
lJC12-HxCDD 789 1.000 1.28 29,08 J0:24 1. 0088
3L 08
Page 2
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: [phone] • Fax: [phone]
0.696
1. 415
1. 075
!Cal
RF
1. 021
!Cal
RF
1. 447
1. 035
0.980
1. 161
0.415
!Cal
RF
1.000
1.000
• 0.018
-0.022 -1. 6%
-0.027 -2.5%
Delta
RF %D
-0.060 -5. 9%
Delta
RF %D
-0.069 -4.8%
-0.077 -7. 5%
-0.029 -2.9%
-0.061 -5. 2%
0.011 2.7%
Delta
RF %D
0.000 0.0%
0.000 0.0%
Printed: 09:48 10/19/98
101