NCD981475932_19950417_FCX Inc. (Washington Plant)_FRBCERCLA RA_Air Emissions Test Report - McLaren Hart-OCR

~'
I
I
I
I
I
I
I
.I·
I
I
I
I
I
I
I
I
I
I ]I
AIR EMISSIONS TEST REPORT
FOR
McLAREN HART FCX SUPERFUND SITE
TEST DATES: DECEMBER 15, 1994
MARCH 16-17, 1995
REPORT DATE: APRIL 17, 1995
• r-1 ..... ~ . .. ..... . -. r~-•• r .._..,, • •
... -4 •
ETS, INC.
A subsidiary of ETS International, Inc.
ETS, Inc.
1401 Municipal Road, N. W.
· Roanoke, VA 24012
703-265-0004
703-265-0131 fax
Air Compliance Division
1635-A Bustleton Pike
Feasterville, PA 19053
215-364-8940
215-364-4596 fax
Pollution Control Consultants_.
Specializing In
Toxic Emission Measurement and Control
ETS CONTRACT NO. 94-365
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
11
REPORT CERTIFICATION
The sampling and analysis perfo=ed for this report were
carried out under my direction and supervision.
DATE: "i' /; z/CJ,5"
SIGNATURE: ?J. ~--ik~
Tony Un erwood
Project Manager
ETS, Inc.
I have reviewed all testing details and results in· this
report. and hereby certify that the test report is authentic and
DATE: C24 ,
SIGNATURE: C Ii;:.
Andy A. Hetz ·
Manager -Field Services
ETS, Inc.
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
TABLE OF CONTENTS
PAGE
1.0 INTRODUCTION. . . 1
1.1 BACKGROUND 1
1.2 OBJECTIVE. . 1
1.3 TEST PROGRAM 1
2.0 SUMMARY OF RESULTS 2
3.0 SAMPLING AND ANALYTICAL PROCEDURES 10
3.1 SAMPLING PROCEDURES. . . . . 10
3.1.1 SAMPLING POINT DETERMINATION -
EPA METHOD 1 . . . . . . . . 10
3.1.2 VOLUMETRIC MEASUREMENTS -EPA METHOD'2 12
3.1.3 MOLECULAR WEIGHT DETERMINATION -
EPA METHOD 3 . . . . . . . . . . . . . 12
3.1.4 FLUE GAS MOISTURE CONTENT -EPA METHOD 4 13
3.1.5 PARTICULATE AND HC1 SAMPLING -
EPA METHOD 0050 . . . . . . . . . . 13
3.1.5.1 SAMPLING TRAIN DESCRIPTION 13
3.1.5.2 SAMPLE TRAIN OPERATION 16
3.1.5.3 SAMPLE RECOVERY AND CLEAN-UP 16
3.1.5.4 FIELD BLANKS . . . . . . . . 17
3.1.6 SEMIVOLATILE SAMPLING -EPA METHOD 23 17
3.1.6.1 SAMPLING TRAIN DESCRIPTION 17
3.1.6.2 SAMPLING TRAIN PREPARATION 20
3.1.6.3 SAMPLE TRAIN OPERATION 20
3.1.6.4 SAMPLE RECOVERY AND CLEAN-UP 21
3.1.6.5 SAMPLE STORAGE AND TRANSPORT 23
3.1.6.6 FIELD BLANKS . . . . . . . 23
3.1.7 VOLATILE ORGANICS SAMPLING
-EPA METHOD 0030 . . . . . . . . . 23
3.1.7.1 SAMPLING TRAIN DESCRIPTION 24
3.1.7.2 SAMPLING TRAIN PREPARATION' 24
3.1.7.3 SAMPLE TRAIN OPERATION 26
3.1.7.4 SAMPLE RECOVERY AND CLEAN-UP 26
3 . 1. 7. 5 FIELD BLANKS . . . . . . . . . 2 7
3.2 ANALYTICAL PROCEDURES. . . . . . . . . . . . 27
3.2.1 OXYGEN AND CARBON DIOXIDE -EPA METHOD 3 27
3.2.2 MOISTURE CONTENT -EPA METHOD 4 28
3.2.3 PARTICULATE ANALYSIS -EPA METHOD 5 28
3.2.4 HCl ANALYSES -EPA METHOD 0050 29
3.2.5 PCDDs/PCDFs ANALYSES ... ; . 29
3.2.6 SEMIVOLATILE ORGANICS ANALYSES 29
3.2.7 PCBs ANALYSES . . . . . . 30
3.2.8 PESTICIDES ANALYSES 30
3.2.9 VOLATILE ORGANICS ANALYSES 31
3.3 DATA ANALYSIS. . . . 31
3. 4 EQUIPMENT CALIBRATION . . . . . .· 32
i
. TABLE OF CONTENTS /CONTINUED)
LIST OF TABLES
TABLE 1 -SUMMARY OF PARTICULATE AND HCL EMISSIONS
TABLE 2 -SUMMARY OF PCDD/PCDF EMISSIONS
TABLE 3 -SUMMARY OF SEMIVOLATILE ORGANIC COMPOUND RESULTS
TABLE 4 -SUMMARY OF PCB RESULTS
TABLE 5 -SUMMARY OF PESTICIDES RESULTS
TABLE 6 -SUMMARY OF VOLATILE ORGANIC COMPOUND RESULTS
LIST OF FIGURES
FIGURE 1 -SAMPLING AND TRAVERSE POINTS
FIGURE 2 -EPA METHOD 3 SAMPLING TRAIN
FIGURE 3 -EPA METHOD 0050 SAMPLING TRAIN
FIGURE 4 -EPA METHOD 23 SAMPLING TRAIN.
FIGURE 5 --EPA METHOD 0030 SAMPLING TRAIN
LIST OF APPENDICES
APPENDIX A -TEST LOG
APPENDIX B -DATA AND RESULTS FOR PARTICULATE AND HCl
TESTING (EPA METHOD 0050)
APPENDIX C -DATA AND RESULTS FOR DIOXINS/FURANS TESTING
(EPA METHOD 23)
APPENDIX D -DATA AND RESULTS FOR SEMIVOLATILES COMPOUNDS
TESTING (EPA METHOD 23)
3
4
5
7
8
9
11
14
15
18
25
APPENDIX E -DATA AND RESULTS FOR PCBs TESTING (EPA METHOD 23)
APPENDIX F -DATA AND RESULTS FOR PESTICIDES TESTING
(EPA METHOD 23)
ii
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
TABLE OF CONTENTS (CONTINUED)
LIST OF APPENDICES (CONTINUED)
APPENDIX G -DATA AND RESULTS FOR VOLATILE COMPOUNDS TESTING
(EPA METHOD 0030)
APPENDIX H -CALCULATIONS
APPENDIX I -RAW FIELD DATA FOR PARTICULATE AND HCl
TESTING (EPA METHOD 0050)
APPENDIX J -RAW FIELD DATA FOR DIOXINS/FURANS, SEMIVOLATILES,
PCBs, AND PESTICIDES TESTING (EPA METHOD 23)
APPENDIX K -RAW FIELD DATA FOR VOLATILE COMPOUNDS TESTING
(EPA METHOD 0030)
APPENDIX L -RAW FIELD DATA FOR 0 2 AND CO2 ANALYSIS
(EPA METHOD 3A)
APPENDIX M -GRAVIMETRIC LABORATORY DATA
APPENDIX N -HYDROGEN CHLORIDE LABORATORY DATA
APPENDIX O -DIOXINS/FURANS LABORATORY DATA
APPENDIX P - SEMIVOLATILE LABORATORY DATA
APPENDIX Q -PCBs LABORATORY DATA
APPENDIX R -PESTICIDES LABORATORY DATA
APPENDIX S -VOLATILES LABORATORY DATA
APPENDIX T -FIELD EQUIPMENT CALIBRATION DATA
iii
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
1.0 INTRODUCTION
1.1 Background: An air emissions test program was conducted at
the McLaren Hart FCX Superfund Site in Washington, North
Carolina. The test program was conducted on December 15, 1994
and March 16 through 17, 1~95 by ETS, Incorporated (ETS) of
Roanoke, Virginia. ETS personnel participating in the test
program for the December trip were Jeff Smith and Terry
Williamson. For the March trip, ETS personnel who participated
were Tony Underwood and Matt Bauman. The test program was
witnessed by Paul Peronard of the United States Environmental
Protection Agency (USEPA).
1.2 Objective: The purpose of this test program was to conduct
performance tests on a IRHV-2000 high vacuum thermal desorption
system for total suspended particulate (TSP), hydrochloric acid
(HCl), dioxins and furans (PCDDs/PCDFs), polychlorinated
biphenyls (PCBs), pesticides, semivolatile organic sampling train
(Semi-VOST) compounds, and volatile organic sampling train (VOST)
compounds.
1.3 Test Program: The test program consisted of performing one
measurement for TSP and HCl and two measurements for PCDDs/PCDFs,
PCBs, pesticides, Semi-VOST and VOST compounds. At the request
of McLaren Hart, only test run 2 was analyzed for the tests where
two measurements were performed. Each measurement included
determination of the subject pollutant emissions as well as
1
measuring the average gas temperature, moisture content,
molecular weight, gas velocity, and volumetric flow rate of the
flue gas. The testing was conducted in accordance with the
procedures of Appendix A of the Code of Federal Regulations,
Title 40, Part 60, (40 CFR 60), and other methods accepted by the
EPA. Appendix A contains a test log which provides the exact
dates and times for each of the tests.
2.0 SUMMARY OF RESULTS
Tables 1 through 6 present summaries of the results for
particulate and HCl, PCDDs/PCDFs, sernivolatile organic compounds,
PCBs, pesticides, and volatile organic compound emissions,
respectively. More detailed data and results are presented in
Appendices B through G.
2
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
TABLE 1
SUMMARY OF PARTICULATE AND HCI EMISSIONS
MCLAREN HART
RUN I.D.
DATE
TIME STARTED
TIME ENDED
STACK OUTLET
SAMPLING PARAMETERS
Metered Volume -def
Corrected Volume -dscf
Total Test Time -min
% lsokinetics
GAS PARAMETERS
Gas Temperature - • F
Oxygen -%
Carbon Dioxide -%
Moisture -%
GAS FLOWRA TE
Velocity -ft/sec
Actual Volume -acfm
Standard Volume -dscfm
PARTICULATE EMISSIONS
Cone. -gr/dscf
Mass Rate -lb/hr
HCI EMISSIONS*
Concentration -ppmdv
Cone. -ppmdv @ 7% 02
Mass Rate -lbs/hr
<
<
<
SO-M0050-R1
03/17/95
14:22
17:27
217.750
212.217
185
98.4
86
18.6
1.6
2.9
,24.99
294
276
0.001
0.001
1.91
11.53
2.99E-03
(*) HCI emmisions are calculated using a detection limit of
0.1 ppm, the lowest standard concentration, which gives a
minimum detection limit of 1.18 mg/ml. This detection
limit was used because the Cl concentration detected in
the blank was higher than the Cl concentration detected
in the sample.
3
TABLE2
SUMMARY OF PCDD/PCOF EMISSIONS
McLAREN HART
STACK OUTLET
RUN 1.0.
DATE
TIME STARTED
TIME ENDED
SAMPLING PARAMETERS
Metered Volume -def
Corrected Volume -dscf
Total Test Time -min
% lsokinetics
GAS PARAMETERS
Gas Temperature - • F
Oxygen -%
Carbon Dioxide -%
Moisture -%
GAS FLOWRA TE
Velocity -ft/sec
Actual Volume -acfm -
Standard Volume.-dscfm
PCDD/PCDF EMISSIONS
(Total as 2378-TCDD Toxic
Equivalents)
Cone. -ng/Nm3 @7% 02
Mass Rate -lb/hr
4
SO-M23-R2
03/17/95
09:02
13:00
196.215
192.086
238
97.4
77
18.5
1.6
2.3
17.38
205
196
1.18E-01
1 40El11/ . ' I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
•1i
' l
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
SAMPLING DATA:
Run Number:
Corr. Sample Volume:
Corr. Flowrate
02 Content:
CO2 Content:
ANALYTICAL DATA
,2' -oxybis( 1-Chloropropane)
4-Methylphenol
N-Nitroso-di-n-propylamine
Hexachloroethane
Nitrobenzene
lsophorone
-Nitrophenol
,4-0imethylphenol
,4-Dichlorophenol
1,2,4-Trichlorobenzene
hloroaniline
,4,~ Trichlorophenol
-Chloronaphthalene
TABLE 3
SUMMARY OF SEMIVOLATILE ORGANICS RESULTS
McLAREN HART
STACK OUTLET
SO-M23-R2
192.086 dscf
196 dscfm
18.5 %
1.6 %
< 3.95 0.00 4 <
< 2.82 0.00 4 <
< 2.48 0.00 4 <
J 2.76 0.00 4 J
< 2.47 0.00 4 <
< 5.30 0.00 4 <
BJ 21.87 B 67.25 4
< 3.55 0.00 4 <
< 3.32 J 14.93 4
< 6.16 0.00 4 <
< 5.54 0.00 4 <
< 3.52 0.00 4 <
< 1.91 0.00 4 <
< 5.11 0.00 4 <
< 3.73 0.00 4 <
< 3.75 0.00 4 <
< 8.73 105.54 4
< 3.89 0.00 4 <
< 3.27 0.00 4 <
B 54.78 B 47.79 4 B
< 2.70 0.00 4 <
< 5.02 0.00 4 <
< 4.02 0.00 4 <
< 1.93 0.00 4 <
< 4.65 0.00 4 <
< 4.64 0.00 4 <
< 4.26 0.00 4 <
< 1.82 0.00 4 <
< 6.57 0.00 4 <
< 1.63 0.00 4 <
< 6.16 0.00 4 <
< 4.44 0.00 4 <
< 1.19 0.00 4 <
5
Page 1 of 2
i•,·svoceij_~*@N~I +•••tll1J\S.!;••t
I \i~r•
1.80E-06
15.80 < 1.27E-06 < 2.14E-06
11.28 < 9.06E-07 < 1.52E-06
9.92 < 7.97E-07 < 1.34E-06
11.04 J 8.87E-07 .J 1.49E-06
9.88 < 7.94E-07 < 1.34E-06
21.20 < 1.70E-06 < 2.87E-06
0.00 0.OOE+OO 0.OOE+OO
14.20 < 1.14E-06 < 1.92E-06
0.00 0.OOE+OO 0.OOE+OO
24.64 < 1.98E-06 < 3.33E-06
22.16 < 1.78E-06 < 3.00E-06
14.08 < 1.13E-06 < 1.00E-06
7.64 < 6.14E-07 < 1.03E-06
20.44 < 1.64E-06 < 2.76E-06
14.92 < 1.20E-06 < 2.02E-06
15.00 < 1.21 E-06 < 2.03E-06
0.00 0.OOE+OO 0.OOE+OO
15.56 < 1.25E-06 < 2.10E-06
13.08 < 1.0SE-06 < 1.TTE-06
27.96 B 2.25E-06 B 3.78E-06
10.80 < 8.6BE-07 < 1.48E-06
20.08 < 1.61E-06 < 2.71E-06
16.08 < 1.29E-06 < 2.17E-06
7.72 < 6.20E-07 < 1.04E-06 I
18.60 < 1.49E-06 < 2.51E-06
18.56 < 1.49E-06 < 2.51E-06
17.04 < 1.37E-06 < 2.30E-06
7.28 < 5.BSE-07 < 9.84E-07
26.28 < 2.11E-06 < 3.SSE-06
6.52 < 5.24E-07 < 8.81E-07
24.64 < 1.98E-06 < 3.33E-06
17.76 < 1.43E-06 < 2.40E-06
4.76 < 3.82E-07 < 6.44E-07
TABLE3
SUMMARY OF SEMIVOLATILE ORGANICS RESULTS
McLAREN HART
STACK OUTLET
SAMPLING DATA:
Run Number:
Corr. Sample Volume:
Corr. Flowrate
02 Content:
CO2 Content:
ANALYTICAL DATA
hlorophenyl-phenylether
Nitroaniline
,6-0initro-2-m~thylphenol
N-Nitrosodiphenylamine
Bromophenyl-phenylether
Hexachlorobenzene
Pentachlorophenol
Phenanthrene
nthracene
Oi-n-butylphthalate
Fluoranthene
Pyrene
Buty1benzylphthalate
,3'-0ichlorobenzidine
bis(2-Ethylhexyl)phthalate
Benzo(a)anthracene
hrysene
0I-n-octylphthalate
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
tndeno(1,2,3-cd)pyrene
Oibenz(a,h)anthracene
Benzo(g, h, i)pery1ene
NOTES:
< Undetected
(B) Present in laboratory blank
SO-M23-R2
192.086 dscf
196 dscfm
18.5 %
1.6 °.4
<
<
<
<
<
BJ
<
<
<
<
<
<
<
<
<
<
BJ
<
<
<
<
J
<
<
<
<
<
<
<
<
<
6.34
2.09
13.92
9.56
1.24
2.12 BJ
3.03
1.67
6.34
9.41
2.99
5.59
4.61
7.58
1.29
1.36
21.42 BJ
1.29
1.22
2.67
4.18
14.90 J
1.45
1.50
1.45
1.77
1.80
1.87
1.85
2.42
2.14
(J) Detected but below the quantitation limit; quantity is estimated
(E) Detected but above calibration range; quantity estimated
0.00
0.00
0.00
0.00
0.00
6.46
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
7.39
0.00
0.00
0.00
0.00
2.37
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
(SAT) Saturated; amount reported should be considered underestimated
4 <
4 <
4 <
4 <
4 <
4
4 <
4 <
4 <
4 <
4 <
4 <
4 <
4 <
4 <
4 <
4 BJ
4 <
4 <
4 <
4 <
4 J
4 <
4 <
4 '<
4 <
4 <
4 <
4 <
4 <
4 <
Page 2 of 2
if F svoc eM,~~
CRi>.TE':•,•:•,··
I F lb/iii ''
25.36 < 2.04E-06 < 3.43E-06
8.36 < 6.72E-07 < 1.13E-Q6
55.68 < 4.47E-Q6 < 7.53E-Q6
38.24 < 3.07E-Q6 < 5.17E-Q6
4.96 < 3.98E-07 < 6.71E-07
0.00 O.OOE+OO O.OOE+OO
12.12 < 9.74E-07 < 1.64E-Q6
6.68 < 5.37E-07 < 9.03E-07
25.36 < 2.04E-Q6 < 3.43E-Q6
37.64 < 3.02E-06 < 5.09E-Q6
11.96 < 9.61E-07 < 1.62E-OS
22.36 < 1.80E-Q6 < 3.02E-06
18.44 < 1.48E-06 < 2.49E-Q6
30.32 < 2.44E-Q6 < 4.10E-06
5.16 < 4.15E-07 < 6.98E-07
5.44 < 4.37E-07 < 7.35E-07
56.12 BJ 4.51E-Q6 BJ 7.59E-06
5.16 < 4.15E-07 < 6.98E-07
4.88 < 3.92E-07 < 6.60E-07
10.68 < 8.58E-07 < 1.44E-Q6
16.72 < 1.34E-06 < 2.26E-06
50.12 J 4.03E-06 J 6.78E-Q6
5.80 < 4.66E-07 < 7.64E-07
6.00 < 4.82E-07 < 8.11E-07
5.80 < 4.66E-07 < 7.64E-07
7.08 < 5.69E-07 < 9.57E-07
7.20 < 5.78E-07 < 9.73E-07
7.48 < 6.01 E-07 < 1.01E-06
7.40 < 5.95E-07 < 1.00E-Q6
9.68 < 7.78E-07 < 1.31E-06
8.56 < 6.88E-07 < 1.16E-06
-• If BLANK(ug/Kg) Not Detected, then CORRECTEO(ug) = SAMPLE (ug); if BLANK(ug) , SAMPLE (ug), then CORRECTEO(ug) = 0.00
6
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
TABLE 4
SUMMARY OF PCB RESULTS '
McLAREN HART
RUN 1.D.
CORR. SAMPLE VOLUME:
CORR. GAS FLOWRA TE:
O2CONTENT:
PCB's
TOTAL MonoCB
TOTALDiCB
TOTAL TriCB
TOTAL TetraCB
TOT AL PentaCB
TOTAL HexaCB
TOT AL HeptaCB
TOTAL OctaCB
TOTAL NonaCB
DecaCB
TOTAL PCB
TOTAL PCB+ EMPC
STACK OUTLET
<
<
<
<
<
<
S0-M23-R2
196.215 dscf
196 dscfm
18.5 %
CONCENTRATION
(µg/Nm3
(µq/Nm3l @7% 02)
0.0031 <
0.2627
0.0232
0.0070 <
0.2859
0.0155 <
0.0155 <
0.0232 <
0.0309 <
0.0000
0.1236
0.5408
7
0.0179 <
1.5214
0.1342
0.0403 <
1.6556
0.0895 <
0.0895 <
0.1342 <
0.1790 <
0.0000
0.7159
3.1322
MASS
RATE
(lb/hr)
2.12E-09
1.80E-07
1.59E-08
4.76E-09
1.96E-07
1.06E-08
1.06E-08
1.59E-08
2.12E-08
0.00E+00
8.47E-08
3.71E-07
TABLE 5
SUMMARY OF PESTICIDES RESULTS
McLAREN HART
STACK OUTLET
RUN I.D. SO-M23-R2
CORR. SAMPLE VOLUME: 192.086 dscf
CORR. GAS FLOWRA TE: 196 dscfm
02CONTENT: 18.5 %
CONCENTRATION
(µg/Nm3
(~g/Nm3) @7% 02)
PESTICIDES.
alpha-BHC < 0.0158 < 0.0914
a-Chlordane < 0.0158 < 0.0914
Aldrin 0.0825 0.4776
beta-BHC < 0.0158 < 0.0914
delta-BHC < 0.0158 < 0.0914
4,4'-DDD 2.2689 13.1410
4,4'-DDE 2.3123 13.3924
4,4'-DDT < 0.0316 < 0.1828
Dieldrin 0.0386 0.2235
Endrin < 0.0316 < 0.1828
Endrin Aldehyde < 0.0316 < 0.1828
Endosulfan I < 0.0158 < 0.0914
Endosulfan II < 0.0316 < 0.1828
Endosulfan sulfate < 0.0316 < 0.1828
gamma-BHC (Lindane) < 0.0158 < 0.0914
g-Chlordane 0.0995 0.5764
Heptachlor 0.0163 0.0946
Heptachlor epoxide < 0.0158 < 0.0914
Methoxychlor < 0.1578 < 0.9142
Toxaphene < 1.5784 < 9.1415
8
<
<
<
<
<
<
<
<
<
<
<
<
<
<
MASS
RATE
(lb/hr)
1.08E-08
1.08E-08
5.65E-08
1.08E-08
1.08E-08
1.55E-06
1.58E-06
2.16E-08
2.64E-08
2.16E-08
2.16E-08
1.08E-08
2.16E-08
2.16E-08
1.08E-08
6.82E-08
1.12E-08
1.08E-08
1.08E-07
1.08E-06
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I TABLE 6
SUMMARY OF VOLATILE ORGANIC COMPOUND EMISSIONS
I McLAREN HART
STACK OUTLET
SAMPLING DATA:
I Run Number. M/H-M0030-R2
Corr. Sample Volume: 0.7458 dscf
Corr. Flatmrte; 150 dscfm (1)
ANALYTICAL DATA:
I Sample I.D.: 94-365--303/305
Blank I.D. 94-365-309/311
I
hloromethane 50.49 E 46.203 J 0.014 E 46.189 E 1.04E+O0 E 2.19E-+03 E 1.23E-03
I lnyl Chloride 62.50 < 0.003 0.000 < 0.003 < 5.47E-05 < 1.42E--01 < 7.98E-08
romomethane 94.95 B 0.768 BJ 0.015 B 0.753 8 9.03E-03 B 3.57E+01 B 2.00E-05
hloroethane 64.51 < 0.003 0.000 < 0.003 < 5.30E-05 < 1.42E-01 < 7.98E-08
I richlorofluoromethane 137.38 J 0.010 0.000 J 0.010 J 8.29E-05 J 4.73E-01 J 2.66E-07
1, 1-Dichloroethene 96.95 < 0.002 0.000 < 0.002 < 2.JSE-05 < 9.47E-02 -< 5.32E-08
rbon disutflde 76.14 J 0,010 J 0.004 J 0.006 J 8.9BE--05 J 2.84E--01 J 1.BOE--07
cetone 58.08 0.615 0.398 0.217 4.26E--03 1.03E-+01 5.77E--06
I Methylene chloride 84.94 0.317 0.433 0.000 0.00E+O0 0.00E+O0 0.OOE+OO
ran&-1,2•Dichloroethene 96.95 < 0.002 0.000 < 0.002 < 2.35E-05 < 9.47E-02 < 5.32E-08
1, 1 •Dichloroethane 98.97 < 0.001 0.000 < 0.001 < 1.15E-05 < 4.73E-02 < 2.66E-08
is-1,2-0ichloroethene 96.95 < 0.001 0.000 < 0.001 < 1.17E-05 < 4.73E-02 < 2.66E-08 I hloroform 119.39 J 0.004 J 0.004 0.000 0.00E+O0 0.00E+O0 0.00E+OO
1,2•Dichloroethane 98.96 < 0.001 0.000 < 0.001 < 1.15E-05 < 4.73E-02 < 2.66E-08
inyl Acetate 86.09 < 0.001 0.000 < 0.001 < 1.32E-05 < 4.73E-02 < 2.66E-08
I •Butanone 72.10 < 0.014 0.000 < 0.014 < 2.21E-04 < 6.63E-01 < 3.72E-07
1, 1, 1-Trichloroethane 133.42 < 0.001 0.000 < 0.001 < 8.54E-06 < 4.73E-02 < 2.66E-08
rbon tetrachloride 153.84 < 0.001 0.000 < 0.001 < 7.40E-06 < 4.73E-02 < 2.66E-08
nzene 78.11 0.089 J 0.042 0.047 6.85E-04 2.23E+O0 1.25E-06
I richloroethene 131.40 < 0.001 0.000 < 0.001 < 8.67E-06 < 4.73E-02 < 2.66E-08
1,2-Dichloropropane 112.99 < 0.001 0.000 < 0.001 < 1.01 E-05 < 4.73E-02 < 2.66E-08
BromOdichloromethane 163.83 < 0.001 0.000 < 0.001 < 6.95E-06 < 4.73E-02 < 2.66E-08
I is-1,3-Dichloropropene 110.98 < 0.001 0.000 < 0.001 < 1.03E-05 < 4.73E-02 < 2.66E-08
rans-1 , 3-0ichloropropene 110.98 < 0.001 0.000 < 0.001 < 1.03E-05 < 4.73E-02 < 2.66E-08
1, 1,2-Trichloroethane 133.42 < 0.002 0.000 < 0.002 < 1.71E-05 < 9.47E-02 < 5.32E-08
Dibromochloromethane 208.28 < 0.001 0.000 < 0.001 < 5.47E-06 < 4.73E--02 < 2.66E--08
I Bromoform 252.77 < 0.003 0.000 < 0.003 < 1.35E-05 < 1.42E-01 < 7.98E-08
Methyl-2-pentanone 100.16 < 0.002 0.000 < 0.002 < 2.27E-05 < 9.47E-02 < 5.32E-08
otuene 92.13 J 0.040 J 0.026 J 0.014 J 1.73E-04 J 6.63E-01 J 3.72E-07
etrachloroethene 165.85 < 0.002 0.000 < 0.002 < 1.37E-05 < 9.47E-02 . < 5.32E-08
I -Hexanone 100.16 < 0.003 0.000 < 0.003 < 3.41E-05 < 1.42E-01 < 7.98E-08
lorobenzene 112.56 < 0.001 0.000 < 0.001 < 1.01E-05 < 4.73E-02 < 2.66E-08
106.16 J 0.003 0.000 J 0.003 J 3.22E-05 J 1.42E-01 J 7.98E-08
I 106.16 J 0.017 J 0.010 J 0.007 J 7.51 E-05 J 3.31 E--01 J 1.86E-07
106.16 J 0.006 0.000 J 0.006 J 6.44E-05 J 2.84E-01 J 1.60E-07
104.14 J 0.009 J 0.006 J 0.003 J 3.28E-05 J 1.42E-01 J 7.98E-08
1122-Tetrachloroethane 167.86 < 0.001 0.000 < 0.001 < 6.79E-06 < 4.73E-02 < 2.66E-08
I NOTES:
(1) FIO'-Nrate taken from Method 23 testing performed on the L TTOS Stack.
< Undetected
I (B) Present in laboratory blank
(J) Detected but below the quantitation limit; quantity is estimated
(E) Detected but above calibration range; quantity estimated
-If BLANK(ug/Kg) Not Detected, then CORRECTED(ug) = SAMPLE (ug); if BLANK(ug) > SAMPLE (ug), then CORRECTED(ug) = 0.00
I 9
3.0 SAMPLING .AND ANALYTICAL PROCEDURES
All sampling and analytical procedures followed those
recommended by the USEPA procedures of Title 40 of the Code of
Federal Regulations, Part 60 (40 CFR 60), Appendix A, or other
methods generally accepted by the EPA. The following specific
methods were performed:
EPA Method lA for determination of sampling and traverse points;
EPA Method 2 for flue gas velocity and volumetric flow rate;
EPA Method 3 for flue gas composition and molecular weight (sampling procedure);
EPA Method 3A for flue gas composition and molecular weight (analytical procedure);
EPA Method 4 for flue gas moisture content;
EPA Method 0030 for determination of VOST compound emissions from EPA SW-846 Methods for;
EPA Method 0050 for determination of total particulate and HCl emissions from 40 CFR 266, Appendix IX;
EPA Method 23 for determination of PCDDs/PCDFs, PCB, and Semi-VOST compound emissions.
3.1 Sampling Procedures
3 .1.1 Sampling Point Determination -EPA Method 1: · A total of
eight sampling and traverse points (four for each of two ports)
for gas flow rate measurements were utilized at the stack outlet.
Figure 1 shows the location.of the points. However, pollutant
sampling was conducted at a single point of average velocity in
accordance with Section 2.1 . .2 of EPA Method lA. This point was
10
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
4
3
2 4
2
DISTANCE FROM
POINT % ID INSIDE OF PORT
(inches)
1 6.7 0.50
2 25.0 1.50
3 75.0 4.50
4 93.3 5.50
I INSIDE STACK DIAMETER 6.0 ,n 0.5 ft
Figure 1 -Schematic of Traverse Points
11
determined from a traverse of the stack that was performed before
sampling began.
3.1.2 Volumetric Measurements -EPA Method 2: EPA Reference
Method 2 was used to determine the velocity and volumetric flow
rates of the stack outlet gases. Stainless steel Type-S pitot
tubes were used to measure the gas velocity heads. The pitot
tubes were calibrated against a NBS traceable pitot tube in
accordance with Method 2. Calibrated Type-K thermocouples were
used to determine gas temperatures. Preliminary velocity and
temperature measurements were made at each of the eight points
traversing the stack as shown in Figure 1. A point representing
the average velocity and temperature of the stack was selected
for sampling purposes.
3.1.3 Molecular Weight Determination -EPA Method 3: Gas
compositional measurements (02 and CO2) for determining the
average molecular weight of the stack gases were done in
accordance with EPA Reference Method 3. Integrated sampling was
used to obtain a constant rate sample of flue gas concurrent with
the pollutant t.esting. Sampling was of the same duration (except
purges following port changes) as the pollutant runs.
A stainless steel probe was affixed to the pollutant
sampling probe for this purpose. A peristaltic•pump, delivering
500 to 700 milliliters per minute (ml/min) of flue gas, was used
12
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
to fill a Tedlar bag. Figure 2 shows a schematic of the Method 3
sampling train.
3.1.4 Flue Gas Moisture Content -EPA Method 4: The flue gas
moisture was measured in conjunction with each of the test runs
according to the sampling and analytical procedures outlined in
EPA Method 4. The flue gas moisture for each test was determined
by gravimetric analyses of the water collected in the impinger
condensers of the pollutant sampling train. All impingers were
contained in an ice bath throughout the testing in order to
assure complete condensation of the moisture in the flue gas
stream. Any moisture which was not condensed in the impingers
was captured in the silica gel contained in the final impinger.
3.1.5 Particulate and HCl Sampling -EPA Method 0050: Sampling
for HCl and particulate was performed in accordance with the
procedures of EPA Method 0050.
3.1.5.1 Sampling Train Description: Figure 3 shows the major
components of the Method 0050 sampling train. A stainless steel
probe with a heated borosilicate glass.liner was used to withdraw
the gas sample. The probe was equipped with an appropriately
sized glass nozzle connected .. directly to the liner for isokinetic
gas withdrawal.
13
I
I
Stainless Steel Probe
Flo•m•I" i
Fine Adjust •
Valve •
I
I
rF c:::::::::::::::~ □
lsokinetic Sampling Probe
'O
Teflon Somple Line I Vacuum Pump
I
Quick Connect
Check Valve I
I
Fle>dble Bog
I
I Riaid Container I
Figure 2 -EPA Method 3 Sampling Train I
I
D
I
I
-.. -I
I
14 I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
BoroslUcote Glo:is Nozzle
Heated Stoinles:, Steel Probe
The~ocouple
Pilot
Tubes
(Type-S)
Inclined
Manometer
71
Inclined
Manometer
Thermometers
/ '
Ory Gos
Meter
Heated
Filter
Thermom11ter
50 ml 100 ml
0.1 N 0.1 N
H2 SO 4 H2 SO 4
100 ml
0.1 N
NoOH
By-Poss
Valve
Van13,
Puma
'" Both
G,I
Vocuum
Gouge
:fl
Coarse
Valve
Figure 3 -EPA Method 0050 Sampling Train
15
Vacuum
Line
From the nozzle and probe, sample gas was pulled through a
heated glass fiber filter for capture of particulate matter. The
filter and filter housing were maintained at 248°F ± 25°F to
prevent water condensation. Sample gas was subsequently passed
through an impinger tr_ain consisting of six glass impingers
immersed in an ice bath. The first impinger contained 50
milliliters of 0.1 normal H2S04 • The second and third impingers
each contained 100 milliliters of 0.1 normal H2so4 for
solubilization of HCl. The fourth and fifth impingers each
contained 100 milliliters of 0.1 normal NaOH for absorption of
chlorine gas. The sixth impinger initially contained
approximately 200 grams of silica gel.
3.1.5.2 Sampling Train Operation: Sampling was conducted in
accordance with EPA Method 0050 procedures and specifications,
including leak checking and isokinetic sampling. Sampling was
conducted at a single point which represented the average
velocity and temperature of the stack for the time required for a
complete desorption cycle to occur.
3.1.5.3 Sample Recovery and Clean-Up: Recovery of the Method
0050 sampling probe was accomplished using a teflon-fiber probe
brush. The probe and front half glassware were rinsed with
acetone three times each and brushed between rinses. These
rinses were recovered for particulate analysis.--Exposed filters
were placed back into their o;iginai tared containers. The
16
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
impinger contents were first quantified to determine the stack
gas moisture content in accordance with EPA Method 4, then
recovered for HCl analysis. The first three impingers were
rinsed with deionized distilled water, and the rinses combined
with the impinger catch. The contents of the fourth and fifth
impingers were transferred to a separate container. The silica
gel from the sixth impinger was transferred back to its original
Nalgene container.
3.1.5.4 Field Blanks: One field blank was collected during the
test program for EPA Method 0050 test. The field blank consisted
of a complete set of regents taken for the regent stock used for
testing.
3.1.6 Semivolatile Sampling -EPA Method 23: PCDDs/PCDFs, PCBs,
pesticides, and semivolatiles were determined in general
accordance with EPA Reference Method 23 of 40 CFR, Part 60,
Appendix. A.
3.1.6.1 Sampling Train Description: Figure 4 illustrates the
EPA Method 23 sampling train. The train employed a single piece
quartz nozzle and probe for sample withdrawal. The nozzle
opening was appropriately sized to maintain isokinetic sampling.
Particulate matter was removed from the gas stream by means of a
heated glass filter supported on a Teflon frit. The filter
temperature was maintained at 248 ± 25°F.
17.
Heated Filter
Quartz
Nou!e <-Heated Quartz Probe r '""~"•'•
Pilot
Tubes
(Type-S)
Inclined
Manometer
Blank
Thermometers
/ '
E~houst
Inclined
Manometer
Dry Cos
Meter
Condenser
/
Coolant
Water
Water
XAO Sorbent Trap
Blank Silica
Gol
By-Poss
Vol..,e •
0
Vane
Puma
Vacuum
Govge ,,,
Coarse
Valve
Figure 4 EPA Method 23 Sampling Train
18
Vacuum
line
I
I
I
I
I
D
I
I
I
I
I
I
I
I
I
I
I
I
I
I
:I
I
I
I
I
••
I
I
I
I
I
I
I
I
I
I
I
I
After particulate removal; the gases passed into a water-
cooled glass condenser and entered an XAD resin sorbent trap.
The sorbent trap was packed with pre-cleaned, quality control
checked amberlite XAD-2 resin. Coolant water maintained at
wet-ice temperature was continuously recirculated into the
assembly using a submersible water pump. The condenser cooled
the sample gases and condensed part of the moisture. The cooled
gases and condensate flowed down through the XAD-2 resin which
retained the organics .
After passing through the sorbent trap, the sample gases
entered a chilled impinger train to remove the remaining
moisture. The impinger train consisted of five glass impingers
packed in ice water. The first impinger was left blank to
facilitate collection of the condensate which passed through the
XAD-2 sorbent trap. The second and third impingers each con-
tained 100 milliliters of distilled water. The fourth impinger
was left blank, and the fifth impinger contained approximately
300 grams of silica gel.
All components from the nozzle to the fourth impinger were
made of glass. All connections from the probe to the exit stem
of the fourth impinger were sealed with Teflon o-rings. Sealing
grease was not used on any connections before the fifth impinger.
19
3.1.6.2 Sampling Train Preparation: Alf glass and Teflon
components of the Method 23 sampling train were precleaned before
use. The following cleaning procedures were used:
1) Washed with hot water and detergent.
2) Rinsed with tap water three times.
3) Rinsed with deionized, distilled water three times.
4) Rinsed with pesticide grade hexane three times.
5) Rinsed with pesticide grade toluene three times.
6) Rinsed with pesticide grade acetone three times.
7) Baked at 400°F for three hours.
8) Capped glassware with hexane-rinsed aluminum foil,
wrapped externally with Teflon tape.
The sorbent traps were pre-cleaned according to the above
methodology, and packed with 20 to 30 grams of quality control
checked XAD-2 resin by Triangle Laboratories (Research Triangle
Park, NC). The laboratory also spiked the traps with a known
amount of labelled organic compounds in order to facilitate
determination of retention and recovery efficiency of the XAD-2
resin. The packed traps were maintained at or below room
temperature to prevent resin decomposition. one trap was
retained at the laboratory as a method blank.
3.1.6.3 sampling-Train Operation: Sampling was conducted in
accordance with EPA Method 5 procedures and specifications,
20
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
including leak checking and isokinetic sampling. Sampling was
conducted at a single point which represented the average
velocity and temperature of the stack for the time required for a
complete desorption cycle to occur. Pressure and temperature
measurements and isokinetic sampling rate adjustments were made
at ten-minute intervals. A minimum sample volume of 106 dry
standard cubic feet was obtained for each test run.
3.1.6.4 Sample Recovery and Clean-up: At the completion of each
test, the probe was removed from the train, and the ends of the
sampling train capped with hexane-rinsed aluminum foil. The
probe was recovered immediately on the sampling platform, while
the remainder of the sampling train was transported to a clean-up
site for recovery. Sample recovery proceeded as follows:
1) Front-half Rinse: The probe, front half of the filter
holder, and all connecting lines between the probe and
filter holder were rinsed three times with pesticide grade
acetone followed by three rinses with pesticide grade
methylene chloride and finally three rinses with pesticide
grade toluene. A teflon-fiber probe brush was used to brush
the probe between rinses. All rinses were collected into
pre-cleaned amber glass bottles fitted with Teflon lined
screw caps. The acetone and methylene chloride rinses were
collected together into one bottle, while the toluene rinse
was collected into a separate bottle.
21
2)
3)
4)
5)
6)
Particulate Catch: The filter was removed from the housing
with Teflon tweezers and placed into a pre-cleaned glass
petri dish. The dish was sealed externally with Teflon
wrapping tape.
Back-half Rinse: The back half of the filter holder and all
connecting lines from the filter to the sorbent tube were
rinsed and treated as in (1) above.
Sorbent Cartridge: The sorbent trap assembly was capped
with hexane-rinsed aluminum foil and sealed externally with
Teflon tape.
Impinger 1 Recovery: The condensate collected in the first
impinger was transferred to a graduated cylinder and the
volume recorded. The liquid was then transferred to a
pre-cleaned amber glass bottle fitted with a Teflon lined
screw cap. The impinger was rinsed three times with
pesticide grade toluene. The rinses were collected into a
separate bottle.
Impingers 2-4 Recovery: The liquid volumes in impingers two
through four were recorded for the Method 4 moisture
determination. The liquids were then discarded.
22
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
.I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
7) Silica Gel: The silica gel in the fifth impinger was
transferred into its original plastic container and sealed.
3.1.6.5 Sample Storage and Transport: Immediately upon re-
covery, all samples including liquid rinses, filters and sorbent
traps were placed into insulated coolers packed with ice, thus
protecting the samples from light and heat.
The samples remained inside the coolers during transport to
the analytical laboratory. While in the custody of ETS, the
temperatures inside the coolers were periodically measured to
insure that the samples did not exceed 32°F. All samples were
express mailed directly to the analytical lab for analysis.
While at the lab, the samples were kept in a refrigerated
compartment until analyzed.
3.1.6.6 Field Blanks: One field blank was collected during the
test program for the Method 23 tests. The field blank consisted
of a complete set of regents taken from the regent stock used for
testing.
3.1.7 Volatile Organics Sampling -EPA Method 0030: Sampling
for volatile organics was conducted in accordance with EPA Method
0030.
23
3.1.7.1 sampling Train Description: Figure 5 illustrates the
EPA Method 0030 volatile organic sampling train (VOST). The
primary components of the VOST system were the probe, condenser,
condensate trap, a second condenser, and a backup resin trap.
The first cartridge was packed with approximately 1.6 grams of
Tenax-GC resin. The second cartridge was packed with Tenax-GC
resin and petroleum-based charcoal (one gram of each,
approximately 3:1 by volume), with the charcoal on the outlet end
of the cartridge. The first trap retained most of the higher
boiling analytes. Lower boiling analytes and the portion of the
higher boiling analytes that broke through the first cartridge
were retained on the second trap. Analytes that collected in the
• I condensate trap were purged into the second trap and condenser
units. The metering system consisted of vacuum gauges, a leak-
free pump, a calibrated rotameter, and a dry gas meter.
3.1.7.2 Sampling Train Preparation: Components of the Method
0030 sampling train were prepared as follows:
(1) All a-rings used were thermally conditioned in a vacuum
oven at 200°c for 48 hours and stored in clean, screw-
capped glass containers prior to use.
(2) The glass resin tubes and condensers were cleaned with
a non-ionic detergent in an ultrasonic bath, rinsed
well with deionized, distilled water, and dried at
110°c.
24
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Heoted Quartz. Probe
Thermomete~
Exhaust
/ '
Dry Gos
Meter
By-Poss
Valve
Vane
Puma
Gloss
Condenaens
Coolont
Water
'"
Teno)( Trop
VCJcuum
Gouge
Coarse
Valve
Ttiflon Lines
I ""...--.....
Conden,ote
Trop
Cooh:inl
Water
o,t
Silica
0,1
Figures -Volatile organic Sampling Train (EPA Method 0030)
25
(3) The metal parts were cleaned with a non-ionic detergent
in an ultrasonic bath, rinsed well with deionized,
'distilled water, air dried, and heated in a muffle
furnace for two hours at 400°C.
3.1.7.3 Sample Train Operation: Sampling was performed in
accordance with EPA Method 0030 procedures, including leak
checking and sampling rate.
The train was leak checked by closing the valve at the inlet
to the first condenser and pulling a vacuum of 10 inches Hg above
the normal operating pressure. The traps and condensers were
isolated from the pump and the leak check noted. The leak rate
was less than o. 1 inches Hg per minute. After leak checking,·
sample collection was accomplished by opening the valve at the
inlet to the first condenser, turning on the pump, and sampling
at the rate of 0.75 liter per minute for 20 minutes (test run
one). At this point, the train was leaked checked at the highest
vacuum achieved during the sampling run, and the first pair of
sorbent cartridges were replaced with a new pair of cartridges.
Sampling was then restarted at the rate of 0.50 liters per minute
and this pair of cartridges ran for 40 minutes (test run 2).
Only the test run 2 cartridges were analyzed.
3.1.7.4 Sample Recovery and Clean-up: At the completion of each
sampling period, each pair of sorbent cartridges were removed
26
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I I
I
from the sampling train, the end caps were replaced on the
cartridges, and the cartridges were stored in a cooler with "Blue
Ice'' until analysis.
The samples remained inside the coolers during transport. to
the analytical laboratory. While in the custody of ETS, the
temperatures inside the coolers were periodically measured to
insure that the samples did not exceed 32°F. All samples were
express mailed directly to the analytical lab for analysis.
While at the lab, the samples were kept in a refrigerated
compartment until analyzed.
3.1.7.5 Field Blanks: One field blank was collected during the
test program for the Method 0030 tests. A single pair of sorbent
cartridges were taken to each sampling location and the ends
removed for a period of time while the two paris of sorbent
cartridges on the VOST system were exchanged. At the end of this
period, the end caps were replaced, and the cartridges were
stored and analyzed with the sample cartridges.
3.2 Analytical Procedures
3.2.1 Oxygen and Carbon Dioxide -EPA Method 3A: Oxygen and
carbon dioxide concentrations of the Method 3 gas samples were
measured instrumentally using continuous gas analyzers. A
Teledyne Model 320A Chemical Cell Portable o 2 Analyzer and a
HORIBA Model PIR-2000 NDIR CO2 Analyzer were used for the
27
analyses. Each instrument conformed.to the design specifications
of EPA Method 3A. Prior to each series of analyses, each
analyzer was zeroed, using zero nitrogen, and spanned, using a
certified calibration gas with a concentration of 80 to 90
percent of the instrument span. Following calibration a mid
range gas, 50 to 60 percent of the instrument span, was
introduced to each monitor. The mid range response error never
exceeded two percent of the instrument span. Data for the o2 and
CO2 analyses are included in Appendix L.
3.2.2 Moisture Content -EPA Method 4: Moisture contents were
determined gravimetrically in accordance with Method 4 by
measuring either the volume or mass gains of each impinger in the
pollutant sampling trains. Data for these measurements are
included in the respective analytical appendices for each
pollutant.
3.2.3 Particulate •Analyses -EPA Method 5: Particulate matter
was determined in accordance with EPA Method 5 procedures. The
filter was analyzed gravimetrically to a constant weight. The
front half acetone rinse was evaporated and analyzed
gravimetrically to a constant weight. The total particulate
catch equals the sum of the front half acetone rinse and the
filter. All gravimetric data concerning the analyses are
included in Appendix M.
28
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
3.2.4 HCl Analyses -EPA Method 0050: HCl analyses of the first
three impinger solutions from the Method 0050 sampling train were
performed by EPA Method 0050 using an chloride ion selective
electrode. Details of the analysis can be found in Appendix N.
3.2.5 PCDDs/PCDFs Analyses: · Analysis of the Method 23 sample
train components from test run 2 for PCDDs/PCDFs was performed in
accordance with the procedures outlined in EPA Reference Method
23 and Method 8280 of SW-846. The analyses were performed with
high resolution gas chromatography/mass spectrometry (GC/MS).
All front-half, back-half, and condensate extracts from the
analyses were combined for one GC/MS analysis for each run.
Appendix O contains a summary of the analytical report for the
analyses. More detailed information for the analyses, including
calibration data and sample chromatograms, are available upon
request.
3.2.6 Semivolatile Organics Analyses: Analysis of the Method 23
sample train components for semivolatile organics from test run 2
was performed in accordance with the procedures outlined in
Method 0010 of SW-846. Analyses were performed for the
semivolatile compounds listed in Method 8270, Table 2. The
analyses were performed with high resolution gas
chromatography/mass spectrometry (GC/MS). All front-half, back-
half, and condensate extracts from the analyses were combined for
one GC/MS analysis for each run. Appendix P contains a summary
29
of. the analytical report for the analyses. More detailed·
information for the analyses, including calibration data and
sample chromatograms, are available upon request.
3.2.7 PCBs Analyses: Analysis of the Method 23 sample train.
components for PCBs from test run 2 was performed in accordance
with the procedures outlined in Method 680. The analyses were
performed with high resolution gas chromatography/mass
spectrometry (GC/MS). All front-half, back-half, and condensate
extracts from the analyses were combined for one GC/MS analysis
for each run. Appendix Q contains a summary of the analytical
report for the analyses. More detailed information for the
analyses, including calibration data and sample chromatograms,
are available upon request.
3.2.8 ,Pesticides Analyses: Analysis of the Method 23 sample
train components for pesticides from test run 2 was performed in
accordance with the procedures outlined in SW-846 Methods 8000
and 8080. The analyses were performed with high resolution gas
chromatography/electron capture detection (GC/ECD). All front-
half, back-half, and condensate extracts from the analyses were
combined for one GC/ECD analysis for each run. Appendix R
contains a summary of the analytical report for the analyses.
More detailed information for the analyses, including calibration
data and sample chromatograms, are available upon request.
30
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
3.2.9 Volatile Organics Analyses: The VOST sorbent cartridges
from test run 2 were analyzed for the volatile organic compounds
listed in Appendix G. The analyses were performed using thermal
desorption and gas chromatography with mass spectrometry (GC/MS)
in accordance with Method 0030 procedures. Prior to analysis by
GC/MS, the pairs of sorbent cartridges were spiked with an
internal standard and thermally desorbed for 10 minutes at 180°C
with organic-free nitrogen.gas (at a flow rate of 100 ml/min),
bubbled through 5 ml of organic-free water, and trapped on an
analytical sorbent trap. Appendix S contains a summary of the
analytical report for the analyses. More detailed information
for the analyses, including calibration data and sample
chromatograms, are available upon request.
3.3 Data Analysis
All calculations related to the Method 1 through 5 type
sampling, including gas flow rates, temperatures, percent
isokinetics, moisture contents, and pollutant emissions, are
shown in Appendix H. Particulate emissions are expressed as
gr/dscf, gr/dscf corrected to 7% o2, gr/dscf corrected to 12%
co2 , gr/dscf corrected to 50% EA, and pounds per hour (lb/hr).
An acetone blank correction was applied to the calculation of
total particulate emissions.
PCDDs/PCDFs are expressed as ng/Nm3 (32°F, 1 Atm.), ng/Nm3
corrected to 7% o2, and lb/hr. EPA Toxic Equivalency Factors
31
were used to obtain 2378-TCDD Toxic Equivalent emissions for
total PCDDs/PCDFs. These factors were derived from EPA document
EPA/625/3-87/012, March, 1987 entitled "Interim Procedures for
Estimating Risks Associated to Exposure to Mixtures of
Chlorinated Dibenzo-p-Dioxins and Dibenzofurans".
Semivolatiles are expressed as gr/dscf and lb/hr and
volatiles are expressed in ppmdv, µg/dscm, and lb/hr. PCBs and
pesticides are expressed as µg/Nm3 (32°F, 1 Atm.), µg/Nm3
corrected to 7% 0 2 , and lb/hr.
3.4 Equipment Calibration
Field equipment was calibrated in accordance with the
requirements of the applicable EPA Methods and those recommended
within the "Quality Assurance Handbook for Air Pollution
Measurement Systems: Volume III" (EPA-600/4-77-027b, August,
1977). Appendix T contains records for all of the calibrations.
32
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
APPENDIX A
I TEST LOG
I
I ·.,
\ . ',,
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
RUN I.D.
MH-M0030-R1 *
MH-M0030-R2
SO-M0050-R 1
SO-M23-R1*
SO-M23-R2
SO-M23-R2
SO-M23-R2
SO-M23-R2
,I TESTLOG ,·
McLAREN HARli
STACK OUTLET:'
POLLUTANT DATE
VOLATILES 12/15/94
VOLATILES 12/15/,94
TSP/HCL 03/17/95
DIOXINS/FURANS 03/16/95 ' DIOXINS/FU RANS 03/17/95
SEMIVOLA TILES 03/17/95
!'
PCB's 03/17/95
PESTICIDES 03/17/95
*Mclaren Hart decided not to have this run analyzed.
START END
TIME TIME
14:34 14:54
15:06 15:46
14:22 17:27
08:44 16:50
09:02 13:00
09:02 13:00
09:02 13:00
09:02 13:00
I
I
I
I
I
I
I
I
I
I ,.
I
I
1·
I
I
I
I
I
APPENDIX B
DATA AND RESULTS FOR
PARTICULATE AND HCl TESTING (METµoD 0050)
I
I RUN NUMBER SO-M0050-R1
Date 03/17/95
I Start Time 14:22
End Time 17:27 METHOD 4 DATA
Stack Diam. 6 inches INIT. FINAL NET
Nozzle I.D. 0.390 inches !!!!D. !!!!D. !!!!D. I Meter Box Gamma 1.0046 IMP.1 100.0 140.0 40.0
Meter Box dH@ 1.7002 IMP.2 100.0 160.0 60.0
Barometric 29.88 in.Hg IMP.3 100.0 112.0 12.0
I Cp 1.00 IMP.4 100.0 96.0 -4.0
Test Duration 185 minutes IMP.5 a.a
IMP.6 a.a
I IMP.7 a.a
METHOD 1-4 RESULTS TOTAL 400.0 508.0 108.0
Metered Volume 217.750 def S.G. 200.0 226.0 26.0
Volume @ Std.Cond. 212.217 dscf
I % Water 2.89 % METHOD 3 DATA
% lsokinetics 98.4 % %02 18.6 Md 29.00
Velocity 24. 99 ft/sec %CO2 1.6 Ms 28.68
I Actual Flow 294 acfm %CO a.a Ps 29.88
Std. Flow 284 scfm %N2 79.8 Fo 1.437
Dry Std. Flow 276 dscfm O2+CO2 20.2 %EA 754
II STACK METER METER TEMPERATURE
TEMP STATIC DP DH VOLUME' INLET OUTLET
POINT (DegF) (in.WC) (in.WC) (in.WC) (de!) (DegF) (DegF)
I 1 84 -0.01 0.040 1.29 476.455 · 83 83
2 86 -0.01 0.075 2.40 694.205 ' 85 85
3 87 0.073 2.35 90 86
I 4 85 0.073 2.35 89 86
5 85 0.120 3.80 91 86
6 85 0.120 3.80 92 87
I 7 86 0.140 4.50 96 88
8 87 0.140 4.50 96 89
9 86 0.160 5.00 95 89
10 88 0.160 5.00 96 89 ,, 11 88 0.150 4.80 97 90
12 88 0.150 4.80 94 88
13 86 0.160 5.00 92 87
I 14 87 0.160 5.00 93 87
15 85 0.200 6.80 93 86
16 85 0.200 6.80 92 85
17 85 0.200 6.80 92 85 I 18 84 0.230 6.90 92 84
19 84 0.095 3.05 91 84
694.205
I AVG. 86 -0.01 0.139 4.47 217.750 89
I
I
I
I·
McLaren Hart
STACK OUTLET
EPA METHOD 5 ANALYTICAL DATA AND RESULTS
SAMPLING DATA:
Run Number:
Corr. Sample Volume:
Corr. Flowrate
02 Content:
CO2 Content:
ANALYTICAL DATA:
COMPONENT
SAMPLE
1.0.
Probe Wash
Corr. for Blank
94-365-201
Filter 94-365-200
Back Half
TOTAL
ACETONE BLANK
Actual Residue
Applicable Blank Corr.
Max Allowable Residue
Blank used
Volume
PARTICULATE EMISSIONS
Actual Grain Loading
Corrected to 7% 02
Corrected to 12% CO2
Corrected to 50% Excess Air .
Mass Rate
SO-M0050-R1
212.217 dscf
276 dscfm
18.6 %
1.6 %
TARE FINAL NET VOLUME
(grams) (grams) (grams)
67.52580 67.52770 . 0.00190
0.38670
0.00000
0.00130 grams
0.00137 grams
0.00082 grams
0.00082 grams
100.0 ml
0.00108
0.39270 0.00600
0.00000. . 0.00000
0.00708
0.00051 gr/dscf
0.00311 gr/dscf@ 7% 02
0.00386 gr/dscf@ 12% CO2
0.00293 gr/dscf@ 50% EA
0.0012 lb/hr
.<mD.
105.0
I
I
I
I
I
I
I
-I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
HCI SAMPLING DATA AND RESULTS
McLaren Hart
Stack Outlet
RUN NUMBER
DATE
START TIME
END TIME
SAMPLING DATA
Initial.Meter Volume - I
Final Meter Volume.-I
Net Meter Volume - I
Average Meter Temp. - F
Barometric Pres. -in.Hg
Avg. Meter Pres. -in.W.C.
Meter Cal. Factor -Gamma
Corr. Meter Volume -dscf
Dry Std. Flow -dscfm
Oxygen-%dv
LABORATORY DATA
Sample Cl Concentration -mg/I
Blank Cl Concentration -mg/I
Corrected Concentration -mg/I
Sample Volume -ml
Chloride Ion in Sample -mg
HCI in Sample -mg
HCI EMISSIONS
Concentration -ppmdv
Cone. -ppmdv @ 7% 02
Mass Rate -lbs/hr
SO-M0050-R1
03/17/95
14:22
17:27
<
<
<
<
<
<
I 476.455
694.205
217.750
89.0
29.88
4.47
1.0046
7.498
276
18.60
1.27
1.46
1.18 •
506
0.60
0.61
1.91
11.53
2.99E-03
(*) HCI emmisions are calculated using a detection limit of
0.1 ppm, the lowest standard concentration, which gives a
minimum detection limit of 1.18 mg/ml. This detection
limit was used because the Cl concentration detected in
the blank was higher than the Cl concentration detected
in the sample.
i• -
I
I
I
'·
I I
I
I
I
I
APPENDIX C
11 DATA AND RESULTS FOR
DIOXINS/FURANS TESTING (EPA METHOD 23)
I
I
I
I
I
I
I
I I
I
I
I.
I
·1 RUN NUMBER SO-M23-R1
Date o:3116195
Start Time 08:44
End Time 16:50 METHOD 4 DATA
I Stack Clam. 6 inches INIT. FINAL NET
Nozztel.O. 0.390 inches !m!l !m!l !m!l
Meter Box Gamma 1.0046 IMP.1 0.0 80.0 80.0
Meter Box dH@ 1.7002 IMP.2 100.0 84,0 -18.0
Barometric 30.18 in.Hg IMP.3 100.0 114.0 14.0 I Cp 1.00 IMP.4 0.0 ~-0 8.0
Test Duration 486.0 minutes IMP.5 0.0
IMP.8 0,0
IMP.7 0.0
I METHOD 1-4 RESULTS TOTAL 200.0 286.0 86.0
Metered Volume 475.802 def S.G. 300.0 342.0 42.0
Volume@ Std.Cond. 462.559 dscf
%Water 1.29 % METHOD 3 DATA ' '6 lsoklnetlcs 116.5 % %02 18.8 Md 28.93
I Velocrty 16.84 ft/sec %CO2 1 .10 Ms 28.79
Actual Flow 198 acfm %CO 0.0 Ps 30.18
Std. Flov., 198 scfm %N2 80.1 Fo 1.909
Dry Std. Flow 194 dscfm 02+C02 19.9 %EA 801
I STACK METER METER TEMPERATURE
TEMP STATIC DP DH VOLUME INLET OUTLET
POINT (!2!s!:l Qn.WC} Qn.WC} Qn.WC) (d!:!) (!2!s!:l (!2!s!:l
I 1 64 -0.010 0.042 1.22 899.on 80 58
2 63 -0.005 0.046 1.39 1374.879 67 59
3 64 0.060 1.85 74 ,63
4 67 0.043 1.28 80 68
5 68 0.042 1.22 83 _71
I 8 68 0.059 1.78 85 _74
7 70 0.055 1.62 90 79
8 71 0.055 1.62 94 83
9 73 0.057 1.69 94 85
I 10 71 0.055 1.62 92 85
11 74 0.056 1.65 93 85
12 73 a.on 2.31 94 ,90
13 75 0.071 2.12 98 91
14 75 0.087 2.60 96 91
I 15 75 0.075 2.28 95 90
16 76 0.080 2.39 95 90
17 78 0.090 2.67 100 94
18 78 0.070 2.05 101 95
I 19 78 0.055 1.62 100 98
20 79 0.055 1.62 99 ,98
21 78 0.060 1.85 98 95
22 79 0.061 1.87 97 '93
23 81 0.052 1 .51 98 93 ,I 24 80 0.060 1.85 98 94
25 81 0.090 2.67 100 95
26 78 0.090 2.67 101 95
27 78 0.089 2.64 97 93
I 28 79 0.090 2.67 100 94
29 85 0.090 2.67 102 '95
30 85 0.100 2.95 104 97
31 86 0.100 2.95 104 97
32 86 0.097 2.89 104 97
I 33 87 0.100 2.95 104 97
34 85 0.090 2.67 101 95
35 87 0.120 3.50 102 98
36 86 0.060 1.85 103 95
I 37 87 0.062 1.88 102 98
38 88 0.060 1.85 100 93
39 88 0.062 1.88 102 93
40 84 0.060 1.85 102 94
41 86 0.059 1.80 103 95
I 42 86 0.060 1.85 101 94
43 87 0.060 1.85 102 94
44 88 0.062 1.88 102 94
45 84 0.063 1.90 101 94
I 46 83 0.010 0.30 101 94
47 82 0.005 0.15 98 94
48 81 0.005 0.15 95 92
49 82 0.005 0.15 93 92
I 1374.879
I AVG. 79 -0.01 0.06 1.92 475.802 93
I
I
RUN NUMBER SO-M23-R2 I Date 03/17/95
Start Time 09:02
End Time 13:00 METHOD 4 DATA I Stack Diam. 6 inches INIT. FINAL NET
Nozzle I.D. 0.390 inches .(m!). .(m!). .(m!).
Meter Box Gamma 1.0046 IMP.1 0.0 62.0 62.0 I Meter Box dH@ 1.7002 IMP.2 100.0 98.0 -2.0
Barometric 29.88 in.Hg IMP.3 100.0 98.0 -2.0
Cp 1.00 IMP.4 0.0 2.0 2.0 I Test Duration 238 minutes IMP.5 0.0
IMP.6 0.0
IMP.7 0.0
METHOD 1-4 RESULTS TOTAL 200.0 260.0 60.0 I Metered Volume 196.215 def S.G. 300.0 334.5 34.5
Volume @ Std.Cond. 192.086 dscf
% Water 2.26 % METHOD 3 DATA I % lsokinetics 97.4 % %02 18.5 Md 29.00
Velocity 17 .38 ft/sec %CO2 1.60 Ms 28.75
Actual Flow 205 acfm %CO 0.0 Ps 29.88 I Std. Flow 201 scfm %N2 79.9 Fo 1.500
Dry Std. Flow 196 dscfm O2+CO2 20.1 %EA 713
STACK METER METER TEMPERATURE I TEMP STATIC DP DH VOLUME INLET OUTLET
POINT (DegF) (in.WC) (in.WC) (in.WC) (de!) (DegF) (DegF)
1 67 -0.01 0.050 1.60 279.730 66 66 I 2 66 0.045 1.45 475.945 69 68
3 66 0.045 1.45 70 68
4 69 0.044 1.40 73 69 I 5 69 0.043 1.38 75 70
6 69 0.043 1.38 75 70
7 70 0.044 1.40 76 71
8 72 0.062 2.00 79 73 I 9 74 0.060 1.91 83 75
10 76 0.060 1.91 86 80
11 77 0.060 1.91 87 80 I 12 78 0.062 2.00 90 82
13 79 0.100 3.20 88 83
14 80 0.060 1.91 90 86
15 83 0.060 1.91 94 89 I 16 84 0.055 1.75 97 91
17 85 0.100 3.20 97 93
18 85 0.090 2.90 96 92 I 19 86 0.100 3.20 97 92
20 84 0.070 2.20 97 92
21 84 0.090 2.90 95 91 I 22 85 0.100 3.20 96 91
23 86 0.100 3.20 96 90
24 85 0.080 2.60 96 91
475.945 I AVG. 77 -0.01 0.07 2.17 196.215 · 84
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
EPA METHOD 23 LABORATORY DATA
McLAREN HART
STACK OUTLET
RUN I.D.
2378-TCDD
12378-PCDD
1234 78-HxCDD
123678-HxCDD
123789-HxCDD
1234678-HpCDD
OCDD
2378-TCDF
12378-PCDF
23478-PCDF
123478-HxCDF
123678-HxCDF
234678-HxCDF
123789-HxCDF
1234678-HpCDF
1234789-HpCDF
OCDF
TOTAL TCDD
TOTAL PCDD
TOTAL HxCDD
TOTAL HpCDD
TOTAL TCDF
TOTALPCDF
TOTAL HxCDF
TOTAL HpCDF
OTHERTCDD
OTHER PCDD
OTHERHxCDD
OTHER HpCDD
OTHER TCDF
OTHER PCDF
OTHERHxCDF
OTHER HpCDF
NOTES:
SO-M23-R2
SAMPLE
(ng)
0.004 •
0.040 •
0.220
0.350
0.500
8.300
36.600
0.160
0.040
0.110
0.110
0.040
0.070
0.020
0.190
0.000
0.190
0.010
0.230
3.900
17.700
0.790
0.880
0.590
0.340
I
BLANK
(ng)
' 0.000
0.000
0.000
0.000
0.000
0.010 •
0.120
0.040
0.002 •
0.020
0.006
0.000
0.010
0:0_00
0.005 •
0.000
0.000
0.004
0.000
0.008 •
0.010 •
0.110
0.070
0.020
0.005 •
c•) Data represents the estimated maximum probable concen_tration (see
RUN-BLANK
(ng)
0.004
0.040
0.220
0.350
0.500
8.290
36.480
0.120
0.038
0.090
0.104
0.040
0.060
0.020
0.185
0.000
0.190
0.006
0.230
3.892
17.690
0.680
0.810
0.570
0.335
0.002
0.190
2.822
9.400
0.560
0.682
0.346
0.150
report narrative accompanying the dioxin/furan laboratory data, A~pendix 0).
' 2378-TCDF and TOTAL TCDF values were taken from column DB-225 confirmation analysis.
This column is specific for furans. ·
EPA METHOD 23 TEST RESULTS
McLAREN HART'
STACK OUTLET
RUN I.D. SO-M23-R2
CORR. SAMPLE VOLUME: 192.086 dscf
CORR. GAS FLOWRATE: 196 dscfm
02 CONTENT: 18.5 %.
2378-TCDD 2378-TCDD TOXIC EQUIVALENCY
CONCENTRATION MASS TOXIC CONCENTRATIONS MASS
(ng/Nm3 RATE EQUIVALENCY (ng/Nm3 RATE
{ng/Nm3) @7%02) {lb/hr) FACTOR {ng/Nm3) @7%02) {lb/hr)
DIOXINS
2378-TCDD 0.0008 0.0046 5.41E-13 1 0.0008 0.0046 5.41E-13
otherTCDD 0.0004 0.0023 2.70E-13 0.01 0.0000 0.0000 2.70E-15
12378-PCDD 0.0079 0.0457 5.41E-12 0.5 0.0039 0.0229 2.70E-12
Other PCDD 0.0375 0.2171 2.57E-11 0.005 0.0002 0.0011 1.28E-13
123478-HxCDD 0.0434 0.2514 2.97E-11 0.04 0.0017 0.0101 1.19E-12
123678-HxCDD . 0.0691 0.3999 4. 73E-11 0.04 0.0028 0.0160 1.89E-12
123789-HxCDD 0.0986 0.5713 6.76E-11 0.04 0.0039 0.0229 2.70E-12
Other HxCDD 0.5568 3.2247 . 3.82E-10 0.0004 0.0002 0.0013 1.53E-13
1234678-HpCDD 1.6356 9.4729 1.12E-09 0.001 0.0016 0.0095 1.12E-12
Other HpCDD 1.8546 · 10.7413 1.27E-09 1E-05 0.0000 0.0001 1.27E-14
OCDD 7.1975 41.6854 4.93E-09 0 0.0000 0.0000 0.00E+00
TOTAL PCDD 11.5022 66.6167 7.88E-09 0.0152 0.0883 1.04E-11
FURANS
2378-TCDF 0.0237 0.1371 1.62E-11 0.1 0.0024 0.0137 1.62E-12
OtherTCDF 0.1105 · 0.6399 7.57E-11 0.001 0.0001 0.0006 7.57E-14
12378-PCDF 0.0075 0.0434 5.14E-12 0.1 0.0007 0.0043 5.14E-13
23478-PCDF 0.0178 0.1028 1.22E-11 0.1 0.0018 0.0103 1.22E-12
other PCDF 0.1346 0.7793 9.22E-11 0.001 0.0001 0.0008 9.22E-14
123478-HxCDF 0.0205 0.1188 1.41E-11 0.01 0.0002 0.0012 1.41E-13
123678-HxCDF 0.0079 0.0457 5.41E-12 0.01 0.0001 0.0005 5.41E-14
234678-HxCDF 0.0118 0.0686 8.11E-12 0.01 0.0001 0.0007 8.11E-14
123789-HxCDF 0.0039 0.0229 · 2. 70E-12 0.01 0.0000 0.0002 2.70E-14
Other HxCDF 0.0683 0.3954 4.68E-11 0.0001 0.0000 0.0000 4.68E-15
1234678-HpCDF 0.0365 0.2114 2.50E-11 0.001 0.0000 0.0002 2.50E-14
1234789-HpCDF , 0.0000 0.0000 0.00E+00 0.001 0.0000 0.0000 0.00E+00
Other HpCDF 0.0296 0.1714 2.03E-11 1E-05 0.0000 0.0000 2.03E-16
OCDF 0.0375 0.2171 2.57E-11 0 0.0000 0.0000 0.00E+00
TOTALPCDF 0.5100 2.9539 3.49E-10 0.0056 0.0326 3.85E-12
TOTAL PCDD+PCDF 12.012 69.571 8.23E-09 0.0209 0.1209 1.43E-11 ---- --- -- -- --- - - ---
I ,,
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
-
I
APPENDIX D
DATA AND RESULTS FOR
SEMIVOLATILE COMPOUNDS TESTING (EPA METHOD 23)
'
I
I RUN NUMBER SO-M23-R2
Date 03/17/95
I Start Time 09:02
End Time 13:00 METHOD 4 DATA
Slack Diam. 6 inches INIT. FINAL NET
I Nozzle 1.0. 0.390 inches !!!lD. !!!lD. !!!lD.
Meter Box Gamma 1.0046 IMP.1 1 0.0 62.0 62.0
Meter Box dH@ 1.7002 IMP.2 1 100.0 98.0 -2.0
Barometric 29.88 in.Hg IMP.3 · 100.0 98.0 -2.0
I Cp 1.00 I 0.0 2.0 2.0 IMP.4 ,,
Test Duration 238 minutes IMP.5, 0.0
IMP.6 0.0
I IMP.7' 0.0
METHOD 1-4 RESULTS TOTAL 1 200.0 260.0 60.0
Metered Volume 196.215 def S.G. I 300.0 334.5 34.5
Volume @ Std.Cond. 192.086 dscf I % Water 2.26 % METHOD 3 DATA
% lsokinetics 97.4 % %02 ', 18.5 Md 29.00
Velocity 17 .38 fl/sec %CO2 I' 1.60 Ms 28.75
I Actual Flow 205 acfm %CO: 0.0 Ps 29.88
Std. Flow 201 scfm %N2 I 79.9 Fo 1.500
Dry Std. Flow 196 dscfm O2+CO2' 20.1 %EA 713
I STACK METER I METER TEMPERATURE
TEMP STATIC DP DH VOLUME INLET OUTLET
POINT (DegF) (in.WC) (in.WC) (in.WC) (de!) (DegF) (DegF) · I 1 67 -0.01 0.050 1.60 279.730 66 66
2 66 0.045 1.45 475.945 69 68
3 66 0.045 1.45 70 68
I 4 69 0.044 1.40 73 69
5 69 0.043 1.38 75 70
6 69 0.043 1.38 75 70
I 7 70 0.044 1.40 76 71
8 72 0.062 2.00 79 73
9 74 0.060 1.91 83 75
10 76 0.060 1.91 86 80
I 11 77 0.060 1.91 87 80
12 78 0.062 2.00 90 82
13 79 0.100 3.20 88 83
I 14 80 0.060 1.91 90 86
15 83 0.060 1.91 94 89
16 84 0.055 1.75 97 91
I 17 85 0.100 3.20 97 93
18 85 0.090 2.90 96 92
19 86 0.100 3.20 97 92
20 84 0.070 2.20 97 92
I 21 84 0.090 2.90 I 95 91
22 85 0.100 3.20 96 91
23 86 0.100 3.20 96 90
I 24 85 0.080 2.60 96 91
475.945 I
AVG. 77 -0.01 0.07 2.17 196.215 84
I
I
McLAREN HART
STACK OUTLET
METHOO 23 • SEMI-VOLATILE ORGANICS
ANALYTICAL DATA AND RESULTS
SAMPLING DATA:
Run Number:
Corr. Sample Volume:
Corr. Flowrate
02 Content:
CO2 Content:
SO-M23-R2
192.086 dscf
196 dscfm
18.5 %
1.6 %
•·•-~iY@fii'.i!B9Mi:PQ~~ IJl l fiom•Method827O·Tabli0:20ofSW'848 ••
<
<
<
1,4-Dichlorobenzene J
1,2-Dichlorobenzene <
,2' -oxybis(1-Chloropropane) <
BJ
<
<
N-Nitroso-di-n-propylamine <
Hexachloroethane <
Nitrobenzene <
tsophorone <
-Nitro phenol <
,4-Dlmethylphenol <
bis(2-Chloroetho~)methane <
<
,4-Dichlorophenol <
1,2,4-Trichtorobenzene <
Naphthalene B
hloroaniline <
Hexachlorobutadiene <
hloro-3-methylphen'ol <
<
Hexachlorocyclopentadlene <
,4.~ TrichJorophenol <
,4,5-Trichlorophenol <
-Chloronaphthalene <
<
<
<
,4-Dinitrotolue'ne <
cenaphthylene <
3.95 0.00 4 <
2.82 0.00 4 <
2.48 0.00 4 <
2.76 0.00 4 J
2.47 0.00 4 <
5.30 0.00 4 <
21.87 B 67.25 4
3.55 0.00 4 <
3.32 J 14.93 4
6.16 0.00 4 <
5.54 0.00 4 <
3.52 0.00 4 <
1.91 0.00 4 <
5.11 0.00 4 <
3.73 0.00 4 <
3.75 0.00 4 <
8.73 105.54 4
3.89 a.co 4 <
3.27 a.co 4 <
54.78 B 47.79 4 B
2.70 0.00 4 <
5.02 a.co 4 <
4.02 0.00 4 <
1.93 0.00 4 <
4.65 a.co 4 <
4.64 0.00 4 <
4.26 a.co 4 <
1.82 a.co 4 <
6.57 a.co 4 <
1.63 a.co 4 <
6.16 a.co 4 <
4.44 a.co 4 <
1.19 0.00 4 <
Page 1 of 2 I
I
I
I
tsvoCEMtSSIONS f ,:: ;~~!ti I
15.80 < 1.27E-06 < 2.14E-06 I 11.28 < 9.06E-07 < 1.52E-06
9.92 < 7.97E-07 < 1.34E-06
11.04 J 8.87E-07 J 1.49E-06
9.88 < 7.94E-07 < 1.34E-06 I
21.20 < 1.7OE-06 < 2.87E-06
0.00 O.OOE+OO O.00E+OO
14.20 < 1.14E-06-< 1'92E-06 I
0.00 O.OOE+OO O.00E+OO
24.64 < 1.98E-06 < 3.33E-06
22.16 < 1.78E-06 < 3.00E-06
14.08 < 1.13E-06 < 1.90E-06 I
7.64 < 6.14E-07 < 1.03E-06
20.44 < 1.64E-06 < 2.76E-06
14.92 < 1.2OE-06 < 2.O2E-06 I
15.00 < 1.21E-06 < 2.03E-06
0.00 O.OOE+OO O.OOE+OO
15.56 < 1.25E-06 < 2.1OE-06 I 13.08 < 1.05E-06 < 1.77E-06
27.96 B 2.25E-06 B 3.78E-06
10.80 < 8.68E-07 < 1.48E-06
20.08 < 1.61E-06 < 2.71E-06 I
16.08 < 1.29E-06 < 2.17E-06
7.72 < 6.2OE-07 < 1.04E-06
18.60 < 1.49E-06 < 2.51E-06 I
18.56 < 1.49E-06 < 2.51E-06
17.04 < 1.37E-06 < 2.30E-06
7.28 < 5.85E-07 < 9.84E-07 I 26.28 < 2.11E-06 < 3.55E-06
6.52 < 5.24E-07 < 8.81E-07
24.64 < 1.98E-06 < 3.33E-06
17.76 < 1.43E-06 < 2.40E-06 I
4.76 < 3.82E-07 < 6.44E-07
I
I
I
I
I
I
I
I
I
I
.I
I
I
I
I
I
I
I
I
I
I
McLAREN HART
STACK OUTLET
METHOD 23 -SEMI-VOLATILE ORGANICS
ANALYTICAL DATA ANO RESULTS
SAMPLING DATA:
Run Number:
Corr. Sample Volume:
Corr. Rowrate
02 Content:
CO2 Content:
Oibenzofuran
Olethylphthalate
hlorophenyl-phenylether
Fluorene
Nitroaniline
,6-Dinitro-2-methylphenol
N-Nitrosodiphenylamine
Bromophenyl-phenylether
nthracene
Di-n-butylphthalate
Fluoranthene
Pyrene
Butylbenzylphthalate
,3-0ichlorobenzidine
bis(2-Ethylhexyl)phthalate
Benzo(a)anthracene
hrysene
Di-n-octylphthalate
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
lndeno(1,2,J..cd)pyrene
Oibenz(a,h)anthracene
Benzo(g,h,i)perylene
NOTES:
< Undetected
Scu.123-R2
192.006 dscf
196 dscfm
18.5 %
1.6 %
<
<
<
<
BJ
<
<
<
<
<
<
<
<
<
<
BJ
<
<
<
<
J
<
<
<
<
<
<
<
<
<
(B) Present in laboratory blank
2.09
13.92
9.56
1.24
2.12
3.03
1.67
6.34
9.41
2.99
5.59
4.61
7.58
1.29
1.36
21.42 BJ
1.29
1.22
2.67
4.18
14.90 J
1.45
1.50
1.45
1.77
1.80
1.87
1.85
2.42
2.14
(J) Detected but below the quantitation limit; quantity is estimated
(E) Detected but above calibration range; quantity estimated
0.00
0.00
0.00
0.00
6.46
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
7.39
0.00
0.00
0.00
0.00
2.37
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
(SA n Saturated; amount reported should be considered underestimated
4
4
4
14
4
4
14
4
4
,4
4
•4
4
'4
14
4
4
·4
'4
4
f
4
4
4
4
4
4
4
4
4
Page 2 of 2
3.43E-06
< 8.36 < 6.72E-07 < 1.13E-06
< 55.68 < 4.47E-06 < 7.53E-06
< 38.24 < 3.07E-06 < 5.17E-06
< 4.96 < 3.98E-07 < 6.71E-07
0.00 O.OOE+OO O.OOE+OO
< 12.12 < 9.74E-07 < 1.64E-06
< 6.68 < 5.37E-07 < 9.03E-07
< 25.36 < 2.04E-06 < 3.43E-06
< 37.64 < 3.02E-06 < 5.09E-06
< 11.96 < 9.61E-07 < 1.62E-06
< 22.36 < 1.SOE-06 < 3.02E-06
< 18.44 < 1.48E-06 < 2.49E-06
< 30.32 < 2.44E-06 < 4.10E-06
< 5.16 < 4.15E-07 < 6.98E-07
< 5.44 < 4.37E-07 < 7.35E-07
BJ 56.12 BJ 4.51E-06 BJ 7.59E-06
< 5.16 < 4.15E-07 < 6.98E-07
< 4.88 < 3.92E-07 < 6.60E-07
< 10.68 < 8.58E-07 < ·1.44E-06
< 16.72 < 1.34E-06 < 2.26E-06
J 50.12 J 4.03E-06 J 6.78E-06
< 5.80 < 4.66E-07 < 7.84E-07
< 6.00 < 4.82E-07 < 8.11E-07
< 5.80 < 4.66E-07 < 7.84E-07
< 7.08 < 5.69E-07 < 9.57E-07
< 7.20 < 5.78E-07 < 9.73E-07
< 7.48 < 6.01 E-07 < 1.01E-06
< 7.40 < 5.95E-07 < 1.00E-06
< 9.68 < 7.78E-07 < 1.31E-06
< 8.56 < 6.88E-07 < 1.16E-06
If BLANK(ug/Kg) Not Detected, then CORRECTEO(ug) = SAMPLE (ug); if BLANK(ug) > SAMPLE (ug), then CORRECTEO(ug) = 0.00
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
APPENDIX E
DATA AND RESULTS FOR
PCB'S TESTING (EPA METHOD 23)
'
I
I RUN NUMBER SO-M23-R2
Date 03/17/95
I Start Time 09:02 I
End Time 13:00 METHOD 4 DATA I
Stack Diam. 6 inches . INIT. FINAL NET
Nozzle I.D. 0.390 inches !!n!l !!n!l !!n!l I Meter Box Gamma 1.0046 IMP.1 0.0 62.0 62.0
Meter Box dH@ 1.7002 IMP.2 · 100.0 98.0 -2.0
Barometric 29.88 in.Hg IMP.3 100.0 98.0 -2.0
I Cp 1.00 IMP.4 ', 0.0 2.0 2.0
Test Duration 238 minutes IMP.5' 0.0
IMPS 1. 0.0 • I
0.0 I IMP.7,
METHOD 1-4 RESULTS TOTAL'· 200.0 260.0 60.0 ·
Metered Volume 196.215 def S.G. · 300.0 334.5 34.5
Volume @ Std.Cond. 192.086 dscf
I % Water 2.26 % METHOD 3 DATA
% lsokinetics 97.4 % %02 18.5 Md 29.00
Velocity 17 .38 ft/sec %C02i 1.60 Ms 28.75
I Actual Flow 205 acfm %CO:. 0.0 Ps 29.88
Std. Flow 201 scfm %N2 i 79.9 Fo 1.500
Dry Std. Flow 196 dscfm 02+C02 20.1 %EA 713
I STACK METER METER TEMPERATURE
TEMP STATIC DP DH VOLUME INLET OUTLET
POINT (Deg!:) (in.WC) (in.WC) (in.WC) (de!) , (DegF) (DegF)
I 1 67 -0.01 0.050 1.60 279.730 66 66
2 66 0.045 1.45 475.945 69 68
3 66 0.045 1.45 70 68
I 4 69 0.044 1.40 73 69
5 69 0.043 1.38 75 70
6 69 0.043 1.38 75 70
I 7 70 0.044 1.40 76 71
8 72 0.062 2.00 79 73
9 74 0.060 1.91 83 75
10 76 0.060 1.91 86 80
I 11 77 0.060 1.91 87 80
12 78 0.062 2.00 I 90 82
13 79 0.100 3.20 88 83
I 14 80 0.060 1.91 90 86
15 83 0.060 1.91 94 89
16 84 0.055 1.75 97 91
17 85 0.100 3.20 97 93
I 18 85 0.090 2.90 96 92
19 86 0.100 3.20 97 92
20 84 0.070 2.20 97 92
I 21 84 0.090 2.90 95 91
22 85 0.100 3.20 96 91
23 86 0.100 3.20 96 90
I 24 85 0.080 2.60 96 91
475.945
AVG. 77 -0.01 0.07 2.17 196.215 84
I
I
EPA METHOD 23 LABORATORY DATA (PCB's)
McLAREN HART
STACK OUTLET
RUN I.D. SO-M23-R2
SAMPLE BLANK DILUTION
(1!9) (1!9) FACTOR
TOTAL MonoCB < 0.004 0.00 4
TOTALDiCB 4.54 B* 4.20 B* 4
TOTAL TriCB 0.03 * 0.00 4
TOTAL TetraCB < 0.009 0.00 4
TOTAL PentaCB 0.37 * 0.00 4
TOTAL HexaCB < 0.02 0.00 4
TOTAL HeptaCB < 0.02 0.00 4
TOTAL OctaCB < 0.03 0.00 4
TOTAL NonaCB < 0.04 0.00 4
DecaCB 0.11 B 0.11 B* 4
TOTAL PCB 0.16 0.00 4
TOTAL PCB+ EMPC 5.00 4.30 4
NOTES:
(*) Data represents the estimated maximum probable concentration (see
report narrative accompanying the dioxin/furan laboratory data, Appendix Q).
(<) Not detected ·
(B) Present in laboratory blank
RUN-BLANK
(1!9)
< 0.02
1.36 B*
0.12
< 0.04
1.48 *
< 0.08
< .0.08
< 0.12
< 0.16
0.00 B*
0.64
2.80
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
EPA METHOD 23 TEST RESULTS (PCBs)
McLAREN HART
STACK OUTLET
RUN 1.D.
CORR. SAMPLE VOLUME:
CORR. GAS FLOWRA TE:
O2CONTENT:
PCB's
TOTAL MonoCB
TOTALDiCB
TOTAL TriCB
TOTAL TetraCB
TOTAL PentaCB
TOTAL HexaCB
TOTAL HeptaCB
TOTAL OctaCB
TOTAL NonaCB
DecaCB
TOTAL PCB
TOTAL PCB+ EMPC
<
<
<
<
<
<
SO-M23-R2
196.215 dscf
196 dscfm
18.5 %
,.
CONCENTRATION
(µg/Nm3
(µg/Nm3l @7% 0:2)
0.0031 < 0.0179
0.2627 1.5214
0.0232 0)342
0.0070 < 0.0403
0.2859 1.6556 ' 0.0155 < 0.0895 ' 0.0155 < 0.0895
0.0232 < oi1342
0.0309 < oi1190 ' 0.0000 0.0000
0.1236 0.7159
0.5408 3.'1322
<
<
<
<
<
<
MASS
RATE
(lb/hrl
2.12E-09
1.80E-07
1.59E-08
4.76E-09
1.96E-07
1.06E-08
1.06E-08
1.59E-08
2.12E-08
0.00E+00
8.47E-08
3.71 E-07
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I I
APPENDIX F
DATA AND RESULTS FOR
PESTICIDES TESTING (EPA METHOD 23)
I
I
I RUN NUMBER SO-M23-R2
Date 03/17/95
I start Time 09:02
End Time 13:00 METHOD 4 DATA
Stack Diam. 6 inches ; INIT. FINAL NET
I Nozzle I.D. 0.390 inches
IMP.1 I !!!!!l !!!!!l !!!!!l Meter Box Gamma 1.0046 0.0 62.0 62.0 Meter Box dH@ 1.7002 IMP.21 100.0 98.0 -2.0 Barometric 29.88 in.Hg IMP.31 100.0 98.0 -2.0 I Cp 1.00 IMP.4• 0.0 2.0 2.0 Test Duration 238 minutes IMP.SI 0.0
IMP.6, 0.0
I IMP.7; 0.0 METHOD 1-4 RESULTS TOTALI 200.0 260.0 60.0 Metered Volume 196.215 def S.G. 300.0 334.5 34.5 Volume@ Std.Cond. 192.086 dscf I I % Water 2.26 % METHOD 3 DATA
% lsokinetics 97.4 % %02 I 18.5 Md 29.00 Velocity 17 .38 ft/sec %CO2! 1.60 Ms 28.75
I Actual Flow 205 acfm %CO I. 0.0 Ps 29.88
Std. Flow 201 scfm %N2 1 79.9 Fo 1.500 Dry Std. Flow 196 dscfm O2+CO2 20.1 %EA 713 ' I STACK METER! METER TEMPERATURE
TEMP STATIC DP DH VOLUME INLET OUTLET
POINT (DegE) (in.WC) (in.WC) (in.WC) (de!) I (DegF) (DegE) I 1 67 -0.01 0.050 1.60 279.739 66 66
2 66 0.045 1.45 475.945 69 68
3 66 0.045 1.45 I 70 68 I 4 69 0.044 1.40 73 69 5 69 0.043 1.38 75 70
6 69 0.043 1.38 75 70
I 7 70 0.044 1.40 76 71
8 72 0.062 2.00 79 73 9 74 0.060 1.91 83 75 10 76 0.060 1.91 86 80 I 11 77 0.060 1.91 87 80 12 78 0.062 2.00 90 82
13 79 0.100 3.20 88 83
I 14 80 0.060 1.91 90 86 15 83 0.060 1.91 94 89
16 84 0.055 1.75 97 91
I 17 85 0.100 3.20 97 93 18 85 0.090 2.90 96 92 19 86 0.100 3.20 97 92
20 84 0.070 2.20 97 92 I 21 84 0.090 2.90 95 91
22 85 0.100 3.20 96 91 23 86 0.100 3.20 ' 96 90
I 24 85 0.080 2.60 ! 96 91
475.945:
AVG. 77 -0.01 0.07 2.17 196.2151 84
I
I
EPA METHOD 23 LABORATORY DATA (PESTICIDES)
McLAREN HART
STACK OUTLET
RUN I.D. SO-M23-R2
SAMPLE
(1:!!!l
alpha-BHC < 0.0200
a-Chlordane < 0.0200
Aldrin 0.1045
beta-BHC < 0.0200
delta-BHC < 0.0200
4,4'-DDD 0.5750 *
4,4'-DDE 0.5860 *
4,4'-DDT < 0.0400
Dieldrin 0.0489
Endrin < 0.0400
Endrin Aldehyde < 0.0400
Endosulfan I < 0.0200
Endosulfan II < 0.0400
Endosulfan sulfate < 0.0400
gamma-BHC (Lindane) < 0.0200
g-Chlordane 0.1261
Heptachlor 0.0207
Heptachlor epoxide < 0.0200
Methoxychlor < 0.2000
Toxaphene < 2.0000
NOTES:
(<) Not detected
BLANK DILUTION
(1:!!!l FACTOR
0.0000 4
0.0000 4
0.0000 4
0.0000 4
0.0000 4
0.0000 20
0.0000 20
0.0000 4
0.0000 4
0.0000 4
0.0000 4
0.0000 4
0.0000 4
0.0000 4
0.0000 4
0.0000 4
0.0000 4
0.0000 4
0.0000 4
0.0000 4
(*) Sample exceeds calibration limit. Sample was reanalyzed at a dilution factor
of 20. All other samples were analyzed at a dilution factor of 4.
RUN-BLANK
(1:!!ll
< 0.0800
< 0.0800
0.4180
< 0.0800
< 0.0800
11.5000
11.7200
< 0.1600
0.1956
< 0.1600
< · 0.1600
< 0.0800
< 0.1600
< 0.1600
< 0.0800
0.5044
0.0828
< 0.0800
< 0.8000
< 8.0000
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
EPA METHOD 23 TEST RESULTS (PESTICIDES)
McLAREN HART 1
.
STACK OUTLET
RUN I.D.
CORR. SAMPLE VOLUME:
CORR. GAS FLOWRATE:
O2CONTENT:
PESTICIDES
alpha-BHC <
a-Chlordane <
Aldrin
beta-BHC <
delta-BHC <
4,4'-DDD
4,4'-DDE
4,4'-DDT <
Dieldrin
Endrin <
Endrin Aldehyde <
Endosulfan I <
Endosulfan II <
Endosulfan sulfate <
gamrna-BHC (Lindane) <
g-Chlordane
Heptachlor
Heptachlor epoxide <
Methoxychlor <
Toxaphene <
' I•
I
SO-M23-R2 I
192.086 dscf
196 dscfrn
18.5 % I
I
CONCENTRATION
(b!g/Nrn3)
0.0158
0.0158 .
0.0825
0.0158
0.0158
2.2689
2.3123
0.0316
0.0386
0.0316
0.0316
0.0158
0.0316
0.0316
0.0158
0.0995
0.0163
0.0158
0.1578
1.5784
j(µg/Nrn3
1@7% 02) I
' <I
<\
<I
<I
I I
<!
I
<'
<I
<i
<
<I
<I
I ,·
< !
< I
<
I
I
0.0914
0.0914
0.4776
0.0914
0.0914
13.1410
13.3924
I•
'
0.1828
0.2235
0.1828
0.1828
0.0914
0.1828
0.1828
0.0914
0.5764
0.0946
0.0914
0.9142
9.1415
MASS
RATE
(lb/hr)
< 1.08E-08
< 1.08E-08
5.65E-08
< 1.08E-08
< 1.08E-08
1.55E-06
1.58E-06
< 2.16E-08
2.64E-08
< 2.16E-08
< 2.16E-08
< 1.08E-08
< 2.16E-08
< 2.16E-08
< 1.08E-08
6.82E-08
1.12E-08
< 1.08E-08
< 1.08E-07
< 1.08E-06
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
APPENDIX G
I
I I
"
DATA AND RESULTS FOR
VOLATILE COMPOUNDS TESTING (EPA METHOD 0030)
-------------------
McLAREN HART
LTTDS
METHOD 0030 (VOST) SAMPLING DATA
Meter Box I.D.
Box Calibration Factor:
Run I.D.
M/H-M0030-R2
18
1.0414
Date
12/15/94
Start
Time
15:06
End
Time
15:46
Meter Meter Bar.
Temp. Press, Press.
(Fo) (in. we) (in. H9)
66.0 1.00 30.30
Initial Final Corrected Corrected
Meter Meter Sample Sample Sample
Volume Volume Volume Volume Volume
(liters) (liters) (liters) (dscm) (dsc!)
2407.27 2427.18 19.910 0.0211 0.7458
I
M:LAREN HART I LTTDS
METHOD 0030 -VOLATIU! ORGANIC COMPOUNDS
ANALYTICAL DATA AND RESULTS
I SAMPLING DATA:
Run Number: MIH-M0030-R2
Corr. Sample Volume: 0.7458 dscf
Corr. Flowrate: 150 dscfm (1) I ANALYTICAL DATA:
Sample I.D.: 94-385-303/305
Blank 1.0. 94-'365-309/311
I
E
,,
62.50 < 0.003 < 0.003 < 5.47E-05 < 1.42E-01 < 7.98E-08 I 94.95 B 0.768 BJ 0.015 B 0.753 B 9.03E-03 B 3.57E+01 B 2.00E..05
64.51 < 0.003 0.000 < 0.003 < 5.30E-05 < 1.42E-01 < 7.98E-08
richlorofluoromethane 137.38 J 0.010 0.000 J 0.010 J 8.29E-05 J 4.73E-01 J 2.66E-07
96.95 < 0.002 0.000 < 0.002 < 2.35E-05 < 9.47E-02 < 5.32E-08 I 76.14 J 0.010 J 0.004 J 0.006 J 8.98E-05 J 2.84E-01 J 1.50E--07
58.08 0.615 0.398 0.217 4.26E-03 1.03E+01 5.77E-06
84.94 0.317 0.433 0.000 O.OOE+OO O.OOE+OO O.OOE+OO
rans-1,2-Dichloroethene 96.95 < 0.002 0.000 < 0.002 < 2.35E-05 < 9.47E-02 < 5.32E-08 ,1 1, 1-Dichloroethane 98.97 < 0.001 0.000 < 0.001 < 1.15E-05 < 4.73E-02 < 2.66E-08
is-1,2-Dichloroethene 96.95 < 0.001 0.000 < 0.001 < 1.17E-05 < 4.73E-02 < 2.66E-08
hloroform 119.39 J 0.004 J 0.004 0.000 O.OOE+OO O.OOE+OO O.OOE+OO I 1,2-Dichloroethane 98.96 < 0.001 0.000 < 0.001 < 1.15E-05 < 4.73E-02 < 2.66E-08
86.09 < 0.001 0.000 < 0.001 < 1.32E-05 < 4.73E-02 < 2.66E-08
72.10 < 0,014 0.000 < 0.014 < 2.21E-04 < 6.63E-01 < 3.72E-07
1, 1, 1-Trichloroethane 133.42 < 0.001 0.000 < 0.001 < 8.54E-06 < 4.73E-02 < 2.66E-08 'I 153.84 < 0.001 0.000 < 0.001 < 7.40E-06 < 4.73E-02 < 2.66E-08
. 78.11 0.089 J 0.042 0.047 6.BSE--04 2.23E+OO 1.25E--06
131.40 < 0.001 0.000 < 0.001 < 8.67E-06 < 4.73E-02 < 2.66E-08 I 112.99 < 0.001 0.000 < 0.001 < 1.01E-05 < 4.73E-02 < 2.66E-08
163.83 < 0.001 0.000 < 0.001 < 6.95E-06 < 4.73E-02 < 2.66E-08
s-1,3-Dichloropropene 110.98 < 0.001 0.000 < 0.001 < 1.0JE-05 < 4.73E-02 < 2.66E-08
110.98 < 0.001 0.000 < 0.001 < 1.03E-05 < 4.73E-02 < 2.BBE-08 I 133.42 < 0.002 -0.000 < 0.002 < 1.71E-05 < 9.47E-02 < 5.32E-08
208.28 < 0.001 · 0.000 < 0.001 < 5.47E-06 < 4.73E-02 < 2.66E-08
252.77 < 0.003 0.000 < 0.003 < 1.3SE-05 < 1.42E-01 < 7.98E-08 I thyt-2-pentanone 100.16 < 0.002 0.000 < 0.002 < 2.27E-05 < 9.47E-02 < 5.32E-08
92.13 J 0.040 J 0.026 J 0.014 J 1.73E--04 J 6.63E--01 J 3.72E-07
etrachloroethene 165.85 < 0.002 0.000 < 0.002 < 1.37E-05 < 9.47E-02 < 5.32E-08
100.16 < 0.003 0.000 < 0.003 < 3.41E-05 < 1.42E-01 < 7.98E-08 I 112.56 < 0.001 0.000 < 0.001 < 1.01E-05 < 4.73E-02 < 2.66E-08
106.16 J 0.003 0.000 J 0.003 J 3.22E-05 J 1.42E-01 J 7.98E-08
106.16 J 0.017 J 0.010 J 0.007 J 7.51E-05 J 3.31E-01 J 1.86E-07 I 106.16 J 0.006 0.000 J 0.006 J 6.44E-05 J 2.84E-01 J 1.60E-07
104.14 J 0.009 J 0.006 J 0.003 J 3.28E-05 J 1.42E-01 J 7.98E-08
11 2 2-Tetrachloroethane 167.86 < 0.001 0.000 < 0.001 < 6.79E-06 < 4.73E-02 < 2.66E-08
NOTES: I (1) Flowrate taken from Method 23 testing performed on the L TTOS Stack.
< Undetected
(8) Present in laboratory blank I (J) Detected but below the quantitatlon limit; quantity is eslimaled
(E) Detected but above calibration range; quantity estimated
-If 81.ANK(ug/Kg) Not Detected, then CORRECTED(ug) = SAMPLE (ug); if BLANK(ug} > SAMPLE (ug), then CORRECTEO(ug} = 0.00
I
I
I
I
I
I
I
I
I
I
APPENDIX H
I CALCULATIONS
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
EPA METHODS 2-4 CALCULATIONS
Metered Gas Sample Volume at Standard Conditions
Vm(std) -Vm X y X
528 B 13.6
[
p + liH ]
29.92x Tm+460
Gas Volume of Water Vapor Collected in' Impinger Liquid
Vwccsed) -(vt -v;) x0.04707
Gas Volume of water Vapor Collected in, Silica Gel
vwsg(std) -(wt' -wi) x0.04715
Moisture Volume Fraction in Flue Gas
B _ VwcCstd) + Vwsg(scd)
ws V +V +V wc(std) wsg(std) m(std)
Moisture Volume Percentage in Flue Gas
%H2O -B_.5 x 10 0
Absolute Pressure of Flue Gas
pstatic
13.6
Nitrogen Content of Flue Gas
%N2 -100 -(%CO2 + %02 + %CO)
Dry Molecular Weight of Flue Gas
Md -0.44x%CO2 + 0.32x%O2 + 0.28x (%N2 + 'liCO)
Wet Molecular Weight of Flue Gas
M5 -Mdx (1 -B.,5 ) + 18 xB.,5
Fuel. Factor Based on Flue Gas Composition
20.9 -%02
%CO2
F -0
EPA METHODS 2-4 CALCULATIONS -continued
11. Excess Air of Flue Gas
%02 -0. 5%CO %EA------=-~----~ xlOO 0.264%N2 -(%O2 -0.5%CO)
12. Average Gas Velocity, ft/sec
13. Area of Round Duct or Stack
1t xD2
A -5 4 X 144
14. Area of Rectangular Duct
(round ducts)
A -L x w (rectangular ducts) 5 144
15. Actual Volumetric Flow Rate of Flue Gas
16. Flow Rate of Flue Gas at Standard Temperature and Pressure
17. Dry Flow Rate of Flue Gas at Std. Temperature and Pressure
Qsd -Qsx (1 -B.,s)
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I A,
Bws
cP I D,
AH
AP
I Fo
y
L
I ~ M,
Pa
PS I p static
Q.
Qs
I Qsd
Tm
Ts
vf I V;
vm
Vm(std) I v.
V wc(stdJ
V wsg(std)
I w
wf
W;
I %Oz
%CO2 %CO
I
%Nz
%EA
I
I
I
I
I
I
I I
I
= =
= =
= = = = = = =
= =
=
=
= = = = =
=
= = =
=
=
=
= = =
= =
=
=
NOMENCLATURE FOR EPA METHODS 2-4
Stack area, ft2
Moisture volume fraction
Pitot tube coefficient (~0.84)
Stack diameter, inches
Average meter orifice pressure, ·in.w.c.
Pitot tube differential pressure, in.w.c.
Combustion factor
Meter calibration factor, gamma
Length of rectangular stack or duct, inches
Dry molecular weight, lb/lb-mole
Wet molecular weight, lb/lb-mole
Barometric pressure, in.Hg
Absolute stack pressure, in.Hg
Average static pressure, in. W .:c.
Actual gas flow rate, acfm
Standard gas flow rate, scfm
Dry standard gas flow rate, dscfm
Average meter temperature, °F
Average stack temperature, °F
Final impinger volume, ml
Initial impinger volume, ml
Uncorrected metered gas volume, def
Corrected gas volume, dscf
Average gas velocity, ft/sec
Gas volume of water caught in:impingers, scf
Gas volume of water caught in silica gel, scf
Width of rectangular stack or duct, inches
Final silica gel mass, grams
Initial silica gel mass, grams
Dry volumetric concentration of o2, %dv
Dry volumetric concentration of CO2 , %dv
Dry volumetric concentration of co, %dv
Dry volumetric concentration of N2, %dv
Percent excess air
1.
2.
3.
4.
5.
6.
EPA METHOD 0050 GRAVIMETRIC CALCULATIONS
PM Collected in Probe Wash -M~
Mpw -( WP.,) final -( WP.,) taro
Applicable Acetone Blank Correction -B8~
[ ( Wab) final -( Wab) care] X VP.,
vab
Maximum Allowable Acetone Blank -Bamax
Bamax -0.7845 X 0.00001 x Vpw
Actual Probe Wash Blank Correction -B~
Bpw -MINIMUM [Bapw' Bamax]
PM Collected on Filter -Mf
Mf -( Wf) final -( Wf) taro
Total PM Collected for Method 5 Calculations -Ms
Ms -Mpw + Mf -Bpw
NOMENCLATURE
Bamax
B•~
~
Mf
M~
Vab V
(~ab) final
(Wab) tare
(Wf) final
(Wf) tare
(W~) final
(W~) tare
=
=
=
=
=
=
=
=
=
=
=
=
=
=
Maximum allowable acetone blank correction, based
on weight of acetone in probe wash, grams
Acetone blank correction based on residue of
blank, grams
Acetone blank correction actually used, grams
Total mass of particulate in train corrected for
acetone blank, grams
Mass gain of filter, grams
Probe wash residue, grams
Liquid volume of acetone blank, ml
Liquid volume of probe wash, ml
Final weight of beaker containing acetone blank
residue, grams
Tare weight of beaker containing acetone blank
residue, grams
Final weight-of filter, grams·-
Tare weight of filter, grams
Final weight of beaker containing probe wash
residue, grams
Tare weight of beaker containing probe wash
residue, grams
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
1.
2.
3.
4.
5.
PARTICULATE EMISSIONS CALCULATIONS
Particulate Concentration -Csd
7000
453.593·
Particulate Concentration Corrected to; 7% 02 -C5d@7%02
C C 20. 9 -7. O
sde?\ -sdx 20. 9 -%02
Particulate Concentration Corrected to 12% CO2 -C5d@12%C02
12
Csd812% -Csdx %CO
2
Particulate Concentration Corrected to 50% Excess Air -
C5d@50%EA
Particulate Mass Rate -MP
X Osd X 453.593
60 ·
6. Isokinetic Variation -%ISO
NOMENCLATURE
=
=
=
=
=
=
=
=
=
=
= =
=
=
=
%Isa -0. 09450 x ( T 8 + 460) XVm(stdl
P8 XV8 XAnx timex (1 -B.,8 ) ,
Nozzle area, ft2
Particulate concentration, grains/dscf
Nozzle diameter, inches
Summation of PM collected in: sample train, grams
Mass rate of particulate emissions, lb/hr
Absolute stack pressure, in.Hg
Dry standard gas flow rate, dscfm
Net sampling time, minutes
Average stack temperature, °F
Corrected gas volume, dscf
Average gas velocity, ft/sec
Dry volumetric concentration of 0 2, %dv
Dry volumetric concentration of CO2, %dv
Percent excess air
Percent isokinetics
EPA METHOD 0050 CALCULATIONS
1. MASS OF Cl ION IN SAMPLE -Met
2 • MASS OF HCl IN SAMPLE -MHCI
3.
..:3c..:6c..:·-:4c::6-=l.,,_g!..../ m=ol=-e=-· Mnc1 • Mc1X 35.453g/mo1e
CONCENTRATION OF HCl -ppmdv
x( lgram )x( g-mole )x( 0.84948ft')xl06
1000mg MW;grams g-mole
4. CONCENTRATION AT 7% 0 2
C, • C X _2_0_. 9_-_7_. 0-'-
i HCl(Ifl 20.9-%02
5. HOURLY EMISSIONS RATE -M;
C;XQ5 dx6 0 XMW; M.•----"'---'""------='---
i 106 xo. 84948x453. 593
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
NOMENCLATURE FOR EPA METHOD 0050
i
M;
C;
Qsd 60
36.461
35.453
0.84948
453.593
106
= mass of Cl ion in sampl'e -mg
= chloride concentration ,of the impinger
catch -mg/liters = chloride concentration of the
blank -mg/liters
= volume of impinger solution -ml = mass of HCl in sample~ mg = the dry basis HCl concentration -ppmdv
= sample gas volume -dscf
= molecular weight of HCl, 36.461
= Concentration of gas i corrected to 7% 02 = Actual gas concentration of 02 ,
% dry volume
= HCl
= Mass emissions rate of :i, lb/hr
= Concentration of i in stack gas, ppmdv
= Average flue gas flow rate, dscfm = Minutes per hour
= molecular weight of HCl -g/mole
= molecular weight of Cl -g/mole = Molar volume of ideal gas, ft3 /mole
= grams per pound
= parts per million
METHOD 23 CALCULATIONS
DIOXINS/FURANS
1. Gas Concentration -Cm; (ng/Nm3)
where W;
Vmstd
35.3145
528/492
Note that
W;x35. 3145 528 Cm1---''-----X--Vms td 492
= total sample weight of (i) (nanograms)
= the volume of gas sampled at STP (dscf) = cubic feet per cubic meter
= temperature conversion from 68°F to 32°F
Normal m3 is defined at 32°F and 1 Atm.
2. Gas Concentration at 7% o2-Cm7; (ng/Nm3) ·
cm_ -em.x20.9-7.0
•. .,, i 20.9-%02
3. The mass flow rate of substance (i), G; (lb/hr), is:
W;X0sdx60 G------==---=----
i VmscdX10 9 x453. 593
where W; = total sample weight of (i) (nanograms)
Vmstd = the volume of gas sampled at STP (dscf)
Qsd stack gas flow rate (dscfm) =
60 = min/hr
109 = nanograms per gram
453.593 = grams/lb
4. Toxic Equivalency Conversion -CiTEF
C--C-xTEF '= i
where TEF = toxic equivalency conversion factor
,., '
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
1.
METHOD 23 CALCULATIONS
SEMIVOLATILES
Total Mass in Sample
1. Concentration
2.
me 7000 Cc ---x __ ..:...;:..::....:'--
Vm.,d 106x453.593
Mass Emissions Rate
=
= = = =
=
=
= = = = =
NOMENCLATURE
total concentration of analyte, gr/dscf
dilution factor
mass of blank, µg
mass of sample, µg
total mass of analyte, µg ,
total mass emissions rate of analyte i, lb/hr
dry standard gas flow rate, dscfm
corrected gas volume, dscf
grams per pound
micrograms per gram
minutes per hour
grains per pound
METHOD 23 CALCULATIONS
PCB's/PESTICIDES
1. Total Sample Weight -W; (micrograms)
wi-( ws-Wb) xd
_where w,
Wb
d
= weight of sample (micrograms)
= weight of blank (mircograms)
= dilution factor
2. Gas Concentration -Cm; (µ.g/Nm3)
Wix35. 3145 528 Cm. -~----=-:-------,--x--
i Vmstd 492
where W;
Vmstd
35.3145
528/492
Note that
= total sample weight of (i) (micrograms)
= the volume of gas sampled at STP (dscf) = cubic feet per cubic meter
= temperature conversion from 68°F to 32°F
Normal m3 is defined at 32°F and 1 Atm.
3. Gas Concentration at 7% 02-Cm7; (µ.g/Nm3 )
cm -em.x20.9-7.o
•• .,, 1 20.9-%02
4. The mass flow rate of substance (i), G; (lb/hr), is:
where W; = total sample weight of ( i) (micrograms) Vmstd = the volume of gas sampled at STP (dscf)
Qsd = stack gas flow rate (dscfm)
60 = min/hr
106 ·= micrograms per gram
453.593 = grams/lb
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
1.
2.
3.
3.
VOST EMISSIONS CALCULATIONS
Metered Gas Sample Volume at Standard Conditions
[
p + !J.H ]'
Vm(std)-VmXYX17,64X B 13 •6 +28.317 Tm + 460 ,
Concentration of Substance, ppmdv
m · o. 84948x106
C----0- X
, Vmstd MWix106
Concentration of Substance, µg/dscm
m. cd---0-x35. 3145
Vmstd
Mass Emission Rate
Cd
Qs
G;
0.84948
28.317
35.3145
453.593
106
106
60
=
=
= =
=
=
=
=
= =
=
=
=
= = =
=
=
=
=
NOMENCLATURE
the volume of gas sampled through the dry gas
meter -liters.·
corrected gas volume, dscf
the DGM calibration factor.
ambient barometric pressure -in. Hg.
the average DGM differential orifice pressure
-in w.c.
meter temperature -°F
total mass of reported pollutant obtained in
laboratory analysis, µg.
the volume of gas ·sampled at STP (dscf).
molecular weight of substance.
concentration of substanc·e in the gas stream,
ppmdv
concentration of substance, µg/dscm
total stack gas flow rate (dscfm)
mass emission rate of substance, lb/hr.
std. cubic feet per gram mole of ideal gas.
liters per cubic foot
std. cubic feet per std. cubic meters
grams per pound
micrograms per gram
parts per million
minutes per hour
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
APPENDIX I
RAW FIELD DATA FOR ·
PARTICULATE AND HCl TESTING (METHOD 0050)
I f-OCY''! "r'"fl / voCi11•o'z) I "HJ3J I. · It. 1-f' 0800 -fdJb ~3l1l•
I 911 I 0 7(( ., r;01' !ill
8P.,b'C HYed
tOUL I eH•
7.b 0 Cl I 'l# I , I , O~I · 9'
'J~OO 'I lYWH\':J
01 ·0·1 XD!I
0·1 # 1011d
071 00 1 2# Iv ~F 5 5d1:
af,11 0/J/ L# h'l V --:1, f,t'/( I "'-f".&1 t 01'
t 31ZZON 1YNJ; 1Yll!NI · H3~NldHI ""'iJ ( ~ -, ,~j •O( I )v'fl '1J 1f :::/ I ~ '51N31NOJ Har.lNldH!
__, '7 I. ::J <I ITT I NOl1d!HJS30 •0·1 31dHYS H3N!V1NOO
Jib "lJ3HJ )V31 'A001Srtl ,O NIVIIJ . I .
I
SO"C·hb? t.,<L S&I
'.) ,hl: ") s h3 lb O'l,~~ 50i SbV' \-,2, 0/!J
51 Q._ <; I'.'. '?S I-, J', . e, b S hl? ~;,,L c;, r . hi? au
S'/ 'est IS~ 5 2, 't b ',, . b, I i-, O'C _5~ <J~/
_c; I o~c: LS-59, --e !, .s '.!,),~ S'? ot· 5g lo._ -0s1
~·1 u.:,c:_ L;; it c;, b .L·or;_J 8'? o-r· Si w,, .
\I ost BS L& b O '·1:, I :; O'S 0"!/ L \\ u,, I .
11 o_c;e LS -Lt,_ 1 I, c;_ ·.:iU7 O'S V') I 0 ·11:1 0-C)
I I osc LS I, 'l, )-, b j··H5 /2, h ~,a I ' ii CJ I!
I I osr LS O!, Lb L O!l.S ~·h <.JS I 2,i 00/
, I I 1 s,~ LS b& "!b 1-, ns Q'S 0 ,, . 9., fs '-'0
1 \ 1 .s I'., °JS !,~ Sb h'.s.SS Q"5 011. ")S lo -CJ8
0/ b/.,t,. h.:i b~ ':lb 5 . ' h::, S'h Oh I. l !l OL
QI l:, h ,:__ h5 f,$ 'J b _,. I\._;, .\, . I; 01-, I , "!2 0~
!, \_' 0 ~,~ s.s lK 'Ch .. ', • CJ /_. ]• fs''. O'l I' ss os
b ';_c,c, O';) '-'lo I j, . h 'lc,O). ~ ''i., 0'('.1 s~ OJ.,
·':) bh t 'e ") ,e t-e: L · oo_g )"L' (_ <;:'I.()" £15 °" " Q..',('. h'? "'.)P ' 01,; kl'! bh 5'.:'t <;;LO' LP, Ot;
0 r_s-c h'7 '>Fl S'& l) ·c;_gi., h'[ SLo·· ')f, 01
h 6h1'.. S'J ~& c;_g S'Sh '')LI; b'C-1 hO' hi! tthl IJ
"JVA "dl!3l . "dl!31 J311l1) 131NI ii "" d' "dl!31 JllYlS 3HU 3H11 lNIOd I 1!3l3W H3.11U Har.lNldHI "dial lelO "dH31 lelO 3Hn"fuh lelO l!313W lOYlS lOYlS 31dWYS
I H -W --0~ :•0•1 Nill o.soo
. 3'6/ti/t :3.1,ro
d s'.l. ' 7 "5R '1NV1/1110d
+<s J+ ~'0 .5j J 6f g :KOuv:m J.s3J.
tt /-,I :3w11 lHV.IS ...
-,----"Tf-J'"'b""fj,--'"'u"",.J"'-b"'),.,.5'""1,(1.,.,_ !lll11JY4 .,
'3Hl1 ON3
40 -l-39Yd
,6f9L/B)
133HS YlYO 9Nl1dWYS Jl13Nll0Sl I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
APPENDIX J
RAW FIELD DATA FOR
DIOXINS/FURANS, SEMIVOLATILES, PCB's, AND PESTICIDES TESTING
(EPA METHOD 23)
I Rev;sfon 1
llfAc1L1rr: Mc ko r re,
.ART TIME: 0 ~ £; '-1
I POINT
SAl4PLE
TIME TIME
r, tJl l/<I
J 10
?-0
I ~~
I..,.,
,o
I (,JJ
10
I '30
'lo
t 100
IIO .
I "O
l2P
Lu-J=. /,5tJ -
,,_
I \70
L~O
I
i'lO
J.oO
:110
I J;J. 0
)..: .... o
I ,_.., 0
CHAIN OF C\JSTOOY·
CONTAINER SAMPLE l.0.
/,.,
{ d-9
/).q
I 'J 0
/JI
/))..
h '/
I
rSOll:rNET!C SAMPlfNG DATA SHEET
f-to c± TEST LOCATION: S+<1c.k Oy ti._,+··
03/16/94
PAGE_/ OF .2._
DATE; --3 ''" h>' ' , EJjD TIME: I{,, 50 POLLUTANT: __,,Cl.,_,_I\J"-'-F ___ .,__ RIJN I.D.: .SO;. M:13 • R J
STACX STACX METER DGM ~LO<E 0GM TEMP. OGM TEMP. IMP!NGER FILTER METER
STATIC TEMP. ,.p 6H ft INLET CJJTLET TEMP. . TEMP. VAC.
[ t/ . I)'-()_ I, L)-S<t'\ .on 1.o 5"/. ff I >>l !,-. ()
(,,} ,O'-il I ._ q 'le, f;". ':, (;. "1 ~ 'l ... , '1.'i"(. ~-0
r '-l . o i;.o ,.ss 'i' I I ; ~ .... I.{ ~"l. S"'J-~SI 7.1)
G, 7 _,,42, l.'l 'il 9 \'\, ~ 9b (g 11 ss :lal ,.a
(o~ • M'-j;l, ).?,_;,, 'l'.15° ·1 Ii'~ 71 59 ~"O C.. 0
"'8 ,, s <\ l,i'a ~ )?-. 0 '?G" 7'-1 C'\ ;;2Y't 7.rl
I" ,Q.GC" I. Vl. <j'\,9,6 't-0 ,9 I" I 7. 5'), /, 0
11 • c,<;5 l.b2 'l'ic..7 q y g) C.5 ~ '-j ~ ,.o
12' .o6l I, I, 'I ~S'-l. o 7'-l ~5 5?, 151 7,0 I
-.0 I ,1 .oss-/, G, ~ 'Hl-3 q., Rfi 'i l 2'>0 1,.D
l'-1 ,0 <oL I. (. ii q~i,_ 5 'I .,, ~s '-I~ -;i ~~ 7..0
7 '.J .017 ) '1. I 9.15. "'\ q '-{ ·qo 5?, '). 5 °' 9.o I
15 '" I I 'J . 1.:i q ';'-j G 0. " q / -51 d. 5" ~ CJ i}
-
7<:;' . "'il 1 ") / '"' 9~ i. <;_ q (, 9 I (,,O ".l 'i C, /0 o -l.5 -", 5 ~ ...... loo;,. J. q.5 C/o (o ~ • :J so 9 O
, r ,()C:, '.2-' °' ID I o. '1 q) 90 Cl "5"0 1.0
-, '6 i,q 0 J., l "'''~-· /0 0 tt'<; ss < s-o /o o
lv . '} 't ).. -OS-//);-'!, ).-"· I "1 ,.,. . ;, I. 0 & 'I,( y .,-. . ,
115 05'< f.'?. /0;,7. 3 100 ? G Go :iSI ,.s
79 .o'~ i-6.l, ·~ L, 4 . ~. q 1 ~ G ti G\ 2. ', ~ 7.o
7~ .0/,,0 /..SIC /0 SI \) ~ '( ~s-6'-J ). '-I 'l '? (;
l"-~o& I 1-'I 1 105'1. 5" Gl 93 5~ 'J 'i "f '8. 0
I! \ ,OS':), /SI /067. J q~ C, .J "o )51 7-0
<;;o . 0 {,,O 1-'i'.5 io,4, ,s '\4 1'-1 6 ( :t5"0 ~ . ,...,
ll l .o~ ).. • l /OB'J,.?, iOD 'is C'-1 Jy 'ii iu o
LEAK CHEO::
DES CR I PTI OH
F:t rf" II
VAC1JIJM
I
/> .,
.I I RATE ,OOe> -4---+---+----11
· pu /luJ,,.. !Pl, ,. IMP!NGER CCNTEJjTS:
I
f-/-1 Toi., . lMPINGER INITIAL FINAL NOZZLE t
-r_. I PITOT i 1,0
-r.~. I ,,. ... #1 0 !?O sax 1.0. /0
Cl;." t. I #2 Io ~ {rl( GAMMA T I, DO~C,
iAo ,,... ~ #3 IO V I) y ,J!il ,. 700:l
' #4 -0 ;? PaAR 10 ,/ 'i1
#5 ~•o, °3cil FILTER
} I .. I ,:!6·
' TECH. I 6.v,,,,,~ {vade/'<)JO•dl
I I I I I I I I I I ::.~-I _;.;_•· I I I I I I I I t ' ;-0 1: 0 I I I I .. I I I I I I I ... __ bl ~ .. },/..t\ .-·--... __ , __ . --JJ. -~ ~ . r. ') . 'c. I, s:J 1-,;.<;, vt•I . ~--(_ Q_j-1'. , .. '1:1 . ... ~r. b.:.... =-Sb --1.-~. o-s I., h I: o, hb 't:, 1, h '8 .'J'C1 Q'',. 6 /,(<!_ b5' hb ) 0/ b'l-,?C.f o·., 'l'.'.s e. 5'5' h1; I 1 o 1 \,'"JS'e,I o·b ,si h.5' t->b '(. CJ 1 't'1ohl/ I V'b ll..SC. rs; i-, b 't.s, I 5·1 hX-1 _9·.1:, ~:s 1'.: ·...S':i h,b I <>l t 'h,t.1 --o:,, --' -) t. .t,' ..Sb '-o I l · 'J-c-tl ... o ·1 !.St 9" hb '(O/ . · 1:--,·· ~ I '!'.I _ 0 6 bh'C. ~5 \: b --c,0/ . -, . n 't I o·b 6h('.. i-,,S 'i:.b Oal 1, "(Ol/ <l'b q_q;. 1.£: ~/:, "C. o/ c·5bl/ <> . b ,;,, },9 />6 'i. (I/ ( ·1.,g11 S5.-I ().!; t. r, ib Y. ()J t,'H .. 11 S'ol ~st. ·o, Sb I CJ/-') · L ,, I 5"1 I l i-,t, &.5 Lb /,OJ f, 'l.b 11 5·11 l ht z...s .. I_ b. hO/ I:,' 1...1-,1 I ...S"l 1 Shi S'S Lb .. hO/ 1-,. ~<;.\I -S'')J .si-,c h.$ ·Lb 1-, 01 S, 6 'el I 0 'o, O.S"C. g ':) 5_; -col '('b1 I I a·ot I _, C. .$' hb 001 1,·1,011 O ·01 lo ht h'.:) Sb Lb L 'QO// 0·01 bht 'i".) 9b I G'JI ,-., 'I bO/ ·,vA "d-31 • cft21 l3'1lr'O , i31HI <l; E313H E3ll!; E:DN!dlll "<!1131 w:io 'd-31 Ir.JO 3h,'11DA lr.lO I i I ·-, I . I J , i ,., -I I I I I .. .... ... ...... -... , ---.. :,,,9 /' 5-n,D~-t:zl,-. ·•· . -.·•-·--·• .. .... Si., _ _sgq: ,: l.t.t ----SI ' ,S QC)' 1:~ £' I 9, 'i. 6 01 ·1 ~ 90' \., 6 &s·1 'C")Q. &S .99., .. I ") 0' L& 58-I '-0' ')b Q 3 '/ b5o · "n ·-ss·1 -;qi h~ ~z-1 ..,_ ')a• g '6 Sil '/ ~o· I, 8 t, i 'I '(..')O' u 5ol 70 .1J Y'( 'C I • U, L ~ 't b U' si I S'l.''C 01' L !, bB c-Lb o• ")€ $1,'l 0.1 V ")cf .9h' t 01' 9g L ) "'(, le, O' s:t "~ ''e b O' I:, L 500 ,_ h '·t bS Q' /1_, L L 'l "t: 1, CJ • lsL H• ti" "dn'3l :lllYlS C":l.3H ::ons ::ons I , I --· .. -.. , .... .:..· -,--.. . 3Hll I --·-I tcrroV/, l=io )\137 I ·-~14, -'. ,.;,-~: ... -.:. ·----" _:_Qi;. Ci. -CJ"Jf; . CJ-'> r, On,, O~h O'try OH:-; t/01~ .. · Ob't, ol?.-<;. OL£ c;, J) o_,f. 01..,\: q~ 9 Otf 0) c:. . _ UC)t Ob'( ewe oi..t 0 '?l: OS'/'. 3Hll lNIOd 51dW\'S II ·-,;_,:. -·~ ;::j =<; 1: ~·--I 8 -... t •-oO, :-c-11((18 .;1010 'lKl'lI1110d os-n '3Hll 0N3 \-,h Bo :3wu·Hvl.S 5b/~1/<;.. ::,no -r>J+IIO_ >j5&fs 'HOl!Y:l071S31 +JBH v,101J()) :.u171,v; 'c ;0[3~Vd ,6191/£0 .!..:aHS f'l\'O Dn:nlWt'IJTJ.3til)OSJ L UO!S!AV~
I
·!1
••
.1
I
I
·1
I
I
-•
I
I
I
Revision 1
FACILITY: /Yl c Lg c~,,
START TIME: ? : 0 2,
SAMPLE
POINT TIME TIME
,4() tt:o:).
10
~o
~
'tr.,
So
,o
le,
)/0
~o
loo
/le
ll,.o
/:!C)
/'to
150 -
IG.o
110
,io
i~O
"°0
;).40
~1..0
J'l,0
-~
I CHAIN OF Cl.lSTOOY:
110°
I
I
I
I
I
CONTAINER SAMPLE 1.0.
I lt
/17
rrt
I 'J'f
I '4 {)
I '-I I
{" }
. •. _113/)6/94
ISOKINETIC SAMPLING DATA SHEET P~GE I Of
TEST LOCAT!OM: _ _.S;..+...,?:,,._,.C a:;IL._· _· ..;:;O_.u;;..+;..l ... e_; .... +_· _· _· DATE: J) I] / qs
£110 TIME: _ _..i-'-:J_O_v __ POLLIITAIIT: _.Q..,.r,,.1 ... f ____ ·_. _.·'RUM 1.0., ~o . M:?-3. ~ ::i,
STACI( STACI( METER DGM~E DGM TEMP. DGM TEMP •. . !!!PINGER FILTER METER STATIC TEMP. ,.p oH . ft .·, , , INLET .. aJTt£l TEMP· •. TEMP. VAC.
(. l .05 (, (.. ;;l.7'1. 7.1,0 ,c.' .. ,-(_ c,;' 57 :. lS-:t ,.
r_r
I') '-I ' I. 'f < .., Q(. , ., CL C<,1 '5'-( .. 2 5:2. " f..(,, ,ll'-1~ l,YS ,q),). 70 r.. 51 <,q ;;/y, l
(o 9 ,0 '-/'-( ., ' 'i jOO. I l"-i C, ~ C, I 'JSO 7
t. "f .ri'-i'\ I,) g 30<,, "\ 75 ,o (,,~ 1So l
-,t\ I (,, 'i' .O'-i.3 I. '.'i ') 311,. G. 15 ID (, 3 -;) ... 'i:I 7 ,o '() '-I y I '-I :,,:,_o. 3 7(.. 71 _', I ::)4 ~ 7 ,'l r, c. -::i 'J. f\ ~27, r, 7'1 ,-i... yo :15'--I q
7'--l AC 191 .)':,5. 0 g) 7 5" 5:\ "d. '-\ 9 ~
' ' 7 (, , 0 (,, ·, 1-9 I )'i';,' 9 ~(.; 2/ <:> ss -;;/ ,:;-.,, 1
17 . 6 " J. q I 3S0,'-1 ~l fii'O s, ;l ) \ ~
t't, C,L 0 " 0 )'°78 ') 9o :;, .;l "i '1 ~5~ "i
l"r • JO 5,1 ~i;,' ?_' -,? 'ii ff) -(,::l ? 'f''-{ p. . -;ro . 0 Co I, 9 I ·,,'!,., _3, '( 0 'i'G:, 63 ~ss 9 . 'd ', • 0 Co I. °t I { )°',' 't '14-'il "I K''-{ . ;, _,;_s-1-
3'-1 ,OSS 17S '.l~:l-. ,'.':, 't l 'r ' SY ?,50 g
85" .. , ◊ ', ' ). ">~'1, 7 '{7 9j 51. ;I '.i '-I I :;l,
85 ,O"f ), "t Lio"!. ~ q (. 9 :l. s 'if 1-Y. \/ I ~
'ill, .,/ 0 ·,, J. '-i,q, (,, 'll 'l :,_ G.O 'J'/0 I 1,
'lY ,0·1 ;/ ;I-'-1)0. 0. c,7 9 J. (, ;;i, ?.S-0 10
'I> '-I . O'l ,.'i '-Jo',' s 'IS 'i I ,,,..., ;) ':, 3 i)
i\5 . /0 3,:1-Y'H . I q G, 9 ( C G )SD i-;\
x (, , /0 1, ' ). "1 )~ ,.) q (.::, 'i'O S'G:. ·Js½ /'J
<;/1, • 0 'i J,(,, '-169. , '1(,, 9 I 55 J. ,:-~ I ;,
'n5. q'IS '
I
LEAIC CHEO::: I ,tr
DESClUPTICH lb.,
.1)1.Z-I
FI f-rr IMPINGER COMTENTS:
;::11/1°((;,M J/11 IMPINGER INITIAL FINAL NOZZLE t
r->I, -r.,/ .. ,~, P!TOT # l,O ..,.._. I #1 0 /,, j..., BOX 1.0. <t/O
t;,,.~ I l:,.,>e #2 ,oo C({ GAMMA T I-0 0,1..
~ :1. ·,. ,,, #3 (OD ri Alllil \,700'1
tkO #4 0 ).... PBAR )-q_'((
#5 '?06 J] L/,5 FILTER -
#6 TECH. ()QuvY\"'" / UA.d<fwOOd
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
APPENDIX K
RAW FIELD DATA FOR
VOLATILE COMPOUNDS TESTING (EPA METHOD 0030)
. • Revision 1 03/16/94
OF
I
I
I
I
I
I
I
I
I
I
I
I
VOST SAMPLING DATA SHEET PAGE
FACILITY: HcMec,.J TEST LOCATION: .l_/ f-P s DATE: /2-/'.';-9</
START TIME: tt/';)_G,. END TIME: _____ _ TECHNICIAN: -:r<;: /TW RUN 1.0.: µ/JJ · Mo":,~ R /<.')._
METER BOX 1.0.: /B,
TENAX I.D.
CHARCOAL I • D.
TIME
METER VOLUME
(liters)
METER TEMP.(°FJ
METER PRESSURE
(in W.C.)
SYSTEM VACUUM
SAMPLE RATE (l/m)
COND • 1 TEMP. (OF)
COND •. 2 TEMP. (OF)
PROBE TEMP. (OF)
LEAK RATE
TENAX I.D.
CHARCOAL I .D.
METER PRESSURE
(in W.C.)
SYSTEM VACUUM
SAMPLE RATE (l/m)
COND. 1 TEMP. (°FJ
COND. 2 TEMP. (OF)
PROBE TEMP. (OF)
LEAK RATE
CALIBRATION FACTOR: {.6/<.//
Zo .._:,... C, • 7S • r ""
CARTRIDGE SET #1
qcJ. 3(.,<;-3o z..
'l't-3'S-300
INITIAL FINAL
l<i?>'f-145'</
23 'ff, I/ !I<
23'1.1,11 24-ofo. 3 rf
¢1 S7
·~ti ~I-I
z. 2.
.7f 1~
J?..'i I 73B
0.0 t).O
"'U,,v I
60.r--1K:)
e\RU:tDOE SET 114
INITIAL FINAL
BAROMETRIC PRESSURE: 3o 3.c LEAK VACUUM:~ RATE: oo,.,,,_ J.J_j-
J./o ,.,,,.1 e ca6' ~ .....
CARTRIDGE SET #2 CARTRIDGE SET #3
q-1-:¾0 3-o~ °ti-~,,. 3-o W'
<?c/-~~-'3-o~ 9'-/--"J(,,,~-a-u.::,
INITIAL FINAL INITIAL FINAL
!so<-15¢(,,.
24o·7. Z'I 2427.18
~2. JO
/.o /.o
2... '2.-
o. Co JI,,~ 6.&'o.f.,._
Z.?-Ci p'{o
6-e· 00
/{v>V'l..
CARTRIDGE SET #5 CARTRIDGE SET #6
INITIAL FINAL INITIAL FINAL
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
APPENDIX L
RAW FIELD DATA FOR 02 AND CO2 ANALYSIS
(EPA METHOD 3A)
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
INTEGRATED BAG ANALYSIS DATA
Job Neme A<LPrt,,,,_ ;,/,;.,/--
Contrcct q?-31:i-'1
Method of Anelysls ~/!"
Run Number i(½ ico2
st) -r-1>-]-/l. ( /!fa l. I
5,l) -/YI f) . ;2 2 !'i.s /.6
!>O -/J'lA,C~ -/l I lt't ;.,
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I I
APPENDIX M
GRAVIMETRICS LABORATORY DATA
---~---------------
Contract No. 94-365
Job I.D.
Test Method METHOD 5/0050
I Sample I Container Other I
I No. I No. I.D. I
I I I
100200 I Fl Q02LOSL94-00SOISO
100201 I F2 /so
/00202 I F3 /so
100203 I F4 /so
/00204 I F5 /so
/00205 I F6 /so
/00206 I Fl Q08L24/94-0028/BLK
/00207 I F2 /BLK
/00208 I F3 /BLK
/00209 I F4 /BLK
I 00210 I F5 /BLK
100211 I F6 /BLK
E T S I N C .
F I E L D S A M P L E L O G
Run Sample
I.D. Type
-050-Rl Tared Quartz Filter
-050-Rl FH ACETONE RINSE
-050-Rl IMP 1-3 CATCH+RINSE
-050-Rl IMP 1-3 CATCH+RINSE
-050-Rl IMP 4-5 CATCH+RINSE
-050-Rl SILICA GEL
-050-RO Tared Quartz Filter
-050-RO FH ACETONE RINSE
-050-RO IMP 1-3 CATCH+RINSE
-050-RO IMP 1-3 CATCH+RINSE
-050-RO IMP 4-5 CATCH+RINSE
-050-RO SILICA GEL
Print Date 03/21/95
Page 1
IVolume,ml Volume,ml Analyst
lno Rinses w/ Rinses
I
I ejb
I ejb
I ejb
I ejb
I ejb
I ejb
I ejb
I ejb
I ejb
I ejb
I ejb
I ejb
Time 11:48:40
Date Comments
03L21L95
03L21L95
03L21L95
o3L21L95
o3L21L95
03/21L95
03/21/95
03/21L95
03L21L95
03L21L95
03L21L95
03L21L95
ETS, Inc.
GRAVIMETRIC LABORATORY DATA
Final Beaker Weights
Job Number: 94-365
Report Prepared on: 03/23/95 Page 1
Beaker#
Filter #
Sample#
Run I.D.
I Constant I . Final Weight Data Constant I
I Tare I Date Time Weight (g) Analyst Final I
Weight (g) I Weight (g) I
I I
Total Vol . , ml Beaker I I I
I Aliquot Vol. Filter I I I
1------------------------l------------------------------------------1--------------I
103/20/95-001 66.19340 103/22/95 15:36 66.58590 PJB I 66.58610 I
1002/08/94-0080 0.38670 103/23/95 09:40 66.58610 PJB I I
I 94-365-00200 I I I
I so -050-Rl I I I
I I I I
I I I I
1------------------------1------------------------------------------I--------------I
I 03/20/95-002 67. 52580 I 03/22/95 15: 36 67. 52720 · PJB I 67. 52770 I
I 0.00000 103/23/95 09:40 67.52770 PJB I I
I 94-365-00201 I I I
I so -050-Rl I I I
I 105. 00000 I I I
I 105. 00000 I I I I
1------------------------1-------------------------·----------------1--------------1
I 03/20/95-003 64. 56890 I 03/22/95 15: 37 64. 95170 PJB I 64. 95220 I
I008/24/94-0028 0.38660 103/23/95 09:40 64.95220 PJB I I
I 94-365-00206 I I I
I BLK -050-RO I I I
I I I I
I I I I
1------------------------l------------------------------------------1--------------I
103/20/95-004 66.89630 103/22/95 15:37 66.89710 PJB I 66.89760 I
I 0.00000 103/23/95 09:40 66.89760 PJB I I
I 94-365-00201 I I I
I BLK -050-RO I I I
1100.00000 I ·1 I I
I 100. 00000 I I I I
1--------------1----------1------------------------------------------1--------------1
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I APPENDIX N
I HCl LABORATORY DATA
I
I
I
I
I
I
I
I
I
I
I
I
I
I
,,.,. ..
k1 ,~;
lft""
IIJOIJl'f-
1
I
I
I
I
I
I
I
I
I
I I
l
c/-
Arn 10,UA.LAB0RAT0RV ANAL VS IS
CALIBRATION CURVE GENERAL INfORMATION
M D EQU8t1on ofCelibrat1on Line Molarity of Electrode
Standard Potential
I Cl-) mV log( M) = a x P + b
a=------
Job IA LL()..p,,...l,._,..,..
Contract lltr-JGS
~ z. 35', 2.
~ Z-3Z. I
b= _____ _ Analyst i5. !lo?~ A
Ambient Lab {{o Temperature
~ [ 'l~. 6 Dete of Test 2: f ,1if 14, 12 l~'t::5
~ JJt . .J Dete of Anal 1J3is z. 'i! ...t A-1t , ,,u·
110.::j-
SAMPLE DATA
Vs~ln Va p M
Total Sample Aliquot Electrode Molarity Run No. Volume Volume Potential
[NH/] ml ml mV
So-/HOO~O -
soC.~l Ri /OrJ-1 Z..33-5
15lAt-lK 'r~O~I /00 ... 1 1, 3,0."
•
i
I
I I I
SIGNATURE __________ _
CHLORIDE ION STANDARD DATA
Standard
Cone. (ma/Ll
1000
100
10
1
0.1
Constant
Std Err of Y Est
R Squared
No. of Observations
Degrees of Freedom
X Coefficient(s)
Std Err of Coef.
Log Reading
Cone. (MVl
3.00 80.70
2.00 136.30
1.00 195.60
0.00 232.10
(1.00) 235.20
Regression Output:
-0.01928938796293
0.00133507 4384349
Duplicate
IMVl
4.6089671049258
0.1540286345405
0.9905100718966
4
2
I
I
I
I
I
I
.I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
STANDARD CHLORIDE ION CURVE
10000 -r------------------,
1000 -.....J -C>
E 100 -' .
0 z 10
0
0
1 .
.
0 ' I I , !
' ' ' ' ~ 80.70 136.30 195.60 232.10 235.20
MV READING
REGRESSION CURVE
10000 ------------~
1000 .-.
_J -0)
E 100 -. . u z 10
0 u
1
0 ~----!'--~-'~-+-'" ---+-' ----+',-/ · I I I -80. 7 136.3 195.6 232.1 235.2
MV READING
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I I
I I
-------------------
HCI LABORATORY DATA AND RESULTS
McLaren Hart
Stack Outlet
Reading Duplicate
Run I.D. (MVI (MV)
SO-M0050-R1 233.50 233.50
Blank 230.40 230.40
Reading Duplicate Liquid Sample Total Cl-
Conc.(mg/Ll Conc.(mg/L) Volume (mil in Samole (mal
1.27 1.27 506.00 0.64
1.46 1.46 400.00 0.58
TL-RTP Project: 31982A
Client Sample: TLI M23 Blank
Method 23 TCDD/TCDF Analysis (DB-225)
Analysis File: X950962
Client Project:
Sample Matrix:
TLRTPID:
Sample Size:
Dry Weight:
GCColumn:
2,3,7,8-TCDF
Total TCDF
"Ci,-2,3,7,8-TCDF
13Ci 2-1,2,3,4-TCDD
n/a
XAD Date Received: I I Spike File:
TII Blank Date Extracted: 03/21/95 ICAL:
Date Analyzed: 03/27/95 CONCAL:
1.000 Dilution Factor: n/a % Moisture:
n/a Blank File: X950962 % Lipid:
DB-225 Analyst: AJB % Solids:
0.05 0.74
0.12 6 0.29
2.7 66.7 0.82
0.78
Data Reviewer. __ S___;_A_,_·_· .c.P_-_~_·..::"'"'~~----03/28/95
Page 1 of 1
Triangle Laboratories of RTP, Inc.
SPC2NF04
XF22224
X950961
n/a
n/a
n/a
22:12
22:11
21:07
Cl."fF _PSR v:1.07, LARS 5.14.08
801 Capitola Drive• Durham, North Carolina 27713
Phone: [phone] • Fax: [phone]
Printed: 17:22 03/28/95
50
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I TL-RTP Project: 31982A , ·
Client Sample: 00145 BLANK
Method 23 TCDD/TCDF Analysis (DB-225)
Analysis File: X950966
1,------------------,
Client Project: McOaren-Hart
Sample Matrix: M23TRAIN I TLRTP ID: 97-160-2A-DF
I Sample Size:
Dry Weight:
GC Column:
1.000
n/a
DB-225
I 11~!¥!~~• t
2,3,7,8-TCDF
11:~e~~~l: l I Total TCDF
I
13Ci2·2,3, 7 ,8-TCDF
11;:fi~5,ey~;~~~n§~! I 1'C1,-1,2.3,4-TCDD
0.04
0.11
2.9
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor:
Blank File:
Analyst:
9
72.3
03/18/95
03/21/95
03/27/95
n/a
X950962
AJB
0.25
Spike File:
ICAL:
CONCAL:
% Moisture:
% Lipid:
% Solids:
0.87
0.81
SPC2NF04
XF22224
X950961
n/a
n/a
n/a
22:26 B
22:25
I ~1tiil ;;§™§~ i:I
0.80 21:19
I
I
I
I
I
I Data Reviewer: ___ S_A_-_P_-_-_.......__,_ ___ 03/28/95
I Triangle Laboratories of ATP, Inc.
801 Capitola Drive• Durham, North Carolina 27713 I Phone: [phone] • Fax: [phone]
Page 1 of 1 cz.-.r_PSR v:l.r:tl, LARS !i.14,08
Printed: 17:22 03/28/95
132
TL-RTP Project: 31982A .
Client Sample: 00145 BLANK
"Ci,-2,3,7,8-TCDF
13C12-2,3,7,8-TCDD
13C12-l,2,3, 7,8-PeCDF
1'C1,-1.2.3,7,8-PeCDD
13C1,-l,2,3,6,7,8-HxCDF
"C12-l,2,3,6,7,8-HxCDD
1'C12-1,2,3,4,6, 7,8-HpCDF
13C12-l,2,3,4,6, 7,8-HpCDD
13C12-1,2,3,4,6, 7,8,9-0CDD
37CLi-2,3, 7 ,8-TCDD
13C12-2,3,4,7,8-PeCDF
llC12-l,2,3,4, 7,8-HxCDF
13Ci2-l,2,3,4, 7 ,8-HxCDD
"Ci,-1.2,3,4, 7 ,8,9-HpCDF
2.2
2.3
2.2
2.4
2.8
2.4
2.5
2.4
3.7
3.3
3.9
3.7
4.1
3.5
55.7
56.9
54.1
60.5
69.3
60.6
62.7
59.2
46.9
83.1
98.7
91.6
102
87.6
I
Method 23 PCDD/PCDF Analysis (a) I
Analysis File: S951720
I
:ti#lit@ ;:,;; ;!~;(;;,: l~~¾~ i'I I
0.80 25:31
0.79 26:18
1.40 29:41
1.71 30:48
0.52 33:22
1.21 34:03
0.44 36:14
1.02 . 37:16
0.88 40:49
26: 18
1.39 30:25
0.52 33: 16
1.20 33:58
0.44 37:45
I
I
I
I
I
I
"C12-1,2,3,7 ,8,9-HxCDF
"C12-2,3,4,6, 7 ,8-HxCDF I
l""!~"'····~"'f""9""Y8""fY"')"'··~"'I~"";"':~"'~"'•··•·••·"'··~"'\==========================='""-=""··:·•"':I I
13Ci2-1,2,3,4-TCDD 0.80 26:06
2.6
4.1
64.0
102
0.51
0.52
34:36
33:51
13C12-l,2,3,7.8.9-HxCDD 1.20 34:21
I
Data Reviewer: __ s_·_/)_·_P_~ __ '--______ 03/28/95
Triangle Laboratories of RTP, Inc.
801 Capitola Drive• Durham, North Carolina 27713
Phone: [phone] • Fax: [phone]
Page 2 of2 X::!37_PSRv:!.07.~ S.l-1.08
I
I
I
I
Printed: 16:58 03/28/95 I
103 I
I'
I
I
I
I
I
I
I
I
I
••
I
I
I
I
I
TL-RTP Project: 31982A
Client Sample: 00145 BLANK
Client Project:
Sample Matrix:
TLRTPID:
Sample Size:
Dry Weight:
GC Column:
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2.3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7.8-TCDF
1,2,3,7,8-PeCDF
2.3,4,7,8-PeCDF
1.2.3,4,7.8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3, 7,8,9-HxCDF
1.2.3,4.6,7.8-HpCDF
1.2,3,4, 7 .8,9-HpCDF
1,2,3,4,6, 7,8,9-OCDF
McClaren-Hart
M23TRAIN
97-160-2A-DF
1.000
n/a
DB-5 ·
ND
ND
ND
ND
ND
EMPC
0.12
0.05
EMPC
0.02
0.006
ND
0.01
ND
EMPC
ND
ND
0.004
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor:
Blank File:
Analyst:
1
0.004
0.007
0.009
0.008
0.009
0.004
0.005
0.008
0.02
Method 23 PCDD/PCDF Analysis {a)
Analysis File: S951720
03/18/95
03/21/95
03/28/95
n/a
S951719
MM
0.01
0.002
0.005
Spike File:
ICAL:
CONCAL:
% Moisture:
% Lipid:
% Solids:
0.80
0.70
1.35
1.25
1.28
SPX23704
SF53254
S951718
n/a
n/a
n/a
40:49
25:33
30:26
33:16
33:52
B_
B
B -B -B -B_
B -
B -
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
ND 0.007
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
Triangle Laboratories of RTP, Inc.
EMPC
EMPC
0.14
0.07
0.02
EMPC
801 Capitola Drive• Durham, North Carolina 27713
Phone: [phone] • Fax: [phone]
7
5
2
0.008
0.01
0.14
0.08
0.02
0.005
Page I of2 X237 _PSR v:1.07, LARS S.14 011
Printed: 16:58 03/28/95
102
TL-RTP Project: 31982A .
Client Sample: 00136 S0-M23-R2
· Method 23 TCDD/TCDF Analysis (DB-2:25)
Analysis File: X950963
Client Project:
Sample Matrix:
TI.RTF ID:
Sample Size: .
Dry Weight:
GC Column:
2,3, 7,8-TCDF
Total TCDF
"C12-1,2,3,4-TCDD
McOaren-Hart
M23TRAIN
97-160-lA-DF
1.000
n/a
DB-225
0.16
0.79
2.2
Date Received: 03/18/95
Date Extracted: 03/21/95
Date Analyzed: 03/27/95
Dilution Factor:
Blank File:
Analyst:
18
53.9
n/a
X950962
AJB
1.0
Spike File:
!CAL:
CONCAL:
% Moisture:
% Lipid:
% Solids:
0.74
0.80
SPC2NF04
XF22224
X950961
n/a
n/a
n/a
22:12
22:10
B_
0.79 21:06
Data Reviewer: ___ s_. _Fl_·_·_?_"'--'--__ '-_____ 03/28/95
Triangle Laboratories of RTP, Inc,
801 Capitola Drive• Durham, North Carolina 27713
Phone: [phone] • Fax: [phone]
Page I of I c:.,'F _PSR v:!.07. LARS 5.P.011
Printed: 17:22 03/28/95
92
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
••
I TL-RTP Project: 31982A -'.
Client Sample: 00136 S0-M23-R2
I 1 III!m~~!~~ml~r~ l r 11r····,······•.•······· .··•.··••.
13C12-2,3,7,8-TCDF 3.0
13C12-2,3,7,8-TCDD 2.9
I 13Ci,-l,2,3, 7 ,8-PeCDF 2.6
13C12-l,2,3,7,8-PeCDD 3.3
13C12-1,2,3,6,7,8-HxCDF 3.4
I 13C12-l,2,3,6,7,8-HxCDD 2.9
13C1,-l,2,3,4,6,7,8-HpCDF 3.2
13C1,-l,2.3,4,6,7.8-HpCDD 3.1
1'Ci,-l,2.3,4,6,7,8,9-OCDD 5.1
Method 23 PCDD/PCDF Analysis {a)
Analysis File: S951721
ii§~~~fyi;:i: t••·•~~;1; 1•~.;~:s1I
76.2
72.0
65.4
83.7
85.3
72.2
80.5
76.9
64.0
0.79 2532
0.77 26:18
1.58 29:41
1.69 30:49
0.51 33:22
1.19 34:04
0.44 36:14
1.04 37:17
0.89 40:49 •~~~~~~~~=~== liv~;I~iif;mir~~Iiil!i \~rrm cn1:t••H1•:r•· %iRecovery ij.iil§f I !RT l\ IE§~~! .;
' "CL.-2,3,7,8-TCDD
13Ci,-2,3,4,7,8-PeCDF .1
13Ci2-1,2,3,4,7,8-HxCDF
13C1,-l,2.3.4. 7 ,8-HxCDD
13Ci,-1,2,3,4, 7 ,8,9-HpCDF
I
I
13Ci,-l,2.3,7,8,9-HxCDF
13C12-2,3.4,6. 7 ,8-HxCDF
1 l•l'l~R?X?rx~~~r~~~ •?I
13C12-1,2,3,4-TCDD I 1'C12-l,2,3,7,8,9-HxCDD
I
I
I
3.6
4.1
3.5
4.4
3.6
3.2
4.7
91.0
103
88.7
110
91.0
81.0
117
1.57
0.51
1.20
0.45
0.52
0.51
26: 19
30:26
33: 16
33:58
37:45
34:37
33:52
\l'filtkl 1• rnt••·••·•ar ~;~~ !I
0.79 26:06
1.18 34:22
I Data Reviewer: __ S_·_A-:__· :.._p_..,_____.:....:..._c'::::-;,~-----03/28/95
I Triangle Laboratories of RTP, Inc.
801 Capitola Drive • Durham, North Carolina 27713
1 Phone: [phone] • Fax: [phone]
Page 2 of2 X::!37_PSR v:1.07. LARS 5.!-1.0S
Printed: 16:58 03/28/95
60
TL-RTP Pfoject: 31982A
Client Sample: 00136 S0-Mi'3-R2
Client Project:
Sample Matrix:
TLRTP ID:
Sample Size:
Dry Weight:
GC Column:
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2.3, 7,8,9-HxCDD
1,2.3,4.6,7,3-HpCDD
1,2,3,4,6,7,3,9-OCDD
2,3.7,3-TCDF
1,2,3,7,8-PeCDF
2,3.4,7,3-PeCDF
1,2,3.4,7,3-HxCDF
1,2.3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3.7,8,9-HxCDF
1,2,3.4.6,7,8-HpCDF
1,2.3.4, 7 ,8.9-HpCDF
1,2,3,4,6,7,8,9-OCDF
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
McOaren-Hart
M23TRAIN
97-160-lA-DF
1.000
n/a
DB-5
ND
EMP_C
0.22
0.35
0.50
8.3
36.6
0.26
0.04
0.11
0.1 I
0.04
O.Q7
0.02
0.19
ND
0.19
0.01
0.23
3.9
17.7
0.82
0.88
0.59
0.34
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor:
Blank File:
Analyst:
1
6
7
2
13
13
10
2
0.004
0.007
Method 23 PCDD/PCDF Analysis {a) I
Analysis File: S951721
03/18/95
03/21/95
03/28/95
n/a
S951719
MM
0.04
0.04
0.36
0.86
0.89
0.60
0.36
Spike File:
ICAL:
CONCAL:
% Moisture:
% Lipid:
% Solids:
1.27
1.20
1.24
1.01
0.89
0.68
1.59
1.48
1.08
1.08
1.19
1.09
0.97
0.86
SPX23704
SF53254
S951718
n/a
n/a
n/a
33:59
34:04
34:22
37: 17
40:50
25:35
29:42
30:26
33: 16
33:22
33:52
34:39
36:15
41:02
PE:-
B
B_
B_
B_
B
EJi,..
I
I
I
I
I
Page I of2 X:37_PSR v:!.Q7, LARS 5.14.08
I
I
I
I
I
I
I
I
I
I
I
I
Triangle Laboratories of RTP, Inc.
801 Capttola Drive• Durham, North Carolina 27713
Phone: (919} 544-5729 • Fax: [phone]
Printed: 16:58 0~8j5
.
11719 28-R-i:i 12,44 70S (EI•) $f.is:1Dl&JS
R: 339,re97 H: 341.re67 o, li1.1QJ p, li3.8970 Q: li5.~
: TLI P23 a.Ft« llI13198211 --. .
0...._,.....,._ .................................................................... .....-......... ......... I· H s1,Il,G2 · · · ·
~ 0 S1,I ,62
'
1.00
21,t887
1.00
15.8801
1.00
5401
-8..i--~~---I 27,30 28:00 28:30 29,00 29,30 30,00 30,30 31 ,00 31 ,30 32,00
I
I
I
I
I
I
I
I
I
I 4 3 .
5351719 28-lff-~ 12,44 i'8S CE!•) &ls:lfll&S
G1 2 R: 339.8597 H: 341.8567 O: 351.ml p, 353.89t'"9 Q: liS.8546
Text: TLI 123 Mt: TLil31S82A
100 R St ,11,lx?
50
0 ___ ......,.. ......... _.,.._.....,._,,__.....,......_.............,
Ui• H Sl,I ,Ix? A = 67 .;,9 T: :!=26 00
c"d.~)3 = 1.5209
50
0-..................................... -.,.._.....,.__,....,_.,.,.,.._..... .........
100 0 S1 ,I ,Ix?
50
1.00
5401
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
43 I
·1
351719 28-fi~ 12:44 705 CEI•) &15:!Dl!ilS
~ ii F= 319.8965 G= 321,SSli H= 327.0047 I= 300,9722 J: 331.9:)38
?-'ilLI 1'23 11.fH( lll 131982A -:
I
I
I
I
I
I
I
I
I
I
J Sl,Il,62
1.11
13,6632 X Q • I ')c -i, 'F ~
1,00
13.3159
1.00
4140
13. ·C (
SS51719 28-R~ 12:44 i'0S (El+) Si.ls:tmilS
I GI 2 B: :m.0016 C: ~.8007 D= 315,9419 E: 317,:ms f: 319,8935
Text:TLI '23 llff« TLil3198211 · ·
100• B S1, I1 ,Ix!
0--.........,...,.... ........................... -..--......-..,......._,.....,_,,,
100 C_S1,I ,Ix!
8--. ................... _..._ ....... _......_,_ ............................. ~
100 D S1,I ,62
50
1.00
16,8647
1.00
15,7834
1.00
4533
I
- I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
4S I
I z Rer. aass 292.0025 Peil tt'f) I .le!.gt 2. 10 vd..ts Spai 200 i:1-'ll
9ptea rlle naae lfflJS
I Oat.a rile naae A:~1119
58 Rm.lii.oo llllll
I ~!Uber 2
looi.zat i.oo ,me El•
SWltchlng 'tll.TrtI
I Rer. aasses 292 .m, 416.9768
5 A 293 J ~ s ~
BJ4 K 334 T 3i'0
I C ll6 L 338 u 3i'6
D 316 R 340 Y 410
E 318 H 342
I r l:0 0 352
58 G 322 p 354
H~ Q 356
I I 331 R l:i8
I (Mine!. I 338,9792 Peil tt'f)
5 Heljt 1.03 vd..ts Spai 200 ~
I
I
I
I
I
I
I
I
I
~
I 45
I
S951719 28-ftAR-95 Si.r=Uoltage 70S Sys= N085US
SaRple 1 Injecti.on 1 Group ,4 _ ~ass 457 .7377 I Text=TLI ft23 BLANK TLil31982A .
10~ Nor-= 22 I
~ I I . • . . . . . . . . . .
0 ' I ' • 39; 10 40100 . ' 35=50 36=40 37=30 38=20 40=50 41 =40 42=30 43:20
S951719 28-ftAR-95 Si.r=Uoltage 70S Sys= N085US I SaRple 1 Injecti.on 1 Group 4 ftass 459 .7348
Text=TLI ft23 BLANK TLil31982A
101 NorR' 29 I
I
' . ' . .
0 . I ' ' ' ' ' 35=50 36=40 37=30 38=20 39: 10 40=00 40=50 41=40 42=30 43:20
S951719 28-ftAR-95 Si.r=Uoltage 70S Sys= NOB5US I sa~ple I Injechon I Group 4 ftass 469 .7779
Text=TLI ft23 BLANK TLl131982A I 10 NorR' 1554
I
0 I
35=50 36=40 37=30 38=20 39: 10 40=00 40=50 41 =40 42=30 43:20 I S951719 28-ftAR-95 Si.r=Uoltage 70S Sys: NDBSUS
SaRple 1 In jecti.on 1 Group 4 ftass 471.7750
Text=TLI ft23 BLANK TLil31982A I
10 NorR= 1789 I
I
0
35=50 36=40 37:30 38=20 39: 10 40=00 40=50 41 =40 42:30 43:20 I
4·4 I
I
I
I 10
S951719 28-AAR-95 SLr=Voltage 70S Sys= ND85US
Sa~ple 1 InjectLon 1 Group 4 ftass 441.7428
Text=TLI ft23 BLANK TLil31982A
I 00
60 t,,.A,.J\,,,NII\.NI\J.."-"'l"""""~~lh,..ll~.,Jl.(l,l''f/" .......... .,.,,..,l\,)t,~ I 40
I 20
1
0---~---------------------~ I 35=50 36: 40 37: 30 38=20 39: 10 40: 00
S951719 28-ftAR-95 SLr:Voltage 70S Sys: NDBSUS
SaAple 1 lnjectLon 1 Group 4 ftass 443.7399 I Text : TL! ft23 BLANK TL! 131982A
I 10
80
I se
I 40
20
40:50 41=40 42:30 43:20
NorR' 10
le-.-,--~-----.~---.--~~~~-,-.---r-~~
35=50 36=40 37=30 38=20 39=10 42=30 43=20 I S951719 20-ftAR-95 SLr:Voltage 70S Sys= ND85US
SaRple.1 lnjectLon I Group 4 ftass 513.6775 I Text:TLI A23 BLANK TLil31982A
18 NorR= 9
I ae
llv'-I\.M,~'l"'-,~~~...-M-~...._.,..,...vi,~....,Jv--..,~/\J/'o,,..),,l,J\,AJ\/j,,v,,...Jt.N~·1w~"'1,i.11'M-I 60
40
I 20
I 0 -',----,------,r------.-----r---....------,,------.------r----r-35, 59 37,39 38:20 39: 10 40=00 40=50 41 =40 42:30 43:20
I
I
S951719 28-"AR-95 Si.r=Voltage 70S Sys= NOB5US
-SaRple 1 In jecti.on 1 Group 4 _ ~ass 423 .7766 -,. I
Text=TLI "23 BLANK TLl131982A
10 NorR= 14 I
I
0 I 35=50 36=40 37=30 38=20 39: 10 40=00 40=50 41=40 42=30 43:20
S951719 28-"AR-95 Si.r=Voltage 70S Sys= NOBSUS I SaRple 1 Injecti.on 1 Group 4 "ass 425.7737
Text=TLI ft23 BLANK TLil31982A
10 NorR= 14 I
I
0 I
35=50 36=40 37=30 38=20 39= 10 40=00 40=50 41=40 42=30 43=20
S951719 28-ftAR-95 Si.r=Voltage 705 Sys= NOB5US I SaRple 1 Injecti.on 1 Group 4 "ass 435.8169
Text=TLI "23 BLANK TLil31982A I 10 Nor~= 1834
I
0 I
35=50 36=40 37=30 38=20 39= 10 40=00 40=50 41 =40 42=30 43=20 I S951719 28-"AR-95 Si.r=Voltage 70S Sys= NO85US
Sa~ple 1 lnjecti.on I Group 4 "ass 437.8140
Text=TLI "23 BLANK TLil31982A I
10 Nor•= 1808 I
I
0
35=50 36=40 37=30 38=20 39= 10 40=00 40=50 41 =40 42=30 43:20 I
--
42 I
I
I
S951719 28-ftAR-95 SLr:Uoltage 70S Sys: HOB5US
SaRple 1 InjectLon 1 Group 4 ftass 407.7818
Text:TLI ft23 BLANK TLll31982A
I 101 A . HorR: 28
I '~ : : ~ • '.' :· ·: • ~----~:----:-------· "------, ............ : 4
............... 1
35:50 36 :40 37:30 38:20 39~ 10 40:00 40:58 41 :48 42:30 43:28
I S951719 28-ftAR-95 SLr:Uoltage ,05 Sys: HOB5US
SaRple I InjectLon 1 Group 4 ftass 409.,,89
Text:TLI ft23 BLANK TLil31982A
: '}=~~: " :--: :::'." ' : · : "' . : Hor•= 15
• ~ ~ j
..,.J.
·: I I
I 35:50 36=40 3]:30 38=20 39=10 40=00
S951719 28-AAR-95 SLr=Uoltage ,es Sys: HOB5US
40=50 41: 40 42=30 43:20
Sa~ple I InjectLon I Group 4 ffass 417.8253 I Text=TLI "23 BLANK TLil31982A
I] A
I ' ! ' ' ' ' ' 35=50 36=40 37=30 38=20 39=10 40=00
HorR: 1679
I I 41=40 42=30 I
43=20
S951719 28-"AR-95 SLr=Uoltage 70S Sys= HOBSUS
I · SaRple I . InjectLon 1 Group 4 Kass 419.8220
Text=TLI fl23 BLANK TLil31982A
I
I ]
I ~ I I A I I I I I
3622
I I 35=50 36:40 37=30 38:20 39= 10 40=00 40=50 41=40 I S951719 28-ftAR-95 SLr:Uoltage ,es Sys= HDB5US
SaRple I InjectLon 1 Group 4 Kass 479.7165 I Text=TLI ft23 BLANK TLil31982A
I ':t=· ,-~~-.
I 35,se 36=40 37=30
I 41
S951719 28-ftAR-95 SLr=Voltage 70S Sys= NO85US
Sa•ple I Injechon I Group 3 _ ~ass,389.8156
Text=TLI "23 BLANK TLI131982A .
10 Nor•= 22
32=00 32=29 32=49 33=99 33=29 33=49 34=99 34=29 34=49 35=00 35=29
S951719 28-"AR-95 SLr=Voltage 705 Sys= NOB5US
Sa•ple I InjectLon 1 Group 3 "ass 391.8127
Text=TLI "23 BLANK TLil31982A
19 Nor•= 13
0..__---,-~-.--~-,-----,----.-~---,-~.--~-,-----,----.-~---,--
32=00 32=29 32=40 33=00 33=20 33=40 34=00 34=20 34=40 35=00 35=20
S951719 28-ftAR-95 SLr=Voltage 705 Sys: NOB5US
Sa•ple 1 InjectLon 1 Group 3 "ass 401.8558
Text=TLI ft23 BLANK TLll31982A
19 4508
0 ..L..---.------.------....---....... ---,-L.~=!.,........::::;:o:...,..._,__;.__,.____,_,_ R=~ R=~. 32=40 33=00 33=20 TI=ffl ~=00 34=20 34=40 ~=80 ~:20
S951719 28-ftAR-95 5Lr:Uoltage 70S Sys: HOB5US
Saaple I lnjectLon I Group 3 ftass 403.8529
Text:TLI "23 BLANK TLil31982A
10 3]21
0 .L..----,.---.-,--..--.....--.---,--.---,-----.-~~,....,,~,,,.._ ...... _ __,,.. _ _,_,_
32:00 32,20 32:40 33:00 33:20 33:40 34,00 34=20 34:40 35=00 35,20
40
r
I
I
I
I
I
r
I
I
'
S951719 28-ftAR-95 5Lr:Uoltage 70S Sys: NDB5US
Sanple 1 InjectLon 1 Group 3 ftass 373.8208 ·
Text: TLI ft23 BLANK TLil31982A -.
I '~~ A ·• '"" 21 I e ~ -~
32,00 32,20 32,40 33,0e 33,20 33,40 34,0e 34,20 34,40 35,00 35,20 I S951719 28-ftRR-95 SLr:Uoltage 70S Sys: NDB5US
Sanple 1 InjectLon 1 Group 3 ftass 375.8178 I Text:TLI A23 BLANK TLI131982A
I 10
0
~, ___ ...,_ Nor•' 22
I-' -~ --: :~' ~--, -·:-·:-----· :-:-:~:-:-I 32,00 32,20 32,40 33,ee . 33,20 33,40 34,00 34,20 34,40 35,00 35,20
S951719 28-ftRR-95 SLr:Uoltage 70S Sys: ND85US
Sa~ple 1 InjectLon 1 Group 3 ftass 383.8639
Text:TLI A23 BLANK TLil31982A
] A.
Norn: 4667
Ni f\ I I I • I I I I I 32,00 32,20 32:40 33:88 33:28 33:48 34,00 34,20 34,49 35,00 35,20
5951719 28-ftRR-95 SLr:Voltage 705 Sys: NDB5US
Sa•ple 1 InjectLon 1 Group 3 ftass 385.8610
Text,fll ft23 BLANK TLil31982A
:] A
Norn: 9031
M. ~ I I I I I I I • I I 32:00 32,20 32:40 33:00 33:20 33:40 34,00 34,20 34,40 35,00 35,20
I 5951719 28-ftAR-95 Si.r:Voltage 70S Sys: HD85US
Sanple 1 InjectLon 1 Group 3 ftass 445 .7555
I
Text:TLI N23 BLANK TLil31982A
".1
H rn' 8
I
I
I I I I I I I I I I I 32,00 32,20 32:40 33:00 33:20 33:40 34,00 34,20 34,49 35:00 35,20
I
. -s.--
33
S951719 28-ftAR-95 Si.r=Uoltage 70S Sys= NDB5US I
SaRple I Injecti.on I Group 2 ftass 355.8546 I Text:TLI ft23 BLANK TLil31982A
10 NorR' 15 I
I
0 I 22,00 23=00 24=00 25:00 26:00 27:00 28:00 29=00 30:00 31 :00
S951719 28-ftAR-95 Si.r:Uoltage 70S Sys: NDB5US
SaRple I Injecti.on I Group 2 ftass 357.8516 I Text=TLI ft23 BLANK TLil31982A
10 Nor~= 13 I
I
0 I 22,00 23=80 24=00 25=00 26=00 27=00 28=00 29=00 30=00 31 = 00
S951719 28-ftAR-95 Si.r=Uoltage 78S Sys= ND85US I Sa•ple I Injecti.on I Group 2 ftass 367.8949
Text=TLI ft23 BLANK TLil31982A
10 NorR= 3343 I
I
0 I
22=00 23=00 24=00 25=00 26=00 27=00 · 28=00 29=00 30=00 31=00 I S951719 28-ftAR-95 Si.r=Uoltage 70S Sys= NDBSUS
SaRple 1 In jecti.on I Group 2 ftass 369.8919
Text=TLI ft23 BLANK TLil31982A I
10 NorR= 2031
I
I
8
22=00 23=00 24=00 25=00 26=00 27=00 28=00 29=00 30:00 31 :00 I
. -38 I
I
I
S951719 28-KAR-95 SLr=Voltage 70S Sys= NOB5US
SaRple 1 InjectLon 1 Group 2 Kass 339.8597
Text= TL! K23 BLANK TU 131982A -.
: ]l::==:::;::, :::::;::=;:::, =:::;:, ==:;::, =:::;:, ==::::::;:::, :::::::;::::: ... ::;:, =~k-b~~N~orR::::' ~:;::, ::::::;:::66
22=88 23=88 24=88 25=88 26=88 27=88 28=88 29=88 38=08 31=88
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
S951719 28-KAR-95 SLr=Voltage 70S Sys: NOB5US
SaRple 1 InjectLon 1 Group 2 Kass 341.8567
Text=TLI ft23 BLANK TLil31982A
]-i-----... ---~~ --~ .... -~ _____ ,,.J.. ____ k1 . 3'
i I I I I I I I I I 22=88 23:88 24=88 25=80 26=00 27=08 28=08 29=88 30=00 31=80
S951719 28-KAR-95 SLr=Voltage 70S Sys= NOBSUS
Sa~ple 1 InjectLon 1 Group 2 Kass 351.9000
Text=TLI "23 BLANK TLil31982A
10
0
~•-----.-....-~---,.....,...,_-__,...__, _____ ...c.L.l_.-f....l,,No .... r~_=.L,)=..-..,._54 ...... 01 i I I I e I I i I 6~ ~ l l1= I
22=00 23:00 24=00 25=00 26=00 27=00 28=00 29=00 30=00 31=00
S951719 28-ftAR-95 5Lr=Voltage 705 Sys= NOB5US
Sa~ple 1 Injectton 1 Group 2 Kass 353.8970
Text=TLI ft23 BLANK TLil31982A
1~..L..--,--,--,--,--,--,--,-"""6.w.~-Ll,r_~•-' tw.·-· -,-363-8
22=00 23=00 24=00 25=00 26=00 27=00 28=00 29=00 30=00 31=00
S951719 28-ftAR-95 SLr=Voltage 70S Sys= NOBSUS
Sa~ple I InjectLon I Group 2 ffass 409.7974
Text=TLI K23 BLANK TLil31982A
I 29=00 30=00 31 =00
37
S951719 2B-ftAR-95 Si.r=Voltage 78S Sys: NOB5US
SaRple I InjectLon I Group 2 _ ~ass 319.8965
Text=TLI ft23 BLANK. TLil31982A
:!:::::.,._---.-· ___.~_, ...... ~
25, 00 26, 00 21= 00 20, ee 2s, ee 30, 00 31, 00
S951719 28-ftAR-95 Si.r=Voltage 70S Sys= NDB5US
SaRple I Injecti.on I Group 2 ftass 321.8936
Text=TLI ft23 BLANK TLil31982A
] •' I •, • ::L::-'=~-----. __,._ .. ---•~ • " 1; •
22=00 23:00 24=00 25=00 26=00 2]:00 28=08 29=00 30=00 31=00
S951719 28-ftAR-95 Si.r=Uoltage 70S Sys= ND85US
SaRple 1 InjectLon 1 Group 2 ftass 327.884]
Text=TLI "23 BLANK TL!i31982A
] ~ HorR= 6406
I I I I I I I I I I 22=00 23:00 24=00 25=00 26=08 2]=00 28=00 29=00 30=80 31=00
S951119 28-ftAR-95 SLr=Voltage 70S Sys= NOBSUS
Sa•ple I Injechon I Group 2 ftass 331.9368
Text=TLI ft23 BLANK TLll31982A
] M
HorR= 4140
I I I . I I I I I I I 22=00 23:00 24=00 25=00 26=00 2]=00 28=00 29=00 30=00 31 =00
S951119 28-ftAR-95 Si.r=Voltage 70S Sys= NDB5US
Sa•ple 1 InjectLon I Group 2 ftass 333.9338
Text=TLI ft23 BLANK TLil31982A
]
I I I I I M I I I
HorR= 5233
I I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
22=00 23=00 24=00 25=00 26=00 2]=00 28=00 29=00 30=00 31=00 I
36 I
·I
5951719 28-ftAR-95 SLr=Voltage 70S Sys: NDB5US
I SaRple I InjectLon I Group 2 ftass 303.9016
Text:TLI ft23.BLANK TU 131982A ..
I 10 Nor•' 526
I 0
22,00 23:08 24=88 25=88 26:88 27=88 28=88 29=88 38=88 31 ,ee
I S951719 28-ftRR-95 SLr:Uoltage 70S Sys: NDB5US
Sa~ple I InjectLon I Group 2 ftass 305.8987
I Text=TLI ff23 BLANK TLil31982A
10 Hor•= 281
I 0
I 22=88 23:88 24:08 25:88 26:80 27:80 28:88 29:08 30:88 31,00
S951719 28·"AR-95 SLr=Voltage 70S Sys: NDB5US
I Sa•ple 1 InjectLon 1 Group 2 nass 315.9419
Text:TLI ft23 BLANK TLI131982A
110 Nor•= 4533
I 0
22,00 23:00 24:00 25=00 2s,00 27=00 28=00 29:00 30,00 31,00
S951719 2B-ffARc95 SLr:Uoltage 70S Sys: ND85US I SaRple 1 lnjectLon I Group 2 ftass 317.9389
Text=TLI ft23 BLANK TLil31982A
I 10 Nor•' 5767
I 0
22,00 23:00 24:00 25=00 26=00 27:00 28:00 29=00 30=00 31 =00 I S951719 2B·"AR·95 SLr = Voltage 70S Sys= NDBSUS
Sa•ple I 1njecti.on I Group 2 ffass 375.8364
I Text,fLI ft23 BLANK TLil31982R
1] ~:-·:~ .. : ·~=· : : .. ·.··:~
I I 22,00 23:00 24:00 25:00 26=00 27=00 28=00 29=00 30=00 31 ,00
I .
35
S9jlt!9 28-R-95 12•44 78S CE!+) &ls•lmilS
Ii! 4 r, 425,1137 G: 41,9729 H: ~.8169 J: 437,8140 J: 442.9728
Text.:'lll '23 Ml( Tlll3100c!!
100 J S ,11,64
0~~-~--...,__.., __ ......,._
100 J S1 111 ,64
0......,_,,..::,......,.. __ ...,_~----
1001 J SI 111 164
50
e.._ __ ....,.. ___ ~----
100.00
3187
1679
100.00
3187
1834
100.00
3187
1554
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
·.:::---
34 I
I sr,j!719 28-R~ 12,44 i'8S (El•) &Js:tl15JS
I Iii 3 f: 391.8127 G: 392.9i'68 H: 401.~ J: 403.8529 J: 4ll,9i29
Text:lll 1'23 llflt: llll31!1!211 _ .
I
I ~
I
e.__ _____ .:,;,......w::-""""-l:---1 li!RJ Sl,Il,63
I 59
I
I 0~---"""""'""--...~~--32,00 32:l! 33,09 33:l! 34:00 34:l! :Ji:00 36:lj
I
I
I
I
I
I
I
I
I
I
11.00
1909
466i
111.00
1909
4508
-
33
5931!19 28-111!~ 12=44 78S CEI+) &is=tmilS
Ii 2 F= 319,8$5 G= il.mi H= £1,0047 I= 3l!,9m J: 331,m
Text=TLI El llJN( TLil31982fl
100 I 51 ,Il ,G2
50
8.._.,._,."""""""'"""""""""""'~----.....,.--100 I 51, 1,62
50
8.._.,._,. ___ ....;.l.l ____ __,_ __
109 I S1, 1,62 50 ____ ,___ .......... _..,II
0~ ....... --,_,,,_ ____ ..,t,1,1,,~~-
~f ::: : ' : ·:· : : : . ~ t·
22=00 24=09 26=09 28:09 ~•09
100.00
9198
4533
100,00
9198
4140
100,09
9198
5401
100,00
9198
3343
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
) I
I
32 I
· L1719 28-R-!i 12=44 i0S (El•) 9,js:tmJJS ~ 4 F= 425,mi G= 43:1.9729 H= 4li,8169 J: 437,8148 J: 442,9728 'ext =lll '23 llfl« lllt31982A •~1~;=-: 11~~---:= I ~t::;: :~•~:; 1108~64 I t ~ I ~i?:::~: :~ :::;: ::::::::: 100~~ ~~1!) 164 I 50 . 0 I "'"""'lJ-,00 -37,ee~i-,00-39~,00 --10,00-4~1,00 -42,-00 ~43,00 I I I I I I I I I I 100,00 1900 24,8007 100,00 1900 21,5]88 100,00 3187 19,5588 100,00 3187 13.~ 31
~lil9 28-R~ 12=44 i0S CEI•) ~=IOlrul
ll 2 f: 319,8$5 G= 321,SSll H= 32i.~i I= 3J,9i92 J: 331,9368
Text =llI 1'2311.ftt: 1lll31982A
108
50
0~~-=~~~-..,..-"""""""' __ 108 I SI , I ,IM!
50 ~--_......,~ .....
0 \
108 I SI , I ,IM!
50
03:::::~=:::=::=;:::;:::::::='.':::;::::::..'.~;:::::=
'~r§~:~:-·:,_::::~
22,00 24,00 · 26=08 20,00 30,00
100,00
9198
526
100.00
9198
18.~
100.00
9198
· 66,3257
100,00
9198
15,0764
I
' -I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
30 I
I 5!61719 28-R-i:i 12, 44 70S (EI•) Sqs' lfflJS
I Iii 4 r, 4a;m7 G• 4l!.9729 H• ~.8169 I• 437,8148 J, 442,9728
Text, llI ~ lfH( TLI 131932A _ .
I 108 I S1,Il,G2
._..._,__... ___ .....-J.___._At,.,.....,11
I 59
0~------------1 1001 .. s,1~~!A....._ .. __ i--'"•~•""w~ ~ -~
I se
0~------------1 1000 J Sl,11,64
I 59
I e
I
I
I
I
I
I
I
I
I
I
36•00 37,09 J:00 39,00 48:00 41 :89 42,00 43,09
100,00
9198
100.00
1900
100.00
3187
29
5951719 28-FIR~ 12,44 70S CEI•) SIJs:tmiS
Ii! 2 t' 319,8965 G: ii.~ H: ~.8847 r, n!,9792 J: 331,9ll8
Text.,n.I IEl II.II« n.Il3198cA
100~ J 51 ,II ,ii!
I.
80.
i'll.
60.
50.
48.
30.
20. 1J I , , .... ,
10.
0 . .
22,00 24,00 26:00 28:00 ~:00
100,00
4148
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
2a I
I Page No. 4 Listing of S951719B.dbf
03/28/95 Matched GC Peaks I Ratio / Ret. Time
I Compound/ Match Match Who/ ID
M_Z .... Omit Ratio ..RT. Total. Pe'a~.Area .. Rat RT. Rel.RT Why Identification .. Code
I 0.51 39,32 22 .so F F 1.061 FR
0.91 39,46 45.34 T F 1. 067
0.99 40,33 27.99 T F 1.088
1. 01 40,50 1,309.01 T F 1. 096
436-438 Peaks 8 14,783.98 ••• Total ••• I OCDD 0 40,40-41,00
458-460 0.82 40,50 162.42 T 1. 000 OCDD AN
458-460 Peaks 1 162.42 ••• Total ••• I 13Cl2-0CDD 40,39-40,59
470-472 0.86 40,49 14,983.97 T T 1. 000 l3Cl2-0CDD IS8
I DN 0.67 41,24 19.95 F F 1. 014 WI!
Column ... Description ............ "Why" Code Description
I M_Z -Nominal Ion Mass(es) WL -Below Retention Time Window
RT. -Retention Time WI! -Above Retention Time Window
Match Rat -Ratio Match True/False SN -Below Signal to Noise Level
Match RT -Time Match True/False <M -Below Method Detection Limit I Rel RT -Relative Retention Ti.me FR -Cale based on theoretical ratio
I *** End of Report***
I
I
I
I
I
I
I
I
I Triangle Laboratories, Inc.
I
801 Capttola Drive • Durham, North Carolina 27713
Phone: [phone] • Fax: [phone]
Printed: 14:10 03/28/95
Page No. 3 Listing of S951719B.dbf I 03/28/95 Matched GC Peaks / Ratio / Ret. Time
Compound/ Match Match Who/ ID I M_Z •••• Omit Ratio . .RT. Total.Pe"a~.Area .. Rat RT. Rel.RT Why Identification .. Code
c) ( 0.97 33,22 32.74 p T 1.oooJSF~ 123678-HxCDF AN
_.1.36 33,52 99. 77 T ~ 1. 015 234678-HxCDF AN I 374-376 Peaks 4 269.14 *** Tota ***
13C12-HxCDF 33,06-34,47
384-386 DC 0.49 32,16 118. 55 T F 0.967 WL I 0.51 33,16 25,476.93 T T 0.997 13Cl2-HxCDF 478 SUR3
-0.51 33,22 28,845.53 T T 1. 000 13Cl2-HxCDF 678 IS4
_0.52 33,51 41,699.90 T T 1. 014 13Cl2-HxCDF 234 ALT2
_o.s1 34,36 22,834.97 T T 1. 037 13Cl2cHxCDF 789 ALTl I 384-386 Peaks 4 118,857.33 *** Total***
HxCDD 32,38-34,30
390-392 -2.13 33,15 28.86 F p 0. 977 FR I ......-ON 3. 62 33,22 14.62 p p 0.980 PR
--1.06 33,27 27.82 T p 0.982 ----3.31 33,51 20.64 F p 0.994 FR
DC 1.42 34,04 16.29 T. T 1. 000 SN 1.--' I 390-392 Peaks 2 56.68 ***Total***
13Cl2-HxCDD 33:00-35:00
402-404 1.23 33:27 484.49 T F 0.982 I -1.21 33,58 17,153.07 T T 0.998 13C12-HxCDD 478 SUR4 ---1. 22 34,03 18,537.90 T T 1. 000 13Cl2-HxCDD 678 IS5
....--1. 22 34,21 27,178.35 T T 1. 009 13Cl2-HxCDD 789 RS2
402-404 Peaks 4 63,353.81 *** Total*** I HpCDF 36,05-37,56
408-410 -1. 23 36,15 59.43 F @ 1. ODO FR 1234678-HpCDF AN L ~ J) L I
DC 1. 65 40,50 57.74 F F 1.127 WH I 408-410 Peaks 1 59.43 *** Total"**
13Cl2-HpCDF 36,05-37,56
418-420 ~ 0.45 36,14 18,084.37 T T 1. 000 13Cl2-HpCDF 678 IS6 I 0.44 36,32 283.38 T F 1.008
....-0. 45 37:45 12,484.98 .T T 1.042 13C12-HpCDF 789 SUR5
DC 0.32 38,24 3~--35 F F 1.060 WH
DC 1.02 42,58 79.37 F F 1.186 WH I 418-420 Peaks 3 30,852.73 *** Total """
HpCDD 36,22-37,27
424-426 1.06 36,32 28.83 T F 0.980 1)J ---0.66 37, 16 21.93 F GJ 1. 000 FR 1234678-HpCDD AN c,
424-426 Peaks 2 50.76 ••• Total***
13Cl2-HpCDD 37,07-41,00 I 436-438 DC 0.33 36,03 31.24 F F. 0.967 WL
DC 0.84 36,31 31. 71 F F 0.980 WL.
._-1. 03 37,16 13,305.09 T T 1.000 13C12-HpCDD 678 IS7
2.53 37,40 27.05 F F 1.011 FR I 0.51 37,47 21. 91 F F 1.014 FR
0.80 38 ,21 25.09 F F 1.029 FR
I
I
Triangle Laboratories, Inc. I 801 Capttola Drive • Durham, North Carolina 27713 Printed: 14:10 03/28/95
Phone: [phone] • Fax: [phone]
26 I
I Page No. 2 Listing of S951719B.dbf
03/28/95 Matched GC Peaks I Ratio / Ret. Time
I Compound/ Match Match Who/ ID
M_Z .... Omit Ratio .. RT. Total.Pea~.Area .. Rat RT. Rel.RT Why Identification .. Code
37Cl-TCDD 23,27-30,02 I 328 0.00 24,52 49.69 T F 0.946
--a.oo 26,19 25,839.48 T T 1.001 37Cl-TCDD stlRl
0.00 26,46 105.55 T F 1.018
328 Peaks 3 25,994.72 ••• Total'*** I 13Cl2-TCDO 24,16-28,16
332-334 0.82 25,03 146.07 T F 0.952 -0.80 26,07 40,240.74 T T 0.993 13C12-1234-TCDD RSl I __..o.81 26:18 28,912.84 T T 1.000 13C12-2378-TCDD ISl
0.99 26 J 9 503.20 F F 1.013 FR
DC 0.86 30:49 603.30 T F 1.172 WH
332-334 Peaks 4 69,802.85 ***Total***
I PeCDF 27,29-31,36
340-342 -1.54 27,38 30.84 T F 0.931
-1.72 28,49 346.61 T F 0.971
I .-1. 34 28,59 67.46 T F 0.976
...-_o. 77 29,19 22.92 F F 0.988 FR (;) c 1.94 29,24 29.89 F F 0.990J Fil-) ,.J
..--0 1.22 29,38 20.02 F F 0.998 FR
I s~ -1.63 29:42 59.87 T cv 1.001 12378-PeCDF AN
[) C: 1.18 29,53 26.95 F F 1. 001] -?R _S' .,J
...-, 1.49 29,59 81. 71 T F 1. 010 &.,
I > ....... ___..J,.-.-&1 30,26 I 7Q. ' ( l6G.dd ,·-r (!) 1. 025 1"1t" 23478-PeCDF AN < --; 'J \..-
I __...,..1. 23 30,36 87.77 F F 1.031 FR
340-342 Peaks 10 920.68 ***Total***
l3C12-PeCDF -29,32-30,36
I 352-354 DC 12 .13 24:49 222.07 F F a. 836 WL
DC 1. 61 27,37 101.91 T F 0.930 WL
DC 1.59 28,48 2,521.47 T F 0.970 WL
DC 1.50 28,59 15,852.52 T F a. 976 WL
I DC 1. 77 29,12 558.57 T F 0.984 WL
DC 1. 69 29,24 213. 03 T F 0.990 WL
-1.55 29:41 27,639.12 T T 1. 000 13C12-PeCDF 123 IS2
1. 59 29,59 957.42 T F 1. 010
I -1.51 30,26 35,507.88 T T 1.025 13C12-PeCDF 234 SOR2
DC 1.53 31:25 90.36 T F 1.058 WH
352-354 Peaks 3 64,104.42 ••• Total***
I 13C12-PeCDD 30,38-31,06
368-370 DC 1.45 29,59 99.57 T F 0.973 WL, -1.62 30,49 21,766.20 T T 1.000 13Cl2-PeCDD 123 IS3
1.65 30,56 1,991.61 T F 1.004
I DC 1. 31 31,16 104.63 F F 1. 015 WH
368-370 Peaks 2 23,757.81 ••• Total***
HxCDF 32,08-34,52
I 374-376 DC 1.19 32,18 13 .41 T F 0.968 SN
-0.98 32,26 68. 22 . F F 0.972 FR
--1.20 33,16 68.41 T (fJ 0.997 123478-HxCDF AN
I
I
I Triangle Laboratories, Inc.
801 Capttola Drive • Durham, North Carolina 27713 Printed: 14:10 03/28/95
I Phone: [phone] • Fax: [phone]
25
Initial .... Date ...
B-File/Header Changes SN ~I Jd:1.:!.r Calculated Noise Area: 13 ·Cl
=t _·,i-. :;,..,., N() <DC Manual Integrations Channel: N ,-i r<. (' I vj.....
Transcription _/ I_ Initials: ~
dBASE Corrections _l'-2,,I_ Date:
C ':. I ~ ~ v-
Page No. l Listing of S951719B.dbf
03/28/95 Matched GC Peaks I Ratio / Ret. Time
Compound/ Match Match Who/ ID
M_Z .... Omit Ratio .. RT. Total. Peak.Area .. Rat RT. Rel.RT Why Identification .. Code
TCDF
304-306 DC 1. 90 21'12 2,039.80 ---0.79 22: 41 44.57 --1.10 23,22 103.38
--0.81 23,43 202. 98
_0.72 24,09 306.24
.--0. 80 24,27 158.35
sr-l -0.27 24,47 48.68
-0.81 25,07 255.99
-0.12 25,21 84.74
_...,0,76 25,33 708.76
.-0. 78 26,01 236.31
.D c o.59 26,15 54.32
DC 1.07 30,49 33.50
304-306 Peaks 11 2,204.32
13Cl2-TCDF
316-318 DC 0.82 23,20 1,398.74
DC 0. 72 23,36 334.25
DC 0.97 24,06 92.18
DC 0.67 24,24 842.64
DC 0.86 24:44 136.80
DC 0.74 25,06 567.82
--0.79 25,32 45,305.27
DC 1.03 26,00 443.51
DC 0.67 27,22 97.16
DC 0. 72 28,59 354.86
DC 0.72 29,42 659.08
DC 0.76 30,26 853.85
316-318 Peaks 1 45,305.27
TCDD
320-322 DN 0.49 23,35 20. 63
DC 0.53 28,59 35.84
i-l"' y<--
DC 0.43 29,41 47.54
DC 0.76 30,26 96.00
320-322 Peaks 0 0.00
Triangle Laboratories, Inc,
801 Capttola Drive• Durham, North Carolina 27713
Phone: [phone] • Fax: [phone]
21,58;-27,35
p F 0.830 WL
T F 0.888
F F 0.915 PR
T F 0.929
T F 0.946
T F 0.958
F F 0.971 FR
T F 0.984
T F 0.993
T (£i 1. 001 2378-TCDF AN T. F 1.019
F F 1.028.) l'R .} c-l
F F 1.207 WH ... Total • ••
25,23-25,43
T F 0.914 WL
T F 0.924 .WL
F F 0.944 WL
T F 0.956 WL
T F 0.969 WL
T F 0.983 WL
T T 1.000 13Cl2-2378-TCDF ISO
F F 1.018 WH
T p 1.072 WH
T F 1.135 WH
T F 1.163 WH
T F 1.192 WH ... Total •••
23,27-27,33
F F 0.897 FR
F F 1.102 WH
F F 1.129 WH
T F 1.157 WH ••• Total •••
Printed: 14:10 03/28/95
24
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I TL-RTP Project: 31982A
Client Sample: TLI M23 Blank
I
I "C12-2,3,7,8-TCDF
"Ci,-2,3,7,8-TCDD I "C12-l,2,3,7,8-PeCDF 13Ci2-l,2,3, 7,8-PeCDD
13C12-l,2,3,6, 7,8-1-faCDF
I 1'Ci2-1,2,3,6,7,8-HxCDD
"Ci,-1,2,3,4,6, 7,8-HpCDF
13C12-1,2.3,4,6,7,8-HpCDD I 1'Ci,-l,2.3,4,6, 7 ,8,9-OCDD
2.5
2.5
2.5
3.2
3.0
2.7
2.7
2.6
4.2
I §¥rre~~t!§~n~rfi~R:fYll~11 Ii~m§;l<nili> · :
I
I
"CL.-2.3.7,8-TCDD
;,Ci,-2.3,4, 7 ,8-PeCDF
13C1,-l,2,3,4, 7,8-HxCDF
13C12-1,2,3,4, 7,8-HxCDD
13Ci 2-l,2.3,4, 7,8,9-HpCDF
I 13Ci2-1,2.3.7,8,9-HxCDF
13C12-2,3,4,6, 7 ,8-HxCDF
11;~~ssx~f¥§.!~e§E.~
13C12-l,2,3,4-TCDD I 13C12-1,2.3,7,8,9-HxCDD
I
I
I
3.7
4.7
3.7
4.0
3.8
3.0
4.5
62.8
62.1
61.7
79.3
75.9
67.7
68.0
65.7
53.1
93.5
118
91.4
101
94.2
73.8
113
Method 23 PCDD/PCDF Analysis {a)
Analysis File: S951719
0.79
0.81
1.55
1.62
0.51
1.22
0.45
1.03
0.86
1.51
0.51
1.21
0.45
25:32
26:18
29:41
30:49
33:22
34:03
36:14
37: 16
40:49
26:19
30:26
33: 16
33:58
37:45
0.51 34:36
0.52 33:51
0.80
1.22
26:07
3421
I Data Reviewer: __ s_··---'A-'--· _p_ .. _-__ '---, _____ 03/28/95
I Triangle Laboratories of RTP, Inc.
801 Capitola Drive• Durham, North Carolina 27713 I Phone: [phone] • Fax: [phone].
Page 2 of2 X237_PSR v:1.07, LARS 5.1~.08
Printed: 16:57 03/28/95
·23
I
TL-RTP Project: 31982A
· Client Sample: TLI M23 Blank
Method 23 PCDD/PCDF Analysis {a) I
Analysis File: S951719
Client Project:
Sample Matrix:
TLRTPID:
Sample Size:
Dry Weight:
GC Column:
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1.2,3,6,7,8-HxCDD
1,2,3, 7 ,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8.9-OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4, 7,8-PeCDF
1,2,3,4, 7 ,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4.6,7,8-HxCDF
1,2,3,7.8,9-HxCDF
1,2,3,4.6,7,8-HpCDF
1,2,3,4.7,8,9-HpCDF
1,2,3,4,6, 7 ,8,9-OCDF
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
n/a
XAD
TU Blank
1.000
n/a
DB-5
Triangle Laboratories of RTP, Inc.
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor:
Blank File:
Analyst:
ND 0.004
ND 0.005
ND 0.008
ND 0.007
ND 0.007
EMPC
0.08
0.06
0.008
0.02
0.009
ND 0.004
0.01
ND 0.005
EMPC
ND 0.008
ND 0.02
I I
03/21/95
03/28/95
n/a
S951719
MM
0.007
0.008
ND 0.004
ND 0.005
0.006 1 0.02
0.009 I 0.02
0.18 8 0.19
0.09 6 0.11
0.02 2 0.03
EMPC 0.008
Page 1 of2
801 Capitola Drive• Durham, North Carolina 27713
Phone: [phone] • Fax: [phone]
Spike File:
ICAL:
CONCAL:
% Moisture:
% Lipid:
% Solids:
0.82
0.76
1.63
1.52
1.20
1.36
SPX23704
SF53254
S951718
n/a
n/a
n/a
40:50
25:33
29:42
30:26 ..
33: 16
33:52
X:37_PSR v:1.07. LARS S.l-1.08
Printed: 16:57 03/28/95
22
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
TRIANGLE LABORATORIES OF RTP, INC.
Sample Result Summary for Project 31982A
Method 23X (DB-225)
Page 1
03/28/95
--------------------------------.----===-------========---------------------------=== -
Data File
Sample ID
X950962
TLI M23 Blank
X950963
00136 S0-M23-R2
Units ng ng
Analytes
2378-TCDF 0.05 0.16
TOTAL TCDF 0.12 0.79
Internal Standards Percent Recovery Summary
13Cl2-2378-TCDF 66.7
Triangle Laboratories, Inc.
801 Capttola Drive • Durham, North Carolina 27713
Phone: [phone] • Fax: [phone]
53.9
B
(% Rec)
X950966
00145 BLANK
ng
0.04 B
0 .11
72.3
Printed: 17:23 03/28/95 21
TRIANGLE LABORATORIES OF RTP, INC.
Sample Result Summary for Project 31982A
Method 23X Full Screen Analyses· (DB-5)
Data File
Sample ID
S951719
TLI M23 Blank
S951721
00136 SO-M23-R2
Units
Analytes
2378-TCDD
12378-PeCDD
123478-HxCDD
123678-HxCDD
123789-HxCDD
1234678-HpCDD
OCDD
2378-TCDF
12378-PeCDF
23478-PeCDF
123478-HxCDF
123678-HxCDF
234678-HxCDF
123789-HxCDF
1234678-HpCDF
1234789-HpCDF
OCDF
TOTAL TCDD
TOTAL PeCDD
TOTAL HxCDD
TOTAL HpCDD
TOTAL TCDF
TOTAL PeCDF
TOTAL HxCDF
TOTAL HpCDF
ng
(0. 004)
( 0. 005)
(0.008)
(0.007)
(0.007)
(0.007)
0.08
0.06
0.008
0.02
0.009
(0.004)
0.01
( 0. 0 05)
(0.008)
(0. 008)
(0. 02)
(0.004)
( 0. 00 5)
0.006
0.009
0.18
0.09
0.02
(0 .008)
ng
(0.004)
(0.04)
0.22
0. 35
0.50
8.3
36.6
0.26 B
0.04 B
0 .11 B
0 .11 B
0.04
0.07 B
0.02
0.19
(0.007)
. 0 .19
0.01
0.23
3.9
17.7
0.82
0.88
0.59
0.34
Other Standards
37Cl-TCDD
13Cl2-PeCDF 234
13Cl2-HxCDF 478
13Cl2-HxCDD 4 78
13C12-HpCDF 789
Percent Recovery
93. 5
Summary(%
91. 0
103
88.7
110
Rec)
118
91. 4
101
94.2 91. 0
Other Standards
13Cl2-HxCDF 789
13Cl2-HxCDF 234
Percent Recovery
73.8
Summary (%
81. 0
117
Internal Standards
13Cl2-2378-TCDF
13Cl2-2378-TCDD
13C12-PeCDF 123
13C12-PeCDD 123
13C12-HxCDF 678
13Cl2-HxCDD 678
13C12-HpCDF 67 8
13Cl2-HpCDD 678
13Cl2-0CDD
113
Percent
62.8
62 .1
61. 7
79.3
75.9
67. 7
68.0
65.7
53 .1
Recovery Summary
76. 2
72.0
65.4
83.7
85.3
72.2
80.5
76. 9
64.0
Rec)
(% Rec)
S951720
00145 BLANK
ng
(0.004)
(0.007)
( 0. 009)
(0.008)
(0.009)
(0.01) B
0 .12 B
0. 05 B
{0.002}B
0. 02 B
0.006 B
(0.004)
0.01 B
(0.005)
{0.005}B
( 0. 008)
( 0. 02)
0.004
( 0. 007)
(0 .008)
(0.01)
0 .14
0.07
0.02
(0.005)
83 .1
98.7
91. 6
102
87.6
64.0
102
55.7
56.9
54.1
60.5
69.3
60.6
62.7
59.2
46.9
{Estimated Maximum Possible Concentration}, (Detection Limit).
Triangle Laboratories, Inc.
801 Capitola Drive• Durham, North Carolina 27713
Phone: [phone] • Fax: [phone]
Page 1
03/28/95
Printed: 16:58 03/28/95
20
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I :··
I TRIANGLE LABORATORIES OF RTP,. INC. -
I
I
I
I
I·
I
I
I
I
I
I
I
I
I
I
I
I
Rev. AH • 9/93
SAMPLE
DATA
19
:'ij\.;I .(., j ,Ii \r, ~~ t !:1 I;~ i 1 ,(1 ii) ' J '1,J Ii {! /i ,/:~: l i1~ :I !I ~t hl ![;'i l1'J .11-] . !:!1·'' !' ·,· i ",( . -:H . . ::·)i ·iii' \/ ~-··i ,; -1 : :/ 1 ... ,,, : :i:':i'Hi .. . ...... , .. VMH miii"i:-ciG-HS, COLUHN TYPE COLUMN II PLOT NAME PKO AHClJNT I NJ ACQUISISTION G/C Vt1 X £13 -;z;iC .30.,._~ o. zc,,,_ lf S't 3 .3 '-t :Z.. IV'iUPKf>/<. -~ 2. O_,,JL ).C.,.,..} _ -,-.,... DAIE IIHE 3/ ;z.1 / ,sr II·. ;1,1, ~,_+,~i-('L? if" I~ ;r.f,,r ,3 , J. I, 11~;21/,,.,-1 i<-l-: :LO 3/:z;,/1'>] 1'5 ·. O'l _;i),,1hl -1 .... 3/ZJJ~st t& ,:1.., ~,,, 115" I 1q :,;}(. ~IIPA:E I . co--PROJECT# SAMPLE# No I CLIENJ SAHPLE IO COHl<ENI S 332,'iOP INII 2-13} -I ~El'f&tlnorJ WINDOW (.IIE.LK., #--'\k"::,', CALU~~A:r, o ,J ·-'-· -----------. 1"/, I tlq~ -J....,11,A -.=A l,or,J LA<-<;. 0 l.w.'1 u.i--t~ e.2e~1 a}~ 1-?>7iA -r'e-rµ CL),-./<,AL 5. (J a;:,,'?) &,01,J j .. IJ::i"io) "IJ ,_ -~ No ,._,i;c:;, 1 ,.Gl~1,~ ..31 '10:lA -ru /il(.ANI: IO , ..,...u H'-:l' P.:>LAr-11<. ,., .... , ~ :31'10 ;tA l<t-1-,••-/A-pj I I 50-N2-, -~:2. 1.~e1I ~ ~I 'lf;M 1>-llo-Z<-yl Z-1 Bl-ANI<.. -1-t,j"c. -6~ L ..• ,) l...f~ I® .3 Me>;;l.,4 I q,.·ho-:u.A ;z I f3LA,.J~ -,-t<1 L {r.,._,i,. • ,.1e=1cL iJJ?.J.. .3 ,~ i.:lA 1,_ ,.,,_ ;,,.-g I 1.-I BlArJk. b. 6,l ""lt<b"'-'><!4£D '±0 I !i1dli 7 ~ \~:> I, .... ,. Q\.\y_ i I , ,._,,. \l.I'L.(. · c,..)(~~ 5',...,1c ~T::) 1::: I ~ -P I a I SYR I t-v l'vl t2R111<-hi-,_ 1-r.-.. G,~ 7I>n<A ht'\,I 6.o h,-1-., ~?>17 / --J~ 'f . .i'Jl1f X~1L 1--J-.., Y...3171 1v!::::P~111 t".,nt FILE # 'f,'1501 G1 }'iGoq~o f-.'I,; O•H I ./ X 'i'!', O.'l <. :z... _.,,, '/. 'iG"O'J ~3 / '/. qso "l~'f Y,'iSO",/., ~ '1 "i ,;;09 i."' ./ ')( Cj 5" 0'1 {g_ 7----------------... I
------------·----HUH LOG
HSI COLUl4N TYPE COLUl4N I PLOT NAHE PKO AHWNT INJ ACOUISISJION G/C
'?,:J.<f 'JSjl·S-/tJ ... I/. ?S/1"" ~ J'/ 'if J ;:r; j)tP/L 7 ~/)'_)! "},& ,Jil .,, ti/ //J1>%lt/·
DAIE IIHE PROJECII SAMPLE# No CLIENT SAHPLE ID Cc»<HENTS 332,' OP INIJ p Q SYR I FILE#
f-,rfo~ 6',CCf 51ft1r t9/;12. fP cfl!-H/LC tJ~' ' '·7/1/ 7fb :1 " t32t!!I· 19'S-J?l5 '
} d:-zJ '319ft -rt..:L I 1lit//tC J.Jqk-73/~ t270 p)> ~ I'<" 4 '!'?fl/ :f91,·171/
ot.A-vl-
1 oy((o -?-/33 -12 .. :1c:.Jlt < J 9b?. ~~ l.t-V f"9>lrl7
'
6 ..,..,p· I I,, T'e,i~
¾'¢i~ -.. :tSotrA 'i?7-"Ju If'<. z '> c..,_..) >": u .(,~ \-c) ~ ? v. 11i:;-" '1 'i -:SI ;7 I J"./ -lqr( )
01 :/I,,, Iv ' Si.
' V ·~ \,.,, 5\1~~-.,, '\(41) V _'\i<j!,·/1-IQ /
(\ I J' 44 ' ]\ ~'i<.;i.A-Tl-:1~1,J ¢ n .. , 1'4~3 s1.....J,. MIA.< ,; ., ~~:>-i":l.
I
~!r;).
,L ,1·~1 1~1'\'(;>A-fl--lW-.JA,' '.l (y')\ l(~ o, I .I. :3q1, . '"'""-" , ..... .t'1SI rJc:,, /
V I/ "
\' 1t11 "31qlCl. A 'l·t,o-11<-b I OD l.~ln ~-VIQ..'\ 343-l ~~ 1'-,._., 1. ~ iiJ .1i'l~I 'tJ. I /
11 / :5''.0~ ~ l'i 11 Q'l--11'.. ,<c,l-, :S' Ck·b< -OJ.-r>Ju cJJ.I 0)-'l 0""' jMIAA v {j;ii'J.. ::1'1 ~ I '1-J. . .)
w ,.,. : '5''1 ~ll\~\ ~:i-f'i ·£,1-l,, {., 1".A • l>S -n> -Cl.+O. f\O I o,P ,,,21 i"IM, \~:'J!ra. b"J'.'r 1 1 ,;i 3
' '
31ci11 ~1--i"t-11H 1-CA ·l)S-f.f')-¢21,1,¢2.1 Jtl2Z. i:sl.'il.. $'J ',1 I 2 '/
'
-.J
.,
I
PAGB l OP 1 •----------------------------------------------------:::~~:-~:;;;;.~:;:::-;~::----------------------------------------------------· I
Method: 23X TETRA-OCTA TOL. RINSB COMBINRD HR GC/HRMS ANALYSIS +---------.---------+
Required Detection Limit: 0.050 NG IPROJBCT: Jl982A I
1ST COLUMN 2ND COLUMN 20 µl e 100. o 'PG/µl
I +-----------------------------------------------------------------------------------------------------------------------------------+
•----------------------------------------------------------------------------------------------------------.-------------------------I
•-----------------------------------------------------------------------------------------------------------------------------------I
I
~ I +------------------------------------------------------------------------------------------------------------------------------------
------------------------------------------------------------------------------------------------------------------------------------• I
•--------------------------------------------------------------------------------------------------------;---------------------------I
I
+-----------------------------------------------------------------------------------------------------------------------------------+
I
I +-----------------------------------------------------------------------------------------------------------------------------------+
Type: A I
Spike File: SPX23704 I
Amt of Bxtract: SO\
·-----------------------------------------------------------------------------------------------------------Rl!V 03/07/9S (PSTMP <)--+ I
1s I
I
PAGE 1 OF 1 ----------------------------.------------------------------------------------T
TRIANGLE LABORATORIES, INC.
Transfer Chain-of-Custody Form
Project 31982-A
Transfer From: DWLHI
Initials ..
Released by: ..,II ,:::;
Accepted by:
To: DMSS
Date ...... .
..:!)_;2.5;q'5
_l;l--1 ;9("
Time ...
I . : ()o ----
!Q_,clL_
+------------------------------------------------------------------------------+
'
I
I
I
MILES. ID: . . . . . . . TLI No. . . . . . Cust. Id ................. .
31982-A
31982-A
31982-A
-000
-001
-002
TLI Blank
97-160-lA-DF
97-160-2A-DF
TLI M23 Blank
00136 S0-M23-R2
00145 BLANK
-------------------------------------------------------XfrCOC (Rev 11/01/94)--+
Additional comments or instructions:
· 15
PAGE 1 OF 1
II TRIANGLE LABORATORIES, INC. -1\
II SAMPLE EXTRAC'rION and CLEANUP TRACKING FORM II
II II
II TLI Project: 31982 A II
II II
li======;===,====,=========cCHROMATOGRAPHIC CLEANUP========sl
IIExt S#.crd !Spike IExtr. !Spike II Acid Big IEscltdl Acid I Flor-lcarbonlTrans-1 II
II and lbeforel !after II Base Fish ISilicalAlminal isil IColumnl fer I II
11 TLI Number IExtr. I IExtr. II I Gel I 6 gm I I z..---' I II
I I
I I
IIA 001 11-II II
1197-160-lA-DFI II II
I I
II I I II I I I I
II I I II I I I I 11------+--+---+----ll---+---+---+----+---+--+----+--
II II
II II 11-----+---+--+---ll---+----1----+---+---+--+---+----,
II I II
II I II
11-----+---+----,-+---ll---+----I----+---+---+--+---+----,
II I II
II I II
11-------+---+-----+----1.----+---+-----+---+---+----+---+-----<
II II
II II
11-------+---+-----+----!1-----+---+---+----l----+----+----I------<
II II
II II
I
I
. I
I 11-------+---+----+----!1-----+---+---+----l----+----+----I------,
II II
II II
1;====-=======-==:=!!c=='====ce==::!:c===c!:==!==:!c===!::==
:: @ Rotovap(40ml,(§)dryness) e0) @9;9
:: ~ent Exchang;::5 ~ Sox I
II "---= ~ II
l;============================I
II Comments II
II 11
II II
II II
II II
( PSTMF 4) --'I lk=======================Rev 08/09/94
14
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
+---------------------------------------------------------------------------------------------------.--------------------------------
1: .
I Project: Ji9B2A
TRIANGLB LABORAl'ORIBS, INC.
PCOO/PCOF/PBOD/-PBDF Sample Prep~tion Tracking & Management Poral
Client: BTS, INC. {BTS02)
PAGB 1 OP l
II I · I I I I I I I I I
I I I I I I I I I I I
+------+------------------------------+---------+---------+--------+-------------+-------------+-------------+-------------+---------
I I I I I I I I I I I II I I I I I I I . I I I
+------+------------------------------+---------+---------+--------+-------------+-------------+-------------+-------------+---------
1 I I I I I I I I I
II I I I I I I I I · I I
+------+------------------------------+---------+---------+--------+-------------+-------------+-------------+-------------+---------
1 I I I I I I I : I · .1. ·· I I I I · I I I I . ·· ·•1 ,. . . I . . I . I .
• +-.----+------------------------------+---------+---------+--------+-------------+-------------+-------------+ .------------:---------
1 I · I I I . I I I I I I
I I I I I I I I I I I
l +------+------------------------------+---------+---------+--------+-------------+-------------+-------------+-------------+---------
1 I I . I I I I I I I I
I I 1· I I I I I 1 · I I
+------+------------------------------+---------+---------+--------+-------------+-------------+-------------+-------------+--------• 11 Gross weight. of sample cont.ainer + sample before/after aliquot. removal I Indicat.e below the TLI Ident.ificat.ion Number .. I
I I of Che Sample ~ortification Solut.ions: I
I I USF·AIS, -------I
I I I g I
I COMMBNTS• I USP-I, ~3'il;A D1 L0tlr7'-usF-A,;l2,32A /)./u5jf,.I I
I ____________________ I Eif·•ll)o3/'{f UfJ·''/.:Ja-Jq51
I: ------------------------------: USP-ACS: USF-MX: I
I I 0S1?-C:________ Other:
I------------------------------+----------------------------------------------------------+
I:-----------Initial/Date __ _ _;_;_ I LOT # (Solvenes) ,_,/l\=t_Cf.c.z«<'--9r-J.-'i.1.._?..c.f_--z,,-_____ _
+------------------------------------------------------------------------+
I I INITIALS OP BOTH THB SPIKER AND OBSERVER MUST BB BN1'BRED, j for extraction:
! (XXXXX • Groos Weight not provided for WATBR Samples.) I
+-----------------------------------------•-----------------------------------------------------------------RBV 03/07/95 {PSTMF 7)--+
I 13
oate1 03/24/95
time: 11:0l
Sample
' crd TLI_Number ..
ooo TLI Blank
001 97-160-lABC&.
002 97-160-2A-CE
customer.Sample.Id .......
TLI M23 Blank
00136 so-M23-R2
00145 BLANK
... End of Report ...
1--4
l'v
--

-
--
F. XJ\D
No Color .. · ...
0 WHITE
l WHITE
·l WHITE
-

-
TRIANGLE LABORATORIES, INC.
Wet Lab MM5/PUF Observations
Project: 31982-B
Filter Glass Wool PUF
Color ..... Color ..... Color ..... Odor .......
NONE NONE NA NONE
BEIGE NONE NA NONE
WHITE NONE NA NONE
-

-

-
--
Entered.By ...... Date ....
WHEELER 03/24/95"
WHEELER 03/24/95
WHEELER 03/24/95
-

-

-
PRDPERC v13.07
Page1 1
Time .... s
10:56:13 •
10:56:13 •
10:56:13 •
---
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
TRIANGLE LABORATORIES, INC.
SAMPLE TRACKING AND PROJECT MANAGEMENT FORM
-------------------------ADMINISTRATIVE INFORMATION-------------------------
TLI Proj#: 31982-A Samples: 2 TurnAround.: 8 Day(s) (~d...:J)
Prod Code: D23061 Matrix.: M23Train Hold Time .. : 14 Day(s) I )
DetectLim: 0. 050 NG Type ... : A Date Recvd.: 03/18/95(c.lc,c.l<-.sl-aJi> 3 l"I
Date Due ... : 03/26/95
Analyte List.: Tetra-octa
Method ....... :
Client Proj .. :
23X TETRA-OCTA TOL. RINSE COMBINED
Mcclaren-Hart
Client ....... : ETS, INC. (ETS02)
P.O. No ...... : Collect Date.: 03/17/95.
Contact ...... : TERRY WILLIAMSON Phone ........ : [phone]
Proj. Mgr .... : Hani Karam Sample Origin:
-------------------SPECIAL INSTRUCTIONS/ QA REQUIREMENTS-------------------
Prep Project: 01667 Prespike Standard: USF-S&C
Prespike Amount .. : 4.0ng
Extraction Exp ... : 03/31/95
---------------------------REPORTING REQUIREMENTS---------------------------
Reporting Format: Report Option II
See MILES for Instructions/Communications.
Completed by: DATE, 3 I "2----0 Is s--
Reviewed by: DATE, '3~k-7S°"(PMGT0395)
Triangle Laboratories, Inc.
I 801 Capitola Drive• Durham, North Carolina 27713
Phone: [phone] • Fax: (919)"544-5491
Printed: 13:36 03/20/95
11
I
PAGE 2 OL 2 •---------------------------------------------------.--------------•--------------------•-----------------------------------•------, I
Custody Seal Absent Sample Seals: Absent : Ill Project Nu1ber : 31982 Book
: ~::~~eo~a~~stody ; :;:::~: ;-~;;~~;;-;;;~;------;-;;;:-;~~:--------------------------; 97 : I
: Sample Tag Numbers: Listed +--------------------+-------------------;---\--~---+
;---:::-Forms _________ :_HIA __________ ~~-~~~~~~;--------------------:-~~;;;;;~~~~=~::~~;-;-;~~;~~~~;~~~:: /~":-:'..--; :::e I
+-----------------------------------+-----------+-----------+-----------+-----------+-----------+-----------+-----------+-----------+
: Ill Number Matrix : To LAB : To STORAGE: To LAB : To STORAGE: To L_AB : To STORAGE: To LAB : To STORAGE: I
J mR/H:CPM Client ID Location : Date/Init : Date/lnit : Date/Init : Date/Init : Oate/Init : Date/Init : Oate/Init : Oate/lnit :
+-----------------------------------+-----------+---------------------+-----------+-----------+-----------+-----------+-----------+
1:" "M" -.,., _ "":"""' _ "':: yr&ff Jrf --:------:-----:------1---:---------: •
97-160-2E IMP 2-4 I
+----------+----+-----------+-----------+-----------+-----------+-----------+-----------+ f'(.iYl.v_ , , I , , ,
00148 BLANK
CO2 7 )-zt_,..v I I I 1 I I
+-----------------------------------+------------+-----------+-----------+-----------+-----------+-----------+-----------+ I
' 97-160-ZF 00149 BLA~~LUEHE RI:::+----:---t---;-----------;-----------i-----------i-----------;-----------;-----------;
•-----------------------_-----------•-----------+-----------•-----------•-----------•-----------•-----------•-----------•-----------+ I
+-----------+-----------+-----------+-----------+-----------+-----------+-----------+-----------+
•-----------------------------------•-----------•-----------+-----------•-----------•-----------•-----------•--------_--•-----------• I
' ' ,.
'
.,
'
•-----------•-----------•-----------+-----------•-----------+-----_-----•-----------•-----------• I
+-----------------------------------+-----------+-----------+-----------+-----------+-----------+-----------+-----------+-----------+
+-----------•-----------+-----------•-----------•-----------•-----------•-----------1-----------+ I
+-----------------------------------+-----------+-----------+-----------+-----------+-----------+-----------+-----------+-----------+
' ' +-----------•-----------1-----------1-----------•-----------•-----------•-----------•-----------1 I
,. I
' ' •-----------------------------------•-----------•-----------+-----------•-----------•-----------•-----------•-----------•-----------• I ' ,.
I ' +-----------+-----------+-----------+-----------+-----------+-----------+-----------+-----------+
•----- - --- - - - - - - ---- - - - - - - - - - - - - ----•-- ------ - --•-- - - - ---- --•-- - --------•-- ---------1-- - - - - - - ---+--_-_ -------+-----------•-----------• I
' ' ' ' +-----------+-----------+-----------+-----------+-----------+-----------+-----------+-----------+
' '
~-----------------------------------+-----------+-----------+-----------~-----------+-----------+-----------+-----------+-----------t I
+-----------1--------.--+-----------+-----------+-----------+-----------1-----------+-----------1
i-----------------------------------+-----------+-----------+-· ---------+-----------+-----------+-----------+-----------+-----------+ I
Receiving Remarks: Client's Chain of Custody differs from what the Sample IDs read: used the !Os on sample to log in.
All client samole IDs preceded by '94-365-".
I
I PAGE I or : +------------------------. --------------------------_._ --------------+--------------------+------------------------------------+------+ I ! ~~::~d~/~~;tody : :~::~;t Sa1ole Seals: Absent ;_'.::_~~~i:::_~~~~:~_;_~'.:~: ______________________________ ; Book
Saaole Tags : Present : Client: ETS02 : ETS, INC. : 97 ,
: Samele Tag Numbers: Listed +--------------------+---------------------:;.:\-----~-----+ I ;_ --SMO _Forms-------_:_HI A--------------------------------------__ ;_ Oate _Received------;_ 03/ 18/95 __ ;_ By lu~ ___ ; Page ;
Box NO COOLANT Carrier and Hu1ber TONY UHOERWOOO : 160
I +----------------------------------+-----------+-----------+-----------+-----------+-----------1-----------+-----------1-----------+
: Ill Number Matrix : To LAB : To STORAGE: To LAB : To STORAGE: To LAB : To STORAGE: To LAB : To STORAGE:
: mR/H:CPM Client IO Location : Oate/Init : Oate/Init : Oate/Init : Oate/lnit : Oate/Init : Oate/lnit : Oate/Init : Oate/Init :
;-97-160-IA·-----------------F!LTER-;>,~_q -;-----------;-----------;-------·---;-----------;-----------;-----------;-----------; I : 00136 SO-M23-R2 I __ } ______ .>., l~--i .J.;,!;J ____ --+-----------+-----------+-----------+-----------+-----------+
: CO2 : ) . J : r 1
•: : · : : : : : I ;-97-160-1 B --------------------xAo -;s &~
22
--:--· ~ --+--
1
J ----;-----------;-----------;-----------;-----------;-----------;
' 00143 SO-M23-R2 1---} ___ .,,:i,iJ-_()/_~pJ(P_ ________ +-----------+-----------+-----------1-----------+-----------+ 1 -r-·
I : CO2 : : : : : : : : :
;-97-160-IC------------FH/ ACE/ MECL2 -; 5 6 -'iz.~-:---r · --:--,J_-----;-----------;-----------;-----------;-----------;-----------;
: 00137 SO-M23-R2 +---S..-----tZ-~ crJl -------+-----------+-----------+-----------+-----------+-----------I 1 f-97-160-10 ------------FH / TOL -R I:::-i~ ~ ~7:c ~--------+ J -----;-----------;----------;----------+----------;-----------;
I L. "UO."""" ...... "'i°··"-· 1d,rt'. ·;· T T ··:· . . .. : : :
' 97-160-lE IMP I ' .::, i>/l'I ' _s {J./rl ' ' ' ' ' ' ' 11 I --: .'1'1-C.C. I 11->7 r r I I I I I
: 00139 SO-M23-R2 1--1"-""-u_, ___ }-_-,,:_ '.5.,1-----------+-----------+-----------1-----------+-----------+-----------+
' CO2 I ./ I L 1 I I I ' . I I
I I y I I ! I I I t I
1-----------------------------------1-----------1----------+-----------+-----------+-----------1-----------+-----------+-----------1 I ; 97-160-IF 00 I 40 SO-M2!~i~EH E RINSE ;_~tri:Jf --;_ ----_____ ; ___________ ; ___________ ; __ ---------;_ -------___ ; __ ---------; _____ ------;
: CO2 : '+ : : I +-;;:;~~:~~ -----------------;~;-;:;-;3-i M---;----------;-----------+-----------+-----------+-----------+-------. ---+-----------+
: 154 SO-M23-R2 +---1 ~M5..+---------+----------+-----------+-----------+--___ -----+---___ ----+------:----+
.1 l-;;:;~~: ;~------------------;;~ :::-is f ~ ---:----------;-----------;-· ---______ ; ___________ +-----------+----------+----------!
00145 BLANK 1--}-·:.'Z.t:_'t:.+----------1-----------+-----------1-----------1-----------1-----------1-----------+
CO2 : I I I I +-----------------------------------+----------~----------~-----------~-----------+-----------+-----------+-----------+-----------+
97-l60-2B XAD .:
00152 BLANK COZ +----------;-------t :1{1-i' ~--;-----------;-----------;-----------;-----------;-----------;
.I ~-;;:;~~:;~------------;;j;~~;~~~~;-;·---------;----~·(;;;:-z.r;:~-----------;~----------;-----------;-----------;-----------;
I ' 00146 BLANK . f----------+----------1-----------1-----------1-----------1-----------1-----------1-----------1 ! ·. f
: · CO2 : f . : .
;--~;~;;~;~~-~;:;;;;;--~;;;~;:;'.~~;;~-f:;;;;y·;;;;;;;-;;;:-~~;;-~~;-;::;;;-;~;-;;:;;-:;;;-;~;+;~;-;~-;;:;;;-;;-;;;-;~'.-----------1 I ; · All client samole IDs preceded by "94-365-•.
' 1-----------------------------------------------------------------------------------------------------------------------------------:
I i Archive Remark5: 9
+---------~------------------------TRIANGLE LABORATORIES. INC.--CHAIH OF CUSTODY--REVISED 02/l7/95----------------------------------+
I CLIENT CHAIN OF CUSTODY SAMPLER'S SIGNATURE~ P/Q 01667/1100000961 I
From, ETS, I NC. Contact, TERRY WILLIAMSON Total Number of Analysis Wanted:
1401 MUNICIPAL DRIVE l'honeo 703-265-(Xl04 Containers:
ROANOKE, VA 241l12 Fax, 703-265-0131
Project: f"l< la'tn · J/<4/ P.O.#, 5408 I
(ETS02 n-tK)
STA NO. Date Time Comp Grab Sample Id.# Sample Ami. Remarks
J-,7 I ?d D
'.i ,-,;
/~'{ )-tc,;,1 .>d -/1}.), J ~/l i.
'
Relinquished By/Sign. Date/Time Received By/Sign. Relinquished By/Sign. Date/Time Received By/Sign.
~ U,1 .. j )/t?J 1 s' /I '.L :;'
Rellnqufuhed By/Sign.
. .
Date/Time Received By/Sign. Relinquished By/Sign. Date!Tlme Received By/Sign.
Received _for Laboratory By/Signature Date!Time _ f-Send Samples to: Triangle Laboratories, Inc.
C l ~ji_./}_ 3,/ 1-zr/? ':? · Attn: Sample Custodian
II'. /0 801 Capitola Drive
Durham, NC 27713 USA I
, . -.....,, Phone: [phone] • Fax: [phone]
-------------------
-------------------
'}
Cl
C
.l
·•
' ,:
"
:, .,
)
. . ----
CLIENT CIIAIN OF CUSTODY SAMPLER'S SIGNATURE~~ Quo1e 1100000961
Fmnc EIS, INC. Cuni.<t: '11:RRY WILLIAl\1SON Total Number of /\nalysls Wsnhld:
HOI MUNICIPAi. DRIVE r, .... , 71n-265-{XKJ.1 Containers: J); &J',~> /Fu rq,i.J,
ROANOKE, VA 24012 fax; 71n-265-0:3t Pclj..5
l'roje<t />)c.,Lq-,,, -4 r,, ,/, r.O.I: /1 f )-,, p L(Sf
(ETS02AIK} .. ' ..
STANO. Dalo Tlme Comp Grob Sample kl.ff Sample Ami. Remark"
"}.-1'7 /{CO ..../ /Ji, p•,f.<,. Sd-f>i•J-R. .L --/3? It-, I-,,.,:, .,. •ll. J ' . '
/ IJY hit -I?, 9 Hlo/) -/ L/ -;J;,,e, I '0 ,t.~)t
,--/lj 5 f,+P • '✓ .
/ I'={ 5 p,,J-,,-I'? lo .... ( -I IJL
II, ',,._,, I ' ;>,tll, ..
,,.-/.47 77i I .. ,,.<
' . J -I •I 't ,,,,...,. ..
V /
}!,~ ~/r 0 t'-'
Oatefl~-l--.... --------..• .. -. ----·•'-
Oollnqubhod Dy/Sign. necelvcd Dy/Sign. Relinquished By/Sign. Oalafflme Received B,-lSlgn. V,;::. tl}, ?· lf-V:
nolinqulshod By/Sign. Dain/Time Received By/Sign. Relinquished BylSlgn. Dalafflme Received By/Sign.
-· ----. "#~rnd,~ Dnle/TilllD Send Samples to: Triangle Laboratories, Inc.
-S,f (g(?? Alln: Sample Custodian
801 Capltola Drive
11:(D Durham, NC 2TTl3 USA I
Phone: [phone] • Fax: [phone]
I
I -@$¥$1,l?ii,§),,T . I
. TRIANGLE IABORATORIES OF RT~ INC.
R=.AH-9/93
.DOCUMENT
CONTROL
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
. s I
I.
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Triangle Laboratories of RTP, Inc.
Case Narrative · March 28, 1995
31982A .
By our interpretation, the analytical data in this project are valid based on the guidelines
of EPA Method 23 and Triangle Laboratories' Method 23 Data User's Manual. Any
specific QC concerns or problems have been discussed in the QC REMARKS section
with emphasis on their affect on the data. Should ETS, Inc. have any questions or_
comments regarding this data package, please feel free to contact Han1 Karam, Air
Quality Client Services Manager, at [phone].
For Triangle Laboratories of RTP, Inc.,
Report Preparation Quality Control . .
\.kC~ <5l v1/9J
Saroj A. Parikh Vijay S. Chhabra
Report Preparation Chemist Report Preparation Chemist
The total number of pages in this report are: _ _._H-1--l __
Triangle Laboratories of RTP, Inc.
Case Narrative
March 28, 1995
31982A
A8 is the integrated current of the characteristic ions of the corresponding internal
standard,
Q8 rep_resents the amount of internal standard added to the sample before
extraction,
RRF(6) is the mean analyte relative response factor from the initial calibration
(Ical) and,
W is the sample weight or volume (W = 1 for M23)
DL is expressed in ng or pg
Other sample calculations may be found in Triangle Laboratories' Data User's Manual.
Data Flags
A "B" flag is used to indicate that an analyte has been detected in the laboratory method
blank as well as in an associated field sample. The "B" flag will be used only when
the concentration of analyte found in the sample is less than 20 times that found in the
associated blank. This flag denotes possible contribution of background laboratory
contamination to the concentration or amount of that analyte detected in the field sample.
Under Triangle Laboratories of RTP guidelines, a laboratory blank is acceptable if one of
the following conditions is satisfied: 1) the tetra through hepta CDD/CDF levels are all
below the target detection limits (TDLs), 2) the analyte levels found are all below 1/3 the
theoretical method detection limit (TMQL), or 3) the contamination levels are less than
5% of the levels detected in the associated field samples. If these conditions are satisfied
or if the blank is unable to be reextracted, the interpretation of the contamination
levels relative to the samples should be as follows: 1) analyte quantitations should be
considered valid if the level of blank contamination is less than five percent of the level
detected in the field sample, 2) analyte quantitations should be considered estimated if the
analyte level in the sample is five to twenty times the level of the analyte in the blank, or
3) analytes whose level in a sample is the same as or less than five times the level
detected in the associated blank should be considered present likely due to laboratory
contamination and not native to the sample. ·
A "PR" flag is used to indicate that a GC peak is poorly resolved. This resolution
problem may be seen as two closely eluting peaks without a reasonable valley between
the peak tops, overly broad peaks, or peaks whose shapes vary greatly from a normal
distribution.· The concentrat10ns or amounts reported for such peaks are most likely
overestimated.
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Triangle Laboratories of RTP, Inc.
Case Narrative
where:
Arnt.(6) is the amount of a given analyte (expressed in ng or pg),
A6 is the integrated current for the characteristic ions of the analyte,
!Vlarch 28, 1995
31982A
AB is the integrated current of the characteristic ions of the corresponding internal
standard, .
QB rep_resents the amount of internal standard added to the sample before
extract10n,
W is the sample weight or volume (W = 1 for M23)
RRF(6) is the mean analyte relative response factor from the initial
calibration (!Cal) and,
Detection Limits
The detection limit reported for a target analyte that is not detected or presents ari analyte
response that is less than 2.5 times the background level is calculated by using the
following expression. The area of the analyte is replaced by the noise level measured in
a region of the chromatogram clear of genuine GC signals multiplied by an empirically
determined factor. The detection limits represent the maximum possible concentration of
a target analyte that could be present without being detected.
2 * 2.5 * (F * H) * QB
where:
DL(6) is the estimated detection limit for a target analyte,
2.5 is the minimum response required for a GC signal,
F is an eml?irical number that approximates the area to height ratio for a GC
signal. This number is 5 for the DB-5 column and 3.5 for the DB-225 column,
H is the height of the noise,
Triangle Laboratories of RTP, Inc.
Case Narrative
Overview
March .28, 1995
31982A
Two M23 samples were received from ETS, Inc. in good condition without any coolant
on March 18, 1995 and were stored in a refrigerator at 4°C until the time of extraction.
The samples were extracted and analyzed for PCDD/PCDFs according to procedures de-
scribed in the Triangle Laboratories Data User's Manual (Rev. 12/93-HK-2-AH-2/93).
Any particular difficulties encountered during the sample handling by Triangle Labs
will be discussed in the QC Remarks section below. Results reported relate only to the .
items tested.
Quality Control Samples
A laboratory method blank --identified as the TLI blank was prepared along with the
samples.
oc Remarks
The release of this_particular set of ETS, Inc. analytical data by Triangle Labs was .
authorized by the (..1uality Control Chemist who has reviewed each sample data package
individually following a series of inspections/reviews. When applicable, general
deviations from acceptable QC requirements are identified below and comments are
made on the effect of these deviations upon the validity and reliability of the results.
Please consult Triangle Laboratories' Data User's Manual for further details. Specific
QC issues associated with this particular project are: ·
Sample Receipt: None
Sample Preparation Laboratory: None
Mass Spectrometry: None
Data Review: Any 2,3,7,8-substituted analytes found in the TLI Blank are detected at
a level equal to or below the target detection limit (TDL), with the exception of the
2,3,7 ,8-TCDF. The levels detected below the target detection limits are acceptable as
per TLI Guidelines. 2,3,7,8-TCDF in the TLI Blank was detected at 0.05 ng on the DB-
225 column analysis, which is at the target detection limit. The results are bemg released
as per client's request. Please refer to Data Flags section of this case narrative for the
effect of this blank contamination on the sample results.
Sample Calculations:
Analyte Amount
The amount of any analyte is calculated using the following expression.
2
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
. Ii
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
CASE NARRATIVE
Analysis of Samples for the Presence of
Polychlorinated Dibenzo-p-Dioxins and Dibenzofurans by
High-Resolution Gas Chromatography/ High-Resolution Mass Spectrometry
Date:
Client ID:
P.O. Number :
TLI Project Number:
Method23X
March 28, 1995
ETS, Inc.
31982A
This report should only be reproduced in full. Any reproduction of this report requires permission from Triangle
Laboratories of RTP, Inc.
Rev. 12/17/93
Analytical Services Division
801 Capitola Drive P.O. Box 13485
1
Durham, NC 27713-4411 Research Triangle Park, NC 27709-3485
919-544'5729 Fax# [phone]
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
-•
APPENDIX 0
DIOXINS/FURANS LABORATORY DATA
I
I
I
I
I
I
I
I
I
APPENDIX P
I SEMIVOLATILE LABORATORY DATA
I
I
I
I
I
I
I ,, •. :-:
11
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
CASE NARRATIVE
TRIANGLE LABORATORIES OF RTP, INC
• 801 Capitola Drive
Durham, NC 27713
Phone:[phone]
Fax: [phone]
DATE: March 30, 1995
TLI NO: 31982D
OBJECTIVE: Analysis of two MM5 trains and a method blank for Method 8270 Table 2
selected semivolatile compounds.
METHOD:
Two MM5 trains were received by Triangle Laboratories of RTP, Inc. without coolant
and in good condition. on March 18, 1995 and were stored at 4"C until extraction and analysis.
Sample portion 00148 IMP 2-4 was not listed on the client chain of custody. Prior to extraction,
the XAD, filter, and rinses were spiked with 100 ug of phenol-d , 1,4-dibromobenzene-d4,
pyrene-d 0, and 2,4,6-tribromophenol. These portions of the MM5 trains were Soxhlet extracted
with metf!ylene chloride for 16 hours. The impinger rinses when present were spiked with 100 ug
of the surrogate standards nitrobenzene-dl, 2-fluorobiphenyl, l,3,5-trichlorobenzene-d_, and
anthracene-d10 before being extracted witn methylene chloride using a separatory funnel. The
extracts were split with 50 percent of each extract being used for the dioxin analysis. The other
halves of the extracts were later split with 50 percent of each being used for 8270 and PCB
analyses. Only the compounds listed on Table 2 of Method 8270 are reported in this data pack-
age. The analysis is based on the guidelines of Method 8270. The results reported relate only to
the items tested.
The internal standards. l,4-dichlorobenzene-d4, naphthalene-d8, acenaphthene-d10,
phenanthrene-d10, perylene-dl', and chrysene-d12 were added such that the final concentration
was 40 ug/milli11ter immediately prior to analysis by GC/MS.
The GC/MS analysis conditions are listed below:
GC CONDITIONS:
Column:
Program:
Carrier Gas:
MS CONDmONS:
Instrument:
Scan:
Interface:
REPORT:
J&W DB5-625, 30m x .32mm x lu
35C, ramp 12C/min to 285C, hold
for 2 min, ramp at 8.5C/min to
3 !5C, hold for 13 min.
Helium
HP MSD, Chemsystem and Target data systems
35-550 amu at 1.67 scan/sec
Capillary, 250C
Enclosed with the case narrative are the sample identification index, project summary
sheets, client paperwork, TLI chain of custody sheets, wet laboratory extraction information
I 1
TRIANGLE LABORATORIES OF RTP, INC.
CASE NARRATIVE
March 30, 1995
31982D
. sheets, analyst run logs, and tracking fonns. AU initial and continuing calibration data are locat-
ed behind the samples in the back of the data package. Project summary sheets are enclosed
behind the case narrative. These include a sample identification index which correlates the client
sample name, TLI sample number, and the analytical filename. The project summary sheets
summarize the amounts of detected analytes in gray and include the estimated detection limits in
parentheses for analytes which were not detected.
The data are reported as quantitation reports, TIC reports, chromatograms, interim re-
ports, and spectra of detected target analytes and TICs. The quantitation report header lists the
TLI project number, analysis method, instrument sample file name, and client sample name. The
client project number, TLI sample number, calibration file, dilution factor, and date received,
extracted, and analyzed are also listed in the quantitation report header. The response factors
used for all calculations are from the continuing calibration listed in the header. The amount
reported for each target analyte detected in the sample is listed in total micrograms (ug). The
retention time (RT) will be listed for all internal standards and analytes which are detected .. If a
target analyte is not detected, it will be flagged with a "U" and a detection limit will be listed.
Estimated detection limits were calculated for all analytes which were not detected by using an
area of 10,000. The estimated detection limits reported are the average detection limits achiev-
able over time on an instrument type. The actual detection limit for a given compound on a given
day may vary from the estimate reported. The quantitation limit for all analytes is half of the low
. point of the initial calibration adjusted for dilution when appropriate. Below this point the cali-
bration cannot be considered to be linear. Any amounts reported at a level below the quantitation
limit will be flagged with a "J" and should be considered estimated. If a target analyte is found at
a level exceeding the upper calibration limit, it will be flagged with an "E" and should also be
considered estimated. In the event that an analyte is sufficiently above the calibration range that
the mass spectrometer becomes saturated, the analyte will be flagged with "SAT' and any
amount reported should be considered underestimated. Any compounds detected in the labora-
tory blank will be flagged with a "B" on the sample topsheets if detected in the sample. All
target analytes are quantitated against the internal standard preceding them on the target analyte
list. Surrogate standards are quantitated against the internal standard with the matching internal
standard reference number. For example, phenol-d5 has 1 in the IS Ref column and would be
quantitated against the internal standard which has IS l listed in the flag column. If an internal
standard area is above or below the quality control limits as defined by the continuing calibra-
tion, it will be flagged with "High" or "Low" in the flag column. ·
RESULTS:
Please note that while Method 8270 Table 2 lists bis(2-chloroisopropyl)ether, this
compound is not listed on the quantitation reports. The reports list 2,2' -oxybis(l-chlo-
ropropane) which is a structural isomer. These compounds coelute and are considered equival-
ent.
All samples were extracted within the fourteen day sampling to analysis holding time and
analyzed within the. extraction to analysis holding time.
All internal standard areas met method criteria for the method blank and all of the sam-
ples.
All surrogate standard percent recoveries met in -house QC criteria as detennined by a
95% confidence intervals:
2 2.
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
TRIANGLE LABORATORIES OF RTP, INC.
CASE NARRATIVE
March 30, 1995
31982D
Surrogate Standards Mean 95% confidence interval ,·
1,3,5-trichlorobenzene-d3 53.5 4.4 -102.6
l,4-dibromobenzene-d4 . 72.2 15.9 -128.5
2,4,6-tribromophenol 73.2 D -153.1
2-fluorobiphenyl 64.3 11.0 -117.6
anthracene-d1 78.5 24.5 -132.5
nitrobenzene-~5 60.2 · 15.8 -104.6
phenol-d5 62.8 10.9 -114.7
pyrene-d10 67.8 14.3 -121.2
The method blank contained several target analytes at levels below the quantitation limit
and one analyte, naphthalene, within the calibration range. These analytes are flagged with a "B"
on the sample topsheets when detected in the samples. These analytes in the blank should not be
considered truly present in the native samples unless they are detected at a level at least five
times that found in the blank. ·
SAMPLE CALCULATIONS:
Response Factor (RF) =
Amt of X (ug) =
Where:
(Area X X Amt IS)
(Area IS x Amt X)
(Area X in sample) x (Amt IS) x DF
(Area IS in sample) x (RF from ccal)
Amt IS = amount of internal standard = 40 ug
Amt X in the ccal = amount of analyte spiked into the continuing calibration= 50 ug
DF = dilution factor ·
This report should only be produced in full. Any reproduction of this report requires
permission from Triangle Laboratories of RTP, Inc. Should you have any questions about this
project, please feel free to contact Hani Karam, Air Quality Client Services Manager, Hani
Karam, at [phone].
For Triangle Laboratories of RTP, Inc.,
Report Preparation:
gr,J.-e. ~~~ ~-1t·~)
Bracha RosenbergJ
Report Preparation Chemist
The total number of pages in this data package is 1 .?-) . 3
_,
_,
'l
'l
C
-1
·.)
l
) .
C
·•
"
_I .,
--. -· ....
CLIENT CIIAIN OF CUSTODY SAMPLER'S SIGNATURE _2~~ Quo1e 1100000961
---------
Fmm: EIS, INC. Cunlut: "11:RRY WILLIAMSON Total Number of l\nal~als Wanlud:
MUI MUNICll'AL DRIVE r, .. ,., 700-265-{XX}I Containers: J); t.t,,,> /F«r4 -i.1,
ROANOKE, VA 24012 fa,c 71ll-2~0:31 Pc/J..5 ' />J(_,larl,i • I-{ c,, .I-rn;..,<t l'.0.1: /1 f )-"/P LIS:f
(ETS02nlK) .-
-.. --
STANO. llato llm8 Comp Gmh Smnplo ld.n S,implo Ami. Remarks
--
'J.-, /7 /'{tJO ,._./ /JI, F: 11-<,. S<I-f>l,.J-R. .L
-------
/ 30 11-,fr-i, l/ I
/ !Ti 11!1,,., -1 -c 9 .fn./ I
---I 'I -:Jne, I ' -0 j't. "")f.
,.-----/ '-f 3 f,+P . ,..,
/ I':/ 5 p.,J.,,... ~ /c,,,( --tJ, ';.,,, I ,
. I ~I' /'l(tl ,._ ---
r /.'I 7 r,; L,,~, --
• / -I 11 'I ,;1..,. ... , u / Is-,;.. ;i. -1-o L'/
. ---n .-1. . .. . .. . ..... ----·--...... .. . ----· -·· .. . ...
llollnrrlkhod Dy/Sign. 0alofllme llecelved lly/Sl!Jn. Hollnqulshod 0y/Slyn. Dnlofllmo llec•lved By/Sign.
V ~tLJ.i.~-/ _,
?·lf-U ---
llollnqu hod Dy/Sign. DatofTime llocolved Uy/Sl!Jn. notinc1uished By/Sl!Jn. Dalafllmo Received By/Sign.
•--. ---······------· "#~''"~ Ollolle/Tlmo S,nl Samples lo: Trfanglo Laboralorlas, Inc.
'3/(6/?"J Alln: Sample Custodian
001 Capltoln Drlva u:/D Durham, NC 2TTl3 US/\
Phone: [phone] • Fax: [phone],W91
-------------------
------------------

-
I CLIENT CHAIN OF CUSTODY SAMPLER'S SIGNATURE~ P/Q 01667/1100000961 I
From: ETS, INC. Contact: TERRY WILLIAMSON Total Number of Analysls Wanted:
1401 MUNICIPAL DRIVE !'hone: 703-265-0004 Containers:
ROANOKE, VA 24012 Fa,: 703-265-0131
Project: /'\ ( /.A ,,-t n · J/(4 / P.O.#: 5408 I
(ETS02/HK)
STA NO, . Date Time Comp Grab Sample Id.# Sample Amt. Remarks
J-,7 /t~O / '.J r-J' l~'I >-UV•I 5,d -/17.J, J ,/4 ~
.
Relinquished By/Sign. Date/Time Received By/Sign. Relinquished By/Sign. DatefTlme Received By/Sign.
cw:c. uJ,,, .,/ }/(?J?!," /1 :L,5' .
Relinq shed By/Sign. Dale/Time Received By/Sign. Relinquished By/Sign. DatefTime Received By/Sign.
c.:
Received lor Laboratory By/Signature Date/Time _ ~ Send Samples to: Triangle Laboratories, Inc.
1 ;4J!t~~ ~I 1-'ir' I?'::> Attn: Sample Custodian
//'· /0 801 Capitola Drive
Durham, NC 27713 USA
Phone: [phone] • Fax: [phone]
I
PAGE i' .OF 2
1····························································· ····l····················l····································l······I I
Custody Seal Absent Sa1ple Seals: Absent : Ill Project Hu1ber : 31982 : Book
Chain of Custody : Present 1····················1····································1
Sa1ple Tags : Present : Client: ETS02 : ETS, INC. 97 I
: Samele Tag Humbers: Listed 1····················1·····················u····~·····I
; ... SMO.:~~~: ......... :.NIA·······················-···· _·····-·---·;·~~~:-~:::'.~:~ ...... ;.~~'.:~'.:: .. ;.ay '()~.-·; Page : I
Box HO COOLANT Carrier and Humber TOHY UHOERWOOO : 160
l--··---·········-··---·-·····----··l···--··----l·-··-·--···1···--······1--·········l···-·-·····1········---1·········--1··-········1
: TL! Humber Matrix : To LAB : To STORAGE: To LAB : To STORAGE: To LAB : To STORAGE: To LAB : To STORAGE: I
: mR/H:CPM Client ID Location : Date/lnit : Date/Init : Date/Init : Date/lnit : Date/lnit : Date/Init : Date/lnit : Date/Init :
;· 97· 160-IA-·-··--··--··-·---FILTER ·~ftl_.tj -;-·--·-·--·-;-·---·-····;·---······-;·····-·-···;·--····-···;·-·-·-··--·;··········-;
: OOIJ6 SO·M23-R2 I··}--·-_.$. 11-:i r1.11J-···--I····-----·· I···-·-···--1·-------·-·I-----··--··I-··--··--·-I I
:-97-160-1B----------··-·····--·:::·~~ h.~22 --:-S-1-·-; __ .J -----~--···--····:·--·------·~···-·-··-·-!--··----·--!--····-··-·!
: 00 l 43 SO-M23-R2 ;_ -.3. :_-"'~fr-_()/_( r-lJ. __ ·····;-:···----·· ; __ -·-·---··;··-····--·· ;····---·-__ ;_·-···---_.; I
: CO2 : : : : : : : : :
;-97-[60-ic -··-·-··-··· mi ACE/HECL2 ·; 5 '> -'iz..,-, -r _ ··:· .J·----;------·····;···--------;-·--·· ---·;-·---··--·-;-····· ···-; I
: 00[37 S0-H23-R2 I··-~··---~Z.d..tf]rl_ -·---··I·---···---·I-----------1--·····-·--1-·--·-'···-+··-·----··-I
!-97-160-10 · ---······ FH/TOL. RI::: ·f s. i}~~·.i-~-·-r~·~; L , ····-;···-------·;-······-··-;·--····-·--;-· -··--··+---····-··; I
: OOIJB SO-H23-R2 I·-·· _·,-... --(1 /.I .J..l(Iev/ ..••.. +-······----+-----·---·-+-·-· -·-----1--·------·-1---·--··-·· +
~-_. _____________________________ coz. l · _ _ _ _ _ _ _ _ _ ] ____ .. __ --L---------. i. ---------. l. ----------l-----------l. ----------l----------. l I
'97-160-IE IMP l '7 ~ ' 5,(J,.Jrl ,3--2.2~~, ' ' ' ' ' I I ,.c,c. I -Wl~ I I I ' ' I I ! OOIJ9_ SO·H23-R2 CO2 ;·-Xt -U·;-··l·---✓-+-··~.:.··-+ ··········;··-·-----·-;-·--··-····;-·····-···-;-··········+ I
;·;;:;:~:;;:::::·:::::~~~~~;~·~;;;~-::~r.2~~::::::·:_::::::::::-:::::::. :~I-·---:.:::.::. __ ·--·-:·-··-··-·-·:-.......... : I
: . . CO2 : ~ : l : : :
;-;;:; 60:7~ -·~~i$ ~,~1i"i$ ;~~ ·;:~·;3-~-fi--· ;----·-····+···-----·-+---s ,q.e_: ······---;---· --·-···;-···--··-··;-·······---;
: 154 SO·H23-R2 +···~~M~+· ······--· +-------·-·+ .... L-·-+··--·-·····+-·····-····+---··---···+-···-··-···+ I
~~ ----~ -------------------------=~~-l--__ l _ ----l----------+------------r -·----------+-----_____ ·_ +-___ -------+-----------+-------___ ~ ~
97-l 60·iA 00 l 45 BLANK FILTER ;~:~.a-q~ ;. ___ ·-·---:-----····-_;_·-··-·--··;· .......... ;. __ ... ~ .... ; ........ _._; __ ··-------; I
CO2 :
1---·-·---····-·---········--··---··+···· ··-·--+-··-··--··+···-·······+·-···-·--··+······-·-··1---··-·-···1-···-----·-1-··········+ I
97-l60-2B XAD
' 00l52 BLAHK I·-·· ---···+······· ···+ ,---· s-·+·-······-··+··········-+·-·····-···+--·-·--···-1-·········-1
. ;·;; :;~;:;~··--·· ... --·;;j ;~;;~;~~;·;·-· -------;··· -~l f;~-t~ ;:l----····-··;···-·--·-·· ;·· ...... -·-;---·-···--+···-·· .... ; I
: 00146 BLANK t------·---+--·-·· -·-·l···-··-·---1••······---t···---··-··+·-····-·-··+-·····-----+···-·-·-···+
:··········---------·-···-----··:~=·;-~ ---I ······--···l·----------1-··········+--------··-+-·-·-·-----+-·--···--·-I---·-·-·-··+
Receiving Remarks: Client's Chain o/ Custody differs from what the Sample IDs· read: used the IDs on sample to log in.
All client samole IDs preceded by •94-365-·.
:---------------.--------------------------------------------------------------------------------------------.----------------------: I
: Archive Remarks:
-I·····-·---····· -··-· ···--'· · .:. :·. 0 TR !ANGLE LABORATORIES.
6 . :
IHC. ··CHAIH OF CUSTODY ··REV I SEO 02/ l 7 /95·----··-.. -·····-·----··-··· ------I I
I
I · PAGE 2 OF 2
································································1····················+····································+······1
: Custody Seal Absent Sample Seals: Absent : Tl! Project Hu1ber : 51982 : Book '
' Chain of Custody : Present I····················+····································+ , ~ :::::: ;::s Nu1bers: ~;:~:~t ;.::'.~~:'..:'.:~: ...... ;.:'.::.:~:: ........ ·,···r·~~::.; I ·:::·Forms·········'·"'A .......... HO.COOLANT····················;·::::i::c:::e:u•ber·:·::::
8
:::ER:o::1~ ... '. :::e i
1···································1···········+···········1···········+···········1···········+···········+···········1···········1
Ill Number "atrix : To LAB : To STORAGE: To LAB : To STORAGE: To LAB : To STORAGE: To LAB : To STORAGE:
R/H:CP" Client IO Location : Oate/lnit : Oate/Init : Oate/Init : Oate/Init : Oate/lnit : Date/Init : Date/lnit : Date/lnit :
1···································+···········1··········· ···········+···········1···········+···········1···········1···········1 r ,.,_,. _ °''" _ "'"":""" "'::: yt/,%}Jrf-------: -----:----:------:---------:---:
197·160·2E 00148 BLANK l"P 2·4 I····· ·····1·· .. :3,;-22-"'71 ......... ; ........... ; ........... ; ........... ;. ·········;
I;;:;~~:;;···········;~~~;~;·~;~;~·~····· : 7 ~~~; ··1-·+ ~·········;··········+·········+··········;
; 00149 BLANK . . COl ;--·· . : ····/···;--··r·····;--.~r42)'-········;-··········;···········;-··········;
I··································:···········:···········:···········:···········:···········:···········:···········:···········:
, I I I I I L I I I
: +-----------+-----------+-----------+-----------+-----------+-----------+-----------+-----------+
•................................. ; ........... ; ........... ; ....•.....• ; ........... ; ........... ; ........... ; ........... ; ...•....... ;
I I I J I I I I I I
I ! I I 1 I t I I 1 I .................................. ;-· ........ ·:-........ -· ;-......... · :-......... · :-......... · ;-· ........ ·; · ......... · :-..... ·:: ·:;
' I I 1 I 'I
I I I I I I
+-----------+-----------+-----------+-----------+-----------+-----------+-----------+-----------+
1···································1···········1···········1···········1···········1···········+···········1···········1···········1
I 1···········1···········1···········1···········+···········1···········+···········1···········1
' i I ........... : ........... : ........... : ........... : ........... : ........... : ........... : ........... :
I I I L I I I I I
I I I I ! 1 I I 1
1----------------------------------~-----------~-----------;-----------;-----------~----··-----~-----------~-----------~---,------·~
1···········+···········1···········1···········1···········+···········1···········1···········1
I I I l I L I I I I I········ .......... ··· ..... ········:·· ...... ···:· ........ ··: ......... ··:· ........ ·· :····· ... ···:········ ··· :· ........ ··:·· ..... ····:
I I I I I I I 1 I I
: +----------·+-·--·------+------··-··t-----------+--·---·----+---·-------+-·---·-··--+-··------·-+
1---_. _ . __________ . ____ . _. : ___ ..... -l-------. --. l. -.. -------l---. -... ---l---. -.. -... l. ---. --·-.. l .. _. ·-. -. -. l. ---....... l-.... ---.. -l
Receiving Remarks: Client's Chain of Custody differs from what the Sample !Os read: used the IDs on sample to log in.
I All client sample IDs preceded by "94·565··. !
·························-----··-····~-.. -............ _ ............... _ ........ _ ..••....•........•...••...•......•••. -.. -••..•.....
' Archive Remarks:
' 1·································1RlAHGLE LABORATOR[ES,
. 7 :
INC.· ·CHA [H OF CUSTODY· ·REV [SEO 02/ 17 /95· ,·, .. · .· .. ·· · · • · ··· ·· ··········:···I
GlART #: M23-36FF
CLIENI'·
'ILI #' ~ 3\ i'iS2 P-.-D
M'15 'IOLUENE RINSES a::MBINED
ORGANICS SS SPIKE-X
PHENJL-DS 100 ug
1, 4-DIBRQ\IOBENZENE-D4 100 ug
FU:11< Oll\RI' FOR: PCDDs/PCDFs,SVCX::,PCBs, & PEST 2,4,6-'IRIBR(l'1)PHENJL 100 ug
PYRENE-Dl0 -100 ug
'IOLUENE AC/MeCL2 XAD
RINSES RINSES PRFSPIKED W/
I 4 ng D/F SS
100 I.lg !,Ii<-ORGANICS SS SPIKE-II
ROIOVAP -KD --'":'..._.-,.,, ..... 3-UJ-'l ~ . ---------------------'IO 2 mL 'IO 2 mL I DS-NI'IROBENZENE 100 ug
2-FiilJROBIPHENYL 100 ug
XAD + FILTER 1,. , 5-'IRIOIIDROBENZENE-D3 100 ug
-AID 'IO SOX ADD 'IO SOX ADD 'IO SOXHLEI' I ANIHRACENE-Dl0 100 ug
FOR 'IOLUENE FOR MeC12
EXTRACTION EXTRACTION t:J IMP:m;ER
RINSES .
SPIKE W/ I 4 ng D/F IS 7 ORc.~CS ss KD
SPIKE-X SPIKE W/ 'IO 2 mL
1 ug PCS IS's ORG.l\NICS SS I 400 uL PES:" SPiliE SPIIG-W rl_ JILD TO (0.4 ug/mL} PCB AS 1 ug
I I IMP I!-l::ER
WA'..!.~'i.
SOXHLEI' lN LIQ-LIQ
10LUENE-2nd 'l SOXl-:Lc."""'I' lN EXTRACT-MeC12 IARCHiv"E 1/2 MeCL2-lst I
SPIKE W/ lsPLIT 1,1:
4 ng D/F AS
I 50% MeCL2 I I
11 SPLIT l:lh
!SPLIT l:ll ElITRF.CT
'IO ORG.".N.ICS
I
50% 'IOLUENE 50% TOLUENE. · 50% MeCT2 I ~ . -I
I
I S=-LIT 1:1
ECTRACT EXIRACT EXIRACT l 'IO ARCHIVE 'IO DIOXINS 10 DIOXINS .
y µ 25% MeCL2
XCHAN3E 25% MeCL2
a::MBINE 'IO HEXANE KD 'IO 1 mL
I I ANl'.L"YZE FOR
Im PCDDs/Fs CLEJI.NUP I SVCC's
I:O FLORISIL 'ThBLE 2,8270
I CLEJI.NUP
I ANAL"YZE FOR
ANAL"YZE FOR PCDDs/Fs MEIHOD 23X MJN'.l-DECA
FINAL VOLUME !?CBS
1 mL 680 LRMS
I:O 8080
PEST ANl'LYSI
1LI HK MARCH 95
8
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
PAGB l OP l
+------+---------------------------------+---------+------+-----------+-----------+-----------+---------·--+-----------+-----------+ I I I I I I . I I I I I I
I I I I I I I I I I I
+------+---------------------------------+---------+------+-----------+-----------+-----------+-----------+-----------+-----------+
1: I
1.
+------+---------------------------------+---------+------+-----------+-----------+-----------+-----------+-----------+-----------+
I I I I I I I I I I I I
· I I I I I I I I ·. I I I
+------+---------------------------------+---------+------+-----------+-----------+-----------+-----------+-----.-----+-----------+
. I I I I I I I I . I I I :11 I I I I I I I I I I
+------+---------------------------------+---------+------+-----------+-----------+-----------+-----------+·----------+-----------+
I I I I I I I
I I I I I I I I I I I I
+------+---------------------------------+---------+------+-----------+-----------+-----------+----------·+-----------+-----------+
I I : ! COmmento: ______________________ ;___________________ I
I: ============================================================ : +------------------------------------------------------------·--------------------------------------------RliV 07/26/9j (PSTMF 7)--+
I
I
9
imo 1 667
8 \ f; \-\-,tC -~-, ~rL-
~ ,o-c.\,e_fJ'.0
" ' 51l2-tl5. IJ\C.
IZJIZJ136 SIZJ-M23-R2
F· rc::> _j e-c::: t: 3 1 98:2
97-160-1A
.. ... . ·-.. -·•· ~ ' -.
\ '(, \.\-i I -c.\ec,.~
tfc~ L.\ < 4 r-
ETS02--£TS, IJ\C.
12JIZJ 145 · BLANK
F· rc::> j e-c::: t : 3 1 982
97-160-::ZA
E"TS02-e.,s, I/IC.
F-,-o -IZJIZJ 152 BLANK
. J E:!-c: t --,,. :i. . 97_ 1 ..,__,.;. -· S>e:2 ~v-_,--::2a
METHOD 23
CONTAINER Fl
SAMPLE# 94-365-00136
RUN It d · /JJJ. J· fl).
CONTE: • Quar_tz Filter
----
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
.·.· .. ,~ ~ "·P I
I
1 o _-I
Date: 03/23/95
Time: 11:36
Sample
# crd TLI Number .. CUstomer.Safflple.Id ....... -
000 TLI Blank TLI M23 Blank
~~-<•-~•-<5
001 97-160-lABC& ~ SO-M23-R2
002 97-160-2A-CE 'O'M+5 BLANK €<,--~q,r5 ... End of Report •••
~ -- - -
F. XAD
No Color .....
0 WHITE
1 WHITE
1 WHITE
- -
TRIANGLE LN30RATORIES, INC.
Wet La~UF Observations
ProJect: 319B2-D
Filter Glass Wool PUF
Color ..... Color .... Color .... ·. Odor ......
NONE NONE NA NONE
BEIGE NONE NA NONE
WHITE NA NONE
---- -
Entered. By ...... Date ....
WHEELER• 03/23/95
WHEELER 03/23/95
WHEELER 03/23/95
-- -
PRDPERC v:3.07
Page: 1
Time .... s
11:36:05 F
11:36:05 F
11:36:05 F
--
...-➔
...-➔
I
--
--Date: 03/21/95
Time: i6:50
sample
-- -
# crd TLI_Number .. Customer. Sample. Id .......
000 TLI Blank. TLI M23 Blank
001 97-160-lABC&: -S0-M23-R2
<¥-Ill If I-~'
002 97-160-2A-CE ~ BLANK
(4,¥.f·fl~ ... End of Report . ..
-
Init.
pH ..•
7.00
7.00
1 .oo·
------TRlANGLF. LJ\OORATORIES, INC.
Wet Lab Extraction and Observations
Project, 31982-D vA-TcrL PA-<Lt
NaOH Adj. H2S04 Adj.
mL .• pH.l. mL .•• pH. 2. Appearance. Color .•.... Odor ...
0.7 12.00 1.0 2.00 CLEAR COLORLESS NO
0.7 12. 00 1.0 2.00 CLEAR COLORLESS NO
0.7 12. 00 1.0 2.00 CLEAR COLORLESS NO
-- -- -
Vol. Entered. By •....•
300 GATCHET
270 GATCHET
210 GATCHET
PROPERC v: 3. 07
Page: 1
Date .... Time •.•• s
03/21/95 16:49:43 F
.03/21/95 16:49:43 F
03/21/95 16:49:44 F
--
N
,-j
I
I
I
.I
I
I
I
I
I
I
I
I
I
I
I
I
I
I Sample No.
~-1-.
I -1-
'!() -l
/-).
ti-J.
fl ')
' J
0 /l,
I
j;
Comments:
TRIAJ.'l'GLE LABORATORIES, INC.
SAMPLE EXTRACTION AND CLEANUP TRACKING FORM
ORGANIC WET LAB
TLI Project Number: 31 qgd-~4C.,,J)
I Steps I SOP No.
Pr.; /J G-\A-;<,-.5, ,,,. /1/,,.-;:;::, YYV" C.b .
\:...D ~~ IA 1-1 /: ..,<-, .
f1.qt ~ l=i I+--!/ ; • ,.LL ' I/. .... "·· hJ.. V.,,,,V1 :,,.,-1.-.{-,~:~t,Je. • ,dJ ~w... /,4 t.J / :,,, , c~ .J.... U · __ L/<L
':>P:t, ~-4D ·~ 0 1 ,s.,F-T
SP~L .. w I 1:>0!\ , 0 '5<..-i-., y . ~(} :--t 1"' ,7.., ,~-~.-...P, Lf le. A -T
' < a;)'., -l.l-..J 'x D:t b f~'.'-. /-1 _ r 1-,'M <, /. i..'.,-.. . , v
'.:lex // ~ L-. /~ ,-rvll Cl,
A-.t.1 t" ~rl"\PL .. 4.(/ , . 1.-1 J.,r \,.. ~ ,, Fi', -./ ~ .
N.~a \..,.,. ,., -,I u rh ,,I P 1-J a~J ,.-1. ~ <-
A-J~ < 'So'/', I, f I""" , 0
5,,;1:.,-, , "".: , P J e PcB-4
AA'.-.. ":, t-Pi-! 25'~ -!h I\ / , _ .A ~;,:_-/-r,,c.-.f-<. V{.g,vy,/ "' ff.
AJ.t .,f-fH ,.,+ f'f-,6 7 IJ r:, N/,,v-1.-c.-f ~v (,.6,,,,,,; /1(,,'G
F,• /-f..,-/ < ,n. ,~/.,[,., ..JJ<:, ~oV ..L ,' -,,,.'~,i ~,, -e:~-,vqr:TT
• . I -,I l --<nd:, --<, 1.C.?e:.. . -· en b, ..U... ~ '£ t,.,, c.f-r <' -ra.l-e/4
' ,
f\~1,· JL-L_,11 _p-.,-l_,,f.. QI .2:::.c
J,i 5o:x -1;," o,-~ -:1 ~ ½. tr n:011.',,.,
Yi. th r, +sr l)~..,,,_,.,;c.·s A '!l-rc./i.tA-
C.o ,..,h;,.,, e. 1/-z.. Sc,x ~ Ye-H-zo -Ar l)('..,a/l[c..S
n,-u;A~ "'1,'<:£>
~5"/4 -h,/ ~6~i') I Js-%' -W 'x.'dJD+ l/.fc8 ~
I Init I Date I
ff(r 3/z;/q
St(')'"\
\ I ,..
%0 ,/YJ
I
\ 'I
<,!1, rn I )
A-(' .... 3/zi//1
'
,41r,"".. L ,
11 I,
t1-G--
\ I
,; ' ,.,..,,
' j ' I I
=~ o In/',
/
rv. 11/
•---------~-------
• I --
Rev.WM/NU:PREP.DOC,WPS;395
Sample
No.
b-1..--
'
\Ii ·
.
Steps
TRIA.i'fGLE LABORATORIES, INC.
SAMPLE EXTRACTION AND CLEANUP TRACKING FORM
ORGANIC WET LAB
TLI Project Number:
SOP
No.
Init
~5'% +,, L(.fc..e, -+-iJ '7i) . k)_ -+o \ .-v-. I ';j\lJ 1:,\t
Q,(,._.1!1
~ ,r a."' s-f:-t /. 'fl.).., +, l~i ..:::; n,._..,.(r_ I~
i? ..o l'"-" , -h, 11-1~ ' Tl
Js¼ -Ir,; tofa -s,-J, 1p,, + '1.-cl,:1,,,,,,LL.<./ llef<?-1
\ ~,a J
' F I <>f" : "' .-I e,1-,,,q yl '-N::J .
(?~..\.._,\\n ~ -l..... I --I w "_\.,_;/')L --<-
1r,,_<.t..,~ +,.... ~~1,i_fo~ ...,;.,/, lJ1 -h.. I --I
' to \ , -• , ~ 1-1 '-
I
,·
Date
3/zJn
I I
\V
Comments: -----------------------'------
Rev. WM/NU: PREP. DOC, WPS!~ 5
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I PAGE 1 OF 1
------------------------------------------------------------------------------+
TRIANGLE LABORATORIES, INC.
Transfer Chain-of-Custody Form
Project 31982-D
Transfer From: OWLSP To: OMSSV
Initials .. Date .......
Released by: >SW 211.Y°rS
Accepted by: '00 _;J__/ 12}_; 3§
Time ...
.!.}_!Q.2
1.3_ci)
+-------------------------------------------------------------------------.-----T
I
I
I
MILES. ID. . . . . . . . TLI No. . . . . . Cust. Id ................. .
31982-D
31982-D
31982-D
-000
-001
-002
TLI Blank
97-160-lABC&
97-160-2A-C.E
TLI M23 Blank
.~ S0-M23-R2
/00145 BLANK f ~e /1.~·',1·'{
(Rev 11/01/94)--+
SEMIVOLATILE GC/MS TRACKING FORM I
TL-ATP P;oject #: '.,,a"-'J_,_q?J..,,Z-Q"'Jo!--__ _
MATRIX:~ PUF Water Soil. Other
METHOD: e 625 CLP
ANALYTE LIST: QTCLP 625 CLP CAA/PAP PAH CB/CP Other _____ _
ICAL Name: ICAL V.,,,!3::.:Z-::J.j ____ _
I
I
I
I
SSTD050 VDi=14 I
l's JI
l-+" <·W
l>-B ,45 {3;_.P,+JiL.
v'D1S6 ·
VO iB1 · I
I
O<,,L/2 .. ic,o, (J, (PP VD 1q..;
0704 ·z.42) . ~,ix),;t) VD J"i~ I
1)8</i ¢;Qf3t, SC-MZ3-e2 VD tq:J ·
C--t-R H•·~S I
I
••
I
I
I
I
I
TRIANGLE LABORATORIES OF RTP, INC.
I
SOP No. OMS 130 Revision 3.0 12 January 1994 page 9 of 10
I , 16
· TRIANGLE LABORATORIES OF RTP, INC. RUN LOG
MS# COLUMN TYPE COLUMN# ANALYSI_§--1\CO METIIOD GC METl19D/ FIND DB'S OTHER
\J 'OI'½ LP7A 4341031:.} ~ tt\lrl'.110 ~ 1.
EXTRACT/ SAMPLE VOLUME l u / ml 2.
DATE TIME PROJECT# SAMPLE# CLIENT SAMPLE ID FILENAME Ol'Efl lll'iti<LiP PllOC pll COMMENTS
IIET AflC
r -----

-
"t/-:J h...L<J J.-,
1/.)0/4 1531 -1qo1 DPTf'f' VDiL\-'> 1:JQ I:'.)()
&
. 1/tj::J 1L,7t,
1101 {)Ft(>p
-l'-J!. /(Q03 -Vo1,f ,f l'.)(,O QJ
~5 /&33 -{t/0} CfTPP V bl'/.S-tY' a)
i¼
(Ll.i.Jv·IY I 14 I .,
--
0101 IC/Or OFT/JP VDi4~ to /){}
i.,. -,1,'.l C,,,-I ,I
13/
.
,/ i.;¼s q:30 -~1-tg :SSi'i:>/4,Q VD1'}+ _,,-, ()() ~
J/J.'i ";;JJ./ 11 V/)/'ft', /
. -is 10·-~~ -,S';,70/,X) J:i,-., .1l0_
;/J-1/i / -{)i/-XJ ..ssruD<;,o / 1, "''.<; ,._
V/)ft/<"7 w ,ao
)kt/4 -.:J.l/.J/ .SSTt)Of:b VDtSD,,.. 'i:t, ly 11".J'b i~
)~'ks -,;]_tJ.-:).a.. SSTDO,hl VOis;/ ...-/
l)'.}j (,l) ~ Cu,w. 0,.ue,J
1~lri
.
\1",t0 -?-;i\9> S~'i1;,l~o-CA4 1/bfS.l u,
INTEflNAL STANDAflD sunnoGATE STANllAflD ANALYTE STANDAflD
,;) ---

-
--

-
-
MS# v.
DATE -•1zi
3/afr
P/2,~
1u~
'fz~)i;
~~
~
~~
t/25
½.i.~
---------------TRIANGLE LABORATORIES OF RTP, INC. RUN LOG -
COLUMN TYPE COLUMN# ANALYSIS ACQ METHOD GC METHOD FIND DB'S OTHER
()(Jj fv;J.~ 4e?~10.o I J -----------
-
<-' ( ,f,. <lh; n1 -~ 1. /2.Jl/
EXTRACT/ SAMPLE VOLUME tao ulJ/mL 2.
TIME PROJECT# SAMPLE# CLIENT. SAMPLE ID FILENAME OPER 0ACkUP PROC pll COMMENTS
NET ARC -5 --

-
-

-
Sf.. D,L.
J/81r' CJ~-6o 5 Tl!(! 5/]rnflt£ 5 JD/7."! JJO .;; r,. e-i V9 I It lfl(__ = SU It, {j -114 {p
(p TfC 5/J,v{tE & -_:r ,,('-J) I 1.-G'C ;,,, ~/•t/75-
1141 <J/61:Y Jl-50-(p vo11v ,ll/l
()(} r:-.JkJ/, ,.,,_;:-'P"' (,
1r1," j/t:;,J)) 91·'5o-,j 3 ,£e S,1rrf)lff 6 VO /7!5 iXJ I DX JJ Jl--
DJ fl,,,f,i. , ...... So.., Ii
.f)1B?Y GJ1-SH f ·we 51/tnOLE 4-VD 111.,, 0.0 /DJ. /)IL.
\f\lb OJ ftA,lw ( • .-, ~ So,,J..,
D&I' v'orrl iv ):.V
(1',¼ -)4or ~ a~w
~ I
tfNv -. ~'1J I )'>'T1)0$l) v1>11,~ e.r--u -I fl.,/ ()n
0 c'.td qJ, I Y.t bf• co uu,,,.,.__
JOI/~.
l\£u., l,.0-.v,_.,
-dl-\Ji SSlDl;(;-i) \/ f) 11· <J,/ 00 DI') FVl /1 ,,;;z , .
I
ll??J --;:XX)\ ,<'<"1DC't:.c) c/\J\_ VDlfsO [)_() t!'J MMl'ti,
f t,o CL/dolu.11':J/4 ,.~
12.11--J,110 q.:0Dng) f2n1r • v'D/&'/ OD 00 _w, ,,~,
IX,1 -u t.W) Iv,_~~
./37 ;J/10 .$::)1/)()Sl) /21)((,_, VL)I $)-. IP 0-0 1 .p • ',,./ _.,, '
WI ':1/l'1/¼ "1 l'
INTERNAL STANDARD SURROGATE STANO ARD . ANALYTE STMlDARD
,·· I 1
• _I 'J
to
~
TRIANGLE LABORATORIES OF RTP, INC. RUN LOG
MS# COLUMN TYPE COLUMN # ANAL'(SIS ACQ METHOD OTHER
v l
2.
IJATE TIME PROJECT# SAMPLE# CLIENT SAMPLE llJ FILENAME OPEfl DACi(IJI' PROC pll' COMMENTS
NET ARC ------
jJ 0 CAA
%-1!111-8/q1ft -51!,U{, 03U </ 5" VD/J~ or,, (J(}
·rt o~lk.. iJs§,,;-
i'ioa,l vu{• Sm I:,
l¥ll 3/qo?Jb -VO It. I QJ Or:> · a; 11e,,1~l-6"
. " . , .
9
I~ .31q8z.o .:::i3Lll. U3Zl95 Vf}/g(; _,
,
l5il -l11 ()0
l?,1_ ''U-15,/. 4 cAA
. ·•. '31~11, :iV9 51013--;.v•l-SIOfi<, r /55F; 4A-D VD ;g ~ · w ot>
7;6 Al •IJ
17"' -:i.. e(c: /Av \I',') ,¾ 31£182.D -'(°J.·l&O · 99,'t/S" Bi.AN IC. \/D18'1 ./ I /Aft 7A-C/i tb DO
JZ%1 r13f 1/"1 /t,O-1 C+/t'<ll',~
/IUll t>./Jl)hfi"C/ (6/ (r11' "-'
31~f!llD "/A&;•.'t4 001~1r .:SO-Ati.;.13-ez., VDU?& '/JO
. ~e TEiJ SE&i#/Jef
.__ -
'II• l'SV. I J. -,,..,,,,,,,, f '-""' ) 2fl1{, /~-D °5v'75/o ':>VJS loop V[) /f1 p_J ·-nu,/ /
? 7-/Sil· 2. SVC/900.;,-.:S'vySJL'08
c/1>,A
jl910 ~ --zA-1) VDJCJO -. e11,IJI 'l
f/I 19/ 3 5vr/SJD09-sv9sto/,-:;.
q,.A )
--31911, 3'1-1) /!tJA'# -", ✓o ,q; w -\
31q0Be> '}1-Yt,·/ I -./1 I
nAJl'L Vl'l.' -,,, ,,.,, s
·--M Al H1 /1,t:, ~) f/.J-
._,,,
IX' -
INTERNAL STANDARD SURROGATE STANDARD ANALYTE STANDARD
--------: 1 .. 1 .... ~_. ~.:i■·,,:■/.1-J r.,~qllt/■· t'-,fl"':'1111/ !!11-='•.-------.-r---..l•"""..._ __ ..., __ ._J -... -
; .,
' \ ,.
i
------------------TRIANGLE LABORATORIES OF RTP, INC. RUN LOG
MS/I COLUMN TYPE COLUMN 11 ANALYSIS---· ACQ METHOD GC METHOD FIND DB'S OTHER
~ .,::: ~cLIL1-iYJ
.::::
V 1>B5-i?•Z~ 43~J031 J ~ 1. dLc ~tliZ.(
W = 3~N,1, /{fl) IL ml 2. -/Z//,;;/i Z
EXTRACT/ SAMPLE V( L ME
DATE TIME PROJECT# SAMPLE# CLIENT SAMPLE IIJ FILENAME OPEn 0/\Ci<liP
NET 11nc rnoc pll COMMENTS
!
---

-

-

-

-
'1NIIL VOll.L(IILt' = 'Smls
q7.s,:,. t. 2
VD 14'3_ -.51'<!.\.LclJCC A6o/!ff;tJ 31qo51o .:11 z. /.Af'IC m 1J G DV .,
j o/i5
;j_,_'1,,_!,rr"~ I T✓EfiPO~
V'141 \jl){Cj1-.
"<"f trl Stp , Ir> -JqO'.J-o,-,-Pf t}{) /)CJ .,.,__;cgd_
•✓ z_LJ.2./ I
~'
OM --/?fj;_~; ic.:S::, --rfX'"';(g) VD/9!;;,,, / /)I::) O.tJ 1 tiq s,;;,d . . ,
.
O?Sl -22.z../ SS.'7VDSX> CAA V-DiC,& t?'9 [P IYJ§R/
t1/41s
3/18Z.f> q 7 I 1,,0, I (-( fP.J!M1 •
-,I ' &''/%, so. /il:23-£'2. v!;}J aiffli:;,. D JAP.xf/;1 Vt/{t['-1./ Oh Iv I'
~ .. '1"1-151 1 S~5llJO/-s; 1,1:?S/oo,/
I~> 012.l :31q ·J-rp /A-[) .KllN tr I Vof'ft} m w
x~ 97-/S4· 2 s~q5 ,co,;; . .JV?:i"10t 7
1£" ,o<fi 3/ql{p ZA -t> {2µ;,J -ff 2. Vo1q9 w a,
ifi( 311"lv Yl· /s;,j-3 .SV'7{;100"7.SV/51u/;,
Vo200 · 106.3 .31,.-f} f!'tl.Jil:,: Jm_ Oo , . (. 0
W. 3111w , \ ,·H . ..., -I svqfJ:;,o I -:S V'IS 1oc'x/ Jt Ql( PILLfffD~
1/l'){,; 3/l/l88~'
~ •• , u .... , I _,, , _ t'U/V
\l~lf
qJ.,51/. w 3f:,J,f'a~· ·, ·-V(>J.O I l;V w J/1-t) 1£
t%f., -.~ . r• ;t"' I UO (;"-: -5'. IN~/ CDB .5Xx. D/Ul71DiJ ., , JYJ. a.. . . ;~ ri11> ~·, 1 ·lt. '11:,J,.~ -. -i:, fl 17/CI 'fl]~t:-IJiJN 11, V{)ZiJ-;_ );iJ 1?()
a:; ,,.., "(.li//C,~
INTEnNAL STAtlDAnD sunnoGATE STANr>/\nD ANALYTE ST/\tlDARD
l._r_A#G_E..._l __ ::)_;:_,_____,j 347z B ~, 9~ [ I !,____ _____ _,
: !!L Number. 319820 Method 8270 M23
Sample ID: SO-M23-R2
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Sample File: VD197
-
1,4-Dichlorobenzene-d ' Phenol
bis(2-Chloroethyl)ether
2-Chlorophenol
1,3-Dichlorobenzene
1,4-Dichlo~obenzene
1,2-Dichlorobeni.ene
2,2' -oxybis( 1-Chloropro pane)
Benzyl alcohol
2-Methylphenol
3/4-Methylphenol
N-Nicroso-4i-n-propylamine
Hexachloroethane
Naphthalene-cl ' Nitrobenzene
·Isophorone
2-Nitrophenol
2,4-Dimethylphenol
bis(2-Chloroethoxy)methane
Benroicacid
2,4-Dichlorophenol
1,2,4-T richlorobenzene
Naphthalene
4-Chloroaniline
Hexachlorobutadiene
4-Chloro-3-methylphenol
Dilution Factor: 4.00
IS 1
6.67 BJ
u
u
u
2.76 J
u
u
21.87 BJ
u
u
u
u
IS 2
u
u
u
u
u
u
u
u
54.78 B
u
u
u
8.03
8.67
8.94
11 .13
11.17
3.95
2.82
2.48
2.47
5.30
3.55
3.32
6.16
5.54
3.52
1.91
5.11
3.73
3.75
8.73
3.89
3.27
2.70
5.02
4.02
NA-Not Applicable; Det. Limit Detection Limit; Quan. Limit Quantitation Limit
40
40
40
40
40
'40
40
40
40
40
40
40
40
40
40
40
40
100
40
40
40
40
40
40
IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated-Below Quantitation Limit; E: Estimated.; Above Calibration Range
Triangle Laboratories of RTP, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone, [phone] • Fruc [phone]
Sav_ar v3.4a
Printed, 18,24 03/31jl995
I 1 1
==================1
Project Number: 31982D Method 8270 M23
Sample File: VD197 Sample ID: SO-M23-R2
-Dilution Factor: 4.00
I
I
•·.••.··.••.•.• .. ·•.••·.••.•·•••·•• .. ·•.•.• .. •• .. · .. a·•.·•·.•.••·.i·••.••.$•·•·•• .. •• .. •.•·•.··t.•.•.••.•···••.~.•• .. •.•••.••.•.• I I;:.. • .. •• .. •1 •
1 II• !iiii n · !f&•u······· =============================================== 2-Methylnaphthalene 1.93 40
Acenaphthene-d 14.70
u
IS 3 10
Hexachlorocydopencadiene
2,4,6-Trichlorophenol
· 2,4,5-Trichlorophenol
2-Chloronaphthalene
2-Nitroaniline
Dimethylphthalate
2,6-Dinitrotoluene
2,4-Dinitrotoluene
Acenaphthylene
3-Nicroaniline
Acenaphthene
2,4-Dinitrophenol
4-Nitrophenol
Dibenzofuran
Diethylphthalace
4-Chlorophenyl-phenylether
Fluorene
4-Nicroaniline
P:lenanthrene-d
10
. 4,6-Dinitro-2-methylphenol
N-Nitrosodiphenylamine
4-Bromophenyl-phenylethet ·
Hexachlorobenzene
Pentachlorophenol
u
u
u
u
u
u
u
u
u
u
u
u
u
u
2.12 BJ
u
u
u
IS 4
u
u
u
u
u
15.69
17.74
4.65
4.64
4.26
1.82
6.57
1.63
6.16
4.44
1.19
6.34
2.09
13.92
9.56
1.24
3.03
1.67
6.34
9.41
2.99
5.59
4.61
7.58
NA-Not Applicable; Det. Limit: Detection Limit; Quan. Limit Quantitation Limit
40
40
40
40
100
40
40
40
40
100
40
100
100
40
40
40
40
100
100
40
40
40
40
IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated-Below Quantitation Limit; E: Estimated-Above Calibration Range
Triangle laboratories of RTP, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone, [phone] • Fax, (919) 544--5491
Savar v3.4a
Printed: 18,24 03/31_/1995
I
I
I
I
I
I
I
I
I
I
I
I
I
I. Project Number: 31982D
Sample File: VD197
Method 8270 M23
Sample ID: SO-M23-R2
·-I
I
I Phenanthrene
Anthracene
I Oi-n-bucylphchalace
Fluoranthene
Chrysene-d 12
I Pyrene
Bucylbenzylphchalace
3,3' -Dichlorobenzidine I bis(2-Echylhexyl)phchalace
Benzo(a)anthracene
I Chrysene
Perylene-d " Di-n-occylph chalace
I Benzo{b)fluoranthem::
Benzo(k) fl uoran chene
Benzo(a)pyrene
I Indeno(l ,2,3-cd)pyrene
D ibe nz( a. h)an chracene
Benzo(g,h,i)perylene
I
I
I
I
I
Phenol-d ,
Nicrobenzem:-d ,
1.3,5-Trichlorobenzene-d
t ,4-Dibromobenzene-d4
'
Dilution Factor:
u
u
21.42 BJ
u
IS 5
u
u
u
14.90 J
80.16
82.38
70.75
88.30
u
u
IS 6
u
u
u
u
u
u
u
4.00
1.29
1.36
19.08
1.29
23.17
1.22
2.67
4. 18
23.38
1.45
1.50
26.51
1.45
1.77
I.SO
1.87
1.85
2.42
2.14
8.01
9.71 2
10.39 2
11.24
NA• Not Applicable; Del Limit: Detection Limit; Quan. Limit: Quantitation Limit
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
80
82
71
88
IS: Internal Standard; U: Undetected; 8: Present In Blank; J: Estimated-Below Quantitation Limit; E; Estimated-Above Calibration Range I Triangle Laboratories of RTP, Inc.
I
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-Sn9 • Fax: [phone]
Savar v3.4a
Printed: 18:24 03 /3V 1995
23
Project Number: 31982D
Sample File: VD197
2-Fluorobiphenyl
2,4,6-Tribromophenol
Anthracene-d
10
Pyrene-d · . 10
Reviewed by--------~~--
Dilution Factor: 4.00
85.31 13.37
71.60 16.32
80.61 17.86
86.20 20.64
Date l__1_][J_2.$
Method 8270 M23
Sample ID: SO-M23-R2
3 85
3 72
4 81
5 86
NA-Not Applicable; Del Limit Detection Limit; Quan. Limit Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated-Below Quantitation Limit; E: Estimated-Above Calibration Range
Triangle Laboratories of RTP, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: [phone] • Fax: [phone]
Savar v3.4a
Printed: 18:24 03/3l/!995
24
I
I
I
I
I
I
I
I
I
I
I
I
I
I:
I
I
I
I
I
I
I Project Number: 31982D
Sample File: VD187
Method 8270 M23
Sample ID: BLANK
I
I
I
-
I
I
I
I
I
I
I
I
I
I
I
I
I
I ,4-Dichlorobenzene-d4
Phenol
bis(2-Chloroethyl)ether
2-Chlorophenol
1,3-Dichlorobenzene
1,4-Dichlorobenzene
• 1,2-Dichlorobenzene
· 2,2 '-oxybis( 1-Chloropropane)
Benzyl alcohol
2-Methylphenol
3/4-Methylphenol
N-Nicroso-di-n-propylamine
Hexachloroc:thane
Nap hthalene-d,
Nicrobenzene
Isophorone
2-Nitrophenol
2.4-Dimethylphenol
bis(2-Chloroethoxy)methane
Benzoic acid
2,4-Dichlorophenol
, 1,2,4-Trichlorobenzene
Naphthalene
4-Chloroaniline
Hexachlorobucadiene
-4-Chloro-3-methylphenol
Dilution.Factor: 4.00
IS I
3.35 BJ
u
u
u
u
u
u
67.25 B
u
14.93 J
u
u
IS 2
u
u
u
u
u
I 05.54
u
u
47.79 B
u
u
u
8.66
8.06
8.96
9.51
11.15
10.72
11.19
3.82
2.73
2.37
2.34
2.40
5.07
3.36
5.81
5.29
3.40
1.89
4.87
3.42
3.52
3.63
3.08
2.60
4.76
3.90
NA-Not Applicable; Det. Limit: Detection Limit; Quan. Limit Quantitation Limit
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
JOO
40
40
40"
40
40
40
IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated-Below Quantitation Limit; E: Estimated-Above Calibration Range
Triangle Laboratories of RTP, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone, (919) 544-5n9 • Fax, [phone]
Savar v3.4a
Printed, 18,24 03/31/1995
3B
Project Number: 31982D
Sample File: VD187
2-Methylnaphthalene
Acenaphthene-d IO
Hexachlorocyclopentadienc:
2.4,6-Trichlorophenol
2,4,5-T richlorophenol
2-Chloronaphthalene
2-Nicroaniline
Dimethylphchalate
2,6-Dinitrocoluene
2,4-Dinicrocoluene
Acenaphthylene
3-Nitroaniline
Acenaphchene
2.4-Dinirrophenol
4-Nirrophenol
Dibenzofuran
Diethylphchalace
4-Chlorophenyl-phenylether
Fluorene
4-Nitroaniline
Phenanthrene-d IO
4,6-Dinitro-2-merhylphenol
N-Nicrosodiphenyl~ine
4-Bromophenyl-phenylether
Hexachlorobenzene
Pentachlorophenol
Dilution Factor: 4.00
u 1.86
IS 3 14.72
u 4.27
u 4.36
u 4.27
u 1.80
u 6.93
u 1.63
u 6.15
u 4.66
u I. 13
u 6.61
u 2.04
u 12.79
u 10. 11
u 1.24
6.46 BJ 15.71
u 3.11
u 1.62
u 6.85
IS 4 17.76
u 8.53
u 2.77
u 5.21
u 4.36
u 8.20
·NA-Not Applicable; Det. Limit: Detection Limit; Quan. Limit Quantitation Limit
Method 8270 M23
Sample ID: BLANK
40
40
40
40
40
100
40
40
40
40
100
40
100
100
40
40
40
40
100
100
40
40
40
40
IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated-Below Quantitation Limit; E: Estimated-Above Calibration Range
Triangle Laboratories of RTP, Inc.
. 801 Capitola Drive • Durham, North Carolina 2m3
Phone, (919) 54.J..Si29 • Fax, (919) 544--5491
Savar v3.4a
Printed: 18,24 03/31/1995
39
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I Project Number: 31982D
Sample File: VD187. ·
Method 8270 M23
Sample ID: BLANK
:-Dilution Factor:
I
I Phenamhrene
Anthrac.c:ne
I Di-n-bucylphthalace
Fluoranthene
Chrysene-d 12
I Pyrc:ne
Bucylbenzylphthalace
3,3 ' -Dichlorobenzidine I bis(2-Echylhexyl)phthalace
Benw(a)anrhracene
I Chrysene
Perylene-d 12
Di-n-octylphthalace
I Benzo(b)fluoranthene
Benzo(k)fl uoran chene
Benzo(a)pyrene
I Indeno(l .2.3-cd)pyrene
Dibenz(a,h)anchracene
Benzo(g,h,i) perylene
I
I Phenol-cl,
Nitrobenzene-d5
I 1,3,5-Trichlorobenzene-d
-1,4-Dibromobenzene-d
3
4
I
I
7.39
2.37
70.31
65.08
70.89
u
u
BJ
u
IS 5
u
u
u
J
u
u
IS 6
u
u
u
u
u
u
u
4.00
19.10
23.18
23.39
26.53
8.03
9.73
10.41
11.26
1.22
1.27
1.23
1.21
2.70
4. 18
1.4 I
1.50
2. 13
2.37
2.65
2.59
2.36
3.08
2.78
1
2
2
NA-Not Applicable; Det. Limit: Detection Limit; Quan. Limit: Quantitation Limit
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40 ·
40
40
70
65
71
IS: Internal Standard; U: Undetected; B: Present In Blatlk; J: E.!timated-Below Quantitation limit; E: Estimated-Above Calibration Range I Triangle Llbor.1tories of RTP, Inc.
:1
I
801 Capitola Drive • Durham, North Carolina 27713
Phone, [phone] • Fax, [phone]
Savar v3..la
Printed, 18,24 03/31/1995
. Project Number: 31982D
Sample File: VD187
Method 8270 M23
Sample ID: BLANK
-Dilution Factor: 4.00
2-Fluorobiphenyl 72.73 13.38 3 73
2,4,6-Tribromophenol 77.11 16.34 3 77
Anthracene-d 64.56 17.87 4 65 JO
PyreneCd
JO 86.70 20.66 5 87
pt, Reviewed by _________ _ D_ate 7;, / Jl.1 .Ji_
NA-Not Applicable; Det. Limit Detection Limit; Quan. Limit Q~antitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated-Below Quantitation Limit; E: Estimated-Above Calibration-Range
Triangle Laboratories of RTP~ Inc.
801 Capitola Drive • Durham,. North Carolina 27713
Phone, [phone] • Fax, [phone]
Sav.u-v3.4a
· Printed: 18'24 113/31/1995
41 -." .. :
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I Project Number: 31982D
Sample File: VD185
Method 8270 XAD
Sample ID: SBLK 032195
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
-
J ,4-D ichlorobenzene-d,
Phenol
bis(2-Chloroethyl)ether
2-Chlorophenol
1,3-Dichlorobenzene
J ,4-Dichlorobenzene
1,2-Dichlorobenzene
2,2' -oxybis( 1-Chloropropane)
Benzyl alcohol
2-Methylphenol
3/4-Mechylphenol
N-Nicroso-di-n-propylamine
Hexachloroethane
Naphthalene-cl 8
Nicrobenzene
lsophorone
2-Nitrophenol
2,4-Dimechylphenol
bis(2-Chloroethoxy)methane
Benzoic acid
2,4-Dichlorophenol
1,2.4-Trichlorobenzene
Naphthalene
4-Chloroaniline
Hexachlorobucad.iene
4-Chloro-3-methylphenol
Dilution Factor: 4.00
IS I
0.77 J
u
u
u
u
u
u
0.87 J
42.89
u
u
u
u
IS 2
u
u
u
u
u
u
u
u
u
u
u
8.66
8.04
8.96
I I.I 5
11.19
4.23
3.03
2.62
2.59
2.66
5.62
3.73
3.53
6.44
5.86
3.65
2.02
5.22
3.67
3.77
8.30
3.89
3.30
2.79
5. 10
4.18
NA• Not Applicable; Del Limit Detection Limit; Quan. Limit: Quantitation Limit
40
40
40
40
40
40
40
40
40.
40
. 40
40
40
40
40
40
40
100
40
40
40
40
40
40
IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated-Below Quantitation Limit; E: Estimated-Above Calibration Range
Triangle Laboratories of RTP, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone, [phone] • Fax, [phone]
..... ···--------·-·-·· ------'---·------·---·--··-·-
Savar v3.4a
Printedc 18,23 0,/31/1995
55
I
Project Number: 31982D
Sample File: VD185
Method 8270 XAD I
Sample ID: SBLK 032195
-Dilution Factor: 4.00
2-Methylnaphthalene u 1.99 40
Acenaphthene-d10 IS 3 14.72
Hexachlorocydopentadiene u 4.39 40
2,4,6-T richlorophenol u 4.48 40
2,4,5-T richlorophenol u 4.39 40
2-Chloronaphthalene u 1.85 40
2-Nitroaniline u 7.12 100
Dimethylphthalate u 1.67· 40
2,6-Dinitrotoluene u 6.32 '· 40
2,4-Dinitrotoluene u 4.79 40
Acenaphthylene u 1.16 40
3-Nicroaniline u 6.80 100
Acenaphchene u 2.10 40
2,4-Dinitrophenol u 13:14 100
4-Nitrophenol u 10.39 100
Dibenzofuran u 1.28 40
Diethylphthalate 1.51 J 15.71 40
4-.Chlorophenyl-phenylether u 3.19 40
Fluorene u 1.66 40
4--Nitroaniline u 7.04 100
Phenanthrene-d 10 IS 4 17.75
4,6-Dinitro-2-methylphenol u 9.02 100
N-Nirrosodiphenylamine u 2.93 40
4-Bromophenyl-phenylether u 5.52 40
Hexachlorobenzcne u 4.62 40.
Pentachlorophenol u 8.68 40
NA-Not App1icable; Det. Limit Detection Limit; Quan. Limit Quantitation Limit
IS: Internal Standard; U: Undeteci:ed; B: Pre.,ent In Blank; J: Estimated-Below Quantitation Limit; E: Estimated-Above Calibration Range
Triangle Laboratories of RTP, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: [phone] • Fax: [phone]
Savar v3.-l-a
Printed, 18:23 03/31/1995 5G
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Project Number: 31982D
Sample File: VD185
Method 8270 XAD
Sample ID: SBLK 032195
:-Dilution Factor: 4.00
•• ·.: .. : ..• ,.:,.:.,.:,.~·-.··• .. '..,.::'.•···:,.'..,.:, .. :.,.P .. '.:::'.:._.:.•.::::.'. •. ~ .. :: .. :::::~'.~ ... ~-.:::····e::~'.~ ... :,·.:::~'.~--.. :,.t::;·,·.l·,_~-.t·_ .• _~::f',~-:r,.r:::'.i::~·::::['.~:.i,.t .. :~· .. i:.r •. \, .. 1 .. ;,.:,.~·-.~-_;:.l .. ~ •. i,.:: .. :·.··1:,.~,.:, .• : •. ~::•·.;~1::.: .. 1:.~.:::.i.:.~.:.i,c!: '-~ ,, , ' : ~ , : ;;~~ :-(i{ ~~<❖~?; €~J~❖ ~: y>. FLAG, -:~:~S~(*~~Rm:, ~ ; ~~-' -;~w~' DetY L~i ~ \>❖~:><:~~~,:{!;;ab: <jjii,){ ~ . ~->:·· -·-:-:::·:·:·~·-:· :~_·:_-:._~:· --,·----,t ~/~~~<;::~yZJ)\f~, :< : ,-'>:,,~;?:'?f~{~ii;p ?f./~,z~:-~;;:,:;:/~?:~s-~-~/)1::tt~{:::i~~~~,~ ~:-~~?~\~i~~ .
Phenam.hrene
Anthrac,ne
u 1.29 40
I Di-n-but)'lphthalate
Fluoranthene
Chrysene-d 12 I Pyrcne ·
Butylbenzylphthalate
3.3' -Dichlorobenzidine I bis(2-Ethylhexyl)phthalace
Benzo(a)an thracene
I Chrysene
Perylene-d 12
Di-n-octylphthalare
I Benw(b)fluoranthene
Benzo(k) fl uoran thene
Bcnzo(a)pyrene
I lndeno(l ,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i) perylene I
I Phenol-d5
Nitrobenzene-d ,
I l,3,5-Trichlorobenzcne-d3
l .4-Dibromobcnzene-d4
I
I
u 1.35 40
13.32 J 19.10 40
u 1.31 40
IS 5 23.18
u 1.22 40
u 2.73 40
u 4.23 40
u 2.23 40
u 1.43 40
u 1.52 40
IS 6 26.52
u 1.39 40
u 1.54 40
u !.72 40
u !.69 40
u 1.54 40
u 2.01 40
u 1.81 40
73.38 8.01 I 73
69.23 9.73 2 69
63.72 10.40 2 64
79.53 11.26 80
NA-Not Applicable; Det. Limit: Detection Limit; Quan. Limit: Quantitation Limit
I . IS: Internal S~ndard; U: Unddected; B: Present In Blank; J: Estimated-Below Quantitation Limit; E: Estimated-Above Calibration Range
Triangle La.bora.tones of RTP, Inc. .. · Savar v3Aa
· 801 Capitola Drive• Durham, North Carolina 27713 Printed: 18:23 03/31/1995 I Phone: [phone] • Fax: [phone]· ·
Project Number: 31982D
Sample File: VD185
Method 8270 XAD
Sample ID: SBLK 032195
-Dilution Factor: 4.00
2-Fluorobiphenyl 73.03 13.38 3 73
2,4,6-Tribrornophenol 77.77 16.34 3 78
Anthracene-d 83.48 17.87 4 83 IO
Pyrene-d
. IO 83.00 20.66 5 83
Reviewed by _______ ~-----Date _}_1 .lL1ii_
NA-Not Applicable; Det. Limit: Detection Li~it; Quan. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected; B: Pre.sent In Blank; J: Estimated-Below Quantitation Limit; E.: Estimated-Above Calibration Range
Triangle Laboratories of RTP, Inc.
801 Capitola Drive • Durham, North C.irolina 27713
Phone, (919) 544-5n9 • Fmc [phone]
Sa.var v3.4a
Printed, 18'23 03/31/1995
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
APPENDIX Q
I PCB's LABORATORY DATA
I
I
I
I
I
I
I
.I
11
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
CASE NARRATIVE
TRIANGLE LABORATORIES OF RTP, INC.
801 Capitola Drive
Durham, N.C. 27713
Phone: [phone]
Fax: [phone]
DATE: March 31, 1995
TLI NO.: 31982C
OBJECTIVE: Detennine the polychlorobiphenyl (PCB) content of two M23 trains.
METHOD:
Two M23 samples were received at Triangle Laboratories of RTP, Inc. at ambient tem-
perature and in good condition on March 18, 1995 and were stored at 4C prior to extraction. ·The
M23 train samples were extracted and analyzed according to the guidelines of Method 680.
Prior to extraction the XAD traps, filters, and solvent rinses were spiked with one microgram
(ug) of 13C-3,3' ,4,4' -tetrachlorobiph~nyl and 13C-2,2' ,3, 3' ,5,5' ,6,6' -octachlorobiphenyl as
internal standards. These M23 train portions were Soxhlet extracted for 16 hours with methylene
chloride. The condensate rinses and the water portions of the samples. when present, were
spiked with one ug of 13C-2,2' ,4,4' ,5,5' -hexachlorobiphenyl and extracted with methylene
chloride using a separatory funnel. The extracts were split with twenty-five percent being used
for the Method 680 PCB analysis. Samples were concentrated to one milliliter (mL) for this
analysis. Immediately prior to GC/MS analysis, ten micro liters of each of the two recovery
standards 13C-2;2' ,5,5' -tetrachlorobiphenyl and 13C-3,3' ,4,4' ,5,5' -hexachlorobiphenyl were
added to 100 uL of extract so that the final recovery standard concentration was 1.0 ug/mL. The
results reported relate only to the items tested. ·
The analysis was done on a HP 5971 mass selective detector, and HP 5890 gas chroma-
tograph. The mass spectrometer was operated at an ionizing energy of 70eV, in selected ion
recording mode. A 30m DB-5 column (0.32mm id ; 1 u film) directly inserted into the ion
source was used for the analysis. A 1.0 uL aliquot of the extract was injected splitless onto the
column at 60 C (1 min hold), programmed at 30 C/minute to 120 C, then at 6 C/minute to 250 C,
then at 10 C/minute to 300 C and held 6 min.
A calibration curve for the mono-deca chlorinated biphenyls was generated using a
mixture of specific isomers (EPA Method 680; Anal. Chem., 58, 2014-2022, 1986). Also includ-
ed was the 2.2' ,3,3' ,4,4' ,5,6,6' -nonachlorobiphenyl isomer. The response factors for the mono-
penta PCBs (versus the 13C-3,3' ,4,4' -tetrachlorobiphenyl) and for the hexa-deca PCBs (versus
he 13C-2,2' ,3,3' ,5,5' ,6,6' -octachlorobiphenyl) were calculated using the following equation:
(Area M + Area M+2) * Amt IS
RF = -----------------------------------------------------
( Area IS M + Area IS M+2) * Amt Analyte
1
1
TRIANGLE LABORATORIES OF RTP, INC.
CASE NARRATIVE
Where:
Area M = the area of the peak corresponding to the mass M
Area M+2 = the area of the peak corresponding to the mass M+2
Arnt IS = the amount of internal standard added = 1 ug
Arnt Analyte = the amount of analyte in the calibration point
March 31, 1995
31982C
In order to maximize sensitivity, the hexa-deca PCBs used the areas of the M+2 and M+4
ions to calculate their response factors. ·
Response factors for the internal standards versus their recovery standard were calculated
in order to measure the recovery of the standards. The response factors are summarized in the
initial calibration table. All calibration data is located at the back of the data package.
Any PCBs found in the sample were quantitated using the following equation:
(Area M + Area M+2) x Arnt IS (ug)
Arnt (ug) = . ---------------------------------
(Area ISM+ Area IS M+2) x RF
In the case of the hexa-deca PCBs, the areas of the M+2 and M+4 peaks are used ·for
quantitation.
A continuing calibration was run prior to each sample analysis. The response factors in
the continuing calibration must be within 25% of those in the initial calibration. However. the
mean response factors from the initial calibration were used for all sample calculations.
The retention time windows for each degree of chlorination were established by means of
a retention window mixture supplied from Cambridge Isotope Labs. This mixture contains the
first and last eluting isomers for each degree of chlorination when analyzed on a DB-5 column.
The compounds contained in this mixture are: 2-monochlorobiphenyl; 4-monochlorobiphenyl;
2,6-dichlorobiphenyl; 4,4' -dichlorobiphenyl; 2,4,6-trichlorobiphenyl; 3,4,4' -trichlorobiphenyl;
2,2' ,6,6' -tetrachlorobiphenyl; 3,3' 4,4' -tetrachlorobiphenyl; 2,2' ,4,6,6' -pentachlorobiphenyl;
3,3' ,4,4' ,5-pentachlorobiphenyl; 2,2' ,4,4' ,6,6' -hexachlorobiphenyl; 3,3' ,4, 4' ,5,5'-hexachlorobi-
phenyl; 2,2' ,3,4' ,5,6,6' -heptachlorobiphenyl; 2,3,3' ,4,4' ,5,5' -heptachlorobiphenyl;
2,2' ,3,3' ,5,5' ,6,6' -octachlorobiphenyl; 2,3,3' ,4,4' ,5,5' ,6-octachlorobiphenyl; 2,2' ,3,3' ,4,
5,5' ,6,6' -nonachlorobiphenyl; 2,2' ,3,3' ,4,4' ,5,5' ,6-nonachlorobiphenyl; and decachlorobiphenyl.
The retention time window data is included in the calibration data located in the back of ·
the data package.
If no signal is observed in a given mass channel, the detection limit is estimated by using
a summed peak area. This is found by estimating the noise level of an empty mass channel. A
formula developed in-house was used to estimate the detection limit area. This formula is as
follows:
2
.. 2
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
;I
I
I
I
I
I
I
I
I
I
I
I
.I
I
I
I
"I
I
TRIANGLE LABORATORIES OF RTP, INC.
CASE NARRATIVE
. DL= Abundance x (2) x (2.5)
------------------------
31.2
Where:
March 31, 1995
31982C
Abundance = a measure of the ion current intensity which is found on the y-axis of the chroma-
tograms minus the background abundance.
2 = factor that accounts for the two ion traces monitored for each PCB
2.5 = factor that accounts for signals needing to be at least 2.5 times the noise level to be quanti-
tated with 95 percent confidence
31.2 = a factor converting the abundance into an integrated ion current representing peak area.
empirically derived in house from evaluating 50 individual genuine PCB peaks.
If matched sets of peaks in the time window do not have the appropriate ion mass ratios
for a true PCB, the estimated maximum possible concentration (EMPC) is calculated using the
summed areas of the observed peaks. If one peak is much larger than the other, thus causing
artificially high EMPC values, the summed area is based upon the smaller peak area, and the
other area is calculated using the theoretical PCB isotope ratio. The channel will be flagged with
"Recalc" in this case. If peaks are detected as PCBs, and others are observed with an incorrect
ratio, the EMPC_is the sum of these two values.
On the quantitation report for each sample, the results are expressed as total amount in ug
and have been corrected for the internal standard recovery. The "Number" is the number of PCB
isomers observed for a given degree of chlorination; "DL" is the detection limit in ug; "EMPC"
is the estimated maximum possible concentration in the same units.
"Ratio" is the measured ratio of the M to M+2 ions (or M+2 to M+4 for the hexa through
deca PCB' s) and "RT" is the retention time in minutes and seconds for any specific isomers. The
acceptable range of ratios for the isomers are:
mono
di
tri
tetra
penta
RATIOS (Ml M+2)
2.51 -3.62
1.25 -1.81
0.84 -1.21
0.63 -0.91
0.50 -0.72
RATIOS (M+2/ M+4)
hexa 1.01 -1.45
hepta 0.84 -1.21
octa 0.72 -1.03
nona 0.64 -0.92
deca 0.56 -0.81
3 3
TRIANGL_E LABORATORIES OF RTP, INC.
CASE NARRATIVE "'
. RESULTS:
March 31, 1995
31982C
The laboratory blank contained decachlorobiphenyl and dichlorobiphenyl EMPC peaks.
In the case where the amount of analyte detected in the sample is less than twenty times the level
of that analyte in the blank, the analyte detected in the sample is flagged "B". It is important to
not attribute blank contamination to the amounts reported which are due to peaks at a different
. retention time than that found in the blank.
Please note that the impinger catch, 00148, for the field blank was not listed on the client
chain of custody. This sample portion was extracted and analyzed with the remainder of the field
blank.
All samples were extracted and analyzed within sampling to extraction and extraction to
analysis holding times. ·
All internal standard and hexachlorobiphenyl alternate standard recoveries were within
the advisory quality control limits for an air matrix for all samples and blanks. ·
This report should only be reproduced in full. Any reproduction of this report requires
permission from Triangle Laboratories of RTP, Inc. Should you have any questions about this
project. please feel free to contact our Air Quality Client Services Manager, Hani Karam, at
[phone].
For Triangle Laboratories of RTP, Inc.,
Report Preparation: Quality Control:
Eileen Winchester Selena Armistead
Report Preparation Chemist Report Preparation Chemist
The total number of pages in this data package is / ?Jj .
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
.,
1
')
C
l
.
C
' ,;
"
)
----------
' SAMPLEJl'S SIGN/\TURE _.2JdtMd-:_~
.. ..
CLIEHf CHAIN OF CUSTODY Quote 1100000961
Fnwru 1,IS, INC. Cunlut: "IURRY WILLIAMSON T olal Number of Anafynls Wmllod:
MUI MUNICll'AI. DRIVli r,.,,.., 7113-2fMJ004 Contaloors: j); &/1,nJ, /Furq;Jj, ·
ROANOKE, VA 24012 ·;,.,c 7113-265-0:31 . Pct.J>
ITI,j,<t /'le,,lq-1,-, -I-( r,,, ,/, l'.0.1: II f )-'11> LiST
(ETS02nlK)
.. . ·• ..
STANO. u:11 .. 11nm Com11 Gmh Snmp"' kl.ff S.-implo Ami. nnm,uk!I
'J.-/7 /'(OD / /Ji, P,· 1f.,,. So -l>i,,J,J -I?. .L
-----13'} ft-I f r-i,, .,, {{. J
/ !Ti n/ ..
_..., I ~ 9 .fu.f I
---{ 'f -:;;.,P.. I • 0 ;t ..... ~
,---l'i J f,+P --
,I/
.
/ It,/ !f P,11-t,-If {c,,-,(
--/IJl
Q,,1,,,,/ I
·t-/'ltC/4
,,---1.117 JO~tA(
/ -/ I{ 'l ll'v."· • . . u / /5" );_ ~ /I" V
V,, r
.. . ·-------. T/ ;1. . . .. ---.. .. ·-. . --. . . . . . ..
1lnllnrr1hhod Dy/Sign. D11WTll1Mt ll.-ct!IYl!d Dy/Sign. no1111qulshod Dy/Sign. Dnlofflm" llPCPlvtld By/Sign.
v · ~ 11. 1. ?·/f-u ------
llollnqu(shod Dy/Sign. OalofTilne llocolYl!d Uy/Sign. nelinquished By/Sign. DnlNTlmo llecehred By/Sign.
-. -. -. -·41~-D,.l!/flmo Serlll Samplt.,,; to: Trfanglo Laboratorle!I, Inc.
"3/f&/~ l\lln: S11mple Custodian
801 Cnpllnln Drive
11:(D Durham, NC 27713 US/I.
Phone: [phone] • Fax: [phone]'191 -------------

-

-

-

-
-------------------
I ' SAMPLER'S SIGNATURE~ I CLIENT CHAIN OF CUSTODY P/Q 01667/1100000961
\()
From: ETS, INC. c .. ntact: TERRY WILLIAMSON Total Number of Analysis Wanted:
1401 MUNICIPAL DRIVE l'h<>ne: 703-265-0!HJ4 Containers:
ROANOKE, VA 24012 Fax: 703-265-lllJI
r«;ect: />\ 1 lo ..--, " · J/ 4 ..,r l'.O.!: 5408 I
(ETS02/HK)
STA NO. Dnln Tlmo Comp Grnh Smnple Id.ff Smnplo Amt. Romnrks
J-,7 /?dD / :..~p
I :;'I )-~ c,1. I ;,d -/77;. J c/t 2
.
'
.
.
Rellnqulshed B/,Slgn. DalefTlme Received By/Sign. Relinquished By/Sign. Dale/Time Received By/Sign.
~ 7/4 ', ./ )/(//fs' /1:L ;'
. -
R~llnqubhed By/Sign. DatefTime Received By/Sign. Relinquished By/Sign. Dale/Time Received By/Sign.
Received for Laboratory By/Signature Date/Time c-Send Samples to: Triangle Laboratories, Inc.
-< . ~ ~//"ir°(?':? -Attn: Sample Custodian ;~'1< -:~-II'. /0 801 Capitola Drive
Durham, NC 27713 USA
. Phone: [phone] • Fax: [phone]
I
I
I
I
I
I
I
I
I
I
I
I
I
I
.I
I
I
I
PAGE 1 Of '.
Custoav Seal Absent Sa■ele Seals:. Aosent : iLI Project Hu ■oer : 31982 Boo,
cnain of Custoav : Present +--------------------+-----------------------------------+
: Samele Tags : Present : Client: ETS02 : ETS, !NC. 97
: Samele Tag Nuoeers: Listea · +--------------------+---------------------:u-----~-----i !---SftO _Forms---------:_ HI A----------------------------------------l-Oa te _Received _____ ;_ 03/ 18/95 --l-Bylu~ ___ ; Page :
Box HO COOLANT ' Carrier.and Huaber : TONY UNDERWOOD : 160
+-----------------------------------+-----------+-----------+-----------+-----------+-----------+-----------+---······--+-----------+ : TL! Number ftatrix : To LAB : To STORAGE: To LAB : To STORAGE; To LAB : To STORAGE: To LAB : To STORAGE:
: 1R/H:CPN · Client ID Location : Oate/Init : Oate/lnit : Date/Init : Oate/lnit : Date/Init : Oate/Init : Date/Init : Date/lnit :
+---------------------·-·········---+-----------+-----------+-----------+-----------T-----------+-----------+-----------+-----------+
97-160-lA FILTER '
00136 SO-M23-R2 +-----------+-----------+-----······~-----------t-----------+-----------+-----------+-----------+
CO2 1
+-----------------------------------+-----------+-----------+-----------+-----------•-----------+-----------+--------·-·+------·---·+
97-160-1B XAO '
00143 SO-M23-R2 +·--··--·---+···--······+-··--------+----·-····-+--····-·-·-+--------·-·+----·-·-··-+·---·-----·+ co: I
+-------------·------·----·----·----+----·-·-·--+--·-·--·--·+--·--------+--·-·------+-----·-·-·-+--·-----·--+··--·--···-+-··------··+
' 97-160-lC FH/ACE/M,:L2 '
00137 SO-M23-R2 +-----------+-----------+--·--------+-----------+-----------•-----------+-----------+-----------+
,.. "I I ... v,
+-·---------·-·-·-------·----·-·----+·--------·-+·----·-----+·-·-·-·-··-+--·--·-----·-------··-·+···--------+·-·--···---+-··-·--·-·-t
97-160-10 FH/TOL R!NS,
00138 SO-M23-R2 +---·------·+------··-·-+·----·-·•--:---·---·---+-----------+---------·-+·-····-----+-----------+
CO2 1
+-----·-----·--------·-----·-·-··--·+--··-··-·--+-------··--+···-··---·-·---·----·--:·----·--·--.--·····----+--·-·------+----··-·--·+
' ' '
97-160-lE
00139 S0-M23-R2
IMP 1 ' ' ' +----·---·--+-----·-----+--------·-·+--·-·---·--.------·----+·----------+-·--·--·-·-+-----·---•-♦
ccz
+------------··----·---·----·--·-···+--·-···-·-·+-----------+·--·----·-·--··--------+---·----·-----·-------·+---··-----·•······-----+
' 97-160-lF TOLUENE RINSE '
00140 SO-M23-R2 +-----------+-----------•·--··-·----:•--·-------.----------•:••--·------:•----------+------·----:
+-----------···-·-~···r----···-----+----·--···-+-------··--+·----·-·-·------------·•----·--·-·-·---··-·-··-+---------·-+-··-·-·-·--+
: 97-160-j('jG ~~\"\'? IMP Z-t : : : : : : : : :
154 SO-M2J·R2 +-----------+----------·•-----------,----------------------+-----------+-----------+----------·+
, CO2 :
+----····----····-·---------·----·--+···-·-···--+·---··-----+-----------+-------·---•---·--· ----+---·-------+·----------+-·---------+
' 97-160·2A f!LiER '
00145 BLAH>
co:
t-•••••••••••••••••••••-••••••••••••T••••••-••••+••••••••-••f•••••--••••T••••-•••••••••••••••-•-+•••••-----•f-•--•••••••f•••••••••••t
97-160-2B XAQ
+ .--·-·----·-----~-·-·--··----------+-----·-----+----------··------····-+--------·--+·------·-·-+--·----··--+----··-----+-----------+
' 97-160-lC FH/~CEIMEC,2
00146 Sl~NK +··-··------+·-·--·-···-•--------·--+-···-·-----•-··-·----·-+---·-----·-+----------· +---·----··-•
' co:
+------··----··-·-----··-~------··--+·--·-----··+-·--···--·-·--·····--•-:-------·-·-+-·---------···--.------+------·----+--··-------•
' Receiving Re,arts: Client's Chain of Custody differs fro• ,r,,t the laoole IDs reac: used the !Os on sa•ole to log in.
All client sa■ole IDs preceaed b·, ·9,-J,:-·.
: Ar.chive Re111arks: ,
+-------------·----------·---------TRIANGLE LABORATORIES. !NC.-·CHAIN Of CVliOOY--REViSEO 02/17/0 5------------------------·--]---··t
-,
PAGE 2 Of 2
~------------------------------------------------------------------+--------------------•------------------------·-----------+-----+
Custod,· Seal Absent Sa ■ole Seals: Absent ; TL! ProJect Muooer : 31982 ' Book
cnain of. Custody Present +--------------------+------------------------------------+
, Saacle Tags . Present : Client: ETS02 : ETS. IMC. , 97 ,
' Saaole Tao Nu1bers: Listed +--------------------+-------------------;---~--~---+
; ___ s~o_roros _________ :_HIA ________________________________________ ;_Date_Received ______ ;_o3/18/9S __ ;_Bv4~::: __ ; Page ;
' Box NO COOLANT : Carrier and Nu10er : TONY UNDERWOOD : 160
+-----------------------------------+-----------+-----------+-----------+-----------+-----------+-----------+-----------+-----------+
: TL! Huaoer
: 1R/H:CPM Client ID
~atrix ' To LAB ' To STORAGE: To LAB : To STORAGE: To LAB : To STORAGE: To LAB
Location ' Oate/lnit Oate/lnit : Date/lnit : Date/Init : Oate/Init : Date/lnit : Date/!nit
: To STORAGE:
: Date/lni t : +--------------------------·---------+-----------+-----------+-----------+-----------+-----------+-----------+-----------+--,--------+
9i·l60·20 fH/TOL RINSE '
00147 BLANK
CO2
+-----------------------------------+-----------+-----------+-----------+-----------+-----------+-----------+-----------+-----------+
' 9i-l60·2E
00148 BLANK
IMP 2·4 ' ' ' ' +·-·-·---·-·•··-·--·--·-+--·-·······+-·-········+-·-·--···-·+-·-··--·-··+-··-·····-. f·-·-·······+
CO2 ' ' +---------·---·· -·--···---·-·-·--·--:••·········+-·--···-···~···-····--+-·.········+-·-····-···+···-··--·--+··--·--····+···········+
I 97·16O·2F TOLUENE RINSE j ' : I I I I . 1 I
00149 BLANK +···--······+···········+····-···---+···········+···········+·-·-·-·--·-+···· .······+···-·-·····+
CO2 1
+-·················-·--·---·. ····•--:••·-·-·-··-+········-··+---·-----·-•·-----··-··+·····--··--+--··-·-·-·-+-----------+·-········-+
' ' t-··•·•···························••:•-·•·······♦··••··-·•··+···········T·········••:••••·•·····••···••••••·•·••••·••·•••··•········•
' f•••••••••••••••••••••••••••••••••••T•••••••••••T•••••••••••f•••••••••••·•••••••••••~•••••••••••t••-••••••••♦•••••••••••••••••••••••t
+·-········--··--··--····---·-····•-.•-··-···---•···-·······+·--····--··•····· ···-·-·---·-····--+··---·····. +·····-.·-·-+--·--····--+ ·, '
' ' T••·••·•····t···•••·····••··········♦--···••••··•····•······t••••·······•········•••t••·········•
T········•··••••••••···········•··•·•····-•·•···•·-·••·•••··t··-········•··•····••··+-··•••••···•• ·····•····t·-·-·······t--··•·••·••t
'
I
I
I
I
I
I
I
I
I
I
I
I
I
I
+··--·····••f·•·········•···········T····-·····•♦•-·········~---··---··-+·······-···~----·······+ I
' ' +··-··········--·········--····--·-····-···-····+··---··--···----·---·•-f••---·············----·+· ··--·-··-·+·-······-··+·--·-······+ . . I ' ' ' +··-··------:--•---···--+--··--···-·+-······---·+--········-+·-------·-·+-··-.-·-·-·+·····-···. -+
' ' ' ' +••••••••••••••••••••••••••, ••••••••'•••••••• L -~-• •••••••••+•••••••••••+•••••••••••+•••••••••••+•••••••••••+•••••••••••+•••••••••••+
Receiving Remarks: Client's Chair, of Custody differs fro, ,hat· the_·sa■ole !us reaa·: used the ·IDs on saople to log in.
All client saecle !Os preceded by "94-365·".
'
: Archive Remarks: 1
+····················-·······-·····TR[~NGLE LA80RATOR[ES. INC.-·CHAIN Of CUSiOOY·-REV!SEO 02/li/95---0 ····-··--······=--···--····8·+
I
I
I
·1 CllART #: M23-36FF ORGANICS SS SPIKE-X
CLIENT· -
I n,r #'~ 3l122..11-D
M'15 TOLUENE RINSES CXMBD!ED
FI& CHART FOR: PCDDs/PCDFs,SVCX:,PCBs,
PHEN)L-D5 100 ug
l,4-DIBRa1JBENZENE-D4 100 ug
& PESI' 2, 4, 6-'IRIBR(MJPHENJL _; 100 1.ig
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
PYRENE-Dl0 . 100 ug
TOLUENE AC/MeCL2 Xl\D
RINSES RINSES PRFSPIKED W/
4 ng D/F SS
100 ag l_j. J<. ORGANICS SS SPIKE-II
ROIDVAP KD --· 3,-,....')f. ----------------------TO 2 rnL 1D 2 rnL D5-NI'rnOEENZENE 100 ug
2-FLUJROBIPHENYL 100 ug
Xl\D + FILTER 1,. ,5-'IRICELOROBENZENE-D3 100 ug
ADD TO SOX ADD TO SOX ADD TO SOXHLET I ANIHRACENE-Dl0 100 ug
FOR TOLUENE FOR MeCl.2
EXTRACTION . EXTRACTION
IMPrn;ER IMPilGER
WA."'ER RINSES
SPIKE W/ I 4 ng D/F IS I ORGANICS ss l<D
SPri:E-X SPIKE W/ TO 2 mL
1 ug PCB IS's ORGANICS SS I 400 1.iL PEST SPIKE SPIKE-W
(0.4 ug/mL) PCB AS 1 ug IL ADD TO
I I IMPIN:;:ER_
WATER
SOXHLET IN LIQ-LIQ
TOLUENE-2rnir-i-SOXHLc7' IN E:m<ACT-MeCl.2
!ARCHIVE Mea,2-lst: I 1/2
SPIKE W/ I s;;Lrr 1:1
4 ng D/F AS
I 50% MeCL2
:SPLIT 1:1 11 SPLIT l:lh
ElCIRACT
TO ORGANICS
I
50%-TOLUENE 50%-TOLUENE 50%-MeCT,2 : SPLIT 1:11
I E:m<ACT EXTRACT EX'IRACT
I TOARQITVE TO DIOXINS TO DIOXINS
y µ 25%-MeCL2
XCHAN:;E 25%-MeCL2
cx:MBINE 10 HE:X,>.NE KDTOlmL
I I ANALnE FOR
I DO PCI;Ds /Fs CT..E'JI.NOP I SVCC's
DO FLORISIL 'UIBLE 2,8270
CLFAJ.'lUP
I ANALnE FOR
ANALnE FOR PCDDs/Fs ME'IHOD 23X M'.)NJ-DECA
FINAL VOLUME PCBs
1 mL 680 LRMS
DO 8080
PESI' ANALYSI
I n,r HK MARGI 95
.
I 9
PAGB l OP l
I TRI.ANGLB LABORATORIBS, INC.
I . Sample Preparation Tracking &. Management Form
I Project: ll982C Client: BTS, INC. (BTS02)
+------+---------------------------------+---------+------+-----------+-----------+-----------+-----------+-----------+-----------+
+------+---------------------------------+---------+------+-----------+-----------+-----------+-----------+-----------+-----------+
+------+---------------------------------+---------+------+-----------+-----------+-----------+-----------+-------. ---+-----------+
+------+---------------------------------+---------+------+-----------+-----------+-----------+-----------+-----------+-----------+
+------+---------------------------------+---------+------+-----------+-----------+-----------+-----------+-----------+-----------+
+------+---------------------------------+---------+------+-----------+-----------+-----------+-----------+-----------+-----------+
+------+---------------------------------+---------+------+-----------+-----------+-----------+-----------+-----------+-----------+
I
I
+------+---------------------------------+---------+------+-----------+-----------+-----------+-----------+-----------+-----------+
Comment:i: ----------------------------------------
+---• --• • --------- - ---. ---------------- ------------. --- - - - - ---------- ----------_------------- - ------- - - - - --RSV 07 /26/'J3 ( PSTMF 7) --+
1 0
.... -.. -·· ....
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
•_I
I
I
TRIAL~GLE LABORATORIES, INC.
SAMPLE EXTRACTION AND CLEANUP TRACKING FORM
ORGANIC WET LAB
TLI P:::-oject Numbe:::-: 31q8d.~4(.,,J)
I Sample No. I Steps I SOP No.
;(\ -.1_ P,J ll G-IOr:<-5• -, ~ /(.. v:,· ""' ~ C,1-7
I-1.. "(.._D. r:=-1J-.ffi u /: _,_,
i:i 1.. f\q(., f; /t--(/:. ,11' I /. .J. .,, . • I. V,,._,v, ;_,.,tr,JJ '-id-e..
' I ).. " ,lJ +: U-IA /.I / :,,., , c~ -1.. /) . I /r-
ti-J. ':, p; L -. lJ {) . 0 I ,s.c--.
'
fl 1 $p,'L.-w I CO" · 0 ~ <.. .'j,, I,,
' "':),,"-y~ -:-, , ____ ,.tJ L f le.. 11.. _.,.
< n;Y ~ -LI D 'xor? b f-e-<, I-, , I-!,--<-/ .. /..,',r,
' = J
5c'i. II~ L-. /:'-.-fvi.e Cf-,
~-(' ,,.,,p\,A(f ,. ,.Lr ,.<~ i:;-./ ~ '
II•~~ SL,( •• ~-1,.,r_,,J Pl-Irr-~,~!.-.<_
A-J~ < ':)n"/-'. \. r '""""'. -0
")p;), , --, '""-. () 1 " Pcfs-LJ.
1U '. __. ':> {-P /.4 it -ih r, ,, --, ,J "-t:-/.r" c,.-/. <. v (.,, ;, -, ( '" ./' I,
l+J.t \t" fH ,.,+ /-1-..,o 7 // 11 -" ••✓-1-cf-'<v /.6 -1 Af.,-c;{.
F: u.,./ <'" . ~J.,{f1 .JJ-(._. ~C,'/ ..1.. ,' -.o < .. A • --e ~..&,,,ch
• ., ,J
'¼{1,, .< ;.,,f, . < .. 1L~G
t' /1 b. cl.).__ -<. V Iv~ e,k <" -"" rd'.1-e I,_
' ,
l"\\.,;J .. \,_.JJ. P'' I r _J. z::-1\•.~
Ji 5ox L Dr~-•,.._:,<.½_ fiir O;o,,<-
~ ' h 11-r e-Ii . i.x, ' j Yz.. l-6,., tr ~r"q_";c.5
(o -h,' ., e. 1/--z.. So'( ~ Y-i. H-zD -J!n r " rd. a /'l { c. .S
l'l;u ;A{. 9->' G
\/ ;is% ~r 'i<b~D , JS-~ -W '9.J;o'+ Lf.fc8 ~
Comments:
I Init I Date I'
f/-{r' 3/z;h
5~m
I I
~
. 5/Jfll "i/Y.
I
\1
(_/1_ tr\ ,)
A-f'-3/zt..//1
~
I A-~'T"L ,
II ).
t1-G-
\ I
·. ,; ~:n--:
' / ' '
-PS: o/mc
/
/ 1/
Rev. WM(NU: PREP. DOC, WPS; 3 9$ 1
Sample
No.
o-)2.
I
J,
TRIA!'l"GLE LABORATORIES, INC.
SAMPLE EXTRACTION AND CLEANUP TRACKING FORM
ORGANIC WET LAB
TLI Project Number:
Steps sopi9f
No !._e_.
,;)~/2 -fc1 /_(..fc.c, .J..-1:,J '10 , ~)--4-,, \ --I
~-~
-vv~
Tr ct.,... s-12-! 1 . ' y.. \_ +:, I --I wY'.-~('-
'?o L..:"-.,, -h, H~. ,u
Js¼ -1.,; fbfo -s~J, 1,,,, f 't,-c,£..4,,,,,,e..w /kr,;,,,
I ~f" ~ ' F I <>I" ; , .-/ cl-,Pqy, ~ ,
r:;,-\....1,~ n 4-I --I w "_1,.,.,/)L -...._
!(11_<1.', -!.. c}..~1 ..l ,_ -u:.,/ '-.)7 .l-.. I -I .
Pn\<_. 0'-. -I.. • I
~Init ·Date
$K.
a.Cr" ~ l?/r3!t_
=7-)CV I
,II \ )
Comments: ------------------------'-------
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Rev. WM/NU: PREP. DOC, WPS; 3 9~ 21
Date: 03/21/95
Time: 16:50
Sample
ff crd TLI _Number ..
000 TLI Blank
001 91-160-lABC&.
002 97-160-2A-CE
customer.Sample.Id .......
TLI M23 Blf-k '~.,_, '>/11 .r
~ SO·Hx-R2 E~--./,, :I
~ BLANK
••• End of Report ·••·
.. -- --
Init.
pH ...
7.00
7.00
7,00
-
TRIANGLE LABORATORIES, INC.
Wet Lab Extraction and Observations
Project, 31982-£ v/A-1&-fL P1IR-r
NaOH Adj. H2S04 Adj.
mL •• pH.I. mL ... pH.2. Appearance. Color ...... Odor ...
0.7 12.00 1.0 2.00 CLEAR COLORLESS NO
0.7 12.00 1.0 2,00 CLEAR COLORLESS NO
0. 7 12.00 1.0 2.00 CLEAR COLORLESS NO
-----
Vol. Entered.By ......
JOO GATCHET
270 GATCHET
210 GATCHET
PRDPERC v:).01
Page: 1
Date .... Time .... s
03/21/95 16:49:43 F
03/21/95 16 :49 :43 F
03/21/95 16:49:44 F
---- -
.
.. -
--Date: 03/23/95
Time: 13:19 '
- - - -
Sample F. XAD
-
ff crd TLI_Number .. CUstomer.Sariiple.Id: ...... No Color ..
000
001
002 ...
TLI Blank TLI M23 Blapk
€E"-' '!>/1,f<;:$
97-160-lABC& ~ S0-M23-R2
e<i.., -,,h,I,,:,'
97-160-2A-CE 04.2.46 BLANk"
End of Report***
0 WHITE
1. WHITE
1 WHITE
- - -
TRIJ\NGLE LABORATORIES, INC.
Wet Lab MMS/PUF Observations
Project: 31982-C
Filter Glass Wool PUF
--
Color .... Color .... Color ..... Odor .......
WHITE NONE NONE NONE
BEIGE NONE NONE NONE
WHITE NONE NONE NONE
- --
Entered. By ...... Date ....
WHEELER· 03/23/95
WHEELER 03/23/95
WHEELER 03/23/95
--PRDPERC v:J.07
Page: 1
Time .... s
13:16:45 F
13:16:45 F
13:16:45 F
- -
I PAGE 1 OF 1
If ----------------------------------------.· ------------------------------------+
. TRIANGLE LABORATORIES, INC. -
Transfer Chain-of-Custody .Form
· Project 31982-C
I Transfer From: OWLSP To: OMSSV
I Initials ..
Released by:
Date ...... . Time ...
I Accepted by: {)()
+---------------------------------------------------~--------------------------+
I
I
I
I
I
I
I
I
I
I
I
I
I
MILES. ID ....... .
31982-C
31982-C
31982-C
-000
-001
-002
TLI No ..... .
TLI Blank
97-160-lABC&
97-160-2A-CE
Cust. Id ................. .
TLI M23 Blank
0.H-3-6 S0-M23-R2
O-&H-5 BLANK -,..,. --,;,,A.,
1 5
ATTACHMENT10 .
' ' .. SEMIVOLATILE SIR GC/MS TRACKING FORM
TL-RTP Project #: 3li:!6lc.., ·'
MA~RIX: ~ PUF Water Soil Ofuer ____ _
METHOD: ~O~fu:e~r==::::::::::::::::--
ANAL YTE LIST: Mono-Decachloro PCBs Other _____ _
ICAL Name: PCB _,_V...,,.3'-'2.::..9_,_ __ _
PCB Window Mix
PCB SID#3 V, ~ ~
Solvent Blks ii Oo2'-/w ,{ I/ O:,li/f
1001 SBLK Q.;jo1/ q':>-. {Jc). '-13 Dr---'-
1,).8 91-l&o=-211-C £ vwso c,,,-,
1846 <i:---"".J/3,1 "t:;f
..£ O· flb/.:5 ,(bl_ Voo1.s ,,..-t>F'• '1
TRIANGLE LABORATORIES OF RTP, INC.
SOP No. OMS160 1 0 November 1993 page 20 of 20
\ 1 6
I
I
I
I
TRIANGLE LABORATORIES OF ATP, INC. RUN LOG
MS# COLUMN TYPE COLUMN# · ANALYSIS ACQ METHOD GC METHOD FIND DB'S OTHER
I/ ' D8'5 -l,z_s i/~ 10j I~ -----flcbs1rtl ,ffl / 1 .
.
EXTRACT/ SAMPLE VOLUME /OD @tmL
2.
TIME PROJECT# SAMPLE# CLIENT SAMPLE ID FILENAME OPER BACKUP PROC pH COMMENTS
DATE NET ARC
I / Soluetd Eld,Jc_, VD 2.32--1iJ /l.V
I ~t3 ~1()# 1--· u1/ rnow
(p'5,f ;_1·11p /:e6 «)#J~{! J/i YfJ 2,53 ltLJ /LV ,()JO /7,fl
'
'&i,h
PCfJ S-r[j ti 1.
YOt!}~
•lfl p;JO .
13.'I-I 211v €i6V:b1thF-7''=~ ~\) r,v 1/111LJ
~ -t; J:J,,/ j'';,9MS-//I/. If
3/t.e/,t; /f) It/-/ / StPt,d!l/r MML VOZ65 tu
Ff fW'-l'f/" /Jt,a.
f Stl,IJ\. t $ -
/ / .50/...UN, t:uJAJL 1/l) ~:f V02;)h
t,, t..9/96
/9:15 31qgzc, ·/ /t.1::': .;5/Z9 /15 V0231 Ill) -, 4e l;Y_,'9,t,\S
C/5 .:>81-O!JZ/9()
; ;
q1-1w;-~h,,;
'
/0 J /t?l}Z.C-7Ctff-r Vo 1-Y3 IU i
C. / ,f :j t.3;.,;,Mt,,
~ JI "l!} 2 C... -& 00/ 5~ $1-/26 /t Z., tloz~q ll) ....__,;,,
~ 0841 ILlSS jl • I.'} LU I ,I./ /)J; u /1? I l/Q 240 11v tv
131 2111,,, tbf.l .sTD #1 VD~4t /J,J f. V fY1. 101,6 f; LNMJ-J.
~D~;,,ul I IJT1:V1ht-
lll'fERl·AL STANDARD SYROOGATESTANOARD ANALYTE STANDARD
-;:Rll•,' .J: al.c/!J/J I _,_ ·-·,, -r-;,,,-----.. · .... v --
------------------· TRIANGLE LABORATORIES OF RTP, INC. , RUN LOG
MS# COLUMN TYPE COLUMN # ANALYSIS ACQ METHOD GC METIIOD FIND DB'S OTHER .. •·
1. ~--;~'.
.EXTRACT/ SAMPLE VOLUME ___ /i~r:'0"-----1emL 2.
DATE TIME PROJECT# SAMPLE# CLIENT SAMPLE ID FILENAME OPER B/\CkUP PROC pll COMMENTS NET /\RC
1~ / -(iddL-rr 1111,I' ~ IO«JI~ "'~,,J l/t1!/5 / 1-116 ~801D-#z.. VD~2.-/Li) uzPr&-z ... ~, 6 .
' 'H:. KV
t/re I '7c,l',Q/i /,Y,t t{J. /,U,fJ,,e_, .
2173 ".:jQf.> SiD i¾,{ V D.zt/3 Ii> L,{!PC -.£ -<01 ,!
///2 tv .
7~ ';/r,7 I 2172-+o@-9w th 5 Vol44 w ft/
tkl'«,-d -, • .,,d' A ,,.., ~
L1m6-£ o&il 6
WA,1 I ~ 61\) -# 3 oddrd' ,~~ '1./7;,e.C, ' Z.17f Vo24-5 V..'1-"M·.L,,1. ,s· // . ·FJ:_ /l32. JlJ . tY ~<,...,vu -..r,JJ ..
'1l}kj /45i /' / 501.-~~<-,,, J)Z-4(.p \\) lb.)
1:i/z.1k / . .,,,.,----~~~ °33<Ail.iL.-VDz.41 10 l5ZJ .. ltJ
1zqk /f;t11 6iqB2.C.. / ~BLl!.031190 v'DzA6 .J (tJ
o/2qlr_ IH-7 32()¾-f> / 5BLK osz1qs/ \J D)49 tu t/J
3/z.?/2, 01q/Jlo C/1-1110 -<tt"'.,!;f" . VJ)Z!vo ~J /JJ 1126 ZII-C(J' {)e14, ,6LI/M(...
r,1'1-o1 ,,-uJ
,
YPl:;.iJ leob l32p~ /!i LIi Ml. vvz'=', Ip, 1 Iv I
AN/\LYTE STANDARD
TRIANGLE LABORATORIES OF RTP, INC. RUN LOG
MS# COLUMN TYPE COLUMN # ANALYSIS ACQ METHOD GC METHOD FIND DB'S OTHER
EXTRACT/ SAMPLE VOLUME __ .....:.lrD.:::..,. ~"-~ _,Q ml 2.
DATE TIME PROJECT# SAMPLE# CLIENT SAMPLE ID FILENAME OPER BACkliP PROC pit COMMENTS
NET ARC
l~r 3 lt;'#,1,6
":!1·11,0· ?Zt-J,r1, fJ tJ
JfW? ·~ef6; ~ so -IYJ,!?& -R-v l/!).252-/1,J
it/4{ 'J7-r:,l//-R Jl,<,1 ..u .,;z ~ --, /On( 15, {.,c,dt'¢.L
lt/l1 3.l iJ:&3 15 I, :,, {-VD z:5-j--0 /0 ,,/St,.&Cu/o ,.,, ·=fi{ ["" .
,cv d'.:4-l'oi fa1'V', JI/JII{
3h1k-91-cJI/-Ro.,c/~ VfJZ5c/ le) "/{)4/1 ?{, (.,(,4'.<1@
.jM.:0~ I/ g, ,f, Ir_,,., 1-t.3,J:,1"~ c1 ·-......::. ~-'.t ,/
:JiJn'l IO)(a,,//,/,, ·-/211/ ;,,
(
~318<:fg~ /i.J-5$ -:jc~ W"-111::w ,nt')L! VLJ25:; ho
~~ ' R:!A :5TD ll.3 (oz.st, 1,J JJ11' ~~ :._,,.
3/3o/95
(;j1.
v..i7.2s r f:.W .,t z.; SsJ1.-vw.-{,u
Pt.A7\J1L.
& hJ,-,, ,-l. I
--,..... • 'C,-J
.;
·.'
t.
i
' i
(~~rD /v,7.l,tNi--
l~ITEiRMAL STANDARD SlJflROGJ\Te-STANOARD ANALYTE STANDARD
'--" -~µ ci!i/8/1 'M)j-.I d,i/5-6 I /o,,f (!! ,f)'r /n"€-,IJ{'de, 1/)(,6 f:,,K., ---------11,..1.-11. L,_l--__ l-__ 1-1_1-_F-~lll---R·ll...----;-g--g__.i --
0\
c-! '
' , . ..
(~··
I
TL-RTP Project: 31982C
Client Sample: S0-M23-R2
Modified Method 680 PCB Analysis I
Analysis File: VD25200
Client Project:
Sample Matrix:
TLRTP ID:
Sample Size:
Dry Weight
Total MonoCB
Total DiCB
Total TriCB
Total TetraCB
Total PentaCB
Total HexaCB
Total HepraCB
Total OctaCB
Total NonaCB
DecaCB
TOTAL PCB
TOTAL PCB+ EMPC
MCCLAREN-HART
M23 Date Received: 03/18/95
97-160-1* Date Extracted: 03/21/95
Date Analyzed: 03/29/95
1.000
n/a
ND
0.04
EMPC
ND
EMPC
ND
ND
ND
ND
0.11
0.16
5.0
Dilution Factor: 4
Blank File: n/a
Analyst: KV
0.004
2 4.5
0.03
0.009
0.37
0.02
0.02
0.03
0.04
13C12-3,3' ,4,4' -TetraCB
13C1r2,2' ,3,3' ,5,5' ,6,6' -OctaCB
1.00
0.70
99.8
70.2
13C12-2,2' ,4,4' ,5,5' -HexaCB 1.0 102
Spike File: SPPCBF0l I
ICAL: PCBV329 I CONCAL: VD245
% Moisture: n/a
% Lipid: n/a I % Solids: n/a
n ' a:r1 •ffillr!I ·•••·•••·1 I
0.82
0.88
1.32
29.02
21.08
27.62
22.52
_6. I
I
I
I
I
I
I
····•·························•···•···· ff tIR'~t@:· RT q Jl!i@jjiW •••• , I "Ci,-2,2' ,5,5'-TetraCB
13C1i-3,3' ,4,4' ,5,5' -HexaCB
Quality Control Notes:
A,B,C,E,G
0.82 17.17
1.36 25.93 I
l :J Data Reviewer: ____________ 03/31/95
I
I
Triangle Laboratories of RTP, Inc.
801 Capitola Drive• Durham, North Carolina 27713
Phone: [phone] • Fax: [phone]
Page I of I · .~, PCBF_pSR v:1.06, LARSS.!4.08
Printed: 18:24 03/31~U I
I,
I TL-RTP Project: 31982C
Client Sampl~: BLANK
Modified Method 680 PCB Analy-sis
Analysis File: VD25000
I Client Project: MCCLAREN-HART
Sample Matrix: M23
I TLRTP ID: 97-160-2A-CE
Sample Size:
I Dry Weight:
1.000
n/a
I
Total MonoCB
I Total DiCB
Total TriCB
Total TetraCB
I Total PentaCB
Total HexaCB
Total HeptaCB
Total OctaCB
I Total NonaCB
DecaCB
I TOTAL PCB
TOTAL PCB+ EMPC
I
13C12-3,3' ,4,4' -TetraCB
1 13C,,-2,2' ,3,3' ,5,5',6,6' -OciaCB
1. 13C12-2,2' ,4,4' ,5,5' -HexaCB
I 1i~~ekx~.lx~~nit~r~1l;t,l:
13Ci,-2.2' ,5,5'-TetraCB I 13C1,-3,3',4,4',5,5'-HexaCB
. ND
EMPC
ND
ND
ND
ND
ND
ND
ND
EMPC
n/a
4.3
1.00
0.73
1.1
Date Received: 03/18/95
Date Extracted: 03/21/95
Date Analyzed: 03/29/95
Dilution Factor: 4
Blank File:
Analyst:
n/a
KV
0.003
0.004
0.008
0.01
0.02
0.02
0.02
0.03
99.8
73.0
107
4.2
0.11
Spike File:
!CAL:
CONCAL:
% Moisture:
% Lipid:
% Solids:
0.81
0.87
1.29
SPPCBF0l
PCBV329
· VD245
n/a
n/a
n/a
21.08
27.62
22.52
..... ;;.. I: E ff'!3fil : :l'i:ll~/ii;!:ilill
0.83 17.17
1.30 25.93
I
I Data Reviewer: _____ C> _______ 03/31/95
I Triangle Laboratories of ATP, Inc.
801 Capitola Drive• Durham, North Carolina 2TT13
1 Phone: [phone] • Fax: [phone]
Page 1 of 1 PCBF_PSR v:1.06. LARSS.14.08
Printed: 18:24 03/31/95
40
TL-RTP Project: 31982C
Client Sample:. SBLK 032195
Modified Method 680 PCB Analysis
Analysis File: VD24800
Client Project: MCCLAREN-HART
Sample Matrix: XAD Date Received: I I
03/21/95
03/29/95
TLRTPID: SBLK 032195 Date Extracted:
Sample Size:
Dry Weight:
Total MonoCB
Total DiCB
Total TriCB
Total TetraCB
Total PentaCB
Total HexaCB
Total HeptaCB
Total OctaCB
Total NonaCB
DecaCB
TOTAL PCB
TOT AL PCB + EMPC
1.000
n/a
"Ci,-3,3' ,4,4' -TetraCB
13C12-2,2' ,3.3' ,5.5' ,6,6' -OctaCB
13C 12-2,2' ,4,4' ,5,5' -HexaCB
1'C12-2,2' ,5,5' -TetraCB
13Ci2-3,3' ,4.4· .5,5' -HexaCB
ND
EMPC
ND
ND
ND
ND
ND
ND
ND
0.11
0.11
5.1
0.90
0.68
0.84
Date Analyzed:
Dilution Factor: 4
Blank File: n/a ·
Analyst: KV ·
0.004
0.006
O.Ql
0.02
0.02
0.02
0.02
0.03
90.2
68.3
83.5
. 5.0
Spike File:
!CAL:
CONCAL:
% Moisture:
% Lipid:
% Solids:
SPPCBF0l
PCBV329
· VD245
n/a
n/a
n/a
29.02
0.79
0.91
1.36
21.08
27.62
22.52
0.81 17.17
1.29 25.93
~ Data Reviewer: ____________ 03/31/95
Triangle Laboratories of RTP, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: [phone] • Fax: [phone]
Page I of I PCBF_PSR v:l.o6. LARS 5.14.08
60
Printed: 18:23 03/31/95
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
.I
I
I
I
I
I
I
I
APPENDIX R
PESTICIDES LABORATORY DATA
I
·1
I
CASE NARRATIVE
TRIANGLE LABORATORIES OF RTP, INC.
801 CAPITOLA DRIVE
Durham, N.C. 27713
Phone: [phone]
Fax: [phone]
I DATE: April 4, 1995
PROJECT NUMBER: 31982B
I
I
I
I
I
I
I
I
••
:I
I
I
I
I
CLIENT P.O. NO:
CLIENT ID: ETS, Inc.
SAMPLE IDs: 00136 SO-M23-R2 00145 BLANK
OBJECTIVE: Analysis of one M23 sample train and one blank train for organochlorine pesticides.
RESULTS:
Results reported relate only to items tested.
Information pertaining to this analysis is as follows: The results are reported in total µg for the samples. The baselines are determined using the mathematical algorithm contained in the chromatography data system "MAXIMA" by WATERS. All analytes were quantitated using the second internal standard cis-Permethrin. The samples were received on March 18, 1995 in good condition at an ambient temperature.
The second internal standard, cis-Permethrin, is part of a mixture of two isomers. The cis isomer used for· quantitation is labelled IS2 C-PERM or IS2 cis-Permethrin while the other isomer, trans, is labelled IS2 ISOMER.
A nominal volume/weight value of one was assigned to the sample and project .blank in order to calculate concentrations in total micrograms. A dilution factor of four is used for calculating the result due to the fact that the sample was split in order to perform multiple analyses. Additional dilutions were performed in order to quantitate 4,4'-DDE and 4,4'-DDD in sample 00136 SO-M23-. R2. The reported surrogates for the sample and blank are tetra-chlorometaxylene (TCMX) and decachlorobiphenyl (DCBP). The blank and samples associated with this project displayed surrogate recoveries within the 50-150% advisory range of method 8080 ..
METHODOLOGY:
Prior to extraction, the samples were spiked with four hundred µL of a surrogate standard solution containing tetrachlorometa-xylene (TCMX) and decachlorobiphenyl (DCBP) at a concentration of 0.4 µg/mL each. The filter and XAD portions of the trains were extracted according to the guidelines of USEPA SW 846, Method 3540. The aqueous portions were extracted along with the toluene rinses,
1
1
TRIANGLE LABORATORIES OF R~P, INC,
CASE NARRATIVE DATE: April 4, 1995
PROJECT NUMBER: 31982B
which were reconstituted in methylene chloride, according to the' guidelines of USEPA SW 846, Method 3510. The extracts for each train were then combined and split into four equal parts. Thus; 25 percent of each extract underwent Florisil cleanup according to the guidelines of USEPA SW 846, Method 3620. The extracts were brought to a final volume of one mL.
The extracts were analyzed following the guidelines of USEPA SW 846, Methods 8000 and 8080. Pentachlorobenzene at a concentra-tion of 2. 0 µg/mL and cis-Permethrin at a concentration of 100 µg/mL were added as internal standards prior to GC/ECD analysis.·
ANALYTICAL CONDITIONS:
Instrument: HP 5890 Series II GC with 7673 Autosamplers
Modified packed column injectors, dual ECD detectors
Columns:
Program:
REPORT:
Injector temperature -225 degrees C Detector temperature -300 degrees C Carrier gas -Hydrogen
Make-up gas -Nitrogen at 60 ml/minute flow Column flow -40 cm/sec
Injection volume -1.0 µl
RTX-35, 30M x 0.53mm ID, 1.0µ film RTX-1701, 30M x 0.53mm ID, 1.0µ film
Initial temperature -150 degrees C
Ramp -

6

degrees C/minute
Final Temperature -270 degrees C
Final time -15.0 minutes
Enclosed with the case narrative for this data package are copies of all client paperwork, the relevant receiving log pages, copies of all TLI correspondence, sample preparation laboratory extraction and cleanup information, analyst worksheets and instrument run log pages. All initial and continuing calibration verification data is located at the back of the data package.
The data is reported in sample analysis reports which include the following information: the project number, the client sample identification, the TLI sample identification, the sample matrix, the sample extraction date, the sample size, the dilution factor, the date of analysis, the instrument identification, analyte CAS Numbers, the GC column types, the detector identifications and the computer data file identifications for the.sample.
Individual sample analysis reports contain pesticide CAS number, analyte peak retention times, peak quantitation values and the lower of the calculated concentration value taken from both columns. Also reported are the surrogate concentrations, percent recoveries and the relative standard deviations between column one
2
.. --; -.-----
I
I
I
I
I
I
I
I
I
I
'I
I
I
I
I
I
I
I
2 I
I TRIANGLE LABORATORIES OF RTP, INC. DATE: April 4, 1995
PROJECT NUMBER: 31982B I CASE NARRATIVE
and column two calculated concentration values.
I The response factors (RFs) used are the mean values calculated from the initial calibrations. The surrogate recoveries are calculated using ari average of the RF values from all of the
1 initial calibrations.
If the analyte is not detected, the concentration is reported as <PQL. The following Q codes may be used to describe the I results: "U" if undetected, 11 J" if the analyte is below the calibration range, "P" if the percent difference between columns is greater than 25%, "E" if the analyte is above the calibration
I range, 11 D" if the sample was diluted, and "X" if the percent relative standard deviation (RSD) of the peaks used for quantita-tion is greater than 40%.
I
I
I
I
I
SAMPLE CALCULATION:
1. Response Factor (RF)
where:
Response for the analyte to be measured
Response for the internal standard
Concentration of the internal standard, ng/uL· Concentration of the analyte to be measured, ng/uL I 2. Concentration ( C)
I
I
I
I
I
I
I
where:
A, =
A;, =
c. =
v. = v, =
D =
RF = v. = v, =
C ( totalµg) = (Ax) x(Ci5 ) x(Vis) x(Vx) x (D)
(Ais) x (RF) x ( Va) x ( V5 )
Area response of analyte.
Area response of internal standard.
Concentration of internal standard solution (µg/mL). Volume of internal standard spiked (µL).
Final extract volume (mL).
Dilution factor.
Analyte response factor.
Aliquot volume (µL).
air sample nominal value= 1
3
3
TRIANGLE LABORATORIES OF RTP, INC.
CASE NARRATIVE
DATE: April 4, 1995
PROJECT NUMBER: 31982B
For example: an M23 extract which underwent analysis by Method 8080 would have the following calculation -
A,. = 235104 (From sample analysis report). A,. = 36785 (From sample analysis report).
Cb= 100.0 µg/mL
vb = 2 µL v. = 1.0 mL
D = 2
RF = 0.0370 (From initial calibration report).
V, = 200.0 µL
v, = 1
Analyte ( total1,1g) = (235104)x(l00.0)x(2)x(l.0)x(2.0)
(36785)x(0.0370)x(200.0)x(l)
= 345.5 total µg Analyte
3. Practical Quantitation Limit (PQL)
PQL
where:
c, =
v, =
v, =
Analyte concentration in lowest initial calibra-
tion solution (ng/µL).
Volume of total extract (µL).
Nominal value for air sample
If you have any questions or comments about this data package, please feel free to contact Hani Karam at 919-544-8351.
For Triangle Laboratories of RTP. Inc. ,.
David Berkowit
GC Chemist
Report Preparation
{,~
GC Supervisor
This report should only be reproduced in full. Any reproduction of this report requires permission from Triangle Laboratories of RTP, Inc.
4.
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
.4 I
.. ,,.,, ~•~. -.
I,')
CLIENT CHAIN OF CUSTODY SAMPLER'S SIGNATURE~ P/Q 01667/1100000961
From: ETS, INC. Contact: TERRY WILLIAMSON Total Number of Analysis Wanted:
1401 MUNICtrAL DRIVE Phone: [phone] Containers:
ROANOKE, VA 24012 Fax: [phone]
Project: /1'\ 1 /A ;-c,, · J/ f4 / P.o.,, 5408 I
I
(ETS02/HK)
STA NO. Date Time Comp Grab Sample Id.# Sample Amt. Remarks
3--,7 /?dO / l>'I ",,.,I' >d -/1})-l ,/? l >-HV• I
-
.
Rellnqulshed B/,Slgn. Dale/Time Received By/Sign. Rellnqulshed By/Sign. Dale/Time Received By/Sign.
~u. , .. ~ J/tlJ 'ts' ,, :r.: -
Rellnquhhed By/Sign.
~
Date/Time Received By/Sign. Rellnqulshed By/Sign. Dale/Time Received By/Sign.
Received for Laboratory By/Signature Date/Time _ I-Send Samples to: Triangle Laboratories, Inc. %4 / n -/J
~I l""dl? ":;J Attn: Sample Custodian
801 Capitola Drive .,A ¥ '----. . II'· /0 Durham, NC 27713 USA
Phone: [phone] • Fax: [phone] -------------------
I
PAGE I OF :
+---·---------------------······-----------------------------------+--------------------+-----· ------------------------------·------· I
: Carrier.and Nu1ber : TONY UNDERWOOD : 160
+···································+········ ···+···········+···········+···········+···········+···········+···········+···········+
:. TL! Number "atrix : To LAB : To.STORAGE: lo LAB : lo STORAGE: To LAB : To STORAGE: lo LAB : To STORAGE:
: 1R/H:CP" Client ID Location : Date/lnit : Date/lnit ' Date/lnit : Date/lnit : Date/Init : Oate/lnit : Date/Init : Date/lnit : I +···································+···········+······· ·······+···········+···········+···········+···········+···········+
97·160·1A FILTER
00136 SO·M23·R2
CO2 '
' ' ' +-----------+ ·----------+------·---·~---···-·---t-----······+-· ··-· ·-·--+·-·········•·---·--····+ I
+-----------------------------------+-----------+-----------+-----------+-----------+-----------+-----------+-----------+-----------+
97
•
160
•
18
00143 SO·K23·R2 XAD l ........... l ........... l ........... i ........... i ........... i ........... l ........... i ........... i I
CO2 : '·
+···································•···········+···········+···········+···········+···········•···········+···········+···········: I
: 97·160:lC FH/ACE/"ECL2
: 00137 SO·K23·R2 +···········+···········+···········+···········+···········+···········+···········+···········+ :· ----··· --CO2: --:·· -----: ----·-: -----·: --·-: -~----:--: : --:
;-97· 160· ID •••••••••••• FH/TOL. RINSE·;-··········;-··········;-··········;-··········~····· ·. ····;-··········;···········; ··········; I
' 00138 SO·K23·R2 +······· ·· ·+··· · ······· .. ···· ······•······ ···· ·+···········+········· ·· +········· ·· +·········· · +
................................ ~~~.l···········•···········+-··········+···········+···········•···········+···········+···········l I
' '
97· 160· IE I"P I :
00139 SO·K23·R2
: coz :
+-----------------------------------+-----------+-----------+-----------t···········+-----------+-----------+-----------+-----------+
97· 160· IF TOLUENE RJHSE '
I
' 97·160·2A FJLTEP.
00145 BLAHI
-.. I I I I I I I I I ,
1 I I I I I 1 I '
+·-·-·-·----+-··-··-····•····---·--. +·····--·---•----------·+-·-·-----·-+··-·---··--+-·---·-----t
CO2·
;-97· 160· 28 ••••• ••••• .••••••••• XAD ·:·· ·········t··········:···········:···········t··········;-······ · ···;-··········;·········· ·; I
' 00152 BLAHK +···········+···········+···········+···········+···········+···········+···········+···········+
. : . . co: : : : : : : : ~ :
;· 97 • 160· 2C ........ ·_· .. FH /ACE I NE CL2 • ;·.. • ••••• • ;· ••••••••• • ;·. -••••••• ·:··. • ••••• • t·· ...... · ;· ........ ·· ;· ......... · ;· ......... ·: I
00146 BLAHK +···········t···········•···········•···········•···········+···········+···········+···········+
' co:
+-------· ·--·-·-··················-·t·····--···-~·······················.-······-···•········--·····-······-+····-----··+-······--··•
Receiving Re,ark:: Client's Chain of.Custody differs fro, wr,at the
All client saeole IDs preceded b·, ·q,.3,5. ·.
Sa,ole IDs read: used the IDs on samole to log in.
'··········-·--··-·······-··············-·······--······························--·-·······-·······--·····-·····-···-·-·-······--·--'. ' '
I
-. . Archive Re111ar~s: ,
+···· ..• · .... · · · ..... · .. ---· • · -· · --TR I ANGLE LABOR A TOR I ES. I HC. ··CHAI h o: CVS TOO\· ·REV! SED 0211 71°5 · · • • ... • · · · ......... · • · ..... -·· -6-' I
·• PAGB l OF 1
1----------------------------------------------------. ---------------------------------------------------------------------------·
TRIANGLB LABORATORIES, INC. I
, Sample Preparation Tracking & Management Form /
\ ?reject: 319828 Client: .BTS, INC. (BTS02) I
1-------------------------------------------------------------------------------------------------------------------------------·
Sample Information I
I Meehod, $DSD Bxeraceion Dari _j_;~ q~r . . I
-ol ve~e/Acid• () '---"~gU1...-----------~e -<flf "1 ~-t; -; ~~c;-----------~-----------~-----------~----------~-----------~
I I TLI / I Sample !Pinal I01~}c7P · I I I I I
l mplel SAMPLB ID / CLIBNT IWge / VollVolum•l~~I/~ __ /_/ I_/ !_l_l_!_I_!_! I_/. /_I
crdl / SAMPLB ID I 9 / ml I ml I ',I 1)1 I I I I I
+-- - - --+-- - - ---- - - - - - - - - - --- - - - - - - - - - - - --+-- - - - - - --+-- - - --+--:, Pt>~+-----------+-- - - - - - - ---+-- - - - - - - - --+-- - - - - - - - --+-- - - - - - - - - -+
I I TLI Blank 1 1 1 .: xi 1 1 1 . 1 1 1
0 I TLI M23 Blank I I I / k!jfJ I I I I I I
+------+---------------------------------+---------+------+--1--------+-----------+-----------+-----------+-----------+-----------+
I• I '7-160-lABC&E,(:,--I I I 'Ui . .r'rr/ I I I I I I 11 I 00136 S0-M23-R2 I I I !)' 1:_,1 (}/ I I I I I I ii \11V • • • • ,7r,... / + + + + . + •
I• I '7-1'0-2A-cn I . I I;''·' (':' I I I I I I
12 I 00145 BI.ANK I I I If~ I I I I I . I
----+---------------------------------+---------+------•-7---------+-----------+-----------+-----------+-----------+-----------+
I I I I I .· I I I I I I
I I . I I L1 I I I I I I
'
----+---------------------------------+---------+------+-----------+-----------+-----------+-----------+-----------+-----------+
I I I I I I I I I I
I I I I I I I I I I I
'
----+---------------------------------+---------+------+-----------+-----------+-----------•-... ---------+-----------+-----------+
I I I I I I I I I I
I I I I I I I I I I I
I----+--------.------------------------+---------+------+-----------+---------.-+-----------+-----------+-----------+-----------+
I . I I I I I I I I I
I I I I I I I I I I
+------+---------------------------------+---------+------•-----------+-----------+-----------+-----------+-----------+-----------+ I
+------+---------------------------------+---------+------+-----------+-----------+-----------+-----------+-----------+-----------+
-----+---------------------------------+---------+------+-----------•-----------+-----------+-----------•----------+-----------·
I I I I I I I I I I I I I I I I I I I I I I
----+---------------------------------+---------+------+-----------+-----------+-----------+-----------+-----------+-----------+
I I I I I I I I I I I I I I I I I I I I I I
,. ----+---------------------------------+---------+. -----+-----------+-----------+-----------+-----------+-----------+-----------~
'Comments,=============================================================== : +---------------------------------------------------------------------------------------------------------RSV 07/26/93 (iSTMF 7)--+
I
I
I -(
Date: 03/24/95
Time: 11:03
Sample
n crd TLI Number .. customer.Sample.Id ....... -
000 TLI Blank TLI M23 Blank
001 97-160-lABC& 00136 S0-M23-R2
002 97-160-2A-CE 00145 BLANK
••• End of Report ...
co
-- ---
F. XAD
No Colar .....
0 WHITE
1 WHITE
1 WHITE
- -
TRIANGLE LABORATORIES, INC.
Wet Lab MM5/PUf' Observations
Project: 31982-B
Filter Glass Wool PUF
Colar ..... Colar.,. Colar ..... Odor ..... ,.
NONE NONE NA NONE
BEIGE NONE NA NONE
WHITE NONE NA NONE
---- -
Entered.By ...... Date ....
WHEELER 03/24/95
WHEELER 03/24/95
WHEELER 03/24/95
-- -
PRDPERC v: 3. 07
Page: l
Time., .. s
10:56:13 F
10:56:13 F
10:56:13 F
-- --
--Date: 03/24/95
Time: 11:03
Sample • crd TLI Number .. -
000 TLI Blank
001 97-160-lABC&
002 91-160-2A-CE
- - -
Customer.Sample.Id .......
TLI M23 Blank
00136 S0-M23-R2
00145 BLANK
End of Report ...
-
Init.
pH.
7.00
7.00
7.00
-----
NaOH
mL ••
0 .7
0 .7
0.7
TRIANGLE LABORATORIES, INC.
Wet Lab Extraction and Observations
Project: 31982-8
Adj. H2S04 Adj.
pH.l. mL. pH.2. Appearance. Color ......
12. 00 1 .0 2.00 CLEAR COLORLESS
12.00 1 .0 2.00 CLEAR COLORLESS
12. 00 1 .0 2.00 CLEAR COLORLESS
..
Odor.
NONE
NONE
NONE
----
Vol. Entered. By ......
300 WHEELER
270 WHEELER
210 WHEELER
PRDPERC v: 3. 01
Page: l
Date ...• Time .... s
03/24/95 11: 02: 39 F
03/24/95 11:02:39 F
03/24/95 11:02:39 F
--
. , PAGE 1 OF 1 I
+-------. __ . ---------------. __ ., --.. :--· ----·--: -.. _._. ------------. ----------------+
TRIANGLE LABORATORIES, INC. I
Transfer Chain-of-Custody Form
·Project 31982-B
Transfer From: OWLSP To: OMSSV
Initials .. Date ....... Time ...
Released by: JLE 3_µ4-; q,r !.K__/7\
%/Jp ~;5._;&r5 6 :J-::f5.. Accepted by:
+------------------------------------------------------------------------------
MILES. ID ....... .
31982-B
31982-B
31982-B
-000
-001
-002
TLI No. ; ....
TLI Blank
97-160-lABC&
97-160-2A-CE
Cust. Id .................. ·
TLI M23 Blank
00136 S0-M23-R2
00145 BLANK
+-------------------------------------------------------XfrCOC (Rev 11/01/94)--+
Additional comments or instructions:
. '
I
I
I
10 I
2'7
ARCHIVE
INSTR rn, M INSTR rn, A1\
COLUHH TYPE: V'-11_ -".,,,::;--COLUHH TYPE: /:_f}(/:T (J
DATE OPER PROJECTf 0 Q CLIENT SAHPLE ID FILE HANE COHHEHTS
J
;;(_y(\ -
CCnL-z z"' ·30
(l/1./L
MYIDI?
/L
Cf-\ L-/vlx IO I ~lo
V
\ V
- - - - ---------- - - - -
PAGE I 1 ~)
INIIIAL TEIF(I) •t FLOW 111./•ln,
INSTR IOr M INSTR ID: ,l/
ARCHIVE COLUHH TYPE: /7). -~S COLUHH TYPE: ,C,>-/~0
DATE OPER PROJECTI 0 Q CLIENT SAHPLE ID FILE NAHE FILE HAHE COHHENTS
· 15 7..<.,
(_ CA-( J 1 I ,\-Joo t=+--
2,2kb
✓
/
M
'3i < L
C<AC. ./
ll1
,, ~ .. ., .. . ' ·, . ---:·_,,_.,.,, ·.,·· .........
·;., PAOB I ~
INITIAL TOP(I) • C • IWl'(I) •c,-t11,, ·-. flllAI. TOl'(1) • c ·· • rLOII 111./■ln •
l5oc__ tc/~----z;Jo"'L/1<;~-Lfo(l,..._/4c_
~--Z...1-5 I)=-,_~,
INSTR ID: M. INSTR ID:/4
ARCHIVE COLUHN TYPE:liJ<--:i'5 COLUHN TYPE:121 ,>.--J?a I
DATE OPER PR9JECU 0 Q CLIENT SAHPLE 10 . FILE NAHE FILE NAHE COHMENTS
-irAi-4 C)l/~t:tL .J Z4-::JR )A y ( (J1) ?,u
•. () ./ 2 '-'-=r.1--MJ(lu?J3J
./ "Z-4":f-f,,, Ally ( Vb 31..-
' ,/ z; ,,--,-)fa'y (01)37, I 7 .I
~~~ ,/
?-'f3D Mk l orrr. <./-
/ ·24251 ' ~/Ol)~i;
./ Vf7'.A Ji½.-,
,,/,I .::-.... -. ./ 2..J-{i, 1-L0< /07J''7f-I,
' I ./ 2-ilt-J{k(D03d
P,; Ji,'>!~ / Z,'{35 .iJY(VD37
./ 7.:{3c./ ~/07)./(J ,
./ '2H-~~ Af tau<-1-(
I ../ "2f3L )A._,j,--I aot/7 I
I ' ,j ,I / Ly.-; I .iJLy I 07ill 3
-------------------
..
- - - - - - - - - - - -.. --liiii liiii
iiii -::r
ARCHIVE
DATE OPER PROJECTI 0 Q
J
.J
J
.J
./
/
/
./
1 t&B"i ./
? 1-=1-5 I ./
./
,/
./ .,
CLIENT SAMPLE ID
'2 (,, C,
1'6UC--
2.1 ½ I .?!(j::..
/Je,.t,,oo f -a -z_o
/Jc. ti(X) ( -o?..J
,U:_ (o;X> l -02 ·
• HOii 111./■ln,
INSTR ID: ,(.,1 INSTR ID: /,f
COLUHN TYPE:,e71,---,'3S CO~UHN TYPE:.f-µ• /'h)
FILE NAHE FIi.£ NAHE
fov'5-z.__
;Ll.,r { 00 S _3
.u
/J.k, av s5 .
PAGE I
CDHltENTS
') . '-I
. . . -· . -.... ; ,.,._. ,. . . ·~, .-
I GC LAB PROJECT FORM
SEQUENCE: _Z-=--DATE: 4/3/ q'5
I '
I METHOD:
I
_____ TU CLP
_____ TU CLP Pest. only
_____ TU CLP PCBs only
_____ TLIGreenBayPCBs
_____ Other
I EXTERNAL STANDARD METHOD:---,---
INTERNAL STANDARD METHOD:_....,✓'---• __
I Concentrations: Pentachlorobenzene (PCNB)
cis-Permethrin (C-PERM)
_____ Tll 608
_____ TU 608 Pest. only
_____ TU 608 PCBs only
_____ Tl! 8080
----'✓'----TU 8080 Pest. only
_____ TU 8080 PCBs only
IS SOLUTION ID: :2...?i 1---=~--------
1 · O ug/ml
, oO. 0 ug/ml
Jv\ y' I I\ I Yi
/vd I~\ Y1J
oo 13ia 5r,-Ml3-r2:z.,.
00 I 3-u <.ri -/0, z._z.. -r2 z._
-z_o
l .I,
I ,1-----+-----+-------+---+---+-----+-----II
I ,1----1------+-------+---+----+-------+------ll
I ,~-----1----+-----l---+--+------'---+----ll
111-----+-----+-------+---+---+------+-----II
·i'====d======-======='====="=~=~==11
1--
1--
File
f,\¥10 J uO
FCV
Mix
Pe,)-/vii~ b Z.'l':> 3
17,,':rt AA i 1: A z..; t,c\
1
I COMMENTS: . 51<,r1.ph-ct'J JJ cl '/,. 0 ~ y_ /0 0-xvJ. OK1J1;J
! 1 -~=~;.""'..,_ ,;;:;.l r "' 41,~,r;.~ ...
I ... · ...
File
LI 'I. 10 I c.\..\
paga3ol3 15
GC LAB PROJECT FORM
PROJECT NO: :3/ qr;z_ D SEQUENCE: / . DATE: '-l/3/ c,.:;
'
METHOD: _____ TL!CLP
_____ TU CLP Pest only
_____ TU CLP PCBs only
_____ · TU Green Bay PCBs
_____ Other
.EXTERNAL STANDARD METHOD: ___ _
INTERNAL STANDARD METHOD: ---"':__-'-
Concentrations: Pentachlorobenzene (PCNB)
cis-Permethrin (C-PERM)
_____ Tl! 608
_____ TU 608 Pest. only
_____ TLI 608 PCBs only
__ -,-__ Tl! 8080
_ __:✓::__ __ TU 8080 Pest. only
_____ TLI 8080 PCBs only
IS SOLUTION ID: --";).'"'3""-'-i _+-______ _
z_, 0 ug/ml
; po . V ug/ml
:,:t,:!tl'!f ': ·r-~!~1:B~=;· ':lr~nJt~~nr.:~!~="r:·:t: :t~!r:·:s~~7r ['j5%;"3lJllj
3/J.r /c,"5 MX.!O I 3.'.3 fl T: MZ.:, hi A•1 )!'..-:2, '.-Zino O 4-V--
/ \ M'l.10 I :i.Lj /', Di"G so -AA 7-::Z..-(2...Z.., i / " /
ICV
File
AA/lti3D
AJ. t ltJ I 3-1
\JH I() I 3 z_
FCV
I
I
I
I
I
I
I
I
I
I
m
•• •
D
I
D
I
u
page 3 of 3 lG I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
SAMPLE NO.
METHOD 8080 ANALYSIS DATA SHEET
00136 SO-M23-R2
Project No.: 31982B Lab Name: Triangle Labs of RTP, Inc.
Matrix: M23 Lab Sample ID: 97-160-1
Sample wt/vol: 1.00000
\Moisture/Lipid:. iJ/fl
Extraction: ,S()./.
Lab File ID: MX10134
Concentrated Extract Volume: 1. 0 (mL)
Date Received: 03/18/95
Date Extracted: 03/21/95
Date Analyzed: 03/27/95
Injection Volume: 1 (uL) Dilution Factor: 4.00
CONCENTRATION
CAS NO. COMPOUND ug/ Q
<0.0200 319-84-6--------alpha-BHC ________________ _
<0.0200 5103-71-9-------a-Chlordane __________ ---=-'-'-=~
0.1045 309-00-2-~------Aldrin _____________ ---=..:...=.::..:.::.-
<0.0200 319-85-7--------beta-BHC. ___________ ---~=-
<0.0200 319-86-8--------delta-BHC. ___________ ---'-"-'-=-"-"-
0.7046 72-54-8---------4,4"-DDD ___ --'------------=-'-'--=-=-"--
0.7457 72-55-9---------4,4"-DDE. ________________ _
50-29-3---------4,4"-DDT
60-57-1----~----Dieldrin·------------
72-20-8---------Endrin. ____________ _
7421-93-4-------Endrin Aldehyde. _______ _
959-98-8--------Endosulfan I ________ _
33212-65-9------Endosulfan II. ________ _
1031-07-8-------Endosulfan sulfate _____ _
58-89-9---------gamma-BHC (Lindane) _____ _
5103-74-2-------g-Chlordane _________ _
76-44-8---------Heptachlor _________ _
1024-57-3-------Heptachlor epoxide _____ _
<0.0400
0.0489 __ ..::..:..::..:=-
<0.0400
<0.0400
<0.0200
<0.0400
<0.0400
,<0.0200
0.1261
0.0207
<0.0200
<0.2000 72-43-5---------Methoxychlor __________ ---===.:;._
<2.0000 8001-35-2---~---Toxaphene ________________ _
I I
l£!L_l
l£!L_l
i_D __ :
l£!L_
[£!L_
1!£._I
1!£._I
iuo i , ___
i_D __
l£!L_
l£!L_
l£!L_
[£!L_
l£!L_
l£!L_
i_D __
i_D __ :
l£!L_I
l£!L_I
l£!L_I
I I I I
U=undetected, J=estimated, P=%D>25, E=exceeds calib, D=diluted, X=%RSD>40
Prepared by~ on 04/03/95 at 13:00:13
1
17
SAMPLE !fO.
METHOD 8080 SURROGATE RECOVERY
00136 SO-M23-R2
Lab Name: Triangle Labs of RTP, Inc.
I Project No.: 319826
I Lab Sample ID: 97-160-1
I Instrument ID (l): _GC-M ECD-C I
I GC Column (1): RTX-35
Date Analyzed: 03/27/95
Instrument ID ( 2) : G.C-M ECD-D
GC Column (2): RTX-1701
I I I I I · 1 IS I
l REF I ANALYTE I COL I RT I AREA RF I REF I CONC
1=·=:======================!===1========1========]==== · ='===!========
\SS2\DCBP \ l 30.64 260749\13.9892 IS2\ 0.0811
\ ', \ 2 26 .18 198586 1 11. 9899 IS2 \ 0. 0799
I I I I I
\SSl\TCMX
I I
I
I
\IS2
I I
I
\ISl
I I I
I I
I
ci~-Permethrin
PCBNZ
'-'--,---------'
l 7.27
2 6.74
l 25.60
2 23.57
l 6.02
2 5.57
Prepared by~ on 04/03/95 at 11:06:18
I I
181908 14.5153 IS2\ 0.0545 1
92397 12.6070 !S2\ 0.0353
919882
829391,
I I
312597\
61314\
%REC
50.7
49.9
34.1
22.1
l
13
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
••
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
SAMPLE NO.
METHOD 8080 ANALYSIS DATA SHEET
Lab. Name: Triangle Labs of RTP, Inc.
Matrix: M23
Sample wt/vol: 1.00000
l \ I I\ % Moisture/Lipid: 4
Extraction: :it,"'!.
Concentrated Extract Volume:
Injection Volume: 1 (uL)
CAS NO. COMPOUND
1.0 (mL)
00136 SO-M23-R2
Project No.: 31982B
Lab Sample ID: 97-160-1
Lab File ID: MX10143
Date Received: 03/18/95
Date Extracted: 03/21/95
Date Analyzed: 03/29/95
Dilution Factor: 20.00
CONCENTRATION
ug/ Q
I I I I
72-54-8---------4,4'-DDD __________ _ 0.575 I_D __ I
72-55-9---------4,4'-DDE. ___________ _ 0.586 ID ___ I
U=undetected, J=estimated, P=%D>25, E=exceeds calib, D=diluted, X=%RSD>40
Prepared by Fon 03/30/95 at 15:16:59
2
28
SAMPLE NO. METHOD 8080 SURROGATE _RECOVERY
00136 SO-M23-R2 ,.
I , I ---------'
' Lab Name:,Triangle Labs of RTP, Inc. I Project No.: 31982B 2
Lab Sample ID: 97-160-1
-I
Instrument ID (1): GC-M ECD-C
Date Analyzed: 03/29/95
Instrument ID (2): GC-M ECD-D ' I GC Column• (1): RTX-35 GC Column (2): RTX-1701
I
I I
. / REF I ANALYTE I COL I. RT AREA
!IS I
RF IREFI CONC %REC \===\====·================= ===\========l======== =======!==='========!===== iIS2icis-Perrnethrin 1 I 25.60 907295 I
i : 2 i 23.57 979491 i l I ! I I iISliPCBN~ 1 I 6.03 270855 1 i
2 \ 5. 49 368325 i \
I I '-----------'-----
Prepared by~Jj'V'""" on 04/03/95 at 10:42:02 I I ',
I
' ' '
23
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
11
I
I
I
SAMPLE NO.
METHOD 8080 ANALYSIS DATA SHEET
00145 BLANK
Project No.: 31982B Lab Name: Triangle Labs of RTP, Inc.
Matrix: M23 Lab sample ID: 97-160-2
Sample wt/vol: l.00000, Lab File ID: MX10135
•~"'~~\"'~
\ Moisture/Lipid: :2)1 tvf 'f\ Date Received: 03/18/95
/ I
Extraction: ..2Ji! Date Extracted: 03/21/95
Concentrated Extract Volume: l.O (mL) Date Analyzed: 03/27/95
Injection Volume: 1 (uL) Dilution Factor: 4.00
CONCENTRATION
CAS NO; COMPOUND
319-84-6--------alpha-BHC _________ _
5103-71-9-------a-Chlordane ---------309 -00 - 2 - - - - - - - -Aldrin ------------3 l 9 -85 - 7 - - - - - - - -bet a - B H C -----------3 l 9 -86 - 8 - - - - - - - -delta - B H C ----------72 -54 - 8 - - - - - - - - -4, 4' -DD D -----------72 -55 - 9 - - - - - - - - -4, 4' -DD E -----------50 -29 - 3 - - - - - - - - -4, 4' -DDT __________ _
60-57-1---------Dieldrin -----------72 -20 - 8 - - - - - - - - -End r in -.,---------~-742 l -93 -4 - - - - - - -End r in Aldehyde _______ _
959-98-8--------Endosulfan I ---------332 l 2 -65 - 9 - - - - - -Endo sulfa n II --------103 l -07 - 8 - - - - - - -Endo sulfa n sulfate ------58-89-9---------garnma-BHC (Lindane) _____ _
5103-74-2-------g-Chlordane ________ _
76-44-8---------Heptachlor _________ _
1024-57-3-------Heptachlor epoxide _____ _
72-43-5---------Methoxychlor ---------800 l -35 - 2 - - - - - - -To x a p hen e _________ _
ug/ Q
l l l l
<0.0200 :~:
<0.0200 1~1
<0.0200 :~:
<0.0200 :~:
<0.0200 :~
<0.0400 :~:
<0.0400 :~:
<0.0400 :~:
<0.0400 1~1
<0.0400 :~:
<0.0400 :~:
<0.0200 l~l
<0.0400 :~:
<0.0400 :~:
<0.0200 :~:
<0.0200 :~:
<0.0200 :~:
<0.0200 :~
<0.2000 :~I
<2.0000 :~:
U=undetected, J=estimated, P=%D>25, E=exceeds calib, D=diluted, X=%RSD>40
Prepared by ~?(.I"-" on 04/03/95 at 13:00:16
1
37-
SAMPLE NO. METHOD 8080 SURROGATE RECOVERY
Lab Name: Triangle Labs of RTP, Inc. I
I Lab Sample ID: 97-160-2
'
Instrument ID (1): GC-M ECD-C
I GC Column (l): RTX-35
. I
I
00145 BLANK
Project No.: 31982B
Date Analyzed: 03/27/95
Instrument ID (2): GC-M ECD-D
GC Column (2): RTX-1701
I I I I I I Is I I I REF l ANALYTE I COL I RT I. AREA l RF I REF I CONC %REC I l===\==·===================1===l========1========l=======!===1===·====1=====t JSS2IDCBP 1 I 30.66 441292Jl3.9892IIS2 0.1431 89.41 I I 1 2 I 26.19 284542\ll.9899\IS2 0.1095 GB.SI I I I 1 I I I I I J I :ssllTCMX l I 7.27 541944 l4.5153IIS2 0.1693 105.8 \ 2 6.72 468564 l2.6070IIS2 0.1715 107.2
I :
IIS2lcis-Permethrin 1 25.60
I I I I
\ISlJPCBNZ
I
I I
2 23. 58
1
2
6.02
5.58
' I
881961 I I
866694 I ' I I
531498 I I
1316480 I I
I. I
I I
I '-'-~,---------,_, --'
' Prepared
I I
' I
'
by~ on 03/29/95 at 10:14:43
I
I
1 I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
38 •
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
SAMPLE NO.
METHOD 8080 ANALYSIS DATA SHEET
TLI M23 BLANK
Lab Name: Triangle Labs of RTP, Inc.
Matrix: M23
Project No. : 31982B
Sample wt/vol: 1.00000
\ Moisture/Lipid: 0/R
Extraction: C/J~
Concentrated Extract Volume: 1.0 (mL)
Lab Sample ID: TLI BLK
Lab File ID: MX10133
Date Received: 03/18/95
Date Extracted: 03/21/95
Date Analyzed: 03/27/95
Injection Volume: 1 (uL) Dilution Factor: 4.00
CONCENTRATION
CAS NO. COMPOUND ug/ Q
I I
<0.0200 319-84-6--------alpha-BHC __________ ----'===-I~
<0.0200 5103-71-9-------a-Chlordane. ______________ _ I~
<0.0200 309-00-2--------Aldrin ____________ ---'==.c..... I~
<0.0200 319-85-7--------beta-BHC. ___________ --...:..::-=-==-=-I~
<0.0200 319-86-8--------delta-BHC. __________ ----'===-1UD '--<0.0400 72-54-8---------4,4'-DDD. _____________ ...:..::..:....=...:..::.;::_ I~
<0.0400 72-55-9---------4,4'-DOE. ______________ .....;...:..::~ I~ 50-29-3---------4,4'-DDT ___________ --...:..::.c....c...:..::..;;_
60-57-1-~-------Dieldrin ·---------
<0.0400 !~
<0.0400 I~
<0.0400 72-20-8---------Endrin. ____________ ---'-'--'...:..::-"--l~
<0.0400 7421-93-4-------Endrin Aldehyde _______ --=-=-=='--I~
959-98-8--------Endosulfan I. _________ ---'-'=-"--<0.0200 ·1~1
<0.0400 33212-65-9------Endosulfan II. ________ --=-=-=='--l~l
<0.0400 1031-07-8-------Endosulfan sulfate ___________ _ 1~1
<0.0200 58-89-9---------garnma-BHC (Lindane) _____ --===-I~[
<0.0200 5103-74-2-------g-Chlordane _________ --===-!~I
76-44-8---------Heptachlor __ --,--,-------__ ..:..::..:...::.=;:_
1024-57-3-------Heptachlor epoxide ______ ----=..;;_ <0.0200 :~:
<0.0200 I~
<0.2000 72-43-5---------Methoxychlor _________ ---'-==.c.... t~
<2.0000 8001-35-2-------Toxaphene __________ ----'===-[~1
I I , ___ ,
U=undetected, J=estimated, P=%D>25, E=exceeds calib, D=diluted, X=%RSD>40
Prepared by~ on 04/03/95 at 13:00:10
1
49
SAMPLE NO. METHOD 8080 SURROGATE RECOVERY
TLI M23 BLANK
' I ' Lab Name: ,Triangle Labs of RTP, Inc. Project No.: 31982B '
' ' Lab Sample ID: TLI BLK Date Analyzed: 03/27/95
I
I Instrument ID (l): GC-M ECD-C
GC Column (1): RTX-35
Instrument ID (2): GC-M ECD-D
GC column (2): RTX-1701 I
I I I I I I IS
J REF/ ANALYTE / COL / RT AREA RF / REF I===\====·================='==='========!========'======='===
/Ss2/DCBP: 1 30.64 / 399999 13.9892 IS2 I 2 26. 20 \ 288117 ll. 9899 IS2 I I I I i I /SSl/TCMX' · 1 7.27 / 271810 14.5153 IS2
\ \. 2 6.68 1 250493 12.6070 IS2 I l
!IS2 cis-~ermethrin
I
I I
/ISl PCBNZ
I I
I ,_ ---"--------
1 25.61
2 23.58
1 6.02
2 5.49
I _,
Prepared ~y~on 03/29/95 at 10:14:39
' I I
I
9600981
978971 I I I
I I I I
300423\ I I
5642421 I I
I ,_
CONC IREC
======== =======
0 .1191 74.5
0.0982 61.4
0.0780 48.8
0.0812 50.7,
1
50
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I APPENDIX S
VOLATILES LABORATORY DATA
I
I
I
I
I
I
I
I
I
,.
I
D
D
D
D
D
D
u
I
u
I
g
m
g
m
m
I
m
DATE: December 28, 1994
TLI NO: 30908ab
Case Narrative
Triangle Laboratories of RTP, Inc.
801 Capitola Drive
Durham, N.C. 27713
Phone: [phone]
Fax: [phone]
OBJECTIVE: Analysis of one VOST tube pair, and one field blank pair for Method 8240
Table 2 compounds.
METIIOD:
Two pair of VOST tubes were received by Triangle Laboratories of RTP, Inc. in
good condition at 3°C on December 17, 1994. The VOST tubes were stored at 4°C prior
to analysis. The VOST tubes were analyzed according to the guidelines of Methods
8240 and 5040. The internal standards and surrogate standards were added in the
amount of 0.25 ug to each VOST tube immediatefy prior to analysis by GC/MS. The
internal standards are bromochloromethane, 1,4-difluorobenzene, and chlorobenzene-
d5 and the surrogate standards reported are l,2-dichloroethane-d4, toluene-dB, and
benzene-d6. The results reported relate only to items tested.
The GC /MS analysis conditions are listed below:
VOLATILES:
Purge and trap:
Purge:
Desorb Temperature:
Desorb Time:
GC CONDmONS:
Column:
MS CONDmONS:
Instrument:
Scan:
Interface:
REPORT:
Tekmar LSC-2000
11 min.
250C
3min.
30 m x .53 mm x 0.3u J&W DB624
0 C hold .5 min. to 45 C at 10
C/min, to 90 Cat 6 C/min,hold
4 min to 200 at 27.5 C/min.
VGTRI0-1
Lab Base data system
35-350 amu at .6s/scan
Jet Separator, 200 C
Enclosed with the case narrative are copies of the client chain-of-custody, .
sample log-in ~heets, and log ):,ook_ra~. ~roject summary she7ts are enclosed behin_d
the case narrative. A sample identification mdex summarizes client sample name, ·
laboratory identification, and file name for each sample and blank. The prof~ct sum
mary includes the amounts detected which will be highlighted in grey. Estimated detec-
tion limits will be listed in parentheses when the target analytes are not detected.
1
Triangle Laboratories of RTP, Inc.·
Case Narrative
' REPORTI cont:
'
December 28, 1994
30908ab
The data are reported as quantitation reports, chromatograms, interim reports,
and spectra of detecteo. target analytes. The quantitation report header lists the 1LI
project number, analysis method, instrument sample file name, and client sample ID.
The client project number, TII sample ID, calibration file, date received, and analysis
date are also listed in the quantitation report header. The response factors used for all
VOST tuoe calculations are average response factors from the initial calibration listed in
the header. All initial and continuing calibration data are located in the back of the data
package. 1 The amount reported is the amount of the tar__get analyte detected in the
sam2le in1 total micrograms (ug). The retention time (RT) will be listed for all internal
stano.ards and analytes which are detected. If a target analyte is not detected, it will be
flagged with a 'U" and a detection limit will be listed. Estimated detection limits are
calculated using an area of 2000 for all analytes which were not found in the sam12les.
The quantitation limit for all analytes is half of the low point of the initial calibration.
The estimated detection limits reported are the average detection limits achievable over
time on an instrument type. The actual detection limit for a given compound on a given
day may vary from the estimate reported. Below this point the calibration cannot be
considered to be linear. Any amounts reported at a level below the quantitation limit
will be flagged with a "J" and should be considered estimates. If a target analyte is
found at a level exceeding the upper calibration limit, it will be flagged with an "E" and
· should also be considered estimated. In the event that an analyte is sufficiently above
the calibration ran~e that the mass spectrometer becomes saturated, the analytes will be
flagged with "SAT' and any amount reported should be considered underestimated.
All target analytes are quantitated against the internal standard preceding them on the
target analyte list. Surrogate standards are quantitated against the internal standard
with the Il}atching internal standard reference number. For example, toluene-dB has 3
in the IS Ref column and would be quantitated against the internal standard which has
IS3 listed in the flag column. If an internal standard area is ·above or below the quality
control limits as defined by the continuing calibration, it will be flagged with "High" or
"Low" in the flag column.
I I
RESULTS:
' I
The VOST tubes were analyzed in tandem. As no specific sampling date was
given for the sample and the field blank the sampling to analysis h9lding times could
not be determined. Both the sample and the field blank were analyzed within five days
of receipt. , . I
All internal standard areas and surrogate standard percent recoveries met
method QC criteria.
The_method blank contained,bromomethane at a level below the quantitation -
limit. This target analyte should not be considered as truly present in the native samples
unless found at levels at least five times the level found in the associated blank.
· Sample Ul-VST-R2-00303/00305 T/TC contained chloromethane at a level above
the upper calibration limit and sufficient to saturate the mass spectral detector. The
amount reported for saturated compounds should be considered as underestimated.
I
I
2
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
·1
I
I
m
m
I
I
I
I
I
:1
I
I
I
.I
I
I
I
I
I
I
I
Triangle Laboratories of RTP, Inc.
Case Narrative
SAMPLE CALCULATIONS:
Response Factor (RF) =
Amount in ug =
(area analyte) x (amt IS)
(area IS) x (amt analyte)
(area analyte in samifJe} x (amt IS)
(area IS) x (avg ical )
Where: ical = initial calibration
amt IS = amount of internal standard = 0.25 ug
December 28, 1994
30908ab
amt analyte ical = amount of analyte in the ical = .1 to 1.0 ug
The data reported has been judged as meeting the guideline of Method
8240/5040 excepted as previously noted. This report should only be produced in full.
Any reproduction of this report requires permission from Triangle Laboratories of RTP,
Inc. Should you have any question regarding this data package please feel free to con-
tact our Air Quality Senior -Project Manager, 1fani Karam, at [phone].
For Triangle Laboratories, Inc.,
Report Prepar ·on:
' 1'-1-Z.°) \J
Quality Control:
aration Chemist
/J SIL /17' Selena Armistead
· Report Preparation Chemist
The total number of pages in the data package is
3
Triangle Laboratories of RTP
Sample Identification Index for Project 30908ab
Ul-VST-R2-003a3/00305 T/TC
BLK-VST-R0-00309 /00311 T /TC
VOSTBLK122294
i
I
Triangle Laboratories of RTP, Inc.
801 Cap;to!a Drive • Durham, North Carolina 2m3
Phone: [phone]n9 • Fax: [phone]
I
I
93-100-lA/lB
93-100-2A/2B
. VOSTBLK12229
I
I
FP041 I
FP040
FP028 I
I
I
I
I
I
I
I
I
I
I
I
I
I
Pro~Sum v4.0 I
4 I
·I Triangle Laboratories of RTP
Project Summary for Project 30908ab
I Client ID:
I Filename:
TL!Id :
Matrix : I Units :
Ul-VST-R2-
00303/0030
ST/TC
FP041
93-100-lA/lB
VOST
ug
BLK-VST-RO
-00309 /003
11 T/TC
FP040
93-100-2A/2B
VOST
ug
VOSTBLK122
294
FP028
VOSTBLK12229
VOST
ug
Otloromethane 'I Vinyl Otloride
Bro mo methane
tBMMJ@WHJq~~ Iirn@1m£.tJm1.~~u.~ (0.004)
(0.003) (0.003) (0.003)
Otloroethane I Trichlorofluoromethane
(0.003) (0.003)
ffffli1Mi!uM9lm'.!ll (0.001>
1,1-Dichloroethene (0.002) (0.002)
I, Carbon disulfide
Acetone ·,
I
I
Methylene chloride
trans-1,2-Dichloroethene
1,1-Dichloroethane
cis-1,2-Dichloroethene
Otloroform
1,2-Dichloroethane
I Vinyl acetate
2-Butanone
1,1,1-Trichloroethane
(0.002)
(0.001)
(0.001)
(0.001)
(0.001)
(0.014)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.014)
(0.001)
(0.001) I Carbon tetrachloride
Benzene
Trichloroethene
~#fr@HWF1ft@S9~ :m:::tn:~!!!@fEF•
11,2-Dichloropropane
Bromodichloromethane
I cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
1,1,2-Trichloroethane
I Dibromochloromethane
Bromoform
4-Methyl-2-pentanone
I Toluene
Tetrachloroethene
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.002)
(0.001)
(0.003)
(0.002)
(0.002)
(0.003)
(0.001)
2-Hexanone I Otlorobenzene
~· Ethylbenzene
I m-/p-Xylene
o-Xylene
lz£Jj9; i M 'O,oM
mtAJ:f tttttt:@JJiif.
*~Nim!JrtSt!!]JiJ)®.~:
I Triangle Laboratories of RTP, Inc.
801 Capitola Drive • Durham, North Carolina zm3 I Phone: [phone] • Fax: [phone]
, (0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.002)
(0.001)
(0.002)
(0.002)
(0.002)
(0.003)
(0.001)
(0.001)
I tiiW@ P!im:l'
(0.001)
( )•&timated Detection Limit
(0.003)
(0.001)
(0.002)
(0.001)
(0.006)
(0.002)
(0.002)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.015)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.002)
(0.001)
(0.003)
(0.002)
(0.001)
(0.002)
(0.003)
(0.001)
(0.001)
(0.001)
(0.001)
Page 1
Savarv3.4
Printed: 10:23:32 U/29!9'!)
Client ID:
Filename:
TU!d :
Matrix :
Units :
Triangle Laboratories of RTP
Project Summary for Project 30908a b
Ul-VST-R2-
003{8/0030
ST/TC
FP041
93-100-lA/1B
VOST
ug
BLK-VST-RO
--00309 /003
11 T/TC
FP040
93-100-2A/2B
VOST
ug
VOSTBLK122
294
FP028
VOSTBLK12229
VOST
ug
1,1,2,2-Tetrachloroethane (0.001) (0.001)
(0.001)
(0.002)
Triangle Laboratories of RTP, Inc.
801 Capitola Drive • ~ham, North Carolina 27713
Phone: [phone] • Fax: [phone] !
( ).Estimated Detection Limit Page 2
I
I
I
I
•·
I
'I ·-·
I
I
I
I
I
I
I
I
I
I
Savarv3.4
Printed: 10:23:32 12/29/94()
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
December 16, 1994
Debbie Hage
Triangle Laboratories, of RTP Inc.
801 Cacitola Drive
Durham~ NC 27713
RE: VOST ANALYSIS,
ETS I? .0.: 5273
ETS CONT:<ACT #:94-365-T
Dear Debbie:
Accompanying this let~er is one cooler containing two pair of
VOST sampling tubes(Run #2 and one blank). Use M8240 TABLE 2 to
analysis these samples. A 14 day turn around is requested for
Run #2 and a 21 day turn around for the blank.
Please feel free to call if you have any questions.
Sincerely,
~~~
Terry G. Williamson
Manager/Field Prep.
/TG''ll
Enclosure(s}
7
Contract No. 94-365
Job I.D.
Test Method VOST
JsampleJContainerJ Other
I No. I Ho. I 1.0.
I I -I I o-0J oo I El I
1o~g1 I 1"3 I
J(H)rn2 I f'2 I -·----J00303 I Fl I
I og3g1 I f'3 I
100305 I F2 I
100309 I Fl I
I 00310 I FJ I
100311 I F2 I
I
I
I I \Jl
101 p11
Jul
Jth
I !!1
IDLK
IDLK
IBLK
E T S I N C .
F I E L D S A M P L E L O 0
Print Date 12/16/94 Time 13:22:05
Page 1
Run Sample JVolume,mlJVolume,mliAnalystJ Date
1.0. Type Jno RinsesJw/ RinsesJ I
I I I I I
•o'~T-!~:!=-f IJOS I TUBE -tllllRCOl\!J I I I re1t-f 12 '16 1s11 i t:
-VST Rl ITFDI.AR BAG I I I 'l'QH I tJ/1fl9~I
'o'3'i' Rl 1vvs1 I tffl8 !Flnrnx I I I TGW I n/Ji:fJ'lt
-VS'f-R2 IVOST TUBE -CIIARCOALI I I TGW J12/16/94J
VST P1 l'PBDL/ltR BAG I I I IG~ J Hf'.1:6/ 9"'4 J
-VST-R2 JvosT TUBE -TENAX I I I TOW 112/16/94I
-VST-RO IVOST TUBE -CHARCOAL I I I TOW 112/16/94I
VST PO I TEDI l\.P 9,11.,e I I I TOU I H! '161911 -f I
-VST-RO IVOST TUBE -TENAX I I I TGW 112L1GL94J
Comments
I
Custoov Seal Present/Intact : ILi Project Nu■oer : 30908
Chain of Custodv Present t····················t····································1
Sa■ole Tags Present : Client: ETS02 : ETS, INC.
1 ... ~;~:~;~;;:.::::::: ... :.~~~~~~ .................................. :·~~~:·;:~:~::~······:·;;;;;;;~··:·~~~-··;·;~~:·;
I 93 '
Ice Chest ICE le■o 3.0 C ' Carrier and Number. : FedEx/ : 100
1···································1···········+···········1···········1···········1···········1···········1.•·········+···········1
TL! Number "atrix : To LAB ! To STORAGE: To LAB ! lo STORAGE: To LAB ! To STORAGE; To LAB : To STORAGE:
: IR/H:CP" Client ID Location : Date/lnit : Oate/lnit ! Oate/Init : Date/lnit·: Oate/Init : Oate/Init : Date/Init : Oate/lnit :
···································1···········+···········+···········1···········+···········1···········+···········+···········1
I 13· 100· lA IEHAX ' ' ' ' 1 1 1 , . , l I I I I , I I I t
Ul·VST·R2·oo305 I···········+········ ···+···········+···········1···········+···········+···········1···· ······+
FRIG13 : , : , , 1 , : :
l :·93·100·18················1HX/CHAR·:···········:·········· :···········:···········:···········:···········:····· ······:···········:
• I I . I I I I , I I J. . I
' U 1 • VS l · R2: OOlOl t· · · · · · ·· ·. ··+····· ······I··········· I·· .... ·•··. I·· ... •• ... · I· ..•••..••• 1· .•.•.•.•• ·+· •••...•...•
1: ............................ :::::~.: ........... : ........... : ........... : ........... l ........... : ........... : ........... : ........... :
: 93-100·2A TENAX 1 ' ', 1 -t • 1 , , ' '
I BLK-VST-RO=OOJll +-----------+-----------+-----------+-----------+-----------+-----------+-----------+-----------+
ll ............................ FRIGll.; ........... ; ........... l ........... ; ........... l ........... ; ........... l ........... ; ........... ;
' 93·100·2B INX/CHAR ' ' ' '
BLK·VST·R0=00309 +-----------+-----------+-----------+-----------+--·-------·+·-·····----+···--··----+-··--·-··--.
I
I I I I I I FRIGIZ
·-----------------------------------+-----------+-----------+-----------+-----------+-----------+-----------+---------·--+-----------+
' ' 1; I I 1 I
+···-····---+--···--··--+·-·----·-··+-··--····-·+···········+-···-····-·+·····---··-+---··--·--·+
I
I ' '
I ~.-·-+ +·· ···-+-·····--··· +···-·-··-··r-···-·-· ·-:····--··---+-·-··------:·--·-·--·--·:
············•·····--····+·····-·····+--·······-·+·····-·····+-····-···-·+-··-··-···+·-·--·······
I ,.
I . I 1 I I I I
I~·····-······-···-···············-··:··········-~·-·········~···········~···········:···········:--·-···-···:··-····--··:·········-·:
I . I I I I , 1 I I I
+·······-···+--··-···-··+········-··+··-·-······+·······-···+····-···-··+·-···----··+······--····
: : I I I I . I I . I I
I. I I t I I I I 1
:··--·····-·····-···-··············-:···········;···········;···········:-···-······:···-·······;-·········-;···········:·····--·-··~
' ' ' I I l I
+···--······+····-······+······-····+·-······-··+·····-·-·-·+···········•···········+····--·····+
I . ' I I I I I t \
!······················-·-·····-····~···-···-··-+····-··--··+-··--······•······-··--+-····-·····+·-·········+-····--···-+·-·········•
I
I '
• I I I I t I
T••·· .....•...•..•....•.•.... _••••·······+••·•·······+••········-T···········•····•······t•··•·····•·t•••••···•••T··••··•••••t
I
I I I 1
~··--·-·····i··········-+-···-······+··········-+···········+·········-·+·······-···t•-··-·---··+
I I I I l
• 1 ' 1 I I I •
~················-··················+···········~·········-·+····--·····+···········+-··········t···--······+·····-·····+·--········+
· Receiving Reman.s: No :eEo:r.;turc "·',;.nr arrive; w1· tn sa■ole'.. ' t •1 · • • . , e•oerature , an,. was provided by 1 riangle labs .
I Ar:nive Remark;:
•····························•·;.,mGL[ LA60RATG.IES or RTP.
. . . . . . . . . . . .. . . . . . . ........ .. . ........ .... .. . . . . . . . . . .. . . . . . . . . . . .. . ·., :· . ' ................ · ............ · 9
. . .
INC.··CHAIH Of cus;oDY··RE11SED ll/15/Q4 ........................... .
i
- - -... - ----_, - - - - - - - --; -TRIANGLE LABORATORIES OF ATP, INC. RUN LOG
MS# COLUMN TYPE COLUMN# ANALYSIS . ACQ METHOD GC METHOD FIND DB'S OTHER
'F \::i'bhZ,-1 ,,_ "i '?,."' "'\ ., ") "?iz-ro '-)<~ f<> clJ,n-1. ~"J 1.,,I,/~ t·
EXTRACT/ SAMPLE VOLUME uL/mL ', 2. . ' .
DATE TIME PROJECT# SAMPLE# CLIENT SAMPLE ID FILENAME OPER BACKUP PROC pH
NET ARC
·v h 't ~·-t. r
/J(:, I'~•">'-r ... -.~,,.,
INTERNAL STANDARD SURROGATE STANIJARD ANALYTE STANDARD
I I I
TRIANGLE LABORATORIES OF RTP, INC. RUN LOG ,-
MS# COLUMN TYPE COLUMN # ANALYSIS ACQ METHOD GC METHOD FIND DB'S OTHER .---
1.. "\ \..) IJ\1 1. t.tlo f'
EXTRACT/SAMPLE VOLUME ____ _ uL/mL 2.
DATE TIME PROJECT# SAMPLE# CLIENT SAMPLE 10 FILENAME OPER BACKUP PROC pH COMMENTS
NET ARC
I 1,'
]1\,,
I,., E?-¼ ~
11<> lb\.-e VJ\' ',C o 11 '
ANALYTE STAtlDARD
-~~~~ _, •,
Project·Ntimber: 30908AB Method 8240 VOST Sample File: FP04l Sample ID: Ul-VST-R2-00303/00305 T/TC
BromochloroIT;ethanc
ChlofomcthanC:
I Vinyl Chloride
Bromomerhanc
Chlorocthane !
T richlorofluoromcthanc
I I, 1-Dichlorocthene
Carbon disulfide
i Acetone
I
Methylene chl~ride
trans-1,2-Dichloroethene
' I, 1-Dichlorocthane
' cis-1,2-Dichloroethene
I
Chloroform I
1,2-Dichlorocthane
1.4-Difluorobe~zene
Vinyl ac.ctacc I 2-Butanonc
1, I, 1-T richlorcicthane
I
Carbon tetrachloride
Benzene
T richloroethen~
1,2-Dichlorop'.°pane
Bromodichloromcthanc
cis-1,3-Dichloropropene
crans-1,3-Dichloropropene
' !
!
IS I
46.203 E ':>1-1''\
u
0.768 B
u
0.010 J
u
0.010 J
0.615
0317
u
u
u
0.004 J
u
IS 2
u
u
u
u
0.089
u
u
u
u
u
4.96
1.10
J.69
2.15
2.88
2.94
3.37
5.10
6.14
5.60
0.003
0.003
0.002
0.002
0.001
0.001
0.001
0.001
0.014
0.001
0.001
0.001
0.001
0.001
0.001
0.001
NA• Not Applicable; Del Limit: Detection Limit; Quan. Limit: Quantitation Limit
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
·0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
7 2
IS: Internal Standard; U: Undetected; B: Pre.sent In Blank; J: Estimated-Below Quantitation Limit; E: Estimated-Above C.aJibration Range
Triangle Laboratories of RTP, Inc.
. 801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544!5729 • F= [phone]
Savarv3.4
Printed: 13:53 12/7.8/1994 .
:
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I Project Number: 30908AB
Sample File: FP041
Method 8240 VOST
Sample ID: -Ul-VST-R2-00303/00305 T/TC
I .;~~~~
I=======..,,......,..,.==~.....,,....,..
I
I
1, 1,2-T richlorocthane
Dibromochloromethane
Bromoform
Chlorobcnzcne-d ,
I 4-Methyl-2-pentanone
Toluene
T etrachlorocthene
I 2-Hcxanonc
Chlorobenzene
Ethylbcnzene
I m-/p-Xylcne
a-Xylene
I Styrene
1, 1,2,2-Tetrachlorocthane
1,2-Dichlorocthane-d
I Benzene-cl 6
Tolucne-d •
•
I
I
I
0.040
0.003
0.017
0.006
0.009
0.287
0.301
0.309
u
u
u
IS 3
u
J
u
u
u
J
J
J
J
u
10.39
8.06
10.74
10.97
11.71
11.77
5.58
5.56
7.97
I Reviewed by 4{_ ) Date /L1Z£119:f . .
0.002
0.001
0.003
0.002
0.002
0.003
0.001
0.001
1
2
3
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.10
0.05
0.05
0.05
115
120
124
1 3
I c.7' NA-Not Applicable; Del Limit Detection Limit; Quan. limit Quantitation Limit
•-■1s,_,,.1n■•■•■m■•■l ■S11ta■n11da■r■d■;■u.,,■u■n■d■•tect-■ed,i;■B■,■P■res-•n■••I11n■Balan-lc;11·.,J,■Es_,,•i,.ma-••,.d,.-,.B.,•l.,o■w•Q;,u,.•■n■ti■ta■ti■o■n■L■im■ai~i,E,■·■Es-ti■m■•ate11d11-.,A■b■ov■••C.;,;tJ_ib11r■••■io■n-R11an.;g;.• __
Triangle La.boratories of RTP, Inc.
I 801 CapitOta· Drive • Durham, North Carolina 27713
Phone: _(919) 544-5729 • Fa,c [phone]
Savar v3.4
Printed: 13,53 12/28/1994
I
Project Number: 30908AB
Sample File::FP040
Bromochloromc:ilianc:
I
I I
Chloromethane
Vinyl Chloride
Bromomcth.anc: I
Chloroethane I I
I
T richlorofluoromC:tlianc:
1,1-Dichlorocthene .
Carbon disulfide
Acetone
Methylene chloride
trans-1,2-Dichloroethene
1,1-Dichlorocthane .
cis-1,2-Dichloroechene
Chloroform I
1,2-Dichlorocthanc
I
I.4-Difluorobcnzcne
Vinyl aa:tare
2~Butanonc:
I
I 1, !, 1-T richlorocthi"'e
Carbon cecrachloride
Bcnune !
I T richlorocthene I
. 1,2-Dichloropropape
Bromodichloromc:thanc
I
cis-1,3-Dichloropropene
I
crans-1,3-Dichloropropene
IS 1
0.014 J
u
0.015 BJ
u
u
u
0.004 J
0.398
0.433
u
u
u
0.004 J
u
IS 2
u
u
u
u
0.042 J
u
u
u
u
u
Method 8240 VOST
Sample ID: BLK-VST-R0-00309/00311 T/TC
4.96
1.13
1.69
2.88
2.94
3.37
5.10
6.14
5.60
0.003
0.003
0.001
0.002
./
0.001
0.001
0.001
0.001
0.001
0.014
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
-NA• Not Applicable; Det. Liinit Detection Limit; Quan. Limit: Quantitation Limit
IS: Internal Stapdard; U: Undetected; B: Present In Bbnk; J: Estimated• Below Quantitation Limit; E: futimated• Above Calibration Range
Triangil!'taboratori~.s of RTP, Inc.
801 CapitolaDrive • 'ourham, North Carolina 2m3
Phone: [phone]n9 • Fax: [phone] • • I
Savarv3.4
Printed: 10:17 12/29/1994
29
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I.
I
.I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Project Number: 30908AB
Sample File: FP040
l,l ,2-T richlorocthane U
Dibromochloromethane U
Bromoform
Chlorobcnzcne-d1
4-Methyl-2-pcntanone
Toluene
T cuachlorocthcnc
2-Hc:xanonc
Chlorobcnzcne
Ethylbcnzcne
m-/p-Xylene
a-Xylene
Scyrene
1, 1,2,2-T ecrachlorocthane
1,2-Dichlorocthane-d,
Ben:zcnc-d • Toluene-cl •
Reviewed by_...u,_d,L....-l _
-----
u
IS 3
u
0.026 J
u
u
u
u
0.010 J
u
0.006 J
u
0.293
0.306
0.322
Method 8240 VOST
Sample ID: BLK-VST-RO-00309/00311 T/TC
10.36
8.06
10.94
11.75
5.58
5.56
7.97
0.002
0.001
0.002
0.002
0.002
0.003
0.001
0.001
0.001
0.001
2
3
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.10
0.05
_0.05
0.05
I 17
122
129
NA-Not Applicable; Det. Limit Detection Limit; Quan. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected; 8: Present In Blank; J: Estimated-Below Quantitation Limit; E: Estimated-Above Calibration Range
Triangle Laboratories of RTP, Inc.
801 Capitola Drive.• Durham, North Carolina 2m3
Phone, [phone] • Fax: [phone] .
Savar v3.4
Printed, 10,17 12/29/1994.
30
Project Number: 30908AB'
Sample File:!FP028
Method 8240 VOST
Sample ID: VOSTBLK122294
-
Bromochloromcthanc
Chloromechane
Vinyl Chloride
Bromomcthanc
Chlorocchane
T richlorofluoromCthanc
I 1,1-Dichlorocchene
I Carbon disulfide '
ACCtonc
Mechylene chloride
trans-1,2-Dichlorocchene ' 1, 1-Dichloroechan'e
cis-1,2-Dichloroechene
Chloroform
1
1,2-Dichlorocchane
!
1,4-Difluorobcnzehe
Vinyl acetate
2-Butanonc
1, 1, 1-T richlorocchane
' Carbon tetrachloride
Bcnu:nc
T richlorocchene 1
1.2-Dichloroprop:ine
Bromodichloromcthanc
ci,-1,3-Dichloropropcne
· trans-1,3-Dichloropropene
IS 1
u
u
0.013 J
u
u
·U
u
u
u
u
u
u
u
u
IS 2
u
u
u
u
u
u
u
u
u
u
. 4.96
1.75
6.13
0.004
0.003
0.003
0.001
0.002
0.001
0.006
0.002
0.002
0.001
0.001
0.001
0.001
0.001
O.oJ5
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
NA-Not Applicable; Det. Limit: Detection Limit; Quan. Limit Quantitation Limit
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
.0.05
0.05
0.05
0.05
0.05
0.05
0.05
IS: Intemal S~nda.rd; U: Undetected; B: Present In Blank; J: Estiinated-Below Quantitation Limit; E: Estimated-Above CaJibration Range
Triangle l.a.boratories of RTP, Inc.
801 Capitola Drive •!Durham, North Carolina 2m3
Phone, [phone] • Fwc [phone]
I
Savar v3.4
Printed, 13,52 12/28/1994
'1 3
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I Project Number: 30908AB
Sample File: FP028
I
I
I
I I, 1,2-T richlorocthane
Oibromochloromethane
I Bromoform
Chlorobenzene-d ,
I 4-Mechyl-2-penw10ne
Toluene
T etrachloroechene
I 2-Hcxanone
Chlorobenzene
Echylbc:nzene
I m-lp-Xylene
o-Xylene
I
Styrene
I , 1,2,2-T errachlorocchane
1,2-Oichlorocthane-d • I Benzenc-d • Toluene-d •
I
I
I
I
u
u
u
IS 3 10.39
u
u
u
u
u
u
u
u
u
u
0.275 5.58
0.278 5.56
0.286 7.98
Method 8240 VOST
Sample ID: VOSTBLK122294
0.002 0.05
0.001 0.05
0.003 0.05
0.002 0.05
0.001 0.05
0.002 0.05
0.003 0.05
0.001 0.05
0.001 0.05
0.001 0.10
0.001 0.05
0.001 0.05
0.002 0.05
I 110
2 111
3 I 14
I
Reviewed by Ill,) Oare JZ,JE::) ~ NA-Not Applicable; Ott. Limit Detection Limit; Quan. Limit Quantitation Limit
I
IS: Internal Standard; U: Undetected; B: Present In Blank; J: utimated-Below Quantitation Limit; E: Estimated-Above Calibration Range
Triangle Laboratories of RTP, Inc.
801 Capitola Drive • Durham, North Carolina 2m3
Phone, (919) 544-Sn9 • Fax, [phone]
Sav%3.4 . ,1
Printed, 13,52 12/28 94
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
1•
APPENDIX T
FIELD EQUIPMENT CALIBRATION DATA
I
I
--------------

-

-
--

-
.. -'
E T S I N C .
METER CONSOLE CALIBRATION FORM
Contract No. 94-263
Job I.D.
Meter Box No.: 10
Delta H: 1.7002
Gamma: 1.0046
Print Date 12/22/94
Analyst: w1L:._ t )t.,.L __
Calibration Date: 12/22/94
Test Meter No. 9548
Barometric Pressure. 29. 06
QA/QC Check: VLl/-f¥4-uL;:s..Ll'...-'i'/-./""'-~U.· ';a-·=_..,."°:/;l_/.1.::i/1f
Previous Cali OB/05/94
Previous Gamma:
RuniOrfiinitial Final Volume InitlFinllTest !Initial Final Volume 11-1 11-0 IF-I IF-0 !Temp I Time I Delta 111 Gamma
!Seti Test Test Test Tempi Tempi Temp I Box Box Box ITemp!TempiTempiTempl I I I _,_, _,_, I ,_,_,_,_, I_I I
I I I I I I I I I I I I I I
1 !0.5,308.213 316.851 8.638 12.0112.0112.001103.560 792.122 0.562112.0115.0l7o.ol73.ol12.5ol20.511.63275l1.00055I
_. ,_, _,_, __ , ,_,_,_,_, __ ,_, I I
I I I I I I I I I I I I I I
2 11.01317.213 333.492 16.279 12.0114.ol1J.001192.402 808.746 16.264l75.0l73.0l81.0l76.0l76.25l27.5l1.64915 1.004481 _,_, _,_,_, ,_,_,_,_, ,_, I
I I I I I I I I I I I I I
3 11.5,333.740 343.947 10.207 74.0l74.0l74.00l808.992 819.212 10.220101.0116.0l85.0l77.0l79.75l14.5ll.74455 1.005671 _,_, _,_, __ , ,_,_,_,_, __ ,_, I
I I I I I I I I I I I I I I
4 12.01344.737 355.152 10.415l74.0l80.0l77.00l820.000 830.464 · 10.464l84.0l77.0l86.ol79.ol01.5ol12.5ll.67358 o.998601 _,_, ,_,_, I
,_,_,_,_, ,_, I
I I I I I I I I I I I I I I
5 i2.5J355.55l 365.532 9.981l75.0J75.0l75.00J830.856 840.847 9.9911s2.0110.0Js1.0J19.0101.5ol11.011.15o85 1.004101 ,_,_, ,_,_, __ , ,_,_,_,_, ,_, I
I I I I I I I I I I I I I I I
I 6 J3.oJ365.109 377.211 ll.422J76.0J74.0l75.00J841.106 852.536 11.430l84.0J79.0J01.0J00.0J02.50J11.5Jl.75027 1.0056oJ ,_,_,, ,_,_,_, ,_,_,_,_, I_I I
I
\"
R
E,T.S. INC.
PIETER CONSOLE t14..JBRATION FORM
I REFERENCE Clll.IBRATOR Meter Box No ........... 10 HH71 Cii.-K
THERIIOCOUPLE NUMBER I Date .................... 19-Sep-94
Reference Theraccouple Difference
Te,perature Te,perature i
I 0 0 0.000
2 32 31 0.203
3 100 99 0.179
4 200 2ll0 0.000
5 300 301 -0.132
6 400 400 0.000
7 500 499 0.104
8 &00 &01 -0. 094
9 700 701 -\J, 08&
10 800 800 0.000
II 900 901 -\J,074
0. 009 AVERAGE OIFF
Calibration Perfor,ed By .. • .. .. CARL POW8.I.
I
I
i Post Test Calibration-Contract 1\-
' i
Pre-Test Calibration-Contract#-
1
Couents:
I
·I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I(
I
I
I
I
I
I
I
le.
I
I
I
I
I
I
I
R
E.T.S. INC.
ME1ER CONSOLE CALIBRATION FORM
Meter Box No •••••••••••
THERMOCOUPLE ~ER
I
2
3
4
5
&
7
8
9
l0
II
10
2
Reference
Te,perature
0
32
100
200
:l00
400
500
&00
700
800
100
Calibration Perfor■ed By .••••••
Post Test Calibration-Contract#\-
Pre-Test Calibration-Contract#-
Conents:
REFERENCE CALIBRATOR
Date ••••••••••••••••••••
Ther■ocouple Difference
Te■perature i
I ~.217
32 0.000
91 0.179
200 0.000
300 0.000
399 0.11&
411 0.104
&00 0.000
&99 0.00&
719 0.079
899 0.074
0.038
CARL POWEil.
. '
HH71 CAL-I\
19-Sep-14
AVERAGE DlFF
(
R
E.T.S. INC.
METER CONSOLE CALIBRATION FORM
I Meter Box No ••••••••••• 10
THERMOCOUPLE NUMBER 3
Reference
Teoperature
I 0
2 32
3 100
4 200
5 300
0 400
7 500 a 000
g 700
10 800
II q00
I Calibration Perfor■ed By •••••••
I
Post Test Calibration-Contract 11\-
1
Pre-Test Calibration-Contract II-
!
Couents:
REFERENCE CALIBRATOR
Oate ••••••••••••••••••••
Thenocouple Difference
Te■perature i
0 0,000
32 0.000
qq 0.179
200 0.000
300 0.000
400 0.000
4qq 0.104
000 0.000
700 0.000
800 0.000
899 0.074
0,032
CARL POW8.l.
HH71 CAL -I<
19-Sep-94
AVERAGE DIFF
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
D
I
I R
I
E.T. S. INC. I METER CONSOLE CALIBRATION FORM
I Met er Box No ........... 10
THERIIOCOUPLE NUMBER 4
ReferJ1nce
I Teoperature
I 0
2 32
I 3 100
4 200
5 3ll0
I & 400
7 500
8 &00
9 700
I 10 800
ll 900
a Calibration Perfor,ed By •••••••
I Post Test Calibration-Contract #\-
I Pre-Test Calibration-Contract#-
1
I
I
I
Conents:
REFERENCE Cl\LIBRATOR
Date ••••••••••••.•••••••
Ther,ocouple Difference
Teoperature i
0 0.000
3ll 0.407
98 0.357
200 0.000
3ll0 0.000
400 0.000
498 0.2\l8
&00 0.000
&99 0.08&
799 0.079
899 0.074
0.110
CSlRL POWELL
HH71 CAL-K
19-Sep-94
AVERAGE DIFF
(
R
' I E. T.S. INC.
METER CONSOLE CALIBRATION FORM
Meter Box No ..... , ..... 10 REFERENCE CALIBRATOR lfl71 CAL -K
THERIIOCOUPLE t{JMBER 5 Dat, .................... 19-Sep-94 : Reference Theroocouple Difference
Te■perature Te■perature %
I 0 I -0.217
2 32 31 0.203
3 100 99 0.179
4 200 -200 0.000
5 300 300 0.000
& 400 400 0.000
7 500 4% 0.208
B 600 &01 -0. 094
q 700 700 0.000
10 800 799 0.079
II 900 gqq 0.074
Calibration Perfo~■ed By....... CARL POWELL
0.039 AVERAGE DIFF
I
i
I Post Test Calibration-Contract II\-
Pre-Test Calibration-Contract Il-
l
I
I
Co1■ents:
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
t
I
I
I
I
I
I
I
I
I
I
I
I
I
R
E.T. S. INC.
METER CONSOLE Clll.lBRATION FORM
Meter Box No ••••••••••• 10
THERMOCOUPLE NUMBER &
Reference
Te■perature
I 0
2 32
3 100
4 2011
5 3ll\l
& 400
7 500
a &00
9 700
10 800
11 900
Calibration Perfor ■ed By •••••••
Post Test Calibration-Contract#\-
Pre-Test Calibration-Contract i-
Co11ents:
REFERENCE ClUBRlHOR
Date ••••••••••••••••••••
Ther■ocouple Difference
Te■perature i
0 0.000
31 0.203
98 0.357
2011 0.000
301 -0.132
400 0.000
499 0.104
&01 -0. 094
700 0.000
800 0.000
901 -0.074
0.033
CARL POWELL
HH71 CSll. -K
19-Sep-94
AVERAGE DIFF
(
(
R
E. T.S. INC.
METER CONSOLE Cl11.IBRATJON FORM
I ' Meter Box No,,;, ••••••• 10
' THERMOCOUPLE NUMBER 7
i Reference
I Te■perature
I 0
2 32
3 100
4 200
5 300
& 400
7 500
B &00
q 700
10 800
II q00
i
I
Calibration Perfor■ed By •••••••
I Post Test Calibration-Contract 3\-,
Pre-Test Calibration-Contract I-
Couents:
REFERENCE CALIBRATOR
Date ....................
Ther■ocouple Difference
Te ■perature ~
0 0.000
30 0.407
qq 0,17q
21'10 0.000
300 0.000
,qq 0.11&
4qq 0.104
&00 0.000
700 0.000
7qq 0.0n
sqq 0.074
0.087
CARL POWELL
. HH71 IA-K
1q-sep-q4
AVERAGE DIFF
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
a
I
I
I
I
I
I
' I
I
I
I
I
I
I
I
I
R
flETHOD 26 METER BOX CALIBRATION
METER BOX I. D. :
DATE:
BllROMETRIC PRESSURE:
Box 18
6/13/94
Z'l, 171 in. Hg.
TEDiNICIAN: Robert Richards
BUBBLE TUBE DATA:
Calibration Te■p. !Teall:
Bubble Tube Volu■ e (Vt):
Calibration Test Data:
Ti1e for Test I
Ti■ e for Ti!St 2
Ti>e for Test 3
Ti•e for Test 4
Ti■ e for Test 5
Ti■ e for Test 6
Ti,e for Test 7
Ti■e for Test 8
Ti■e for Test 9
Ti1e for Test 10
Average Test Ti,e
METER BOX DATA:
~eter Box Te1perature -F
Meter Box Volu,e -L
Meter Box dH ~:
Duration of Cal. Test:
CALIBRATION DATA:
Bubble Tube Rate:
Meter Box Rate:
METER BOX GAMMA:
74 F
I. 0 L
60. 22 seconds
60.19 seconds
60. 02 seconds
60.15 seconds
60.18 ;econds
59.88 seconds
60. 29 seconds
60.22 seconds
· 59. 97 seconds
60,15 seconds
60.127
Initial
8-1
7470.57
I. 3
seconds
Final
88
7484.61
14 1in
0.99789 LPII (actual)
l.llll286 LPII (actual)
I. 0141
Note: The ,eter box ga11a is calculated based on standard
te■perature and pressure.
(
c
R ' ' ,.
E. T, S. INC.
METER CONSOLE CSU.IBRATION FORll
Meler Box No ••.•• ! .....
THERIIOCOUPLE NUMBER
1
2
3
4
5
&
7
8
q
10
11
I
I
18
Reference
Te ■perature
0
32
100
200
300
400
'500
&00
700
800
q00
Calibration Perfor■ed By •••••••
I
I
' ' Post Test Calibraiicn-Conlracl•i\-
Pre-Test Calibration-Contract ij-
i
Cc11ents:
REFERENCE CALIBRATOR HH71 CAL-K
Dale .................... 21-Sep-q4
Ther1occuple Difference
Te■peralure J
0 0.000
31 0.203
qq 0.17q
1qq 0. 152
300 0.000
3qq 0.11&
4qq 0.104
&00 . 0.000
700 0.000
800 0.~00
q00 0.000
0.0&q AVERAGE DIFF
MIC~ BERJ<HE>1D
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
rR
I
E.T. S. INC. I
I
I
I
I
MffiR CCNSOLE Clll.lBRATION FORII
I
• I
I
I
I
I
I
~,ter Box No ••••••••••• 18
lliERIIOCOUPLE t,\JMBER 2
Reference
Te1perature
I 0
2 32
3 100
4 200
5 3110
6 400
7 500
8 600
'l 700
10 800
11 900
Calibration Pe,•for1ed By .......
Post Test Calibration-Contract#\-
Pre-Test Calibration-Contract#-
Co11ents:
REFEllENCE Clll.lBRATOR
Date ....................
Ther■ocouple Difference
Te1perature i
0 0.000
31 0.203
98 0.357
200 0.000
300 0.000
3'18 0.233
499 0.104
600 0.000
699 0.086
800 0.000
900 0.000
0.089
MIDI BERKHEAD
HH7 I Clll. -K
21-Sep-94
AVERAGE DIFF
l
E.T. S. INC.
METER CONSOLE CALIBRATION FORM
Meter Box No •• .' •••••.•• 18
' THERIIOCOUPLE NUMBER J
Reference
Te ■perature
0
0 32 -J 10\l
4 200
5 3~0
& 400
7 500
8 &0\l
5 70\l
10 800
11 500
Calibration Perfor■ed By •••••••
' Post Test Calibration-Contract#\-
1
Pre-Test Calibration-Contract 3-
Conents:
,
I
I
REFERENCE C/U.!BRATOR
Date ••••••••••••••••••.•
Ther■ocouple Difference
Te ■perature i
0 0.000
JI 0.203
55 0. 175
200 0.000
JC'3 0.000
355 0.11&
455 0. 104
&00 0.000
7illl 0.000
800 0.000
500 0.000
0.055
MIO< BERKHEAD
HlHI CAL-K
21-Sep-q4
AVE:lllGE DIFF
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
(
I
E.T. S. INC.
I METER CONSOLE CALIBRATION FORN
I Meter Box No ........... 18
THERIIOCOUPLE NUMBER 4
Reference
I Te1perature
0
2 32
3 100
I 4 200
5 300
i, 400
I 7 500
8 &00
q 700
I 10 800
ll q00
I Calibration Perfor■ed By •••••••
I Post Test Calibration-Contract 1\-
1
I
I
I
I
I
I
Pre-Test Calibration-Contract#-
Conents:
REFERENCE CALIBRATOR
Date ....................
Ther1ocouple Difference
Te1perature ~
0 0.000
30' 0.407
qa 0.357
1sq 0.152
300 0.•J00
359 0. ll&
498 0.208
&00 0,000
700 0.000
800 0.000
sqq 0.074
0.m
MICK BERJ<HEAD
HH7l CAL-K
21-Sep-q4
AUERAG£ DIFF
E.T. S. INC.
l'IETER CONSOLE CALIBR/ff!ON FORM
I
Meter Bo, No .... .' ...... 18 REFERENCE CALIBRATOR
THERMCCOUPLE NUME1ER e Date .................... .,
Reference Ther1oco1Jple Difference
Te■perature Te■perature i
1 0 0 0.000
2 32 30 0.407
3 100 9B 0. 3.."7
4 200 199 0.152
5 300 300 0.000
& 400 398 · 0.233
7 500 498 0.208
8 &00 &00 0.000
9 700 699 0.086
10 B00 799 0.079
11 900 900 0.000
( 0.138
Calibration Perforaed By ••••••• MICK BERKHEAO '
Post Test Calibration-Contract i\-
1 Pre-Test Calibration-Contract#-
Conents:
HH71 CAL-K
21-Sep-94
AVERAGE OIFF
-,•.
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
. 1
I
I
I
I
C I
I
I
I
I
I
I
I
I
E, T.S. INC.
MffiR CONSOLE CALIBRATION FOHN
Met er Box No ........... IS
THERMOCOUPLE NUMBER (,
Reference
Te,perature
I 0
2 32
3 100
4 200
5 300
(, 400
7 50'3
8 (,00
q 700
10 800
11 900
Calibration Perfor■ed By ...... ,
Post Test Calibration-Contract#\-
Pre-Test Calibration-C,ntract #-
Conents:
REFERENCE CHLIBRATOR
Date ....................
Ther1ocouple Difference
Te,perature i
0 0.000
30 0,407
97 0 i:''"' . ,.,.
199 0.152
300 0.000
358 0 .,,. ....... .:.i
498 0.208
599 0.094
r,99 0.08(,
798 0.159
899 0.074
0. 177
MIC',( SERl{HEJ'.lD
HH71 CAL-K
21-Sep-94
AVERAGE OIFF
R
E.T. S. INC.
METER CONSOLE CJU.!BRATIIJN FORII
Meter Box No •.••••.••••
' 18 REFERENCE CALIBRATOR
THERMOCOUPLE NUMBER 7 Date •••••••••••••••••••• I Reference Ther1ocouple Difference I I Teoperature T eoperat ure i
0 0 0.0110
2 32 ~ 0.407
3 100 q7 0.53&
4 200 1q9 0.152
5 300 300 0. 0110
& 400 3qq 0. 11&
7 500 498 0.203
8 &00 599 0. 094
q 700 &59 0.08&
10 800 7qq 0.079
11 q011 sqq 0.074
( I I 0. 15q
Calibration Perfor,ed By ••••••• MICK BERKHEJ1D
i
Post Test Calibration-Contract ~\-
Pre-Test Calibration-Contract i-
Conents:
I
HH71 CT.1.-K
21-Sej>""94
AVERAGE DIFF
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
(
I
I
I
I
I
I
I
I
I
EPA METHOD 20
INTERFERENCE RESPONSE TABLE
Date:
Analyzer Type:
Serial Number:
Span Value:
Test Gas Tvoe
co
CO2
SO2
NOx
Total
04/15/93
Oxygen
111917
25 %
Concentration
lnnmdv\
488
9.98
231
232
Analyzer
Cutout
0.009
0.015
-0.022
-0.014
% of Soan
0.0004
0.0006
0.0009
0.0006
0.0024
% of Span= (Analyzer output response/ Instrument span) x 100
The sum of the (% of Span) values should not exceed 2%.
I
(
EPA METHOD 20
INTERFERENCE RESPONSE TABLE
Date:
Analyzer Type:
Serial Number:
Span Value:
Test Gas Tvne
co
02
SO2
NOx
Total
04/19/93
Carbon Dioxide
91-20-15
20 %
Concentration
lnnmdv)
488
21.9
231
232
Analyzer
Outout
0.101
0.203
-0.021
-0.007
% of Scan
0.0051
0.0102
0.0011
0.0004
0.0166
% of Span = (Analyzer output response/ Instrument span) x 100
The sum of the (% of Span) values should not exceed 2%.
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
-------------------Revision 1 03/16/94_
REFERENCE METHOD CALIBRATION DATA
PAGE OF
!I I, hJ,0~: T.V71"'q ID: ANALYZER CALIBRATION
'· I UNITS: "(o SPAN: ~o GAS GAS ANALYZER ERROR
RANGE CYLINDER ID VALUE RESPONSE % SPAN TIME
SOURCE ID: ·tv,,__ I _,,,.._,_ n 4r\-ZERO .Ji<.. 3<.-'t,4-0 0 D.O \ o·. IS
LOCATION: 'SO LOW -l--t...M o +5lo:S-t 'll. o+ lO-Z'6 ~ l.2_ 10 ·-1 q
TECHNICIAN: ~-1--\o,"-J-:,\,,..-;, 5 HIGH /I..L'MODll3'3 l1 -l.o'iS 11.(o~ 0-() to' 17'
DATE (S): 3/w( c,<1-/ I OTHER
SYSTEM BIAS AND DRIFT SYSTEM BIAS SYSTEM DRIFT
ANALYZER SYSTEM ABSOLUTE ERROR SYSTEM ABSOLUTE ERROR
RUN ID RANGE RESPONSE RESPONSE ERROR % SPAN TIME RESPONSE ERROR % SPAN TIME
ZERO
UPSCALE
ZERO
UPSCALE • :
ZERO
UPSCALE
ZERO
UPSCALE
ZERO
UPSCALE
ZERO
UPSCALE
Revision 1 03/16/94
REFERENCE METHOD CALIBRATION DATA
PAGE OF
~ ·t:;·;... ·,: :;;-·T~··;~ lJ: ANALYZER CALIBRATION
-UH:I'!'S: t-----+-SPAN:--&----
SOURCE ID: 'I-\<-Lev-< ,J ~c;,+
---.. ---· ---------------------------------------------. - --. -GAS GAS ANALYZER ERROR
RANGE CYLINDER ID VALUE RESPONSE % SPAN TIME
ZERO j'(3·~~ D \\\\ \ 0 o.v \'Q'.15
LOCATION: so
TECHNICIAN: L. !-\o..,,,r,hyi e<.,
DATE(S) : .J{c.D{q+f I
LOW ALM 045l,,37 9,9q \Cl'· \9 ~"'~" q _q'=f 0.0
HIGH 'P'.L M bb I l:l'1i ·c, .-r-o.O -~'h. "(_c-1 I D'-11
OTHER
SYSTEM BIAS AND DRIFT SYSTEM BIAS SYSTEM DRIFT
ANALYZER SYSTEM ABSOLUTE ERROR : SYSTEM ABSOLUTE ERROR
RUN ID RANGE RESPONSE RESPONSE ERROR % SPAN TIM.i;: RESPONSE ERROR % SPAN TIME
ZERO ' .
!
UPSCALE .. ·
ZERO ;· '.. ::; '
..
UPSCALE •, " ,"
ZERO
UPSCALE
,.
ZERO . " : , . .
UPSCALE . •' :;;_,.!-) :., ·.: ;,1
·.? : "
ZERO '. ... ··" iO .
. · '. ·. . .
UPSCALE . ' ' )y-!.·I _;-: .. .
n'• -~ • • •
ZERO
UPSCALE
--- -
------------
I
Ir l.{.C~j Scott Specialty. Gases, Inc.
17SJ EAST CLUB BOULEVARD, DURHAM. NC Z7i04 (919) manl FAX: (919) 22J.CBll
I
I
I
I
I
--1
'~-, 7'➔• •• -~ :.:£.l
--ic{_._.:( .. -:,,, ---
-=: ,
-· ·:·:1
-I
-1
I
I
I
' '
I
CERTIFICATE OF ANALYSIS: EPA PROTOCOL GAS
Customer
ETS. INC.
Al1n: Bill Hayes
140 I Mwticipa! Road NW
Roanoke. VA 24012
ANALYTICAL INFORMATION
Assay Laboratory
Scott Specialty Gases. Inc.
1750 East Club Boulevard
Durham. NC 27704
Purchase Order 5129
Scott Project# 12--08743
Certified to exceed the minimum specifications of EPA Protocol Procedure #GI, issued S"!'tember, 1993.
Cylinder Number ALM--045637 Certification Date 10--05-94 Eipiration Date 10--05-97
Cylinder Pressure 1915 PSIG Previous Certification None
ANALYZED CYLINDER
Components
Carbon Dioxide
Oxygen
Nitrogen
Do 1l« mo when cyl.mdc:r ~ is icD tbm l50 PSIG.
Certified Concentr:ltion
10.().l ¾
9.97 ¾
•An&t)-tic.a.11mcert&mty is n:telusive ofusmJ bawn c:trorsomccs which at le.st incflldc:s n:fcmrc:c stand.a-d CDtlT'& pn,cmDQ oftbc
REFERENCE STANDARD
Type
··.NTRM # !675
. NTRM# 2658
Expiration Date
09195
10/94
INSTRUMENTATION
Imtrument/ModeUSerial #
Varian /3400/0160
Varian /3400/ l 6804
Cylinder Number
ALM--032766
ALM--017559
Last Date Calibrated
09-14-94
09-14-94
AnahiiCII Uncertaintv•
+/-I¾ litST Directly Traceable
+/-I¾ litST Traceable
Balance
pnxca<L
Concentration
14.01 ¾Ba!anceinNitrogen
9.56 % Balance in Nitrogen
Analyria.1 Principle
Gas Chromatography
Gas Chromatography
ANAL Y2ER READINGS (Z-Z.ro Gas R-Ref•= Ga T-T..i Gas r-<:orrdadon Codllcieutl
Compon~nts
<:at,oqOio,cido
""'-
Fir.it Triad Analysis
Date: JO,O,-.iJ4 Rcspomo Uaitr. An:a
S'TD-63+U9 sPt.-4"4211
SPL""4"4607 SPL-4,'1-U
STD-634211 S'ID-63310&
Om: 10,.0,-94
S1D•I76021
SPL•l12917
SiD•l76I21
Om:
STD-
SPL ..
STD-
~ Units: Atca
SPL•IS-1,12"'
SPL•ltl-Ul
S'l'D-17'11I
SPL•
SPL•
sro-
Second Triad Analysis
o-.
m>-
SPL•
sro-
Om:
S1D•
SPL•
m>-
R.cspoasoUuits:
m-
sPL-
sro-
R.c:spomoGniu.:
SPL-
SPL•
no-
SPL-
SPL•
sro-
Calibration Curi-e
1
Scqtt Specialty:Gases, Inc.
1i'SJ EAST CLUB BOULEVARD, DURHAM, NC :z7704 (919) Z200:03 FAX: (919) 22'.>C8'.ll I
I
CERTIFICATE OF ANALYSIS: EPA PROTOCOL GAS
' Customer
EIS, INC!
Attn: Bill Hayes
1401 Municipal Road NW
Roanoke, 1VA 24012
I
ANALYTICAL INFORMATION
AJ,ay Labontory
Scott Specialty Gases, rnc.
1750 East Club Boulevard
Durham.NC 27704
Purchase Order ~886
Scott Project# 12-07484
·. Certified to exceed the minimum specifications ofEPAProtocol Procedure #GI, issued September, 1993.
I _ Cylinder Number ALM-018284 Certification Date 06-23-94 Expiration Date 06-23-97
· Cylinder fressure 1915 PSIG Previou, Certification None
I
ANALYZED CYLINDER
Componellts
.. , Oxygen 1 · .· . Carbon Dioxide
. _ ..;.-Nitrogen:
Do not me wbcn. c:ylmdc:r~ is less th.a 1,0 PSIG.
Certified Concentration
22.7%
17.68%
Analvtical Unremintv•
+/-1 ¾ NIST Traceable
+/-1 % NIST Directly Tnceable
Balance
:::·.,,: ..
:a-;,.;..;.~.; •ADaiyticaJ miir.c:rtaimy is im:fauvc afmm.l mowQ czrartom:c:1 'Wliicb • lcm ildmb rdi:n::D:o umdard mer .I: precmaa oftbo """"""" ;::~y.=a . ···t:;-.;_ .
::;,"g REFERENCE STANDARD . . _,. .
"'··tt~?"7::.~~'fype · Expiration Date ·; .:·.~_:~:-~--. _ _..-::Cylinder Number ~"""-~GMIS I 12/95 .. ~·>", :i.-K.-OQOZ74 ,,._;::_;iJ;;NTRM # 1675 06/94 '.'.~ ' -,--:.1 AIM-001138
:Ji1r1rir&nmkNTATION _ .
· ~-:'.i,,._ ·· Instrument/Model/Serial # wt Date Calibn!M
ic.11 Varian /3400/16804 06-21-94 '..-<-:S, .Varian/3400/0160 06-17-94 _·:-~· -· .
··,,.:! I
. ·.·1 Components ·=··· , .... , I
Fint Triad Analysis Second Tmd Analysis
--~:?l/~, : , ~
-:..:::-:;-~,;:---: .-.-:..~~:.--:
··::':
.. ,
. --~~-· .. ·. -··
I C...X.Dioxido
I
O.O. IJ6.Z3-94 -u.;,c-
S'ID-962J44 SPL•I044156
SPL•t0::Wl9 SPJ..•1044720
S'ID-96191!1 S'ID-964111
Dase:06-23-94 Ra;paaot.."'mtl: Ala.
5'Il>-1!1320I SPL•'°"4l!I
SPL .. 701261 SPL-106691
S"II)-j!l3144-S'ID-''3123
1-.
sm-
Sl'l.-
sm-
_,
rn>-
Sl'l.-
SID-
-u-m.-
m.-
sm-
-Uamc
SPL-
SPL-
SID-
'·· Concentradon
. · 20.98 o/o Balance in Nitrogen
: 14.02 o/o Balance in Nitrogen
• Analytial Principle
.. Gas Chromatography
Gas Chromatography
-, Calibndon Cun-e
~---------~
1-~·~
°""' sm-
SPL-
sm-
SPL-
SPL-
sm-
-u.;,c _,
sm-
SPL-
SID-
SPL-
SPL-
sm-
I
I
I
I
I
'ii . '
I
I
I