NCD981475932_19950407_FCX Inc. (Washington Plant)_FRBCERCLA RA_Recommended Operating Parameters for Unit-OCR

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~EC~IVED
MAY O 5 1995
ENVIRONMENTAL ENGINEERING CORPORATION SUPERFUND SECT/ON
Date: April 7, 1995 Contract No: 68-S4-4003
Transmittal No: 007 Project Title:
To: Paul R. Peronard M/H Project No:
Emergency Response and
Removal Branch (4WD-ERRB)
USEPA Region IV
Transmittal:
Farmer's Cooperative Exch,rige
R:J\ \;\Je,.,i;l~';._,f ·z ~
20.0802179 1/
X New
Resubmittal
345 Courtland SI. NE
Atlanta, GA 30365
We are transmitting the following listed submittals:
No. of Copies Date Submittal# Description
3 4/7/95 007 Recommended Ooeratina Parameters for Unit
-.
' '
These are transmitted for your review and comment as required.
I certify that the above submitted items have been reviewed in detail
and are correct and in strict conformance with the contract drawings
and specifications except as otherwise noted.
Signed: -
Great Woods Park, 800 South Main Street, Mansfield, MA 02048 [phone] FAX [phone]
Q,,.,.,,.t,yJ,...,(·•
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I. INTRODUCTION
Following the completion of the Demonstration Program of the high vacuum Low Temperature
Thermal Desorption System (L TTDS), McLaren/Hart is presenting herewith the recommended
operating parameters for the L TTDS to treat the pesticide contaminated soils at the FCX site in
Washington, North Carolina. The performance of the L TTDS verifies the effectiveness of the
system to desorb pesticides from the soil as well as the ability of the system to comply with the
contract specifications as outlined in the Statement of Work (SOW).
II. PRE-TREATMENT SAMPLING PROGRAM
Prior to the commencement of the demonstration program, McLaren/Hart transported sixty (60)
soil bags, each containing I. 75 cubic yards of soil, from the warehouse to the work area and
separated them into three (3) 35 cubic yard lots comprised of twenty bags of soil per lot. One
composite soil sample was obtained from each of the three lots, representing soil from all' twenty
bags within the lots. The three (3) samples were shipped to the laboratory and analyzed for total
pesticides in accordance with EPA Method 8080. Additionally, three composite samples
representing all 60 bags were obtained and analyzed for dioxins and furans, semi-volatile organic
compounds and total RCRA metals in accordance with EPA Method 8280, EPA Method 8270
and SW-846-3051/6010A, respectively.
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Ill. DEMONSTRATION PROTOCOL
McLaren/Hart began the demonstration of the LTTDS on March 16, 1995. Initially, it was
anticipated that the four treatment chambers would run simultaneously throughout the
demonstration program. However, as discussed with the EPA, McLaren/Hart chose to isolate
one chamber per vacuum pump and blower because of the resulting increased airflow.
McLaren/Hart's subcontractor, ETSI, performed the necessary stack sampling on March 17,
•1995. In accordance with the approved Demonstration and Sampling and Analysis Plan, ETS
ran a total of three sample trains. The Volatile Organic Compound Train, EPA Method 0030,
was completed on ETS's first visit to the FCX site in December, 1994. The two remaining
trains, Method 23 (Dioxins and Furans, Pesticides, and Semi-Volatiles) and Method 0050 (HCI
and Particulates) were obtained during two separate runs on March 17, 1995. During each run,
both vacuum pumps were operating with one chamber per pump and four inches of soil in each
tray.
Pursuant to the conversation at the FCX site between the EPA and McLaren/Hart on March 16,
1995, McLaren/Hart agreed that the post-treatment dioxin and furan soil sample should be
obtained from the same treatment run during which the emissions were monitored for dioxins and
furans. Therefore, upon completing the treatment cycle and the Method 23 Sample Train, a
composite soil sample of the four soil trays which were treated throughout the dioxin and furan
stack sampling was obtained and sent to the laboratory to be analyzed for dioxins and furans in
accordance with EPA Method 8280.
Throughout the demonstration program, the pre-treatment and the post treatment soils remained
segregated in three corresponding lots, totaling 35 cubic yards per lot. One composite sample
from each of the three post-treatment lots were obtained and were analyzed for total pesticides
in accordance with EPA Method 8080 to verify that each lot was in compliance with the clean-up
objective of I ppm total pesticides.
The results of the analysis performed on the first composite post treatment sample obtained from
Lot #I detected a concentration above the clean up objective of I ppm total pesticides, therefore
Lot # I was re-treated. A composite sample was obtained from the re-treated soils and sent to
the laboratory to be analyzed for total pesticides.
Additionally, upon completing the treatment of the 60 bags of soil, two composite samples
representing the 105 cubic yards of treated soil were obtained and were analyzed for semi-volatile
organics and total RCRA metals.
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IV. ANALYTICAL RESULTS
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PRE-TREATMENT SOIL ANALYSIS
A . Pesticides
The results of the analysis performed on pre-treatment soil obtained from Lots I, 2 and
3 indicate total pesticide concentration levels of 3226 ppm, 57 .2 ppm, and 57 .7 ppm total .
pesticides, respectively. The analytical results are attached hereto as Exhibit A.
B. Dioxins/Furans
The results of the analyses performed on pre-treatment soil obtained from a composite
sample representing all sixty soil bags indicate dioxin contamination as 7. 14 ppb of
1,2,3,4,6,7,8-HpCDD and 122 ppb of 1,2,3,4,6,7,8,9-OCDD. Ex.pressed as a 2,3,7,8-
TCDD Toxicity (1989 ITF) Equivalent, the total dioxin contamination is 0.193 ppb.
These analytical results are attached hereto as Exhibit B.
C. Semi-Volatiles/RCRA Metals
Two composite samples representing all sixty bags were obtained and analyzed fur semi-
volatiles and total RCRA metals. The results of these analyses indicate a total semi-
volatile concentration levels of 571.5 ppb and Arsenic, Barium, Chromium, and Lead
concentration levels of 8.5 ppm, 11 ppm, 3.1 ppm, and 4.0 ppm, respectively. The
analytical results are attached hereto as Exhibit C.
POST-TREATMENT SOIL ANALYSIS
A. Pesticides
The results of the analysis performed on post-treatment soil obtained from a composite
sample from Lots I, 2, 3 indicate total pesticide concentration levels of O. 0252 ppm,
0.0292 ppm, and 0. 187 ppm, respectively, verifying the effectiveness of the LTTD
system to desorb pesticides from soils and the ability of the system to meet the clean up
· objective of I ppm total pesticides. The analytical results are attached hereto as Exhibit
D.
The analytical result for Lot #1 referenced above is the concentration of the sample
obtained from the re-treated soils. The results of the analysis performed on the initial
composite post treatment sample from Lot # I indicated a total pesticide concentration of
4.1 ppm. McLaren/Hart questioned the validity of this result, specifically due to the fact
that I 000 ppb of Methoxychlor was detected, however there was no detection of the
compound in the pre-treatment analysis.
McLaren/Hart requested that the laboratory re-run the original sample to determine the
accuracy of these results. Additionally, a second composite soil sample was obtained
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from Lot # I and sent to the laboratory to be analyzed for total pesticides to verify the
resulL~ of the first sample. McLaren/Hart hegan re-treating Lot # I while awaiting the
analytical results.
The analytical data from the second run of the first sample confirmed that an error had
occurred during the original analysis, resulting in a faulty detection of Methoxychlor.
The total pesticide concentration of this sample was detected to be I. 93 ppm, which is
significantly lower than the laboratory's first analysis. The results of the analysis
performed on the second sample from Lot # I detected a total pesticide concentration of
0.845 ppm, which is in compliance with the treatment objective of I ppm total pesticides.
The majority of Lot #1 had been re-treated hy the time the analytical results were
received therefore McLaren/Hart proceed re-treating Lot#! until it was complete. As
stated above, the results of analysis obtain_ed from the re-treated batch detected a total
pesticide concentration of 0.0252 ppm.
B. Dioxins/Furan
The results of the analysis performed on post-treatment soil obtained from a composite
sample representing the soil which was treated during the stack sampling indicates dioxin
contamination of 0.36 ppb of 1,2,3,4,6, 7,8-HpCDD and 4.88 ppb of 1,2,3,4,6,7,8,9-
OCDD. Expressed as a 2,3,7,8-TCDD Toxicity (1989 ITF) Equivalent, the total dioxin
contamination is 0.0085 ppb. The post-treatment dioxin and furan analytical results show
lower concentration levels than the pre-treatment analytical, verifying that dioxins and
furans were not created throughout the treatment process. The analytical results are
attached hereto as Exhibit E.
C. Semi-Volatile/Total RCRA Metals
The results of the semi-volatile analysis and the total RCRA metal analysis are not yet
available. The analytical results will be submitted as an amendment to this document at
a later date.
D. Stack SamplinK
· ETS is preparing a summary detailing the analytical results of the three sample trains
obtained during the stack sampling which will be submitted as an attachment to the
document at a later date. Presently, McLaren/Hart has received the preliminary results
of the volatile organic compound analysis and the analysis of the dioxin and furan
em1ssmns. Expressed as a 2,3,7,8-TCDD Toxicity Equivalent, a total dioxin
concentration of l.18E-OI ng/Nm' and an emissions mass rate of l.4E-I I lb/hr were
detected in the dioxin/furan analysis. The available stack sampling results are attached
hereto as Exhibit F.
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V. RECOMMENDED OPERATING PARAMETERS
Throughout the Demonstration Program, the thermocouples on the exhaust manifolds of the
treatment chambers were frequently monitored to track the progress of each treatment batch.
Upon reaching a manifold temperature of 320 to 350 degrees Fahrenheit, the treatment batch was
considered complete and the chamber was shut down. The two soil trays were removed and the
temperature throughout the soil was monitored with thermocouples to ensure a minimum
temperature of 350 degrees.
The post treatment soil analytical results from the Demonstration Program verify that at a soil
treatment temperature of 350 degrees Fahrenheit, under vacuum conditions, pesticides are
effectively desorbed from the soils. In consideration of the foregoing, McLaren/Hart intends to
continue treating to a minimum soil temperature of 350 degrees Fahrenheit throughout the full-
scale treatment process. A definite time duration will not be indicated since the treatment goal
is a temperature, instead the process will be monitored using the thermocouples on the exhaust
manifold.
The soil trays will be loaded into the treatment chambers and the temperature will be increased
from ambient conditions to a temperature of -320 to 350 degrees Fahrenheit on the exhaust
manifold, at which point the treatment hatch will be deemed complete. The chamber will be shut
down and the trays will be unloaded. Prior to dumping the treated soil, the temperature
throughout the soil will be checked to ensure a minimum temperature of 350 degrees. In the
event that the minimum treatment temperature of 350 degrees is not obtained, the tray will be
re-loaded into the treatment chamber and the treatment will continue until the soil has reached
a temperature of 350 degrees or higher.
After completing each batch, the treated soil will be stockpiled in the treated soil pile within the
exclusion zone. As stated in the SOW, the treated soils will be sampled and analyzed for total
pesticides in accordance with EPA Method 8080 in either daily lots or 500 ton allotments. Upon
receipt of the analytical results verifying that the soil meets the clean up objective of I ppm total
pesticides, the treated soil will be transported outside the exclusion zone to the clean soils staging
area. In the event that the soil analytical results indicate a level of total pesticides greater than
one ppm the soil will be re-treated and re-analyzed, ensuring that the soil meets the treatment
objective as outlined in the SOW, prior to leaving the exclusion zone.
Presently, McLaren/Hart is making additional improvements to the IRHV-200 LTTD system to
enhance the treatment duration and the productivity of the system. The soil trays will be
modified with an agitation system which will transfer the soils in the tray, exposing all of the
material to the infrared energy during the treatment process. The implementation of this system
will allow greater depths of soil to be treated during each treatment batch as well as significantly
reduce the treatment times. Additionally, McLaren/Hart is experimenting with different blowers
to determine the most effective way to recirculate and intensify the airflow through the system.
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EXHIBIT A
I PRE-TREATMENT SOIL ANALYSIS
Pesticides
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KIBER ENVIRONMENTAL SERVICES, INC.
ANALYTICAL CASE NARRATIVE
McLaren Hart -FCX
1121-412030
Three soil samples were received for analysis on December 9, 1994 at 1140 hours. The
Environmental Protection Agency (EPA) sampling procedures require soil samples to be
preserved at 4"C ± 2"C. The samples arrived at 4. 7"C.
The requested analysis and corresponding methods were as follows:
Analysis Method
Pesticides SW-846 Methods: 3550
and 8080
Polychlorinated biphenyls
Analysis
There were no analytical difficulties noted during the analysis.
Quality Control
The quality control results were within the method specified limits except for the
following:
I.
2.
The surrogate recoveries were unable to be determined for all sample analyses
due to the dilution necessary for analysis.
The matrix spike and matrix spike duplicate recoveries were unable to be
determined due to the dilution necessary for analysis. The matrix spike and
matrix spike duplicate reports are not included since no information is available
concerning the recoveries.
The quality control analyses included an extraction blank and an extraction blank
spike.
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i -
11
KIBER ENVIRONMENTAL SERVICES. INC.
PESTICIDE RESULTS
SW-846-3550/8080
CUent Name: McLaren Hart
Project Name/#: fC)(/1121
Date Sampled: 12/08/94
Date Received: 12/09/94
Matrll: Soil
Client Sample#: Pre Lot I -128Pl
CAS Number II Compowtd Name
319-84-6 alpha-BHC
58-89-9 gamma-BHC(Lindane)
76-44-8 Heptachlor
959-98-8 Endosulfan 1
60-57-1 Dieldrin
72-20-8 Enclrin
72-54-8 4,4'-DDD
50-29-3 4,4'-DDT
72-43-5 Methoxvchlor
319-85-7 beta-BHC
. 319-86-8 delta-BHC
309-00-2 Aldrin
1024-57-3 Heptachlor epoxide
72,55.9 4,4'-DDE
33123-65-9 Endosulfan II
7421-36-3 Enclrin aldehyde
1031-0.7-8 Endosulfan sulfate
53494-70-5 Enclrin ketone
5103-71-9 alpha-Chlordane
5103-74-2 gamma-Chlordane
8001-35-2 Toxaohene
Note:
I Dilution
factor
5000
5000
5000
5000
5000
5000
5000
5000
5000
5000
5000
5000
5000
5000
5000
5000
5000
5000
5000
5000
5000
E = Concentration exceeds calibration range (results estimated)
J = Estimated value (less than PQL but greater than MDL)
I
Lab Sample ID:
Date Extracted:
•;. Solids:
lnitlal Wt/Vol:
Final Vol:
Cleanuo/#:
Analy>b II Dal<
12/09/94
12/09/94
12/09/94
12/09/94
12/09/94
12/09/94
12/09/94
12/09/94
12/09/94
12/09/94
12/09/94
12/09/94
12/09/94
12/09/94
12/09/94
12/09/94
12/09/94
12/09/94
12/09/94
12/09/94
12/09/94
B = Analyte found in blank (possible/probable blank contamination)
412030-1
12/09/94
93.7
30.25 g
10.00 ml
NA
Result IC::JEJ ug~
BQL 18000
BQL 18000
BQL 18000
BQL 18000
BQL 35000
BQL 35000
56000 35000 E
BQL 35000
BQL 180000
BQL 18000
BQL 18000
BQL 18000
BQL 18000
BQL 18000
BQL 35000
BQL 35000
BQL 35000
BQL 35000
BQL 18000
BQL 35000
3170000 1760000
BQL = Below Quantitation Limit
PQL = Practical Quantitation Limit
NA= Not Applicable
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KTRER ENVIRONMENTAL SERVICES. INC.
Client Name: McLaren Hart
Project Name/#: FOUi 121
Date Sampled:12/08/94
Date Received: 12/09/94
Matrll: Soil
Client Samole #: Pre Lot l -128P l
TCLP PESTICIDE RESULTS
SW-846-3550/8080
Lab Sample ID:
Date Extracted:
¾ Solids:
Initial Wt/Vol:
Final Vol:
Cleanuo/#:
412030-1
12/09/94
93.7
30.25 g
10.00 ml
NA
II ~~b II !!, II Ll~TS II R.:~•••ry I Note I
l~=====1"'etr=a=c'"hl;=o,=o=-m=-=xy==1c=n=e=====~l~I 1'='21=0'='91=94~11~ ===3==s~2s""1=~l:=I ==60==.c=1 scco;===ilii ==o=~II IT]
Surrocate Compound
• = Surrogate(s) out of QC Limits (see case narrative)
D = Diluted out
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KIBER ENVIRONMENTAL SERVICES, INC,
PESTICIDE RESULTS
S\V-846-3550/8080
CUent Name: McLaren Hart
Project Name/#: FOUi 121
Date Sampled: 12/08/94
Date Received: 12/09/94
Matrix: Soil
Client Sample#: Pre Lot 2 -128P2
CASNumber II Compound Name
319-84-6 alpha-BHC
58-89-9 gamma-BHC(Lindanc)
76-44-8 Heotachlor
959-98-8 Endosulfan I
60-57-1 Dieldrin
72-20-8 Endrin
72-54-8 4,4'-DDD
50-29-3 4,4'-DDT
72-43-5 Methoxvchlor
319-85-7 beta-BHC
3 I 9-86-8 delta-BHC
309-00-2 Aldrin
1024-57-3 Heptachlor epoxide
72-55-9 4,4'-DDE
33123-65-9 Endosulfan II
7421-36-3 Endrin aldehvde
1031-07-8 Endosulfan sulfate
53494-70-5 Endrin ketone
5103-71-9 alpha-Chlordane
5103-74-2 gamma-Chlordane
8001-35-2 Toxaphene
Note:
I Dilution
Factor
1000
1000
1000
I 000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
E = Concentration exceeds calibration range (results estimated)
J = Estimated value (less than PQL but greater than MDL)
I
Lab Sample ID:
Date Extracted:
'1/■ SoUds:
Initial Wt/Vol:
Final Vol:
Cleanup/#:
Anal)'b II Date
12/09/94
12/09/94
12/09/94
12/09/94
12/09/94
12/09/94
12/09/94
12/09/94
12/09/94
12/09/94
12/09/94
12/09/94
12/09/94
12/09/94
12/09/94
12/09/94
12/09/94
12/09/94
12/09/94
12/09/94
12/09/94
B = Analyte found in blank (possible/probable blank contamination)
412030-2
12/09/94
94.2
30.17 g
10.00 ml
NA
Rnult IWEJ 011kt
BQL 3500
BQL 3500
BQL 3500
BQL 3500
16000 7000
9200 7000
28000 7000
18000 7000
BQL 35000
BQL 3500
BQL 3500
4000 3500
BQL 3500
BQL 3500
BQL 7000
BQL 7000
BQL 7000
BQL 7000
BQL 3500
BQL 7000
BOL 350000
BQL = Below Quantitation Limit
PQL = Practical Quantitation Limit
NA = Not Applicable
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KJRER ENYJRQNMENTAL SERYJCES, JNC,
CUent Name: McLaren Hart
Project Name/#: FC)(/1121
Date Sampled: 12/08/94
Date Received: 12/09/94
Matrix: Soil
CUent Samo le#: Pre Lot 2 -128P2
TCLP PESTICIDE RESULTS
SW-846-3550/8080
Lab Sample ID:
Date E1tracted:
'\lo Solid,:
Initial Wt/Vol:
Final Vol:
Cleanuo/#:
412030-2
12/09/94
94.2
30.17 g
l0.00 ml
NA
II ~;,u II !~, II LI~TS II R«:• .. ,y
l!======1==e=lr=ac""w==o=ro=-m=-=xy=cl=en=e======:l~I 1""2'=10'='91'=9=4 ;llf ==10"'3'=7===1::=I ==c6'='0-=1'='so==11 0
Surrocate Compound
• = Surrogate(s) out of QC Linuls (see case narrallve)
D = Diluted out
EJ
ll!Ll
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KIBER ENYJRONMENTAL SERYJCES, INC,
PESTICIDE RESULTS
SW-846-3550/8080
CUeot Name: McLaren Rart
Project Name/#: FOUi 121
Date Sampled: 12/08/94
Date Received: 12/09/94
Matrix: Soil
CUeot Samole #: Pre Lot 3 -l28P3
CASNwnbu II Compound Name
319-84-6 alpha-BHC
58-89-9 gamma-BHC(Lindane)
76-44-8 Henlachlor
959-98-8 Endosulfan I
60-57-1 Dieldrin
72-20-8 Endrin
72-54-8 4,4'-DDD
50-29-3 4,4'-DDT
72-43-5 Methoxvchlor
319-85-7 b_ela-BHC
319-86-8 della-BHC
309-00-2 Aldrin
1024-57-3 Heplachlor epoxide
72-55-9 4,4'-DDE
33123-65-9 Endosulfan II
7421-36-3 Endrin aldehvde
1031-07-8 Endosulfan sulfate
53494-70-5 Endrin ketone
5103-71-9 alpha-Chlordane
5103-74-2 gamma-Chlordane
8001-35-2 Toxaohene
Nole:
I Dilution
Fador
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
E = Concentration exceeds calibration range (results estimated)
J = Estimated value (less than PQL but greater than MDL)
I
Lab Sample ID:
Date Extracted:
% SoUds:
Initial Wt/Vol:
Final Vol:
Cleanup/#:
An.alysb II Dat<
12/09/94
12/09/94
12/09/94
12/09/94
12/09/94
I 2/09/94
12/09/94
12/09/94
12/09/94
12/09/94
12/09/94
12/09/94
12/09/94
12/09/94
12/09/94
12/09/94
12/09/94
12/09/94
12/09/94
12/09/94
12/09/94
B = Analyte found in blank (possible/probable blank contamination)
412030-3
12/09/94
93.8
30.13 g
10.00 ml
NA
Result IWEJ ugfkl:
BQL 3500
BQL 3500
BQL 3500
BQL 3500
9200 7100
8500 7100
27000 7100
13000 7100
BQL 35000
BQL 3500
BQL 3500
BQL 3500
BQL 3500
BQL 3500
BQL 7100
BQL 7100
BQL 7100
BQL 7100
BQL 3500
BQL 7100
BOL 350000
BQL = Below Quantilation Limit
PQL = Practical Quantilation Limit
NA= Not Applicable
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KJBEB ENVTRONMENTAL SERYJCES. INC.
Client Name: McLaren-Hart
Project Name/#: FOUi 121
Date Sampled: 12/08/94
Date Received: 12/09/94
Matrix: Soil
Client Samnle #: Pre Lot 3 • I 28P3
Surroc■te Compound
T etrachloro-m-~lene
TCLP PESTICIDE RESULTS
SW-846-3550/8080
l~I II I 2/09/94 II
Lab Sample ID:
Date Extracted:
'I. Solids:
Initial Wt/Vol:
Final Vol:
Cleanup/#:
SpU..
II Amount
7077 II
• = SUITogate(s) out of QC Lirruts (see case narrative)
D = Diluted out
412030-3
12/09/94
93.8
30.13 g
10.00 ml
NA
QC 'I,
LIMITS I Rttonry
60-150 II 0
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IDLJ
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KIBER ENYIBQNMENTAL SERYJCES. INC,
QUALITY CONTROL PESTICIDE RESULTS
SW-846-3550/8080
Client Name: McLaren Aart
Project Name/#: fC){/1121
Date Sampled: NA
Date Received: NA
Matrix: Soil
Client Sample#: NA
CASNumber II Compound Name I DUutJon
Factor
3 I 9-84-6 aipha-BHC I
58-89-9 gamma-BHC(Lindane) I
76-44-8 Heptachlor I
959-98-8 Endosulfan I I
60-57-I Dieidrin I
72-20-8 Endrin l
72-54-8 4,4'-DDD I
50-29-3 4,4'-DDT I
72-43-5 Methoxvchlor I
3 I 9-85-7 beta-BHC I
319-86-8 delta-l3HC I
309-00-2 Aldrin I
I 024-57-3 Heptachlor epoxide I
72-55-9 4,4'-DDE I
33123-65-9 Endosulfan II I
7421-36-3 Endrin aldehyde I
1031-07-8 Endosulfan sulfate I
53494-70-5 Endrin ketone I
5103-71-9 alpha-Chlordane I
5103-74-2 gamma-Chlordane I
8001-35-2 Toxaohene I
Note:
E = Concentration exceeds calibration range (results estimated)
J = Estimated value (less than PQL but greater than MDL)
Lab Sample ID:
Date Extracted:
¾ Solids:
Initial WUV ol:
Final Vol:
Cleanup/#:
I Anal)'II II Dal<
I 2/09/94
I 2/09/94
12/09/94
12/09/94
12/09/94
12/09/94
12/09/94
I 2/09/94
12/09/94
12/09/94
12/09/94
I 2/09/94
12/09/94
12/09/94
12/09/94
I 2/09/94
12/09/94
12/09/94
12/09/94
12/09/94
12/09/94
8 = Analyte found in blank (possible/probable blank contrunination)
Q4 l 20902EBS
12/09/94
NA
30.00 g
10.00 ml
NA
ResuJt IWEJ ug!!g
BQL 3.3
9.7 3.3
8.7 3.3
BQL 3.3
43 6.7
39 6.7
8.9 6.7
27 6.7
BQL 33
BQL 3.3
BQL 3.3
7.9 3.3
BQL 3.3
BQL 3.3
BQL 6.7
BQL 6.7
BQL 6.7
BQL 6.7 I
BQL 3.3
BQL 6.7
BOL 330
BQL = Below Quantitation Limit
PQL = Practical Quantitation Limit
NA = Not Applicable
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KJBER ENVIRONMENTAL SERVICES. JNC.
QUALITY CONTROL TCLP PESTICIDE RESULTS
SW-846-3550/8080
Client Name: McLaren Hart
Project Name/#: FC)(/1121
Dale Sampled: NA
Date Received: NA
Matrix: Soil
CUent Samole #: NA
Surroeate Compound
Lab Sample ID: Q4120902EBS
Dale Extracted:
¾ Solids:
Initial Wt/Vol:
Final Vol:
Cleanuo/#:
12/09/94
NA
30.00 g
10.00 ml
NA
l~o.r .. •" I spu.. II QC I ¾ EJ•" .~. Amount .. LIMITS II Rtconry
l~=====cco=ec=ac=,cW7o=ro=,cbcsip=ch=en=y,=I ======11211'=2'°'10'=91'=9""4 ~Iii ==6"'. 1=====i1i?'I ==;;6"'0-=cl~SO:==={l=c=I "'11~li-=:J
• = Surrogale(s) out of QC LIIIUts (see case narrative)
. D = Diluted out
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K1IlE8 ENVIRONMENTAL SERVICES, INC,
PESTICIDE RES UL TS
SW-846-3550/8080
Client Name: McLaren Bart
Project Name/#: FCX/1121
Date Sampled: NA
Date Received: NA
Matrix: Soil
Client Sample#: NA
CAS Number II Compound Name
319-84-6 alpha-BHC
58-89-9 gamma-BHC(Lindane)
76-44-8 Heotachlor
959-98-8 Endosulfan I
60-57-1 Dieldrin
72-20-8 Endrin
72-54-8 4,4'-DDD
50-29-3 4,4'-DDT
72-43-5 Methoxvchlor
319-85-7 beta-BHC
3 l 9-86-8 delta-BHC
309-00-2 Aldrin
1024-57-3 Heptachlor epoxide
72-55-9 4,4'-DDE
33123-65-9 Endosulfan II
7421-36-3 Endrin aldehyde
1031-07-8 Endosulfan sulfate
53494-70-5 Endrin ketone
5103-71-9 alpha-Chlordane
5103-74-2 gamma-Chlordane
8001-35-2 Toxaohene
Note:
I Dilution
Factor
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E = Concentration exceeds calibration range (results estimated)
J = Estimated value (less than PQL but greater than MDL)
I
Lab Sample ID:
Date Extracted:
• 'llo Solids:
Initial Wt/Vol:
Final Vol:
Cleanup/#:
Analym II Date
12/09/94
12/09/94
12/09/94
12/09/94
12/09/94
12/09/94
12/09/94
12/09/94
12/09/94
12/09/94
12/09/94
12/09/94
12/09/94
12/09/94
12/09/94
12/09/94
12/09/94
12/09/94
12/09/94
12/09/94
12/09/94
B = Analyte found in blank (possible/probable blank contamination)
Q4120901EB
12/09/94
NA
30.00 g
10.00 ml
NA
Result l~EJ ugfkt.
BQL 3.3
BQL 3.3
BQL 3.3
BQL 3.3
BQL , 6.7
BQL 6.7
BQL 6.7
BQL 6.7
BQL 33
BQL 3.3
BQL 3.3
BQL 3.3
BQL 3.3
BQL 3.3
BQL 6.7
BQL 6.7
BQL 6.7
BQL 6.7
BQL 3.3
BQL 6.7
BOL 330
BQL = Below Quantitation Limit
PQL = Practical Quantitation Limit
NA= Not Applicable
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KIBER ENVIRONMENTAL SERVICES, INC.
CUeot Name: McLaren Hart
Project Name/#: FC)(Jl 121
Date Sampled: NA
Date Received: NA
Matrix: Soil
CUent Samnle #: NA
TCLP PESTICIDE RESULTS
S\V-846-3550/8080
Lab Sample ID:
Date Extracted:
¾ SoUds:
Initial WtNol:
Final Vol:
Cleanuo/#:
Surrocate Compound [~JI SpU.. II Amount
Tetrachloro-m-xylene
Decachlorobiehenvl .. • = Surrogate(s) out of QC Luruts (see case narrative)
D = Diluted out
112/09/94 11 6.7 II 12109194 I 6.7
Q4120901EB
12/09/94
NA
30.00 g
10.00 ml
NA
QC ¼
LIMITS I Recovery EJ
60-150 IEEB 60-150
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KJRER ENVIRONMENTAL SERVICES, INC
Client Name: McLaren Hart
Project Name/#: FCX/1121
Date Sampled: NA
Date Received: NA
Client Sample # NA
Spike
Compound
II
ConctnlnUon
gamma-BHC
Heptnchlor
Aldrin
Dieldrin
Endrin
4 4'-DDT
• = QC outside luruts
D = Diluted out
Addfd
17
17
17
67
67
67
II
Quality Control Results
Blank Spike(BS)
SW-846C3550/8080
Lab Sample ID: Q4120902EBS
MatriI:
Date £1t111cted:
Initial Wt/Vol:
Final Vol:
Clea nun/#:
BLANK SPIKE(BS)
Con;;:uon II Con::;tloo
0 9.7
0 8.7
0 7.9
0 43
0 39
0 27
Soil
12/09/94
30.00 g
10.00 ml
NA
11:D~B Rtc0ve .,-.
58 56-123
52 40-131
47 40-120
65 52-126
59 56-121
41 38-127
KIBER
ENVIRONMENTAL =:: SERVICES, INC.
',
'' IJ • ·~· ·-·•.
/17'" /.c-1 c-r1 / /4:,, )
' nOUNDu= 8'1 }Y.
,,
/j /.,,.,/4(/ l)lJEDA1E: , ,
PHONE#:·· q)q_q;,<,1-1')7.21
,SAMPLE. SAMPLE
NUMBER. DESaumoN
.:, ; .. ~-,i~I loW') 3!>-cu. :~5 ', ',
/~?~: "7>,~ k,+ ..,. .., ''
.··. '15c.,,, ..1,
/.;JO-~
-,.., ' . 1--(e J.,,f 3 35 a.,. ,;J,
,.
' -' .
'
SAMPLED .BY: DATE
0RINI'ED NAME: SAMPLED:
''
N ,._~ NETT~ 02.t..
l'i!GNA~ TIME
~ C. o"' SAMPLED:
a>MPANY:
t-\ cl ~E i., Ji.1 ... ,..
, . . ;_·.-..
SAMPLE CHAIN-OF-CUSTODY RECORD cocl
3786 DEKALB TECHNOLOGY PARKWAY
ATIANTA, GEORGIA 30340
404) 455-3944 FAX <404) 451-0155 . • I """'· • ,hr: , . ANALYTICAL PAR.AMETERS (lodicata 1ana I.Ill)
/ex 112 I -~-
CON1ACT: . """' r i<.OJ =-1 '\~
/teiJ-#'e Oro/; MANAGER: -~ ~\ ~ ,::·
RECEIVING LAB: PO#:
-~ ,, . •'
'., '
SAMPLE GRAB, SAMPLE PRESERI. #/SIZEOF
-~ 1-•-•.
DATil/TIME COMP. MA1RIX VA-rrvl CONTAINERS
: I' ~;/ ,.v,f \-'6°~;,f/ )( 1~µ ''
-
'' ··•·
/.)A ·:·,-.:;· r . ~ ; . .i;i,¾_.01·-j... --.~, •fi::,
, ,_g ,.•
J.Jh. C. '' c; 'i , \-~-1-.· :I.. ' .
. --...... ... '
: . ,, .. ,.
' '
-
. ·.,··
' -.
'
,•
''
·.'.
'
':
SAMPLES DAIBJ . ' SAMPLES DAIBJ COMMENTS:
REUNQUISHED BY: TIME ACCEPTED BY:· TIME
11 I ~ 11/1 . ' --,,,;,;
1 ,
!
-
----------------
·Ul36
Lll7D3C
Remarks
-I
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-1
' '
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. ... -
~ '~~
L vC
,0
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EXHIBIT B
PRE-TREATMENT SOIL ANALYSIS
Dioxins/Furans
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-ANALYTICAL RESULTS
FOR THE
FCX SITE
KJBER PROJECT # 1 121-41203 2
PRESENTED TO
MCLAREN/HART REM ED IA TION SERVICES
Great Woods Park .
800 South Main Street
Mansfield, MA 02048
PRESENTED BY
KIBER ENVIRONMENTAL SERVICES, INC.
3 786 DEKALB TECHNOLOGY PARKWAY
ATLANTA, GEORGIA 30340
[phone]
January 6, 1995
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Case Narrative
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KIBER ENVIRONMENTAL SERVICES, INC.
ANALYTICAL CASE NARRATIVE
McLaren Hart -FCX
1121-412032
One soil sample was received for analysis on December 9, I 994 at 1025 hours. The
Environmental Protection Agency (EPA) sampling procedures require soil samples to be
preserved at 4°C ± 2°C. The sample arrived at 4.7°C.
The requested analysis and corresponding methods were as follows:
Analysis Method
Dioxins, furans SW-846 Methods: 3550
and 8270A
Dioxi11s, Jura11s
Analysis
There were no analytical difficulties noted during the analysis.
Quality Control
The quality control results were within the method specified limits.
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I Dioxin Sample Results
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TL-RTP Project: 30794
Client Sample: 412032-1
Method 8280 PCDD/PCDF Analysis (b)
Analysis File: E941691
Client Project: FCX:1121/KES-McLAREN HART Matrix: SOIL
PCDDIPCDF SUMMARY REPORT
SpecificAnalytes (•·•·• .·. Cone. (ppb) >bL(ppb)> > Blank (ppb) .
2,3.7,8-TCDD ND 0.074
1.2.3. 7 ,8-PcCDD ND 0.129
1,2.3,4, 7,8-HxCDD ND 0.21
1,2.3,6.7,8-HxCDD ND 0.106
1,2.3,7.8,9-HxCDD ND 0.179
1,2.3.4.6,7,8-HpCDD 7.14 0.214
1,2,3,4,6,7,8,9-OCDD 122 0.283
2.3,7,8-TCDF ND 0.0643
1,2.3.7.8-PeCDF ND 0.101
2,3,4,7,8-PcCDF ND 0.105
1,2,3,4, 7,8-HxCDF ND 0.118
1,2.3,6,7,8-HxCDF ND 00922
2,3,4,6. 7 ,8-HxCDF ND 0.171
1,2.3. 7,8,9-HxCDF ND 0.22
1,2,3,4,6,7 ,8-HpCDF ND 0.176
1,2.3.4. 7 ,8,9-HpCDF ND 0.189
1.2,3,4,6, 7 ,8.9-OCDF ND 0.352
Tot.al TCDD ND 0.074
Tot.al PcCDD ND 0.129
Tot.al HxCDD ND 0.1_65
Tot.al HpCDD 19.5 0.214
Tot.al TCDF ND 0.0643
Tot.al PcCDF ND 0.103
Tot.al HxCDF ND 0.15
Tot.al HpCDF 0.269 0.182
Triangle Laboratories of RTP, Inc.
801 Capitola Drive• Durham, North Carolina 27713
Phone• [phone] • Fax• [phone]
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Page l of l
. Definitions:
~ci~c. -ii;eclJ:~iration oft~~.·.··
specific anaiyie iri ihe · .
i.mits shciWri, ·
DL.--Thfci!tlii.;··;i~i)~•th~.
specific analyte· in the·
units shown,
.·• ·. Blank ~Th: concentr~nof the .
method bia.nko. .
· . ND · (Non-Detect) The ... ·•.. . ·. • .
• • conceniraticin of the analyte i
· is iess than the d~teclion .
limit•
U!IO_PSR v:2.0S. I.A.RS~ I J.11b
Printed• 10• 19 01/05/95
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TL-RTP Project: 30794
Client Sample: 412032-1
Method 8280 PCDD/PCDF Analysis (b)
Analysis File: E941691
Client Project:
Sample Matrix:
TLRTP ID:
Sample Size:
Dry Weight:
GC Column:
2.3.7,8-TCDD
1.2.3. 7 ,8-PeCDD
1,2.3.4.7,8-HxCDD
1.2.3,6,7,3-HxCDD
I.2.3.7,8,9-HxCDD
1,2,3,4.6,7,3-HpCDD
I.2.3.4.6. 7 .8.9-OCDD
2.3,7,8-TCDF
1.2.3, 7 ,8-PeCDF
2,3.4. 7 .8-PeCDF
1,2,3.4,7,8-HxCDF
1.2,3,6,7,8-HxCDF
2.3.4.6,7,8-HxCDF
I.2.3, 7 ,8,9-HxCDF
1,2,3.4,6, 7 ,8-HpCDF
! ,2,3,4,7,8,9-HpCDF
1,2.3.4,6, 7 ,8, 9-OCDF
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
FCX:1121/KES-McLAREN HART
SOIL Date Received: 12/10/94
92-238-1 Date Extracted: 12/13/94
Date Analyzed: 12/22/94
10.070 g
9.325 g
DB-5
ND
ND
ND
ND
ND
7.14
122
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
19.5
ND
ND
ND
0.269
Dilution Factor: n/a
E941684
JF
Blank File:
Analyst:
0
0
0
2
0
0
0
0.074
0. 129
0.21
O.l06
0.179
0.0643
0.101
0 105
0.118
0.0922
0.171
0.22
0.176
0.189
0352
0.129
0.165
0.0643
0.103
0 15
Page I or 2
Triangle Laboratories of ATP, Inc.
801 Capitola Drive• Durham, North Carolina 27713
Phone: [phone] • Fax: [phone]
0.677
Spike File:
!CAL:
CONCAL:
% Moisture:
% Lipid:
% Solids:
I /J7
0.89
5?828050
E959204
E941680
7.4
n/a
92.6
36:30
40:02
Printed: 10:19 01/05/95
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TL-RTP Project: 30794
Client Sample: 412032-1
"C,,-2.3.7,8-TCDF
"C,,-2.3. 7 ,8-TCDD
"C,,-1,2,3,6, 7 .8-HxCDD
"C,,-1.2.3,4.6, 7 ,8-HpCDF
"C,,-1,2.3.4.6,7 .8,9-OCDD
"CL.-2,3,7 .8-TCDD
"C,,-1.2.3.4-TCDD
"C,-1.2.3,7 .8.9-HxCDD
Triangle Laboratories of ATP, Inc.
3.08
3.99
4.21
7.87
10.7
l .91
801 Capitola Drive• Durham. North Carolina 27713
Phone: [phone] • Fax: [phone]
Method 8280 PCDD/PCDF Analysis (b)
Analysis File: E941691
57.5 40%-120% 0.77 24:46
74.3 40%-120% 0.79 25:34
78.5 40%-120% 1.25 33:21
73.4 40%-120% 1.05 35:28
99.5 25%-120% 0.91 40:01
71.4 40%-120% 25:34
0.78 25:22
1.29 33:38
01/05/95
nso_PSR ~:2.05, LARS 5.13.17b
Printed: 10:19 01/05/95
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TL-RTP Project: 30794
Client Sample: 412032-1
Client Project:
Sample Matrix:
TI.RTP ID:
Sample Size:
Dry Weight:
GC Column:
2.3,7,8-TCDD
1,2,3.7,8-PeCDD
1,2.3.4,7 .8-llxCDD
1,1.3.6.7,8-HxCDD
l.2.3,7.8,9-1-lxCDD
1.2,3.4,6.7,8-HpCDD
' I.2.3.4.6.7,8.9-0CDD
2.3.7.8-TCDF
1,2.3.7,8-PeCDF
2,3.4,7.8-PeCDF
l.2.3.4.7.8-1-lxCDF
1.2,3.6,7 ,8-HxCDF
2,3.4.6,7,8-HxCDF
1.2.3.7.8,9-HxCDF
1.2.3.4.6.7 ,8-HpCDF
1,2,3.4,7 ,8.9-HpCDF
1,2.3.4,6.7 ,8,9-0CDF
FCX:1121/KES-McLAREN HART
SOIL Date Received: 12/10/94
12/13/94
12/22/94
92-238-1 Date Extracted:
10.070 g
9.325 g
DB-5
Date Analyzed:
Dilution Factor: n/a
E941684
JF
Blank File:
Analyst:
ND X
ND X
ND X
ND X
ND X
7.1 •
122 •
ND .,
ND X
ND X
ND X
ND X
ND X
ND X
ND X
ND X
ND X
l
0.5
0.1
0.1
0.1
O.Ql
0 001
0.1
0.0S
0.5
0.1
0.1
0.1
0.1
0.01
0.01
0.001
=
=
=
=
=
=
=
=
=
=
=
=
=
=
=
=
Toxicity Equivalents Report
Analysis File: £941691
Spike File:
!CAL:
CONCAL:
% Moisture:
% Lipid:
% Solids:
0
0
0
0
0
0.071
0.122
0
0
0
0
0
0
0
0
0
0
.
SP828050
E959204
E941680
7.4
n/a
92.6
Total 2,3,7,B-TCDD Toxiclty-(1989 ITF) Equivalents: 0.193 ppb
Triangle Laboratories of RTP, Inc.
801 Capitola Drive• Durham. North Carolina 27713
Phone: [phone] • Fax: [phone] ·
Page I of l TI:FPR.Pfg vS 01.LARS S.ll17b
Printed: 10:20 01/05/95
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QA/QC Results
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TL-RTP Project: 30794
Client Sample: TLI SOIL BLANK
Client Project: n/a
Method 8280 PCDD/PCDF Analysis (b)
Analysis File: £941684
Matrix: SAND
PCDDIPCDF SUMMARY REPORT
Specdic Analytes .·. • ···:·•. Cohee. (ppb)i • iDL(ppt,):
2.3.7.8-TCDD ND 0.0687
1.2.3.7,8-PeCDD ND 0.119
1,2.3,4.7.8-HxCDD ND 0.195
1,2.3.6. 7 ,8-HxCDD ND 0.0985
1.2.3.7.8.9-HxCDD ND 0.166
1.2.3,4.6,7,8-HpCDD ND 0 199
1.2.3.4,6. 7 .8. 9-OCDD ND 0.263
2.3.7.8-TCDF ND 0.0597
1.2.3.7.8-PeCDF ND IJ 0935
2.3.4,7.8-PeCDF ND 0.0975
1.2.3.4. 7.8-HxCDF ND 0.109
1.2.3,6,7,8-HxCDF ND 0.0856
2.3.4.6.7.8-HxCDF ND 0.158
1.2.3.7.8.9-HxCDF ND 0.204
1,2.3,4,6, 7 .8-HpCDF ND 0.163
1.2.3,4, 7,8,9-HpCDF ND 0.175
1.2.3.4.6,7 ,8,9-OCDF ND 0.326
Total-Analyies. (ppb) ,.·· > DL(ppb)
Total TCDD ND 0.0687
Total PeCDD ND 0.119
Total l!xCDD ND 0 153
Total HpCDD ND 0.199
Total TCDF ND 0.0597
Total PeCDF ND 0.0955
Total HxCDF ND 0.139
Total HpCDF ND 0.169
Triangle Laboratories of ATP, Inc.
801 Capitola Drive• Durham, North Carolina 27713
Phone: [phone] • Fax: [phone]
·. .. . . ...•. . •,: . Blank.(ppb) > ·: Definitions:
ND ·····Cone, -The concentration of the·
ND specific analyte in the
ND unns shown.
ND
ND DL -The detection limit of the
ND specific analyte in the
ND unns shown.
Blank -The concentration of the
ND method blank.·
ND
ND ND. -(Non-Detect) The
ND concentration of the analyte
ND · is less than the detection
ND limn.
ND
ND
ND ..
ND : ·:-:'
.
Page l of l
Printed: 10:24 01/05/95
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TL-RTP Project: 30794
Client Sample: TLI SOIL BLANK
Method 8280 PCDD/PCDF Analysis (b)
Analysis File: £941684
Client Project:
Sample Matrix:
lLRTP ID:
Sample Size:
Dry Weight:
GC Column:
2,3,7,8-TCDD
1,2,3, 7 ,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6.7,8-HxCDD
1,2,3,7,8,9-HxCDD
1.2.3.4,6. 7,8-HpCDD
1,2,3,4,6,7,S,9-OCDD
2,3,7,S-TCDF
1,2,3, 7 ,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6, 7 ,8-HpCDF
1,2,3,4,7 ,8.9-HpCDF
1.2,3,4,6.7 ,8,9-OCDF
Total TCDD
Total PeCDD
Total JlxCDD
Total HpCDD ·
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
n/a
SAND
TLI BLANK
10.050 g
n/a
DB-5
Triangle Laboratories of RTP, Inc,
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor:
Blank File:
Analyst:
I I
12/13/94
12/21/94
n/a
E941684
BO
ND 0.0687
ND 0.119
ND 0.195
ND 0.0985
ND 0.166
ND 0.199
ND 0.263
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0
0
0.0597
0.0935
0.0975
0.109
0.0856
0.158
0.204
0.163
0.175
0.326
0.119
0 . 0.153
0 0.199
0 0.0597
0 0.0955
0 0.139
0 0.169
Pagelof2
801 Capitola Drive• Durham, North Carolina 27713
Phone: {919) 544-5729 • Fax: [phone] ·
0.36
'Spike File:
!CAL:
CONCAL:
% Moisture:
% Lipid:
% Solids:
SP828050
E959204
E941680
n/a
n/a
n/a
S'l!O_PSR ...-2.m. LARS~ IJ.ITh
Printed: 10:24 01 /05/95
') -'-;)
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TL-RTP Project: 30794
Client Sample: TLI SOIL BLANK
"C12-2.3,7 ,8-TCDF
"C12-2.3.7 ,8-TCDD
"C12-l.2.3.6, 7,8-HxCDD
"C, 2-1,2,3,4,6, 7 .8-HpCDF
"C12-1,2.3.4,6.7 ,8,9-OCDD
"CL.-2.3, 7,8-TCDD
"C12-l.2.3.4-TCDD
"C12-1,2.3.7 ,8,9-HxCDD
Triangle Laboratories of ATP, Inc.
1.88
2.37
2.44
4.97
3.98
1.15
801 Capilola Drive • Durham. North Carolina 27713
Phone: [phone] • Fax: [phone]
Method 8280 PCDD/PCDF Analysis (b)
Analysis File: £941684
37.7
47.7
49.0
49.9
40.0
46.0
40%-120%
40%-120%
40%-120%
40%-120%
25%-120%
40%-120%
0.79
0.80
1.27
1.07
0.86
0.77
1.23
01/05/95
24:48 v_
25:35
33:20
35:28
40:00
25:36
25:23
33:38
'280~PSR V'.2 OS, LARS 5.13.17h
Printed: 10:24 01/05195 2G
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TL-_RTP Project: 30794
Client Sample: TLI SOIL BLANK
Client Project:
Sample Matrix:
TLRTP ID:
Sample Size:
Dry. Weight:
GC Column:
2.3,7,8-TCDD
1.2,3.7,8-PeCDD
1.2.3.4,7,8-HxCDD
1,2,3,6. 7,8-HxCDD
1,2.3. 7 .8.9-HxCDD
1,2,3,4,6.7 ,8-1 !pCDD
1,2.3,4,6,7.8.9-OCDD
2.3.7,8-TCDF
1,2,3, 7 ,8-PeCDF
2,3,4,7,8-PeCDF
1.2.3.4.7,8-HxCDF
1.2.3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1.2.3. 7 ,8,9-HxCDF
1.2.3.4.6,7 .8-HpCDF
1.2.3.4, 7 ,8,9-HpCDF
1.2.3.4.6. 7 .8.9-OCDF
n/a
SAND
TLIBLANK
10.050 g
n/a
DB-5
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor:
Blank File:
Analyst:
X l
X 0.5
X 0.1
X 0.1
X 0.1
X O.Ql
I I
12/13/94
12/21/94
n/a
E941684
BD
=
=
=
=
=
=
X 0.001 =
X 0.1 =
X 0.05 =
X 0.5 =
X 0.1 =
X 0.1 =
X 0.1 =
X 0.1 =
X 0.01 =
X 0.01 =
X 0.001 =
Toxicity Equivalents Report
Analysis File: £941684
Spike File:
!CAL:
CONCAL:
% Moisture:
% Lipid:
% Solids:
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
SP828050
E959204
E941680
n/a
n/a
n/a
Total 2,3,7,8-TCDD Toxicity (1989 ITF) Equivalents: 0 ppb
Triangle Laboratories of RTP, Inc.
801 Capitola Drive• Durham, North Carolina 27713
Phone: [phone] • Fax: [phone]
Page l of l TIFl'Rpi-1 ~5.0l. LARS 5.13. I 7b
Printed: 10:25 01/05/95
27
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Chain of Custody
' ,!,
KIBER
ENVIRONMENT AL
SERVICES, INC.
'k
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llJRNAROUND TIME: . .. ,,_. , ·(/
DUE DATE: 7 , • ., ·:,,..✓_-• /r.;·c,1
PHONE#: _. ;, , I '. ~ ,, -. ( ~· ::1
SAMPLE SAMPLE
NUMBER DESCRIPTION
.-·.};, ... s ,/ ,,_._, •,·,, .. .
/--' /· ~::~ >-1 -·-·:.-,·r ):,,.. ~.
/:-->--.:;:.:;....-.. ~7"'7 -....-_.~ . ' ,·.) _:._._ -:--. --
..-:.i. ::-:-i ... .:-' . . . • '~ ,·. ·1 ,-/, -· ,:: .
SAMPLED BY: DATE
PRINTED NAME: SAMPLED:
~i:\i"JJ',' [. T j e:· c;~ ,:..::. \i./.:,f'i '1
\s!GNATI.JRE: TIME
·. ·. , ..... , .. ·lr'--' -, SAMPLED:
k::oMPANY: ;·. d) ti"·!
' l ,,,.-L _:.;1• . ..:f 1·· ,,. l
-

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-
SAMPLE CHAIN-OF-CUSTODY RECORD COC#
3786 DEKALB TECHNOLOOY PARKWAY
A1LANTA, GEORGIA 30340
404) 455-3944 FAX (404\ 451-0155
' I. ,k• ~. ' .1 ": ANAL ITICAL PARAMETERS (indic.a1e urgel list)
.-IIZ I 1 C ) : -
CONTACT: KESPROJECT .( "'
.. ,·
V .. \
MANAGER: •. ., ·,,i:::_ ,.·-C
,\;~-('I,,,:·~/-=-
,_ \.
-:r,
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RECEMNG LAB: PO#: .. , I ., ,,
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:...; ,\, {l ,._, ~:,
SAMPLE GRAB/ SAMPLE PRESER #/SIZE OF . ' y ..
·' ' ; ; '-.\~ Remarks --~ r, DATE/llME COMP. MA1RlX VATIVE COITTAINERS I; . l 11 .-. , I) I
I -C .v/1 X I II?, . ; I ... rr t ( _.,
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-·/}· , .
SAMPLES DATE/ SAMPLES DATE/ COMMENTS:
RELINQUISHED BY: TIME ACCEPTED BY: TIME
'j "/ ., / I . /-I r"'' ·,,. . . ,, /·-c ·; I{ 7( r
\@,
~,1
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EXHIBIT C
PRE-TREATMENT SOIL ANALYSIS
Semi-Volatiles/RCRA Metals
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KIBER ENVIRONMENTAL SERVICES, INC.
ANALYTICAL CASE NARRATIVE
McLaren Hart -FCX
1121-412031
Two soil samples were received for analysis on December 9, 1994 at 1130 hours. The '
Environmental Protection Agency (EPA) sampling procedures require soil samples to be
preserved at 4°C ± 2°C. The samples arrived at 4.7°C.
The requested analyses and corresponding methods were as follows:
Analysis Method
Semi volatiles SW-846 Methods: 3550,
3640. and 8270A '
Total RCRA Metals SW-846 Methods: 3051.
6010A, and 7471
SemiYOlatiles
Analysis
The sample was processed through the gel permeation cleanup due to the nature of the
matrix. There were no further analytical difficulties noted during the analysis.
Quality Control
The quality control included the following analyses and the results were within the
method specified limits: an extraction blank. an extraction blank spike. a matrix
spike, and a matrix spike duplicate. The sample selected for the matrix spike ahd
matrix spike duplicate analyses. may not be representative of the sample submitted for ·
semivolatile analysis of the FCX study.
Total RCRA Metals
Analysis
There were no analytical difficulties noted during the analysis.
Quality Control
The quality control results were within the method specified limits except for the
following:
I. The silver laboratory control standard recovery was below the method specified
limits. Precipitation is suspected for the low silver recovery.
1
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KIBER ENVIRONMENTAL SERVICES, INC.
ANALYTICAL CASE NARRATIVE
McLaren Hart -FCX
1121-412031
Total RCRA Metals continued
Quality Control continued
2. The matrix spike recovery for silver was low. Precipitation and/or a matrix
interference are suspected for the low recovery.
3. The relative percent differences between the sample and replicate results for
selenium and chromium were above the method specified limits. Sample
nonhomogeneity is suspected.
The quality control consisted of the following analyses: a preparation blank, a
laboratory control standard, a replicate, a matrix spike, apd .a serial dilution (excluding
mercury). The sample selected for the mercury replicate and matrix spike analyses
was Pre-sampling -128TRM. The sample selected for the replicate, serial dilution,
and the matrix spike analyses for the remaining RCRA metals may not be
representative of the sample submitted for metals analysis of the FCX study.
2
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KIBER ENVIRONMENTAL SERVICES, INC.
Client Name: McLaren Hart
Project Name/#: FCX/1121
Date Sampled: 12/08/94
Date Received: 12/09/94
Matrix: Soil
Client Samnle # Pre-sarnnlin2 -I 28SV
SEMIVOLATILE RESULTS
SW-846-3550/8270A
Lab Sample ID:
Date Extracted:
% Solid,:
Initial WtNol:
Final Vol:
Cleanuni#:
412031-1
12/12/94
94.4
30.25 g
1.00 ml
NA
CAS l'iumber II Compound Name I Dilution Analy111!1 I Re!luJt IWEJ Factor Date ugikf:
83-32-9 Acenaphthene
208-96-8 Acenaphthylene
· 120-12-7 Anthracenc
56-55-3 Benzo( a)anthracene
205-99-2 Benzo(b )fiuoranthene
207-08-9 l3enzo(k )fiuoranthene
65-85-0 Benzoic acid
191-24-2 Benzo(g,h,i)pcrylene
193-39-5 Benzo(a)pyrene
100-51-6 Benzvl alcohol
111-91-1 bis(2-Chloroethoxy)methane
111-44-4 bis(2-Chlorocthyl)ether
108-60-1 bis(2-Chloroisopropyi)ether
117-81-7 b1s(2-Ethylhexyl)phthalate
101-55-3 4-Bromophenyl-phenylether
85-68-7 l3utylbenzylphthalate
106-47-8 4-Chloroaniline
59-50-7 4-Chloro-3-methylphenol
91-58-7 2-Chloronaphthalene
95-57-8 2-Chlorophenol
7005-72-3 4-Chlorophenyl-phenylether
218-01-9 Chrysene
53-70-3 Dibenz(a,h)anthraccne
132-64-9 Dibenzofuran
84-74-2 Di-n-butylphthalate
95-50-1 1,2-Dichlorobenzene
541-73-1 1,3-Dichlorobenzene
106-46-7 1,4-Dichlorobenzcne
91-94-1 3 ,3' -Dichlorobenzidene
120-83-2 2,4-Dichlorophenol
84-66-2 Diethylphthalate
105-67-9 2,4-Dimcthvlphenol
131-11-3 Dimethvlnhthalate 0
Note:
E = Concentration exceeds calibration range (results estimated)
J = Estimated value (less than PQL but greater than zero)
13 = J\nalyte found in blank (possible/probable blank contamination)
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12/14/94 BQL
12/14/94 l3QL
12/14/94 13QL
12/14/94 13QL
I 2/14/94 13QL
12/14/94 l3QL
I 2/14/94 BQL
12/14/94 13QL
12/14/94 BQL
12/14/94 BQL
12/14/94 13QL
12/14/94 BQL
12/14/94 BQL
12/14/94 430
12/14/94 BQL
12/14/94 9.3
12/14/94 BQL
12/14/94 BQL
12/14/94 BQL
12/14/94 BQL
12/14/94 13QL
12/14/94 BQL
12/14/94 BQL
12/14/94 BQL
12/14/94 14
12/14/94 BQL
12/14/94 BQL
12/14/94 BQL
12/14/94 BQL
I 2/14/94 l3QL
12/14/94 l3QL
12/14/94 13QL
12/14/94 l3OL
BQL = Below Quantitation Limit
PQL = Practical Quantitation Limit
NA= Not Applicable
350
350
350
350
350
350
350
350
350
350
350
350
~ 350
350 13
350
350 J
350
350
350
350
350
350
350
350
350 J -350
350
350
350
350
350
350 f---
350
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KIBER ENVIRONMENTAL SERVICES, INC.
SEMIVOLATILE RESULTS
SW-846-3550/8270A
Client Name: McLaren Hart
Project Name/#: FOUi 121
Date Sampled: 12/08/94
Date Received: 12/09/94
Matrix: Soil
Client Samnle # Prc-samoline -128SV
CAS Number 11 ·
Compound Name
534-52-1 4,6-Dinitro-2-mcthylphcnol
51-28-5 2,4-Dinitrophcnol
121-14-2 2,4-Dinitrotolucnc
606-20-2 2,6-Dinitrotolucnc
117-84-11 Di-n-octylphthalatc
206-44-11 Fluoranthcnc
86-73-7 Fluorene
118-74-1 Hexachlorobcnzcnc
87-68-3 Hexachlorobutadiene
77-47-4 1-lexachlorocyclopcntadiene
67-72-1 Hexachlorocthane
193-39-5 lndeno( I, 2,3-cd)p)TCnc
78-59-1 lsophoronc
91-57-6 2-Methylnaphthalcnc
95-48-7 2-Methvlphenol
106-44-5 4-Methvlphenol
91-20-3 Naphthalene
88-74-4 2-Nitroaniline
99-09-2 3-Nitroaniline
100-01-6 4-Nitroaniline
98-95-3 Nitrobenzcne
88-75-5 2-Nitrophenol
100-02-7 4-Nitrophcnol
86-30-6 N-Nitrosodiphcnylaminc
621-64-7 N-Nitroso-di-n-propylaminc
87-86-5 Pentachlorophenol
85-01-8 Phenantlircne
108-95-2 Phenol
129-00-0 Pyrenc
120-82-1 1,2,4-Trichlorobcnzcnc
95-95-4 2,4,5-Trichlorophenol
88-06-02 2,4,6-T richloronhcnol
Note:
E = Concentration exceeds calibration range (results estimated)
J = Estimated value (less than PQL but greater than zero)
I
13 = i\nalytc found in blank (possible/probable blank contamination)
Dilution
Factor
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Lab Sample ID:
Date Extracted:
% Solids:
Initial WtNol:
Final Vol:
Cleanup/#:
AnaJy!!b
Date
12/14/94
12/14/94
12/14/94
12/14/94
12/14/94
12/14/94
12/14/94
12/14/94
12/14/94
I 2/14/94
12/14/94
12/14/94
12/] 4/94
12/14/94
12/14/94
12/14/94
12/14/94
12/14/94
12/14/94
12/14/94
12/14/94
12/14/94
12/i 4/94
12/14/94
12/14/94
12/14/94
12/14/94
12/14/94
12/14/94
12/14/94
12/14/94
12/14/94
I
412031-1
12/12/94
94.4
30.25 g
1.00 ml
Ni\
Re:mlt
II ug/kg
BQL
BQL
BQL
BQL
BQL
8.2
BQL
110
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
13QL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
13QL
13QL
BQL
BQL
BOL
13QL = Below Quantitation Limit
PQL = Practical Quantitation Lm1it
NA= Not Applicable
PQL 19 ug/K2
350
350 -350
350
350
350 J
350
350 J
350
350
350 ·
350
350
350
350
350
350
350
350
350
350
350
350
350
350
350
350
350 -
350
350
350
350
I KIBER ENVIRONMENTAL SERVIQS,, INC.
I II SEMIVOLATILE RESULTS
~==============~SW~-8~4~6==-3'=5~50=/~82~7~0=A================;I
Client Name: McLaren Hart Lab Sample ID:
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' Project Name/#: FCX/1121 · Date Extracted:
Date Sampled: 12/08/94 % Solid,:
Date Received: 12/09/94 Initial WtNol:
Matrix: Soil Final Vol:
Client Sample# Pre-samoline -

I

28SV Cleanun/#:
Surrogate Compound
2-Fluorophenol
Phenol-d6
Nitrobcnzene-d5
2-Fluorobiphenyl
2,4,6-T ribrornophcnol
Tcrnhcnvl-d14
• = Surrogate(s) out of QC Limits (see case narrative)
D = Diluted out
I ,\naly,I,
I
Spike
II Amount Date
12/14/94 7004
12/14/94 7004
12/14194 3502
12/14/94 3502
12/14/94 7004
12/14/94 3502
412031-1
12/12/94
94.4
30.25 g
1.00 ml
NA
QC
LIMITS I % IE] Reco,·cry
25-121 57
24-113 63
23-120 69
30-115 62
19-122 76
18-137 42
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g
u
!
D
D
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CUent Name: McLaren Hart
Project Name/#: FCX/1121
Date Sampled: NA
Date Received: NA
Matr!I: Soil
Client Samole # NA
KTBER ENVJRQNMENTAL SERVICES. rNC,
QUALITY CONTROL SEMIVOLATILE RESULTS
SW-846-3550/8270A
Lab Sample ID: .
Date Ellracted:
¾ Solids:
Initial Wt/Vol:
Final Vol:
Cleanuo/#:
412031-EB
12/12/94
NA
30.00 g
1.00 ml
NA
CASNumber II Compound Name I[=]! Analy.u II Rault l~EJ Dat, ag!g
83-32-9 Acenaphtheoe
208-96-8 Acenaphthyleoe
120-12-7 Anthracene
. 56-55-3 Benzo( a )anthracene
205-99-2 Benzo(b )fluoranthene
207-08-9 Benzo(k)fluoranthene
65-85-0 Benzoic acid
\ 191-24-2 Benzo(g,h,i)perylene
193-39-5 Benzo(a)nvrene
100-51-6 Benzvl alcohol
111~91-I bis(2-Chloroethoxv)methane
111-44-4 bis(2-Chloroethyl)ether
108-60-1 bis(2-Chloroisopropyl)ether
117-81-7 bis(2-Ethylhexyl)phthalate
101-55-3 4-Bromophenvl-phenvlether
85-68-7 Butylbenzvlphthalate
106-47-8 4-Chloroaniline
59-50-7 4-Chloro-3-methylpheool
91-58-7 2-Chloronaphthaleoe
95-57-8 2-Chlorophenol
7005-72-3 4-Chlorophenvl-phenvlether
218-01-9 Chrvsene
53-70-3 Dihen71 a,h )anthracene
132-64-9 Dibenzofuran I
84-74-2 Di-n-butylphthalate
95-50-1 1,2-Dichlorobenzeoe
541-73-1 1,3-Dichlorobenzeoe
106-46-7 1,4-Dichlorobenzeoe
91-94-1 3 ,3 '-Dichlorobenzidene
120-83-2 2,4-Dichlorophenol
84-66-2 DiethvlPhthalate
105-67-9 2,4-Dimethvlphenol
131-11-3 Dimethvlphthalate
Note:
E = Concentration exceeds calibration range (results estimated)
J = Estimated value (less than PQL but greater than zero)
B = Analyte found in blank (possible/probable blank contamination)
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12/14/94 BQL
12/14/94 BQL
12/14/94 BQL
12/14/94 BQL
12/14/94 BQL
12/14/94 BQL
12/14/94 BQL
12/14/94 BQL
12/14/94 BQL
12/14/94 BQL
12/14/94 BQL
12/14/94 BQL
12/14/94 BQL
12/14/94 32
12/14/94 BQL
12/14/94 BQL
12/14/94 BQL
12/14/94 BQL
12/14/94 BQL
12/14/94 BQL
12/14/94 BQL
12/14/94 BQL
12/14/94 BQL
12/14/94 BQL
12/14/94 BQL
12/14/94 BQL
12/14/94 BQL
12/14/94 BQL
12/14/94 BQL
12/14/94 BQL
12/14/94 BOL
12/14/94 BQL
12/14/94 BOL
BQL = Below Quantitation Limit
PQL = Practical Quantitation Limit
NA = Not Applicable
330
330
330
330
330
330
330
330
330
330
330
330
330
330 J
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
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Client Name: McLaren Hart
Project Name/#: FCX/1121
Date Sampled: NA
KIBER ENYJRQNMENJAL SERYJCES, INC.
QUALITY CONTROL SEMIVOLA TILE RES UL TS
SW-846-3550/8270A
Lab Sample ID:
Date Eitracted:
'¼ Solids:
412031-EB
12/12/94
NA
Date Received: NA lnltial Wt/Vol: 30.00 g
Matrix: Soil
Client Samnle # NA
CASNomber II
Compound Name
534-52-l 4,6-Dinitro-2-meUiylphcnol
51-28~5 2,4-Dinitrophcnol
121-14-2 2,4-Dinitrotoluene
606-20-2 2,6-Dinitrololuene
117-84-0 Di-n-octvlohthalate
206-44-0 Fluoranthene
86-73-7 Fluorene
118-74-l Hexachlorobenzene
87~8-3 Hexachlorobutadiene
77-47-4 Hexachlorocvclooentadiene
67-72-1 Hexachloroethane
193-39-5 lndeno( 1,2,3-cd)pyrene
78-59-1 Isophorone
91-57~ 2-Methylnaphthalene
95-48-7 2-Methvlohenol
106-44-5 4-Methvlohenol
91.20-r Naohthalene
88-74-4 2-Nitroaniline
99-09-2 J-Nitroaniline
100-01~ 4-Nitroaniline
98-95-3 Nitrobenzcne ·
88-75-5 2-Nitroohenol
100-02-7 4-Nitroohcnol
86-30~ N-Nitrosodiphenvlarnine
621~4-7 N-Nitroso-di-n-propylarnine
87-86-5 Pentachloroohenol
85-01-8 Phenanthrene
108-95-2 Phenol
129-00-0 Pvrcne
120-82-l 1,2,4-Trichlorobenzene
95-95-4 2,4,5-Trichlorophenol
88-06-02 2 4.6-Trichloroohenol
Note:
E = Concentration exceeds calibration range (results estimnted)
J = Estimated value (less than PQL but greater than zero)
I Dlludon
Factor
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B = Analyte found in blank (possible/probable blank contamination)
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Final Vol: 1.00 ml
Cleanuo/#: NA
Allaly>i, II R....it
!)at, . .,,..
12/14/94 BQL
12/14/94 BQL
12/14/94 BQL'
12/14/94 BQL
12/14/94 BQL
I 2/14/94 BQL
12/14/94 BQL
12/14/94 BQL
12/14/94 BQL
12/14/94 BQL
12/14/94 BQL
12/14/94 BQL
12/14/94 BQL
12/14/94 BQL
12/14/94 BQL
12/14/94 BQL
12/14/94 BOL
12/14/94 BQL
12/14/94 BQL
12/14/94 BQL
12/14/94 BQL
12/14/94 BQL
12/14/94 BQL
12/14/94 BQL
12/14/94 BQL
12/14/94 BQL
12/14/94 BQL
12/14/94 BQL
12/14/94 BQL
12/14/94 BQL
12/14/94 BQL
12/14/94 BOL
BQL = Below Quanlilation Limit
PQL = Practical Quanlitalion Limit
NA = Nol Applicable
II PQL 19 -~ 330
330
330
330
)30-
330
))0
3)0
330
330
330
330
330
)30
))0
))0
))0
)30
))0
330
330
330
330
330
330
330
330
330
330
330
330
330
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1:
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KIBER ENVIRONMENTAL SERVICES. INC.
II QUALITY CONTROL SEMIVOLATILE RESULTS
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CUeot Name: McLaren Hart
Project Name/#: FCX/1121
Date Sampled: NA
Date Received: NA
Matr!I: Soil
CUent Samole # NA
Sllff01•te Compound
2-Fluorophenol
Phenol-d6
Nitrobenzene-dS
2-Fluorobinhenvl
2,4,6-Tribromoohenol
Terohenvl-d 14 .. • = Surrogate(s) out of QC Luruls (see case narrallve)
D = Diluted out
SW-846-3550/82 70A
Lab Sample ID:
Date E1tracted:
¾ SoUds:
Initial Wt/Vol:
Final Vol:
Cleaoun/#:
l~JI SpU..
II Amount
12/14/94 6667
12/14/94 6667
12/14/94 3333
12/14/94 3333
12/14/94 6667
12/14/94 3333
412031-EB
12/12/94
NA
30.00 g
1.00 ml
NA
QC
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% I Nou I LIMITS Rttonry
25-121 52
24-113 55
23-120 60
30-115 55
19-122 58
18-137 74
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KIBER ENVIRONMENTAL SERYJf=ES,.W.C.
Quality Control Results
Matrix Spike(MS) & Matrix Spike Duplicate(MSD)
SW-846-8270A
Client Name: McLaren Hart
Project Name/#: FCJUI 121
Date Sampled: 12/09/94
Date Received: 12/12/94
Client Sample# NA
~p!l(c
Compound Concenlrallon
Lab Sample ID:
Matrix:
Date Extracted:
Initial WtNol:
Final Vol:
Cleanun/#:
MATRIX SPIKE(MS)
!:>ample
Conuntratlon
412033-1 ..
Soil
12/12/94
30.15 g
1.00 ml
GPC/3640
IH.:\
¾ I Added ua.lk.ci: I Co•:=tlon I Recoverv
Phenol
2-Chlorophenol
1.4-Dichlorobcnzcnc
N-Nitroso-di-n-propylamine
I, 2,4-Trich.lorobenzcnc
4-Chloro-3-mcthylphenol
,\ccnaphthcne
4-Nitrophcnol
2, 4-Dinitrotolucnc
Pcnl.achlorophcnol
Pvrcne
Compound
Phenol
2-Chlorophcnol
I, 4-Dichlorobcnzcnc
N-Nitroso•di•n-propylaminc
1,2,4-Trichlorobcnzcnc
4-Chloro-3-mcthylphcnol
Accnaphlhcnc
4-Nilrophcnol
2,4-Dinitrotolucnc
Pentachloroph.cnol
Pv.cnc
• = QC outside limits
I)= Diluted out
"= Batch QC
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7973 0 3617
7973 0 311711
3986 0 1937
3986 0 2133
3986 0 2061
7973 0 3937
39116 0 -2185
7973 0 4095
39116 0 2308
7973 0 61121
39116 0 2769
MATRIX SPIKE DUPLICATE(MSD)
Initial Wt/Vol:
Final Vol:
:-.plKC MSD
I
MSD
Concenlratlon Conccntrallon ¾
Added ua/l,o RcCO\ltl"Y
7973 4790 ,o
7973 5113 lJ
3986 2570 _ " 3986 2957 62
3986 2702 56
7973 4716 49
3986 2899 61
7973 5818 61
3986 2773 l8
7973 8031 " 3986 3284 69
30.15 g
1.00 ml
I~
9.7
9.3
9.9
14.3
8.7
0.3
9.9
16.7
0.0
2.1
1.3
4l
" 49
l4
" 49
" l1
" 86
69
RPD
2l
2l
2l
2l
2l
2l
2l
2l
2l
2l
2l
Recovery B LimlU
¾
25-90
24-102
27-104
40-126
37-!07
25-103
30-137
10-114
27-89
16-I09
34-142
l)C B Limit.
% RtCOH'l"Y
25-90
24-102
27-104
40-126
37-107
25-103
30-137
10-114
27-89
16-109
34-142
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KJBER ENVIRONMENTAL SERVICES, INC
Client Name: McLaren Hart
Project Name/#: FCJ(II 121
Date Sampled: NA
Date Receind: NA
Client Sample# NA
Spike
Compound I
Conctnlratlon
Phenol
2-Chlorophcnol
1,4-Dichlorobcnzcnc
N-Nitro~o-di-n-propylarnine
1,2,4· Trichlorobcnzcnc
4-Chloro-3-mcthylphenol
Accnaphlhcm:
4-Nitrophenol
2, 4-Dinitrotolucnc
Pentachlorophcnol
-~,
• = QC oulside limits
D = Diluted out
Added
6667
6667
3333
3333
3333
6667
3333
6667
3333
6667
3333
Quality Control Results
Blank Spike(BS)
SW-846-8270A
Lab Sample ID: 412031-EBS
BLANK SPIKE(BS)
Ulan1<
I Conc,ntratlon
u11/l<a
0
0
0
()
()
0
u
0
0
0
0
Matrix:
Date Extracted:
Initial WtNol:
Final Vol:
Cleanun/#:
Co•:;;lion
3214
3437
1718
2139
IS24
3214
1916
3808
1926
"'"
2455
Soil
12/12/94
30.00 g
LOO ml
GPC/3640
u.,
%
I ReCO\l'n'
" l2
l2
64 ,,
" " l7
58
67
74
Kccovcry IE] Limits
%
25-90
24-102
27-104
40-126
37-107
25-103
30-137
10-114
27-89
16-109
34-142
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-,KIBER ENVIRONMENTAL SERVICES, INC.
Client Name: McLaren Hart
Project Name/#: FCX I 1121
Date Sampled: 12/08/94
Date Received: 12/09/94
Matrix: Soil
Client Samnle #: Pre-samoling - I 28TRM
RCRA METALS RESULTS
SW-846-3051/60 I OA
Lab Sample ID:
Date Dige,ted:
% Solids:
Initial Wt:
Final Vol:
412031-2
12/12/94
93.6
0.47 g
50 ml
Target Analyte List I Dilution Analysis Result ~6 Factor Date mg/kg .
Note:
i\rscnic (/\s)
Barium (Ba)
Cadmium (Cd)
Chromium (Cr)
Lead (Pb)
Mercury (Hg)
Selenium (Se)
Silver (/\0 '
E = Concentration exceeds calibration range (results estimated)
J = Estimated value (less than PQL but greater than IDL)
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B = /\nalytc found in blank (possible/probable blank contamination)
12/14/94 8.5
12/14/94 11
12/14/94 BQL
12/14/94 3.1
12/14/94 . 4.0
12/13/94 BQL
12/14/94 BQL
12/14/94 BOL
BQL = Below Quantitation Limit
PQL = Practical Quantitation Limit
N/\ = Not /\pplicable
13 J
23 BJ
2.7
I.I
.14 J
0.52
19
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KIRRR ENVIRONMENTAL SERVICES, INC.
Client Name: McLaren Hart
Project Name/#: FCX I 1121
Date Sampled: Ni\
Date Received: NA
Matrix: Soil
Client Samnle #: NA
RCRA METALS RESULTS
SW-846-3051/601 OA
Lab Sample ID:
Date Dige,ted:
% SOiids:
Initial WtNol:
Final Vol:
PBSl212A
12/12/94
NA
45 ml
50 ml
Target Analyte List I Dilution Analysb Re,ult ~EJ Factor Date mg/kg g
Nole:
i\rsenic (i\s)
Barium (Ba)
Cadmium (Cd)
Chromium (Cr)
Lead (Pb)
Mercury (I lg)
Selenium (Se)
Silver r Au\
E = Concentralion exceeds calibration range (results estimated)
J = Estimated value (less than PQL but greater than IDL)
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13 = i\nalyte found in blank (possible/probable blank contamination)
12/14/94 BQL
12/14/94 0.005
12/14/94 BQL
12/14/94 BQL
12/14/94 BQL
12/13/94 BQL
12/14/94 BQL
12/14/94 BQL
BQL = Below Quantitation Limit
PQL = Practical Quanlilalion Limit
NA= Not i\pplicable
0.12
0.22 J
0.03
0.01
0.14
0.001
0.19
0.01
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-KIBER ENVIRONMENTAL SERVICES, INC.
Quality Control Results
Laboratory Control Sample (LCS)
SW-846-3051/60 I OA
Client Name: McLaren Hart
Batch#: 772
Lab Sample#: LCSS 1212A
Date Digested: 12/12/94
Matrix: Soil
Target Analyte List
Arsenic (As)
Barium (Ba)
Cadmium (Cd)
Chromium (Cr)
Lead (Pb)
Mercurv (Hg)
Selenium (Se)
Silver ( ,\u)
Note:
11
B= Analyte found in blank (possible/probable blank contamination)
• See Case Narrative
% Solids:
Initial Wt:
Final Vol:
Measured
Value
m!!/kg
104
142
106
160
' 180
0.54
112
7,9
Standard ID: Environmental Resource Associates, lnorganics In Soil, lot# 220
100.0
0.48 g
50 ml
Certified
Value
m!!ik!!
112
158
131
187
208
0.50
122
54.0
Acceptable El Range
m !!lk!!
54.7 -166
111 -205 B
65.3-183
110 -26 I
112 -291
0.37 -6.63
62.3 -178
21.6 -79.4 •
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KIRER ENVIRONMENTAL SERVICES. INC,
Client Name: McLaren Hart
Batch#: 772
Date Dige,ted: 12/12/94
Matrix: Soil
Target Analyte List
Arsenic (As)
llarium (lla)
Cadmiwn (Cd)
Chromium (Cr)
Lead (Pb)
Mercury (Ilg)
Selenium (Se)
Silver (Ag)
NA Not Applicable
Note:
•see Case Narrative
. Sample
Concentration
mQ/kQ
28
30
0 00
70
0.00
0.00
25
0.00
Quality Control Results
Replicate Sample ' SW-846-3051/6010A
Replicate
Concentration
mQ/kQ
25
28
U.00
190
0.00
(1.00
36
0.00
• • Mercury replicate was performed on sample 412031-2
Lab Sample#: 412033-IR
%, SolidJ: 83.2
Initial Wt: 0.48 g
Final Vol: 50 ml
Relative Acceptable
Percent RPD LIMIT
Difference( RPDl %
12 25
10 25
NA 25
90 25
NA 25
NA 25
36 25
NA 25
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KIBER ENVIRONMENTAL SERVICES, JNC.
Client Name: McLaren Hart
Batch#: 772
Date Digested: 12/12/94
Matrix: Soil
Spike
Quality Control Results
Matrix Spike(MS)
SW-846-3051/601 OA
Sample MS
Lab Sample #: 4 I 2033-1 MS
% Solids: 83.2
Initial Wt: 0.52 g
Final Vol: SO ml
Percent Percent
Target Analyte List Concentration Concentration Concentration Recovery Recovery
Added
Arsenic (As) 462.28
Barium (Ba) 462.28
Cadmium (Cd) 11.56
Chromium (Cr) 46.23
Lead (Pb) 115.57
Mercury (Hg) 0.50
Selenium (Se) 462.28
Silver (/\o\ I 1.56
Note.
D = Diluted Out
• See Case Narrative
• • Mercury spike was performed on sample 41203 \ .2
Standard ID: Spike-I lot# 6-88AS
m!!/k!! m11/k11 Limits
28 443 90 75 -125
30 456 92 75 -125
ll. 011 10 87 75 -125
70 122 112 75 -125
IJ.IJO 112 97 75 -125
0.00 0.52 104 75 -125
25 465 95 75 -125
0.00 8.4 73 75 -125
E]
••
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EXHIBIT D
POST-TREATMENT SOIL ANALYSIS
Pesticides
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I Lot 1 : Re-Treated Soil Sample
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I -ANALYTICAL RESULTS
I FOR THE
I FCXPROJECT
KIBER PROJECT #1121-503063
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I PRESENTED TO
I McLAREN/HART REMEDIATION SERVICES
411 Grimes Road
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Washington, North Carolina 27889
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I PRESENTED BY
I KIBER ENVIRONMENTAL SERVICES, INC.
3786 DEKALB TECHNOLOGY PARKWAY
I ATLANTA, GEORGIA 30340
[phone]
I /
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I March 3 I, I 99 5
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Case Narrative
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KIBER ENVIRONMENTAL SERVICES, INC.
ANALYTICAL CASE NARRATIVE
McLaren/Hart -FCX
1121 -503063
One soil sample was received for analysis on March 29, 1995 at 1000 hours. The
Environmental Protection Agency (EPA) sampling procedures require soil samples to be
preserved at 4°C ± 2°C. The client was notified the samples arrived at 6.9 °c.
The requested analyses and corresponding methods follow:
Total Pesticides
Analysis
Ahalysis• ·
Total Pesticides SW-846 Methods: 3550 and
8080
There were no analytical difficulties noted during the analyses.
Quality Control
The quality control analyses included the following: an extraction blank, extraction
blank spike, and extraction blank spike duplicate. The quality control results were
within the method specified limits.
Da,le I
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·1
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I Pesticide Sample Results
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KJBEB ENVIRQNMENJAL SERVICES, INC,
PESTICIDE RESULTS
SW-846-3550/8080
Client Name: McLaren-Hart
Project Name/#: FCX/1121
Date Sampled:03/28/95
Date Received:03/29/95
Matrix: Soil
Client Samole #: 328RTI
CASNumber II
319-84-6
58-89-9
76-44-8
959-98-8
60-57-1
72-20-8
72-54-8
50-29-3
72-43-5
319-85-7
319-86-8
309-00-2
1024-57-3
72-55-9 .
33123-65-9
7421-36-3
1031-07-8
53494-70-5
5103-71-9
5103-74-2
8001-35-2
Note:
Compound Name
alpha-BHC
garnma-BHC(Lindane)
H=tachlor
Endosulfan I
Dieldrin
Endrin
4,4'-DDD
4,4'-DDT
Metho~chlor
beta-BHC
delta-BHC
Aldrin
Heptachlor epoxide
4,4'-DDE
Endosulfan II
Endrin aldehvde
Endosulfan sulfate
Endrin ketone
alpha-Chlordane
gamma-Chlordane
Toxaohene
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Dilution
Factor
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1
E = Concentration exceeds calibration range (results estimated)
J = Estimated value (less than PQL but greater than MDL)
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Lab Sample ID:
Date Extracted:
% Solids:
Initial Wt:
Final Vol:
Cleaouo/#:
Analysis II Dale
03/29/95
03/29/95
03/29/95
03/29/95
03/29/95
03/29/95
03/29/95
03/29/95
03/29/95
03/29/95
03/29/95
03/29/95
03/29/95
03/29/95
03/29/95
03/29/95
03/29/95
03/29/95
03/29/95
03/29/95
03/29/95
B = Analyte found in blank (possible/probable blank contamination)
503063-1
03/29/95
NA
32.17 g
10.00 ml
NA
Result IWEJ ue/ke
BQL 3.1
BQL 3.1
BQL 3.1
BQL 3.1
BQL 6.2
BQL 6.2
BQL 6.2
BQL 6.2
BQL 31
BQL 3.1
BQL 3.1
BQL 3.1
BQL 3.1
21 6.2
BQL 6.2 -BQL 6.2 -BQL 6.2 -BQL 6.2
~
4.2 3.1
BQL 3.1
BOL 310
BQL = Below Quantitation Limit
PQL = Practical Quantitation Limit
NA = Not Applicable
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KIBfR ENVIRONMENTAL SERVICES, INC,
PESTICIDE RESULTS
SW-846-3550/8080
Client Name: McLaren-t-lart
Project Name/#: FOUi 121 •
Date Sampled:03/28/95
Date Received:03/29/95
Matrix: Soil
Client Samole #: 328RTI
Surroe:ate Compound
Tetrachloro-m-xy\ene
Decachlorobiehenyl
• = Surrogate(s) out of QC Lmuts (see case narrattve)
D = Diluted out
Ir;:]
1
03/29/95
1 03/29/95
Lab Sample ID:
Date Extracted:
% Solids:
Initial Wt:
Final Vol:
Cleanup/#:
Spllu, II Amount
62.2
11 62.2
503063-1
03/29/95
NA
32.17 g
10.00 ml
NA
QC %
LIMITS I Recovery EJ
60-150 IBE3B 60-150
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QA/QC Results
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KIBER ENVIRONMENTAL SERVICES, INC.
QUALITY CONTROL PESTICIDE RESULTS
SW-846-3550/8080
Client Name: McLaren-Hart
Project Name/#: FCX/1121
Date Sampled: NA
Date Received: NA
Matrix: Soil
Client Sample#: NA
'
CASNumber II Compound Name I Dilution
Factor
3 I 9-84-6 alpha-BHC I
58-89-9 gamma-BHC(Lindane) I
76-44-8 Heptachlor I
959-98-8 Endosulfan I I
60-57-1 Dieldrin 1
72-20-8 Endrin I
72-54-8 4,4'-DDD I
50-29-3 4,4'-DDT I
72-43-5 Methoxvchlor I
319-85-7 beta-BHC I
319-86-8 delta-BHC 1
309-00-2 Aldrin 1
1024-57-3 Heptachlor epoxide I
. 72-55-9 4,4'-DDE 1
33123-65-9 Endosulfan II I
7421-36-3 Endrin aldehyde I
1031-07-8 Endosulfan sulfate I
53494-70-5 Endrin ketone I
5103-71-9 alpha-Chlordane I
5103-74-2 gamma-Chlordane I
8001-35-2 Toxaohene I
Note:
E = Concentration exceeds calibration range (results estimated)
J = Estimated value (less than PQL but greater than MDL)
Lab Sample ID:
Date Extracted:
% Solids:
Initial Wt:
Final Vol:
Cleanup/#:
I Analy,b II Dau
03/29/95
03/29/95
03/29/95
03/29/95
03/29/95
03/29/95
03/29/95
03/29/95
03/29/95
03/29/95
03/29/95
03/29/95
03/29/95
03/29/95
03/29/95
03/29/95
03/29/95
03/29/95
03/29/95
03/29/95
03/29/95
B = Analyte found in blank (possible/probable blank contamination)
Q5032906EB .
03/29/95
NA
30.00 g
10.00 ml
NA
Result IWEJ ug/ke
BQL 3.3
BQL 3.3
BQL 3.3
BQL 3.3
BQL 6.7
BQL 6.7
BQL 6.7
BQL 6.7
BQL 33
BQL 3.3
BQL 3.3
BQL 3.3
BQL 3.3
BQL 6.7
BQL 6.7
BQL 6.7
BQL 6.7
BQL 6.7
BQL 3.3
BQL 3.3
BOL 330
BQL = Below Quantitation Limit
PQL = Practical Quantitation Limit
NA = Not Applicable
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KJBEB ENVIRONMENTAL SERVICES, INC.
QUALITY CONTROL PESTICIDE RESULTS
SW-846-3550/8080
Client Name: McLaren-l-lart Lab Sample ID: Q5032906EB
Project Name/#: FCX/1121
Date Sampled: NA
Date Received: NA
Matrix: Soil
Client Samnle #: NA
Sun"Ocate Compound
Tetrachloro-m-xylene
Decachlorobi[>henyl
• = Surrogate(s) out of QC Lumts (see case narrative)
D = Diluted out
l~I I 03129195
I I 03129195
Date Extracted: 03n9l95
% Solids: NA
Initial Wt: 30.00 g
Final Vol: l0.00 ml
Cleanuo/#: NA
SpU.. II QC
I
% E] Amount LIMITS Rrcovery
6.7 II 60-150 IBBB 6.7 60-150
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KIBEB ENVTBONMENIAJ, SERVICES INC,
Quality Control Results
Blank Spike(BS) & Blank Spike Duplicate(BSD)
SW-846-3550/8080
Client Name: McLaren-Hart Lab Sample ID: Q5032907EBS / Q5032908EBSD
Project Name/#: fC}{!! !21
Date Sampled: NA
Date Received: NA
Client Sample #NA
.
Compound II
gamma-BHC
Heptach!or
Aldrin
Dieldrin
Endrin
4 4'-DDT
Spike
CollCffltratJon
Added
16.667
16.667
16.667
66.667
66.667
66.667
BLANK SPIKE (BS)
II c..;;:••• II
0
0
0
0
0
0
Matrix:
Date Eitncted:
Initial Wt:
Final Vol:
Clea nun/#:
Con::;uon
11.353
11.947
11.888
44.113
55.394
40.764
Soil
03/29/95
30.00 g
10.00 ml
NA
I□ H.econry
Umits
¾
Initial Wt:
Final Vol:
68 46-127
72 35-130
71 34-132
66 31-134
83 42-139
61 23-134
30.00 g
10.00 ml
BLANK SPIKE DUPLICATE (BSD)
Compound
gamma-BHC
Heptachlor
Aldrin
Dieldrin
Endrin
4 4'-DDT
• = QC outside limits
D = Diluted out
II Spike II C••:::••• II ConcentntJon
Addfd
16.667 11.221
16.667 11.957
16.667 11.833
66.667 45.086
66.667 55.640
66.667 43.387 .
BSD I~ V'-
¾ Umlts
Recove!.l RPO · •;• Recoven-
67 1.2 15 46-127
72 0.1 20 35-130
71 . 0.5 22 34-132
68 2.2 18 31-134
83 0.4 21 42-139
65 6.2 27 23-134
B
B
----·-·
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I Chain of Custody
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-------------------KIBER
ENVIRONMENTAL
SERVICES, INC.
..... Nl ..... :
t--,.~(._ l f\~c. N, '"'I,-...,:..~
, URNAROUNU TIME: .::..4--t\'-·-
l)lJE DA TE:::::/;: C\ i 'I 5 .
PHONE#: ''1 1 c, '1 '°I 7 "-i-ii 2. ~
SAMPLE SAMPLE
NUMBER-< DESCRIPTION
-~ . ''" '-,.'{l·· ;. I
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-
SAMPLED BY: DATE
PRINTED NAME, SAMPLED,
.. uz~ I '--"' \-..:.,,"'.._,c·i"'7'C '-,,z 't, Fr,
isIGNATIJREc TIME
.-, . ·, ''., SAMPLED,
lleoMPANYc
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SAMPLE CHAIN-OF-'--LJSTODY RECORD COC#
"~' I : -r C X
CO1~1ACT:
N I\N ._, c,-.r: 0,-, -•-<--
RECEIVING LAB:
SAMPLE GRAB SAMPLE
DATE/11ME COMP. MATRIX
Ea/'-~/~,-:i. '--);:,1.1.. ,·. C. ~-/
•
lllf. )'!:'
SAMPLES
RELINQUISHED BY,
'
~. • 'J. ff°:
KESPROJECT
MANAGER:
PO#:
PRESt::1< #/SIZE OF
VATIVE CONTAINERS
I • " ""'4' I".\ .~" '-'
.--
..
-',W• -..
-! . -. ----.
3786 DEKALB TECHNOLOGY PARKWAY
ATI..ANTA, GEORGIA 30340
404\ 455-3944 FAX (404\ 451-0155
ANALYTICAL PARAMETERS (iDdiute target Ii•)
,,J -:--,,J -,:-;
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0 J <>a < ,-t)
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-. /
. ---
--
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-:ft.
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-----.,
-
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DATE/ SAMPLES DATE/ COMMENTS:
TIME ACCEPTED BYc TIME
'id. ~lrbl ~71 1~ / . ' ' t-(fl ,,.,.., lllu
-"."'' -·-
JI 2 I" ~lV'i,~
Remarks -,
,
.
-----"-(LY)
;·u t "{ V\
I· -
r,)--~ \/
,:;,
I r,
~ ,,~/
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Lot I:
Original Analysis of First Post Treatment Soil Sample
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lti: I Y
--------· -·---------
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KJBEB ENYIBQNMENJ:\L SER\:JCES. INC:,
CUenl N,me: McL!ll'en-Hart
Project Namt/#: FCX/1121
Date Sampled:03122/95
Date Rerelvod:03123/95
Matrh: Soil
Cllen< Sam le#: 322 Pl Post
PESTICIDE RESULTS .. ~~,
SW-1146~3_55_0/S=-"OJl"-'O~~=====~=c==== _I
Lab Sample ID: 503045-1
Date Eitrac1ed: 0)123/95
•fo SoUd,: NA 'i
Initial Wt: 30.34 g
Final Vol: 10.00 ml I .,
Cltaoupl#: HA
CAS !\°W11btr r Compow,d Nun, I Dilution I AMI),~ -11 R,,ult :1 ·.~--rL: .. 7
i: ___J Factor I Dale I u•l1c.( ' u , _ _ __ ·!
f-_:.3:.:1:.9.c•8c.4-=•Q:_.--i:11-~----=alphe-BHC --·7no7 -03124/95 ,-_E.;,Q.;;.L ~ __ .1 99_ -·-' ,'
58-89-9 gamma-BHC(Lindane) i 30 OJ/24195 BQL 1i 9\' I
:--.....::;5::'.69.:.:_~::94g..:~:...s _ _,•1-i --==t::.n~=~c::"'1an::0r:.:1="'----+I ---=;c:~-~~~:;~~ -~--!r ~~ =.I
60-57-1 Dieldrin JO OJ/24/95 330 I 200 '
72-20-8 Endrin 30 ,-· 0QL--I 200 --i .. ....J• ---,-.C..C.-~<----0--'--]124i95 ~·---. __ ,
1---__:7..::2.:.:•5:.:4..:•8:._~1---------,-4·'-'4:..,··D:::D=:':::D------+---=3:::o~..11----:o:::J-::n.'-:4-:':19:::5--II-I --=J907C" _ ____,li~OO___ '
_50-29_-_J __ , _____ 4:.:..4.:..'·..:D:.:D::.. ... .:..' ____ 30 __ -~lJ?~,:95__ BQL " 20J
1 --72.43.5 Methoxvchlor i -30 -03/24,95 _ !_0~. ( ... 9~, __ ,
319-85-7 beta-BHC 11-.:.30.:..........;'f -"'""OJ:..12;;;.4:c./.:c95'---<f--~91::.__, 99 ,
1
_. ':
:~--"l~l::.9•::'.86~-~8:___---1e----.::de:::l:::lll___,·B=.4-'-'C::.... ___ _,f-=......,li 03/24i95 BQL 99____ :,
309-00-2 Aldnn :I ~124;95-140 °9 ·t ': ·--i 30
._...::10:.!2::4:::•5:_:i:::-::.3 _~f..--_:.l-.::l<p=t•:.::ch:::l:.::o:.,r .-P:,• :,::o:.:XJ:.:.d:.::e ___ cf..-....::.c....-;ll_..:O.::J:,::12:.:4::/9.:.5:...__---1,t!=-65 -,·0' __ ;_9_ J _J ~ .•
I _..,....:.7-=-2•..:5~5-,=,9..,....--+-----=-'-4 ·:c.4'...:·D=::D:"EC-::-----+---::-:---il-03/24/95 --~-790!c... _....JII 21)J : _::
33123-65-9 Endo!Ulfan 1! 03124/95 ' 200 f----'
7421-36-3 Endnn aJde. de Ol/24195 · 230 :, 200 . I
30
JO
30
30
30 f-...:.:==.:...-i1----==='-,='=~---1-.::..:...-1f--===-~,---=.:.....---'f----'-·····-· '·--
1031-07-S Endosulfa.,.,tlfote ----~ JO ____ Ql/24i?~_j lJ L WO : :
ll--5..C.3:;.:4;.c94-70-5 Endrin ketone . , 30 , 03124195 1 BQL 200 1r-~1
i,.........::.S:..;10"'3_-7...:1_-9_-le---alpha-Chlordane 00 ~!_2419~ __ :1
1, 750 __ _?~---~F· -1
5103-74-2 cmm,,n.lordane I JO I OJ/24,95 93~ 9', : . 1,_f.-_:_ 8:.:00=1.--'-3-5.-=2-__ ~_f-_----"""'_"'Toc.._,--'~-"-h'-en_e__ JQ__ [_.Qlli:!!.9_1_J: __ .BOL =-·~·-,~2,900 [ •
Noh::
E • Concentration C)(cecds calibration range (rc:sull~ estir.1at:d)
J c Esti:no:ed , alue (le,s than PQL but greater than MDL)
B = Aaalvte fou.od in Ma."lk (possible/proba~le blw evnta.'11li1Etion)
RC,Jl ,,. Belc:i~ f,Juan~itstion Li.:nit
PQI. ,. Practical Qwmtitation Limit
NA= Not Afplicaole
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h' t;,:.:,
K[BER EN\Tiill"ll'llENidl,.!iERyJCES. TNC.
:I CUent Name: l,fcLaren-llar1
i Froje<:t Name/~: FCX/1121
I ~::: :~~!:~:;:~~;::
I
CUent Sample#: 322 P! f'o:Jt
Pt:STi<."IDi(RESU LTS
S\\'-846-3550/808_0==-==
Lah Sample ID:
Date E1troctcr1:
% Solids:
lnltlal W1:
Fin el Vul:
• __________ C=leJ~~-,,;P'c.:#,:.,: ==
·:..:::-.71
i
503045-1
0)/23/95
====·:.:~~;
:-/A
30.34 g
10.0l' ml
-__ N_A
i
r· . Sur,o,,c. Compound -_·· -r~~;;• !--~~~;, -:1 U~(~T~--Ji ~,:~•..,,J_ '"' i
le Tetmhloro-m-xvlene ·•-~=...:.··.93i~4;95 I ·,n· ... ,=7 60-1,9 ___ L O .J D ci
... = Sw-rogale(s) out 'JfQ: ~.irrJts (see Cl!Se n:nra'i\'I.!)
D = Diluted out
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Lot I:
Second Analysis of First Post Treatment Soil Sample
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-ANALYTICAL RESULTS
FOR THE
FCXPROJECT
KIBER PROJECT #1121-503045
PRESENTED TO
McLAREN/HART REMEDIATION SERVICES
411 Grimes Road
Washington, North Carolina 27889
PRESENTED BY
KIBER ENVIRONMENTAL SERVICES, INC.
3 786 DEKALB TECHNOLOGY PARKWAY
ATLANTA, GEORGIA 30340
[phone]
March 30, 1995
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Case Narrative
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KIBER ENVIRONMENTAL SERVICES, INC.
ANALYTICAL CASE NARRATIVE
McLaren/Hart -FCX
1121 -503045
One soil sample was received for analysis on March 23, 1995 at 1005 hours. The
Environmental Protection Agency (EPA) sampling procedures require soil samples to be
preserved at 4°C ± 2°c. The sample arrived at 5.0 °c.
The requested analyses and corresponding methods follow:
Total Pesticides
Analysis
Total Pesticides SW-846 Methods: 3550 and
8080
There were no analytical difficulties noted during the analyses.
Quality Control
The quality control analyses included an extraction blank and extraction blank spike.
The quality control results were within the method specified limits except for the
following:
The surrogate recovery for sample 322 Pl Post was unable to be determined
due to the dilution necessary for analysis.
)
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I Pesticide Sample Results
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II
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KJBER ENVIRONMENTAL SERVICES, INC.
PESTICIDE RES UL TS
SW-846-3550/8080
Client Name: McLarerr-Hart
Project Name/#: FCX/1121
· Date Sampled:03/22/95
Date Received:03/23/95
Matrix: Soil
Client Sample#: 322 PI Post
CASNwnbcr
II
Compound Name
3 I 9-84-6 alpha-BHC
58-89-9 gamma-BHC(Lindane)
76-44-8 Hentachlor
959-98-8 Endosulfan I
60-57-1 Dieldrin
72-20-8 Endrin
72-54-8 4,4'-DDD
50-29-3 4,4'-DDT
72-43-5 Methoxvchlor
319-85-7 beta-BHC
319-86-8 delta-BHC
309-00-2 Aldrin
1024-57-3 Hentachlor epoxide
72-55-9 4,4'-DDE
33123-65-9 Endosulfan JI
7421-36-3 Endrin aldehyde
1031-07-8 Endosulfan sulfate
53494-70-5 Endrin ketone
5103-71-9 alpha-Chlordane
5103-74-2 gamma-Chlordane
8001-35-2 Toxanhene
Note:
I
DUudon
Factor
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
E = Concentration exceeds calibration range (results estimated)
J = Estimated value (less than PQL but greater than MDL)
Lab Sample ID:
Date Extracted:
% Solids:
Initial Wt:
Final Vol:
Cleanun/#:
I Analysis
II Oat,
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
B = Analyte found in blank (possible/probable blank contamination)
•
503045-1
03/23/95
NA
30.34 g
10.00 ml
NA
Result l~EJ ul!ik,
BQL 99
BQL 99
BQL 99
BQL 99
230 200
BQL 200
280 200
BQL 200
BQL 990
BQL 99
BQL 99
120 99
BQL 99
BQL 200
BQL 200
BQL 200 -BQL 200 -BQL 200 -550 99 -750 99
BOL 9900
BQL = Below Quantitation Limit
PQL = Practical Quantitation Limit ·
NA = Not Applicable
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KTRER ENVIRONMENTAL SERVICES. INC,
PESTICIDE RESULTS
SW-846-3550/8080
Client Name: McLareB-Hart
Project Name/#: FOUi 121
Date Sampled:03/22/95
Date Received:03/23/95
Matrix: Soil
Client Samole #: 322 PI Post
SWTOa:ate Compound
Telrachloro-m-~Jene
• = Surrogate(s) out of QC LIIIllts (see case narratove)
D = Diluted out
l[~JI
llo3t28t9s 11
Lab Sample ID:
Date Extracted:
¼ Solids:
Initial Wt:
Final Vol:
Cleanun/#:
SpU..
II Amount
198 II
503045-1
03/23/95
NA
30.34 g
10.00 ml
NA
QC 'I,
LIMITS I Recovery
60-150 II 0
EJ
IDD
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QA/QC Results
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KfiER ENVIRONMENTAL SERVICES, INC,
QUALITY CONTROL PESTICIDE RESULTS
SW-846-3550/8080
Client Name: McLaren-Hart
Project Name/#: FCX/1121
Date Sampled: NA
Date Received: NA
Matrix: Soil
Client Samole #: NA
CASNumber II Compound Name I Dilution
Factor
3 I 9-84-6 alpha-BHC I
58-89-9 gamma-BHC(Lindane) I
76-44-8 Hentachlor I
959-98-8 Endosulfan I I
60-57-1 Dieidrin I
72-20-8 Endrin I
72-54-8 4,4'-DDD 1.
50-29-3 4,4'-DDT I
72-43-5 . Metho~chlor I
319-85-7 beta-BHC I
319-86-8 delta-BHC I
309-00-2 Aldrin I
1024-57-3 Heptachlor epoxide I
72-55-9 4,4'-DDE I
33 I 23-65-9 Endosulfan II I
7421-36-3 Endrin aldehyde I
1031-07-8 Endosulfan sulfate I
53494-70-5 Endrin ketone I
5103-71-9 alpha-Chlordane I
5103-74-2 gamma-Chlordane I
8001-35-2 Toxaohene 1
Note:
E = Concentration exceeds calibration range (results estimated)
J = Estimated value (less than PQL but greater than MDL)
Lab Sample ID:
Date Extracted:
"lo Solids:
Initial Wt:
Final Vol:
Cleanuo/#:
I Analy,ls II Dau
03/23/95
03/23/95
03/23/95
03/23/95
03/23/95
03/23/95
03/23/95
03/23/95
03/23/95
03/23/95
03/23/95
03/23/95
03/23/95
03/23/95
03/23/95
03/23/95
03/23/95
03/23/95
03/23/95
03/23/95
03/23/95
B = Analyte found in blank (possible/probable blank contamination)
Q5032304EB
03/23/95
NA
30.00 g
10.00 ml
NA
Result IWEJ ug/ke
BQL 3.3
BQL 3.3
BQL 3.3
BQL 3.3
BQL 6.7
BQL 6.7
BQL 6.7
BQL 6.7
BQL 33
BQL 3.3
BQL 3.3
BQL 3.3
BQL 3.3
BQL 6.7
BQL 6.7
BQL 6.7
BQL 6.7
BQL 6.7
BQL 3.3 ~
BQL 3.3
SOL 330
BQL = Below Quantitation Limit
PQL = Practical Quantitation Limit
NA= Not Applicable
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KIBER ENVIRONMENTAL SERVICES, INC.
QUALITY CONTRQL PESTICIDE RESULTS
SW-846-3550/8080
Client Naine: McLaren-Wart Lab Sample ID: Q5032304EB
Project Name/#: FCX/1121
Date Sampled: NA
Date Received: NA
Matrix: Soil
Client Samole #: NA
Surrogate Compound
Tetrachloro-m-xyiene
Decachlorobiehenyl
• = Surrogate(s) out of QC Luruts (see case narrative)
D = Diluted out
1§1 I 03/23/95 I
03/23/95
Date Extracted:
¾ Solids:
Initial Wt:
Final Vol:
Cleanup/#:
SpU..
II Amount
6.7 II 6.7
03/23/95
NA
30.00 g
10.00 ml
NA
QC
I
'lo E] LIMITS Recovery
60-150 IBBB 60-150
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KIBER ENVIRONMENTAi, SERYJCES, JNC,
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Client Name: McLaren-Hart
Project Name/#: FCX/1121
Date Sampled: NA
Date RCceived: NA
Client Sample # NA
Compound II
gamma-BHC
Heptachlor
Aldrin
Dieldrin
Endrin
4 4'-DDT
Spike
Coocentntlon
Added
16.667
16.667
16.667
66.667
66.667
66.667
* = QC outside limits
· D = Diluted out
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Quality Control Results
Blank Spike(BS)
SW-846-3550/8080
Lab Sample ID: Q5032305EBS
BLANK SPIKE (BS)
Hlanll.
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Concentntion ,-•·-
o
o
o
o
o
o
Matrix:
Date Extracted:
Initial Wt:
Final Vol:
Cleanuo/#:
Co•:=•••
13.430
13.868
16.104
46.638
60.927
39.700
Soil
03/23/95
30.00 g
10.00 ml
NA
lc:!J
81
83
97
70
91
60
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Recovery B Umlts
%
56-123
40-131
40-120
52-126
56-121
38-127
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· Chain of Custody
KIBER
ENVIRONMENT AL
SERVICES, INC.
' 1 1V\JVU:.:
l-k l ,'i'.i:N +jA..:T
J ' 'AT OUND TIME:
~'1" 'r\e-s
nUEDATE: ~/ ;_· L-i-=, 5
PHONE#:f:l 1~)'114-,ii..z..
SAMPLE SAMPLE
NUMBER DESCRIPTION
:,i;1.~'\ ?cs.
·r"...::·..;;.-:-·, .. -L;-:;T~tC.a...rr
L~ \_ ~-:·e·,,-1c.,i>L.~
SAMPLED BY: DATE
PRINTED NAME: SAMPLED:
' !, ---, .-~'. .. :,,,t:..2..1 ·t ~
isJGNATIJRE: 'i / TIME ', J..:t . .' k ··+c. \ _,...-----SAMPLED:
lc:OMPANY:
r./1_ L..:.., .. -;:__)...1/:-_ ..,__ ,,-r ;-",;CC.,. ;·w;
'
--- --- -·-SAMPLE CHAIN-OF-CUSTODY RECORD COC#
"~' .
,-CY,
CONTACT:
N--.-.1 IJC:T,E O L c_
RECEMNG LAB:
SAMPLE GRAB/ SAMPLE
DATE/llME COMP. MAlRIX
"_:_,/~~f;.1'5 c... ' :--:;.: c,o .. ,
-''
SAMPLES
RELINQUISHED BY:
~. • "':
r.=PROJfa_.1
MANAGER:
PO#:
PRESEJ< #/SIZE OF
VATIVE CONTAINERS
h\A \ -~c,,_
i:
_i:-
-
-. ~-----
-
DATE/
TIME
3786 DEKALB TECHNOLOGY PARKWAY
ATI.ANTA, GEORGIA 30340 404) 455-3944 FAX [phone]
ANALYTICAL PARAM!rIBRS (iDdicau: Wgct lia.) ' " ,;;
,J I
'" ' .~ -~ c9, --~· ,-Q -.,,,-j• 2 k-· '" ~. 1~, ,
. :.-
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"·
-',.;. --
SAMPLES DATE/ COMMENTS:
-ACCEPTED BY: TIME
</4. ·~ ~2~ ·/u r t_J., r),I Ji /6:_l~ l, , ..
I I z I -'Q;_Y'\l/C:::
Remarks
-I
(.' . ,;;.@ ]JC ~ C.
£.0\\ ~s\12
l\'J)
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Lot 1 : Second Post Treatment Soil Sample
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1:
, :
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_ ANALYTICAL RESULTS
FOR THE
FCXPROJECT
KIBER PROJECT #1121-503054
PRESENTED TO
McLAREN/HART RE!\'lEDIATION SERVICES
4 11 Grimes Road
Washington, North Carolina 27889
PRESENTED BY
KIBER ENVIRON1\1ENTAL SERVICES, INC.
3 786 DEKALB TECHNOLOGY PARKWAY
ATLANTA, GEORGIA 30340
[phone]
March 30, I 995
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Case Narrative
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KIBER ENVIRONMENTAL SERVICES, INC.
ANALYTICAL CASE NARRATIVE
McLaren/Hart -FCX
1121 -503054
Two soil samples were received for analysis on March 27, 1995 at 1015 hours. The
Environmental Protection Agency (EPA) sampling procedures require soil samples to be
preserved at 4°C ± 2°C. The client was notified the samples arrived at 20.6 °C.
The requested analyses and corresponding methods follow:
Total Pesticides
Analysis
Analysis
Total Pesticides
Method
SW-846 Methods:
8080
3550 and
There were no analytical difficulties noted during the analyses.
Quality Control
The quality control analyses included the following: an extraction blank, extraction
blank spike, matrix spike, and matrix spike duplicate. The quality control results were
within the method specified limits except for the following:
I.
2.
The surrogates for samples 324 P2 and Post -1 -2nd were unable to be
determined due to the dilution necessary for analysis.
The matrix spike recoveries _were unable to be determined for the matrix spike
and matrix spike duplicate analyses due to the dilution necessary for analysis.
J:\ta Review AuthOrization
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Pesticide Sample Results
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KJBER ENVIRONMENTAL SERVICES, INC,
I
PESTICIDE RESULTS
SW-846-3550/8080
Client Name: McLareil-Hart
Project Name/#: FCX/11'21
Date Sampled:03/24/95
Date Received:03/27/95
Matrix: Soil
Client Samole #: Post -I • 2nd
CASNumbt:r II Compound Name
319-84-6 alpha-BHC
58-89-9 gamma-BHC(Lindane)
76-44-8 Hertachlor
959-98-8 Endosulfan I
60-57-1 · Die!drin
72-20-8 Endrin
72-54-8 4,4'-DDD
50-29-3 4,4'-DDT
72-43-5 MethoYVchlor
319-85-7 beta-BHC
319-86-8 delta-BHC
309-00-2 Aldrin
1024-57-3 H~tachlor epoxide
72-55-9 4,4'-DDE
33123-65-9 Endosulfan II
7421-36-3 Endrin aldehvde
1031-07-8 Endosulfan sulfate
53494-70-5 Endrin ketone
5103-71-9 alpha-Chlordane
5103-74-2 gamma-Chlordane
8001-35-2 Toxanhene
I DUutioo I Factor
10
10
10
10
10
10
10
10
10
10
10
10
10
10
IO
10
10
10
10
10
10
Lab Sample ID:
Date Extracted:
¾ Solids:
. Initial Wt:
Final Vol:
Cleanup/#:
Analysb II Dat.
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
· Note:
E = Concentration exceeds calibration range (results estimated)
J = Estimated value (less than PQL but greater than MDL)
B = Anal)1e found in blank (possible/probable blank contamination)
503054-2
03/27/95
NA
30.68 g
10.00 ml
NA
Result IWEJ u&!!g:
BQL 33
BQL 33
BQL 33
BQL 33
BQL 65
BQL 65
96 65
BQL 65
BQL 330
BQL 33
BQL 33
92 33
17 33 J
510 65
BQL 65
BQL 65
BQL 65
BQL 65
BQL 33
130 33
BOL 3300
BQL = Below Quantitation Limit
PQL = Practical Q~antitation Limit
NA = Not Applicable
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KTRER ENYJRONMENTAL SEBYJCES. INC.
PESTICIDE RESULTS
SW-846-3550/8080
CUeol Name: McLaren-Hart
Project Name/#: FCX/1121
Dale Sampled:03/24/95
Date Received:03/27/95
Matrix: Soil
Client Samnle #: Post -I -2nd
Surrogate Compound
Tetrachloro-m-~lcnc
• = Surrogate(s) out of QC L1I1Uts (see case narrative)
D = Diluted out
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Analysis
I Date
110312319s 11
Lab Sample ID:
Date E1tracted:
¾ Solids:
Initial Wt:
Final Vol:
Clcanun/#:
Splk,
II Amount
65 II
503054-2
03/27/95
NA
30.68 g
10.00 ml
NA
QC ¾
LIMITS I Reconry
60-1 so II 0
EJ
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QA/QC Results
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KIBER ENVIRONMENTAL SERVICES, INC,
QUALITY CONTROL PESTICIDE RESULTS
SW-846-3550/8080
CUent Name: McLaren-Hart
Project Name/#: FCX/1121
Date Sampled: NA
Date Received: NA
Matrix: Soil ·
CUent Samnle #: NA
CASNumber II CompoW1d Name I DUuUon
Factor
3 I 9-84-6 alpha-BHC I
58-89-9 garnma-BHC(Lindane) I
76-44-8 HeptacWor I
959-98-8 Endosulfan I I
60-57-1 Dieldrin I
72-20-8 Endrin I
72-54-8 4,4'-DDD I
50-29-3 4,4'-DDT I
72-43-5 Melhoxvchlor I
319-85-7 beta-Bl·IC I
3 I 9-86-8 della-BHC I
309-00-2 Aldrin I
1024-57-3 Heplacltlor epoxide I
72-55-9 4,4'-DDE I
33123-65-9 Endosulfan II I
7421-36-3 Endrin aldehvde I
1031,07-8 Endosulfan sulfate I
53494-70-5 Endrin ketone I
5103-71-9 alpha-Chlordane I
5103-74-2 garnma-Cltlordane I
8001-35-2 Toxanhene I
Nole:
E = Concen.lralion exceeds calibralion range (rcsulls estimated)
J = Estimated value (less than PQL but greater ti1an MDL)
Lab Sample ID:
Date Extracted:
% Solids:
Initial Wt:
Final Vol:
Cleanup/#:
I AnaJysb II Date
03/28/95
03/28/95.
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
8 = Analyte found in blank (possible/prooable blank contamination)
Q5032701EB
03/27/95
NA
30.00 g
10.00 ml
NA
Ruult IWEJ uglkf:
BQL 3.3
BQL 3.3
BQL 3.3
BQL 3.3
BQL 6.7
BQL 6.7
BQL 6.7
BQL 6.7
BQL 33
BQL 3.3
BQL 3.3
BQL 3.3
BQL 3.3
BQL 6.7
BQL 6.7
BQL 6.7
BQL 6.7
BQL 6.7
BQL 3.3
BQL 3.3
BOL 330
BQL = Below Quanlilation Limit
l'QL = l'roctical Quantitalion Limit
NA = Not Applicable
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KJJlEB ENVIRONMENTAL SERYJCES. INC.
QUALITY CONTROL PESTICIDE RESULTS
SW-846-3550/8080
Client Name: McLaren-Hart Lab Sample ID: Q5032701EB
Project Name/#: FOUi 121
Date Sampled: NA
Date Received: NA
Matrix: Soil
Client Sample#: NA
Surroeate Compound
TetracWoro-m-xyiene
DecacWorobiQhenyl
• = Surrogate(s) out of QC LLn1Jts (see case narrative)
D = Diluted out
II Ano~::~ I
1103/28/95 I
1103/28/95
Date Extracted:
% Solids:
Initial Wt:
Final Vol:
Cleanuo/#:
Spike
II Amount
6.7
II 6.7
03/27/95
NA
30.00 g
10.00 ml
NA
QC
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¼ B LIMITS R~CO'Hry
60-I 50 lffiB 60-150
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KIBER ENVIRONMENTAL SERVICES, INC.
Client Name: McLaren-Hart
Project Name/#: FCJUI 121
Date Sampled: NA
Date Received: NA
Client Sample# NA
·•·-Compound I' ConcrnlnUon
gamma-BHC
Heptachlor
Aldrin
Dieldrin
Endrin
4 4'-DDT
• = QC outside luruts
D = Diluted out
Addrd
17
17
17
67
67
67
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Quality Control Results
Blank Spike(BS)
SW-846-3550/8080
Lab Sample ID: Q5032702EBS
Matrix:
Date E1tracted:
Initial Wt:
Final Vol:
Clea nun/#:
BLANK SPIKE (BS)
UlaJ'\K
I Co•::;uon Concrntn.Uon .. ~.
0 II
0 12
0 12
o 48
o 59
o 49
Soil
03/27/95
30.00 g
10.00 ml
NA
u,
¾
I Recovuy
66
71
72
72
88
73
t<tCOVH')' EJ Llmlu
¾
56-123
40-131
40-120
52-126
56-121
38-127
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I Chain of Custody
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-------------------
KIBER · SAMPLE CHAIN-OF-CUSTODY RECORD COC#
ENVIRONMENTAL
SERVICES, INC.
3786 DEKALB TECHNOLOOY PARKWAY
ATLANTA, GEORGIA 30340
404) 455-3944 FAX /404) 451-0155
I I 1-'P l . !" , IVI r.: .l\J:::,.::, .. :w< ANAL Yl'ICAL PARA.METERS {indica1c 1argel lilt.)
;.-C
~-
l~r'irr'uKN""'.AR:n?O~UND""'~TI'ri>ME:no:-:-::--.-,--+cRoRJNM~1A~CTRi"::-----ruKES"c<'op~Rro~JE~CT"'T'"--JI·~
MANAGER: ,.
DUE DATE: i;::..:c==..:==-----'---~----+=RE=c"'EM~=N=G""LAB,---,sa.-:---tcp""o"""'#":------1I\ ~
1~P_,_H!::O"'NE-""'#'-':-r __ .--'c-·c-,·",--:,,--. -=>:-:'J::--::~• ~"----+--::-c-:-::::-=--r:::::-:-:cr:cc-::-::::-:c+:==:r--~===:-il·., . .-
SAMPLE SAMPLE SAMPLE GRAB/ SAMPLE PRESl:l< #/SIZE OF I.'. {
NUMBER DESCRIPTION DATE/11ME COMP. MATIUX VATI'" CONTAINERS
...... """"'LED BY:
PRINTED NAME:
iCOMPANY:
DATE
SAMPLED:
TIME
SAMPLED:
'
SAMPLES
RELINQUISHED BY:
DATE/
TIME
SAMPLES
ACCEPTED BY:
DATE/ COMMENTS:
TIME
I
I 12/-'S£Jl:5/-/
Remarks
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KJQfB ENVIRONMENTAL SERVICES. INC.
( 'b ft t) -e.~_1 <:..M '0 ~--••ff'll5~ J
PESTICIDE RESULTS '
lf==::c.';'==.===~~7.:'~===~S=W,;,;•;;;8~46~-3;;.5~5~0/~80~8~0~==,a-===~';'======sj Client Namei McLann-Hart Lab Sample ID: SOJOS9-I
Project Namo/11: FCX/1121 Date E1tracted: Ol/28/9S
Date Sampl,d:OJ/27/95 •1, Solid,: NA
Dale Rcceind:03128/95 Initial Wt: 30.06 g
M■trll: Soil Final Volr 10.00 ml
Client Samole #: 327 P2 Post Cleaoun/#: NA
' J
Ii CAH N~_:J[ C\vnpo<md Nam, I ~•;~ 11 .... ~:w II :-;:• ![;2~ Jl:J
l~-]~1~9~•84:_l-¢~-...jlll--__ ___;•~lnh~••~l:llH:::_C..,.... __ _jj_..'..l __ jf __ O'.'.;J'..'.:(l~ll/'..:9:~S-~[1-......!l.:.'.:.8:.___--,-<li-Iqt-4-
1 ; 58-89-9 II oamma-13HC(Lindwie) I I 03/28/9S 1.9 I~ J ..
1
,
76-44-8 1i Hcotachlor I 03/28/95 130L I 3.3 I I
959-91!-8 I· Endosulfan I I OJ/28195 'I BQL I J.J ,,
ll--60::..::.."::.-S 7c.•.;.l _-1 ____ ......c.D.c.ie-'ldr-,-in ____ --,1-_l'-~l--'-OJ:c/2.c.8c..lc..9 S'---l~ BO L 6. 7
72-20-8 i Endrin I 03(18195 5.6 6.7 J
i1-......:7.::2..::-Sc..:.4..:•8c.........Ji-----'4.4·.ooo 1 01128195 1.1 6.7 i 50-29-3 I 4,4'-DDT I OJ/28/9~5·-·H---::B":Q'cL--ll--'6::...7,---if--<I
IL __ 7;.:2:..•4c;l:..•5::__+' ___ _..:.Mc,e:..:looc:>""::><Vc',,hl:'o"-r----,j,---'l--lf-O'-'J'-'(l::.:8:':19:'5:---lf--'B:.:.:QL:__,f--=33 .... t--<
319-85-7 i bcta-BHC I 03/28195 130L 3.3 L-J I J 19-86-8 dclta-HHC I 03(18195 BQL 3.J : I
I 309-00-2 Aldrin I Olr.?819S 4.2 3.J
1024-S7-3 ! H,ntachlor enoxide I 03(18/95 BOL 3.1
,l----'7-=-2•..:5c:.5•..:9 _ __,1 ____ ....c4.c;,4_'·Dc..Dc..cc.E ____ _,1--l-..,1--'0_3r.?-'-8_/_95'---1'1---"'tl~Q=-L---,11_..:6-'-. 7_...Ji---ll
1
;1-..::3.::3.:.:12:.:l:...-6:.:S:..·=..9 -!1-----:,::E:::n:=do:.:s":ul:.cf an=l=-l ----ll--'1--11--0:..:l:':fl::.:8:;,/9:..:5:._-llf ~--'B:..::Qs;L:.__,,
1
_1--=6:c.· '-~1---1!
7421-36-3 I Endrin 1idchydc I 03r.?8/95 BQL 6.7 , ,1--_;._=..::..:;...:;.__ll----'=====----,l--'--li--===-11---==--1•h.-~-~r-~,
ll----'-"10=3~1~-0~7...:-8':---ll----=En~d=o~•tili=,an=su=lf.::•l=•---"r-'l--lf-O::.:J:':fl::.:8:':19:..:5,---ll---'8~Q~L:.__1f-_:_6,~7-'._,; I
53494-70-5 Encbin ketone l 03128195 BQL 6. 7 'J
: 5103-71-9 aloha-Chlordane I 03/28,95--ll---'E'-'Q""t.'--II--J"-.J-·§· -·7
I' ~, 5103-74-2 .. mma-Chlordanc I Olr.?8195 8.6 3.J ll--'-=---,1---......._=---'-----~I--
I 8001-35-2 I To"!'ohc~• I 03/28/95 BQL /I 330 1 __ j
Note:
E • Concentration exceed! ca1ibruton range (resu\B estimated)
J = Estimated ,olue (le"" than PQL but greeter U1an MDL)
B -An1ly1c fow,d in blank (pos,iblclprobablc blonk contaminotion)
,{'.J9
BQL = Below (,luantitotion Limit
PQI. -Practical Quentitatio!l LUl'Ut
NA= Not Applicable
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KWEB ENVIRONMENTAL St;RVICES, INC.
PESTICIDE RESULTS
~W-846-3550/80~0
Cllcnl Name: Mcl..aren-llart Lab Sample ID:
Project N•me/#: FCX/1121 -Date E1trac1ed1
Dal& Sampled:03n719S •;. Solidu
Date Recek•ed:03n8/9S lnltlal Wt:
Malrli: Soil Final Vol:
Cllenl S•mple #: 327 P2 Post Cleanupl#1
Sunopl• Compound
Decachlorobiphenyl ll0Jns195 II
• ~ SUITogate(s) oul of QC Limils (see case narrative)
D • Diluted 001
6.1 11 -
503059-1
03/28195
NA
JO 06 g
1000 ml
QC
UMIT8
I'! ..
~ !
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J
60-1 so 11 so lc:J
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-· •LJ 0l1 ·I·-·-·-
KIBEB ENYJBQNMFNTAI, SEBYJ(ES INC,
L QUALilY CONTROL PESTICIDE RESULTS I SW-84~~3550/8080 , \ Client Name: McLaren-Hart Lab Sample ID: Q50l2804EB I I Proje<I N1me/#1 FCX/1111 Date E,tracltd: Ol/28/95 · I Dale Sampled, NA 'V, SoUds: NA
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Dale a ... 1,ed, NA Initial Wt: 30.00 g I llru: Soil final Yoh 10.00 ml
'Ele=#=:=N=A==================C='l=ea=n~ua!::IN=•====cd,N=A"'======jc!ii
CA! Number JC c ... po..,d N-I OUaHon
Factor
)19-84-6 alpha-BHC I
58-89-9 gamma-BHC(l.indanc) I
76-44-8 Hentachlor I
959-98-8 Endosulfon I I
60-57-1 Dicldrin I
72-20-8 Endrin I
72-54-8 4,4'-DDD I
50-29-3 4,4'-DDT I
72.43.5 MctJi=chlor I
319-85-7 bcta-BHC I
319-86-8 dclla-BHC, I
309-00-2 AJdrin ~ I
1024-57-3 l_lcptachlor enoxide I
72-55-9 4,4'-DDE I
33123-65-9 Endosulfan lJ I
7421-36:~----J Endrin aldehyde i I -1031-07-8 Endo,ulfan sulfalc I I I 53494-70-5 I Endrin ketone I
5103-71-9 I alphe-Chlordane I
5!03-74-2 gamma-Chlordane I
8001-35-2 Toxenhene I
Note:
E • Conccntralion c"-cceds calibralion range (resulLS estimated)
J • Esti:nstrd value (less than PQL but g,caJ..-than MDL)
[
-
B • Analyte found in blank (po,sible/probable blank conlarnin!liool
Analyela II 0.lo
UJW!/'J5 I
Ol/28/95
03/28/95
03/28/95
Ol/28/95
Ol/28/95
03/28195
OJ/28/95
Oli28/95
Ol/28195
Olt'.28195
03128/95 .. -03/28/95
03/28/95
OJn8195
03/28/95
OJ/28/95
OJ/28/95
03/28/95
03/26/b
01/28/95
Resull .II :~Jl:J' u1'"-a
BQL J.J
BQL I l.J
BQL J.3
BQL J.J
BQL 6.7
BQL 6.7
BQL 6.7
llQL 6.7
lll
,__
BOL ' BOL 3.J ' I
BQL 3.3 ·>---BQL . I 3.3
I~
~ 3.J
6,7 .
B-,L 6.7
BQL 6,7
BQL 6.7 ~ BQL 6.7 8 BQL 3.J
BQL 3.3
fJQL I 330
BQL • Below Quanlilation Luni1
PQL ,.. Practical Qua.,titation Li.mjt
NA• Not Applicable
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KWEB ENVTRQNMENTAL SERYICt5, (NC,
QUALIIT CONTROL PESTICmE RESULTS
SW-846-3550/8080
Oleat N■me: t.klami-Hart Lab Sample ID: QS032804EB
Project Namt/#1 FCX/1121 Date E1tractcd: 0J/28/95
Date Sampled: NA ~. Solidi: NA
Date Ruelved: NA lnltlal Wt: 30.00 g
Matrb: Soil Final Voh I0.00 ml
Client Samnle #: NA Clunupi#: NA J
~ S.nor"' Compo .. d II An~~ II ~r:_, II Ll~TS =11 R,:.,., IEl
'1:======aar""ctr=•=;chJPfo=,=o-=m=-xy=;=lcn=e======:t"'oJ;';/2:C,8/;':;9;;5=\:lr==67'i'7==-i==rri ==;60':;'_"';J';'SOF~ll~B, 1--==-----::D:-'cc:coc.:.:,:,hl:.:orc:.o.,cb,..i '"hc"-n--':'-1 ------,l="'OJ:':/::':28:':/9:cS:-,r---'6:°::: 7 60-150 71 U
• • Sw,vg,IIU:'(tt) 01..l uf QC Lirn..iu:1 (~ cll!le nw-nutvc)
D ~ Diluted oul
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, .. , -, . ' ., ...... , , .. 1 ,., ... ,
KIBt;H El'iYIBPNMENTAJ. SERYJ[ES, INC,
-===-=·===== \~-
I! .••
I Client Name: Mclaren-Hast
Projtid N•me/#: FCX.'l 121
D1t. Sampled: NA
Dale Received: t-:'A
Cllent Sample # NA
Quality Control Resul!•.
lllank Spike(BS)
SW-846-J55D/8080
' t..h Sampl• ID: QSOJ2BOSEBS
Murh.: Soil
Date E-.lracted; 03n819S
IDltlol Wt: J0.00 g
flnal Vol: 10.00 ml
]
========~--==--=~□~••::•:::u~p;,;;i#;;,: = _ _,;~==-======'
I r=: ~.unm.o-B!iC I Henw:nlor
Aldrir. -,: Dicl<lrin
i:
Endrin
◄ 4'-DDT
• "' QC cul.Side lir.uts
D •Dilu~ out
i1
11 L
. ..
BLANK SPIKE (BS)
Addrd II -~ __ I
16.667 11 0 E 16.667 0
16 667 0 I -'>6.667 0 I'
1!
66.657 0
66,667 .Q
:i1•k1
118~9~ 1 :.63}
ll.ll4
49.ll45 I .. .3 56.688
4-:'.)76 --·-·-
71 56-123 Ji -· 75 40-1 JI
74 40.I 20
74 ---1 ~---I
ll-il6 :
85 I S6-\ll I · I 71 I if>..121 ·-/J
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KlBE.R ENYJRQNMENTAL SEBYICES INC
_ _ __ _ __ Quality Control Result,
Matru Sp,ke(M:S) & MatrlI Spike Duplicate(MSD)
SW-8~6-131 IITCLP\/35 IOA/8080
Clical Name: McLa.ren-Hart
Project Name/#: FCX/1121
Date Sampled:O.l/'2?/9l
Lab Sumple ID:
Date Elfracted:
0/. Solld1:
Initial We:
503059-1
O.l/'28/9l
NA
30.40 B
----=:JJ
--~\
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Dat, _R«eh-ed:U3n8/9i
M1tru: Soil Flu!Vol: 10.00 ml i
I Client Sample#: 327 P2 Post
II
Spllui
C1Mnpcwnd CO!KHll"IU.a
Addtd
g&rnm.0-8 l!C 16.-147
HcnlBchlor 16.447
AJdnn 16.447
Dicl.:irin 65.789
Emir" 6l.789
4 4'-DDT 6l. 789
Cleaaup/t:
MATRIX SPIKE (MS)
I!
!,mp• ~ US
Conc:"'tnllo: Co11t'lntnUon ·~ •""1!1
I. 916 9.726
r, 11.06-1
4. l l5 14.573
0 4l.354
7.145 l 1.643
0 l8.693
MATRIX SPIKE DUPLICATE (MSD)
NA I
IL:!J~B Rn:ovc %
loltlal Wt:
Fhul Vol:
47 46-127
61 35-IJO
63 34-132
69 l l-134
68 42-139
89 23-134
30.21 g
10.00 ml
I
I -~-I MSO
II
MSD ~ I' . ~ .., 11~: C1Mnpound Con<ntr.Uoo Conc1ntrallon "· •1~_j L~du L'.'.:J Add1d u1!!Y R..,n ... !Z RPn . RPD l "-~
pmma-BHC
llcp<.achlor
Aldrin
Dicldrin
Endrin
4 4'-DDT
• : QC outsKle timi1,
D =-Diluted out
I'
16.5l I
16.551
!6_551
66.203
66.203
66.203
10. 196 50
11.306 68
13.717 58
45.224 68
56.432 I 74
I 59.482 90 .
l.2 r-T3 46-127
l.l 20 35-130 I
9.2 I 22 34-132
0.9 18 31-134 ·-
9.6 -21 42-139 ---I
0.1 l7 ll-134 I I
+ ·• ·-·
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ANALYTICAL RESULTS
FOR THE
FCX PROJECT
KIBER PROJECT# I 121-503054
PRESENTED TO
McLAREN/HART RE!'VIEDIATION SERVICES
41 I Grimes Road
Washington, North Carolina 27889
PRESENTED BY
KIBER ENVIRON!\1ENTAL SERVICES, INC.
3786 DEKALB TECHNOLOGY PARKWAY
ATLANTA, GEORGIA 30340
( 404) 455-3944
March 30, 1995
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I Case Narrative
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KIBER ENVIRONMENTAL SERVICES, INC.
ANALYTICAL CASE NARRATIVE
McLaren/Hart -FCX
1121 -503054
Two soil samples were received for analysis on March 27, 1995 at 1015 hours. The
Environmental Protection Agency (EPA) sampling procedures require soil samples to be
preserved at 4°C ± 2°C. The client was notified the samples arrived at 20.6 °C.
The requested analyses and corresponding methods follow:
Total Pesticides
Analysis
Analysis
Total Pesticides
Method
SW-846 Methods:
8080
3550 and
There v.;ere no analytical difficulties noted during the analyses.
Quality Control
The quality control analyses included the following: an extraction blank, extraction
blank spike, matrix spike, and matrix spike duplicate. The quality control results were
within the method specified limits except for the following:
I. The surrogates for samples 324 P2 and Post -1 -2nd were unable to be
determined due to the dilution necessary for analysis.
2. The matrix spike recoveries-were unable to be determined for the matrix spike
and matrix spikc'duplicate analyses due to the dilution necessary for analysis.
', :'\ lL-1
, ~,ha Review AUlhOrization D:ite '.
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Pesticide Sample Results
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KJBEB ENVIRONMENTAL SERYJCES, INC.
PESTICIDE RESULTS
SW-846-3550/8080
Client Name: McLaren-Hart
Project Name/#: FOUi 121
Dale Sampled:03/24/95
Dale Received:03/27/95
Matrix: Soil
Client Samo le#: 324 P2
CAS Number II
3 I 9-84-6
58-89-9
76-44-8
959-98-8
60-57-1
72-20-8
72-54-8
50-29-3
72-43-5
3 I 9-85-7
3 I 9-86-8
309-00-2
I 024-57-3
72-55-9
33123-65-9
7421-36-3
1031-07-8
53494-70-5
5103-71-9
5103-74-2
8001-35-2
Note:
Compound Name
alpha-BHC
gamma-BHC(Lindane)
Heptachlor
Endosulfan I
Dieldrin
Endrin
4,4'-DDD
4,4'-DDT
Methoxvchlor
beta-BHC
delta-BHC
Aldrin
Heptachlor epoxide
4,4'-DDE
Endosulfan II
Endrin aldehyde
Endosulfan sulfate
Endrin ketone
alpha-Chlordane
gamma-Chlordane
Toxanhcne
I DUutlon
Factor
IO
IO
IO
10
10
10
10
10
10
10
10
10
IO
IO
10
10
10
10
10
10
10
E = Concentn,Jtion exceeds calibration rru1gc (results estimated)
J = Estimated value (less than PQL but greater U1an MDL)
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Lab Sample ID:
Date Extracted:
0/o Solids:
Initial Wt:
Final Vol:
Cleanuo/#:
Analy,ls
Dau
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
B = Anal)1e found in blank (possible/probable blank contamination)
II
503054-1
03/27/95
NA
30.84 g
10.00 ml
NA
R~ult IWB ug~
BQL 32
BQL 32
BQL 32
BQL 32
BQL 65
BQL 65
BQL 65
BQL 65
BQL 320
BQL 32
BQL 32
28 32 J
29 32 J
BQL 65
BQL 65
BQL 65
BQL 65
BQL 65
BQL 32
130 32
BOL 3200
l3QL = 13clow Quantitation Limit
PQL. = Practical Quantitation Limit
NA = Not Applicable
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KJRER ENVIRONMENTAL SERVICES, INC.
PESTICIDE RESULTS
SW-846-3550/8080
Client Name: McLaren-Hart
Project Name/#: FOUi 121
Date Sampled:03/24/95
Date Received:03/27/95
Matrii: Soil ·
Client Samo le#: 324 !'2
Surroe:ate Compound
Tetrachloro-m-~lene
• = Surrogate(s) out of QC Luruts (see case narralive)
D = Diluted out
1§1
1103/28/95 II
Lab Sample ID:
Date Extracted:
¼ Solid,:
Initial Wt:
Final Vol:
Cleanun/#:
Splk,
II Amowit
65 II
503054-1
03/27/95
NA
30.84 g
10.00 ml
NA
QC ¼
LIMITS I Recovery
60-150 II 0
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QA/QC Results
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KIBER ENVIRONMENTAL SERVICES, INC.
QUALITY CONTROL PESTICIDE RES UL TS
SW-846a3550/8080
Client Name: McLaren-Hart
Project Name/#: FOUi 121
Date Sampled: NA
Date Received: NA
MatriJ.: Soil
Client Sample#: NA
CASNumber II Compound Name
319-84-6 alpha-BHC
58-89-9 gamma-BHC(Lindane)
76-44-8 HeolacWor
959-98-8 Endosulfan I
60-57-1 Dieldrin
72-20-8 Endrin
72.54.3 4,4'-DDD
50-29-3 4.4'-DDT
72.43.5 Methoxychlor
319-85-7 beta-Bl-IC
3 ! 9-86-8 delta-Bl-IC
309-00-2 Aldrin
1024-57-3 HeptacWor epoxide
72-55-9 4.4'-DDE
33123-65-9 Endosulfan II
7421-36-3 Endrin aldehyde
1031-07-8 Endosulfan sulfate
53494-70-5 Endrin ketone
5103-71-9 alpha-Chlordane
5103-74-2 gamma-Chlordane
8001-35-2 Toxaohene
Nole:
I DUutfon
Factor
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E = Conccnlration exceeds calibration ra.11gc (results estimated)
J = Estimated value (less than PQL but greater tl1an MDL)
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Lab Sample ID:
Date Extracted:
¼ Solid,:
Initial Wt:
Final Vol:
Cleanup/#:
An.aly!b II Date
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
03/28/95
B = Analyte found in blank (possible/probable blank contamination)
Q5032701EB
03/27/95
NA
30.00 g
I0.00 ml
NA
R~uJt l~EJ ugfkt:
BQL 3.3
BQL 3.3
BQL 3.3
BQL 3.3
BQL 6.7
BQL 6.7
BQL 6.7
BQL 6.7
BQL 33
BQL 3.3
BQL 3.3
BQL 3.3
BQL 3.3
BQL 6.7
BQL 6.7
BQL 6.7
BQL 6.7
BQL 6.7
BQL 3.3
BQL 3.3
BQL 330
BQL = Below Quantitation Limit
PQL = Practical Quantitation Limit
NA= Not Applicable
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KJRER ENVIRONMENTAL SERVICES, INC,
QUALITY CONTROL PESTICIDE RESULTS
SW-846-3550/8080
Client Name: McLaren-Hart
Project Name/#: FOUi 121
Date Sampled: NA
Date Received: NA
Matri.t: Soil
Client Sample#: NA
SWTOcate Compound
Lab Sample lD:
Date Extracted:
% Solhh:
Initial Wt:
Final Vol:
Cleanup/#:
Spike
Q5032701EB
03/27/95
NA
30.00 g
10.00 ml
NA
QC ¼
1
Analy,u
Dale I Amowit II LIMITS I Recovery EJ
Tetrachloro-m-xylene I 03/28/95 1 6.7
II
60-150 IBBB Decachlorobiehenyl 6.7 60-150 03/28/95
• = SWTogate(s) out of QC Luruts (see case narrative)
D = Dilute<! out
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KlllER ENVIRONI\JENTAL SERVICES, INC
Client Name: McLaren-Hart
Project Name/#: FClUI 121
Dale Sampled: NA
Date Received: NA
Client Sample# NA
.::,pn.:e
Compound I ConcentnUon
gamma-BHC
Heptachlor
Aldrin
Dicldrin
Endrin
4.4'-DDT
• = QC outside limits
D = Diluled out
Addrd
17
17
17
67
67
67
Quality Control Results
Blank Spike(BS)
S W-846-3550/8080
Lab Sample ID: Q5032702EBS
Matri1:
Date Extracted:
Initial Wt:
Final Vol:
Cleanun/#:
BLANK SPIKE (BS)
ulanw.
I C••:•;:Uon ConcentnUon
"°"'"
0 II
0 12
0 12
0 48
0 59
0 49
Soil
03/27/95
30.00 g
10.00 ml
NA
ua
¼ I Reconrv
66
71
72
72
88
73
Kecon·ry B Llmll'I
¼
56-123
40-13 I
40-120
52-126
56-121
38-127
Chain of Custod)_'.
-------------------KIBER
ENVIRONMENTAL
SERVICES INC. '
'I I •
' . ' . -
I ' uOUNDTI=: ::::-1 .Y ,.
DUE DATE: -::.:--/,:-. --..
\ ,., ,r ~--=-;,.,, ? : .,J ,:1 PHONE#: i I I ,
SAMPLE SAMPLE
NUMBER DESCRIPTION
----.! -· j~ , , .. .. .. ,•,-. _,_. __ ...
SAMPLED BY: DATE
IPRINTED NAME: SAMPLED:
, ! .-, -· ) ,/i:-.:.n., ... , ::~•~1!: ,;,,J;:!,,/"1 /,,
ls1q~TURE, _.· TIME . ..
r:> ,-. .• _, ,:-;..,:::;--,,--·:..--SAMPLED:
;/(:OMPANY:
• •• • I ., . Ju ,-:-r.
;1·.; --_, .. -:. r.:: . ..,.
SAMPLE CHAIN-OF-~USTODY RECORD COC#
3786 DEKALB TECHNOLOGY PARKWAY
404) 455-3944 FAX /404) 451-0155 r-AlLANTA, GEORGIA 30340
r'KUJc.\...J. •.. ,~: """'· " . I.,; ANALYTICAL PARAMETI::RS (indUte targce lill) •
·ex \ •
CONTACT: KES PROJE'--1
MANAGER: . .
,;,, /" ·#';'-•Ji/ . :, . / ,_,I'. 1,-.....
RECEMNG LAB: PO#: . ' . ~. ll' .:I-~6~S'I SAMPLE GRAB/ SAMPLE PRESE! #/SIZE OF \"
DATE/TIME COMP. MATRIX VATIVE CONTAINERS ,. Remarks
, .1/,: '.l/f:. /'-;11.-1
I
r .. I /-f-,,• -,,._ . ,
,.. . ?/) _.r.,r,_ i
'
SAMPLES DATE/ SAMPLES DATE/ COMMENTS:
RELINQUISHED BY: TIME ACCEPTED BY: TIME r-
--. 1/ .},<:-/;f I, I UJk,rr Pl?i!' <; \ /,, .
·'£ . . ' \ ~ , (~, , _, i. r-li:t<'." -· :._/,r?:. .....__ .... _ ~~ ft) ,,r,., •. ,_,,,:. ,;-i.✓: _; r· u -L-, . \ l ... · . L \·--i -. rl , l · . , .. ' ! --\
' ,,Y . \ . ' ..
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EXHIBIT E
I POST-TREATMENT SOIL ANALYSIS
Dioxins/Furans
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-ANALYTICAL RESULTS
FOR THE
FCXPROJECT
KIBER PROJECT #1121-503036
PRESENTED TO
McLAREN/HART REMEDIATION SERVICES
411 Grimes Road
Washington, North Carolina 27889
PRESENTED BY
KIBER ENVIRONMENTAL SERVICES, INC.
3786 DEKALB TECHNOLOGY PARKWAY
ATLANTA, GEORGIA 30340
( 404) 455-3944
March 3 I, 1995
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Case Narrative
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KIBER ENVIRONMENTAL SERVICES, INC.
ANALYTICAL CASE NARRATIVE
McLaren/Hart -FCX
1121 -503036
One soil sample was received for analysis on March 20, 1995 at 1004 hours. The
Environmental Protection Agency (EPA) sampling procedures require soil samples to be
preserved at 4°C ± 2°C. The client was notified that the sample arrived at 16.0 °C.
The requested analysis and corresponding method follow:
·-Analysis . Method
Polychlorinated Dibenzo-p-SW-846 Methods: 8280
Dioxins and Dibenzofurans
Polychlorinated Dibenzo-p-Dioxins and Dibenzofurans
Analysis
Some of the labeled standards used in the analysis have ion fragments with the same
mass as the quantitation mass of some of the analytes. This is true for the TCDF
internal standard and the TCDD analyte. Here fragments of TCDF may be detected
within the retention time window for TCD D. Such occurrences are reported under the
heading estimated maximum possible concentration (EMPC). EMPCs may be
considered artifacts from the labeled standards and are a direct result from the method
requested use of low-resolution mass spectrometry (LRMS). There were no further
analytical difficulties noted during the analyses.
Quality Control
The quality control analyses included the following: a method blank (TU Soil Blank),
matrix spike, and matrix spike duplicate. The results were within the method
specified limits. The sample selected for the matrix spike and matrix spike duplicate
analyses may not be representative of the sample in the FCX study.
Dat
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I Dioxins & Furans Results
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TL~RTP Project: 31988
Client Sample: 505036-5
Client Project: 1121-503036
Method 8280 PCDD/PCDF Analysis (b)
Analysis File: E951116
Matrix: SOIL
PCDDIPCDF SUMMARY REPORT
$piici/ic!~~ci• i¢Si\p'l@!Jb1/l ••••oti(wBjt\:1 !$r~hiffupt\j
2,3,7,8-TCDD
1,2.3,7,8-PeCDD
1,2.3,4,7,8-HxCDD
1,2.3,6.7,8-HxCDD
1.2.3. 7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2.3,4,6,7,8,9-0CDD
2,3,7,8-TCDF
1,2.3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2.3,6,7,8-HxCDF
2,3,4,6, 7,8-HxCDF
1,2.3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1.2.3.4. 7,8,9-HpCDF
1,2.3,4.6.7.8,9-0CDF
Total TCDD
Total PeCDD
TotalHxCDD
TotalHpCDD
Total TCDF
Total PeCDF ·
Total HxCDF
Total HpCDF
ND
ND
ND
ND
ND
0.36
4.88
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.726
ND
ND
ND
ND
Triangle Laboratories of ATP, Inc.
0.0199
0.225
0.0922
0.068
0.129
0.176
0.0544
0.0235
0.0837
0.159
0.194
0.255
0.222
0.16
0.139.
0.173
0.161
0.199
0.225
0.0964
0.176
0.0235
0.122
0.208
0.156
801 Caprtola Drive• Durham, North Carolina 2n13
Phone: [phone] • Fax: [phone]
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Page l of l
Printed: 14:59 03128/95
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TL-RTP Project: 31988
Client Sample: · 50~036-5
Client Project:
Sample Matrix:
lLRTP ID: ;
Sample Size:
Dry Weight:
GCColumn:
2.3.7.8-TCDD
1.2.3.7,8-PeCDD
1.2.3.4,7.8-HxCDD
1,2.3.6,7,8-HxCDD
1.2.3,7,8.9-HxCDD
1.2.3,4,6.7.8-HpCDD
1,2,3,4,6,7,8,9-0CDD
2.3,7,8-TCDF
1.2.3,7,8-PeCDF
2.3.4,7,8-PeCDF
1.2.3,4,7,8-HxCDF
1.2.3,6,7,8-HxCDF
2.3.4,6,7,8-HxCDF
1.2.3,7,8,9-HxCDF
1.2.3.4,6,7,8-HpCDF
1,2.3.4,7,8,9-HpCDF
1,2,3,4,6, 7 ,8,9-0CDF
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
llll-503036
SOIL
97-166-1
10.000 g
n/a
DB-5
Triangle Laboratories of ATP, Inc.
ND
ND
ND
ND
ND
0.36
4.88
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.726
ND
ND
ND
Method 8280 PCDD/PCDF Analysis (b)
Analysis File: £951116
Date Received: 03/21/95 Spike File: SP828050
Date Extracted: 03/21/95 ICAL: E851135
Date Analyzed: 03/26/95 CONCAL: E951111
Dilution Factor: n/a ) % Moisture: 0.0.
Blank File: E951115 % Lipid: n/a
Analyst: GM % Solids: 100.0
0.0199
0.225
0.0922
0.068
0.129
1.04 35:05
0.88 38:15
0.0235
0.0837
0.159
0.194
0.255
0.222
0.16
0.139
0.173
0.161
0 0.491
0 0.225
0 0.0964
2
0 0.0289
0 0.122
0 0.208
0 0.156
Page 1 of2 !12BO_PSR v:l05. LARS 5.l-l.08
801 Capitola Drive• Durham. North Carolina 27713
Phone: [phone] • Fax: [phone]
Printed: 14:59 03/28/95 40
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TL-RTP Project: 31988
Client Sample: 503036-5
"C11-2,3,7,8-TCDF
"C,,-2,3,7,8-TCDD
"C11-l,2,3,6, 7,8-HxCDD
''C,,-1,2,3.4,6,7,8-HpCDF
"C11-l,2,3,4,6, 7 ,8,9-0CDD
"C4-2.3,7,8-TCDD
"Ci,-1,2,3,4-TCDD
"Ci,-1,2,3,7,8,9-HxCDD
Triangle Laboratories of RTP, Inc.
3.04
3.7
4.16
821
531
1.67
801 Caprtola Drive• Durham, North Carolina 27713
Phone: [phone] • Fax: [phone]
Method 8280 PCDD/PCDF Analysis (b)
Analysis File: E951116
60.8 40%-120%
73.9 40%-120%
83.1 40%-120%
82.7 40%-120%
53.1 25%-120%
67.0 40%-120%
0.79
0.80
1.26
1.07
0.90
0.79
1.28
03/28/95
22:57
23:50
32:06
34:07
38:14
23:51
23:36
32:23
Printed: 14:59 03/28/95
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TL-RTP Project: 31988 Toxicity Equivalents Report
Client Sample: 503036-5 Analysis File: E951116
Client Project: lUl-503036
Sample Matrix: SOIL Date Received: 03/21/95 Spike File: SP828050
1LRTPID: 97-166-1 Date Extracted: 03/21/95 ICAL: E851135.
Date Analyzed: 03/26/95 CONCAL: E951111
Sample Size: 10.000 g Dilution Factor: n/a % Moisture: 0.0
Dry Weight: n/a Blank File: E951115 % Lipid: n/a
GC Column: DB-5 Analyst: GM % Solids: 100.0
2,3,7,8-TCDD .ND X I = 0
1,2,3, 7,8-PeCDD ND X 0.5 = 0
1,2,3,4,7,8-HxCDD ND X 0.1 = 0
1,2,3,6.7,8-HxCDD ND X 0.1 = 0
1,2,3,7,8,9-HxCDD ND X 0.1 = 0
1,2,3,4,6,7,8-HpCDD 036 X 0,01 = 0.0036
1,2,3,4,6,7,8,9-0CDD 4.9 X 0.001 = 0.0049
2,3,7,8-TCDF ND X 0.1 = 0
1,2,3,7,8-PeCDF ND X 0.05 = 0
2.3,4, 7,8-PeCDF ND X 0.5 = 0
1,2,3,4,7,8-HxCDF ND X 0.1 = 0
1,2,3,6,7,8-HxCDF ND X 0.1 = 0
2,3,4,6,7,8-HxCDF ND X 0.1 = 0
1,2,3,7,8,9-HxCDF ND X 0.1 = 0
1,2.3,4,6,7,8-HpCDF ND X 0,01 = 0
1.2.3,4,7,8,9-HpCDF ND X 0,01 = 0
1,2.3,4,6,7,8,9-0CDF ND X 0.001 = 0
Total 2,3,7,8-TCDD Toxicity (1989 ITF} Equivalents: 0.0085 ppb
Triangle Laboratories of ATP, Inc.
801 Capitola Drive• Durham, North Carolina 27713
Phone: [phone] • Fax: [phone]
Page 1 of 1 TEFPR.~ YS 06, LARS 3.14 08
Printed: 15:02 03/28/95
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TL-RTP Project: 31988
Client Sample: TI.I SOIL BLANK
Client Project: n/a
Method 8280 PCDD/PCDF Analysis (b)
Analysis File: E951115
Matrix: NA2SO4
PCDDIPCDF SUMMARY REPORT
sf,~Sijhalyj.iis Il¢&/lql @i:i~>ii l;illPP'@ilb);(;\l;;!:Bi~ok@pbjf
2.3,7,8-TCDD ND ND 0.0199
1,2,3, 7,8-PeCDD ND ND 0.225
1,2,3,4,7,8-HxCDD ND ND 0.()1)22
1,2,3,6,7,8-HxCDD ND ND 0.068
1,2,3, 7,8,9-HxCDD ND ND 0.129
1,2,3,4,6, 7,8-HpCDD . ND ND 0.176
1,2,3,4,6,7,8,9-0CDD ND ND 0.0544
2.3,7,8-TCDF
1.2.3,7,8-PeCDF
2.3,4, 7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6, 7,8-HxCDF
2.3,4,6,7,8-HxCDF·
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-0CDF
Total TCDD
Total PeCDD
Total HxCDD
TotalHpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND.
ND
ND
ND
ND
ND
ND
Triangle Laboratories of RTP, Inc.
0.0235
0.0837
0.159
0.194
0.255
0.222
0.16
0.139
0.173
0.161
0.199
0.225
0.()1)64
0.176
· 0.0235
0.122
0.208
0.156
801 Capitola Drive• Durham, North Carolina 27713
Phone: [phone] • Fax: [phone]
Page 1 of 1
Printed: 14:25 03/28/95
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TL-RTP Project: 31988
Client Sample: . TLI SOIL BLANK
Method 8280 PCDD/PCDF Analysis (b)
Analysis File: E951115
Client Project:
Sample Matrix:
1LRTPID:
Sample Size:
Dry Weight:
GC Column:
2.3.7.8-TCDD
1.2.3.7.8-PeCDD
1,2,3,4.7,8-HxCDD
1.2.3.6.7,8-HxCDD
1,2,3,7.8.9-HxCDD
1,2,3,4.6.7,8-HpCDD
1,2,3,4,6, 7,8,9-0CDD
2,3,7,8-TCDF
1,2,3.7,8-PeCDF
2.3.4,7,8-PeCDF
;,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2.3,4,6,7,8,9-0CDF
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
n/a
NA2SO4
. TIIBLANK
10.000 g
n/a
DB-5
Triangle Laboratories of RTP, Inc.
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Date Received: I I
Date Extracted: 03/21/95
Date Analyzed: 03/26/95
Dilution Factor: n/a
Blank File: E951115
Analyst:
0
0
0
0
0
0
0
0
0.0199
0.225
0.0922
0.068
0.129
0.176
0.0544
0.0235
0.0837
0.159
0.194
0.255
0.222
0.16
0.139
0.173
0.161
GM
0.225
0.0964
0.176
0.122
0.208
0.156
Page I of2
801 Caprtola Drive• Durham, North Carolina 27713
Phone: [phone] • Fax: [phone]
Spike File: SP828050
ICAL: E851135
CONCAL: E951111
% Moisture: n/a
% Lipid: n/a
% Solids: n/a
0.476
0.0306
8230_PSR ¥:1.05. LARS 5.14 08
Printed: 14:25 03/28/95
20
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::+ ;:::'\t'"fo: ;>;:::::::'ex1~ER;~~o~~-~;s~¥i~rmiS:';j1r:,:<\sf :t4::'~;:'r~:;
TL-RTP Project: 31988 Method 8280 PCDD/PCDF Analysis (b)
Client Sample: n1 SOIL BLANK Analysis File: £951115
"C,r2.3, 7,8-TQ)F 2.62 52.5 40%-120%
"C,r2.3, 7,8-TQ)D 3.23 64.7 40%-120%
"C,r 1,2.3,6, 7,8-HxQ)D 3.74 74.8 40%-120%
"C,rl,2,3,4,6,7,8-HpCDF 7.64 76.4 40%-120%
"C12-l,2.3.4,6, 7,8,9-omD 4.8 48.0 25%-120%
"CI.-2,3,7,8-TQ)D 1.53 61.2 40%-120%
"C12-1,2,3,4-TffiD
"C 12· 1,2.3, 7,8,9-HxQ)D
""',,.,.Jj/i,f,,e,r, COa1f ,,~
Triangle Laboratories of ATP, Inc.
801 Capitola Drive• Durham, North Carolina 27713
Phone: [phone] • Fax: [phone]
Page 2 of2
0.79 22:59
0.79 23:52
1.29 32:07
1.06 34:08
0.89 38:15
23:53
0.81 23:39
127 32:24
03/28/95
8280_PSR .,:~0.5. LARS 5,!4.08
21
Printed: 14:25 03/28/95
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TL-RTP Project: 31988
Client Sample: TLI SOIL BLANK
Client Project: n/a
Sample Matrix: NA2S04 Date Received:
1LRTP ID: TLIBLANK Date Extracted:
Date Analyzed:
Sample Size: 10.000 g . Dilution Factor:
Dry Weight: n/a Blank Fl.le:
GC Column: DB-5 Analyst:
2,3,7,8-TCDD ND X 1
1.2.3.7.8-PeCDD ND X 0.5
1.2.3,4,7,8-HxCDD ND X 0.1
1,2,3,6,7,8-HxCDD ND X 0.1
1.2.3.7,8,9-HxCDD ND X 0.1
1,2.3,4,6,7,8-HpCDD ND X 0.01
1,2,3,4,6,7,8,9-0CDD ND X 0.001
2,3,7,8-TCDF ND X 0.1
1.2.3,7,8-PeCDF ND X 0.05
2,3,4, 7,8-PeCDI" ND X 0.5
1.2.3,4,7,8-HxCDF ND X 0.1
1.2.3,6, 7 ,8-HxCDF ND X 0.1
2.3,4,6,7,8-HxCDF ND X 0.1
1.2.3,7,8,9-HxCDF ND X 0.1
1,2,3,4,6,7,8-HpCDF ND X 0.01
1.2.3,4,7,8,9-HpCDF ND X O.Ql
1,2,3,4,6, 7 ,8,9-0CDF ND X 0.001
I I
03/21/95
03/26/95
n/a
E951115
GM
=
=
=
=
=
=
=
=
=
=
=
=
=
=
=
=
=
Toxicity Equivalents Report
Analysis File: E951115
Spike File:
ICAL:
CONCAL:
% Moisture:
% Lipid:
% Solids:
0
·O
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
SP828050
E851135
E951111
n/a
n/a
n/a
Total 2,3,7,8-TCDD Toxicity (1989 ITF) Equivalents: O ppb
Triangle Laboratories of ATP, Inc.
801 Caprtola Drive• Durham, North Carolina 27713
Phone: {919) 544-5729 • Fax: {919) 544-5491
Page I of I TEFPR.~g vS.06. LARS ~.lJ OS
Printed: 14:25 03/28/95
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Isomer
TRIA...~GLE LABORATORIES OF RTP, INC.
MATRIX SPIKE RECOVERY ANALYSIS AND COMPARISON
E951021
ID,
L9507599-00
2
Sample
(ppb)
Project: _31962
Matrix: SOLID
Method: 8280
E951022
ID,
L9507599-00
2 CMS)
With Spike Percent
(ppb) Recovery
E951023
ID,
L9507599-00
2 (MSD)
Spike Dup
(ppb)
Relative
Percent Percent
Recovery Ditterence
----=====================---------------================================================================
2378-TCDD ND 0.86 86.1 1.0 100 14.9
12378-PeCDD ND 2.7 109 3.2 128 16.0
123478-HxCDD ND 2.2 87.2 2.6 102 15.6
123678-HxCDD ND 2.8 113 3.2 125 10.1
123789-HxCDD ND 2.3 90.2 3.1 122 30.0
1234678-HpCDD ND 2.2 86.2 3.0 120 32.8
OCDD 0.20 3.9 74.5 4.7 89.5 18.3
2378-TCDF ND 0.92 91.4 1.1 105 13.8
12378-PeCDF ND 2.8 110 3.2 126 13.6
23478-PeCDF ND 3. 1 122 3.7 145 17.2
123478-HxCDF ND. 2.4 95.2 2.2 88.5 7.29
123678-HxCDP ND 2.0 77 .8 2.0 80.4 3.29
234678-HxCDP ND 1. 9 74.1 2.2 88.7 17.9
123789-HxCDF ND 1. 7 68.1 2.2 87.1 24.5
1234678-HpCDP ND 2.1 84.8 2.4 95.4 11. 8
1234789-HpCDP ND 1. 6 64.8 2.0 80.6 21. 7
OCDP ND 4.2 84.6 4.3 85.0 0.47
==============================-==--=-==-===============================================================
ND: Not Detected
NA: Not Applicable
( .. ]: EMPC Value
Triangle laboratories, Inc.
801 Capitola Drive• Durham, North Carolina 27713
Phone: [phone] • Fax: [phone]
LARS 5.14.08
TLI_PSUM v2.02
b
Printed: 14:28 03/28/95
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Chain of Custody
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-------------------
KIBER
ENVIRONMENT AL
SERVICES, INC.
'N l NAMJ::.: I
SAMPLE CHAIN-OF-CUSTODY RECORD
,,. :
I
3786 DEKALB TECHNOLOOY PARKWAY
A1LANTA, GEORGIA 30340
404) 455-3944 FAX/[phone]
ANALYTICAL eJ.RAMETERS (indiu111 larg£t lia)
..;:
r--.)
PHONE#: (0 ,,, c"\·1'\-7,-:_::_.. , "
li!..!-:'SAM~P::LE'::'-''-f-'-'--'-'--';;SAM-'-:-:-:::PL:--:Ec-'=-=-f-==-;::-,;:====~==;;,--;,-;=;;:;-;:;;;-il '.~ f
NUMBER DESCRil'TION
~:--, 1"'-L-,7'-1'C,?-,._J\
~:.,._,,,.,\_,. ;:-1...,._:,A_•.._i
,
SAMPLE
DATE/TIME
~'i" i ,--, -r
:i,oo
GRAB SAMPLE
COMP. MA1RIX
c... ~
PRESct< #/SIZE OF
VATIVl CONTAINERS
:,\,:,,,. I -"-\~.,__
·-f£__
J
.r
COC#
I
Remarks
I\Jl.3,
•
. -
~A•=LEDBY: DATE
SAMPLED:
SAMPLES
RELINQUISHED BY:
DATE.I
TIME
SAMPLES
ACCEPTED BY:
DATE/ COMMENTS:
PRINTED NAME:
~OMPANY:
!·-.,;;_ \,.1,,.,:.~,,jHAc~\
TIME
SAMPLED:
. . . , .• ..
TIME
QJJ,,}0 ,r.
.•. , I ~ G ,
\ L9 '\ . t~c
h-"\l_
iv-
' 1
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EXHIBIT F
POST-TREATMENT SOIL ANALYSIS
Stack Sampling
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03/29/95 11:00 FAX [phone] ET:; I NC.
'
SUMMARY OF PCDD/PCOF EMISSIONS
McLAREN HART
RUN 1.0.
DATE
TIME STARTED
TIME ENDED
STACK OUTLET
SAMPLING PARAMETERS
Metered Volume -def
C01Tected Volume • dscf
Tote! Test Time • min
% lsokinetics
GAS PARAMETERS
Gas Temperature -° F
Oxygen•%
Carbon Dioxide -%
Moisture -0,,,
GAS FLOWRA TE
Velocity -ntsec
Actual Volume -actm
Standard Volume • dscfm
PCODIPCDF EMISSIONS
{Total as 2378-TCDD Toxle
Equivalents)
Cone. -ng1Nm3 @7% 02
Mass Rete -lb/hr
SO-M23-R2
03117/95
09:02
13:00
196.215
193.042
238
97.8
77
16.5
1.8
2.3
17.38
205
196
1.1 BE-01
1.40E-11
uJ,Z1l/\J& l1:34 f AX 'I <13Zti51J l 3 I El,; IN<.'. .\'.l'OUJ
I
RUN NUMBER SO-M23-R2
I Dale 03/17/95
Start Time -09:02
End Tlme 13:00 M!:THOD 4 DATA I Stack Diam. 8 lnc/1es INIT. l"'INAL NET
Nozzle 1.0. 0.390 Inch&! (mil {mil !mil
Meler Box Gemme 1.0096 IMP.1 0.0 62.0 62.0
I Me1erBoxdH@ 1 7002 IMP.2 100.0 98.0 •2.0
Barometric 29.88 In.Hg IMP.3 100.0 98.0 -2.0.
Cp 1.00 IMP.4 0.0 2.0 2.0
Test Ourellon 238 minutes IMP.5 0.0
IMP.6 0.0
IMP.7 0.0
METHOD 1-4 RESULTS TOTAL 200.0 260.0 60.0
Me1enld Volume 196.215 def S.G. 300.0 334.5 34.5
Volume (!; Sld.Cond. 193.042 d!Cf
% Waler 2.25 •A, METHOD 3 DATA
I % lsokinellcs 97.8 o/o %02 18.5 Md 29.00
Velocity 17.38 Nsec %CO2 1.80 Ms 28.75
Acluel Flow 205 actm %CO 0.0 PS 29.88
Sid. Flow 201 sclm o/oN2 79.9 Fo 1.500
I Dry Sid. Flow 198 dscfm 02~C02 20., %EA 713
STACK METER METER TEMPERATURE
TEMP STATIC DP DH VOLUME INLET OUTLET
I POINT !DegE} !In.WC) !in.WC) !In.WC) (de/) !DeaE} ~SF! 1 67 -0.01 0.050 1.60 279.730 66 66
2 88 0.045 1.45 475.945 89 88
I 3 66 0.045 1.45 70 88
4 89 0.044 1.40 73 &9
5 69 0.043 1.38 75 70
6 69 0.043 1.38 75 70 I 7 70 0.044 1.40 76 71
8 72 0.082 2 00 79 73 ' 9 74 0.060 1.91 83 75 i 10 78 0.060 1.91 86 80 I 11 77 0.060 1.91 87 80
12 78 0.062 2.00 90 62 I 13 79 0.100 3.20 88 83 ,, 80 0.060 1.91 90 88
15 83 0.080 1.111 94 89
18 &4 0.055 1.7S 97 91
17 85 D.100 3.20 97 93
18 85 0.090 2.90 96 92
19 88 0.100 3.20 97 92
20 84 0.070 . 2.20 97 92
21 M 0.090 · 2.90 95 91
22 65 0.100 3.20 ~ 91
23 86 0.100 3.20 98 90
I 24 85 0.080 2.80 06 91
475.945
I AVG. 77 -0.01 0.07 2.17 1ge.21s 84 I I I
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FAX 7U3265ll! 3 I ETS I NC.
EPA METHOO 23 LABORATORY DATA
McLAREN HART '
STACK OUTLET
RUN I.D.
2378-TCDD
12376-PCDD
123476-HxCDO
123678-HxCDD
123789-HxCDD
1234878-HpCDD
OCDO
2378-TCDF
12376-PCDF
23478-PCDF
123478-HxCOF
123878-HxCDF
234678-HxCDF
123789-HxCDF
1234678-HpCDF
1234 75g.HpeDF
OCOF
TOTAL TCDD
TOTAL PCOD
TOTAL HxCOD
TOTALHpCDD
TOTAL TCOF
TOTAL PCDF
TOTALHxCDF
TOTAL HpCOF
OTHER TCDD
OTHER PCOD
OTHER HxCDD
OTHER HpCDO
OTHER TCDF
OTHER PCDF
OTHER HxCDF
OTHER HpCOF
NOTES:
90-M23-R2
SAMPLE
(nql
0.004 •
0.040 •
0.220
0.350
0.500
8.300
38.800
0.160
0.040
0.110
0.110
0.040
0.070
0.020
0.190
0.000
0.190
0.010
0.230
3.000
17.700
0.700
0.880
0.590
0.340
BLANK
(ngl
0.000
0.000
0.000
0.000
0.000
0.010 •
0.120
0.040
0.002 '
0.020,...,
0.008
0.000
0.010
0.000
. 0.005 •
0.000
0.000
0.004
0.000
0.008 •
0.010 •
0.110
0.070
0.020
0.005 '
RUN-BLANK
(ng)
0.004
0.040
0.220
0.350
0 500
8.290
38.480
0.120
0.038 oogo
0.104
0.040
0.060
0.020
0.185
0.000
0.1_90
0.006
0.230
3.892
17.690
0.880
0.810
0.570
0.335
0.002
0.190
2.822
9.400
0.580
0.882
0.348
0.150
(') Data represents the estimated maximum probable concentration (see
report narrative accompanying the dioxin/furan labOratory date, Appendix ).
· 2378-TCDF and TOTAL TCDF values were taken from column DB-225 confirmation en
This column is specific for furans.
-------------------l!ll!IIIL_
" " " " \! J. (J EPA METHOD n TEST ~ESUt TS
McLAREN HART
~
~
STACK OllTlH -~
~
RUNl.0. SO-M.>-IU
CORR. SAMP'-E VOl~ME: 196.'.?15 dsd
~ CORR. GAS F'-OWRATE: 191!1 d&efm ), 02CONTENT: 18:5 % >
2375-TCOO 2,re-rcoo TOXIC EQUIVAL.ENCY -:s " CONCENTRATION ....,;s TOYJC CONCENTRATIONS MASS " a: (OQ.'Nml RATE tUUNALENCY (ng/NmJ RATE g {ng1Nm3) Gl:7~02} ~ FACTOR (04'Nm3} C~Q2] IOOrrl -OKlXL.'\IS -"' X378--TCDD 00008 00045 ::i.29E-13 ' 00006 0.0045 5.29E·13 Oltler TCDO 0.000. 0.0022 2Jl5E-13 0.01 o_oooo 0.0000 2.65E-1S 11376-PCOD 0.00/7 0,04(7 5.29:E-12 0.5 0.0008 0022-l 2.65E-t2 ultwl:rF'COO 0.00<!7 0.212:li 2.!51 E.-11 o.= 0_0002 0.0011 l -lef-13 1234764-btCnO 0.O.C25 0.2461 2.91E-11 004 0.0017 0.0098 1.16E-12 123878-HJCOO 0.0676 'J.3915 ,.63E-11 004 00027 0.0157 1.8!5E-12 t2J78S-HxCOO 00981! o.= 6.62:E-11 0.04 o_ooos 0.0224 2.65E·12 OtrMir 1-hCOO 0.5"!51 3.1568 3_1,e-10 0.000. 0.0002 0.0013 L.cQE-13 (Tl 1234678-ttpCOO URl12 9.27J6 1 ,oe-00 oom 0.W16 0.0093 1.I0E-12 ~ .:.n OttN:r ttpCOD 1.815G 105153 124f-09 u:.-os 0.0000 00001 1.24E-14 ocoo 7.CW60 40.80f33 .&..83E-00 0 noooo 0.0000 O.OOE-00 z r: TOTALPCOO 11.2601 65.21-49 7.72E-09 0.0149 0.0866 1.0'2E-11
FUUNS
2378-fCOF 0.0232 0.13'2 1591:-11 01 0.0023 0013-4 1.59E-12 on,.,n:DF 0.1082 0.6264 7.41E-11 0001 '10001 00006 7.41E-14. 123~0F 0_0073 004.5 5.0JE-12 01 0.0007 0.00.fJ 5.00E-13 23478 PCOF 0.0174 0.1007 1.191:-11 0.1 00017 0.0101 1.tQE-12 Olll«PCDF 0.1317 0.762\l 900c·11 0001 0OOJ1 0.0008 9.G:?f.-14 123478-tb:COF 0.0201 0.1163 1.38t-11 0 Dt O 0002 0.0012 1.38E-13 12:i678-Hli:COF 0.0077 0.04-47 5 29E-12 o Dt 00001 0.0004 s.:9E-14 2J4678-H::tC0F 0.0116 00671 7.94E-1i o_o, 0.0001 0.0001 7.YO:-14 123769-H>COF 0.0039 0.02:i74 2.65F.-12 0.01 00000 0.ocx:12 :.65E-f4 OCher 1-hCOF 0JJ668 0.3871 4.5!1E-11 a.mot 0.0000 0.0000 4.SSf-15 1234676-H!>C()F O.OCJ57 0.20ti9 ·1.~E-11 o.mn 0.0000 U.0002 2.45E-14 1:3<799-HpCOF 0.0000 0.0000 o.ooe .. oo 0.001 00000 0.0000 O.OOE•OO Oth<ir HpCOF 0-□290 0.1678 1.99E-11 1E-05 00000 0_0000 1.a-e.16 OCOF 0.006? 0.2125 2.51E-11 0 00010 O.O<nJ 0.OOE+OO
TOT,i,l__PCOF 0.4993 2.8917 1 .. ::e-10 00055 0.0319 3.77E-12
ror~PCDD+PCOF 11.759 66.107 8 OSE-09 0.0204 0.11&3 1.-40E-J1 §
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ME"Tl100 0030 • VOl>Tl~I! OACA!"flC OOMP(;ll.N)S
....,....,l.YTlCAL OAT,. ANO RBSUl T!I
SAMPLING DATA:
RunHumtirr:
Coif, $3rnplt Vol....-.
COl"I. F,o,,,rat..
ANALYTICAL DA TA:
e•,ic,19 t.O.:
Bt,n~ LO.
A.et1on•
~.t~t"lt chl0f1dt
rtl'lt-· 1,Z-Ol::hlo"'91,,.,_
I, 1-0ich~!hltM
t.,_1,2-0lch~ -1,2-Di:h~tl909
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rant•, ,3-Dchlorop~t
1, 1.2•i'1chlo!twth.-,,
't,,vne-,hi0f0(T't'thllrw -·"'"'t¥-l•p,tnhlnon11 ~,..,.
sfl'llet'lm:dllre
NOTES:
WH-4110000-AI
0, ,4.58 dsd
150 dldm (1)
94-:,0::-,0:r.:-oo;
;14,.J05-31)131311
!10.'40
"Z.50
94.0!5
ue1
137 ~t!
OG.Q5
re ,,
IHJ,01'
U.04
oe,g~
08 G7
119.39
oe-.ee
815.Cl''il
12.10
1JJ.42
153.84
79, 11
131.40
112 gg
'"1.91
110.;11
110.~e
133.42
208.28
2!32.11
100.,e g,_,,
,e,e,
IC0.11J
112.56
10611!
100.115
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11'7 M
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