NCD986187094_20010930_Reasor Chemical Company_FRBCERCLA SPD_HRS Documentation Package Volume V References 14 - 30-OCR

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STATE OF
NORTH CAROLINA
Department of Environment
and Natural Resources
Division of Waste Management
Supe,fund Section
HRS DOCUMENTATION PACKAGE
Volume VI References 14 -30
December 2000
Reasor Chemical Company
NCD 986187 094
Castle Hayne, New Hanover County, Norlh Carolina
Jeanette Stanley
E11viro11mental Chemist
Division of Waste Ma11ageme11t
Supe,fund Section
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Ref. 14 Reasor Chemical
NCO 986 187 094
Castle Hayne, New Hanover Co., NC
LATITUDE AND LONGITUDE CIILCULIITIOII WOR.KSHE:F.T 12 LI USING ENGINEER'S SCALE (1/60)
STATE: ;JC -~----SJ.TE flEF'ER.ENCE POI HT: G<to MC'...-r~· C. l_a ..... +~
USGS QUAD HAP NAHE: C,r//<.-Ha;"'-' -------~----TOh'NSHl P: MI s RANGE:. E / W l'i,o SCALE: 1: 2 4, 000 HAP DATE: SECTION: 1/4 ---1/4 ---___ l/4 HAP DATUH: §) 1983 (CIRCLE 011£) HERIDI/\.N: ------------------COORDIIIATES FROH LOWER RIGHT (SOUTHEAST) CORNER OF 7.5' HAP (attach photocopy;: LUNGITUDE:
LATITUDE: :3, '-/ 0 IS-, oo ,,
COORDINATES FROH LOh'ER RIGHT (SOUTIJEAST) CORllER OF 2. 5' GHIO CELL: LONGITUDE: 77 0 Sl..-, 20,,
LATITUDE: J'-/ 0 ']_O, 00 ,,
CALCULATIONS: :..ATITUOE ( 7. 5' QUADRAilCL2 HAP)
NUHBEA OF RULSA GAADUATIOHS FROM LAT!TUDE GHIO LINE TO SITE RE:F POINT: HULTIPLY (A) BY 0.]304 TO C0!·1VEl~T l'O SECONDS:
C)' Et.PRESS Itl HIIIUTF:S AIJD SECOIHJS ( l '= 60"): 0
D) A.DD TO ST.l\..RTING LATITUDE: 3<./ o '),O • QO 0 + 0
SITE LATITUDE: JL( o 1.,.0
CALCULATIONS.: LONGITUDE ( 7. 5' QUl\DR.AtlGLF: Ml\P)
Ai NUHBER OF RULER. GRADUATIOllS FROM fUGHT LO//GlTUDE Lit-iE TO SITE REF POll"/T: 8) !1ULTIPLY (A) BY O.JJ04 TO CO/~VEnT TO S2COl~DS:
AX O.JJO-~
C) EXPRESS rn liIIIUT:;s A/:0 SECOJIDS I I d
/10
I D) ,\DD TO STA.RTiriG LOIIG!TUDE: '77 o Sl.-, l,o 6 0
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r'-_--------7-7_o_r_3·-.-..,,-/--CJ-~
SITE LO//CITUDE: ....:i ..J ------
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SITE NAME:_J_,_,_~_•_•_• __ ___,,_-_~_,,._,_~_._1 _________ _ NUMBER:_l_•_~_v __ ,_•_·_• __ •_•_•_•_,_·,_
~---······························------
TOPOGRAPHIC MAP QUADRANGLE NAME: rJC. Q,~"•fl,<tl-o,;.,..,( SCALE: I :24 ,000
COORDINATES OF LOWER RJGHT-HAND CORNER OF 2.5-MINuTE GRJD:
LATITUDE: 3'f o "lo · 00 · LONGITUDE: 17 o Si-3o ·
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FRANKLIN E. MAHTIN
JouN G. WESSELL, III
WILLIAM A. HANEY, Ju.
Ref 15
Reasor Chemical
NCD 986 187 094
Castle Hayne, New Hanover Co., NC
MARTIN, WESSELL & l~ANEY
ATTORNEYS AT LAW
107 NoBTU SECOND STREET ~-'
PosT 0Pl'IOE Box 1040 ·IY '.e·-·
\VILMJNOTON, NORTH GAHOLINA 284~ :(,Jt _ . TELEPHONI!: (010) 343·0106
•~_•.;~--~~... . FAX (0!0) 76fl·O272 ~ti~;: fj'/ ~"t(J
'I'/} ~<) August 31, 1990 ~hi ·
~4'
Mr. Jack Butler
Environmental Engineer
Superfund Section
Division of Solid Waste Management
P.O. Box 27687
Raleigh, NC 27611-7687
Re: Reasor Chemical Company
Castle Hayne, New Hanover County, North Carolina
Dear Mr. Butler:
Our firm represents Hilda and Jane Cameron who are the
owners of the former Reasor Chemical Company site in New Hanover
County. Mr. Bruce Cameron has acted as spokesperson for the
family-owned property.
In your correspondence to Mr. Cameron of August 22,
1990, you requested that he complete and submit a "Notification
of an Inactive Hazardous Substance or Waste Disposal Site.'' Such
a notification was completed and submitted to Charlotte
Varlashkin of the Superfund Program on May 25, 1989. This was
soon after the potential problems at the site were discovered. I
have enclosed a copy of the notification that was submitted at
that time.
If we can be of further assistance, please contact me.
WAR:pk
WAR3: 24
Enclosure
cc: Mr. Robert A. O'Quinn
Mr. Bruce Cameron
Sincerely,
MARTIN, WESSELL & RANEY
~ f
w. A. Raney, Jr.
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I l.C. Oepartment of Human Resources
1
.• '.ivision of Health Services
SECTION A
I NOTIFICATION OF AN INACTIVE HAZARDOUS SUBSTANCE
OR WASTE DISPOSAL SITE
I North Carolina Gl'nernl Statutes Section I 30A-] 10 rrovide.c; (or prntl'ctio11 of the public ftrnn in:ll.'tive ha::irdow; :rnhstancc or wastl' disposal sites. Notification Information, required by North l:arulina Gl'IH:ral Statutes Section J 30A-l 10.1 ( b) must he submitted to:
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Supe;fund lJnir
Division of Health Services
P.O. Box 2091
Raleid,, NC 2 7602-2091
Plerue rcacl iruiru:ctions befare completin~.
Plerue ryf,e or print in blac.:k ink.
A. SITE NAME AND PERSON REQUIRED TO NOTIFY:
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t. Site Name Reasor Chemical (Company)
(One site per form}
2. Person Completing Form:
Name W. A. Raney, Jr.
Mailing Address P, 0, Box 104 9
City Wilmington Stat< N, C. Zip CnJe __ 2_8_4_0_2 __ _ Telephone ( 919 ) 343-0196
3. Present Owner:
Name Jane Wells Cameron -Hilda C. Cameron-
Mailing Address c/o Bruce B. Cameron P. 0. Box 4029
City Wilmington State_ . .!'I~ ..... Zip CoJc -·-?§~9§ __ _ T elephunc _...( _9ulc,9,_.,_) __,7...,,6,..2~-_,2,.,6c,7..,6:._ ____ __c_
4. Other Martin Mariet-ta Corp.
Mailing Address Castle Hayne, N. C.
City
Telephone
s. Other Reasor Chemical Company
Mailing Address Dissolved Corporation
City .... ______ _
T eleph(~nc
l>IIS \'iJ4111:1,n,
l'r«·scnr ( Jwner
l'nst Owrn:r
Present Operator
P:-ist Operator
l )ther
(.if>ecify) Attorney for
present owners
(:t.lrpornti1m
11:irtnership
Individual
Other Rcspo,nsihle Party
I ,1•cc'i{y) ____ _
P:,st Ownn
Present Uper:ltor
Pnst Operator
Ud1er R~!•q1unsiblc Party
(1/>cn/y)
Past Owner
Present t)pcr;1tl>r
l':1sr ()p,·r:1111r
( lt/1cr 1lt·~11C111~il1lc !'any
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Site Name Reasor
I .B. SITE LOCATION: •• N. C. Highway 132 I. Street or Route Address ---------------------------------
City or Town ______ Cc..a.cs.ct_l'--e_H_a-'y'--n_e __________________ '--'---------
County New Hanover
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2. Directions to the Site (U.1e state road numbers where possible.)
Main entrance to the site is from N. C. Highway 132 approximately 1/2 mile South
of its merger with N. C. Highway 117. The entrance is controlled by a gate and is
located almost directly across Highway 132 from Dickerson Carolina, Inc. Ifie
entrance road is a dirt road.
3. Attach a Department of Transportation map or a USGS ni.ap showing the location of the site or facility. Label the map with the
site name.
4. Check the appropriate description of the area surrounding the site. ( More than one ma:, apply.)
0 Reside,;tial
0 Business
[J Industrial
0 Pasture Land
Q Forest Land
0 Farm Land
0 Other (specif)) -------------------
C. TYPE AND YEARS OF OPERATION:
I. Type of Operation Manufactured pine chemical products
Standard Industrial Classification Code (SIC) _,u,.:nc:ko:nccO,cw::_n"----------
Years of Operation (Dates) from __ / J..9_ to __ / .}_Q_
Z. Type of Operation
Standard Industrial Classification Code (SIC) ___________ _
Years of Operation (Dates) from __ / __ to __ / __
3. Type of Operation
Standard Industrial Classification Code (SIC) ___________ _
Years of Operation (Dates) from __ / __ to __ / __
D. ENVIRONMENTAL PERMIT HISTORY:
1··1 Present
1.".l Past
J_j Present
LJ Past
J J Present
l J Past
l( no environmental permit has been issued, check "None" for each type of permit. Complete for each of the following.
Type of Permit
l. NPDES
Z. Air·
3. RCRA
4. RCRA
5. State
interim status
None
Permit
Number
Date
Issued
Expiration
Date __ /:._ ___ / __ __ / ____ / __
__ / ____ / __ __ / ____ / __
Comments
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a. Non-dis.charge
b. High productivity well
c. Other (,pacify) ___ _
Local (,pocify) ----'--
__ / ____ / __ __ / ____ / __
__ / __ --1-~
__/ ____ / __
possible septic tank perm: __ / ____ / __
7. Other (,pedfy) ____ _ --1-,---__ / __
I DHS 3524 (II /HJ)
Site Name Reasor
E. CURRENT ENVIRONMENTAL PERMITS:
If no environmental permit has been issued, check '' None'' for each type of permit. COmplete for each of the followin~.
Type of Permit None
I. NPDES [ii
2. A~ Ii/
3. RCRA Ii/
4. RCRA intcrhn status Ii/
5. State [jg
a. Non-discharge ~
b. High productivity well Qg c. Other (sf,ecib) ____ Q9
6. Local (specif,) ____ Q<I
7. Other (specif,) _____ 0
Permit
Number
Date Expiration
ls8~ed Date Comments __ / ____ / __ _ _( ____ / __ __ / ____ / __ __ / ____ / __ __ / ____ / __ __ / ____ / __
--1--__ / __ __ / ____ / __
__ / __ --!--__ / ____ / __
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F. KNOWN OR SUSPECTED RELEASE OF HAZARDOUS SUBSTANCE OR WASTE TO THE ENVIRONMENT: (Mare than one maJ appl,.)
Date of Known
Environmental or Suspected
Media Known Suopected Release Likely Unlikely None Comments
1. Ground water □ ~ __ / __ [] 1: I II See Law Environmental 2. Surface water □ [I __ / __ [] II u 3: Surface soil □ fx] __ / __ [J I I IJ See Law Environmental 4. Subsurface soil 0 I I __ (. __ I] 11 11 5. Air □ 11 __ / __ LI I I II •• I G. PHYSICAL STATE OF HAZARDOUS SUBSTANCE OR WASTE AS DEPOSITED: (Mo,e than one maJ af,ply.)
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I. [I Solid
2. [J Powder
J. 0 Liquid
4. [1 Sludge
5. 0 Non-Containerized Gas
6. 0 Containerized Gas
7. [!',) Other (J,s,Tibc) Unknown, probably liquid
, H. HAZARDOUS SUBSTANCE OR WASTE DISPOSAL AND STORAGE METHOD: ( Mme than one may af,J,ly.)
I. 0 Piles
2. Ll Land treatment
3. 0 Landfill
4. 0 Tanks, underground
5. ~j Tanks, above ground
6. [J Septic tanks
7. [J lmpoundrnent
8. [J. Underground injection
9. [':J Drums, above ground
10. [J Drums, above ground, in open
I I. 1-l Drums, below ground
12. 11 Other (sr,cd{y)
I. HAZARDOUS SUBSTANCE OR WASTE TYPE USED OR DISPOSED ON SITE: ( Mme than one may ar,J,ly.)
I. I'-~ Organics
2. I] lnorganics
.l. li!j Solvents
4. I~! Pesticides
7. I_ I Bases
8. [J PCBs
9. [] MixcJ municipal waste
I 0. / I Unknown
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5. ·I_I Heavy metals· 11. I. I Other (.</,er1/,) ______________________ _ 6. 0 Acids
OHS JU4 (111~71
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Site Name Reasor
J. HAZARDOUS SUBSTANCE OR WASTE QUANTITY: (More than one may apply./
l. Pounds: 4. Gallons:
1J less than 10 pounds [ .J less than IO gallons
[.J 10 pounds or more, but less than 100 pounJs
D I 00 pounds or more, but less than 1000 pounds
D 1000 pounds or more
[_] 10 gallons or more, hut less than 100 gallons
LJ 100 gallons or more, but less than 1000 gallons
D 1000 gallons or more
~ Unknown [2g Unknown
2.· Drums: 5. Total area of site:
D less than 10 drums D less than I acre
D 10 drums or more, but less than 100 drums
D 100 drums or more, but less than 1000 drums
D 1000 drums or more
0 1 acre or more, but less than 5 acres
D 5 acres or more, but less than IO acres
[iiJ IO acres or more
lli] Unknown
3. Cubic Feet:
[I less than 10 cubic feet
LJ 10 cubic feet or more, but less than 100 cubic feet
0 100 cubic feet or more, but less than 1000 cubic feet
0 1000 cubic feet or more
lli] Unknown
D Unknown
K. SOURCE OF HAZARDOUS SUBSTANCE OR WASTE USED OR DISPOSED ON SITE:
( More than one may apply)
1. Mining ..... ~ .... '._ ......... _ ... _._ ................. • ..
2. Crinstruction ............................ _-.. · ...... .
3. Tex tiles ........................................ .
4. Fertilizer ........................ , ............... .
5. Paper/printing .................................... .
6. Leather tanning ................................... .
7. Iron/steel foundry ..................... , ......... ; ..
8. Chen1ical, general .................................. .
9. Plating/polishing .•••.. · .......•.....................
10. Military/ammunition ............................... .
11. Electrical conductors ............................... .
12. Transformers .................................... .
13. Utility companies .••...•......•............ · ........ .
14. Sanitary/refuse ...................... , ............ .
15. Photo finish .•...•.........•......................
16 .. Lab/hospital •••..•.•..•...•......•.....•...••.....
17. Wood treating.· ................................... '.
18. Battery reclaination ................................ .
19. Pesticides formulation, packaging and/ or distrihution ......... .
20. Herbicide formulation, packaging and/or distribution .......... .
21. Other Agrichemical formulation, packaging :md/or distribution ... .
22. Dry cleaning .................................... , ,
23. Petrochemical processing or refining ..................... .
24. Unknown ....•••..•.......•......................
25. Other (.,peci{y) Pine products ......... .
IJHS J524 ( I l/R7)
Used
On Site
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On-Site
Disposal
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OH-Site
Disposal
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Site Name Reasor
L. SPECIFIC HAZARDOUS SUBSTANCE OR WASTE COMPOUNDS ASSOCIATED WITH THE SITE, IF
KNOWN: (MOTe than one mai af,plJ.)
Waste Compounds/ Generated Off-Site On-Site
Substances On Site Disposal Disposal
I. Naphtha (No-known intentional disposal) [J LJ LI 2. □ LI □ 3. [] [] LJ 4. [I D □ 5. [I IJ [J
6. II [I u I M. ACCESSIBILITY OF _SITE: (MOTe than one maJ CJ/>PIJ.)
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I. [] Security guard
2. [J Physical barrier (steep bank, creek, walls, etc.)
Describe physical barriers Ditches surround most of the site. Dense vegetation surrounds
site except on access road which is controlled by a gate.
3. 0 Site completely surrounded by fence
4. D Site partially surrounded by fence
.5. GI Locked gate
6. [.I Unlocked gate
7. [] No control of access to site
8. [ig Other (speci{:J) Unimproved dirt road off SR 1002 accessable only by four-wheel drive
or fqot.
REMEDIAL ACTION: (MOTe than one maJ apf>IJ.)
l. [~] No environmental action
2. ~ Environmental study (preliminary)
3. [] Remedial action
0. AVAILABILITY OF ANALYTICAL MONITORING DATA:
ls analytical monitoring data for the site availabld
I ,j YES I I NO
IF YES: check the appropriate box to indica_te the purpose for which the data was collected. ( More than one ma:, aJ>f,ly.)
[J CERCLA
[J RCRA
0 Remedial Action
0 Environmental Audit
~ Other(iped/J) Environmental study for possible sale of property.
IF DATA WAS COLLECTED: FIRST COMPLETE SECTION P. CERTIFICATION ANO SIGNATURE ON THE NEXT
PAGE ANO THEN COMPLETE DI-IS 3525. SECTION B SITE DATA ADDENDUM NOTIFICATION OF AN INACTIVE
HAZARDOUS SUBSTANCE OR WASTE DISPOSAL SITE.
DHS 35Z4 ( t I .'87)
0
Site Name Reasor
P. CERTIFICATION AND SIGNATURE: m • I
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I certify that to the best of my know edge and belief, the information supp\ieJ on this form is completc·and accurate.
Date 6-1-89
Name and Title (Type ar J;rrint) -----~~_J_r_.~•~A_t_t_o_r_n_e~_f_o_r_0_w_n_e_r_s ____________ _
Mailing Addr~ss Martin, Wessell & Raney, Post Office Box 1049, Wilmington, NC 28402.
I NORTH CAROUNA
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NEW HANOVER ___________ County
I, ----~J~u~d~i~· t~h~T=• ~H=a=s=s~o~n~-------, a Notary Public for said County and State, do hereby certify that
__ W~•-A~·-R~a_n_e_y~•~J_r_. ________ personally appeared before me this <lay an<l acknowledged the due execLition
of the foregoing instrument.
Witness my hand and official seal, this the __ l_s_t __ day of ___ J_u_n_e _______ ~ 1989
(Official Seal)
My commission expires -~{(2~~~~==~-:2. _____ 19 'L .9
11HS 1''14 f 11 m11
Ref 16
Reasor Chemical
NCD 986 187 094
Castle Hayne, New Hanover Co., NC
State of North Carolina
Department of Environment, Health, and Natural Resources
Division of Solid Waste Management
P.O. Box 27687 · Raleigh, Norih Carolina 27611-7687 I
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James G. Martin, Governor
William W. Cobey, Jr., Secretary
William L. Meyer
Director
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September 6, 1991
Mr. Earl Bozeman
EPA NC CERCLA Project Officer
U. S. EPA Region IV Waste Division
345 Courtland Street, NE
Atlanta, GA 30365
Subject: Preliminary Assessment
Reasor Chemical Compariy Site (NCD986187094)
Castle Hayne, New Hanover County, NC
Dear Mr. Bozeman:
This letter contains the findings of the Preliminary Assessment of the Reasor Chemical Company Site in New Hanover County, North Carolina. The NC superfund Section recommends that a Screening site Investigation be conducted at this site.
site Description
The site .is located on Highway 132 approximately 1/2 mile south of. the Highway 132/117/133 interchange in castle Hayne. The ··site coordinates are 34°20'36'' N latitud~~ind 77d53•_30•1 W lon~itude (1, 2). · The site is the former location of a stump rendering facility that reportedly produced turpentine, pine resin, pitch, tall oil,,pine oil, camphor, pine tar, and charcoal from pine tree stumps ( 2) . Little is kno_wn about the exact process used to produce each product. However, it is probable that chipped stumps were extracted with various solvents which• were distilled for separation into various fractions and products.
The site covers approximately 25 wooded acres with little or no development within a quarter mile of the site. The site is not fenced, but there is a locked gate at the entrance to the site on Highway 132 that restricts vehicle access (3). Figure 1 is a map of the site layout showing both past and present structures on the
---·--
11 '-.
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0 ,oo ~
SCALE IN FEET
~JOT:: LOCATICX'-15 ANO, SCN_E!. OF
8JILOJNGS AIIE /,PPAOXIMl,TE
LEGEND
DliH NOA(?
STRE>.'.1 OR
D~.'\ I !\.\GE DITCH
A•.JLROAD TRACKS
---------
ROUTE 1 Jl
\
□ PONO SEDIMENT SAMPLING LOCATION
GROUND·VATER
SAi.iPL IHG LOCATION
o ISOLATED oRUM
----

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FIGURE 1. REASOR G!EMICAL SI'IE LAYOUT AND SAMPLING LCCATICNS
(SCXJRCE: Reference 2)
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A 3
; SLUICE ~~; .\HEA
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site (2). The attached U.S.G.S. topographic quad shows the site
location. There are 4 existing and 1 drained impoundments on the
site I which were found to contain varying levels of volatile
organics in 1989 (2).
I Areas of environmental interest on.the site are denoted on
Figure 1. There is a pile of burned scrap copper, copper wire and
othe~ plastic materials at the western entrance to the site. There
are also two or three former tank cradle areas. Cradle Area 1
cons~sted of 6 concrete cradles for large tanks of 15,000 to 20,000
galldns each and four cradles for smaller 4,000 to 6,000 gallon
tanksl underlain by a concrete slab measuring approximately 60 by 80
feet.\ A 15-inch concrete containment wall surrounded the slab.
One large intact tank (estimated capacity, 15,000 gallons) which
appeared to be empty was lying across the containment wall half in I . and out of the containment area. At Cradle Area 2, 100 yards
southkast of Cradle Area 1, balls and layers of pine resin were
evideht on the concrete and land surfaces. There were 6 cradles
for ,;imaller tanks, but no tanks were evident. Metal scrap,
proba!Jly from some type of distillation un.it, was also noted· in I • Cradle Area 2 (3). .
I The former chip staging area is a large open. sparsely
vegetated field running from southwest to northeast covered to this
day wtth a layer of pine chips. It is approximately 500 to 600
feet long and 50 to 100 feet wide. At the southwest erid was a
concrJte bunker-like structure that reportedly contained stump
grindJrs. At the northeast end were two brick-lined furnaces. In
the Chip Staging Area we noted that there are piles and layers of
pine chips lying on the land surface and there is little or no
vegeta:tion in the area. At about the midpoint of the Chip Staging
Area hre two small. impoundments to the southeast. Brownish
leachdte seeps from the chip area were seen and photographed
enterilng this impoundment. At the northeast end of the Chip
Stagin'g Area was a horseshoe shaped impoundment referred to in the
Law En'vironmental Liability Assessment as the Settling Pond. To
the ea~t of this area was another chip storage area referred to on
Figure! 1 as the Sluice Area. It was evidently used for
storage/disposal of spent, extracted chips. As with the Chip
Staging Area, the Sluice Area .was cleared, sparsely vegetated, and
contained layers of spent pine chips. The area was poorly drained
and· cohtained numerous puddles from recent rains ( J) .
Ai noted on Figure 1 a drum disposal area is located in the
center\of the site. It contains a dozen or more half buried drums
proj ec1;:ing out of the ground ( 3) . Law Environmental reported
observing 40 drums in this location during the 1989 Liability I .Assessment ( 2) .
I The former water · supply well shown on Figure 2 is non
·operat~onal. A large pump remains that had once pulled water from
a 4-inch steel casing, but it is in obvious disrepair and is no
longer !connected to the casing. [For future reference it would be
difficult to sample this well because an elbow must be removed from
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the casing to be able to fit a bailer in the well.] A NC DEM observation well is reportedly located in the southwest corner of the kite (2)·. It was sampled and was found to contain volatile orgaQics during Law Environmental' s Liability Assessment. However, due to dense vegetation this well could not be located. A 4-foot section of what appeared to be 4-inch ·casing was lying on the groutid in the area where this observation well was reportedly located. Therefore, it is possible that this well has been dismantled (3).
Site History
The site was owned and operated by Reasor Chemical from 1959 through 1972 as a stump rendering facility that produced pitch turp~ntine, tall oil, camphor, and other pine products. In 1972 the slite was purchased by the Martin Marietta Corporation. Martin Mari~tta reportedly let the site sit idle the its entire period of owner1ship. Hilda Cameron and Jane Sullivan· purchased the property in 1~86. The Cameron Company (1201 Glen Meade Road, P.O. Box 3649,1 Wilmington, NC 28406, (919)762'-2676) manages the site (2).
The plant was obviously dismantled and sold for scrap at some point!, because the steel structures have been cut from the ground and removed from the site. The only notable steel remaining on the site is the one tank in Cradle Area 1. It is not known when the plantlwas dismantled. However, the Cameron Company indicates it was before Hilda Cameron and Jane Sullivan purchased the property in 1986 (3).
I . A Law Environmental Liability Assessment, for a potential buyerJ of the property, was conducted on the site in 1989. Analytical data show there are contaminated soils, surface impoutidments, and groundwater on the site (2). On July 15 and 16, 1991, !Mary Ganley and Bruce Nicholson of the NC Superfund Section conducted a reconnaissance of the site. Mr. Jabe Hardee of the Camerdn Company was present during the reconnaissance (3). On July 115, prior to visiting the site, 1990 aerial photographs of the .site .!trea were. obtained at the New Hanover County Land Records Offic~, 320 Chestnut Street, Wilmington, NC 28401, [phone]. I .·
Hazardous Substances
I The Law Environmental samples were only analyzed for benzene, toluen1e, xylene, acetone, phenols, and toxpahene. All of these I I ' ' ' compounds were found on site except for toxaphene (2). It 1.s also likely! that higher organics consistent with turpentine production such as pinene, diturpene, and other turpenes are present as well. I Laboratory Data
Rlsults of soil and surface water samples taken during the Law Envirohmental Liability Assessment are shown in Table 1 below. I Samples were only analyzed for benzene,toluene, xylene, acetone,
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phenol, and toxaphene. Note, the sampling locations are denoted on
Figure 1. The results show that the most highly contaminated areas
are the impoundments which could be contributing to groundwater
contamination. Note t·hat the observation well contains benzene,
toluene, xylene, and phenol which confirms an observed release to I the groundwater.
Table 1. \Groundwater and Soil Analyses From Law Environmental Uability Assessment, ug/Kg soil or ug/I water (2)
Sample Sample Sample
Location ~ Description benzene toluene xylene ~ phenol toxaphene
soil Cradle Area 1 <5 18.2 92.9 108 NA NA
2 sediment Drained Pond 909 10,000 11,000 5,600 NA NA
3 soil Sluice Area <5 <5 <5 125 NA NA
4 sediment Small Pond 1 41.7 5,550 <2 3.7 175,000 NA
5 sediment Small Pond 2 390 90,000 25 <500 83,000 NA
6 soil Drum Area . <5 <5 <5 133 5,120 <500
7 sediment Settling Pond <5 <5 <5 117 903 <200
8 groundwater Observation Well 3.6 11 18.9 <10 18 <1
Ground .Water Pathway I . . .
The site is in the Coastal Plain Physiographic Province of
_NorthlCarolina. Basement metamorphic rocks lie about 1,100 feet
below land surface in the area of the site. Above these rocks lie
sedimentary rocks of cretaceous to recent age that comprise the
predo~inant aquifers in the area. The three major aquifers are the
surficial water table aquifer, the tertiary limestone aquifer, and
the cretaceous aquifer. _. .The surf icial aquifer, consisting of
surficial sands and shell beds, is the main domestic supply
• -aquifJr. Beneath a confining layer lies the Castle.Hayne Limestone
.. which I serves as the tertiary limestone aquifer. The Cretaceous
.· aquifer lies·deeper, about 800 to 900 feet in the site area. It is
gener~lly not used for domestic supplies because of its depth and
it cohtains high chloride levels compared'. to the two upper
· aqi.life'rs. , However, this lower cretaceous unit is also generally
• artesi1an, and in the site area has a piezometric surface of 90 or ' more feet above sea level (4).
I
·iic•.,'•:•-;, · Tpere are very few wells in the immediate site vicinity. The
· nearest is directly across Highway 132 from the site at the
I ..;,r--.Dickerkon Carolina asphalt plant. There are two wells at this
· ·,•• ..... · facility, one of which is no longer used. The second well supplies
_:. drinkihg water to approximately 18 workers who are at the facility I' -.jt;-8 hours per day ( 5, 6) . Carolina-Dickerson estimated the well to be
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facility, one of which is no longer used. The second well supplies drink'.ing water to approximately 18 workers who are at the facility 8 hours per day (5,6). Carolina-Dickerson estimated the well to be 50 tol 60 feet deep, and it has a 26 gallon per minute yield. No water is used in the production process so that this well is pumped only for domestic potable use and for a steam genny for equipment cleanup (5,6). Additional areas likely for wells were identified on th1e aerial .photographs of the site. However, none of these areas I is within a quarter mile of the site. Residences were checked in these areas both to the north and south of the site and well houses were noted.
I Water for domestic use is supplied exclusively by groundwater. Most individualB in the area are on private wells and there are a few community supplies. An accurate house count is possible from the 19
190 aerial photograph from the New Hanover County Land Records Office (included as Map 2). This was used to estimate total popul~tion and ground water targets within 0.5 miies of the site. Beyond this distance, the PCGEMS census data program was used because of the· age of the topographic maps. The resulting estimated ground water target population is the same as the total popula,tion estimate. A summary of this estimate is shown in Table 2 belo(.
Table 2. Groundwater Target Population (and Total Population) For Reasor Chemical Site (1,12).
I .
Ring Cumulative I . Annulus, ml Population Population
j --
2cf 0.0 -0.25 20 I
328' 0.25-0.50 348 ' 0.50-1.0 1,563 1,911 ' 1.0 -2.0 1,263 3,174
2.b -3.o 1,289 4,463 ' 3.0 -4.0 58 4,521 I
' lhcludes 18 employees of Dickerson-Carolina and 1 residence (5,6,7).
b lr,cludes 135 residences counted on 1990 aerial photograph (7); based on 1990
Gensus data of 2.43 residents per household (8).
Tje annual precipitation for the Castle Hayne area is 56 inches.,! and the annual evaporation rate is 42 inches; therefore, the ann
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ual ,net precipitation is 14 inches (9) •
. surface Water Pathway .
I . 1 . . The sites opes gently from the northwest to the southeast. The northwest corner of the site lies at an elevation of 20 feet
I . .• __ · and the southeast corner lies at 10 feet.· From the southeast edge .~ of the site there flows a well defined drainage ditch. rt is .,A_.:·.· .. important to note that the impoundment that lies along the chip "J'JII''· staging! area may be bermed to the edge of this ditch. The ditch I flows 700 feet to Prince George Creek. Prince George creek flows ! .
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westward for 6,0 miles and enters the Northeast Cape Fear River. The ~ortheast Cape Fear flows 12.9 miles before it reaches the emergency water inta.ke for the city of Wilmington. Therefore, this intake is 18.9 stream miles from the site and is outside the 15-stre!i.m mile target distance limit. However, from a point 2. 9 stre.l.m-miles from the point of entry, both l'rince George Creek and the Northeast Cape Fear flow exclusively through estuarial I wetlands ( 1) .
\Prince George Creek and the Northeast Cape Fear River are Class "C" surface water bodies throughout the 15 stream-mile target distclnce limit. They are suitable for fish propagation and secoridary recreation but .not for water supply. Immediately after the 115 stream-mile limit, the Northeast Cape Fear changes to Class "SC" \..rhich is a tidal salt water suitable for fish propagation and I ' . secondary recreation (10). . I
On site Exposure Pathway
~he site itself is in an otherwise lightly developed wooded area.\ The dirt road entering the_ site -from Highway 132 has a locked fence to restrict access. However, there are no fences to restrtct access by foot. There are no residents within 200 feet of the site (7). The only other facility or development within 0.25 miles. I of the site is the Dickerson-Carolina asphalt plant which lies on Highway 132, approximately 800 feet from the site . The site 'is about o. 75 miles south of the town of Castle Hayne, population 1,182. The population distribution around the site was estimated using a house count from the 199 o aerial photo ( for withi~ 0.50 miles of the site) and the PCGEMS Census program (for outside-0.50 ~iles-from the site) (7,12). · As shown in Table 2 above,[ there are an estimated 20 residents within 0.25 miles of the site and 348 residents within 0.5 miles of the site.
Recommbndation
Rksidual contaminants from the operation of the Reasor Chemic!i.l stump rendering facility are in site soils and surface impoundments. These contaminants may be acting as a source for I • • ' surface water and groundwater contamination. There may also be
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·unknowri chemicals in the drums found on site. Therefore, the NC Superfund Section recommends that a Screening Site Investigation be • I ' .conducted in the near future.
I If you have any questions concerning this site please contact me at [phone].
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1'.1~-i .·• attachm~nts
BIN/rep;;'reaspa
;c:yitll-
Bruce ·Nicholson
Chemical Engineer
Superfund Section
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3.
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REFERENCES
United States Geological Survey Topographic Maps (7.5 minute
series).· castle Hayne, 1970; Rocky Point, 1970, Scotts Hill,
1970; and Mooretown, 1970.
Preliminary Environmental Liability Assessment. Law
Environmental, Inc. Wilmington, NC. April 6, 1991.
Memorandum. Bruce Nicholson, NC Superfund Section, to Reasor
Chemical Site File. Preliminary Assessment Reconnaissance;
July 23, 1991.
A Preliminary Report on Anomalous Pressures in Deep Artesian
~quifers in Southeastern North Carolina (Report of
:Investigation No. 10). North Carolina Department of Natural
~nd Economic Resources, Raleigh, NC. August 1975. . I . . . .
Telecon. _Bruce Nicholson, NC Superfund Section, with Fred
Cox, Carolina-Dickerson. Information About Carolina-
Dickerson' s Wells. July 17, 1991. I Field Notes. Bruce Nicholson, NC Superfund Section, during
Preliminary Assessment On-Site Reconnaissance, July 15, 1991.
I . . Aerial Photograph. New Hanover County Land Records Office,
Wilmington, NC. 1990. . I . . .
Memorandum. Pat DeRosa, CERCLA Branch Head, to NC Superfund
Section Staff. U.S. Census Bureau 1990 Population Data. June is, 1990. ·
I . . . North Carolina Atlas, Portrait of a Changing Southern State .
University of North Carolina Press. 1975.
Jlassifications and Water Quality Standards Assigned to the
Waters of the Cape Fear River Basin. NC Department of Natural
Resources and Community Development, Division of Environmental
Management. September 1, 1981, as amended February 1, 1986. I BICGEMS Census Data Program. Computer Program Run April 26,
1991. Census Data Surrounding the Reasor Chemical Site.
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Ref 17
Reasor Chemical
NCD 986 187 094
Castle Hayne, New Hanover Co., NC
KIRK-OTHMER
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ENCYCLOPEDIA Of
CHEMICAL TECHNOLOGY
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B
D A WILEY-INTERSCIENCE PUBLICATION
John •Wiley & Sons
THIRD EDITION
VOLUME 24
VITAMINS
TO
ZONE REFINING
NEW YORK • CHICHESTER • BRISBANE • TORONTO ,· SINGAPORE
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th;•· ;'f./."
Vol. 24 WOOD 601
There are a few minor wood-based chemical industries. After chestnut blight
wiped out the American chestnut, U.S. tannin production essentially ceased. The main
natural tannins, wattle and quebracho, are now imported. High U.S. labor costs and
the advent of synthetic tannins make re-establishment of a U.S. tannin industry un-
likely. Tannins and by-product lignins are used in oil-well drilling muds (see Petroleum
drilling fluids). Wax is isolated from Douglas fir bark. Tree exudates include rubber,
true carbohydrate gums (eg, acacia gum), kinos (eg, the phenolic exudates from eu-
calypts), balsams (eg, Storax from Liquidambar spp.), and many different types of
oleoresins (mixtures of a solid resin and a liquid essential oil). The most important
oleoresin in the United States is pine gum (rosin plus turpentine), although Canada
balsam is also well known.
Wood is the raw material of the naval stores industry. Naval stores, so named
because of their importance to the wooden ships of past centuries, consist of rosin
(diterpene resin acids), turpentine (monoterpene hydrocarbons), and associated
chemicals derived from pine (see Terpenoids). These were obtained by wounding the
tree to yield pine gum, but the high labor costs have substantially reduced this pro-
duction in the United States. More important has been the production of rosin and
turpentine obtained by the extraction of old pine stumps. This is a nonrenewable re-
source and this industry is in decline. The most important source of naval stores has
been the sulfate liquors from pulping pine. In 1979, U.S. production of rosin from all
sources was estimated at 320,000 metric tons and of turpentine at 74,000 metric tons.
Distillation of tall oil (qv) provides, in addition to rosin, nearly 200,000 metric tons
of tall oil fatty acids annually. In 1980, the value of naval stores primary products (rosin,
turpentine, tall oil fatty acids, and processing by-products) was over $300 X 106
(76).
··· 1· Hydrolysis
· 'r, . In the hydrolysis process (77-79), wood is treated with concentrated or dilute acid
~-(_)":· solution to produce a lignin rich residue and a liquor containing sugars, organic acids,
furfural, and other chemicals. The process is adaptable to all species and all forms of
wood waste. The liquor can be concentrated to a molasses for animal feed (80), used
· as a substrate for fermentation to ethanol or yeast (80), or dehydrated 'to furfural and
levulinic acid (81-84). Attempts have been made to obtain marketable products from
the lignin residue (85) rather than using it as a fuel, but currently only carbohy-
drate-derived products appear practical.
When concentrated acids are used, the carbohydrates are recovered in high yields,
but the problem of economically recovering the large quantities of acid used has not
been solved. At the present state of development, the dilute acid processes, especially
percolating and two-stage, appear more promising.· ·
A number of commercial plants using the Scholler percolation process (86) have
been built in Germany, Switzerland, and the USSR; only the USSR plants are still
in operation. In general, these plants were built to produce sugars for fermentation
to ethanol and yeast (qv). Except under special circumstances, however, such a process
has proved to be uneconomical. In the Scholler process, a hot dilute solution of sulfuric
acid is percolated through wood chips; the solubilized sugars are carried with the so-
lution withdrawn from the bottom of the digester. The acid concentration and tem-
perature of the charged solution are continuously increased; the more labile hemi-
22 TERPENOIDS 747
,, . Other methods for the synthesis of camphor exist but are not commercially im-
_:p~rtant. The 1981 price of the synthetic product is ca $4-6/kg (53).
re ~~0" Uses. Camphor is used chiefly as an ingredient in pharmaceutical preparations,
< ''•,as a moth repellent (see Repellents in Supplement Volume), a religious incense, and
.~·an odorant-flavorant in a variety of consumer products.
'· Pine Oil. Except for acet.ylation and. hydrogenation of a-terpineol-rich fractions
is0lated from it,, pine oil undergoes no important commercial reactions.
Manufacture and Price. There are three tvpes of pine oil: steam-distilled, sulfate,
and synthetic. Steam-distilled pine oil, a product of the wood naval-stores industry,
_:_,. is obtained by distillation of the extract from aged pine stumps in the southeastern
· United States. Sulfate pine oil is obtained by the fractionation of crude sulfate tur-
pentine. Synthetic pine oil is produced by the acid-catalyzed hydration of pinene,
usually a-pinene, followed by distillation. Mineral acids are commonly used in
strengths of 20-40 wt% and at ca 30-50°C. The hydration is carried out to produce
a maximum of alcohols and a minimum of hydrocarbons and cineoles by controlling
the reaction variables of time, temperature, and acid strength. The reaction proceeds
through carbonium ion mechanisms. Formation of the monocyclic products is depicted
below. Some of the reactions are reversible under the acid reaction conditions.
The chief oxygenated components of pine oils are a-terpineol, J'l-terpineol
[138-87-4), 1 -terpineol, a-fenchol, borneol, isoborneol, camphor, terpinen-1-ol, ter-
pinen-4-ol,clihydroterpineol [498-81-71, methyl chav,col [140-67-0], anethole 110T
4o: 1r,and 1,4::aiiaT]'-cineole. Not all of these components are present in all pine oils,
but all pine oils contai~pineol as the main oxygenated component. ln addition
to the oxygenated components, all pine oils contain amounts of p-menthadienes, the
most predominant ones being limonene (dipentene), terpinolene, and a-terpinene,
with smaller amounts of 2,4(8)-p-menthadiene and 1 -terpinene: small amounts of
pinene and cymene may also be present.
Many grades of pine oil are available commercially and differ according to the
source, the efficiency and type of distillation, and the way the various distillation cuts
are combined. A high grade synthetic pine oil has the composition shown in Table 4,
as determined by capillary gas chromatography.
Synthetic pine·oils usually have higher terpinolene contents than the other pine
oils, and only trace amounts of camphor are present. They contain no appreciable
. amounts of sesquiterpenes and do not contain anethole and methyl chavicol, which
-. are usually in the other types of pine oil. Steam-distilled pine oil is relatively high in
.,,· borneol and fenchol. Commercial pine oils are specified by physical properties and
by alcohol content, as determined by either ASTM D 802-57 or gas chromatography.
·,. · A pine oil, su~h as described above, typically has the properties listed in Table 5.
Lower grades of a-terpineol for odorant use can be obtained by distillation from
pine oil, but these always contain small amounts of borneol, 1 -terpineol, or both. High
grade perfumery a-terpineol is made by partial dehydration of terpin hydrate
[2451-01-6] under weakly acidic conditions (165). A substantial portion of a-terpineol
produced is converted to its acetate [80-26-2] or dihydro-a-terpineol and its acetate
which are also widely used in perfumery. U.S. production of synthetic pine oil in 1980
amounted to 20,000 tat an average price of $1.20/kg (53).
Uses. By far the largest use of pine oil is in the manufacture of cleaners and dis-
. infectants; it is effective against gram-negative enterobacteria but not against gram-
posi_tive organisms. Lower grades, eg, pine-oil sulfate, µre used as frothers in separating
Vol. 22
Table 4. Composition of Synthetic Pine Oil
Alcohols Wt%
a-and )'-terpineol 67.0
terpinene-1-ol 3.9
cis-/3-terpineol 2.8
isoborneo! 2.2
horneol 2.1
terpincne-4-ol 2.0
fenchol 1.9
t ra ns-{'3-terpineol 1.3
trace alcohols 2.5
Others
terpinolene
limonene
p -2.4 (8)-menthadiene
a-terpinene
1.8-cineole
camphor
1,4-cineole
r·-terpinen£'
p-cymene
TERPENOIDS
Table 5. Physical Properties of Synthetic Pine Oil
Property Value
specific grnvity (15.5/Ifi.5°C), min
t erpene alcohols0 , wt %, min
moisture, wt%, max
color (APHA)
refrncti\'e index, nff
acid number
Oash point. °C
Kauri hutnnul value
distillnt.ion rnnge, %
<195°C, max
<230°C, min
0 As measured by gas chromatog:rnphy.
0.930
Sfi
0.5
10
1.-l79-I .-139
<I
75
>500
5.0
_95.0
749
Wt.%
6.7
2.1
1.7
I.I
0.8
0.7
0.6
o.:J
0.3
minerals by notation. Some of the attributes of pine oil that make it useful in the
manufacture of glues and adhesives (qv) are its dispersive and solvent power, its surface
activity, and its preservation and plasticizing properties. Another use of pine oil is in
the textile industry as a penetrant, dispersing agent, wetting agent, and inhibitor of
bacterial growth in wet-processing of cotton, silk, rayon, and woolen goods. It. also is
used in the protective-coatings, agricultural-chemicals, 1,acking-house, and leather
industries· (see Disinfectants).
Terpene Resins. Large quantities ofterpene hydrocarbons are used in the man-
ufacture of terpene resins. The most commonly used terpenes are J3-pinene, a•pinene,
hmonene, or a combination of these. Other terpenes have been used, but to much less
extent. The cationic polymerization is typically accomplished by reaction in a solvent,
eg, toluene, and catalyzed by a Lewis acid, AlC13 being the. most commonly used. The
resins are thermoplastic and generally of light color (Gardner 2-5). Terpenes have
also been copolymerized with a variety of nonterpene monomers. The largest use of
terpene resins is in hot.-melt and pressure-sensitive adhesives, although other signif-
icant uses exist.
· ~ai:~~ s
750 TERPENOIDS
Sesquiterpenes
Sesquiterpene hydrocarbons contain 15 carbol:l atoms usually comprised of 3
isoprene units, although commonly these are rearranged. There are acyclic, monocyclic,
bicyclic, tricyclic, and tetracyclic sesquiterpenes. Their structures can be simple or
complex. lt has been estimated that at least 2000 sesquiterpenes and their derivatives
have been discovered in nature (166). Some of the technologically important sesqui-
terpenes and their sources are listed in Table 6.
Reactions. The two most important commercial reactions of sesquiterpenes are
esterification and oxidation to obtain aroma products; sesquiterpene acetates are
especially valued for this application. Acetylation of longifolene and hydroxylation
of caryophyllene yield products useful in perfumery.
An interesting anti ulcer drug, geranyl farnesyl acetate [51-77-4] (Gefarnate), has
been developed (167-170). A synthesis of this compound involves reaction of farnesyl
bromide [6874-67-5] with diethyl malonate to produce, after hydrolysis, farnesyl-
malonic acid [62088-08-8] which is decarboxylated to obtain farnesylacetic acid
[23224-49-9]. Esterification of the acid with geraniol gives geranyl farnesylacetate
(171). Heating nerolidol with digeranyl malonate [67779-10-6] in dimethylformamide
or dimethyl sulfoxide in the presence of aluminum isopropylate also produces Ge-
farnate (172). Other syntheses exist.
CH,
~ce,,, , cs,,oo,c,H,\ -
H,C CH, H,C
CH(CO,C,H,)
CH,
farnesyl bromide
CH,
'¾
H,C CH,
CH, 0
'¾
Gefarnat.e
(4 isomers)
farnesyhnalonic acid ester
l /. hydroly~is
2. dec11rbo~y!eiion_
)
O CH,
i:eraniol
CH,
H,C CH,
COOH
farnesylacetic acid
Manufacture. With a few exceptions, the limited number of commercially avail-
able sesquiterpenes have been isolated from natural sources, primarily essential oils
to which they impart characteristic organoleptic properties. Isolation is usually ac-
complished by extraction, fractionation, crystallization, or a combination thereof. In
general, the commercial products are not highly pure compounds unless they are
amenable to crystallization, eg, cedrol.
Th, IIWrnC,,e oo Ch• s,,Chois ,,d <rnosformaCl@s oC "'""""''""{fff 5
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Reasor Chemical
NCO 986 187 094
Castle Hayne, New Hanover Co,, NC
PULP AND PAPER MANUFACTURE
SECOND EDITION
vTOLUJ\tfE I
THE
PULPJNG
OF
WOOD
Prepared under the direction of the
JOl;\T TEXTBOOK CO~t}.!lTTEE OF T!IE PAPER INDUSTRY
RONALD C. MACDONALD, Editor
JOHN N. FRANKLIN, Technical Editor
~lcCRA\\'-HILL BOCH: COMPANY
NEW YORK ST. LOUl::i SAN FIIANCISCO LOJ',,'"DON
SYDNEY TOI\ONTO J\.IEXICO PANAMA
TABLE 2-6 EXTRACTIVE COMPO;,;EJ\'TS
Volatile with
steam
Soluble in
hot ether
Soluble in
hot alcohol
Soluble in
cold water
Hydrocarbons
Acids
Alclehydes
Alcohols
Fatty acids
Resin acids
Fats
Tannins Sugars
Salts
Sterols
Unsaponifiables
Coloring materials
Some water solubles
Phenolics
Cyclic alcohols
Low molecular weight
polysaccharides
serves such as fats and their esters are located in
the parenchyma cells, especially in the ray
cells. The terpenes and resin acids are found in
and around resin ducts in softwoods where
they are generated, especially when the wood
becomes heart\vood and the resin acids assume
a wood-preservation function. Many pheno-
lics found in heartwood of certain species are
toxic to fungi. Constituents soluble in water,
such as sugars, are found in the sapwood of the
tree. Hardwoods may contain considerable
resin materials in the vessels of the heartwood.
The high resin content of the Populus (aspen)
and Betula (birch) species is particularlv
troublesome in causing pitch problems in the
paper mill.
\Vood rays from some softwoods ma:·
contain about 20% extractives which, in the
case of sulphite pulping, are not dissolved.
Liberation of these resins and fatty acids dur-
ing fiber processing is a common source of the
sticky deposits ("pitch") in a sulphite plant.
Of the softwoods the pine species have an
especially high resin content. Tannins usually
are found in the bark, although some species
have significant amounts in the wood itself.
Mineral constituents are concentrated in
the middle larnella and primary wall of fibers,
although significant quantities are also found
throughout the secondary wall.
2-24 SUM11ARY OF EXTRANEOUS
COMPONENTS
A few brief comments, and examples of
the major classes of extraneous materials, are
presented below. \Vood is the source of an im-
portant group of chemicals, tefmed sild-
chemicals. Table 2-7 presents an excellent re-
view of the economics of• this group of
materials.
64
Volatile acids. These materials are gen-
erally toxic to fungi; they exist in the free form
or as esters. The most common example is
acetic acid, which results from the hydrolysis of
acetyl groups in wood during steaming or dur-
ing heating in water. A few species also yield
formic and butyric acids. An acid found in
western red cedar is discussed later in connec-
tion with digester corrosion. It is not general
practice to recover the volatile acids for com-
mercial purposes from the pulping processes,
although significant amounts of acetic acid and
formic acid are produced. The pyrolysis of
wood yields commercial quantities of acetic
acid, methanol, and charcoal.
Volatile oils. This complex group of sub-
stances is of considerable economic: value,
because it is the source of h1rpentine, pine oil,
and other chemicals. Softwood species such as
pines and cedars are particularly rich in this
fraction .. These are often termed "essential
oils," and they are made up of a mixture of
from a few to many components \.Vhich may be
separated by fractional distillation. Chemical
classes present include hydrocarbons, alcohols,
acids, ketones, and lactones. In softwood
species cyclic hydrocarbons of the composition
C10H16 (terpenes) are especially significant.
Upon oxidation the terpenes form products
such as camphor. Some of the more common
volatile oil components are depicted in Fig-
ure 2-18.
A number of isomers of terpenes related to
1-limonene have been isolated from wood. A
mixture of the two forms of lirnonene is
termed dipentene. The terpenes are suscept-
ible to isomerization, disproportionation, and
condensation reactions which make their stud_v
dif!icltlt.
Turpentine is essentiallv a mixture of a-j
and ~-pinene and is obtained bv four basic
i' !,
" 1: I
L-LIMONENE
I A MONOCYCLIC TERPENE,
C10H16 l
P-CYMENE
(SULPHITE "TURPENTINE")
~ ~
ALPHA-PINENE BETA-PINENE t:}-CARENE
COMPONENTS OF TURPENTINES
I Bl CYCLIC TERPENES)
Fig. 2-18 Some components of the steam-valatile
fraction of wond.
methods: ( l) fractional steam distillation of the
oleoresin ·which is obtained as an exudate from
wounded living southern pines (gum turpen-
tine), (2) solvent extraction of chips from old
pine stumps f-ollowed by steam stripping,
washing, and distillation to recover tur entine
woo turpentine), pine oil, and other terpene
fractions, (3) destmctive distillation of pine-
wood chips to yield turpentine, pine oil, tar
oils, pitch, clipentene, and charcoal, and (4) re-
cove1y of the volatiles from the kraft pulping of
softwoods by condensation of digester relief
gases followed by deodorization of the liquid
(sttlphate turpentine). The proportions of a-
and ,B-pinene vary with the isolation metl1od
and wood species.
As indicated in Table 2-7, the amount of
turpentine produced as a by-product of kraft
pulping exceeds that produced frc1m all other
sources combined. Most pul? mills .1:ell the
product ii: its cn1de form tt: ccntr~H::....ed refiner-
i~s which produce CG1nmcre:i::..: sulphate tur-
pentine by fr'lc .hmal c\lstillation. F roi:.~ IJ.5 to
10 6al of crnde turpentine is 0rnduced ~Jer tori
of pulp. depending upon the woocl ~i"'er:ies, :::.g:e-
of the wuod, ~~....-.cl pulping conditions. AC'cut 3
gal/ton yield of tL7. refined product is cc:::i-
siderccl go:1d.
All except about four pine species have
~)ineG:>. in their turpentine, but there is a wide
variation in the composition of this fraction
06
f~orn species to species. Other compounds pres-
ent include limonene, phellandren~, !::i. 3-caren~,
camphene, linear hydrocarbons, and oxidized
terpenes. A large amount of pine turpentine
pinenes is converted to synthetic pine oil,
pharmaceuticals. and other chemicals. Other
uses for turpentine include thinner for paints
and varnishes, synthetic resin manufacture,
and cleaning and polishing compounds.
Pine oil is recovered during fractional dis-
tillation of volatile oils or by the destmctive
distillation of wood in the process for rnanu-
fachuing wood turpentine; also, large amounts
of pine oil are made from turpentine. Turpen-
tine distills at below l 70°C and pine oil from
185 to 215°C. Pine oil consists largely ofter-
pene alcohols and ethers, terpenes such as
limonene, and ketOnes. It find:s Wide use as a
wetting, dispersing, and defoaming agent.
p-Cymenc is found in the condensate of
the relief vapors from the sulphite pulping of
spn1ces and firs. It is often referred to as sul-
phite turpentine. The material has not found
v:ide commercial use, but it h.as solvent prop-
erties. From 0.5 to 2.5 lb/ton of pttlp can be
recovered.
Dipcntene and rosin oil are terpene-re-
lated products present in the oleoresins from
pine species. Dipentene is obtained as a frac-
tion which is intermediate in boiling point
between turpentine and pine oil, whereas rosin
oil is obtained by the destrnctive distillation of
rosin. Another volatile oil compound, found in
very large proportion in digger and Jeffrey pine
oleoresin, is n-heptane. However, it is doubtful
that this source of gasoline will replace petro-
leum ! Other essential oils isolated from wood
include c.:edarwood oils, sassafras oil, rosewood
oil, camphor oil, and sandalwood oil. These arP
largely oxidation products of terpc11P .r:..lH~ed
materials.
Resin and fatty ;1ri~! jractions. The
broad te!'~ u:ord resins is applied to a class of
materials whl1.;b arl? s01uhli: ... l{~ne1c1 Hy in P.Lher
(ar,J/or, less con11i:2!•:_.-. i:• accicne an(l alco-
hol). Tiw major c:ompone11l!--in.::i .. ,de ri::,,:•:
acids, fatty acids, terpene and other estr~.~s. and
unsapornfiablcs (\vaxcs, stcrols, etc.). Th;-:re i;:
a wide variation in the composition and
amount of rr::sinlike material present in wood,
y,,ith the softwood species and the heartwood
r
.~ I I
I
OH
Fig. 2-20 Catechin.
of high molecular weight. The condensed tan-
nins, the group to which most of the natural
wood tannins belong, are considered to be
polymeric (;ondensation products o(the cate--
chins (Fig. 2-20) or leucoanthocyanidins,
which are similar. The tannins are largel~, solu-
ble in the lower alcohols b11t insoluble in ether
and benzene.
Very few species contain tannin as part of
the wood, although many species (e.g., western
hemlock, redwood. and oak) have bark which
is high in tannin content. Tannins are commer-
cially extracted with hot water from quebracho
heartwood (South Ameiica) and _wattle tree
bark (Africa). Chestnut wood was also a source
in the United States prior to the blight. The
bark of eastern hemlock has also been used in
tlle past. Tannins in wood consume chemical,;;
during pulping and bleaching and also may
contribute to color of pulps prior to bleaching.
Phenolics aside from the tannins are wide
in number when all wood species are con-
sidered; they determine the color and durabil-
ity of heartwood. TI1ey include pinosylvin, di-
hydroq1iercetin, and the thufaplicins \vhich are
discussed in a later section. The lignans are
formed by the condensation of two phenylpro-
pane units and are thus closely related to lignin.
One example of a lignan is conide11drin, which
has been isolated from sprnce and hemlock
sulphite pulping liquors and has been found to
have antioxidant and pharmaceutical potential.
Coloring substances of the flz.,10;1oid (C,.,C3C6
backbone) are present in many species Other·
types als0 exist si1ch as quinonD;: and leucc,--
c!.!1thoc)'anidins.
Inorganics. Most 'NOod specws cu11lni1·,
less than O :j~'.' •• 1iner::i.i matter ("ash"), c011si:.-:t-
ing mainly of cak.inrn, IJ'1lassiL11~1 , and mag-
nesium combiued as c.:arbe,,wtes, pl"!0;,;phates,
sulphates, oxalatcs, and silic..:\eS Jnd rnL;:ed
with carboxyl groups. A very large number 0f
trace elements exist. Many of them play key
roles in metabolism of the plant. TI1e ash con-
68
tent can cal1se problems in liquor recovery.
and in processing of pulps for rayon mannfac-
ture. Silica crystals in straw make pulping of
that material difficult. Discoloration reactions
of pulps are often caused by trace amounts of
iron and manganese. Acid treatment of pulp
is recommended for removal of metal impur-
ities from pulp.
Water-soluble extractives. Generally,
very small quantities of wood are soluble in
cold, neutral water. An exception is the ara-
hinogalactans of larch, which comprise up tci
20% of the wood (see Hemicelluloses). Small
amounts of sr,gars (sucrose, glucose, fn1ctose,
and arabinosc) and gli;cosides are also found
in the sapwood and inner bark of wood.
Pectins are essentially polymers of galac-
turonic acid, but they are not extractable with
usual neutral solvents. Cyclic alcohols known
~lS cyclitols are found in some spedes. Some
nitrogen is present in wood owing to protein
residues, .and in a few species alkaloids.are
present.
2-25 OTHER DY-PRODUCTS FROM WOOD
Several chemicals from wood (silvichem-
icals) have been discussed in the preceding
section. Other by-products based on wood (not
necessarily extraneous materials) should be re-
viewed here. Reference should be made to
Table 2-7 to evaluate the economics of the
products.
Sulphate (kraft) mill product,. Turpen-
tine and tall oil fatty resin acids have already
been cliscussecl. Dimethylsulphide and di-
methyl sulphoxicle are the major odoriferous
cornponents (along with hydrogen sulphide)
resulting from demethylation of lignin in the
kraft process. Tiie former is sold for makin;-
natn:·aJ ga.i; detectable l:•:; odor for safety !Jtir-
poses; the latter is se,1d as an excellent .':olve1~;
and is being in,,..~~igated for its ~~,,~,.rP.ntl,., :-~
,~--.8.:·h1l)l~ :n_P.dicinai'"" prfJpt1 ti .:.:s.
1
,
.5·.omt: 0~ thf! li~nin present in kraft blac.ii-
liqlior is rc.:.·; .. "ered. 't>· precipitation with car-
bon dioxide, fkration, a..-1d u~;.-\ng. It has been
used in plastic iJ.mi1,1te manufa-:.::ure, in as-
)· _~!t ~rr11!lsions, and a . .; a tanning extender,
plastics ~~xtender, and n:hber additive. How-
ever, almosi. ;;_!l the iignin in kraft black liquor
I
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Ref 19
Reasor Chemical
NCO 986 187 094
Castle Hayne, New Hanover Co., NC
Hawley's
Condensed Chemical
Dictionary
TWELFTH EDITION
Re\'ised by
Richard J. Lewis, Sr.
~VANNOSTRAND REINHOLD COMPANY ~ -------------New York
Copyright© 1993 by Van Nostrand Reinhold
Library of Congress Catalog Card Number 92-18951
ISBN 0-442-01131-8
All rights reserved. Certain portions of this work © I 930, 1920, 1919 by The Chemical Catalog Co., Inc., and
I 987, I 98 I, 1977, 1971, I 966, 1956, I 950 by Van Nostrand Reinhold. No part of this work covered by the copyright
hereon may be reproduced or used in any form or by any means-graphic, electronic, or mechanical. including pho-
tocopying, recording, taping, or informational storage and retrieval systems-without wrinen permission of the
publisher.
Printed in the United States of America
Published by Van Nostrand Reinhold
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16 15 14 13 12 II 10 9 8 7 6 5 4 J 2
Library of Congress Cataloging-in-Publication Dae a
Condensed chemical dictionary.
Hawley's condensed chemical dictionary .-12th ed./revised by
Richard J. Lewis, Sr.
p. cm.
ISBN 0-442-01131-8
l. Chemistry-Dictionaries. I, Hawley, Gessner Goodrich, 1905-1983
II. Lewis, Richard J., Sr. Ill. Title.
QD5.C5 1992
540' .3-dc20 92-18951
C!P
t
, , I' ,
CRAZING 322
bony! compounds containing an asymmetric
center. The diastereomer which is formed by ap-
proach of the reagent from the less hindered side
of the carbonyl group predomir1ates in the prod-
uct. The a-substituents are schematically repre-
sented as S (small), M (medium), and L (large).
crazing. Development of minute cracks in the
surface of a material, such as ceramic glaze, var-
nish, paint, etc., often as a result of exposure to
sunlight or weathering. ·
cream of tartar. See potassium biranrate.
crealine. (N-methyl-N-guanylglycine; (a-meth-
ylguanido)acetic acid).
HN:C(NH2)N(CH3)CH2COOH. A nitroge-
nous acid widely distributed in the muscular tis-
sue of the body.
Properties: (monohydrate) Prisms from water,
anhydrous at IOOC, decomposes 303C, slightly
soluble in water, insoluble in ether.
Source: Commercially isolated from meat ex-
tracts.
Grade: Technical, CP.
Use: Biochemical research.
creatinine. C~H 7N30. The anhydride of cre-
atine, a metabolic waste product.
Properties: Colorless co yellow liquid; d l .092
(25C); mp 5.5C; bp 220C; sligh1ly soluble in
water, alcohol, benzene, chloroform, ether, ace-
tic acid.
Creighton process. Electrochemical reduction of
sugars, e.g., reduction of glucose, xylose, and
galactosc to sorbitol, xylitol, and dulcitol.
creosote, coal-tar. (creosote oil; liquid pitch oil;
tar oil).
Properties: Yellowish to dark-green-brown, oily
liquid; clear at 38C or higher; napluhenic odor;
frequently contains substantial amounts of
naphtha!ene and anthracene; dis1illing range
200-400C; nash p 165F (74C) (CC). Soluble in
alcohol, benzene, and toluene; immiscible with
water. Autoign temperature 637F (335C), d
1.06-1.10.
Derivation: Fractional distillation of coal tar.
Method of purification: Rectification.
Grade: Technical, crude, refined.
Hazard: Toxic by inhalation of fumes, skin and
eye irritant. Use may be restricted.
Use: Wood preservative (ties. telephone poles,
marine pilings, ere.), disinfectants, fungicide,
biocide.
p~cresidine. See 5-methyl-o-anisidine.
"Creslan" (American Cyanamid). TM for an
acrylic fiber.
cresol. (methylphenol; hydroxymethylbenzene;
cresylic acid). CAS: 1319-77-3.
CH3C6H40H. A mixture of isomers obtained
from coal tar or petroleum.
Propenies: Colorless, yellowish, or pinkish liq-
uid; phenolic odor; d 1.030-1.047; wt/gal 8.66-
8.68 lb; nash p approximately 1 S0F (82C): mp
l l-35C; bp 191-203C. Soluble in alcohol, gly-
col, dilute alkalies, and water.
Derivation: Coal tar (from coke and gas works),
also from toluene by sulfonation or oxidation.
Grade: Various, depending on phenol content or
other properties. NF grade contains not more
than 5% phenol.
Hazard: Irritant, corrosive to skin and mucous
~embranes, absorbed via skin. TLV: 5 ppm in
air.
·use: Disinfectant, phenolic resins, tricresyl phos-
phate, ore flotation, textile scouring agem, or-
ganic intermediate, manufacture of salicy!alde-
hyde, coumarin, and herbicides, surfactant,
synthetic food flavors (para isomer only).
See also cresylic acids.
m-cresol. (m-cresylic acid; 3-methylphenol).
CAS: 108-39-4. CH1C6H,OH.
Properties: Colorless to yellowish liquid, phenol-
like odor. Soluble in alcohol ether, and chloro-
form; soluble in water. D l.034, mp 12C, bp
203C, wt/gal 8.66 lb, nash p 187F (86C), au-
toign temperature \038F (558C).
Derivation: By fractional distillation of crude
cresol (from coal tar), also svntheticallv.
Method of purification: Rectification. ·
Grade: Technical (95-980/o).
See cresol.
o-cresol. (o-cresylic acid; 2-methylphenol).
CAS: 95-48-7. CH3C6H,OH.
Properties: White crys\als, phenol-like odor. Sol-
uble in alcohol, ether, chloroform, and hot
water; d 1.047; mp 30.9C; nash p 178F (SIC);
autoign temperature 11 !OF (598C); bp 191C;
wt/gal 8.68 lb.
Derivation: (I) By fractional distillation of crude
cresol from coal tar. (2) Interaction of methanol
and phenol.
Method of purification: Crystals.
Grade: According to fp: 25, 29, 30, 30.5C, etc.
See cresol.
p-cresol. (p-cresylic acid; 4-methylphenol).
CAS: 106-44-5. CH3C6H,OH.
1
I
' ·=:
,:.
~ :-
·1 < ...
· 1·! . ~ ~,, :i
I . ·~~\
323
Properties: Crystalline mass, phenol-like odor: Soluble in alcohol, ether, chloroform and hot water. Wt/gal 8.67 lb, d 1.039, bp 202C, mp 35.25C, flash p 187E (86C), autoign tempera-ture !038F (558C).
Derivation: (I) By fractional distillation of crude cresol. (2) From benzene by the cumene process (see phenol).
Met hod of purification: Crysral!izacion. Grade: Technical, 98%, 99,00/o min purity or 34C min fp.
See creso!.
cresolphlhalein.
C6H,COOC(C,H3(OH)CH3)2. An acid-base indicator, changes from colorless to red between pH 8.2 and 9.8, reagent. See also indicator.
cresol purple.
C,H4SO,0C(C,H i(OH)CH 3)2• M-cresolsulfon-phthalein, an acid-base indicator, showing color change from red to yellow over the range pH 1.2-2.8 and from yellow to purple over the range pH 7.4-9.0.
See also indicator.
cresol red.
C6H,SO2OC(C6H3(OH)CH3)2• O-cresol-sulfonphrhalein, an acid-base indica-tor, changes from yellow to red between pH 7 .0 and 8.8.
See also indicator.
crcsotic acid. (cresotinic acid; hydroxytoluic acid). CH3C6H3(OH)COOH. Ten possible isomers; most common is 2-hydroxy-3-methylbenzoic acid, also known as o-cresotic acid or o-homosalicylic acid. The description which follows is of this isomer. Properties: White crystals or powder, mp J 66C, bp approximately 250C, partially soluble in hot water, soluble in alcohol and ether, combusti-ble.
Derivation: Treatment of o-cresol wirh caustic and carbon dioxide under pressure.
Use: Dye intermediate, research on plant growth inhibition.
m-cresyl acetate. (m-toly! acetate). CAS: 140-39-6. CH3C6H,OCOCH3 . Properties: Colorless, oily liquid; odor similar to phenol; bp approximately I 12C; distillation with steam; insoluble in water; soluble in com-mon organic solvents; combustible. Use: Medicine (antiseptic, fungicide).
o-cresyl acetale. . (o-tolyl acetate).
CH3COOC6H,CH3.
CRESYLIC ACIDS
Properties: Liquid, bp 208C. Nearly insoluble in cold water, soluble in hot water, soluble in or-ganic solvents, combustible.
Use: Flavoring.
p-cresyl acetale. (p-tolyl acetate). CH3C0H,COCH3• Properties: Colorless liquid, noral odor, soluble in 2.5 volumes of 70% alcohol, in most fixed oils, insoluble in glycerol, d 1.0532 (15C), opti-cal rotation (100 mm Hg) 0 degrees, refr index 1.500-1.504, acid value 0.7, ester value 341.6, combustible.
Grade: Technical, FCC.
Use: Perfumery, navoring.
cresyldigl)"'COI carbonate. (diethylene glycol-bis (cresy!carbonatc)). C20H220 7• Properties: Colorless liquid of low volatility, d 1.19 (20/4C), bp approximately 250C (2 mm Hg), nash p 475F (246C), refr index 1.523 (20C). Insoluble in water (very stable to hydrol-ysi~). Widely soluble in organic solvents. Com-patible with many resins and plastics. Combusti-ble.
Use: Plasticizer.
cresyldiphenyl phosphale. (cresyl phenyl phos-phate). (CH3C6H,)(C6HsJ,PO,. Probably sel-dom a pure compound, but a mixture of o-, m-, and p-cresyl and phenyl phosphates. Properties: Colorless, transparent liquid; very slight odor; insoluble in water; soluble in most organic solvents except glycerol; d l .20 (20/20C); fp -38C; boiling range 235-255C (4 mm Hg); nash p 450F (232C); combustible. Use: Plasticizer, extreme-pressure lubricant, hy-draulic nuids, gasoline additive, food packag-ing.
cresylic acids. Commercial mixtures of phenolic materials boiling above the cresol range. An ar-bitrarv standard in use for cresylic acids is that 50% ~ust boil above 204C. If the boiling point is less than 204C, the material is called cresol. Cresylic acid varies widely according to its source and boiling range.
A typical commercial cut, bp 220-250C. has the composition m-and p-cresols 0-1 OJo; 2,4-and 2,5-xylenols 0-3%; 2,3-and 3,5-xylenols 10-200/o; 3,4-xylenol 20-300/o; and C9 phenols 50-60%. Excellent electrical insulators. Derivation: Petroleum, coal-tar. Imported cre-sylic acid is derived from coal tar (gasworks), also made synthetically.
Hazard: Corrosive to skin, absorbed via skin. Use: Phosphate esters, phenolic resins, wire enamel solvent, plasticizers, gasoline additives, laminates, coating for magnet wire for small electric motors. Disinfectants, metal-cleaning compounds, phenolic resins, notation agents,
I
@!
o-ETHYLANILINE 480
in presence of sulfuric acid with subsequent dis-
tillation.
Hazard: Toxic by ingestion, inhalation. and skin
absorption.
Use: Organic synthesis.
o-crhylaniline. CAS: 5i8-54-l.
C6H,(NH,JC,H5.
Properties: Brown liquid. fp -44C, d 0.982
(20C), bp 214C, flash p (OC) 185F (85C), solu-
ble in alcohol and toluene, insoluble in water.
Combustible.
Use: Intermediate for pharmaceuticals, dye-
stuffs, pesticides, and other products.
ethyl anfhranilale. (ethy!-o-aminobenzoate).
CAS: 87-25-2. C6H,(NH,JCOOCH,CH3.
Properties: Colorless liquid, fruity odor. d 1.117,
refr index I .564, bp 260C, soluble in alcohol and
propylene glycol. Combustible.
Grade: Technical, FCC.
Use: Perfumery and flavors. similar to methyl
anthranilate.
2-elhylanthratiuinonc. C 1~HsO~C2 H!.
Properties: Buff to light yellow paste, mp !08C.
Use: Synthesis, especially of hydrogen peroxide.
"Eth)·I'' Antiknock Compounds [Ethy[J. Tl\·1
for a series of fuel additives containing various
percentages of tetraethyl lead, ethylene dibro-
mide, ethylene dichloride. dye, kerosene. and
antioxidant. All are used 10 improve the oc1ane
rating of motor fuels.
cfhvhirsenious oxide. C,H,AsO.
Pr.operties: Colorless oCJ; gar!i-:-!ike. nauseating
odor: oxidizes in air and forms colorless crys-
tals; soluble in acetone, benzene, ether: d ! .802
(11 CJ; bp l 58C ( JO mm Hg).
Hazard: Highly toxic.
Use: Organic synthesis.
2-elh)'laziridinc. Si:e ethylcthy!eneimine.
elhylhcnzenc. (phenylethane). CAS: !00-➔ 1-4.
C6H5C~H5• 20th highest-volume chemical pro-
duced in U.S. (199 I).
Properties: Colorless liquid, aromatic odor,
vapor heavier than air, bp 136. !87C, refr index
1.49594 (20C), d 0.867 (20C), fp -95C. bulk d
7.21 lb/gal (25C), nash p 59F (15C), autoign
temperature 810F (432C), specific hea! 0.41
cal/gal K, viscosity 0.64 cP (25C). Soluble in al-
coho!, ~enzene, c_arbon tetrachloride, and ether.
a!most msolub!e m water. •i:
f:?erivation: (l) By he~ting benze:1e and ethylene
m prese_nc_e o~ aluminum chlo.nde with subsc,:
quent distiliauon, (2) by fracuonation directJJ
f~o.m the mixed xylene stream in petroleum re.
fimng. 4':
Grade: Technical, pure, research.
Hazard: To:,:ic by ingestion, inhalation and skin
absorption; irrit_ant .to skin and eyes. Flamm.a. ·.
b!e, dangerous fire nsk. TLV: 100 ppm in air ,-Ji::r-;
Use: Intermediate in production of styrene, ~
vent.
4-ethylhenzenesulf onic acid. (p-ethylbenzenesu.i.:
fonic acid). CAS: 98-69-1. C,H,C6H,SO,H. _
Propemes: Sohd wHh mw 186.23, d 1.229, ·
p > l l0C.
Hazard: Corrosive.
ethyl henzoate. CAS: 93-89-0. C6H5CO,C.H'
Properties: Colorless aromatic liquid, soiub1c·•
alcohol and ether, insoluble in water, ct 1.0("!
1.046, fp -32.7C, bp 212.9C, refr index I.SOS
flash p 200F (93C). Combustible. ~•
Derivation: By heating ethanol and benzoic
in presence of sulfuric acid.
Grade: Technical, FCC. ~
Use: Flavoring, perfumery, solvent mixrure, lac~
quers, solvent for many cel!ulose derivatives and
natural and synthetic resins.
elhyl henzoylaCcrate. CAS: 94~02-0.
C6H,COCH,COOC,H5•
Properties: Light yc!low oil, bp 265C (d
poses), d 1.111-1.1 I 7 (20CJ, 0ash p 2751".
( I 35C), soluble in most organic solvents, insolu,;
ble in water. Combustible.
Derivation: Reaction of ethyl acetate and~
benzoate with metallic sodium. l·
fVlcthod of purification: Vacuum disti!la[ion. -~
Grade: 950Jo pure.
Use: Dye and pharmaceutical intermediate.
eth,yl-o-hem:oyl henloate.
C"H,COC,,H,COOC,H,. .
Properties: Yellowish-white solid; odorless;:.-
so!uble in water· soluble in alcohol. am ..
~thy] acetate, a~d benzene; mp 56-SBC;J.
325C. Combustible.
Use: Plasticizer for nitrocellulose and syn,
resins.
1-eth)·lbenzyl alcohol. (I-phenyl-I -prop
erhylphenylcarbinol). CAS: 93-54-9.
C9H"OH.
Properties: Oily liquid; bp 220C; d 0.
index 1.51; soluble in ethanol and m.;.:;
cohols, benzene, and toluene. ~,~,~
Derivation: Benzaldehyde or ph_enyl e~~y
Use: Heat-transfer f1uid. ·· ·
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1157 TOLUENE-2,4-DIISOCYANATE
through which the plasma moves. Surrounding
the torus is an electromagnetic field powerful
enough to confine the energized plasma suffi-
ciently to achieve the required density of 1014
particles/cc/sec and a temperature well above 44
million centigrade. Up to 74 million centigrade
has been obtained experimentally, but 100 mil-
lion centigrade will be necessary for power
production. The vacuum chamber and the mag-
netic field simulate conditions on the sun, i.e.,
absence of air and immense gravitational
forces.
Several experimental tokamaks are in opera-
tion in the U.S .. the largest being at Prince-
ton, NJ. It is utilizing hydrogen and deutur-
ium as a test plasma, and thus can attain
temperatures of only 100,000C. After further
experimentation and modification, it should
be capable of reaching the JOO million degrees
necessary for power production when tritium
is used.
See also fusion.
1olan. (diphenylacetylene). CAS: 501-65-5.
C6H5C:CC6H5.
Properties: Monoclinic crystals, inp 59-61 C, bp
300C, 170C (19 mm Hg), d 0.966 (I00/4C), in-
soluble in water, soluble in ether or hot alcohol.
Grade: Technical, purified.
Use: Organic synthesis, purified grade, primary
fluor or wavelength shifter in soluble scintilla-
tors.
o-tolidine. (3,3'-dimethylbenzidine; diaminodi-
tolyl)'. CAS: II 9-93-7.
[C6H3(CH3)NH2l,.
Properties: Glistening plates, white to reddish,
mp 129-lJlC, soluble in alcohol and ether,
sparingly soluble in water, affected by light.
Combustible.
Derivation: Reduction of o-nitrotoluene with
zinc dust and caustic soda and conversion of the
hydrazotoluene by boiling with hydrochloric
acid.
Grade: Technical, dry, or paste.
Use: Dyes, sensitive reagent for gold (1: 10 million
detectable) and for free chlorine in water, curing
agent for urethane resins (also available as the
dihydrochloride).
Tollens' reagent. Solution of ammoniacal silver
nitrate containing free sodium bicarbonate.
Use: To test for aldehydes.
tolnaftate. (USAN name for o-2-naphthyl-meta-
N-dimelhylthiocarbanilate). CAS: 2398-96-1.
C10H,OC(S)N(CH3)C6H4CH3•
Use: Antifungal treatment (medicine).
3-o-toloxy-1,2-propanediol. See mephenesin.
tolualdehdye. See tolyl aldehydes.
toluazotoluidine. See o-aminoazotoluene.
tolu balsam. See balsam.
toluene. (methylbenzene;phenylmethane).
CAS: 108-88-3. C6H5CH3 241h highest-vol-
ume chemical produced in U.S. (1991).
0
Properties: Colorless liquid, benzene-like odor, d
0.866 (20/4C), fp · -94.5C, bp 110.7C, refr
index l.497 (20C), aniline equivalent 15, flash p
(CC) 40F (4.4C), autoign temp 997F (536C).
Soluble in alcohol, benzene and ether; insoluble
in water.
Derivation: (I) By catalytic reforming of petro-
leum. (2) By fractional distillation of coal-tar
light oil.
Method of purification: Rectification.
Grade (usually defined in terms of boiling
ranges): Pure, commercial, straw-colored, nitra-
tion, scintillation, industrial. ,
Hazard: Flammable, dangerous fire risk. Explo-
sive limits in air 1.27-7%. Toxic by ingestion,
inhalation, and skin absorption. TLV: 100 ppm
in air.
Use: Aviation gasoline and high-octane blending
stock; benzene, phenol, and caprolactam; sol-
vent for paints and coatings, gums, resins, most
oils, rubber, vinyl organosols; diluent and thin-
ner in nitrocellulose lacquers; adhesive solvent
in plastic toys and model airplanes; chemicals
(benzoic acid, benzyl and benzoyl derivatives,
saccharin, medicines, dyes, perfumes); source of
toluenediisocyanates (polyurethane resins); ex-
plosives (TNT); toluene sulfonates (detergents);
scintillation counters.
toluene-2,4-diamine. (m-tolylenediamine; MTD;
m-toluylenediamine; diaminotoluene).
CAS: 95-80-7. CH3C6H3(NH2l,.
Properties: Colorless crystals; soluble in water,
alcohol, and ether; mp 99C; bp 280C.
Derivation: Reduction of m-dinitrotoluene with
iron and hydrochloric acid.
Hazard: A carcinogen.
Use: Chain extender and cross-linker, intermedi-
ate in organic synthesis of dyes, polymers, espe-
cially polyurethanes.
toluene-2,4-diisocyanate. (2,4-tolylene diisocya-
nate; m-tolylene diisocyanate; TDI).
CAS: 584-84-9. CH3C6H3(NCO)2•
nm &:XIC&C!El:..Jt!&l2J4#W!&Li&.;&&£§1
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TUNGSTEN STEEL 1194
Use: Oxidation-resistant coatings, electrical resis-
tance and refractory applications.
tungsten steel. In many of its alloying effects,
tungsten is similar to molybdenum. Tungsten in-
creases the density of alloys to which it is added.
Use: To obtain steels with great wear resistance
and special resistance to tempering, as in high-
speed steels, hot-work steels, finishing steels that
maintain keen cutting edge and great wear resis-
tance, creep-resisting steels, and oxidation-resis-
tant, high-temperature, high-sirength alloys.
tungsten trioxide. See tungstic oxide.
tungstic acid. (wolframic acid; orthotungstic
acid). CAS: 7783-03-1. H1WO,.
Properties: Yellow powder, d 5.5, insoluble in
water, soluble in hydrogen fluoride and alkalies.
A white form of tungstic acid exists, having the
formula H~W04·H20. This is formed by acidi-
fying tungsten solutions in the cold.
Derivation: Decomposition of sodium tungstate
with hot sulfuric acid.
Grade: Technical, CP, reagent.
Hazard: Toxic material. TL V (as W): 5 mg/m~ of
air.
Use: Textiles (mordant, color resist), plastics,
tungsten metal, wire, etc.
tungstic acid anh)·dride. See rnngstic oxide.
tungstic anhydride. See tungstic oxide.
tungslic oxide. (tungsric acid anhydride; tungsric
anhydride; tungsten trioxide; wolframic acid,
anhydrous}. WO~.
Properties: Canary-yellow, heavy powder, dark
orange when heated and regains original color
on cooling, mp l473C, d 7.16, insoluble in
water, soluble in caustic alkalies, soluble with
difficulty in acids. Non-combustible.
Derivation: Scheelite ore is treated with hydro-
chloric acid and the resulting product dissolved
out with· ammonia. The complex ammonium
tungstate can then be ignited to tungstic oxide.
Hazard: Toxic material. TLV (as W): 5 mg!m3 of
air.
Use: To form metal by reduction, alloys, prepa-
ration of tungstates for x-ray screens, fireproof-
ing fabrics, yellow pigment in ceramics.
tungstophosphate. Structure and properties are
similar to rnolybdophosphate.
12-tungstophosphoric acid. See phosphotungstic
acid. ·
tungstosilicate. One of a group of complex inor-
ganic compounds of high molecular· weight,
containing a central silicon atom surrounded by
tungsten oxide octahedra. They have high mo-
lecular weight, high degree of hydration, strong
oxidizing action in aqueous solutions; they de-
compose in strongly basic aqueous solutions to
give simple tungstate solutions; they form highly
colored anions or reaction products.
See silicotungstic acid and sodium-12-tungsto-
silicate.
12-tungstosilicic acid. See silicotungstic acid.
turkey brown. (turkey umber). Natural earth
used as permanent pigment. Contains iron and
manganese oxide with some clay.
Turkey red. See iron oxide red.
Turkey red oil. (castor oil, sulfonated; castor oil,
soluble). CAS: 72-48-0. It is also known as
alizarin assistant and alizarin oil because of its
use in dyeing with alizarin.
Properties: Viscous liquid, d 0.95, iodine no.
82.1, acid no. 174.3, saponification no. 189.3,
soluble in water, autoign temp 833F (445C).
Combustible.
Derivation: By sulfonating castor oil with sulfu-
ric acid and washing.
Grade: Sulfonated castor oil graded as to mois-
ture and color.
Use: Textiles, !eather, manufacture of soaps,
alizarin dye assistant, paper coatings.
Turn bull's Blue. An inorganic blue pigment
made bv the reaction of a ferrous salt and potas-
sium fe.rricyanide [Fe3fe(CN)6Ji. One of its im-
portant uses is in making blueprints, in which
sensitized paper containing ferric ammonium ci-
trate and potassium ferricyanide is exposed to
light, the ferric ions being thus reduced to fer-
rous ions.
See also Iron Blue.
turpentine (gum). The oleoresin or pltch ob-
tained from living pine trees. Sr icky, viscous,
balsamic liquid comprising a mixture of rosin
and turpentine oil; strong piny odor; soluble in
alcohol. ether, chloroform, and glacial acetic
acid. Combustible.
Use: Source of turpentine oil and gum rosin.
See also rosin.
turpentine (oil). CAS: 8006-64-2. C,0H16 A volatile esse11tia! oil whose chief constituents
are pinene and diterpene.
Derivation: Steam-distillation of the turpentine
gum exuded from living pine trees (gum turpen-
tine), or naphtha-extraction of pine stumps
(wood turpentine), destructive distillation of
pine wood.
See also rosin, rosin oil.
Properties: Colorless liquid, penetrating odor,
6)
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1195 "TYRILFOAM"
immiscible with water, lighter than water. Con-siderable variation appears in constants re-
ported; the following are based on tests made by the Forest Products Laboratory: d 0.860-0.875
(15C), refr index 1.463-1.483 (20C), flash p
(CC) 90-J !5F (32-46C) acidity none, bulk d 7. JS lb/gal, autoign temp 488F (253C).
Hazard: Moderate fire risk. Toxic by ingestion.
TL V: 100 ppm in air.
Use: Solvent; thinner for p"aints, varnishes, and
lacquers; rubber solvent and reclaiming agent;
insecticide; synthesis of camphor and menthol;
wax-based polishes; medicine (liniments); per-
fumery.
lutocaine hydrochloride. (;--dimethylamino--a,/3-
dimethylpropyl-p-aminobenzoate hydrochloride.)
CAS: 532-62-7. C,.H220 2N2•HCI.
Use: Local anesthetic.
luyere. A duct or pipe through which a stream of
hot air is introduced into a blast furnace or cu-
pola to support combustion.
Tw. Abbreviation for Twaddcll, used in report-
ing specific gravities for densities greater than
water, as degrees Tw. A Twaddell reading, mul-tiplied by five and added to 1000, gives specific
gravity with reference to water as 1000.
twinning axis. Axis around which one part of a
twin cryslal may be viewe~ as having been ro-
tated 180° relative to the other part.
Twilchell process. Commercial process for split-
ting fats to glycerol and fatty acids by heating
the sulfuric acid-washed fat 20-48 hours in an
open rank with steam in a mixture of 25-500"/o
water, 0.5% sulfuric acid, and 0.75-1.25%
Twitchell reagent. The original Twitchell cata-
lyst was prepared by sulfonation of a mixture of
fany acid and benzene, but nowadays sulfo-
nated petroleum products are used.
Twitchell reagent. Catalyst for the Twitchell pro-
cess (acid hydrolysis of fats). It is a sulfonated
addition product of naphthalene and oleic acid,
a naphth'alenestearosulfonic acid.
"Tygon." TM for a series of vinyl compounds
used as linings, coatings, adhesives, tubing, and
extruded shapes applied to chemical process
equipment as corrosion protection.
"Tylac" rReichhold J. TM for a series of syn-
thetic latexes and elastomers.
BL High-strength, film-forming, nitrile rubber
latexes and rubbers and carboxylated polymers
characterized by exceptional oil, solvent,· and
abrasion resistance.
SBL Butadiene/styrene and carboxylated bu-
tadiene/styrene and high-styrene latexes of vari-
ous monomer ratios. Modified versions avail-
able.
Use: Paper, textiles, adhesives, Portland cement,
molded products, polyvinyl chloride and pheno-
lic resin blends.
"Tylenol" {McNeil]. TM for p-acetylamino-
phenol (acetaminophen).
tyloxapol. (USAN). CAS: 25301-02-4. An
oxyethylated-tcrt-octylphenolpolymethylene
polymer and low toxicity, non-ionic surfactant.
1yloxin. Antibiotic substance isolated from a
strain of Srrepromycesjradiae.
Properties: Crystals, mp 128-130C, solutions are
stable between pH 4-9.
Use: Veterinary medicine.
Tyndall effect. A colloidal phenomenon in
which particles too small to be resolved in an op-
tical microscope suspended in a gas or liquid re-
veal their presence by scattering a beam of light
as i_t passes through the suspension. the extent of
reflection being dependent on the position of the
irregularly shaped particles relative to the inci-
dent light. The effect causes the appearance of a
visible cone of light through the suspension.
This principle is utilized in the ultra•microscope.
"Tynex" IDu Ponti. TM for nylon filament.
Available tapered with an essentially uniform
taper from butt to tip, and also level, i.e., in a
wide range of constant diameters. The tapered
form is used primarily in paint brushes, the level
form in other brushes.
type metal. Alloy of 75-95% lead, 2.5-18% an-
timony, with a little tin and sometimes copper,
which expands slightly upon solidification and
produces sharp castings.
Tyr. Abbreviation for tyrosine.
Tyrer sulfonation process. Sulfonation of ben-
zene in the vapor phase with sulfuric acid at l 70-
180C with passage of benzene vapor and
azeotropic removal of the water of reaction.
"Tyrez" (Reichhold]. TM for a series of impact
modifiers for plastics.
"Tyril" IDowJ. TM for a group of st)'rene-acry-
lonitrile copolymers.
"T~'rilfoam" 80 (Dow). TM for expanded
styreneacrylonitrile for notation uses under con-
ditions of gasoline spillage, petroleum scum
from outboard motors, and stagnant water.
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1235 XYLENOL
molecules, cancer therapy, diagnostic medicine,
nondestructive testing of metals, identification
of original paintings, preservation of foods.
See also radiation, ionizing, diffraction, Roent-
gen.
"Xydar." TM for liquid crystal polymer
glass/mineral combination product.
Use: In microwave cabinets, cookware, automo-
tive materials, and electronic components.
xylenes. (dimethylbenzene). CAS: 1330-20-7.
C6HiCH3)i. A commercial mixture of the
three isomers, o-, m-, and p-xylene. The last two
predominate. 26th highest-volume chemical
produced in U.S. (1991) (all grades).
Properties: Clear liquid, soluble in alcohol and
ether, insoluble in water, ct about 0.86. See
under Grade for boiling range; flash p (TOC)
from 8 I-I I 5F (27.2-46. IC).
Derivation: (I) Fractional distillation from petro-
leum (90%), coal tar or coal gas, (2) by catalytic
reforming from petroleum, followed by separa-
tion of p-xylene by continuous crystallization,
(3) from toluene by transalkylation.
Grade: Nitration (bp range 137.2-140.SC), 4 de-
grees (bp range 138-134C), 5 degrees (bp range
137-142C, high in m-isomer), 10 degrees (bp
range 135-145C), industrial (bp 9011/o 40C, com-
plete 160C). Also other grades depending upon
use. In some cases, one or another of the indus-
trial isomers is partially removed for use in
chemical production.
Hazard: Flammable, moderate fire risk. Toxic by
ingestion and inhalation. TLY: 100 ppm in air.
Use: Aviation gasoline; protective coatings; sol-
vent for alkyd resins, lacquers, enamels, rubber
cements; synthesis of organic chemicals.
See also following entries.
m-xylene. (1,3-dimethylbenzene).
CAS: IOS-38-3. I ,3-C6H.(CH3),.
Properties: Clear, colorless liquid; soluble in al-
cohol and ether; insoluble in water. D 0.8684
(15C), fp -47.4C, bp 138.SC, refr index 1.4973
(20C), nash p 85F (29.4C), autoign temp 982F
(527. 7C),
Derivation: Selective crystallization or solvent ex-
traction of m-, p-mixture.
Grade: 9511/o (technical), 9911/o, 99.90/o (research).
Hazard: Flammable, moderate fire risk. TLV:
100 ppm in air.
Use: Solvent; intermediate for dyes and organic
synthesis, especially isophthalic acid; insecti-
cides; aviation fuel.
o-xylene. (1,2-dimethylbenzene).
CAS: 95-47-6. 1,2-C6H4(CH3),.
Properties: Clear, colorless liquid; soluble in al-
cohol and ether; insoluble in water. D 0.880
(20/4C), fp -25C, bp 144C, refr index 1.505
(20C), nash p (TOC) 115F (46. IC), autoign
temp 867F (463.SC). Combustible.
Grade: 99%, free of hydrogen sulfide and sulfur
dioxide, technical 95 OJo, research 99 .9%.
Hazard: Moderate fire risk. TLV: 100 ppm in air.
Use: Manufacture ofphthalic anhydride, vitamin
and pharmaceutical syntheses, dyes, insecti-
cides, motor fuels.
p-xylene. (1,4-dimethylbenzene).
CAS: 106-42-3. I ,4-C6H.(CH3),. 28th high-
est-volume chemical produced in the U.S. (1991).
Properties: Colorless liquid, crystallizes at low
temperature, soluble in alcohol and ether, i_nsol-
uble in water, d 0.8611 (20C), mp 13.2C, bp
138.5C, refr index 1.5004 (21C), nash p (TOC)
81 F (27 .2C).
Derivation: Selective crystallization or solvent ex-
traction of m-, p-mixture; separation :'rom
mixed-xylene feedstocks by adsorption.
Hazard: Flammable, dangerous fire risk. TLV:
100 ppm in air.
Use: Synthesis of terephthalic acid for polyester
resins and fibers ("Dacron," "Mylar," "Ter-
ylene"), vitamin and pharmaceutical syntheses,
insecticides.
p-xylene-a,a'-diol. C6H4(CH20H)i.
Properties: White, crystalline solid; mp 11 SC; bp
138-144C (0.8-1.0 mm Hg). Slightly soluble in
water (25C).
Purity: 980"/o.
Use: Polyester resins.
xylenol. (dimethylphenol; hydroxydimethvlben-
zene; dimethylhydroxybenzene). •.
CAS: 1300-71-6. (CH3),C6H,OH. There are
Ref 20
Reasor Chemical
NCD 986 187 094
Castle Hayne, New Hanover Co., NC KNOW YOUR ENVIRONMENT
l'lllt .. \J>t'.l.MIJ.\
DIOXINS AND FURANS: WHERE THEY
COME FROM
by fodd Paddock,
Academy of Natural Sciences
July, 1989
Dioxins have caused a great deal of concern because they have been found in many places and are extremely toxic. Furans are similar chemicals and are often found with dioxins.
Dioxins and furans have never been manufactured deliberately, except in small amounts for research purposes. They are unintentionally created in two major ways: I) by the processes used to manufacture some products, for example, cenain pesticides, preservatives, disinfectants, and paper products; 2) when materials are burned at low temperatures, for example, cenain chemical products, leaded gasoline, plastic, paper, and wood.
Dioxins and furans from manufacturing
Dioxins can be inadvenently formed during the manufacture of a group of chemicals called chlorophenols, and the products made from them. Chlorophenols have been widely used to preserve wood, hides, te;.1iles, paints, glues, and other materials, as disinfectants, and to keep industrial cooling waters free of nuisance organisms. Some of these uses have been phased out.
A chlorophenol called 2,4,5-trichlorophenol is always contaminated with the most toxic kind of dioxin or furan, called 2,3, 7,8-TCDD. After 2,4,5-trichlorophenol was identified as a source of dioxins, manufacturers that used 2,4,5-trichlorophenol found ways to remove the contaminant from their products This often meant that the 2,3,7,8-TCDD was then concentrated in the wastes from such production.
Improper disposal of such waste resulted in the contamination of the town of Times Beach in Missouri, the Love Canal in New York, and other areas. Many highly contaminated sites remain where these wastes were handled, stored, or landfilled 2, 4, 5-trichlorophenol is no longer produced in the U. S
Other chlorophenols can contain dioxins and fi.irans. Pentachlorophenols, which are used to preserve wood, can contain relatively high levels of dioxins and fiirans, including many highly toxic kinds. Wood treatment facilities and sawmills have been significant sources of contamination, and wastes from their facilities are now treated as hazardous, or are proposed to be treated as such.
Polychlorinated biphenyls (PCBs) have been widely used as cooling fluids in electrical equipment and
01/27/97 1f-i"'12:22
""
UIUA•••--' '"''''-'' ,_,,,,-,.,~ -
some mdusLrJa1 cooiing systems. Suen iiuids are often a mixture of PCBs and other chemicals. PCBs can
contain low levels of furans, and the other chemicals can contain low levels of both dioxins and furans
Very large amounts of PCBs have been released to the environment. They are no longer manufactured in
the U.S., and are being removed from most uses.
Dioxins and furans were discovered in the waste products of some pulp and paper mills in 1985, after fish
downstream from the mills were found to contain low levels of2,3,7,8-TCDD. Since then; extremely
small amounts of dioxins and furans have been found in some paper products. The EPA and the paper
industry have been working together to understand the problem and reduce cir eliminate the amounts
inadvertently formed in the manufacture of paper. Presently, it is believed that a chlorine bleaching
process used at some paper mills is responsible for the creation of dioxins and furans
Dioxins and furans from burning
Many of the products and wastes that are contaminated with dioxins and furans will produce larger
amounts when burned. For example, when treated wood is eventually burned, the chlorophenols that burn
with it could be a widespread source of dioxins and furans. Also, wood treatment facilities often collect
waste pentachlorophenol in ponds, and in the past set fire to the ponds to reduce their volume. This
practice generated significant amounts of dioxins and furans.
PCBs can produce large amounts offurans when they are burned, and the chemicals that are often mixed
with PCBs for use in electrical equipment can produce dioxins. Fires involving transformers and
capacitors have contaminated buildings, power stations, locomotives, and other places with dioxins and
furans.
Polybrominated biphenyls (PBBs) are widely used as flame retardants in textiles, carpets, and plastics.
These materials are resistant to igniting but will burn in a building fire or incinerator. When they burn,
they can be a source of dioxins and furans.
Polyvinyl chloride (PVC) is a common plastic that can produce dioxins and furans when burned. PVC is
often present in municipal waste in large amounts, and is believed to contribute to the dioxins and furans
from incinerators.
Many sources of combustion produce dioxins and furans. Incinerators, both municipal and industrial, are
significant sources. Dioxins and furans have been found both in the incinerator ash and in the gases and
tiny particles escaping through stacks. Power plants, smelters, steel mills, and oil and wood stoves and
furnaces all emit dioxins and furans.
Greater amounts of dioxins and furans are produced when material is burned inefficiently and at low
temperatures. For example, the amounts of dioxins and furans formed during incineration can be reduced
by higher temperatures and more complete burning. Modern incinerators produce smaller amounts of
dioxins and furans than older ones, and new technology is expected to reduce the amounts even further.
Leaded gasolines, which contain chlorinated additives, produce very small amounts of dioxins and furans
when they are burned. Thus, autos may contribute significant amounts of dioxins and furans, especially in
urban areas. In the U.S. and much of Europe, the use of leaded fuel has declined dramatically in the past
decade and will continue to decline, thus reducing this source considerably.
Because dioxins and furans have been found in the chimneys of wood burning stoves, it has been
01/27/97 16:42
proposed that forest fires and other natural burning is responsible for a large amount of the dioxins and
furans present in our environment.
Cores drilled from the bottom of the Great Lakes and from a lake in Switzerland were analyzed for
dioxins and furans. Researchers can count the years in such cores, just as you can count the rings in a
tree. In the sediment cores from all lakes, they found almost undetectable amounts of dioxins and furans
before around 1940, a time they say corresponds to the large scale producticin·and incineration of
chlorinated aromatics. There are many sources of dioxins and furans. Some of them, such as the use of
chlorophenols, the incineration of waste, and other sources of combustion, ar°e widespread and numerous.
Others, such as contaminated manufacturing and waste sites, are few in number and usually local
problems. Reducing the creation and release of dioxins and furans will require attention to all these
sources.
This anicle is based on information contained in a Special Repon: Dioxins and Furans, published by the
Environmental Associates. Follow this link to learn more.
Offer feedback
Know Your Environment AI1icle lndex
Know Your Environment Homepage
Cop)·right (c) 1996 The Academy of Natural Sciences
Last Modified on Frida)', 01-Nov-96 09:46:24 EST
1900 Benjamin Franklin Parkway
Philadelphia, PA 19103-1195
215-299-)000
01/27/97 16:42
To:
From:
Date:
Re:
MEMORANDUM
File
Stuart F. Parker, Jr., Hydrogeologist
July 20, 1994
Reasor Chemical
NCO 986 187 094
Surface Water Pathway Definition
Ref. 21
Reasor Chemical
NCO 986 187 094
Castle Hayne, New Hanover Co., NC
SFP telephoned Ed Beck of the DEI-INR Water Quality Section to follow up on Bruce
Nicholson's 8/29/91 conversation. SFP asked about the limits of tidal flow reversal in the NE
Cape Fear River system. Again, he replied that on any given water body the 5-ft USGS contour
crossing was the best indicator of the upstream limit of such tidal influence.
Prince George Creek flows west to within 700 ft of the SE corner of the site, where SI
field observations indicate it receives runoff from the site via 3 intermittent stream channels
spaced within a few hundred feet along the creek's bordering cypress wetlands. The 3 entry points
at the edge of the wetlands, approximately 500 ft from the nearest identified contaminant source
are PPEs to the surface water pathway. The creek flows 5.5 miles to the NE Cape Fear River,
but crosses the 5-ft contour 1 mile from the site at US Route 117.
Like the lower creek, the NE Cape Fear River and lower sections of its other tributaries
undergo tidal reversal. Studies indicate the limit of saltwater intrusion to be located in the main
river channel approximately 6.5 miles upstream of where Prince George Creek enters the river
(Ref. 31, plate 1). The tributaries are assumed to be tidally-reversing up to 5 ft USGS altitude.
15-mile surface water pathway:
Using USGS data o,ef.25), SFP estimated flow conditions for the various segments of the
surface water pathway, as defined above. For each segment, the endpoint drainage areas (in
square miles) were averaged and the mean drainage multiplied by the local mean annual runoff
(MAR)(Ref. 26)and divided by a conversion factor (13 .58) to produce a segment mean annual
discharge (cfs). Wetland frontage was measured for each segment using National Wetland
Inventory Maps (Ref. 33).
(next page)
Segment Distance Drainage Area Flow Wetland
(mi) (sq. mi.) (cfs) Ei.::Qnt.ige *
(mi)
Non-tidal 0-1.0 9.25 13.6 1.9
Prince George
rl Creek
Tidal 1.0-5.5 13.7 20.2 7.6
'
Prince George
Creek
'
NECFR 5.5-15 1609 2370 19.0
(Downstream) ,. NE CFR 5.5-12 1603 2360 43.2
(Upstream)
ala * Includes both main channel and tidal tributaries. :. I -
August 29, 1991
· To :?,IB/;\asor :,.c::p'"mical., CCJmpaDY ,•si.t:'" File;
From: Bruce Nicholson~N
Subj: Telecons with Ed Beck, Water Quality Section, and Rick
Shiver, Groundwater Section Wilmington Regional Office,
NC Div. of Environmental Management, [phone].
I spoke with Mr. Beck concerning the surface water pathway and
obtained the following data:
In the area of the site both Prince George Creek and the
Northeast Cape Fear River are tidally influenced, that is both
have flow reversals with the tide. The tidal influence on
Prince George Creek extends to about the point where the 5-
foot contour crosses the creek. This would be at Highway
117/133 less than a mile downstream of the site.
Even above this point, flow in Prince George Creek is very low
because it is so flat and swampy.
NC DEM data from NPDES permit applications indicate that the
7Ql0 and 30Q2 flows in the creek near Castle Hayne are zero.
The U.S.G.S. average flow estimates range from 6.3 cubic feet
per second (cfs) to 15 cfs depending on the location in the
Castle Hayne area.
I spoke with Mr. Shiver about the reported DEM observation
well at the site. He said he thought at one time that DEM had been
monitoring that well and he is aware that Law Environmental sampled
it during the liability assessment. He said it has not been
dismantled to his knowledge, but that it would be difficult to find
unless it was winter. If we need to sample the well for the SSI,
he will help us find the well and also the well record.
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UNITED STATES·
DEPARTMENT OF THE INTERIOR
GEOLOGICAL SURVEY
DRAINAGE AREAS OF SELECTED SITES ON STREAMS IN NORTH CAROLINA
By Robert L. Meikle
Open-File Report 83-211
Prepared in cooperation with the
NORTH CAROLINA DEPARTMENT OF NATURAL
RESOURCES AND COMMUNITY DEVELOPMENT
Raleigh, North Carolina
19S3
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TRIB ~ Mil.!.. ,:;:,=fl'. " 3Lo0loL,£. 7B".:,:J58 FLNST□r~ o:'3 .;.21oc177·3~S SW,JN f'; AT MTH NR MlLL CRrEK ao 31,05•'.).:1 ;,10.:.:37 FUNST('1N 01 '? q •.)210i377·9s~1 >-ilCl\l""Atl r! AT M1H AT MILC CPC:Fr -'· ~" ao 3.:.oS'-'.' 780"i3U FUNSlQr-1 019 ,, 80 _i_ .. ,,,..:.;.·(.::~ '!!L_-·-
M
11mi MAP OF MEAN ANNUAL RUNOFF FOR THE
,8 . NORTHEASTERN, SOUTHEASTERN, AND
_-~.)MID-ATLANTIC UNITED STATES,. II WATER YEARS 1951-80
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By.· .
William R. Krug, Warren A. Gebert,.David J. Graczyk, U.S. Geological Survey; Donald L. Stevens, Jr., Eastern Oregon State College;
Barry P. Rochelle, Northrop Services, Inc.;
and M. Robbins Church, U.S. Environmental Protection Agency
. rJ U.S. GEOLOGICAL SURVEY
II Water-Resources Investigations Report 88-4094
Ill Prepared in cooperation with the
U.S. ENVIRONMENTAL PROTECTION AGENCY
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Madison, Wisconsin
1990
J sions that the methods that used the area-weighted
.iialverage of the _drainage ·area or the centroid of the
. wrainage area produced somewhat better correlations-
J ~that is,. the interecept was closer _to zero, the standard
. 2rrors were small, and tl1.e CC;rrelftion coefficients were
· 1arger. These methods have slightly greater power to
rl · -r~e!it~~~~~~;~~~ii:{i~~~~~i;ati~n-i~u~ct no significant
. differences in reliability of the runoff estimates among
_J _th_e areas. No significant differences existed in the errors
11
for stations with drainage areas of differing size.
~
~
~
USE OF MEAN ANNUAL RUNOFF MAP
Mean annual runoff for a site can be estimated from
the runoff map by several methods. The simplest
method of estimating the runoff is to locate the site on
the runoff map and to identify the runoff contour
nearest the site. This method, however, is less accurate
than other methods. The most accurate method is to
draw the drainage basin on the runoff map, and use the
runoff contours to divide the basin into bands of differ-
ing runoff. The area of each of the bands within the
drainage basin is then determined. The areas of the
separate bands are then used to compute a weighted
average runoff for the bas111. For example, if 50 percent
•
f the basin 1s 111 an area of 18 111/yr (inches per year) of
unoff, 30 percent 111 an area of 20 in/yrof runoff and 20
,ercent in an area of 22 in/yr of runoff the mean annual
· runoff would be calculated as follows:
0.5 xl8 + 0.3 X 20 + 0.2 X 22; 19.4
Runoff estimated from the map is in inches per
year, averaged over the entire drainage basin. Multiply
this value by the drainage area, in square miles, and
divide by 13.58 to convert to mean annual discharge, in
cubic feet per second. In the above example, assume the
drainage area of the site is 100 mi'. The mean annual
discharge, in cubic feet per second, _1Yould be:-·•
19.4 xl00/13.58 ;143
The runoff map was prepared to allow estimation of
mean annual runoff at sites where no streamflow data
are available. The map represents mean annual runoff
for areas with natural land cover. Caution should be
used in applying the map to estimate runoff for areas
that are not natural land areas. The runoff map should
not be used for areas, such as large urban areas, where
the land cover has been altered in ways that would
change the amount of runoff. The runoff map is not
applicable for lakes or bays, for coastal wetlands affected
by tides, for streams controlled by reservoirs large enough
to· influence the total annual streamflow, or for streams
with substantial diversions.
Local features could cause the runoff at a particular
site to differ substantially from the runoff indicated by
the runoff map. The geology of the drainage basin
might cause substantial amounts of water to enter or
leave the basin as ground water. This could substan-
tially increase or decrease the runoff. For example, a
stream with a small drainage area that includes a large
spring probably would have higher average streamflow
than indicated by the runoff map.
Table 5.-Descriptive statistics of errors in estimated rnnoff
at 93 test stations
Method
Area-weighted
Centroid
GIS
Nearest-inch
Nearest contour
Area-weighted
/ Centroid
G!S
Nearest•inch
Nearest-contour
.__)
Mean
absolute
value
2.0
2.2
2.7
2.8
2.8
9.0
9.8
12.0
12.1
12.2
Mean
Error, in inches
-0.35
-.71
-1.74
-1.77
-1.79
Percent error
-0.54
-.71
-6.42
-6.20
-6.26
Standard
error of
mean
0.30
.33
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0 HEASOJ{ CliEMfCAL CO,
NCO 986 187 094
To:
From:
Date:
Re:
MEMORANDUM
File
Ref 22
Reasor Chemical
NCD 986 187 094
Castle Hayne, New Hanover Co., NC
Stuart F. Parker, Jr., Hydrogeologist
September 29, 1994
Reasor Chemical
NCD 986 187 094
Fisheries in the Study Area.
On 9/29/94, SFP telephoned Brad Hammers, Wilmington District
Fisheries Biologist (919-939-1167), and Fritz Rhode, of Marine
Fisheries (910-395-3900) for fisheries information on the Cape Fear
and Northeast Cape Fear Rivers in New Hanover County. According to
them, both the Cape Fear and Northeast Cape Fear Rivers are
recreationally and commercially fished for human consumption.
Species in the fisheries include american and hickory shad,
herring, atlantic and short-nosed sturgeon, resident and seasonal
striped bass, largemouth bass, redbreast, and flathead and blue
catfish. Additionally, the Cape Fear River is a nursery for blue
crab, eel, and shrimp.
&sor ~•7Y --- -
Subject: Reasor Chemical Company
Date: Wed, 04 Apr 2001 13: 10:27 -0400
-
From: [e-mail]
To: [e-mail]
-- -•
Could you check into this, as we just discussed? Thanks!
--
Forwarded by Samantha Urquhart-Foster/R4/USEPA/US on 04/04/2001 01:09
PM-----
--
MorleyPitCrew
[e-mail] To: Samantha Urquhart-Foster/R4/USEPA/US@EPA
l of l
03/26/2001
06:19 PM
cc:
Subject: Reasor Chemical Company
I am a concerned citizen of this area. I hope this will help expidite this
issue. This area constantly floods. We received 2 inches of rain ·1ast week
and it flooded all the way across the street. It also runs parallel to the
Cape Fear River. Which does serve as our source of drinking water. Most of
the people who live down there use wells for their drinking water. There
was
people out there fishing in the flooded area, by the road. Please try and
do
something about this. I told a friend that lives down there and she didn't
even know what a Superfund is. Someone could really get sick. I've lived
here for 15 years and didn't even know this place existed Thank you for
your
time in reading my mail. Sincerly, Katheryne Morley
[e-mail]
-- -• -
z
()
04/17/2001 10:40 AM
Ref. 23
Reasor Chemical
NCD 986 187 094 .
Castle Hayne, New Hanover Co., NC ,
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UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
REGION 4
ATLANTA FEDERAL CENTER
61 FORSYTH STREET
ATLANTA, GEORGIA 30303-8960
November 8, 2000
RECEIV~T'-
4WD-NSMB
NOV 132000
Ms. Jeanette Stanley
Site Evaluation Branch, Division of Solid Waste Management SUPERFUND ~1::c·i iU,
NCDENR
401 Oberlin Road .
Suite 150
Raleigh, NC 27605
SUBJECT: Field Logs
Remedial Investigation Repo11
Reasor Chemical Company Site, Castle Hayne, New Hanover County, NC
Dear Ms. Stanley:
Enclosed arc copies of the Field Log Books of David Nelson, WESTON, during the time
period of 1998 and 1999, which you previously requested. lfyou have any question, please call
me at [phone].
Enclosure
Samantha Urquha11-Fostcr
Remedial Project Manager
North Site Managemeni Branch
Internet Address (URL)• http:/Jwww.epa.gov
Recycled/Recyclable • Printed with Vegetable Oil Based Inks on Recycled Paper (Minimum 30% Postc_onsumer) .
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MEMO
DATE:
TO:
FROM:
RE:
April 30, 2001
File
Ref. 24
, Reasor Chemical
NCD 986 187 094
Castle Hayne, New Hanover Co., NC
Jeanette Stanley, Environmental Chemist,
NC Superfund
Reasor Chemical co.
NCD 986 187 094
Castle Hayne, New Hanover Co., NC
On April 25, 2001, I went on the Internet and searched for Glen M. Neubert, who was listed
as the president of Reasor Chemical Co. when it closed. This information was provided in Martin
Marietta's response to EPA in a 1996 letter, which was provided as Appendix A of the Remedial
Investigation Report on the Reasor Chemical Co. Site.
I found two telephone numbers listed under Glen M. Neubert, both in Dallas, Texas -(972)
387-4590 at Mcewen Rd. 75244 and [phone] at High Summit Dr. 75244. I called (972)
387-4590, and the lady who answered said that Glen M. Neubert was her father, but he passed away
on March 14, 1997. She stated that her father was the Glen M. Neubert listed as the president of
Reasor Chemical. Her grandfather, Gerald Reasor, founded Reasor Chemical Co. He passed away
in October 1969, and his son-in-law, Mr. Neubert, became the executor of his estate. Mr. Neubert's
daughter stated that she was familiar with the Superfund process. Another property in Columbia,
MS, formerly owned by Reasor Chemical had been purchased and subsequently operated by
Reichhold Chemicals. She said that activities conducted by Reichhold had contaminated the property
and that as a previous owner and operator, the remaining Reasor Chemical Co. assets had been
"wiped out". I checked NPL, and the Reichhold site in Columbia, MS is listed.
I also called Mr. Richard D. Foxworth, and attorney in Colombia, MS, on April 25, 2001 and
left a message. In the same above-mentioned report, he was listed as a principal of Reasor Real
Estate, a corporate successor to Reasor Chemical Co. Mr. Foxworth called me on April 26, 2001
and I asked if he knew anyone who had worked at either plant who could tell me the daily operations
· of the plant in North Carolina. He gave me the name of Leslie Alexander [phone], and I
called him. .Mr. Alexander, though now 82 year old, was at work, and I was asked to call him the
next morning.
I called Mr. Alexander on Friday, April 27, 2001. He said that he had worked at the
Mississippi plant from 1950 -1979. This plant was owned by Reasor Chemical Co. during part of
his employment. Mr. Alexander reported that he was the last person to leave the property in 1979.
He said that he never went to the North Carolina plant, and the people with whom he worked who
· had visited the NC plant (Mason Graham, Mr. Low, Odel Turnage) were all deceased.
I asked Mr. Alexander about facility practices, and he said that he thought the two plants
were similar. He said that the Mississippi plant, during its operation as Reasor Chemical Co.,
extracted pine stumps using solvents such as VM&P Naptha and toluene. He said that pine oil was
commonly found these sites. I asked Mr. Alexander if he thought that ponds were constructed at
North Carolina plant to receive wastes. He said that they probably were, but that he couldn't say for
sure since he had not visited the NC plant.
CD
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MEMO
TO:
FROM:
DATE:
SUBJECT:
File
Jeanette Stanley
Environmental Chemist
NC Superfund Section
May 31, 2001
Reasor Chemical
NCO 986 187 094
Castle Hayne, New Hanover Co., NC
On Friday, May 25, 2001, I talked with Earl Pickett, a former welder for Reasor Chemical
Co. and currently an employee of Martin Marietta Materials. Also on the telephone call was
Yvonne Bailey, attorney for Martin Marietta Materials. I had previously contacted Yvonne
Bailey and asked if she knew how to contact any former Reasor employees. (Ms. Bailey had
earlier provided a January 15, 1970 map which had been provided to her by a former employee.)
Ms. Bailey ([phone]) arranged for and placed this conference call.
Mr. Pickett stated that he worked for Reasor for about eight years, up until the plant
closed in 1969. He was a welder and worked primarily in.the pipe shop area. We discussed most
of the potential source areas shown on the Site map provided in Weston's RI report (dated
9/8/98) as well as features shown on January 15, 1970 site map and an 1978 aerial photograph of
the site. Mr. Pickett stated that the µ-shaped pond, labeled as "settling pond" on the 1998 map
and "lake" on the 1970 map was actually a cooling water pond for the boiler.
Mr. Pickett also stated that ·the area labeled as "Sluice Area" on the 1998 Weston map
was the area where left over chips were deposited after they had been extracted. He said that
Pond# 4 (on the Weston map), or the northernmost "Waste Lagoon" (on the I 970 map) was a
spill catch basin. He said that spills sometimes occurred, and the spill liquid would usually float
on top of the pond and the layer would then be "sucked oft". Mr. Pickett could not say for sure if
this pond was constructed for the purpose of handling waste. He was not knowledgeable about
the use of any other ponds on the site.
Mr. Pickett stated that naptha was used to extract the stumps. He said that product lines
were aboveground and water lines were below ground. He was not aware of any activities that
occurred in the laboratory, except to check product purity.
Mr. Pickett said that in his supervisor's office (Butch Barnhardt, the quarry manager), was
a very large 1966 aerial (drawing or photograph, can't remember which they said) of the Reasor
Chemical Co. Site. He offered to take a photograph of this aerial and send it to me, but I
declined. I was invited to come view this when I was in Wilmington, NC.
Ci)
lllili! EP'li:lion "i;lissii;:;;j'L s;a;rnm.a liliil liiiiil iili ----.,up:--.ep-regi-aste ... 1/np-.,ws ... htm •
l of2
• • ft Er)A UotodStm!s o rl'\ _ _,,,_ waste manageQ)ent
division D,eg·1ftn 4 sorwio me r\.; ,.. soutrieast
Newsom Brothers/Old Reichhold Chemicals
EPA ID: MSD980840045
Administrative Record Index: OU2, Deletion
Site Repository:
Columbia, Marion County, MS
Congressional District: 04
NPL Status: Proposed: 10/15/84; Final 06/10/86;
Deleted: 09/27/00
Project Manager
SOUTH MS REGIONAL LIBRARY
900 BROAD STREET
COLUMBUS MS 39429
Site Background: The 81-acre Newsom Brothers Site was used to produce wood derivatives such
as resin, turpentine, pine oil and tall oil. The process involved grinding pine stumps and digesting
them with a boiling liquor of sodium hydroxide and sodium sulfite. The site operated for almost
50 years. Reichhold Chemicals purchased the property and continued mixing pentachlorophenol
with diesel oil. An explosion and fire in one of the boiler units destroyed most of the processing
facility in 1977 and operations ceased. In 1984, EP A's initial investigation discovered 600 surface
drums, two contaminated on-site ponds and several areas of contaminated soil.
Cleanup Progress: Remediation Complete: Cleanup activities have been completed. After
EP A's initial investigation, EPA removed the drums and filled the two ponds. Cleanup actions
taken by Reichhold Chemicals, the responsible party, included: removal of asbestos-containing
materials; removal of above-ground and underground storage tanks; excavation of contaminated
soils; excavation of black tar-like waste material; drainage of on-site ponds; disposal of
contaminated sediments; and groundwater monitoring. During the final stages of the cleanup
action, a small area of potential groundwater contamination was identified in the vicinity of the
North Pond. Since groundwater contamination was not addressed initially, EPA began a second
site study. After completion of this study, EPA determined that no further action was required.
However, continued groundwater monitoring is being conducted at the site to confirm the
protectiveness of the selected remedy.
In FY97, a 3-year groundwater monitoring program began pursuant to the second EPA site study.
The most recent groundwater monitoring report, dated July 1998, continues to show no
contaminants at levels above groundwater protection standards. The last required monitoring
event for the site occurred in December 1999. The final groundwater report, submitted in early
2000, indicated that no threat to the environment or human health exists in the groundwater at the
site. A certificate of completion for this operable unit (OU2) was issued to the PRP on July 26,
2000. A delisting package was then prepared for the site.
The site was proposed for delisting in August 2000 by publication in the Federal Register for a
30-day public comment period. Only one comment was received and a Responsiveness Summary
was prepared. The Notice of Deletion was finalized and published in the Federal Register on
September 27, 2000.
04/26/200 l 10:09 AM
liiliil lillil ..,ttp,..,,.ep-regi-aste...,1/npaia,wsclllahtm • I EPA I REGION 41 HOME I SEARCH I COMMENT I
Opdatecf"November 2, 2000 •
URL: http://www.epa.gov/region4/waste/npl/nplms/newsomms.htm
2 of2 04/26/200 I I 0:09 AM
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Martin Marietta Materials Reasor Chemical
NCD 986 187 094
... 4
:;-;:,,.:.:,;•:;7::,::a: .... :--.::.: .. : ...... ::::: .... :::,:: .. :...,,:.:::::=::· :::..........-C==·,,. astlc Hayne, New Hanover Coy NC.~
Post Office Box 30013
Raleigh, North Carolina 27622-0013
Telephone [phone]
Fax [phone]
October 11, 1996 fB)lEtlE~WlE[Rl
·lru MAY 7 2001 lW Yvonne c. Bailey
Assistant General Counsel
Ms. Giezelle Bennett
U. S. Environmental Protection Agency
Waste Management Division SUPERFUND SECTION
I 00 Alabama Street, SW
Atlanta, GA 30303
Re: Reasor Chemical Company Site in Castle Hayne, New Hanover County, North
Carolina ( the Site) ·
Dear Ms. Bennett:
The purpose of this letter is to give you additional background information which may help your investigation of the above-referenced site. I believe this information will help the consultant
understand the plant layout and determine the best areas to test. The information I received was from a former employee of Reasor Chemical, and I will refer to the structures in the enclosed drawing and schedule of buildings prepared on January 15, 1970, which was previously submitted to you.
The wood rosin produced at the Site was obtained by extracting the rosin from pine stumps
with naphtha. The naphtha was stored in an aboveground tank by building 11, the Mill Room. The fuel bin between buildings 11 and 12 contained spent wood chips from which the rosin had already
been removed. The liqui_d product which was produced was piped around the facility above the ground. The finish tanks by the railroad tracks were used to hold the finished product which was pumped into railroad cars.
I strongly urge you to provide the enclosed drawing and schedule to the consultants prior to their visit to the Site because it will give them a good orientation.
If you need any additional information, do not hesitate to contact me.
YCB/rjo
cc: Tom Vanderberg (w/o encl)
Paxton Badham (w/o encl)
Tom Barefoot (w/o encl) Karen Singer (w/o encl)
Very truly yours,
·y1~u~
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Ref. 27
Reasor Chemical
NCD 986 187 094
· Castle Hayne, New Hanover Co., NC EPA540-R-92"026
OSWER Directive 9345;1-07 ··.
Novemti~r fg92 · :: ~~-:~:: ;;, SUPERFlJND SfCTtON
The Hazard Ranking System· ·
Guidance Manual
Interim Final
Hazardous Site Evaluation Division
Office of Solid Waste and Emergency Response
U.S. Environmental Protection Agency•
Washington, DC 20460
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Ref 28
Reasor Chemical
NCO 986 187 094
Castle Hayne, New Hanover Co., NC ,
MEMO
TO:
FROM:
DATE:
SUBJECT:
File
Jeanette Stanley
Environmental Chemist
NC Superfund Section
May 14, 2001
Reasor Chemical
NCD 986 187 094
Castle Hayne, New Hanover Co., NC
Attached is a enlarged (with scale) section of the Wetland Inventory Map showing the site
(US Department of the Interior, Fish and Wildlife Service, National Wetlands Inventory, Castle
Hayne, NC, 1994). Sample locations are noted on this map. The full size Castle Hayne National
Wetland Inventory map can be found in the HRS documentation package on this site, at reference
7. Also attached are copies of photographs taken of the surface water pathway and a diagram of
surrounding land use with field log notes. These items will be discussed in more detail below.
The PPE is in a wetland area without a distinct channel. The National Wetlands Inventory
Map shows that the area of the PPE is a PFOI/2F, Palustrine Forested Broad-Leafed
Deciduous/Needle-Leafed Deciduous, Semipermanently Flooded wetland.
On July 11, 2000, I drove past the Reasor Chemical Co. Site in order to view the stream
from Highway 132. (After viewing the maps and aerial photograph of the site, I had been unable
to determine if Prince George Creek upgradient from the highway was channelized.) When I
drove past, I observed the creek to be a flooded wetland, and could not identify a stream channel
upgradient from the outfall under Highway 132. On March 29, 2001, I again drove past the site
and observed the surface water pathway from Hwy. 132. It was a flooded wetland, not a
channelized stream. I took five photographs, four upstream from Hwy. 132 and one downstream
of Hwy. 132. These photographs are attached. I collected information on surrounding land use
during the same visit, and a figure of the surrounding land use is attached.
The National Wetlands Inventory Map was reviewed to confirm the presence ofHRS-
eligible wetlands. The Wetland Inventory map shows that Prince George Creek adjacent to and
downgradient from the Reasor Chemical Co. Site is a PFO I/2F (Palustrine Forested Broad-
Leafed Deciduous/Needle-Leafed Deciduous, Semipermanently Flooded) wetland above Hwy.
132 and a PFOl/4C (Palustrine Forested Broad-Leafed Deciduous/Needle-Leafed Evergreen,
Seasonally Flooded) wetland upgradient of the Reasor Chemical Co. Site. According to the
Hazard Ranking System Guidance Manual, page A-22, both types of Palustrine Forested wetlands
can be presumed to meet the 40 CFR 230.0 definition of a wetland.
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MEMO TO File
May 14, 2001
Reasor Chemical
page 2
I reviewed the consultant's figures and notes of the sampling locations. These figures
indicate wetlands along the downstream part of the surface water pathway, but not at the
background locations. When comparing these figures with the HRS-eligible wetlands appearing
on the National Wetland Inventory map (discussed above), it appears that the consultant's figures
only showed the Semipermanently Flooded wetlands but did not include the Seasonally Flooded
wetlands on the sample location figures. Based on the sample locations indicated on these figures
and wetlands shown on the National Wetland Inventory Map, both the downstream and
background surface water and sediment samples were collected in HRS-eligible wetlands.
In order to determine wetland frontage exposed to contamination, I used the Hazardous
Ranking System Guidance System Highlights 8-65 and 8-68 (pages 337 and 342, respectively).
Using the above discussed figures as guidance, I marked SE-22 and background sample locations
on the National Wetland Inventory map, and then marked the perimeter of this wetland area.
Using a map wheel to measure the perimeter marked on the attached copy of the wetland
inventory map, and measuring three times 1 determined the perimeter of the wetland exposed to
contamination to be 4,200', or 0.8 miles.
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asor C ,,~
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Chin's Auto Sales
Automated Plastic Engineering
Castle Hayne Mini Storage
Wilmington Auto Salvage & Sales
APAC Concrete
Warehouse with 5 - 6 scrap cars in parking lot
E & S Steel
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Figure Surrounding Land Use -March 29, 2001
J. Stanley Reasor Chemical Co., NCD 986 187 094, Castle Hayne, New Hanover Co., NC
,
~~. ~..___, .L,'.'::"·!, ,..1•-~--7.·,:_;;._J.°"',-._~i._!"1;'~":;.•~
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viewed from Hwy 132, about 20' NW of culvert,
Looking upstream and Northeast
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orge Creek, 03
m Hwy 132 c
Prince Georg;'c~, 03/29/01
viewed from Hwy 13 2 culvert,
Looking upstream and North
t l 1 Prince George Creek, 03/29/01
viewed from Hwy 132 culvert,
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Prince George Creek, 03/29/01
viewed from Hwy 132 culvert,
Looking downstream (West)
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Integrated.
Laboratory
Systems
MEMORANDUM
SUBJECT:
FROM:
TO:
THROUGH:
Ref. 29
Reasor Chemical
NCD 986 187 094
Castle Hayne, New Hanover Co., NC
Waste Division
Office of Technical Services
US EPA Region IV
61 Forsyth Street
Atlanta, GA 30303-3104
404-562-8643
September 12, 2000
Site visit comments
Reasor Chemical Site, Castle Hayne, New Hanover County, North
Carolina
Linda S. George --tsY
ILS E.S.A.T. Contractor
Office of Technical Services
Bobby Lewis
ESD
Samantha Urquhart-Foster
Remedial Project Manager
Elmer W. Akin, Chief
Office of Technical Services
Per your request dated September 8, 2000, I have compiled my field notes from the
Reasor Chemical Superfund Site visit conducted September 7, 2000. Participants in the site visit
included Bobby Lewis (ESD), Joe Owusu (ILS, Inc.), Tom Dillon (NOAA), and Tom Augsburger
(USFWS). The other participants may have additional information to the species and habitat
types found on this site. To facilitate the verbatim conveyance, I will be pleased to provide on
request a copy of this memo via cc:mail.
All met at the site at.0845 near the front gate. We drove aroun·d the site via existing
roads, stopping periodically to walk the site. Most roads were accessible except the South Access
Road heading west due to several fallen trees. We had a map of the site created by Roy F.
Weston, Inc., which was mostly accurate in relation to the site layout and locations of buildings.
The map, however, did not fully depict waterways. I would recommend the site map be updated
to include all drainage pathways. The site visit lasted approximately three hours.
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The site consisted mostly of a Zone IV type riparian system. This type is seasonally
flooded, and consisted dominantly of oak, sweetgum, red maple, and sycamore trees. Vegetation
became more obligatory near the ponds and tributaries. The 1994 National Wetlands Inventory
map describes the following areas as: Settling pond -PUBHx -palustrine, unconsolidated
bottom, permanently flooded, excavated. South of site near Prince George Creek-PF01/2C -
palustrine, forested, broad-leaved deciduous and needle-leaved deciduous, seasonally flooded, and
PFO 1 /2F -palustrine, forested, broad-leaved deciduous and needle-leaved deciduous, ·
semipermanently flooded. Northwest of the site boundary -PF04/IA -palustrine, forested,
needle-leaved evergreen and broad-leaved deciduous, temporarily flooded. Northeast of the site
boundary -PSS lB -palustrine, scrub-shrub, broad-leaved deciduous, saturated.
The roads were wet in some spots, as the area had recently received rain. The tributarJ
intersecting the road south of the North Tank Cradle area contained tannic water, with an evident
current. The bottom contained abundant leaflitter, however, no invertebrates were observed.
The sluice area and spent wood chips area still contain some wood chips. Water was evident in
the settling pond, and other ponds, although the depression areas_ofthese other ponds were larger
than the standing water, indicating that in the past, they contained more water. A toluene smell
was evident at Pond #3, and bladderwort was blooming in this pond. Pond #4, which was mostly
dry, contained a felled tree that had been cut down by a beaver. A ditch led from this pond to the
tributary, which was not located on the map .
Prince George Creek, where it intersected Highway 132, is a bald cypress (Taxodium
distichum) swamp, and was completely covered in water. Other species present were red maple
(Acer rubrum), dogwood (Camus sp.). Smartweeds (Polygonum sp.), morning glories (Ipomoea
sp.) and climbing hempweed (Mikania scandens) were blooming, and dallis grass (Paspalum
di/atatum) was growing near the road. Duckweed (Lemnaceae) was present in the water, and
spanish moss (Tillandsia usneoides) was in the trees and power line. A frog was observed in the
swamp.
We also attempted to look at Prince George Creek upstream of the site. The vegetation
was too thick to get to the creek itself, but vegetation at this location.included flowering touch-
me-nots (Impatiens capensis) and climbing hempweed. A red-bellied woodpecker (Melanerpes
carolinus) was present, and an eastern king snake (Lampropeltis getulus) was caught nearby.
A list of species noted on the site are as follows:
Vegetation
white pine (Pinus strobus), other pine trees, sweetgum (Liquidambar styraciflua), cherry (Prunus
sp.), bay (species unknown), tulip tree (Liriodendron tulipifera), red maple (Acer rubrum), oaks
(Quercus sp.), and sycamore (Pia/anus occidentalis).
Lespedeza sp., cattails (Typha sp.), wax myrtle (Myrica cerifera), rush (Juncus sp.), white and
yellow composites (Asteraceae), passion-flower (Passijlora incarnata), sedges (Cyperus sp.),
I
•• I
I
I
I
I
I
I ••
I
I
I
I
I
I
3
milkweed (Asclepias sp.), greenbrier (Smilax rotundifo/ia), wild ginger (Asarum canadense),
candyweed (Polygala lutea), meadow beauty (Rhexia sp.), purple gerardia (Aga/inis purpurea),
goldenrod (Solidago sp.), muscadine (Vi/is rotundifo/ia), ebony spleenwort (Asplenium
p/atyneuron), cinnamon fern (Osmunda cinnamomea), royal fern (Osmunda regalis), sedges
(Cyperus sp.), wire grass (Poaceae), umbrella grass (Fuirena sp.), pokeweed (Phyto/acca rigida),
and bladderwort ( Utricularia sp.). Mushrooms and other fungi, and moss were also observed.
Birds
Turkey vulture (Cathartes aura), Carolina chickadee (Parus caro/inensis), hawk (Buteo sp.),
American crow (Corvus brachyrhynchos), Great crested flycatcher (Myiarchus crinitus),
Northern mockingbird (Mimus polyglollos), Northern flicker (Colaptes duratus), Hairy
woodpecker (Picoides. vi!/osus), Carolina wren (Th,yothorus ludovicianus), and other
unidentified songbirds.
Animals
Beaver (Castor canadensis) evidence (felled trees and branches), dog tracks (domesticated
animal), white-tailed deer tracks (Odocoileus virginianus), mole (Talpidae) mound trails, two
black racers (Co/uber constrictor), 2 lizards (Squamata), oyster shells (Ostreidae), bumble bees
(Hymenoptera), fire ants (Hymenoptera), chiggers, spiders (Araneae), crickets (Gryllidae), dragon
flies (Odonata), butterflies (Lepidoptera), and mosquito fish (Gambusia sp.) .
11119'2 (,-\ .-NALIIIII; ---""f -R-N l~'J, ftNs,ll!!P
~Sample • .--O--FY--19_9_7 __ P_ro_je_c_t:_9_7 ___ 0_35-3--------------l --~ro-on .1 •• 15:P
METALS SCAN
Facilily: REASOR CHEMICAL CASTLE HAYNE. NC
Case Number: 25634
MD Number: MX13
Program: NSF
Id/Station: RCSS18
Media: SOIL
RESULTS UNITS
0.17U MG/l(G
0.42U MG/KG
7.2 MG/KG
0.02U MG/KG
1U MG/KG
0.36J MG/KG
7.7 MG/KG
13J MG/KG
1.4J MG/KG
48J MG/KG
1U MG/KG
0.51UJ MG/KG
0.72U MG/KG
3.4J MG/KG
22 MG/KG
2.4 MG/KG
1200 MG/KG
6.5 MG/KG
990J MG/KG
100U MG/KG
1500J MG/KG
70 MG/KG
70UJ MG/KG
7 %
D Number: MX47
ANALYTE
SILVER
ARSENIC
BARIUM
BERYLLIUM
CADMIUM
COBALT
CHROMIUM
COPPER
NICKEL
LEAD
ANTIMONY
SELENIUM
THALLIUM
VANADIUM
ZINC
TOTAL MERCURY
ALUMINUM
MANGANESE
CALCIUM
MAGNESIUM
IRON
SODIUM
POTASSIUM
% MOISTURE
lnorg Contractor: SENTIN
Org Contractor: CLAYTN
A-average value. NA-not analyzed. NAl-interferences. J-estimated value. N-presumplive evidence of presence of material.
Produced by: Keilh Bales
Requestor: RAY DOYLE
Project Leader: DOYLE
Beginning: 08/15/97 10:45
Ending:
z (")
K-actual value is known to be less than value given. L-actual value is known to be greater than value given. U-material was analyzed for but not detected. the number is the minimum quantitation limit. R-qc indicates that data unusable. compound may or may not be present. resampling and reanalysis is necessary_ for verification. · C-confirmed by gems: 1.when no value is reported, see chlordane constituents 2.constiluents or metabolites of technical chlordane
== 111111 iiiii iiiiii iiii -
Sample 20 FY 1997
SPECIFIED TESTS
Facility: REASOR CHEMICAL
Program: NSF
Id/Station: RCSS18
Media: SOIL
RESULTS UNITS ANALYTE
0.12U MG/KG CYANIDE
Project: 97 -0353
CASTLE HAYNE, NC
Case Number: 25634
MD Number: MX13
D Number: MX4 7
lnorg Contractor: SENTIN
Org Contractor: CLA YTN
A-average value. NA-not analyzed. NAl-interferences. J-estimated value. N-presumptive evidence of presence of material.
Produced by: Keith Bates
Requester: RAY DOYLE
Project Leader: DOYLE
Beginning: 08/15/97 10:45
Ending:
Production Date: .0/97 15:24
K-actual value is· ·vn to be less than value given. L-actual value is known to be greater than value U-material was analyzed for but not detected. the num_ber is the minimum qu;: on limit. R--qc indicates ti .a unusable. compound may or may not be present. resampting and reanalysis cessary for verification. r:-confirmed by 91... --~= 1.when no value is reported, see chlordane constituents 2.constituents or melaoofltes or technical chlordane
"2: ,a;a::,L,._S s.ijliiii-E ..-vs,_ --~-lll!!ll:>N ---EN--= 1111111 11111 lliiiliil ProiliJion l!iiiJ. 12 ... 11 ..
Sample llss~· _F_Y_1_9_97--P-ro-je_c_t_: -9-7--0-3_5_3-----------~• _______ P_ro_d_u-ce-d-by_:_J_o_hn_M_c_C_on_n_e_y-------.1•
VOLATILES SCAN Requestor:RAY DOYLE
Project Leader: DOYLE
Facility: REASOR CHEMICAL CASTLE HAYNE, NC Beginning: 08/18/97 10:15
Program: NSF Case Number: 25634 Ending:
ld/Slation: RCSS23(01
Media: SOIL D Number: MX61 Org Contractor: CLA YTN
RESULTS UNITS
10U UG/KG
10U UG/KG
10U UG/KG
10U UG/KG
10U UG/KG
20U UG/KG
10U UG/KG
10U UG/KG
10U UG/KG
10U UG/KG
10U UG/KG
10U UG/KG
10U UG/KG
10U UG/KG
10U UG/KG
10U UG/KG
10U UG/KG
10U UG/KG
10U UG/KG
10U UG/KG
10U UG/KG
10U UG/KG
10U UG/KG
10U UG/KG
10U UG/KG
10U UG/KG
10U UG/KG
10U UG/KG
10U UG/KG
10U UG/KG
10U UG/KG
10U UG/KG
10U UG/KG
4 %
ANALYTE
CHLOROMETHANE
BROMOMETHANE
VINYL CHLORIDE
CHLOROETHANE
METHYLENE CHLORIDE
ACETONE
CARBON DISULFIDE
1, 1-DICHLOROETHENE (1, 1-DICHLOROETHYLENE)
1, 1-DICHLOROETHANE
1,2-DICHLOROETHENE (TOTAL)
CHLOROFORM
1,2-DICHLOROETHANE
METHYL ETHYL KETONE
1, 1, 1-TRICHLOROETHANE
CARBON TETRACHLORIDE
BROMODICHLOROMETHANE
1,2-DICHLOROPROPANE
CIS-1,3-DICHLOROPROPENE
TRICHLOROETHENE (TRICHLOROETHYLENE)
DIBROMOCHLOROMETHANE
1, 1,2-TRICHLOROETHANE
BENZENE
TRANS-1,3-DICHLOROPROPENE
BROMOFORM
METHYL ISOBUTYL KETONE
METHYL BUTYL KETONE
TETRACHLOROETHENE (TETRACHLOROETHYLENE)
1, 1,2,2-TETRACHLOROETHANE
TOLUENE
CHLOROBENZENE
ETHYL BENZENE
STYRENE
· TOTALXYLENES
% MOISTURE
A-average value. NA-not analyzed. NAl-interferences. J-estimated value. N-pri?sumptive evidence or presence of material.
•
K-actua1 value is known to be less than value given. l-actual value is known to be greater than value given. U-material was analyzed for _but not detected. the number is the minimum quantitation limit.
R-qc indicates that data unusable. compound may or may not be present. resampling and reanalysis is necessary for verification.
C-confirmed by gems: 1.when no value is reported, see chlordane constituents 2.constituents or metabolites of technical chlordane
l!!!!!!!I voil!!l!..ES==PL~L y;;;il ;;;;a iili
Sampl 2765 FY 1997 Project: 97-0353
MISCELLANEOUS COMPOUNDS
Facility: REASOR CHEMICAL CASTLE HAYNE. NC
Program: NSF Case Number: 25634
Id/Station: RCSS23(01
Media: SOIL D Number: MX61
RESULTS
20J
50J
UNITS
UG/KG
UG/KG
ANALYTE
PIN ENE ISOMER
ALKANES
Org Contractor: CLA Yl'N
A-average value. NA-not analyzed. NAl-interferences. J-estimated value. N-presumptive evidence of presence of material.
Produced by: John McConney
Requestor:-RAY DOYLE
Project Leader: DOYLE
Beginning: 08/18/97 10:15
Ending:
K-actual value is ' ·. ·in to be Jess than value given. L-actual value is known to be greater than value ( U-material was analyzed for but not detected. the number is the minimum quar R-qc indicates th . a unusable. compound may or may not be present. resampling and reanalysis .essary for verification. r -confirmed by 91... .. .;: 1.when no value is reported, see chlordane constituents 2.constituents or metabu11tes of technical chlordane
1n limit.
=::5xT~ AB'aiiitAll'iiifi AN~IS liiiii --A --0Nl!!!!!!!l!F'~ENll!9, -11111 11111/11 Prlliiltio,.,..,: 1 iliii7 1 :iiiii
Sample .70 FY 1997 Project: 97-0353
EXTRACTABLES SCAN
Facility: REASOR CHEMICAL
Program: NSF
CASTLE HAYNE, NC
Case Number: 25634
Id/Station: RCSS2301
Media: SOIL
RES UL TS UNITS
1800U
1800U
1800U
1800U
1800U
1800U
1800U
1800U
1800U
1800U
1800U
1800U
1800U
1800U
1800U
1800U
1800U
1800U
1200J
1800U
1800U
1800U
1100J
1800U
1800U
4500U
1800U
4500U
1800U
510J
1800U
4500U
1800U
4500U
4500U
1800U
1800U
81800U
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
D Number: MX62
ANALYTE
PHENOL
BIS(2-CHLOROETHYL) ETHER
2-CHLOROPHENOL
1,3-DICHLOROBENZENE
1,4-DICHLOROBENZENE
1,2-DICHLOROBENZENE
2-METHYLPHENOL
BIS(2-CHLOROISOPROPYL) ETHER
(3-AND/OR 4-)METHYLPHENOL
N-NITROSODI-N-PROPYLAMINE
HEXACHLOROETHANE
NITROBENZENE
ISOPHORONE
2-NITROPHENOL
2,4-DIMETHYLPHENOL
BIS(2-CHLOROETHOXY)METHANE
2,4-DICHLOROPHENOL
1,2,4-TRICHLOROBENZENE
NAPHTHALENE
4-CHLOROANILINE
HEXACHLOROBUTADIENE
4-CHLORO-3-METHYLPHENOL
2-METHYLNAPHTHALENE
HEXACHLOROCYCLOPENTADIENE (HCCP)
2,4,6-TRICHLOROPHENOL
2,4,5-TRICHLOROPHENOL
2-CHLORONAPHTHALENE
2-NITROANILINE
DIMETHYL PHTHALATE
ACENAPHTHYLENE
2,6-DINITROTOLUENE
3-NITROANILINE
ACENAPHTHENE
2,4-DINITROPHENOL
4-NITROPHENOL
DIBENZOFURAN
2,4-DINITROTOLUENE
DIETHYL PHTHALATE
•---~----• Produced by: John McConney
Org Contractor: CLA YTN
Requester: HAY DOYLE
Project Leader: DOYLE
Beginning: 08/18/97 10:15
Ending:
RESULTS UNITS ANALYTE
1800U
840J
4500U
4500U
1800U
1800U
· 1800U
4500U
4100
670J
1800U
1800U
1700J
2900
1800U
1800U
1200J
1400J
1800U
1800U
1300J
850J
1800U
1800U
1800U
7
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
%
4-CHLOROPHENYL PHENYL ETHER
FLUORENE
4-NITROANILINE
2-METHYL-4,6-DINITROPHENOL
N-NITROSODIPHENYLAMINE/DIPHENYLAMINE
4-BROMOPHENYL PHENYL ETHER
HEXACHLOROBENZENE(HCB)
PENTACHLOROPHENOL
PHENANTHRENE
ANTHRACENE
CARBAZOLE
DI-N-BUTYLPHTHALA TE
FLUORANTHENE
PYRENE
BENZYLBUTYLPHTHALATE
3,3'-DICHLOROBENZIDINE
BENZO(A)ANTHRACENE
CHRYSENE
BIS(2-ETHYLHEXYL) PHTHALA TE
DI-N-OCTYLPHTHALA TE
BENZO(B AND/OR K)FLUORANTHENE
BENZO-A-PYRENE
INDENO (1,2,3-CD) PYRENE
DIBENZO(A,H)ANTHRACENE
BENZO(GHl)PERYLENE
% MOISTURE
A-average value. NA-not analyzed. NAl-interferences. J-estimaled value. N-presumptlve evidence of presence of material.
K-actual val1:•.> i-; known to be less than value given. L-actual value is known to be greater than value given. U-material was analyzed for but not detected. the number is the minimum quantitation limit.
R-qc ind;r,.,:;:c:;. iiia! •fala unusable. compound may or may not be present. resampling and reanalysis is necessary for verification.
C-confirmed by gems: l .when no value is reported, see chlordane constituents 2.conslituents or metabolites of technical chlordane
. !!!!!!EX-elmTAic= SAl:liiiia: Arliilts1sliii liiii
Sample 3470 FY 1997 Project: 97-0353
MISCELLANEOUS COMPOUNDS
Facility: REASOR CHEMICAL
Program: NSF
CASTLE HAYNE. NC
Case Number: 25634
Id/Station: RCSS2301
Media: SOIL
RESULTS
1000J
4000J
2000J
80000J
20000J
UNITS
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
D Number: MX62
ANALYTE
METHYLANTHRACENE ISOMER
UNIDENTIFIED PAH'S
POL YNUCLEAR THIOPHENE
25 UNIDENTIFIED COMPOUNDS
ALKANES
Org Contractor: CLA YTN
A-average value. NA-not analyzed. NAl-interferences. J-estimated value. N-presumplive evidence of presence or material.
-1111111 liilil Production Date·
Produced by: John McConney
Requestor: RAY DOYLE
Project Leader. DOYLE
Beginning: 08/18/97 10:15
Ending:
.. iiiil
/15/97 12:24
K-actual value is~ . -..,n to'be less than value given. L-actual value is known to be greater than value f' U-material was analyzed for but not detected. the number is the minimum quar-,n limit. R-qc indicates th a unusable. compound may or may not be present. resampting and reanalysis .essary for verification. C-confirmed by 91,. ___ .,_ 1.when no value is reported, see chlordane constituents 2.constituents or metabv111es of technical chlordane
liBll>LAaa,_~EAIIIIYSI ..
--Sample ·:· u -~y ~-~ ~reject:
I!!!!!!!!! !!!!!I-~ -IRiN ,J!IR,o~filJlNs~--1!!!!!!!!1-'-aa--~,o-~n Date: 1•'97~ :P
, • Produced by: John McConney 97-0353
VOLATILES SCAN
Facility: REASOR CHEMICAL
Program: NSF
CASTLE HAYNE, NC
Case Number: 25634
Id/Station: RCSS26(1
Media: SOIL
RESULTS
10U
10U
10U
10U
10U
10U
10U
10U
10U
10U
10U
10U
10U
10U
10U
10U
10U
10U
10U
10U
10U
10U
10U
10U
10U
10U
10U
10U
10U
10U
10U
10U
10U
4
UNITS
UG/KG
UG/KG
UG/KG
UG/KG
. UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
%
D Number: MX71
ANALYTE
CHLOROMETHANE
BROMOMETHANE
VINYL CHLORIDE
CHLOROETHANE
METHYLENE CHLORIDE
ACETONE
CARBON DISULFIDE
Org Contractor: CLA YTN
1, 1-DICHLOROETHENE (1, 1-DICHLOROETHYLENE)
1, 1-DICHLOROETHANE
1,2-DICHLOROETHENE (TOTAL)
CHLOROFORM
1,2-DICHLOROETHANE
METHYL ETHYL KETONE
1, 1, 1-TRICHLOROETHANE
CARBON TETRACHLORIDE
BROMODICHLOROMETHANE
1,2-DICHLOROPROPANE
CIS-1,3-DICHLOROPROPENE
TRICHLOROETHENE (TRICHLOROETHYLENE) ·
DIBROMOCHLOROMETHANE
1, 1,2-TRICHLOROETHANE
BENZENE
· TRANS-1,3-DICHLOROPROPENE
BROMOFORM
METHYL ISOBUTYL KETONE
METHYL BUTYL KETONE
TETRACHLOROETHENE (TETRACHLOROETHYLENE)
1, 1,2,2-TETRACHLOROETHANE
TOLUENE
CHLOROBENZENE
ETHYL BENZENE
STYRENE
TOTAL XYLENES
¾MOISTURE
A-average value. NA-not analyzed. NAl-interferences. J-estimated value. N-presumptive evidence of presence of material.
Requester: RAY DOYLE
Project Leader: DOYLE
Beginning: 08/18/97 10:55
Ending:
K-actual value is known to be less than value given. L-actual value is known to be greater than value given. LI-material was analyzed for but not detected. the number is the minimum quantitation limit. R-qc indicates that data unusable. compound may or may not be present. resampling and reanalysis is necessary for verification. C-confirmed by gems: 1.when no value is reported, see chlordane constituents 2.constituents or metabolites of technical chlordane
Sample 1 FY 1997 Project: 97-0353
MISCELLANEOUS COMPOUNDS
Facility: REASOR CHEMICAL : CASTLE HAYNE, NC
Case Number: 25634 Program: NSF
Id/Station: RCSS26(1
Media: SOIL
RESULTS
50J
80J
1000J
UNITS
UG/KG
UG/KG
UG/KG
D Number: MX71
ANALYTE
PINENE ISOMER
LIMONENE ISOMER
ALKANES
Org Contractor: CLA YTN
A-average value. NA-not analyzed. NAl-interferences. J-estimated value. N-presumptive evidence of presence of material.
Produced by: John Mcconney
Requester: RAY DOYLE
Project Leader: DOYLE
Beginning: 08/18/97 10:55
Ending:
K-actual value is Ir· ·. ·'1 to be less than value given. L-actual value is known to be greater than value g' U-material was analyzed for but not detected. the number is the minimum quan· R-qc indicates the unusable. compound may or may not be present. resampling and reanalysis l .!ssary for verification. C-confirmed by g'4 ..• :. ·1.when no value is reported, see chlordane constituents 2.constituents or metabuules of technical chlordane
n limit.
'IMRA~~, _§Ji,,~LfflAL ~~ --=--5f--Rl8ffnv §t. A-S,·---.----,roduct,o;~a~2.flii/f4,2:2:piii--
Sample 1 i FY 1997 Project: 97-0353 . Produced by: John Mcconney .
EXTRACTABLES SCAN Requester: RAY DOYLE
Facility: REASOR CHEMICAL
Program: NSF
CASTLE HAYNE, NC
Case Number: 25634
Id/Station: RCSS2601
Media: SOIL
RESULTS .UNITS
3600U UG/KG
3600U UG/KG
3600U UG/KG
3600U UG/KG
3600U UG/KG
3600U UG/KG
3600U UG/KG ·
3600U UG/KG
3600U UG/KG
3600U UG/KG
3600U UG/KG
3600U UG/KG
3600U UG/KG
3600U UG/KG
3600U UG/KG
3600U UG/KG
3600U UG/KG
3600U UG/KG
11D0J UG/KG
3600U UG/KG
3600U UG/KG
3600U UG/KG
12D0J UG/KG
3600U UG/KG
3600U UG/KG
9000U UG/KG
3600U UG/KG
9000U UG/KG
3600U UG/KG
1500J . UG/KG
3600U UG/KG
9000U UG/KG
3600U UG/KG
9000U UG/KG
9000U UG/KG
3600U UG/KG
3600U UG/KG (500U UG/KG
D Number: MX72
ANALYTE
PHENOL
BIS(2-CHLOROETHYL) ETHER
2-CHLOROPHENOL
1,3-DICHLOROBENZENE
1.4-DICHLOROBENZENE
1,2-DICHLOROBENZENE
2-METHYLPHENOL
BIS(2-CHLOROISOPROPYL) ETHER
(3-AND/OR 4-)METHYLPHENOL
N-NITROSODI-N-PROPYLAMINE
HEXACHLOROETHANE
NITROBENZENE
ISOPHORONE
2-NITROPHENOL
2.4-DIMETHYLPHENOL
BIS(2-CHLOROETHOXY)METHANE
2,4-DICHLOROPHENOL
1,2,4-TRICHLOROBENZENE
NAPHTHALENE ·
4-CHLOROANILINE
. HEXACHLOROBUTADIENE
4-CHLORO-3-METHYLPHENOL
2-METHYLNAPHTHALENE .
HEXACHLOROCYCLOPENTADIENE (HCCP)
2.4.6-TRICHLOROPHENOL
2.4,5-TRICHLOROPHENOL
2-CHLORONAPHTHALENE
2-NITROANILINE
DIMETHYL PHTHALATE
ACENAPHTHYLENE
2,6-DINITROTOLUENE
3-NITROANILINE
ACENAPHTHENE
2.4-DINITROPHENOL
4-NITROPHENOL
DIBENZOFURAN
2,4-DINITROTOLUENE
DIETHYL PHTHALATE
Org Contractor: CLA YTN
RESULTS
3600U
1200J
9000U
9000U
3600U
3600U
3600U
9000U
7100
1800J
3600U
3600U
6600
8500
3600U
3600U
4400
4700
3600U
3600U
5300J
3900
2100J
3600U
2400J
8
Project Leader: DOYLE
Beginning: 08/18/97 10:55
Ending:
UNITS
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
.UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
%
ANALYTE
4-CHLOROPHENYL PHENYL ETHER
FLUORENE
4-NITROANILINE
2-METHYL-4,6-DINITROPHENOL
N-NITROSODIPHENYLAMINE/DIPHENYLAMINE
4-BROMOPHENYL PHENYL ETHER
HEXACHLOROBENZENE(HCB)
. PENTACHLOROPHENOL
PHENANTHRENE
ANTHRACENE
CARBAZOLE
DI-N-BUTYLPHTHALA TE
FLUORANTHENE
PYRENE
BENlYLBUTYLPHTHALATE
3,3'-DICHLOROBENZIDINE
BENZO(A)ANTHRACENE
CHRYSENE
BIS(2-ETHYLHEXYL) PHTHALATE
DI-N-OCTYLPHTHALA TE
BENZO(B AND/OR K)FLUORANTHENE
BENZO-A-PYRENE
INDENO (1,2,3-CD) PYRENE
DIBENZO(A,H)ANTHRACENE
BENZO(GHl)PERYLENE
% MOISTURE
A-average value. NA-not analyzed. NAl-interferences. J-estimaled value. N-presumptive evidence of presence of material.
K-actual value is known to be less than value given. L-actual value is known to be greater than value given. LI-material was analyzed for but not detected. the number is the minimum quantitation limit.
R-qc indicates that data unusable. compound may or may not be present. resampling and reanalysis is necessary for verification.
C-confirmed by gems: f.when no value is reported, see chlordane constituents 2.constituents or metaboliles of technical chlordane
Sample FY 1997 Project: 97-0353
MISCELLANEOUS COMPOUNDS
Facility: REASOR CHEMICAL
Program: NSF
CASTLE HAYNE, NC
Case Number: 25634 Id/Station: RCSS2601
Media: SOIL
RESULTS
1000J
900J
2000J
10000J
ANALYTE
PINENE ISOMER
D Number: MX72
METHYL NAPHTHALENE (NOT 2-METHYL) DIMETHYL NAPHTHALENE (2 ISOMERS)
METHYL ANTHRACENE (4 ISOMERS) PHENYL NAPHTHALENE ISOMER
DIMETHYL PHENANTHRENE (3 ISOMERS)
METHYL PYRENE
Org Contractor: CLA YTN
900J
6000J
1000J
3000J
2000J
4000J
9000J
8000J
4000J
UNITS
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
BENZONAPHTHOTHIOPHENE (2 ISOMERS) HYDROXY-METHOXYPHENYLPROPENONE (2 ISOMERS) SUBSTITUTED DECAHYDRONAPHTHALENE
6 UNIDENTIFIED PAH'S
3 UNIDENTIFIED COMPOUNDS
ALKANES
Produced by: John Mcconney·
Requester: RAY DOYLE
Project Leader. DOYLE
Beginning: 08/18/97 10:55
Ending:
A-average value. NA-not analyzed. NAl-interferences. J-estimated value. N-presumptive evidence of presence of material. K-actual value is 1· • ·,n to be less than value given. L-actlfal value is known to be greater than value ( U-material was analyzed for but not detected. the number is the minimum quar R-qc indicates th 3 unusable. compound may or may not be present. resampling and reanalysis essary for verification. C--confirmed by gt... __ : 1.when no value is reported, see chlordane constituents 2.constiluents or metat:J.., .. ies of technical chlordane
'O limit.
Sampl 897 FY 1997 Project: 97-0357
___ VOLATILES SCAN
Facility: REASOR CHEMICAL CASTLE HAYNE, NC
Program: NSF Case Number: 25655
Id/Station: RCSS9701
Media: SOIL
RESULTS UNITS
11U UG/KG
11U UG/KG
11U UG/KG
11U UG/KG
11U UG/KG
11U UG/KG
11U ·uG/KG
11U UG/KG
11U UG/KG
11U UG/KG
11U UG/KG
11U UG/KG
11U UG/KG
11U UG/KG
11U UG/KG
11U U_G/KG
11U UG/KG
11U UG/KG
11U UG/KG
11U UG/KG
11U UG/KG
11U UG/KG
11U_ UG/KG
11U UG/KG
11U UG/KG
11U UG/KG
11U UG/KG
11U UG/KG
11U UG/KG
11U UG/KG
11U UG/KG
11U UG/KG
11U UG/KG
7 %
D Number: MY 48
ANALYTE
CHLOROMETHANE
BROMOMETHANE
VINYL CHLORIDE
CHLOROETHANE
METHYLENE CHLORIDE
ACETONE
CARBON DISULFIDE
Org Contractor: AA TS
1, 1-DICHLOROETHENE (1, 1-DICHLOROETHYLENE}
1, 1-DICHLOROETHANE
1,2-DICHLOROETHENE (TOTAL}
CHLOROFORM
1,2-DICHLOROETHANE
METHYL ETHYL KETONE
1, 1, 1-TRICHLOROETHANE
CARBON TETRACHLORIDE
BROMODICHLOROMETHANE
1,2-DICHLOROPROPANE
CIS-1,3-DICHLOROPROPENE
TRICHLOROETHENE (TRICHLOROETHYLENE)
DIBROMOCHLOROMETHANE
1, 1,2-TRICHLOROETHANE
BENZENE
TRANS-1,3-DICHLOROPROPENE
BROMOFORM
METHYL ISOBUTYL KETONE
METHYL BUTYL KETONE
TETRACHLOROETHENE (TETRACHLOROETHYLENE)
1, 1,2,2-TETRACHLOROETHANE
TOLUENE
CHLOROBENZENE
ETHYL BENZENE
STYRENE
TOTAL XYLENES
%MOISTURE
Produced by: Denise_Goddard
I{equestor: RAY DOYLE
Project Leader: DOYLE
Beginning: 08/23/97 11:20
Ending:
A-average value. NA-not analyzed. NAl-interferences. J-estimated value. N-presumptive evidence of presence of material.
K-actual value ir · vn to be less than value given. L-actual value is known to be greater than value· . U-material was analyzed for but not detected. the number is the minimum qua· 'on limit.
R-qc indicates U . ta unusable.· compound maY or may not be present. resampling and reanalysis ;essary for verification.
r.-confirmed by ger,1s: 1.when no value is reported, see chlordane constituents 2.constituents or metabuutes of technical chlordane
------
-~O~E~.-,,Ll: .. LY~ _m= -_m::I __ Jiiili~PA ---IO~"'cf!ll'HE~A----------delif!iMe=r.-8 1M
Sample 11897 FY 1997 ProJect: 97-0357 Produced by Denise Goddard -·
MISCELlANEOUS COMPOUNDS-· -Requestor: RAY DOYLE
Project Leader: DOYLE Facility: REASOR CHEMICAL
Program: NSF
Id/Station: RCSS9701
Media: SOIL
RESULTS UNITS ANALYTE
CASTLE HAYNE, NC
Case Number: 25655
D Number: MY 48
SOJ UG/KG 1 UNIDENTIFIED COMPOUND
Org Contractor: AA TS
A-average value. NA-not analyzed. NAl-interferences. J-estimated value. N-presumptive. evidence of presence of material.
Beginning: 08/23/97 11 :20
Ending:
K-actual value is known to be less than value given. L-adual value is known to be greater than value given. U-material was analyzed for but not detected. the number is the minimum quantitation limit.
R-qc indicates that data unusable. compound may or may not be present. resampling and reanalysis is necessary for verification.
C:-confirmed by gems: 1.when no value is reported, see chlordane constituents 2.constiluents or metabolites of technical chlordane
.-XT~AB.Arv11!!!!1AN.f!!!!!IS l!!!!!!!I _ -~-_=aA -liiliiiiiilON -.=-EN ____ ------A--ed -:O~'i _ _,, 1 ~
-~---S~m~e-9~--F; 1997 Project: 97-0357 • Produced by: Denise Goddard .•
EXTRACTABLES SCAN
Facility: REASOR CHEMICAL CASTLE HAYNE, NC
Program: NSF
Id/Station: RCSS9701
Media: SOIL
RESULTS UNITS
350U UG/KG
350U UG/KG
350U UG/KG
350U UG/KG
350U UG/KG
350U UG/KG
350U UG/KG
350U UG/KG
350U UG/KG
350U UG/KG
350U UG/KG
350U UG/KG
350U UG/KG
350U UG/KG
350UJ UG/KG
350U UG/KG
350U UG/KG
350U UG/KG
350U UG/KG
350U UG/KG
350U UG/KG
350U UG/KG
350U UG/KG
350U UG/KG
350U UG/KG
890U UG/KG
350U UG/KG
890U UG/KG
350U UG/KG
350U UG/KG
350U · UG/KG
890U UG/KG ·
350U UG/KG
890U UG/KG
890U UG/KG
350U UG/KG
~~sou . UG/KG 050U UG/KG
Case Number: 25655
D Number: MY 48
ANALYTE
PHENOL
BIS(2-CHLOROETHYL) ETHER
2-CHLOROPHENOL
1,3-DICHLOROBENZENE
1,4-DICHLOROBENZENE
1,2-0/CHLOROBENZENE
2-METHYLPHENOL
BIS(2-CHLOROISOPROPYL) ETHER
(3-AND/OR 4-)METHYLPHENOL
N-NITROSODI-N-PROPYLAMINE
HEXACHLOROETHANE
NITROBENZENE
ISOPHORONE
2-NITROPHENOL
2,4-DIMETHYLPHENOL
BIS(2-CHLOROETHOXY)METHANE
2,4-0/CHLOROPHENOL
1,2,4-TRICHLOROBENZENE
NAPHTHALENE
4-CHLOROANILINE
HEXACHLOROBUTADIENE
4-CHLORO-3-METHYLPHENOL
2-METHYLNAPHTHALENE
HEXACHLOROCYCLOPENTADIENE (HCCP)
2,4,6-TRICHLORDPHENOL
2,4,5-TRICHLOROPHENOL
2-CHLORONAPHTHALENE
2-NITROANILINE
DIMETHYL PHTHALATE
ACENAPHTHYLENE
2,6-0/NITROTOLUENE
3-NITROANILINE ·
ACENAPHTHENE
2,4-DINITROPHENOL
4-NITROPHENOL
DIBENZOFURAN
2,4-0/NITROTOLUENE
DIETHYL PHTHALATE
Requestor: RAY DOYLE
Project Leader: DOYLE
Beginning: 08/23/97 11 :20
Ending:
Org Contractor: AA TS
RESULTS UNITS ANALYTE
350U
350U
890U
890U
350U
350UJ
350U
890U
350U
350U
350U
350U
350U
350U
350U
350U
350U
350U
350U
350U
350U.
350U
350U
350U
350U
7
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
%
4-CHLOROPHENYL PHENYL ETHER
FLUORENE
4-NITROANILINE
2-METHYL-4,6-DINITROPHENOL
N-NITROSODIPHENYLAMINE/DIPHENYLAMINE
_4-BROMOPHENYL PHENYL ETHER
HEXACHLOROBENZENE(HCB)
PENTACHLOROPHENOL
PHENANTHRENE)
ANTHRACENE
CARBAZOLE
0/-N-BUTYLPHTHALATE
FLUORANTHENE
PYRENE
BENZVLBUTYLPHTHALATE
3,3'-DICHLOROBENZIDINE
BENZO(A)ANTHRACENE
CHRYSENE
BIS(2-ETHYLHEXYL) PHTHALATE
0/-N-OCTYLPHTHALA TE
BENZO(B AND/OR K)FLUORANTHENE
BENZO-A-PYRENEo
INDENO (1,2,3-CD) PYRENE
DIBENZO(A,H)ANTHRACENE
BENZO(GHl)PERYLENE
% MOISTURE
A-average value. NA-not analyzed. NAl-interferences. J-estimated value. N-presumptive evidence of presence of material.
K-actual value is known to be less than value given. L-actual value is known to be greater than value given. LI-material was analyzed for but not detected. the number is the minimum quantitation limit.
R-qc indicates that data unusable. ·compound may or may not be present. resampling and reanalysis is necessary for verification.
f"':-r.onfirmed by gems: 1.when no value is reported, see chlordane constituents 2.constituents or metabolites of technical chlordane
P .I Sample 897 FY 1997 roJect:
MISCELLANEOUS COMPOUNDS
Facility: REASOR CHEMICAL
Program: NSF
Id/Station: RCSS9701
Media: SOIL
RESULTS UNITS
2000JN UG/KG
1000JN UG/KG
1000JN UG/KG
ANALYTE
BENZALDEHYDE
LIMONENE
BENZOIC ACID
97-0357
CASTLE HAYNE, NC
Case Number: 25655
D Number: MY 48 Org Contractor: AA TS
20000JN UG/KG
2000JN UG/KG
SUBSTITUTED PHENANTHRENE CARBOXYLIC ACIDS
NORTRACHELOGENIN
90000J UG/KG 26 UNIDENTIFED COMPOUNDS
A-average value. NA-not analyzed. NAl-interferences. J-estimated value. N-presumptfVe evidence of presence of material.
Produced by: Denise Goddard
Requester: RAY DOYLE
Project Leader: DOYLE
Beginning: 08/23/97 11 :20
Ending:
K-actual value is ' -·11 to be less than value given. L-actual value is known to be greater than value 91 LI-material was analyzed for but not detected. the number is the minimum quan'· •n limit.
R-qc indicates th. . J unusable. compound may or may not be present. resampling and reanalysis , ~ssary for verification.
C-confirmed by gei,,.,_ 1.when no value is reported, see chlordane constituents 2.constituents or metabv .. ,es of technical chlordane
I!!!!!!
Sample 79 FY 1997 Project: 97-0357
VOLATILES SCAN
Facility: REASOR CHEMICAL
Program: NSF
CASTLE HAYNE, NC
Case Number: 25655
MD Number: MY22 Id/Station: RCSS9801
Media: SOIL D Number: MY 49
RESULTS UNITS ANAL YTE
CHLOROMETHANE
BROMOMETHANE
VINYL CHLORIDE
CHLOROETHANE
METHYLENE CHLORIDE
ACETONE
CARBON DISULFIDE
. lnorg Contractor: ARI
Org Contractor: AA TS
12U
12U
12U
12U
12U
12U
12U
12U
12U
12U
12U
12U
12U
12U
12U
12U
12U
12U
12U
12U
12U
12U
12U
12U
12U
12U
12U
12U
12U
12U
12U
12U
12U
16
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
%
1, 1-DICHLOROETHENE (1, 1-DICHLOROETHYLENE)
1, 1-DICHLOROETHANE
1,2-DICHLOROETHENE (TOTAL)
CHLOROFORM
1,2-DICHLOROETHANE
METHYL ETHYL KETONE
1, 1, 1-TRICHLOROETHANE
CARBON TETRACHLORIDE
BROMODICHLOROMETHANE
1,2-DICHLOROPROPANE
CIS-1,3-DICHLOROPROPENE
TRICHLOROETHENE (TRICHLOROETHYLENE)
DIBROMOCHLOROMETHANE
1, 1,2-TRICHLOROETHANE
BENZENE
TRANS-1,3-DICHLOROPROPENE
BROMOFORM
METHYL ISOBUTYL KETONE
METHYL BUTYL KETONE
TETRACHLOROETHENE (TETRACHLOROETHYLENE)
1, 1,2,2-TETRACHLOROETHANE .
TOLUENE
CHLOROBENZENE
ETHYL BENZENE
STYRENE
TOTAL XYLENES
% MOISTURE
A-average value. NA-not analyzed. NAl-interferences. J-estimated value. N-presumptive evidence of presence of material.
Produced by: D_enise Goddard
Requestor: RAY DOYLE
Project Leader: DOYLE
Beginning: 08/23/97 11_:35
Ending:
K-actual value is ~-'. ·•n to be less than value given. L-actual value is known to be greater than value g;-· U-material was analyzed for but not detected. the number is the minimum quanP ·=.,n limit.
R-qc indicates th 3 unusable. compound may or may not be present. resampling and reanalysis essary for verification.
C-confirmed by Qt... .... :. 1.when no value is reported, see chlordane constituents 2.constituents or metaL. ...... ds of technical chlordane
I -- ----VOLAT~ i='-'-llil'LE A""SIS----""-=-R=N 1J;lll1J,-..-Ns,.-------,;: --d D-21"-1:2111r
---~87~ FY 1997 Pr::~7==---• Producedby:DeniseGoddard •
MISCELLANEOUS COMPOUNDS Requestor: RAY DOYLE
Project Leader: DOYLE
Facility: REASOR CHEMICAL CASTLE HAYNE, NC Beginning: 08/23/97 11 :35
Program: NSF Case Number: 25655 Ending:
Id/Station: RCSS9801 MD Number: MY22 lnorg Contractor: ARI
Media: SOIL D Number: MY49 Org Contractor: AATS
RESULTS UNITS ANALYTE
2DOJ UG/KG 1 UNIDENTIFIED COMPOUND
A-average value. NA-not analyzed. NAl-interferences. J-estimated value. N-presumptive evidence Ot presence of material.
K-actual value is known to be less than value given. L-actual value is known to be greater than value given. U-material was analyzed for but not detected. the number is the minimum quantitation limit.
R-qc indicates that data unusable. compound may or may not be present. resampling and reanalysis is necessary for verification.
C-confirmed by gems: 1.when no value is reported, see chlordane constituents 2.constituents or metabolites of techni6al chlordane
----
~T~ABL-AM""'AN-""ls --~-ia:,N "'SD, WMEN8_i== ___ aliil---__:_p;_ecf_ 02/-12 ..
--~-=-=-S_a_m_p_le7--~-~8-7_9 __ FY ___ 19:::9:::7::==P=ro=je=ct=:=9~7~-0-3_5_7---~===----------~,----Produced by: Denise Goddard • .
EXTRACTABLES SCAN
Facility: REASOR CHEMICAL
Program: NSF
CASTLE HAYNE, NC
Case Number: 25655
MD Number: MY22 Id/Station: RCSS9801
Media: SOIL
RESULTS UNITS
D Number: MY 49
ANALYTE
PHENOL
BIS(2-CHLOROETHYL) ETHER
2-CHLOROPHENOL
1,3-DICHLOROBENZENE
1,4-DICHLOROBENZENE
1,2-DICHLOROBENZENE
2-METHYLPHENOL .
BIS(2-CHLOROISOPROPYL) ETHER
(3-AND/OR 4-)METHYLPHENOL
N-NITROSODI-N-PROPYLAMINE
HEXACHLOROETHANE
NITROBENZENE
ISOPHORONE
2-NITROPHENOL
2,4-DIMETHYLPHENOL
BIS(2-CHLOROETHOXY)METHANE
2,4-DICHLOROPHENOL
1,2,4-TRICHLOROBENZENE
NAPHTHALENE
4-CHLOROANILINE
HEXACHLOROBUTADIENE
4-CHLOR0-3-METHYLPHENOL
2-METHYLNAPHTHALENE
HEXACHLOROCYCLOPENTADIENE (HCCP)
2,4,6-TRICHLOROPHENOL
2,4,5-TRICHLOROPHENOL
2-CHLORONAPHTHALENE
2-NITROANILINE
DIMETHYL PHTHALATE
ACENAPHTHYLENE
lnorg Contractor: ARI
Org Contractor: AA TS
RESULTS
390U
390U
990U
990U
390U
390UJ
390U
990U
390U
390U
390U
390U
390U
390U
390U
390U
390U
390U
390U
390U
390U
390U
390U
390U
390U
16
390U
390U
390U
390U
390U
390U
390U
390U
390U
390U
390U
390U
390U
390U
390UJ
390U
390U
390U
390U
390U
390U
390U
390U
390U
390U
990U
390U
990U
390U
390U
390U
990U
390U
990U
990U
390U
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
2,6-DINITROTOLUENE
3-NITROANILINE r<f _tJ ) f. /17.) ACENAPHTHENE ·1
2,4-DINITROPHENQL
4-NITROPHENOL
DIBENZOFURAN
~90U
090U
2,4-DINITROTOLUENE
DIETHYL PHTHALATE
Requestor: RAY DOYLE
Project Leader: DOYLE
Beginning: 08/23/97 11 :35
Ending:
UNITS
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
lJG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
%
ANALYTE
4-CHLOROPHENYL PHENYL ETHER
FLUORENE
4-NITROANILINE
2-METHYL-4,6-DINITROPHENOL
N-NITROSODIPHENYLAMINE/DIPHENYLAMINE
4-BROMOPHENYL PHENYL ETHER
HEXACHLOROBENZENE (HCB)
PENTACHLOROPHENOL
PHENANTHRENE
ANTHRACENE
CARBAZOLE.
DI-N-BUTYLPHTHALATE
FLUORANTHENE
PYRENE
BENZVLBUTYLPHTHALATE
3,3'-DICHLOROBENZIDINE
BENZO(A)ANTHRACENE
CHRYSENE
BIS(2-ETHYLHEXYL) PHTHALATE
DI-N-OCTYLPHTHALA TE
BENZO(B AND/OR K)FLUORANTHENE
BENZO-A-PYRENE
INDENO (1,2,3-CD) PYRENE
DIBENZO(A,H)ANTHRACENE
BENZO(GHl)PERYLENE
%MOISTURE
A-average value. NA-not analyzed. NAl-interferences. J-estimated value. N-presumptive evidence of presence of m"aterial. _
K-actual value is i, ' - , to be less than value given. L-actual value is known to be greater than value gi• LI-material was analyzed for but not detected. the number is the minimum quant;• , limit.
R-qc indicates th~ .. unusable. compound may or may not be present. resampling and reanalysis i: ,ssary for verification.
C-confirmed by gcr,·, ... : 1.when no value is reported, see chlordane constituents 2.constituents or metabo ... ~s of technical chlordane
.. TRaipBf~AMialr\N..__:_I!!!'! __ ~ -~:-~~~"lJ:liiliEN~----------A-ed·-02/-:12~--
--Sample .79 FY 19~;-Project: 97-0357 • . Produced by: Denise Goddard · •
MISCELLANEOUS COMPOUNDS
Facility: REASOR CHEMICAL
Program: NSF .. ,_
Id/Station: RCSS9801
Media: SOIL
RESULTS UNITS
600JN UG/KG
500JN UG/KG
ANALYTE
BENZALDEHYDE
LIMONENE
CASTLE HAYNE, NC
Case Number: 25655
MD Number: MY22
D Number: MY 49
lnorg Contractor: ARI
Org Contractor: AA TS
2000JN UG/KG
1000JN UG/KG
SUBSTITUTED PHENANTHRENE CARBOXYLIC ACID
NORTRACHELOGENIN
10000J UG/KG 11 UNIDENTIFIED COMPOUNDS
A-average value. NA-not analyzed. NAl-interferences. J-estimated value. N-presumptive evidence of presence of material.
Requester: RAY DOYLE
Project Leader: DOYLE
Beginning: 08/23/97 11 :35
Ending:
K-actual value is known to be less than value given. L-actual value is known to be greater than value given. U-material was analyzed for but not detected. the number is the minimum quantitation limit.
R-qc indicates that data unusable. compound may or may not be present. resampling and reanalysis is necessary for verification.
C-confinned by gems: 1.when no value is reported, see chlordane constituents 2.constituents or metabolites of technical chlordane
-ET,,_A~AN-IS ---_----Sample 879-FY-fa97 Project: 97 -0357
METALS SCAN
Facility: REASOR CHEMICAL
Program: NSF
Id/Station: RCSS9801
Media: SOIL
RESULTS UNITS ANALYTE
0.19J MG/KG SILVER
0.47U MG/KG ARSENIC
8.5J MG/KG BARIUM
1U MG/KG BERYLLIUM
0.14J MG/KG CADMIUM
0.33U MG/KG COBALT
3.5 MG/KG CHROMIUM
5.6J MG/KG COPPER
0.84U MG/KG NICKEL
9.9J MG/KG LEAD
1.1UJ MG/KG ANTIMONY
0.56UJ MG/KG SELENIUM
0.79U MG/KG THALLIUM
3.3J MG/KG VANADIUM
5.4 MG/KG . ZINC
CASTLE HAYNE, NC
Case Number: 25655
MD Number: MY22
D Number: MY 49
0.05U MG/KG TOTAL MERCURY
3400 MG/KG ALUMINUM
7.8J MG/KG MANGANESE
16000J MG/KG CALCIUM
270J MG/KG MAGNESIUM
1100 MG/KG IRON
72 MG/KG SODIUM
93J MG/KG POTASSIUM
15 % % MOISTURE
lnorg Contractor: ARI
Org Contractor: AA TS
A-average value. NA-not analyzed. NAl-interferences. J-estimated value. N-presumptive evidence of presence of material.
Produced by: Keith Bates
Requester: RAY DOYLE
Project Leader: DOYLE
Beginning: 08/23/97 11 :35
Ending:
K-actual value is Jc ... ;wn to be less than vatue _given. L-actual value is known to be greater than value ~;. ~. U-material was analyzed for but not detected. the number is the minimum quar ·,n limit. R-qc indicates lh a unusable. compound may or may not be present. resampling and reanalysis essary for verlfrcation. C-confirmed by g, 1.when no value is reported, see chlordane constituents 2.constituents or metal. ... es of technical chlordane
- ----!!!!!!!I 1!!!11:1 ___ r;;aa ----------------------------_-=et.AS'S'Tt:'l\L.'",;'"'TRIEl'l'TS"SAMl"l:'E' AN~1s--"E"A -l'rr'G'ION IV. 7,ATRENs,GA Proauciion Date:. '1712:51
Sample "!1'379 FY 1997 Projecl· 97-0357 Produced by: Keith Bates
SPECIFIED TESTS Requestor: RAY DOYLE
Facility: REASOR CHEMICAL
Program: NSF
ld/Slation: RCSS9801
Media: SOIL
RESULTS UNITS ANALYTE
0.13U MG/KG CYANIDE
CASTLE HAYNE, NC
Case Number: 25655
MD Number: MY22
D Number: MY49
lnorg Contractor: ARI
Org Contractor: AA TS
A-average value. NA-not analyzed. NAl-interferences. J-eslimated value. N-presumptive evidence or presence of material.
Project Leader: DOYLE
Beginning: 08/23/97 11 :35
Ending:
K-actual value is known to be less than value given. L-actual value is known to be greater than value given. U-materia1 was analyzed for but not detected. the number is the minimum quantitation limit.
R-qc indicates that data unusable. compound may or may not be present. resampling and reanalysis is necessary for verification.
r-confirmed by gems: 1.when no value is reported, see chlordane constituents 2.constituents or metabolites of technical chlordane
Sample 29 FY 1997 Project: 97-0370
DIOXIN SCAN
Facility: REASOR CHEMICAL CASTLE HAYNE, NC
Program: NSF
Id/Sta lion: RCSS9801
Media: SOIL
RESULTS
2.3UR
3.2J
1.9J
1.9J
5.BU
5.BU
5.BU
2.9J
3.SU
9.SJ
68J
2.3U
4.SJ
5.BU
5.BUR
5.BUJ
5.BU
5.BU
5.BU
5.BUR
5.BUJ
1.3J
5.BU
1.3J
4.9J
1.1J
14
UNITS
NG/KG
NG/KG
NG/KG
NG/KG
NG/KG
NG/KG
NG/KG
NG/KG
NG/KG
NG/KG
NG/KG
NG/KG
NG/KG
NG/KG
NG/KG
NG/KG
NG/KG
NG/KG
NG/KG
NG/KG
NG/KG
NG/KG
NG/KG
NG/KG
NG/KG
NG/KG
%
D Number: SS98
ANALYTE
2,3,7,8-TETRACHLORODIBENZODIOXIN
TETRACHLORODIBENZODIOXIN (TOTAL)
1,2,3, 7,8-PENTACHLORODIBENZODIOXIN
PENTACHLORODIBENZODIOXIN (TOTAL) 1,2,3,4, 7,8-HEXACHLORODIBENZODIOXIN
1,2,3,6,7,8-HEXACHLORODIBENZODIOXIN
1,2,3,7 ,8,9-HEXACHLORODIBENZODIOXIN
HEXACHLORODIBENZODIOXIN (TOTAL) 1,2,3,4,6,7,8-HEPTACHLORODIBENZODIOXIN
HEPTACHLORODIBENZODIOXIN (TOTAL}
OCTACHLORODIBENZODIOX/N
2,3,7,8-TETRACHLORODIBENZOFURAN
TETRACHLOROD/BENZOFURAN (TOTAL)
1,2,3,7,8-PENTACHLORODIBENZOFURAN
2,3,4,7,8-PENTACHLORODIBENZOFURAN
PENTACHLOROD/BENZOFURAN (TOTAL)
1,2,3,4, 7,8-HEXACHLORODIBENZOFURAN
1,2,3,6, 7,8-HEXACHLORODIBENZOFURAN
1,2,3, 7,8,9-HEXACHLORODIBENZOFURAN
2,3,4,6,7,8-HEXACHLORODIBENZOFURAN
HEXACHLORODIBENZOFURAN (TOTAL)
1,2,3,4,6, 7,8-HEPTACHLORODIBENZOFURAN
1,2,3,4,7 ,8,9-HEPTACHLORODIBENZOFURAN
HEPTACHLORODIBENZOFURAN (TOTAL)
OCTACHLORODIBENZOFURAN
TEO (TOXIC. EQUIV. VALUE, FROM I-TEF/89)
% MOISTURE
SAS Number:DIOX
Org Contractor: SWOK
A-average value. NA-not analyzed. NAl-inlerferences. J-estimated value. N-presumptive evidence or presence of material.
Produced by: John Mcconney
Requester: RAY DOYLE
Projecl Leader: DOYLE
Beginning: 08/23/97 11 :35
Ending:
K-actual value is •· ·. vn to be less than value given. L-actual value is known to be greater than value r U-material was analyzed for but not detected. the number is the minimum qua• R-qc indicates th a unusable. compound may or may not be present. resampling· and reanalysis ;essary for verification. r.-confirmed by gt... .... ·. 1. when no value is reported, see chlordane constituents 2.constituents or metallvutes of technical chlordane
,n limit.
~ES1mESJGiil~J:\Jiiiiii AfiiiiiiSIS----.. A "-10~ .J, A I I,..:~-------;-tionWe. 197 ~-
-· -~79 FY 1997 Project: 97-0357 . • . Produced by: John McConney . PESTICIDES SCAN Requestor: RAY DOYLE
Project Leader: DOYLE
Beginning: 08/23/97 11 :35
·Ending:
Facility: REASOR CHEMICAL
Program: NSF
CASTLE HAYNE, NC
Case Number: 25655
Id/Station: RCSS9801
Media: SOIL
RES UL TS UNITS
2.0U UG/KG
2.0U UG/KG
2.0U UG/KG
2.0U UG/KG
2.0U UG/KG
2.0U UG/KG
2.0U UG/KG
2.0U UG/KG
3.9U UG/KG
3.9U UG/KG
3.9U. UG/KG
3.9U UG/KG
3.9U UG/KG
3.9U UG/KG
3.9U UG/KG
20U UG/KG
3.9U UG/KG
3.9U . UG/KG
2.0U UG/KG
2.0U UG/KG
200U UG/KG
39U UG/KG
BOU UG/KG
39U UG/KG
39U UG/KG
39U UG/KG
39U UG/KG
39U UG/KG
16 %
MD Number: MY22
D Number: MY 49
ANALYTE
ALPHA-BHC
BETA-BHC
DELTA-BHC
GAMMA-BHC {LINDANE)
HEPTACHLOR
ALDRIN
HEPTACHLOR EPOXIDE
ENDOSULFAN I (ALPHA)
DIELDRIN
4,4'-DDE (P,P'-DDE)
ENDRIN
ENDOSULFAN II {BETA)
4,4'-000 (P,P'-000)
ENDOSULFAN SULFATE
4,4'-DDT (P,P'-001)
METHOXYCHLOR
ENDRIN KETONE
ENDRIN ALDEHYDE
ALPHA-CHLORDANE /2
GAMMA-CHLORDANE /2
TOXAPHENE
PCB-1016 {AROCLOR 1016)
PCB-1221 {AROCLOR 1221)
PCB-1232 {AROCLOR 1232)
PCB-1242 {AROCLOR 1242) ·
PCB-1248 {AROCLOR 1248)
PCB-1254 {AROCLOR 1254)
PCB-1260 {AROCLOR 1260)
%MOISTURE
lnorg Contractor: ARI
Org Contractor: AA TS
A-average value. NA-not analyzed. NAl-interferences. J-estimated value. N-presumptive evidence of presence of material. K-actual value is known to be less than value given. L-actual value is known to be greater than value given. U-material was analyzed for but not detected. the number is the minimum quantitation limit. R-qc indicates that data unusable. compound may or may not be present. resampling and reanalysis is necessary for verification. C-confirmed by gems: 1.when no value is reported, see· chlordane constituents 2.constituents or metabolites of technical chlordane
_llil::Jou&:s~1;;e-.acvs•------lllll!!IIA-c-oN""""'O--EN----------Aa.:ied-:oz!i 131!1..L( ,--
Sample -8~ FY 1997 Project: 97-0357 -• ' Produced by: Denise Goddard •
VOLATILES SCAN
Facility: REASOR CHEMICAL
Program: NSF
CASTLE HAYNE, NC
Case Number: 25655
Id/Station: RCSS9901
Media: SOIL
RESULTS
12U
12U
12U
12U
12U
12U
12U
12U
12U
12U
12U
12U
12U
12U
12U
12U
12U
12U ·
12U
12U
12U
12U
12U
12U
12U
12U
12U
12U
12U
12U
12U
12U
12U
14
UNITS
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
%
MD Number: MY23
D Number: MY51
ANALYTE
CHLOROMETHANE
BROMOMETHANE
VINYL CHLORIDE
CHLOROETHANE
METHYLENE CHLORIDE
ACETONE
CARBON DISULFIDE
lnorg Contractor: ARI
Org Contractor: AA TS
1, 1-DICHLOROETHENE (1, 1-DICHLOROETHYLENE)
1, 1-DICHLOROETHANE
1,2-DICHLOROETHENE {TOTAL)
CHLOROFORM
1,2-DICHLOROETHANE
METHYL ETHYL KETONE
1,1, 1-TRICHLOROETHANE
CARBON TETRACHLORIDE
BROMODICHLOROMETHANE
1,2-DICHLOROPROPANE
CIS-1,3-DICHLOROPROPENE
TRICHLOROETHENE {TRICHLOROETHYLENE)
DIBROMOCHLOROMETHANE
1, 1,2-TRICHLOROETHANE
BENZENE
TRANS-1,3-DICHLOROPROPENE
BROMOFORM
METHYL ISOBUTYL KETONE
METHYL BUTYL KETONE
TETRACHLOROETHENE {TETRACHLOROETHYLENE)
1, 1,2,2-TETRACHLOROETHANE
TOLUENE
CHLOROBENZENE
ETHYL BENZENE
STYRENE
TOTAL XYLENES
% MOISTURE
Requestor: RAY DOYLE
Project Leader: DOYLE
Beginning: 08/23/97 13:30
Ending:
A-average value. NA-not analyzed. · NAl-interferences. J-estimated value. N-presumptive evidence of presence of material. . ·
K-actual value is known to be less than value given. L-actual value is known to be greater than value given. U-material was analyzed for but not detected. the number is the minimum quantitation limit.
R-qc indicates that data unusable. compound may or may not be present. resampling and reanalysis is necessary for verification.
C-confirmed by gems: 1.when no value is reported, see ch_lordane constituents 2.constituents or metabolites of technical chlordane
---~-Ql.JlillifS lWlilLE-. vs ______ -----A --ON -SD-EN--------A .. ed-02.-ili 11-
Sample 80 FY 1997 Project: 97-0357
MISCELLANEOUS COMPOUNDS
Facility: REASOR CHEMICAL .
Program: NSF
Id/Station: RCSS9901
Media: SOIL
RESULTS UNITS ANALYTE
CASTLE HAYNE, NC
Case Number: 25655
MD Number: MY23
D Number: MY51
200J UG/KG 1 UNIDENTIFIED COMPOUND
lnorg Contractor: ARI
Org Contractor: AA TS
A-average value. NA-not analyzed. NAl-interferences. J-estimated value. N-presumptive evidence of presence of material.
Produced by: Denise Goddard
Requestor: RAY DOYLE
Project Leader: DOYLE
Beginning: 08/23/97 13:30
Ending:
K-actual value is i.. ':vn to be less than value given. L-actual value is known to be greater than value :i · LI-material was analyzed for but not detected. the number is the minimum quanli' .,;,.,n limit.
R-qc indicates th a unusable. compound may or may not be present. resampling and reanalysis essary for verification.
C-confirmed by Qi....-~-1.when no value is reported, see chlordane constituents 2.constituents or melaL •.... ..!S of technical chlordane
--xT!tliialABL-A~AN..-1s----· · llil!!IIA ~ iRoN illllllso, REN~
Sample liao FY 1997 Project: 97-0357 • ·
-----~-e~--,-12. Produced by: Denise Goddard
Requestor: RAY DOYLE
Project Leader: DOYLE
Beginning: 08/23/97 13:30
Ending:
----
EXTRACT ABLES SCAN
Facility: REASOR CHEMICAL
Program: NSF
CASTLE HAYNE, NC
Case Number: 25655
MD Number: MY23 Id/Station: RCSS9901
Media: SOIL
RESULTS UNITS
380U UG/KG
380U UG/KG
380U UG/KG
380U UG/KG
380U UG/KG
380U UG/KG
380U UG/KG
380U UG/KG
380U UG/KG
380U UG/KG
380U UG/KG
380U UG/KG
380U UG/KG
380U UG/KG
380UJ UG/KG
380U UG/KG
380U UG/KG
380U UG/KG
380U UG/KG
380U UG/KG
380U UG/KG
380U UG/KG
380U UG/KG
380U UG/KG
380U UG/KG
960U UG/KG
380U UG/KG
960U UG/KG
380U UG/KG
380U UG/KG
380U UG/KG
960U UG/KG
380U UG/KG
960U UG/KG
960U UG/KG
®380U UG/KG
380U UG/KG
380U UG/KG
D Number: MY51
ANALYTE
PHENOL
BIS(2-CHLOROETHYL) ETHER
2-CHLOROPHENOL
1,3-DICHLOROBENZENE
1,4-DICHLOROBENZENE
1,2-DICHLOROBENZENE
2-METHYLPHENOL
BIS(2-CHLOROISOPROPYL) ETHER
(3-AND/OR 4-)METHYLPHENOL
N-NITROSODI-N-PROPYLAMINE
HEXACHLOROETHANE
NITROBENZENE
ISOPHORONE
2-NITROPHENOL
2,4-DIMETHYLPHENOL
BIS(2-CHLOROETHOXY)METHANE
2,4-DICHLOROPHENOL
1,2,4-TRICHLOROBENZENE
NAPHTHALENE
4-CHLOROANILINE
HEXACHLOROBUTADtENE
4-CHLORO-3-METHYLPHENOL
2-METHYLNAPHTHALENE
HEXACHLOROCYCLOPENTADIENE (HCCP)
2,4,6-TRICHLOROPHENOL
2,4,5-TRICHLOROPHENOL
2-CHLORONAPHTHALENE
2-NITROANILINE
DIMETHYL PHTHALATE
ACENAPHTHYLENE
2,6-DINITROTOLUENE
3-NITROANILINE
ACENAPHTHENE
2,4-DINITROPHENOL
4-NITROPHENOL
DIBENZOFURAN
2,4-DINITROTOLUENE
DIETHYL PHTHALATE
lnorg Contractor: ARI
Qrg Contractor: AA TS
RESULTS UNITS
380U UG/KG
380U UG/KG
960U UG/KG
960U UG/KG
380U UG/KG
380UJ UG/KG
380U UG/KG
960U UG/KG
380U UG/KG
380U UG/KG
380U UG/KG
380U UG/KG
380U UG/KG
380U UG/KG
380U UG/KG
380U UG/KG
380U UG/KG
380U UG/KG
380U UG/KG
380U UG/KG
380U UG/KG
380U UG/KG
380U UG/KG
380U UG/KG
380U UG/KG
14 %
ANALYTE
4-CHLOROPHENYL PHENYL ETHER
FLUORENE
4-NITROANILINE
2-METHYL-4,6-DINtTROPHENOL
N-NITROSODIPHENYLAMINE/DIPHENYLAMINE
4-BROMOPHENYLPHENYLETHER
HEXACHLOROBENZENE (HCB)
PENTACHLOROPHENOL
PHENANTHRENE
ANTHRACENE
CARBAZOLE
DI-N-BUTYLPHTHALA TE
FLUORANTHENE
PYRENE
BENlYLBUTYLPHTHALATE
3,3'-DICHLOROBENZIDINE
BENZO(A)ANTHRACENE
CHRYSENE
BIS(2-ETHYLHEXYL) PHTHALATE
DI-N-OCTYLPHTHALA TE
BENZO(B AND/OR K)FLUORANTHENE
BENZO-A-PYRENE
INDENO (1,2,3-CD) PYRENE
DIBENZO(A,H)ANTHRACENE
BENZO(GHl)PERYLENE
%MOISTURE
A-average value. NA-not analyzed. NAl-interferences. J-estimated value. N-presumptive evidence of presence of material.
K-actual value is kr ·. · to be less than value given. L-actual value is known to be greater than value giv' • J-material was analyzed for but not detected. the number is the minimum quantit limit.
R-qc indicates that . unusable. compound may or may not be present. resampling and reanatysis is ;sary for verification.
r.-confirrned by gcr1,__.-1.when no value is reported, see chlordane constituents 2.constituents or metabo11 ... .s of tec;:hnical chlordane
_ -".'._ 'llliiA~~A,.,. ~Ntiif 1~ -___ .
~80 FY 1997 Project: 97-0357
MISCELLANEOUS COMPOUNDS
Facility: REASOR CHEMICAL
Program: NSF
CASTLE HAYNE, NC
Case Number: 25655
MD Number: MY23 Id/Station: RCSS9901
Media: SOIL
RESULTS UNITS
800JN UG/KG
2000J UG/KG
40000J UG/KG
D Number: MY51
ANALYTE
NORTRACHELOGENIN
ALKANES
18 UNIDENTIFIED COMPOUNDS
lnorg Contractor: ARI
Org Contractor: AA TS
A-average value. NA-not analyzed. NAl-interferences. J-estimated value. N-presumptive evidence of presence of material.
Produced by: Denise Goddard
Requester: RAY DOYLE
Project Leader: DOYLE
Beginning: 08/23/97 13:30
Ending:
•
K-actual value is known to be less than value given. L-actual value is known to be greater than value given. U-material was analyzed for but not detected. the number is the minimum quantitation limit.
R-qc indicates that data unusable. compound may or may not be present. resampling and reanalysis is necessary for verification.
C-confirmed by gems: 1.when no value is reported, see chlordane constituents 2.constituents or metabolites of technical chlordane
----------_-.,,FT-SA~At-.-,1S ___ ----~A--ION IJ.--:J!lil'HE~A ----Pr!Jl!tion Date. '9711:32
~880 FY 1997 Project: 97-0357 Produced by: Keith Bates
METALS SCAN Requestor: RAY DOYLE
Project Leader: DOYLE
Facility: REASOR CHEMICAL CASTLE HAYNE, NC Beginning: 08/23/97 13:30
_Program: NSF Case Number: 25655 Ending:
Id/Station: RCSS9901 MD Number: MY23 lnorg Contractor: ARI
Media: SOIL
RESULTS UNITS ANALYTE
0.18U MG/KG SILVER
0.44U MG/KG ARSENIC
7_gJ MG/KG BARIUM
1 U MG/KG BERYLLIUM
0.07U MG/KG CADMIUM
0.31U MG/KG COBALT
----~3,7--MG/KG-CHROMIUM
4.9J MG/KG COPPER
0.80U MG/KG NICKEL
8.8J MG/KG LEAD
1UJ MG/KG ANTIMONY
0.53UJ MG/KG SELENIUM
0.75U MG/KG THALLIUM
3.4J MG/KG VANADIUM
6.3 MG/KG ZINC
D Number: MY51
0.0SU MG/KG TOTAL MERCURY
2700 MG/KG ALUMINUM
6.SJ MG/KG MANGANESE
8300J MG/KG CALCIUM
180J MG/KG MAGNESIUM
1100 MG/KG IRON
76 MG/KG SODIUM
87J MG/KG POTASSIUM
12 % % MOISTURE
Org Contractor: AA TS
A-average value. NA-not analyzed. NAl-interferences. J-estimated value. N-presumptive evidence of piesence of material.
K:actual value is known to be less than value given. L-actual value is known to be greater than value given. U-material was analyzed for but not detected. lhe number is the minimum quantitation limit.
R--qc indicates that data unusable. compound may or may not be present. resampling and reanalysis is necessary for verification.
C-confirmed by gems: 1.when no value is reported, see chlordane constituents 2.constituents or metabolites of technical chlordane
Sampl 880 FY 1997
SPECIFIED TESTS
Facility: REASOR CHEMICAL
Program: NSF
Id/Station: RCSS9901
Media: SOIL
RESULTS UNITS
0.13U MG/KG
ANALYTE
CYANIDE
Project: 97-0357 .
CASTLE HAYNE, NC
Case Number: 25655
MD Number: MY23
D Number: MY51
lnorg Contractor: ARI
Org Contractor: AA TS
A-average value. NA-not analyzed. NAl-interferences. J-estimated value. N-presumptive evidence of presence of material.
Produced by: Keith Bates
Requester: RAY DOYLE
Project Leader: DOYLE
Beginning: 08/23/97 13:30
Ending:
K-actual value is J.-.... :-wn to be less than value given. L-actual value is known lo be greater than value~-,_ U-material was analyzed for but not detected. the number is the minimum quar ·'ln limit. R-qc indicates It-'a unusable. compound may or may not be present. resampling and reanalysis ;essary for verification. C--confirmed by 9, . ·. 1.when no value is reported, see chlordane constituents 2.constituents or meta ... _.,.es of technical chlordane
Sampl 880 FY 1997 Project: 97-0357
PESTICIDES SCAN
Facility: REASOR CHEMICAL CASTLE HAYNE, NC
Program: NSF· Case Number: 25655
Id/Station: RCSS9901 MD Number: MY23
Media: SOIL D Number: MY51
RESULTS UNITS
2.0U UG/KG
2.0U UG/_KG
2.0U UG/KG
2.0U UG/KG
2.0U UG/KG
ANALYTE
ALPHA-BHC
BETA-BHC
DELTA-BHC
GAMMA-BHC (LINDANE)
HEPTACHLOR
lnorg Contractor: ARI
Org Contractor: AA TS
Produced by: John Mcconney
Requestor: RAY DOYLE
Project Leader: DOYLE
Beginning: 08/23/97 13:30
Ending:
2.0U UG/KG
2.0U UG/KG ALDRIN ---------------------------------------------HEPTACHLOR.EeOXIDE -----2:ou-uG/KG
3.8U UG/KG
3.8U UG/KG
3.8U UG/KG
3.8U UG/KG
3.8U UG/KG
3.8U . UG/KG
3.8U UG/KG
20U UG/KG
3.8U UG/KG
3.8U UG/KG
2.0U UG/KG
2.0U UG/KG
200U UG/KG
38U UG/KG
78U UG/KG
38U UG/KG
38U UG/KG
38U UG/KG
38U UG/KG
38U UG/KG
14 %
ENDOSULFAN I (ALPHA)
DIELDRIN
4,4'-DDE (P;P'-DDE)
ENDRIN
ENDOSULFAN 11 (BETA)
4,4'-DDD (P,P'-DDD)
ENDOSULFAN SULFATE
4,4'-DDT (P,P'-DDT)
METHOXYCHLOR
ENDRIN KETONE
ENDRIN ALDEHYDE
ALPHA-CHLORDANE /2
GAMMA-CHLORDANE /2
TOXAPHENE
PCB-1016 (AROCLOR 1016)
PCB-1221 (AROCLOR 1221)
PCB-1232 (AROCLOR 1232)
PCB-1242 (AROCLOR 1242)
PCB-1248 (AROCLOR 1248)
PCB-1254 (AROCLOR 1254)
PCB-1260 (AROCLOR 1260)
% MOISTURE
A-average value. NA-not analyzed. NAl-interferences. J-estimated value. N-presumptive evidence of presence of material. K-actual value is ' '. ·•n to be Jess than value given. L-actual value is known lo be greater than value , U-material was analyzed for but not detected. the number is the minimum qua R..qc indicates th . a unusable. compound may or may not be present. resampling and reanalysis .;essary for verification. r.---confirmed by gC.,,.,: 1.when no value is reported, see chlordane constituents 2.constituents or metabo11tes of technical chlordane
1n limit.
-~ox1~AIV'~NAMs --· -
Sample 130, FY 1997 Project: 97-0370
"'A :&N "~ fll"E~ffl----p~:9-:o~ f!!:r_ 13.
Produced by: John Mcconney
Requeslor: RAY DOYLE
Project Leader: DOYLE . DIOXIN SCAN
Facility: REASOR CHEMICAL
Program: NSF
Id/Station: RCSS9901
Media: SOIL
RES UL TS UNITS ANAL YTE
CASTLE HAYNE, NC
D Number: SS99
2.3UR NG/KG 2,3,7,8-TETRACHLORODIBENZODIOXIN
2.3UR NG/KG TETRACHLORODIBENZODIOXIN (TOTAL)
5.7UR. NG/KG 1,2,3,7,8-PENTACHLORODIBENZODIOXIN
5.7UJ NG/KG PENTACHLORODIBENZODIOXIN (TOTAL)
SAS Number:DIOX
Org Contractor: SWOK
Beginning: 08/23/97 13:00
Ending:
5.7U NG/KG 1,2,3,4,7,8-HEXACHLORODIBENZODIOXIN
____ Q.6J_NG/KG-1,2,3,6,7,8-HEXACHlORODIBENZ0010XIN------~------------------------------
5.7U NG/KG 1,2,3,7,8,9-HEXACHLORODIBENZODIOXIN
6.8J NG/KG HEXACHLORODIBENZODIOXIN (TOTAL)
31 NG/KG 1,2,3,4,6,7,8-HEPTACHLORODIBENZODIOXIN
58J NG/KG HEPTACHLORODIBENZODIOXIN (TOTAL)
280J NG/KG OCTACHLORODIBENZODIOXIN
0.5J NG/KG 2,3,7,8-TETRACHLORODIBENZOFURAN
2.7J NG/KG TETRACHLORODIBENZOFURAN (TOTAL)
5:7U NG/KG 1,2,3,7,8-PENTACHLORODIBENZOFURAN
0. 7 J NG/KG 2,3,4, 7 ,8-PENTACHLORODIBENZOFURAN
5.9J NG/KG PENTACHLORODIBENZOFURAN (TOTAL)
5.7U NG/KG 1,2,3,4,7,8-HEXACHLORODIBENZOFURAN
5.7U NG/KG 1,2,3,6,7,8-HEXACHLORODIBENZOFURAN
5.7U NG/KG 1,2,3,7,8,9-HEXACHLORODIBENZOFURAN
0.9J NG/KG 2,3,4,6,7,8-HEXACHLORODIBENZOFURAN
6.0J NG/KG HEXACHLORODIBENZOFURAN (TOTAL)
6.3 NG/KG 1,2,3,4,6,7,8-HEPTACHLORODIBENZOFURAN
5.7U NG/KG 1,2,3,4,7,8,9-HEPTACHLORODIBENZOFURAN
18J NG/KG HEPTACHLORODIBENZOFURAN (TOTAL)
BJ NG/KG OCTACHLORODIBENZOFURAN
1.2J NG/KG TEO (TOXIC. EQUIV. VALUE, FROM I-TEF/89)
12 % % MOISTURE
A-average value. NA-not analyzed. NAl-interferences. J-estimiiled value. N-presumptive evidence of presence of material.
K-actual value is known to be less than value given. L-actual value is known to be greater than value given. U-material was analyzed for but not detected. the number is the minimum quantitation limit.
R-qc indicates that data unusable. compound may or may not be present. resampling and reanalysis is necessary for verification.
r.-r.onfinned by gems: 1.when no value is reported, see chlordane constituents 2.constituents or metabolites of technical chlordane
_llllli'UL•E~_ g'l.~~L Y~_ -~ __ --~ --~A~--!0~-~---7_
Sampl 881 FY 1997 .---------------------i Produced by: Denise Goddard
Requestor: RAY DOYLE
Projecl Leader: DOYLE
Beginning: 08/23/97 15:20
Ending:
VOLATILES SCAN
Facility: REASOR CHEMICAL
Program: NSF
Id/Station: RCSS10001
Media: SOIL
RESULTS UNITS ANALYTE
Project: 97-0357
CASTLE HAYNE, NC
Case Number: 25655
MD Number: MY24
D Number: MY52
12U UG/KG CHLOROMETHANE
12U UG/KG BROMOMETHANE
12U UG/KG VINYL CHLORIDE
12U UG/KG CHLOROETHANE
12U UG/KG METHYLENE CHLORIDE
lnorg Contractor: ARI
Org Contractor: AA TS
12U UG/KG ACETONE .. ~)R.&°=,---;-;---;-;=:-::-:===-::-::::::::------------------------------c-------12U UG/KG CARBON DISU)/IDE
-----12u-uG/KG-1~1=D1CHLORbETHENE (1. 1-DICHLOROETHYLENE)
12U UG/KG 1,1sDICHLOROETHANE
12U UG/KG 1,2-DICHLOROETHENE (TOTAL)
12U UG/KG CHLOROFORM
12U UG/KG 1,2-DICHLOROETHANE
12U UG/KG METHYL ETHYL KETONE
12U UG/KG 1,1,1-TRICHLOROETHANE
12U UG/KG CARBON TETRACHLORIDE
12U UG/KG BROMODICHLOROMETHANE
· 12U UG/KG 1,2-DICHLOROPROPANE
12U UG/KG CIS-1,3-DICHLOROPROPENE
12U UG/KG TRICHLOROETHENE (TRICHLOROETHYLENE)
12U UG/KG DIBROMOCHLOROMETHANE
12U UG/KG 1,1,2-TRICHLOROETHANE
12U UG/KG BENZENE
12U UG/KG TRANS-1,3-DICHLOROPROPENE
12U UG/KG BROMOFORM
12U UG/KG METHYL ISOBUTYL KETONE
12U UG/KG METHYL BUTYL KETONE
12U . UG/KG TETRACHLOROETHENE (TETRACHLOROETHYLENE)
12U UG/KG 1, 1,2,2-TETRACHLOROETHANE
12U UG/KG TOLUENE
12U UG/KG CHLOROBENZENE
12U UG/KG ETHYL BENZENE
12U UG/KG STYRENE
12U UG/KG TOTALXYLENES
15 % % MOISTURE
A-average value. NA-not analyzed. NAl-interferences. J-estimated value. N-presumptive evidence of presence of material.
K-actual value is 1-~ ·:~n to be less than value given. L-actual value is known to be greater than value gi· · U-materia/ was analyzed for but not detected. the number is the minimum quant:• ··,n limit.
R-qc indicates th i unusable. compound may or may not be present. resampling and reanalysis ~ssary for verification.
C-confirmed by 91. . : 1.whe~ no v~lue !~ reported, see chlordane constituents 2.constituents or meta!,. ._.:is of technical chlordane
... o~s ~t:E -~vs• -----IWA·--oN"""""'·ENf.l9--------A-.ied-:02.-.S11 .. --
. · --. • , -Produced by: Denise Goddard • ··
Requester: RAY DOYLE
~8-81 FY 1997 Project: 97-0357
MISCELLANEOUS COMPOUNDS
Facility: REASOR CHEMICAL
Program: NSF
Id/Station: RCSS10001
Media: SOIL
RESULTS UNITS ANALYTE
CASTLE HAYNE, NC
Case Number: 25655
MD Number: MY24
D Number: MY52
200J UG/KG 1 UNIDENTIFIED COMPOUND
lnorg Contractor: ARI
Org Contractor: AA TS
Project Leader: DOYLE
Beginning: 08/23/97 15:20
Ending:
A-average value. NA-not analyzed. NAl-interferences. J-estimated value. N-presumptive evidence of presence of material.
K-actual value is known to be less than value given. L-actual value is known to be greater than value given. LI-material was analyzed for but not detected. the nu~ber is the minimum quantitation limit.
R-qc indicates that data unusable. compound may or may not be present. resampling and reanalysis is necessary for verification.
C-confirmed by gans: 1.when no value is reported, see chlordane constituents 2.constituents or metabolites of te~tmical chlordane
-XTF-AB..,A~AN .. IS --IIWA --ON ~SD,.EN8 •~-------------,• ---1\-A,<-.M-..'> .. ,.,.,,, ... ,,u,i;.u .,_,g.,,i;;. l"'""',;;,u IL.JV
Sample 881 FY 1997 Project: 97-0357
EXTRACTABLES SCAN
Facility: REASOR CHEMICAL
Program: NSF
Id/Station: RCSS10001
Media: SOIL
CASTLE HAYNE, NC
Case Number: 25655
MD Number: MY24
D Number: MY52
lnorg Contractor: ARI
Org Contractor: AA TS
Produced by: Denise Goddard
Requester: RAY DOYLE
Project Leader: DOYLE
Beginning: 08/23/97 15:20
Ending:
RESULTS UNITS ANALYTE RESULTS UNITS ANALYTE
390U UG/KG PHENOL 390U UG/KG 4-CHLOROPHENYL PHENYL ETHER
390U UG/KG BIS(2-CHLOROETHYL) ETHER 390U UG/KG FLUORENE
390U UG/KG 2-CHLOROPHENOL 980U UG/KG 4-NITROANILINE
390U UG/KG 1,3-DICHLOROBENZENE 980U UG/KG 2-METHYL-4,6-DINITROPHENOL
390U UG/KG 1,4-DICHLOROBENZENE 390U UG/KG N-NITROSODIPHENYLAMINE/DIPHENYLAMINE
____ 390U_UG/KG_1,2,DICHLOROBENZENE,---------------390UJ-UG/KG-4°BROMOPHENYL:-PHENYL:-ETHER' ________ _
390U UG/KG 2-METHYLPHENOL 390U UG/KG HEXACHLOROBENZENE (HCB)
390U UG/KG BIS(2-CHLOROISOPROPYL) ETHER 980U UG/KG PENTACHLOROPHENOL
390U UG/KG (3-AND/OR 4-)METHYLPHENOL 390U UG/KG PHENANTHRENE
390U UG/KG N-NITROSODI-N-PROPYLAMINE 390U UG/KG ANTHRACENE
390U UG/KG HEXACHLOROETHANE 390U UG/KG CARBAZOLE
390U UG/KG NITROBENZENE 390U UG/KG DI-N-BUTYLPHTHALATE
390U UG/KG ISOPHORONE 390U UG/KG FLUORANTHENE
390U UG/KG 2-NITROPHENOL 390U UG/KG PYRENE
390UJ UG/KG 2,4-DIMETHYLPHENOL 390U UG/KG BENlYL BUTYL PHTHALA TE
390U UG/KG BIS(2-CHLOROETHOXY)METHANE 390U UG/KG 3,3'-DICHLOROBENZIDINE
390U UG/KG 2,4-DICHLOROPHENOL 390U UG/KG BENZO(A)ANTHRACENE
390U UG/KG 1,2,4-TRICHLOROBENZENE 390U UG/KG CHRYSENE
390U UG/KG NAPHTHALENE 390U UG/KG BIS(2-ETHYLHEXYL) PHTHALA TE
390U UG/KG 4-CHLOROANILINE 390U UG/KG DI-N-OCTYLPHTHALATE
390U UG/KG HEXACHLOROBUTADIENE 390U UG/KG BENZO(B AND/OR K)FLUORANTHENE
390U UG/KG 4-CHLORO-3-METHYLPHENOL 390U UG/KG BENZO-A-PYRENE
390U UG/KG 2-METHYLNAPHTHALENE 390U UG/KG INDENO (1,2,3-CD) PYRENE
390U UG/KG HEXACHLOROCYCLOPENTADIENE (HCCP) 390U UG/KG DIBENZO(A,H)ANTHRACENE
390U UG/KG 2,4,6-TRICHLOROPHENOL 390U UG/KG BENZO(GHl)PERYLENE
980U UG/KG 2,4,5-TRICHLOROPHENOL 15 % % MOISTURE
390U UG/KG 2-CHLORONAPHTHALENE
980U UG/KG 2-NITROANILINE
390U UG/KG DIMETHYL PHTHALATE
. 390U UG/KG ACENAPHTHYLENE
390U UG/KG 2,6-DINITROTOLUENE
980U UG/KG 3-NITROANILINE
390U UG/KG ACENAPHTHENE
980U UG/KG 2,4-DINITROPHENOL
980U UG/KG 4-NITROPHENOL
390U UG/KG DIBENZOFURAN
390U UG/KG 2,4-DINITROTOLUENE
390U UG/KG DIETHYL PHTHALATE
~
A-average value. NA-not analyzed. NAl-interferences. J-estimated value. N-presumptive evidence of presence of material.
K-actual value is k.. -_-., to be less than value given. L-actual value is known to be greater than value giv V-material was analyzed for but not detected. the number is the minimum quantit , limit.
R-qc indicates tha unusable. compound may or may not be present. resampling and reanalysis is >sary for verification.
r.-confrrmed by gcr1, ... --1.when no value is reported, s1:e chlordane constituents 2.constituents or metabo., __ .s of technical chlordane
~ I ~l:iliiiAMMWifN'llliil:; --
Sample .81 FY 1997 Project: 97.0357
MISCELLANEOUS COMPOUNDS
Facility: REASOR CHEMICAL
Program: NSF
Id/Station: RCSS10001
Media: SOIL
RESULTS UNITS ANALYTE
CASTLE HAYNE, NC
Case Number: 25655
MD Number: MY24
D Number: MY52
20000J UG/KG
2000J UG/KG
16 UNIDENTIFIED COMPOUNDS
ALKANES
~ -ljiiiON lllilii-SDtlifiEN~ ---A--ed ... 0211!13 12-• ----------,· Produced by: Denise Goddard
lnorg Contractor: ARI
Org Contractor: AA TS
Requester: RAY DOYLE
Project Leader: DOYLE
Beginning: 08/23/97 15:20
Ending:
A-average value. NA-not analyzed. NAl-interferences. J-estimated value. N-presumptive evidence of presence of material.
K-actual value is known to be less than value given. L-actual value is known to be greater than value given. U-material was analyzed for but not detected. the number is the minimum quantitation limit.
R-qc indicates that data unusable. compound may or may not be present. resampling and reanalysis is necessary for verification.
C-confirmed by gems: 1.when no value is reported, see chlordane constituents 2.constituents or metabolites of technical chlordane
_,ET_,;A~ AN...,IS ----A --IONllilll:S°""9-{ENll!llt\ ---Prllllltion-: 11-7 1J.ll!I ------------------j■-~--------~--~•---Sample 881 FY 1997 Project: 97-0357 Produced by: Keith Bates
METALS SCAN Requestor: RAY DOYLE
Facility: REASOR CHEMICAL
Program: NSF
Id/Station: RCSS10001
Media: SOIL
RESULTS UNITS ANALYTE
0.1 ?U MG/KG SILVER
0.43U MG/KG ARSENIC
4.7J MG/KG BARIUM
1 U MG/KG BERYLLIUM
0.07J MG/KG CADMIUM
CASTLE HAYNE, NC
Case Numher: 25655
MD Number: MY24
D Number: MY52
lnorg Contractor: ARI
Org Contractor: AA TS
Project Leader: DOYLE
Beginning: 08123197 15:20
Ending:
0.30U MG/KG COBALT _ _:__ _ _: ________________________ ~-------:~-~--------c----_____ 2U_MGIKG-CHROMIUM-
3.6J MG/KG COPPER
0. 78U MG/KG NICKEL
6.4J MG/KG LEAD
1 UJ MG/KG ANTIMONY
0.52UJ MG/KG SELENIUM
0.74U MG/KG THALLIUM
2.3J MG/KG VANADIUM
3.7U MG/KG ZINC
0.05U MG/KG TOTAL MERCURY
1300 MG/KG ALUMINUM
3UJ MG/KG MANGANESE
200J MG/KG CALCIUM
50UJ MG/KG MAGNESIUM
560 MG/KG IRON
-50 MG/KG SODIUM
71J MG/KG POTASSIUM
13 % % MOISTURE
A-average value. NA-not analyzed. NAl-interferences. J-estimated value. N-presumplive evidence of presence of material.
K-actual value is !< '. ·•n to be less than value given. L-actual value is known to be greater than value !i U-material was analyzed for but not detected. the number is the minimum qua,,
R-:<ic indicates th . l unusable. compound may or may not be present. resampling and reanalysis , ~ssary for verification.
C-confirmed by gc, ..... .-1.when no value is report~d~ see chlordane constituents 2.i;:onstituent~ or m~tab1.r11~es of technical chlord?ne
'n limit.
-LA~LS·~IE...,A~AN-IS --A--ON---""',-EN ... ---P,clllaion-:11.1111712---~s-·\-----------~-------------• Sample ._H81 FY 1997 Project: 97-0357 Produced by: Keith Bales
SPECIFIED TESTS
Facility: REASOR CHEMICAL
Program: NSF
ld/Slalion: RCSS10001
Media: SOIL
RESULTS UNITS
0.13U MG/KG
ANALYTE
CYANIDE
CASTLE HAYNE, NC
Case Number: 25655
MD Number: MY24
D Number: MY52
lnorg Contractor: ARI
Org Contractor: AA TS
A-average value. NA-not analyzed. NAl-interferences. J-estimated value. N-presumptive evidence of presence of material.
Requestor: RAY DOYLE
Project Leader: DOYLE
Beginning: 08/23/97 15:20
Ending:
K-actual value is known to be less than value given. L-actual value is known to be greater than value given. U-material was analyzed for but not detected. the number is the minimum quantltation limit.
R--qc indicates that data unusable. compound may·or may not be present. resampling and reanalysis is necessary for verification.
C-confirmed by gems: 1.when no value is reported, see chlordane constituents 2.constituenls or metabolites of technical chlordane
-u.x.1 .. AM1iiirN'11i11ilS ---IIIF, --.ON -S□,-EN~ ---Prollllon -12/-13. ----:=.--------------------j • ._-------------~•----Sample .31 FY 1997 Project: 97-0370 Produced by: John Mcconney DIOXIN SCAN Requeslor: RAY DOYLE
Facility: REASOR CHEMICAL
Program: NSF
CASTLE HAYNE, NC
Id/Station: RCSS 10001
Media: SOIL D Number: SS 100
RES UL TS UNITS ANAL YTE
2.3UR
5,SJ
5.BUR
5.BUJ
5.BU
5.BU
5.BU
O.BJ
2.3J
6.5J
31J
2.3U
3.7J
5.BU
5.BUR
5.BUJ
5.BU
5.BU
5.BU
5.BUR
5.BUJ
5.BU
5.BU
O.BJ
12U
0.1J
14
NG/KG
NG/KG
NG/KG
NG/KG
NG/KG
NG/KG
NG/KG
NG/KG
NG/KG
NG/KG
NG/KG
NG/KG
NG/KG
NG/KG
NG/KG
NG/KG
NG/KG
NG/KG
NG/KG
NG/KG
NG/KG
NG/KG
NG/KG
NG/KG
NG/KG
NG/KG
%
2,3, 7 ,8-TETRACHLORODIBENZODIOXIN
TETRACHLORODIBENZODIOXIN (TOTAL)
1,2,3, 7,8-PENTACHLORODIBENZODIOXIN
PENTACHLORODIBENZODIOXIN (TOTAL) 1,2,3,4,7,8-HEXACHLORODIBENZODIOXIN
· 1,2,3,6, 7,8-HEXACHLORODIBENZODIOXIN
1,2,3, 7 ,8,g-HEXACHLORODIBENZODIOXIN
HEXACHLORODIBENZODIOXIN (TOTAL)
1,2,3,4,6, 7,8-HEPTACHLORODIBENZODIOXIN
HEPTACHLORODIBENZODIOXIN (TOTAL)
OCTACHLORODIBENZODIOXIN
2,3,7,8-TETRACHLORODIBENZOFURAN
TETRACHLORODIBENZOFURAN (TOTAL)
1,2,3, 7 ,8-PENTACHLORODIBENZOFURAN
2,3,4, 7 ,8-PENTACHLORODIBENZOFURAN
PENTACHLORODIBENZOFURAN (TOTAL) 1,2,3,4,7,8-HEXACHLORODIBENZOFURAN
1,2,3,6, 7,8-HEXACHLORODIBENZOFURAN
1,2,3, 7,8,9-HEXACHLORODIBENZOFURAN
2,3,4,6,7,8-HEXACHLORODIBENZOFURAN
HEXACHLORODIBENZOFURAN (TOTAL)
1,2,3,4,6, 7 ,8-HEPTACHLORODIBENZOFURAN
1,2,3,4,7,8,9-HEPTACHLORODIBENZOFURAN
HEPTACHLORODIBENZOFURAN (TOTAL)
OCTACHLORODIBENZOFURAN
TEQ (TOXIC. EQUIV. VALUE, FROM I-TEF/89)
% MOISTURE
SAS Number:DIOX
Org Contractor: SWOK
A-average value. NA-not analyzed. NAl-interferences. J-estimated value. N-presumptive evidence of presence of material.
Project Leader: DOYLE
Beginning: 08/23/97 15:00
Ending:
K-actual value is kr ':'l to be less than value given. L-actual value is known to be greater than value gi• U-malerial was analyzed for but not detected. the number is the minimum quant' , limit. R-qc iridicates th< unusable. compound may or may not be present. resampling and reanalysis i; ssary for verification. c-confinned by gc. .. ·1.when no v~!u~ is reported, see chl9fd~ne co~s_~iluents 2.~n~tituents or meta~~":"'s of t~~~l~I chlordane
-ES SIIJlll3Ar..a1AN .. IS ---A--ON~"J;)-EN----Prclllaion-:1iali71clllll
~d1--F-Y~1_9_9_7 __ P_ro_j-ect-: _9_7_-0_3_5_7------------i· _______ P_ro_d_u_ce_d_b_y_: J_o_h_n_M-cC-o-nn_e_y------~•
PESTICIDES SCAN Requestor: RAY DOYLE
Project Leader: DOYLE
Facility: REASOR CHEMICAL CASTLE HAYNE, NC Beginning: 08/23/97 15:20
Program: NSF Case Number: 25555·
ld/Station:RCSS10001 MD Number. MY24
Media: SOIL D Number: MY52
RES UL TS UNITS
2.0U UG/KG
2.0U UG/KG
2.0U UG/KG
2.0U UG/KG
2.0U UG/KG
2.0U UG/KG
2.0U UG/KG
2.0U UG/KG
3.9U UG/KG
3.9U UG/KG
3.9U UG/KG
3.9U UG/KG
3.9U UG/KG
3.9U UG/KG
3.9U UG/KG
20U UG/KG
3.9U UG/KG
3.9U UG/KG
2.0U UG/KG
2.0U UG/KG
200U UG/KG
39U UG/KG
79U UG/KG
39U UG/KG
39U UG/KG
39U UG/KG
39U UG/KG
39U UG/KG
15 %
ANALYTE
ALPHA-BHC
BETA-BHC
DELTA-BHC
GAMMA-BHC (LINDANE)
HEPTACHLOR
ALDRIN
HEPTACHLOR EPOXIDE
ENDOSULFAN I (ALPHA)
DIELDRIN
4,4'-DDE (P,P'-DDE)
ENDRIN
ENDOSULFAN II (BETA)
4.4'-000 (P,P'-000)
ENDOSULFAN SULFATE
4,4'-DDT (P ,P'-001)
METHOXYCHLOR
ENDRIN KETONE
ENDRIN ALDEHYDE
ALPHA-CHLORDANE /2
GAMMA-CHLORDANE /2
TOXAPHENE
PCB-1016 (AROCLOR 1016)
PCB-1221 (AROCLOR 1221)
PCB-1232 (AROCLOR 1232)
PCB-1242 (AROCLOR 1242)
PCB-1248 (AROCLOR 1248)
PCB-1254 (AROCLOR 1254)
PCB-1260 (AROCLOR 1260)
% MOISTURE
lnorg Contractor: ARI
Org Contractor: AA TS
A-average value. NA-not analyzed. NAl-interferences. J-estimated value. N-presumptive evidence of presence of material.
Ending:
K-actual value is known to be less than value given. L-actual value is known to be greater than value given. U-malerial was analyzed for but not detected. the number is the minimum quantitation limit.
R-qc indicates that data unusable. compound may or may not be present. resampling and reanalysis is necessary for verification.
C-confinned by gems: 1.when no value is reported, see chlordane constituents 2.constituen.ts or metabolites of technical chlordane
.... O~ES...,L~LY---..,A .... IOra.,=~-HErlllllA ---allaide-e:0~81-----· _' -------'----------,---i. -----------.• Sampl-2882 FY 1997 Project: 97-0357 Produced by: Denise Goddard
VOLATILES SCAN Requestor. RAY DOYLE
Facility: REASOR CHEMICAL
Program: NSF
CASTLE HAYNE, NC
Case Number: 25655
MD Number: MY25 Id/Station: RCSS10101 lnorg Contractor: ARI
Org Contractor: AA TS Media: SOIL
RES UL TS UNITS
12U UG/KG
12U UG/KG
12U UG/KG
12U UG/KG
12U UG/KG
12U UG/KG
12U UG/KG
12U UG/KG
12U UG/KG
12U UG/KG
12U UG/KG
12U UG/KG
12U UG/KG
12U UG/KG
12U UG/KG
12U UG/KG
12U UG/KG
12U UG/KG
12U UG/KG
12U UG/KG
12U UG/KG
12U UG/KG
12U UG/KG
12U UG/KG
12U UG/KG
12U UG/KG
12U UG/KG
12U UG/KG
12U UG/KG
12U UG/KG
12U UG/KG
12U UG/KG
12U UG/KG
14 %
D Number: MY53
ANALYTE
CHLOROMETHANE
BROMOMETHANE
VINYL CHLORIDE
CHLOROETHANE
METHYLENE CHLORIDE
ACETONE
CARBON DISULFIDE
1, 1-DICHLOROETHENE (1, 1-DICHLOROETHYLENE)
1, 1-DICHLOROETHANE
.1,2-DICHLOROETHENE (TOTAL)
CHLOROFORM
1,2-DICHLOROETHANE
METHYL ETHYL KETONE
1, 1, 1-TRICHLOROETHANE
CARBON TETRACHLORIDE
BROMODICHLOROMETHANE
1,2-DICHLOROPROPANE
CIS-1,3-DICHLOROPROPENE
TRICHLOROETHENE (TRICHLOROETHYLENE)
DIBROMOCHLOROMETHANE
1, 1,2-TRICHLOROETHANE
BENZENE
TRANS-1,3-DICHLOROPROPENE
BROMOFORM
METHYL ISOBUTYL KETONE
METHYL BUTYL KETONE _
TETRACHLOROETHENE (TETRACHLOROETHYLENE)
1, 1,2,2-TETRACHLOROETHANE
TOLUENE .
CHLOROBENZENE
ETHYL BENZENE
STYRENE
TOTAL XYLENES
%MOISTURE
A-a·verage value. NA-not a·nalyzecl. NAl-interferences. J--eslimated value. N-presumptive evidence of presence of material.
Project Leader: DOYLE
Beginning: 08/23/97 15:20
Ending:
K-actual value is known to be less than value given. L-actual value is known to be greater than value given. U-material was analyzed for but not detected. the number is the minimum quantitation limit.
R-qc indicates that data unusable. compound may or may not be present. resampling and reanalysis is necessary for verification.
r.-r.onfirmed by gems: 1.when no value is reported, see c~lordane constituents 2.constituents or metabolites of technical chlordane
liiiii iiiii llililA --ON llliiJSD,MENlililt
Sample 882 FY 1997 Project: 97-0357
MISCELLANEOUS COMPOUNDS
Facility: REASOR CHEMICAL CASTLE HAYNE, NC
Program: NSF Case Number: 25655
Id/Station: RCSS10101 MD Number: MY25
Media: SOIL D Number: MY53
RESULTS UNITS ANALYTE
100J UG/KG 1 UNIDENTIFIED COMPOUND
lnorg Contractor: ARI
Org Contractor: AA TS
A-average value. NA-not analyzed. NAl-interferences. J-estimated value. N-presumptive evidence of presence of material.
--Produced by: Denise Goddard
Requester: RAY DOYLE
Project leader: DOYLE
Beginning: 08/23/97 15:20
Ending:
K-actual value is 1r--~:..,n to be less than value given. L-actual value is known to be greater than value giv,...,, U-material was analyzed for but not detected. the number is the minimum quanti•--•ion limit.
R-qc indicates th 3 unusable. compound may or may not be present. resampling and reanalysis i ?ssary for verification.
,... -r:onfirmed by g... . ; 1.when no value is reported, see chlordane constituents 2.constituentS or metaL ~S of technical chlordane
em<T"'R.,..""'l.8'-5iiiiiaAM1iiiiiAN .. IS -liill ~ -falla>N -SD,-EN~ ---A-ed -02/111112-
Sample .o-o-'-82--FY--1-9_9_7 __ P_r_oJ-.e-ct_:_9_7_..0_3_5_7 ___________ -l.t--------P-ro_d_u_ce_d_b_y_:_D~e-ni_s_e~G~o-d-da_r_d _______ l-----
EXTRACTABLES SCAN
Facility: REASOR CHEMICAL
Program: NSF
CASTLE HAYNE, NC
Case Number: 25655
MD Number: MY25 Id/Station: RCSS10101
Media: SOIL
RESULTS UNITS
380U
380U
380U
380U
380U
380U
380U
380U
380U
380U
380U
380U
380U
380U
380UJ
380U
380U
380U
380U
380U
380U
380U
380U
380U
380U
960U
380U
960U
380U
380U
380U
960U
380U.
960U
960U
380U
380U
®380U
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
D Number: MY53
ANALYTE
PHENOL .
BIS(2-CHLOROETHYL) ETHER
2-CHLOROPHENOL
1,3-DICHLOROBENZENE
1,4-DICHLOROBENZENE
1,2-DICHLOROBENZENE
2-METHYLPHENOL
BIS(2-CHLOROISOPROPYL) ETHER
(3-AND/OR 4-)METHYLPHENOL
N-NITROSODI-N-PROPYLAMINE
HEXACHLOROETHANE
NITROBENZENE
ISOPHORONE
2-NITROPHENOL
2,4-DIMETHYLPHENOL
BIS(2-CHLOROETHOXY)METHANE
2,4-DICHLOROPHENOL
1,2,4-TRICHLOROBENZENE
NAPHTHALENE
4-CHLOROANILINE
HEXACHLOROBUTADIENE
4-CHLORO-3-METHYLPHENOL
2-METHYLNAPHTHALENE
HEXACHLOROCYCLOPENTADIENE (HCCP)
2,4,6-TRICHLOROPHENOL
2,4,5-TRICHLOROPHENOL
2-CHLORONAPHTHALENE
2-NITROANILINE
DIMETHYL PHTHALATE
ACENAPHTHYLENE
2,6-DINITROTOLUENE
3-NITROANILINE
ACENAPHTHENE
2,4-DINITROPHENOL
4-NITROPHENOL
DIBENZOFURAN
2,4-DINITROTOLUENE
DIETHYL PHTHALATE
lnorg Contractor: ARI
Org Contractor: AA TS
Requestor: RAY DOYLE
Project Leader: DOYLE
Beginning: 08/23/97 15:20
Ending:
RESULTS UNITS ANALYTE
380U UG/KG
380U UG/KG
960U UG/KG
960U UG/KG
380U UG/KG
380UJ UG/KG
380U UG/KG
960U UG/KG
380U UG/KG
380U UG/KG
380U UG/KG
380U UG/KG
380U UG/KG
380U UG/KG
380U UG/KG
380U UG/KG
380U UG/KG
380U UG/KG
380U UG/KG
380U UG/KG
380U UG/KG
380U UG/KG
380U UG/KG
380U UG/KG
380U UG/KG
14 %
4-CHLOROPHENYL PHENYL ETHER
FLUORENE
4-NITROANILINE
2-METHYL-4,6-DINITROPHENOL
N-NITROSODIPHENYLAMINE/DIPHENYLAMINE
4-BROMOPHENYL PHENYL ETHER
HEXACHLOROBENZENE (HCB)
PENTACHLOROPHENOL
PHENANTHRENE
ANTHRACENE
CARBAZOLE
DI-N-BUTYLPHTHALA TE
FLUORANTHENE
PYRENE
BENZVLBUTYLPHTHALATE
3,3'-DICHLOROBENZIDINE
BENZO(A)ANTHRACENE
CHRYSENE
BIS(2-ETHYLHEXYL) PHTHALA TE
DI-N-OCTYLPHTHALA TE
BENZO(B AND/OR K)FLUORANTHENE
BENZO-A-PYRENE
INDENO (1,2,3-CD) PYRENE
DIBENZO(A,H)ANTHRACENE
BENZO(GHl)PERYLENE
% MOISTURE
A-average value. NA-not analyzed. NAl-interferences. J-estimated value. N-presumptive evidence of presence of material.
K-actual value is kr .. ·_..,to be less than value given. L-actual value is known to be greater than value giv,.. U-material was analyzed for but not detected. the number is the minimum quantit ... , limit.
R-qc indicates tha unusable. compound may or may not be present. resampling and reanalysis i~ ssary for verification.
C-confirmed by gc. ... , .· 1.when no value is reported, see chlordane ~nstituents 2.constituents or metabl. _; of technical chlordane
lllifTRtiii"BL~MilitN~S --
Sample .82 FY 1997 Project: 97--0357
MISCELLANEOUS COMPOUNDS
Facility: REASOR CHEMICAL
Program: NSF
Id/Station: RCSS10101
Media: SOIL
RESULTS UNITS ANALYTE
CASTLE HAYNE, NC
Case Number: 25655
MD Number: MY25
D Number. MY53
10000J UG/KG 10 UNIDENTIFIED COMPOUNDS
2000J UG/KG ALKANES
llill'-PMf>N l'ilili"'". eMf:N51M1 •
lnorg Contractor: ARI
Org Contractor: AA TS
- -Produced by: Denise Goddard
Requestor. RAY DOYLE
Project Leader: DOYLE
Beginning: 08/23/97 15:20
Ending:
A-average vatue. NA-not analyzed. NAl-interferences. J-estimated value. N-presumptive evidence of presence of material. .
K-actual value is known to be less than value given. L-actual value is known to· be greater than value given. LI-material was analyzed for but not detected. the number is the minimum quantitation limit:
R-qc indicates that data unusable. compound may or may not be present. resampling and reanalysis is necessary for verification.
C-confirmed by gems: 1.when no value is reported, see chlordane constituents 2.constituents or metabolites of technical chlordane
-Sample 12882 FY 1997 Project: 97 -0357
METALS SCAN
Facility: REASOR CHEMICAL
Program: NSF
Id/Station: RCSS10101
Media: SOIL
RESULTS UNITS ANALYTE
0.18U MG/KG SILVER
0.44U MG/KG ARSENIC
3UJ MG/KG BARIUM
1U MG/KG BERYLLIUM
0.07U MG/KG CADMIUM
0.31U MG/KG COBALT
3U MG/KG CHROMIUM
2.2J MG/KG COPPER
0.80U MG/KG NICKEL
4.SJ MG/KG LEAD
1UJ MG/KG ANTIMONY
0.53UJ MG/KG SELENIUM
0.75U MG/KG THALLIUM
2.1J MG/KG VANADIUM
3.7U MG/KG ZINC
CASTLE HAYNE, NC
Case Number: 25655
MD Number: MY25
D Number: MY53
0.05U MG/KG TOTAL MERCURY
1500 MG/KG ALUMINUM
1UJ MG/KG MANGANESE
170J MG/KG CALCIUM
30UJ MG/KG MAGNESIUM
620 MG/KG IRON
69 MG/KG SODIUM
49J MG/KG POTASSIUM
13 % % MOISTURE
lnorg Contractor: ARI
Org Contractor: AA TS
A-average value. NA-not analyzed. NAl-interferences. J--estimated value. N-presumptive evidence of presence of material.
-Produced by: Keith Bates
Requester: RAY DOYLE
Project Leader: DOYLE
Beginning: 08123197 15:20
Ending:
71-t9
K-actual value is known to be less than value given. L-actual value is known to be greater than value given. U-material was analyzed for but not detected. the number is the minimum quantitation limit.
R-qc indicates that data unusable. compound may or may not be present. resampling and reanalysis is necessary for verification.
,..... ,..onfinned by gems: 1.when no value is reported, see chlordane constituents 2.constituents or metabolites or technical chlordane
Sampl 2882 FY 1997
SPECIFIED TESTS
Facility: REASOR CHEMICAL
Program: NSF
Id/Station: RCSS 10101
Media: SOIL
RES UL TS UNITS
0.13U MG/KG
ANALYTE
CYANIDE
..,A--IOralliES-HE,...A --Project: 97-0357
CASTLE HAYNE, NC
Case Number: 25655
MD Number: MY25
D Number: MY53
lnorg Contractor: ARI
Org Contractor: AA TS
Produced by: Keith Bates
Requester: RAY DOYLE
Project Leader: DOYLE
Beginning: 08/23/97 15:20
Ending:
A-average value. NA-not analyzed. NAl-interferences. J-estimated value. N-presurnptive evidence of presence of material. K-actual value is 1--·;--wn to be less than value given. L-actual value is known to be greater than value,.· '. U-material was analyzed for but not detected. the number is the minimum qua· R-qc indicates ti !a unusable. compound may or may not be present. resampling and reanalysis ;essary for verification. r:-confirmed by Q~ . .:' 1.when no valu~ is reported, see chlordane constituents 2.constituents or metav .... o1tes of technical chlord_ane
·,n limit.
-Dlciiiiii S 6 E l\ .. Sl!:ali --~PA-,I0 ,~,s IHElllll,A ---i:a.cticallte: -/97 -
~30,32 FY 1997 Project: 97-0370
DIOXIN SCAN
Facility: REASOR CHEMICAL
Program: NSF
CASTLE HAYNE, NC
ld/Slation: RCSS10101
Media: SOIL
RESULTS
2.3UR
2.6J
5.7UR
1.6J
5.7U
5.7U
5.7U
1.7J
1.8J
5.7J
24J
2.3U
3.8J
5.7U
5.7UR
5.7UJ
5.7U
5.7U
5.7U
5.7UR
5.7UJ
5.7U
5.7U
5.7UJ
11 U
0.04J
13
UNITS
NG/KG
NG/KG
NG/KG
NG/KG
NG/KG
NG/KG
NG/KG
NG/KG
NG/KG
NG/KG
NG/KG
NG/KG
NG/KG
NG/KG
NG/KG
NG/KG
NG/KG
NG/KG
NG/KG
NG/KG
NG/KG
NG/KG
NG/KG
NG/KG
NG/KG
NG/KG
%
D Number: SS101
ANALYTE
2,3,7,8-TETRACHLORODIBENZODIOXIN
TETRACHLORODIBENZODIOXIN (TOTAL)
1,2,3,7,8-PENTACHLORODIBENZODIOXIN
PENTACHLORODIBENZODIOXIN (TOTAL)
1,2,3,4, 7,8-HEXACHLORODIBENZODIOXIN
1,2,3,6,7,8-HEXACHLORODIBENZODIOXIN
1,2,3,7,8,9-HEXACHLORODIBENZODIOXIN
HEXACHLORODIBENZODIOXIN (TOTAL)
1,2,3,4,6,7,8-HEPTACHLORODIBENZODIOXIN
HEPTACHLORODIBENZODIOXIN (TOTAL)
OCTACHLORODIBENZODIOXIN
2,3,7,8-TETRACHLORODIBENZOFURAN
TETRACHLORODIBENZOFURAN (TOTAL)
1,2,3,7,8-PENTACHLORODIBENZOFURAN
2,3,4,7,8-PENTACHLORODIBENZOFURAN
PENTACHLORODIBENZOFURAN (TOTAL)
1,2,3,4,7,8-HEXACHLORODIBENZOFURAN
1,2,3,6, 7,8-HEXACHLORODIBENZOFURAN.
1,2,3, 7 ,8,9-HEXACHLORODIBENZOFURAN
2,3,4,6,7,8-HEXACHLORODIBENZOFURAN
HEXACHLORODIBENZOFURAN (TOTAL)
1,2,3,4,6,7,8-HEPTACHLORODIBENZOFURAN
1,2,3,4, 7 ,8,9-HEPTACHLORODIBENZOFURAN
HEPTACHLORODIBENZOFURAN (TOTAL)
OCTACHLORODIBENZOFURAN
TEO (TOXIC. EQUIV. VALUE, FROM I-TEF/89)
% MOISTURE
• ~' --~----• Produced by: John Mcconney
SAS Number:DIOX
Org Contractor: SWOK
Requester: RAY DOYLE
Project Leader: DOYLE
Beginning: 08/23/97 15:20
Endiiig:
A-average value. NA-not analyzed. NAl-interferences. J-estimated value. N-presumptive evidence of presence of material.
K-actual value is known to be less than value given. L-actual value is known to be greater than value given. U-material was analyzed for but not detected. the number is the minimum quantitation limit.
R-qc indicates that data unusable: compound may or may not be present. resampling and reanalysis is necessary for verification.
C-confirmed by gems: 1.when no value is reported, see chlordane con_stituenls 2.constituents or metabolites of technical chlordane
Sample 882 FY 1997 Project: 97 --0357
PESTICIDES SCAN
Facility: REASOR CHEMICAL
Program: NSF
CASTLE HAYNE, NC
Case Number. 25655
MD Number: MY25 Id/Station: RCSS10101
Media: SOIL
RESULTS
2.0U
2.0U
2.0U
2.0U
2.0U
2.0U
2.0U
2.0U
3.8U
3.8U
3.8U
3.8U
3.8U
3.BU
3.8U
20U
3.8U
3.8U
2.0U
2.0U
200U
38U
78U
38U
38U
38U
38U
38U
14
UNITS
UGIKG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
%
D Number: MY53
ANALYTE
ALPHA-BHC
BETA-BHC
DELTA-BHC
GAMMA-BHC (LINDANE)
HEPTACHLOR
ALDRIN
HEPTACHLOR EPOXIDE
ENDOSULFAN I (ALPHA)
DIELDRIN
4,4'-DDE (P,P'-DDE)
ENDRIN
ENDOSULF AN II (BETA)
4.4'-DDD (P,P'-DDD)
ENDOSULFAN SULFATE
. 4.4'-DDT (P,P'-DDT)
METHOXYCHLOR
ENDRIN KETONE
ENDRIN ALDEHYDE
ALPHA-CHLORDANE /2
GAMMA-CHLORDANE /2
TOXAPHENE
PCB-1016 (AROCLOR 1016)
PCB-1221 (AROCLOR 1221)
PCB-1232 (AROCLOR 1232)
PCB-1242 (AROCLOR 1242)
PCB-1248 (AROCLOR 1248)
PCB-1254 (AROCLOR 1254)
PCB-1260 (AROCLOR 1260)
% MOISTURE
lnorg Contractor: ARI
Org Contractor: AA TS
-Produced by: John McConney
Requester: RAY DOYLE
Project Leader: DOYLE
Beginning: 08/23/97 15:20
Ending:
A-average value. NA-not analyzed. NAl-interferences. J-estlmated value. N-presumptive evidence of presence of material.
K-actual value is )c>·-_-.,.n to be less than value given. L-actual value is known to be greater than value gi·-· .. U-material was analyzed for but not detected. the number is the minimum quan1 .. ·•.,n limit.
R-qc indicates th J unusable. compound may or may not be present. resampling and reanalysis essary for verification.
C-confirmed by QL · 1.when no value is reported, see chlorc:t3ne constituents 2.constituents or metal. .... ~s ~f t~chnical chlordane
l!!!!eoL~S sC::ILE ==-Ysllll a; liliil
Sample 905 FY 1997 Project: 97-0357
VOLATILES SCAN
Facility: REASOR CHEMICAL CASTLE HAYNE, NC
. Program: NSF Case Number: 25655
Id/Station: RCSS10201
Media: SOIL D Number: MY54
RESULTS UNITS ANALYTE
CHLOROMETHANE
BROMOMETHANE
VINYL CHLORIDE
CHLOROETHANE
METHYLENE CHLORIDE
ACETONE
CARBON DISULFIDE
Org Contractor: AA TS
12U
12U
12U
12U
12U
12U
12U
12U
12U
12U
12U
12U
12U
12U
12U
12U
12U
12U
12U
12U
12U
12U
12U
12U
12U
12U
12U
12U
12U
12U
12U
12U
12U
15
UG/KG
UG/KG
UG/KG
UG/KG ·
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UGIKG
UG/KG
UGIKG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
%
1, 1-DICHLOROETHENE (1, 1-DICHLOROETHYLENE)
1, 1-DICHLOROETHANE
1,2-DICHLOROETHENE (TOTAL)
CHLOROFORM
1,2-DICHLOROETHANE
METHYL ETHYL KETONE
1, 1, 1-TRICHLOROETHANE
CARBON TETRACHLORIDE
BROMODICHLOROMETHANE
1,2-DICHLOROPROPANE
CIS-1,3-DICHLOROPROPENE
TRICHLOROETHENE (TRICHLOROETHYLENE)
DIBROMOCHLOROMETHANE
1, 1,2-TRICHLOROETHANE
BENZENE
TRANS-1,3-DICHLOROPROPENE
BROMOFORM
METHYL ISOBUTYL KETONE
METHYL BUTYL KETONE
TETRACHLOROETHENE (TETRACHLOROETHYLENE)
1, 1,2,2-TETRACHLOROETHANE
TOLUENE
CHLOROBENZENE
ETHYL BENZENE
STYRENE
TOTAL XYLENES
% MOISTURE
-Produced by: Denise Goddard
Requester: RAY DOYLE
Project Leader. DOYLE
Beginning: 08/23/97 15:40
Ending:
A-average value. NA-not analyzed. NAl-interferences. J-estimated value. N-presumptive evidence of presence of material.
K-actual value i' · ·,m to be less than value given. L-actual value is known to be greater than value ,.· '\. LJ-material was analyzed for but not detected. the number is the minimum quanti•1tion limit.
R-qc indicates t ita unusable. compound may or may not be present. resampling and reanalysi~ :essary for verification.
r:-confi~ed by gw1s: 1.when no valu~ is report~, see chlo~~ane constituents 2.~ns~ituents or met;;._ .,ce~ of !~chnical chlordane
-OLA I :l~s , li.'Lea.L Yiiiili --
~2905 FY 1997 Project: 97-0357
MISCELLANEOUS COMPOUNDS
Fa50ility: REASOR CHEMICAL
Program: NSF
Id/Station: RCSS10201
Media: SOIL
RESULTS UNITS ANALYTE
CASTLE HAYNE, NC
Case Number: 25655
D Number: MY54
90J UG/KG 1 UNIDENTIFIED COMPOUND
Org Contractor: AA TS
A-average value. NA-not analyzed. NAl-interferences. J-estimated value. N-presumptive evidence of presence of material.
---Produced by: Denise Goddard
Requestor: RAY DOYLE
Project Leader: DOYLE
Beginning: 08/23/97 15:40
Ending:
K-actual value is known to be less than value given. L-actual value is known to be greater than value given. U-material was analyzed for but not detected. the number is the minimum quantitation limit.
R-qc indicates that data unusable. compound may or may not be present. resampling and reanalysis is necessary for verification.
C-confinned by gems: 1.when no value is reported, see chlordane constituents 2.constituents or metabolites of technical chlordane
aia<TRlliif.Bl,-llilAMflllr.NAliaS --
~05 FY 1997 Project: 97-0357
~-1911J)Ni_.,ri,.a:NSIIII ---ArJlllledllal02/-12-
EXTRACTABLE$ SCAN
Facility: REASOR CHEMICAL
Program: NSF
CASTLE HAYNE, NC
Case Number: 25655
Id/Station: RCSS10201
Media: SOIL
RESULTS
390U
390U
390U
390U
390U
390U
390U
390U
390U
390U
390U
390U
390U
390U
390UJ
390U
390U
390U
390U
390U
390U
390U
390U
390U
390U
980U
390U
9B0U-
390U
390U
390U
9B0U
390U
980U
980U
390U
~390U
,~390U
UNITS
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
D Number: MY54
ANALYTE
PHENOL
BIS(2-CHLOROETHYL) ETHER
2-CHLOROPHENOL
1,3-DICHLOROBENZENE
1,4-DICHLOROBENZENE
1,2-DICHLOROBENZENE
2-METHYLPHENOL
BIS(2-CHLOROISOPROPYL) ETHER
(3-AND/OR 4-)METHYLPHENOL
N-NITROSODI-N-PROPYLAMINE
HEXACHLOROETHANE
NITROBENZENE
ISOPHORONE
2-NITROPHENOL
2,4-DIMETHYLPHENOL
BIS(2-CHLOROETHOXY)METHANE
2,4-DICHLOROPHENOL
1,2,4-TRICHLOROBENZENE
NAPHTHALENE
4-CHLOROANILINE
HEXACHLOROBUTADIENE
4-CHLORO-3-METHYLPHENOL
2-METHYLNAPHTHALENE
HEXACHLOROCYCLOPENTADIENE (HCCP)
2,4,6-TRICHLOROPHENOL
2,4,5-TRICHLOROPHENOL
2-CHLORONAPHTHALENE
2-NITROANILINE
DIMETHYL PHTHALATE
ACENAPHTHYLENE
2,6-DINITROTOLUENE
3-NITROANILINE
ACENAPHTHENE
2,4-DINITROPHENOL
4-NITROPHENOL
DIBENZOFURAN
2,4-DINITROTOLUENE
DIETHYL PHTHALATE
• ______ ___,_
Produced by: Denise Goddard
Requestor: RAY DOYLE
Org Contractor: AA TS
RESULTS
390U
390U
980U
980U
390U
390UJ
J90U
9B0U
390U
390U
390U
390U
390U
390U
390U
390U
390U
390U
390U
390U
390U
390U
390U
390U
390U
15
Project Leader: DOYLE .
Beginning: 08/23/9_7 15:40
Ending:
UNITS
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UGIKG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
UG/KG
%
ANALYTE
4-CHLOROPHENYL PHENYL ETHER
FLUORENE
4-NITROANILINE
2-METHYL-4,6-DINITROPHENOL
N-NITROSODIPHENYLAMINE/DIPHENYLAMINE
4-BROMOPHENYL PHENYL ETHER
HEXACHLOROBENZENE (HCB)
PENTACHLOROPHENOL
PHENANTHRENE
ANTHRACENE
CARBAZOLE
D1-N-BUTYLPHTHALA TE
FLUORANTHENE
PYRENE
BENZYLBUTYLPHTHALATE
3,3'-DICHLOROBENZIDINE
BENZO(A)ANTHRACENE
CHRYSENE
BIS(2-ETHYLHEXYL) PHTHALA TE
DI-N-OCTYLPHTHALA TE
BENZO(B AND/OR K)FLUORANTHENE
BENZO-A-PYRENE
INDENO (1,2,3-CD) PYRENE
DIBENZO(A,H)ANTHRACENE
BENZO(GHl)PERYLENE
%MOISTURE
A-average value. NA-not analyzed. NAl-interferences. J-estimated value. N-presumptive evidence of presence of material.
K-actual value is known to be less than value given. L.°actual value is known to be greater than value given. U-material was analyzed for but not detected. the number is the minimum quantitation limit.
R-qc indicates that data unusable. compound may or may not be present. resampling and reanalysis is necessary for verification.
C-confinned by gems: 1.when no value is reported, see chlordane constituents 2.constituents or metabolites of technical chlordane
-TRAiiiilBL~Mi=-NA..., -
Sample 05 FY 1997 Project: 97--0357
MISCELLANEOUS COMPOUNDS
Facility: REASOR CHEMICAL
Program: NSF
Id/Station: RCSS10201
Media: SOIL
ANALYTE
CASTLE HAYNE, NC
Case Number: 25655
D Number: MY54 Org Contractor: AA TS
RESULTS
2000JN
400JN
UNITS
UG/KG
UG/KG
UG/KG
UG/KG
SUBSTITUTED PHENANTHRENE CARBOXYLIC ACID (2 ISOMER~
CINNAMYL CINNAMATE
2000J
10000J
ALKANES
24 UNIDENTIFIED COMPOUNDS
A-average value. NA-not analyzed. NAl-interferences. J-estimated value. N-presumptive evidence of pres,..,ce of material.
---Produced by: Denise Goddard
Requester: RAY DOYLE
Project Leader: DOYLE
Beginning: 08/23/97 15:40
Ending:
K-actual value is kr. ·. to be less than value given. L-actual value is known to be greater than value givr I-material was analyzed for but not detected. the number is the minimum quantit?'" · limit.
R-qc indicates that musable. compound may or may n.ot be present. resampling and reanalysis is sary for verification.
C-confirmed by gen,-.. ·,.when no value is reported, see chlordane constitue~ts 2.constituents or metabo .... of technical chlordane