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HomeMy WebLinkAboutNCD986175644_20060512_Davis Park Road TCE Site_FRBCERCLA LTAR_LTAR Feb 2006 Annual Sampling Event Report-OCRI I I I I I I I I I I I I I I I I I I Document' Control No. RFW205-2A-A VEI Revision 0 LONG TERM RESPONSE AC M,4y 1 8 · FEBRUARY 2006 ANNUA........,""" SAMPLING EVENT REPO DAVIS PARK ROAD TCE SITE GASTONIA, NORTH CAROLINA Work Assignment No. 205-RALR-04PN MAY 2006 REGION 5 U.S. EPA CONTRACT NO. 68-W7-0026 Weston Solutions, Inc. Suite 100 5430 Metric Place Norcross, Georgia 30092 WESTON W.O. No. 20064.205.100.0930 I I I I I I I I I I I I I I I I I I I Prepared By: Approved By: Approved by: Approved by: LONG TERM RESPONSE ACTION FEBRUARY 2006 ANNUAL SAMPLING EVENT REPORT REVISION0 DAVIS PARK ROAD TCE SITE GASTONIA, NORTH CAROLINA U.S. EPA Contract No. 68-W7-0026 Work Assignment No. 205-RALR-04PN Document Control No. RFW205-2A-A YE! MAY 2006 /'-Teresa Offner, P. . WESTON Work Assignment Manager James M. Brnton, P.E. WESTON Program Manager Jennifer Wendel U.S. EPA Remedial Project Manager Date: _______ _ Date: _______ _ WESTON W.O. No. 20064.205.100.0930 K:\20064\205\Fi rst Annual\Feb06FirstAnnuallR pg .doc RFW205-2A-AVEI I I I I I I I I I I I I I I I I I I I This document was prepared by Weston Solutions, Inc., expressly for EPA. It shall not be disclosed, in whole or in part, without the express written pennission of EPA. Section 1 2 3 4 February 2006 Annual Sampling Event Report Davis Park Road TCE Site Section: Table of Contents Revision: 0 Date: May 2006 TABLE OF CONTENTS INTRODUCTION .............................................................................................. 1-1 I . I Purpose .................................................................................................... 1-1 1.2 Background ............................................................................................. 1-1 1.3 Groundwater Contaminant Description ................................................... 1-6 1.3.1 Contaminant Source Area .................................................................. 1-6 1.3.2 Groundwater Plume Concentration and Extent.. ............................... 1-8 1.4 Site Geology and Hydrogeology .......................... : .................................. 1-9 LONG TERM RESPONSE ACTION .............................................................. 2-1 2.1 Quarterly and Semiannual Groundwater Monitoring .............................. 2-2 2.2 First Year Quarterly LTRA Sampling Events (2002/2003) .................... 2-5 2.3 Semiannual LTRA Sampling Events (August 2003/February 2004/August 2004/February 2005) ......................................................... 2-7 FEBRUARY 2006 ANNUAL LTRA SUMMARY .......................................... 3-1 3.1 Groundwater Sampling ............................................................................ 3-1 3.1.1 Monitor Well Sampling Procedures .................................................. 3-1 3.1.2 Community and Private Well Sampling Procedures ......................... 3-4 3.1.3 Field Quality Assurance/Quality Control Samples ........................... 3-4 3.2 Groundwater Elevation ............................................................................ 3-5 3.3 Groundwater Analytical Results ............................................................. 3-9 3.3.1 Groundwater Samples ....................................................................... 3-9 CONCLUSIONS AND RECOMMENDATIONS ........................................... 4-1 4.1 4.2 4.3 L TRA Results Summary ......................................................................... 4-1 Conclusions ............................................................................................. 4-6 Recommendations ................................................................................. 4-10 K:120064\205\First Annual\Feb06FirstAnnuallRpg.doc RFW205-2A-AVEI I I I I I I I I I I I I I I I I I I I This document was prepared by Weston Solutions, Inc., expressly for EPA. It shall not be disclosed, in whole or in part, without the express written permission of EPA. Figure 1-1 1-2 1-3 1-4 1-5 2-1 3-1 3-2 3-3 4-1 4-2 4-3 4-4 4-5 4-6 February 2006 Annual Sampling Event Report Davis Park Road TCE Site Section: Table of Contents Revision: 0 Date: May 2006 LIST OF FIGURES Site Map ............................................................................................................... 1-3 Residences Connected to City Water, September 2000 ....................................... 1-4 Residences Supplied with Carbon Filtration Units. August 2000 ....................... 1-5 Street Address Location Map ............................................................................... 1-7 Water Supply Sources Following RA ................................................................ 1-10 LTRA Monitor Well Sampling Network ............................................................. 2-3 Potentiometric Contour Map, Bedrock Aquifer, February 2006 ......................... 3-8 TCE Concentrations in Groundwater Febrnary 2006 ........................................ 3-17 PCE Concentrations in Groundwater February 2006 ........................................ 3-18 Trichloroethene Concentration vs. Time, 2419 Davis Park Road, MW-5 ........... 4-2 Trichloroethene and Tetrachloroethene Concentration vs. Time, 2719 Davis Park Road, MW-12 .............................................................................................. 4-3 Trichloroethene and Tetrachloroethene Concentration vs. Time, 2232 Tate Street, MW-15 ...................................................................................................... 4-5 Trichloroethene and Tetrachloroethene Concentration vs. Time. 2639 Springbrook Street, MW-9 ................................................................................... 4-7 Trichloroethene and Tetrachloroethene Concentration vs. Time. MW-17 .......... 4-8 Trichloroethene and Tetrachloroethene Concentration vs. Time, MW-18 .......... 4-9 K :1200641205\Fi rst Annual\Feb06FirstAnnuallRpg. doc II AFW205·2A·AVEI I I I I I I I I I I I I I I I 'I I I I This document was prepared by Weston Solutions. Inc., expressly for EPA. It shall not be disclosed, in whole or in part, without the express written permission of EPA. Table 1-1 2-1 3-1 3-2 3-3 3-4 3-5 LIST OF TABLES February 2006 Annual Sampling Event Report Davis Park Road TCE Site Section: Table of Contents Revision: O Date: May 2006 Residential Well Historical Analytical Results .................................................. 1-11 LTRA Monitor Well Sampling Network ............................................................. 2-4 L TRA Monitor Well Sampling Network Global Positionin System Coordinates .......................................................................................................... 3-2 PDB Installation Depths ...................................................................................... 3-3 February 2006 Annual L TRA QA/QC Laboratory Analytical Results Summary .............................................................................................................. 3-6 February 2006 L TRA Groundwater Level Data .................................................. 3-7 L TRA Laboratory Analytical Results Summary ............................................... 3-10 LIST OF APPENDICES APPENDIX A -Log Notes/Field Water Quality Data Sheets APPENDIX B -Laboratory Analytical Reports K:120064\205\First Annual\Feb06FirstAnnuallApg.doc 111 RFW205-2A-AVEI •",:• ... _ ,.:.':· ·.· ... ·•: ' . ·, -·, .,.-. . . ... ··, ·•·' .-.·'},_'{.,-::: 'p -::,·• ,• -"",."I" . '. ·--~--: •~ .. , .• ~, .... ,: ... ,. . . -,~: ,. : ' : _,,.. -.. . ' . ... · .. ,._, . .. . ,, ... • .. r , . _. ,"· , ', I I I I I I I I I I I I I I I I I I I This document was prepared by Weston Solutions, Inc., expressly for EPA. 1t shall not be disclosed, in whole or in part, without the express written permission of EPA. 1.1 PURPOSE SECTION 1 INTRODUCTION February 2006 Annual Sampling Event Report Davis Park Road TCE Site Section: 1 Revision: 0 Date: May 2006 Weston Solutions, Inc., (WESTON@) has been tasked by the U.S. Environmental Protection Agency (EPA) Region 4 to perform the Long Term Response Action (LTRA) at the Davis Park Road Trichloroethene (TCE) Site in Gastonia. North Carolina. The work is conducted under the Region 5 Remedial Action Contract (RAC) Program and implemented as a contract crossover to Region 4. Contract Number 68-W7-0026, Work Assignment Number 205-RALR-04PN. The current L TRA includes monitoring the bedrock aquifer contaminant plume by sampling a network of bedrock wells for volatile organic compounds (VOCs) on a quarterly basis for one year, semiannually for two years, and annually thereafter for 27 years, pending review of analytical results, to ensure the plume is in fact naturally attenuating. This report presents data from the fourth year of the L TRA, the first annual sampling event. 1.2 BACKGROUND The Davis Park Road TCE Site is located within the Gastonia Extra Territorial Jurisdiction area along Davis Park Road, south of Hudson Boulevard and north of Blackwood Creek in the southwestern portion of Gastonia, Gaston County, North Carolina. The site consists of an area of reportedly contaminated soil behind a building that is located at 2307 Davis Park Road (Davis Park Auto Repair), and a plume of contaminated groundwater that emanates from this property and extends south along Davis Park Road to Blackwood Creek. The site also includes the Cedar Oak Park subdivision located on the east side of Davis Park Road within the confines of Cedar K:1200641205\First AnnuallFeb06FirstAnnuallRpg.doc 1-1 RFW205-2A-AVEI I I I I I I I I I I I I I I I I I I I This document was prepared by Weston Solutions, Inc., expressly for EPA. lt shall not be disclosed, in whole or in part, without the express written permission of EPA. February 2006 Annual Sampling Event Report Davis Park Road TCE Site Section: 1 Revision: 0 Date: May 2006 Oak Circle as well as areas along the western side of Davis Park Road. Figure 1-1 presents a site map for the Davis Park Road TCE Site. The plume of contaminated groundwater underlies residential areas along the plume's entire horizontal extent. The contaminant levels and aerial extent are further described in Section 1.3.2. At the time of the discovery of contaminants in the groundwater (March 1990). a majority of the residences throughout the site were supplied water by residential water supply wells. As a result of the continued migration of the plume. groundwater supplying many of these residential water wells became contaminated with the chlorinated hydrocarbons found in the plume. Since that time, several neighborhoods within the site have been connected to the Gastonia public water supply to reduce the potential health threat from the contaminants. In 1996. many of the houses within the Hedgewood Circle neighborhood, which borders the northern edge of the site. were connected to the public water supply. In late I 997 and early I 998, after petitioning the city for water services. all of the homes in the Cedar Oak Circle subdivision, which dominates the eastern side of the site. were connected to the public water supply. Approximately 130 homes within the site were receiving water from residential water supply wells prior to Remedial Action (RA) activities. Over half of these homes (approximately 75) had water supply wells that were or could potentially be affected by the contaminant plume as depicted in the I 998 Remedial Investigation (RI) report. In August 2000, five of these residences were supplied with carbon filtration units, and in September 2000, sixty-four (64) of the residences were connected to the Gastonia public water supply as part of the RA to execute the provisions of the Record of Decision (ROD) for the site. The locations of the residences connected to the Gastonia public water supply and the carbon filtration units are presented in Figures 1-2 and 1-3, respectively. K:120064\205\First AnnuallFeb06FirstArmuallApg.doc 1-2 RFW205·2A-AVEI - ~ ~ ~ ~ z n: ., ~ I ------ 0 -- - FIGURE 1-1 SITE MAP - DAVIS PARK ROAD TCE SITE GASTONIA, NORTH CAROLINA - -- si-~\e,.. \~) {l GOTHIC COURT GASTON LA CITY UMITS 0 --- Approximate Scale In Feet 600 - 1200 9 '"'-------------------------------------1 - • 19 •I I / I I ---- t::, • ,.. .... . -· -DAVIS PARK ROAD • • c=i -- 1., I I • Q , □• ◊ I I I " I I • I 0 I • ■ ~ ■ i ii' 0 0 ■o ~ 0 , 0 . , "~ .. "<-o () .0 i I • ■ ~ • ■ I DAVIS PARK ROAD GASTONIA, GASTON COUNTY, 0 - 0 ~ ◊ Q TCE SITE -- • " 0 LEGEND RESIDENCE RESIDENCE CONNECTED TO CITY WATER SEPT. 2000 NORTH CAROLINA UL~. DRAWN: DATE: W.0. NO.: RESIDENCES CONNECTED TO CITY WATER SEPTEMBER 2000 J. MILLER 2/12/01 20064-205-100-0930 DES. ENG.: DATE: CAD NAME: FIGURE 1-2 fin-1-2. dw□ / ------------------- LEGEND I Ii -RESIDENCE -RESIDENCE SUPPLIED WITH CARBON fll TRA TION UNITS ..,..,.,,,,_ 0 G!J l!!!I l!!I ... c::, .. rif!8 ~ elm ~ DAVIS PARK ROAD l!i!I l!!!J DAVIS PARK ROAD Oo • It 0 !? ' I ~ J • Iii! CJ -J -lil!rt, lo I Ii ff j/ JU II /iJ Q IJJ ◊ w □ Iii \\\ 11 g ,, /j jJ " 0 I 1M Ill ~ I 0 I j/ ~ ~ ~ I :'> ' ~ .. • 18 g .. 0 ; <:, If' "' D I§ ■•• -I . ~ --..... PURITA.N ST. •~r======71=====;,:===d •,11 •:c ..... ~ •. j! J• I • • --,, •. ii . l!J w ii ~ ◊ C C l!I" ~ C ; 0 Iii Iii ~ e ~ • Ill I ◊ a • • , 4ilt / ~~-' DAVIS PARK ROAD TCE SITE GASTONIA, GASTON COUNTY, NORTH CAROLINA RESIDENCES SUPPLIED WITH CARBON FILTRATION UNITS ORA'MII: DATE: W.O. NO.: J. MILLER 2/12/01 20064-205-100-0930 AUGUST 2000 DES. ENG.: DATE: CAO NAME: '-FIGURE 1 3 fig-1-3.dwg , ------------------- I I I I I I I I I I I I I I I I I I I This document was prepared by Weston Solutions, Inc., expressly for EPA. It shall not be disclosed, in whole or in part, without the express written permission of EPA. February 2006 Annual Sampling Event Report Davis Park Road TCE Site Section: 1 Revision: 0 Date: May 2006 1.3 GROUNDWATER CONTAMINANT DESCRIPTION This section describes the potential source area of the contamination, current knowledge of the groundwater plume, and the extent of the plume. l.3,1 Contaminant Source Area According to preliminary site investigation reports (see RI Report, 1998, for summary), a groundwater sample was collected on 31 March 1990 from a supply well within the Cedar Oak Park subdivision by Gaston County Environmental Health representatives as part of a routine sampling procedure in accordance with "Community Well Rules." Analysis of the sample revealed concentrations of TCE (34.9 micrograms per liter [µg/11), tetrachloroethene (PCE) (23.7 µg/1), and chloroform (9.2 µg/1). Analytical results for a confirmation sample collected from this well on 17 April I 990 were similar to the original sample. Groundwater samples collected from three nearby private wells in May 1990 by the Gaston County Health Department indicated that the groundwater was contaminated with TCE. The highest concentration of TCE (IO 1.4 µg/1) was detected in a sample collected from the private well located at 2419 Davis Park Road (see Figure 1-4), 200 feet south of the Davis Park Auto Repair facility (located at 2307 Davis Park Road). The current EPA Drinking Water Maximum Contaminant Level (MCL) for TCE and PCE is 5 µg/1. Current State (North Carolina Department of Environment and Natural Resources INCDENRI) MCLs for TCE and PCE are 2.8 µg/1 and 0.7 µg/1 respectively. The Environmental Services Division of EPA collected groundwater samples from the contaminated wells along Davis Park Road and within the Cedar Oak Park subdivision in July 1990. TCE was detected at concentrations of 82 µg/1 and 31 µg/1 in groundwater sampled from the private well located at 24 I 9 Davis Park Road and a Cedar Oak Park subdivision well (2719 Davis Park Road), respectively. K:1200641205\First Annual\Feb06FirstAnnuallRpg.doc 1-6 RFW205-2A-AVEI - ~ ~ ' 6 ~ z " 4 ~ I FIGURE 1-4 STREET ADDRESS LOCATION MAP DAVIS PARK ROAD TCE SITE GASTONIA, NORTH CAROLINA ~~ICCOUST GASTONIA CITY LIMITS Cl 0 "' Q\ Approximate Scale In Feet 600 1200 ~ ~._ _________________________________________________________ __, - - - ---- ------ ----- I I I I I I I I I I I I I I I I I I I This document was prepared by Weston Solutions, Inc., expressly for EPA. It shall not be disclosed, in whole or in part, without the express written permission of EPA. February 2006 Annual Sampling Event Report Davis Park Road TCE Site Section: 1 Revision: 0 Date: May 2006 Additional investigations and groundwater sampling events pnor to the initiation of the RI continued to reveal levels of contaminants above State and Federal drinking water standards. Investigation activities focused on a possible source location(s). Several potential sources of the contamination at the Davis Park Road TCE Site were reviewed. Consideration of proximity, regional and local groundwater flow directions, and groundwater sample analytical data indicated that the Davis Park Road Auto Repair facility was the most likely contaminant source at the Davis Park Road TCE Site (NCDENR Site Inspection. I 993). As a result of these findings and in an effort to further define the source area for the water supply well contaminants, environmental assessments were conducted, including the Site Inspection Addendum (SI) (May 1993), Expanded Site Investigation (ES!) (May 1994), and RI (1996- 1998). The RI report summarizes the source investigation as follows: " ... according to data generated from this and previous investigations, solvents such as PCE or TCE were introduced to the environment from the property at 2307 Davis Park Road. This 'spill' migrated through the vadose zone and the saprolite/partially weathered rock aquifer, and into the bedrock aquifer. Once introduced into the environment, various biophysiochemical processes acted on the contaminants to reduce the overall concentration as well as spread the contaminant mass throughout various matrices. CuITently, the VOC contaminants, principally TCE and PCE. appear to be present only within the bedrock aquifer and may continue to be drawn towards active residential wells scattered throughout the site, specifically those wells to the west of Davis Park Road." 1.3,2 Groundwater Plume Concentration and Extent Five potential sources for water supply were identified in the Davis Park Road Area and presented in the RI report. These include the following: City of Gastonia Public Water Supply System: City of Gastonia Restricted Use Water Line: water supply well as part of a Community K:1200641205\First Mnual1Feb06FirstAnnuaJIRpg.doc 1-8 RFW205-2A-AVEI I I I I I I I I I I I I I I I I I I I This document was prepared by Weston Solutions, lnc., expressly for EPA. It shall not be disclosed, in whole or in part, without the express written permission of EPA. February 2006 Annual Sampling Event Report Davis Park Road TCE Site Section: 1 Revision: 0 Date: May 2006 Water System; a water supply well as part of a Private Well System, and private water supply wells. Nine monitor wells were installed during completion of the RI (MW-IS, MW-ID, MW- 2S, MW-2D, MW-3S, MW-3D, MW-4S, MW-4D, and MW-5S). Following connection to City Water in August 2000, seventeen private wells were abandoned, seven wells were converted into monitor wells (CW-I through CW-7), and five residences were supplied with carbon filtration units (2400 Skyland, 2419 Davis Park Road, 2717 Davis Park Road, 2839 Davis Park Road, and 2639 Springbrook). Figure 1-5 details the locations and water supply source of residences within the vicinity of the Davis Park Road TCE Site updated to include activities completed as part of the 1998 RI and as part of the 200 I RA to execute the provisions of the ROD for the site. A summary of analytical data for the primary constituents of concern (PCE and TCE) detected in groundwater sampled at the Davis Park Road TCE Site is presented in Table 1-1. Analytical data was obtained for groundwater sampled after August 200 I from the 5 residences supplied with carbon filtration units as part of the RA to execute the provisions of the ROD. This data is included for PCE and TCE in Table 1-1. As described in the 1998 RI, the contaminant plume was centered along Davis Park Road from Glenraven to Blackwood Creek and underlies areas approximately 500 feet to the east and west of Davis Park Road. 1.4 SITE GEOLOGY AND HYDROGEOLOGY The geologic profile across the site generally consists of a saprolite layer, underlain by a partially weathered rock zone and the underlying fractured crystalline bedrock. The saprolite is a silty, clay-rich, residual material derived from in-place weathering of rock. The saprolite zone appears to be thickest (approximately 80 feet) near the ridge crest along the northern edge of the site, thinning towards the lower elevations or stream valleys to approximately 20 feet in thickness. A partially weathered rock layer typically underlies the saprolite, and ranges in thickness from approximately 5 to 25 feet. This layer is composed of saprolite and fragments of weathered bedrock. The bedrock is generally observed to be a fractured quartz biotite granite or granitic gneiss. K:1200641205\Fi rs\ Annual\Feb06FirstAnnuall Rpg ,doc 1-9 RFW205-2A-AVEI I I I I I I I I I I I I I I I I I I I I I I I N wTE s ◊ .---,I ; r ; --.-----·--__;:< ~( I ' '0 --D" ♦ • •o 0 .. ,® • ,' ~' •' 0 ♦ • . "' ◊ ~.,o .. I 0 0 I -0 ;a ,□ --~' *~_\.I, $ ,,.. GAAAGEb' ~ ,,~''' ,.J "'~I'■ ~ ®o ,,~• • • i-•· ••• • --" -I •ta -~ ,,~••-~ D .~ fr, •• • > -2 2 •• I I • 0 "% \¼~ ~'I, -~ oo,H,cc, I I RICHLAND AVENUE ! I_ GLENRAVEN AVENUE ' -~ ~ ~ ~ \ '. I '. \ \ \ -I -------. ---CEQc'R OAK CIRCLE ' ., .. ~ ~-"''ll· •• ~ ~,$ ,,~. -0 Cl • I ,,.., ® 0 'tf" I I I •• ~-\~ " I .. \ 1-. ~ \.'Ii, 1.-.YLOR MEMORIAL BAPTIST CHURCH "'-r1·'®' I I I I I ·c \\ ., \ SARNS~ \ ~ ·. D◊ ,,., I I,,.,, \ \' • I ----I LEGEND RESIDENCES CONNECTED TO OTYWATER RESIDENCES ON RESTRICTED ltSE WATER LINE -CITY OF GASTONIA RESIDENCES ON COMMUNITY WELLS> OR= 15 SUBSCRIBERS RESIDENCES ON PRIVATE WELL SYSTEM WITH 2-14 SUBSCRIBERS RESIDENCES ON PRIVATE WELLS RESIDENCES WITH CARBON FILTRATION UNIT ■ I 11 I 11 0 n "' 0 I 0 0 'I"' U) 0 0 N •• I g ~I"' .ot!:l Oo:z: 3: N VJ ~ ~ "' -,... 00 ~ .-0 a; <( u, 0 0 0 0 c3 :I:: (/) w II j"'~j "' ~ I . o::: .....: lf) iu,=>I < 0 -w " f->-_f-(/) z ::J w O <( ~uz _J o2o <( 0 et:: of-<( er: (/) u <( ::,c:(.'.):r: er: "f-<( <( et:: Q_ -0 Zz (/) 0 _f-> (/) <( <( 0 (.'.) I I I I I I "' . >-0 ~ :'.S (/) w u et:: ::J <( 0 et:: (/) >-(.'.) _Jz Q_ s: Q_ 0 ::J _J (/) _J 0 et:: LL w f-<( s: I I U) I w "' ::J 0 G:: z 0 ui 5 w "' I~ I §? "' Q_ <( -- ----.. ----- ---This document was prepared by Weston Solutions, Inc, expressly for EPA. It shall not be disclosed, in whole or in part, without the express written permission of EPA. Address 2501 Briaroak 2510 Briar Oak Date 6/14/90 5/6/96 PCE ND ND TCE ND ND Address 2302 Hedgewood 2314 Hedgewood Date sn196 1/14/98 PCE .66AJ ND TCE ND ND Address 2618 Puritan 2612 Puritan Date 4/27/90 5[7/96 PCE ND ND TCE ND ND ID MW-1S MW-10 Screen 20-30 40-75 Date 1/13/98 1/13/98 PCE ND ND TCE ND ND Address 2329 Sky1and Date PCE TCE ,,...ddress Date PCE TCE J -Estimated Value A -Average Value ND -= not detected 7/10/90 5ll/96 trace ND trace 18A 2407 Skyland 4/27/90 I 5ll/96 ND I ND ND 2.6A All results reported in micrograms per liter K:\20064\205\FirstAnnual\Feb06FirstAnnualApt_ lbls Table 1-1 Residential Well Historical Analytical Results Davis Park Road TCE Site 2241 Cedar Oak 2326 Cricket 148 Grassy 6/9/92 sn/96 517/96 sn100 1K ND ND ND ND ND ND ND 2322 Hedgewood 2347 Hedgewood 2363 Hedgewood 2375 Hedgewood 1511 Jackson 5(7/96 6/14/90 5[7/96 6/27/91 1/13/98 5/6/96 ND ND ND 1.1 ND ND ND ND ND ND ND 0.97AJ 2704 Puritan 2720 Puritan 2725 Puritan 2230 Richland 2425 Rotan 516196 5(7/96 4/27/90 5{7/96 2/3/93 5/7/96 NO ND trace ND ND ND ND ND trace ND ND ND MW-2S MW-2D MW-3S MW-3D MW-4S MW-40 5-15 21-54 64-74 87-150 36-46 130-142 1/14/98 1/13/98 1/13/98 2/25/98 1/15/98 1/15/98 NO 6 ND ND ND NO ND 17 ND ND ND NO 2308 2314 2304 Sky1and Sky1and Sky1and 2309 Skyland 'J/7/95 'J/7/95 5/23/94 4/19/93 5n/90 5/6/96 J ND ND ND 0.85 0.52J 0.91 0.75 0.72 NO ND 2415 Skyland 2634 Skyland Skyland Community Well 5n/96 4/27/90 5/6/96 4/27/90 l 7/18/93 9/8/93 ND trace ND ND I ND 1K ND trace ND ND 2.4 1K 1-11 8/24100 I 10/17/00 NO I ND 7.4 8.2 MW-5S 9-19 1/14/98 ND ND 2400 Skyland 8/24/00 10/17/00 I ND ND I ND ND 2639 Springbrook 1/24/01 5/9/01 ND ND 8.8 10 1/24/01 5/9/01 ND ND ND ND --- 2232 Tate 8/10/01 11/20/01 2/25/98 NO ND ND 8.6 6.8 34 8/10/01 11/20/01 ND ND NO ND - ------ - - - --This document was prepared by Weston Solutions, Inc., expressly for EPA. lt shall not be disclosed, in whole or in part, without the express written permission of EPA. Address 627 DPR 2212 DPR 2231 DPR Date 6/11/90 6/11/90 6/14/90 7/13/90 1/25/94 PCE ND trace ND 1K ND TCE ~,n 1K ND trace ND Address 2307 DPR nate 8/8/91 8/13/92 4/19/93 2/10/98 2/10/98 PCE ND ND NU NU ND TCE 30! 0.75 172 ND ND ..... ddress Date 4/27/90 517190 6/21/90 7/6/90 8/23/90 PCE 1K 0.85 1K ND 1K TCE 101.4 NA 134.3 82 116.3 M.ddress 2425 DPR Date 517190 5/15/90 PCE 0.31 trace TCE 8.4 6.8 Address 2509 DPR 2603 DPR Date 517196 6/11/90 PCE ND 1K TCE ND 1K Address 2723 DPR Date 6/11/90 PCE ND TCE ND E.J -Estimated Value A • Average Value 5/6/96 .76AJ ND 7/13/90 2/3/93 ND J 7.0 30E 6/14/90 5/6/96 ND ND ND ND 2800 DPR 5/23/90 5/6/96 ND 0.62AJ ND ND K -Actual value is known to be less than value given ND -Not detected K:1200641205\First.Annual\Feb06FirstAnnualApt_tbls 3/19/93 trace 8.0 8/24/00 2.2 2.8 6/14/90 1K 1.2 517196 517190 ND 0.25 ND 5/15/90 5/20/90 trace trace 44.5 24.3 10/9/90 1/30/91 ND 1K 68AJ 84.2 1/25/94 5/30/95 ND ND 11 NA 2717 DPR 10/17/00 1/24/01 0.68 1.8 0.79 2.1 2816 DPR 5/6/96 2/10/98 6.4A 10 14A 18 Table 1-1 (continued} Residential Well Historical Analytical Results Davis Park Road TCE Site 2301 DPR 2304 DPR 5/15/90 7/13/90 · 1/25/94 517196 1/14/98 5/23/94 trace trace ND ND ND ND 44.5 37.t ND ND ND U.!:11 2403 DPR 7/12/90 1/30/91 7/23/92 4/19/93 9/24/93 1/25/94 trace trace ND ND ND ND 37.1 28 17 12 7.3 10 2419 DPR 5/20/91 2/3/93 6/21/93 9/24/93 1/25/94 8/5/94 1K 0.48 0.56E ND ND ND 66.2 54 23 30 38 NA 2503 DPR 517196 5/15/90 3/19/93 5/23/94 ND ND ND ND 3.0A ND 1.5 0.65 5/9/01 8/10/01 11/20/01 3/31/90 5/1/90 6/21/90 1.3 1.2 0.96 23.7 18.9 1.4 1.2 1.1 34.9 51.8 51.8 2839 DPR 8/24/00 10/17/00 1/24/01 5/9/01 8/t0/01 11/20/01 ND ND ND ND ND ND ND ND ND ND ND ND J-12 5/30/95 1/16/98 ND ND NA ND 5/30/95 517196 2/10/98 ND ND ND NA 15A 8 2719 DPR 7/6/90 8/23/90 I 10/9/90 12 20.9 14 31 56.1 41 --- - - 8/24/00 10/17/00 1/24/01 5/9/01 8/10/01 11/20/01 ND ND ND ND ND ND 2.4 2.4 2.6 2.6 2.2 1.8 5/17/93 1/25/94 1/25/94 517196 1/14/98 13.7 18 17 10 14 44.6 51 50 32 32 ;. ,._,.' ..;. ·.:·::,·· ~ ··.~ .. . . ~ ·• ·-_\.; .~·'.'"'-·•-; . . : . ( .. --; ·>·. ~- .• . :• ·, f . ... ..... _,·~ '.:.. :,;.;<:.,~:' . ':;r:'/:-.:.-t:·.::·\\{,:? .. ::-. , .. . ~-•:.'t : I I I I I I I I I I I I I I I I I I I This document was prepared by Weston Solutions, Inc., expressly for EPA. It shall not be disclosed, in whole or in part, without the express written permission of EPA. SECTION 2 February 2006 First Annual Sampling Event Report Davis Park Road TCE Site Section: 2 Revision: 0 Date: May 2006 LONG TERM RESPONSE ACTION The ROD for the Davis Park Road TCE Site (September I 998) states that following initiation of a natural attenuation study, groundwater monitoring will be conducted on a quarterly basis for three years and annually for the next 27 years. First year LTRA sampling results indicated a continued decrease in contaminant concentrations as the plume migrates south and away from the source area. Additionally, contamination concentrations did not vary significantly between sequential quarters for any of the wells in the monitoring network. It was therefore recommended that the sampling program be reduced from quarterly to semiannual monitoring after the first year of the LTRA, then semiannually for the next 2 years. Results from the qua11erly and semiannual sampling are summarized below. Results from the most recent sampling (the first annual) event, are summarized in Section 3.0. Data obtained from the long term groundwater monitoring are used to evaluate natural attenuation of contaminant constituents within the bedrock aquifer plume at the Davis Park Road Site following provision of city water to 64 residences in August 2000. In April 2002 a baseline sampling event was conducted to establish current conditions and to evaluate the need for installation of additional wells for the L TRA. Based on analytical results, it was determined that natural attenuation was occurring at rates consistent with expectations, and that the wells currently available for sampling were sufficient to evaluate natural attenuation in long term performance monitoring. A Monitored Natural Attenuation Plan (submitted to EPA in October 2002) was developed to include sampling a network of bedrock wells for VOCs to effectively characterize contaminant levels (VOCs) · in the bedrock aquifer within the contaminant plume as well as the surrounding area for the potential migration of contaminants from within the existing groundwater plume. K:120064\205\First Annual\Feb06Fi1stAnnuallRpg.doc 2-1 RFW205-2A-AVEI I I I I I I I I I I I I I I I I I I I This document was prepared by Weston Solutions, Inc., expressly for EPA. It shall not be disclosed, in whole or in part, without the express written permission of EPA. February 2006 First Annual Sampling Event Report Da"vis Park Road TCE Site Section: 2 Revision: 0 Date: May 2006 The eighteen bedrock wells initially included for groundwater sampling in each L TRA monitoring event included four bedrock monitor wells installed in December 1997 (MW-I through MW-4), the five private wells provided with carbon filtration units in August 2000 (MW-5 through MW-9), two community wells located west of Davis Park Road (MW-10 and MW-11), four converted wells (MW-12 through MW-15), and three private wells (MW-16 through MW-18). Monitor wells MW-2, MW-5, MW-6, MW-9, MW-12, MW-15. MW-16, MW-17, and MW-18 were selected to provide groundwater quality information within the contaminant plume. The remaining monitor wells (MW-I. MW-3, MW-4, MW-7, MW-8, MW- 10, MW-11, MW-13, and MW-14), located outside the contaminant plume, were selected to provide evidence of potential contaminant migration. Beginning with the first year fourth quarter sampling event, MW-13 was removed from the sampling network arid replaced with MW-19, located south of the site, just outside the contaminant plume. Additionally, following the fourth quarter sampling event. two bedrock wells were installed west of the plume to monitor the area between the plume and the currently pumping community wells to the west of the site (MW-IO and MW-I I). These wells were incorporated into the monitoring network and are designated MW-20 and MW-21. Figure 2-1 provides the locations of the monitor wells in the sampling network. Table 2-1 provides monitored natural attenuation sample designations cross-referenced with addresses and former designations. 2.1 QUARTERLY AND SEMIANNUAL GROUNDWATER MONITORING The purpose of L TRA groundwater monitoring is to verify the following: • Natural attenuation is occurring at rates according to expectations, • No changing conditions arise that might reduce efficacy of this remedy, • The continued absence of toxic and/or mobile transformation products. K:\200641205\First Annual\Feb06FirstAnnuaJIRpg.doc 2-2 RFW205·2A·AVEI -~ - -11!!1 l!!!l!!B -.... - -lli!!!!I --.. 0 0 D DD[':, I EN Ny C:J C:) 0 □ □ □ ◊\l,,.__ D D oo ..._, D APRVD. DATE: D 0 REVISION 0 0 <> ~ ~ \ cl.---.lw * ~ \.JS' \ 0 .., \ " --==d~~!'-==-• \ \J o-o= o Cl 0"□ 0 D D 0 0 □ □ BROOK STREET 0 0 Cl 0 \ 0 0 0 0 \*□ d '<,!) 0 \'.I D \) D 0 CJ : D • D io 'i) Q ~ 0 D D c:> □ ◊ 0 () IT ~□ z io z i □ a D D D --·--·-··-· D DAVIS PARK ROAD TCE SITE GASTONIA, GASTON COUNTY, NORTH CAROLINA 0 G D Cl >O 'i~ oo ~~ h • D [} D □ DRAWN: DATE: 0 QQ 0 D • 0 ~ □ 0 !□ a D □ □" LTRA MONITOR WELL SAMPLING NETWORK J. MILLER 6 5 02 LAYOUT: CADD FllE: FIGURE 2-1 2-1 avispark.dwg 8 Cl ;,I>' a~,,""' ~ 0 ~ 0 ~ ~ 31',ll:IQ mJO;l.UIVH -- ♦ ~ f;; " r "' r z r C, 0 (") ,. =' 0 z W.O. NO.: 20064-205-100-0930 SHEET: OF 1 1 I I I I I I I I I I I I I I I I I I I This document was prepared by Weston Solutions, Inc., expressly for EPA. It shall not be disclosed, in whole or in part, without the express written permission of EPA. Table 2-1 L TRA Monitor Well Sampling Network Davis Park Road TCE Site Sample ID Status Former Designation(s) Street Address MW-I monitor well MW-ID S of Cedar Oak MW-2 monitor well MW-2D 2816 Davis Park MW-3 monitor well MW-3D Lendora Drive MW-4 monitor well MW-4D 2415 Skyland MW-5 carbon unit CO-I. PW-2, 121 2419 Davis Park MW-6 carbon unit CO-13, 235 2717 Davis Park MW-7 carbon unit 298 2839 Davis Park MW-8 carbon unit 252 2400 Skyland MW-9 carbon unit 182 2639 Springbrook MW-10 community well CO-2, 300 2634 Skyland MW-II community well CO-3, 269 Briar Oak MW-12 converted well CW-5 Cedar Oak Subdivision 2719 Davis Park MW-13 converted well CW-6 Cedar Oak Subdivision 2241 Cedar Oak MW-14 converted well CW-4, 49 2403 Davis Park MW-15 converted well CW-7, 175 2232 Tate MW-16 private CO-5, 195 2725 Puritan MW0 l7 private CO-14. 286 2816 Davis Park MW-18 private 192 2800 Davis Park MW-19 private 277 2833 Penny Park MW-20 monitor well -Lendora Drive (north of Skyland) MW-21 monitor well -Lendora Drive (south of Skvland) Notes: MW-13 was removed lrom the sampling network following the December 2002 sampling event. MW-14 was removed from the sampling network following the February 2005 sampling event. MW-19 was added to the sampling network in March 2003. MW-20 and MW-21 were added to the sampling network in August 2003. 2-4 K:\20064\205\FirstAnnual\Feb06FirstAnnualRpt_tbls Depth (feet below oround surface I 75 54 150 142 187 Unknown Unknown Unknown Unknown Unknown 270 112 125 74 145 Unknown Unknown Unknown Unknown 173 135 I I I I I I I I I I I I I I I I I I I This document was prepared by Weston Solutions, Inc., expressly for EPA. It shall not be disclosed, in whole or in part, without the express written permisSion of EPA. February 2006 First Annual Sampling Event Report Davis Park Road TCE Site Section: 2 Revision: 0 Date: May 2006 • The plume is not expanding, • There is no impact downgradient, • There arc no new releases, and • Attainment of remediation objectives. The samples are collected in accordance with the following documents: • Final Monitored Natural Attenuation Plan, dated October 2002, • U.S. Environmental Protection Agency Science and Ecosystem Support Division (EPA- SESD), Region 4, revised Environmental Investigation Standard Operating procedure and Quality Assurance Manual (EISOPQAM), May I 996, and • U.S. Geological Survey, User's Guide for Polyethylene-Based Passive Diffusion Bag Samplers to Obtain Volatile Organic Compound Concentrations in Wells, 2001. All samples are analyzed by laboratories in the Contract Laboratory Program (CLP). Samples are analyzed for VOCs using EPA Method 8260. 2.2 FIRST YEAR OUARTERL Y LTRA SAMPLING EVENTS (2002/2003) The first quarter sampling event, performed in April 2002, was originally developed as the baseline event to establish current conditions and to evaluate the need for installation of additional wells. Based on analytical results, it was determined that the wells then available for sampling were sufficient to evaluate natural attenuation in long term performance monitoring. Thirteen of the 18 wells selected for the sampling network and two additional wells were sampled in the baseline-sampling event. All 18 wells in the LTRA sampling network were sampled during the second and third quarter sampling events, performed in September and December 2002, respectively. K:'200641205\First Annual\Feb06FirstAnnuallRpg.doc 2-5 RFW205-2A-AVEI I I I I I I I I I I I I I I I I I I This document was prepared by Weston Solutions, Inc., expressly for EPA. It shall not be disclosed, in whole or in part, without the express written permission of EPA. February 2006 First Annual Sampling Event Report Davis Park Road TCE Site Section: 2 Revision: O Date: May 2006 During the fourth quarter sampling event, performed in March 2003, monitor well MW-13 could not be sampled due to hostile property owners. The ,residence at 2833 Davis Park Road was sampled instead, and incorporated into the monitor well network as MW-19. BecaL1se the owners of the property were not willing to allow samplers to pass through their yard to access the well, and because VOCs have not historically been detected in groundwater sampled from the well, MW-13 was removed from the monitor well network permanently and replaced with MW- 19. All of the remaining 17 wells in the LTRA sampling network were sampled during the fourth . . quarter sampling event. Depth to water was recorded where possible (MW-I through MW-4, MW-12 through MW-15) prior to sampling. Field parameters (pH. specific conductivity, temperature, dissolved oxygen, oxidation reduction potential, and turbidity) were also recorded. The potentiometric maps for the bedrock aquifer in first through fourth quarter LTRA sampling events indicated a groundwater flow direction in the bedrock aquifer ranging from south to east across the site, with the strongest component of flow to the southeast. This is consistent with previously reported data. TCE and PCE concentrations detected in groundwater during the first through fourth quarter sampling events suggest the contaminant plume is migrating slightly to the west and also southeast. Concentrations were significantly less than those detected in 1990 for wells in the northern portion of the plume. However, concentrations increased slightly in wells to the west and southeast. Levels were consistent with a naturally attenuating plume that is shifting due to pumping ( community wells on Skyland Drive and Briar Oak Drive located west of the site) and to a groundwater flow direction trending to the southeast and Blackwood Creek. First through fourth quarter analytical results are detailed in the LTRA Second, Third, and Fourth Quarter Sampling Event Reports submitted to EPA in January, April, and June 2003. respectively. K:1200641205\First Annual\Feb06FirstAnnuallApg.doc 2-6 RFW205·2A·AVEI I I I I I I I I I I I I I I I I I I I This document was prepared by Weston Solutions, Inc., expressly for EPA. It shall not be disclosed, in whole or in part, without the express written permission of EPA. February 2006 First Annual Sampling Event Report Davis Park Road TCE Site Section: 2 Revision: O Date: May 2006 2.3 SEMIANNUAL LTRA SAMPLING EVENTS (AUGUST 2003/FEBRUARY 2004/AUGUST 2004/FEBRUARY 2005) Following the first year of quarterly sampling at the Davis Park Road Site, two additional monitor wells were installed between the contaminant plume and the cmTently pumping community wells MW-10 and MW-1 l. These wells, designated MW-20 and MW-21, were incorporated into the LTRA monitor well network and sampled in August 2003, February 2004, August 2004, and February 2005. During these sampling events, the nine wells in the monitor well network that could be accessed at the well-head were sampled using both low-flow technology and passive diffusive bag (PDB) samplers. PDBs were evaluated and found to be an effective sampling alternative to the low- flow method of sampling. PDBs were subsequently recommended as the select method for sampling monitor wells that can be accessed for the remainder of the L TRA. PDBs are polymer membranes filled with deionized water that are placed at select depths into the groundwater column. Organic analytes permeate the membrane, diffusing deionized water out of the device until equilibrium is reached with the surrounding groundwater. Advantages to using PDBs verses traditional sampling methods include decreased spending on labor and equipment and elimination of containing and disposing of sampling purge and decontamination fluids. The potentiometric maps for the bedrock aquifer based on the semiannual LTRA sampling events indicated a groundwater flow direction in the bedrock aquifer ranging from south to east across the site, with the strongest component to the southeast, consistent with previous reports. However, the addition of three new survey points (MW-15, MW-20, and MW-21) provided data indicating that to the north of the site there is also a west to southwest component to the groundwater flow. This flow component was attributed in pait to the actively pumping community wells to the west of the site. K:\200641205\First Annual\Feb06FirstAnnuallRpg.doc 2-7 RFW205-2A-AVEI I I I I I I I I I I I I I I I I I I I This document was prepared by Weston Solutions, Inc., expressly for EPA. It shall not be disclosed, in whole or in part, without the express written permission of EPA. February 2006 First Annual Sampling Event Report Davis Park Road TCE Site Section: 2 Revision: 0 Date: May 2006 TCE and PCE concentrations detected in groundwater during the semiannual L TRA sampling events continued to suggest the contaminant plume is migrating slightly to the west and also to the south. TCE and PCE levels were consistent with a naturally attenuating plume that is shifting slightly due to pumping and to a groundwater flow direction trending to the southeast. The semiannual analytical results are detailed in the LTRA August 2003, Febrnary 2004, August 2004, and February 2005 Semiannual Sampling Event Reports submitted to EPA in December 2003, April 2004, November 2004, and May 2005 respectively. Following the February 2005 sampling event, the owner of monitor well MW-14, located north and upgradicnt of the current contaminant plume, requested permission to abandon the monitor well on her property at 2403 Davis Park Road. Because samples from this well had not contained COCs at levels exceeding the repo1ting limit since L TRA sampling began in September 2002, it was agreed this well was no longer necessary to the monitor well network, and MW-14 was abandoned and removed from the L TRA monitoring program. K:120064\205\First Annual\Feb06FirstAnnuallApg.Ooc 2-8 RFW205-2A-AVEI I I I I I I I I I I I I I I I I I I I This document was prepared by Weston Solutions, lnc., expressly for EPA. It shall not be disclosed, in whole or in part, without the express written permission of EPA. SECTION 3 February 2006 First Annual Sampling Event Report Davis Park Road TCE Site Section: 3 Revision: O Date: May 2006 FEBRUARY 2006 ANNUAL LTRA SUMMARY Section 3 of this report summarizes activities conducted as part of the first annual sampling event for the Davis Park Road TCE L TRA. 3.1 GROUNDWATERSAMPLING 3.1.1 Monitor Well Sampling Procedures WESTON mobilized to the site the week of 7 February 2006. With the exception of one location, MW-6, which could not be accessed, groundwater samples were collected from all wells in the monitor well network from 7 February through 8 February 2006. In order to ensure their location during future sampling events, all LTRA sampling points were logged with a Global Positioning System (GPS) unit during this sampling event. The results from the GPS survey are presented in Table 3-1. PDB samplers were used to sample the eight monitor wells that can be directly accessed at the Davis Park Road Site (MW-I through MW-4, MW-12, MW-15, MW-20, and MW-21). Hanger assemblies, to which PDBs in protective mesh were attached, were placed at selected depths along polypropylene ropes for each of the accessible wells during the February 2005 sampling event (see Table 3-2). During the February 2006 sampling event, each of the PDBs was pulled and pierced with a small discharge tube which allowed the transfer of the groundwater to 40 milliliter (ml) septa vials that contained hydrochloric acid preservative. After the sampler bag was disconnected from the rope. K:120064\205\First Annual\Feb06FirstAnnuallRpg.doc 3-1 RFW205-2A-AVEI I I I I I I I I I I I I I I I I I I I I This document was prepared by Weston Solutions, Inc., expressty tor EPA. It shall not be disclosed, in whole or in part, without the express written permission of EPA. Sam~le ID I Status I t\.·1W-I monitor well MW-2 monitor well MW-3 monitor well MW-4 monitor well MW-5 carbon unit MW-6 carbon unit MW-7 carbon unit MW-8 carbon unit MW-9 carbon unit MW-10 community well MW-II community well MW-12 converted well MW-15 converted well MW-16 private MW-17 private MW-18 private MW-19 private MW-20 monitor well MW-21 monitor well Note: NA = Not A..:ccsscd Table3-I L TRA Monitor Well Sampling Network Global Positioning System Coordinates Davis Park Road TCE Site Former Designalion(s/ I Latitude (Nl I MW-ID 35" 13' 36.88 ~-tW-2D 35" \]' 36.26 MW-JD 35" \]' 35.20 MW-4D 35" \]' 39.33 CO-I. PW-2. 121 35" I J' 54.36 CO-13. 235 NA 298 35" 13' 29.16 252 35" 13' 52.24 182 35" \]' 44.90 CO-2. 300 35" 13' 45.91 CO-3. 269 35" Jl' 43.9 I CW-5 35" 13' 44.57 CW-7, 175 35" \]' 47.35 CO-5, 195 35" \]' 37.80 C0-14. 286 35" 13' 36.88 192 35" 13' 37.49 277 35" 13' 33.39 -35" I 3' 50.88 35" I 3' 44.69 3-2 K:\20064\205\FirstAnnuaf\Feb06FirstAnnualRpt_tblS Longitude (\\11 I -81" 12' 50.89 -81" 12' 50.35 -SI" 13' 11.88 -81" \]' 12.69 -81" \]'05.91 NA -81" 12· 59.69 -81" I]' 11.25 -81" 1]'09.21 -81" \]' 21.14 -81" \]' 15.56 -81" 12' 56.72 -81" 13' 05.63 -81" 1]'02.30 -81" 12' 53.59 -81" 12'57.23 -81" 12'58.37 -81" \]' 10.94 -81" 13' 11.92 I I I I I I I I I I I I I I I I I I I Well ID Former ID MVV·1 MW-1D MW-2 MW-2D MW-3 MW-3D MW-4 MW-4D MW-12 CW-5 MW-14 CW-4 MW-15 2232 Tate MW-20 North Lendora Dr. MW-21 South Lendora Dr. ft bgs = feet below ground surface ft msl = feet above mean sea level Table 3-2 Passive Diffusion Bag Sampler Placement Davis Park Road TCE Site Screened Geophysical Interval Probable Water Zones Elevation (tt bgs) (ft bgs) (tt msl) 40-75 38-44; 65-68 688 21-54 20-33; 40-44 685 86-150 83-100; 108-145 746 130-142 130-142 740 68-103 82·82.5; 100· 103 707 ?-74 .. 768 ?-143 .. 721 163-173 .. 768 125-135 .. 721 Sampler Depth (tt bgs) 58.5 36 108 129.5 75 68 135 128, 133 167, 173 Geophysical probable water zones are based on interpretation of previous downhole logging conducted as part of the 1998 RI Sampler Elevation (tt msl) 629.5 662 659 610 627 705 591 705 591 I I I I I I I' I I I I I I. I I I I I I This document was prepared by Weston Solutions, Inc., expressly for EPA. It shall not be disclosed, in whole or in part, without the express written permission of EPA. February 2006 First Annual Sampling Event Report Davis Park Road TCE Site Section: 3 Revision: 0 Date: May 2006 a new filled PDB sampler was attached and placed downhole at the same depth. The PDB will then equilibrate with the surrounding groundwater for the next annual sampling event. All samples were placed on ice pnor to shipment under CLP protocol to EPA -SESD Laboratory, located in Athens, GA, for VOC analysis using EPA Method 8260. 3.1.2 Community and Private Well Sampling Procedures Community wells MW-10 and MW-11 and private wells MW-5 through MW-9 and MW-16 through MW-19 were purged and sampled from the in-situ pumping system, but prior to any filter mechanism that may have been in place. Wells were purged at approximately I gallon per minute for a period of approximately 15 minutes. Specific conductivity. pH. temperature, dissolved oxygen, and oxidation/reduction potential were measured approximately every 5 minutes during the purge process. Purging continued until parameters were stable for three successive readings, and samples were collected directly into pre-labeled, pre-preserved 40-ml glass vials. All samples were placed on ice prior to shipment under CLP protocol to EPA - SESD Laboratory, located in Athens, GA. for VOC analysis using EPA Method 8260. Water quality data sheets and field log notes are provided in Appendix A. 3.1.3 Field Quality Assurance/Quality Control Samples One rinse blank, one trip blank, and one duplicate sample were collected during the sampling event. The rinse blank was collected by pouring laboratory-grade deionized water into the PDB and collecting directly into pre-labeled. pre-preserved 40-ml glass vials. One trip blank was collected by pouring lab-grade deionized water directly from the deionized water container into the sample vial prior to commencing field activities. The trip blank was stored with collected samples throughout the sampling event. The duplicate sample was collected from well MW-I 5, K:120064\205\First Annual\Feb06FirstAnnuallRpg.doc 3-4 RFW205-2A-AVEI I I I I I I I I I I I I I I I I I I I This document was prepared by Weston Solutions, Inc., expressly for EPA. It shall not be disclosed, in whole or in part, without the express written permission of EPA. February 2006 First Annual Sampling Event Report Davis Park Road TCE Site Section: 3 Revision: 0 Date: May 2006 using two PDB samplers. All samples were placed on ice prior to shipment under CLP protocol to EPA -SESD Laboratory, located in Athens, GA, for VOC analysis using EPA Method 8260. All samples were analyzed for VOCs using EPA Method 8260. Analytical results for the QA/QC samples are summarized in Table 3-2. No VOCs were detected in the trip, rinsate, or field blank samples. Cyclohexane, a common laboratory contaminant, was detected at a low concentration (l.4 µg/1) in the original sample MW-15 but not in the duplicate. All other detected constituents were reported at the same concentration in both the original and duplicate samples. 3.2 GROUNDWATER ELEVATION WESTON collected water level measurements referenced to the top of the well casmg for monitor wells MW-I through MW-4, MW-12, MW-15, MW-20 and MW-21 on 7 and 8 Febmary 2006 (Table 3-3). Depth to water was measured using an electronic water level meter. The water level probe and tape were decontaminated prior to each measurement. Figure 3-1 provides a potentiometric surface map of the bedrock aquifer. As in the previous two semiannual sampling events, data from monitor well MW-21 was considered anomalously high, and not included for development of the potentiometric surface map. As in previous sampling events, the water level in this well was carefully evaluated and measured at various times during the event to confirm findings and to evaluate for potential fluctuations. The water level remains anomalously high relative to the other monitor wells in the well network. It is likely the well is screened in a low yield fracture that equilibrated ovenime to the current elevation. The measurement was agat11 not included for development of the potcntiometric surface map. K:\200641205\First Annual\Feb06FirstAnnuallRpg.doc 3-5 RFW205-2A-AVEI -' - ---- -- - -- -----This document was prepared by Weston Solutions, Jnc., expressly for EPA. It shall not be disclosed, in whole or in part, without the express written permission of EPA. Table 3-3 L TRA QA/QC Laboratory Analytical Results Summary February 2006 Davis Park Road TCE Site Sample I dentiflcatIon: Trip MW1RB MW1FB Blank PDB Field Blank Rinse Blank Date Samoled: 2/8106 2/8106 Volatile Organic Compounds (ug/1) Cyclohexane WWW cis 1,2-Dichloroethene ND ND tTrichloroethene ND ND Notes: Only constituents that were detected in at least one sample are included in this table. ND= not detected in sample Balded values exceed EPA MCLs PDB = Passive Diffusion Bag Samples were analyzed following CLP protocol. 3-6 K:\20064\205\FirstAnnual\Feb06FirstAnnualRpt_tbls I MW-1s I 2/8106 duplicate 1.4 ND 3.4 3.4 40 40 -- - ----- -- - - - --- --- This document was prepared by Weston Solutions, Inc., expressly for EPA. It shall not be disclosed, in who!e or in part, without the express wntten permission of EPA. Sample ID: Former ID: Street Location: Screened Interval: Total Depth (record): Date: Top of Casing Elevation (tt msl): Depth to Water (tt bloc): Water Elevation (ft msl): Notes: It msl = feet above mean sea level ft btoc = feet below top of casing J It= feet K:\20064\205\FirstAnnual\Feb06FirstAnnualRpt_tbls MW-1 MW-2 MW-1D MW-2D S of Cedar Oak 2816 DPR 40-75 tt 21-54 75 54 2/8/06 218/06 687.50 684.6 3.96 4.78 683.54 679.82 Table 3-4 LTRA Groundwater Elevation Data February 2006 Davis Park Road TCE Site MW-3 MW-4 MW-3D MW-4D N of 2400 Skyland 2415 Skyland 87-150 130-142 150 142 218/06 218/06 746.29 740.0 23.73 34.22 722.56 705.75 3-7 MW-12 MW-15 MW-20 CW-5 CW-7 Cedar Oak Subdivision 2332 Tale Lendora N 70-112 Unknown 163-173 112 143.3 173 218/06 218/06 218/06 707.21 720.99 743.72 13.90 4.98 24.13 693.31 716.01 719.59 - -- MW-21 Lendora N 125-135 135 218/06 750.85 13.74 737.11 I 1 r N 11 W----E I s I () I I I I I I I I I I I I I I 0 c::i 0 000 00 0~0,o-" ,,<fa'"" of::J 0 0 c:> <'.>CJ. 0 □ 0 0 0 000 0 ~o 0 0 <, D CJ ◊ ('.)a ® r:,., <> ,,,,. GARAGeb fJ // _ 1'1-0 0 ,,,,.,,, \~ II \ '0'<-<> ' ~ oo,e,cc, ' \ \ C D DD D o□ ' 0 RICHLAND AVENUE DO D D b=□=□=o GLENRAVEN AVENUE DDDCIOC:Jo □ #h ~ \) c::io□ooc::, 0 CEDAR OAK CIRCLE ~ \ ·~ 0 <> 'V l,, .. 9.'f.1~~1 D o~1o C)Cl oO 0 0 □0 \ 1, ·-~ '.% ·c ,~ ·. I;). \ <> {J r \ II ,,,,.,, 0 ( ) <>(/ ◊ <) ◊ o<> <><> o<> ® ~ ~i.-:=a: oJF°l\O D " #:2.'\ II ,,o 0 II 0 ~ 0 ~<:.,1':.>~ ,o~· 0 > , , 0 ll. D D D 0 D 0 Cl ~'/,,;·o 0 -S~N D () $z9® oo 0 ◊ D "',,.., I D D~D ® D I I J~~~ ii~~~AL; .,, " ,,,,., I l,~·&'•) ® _I I I I I I \\ """~(' \t,1/ #'"1 " ~ \ I D LEGEND ♦ WELL LOCATION (755.0) --705 --WATIER ELEVATION (ft msl) 5ft. CONTOUR INTIERVAL POTIENTIOMETRIC SURFACE □ w -1-->--1--Ul Z :::) w O <l'. ~Uz __J ozo <l'. 0 O:'.'. 0 1--<l'. O:'.'. (J) u <l'. ~C):r: O:'.'. -1--<l'. <l'. O:'.'. 0... -0 Zz (J) 0 -1--> (J) <l'. <l'. OG 0... <l'. 2 O:'.'. 0 r') a, 0 II~ 0 0 I l"-lf) O 0 N g ll"' .ol!:1 C?O I ,< N v, ~ "' ,. ; "! ~~ C: Q_ ~ 0 ·5 <l{) ~ 0 0ou-o (f) w "' I .. a::i:-.:n i (f) :::, I < 0 "' 0::: • >-·-0 y: :s LL. :::) O:'.'. Ow<.D 1--Li... 0 Z-o 0 :::) -uoN,J, <l'. >-w u O:'.'. a:: -~<l'.:::, O:'.'. u S2,, f--:::) LL wOO:'.'. :::;;;: D:'.'. m 0ow -Wu... 1--m z w 1--0 0... z 0 i7i 5 w a:: ~ -,: 0 0 > a:: 0.. -,: I I I I I I I I I I I I I I I I I I I This document was prepared by Weston Solutions, Inc., expressly for EPA. It shall not be disclosed, in whole or in part, without the express written permission of EPA. 3.3 GROUNDWATER ANALYTICAL RESULTS 3.3.1 Groundwater Samples February 2006 First Annual Sampling Event Report Davis Park Road TCE Site Section: 3 Revision: 0 Date: May 2006 Consistent with previous L TRA sampling events. TCE and PCE were the only YOC constituents lo exceed the ROD Performance Standards in groundwater samples collected during the February 2006 Annual L TRA sampling event. TCE and/or PCE were detected in groundwater sampled from 7 of the 18 wells sampled. The Performance Standard of 2.8 µg/1 (TCE) and/or I µg/1 (PCE) was exceeded in 5 groundwater samples. TCE exceeded the ROD Performance Standard in the following samples: MW-2 (2.9 µg/1), MW-9 (12 µg/1), MW-15 (40 µg/1) and MW-17 (13 µg/1). PCE exceeded the ROD Performance Standard in the following samples: MW-2 (2.6 µg/1), MW-17 (7.4 µg/1), and MW-18 (4.2 µg/1). Monitor well MW-6. which has historically exceeded the ROD Performance Standards for TCE and PCE, could not be accessed for sampling during this event. Laboratory analytical results for first year through fourth year L TRA sampling events arc summarized in Table 3-4. The February 2006 analytical results are summarized graphically in Figures 3-2 and 3-3 for TCE and PCE, respectively. Laboratory analytical reports are included in Appendix B. The highest TCE concentration (40 µg/1) was detected in groundwater sampled from monitor well MW-15, located at the west central portion of the site. The second highest TCE concentration (13 µg/1) was detected in groundwater sampled from monitor well MW-17, located on the southern side of the site. The highest PCE concentration (7.4 µg/1) was also detected in groundwater sampled from MW-I 7. The second highest PCE concentration (4.2 µg/1) was detected in groundwater sampled from MW-18, localed immediately north and west of MW-17. K:'200641205\First Annual\Feb06FirstAnnuallRpg.doc 3-9 RFW205-2A-AVEI ------- - ------ Tr11s clo:ument ,..as preparea t,y Weston Solubons. Inc .. e~pre.¼ly tor EPA. 11 shall not be d1sclosea. ,n wnole or 1n part, wunout Ille e,press ·1111tten porm,ss1on ot EPA. Table 3-5 LTRA Laboratory Analytical Results Summary April, September, December 2002; March, August 2003; February, August 2004; February 2005; February 2006 Davis Park Road TCE Site , ;>&ffil"• 2816 "' Location: ~,oak "" Jlalc~•m,lnl. \po-U.' .......... li.,-u.' M•,-"·' \~.~•.l ><= -~~ F,1>,11; hb_,.. \ov.<,.' i,,.,....11.' lh-4.' ~1 .... ..-.i Aue_.., •= \uo.t-1 ht>-'15 l<M'6 , ... ..(I! .... a.' 1 • ...-ti...-...,g,anic n1oroniet1,ane 0.28J 0 28.JB 1. t-Oicnlorootriene 0.51 0.31J !A,celom, ~olhytene cn1onoa " " ,OJ 28A .. ,bon o,sulhde MAfhyt T•Buryt Emer " " 1.1-0,cnloroelh,me 1.1-Dicnloroolhane rans 1.2-D,cnloroemene ·,s 1.2-Dochklo'oethene Matnyi Elhyl Ketone ,, 6.9 Chlorolorm 0.HJ 0.528 0 37J 0.50 0 32J O<OJ BenZl!lld .1. 1 -Trichloroom,me 0.48.J 0 5' 0 43.J °'" 0 31J OJSJ 0 24J Cyclohe,rum 0.50 °" 1.2-Dic:hloroomane ricnloroothene ,.o ,., .. , u 2.9 ,.o 2.7A 2., 2., Mathylcyclone,ane Melhyl lsobulyl KetllfiB 1s-1,3-01Chlorop1openu oluene etrachloroomene 2., ,., ,., ,., 2.0 " 1.9A 2.0 2.6 0 22J lhylt,eOLane 023J 0.52AJ 0.40.J Olal Xyllffies 0.19J 0.35.J t)romotorm 1.3-Doclllorobenzene 1 4-D.ch!orotJCnzene No10: Only consu1uents 01.31 weie delected ,n al leas! one sample aunng lht' tiasehne sampling event a1e included in 1t11s taule J mOlcates esumat.:.d valu€: N mOCates pre,,.umptr,e &;!<Jenee or matenaJ: A= Analyte analyzed ,n rephcate. Reported value •~ ·a...erage• o1 replicates Bol08-d valum; e•cood ROD Pertormarice Standalds sampl~ we.a analyzed IDIIOWlfl!l CLP protocol ·-,na,cates not OO!oc!ed atxwe the repo<tmg hrmt l"'--".' ,0 0.18.J 0 24J 0.15.J ---- ,., N of 2400 Skyland \br-".l ht>-41 \u•.o.l f,h--1>!' ·~· ' ss, " " 3.0 " " " 6f> "'" 0 23J 0.18.J 020J 0.1 lJ '' -- - -- - - ----- Th,s document was prepartl'd tr{ Weston 5olullons, Inc .• e,p,essly tor EPA. It shall not be d,scloi;ed, ,n ..t,ole or m part, withool lhe e,press wnnon pmm,ss,on of EPA Table 3-5 LTRA Laboratory Analytical Results Summary April, September, December 2002; March, August 2003; February, August 2004; February 2005; February 2006 Davis Park Road TCE Site Location, ll~k ~~•nulul· ~pr-'l! ·--~ v,paruc "ompou ~,-,,., htommalhane 1,l•DichlOfoeltlene IA,.::etooe ~'31hylane Chlonoo !Camon D,sul1,oe ~11,yt T·Butyl Elher 1.1-0,chlorootnene 1.1•0,chloroetnane ans 1.2-0..;nloroomene IS 1.2-Dichloroetne,ie Mllhyl Ethyl Ketone t;:n1oroform ~enzene 1.1. 1 •Tnchloroelhane -fClohe.ane 1.2-D,chloroemam, nchloroolh._.,e ~,itt1ylcyclotw,ane ~lhyl lsot>ut,1 Ke1011e •s·1.3·D1Ch!oroprop,;ne lfloluene ltTBll<1Chloroe1nene IJ::tt,y1r.,eo1ene U,-otal Xyl11nes ~romotorm 1.3-01chl0<oben1ene 1.4-0IChlOl'O(,eoze,,e Note: 0.48..J 0.lBJ 11,,..u! ,1.,~I.i 0.17J Only consntuonts th,H wrne cturncted m at least on<c1 samr~e dunng !M bdS-etme samplmg event a,e incluOe<;t in lh,s labte. J Ind1<:aIos e:.t,matad valu&. N 11wrc;,Ies presumptive evidence of ma1enaI: A= An.llyte analyzed ,n replleate. Reported val.Je Is •ave<ag11· of replicates Bol<ied ·,aI11es e,ceoct ROD Pef1ormance Standanls Samµles were anal,-zed tol1ow,ng CLP p,<otocol. --mdlca18S JlOI de!ec;l"'1 af>O\le the reporung hmll """ 2415 Sky land ~~~-l!.1 0.18J 0.'6 f',b-0-I 0.33.J " HJJ 8.6 0.14J o.ru 0.45.J hl>-•16 oso '' ,., 3-11 V.15.J 0.15.J LSJ " ... rl"-5 2419 oeR ,., 0.32J 0.1 lJ '' 0""' 0 67 0.57 0.13.J - " 0.16 L6 0.16J ,., ,., - .. 2717 OeR I"'•"! \lot~/3 0.59J 0.33.J 3.9J H 2.7J 3.0 0.llJ - 0.34J 0 20J ,, ,., 0 3()J 0.31J 3.0 ,. 0.11J G.11J - --- - -- - -- ----- This docunlll<lt was prepared by W,:,ston SoluhOM,, Inc .• e,pressly for EPA 11 shall not t;,e di!>elo5.ed, in 11,hole or u, pan, ,.,mout lhE, e•pr~s -..Tlttefl r'-lfllll~ioo o! EPA. Table 3-5 LTRA Laboratory Analytical Results Summary April, September, December 2002; March, August 2003; February, August 2004; February 2005; February 2006 Davis Park Road TCE Site Location ll~te :-:~n, 1.-,l. ...,....! e urganc .. om Chk.lfomelhdne 1, 1 •D,cnloroott1<Jne Aceton'-' Methylene Chlonde O::arbon D1su1t,oo Mtllhy1 T-Butyl Erna< 1.1-01chlo,o,ithene 1.1-D1ehloroomane r.ms 1,2-0..:hloroothene ,s 1.2-D1ehlomelhene ;..e1nyt Ethyt Ketone t::;n1orotorm )3,;nzene 1.1.1 •Trichloroethane ~yc1ot1e,ane 1.2-D,cnloroelhane trncntoroelh\lf1e ~0U1ylcyclohox;me M81ny1 lsobutyt Ketone ·,s-1 .3-0,cnlorop,opene Oluene tr etracn1oroelher10 ielhylbehleflO h"otal xy1en-,s ~romofonn 1.3-Dochlomt,enzeoe 1 .4-D,chlorutJOnzeno 0.17J 0.19J •.. , 2537 0.12J 0.lGJ 0<1ly corn;btuents thdt w01t> oetoctoo ,n at least one sample <Junng the ~elme samphng evBfll are 1nciude<l ,n 111,~ table J ,ncticates esbmated val11t1; N mlllcates preMJmpt,ve ev,dence ot matl;lfla.1; A " .O.nalyte anatyie\\ m ,ep1,ca1e. Aeponoo ,atue •s ·a,erago· ot rep11ca1ei.. Bolded values e~cood ROD Perto,mance Sla/ldafds Samples wern analyze<] tollvwany CLP pr01ocol. --md,cut.,,; IIOl detac:IW above the ,eporung lom,1 ... --"! 02'.J 0.23.J LB 02'.J 030.J 05() 0.32JB L2.J 6.8.J 20.J 0.12J u 0.16.J ,.., ,., 0.42J 0.16.J 3-12 0.16.J 0.12J 0 12J ,., 0.67 'O.J 8.5.J 0,14J 0 44J ,. •• ,,., 20, 036.J 0 36.J ,., ,.,. Springbrook \l•c-11• •u~-UJ l,Ml-l 0 30.J 0 14J 0.16.J 0.18J L6 O,&J 0 88 0.15.J 0.14J 0,8.J 0,42J °'' " '' 0A~J 0.J9J -- 0.15.J 0.77J 093 LJ ,., ,. " 0.3-IJ --- ---.. -------- Tn•'i document •as preparoo t,y Weston Soluboni;, Inc., e,pi-es.sty 1or EPA. n shall riot r;,e dIscl0Se<I, m wtlole or m part w;lllout lhe exi:wess W111\en pomus.s,oo ol EPA. Table JAS LTAA Laboratory Analytical Results Summary April, September, December 2002; March, August 2003; February, August 2004; February 2005; February 2006 Davis Park Road TCE Site ::,ampoe ,u, Location· h.1k~.1n1111-d: ,,.--<t! • A! 10.,.-111 Ma,dl_, JVOIB/1/e organic r::ompou n~(Ul,l'•J t:111of0melhane 045.JB 1, l•Dichkll'ootllene !Acetone ~thylooe ChlooOO )::arboo O,sult1de Ue111v1 T -Butyl Emer 0.1,J 1.t-DIChlofOOU'lane 1 • 1 -DIChloroethane luans 1.2-D,cn1oroot1,ene IS l.2·01Ct1loroelhene Melll,'1 Etnyl Ketone Chlo,otom, _,<?nicene 1, 1, 1-Tr,chloroomane k;yc1orie,ane 1.2-Dichlomeu,ane trnchloroelh1me 0,16.J 0.15.J 0.16.J Methylcyclohoxa,,e ~!tlyl lsot>ut;-I Ketone ·1s-1 .3·Dlcill0fopr0p808 oluene ... ITotrachloroethooe 0.t6J 0.20J 0.2-IJ lelhytbonle<ll! !Total Xylenes ~romo1orm 1.3-0,ct,l{)f()ti.,n:0<\e 1.~•D,chloroLe!liene Note: Only c-onsi<tuen~ thal we<e dotOClf'd m at l~I one sample duung tt,e baSehne sampling Eo•ent are ,ncto.><Je<I m this ldble J ,nct,cate~ esbmat&d value: N indicates p,-e$Ump11-.e 1N1dene11 or materiaJ: A= Analyte analyzed In rep1,cat11. Reponod Mlue ,s ·a•Arage· o! rephcates. Soloed valu% fl•Ceed ROD Pei1ormance Standards SamplPs weie arIaly·zt,1 tollowmg CLP prntocol •· m.-i,catcs not OO!octtKJ abcNe !he reporting hmll ....... ,o .•. ,, ,.,. '"' Skyland Briar Oak ,..,,-4., •·= ... ~ • ..,..I!' ·~· \p<-'I! 11.,-11: ~, ..... , , .. : ... -• l•f>-•M \uo•M 0.52JB " 0.47J 06'J 03.J '"" 0.24J 0.11J 0.11J 0.17J 3-13 l,MI, 0.16.J --- - J.t,...( .. -------------- Th,s documen1 wilS preparEl<J tr; Wes1on Solutions, Inc .. e,p,essty IOI EPA. II shall not t>e ci,sclosl!d, In whole o, ,n pan. wilhoul the e,pie!>~ wnneo permission ot EPA. Table 3-5 L TRA Laboratory Analytical Results Summary April, September, December 2002; March, August 2003; February, Aug1:,1st 2004; February 2005; February 2006 Davis Park Road TCE Site ~m.,...,M, "' ... M-.i-1J m 2719 22'1 "'" Location· o,a Cedar 0.k "'" lJalt~am,k-<I; \pr ij! ........ ! IIH_.! Mar~\ \""..U.l ><= h;:4' f<MI~ 1,1>_ \~-'ii! _,,,., 1 .... ,c ... --•! 11n.-<1! ~, .... ~, \~~"'°-' .. , p.llllC._ompou -'(U.,.,, r1Joromethane 1 • 1 -D,chloroothene D "" IAceione '" \Aelhyteoe Cnlonae arbon o,w11100 ~lhyl T•Butyl Ether 1, 1-D,chloroemene 1, l·DICMl)rOOltlane ans 1 2·Dichlo,oemen-e ·,s 1 2-01Chlorooll1e<1e ~lhyl ElhJ1 Ketone ,.2 f;:n1orofonn ~enzene 1, 1,1-TuchlOroolhdfle 038.J t;:yclohe,ane 1.2•Dichlomelhane nchloroo\hr,o., ,.o '' , 1 2.< " ,., 2.D 22 2.1A 0 49J "'" 027J 0.25.J ~thylcyclohe,ane ~lhyl lsobulyl Kecone 0.16.J .,,..1,3•011:tlkl<oprop,,oe otueoe 0.17J 0.19J 0.59 eu-a,;;hloro,nnene 1.6 '·' °'" o.,g 0.88 ,.. 1.1 1.2 1.0A Elhylbenzone oldl Xylanes 0.14J """ ~•omotorm 0.20.JB 0.20J6 1.J-011:hlorot,tm;,-ene 1.4-DichlorOl~;nzene 0.12J 0.12J Nole: Only con,.otuents 111,u were detecled Ir1 at lei!!>t one sample dunng the bdselme ~ampi,ng ENeot a,e mcludad in IM", table J I11d1Cd!es e,,tunatad ~alue: N mwtall/$ presumptl\'e a,,odenca ot malanal: A "Am1IY1e analyrn<l In rephcata. RllP(lrted value ,,. ";,veraga· ol repticateo.. Boidl!d values e,ceod ROD Partorrn.1nce StandanJs Samples were an<1lyzad loilO"IMg CLP protocol, --lfldieattl5 not deloctad abovtt Iha reponmg 1,m,1 3-14 ·- ,., " 0.22J ---- \~o•'-1 /',h-0!' 30 -- -- - - - -------- This oveument wa,; prnµared by Weston SoluUOfls, lr.c .. e•pres~ly tor EPA. 11 shall not b8 <ISCI~. ,n -..tJole or ,n pan, wilhOut the e•pr= wnlloo perllll~,on ot EPA Table 3.5 L TRA Laboratory Analytical Results Summary April, September, December 2002; March, August 2003; February, August 2004; February 2005; February 2006 Davis Park Road TCE Site -mfl'e , ... .,. '"' ,n5 Location ,.. Puritan 11.ilt Samult"d ",,Ul 1 .... ,,i M,r.11.' \ue••·' t.t, ..... \ue-0,l hh-ll~ f,t,""" ..,~,1 [).,,•-0! ,1., .. ,.1 ,u;-u., ld,.IM .......... f<t,-fl~ ~•h""' ••--<I! -..-ail v .... ,1 ,..,_ti,., v,fil"tllC ~om n1oromett,ane 0 11JB 024J 0 40JB 1,, -Dict,1oroethene Acetone " n, Melhytene Chloo<>o! '"' ;imon o,suu,c1,., '·"" 030J '"" Methyl T·But,1 Etner 0.25J 0.H;iJ 009W 047J 1, 1-oic111oroetnene 1. 1 ·DIChlOIOOlhano 0.20J 0.17.J 0.27J 0.22J ldflS 1 2·01Chl(lloelhe11e 0.!5J Is 1 2·D.:::hlomelhene " 26 3.6 2.6 ., 3.3 36 3< '·"" Mi myl Ethyl Ke1ono 93 Chlorn1orrn 0 22J 0.31J 0.25JB 0.27J Bl!Nene 1.1., -Tncl'lloroethane 06' 0.47J 04~ Cycloho,ane ''" '' 1 2-Dichloroemane nchl.:>roolhene 50 ,. '° " 50 " " .. " '3 ,,., MtJthyicycluhe•ilnit Memyt bobutyl Ketone :is-1,3-Do:::hlorOPfopene oluene euach!oroo!heno 0,3\J 0.21J 0.21J om 0.30-' 5., 5., . .., lhytbenzllfle O.tOJ otal Xytenes 022J ~romof01m l .3· DIChlof()O(,nZ<me 0.35.J 1 4-DIChi.J<Ot>enlene 0.23.J 0.33J 02ill O.Jru 0 3-IJ NOie: Col)· coos1,1uems lh,11 we1e llllt&.:ted ,n at lear.t one samj:R durmg Iha bas.,hne samµhng es.·ent are includad In lh,s talJle J indicates est1ma1eJ value: N mdIca1es pr.-i~ump~ve ;,vodencil or m<1tenal: A" An,1tyte anatyze,a ,n rephcate. Reported ,aiu.e ,s ·aoe1<1ge· of rnp1..:ata!i BolUod values e,cead ROO Perlormance SIanoanls S.imples •N8fe anal;78C foHo .. ,og CLP protocol •· ,no,ca1es not 0<itecI8d abOve 1110 reportmg I,m,i 3-15 \J-,.jj\ ,e O,W o,w 0.70 " '2 -- - - ... , ... IJ 2816 D>A '""''·' ><= ""~"1-1 f,lo--<1~ F,h-Ot. OJ,C 035.> 060 098 0.98 061J oa, ,o °" 0 22J 0 J6J 0.57 OS •• " " " '3 •. , 9.0 65 5.3 , .. - - -- - - -.. ------- This document was p,ep.-irod by Wes10,, Solu11ons. Inc., exJ)fes&ly !o, EPA. II s.hall no1 be disclosed, ,n whole o, ,n part, wilt\Oul 1he exprsss ,,-rmen pa,nu¼IQO o! EPA Table 3-5 LTRA Laboratory Analytical Results Summary April, September, December 2002; March, August 2003; February, August 2004; February 2005; February 2006 Davis Park Road TCE Site ~m -·'·" ..... ,, Mw'-2(l 2800 2833 2416 Location, DPR Penny Pan. Skyland \l.,lr.,~onok~I. \ ... u: ~n-.1• V.-..-01 Mu-O.• \•e-t1.• .. -hb--0~ .. .,_.,. \I.,~ .. , ho ... J ht....» \•~""" f,l>>I.• r,,,~~ ,.~ .... _. t,t,.,,.. \••-0-I f<h-U~ hhl>b ou,ti,e v,~mc Lompou,,. ·~" hklfooIetnane 0.44J I • 1 -D.:hloroechene l!Aco,to,,.e s, '" ~lhylene Chk>oOO ~arbon D,sulhOe i>,4eu,yt T-Butyl EIDer n ., fAA '° 99 1, 1-Dichlowetriene \, 1-0ichloroelllane 0.11J rans 1,2-D,chlCM"oothene ;is 1.2-0ich.loroelhorle 021J 0.14J Mtilhyl Ethyl K11tone I1Iomf01m ):lenzene 1 , 1 .1 • T r.:::nlo,oelhami t;:yclolle•dll<:l 0.81 1.2-0.:::tll0<oelhane 0.15.J r.:::hloroemene ., ,., ,.o., .. ... ., " 2.0 0..14J 02◄ J 0.4lJ "" >,.ett1ytcyclooe•dlle ~em-,1 lsobutyl Ketone ·1,..1 .3-0.:::hlo,opmp,me oluena "'-' 0.42J 0.35J etrochl0<0€lh<lfle ,., " ,_,., ,., " .. , ,., ., 03'J 0.26.J 0,39J 025.J 0.90 1Ett1V1beflzane 0 31J 1.1A u " otal A','IOl\85 "'-' ,., ~1omo1orm 1.3·D.:::hlorobenzane 1 A·D.:::hlorot>.l<uene Nole Only cons1,1uents 1t1aI -..ece ootec100 10 at ledSt one si1111ple dunng tne Da5elmo ;.ampllog e-.ent are 1r"1Cludod 1n ltlcs tabltl J mOicates e5t1maI00 Vdlue: N mt1.:::ate5 pre5umpll\/e evidence ot material: A= Anatyte analylOO m repllCale. Reported value ,s •average· of ropf,carns. Bolded v<1lue5 exceoo AOO Pet10<manco S1andan!s Samples ;r,ern analyi...:I tollowmg CLP protocol •• 1ndlca1es not detecled above 1tle reporung 1Im11 3-16 \•~,u ,., ,, 090 0.74 0◄4J ---- _,.,.,, 2419 Skyland t',M4 \u•.Q.I f,P,,il~ l<h--<111 ''-' " '"' :..6 62 '' 7.7AJ 0" ,., 0.35.J °''" oow u 0 92AJ 2 ,., Ul 0 <> <> Cl 0 () 0 = 0 D o □ D CJ l:':i D ENN'r D 0 D ◊ G (:) D D 00 Cl 0 I] D ~o D z ~□ D z ~D CJ :a D 0 D 'i) D Q rtl•,; (26"---;\!># D ~ a 0 ~ □ 0 D ~□ 0 C 0 rn ,' D 0 □ ~ □ ~ □ D 31\ll:jQ 0)<0cJ.1HVH □" D □ -· --------------· i;; ,I ~ z z " □ 0 0 ,,, 0 r --< --< z r 0 I V) 0 r r > "' 0 0 "' '" ,, () 0 > " () "' cl i;; '" 'i' 0 C, 0 "' z z "' () 0 z () ,,, z ,I > cl 0 z V) z C ~ > / DAVIS PARK ROAD TCE SITE ~- GASTONIA, GASTON COUNTY, NORTH CAROLINA TCE CONCENTRATIONS IN DRAWN: DATE: W.O. NO.: GROUNDWATER FEBRUARY 2006 K. SPIKES 05/02/06 20064-205-100-0930 LAYOUT: CAD□ FILE: SHEET: Of APRVD. DATE: REVISION FIGURE 3 2 Fig-3-2 davisp □rk.dwg 1 1 0 D D / APRVD. DATE: 0 G 0 D REVISION 0 <> \) I.:, D n D > • io D Q ~ D !) a (;> 0 □ DAVIS PARK ROAD TCE SITE GASTONIA, GASTON COUNTY, NORTH CAROLINA PCE CONCENTRATIONS IN GROUNDWATER FEBRUARY 2006 FIGURE 3-3 D D I] D ~□ D z ~D D z !O CJ C m D D 'i) D D • 0 ~ □ □ □ i □ C m D D □ D D □ D -·-- :fl cn----.j♦IIIIB-30-z 0 = 8 CJ 0. ~,TPc;, a ()',,,i»'J ~ ~ 0 ~ :;:::::; 3/\U:iO ml0.::111:NH 0 --· - z ~ ♦ z ~ ~ .s r e1 ~ "' z z " 0 0 "' .... ;rj r .... z r 0 (/) )> 0 )> () r "' <: I 0 e1 " r () r 0 )> () "' ,, =' e1 0 0 0 "' z 0 ,, "' z "' () 0 z () "' z ;rj )> =' 0 z (/) z C "' '-r -- m~. DRAWN: DATE, W.O. NO., K. SPIKES 05/02/06 20064-205-100-0930 LAYOUT: CADD FILE: SHEET: OF Fig-3-3 davispark.dwg 1 1 -1 g I I 0 g D I D 0 R D 0 I I I I This document was prepared by Weston Solutions, Inc., expressly for EPA. It shall not be disclosed, in whole or in part, without the express written permission of EPA. February 2006 First Annual Sampling Event Report Davis Park Road TCE Site Section: 3 Revision: O Date: May 2006 Detections of TCE and PCE in groundwater sampled in February 2006 at the Davis Park Road site were similar to concentrations detected in previous L TRA groundwater sampling events. PCE and TCE concentrations in groundwater have generally remained stable or decreased at sampling locations during the first four years of the Davis Park Road TCE Site LTRA. There are two areas where PCE and TCE concentrations continue to exceed guidance concentrations. One area is downgradient of the original groundwater contaminant plume center at the southern and eastern portion of the site. The second area is located in the central and western portion of the site. PCE and TCE concentrations in both these locations remain lower than historical detections in the former plume center. PCE and TCE, previously detected in trace concentrations m groundwater sampled from locations west and north of the former plume boundary (MW-10, MW-l l, MW-20, MW-21) have not been detected in any of these monitor wells since February 2004. Pumping from community wells in this area does not appear to be causing migration of the contaminant plume in this direction. Groundwater elevations, discussed in Section 3 .2, support this conclusion. MTBE was detected in the two following samples: MW-3 (l 7 µg/1) and MW-20 (99 µg/1). Groundwater samples collected from these monitor wells, both located adjacent to the 2400 Skyland residence, have historically contained MTBE concentrations at similar levels. MTBE was not detected in any other groundwater samples collected during the February 2006 sampling event. and does not appear to be related to the TCE plume at the Davis Park Road site. MTBE concentrations have generally remained stable during the first four years of LTRA. The ROD Performance Standard of 200 µg/1 for MTBE has not historically been exceeded. K:120064\205\Fi rs! Annual\Feb06FirstAnnuallRpg. doc 3-19 RFW205-2A-AVEI I 0 u I I I I I I I I I I I I I I This document was prepared by Weston Solutions, Inc., expressly for EPA. It shall not be disclosed. in whole or in part, without the express written permission of EPA. SECTION 4 February 2006 First Annual Sampling Event Report Davis Park Road TCE Site Section: 4 Revision: O Date: May 2006 CONCLUSIONS AND RECOMMENDATIONS 4.1 LTRA RESULTS SUMMARY The source for the TCE/PCE contamination in groundwater at the Davis Park Road TCE Site is depleted or removed based on groundwater sampling results reported from the time of contaminant discovery (1990) to the current February 2006 LTRA Annual sampling event. Water sampled from wells north of Skyland Drive (MW-5) and in the Cedar Oak Circle Subdivision (MW-12) contained concentrations of between 44 and 134 µg/1 TCE and up to 24 µg/1 PCE when sampled in 1990. Groundwater sampled from MW-5 and MW-12 in February 2006 did not contain concentrations of TCE or PCE above the ROD Performance Standards (2.8 µg/1 and I µg/1, respectively). Figures 4-1 through 4-2 graphically depict the decreased levels of COCs in these wells. TCE and PCE concentrations in all wells have generally decreased over time, with the exception of the areas southwest central and south southeast of the site. Groundwater sampled from monitor well MW-15. located southwest of the source area, contained 40 µg/1 TCE during the current sampling event. Excluding this groundwater sample, the maximum TCE concentration for groundwater samples collected this sampling event is 13 µg/1 in groundwater sampled from well MW-I 7. The maximum PCE concentration is 7.4 µg/1, also detected in groundwater sampled from well MW-17. Monitor well MW-17 is located on the southeast portion of the site approaching Blackwood Creek, suggesting groundwater contamination continues to attenuate as it migrates toward this natural groundwater discharge area. 4-1 K:120064\205\First Annual\Feb06FirstAnnualApt 1rk chgs.doc RFW205·2A-AVEI ---- i ., C: ., .c: -e .!2 .c: u ·;: I- 1000 100 10 0.1 r C r r F ' ' f ' I r -- ---- - Figure 4-1 Trichloroethene Concentration vs. Time 2419 Davis Park Road, MW-5 Davis Park Road TCE Site Gastonia, North Carolina (ROD Remediation Goal = 2.8 µg/1) -.. - --- - Feb-90 Mar-91 Mar-92 Apr-93 May-94 Jun-95 Jul-96 Aug-97 Aug-98 Sep-99 Oct-00 Nov-01 Dec-02 Dec-03 Jan-05 Feb-06 Date K:\20064\205\FirstAnnual\Figs 4-1 -4-6\hg4-1 --- -- ------- i ., C ., ,:: .; 0 ~ ..5! ,:: <J ·;: I- Figure 4-2 Trichloroethene and Tetrachloroethene Concentration vs. Time 2719 Davis Park Road, MW-12 Davis Park Road TCE Site Gastonia, North Carolina 100 ~-------------------- • •• I ~;-. . ..•... .. .. . . . . . . . . . . . . . .. . ... 10 I ♦ r r .•. I -------------------------------------------' ,---- (ROD Remediation Goal for TCE = 2.8 µg/1) • (ROD Remediation Goal for PCE = 1 µg/1) 0.1 • ---- · .......... .. 1 · .•.. PCE 1 ----TCE I Feb-90 Mar-91 Mar-92 Apr-93 May-94 Jun-95 Jul-96 Aug-97 Aug-98 Sep-99 Oct-00 Nov-01 Dec-02 Dec-03 Jan-05 Feb-06 Date K:\20064\205\FirstAnnual\Figs 4-1 -4-6\fig4-2 - I I I I I I I I I I I I I I I I I I I This document was prepared by Weston Solutions, Inc., expressly for EPA. lt shall not be disclosed, in whole or in part, without the express written permission of EPA. February 2006 First Annual Sampling Event Report Davis Park Road TCE Site Section: 4 Revision: 0 Date: May 2006 Concurrently with the migration toward Blackwood Creek, the August 2003 and February 2004 sampling data indicated a contaminant migration southwest of the source area, as evidenced by groundwater elevations and the detection of trace TCE and PCE concentrations in groundwater sampled from the western side of the site. However, the August 2004, February 2005 and February 2006 sampling results show no detections of TCE or PCE on the west side of the site. Although pumping of groundwater has been discontinued over most of the Davis Park Road TCE Site area, two community wells (MW-10 and MW-11) are currently still active near Briar Oak Drive, west of the site. Community well MW-I 0, located on Skyland Drive, supplies between 30 and 40 people, and MW-I 1, located on Briar Oak Drive, supplies approximately nine people, according to Mr. Doc Thompson of the Gaston County Health Department. It was thought that pumping of these wells might facilitate migration of. groundwater contaminants in a westerly direction. Monitor wells MW-20 and MW-21 were installed in the area between the contaminant plume and the community wells, to monitor for potential migration of the contaminant plume. These wells are located between MW-15 (the well with the highest TCE concentration) and the ctnTently pumping community wells. However, the data from sampling wells MW-20 and MW- 21 do not currently indicate that COCs in groundwater are migrating toward the pumping wells. Additionally, groundwater levels in MW-21 indicate an upward gradient to the bedrock aquifer in this area. This may provide a natural barrier to movement of the contaminant plume in this direction. Monitor well MW-15 is located southwest of the source area, with Davis Park Road to the east and well MW-9 to the southwest. Concentrations ofTCE detected in monitor well MW-15 have fluctuated between 36 µg/1 and 50 µg/1 since September 2002 (see Figure 4-3), similar to historical levels detected in groundwater sampled from converted community well MW-12 (located east and downgradient of the source area, in the former plume center) (see Figure 4-2). TCE concentrations fluctuated between approximately 30 and 50 µg/1 in groundwater sampled from MW-12 from 1990 through 1998. TCE was detected at 2.1 µg/1 in groundwater sampled 4-4 K:120064\205\First Annual\Feb06FirstAnnualRpt trk chgs.doc RFW205-2A-AVEI -- - - - - - --.. - -- Figure 4-3 Trichloroethene and Tetrachloroethene Concentration vs. Time 2232 Tate Street, MW-15 Davis Park Road TCE Site Gastonia, North Carolina --- 100 ~-------- ---■------'\.-------------■------■ 10 ~1 -------------------------------------- f [ I I l i ♦ • • • • (ROD Remediation Goal for TCE = 2.8 µg/1) -- I --~~~+-~~~ f (ROD Remediation Goal for PC:'E e=-1 µ9/I) ' [ l l • . ·• . 0.1 C---~---c---~--~--~---~--~--~---~--~~---~---~---♦-. - Jan-98 Aug-98 Apr-99 Nov-99 Jul-00 Feb-01 Oct-01 Jun-02 Jan-03 Sep-03 Apr-04 Dec-04 Jul-OS Mar-06 Date K:\20064\205\FirstAnnual\Figs 4-1 -4-6\fig4-3 --- 1-· ♦ · ·PCE I ■ TCE I I I I I I I I I I 1· I I I I I I I I This document was prepared by Weston Solutions, Inc., expressly for EPA. It shall not be disclosed, in whole or in part, without the express written permission of EPA. February 2006 First Annual Sampling Event Report Davis Park Road TCE Site Section: 4 Revision: O Date: May 2006 from MW-12 during this groundwater sampling event. TCE concentrations 111 groundwater sampled from well MW-9 (currently supplied with a carbon filtration unit) have fluctuated since August 2000 when first sampled, but have ranged from 6.8 µg/1 (detected in November 200 I) to 16 µg/1 (detected in March 2003) (see Figure 4-4). These levels are similar to groundwater samples collected from wells MW-17 and MW-18, located further south and downgradient of the source area toward Blackwood Creek (see Figures 4-5 and 4-6). Results are consistent with an attenuating plume migrating from the former sources area. 4.2 CONCLUSIONS TCE and PCE concentrations continue to decrease in the contaminant plume as it migrates south and away from the former source area. No additional degradation products of these two constituents were detected at any significant level in any of the groundwater samples collected historically or during the L TRA quarterly/semiannual sampling events. Graphs of historical TCE and PCE concentrations from key monitor wells are presented as Figures 4-1 through 4-6. Figures 4-1 and 4-2 shows the decline of COCs in groundwater sampled near the original plume center from levels well above EPA MCLs to levels either approaching or consistently below the MCLs and ROD Remediation Goals from 1990 through the current sampling event. Figures 4-3 through 4-6 illustrate the fluctuating COC levels in wells located at and downgradient of the current plume center. These values are significantly lower than levels detected at the plume center in the early 1990s, following discovery of the plume. Figures 4-1 through 4-6 support the groundwater concept model (EPA Memorandum. 25 September 2000) that the primary mechanism for the observed natural attenuation of the TCE plume at Davis Park Road is dilution as contamination essentially flushes through the bedrock aquifer. The analytical results are consistent with the proposed cleanup time of 13 years (by the year 2017) to attain EPA MCLs. 4-6 K:\200641205\First Annual\Feb06FirstAnnualRpt Irk chgs.doc RFW205·2A·AVEI -- j ., C: ., ,::. .; e .2 ,::. u ·;: I- -- ' - - ------ Figure 4-4 Trichloroethene and Tetrachloroethene Concentration vs. Time 2639 Springbrook Street, MW-9 Davis Park Road TCE Site Gastonia, North Carolina I _.,_ ••• -·-• --.. I •. ♦..... ♦ ♦• 1:..-.-.--.....---♦---+ --o-----v-' .. --------- -------. - - ---- ---; -.._, __ --- - ----- 1· (ROD Remediation Goal for TCE = 2.8 µg/1) •• ; • •.. __ 0.1 ~-------------------·•-- 0.01 .-,-,-,- i (ROD Remediation Goal for PCE = 1 µg/1) i I 0.001 .. !----~--~--~--~-----------------♦•~------------ Jun-00 Nov-00 Apr-01 Sep-01 Feb-02 Jul-02 Dec-02 May-03 Oct-03 Mar-04 Aug-04 Dec-04 May-05 Oct-05 Mar-06 Date K:\20064\205\FirstAnnuaf\Figs 4-1 -4-6\fig4-4 - -- 1· .•. · PCE 1 -TCE, --------------- Figure 4-5 Trichloroethene and Tetrachloroethene Concentration vs. Time 2816 Davis Park Road, MW-17 Davis Park Road TCE Site Gastonia, North Carolina - 10 ,-~~------------,/--------;-. •---.-.----------------'\-1---------} ., C ., ..c: .; 0 ~ 0 :c u ·;: f- l 0.1 May-90 Sep-91 (R.GEl'Remediation Goal for TCE = 2.8 µg/1) •. 121 · (ROD Remediation Goal for PCE = 1 µg/1) Jan-93 Jun-94 Oct-95 Mar-97 Jul-98 Date Dec-99 K:\20064\205\FirstAnnual\Figs 4-1 · 4-6\fig4-5 ... •♦ .. Apr-01 Sep-02 Jan-04 May-05 - -- 1· .•. · PCE I ■ TCE -------------- i Cl) C: Cl) .r:. .; e ..2 .r:. u ·.:: I- 100 10 f- 1 0.1 Figure 4-6 Trichloroethene and Tetrachloroethene Concentration vs. Time 2800 Davis Park Road, MW-18 (ROD Remediation Goal for.PCE·~J_µg/1) -.,. Davis Park Road TCE Site Gastonia, North Carolina . . -------------------------- (ROD Re~eaiation Goal for TCE = 2.8 µg/1) - - Mar-90 Jun-91 Sep-92 Nov-93 Feb-95 May-96 Aug-97 Nov-98 Jan-00 Apr-01 Jul-02 Oct-03 Dec-04 Mar-06 Date K:\20064\205\FirstAnnual\Figs 4-1 -4-6\lig4-6 - - - I I I I I I I I I I I I I I I I I I I This document was prepared by Weston Solutions, Inc., expressly for EPA. It shall not be disclosed, in whole or in part, without the express written permission of EPA February 2006 First Annual Sampling Event Report Davis Park Road TCE Site Section: 4 Revision: 0 Date: May 2006 In conclusion. the February 2006 first Annual LTRA sampling event results confirm that natural attenuation is occurring at rates according to expectations, no changing conditions have arisen that might reduce efficacy of this remedy, no toxic and/or mobile transformation products are being produced, the plume is not expanding, there is no impact downgradient, there 1s no evidence of a new release, and source area wells have attained remediation objectives. 4.3 RECOMMENDATIONS Analytical results from quarterly, semiannual, and annual sampling of the monitor well network at the Davis Park Road Site indicate decreasing levels of COCs. Perimeter wells located outside the plume continue to monitor for potential migration of plume constituents. PDBs continue to provide representative samples of the principle COCs in groundwater at the Davis Park Road Site, while at the same time being more easily implemented and cost-effective than low-flow sampling methods. It is recommended that annual sampling be continued for the duration of the LTRA. Access to monitor well MW-6 has been prevented by the owner for three consecutive sampling events. The monitoring point is within the current contaminant plume and provides information that helps characterize the plume. The current home owners did not request access to city water and were provided with a carbon filtration unit for their drinking water. It is recommended that the owners be contacted during the coming year to request their formal approval for inclusion within the LTRA sampling network. If approval is refused, monitor well MW-6 will be removed from the monitoring program. Because there are monitoring points up-and down-gradient of this well, it will not be necessary to replace this sampling point. The plume will continue to be characterized without the additional information provided by data collected from sampling of this well. 4-10 K:120064\205\First Annual\Feb06FirstAnnualRpt Irk. chgs.doc RFW205-2A-AVEI ••• :-,• . r. ., '· .. ' . :: •. ...... .. •• , ....... ' ' ' . ' ' ' ... , . _· ' ' 't • ;-···:.~. -' ' ·-•·· ·, :_ . , ·1 ··. . .. -,· •-. ' .-. ,• 9P-076J ,i·: :;: :-.. " ·.,. . ... ~ •· -'v· .. {~> ·--~ ; .:r, , ., ,· ·.'.: ·, .. ·; ... ·,\ ' •. .j' :-:. " ' ··1 .;.". :..:, ·; , .. ·._ .. ,. " '. . . ,, . · .. -. _ .... -' ':.1' .. /: .. . ·.• .. . :t-·-···;·'· -·. j . ,' ,'J.•,• ::· ,,': ..... , .• ' ' -~ ... ' ........ , . ·,-'. '~ ~ .•' .. ,._:;., ~...:: i; · \~/· .. ",-' . _,._ '• . _..,. ,._,;.__ ·, .. . ... . . '· . ,;. '' .,. i•~' ',,· • . . ,. . ' . '.,: '· • ·'t ; ' ·• ·,··. ~ ~·. ', ··-··-. ~-... ~: . . ·. ' ·; .... ' . '.!. .-,. "l "°; . ,.~'-· - \:>) ·•.:•::) ;,,:': ·t,·.:, ,· . •' . ,:, ·. ,, ... _ .. .:!. ~ ' 7-"'. ,-_·,:1, . . . . ' • ' + • ••• : ; •' ,-• -... · ,' 'J __ :: •·/·;:' /" ... -·· ..... • .. i:·1 .:; · . .;, '. . ·. , .. , .'-. .. '. ..._ ·.• ,,.. __ _ .' ,· .,, .. . ·, .. ·.r. . } . f :::. •· ·. . t ' . . ,._, f I I I I I I I I I I I I I I I I I I I This document was prepared by Weston Solutions, Inc., expressly for EPA. It shall not be disclosed, in whole or in part, without the express written permission of EPA. APPENDIX A February 2006 First Annual Sampling Event Report Davis Park Road TCE Site Section: Appendices Revision: O Date: May 2006 LOG NOTES/FIELD WATER QUALITY DATA SHEETS K:\20064\205\First AnnuallFeb06FirstAnnualRpt Irk chgs.doc RFW205-2A-AVEI v1 ..J '" v' _;, :-I ,;-r-l,J J)l ..J.' J) 0 -- p;; t-1' 1,J ('> ~· ,~- ~ I I I I I I I I I I I I I I I I I I I DAVIS PARK TCE SITE WESTON W.O. NO. 20064.205.100.0720 Date: 02/ O $: 12006 WELL EVACUATION/SAMP.LING FORM GENERAL INFORMATION Well No.: MW-1 Weather: t,, ........ 1..... ... ?)OJ; Sampling Team: Kris Spikes, Tim Royer. Samplers Signatt.ir1 k ~ . . . . ( i'--------WELL MEASUREMENTS Protective Casing: In ~t I Damaged Comments: Locked: y ;~ I NO Concrete Base: lnt~C, I_ Damaged Casing Diameter: 4in., 6;h.) WELL INFORMATION Total Depth (Top of Casing = TOC): Well Sampling Method : Depth to Water (DTW) (TOC): 3Av Passive Diffusion Bag Sampler Column of Standing Water (C=A-8): Note: Well No Longer Purged INDICATOR PARAMETERS Odor: SULFUR / PINE TAR / NAPL Observed: TAR I FOAM I --. ---:t,:,~"--~ ----------~ SAMPLE COLLECTION INFORMATION Sample ID: MW-1 CLP Number: Sample Time/Date: I'\ ao ----021bt 12006 Laboratory: Duplicate: NO Case No: Equipment (Rinsate) Blank: Yes Date Shipped: 02/ 0 1, 106 Equipment Blank Sample ID: MW-1RB Field Blank: YES Parameters: voes -EPA METHOD 8260 Field Blank Sample ID: MW-1FB --- COMMENTS ·sample MW-1FB collected near well. ·sample MW-1 RB collected through PDB. u-~< \,. 4;, ·"'.l Lu-1\ .17 .<-o.g"I , , ii I - DAVIS PARK TCE SITE WESTON W.O. NO. 20064.205.100.0720 Date: 02/ 0 8' 12005 WELL EVACUATION/SAMPLING FORM GENERAL INFORMATION Well No.: MW-2 Weather re,,,_\-(()~ .. ,l , ~ cl 'S Sampling Team: Kris Spikes, Tim Royer. Sampler's Signaturei~ WELL MEASUREMENTS Protective Casing: Intact I Damaged Comments: Locked: YES I NO Concrete Base: Intact I Damaged Casing Diameter: 4in., 6in. WELL INFORMATION Total Depth (Top of Casing = TOC): ~ell Sampling Method : Depth to Water (DTW) (TOC): ..f-,~ Passive Diffusion Bag Sampler Column of Standing Water (C=A-B): Note: Well No Longer Purged INDICATOR PARAMETERS Odor: SULFUR / PINE TAR / I NAPL Observe-0L__I AR_ I FQ~M -I ---------~ ru>t\L------------. ---~---. W\_O" SAMPLE COLLECTION INFORMATION Sample ID MW-2 CLP Number: -Sample Time/Date: ·1, ,~ ----02I O 'l° /2006 Laboratory: S6S.D Duplicate: NO Case No: -Parameters: voes -EPA METHOD 8260 Date Shipped: 02/ fl f /06 .. COMMENTS N -$'i., \~ sl,.I) I. \A.f -iL. \'2 .~0.'3:S 7 . . I I I I I I I I .- 1 I I I I I I I I I I I I I I I I .---- 1 I I I I I I I I I DAVIS PARK TCE SITE WESTON W.O. NO. 20064.205.100.0720 Date: 02/ Qj( /2006 WELL EVACUATION/SAMPLING FORM GENERAL INFORMATION Well No.: MW-3 Weather: S,"'"""' , 30, S SamplingTeam: Kris Spikes, Tim Royer. Sampler's Signatur~ ~ (~ WELL MEASUREMENTS . - Protective Casing: Intact I Damaged Comments: Locked: YES I NO Concrete Base: Intact I Damaged Casing Diameter: 4in, 6in. WELL INFORMATION Total Depth (Top of Casing= TOC): Well Sampling Method : Depth to Water (DTW) (TOC): 1 1. .73 Passive Diffusion Bag Sampler Column of Standing Water (C=A-B): Note: Well No Longer Purged INDICATOR PARAMETERS Odor: SULFUR / PINE TAR / NAPL Observed: TAR I FOAM I ----~-----·-· .. -----1\,~r\C----------~--~----~ . -v'\01\4., -· ---- SAMPLE COLLECTION INFORMATION Sample ID: MW-3 CLP Number: Sample Time/Date: 1000 ----021 vV 12006 Laboratory: Duplicate: NO Case No: Parameters: voes -EPA METHOD 8260 Date Shipped: 02/ o y /2006 COMMENTS ~,-Y~ , l ~ . S'-1. . ? b VJ-i, -\~_,\\.ii . ·---·· •-.. ---~ A; ,: DAVIS PARK TCE SITE WESTON W.O. NO. 20064.205.100.0720 Date: 02/ e'f /2006 WELL EVACUATION/SAMPLING FORM GENERAL INFORMATION Well No.: MW-4 Weather: Sampling Team: Kris Spikes, Tim Royer. Sampler's Signature: WELL MEASUREMENTS Protective Casing: Intact I Damaged Comments: Locked: YES I NO Concrete Base: Intact I Damaged Casing Diameter: 4in., 6in. WELL INFORMATION Total Depth (Top of Casing= TOG): Well Sampling Method : Depth to Water (DTW) (TOG): ;;'{ ,).,._ Passive Diffusion Bag Sampler Column of Standing Water (C=A-B): Note: Well No Longer Purged INDICATOR PARAMETERS Odor: SULFUR / PINE TAR / NAP L Observed: TAR I FOAM I ------------~------------~t,; Y\O'i'V SAMPLE COLLECTION INFORMATION Sample ID: MW-4 CLP Number: Sample Time/Date: I 150 ----02/ 0 i /2006 Laboratory: Duplicate: NO Case No: Parameters: voes -EPA METHOD 8260 Date Shipped: 02/ D S" /2006 COMMENTS \..) -°7? I\? , :>~ -~ 3 w-~l , 13., \'Z. .l.,C\. . -. , 0"-\.'4. 0<\, q_ " 011\ ~ o\\e,~ >.. 1~"o u_,.,.\, I) j ~ ,. ,. .,.. . ""1l1' ~ ' I I I I I I I I ---. I I I I I I I I I I I I I I I I I I I I I I I I I I I DAVIS PARK TCE SITE WESTON W.O. NO. 20064.205.100.0720 Date: 021 o-=t--/2006 WELL EVACUATION/SAMPLING FORM GENERAL INFORMATION Well No.: MW-5 Weather: "2,...,1\.j\--, . '-1.0 ':.'.) Sampling Team: Kris Spikes, Tim Royer Samplers SignatureK ( • (_, ' J INDICATOR PARAMETERS Time: \~5 ,-:ioi, \-:Jo1-11-0 B no'\ 11 lO 0.0. (mg/L): 8'. 2.1( 1.q~ 1.oq_ 1-2,~ 1-'Hl t. •HI ORP (mv): \'\~ ., 1'11-3 l'-1"\.7 ISl.'1 1«;2..9 \S'l.3 Temperature (DC): 11..S'i lt., .?S 11,.i,S I 1,.11, llf.1'1 (t.18 pH: ".'1S ((.lY 1,.01 l,-01 \, .() li' \, .()"\ Specific Conductivity(s): '2-0 I 'lo I 2.03 1,..0'-f ;;i.o,,, ~(. Turbidity (NTU): o .01 ---0.0\ -Odor: SULFUR / PINE TAR / NAPL Observed: TAR I FOAM I \I\J>n.f < 11'-1>"-~ SAMPLE COLLECTION INFORMATION Sample ID: MW-5 CLP Number: Sample Time/Date: \7\S ---02/ flJ'l-/2006 Laboratory: Duplicate: NO Case No: . .. .. Parameters: voes· -EPA METHOD 8260 Date Shipped: 02/ 06 /2006 COMMENTS }J -.._,-5 , l'>i s--< ·'!,l1 W-l>I. 17> .OS. !\I WELL EVACUATION/SAMPLING FORM GENERAL INFORMATION ;, Well No.: MW-6 Weather: / Sampling Team: Kro~es,.Tim Royer ----·-Sampler:s Signature:-.. -------·----. / "' INDICATOR P~RAMETERS Time: "--/ D.0. (mg/L): " / / ORP (mv): V Temperature (DC): / "-pH: / " Specific Conductivity(s): / "-Turbidity (NTU): / "--Odor: SUL~ PINE TAR / NAPl>.~erved: TAR I FOAM I SAMPLE COLLECTION INFORMA11~ Sample ID: MW-6 CLP Number: Sample Time/Date: ----02/ /2006 Laboratory: Duplicate: NO Case No: Parameters: VOCs -EPA METHOD 8260 Dale Shipped: 02/ /2006 COMMENTS n.t.~ --· "I.,,\ bu)"'••< 1, l l\ttl. A.~.,_~ d,t< . .. DAVIS PARK TCE SITE WESTON W.O. NO. 20064.205.100.0720 Date: 02/ o "'r /2006 WELL EVACUATION/SAMPLING FORM GENERAL INFORMATION Well No.: MW-7 Weather: '> IA.V\.l'\."'I 'SO'$ Sampling Team·. Kris Spikes, Tim Royer Samplers Signature: u < ~ • INDICATOR PARAMETERS Time: LS? n 15~\ \ s '2, '2.. \'5;t3 l'-:l&l I< :i.< ''\') t. D.O. (mg/L): lt-11 1-'H, 1-'l-< ir;. z_\ l! . '" 1.1'i( '&·Oft ORP (mv): x1 .J 115. \, I "l-,,. .'l. \2 t.1 131. ( I '<3 . 5 I'< 1. o Temperature (DC): 1'{$2. \'\. "15 1'5. 0 e, ~-llt IS ."2..1• 15 .b'j ~'5 :ti pH: l,. ID '5-1>1 S."tz.. .., .'60 ,S.1'\ ~-15 S .,1 Specific Conductivity(s): \~1 151 I '5?; IS "I I '5 "I \ s "I 1st Turbidity (NTU): &-3 0 --o:1 ,. --o.e\ Odor: SULFUR / PINE TAR / NAPL Observed: TAR I FOAM I \\.o<I.(.., lo\.O<\& SAMPLE COLLECTION INFORMATION Sample ID: MW-7 CLP Number: Sample Time/Date: \S"3o ----02/ 6":r/2006 Laborato,y: Duplicate: NO Case No: ---------. -. Parameters: V0Cs -EPA METHOD 8260 Date Shipped: 02/ e ~ /2006 COMMENTS \,J -~s ,1~.2."l-1 io 'N -~l,l'L S'\-1."I WELL EVACUATION/SAMPLING FORM GENERAL INFORMATION Well No.: MW-8 Weather: s,.._...,_,_..,. . Sb::, Sampling_Team: Kris.Spikes,.Tim Royer-------Samplers Sign~e:-~------ INDICATOR PARAMETERS '-./ Time: \ ~ ~o \1,)\ ttt;;i_ 11, "'!, '1 \~~5 \l,'} l< \lc37 \\t~<l --- D.O. (mg/L): q_q7 o, 'IS °I.<\ I i.'\i \O. l'l-LO .08' LO.CN \O.o(, . ORP (mv): S~-1 \, I • .:Z. I,,., 1'1-'i 'ro .(. 8S .'1 't"l-'1 "l'<·l Temperature (DC): l~.\;i_ 1"\, '\'i l't~1 ii/, 113 1~.io ,'{. "I 1, \'-\."l"I 15.o'l. pH: Lt -~i l,.'{3 l,,'l'I u.'IS l.·"I.~ L, . '( "I '-< ,5"!> 1.,.s3 Specific Conductivity(s): \05 \ t,'{ \O'i IAU \0$ lo'1 lo\( \ 0'1 Turbidity (NTU): 3.1,1 --o.o \ --0,0 \ o." I Odor: SULFUR / PINE TAR / NAPL Observed: TAR I FOAM I 11,c,'1,e "'-""'-e.- SAMPLE COLLECTION INFORMATION Sample ID: MW-8 CLP Number: Sample Time/Date: \ lt "i O ----02/O=l-/2006 Laborato,y: . Duplicate: NO Case No: Parameters: voes -EPA METHOD 8260 Date Shipped: 02/ O'i( /2006 COMMENTS \.\-~s ,~ .5.J..2..'t w-T I , l'3. \l· lS I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I DAVIS PARK TCE SITE WESTON W.O. NO. 20064.205.100.0720 Date: 02/ t> 1 /2006 WELL EVACUATION/SAMPLING FORM GENERAL INFORMATION Well No.: MW-9 -~.1,;~ '\ s~.:~\~1¥.-~-Weather: "1'::,u. "-"" • S C •.:;. Sampling Team: Kris Spikes, Tim Royer Samplers Signature: L ~ INDICATOR PARAMETERS Time: I:>:,'\ 1~'\0 \"!.~I \ "?,'\ 1.. l~'\'1 1i~l, \~'t'l\' D.0. (mg/L): 1-l.5 1.'\ D 1.t.t t-n s.s 1 1-'1."\ i:i 'i ORP (mv): \ ~'\.c; I I\ I.'\ \'\'\_ '2. l'\'\:1 l'\1.-1 \'1S-I \'11, .I, Temperature (DC)·. ,s.11 ,ss"\ ,s.-t'?> 1<;.'\"2 \,;; . '"61. 1,;.1 l 1':,.10 pH: 1.-i \ le .'-\0. I, -'\I> I.,.?, 1 1,:~,z ":3,s "-"lS Specific Conductivity(s): r1~ n~ \11 \11 1\71. .n1 n1 Turbidity (NTU): o.e\ o.ol ------o .o I Odor: SULFUR / PINE TAR / NAPL Observed:. TAR I FOAM I ~e_ 'ru, "'~ SAMPLE COLLECTION INFORMATION Sample ID: MW-9 CLP Number: Sample Time/Date: 1½0 ----02/ 01 /2006 Laboratory: Duplicate: NO Case No: -Parameters: VOCs -EPA METHOD 8260 Date Shipped: 02/ /2006 COMMENTS \.l -3S. \:, .'-\'\. I!\ t> lt.J -¥1 , r~ \) °' . "l.\ WELL EVACUATION/SAMPLING FORM 02-0 'i( GENERAL INFORMATION Well No.: MW-10 Weather: 1...J-t I __ • J , 1.\0 !5 Sampling Team: Kris Spikes, Tim Royer. Samplers Signature: l:(, ~ INDICATOR PARAMETERS Time: 1; a<, \';o~ l3o1 \ 1. 0 'I( l1AA (\lh 0.0. (mg/L): '6.10 'l.'{1 V.to li, '2-( t ... ;I. "l. I C ORP (mv): 1'-\I, .1 ('{\-0 I '{f. '6 1-<l-'1 1'12--S 1 '{z., '{ Temperature (DC): 1S:-t9 11,.0'\ '"·'" (I. 1£> II •. I "I 11, . 1.2. pH: i.01 1-'{ l{ 1. \ '4 ".'\5 r. iS I •• 1 l! Specific Conductivity(s): 117 11'6 l1t, 11 I, 11 (, 11 (, Turbidity (NTU): o .e I i,. o I o . ., \ o.o \ 0, O \ o.o I Odor: SULFUR / PINE TAR / NAPL Observed: TAR I FOAM I V\,oN,, l\o'\.(... SAMPLE COLLECTION INFORMATION Sample ID: MW-10 CLP Number: -Sample Time/Date: \ ~ \C, ----02/ 0 'i( /2006 Laboratory: S\'.'.:St> Duplicate: NO Case No: ' Parameters: voes -EPA METHOD 8260 Date Shipped: 02/ O '& /2006 CO_MMENTS N -1~ 1'?> .'1S.'\\ \l',J -il,Ll.2-1-\-I, DAVIS PARK TCE SITE WESTON W.O. NO. 20064.205.100.0720 02--ot, Date: ~/ 0 l-/2004' WELL EVACUATION/SAMPLING FORM GENERAL INFORMATION Well No.: MW-11 2-"Z> o v ~:cv,. c~ \>\. Weather: ':, """"'-'ll . so • 5 Sampling Team: Kris Spikes, Tim Royer Samplers Signature: K ~ INDICATOR PARAMETERS Time: •~ l t. \:, I 3 la\'.\ l?,l!, \'31 l, 1'-l1 0.0. (mg/L): '\.'31 ~-<; l, '\.O\ \ '\ .'\c.; '\,'\I .. '\.1 <s ORP (mv): 10'\.'\ ns.-i ,U .'\ l'l'S .I. 1-u, _3 1'2i.C, Temperature (DC): l'> .&'i ll... t> \ \(, • t) "I \ l,. IY.'l \I, .l7. l 1.. oo pH: ~. i '\ 1.1~ 1.t t> 1,,8:0 (c:1 \ (,. (, 1-Specific Conductivity(s): t<15 \?, i \3\ \'1,3 l?,7.-\)1, Turbidity (NTU): ;..'('.l,'{ '.l...OS 1-51 0. '2.1.. o.s, -Odor: SULFUR / PINE TAR / NAPL Observed: TAR I FOAM I ic,.g "-e,.. """t_. SAMPLE COLLECTION INFORMATION · Sample ID: MW-11 CLP Number: Sample Time/Date: -t 7> '2,o ----02/ O ':f-/2006 Laboratory: Dupr,cate: NO Case No: ---Paiameters:VOCs.:. EPA METHOD 8260 Date Shipped: 02/ /2006 COMMENTS "3-?.S ,\~ .'l~ ."\ \ "'1-~\' \~ \S. ti,, WELL EVACUATION/SAMPLING FORM GENERAL INFORMATION Well No.: MW-16 Weather: ~"'-V\k-.. <c-() ..._ Sampling Team: Kris Spikes,_Tim Royer .. -Samplers Signature: K~ INDICATOR PARAMETERS Time: i l, O"'-l It o-:i-I lt0'/5 \l,O'\ \Lt\() I 1, I l 0.0. (mg/L) s.S4 1. ~\/ ll-lS S.(,'f 1.:J..<., l, ,OJ ORP (mv): . ~I( .I, 3'i-1 >?.S ;,'2.-3 ?,o.9; ';;,.3 Temperature (DC): ,r...\ s , le-~ I, tl,,l.{'3 11,.So )l...Sl/ \ & .c:; 3 pH: Ct .1.'\ l, . .).1 u.:i.Y (,.\Y v.l~ l,.(I, Specific Conductivrry(s): \YT l~1 I )i ,~, l't tl ,~o Turbidity (NTU): J.a\." --\(,'\.i -,so.c; Odor: SULFUR / PINE TAR / NAPL Observed: TAR I FOAM I V\.o<\e., l'\.o!!.e, SAMPLE COLLECTION INFORMATION Sample ID: MW-16 CLP Number: Sample Time/Date: \ IL\ S ··--02/ 0'1-/2006 Laboratory: Duplicate: NO Case No: Parameters: voes -EPA METHOD 8260 Date Shipped: 02/ <>)t /2006 COMMENTS ts.\-:,S 1-::i. ~,. '&D \N-'in .13.0'2--.. n I I I I I I I I ----• I I I I I I I I I I I I I I I I I I I I I I I I I I I I DAVIS PARK TCE SITE WESTON W.O. NO. 20064205 100.0720 Date: 02/ El [ /2006 WELL EVACUATION/SAMPLING FORM GENERAL INFORMATION Well No.: MW-12 Weather: 'PAlt~ cr_c.J...._ 11 ~ '.5 Sampling Team: Kris Spikes, Tim Royer. Sampler's Signature: ' I(._ _S ,.:_ WELL MEASUREMENTS Protective Casing: Intact I Damaged Comments: Locked: YES I NO Concrete Base: Intact I Damaged Casing Diameter: 4in., 6in. WELL INFORMATION Total Depth (Top of Casing= TOC): Well Sampling Method : Depth to Water (DTW) (TOC): l'?i ."10 Passive Diffusion Bag Sampler Column of Standing Water (C=A-B): Note: Well No Longer Purged INDICATOR PARAMETERS Odor: SULFUR / PINE TAR / NAPL Observed: TAR I FQ_AM_ !_ ~ ----------------·--"" &..<:..-----------M '\ ,c ~ - SAMPLE COLLECTION INFORMATION Sample ID: MW-12 CLP Number: -Sample Time/Date: I'{ C 0 ----021 0 l) /2006 .Laboratory: '5'6S.D Duplicate: NO Case No: Parameters: voes -EPA METHOD 8260 Date Shipped: 02/ CJ l /2006 COMMENTS "1,,5 '\:,. '{'1'. .$, vJ-}(\.17 _ c. In . 7 :;t_ --·- ' -- DAVIS PARK TCE SITE WESTON W.O. NO. 20064.205.100.0720 Date: 02/ O( /2006 WELL EVACUATION/SAMPLING FORM GENERAL INFORMATION Well No.: MW-15 Weather: ~--;o :5. Sampling Team: Kris Spikes, Tim Royer. Samplers Signature, f) . , WELL MEASUREMENTS Protective Casing: ln~t I Damaged Comments: Locked: YES I NO Concrete Base: Intact I Damaged Casing Diameter: 4in., 6in. WELL INFORMATION Total Depth (Top of Casing= TOC): Well Sampling Method : Depth to Water (DTW) (TOC): '(_qg' Passive Diffusion Bag Sampler Column of Standing Water (C=A-B): Note: Well No Longer Purged INDICATOR PARAMETERS Odor. SULFUR / PINE TAR / NAPL Observed: TAR I ~OAM I ---- - --"-'> W\LI -. ---~-----. . ---,!\-~~-£ SAMPLE COLLECTION INFORMATION Sample ID: MW-15 CLP Number: Sample Time/Date: 0 '\ LO ----021 o<t 12006 Laboratory: Duplicate: YES-MW-15D Case No: Parameters: voes -EPA METHOD 8260 Date Shipped: 02/ /2006 COMMENTS **DUPLICATE SAMPLE COLLECTED** ' --... - "-l -"'!>S. r~. 47-"3S \.,.I-~\ • \.6 . C:5". la 3 - ¼o.l.c.·.b.,.-:, ,,...,.\~ '-~L-;j.\l,;ivV-:,-~"l)O. \e~=• . ,\_,_ -n" ,{ _f __ .• , . "' 0 0 . . ~ V - I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I DAVIS PARK TCE SITE WESTON W.O. NO. 20064.205.100.0720 Date: 02/ O'T /2006 WELL EVACUATION/SAMPLING FORM GENERAL INFORMATION Well No.: MW-17 Weather: 'Su""-71 , <,O '5 Sampling Team: Kris Spikes, Tim Royer Sampler's Signature: K (.5--.:_____ INDICATOR PARAMETERS Time: I ,lo f /fO <. 14-ol lfoi i 4-10 I 4 II /,{/"J., D.O. (mg/L): ';. 7o Y.o5 <y.2-I 9. I!) 'ii. Z 1 117 9. I C. ORP (mv): ,~<;.7 '4Z.1 14/o.; ,~.z. l•HJ' /,l<,. l Jr •. 1 Temperature (DC): 11 31 14,DI 1.d. At 14.< I 4 .c,41 I 4. I. 14.C,~ pH: l _<;q ( •. 4 / r •. 1..L l. . z. "I (. ,s (. °?>4 e,_?,~ Specific Conductivity(s): I" I/ 1, 1/ i) II?, II J., 1/ 2-1/2. Turbidity (NTU): -0.40 ----fl 7_ 4--Odor: SULFUR / PINE TAR / NAPL Observed: TAR I FOAM I SAMPLE COLLECTION INFORMATION Sample ID: MW-17 CLP Number: Sample Time/Date: / 41 " ----02/ 0::/-/2006 Laboratory: Duplicate: NO Case No: . ----. Parameters:VOCs -EPA METHOD 8260 Date Shipped: 02/ O lf /2006 COMMENTS N --:>., ':, I-.... ""::I. I, . lS 'K ~-'81.\2. 'Sl, .S'\ 1:1 ...... " \" <"o..-.,"t\, WELL EVACUATION/SAMPLING FORM GENERAL INFORMATION Well No.: MW-18 Weather: s ....... V\.,, . so •;::. Sampling Te_a_n1:_~is Spikes, .Tim Royer .. ---.. ---. Sampler's Sig,~: ( -~ '- INDICATOR PARAMETERS Time: \'{ i" l * 'to i-t 1.1. I l'\ * .::t \'\'1.~ l'\"\S \'{ '{ i 1'4 'i '\ D.O. (mg/L): l,." t. .lf L, ".o\ -..11'( ~.c;;i. ~.3'( 'f,."?, l,. \ 1 ORP (mv): '\\, .'\ t. I\ .'-\ Ito. I ,;,i ."\ (,1 .(. I("> .2, 1,1 .'\ I, I, ·O Temperature (DC): '\. J.Y 11 -it~ l1-l1 l'l l'{ \'\ .i, \'I . o-1 1'\'. o-1 ~Lf o7 pH: I..!) 1 l,. . \ 0 l,.10 l,,\!) l, ,02. 1,.os (., .01 t. .o'il Specific Conductivity(s): \!; \ lSO ISO I SQ \ '\ "\ \"\ 'i( I"\ i I '-11 Turbidity (NTU): "7 \~ ~\l ~ I-\. Vo ,._,\; ,,. ---Odor: SULFUR / PINE TAR / NAPL Observed: TAR I FOAM I l\b-<\.~ "'-OV\ e.,. SAMPLE COLLECTION INFORMATION Sample ID: MW-18 CLP Number: Sample Time/Date: \ "\ '5 O ----02/ e, -:J-12006 Laboratory: Duplicate: NO Case No: Parameters: VOCs -EPA METHOD 8260 Date Shipped: 02/ o t /2006 COMMENTS "1-~<;. \3 .31-'1" \IJ-ti .ll..Si .?..3 DAVIS PARK TCE SITE WESTON W.O. NO. 20064.205.100.0720 Date: 02/ g 1 /2006 WELL EVACUATION/SAMPLING FORM GENERAL INFORMATION Well No.: MW-19 Weather: , 'I."""' , <; O • s Sampling Team: Kris Spikes, Tim Royer. Sampler's SignatuYe: IC; . ' __....---WECL MEASUREMENTS Protective Casing: Intact ...J----Damaged Comments: Locked: __....---YES I NO ConcretEl,.Base: Intact I Damaged CjlS!fig Diameter: 4in., 6in. WELL INFORMATION __. Total Depth (Top of Casing= TOG): __,,----- Depth to Water (DTW) (TOG~ Well Sampling Me~ Passive Di!fusion Bag Sampler A IL-'P I I I I I I I I Column of Standing Vy:;iter (C=A-B): ~ I I I Note: Well No I_J)nger Purged . / INDICATOR PARAMETERS oy.suLFUR / PINE TAR / NAPL Observed: TAR I FOAM I --· SAMPLE COLLECTION INFORMATION Sample ID: MW-19 CLP Number: Sample Time/Date: L °555 ----02/ f>-=f /2006 Laboratory: Duplicate: NO Case No: Parameters: voes -EPA METHOD 8260 Date Shipped: 02/ () 7'i2006 COMMENTS W-35. 1:,. 3•-3"1 'W-'&-l 12-.5 Z · °b:1 ·- ''""-e... l1<a'il i S-13 1'5~~ \$~\ l'.,1/ I, 15'(1 1'5'1 S lS ISE;O 1)Cl q.'{3 f.1.,2, '&,3 8 t. '(;>. i.~3 i.11,, i. \3 o..-i"I '& ,ii "I oR\> I'll, ,7 l"I:> l'f I .:;l,, ----l'{o ,I, 13'\ ·" ro.1, 1'1~. S' l'-11. 0 I '11 • I Ii.NY'{) .~ .20 1'!,.'\S \~. "\~ ,~."11 11. i lt --1'-1-'\'l l'-1. 'ID 11.(, ?,7 l'f . &-s t,.3.Z.. l, .3 "I t.->1 ---··--. p~ It. '1.l. '.l{J. I.,.'{~ l, • '{ '1 ---- -~:_'<'1 t,.t{S c .. ,~ 1'13 \'i3 N'-I -·----l 'I 'f \'i'f I "I'-{ .. -I 'I'{ l'1'1 I '1.'1 .,_ '(I, ------o.o I . ----· ---·---~~-,~ ----0 •O \ O,o I - l I ---.- ,ss I ~-20 t '{ 1., \'1. 8tl "·'<S \'{ '1 1> -o I 1 I I I I I I I I I I I I I I I I I I I I I I I I I I I DAVIS PARK TCE SITE WESTON W.O. NO. 20064.205.100.0720 Date: 02/ O?:' /2006 WELL EVACUATION/SAMPLING FORM GENERAL INFORMATION Well No.: MW-20 Weather: Su__.-~ u ",Q ':s, Sampling Team: Kris Spikes, Tim Royer. Sampler's Sign~-~ WELL MEASUREMENTS Protective Casing: it I Damaged Comments: Locked: I NO ' Concrete Base: lrilact I Damaged Casing Diameter: 4in, 6in. WELL INFORMATION Total Depth (Top of Casing= TOG): Well Sampling Method : Depth to Water (DTW) (TOG): '}A .13 Passive Diffusion Bag Sampler Column of Standing Water (C=A-B): Note: Well No Longer Purged INDICATOR PARAMETERS Odor: SULFUR / PINE TAR / NAPL Observed: TAR I FOAM I --· -----· --------· -------- SAMPLE COLLECTION INFORMATION Sample ID: MW-20 CLP Number: Sample Time/Date: I\ o o ----02/ 0 f'/2006 Laboratory: Duplicate: NO Case No: Parameters: voes -EPA METHOD 8260 Date Shipped: 02/Oo/2006 COMMENTS N-~S.1-=>;, So. %'K , .. i-'1;'.\ L~ .10 .. 'L!-L . . . .. --- - -. , , . DAVIS PARK TCE SITE WESTON W.O. NO. 20064.205.100.0720 Date: 02/ r:,f /2006 WELL EVACUATION/SAMPLING FORM . GENERAL INFORMATION Well No.: MW-21 Weather: S""'"~ ~o·s Sampling Team: Kris Spikes, Tim Royer. Sampler's Sign,:: • \ ' • -, \ WELL MEASUREMENTS Protective Casing: Intact I Damaged Comments: Locked: YES I NO Concrete Base: Intact I Damaged Casing Diameter: 4in., 6in. WELL INFORMATION Total Depth (Top of Casing = TOC): Well Sampling Method : Depth to Water (DTW) (TOC): I 3 .1 'f Passive Diffusion Bag Sampler Column of Standing Water (C=A-8): Note: Well No Longer Purged INDICATOR PARAMETERS Odor: SULFUR i PINETAR / NAPL Observed: TAR I FOAM I SAMPLE COLLECTION INFORMATION Sample ID: MW-21 CLP Number: Sample Time/Date: l l 1) o .... 02/ l!l ~/2006 Laboratory: Duplicate: NO Case No: Parameters: voes -EPA METHOD 8260 Date Shipped: 02/ O't /2006 COMMENTS .. -------. . ~-~.'i (; ,'l,!.\.,lt1 \v , il , I 7i ll.'l1-. . . ' . ~o~ ·. o.,_\..,_ 'l. \fbt\s J..\\,& • •. \'i)"B \eo-.\,·,-• v>liuM. -., o • i eui · c,\ -, -~ ~ " . . . .. -. I I I I I I I I I I I I I I I I I I .,:-t·. ,I. ·?:·,.: ,:,·, ... ~·-: u .. , ·•1 .. • • < •,,;., ._·., :,•· . . , .. ·.(,'-/:<·i:'::~;1;;.;;:.::; . :•.·,'·, .:,_._•·,/' ~ \·:' .,~ '' ··:--,•:'r, ,· ,.. . •, '-: -~; ·. ;:~,'/~,; , ,_.,.._ ,· •· '.f/ }.·:.~ ... ;.. •.' ·_-. .., .. ,. . ,,, . ' . . . '~ .·, . .: ., . ._:' i .. ·,, \-~ : ; · .. \:\· ·.: ,· , . .,-~ 1, ~· .~ ·::·(:)-}<·.~ .... ·: ....... .-. ,✓1 ' ·,, ·~: , .•• :! ;, .. .', • -1~. ~ . .:.>~.-... ~\ .. j.'1, •. ., :,t ·.)· r'j_.-._ ''.'·t.; \ ', . . . . . . ·~ . •'-': ·, '• ?, ;,., •,_. ·•. \J :• I I I I I I I I I I I I I I I I I I This document was prepared by Weston Solutions, lnc., expressly for EPA. It shall not be disclosed, in whole or in part, without the express written permission of EPA. APPENDIXB February 2006 First Annual Sampling Event Report Davis Park Road TCE Site Section: Appendices Revision: 0 Date: May 2006 LABORATORY ANALYTICAL REPORTS K:\200641205\First Annual\Feb06FirstAnnualApt trk chgs.doc RFW205-2A-AVEI -Sample 3149 FY 2006 Project: 06-0266 Volatiles Scan Facility: Davis Park Rd Program: SF Gastonia, NC Id/Station: MW01 / Media: GROUNDWATER RESULTS UNITS ANALYTE 0.50 U UG/L Dichlorodifluoromethane 0.50 U UG/L Chloromethane 0.50 U UG/L 1, 1,2-Trichloro-1,2,2-Trifluoroethane (Freon 113) . 0.50 U UG/L Methyl T-Butyl Ether (MTBE) 0.50 U UG/L Bromomethane 0.50 UG/L Cyclohexane 0.50 U UG/L Vinyl Chloride 0.50 U UG/L Chloroethane 0.50 U UG/L Trichlorofluoromethane (Freon 11) 0.50 U UG/L 1, 1-Dichloroethene (1, 1-Dichloroethylene) 0.50 U UG/L Methylene Chloride 2.0 U UG/L Acetone 0.50 U UG/L Carbon Disulfide 1.0 U UG/L Methyl Acetate 0.50 U UG/L 1, 1-Dichloroethane 0.50 U UG/L cis-1,2-Dichloroethene 0.50 U UG/L 2,2-Dichloropropane 2.0 U UG/L Methyl Ethyl Ketone 0.50 U UG/L Bromochloromethane 0.50 U UG/L trans-1,2-Dichloroethene 0.50 U UG/L Chloroform 0.50 U UG/L 1,2-Dichloroethane 0.50 U UG/L 1, 1, 1-T richloroethane 0.50 U UG/L 1, 1-Dichloropropene 0.50 U UG/L Carbon Tetrachloride 0.50 U UG/L Bromodichloromethane 2.0 U UG/L Methyl lsobutyl Ketone 0.50 U UG/L 1,2-Dichloropropane 0.50 U UGIL Methylcyclohexane 0.50 U UG/L Dibromomethane 0.50 U UG/L trans-1,3-Dichloropropene 0.50 U UG/L Trichloroethene (Trichloroethylene) 0.50 U UGIL Benzene 0.50 U · UGIL Dibromochloromethane 0.50 U UGIL 1, 1,2-Trichloroethane Sample Received Unpreserved; Holdin~ Time & all other Criteria Met! RESULTS 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 2.0 U 0.50 U 0.50 U 0.50 U 0.50 U 1.0 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U -Produced by: Hale, Sallie Requester: Project Leader: JWENDEL Beginning: 02/08/2006 09:00 Ending: UNITS ANALYTE UG/L cis-1,3-Dichloropropene UG/L Bromoform UG/L Bromobenzene UG/L 1, 1,2,2-Tetrachloroethane UG/L Tetrachloroethene (Tetrachloroethylene) UG/L 1,3-Dichloropropane UG/L Methyl Butyl Ketone UG/L Toluene UG/L Chlorobenzene UG/L 1, 1, 1,2-Tetrachloroethane UG/L Ethyl Benzene UG/L (m-and/or p-)Xylene UG/L a-Xylene UG/L Styrene UG/L 1,2,3-Trichloropropane UG/L o-Chlorotoluene UG/L p-Chlorotoluene UG/L 1,3-Dichlorobenzene UG/L 1,4-Dichlorobenzene UG/L 1,2-Dichlorobenzene UG/L 1,2-Dibromoethane (EDB) UG/L lsopropylbenzene UG/L n-Propylbenzene UG/L 1,3,5-Trimethylbenzene UGIL tert-Butylbenzene UG/L 1,2,4-Trimethylbenzene UG/L sec-Butylbenzene UGIL p-lsopropyltoluene UG/L n-Butylbenzene UG/L 1,2-Dibromo-3-Chloropropane (DBCP) UG/L 1,2,4-Trichlorobenzene UG/L Hexachloro-i ,3-Butadiene UGIL 1,2,3-Trichlorobenzene U-Analyte not detected at or above reporting limit. I J-ldentification of analyte is acceptable; reported value is an estimate. I UJ-Analyte not detected at or above reporting limit. Reporting limit is an estimate. N-Presumptive evidence analyte is present; analyte reported as tentative identification. I NJ-Presumptive evidence analyte is present; analyte reported as tentative identification. Reported value is an estimate. K-ldentification of anafyte is acceptable; reported value may be biased high. Actual value expected to be less than the reported value. L-ldentification of analyte is acceptable; reported value may be biased low. Actual value expected to be greater than reported value. NA-Not Analyzed. I NAI-Not Analyzed due to Interferences. I A-Analyte analyzed in replicate. Reported value is ·average" of replicates. A-Presence or absence of analyte can not be determined from data due to severe quality control problems. Data are rejected and considered unusable. Page 1 of 1 VOLATILES SAMPLE ANALYSIS EPA -REGION IV SESD, ATHENS, GA Production Date: 03/24/2006 16:14 Sample 3150 FY 2006 Project: 06-0266 Volatiles Scan Facility: Davis Park Rd Program: SF Gastonia, NC Id/Station: MW02 / Media: GROUNDWATER RESULTS UNITS ANALYTE 0.50 U UG/L Dichlorodifluoromethane 0.50 U UG/L Chloromethane 0.50 U UG/L 1, f,2-Trichloro-1,2,2-Trifluoroethane (Freon 113) 0.50 U UG/L Methyl T-Butyl Ether (MTBE) 0.50 U ·uG/L Bromomethane 0.73 UG/L Cyclohexane 0.50 U UG/L Vinyl Chloride 0.50 U UG/L Chloroethane 0.50 U UG/L Trichlorofluoromethane (Freon 11) 0.50 U UG/L 1, 1-Dichloroethene (1, 1-Dichloroethylene) 0.50 U UG/L Methylene Chloride 2.0 U UG/L Acetone 0.50 U UG/L Carbon Disulfide 1.0 U UG/L Methyl Acetate 0.50 U UG/L 1, 1-Dichloroethane 0.50 U UG/L cis-1,2-Dichloroethene 0.50 U UG/L 2,2-Dichloropropane 2.0 U UG/L Methyl Ethyl Ketone 0.50 U UG/L Bromochloromethane 0.50 U UG/L trans-1,2-Dichloroethene 0.50 U UG/L Chloroform 0.50 U UG/L 1,2-Dichloroethane 0.50 U UG/L 1, 1, 1-Trichloroethane 0.50 U UG/L 1, 1-Dichloropropene 0.50 U UG/L Carbon Tetrachloride 0.50 U UG/L Bromodichloromethane 2.0 U UG/L Methyl lsobutyl Ketone 0.50 U UG/L 1,2-Dichloropropane 0.50 U UG/L Methylcyclohexane 0.50 U UG/L Oibromomethane 0.50 U UG/L trans-1,3-Dichloropropene 2.9 UG/L Trichloroethene (Trichloroethylene) 0.50 U UG/L Benzene 0.50 U UG/L Dibromochloromethane 0.50 U UG/L 1 , 1 ,2-Trichloroethane Sample Received Unpreserved; Holding Time & all other Criteria Met! RESULTS 0.50 U 0.50 U 0.50 U 0.50 U 2.6 0.50 U 2.0 U 0.50 U 0.50 U 0.50 U 0.50 U 1.0 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U Produced by: Hale, Sallie Requestor: Project Leader: JWENDEL Beginning: 02/08/2006 13:35 Ending: UNITS ANALYTE UG/L cis-1,3-Dichloropropene UG/L Bromoform UG/L Bromobenzene UG/L 1, 1,2,2-T etrachloroethane UG/L T etrachloroethene (T etrachloroethylene) UG/L 1,3-Dichloropropane UG/L Methyl Butyl Ketone UG/L Toluene UG/L Chlorobenzene UG/L 1, 1, 1,2-Tetrachloroethane UG/L Ethyl Benzene UG/L (m-and/or p-)Xylene UG/L a-Xylene UG/L Styrene UG/L 1,2,3-Trichloropropane UG/L o-Chlorotoluene UG/L p-Chlorotoluene UG/L 1·,3-Dichlorobenzene UG/L 1,4-Dichlorobenzene UG/L 1,2-Dichlorobenzene UG/L 1,2-Dibromoethane (EDB) UG/L lsopropylbenzene UG/L n-Propylbenzene UG/L 1,3,5-Trimethylbenzene UG/L tert-Butylbenzene UG/L 1,2,4-Trimethylbenzene UG/L sec-Butylbenzene UG/L p-lsopropyltoluene UG/L n-Butylbenzene UG/L 1,2-Dibromo-3-Chloropropane (DBCP) UG/L 1,2,4-Trichlorobenzene UG/L Hexachloro-1,3-Butadiene UG/L 1,2,3-Trichlorobenzene U-Analyte not detected at or above reporting limit. I J-ldentification of analyte is acceptable; reported value is an estimate. I UJ-Analyte not detected at or above reporting limit. Reporting limit is an estimate. N-Presumptive evidence analyte is present; analyte reported_ as tentative identification. I NJ·Presumptive evidence analyte is present; analyte reported as tentative identification. Reported value is an estimate. K·ldentification of analyte is acceptable; reported value may be biased high. Actual value expected to be less than the reported value. L·ldentification of analyte is acceptable; reported value may be biased low. Actual value expected to be greater than reported value. NA·Not Analyzed. I NAl·Not Analyzed due to Interferences. I A·Analyte analyzed in replicate. Reported value is "average· of replicates. R·Presence or absence of analyte can not be determined from data due to severe quality control problems. Data are rejected and considered unusable. - - - -- - - - - -- - ----Page 1 of 1 - -- --E~EGI..., S~AThlll, G ... -Sample 3151 FY 2006 Project: 06-0266 Volatiles Scan Facility: Davis Park Rd Program: SF Gastonia, NC Id/Station: MW03 / Media: GROUNDW.ATER RESULTS UNITS ANALYTE 0.50 U UG/L Dichlorodifluoromethane 0.50 U UG/L Chloromethane 0.50 U UG/L 1, 1,2-Trichloro-1,2,2-Trifluoroethane (Freon 113) 17 UG/L Methyl T-Butyl Ether (MTBE) 0.50 U UG/L Bromomethane 0.50 U UG/L Cyclohexane 0.50 U UG/L Vinyl Chloride 0.50 U UG/L Chloroethane 0.50 U UG/L Trichlorofluoromethane (Freon 11) 0.50 U UG/L 1, 1-Dichloroethene (1, 1-Dichloroethylene) 0.50 U UG/L Methylene Chloride 2.0 U UG/L Acetone 0.50 U UG/L Carbon Disulfide 1.0 U UG/L Methyl Acetate 0.50 U UG/L 1, 1-Dichloroethane 0.50 U UG/L cis-1,2-Dichloroethene 0.50 U UG/L 2,2-Dichloropropane 2.0 U UG/L Methyl Ethyl Ketone 0.50 U UG/L Bromochloromethane 0.50 U UG/L trans-1,2-Dichloroethene 0.50 U UG/L Chloroform 0.50 U UG/L 1,2-Dichloroethane 0.50 U UG/L 1, 1, 1-Trichloroethane 0.50 U UG/L 1, 1-Dichloropropene 0.50 U UG/L Carbon Tetrachloride 0.50 U UG/L Bromodichloromethane 2.0 U UG/L Methyl lsobutyl Ketone 0.50 U UG/L 1,2-Dichloropropane 0.50 U UG/L Methylcyclohexane 0.50 U UG/L Dibromomethane 0.50 U UG/L trans-1,3-Dichloropropene 0.50 U UG/L Trichloroethene (Trichloroethylene) 0.50 U UG/L Benzene 0.50 U UG/L Dibromochloromethane 0.50 U UG/L 1, 1,2-Trichloroethane Sample Received Unpreserved; Holding Time & all other Criteria Met! RESULTS 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 2.0 U 0.50 U 0.50 U 0.50 U 0.50 U 1.0 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0:50 U 0.50 U Produced by: Hale, Sallie Requester: Project Leader: JWENDEL Beginning: 02/08/2006 10:00 Ending: UNITS ANALYTE UG/L cis-1,3-Dichloropropene UG/L Bromoform UG/L Bromobenzene UG/L 1, 1,2,2-Tetrachloroethane UG/L T etrachloroethene (T etrachloroethylene) UG/L 1,3-Dichloropropane UG/L Methyl Butyl Ketone UG/L Toluene UG/L Chlorobenzene UG/L 1, 1, 1,2-Tetrachloroethane UG/L Ethyl Benzene UG/L (m-and/or p-)Xylene UG/L o-Xylene UG/L Styrene UG/L 1,2,3-Trichloropropane UG/L o-Chlorotoluene UG/L p-Chlorotoluene UG/L 1,3-Dichlorobenzene UG/L 1,4-Dichlorobenzene UG/L 1,2-Dichlorobenzene UG/L 1,2-Dibromoethane (EDS) UG/L lsopropylbenzene UG/L n-Propylbenzene UG/L 1,3,5-Trimethylbenzene UG/L tert-Butylbenzene UG/L 1,2,4-Trimethylbenzene UG/L sec-Butyl benzene UG/L p-lsopropyltoluene UG/L n-Butylbenzene UG/L 1,2-Dibromo-3-Chloropropane (DBCP) UG/L 1,2,4-Trichlorobenzene UG/L Hexachloro-1,3-Butadiene UG/L 1,2,3-Trichlorobenzene U-Analyte not detected at or above reporting limit. I J-ldentification of analyte is acceptable; reported value is an estimate. I UJ-Analyte not detected at or above reporting limit. Reporting limit is an estimate. N-Presumptive evidence analyte is present; analyte reported as tentative identification. I NJ-Presumptive evidence analyte is present; analyte reported as tentative identification. Reported value is an estimate. K-ldentification of analyte is acceptable; reported value may be biased high. Actual value expected to be less than the reported value. L-ldentification of analyte is acceptable; reported value may be biased low. Actual value expected to be greater than reported value. NA-Not Analyzed. I NAI-Not Analyzed due to lnterierences. l A-Analyte analyzed in replicate. Reported value is "average" of replicates. A-Presence or absence of analyte can not be determined from data due to severe quality control problems. Data are rejected and considered unusable. Page 1 of 1 VOLATILES SAMPLE ANALYSIS EPA -REGION IV SESD, ATHENS, GA Production Date: 03/24/2006 16:14 Sample 3152 FY 2006 Project: 06-0266 Volatiles Scan Facility: Davis Park Rd Program: SF Gastonia, NC Id/Station: MW04 / Media: GROUNDWATER RESULTS UNITS ANALYTE 0.50 U UG/L Dichlorodifluoromethane 0.50 U UG/L Chloromethane 0.50 U UG/L 1, 1,2-Trichloro-1,2,2-Trifluoroethane (Freon 113) 0.50 U UG/L Methyl T-Butyl Ether (MTBE) 0.50 U UG/L Brom om ethane 0.60 UG/L Cyclohexane 0.50 U UG/L Vinyl Chloride 0.50 U UG/L Chloroethane 0.50 U UG/L Trichlorofluoromethane (Freon 11) 0.50 U UG/L 1, 1-Dichloroethene (1, 1-Dichloroethylene) 0.50 U UG/L Methylene Chloride 2.0 U UG/L Acetone 0.50 U UG/L Carbon Disulfide 1.0 U UG/L Methyl Acetate 0.50 U UG/L 1, 1-Dichloroethane 0.50 U UG/L cis-1,2-Dichloroethene 0.50 U UG/L 2,2-Dichloropropane 2.0 U UG/L Methyl Ethyl Ketone · 0.50 U UG/L Bromochloromethane 0.50 U UG/L trans-1,2-Dichloroethene 0.50 U UG/L Chloroform 0.50 U UG/L 1 ,2-Dichloroethane 0.50 U UG/L 1, 1, 1-Trichloroethane 0.50 U UG/L 1, 1-Dichloropropene 0.50 U UG/L Carbon Tetrachloride 0.50 U UG/L Bromodich1oromethane 2.0 U UG/L Methyl lsobutyl Ketone 0.50 U UG/L 1,2-Dichloropropane 0.50 U UG/L Methylcyclohexane 0.50 U UG/L Dibromomethane 0.50 U UG/L trans-1,3-Dichloropropene 0.50 U UG/L Trichloroethane (Trichloroethylene) 0.50 U UG/L Benzene 0.50 U UG/L Dibromochloromethane 0.50 U UG/L 1, 1,2-Trichloroethane Sample Received Unpreserved; Holding Time & all other Criteria Met! RESULTS 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 2.0 U 0.50 U 0.50 U 0.50 U 0.50 U 1.0 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U Produced by: Hale, Sallie Requestor: Project Leader: JWENDEL Beginning: 02/08/2006 11 :50 Ending: UNITS ANALYTE UG/L cis-1,3-Dichloropropene UG/L Bromoform UG/L Bromobenzene · UG/L 1, 1,2,2-Tetrachloroethane UG/L T etrachloroethene (T etrachloroethylene) UG/L 1,3-Dichloropropane UG/L Methyl Butyl Ketone UG/L Toluene UG/L Chlorobenzene UG/L 1, 1 , 1,2-T etrachloroethane UG/L Ethyl Benzene UG/L (m-and/or p-)Xylene UG/L o-Xylene UG/L Styrene UG/L · 1,2,3-Trichloropropane UG/L o-Chlorotoluene UG/L p-Chlorotoluene UG/L 1,3-Dichlorobenzene UG/L 1,4-Dichlorobenzene UG/L 1,2-Dichlorobenzene · UG/L 1,2-Dibromoethane (EDB) UG/L lsopropylbenzene UG/L n-Propylbenzene UG/L 1,3,5-Trimethylbenzene UG/L tert-Butylbenzene UG/L 1,2,4-Trimethylbenzene UG/L sec-Butyl benzene UG/L p-lsopropyltoluene UG/L n-Butylbenzene UG/L 1,2-Dibromo-3-Chloropropane (DBCP) UG/L 1,2,4-Trichlorobenzene UG/L Hexachloro-1,3-Butadiene UG/L 1,2,3-Trichlorobenzene U-Analyte not detected at or above reporting limit. I J-ldentification of analyte is acceptable; reported value is an estimate. I UJ-Analyte not detected at or 8.bove reporting limit. Reporting limit is an estimate. N-Presumptive evidence analyte is present; analyte reported as tentative identificatioii. I NJ-Presumptive evidence analyte is present; analyte reported as tentative identification. Reported value is an estimate. K·ldentification of analyte is acceptable; reported value may be biased high. Actual value expected to be less than the reported value. L·ldentification of analyte is acceptable; reported value may be biased low. Actual value expected to be greater than reported value. NA•Not Analyzed. I NAl·Not Analyzed due to Interferences. I A·Analyte analyzed in replicate. Reported value is "average" of replicates. A-Presence or absence of analyte can not be determined from data due to severe quality control problems. Data are rejected and considered unusable. ----------------~~- -Sample 3153 FY 2006 Project: 06-0266 Volatiles Scan Facility: Davis Park Rd Program: SF Gastonia, NC Id/Station: MW05 / Media: GROUNDWATER RESULTS 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 2.0 U 0.50 U 1.0 U 0.50 U 0.50 U 0.50 U 2.0 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 2.0 U 0.50 U 0.50 U 0.50 U 0.50 U 0.57 0.50 U 0.50 U 0.50 U UNITS UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L ANALYTE Dichlorodifluoromethane Chloromethane 1, 1,2-T richloro-1,2,2-Trifluoroethane (Freon 113) Methyl T-Butyl Ether (MTBE) Bromomethane Cyclohexane Vinyl Chloride Chloroethane Trichlorofluoromethane (Freon 11) 1, 1-Dichloroethene (1, 1-Dichloroethylene) Methylene Chloride Acetone Carbon Disulfide Methyl Acetate 1, 1-Dichloroethane cis-1,2-Dichloroethene 2,2-Dichloropropane Methyl Ethyl Ketone Bromochloromethane trans-1,2-Dichloroethene Chloroform 1,2-Dichloroethane 1, 1, 1-Trichloroethane 1, 1-Dichloropropene Carbon Tetrachloride Bromodichloromethane Methyl lsobutyl Ketone 1,2-Dichloropropane Methylcyclohexane Dibromomethane trans-1,3-Dichloropropene Trichloroethene (Trichloroethylene) Benzene Dibromochloromethane 1, 1,2-Trichloroethane Sample Received Unpreserved; Holding Time & all other Criteria Met! RESULTS 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 2.0 U 0.50 U 0.50 U 0.50 U 0.50 U 1.0 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U -Produced by: Hale, Sallie Requester: Project Leader: JW ENDEL Beginning: 02/07/2006 17:15 Ending: UNITS UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UGIL UG/L UG/L ANALYTE cis-1,3-Dichloropropene Bromoform Bromobenzene 1, 1,2,2-Tetrachloroethane T etrachloroethene (T etrachloroethylene) 1,3-Dichloropropane Methyl Butyl Ketone Toluene Chlorobenzene 1, 1, 1,2-Tetrachloroethane Ethyl Benzene (m-and/or p-)Xylene a-Xylene Styrene 1,2,3-Trichloropropane o-Chlorotoluene p-Chlorotoluene 1 ,3-Dichlorobenzene 1 ,4-Dichlorobenzene 1 ,2-Dichlorobenzene 1,2-Dibromoethane (EDB) lsopropylbenzene n-Propylbenzene 1,3,5-Trimethylbenzene tert-Butylbenzene 1,2,4-Trimethylbenzene sec-Butylbenzene p-lsopropyltoluene n-Butylbenzene 1,2-Dibromo-3-Chloropropane (DBCP) 1,2,4-Trichlorobenzene Hexachloro-1,3-Butadiene 1,2,3-Trichlorobenzene U-Analyte not detected at or above reporting limit. I J-ldentification of analyte is acceptable; reported value is an estimate. I UJ-Analyte not detected at or above reporting limit. Reporting limit is an estimate. N-Presumptive evidence analyte is present; analyte reported as tentative identification. I NJ-Presumptive evidence analyte is present; analyte reported as tentative identification. Reported value is an estimate. K-ldentification of analyte is acceptable; reported value may be biased high. Actual value expected to be less than the reported value. L-ldentification of analyte is acceptable; reported value may be biased low. Actual value expected to be greater than reported value. NA-Not Analyzed. I NAl-Not Analyzed due to lnterterences. I A-Analyte analyzed in replicate. Reported value is "average" of replicates. A-Presence or absence of analyte can not be determined from data due to severe quality control problems. Data are rejected and considered unusable. Page 1 of 1 VOLATILES SAMPLE ANALYSIS EPA -REGION IV SESD, ATHENS, GA Production Date: 03/24/2006 16:14 Sample 3154 FY 2006 Project: 06-0266 Volatiles Scan Facility: Davis Park Ad Program: SF Gastonia, NC Id/Station: MW07 / Media: GROUNDWATER RESULTS UNITS ANALYTE 0.50 U UG/L Dichlorodifluoromethane 0.50 U UG/L Chloromethane 0.50 U UG/L 1, 1,2-Trichloro-1,2,2-Trifluoroethane (Freon 113) 0.50 U UG/L Methyl T-Butyl Ether (MTBE) 0.50 U UG/L Bromomethane 0.50 U UG/L Cyclohexane 0.50 U UG/L Vinyl Chloride 0.50 U UG/L Chloroethane 0.50 U UG/L Trichlorofluoromethane (Freon 11) 0.50 U UG/L 1, 1-Dichloroethene (1, 1-Dichloroethylene) 0.50 U UG/L Methylene Chloride 2.0 U UG/L Acetone 0.50 U UG/L Carbon Disulfide 1.0 U UG/L Methyl Acetate 0.50 U UG/L 1 , 1-Dichloroethane 0.50 U UG/L cis-1 ,2-Dichloroethene 0.50 U UG/L 2,2-Dichloropropane 2.0 U UG/L Methyl Ethyl Ketone 0.50 U UG/L Bromochloromethane 0.50 U UG/L trans-1,2-Dichloroethene 0.50 UG/L Chloroform 0.50 U UG/L 1,2-Dichloroethane 0.50 U UG/L 1, 1 , 1-Trichloroethane 0.50 U UG/L 1, 1-Dichloropropene 0.50 U UG/L Carbon Tetrachloride 0.50 U UG/L Bromodichloromethane 2.0 U UG/L Methyl lsobutyl Ketone 0.50 U UG/L 1,2-Dichloropropane 0.50 U UG/L Methylcyclohexane 0.50 U UG/L Dibromomethane 0.50 U UG/L trans-1 ,3-Dichloropropene 0.50 U UG/L Trichloroethene (Trichloroethylene) 0.50 U UG/L Benzene 0.50 U UG/L Dibromochloromethane 0.50 U UG/L 1, 1,2-Trichloroethane Sample Received Unpreserved; Holding Time & all other Criteria Met! RESULTS 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 2.0 U 0.50 U 0.50 U 0.50 U 0.50 U 1.0 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U Produced by: Hale, Sallie Requestor: Project Leader: JWENDEL Beginning: 02/07/2006 15:30 Ending: UNITS ANALYTE UG/L cis-1,3-Dichloropropene UG/L Bromoform UG/L Bromobenzene UG/L 1, 1,2,2-T etrachloroethane UG/L Tetrachloroethene (Tetrachloroethylene) UG/L 1,3-Dichloropropane UG/L Methyl Butyl Ketone UG/L Toluene UG/L Chlorobenzene UG/L 1, 1, 1,2-Tetrachloroethane UG/L Ethyl Benzene UG/L (m-and/or p-)Xylene UG/L o-Xylene UG/L Styrene UG/L 1,2,3-Trichloropropane UG/L o-Chlorotoluene UG/L p-Chlorotoluene UG/L 1,3-0ichlorobenzene UG/L 1,4-Dichlorobenzene UG/L 1,2-Dichlorobenzene UG/L 1,2-Dibromoethane (EDB) UG/L lsopropylbenzene UG/L n-Propylbenzene UG/L 1,3,5-Trimethylbenzene UG/L tert-Butylbenzene UG/L 1,2,4-Trimethylbenzene UG/L sec-Butylbenzene UG/L p-lsopropyltoluene UG/L n-Butylbenzene UG/L 1,2-Dibromo-3-Chloropropane (DBCP) UG/L 1,2,4-Trichlorobenzene UG/L Hexachloro-1,3-Butadiene UG/L 1,2,3-Trichlorobenzene U-Analyte not detected at or above reporting limit. I J-ldentification of analyte is acceptable!; reported value is an estimate. I UJ-Analyte not detected at or above reporting limit. Reporting limit is an estimate. N-Presumptive evidence analyte is present; analyte reported as tentative identification. I NJ-Presumptive evidence analyte is present; analyte reported as tentative identification. Reported value is an estimate. K-ldentification of analyte is acceptable; reported value may be biased high. Actual value expected to be less than the reported value. L-ldentification of analyte is acceptable; reported value may be biased low. Actual value expected to be greater than reported value. NA-Not Analyzed. I NAI-Not Analyzed due to Interferences. I A-Analyte analyzed in replicate. Reported value is "average" of replicates. A-Presence or absence of analyte can not be determined from data due to severe quality control problems. Data are rejected and considered unusable. ----------------~~- - - Sample 3155 FY 2006 Project: 06-0266 Volatiles Scan Facility: Davis Park Rd Program: SF Gastonia, NC Id/Station: MW08 / Media: GROUNDWATER RESULTS 0.50 UJ 0.50 U 0.50 U 0.50 U 0.50 UJ 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 2.0 U 0.50 U 1.0 U 0.50 U 0.50 U 0.50 U 2.0 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 2.0 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U UNITS UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L ANALYTE Dichlorodifluoromethane Chloromethane 1, 1,2-Trichloro-1,2,2-Trifluoroethane (Freon 113) Methyl T-Butyl Ether (MTBE) Bromomethane Cyclohexane Vinyl Chloride Chloroethane Trichlorofluoromethane (Freon 11) 1, 1-Dichloroethene (1, 1-Dichloroethylene) Methylene Chloride Acetone Carbon Disulfide Methyl Acetate 1, 1-Dichloroethane cis-1,2-Dichloroethene 2,2-Dichloropropane Methyl Ethyl Ketone Bromoch1oromethane trans-1 ,2-Dichloroethene Chloroform 1,2-Dichloroethane 1, 1, 1-Trichloroethane 1, 1-Dichloropropene Carbon Tetrachloride Bromodichloromethane Methyl lsobutyl Ketone 1,2-Dichloropropane Methylcyclohexane Dibromomethane trans-1,3-0ichloropropene Trichloroethane (Trichloroethylene) Benzene Dibromochloromethane 1, 1,2-Trichloroethane Dichlorodifluoromethane & Bromomethane had low recovery in the CCV. Sample Received Unpreserved; Holding Time & all other Criteria Met! RESULTS 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 2.0 U 0.50 U 0.50 U 0.50 U 0.50 U 1.0 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U -Produced by: Hale, Sallie Requester: Project Leader: JWENDEL Beginning: 02/07/2006 16:40 Ending: UNITS UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L ANALYTE cis-1,3-Dichloropropene Bromoform Bromobenzene 1, 1,2,2-T etrachloroethane T etrachloroethene (T etrachloroethylene) 1,3-Dichloropropane Methyl Butyl Ketone Toluene Chlorobenzene 1, 1, 1,2-Tetrachloroethane Ethyl Benzene (m-and/or p-)Xylene o-Xylene Styrene 1,2,3-Trichloropropane o-Chlorotoluene p-Chlorotoluene 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene 1,2-Dibromoethane (EDB) lsopropylbenzene n-Propylbenzene 1,3,5-Trimethylbenzene tert-Butylbenzene 1,2,4-Trimethylbenzene sec-Butylbenzene p-lsopropyltoluene n-Butylbenzene 1,2-Dibromo-3-Chloropropane (DBCP) 1,2,4-Trichlorobenzene Hexachloro-1,3-Butadiene 1,2,3-Trichlorobenzene U-Analyte not detected at or above reporting limit. 1 J-ldentification of analyte is acceptable; reported value is an estimate. ! UJ-Analyte not detected at or above reporting limit. Reporting limit is an estimate. N-Presumptive evidence analyte is present; analyte reported as tentative identification. I NJ-Presumptive evidence analyte is present; analyte reported as tentative identification. Reported value is an estimate. K-ldentification of analyte is acceptable; reported value may be biased high. Actual value expected to be less than the reported value. L-ldentification of analyte is acceptable; reported value may be biased low. Actual value expected to be greater than reported value. NA-Not Analyzed. I NAI-Not Analyzed due to lnterlerences. I A-Analyte analyzed in replicate. Reported value ls •average· of replicates. A-Presence or absence of anatyte can not be determined from data due to severe quality control problems. Data are rejected and considered unusable. Page 1 of 1 VOLATILES SAMPLE ANALYSIS EPA -REGION IV SESD, ATHENS, GA Production Date: 03/24/2006 16:14 Sample 3156 FY 2006 Project: 06-0266 Volatiles Scan Facility: Davis Park Rd Program: SF Gastonia, NC Id/Station: MW09 / Media: GROUNDWATER RESULTS UNITS ANALVTE 0.50 UJ UG/L Dichlorodifluoromethane 0.50 U UG/L Chloromethane 0.50 U UG/L 1, 1,2-Trichloro-1,2,2-Trifluoroe_thane (Freon 113) 0.50 U UG/L Methyl T-Butyl Ether (MTBE) 0.50 UJ UG/L Bromomethane 0.50 U UG/L Cyclohexane 0.50 U UG/L Vinyl Chloride 0.50 U UG/L Chloroethane 0.50 U UG/L Trichlorofluoromethane (Freon 11) 0.50 U UG/L 1, 1-Dichloroethene (1, 1-Dichloroethylene) 0.50 U UG/L Methylene Chloride 2.0 U UG/L Acetone 0.50 U UG/L Carbon Disulfide 1.0 U UG/L Methyl Acetate 0.50 U UG/L 1, 1-Dichloroethane 1.3 UG/L cis-1,2-Dichloroethene 0.50 U UG/L 2,2-Dichloropropane 2.0 U UG/L Methyl Ethyl Ketone 0.50 U UG/L Bromochloromethane 0.50 U UG/L trans-1,2-Dichloroethene 0.50 U UG/L Chloroform 0.50 U UG/L 1,2-Dichloroethane 0.50 U UG/L 1, 1, 1-Trichloroethane 0.50 U UG/L 1, 1-Dichloropropene 0.50 U UG/L Carbon Tetrachloride 0.50 U UG/L Bromodichloromethane 2.0 U UG/L Methyl lsobutyl Ketone 0.50 U UG/L 1,2-Dichloropropane 0.50 U UG/L Methylcyclohexane 0.50 U UG/L Dibromomethane 0.50 U UG/L trans-1,3-Dichloropropene 12 UG/L Trichloroethane (Trichloroethylene) 0.50 U UG/L Benzene 0.50 U UG/L Dibromochloromethane 0.50 U UG/L 1, 1,2-Trichloroethane Dichlorodifluoromethane & Bromomethane had low recovery in the CCV. Sample Received Unpreserved; Holding Time & all other Criteria Met! RESULTS 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 2.0 U 0.50 U 0.50 U 0.50 U 0.50 U 1.0 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U Produced by: Hale, Sallie Requester: Project Leader: JWENDEL Beginning: 02/07/2006 13:50 Ending: UNITS ANALVTE UG/L cis-1,3-Dichloropropene UG/L Bromoform UG/L Bromobenzene UG/L 1, 1,2,2-Tetrachloroethane UG/L T etrachloroethene (T etrachloroethylene) UG/L 1,3-Dichloropropane UG/L Methyl Butyl Ketone UG/L Toluene UG/L Chlorobenzene UG/L 1, 1, 1,2-Tetrachloroethane UG/L Ethyl Benzene UG/L (m-and/or p-)Xylene UG/L a-Xylene UG/L Styrene UG/L 1,2,3-Trichloropropane UG/L o-Chlorotoluene UG/L p-Chlorotoluene UG/L 1,3-Dichlorobenzene UG/L 1,4-Dichlorobenzene UG/L 1 ,2-Dichlorobenzene UG/L 1,2-Dibromoethane (EDB) UG/L lsopropylbenzene UG/L n-Propylbenzene UG/L 1,3,5-Trimethylbenzene UG/L tert-Butylbenzene UG/L 1,2,4-Trimethylbenzene UG/L sec-Butyl benzene UG/L p-lsopropyltoluene UG/L n-Butylbenzene UG/L 1,2-Dibromo-3-Chloropropane (DBCP) UG/L 1,2,4-Trichlorobenzene UG/L Hexachloro-1,3-Butadiene UG/L 1,2,3-Trichlorobenzene U-Analyte not detected at or above reporting limit. I J-ldentification of analyte is acceptable; reported value is an estimate. j UJ·Analyte not detected at or above reporting limit. Reporting limit is an estimate. N-Presumptive evidence analyte is present; analyte reported as tentative identification. I NJ-Presumptive evidence analyte is present; analyte reported as tentative identification. Reported value is an estimate. K-ldentification of analyte is acceptable; reported value may be biased high. Actual value expected to be less than the reported value. L-ldentification of analyte is acceptable; reported value may be biased low. Actual value expected to be greater than reported value. NA-Not Analyzed. I NAI-Not Analyzed due to Interferences. I A-Analyte analyzed in ·replicate. Reported value is "average" of replicates. A-Presence or absence of analyte can not be determined from data due to severe quality control problems. Data are rejected and considered unusable. -- -- - - ---- -- -- - - Page 1 of 1 - -- -Sample 3157 FY 2006 Project: 06-0266 Volatiles Scan Facility: Davis Park Rd Program: SF Gastonia, NC Id/Station: MW10 / Media: GROUNDWATER RESULTS 0.50 UJ 0.50 U 0.50 U 0.50 U 0.50 UJ 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 2.0 U 0.50 U 1.0 U 0.50 U 0.50 U 0.50 U 2.0 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 2.0 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U UNITS UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L ANALYTE Dichlorodifluoromethane Chloromethane 1, 1,2-Trichloro-1,2,2-Trifluoroethane (Freon 113) Methyl T-Butyl Ether (MTBE) Brom om ethane Cyclohexane Vinyl Chloride Chloroethane Trichlorofluoromethane (Freon 11) 1, 1-Dichloroethene (1, 1-Dichloroethylene) Methylene Chloride Acetone Carbon Disulfide Methyl Acetate 1 , 1-Dichloroethane cis-1 ,2-Dichloroethene 2,2-Dichloropropane Methyl Ethyl Ketone Bromochloromethane trans-1,2-Dichloroethene Chloroform 1,2-Dichloroethane 1, 1 , 1-Trichloroethane 1, 1-Dichloropropene Carbon Tetrachloride Bromodichloromethane Methyl lsobutyl Ketone 1,2-Dichloropropane Methylcyclohexane Oibromomethane trans-1,3-Dichloropropene Trichloroethane (Trichloroethylene) Benzene Oibromochloromethane 1, 1,2-T richloroethane Dichlorodifluoromethane & Bromomethane had low recovery in the CCV. Sample Received Unpreserved; Holding Time & all other Criteria Met! RESULTS 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 2.0 U 0.50 U 0.50 U 0.50 U 0.50 U 1.0 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U -Produced by: Hale, Sallie Requestor: Project Leader: JWENDEL Beginning: 02/08/2006 13:10 Ending: UNITS UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L ANALYTE cis-1,3-Dichloropropene Bromoform Bromobenzene 1, 1,2,2-Tetrachloroethane Tetrachloroethene (Tetrachloroethylene) 1,3-Dichloropropane Methyl Butyl Ketone Toluene Chlorobenzene 1, 1, 1,2-Tetrachloroethane Ethyl Benzene (m-and/or p-)Xylene a-Xylene Styrene 1,2,3-Trichloropropane o-Chlorotoluene p-Chlorotoluene 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene 1,2-Dibromoethane (EDB) lsopropylbenzene n-Propylbenzene 1,3,5-Trimethylbenzene tert-Butylbenzene 1,2,4-Trimethylbenzene sec-Butylbenzene p-lsopropyltoluene n-Butylbenzene 1,2-Dibromo-3-Chloropropane (DBCP) 1,2,4-Trichlorobenzene Hexachloro-1,3-Butadiene 1,2,3-Trichlorobenzene U-Analyte not detected at or above reporting limit. I J-ldentification of analyte is acceptable; reported value is an estimate. I UJ-Analyte not detected at or above reporting limit. Reporting limit is an estimate. N-Presumptive evidence analyte is present; analyte reported as tentative identification. I NJ-Presumptive evidence analyte is present; analyte reported as tentative identification. Reported value is an estimate. K-ldentification of analyte is acceptable; reported value may be biased high. Actual value expected to be less than the reported value. L-ldentification of analyte is acceptable; reported value may be biased low. Actual value expected to be greater than reported value. NA-Not Analyzed. I NAI-Not Analyzed due to lnterierences. I A-Analyte analyzed in replicate. Reported value is "average" of replicates. A-Presence or absence of analyte can not be determined from data due to severe quality control problems. Data are rejected and considered unusable. Page 1 of 1 VOLATILES SAMPLE ANALYSIS EPA-REGION IV SES0, ATHENS, GA Production Date: 03/24/2006 16:14 Sample 3158 FY 2006 Project: 06-0266 Volatiles Scan Facility: Davis Park Rd Program: SF Gastonia, NC Id/Station: MW11 / Media: GROUNDWATER RESULTS UNITS ANALYTE 0.50 UJ UG/L Dichlorodifluoromethane 0.50 U UG/L Chloromethane 0.50 U UG/L 1, 1,2-Trichloro-1,2,2-Trifluoroethane (Freon 113) 0.50 U UG/L Methyl T-Butyl Ether (MTBE) 0.50 UJ UG/L Bromomethane 0.50 U UG/L Cyclohexane 0.50 U UG/L Vinyl Chloride 0.50 U UG/L Chloroethane 0.50 U UG/L Trichlorofluoromethane (Freon 11) 0.50 U UG/L 1, 1-Dichloroethene ( 1 , 1-Dichloroethylene) 0.50 U UG/L Methylene Chloride 2.0 U UG/L Acetone 0.50 U UG/L Carbon Disulfide 1.0 U UG/L Methyl Acetate 0.50 U UG/L 1, 1-Dichloroethane 0.50 U UG/L cis-1 ,2-Dichloroethene 0.50 U UG/L 2,2-Dichloropropane 2.0 U UG/L Methyl Ethyl Ketone· 0.50 U UG/L Bromochloromethane 0.50 U UG/L trans-1,2-Dichloroethene 0.50 U UG/L Chloroform 0.50 U UG/L 1,2-Dichloroethane 0.50 U UG/L 1, 1, 1-Trichloroethane 0.50 U UG/L 1, 1-Dichloropropene 0.50 U UG/L Carbon Tetrachloride 0.50 U UG/L Bromodichloromethane 2.0 U UG/L Methyl lsobutyl Ketone 0.50 U UG/L 1,2-Dichloropropane 0.50 U UG/L Methylcyclohexane 0.50 U UG/L Dibromomethane 0.50 U UG/L trans-1,3-Dichloropropene 0.50 U UG/L Trichloroethene (Trichloroethylene) 0.50 U UG/L Benzene 0.50 U UG/L Dibromochloromethane 0.50 U UG/L 1, 1,2-Trichloroethane Dichlorodifluoromethane & Bromomethane had low recovery in the CCV. Sample Received Unpreserved; Holding Time & all other Criteria Met! RESULTS 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 2.0 U 0.50 U 0.50 U 0.50 U 0.50 U 1.0 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U P_roduced by: Hale, Sallie Requester: Project Leader: JWENDEL Beginning: 02/07/2006 13:20 Ending: UNITS ANALYTE UG/L cis-1,3-Dichloropropene UG/L Bromoform UG/L Bromobenzene UG/L 1, 1,2,2-Tetrachloroethane UG/L Tetrachloroethene (Tetrachloroethylene) UG/L 1,3-Dichloropropane UG/L Methyl Butyl Ketone UG/L Toluene UG/L Chlorobenzene UG/L 1, 1, 1,2-Tetrachloroethane UG/L Ethyl Benzene UG/L (m-and/or p-)Xylene UG/L a-Xylene UG/L Styrene UG/L 1,2,3-Trichloropropane UG/L o-Chlorotoluene UG/L p-Chlorotoluene UG/L 1,3-Dichlorobenzene UG/L 1,4-Dichlorobenzene UG/L 1,2-Dichlorobenzene UG/L 1,2-Dibromoethane (EDB) UG/L lsopropylbenzene UG/L n-Propylbenzene UG/L . 1,3,5-Trimethylbenzene UG/L tert-Butylbenzene UG/L 1,2,4-Trimethylbenzene UG/L sec-Butylbenzene UG/L p-lsopropyltoluene UG/L n-Butylbenzene UG/L 1,2-Dibromo-3-Chloropropane (DBCP) UG/L 1,2,4-Trichlorobenzene UG/L Hexachloro-1,3-Butadiene UG/L 1,2,3-Trichlorobenzene U-Analyte not detected at or above reporting limit. I J-ldentification of analyte is acceptable; reported value is an estimate. I UJ-Analyte not detected at or above reporting limit. Reporting limit is an estimate. N-Presumptive evidence ana1yte is present; analyte r_eported as tentative identification. I NJ-Presumptive evidence analyte is present; analyte reported as tentative identification. Reported value is an estimate. K-ldentification of ana1yte is acceptable; reported value may be biased high. Actual value expected to be less than the reported value. L-ldentification of analyte is acceptable; reported value may be biased low. Actual value expected to be greater than reported value. NA-Not Analyzed. I NAI-Not Analyzed due to lnterterences. I A-Analyte analyzed in replicate. Reported value is "average" of replicates. A-Presence or absence of analyte can not be determined from data due to severe quality control problems. Data are rejected and considered unusable. -- - - - - ---- - - ----Page 1 of 1 - - - -Sample 3159 FY 2006 Project: 06-0266 Volatiles Scan Facility: Davis Park Rd Program: SF Gastonia, NC Id/Station: MW 12 / Media: GROUNDWATER RESULTS 0.50 UJ 0.50 U 0.50 U 0.50 U 0.50 UJ 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 2.0 U 0.50 U 1.0 U 0.50.U 0.50 U 0.50 U 2.0 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 2.0 U 0.50 U 0.50 U 0.50 U 0.50 U 2.1 A 0.50 U 0.50 U 0.50 U UNITS UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L ANALYTE Dichlorodifluoromethane Chloromethane 1, 1,2-Trichloro-1,2,2-Trifluoroethane (Freon 113) Methyl T-Butyl Ether (MTBE) Bromomethane Cyclohexane Vinyl Chloride Chloroethane Trichlorofluoromethane (Freon 11) 1, 1-Dichloroethene (1, 1-Dichloroethylene) Methylene Chloride Acetone Carbon Disulfide Methyl Acetate 1, 1-Dichloroethane cis-1,2-Dichloroethene 2,2-Dichloropropane Methyl Ethyl Ketone Bromochloromethane trans-1,2-Dichloroethene Chloroform 1,2-Dichloroethane 1, 1, 1-Trichloroethane 1, 1-Dichloropropene Carbon Tetrachloride Bromodichloromethane Methyl lsobutyl Ketone 1,2-Dichloropropane Methylcyclohexane Dibromomethane trans-1,3-Dichloropropene Trichloroethene (Trichloroethylene) Benzene Dibromochloromethane 1, 1,2-Trichloroethane Dichlorodifluoromethane & Bromomethane had low recovery in the CCV. Sample Received Unpreserved; Holding Time & all other Criteria Met! RESULTS 0.50 U 0.50 U 0.50 U 0.50 U 1.0 A 0.50 U 2.0 U 0.50 U 0.50 U 0.50 U 0.50 U 1.0 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U -Produced by: Hale, Sallie Requestor: Project Leader: JWENDEL Beginning: 02/08/2006 14:00 Ending: UNITS UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L ANALYTE cis-1,3-Dichloropropene Bromoform Bromobenzene 1, 1,2,2-Tetrachloroethane T etrachloroethene (T etrachloroethylene) 1,3-Dichloropropane Methyl Butyl Ketone Toluene Chlorobenzene 1, 1, 1,2-Tetrachloroethane Ethyl Benzene (m-and/or p-)Xylene a-Xylene Styrene 1,2,3-Trichloropropane o-Chlorotoluene p-Chlorotoluene 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene 1,2-Dibromoethane (EDS) lsopropylbenzene n-Propylbenzene 1,3,5-Trimethylbenzene tert-Butylbenzene 1,2,4-Trimethylbenzene sec-Butylbenzene p-lsopropyltoluene n-Butylbenzene 1,2-Dibromo-3-Chloropropane (DBCP) 1,2,4-Trichlorobenzene Hexachloro-1,3-Butadiene 1,2,3-Trichlorobenzene U-Analyte not detected at or above reporting limit. I J-ldentification of analyte is acceptable; reported value is an estimate. I UJ-Analyte not detected at or above reporting limit. Reporting limit is an estimate. N-Presumptive evidence analyte is present; analyte reported as tentative identification. I NJ-Presumptive evidence analyte is present; analyte reported as tentative identification. Reported value is an estimate. K-ldentification of analyte is acceptable; reported value may be biased high. Actual value expected to be less than the reported value. L-tdentification of analyte is acceptable; reported value may be biased low. Actual value expected to be greater than reported value. NA-Not Analyzed. I NAI-Not Analyzed due to Interferences. I A-Analyte analyzed in replicate. Reported value is ·average" of replicates. A-Presence or absence of analyte can not be determined from data due to severe quality control problems. Data are rejected and considered unusable. Page 1 of 1 VOLATILES SAMPLE ANALYSIS EPA -REGION IV SESO, ATHENS, GA Production Date: 03/24/2006 16:14 Sample 3160 FY 2006 Project: 06-0266 Volatiles Scan Facility: Davis Park Rd Program: SF ld/Station:MW15 / Media: GROUNDWATER Gastonia, NC RESULTS UNITS ANALYTE 0.50 UJ UG/L Dichlorodifluoromethane 0.50 U UG/L Chloromethane 0.50 U UG/L 1, 1,2-Trichloro-1,2,2-Trifluoroethane (Freon 113) 0.50 U UG/L Methyl T-Butyl Ether (MTBE) 0.50 UJ UG/L Bromomethane 1.4 UG/L Cyclohexane 0.50 U UG/L Vinyl Chloride 0.50 U UG/L Chloroethane 0.50 U UG/L Trichlorofluoromethane (Freon 11) 0.50 U UG/L 1, 1-Dichloroethene (1, 1-Dichloroethylene) 0.50 U UG/L Methylene Chloride 2.0 U UG/L Acetone 0.50 U UG/L Carbon Disulfide 1.0 U UG/L Methyl Acetate 0.50 U UG/L 1, 1-Dichloroethane 3.4 UG/L cis-1,2-Dichloroethene 0.50 U UG/L 2,2-Dichloropropane 2.0 U UG/L Methyl Ethyl Ketone 0.50 U UG/L Bromochloromethane 0.50 U UG/L trans-1,2-Dichloroethene 0.50 U UG/L Chloroform 0.50 U UG/L 1,2-Dichloroethane 0.50 U UG/L 1 , 1, 1-Trichloroethane 0.50 U UG/L 1 , 1-Dichloropropene 0.50 U UG/L Carbon Tetrachloride 0.50 U UG/L Bromodichloromethane 2.0 U UG/L Methyl lsobutyl Ketone 0.50 U UG/L 1,2-Dichloropropane 0.50 U UG/L Methylcyclohexane 0.50 U UG/L Dibromomethane 0.50 U UG/L trans-1,3-Dichloropropene 40 UG/L Trichloroethene (Trichloroethylene) 0.50 U UG/L Benzene 0.50 U UG/L Dibromochloromethane 0.50 U UG/L 1 , 1,2-T richloroethane Dichlorodifluoromethane & Bromomethane had low recovery in the CCV. Sample Received Unpreserved; Holding Time & all other Criteria Met! RESULTS 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 2.0 U 0.50 U 0.50 U 0.50 U 0.50 U 1.0 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U Produced by: Hale, Sallie Requestor: Project Leader: JWENDEL Beginning: 02/08/2006 09:20 Ending: UNITS ANALYTE UG/L cis-1,3-Dichloropropene UG/L Bromoform UG/L Bromobenzene UG/L 1, 1,2,2-Tetrachloroethane UG/L T etrachloroethene (T etrachloroethylene) UG/L 1,3-Dichloropropane UG/L Methyl Butyl Ketone UG/L Toluene UG/L Chlorobenzene UG/L 1, 1, 1,2-Tetrachloroethane UG/L Ethyl Benzene UG/L (m-and/or p-)Xylene UG/L o-Xylene UG/L Styrene UG/L 1,2,3-Trichloropropane UG/L o-Chlorotoluene UG/L p-Chlorotoluene UG/L 1,3-Dichlorobenzene UG/L 1,4-Dichlorobenzene UG/L 1,2-Dichlorobenzene UG/L 1,2-Dibromoethane (EDB) UG/L lsopropylbenzene UG/L n-Propylbenzene UG/L 1,3,5-Trimethylbenzene UG/L tert-Butylbenzene UG/L 1,2,4-Trimethylbenzene UG/L sec-Butylbenzene UG/L p-lsopropyltoluene UG/L n-Butylbenzene UG/L . 1,2-Dibromo-3-Chloropropane (DBCP) UG/L 1,2,4-Trichlorobenzene UG/L Hexachloro-1,3-Butadiene UG/L 1,2,3-Trichlorobenzene U-Analyte not detected at or above reporting limit. ! J-ldentification of analyte is acceptable; reported value is an estimate. I UJ-Anatyte not detected at or above reporting limit. Reporting limit is an estimate. N-Presumptive evidence analyte is present; analyte reported as tentative identification. I NJ-Presumptive evidence analyte is present; analyte reported as tentative identification. Reported value is an estimate. K-ldentification of analyte is acceptable; reported value may be biased high. Actual value expected to be less than the reported value. L-ldentification of analyte is acceptable; reported value may be biased low. Actual value expected to be greater than reported value. NA-Not Analyzed. I NAI-Not Analyzed due to lnterterences. I A-Analyte analyzed in replicate. Reported value is "average' of replicates. A-Presence or absence of analyte can not be determined from data due to severe quality control problems. Data are rejected and considered unusable. - - -- - - --- -------Page 1 of 1 - -- -Sample 3161 FY 2006 Project: 06-0266 Volatiles Scan Facility: Davis Park Rd Program: SF Gastonia, NC Id/Station: MW15D / Media: GROUNDWATER RESULTS UNITS 0.50 UJ UG/L 0.50 U UG/L 0.50 U UG/L 0.50 U UG/L 0.50 UJ UG/L 0.50 U UG/L 0.50 U UG/L 0.50 U UG/L 0.50 U UG/L 0.50 U UG/L 0.50 U UG/L 2.0 U UG/L 0.50 U UG/L 1.0 U UGIL 0.50 U UG/L 3.4 UGIL 0.50 U UG/L 2.0 U UG/L 0.50 U UG/L 0.50 U UG/L 0.50 U UG/L 0.50 U UG/L 0.50 U UG/L 0.50 U UG/L 0.50 U UG/L 0.50 U UG/L 2.0 U UG/L 0.50 U UG/L 0.50 U UG/L 0.50 U UG/L 0.50 U UGIL 40 UGIL 0.50 U UGIL 0.50 U UGIL 0.50 U UGIL ANALYTE Dichlorodifluoromethane Chloromethane 1, 1,2-Trichloro-1,2,2-Trifluoroethane (Freon 113) Methyl T-Butyl Ether (MTBE) Bromomethane Cyclohexane Vinyl Chloride Chloroethane Trichlorofluoromethane (Freon 11) 1, 1-Dichloroethene (1, 1-Dichloroethylene) Methylene Chloride Acetone Carbon Disulfide Methyl Acetate 1, 1-Dichloroethane cis-1,2-Dichloroethene 2,2-Dichloropropane Methyl Ethyl Ketone Bromochloromethane trans-1,2-Dichloroethene Chloroform 1,2-Dichloroethane 1, 1, 1-Trichloroethane 1, 1-Dichloropropene Carbon Tetrachloride Bromodichloromethane Methyl lsobutyl Ketone 1,2-Dichloropropane Methylcyclohexane Dibromomethane trans-1,3-Dichloropropene Trichloroethene (Trichloroethylene) Benzene Dibromochloromethane 1, 1,2-Trichloroethane Dichlorodifluoromethane & Bromomethane had low recovery in the CCV. Sample Received Unpreserved; Holding Time & all other Criteria Met! RESULTS 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 2.0 U 0.50 U 0.50 U 0.50 U 0.50 U 1.0 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U -Produced by: Hale, Sallie Requester: Project Leader: JWENDEL Beginning: 02/08/2006 09:20 Ending: UNITS UGIL UGIL UGIL UGIL UGIL UGIL UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L ANALYTE cis-1 ,3-Dichloropropene Bromoform Bromobenzene 1, 1,2,2-Tetrachloroethane Tetrachloroethene (Tetrachloroethylene) 1 ,3-Dichloropropane Methyl Butyl Ketone Toluene Chlorobenzene 1, 1, 1,2-T etrachloroethane Ethyl Benzene (m-and/or p-)Xylene a-Xylene Styrene 1,2,3-T richloropropane o-Chlorotoluene p-Chlorotoluene 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene 1,2-Dibromoethane (EDB) lsopropylbenzene n-Propylbenzene 1,3,5-Trimethylbenzene tert-Butylbenzene 1,2,4-Trimethylbenzene sec-Butylbenzene p-lsopropyltoluene n-Butylbenzene 1,2-Dibromo-3-Chloropropane (DBCP) 1,2,4-Trichlorobenzene Hexachloro-1,3-Butadiene 1,2,3-Trichlorobenzene U-Analyte not detected at or above reporting limit. I J-ldentification of analyte is acceptable; reported value is an estimate. I UJ-Analyte not detected at or above reporting limit. Reporting limit is an estimate. N-Presumptive evidence analyte is present; analyte reported as tentative identification. I NJ-Presumptive evidence analyte is present; analyte reported as tentative identification. Reported value is an estimate. K-ldentification of analyte is acceptable; reported value may be biased high. Actual value expected to be less than the reported value. L-ldentification of analyte is acceptable; reported value may be biased low. Actual value expected to be greater than reported value. NA-Not Analyzed. I NAI-Not Analyzed due to Interferences. I A-Analyte analyzed in replicate. Reported value is "average" of replicates. A-Presence or absence of analyte can not be determined from data due to severe quality control problems. Data are rejected and considered unusable. Page 1 of 1 VOLATILES SAMPLE ANALYSIS EPA -REGION IV SESD, ATHENS, GA Production Date: 03/24/200616:14 Sample 3162 FY 2006 Project: 06-0266 Volatiles Scan Facility: Davis Park Rd Program: SF Gastonia, NC Id/Station: MW 16 / Media: GROUNDWATER RESULTS UNITS ANALYTE 0.50 UJ UG/L Dichlorodifluoromethane 0.50 U UG/L Chloromethane 0.50 U UG/L 1, 1,2-Trichloro-1,2,2-Trifluoroethane (Freon 113) 0.50 U UG/L Methyl T-Butyl Ether (MTBE) 0.50 UJ UG/L Bromomethane 0.50 U UG/L Cyclohexane 0.50 U UG/L Vinyl Chloride 0.50 U UG/L Chloroethane 0.50 U UG/L Trichlorofluoromethane (Freon 11) 0.50 U UG/L 1, 1-Dichloroethene (1, 1-Dichloroethylene) 0.50 U UG/L Methylene Chloride 2.0 U UG/L Acetone 0.50 U UG/L Carbon Disulfide 1.0 U UG/L Methyl Acetate 0.50 U UG/L 1, 1-Dichloroethane 0.50 U UG/L cis-1,2-Dichloroethene 0.50 U UG/L 2,2-Dichloropropane 2.0 U UG/L Methyl Ethyl Ketone 0.50 U UG/L Bromochloromethane 0.50 U UG/L trans-1,2-Dichloroethene 0.50 U UG/L Chloroform 0.50 U UG/L 1,2-Dichloroethane 0.50 U UG/L 1, 1, 1-Trichloroethane 0.50 U UG/L 1, 1-0ichloropropene 0.50 U UG/L Carbon Tetrachloride 0.50 U UG/L Bromodichloromethane 2.0 U UG/L Methyl lsobutyl Ketone 0.50 U UG/L 1,2-Dichloropropane 0.50 U UG/L Methylcyclohexane 0.50 U UG/L Dibromomethane 0.50 U UG/L trans-1,3-0ichloropropene 0.50 U UG/L Trichloroethane (Trichloroethylene) 0.50 U UG/L Benzene 0.50 U UG/L Dibromochloromethane 0.50 U UG/L 1, 1,2-Trichloroethane Dichlorodifluoromethane & Bromomethane had low recovery in the CCV. Sample Received Unpreserved; Holding Time & all other Criteria Met! RESULTS 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 2.0 U 0.50 U 0.50 U 0.50 U 0.50 U 1.0 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U Produced by: Hale, Sallie Requestor: Project Leader: JWENDEL Beginning: 02/07/200616:15 Ending: UNITS ANALYTE UG/L cis-1,3-Dichloropropene UG/L Bromoform UG/L Bromobenzene UG/L 1, 1,2,2-Tetrachloroethane UG/L Tetrachloroethene (Tetrachloroethylene) UG/L 1,3-Dichloropropane UG/L Methyl Butyl Ketone UG/L Toluene UG/L Chlorobenzene UG/L 1, 1 , 1,2-Tetrachloroethane UG/L Ethyl Benzene UG/L (m-and/or p-)Xylene UG/L a-Xylene UG/L Styrene UG/L 1,2,3-Trichloropropane UG/L o-Chlorotoluene UG/L p-Chlorotoluene UG/L 1,3-Dichlorobenzene UG/L 1,4-Dichlorobenzene UG/L 1,2-Dichlorobenzene UG/L 1,2-Dibromoethane (EDB) UG/L lsopropylbenzene UG/L n-Propylbenzene UG/L 1,3,5-Trimethylbenzene UG/L tert-Butylbenzene UG/L 1,2,4-Trimethylbenzene UG/L sec-Butyl benzene UG/L p-lsopropyltoluene UG/L n-Butylbenzene UG/L 1,2-Dibromo-3-Chloropropane (DBCP) UG/L 1,2,4-Trichlorobenzene UG/L Hexachloro-1,3-Butadiene UG/L 1,2,3-Trichlorobenzene U-Analyte not detected at or above reporting limit. I J-ldentification of analyte is acceptable; reported value is an estimate. I UJ-Analyte not detected at or above reporting limit. Reporting limit is an estimate. N-Presumptive evidence analyte is present; analyte reported as tentative identification. ! NJ-Presumptive evidence analyte is present; analyte reported as tentative identification. Reported value is an estimate. K-ldentification of analyte is acceptable; reported value may be biased high. Actual value expected to be less than the reported value. L-ldentification of analyte is acceptable; reported value may be biased low. Actual value expected to be greater than reported value. NA-Not Analyzed. I NAI-Not Analyzed due to Interferences. I A-Analyte analyzed in replicate. Reported value is "average" of replicates. A-Presence or absence Of analyte can not be determined from data due to severe.quality control pn;>blems. Data are rejected ar,d considered unusable. --------------- - Page 1 of 1 - - - -Sample 3163 FY 2006 Project: 06-0266 Volatiles Scan Facility: Davis Park Rd Program: SF ld/Station:MW17 / Gastonia, NC Media: GROUNDWATER RESULTS UNITS ANALYTE 0.50 UJ UG/L Dichlorodifluoromethane 0.50 U UG/L Chloromethane 0.50 U UG/L 1, 1 ,2-Trichloro-1,2,2-T rifluoroethane (Freon 113) 0.50 U UG/L Methyl T-Butyl Ether (MTBE) 0.50 UJ UG/L Bromomethane 0.50 U UG/L Cyclohexane 0.50 U UG/L Vinyl Chloride 0.50 U UG/L Chloroethane 0.50 U UG/L Trichlorofluoromethane (Freon 11) 1.0 UG/L 1, 1-Dichloroethene (1, 1-Dichloroethylene) 0.50 U UG/L Methylene Chloride 2.0 U UG/L Acetone 0.50 U UG/L Carbon Disulfide 1.0U UG/L Methyl Acetate 0.50 U UG/L 1, 1-Dichloroethane 0.50 U UG/L cis-1,2-Dichloroethene 0.50 U UG/L 2,2-Dichloropropane 2.0 U UG/L Methyl Ethyl Ketone 0.50 U UG/L Bromochloromethane 0.50 U UG/L trans-1,2-Dichloroethene 0.50 U UG/L Chloroform 0.50 U UG/L 1,2-Dichloroethane 0.50 U UG/L 1, 1, 1-Trichloroethane 0.50 U UG/L 1, 1-Dichloropropene 0.50 U UG/L Carbon Tetrachloride 0.50 U UG/L Bromodichloromethane 2.0 U UG/L Methyl lsobutyl Ketone 0.50 U UG/L 1,2-Dichloropropane 0.50 U UG/L Methylcyclohexane 0.50 U UG/L Oibromomethane 0.50 U UG/L trans-1 ,3-Dichloropropene 13 UG/L Trichloroethene (Trichloroethylene) 0.50 U UG/L Benzene 0.50 U UG/L Dibromochloromethane 0.50 u. UG/L 1, 1,2-Trichloroethane Dichlorodifluoromethane & Bromomethane had low recovery in the CCV. Sample Received Unpreserved; Holding Time & all other Criteria Met! RESULTS 0.50 U 0.50 U 0.50 U 0.50 U 7.4 0.50 U 2.0 U 0.50 U 0.50 U 0.50 U 0.50 U 1.0 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U -Produced by: Hale, Sallie Requestor: Project Leader: JWENDEL Beginning: 02/07/2006 14:15 Ending: UNITS ANALYTE UG/L cis-1,3-Dichloropropene UG/L Bromoform UG/L Bromobenzene UG/L 1 , 1,2,2-Tetrachloroethane UG/L T etrachloroethene (T etrachloroethylene) UG/L 1,3-Dichloropropane UG/L Methyl Butyl Ketone UG/L Toluene UG/L Chlorobenzene UG/L 1, 1, 1,2-Tetrachloroethane UG/L Ethyl Benzene UG/L (m-and/or p-)Xylene UG/L a-Xylene UG/L Styrene UG/L 1,2,3-Trichloropropane UG/L o-Chlorotoluene UG/L p-Chlorotoluene UG/L 1,3-Dichlorobenzene UG/L 1,4-Dichlorobenzene UG/L 1,2-Dichlorobenzene UG/L 1,2-Dibromoethane (EDS) UG/L lsopropylbenzene UG/L n-Propylbenzene UG/L 1,3,5-Trimethylbenzene UG/L tert-Butylbenzene UG/L 1,2,4-Trimethylbenzene UG/L sec-Butylbenzene UG/L p-lsopropyltoluene UG/L n-Butylbenzene UG/L 1,2-Dibromo-3-Chloropropane (DBCP) UG/L 1,2,4-Trichlorobenzene UG/L Hexachloro-1,3-Butadiene UG/L 1,2,3-Trichlorobenzene U-Analyte not detected at or above reporting limit. I J-ldentification of analyte is acceptable; reported value is an estimate. I UJ-Analyte not detected at or above reporting limit. Reporting limit is an estimate. N-Presumptive evidence anatyte is present; analyte reported as tentative identification. I NJ-Presumptive evidence analyte is present; analyte reported as tentative identification. Reported value is an estimate. K-ldentification of analyte is acceptable; reported value may be biased high. Actual value expected to be less than the reported value. L-ldentification of analyte is acceptable; reported value may be biased low. Actual value expected to be greater than reported value. NA-Not Analyzed. I NAI-Not Analyzed due to Interferences. I A-Analyte analyzed in replicate. Reported value is ·average" of replicates. A-Presence or absence of analyte can not be determined from data due to severe quality control problems. Data are rejected and considered unusable. Page 1 of 1 VOLATILES SAMPLE ANALYSIS EPA -REGION IV SESD, ATHENS, GA Production Date: 03/24/2006 16:14 Sample 3164 FY 2006 Project: 06-0266 Volatiles Scan Facility: Davis Park Rd Program: SF Gastonia, NC Id/Station: MW 18 / Media: GROUNDWATER RESULTS UNITS ANALYTE 0.50 UJ UG/L Dichlorodifluoromethane 0.50 U UG/L Chloromethane 0.50 U UG/L 1, 1,2-T richloro"-1 ,2,2-Trifluoroethane (Freon 113) 0.50 U UG/L Methyl T-Butyl Ether (MTBE) 0.50 UJ UG/L Bromomethane 0.50 U UG/L Cyclohexane 0.50 U UG/L Vinyl Chloride 0.50 U UG/L Chloroethane 0.50 U UG/L Trichlorofluoromethane (Freon 11) 0.50 U UG/L 1, 1-Dichloroethene (1, 1-Dichloroethylene) 0.50 U UG/L Methylene Chloride 2.0 U UG/L Acetone 0.50 U UG/L Carbon Disulfide 1.0 U UG/L Methyl Acetate 0.50 U UG/L 1, 1-Dichloroethane 0.50 U UG/L cis-1,2-Dichloroethene 0.50 U UG/L 2,2-Dichloropropane 2.0 U UG/L Methyl Ethyl Ketone 0.50 U UG/L Bromochloromethane 0.50 U UG/L trans-1,2-Dichloroethene 0.50 U UG/L Chloroform 0.50 U UG/L 1,2-Dichloroethane 0.50 U UG/L 1 , 1, 1-T richloroethane 0.50 U UG/L 1 , 1-Dichloropropene 0.50 U UG/L Carbon Tetrachloride 0.50 U UG/L Bromodichloromethane 2.0 U UG/L Methyl lsobutyl Ketone 0.50 U UG/L 1,2-Dichloropropane 0.50 U UG/L Methylcyclohexane 0.50 U UG/L Dibromomethane 0.50 U UG/L trans-1,3-Dichloropropene 2.0 UG/L Trichloroethene (Trichloroethylene) 0.50 U UG/L Benzene 0.50 U UG/L Dibromochloromethane 0.50 U UG/L 1, 1,2-Trichloroethane Dichlorodifluoromethane & Bromomethane had low recovery in the CCV. Sample Received Unpreserved; Holding Time & all other Criteria Met! RESULTS 0.50 U 0.50 U 0.50 U 0.50 U 4.2 0.50 U 2.0 U 0.50 U 0.50 U 0.50 U 0.50 U 1.0 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U Produced by: Hale, Sallie Requestor: Project Leader: JWENDEL Beginning: 02/07/2006 14:50 Ending: UNITS ANALYTE UG/L cis-1,3-Dichloropropene UG/L Bromoform UG/L Bromobenzene UG/L 1 , 1,2,2-T etrachloroethane UG/L Tetrachloroethene (Tetrachloroethylene) UG/L 1,3-Dichloropropane UG/L Methyl Butyl Ketone UG/L Toluene UG/L Chlorobenzene UG/L 1, 1, 1,2-Tetrachloroethane UG/L Ethyl Benzene UG/L (m-and/or p-)Xylene UG/L a-Xylene UG/L Styrene UG/L 1,2,3-Trichloropropane UG/L o-Chlorotoluene UG/L p-Chlorotoluene UG/L 1 ,3-Dichlorobenzene UG/L 1,4-Dichlorobenzene UG/L 1,2-Dichlorobenzene UG/L 1,2-Dibromoethane (EDB) UG/L lsopropylbenzene UG/L n-Propylbenzene UG/L 1,3,5-Trimethylbenzene UG/L tert-Butylbenzene UG/L 1,2,4-Trimethylbenzene UG/L sec-Butylbenzene UG/L p-lsopropyltoluene UG/L n-Butylbenzene UG/L 1,2-Dibromo-3-Chloropropane (DBCP) UG/L 1,2,4-Trichlorobenzene UG/L Hexachloro-1,3-Butadiene UG/L 1,2,3-Trichlorobenzene U-Analyte not detected at or above reporting limit. I J-ldentification of analyte is acceptable; reported value is an estimate. I UJ-Analyte not detected at or above reporting limit. Reporting limit is an estimate. N-Presumptive evidence analyte is present; analyte reported as tentative identification. I ·NJ-Presumptive evidence analyte is present; analyte reported as tentative identification. Reported value is an estimate. K-ldentification of analyte is acceptable; reported value may be biased high. Actual value expected to be less than the reported value. L-ldentification of analyte is acceptable; reported value may be biased low. Actual value expected to be greater than reported value. NA-Not Analyzed. I NAI-Not Analyzed due to lnterterences. I A-Analyte analyzed in replicate. Reported value is "averageH of replicates. A-Presence or absence of analyte can not be determined from data due to severe quality control problems. Data are rejected and considered unusable. ----------- - ----Page 1 of 1 - - - -Sample 3165 FY 2006 Project: 06-0266 Volatiles Scan Facility: Davis Park Rd Program: SF Gastonia, NC ld/Slation: MW 19 / Media: GROUNDWATER RESULTS 0.50 UJ 0.50 U 0.50 U 0.50 U 0.50 UJ 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 2.0 U 0.50 U 1.0 U 0.50 U 0.50 U 0.50 U 2.0 U 0.50 U 0.50 U 0.50 U · 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 2.0 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U UNITS UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L ANALYTE Dichlorodifluoromethane Chloromethane 1, 1,2-Trichloro-1,2,2-Trifluoroethane (Freon 113) Methyl T-Butyl Ether (MTBE) Bro mom ethane Cyclohexane Vinyl Chloride Chloroethane Trichlorofluoromethane (Freon 11) 1, 1-Dichloroethene (1, 1-Dichloroethylene) Melhylene Chloride Acetone Carbon Disulfide Methyl Acetate 1, 1-Dichloroelhane cis-1,2-Dichloroethene 2,2-Dichloropropane Methyl Ethyl Ketone Bromochloromethane trans-1,2-Dichloroethene Chloroform 1 ,2-Dichloroethane 1, 1, 1-Trichloroethane 1, 1-Dichloropropene Carbon Tetrachloride Bromodichloromethane Methyl lsobutyl Kelone 1,2-Dichloropropane Methylcyclohexane Dibromomethane trans-1,3-Dichloropropene Trichloroethene (Trichloroethylene) Benzene Dibromochloromethane 1, 1,2-Trichloroethane Dichlorodifluoromelhane & Bromomelhane had low recovery in the CCV. Sample Received Unpreserved; Holding Time & all other Criteria Met! RESULTS 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 2.0 U 0.50 U 0.50 U 0.50 U 0.50 U 1.0 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U -Produced by: Hale, Sallie Requestor: Project Leader: JW ENDEL Beginning: 02/07/2006 15:55 Ending: UNITS UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L ANALYTE cis-1,3-Dichloropropene Bromoform Bromobenzene 1, 1,2,2-Tetrachloroethane T etrachloroethene (T etrachloroethylene) 1 ,3-Dichloropropane Melhyl Butyl Ketone Toluene Chlorobenzene 1, 1, 1 ,2-Tetrachloroethane Ethyl Benzene (m-and/or p-)Xylene a-Xylene Styrene 1,2,3-Trichloropropane o-Chlorotoluene p-Chlorotoluene 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene 1,2-Dibromoelhane (EDB) lsopropylbenzene n-Propylbenzene 1,3,5-Trimethylbenzene tert-Butylbenzene 1,2,4-Trimethylbenzene sec-Butylbenzene p-lsopropyltoluene n-Butylbenzene 1,2-Dibromo-3-Chloropropane (DBCP) 1,2,4-Trichlorobenzene Hexachloro-1,3-Butadiene 1,2,3-Trichlorobenzene U-Analyte not detected at or above reporting limit. I J-ldentification of analyte is acceptable; reported value is an estimate. I UJ-Analyte not detected at or above reporting limit. Reporting limit is an estimate. N-Presumptive evidence analyte is present; analyte reported as tentative identification. I NJ-Presumptive evidence analyte is present; ana1yte reported as tentative identification. Reported value is an estimate. K-ldentification of analyte is acceptable; reported value may be biased high. Actual value expected to be less than the reported value. L-ldentification of analyte is acceptable; reported value may be biased low. Actual value expected to be greater than reported value. NA-Not Analyzed. f NAI-Not Analyzed due to Interferences. I A-Analyte analyzed in replicate. Reported value is ·average" of replicates. A-Presence or absence of analyte can not be determined from data due to severe quality control problems. Data are rejected and considered unusable. Page 1 of 1 VOLATILES SAMPLE ANALYSIS EPA -REGION IV SESD, ATHENS, GA Production Date: 03/24/2006 16:14 Sample 3166 FY 2006 Project: 06-0266 Volatiles Scan Facility: Davis Park Rd Program: SF Id/Station: MW 1 FB / Media: FIELD BLANK Gastonia, NC RESULTS UNITS ANALYTE 0.50 U UG/L Dichlorodifluoromethane 0.50 U UG/L Chloromethane 0.50 U UG/L 1, 1,2-Trichloro-1,2,2-Trifluoroethane (Freon 113) 0.50 U UG/L Methyl T-Butyl Ether (MTBE) 0.50 U UG/L Bromomethane 0.50 U UG/L Cyclohexane 0.50 U UG/L Vinyl Chloride 0.50 U UG/L Chloroethane 0.50 U UG/L Trichlorofluoromethane (Freon 11) 0.50 U UG/L 1, 1-Dichloroethene (1, 1-Dichloroethylene) 0.50 U UG/L Methylene Chloride 2.0 U UG/L Acetone 0.50 U UG/L Carbon Disulfide 1.0 U UG/L Methyl Acetate 0.50 U UG/L 1, 1-Dichloroethane 0.50 U UG/L cis-1,2-Dichloroethene 0.50 U UG/L 2,2-Dichloropropane 2.0 U UG/L Methyl Ethyl Ketone 0.50 U UG/L Bromochloromethane 0.50 U UG/L trans-1,2-Dichloroethene 0.50 U UG/L Chloroform 0.50 U UG/L 1,2-Dichloroethane 0.50 U UG/L 1, 1, 1-Trichloroethane 0.50 U UG/L 1, 1-Dichloropropene 0.50 U UG/L Carbon Tetrachloride 0.50 U UG/L Bromodichloromethane 2.0 U UG/L Methyl lsobutyl Ketone 0.50 U UG/L 1,2-Dichloropropane 0.50 U UG/L Methylcyclohexane 0.50 U UG/L Oibromomethane 0.50 U UG/L trans-1 ,3-Dichloropropene 0.50 U UG/L Trichloroethene (Trichloroethylene) 0.50 U UG/L Benzene 0.50 U UG/L Dibrom-ochloromethane 0.50 U UG/L 1, 1,2-Trichloroethane Sample Received Unpreserved; Holding Time & all other Criteria Met! RESULTS 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 2.0 U 0.50 U 0.50 U 0.50 U 0.50 U 1.0 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U Produced by: Hale, Sallie Requestor: Project Leader: JWENDEL Beginning: 02/08/2006 08:50 Ending: UNITS ANALYTE UG/L cis-1,3-Dichloropropene UG/L Bromoform UG/L Bromobenzene UG/L 1, 1,2,2-Tetrachloroethane UG/L T etrachloroethene (T etrachloroethylene) UG/L 1 ,3-Dichloropropane UG/L Methyl Butyl Ketone UG/L Toluene UG/L Chlorobenzene UG/L 1, 1, 1,2-Tetrachloroethane UG/L Ethyl Benzene UG/L (m-and/or p-)Xylene UG/L a-Xylene UG/L Styrene UG/L 1,2,3-T richloropropane UG/L o-Chlorotoluene UG/L p-Chlorotoluene UG/L 1 ,3-Dichlorobenzene UG/L 1,4-Dichlorobenzene UG/L 1,2-Dichlorobenzene UG/L 1,2-Dibromoethane (EDB) UG/L lsopropylbenzene UG/L n-Propylbenzene UG/L 1,3,5-T rimethylbenzene UG/L tert-Butylbenzene UG/L 1,2,4-Trimethylbenzene UG/L sec-Butylbenzene UG/L p-lsopropyltoluene UG/L n-Butylbenzene UG/L 1,2-Dibromo-3-Chloropropane (DBCP) UG/L 1,2,4-Trichlorobenzene UG/L Hexachloro-1,3-Butadiene UG/L 1,2,3-Trichlorobenzene U-Analyte not detected at or above reporting limit. I J-ldentification of analyte is acceptable; reported value is an estimate. I UJ-Analyte not detected at or above reporting limit. Reporting limit is an estimate. N-Presumptive evidence analyte is present; analyte reported as tentative identification. ! NJ-Presumptive evidence analyte is present; analyte reported as tentative identification. Reported value is an estimate. K-ldentification of analyte is acceptable; reported value may be biased high. Actual value expected to be less than the reported value. L-ldentification of anatyte is acceptable; reported value may be biased low. Actual value expected to be greater than reported value. NA-Not Analyzed. I NAI-Not Analyzed due to lnterlerences. I A-Analyte analyzed in replicate. Reported value is "average" of replicates. A-Presence or absence of analyte can not be determined from data due to severe quality control problems. Data are rejected and considered unusable. ----------------~~- -Sample 3167 FY 2006 Project: 06-0266 Volatiles Scan Facility: Davis Park Rd Program: SF Id/Station: MW1 RB/ Gastonia, NC Media: EQUIPMENT RINSE BLANK RESULTS UNITS ANALYTE 0.50 U UG/L Dichlorodifluoromethane 0.50 U UG/L Chlciromethane 0.50 U UG/L 1, 1,2-Trichloro-1,2,2-Trifluoroethane (Freon 113) 0.50 U UG/L Methyl T-Butyl Ether (MTBE) 0.50 U UG/L Bromomethane 0.50 U UG/L Cyclohexane 0.50 U UG/L Vinyl Chloride 0.50 U UG/L Chloroethane 0.50 U UG/L Trichlorofluoromethane (Freon 11) 0.50 U UG/L 1, 1-Dichloroethene (1, 1-Dichloroethylene) 0.50 U UG/L Methylene Chloride 2.0 U UG/L Acetone 0.50 U UG/L Carbon Disulfide 1.0 U UG/L Methyl Acetate 0.50 U UG/L 1 , 1-Dichloroethane 0.50 U UG/L cis-1,2-Dichloroethene 0.50 U UG/L 2,2-Dichloropropane 2.0 U UG/L Methyl Ethyl Ketone 0.50 U UG/L Bromochloromethane 0.50 U UG/L trans-1,2-Dichloroethene 0.50 U UG/L Chloroform 0.50 U UG/L 1,2-Dichloroethane 0.50 U UG/L 1 , 1, 1-Trichloroethane 0.50 U UG/L 1 , 1-Dichloropropene 0.50 U UG/L Carbon Tetrachloride 0.50 U UG/L Bromodichloromethane 2.0 U UG/L Methyl lsobutyl Ketone ·o.5o u UG/L 1,2-Dichloropropane 0.50 U UG/L Methylcyclohexane 0.50 U UG/L Dibromomethane 0.50 U UG/L trans-1,3-0ichloropropene 0.50 U UG/L Trichloroethane (Trichloroethylene) 0.50 U UG/L Benzene 0.50 U UG/L Dibromochloromethane 0.50 U UG/L 1, 1,2-Trichloroethane Sample Received Unpreserved; Holding Time & all other Criteria Met! RESULTS 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 2.0 U 0.50 U 0.50 U 0.50 U 0.50 U 1.0 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U -Produced by: Hale, Sallie Requestor: Project Leader: JWENDEL Beginning: 02/08/2006 08:45 Ending: UNITS. ANALYTE UG/L cis-1,3-Dichloropropene UG/L Bromoform .UG/L Bromobenzene UG/L 1, 1,2,2-T etrachloroethane UG/L T etrachloroethene (T etrachloroethylene) UG/L 1,3-Dichloropropane UG/L Methyl Butyl Ketone UG/L Toluene UG/L Chlorobenzene UG/L 1, 1, 1,2-Tetrachloroethane UG/L Ethyl Benzene UG/L (m-and/or p-)Xylene UG/L a-Xylene UG/L Styrene UG/L 1,2,3-Trichloropropane UG/L o-Chlorotoluene UG/L p-Chlorotoluene UG/L 1,3-Dichlorobenzene UG/L 1 ,4-Dichlorobenzene UG/L 1 ,2-Dichlorobenzene UG/L 1,2-Dibromoethane (EDB) UG/L lsopropylbenzene UG/L n-Propylbenzene UG/L 1,3,5-Trimethylbenzene UG/L tert-Butylbenzene UG/L 1,2,4-Trimethylbenzene UG/L sec-Butylbenzene UG/L p-lsopropyltoluene UG/L n-Butylbenzene UG/L 1,2-Dibromo-3-Chloropropane (DBCP) UG/L 1,2,4-Trichlorobenzene UG/L Hexachloro-1,3-Butadiene UG/L 1,2,3-Trichlorobenzene U-Analyte not detected at or above reporting limit. I J-ldentification of analyte is acceptable; reported value is an estimate. I UJ-Analyte not detected at or above reporting limit. Reporting limit is an estimate. N-Presumptive evidence analyte is present; anatyte reported as tentative identification. I NJ-Presumptive evidence analyte is present; analyte reported as tentative identification. Reported value is an estimate. K-ldentification of analyte is acceptable; reported value may be_ biased high. Actual value expected to be less than the reported value. L-ldentification of analyte is acceptable; reported value may be biased low. Actual value expected to be greater than reported value. NA-Not Analyzed. I NAl-Not Analyzed due to Interferences. I A-Anatyte analyzed in replicate. Reported value is "average" of replicates. A-Presence or absence of analyte can not be determined from data due to severe quality control problems. Data are rejected and considered unusable. Page 1 of 1 VOLATILES SAMPLE ANALYSIS EPA-REGION IV SESD, ATHENS, GA Production Date: 03/24/200616:14 Sample 3168 FY 2006 Project: 06-0266 Volatiles Scan Facility: Davis Park Rd Program: SF Gastonia, NC Id/Station: MW20 / Media: GROUNDWATER RESULTS UNITS ANALYTE 0.50 UJ UG/L Dichlorodifluoromethane 0.50 U UG/L Chloromethane 0.50 U UG/L 1, 1,2-Trichloro-1,2,2-Trifluoroethane (Freon 113) 99 UG/L Methyl T-Butyl Ether (MTBE) 0.50 UJ UG/L Bromomethane 0.81 UG/L Cyclohexane 0.50 U UG/L Vinyl Chloride 0.50 U UG/L Chloroethane 0.50 U UG/L Trichlorofluoromethane (Freon 11) 0.50 U UG/L 1, 1-Dichloroethene (1, 1-Dichloroethylene) 0.50 U UG/L Methylene Chloride 2.0 U UG/L Acetone 0.50 U UG/L Carbon Disulfide 1.0 U UG/L Methyl Acetate 0.50 U UG/L 1, 1-Dichloroethane 0.50 U UG/L cis-1,2-Dichloroethene 0.50 U UG/L 2,2-Dichloropropane 2.0 U UG/L Methyl Ethyl Ketone 0.50 U UG/L Bromochloromethane 0.50 U UG/L trans-1 ,2-0ichloroethene 0.50 U UG/L Chloroform 0.50 U UG/L 1 ,2-Dichloroethane 0.50 U UG/L 1 , 1, 1-Trichloroethane 0.50 U UG/L 1, 1-Dichloropropene 0.50 U UG/L Carbon Tetrachloride 0.50 U UG/L Bromodichloromethane 2.0 U UG/L Methyl lsobutyl Ketone 0.50 U UG/L 1,2-Dichloropropane 0.50 U UG/L Methylcyclohexane 0.50 U UG/L Dibromomethane 0.50 U UG/L trans-1 ,3-Dichloropropene 0.50 U UG/L Trichloroethane (Trichloroethylene) 0.50 U UG/L Ber:izene 0.50 U UG/L Dibromoch1oromethane 0.50 U UG/L 1, 1,2-Trichloroethane Dichlorodifluoromethane & Bromomethane had low recovery in the CCV. Sample Received Unpreserved; Holding Time & all other Criteria Met! RESULTS 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 2.0 U 0.50 U 0.50 U 0.50 U 1.7 1.0 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U Produced by: Hale, Sallie Requester: Project Leader: JWENDEL Beginning: 02/08/2006 11 :00 Ending: UNITS ANALYTE UG/L cis-1,3-Dichloropropene UG/L Bromoform UG/L Bromobenzene UG/L 1, 1,2,2-Tetrachloroethane UG/L Tetrachloroethene (Telrachloroethylene) UG/L 1,3-Dichloropropane UG/L Methyl Butyl Ketone UG/L Toluene UG/L Chlorobenzene UG/L 1, 1, 1,2-Tetrachloroethane UG/L Ethyl Benzene UG/L (m-and/or p-)Xylene UG/L a-Xylene UG/L Styrene UG/L 1,2,3-Trichloropropane UG/L o-Chlorotoluene UG/L p-Chlorotoluene . UG/L 1,3-Dichlorobenzene UG/L 1,4-Dichlorobenzene UG/L 1,2-Dichlorobenzene UG/L 1,2-Dibromoethane (EDB) UG/L lsopropylbenzene UG/L n-Propylbenzene UG/L 1,3,5-Trimethylbenzene UG/L tert-Butylbenzene UG/L 1,2,4-Trimethylbenzene UG/L sec-Butylbenzene UG/L p-lsopropyltoluene UG/L n-Butylbenzene UG/L 1,2-Dibromo-3-Chloropropane (DBCP) UG/L 1,2,4-Trichlorobenzene UG/L Hexachloro-1 ,3-Butadiene UG/L 1,2,3-Trichlorobenzene U-Analyte not detected at or above reporting limit. I J-ldentification of analyte is acceptable; reported value is an estimate. UJ-Analyte not detected at or above reporting limit. Reporting limit is an estimate. N-Presumptive evidence analyte is present; analyte reported as tentative identification. I NJ·Presumptive evidence analyte is present; analyte reported as tentative identification. Reported value is an estimate. K·ldentification of analyte is acceptable; reported value may be biased high. Actual value expected to be less than the reported value. L·ldentification of analyte is acceptable; reported value may be biased low. Actual value expected to be greater than reported value. NA•Not Analyzed. I NAl·Not Analyzed due to Interferences. I A·Analyte analyzed in replicate. Reported value is "average" of replicates. R·Presence or absence of analyte can not be determined from data due to severe quality control problems. Data are rejected and considered unusable. ----------- - -- --Page 1 of 1 - - - --E~EG.._,S.AT~,GJJIII -Sample 3169 FY 2006 Project: 06-0266 Volatiles Scan Facility: Davis Park Rd Program: SF · Gastonia, NC Id/Station: MW21 / Media: GROUNDWATER RESULTS 0.50 UJ 0.50 UJ 0.50 UJ 0.50 UJ 0.50 UJ 0.50 UJ 0.50 UJ 0.50 UJ 0.50 UJ 0.50 UJ 0.50 UJ 27 AJ 0.50 UJ 1.0 UJ 0.50 UJ 0.50 UJ 0.50 UJ 7.7 AJ 0.50 UJ 0.50 UJ 0.50 UJ 0.50 UJ 0.50 UJ 0.50 UJ 0.50 UJ 0.50 UJ 2.0 UJ 0.50 UJ 0.50 UJ 0.50 UJ 0.50 UJ 0.50 UJ 0.50 UJ 0.50 UJ 0.50 UJ UNITS UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L ANALYTE Dichlorodifluoromethane Chloromethane 1, 1,2-Trichloro-1,2,2-Trifluoroethane (Freon 113) Methyl T-Butyl Ether (MTBE) Bromomethane Cyclohexane Vinyl Chloride Chloroethane Trichlorofluoromethane (Freon 11) 1, 1-Dichloroethene (1, 1-Dichloroethylene) Methylene Chloride Acetone Carbon Disulfide Methyl Acetate 1, 1-Dichloroethane cis-1,2-Dichloroethene 2,2-Dichloropropane Methyl Ethyl Ketone Bromochloromethane trans-1,2-Dichloroethene Chloroform 1,2-Dichloroethane 1, 1, 1-Trichloroethane 1, 1-Dichloropropene Carbon Tetrachloride Bromodichloromethane Methyl lsobutyl Ketone 1,2-Dichloropropane Methylcyclohexane Dibromomethane trans-1,3-Dichloropropene Trichloroethane (Trichloroethylene) Benzene Dibromochloromethane 1, 1,2-Trichloroethane J qualification due to failing surrogate recoveries on two separate runs. Results were averaged. RESULTS 0.50 UJ 0.50 UJ 0.50 UJ 0.50 UJ 0.50 UJ 0.50 UJ 2.0 UJ 0.50 UJ 0.50 UJ 0.50 UJ 0.92 AJ 1.0 UJ 0.50 UJ 0.50 UJ 0.50 UJ 0.50 UJ 0.50 UJ 0.50 UJ 0.50 UJ 0.50 UJ 0.50 UJ 0.50 UJ 0.50 UJ 0.50 UJ 0.50 UJ 0.50 UJ 0.50 UJ 0.50 UJ 0.50 UJ 0.50 UJ 0.50 UJ 0.50 UJ 0.50 UJ Produced by: Hale, Sallie Requester: Project Leader: JWENDEL Beginning: 02/08/2006 11 :30 Ending: UNITS UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L ANALYTE cis-1,3-Dichloropropene Bromoform Bromobenzene 1, 1,2,2-Tetrachloroethane T etrachloroethene (T etrachloroethylene) 1,3-Dichloropropane Methyl Butyl Ketone Toluene Chlorobenzene 1, 1, 1,2-T etrachloroethane Ethyl Benzene (m-and/or p-)Xylene o-Xylene Styrene 1,2,3-Trichloropropane o-Chlorotoluene p-Chlorotoluene 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-0ichlorobenzene 1,2-Dibromoethane (EDB) lsopropylbenzene n-Propylbenzene 1,3,5-Trimethylbenzene tert-Butylbenzene 1,2,4-Trimethylbenzene sec-Butylbenzene p-lsopropyltoluene n-Butylbenzene 1,2-Dibromo-3-Chloropropane (DBCP) 1,2,4-Trichlorobenzene Hexachloro-1,3-Butadiene 1,2,3-Trichlorobenzene Sample Received Unpreserved; HoldinQ Time & all other Criteria Met! U-Analyte not detected at or above reporting limit. I J-ldentification of analyte is acceptable; reported value is an estimate. I UJ-Anatyte not detected at or above reporting limit. Reporting limit is an estimate. N-Presumptive evidence analyte is present; analyte reported as tentative identification. I NJ-Presumptive evidence analyte is present; analyte reported as tentative identification. Reported value is an estimate. K-ldentification of analyte is acceptable; reported value may be biased high. Actual value expected to be less than the reported value. L-ldentification of analyte is acceptable; reported value may be biased low. Actual value expected to be greater than reported value. NA-Not Analyzed. I NAI-Not Analyzed due to lnterierences. ] A-Analyte analyzed in replicate. Reported value is "average" of replicates. A-Presence or absence of analyte can not be determined from data due to severe quality control problems. Data are rejected and considered unusable. Page 1 of 1 VOLATILES SAMPLE ANALYSIS EPA -REGION IV SESD, ATHENS, GA Production Date: 03/24/200616:14 Sample 3170 FY 2006 Project: 06-0266 Volatiles Scan Facility: Davis Park Rd Program: SF Id/Station: TB1 / Gastonia, NC Media:TRIP BLANK -WATER RESULTS UNITS ANALYTE 0.50 U UG/L Dichlorodifluoromethane 0.50 U UG/L Chloromethane 0.50 U UG/L 1, 1,2-Trichloro-1,2,2-Trifluoroethane (Freon 113) 0.50 U UG/L Methyl T-Butyl Ether (MTBE) 0.50 U UG/L Bromomethane 0.50 U UG/L Cyclohexane 0.50 U UG/L Vinyl Chloride 0.50 U UG/L Chloroethane 0.50 U UG/L Trichlorofluoromethane (Freon 11) 0.50 U UG/L 1, 1-Dichloroethene (1, 1-Dichloroethylene) 0.50 U UG/L Methylene Chloride 2.0 U UG/L Acetone 0.50 U UG/L Carbon Disulfide 1.0 U UG/L Methyl Acetate 0.50 U UG/L 1, 1-Dichloroethane 0.50 U UG/L cis-1,2-Dichloroethene 0.50 U UG/L 2,2-Dichloropropane 2.0 U UG/L Methyl Ethyl Ketone 0.50 U UG/L Bromochloromethane 0.50 U UG/L trans-1,2-Dichloroethene 0.50 U UG/L Chloroform 0.50 U UG/L 1,2-Dichloroethane 0.50 U UG/L 1, 1, 1-Trichloroethane 0.50 U UG/L 1, 1-Dichloropropene 0.50 U UG/L Carbon Tetrachloride 0.50 U UG/L Bromodichloromethane 2.0 U UG/L Methyl lsobutyl Ketone 0.50 U UG/L 1,2-Dichloropropane 0.50 U UG/L Methylcyclohexane 0.50 U UG/L Dibromomethane 0.50 U UG/L trans-1,3-Dichloropropene 0.50 U UG/L Trichloroethene (Trichloroethylene) 0.50 U UG/L Benzene 0.50 U UG/L Oibromochloromethane 0.50 U UG/L 1, 1,2-Trichloroethane Sample Received Unpreserved; Holding Time & all other Criteria Met! RESULTS 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 2.0 U 0.50 U 0.50 U 0.50 U 0.50 U 1.0 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U Produced by: Hale, Sallie Requestor: Project Leader: JWENDEL Beginning: 02/07/2006 08:05 Ending: UNITS ANALYTE UG/L cis-1 ,3-Dichloropropene UG/L Bromoform UG/L Bromobenzene UG/L 1, 1,2,2-T etrachloroethane UG/L T etrachloroethene (T etrachloroethylene) UG/L 1 ,3-Dichloropropane UG/L Methyl Butyl Ketone UG/L Toluene UG/L Chlorobenzene UG/L 1, 1, 1,2-Tetrachloroethane UG/L Ethyl Benzene UG/L (m-and/or p-)Xylene UG/L a-Xylene UG/L Styrene UG/L 1,2,3-Trichloropropane UG/L o-Chlorotoluene UG/L p-Chlorotoluene UG/L 1,3-Dichlorobenzene UG/L 1 .4-Dichlorobenzene UG/L 1,2-Dichlorobenzene UG/L 1,2-Dibromoethane (EDB) UG/L lsopropylbenzene UG/L n-Propylbenzene UG/L 1,3,5-Trimethylbenzene UG/L tert-Butylbenzene UG/L 1,2,4-Trimethylbenzene UG/L sec-Butyl benzene UG/L p-lsopropyltoluene UG/L n-Butylbenzene UG/L 1,2-Dibromo-3-Chloropropane (DBCP) UG/L 1,2,4-Trichlorobenzene UG/L Hexachloro-1,3-Butadiene UG/L 1,2,3-Trichlorobenzene U-Analyte not detected at or above reporting limit. I J-ldentification of analyte is acceptable; reported value is an estimate. I UJ-Analyte not detected at or above reporting limit. Reporting limit ls 8.n estimate. N-Presumptive evidence analyte is present; analyte reported as tentative identification. I NJ-Presumptive evidence analyte is present; analyte reported as tentative identification. Reported value is an estimate. K-ldentification of analyte is acceptable; reported value may be biased high. Actual value expected to be less than the reported value. L-ldentification of analyte is acceptable; reported value may be biased low. Actual value expected to be greater than reported value. NA-Not Analyzed. ] NAI-Not Analyzed due to lnterierences. I A-Analyte analyzed in replicate. Reported value is "average" of replicates. A-Presence or absence of analyte can not be determined from data due to severe quality control problems. Data are rejected and considered unusable. ------------ - ---Page 1 of 1 - - -