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HomeMy WebLinkAboutNCD981023260_19900718_Potters Septic Tank Service Pits_FRBCERCLA SPD_Preliminary Health Assessment-OCR1. \ I I I I I I I I I I I I I I I I I I .. PRELl'MINARY .Health . Assessment for POTTER'S SEPTIC TANK SERVICE PITS MACO, BRUNSWICK COUNTY, NORTH CAROLINA CERCLIS NO. NCD981O2326O JUL 18 1990 U.S. DEPARTMENT OF lHEAlLT!H AND !HUMAN SERVlICE§ PUBLIC HEALTH SERVICE Agency for Toxic Substances and Disease Registry -------------------------------------------------- THE A TSDR HEAL TII ASSESSMENT: A NOTE OF EXPLANATION Section 104 (i) (7) (A) of the Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA), as amended, states " ... the term 'health assessment' shall include preliminary assessments of potential risks to human health posed by individual sites and facilities, based on such factors as the nature and extent of contamination, the existence of potential pathways of human exposure (including ground or surface water contamination, air emissions, and food chain contamination), the size and potential susceptibility of the community within the likely pathways of exposure, the comparison of expected human exposure levels to the short-term and long-term health effects associated with identified hazardous substances and any available recommended exposure or tolerance limits for such hazardous substances, and the comparison of existing morbidity and mortality data on diseases that may be associated with the observed levels of exposure. The Administrator of ATSDR shall use appropriate data, risks assessments, risk evaluations and studies available from the Administrator of EPA." In accordance with the CERCLA section cited, A TSDR has conducted this preliminary health assessment on the data in the site summary form. Additional health assessments may be conducted for this site as more information becomes available to ATSDR. Use of trade names is for identification only and does not constitute endorsement by the Public Health Service or the U.S. Department of Health and Human Services. .1 I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I In May 1976, the North Carolina Department of Natural Resources (NCDNR) notified the owner of the three waste hauling companies that the oil disposal pit in Area 2 violated North Carolina statutes and must be cleaned up. The pit, which was approximately 60 feet long, 20 feet wide, and 2 to 4 feet deep, contained approximately 2,000 to 3,000 gallons of waste oil. The owner pumped the oil from the pit and covered the pit with soil. The composition of the oil, its ultimate fate, and the characteristics of the soil or sludge buried on site are unknown. Soil-gas sampling has been conducted in Area 2. Results were negative, suggesting that, if there was once contamination in this area, the cleanup must have effectively removed most, if not all, of the contamination. This area is not now considered to be part of the NPL site. Soil-gas and soil sampling were recently performed in Area 3. The soil-gas samples were unremarkable. If the soil samples reveal similar results, Area 3 will not receive further consideration as part of this NPL site. In August 1976, an earthen berm in Area 1 failed, and approximately 20,000 gallons of oil flowed into Chinnis Branch, a nearby stream. The contamination then flowed via Chinnis Branch to the Rattlesnake Branch. The U.S. Coast Guard was notified of the contamination of this Class C water body, and a cleanup was initiated. Due to ineffective cleanup methods, the oily contamination in the swampy areas of Rattlesnake Branch was left in place. An additional 20,000 gallons of oil remaining in the pit was pumped out and disposed of at Fort Bragg, North Carolina. Oil sludge also was removed from the pit, and transported to Brunswick County Landfill in Leland, North Carolina. Three other pits found in the area were similarly remediated. Thick sludge that could not be pumped out was mixed with sand and buried on site. About 1982, the property in and around the site was subdivided for residential property known as Sandy Creek Acres. At least three occupied residences are located on or near the site. In July 1983, after development of the subdivision, the owner of one of the lots found sludge in his front yard and informed the North Carolina Department of Human Resources (NCDHR). Subsequent investigation by NCDHR indicated that the residence appeared to be located over at least one of the former pits. The water well for this residence may have been sited through one of the pits. Water samples from this well were found to contain phenols, substituted benzenes, creosote and septic tank sludge. Subsequent sampling by NCDHR revealed these and other contaminants in soil near the surface. NCDHR advised the owner to discontinue use of the well. The residence reportedly is now supplied with water from the well of a residence across the street. The well purportedly is upgradient. Page 2 I I I I I I I I I I I I I I I I I I In September 1983 and February 1984, EPA's Office of Emergency Response conducted various site investigations--collecting air, subsurface soil, surface water, and groundwater samples, and evaluating the magnitude of the buried wastes. On March 9, 1984, ATSDR certified to EPA that the site represented a threat to hwnan health and warranted immediate cleanup. Subsequently, EPA initiated an immediate removal action that centered around the residential property initially reporting contamination. Two areas were excavated to various depths, and 1,770 tons of oily sludges and contaminated soils were removed. The areas were refiiled with clean soil, then graded and seeded. In May 1984, a groundwater study, of 12 wells determined that the shallow aquifer was contaminated with various organic chemicals; but the deep aquifer had not been impacted. In a groundwater monitoring program recommended by EPA, NCDHR confirmed the shallow aquifer contamination in May 1988. This more recent data indicated the possibility that the deep aquifer had become contaminated. The site is in a mostly forested area, except for that land cleared for residential housing. Each house has a private domestic water well. The area is primarily flat, lying in the coastal plain. Significant surface water bodies nearby are: Chinnis Branch, Little Green Swamp (the headwaters for Chinnis Branch, west of the site), and Rattlesnake Branch (northeast of the site). Hood Creek receives water from Rattlesnake Branch, and then flows northeast into the Cape Fear River, which flows into the Atlantic River. The site maps in the Appendix show these relationships. Groundwater in the shallow aquifer is believed to flow in a variable but generally east-southeast direction. Groundwater in the deep aquifer is believed to flow in a north-northeast direction. B. SITE VISIT A site visit was performed by representatives of ATSDR on March 15, 1989. Land use in the site vicinity is residential, with mobile homes and single family residences. Access to the site is unrestricted. The surface grasses and ground cover are typical of residential lot. Private wells provide drinking water for residential use. C. COMMUNITY HEALTH CONCERNS On February 28, 1990, regarding this site. following topics were ATSDR representatives attended a community meeting Approximately 78 people were in attendance. The discussed. 1. 2. Long-term health effects of benzene and other voes. What carcinogenic chemicals are found at the site. Page 3 I I I I I I I I I I I I I I I I I I I 3. 4. Tests of the drinking water used by the residents living near the site. Installation of an alternative water supply. DEMOGRAPHICS, LAND USE, AND NATURAL RESOURCE USE The site's disposal areas are located in a rural section of Brunswick County called Sandy Creek Acres, approximately one mile west of Maco (population unknown). Approximately 1,000 people living within 3 miles of the three areas are dependent upon groundwater for water supplies. Most.if not all. local residential wells tap the deep aquifer, which apparently is separated from the shallow aquifer by a continuous clay layer. The shallow aquifer is estimated to be 10 to 12 feet thick and 5 to 17 feet below land surface. There are no municipal water systems for Maco or the area of Brunswick County surrounding Maco. ENVIRONMENTAL CONTAMINATION AND OTHER HAZARDS A. ON-SITE CONTAMINATION Heavy metals, volatile organic compounds (VOCs), and polynuclear aromatic hydrocarbons (PAHs) have been detected in groundwater, sediment, surface water, and soil at the site. The following tables highlight the documented chemical contamination, the media in which the contamination was measured, and the maximum concentrations reported. Sampling data are available for 1983, 1984, and 1988. Some of the data un individual compounds were estimated values and are not listed here. Results of heavy metal analyses from 1984 and 1988 were unremarkable. Substances other than those listed in the following tables were detected at this site. However, those chemicals will not be considered further in this preliminary health assessment for one or more of the following reasons: the chemicals were detected in very few samples; the chemicals were detected in limited areas; the chemicals concentrations were low relative to levels considered to be of public health importance; the chemical concentrations were low relative to typical background concentrations; or the chemicals were detected in low concentration and had similar environmental fate and transport characteristics to other evaluated chemicals. Page 4 I I I I I I I: I I I I I Table 1 ON-SITE CONTAMINATION POTTER'S SEPTIC TANK SERVICE PITS SITE Contaminant benzene toluene total xylenes lead arsenic zinc total PAHs total PAHs benzene toluene total xylenes benzene toluene: _ total xylenes ethylbenzene B.. -OFF-SITE CONTAMINATION Medium Max. Cone. i££IB1 1983 Data groundwater 1.3 6.6 21 0.24 0.01 11 0.79 subsurface soil 45 1983 Data groundwater 1988 Data g"t"oundwater 10 35 23 7 .4 77 25.3 4. 6 The only samples that will be considered "off-site" are two private well samples, three EPA monitoring well samples, and two surface water ·and sediment samples from Chinnis Branch. The locations are .depicted in Site Map 2. _These samples presumably would. indicate if contaminants have migrated from the immediate disposal areas. The-s·e· rePortetj results for benzene, toluene, and total xylenes are summarized in the table below. Page 5 I I I I I I I I I I I I I I I I I I I Table 2 OFF-SITE CONTAMINATION POTTER'S SEPTIC TANK SERVICE PITS SITE Contaminant Medium Max. Cone. (ppm) 1983 Data No concentrations of public health significance. total xylenes 1984 Data groundwater 1988 Data 0.65 No concentrations of public health significance. C. QUALITY ASSURANCE AND QUALITY CONTROL The analytical data regarding extractable organic material often were estimated, presumptive, or average values. Such data were not used. Detection limits for analytical methods were not indicated. It is assumed that the data provided for this Preliminary Health Assessment were collected and analyzed according to standard methodology, and in the absence of definitive information regarding these procedures, are acceptable for the purpose of Preliminary Health Assessment. D. PHYSICAL AND OTHER HAZARDS No physical hazards were identified at the site. PATHWAYS ANALYSES A. ENVIRONMENTAL PATHWAYS (FATE and TRANSPORT) The environmental pathways of concern at the site are: contaminated groundwater, surface water, sediment, surface and subsurface soil, and air. Groundwater has been shown to contain high concentrations of hazardous substances. Benzene, toluene, ethylbenzene, and xylene, arsenic, lead, and PAHs (several polynuclear aromatic hydrocarbons of varying degrees of toxicity are grouped and referred to as total PAHs) have been measured in groundwater and subsurface soil. Data since 1984 were collected after an emergency removal operation took place, and suggests that a considerable reservoir of contamination remains. Page 6 I I I I I I I I I I I I I I I I I I Due to the removal action, contaminated surface soil may no longer exist; however, this has not been confirmed by sampling. Unless substantial surface soil contamination is present, airborne contamination by V0Cs or contaminated particulates is unlikely. Based on the most recent groundwater sampling, subsurface soil contamination is believed to be present. Asswning that the shallow groundwater flow is south-southeast, the potential exists for contamination of Chinnis Branch and joining surface water bodies. The VOCs detected are soluble in water (solubilities range from 198 to 515 mg/L), so solution from soil to groundwater can occur. This transport phenomenon can be retarded by soil with a high organic content. The log octanol/water coefficients measure of tendency to partition between organic and inorganic media--range from 2.79 to 3.26. Volatilization from surface water or surface soil can occur. Vapor pressures of these VOCs range from 10 to 22 millimeters of mercury at 20 degrees Centigrade). Soluble forms of arsenic tend to be very mobile in water, while less soluble forms tend to adsorb to soil particles and migrate according to surface water and groundwater movements. Acidity (pH) is important with respect to arsenic leaching from soil, with higher acidity soils tending to retain arsenic to a greater extent. Transformation (such as methylation) to organic forms will cause release back to the water column. Methylation and reduction by soil and water microorganisms increases the volatilization of arsenic from these media, so arsenic may be released to the atmosphere. Bioconcentration occurs in aquatic organisms, primarily algae and lower invertebrates. Biomagnification of arsenic in aquatic food chains does not appear to be significant. Some plants can accumulate arsenic via root uptake. Lead is transferred continuously between air, water, and soil by natural chemical processes such as weathering, runoff, precipitation, dry deposition of dust, and stream or river flow; however, soil and sediments appear to be important sinks for lead, and very little is transported into surface water or groundwater. Many plants commonly take up lead from soil. Lead in aqueous solution may occur in many forms, however it has a tendency to form insoluble compounds with carbonate, hydroxide, and sulfide. The amount of lead remaining in water depends on the acidity of the water. Except for some shellfish such as mussels, lead does not appear to bioaccumulate significantly in most fish. Polynuclear aromatic hydrocarbons (PAHs) occur in the environment mostly as a result of man-induced incomplete combustion of organic material such as coal, oil, and wood. PAHs are primarily partitioned to soil and sediment and are very persistent in these media, with the main degradation mechanism being biodegradation. PAHs have low water solubilities and a high propensity for binding to organic or particulate matter. Aquatic organisms can assimilate PAHs readily; however, metabolism and excretion of PAHs by aquatic organisms is rapid. Page 7 I I I I I I I I I I I I I I I I I I In swnmary, groundwater and soil contamination are the environmental pathways of most concern. Surface water and soil will release most VOCs to the atmosphere. Some arsenic and lead may be retained by aqueous media, but most arsenic and lead is expected to adsorb to either soil or sediment. PAHs will be retained by the sediment or soil they contact. B. HUMAN EXPOSURE PATHWAYS The human exposure pathway of primary concern is conswnption of contaminated groundwater. In addition, inhalation of VOCs released from groundwater used for bathing, showering, and cooking also can be important pathways. Because of the removal operations that took place, dermal contact with contaminated groundwater and surface water, soil, and sediment, and ingestion of contaminated soil and sediment probably are less important pathways. PUBLIC HEALTH IMPLICATIONS The limited sampling information in Table 2 suggests that most of the contaminants present on site have not migrated off site in groundwater, sediment, surface water, or soil. However, this conclusion may be in error, since sample locations may be upgradient of the groundwater flow. The data from Table 1 indicates high concentrations of contaminants remained on site after the emergency removal. Heavy metal, PAH, and VOC contamination has been docwnented in groundwater at the site. Of these substances, benzene, arsenic, and PAHs have been shown to cause cancer. VOC contamination appears to be the most significant in terms of concentration. Using the maximum concentration measured, and assuming 2 and 1 liters (L) of water per day and a body weight of 70 and 20 kilograms for an adult and child, respectively, the potential public health impact of the individual contaminants can be estimated. Calculations using the assumptions noted above and the data in Tables 1 and 2 indicate that chronic conswnption of the groundwater may exceed the intake levels recommended by EPA for toluene, xylene, lead, zinc, and ethylbenzene. In addition, similar calculations for arsenic, benzene, and PAHs suggest that persons are at increased risk of developing cancer as a result of drinking this groundwater. CONCLUSIONS Based upon information reviewed, ATSDR has concluded that this site is of potential public health concern because of the risk to human health resulting from possible exposure to hazardous substances at concentration~ that may result in adverse human health effects. As noted in the Human Exposure Pathways Section above, hwnan exposure to heavy metals, PAHs, and VOCs may be occurring and may have occurred in the past via contaminated groundwater, surface water, soil, sediment, air, and the food chain. Page 8 I I I I I I I I I I I I I I I I I Off-site contamination has not been investigated. Our definition of off site was based on the suspected location of the waste pits. Shallow groundwater is suspected of flowing in the direction of Chinnis Branch, which would place the off-site well, surface water, and sediment samples in an upgradient location. Hence, these data may be useful in defining the upgradient contamination boundaries. The removal operation at the site was not evaluated for cleanup efficiency. The potential may exist for residents to come in contact with contaminated surface soil. Further environmental characterization and sampling of the site and impacted off-site areas during the Remedial Investigation and Feasibility Study (RI/FS) should be designed to address the environmental and human exposure pathways discussed above. When additional information and data become available, such material will form the basis for further assessment by ATSDR at a later date. RECOMMENDATIONS In accordance with the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) as amended, the Potter's Septic Tank Pits site has been evaluated for appropriate follow-up with respect to health effects studies. Since human exposure to on-site or off-site contaminants of significant public health concern may currently be occurring and may have occurred in the past, this site is being considered for follow-up studies. After consultation with Regional EPA staff and State and local health and environmental officials, the Epidemiology and Medicine Branch, Division of Health Studies, ATSDR, will determine if follow-up public health actions or studies are appropriate for this site. The following recommendations are offered: 1. Sample the deep aquifer underlying the site to determine if it has been affected by site contaminants. 2. Sample surface soil sampling to determine the efficiency of the removal effort. 3. Conriuct a sampling program for present residential wells. All new residential wells should be sampled before occupancy. A monitoring program may be necessary to prevent future contamination of wells initially judged to be acceptable. An alternate water supply should be identified should its use become necessary. 4. When indicated by public health needs, and as resources permit, the evaluation of additional relevant public health outcome data and community health concerns, if available, is recommended. Page 9 I I I I I I I I I I I I I I I I I I PREPARER OF THE REPORT Environmental and Health Assessor: Clifford L. Moseley Remedial Programs Branch Division of Health Assessment and Consultation ATSDR REGIONAL REPRESENTATIVE Regional Representative: Casimer Pietrosewicz Public Health Advisor Region IV Page 10 I I I I I I I I I I I I I I I I I I I REFERENCES The following documents were used by ATSDR to prepare this Preliminary Health Assessment. Further information made available after the development of this preliminary health assessment will be addressed in any subsequent health assessment. Ebasco Services Incorporated. Draft Work Plan, Potter's Pits Septic Tank Site. March 1989. Hazard Ranking System Package Scoresheet and Documentation. September 22, 1986. NUS Corporation. Pits. August 27, Sampling Investigation Report, Potter's Septic Tank 1985. Agency for Toxic Substances and Disease. Registry. dated march 12, 1984, concerning emergency cleanup Site. Memorandum to EPA, of Potter's Pits CERCLA Agency for Toxic Substances and Disease Registry. Toxicological Profiles for various Polynuclear Aromatic Hydrocarbons. Atlanta, Georgia. In draft. Agency for Toxic Substances and Disease Registry. Toxicological Profile for Arsenic. Agency for Toxic Substances and Disease Registry Publication No. ATSDR/TP-88/02. Atlanta, Georgia. March 1989. Agency for for Lead. Toxic Substances and Disease Atlanta, Georgia. In draft. Registry. Toxicological Profile Agency for Toxic Substances and Disease Registry. Toxicological Profile for Benzene. Agency for Toxic Substances and Disease Registry Publication No. ATSDR/TP-88/03. May 1989. Agency for Toxic Substances and Disease Registry. Toxicological Profile for Toluene. Agency for Toxic Substances and Disease Registry Publication No. ATSDR/TP-89/23. December 1989. Agency for Toxic Substances and Disease Registry. for Zinc. Agency for Toxic Substances and Disease No. ATSDR/TP-89/25. December 1989. Page 11 Toxicological Profile Registry Publication I I I I I I I I I I I I I I I I I I APPENDIX Site Map 1, three areas of suspected waste disposal, Potters Proposed NPL Site. Site Map 2, suspected location of waste pits in Area 1, Potters Proposed NPL Site. Site Map 3, general location of site to major geographic features, Potters Proposed NPL Site. Page 12 - --- - - - - - - - - - - - - -,_ -- 1 ~ r'"'. /1 ~ ✓I/ ..,.,,/'::,,,~~\ ~ ~;:?)J \\~ ,,.,;:: ""··( ~~ .'\ ... t,~t' . . ,;,--:;-" . ~,k.<'!.cf;?", . /---··· .•·w ___ ... APPROX. SCALE 0 350 700 FEET -~ / LEGEND ===PAVED ROAD t I I I 1 1 I RAILROAD TRACKS - · -OLD ACCESS ROAD = = = = UNPAVED ROAD -···-STREAM :@J;@ STUDY AREA /.. ·----.. .•· / EA 2 SITE MAP 1 LOC<\TION OF THREE STUDY AREAS POi !ER'S SEPTIC TANK PITS SITE MACO, NOf:ITH CAROLINA ------------------- -----• • -.--. •• CHINIIIS ... --·. --·· PITS-<-"'-~. RESIDENCE--..___ CJ RESIDENCE --·-··- \ 6 c==sJ ===------- D RESIOEIICE SITE MAP 2 SAMPLE POINT LOCATIONS SEPTEMBER 6-9, 1983 1 1 -~-~"~ -~ktv, --- •WATER SAMPLE • ■ SOll/Sl'DIMEl<T SAMPLE NOT "lO SCALE ' POTTER'S SEPTIC TANK PITS SITE MACO, NORTH CAROLINA I I I I I I I I I I I I I I ' / QUAOA-'NC.lf. LOCA TLON ~\,J\t_f: IN F((T I _....,. 0 1000 2000. / / / SITE MAP 3 SITE LOCATION MAP POTTER'S SEPTIC TANK PITS SITE MACO, NORTH CAROLINA