Loading...
HomeMy WebLinkAboutNCD981021157_20051213_New Hanover County Airport Burn Pit_FRBCERCLA LTRA_Monitoring Report - November 2005 Sampling Event-OCRI I I I I I m g n 0 D u I I I I I I I . MONITORING REPORT NOVEMBER 2005 SAMPLING EVENT . NEW HANOVER COUNTY AIRPORT BURN PIT SUPERFUND SITE WILMINGTON, NORTH CAROLINA DECEMBER 13, 2005 PREPARED FOR: NEW HANOVER COUNTY, THE CITY OF WILMINGTON AND CAPE FEAR COMMUNITY COLLEGE WILMINGTON, NORTH CAROLINA CATLIN PROJECT NO. 194-040 PREPARED BY: CATLIN ENGINEERS AND SCIENTISTS P. 0. BOX 10279 WILMINGTON, NORTH CAROLINA 28404-0279 (910) 452-5861 I I I I I I m 0 u I I I I I I I I I I TABLE OF CONTENTS PAGE LIST OF ACRONYMS 1.0 PURPOSE 2.0 SITE GROUNDWATER MONITORING WELLS 3.0 · SITE MONITORING PLAN 4.0 SITE ACTIVE REMEDIATION ACTIVITIES 4:1 PULSE AIR SPARGE (PAS) 4.1.1 Pulse Air Sparge Description 4.1.2 Performance 5.0 SUMMARY OF SURFICIAL GROUNDWATER TABLE DATA 6.0 SUMMARY OF GROUNDWATER QUALITY TESTING 6.1 . 6.2 6.3 . FIEW MEASUREMENT (DISSOLVED OXYGEN) GROUNDWATER SAMPLING GROUNDWATER QUALITY -EPA METHOD 602 7.0 CONCLUSION AND RECOMMENDATIONS 7.1 CONCLUSIONS 7.2 RECOMMENDATIONS 8.0 LIMITATIONS TABLES i 1 1 2 2 2 2 3 4 4 4 5 5 6 6 7 7 TABLE 1 TABLE2 TABLE3 TABLE4 SUMMARY OF MONITORING WELL CONSTRUCTION DATA AND . GROUNDWATER TABLE ELEVATIONS AS OFNOVEMBER3,2005 HISTORICAL GROUNDWATER TABLE ELEVATIONS SUMMARY OF CURRENT GROUNDWATER LABORATORY RESULTS SUMMARY OF HISTORICAL GROUNDWATER LABORATORY RESULTS New Hanover County Burn Pit; 94040 mon rpt NOV0S CATUN Project No. 194-040 CA TUN Engineers and Scientists December 2005 I I I I I I I g D D m I I I I 'I I I I FIGURE! · FIGURE2 FIGURE3 · FIGURE4 FIGURES FIGURE6 FIGURES GENERAL LOCATION USGS TOPOGRAPHIC QUADRANGLE SITE MAP WITH CURRENT MONITORING WELL.LOCATIONS SITE MAP WITH CURRENT PULSE AIR SPARGE (PAS) LOCATIONS SITE MAP WITH GROUNDWATER TABLE CONTOURS AS OF NOVEMBER 3, 2005 SITE MAP WITH BENZENE CONCENTRATIONS AS OF NOVEMBER 3, 2005 SITE MAP WITH LOCATIONS OF PULSE SPARGE ZONES APPENDICES APPENDIX A APPENDIXB LABORATORY ANALYTICAL REPORTS AND CHAIN OF CUSTODY DOCUMENTS BENZENE CONCENTRATIONS VS. TIME GRAPH New Hanover County Burn Pit; 94040 mon rpt NO VOS CATUN Project No. 194-040 CAT UN Engineers and Scientists December 2005 I I I I I I I I n D I I I I I I I I 2000 Guidelines 2001 Guidelines 2LGWQS ARO AS AST BDL BN BNA BQL BLS BTEX CAP. CATLIN CFR Cr CSA CNP CPT DEM ·o!PE DO . DOD. DPT DWQ DWM DTW EAD EDB EMO EPA EPH EQB Fe FID FOO FRO FT GCL GIS GPS LIST OF ACRONYMS Groundwater Section Guidelines for Investigation and Remediation of Soil and Groundwater. Guidelines for Assessment and Corrective Actio·n, North Carolina Underground Storage Tank Section (Effective July I, 2001) · · NCAC Tl 5A:02L Groundwater Quality Standards Asheville Regional Office Air Sparge Aboveground Storage Tank Below Detection Limit Base/Neutral (extractables) Base/Neutral/Acid (extractables) Below Quantitation Limit Below Land Surface Benzene, Toluene, Ethylbenzene, Xylenes Corrective Action Plan CATLIN Engineers and Scientists .(Formerly RC&A) Code of Federal Regulations Chromium Comprehensive Site Assessment Carbon Nitrogen Phosphorous Cone Penetrometer Test Division of Environmental Management Diisopropyl Ether Dissolved Oxygen Department of Defense . Direct Push Technology Division of Water Quality Division of WaSte Management Depth to Water Environmental Affairs Department Ethylene di-bromide Environmeµtal Management Division Environmental Protection Agency Extractable Petroleum Hydrocarbons Environmental Quality Branch Iron Flame Ionization Detector Foreign Object Debris Fayetteville Regional Office Feet · Gross Contaminant Level Geographic Information System Global Positioning System New Hanover County Burn Pit; 94040 mon rpt NO VOS CATUN ProjeciNo. 194-040 CATUN Engineers and Scientists December 2005 I I I I I I I I I I I I I I I I I I I Guidelines Vol. I Guidelines Vol. II HDPE 1/C ID I&E IGWQS !PE LANTDIV LSA LUST m- m MADEP MCALF MCAS MCB MCOLF MDL mg/Kg mg/L MRO MSCC MSL MTBE µg/Kg µg/L NA NIA NC NCAC NCDENR NCDOC NCDOT NCSP NCSPA NE NM NMT NS o- OVA Groundwater Section Guidelines for Investigation and Remediation of Soil and Groundwater,· Volume I, Sources OtherThan Petroleum Underground Storage Tanks (May I 998) Groundwater Section Guidelines for Investigation and Remediation of Soil and Groundwater,. Volume II, Petroleum Underground Storage Tanks (January 2, 1998) High Density Polyethyl.ene Industrial/Commercial Identification Installations and Environment Department Interim Groundwater. Quality Standards Isopropyl Ether Atlantic Division Limited Site Assessmen.t Leaking Underground Storage Tank ~eta meter Massachusetts Department of Environmental Protection Marine Corps Auxiliary Landing Field Marine Corps Air Station Marine Corps Base Marine Corps Outlying Landing Field Method Detection Liinit Milligrams per Kilogram · Milligrams per Litre Mooresville Regional Office Maximum Soil Contaminant ConCentration Mean Sea Level Methyl tertiary butyl ether Micrograms per Kilogram Micrograms per Litre Not Analyzed . Not Applicable North Carolina North Carolina Administrative Code North Carolina Department of Environment and Natural Resources North Carolina Department of Corrections North Carolina Department of Transportation North Carolina State Plane · North Carolina State Ports Authority None Established Not Measured No Measurable Thickness Not Sampled ortho Organic Vapor Analyzer New Hanover County Burn Pit; 94040 mon rpt NO VOS CATUN Project No. 194-040 11 CA TUN Engineers find Scientists December 2005 I I I I I I I I I I I I I I I I I I I p- PAS PAH Pb PPB PPM PID PQL PVC RBCA RCRA Res ROI RRO sow STGW SVE. svoc TDHF TCLP TIC TKN TOC. TPH us uses USEPA USGS UST voe VPH WaRO WiRO WSRO para Pulse Air Sparge Polynuclear Aromatic Hydrocarbons Lead Parts Per BH!ion Parts Per Million Photo Ionization Detector Practical Quantitation Limit Polyvinyl chloride Risk-Based Corrective Action Resource Conservation and Recovery Act Residential Radius of Influence Raleigh Regional Office Scope of Work Soil-to-Groundwater Soil Vapor Extraction Semi. Volatile Organic Compound ToxicologicalliDefined Hydrocarbons Fractions Toxicity Characteristic Leaching Procedure Tentatively Identified Compound Total Kjeldahl Nitrogen Top of Casing Total Petroleum·Hydrocarbons United States Unified Soil Classification System United States Environmental Protection Agency United States Geological Survey Underground Storage Tank Volatile Organic Compounds Volatile Petroleum Hydrocarbons Washington Regional Office Wilmington Regional Office Winston-Sale.m Regional Office New Hanover County Burn Pit; 94040 mon rpt NOV0S CATLIN Project No. 194-040 111 CATLIN Engineers and Scientists December 2005 I I I I I I I D D I I I I I I I MONITORING REPORT NOVEMBER 3, 2005 SAMPLING EVENT . · NEW HANOVER COUNTY AIRPORT BURN PIT SUPERFUND SITE WILMINGTON, NORTH CAROLINA. DECEMBER 13, 2005 · CATLIN PROJECT NO.194-040 1.0 .PURPOSE 2.0 The purpose of this report is to present the latest data (May 2005 through November 2005) regarding the latest surficial groundwater quality and remediation efforts at the New Hanover County Airport Bum Pit Stiperfund Site on Gardner Drive, Wilmington, North Carolina (see Figure 1) since the last (May 2, 2005) groundwater sampling event. Historic usage of the site has impacted the site surficial groundwater with dissolved Volatile Organic Compounds (VOC) in excess of current NCAC T15A:02L North Carolina Groundwater Quality Standards (2L GWQS) .. Since 1998 the compound of concern has been benzene dissolved. in the site surficial groundwater. SITE GROUNDWATER MONITORING WELLS Currently, there are twenty-six site groundwater monitoring wells or piezometers. Twenty-four are Type I and . II monitoring wells or piezometers screened at depths ranging from approximately one to twenty-eight feet below land surface (BLS). Two Type III monitoring wells TMW-1 and TMW-2 are screened at depths of 40-45 and 38.5-43.5 feet BLS respectively. Monitoring well construction data is provided in Table I. Figure 2 illustrates the current groundwater monitoring well locations in relation to the site map. · Monitoring wells within the historic dissolved benzene plume boundary have been designated performance verification wells. These wells are located in interstitial zones between sparge points and are intended to provide data points to monitor contaminant reduction and dissolved oxygen levels within the deeper portion of the surficial aquifer. One performance verification monitoring well (PVSMW-002, located in the bum pit source area) is screened from one to ten feet BLS and is used to verify contaminant reduction within the shallow portion of the surficial aquifer. Performance .verification wells include: MWD-001, PVSMW-002, MWD-002, MWS-003, PVMW-010, PVMW-011, PVMW-014 and PVMW-015. Wells outside the historic dissolved benzene plume boundary have been designated compliance monitoring wells and are used to evaluate potential dissolved plume migration .. Compliance monitoring wells currently employed to monitor the groundwater plume boundary include: MWS-004,MWD-006,CMW-007,CMW-008,CMW-009,CMW-012,CMW-013andCMW- 016. New Hanover County Burn Pit; 94040 mon rpt NO VOS CATLIN Engineers and Scientists December 2005 CATUN Project No. 194-040 1 I I I I I I I I I I I I I u D D D D 3.0 4.0 SITE MONITORING PLAN Monthly CATLIN personnel conduct the following activities on a monthly basis: • Check and adjust system to ensure proper operation . • Measure dissolved oxygen (DO) in MWD-002. Semi-Annually (May and November) In addition to the monthly activities, CATLIN personnel also conduct the following activities on a semi-annual basis: • • Gauge and sample performance verification and compliance monitoring wells per EPA Method 602. • Measure DO in MWD-002 . • Prepare a monitoring report for submission to USEPA, NCDENR and PRPs. The report includes: system status updated groundwater table contour map updated groundwater contaminant isoconcentration map tabulated field and laboratory analysis summary table independent laboratory reports SITE ACTIVE REMEDIATION ACTIVITIES In accordance with the site Final Design Remedial Report, the performance goal for remediating non-compliant VOC concentrations within the impacted site surficial aquifer is 1 ug/L of benzene or as agreed to by involved entities. To achieve this objective a pulse air sparge system consisting of air compressors, 79 air injection wells, and associated controls has been designed and installed at the site. Pulse Air Sparge (PAS) injection wells were installed to depths of 23 to 25 feet below land surface. The locations of the current PAS injection wells are shown on Figure 3. 4.1 PULSE AIR SPARGE (PAS) 4.1.1 Pulse Air Sparge Description Pulse Air Sparge consists of injecting a pulse of ambient air within or below the contaminated zone of the impacted aquifer, through an air sparge well. As air is injected into the aquifer, a de-watered sphere grows around the New Hanover County Burn Pit; 94040 mon rpt NOV0S CA TUN Engineers and Scientists · December 2005 CATUN Projec/No. 194-040 2 I I I I I I I I I I I I a n D D u sparge point. This spherical volume of air continues to grow displacing groundwater until just before the top of the sphere "breaks through» the surface of the ground water table. Prior to "breakthrough", the air injection is terminated, injected air migrates back up to the ground surface, and the aquifer is allowed to recharge before the next "pulse". The 79 air_ injection wells are divided into 16 separate zones. Each zone is activated for · approximately 75 minutes every day. Zones are sequentially activated across from the site from each other to prevent interference and mitigate potential contamination migration from the temporary high water table conditions. The intent of this activity is to volatilize· dissolved. gasoline compounds within the impacted aquifer, and supply oxygen to indigenous aerobic · microbes. Indigenous aerobic microbe species important in dissolved gasoline compound degradation utilize dissolved oxygen (DO) from the · aquifer as an electron acceptor to convert dissolved gasoline compounds to CO2, water, and biomass. Aeration efforts of the PAS system replenish dissolved oxygen into the aquifer. Studies have repeatedly shown aerobic microbes, as opposed to anaerobic microbes, biodegrade dissolved gasoline compounds more rapidly. 4.1.2 Performance The PAS system performance was optimized during system calibration. Calibration of the PAS system occurred for approximately two weeks following system start-up. The calibration period consisted of adjusting airflow to specific zones in order to optimize performance and abandoning and re-drilling air sparge wells that were short-circuiting. In addition, during site visits, CATLIN personnel monitor compressor run times. Since the May 2, 2005 sampling event, the PAS system has operated approximately 80 % of the time. Periodic power outages have disrupted system . operation. Ultimately, site remediation performance is evaluated by reviewing the groundwater dissolved gasoline compound concentrations trend over time. Note -Since the active site remediation efforts were initiated, remnant groundwater contamination has apparently been reduced to the area around site monitoring wells MWD-002 and PVMW-014. Therefore, on October 3, 2005 air sparge zones 2, 4, 5, 10, 11, 15 and 16 have been turned off. Zones in and around site monitoring wells MWD-002 and PVMW-014 (Zones 1, 3, 6, 7, 8,. 9, 12, 13 and 14) are now active twice a day (see Figure 6). If contaminant concentrations rebound in the inactive zones the air sparge ·efforts can be reactivated quickly. New Hanover County Burn Pit; 94040.mon rpt NO VOS CATLIN Project No. 194-040 3 CATLIN Engineers and Scientists December 2005 I 0 D I I I I I D D D D I 5.0 SUMMARY OF SURFICIAL GROUNDWATER TABLE DAT A 6.0 Each of the site monitoring well top of casing (TOC) elevations has been surveyed in relation to mean sea level (MSL). The latest groundwater table depths were obtained at all site monitoring wells on November 3, 2005. While gauging the site monitoring wells, air sparge efforts had just ceased at zone 12 and were initiating in zone 14. The depth to groundwater table data has been subtracted from the TOC elevation to determine the site groundwater table elevations .as of November 3, 2005. The November 3, 2005 groundwater table depth . . and elevation data has been summarized on Table 1. The elevation data was entered into contouring software. program (AutoCAD Land Development) to generate the su_rficial groundwater table contours illustrated Figure 4. A review of Figure 4 indicates a groundwater high around performance verification well PVMW-014 as a result of the PAS efforts at nearby zones. The apparent overall site-wide groundwater flow direction is toward_ the southwest Historically, the predominant site-wide groundwater flow directions have been to the southwest with a northeasterly component of flow normally observed beneath the northeastern portion of the property. Historical site groundwater table elevation data has been listed ih Table 2. ·. SUMMARY OF GROUNDWATER QUALITY TESTING Prior to system installation, CATLIN personnel conducted a site groundwater sampling event to provide a pre-construction baseline of the dissolved contaminant plume. As of November 3, 2005, CATLIN has performed six post system installation sampling events. During each sampling event, CATLIN personnel recorded selected groundwater field parameter data and obtained groundwater samples in general accordance with the following procedures. 6.1 FIEW MEASUREMENT (DISSOLVED OXYGEN) Initial uninfluenced site groundwater DO levels were typically less than 0.5 milligram per Liter (mg/L). Aerobic groundwater conditions are generally those with DO levels greater than 1.0 ug/L. Site DO measurements are obtained by utilizing a low flow l 2~volt pump (Geopump or whale) to pump recovered groundwater through a flow through cell. Groundwater DO measurement are measured with a YSI Model 650 multi-parameter water quality instrument and Model 600XL sonde placed in the flow through cell. Groundwater DO levels, within the PAS injection well radius of influence, will fluctuate in accordance with the PAS air injection cycle. MWD-002 is gauged monthly due to its central location in relation to the site, its position in an interstitial zone between sparge points and the depth of its screened interval. Since the last (May 2, 2005) sample event DO measurements at MWD-002 have ranged from 0.1 I to0.72 mg/L. On November 3, 2005 DO measurements at the performance verification wells ranged from 0.08 to 2.29 ug/L. Performance verification wells with greater than 0.5 mg/L DO demonstrate the positive influence New Hanover County Burn Pit; 94040 mon rpt NO VOS CATLJN Engineers and Scientists December 2005 CATLJN Project.No. 194-040 4 g I u R D D I I I I I I I I R n D D .6.2 6.3 of the PAS efforts. DO measurements at the compliance monitoring wells .ranged from 0.11 to 0.38 ug/L, typical of uninfluenced groundwater. GROUNDWATER SAMPUNG Prior to sampling, each well was purged to ensure the· collected sample was representative of the surficial aquifer. Purging was performed by first removing a minimum of three well volumes from each monitoring well using disposable hailers. A pump was then used to extract groundwater from each well. The extracted groundwater was delivered to a flow-through cell via clean polyethylene tubing and temperature, conductivity, and pH were measured using an YSI Model 650 multi-parameter water quality instrument with Model 600XL sonde. Measurements were recorded at one- minute intervals until the readings had equilibrated. Once stabilized, the well was sampled and the recorded data was used to document the selected field paranieters. Groundwater samples were obtained from new polyethylene tubing attached to the discharge end of the test cell. The Model 600XL sonde, as well as the test cell were cleaned after each sample was collected in accordance with the manufacturer's instructions. A new set of disposable gloves and bailer were utilized for each sample collected. Each sample was placed in laboratory prepared sample glassware labeled with the well ·. ID, sample date, site name, sampler, and placed in an iced cooler. Samples were delivered to Paradigm Analytical Laborntories; Inc. (Paradigm; North Carolina Certification #481) in Wilmington, North Carolina for analysis. To determine groundwater concentrations (in ug/L) of remnant-dissolved gasoline compounds, all groundwater samples were analyzed for volatile compounds per EPA Method 602. GROUNDWATER QUAUTY -EPA METHOD 602 Since July of 1998 the compound of concern has been dissolved benzene concentrations within the site surficial groundwater. EPA Method 602 analysis of the latest site groundwater samples found only the groundwater ·sample from performance verification well PVMW-014 exhibited benzene concentrations (3.20 ug/L) above applicable 2L GWQS of I ug/L. For the first time a groundwater sample from performance verification well MWD-02 has tested compliant for all EPA . · Method 602 analytes. New Hanover County Burn Pit; 94040 inon rpt NO VOS CATLIN Engineers and Scientists December 2005 CATUN Project No. 194-040 5 n u D I I I I I I I I n D D D 7.0 Benzene concentrations as evaluated from the latest sample event (November 3, 2005) data, can be summarized as follows: i1~1fg\,~):&tif;&1l,~;1tiJi~Tu{JBCDzene1~oncentra"tiOris';iii'rti2/1'?$j;~~~~:·.'Si:~~f:~~lf~Hli t;{~1t&WCll'.ID]JX~ ~;:HiSiOiiC811Hit!lii~ {;t His.tCJriC81°1iO\V'.M r,t,;MtBS'SetillEt~Y~ ~~1t,1;iltesi'~J!iifll MWD-001 15 <0.5 <0.5 <I MWD-002 136 <l 18.6 <I MWD-006 3.4 <0.5 3.4 <l · PVMW-011 2.6 <l 2.6 <I PVMW-014 5 <l 4.4 3.20 .PVMW-015 4.1 <I 4.1 <I Figure 5 illustrates the benzene concentrations within the site surficial groundwater as of November 3, 2005. The latest groundwater sample analytical results have been summarized on Table 3. Historical EPA Meihod 602 analysis results have been summarized on Table 4. A copy of the Paradigm laboratory report for the latest sample event has been provided in Appendix A. To illustrate the historical groundwater remediation trend, a graphical . representation of historical benzene concentrations at site monitoring wells MWD-001, MWD-002, MWS-003, MWD-006, PVMW-011, PVMW-014 and PVMW-015 has . been prepared (see Appendix B). CONCLUSION AND RECOMMENDATIONS 7.1 CONCLUSIONS Based on the field and laboratory data obtained during the most recent monitoring period, the following conclusions are provided: Active Remediation System Operation • The PAS system has been operating properly for approximately 80% of the period from the May 2005 sampling event to the present. Surjicial Groundwater Quality • · The latest groundwater analyses revealed the site·surficial groundwater, in the vicinity of performance verification well PVMW-014, contains . minor concentrations (3.20 ug/L) of benzene in excess of applicable 2L GWQS. In reviewing the historical dissolved contaminant concentration data (Table 4 and graph in Appendix B), the overall trend indicates a progressive decline in benzene concentrations at all monitoring well locations. Compared to the baseline data, . . MWD-002 benzene concentration has declined from 18.6 ug/L to <l ug/L and benzene concentrations at PVMW-014 have decreased to 3:20 ug/L from 4.4 ug/L. New Hanover County Burn Pit; 94040 mon rpt NO VOS CATLIN Engineers and Scientists December 2005 CATLIN Project No. 194-040 6 D I I I I I I I I I I I I I I I I I I 8.0 In contrast to the July 2004 sampling event, MWD-002 decreased to 23.6 ug/L from 69 ug/L. Currently, only PVMW-014 contains a non-compliant concentration of benzene. Benzene concentrations do not appear to be migrating upwards in the water column as evidenced from the sample results collected froni monitoring wells MWD-002 and PVSMW-002. PVSMW-002 (screened to 10 feet below land surface (BLS)), which is in close proximity to MWD-002 (screened to 27 feet BLS), continued to display · benzene concentrations below 2L GWQS. 7.2 RECOMMENDATIONS CATLIN recommendations are based on a review of the current site conditions and are as follows: , Continue with the monitoring and maintenance schedule outlined in the Final Remedial Design Report. • Continue to focus remediation efforts of the pulsed air sparge system to zones southwest of PVMW-011, specifically zones 1, 3, 6, 7, 8, 9, 12, 13, and 14 (see Figure 6}. LIMITATIONS The field and groundwater data evaluated as part of this monitoring report provide isolated data points and may not represent conditions at every location in the project area. Analyses· and conclusions of this report, being based on interpolation between data points at the project area, may not be completely representative of all site conditions. Conclusions and recommendations of this monitoring program and report are based on the best available data in an effort to comply with current regulatory requirements. New Hanover County Burn Pit; 94040 mon rpt NO VOS CATLIN Engineers and Scientists December 2005 CATUN Project No. 194-040 7 I I I I I I I I I I I D D I I I TABLES New Hanover County Burn Pit; 94040 mon rpt NOV0S CATUN Project No. 194-040 CAT UN Engineers and Scientists December 2005 - - - ·--l!!!!!!!!!I !!!!!I == liiiiil lliiiiiil - - - Date: December 2005 MWD-001 1992 11/3/2005 17.5 MWD-002 1992 11/3/2005 17 PVSMW-002 5/28/02 11/3/2005 1 MWS-003 1992 11/3/2005 5 MWS-004 1992 11/3/2005 5 MWD-005 1 /4/00 11/3/2005 12 MWD-006 4/4/01 11/3/2005 14 CMW-007 1/4/01 11/3/2005 12 CMW-008 5/31/02 11/3/2005 3 TABLE 1 SUMMARY OF MONITORING WELL CONSTRUCTION DATA AND GROUNDWATER TABLE ELEVATIONS New Hanover County Airport Burn Pit Superfund Site 17.5,27.5 27.5 33.51 31.26 5.27 17-27 27 33.27 30.72 5.99 1-10 10 33.46 30.38 6.10 5-15 15 33.34 30.76 5.86 5-14.5 15 32.31 29.81 5.59 12-22 22 32.21 29.86 3.78 14-24 24 32.06 30.26 4.34 12-22 22 33.16 30.40 5.2.5 3-23 23 34.27 31.50 6.14 NHC Airpori BurnpiJ Superfund Site; 194040 Table 1 mw const-waler elev data_ CATUN Project No. 194-040 0 0 0 0 0 0 0 0 0 - - - - - 28.24. 27.28 27.36 27.48 26.72 28.43 27.72 2,7.91 28.13 Page 1 of 3 Performance Verification Monitoring Well Performance Verification Monitoring Well Performance Verification Monitoring Well Performance Verificaiion Monitoring Well Compliance Monitoring Well Monitoring Well••• · Compliance Monitoring Well Compliance Monitoring Well Compliance Monitoring Well CATUN Engineers and &,.-enlists November 2005 - - -I!!!!! !!!!!I Date: December 2005 CMW-009 5/30/02 11/3/2005 PVMW-01 0 5/30/02 11/3/2005 PVMW-011 5/30/02 11/3/2005 CMW-012 5/30/02 11/3/2005 CMW-013 5/30/02 11/3/2005 PVMW-014 5/28/02 11/3/2005 PVMW-015 5/28/02 11/3/2005 CMW-016 6/3/02 11/3/2005 P-1 1998 11/3/2005 == == -lliii -·-- - - 3 4 4 3 2 4 4 3 0 TABLE 1 SUMMARY OF MONITORING WELL CONSTRUCTION DATA AND GROUNDWATER TABLE ELEVATIONS 3-23 23 33.22 30.46 5.22. 4-24 24 32.78 30.10 4.62 4-24 24 33.43 30 .. 69 5.37 3-23 23 32.85 30.11 4.86 2-27 27 33.53 30.86 5.63 4-24 24 32.16 29.39 2'59 4-23 23 31.51 28.77 3.17 3-23 23 32.53. 29.85 4.31 0-7 7 32.41 29.54 6.51 0 0 0 0 0 0 0 0 0 NHC Airport Burnpit Super/und Sile; 194040 Table 1 mw Const•water elev.data CATUN Project No.194-040 . - - - - - 28.00 28.16 28.06 27.99 27.90 29.57 28.34 28.22 25.90 Page2 of 3 Co.mpliance Monitoring Well Performance Verification Monitoring· Well Performance Verification Monitoring Well Compliance Monitoring Well Compliance Monitoring Well Performance Verification Monitoring Well Performance Verification Monitoring Well Compliance Monitoring . Well Piezometer ••• CATUN Engineers and Sciennsls November 2005 liiiiil liiiilliil . liiiiil iiiil iiiil Date: December 2005 P-2 1998 11/3/2005 T-12 11/25/98 NM T-13 12/22/98 11/3/2005 T-14 12/22/98 11/3/2005 T-15 12/22/98 11/3/2005 T-16 1 /3/01 11/3/2005 TMW-1 9/30/94 NM TMW-2 9/30/94 NM iiii iiii --- - - - 0 2 5 5 5 17 40 38.5 . TABLE 1 SUMMARY OF MONITORING WELL CONSTRUCTION DATA AND GROUNDWATER TABLE ELEVATIONS New Hanover County Airport Burn Pit Superfund Site 0-8 8 31.55 30.28 4.27 2-14.5 14.5 33.59 NM· NM 5-15 15 32.19 29.61 4.91 5-15 15. 33.10 30.10 5.40 5-15 15 32.44 29.99 4.71 17-27 27 . 32.39 30.39 4.98 40-45 45 33.02 NM NM 38.5-43.5 43.5 33.21 NM NM • Aeferen~e point for all elevati~ns is ba_sed_ on Mean Sea Level -- 0 27.28- NM NM 0 27.28 0 27.70 0 27.73 0 27.41 NM NM NM NM -- - Page 3of 3 Piezometer 0 * Monitoring Well ••• Monitoring Well •·• Monitoring Well ••• Monitoring Well •·· Monitoring Well••• Telescoping Monitoring Well"*~- Telescoping Monitoring we11·0 . ** If free product is preseiit in a· well, g~ound water 81evation s~ould be calculated by: [Top of <?aSing Elevation • Depth to Water] + [free product thickness x (specific gravity of free pr?C1uct)] •u Well is not being sarripled as part of current monitoring network. ft BLS = feet below land surface NM = Not Measured NHC Airport· BurnpiJ Superfund Sile; 194040 Table 1 mw const-waJer elev dala CATUN Project No. 194-040 · CATLIN Engineers and Scientists November 2005 - I Date: December 2005 TABLE 2 HISTORICAL GROUNDWATER TABLE ELEVATIONS Page l.of3 I · New Hanover County Airport Bum Ptt Superfund Site ,~t'l:\lfisY.~ ~'fl ~!"~~:t~ r:.::.('<ei,J,K0J.t,W'_~; I ,!9f.QF,I ' -' ," FREEi fmA.DJUS!fP .\'l '/>"CASING' .,, \!)~_gf_fJTQ .~il'i ~-~r~-~-J~!'I:f.1 ~,{,. ... ~ • .,--•"" ~ij· ~t!'~9P¥~·r~J ELEVATION• GROUNDWATER ~(E~1[1 a ]Ji"li ---ii.THICKNESS (F;f.); :r ~ inttlcri'.i• -"~ .i.,s-r,,,;,~1 t-#l<J ;.,~. ,: ' '.c:>;·,x ,1Y . itt·~.10, jj,w:~-_? · • 6/11/2002 33.51 9.43 NMT 24.08 · •• 9/4/2003 33.51 4.39 ~MT 29.12 1113/2003 33,51 3.77 NMT 29.74 1ll/2004 33.51 4.57 NMT 28.94 MW0-001 4/1/2004 33.51 4.41 NMT 29.10 I 7/21/2004 33,51 8.73 NMT 24.78 5/212005 33.51 6.03 NMT 27.48 11/3/2005 33.51 5.27 NMT 28.24 6/11/2002 33.27 9.21 NMT 24.06 I 9/4/2003 33.27 4.50 NMT 28.77 1113/2003 33.27 3.69 NMT 29.58 MWD-002 lll/2004 33.27 4.46 NMT 28.81 4/112004 33.27 429 NMT 28.98 7/21/2004 33.27. 8.42 NMT 24.85 I 5/212005 33.27 5,72 NMT 27.55 11/3/2005 3327 5.99 NMT 27.28 6/11'2002 33.46 9.52 NMT 23.94 I 9/4/2003 33.46 5.17 NMT 28.29 11/3/2003 33.46 4.08 NMT 29.38 PVSMW-002 1n12004 33.46 4.92 NMT 28.54 4/1/2004 33.46 4.60 NMT 28.86 7/21/2004 33.46 8,84 NMT 24.62 I 5/2/2005 33.46 6.20 NMT 27.26 11/3/2005 33.46 6.10 NMT 27.36 6/11/2002 33.34 9.36 NMT 23.98 9/4/2003 33.34 4.69 NMT 28.65 I 11/3/2003 33.34' 4.24 NMT 29.10 MWS-003 1n12004 33.34 5.26 NMT 28.08 4/1/2004 33.34 4.54 ·NMT 28.80 7/21/2004 33.34 9.31 NMT 24.03 I 5/212005 33.34 6.59 NMT 26.75 11/3/2005 33.34 5.86 NMT 27.48 6111/2002 32.31 8.52 NMT 23.79 9/4/2003 32.31 3.27 NMT 29.04 I 11/3/2003 32.31 3.34 NMT 28.97 MWS-004 1n12004 32.31 3.67 NMT 28.64 4/1/2004 32.31 3.75 NMT. 28.56 7/21/2004 32.31 7.67 NMT · 24.64 512/200:5 32.31 521 NMT 27.10 D 11/3/2005 32.31 5.59 NMT 26.72 .11/3/2003 32.21 2.85 NMT 29.36 1n12004 32.21 3.92 NMT 28.29 I MWD-005 4/1/2004 32.21 3,86 NMT 28.35 7/21/2004 32.21 8.17 NMT -24.04 5/2/2005 32.21 4.94 NMT 27.27 11/3/2005 32.21 3.78 NMT 28.43 I 6/11/2002 32.06 8.75 NMT 23.31 9/4/2003 32.06 3.50 NMT. 28.56 11/3/2003 32.06 3.45 NMT 28.61 MWD-006 1nl2004 32.06 3.96 NMT· 28.10 · 4/1/2004 32.06 3.94 NMT 28.12 I · 7/21/2004 32.06 7.96 NMT 24.10 5/212005 32.06 5.59 NMT 26.47 11/3/2005 32.06 4.34 NMT 27.72 I I I ,me,....,.,_.,,_ ru1t1 i.u,, .. 111, CATUNf;,,,WM•NISri,,t.at, -•-• ••• h .. o •• , ... ·~· Offl ll«tlrlbu 200, I Date: December 2005 . TABLE 2 HISTORICAL GROUNDWATER TABLE ELEVATIONS Page 2 of 3 I New Hanover County Airport Bum Pit Supertund Site lr""'""''I ~~~Bi /WAPPARE~ ~~it1A'<fWE•~tt~ I $~i~~~~. f. ,;;-,;.,~~ ,.,iFREfr , _.!~l:>JY§!?J..>J½'..~ ' , DEPTH;T ,;;(,._, ..... :'I!,;' ,TABLE* ~--.• • •· .PRODUCTJl!! ··~·~ ',i:,.(: , •. -* ELEVATION•, GROUNDWA •H--•·---·-···' ;if ·EVATION· kt· ?fi?V~~;I -~'ff •• :··~-J!'?'~~esi~ ~ICKNF.S~ ··· ·, . · J::,:, -~ hf[~~·.::·_ ft 1¾ ~--~<:1-,··~~---~f"""'•-~ ~ _.) , ,,'I,,,, ,.-.;, ;0J ,)., ,(FT,),~ ~ ,, x,;, 6111/2002 33.16 9.64 NMT I 9/4/2003 33.16 3.66 NMT. 11/3/2003 33.16 3.78 NMT 1/7/2004 33.16 4.27 NMT 28.89 CMW-007 4/1/2004 33.16 4.13 NMT 29.03 I 7/21/2004 33.16 8.82 NMT 24.34 5/2/2005 33.16 5.67 NMT 27.49 11/3/2005 33.16 5.25 NMT 27.91 6/11/2002 34.27 10.51 NMT 23.76 I 9/412003 34.27 4.58 NMT 29.69 11/3/2003 34.27 4.67 NMT 29.60 CMW-008 1/7/2004 34.27 5.32 NMT 28.95 4/1/2004 34.27 5.17 NMT 29.10 7/21/2004 34.27 9.79 NMT 24.48 I 5/212005 34.27 6.71 NMT 27.56 11/3/2005 -34.27 6.14 NMT 28.13 6/11/2002 33.22 9.22 NMT 24.00. I 9/4/2003 3322 325· NMT 29.97' 11/3/2003 33.22 3.42 NMT 29.80 CMW-009 1/7/2004 33.22 4.21 NMT 29.01 . 4/1/2004 33.22 4.22 NMT 29.00 7/21/2004 33.22 8.57 NMT 24.65 I 512/2005 33.22 5.82 NMT 27.40 11/3/2005 33.22 5.22 NMT 28.00 6/11/2002 32.78 8.65 NMT 24.13 9/412003 32.78 3.25 NMT 29.53 I 11/3/2003 32.78 2.87 NMT 29.91 PVMW-010 1/7/2004 32.78 3.94 NMT 28.84 4/1/2004 32.78 3.67 NMT 29.11 7/21/2004 32.78 7.91 NMT 24.87 512/2005 32.78 5.39 NMT 27.39 I 11/3/2005 32.78 4.62 NMT 28.16 6/11/2002 33.43· 9.37 NMT 24.06 9/4/2003 33.43 4.49 NMT 28.94 I 11/3/2003 33.43 1.19 NMT 32.24 PVMW-011 1ll/2004 33.43 4.62 NMT 28.81 4/1/2004 33.43 4.49 NMT 28.94 7/21/2004 33.43 8.63 NMT 24.80 512/2005 33.43 6.04 NMT 27.39 n 11/3/2005 33.43 5.37 NMT. 28.06 6/11/2002 32.85 8.92 NMT 23.93 9/4/2003 32.85 3.42 NMT 29.43 11/3/2003 32.85 2.63 NMT 30.22 D . CMW-012 1ll/2004 32.85 3.93 NMT 28.92 4/1/2004 32.85 3.96 NMT 28.89 7/21/2004 32.85 8.25 NMT 24.60 5/2/2005 32.85 5.42 NMT 27.43 m 11/3/2005 32.85 4.86 NMT 27.99 6/11/2002 31.95 9.53 NMT 22.42 9/4/2003 31.95 4.44 NMT 27.51 11/3/2003 33.53 3.42 NMT 30.11 I CMW-013 1ll/2004 33.53 4.67 NMT 28.86 4/1/2004 33.53 4.61 NMT 28.92 7/21/2004 33.53 8.65 NMT 24.88 512/2005 33.53 6.21 NMT 27.32 I 11/312005 33.53 5.63 NMT 27.90 I I NHC 81Un,/l." /9-MUIJ T•blt ZA/S/JW tit, CA TUN ~UOttf1•n,I Sdftli,n f'.AT/J,Vl'NH<fN•. /9.µua --· I Date: December 2005 TABLE 2 HISTORICAL GROUNDWATER TABLE ELEVATIONS Page 3 of 3 I New Hanover County Airport Bum Pit Superfund Site ·~,m• J ''""%"1;\%(~11 ~;APP,\RENTi>t ~-,·:;,;,';'':<J'</;il;f't.,•i: · TOr'OF~:-· _: I It~ , ·:I IJ;":ilt,,, " . : f~/4E~E,~ fit, ID,J~~~r;,'~--:, d;;i.~~-~9' -_; f.;~.TQ1-.,. 1 bWATER.TABLE1 ., ••• w •••• -..... --c{<')( ~LEY1I!PN,~ GROUNDWATER ~THICKNESS~ ~~EYATl,OJJjf, 'l'/l;ll(Fr.)£:1 ;,~~1;r;•~r~ iiji,;,,·ff">'' .• ¾£~ ;,~KJ'J&J)ft:,1 i,;) p;,"'1,'lf~ ; X;-~-~ w,; ~J_., 1'_. 11'?9 ,. ',,_'\\ ( .)~<\<· 32:16 · 8.63 NMT 23.53 I 32.16 4.45 _NMT 27.71 32.16 3.18 . NMT 28.98 1n/2004 32.16 4:74 NMT 27.42 PVMW-014 411/2004 32.16 3.45 NMT 28.71 I 7/21/2004 32.16 9.10 NMT 23.06 512/2005 32.16 5.98 NMT 26.18 11/3/2005 32.16 2.59 NMT 29.57 6/11/2002 31.51 8.32 NMT 23.19 I 9/4/2003 31.51 2.77 NMT 28.74 1/7/2004 31.51 3.07 NMT 28.44 PVMW-015 4/1/2004 31.51 3.02 NMT 28.49 7/21/2004 31.51 6.98 NMT 24.53 5/2/2005 31.51 4.58 NMT 26.93 I 11/3/2005 31.51 3.17 NMT 28.34 6/11/2002 32.53 8.90 NMT 23.63 9/4/2003 32.53 3.37 NMT 29.16 I 11/3/2003 32.53 3.40 NMT 29.13 CMW-016 1n12004 32.53 4.13 NMT 28.40 4/1/2004 32.53 4.23 NMT 28.30 7/21/2004 32.53 8.16 NMT 24.37 512/2005 32.53 5.73 NMT 26.80 I 11/3/2005 32.53 4.31 NMT 28.22 11/3/2003 32.41 5.29 NMT 27.12 1n/2004 32.41 5.82 NMT 26.59 P-1 4/1/2004 32.41 5.96 NMT 26.45 I 7/21/2004 32.41 · 9.60 NMT 22.81 5l2l200S. 32.41 7.35 NMT 25.06 11f312005 32.41 6.51 NMT 25.90 I 11/3/2003 31.55 2.60 NMT 28.95 1n12004 31.55 3.29 NMT 28.26 P-2 4/1/2004 31.55 3.04 NMT , 28.51 7/21/2004 31.55 6.61 NMT 24.94 512/2005 31.55 4.69 NMT 26.86 I 11/3/2005 31.55 4.27 NMT 27.28 11/3/2003 32.19 3.44 NMT 28.75 1/7/2004 32.19 4.37 NMT 27.82 T-13 411/2004 32.19 4.51 NMT 27.68 D 7/21/2004 32.19 8.40 NMT 23.79 5/2/2005 32.19 6.06 NMT 26.13 11/312005 32.19 4.91 NMT 27.28 I 11/3/2003 33.10 4.48 NMT 28.62 1/7/2004 33.10 5.00 NMT 28.10 T-14 4/1/2004 33.10 4.95 NMT 28.15 7/21/2004 33.10 9.00 NMT 24.10 512/2005 33.10 6.61 NMT 26.49 I 11/3/2005 33.10 5.40 NMT 27.70 11/312003 32.44 3.78 NMT 28.66 117/2004 32.44 4.21 NMT 28.23 T-15 4/1/2004 32.44 4.09 NMT 28.35 I .7/21/2004 32.44 8.19 NMT 24.25 5f2i2005 32.44 6.31 NMT 26.13 11/312005 32.44 4,71 NMT 27.73 11/3/2003 32.39 3.62 NMT 28.77 I 10/2004 32.39 420 NMT 28.19 T-16 4/1/2004 32.39 3.91 NMT 28.48 7/21/2004 32.39 '7.31 NMT 25.08 512/2005 32.39 5.51 NMT 26.88 11/3/2005 32.39 4.98 NMT 27.41 I • Top uf casing clcva1ion i$ rcfom,o:d 10 mean iea lcYCI (fop of casing 15 cKVll!cd ahoYC ground lcYCI.) NMr -No Mcuurublc Thickn= I NHC Uw,q,IJ: /'Utu4 r."" i •w, .. ,,,. C..t TUN t:~uu-m •"" Sd,!Ulm r,.r,m/>ro....,/'la. /'4--.ia 1,, .... 0 ... 10115 I I I I I I I I I I I D m I I I I I Date: December 2005 TABLE 3 SUMMARY OF CURRENT GROUNDWATER LABORATORY RESULTS New Hanover County Airport Burn Pit Superfund Site . 'i;Jf,~~1~~ if.:£f~0i''>'k"Rl,~~ ~·'>«11550t,.:; ;,,e1,1000~ t':<:~-i\-t'~;,,-,,,1,,,}\ti .J/j--i", •1-·~Y""'@' ~~-f '< MWD-001 MWD-001 11/3/2005 <1.00 3.77 <1.00 MWD-002 MWD-002 11/3/2005 <1.00 <1.00 <1.00 PVSMW-002 PVSMW-002 11/3/2005 <1.00 <1.00 <1.00 MWS-003 MWS-003 11/3/2005 <1.00 <1.00 · <1.00 · MWS-004 MWS-004 11/3/2005 <1.00 <1.00 <1.00 MWD-006 . MWD-006 11/3/2005 <1.00. <1.00 <1.00 · CMW-007 CMW-007 11/3/2005 <1.00 <1.00 <1.00 CMW-008 CMW-008 11/3/2005 <1.00 <1.00 <1.00 CMW-009 CMW-009 11/3/2005 <1.00 <1.00 . <1.00 PVMW-010 PVMW-010 . 11/3/2005 <1.00 <1.00 <1.00 PVMW-011 PVMW-011 11/3/2005 . <1.00 <1:00 <1.00 CMW-012 CMW-012 11/3/2005 <1.00 <1.00 <1.00 CMW-013 CMW-013 11/3/2005 <1.00 <1.00 <1.00 PVMW-014 PVMW-014 11/3/2005 Ii:---~ -~. :2£_?,Qi ,". 0.319 J <1.00 . PVMW-015 PVMW-015 11/3/2005 <1.00 <1.00 <1.00 CMW-016 CMW-016 .· 11/3/2005 <1.00 <1.00 <1.00 All results in ug/L BQL = Below Quantitation Lim its Shaded areas indicate concentrations greater than the 2L GWQS. < -Less ~han quantitation limits. J = Estimated concentration, below calibration range and above Method Detection Limit Page 1 of 1 ~~~ilii£j J!'ll"""'iil'lf\fi I< ~F1¥i~ ~rie·s,i'c , '·1 !\., '";~;q&"J'1 off . . .. --· <4.00 BQL <4.00 · BQL <4.00 BQL · <4.00 BQL <4.00 BQL <3.73J BQL <4.00 BQL <4.00 BQL <4.00 BQL <4.00 · BQL <4.00 BQL <4.00 BQL <4.00 BQL <4.00 BQL <4.00 BQL <4.00 BQL Client; 194040 Table 3 current 602 OW resulls CATUN Project No. 194-040 CATLIN Engineers and Scit!ntists December 2005 I I I I I I I I I I I I I I I 0 D D M Date: December 2005 TABLE 4 SUMMARY OF HISTORICAL GROUNDWATER LABORATORY RESULTS New Hanover County Airport Burn Pit Superfund Site MWD-001 M"NS-001 MWD-002 NHC Bumpll.; ,uruo Tab~4 hi# 602 GW"rulls CATUNPn,fec:tNo.194.().10 MWD-001 4{17/1991 l"'79Jij MWD-001 . 5/7/1991 ;"JJfli· ·; MWD-001 11/19/1991 ,,~)vi MWD-001 1m,m -·-~14Jrw ~~ .:_-Y ~: <>c·{. ~ MWD-001 12/9/1992 ;Tut,%9·4J·o<}, -··-"'*I MWD-001 6/8/1993 ~~~~::&;!.,,.: ~D-001 1015/1994 <0.5 MWD-CX>1 6111/2002 <0.5 MWD-001 915/2003 <1 MWD-001 ln/2004 <1 MWD-001 4/1/2004 <1 MWD-001 7121/2004 <1 MWD-001 51212005 <1 MWD-001 11/2512005 <1 MWS-001 &'11/2002 <0.5 Nol lnduded In current groundwater sampling plan MWD-002 4/17/1991 MWD•002 5/7/1991 MWD-002 11/20/1991 MWD-002 7/7/1992 MWD-002 12/9/1992 MWD-002 6/8/1993 MWD-002 10/6/1994 MWD-002 6122/1998 MWD-002 6/2511998 MWD-002 7/9/1998 MWD-002 7/23/1998 MWD-002 7/3Q/1998 MWD-002 1/1612001 MWD-002 6/11/2002 MWD-002 915/2003 . MWD-002 lll/2004 MWD-002 4/1/2004 MWD-002 7/21/2004 . MWD-002 51212005 MWD-002 11/3/2005 8.SJ 7.4 8.8 18 10 19 <0.5 8.0 3.3 3.5 3.3 2.92 2.32 177 <0.5 1.1 14.8 6.8 14 11 10 18.2 7.46 <1 2.0J 1.SJ 1.1J 1.4J <0.5 1.3.J <0.5 <0.5 <1 <1 <1 <1 0.832 J <1 <0.5 14J 13.J 5.9J 2.BJ 3.4J <0.5 9.4 4.1 2.5 238 2.1 2.3 <05 <0.5 <1 <1 <1 <1 1.28 <1 25.3J 29.1J <0.5 <0.5 <0.5 <0.5 <0.5 <1.5 <4 <4 <4 <4 <4 <4 <1.5 B2J 82J <0.5 <0.5 <0.5 2.0J 35.9 23.2 27.4 115 20.8 c::1.5 17.8 4.8 <7 <5.8 <4 23.68 3.44J <4 Pagelo/4 CA TUN En1iriurs and Scitntists Dtumbu2005 I I I I I I I I I I I I g D D I • I I Date: December 2005 TABLE 4 SUMMARY OF HISTORICAL GROUNDWATER LABORATORY RESULTS. New Hanover.County Airport Bum Pit Superfund Site Not induded in curren1 groundwater sampling plan PVSMW-002 6/11/2002 <0.5 . <0.5 <0.5 PVSMIN-002 914/2003 <1 <1 <1 f>l.'.SMW-002 1n/2004 ,1 <1 -~1 PVSMW-002 PVSMW-002 4/1/2004 <1 <1 <1 PVSMW-002 7/21/2004 <1 <1 <1 PVSMW-002 51212005 <1 <1 0.921 J PVSM'N-002 11/3/2005 <1 <1 <1 MWS-003 4/17/1991 <0.5 <0.5 089J MWS-003 Sf'T/1991 <0.5 <0.5 <0.5 MWS-000 11/19/1991 <0.5 <0.5 <0.5 MWS-003 7ntHJ92 <0.5 <0.5 <0.5 MWS-003 12/9/1992 <0.5 <0.5 <0.5 MWS-000 619/1993 <0.5 <O.S <0.5 MWS-003 10/5/1994 <5 <5 <5 MWS-003 MWS-003 1/1612001 0.5 <0.5 MWS-003 6/11/2002 <0.5 <0.5 <0.5 MWS-003 9/4/2003 <1 <1 ,1 MWS-003 1n12004 <1 <1 <1 MWS-000 4/1/2004 . <1 <1 <1 MWS-000 7/21/2004 <1 <1 <1 MWS-000 51212005 <1 <1 1.60 MWS-003 11/3/2005 <1 <1 <1 MWS-004 4/17/1991 <0.5 <0.5 <0.5 MW8-004 5/7/1991 <0.5 <0.5 "15 MW8-004 7n/1991 <0.5 <0.5 0.52J MW8-004 11/1911991 <0.5 <0.5 <0.5 MWS--004 12/9/1992 <0.5 <0.5 <0.5 MWS-004 619/1993 <0.5 <0.5 <0.5 MWS-004 10/5/1994 <0.5 <0.5 <0.5 MWS-004 MWS-004 1/16/2001 <0.5 <0.5 <0.5 MW8-004 &'11'2002 <0.5 <0.5 <0.5 MW8-004 9/4/2003 <1 <1 ,1 MWS-004 118/2004 <1 <1 <1 MWS-004 4/1/2004 <1 <1 <1 MWS-004 7/21/2004 <1 <1 ,1 MW8-004 51212005 <1 <1 1.47 MW8-004 11/3/2005 <1 <1 <1 NHC Bumpil; /94040 Tobit 4 hist 602 GW rrsulls ,-., ..,, ,., o •• , • .., ~,. 104.IU/I <1.5 <4 ,4 ,4 <5.54 <4 ·,4 <1.5 0.77J <1.5 <1.5 <1.5 <1 .. 5 <10 2.4 <1.5 ,4 ,4 ,4 <4 <4 <4 <1.6 <1.5 <1.5 ·<1.5 <1.5 <1.5 <1.5 <1.5 <1.5 ·. ,4 <4 <4 ,4 <4 <4 Page 2 of4 CA TUN En,:lnttn aml St:Untlsts lhum/Hr_l{)()S I I I I I I I I I I I I I I I I I • D Date: December 2005 TABLE 4 SUMMARY OF HISTORICAL GROUNDWATER LABORATORY RESULTS New Hanover County Airport Burn Pit Superfund Site Not lnduded in current groundwater sampling plan MWD-006 4/12/2001 <0.5 <0.5 <0.5 MWD-006 6/11/2002 ~~41;• ·<0.5 <0.5 MWD-006 9/412003 :tl'Jf~'""r ·<J <1 <1 ~~:1.1-,ei,.t: MWD-006 MWD-006 1/812004 <1 <1 . <1 MWD-006 4/1/2004 <1 <1 <1 MWD-006 7/21/2004 <1 <1 <1 MWD-006 5/2/2005 <1 <1 0.490 J. MWD-006 11/3/2005 <1 <1. <1 CMW-007 6111/2002 <0.5 <0.5 <0.5 CM"N-007 9/5/2003 <1 <1 <1 CMW-007 1/7/2004 <1 <1 <1 CMN-007 CMW-007 4/1/2004 <1 <1 <1 . CMW-007 ·7/21/2004 <1 <1 <1 CMW-007 51212005 <1 <1 0.736J CMW-007 11/3/2005 <1 <1 <1 CMW-008 6/11/2002 <0.5 <0.5 <0.5 c·MW-008 9/5/2003 <1 <1 <1 CMW--006 1/7/2004 <1 <1 <1 CMW--006 CMW--006 4/1/2004 <1 <1 <1 CMW--006 7/21/2004 <1 <1 <1 CMW-006 51212005 <1 <1 ·o.e10J CMW--006 11/3/2005 <1 <1 <1 CMW-009 6111/2002. <0.5 <0.5 <0.5 CMW-009 915/2003 <1 <1 <1 CMW-009 1(7/2004 <1 <1 <1 CMW-009 CMW-009 4/1/2004 <1 <1 <1 CMW-009 7/21/2004 <1 <1 <1 CMW-009 5/2/2005 <1 <1 0.876 J CMW-()09 11/312005 . <1 <1 '<1 PVMW-010 6/11/2002 <0.5 <0.5 <0.5 PVMW-010 9/5/2003 <1 <1 <1 · PVMW-010 1n/2004 <1 <1 <1 PVMW-010 PVMW-010 4/1/2004 <1 <1 <1 PVMW-010 7/21/2004 <1 1.57 <1 PVMW-010 5f212005 <1 0.310J 0.866 J PVMW-010 1113/2005 <1 <1 <1 NHC Burnpil; 194040 Tabk 4 hist 602 GWnsulls ,.,,,.., ,., ,,__, __ , M. "" tun <1.5 3.6 <4 <4 <4 <4 <2.820 J < 3.73 J <1.5 <4 <4 <4 <4 <4 <4 <1.5 <4 <4 <4 <4 <2.618 J <4 <1.5 <4 <4 <4 <4.29 <4 <4 <1.5 <4 <4 <4 <4.73 <4 <4 Page 3 o/4 CA. TUN Enslnurs and Sdtntists Dtumhr 2005 I I Date: December 2005 TABLE4 SUMMARY OF HISTORICAL Page 4 o/4 GROUNDWATER LABORATORY RESULTS I New Hanover County Airport Burn Pit Superfund Site I I ,-, •i<-e'' , • .«.-,:· " ..,,," ~·» PVMW·011 6/11/2002 2.6 2.7 <0.5 2.B PVMW-011 . 9/5/2003 <1 <1 <1 <4 I PVMW·011 ,n12004 <1 <1 <1 <4 PVMW-011 PVMW-011 4/1/2004 <1 <1 <1 <4 PVMW-011 7/21/2004 <1 <1 <1 <4 I PVMW·011 512/2005 <1 <1 0.976J <4 PVMW-011 11/3/2005 <1 <1 <1 <4 CMW·012 6/11/2002 «l.5 <0.5 <0.5 <1.5 I CMW·012 9/5/2003 <1 <1 <1 <4 CMW-012 1n/2004 <1 <1 <1 <4 .CMW-012 CMW·012 4/1!2004 <1 <1 <1 <4 CMW-012 7/21/2004 <1 <1 <1 <4 I CMW-012 5/2/2005 <1 <1 0.980 J <4 CMW·0t2· 11/3/2005 CMW-013 6111/2002 <0.5 <0.5 <0.5 <1.5 I CMW-013 9/5/2003 <1 <1 <1 <4 CMW-013 ,n12004 <1 <1 <1 <4 CMW-013 CMW-013 4/112004 <1 <1 <1 <4 I . CMW-013 7/21/2004. <1 <1 <1 <6.84 CMW·Ot3 5/2/2005 <1 <1 1.24 1.290 J CMW-013 11/3/2005_. <1 <1 <1 <4 I PVMW-014 6/11/2002 1.6 <0.5 2.1 PVMW·014 9/4/2003 <1 <1 <4 ... PVMW-014 1n12004 3.3. <1 <1 <4 PVMW.014 PVMW-014 4/1/2004 <1 <1 <4 I PVMW·014 7/21/2004 -<1 <1 <1. <4 PVMW•014 512/2005 0.306 J 2.29 1.346J PVMW·014 11/3/2005 0.319J <1 <4· I PVMW-015 6/11/2002 4.1 1.4 <0.5 2.1 PVMW·015 9/4/2003 <1 <1 <1 <4 PVMW-015 1/812004 <1 <1 <1 <4 I PVMW-015 PVMW-015 4/22/2004 <1 <1 <1 <4 PVMW·015 7/21/2004 <1 <1 <1 <4 PVMW·015 5/2/2005 0.779 J 0.311 J 2.33 1.349J PVMW·015 11/3/2005 <1 <1 <1 <4 I CMW-016 &'1112002 <0.5 <0.5 <0.5 <1.5 CMW-016 915/2003 <1 <1 <1 <4 CMW-016 1/812004 <1 <1 <1 <4 I CMW-016 CMW·016 4/1/2004 <1 <1 <1 <4 CMW·016 7/2112004 <1 <1 <1 <4 CMW-016 5/2/2005 <1 <1 2.31 <2.666 J I CMW-016 11/3/2005 <1 <1 <1 <4 ' "" J • ESlm&led Value Shilded llgura indicates c:on=entratk:>n a:eedS the appilcable 2L GWOS. I < • Less than quantllalion llmls. NflC Bumpil: 194()4() Tablt 4 hiJt 602 GW mu/Js CA TUN Enginu_n and Scitntists Dtumbtr 2005 I I I I I I I I I I I I I I I I I I I FIGURES New Hanover County Burn Pit; 94040 mon rpt NOV0S CATUN Project No. 194-040 CAT UN Engineers and Scientists December 2005 I I I I I I I I I I I I I I I I I I I 1 MILE NOTE: 1 _ MAP PROVIDED BY TOPOZONE.COM ~ £ ' [11:Jl]lli ENGINEERS and SCIENTISl'S WILMINGTON, NORTH CARO..!NA 1/2 MILE PROJECT 0 CASTLE HAYNE, N.C. 2000 NEW HANOVER COUNTY AIRPORT BURN PIT SUPERFUNO SITE WILMINGTON, N.C. 1 MILE QUADRANGLE LOCATION GENERAL LOCATION USGS TOPOGRAPHIC QUADRANGLE JOO NO: 194-040 SCALE· ORA~ BY: HCS DATE: NOV 2005 · AS SHOWN CHECXED BY: GRG FIGURE 1 ustatlon 184040-MR-NOV0S-01 I I I I I I I I I I I I I I I I I I I T-13 ffi CMW-016 • 8 PVMW-015 (FORMERLY PVMW-7) 8 PVMW-014 DENSE WOODS EBT-15 RR SPIKE AT NOTE: it PAVEMENT INTERSECTION ELEV -31.08' MSL 1. TI-115 DRAWING WAS ADAPTED FROM EXISTING EPA DRA'MNGS AND AERIAL MAPPING. 2. WELL LOCATIONS AND ELEVATIONS LOCATED BY STOCKS LAND SURVEY!NG. P .C. DA TED 24 APRIL 2001. 3. WELLS IN BOLD ARE INCLUDED IN CURRENT MONITORING NETWORK AND ARE SAMPLED ON A SEMI-ANNUAL BASIS NO. DESCRIPTION REVISIONS T-12 ffi BY TMW-~ ~a -"½ MWS-00 DENSE WOODS m MWO 005 DENSE WOODS BLOCK BLOG. a Q PVSMW-002 ff MWD-002 TMW-Zffi CMW-013 TREATMENT PVMW-011 8 CMW-008 • BLOCK BLDG. t:::::J • CMW-007 ( FO?-MERL Y T - I 7j DENSE WOODS LEGEND ~ ,f PANEL BOX AND METER BASE 3 PHASE 100 AMP 0 BLOCK BLDG. ff T-16 0 DESIGNED BY: WJW DRA'M'<' BY: HCS CHECKED BY: WJW APPROV£0 BY: GRG DATE: NOVEMBER 2005 194040-MR-NOVOS-02 <:s£csl1,□o=D --IIICIDITIB11I WILMINGTON, NORTH CAROLINA GARDNER DRIVE PRo.ECT RR SP!KE " NEW HANOVER COUNTY AIRPORT BURN PIT SUPERFUND SITE 'MLMINGTON, N.C. EXISTING EB m [] 8 • 0 TITl.E SCALE: DESCRIPTION MONITORING WELL (NOT CURREN TI. Y SAMPLED) TYPE Ill MONITORING WELL (NOT CURREN TI. Y SAMPLED) PIEZOMETER 80 PERFORMANCE VERIFICATION MONITORING WELL COMPLIANCE MONITORING WELL POWER POLE 0 80 SCALE IN FEET SITE MAP WITH CURRENT MONITORING WELL LOCATIONS JJB NO. 194-040 """ 2 I I I I I I I I I I I I I I I I I I I CMW-016 ® DENSE WOODS E!)T-15 ~',..... I.!,; 84 B ..... _________ ... B2 RR SPIKE AT ~ PAVEMENT INTERSECTION ELEV -31.08' MSL NOTE: 1. THIS DRAWING WAS ADAPTED FROM EXISTING EPA DRAWINGS ANO AERIAL MAPPING. 2. 'NELL LOCATIONS AND ELEVATIONS LOCATED BY STOCKS LAND SURVEYING, P .C. DA TED 24 APRIL 2001. NO. DESCRIPTION REVISIONS T-12 $ \ \ BY om ,--- DENSE WOODS CMW-008 @ --·-F32 Le..-r-__,,..F34 ,, @MWS-004 BLOCI". BLDG. a GCMW-009 BLOCK B~,,-~ ~d 9 ~E3 CMW-013 TREATMENT PANEL BOX ANO METER BASE 3 PHASE 100 AMP P-2 0 BLOCK BLDG. Q£5jGNEO BY: WJW OflA"" 8Y· HCS CHECKED BY: WJW APPROVED BY: GRG DA TE: NOVEMBER 2005 194040-MR-NOVOS-03 DENSE WOODS es&csC1,□CFO 'MLMINGTON, NORTH CAROLINA , , D28 ,,, -030 ,· . GARDNER DRIVE PRo..ECT RR SPIKE @ NEW HANOVER COUNTY AIRPORT BURN PIT SUPERFUNO SITE WILMINGTON, N.C. CMW-007 (FORMERLY T-I 7) LEGEND EXISTING 8) e 8 ® IQ] 0 SCALE: DESCRIPTION MONITORING WELL (NOT CURRENTLY SAMPLED) TYPE Ill MONITORING WELL (NOT CURRENTLY SAMPLED) PERFORMANCE VERIFICATION MONITORING WELL COMPLIANCE MONITORING WELL 80 PIEZOMETER POWER POLE SPARGE WELL WITH BOX CONTROL VALVE BOX 0 SCALE IN FEET 80 SITE MAP WITH CURRENT PULSE AIR SPARGE (PAS) LOCATIONS JOB NO. 194-040 FlGUlE 3 I I I I I I I I I I I I I I I I I I NOTE: EB T-13 (27.28) MWD-006 (27.72) •T-14 (27.70) 1. THIS DRAWING WAS ADAPTED FROM EXISTING EPA DRAWINGS ANO AERIAL MAPPING. 2. 'NELL LOCATIONS ANO ELEVATIONS LOCATED BY STOCKS LAND SURVE't1NG, P .C. DA TED 24 APRIL 2001. 3. DATA FROM MW-005 (NOT SHO'NN) WAS USED FOR CONTOURING. 4. CONTOUR INTERVAL = 0.50 FOOT RR SPIKE AT 'l_ PAVEMENT INTERSECTION ELEV -31.08' MSL PA~iil, BOX AND ~Ef BASE 3 ,1:iHAJE 100 AMP ,, I ,,,. I .,,. ... P-2 1 !'7770l-- (27.28) 1 ~--:3 [21 t.--~ BLOCK BLDG. T-16 (27.41) DESIGNED BY: __ _,_W'-"J,eW __ l---1-------------------------------t--+--, DRAWN BY: __ ~J~cw~-- l---1-------------------------------t--+--, CHEO<EO BY: __ _,_W'-"J"W __ l---1-------------------------------t--+--, APPRO~D BY: GRG f-oN°'o.+----------,;oE"S"C"'Rla-PTI"'ON'"---------------t--, • .,,--t--,oc.,nn:rl DATE: NOVEMBER 2005 REVISIONS 194040-MR-NOVOS-04 ~ CMW-008 (28.13). , I \ \ \ \ \ \ \ J \ \ o--' _1,.1e,.O ' PVMW-011 .,...,,,.,,, : 8(28.06) ----, ---, --, ---, __ _ DENSE WOODS \ GARDNER DRIVE PRo..ECT RR SPIKE @ --- --~ NEW HANOVER COUNTY AIRPORT BURN PIT SUPERFUND SITE WILMINGTON, N.C. 'NILMINGTOO. NORTH CAROLINA I I I I I I I I ·--------I _ .. • --CMW-007 (FORMERLY T -1 7) (27.91) LEGEND EXISTING EB Ei) □ 8 • 0 ( ) NM .... TIil£ DESCRIPTION MONITORING WELL (NOT CURRENTIL Y SAMPLED) TYPE 111 MONITORING WELL (NOT CURRENTLY SAMPLED) PIEZOMETER 80 PERFORMANCE VERIFICATION MONITORING WELL COMPLIANCE MONITORING WELL POWER POLE GROUNDWATER ELEVATION IN FEET NOT MEASURED GROUNDWATER FLOW DIRECTION GROUNDWATER CONTOUR 0 80 SCALE IN FEET SITE MAP WITH GROUNDWATER TABLE CONTOURS AS OF NOVEMBER 3, 2005 JOO NO. 194-040 4 I I I I I I I I I I I I I I I I I I I T-i3 (NS) ffi CMW-Oll! (<1). 8 PVMW-015 (FORMERLY PVMW-7) (<1) DENSE WOODS tl)T-15 (NS) 8 PVMW-014 (3.20) T-12 (NS) ffi • MWS-004 (<1) BLOCK BLDG. G DENSE WOOiJS • CMW-009 ( < 1) TM'c_,~~~-. BLOCK BZ:);:;:· (sf~ -~-\~tt-ooJ CM~~ PVMW-010 ~ (<1) s . (<l) ~-/ 8 (<1) DENSE -~J WOODS PVSMW-0029 (<l) ff MWD-002 V (<1) m TMW-2m (NS) TREATMENT CMW-013 ( <1) PVMW-011 .a. (<1) ..,. CMW-008 (<1) • • CMW-007 (FORMERLY T-17) (<1) DENSE WOODS LEGEND NOTE: RR SPIKE AT ~ PAVEMENT INTERSECTION ELEV = 31.08' MSL 1. THIS DRAWING WAS ADAPTED FROM EXISTING EPA □RAW1NGS ANO AERIAL MAPPING. 2. WELL LOCATIONS ANO ELEVATIONS LOCATED BY STOCKS LAND SURVEYING, P.C. DATED 24 APRIL 2001. 3. WELLS IN BOLD ARE INCLUDED IN CURRENT MONITORING NETWORK AND ARE SAMPLED ON A SEMI-ANNUAL BASIS. 4. WELLS H!GHUGHTED IN RED IND1CA TE LOCATIONS OF NON COMPLIANT BENZENE CONCENTRATIONS. PANEL BOX AND METER BASE 3 PHASE 100 AMP P-2 0 BLOCK BLDG. T-16 (NS) DESIGNED 8Y: __ W=J=W __ ~==~~====================================================⇒====±====~ ORAv.N BY· _ __!Ho,C<.aS __ t--t---------------------------,f--+----j CHECKED BY: WJW t--t---------------------------,f--+----j APPROVEO BY: GRG r.;N"O.-+----------,o"E"SC~R~IP~TION~-------------,hro,-+~DA""lE,.-j DATE: NOVEMBER 2005 REVISIONS 194040-MR-NOV05-05 --~ WILMINGTON, NORTH CAROLINA GARDNER DRIVE RR flKE PRQ.{CT NEW HANOVER COUNTY AIRPORT BURN PIT SUPERFUND SITE WILMINGTON, N.C. EXISTING ffi m 8 • □ 0 ( ) NS J DESCRIPTION MONITORING WELL (NOT CURRENTLY SAMPLED) TYPE Ill MONITORING WELL (NOT CURRENTLY SAMPLED) PERFORMANCE VERIFICATION MONITORING WELL COMPLIANCE MONITORING WELL 80 PIEZOMETIER POWER POLE BENZENE CONCENTRATION IN µg/L NOT SAMPLED ESTIMATED CONCENTRATION 0 80 SCALE IN FEET SITE MAP WITH BENZENE CONCENTRATIONS AS OF NOVEMBER 3, 2005 .QJNO. 194-040 """' 5 I I I I I I I I I I I I I I I I I I I PVMW-015 (FORMERLY PVMW-7) -, \ \~t 0 0 0 0 P-1 '~ ZONE 6 0 T-12 (B RR SPIKE AT \ \ § MWS-004 0 TREATMENT DENSE WOODS ESTIMATED SPARGE WELL RADIUS OF INFLUENCE BLOCK BLDG. u CMW-013 DENSE WOODS 'i'_ PAVEMENT INTERSECTION ELEV -31.08' MSL P-2 0 NOTE: 1. THIS DRAWING WAS ADAPTED FROM EXISTING EPA DRAWINGS AND AERIAL MAPPING. 2. WELL LOCATIONS ANO ELEVATIONS LOCATED BY STOCKS LAND SURVEYING, P.C. DATED 24 APRIL 2001. 3. WELLS IN BOLO ARE INCLUDED IN CURRENT MONITORING NETWORK AND ARE SAMPLED ON A SEMI-ANNUAL BASIS 4. ALL EXISTING TEMPORARY OR PERMANENT MONITORING WELLS INSIDE PLUME BOUNDARY NOT DESIGNATED AS PERFORMANCE VERIFICATION \\"ELLS SHALL BE PROPERLY ABANDONED TO PREVENT SHORT CIRCU!TING OF SPARG!NG. 5. ON 10/03/2005 ZONES 2, 4, 5, 10, 11, 15 AND 16 HAVE BEEN TURNED OFF REMAINING ZONES ARE STILL ACTIVE. BLOCK BLDG. T-16 DESIGNED BY: -~W~J~W __ f--t---------------------------+--+---+ DRA'NN BY: -~H~C=S __ 1----+---------------------------+--f----, a-tECKED BY: --~WJ~W~_ 1----+---------------------------+--f----, APPRO~ BY: __ ,,,,GR,,G.__ f-ccNO~.-+----------~o=,s=c=•1=,TI=o=N-------------+-~.=,-+~o,=rr=-' DATE: NOVEMBER 2005 REVISIONS 194040-MR-N0VOS-06 ~,m!i sc,aUliii& WILMINGTON. NORTH CAROLINA 0 ZONE16 0 0 E)CMW-009 0 0 CMW-008 ~0 j e CMW-007 (FORMERLY T-I 7) LEGEND GARDNER DRIVE RRl'"' EXISTING ttl e IQI 8 © 0 0 0 PRo.ECT TITLE NEW HANOVER COUNTY AIRPORT BURN PIT SUPERFUND SITE WILMINGTON, N.C. SCM.f: DESCRIPTION MONITORING WELL (NOT CURRENTLY SAMPLED) TYPE 111 MONITORING WELL (NOT CURRENTLY SAMPLED) PIEZOMETER 80 PERFORMANCE VERIFICATION MONITORING WELL COMPLIANCE MONITORING WELL ACTIVE SPARGE WELL INACTIVE SPARGE WELL POWER POLE 0 80 SCALE IN FEET SITE MAP WITH LOCATIONS OF PULSE SPARGE ZONES .QINO. 194-040 FIGURE 6 I I I I I I I I D D I I I APPENDIX A LABORATORY ANALYTICAL REPORTS AND . CHAIN OF CUSTODY DOCUMENTS New Hanover County Burn Pit; 94040 mon rpt NO VOS CATUN Project No. 194-040 CATUN Engineers and Scientists· December 2005 I I I I I I I I I u D I I I · PARADIGM:. ANALYTICAL LABORATORIES, INC. Mr. Rick Garrett Richard Catlin & Associates 220 Old Dairy Rd. · Wilmington NC 28405 ReportNumber: Gl28-1631 Client Project: NHC Burn Pit Dear Mr. Garrett: FILE COPY Enclosed are the results of the analytical services performed under the referenced project. The samples are certified to meet the requirements of the National Environmental Laboratory Accreditation Conference Standards. Copies of this report and supporting data will be retained in our files for a period of five years in the event they are required for future reference. Ariy samples submitted to our laboratory will will be. retained for a maximu.m of thirty (30) days from the date of this report unless other arrangements are requested. If there are any questions about the report or the services performed during this project, please call Paradigm at (910) 350-1903. We will be happy to answer any questions or concerns which you may have. Thank you for using Paradigm Analytical Labs for your analytical services. We look · forward to working with you again on any additional analytical needs which you may have. ical Laboratories, Inc. N.C. Certification #481 S.C. Certification #99029 1 of 29 I I I I I I I u I I I I I I PARADIGM ANALYfICAL LABORATORIES, INC. Results for Volatiles by GC 602 Client Sample ID: PVMW-010 Client Project ID: NHC Burn Pit Lab Sample ID: G128-1631-1A Lab Project ID: G128-1631 Analyte Benzene Chlorobenzene 1,2-Dlchlorobenzene 1.3-Dichlorobenzene 1,4-Dichlorobenzene Ethylbenzene Toluene m/p-Xylene a-Xylene Surrogate Spike Recoveries Trifluorotoluene Comments: All values corrected for dilution. BQL = Below quantitation limit. Result ug/L BQL BQL BQL BQL BQL BQL BQL BQL BQL Analyzed By: MJC Date Collected: 1113/2005 12:25 Date Received: 11/4/2005 Matrix: Water RL MDL Dilution Date ug/L ug/L Factor •Analyzed 1.00 0.316 1 11/9/2005 1.00 0.298 1 11/9/2005 2.00· 0.608 1 11/9/2005 1.00 0.281 1 11/9/2005 · 2.00 0.56 1 11/9/2005 1.00 0.299 1 • 11/9/2005 1.00 0.302 1 • 11/9/2005 2.00 0.608 1 11/9/2005 2.00 0.596 1 11/9/2005 Spike Spike Percent Added Result Recovery 40 . 40.3 101 Flags Reviewed By: t".'1::::: ·. GC_LIMS_,:Z i2 Of 29 N.C. Certification #481 S.C. Certification #99029 I I I I I I I g D D D I I I I I PARADIGM ANALYTICAL LABORATORIES, INC. Results for Volatiles byGC 602 Client Sample ID: MWD-001 . Client Project ID: NHC Burn Pit · Lab Sample ID: G128-1631-2A Lab Project ID: 8128-1631 Analyte Benzene Chlorobenzene 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1 .4-Dichlorobenzene Ethylbenzene Toluene m/p-Xylene o-Xylene Surrogate Spike Recove_rles Trifluorotoluene Comments: · All values corrected for dilution. BQL.= Below quanlitation limit. Result ug/L BQL BQL BQL BQL BQL 3.77 BQL BQL BQL Analyzed By: MJC Date Collected: 11/3/2005 15:00 Date Received: 11/4/2005 Matrix: Water RL MDL· DIiution Date ug/L Ug/L Factor Analyzed 1.00 0.316 1 1119/2005 1.00 0.298 1 11/912005 2.00 0.608 1 111912005 1.00 0.281 1 11/912005 2.00 · 0.56 1 11/9/2005 1.00 0.299 1 11/9/2005 1.00 0.302 1 111912005 2.00 0.608 1 11/9/2005 , 2.00 0.596 1 1119/2005 Spike Spike Percent Added Result Recovery 40 40.3 101 . Flags Reviewed By: O::'.'::'.'. GC.LIMS.v.>.!3 Qf 29 N.C. Certification #48 I S.C. Certification #99029 I I I I I I I D 0 D I I I I I PARADIGM ANALYTICAL LABORATORIES, INC. Results for Volatiles by GC 602 Client Sample ID: MWD-002 Client Project ID: NHC Burn Pit Lab Sample ID: G128-1631-3A Lab Project ID: G128-1631 Analyte Benzene Chlorobenzene 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Ethylbenzene Toluene m/p-Xylene a-Xylene Surrogate Spike Recoveries T rifluorotoluene Comments: All values corrected for dilution. BQL = Below quantitation limit. Result ug/L BQL BQL BQL BQL BQL BQL BQL BQL BQL Analyzed By: MJC Date Collected: 11/3/2005 18:10 Date Received: 11/4/2005 Matrix: Water RL MDL Dilution Date ug/L ug/L Factor ·Analyzed- 1.00 0.316 1 11/9/2005 1.00 0.298 1 11/9/2005 2.00 0.608 1 11/9/2005 1.00 0.281 1 11/9/2005 2.00 0.56 1 11/9/2005 1.00 0.299 1 11/9/2005 1.00 0.302 1 .· 1 _1 /9/2005 2.00 0.608 1 11/9/2005 2.00 0.596 1 11/9/2005 Spike Spike Percent Ad_ded Result Recovery 40 40.5 101 Flags Reviewed By: r'.'(1 GC_LIMS."24 Of 29 N.C. Certification #481 S.C. Certification #99029 I I I I I I n 0 D I I I I I I PARADIGM ANALYflCAL LABORATORIES, INC. Results for Volatlles byGC 602 Client Sample ID: PVSMW-002 Client Project ID: NHC Bum Pit Lab Sample ID: G128-1631-4...A Lab Project ID: G128-1631 Analyte Benzene Chlorobenzene 1,2-Dichlorobenzene 1.3-Dichlorobenzene 1,4-Dichlorobe·nzene Ethylbenzene Toluene m/p-Xylene o-Xylene Surrogate Spike Recoveries Trifluorotoluene Comments: All values corrected for dilution. BQL = Below quanlitation limit. Result ug/L BQL BQL BQL BQL BQL BQL. BQL BQL BQL Analyzed By: 'MJC Date Collected: 11/3/2005 17:45 Date Received: 11/4/2005 Matrix: Water RL MDL· DIiution Data ug/L ug/L Factor Analyzed 1.00 0.316 1 11/9/2005 1.00 .0.298 1 11/9/2005 2.00 0.608 1 11/9/2005 1.00 0.281 1 11/9/2005 2.00 0.56 1 11/9/2005 1.00 0.299 1 11/9/2005 1.00 0.302 1 11/9/2005 2.00 0.608 1 11/9/2005 2.00 0.596 1 11/9/2005 Spike Spike Percent Added Result Recovery 40 40.5 101 .· Flags Reviewed By: V"'Y GC_LIMS_,2 5 Qf 29 N.C. Certhfication #481 S.C. Certification #99029 I I I I I I a g n D u I I I I I I I PARADIGM ANALYTICAL LABORATORIES, INC. Results for Volatiles by GC 602 Client Sample ID: MWS-003 Client Project ID: NHC Burn Pit Lab Sample ID: G128-1631-5A Lab Project ID: G128-1631 Analyte Benzene Chlorobenzene 1,2-Dichlorobenzene 1,3-Dichlorobenzene · 1,4-Dichlorobenzene Ethylbenzene . Toluene m/p-Xylene o-Xylene Surrogate Spike Recoveries Trifluorotoluene Comments: · All values corrected for dilution. BQL = Below quantitation limit. Result ug/L BQL BQL BQL BQL BQL BQL BQL BQL BQL Analyzed By: MJC Date Collected: 11/3/2005 16:35 Date Received: 11/4/2005 Matrix: Water RL MDL Dilution Date ug/L ug/L Factor Analyzed 1.00 0.316 1 11/9/2005 1.00 0.298 1 11/9/2005 2.00 0.608 1 11/9/2005. 1.00 0.281 1 11/9/2005 2.00 0.56 1 11/9/2005 1.00 0.299 1 11/9/2005 1.00 0.302 1 11/9/2005 2.00 0.608 1 11/9/2005 2.00 0.596 1 1_1/9/2005 Spike Spike Percent Added Result Recovery 40 40.6 102 Flags Reviewed By: ,.,,y • . GC_LIMS_"2 <6 Of 29 N.C. Certification #481 S.C. Certification #99029 I I I I I I g D 0 D E I I I I I I I PARADIGM ANALYTICAL LABORATORIES, INC. Client Sample ID: MWS-004 .. Client Project ID: NHC Burn Pit Lab Sample ID:. G128,1631-6A Lab Project ID: G128-1631 Analyte Benzene Chlorobenzene 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Ethyibenzene Toluene m/p-Xylene o-Xylene Surrogate Spike Recoveries Trifluorotoluene Comments: All values corrected for dilution. BQL = Below quanlilation limit. Results for Volatiles by GC 602 Result ug/L BOL BQL BQL BQL BQL BOL BQL BQL BOL. Analyzed By: MJC Date Collected: 11/3/2005 16:10 Date Received: 11/4/2005 Matrix: Water RL MDL DIiution Date ug/L ug/L Factor Analyzed 1.00 0.316 1 11/9/2004 1.00 0.298 1 11/9/2004 2.00 0.608 1 11/9/2004 1.00 0.281 1 11/9/2004 2.00 0.56 1 11/9/2004 1.00 0.299 1 11/9/2004 1.00 0.302 1 11/9/2004 2.00 0.608 1 11/9/2004 2.00 0.596 1 11/9/2004 Spike Spike Percent Added Result Recovery 40 40.7 102· .. Flags Reviewed By: twY GC_LIMS_,2,v of 29 N.C. Certification #481 S.C. Certification #99029 I I I I a D D I I I I I I I I I I PARADIGM ANALYTICAL LABORATORIES, INC. Results for Volatiles by GC602 Client Sample ID: MWD-006. Client Project ID: NHC Burn Pit Lab Sample ID: G128-1631-7A Lab Project ID: G128-1631 Analyte Benzene Chlorobenzene 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Ethylbenzene Toluene Result ug/L BQL BQL BQL BQL BQL BQL BQL Analyzed By: MJC Date Collected: 11/3/2005 18:30 Date Received: 11/4/2005 Matrix: Water RL MDL DIiution Date ug/L uglL Factor Analyzed 1.00 0.316 1 11/10/2004 1.00 · 0.298 1 11/10/2004 2.00 0.608 11/10/2004 1.00 0.281 1 11/10/2004 2.00 0.56 1 11/10/2004 1.00 0.299 1 11/10/2004 1.00 0.302 1 11./10/2004 Flags m/p-Xylene BQL 2.00 0.608 1 11/10/2004 · a-Xylene 1.73 2.00 0.596 1 11/10/2004 J Surrogate Spike Recoveries Spike Spike Percent Added Result Recovery Trifluorotoluene 40 41.6 104 Comments: All values corrected for dilution. BQL = Below quantitation limit. . Reviewed By: w:t::-::: GC.LIMS_,2 ~ Qf 29 N.C. Certification #481 S.C. Certification #99029 I I I I I g D 0 D I I I I I I I PARADIGM ANALYTICAL LABORATORIES, INC. Results for Volatiles by G_C 602 Client Sample ID: CMW-007 · Client Project ID: NHC Burn Pit Lab Sample ID: G128-1631-8A Lab Project ID: G128-1631 Analyte Benzene Chlorcibenzene 1,2-Dlchlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Ethylbenzene Toluene m/p-Xylene a-Xylene Surrogate Spike Recoveries Trifluorotoluene Comments: All values corrected for dilution. BOL = Below quantitation limit. Result ug/L BOL BQL BQL BQL BQL BQL BQL BQL BQL Analyzed By: MJC Date Collected: 11/3/2005 15:20 Date Received: 11/4/2005 Matrix: Water RL MDL· DIiution Date ug/L ug/L Factor Analyzed 1.00 0.316 1 11/10/2004 1.00 0.298 1 11/10/2004 2.00 0.608 1 11/10/2004 1.00 0.281 1 11/10/2004 2.00 0.56 1 11/10/2004 1.00 0.299 1 11/10/2004 1.00 0.302 1 11/10/2004 2.00 0.608 1 11/10/2004 2.00 0.596 1 11/10/2004 Spike Spike Percent Added Result Recovery 40 41.1 103 -Flags Reviewed By: /v'<./ GC_LIMS."2.'9 Of 29 N.C. Certification #481 S.C. Certification #99029 I I I I g H D E I E I I I I I I I I PARADIGM ANALYTICAL LABORATORIES, INC. Results for Volatiles byGC 602 Client Sample ID: CMW-008 Client Project ID: NHC Burn Pit Lab Sample ID: G128-1631,9A Lab Project ID: G128-1631 Analyte Benzene Chlorobenzene 1,2-Dichlorobenzene Result ug/L BQL BQL BQL Analyzed By: MJC Date Collected: 11/312005 15:45 Date Received: 11/412005 Matrix: Water RL MOL DIiution Date ug/L ug/L Factor Analyzed 1.00 0.316 1 11/10/2004 1.00 0.298 1 11/10/2004 2.00 0.608 1 11/10/2004 Flags 1.3-Dichlorobenzene BQL 1.00 0.281 1 11/10/2004 · 1,4-Dlchlorobenzene BQL 2.00 · 0.56 1 11/10/2004 Ethylbenzene BQL 1.00 0.299 1 11/10/2004 Toluene BQL 1.00 0.302 1 11/10/2004 m/p-Xylene BQL 2.00 0.608 1 11/10/2004 o-Xylene BQL 2.00 0.596 1 11/10/2004 Surrogate Spike Recoveries Spike Spike Percent Added Result Recovery Trlfluoroto_luene 40 41.1 . 103 Comments: ·All values corrected for dilution. BQL = Below quantitation limit. . Reviewed By: ,.,..& GC.LIMS_'2.<7l Q Of 29 N.C. Certification #481 S.C. Certification #99029 I I I I I n D D I I I I I I I I I PARADIGM ANALYTICAL LABORATORIES, INC. Results for Volatiles by GC 602 Client Sample ID: CMW-009 Client Project ID: NHC Burn Pia Lab Sample ID: G128-1631-1 QA Lab Project ID: G128-1631 Analyte Result ug/L Benzene BQL Chlorobenzene BQL 1,2-Dichlorobenzene BQL 1,3-Dichlorobenzene BQL 1,4-Dichlorobenzene BQL. Ethyl benzene BQL Toluene BQL m/p-Xylene BQL o-Xylene BQL Surrogate Spike Recoveries Trlfluorotoluene Comments: All values corrected for dilution. BQL = Below quantitation limit. Analyzed By: MJC Date Collected: 11/3/2005 15:25 Date Received: 11/4/2005 Matrix: Water RL MDL DIiution Date ug/L ug/L Factor Analyzed 1.00 0.316 1 11/10/2004 1.00 0.298 1 11/1012004 2.00 0.608 1 11/10/2004 1.00 0.281 1 11/10/2004 2.00 . 0.56 1 11/10/2004 1.00 0.299 1 11/10/2004 1.00 0.302 1 11/10/2004 2.00 0.608 1 11/10/2004 2.00 0.596 1 11/1012004 Spike Spike Percent Added Result Recovery 40 40.9 102 · Flags Reviewed By: .,...._,,, GC_LIMS_'2.q 1 Of 29 N.C. Cert=:ification #481 S.C. Certification #99029 I I I I 0 D D 11 I I I I I I I I PARADIGM ANALYTICAL LABORATORIES, INC. Results for Volatiles by GC 602 Client Sample ID: PVMW-011 Client Project ID: NHC Burn Pit Lab Sample ID: G128-1631,11A Lab Project ID: G128-1631 Analyte Result ug/L Benzene BQL Chlorobenzene BQL 1,2-Dichlorobenzene BQL 1,3-Dichlorobenzene BQL 1,4-Dichlorobenzene BOL Ethylbenzene BQL Toluene BQL m/p-Xylene BQL a-Xylene BQL Surrogate Spike Recoveries Trifluorotoluene Comments: All values corrected for dilution. BQL = Below quantitation limit. Analyzed By: MJC Date Collected: 11/3/2005 14:10 Date Received: 11/4/2005 Matrix: Water RL MDL DIiution Date ug/L ug/L Factor ·Analyzed 1.00 0.316 1 11/10/2005 1.00 0.298 1 · 11 /1 0/2005 2.00 0.608 1 11/10/2005 1.00 0.281 1 11/10/2005 2.00 0.56 1 11/10/2005 1.00 0.299 1 11/10/2005 1.00 0.302 1 11/10/2005 2.00 0.608 1 11/10/2005 2.00 0.596 1 1,1/10/2005 Spike Spike Percent Added Result Recovery 40 40.5 101 -Flags Reviewed By: ,.,...,,, · . GC.LIMS_,2.012 Of 29 N.C. Certification #481 S.C. Certification #99029 I I I I n D I I I I I I I I I PARADIGM ANALYTICAL LABORATORIES, INC. Results for Volatiles by GC602 Client Sample ID: CMW-012 Client Project ID: NHC Burn Pit Lab Sample ID: G128-1631-12B Lab Project ID: G128,1631 Analyte Result ug/L Benzene BQL Chlorobenzene BQL 1,2-Dichlorobenzene BQL 1,3-Dichlorobenzene BQL 1,4-Dichlorobenzene BQL Ethylbenzene BQL Toluene BQL m/p-Xylene BQL a-Xylene BQL. Surrogate Spike Recoveries Trifluorotoluene Comments: All values corrected for dilution. BQL = Below quantitation limit. Analyzed By: MJC Date Collected: 11/3/2005 14:25 Date Received: 11/4/2005 Matrix: Water RL MDL Dilution Date ug/L ug/L Factor Analyzed 1.00 0.316 1 11/10/2005 1.00 0.298 1 11/10/2005 2.00 . 0.608 1 11/10/2005 1.00 0.281 1 11/10/2005 2.00 0.56 1 11/10/2005 1.00 0.299 1 11/10/2005 1.00 0.302 1 11/10/2005 2.00 0.608 1 11/10/2005 2.00 0.596 1 11/10/2005 Spike Spike Percent Added Result Recovery 40 40.5 101 Flags Reviewed By: r":'.':::'. GC_LIMS_'2.013 Of 29 N.C. Certification #481 S.C. Certification #99029 I I I I I D 0 I I I I I I I I I PARADIGM ANALYTICAL LABORATORIES, INC. Results for Volatiles by GC 602 Client Sample ID: CMW-013. Client Project ID: NHC Bum Pit Lab Sample m: G128-1631-13B Lab Project ID: G128-1631 Analyte Result ug/L Benzene BQL Chlorobenzene BQL 1,2-Dichlorobenzene BQL 1,3-Dichlorobenzene BQL 1,4-Dichlorobenzene BQL Ethylbenzene BOL Toluene BQL m/p-Xylene BQL o-Xylene BQL Surrogate Spike Recoveries Trifluorotoluene Comments: All values corrected for dilution. BQL = Below quantitation limit. Analyzed By: MJC Date Collected: 11/3/2005 13:10 Date Received: 11/4/2005 Matrix: Water RL MDL DIiution Date ug/L ug/L Factor Analyzed 1.00 0.316 1 11/10/2005 1.00. 0.298 1 11/10/2005 2.00 0.608 1 11/10/2005 1.00 0.281 1 11/10/2005 2.00 0.56 1 11/10/2005 1.00 0.299 1 11/10/2005 1.00 0.302 1 11/10/2005 2.00 0.608 1 11/10/2005 2.00 0.596 1 11/10/2005 Spike Spike Percent Added Result Recovery 40 40.4 101 . Flags Reviewed By: i,,-,v GC_LIMS."1."14 Of 29 N.C. Certification #481 S.C. Certification #99029 I I I I I u D I I I I I I I I PARADIGM ANALYfICAL LABORATORIES, INC. Results for Volatiles by GC 602 Client Sample ID: PVMW-014 Client Project ID: NHC Bum Pit Lab Sample ID: G128-1631~14B Lab Project ID: G128-1631 Analyte Result ug/L fiBenzeneJ~~\ffl'jl£~-~l3312~ Chlorobenzene BQL 1,2-Dichlorobenzene BQL 1,3-Dlchlorobenzene BQL 1,4-Dichlorobenzene BQL Ethylbenzene 0.319 Toluene BQL m/p-Xylene BQL a-Xylene BQL. Surrogate Spike Recove_rles Trifluorotoluene Comments: All values corrected for dilution. BOL = Below quanlitalion limit. Analyzed By: MJC Date Collected: 11/3/2005 17:20 . Date Received: 11/4/2005 Matrix: Water RL MDL· DIiution Date ug/L ug/L Factor Analyzed 1.00 0.316 1 11/11/2005 1.00 0.298 1 11/11/2005 2.00 0.608 1 11/11/2005 1.00 0.281 1 11/11/2005 2.00 · 0.56 1 11/11/2005 1.00 0.299 1 11/11/2005 1.00 0.302 1 11/11/2005 2.00 0.608 1 11/11/2005 2.00 0.596 1 11/11/2005 Spike Spike Percent Added Result Recovery 40 40.0 100 • Flags J Reviewed By: ,.,./4/ . GC.UMS_,2.015 Of 29 N.C. Certification #481 S.C. Certification #99029 I I I I I n D D I I I I I I I PARADIGM ANALYTICAL LABORATORIES, INC. Results for Volatiles by GC 602 Client Sample ID: PVMW-015 . Client Project ID: NHC Bum Pit Lab Sample ID: G128-1631,15B Lab Project ID: G128-1631 Analyte Result ug/L Benzene BQL Chlorobenzene BQL 1,2-Dichlorobenzene BQL Analyzed By: MJC Date Collected: 11/3/2005 16:55 Date Received: 11/4/2005 Matrix: Water RL MDL DIiution Date ug/L ug/L Factor Analyzed 1.00 0.316 1 11/11/2005 1.00 0.298 1 11/11/2005 2.00 0.608 1 11/11/2005 . Flags 1,3-Dichlorobenzene BQL 1.00 0.281 1 11/11/2005 · 1,4-Dichlorobenzene BQL 2.00 0.56 1 11/11/2005 Ethylbenzene BQL 1.00 0.299 1 11/11/2005 Toluene BQL 1.00 0.302 1 11/11/2005 m/p-Xylene BQL 2.00 0.608 1 11/11/2005. a-Xylene BQL 2.00 0.596 1 11/11/2005 Surrogate Spike Recoveries Spike Spike Percent Added Result Recovery Trifluorotoluene 40 40.7 1.02 Comments: All values corrected for dilution. BQL = Below quantitation limit. Reviewed By: tr:<-:::: GC.LIMS.,20l5 Qf 29 N.C. Certification #481 S.C. Certification #99029 I I I I I I n D I I I I I I I I PARADIGM ANALYTICAL LABORATORIES, INC. Results for Volatiles by GC 602 Client Sample ID: CMW-016 · Client Project ID: NHC Burn Pit Lab Sample ID: 8128-1631-168 Lab Project ID: 8128-1631 Analyte Result ug/L Benzene BQL Chlorobenzene BQL 1.2-Dichlorobenzene BQL 1,3-Dichlorobenzene BQL · · 1,4-Dichlorobenzene BQL Ethylbenzene BQL Toluene BQL m/p-Xylene BQL o-Xylene BQL Surrogate Spike Recoveries Trifluorotoluene Comments: All values corrected for dilution. BQL = Below quantitation limit. Analyzed By: MJC Date Collected: 11/3/2005 17:10 Date Received: 11/4/2005 Matrix: Water RL MDL· Dilution Date ug/L ug/L Factor Analyzed 1.00 0.316 1 11/11/2005 1.00 0.298 1 11/11/2005 2.00 0.608 1 11/11/2005 1.00 0.281 1 11/11/2005 2.00 0.56 1 11/11/2005 1.00 · 0.299 1 11/11/2005 1.00 0.302 1 11/11/2005 2.00 0.608 1 11/11/2005 2.00 0.596 1 11/11/2005 Spike Spike Percent Added Result Recovery 40 40.5 101 · Flags Reviewed By: ~ GC_LIMS_,2.1117 Qf 29 N.C. Certification #481 S.C. Certification #99029 I I I I I n D I I I I I I I PARADIGM ANALYfICAL LABORATORIES, INC. Results for Volatlles by GC 602 Client Sample ID: Method Blank Client Project ID: Lab Sample ID: VBLK3110905A Lab Project ID: Analyte Result ug/L Benzene BQL Chlorobenzene BQL 1,2-Dichlorobenzene BQL 1,3-Dichlorobenzene BQL 1,4-Dichlorobenzene BQL Ethylbenzene BQL Toluene BQL m/p-Xylene BQL a-Xylene BQL Surrogate Spike Recoveries Trifiuorotoluene Comments: ·All values corrected for dilution. BQL = Below quantitation limit. Analyzed By: MJC Date Collected: Date Received: Matrix: Water RL MDL Dilution ug/L ug/L Factor 1.00 0.316 1 1.00 0.298 1 2.00 0.608 1 1.00 0.281 1 2.00 0.56 1 1.00 0.299 1 1.00 0.302 1 2.00 0.608 1 2.00 0.596 1 Spike Spike Added Result 40 40.3 N.C. Cenification #481 S.C. Certification #99029 Date Analyzed . Flags 11/9/2005 11/9/2005 11/9/2005 1119/2005 1119/2005 111912005 · 1119/2005 11/9/2005 . 111912005 Percent Recovery 101 Reviewed By: f-1'-/ GC.LIMS.,2 ~ 8 Of 29 I I I I I I D u I I I I I I I I I I PARADIGM ANALYfICAL LABORATORIES, INC. Results for Volatlles byGC 602 Client Sample ID: Method Blank· Client Project ID: Lab Sample ID: VBLK1110905B Lab Project ID: Analyte Result ug/l Benzene BQL Chlorobenzene BQL 1,2-Dichlorobenzene BQL 1,3-Dichloroben.zene BQL · 1,4-Dichlorobenzene BQL Ethylbenzene BQL Toluene BQL m/p-Xylene BQL o-Xylene BQL Surrogate Spike Recoveries Trifluorotoluene Comments: All values corrected for dilution. BQL = Below quantitation limit. Analyzed By: MJC Date Collected: Date Received: Matrix: Water RL MDL. DIiution ug/L ug/L Factor 1.00 0.316 1 1.00 0.298 1 2.00 0.608 1 1.00 0.281 1 2.00 0.56 1 1.00 0.299 1 1.00 0.302 1 2.00 0.608 1 2.00 0.596 1 Spike Spike Added Result 40 40.6 N.C. Certification #481 S.C. Certification #99029 Date Analyzed . . Flags 11/9/2004 11/9/2004 11/9/2004. 11/9/2004 11/9/2004 11/9/2004 11/9/2004 11/9/2004 11/9/2004 Percent Recovery 101 Reviewed By: ~ GC_LIMS_.2.itl 9 Qf 29 I I I I I I n D I I I I I I I I I I PARADIGM ANALYTICAL LABORATORIES, INC. Results for Volatiles byGC 602 Client Sample ID: Method Blank Client Project ID: Lab Sample ID: VBLK3111005B Lab Project ID: Analyte Result ug/L Benzene BQL Chlorobenzene BQL 1,2-Dlchlorobenzene BQL 1,3-Dichlorobenzene BQL 1,4-Dichlorobenzene BQL Ethylbenzene BQL Toluene BQL m/p-Xylene BQL o-Xylene BQL Surrogate Spike Recoveries Trifluorotoluene Comments: · All values corrected for dilution. BQL = Below quantitation limit. N. C. Certification #481 Analyzed By: MJC Date Collected: Date Received: Matrix: Water RL MDL DIiution ug/L ug/L Factor 1.00 0.316 1 1.00 0.298 1 2.00 0.608 1 1.00 0.281 . 1 2.00 . 0.56 1 1.00 0.299 1 1.00 0.302 1 2.00 0.608 1 2.00 0.596 1 Spike Spike Added Result 40 40.3 S.C. Certification #99029 Date Analyzed . Flags 11/10/2005 11/10/2005 11/10/2005 11/10/2005 11/10/2005 11/10/2005 11/10/2005 11/10/2005 11/10/2005 Percent Recovery 101 Reviewed By: M/ GC_LIMS_,:1.<2Q Of 29 I I I I I I I D u E I I I I I PARADIGM ANALYTICAL LABORATORIES, INC. Control Llrnlts for QC Check / Laboratory Control Spike Method: 602 Splkejppb) : 10 Instrument: gc3 FIiename : 110905\005r0101.txl QC Llmtt1 LCS Limit• Comnnund Benzene . ChlorobenZene 1,2-Dlchlorooenzene 1,3-Dlchlorobenzene 1,4-Dlchlorobenzene DIIBOpropyl ether Ethylbenzene MTBE Toluene m,p-Xylene o-X•ne Flag•: + = out of QC limits. • = lab generated limits. o = Detected n= Ql%l 9,9 89.2 1.8 97.8 10.1 100.8 8,7 87.0 8.8 88.3 u 81.1 10.2 101,8 . 8,7 87.o 10,0 89.6 20A 101.8 10.0 98.e Lower Un-• P,1%) Lower un-r 77.0 123.0 88 38 1eo 8o.e 11U 81 ee 138 68.0 132.0 101 37 1114 72.1 127.e 87 eo 141 6U 130.1 88 42 143 43,1 1H.8 81 30 170 83.0. 137J> 102 32 180 48.8 113.2 87 31 1&e 11.e 127.0 100 48 148 11.2 181.8 102 D 238 47.6 112A 100 36 1114 Reviewed by: iv-{., N.C. Certification #481 S.C. Certification #99029 21 of 29 I I I I I 0 I I I I I I I I I I PARADIGM ANALYTICAL LABORATORIES, INC. Control Limits for MS-MSD Method: 602 Splke[ppb) : 10 lnstnnnent: gc3 Sample: 110905\022r0101.txl MS: 110905\023r0101.txl MSD • 110905\024r0101 txl Comoound Sam. Benzene Chlorobenzena 1 ,2·Dlchlorobenzene 1,3--Dlchlorobenzene 1,4-Dlchlorobenzene Dllaopropyl ether Ethylbenzene MTBE Toluene m,p-Xylene o-Xvlana Flags: + = out of QC limits. • = lab generated llmlts. o = · Detected ND = None Detected ND ND ND ND ND NO ND ND ND ND ND UDll MS MSD MS 10.2 10.1 102 8.7 8.8 87 8.2 8.8 12 8.6 8.2 81 8.0 8.8 80 8.1 1.8 11 10,3 10.1 103 8.8 1.7 88 10.1 10.1 101 20.4 20., 102 8.7 8,6 87 PIil .Pllmlte MBD Lower Un-• 101 38 1150 88 66 136 . 88 37 1114 82 60 141 88 42 143 88 30 170 101 32 180 87 36 116 101 48 1 .. 100 D 238 86 38 1114 Reviewed by: ...,..,_.., N.C. Cenification #481 S.C. Certification #99029 22 of 29 I I I I I I n D I I I I I I I PARADIGM ANALYTICAL LABORATORIES, INC. Control Limits for QC Check / Laboratory Control Spike Method: 602 Splke[ppb]: 10 Instrument : gc1 Filename · 110905\027nl 101 txt QC Limits LCS Limits Compound Benzene Chlorobenzen8 1,2-Dichlorobenzene 1,3-Dlchlorobenzene 1,4-0lchlorobenzene D\isopropyl ether Ethylbenzene MTBE Toluene m,p-Xylene o-Xvlene Flags: + = out of QC limits. , = lab generated limits. o = Detected nnb Qlo/,\ 10.3 103.2 9.4 94.0 8.8 88.4 8.8 87.9 8.8 86.1 9.3 , 92,6 9.7 97.4 · 10.s 105.1 9.9 98.7 19.2 96.0 9.2 91.8 Lower U"-"er P,(¼) Lower Un""r 77.0 123.0 103 39 150 80.5 119.5 94 55 135 68.0 132.0 88 37 154 72.5 127.5 88 50 · 141 89.5 130.5 88 42 143 43.1 156.9 93 30 170 63.0 137.0 97 32 180 48.8 153.2 105 35 185 77.5 127.0 99 46 148 11.2 188.6 96 D ·239 47.6 152,4 92 36 164 Reviewed by: v:'::: N.C. Certification #481 S.C. Certification #99029 23 of 29 I I I I I I I I D u I I I I I I I PARADIGM ANALYTICAL LABORATORIES, INC. Control Limits for MS-MSD Method: 602 Splka[ppb]: 10 Instrument: gc1 . Sample: 1109051045r0101.txt MS: 110905\049r0101.txt MSD: 110905I050r0101.txt Compound Sam. Benzene . ChlorobenZene 1,2-Dlchlorobenzene 1,3-Dichlorobenzene 1,4-Dlchlorobenzen8 Dilsopropy\ ether Ethy\benzene MTBE Toluene m,p-Xy\ene o-Xylene . Flags: · + = out of QC limits. • = lab generated limits. o = Detected ND = None Detected ND ND ND ND ND ND ND ND ND ND ND ~g/L .p MS MSD MS 10.1 10.3 101 9.8 10.0 98 9.5 9.4 95 9.7 9.7 97 9.6 9.7 96 10.4 10.1 104 10.0 10.1 100 10.3 10.2 103 9.9 10.2 99 20.0 20.1 100 9.9 9.9 99 '/,} P Limits MSD Lower Un=r 103 39 150 100 55 135 94 37 154 97 50 141 97 42 143 101 30 170 101 32 160 102 35 165 102 46 148 100 D 239 99 36 164 Reviewed by: : tv'<-- N.C. Certification #481 S.C. Certification #99029 24 of 29 I I I I I I I I g 0 D I I I I I I I PARADIGM ANALYTICAL LABORATORIES, INC. Control Limits for QC Check/ Laboratory Control Spike Method: 602 Splke(ppb] : '10 lnstnmenl : gc3 FIiename • 111005\024r0101 bet QC Limits LCS Limits Comnnund Benzene ChlofObenzena 1,2-Dlchlorobenzane 1,3-Dlchio<ooonZene 1,4-0lchlorobel'\Zene Dllsopropyl other Ethyl benzene MTBE Toluene m,p-Xytane o-Xvt.na Flag■: + " out of QC limits. • = lab generated limits. o = Detected nnb Ql'lll 10.4 10U 10.1 101.2 10.2 101.8 10.0 II.I 10.1 100.9 8.8 Bl.I 10.1 104.1 10.1 101.J 10.3 103.3 21.0 101.1 10.2 102.1 Lower U•-r p_ .... , Lower U•- 77.0 12U 104 H 1IO ID.I 111.1. 101 II 1:sll 88.0 132.0 102 37 114 72.1 127.1 100 10 141 81.1 1SO.I 101 42 143 43.1 118.8 88 30 170 13.0 137.0 101 32 1IO 48.8 113.2 101 31 181 77.1 127.0 103 48 148 11.2 188.8 101 D 2:111 47.8 112.4 102 38 184 Reviewed by: w{,,; N.C. Certification #481 S.C. Certification #99029 25 of 29 I I I I I I n D I I I I I I I PARADIGM ANALYTICAL LABORATORIES, INC. Control Limits for MS-MSD Mot hod: 602 Splke[ppb) : 10 Instrument : gc3 Sample: 111005\039r0101 .bd MS: 111005\040r0101.bd MSD• 111005\041r0101 txl Comnaun<t Sam. Benzene Chlon>benzene 1,2-Dlchlo,obenzane 1,3-Dlchlo,_nzene 1,4-Dlch-nzena Diiaopropyl ell1er Elhylbanzene MTBE Toluene m,p-Xylene o-Xvlena Fle!P: + = out of QC limits. • = lab generated limits. D = Detected ND = None Detected 2U ND ND ND ND ND 1.8 2A ND 1.0 ND """ MS MSD MS 31.8 32.0 1oe 10.0 10.1 100 9.8 1M 18 9A 1.7 84 8.8 1.1 87 10.8 10.1 II 12,3 12.1 101 12.4 12.7 101 10.8 11.a 101 22.0 22A 101 ' 11.1 11.3 101 p •• ·PL.lmlU MSD Lower u- 107 31 150 101 H 131 . 100 37 154 17 IO 141 IO 42 143 102 30 170 107 .32 180 103 31 181 107 48 i 107 D 104 38 184 Revlowed by. 1,/'-G/ N.C. Certification #481 S.C. Certification #99029 26 of 29 I I I I I I I I I I I I D D D D PARADIGM ANALYTICAL LABORATORIES, INC. List of Reporting Abbreviations and Data Qualifiers B = Compound also detected in batch blank BQL = Below Quantitation Limit OF = Dilution Factor Dup = Duplicate D = Detected, but RPO is > 40% between results in dual column method. E = Estimated concentration, exceeds calibration range. .J = Estimated concentration, below calibration range and above MDL LCS(D) = Laboratory Control Spike (Duplicate) MDL = Method Detection Limit MS(D) = Matrix Spike (Duplicate) POL = Practical Quantitation Limit RL = Reporting Limit RPO = Relative Percent Difference · mg/kg = milligram per kilogram, ppm, parts per million ug/kg = micrograms per kilogram, ppb, parts per billion mg/L = milligram per liter, ppm, parts per million ug/L = micrograms per liter, ppb, parts per billion % Rec = Percent Recovery % soilds = Percent Solids Special Notes: 1) Metals and mercury samples are digested with a hot block, see the standard operating procedure document for details. 2) Uncertainty for all reported data is less than or. equal to 30 percent. N.C. Certification #481 S.C. Certification #99029 M134.092205.2 27 of 29 PARADIGM ANALYTICAL LABORATORIES, INC. 5500 _Business-Brive,Wilmington, NC 28405-Chain-of Custody Record & Analytical Request · Phone: (910)-350-1903 FAX: (910)-350-1557 Client: · Project ID: HH c Jl,,,;XN 7:..,-N-.v · 1'1· 0£ Turnaround: ~S,._.7A"""Hu41>"""'ABP""""'-- Job Number: ~l~2~'f,_,'-'fl."-<£~i'---- P.O Number: ._ ·zs I /rj_c, -z Date: Address: ~ t?! D ;;:, .. ;«'( e,o, . L Address: l.llt.m. NC . Quote#: " 'PVMW-m I .I. II•!>·~ 11.'l.5' ,t::'"' ts ff o,17> -d. ,I, I /5</,,) ""J) . ch" z.. 18 I 'f! ~-¢,clz. l'I.,, <1'1Wf, ·cbl63 '"3<. :;; t.:'/1 W S -t!,,J '1 I' l,t, Q < .... ,, , . -.... - 'i:i:; rfW:J> • <J~, l8Ja C~w -t:&S-, /5Z.~ . IS'/$ Contact: Z iey 44'6 Tr Phonief, o ) 't.S:Z.• 5'6'"( . :> Fax· PnBervutiYes ... • N 0 \t .. ~· ~- .,,, ✓ ✓ ✓ t/ ./ . +" ✓ ..... f ✓ . I • COC# 52316 Page / of t.. Report To: CATLlH. 4-Tv r tz.,·g, G+tu:r. If , Invoice To: CA'rJH ~ ~ ,:5,-icA Comments: Plea'ie specify ~y special reporting I C1'1w -¢,a'>8 ·a ·lJy Date Time Received By Date Time !Iemperature State Certification Requested i_U,.,/-;;' It-• -,s-' ()OC) !/-,. A /l ,1/ .4/2 t1/ SEE REVERSE FOR TERMS AND CONDITIONS PARADIGM ANALYTICAL LABORATORIES, INC. 5500 Business Drive, Wilmington, NC 28405 Chain-of Custody Record & Analytical Request Phone: (910)-350-1903 FAX: (910)-350-1557 Client: CA:rLut €HI$. ~ S-c:.c . I Project m, NJ.le. :r:...IZH 1',-r Date: -~''~·-'1~---,,,ef~~~-- Address: Z.Z.\(> <=><..:z> -:z,..;g.'J" RP-Contact, ll.'oc ~AC&e::rf Turnaround: ~.S~nu~~P~-1£ ....... ~P __ Address: l.t./,•,_ ,YC Phone, (!110 \ '.Y5l,.S8':il-Job Number: #"!'f-~'<L > ~~~~~-- Quote#: . Fax· P.O Number-Z.5//<fo{ • o L-. . . J -~:,1·· . . . ~es Anal ...... ~ • ' ~.., ... , . . . . . t . ·.~·· •• :-.1-,;.._. .• ,-:;_ • -.. . . -~•-•J-:.~. ~ ~ N /] () . . • • •,••. ,, ·1 : ,.. ' ·--' ' \I' ~ --· .. -.-·_ '~}Si;.; -•.)·. -~: '' .: . ; . f. _,c,· .;.~-. • . ., .... f-,. ;. •\· ·. IJC,I-' . ~: ~ :, . -. 'II ~CMK-~-'-t ✓ ~ 1/•J-rJ..~ /fl.&" ~'4) . ~ n . . IU~ . -_... IL.I f'Vl'-1W-dJ II l~IP . ✓ ~ v ~C~w .d,.,z... I'll-~ ' ✓ ~CHu-dJ1.3 (?, I <I:. ! ✓ ' i ~PvHW" I .I -¢,,.,. IIJ'U I I Q ✓ ~,,.1'1 ,J -tf,,~ 16~~ «; . ~ J ,.,,4 If \/ CMw-mtfo ~By Date Tone Received By Date Tone' Tumperature -COC# 5231 7 Page '2.. of :t. . . Invoice To· ~,"'N ATFII • !:He/._._ Comments: Please specify any spedal n:porting . reouirements Cr zS '--'I ( 3/ ., f,,,,..,..~ £DD Fo-' -. .;, a ... "Rirr l4>.., -~u_,yr 0 ,A/C-s~ ,G.,.--.N.J A £..,.- • ~02-J!,u(t,r />,·-,, t.i:. -r . . State Certification Requested · <di -d_ If• .,,,..k-I,.,_ ~-/_/__fl -tf'yJor' /oo> ,.,; ~~ NC i/ SC Other /"/ I?-" ~ . c:;-rr' r SEE REVERSE FOR --TERMS AND CONDffiONS OR\GINAl N 0 CJ) N . °' N 0 °' i C: 0 ·~ u ,;::: '€ " u (..) Cl) I I I I I I I I I I I g I n n D APPENDIXB BENZENECONCENTRATIONS VS. TIME GRAPH New Hanover County Burn Pit; 94040 mon rpt NOV0S CATUN Project No. 194-040 CATUN Engineers and Scientists December 2005 --l!!!!!!l!!!I l!!!!I !!!!!!!I l!!!!!!I -ma liiiiiil iiiil iiii iilll - - -...J 0, :::, -C 0 :;::; I'll ... -C Cl) 0 C 0 0 Benzene Concentrations vs. Time New Hanover County Airport Burnpit Superfund Site 120 100 80 60 40 20 NOTE: Only wells exhibiting Benzene concentrations above the 2L GWQS are shown. Date - - - - - -+-·-MWD-001 --O--MWD-002 -u--MWS-003 -MWD-006 -PVMW-011 e PVMW-014 -+--PVMW-015 · · · · · ·2L GWQS = 1 ug/L