NCD982096653_20071129_Ram Leather Care Site_FRBCERCLA FS_Draft Evaluation Report RI FS Groundwater Sampling (Revision 0)-OCR

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Data Evaluation Report
Remedial Investigation/Feasibility Study
Groundwater Sampling
(Revision 0)
Ram Leather Care Site
Charlotte, Mecklenburg County, North Carolina
November 2007
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DATA EVALUATION REPORT
Remedial Investigation/Feasibility Study
Groundwater Sampling
Revision 0
Ram Leather Care Site
Charlotte, Mecklenburg County, North Carolina
U.S. EPA Work Assignment No. 697-RICO-A419
Black & Veatch Project No. 048697.0106
Prepared under
EPA Contract No. 68-W-99-043
November 2007
Prepared by
Black & Veatch Special Projects Corp.
1120 Sanctuary Parkway, Suite 200
Alpharetta, Georgia 30004
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Data Evaluation Report S1..-ction: TOC
Revision;()
Nov1..,nbcr 29, 2007
EPA Contr.ic1 No. 68-W-99-043
Work Assignment No. 097-RICO-A4 I 9
Ram Ll·athcr Care Site
CONTENTS
Acronyms and Abbreviations ...................................................................................... AA-I
1.0 Introduction ............................................................................................................... 1-1
1.1 Purpose and Scope of Data Evaluation Report ........................................... 1-1
1.2 Report Organization .................................................................................... 1-2
2.0 2007 Field Investigation Data Acquisition .............................................................. 2-1
2.1 Monitoring Well Sampling ......................................................................... 2-I
2.2 Residential Well Sampling ......................................................................... 2-2
2.2.1 Residential Wells Not Sampled ...................................................... 2-2
2.2.2 Dechlorination Filters Installed by EPA ......................................... 2-3
2.2.3 Residential Wells Without EPA Filters .......................................... 2-3
2.3 Quality Assurance/Quality Control (QA/QC) Samples .............................. 2-3
2.4 Investigation-Derived Waste ...................................................................... 2-4
3 .0 Data Reduction, Tabulation, and Evaluation ........................................................... 3-1
3. I Groundwater Field Data ................................................................................ 3-1
3.2 Analytical Data ............................................................................................. 3-1
3.2.1 Data Qualifiers ................................................................................ 3-1
3.2.2 Groundwater Analytical Data -Monitoring Wells ......................... 3-2
3.2.3 Groundwater Analytical Data -Residential Wells ......................... 3-3
4.0 Data Usability .......................................................................................................... 4-1
4.1 2007 RI/FS Data ......................................................................................... 4-1
4. I. I Field Data ........................................................................................ 4-1
4.1.2 Chemical Analytical Data ............................................................... 4-2
5.0 Data Evaluation Summary ...................................................................................... 5-1
6.0 References ......................................................................................................... 6-1
Tables
Table 2-1
Table 3-1
Table 3-2
Table 3-3
Table 3-4
Sample Codes, Sample Activities, Locations, and Rationale
Final Monitoring Well Field Parameters (2007)
Final Potable Well Field Parameters (2007)
Monitoring Well Analytical Results ( 1991 -2007)
Residential Well Analytical Results (1991 -2007)
TC-I
Data Evaluation Report Section: TOC
EPA Contrnct No. 68-W-99-043 Revision: O
Work Assignment No. 697-RIC0-A419 Novcmbcr 29. 2007
Ram Leather Care Site
CONTENTS (Continued)
Figures
Figure 1-1 Site Vicinity Map
Figure 2-1 Monitoring Well Locations and VOC Results
Figure 2-2 Residential Well Locations and VOC Results
Appendices
Appendix A Groundwater Collection Records and Potable Well Sampling Forms
Appendix 8 2007 Analytical Data Packages
Appendix C 2007 Data Validation Reports
TC-2
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Data Ev;iluation Report
EPA Contmct No. 68-W-99-043
Work A:-.signmcnt No. 697-RICO-t\4 \ 9
Ram leather Can: Site
Black & Veatch
bis
BOA
cis-1,2-DCE
DER
DO
DOT
EPA
FS
FSP
IDW
MCL
µg/L
Acronyms and Abbreviations
Black & Veatch Special Projects Corp.
below land surface
Basic Ordering Agreement
cis-1,2-dichloroethene
Data Evaluation Report
dissolved oxygen
U.S.· Department of Transportation
U.S. Environmental Protection Agency
Feasibility Study
Field Sampling Plan
investigation-derived waste
Maximum Contaminant Levels
microh'fams per liter
S1..-ctinn: AA
Revision: 0
NovLinhcr 29. 2007
NCDENR
redox
North Carolina Department of Environment and Natural Resources
oxidation-reduction
PCE
PPE
QA
QC
RA
RAC
RI
RPM
SAP
SESD
sow
SQL
TCE
vc
voe
tetrachloroethene
personal protective equipment
quality assurance
quality control
remedial action
Remedial Action Contract
Remedial Investigation
Remedial Project Manager
Sampling and Analysis Plan
U.S. EPA Science and Ecosystem Support Division
Statement of Work
Sample quantitation limit
trichloroethene
vinyl chloride
volatile organic compound
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Data Evaluation Rcpon
EPA Contrni.:t No. 68-W-99-043
Work Assignment No. 697-RICO-A419
Ram Leather Care Site
1.0 Introduction
Si..-ctinn: I
Revision: 0
Novtinbcr 29, 2007
This data evaluation report (DER) has been prepared in accordance with the Remedial
Investigation/Feasibility Study (RI/FS) Work Plan, Revision 0, dated November 2006 for
the Ram Leather Care site (Black & Veatch, 2006a). All activities were performed in
accordance with the work plan and the September 27, 2006, U.S. Environmental
Protection Agency (EPA) Statement of Work (SOW) for the RI/FS at the Ram Leather
Care site located in Charlotte, Mecklenburg County, North Carolina. A site vicinity map
is presented as Figure 1-1.
This DER evaluates the usability of groundwater monitoring well and potable well data
collected during sampling conducted September 2007. Data will be used to prepare an
RI/FS Report Addendum. Black & Veatch Special Projects Corp. (Black & Veatch) is
performing the Ram Leather Care RI/FS under EPA Region 4 Remedial Action Contract
(RAC) No. 68-W-99-043, Work Assignment No. 697-RICO-A419.
1.1 Purpose and Scope of Data Evaluation Report
The purpose of the DER is to compile, organize, and evaluate data usability to generate
RI/FS project reports. This DER presents historical data and summarizes and evaluates
the following information from the September 2007 sampling event:
• Descriptions and summary tables of actual sampling locations, rationale for
locations, and sample location maps.
• Field measurements for groundwater.
• Laboratory reports and summary tables of detected contaminant concentrations.
• Data validation and usability oflaboratory data.
• Data evaluation in terms of usability for RI/FS efforts.
This DER does not provide a description of historical sampling events at the Ram Leather
Care site; a detailed description of previous sampling events and data is presented in the
Remedial Investigation Report for Ram Leather Care Site, dated January 2005 (COM,
2005). Historical data will be included in the DER analytical data tables for comparison.
1-1
Data Evaluation Report
EPA Contract No. 68-W-99-043
Work Assignment No. 697-RICO-A419
Ram Leather Care Site
1.2 Report Organization
Section: I
Revision: 0
Nov1.-mbcr 29. 2007
Section I of this report outlines the purpose of this document. Section 2 summarizes the
acquisition of data in September 2007. Section 3 presents data evaluation, tabulation, and
interpretation from the 2007 sampling event. Section 4 summarizes and evaluates the
usability of analytical and field data generated during the 2007 field investigation.
Section 5.0 provides a data evaluation summary. Section 6 lists references. All tables,
figures, and appendices are presented at the end of the report.
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Data Evaluation Report
EPA Contmct No. 08-W-99-043
Work Assignment No. 697-RICO-A419
Ram L . .'athcr Care Site
2.0 2007 Field Investigation Data Acquisition
Section: 2
Rt·vision: 0
Nov1.inhcr 29, 2007
Specific activities performed at the Ram Leather Care site in September 2007 included
field personnel mobilization, collection of b'fOundwater sampling from existing
monitoring wells, residential well sampling, investigation-derived waste (IDW) staging,
and laboratory sample analyses.
Residential well sampling was conducted in accordance with the Sampling and Analysis
Plan (SAP): Volume l -Field Sampling Plan (FSP), Revision 0, dated December 2006
(Black & Veatch, 2006) and the Well Survey and Proposed Potable Well Sampling
Technical Memorandum (Black & Veatch, 2007).
At the request of the EPA Remedial Project Manager (RPM), Black & Veatch also
collected groundwater samples from existing monitoring wells associated with the Ram
Leather Care site in support of EPA 's groundwater remedial action (RA) at this site.
Sampling activities were conducted in accordance with the EPA Science and Ecosystem
Support Division (SESD) Operating Procedures (EPA, 2007a through f). All samples
were analyzed for volatile organic compounds (VOCs) (SW-846 Method 82608) and
analyzed by one of Black & Veatch's subcontracted [Basic Ordering Agreement (BOA)]
laboratories.
2.1 Monitoring Well Sampling
At the request of the EPA RPM, Black & Veatch collected b'foundwater samples from
eight monitoring wells in support of the groundwater RA. This monitoring sampling
event served as the baseline monitoring proposed in Section 4.8 of the Pre-Final Design
Report for the Groundwater Interim Remedy (Black & Veatch, 2006b ). The Pre-Final
Design Report proposes baseline monitoring of the former onsite drinking water well
(DWl l), 4 onsite monitoring wells (MW-1, MW-2, MW-3, and MW-2D), 3 offsite
monitoring wells (MW-lD, MW-3D, and MW-4D), and 5 residential wells in the
surrounding area (Segrest, Glosson, Ivey, Beaver, and Tucker) for VOCs prior to the start
of the groundwater interim RA (Figure 2-1 ). Monitoring well sample rationale is
included on Table 2-1.
2-1
Data Evaluation Report
EPA Contrne1 No. 68-W-99-043
Work Assignment No. 697-RICO-A419
Ram Leather Care Site
Section: 2
Revision: 0
Novl'lTiher 29, 2007
MW-3 was observed as nearly dry, with approximately 0.4 feet of water in the bottom of
the well; therefore, MW-3 was not sampled. MW-I contained approximately 7 feet of
muddy/silty water in the bottom of the well; this well was redeveloped prior to sampling.
MW-ID and MW-4D (both I 82 feet deep) experienced severe drawdown and extremely
slow recharge. These two wells were purged dry and were sampled after several hours of
recharge allowed collection of adequate sample volume. DWI I, MW-2, MW-2D, and
MW-3D were sampled without encountering any problems.
2.2 Residential Well Sampling
A total of 14 residential wells were sampled during the September 2007 RVFS sampling
event. For all residential wells sampled, Table 2-1 describes the sample ID, resident's
name, resident's address, type of analysis, sample date, and sample time. Figure 2-2
shows the locations of the potable wells. For each residential well sample, a "Potable
Well Sampling Form" was filled-out, and is attached as Attachment A. Each "Potable
Well Sampling Form" provides resident information, well information, purge data, and
sampling information. Many residences expressed concern about wasting water, so only
minimal water was allowed to be purged from these residences' wells. It should be noted
that sample quality at these residences may have been affected because the wells were
purged for less than 15 minutes as described in Section 4.1.1.1. Total purge estimates are
noted under the "purge data" of each "Potable Well Sampling Form".
Several access agreements were faxed to Black & Veatch prior to mobilization to the site,
and EPA Public Affairs Specialist, Angela R. Miller, was onsite to obtain remaining
access agreements from residents. She also assisted with receiving access to offsite
monitoring wells that were previously installed by the EPA.
2.2.1 Residential Wells Not Sampled
Property access was denied for two residential wells proposed for sampling in the Well
Survey and Proposed Potable Well Sampling Technical Memorandum (Black & Veatch,
2007). These wells are located at 1403 Alvin Hough Road, Midland, NC 28701 (Sample
ID: RAM_HONEYCUTT_l403) and 1371 Alvin Hough Road, Midland, NC 28701
(Sample ID: RAM_HONEYCUTT_I371). Both residents provided their water to Black
& Veatch in Mason jars. Black & Veatch did not witness the collection of this residential
water; therefore, EPA declined to analyze these samples, and the samples were discarded.
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Data Evaluation Report
EPA Contrai.:t No. 68-W-99-043
Work Assignment No. 697-RJCO-A419
Ram Leather Care Site
Section: 2
Revision: 0
NnvLit1bcr 29. 2007
One additional residential location proposed in the Well Survey and Proposed Potable
Well Sampling Technical Memorandum (Black & Veatch, 2007) was not sampled. All
wells located on the 91-acre Lawrence property on Coble Road (Sample ID:
RAM LAWRENCE) were abandoned after the resident sold the property to a developer;
therefore, none of the wells on the Lawrence property were sampled during this event.
2.2.2 Dechlorination Filters Installed by EPA
In 1997, the EPA installed dechlorination filters on four contaminated residential wells
located near the Ram Leather site, including the properties of Glosson (Sample ID:
RAM_GLOSSON), Beaver (Sample ID: RAM_BEAVER), Ivey (Sample ID:
RAM_IVEY), and Segrest (Sample ID: RAM_SEGREST). EPA requested that Black &
Veatch collect a pre-filter and a post-filter sample from each of the four abovementioned
wells. At the time of sampling, Black & Veatch observed that all four residents had
removed the filters installed by the EPA from their wells. Mr. Beaver removed the filter
from his well about one year prior to the September 2007 sampling event because the
filters were "leaking profusely". Mr. Ivey could not remember when his filter was
removed, but it could have been removed when he had some work performed on his well
a few years ago. There was no evidence of the EPA filters on Mr. lvey's property. The
Glosson property at 15208 Albemarle Road, which is now owned by Mr. Sanchez, is now
considered to be a commercial property; therefore, Mr. Sanchez removed the filter from
the well. The Segrest property is owned by Mr. Segrest, but is inhabited by renters. The
filters were still on the property in a shed, but were disconnected. Since no filters were
present on any of these four wells, only one sample was collected from each well.
2.2.3 Residential Wells Without EPA Filters
Ten other residential wells were sampled by Black & Veatch that did not have
dechlorination filters installed by the EPA. These samples were collected from the
following properties: Allen, McNair, Foster, Glosson ( 1475 Alvin Hough Road), Perault,
Estep, Jamerson, and Tucker (three wells were sampled on Mr. Tucker's property).
Table 2-l describes the sample ID, resident's name, resident's address, type of analysis,
sample date, and sample time for each of the ten abovementioned wells.
2.3 Quality Assurance/Quality Control (QA/QC) Samples
As part of the sampling effort, QA/QC samples were submitted to the laboratory with
field investigation samples in order to evaluate the confirmatory sampling procedures and
analytical methodologies. Field duplicate samples were collected at the rate of
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Data Evaluation Report
EPA Contmct No. 68-W-99-043
Work Assignment No. 697-RICO-A4 l 9
Ram Ll·athcr Care Site
Section: 2
Revision: 0
Nov1..,nhcr 29, 2007
approximately 10 percent of the regular samples and matrix spike and matrix spike
duplicate samples were collected at the rate of approximately 10 percent of the regular
samples.
2.4 Investigation-Derived Waste
Personal protective equipment (PPE), decontamination fluids, purge water from
monitoring wells, and other uncontaminated waste (as defined in Section 7.0 of the FSP
[Black & Veatch, 2006a)) were containerized in U.S. Department of Transportation
(DOT)-approved 55-gallon UNIA or lA-2 drums. The drums were then labeled and
staged onsite for future characterization and disposal. Purge water resulting from purging
of residential wells was purged directly onto the ground surface on the property of the
resident.
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Data Evaluation Report
EPA Contrni.:t No. 68-W-99-043
Work Assigmnc:nt No. 697-RJCO-A419
Ram Leather Care Site
St-ction: 3
Revision: 0
Novt..•mhcr 29, 2007
3.0 Data Reduction, Tabulation, and Evaluation
This section provides sample analytical results and other data collected during the
September 2007 RI/FS sampling event. Results for historical VOC concentrations in
groundwater and potable wells are included for comparison.
3.1 Groundwater Field Data
Groundwater parameters were recorded during monitoring well sampling and residential
well sampling. Groundwater samples from the monitoring wells were analyzed for the
following field parameters: temperature, pH, conductivity, oxidation-reduction (redox)
potential, dissolved oxygen (DO), and turbidity. Depth to groundwater was measured in
monitoring wells; however, water table elevations are approximate because the height of
the sitck-up wells above ground was estimated. Potable well samples were analyzed for
temperature, pH, and conductivity. Monitoring well and potable well field data were
recorded on groundwater sample collection record forms and potable well sampling
forms, respectively (provided in Appendix A). Table 3-1 provides monitoring well field
data and Table 3-2 provides potable well field data collected during the 2007 sampling
event.
3.2 Analytical Data
The analytical data derived from the September 2007 sampling event are summarized
below. All analytical data were subjected to the quality assurance review (data
validation) described in Section 4.0. Analytical data packages are presented in Appendix
B.
3.2.1 Data Qualifiers
In the analytical data tables presented in this report, some concentrations of organic
constituents were assigned a "J" qualifier, indicating that the qualitative analysis was
acceptable, but the quantitative value is an estimate. Sample results assigned a "U"
qualifier indicate that the constituents were analyzed for, but not detected above the
sample quantitation limit (SQL) for that sample. The reported number is the laboratory
derived SQL for the constituent. Data assigned an "R" qualifier are not useable data.
Samples containing concentrations of contaminants greater than the appropriate
regulatory standards are considered to be elevated.
3-1
Datu Evaluation Report
EPA Contmct Nq. 68-W-99-043
Work Assignment No. 697-RJCO-A4 I 9
Rum Leather Cure Site
3.2.2 Groundwater Analytical Data -Monitoring Wells
St.-ction: 3
Revision: 0
Novt..·mbcr 29, 2007
Groundwater samples were collected from seven monitoring wells in September 2007
and were analyzed for VOCs (SW-846 Method 8260). Monitoring well analytical results
were compared to North Carolina Department of Environment and Natural Resources
(NCDENR) 2L Standards (NCDENR, 2005) and Federal Maximum Contaminant Levels
(MCLs) (EPA, 2002). Analytical results, including historical and 2007 results for
detected compounds only, are reported on Table 3-3. Figure 2-1 shows groundwater
sampling results for select VOCs.
Concentrations of VOCs exceeded regulatory goals in five monitoring well samples
collected in September 2007. The primary constituents of concern in the groundwater at
the Ram Leather Care site are chlorinated solvent compounds. tetrachloroethene (PCE),
trichloroethene (TCE), cis-1,2-dichloroethene ( cis-1,2-DCE), and vinyl chloride (VC).
MCLs for PCE [5 micrograms per liter (~tg/L)], TCE (5 µg!L), cis-1,2-DCE (70 ~tg/L),
and VC (2 µg/L) were exceeded in the following sample in 2007:
• DWI I -PCE (4,300 µg!L), TCE (356 ~tg/L), cis-1,2-DCE (1,430 µg/L), and VC
18.2 ~Lg/L)
NCDENR 2L Standards for PCE (0.7 ~tg/L), TCE (2.8 µg/L), cis-1,2-DCE (70 ~tg/L),
chloroform (0.019 µg/L), and VC (0.015 µg!L) were exceeded in the following samples
in 2007:
• DWI I --PCE (4,300 ~tg/L), TCE (356 µg/L), cis-1,2-DCE (1,430 µg!L), and
vc 18.2 ~Lg/L)
• MW-I -PCE (3.5 ~tg/L)
• MW ID -Chloroform ( I ~tg/L)
• MW-2D-PCE (0.95 J µg/L)
• MW-2D (duplicate) -PCE (0.98 J ~tg/L)
It should be noted that the laboratory reporting limit (I µg!L) for several VOCs
(including PCE, chloroform, and VC) is greater than the NCDENR 2L Standard. The
complete set of analytical data is presented in Appendix S:
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Data Evaluation Rcpon
EPA Cnntmct No. 68-W-99-043
Work Assignment No. 697-RICO-A419
Ram Leather Care Site
3.2.3 Groundwater Analytical Data -Residential Wells
SL-ction: 3
Revision: 0
Nov1.,nbcr 29, 2007
Groundwater samples were collected from 14 potable wells in September 2007 and were
analyzed for VOCs (SW-846 Method 8260). Potable well analytical results were
compared to Federal MCLs (EPA, 2002). Analytical results, including historical and
2007 results for detected compounds only, are reported on Table 3-4. Figure 3-2 shows
potable well sampling results for select VOCs.
Concentrations of VOCs exceeded regulatory goals in six residential well samples
collected in September 2007. MCLs for PCE [5 microi,,'fams per liter (~tg/L)], TCE (5
~tg/L), cis-1,2-DCE (70 ~tg/L), and VC (2 ~tg/L) were exceeded in the following samples:
r
• Beaver-PCE (41.3 ~tg/L)
• Beaver (duplicate) -PCE (39.4 ~tg/L)
• Glosson -PCE (IOI µg/L) and TCE (32.7 ~tg/L)
• Glosson (duplicate)-PCE (108 ~tg/L), TCE (36.1 ~tg/L), and cis-1,2-DCE (77.6
µg/L)
• Ivey-PCE (5.6 ~tg/L)
• Segrest -PCE (99.2 ~tg/L) and TCE (6.4 ~tg/L)
It is important to note that concentrations of PCE exceeded the MCL by approximately
20 times in the Glosson and Segrest residential wells. A dechlorination filter is not in use
at the Segrest residence. Although the EPA-installed dechlorination filter has been
removed from the Glosson (now Sanchez) residential well, the well is no longer in use for
drinking water purposes (Table 2-1 ). The complete set of analytical data is presented in
Appendix B.
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Data Evaluation Rt·por1
EPA Contr.ict No. 68-W-99-043
Work Assignment No. 697-RICO-A4 \ 9
Ram Leather Care Site
4.0 Data Usability
St-ction: 4
Revision: 0
Novt·mbcr 29, 2007
This section provides information on the usability of sample analytical data and field data
generated during the September 2007 groundwater sampling event for the Ram Leather
Care site. The data usability report evaluates the quality of the data and the implication
of a qualifier applied to the sample result. Data validation was completed by Black &
Veatch. During data validati~n, qualifiers were applied to sample results in accordance
with criteria and parameters listed in the United States Environmental Protection Agency
Contract Laboratory Program National Functional Guidelines for Organic Data Review
(EPA, 1999). Data validation reports are provided in Appendix C.
The usability of sample data was evaluated based on data sources, documentation,
analytical methods and detection limits, completeness, comparability, representativeness,
precision, and accuracy in accordance with specifications outlined in the U.S.
Environmental Protection Agency Guidance for Data Usability in Risk Assessment (Part
A) (EPA, 1992).
4.1 2007 RI/FS Data
Field and chemical analytical data were collected during the September 2007 RI/FS
sampling efforts. The usability of field and analytical data is detailed in the following
subsections.
4. 1. 1 Field Data
Field data consist of groundwater field parameters recorded before monitoring well and
potable well sample collection and approximate monitoring well groundwater levels.
Field data recorded for use in project reports is included on Tables 3-1 and 3-2. The
following subsections present detailed information about this type of field data.
4.1.1.1 Groundwater Field Parameters. Monitoring well groundwater samples
were analyzed for the following field parameters: temperature, pH, conductivity, redox
potential, DO, and turbidity. Table 3-1 provides monitoring well sampling field
parameters for the 2007 sampling event. Potable well samples were analyzed for
temperature, pH, and conductivity. Table 3-2 provides potable well field data collected
during the 2007 sampling event.
4-1
Data Evaluation Rcpnrt
EPA Contract Nn. 68-W-99-043
Work Assigmncnt No. 697-RICO-A4 I 9
Ram L1.·a1hcr Can: Site
Section: 4
Revision: 0
November 29. 2007
A Horiba U20 Multiprobe System with flow through cell was used to measure pH,
temperature, and conductivity; a YSI-50B down-hole probe was used to measure DO;
and a Lamotte 20/20 Turbidimeter was used to measure turbidity. Monitoring well field
parameters were recorded on groundwater sample collection record sheets and potable
well field parameters were measured on potable well sampling forms (Appendix A). Data
were tabulated, reviewed, and approved as tabulated.
Monitoring well and potable well field data are considered to be of sufficient quality and
have been deemed acceptable for their intended use. It should be noted that the high
turbidities in monitoring well samples is not a concern because samples were not
analyzed for metals.
During analysis of potable well field parameters, observations were made regarding
parameter stability and purge duration that may affect analytical data quality. Field
parameters recorded during potable well sampling of the Estep residential well do not
appear to have stabilized prior to sample collection. This instability may indicate that
groundwater representative of the formation was not sampled and instead stagnant well
water or water in the transfer lines may have been sampled. Additionally, three
residential wells (Allen, Glosson_l475, and Perault) were purged for a duration
significantly less than the 15 minute minimum purge proposed in the Sampling and
Analysis Plan, Volume I -Field Sampling Plan (Black & Veatch, 2006). Potable well
purge durations are included on Table 3-2. The Glosson_l475 and Perault wells were
purged less than 15 minutes because the residents would only allow a 5-gallon purge
from each of these wells. Low purge durations for the Allen, Glosson_l475, and Perault
wells may indicate that voe concentrations in these wells are inaccurate and may be low
due to voe volatilization within the well headspace.
4.1.1.2 Groundwater Levels. During the 2007 field event, depth to groundwater in
monitoring wells was measured from the top of the casing of the stick-up wells. Depth to
water below land surface (bis) on Table 3-1 is approximate because casing height above
the land surface is estimated as 32 inches. Since water levels are approximate, a
groundwater potentiometric surface map was not generated.
4-2
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Data Evaluation Report
EPA Contract No. 68-W-99-043
Work ,\ssignmcnl No. 697-RICO-A4 l 9
Ram Leather Care Site
4.1.2 Chemical Analytical Data
Sl·ction: 4
Revision: 0
November 29, 2007
A data validation report (Appendix C) was generated for each set of data derived from
the 2007 Rl/FS field investigation. Samples were analyzed for VOCs (SW-846 Method
8260) by PEL Laboratories, Inc.
The analytical data associated with sample delivery groups 2507667, 2507682, and
2507692 were determined to be of sufficient quality and were deemed acceptable for
their intended use except those sample results qualified "R" which are considered
unusable. There were no major issues reported for any of the three data groups. Data
validation reports are included in Appendix C. Attachments included in each data
validation report are a glossary of data qualifiers, a summary of analytes failing criteria,
sample results based on data validation, and sample results as reported by the laboratory.
4-3
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Data Evaluation Rt·pon
EPA Contrnct No. 68-W-99-043
Work Assignment No. 697-RICO-r\4 I 9
Ram Leather Care Site
5.0 Data Evaluation Summary
Section: 5
Rcvision: 0
November 29, 2007
The following data have been evaluated and determined usable to prepare Ram Leather
Care reports:
I. Site vicinity map (Figure 1-1 ).
2. Groundwater sampling records (monitoring wells) from the 2007 field event
(Appendix A).
3. Potable well sampling forms from the 2007 field event (Appendix A).
4. Groundwater sample field parameters for monitoring well and potable well
samples (Tables 3-1 and 3-2).
5. Analytical results from chemical sample collection associated with the 2007
RI/FS field investigation that have been determined to be useable in the data
evaluation report (not qualified with an "R").
6. Monitoring well analytical data are adequate for use in creating reports.
7. With the exception of potable wells that were not purged sufficiently, potable
well analytical data are sufficient to show which wells are contaminated with
VOCs. Analytical data collected from potable wells that were purged less than
15 minutes may not accurately reflect VOC contamination.
5-1
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Data Evaluation Report
EPA Contract No. 68-W-99-043
Work Assignment No. 697-RICO-A419
Ram Lcathcr Care Sitt!
6.0 References
Section: 6
Revision: 0
Novc..,nbcr 29. 2007
Black & Veatch, 2006a. Black & Veatch Special Projects Corp. Sampling and Analysis
Plan. Volume I -Field Sampling Plan. Ra_m Leather Care Site, Revision 0, December
2006.
Black & Veatch, 2006b. · Black & Veatch Special Projects Corp. Pre-Final Design
Report for Groundwater Interim Remedy. Ram Leather Care Site, Revision I, June 12,
12, 2006.
Black & Veatch, 2007. Black & Veatch Special Projects Corp., Technical Memorandum:
Well Survey and Proposed Potable Well Sampling, Ram Leather Care Site, January 25,
2007.
CDM, 2005. CDM Federal Programs Corporation. Remedial Investigation Report for
Ram Leather Care Site, January 2005.
EPA, 1992. U.S. Environmental Protection Agency, Guidance for Data Usability in Risk
Assessment (Part A), Final, PB92-963356, April 1992.
EPA, 1999. U.S. Environmental Protection Agency, USEPA Contract Laboratory
Program. National Functional Guidelines for Organic Data Review, October 1999.
EPA, 2002. U.S. Environmental Protection Agency, Groundwater & Drinking Water
Current Drinking Water Standards, July 2002.
EPA, 2007a. U.S. Environmental Protection Agency, Region IV, Science and Ecosystem
Support Division, Operating Procedure: Potable Water Supply Sampling. SESDPROC-
305-R0, February 2007.
EPA, 2007b. U.S. Environmental Protection Agency, Region IV, Science and Ecosystem
Support Division, Operating Procedure: Field pH Measurement. SESDPROC-100-R0,
February 2007.
6-1
Data Evaluation Rt•port
EPA Contract No. 68-W-99-043
Work Assignment No. 697-RICO-A4 l 9
Ram Ll'ather Care Sile
Sc..-ction: 6
Rc..·vision: 0
Nnvcmhcr 29, 2007
EPA, 2007c. U.S. Environmental Protection Agency, Region IV, Science and Ecosystem
Support Division, Operating Procedure: Field Specific Conductance Measurement,
SESDPROC-I0I-R0, February 2007.
EPA, 2007d. U.S. Environmental Protection Agency, Region IV, Science and Ecosystem
Support Division, Operating Procedure: Field Temperature Measurement. SESDPROC-
102-R0, February 2007.
EPA, 2007e. U.S. Environmental Protection Agency, Region IV, Science and Ecosystem
Support Division, Operating Procedure: Field Turbidity Measurement, SESDPROC-
103-R0, February 2007.
EPA, 2007f. U.S. Environmental Protection Agency, Region IV, Science and Ecosystem
Support Division, Operating Procedure: Field Dissolved Oxygen Measurement,
SESDPROC-106-R0, February 2007.
NCDENR, 2005. North Carolina Department of Environment and Natural Resources,
Groundwater Classifications and Standards, Title 15A of the North Carolina
Administrative Code Section 2L .0200, April I 0, 2005.
6-2
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I Athlll Sample m A111ty1a
RAM_ALl,[N voe
I RAM_BEAVl:R voe
I
I RAM_B[AVER, voe
RAM_FOSTER voe
RAM_GLOSSON voe
I RAM_GL0SSON9 voe
RAM_GLOSSON_U7!1 voe
I RAM_IVE\' voe
I RAM_MCNAlR voe
RAM_PERAULT voe
I RAM_SF.GREST voe
RAM_SEGREST-MS voe
I RAM_SEGREST-MSD voe
RAM_ESTEP voe
I RAM_JAMERSON voe
I RAM -HU/'lt:\'CU1T_1403 NIA
I RAM_HUNE\'CUTl'_ll71 NIA
RAM_LAWRENCE NIA
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Reiklcnt N■int
Allen
Beaver
Foster
Glouon
Glonnn (different
Table l•I
Sample Cod9, Sample Activities, Locations, ■nd Rationale
Ram Lulber Care, Charlotte. NC
M■p ID No. SampJe Activtty Sample Location
(from Wdl
Sunry Memo .. USIDENTJAL WELLS SAMPLED~. , ' " Collected water s..mplc from 10501 Coble Rd, Charlotte 28227
residcn ial well
26 Collected water urnple from Buvcr residential well located 11 l S 1 SS Alt>emarlc residential well Road
Co!!ccted duplicate ~ter sample Beaver residential well located at 151 H Albemarle
from residential well Rnad
ll Collected w.i1er w.mple from 13500 Mullis Rd, Charlene 28227
re1iden1ia! w IJ
" Collected waler sample from Glouon re1idential well located at I S208 Alhcmarle
ruidential well Road {note: the Mecklenbcrg Co. databale li11ed
the new resident's name al Sanchu).
Collccted duplicate water sample Glau.on ruidential well located 11 I 5208 Albemarle
from residential well Road
" Collected water i.ample from 147S Alvin Hough Rd, Midland 28107 nronerw from above I re1idcntial Wf:11
'"" 27 Collocted w11er sample from Ivey reiidential well located 11 IS 11 S. Albemarle
re~idential well Road
McNair l2 Collected water sample from 1161 Alvin Hough Rd., Midland 28107
re,idential well
Perault 19 Collected water sample from 141 I Alvin Hough Rd, Midi.ind 28107
residential well
Segrest 20 Collected water sample from Segrest residential well located at 1 S 11 S Albemarle
residential well Road
Collected matri~ spike water
IAm"le from residential well
Collected matri~ spike duplicate
water iample from reaidential well
· ,, ADDmONAL RESIDENTIAL WI: SAMPLED AT RE UEST OF Rr.sn> .. . , ... ·•·.·-,a
Estep 7 Collcct water sample from E1tep residential we!! located at 11216 Coble Road
residential well
Jamerson " Collect wa1er iample from Tucker'• d1ughter'1 property (next door) -

I

SJ0I
residential ~II Albemarle Road
Nota
. -~ .. , '.' . "·
Filler di1co1mccted approximately l
year ago because it wu Inking
Mr. Beaver stated "EPA per1on
working on wucr line told me 1luit
EPA didn't have enough money to
fix my filter", Two week! ago EPA
brought out potable water supply,
bul it i1 almott gone.
Sanchu ha1 removed filler sin«
well i1 nol being used for drinking
water. Property now used 111
buiinesa
No filter per Mr. Ivey, Per EPA,
filter1 were in111l1ed in l ~7. Mr.
Ivey had work done to his well "a
few ~can ago". Filter may have
been removed during the work.
No filter present.
No fiher present.
Resident wu not home at lime of
i.ampling. The well water had
11rongodor. EPA filter, well! on
the property, but not eonnccted
-;,• .. '. ,,. ..
Co!!ccted sample from Mr. Tucker'
Daughta'1 well. This sample i1
called RAM_JAMERSON.
IDENTIAL WELLS NOT SAMPLED .~ . ,\.'". ,,, , .. ,1. -.. _. ', '7 .,~.,..· '•• .. . , .. ,.
Huneycu11 )I NIA 1403 Alvin Hough Rd., Midland 28107 Declined accen, then resident
provided groundw11er in Muon ju
Sample collection wu not
witneued: therefore, iample wu ---· Honeycutt (different JO NIA IJ71 Alvin Hough Rd,, Midland 28107 Declined access, then residem property from above) provided groundwater in M110n jar
Sample eollcction wu not
witne1sed: therefore, sample was ---· Lawrence II NIA Mailing: 1908 Smling Rd., Charlolle 28209 Well wu abandoned; property to b
used for new deve!onment
Page 1 ol 2
Atlul Sample ID A11aly1a Raide1n Name
RAM_DWII voe NIA
RAM_MW0I voe NIA
RAM MW0I-MS voe NIA
RAM MW0l-MSD voe NIA RAM_MW0l voe NIA
RAM_MW0JD voe NIA
RAM MW'JOJD voe NIA
RAM_MW0ID voe NIA
RAM_MW0JD voe NIA
RAM_MWIMD voe NIA
RAM_ TIJCKERl voe Tucker
RAM_ TIJCKIRl voe Tucker
RAM_TIJCKERJ voe Tucker
Table 2-1
Sample Codu, Sample Activities. Locatlon1, and Rationale
Ram Leather Care, Charlotte, NC
Map ID No. Sample ActMty Sample Lllutto11 (fr11m wen
San<n Memo .. SAMPLING IN SUPPORT or GROUNDWATER RA\ . ' . . " .,.,._.
NIA Collected groundwater !.Bmpln On1itc
from •:itistin" monitorina well
NIA Col1ect groundwater samples from Onsitc
«inin., monitorina well
NIA Matrix mike Onsite
NIA Matrix I ikc dunlicatc Onsitc
NIA Collect groundwater samples from Onsitc
c~istin" monitorina well
NIA Collect groundwaier samplc1 from On1i1e
tJti11inn monitorin° well
NIA Dunlic•le Onsi!c ':,'/A Collc.:t groundwater samples from Off-site
cJtisling monitoring welt
NIA Collect groundwater u.mple1 from Off-site
e~istinn monitorin" well
NIA Collect groundwater samples from Off-site
eJtiuing monitoring well
24 Collect water sample from ~! residential weJI -!5221 Albemarle Rd
residen!ial well
Collect water sample from #2 residential well-15221 Albemarle Rd
re,idcntial w,ell
Collect water Nlllple from #3 residential well • 1522 I Albemarle Rd,
r•1idential Ii
Nola
;i;c ,:' . ..• .. ,., . . •. .~< I
B011om of casing wu very soft
from sediment deposits. Low
recharge rate noted,
Well wu cnentially dry and had a
low rechar11c rate
Well purged dry. Well sampled
after enough rc.:harge to allow
Well purged dry. Well wnplcd
after enough recharge to allow
Mr. Tucker'1 well used 11 his hou,c
Well at back ofpropcny. near old
trailer
fl ii noted lhal 1amplcs from rttlduitlal welb Beaver, G101100, Ivey, and Sqrat wen: alllo proposed 111 ■upporfofthe Grou11dwater Interim Remedy. Samp"-t'nim these welb an: located above undu lhe Rcsklenll.a.l Wdlt Sampled 1ectlo11, beeaa,e tbae •db were abo propoNd 10 be be umpled u part oftbe RI/FS raklaidal 1-1mplln1 effort.
RAM_MW0J
NOTES:
NIA
MW Monitoring well
NIA Not applic•ble
NIA
VOC Volatile organic compound
,.,, ·,, ·.MONITORINGWELLSN"OT Ul)• .... >f, :~ ...,.._ r.·-
NIA NIA Oruite
Page2of2
,~. -:,, ·"'. ... -•; .. ..: .: !.+'' ;, "' -' . I
Well contained very little w•ter and
wu unable to be u.mo1ed
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---liil ----··-·--- --- -- --Table 3-1
Final Monitoring Well Field Parameters (2007)
Ram Leather Care, Charlotte, NC
Monitoring Sample Water Approximate Total Temperature pH Conductivity Redox Duaolved Unfiltered
WeU Date Level Water Level Purge ('C) (SU) (mS/cm) Potential Oxygen Sample
BTOC BL'l Volume (mV) (mg/L) Turbidity
(feet) (feet) (e:aUons) (NTU)
MW-I 9/28/2007 23.34 20.67 3.48 18.4 10.80 8.1 136 9.33 >990
MW-ID** 9/29/2007 27.40 24.73 75.5 23.20 9.44 0.990 107 • 57.7
MW-2** 9/25/2007 21.28 18.61 5.27 21.9 5.68 13.2 138 5.89* >900
MW-2D 9/25/2007 23.45 20.78 10.53 15.5 5.70 15.3 139 3.34 16.0
MW-3D** 9/26/2007 19.79 17.12 80 17.1 7.05 44.8 33 2.26 927
MW-4D 9/29/2007 27.02 24.35 75.7 19.43 8.15 1.12 -73 6.02 23.6
DWI! 9/27/2007 24.05 21.38 952 17.8 5.80 18.3 214 3.27 7.3
NOTES:
[3TOC Below top of casing
BLS Below land swface
'C degrees Celsius
SU Standard units
mS/cm millisemens per centimeter
mV millivolts
mg/L milligrams per liter
NTU Nephelometric Turbidity Unit • Not sufficient water present/recharge rate for down-hole DO probe. Flow-through cell DO measurement was recorded when possible . •• Well ran dry dwing sampling. Sufficient recharge rate for sampling .
Well MW-3 was not sampled due lo insufficient water volume in well.
Ii!!!!!!! ~ liiiiiiil liiiiiii. - ----------Table 3-2
Final Reaidential Well Field Parameten (2007)
Ram Leather Care, Charlotte, NC
Monltorin& Sampl, ApproL Well Total Appro:dmate Temperatur. pH Coududlvlly Fllter Wdl Date Wdl Yldd Purce Purce ("C) (SU) (mS/cm) Present
Depth v.-Durallou
(fed) (ipm) (pllom) (minutes)
:\.Hen 9/27/2007 206 -15 10 18.47 6.11 0.351 --
Bcavc.-r 9/26/2007 150 <5 100 23 17.01 6.20 0.770 No
Estr.-n 9/28/2007 --25 13 17.63 5.12 0.557 No
FOSier 9/28/2007 -20 20 22.64 7.45 0.999 -Glosson 9/28/2007 --20 12 17.73 7.00 1.62 No
Glosson 1475 9/25/2007 5 8 18.37 6.33 0.679 Sediment
Ivey 9/26/2007 217 3-5 25 14 17.9 6.88 0.986 No
Jameson 9/25/2007 380 I - 2 40 15 21.11 6.79 0.694 Sediment
McNair 9/26/2007 270 >5 25 17.39 5.85 0.931 No
Perault 9/25/2007 215 24 5 7 18.06 7.07 0.91 No
Se-est 9/28/2007 -50.0 17 18.22 6.72 0.999 No
Tucker 01 9/25/2007 100 10 -12 250 33 22.42 6.63 1.10 No
Tucker 02 9/25/2007 100 12 •14 250 14 19.25 6.26 0.745 Yos
Tucker 03 9/26/2007 150 25 300 12 18.82 6.73 0.926
NOTES,
gpm gallons per-minute
-unknown
•c degrees Celsius
SU Standard units
mS/cm millisemens ...,.,_ centimeter
-- -- -
l!!!!!!I iiiii - - - - - --- --
Table 3-3
Monitoring Well Analytical Results (1991 -2007)
Ram Leather Care Site
Charlotte, Mecklenberg County, North Carolina
Location ID N.C. 2L Federal OMW0I OMW0l MW-I MW-2
Sample ID Groundwate1 MCLs OMW0\_0591 OMW0!_0394 u,-n U""'°"n MWl\_0499 RAM_MWOJ_0907 u,-. u,-n MW22_0499 RAM_MW02_0907
Constituent 5/1/1991 3/1/1994 1991 1994 4/20/1999 9/28/2007 1991 1994 4/20/1999 9/25/2007
Volatile Organit'5 (SW-846 Method 8260) (ug{L)
1.12-Trichloroethane 0.6 5 ND 1 u I u ND I u I u
I, 1-Dichloroethene 7 7 I u I u ---I u I u
1,2-Dichloroethane 0.38 5 -ND I u I u ND -I u I u
Acetone 700 NE 25 u 10 U --25 u 10 U
Carbon disulfide 700 NE ---2.5 u I u ----2.5 u I U
Chloroform 0.19 • I u I u ----I u 1 u
cis-1.2-Dichloroethene 70 70 590 -;,,.;ro I u I u --ND 1 u 1 u
Meth,.,J tert-butvl ether 200 NE I u ----I u
Tetrachloroethene 0.7 5 4690 2500 ND ND I u 3.5 ND ND I u I u
trans-1.2 Dichloroethene 70 100 ND I u I u ND I u I u
Trichloroethene 2.8 5 98 ND ND I u I u ND ND I u I u
Vinyl Chloride 0.015 2 ----I u I u ----I u I u
-- - --- -
l!!!l!!!I iiiil -- -- -- - --
Table 3-3 (Continued)
Monitoring Well Analytical Results (1991 -2007)
Ram Leather Care Site
Charlotte, Mecklenberg County, North Carolina
Location ID N.C. 2L Federal MW-3 MW-ID MW-2D
Sample ID Groundwate MCLs Uakoowo U""""'TI MW33_0499 MW04_0800 RAM_MW\0_0907 M\\'05_0800 MW905_0800 RAM_MW02D_0907 RAM_MW902D_0907
duplicate duplicate
Constituent 1991 1994 4/20/1999 8117/2000 9/28/2007 8/15/2000 8/15/2000 9/25/2007 9/25/2007
Volatile Or,::anics {SW-846 Method 8260) {ug/L)
1.1.2-Trichloroethane 0.6 5 l\'D --I u I u I u I u I u I u I u
1.1-Dichloroethene 7 7 ----I u I u I u I u I u I u I u
1.2-Dichloroethane 0.38 5 ND --I u I u I u I I I u I u
Acetone 700 NE --25 u 5 UR 10 u 6 J 5 UR 10 u to u
Carbon d:isu1fide 700 NE --2.5 u 0.7 J I u 5 4 tu I u
Chloroform 0.19 • --I u 3 I I u I u tu I u
cis-1.2-Dichloroethene 70 70 ND I u I u I u 4 5 0.62 J 0.52 J
Methvl tert-butvl ether 200 ~'E --1.2 --I u I u
Tetrachloroethene 0.7 5 ND ND I u I u I u 2 2 0.95 J 0.98 J
trans-1.2-Dichloroethene 70 100 ND -I u I u I u I u I u I u I u
Trichloroethene 2.8 5 ND ND I u I u I u I u I u I u I u
Vinyl Chloride 0.015 2 I u I u I u I u I u I u I u
-l!!!!!!!!I liiiii iiiil -- - - -- -- --- --
Table 3-3 (Continued)
Monitoring \Veil Analytical Results (1991 -2007)
Ram Leather Care Site
Charlotte, Mecklenberg County, North Carolina
Location ID X.C. 2L Federal MW-3D MW-4D MW4D DWOI DWtl
Sample ID Groundwate. )ICLs MW06_0&00 RAM_MW03D_0907 MW07_0800 RAM_MW4D_0907 DW0J_0791 DW!l_0499
Constituent 8/15/2000 9/26/2007 8/16/2000 9/28/2007 1991 4/20/1999
Volatile Organics (SW-846 Method 8260) (uwL)
1.1.2-Trichloroethane 0.6 5 I u 1 u I u I u ND 100 U
1.1-Dichloroethene 7 7 I u 1 u I u I u --100 U
J .2-Dichloroethane 0.38 5 1 1 u 0.5 J I u ~'D 100 U
Acetone 700 NE 7 J 10 U 5 UR 10 U -2500 U
Carbon disulfide 700 ~'E 1 u IU 2 lU --250 U
Chloroform 0.19 • 2 I u 1 u 1 u --100 U
cis-1,2-Dichloroethene 70 70 1 u 1 u 1 u I u 1200
Methvl tert-butvl ether 200 NE -1 u --1 u --
Tetrachloroethene 0.7 5 I u 1 u 1 u 1 u ND 4000
trans-1.2-Dichloroethene 70 100 I u 1 u 1 u 1 u ~'D 100 u
Trichloroethene 2.8 5 I u 1 u I u 1 u 9 210
Vinyl Chloride 0.015 2 I u 1 u 1 u 1 u -100 u
----11!!!!1!1 11!!1 == liiil - -- - -
Table 3-3 (Continued)
Monitoring Well Analytical Results (1991 -2007)
Ram Leather Care Site
Charlotte, Mecklenberg County, North Carolina
Location ID l'•I.C. 2L Federal DWll
Sample ID Groundwate1 MCLs DWll-128_0802 DWll-262_0802 DWI 1-275_0802 DWI 1-286_0802 DW!l-386_0802 DW!l-463_0802
(128 feet)1 (262 feet)1 (275 feet}' (286 feet/ (386 fect)1 (463 feet)1
Constituent 8/16/2002 8/16/2002 8/16/2002 8/16/2002 8/15/2002 8/15/2002
Vol.atile Ofl!:anics (SW-846 Method 8260) {ug/L)
1.1.2-Trichloroethane 0.6 5 I u 40 U 40 U 40 U 40 U 40 U
1.1-Dichloroethene 7 7 1.3 40 U 40 U 40 U 40 U 40 u
1.2-Dichloroethane 0.38 5 I u 40 U 40 U 40 u 40 U 40 u
Acetone 700 NE 25 u 1000 U 1000 U 1000 u 1000 U 1000 u
Carbon disulfide 700 NE 2.5 u 100 U 100 u 100 u 100 U 100 u
Chloroform 0.19 • I u 40 U 40 u 40 u 40 U 40 u
cis-1.2-Dichloroethene 70 70 550 1100 1100 1000 680 780
Methvl tert-butvl ether 200 NE I u 40 U 40 u 40 u 40 u 40 u
Tetrachloroethene 0.7 5 1700 3700 4000 3800 2400 2700
trans-1.2-Dichloroethene 70 100 2.2 40 U 40 u 21 J 58 70
Trichloroethene 2.8 5 97 190 200 200 120 160
Vinyl Chloride 0.015 2 8.5 40 U 40 U 40 U 40 U 40 U
NOTES:
:-..C. 2L Groundwater N.C. Groundwater Quality Standards for the Protection of the Groundwaters of North Carolina, \SA NCAC 2L .0200 (NCDENR. 2005).
Federal MCLs National Primary Drinking Water Standard Maxirnwn Contaminant Levels, July 2002
ugll. micrograms per liter.
NE Not Established.
-Value not recorded.
U The analyte was analyzed for, but was not detected above the reported sample quantitation limit.
The analyte was positively identified; the associated numerical value is the approximate concentration of the analyte in the sample.
R Presence or absence of analyte cannot be determine from date due to severe quality control problems. Data are rejected and considered un~sable.
Well sample collection depth.
Sum of the total trihalomethanes (TTHM.s) (chloroform, bromodichloromethane, dibromochlorometbane, and bromofonn) may not exceed 80 ugfL.
Result reported from the diluted analysis.
Shading Indicates the detec1ed concentration exceeded any of the given regulatory standards.
-- - --
DWlt DWII
DW\1-495_0802 DWll-01_0605 DWll_0907
(495 feet)1
8/15/2002 6/14/2005 9/27/2007
40 U 50 U 5U
40 U 50 U 2.7 J
40 U 50 U 5U
l000 U 100 U 50 U
100 U 50 U 5U
40 U 50 U 5U
1100 1200 1430 *"
40 u 50 U 5U
2800 3500 4300 n
38 J 36 J 15.2
160 260 356
40 U 50 U 18.2
----liiiil - -- -- -- --- --
Table 3-4
Residential Well Analytical Results (1991 -2007)
Ram Leather Care Site
Charlotte, Mecklenberg County, North Carolina
Constituent Federal Adams Allen Beaver Bea,·er Bea\'er Bea'\'er Bea\'er Beaver Beaver Beaver
MCLs pre-filter post-filter 129 fect1 duplicate
4/18/2006 9/27/2007 5/1/1991 3/1/1994 4/19/1999 4/19/1999 8/14/2002 8/15/2002 9/26/2007 9/26/2007
Volatile Oq~anics (SW-846 Method 8260) (ug/L)
1, 1-Dichloroethene 7 0.5 u 1 u --I u 1 u I u 1 u 1 u I u
1.2-Dichlorobenzene 600 0.5 u 1 u ---0.71 J 0.68 J 0.84 J I 1 u I u
l,4-Dichlorobenzene 75 0.5 u 1 u -· .. 1 u 1 u 1 u 1 u 0.61 J 0.64 J
Bromodichloromethane • 0.5 u 1 u -· -· 1 u 1 u 1 u 1.8 1 u 1 u
Bromoform • 1 u I u .. .. 1 u 1 u 1 u 4 1 u 1 u
Chloroform • 0.5 u 1 u -· -1 u 1 u 1 u 1.1 1 u 1 u
cis-1.2-Dichloroethene 70 I u I u -24 29 30 37 40 17.9 17.5
Dibromochloromethane • 0.5 u I u 1 u 1 u 1 u 2.8 1 u 1 u
Methvl tert-but'-, 1 ether NE 0.5 u 1 u ----1 u 1 u 1 u 1 u
Tetrachloroethene 5 0.5 u 1 u 3.9 7.5 14 14 11 13 41.3 39.4
trans-1.2-Dichloroethene 100 0.5 u 1 u ·-1 u 1 u 0.76 J J 1 u 1 u
Trichloroethene 5 0.5 u 1 u ·-0.57 1 1.1 A 0.99 J 1.2 1.6 1.6
-- -- --- ---- -- - - ---
Table 3-4 (Continued)
Residential Well Analytical Results (1991 -2007)
Ram Leather Care Site
Charlotte, Mecklenberg County, North Carolina
Constituent Federal Brown Corbett Estep Estep Estep Foster Fox
MCLs
4/17/2006 4/17/2006 4/19/1999 4111noo6 9/28/2007 9/28/2007 4/18/2006
Volatile O~anics (SW--846 Method 8260) (ug/L)
I, 1-Dich\oroethene 7 0.5 U 0.5 U I u 0.5 U I u I u 0.5 u
1.2-Dich\orobenzene 600 0.5 U 0.5 U I u 0.5 U I u I u 0.5 u
1.4-Dichlorobenzene 75 0.5 u 0.5 U I u 0.5 U I u I u 0.5 u
Bromodichloromethane • 0.5 u 0.5 U I u 0.5 U I u I u 0.5 u
Bromoforrn • I u I U I u I u I u I u I u
Chloroform • 0.5 u 0.5 u I u 0.5 u I u I u 0.5 u
cis-1.2-Dichloroethene 70 I u I u I u I u I u I u IU
Dibromochloromethane • 0.5 u 0.5 U I u 0.5 u I u I u 0.5 U
Meth, I tert-butvl ether NE 0.5 U 0.5 u 0.5 u I u I u 0.5 U
Tetrachloroethene 5 0.5 U 0.5 U I u 0.5 U I u I u 0.5 U
trans-1,2-Dichloroethene 100 0.5 u 0.5 U I u 0.5 U I u I u 0.5 U
Trichloroethene 5 0.5 U 0.5 U I u 0.5 U I u I u 0.5 U
--... ----- --- --- - - - --
Table 3-4 (Continued)
Residential Well Analytical Results (1991 -2007)
Ram Leather Care Site
Charlotte, Mecklenberg County, North Carolina
Constituent Federal Glosson Glosson Glosson Glosson Glosson Glosson_l475 Hutchinson hey Ivey
MCLs pre-filter post-filter duplicate
(no\-\' Sanchez) (now Sanchez)
3/1/1994 4/20/1999 4/20/1999 9/28/2007 9/28/2007 9/25/2007 4/20/1999 4/19/1999 9/26/2007
Volatile Ot2anics (SW-846 Method 8260) (ug/L)
1, 1-Dichloroethene 7 -1 u 1 u 1 u 1 u 1 u 1 u 1 u 1 u
1,2-Dichlorobenzene 600 -1 u 1 u 1 u 1 u 1 u 1 u 1 u 1 u
1.4-Dichlorobenzene 75 --1 u 1 u 1 u 1 u 1 u 1 u 1 u 1 u
Bromodich\oromethane • --1 u 1 u 1 u 1 u 1 u 1 u 1 u 1 u
Bromoform • --1 u 1 u 1 u 1 u 1 u 1 u 1 u 1 u
Chloroform • --1 u 1 u 1 u 1 u 1 u 1 u 1 u 1 u
cis-1,2-Dichloroethene 70 4.8 42 1 u 70 77.6 1 u 1 u 3.3 6.2
Dibromochloromethane • 1 u 1 u 1 u 1 U 1 u 1 u 1 U 1 u
Methvl tert-butvl ether NE ---lU 1 U 1 u -1 u
Tetrachloroethene 5 24 100 1 U 101 ** 108 ** 1 u 1 u 1 5.6
trans-1.2-Dichloroethene 100 --lU 1 u 1.1 0.52 J 1 u lU 1 u 1 u
Trichloroethene 5 2.8 26 1 u 32.7 36.1 1 u lU 1 u 2.2
-- - ----- --- --- - - - --
Table 3-4 (Continued)
Residential Well Analytical Results (1991 -2007)
Ram Leather Care Site
Charlotte, Mecklenberg County, North Carolina
Constituent Federal Jamerson Jamerson Jamison Massey Massey McDonald McNair· Montegue Montegue
MCLs (was Tucker) duplicate duplicate
4/20/1999 9/25/2007 4/20/1999 4/19/1999 4/19/1999 4/17/2006 9/26/2007 4/17/2006 4/17/2006
Volatile O~anics (SW-846 :\1ethod 8260) (ug/L)
1.1-Dichloroethene 7 I u 1 u I u I u I u 0.5 U I u 0.5 U 0.5 U
1.2-Dichlorobenzene 600 I u I u I u I u I u 0.5 U I u 0.5 U 0.5 u
I .4-Dich\orobenzene 75 I u I u I u I u I u 0.5 u I u 0.5 U 0.5 u
Bromodichloromethane • I u I u I u I u I u 0.5 U I u 0.5 U 0.5 u
Bromofonn • I u I u I u I u I u IU I u I U I u
Chloroform • 0.66 J I u I u I u I u 0.5 U I u 0.5 U 0.5 U
cis-1.2-Dichloroethene 70 IU I u I u I u I u IU I u IU I u
Dibromochloromethane • I u I u I u I u I u 0.5 U I u 0.5 U 0.5 U
Methvl tert-butvl ether NE --I u 0.5 u I u 0.5 U 0.5 u
Tetrachloroethene 5 IU I u I u I u I u 0.5 u I u 0.5 U 0.5 U
trans-1,2-Dichloroethene 100 I u I u I u I u I u 0.5 u I u 0.5 u 0.5 U
Trichloroethene 5 IU I u I u I u I u 0.5 u I u 0.5 U 0.5 U
-- -- - -- - --- - -- - ----
Table 3-4 (Continued)
Residential Well Analytical Results (1991 -2007)
Ram Leather Care Site
Charlotte, Mecklenberg County, North Carolina
Constituent Federal Perault Phund Segrest Segrest Segrest Segrest Segrest Segrest Sha,,er StateWell
MCLs pre-filter post-filter
9/25/2007 4/17/2006 5/1/1991 3/1/1994 4/19/1999 4/19/1999 8/16/2002 9/28/2007 4/17/2006 8/16/2002
Volatile Or,?anics (SW-846 Method 8260) (ug/L)
1,1-Dichloroethene 7 I u 0.5 u -1 u I u 2 u 1 u 0.5 u 1 u
1,2-Dichlorobenzene 600 1 u 0.5 u --1 u 1 u 2 u 1 u 0.5 u I u
1.4-Dichlorobenzene 75 1 u 0.5 u --I u 1 u 2 u I u 0.5 u 1 u
Bromodichloromethane • I u 0.5 u ---1 u 1 u 2 u 1 u 0.5 u 1 u
Bromoform • 1 u I u -1 u 1 u 2 u I u 1 u I u
Chloroform • I u 0.5 u ----I u 1 u 2 u 1 u 3 J 1 u
cis-1,2-Dichloroethene 70 I u I u --4.4 I u 3.2 6.6 1 u 1 u
Dibromochloromethane • 1 u 0.5 u ----1 u 1 u 2 u 1 u 0.5 u I u
Methvl tert-butvl ether NE 1 u 0.5 u ----2 u 2 0.5 u 1 u
Tetrachloroethene 5 1 u 0.5 u 19 16 70 1 u 54 99.2 ** 0.5 u 1 u
trans-1,2-Dichloroethene 100 1 u 0.5 u -1 u 1 u 2 u JU 0.5 u 1 u
Trichloroethene 5 1 u 0.5 u ----3.3 1 u 2.2 6.4 0.5 u 1 u
-- -------- -- -
Table 3-4 (Continued)
Residential Well Analytical Results (1991 -2007)
Ram Leather Care Site
Charlotte, Mecklenberg County, North Carolina
Constituent Federal Tennant Tucker_Ol Tucker_02 Tucker_03
MCLs
4/20/1999 9/25/2007 9/25/2007 9/26/2007
Volatile O~anics (SW--846 Method 8260) (ug/L)
I, 1-Dich\oroethene 7 1 u 1 u 1 u 1 u
1.2-Dichlorobenzene 600 1 u 1 u 1 u 1 u
1,4-Dichlorobenzene 75 1 u 1 u 1 u 1 u
Bromodichloromethane • 1 u 1 u 1 u 1 u
Bromofonn • 1 u 1 u 1 u 1 u
Chloroform • 1 u 1 u 1 u 1 u
cis-1.2-Dichloroethene 70 1 u 1 u 1 u 1 u
Dibromochloromethane • 1 u 1 u 1 u 1 u
Methvl tert-but"I ether NE .. 1 u 1 u 1 u
Tetrachloroethene 5 1 u 1 u 1 u 1 u
trans-1.2-Dichloroethene 100 1 u 1 u 1 u 1 u
Trichloroethene 5 1 u 1 u 1 u 1 u
;'l;QTES:
N.C. 2L Groundwater N.C. Groundwater Quality Standards for the Protection of the Groundwaters of North Carolina,
J5A NCAC 2L .0200 (NCDENR, 2005).
Federal MCLs National Primary Drinking Water Standard Maximum Contaminant Levels, July 2002
ug/L micrograms per liter.
XE Not Established.
--Value not recorded.
U The analyte was analyzed for, but was not detected above the reported sample quantitation limit.
J The analyte was positively identified; the associated numerical value is the approximate
concentration of the analyte in the sample.
Well sample collection depth.
Sum of the total tnllalomethanes (TTHMs) (chlorofom1, bromodichloromethane,
dibromochlororncthane, and bromofonn) may not exceed 80 ug/L.
Result reported from the diluted analysis.
Shading Indicates the detected concentration exceeded any of the given regulatory standards.
------
Vadala \\'agoner
4/17/2006 4/18/2006
0.5 u 0.5 U
0.5 u 0.5 U
0.5 u 0.5 U
0.5 u 0.5 U
1 u 1 U
0.5 u 0.5 U
JU 1 u
0.5 U 0.5 U
0.5 U 0.5 U
0.5 U 0.5 U
0.5 U 0.5 U
0.5 U 0.5 U
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100 200 300
I I I
f"CCl
State Pliinc NC NAD8J
Site Vicinity
Ram Leather Site
Charlotte, North Carolina
--County-Boundary
--Creek-Stream
--Parcel
-Pond
F!==t==t Railroad
M LJ
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1.2~ 1 U
Chlcfflonn...,,.._.,__ 1U
1.2-0icl1lon>oltla
Chlorofmn
ca-1,2-0ictlloroolhone c»-1,2-0idllo,oolheno 1 U r--. 1U T--19
Trich-1U Trich-
□
()
1U
1
1U
1U 1U
S MW-10
DRINKING WATER WELL
MONITORING WELL
NO
NO
NO
18
NO
NO
NO
RAM Leather Core Site
1,0 U 2 U
1.0U 2 U
4.4 32
70 54
3.3 22
1 U
1U
8.8
811.2'
8.4
SEGREST
(FORMERLY PARNELL)&
PW-0011
TUCKER/JAMERSONA-----r=
PW0089
STATEWELL 8
1
1U
5"
2 1U
1U
1U
0.82J o.ee.r 1 U
i
0.&eJ 1U
1 U 1.1
29 40
14 13
1 12
* Sample result from duplicate
NO
NO
4.8
24
2.8
1U
1U
17.9
41.3
1.8
10 ug/L Sample result exceeds NCDENR 2L Standard and/or MCL
1U
1U
42 100
28
1U ,u n.r ,or
38.1·
Monitoring Well Locations and VOC Results
Charlotte, Mecklenburg County, North Carolina
180 MM
LEGEND
90 0 MM M
1· = 180'
0
180
FIGURE
2-1
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Segrest Well Concentration (µg/L)
Cofl1)ound 1991 1994 1999 2002
cis-1,2-Dichloroethene 4.4 3.2 6.6
Tetrachloroethene 19 16 70 54 99.2
Trichloroethene 3.3 2.2 6.4
Beaver Well Concentration (µg/L)
Cofl1)ound 1991 1994 1999 2002 2007
cis-1,2-Dichloroethene 24 29 40 17.9
Legend
CJ Property with residential well sampled by B&V in 2007
CJ Tax Parcel Boundary
-Landfill
-Ram Leather Care Site
Creek-Stream
Value not recorded
* Sample results from duplicate sample
Red font indicates concentration exceeds the Federal MCL.
0 500 1,000 2,000 3,000 ... 1 __ ..,_l __ _.1 __ _._ __ .LI __ _L_ _ _JI
Feet
Nonh Carolina State Plane NAD 83
Concentration (µg/L)
Cofl1)ound 1994 1999 2007
cis-1,2-Dichloroethene 4.8 42
Tetrachloroethene 24 100
26
Ivey Well Concentration (µg/L)
'1i Cofl1)ound
e:> cis-1,2-Dichloroethene
1999 2007
3.3 6.2
Residential Well Locations and VOC Results
Ram Leather Care Site
Charlotte, North Carolina
N
A
Figure
2-2
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''
APPENDIX A
Groundwate1r Collection Records and
Potable \Nell Sampling Forms
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Well 10: (YI w ·-o '2.
Groundwater Sample Collection Record
Project Name: Ram Leather Date/Time Start:o~ /, ( 107,
Project Number: Date/Time Finish: IA I Z~ /07,
Location: Charlotte, NC Analysis: ~. 1.1, 1, ,
Weather: Samoler: () C
1) Water Level Data (from TDC)
Total Well Depth
Well Volume per casing diamater
11 os 1" V = 0.041 X h V Volume of water
Water Table Depth )l.'Zi 2" V=0.163xh h Height of the water cotumn
Water Column Length I0,77 3" V = 0.367 x h in the well measured in feet
Water Volume in Well I .1~ 4" V = 0.653 x h
TOC height above/below land (approx). 5" V = 1.020 x h
6" V=1.463xh
2) Total Purge Volume
Purge Method
C:. 21 gallons
3)
Field Testing Equipment_
Primary data collection method (!tow-Th_r~ ~ Other
~SI ~s-08
Parameters
Time /320 £6/0 I 910
Volume Removed (gal) /, !( J,S' [(
Color c. lo•t •, l/ ... t,O'( c/ouO•t
Turbidity (NTU) -zt:y r<roo I 'I (Y.J
pH ,:;:73 :r; <'I ~C.<,:
Conductivity ( i-~,O 13.2 iz.?.
DO (mg/L) (.iS" ~l'f 5':,tq
Temperature C'" ?f.;! ,z:z., ::,_ J l.':J
Reduction Potential (mV) /1~ l:tl ,~g
OVA(ppm)
Saliait; I,,., (<)~ "J{. /J~ /J A Y<I· r, O (y. i,,)
Ferrous Iron ----,JI! 1101 t ... o .... .,t-. t,J,fr{,f. u,,; .. _,.., r.~ t.O ,f):--:~ (. c11..,.A. I-lo/, .
Filtered? Yes Q Other Observations: (\.Joi '".t"> AP.'o..,t-t; JV {Jc H.'1 .... (. r
Sample Turbidity (NTU) (+'100) b,f-,,.~ R .. ~;, ~'•), (;,-1 i,.J! rl --ioo/.'. · f?"'~~.ru ..
Sample Time I 't IO . f""~: ,...,., ,r.,. b,u t..b o "-r~ d,, .~,--.,If.. jT,A,\L
• DO should be measured down-hole within the well screen or through a flow-through cell. All other parameters may be measured using either method, or from a sample collected from the purge /Ina.
Well ID: f"-1,,J -{JI, D
Groundwater Sample Collection Record
Project Name·. Ram Leather Date/Time Start:ll'I/ 2.>/07,
Project Number:
Local',on: Charlotte, NC
Weather:
Date/Time Finish:,,,/ z, /07,
Analysis: ,Jo 1 .. .4-:! r. 'l
Samoler: P•~I Co H~
1) Water Level Data (from TOC)
Total Well Depth
Well Volume per casing diamater
4 y, "f'j 1" V=0.041 xh V Volume of water
Water Table Depth :i-1. 4 $'" 2" V=0.163xh h Height of the water column
Water Column Length ).i.5"'J 3" V = 0.367 x h in the wen measured in feet
Water Volume in Well 1.s-1 4" V = 0.653 x h
TOC height above/below land (approx). 5" V = 1.020 X h
6" V= 1.463xh
2) Total Purge Volume
Purge Method
I O • 5'3 gallons
3)
Field Testing Equipment
Primary data collection method 0~;,.,,~Through)_'b~;,.,,;;=;;;,le~1 Other _______________ _ ------------~ ···---·-· ·-··---·-,.........._
Parameters
Time O'\ lO oq lie t:A 2 2. 0'1,,2 ") oq 1'1
Volume Removed (gal) lf,O 1.0 1;!,.0 I~-o 'l.0,0
Color ef:!':cl, .... , Clo...,,_::, c(o""'Aj ·cJe.tr~"'J c/(M.
Turbidity (NTU) ]04 .0 ,:4.( 1.'l. S" 14,7 ·I 'l. •
pH ,.,'( S"-~<t ,;,,1 r:i;q r,: ·10
Conductivity ( 1(: 7 I'/. 't l~.'i/ />, 0 l :,~'
DO (mg/L) q_('{ '3. 'f O 341 3.Y~ 3-3 ~
Temperature c0 I;-. 'f ,r-'f IS'.~ /~-~ i ,;. s
Reduction Potential (mV)
I ""
I,;( /'f s' /¥2. 111
OVA (ppm)
S..linity (%) '-/,IC l)o '¾) 1£ ;LO~ "11,,, I .06 "'1 IL J:12 "ti<-I .•fz~1 /L,. . I '-" ,,· ."'¾
Ferrous Iron
Filtered? Yes Gi Other Observations: T-.1,;J.,'.~ .,(c~,--r-10._ I{: ,...,..,___
Sample Turbidity (NTU) Ii,,. 0 --'i2"Z='::.::=--,J-..::S::.:·•.=-,llf"'l;:::~:.7c....:...· __________ _
Sample TiQle 01?, '/ • DO should be measured down-hole within the well screen or through a flow-through cell. All other parameters may be measured using either method, or from a sample collected from the purge line.
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Well ID: yY/w·Of
Groundwater Samole Collection Record
Project Name: Ram Leather
Project Number:
Location: Charlotte, NC
Weather:
1) Water Level Data (from TDC)
Total Well Depth
Water Table Depth
Water Column Length
Water Volume in Well
TOC height above/below land (approx).
Date/Time Start: G"'I / 2 s /07,
Date/Time Finish:C'J / Zi /07,
Analysis:
Samoler:
C,<f10
Well Volume per casing diamater
'3C-Y1 1· V=0.041 x h V Volume of water
-:23 31/ 2" V = 0.163 x h h Height of the water column
7, n 3" V = 0.367 x h in the well measured in feet
)-/~ 4" V = 0.653 x h
5" V = 1.020 x h
6" V=1.463xh
2) Total Purge Volume '3. ~,; gallons
3)
' Purge Method
Field Testing Equipment
.--.-.. -~
Primary data collection method ~~ Down-Hole Other
Parameters I '.l.<}
Time 1-3+,d!j) /3 o "J l'-1 a,
Volume Removed (gal) 1. ~ -z y 3. <
Color GI""'~ tie"'"'~ ~•""61
Turbidity (NTU) ,.41~ -+q'lC Y ·.'.flfO
pH :r~o '1..'7 3 Jo. ,;c
Conductivity ( g.o ,.r-~-I
DO (mg/L) 7. 7 I 1;~ I q. 0 -. :,, ~
Temperature C" r-,H,+ 2,.1 M.~ ) !. ~
Reduction Potential (mV) '!I /'( C 11 (.
OVA (ppm)
Salinity(%) '". l'-4
Ferrous Iron ,,)~ .:,
Filtered? Yes g: Other Observations: g,,..~ ,+ ~/-.. i.1-l-.. ,}I'~ ... •j;d {' I•
Sample Turbidity (NTU) n~o +-,,._, ':w:l; .• , ,-.., ;--f,·f·«•n,. t) .. I'"'"' 11·, .....,,Jt'. ,e· j,,.. r,rJ
Sample Time J'-{: 10 I);.;,.._. ,::,,_..,....·-,ti,.,lti·..::.. A-1..o ..... f-•<-"•'•'i-........ 'i" .....,." ,..,.:.rt.fi,.
• DO should be measured down-hole within the well screen or through a flow-through cell. All other parameters
may be measured using either method, or from a sample collected from the ~urge line.
R.--...1..:'"1,'7 ...,.,._ -fa.~ .... ~ ,.,_.. i,h,•<':nr, """"'-o!', cJ.,.,. ..• ,d ',\.
1°j•J 1"6W,
Well ID:
Groundwater Samole Collection Record
Project Name: Ram Leather Date/Time Start:O• / 2(. /07,
Project Number: Date/Time Finish:t11 / 7~ /07,
Location: Charlotte, NC Analysis: v.1~HI< a
Weather: Sampler: Pc
1) Water Level Data (from TOG)
Total Well Depth
Well Volume per casing diamater
2)
l'i> ,
Water Table Depth 1'.71
Water Column Length /lo3.7/
Water Volume in Well ,;i~. G i!
TOG height above/below land (approx).
Total Purge Volume
Purge Method
Field Testing Equipment
'2° gallons
1" V • 0.041 x h V Volume of water
2" V•0.163xh h Height of the water column
3" V • 0.367 X h in the well measured in feet
4" V • 0.653 X h
s· V • 1.020 x h
6" V • 1.463 x h
Primary data collection method Other _______________ _
3) Parameters
Time
Volume_ Removed (gal)
Color
Turbidity (NTU)
pH
Conductivity ( ,.• . )
DO (mg/L)
Temperature C0
Reduction Potential (mV)
OVA (ppm)
&alii 11ty {"/oJ -~ :,j . :·1 C. ~.: f.~.~
Ferrous Iron
Filtered?
fO'CO
/(a
t;l!"-•I'
; .. ·?
,f. ·:,'
!":, 'i
:.?~
1,../ 0
Io ·1
-:: . o:, f'·'•,'
,'(.
,, : I';
Yes No
IO~ 7.t; wn
?7. 'it/
Ckvc·, C 1 • .,,.,
32to ---~90
1 ,o 1 "1. '~
"]l(,q 4G, .0
1-7 'l 1 ·0\
17 1 1'7. \
; 7. -1. '
'.) .•,·;;: 111 ~1c
Other Observations:
ii A J'-QO /~O
0'-/ '20
(./•'¼·1 C/ovd.l
t-q ~o q'2.7
(,,.70 7,0~
y ~-" 'll/. i/
:l. S" I ';},-;1/,:,
I/,\ 11, 1
(;, \ J'3
o.,;f~x 0-177{_
' ~ X:::f •; o\ \....,, r chi11--<I,.., bo
Sample Turbidity (NTU) p, erobt, °"A' \J( I\ 1,..1.11", f-1 \ 1,.,..J._t> 'Ill fcc:1-a...,.l,t,. J""',;r i
Sample Time /'5/o 1~0 cL-.
• DO should be measured down-hole within the we"'ll'"s!.c.:.re""e""n-o-r"'th,--r-o-ug'"'h:-a::--;;flo=w:-:,-;;th::r:::-ou:::g:;h;-ce:::;;II'. 'A"'ll-;o"'th;;;e;;,-;;p;;a;;ra;;;m;;;e;;:te;;;,:;s
may be measured using either method, or from a sample collected from the purge line.
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Well ID: D w oo I I
Groundwater Sample Collection Record.
Project Name: Ram Leather Date/Time Start: c,•1/27 /07,
Project Number: Date/Time Finish: / /07,
Location: Charlotte, NC Analysis·. Je,.·t
Weather: Sampler: f) '-·
1) Water Level Data (from TOC)
T otat Well Depth
Well Volume per casing diamater
l'il 1 ,. O·'"
Water Table Depth ;l."/,0.>
Water Column Length ~«.•,, /~q, ~ffK
Water Volume in Well ,i7.•n
TDC height above/below land (approx).
2) Total Purge Volume
Purge Method
Field Testing Equipment
q,2 gallons
.,_..,! f;,,,
H-o..-: be. \)· 2.o / '-f ",I-)C B
'
1" V = 0.041 x h V Volume of water
2" V=0.163xh h Height of the water column
3" V = 0.367 x h in the welt measured in feet
4" V = 0.653 x h
5" V = 1.020 X h
6" V = 1.483 x h
Primary data collection method b~ ~-, Other _____________ _
"1 >r-S"'c. J:
3) Parameters
Time
Volume Removed (gal)
Color
Turbidity (NTU)
pH
Conductivity rl"f{,(11 )
DO ( mg/L) I-\.; n b "'-'
Temperature C0
11 :OG
l ~ <;."
cka.,
lk 3'
), ~7
/77
;/. I~
,-,. )
l s; Y ~
3 3 b
Lka.1
/Q,l
5 ,g-
~-$
35')
11)"c
1·,',7~ 16: ~:,' /<;::s'~ 1"'1, 26 p
½'1f '115 q,;s
c/,.,c c/<~l C(e,,._,
q .,--(c 1 If£]
'7-7?.. s-SI {}~
I<;. l1 tS-I /',s.) ,.,)' 'J, (,,'7 3. 27
n'S 11.'& 1,.11
I() f. f Red"etioa PeteRtio!-(mV)
OVA (ppm)
122 Fl.{ 14 I I., a /'l 'il ?rt
II v, ;r Saliai!J (%) ( Di·,\ ~~{
II Ferrous Iron
111 ~ !,'i'b I '-1 'i' {. ~~ I 5'2..
µ /A
Filtered? Yes ½) Other Observations: l)C' i'.:>,C'b'l:. i' wt.IL AbouL l,.,. I
I Sample Turbidity (NTU) /,;, ,. ,l...-
Sample Time
D
D
I
"' DO should be measured down-hole within the well screen or through a flow-through cell. All other parameters may be measured using either method, or from a sample collected from the purge line.
Well ID: "''" -ID
Groundwater Sample Collection Record
Project Name: Ram Leather Date/Time Start: ,,,, 21 /07,
Project Number: Date/Time Finish;,, /., ,, /07,
Location: Charlotte, NC Analysis:
Weather: Sampler:
1)
2)
3)
Water Level Dala (from TOG)
Total Well Depth
Water Table Depth
Water Column Leng1h
Water Volume in Well
I 2 "2
?."LH
l)~.rc,O
~1,;,1')
TOG height above/below land (approx).
Total Purge Volume
Purge Method
Field Testing Equipment
1,, f gallons
(;..,. .... ,_). (.,~ 5 :,.,,,_.,.~ 'l
Well Volume per casing diamater
1. V = 0.041 x h V Volume of water
2" V = 0.163 x h h Height of the water column
3" V = 0.367 x h in the well measured in feet
4" V = 0.653 x h
5" V = 1.020 x h
6" V = 1.463 x h
Primary data collection method Flow-Through Down-Hole Other
Parameters
Time
Volume Removed (gal) .
Color
Turbidity (NTU)
pH
Conductivity (
DO (mg/L)
Temperature c0
Reduction Potential (mV)
OVA (ppm)
SaliRil) {%) ,,,,.,H (t<'J)
Ferrous Iron
Filtered?
Sample Turbidity (NTU)
\C: 0 ('.',
Yes G
(1,1
----------------
4c D'-~ (Ye,\ ----cl,~,
Other Observations:
l,v,f,11
{2,,,.! ~ ·> ~,-,
i . .'J"·.
Sample Time ) -~00 ____ -·_· ---,--=---c==:-:c:;;--;;;;-::;;:::::;-;;:;;::;;;;;;;;;;;;-
• DO should be measured down-hole within the well screen or through a flow-through cell. All other parameters
may be measured using either method, or from a sample collected from the purge line.
@ Dy) p,---,,\)e ~ .f .....,.,.<-<-
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Well ID: Mw · ~o
' Groundwater Sample Collection Record
Project Name: Ram Leather Date/Time Start: 01/ ,, /07,
Project Number: Datemme Finish:<I / ,9 /07,
Location: Charlotte, NC Analysis: """
Weather: Samoler: P<-
1) Water Level Data (from TOC)
Total Well Depth
Well Volume per casing diamater
2)
3)
1i, 1" V = 0.041 x h
Water Table Depth 1.:1 .01 2" V=0.163xh
Water Column Length I('/.'), 3" V = 0.367 x h
Water Volume in Well .,,,;_,,
4" V = 0.653 x h
TOC height above/below land (approx). 5" V = 1.020 x h
6" V=1.463xh
Total Purge Volume
Purge Method
70 ,7 gallons
C.,,.,.,J (.,,
Field Testing Equipment
----··~-
Primary data collection method ~1 ~ Other
'15-z: ·roi;
Parameters
Time 1z.<O l 11 ~ lt..oC
Volume Removed (gal) -i,s ?, ., D,-(. 4o1)
Color C{£4.L ~{t:4.,C. cl,."'-,
Turbidity (NTU) ,3,. 0 , <-0 ·i,.G,
pH q. 7c 1 5c, g, 11
Conductivity ( C. •-~ ~ o.,; •le I .r Z
DO (mg/L) ,-. ~ 'j {:q' i; ,,:. 1
Temperature C0 l'i .)(! ,q. ~; 19, '-f )
Reduction Potential (mV) ) -,·2 -7 '3
OVA (ppm)
SBfflillY (l,/o) 1<r-,,(60 ""J{) v~ I<-v~ "-v~ IC
Ferrous Iron f'-'~
Filtered? Yes ~! Other Observations:
Sample Turbidity (NTU) 7.1.e,
Sample Time lboO
V Volume of water
h Height of the water column
in the well measured in feet
• DO should be measured down-hole within the well screen or through a flow•through cell. may be measured using either method, or from a sample collected from the purge line.
All other parameters
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I
Data:
Weather:
Project Name:
Project Number:
Sampler(e} Name:
Resident Name:
Resident Address:
Malllng Address:
(If different from Resident Address)
Resident Phone Number:
(Home and Work}
Date Installed:
Well lnstallatlon Company:
Depth:
Uses (check those applicable)
Drinking water:
Cooking:
Bathing:
Irrigation:
v
V
'{J
Does well have a chlorlnatlon system?
If yes, a spigot located outside of the chlorlnatlon aystem?
Other Information:
(see back of form)
Yleld: __ f'\J_....:3=--....:~"'¥/=f<tJ.'lJ'l-------
Yes
Yes
Parameter Units #1 #2 #3 #4 #5
· Time I b 3o (O 35: fo3"J
Volume ,.,_, I .s--lo ,;;~
DH :J {;, 'l I /,,, 77 I/ r't't
TemDerature ~ L Jo. ll It. 3-g 17.? l
Sp. Conductlvltv t1<-5/4 ii'\ /. J '-( () 'qc;c, o,Cjyt,
Fleld Instrumentation:
Location ohplgot for sampllng: .At /4t<. c-t{ J'n.-.-.S. dt, fr M /JU.<<
Sample ID: _,_/?1....,.M~a..:'t .... v'--'f=+y ________________ _
Sample DatefTlme: O 'z ~ Je, -o 7 /;d l/ tJ -"--'-""'-''--'::C..:.--,7"-'-"--''--'-----------------
Analyses:
Laboratory:
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ff
D
Date:
Weather:
Project Name:
Project Number:
Sample'1a) Name:
Resident Name:
Resident Addrase:
Malllng Address:
(If different from Resident Address)
Resident Phone Number:
(Home and Work)
Date Installed:
Well lnstallatlon Company:
Depth:
Uses (check those applicable)
Drinking water:
Cooking:
Bathing:
Irrigation:
Does well have a chlorlnatlon system?
~otable wau sampllrig Form/ .: .:', .... .. .. '. ., .. , I
Time: __ _,_,/ '3L..!-'/ =!..5'" ____ _
.:. ·.-, : • ·• Project lnfonnatlon ;-•. -.,,,. I
Mr. , IA...l.k.<-,,..
Yleld: ____ l"'\J __ ;;)_5"_,_,_¥-0"-'0J..L.... __ _ J,
/\J,.
ND
rJ 0
~
If yes, a spigot located outside of the chlorlnatlon system?
Yes
Yes No
Other lnfonnatlon:
(see back of fonn)
Parameter Units #1 #2 #3 #4 #5
Time Jt.fot-f /'/0'6 l'--f/',
Volume 11 D. l $""0 IS-o ""2,oo
DH v_ 7,oa, r. qt;, ~.1)
Temoerature "'l ,] 0 I fL/ r°J,:Jr ll.'l:J
So. Conductlvltv llt ¾111 () ,ti! I. 31 0.1:;c;,
Field Instrumentation:
Location of spigot for sampling: ""A--'-'t'--..,vt,K'-"-_{_( _________________ _
Sample ID: ....L..fA=,M.,_.__-r....,.,, l..1.C.cl-E::i.-'-'(<._~n'-'-3.,_ ____________ _
Sample Date/Time: __.C,,_,.9_-_;;l:....":..... -:....t):...._r _________________ _
Analyses:
Laboratory:
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n
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I
/Vl rvAI~
: :, -
Date:
Weather:
Project Name:
Project Number:
Sampler(s) Name:
Resident Name:
Resident Address:
Malling Address:
(If different from Resident Address)
Resident Phone Number:
(Home and Work)
Date Installed:
Well lnstallatlon Company:
Depth:
Uses (check those applicable)
Drinking water:
Cooking:
Bathing:
Irrigation:
Does well have a chlorination system?
,..
V
If yes, a spigot located outside of the chlorination system?
Other Information:
(see back of form)
Time: _____________ _
Yes
Yes
'19
No
•
I
· "': .• : ... , ~: .: .,;~ ,. , . : ·.,: : ... :.)-,;, ~~");.v_~-\ ,~''.L r.-F'u G'Data;-: \•~1., ~-';'.(,r~~~---~ 1;:t ~ ;~1. .. : ,t:' •'. ·t-,,;-_ 'ft :~; >;:;_!•.;.: .:/;~t-~~•,,-~~i.!~-~ I
Parameter ""11 tf11lt9
Time
Volume 'lt1-I /f;-
~
pH -(,;,(,,Q
Temperature "c... 19, ~ 1 ~
''% Sp. Conductivity lm ]I~ 0. ,.:ro~
Field Instrumentation:
Location of spigot for sampling:
Sample ID:
Sample OatefTlme:
Analyses: voA-
Laboratory:
a ~ .tw,
~ c)-~,-
~I) I/ l::j" ,'6 ~
/1.Y) j"'7. 31
I. 10 ©.'73/
#3 #4
-,.
.
#5 I
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I.
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Data:
Waathar:
Project Name:
Project Number:
Samplar(a) Name:
Raaldant Name:
Resident Addraaa:
Malllng Address:
(If different from Raaldant Addraaa)
Raaldent Phone Number:
(Homa and Work)
Data Installed:
Wall lnatallatlon Company:
Depth:
Uses (check thoaa applicable)
Drinking water:
Cooking:
Bathing:
Irrigation:
a L
'
Does well have a chlorlnatlon system?
~ J!-~t Time:
4d : j f05 {u nn1:1
7
' Ylald: ___ 7..:~:._ ________ _
If yea, a spigot located outside of Iha chlorlnatlon system?
Yea
Yea
Other Information:
(see back of form)
Parameter Units
Time / 35v
Volume c;. t-1• f lo
_/
&,, 7J pH
Temperature P(._, /C/_ ).)
'"¾ So. Conductlvltv l m I . I <;
Fleld Instrumentation:
Location of spigot for sampling:
Sample ID:
Sample DatefTlme:
Analyses:
Laboratory:
#1 #2
/"3 3:) I 5 'j' G. ,~-;;Jo
(p,C/<t 7.oo
It OD / 7. 71
I, 'll.f /, {,,d
#3 #4
f ,.-_,· .• '
' ·,;
#5
·,
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Data:
Weather:
Project Name:
Project Number:
Sampler(a) Name:
Resident Name:
Resident Addre88:
Malllng Address:
(If different from Resident Addr88s)
R88ldent Phone Number:
(Home and Work)
Date Installed:
Well lnstallatlon Company:
Depth:
Uses (check those appllcable)
Drinking water:
Cooking:
Bathing:
Irrigation:
✓
Does well have a chlorination system?
f C.o/.L
1
'2. ..
If yes, a spigot located outside of the chlorination system?
Other Information:
(sea back of form)
Time: /J,'00
Yield: 1
0 -------------
Yes
Yes
Parameter Unit& #1
Time I 3oS-130"1
Volume 6..,.,\ :> IO
./ /, /( {;, l,C, pH
Temperature O C. /C,, 5 I l'l.Jt
Sa. Conductlvltv "'3/lWI D-Y~;) 0,7'6;)
Field Instrumentation:
Location of spigot for sampling:
Sample ID:
Sample Date/Time:
I
Analyses: Vo.A
Laboratory: l
#2 #3 #4 #5
l"31'-{
;; ~
5, 7~
/7, ~ 3
o.sr7
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...
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"I : :l , ..
:"·'1 ..
. ~: ;,,I
:::! .
.. I
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Date: Time: /D '. O <>
Weather:
'" I\ I\ ::1
Project Name:
Project Number:
Sampler(s) Name:
Resident Name:
Resident Address:
Malllng Address:
(If different from Resident Address)
Resident Phone Number:
(Home and Work)
Date Installed:
Well Installation Company:
Depth:
Uses (check those applicable)
Drinking water:
Cooking:
Bathing:
Irrigation:
, lo 1--t
1
Does well have a chlorination system? 1,
If yes, a spigot located outside of the chlorination system?'\
'
Other Information:
(see back of form)
Yield: l --+-------------
Yes
Yes
No
No
•
Parameter Units #1
Time lo~o 1p
Volume "'A-I (o
J /,l),3 oH
T em oerature O (_ .QS-:s~
So. Conductlvltv "'f cM 0.1 II
Field Instrumentation:
Location of spigot for sampling:
Sample ID:
Sample Date/Time:
Analyses:
Laboratory: f L
#2
lo.' I;)
I'\
7:--< 5
ld 3 .<a3
I. ab
#3
I O: I b
;;:Jo
·7,y5"
J ;;;, ~Lf
f) .C,C,9
#4 #5
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1:
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1:
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I ,,
I
Weather:
Project Name:
Project Number:
Sampler(s) Name:
Resident Name:
Resident Address:
Malling Address:
(If different from Resident Address)
Resident Phone Number:
(Home and Work)
Date Installed:
Well Installation Company:
Depth:
Uses (check those applicable)
Drinking water:
Cooking:
Bathing:
Irrigation:
Does well have a chlorination system?
f,Col-<
✓
v
If yes, a spigot located outside of the chlorination system?
Other Information:
(see back of form)
Yleld:_<._~_j__,pl"-'-M.,__._ ____ _
Yes @
Yes No
Parameter
Time
Volume "·" I
J
DH
Temceratura O C
So. Conductivity ;o,v,/4 ,l-
Field Instrumentation:
location of spigot for sampling:
Sample ID:
Sample Date/Time:
Analyses:
laboratory:
I
Units #1
. . .. 0'1'?, 5.
. ?.o.
(,; (i',f
{f,J?.
' 0,7;);)
... ' ............ , ', ~ .. ,. -... . . . .. .
#2' #3 #4
-~'i.--t~. "'/453
.-.: 4·o ·ro D
~ I 7> '( l,,c)V
:t1,, i~{ ·. 11.01
0.1~1 11,'710
.
#5
' .
,·~--..
·:· .... ' •r
., . '
.
: ~·trt '1 : ... ,,.
"
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0
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Date: Time: _ _._( .... '.f ... 3,._$"-,,.-------
Weather:
Project Name:
Project Number:
Sampler(&) Name: /, eot~
Resident Name: _ ....... '1?_.,_/4r-=--''---'7_k-_G_k,_~ _______________ _
Resident Address: / 5 ;:J d I 5{_ I h .t, M PY / <
Malling Address:
(If different from Resident Address)
Resident Phone Number:
(Home and Work)
Data Installed:
Well Installation Company:
Depth:
Uses (check those applicable)
Drinking water:
Cooking:
Bathing:
Irrigation:
Does well have a chlorlnatlon system?
rv 1411
1 o o '
II yes, a spigot located outside of the chlorlnatlon system?
Other Information:
(see back of form)
Yield:/ 0 -1 'J J ol(/ , r
Yes st!,
Yes No
Parameter Units #1
Time /~JO
Volume i:,c,, I / .~i>
J
t~ r. I pH
Temperature O
( !:)?.;) D
Sp, Conductlvltv rlW/4"" I Ct'
Field Instrumentation:
Location of spigot for sampling:
Sample ID:
Sample Date/Time:
'
Analyses: \)!)A
Laboratory: El
#2 #3
I Y 37 144 ·'J_
;;)Do ~so
l. <,; \. l 1. s
JJ,t:C.,. J;),'-1;)
A ··-ii¼ I . I o ' '
#4 #5
".,, .f 1'
d"/' /.:/::<:~
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•·
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1·
:I
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I
Date:
Weather:
Project Name:
Project Number:
Sampler(s) Name:
Resident Name:
Resident Address:
Malllng Address:
(If different from Resident Address)
Resident Phone Number:
(Home and Work)
Date Installed:
Well Installation Com_pany: ··-.::.,.
Depth:
Uses (check those applicable)
Drinking water:
Cooking:
Bathing:
Irrigation:
f) i --;;. r--0 I Time: __ /...,3'-''~Y ..... s .... "' _____ _
1' 'tb 'fs ;;::,,..ma 5
f. Cole
Yleld: _ ___._l-""'"~'--J-1-f1--)'Vl ____ _
Does well have a chlorination system? Yes
Yes If yes, a spigot located outside of the chlorination system?
I
Other Information:
(see back of form)
'
Parameter Units #1
Time I /1S"~
Volume r..o,, I ,'"\.,;) 0
.,I ,. I I pH
Temperature PL ::J?.o 1
SP. Conductlvltv ~lf1 0, t,;;,
Field Instrumentation:
Location of spigot for sampllng:
Sample ID:
Sample Date/Time:
Analyses: VoA
Laboratory: EL
#2 #3
/l/00 I l/oS-
"43o "'Yo
/p.7?, fi, 77
,Q/,/1 ,? I I I
0, 71 <, I}, 1,, 71
#4 #5
.
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II
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I
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I:
I ,,
I
I
I
I .,
I ,,
I
I,
I·
I
Date:
Weather:
Project Name:
Project Number:
Sampler(&) Name:
Resident Name:
Resident Address:
Malling Address:
(If different from Resident Address)
Resident Phone Number:
(Home and Work)
Data Installed:
Well Installation .Campliii~--
Depth:
t, . ~A. '-\le, (, oc L l ou,.. -
Uses (check those applicable)
Drinking water:
Cooking:
Bathing:
Irrigation:
Does wall have a chlorlnatlon system?
J
✓
./
If yea, a spigot located outside of the chlorlnatlon system?
Other Information:
Time: "' ( '-{ 0 D
5 I.,(,, n ,, j
Yea
Yes
(see back of form)
~
Units'
. ' t ..
Parameter #1·· .. #2.· :'°'..,, -#3
Time IL{ I I:, • . I 4 ,;, 1'1~1
Volume. Dv, I "'-l r;v ., ·"'.?ov /\Jd)'~
,J '4,-, I' ~. ~J . v·, ~v pH
Temperature C[ {'1. 7'? 14 :io '/9,;)5'
"'½ Sp. Conductivity l m 0, c;:YS' C-· l,(,'1' 0, 7'-f.~
Field Instrumentation:
1. ~\ I.I \ li,efr-'r, < \ I Location of spigot for sampllng: A " W ..{., f'<-"-.cl e+:--t-, ,;:;...._...
Sample ID: T µ_,JL.-(4 _ 6 ?
Sa,mple Date/Time: 01/~S'/~ J I
1 '-{ Jt;'
Analyses: u' A-
Laboratory: p(; l, ..... -. ,,
:
. #4
. '
.
~ . : ; , #5:---·
-"\:·',
... "( . •t
... : ;
. .. ..
1 .. ,. :, .. : .·• ,· . .. . .-••·,.
'
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g
I
n
g
Date:
Weather:
Project Name:
Project Number:
Sampler{s) Name:
Resident Name:
Resident AddreSB:
0 /' JS-o 7 Tlme: __ __.(....;;]'--',' .... /J'-'0 ____ _
Oro[ / b,2._ -JJ.:<-" "j
,[of-<..
I· Malllng AddreBS:
I
I
I
1·
I
I ,,
I
I
I
I
(If different from Resident Addl'888)
Resident Phone Number: ·; D L/ -S-1../ J -(.,, 3 7 d
(Homa and Work)
Date Installed:
Well lnstallatlon Company:
Depth:
UsBB (check those appllcable)
Drinking water:
Yleld: __ -;;J_'f_,__j"'Hl'f:..:.iV1....._ ____ _
V
Cooking: V
Bathing: V
Irrigation:
DoBB well have a chlorlnatlon system?
If yes, a spigot located outside of the chlorlnatlon system? /V / tr
Other Information:
(see back of form)
YBB
YBB
~
No
Parameter Unlta #1 #2 #3 #4 #5
Time I 3oS-(301 13/0
Volume II.I\ I ~ 'i 5
DH J (,, :1&, 1,o"'3 101
TemDerature
4 L /°l,<{i I f.3x ;t. 'I)~
Sp. ConductlvltvMf/t f'1 o.croo f), °J(j' fJ,";/u
Fleld Instrumentation:
Locatlonofsplgotforaampllng: At wt/{ hl41 bt-{dr~ flt.-wa
Sample ID: _:_Nt.:......:.M....::-~fl:~-R.c.::.Ac::.,,_:_Ue,_LL..__ _____________ _
Sample DatefTlma: 13 : Io
Analyses: oA
Laboratory: c (..
I
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I
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I ,,
I,
,f ,,
I
I
I ,,
I
Date:
Weather:
Project Name:
Project Number:
Sampler(s) Name:
Resident Name:
Resident Address:
Malling Address:
(If different from Resident Address)
Resident Phone Number:
(Home and Work)
I
Date Installed: _ __,U.,:.;;.;.;llc,:k~n""-"o..:W.;;..:.Yl.,:_ ________________ _
Well Installation Company: __ U.__,_n._...kC-'n...:....;;o_w __ fl ___________________ _
Depth:
Uses (check those applicable)
Drinking water:
Cooking:
Bathing:
Irrigation:
Unknow fl
v
V
Does well have a chlorlnatlon system?
If yes, a spigot located outside of the chlorlnatlon system?
Other Information:
(see back of form)
Yleld: _ _./).c...:....:..vf:...:.k_n_c_o_L,V_Vl ___ _
Yea
Yes
0
No (\/,A-
Parameter
Time
Volume
nH
Temnerature
So. Conductlvltv
Field Instrumentation:
Location of spigot for sampling:
Sample ID:
Sample DatefTlme:
Analyses:
Laboratory:
Units #1 #2 #3 #4 -I ~-d (.. /?.' .,o
Q:'},;,c. / _;;r . .) c--,..., -~.3o 0, "53
~ (._ Ii .30 /%,)7
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Date:
Weather:
Project Name:
Project Number:
Sampler(s) Name:
Resident Name:
Resident AddrsBS:
Malllng AddrBBS:
(If different from Resident Addrsss)
Resident Phone Number:
(Home and Work)
Date Installed:
•· Pro act lnfonnatlon·.-
ID )D l C.oh~ f. d
;}oD I
Well lnstsllatlon Company: { Olrv I: r1e,_ lv.1. I I
Depth:
Uses (check those appllcable)
Drinking water:
Cooking:
Bathing:
Irrigation:
• Does well have a chlorlnatlon system?
If yes, a spigot located outside of the chlorlnatlon system?
Other lnfonnatlon: -8 itw
(see back of fonn)
Yleld: ('\) ""f <. u.J
Parameter Units
Time I 9 3 c;
Volume c.,, I c;
..)
&}, t 'J DH
Temperature ~l 16.fR( . ;k¾ SD. Conductlvltv • ( "'1 O.)GO
Field Instrumentation:
Location of spigot for sampling:
Sample ID:
Sample Date/Time:
Analysea: V 1k
Laboratory: ftl-
I IJ/j
#1 #2
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lo I~
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Date:
Weather: J,
Project Name:
Project Number:
Sampler(&) Name:
Resident Name:
Resident Add1'888:
Malllng Address:
(If different from Resident Address)
Resident Phone Number:
(Home and Work)
Date Installed:
Well lnstallallon Company:
Depth:
Uses (check those appllcable)
Drinking water:
Cooking:
Bathing:
Irrigation:
Does well have a chlorination system?
oCJ-J'l-tJ1 Tlme: __ ,.__/3_. _J_o _____ _
~ D ~ 5)1, YJ I! t? -ID, / '(° Ykcfb &t?5t w :11 d
tl~
Realdent lnformallon •i ~' ·. ,. ·;:-
7 .
Yleld: ____ 7..._ ______ _
If yea, a spigot located outside of the chlorlnatlon system? 1..., Yes
Yes
Other Information:
(see back of form)
Parameter Units #1 #2 #3 #4 #5
Time 1355' /3f'1 /40 '-1
Volume -~ I 'Jo 3o !> 0
DH / (: .C,;) t.C, I t 7;)
TemDarature " C I !.f;} /f,}d ;g,;)')
M1/i SD. Conductlvltu c,111 ~.~13 6_<,,C, o j.177
Field Instrumentation:
"':' \
Location of spigot for sampllng: L..;1_/: _ _./;X-'-"-_/_( __ hL;.;;...::q....._J _____________ _
Sample ID: MM ,., Y:Gd?,ES T {M {1 MS O _)
Sample Date/Time: .......,6 .... j._-_..p)..,.i!"----b...:.7,,_/...,/ .... r'-"l)__.t::.__ _____________ _
I
Analyses: {I,) ,c,
Laboratory:
----l-~.l.,!..!-l£..J,'i..1_.~Cf..lL/..._..!.l..!.c/..!...=i:... _ ___!_.!::..:ic!..__,;;;.~_L!_~µ.L.::J.,_,....LJL-~:..&.'.i::..._~~~::.........;=;J
;..::.....!...'..n:;;_:J_J,-;-;=~...JLf-'/..L____!,J~=-:..,.....,..L.::J.q-:::.L.:t.~...:L!,:_..2,~~-,---c:i'L!!.L~:.S-~~c
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APPENDIX B
2007 Analytical Data Packages
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Analytical data is provided on CD.
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APPENDIX C
2007 Data Validation Reports
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ENERGY WATER INFORMATION GOVERNMENT
Date:
Subject:
From:
To:
October 22, 2007
Organic Data Validation for SDG 2507667
Ram Leather Site
Suzanne Prouty, Validator
Environmental Scientist
Georgia Office
Nancy Gellar
Black & Veatch Special Projects
Project Manager
Gina Montgomery, Oversight Reviewer
Lead Scientist, Georgia Office
Black & Veatch Special Projec_ts Corp. • 1120 Sanctuary Parkway• Suite 200 • Alpharetta, GA 30004 USA. Telephone: [phone] • Fax: [phone]
I. OVERVIEW
This report presents the results of the Region IV data validation for samples collected at
the Ram Leather Site. PEL Laboratories, Inc. analyzed 15 water samples under SDG
2507667. The water samples were analyzed for volatile organics (SW-846 Method
8260).
The samples were assessed based on the data review criteria specified in the United
States Environmental Protection Agency Region 4 National Functional Guidelines for
Organic Data Review, June 2001.
II. SUMMARY
All samples were successfully analyzed. No data were rejected.
III. MAJOR PROBLEMS
No major problems were noted.
IV. MINORPROBLEMS
Volatile Organic Compounds
• The preservation and holding times were acceptable.
• The Method Blank results were acceptable. No contaminants were
· present.
• The performance of the Deuterated Monitoring Compounds (DMCs) was
acceptable.
• The surrogate percent recoveries were acceptable for all compounds.
• A matrix spike was not requested.
• The laboratory control spike had acceptable percent recovery (¾R).
• The initial calibrations had acceptable relative response factors (RRFs)
and percent relative standard deviation (¾RSD) for all compounds.
• The secondary source calibration had acceptable percent difference for
all compounds.
• The continuing calibration had acceptable percent difference and RRFs
for all compounds.
• The data set did not include a performance evaluation sample.
• The instrument performance check (!PC) was acceptable.
• The internal standards were acceptable for all compounds.
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V. NOTES
' Tentatively Identified Compounds (TICs) were not provided in the data package;
therefore, this information has not been evaluated.
VI. REPORT CONTENT STATEMENT
This validation has been validated in accordance with the United States
Environmental Protection Agency Region 4 National Functional Guidelines for
Organic Data Review, June 2001. The content of this report addresses reasons
for qualifiers and questions which might affect data usability.
VII. ATTACHMENTS
Appendix A -Glossary of Data Qualifiers
Appendix B -Table I -Summary of Analytes Failing Criteria
Appendix C -Sample Results Based On Data Validation
Appendix D -Sample Results as Reported by the Laboratory
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Calculations I
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I r'e L :::> Pb L-:::i o , lo lo ,
L ODCYCL~ (or\ iYD \ 2il/YI p It
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l1\'\111·0J Co.\;bfQ,-hDn ~ Con-h0ui!j CoJJ b(tlfi~n
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-::,233 /
I I S<::CJ:Dd.Q\{J Sax@ C1,\ i \:,; ,t,-\i [J}-,
'/. D ~ ~-Chlifotn(m
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Organic Review Summary I
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APPENDIX B:
ORGANIC DATA REVIEW SUMMARY
CASE NO. __________ SITE __ R'-"a"'m"'-"L"-'ea"'th,,,e"--r ________ _
LABORATORY PEL Laboratories NO. OF SAMPLES/MA TRIX 15 water
SDG NO. 2507667 SOW NO. ______ _ REGION.~l~V __ _
REVIEWER NAME ,,_Su,,,z,,.a!.enn,.,e:..,P__cro,,,u,,ty,__ ____ COMPLETION DA TE I 0/25/2007
CLP PO: ACTION -----~ ___ FYI _____ _
REVIEW CRITERIA FRACTION
VOA BNA PEST/PCB
I. PRESERVATION 0
2. GC/MS OR GC/ECD fNSTRUMENT
PERFORMANCE CHECK 0
3. fNITIAL CALIBRATION 0
4. CONTINUING CALIBRATION OR
CALIBRATION VER!FICA TION 0
5. BLANKS 0
6. DEUTERATED MONITORING COMPOUND
SURROGATE SPIKES 0
7. MA TRIX SPIKES/MA TRIX SPIKE
UPLICATES X
8. LABORATORY CONTROL SAMPLE .. ;.\t.?, "' ·-:'-1:' ·: ~-:_.· -'!)"" •• .,,:--·--.'
-· ,,:.-.;·. ... ,.::, • ,··•,
9. REGIONAL QA/QC 0
10. INTERNAL ST AND ARDS 0 -,·,:~,_(,._i'f:\\ -~··; ...• \ ~-~,~-
I I. FLORISIL CARTRIDE PERFORMANCE ~~':;/~,~:-(~f J:~-~-r._.:t~i :;:; -·:t;·_.-< ~ CHECK ~.·: ~i;;:t_·;];}~~;. X1 tt·,.~1::.t, , t,,• \). r .. c..,. ··'-"' .•. ,,ii , .• .,
12. TARGET COMPOUND IDENTIFICATION 0
13. COMPOUND QUANTITATION AND
REPORTED CRQLS 0
14. COMPOUND QUANTIT A TION
AND REPORTED CRQLS 0
15. TENTATIVELY IDENTIFED COMPOUNDS X ·_f':)\:·.~::;};: :~ .. ?:'•-:f. ~. :i
16. SYSTEM PERFORMANCE 0 ':: ·;:Z',ii-~:~;: '~;;, . .":;· f\:; .::~
Appendix A
Glossary of Data Qualifiers
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DATA QUALIFIER DEFINITIONS
The following definitions provide brief explanations of the national qualifiers assigned to results in the data review process. If the Regions choose to use additional qualifiers, a complete explanation of those qualifiers should accompany the data review.
u The analyte was analyzed for, but was not detected above the level of the reported sample quantitation limit.
J The result is an estimated quantity. The associated numerical value is the approximate concentration of the analyte in the sample.
J+ The result is an estimated quantity, but the result may be biased higb.
J-The result is an estimated quantity, but the result may be biased low.
R The data are unusable. The sample results are rejected due to serious deficiencies in meeting Quality Control (QC) criteria. The analyte may or may not be present in the sample.
UJ The analyte was analyzed for, but was not detected. The reported quantitation limit is approximate and may be inaccurate or imprecise.
Appendix B
Table I -Summary of Analytes Failing Criteria
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l!!!!9 Clliiia &iii! liiiiill liii8
QC R..,,, uiremebt I A.aaJyte1 Failing Criteria
& Criteria I
R:\48697 -Ram Lcalhcr Rl-FS\J)ata ValiJatioo\SDG 2507667\2507667 table.xis
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- --Table I
Summary of Analytc• Failing Criteria
Ram Leather Site
SDG 2507667
Aoalvtiul
Method
-
I Re.ult
I Fl ..
No sample results were qualified for thu sample delivery group.
-- - ----
I Resuh Flae: Annlied To
I (S.--ifk A.aalvtes ln)
AppendixC
Samples Results Qualified Based On Data Validation
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No data was qualified based on the data validation.
AppendlixD
Results as Reported by the Laboratory
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VOLATILEOROANICANALYSIS DATA SHEET
EPA Sample No.
Lab Name: PEL Laboratories, Inc. Contract: RAM LEATHER/ 048697.01.03 RAM_MW02
Lab Code : PEL=----Case No.:
Matrix: WATER -------
Sample wt/vol: _5 ___ Units: _M_L ____ _
Concentrated Extract Volume: 5 ---
Lewl:(low/med) _L_O_W ____ _
PercentSolids: .~ ___ decanted: ( __ _
Extraction: PURGETRAP
GPC Cleanup : ( YIN ) ___ pH:
Column(1): DB_-8_2_4 ___ _ ID: 0.18
CONCENTRATION UNITS: UG/L ----·--
CASNO. ANALYTf!
75-71·8 Dlchlorodtftuoromethane
74-87-3 Chlorcmethane
75--01-4 Vinyl chloride
74-83-9 Brome methane
75--00-3 Chloroethane
75-89-4 Trichlorofluoromethane
75.35-4 1, 1-0lchloroethene
75-15--0 Carbon disulfide
75--09-2 Methylene chloride
158-80-5 trans-1,2-Dlchloroethene
75.34-3 1, 1-Dichloroethane
67-84·1 Acetone
156-59-2 cls-1,2-Dlchloroethene
74.97.5 Bromochloromethane
78-93-3 2-Butanone
67-66-3 Chloroform
71-55-8 1, 1, 1-Trichloroethane
56-23-5 Carbon tetrachlor1de
71-43-2 Benzene
107--08-2 1,2-Dlchloroethane
79--01-8 Trichk>roethene
78-87-5 1,2-0ichloropropane
75-27-4 Bromodlchloromethane
10061--01-5 cia-1,3-Dlchloropropene
108·10-1 4-Methyl-2-pentanone
108-88-3 Toluene
10061--02-8 trans-1,3-Dichloropropene
Cll'Ol17'"''
SAS No: ______ SOG No.: _2_5_07_68_7 ____ _
Lab Sample ID: 250768701 Lab FIie ID: 66701.D
Data Received: ~0~9/2=7/~07~-----------
Date Extracted:
Date Analyzed:
Dilution Factor:
Station ID:
RESULT
10
1
5
1
5
Fomn I
2507667
10/02/07
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Time: 1120 =~-
VOLATILE ORGANIC ANALYSIS OATA SHEET
EPA Sample No,
Lab Name: PEL laboratories, tnc. Contract: RAM LEATHER I 048897.01.03 RAM_MW02
Lab Code : PEL Case No.: ----
MatriX: WATER -------
Sample wt/vol: _5 _________ Units: M_L ____ _
Concentrated Extrad Volume: 5 "•---------·-
Lewl:(lowlmed) ~OW ____ ..
PercentSollds: O decanted: (
Extraction: PURGETRAP ----------
GPC Cleanup : ( YIN )
Column(1): _D_B_-8~2~•----
.. pH:
ID: 0.18
CONCENTRATION UNITS: UGIL ~--
CASNO. ANALYn!
79-00-5 1, 1,2-Trlchloroethane
127-18--4 Tetrachloroethene
591-78-e 2-Hexanone
124◄8-1 Olbromochloromethane
106-93◄ 1,2-Dlbromoethane(EDB)
108-90-7 Chlorobenzene
100◄1 ◄ Ethylbenzene
100◄2-5 Styrene
75-25-2 Bromoform
98-82-8 lsopropylbenzene (Cumene)
79.34.5 1, 1,2,2-Tetrachloroethane
541-73,1 1,3-0lchlorobenzene
106◄8-7 1,4-Dlchlorobenzene
95-50-1 1,2-0lchlorobenzene
98-12-8 1,2-0fbromo-3-chloropropane
120-82-1 1,2,4-Trlchlorobenzene
87-81-8 1,2,3-Trichlorobenzene
1330-20-7 Xylene (total)
1634-04-4 MTBE
76-13-1 1, 1,2-Tr1chlorotrifluoroethane
108-87-2 Methyl Cyclohexane
79-20-9 Methyl Acetate
110-82-7 Cyc:lohexane
01,cm , .. ,
SAS No: SDG No.: "2"-50"7-'-68"7 ___ _
Lab Sample ID: _2~-~?~?0J ___ ....... Lab FIie ID: 68701.D
Date Recel\Hld: 09127107 •-•----•••H• ••-• -••• ---•••--•••••
Date Extracted:
Date Analyzed: 10/02/07 __ _
Dilutlon Factor:
Station to:
RESULT
1
1
5
1
2
2
1
5
Form I
__________________ Method: ~
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VOLATILEORGANICANALYSIS DATA SHEET
EPA Sample No.
Lab Name: PEL Laboratories, Inc. Contract RAM LEATHER/ llo48697.01 .03 RAM_MW02D
Lab Code : -'P-=E:::L ___ _ Case No.:
Matrtx: ~W:..:A:..:T.:.:E:::Rc:._ ___ _
Sample wt/Vol: _,5,____ Units: .:,Mc,L,_ __ _
Concentrated Extract Volume:
Level:(low/med) LOW . -----·· -------
PercentSolida: O,c__ __ decanted: ( _________ _
Extraction: PURGETRAP
GPC Cleanup : ( YIN ) ··----pH:
Column(1 ): _,D::,B,c-8:,.:2,::4:_ __ _ ID: 0.18
CONCENTRA T/ON UNITS: ..::U:.:G:::IL:._ ___ _
CASNO. ANALY1li
75-71-6 Dichlorodlffuoromethane
74-87-3 Chloromethane
75-01-4 Vinyl chloride
74-83-9 Bromomethane
75-00-3 Chloroethane
75-<39-4 Trichlorofluoromethane
75-35-4 1, 1-0lchloroethena
75-15-0 Carbon disulfide
75-09-2 Methylene c:nlonda
158-80-5 trena-1,2-Dlchloroethene
75-34-3 1, 1-Dichloroethane
67-64-1 Acetone
156-59-2 ds-1,2-Dlchloroethene
74-97-5 Bromochtoromethane
78-93-3 2-Butanone
67-<36-3 Chloroform
71-55-8 1, 1,1-Trichloroethane
56-23-5 Carbon tetrachloride
71-43-2 Benzene
107-06-2 1,2-0ichloroethane
79-01-8 Trichloroethane
78-87-5 1,2-Dichloropropane
75-27-4 Bromodichloromethane
10081-01-5. da-1,3-0ichloropropene
108-10-1 4-Melhyl-2-pentanone
108-88-3 Toluene
10061-02-8 trans-1,3-0ichloropropene
o,uio, ,.,
SAS No: ______ SDG No.: ~2cc5.::07:..:86=7 ____ _
Lab Sample ID: 250786702 Lab FIie ID: 86702.D
Date Received: .::0::c9/2=7/0.::7:.___ ________ _
Date Extracted:
Date Analyzed:
Dilution Factor:
Station ID:
RESULT
10
0.82
5
Form I
2507667
,0/02/07 __ _
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Time:
Method: B26Jl
1d
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VOLATILE ORGANIC ANALYSIS DATA SHEET
EPA Sample No.
Lab Name: PEL Laboratories, Inc . RAM_MW02D .. ··-···-· --·· ----·
Lab Code: _l"_E,:L _________ Case No.: ___________ SAS No: ______ .. _________ SDG No.: .2.~0J_~--------__ _
Matrix: W,\!_~!3___ _ Lab Sample ID: _ 2~7_!!~702_ Lab FIie ID: ~702.D _
Sample wt/vol: 5 Unns: ML
Concentrated Extract Volume: 5
level:(lowlmed) LOW
PercentSolfds: O decanted : (
Extraction: PU_RGETRAP _______ _
GPC Cleanup: ( YIN ) pH:
Column(1): _DB-624 ________ _ ID: 0.18
CONCENTRATION UNITS: _IJG_/L~---
CASNO. ANALYTE
79--00-5 1, 1,2-Trichloroethane
127-18-4 Tetrachloroethene
591-78-8 2-Hexanone
12448-1 Dlbromochloromethane
108-93-4 1,2-Dlbromoethane(EDB)
108-90-7 Chlorobenzene
100-41-4 Ethylbenzene
100-42-5 Styrene
75-25-2 Bromoform
98-62-6 lsopropylbenzene (Cumene)
79-34-5 1, 1,2,2-Tetrachloroelhane
541-73-1 1,3-0lchlorobenzene
106-46-7 1,4-Dlchlorobenzene
95-50-1 1,2-0ichtorobenzene
96-12-8 1,2-Dlbromo-3-chloropropane
120-82-1 1,2,4-Trtchlorobenzene
87-61-6 1,2,3-Tr1chtorobenzene
1330-20-7 Xylene (lolal)
1634--04-4 MTBE
76-13-1 1, 1,2-Trlchlorolr1ffuoroethane
108-87-2 Methyl CycJohexane
79-20-9 Methyl Acetate
110-82-7 Cydohexane
Ol><lfft••
Date Recelved: 09/27/07
Date Extracted:
Date Analyzed: 10/02/07
Dllutlon Factor:
Station 10:
RESULT
0.95
5
1
2
1
2
5
Form I
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Time: 1144
Method: lll§Q
VOLATILE ORGANIC ANALYSIS DATA SHEET
EPA Sample No.
Lab Name: PEL Laboratories, Inc. Contract: RAM LEATHER I 048697.01 .03 RAM_IVEY
Lab Code : PEL -~---Case No.:
Matrix: WATER -'-"-"'-""-'-----
Concentrated Extrad Volume: 5
Level:(lowlmed) _LO~----__ _
PercentSolids: -~------·_ .. decanted:( __ _
Extraction: PURGETRAP
GPC Cleanup : I YIN ) ___ pH:
Column(1): _D_B_-6_2_4 ___ _ ID: 0.16
CONCENTRATION UNITS: UGIL ____________ ,., ___ ·-
CASNO. ANALYTE
75-71-8 Dld11orodtfluoromethane
74-87-3 Chloromethane
75-01 ◄ Vinyl chloride
74-83-9 Bromomethane
75-00-3 Chloroethane
75-89◄ Tric:hlorofluoromethane
75-35-4 1, 1-Dlchloroethene
75-15-0 Carbon disulfide
75-09-2 Methylene chloride
156-80-5 trans.-1,2-0ichloroethene
75-34-3 1, 1-0lchtoroethane
67-84-1 Acetone
156-59-2 cis-1,2-0lchloroethene
74.97.5 Bromochloromethane
78-93-3 2-Butanone
67-86-3 Chloroform
71-55-6 1, 1,1-Trichloroethane
56-23-5 Carbon tetrachloride
71 ◄3-2 Benzene
107-08-2 1,2-0ichloroethane
79-01-8 Trichloroethane
78-87-5 1,2-Dlchloropropane
75-27-4 Bromodichloromethane
10061-01-5 cls-1,3-0ichloropropene
108-10-1 4-Methyl-2-pentanone
108-88-3 Toluene
10061-02-6 tra na-1, 3-0ichloropropene
SAS No: ______ SDG No.: _2~5~07_68_7 ____ _
Lab Sample ID: 250786703 Lab File 10: 68703.D
Date Extracted:
Date Analyzed: 10/02107 Time: 1208 ---·-----------· __________ .. , ------
Dilution F ador:
Station ID: _________ --------··--Method: ~
RESULT
10
6.2
1
5
2.2
1
5
Form I
Q
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
16
I
I
I
I
I
I
I
I
I
I
I
I
I
D
u
E
I
I
VOLATILE ORGANIC ANALYSIS DATA SHEET
EPA Sample No.
lab Name: PEL Laboratories, Inc. Conlrad: RAM LEATHER I 048697.01 .03 RAM_IVEY ---------------·-··-····-
Lab Code : PEL Case No.:
Matrix: WATER -------·----
Sample wt/vol: 5 Units: ML
Concentrated Extract Volume:
Level:(lowlmed) LOW
PercentSollds: 0 decanted : ( --·--_______ _
Extraction: PURGETRAP
GPC Cleanup·. ( YIN )
Column(1): _DB-ll2_4 __ ID: 0.18
CONCENTRATION UNITS: UGIL ____ -·----·--·-·
CASNO. ANALYTE
79-00-5 1, 1,2-Trichloroethane
127-18-<4 Tetrachloroethene
591-78-8 2-Hexanone
124-48-1 Olbromochloromethane
106-93-4 1,2-0ibromoethane(EOB)
108-91)..7 Chlorobenzene
100-41-4 Ethylbenzene
100-42-5 Styrene
75-25·2 Bromoform
98-82-8 lsopropylbenzene (Cumene)
79.34.5 1, 1,2,2-Tetrad'lloroethane
541-73-1 1,3-Dlchlorobenzene
106-48-7 1,4-Dlchlorobenzene
95.50.1 1.2-Dfchlorobenzene
98-12·8 1,2•Dlbromo-J-chforopropane
120-82-1 1,2,4• Trichlorobenzene
87-61-6 1,2,3-Trichlorobenzene
1330-20·7 Xylene ·(total)
1634-04-<4 MTBE
76-13-1 1, 1,2•Trichlorotrtfluoroethane
108-87-2 Methyl Cydohexane
79-20-9 Methyl Acetate
110-82-7 Cydohexane
-------------·---------
SAS No: ___ SDG No.: 2_50?~7__ ______ .•. __
Lab Sample ID: 2507687_~ Lab File ID: 66703.D
Date Received: 09/27/07
Date Extracted:
Date Analyzed:
Dilution Factor:
Station ID:
RESULT
1
5.8
5
2
2
1
5
Form I
10/02107
Q
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
Time:
Method:
1208
ml)
1
VOLATILE ORGANIC ANALYSIS OATA SHEET
EPA Sample No.
Lab Name: PEL Laboratories, Inc. Contract: RAM LEATHER/ 048697.01 .03 RAM_Glosson_1475
Lab Code : PEL ------Case No.: SAS No: ------SDG No.: 2507667
Matrtx: WATER -'-'-'-"~----Lab Sample 10: 250766704 Lab File ID: .B!l.~:Q ___ -·-
Sample wt/vol: _;; _______ Unfts: ~MccLc_ ___ _ Date Received: 09127/07 -==.cc.-____ _
Concentrated Extrad Volume: 5
Lewl:(low/med) _L()W ___ _
PercentSolids:
Extraction:
()_ __ ··-decanted : (_
PURGETRAP
GPC Cleanup : ( Y/N) pH:
Column(1): "0"8~-6~2~•----10: 0.18
CONCENTRATION UNITS: UG/L =~----
CASNO. ANALYTl!
75-71-6 Oichlorodifluoromethane
74-87-3 Chloromethane
75-01 ◄ Vinyl chloride
74-63-9 Bromomethane
75-00-3 Chloroethane
75-69◄ Trichloroftuoromethane
75-35◄ 1 , 1-Dichloroethene
75-15-0 Carbon disulfide
75-09-2 Methylene chloride
156-60-5 trans-1 ,2-0lchloroethene
75-34-3 1, 1-0ichloroethane
67-64-1 Acetone
156-59-2 ds-1,2-Dichloroethene
74-97-5 Bromochloromethane
78-93-3 2-Butanone
67-66-3 Chlorofonn
71-55-6 1, 1 , 1-Trichloroethane
56-23-5 Carbon tetrachloride
71◄3·2 Benzene
107-08-2 1,2-0ichloroethane
79-01-<I Trichloroethane
78-67-6 1, 2-0ichloropropane
75-27◄ Bromodlchloromethane
10061-01-5 cis-1,3-Dlchloropropene
108-10-1 4-Methyl-2-pentanone
108-88-3 Toluene
10061-02-6 trans-1,3-0ichloropropene
;:Jilllff••·
Date Extracted:
Date Analyzed: 10/02/07 Time: 1232
Dilution F ador:
Station ID:
_(IT1_!!1)__
RESULT
1
1
·10
1
t
5
5
Form I
_____ Method:
Q
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
mo
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
u
I
I
18
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
fl
VOLATILE ORGANIC ANAi. YSIS DATA SHEET
Lab Name:
Lab Code : PEL Case No.:
Matrix: WATER
Sample wt/Vol: .5 _______ Units: ML
Concentrated Extrad Volume: 5
Level:(low/med} !:9~ ___ _
PercentSollds: 0 decanted : (
Extraction: PURGETRAP
GPC Cleanup : ( YIN )
Column(1): DB-624
pH:
ID: 0.18
CONCENTRATION UNITS: UGIL -···-·-···--··-
CASNO. ANALYTE
79-00-5 1, 1,2-Trichloroethane
127-18-4 Tetrachloroethene
591-78-6 2-Hexanone
124-48-1 Dibromochloromethane
1Qe-93-4 1,2-Dlbromoethane(EDB)
108-90-7 Chlorobenzene
100-41-4 Ethylbenzene
100-42-5 Styrene
75-25-2 Bromofonn
98-62-8 tsopropylbenzene (Cumene)
79.34.5 1 , 1,2,2-Tetrachloroethane
541-73-1 1,3-Dlchlorobenzene
106-48-7 1,4-0ichlorobenzene
95-50-1 1 ,2-Dlchlorobenzene
98-12-8 1,2-Dtbromo-3-chloropropane
120-82-1 1,2,4-Trichlorobenzene
87-61-6 1.2,3-Trichtorobenzene
1330-20-7 Xylene (lotal)
1634-04-4 MTBE
78-13-1 1. 1,2-Trichlorotrffluoroethane
108-87-2 Methyl Cydohexane
79-20-9 Methyl Aoetale
110-62-7 Cydohexane
EPA Sample No.
RAM_Glosson_ 1475
SAS No: -·--·· --·····---· SDG No.: -~~O_Ill8.!. _______ ·-· --·-
Lab Samp_, ID: 250768704 . Lab File ID: 68704.D
Dale Reoelwd: 09127107
Date Extracted:
Date Analyzed:
DIiution Fader.
Station JO:
RESULT
1
1
5
1
2
2
5
Form I
10/02107 Time: 1232 --~-------· -·-----·
Q
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
Melhod: llil1
VOLATILE ORGANIC ANALYSIS DATA SHEET
EPA Semple No.
Lab Name: PEL Laboratories, Inc. Contract: RAM LEATHER I IJ.48697.01.03 RAM_Perault
Lab Code : PEL Case No.: SAS No: SDG No.: 2507667 ------
Mat,ix: WATER --------Lab Semple ID: _?_5076§?~--_ Lab File ID: 66705.D
Sample wt/Vol: -~-·--___ Units: ML Date Received: 09127/07
Concentrated Extract Volume: 5
Level:(lowlmed) LOW
Perc.entSolids: o ___ decanted : ( ____ _
Extraction: PURGETRAP '--'-~-----
GP C Cleanup : ( YIN ) ___ pH:
Column(1): DB-624 ID: 0.18
CONCENTRATION UNITS: UGIL
CASNO. ANALYTE
75-71-6 Dichlorodlfluoromethane
74-67•3 Chloromethane
75-01 ◄ Vinyl chloride
74-63-9 Bromomethane
75-00-3 Ch1oroethane
75-69◄ Trichlorofluoromethane
75-35◄ 1, 1-Dlch1oroethene
75-15-0 Carbon dlsutflda
75-09-2 Methylene chloride
156-60-5 trans-1,2-Dichloroethene
75-34·3 1, 1-0ichloroethane
67-64-1 Acetone
156-59-2 cis-1,2-Dlchloroethene
7-4-97-5 Bromodlloromethane
76-93-3 2-Butanone
67-68-3 Chloroform
71-55-6 1, 1, 1-Trich/oroethane
56-23-5 Carbon tetrachloride
71 ◄3-2 Benzene
107-06-2 1,2-Dichloroethane
79-01-6 Trichloroethane
78-67-5 1,2-Dlchloropropane
75-27◄ Bromodlchloromethane
10061-01-5 cls-1,3-Dichloropropene
108-10-1 4-Methy$-2-pentanone
108-68-3 Toluene
10061-02-6 trans-1,3-0ichloropropene
----------·
Date Extracted:
Dale Ana~zed: 10102/07 Time: 1256
Dilution Factor:
Station 10:
RESULT
10
1
5
1
1
5
Form I
?/i07RR7
------.... •-•----...•
_____ Melhod: 6W
Q
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
20
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
D
VOLATILE ORGANIC ANALYSIS DATA SHEET
Lab Name: .PEL .Laboratories, Inc. _____ .-· Contract: -~M!.~~!..t-i.~~ I 048697.01 .03
Lab Code:
Matrix:
PEL
WATER
Sample wt/Vol: 5
Concentrated Extract Volume:
Level:(low/med) LOW
Case No.:
Units: ML
PercentSoUds: 0 decanted:
Extraction:
GPC Cleanup : (YIN) pH:
SAS No:
Lab Sample ID: 250766705
Date Received: 09127/07
Dale Extracted:
Date Analyzed: 10/02/07
Dilution Factor:
Station ID:
Column(1): DB-624 __ .... ID: 0.16 (rn_n,) __
CONCENTRATION UNITS: UG~IL __
CASNO. ANALYTl:
79-00-5 l, 1,2-Trichloroethane
127-16-4 Tetrachloroethene
591-76-6 2-Hexanone
124-46-1 Olbromochloromethane
106-93-4 1,2-Dlbromoethane(EOB)
108-90-7 Chlorobenzene
100-41-4 Ethylbenzene
100-42-5 Styrene
75-25-2 Bromoform
98-82-8 tsopropylbenzene (Cumene)
79 .. 34.5 1,1 ,2,2-Tetrachtoroethane
541-73-1 1.3-Dlchlorobenzene
106-46-7 1,4-Dlchlorobenzene
95-50-1 1,2-Dlchlorobenzene
96-12-8 1,2-Dlbromo-3-chloropropane
120-82-1 1,2,4-Trichlorobenzene
87-61-6 1,2,3-Trichlorobenzene
1330-20-7 Xylene (total)
1634-04-4 MTBE
76-13-1 1, 1,2-Trichlorotrifluoroethane
108-87-2 Methyl Cydohexane
79-20-9 Methyl Acetate
110-82-7 Cydohexane
RESULT
5
1
2
1
1
2
1
5
Fonn I
Q
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
EPA Sample No.
RAM_Perault
SDG No.: 2507667
Lab File ID: 66705.D
Time: 1256 .... ·------··· -
Melhod: ill2
f
VOLATILEORGANICANALYSl8 DATA SHEET
EPA Sample No.
Lab Name: PEL Laboratories, Inc. Contrad: RAM LEATHER/ 048697.01 .03 RAM_Jamerson
Lab Code : P0EccL ___ _ Case No.: SAS No: SDG No.: 2507567
Matrix: WATER Lab Sample 10: 250756706 ---Lab File ID: 56706.D
Sample wt/Vol: .,,5 __ _ Units: M:,L::_ __ Oats Received: 09/27/07 ·-··---------~·-·-------~-·-·-----·
Concentrated Extrad Volume: 5
Level:(klw/med) LO_l',I _____ __
PercentSollds: O decanted : {
Extraction: PURGETRAP
GPC Cleanup : ( YIN ) ___ pH:
Column(1): DB-624:__ __ ID: 0.18
UG/L CONCENTRATION UNITS:
CASNO. ANALYTl!
75-71-8 Olchlorodlfluoromethane
74-67-3 Chloromethane
75-01-4 Vlnyt chtoride
74-63-9 Bromomethane
75-00-3 Chloroethane
75-69-4 Trlchlorofluoromethane
75-35-4 1, 1-0lchloroethene
75-15-0 Cartlon dlsulflde
75-09-2 Methylene chloride
156-60-5 trans-1,2-Dlchloroethene
75-34-3 1, 1-Dichloroethane
67-64-1 Ar.atone
156-59-2 cis-1,2-Dlchloroethene
74-97-5 Bromochloromethane
78-93-3 2-Butanone
87-68-3 Chlorofonn
71-55-6 1, 1, 1-Trichloroethane
58-23-5 Carbon tetrachloride
71-43-2 Benzene
107-08-2 1,2-Dichloroethane
79-01-6 Trichloroethane
78-87-5 1,2-0ichloropropane
75-27-4 Bromodichloromethane
10061-01-5 cis-1,3-Dichloropropene
108-10-1 4-Methyl-2-pentanone
108-88-3 Toluene
10081-02-8 trans-1 ,3-0ici'lloropropene
Date Extracted:
Dale Analyzed: 10/02/07
Dilution Factor:
Station ID:
_(rn_m) __
RESULT
1
10
1
5
1
5
Fomnl
Q
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
Time: 1320
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
22
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
1
VOLATILE ORGANIC ANALYSIS DATA SHEET
EPA Sample No.
Lab Name: PEL. laborat~~e~, Inc ... Contract: RAM LEATHER /048697.01.03 RAM_Jamerson
Lab Code:
Matrix:
PEL
WATER
Case No.:
Sample wt/Vol: 5 Units: Ml
Concentrated Extract Volume: 5 -··--· --..
Level:(lowlmed) LOW
PercentSollds: 0 decanted:( __________ _
Extraction: PURGET_~f'.__ _________ _
GPC Cleanup : ( YIN ) ··---··-pH: ---·-···-· _
Column(1): DB-624 -·--·---· ID: 0.16
CONCENTRATION UNITS: UGIL ___________ _
CASNO. ANALYlc
79-00-5 1.1,2-Trichloroethane
127-18-4 T etrachloroethene
591-78-6 2-Hexanone
124-48-1 Dlbromochloromethane
106-93-4 1,2-Dlbromoethane(EDB)
108-90-7 Chlorobenzene
100-41-4 Ethylbenzene
100-42-5 Styrene
75-25-2 Bromoform
98-82-8 lsopropylbenzene (Cumene)
79-34-5 1, 1,2,2-Tetrachloroethane
541-73-1 1,3-0fchtorobenzene
106-46-7 1,4-0lchlorobenzene
95-50-1 1,2-0lchlorobenzene
96-12-8 1,2-Dibromo-3-chloropropane
120-82-1 1,2,4-Trichlorobenzene
87-61-6 1,2,3-Trichlorobenzene
1330-20-7 Xylene (total)
1634-04-4 MTBE
76-13-1 1, 1,2-Trichlorotrifluoroethane
108-87-2 Methyl Cydohexane
79-20-9 Methyl Acetate
110-82-7 Cydohexane
·-·-·-·· -------... ··-·-
SAS No: SDG No.: 2507667 ---
lab Sample ID: 250766706 Lab File ID: 66706.0 . -------·-···-
Date Received: 09/27107
Date Extracted:
Date Analyzed: -~9fJ2107 ___________ Time:
Oflutlon Factor:
Station ID:
RESULT
1
5
2
1
1
2
5
1
Fonm I
Q
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
Melhod:
VOLATILE ORGANIC ANALYSIS DATA SHEET
EPA Sample No.
Lab Name: PEL Laboratories, "-lnccc·c__ Contract: RAM LEATHER/ 048697.01.03 -----·-·--·······
RAM_TUCKER_02
Lab Code : :..P:::E=.L __ _ Case No.: SAS No: SDG No.: 2507867 --------------·-
Matrix: WATER Lab Sample ID: .2-~7.~7.07 ______ _ Lab Fila ID: 86707.D ----·--··•--··
Sample wt/Vol: 5 Units: ML Date Received: 09/27/07
Concentrated Extract Volume: 5 Date Extracted:
Level:(low/med) _L_O_W __ Date Analyzed: 10/02107 --·--·-----Time:1 ~ 34-4=--
PercentSolida: O ___ decanted : { ___________ _ DIiution Factor:
Extraction: PURGETRAP
GPC Cleanup : ( YIN ) ___ pH:
Column(1): DB~-6=24 __ _ ID: 0.18
CONCENTRA T/ON UNITS: UG/L
CASNO. ANALYTE
75-71-8 Dichlorodifluoromethane
74-87-3 Chloromethane
75-01-4 Vinyl chloride
74-83-9 Bromomethane
75-00-3 Chloroethane
75-69-4 Trlchlorofluoromethane
75-35-4 1, 1-Dlchloroethene
75-15-0 Carbon disulfide
75-09-2 Methylene chloride
156-60-5 trans-1,2-Dlchloroethene
75-34-3 1, 1-Dichloroethane
67-64-1 Acetone
156-59-2 ds-1,2-0ichloroethene
74-97-5 Bromochloromethane
78-93·3 2-Butanone
67-66-3 Chloroform
71-55-6 1, 1, 1-Trichloroethane
56-23-5 Carbon tetrachloride
71-43-2 Benzene
107-06-2 1,2-DichJoroethal')e
79-01-6 Trichloroethene
76-67-5 1,2-Dichloropropane
75-27-4 Bromodlchloromethane
10061-01-5 cis-1,3-Dic.hloropropene
108-10-1 4-Methyl-2-pentanone
106-88-3 Toluene
10061-02-6 trans-1,3-Dichloropropene
Station ID:
RESULT
10
. 1
1
5
1
5
Form I
2507667
___ Method:
Q
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
24
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
VOLATILEORGANICANALYSIS DATA SHEET
Lab Name: PEL Laboratories, _ln_c_. __ _
Lab Code: PEL Case No.:
Matrix: WATER .. ··-·--· -·------------·-
Sample wVvol: 5 Units: ML
Concentrated Extract Volume: 5 ----..... ---·--···-
Level:(low/med) _Low .•••...
PercentSolids: _9 ____ ·--·-_decanted: (
Extraction: PURGETRAP
GPC Cleanup : ( YIN ) -·····-··· pH:
Column(1): _DB-624 ---·----ID: 0.18
CONCENTRATION UNITS: U=.G,c/L.c._ __
CASNO. ANALYTE
79-00-5 1, 1,2-Trlchloroethane
127-18-4 T etrachloroethene
591-78-6 2-Hexanone
124-48--1 Dlbromochloromethane
106-93-4 1,2-0lbromoethane(EOB)
108-90.7 Chlorobenzene
100-41-4 Ethylbenzene
100-42•5 Styrene
75-25-2 Bromofonn
98·82-8 lsopropylbenzene (Cumene)
79.34.5 1,1,2.2-Tetrachloroethane
541.73.1 1,3-Dichlorobenzene
106-46-7 1,4-0lchlorobenzene
95·50-1 1,2-Dlchlorobenzene
96-12-8 1,2-0lbromo-3-chloropropane
120-82·1 1,2,4-Trichlorobenzene
87-61-6 1,2,3-Trichlorobenzene
1330-20-7 Xylena (lolal)
1634-04-4 MTBE
76·13-1 1, 1,2-Trichlorotrttluoroethane
108-87•2 Methyl Cydohexane
79·20-9 Methyl Acetate
110-82•7 Cydohexane
SAS No:
Lab Sample ID: 250766707
Date Received: 09127/07
Date Extracted:
Dale Analyzed: 10/02/07
Dilution Fader:
Station ID:
RESULT
1
5
1
2
1
2
1
5
Form I
EPA Sample No.
SDG No.: 25c:Oc.7=.66:c7 ___ _
Q
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
Lab File ID: 66707.D
Time: 1344
Melhod:
VOLATILE ORGANIC ANALYSIS DATA SHEET
EPA Sample No.
Lab Name: PEL Laboratories, Inc. Contrad: RAM LEATHER/ 048697.01.03 RAM_TUCKER_01
ubCooe: PE~L,__ __ _ Case No.:
Matrix: ..:.W:cA.::T::E:::Rc_ __ _
Sample w1/Vol: 5 Units: M,::L:_ ___ _
Concentrated Extract Volume: -'5'---------
Level:(low/med) LOW
PercentSolids: O decanted : (
Extraction: PURGETRAP
GPC Cleanup : ( Y/N ) ·-·--·· •. -pH:
Column(1): D:.:Bc...-6cc2c..c4 ___ _ ID: 0.18
CONCENTRA T/ON UNITS: ..:UccGccllc___
CASNO. ANALYTE
75-71-8 Didltorodlfluoromethane
74-87-3 Chloromethane
75-01 ◄ Vinyl chloride
74-83-9 Brom om ethane
75-00-3 Chloroethane
75-69--4 Trichtorofluor'Omethane
75-35--4 1, 1-Dichloroethene
75-15-0 Carton disulfide
75-09-2 Methylene chloride
158-60-5 trans-1,2-Dichloroethene
75-34-3 1, 1-0ichloroethane
67-64-1 Acetone
156-59-2 cis--1,2-0lchloroethene
74-97-5 Bromochloromethana
78-93-3 2-Butanone
67-66-3 Chloroform
71-55-6 1, 1, 1-Trlchloroethane
56-23-5 Carbon tetrachloride
71--43-2 Benzene
107-o&-2 1,2-0ichloroethane
79-01-6 Trichloroethane
78-87-5 1,2-0ichloropropane
75-27--4 Bromodlchloromethane
10061-01-5 cis-1,3-0ichloropropene
108-10-1 4-Methyt-2-pentanone
108-88-3 Toluene
10061-02-6 trans-1,3-Didiloropropene
SAS No: -----SDG No.: 2507667
Lab Sample ID: 250788708 Lab FIie ID: ~708.D ________ _
Date Received: 09/27/07
Date Extracted:
OateAnalyzed: ~g~~Q~----·-··-··---Time: 1408
Dilution Factor:
Station 10:
RESULT
10
5
1
5
Form I
")Cn"7a:a:"7
Q
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
Melhoo: 62el!
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
VOLATILE ORGANIC ANALYSIS DATA SHEET
lab Name: _':'.~~-Laboratories. Inc.
Lab Code: PEL Case No:. •· ··----··---·-·-
Matrix: WATER
Samplewt/Vol: ~----·---Units: ML
Concentrated Extract Volume: 5
Level:(tow/med) LOW .. -----·
PercentSollds: O decanted :
Extraction: PURGETRAP
GPC Cleanup : ( YIN ) --·----··-pH:
Column(1): C>B1~•-·-•··--··---· ID: 0.18
CONCENTRATION UNITS: UG/L __________ _
CASNO. ANALYTE
79-00-5 1, 1,2-Trlchloroethane
127-18-<4 Tetrachloroethene
591-78-8 2-Hexanone
124-48-1 Dlbromochloromethane
106-93-4 1.2-0lbromoethane(EDB)
106-91).7 Chlorobenzene
100-41-4 Ethylbenzene
100-42-5 Styrene
75-25-2 Bromoform
96-62-6 lsopropylbenzene (Cumene)
79-34·5 1, 1,2,2-Tetrachtoroethane
541-73-1 1,3-0ichlorobenzene
106-48-7 1,4-Dlchlorobenzene
95-50-1 1,2-Dlchlorobenzene
96-12-6 1,2-Dlbromo-3-chloropropane
120-62-1 1,2,4-Trichlorobenzene
8H!HI 1,2,3-Trichlorobenzene
1330-20•7 Xylene (total)
1634-04-4 MTBE
76-13-1 1, 1,2-Trichtorotriffuoroethane
108-67·2 Methyl Cydohexane
79-20-9 Methyl Acetate .
110-82-7 Cydohexane
EPA Sample No.
RAM_TUCKER_01
SAS No·. SDG No.: 2507667 ---··---------
Lab Sample ID: 250766708 Lab File ID: 66708.D
Date Rec.eived: 09/27107 -··-----
Date Extracted:
Date Analyzed:
DIiution Factor:
Station ID:
RESULT
5
2
2
1
5
Form I
-,cn-,oo-,
10/02107
Q
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
Time: 1408
Method: ~
VOLATILEOROANICAHALYSIS DATA SHEET
EPA Sample No.
Lab Name: .~EL Laboratories, lnc. Contrad: RAM LEATHER/ 046697.01.03 RAM_MWIJ02D
Lab Code : PEL Case No.: ---
Matrix: WATER -----
Sample wt/Vol: ~--____ _ Units: ML ---
Concentrated Extract Volume: 5 ·····----·-· ------
Level:(k>w/med) -~<:J_V'I _____ _
PercentSolids: 0 decanted : (
Extraction: PURGETRAP
GPC Cleanup: ( YIN ) ___ pH:
Column(1): DB-624 __ _ ID: 0.16
CONCENTRA T/ON UNITS: UG/L --· --·-----·-·--·----
CASNO. ANALYTE
75-71-8 Dichlorodifluoromethane
74-87-3 Chtoromethane
75-01--4 Vinyl chloride
74-63-9 Bromomethane
75-00-3 Chloroethane
75-69-4 Trichlorofluoromethane
75-35-4 1, 1-Dlchloroethene
75-15-0 Carbon disulfide
75-09-2 Methylene chloride
156-60-5 trans-1,2-Dichloroethene
75-34-3 1, 1-Dichloroethane
67-64-1 Acetone
156-59-2 cis-1 ,2-Dlchloroethene
74-97-5 Bromochloromethane
76-93-3 2-Butanone
67-66-3 Chloroform
71-55-6 1, 1, 1-Trlchloroethane
56-23-5 Carbon tetrachloride
71-43-2 Benzene
107-06-2 1 ,2-0lchloroethane
79-01-6 Trichloroethane
76-67-5 1,2-Dichloropropana
75-27◄ Bromodichloromethane
10061-01-5 cis-1,3-Dlchloropropene
108-10-1 4-Methyl-2-pentanone
106-86-3 Toluene
10061-02-6 trans-1 ,3-Dlchloropropene
SAS No: SDG No.: 2507667
Lab Sample ID: -~~07~ro_~-------Lab Fia, ID: 6~7p_9.[) __
Date Received: 09/27/07
Date Extracted:
Date Ana~zed: _10_/0~21~0~7 ___ _
Dilution Factor:
Station ID: ---------
RESULT
10
0.52
1
5
1
5
Form I
Q
u
u
u
u
u
u
u
u
u
u
u
u
J
u
u
u
u
u
u
u
u
u
u
u
u
u
u
Time: 1.:.43::2:_ __ _
Method:
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
?A
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
VOLATILE ORGANIC ANALYSIS DATA SHEET
EPA Sample No.
Lab Name: PEL Laboratories, lnc. Contract: RAM LEATHER/ 048697.01.03 RAM_MW902D
Lab Code : PEL Case No.: -----------·-·
Matrix: WATER
Sample wt/vol: ~----_____ Units: ML
Concentrated Extract Volume:
Level:(low/med) LOW
PercentSollds: 0 decanted : ( _ _ _ _________ _
Extraction: PURGETRAP ~=---------
···-····--·-· pH: GPC Cleanup: ( YIN )
Column(1): _[l]l:l32~4'----ID: 0.18
CONCENTRATION UNITS: UG/L
CASNO. ANALYTE
79-00-5 1, 1,2-Trichloroethane
127-18-4 Tetrachloroethene
591-78-6 2-Hexanone
124-48-1 Oibromochloromethane
106-93-4 1,2-0lbromoethane(EDB)
108-90-7 Chlorobenzene
100-41-4 Ethylbenzene
100-42-5 S1yrene
75-25-2 Bromofonn
98-82-8 lsopropylbenzene (Cumene)
79-34-5 1,1,2,2-Tetrad"lloroethane
541-73--1 1,3-0lchtorobenzene
106-48-7 1,4-Dtchlorobenzene
95-50-1 1,2-0lchlorobenzena
96-12-8 1 ,2-Dlbromo-J..chloropropane
120-82-1 1,2,4-Trlchtorobenzene
87-61-6 1,2,3-Trlchlorobenzene
1330-20-7 Xylene (total)
1634-04-4 MTBE
76-13-1 1, 1 ,2-Trtchlorotrifluoroethane
108-87-2 Methyl Cydohexane
79-20-9 Methyl Acetate
110-82-7 Cydohexane
,n,om, .. ,
SAS No: ______ SOGNo.: 15.0?_1!_67 __________ _
Lab Sample ID: 250766709 Lab FIie ID: 66709.D
Date Received: 09/27/07
Date Extracted:
Date Analyzed: _1_~_19.?-!E.? ---·-···-·-·-.. Time: 1_~~~----·-··----·-· ___
Dllutlon Factor:
Station ID:
RESULT
1
0.98
5
2
1
2
1
5
Fomn I
Q
u
J
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
Method:
VOLATILE ORGANIC ANAL YSl8 DATA SHEET
EPA Sample No.
Lab Name: _PEL Laboratories, Inc. Contract: RAM LEATHER/ 048697.01 .03 RAM_MW03D
Lab Code : .:_P.=E:cl ___ _ Case No.: SAS No: SDG No.: 2507667
Matrix: WATER Lab Sample ID: 2507_66_71_0 __ _ Lab File ID: 66710.D --·--·-·· -•-•·• ------
Sample wt/vol: _5 ___ Units: ~-'=----·----Date Received: _,:09cci2:c7:..:/:c07:__ __ ___ ___ ___ ..• ---··. _____ _
Concentrated Extrad Volume: 5 Date Extracted:
Level:(low/med) L_O_W __ Date Analyzed: ~Q~?:!Q~---------Time: 1456
PercentSoHds: __Q_ _________ decanted : ( ____ _ Dilution Fedor:
Extraction: PURGETRAP
GPC Cleanup : ( Y/N ) pH:
Column(1): Dc.cBc.-8cc2cc4 ___ _ ID: 0.18
CONCENTRA T/ON UNITS: UG/L -------···----
CASNO. ANALYTE
75-71-8 Dlc:hlorodlfluoromethane
74-87-3 Chloromethane
75-01◄ Vinyl chloride
74-83-9 Bromomethane
75-00-3 Chloroethane
75-89-4 T richlorofluoromethane
75-35-4 1, 1-Dlchloroethene
75-15-0 Carbon disulfide
75-09-2 Methylene chloride
156-80-5 trans-1,2-Dlchloroethene
75-34-3 1 , 1-Dlchloroethane
67-84-1 Acetone
156-59-2 cls-1,2-Dlchloroethene
74-97-5 Bromoc:hloromethane
78-93-3 2-Butanone
67-86-3 Chloroform
71-55-8 1, 1, 1-Trichloroethane
56-23-5 Carbon tetrachloride
71-43-2 Benzene
107-08-2 1,2-0lchloroethane
79-01-8 Trichloroethane
78-87-5 1,2-Dichloropropane
75-27-4 Bromodichloromethane
10061-01-5 cis-1,3-Dichloropropane
106-10-1 4-Meth~2-pentanone
108-88-3 Toluene
10061-02-6 trans-1,3-Didlloropropene
Station ID:
_I"'_"')_
RESULT
10
1
5
1
5
Fonn I
Q
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
Method: ~
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
VOLATILE ORGANIC ANALYSIS DATA SHEET
EPA Sample No.
Lab Name: PEL Laboratories, Inc. Contract: RAM LEATHER/ 048697.01 .03 RAM_MW03D
-·-·---··· ·-•----···----
Lab Code: Case No.: SAS No:
Matrix:
PEL
WATER Lab Sample ID: 250766710 ...... _ Lab FIie ID: _ll8_71!l:_D ____ ...
Sample wt/Vol: E .. ~·---.. _ Units: Ml:_ ______________ _
Concentrated Extract Volume: 5
Lewl:(low/med) LO;\/ --·-·-·
PercentSollda: P ... __ ... decanted: ( ..... -....
Extraction: PURGETRAP ·------------------· ----·--·----
GPC Cleanup : (YIN) .. pH:
Column(1): DB-62< ...... .. ID: 0.18
CONCENTRATION UNITS: UG/L ···------------
CASNO. ANALYTE
79-00-5 1, 1,2-Trichloroethane
127-18-4 Tetrachloroethene
591-78-6 2-Hexanone
124-48-1 Dibromochloromethane
106-93◄ 1.2-0lbromoethane(EOB)
108-90-7 Chlorobenzene
100-41-4 Ethyl benzene
100-42-5 Styrene
75-25-2 Bromoform
98-82-6 lsopropylbenzene (Cumene)
79-34-5 1, 1,2,2-Tetrachloroethane
5<1-73-1 1,3-0ichlorobenzene
106-46-7 1,4-0lchlorobenzene
95-50-1 1,2-0lch1orobenzene
96-12-8 1,2-0ibromo-3-chloropropane
120-62-1 1,2,4-Trichlorobenzene
87-61-6 1,2,3-Trichlorobenzene
1330-20-7 Xylene (total)
1634-Q<-4 MTBE
76-13-1 1, 1,2-Trichlorotrifluoroethane
108-67-2 Methyl Cydohexane
79-20-9 Methyl Acetate
110-82-7 Cydoi.ixane
Date Received:
Date Extracted:
Date Anatyzed:
Dilution Factor:
Station 10:
RESULT
1
5
1
2
1
2
1
1
5
Fonm I
10/02107
Q
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
Time: 1456
Method:
VOLATILEORGAHICANALYSIS DATA SHEET
EPA Sample No.
Lab Name: PEL Laboratories, Inc. Contract: RAM LEATHER/ 048897.01 .03 RAM_Beaver
Lab Code : PEL Case No.: -----
Matrix: WATER -"'=~----
Sample wt/vot ~--··---·--Units: ML
Concentrated Extrad Volume: 5 _____ _
Level:(low/med) _L_O_W ____ _
PercentSollds: J ___ ._dec.anted : ( ____ _
Extraction: PURGETRAP
GPC Cleanup: (YIN) ___ pH:
Column(1): ~D=Bc..-6=2cc4 ___ _ ID: 0.18
CONCENTRATION UNITS: UG/L ·--·· ------···-•·-••-
CASNO, ANALYTE
75-71-6 Dlchlorodlfluoromethane
74-87-3 Chloromethane
75-01◄ Vinyl chloride
74-63-9 Bromomethane
75-00-3 Chloroethane
75-69-4 Trichlorofluoromethane
75-35-4 . 1, 1-Dlchloroethene
75-15-0 Cartlon dlsulflde
75-09-2 Methylene chloride
156-60-5 trans-1,2-Dichloroethene
75-34-3 1, 1-0lchloroethane
67-64-1 Acetone
156-SS-2 cls-1,2-0ichloroethene
74-97-5 Bromochloromethane
76-93-3 2-Butanone
67-66-3 Chloroform
71-55-6 1, 1, 1-Trichtoroethane
56-23-5 Carbon tetrachloride
71-43-2 Benzene
107-08-2 1,2-0ichloroethane
79-01-6 Trichloroethane
78-87-5 1,2-0ichloropropane
75-27-4 Bromodlchloromethane
10061-01-5 cis-1,3-0ichloropropene
108-10-1 4-Methyl-2-pentanone
108-68-3 Toluene
10061-02-6 trans-1 ,3-0ldiloropropene
SAS No: ______ SDG No.: 250786_7 ____ _
Lab Sample ID: 250786711 Lab File ID: 86711.D
Date Received: 09/27107 ·---·-·-·-·-·-----·•-·-·----_____ ,.,
Date Extracted:
Date Analyzed: _1.Q/01f0.I_ ___ Time: ~3.!_ _____ ---·-
Dilution Fader:
Station ID:
RESULT
1
0.37
10
17.9
5
1
1.6
5
Form I
2507667
Q
u
u
u
u
u
u
u
u
u
u
J
u
u
u
u
u
u
u
u
u
u
u
u
u
u
Method: a2W)
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
32
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
VOLATILE ORGANIC ANALYSIS CATA SHEET
EPA Sample No.
Lab Name: PEL Laboratories. Inc. Conlrad: RAM LEATHER/ 04889~Q!.:_~ RAM_Beaver
Lab Code '. PEL Case No.: ---··-··------SAS No: SDG No.: 2~50'--7~86'-'7 __ _
Matrix: WATER -· ··-···--····· ·----·-· Lab Sample ID: 250766711 -···· Lab FIie ID: 66711.D_, _____ ..
Sample wt/vol: 5 Units: ML Date Rec.etved: 09/27/07 -··•-----· ---.
Concentrated Extract Volume: 5 Date Extracted:
Level:(low/med) LOW Date Analyzed: Time: 0931
PercentSoUds: O decanted : { Dilution Factor:
Extraction: PURGETRAP Station ID: _______ ·---------------· Melhod: §2§.Q
GPC Cleanup : (YIN) ___ pH:
Column(1): _ _1?!3-6_24 __ _ ID: 0,18
CONCENTRATION UNITS: UG/L
~ -------·-··--------·-
CASNO. ANALYTE
79-00-5 1, 1,2-Trichloroethane
127-18-4 Tetrachloroethene
591-78-6 2-Hexanone
124-48-1 Dlbromochloromethane
106-93-4 1,2-Dtbromoethane{EDB)
108-90-7 Chtorobenzene
100-41-4 Ethyl benzene
100-42-5 Styrene
75-25-2 Bromoform
98-62-8 1sopropylbenzene (Cumene)
79-34-5 1, 1.2.2-Tetrachloroethane
541-73-1 1,3-Dlchlorobenzene
106-46-7 1,4-0tchlorobenzene
95-50-1 1,2-Dlchlorobenzene
96-12-8 1,2-Dlbromo-3-chloropropane
120-62-1 1,2,4-Trichlorobenzene
87-61-8 1,2,3-Trichlorobenzene
1330-20-7 Xylene (total) •
1634-04-4 MTBE
76-13-1 1, 1.2-Trlchlorotrifluoroethane
1 08-87-2 Methyl Cydohexane
79-20-9 Methyl Acetate
110-82-7 Cydohexane
RESULT
41.3
5
0.61
1
2
1
1
2
1
5
Form I
'1Cn"7QQ"7
Q
u
u
u
u
u
u
u
u
u
u
u
J
u
u
u
u
u
u
u
u
u
u
VOLATILE ORGANIC ANALYSIS DATA SHEET
EPA Sample No.
Lab Name: PEL Laboratories, Inc. Contrad: RAM LEATHER/ Q.48697.01 .03 RAM_Beave111
Lab Code : P,:Ec.L __ _ Case No.: SAS No: SDG No.: 2507667
Matrix: WATER ===-----Lab Sample ID: -~0766cc7..c1:..2 ___ Lab FIie ID: ~I_1.?,Cl_ ______ _
Sample wt/vol: -'5'---Units:M cc=L ____ _ Date Received: 09,0'2:c7c./0::c7 ___________ _
Concentrated Extrad Volume: -'5'--------Date Extracted:
Level:(low/med) -~()~----Date Analyzed: -'1.::0/0=31:..07:.._ __ _ Time: 0956 ---------------·-
PercentSotids: O decanted:( ____________ _ Dilution Fador:
Extraction: PURGETRAP Station ID: Method:
pH: GPC Cleanup : ( YIN )
Column(1 ): 08-624 ID: 0.18 _(rJ!.111)_
CONCENTRATION UNITS: UG/L -------
CASNO. ANALYTE
75-71-8 Dlct\lorodiftuoromethane
74-87-3 Chloromethane
75-01-4 Vinyl chloride
74-83-9 Bromomethane
75-00-3 Chloroethane
75-69-4 Trichtorofluoromethane
75-35-4 1, 1-0lchloroethene
75-15-0 Carbon disulfide
75-09-2 Methylene chloride
158-60-5 trans-1,2-0ichloroethene
75-34-3 1, 1-Dichloroethane
67-64-1 Acetone
158-59-2 cls-1,2-Dichloroethene
74-97-5 Bromochloromethane
78-93-3 2-Butanone
87-68-3 Chloroform
71-55-6 1, 1, 1-Trichtoroethane
56-23-5 Carbon tetrachloride
71--13-2 Benzene
107-06-2 1,2-0lchloroethane
79-01-6 Trichtoroethene
78-87-5 1,2-0lchloropropane
75-27-4 Bromodichloromethane
10081-01-5 cia-1.3-Dichloropropene
108-10-1 4-Methyl-2-pentanone
108-88-3 Toluene
10081-02-6 trana-1,3-Dichloropropene
031001, .. ,
RESULT
1
10
17.5
1
5
1.8
1
5
Form I
?~07AA7
Q
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
34
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
1
VOLATILE ORGANIC ANAl YSIS DATA SHEET
EPA Sample No.
Lab Name: PEL Laboratories. Inc._·-·· Conlrad: RAM LEATHER/ 048697.01.03_ RAM_Beaver9
Lab Code: PEL Case No.: SAS No: SDG No.: ?5_Cl7_6~-·-·-_ ···-
Matrix: WATER . ·-·---··---·--··-Lab Semple 10: 2~0.7:88_71? ...
Sample wt/Vol: ~---·-··--Units: .~l:__ .. __ Dale Received: 09/27/07 ___ __
Concentrated Extract Volume: 5 Date Extracted: . -----·--•---·------
Level:(low/med) _L_(J.1\/ __ . __ Dale Analyzed: 10/03107
PercentSollds: O decanted : ( Dilution Factor:
Extraction: PURGETRAP --------~ Station ID:
GPC Cleanup : ( Y/N ) pH:
Column(1): 0_8~4.__ ID: 0.18 ("!'!') ..
CONCENTRATION UNITS: UG/L -·--· ··-------···-·
CASNO. ANALYTE
79-00-5 1, 1,2-Trichloroethane
127-16-4 Tetrachloroethene
591-78-6 2-Hexanone
124-48-1 Olbromoc:hloromethane
106-93-4 1,2-Dlbromoethane(EDB)
108-90-7 Chlorobenzene
100-41-4 Ethylbenzene
100-42-5 Styrene
75-25-2 Bromofonn
98-82-6 lsopropylbenzene {Cumene)
79-34-5 1,1,2,2-Tetrachloroethane
541-73-1 1,3-Dlchlorobenzene
106-46-7 1,4-0lchlorobenzene
95-50-1 1,2-0lchlorobenzene
96-12-8 1,2-0lbromo-3-chloropropane
120-82-1 1,2,4-Trichlorobenzene
87-61-6 1,2,3-Trichlorobenzene
1330-20-7 Xylene (total)
1634-04-4 MTBE
78-13-1 1, 1,2-Trichlorotrtfluoroethane
108-87-2 Methyl Cydohexane
79-20-9 Methyl Acetate
110-82-7 Cydohexene
0)>'"'1'1411
RESULT
39.4
5
1
0.84
1
2
1
2
1
5
Form I
Q
u
u
u
u
u
u
u
u
u
u
u
J
u
u
u
u
u
u
u
u
u
u
Lab File ID: 66712.D -·----------..
Time: 0958
Method:
1
VOLATILE ORGANIC ANALYSIS DATA SHEET
EPA Sample No.
Lab Name: PEL Laboratories, Inc.··----···-Contract: RAM LEATHER/ ~8~_9_?.2._!,.03 RAM_ TUCKER03
Lab Code : PEL Case No.:
Matrix: WATER --------
Sample wt/Vol: 5 Units: ML
Concentrated Extract Volume: 5
Level:(lowhned) LOW
PercentSolids: 0 decanted : (
Extraction: PURGETRAP
GPC Cleanup : ( YIN )
Column(1): DB-824 ~=----ID: 0.16
CONCENTRA T!ON UNITS: UG/L -----·---------
CASNO. ANALYTfi
75-71-8 Oichlorodifluoromethane
74-67-3 Chloromethane
75-01 ◄ Vinyl chloride
74-63-9 Bromomethane
75-00-3 Chloroethane
75-89◄ Trichlorofluoromethane
75-35◄ 1, 1-Dlch\oroethene
75-15-0 Carbon disulfide
75-09-2 Methylene chloride
156-80-5 trans-1,2-0ichtoroethene
75-34-3 1 , 1-Dichloroethane
67-84-1 Acetone
156-59-2 cis-1, 2-Dichloroethene
74-97-5 Bromoch\oromethane
78-93-3 2-Butanone
67-68-3 Chloroform
71-55-6 1, 1,1-Trichloroethane
56-23-5 Carbon tetrachloride
71-43-2 Benzene
107-08-2 1,2-0ichloroethane
79-01-6 Trichloroethane
78-87-5 1,2-Dichloropropane
75-27◄ Bromodlchloromethane
10081-01-5 cis-1,3-Dichloropropene
108-10-1 4-Meth)i-2-pentanone
108-88-3 Toluene
10061-02-6 trans-1,3-0ichloropropene
SAS No: ----SDG No.: 2507667
Lab Sample ID: 250766713 Lab File ID: ~I!~-_D __ .. _ ..
Date Reoeh,ed: 09/27107 -----------·-·---·
Date Extracted:
DateAnalyzed: !.Q./03/~~---·-·-·-·-· Time: .!~JE __ , __________ _
Dilution Factor:
Station ID: _____________ Method: mo
RESULT
10
1
1
5
5
Form I
Q
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
I
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36
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VOLATILE ORGANIC ANALYSIS DATA SHEET
EPA Sample No.
lab Name: PEL Laboralorles, Inc, ·----·-Contract: RAM LEATHER-~ Q4_t!~ll_7.0!J_! RAM_TUCKER03
Lab Code : PEL ----Case No.: SAS No: SDG No.: _2~50_7_66_7 __ _
Matrix: WATER Lab Sample ID: .2.~Q.7~6~7cc1..c.3 __
Samplewl/Vol: 5 ________ Untts: _ML_-----------DateReceived: 09/27/07
Concentrated Extract Volume: 5 Date Extracted:
Level:(low/med) LOW DaleAnalyzed: 1_0/03/i)!.
PercentSollda·. O ___ decanted:( _______ ... -----Dilution Factor:
Extraction: PURGETRAP -------·------·----' Station 10:
GPC Cleanup: ( YIN )
Column(1 ): P.~~~------· ID: 0.18 Jrn_rnl_
CONCENTRATION UNITS: UG/L .. ·-··-····-·-.---••-..
CASNO. ANALYTE
79-00-5 1, 1,2-Tr1chloroethane
127-18-4 Tetrachloroethena
591-78-8 2-Hexanone
124-48-1 Dlbromochloromethane
108-93-4 1,2-Dlbromoethane(EOB)
108-90-7 Chlorobenzene
100-41-4 Ethyl benzene
100-42-5 Styrene
75,25-2 Bromoform
98-82-8 lsopropylbenzene (Cumene)
79.34.5 1, 1,22-Tetrachloroethane
541-73-1 1,3-0ichlorobenzene
108-48-7 1,4-Dlchlorobenzene
95-50-1 1,2-Dlchlorobenzene
96-12-8 1 ,2-Dlbromo-3.ctlloropropane
120-82-1 1,2.~-Trichlorobenzene
87-81-8 1,2,3-Trichtorobenzene
1330-20-7 Xylene (total)
1834-04-4 MTBE
78-13-1 1, 1,2-Trtchlorolrtfluoroethane
108-87-2 Melhyt Cydohexane
79-20-9 Methyl Acetate
110-82-7 Cydohexane
RESULT
1
5
1
2
2
' 1
5
Form I
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u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
Lab FIie ID: 66713.D -·--------.
Time: 1020
1
VOLATILE ORGANIC ANALYSIS OATA SHEET
EPA Sample No.
Lab Name: PEL Laboratories, Inc. Contract: RAM LEATHER I IJ.48697.01.03 RAM_MCNAIR
Lab Code : PEL Case No.: -----
Ma!Jix: WATER -------
Sample wt/vol: ~5'----Untts: _M~L'----
Concentrated Extrad Volume: ~5'-------
Level:(lowlmed) -'=-~""----
Perc:entSolids: O decanted : (
Extraction: PURGETRAP
GPC Cleanup : ( YIN ) pH:
SAS No: ______ SDG No.: 2507667
Lab Sample ID: 250766714 Lab File ID: 66714.D
Date ReoelYOd: 09'27107 ~=~--------
Date Extracted:
Date Analyzed: .~g~l{O.] ____ . Time:
Dilutlon F ador:
Station J~: Metnod:
Column(1): _,D"'B'---6"2'-'4 ___ _ ID: 0.18 ("!!!'l_
CONCENTRATION UNITS: UG/Lc_ ___ _
CASNO. ANALYTl!
75-71-8 Dlchlorodifluoromethane
74-87-3 Chloromethane
75-01-4 Vinyl chloride
74-83-9 Bromomethane
75-00-3 Chtoroethane
75-69-4 Trlchlorofluoromethane
75-35-4 1, 1-Dichloroethene
75-15-0 Carbon disulfide
75-09-2 Methylene chloride
156-60-5 trans-1,2-0ichloroethene
75-34·3 1, 1-Dichloroethane
67-64-1 Acetone
156-59-2 cls-1,2-0ichloroethene
74-97-5 Bromodlloromethane
78-93-3 2-Butanone
67-66-3 Chlorofonn
71-55-6 1, 1, 1-Trichloroethane
56-23-5 Car1:lon tetrachloride
71-43-2 Benzene
107-06-2 1,2-Dichloroethane
79-01-6 Trichloroethane
78-87-5 1,2-Dichloropropane
75-27-4 Bromodichloromethane
10061-01-5 cis-1,3-Dichloropropene
108-10-1 4-Metnyl-2-pentanone
108-88-3 Toluene
10061-02-6 trans-1 ,3-0ichloropropene ·
o:IHIC'lt••
RESULT
10
1
1
5
1
5
Fonm I
?~07RR7
Q
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
I
I
I
I
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VOLATILEORGANICANALYSIS DATA SHEET
EPA Sample No.
Lab Name: PEL Laboratories, Inc. Conlract: RAM LEATHER /046687.01.03 RAM_MCNAIR --·-·--------
Lab Code : PEL Case No.: SAS No: --·----
Matrix: WATER Lab Sample ID: 250766714 ____ Lab File ID: 66_?1_4.[) __ . -·
Sample wt/Vol: ~ ____ Units: fv!l_:__________ Date Received: 09127/07 __________________________ _
Concentrated Extrad Volume: 5
Level:(low/med) L'?I/,/____ _
Perc.entSoHds: O decanted: (
Extraction: PURGETRAP
---·---pH: GPC Cleanup : ( YIN)
Column(1): _i;>_B_:6_~•---ID: 0.16
CONCENTRATION UNITS: _U9.(L ____ _
CASNO, ANALYTI:
79-00-5 1,1,2-Trichloroethane
127-16◄ Tetrachloroethene
591-76-8 2-Hexanone
124◄6-1 Dlbromochloromethane
106-8H 1.2-Dlbromoethane(EDB)
106-90-7 Chlorobenzene
100◄H Ethylbenzene
100◄2-5 Styrene
75-25-2 Bromofonn
96-62-6 lsopropylbenzene (Cumene}
78-34-5 1, 1,2,2-Tetrachtoroethane
541-73-1 1,3-Dlchlorobenzene
106◄6-7 1,4-Olchlorobenzene
95-50-1 1,2-Dlchlorobenzene
96-12-6 1,2-Dlbromo-3-chloropropane
120-62-1 1,2 ,4-Trichlorobenzene
67-81-8 1,2,3-Trichlorobenzene
1330-20-7 Xylene (lolal)
1634-04◄ MTBE
76-13-1 1, 1,2-Trichlorotrifluoroethane
106-67-2 Methyl Cydohexane
79-20-9 Methyl Acetate
110-62-7 Cydohexane
Date Extracted:
Date Analyzed: 1~~~0?.______ Time: ~~---______ _
Dilution Factor:
Station ID:
RESULT
1
5
1
2
2
5
Form I
Q
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
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u
Method: ~
VOLATILEORGANICAHALYSIS DATA SHEET
EPA.Sample No.
Lab Name: PEL Laboratories, Inc. Contrad: RAM LEATHER/ 048697.01.03 TRIP BLANK
Lab Code : PEL Case No.:
Matrtx: WATER -'-"---'-'"-'------
Sample wt/Vol: _5 ___ Units: _M_L ___ _
Concentrated Extract Volume: 5
Lavel:(low/med) _L.O~-. _
PercentSolids: O decanted : (
Extraction: PURGETRAP -----·---------·
GPC Cleanup : ( YIN ) ___ pH:
Column(1): D_B_~_2_4 __ _ ID: 0.18
CO/\ICE/1/TRA TIO/\/ U/1/ITS: UG/l
CASNO. ANALYTf!
75-71-8 Dlchlorodifluoromethane
74-87-3 Chloromethane
75-01-4 Vinyl chloride
74-83-9 Bromomethane
75-00-3 Chloroethane
75~9-4 T richlorofluoromethane
75-35-4 1, 1-Dlchloroethene
75-15-0 Carbon disulfide
75-09-2 Methylene d'lloride
156~0-5 trans-1,2-Dichloroethene
75-34-3 1, 1-Dlchloroethane
67~-1 Acetone
156-59-2 cls-1,2-0ichloroethene
74-97-5 Bromochloromethane
78-93-3 2-Butanone
67~-3 Chloroform
71-55~ 1, 1, 1-Trichloroethane
56-23-5 Carbon tetrachloride
71-43-2 Benzene
107-06-2 1,2-0ichloroethane
79-01~ Trichloroethane
78~7-5 1,2-0lchloropropane
75-27-4 Bromodichloromethane
10061-01-5 cis-1,3-0lchloropropena
108-10-1 '4-Methyl-2-pentanone
108-88-3 Toluene
10061-02-6 trans-1,3-Dichloropropene
SAS No: -----SDG No.: _2~50~7~66~7~----
Lab Sample ID: 250766715 Lab File ID: 667,!S_J:)_ ___ _
Date Received: 09/27/07 -------------
Date Extracted:
DateAnalyzed: 10/0_31_0_7 ___ _
Dilution Factor:
Station 10: -----------
RESULT
1
10
1
5
5
Form I
Q
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
Time: 1108
Method: ll2§l1
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40
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1
VOLATILE ORGANIC ANALYSIS DATA SHEET
EPA Sample No.
Lab Name; PEL Laboratories. Inc. . --. ---. -----···-Conlrect: RAM LEATHER /048697.01.03 ----·-·--··-··----'----------~ TRIP BLANK
Lab Code: P_E~---···-· _____ Case No.: -·-----SAS No: ______ SDG No.: 250~7_66_7 ___ _
Matrix: WATER_____ Lab Semple ID: 250766715 Lab File 10: 66715.D
Sample wt/vol: J ______ .. Units: ML Date Received:
Concentrated Extract Volume: 5
Level:(low/med) LOW
PercentSolfds: 0 decanted : (
Extraction: _P~!3_GETRAP
GPC Cleanup : ( Y/N) ___ pH:
Column(1): DB-824 __ _ ID: 0.18
CONCENTRATION UNITS: UG/L -·-------··-··--
CASNO. ANALYTEi
79-00-5 1, 1,2-Tr1chloroethane
127-18-4 Tetrachloroethene
591-78-6 2-Hexanone
124-48-1 Olbromochloromethane
106-93-4 1,2-Dlbromoethane(EDB)
108-90-7 Chlorobenzene
100-41-4 Ethylbenzene
100-42-5 Slyrene
75-25-2 Bromofonn
98-82-8 lsopropytbenzene (Cumens)
79-34-5 1, 1,2,2-Tetrachloroethane
541-73-1 1,3-Dlchlorobenzene
106-48-7 1,4-0ichlorobenzene
95-50-1 1,2-Dlchlorobenzene
96-12-8 1,2-0lbromo•3-chloropropane
120-82-1 1,2,4• Trichlorobenzene
87-81-6 1 .2 .3-Trichlorobenzene
1330-20-7 Xylene (tolel)
1634-04-4 MTBE
76-13-1 1, 1,2-Trichlorotrifluoroethane
108-87-2 Methyl Cydohexane
79-20-9 Methyl Ac:elale
110-82-7 Cydohexane
tt,,,,.,,., .. ,
Date Extracted:
Date Analyzed:
DIiution Factor:
Station ID:
RESULT
1
5
1
2
1
2
1
5
Fonm I
_ 09/27/07 _ --·----------· .. ·-····-·-·
10/03/07 Time: 1108
-----·-··-··-· •. Melhod: ~
Q
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u
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ENERGY WATER INFORMATION GOVERNMENT
Date:
Subject:
From:
To:
October 25, 2007
Organic Data Validation for SDG 2507682
Ram Leather Site
Suzanne Prouty, Validator
Environmental Scientist
Georgia Office
Nancy Gellar
Black & Veatch Special Projects
Project Manager
Gina Montgomery, Oversight Reviewer
Lead Scientist, Georgia Office
Black & Veatch Special Projects Corp., 1120 Sanctuary Parkway, Suite 200, Alpharetta. GA 30004 USA, Telephone: [phone], fax: [phone]
I. OVERVIEW
This report presents the results of the Region IV data validation for samples collected at
the Ram Leather Site. PEL Laboratories, Inc. analyzed IO water samples under SDG
2507682. The water samples were analyzed for volatile organics (SW-846 Method
8260).
The samples were assessed based on the data review criteria specified in the United
States Environmental Protection Agency Region 4 National Functional Guidelines for
Organic Data Review, June 2001.
II. SUMMARY
All samples were successfully analyzed. No data were rejected.
III. MAJOR PROBLEMS
No major problems were noted.
IV. MINOR PROBLEMS
Volatile Organic Compounds
• The preservation and holding times were acceptable.
• The Method Blank results were acceptable. No contaminants were
present.
• The performance of the Deuterated Monitoring Compounds (DMCs) was
acceptable.
• The surrogate percent recoveries were acceptable for all compounds.
• The matrix spike had acceptable percent recoveries (¾R).
• The matrix spike duplicate had unacceptable ¾R for bromomethane,
· trichlorofluoromethane, tetrachloroethene, styrene, methyl acetate, 1,2,3-
trichlorobenzene, and tert-butyl methyl ether (MTBE). The matrix spike
duplicate had unacceptable relative percent difference (RPD) for
dichlorodifluoromethane, vinyl chloride, chlorobenzene, styrene, zylene
(total), tert-butyl methyl ether (MTBE), methyl cyclohexane, and methyl
acetate. The compounds with deficiencies did not have unacceptable
results for any other QC parameters; therefore, no validation was
required for the samples associated with this data package.
• The initial calibrations had acceptable relative response factors (RRFs)
and percent relative standard deviation (¾RSD) for all compounds.
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LCS
ch\o(Df:~= Ir::: 21.7 x 10() = IIY /, ✓ , ZD
,
Cw i br (th 00 ~
8
0::Cofl~ SOU,t.CL Caii ~-(IV\_~
·/ b ().,OKlDI · --~-x I t)(J ::. 1 a I . LI --I oo =-I _ 4 ·; AC,Q:;tt}V Q, Og Si I
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1· Organic Review Summary ,.
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APPENDIX B:
ORGANIC DATA REVIEW SUMMARY
CASE NO. __________ SITE __ R=a=m~L=ea=th=e~r ________ _
LABORATORY PEL Laboratories NO. OF SAMPLES/MATRIX IO water
SDG NO. __ _.2""5.,,_07,_,,6""8,,,_2 ___ _ SOW NO. ______ _ REGION--'I~V __ _
REVIEWER NAME =Su=za=nn=e~P~ro=u=ty.,_ ____ COMPLETION DATE I 0/25/2007
CLP PO: ACTION _________ FYI _____ _
REVIEW CRITERIA FRACTION
VOA BNA PEST/PCB
I. PRESERVATION 0
2. GC/MS OR GC/ECD INSTRUMENT
PERFORMANCE CHECK 0
3. INITIAL CALIBRATION 0
4. CONTINUING CALIBRATION OR
CALIBRATION VERIFICATION 0
5. BLANKS 0
6. DEUTERATED MONITORING COMPOUND
SURROGATE SPIKES 0
7. MATRIX SPIKES/MATRIX SPIKE
UPUCATES X
8. LABORATORY CONTROL SAMPLE ·, ;•· , :·, ... _. ,. •• • •~ ·••,:;. 'l~ •, .. ... ... •' •••• ;~ ;, -~. ·~ 'I
9. REGIONAL QA/QC 0
IO. INTERNAL STANDARDS 0 . -· ,. .1 _,·, .
1' .
II. FLORISIL CARTRIDE PERFORMANCE ··-:-'-"~~r '..X. ,'·'t:-''• .~:· !,.·,J'i'. '_:-;'.' <;/·~ ~ . •' . ..
CHECK . h -:::it.<,·~ ..... .".:.\. ''. '·. ;:
12. TAR GET COMPOUND IDENTIFICATION 0
I 3. COMPOUND QUANTITA TION AND
REPORTED CRQLS 0
14. COMPOUND QUANTITATION
AND REPORTED CRQLS 0
15. TENTATIVELY IDENTIFED COMPOUNDS X -. .. . ,. :
16. SYSTEM PERFORMANCE 0 •·
,'
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Appendix A
Glossary of Data Qualifiers
DATA QUALIFIER DEFINITIONS
The following definitions provide brief explanations of the national qualifiers assigned to results in the data review process. If the Regions choose to use additional qualifiers, a complete explanation of those qualifiers should accompany the data review.
u The analyte was analyzed for, but was not detected above the level of the reported sample quantitation limit.
J The result is an estimated quantity. The associated numerical value is the approximate concentration of the analyte in the sample.
J+ The result is an estimated quantity, but the result may be biased higb.
J-The result is an estimated quantity, but the result may be biased low.
R The data are unusable. The sample results are rejected due to serious deficiencies in meeting Quality Control (QC) criteria. The analyte may or may not be present in the sample.
UJ The aoalyte was analyzed for, but was not detected. The reported quantitation limit is approximate and may be inaccurate or imprecise.
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Appendix B
Table I -Summary of Analytes Failing Criteria
QCD-""-t I Analytes Failing Criteria
& Criteria I
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Table I
Summary of Analytes Failing Criteria
Ram l..eathCI" Site
SDG 2507682
........ ,1
M,tbod
I Rault
I .....
No sample n:sults were qualified for this sample delivery group.
---
l Result Flu• A .. .J....1 To l (S..-ifv. An•Mes ID)
---
••
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Appendix C
Samples Results Qualified Based On Data Validation
No data was qualified based on data validation.
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AppendixD
Results as Reported by the Laboratory ,
VOLATILEORGANICANALYSIS DATA SHEET
EPA Sample No.
Lab Name: PEL Laboratories, Inc. Con~ad: RAM LEATHER I 048897.01.03 RAM_GLOSSON
Lab Code : PEL Case No.: SAS No: SDG No.: 2507882 -------------
Matrix: WATER Lab Sample ID: 250788201 Lab FIie ID: 68201.D -------
Date Received: 09/29/07 -------------
Concentrated Extract Volume: 5 0 ate Extracted:
Le\18I:(lowlmed) ~L~OW __ _ Date Analyzed: 10/09107 Time: 1353 =----
PercentSolids: O decanted : ( DIiution Factor:
Extraction: PURGETRAP Station ID; Mathod: ~
GPC Cleanup : ( YIN ) ___ pH:
Column(1): DB-624 ID: 0.18
CONCENTRATION UNITS: .!,!~G~IL~----
CASNO.
75-71-8
74-87-3
75-01-4
74-83-9
75-00-3
75-69-4
75-35-4
75-15-0
75-09-2
156-60-5
75.34.3
67-64-1
156-59-2
74.97.5
78-93-3
87-68-3
71-55-6
58-23-5
71-43-2
107-06-2
79-01-6
78-67-5
75-27-4
10081-01-5
108-10-1
108-88-3
10081-02-6
1"0Cl' ""'
ANALYTE
Dichlorodifluoromethane
Chloromethane
Vinyl chloride
Bromomethane
Chloroethane
Tr1chlorofluoromethane
1, 1 -Olchloroethene
Carbon dlsutflde
Methylene chlonde
· trans-1,2-Dlchloroethene
1, 1-Dichloroethane
Ac.atone
cia-1,2-0lchloroethene
Bromochloromethane
2-Butanone
Chloroform
1, 1, 1-Tr1chloroethane
Carbon tetrachloride
Benzene
1,2-Dichloroethane
Trichloroethane
1,2-Dlchloropropane
Bromodichloromethane
cis-1,3-0ichloropropene
4-Methyl-2-pentanone
Toluene
lrans-1,3-0lchloropropene
REI/ULT
1 .1
10
70
5
1
1
32.7
1
5
Form I
2507682
Q
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VOLATILE ORGANIC ANALYSIS DATA SHEET
EPA Sample No.
Lab Name: PEL Laboratories, tnc.________ Contract: RAM LEATHER I 048697.01.03 RAM_GLOSSON
Lab Code : PEL Case No.: SAS No: SDG No.: 2507682
Matrbc; WATER ---
Sample wt/\l'ol: 5 Units: ML
Concentrated Extract Volume: 5
Level:(low/med) LOW
PercentSotids:
Extraction:
0
PURGETRAP
decanted : ( .
GPC Cleanup : ( YIN ) ___ pH:
Column(1): DB~24 ____________ ID: 0.18
CONCENTRATION UNITS:
CASNO. ANALYTE
79-00-5 1, 1,2-Trichtoroethane
127-18--4 Tetrachloroethene
581-78-6 2-Hexanone
124-<B-1 Dlbromochloromethane
106-83-< 1.2-Dlbromoethane(EDB)
108-80-7 Chlorobenzene
100-<H Ethylbenzene
100-<2-5 Styrene
75-25-2 Bromoform
98-82-8 lsopropylbenzBne (Cumene)
79-34-5 1.1,2,2-Tetrachloroethane
541-73-1 1,3-0lchtorobenzene
106-<8-7 1,4-0lchlorobenzene
95-50-1 1,2-Dlchlorobenzene
96-12-8 1,2-Dibromo-3-chloropropane
120-82-1 1,2,4-Trlchlorobenzene
87-61-6 1,2,3-Trlchlorobenzene
1330-20-7 Xylene (total)
1834-04-< MTBE
78-13-1 1, 1,2-Trlchtorotrifluoroethane
108-87-2 Methyl Cydohexane
78-20-8 Methyl Acetate
110-82-7 Cydohexane
---------··-----·-·-•--
Lab Sample ID: ~5Q~6~2_1)) .. Lab FIie ID: 68201.D
Date Recelwd: 09/29/07 -------·----------·
Date Extracted:
Date Analyzed: 10/09/07 Time: 1353
Ollutlon Factor;
Station ID: Method: li6Jl
RESULT
97.8
5
2
2
1
5
Form I
2507682
Q
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13
1
VOL.A TILE ORGANIC ANALYSIS DATA SHEET
EPA Sample No.
lab Name: PEL Laboratories, Inc. =="-----Contrad: RAM LEATHER/ 0-48697.01.03 RAM_GLOSSONDL1
Lab Code : PEL Case No.: SAS No: SOG No.: 2507682 ----------
Matrix: WATER Lab Sample ID: 25076620,0L 1 Lab File ID: 682010.D
Sample wt/vol: 5 Units: ML
Concentrated Extrad Volume: 5
Lavel:(low/mea) LOW
PercentSollda: 0 decanted: ( __ ,, _______ ,,_,_ --•-~----·-·-
Extraction: PURGETRAP
GPC Cleanup: ( YIN ) -----·· pH:
Column(1): DB-624 ID: 0.18
CONCENTRATION UNITS: ~U~G~/L~----
CASNO.
75-71-8
74-87-3
75-01 ◄
74-83-9
75-00-3
75-89◄
75-35◄
75-15-0
75-09-2
156-60-5
75.34.3
67-64-1
156-59-2
74-97-5
78-93-3
67-66-3
71-55-6
56-23-5
71◄3-2
107-06-2
79-01-6
76-87-5
75-27◄
10061-01-5
108-10-1
108-86-3
10081-02-6
ANALYn!
Dichlorodifluoromethane
Chloromethane
Vinyl chloride
Bromomethane
Chloroethane
Trichloroffuoromethane
1, 1-Dlchloroethene
, carp'?n disulfide
Methylene chloride
trana-1,2-0ichloroethene
1, 1-0ichloroethane
Acetone
cis-1,2-0lchloroethene
Bromod"lloromethane
2-Butanone
Chloroform
1, 1, 1-Trichloroethane
Carbon tetrachloride
Benzene
1,2-Dlchloroethane
Trichloroethane
1,2-Dlchloropropane
Bromodlchloromethane
cis-1,3-Dlchloropropene
4-Methyt-2-pantenona
Toluene
trans-1,3-0ichloropropene
Date R80Blwd:
Date Extracted:
Date Anatyzed:
Oilutlon Factor:
Station ID:
RESULT
5
5
5
5
5
5
5
5
5
5
5
50
74.4
5
25
5
5
5
5
5
35.2
5
5
5
25
5
5
Fonm I
2507682
09/29/07
10/09/07
5
Q
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Time: 1421 -----
Malhod: ~
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VOLATILE ORGANIC ANALYSIS DATA SHEET
EPA Sample No.
Lab Name: PEL Laboratories. Inc._________ Contrad: RAM LEATHER '·~~~~?J!1.0,! RAM_GLOSSONDL1
Lab Code : PEL Case No.: SAS No: SDG No.: 2507662 -·-----·----· ---·•---------·-··---------
Matrix: WATER
Sample wWol: -~---Units: ML
Concentrated Extract Volume: 5 ·-·-·-----
Level:(low/med) LOW
PercentSollda·, 0 decanted : ( .
Extraction: PURGETRAP ---------------------. ------··----
GPC Cleanup : I Y /N I pH;
Column(1): _(18-62<4 ID: 0.18
CONCENTRATION UNITS: .. Y§.'!c.
CASNO.
79-00-5
127-18-4
591-78-6
124-48-1
106-93-4
108-90-7
100-41-4
100-42-5
75-25-2
98-82-8
79-34-5
5-41-73-1
106-48-7
95-50-1
96-12-8
120-82-1
87-81-6
1330-20-7
1634-04-4
76-13-1
108-87-2
79-20-9
110-82-7
11,,XIT•l'Ool
ANALYTE
1, 1,2-Trichloroethane
Tetrachloroethene
2-Hexanone
Dlbromochloromethane
1.2-0lbromoethane(EDB)
Chiaro benzene
Ethylbenzene
Styrene
Bromoform
tsopropytbenzene (Cumene)
1, 1 ,2,2-Tetrachloroethane
1,3-Olchlorobenzene
1,4-0lchlorobenzene
1,2-0lchlorobenzene
1,2-0ibromo-3-chloropropane
1,2,4-Trlchlorobenzene
1,2,3-Trlchlorobenzene
Xylene (lotal)
MTBE
1, 1,2-Trlchlorotrlfluoroethane
Methy1 Cyclohexane
Methy1 Aoetale
Cydohexane
Lab Sample 10: 250766201DL1 Lab File ID: 66201 D.D _ -·· _
Date Reoelved: 09129/07 -------------
Date Extracted:
DateAnalyzed: )10/0~/0_?_ __________ Time: 1421 ------·
DIiution Factor: 5
Station 10:
RESULT
5
101
25
5
5
5
5
5
5
5
5
5
5
5
10
5
5
10
5
5
5
25
5
Form I
2507682
Q
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u
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u
u
u
u
u
u
u
Method:
15
VOLATILE ORGANIC ANALYSIS DATA SHEET
EPA Sample No.
lab Name: PEL Laboratories, Inc. Contract: RAM LEATHER/ 048897.01.03 RAM_GLOSSON9
Lab Code : PEL Case No.: -----
Matrtx: WATER -=~----
Sample wt/1101: .c.5 ___ Unrts: ~M~L'------
Concentrated Extract Volume: 5 ____ _
Level:(low/med) LOY",·-·· ·-·
PercentSollda: O decanted . (
Extraction: PURGETRAP
GPC Cleanup: ( YIN ) ___ pH:
Column(1): 08-624 10: 0.18
CONCENTRATION UNITS: UG/L
CASNO. ANALYTE
75-71-6 Dlchlorodiftuoromethane
74-87-3 Chloromethene
75--01-4 Vinyl chloride
74-83-9 Bromomethane
75--00-3 Chloroethane
75-69◄ Trichlorofluoromethane
75-35-4 1, 1-0ichloroethene
75-15--0 Carbon disulfide
75--09-2 Methylene chloride
158-60-5 trana-1,2-Dlchloroethene
75-34-3 1, 1-Dlchloroethane
87-&4-1 Acetone
158-59-2 cls-1,2-0ichloroethene
74-97-5 Bromod"lloromethane
78-93-3 2-Butanone
87-66-3 Chloroform
71-55-6 1.1, 1-Trichloroethane
58-23-5 Cartion tetrachloride
71-43-2 Sanzone
107-06-2 1,2-0lchloroethane
79--01-6 Trichloroethane
78-87-5 1,2-Dichloropropane
75-27◄ Bromodichloromethane
10081-01-5 cls-1,3-Dlchloropropene
108-10-1 4-Methyl-2-pentanone
108-88-3 Toluene
1 0081--02-6 trans-1 ,3-0id"lloropropene
SAS No: SOG No.: 2507682 ==-=-----
Lab Sample ID: 250766202 Lab FIie ID: 88202.D
Date Received: 09/29/07 -------
Date Extracted:
DateAnalyzed: 10/09107 ___ Tlme: ·~-~~---·---·----
DIiution Factor:
Station ID:
RESULT
1
0.52
10
77.8
1
5
1
38.1
5
Form I
2507682
Q
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Method: ~
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VOLATILE ORGANIC ANALYSIS DATA SHEET
EPA Sample No.
Lab Name: _PEL Laboratonea. Inc._________ Contrad: RA~ LEA_T!:tfo~{_04_!1~9_7i!-03 ._ __ RA_M ___ G_L_o_s_s_o_N_9 __ ~
Lab Code : PEL Case No.: SAS No: SDG No.: 250768_2 ____ _
Matrix: WATER Lab Sample ID: _2_5-0~6~~~-Lab File ID: 68202.D "'-------~-· -· -. ·--
Sample wt/vol: _5 ________ Units: . .'!".!-_______________ Date Recelll9d: 09129/07
Concentrated Extrad Volume; 5 Date Extracted: -· -----· -·----·--
Level:(low/med) LOW · Date Analyzed: 10/09/07 ___ -·-Time: 1448
PercentSolids: o . decanted ; ( DIiution Factor:
Extraction: PURGETRAP Station ID: Method: ~
GPC Cleanup : ( YIN ) pH:
Column(1): _ DB-624_____ ID: 0.18 _ (~rr,)_
CONCENTRATION UNITS: UG/L -----.-----·-----
CASNO. ANALYTE
79-00-5 1, 1,2-Trichloroethane
127-18-4 Tetrachloroethene
591-78-6 2-Hexenone
124-48-1 Dlbromochloromethane
106-93-4 1,2-Dlbromoethane(EDB)
108-90-7 Chlorobenzene
100-41-4 Ethyl benzene
100-42-5 Styrene
75-25-2 Bromofonn
98-82-8 lsopropylbenzene (Cumene)
79-34-5 1, 1,2,2-Tetrachloroethane
541-73-1 1,3-Dlchlorobenzene
106-48-7 1 ,4-Dlchlorobenzene
95-50-1 1,2-0ichlorobenzene
96-12-8 1,2-0lbromo-3-chloropropane
120-82-1 1,2,4-Trtchlorobenzene
87-61-6 1,2,3-Trlchlorobenzene
1330-20-7 Xylene (total)
1834-04-4 MTBE
76-13-1 1, 1,2-Trlchlorotrffluoroethane
108-87-2 Methyl Cydohexane
79-20-9 Methyl Acetate
110-82-7 Cydohexane
RESULT
105
5
1
2
2
1
5
Form I
2507682
Q
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17
VOLATILE ORGANIC ANALYSIS DATA SHEET
EPA Sample No.
Lab Name: PEL Laboratories, lnc. ·-·•-.. ---• -~---Contrad: RAM LEATHER/ 048897.01.03 RAM_GLOSSON9DL 1
Lab Coda : c.P..=EccL ___ _ Case No.: SAS No: SDG No.: 2507682
Matrix: WATER Lab Semple ID: 250768202DL 1 Lab File ID: 68202.~D'-'.D"-----
Sample wt/Vol: __5 ______ Unila: _M_L ____ _ Data ReceMJd: ~0:::9:::12:::9/'-"0-'-7 __________ _
Concentrated Extrad Volume: 5 Data Extracted:
Level:(low/med) . l,_O11\1 __ .. __ Date Analyzed: 10/09/07 Time: _1:::5cc16::._ __ _
PercentSollds: O decanted : ( Dilution Factor: 5
Extraction: PURGETRAP Slatlon ID: Method: mg
GPC Cleanup: ( YIN) ---·--·-pH:
Column(1): DB-624 ID: 0.18
CONCENTRA T/ON UNITS: ~U~G-'-/1.~----
CASNO. ANALYTE RESULT Q
75-71-8 Oichlorodlfluoromethane 5 u
74-87-3 Chloromethane 5 u
75-01-4 Vinyl chloride 5 u
74-83-9 Bromomethane 5 u
75-00-3 Chloroethane 5 u
75-69-4 Trichlorotluoromethane 5 u
75-35-4 1, 1-0ic:htoroethene 5 u
75-15-0 Carbon disutfide 5 u
75-09-2 Methytene chloride 5 u
156-60-5 trans-1,2-0lchloroethene 5 u
75.34.3 1, 1-Dichloroethane 5 u
67-64-1 Acetone 50 u
156-59-2 cls-1,2-Dichloroethene TT.5
74.97.5 Bromochloromethane 5 u
78-93-3 2-Butanone 25 u
87-66-3 Chloroform 5 u
71-55-6 1, 1,1-Trichloroethane 5 u
56-23-5 Carbon tetrachloride 5 u
71-43-2 Benzene 5 u
107-06-2 1,2-Dlchloroethane 5 u
79-01-6 Trlchloroethena 37.8
78-87-5 1,2-Dlchloropropane 5 u
75-27-4 Bromodichloromethane 5 u
10061-01-5 ds-1,3-0ichloropropene 5 u
108-10-1 ◄-Melhyl-2-pentanone 25 u
108-88-3 Toluene 5 u
10061-02-6 trans-1,3•Dichloropropene 5 u
Form I
2507682
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VOLATILE ORGANIC ANALYSIS DATA SHEET
EPA Sample No.
RAM_GLOSSON9Dl 1
Lab Code: PEL Case No.: SAS No: SDG No.: 2507682 ---·----··--··
Matrix: WATER ----lab Sample ID: _2_~0J8_1!2_D~Cll,~_ -· lab File ID: 682020.D
Sample wt/Vol:5 ____ Units: ML Date Received: 09/29/07 ----
Concentrated Extract Volume: 5 Date Extracted:
Level:(low/med) LOW DateAnalyzed: 10/09/07 Time: 1516
PercentSollds: 0 decanted; ( Dilution Factor: 5
Extraction: _PURGETRAP_··----·-··"··· -·-· -··--·-···--· Station ID: Melhod: ~
GPC Cleanup: ( YIN ) pH:
Column(1): DB-624 ID: 0.18 .('"."'L
CONCENTRATION UNITS: UG/L .. --------·-··· _____ ,. _____
CASNO, ANALYTE RESULT Q
79·00-5 1,1,2-Trichloroethane 5 u
127-18-4 Tetrachloro8thene 108
591-78•8 2-Hexanone 25 u
124-48-1 Dlbromochloromethane 5 u
106-93-4 1,2-0lbromoethane(EDB) 5 u
108-90-7 Chlorobenzene 5 u
100-41-4 Ethylbenzene 5 u
100-42-5 Styrene 5 u
75-25·2 Bromofom, 5 u 98-82·8 l~opropylbenzene (Cumene} 5 u
79.34.5 1, 1,2,2-Tetrachloroethane 5 u
541-73-1 1,3-Dichlorobenzene 5 u
106-48-7 1,4-Dlchlorobenzene 5 u
95-50·1 1.2-0ichlorobenzene 5 u
98-12·8 1 ,2-Dlbromo-3-chloropropane 10 u
120-62·1 1,2,4· Trichlorobenzene 5 u
87-61-6 1,2,3-Trict,lorobenzene 5 u
1330-20-7 Xylene (total) 10 u
1634-04-4 MTBE 5 u
76-13·1 1, 1,2· Trlchlorotrifluoroethane 5 u
108-87-2 Methyl Cydohexane 5 u
79-20·9 Methyl Acetate 25 u
110-82-7 Cydohexane 5 u
Form I
2507682 19
1
VOLATILE ORGANIC ANALYSIS DATA SHEET
EPA Sample No.
Lab Name: PEL Laboratories, Inc. __ Contract: RAM LEATHER/ 048897.01.03 DW11
Lab Code : c_P,cEL=----Case No.:
Matrix: WATER
Concentrated Extrad Volume: 5
Level:(low/med) LOW
PercentSoUda: O decanted ;
Extraction: PUR.'-'GC.CE:.CTc..RAc.c..P ______ _
GPC Cleanup: ( Y/N)
Column(1): DB-624 ID: 0.18
CONCENTRATION UNITS: UG/L
CASNO.
75-71-6
74-67-3
75-01-4
74-63-9
75-00-3
75-69--4
75-35-4
75-15-0
75-09-2
156-60-5
75-34-3
87-64-1
158-59-2
74-97-5
78-93-3
87-68-3
71-55-6
56-23-5
71--43-2
107-06-2
79-01-6
78-87-5
75-27-4
10061-01-5
106-10-1
108-88-3
10061-02-6
ANALYTc
Did"llorod111uoromethane
Chloromethane
Vlnyl chloride
Bromomethane
Chloroethane
Trichlorofluoromethane
1, 1-Dlchloroethene
Carbon disulfide
Methylene chloride
trans-1,2-Dichloroethene
1, 1-Dlchloroethane
Acetone
cis-1,2-Dichloroethene
Bromochloromethane
2-Butanone
Chloroform
1, 1,1-Trichloroethane
Carbon tetrachloride
Benzene
1,2-Dlchloroethana
Trichloroethena
1,2-Dlchtoropropana
Bromodichloromethane
cis-1,3-Dichloropropene
'4-Methyl-2-pentanone
Toluene
trans-1,3-Dichloropropene
SAS No: SDG No.: 2507682
Lab Sample 10: -~51)76821)~---··· Lab FIie ID: 68~20~3~.D~_
Date Received: 09/29/07 ·--··---·--······------··-----_,_,, _____ , _____________ ----
Date Extracted:
Date Analyzed: _ 10/09/07 ... __________ Time:
Dilution Factor: 5
Station ID: ________ Method:
RESULT
5
5
18.2
5
5
5
2.7
5
5
15.2
5
50
1620
5
25
5
5
5
5
5
356
5
5
5
25
5
5
Form I
2507682
Q
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u
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1639
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VOLATILE ORGANIC ANALYSIS DATA SHEET
EPA Sample No.
Lab Name: PEL Laboratortes, Inc. Contrad: RAM LEATHER /048697.01.03 DW11
Lab Code : PEL Case No.: SAS No: SDG No.: 2507682 -----·-----·-··· ------·-·---------· ------------
Matrix: WATER Lab Sample ID: ~~75.S~Q~ ... Lab File ID: 68203.D . ---------· --
Sample wt/vof: §----~-Units: ML -----·-Date Received: :c09::.12cc9c./0'-'7 __________ _
Concentrated Extrad Volume: 5 Date Extracted: ----------· ----------------
Level:(low/med) -~()~----·-Dale Analyzed: !.!I_I0_9fl!! _________ _ Time: 1839 --··--------------· Percen1S0Uds: 0 decanted : ( Dilution Fader: 5
Extraction: PURGETRAP Station ID: Method: ~ -·--------. ---· ---. ----------------
GPC Cleanup : ( Y/N ) pH: --..• -----
Column(1): D.~~~---ID: 0.18 (l11_"1)_
CONCENTRATION UNITS: UG/l -----------.... --------·
CASNO. ANALYTE RESULT Q
79-00-5 1, 1,2-Trlchloroethane 5 u
127-18-4 T etrachloroethene 4320 E
591-78-8 2-Hexanone 25 u
124-48-1 Dlbromochtoromethane 5 u 106-93-4 1,2-Dlbromoethane(EDB) 5 u
108-90-7 Chlorobenzene 5 u
100-41-4 Ethyl benzene 5 u 100-42,5 Slyrene 5 u
75-25-2 Bromoform 5 u 98-82-8 lsopropy1benzene (Cumene) 5 u
79-34-5 1.1,2,2-Tetrachloroethane 5 u 541-73-1 1,3-0lchlorobenzene 5 u
106-48-7 1,4-0lchlorobenzene 5 u
95-50-1 1,2-Dlchlorobenzene 5 u
96-12-8 1,2-Dlbromo-3-chloropropane 10 u 120-82-1 1,2,4-Trtchlorobenzene 5 u
87-81-8 1,2,3-Trtchlorobenzene 5 u
1330-20-7 Xylene (lotal) 10 u 1634-04-4 MTBE 5 u
78-13-1 1, 1,2-Trtchlorolrifluoroethane 5 u 108-87-2 Methyl Cydohexane 5 u
79-20-9 Methyl Acetale 25 u 110-82•7 Cydohexane 5 u
Form I
2507682 21
VOLATILEORGANICANALYSl8 CATA SHEET
EPA Sample No.
Lab Name: PEL Laboratories, Inc. Contract: RAM LEATHER I 048897.01.03 DW11DL1
Lab Code : ~P_:E:::L ___ _ Case No.: SAS No: SDG No.: 02:::50.:.7:._:68=2 ____ _
Matrix: WATER ---·----Lab Sample ID: _2~?~82Q.3_1:)~_1 ___ Lab File ID: El_8!03~.D
Sample wVvol: -~-______ Units: -~~--_ .. --··--· Date Received: 09/29/07 ------------··----·---~--------
Concentrated Extrad Volume: 5 Date Extracted:
Level:(lowlmed) __ L(?Y,_, ..... DateAnalyzed: .. ~lll_9~7-...... -.... Time: 1_~3 .... _ .. _____ _
PercentSollds: ~oc...... __ decanted: ( __ .. ______ _ Dilution Factor: 200
Extraction: PURGETRAP Station ID: Method: ~
GPC Cleanup: ( YIN ) pH: ···-·-----
Column(1): DB-824 ID: 0.18 ("!.•!'l...
CONCENTRATION UNITS: UG/L --······------------
CASNO. ANALYTI! RE!SI/LT Q
75-71-8 Dichlorodlfluoromethane 200 u
74-87-3 Chloromethane 200 u
75-01-4 Vlnyl chloride 200 u
74-83-9 Bromomethane 200 u
75-00-3 Chloroethane 200 u
75-89-4 Trichlorofluoromelhane 200 u
75-35-4 1, 1-Dichloroethene 200 u
75-15-o Carbon dlsulflda 200 u
75-09-2 Methylene chloride 200 u
156-80-5 trans-1,2-0lchloroethene 200 u
75-34-3 1, 1-Dichloroethane 200 u
87-84-1 Acetone 2000 u
156-59-2 cls-1,2-0ichloroethene 1430
74-97-5 Bromochloromethane 200 u
78-93-3 2-Butanone 1000 u
67-88-3 Chloroform 200 u
71-55-8 1, 1, 1-Trlchloroethane 200 u
56-23-5 Carbon tetrachloride 200 u
71-43-2 Benzene 200 u
107-06-2 1,2-0lchloroethane 200 u
79-01-8 Trichtoroethene 322
78-87-5 1,2-Dichloropropane 200 u
75-27◄ Bromodichloromethane 200 u
1006,-01-5 cis-1,3-Dlchloropropene 200 u
108-10-1 4-Methy$-2-pentanone 1000 u
108-88-3 Toluene 200 u
10061-02-8 trans-1,3-0ichloropropene 200 u
Form I
2507682
I
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VOLATTLEORGANICANALYSIS DATA SHEET
EPA Sample No.
OW11DL1 lab Name: PEL Laboratories, Inc. _______ Contract Rf-_~_~EAT~~(P'!~§~!:~O}. ~---------~
Lab Code : PEL Case No.: SAS No: SDG No.: 2507682 ··------·· -------------·-·----· -------
Matrtx: WATER Lab Sample ID: 2~Q?6_8~03DL_1 Lab FIie ID: 682030.D
Sample wt/Vol: _E_ ___ _ Unlta: ML __ _ DateRec.eived: 09/29/07 ______________________ ....
Concentrated Extract Volume: 5 Date Extracted:
Level:(1owtmed) LOW Dale Analyzed: 10/0_910? ...•..
PercentSollds; 0 decanted: ( Dilution Factor:
E>rtractlon: PURGETRAP Station ID:
GPC Cleanup : ( YIN ) _____ ... pH: -------· __
Column(1 ): .~!:i~24 ___ ID: 0.18 . (~!") ..
CONCENTRATION UNITS: UG/L ....... ___ -·---· _
CASNO.
79-00-5
127-18-4
591-78-6
124-48-1
106-93-4
108-90-7
100-41-4
100-42-5
75-25-2
98-82-8
79.34.5
541-73-1
106-48-7
95-50-1
98-12-8
120-82-1
87-81-8
1330-20-7
1634-04-4
76-13-1
108-87-2
79-20-9
110-82-7
ANALYTE
1, 1,2-Trtchloroethane
Tetrachloroethene
2-Hexanone
Dlbromochloromethane
1,2-Dlbromoethane(EDB)
Chlorobenzene
Ethy1benzene
Styrene
Bromoform
lsopropylbenzene (Cumene)
1, 1,2,2-Tetrachloroethane
1,3-Dichlorobenzene
1,4-0ichlorobenzene
1 ,2-Dlchlorobenzene
1,2-0fbromo-3-chloropropane
1,2.4-Trichlorobenzene
1,2,3-Trichlorobenzene
Xylene (iolal)
MTBE
1, 1 ,2-Tr1chlorotrtfluoroethane
Methyl Cydohexane
Methyl Acetate
Cydohexane
RESULT
200
4300
1000
200
200
200
200
200
200
200
200
200
200
200
400
200
200
400
200
200
200
1000
200
Form I
2507682
200
Q
u
u
u
u
u
u
u
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u
u
u
u
u
u
u
u
u
u
u
u
u
Time: 1543
Method: ~
23
VOLATILE ORGANIC ANALYSIS DATA SHEET
EPA Sample No.
lab Name: PEL laboratories, Inc. Contract: RAM LEATHER/ 048697.01.03 RAM_ALLEN
Lab Code: _P_E_L ___ _ Case No.: SAS No: ______ SDG No.: _2_50_7_68_2 ____ _
Matrix: WATER --------Lab Sample ID: 250768204 Lab File ID: 6.~8cc20c..4c.c.D~--
Sample wt/vol: 5 Units: C.MCCL,_ ___ _ Date Recei1Jed: _,0"9/"2"9"/0c.7 ____________ _
Concentrated Extract Volume: 5 ---
Level:{low/med) ~L"O'--W __ _
PercentSolids: 0 decanted : {
Extraction: PURGETRAP
GPC Cleanup : ( Y/N)
Column(1): DB-624 ID·. 0.18
CONCENTRATION UNITS: UG/L ___ _
CASNO. ANALYTE
75-71-6 Dichlorodifluoromethane
74-87-3 Chloromethane
75-01-4 Vinyl chloride
74-83-9 Bromomethane
75-00-3 Chloroethane
75-89-4 Trichlorofluoromethane
75-35-4 1, 1-Dlchloroethene
75-15-0 Carbon disulfide
75-09-2 Methylene chloride
156-60-5 trans-1.2-Olchloroethene
75-34-3 1.1-Oichloroethane
67-64-1 Acetone
156-59-2 cis-1,2-Oichloroethene
74-97-5 Bromochloromethane
78-93-3 2-Butanona
67-66-3 Chloroform
71-55-6 1 , 1 , 1-Trlchtoroethane
56-23-5 Carbon tetrachloride
71-43-2 Benzene
107-06-2 1 ,2-0ichloroethane
79-01-6 Trichloroethene
76-67-5 1,2-0ichloropropane
75-27-4 Bromodichloromethane
10061-01-5 cis-1,3-0ichloropropene
108-10-1 4-Methyl-2-pentanone
108-68-3 Toluene
10061-02-6 lrans-1,3-Dichloropropene
Date Extracted:
Date Analyzed: 10/09/07 Time: 1104
Dilution Factor:
Station ID: ________ Method: 821lll
RESULT
10
1
5
5
Form I
2507682
Q
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
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24 I
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I
VOLATILE ORGANIC ANALYSIS DATA SHEET
EPA Sample No.
Lab Name: PEL Laboratones, Inc. Contract: RAM LEATHER I 048697.01 .03 RAM_ALLEN
Lab Code ; :..P.=Ec::L ___ _ Case No.:
Matrix: WATER
Sample wVvol: _,5 ___ Units: _M~L~----
Concentrated Extract Volume: 5 ··-·---·---------·-
Level:(low/med) _L_O_W __ _
PercentSolids: _,o ___ decanted;
Extraction: PURGETRAP
GPC Cleanup : I YIN I
Column(1 ): DB-6~4·-···-
pH:
ID: 0.18
CONCENTRATION UNITS: _,Uc-Ge.IL=-. ___ _
CASNO. ANALYTE
79-00-5 1, 1,2-Trichloroethane
127-18-4 Tetrachloroethene
591-78-6 2-Hexanone
124-48-1 Dibromochloromethane
106-93-4 1,2-0ibromoethane(EDB)
108-90-7 Chlorobenzene
100-41-4 Ethy!benzene
100-42-5 Styrene
75-25-2 Bromoform
98-82-8 lsopropyt'benzene (Cumene)
79-34-5 1, 1 ,2,2-Tetrachloroethane
541-73-1 1,3-Dichlorobenzene
106-46-7 1,4-Dichlorobenzene
95-50-1 1 ,2-Dichlorobenzene
98-12-8 1 ,2-Dibromo-3-chloropropane
120-82-1 1,2,4-Trichlorobenzene
87-61-8 1,2,3-Trichlorobenzene
1330-20-7 Xylene (total)
1634-04-4 MTBE
76-13-1 1, 1,2-Trichtorotrifluoroethane
108-87-2 Methyl Cyclohexane
79-20-9 Methyl Acetate
110-82-7 Cyclohexane
SAS No:
Lab Sampkl ID: 250768204
SDG No.: 25076"8"'2'-----
Lab Fikl ID: 682~0~4-'.D'---
Date Recei-.ed: 0c::91:.,2,c91o,0,_7 ___________ _
Date Extracted:
Date Analyzed: 10/09/07 __ _ Time: 1104 -·----------·------
Dilution Factor:
Station ID: ________ Method: 8Zllll
RESULT
5
1
2
2
1
5
Form I
2507682
Q
u
u
u
u
u
u
u
u
u
u
u
u
u
u
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u
u
u
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u
25
VOLATILE ORGANIC ANALYSIS DATA SHEET
EPA Sample No.
lab Name: PEL laboratories, Inc. Contract: RAM LEATHER/ 048897.01 .03 RAM_FOSTER
Lab Code : .:..P.ccE=.L ___ _ Case No.: SAS No: ______ SOG No.: 2507682
Matrix: _W=A_T.ccE.:..R ____ _ Lab Sample ID: 250768205 Lab File ID: 6~8.:..20~5~.O~--
Sample wt/vol; 5 Units: .:..M.:..L ____ _ Date Received: .:..0.:..9_/2.:..9.:../0.:..7 ____________ _
Concentrated Extract Volume: 5 Date Extracted:
LeveJ:(low/med) _LO_W __ _ Date Analyzed: 10109107 Time: 1041 .. --•··-· ····--·-----PercentSolids: 0 decanted : ( ____ _ Dilution Factor:
Extraction: PURGETRAP
GPC Cleanup: ( YIN )
Column(1 ): 08-624
pH:
ID: 0.18
CONCENTRATION UNITS: .ccUccGc,/L'-----
CASNO. ANALYTE
75-71-8 Oichlorodifluoromethane
74-87-3 Chlo re methane
75-01-4 Vinyl chloride
74-83-9 Bro mo methane
75-00-3 Chloroethane
75-89-4 Trichlorofluoromethane
75-35-4 1 , 1-Dichloroethene
75-15-0 Carbon disulfide
75-09-2 Methylene chloride
156-60-5 trans-1,2-Dichloroethene
75-34-3 1, 1-0lchtoroethane
67-64-1 Acetone
156-59-2 cis-1,2-Dlchloroethene
74-97-5 Bromochloromethane
78-93-3 2-Butanone
67-66-3 Chloroform
71-55-6 1,1,1-Trichloroethane
56-23-5 Carbon tetrachloride
71-43-2 Benzene
107-06-2 1,2-0ichloroethane
79-01-6 Trichtoroelhene
78-87-5 1 ,2-0ichloropropane
75-27-4 Bromodichloromethane
10061-01-5 cis-1,3-Dichforopropene
108-10-1 4-Methyl-2.pentanone
108-88-3 Toluene
10061-02-8 trans-1,3-Dichtoropropene
Station to: ________ Method: 6Zllll
RESULT Q
10
1
1
5
1
1
5
Form I
2507682
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
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u
u
u
u
u
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26 I
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VOLATILE ORGANIC ANALYSIS DATA SHEET
EPA Sample No.
Lab Name: PEL laboratones, Inc. Contract: RAM LEATHER I 048697.01 .03 RAM_FOSTER
Lab Code : _P~E~L ___ _ Case No.:
Matrix: WATER
Sample wt/vol: _5 ___ Units: _M_L ____ _
Concentrated Extract Volume: 5
Level:(low/med) -'L"O"W-'----
PercentSolids: -'o~ __ decanted: ( ____ _
Extraction: PURGETRAP
Column( 1 ): DB-624-'-----10: 0.18
CONCENTRATION UNITS: -'U-'G~IL:_ ___ _
CASNO. ANALYTE
79-00-5 1 , 1,2-Trichloroethane
127-18-4 Tetrechloroethene
591-78-6 2-Hexanone
124-48-1 Oibromochloromethane
106-93-4 1,2-Dibromoethane(EOB)
108-90-7 Chlorobenzene
100-41-4 Ethylbenzene
100-42-5 Styrene
75-25-2 Bromoform
98-62-6 lsopropylbenzene (Cumene)
79-34-5 1, 1,2,2-Tetrachloroethane
541-73-1 1,3-Dichlorobenzene
108-46-7 1 ,4-0ichlorobenzene
95-50-1 1,2-Dich!orobenzene
96-12-8 1,2-Dibromo-J-chloropropane
120-62-1 1,2,4-Trichlorobenzene
87-61-6 1,2,J-Trichlorobenzene
1330-20-7 Xylene (to1al)
1634-04-4 MTBE
76-13-1 1, 1,2-Trichlorotrifluoroethane
108-67-2 Methy1 Cyclohexane
79-20-9 Methyl Acetate
110-82-7 Cyclohexane
SAS No: SDG No.: ~2:.:5=.07c:B:.:8c_2 ____ _
Lab Sample ID: 250768205 Lab Fi" 10: 6820:::5:::.D:_ __
Date Received: _Q~J.~2:.:91:.:0c:_7 ____________ _
Date Extracted:
Date Analyzed: .1.0/99107 _ ·-·-···-·-·-·· Time: 1041
Dilution Factor:
Station ID: _______ Method: 82eO
RESULT
1
5
1
2
1
1
2
1
5
Form I
2507682
Q
u
u
u
u
u
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27
VOLATILE ORGANIC ANALYSIS DATA SHEET
EPA Sample No.
Lab Name: PEL Laboratories, Inc. Contract RAM LEATHER/ 048697.01.03 RAM_ESTEP
Lab Code : PEL ~~---Case No.: SAS No: -----,--SDG No.: 25076~8~2'------
Matrix: WATER -~-----Lab Sample ID: 250768206 Lab File ID: 68208.D
Sample wt/vol: 5 Units: _M_L ____ _ Date Received: ~0_9_12_9_10_7 ____________ _
Concentrated Extract Volume: 5 ------
Level:{low/med) _L_O_W __ _
PercentSolids: 0 decanted : ( ____ _
Extraction: PURGETRAP
GPC Cleanup ; ( YIN ) pH:
Column(1): DB-624 ID: 0.18
CONCENTRATION UNITS: UG/L ='------
CASNO. ANALYTE
75-71-8 Dichlorodifluoromethane
74-87-3 Chloromethane
75-01-4 Vinyl chloride
74-83-9 Bromomethane
75-00-3 Chloroelhane
75-89-4 Trichlorofluoromethane
75-35-4 1 , 1-Oichloroethene
75-15-0 Carbon disulfide
75-09-2 Methylene chloride
156-60-5 trans-1 .2-Dichloroethene
75-34-3 1 , 1-O!chloroethane
67-64-1 Acetone
156-59-2 cis-1,2-Dichloroethene
74-97-5 Bromochloromethane
7S-93-3 2-Butanone
67-66-3 Chloroform
71-55-8 1,1,1-Trichloroethane
56-23-5 Carbon tetrachloride
71-43-2 Benzene
107-06-2 1 ,2-Oichloroethane
79-01-8 Trichloroethene
76-87-5 1,2-Oichloropropane
75-27-4 Bromodichloromethane
10061-01-5 cis-1,J-Oichloropropene
108-10-1 4-Methyl-2--pentanone
106-88-3 Toluene
10061-02-8 trans-1,3-Oichloropropene
Date Extracted: ··------·-------------------··---·-•·-•-·-
Date Analyzed; __ !9!_0J!Q.7__ --·-----· Time: .-9.~?} __ -~-~-----·--·-
Dilution Factor:
Station ID: ________ Method: 82§0
RESULT
10
1
1
5
1
5
Form I
2507682
Q
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
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28 I
11
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VOLATILE ORGANIC ANALYSIS DATA SHEET
EPA Sample No.
Lab Name: PEL Laboratories, Inc. Conlract: RAM LEATHER I 048697.01.03 RAM_ESTEP
Lab Code: P-=E~L ___ _ Case No.:
Matrix: WATER
Sample wt/vol: __,5:.,_ __ Units: .::M:::L:_ ___ _
Concentrated Extract Volume: 5
Level:(low/med) __,Lc::Oc.W'---
PercentSollds: ~□ ___ decanted:( ____ _
Extraction: PURGETRAP
GPC Cleanup : ( YIN)
Column( 1 ): DB-624 ID: 0.18
CONCENTRATION UNITS: -=U-=G-=IL~----
CAS 110. AIIALYTE
79-00-5 1, 1,2-Trichloroethane
127-18-4 T etrach1oroethene
591-78-6 2-Hexanone
124-48-1 Oibromochloromethane
108-93-4 1,2-0ibromoethane(EDB)
108-90-7 Chlorobenzene
100-41-4 Ethyl benzene
100-42-5 Styrene
75-25-2 Bromoform
98-82-6 lsopropylbenzene (Cumene)
79-34-5 • 1, 1 ,2,2-Tetrachloroethane
541-73-1 1,3-0ichtorobenzene
108-48-7 1,4-0ichlorobenzene
95-50-1 1 ,2-Dichlorobenzene
96-12-6 1 ,2-0ibromo-3~hloropropane
120-82-1 1,2,4-Trichlorobenzene
87-61-6 1,2,3-Trichtorobenzene
1330-20-7 X~ene (total)
1634-04-4 MTBE
76-13-1 1, 1,2-Trichlorotrifluoroethane
108-87-2 Methy1 Cyelohexane
79-20-9 Methy1 Acetate
110-82-7 Cyctohexane
SAS No: SDG No.: 2507682
Lab Sample ID: 250768206 Lab F;le ID: 68206.D
Date Received: "0"9/"2"9lc.,,0.:..7 ____________ _
Date Extracted:
Dale Analyzed: 1 0109107 Time: 0953 ·--·---·----· ------. -----
Oitutlon Factor:
Station ID: ________ .Method: 8250
RESULT
1
5
1
2
1
2
1
5
Form I
2507682
Q
u
u
u
u
u
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29
VOLATILE ORGANIC ANALYSIS DATA SHEET
EPA Sample No.
Lab Name: PEL laboratories. Inc. Contract: RAM LEATHERl048697.01.03 RAM_SEGREST ----
Lab Code : PEL ------Case No.: SAS No: _____ SDG No.: _2_50_7_6_82 ____ _
Matrix: 0Wcc..;A-'-T"'E'-'R ____ _ Lab Sample ID: 250768207 Lab F;le ID: 68207.D
Sample wt/vol: -'5~--Units: 0M~L~----Date Received: -'0~91'-'2~9'-'10~7 ____________ _
Concentrated Extract Volume: 5 Date Extracted:
Level:(low/med) _L~O_W __ _ Date Analyzed: 1 0/09/07 Time: 1611
PercentSolids: 0 decanted : ( ____ _ Dilution Factor:
Extraction: PURGETRAP
GPC Cleanup : ( YIN ) ---·-pH:
Column(1): .. 9.~:li2~---------.. --ID: 0.18
CONCENTRATION UNITS: UGIL ------
CASNO. ANALYTE
75-71-!I Oichloroddluoromethane
74-87-3 Chloromethane
75-01-4 Vinyl chloride
74-83-9 Bromomethane
75-00-3 Chloroethane
75-89-4 Trichlorofluoromethane
75-35-4 1, 1-Dichloroethene
75-15-0 Carbon disulfide
75-09-2 Methylene chloride
156~0-5 trans-1,2-Dichforoethene
75-34-3 1, 1-Dichloroethane
67~4-1 Acetone
158-59-2 cis-1 ,2-Dichloroethene
74-97.5 Bromochloromethane
78-93-3 2-Butanone
6H6-3 Chloroform
71-55~ 1, 1, 1-Trichloroethane
56-23-5 Carbon tetrachloride
71-43-2 Benzene
107-06-2 1,2-Dichloroethane
79-01~ Trichloroethene
78-87-5 1,2-Dlchloropropane
75-27-4 Bromodichloromethane
10061-01-5 cis-1,3-Dichloropropene
108-10-1 4-Methyt.-2-pentanone
108-SS-3 Toluene
10061-02~ trans-1,3-Dichloropropene
""'"""
Station ID; ________ Method: 8260
_Jr11m)_
RESULT Q
1
10
6.8
1
5
6.4
1
5
Form I
2507682
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
I
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I
I
I
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I
30 I
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I
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I
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I
VOLATILE ORGANIC ANALYSIS DATA SHEET
lab Name: PEL Laboratories, Inc.
Lab Code: PEL Case No.:
Matri)(: WATER
Sample wt/vol: 5 Units: ML
Concentrated Extract Volume: 5
Level:(low/med) LOW
PercentSolids: 0 decanted :(
Extraction: PURGETRAP
___ pH:
Contract: RAM LEATHER/ 048697.01 .03
SAS No:
Lab Semp" 10: 250768207
Date Received: 09129107
Date Extracted:
Date Analyzed: 10/09107 . ·····-··-·-·---
Dilution Factor:
EPA Sample No.
RAM_SEGREST
SOG No.: ~2~50~7~6~82~----
Lab File 10: 68207.D
Time: 1611
Station 10: ________ Method: 82!lil
GPC Cleanup : ( YIN)
Column( 1 ): DB-824 ID: 0.18 _(nim).
CONCENTRATION UNITS: UG~/L~----
CASNO. ANALYTE
79-00-5 1, 1,2-Trichloroethane
127-18-4 Tetrachloroethene
591-78-8 2-Hexanone
124-48-1 Dibromochloromethane
108-93-4 1 ,2-0ibromoethane(EDB)
108-90-7 Chlorobenzene
100-41-4 Ethylbenzene
100-42-5 Styrene
75-25-2 Bromoform
98-82-8 lsopropylbenzene (Cumene)
79-34-5 1, 1 ,2,2-T etrachloroethane
541-73-1 1,3-DichJorobenzene
108-48-7 1,4-0ichlorobenzene
95-50-1 1 ,2-0ichlorobenzene
96-12-8 1 ,2-0ibromo-J..chloropropane
120-82-1 1,2,4-Trichtorobenzene
87-81-8 1,2,3-Trichlorobenzene
1330-20-7 Xylene {total)
1634-04-4 MTBE
78-13-1 1, 1 ,2• Trichlorotrifluoroethane
108-87-2 Methyl Cyclohexane
79-20-9 Methyl Acetate
110-82-7 Cydohexane
RESULT
101
5
1
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1
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2
1
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Form I
2507682
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31
VOLATILE ORGANIC ANALYSIS DATA SHEET
EPA Sample No.
Lab Name: PEL Laboratories, Inc. Contract: RAM LEATHER/ 048697.01 .03 RAM_SEGRESTDL 1
Lab Code : _P_E_L ___ _ Case No.: SAS No: SDG No.: 2507682 --------
Matrix: WATER Lab Sample ID: 250766207DL 1 Lab File ID: 68207DR.D --------
Sam p I e wt/vot 5 Units: ~M~L,_ ___ _ Date Received: _,0"'9_,/2"'9'-'/0c.7 ____________ _
Concentrated Extrad Volume: 5
le\lel:(low/med) ..,L..,Oc.W~--
PercentSoUds: O decanted : ( ____ _
Extraction: PURGETRAP
GPC Cleanup : ( YIN )
Column(1): DB-624 ID: 0.18
CONCENTRA T/ON UNITS: ~U..,G~/L~----
CASNO. ANALYTE
75-71-6 Oichlorodifluoromethane
74-67-3 Chloromethane
75-01-4 Vinyl chloride
74-83-9 Bromomethane
75-00-3 Chloroethane
75-89-4 Trichlorofluoromethane
75-35-4 1 , 1-0lchloroethene
75-15-0 Carbon disulfide
75-09-2 Methyiene chloride
156-60-5 . trans-1,2-Dichloroethene
75-34-3 1 ,1-Dlchloroethane
87-64-1 Acetone
156-59-2 cis-1 ,2-Dichloroethene
74-97-5 Bromochloromethane
78-93-3 2-Butanone
67-66-3 Chloroform
71-55-6 1 , 1 .1-Trichloroethane
58-23-5 Carbon tetrachloride
71-43-2 Benzene
107-06-2 1 ,2-0ichloroethane
79-01-6 Trichloroethene
78-87-5 1,2-0ichloropropane
75-27-4 Bromodichloromethane
10061-01-5 cis-1,3-0/chloropropene
108-10-1 4-Methyi--2-pentanone ·
108-86-3 Toluene
10061-02-6 trans-1,3-0ichJoropropene
.,,,.,, ,,..,.
Date Extracted:
DateAnalyzed: J_Q~q~!Q!.. __ ... Time: 1017
Dilution Factor: 5
Station 10; ________ Method: 8260
RESULT Q
5 u
5 u
5 u
5 u
5 u
5 u
5 u
5 u
5 u
5 u
5 u
50 u
8.8
5 u
25 u
5 u
5 u
5 u
5 u
5 u
8.3
5 u
5 u
5 u
25 u
5 u
5 u
Form I
2507682
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VOLATILE ORGANIC ANALYSIS DATA SHEET
EPA Sample No.
Lab Name: PEL Laboratories, Inc. ----·-· Contract: RAM LEATHER/ 048697.01 .03 RAM_SEGRESTDL 1 I
Lab Code : -'-P"'E~L ___ _ Case No.: SAS No: SDG No.: _2~50_7~6~82 ____ _
Matrix: WATE~R ____ _ Lab Sample ID: 250768207DL1 Lab File ID: 68207DR.D
Sample wt/vol: _5 ___ Units: _M_L ____ _ Date Received: 09/29/07 ---------------
Concentrated Extract Volume: 5 Date Extracted:
Level:(low/med) -~Q_~--Time: 1017 -· ---··-·---·--Date Analyzed: 10/09/0'-7~--
PercentSolids: _o _____ decanted:( __ _ Oilution Factor: 5
Extraction; PURGETRAP Station 10: ________ Method: 82110
GPC Cleanup : ( YIN) pH:
Column(1 ): .IJ~.13.4..__________ ID: 0.18
CONCENTRATION UNITS: UG/L ~----
CASNO. ANALYTE RESULT Q
79-00-5 1, 1 ,2-Trichloroethane 5 u
127-18-4 Tetrachloroethene 99.2
591-78-ll 2-Hexanone 25 u
124-48-1 Dibromoch1oromethane 5 u
108-93-4 1,2-Dibromoethane(EDB) 5 u
108-90-7 Chlorobenzene 5 u
100-41-4 Ethylbenzene 5 u
100-42-5 Styrene 5 u
75-25-2 Bromoform 5 u
98-82-ll lsopropylbenzene (Cumene) 5 u
79-34-5 1, 1,2,2-Tetrachloroethane 5 u
541-73-1 1 ,3-Dichlorobenzene 5 u
108-46-7 1,4-0ichlorobenzene 5 u
95-50-1 1,2-Dichlorobenzene 5 u
96-12-ll 1,2-0ibromo-3-chloropropane 10 u
120-82-1 1,2,4-Trichlorobenzene 5 u
87-<11-ll 1,2,3-Trichtorobenzene 5 u
1330-20-7 Xytene (total) 10 u
1634-04-4 MTBE 5 u
76-13-1 1, 1,2-Trichlorotrifluoroethane 5 u
108-87-2 Methyt Cyclohexane 5 u
79-20-9 Methyl Acetate 25 u
110-82-7 Cydohexane 5 u
Form I
2507682 33
VOLATILE ORGANIC ANALYSIS DATA SHEET
EPA Sample No.
lab Name: PEL Laboratories. Inc. Contract: RAM LEATHER I 048697.01.03 TRIP BLANK
Lab Code : PEL ------Case No.: SAS No: _____ SDG No.: 25_0_76_82 ____ _
Matrix: WATER lab Sample ID: 250768210 Lab m, ID: 68210.D --------
Sam p I e wt/vol: _5 ____ Units: 0M"'L'------Date Received: -'0"'9-'12"'9-'/0c.7 ____________ _
Concentrated Extract Volume: 5'--------
Level:(low/med) LOW
PercentSolids: O decanted: -----
Extraction: PURGETRAP
GPC Cleanup: ( YIN) pH:
Column(l ): .fl.~2~----···--ID: 0.18
CONCENTRATION UNITS: UGIL ____ _
CASNO. ANALYTE
75-71-8 Oichlorodifluoromethane
74-87-3 Chloromethane
75-01-4 Vinyl chloride
74-83-9 Bro mom ethane
75-00-3 Chloroethane
75-89-4 Trichlorofluoromethane
75-35-4 1, 1-0lchtoroethene
75-15--0 Carbon disutflde
75-09-2 Methylene chloride
156-80-5 trans• 1,2-0ichloroethene
75-34-3 1, 1-0ichloroethane
67-84-1 Acetone
156-59-2 cis-1 ,2-0ichloroethene
74-97-5 Bromochloromethane
78-93-3 2-Butanone
67-86-3 Chloroform
71-55-8 1, 1,1-Trichloroethane
56-23-5 Carbon tetrachloride
71-43-2 Benzene
107-08-2 1 ,2-Dichloroethane
79-01-8 Trichloroethane
78-87-5 1,2-0/chloropropane
75-27-4 Bromodichloromethane
10061--01-5 cis-1,3-0ichloropropene
108-10-1 4-Methyl-2-pentanone
108-88-3 Toluene
10081-02-8 trans-1,3-Dichloropropene
Date Extracted:
Date Analyzed: 10/09/07 --·-____ Time: 0930 --·---------·----·------
Dilution Factor:
Station ID: ________ Method: a.:ltiO
RESULT
1
10
1
5
1
5
Form I
2507682
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VOLATILE ORGANIC ANALYSIS DATA SHEET
EPA Sample No.
Lab Name: PEL Laboratories, Inc. Contract: RAM LEATHER I 048697.01 .03 TRIP BLANK
Lab Code : PEL ------Case No.: SAS No: ______ SDG No.: ~2~5~07"6~8"'2 ____ _
Matrix: "W"A"T"E~R~----Lab Sample ID: 250768210 Lab File ID: 68210.D
Sample wt/Vol: ~5 ___ Units: _M~L~----Date Received: _0~9_12~9_10~7 ____________ _
Concentrated Extract Volume: 5 Date Extracted:
Level:(low/med) L_O_W __ _ Date Analyzed: 10/09107 Time: 0930
PercentSolids: 0 decanted:( ____ _ DIiution Factor:
Extraction: PURGETRAP Station ID: _______ Method: S250
GPC Cleanup : ( YIN) ---·-pH:
Column(1): DB-624 ID: 0.18 (mm) __
CONCENTRA T/ON UNITS: UGIL -------
CASNO. ANALYTE
7~0-5 1, 1,2-Trichloroethane
127-18-4 Tetrachloroethene
591-78-6 2-Hexanone
124-48-1 Dlbromochloromethane
106-93-4 1,2-Dlb~omoethane(EDB)
108-90-7 Chlorobenzene
100-41-4 Ethylbenzene
100-42•5 Styrene
75-25-2 Bromoform
98-62-6 lsopropylbenzene (Cumene)
79-34-5 t, 1,2,2-Tetrachloroethane
541-73-1 1,3-Dichlorobenzene
106-46•7 1 ,4-Dichlorobenzene
95-50-1 1,2-Dichlorobenzene
96-12-6 1 ,2-Dibromo-3-chloropropane
120-82-1 1,2,4-Trich!orobenzene
87-61-6 1,2,3-Trichforobenzene
1330-20•7 Xylene {total)
1634-04-4 MTBE
76-13-1 1, 1,2-Trichlorotrifluoroethane
108-87-2 Methyl Cyclohexane
79-20·9 Methyl Acetate
110-82•7 Cydohexane
RESULT
1
5
1
2
2
1
5
Form I
2507682
Q
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AppendixE I
Support Documentation I
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VOLATILE ORGANIC MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERY
EPA Sample No.
Lab Name: PEL Laboratories, Inc. Contract: RAM LEATHER/ 0 RAM_SEGRESTSDDL1
Lab Code : PEL Case No.: SAS No:
SPIKE MSD
ADDED CONCENTRATION
COMPOUND UG/L UG/L
Dichlorodifluoromethane 100 82.7
Chloromethane . 100 93.4
Vinyl chloride 100 67.2
Bromomethane 100 79.2
Chloroethane 100 97.8
Trichlorofluoromethane 100 81.7
1 , 1-Dlchloroethene 100 101
Carbon disulflde 100 99.8
Methylene chloride 100 00.8
trans-1,2-Dlchloroethene 100 95
1 , 1-Dichloroethane 100 102
Acetone 300 244
cis-1,2-0ichloroethene 100 111
Bromochloromethane 100 100
2-Butanone 300 268
Chloroform 100 104
1, 1, 1-Trichloroethane 100 97.6
Carbon tetrachloride 100 90.6
Benzene 100 98.9
1 ,2-0ichloroethane 100 102,
Trichloroethane 100 105
1,2-Dichloropropane 100 97.2
Bromodichloromethane 100 94.3
cis-1,3-Dlchloropropene 100 86.1
4-Methyl-2-pentanone 300 275
Toluene 100 00.4
lrans-1,3-Dlchtoropropene 100 83.6
1, 1,2-Trichloroethane 100 93.5
Tetrachloroethene 100 186
2-He)(anone 300 277
# Column to be used to flag recovery values with an asterisk
• Values outside QC limits
Control limit source: (Jab/method)
COMMENTS:
METHOD
Form Ill
2507682
SDG No.: _2~5_07_6~8~2 ___ _
MSD
% % QC LIMITS
REC# RPO# RPO REC.
82.7 16.9 . 13 72-127
93.4 16.3 19 75 -111
67.2 20.4 . 15 78-110
79.2* 11.4 20 83-120
97.8 9.9 16 65-121
61.7° 18.9 20 88-119
101.0 6.7 17 69-113
99.6 6.0 16 67-124
00.8 4.5 20 88-113
95.0 9.0 13 85-113
102.0 3.8 16 91·110
81.3 2.1 17 78-133
104.0 5.3 13 89-117
100.0 4.9 13 86 -107
89.3 4.7 20 75-113
104.0 3.8 10 89-114
97.8 8.3 19 86-114
90.6 9'.9 16 85-125
98.9 5.0 7 92-110
102.0 1.9 11 88 -113
98.7 5.6 16 78-119
97.2 5.8 10 92-109
94.3 5.5 11 83 • 114
86.1 5.5 14 79. 109
91.7 4.3 8 67-113
00.4 5.6 13 89-121
83.6 3.1 8 70-108
93.5 2.0 13 89 • 116
86.8· 6.8 12 68-115
92.3 3.2 7 65-118
48
J
VOLATILE ORGANIC MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERY
EPA Sample No.
Lab Name: PEL Laboratories, Inc. Contract: RAM LEATHER I 0 RAM_SEGRESTSDDL 1
Lab Code : PEL Case No.: SASNo: ---
SPIKE MSD
ADDED CONCENTRATION
COMPOUND UG/L
Dlbromochloromethane 100
1,2-0ibromoethane(EDB) 100
Chlorobenzene 100
Ethylbenzene 100
Styrene 100
Bromoform 100
lsopropylbenzene (Cumene) 100
1.1,2,2-Tetrachloroethane 100
1 ,3-Dichlorobenzene 100
1,4-0lchlorobenzene 100
1 ,2-0ichlorobenzene 100
1 ,2-0ibromo-3~hloropropane 100
1,2,4-Trichlorobenzene 100
1,2,3-Trlchlorobenzene 100
Xylene (total) 300
MTBE 100
1,1,2-Trlchlorotrifluoroethane 100
Meth;i Cyclohexane 100
Methyl Acetate 100
Cyclohexane 100
RPO: 8 outof 50 outside Hmrts
Spike Recovery: 6 outof 50 outside limits
# Column to be used to flag recovery values with an asterisk
• Values outside QC limits
Control limit source: (lab/method)
COMMENTS:
METHOD
UG/L
87.6
93.2
90.6
94.6
92.6
72.8
93
91.6
95.1
95.3
94.2
90.2
96.6
96.1
282
89.3
90
97.5
106
97.1
Form Ill
2507682
SDG No.: 2507682 --------
MSD
% % QC LIMITS
REC# RPO# RPO REC.
87.6 5.9 11 78-114
93.2 4.7 14 90-109/
90.6 10.9 . 7 35-148
94.6 8.3 14 93-111
92.8* 9.7 . 7 93. 111
72.8 8.7 14 57-117
93.0 10.2 12 91 -107
91.6 4.8 11 85-100
95.1 8.9 14 84-112
95.3 8.7 11 56-132
94.2 8.0 8 87-110
90.2 5.8 20 79-109
96.6 6.4 16 87 • 107
98.1 9.6 12 83-105
94.0 9.5 . 9 90-111
89.3· 13.3 . 11 90-111
90.0 17.3 20 84-122
97.5 12.0 . 9 80 -118
106.0 • 10.8 . 10 81 -105
97.1 6.9 11 84-119
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ENERGY WATER INFORMATION GOVERNMENT
Date:
Subject:
From:
To:
October 25, 2007
Organic Data Validation for SDG 2507692
Ram Leather Site
Suzanne Prouty, Validator
Environmental Scientist
Georgia Office
Nancy Gel!ar
Black & Veatch Special Projects
Project Manager
Gina Montgomery, Oversight Reviewer
Lead Scientist, Georgia Office
Black & Veatch Special Projects Corp.· 1120 Sanctuary Parkway· Suite 200 • Alpharetta, GA 30004 USA• Telephone: [phone] • Fax: [phone]
I. OVERVIEW
This report presents the results of the Region IV data validation for samples collected at
the Ram Leather Site. PEL Laboratories, Inc. analyzed 3 water samples, I matrix
spike/matrix spike duplicate (MS/MSO) and I trip blank under SDG 2507692. The water
samples and trip blank were analyzed for volatile organics (SW-846 Method 8260).
The samples were assessed based on the data review criteria specified in the United
States Environmental Protection Agency Region 4 National Functional Guidelines for
Organic Data Review, June 2001.
II. SUMMARY
III.
IV.
All samples were successfully analyzed. No data were rejected.
MAJOR PROBLEMS
No major problems were noted.
MINOR PROBLEMS
Volatile Organic Compounds
• The preservation and holding times were acceptable.
• The Method Blank results were acceptable. No contaminants were
present.
• The performance of the Oeuterated Monitoring Compounds (DMCs) was
· acceptable.
• The surrogate percent recoveries were acceptable for all compounds.
• The matrix spike had unacceptable percent recoveries (¾R) for isopropyl
benzene (cumene), 1,2,3-trichlorobenzene, and tert-butyl methyl ether
(MTBE). The matrix spike duplicate had unacceptable ¾R for MTBE.
The matrix spike duplicate had unacceptable relative percent difference
(RPO) for benzene, bromodichloromethane, 4-methyl-2-pentanone,
trans-1,3-dichloropropene, 2-hex·anone, dibromochloromethane,
chlorobenzene, styrene, isopropylbenzene (cumene), I ,4-
dichlorobenzene, 1,2-dichlorobenzene, and xylene. The compounds with
deficiencies did not have unacceptable results for any other QC
parameters; therefore, no validation was required for the samples
associated with this data package.
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• The initial calibrations had acceptable relative response factors (RRFs)
and percent relative standard deviation (¾RSD) for all compounds.
• The secondary source calibration had acceptable percent difference for
all compounds.
• The continuing calibration had acceptable percent difference and RRFs
for all compounds.
• The data set did not include a performance evaluation sample.
• The instrument performance check (!PC) was acceptable.
• The internal standards were acceptable for all compounds.
V. NOTES
Tentatively Identified Compounds (T!Cs) were not provided in the data package;
therefore, this information has not been evaluated.
VI. REPORT CONTENT STATEMENT
This validation has been validated in accordance with the United States
Environmental Protection Agency Region 4 National Functional Guidelines for
organic Data Review, June 2001. The content of this report addresses reasons for
qualifiers and questions which might affect data usability.
VII. ATTACHMENTS
Appendix A -Glossary of Data Qualifiers
Appendix B -Table I -Summary of Analytes Failing Criteria
Appendix C -Sample Results Based On Data Validation
Appendix D -Sample Results as Reported by the Laboratory
Appendix E -Support Documentation
Calculations
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1 1 LC~
I ·JR-=-\C\.?. *100 ::: q~-;. -✓
d,i. e,\,IOl'od; f lucro~ '2 D
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I I •/ R -(o\.S x 100-= tD2'/ ✓
~(.1.-1,, 'iv-' -(o O. O '
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Pe.L St>6 15Dlto9Z.
){/00 =
21
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Organic Review Summary
APPENDIX B:
ORGANIC DATA REVIEW SUMMARY
CASE NO. __________ SITE -~R=a=m~Le=a=th~e~r ________ _
LABORATORY PEL Laboratories NO. OF SAMPLES/MA TRIX 3 water I TB I MS/MSD
SDG NO. 2507692 SOW NO. ______ _ REGION~l~V __ _
REVIEWER NAME "'S.,,,uz.,a"'-nn,_,_,e'--'P~r-"-ou,,,ty.,__ ____ COMPLETION DA TE I 0/25/2007
CLP PO: ACTION _________ FYI _____ _
REVIEW CRITERIA FRACTION
VOA BNA PEST/PCB
I. PRESERVATION 0
2. GC/MS OR GC/ECD INSTRUMENT
PERFORMANCE CHECK 0
3. INITIAL CALIBRATION 0
4. CONTINUING CALIBRATION OR
CALIBRATION VERIFICATION 0
5. BLANKS 0
6. DEUTERATED MONITORING COMPOUND
SURROGATE SPIKES 0
7. MA TRIX SPIKES/MA TRIX SPIKE
UPLICATES X
8. LABORATORY CONTROL SAMPLE •': ' ... " ., .·.!' t,,:_'., h,;' -,
•r'r .-:'_; '";:.·· ;-~•:'.'I ~". : ·'· ..
9. REGIONAL QA/QC 0
10. INTERNAL STANDARDS 0 . ' ..
-~, .. . . " 11. FLORISIL CARTRIDE PERFORMANCE : -< .. ' . _; . --~; . ' ,'1:,"
.,'-·-'.· : .... :_·;·::;,(,\ CHECK . ~ ..... ': -~ ~,, ;, ' . ' ,.
12. TARGET COMPOUND IDENTIFICATION 0
13. COMPOUND QUANTIT A TION AND
REPORTED CRQLS 0
14. COMPOUND QUANTIT ATION
AND REPORTED CRQLS 0
15. TENTATIVELY IDENTIFED COMPOUNDS X ' . ,, ¥ . -... -16. SYSTEM PERFORMANCE 0 . • ,, J, -., . .•,.: . : ' ~ ~-
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· AppendixA
Glossary of Data Qualifiers
DATA QUALIFIER DEFINITIONS
The following definitions provide brief explanations of the national qualifiers assigned to results in the data review process. If the Regions choose to use additional qualifiers, a complete explanation of those qualifiers should accompany the data review.
u The analyte was analyzed for, but was not detected above the level of the reported sample quantitation limit.
] The result is an estimated quantity. The associated numerical value is the approximate concentration of the analyte in the sample.
]+ The result is an estimated quantity, but the result may be biased high.
]-The result is an estimated quantity, but the result may be biased low.
R The data are unusable. The sample results are rejected due to serious deficiencies in meeting Quality Control (QC) criteria. The analyte may or may not be present in the sample.
UJ The analyte was analyzed for, but was not detected. The reported quantitation limit is approximate and may be inaccurate or imprecise.
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Appendix B
Table I -Summary of Analytes Failing Criteria
QCP~uiremeAf I .
Aa.alyta Failing Criteria & Criteria 7 I
I
Table I
Summary of Analytell Failing Criteria
Ram Leather Site
SDG 2507692
Ao•hmraJ
Motbod
T Result I ' Fl~ I
No sample results were qualified for this sample deliveiy group.
-----
Resuh F1a,: Annlied To
(S--iftc Ao•Ma In)
--

-
----
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I I Appendix C
I I I
I Samples Results Qualified Based On Data Validation
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-No data was qualified based on the data validation.
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Appendix D
Results as Reported by the Laboratory
VOLATILE ORGANIC ANALYSIS DATA SHEET
EPA Sample No.
Lab Name: PEL Laboratories, Inc. Contract; Ram leather 048697.01 .03 RAM_MW01
Lab Code : _P~E=L ___ _ Case No. SAS No: ______ SDG No.: -'2=5.c.07'-'6=9.c.2 ____ _
Matrix: _;Wc:.Ac:.T;.;E:::R-'-------Lab Sample tD: 250769201 Lab File ID: 69201.D
Sample wt/vol: 5 Units: _M_L ____ _ Date Received: _1c,Olc,0:,,21,.:0c:.7 ___________ _
Concentrated Extract Volume: 05:__ ____ _ Date Extracted:
Level:{low/med) -'L=Oc..cW.c._ __ Date Analyzed: __ 1Q!.~_Q{9.Z._,_______ Time: -'2=2=58~---
Pen::entSolids: 0 decanted : ----0ilution Factor:
Extraction: PURGETRAP Station ID: ________ Method: =
pH: GPC Cleanup ; ( Y /N )
Column(l ): DB-624 to: 0.18 (rnrni_
CONCENTRATION UNITS: U=G~/L'----
CASNO. ANALYTE
75-71-8 Dichlorodlfluoromethane
74-87-3 Chloromethane
75-01-4 Vinyl chloride
74-83-9 Bro mom ethane
75-00-3 Chloroethane
75-89-4 Trichlorofluoromethane
75-35-4 1 , 1-0ichloroethene
75-15-0 Carbon disulfide
75-09-2 Methylene chloride
158-80-5 trans-1,2-0lchloroethene
75-34-3 1, 1-Dichloroethane
67-84-1 Acetone
158-59-2 cis-1,2-Dlchloroethene
74-97.5 Bromochloromethane
78-93-3 2-Butanone
67-86-3 Chloroform
71-55-8 1, 1, 1-Trichloroethane
56-23-5 Carbon tetrachloride
71-43-2 Benzene
107-06-2 1 ,2-Dichloroethane
79-01-8 Trichloroelhene
78-87-5 1 ,2-Dichloropropane
75-27-4 Bromodichloromethane
10061-01-5 cis-1,3-Dichloropropene
108-10-1 4-Methyi-2-pentanone
108-88-3 Toluene
10061-02-8 trans-1,3-0ichloropropene
,, .. .,, .. .,
RESULT
10
1
5
1
5
Form I
2507692
Q
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11 I
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D
ffl
VOLATILE ORGANIC ANALYSIS DATA SHEET
Lab Name: PEL Laboratories, Inc. Contract:
Lab Code : _.:P_:Ec:L ___ _ Case No.
Matrix: "W=A-'-T=E:..:Rc_ ___ _
Sample wt/vol: 05,.._ __
Concentrated Extract Volume:
Units: 0M"L'------
5
Level:(low/med) LOW
PercentSollds: O decanted : -----
Extraction: PURGETRAP
pH: GPC Cleanup: ( YIN)
Column( 1 ): D8-624
~----·····-···---
ID: 0.18 (mm)
CONCENTRATION UNITS: "U:.,G::cl=-L ___ _
CASNO. ANALYTE
79-00-5 1.1,2-Trichtoroethane
127-18-4 Tetrachloroethene
591-78-6 2-Hexanone
124-48-1 Dibromochloromethane
108-93-4 1,2-Dibromoethane(EOB)
108-90-7 Chlorobenzene
100-41-4 Ethylbenzene
100-42-5 Styrene
75-25-2 Bromofonn
98-62-8 lsopropylbenzene (Cumene)
79-34-5 1, 1,2,2-Tetrachloroethane
541-73-1 1,3-Dichlorobenzene
108-48-7 1,4-Dichlorobenzene
95-50-1 1,2-Dichlorobenzene
96-12-8 1,2-Dlbromo-3-chloropropane
120-82-1 1,2,4-Trichlorobenzene
87-81-6 1,2,3-Trichlorobenzene
1330-20•7 X~ene (total)
1634-04-4 MTBE
76-13-1 1, 1,2-Trlchlorotrifluoroethane
108-67-2 Methyt Cyclohexane
79-20-9 Methyl Acetate
110-62-7 Cydohexane
EPA Sample No.
Ram Leather 048697.01 .03 RAM_MW01
SAS No:
lab Sample ID:
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor:
SDG No.: 2507692
-=--=="-'---Lab FHe ID: 69201.D 250769201
10102107
10110107 Time: 2258 . -____ , __________ ,. ______ _
Station ID: ________ Method: a2!!0
RESULT
1
3.5
5
1
2
1
1
2
1
5
Form I
Q
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2507692 12
VOLATILE ORGANIC ANALYSIS DATA SHEET
EPA Sample No.
Lab Name: PEL Laboratories, Inc. Contract: Ram Leather 048697.01 .03 RAM_MW4D
Lab Code : _;_P..:Ec::L ___ _ Case No. SAS No: ___ SDG No.: _2_5_07_6_9_2 ____ _
Matrix: -'W"-A'-'-'-TE:.:..:R ____ _ Lab Sample ID: 250769204 Lab F;le ID: 69204.D
Sample wt/vol: 5 Units: -'M~Lc_ ___ _ Date Received: -'1-'0"/0"2/"0c.7 ____________ _
Concentrated Extract Volume: -'5~-----Date Extracted:
Le,el:(low/med) -'L~Oc.W __ _ Date Analyzed: 10/10/07 Time: 2322 -----·------
PercentSollds: O decanted : -----Dilution Factor:
Extraction: PURGETRAP Station ID: ________ Method: ll<§O
GPC Cleanup : ( Y/N) pH:
Column(1 ): DB-624 ID: 0.18 (01mJ_
CONCENTRA T/ON UNITS: 0U"'G"'i::.L ___ _
CASNO. ANALYTE RESULT Q
75-71-a Dichlorodifluoromethane u
74.a7-3 Chloromethane u
75-01-4 Vinyl chloride u
74.a3-9 Bromomethane u
75-00-3 Chloroethane u
75-69-4 Trlchlorofluoromethane u
75-35-4 1 , 1-Dlchloroethene u
75-15-0 Carbon disulfide u
75-09-2 Methylene chloride u
158-60-5 trans-1,2-Dichloroethene u
75-34-3 1, 1-Dichloroethane 1 u
67-a4-1 Acetone 10 u
158-59-2 cis-1,2-0ichloroethene u
74-97-5 Bromochloromethane u
78-93-3 2-Butanone 5 u
67-66-3 Chlorofonn u
71-55-a 1, 1, 1-Trichtoroethane u
56-23-5 Carbon tetrachloride u
71-43-2 Benzene u
107-06-2 1 ,2-0ichtoroethane u
79-01-a Trich!oroethene u
78-67-5 1,2-Dichloropropane u
75-27-4 Bromodlchloromethane u
10061-01-5 cis-1,3-0ichloropropene 1 u
108-10-1 4-Methyl-2-pentanone 5 u
108-68-3 Toluene u
10061-02-6 lrans-1.3-0ichtoropropene u
Form I
2507692
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D
VOLATILE ORGANIC ANALYSIS DATA SHEET
EPA Sample No.
Lab Name: PEL Laboratories, 1nc. Contract: Ram Leather 048697.01.03 RAM_MW40
Lab Code : _:P..:E::L:._ __ _ Case No.
Matrix: _,w-"A:,_T,_,E"R:,__ ___ _
Sample wt/vol: 5 Units: .:;Mc,L,__ ___ _
Concentrated Extract Volume: 05,__ ____ _
Level:(1ow/med) ..:L:.:O:.:W"'----
PercentSolids: 0 decanted : ____ _
Extraction: PURGETRAP
GPC Cleanup : ( YIN )
Column( 1 ): DB-624
-·--·---pH:
ID: 0.18
CONCENTRATION UNITS: UG,~IL:._ ___ _
CASNO. ANALYTE
79-00-5 1, 1,2-Trichloroethane
127-18-4 Tetrachloroethene
591-78-6 2-Hexanone
124-48-1 Dibromochloromethane
108-93-4 1,2-0lbromoethane(EDB)
108-90-7 Chlorobenzene
100-41-4 Ethylbenzene
100-42-5 Styrene
75-25-2 Bromoform
98-82-6 lsopropylbenzene (Cumene)
79-34-5 1,1,2,2-Tetrachloroethane
541-73-1 1,3-Dichlorobenzene
108-48-7 1 ,4-Dichlorobenzene
95-50-1 1 ,2-Dichlorobenzene
96-12-6 1 ,2-Dibromo-3-chloropropane
120-82-1 1,2,4-Trichlorobenzene
87-61-6 1,2,3-Trlchlorobenzene
1330-20-7 X~ene (total)
1834-04-4 MTBE
78-13-1 1, 1,2-TrlchJorotrifluoroethane
108-87-2 Methyl Cyciohexane
79-20-9 Methyl Acetate
110-82-7 Cyciohexane ·
SAS No: ______ SDG No.: .c2::5c.07cc6::9c.2 ____ _
Lab Sample ID: 250769204 Lab F;le 10: 69204.D
Date Received: _1:.:0:,10'°21"0"7 ____________ _
Date Extracted:
Date Analyzed: 1_0/10/07 ·-nme: 232:=2:._ ___ _
Dilution Factor:
Station ID: ________ Method: a26ll
RESULT
1
5
1
2
2
1
1
5
Form I
2507692
Q
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14
VOLATILE ORGANIC ANALYSIS DATA SHEET
EPA Sample No.
Lab Name; PEL Laboratories, Inc. Contract: Ram Leather 048697.01 .03 RAM_MW1D
lab Code : _P.cE~L ___ _ Case No.
Matrix: WATER -~~----
Sample wVvol: 5 Units: .:;Mc;L,_ ___ _
Concentrated Extract Volume: -"5'------
Levet:(Jow/med) -"L'-'0'-'W-'----
PercentSoHds: O decanted : ____ _
Extraction: PURGETRAP
pH:
SAS No: ______ SDG No.: .c2cc5.c.07.c6cc92'-----
lab Sample ID: 250769205 lab File ID: 69205.D
Date Received: ..;1.::0l:.,0=21.::0;_7 ___________ _
Date Extracted:
DateAnalyzed: 1Qf.!.Q~r ____ Time: _?_~_! ____ _
Dilution Factor:
Station ID: _______ Method: 82§0
. GPC Cleanup : ( YIN )
Column(1): ID: 0.18 1rnrnJ __
CONCENTRATION UNITS: U,0G~/~L ___ _
CASNO. ANALYTE
75-71-8 Oichlorodifluoromethane
74-87-3 Chloromethane
75-01-4 Vinyl chloride
74-83-9 Bromomethane
75-00-3 Chloroethane
75-89-4 Trichlorofluoromethane
75-35-4 1 , 1-Dichloroethene
75-15-0 Carbon dfsulflde
75-09-2 Methylene chloride
156-80-5 trans-1,2-Dlchloroethene
75-34-3 1, 1-Dichloroethane
67-84-1 Acetone
156-59-2 cis-1,2-Dlchloroethene
74-97-5 Bromochloromethane
78-93-3 2-Butanone
67-86-3 Chloroform
71-55-6 1, 1, 1-Trichloroethane
56-23-5 Carbon tetrachloride
71-43-2 Benzene
107-06-2 1,2-Dlchloroelhane
79-01-6 Trichloroethene
78-87-5 1 ,2-Dlchloropropane
75-27-4 Bromodichloromethane
10061-01-5 cis-1,3-Dichloropropene
108-10-1 4-Melhyl-21'.)enlanone
108-68-3 Toluene
10081-02-8 frans-1,J-Dichloropropene
RESULT
1
10
1
5
1
5
Form I
2507692
Q
u
u
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u
u
u
u
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VOLATILE ORGANIC ANALYSIS DATA SHEET
EPA Sample No.
Lab Name: PEL Laboratories, Inc. Contract: Ram Leather 048697.01 .03 RAM_MW1D
Lab Code : -'-P--=E=-L ___ _ Case No.
Melrix: --'W--'A-'-T'-'E"R-'------
Sample wt/vol: 5 Units: ML ~----~-----
Concentrated Extract Volume: 5
Level:(low/med) _;L:;0:.:W.:_ __
PercentSolids: 0 decanted : ____ _
Extraction: PURGETRAP
GPC Cleanup : I YIN)
Column( 1 ): DB-624 ID: 0.18
CONCENTRATION °UNITS: UGIL ==-----
CASNO. ANALYTE
79-00-5 1, 1,2-Trichtoroethane
127-184 Tetrachloroethene
591-7~ 2-Hexanone
124-48-1 Dibromochloromethane
108-93-4 1,2-Dibromoethane(EDB)
108-90-7 Chlorobenzene
100-41-4 Ethylbenzene
100-42-5 Styrene
75-25-2 Bromoform
98-82-8 lsopropytbenzene (Cumene)
79-34-5 1, 1,2.2-Tetrachloroethane
541-73-1 1,3-Dichlorobenzene
108-48-7 1 ,4-Dtchlorobenzene
95-50-1 1 ,2-Oichlorobenzene
98-12-8 1,2-Olbromo-3-chloropropane
120-82-1 1 ,2 ,4-Trichlorobenzene
87-81-8 1,2,3-Trichlorobenzene
1330-20-7 X0ene (total)
1634-04-4 MTBE
76-13-1 1, 1,2-Trlchlorotrifluoroethane
108-87-2 Methyl Cyclohexane
79-20-9 Methyl Acetate
110-82-7 Cyciohexane
,,..,, ...
SAS No: ______ SDG No.: ..c2cc50.c.7c.;6cc9=-2-----
Lab Sample ID: 250769205 Lab File ID: 69205.D
Date Received: _1:.,0e;I0,_,21::;0:;7 ____________ _
Date Extracted:
Dilution Factor:
Station 10: --------
RESULT
1
5
2
2
1.2
5
Form I
Q
u
u
u
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u
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u
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u
Time: 2347 ··--··--··-·-
Method: 82fil)
2507692 16
VOLATILE ORGANIC ANALYSIS DATA SHEET
EPA Sample No.
Lab Name: PEL Laboratories, Inc. Contract: Ram Leather 048697.01 .OJ TRIP BLANK
Lab Code : PEL -----Case No. SAS No: _____ SDG No.: ~2~50~7_,6_92 ____ _
Matrix: ~W=A-'-T:,E:_:R ____ _ lab Sample ID: 250769206 lab F;-, ID: 69206.D
Sample wt/vol: _,Sc._ __ Units: ~M°'L,._ ___ _ Date Received: _1c,0:::l0"2/"0"7 ____________ _
Concentrated Extract Volume: 5 Dale Extracted:
Le'v'el:(Jow/med) ~L~O~W~--Date Analyzed: 10/11/0_7 ___ _ Time: 0011 __ _
PercentSolids: O decanted : -----Dilution Factor;
Extraction: PURGETRAP
GPC Cleanup : ( YIN )
Column(1 ); DB.e24 ID: 0.16
CONCENTRATIONUNITS: _U~G~/~L ___ _
CASNO. ANALYTE
75-71-6 Dichlorodifluoromethane
74-67-3 Chloromethane
75-01-4 Vinyl chloride
74-63-9 Bromomethane
75-00-3 Chloroethane
75-69-4 T richlorofluorometha ne
75-35-4 1 , 1-0lchloroethene
75-15-0 Carbon disulflde
75-09-2 Methylene chloride
156-60-5 trans-1,2-0ichloroethene
75-34-3 1, 1-Dichloroethene
67-64-1 Acetone
156-59-2 cis-1,2-Dlchloroethene
74-97-5 Bromochloromethane
76-93-3 2-Butanone
67-66-3 Chloroform
71-55-6 1,1, 1-Trichloroethane
56-23-5 Carbon tetrachloride
71-43-2 Benzene
107-06-2 1 ,2-0ichloroethane
79-01-6 Trichloroethene
76-67-5 1 ,2-0ichloropropane
75-27-4 Bromodichloromethane
10061-01-5 cis-1 ,3-Dichloropropene
106-10-1 4-Methyl-2-pentanone
106-68-3 Toluene
10061--02-6 trans-1,3-Dichloropropene
·J•,11/•UI
Station ID: ________ Method: ll2§l!
Jmm) __
RESULT Q
10
1
5
1
5
Form I
2507692
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VOLATILE ORGANIC ANALYSIS DATA SHEET
EPA Sample No.
Lab Name: PEL Laboratories, Inc. Contract: Ram Leather 048697.01 .03 TRIP BLANK
Lab Code : _P_E~L ___ _ Case No. SAS No: ______ SDG No.: 02:::5c;:0:..;76:::9:::2 ____ _
Matrix: WATER --------Lab Sample ID: 250769206 Lab File ID: 69206.D
Sample wVvol: 05:._ __ Units: 0Mc;L,_ ___ _ Date Received: _1"0"'/0::21:c0:c7 ____________ _
Concentrated Extract Volume: 5 Date Extracted: ··------·-·---·--
Level:(low/med) -'L'-'O'-'W-'----Date Analyzed: 10/11~q?._ .. ______________ Time: 0011
PercentSolids: 0 decanted : ____ _ Dilution Factor:
Extraction: PURGETRAP Station 10: ________ Method: S2fil!
GPC Cleanup : ( Y/N) ___ pH:
Column(1): _gB_12-~----·--······· ID: 0.18 _(mm)
CONCENTRATION UNITS: _,U::,G"-'/L=------
CASNO. ANALYTE
79-00-5 1 , 1,2-Trichloroethane
127-18-4 Tetrachloroethene
591-78-<I 2-Hexanone
124-48-1 Dibromochloromethane
106-93-4 1,2-Dibromoethane(EDB)
108-90-7 Chlorobenzene
100-41-4 Ethyl benzene
100-42-5 Styrene
75-25-2 Bromoform
98-<12-8 lsopropytbenzene (Cumene)
79-34-5 1, 1,2,2-Tetrachloroethane
541-73-1 1,3-0ichlorobenzene
108-46-7 1,4-Dichlorobenzene
95-50-1 1,2-Dichlorobenzene
96-12-8 1,2-0lbromo-3<hloropropane
120-82-1 1,2,4-TrichJorobenzene
67-81-8 1,2,3-Trichlorobenzene
1330-20-7 X~ene (tolal)
1834-04-4 MTBE
76-13-1 1, 1,2-Trichlorotrifluoroethane
108-87-2 Methy1 Cyclohexane
79-20-9 Methyl Acetate
110-82-7 CycJohexane
RESULT
1
5
2
1
1
2
1
5
Form I
2507692
Q
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18
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Appendix E I
Support Documentation I
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VOLATILE ORGANIC MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERY
EPA Sample No.
lab Name: PEL Laboratories, Inc. Contract Ram Leather 048697.01 RAM_MW01MS
Lab Code : PEL Case No. SASNo:
SPIKE SAMPLE
ADDED CONCENTRATION
COMPOUND UG/L
Dibromochloromethane 20
1,2-0ibromoethane(EOB) 20
Chlorobenzene 20
Ethytbenzene 20
Styrene 20
Bromoform 20
lsopropylbenzene (Cumene) 20
1, 1,2,2-Tetrachloroethane 20
1 ,3-0ichlorobenzene 20
1,4-0lchlorobenzene 20
1,2-DJchtorobenzene 20
1 .2-0lbromo-3--chloropropane 20
1,2,4-Trichlorobenzene 20
1,2,3-Trichlorobenzene 20
Xylene (total) 60
MTBE 20
1, 1 ,2-Trichlorotrifluoroethane 20
Methyl Cyclohexane 20
Methyl Acetate 20
Cyclohexane 20
Spike Recovery: 3 outof 50 outside limits
# Column to be used to flag recovery values with an asterisk
• Values outside QC limits
Control limit source: (lab/method)
COMMENTS:
METHOD
UG/L
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Form Ill
2507692
SDG No.: _25_0_7692 _____ _
MS MS CONCENTRATION %
UG/L REC#
20.9 104.0
20.9 104.0
21.1 106.0
21.8 108.0
21.4 107.0
20.9 104.0
22 110.0·
19.8 99.0
21.5 108.0
21.3 106.0
21.2 108.0
18.9 94.5
21.4 107.0
21.7 108.0'
84.8 108.0
23 115.0'
21.4 107.0
22.9 114.0
18.4 92.0
23.5 118.0
QC
LIMITS
REC.
78-114
90-109
35-148
93-111
93-111
57-117
91 -107
85 -100
84-t 12
58-132
87-110
79-109
87 • 107
83-105
90-111
90-111
84-122
80-118
81 • 105
84-119
30
3
VOLATILE ORGANIC MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERY
EPA Sample No.
lab Name: PEL Laboratories, Inc. Contract: Ram Leather 04869 RAM_MW01MSD
Lab Code : PEL Case No. SAS No: SDG No.: 2507692 --------
SPIKE MSO MSD ADDED CONCENTRATION % % QC LIMITS COMPOUND UG/l
Dichlorodlfluoromethane 20
Chloromethane 20
Vlnyl chloride 20
Bromomethane 20
Chloroethane 20
Trichlorofluoromethane 20
1, 1 -Dichloroethene 20
Carbon disulfide 20
Methylene chloride 20
trans-1 ,2-Dichloroelhene 20
1, 1-0ichloroethane 20
Acetone 60
cis-1,2-Dichloroethene 20
Bromochloromethane 20
2-Butanone 60
Chloroform 20
1, 1, 1-Trichloroethane 20
Carbon tetrachloride 20
Benzene 20
1,2-Dichloroethane 20
Trichloroethene 20
1,2-0lchloropropane 20
Bromodichloromethane 20
cis-1,3-Dlchloropropene 20
4-Methyl-2-pentanone 60
Toluene 20
trans-1,J..Oichloropropene 20
1, 1,2-TMchloroethane 20
Tetrachloroethene 20
2-Hexanone 60
# Column to be used to flag recovery values with an asterisk
• Values outside QC limits
Control limit source: (lab/method)
COMMENTS:
'/Uf]/1'•
METHOD
UG/L
17.3
17.8
18
19.1
19.4
18.5
19.9
18.9
18.6
19,7
19.8
54.5
20.5
19.3
53.3
19.7
20.5
19.8
20.1
19.4
19.5
19.5
18.7
19.4
49.2
20.4
19.6
19.4
22.2
55
Form Ill
2507692
REC# RPO# RPO REC,
86.5 9.4 13 72· 127
89.0 6.5 19 75. 111
90.0 3.8 15 78 • 110
95.5 5.6 20 83 • 120
97.0 1.5 18 85 • 121
92.5 7.8 20 88 · 119
99.5 8.7 17 89·113
94.5 11.0 16 67 • 124
93.0 9.2 20 88 · 113
98.5 8.3 13 85 • 113
99.0 7.8 16 91·110
90.8 12.1 17 76 • 133
102.0 8.0 13 89-117
96.5 7.5 13 86-107
86.8 7.8 20 75. 113
98.5 8.3 10 89 • 114
102.0 5.2 19 86 -114
99.0 8.7 16 85-125
100.0 8.1 . 7 92-110
97.0 7.0 11 88-113
97.5 9.8 16 78-119
97.5 8.8 10 92 • 109
93.5 12.5 . 11 83-114
97.0 9.3 14 79. 109
82.0 14.7 . 8 87 • 113
102.0 6.2 13 89 • 121
98.0 9.2 . 8 70-108
97.0 7.0 13 89-116
93.5 12.7 . 12 88-115
91.7 12.0 . 7 65-118
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I Appendix D
I Support Documentation
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3
VOLATILE ORGANIC MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERY
EPA Sample No.
Lab Name: PEL laboratories, Inc. Contract: Ram Leather 048697.01 RAM_MW01MS
Lab Code : PEL Case No. SAS No:
SPIKE SAMPLE
ADDED CONCENTRATION
COMPOUND UG/L
Oibromochloromethane 20
1,2-0ibromoethane(EOB) 20
Chlorobenzene 20
Ethyl benzene 20
Styrene 20
Bromoform 20
lsopropylbenzene (Cumene) 20
1, 1,2,2-Tetrachloroethane 20
1,3-Dlchlorobenzene 20
1,4-Dichlorobenzene 20
1,2-Dlchlorobenzene 20
1,2-D!bromo-3-chloropropane 20
1,2, 4-Trichlorobenzene 20
1,2,3-Trichlorobenzene 20
X~one (total) 60
MTBE 20
1 , 1,2-Trichlorotrifluoroethane 20
Methyl Cyclohexane 20
Methyl Acetate 20
Cyclohexane 20
Spike Recovery: 3 out of 50 outside limits
# Column to be used to flag recovery values with an asterisk
• Values outside QC limits
Control limit source: {tab/method)
COMMENTS:
METHOD
UG/1.
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Form Ill
2507692
SDG No.: ~2~5~07~6~9~2 ____ _
MS MS CONCENTRATION %
UG/L REC#
20.9 104.0
20.9 104.0
21.1 100.0
21.6 108.0
21.4 107.0
20.9 104.0
22 110.0·
19.8 99.0
21.5 108.0
21.3 100.0
21.2 100.0
18.9 94.5
21.4 107.0
21.7 108.0 •
84.6 108.0
23 115.0 •
21.4 107.0
22.9 114.0
16.4 92.0
23.5 118.0
QC
LIMITS
REC.
78-114
90-109
35-148
93-111
93-111
57-117
91 -107
85-100
84-112
58-132
67 -110
79-109
87-107
83-105
90 -111
90-111
84-122
80-118
81 -105
84-119
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3
VOLATILE ORGANIC MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERY
EPA Sample No.
Lab Name: PEL Laboratories, Inc. Contract: Ram Leather 04869 RAM_MW01MSO
lab Code : PEL Case No. SAS No: SOG No.: 250~7~6~92~---
SPIKE MSD MSD
ADDED CONCENTRATION % % QC LIMITS COMPOUND UG/L
Oichlorodifluoromethane 20
Chloromethane 20
Vinyl chloride 20
Bromomelhane 20
Chloroethane 20
Trichlorofluoromethane 20
1, 1-0ichloroethene 20
Carbon dlsulfide 20
Methylene chloride 20
trans-1 ,2-0ichloroethene 20
1, 1-Dlchloroethane 20
Acetone 60
c!s-1 ,2-0ichloroelhene 20
Bromochloromethane 20
2-Butanone 80
Chloroform 20
1, 1, 1-Trichloroethane 20
Carbon tetrachloride 20
Benzene 20
1 ,2-Dlchtoroethane 20
Trichloroethane 20
1,2-0lchloropropane 20
Bromodichloromethane 20
cis-1 ,3-Dlch!oropropene 20
4-Meth~-2-pentanone 60
Toluene 20
trans-1,3-Dichloropropene 20
1, 1,2-Trichloroethane 20
Tetrachloroethene 20
2-Hexanone 60
# Column to be used to flag recovery values with an asterisk
• Values outside QC limits
Control limit source: (tab/method)
COMMENTS:
METHOD
UG/L
17.3
17.8
18
19.1
19.4
18.5
19.9
18.9
18.8
19.7
19.8
54.5
20.5
19.3
53.3
19.7
20.5
19.8
20.1
19.4
19.5
19.5
18.7
19.4
49.2
20.4
19.6
19.4
22.2
55
Form Ill
2507692
REC# RPO# RPO REC.
86.5 9.4 13 72-127
89.0 8.5 19 75-111
90.0 3.8 15 78-110
95.5 5.6 20 83-120
97.0 1.5 18 85-121
92.5 7.8 20 88-119
99.5 8.7 17 89-113
94.5 11 .0 16 87 • 124
93.0 9.2 20 88-113
98.5 8.3 13 85-113
99.0 7.6 16 91 -110
90.8 12.1 17 78-133
102.0 8.0 13 89-117
96.5 7.5 13 86-107
88.8 7.8 20 75 -113
98.5 8.3 10 89-114
102.0 5.2 19 86 -114
99.0 8.7 16 85-125
100.0 8.1 . 7 92-110
97.0 7.0 11 88-113
97.5 9.8 16 78 -119
97.5 8.8 10 92 -109
93.5 12.5 . 11 83 · 114
97.0 9.3 14 79 -109
82.0 14.7 . 8 67-113
102.0 8.2 13 89 -121
98.0 9.2 . 8 70-108
97.0 7.0 13 89 • 118
93.5 12.7 . 12 88-115
91.7 12.0 7 65-118
•
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3
VOLATILE ORGANIC MA TRIX SPIKE/MA TRIX SPIKE DUPLICATE RECOVERY
EPA Sample No.
Lab Name: PEL Laboratories, Inc. Contract: Ram Leather 048691 ~ ____ RA_M ___ M_w_o_1_M_s_o ___ ~
Lab Code: PEL Case No. SAS No:
SPIKE MSD
ADDED CONCENTRA TJON COMPOUND UG/L
Dibromochloromethane 20
1,2-Dibromoethane(EDB) 20
Chlorobenzene 20
Ethytbenzene 20
Styrene 20
Bromoform 20
lsopropylbenzene (Cumene) 20
1,1,2,2-Tetrachloroethane 20
1 ,3-0ichlorobenzene 20
1 ,4-.0ichlorobenzene 20
1,2-Dlchlorobenzene 20
1,2-0/bromo-3-chloropropane 20
1,2,4-Trichlorobenzene 20
1,2,3-T rlchlorobenzene 20
Xylene (lotal) 60
MTBE 20
1, 1,2-Trichlorotrlfluoroethane 20
Methyl Cyciohexane 20
Methyl Acetate 20
Cyciohexane 20
RPO: 13 out of
Spike Recovery:
50 outside 1tm1ts
1 outof 50 outside limits
# Column to be used to flag recovery values with an asterisk
• Values outside QC limits
Control limit source: (lab/method)
COMMENTS:
METHOD
UG/L
18.3
18.3
19
19.2
19.3
18.2
19.3
17.8
19.2
18.6
18.8
18
19.6
19.6
58.2
22.5
20.1
21.1
16.7
21.5
Form Ill
2507692
SDG No.: 250769~2 ____ _
MSD
% % QC LIMITS
REC I RPDI RPO REC.
91.5 13.3 . 11 78 -114
91.5 13.3 14 90-109
95.0 10.5 . 7 35-148
96.0 11.8 14 93-111
96.5 10.3 . 7 93-111
91.0 13.8 14 57-117
96.5 13.1 . 12 91-107
89.0 10.6 11 85-100
96.0 11.3 14 84-112
93.0 13.5 . 11 58-132
94.0 12.0 . 8 67-110
90.0 4.9 20 79-109
99.0 7.8 16 67 -107
98.0 10.2 12 63 -105
97.0 10.7 . 9 90-111
112.0· 2.2 11 90 -111
100.0 6.3 20 64-122
106.0 8.2 9 80 -118
63.5 9.7 10 61 -105
106.0 6.9 11 64-119
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