NCD982096653_20041210_Ram Leather Care Site_FRBCERCLA RD_Draft Site Health and Safety Program-OCR

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Draft
Site Health and Safety Program (HASP)
Ram Leather Site
Charlotte, Mecklenburg County,
North Carolina
December10,2004
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Black & Veatch Special Projects Corp. (Black & Veatch)
Site Health and Safety Program (HASP)
Ram Leather Superfund Site
Charlotte, Mecklenburg County, North Carolina
December 10, 2004
Prepared by: __________ _
Darci Scherbak, P .E.
(Author)
Reviewed by: _________ _
Nancy Geller, P.E.
(Project Manager)
Reviewed by: ----------Jack Schill, Clli, CSP
(Black & Veatch OHS)
Date:
Date:
Date:
---------
---------
---------
Expiration Date: December I 0, 2005
This Health and Safety Plan (HASP) is produced for the use of Black & Veatch and specific
designated contractors on the project indicated herein. This HASP is not intended or represented
to be suitable for use by others on the project or for use on any other project. Any use without
written verification or adaptation by Black & Veatch will be at the user's sole risk and without
liability or legal exposure to Black & Veatch. Any use of this HASP without the written approval
of the Black & Veatch Health and Safety Manager is not authorized.
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EPA <::ontract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A4 I 9
Ram Leather Site
Contents
Health & Safety Plan
Revision No. 0
December I 0, 2004
Page No.
Acronyms and Abbreviations ........................................... AA-1
1.0 Introduction ......................................................... 1
1.1 Purpose ........................................................ 1
1.2 Scope .......................................................... 1
1.3 Compliance with Site HASP ........................................ 1
2.0 Site Background ..................................................... 2
2 .1 Background ...................................................... 2
2.2 Operational History and Current Status ................................ 2
2.3 Nature and Extent of Hazardous Materials .............................. 4
3.0 Hazard Assessment ................................................... 5
3.1 Chemicals of Concern ............................................. 5
3.2 Hazard Communication for Chemicals of Concern ....................... 5
4.0 Personnel Qualifications ............................................... 6
4.1 Training Requirements ............................................ 6
4.1.1 Safety Meetings ............................................. 7
4.2 Medical Surveillance Program ....................................... 7
5.0 Personal Protective Equipment .......................................... 9
5.1 General ......................................................... 9
5.2 Chemical Protective Equipment .............. , ...................... 9
5.2.1 Levels of Protection .......................................... 9
5.2.2 Chemical Ensembles ........................................ 10
5 .3 Hazards and Protection Level ...................................... 11
5.4 Reassessment of Protection Level ................................... 13
5.5 lnspection of PPE ................................................ 13
5.6 Respiratory Protection ............................................ 13
6.0 Monitoring Program ................................................. 16
6.1 Real Time Monitoring ............................................ 16
6.2 Air Monitoring Result Logging ..................................... 16
6.3 Personal Monitoring ............................................. 17
6.4 Operation, Maintenance and Calibration .............................. 17
6.5 Initial Survey ................................................... 18
6.6 Periodic Survey ................................................. 18
6. 7 Perimeter Monitoring ............................................. 19
048369.0121 TOC-1
EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A419
Ram Leather Site
Contents (Continued)
Health & Safety Plan
Revision No. 0
December I 0, 2004
Page No. 7.0 Site Control ........................................................ 20 7.1 Site Mapping ................................................... 20 7.2 Work Zones .................................................... 20 7.2.l Exclusion Zone ............................................ 21
7.2.2 Contamination Reduction Zone ................................ 21 7.2.3 Support Zone .............................................. 21 7.3 Buddy System .................................................. 24 7.4 Audits ......................................................... 25 7.5 Visitors ........................................................ 25
8.0 Safety and Emergency Procedures ...................................... 26 8.1 Standing Safety Orders ........................................... 26 8.2 Medical Emergencies ....................................... : ..... 26
8.2.1 Chemical Exposure Emergency ................................ 27 8.2.2 Accident Reporting ......................................... 28 8.2.3 Hospital Route ............................................. 29 8.3 Temperature Extremes ............................................ 29 8.3. l Heat Stress Monitoring ...................................... 29 8.3.2 Cold Stress Monitoring ...................................... 34 8.4 Decontamination Procedures ....................................... 37 8.4. l General ................................................... 37 8.4.2 ·Emergency Decontamination .................................. 38
8.4.3 PPE ..................................................... 38 8.4.4 Instruments ............................................... 39
8.4.5 Equipment ................................................ 40 8.4.6 Decontamination Solutions ................................... 40 8.4.7 Vehicle Decontamination Station .............................. 40 8.5 Disposition of Decontamination Wastes .............................. 41 8.5.1 Disposal Procedures ........................................ 41 8.5.2 Contamination Reduction Corridor Breakdown ................... 41 8.6 Communications ................................................ 41 8.6. I Internal Communication ..................................... 41
8.6.2 External Communications .................................... 42 8.6.3 Communication Signals ...................................... 43 8.6.4 Hazard Communication ...................................... 44 8.7 Confined Space Entry Procedures ................................... 44
048369.0121 TOC-2
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EPA Contract No.: 68-W99-043 Health & Safety Plan
Revision No. 0
December I 0, 2004
Work Assignment No.: 369-RDRD-A4 I 9
Ram Leather Site
Contents (Continued)
Page No.
9.0 Emergency Action Plan ....................... , ........................ 45
9.1 Preplanning .................................................... 45
9.2 Reporting Emergencies ........................................... 45
9.3 Notification .................................................... 45
9 .4 Emergency Contacts · ............................................. 46
9.5 Fire or Explosion ................................................ 46
9.6 Spills or Leaks .................................................. 46
9.7 Evacuation Procedures ............................................ 47
9.8 Critique of Response and Follow-up ................................. 48
I 0.0 Team Member Responsibilities ........................................ 49
I 0.1 Managerial Responsibility ........................................ 49
I 0.1.1 Health and Safety Manager .................................. 49
I 0.1.2 Project Manager ........................................... 49
I 0.2 Team Organization/Responsibility ................................. 49
10.2.1 Site Manager ............................................. 49
10.2.2 Site Safety Coordinator ..................................... 49
I 0.2.3 Field Team ............................................... 50
11.0 Certification ...................................................... 51
12.0 Record of Changes ................................................. 52
Table 2-1
Table 2-2
Table 2-3
Table 2-4
Table 2-5
Table 2-6
Table 2-7
Table 2-8
Table 2-9
Table 2-10
048369.0 I 21
Tables
Analytical Results -Soil Samples Collected by Ram Leather, 1991
Analytical Results -Soil Samples Collected by EPA, 1994
Analytical Results -PCE/Degradation Products, Soil Samples, 1999
Analytical Results -VOCs, Deep Well, Septic Tank, and Potable Wells
Analytical Results -Metals, Potable Wells
Analytical Results -VOCs, Soil Samples, 1999
Analytical Results -Metals, Soil Samples
Analytical Results -Pesticides/PCBs, Soil Samples, 1999
Analytical Results -BNAs, Soil Samples, 1999
Analytical Results -VOCs, Soil Samples, 1999
TOC-3
EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A4 I 9
Ram Leather Site
Contents (continued)
Table 8-1 Frequency of Physiological Monitoring
Table 8-2 Heat Stress Symptoms and Treatment
Table 8-3 Cold Work Environment Work Practice
Appendices
Appendix I Site Maps and Emergency Information
Figure I Site Vicinity Map
Figure 2 Site Layout Map
Figure 3 Hospital Route Map
Table A-1 Emergency Contacts
Health & Safety Plan
Revision No. 0
December I 0, 2004
Appendix 2 Chemicals of Concern and Applicable Regulatory Standards
Table A-2 Chemicals of Concern and Applicable Regulatory Standards
Appendix 3 Material Safety Data Sheets
Appendix 4 Safety Meeting Checklist
Appendix 5 Medical Monitoring Examination Elements
Appendix 6 Monitoring Equipment Action Levels
Appendix 7 Decontamination Methods
048369.0121 TOC-4
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EPA Contract No.: 68-W99-043 Health & Safety Plan
Revision No. 0
December l 0, 2004
Work Assignment No.: 369-RDRD-A4l9
Ram Leather Site
ACGIH
ACP
ANSI
CAS
CFR
CNS
coc
Con
CPR
CRC
CVS
DCA
DCE
DNAPL
DOT
EKG
EPA
FID
HASP
HSM
IDLH
kg
LEL
MCDEP
MSDS
µg/kg
mg/m3
MSHA
NCDENR
NIOSH
NOV
OSHA
OVA
PCE
048369.0121
Acronyms and Abbreviations
American Conference of Governmental Industrial Hygienists
Access control point
American National Standards Institute
Chemical Abstracts Service
Code of Federal Regulations
Central nervous system
Contaminants of concern
Skin and/or eye contact
Cardio-pulmonary resuscitation
Contamination reduction corridor
Cardiovascular system
I, 1-Dichloroethane
1, 1-Dichloroethene
Dense Non Aqueous Phase Liquid
Department of Transportation
Electrocardiogram
U.S. Environmental Protection Agency
Flame ionization detector
health and safety plan
health and safety manager
Immediately dangerous to life or health
Kilogram
Lower explosive limit
Mecklenburg County Department of Environmental Protection (MCDEP)
Material safety data sheet
Microgram per kilogram
Milligram per cubic meter
Mine Safety and Health Administration
North Carolina Department of Environment and Natural Resources
National Institute for Occupational Safety and Health
Notice of Violation
Occupational Safety and Health Administration
Organic vapor analyzer
Tetrachloroethylene
EPA.Contract No.: 68-W99-043
Health & Safety Plan
Revision No. 0
December I 0, 2004
Work Assignment No.: 369-RDRD-A419
Ram Leather Site
PEL
PID
PM
PPE
PPM
REL
RI
SCBA
SM
SSC
TCE
TLV
TWA
VDS
048369.012I
Acronyms and Abbreviations (Continued)
Permissible exposure limit
Photo ionization detector
project manager
Personal protective equipment
Parts per million
recommended exposure limits
Remedial Investigation
Self-contained breathing apparatus
Site manager
Site safety coordinator
Trichloroethylene
Threshold limit value
Time-weighted average exposure concentration for normal 8-hour (TL V, PEL) or up to a IO-hour (REL) workday and 40-hour workweek
Vehicle decontamination station
AA-2
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EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A4l9
Ram Leather Site
1.1 Purpose
1.0 Introduction
Health & Safety Plan
Revision No. 0
December I 0, 2004
This site health and safety plan (HASP) will establish the site specific health and safety guidelines
and procedures for activities at the Ram Leather Site (Site) located in Charlotte, Mecklenburg
County, North Carolina. The HASP is based on existing data and site reconnaissance and has
been prepared in accordance with Occupational Safety and Health Administration (OSHA) Rules.
The HASP will be approved by the Black & Veatch Special Projects Corp. (Black & Veatch)
· health and safety manager (HSM) or designee.
1.2 Scope
Specific information or procedures that are applicable to all operations and tasks at the site are
included in Sections 1.0 through 9.0 of the HASP. These procedures are applicable to all site
activities unless otherwise stated in the appendices. The appendices address sp~cific tasks and
operations performed at the Ram Leather Site, detailing the hazards and control measures.
Attachment A will be referred to as task-specific health and safety plans (Task HASP).
1.3 Compliance with Site HASP
Consistent with the contents of this Site HASP, work will be conducted in a safe and
environmentally acceptable manner and all Black & Veatch field personnel under this HASP shall
be required to comply with the health and safety requirements specified herein. All field personnel
under this plan are required to read and familiarize themselves with the contents of this Site HASP
and the associated Task HASPs. Field personnel will document this competency through the entry
ofasignature and date as specified in the Certification Section (Section I 1.0) in this Site HASP
and Task HASPs related to the work being performed.
048369.0121 1
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EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A419
Ram Leather Site
2.0 Site Background
2.1 Background
Health & Safety Plan
Revision No. 0
December I 0, 2004
The United States Environmental Protection Agency's (EPA's) identification Number for the Ram
Leather Site is NCD058754 789. The Site is located at 15100 Albemarle Road (Route 24/27)
in a rural area of eastern Mecklenburg County, North Carolina,justwestofthe Cabarrus County
line. The site is locatedat35' 13' 41" north latitude and 80' 36' 24.50" west longitude. The site_
is located approximately four miles from the Charlotte city boundary.
Ram Leather Care restored leather goods and operated as a dry cleaning facility. Chlorinated
hydrocarbon chemicals [primarily tetrachloroethene (PCE) and petroleum hydrocarbons (mineral
spirits)] were used in the cleaning process.
The dry cleaning facility is no longer in operation and the site is currently operating as a weekend
flea market. The site and the surrounding property is illustrated in Figures 1 and 2 presented in
Appendix A. The site is surrounded by residential property. To the south is a 14-acre privately
owned parcel. A small fishing pond is located on the 14-acre parcel. To the east is the 8-acre
privately owned parcel. To the north is another privately owned parcel. To the west is the 18-acre
privately owned parcel. A gravel road running southeast from the Ram Leather driveway provides
access to two residences.
2.2 Operational History and Current Status
The Ram Leather facility operated from 1977 to 1993. The building was constructed in 1967 and
housed a construction business owned by Mr. Worley until 1977. On May 6, 1987, Ram Leather
submitted its first Notification ofHazardous Waste Activity. Ram Leather reported that it was a
generator ofless than 1,000 kilograms (kg)/month of DOOi RCRA wastes (as defined in the
Resource Conservation and Recovery Act, 40 CFR 261.21 ). On June 8, I 987, EPA assigned
the number NCO 982 096 653 to Ram Leather as a small quantity generator.
On April 6, 1991, during a complaint investigation ofademolition landfill on adjacent property,
Mecklenburg County Department of Environmental Protection (MCDEP) inspector discovered
048369.0121 2
EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A419
Ram Leather Site
Health & Safety Plan
Revision No. 0
December l 0, 2004
illegal open burning at the Ram Leather Site. The facility operator was burning filters containing
PCE. The facility was instructed to stop and complied. MCDEP issued a Notice ofViolation
(NOV) for this burning.
On April 29, 1991, the North Carolina Department of Environment and Natural Resources
(NCDENR) inspector visited the site. The inspector noted that the last documented disposal of
D00l waste petroleum naphtha was on February 12, 1988. Mr. Worley stated that the Dry
Cleaners Trade Association had sent information that certain petroleum-based dry cleaning solvents
were no longer deemed hazardous waste and that he had assumed that his waste was no longer
hazardous. The inspector discovered a 250-gallon above-ground storage tank o_fD00 I waste
mineral spirits and 49 drums ofliquid waste in an outside waste storage area. Bungs were open,
allowing rainwater to enter the drums and waste to overflow. Logs and drum markings were not
maintained. The drums were standing in liquid. A composite sample of drum contents and a
surface soil sample were taken on May 2, 1991.
TheNCDENR was notified April 30, 1991,ofaboilerblow-offin the storage area. Apermithad
not been issued for the site, making this an illegal discharge. The area had been recently graded
to allow surface water runoff to flow toward Albemarle Road. A drinking water well was noted
within 50 feet of the storage area and was sampled on May 6, 1991, byMCDEP. Due to
contamination found in the well, Ram Leather was advised to discontinue using the well for
drinking. On May 13, 1991, all off-site drinking water wells within ½ mile were sampled. Two
private residential wells were found to be contaminated.
On June 5, 1991, an NCDENR inspector visited the Ram Leather Site to provide instructions to
Mr. Worley. While there, Ram Leather requested a change in classification under RCRA because
the 49 drums ofD00l hazardous waste were in excess of6,000 kg, exceeding small quantity
generator status. Mr. Worley stated that PCE filters were stored in a dumpster prior to disposal
in a landfill.
Stored hazardous wastes were shipped off-site on June 14, 1991. Ram Leather was reclassified
as a Large Quantity generator on June 17, 1991.
048369.0 I 21 3
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EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A4l9
Ram Leather Site
2.3 Nature and Extent of Hazardous Materials
Health & Safety Plan
Revision No. 0
December I 0, 2004
The EPA completed the first phase of the Remedial Investigation (RI) in 1999 to assess the areal
and vertical extent of contaminated soil and groundwater at the site, and to determine whether
additional potable wells adjacent to the site were contaminated. In 2000, EPA tasked COM to
undertake additional groundwater studies (Phase II). The main objectives of the additional studies
were to determine the nature of the fracture zones in the area and the extent of contamination in the
fractured bedrock aquifer. A review of the data collected suggests that the extent of contamination
has been defined to the north and west-northwest of the site, but remains to be defined on the
southern side and the east-northeast directions from the facility. Additional characterization data
is required for a long-term remedy. Additionally, four private wells sampled during the RI still
showed unacceptable levels of contamination in the 2000 sampling event.
The data collected during the 1999 EPA RI and the 2000 COM groundwater investigation, as, well
as earlier investigations, suggest that soils and groundwater at the site and groundwater at
neighboring private wells are contaminated with chlorinated solvents typically associated with dry
cleaning operations. Limited full scan data that have been collected previously indicate that metals,
SVOCs, and pesticides are not a problem at the site. Site-related contaminants include
tetrachloroethylene (PCE), trichloroethylene (TCE), I, 1-dichloroethene (DCE), and I, 1-
dichloroethane (DCA). The extent of contamination has been estimated to the north and
west-northwest of the site. The extent remains to be defined on the southern side and
east-northeast directions from the facility. The two former potable on-site wells (the "old" and the
"new") have high levels ofcontarnination. The four private wells in the immediate vicinity still show
unacceptable levels of contamination.
Contamination migration pathways were evaluated in rock cores obtained from boring B-1.
Analysis of the cores showed a diagonal fracture pattern, suggesting pathways have existed for
Dense Non Aqueous Phase Liquid (DNAPL) and/ or dissolved PCE in dry cleaning fluids to
migrate downward to the subsurface. The depth of migration is dependent primarily on the actual
geometry of the fracture system, which cannot be determined without detailed analysis.
048369.0121 4
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EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A4l9
Ram Leather Site
3.0 Hazard Assessment
3.1 Chemicals of Concern
Health & Safety Plan
Revision No. 0
December I 0, 2004
Chemicals of concern (COC) at the Ram Leather Site and the maximum detected concentrations
are listed in Appendix 2. The table lists the allowable exposure levels for the chemicals, signs and
symptoms of exposure, dermal absorption hazards, carcinogenicity, immediately dangerous to life
and health (IDLH) values, health hazards, physical hazards, Chemical Abstracts Service (CAS)
registry numbers, and physical characteristics.
3.2 Hazard Communication for Chemicals of Concern
When COC concentrations exceed 1 %, or 0.1 % for a carcinogen, a Material Safety Data Sheet
(MSDS) will be provided in Appendix 3 of the Site HASP. The objective ofa MSDS is to
concisely inform any interested party about the hazards associated with chemicals or compounds
that may be anticipated when handling, using, or encountering that chemical or compound in an
emergency situation. The percent column indicates the approximate percentage of the substance
as compared to the total weight or volume of the product. The MSDSs may not be from the
specific manufacturer, distributor, or potentially responsible parties that deposited the COCs.
Although these are written by a speci fie manufacturer, they are not meant in anyway to suggest that
the waste products or contamination on the site conform to that particular manufacturer. They are
intended to be used solely as an approximation for the waste product to provide safety and health
hazard information, including symptoms of exposure, first-aid procedures and spill control
measures.
048369.0121 5
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EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A419
Ram Leather Site ·
4.0 Personnel Qualifications
4.1 Training Requirements
Health & Safety Plan
Revision No. 0
December I 0, 2004
All personnel who will be engaged in hazardous waste operations must present to the site safety
coordinator (SSC) a certificate of completion for an initial 40-hour hazardous waste operations
training course or the most recent certificate of completion for an 8-hour refresher course. The
course must have been completed within the 12 months of the individual being onsite performing
hazardous waste operations. The training must comply with OSHA regulations found at 29 Code
ofF ederal Regulations (CFR) 1910.120( e ). The certification must be presented to the SSC before
site activities begin.
All personnel must complete a minimum of three days on-the-job training under the direct
supervision ofa qualified SSC or site supervisor before they are qualified to work at a hazardous
waste site unsupervised.
Consistent with OSHA 29 CFR 1910.120 paragraph ( e )( 4), individuals serving in a supervisory
role, such as the field team leader or SSC, require an additional 8 hours of training. Black &
Veatch individuals functioning in a SSC capacity shall also have at least 6 days of experience at the
level of protection planned for in this HASP. A SSC qualified at a given level of protection is also
qualified as a SSC at a lesser level of protection.
Two Black & Veatch personnel on site will be trained and currently certified in first aid and adult
cardiopulmonary resuscitation (CPR).
Personnel who use air supplied respirators must provide the HSM written certification that they
have been trained in the proper use, inspection, emergency use and limitations of the equipment by
a competent person. The training must be current within 12 months prior to the use of the
equipment.
Personnel who participate in permitted confined space entry, radiation work, asbestos work, lead
work, or work involving lockout/tagout of energy sources must provide the HSM written
048369 .0 I 21 6
EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A419
Ram Leather Site
Health & Safety Plan
Revision No. 0
December I 0, 2004
certification that they have been trained in accordance with the applicable OSHA regulations before
performing such work.
Personnel who use health and safety monitoring equipment other than the type and model provided
by the Black & Veatch equipment center must provide written certification to the HSM that they
have been trained in the use, maintenance, calibration and operation of the equipment by a
competent person before using the equipment.
4.1.1 Safety Meetings
Safety meetings with all team members will be conducted prior to initiating any site activity. In
addition, periodic briefings will be held throughout the project, especially when unsafe practices
are noted or a change in site conditions require modifications of the HASP. Periodic meetings will
be held at least weekly where applicable. Similar meetings will be held with individuals who later
become a part of the field team before they take part in site activities.
The Safety Meeting Checklist in Appendix 4 provides a guide of topics to be covered during the
initial briefing and may be covered during periodic meetings. The Safety Meeting Checklist will be
used to document the safety meeting topics discussed and attendance.
The SSC is responsible for conducting and documenting the pre-activity and periodic safety
meetings.
4.2 Medical Surveillance Program
All BVSPC personnel who participate in hazardous waste site investigations will be enrolled in a
medical monitoring program prior to initiating site activities. The medical monitoring program will
consist of an initial baseline examination, periodic monitoring examinations and an exit examination.
All Black & Veatch personnel who will be engaged in hazardous waste operations must present
to the SSC a certificate of completion ofacomprehensivemedical monitoring examination. The
medical examination must have been completed within 24 months prior to the beginning of site
activities. All Black & Veatch subcontract personnel who will be engaged in hazardous waste
048369.0121 7
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EPA Contract No,: 68-W99-043
Work Assignment No.: 369-RDRD-A419
Ram Leather Site
Health & Safety Plan
Revision No. 0
December I 0, 2004
operations must also present to the BVSPC SSC a certificate o fcompletion of a comprehensive
medical monitoring examination and the medical examination must have been completed within 12
months prior to the beginning of site activities. As a minimum, the medical monitoring examination
will include the elements listed in Appendix 5.
Site-specific medical monitoring examinations or tests may be required to augment the standard
examinations. Any additional examinations or tests required will be listed under the Site Speci fie
Medical Monitoring Requirements section of the Task HASP.
Personnel who have the potential to wear respirators must present to the SSC a written
documentation that a physician has determined that they are physically able to perform the work
and use the respirator, and that they have been trained in the use of the respirator.
048369.0121 8
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EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A4 l 9
Ram Leather Site
5.0 Personal Protective Equipment
5.1 General
Health & Safety Plan
Revision No. 0
December I 0, 2004
All site activities require the following personal protective equipment (PPE) to be worn as a
minimum.
• Safety glasses with side shields meeting the requirements and specifications of the
current American National Standards Institute (ANSI) Z87 standard.
• Steel-toed boots meeting the requirements and specifications for class 75
occupational foot protection of the current ANSI Z4 l standard.
The following PPE shall be provided, used and maintained in a sanitary and reliable condition
whenever it is necessary by reason ofhazards of processes or environment, chemical hazards,
radiological hazards or mechanical irritants encountered in a manner capable of causing injury or
impairment in the function of any part of the body through absorption, inhalation or physical
contact.
• Suitable eye protectors .
• Head protection .
• Extremities protection .
• Protective clothing .
• Shields and barriers.
• Face protection .
• Respiratory protection .
• Hearing protection .
5.2 Chemical Protective Equipment
5.2.1 Levels of Protection
Personnel will wear chemical protective equipment when activities involve known or suspected
atmospheric contamination; when airborne vapors, gases or particulate may be generated by site
activities; or when direct contact with skin-affecting substances may occur.
048369:0121 9
EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A419
Ram Leather Site
Health & Safety Plan
Revision No. 0
December I 0, 2004
The specific level of protection and necessary components for each have been divided into four
categories according to the degrees of protection afforded:
Level A: Should be worn when the highest level of respiratory, skin and eye protection is needed.
Note: Black & Veatch personnel are not-authorized to work at Level A without
additional training and written approval from the Black & Veatch HSM.
Level B: Should be worn when the highest level ofrespiratory protection is needed, but a lesser
level of skin protection. Level B is the primary level of choice when encountering
unknown environments.
Level C: Should be worn when the criteria for using air-purifying respirators are met and a lesser
level of skin protection is needed.
Level D: Should be worn as a basic work uniform and not in any area with respiratory or skin
hazards. It provides minimal protection against chemical hazards.
5.2.2 Chemical Ensembles
The following are the standard chemical protective equipment to be used for all hazardous waste
operations. Combinations of chemical protective equipment other than those described for levels
A, 8, C and D protection may be more appropriate and may be used to provide the proper level
of protection. Deviations from this standard are addressed in the Task HASP.
Leve!B PPE:
• Supplied-air respirator [Mine Safety and Health Administration/National Institute for
Occupational Safety and Health (MSHA/NIOSH) approved]. Respirators may be
positive pressure-demand self-contained breathing apparatus (SCBA) or positive
pressure-demand airline respirator (with escape bottle for IDLH or potential for IDLH
atmosphere).
• Hooded chemical-resistant one-piece suit (Saranex/Tyvek) with double bonded seams.
• Long cotton underwear ( optional).
• Outer gloves, chemical-resistant (11 mil nitrite).
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EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A4l9
Ram Leather Site
• Inner gloves, chemical-resistant (4 mil nitrile).
• Boots, chemical-resistant, steel toe.
• Outer boot covers, chemical-resistant, disposable.
• Face shield ( optional).
• Hardhat.
Level C PPE:
Health & Safety Plan
Revision No. 0
December I 0, 2004
• Air Purifying respirator (MSHA/NIOSH approved) with an organic vapor/acid gas/P 100
filter cartridge.
• Chemical-resistant one or two-piece suit (Saranex/Tyvek) with double bonded seams.
• Long cotton underwear ( optional).
• Outer gloves, chemical-resistant (11 mil nitrile).
• Inner gloves, chemical-resistant (4 mil nitrile).
• Boots, chemical-resistant, steel toe.
• Outer boot covers, chemical-resistant, disposable.
• Face shield ( optional).
• Hardhat.
Level D PPE:
• Tyvek for soil sampling, Saranex for water sampling.
• Boots, steel toe.
• Outer boot covers, chemical-resistant, disposable.
• Outer gloves, chemical-resistant (11 mil nitrile).
• Inner gloves, chemical-resistant (4 mil nitrile).
• Safety glasses with side shields.
• Hardhat.
5.3 Hazards and Protection Level
The types of hazards for which levels A, B, C and D protection are appropriate and described
below:
048369.0121 11
EPA Contract No.: 68-W99-043 Health & Safety Plan
Revision No. 0
December 10, 2004
Work Assignment No.: 369-RDRD-A419
Ram Leather Site
Level A protection should be used when:
•
•
•
The hazardous substance has been identified and requires the highest level of protection
for skin, eyes and the respiratory system based on either the measured ( or potential for)
· high concentration of atmospheric vapors, gases or particulate; or the site operations and
work functions involve a high potential for splash, immersion or exposure to unexpected
vapors, gases or particulate of materials that are harmful to skin or capable of being
absorbed through the skin.
Substances with a high degree of hazard to the skin are known or suspected to be
present and skin contact is possible.
Operations are being conducted in confirmed, poorly ventilated areas and the absence
of conditions requiring level A have not yet been determined.
Level B protection should be used when: ·
• The type and atmospheric concentration of substances have been identified and require
a high level ofrespiratory protection, but less skin protection.
• The atmosphere contains less than 19.5 percent oxygen.
• The presence ofincompletelyidentified vapors or gases is indicated by a direct reading
organic vapor detection instrument, but vapors and gases are not suspected of containing
high levels of chemicals harmful to skin or capable of being absorbed through the skin.
Note: This involves atmosphereswithIDLH concentrations of specific substances that present
severe inhalation hazards and that do not represent a severe skin hazard; or that do not
meet the criteria for use of air-purifying respirators.
Level C protection should be used when:
• The atmospheric contaminants, liquid splashes or other direct contact will not adversely
affect or be absorbed through any exposed skin.
• The types of air contaminants have been identified, concentrations measured and an
air-purifying respirator is available that can remove the contaminants.
• All criteria for the use of air-purifying respirators are met.
Level D protection should be used when:
• The atmosphere contains no known hazard.
048369.0121 12
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EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A4 I 9
Ram Leather Site
Health & Safety Plan
Revision No. 0
December I 0, 2004
• Work functions preclude splashes, immersion or the potential for unexpected inhalation
of or contact with hazardous levels of any chemicals.
5.4 Reassessment of Protection Level
The level of protection provided by PPE selection shall be upgraded or downgraded based upon
a change in site conditions or findings ofinvestigations. When a significant change occurs, the
hazards should be reassessed. Some indicators of the need for reassessment are:
• Airborne concentrations of chemicals or physical hazards exceed action levels.
• Commencement of a new work phase, such as the start of drum sampling or work that
begins on a different portion of the site.
• Change in job tasks during a work phase.
• Change of weather.
• When temperature extremes or individual medical considerations limit the effectiveness
ofPPE.
• Contamination other than those previously identified are encountered.
• Change in ambient levels of contaminants.
• Change in work scope which effects the degree of contact with contaminants.
• Detection of contamination by instrument, odor or sight.
5.5 Inspection of PPE
The userofthe PPE is responsible for inspecting the equipment prior to immediate use. The PPE
will not be used if the user is not familiar with the equipment's limitations.
The user's buddy is responsible for periodically checking on the proper use of the protective
equipment while in use.
5.6 Respiratory Protection
Respiratory protection at hazardous waste sites consists of a full face air purifying respirator as a
minimum. Any use of an air supplied system, ifrequired, will be specifically addressed in the Task
HASP. Personnel will not be assigned to tasks requiring use of respirators unless it has been
determined that they are physically able to perform the work and use the equipment. The
048369.0 I 21 13
EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A419
Ram Leather Site
Health & Safety Plan
Revision No. 0
December I 0, 2004
determination will be documented in writing and provided to the SSC in accordance with Section
4.2.
Personnel who have the potential to wear the respirator onsite must be trained in the proper use
of the respirators and their limitations. The training will allow users to handle their respirator to
become familiar with all components, select the proper size fora comfortable fit, wear it in normal
air to become used to the breathing resistance, visibly conduct a critical component inspection, and
administer a positive and negative pressure fit check.
Respirators are not to be worn when conditions prevent a good full seal. Such conditions may be
a growth ofbeard, sideburns, bangs, a skull cap or other clothing that projects under the facepiece
or temple pieces on glasses. To assure proper protection, the respirator will be thoroughly
inspected before each use and a positive and negative fit check will be performed each time the
respirator is donned.
Respirators will be assigned to individuals for their exclusive use during the project. Air purifying
respirators will be regularly cleaned and disinfected. As a minimum, respirators will be cleaned
after each day's use or more often if necessary. Upon completion of the work task, the respirators
will be disassembled, inspected, and thoroughly cleaned and disinfected. Worn or deteriorated
parts will be replaced and the respirators will be stored in a clean and sanitary location in individual
plastic bags.
Selection of the respirator is the responsibility of a person qualified by appropriate training or
experience and will be noted in the Task HASP. Selection will be based on the physical, chemical,
and physiological properties of the air contaminants and the concentration likely to be encountered.
The quality of fit and the nature of the work being performed will also affect the choice of
respirators. The capabilityofthe respirators chosen is determined from appropriate governmental
approvals, manufacturer's test, and the qualified person's experience with respirators.
All workers entering the Exclusion Zone or Contamination Reduction Zone at a site where use of
a respirator is necessary or anticipated, must have passed at least a qualitative fit test in accordance
048369.0121 14
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EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A419
Ram Leather Site
Health & Safety Plan
Revision No. 0
December I 0, 2004
with the guidelines established in the appendix of29 CFR 1910.1025. Personnel must have been
fit tested for the model and size ofrespirator issued to them. The fit test record must be current
within the previous twelve months.
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EPA Contract No.: 68-W99-043 Health & Safety Plan
Revision No. 0
December 10, 2004
Work Assignment No.: 369-RDRD-A419
Ram Leather Site
6.0 Monitoring Program
6.1 Real Time Monitoring
Direct reading instmments are used as real time air monitors. The results of the direct reading
instruments are compared to the Monitoring Equipment Action Levels (Appendix 6) that describes
the protective action that is to be taken to control exposure. The action levels describe the location
of the real time monitoring activity and the action to be taken if predefined values are met or
exceeded. Site specific operations or tasks may have other action levels established. Any change
to the action level task will be noted in the appropriate Task HASP.
The frequency and location ofall real time monitoring activity is based upon the natureofthe site
activity. Periodic real time monitoring will be performed, at a minimum, whenever the following
activities occur.
•
•
•
•
•
•
•
•
•
•
Beginning of site activity .
Operations change .
Work begins on a different portion of the site .
Beginning of invasive site activity .
Contaminants other than those previously identified are being handled.
Personnel begin to handle obviously contaminated materials .
Personnel are handling leaking drums or containers .
Personnel are performing tasks that are likely to expose them to peak levels of
contaminants.
Instrumental or sensible detection of the presence ofa chemical contaminant.
Change in the weather .
6.2 Air Monitoring Result Logging
Before any field activities commence, the background levels of the site must be read and recorded.
Daily background readings must be conducted away from areas of potential contamination to
obtain accurate results.
All monitoring results must be recorded in the field log. The monitoring results should indicate the
following information.
048369.0121 16
EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A419
Ram Leather Site
• Range of readings .
• Mode ofreadings .
• Time .
• Location of reading .
• Activity during reading .
• Weather conditions .
• Wind direction .
• Action taken.
6.3 Personal Monitoring -
Health & Safety Plan
Revision No. 0
December I 0, 2004
Personal monitoring will be performed whenever required by an OSHA chemical-specific standard
found in 29 CFR 1910 Subpart G or Z, or 1926 Subpart Dor Z when deemed necessary to
protect the health of the field team members. All personal monitoring will be performed in
accordance with accepted sampling and analytical procedures as defined by the HSM. Specifics
of the monitoring will be described in the Task HASP.
Personnel who are likely to have exposures above OSHA-Permissible Exposure Limits (PELs)
or published exposure levels for hazardous substances shall participate in a personal air sampling
program. Air monitoring shall be used to identify and quantify airborne levels of hazardous
substances in order to determine the appropriate level of employee protection needed onsite.
BVSPC personnel will be stationed upwind of intrusive activities. Specifics of the monitoring will
be described in the Task HASP.
6.4 Operation, Maintenance and Calibration
The SSC is responsible for the proper operation, maintenance and calibration of each instrument
to be used. The operation, maintenance and calibration instructions in the equipment manuals will
be followed. The equipment manuals will be kept in the support zone during field activities. As a
minimum, at the beginning of each day the instruments will be calibrated according to the manual.
At the end of each day, a check of the calibration of the instrument will be performed. This end
of the day check may be less stringent than the b_eginning of the day calibration as long as it verifies
accurate readings were taken through the day.
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EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A4l9
Ram Leather Site
6.5 Initial Survey
Health & Safety Plan
Revision No. 0
December I 0, 2004
Prior to any site activities, the SSC will conduct perimeter and general site monitoring, upwind and
downwind, to establish background levels.
If information from the site characterization indicates a potential for ionizing radiation or IDLH
condition onsite or ifinsufficient information is available to demonstrate otherwise, then monitoring
shall include: monitoring with direct reading ionizing radiation or IDLH conditions including oxygen,
explosive and toxic atmospheres; and visual observations for actual or potential IDLH conditions
onsite.
Upon initial entry to an area, representative air monitoring will be conducted using direct reading
instruments to identify IDLH conditions, exposures above OSHA PE Ls or other allowable
exposure levels, including exposure to radiation, flammable atmospheres or oxygen deficient
atmospheres.
6.6 Periodic Survey
Periodic monitoring shall be conducted when the possibility of an IDLH condition or flammable
atmosphere has developed or when there is and indication that exposure may have risen over
OSHA-PELs or published exposure levels for hazardous substances
After site activities have commenced, the selective monitoring ofhigh-risk workers, such as those
who are closest to the source of contaminant generation, is essential. Those employees working
closest with the source have the highest likelihood of being exposed to concentrations which
exceed established exposure limits or action levels.
Monitoring efforts will focus on personnel most likely to receive the highest exposures and on all
personnel likely to be exposed to any substance above the action level or OSHA PEL. High risk
workers will be monitored at least every 30 minutes when the potential for exposure exists.
Monitoring will be performed whenever new work begins on a different position of the site anytime
that new contaminants are encountered that differ from those initially encountered, every time a
048369.0 I 21 18
EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A4 l9
Ram Leather Site
Health & Safety Plan
Revision No. 0
December l 0, 2004
different operation is initiated, whenever employees are working in areas of obvious liquid
contamination or employees are handling leaking containers.
6_7 Perimeter Monitoring
The SSC is responsible for determining if site activities could negatively impact zones outside the
contamination reduction zone. If action levels for airborne contaminants listed in the Action Level
Table are exceeded, the SSC will perform monitoring at the perimeter of the contamination
reduction zone to determine if the contaminants are getting out of the controlled zones. If action
levels are exceeded at these locations, the SSC must advise the Project Manager (PM) and the
Black & Veatch HSM. If necessary the control zones will be expanded to compensate for the
presence of the contaminants.
If the release of contaminants could negatively impact the health and safetyofthe surrounding
areas, the SSC will contact the local emergency response organization responsible for protecting
public health from chemical exposures. This agency will be identified prior to the beginning of site
activities as part of the emergency preplanning procedures. The SSC will then notify the site
representative, PM and Black& Veatch HSM. The site manager(SM) will notifytheclientofthe
chemical release and the actions taken by the SSC. Notification will be made in accordance with
Section 9.6, Spills or Leaks.
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EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A4l9
Ram Leather Site
7.0 Site Control
Health & Safety Plan
Revision No. 0
December I 0, 2004
The objective of site control is to control the activities and movement of people and equipment at
hazardous waste sites in order to minimize the potential for worker or public exposure to hazardous
substances, the spread of hazardous substance in the environment or vandalism.
7.1 Site Mapping
Maps of the site are located in Appendix 1. The purpose of these maps are to assist site personnel
in planning and organizing response activities.
The Task HASP will contain site maps that are specific to the area where specific tasks will take
place. This map will include the following information: magnetic north, site drainage points,
previous sampling locations, planned sampling locations, locations of expected contamination,
planned control zones, all natural and man-made topographic features including the location of
buildings, containers, impoundments, pits, ponds, tanks and any other site features.
The Task HASP specific site map will be upgraded to reflect new information gained after initial
site entry or from subsequent sampling and analysis activities or changes in site conditions, including
changes resulting from accidents, ongoing site operations, hazards not previously identified, new
materials introduced onsite, unauthorized entry or vandalism or weather condi_tions.
Use of overlays or other mapping techniques may be used to reduce cluttering of information.
7.2 Work Zones
Work zones will be established to:
• Reduce the accidental spread of hazardous substances by workers or equipment from
the contaminated areas to the clean areas.
• Confine work activities to the appropriate areas, thereby minimizing the likelihood of
accidental exposure.
• Facilitate the location and evacuation of personnel in case of an emergency.
048369.012 I 20
EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A4 l 9
Ram Leather Site
Health & Safety Plan
Revision No. 0
December 10, 2004
To accomplish this, the site will be divided into as many zones as necessary to ensure minimal
employee exposure to hazardous substances. As a minimum, three zones will be identified,
including the Exclusion Zone, the Contamination Reduction Zone, and the Support Zone.
Movement of personnel and equipment between these zones should be minimized and restricted
to specific Access Control Points to prevent cross-contamination from contaminated areas to clean
areas.
The work site will be divided into the following three zones. These zones are established so field
personnel can identify where the site hazards exist. The work zones will be established so
nonessential personnel will not be affected by the hazards and the hazards do not leave the zones.
Details of the work site control zones will be established by the SSC prior to stating site activities
and will be established so that the support zone is upwind of the Exclusion Zone or at a distance
far enough away that it is not affected by the dispersion of contaminants from the Exclusion Zone.
Following is a description of each work zone and the factors to be considered when establishing
them.
7.2.1 Exclusion Zone
The Exclusion Zone is the innermost area of the three areas and is considered contaminated.
Within this area, levels of protection prescribed in the HASP will be used by all personnel. An
Access Control Point (ACP) will be established at the peripheryofthe Exclusion Zone to control
the flow of personnel and equipment between it and the Contamination Reduction Zone and to
check that entrance and exit procedures are followed. The extent of the Exclusion Zone is
determined by the following:
( 1) Location, nature and toxicity of the waste materials.
(2) Meteorological conditions affecting potential dispersion of contaminants.
(3) Concern for minimal exposure of the unprotected public and investigation personnel.
(4) Topography.
048369.012 I 21
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EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A4 I 9
Ram Leather Site
Health & Safety Plan
Revision No. 0
December I 0, 2004
The Exclusion Zone boundary ("hot line") will be established at a reasonably safe distance from
drums, tanks, ponds, liquid run-off or other physical indicators ofhazardous substances. This
distance will be established by the SSC before site activities begin and will take into account such
factors as physical condition of site, weather conditions, sources of potential hazard and duration
of activity. Subsequent to the start of operations, the boundary may be readjusted based on
observation or measurements. The boundary will be physically secure and posted, well defined
by geographical boundaries or otherwise delineated.
The Exclusion Zone could be further divided into zones with different levels of protection for each
zone. Based upon environmental measurements or expected onsite work practices, locations
within the Exclusion Zone would be defined in accordance with the level of protection required for
that area. This procedure would allow for more flexibility in operation, decontamination
procedures and resource utilization.
7.2.2 Contamination Reduction Zane
The area between the Exclusion and Support Zones is the Contamination Reduction Zone. The
purpose of the Contamination Reduction Zone is to prevent the transfer of contaminants that may
have been picked up by personnel or equipment leaving the Exclusion Zone. An area within the
Contamination Reduction Zones is the Contamination Reduction Corridor (CRC). The CRC is
a path that persons or vehicles must take during decontamination. The CRC controls access into
and out of the Exclusion Zone and confines decontamination activities to a restricted area. The
CRC must be laid with plastic sheeting or equivalent.
At the boundary between the Contamination Reduction Zone and the Exclusion Zone is the hot line
and access control point. Entrance into the Exclusion Zone requires the wearing of the prescribed
personal protection equipment and adherence to established site entry procedures. Equipment
requirements for working in the Contamination Reduction Zone may be different than those for the
Exclusion Zone. At a point close to the hot line, a decontamination station will be established for
both personnel and equipment exiting the Exclusion Zone. Another decontamination station may
be established closer to the contamination control line for those working only in the Contamination
Reduction Zone. In addition, a vehicle decontamination station wi 11 be established as necessary.
048369.0121 22
EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A419
Ram Leather Site
Health & Safety Plan
Revision No. 0
December I 0, 2004
The boundary between the Support Zone and the Contamination Reduction Zone is the
contamination control line. Entry into the Contamination Reduction Zone from the Support Zone
will be through a common point. Personnel entering at this station must be wearing the prescribed
PPE for working in the decontamination area. Exiting the Contamination Reduction Zone to the
Support Zone requires the removal of any suspected contaminated personal protection equipment
and compliance with decontamination procedures.
All facilities and operations located in the Contamination Reduction Zone will be positioned upwind
of the actual waste location whenever possible.
7.2.3 Support Zone
The Support Zone is the outermost region and is considered anon-contaminated or clean area.
It will contain the field office, first aid area and other facilities necessary to support site activities.
Change rooms, lunch and break areas, supplies, equipment storage and maintenance areas may
be located in this area. Onsite eating, drinking and smoking will be allowed only in this area.
Support facilities will be located upwind from the Exclusion and Contamination Reduction Zones
in relation to the prevailing wind whenever possible.
A support center or command center will be established in the Support Zone for each activity and
will include the following as a minimum:
• Fully stocked industrial first aid kit.
• 15 minute eye wash station -as needed.
• Fire extinguisher (10A60BC multipurpose dry chemical).
• Telephone or radio communications capability.
• Posted emergency telephone numbers.
• Posted HASP.
• Posted OSHA "Job Safety and Health Protection" poster.
• Posted OSHA Noise standard -as needed.
• Copy of Black & Veatch "Focus on Health and Safety".
• Posted map with route to hospital.
• [nstrument manuals.
• Binder of MSDS.
048369 .0 I 21 23
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EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A4 I 9
Ram Leather Site
Health & Safety Plan
Revision No. 0
December I 0, 2004
At the discretion of the SSC, the support center may be based in an onsite vehicle.
7.3 Buddy System
Except for Level D work involving nonintmsive methods, the implementation ofa buddy system
is mandatory for entry into the Contamination Reduction Zones or the Exclusion Zone. The prime
objective of the buddy system is to ensure rapid assistance in the event ofan emergency.
Each memberofthe field team will be designated by the SSC to observe at least one other field
team member. The SSC will implement the system at the Access Control Point for personnel
entering the Exclusion Zone.
As part of the buddy system, workers will remain close together and maintain visual contact with
each other to provide assistance in the event of an emergency. Should an emergency situation
arise, workers will use the communication signals established and agreed upon prior to entering the
contaminated area. The communication signals are located in Section 8.7.3.
The responsibilities of workers utilizing the buddy system include:
•
•
•
•
•
Providing their buddy with assistance .
Observing their buddy for signs of chemical exposure .
Observing their buddy for signs of stress due to temperature extremes.
Observing their buddy for signs of stress or anxiety while wearing chemical protective
clothing.
Periodically checking the integrity of their buddy's PPE .
Notifying the SSC or other site supervisory personnel if emergency assistance is
needed.
Workers should not rely entirely on the buddy system to ensure that help will be provided in the
event of an emergency. To augment this system, workers in contaminated areas should, whenever
possible, remain in line-of-sight or communication contact with the SSC or other personnel in the
Sup port Zone.
048369.0121 24
EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A4l9
Ram Leather Site
7.4 Audits
Health & Safety Plan
Revision No. 0
December I 0, 2004
Inspection and audits of the work area will be conducted by the SSC as necessary to determine
the effectiveness of the HASP or Task HASP. The HASP and Task HASP will be periodically
reviewed by the SSC to keep it current with respect to site conditions. The SSC will report their
findings to the site manager. Correcting deficiencies in the effectiveness and application of the
HASP is the responsibility of the site manager. Changes to the HASP to address any deficiencies
will be made to the Task HASP in accordance with the Section 12 of the Task HASP.
7.5 Visitors
Black & Veatch recognizes that all visitors' employers are ultimately responsible for their
compliance with all applicable OSHA regulations while on a hazardous waste site. Black &
Veatch personnel will be courteous to all visitors and adhere to the following procedures for the
safety sake of the visitors.
• Visitors are expected to have the permission of the site owner to be on the site.
• The SSC will advise all visitors of the nature, level and degree of exposure likely as a
result ofBlack & Veatch related activities and the emergency response procedures that
pertains to the visitors for the site.
• The SSC will advise all subcontractors coming onto the site of the hazardous chemicals
present, effect ofexposure, location of the MSDSs, location of the emergency equipment
and the emergency plan and evacuation procedures.
• Visitors entering the Contamination Reduction Zone and Exclusion Zone at the Site will
be offered an opportunity to read the applicable provisions of this HASP.
• Visitors will be expected to comply with OSHA requirements such as medical
monitoring, training and respiratory protection.
• Visitors will be expected to provide their own PPE.
• In the event that a visitor does not adhere to the provisions of the HASP, the SSC will
request the visitor to leave the work area.
• If the visitor interferes with the work activity or poses a safety hazard to anyone onsite,
the SSC will terminate work activities and the Black & Veatch PM and HSM will be
contacted immediately.
• All nonconformance incidents will be recorded in the site log by the SSC.
• The client and governmental authorities may choose to adopt this plan or develop their
own to protect their onsite employees, although Black & Veatch will not take
responsibility for compliance of onsite personnel employed by these parties.
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EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A4l9
Ram Leather Site
8.0 Safety and Emergency Procedures
8.1 Standing Safety Orders
Health & Safety Plan
Revision No. 0
December I 0, 2004
The following standing orders are established to ensure safe work practices. Task specific standing
orders are addressed in the Task HASP.
• Report any sign of radioactivity, explosivity or unusual conditions to the supervisor
immediately.
• Check in and out at the entrance ACP of the Exclusion Zone.
• Maintain close contact with your buddy in the Exclusion Zone.
• Eating, drinking, chewing gum or tobacco, smoking or any practices that increases the
probability ofhand-to-mouth transfers and ingestion of material is prohibited in any
controlled area such as Contaminant Reduction Zone and Exclusion Zone.
• Whenever decontamination procedures for outer garments are in effect, good personal
hygiene will be practiced as soon as possible after the protective garment is removed
(i.e., washing hands). A shower is recommended immediately after any work period.
• No facial hair that interferes with the effectiveness of a respirator will be permitted on
personnel required or potentially required to wear respiratory protection equipment.
• Contact with potentially contaminated surfaces will be avoided whenever possible.
Personnel should not walk through puddles, mud orother discolored surfaces or kneel
on the ground. Personnel should not lean, sit or place equipment on drums, containers,
vehicles or exposed surfaces without plastic covering.
• Medicine and alcohol can magnify the effect from exposure to certain compounds. It will
be responsibility of each Black & Veatch employee and each subcontractor to notify, on
a daily basis, the SSC of any individual who is using prescribed medication. Site
personnel will not be allowed onsite while under the influence of alcohol or drugs that
cannot be obtained over the counter without a physician's authorization.
• Personnel and equipment in the work areas will be minimized, but consistent with
effective site operations.
• All unsafe or inoperable sampling or monitoring equipment left unattended will be
identified by the SSC by a "DANGER-DO NOT OPERA TE". tag.
• Work will be restricted to daylight hours only.
8.2 Medical Emergencies
At least two Black & Veatch team members conducting hazardous waste operations at the site will
have successfully completed a certified course in adult first aid and CPR. Prior to the start of
048369.0121 26
EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A4 l 9
Ram Leather Site
Health & Safety Plan
Revision No. 0
December I 0, 2004
work, the SSC will make arrangements for medical facilities, ambulance service and medical
personnel to be available for prompt attention to the injured.
Onsite activities will require a first-aid station which will be located within the Support Zone.
First-aid kits will be, as a minimum, 16-unit first-aid kits and will be provided in the ratio ofone for
each 10 persons.
Portable 15-minute emergency eye-wash stations will be provided as needed within the Support
Zone. Identification markers will be provided to readily denote locations of the eyewash stations.
Emergency telephone numbers and reporting instructions for ambulance, local physician, hospital,
poison control center, fire and police will be conspicuously posted in the Support Zone.
The SSC will act as the emergency coordinator for all medical emergencies. If a person is injured
or becomes ill, personnel identified as trained in first aid and CPR will be notified immediately.
First aid and CPR will be administered immediately. In all cases, treatment for shock should be
considered. After attending to the victim, the SSC will be notified. Depending on the severity of
the injury or illness, the SSC may notify medical emergency response organizations. If the victim
is transferred off-site, the SSC will assign a field team member to accompany the victim.
B-2.1 Chemical Exposure Emergency
If personnel experience any adverse effects or symptoms during field activity, the individuals will
notify the SSC. The SSC will assess the situation and make a determination on the extent of
medical attention needed. Ifit is determined that the problem was due to chemical exposure, first
aid for chemical exposure will be administered as soon as possible. If necessary to transport the
individual to the hospital the individual( s) exposed to those chemicals will be transported by an
unexposed individual. The Site HASP and available MSDSs will accompany the group to the
hospital. The incident must be reported to the HSM immediately. A written report of the incident
will be distributed to the PM and the HSM within 48 hours.
048369.0 I 2 I 27
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EPA Contract No.: 68-W99-043 Health & Safety Plan
Revision No. 0
December l 0, 2004
Work Assignment No.: 369-RDRD-A4 I 9
Ram Leather Site
The following first aid for chemical exposures will be administered as soon as possible;
Eye Exposure If contaminated solid or liquid gets into the eyes, they will be washed
immediately at the 15 minute emergency eyewash station using large amounts
of water and lifting their lower and upper lids occasionally. Medical attention
will be obtained immediately. (Personnel that wear contacts while working
onsite must notify the SSC prior to commencing work).
Skin Exposure If contaminated solid or liquid gets on the skin, the affected individual will
Inhalation
Ingestion
promptly flush the skin for at least 15 minutes, then wash with soap or mild
detergent and water. If contaminated solids or liquids penetrate through the
clothing, clothing will be immediately removed and treatment for skin exposure
administered. Medical attention will be obtained if symptoms warrant.
If a person breathes in a large volume of potentiallytoxic contaminants, the
affected person will be moved to fresh air at once. lfbreathing has stopped,
CPR will be performed. The affected person will be kept warm and at rest.
Medical attention will be obtained immediately.
If contaminated solid or liquid is swallowed, medical attention will be obtained
immediate! y.
8.2.2 Accident Reporting
Iajuries or illnesses that require attention beyond simple first aid or requiring attention by a physician
or involve exposure to blood or other potentially infectious materials must be reported to the
Worker's Compensation Administrator and Black & Veatch HSM as soon as possible but no later
than 24 hours after the accident. In the event of a fatality or more than one hospitality, the
notification to the Black & Veatch HSM must be immediate. The Black & Veatch HSM
notification to the local OSHA area office must be within 8 hours. The SSC must complete the
appropriate accident report forms and the required State Workers Compensation form. The SSC
is responsible for contacting the State Worker's Compensation Office to obtain the necessary
report form. The SSC is responsible for completing the forms and submitting the originals to the
Black & Veatch HSM. Copies should be sent to the Workers Compensation Administrator and
PM. Copies must be filed in the project file.
048369.0121 28
EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A419
Ram Leather Site
Accidents that must be reported include:
Health & Safety Plan
Revision No. 0
December I 0, 2004
•
•
•
Injury or illnesses that require attention beyond simple first aid . Injury or illnesses that require attention by medical professionals . Injury or illnesses that result in time away from work . •
•
•
•
Injury or illnesses that restricts the ability of the injured to work.
Unconsciousness, explained or unexplained .
Exposures of personnel to blood or other potentially infectious agents . Exposures to chemical or physical agents that result in adverse signs or symptoms .
All incidents that are near miss injury or illness accidents or physical accidents must be summarized
on the hazardous waste site investigation activity report form and submitted to the PM and Black
& Veatch HSM as soon as possible.
The SSC is responsible for investigating the cause of all accidents and report on the findings and
corrective actions taken in the manner described above. The SSC may request the assistance of
the Black & Veatch HSM or other personnel to investigate the accident. The final report on the
accident is the responsibility of the SSC.
Accident investigation and record keeping must comply with the Black & Veatch accident
investigation and record keeping standard operating procedure.
8.2.3 Hospital Route
The route to the hospital is shown and desc_ribed in Appendix 1. The route to the hospital will be
conspicuously posted in the Support Zone. The SSC and key field personnel will drive the route
to the hospital emergency room door prior to the start of site activities in order to become familiar
with the route. The route will be driven at least weekly to confirm an unobstructed route.
8.3 Temperature Extremes
8.3.1 Heat Stress Monitoring
Heat stress poses a serious health danger to site workers and may create secondary safety hazards
by impairing a worker's coordination and judgement. Heat stress can occur at almost any
temperature and is more likely when PPE is in use.
048369.0121 29
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EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A4 I 9
Ram Leather Site
Health & Safety Plan
Revision No. 0
December I 0, 2004
The use of protective equipment may create heat stress. Monitoring of personnel will commence
when the ambient temperature is 70°F or above. Table 8-1 presents the suggested frequency for
such monitoring. Monitoring frequency is dependent on the type of protection worn (permeable
or impermeable clothing), the dry bulb temperature and the amount of sunshine. Monitoring
frequency should increase as the ambient temperature increases or as slow recovery rates are
observed. Heat stress monitoring should be performed by a person with a current first aid
certification who is trained to recognize heat stress symptoms. For monitoring the body's response
to excess heat, one or more of the following techniques will be used.
048369.0121 30
EPA Contract No.: 68-W99-043 Health & Safety Plan
Revision No. 0
December I 0, 2004
Work Assignment No.: 369-RDRD-A4 l 9
Ram Leather Site
Table 8-1
Suggested Frequency of Physiological Monitoring for Fit and Acclimatized \Yorkers
a
b
C
d
•
•
Adjusted Temperatureb Normal Work Ensemble' Impermeable EnsembJed
90 °P (32.2 °C) After each 45 minutes of After each 15 minutes of
or above work work
87.5 to 90 °P After each 60 minutes of After each 30 minutes of
(30.8 to 32.2 °C) work work
82.5 to 87.5 °P After each 90 minutes of After each 60 minutes of
(28.1 to 30.8 °C) work work
77.5 to 82.5 °P After each 120 minutes of After each 90 minutes of
(25.3 to 28.1 °C) work work
72.5 to 77 .5 °P After each 150 minutes of After each 120 minutes of
(22.5 to 25.3 °C) work work
For work levels of 250 kilocalories/hour.
Calculate the adjusted air temperature (ta adj) by using the equation:
ta adj °F = ta °F + (13 x (% + 100) sunshine).
Measure air temperature (ta) with a standard alcohol-in-glass thermometer or equivalent, with the
bulb shielded from radiant heat.
Estimate percent sunshine by judging the percent of time the sun is not covered by clouds that are thick enough to produce a shadow ( 100% sunshine= no cloud cover and a sharp distinct shadow;
0% sunshine= no shadows).
A normal work ensemble consists of cotton overalls.
An impermeable ensemble consists of tvvek overalls.
Heart rate. Count the radial pulse before site activities and during a 30-second period as
early as possible in the monitoring cycle.
If the heart rate exceeds 110 beats per minute at the beginning of the rest period,
shorten the next cycle by one-third and keep the rest period the same.
If the heart rate still exceeds 110 beats per minute at the next rest period, shorten
the following cycle by one-third.
Oral temperature. Use a clinical thermometer (three minutes under the tongue) or similar
device to measure the oral temperature before site activities and at the end of the
monitoring cycle (before the worker drinks liquid).
048369.0121 31
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EPA Contract No.: 68-W99-043 Health & Safety Plan
Revision No. 0
December IO, 2004
Work Assignment No.: 369-RDRD-A419
Ram Leather Site
If oral temperature exceeds 99.6°F (37.6°C), shorten the next work cycle by
one-third without changing the rest period.
-If oral temperature still exceeds 99.6°F (37.6°C) at the beginning of the next rest
period, shorten the following cycle by one-third.
-Do not permit a worker to wear a semipermeable or impermeable garment when
oral temperature exceeds I 00.6°F (38.1 °C).
Heat stroke is a life-threatening heat disorder that requires life-saving first aid. Decontamination
should be omitted prior to obtaining immediate medical attention.
Heat stress can become life threatening. Unless the victim is grossly contaminated,
decontamination should be omitted or minimized and treatment begun immediately.
• Prevention of Heat Stress. Proper training and prevention measures will aid in
averting serious illness and loss of productivity. Heat stress prevention is particularly
important because once a person suffers from heat stroke or heat exhaustion that
person may be predisposed to additional heat-related illnesses. To avoid heat stress,
the SSC has the authority to take the following steps.
• Adjust work schedules
Modify work/rest schedules according to monitoring requirements.
Mandate work slowdowns as needed.
Perform work during cooler hours of the day if possible or at night if adequate
lighting can be provided
• Provide shelter (air-conditioned, if possible) or shaded areas to protect personnel
during rest periods.
• Maintain worker's body fluids at normal levels. This is necessary to ensure that the
cardiovascular system functions adequately. Daily fluid intake must approximately
equal to the amount of water lost in sweat, e.g., eight fluid ounces (0.23 liters) of
water must be ingested for approximately every eight ounces (0.23 kg) of weight loss.
The normal thirst mechanism is not sensitive enough to ensure that enough water will
be drunk to replace lost sweat. When heavy sweating occurs, the workers will be
encouraged to drink more. The following strategies may be useful:
• Provide drinking water as needed
048369.0121
Maintain water temperature at 50 to 60°F (IO to 16.6°C).
Provide dedicated personal bottles or containers that hold about I quart of
water.
Dedicated personal bottles of water should be allowed in the Contamination
Reduction Zone.
32
EPA Contract No.: 68-W99-043 Health & Safety Plan
Revision No. 0
December 10, 2004
Work Assignment No.: 369-RDRD-A4l9
Ram Leather Site
I
•
•
•
Have workers drink 16 ounces (0.5 liters) of fluid (preferably water or diluted drinks) before beginning work.
Urge workers to drink a cup or two every 15 to 20 minutes or at each break. A total of 1 to 1.6 gallons ( 4 to 6 liters) of fluid per person per day are
recommended, but more may be necessary to maintain body weight.
An additional water source should be maintained outside of Contamination
Reduction Zone.
Train workers to recognize the symptoms ofheat_-related illnesses. Table 8-2 presents a summary of typical symptoms and treatment of heat stress.
Source of water should be available to spray down a person as a measure of preventing or treating heat stress.
Table 8-2
Heat Stress Symptoms and Treatment
Type I Symptoms I Treatment I
Heat Related Localized redness of skin Keep skin clean and dry.
Illness and reduced sweating;
reduced tolerance to heat.
Heat cramps Muscle spasm and pain in Remove person to cool area. Give small
extremities and abdomen. amounts of salted water.
Heat Weak pulse; shallow Remove person to cool area, reduce bod) Exhaustion breathing; pale, cool, moist temperature. Cool by convection. Give . skin; profuse sweating; small amounts of salted water. Do not
dizziness; fatigue. allow person to become chilled.
Heat stroke Red, hot, dry skin; body Seek medical attention immediately. Ge temperature of 105 °F or victim cool quickly, wrap in wet cloth,
greater; nausea; dizziness; spray with cool water or immerse in cool
confusion; strong rapid water. Fan vigorously during transport tc
pulse; coma. Convulsions hospital. Apply cold packs, if available,
may occur. avoiding direct contact between skin and
oack/ice.
048369.0121 33
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EPA Contract No.: 68-\¥99-043
Work Assignment No.: 369-RDRD-A419
Ram Leather Site
8.3.2 Cold Stress Monitoring
Health & Safety Plan
Revision No. 0
December I 0, 2004
When ambient temperature reaches 45°F or below steps should be taken to prevent cold stress.
Excessive exposure to low environmental air temperatures or immersion in low temperature water
are usually fatal unless quickly remedied. Workers must be protected from exposure to cold so
that the deep core temperature of the body does not fall below 96.8°F.
Pain in the extremities may be the first early warning of danger to cold stress. Severe shivering may
occur if the body temperature drops to 95°F. Workers exhibiting signs of cold stress or
hypothermia must get to a warm area.
• At air temperatures o f2°C (3 5 .6°F) orless, it is imperative that workers who become
immersed in water or whose clothing becomes wet be immediately provided a change
of clothing and be treated for hypothermia.
• Provisions for additional total body protection are required if work is performed in an
environment at or below 4°C ( 40°F). The workers shall wear cold protective clothing
appropriate for the level of cold and physical activity.
• [fonly light work is involved and if the clothing on the worker may become wet on the
job site, the outer layer of the clothing in use maybe ofa type impermeable to water.
With more severe work under such conditions, the outer layer should be water repellent
and their outerwear should be changed as it becomes wetted. The outer garments must
include provisions for easy ventilation in order to prevent wetting of inner layers by sweat.
If work is done at normal temperatures or in a hot environment before entering the cold
area, the employees shall make sure that their clothing is not wet as a consequence of
sweating. If their clothing is wet, the employee shall change into dry clothes before
entering the co Id area.
• The workers shall change socks and any removable felt insoles at regular daily intervals
or use vapor barrier boots. The optimal frequency of changes shall be determined
empirically and will vary individually and according to the type of shoe worn and how
much the individual's feet sweat.
048369.0121 34
EPA Contract No.: 68-W99-043
Health & Safety Pian
Revision No. 0
December 10, 2004
Work Assignment No.: 369-RDRD-A4 I 9
Ram Leather Site
•
•
•
If extremities, ears, toes and nose, cannot be protected sufficiently to prevent sensation
of excessive cold or frostbite by hand ware; footwear and face masks, these protective
items shall be supplied in auxiliary heated versions.
If the available clothing does not give adequate protection to prevent hypothermia or
frostbite, work shall be modified or suspended until adequate clothing is made available
or until weather conditions improve.
The recommended limits for properly clothed workers for periods of work at
temperatures below freezing are listed in Table 8-3.
048369.0121 35
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EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A419
Ram Leather Site
Table 8-3
Health & Safety Plan
Revision No. 0
December I 0, 2004
Cold 'Work Environment Work Practice
Estimated Actual Tern Wind Speed
(in mph)
calm
5
10
15
20
25
JO
35
40
(Wind ss::1s greater 40
mJch have little
a ditional effect.)
50 40 JO
48 37 27
40 28 16
36 22 9
32 18 4
JO 16 0
28 13 -2
27 II -4
26 10 -6
Little Dan~er In <hr wit dry skin.
Maximum danger of false
sense of security.
20 0
16 -5
4 -9 -]]
-5 -32 -45
-10 -25 -39 -53
-15 -29 -44 -59
-18 -33 -48 -63
-20 -35 -51 -67
-21 -37 -53 -69
[ncreasing Danger
Danger from freezing
of exposed flesh
within I min.
-JO -40 -50 -60
-26 -36 -47
-46 -58 -83 -95
-58 -85 -99 -112
-82 -96 -110 -121
-74 -88 -104 -118 -133
-79 -94 -109 -125 -140
-82 -98 -113 -129 -145
-85 -100 -116 -132 -148
Great Oan\er Fle;h may eeze within 30 seconds.
Trenchfoot and immersion foot may occur at any point on this chart.
*Developed by U.S. Army Research Institute of Environment.al Medicine, Natick, MA.
Work/Warmup Schedule for 4~hour Shift*
Air Temperature No Noticeable 5 mph Wind 10 mph Wind 15 mph Wind 20mph Wind Sunny Sky Wind
'C 'F Max. No. of Max. No.of Max. No. of Max. No. of Max. No. of (appr.) Work Breaks Work Breaks Work Breaks Work Breaks Work Breaks Period Period Period Period Period
I. -26 -IS to 1 Nonna\ Break I Nonna! Break 75 2 55 3 40 4 to -28 -19 min min min
2. -29 -20 to I Normal Break 75 2 55 J 40 4 30 5 to -3 I -24 min min min min
3. -32 -25 to 75 2 55 J 40 4 JO 5 Non-emer~ency to -34 -29 mm min mm min work shou d
ce-J.se 4. -35 -30 to 55 J 40 4 30 5 Non-emer~ency to -37 -34 min min mm work shou d
cease
5. -38 -35 to 40 4 JO 5 Non-emer~ency to -39 -39 min min work shou d
cease
6. -40 -40 to JO 5 Non-emer~ency to -42 -44 mm work shou d cease
7. <-45 Non-emer~ency <-43 work shou d
cease
Schedule applit. .. "S to moderate to heavy work activity with warmup breaks of IO minutes in a warm location. For light to
moderate work (limited physical movement) apply the schedule one step lower. For example, at -30 °F with no noticeable wind
(Step 4), a worker at a job with little physical movement should have a maximum work period of 40 minutes with 4 breaks in
a 4-hour period (Step 5).
The following is suggested as a guide for estimating wind velocity. If accurate information is not available: 5 mph -light flag
moves; lO mph -light flag fully extended; 15 mph -raises newspaper sheet; 20 mph -blowing and drifting snow.
048369.0121 36
EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A4 I 9
Ram Leather Site
8.4 Decontamination Procedures
8.4. 1 General
Health & Safety Plan
Revision No. 0
December I 0, 2004
All personnel and equipment will be properly ·decontaminated prior to leaving a site ..
Decontamination methods could involve (I) physically removing contaminants, (2) neutralizing
contaminants by chemical detoxification or disinfection, or (3) removing contaminants through a
combination of both physical and chemical means. The types, locations, physical states and
concentrations of contaminations present will determine th_e degree of decontamination necessary.
As part of the system to prevent these physical transfers of contaminants bypeopleor equipment
from onsite to off-site areas, site specific procedures will be instituted for decontaminating all items
leaving the Exclusion Zone and the Contamination Reduction Zone. These procedures will include
the decontamination of PPE, vehicles and all field equipment and use of correct methods of
removingPPE to avoid transferof contaminants from the clothing to the body and decontamination
or disposal. In addition to the decontamination procedures, specific entry and exit routes through
the Contamination Reduction Zone will be established for personnel, equipment and vehicles to
minimize the possibilities of additional spread of contaminants. These site specific decontamination
procedures are described in the Task HASP.
Equipment that is not decontaminated or not completely decontaminated will be disposed onsite
or transferred in a controlled manner for subsequent decontamination in controlled situation. Such
equipment will be bagged or wrapped in plastic for transferring to the decontamination location.
The outside container of the equipment must be labeled as contaminated and list the potential
contaminants and associated hazards. In order to minimize the need to decontaminate equipment,
this type of equipment may be packaged or wrapped in a material that will protect them from
contamination but does not interfere with their proper operation.
The initial decontamination plan is based upon a nominal case situation. This initial decontamination
plan \viii be modified, adding necessary stations or otherwise adapting it to site conditions when a
worst-case situation occurs. Changes in the decontamiriation plan will be made and noted in the
Task HASP by the SSC. If, on visual examination, chemical protective clothing appears grossly
contaminated, a thorough decontamination is required.
048369.0121 37
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EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A419
Ram Leather Site
Health & Safety Plan
Revision No. 0
December I 0, 2004
The SSC is responsible for selecting and monitoring the decontamination procedures to verify their
effectiveness of decontamination. When the decontamination procedures are found to be
ineffective, appropriate steps will be taken to correct the deficiencies. Methods that have proven
to be effective in removal of contaminants are included in Appendix 7.
8.4.2 Emergency Decontamination
In a medical emergency, the primary concern is to prevent the loss oflife or severe injury to site
personnel. Any person who becomes ill or injured in the Exclusion Zone must be decontaminated
to the maximum extent possible before providing the necessary first aid or before permitting the
person to enter the Support Zone.
If the patient's condition is serious, at least partial decontamination should be completed. This may
be accomplished by:
• Complete disrobing of the patient and redressing in clean coveralls.
• Wrapping patient in a blanket or plastic.
• Spot decontamination.
If the injury or illness is minor, full decontamination will be completed and first aid administered
prior to transport. The SSC will select the degree of needed decontamination in proportion to the
potential hazards posed by the contaminants. When a person who is not fully decontaminated that
requires transportation to the hospital, the SSC will have the surfaces covered with plastic to
prevent spreading contamination. First aid should be administered while awaiting an ambulance
or paramedics.
8.4.3 PPE
Personnel leaving the Exclusion Zone must remove potential contaminants in an orderly and
controlled manner in order to avoid contamination of the person. Primary means ofavoiding
contamination of the person is to minimize contact with contaminants during site activities.
Secondary means is to assume contamination and systematically reduce the contamination prior
to doffing.
048369.0121 38
EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A419
Ram Leather Site
Health & Safety Plan
Revision No. 0
December I 0, 2004
Personal decontamination involves the sequential doffing of PPE, starting with the most heavily
contaminated and working to the least contaminated. This progression, in combination with
separating each step of the decontamination procedure by a minimum of three feet, ensures
contamination decreases as the person moves from one station to another further along the line.
Wash and rinse steps may be needed in order to reduce the level of contamination to a level safe
to handle. Since it is virtually impossible to prevent the transfer of contaminants on protective
clothing to the wearer, thorough decontamination of the chemical protective clothing is necessary.
When done effectively the amount of substance remaining on the chemical protective clothing is
greatly reduced and the possibility of transfer is proportionately reduced. Therefore, heavily
contaminated disposable chemical protective clothing should be washed and rinsed to minimize the
spread of the contaminants during doffing. Unsoiled disposable chemical protective clothing may
not require the wash and rinse steps.
Polyethylene plastic sheeting will be placed on the ground in the personal decontamination corridor
and the decontamination stations arranged on the top of the plastic. The first station will be located
within the Exclusion Zone and will be the station where gross contamination is removed.
As a minimum, the level of protection required for the personnel assisting with personal
decontamination will be the most protective of either Level Dor one level less than the level worn
in the Exclusion Zone.
The SSC is responsible for monitoring the effectiveness of the decontamination procedures.
8.4.4 Instruments
Instrument decontamination requires that, as a minimum, all external surfaces and surfaces that
came in contact with the contaminants be wiped with a cloth dampened with a trisodium phosphate
detergent and wiped dry. Contamination should be prevented by packaging or wrapping the
instrument in a material that will protect them from contamination but does not interfere with the
proper operation.
048369.0121 39
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EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A4 I 9
Ram Leather Site
Health & Safety Plan
Revision No. 0
December I 0, 2004
Instrnments that are internally contaminated or not completely decontaminated will be transferred
in a controlled manner for subsequent decontamination. Such instruments will be bagged or
wrapped in plastic for transferring to the decontamination location. The outside container of the
instrnment must be labeled as contaminated and list the potential contaminants and associated
hazards.
8.4.5 Equipment
Equipment that came in direct contact with the contaminant must be decontaminated and shown
to be clean before returning it to the owner or equipment center.
8.4.6 Decontamination Solutions
The standard decontamination solutions will be a solution of Alconox ® or equivalent detergent.
Generally a solution of trisodium phosphate detergent is sufficient for most site applications. The
decontamination solution should be prepared in accordance with the manufacturer's instructions.
[n general, potable water is a sufficient rinse, although for specific equipment, decontamination may
require the use of deionized or distilled water. Other decontamination solutions are listed in
Appendix 7.
8.4. 7 Vehicle Decontamination Station
At sites where drill rigs or other vehicles are used for onsite activities, it may be necessary to
construct a vehicle decontamination station (VDS) to prevent the spread of contaminants to off-site
locations. Typically, the VDS is a sloping area lined with plastic sheeting and gravel so that
decontamination solutions can flow into a lined collection pit, sump or trench. The pit contents can
then be pumped into Department ofTransportation (DOT) approved 55 gallon drums or containers
for later disposal. Other VDS configurations include plastic sheeting with wood runways to
accommodate vehicles.
It is imperative that all vehicles used onsite be thoroughly decontaminated before being allowed to
leave the site. Special attention should be paid to the treads or tracks and interior surfaces.
Decontamination can be expedited if vehicle interiors are lined with plastic sheeting prior to
commencing onsite activities.
048369.012 I 40
EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A4l9
Ram Leather Site
Health & Safety Plan
Revision No. 0
December I 0, 2004
When using a central vehicular decontamination station, gross dirt must be removed from the
vehicle before leaving the Contamination Reduction Zone.
8.5 Disposition of Decontamination Wastes
All materials and equipment used for decontamination must be disposed of properly. Clothing,
tools, buckets, brushes and other equipment that is contaminated must be secured in containers and labeled. Clothing not completely decontaminated onsite should be double bagged before being
removed from the site. Spent decontamination soap/rinse solutions are transferred to drums which
are labeled and disposed of with other substances onsite.
Commercial laundries or cleaning establishments that clean protective clothing or equipment shall
be informed of the potentially harmful effects of exposures to the contaminants.
8.5.1 Disposal Procedures
All wash and rinse water will be transferred to a container that will be covered and labeled as to
contents and stored onsite. If 55-gallondrums are used, they will be DOT-approved drums and lids will be put on all drums in the event ofrain and at the close of each work day. Drums will be
supported on wood blocks or pallets to reduce corrosion. Means and method of disposal of decontamination solutions will be decided on a case-by-case basis and will be detailed in the Task
HASP.
8.5.2 Contamination Reduction Corridor Breakdown
When the Contamination Reduction Corridor is no longer needed, it must be closed down. All
disposable clothing and plastic sheeting used during the operation must be double bagged and
contained onsite in a labeled DOT-approved drum or container. All wash tubs, pails, containers,
etc. must be thoroughly washed, rinsed and dried prior to removal from the site.
8.6 Communications
Communication systems will be established at the site for both internal and external communication
for both routine and emergency operations.
048369.0121 41
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EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A4l9
Ram Leather Site
8.6.1 Internal Communication
Health & Safety Plan
Revision No. 0
December I 0, 2004
Internal communication refers to communication between workers operating in the Exclusion Zone
or Contamination Reduction Zone or to communication from the Support Zone to these workers.
Internal communication will be used to:
• Alert team members to emergency situations.
• Convey safety information ( e.g., air time remaining in SCBA, heat stress check, hazards
detected).
• Communicate changes in the work to be accomplished.
• Maintain site control.
The internal communication system may include such standard communication devices as radio,
audible signals from noise makers or visual signals from hand or body movements.
Identification ofindividual workers is necessary to ensure commands are addressed to the right
worker. This may be accomplished by one of several methods, depending on the specifies of the
site activities.
•
•
•
Marking the suit with the worker's name .
Color coding, numbering or symbols for long-distance identification .
Use of names for short distance, small work force tasks .
Standard audible and visual communication signals are listed in Section 8.6.3.
8.6.2 External Communications
External communications refers to communication between onsite and off-site personnel. An
external communication system must be maintained in order to:
• Coordinate emergency response efforts with off-site responders.
• Report progress or problems to management.
• Maintain contact with essential off-site personnel.
048369.0121 42
EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A419
Ram Leather Site
Health & Safety Plan
Revision No. 0
December I 0, 2004
The primary means of external communication are telephone and radio. Where telephones are not
available immediately at the site, all team members will be notified ofthe location and dialing
instructions of the nearest telephone. The correct change and necessary telephone numbers will
be made readily available in the Support Zone. If radios are used, its location will be clearly
marked. Clear instmctions for its use will be posted with the radio at all times.
If access to external communications takes longer than five minutes to reach, the field team will be
equipped to have immediate access to emergency response organizations.
Specifics of the internal and external communication methods will be detailed in the Task HASP.
8.6.3 Communication Signals
Purpose: To alert members of emergencies, convey safety information, communicate changes in
the work to be accomplished and to maintain site control.
•
•
Audible Cnternal Communications (whistle, vehicle horn, personal air horn)
Signal Definition
1) one long blast
2) two short blasts
3) two long blasts
4) three short blasts
evacuate area
localized problem, be on the alert
all clear, reentry permitted
cease work operations
Visual [ntemal Communications (hand signals)
Signal Definition
I) Hands clutching throat
2) Hands on top of head
3) Thumbs up
4) Thumbs down
5) Arms waiving upright
6) Grip partners wrist
7) Cross arms above head
Out of air/cannot breath
Need assistance
OK/I am alright/I understand
No/negative
Send backup support
Exit area immediately
Cease work operations
048369.0121 43
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EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A4l9
Ram Leather Site
8.6.4 Hazard Communication
Health & Safety Plan
Revision No. 0
December I 0, 2004
The following apply to all chemicals where the chemical concentration exceeds I% orO. l % for
a carcinogen. This section is applicable to all chemicals brought onsite, used onsite or present as
a contaminant onsite.
All chemicals will be accompanied by aMSDS. All MSDS's will be included in Appendix 3 of
the Site HASP and made available to all personnel.
All containers of chemicals will be properly labeled with the chemical name and appropriate hazard
warning statement.
All team members will be trained in the following at the initial safety briefing or wherever the
presence of the chemicals is identified.
• Methods and observations that may be used to detect the presence or release of a
hazardous chemical in the work area.
• The physical and health hazards of the chemical in the work area.
• The measures employees can take to protect themselves from these hazards.
• Location of the MSDS's.
• Explanation of the labeling system.
8. 7 Confined Space Entry Procedures
Black & Veatch team members are not authorized to enter confined spaces without written
authorization from the Black & Veatch HSM or designee. Confined spaces are defined as spaces
that meet the following criteria.
• Large enough for a person to bodily enter.
• Limited or restricted means of entry or exit.
• Not designed for continuous employee occupancy.
048369.0121 44
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EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A419
Ram Leather Site
9.0 Emergency Action Plan
Health & Safety Plan
Revision No. 0
December 10, 2004
In the event of any emergency, the SSC will act as the Emergency Coordinator. The SSC will
assess the emergency and determine if onsite resources are capable of responding to the
emergency without exceeding the level of training and resources available. Otherwise, emergency
response by Black & Veatch field team members will be to immediately evacuate the site in the
event of a non-medical emergency. No member of the field team is permitted to assist in
responding to a major non-medical emergency.
9.1 Preplanning
Arrangements will be made with the local response community (i.e. fire department or local
response services) for them to respond to emergencies that may occur during site operations. The ·
local response community will be provided information regarding site activities, including the types
of operations being conducted at the site, the type and degree of contamination at the site, the
location of the work zone and any other relevant information that may be necessary for an
appropriate response. Such information will be provided to a supervisory level representative of
the emergency response organization prior to the commencement of site operations.
9.2 Reporting Emergencies
Emergencies of all types must be reported to the SSC immediately through established
communication means. If the SSC is not available, report the emergency to the nearest Black &
Veatch supervisory representative.
The SSC w_ill assess the emergency and determine if onsite resources are capable ofresponding
to the emergency without exceeding the level of training and resources available. If offsite
emergency response organizations are needed, the appropriate notifications will be made in
accordance with the preplanning arrangements made.
9.3 Notification
In the event ofan emergency, Black & Veatch personnel will take direction from the SSC. As
soon as possible, the SSC will make contact with the Black & Veatch PM and the Black &
048369.0 I 21 45
EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A4l9
Ram Leather Site
Health & Safety Plan
Revision No. 0
December I 0, 2004
Veatch HSM. If an emergency response organization is notified to respond, the SSC will dispatch
a representative to the site entrance to escort the emergency response organization to the
emergency scene. The SCC will act as the liaison with the officer-in-charge of the emergency
response organization.
9.4 Emergency Contacts
Appendix I lists emergency telephone numbers and reporting instructions for ambulance,
physician, hospital, poison control center, fire, police, local hazmatteam, emergency rescue team,
client contact and site contact. Appendix I will be conspicuously posted in the Support Zone.
Where phone numbers are not available for the above mentioned organization, the list will so
indicate.
The present status and capabilities of emergency response teams that would provide assistance at
the time of an emergency is described in the Task HASP.
9.5 Fire or Explosion
In the event of a fire or explosion, the local fire department should be notified immediately. The
SSC or designated alternate will advise the fire commander of the location, nature and identification
of the hazardous materials onsite. The SSC will maintain contact with the emergency response
organization officer-in-charge.
If it is safe to do so, site personnel may:
• Use fire fighting equipment available onsite to control or extinguish incipient fires.
• Remove or isolate flammableorother hazardous materials they may contribute to the fire.
• Inform the site supervisor immediately.
• Inform the site contact immediately.
9.6 Spills or Leaks
In the event of a spill or a leak, site personnel will:
• Inform the site supervisor immediately.
048369.0121 46
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EPA Contract No.: 68-W99-043 Health & Safety Plan
Revision No. 0
December I 0, 2004
Work Assignment No.: 369-RDRD-A4 I 9
Ram Leather Site
•
•
•
•
•
•
Inform the site contact immediately .
Locate the source of the spillage and stop the flow ifit can be done safely .
Contain the spill.
Notify the local emergency response organization if the spill_ cannot be controlled.
Notify the local fire department if the chemical release has the potential of impacting
the public health or environment off-site.
Request off-site assistance in recovery of spilled material.
If the SSC determines that a situation exists that could threaten human health or the environment
outside the site area, the local fire department will be notified immediately. In accordance with
USEPA SARA Title Ill, the SSC will also immediately notify the National Response Center and
the Black & Veatch PM. The telephone report will include:
•
•
•
•
•
•
•
Name and telephone number of reporter.
Name and address of facility .
Time and type of incident (e.g., release, fire).
Name and quantity ofmaterials(s) involved, to the extent known and the location of
the discharge within the facility.
The extent of injuries, if any .
The possible hazards to human health, or the environment, outside of the site area .
Actions the person reporting the discharge proposes to take to contain, clean up and
remove the substance.
9.7 Evacuation Procedures
At each work site, an evacuation route and rally point will be identified. The evacuation route will
be selected to direct field personnel away from the Exclusion Zone to the nearest exit. During
evacuation, every effort will be made to evacuate with their assigned buddy. The evacuation route
will avoid high hazard areas and efficiently move personnel away from the emergency site.
The evacuation route will be towards a rally point. The rally point is a common area where all field
team members are to meet following an evacuation. The purpose of the rally point is to remove
personnel to a location a safe distance away from the emergency and away from high hazard areas
and to give the SSC a location where all field personnel can be accounted. [n the event of missing
personnel, emergency response organizations will be notified immediately. The SSC will offer
048369 .o 121 47
EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A4 I 9
Ram Leather Site
Health & Safety Plan
Revision No. 0
December I 0, 2004
whatever assistance is requested by the emergency response organizations in the event search and
rescue is necessary. In the event that the rally point is proximate to the hazard, the SSC will
authorize the evacuees to move to a safer rally point. All personnel will remain at the rally point
until authorized to leave by the SSC.
9.8 Critique of Response and Follow-up
A follow-up meeting will be held after any emergency situation to assess the actions taken. The
meeting will be attended by the SSC and other individuals as appropriate. A record of the meeting
will be kept by the SSC. Recommendations from the meeting will be incorporated into the future
responses to emergency situations.
048369.0121 48
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EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A4 I 9
Ram Leather Site
10.0 Team Member Responsibilities
10.1 Managerial Responsibility
10.1.1 Health and Safety Manager
Health & Safety Plan
Revision No. 0
December I 0, 2004
The HSM is responsible for providing the PM with assistance and support with regard to all
regulatory and safety aspects of site activity.
10.1.2 Project Manager
The Black & Veatch PM is responsible for technical direction and overall project administration.
As a part of that function, the PM will ensure that, at a minimum, Black & Veatch's project plans
meet OSHA requirements and that the health and safetyofall site personnel are a primary concern.
10.2 Team Organization/Responsibility
The following personnel organization is critical to the planned activities at the site. The
organizational structure is assigned and will be reviewed and updated periodically, by the PM.
10.2.1 Site Manager
The Black & Veatch site manager (SM) is responsible for leading the team in the planned field
activities. The responsibilities include close attention to site conditions as they may affect the health
and safety of all team members during their onsite activities. The SSC will assist the site manager
in the site activities.
10.2.2 Site Safety Coordinator
The SSC has total responsibility for ensuring that the provisions of this HASP are adequate and
implemented in the field. Changing field conditions may require decisions to be made concerning
adequate protection programs. Therefore, it is vital that personnel assigned as SSC be
experienced and meet the additional training requirements specified by OSHA in 29 CFR
1910.120 and the Black& Veatch Safety and Health Program. The SSC is also responsible for
conducting site inspections on a regular basis to ensure the effectiveness of the HASP.
048369.0121 49
EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A4 l 9 Ram Leather Site
10.2.3 Field Team
Health & Safety Plan
Revision No. 0
December 10, 2004
The field team is the Black & Veatch team personnel responsible for performing the activities
described in the HASP under the SM's oversight. Each member is expected to handle the assigned
duties with attention to the inherent hazards involved. All field team members agree to adhere to the provisions in the HASP.
048369.0121 50
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EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A419
Ram Leather Site
11.0 Certification
Health & Safety Plan
Revision No. 0
December I 0, 2004
All field team members are required to read and familiarize themselves with the contents of this
HASP and than to document their competency through the entry of a signature and date on the
section below. Any changes to the HASP will be made in accordance with Section 12.0, Record
of Changes.
By my signature, I certify that:
• I have read,
• I understand and
• I will abide by the Health and Safety Plan for the Ram Leather Site
Printed Name Signature Date Affiliation
048369.0121 51
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EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A4 I 9
Ram Leather Site
12.0 Record of Changes
Health & Safety Plan
Revision No. 0
December 10, 2004
Changes to this HASP must be made on the following form and submitted to the Black & Veatch
PM and HSM for their approval. Field activities related to the potential for exposure to
contaminants shall be halted until the HASP has been modified to reflect changed conditions and
the Black & Veatch HSMhas reviewed or approved the changes. All field team members who
are affected by the changes must initial that they have been informed of the changes.
Revised Number Subject Section/Page Initials/Date
048369.0121 52
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EPA Contract No.: 68-W99-043 Health & Safety Plan
I Work Assignment No.: 369-RDRD-A419 Revision No. 0
Ram Leather Site December I 0, 2004
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Table 2-1
Soil Samples Collected by Ram Leather Care, 1991
Mecklenburg County, North Carolina
Soil Boring ID, Om md Location De:aaiptioo Dcpcb of umplc Re.ult., uar.. PCE
I No,rTmk p>d ~ 16,584
9-11-91 "' l,168
IS' 11
20' ND
2<' 19
l No,r"""""1a ~ 15
9-19-91 10' 51
IS' ND
20' JJ<
25' ND
3 Nur Sc:ptic tank dnin box 9-11-91 •• ND
T ND
• Drum.,.. 9-20-91 T ND
5 Soil.l)onanorthcrly~Kc:Wdcrnmoffpath 9-20-91 10' l!,503
6 In culvert, before puaing r.mdcr tn.cu 9,,26-91 6' ND
7 In culvert, dlcr pusing under tracb 9-26-91 6' ND
I Drum~ 10-21-91 4' and 10' ND
9 Along northerly runoff path 10..21-91 •• 380
Aao detected: 22 ppb cthylbmz.cnc md 74 ppb xylene 10' 2,11 BOLD• Samples with contanunant: levels grca1.cr than three tunes ba.ckground 'TCA • I, I, 1-trichloroetlwu: .
!1!11!1 Mincn!Spiril,
TCA•
ND 19
ND 7
ND •
ND ""·'
ND I
ND ""·'
ND I.I
ND ""·'
30 2.3
31 ""·'
16 ""·'
31 ""·'
ND NA
ND NA
ND NA
ND NA
ND «J.S
ND ""·'
ND ,.,
(Source: Combined Preliminary A,1sessmenVSite /nJJHCtion, Ram Ullther Care, Vol. I and II. NC Dcputmmt of Environmem. Hcahb. and Natura.I R,sowec,, March 1996).
Remedial Investigation Report
Ram Leather Care
8
Sample ID (all surface soil)
Organic, ug/kg (ppb)
2•Butmonc (MEK)
Momy!,ne Cbloridc
Totncblorwlh= (PCE)
Trichlorocthenc (TCE)
bi,(2-othyl boxyl)phO..W.
3,4-mcthytphcnoJ
Table 2-2
Soil Samples Collected by EPA, March 1994
Ram Leather Care
Mecklenburg County, North Carolina
Nea dnan area Alu of nrc::ucd Under drain pipe ~ontiu:r'drum. oonm1hof ... bwl<fina
ND ND ND
6.0E 9.7 E l.5E
32 •.2E I.IE .
0.9E ND ND
3(0 270 >H
.
ND ND ND E = Estimated value, concentration below the pracl!cal quanl!tal!on limit BOLD= Levels of contaminants greater than three times background
Surfac.c water
nmoff p.ah, bcf'DR ·-
66E
22E
21
ND
2300
370
(Source: Combined PreliminaryAssessmenl/Sile inspection, RamU!ather Care, Vol. I and II, NC Department of Environment, He.a.Ith. and Natural Resources, March 1996).
Remedial Investigation Rq,ort
Ram Leather Care
9
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Table 2-3
PCEIDEGRADATION PRODUCTS ANALYTICAL RESULTS (SOIL)
RAM LEATHER CARE (1999)
MECKLENBURG COUNTY, NORTH CAROLINA
·s,1;,;;;>> · ... •·•···•·····••· < . \ ',,·:/\\:-·?::::::-.. , ,.,
DSOOIJA
DS0081B
DS0022A
DS0054A
DS0065A
OS0105B
OS0096B
DS0037A
OS0119C
OS01410B
ND0021B
SS0081B
RL23C
Rl.23D
RL23E
RL23F
Rl.23O
RL24C
Rl.24D
RL24E
RL24F
RL24H
RL25H
RL26C
Rl.26D
RL26E
RL27C
RL27E
RL27F
RL28C
Remedi.a.J Investigation Report
!um l..ca!her Care
. Dq,th (ft) i . ,·,· .
0--0.5
5
0--0.5
0--0.5
0--0.5
5
5
0--0.5
10
5
5
5
10
15
20
25
30
10
15
20
25
45
◄5
10
15
20
10
20
25
10
· l'Ct ,~~j\/i 'Tcicu~g) _• ocF'.tu~J \.·
. 61 --
1201 19 -
21 --
110 --
21 --
13 --
16 -·-
21 --
78000 --
J.2 --
J.3 --
LI 0.491 -
4201 84 0.691
5.7 J.7 -
4.1 0.591 -
36 3.6 -
36 2.3 -
5800 --
3801 0.80) -
330) 0.88 -
56 0.96 -
2201 5.8 -
0.8◄ --
140) 4.7 -
1601 8.6 -
15 --
170) 3.◄ -
3200 ◄3 -
20000 --
29 11 -
25
.·vLlr1·q,i~•i4i!I••••••••
-
-
-
-
-
-
-
-
-
-
-
-
5.8
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
3.9)
RL280
RL28E
RL21F
RL21H
-m&lyzed fc..-but DO( detected
Remedial lnvcstigatioa !!,port
Ram Leath..-c.n,
"
20
2l
.,
120) 17
IJOJ lJ
IJOJ 14
4,0) 1101
26
161
0.411
u 44
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Table 2-4
Ram Leather Care
Ana~ytical Results -Volatile Organic Compounds Ons,te Deep Well, Septic Tank, and Potable Wells
Analyte (ugm IP · +filillmiiv; • t :I n1e1racti1atoet6enaii Utrictiliiwietheoii 1 ······ · ·· · · · ·
•···•·• <t.owoo.1.1 er
\ST001.1{Ti•+
?PW0011•:t/>·•
••·• ••• fpwoo22•.,Jt••··•·•••··•
i/iw0022e.F
,<•W•npWoi 13</
'/. A{ F'W0089)))/\
••·pwoa312 it
4000
70
14
14A
100
1
210
3.3
0.98J 1.1A 1.1A
26
1200
0.69J
4.4
29 0.71J
30A 0.68AJ
42
0.66J
3.3
Table 2-5 Analytical Results -Metals Potable Wells Anatyte (ug/1) Aiuniin'uinl•·~1tnoiwl•,....,;i.;I Biiiiumi·•iloi'ittiuni.! •••>c;;iciimi•i>!iC11nmiiuin•·l•.coiiaitl:eo;;;.;;.1J•·. •••,,:.;;,v,1\g.kiJl•~....i.111l·Manu•~·.1~Ft4k~••[J>01.~1~,;;••••fs~.;;,i1;;; ••c::.:.•: •• •;,::••MCL.luiiiui'?••••••·•·• ·•·••••Ajirl1•1999(uuii))/•·. :P\\1001 !)~; .; =12;; ••:C://}:(PW001'4.\ ·rct/HpW0055 >r·••·· i'PWOOGa :"<:'\:-\)\){PW0076(:f.::,~.:Y,X· •;.:,X//N100&9·•.f'•·····'·•· .,,,:,.:o+:<\PW0011i•1'M'>' ~ ~ •:)L:t)•QAll01iiFie{:{c:\•/ .•••· /)QA001ER1 >··:))• ·7 tciA001&.vi// /· 1200J I ···· .. ,., ••.. ,;·ai.ooiowitt?'·•·· :owoo11 .. h LI SJOJ .foiie ,m iuaiii Y ,.., .. •·ilL001PW}\·· ·' .,.., .•'•••A'·••··RL0021'W:·p{U·•····•·· ...• , •• ,.,..., • .,. •. Ri.ooJP\N:()r•••··•··· i >RL004f'WH -::,.:.:.//j{:}R~OOSPYV)}f:''',-·•-·-.·. •••••·/t\••)1L00&PW·••}i>'••·•• •••••·•••••••··}\RL007P-N}'.f•:••••••••• :(Ri.<mP\N'H,;y·•··•· iiRL009PW) :-· ::" RL010P'N\;?Y=/ .--· •"'<""""• 1999 (ugll)if'····· ··•··•<'c>.·RLri111PW.')}'.}• •'·'\iRLOiBPW ••••·RLiMAPw> .. :.•i•.\\i,RL.04BPW\J••>•••· J • esUmafed walue 1 l1!1 IZ2!!!!1 ~ I I w I IW!!I 115 I I I 2 Ill.! I B.4J I 90 9.9J 74 61 -16 15 35 -46 -46 -120 110 84 20 42 1.3 9.7 54 68 56 30 49 38 110 46 46 84 32 15 95 78 77 78 30000 26000 27000 11000 11000 5100 28000 44000 40000 47000 27000 260 280 150 220 16000 36000 27000 29000 26000 42000 30000 46000 31000 6000 11000 46000 44000 34000 32000 N -prnumpOve evtdence of presence of malerial 2.4J 0.88J 1.0J 1.8J 14.J J6J 29J 21J 22J 10J 8.2J 29J 16J 11J 18J 22J 11J 5.2J 12J 15J 15 15 9 11 . 20 3000 160 1co· 3700 810 420 4400 170 1100 55 Mercury data rejected due lo lab contamination 1s I I L .. 2 I 0.1 Jo:i'•D I 2800 9.9J 8.5J 7.1J 5J 4.9J 7.5 7500 17000 18000 4000 3800 2100 9700 26000 7800 &800 12000 2.4J 5600 7900 18000 19000 3700 8200 11000 28000 13000 2200 4000 9000 8900 6100 6100 520 71 15 31 21 140 470 89 25 510 38 14 66 110 28 21 100 470 460 690 650 :;~·::1 I ;: j#il I 740 ;\is'iH I 100 !'faitj'}i I 820 j!33'.i}I I 1100 W~il I I 3200 l;;;~'J:I I ~= I I 2900 1.SJ I I 59 ;i:i:i/['. I I 46 42 5.4 75 I; 1000 1600 1900 2600 2500 2100 1600 3000 2900 no 730 21000 2200 --------.. _, __ -.. l!!!l!S' 111111 == --
----.. &1. iilii aa iiiiiia
Table 2-5 continued
Analytical Results -Metals
Potable Wells
13000
18000
18000
12000
11000
5600
13000
-·t--i>wcio8g"•"ft••• 28000 ,_.,,.· .. · .. :--.-.-. ····-·._.,._.:·
12000
11000
12000
150J
11000
130 12000
2-40 19000
170 17000
◄70 16000
310 12000
2◄0 1◄000
320 29000
150 12000
◄1 5900
97 12000
1◄0 1'4000J
130 1◄000J
160 15000J
160 15000J
5.0J 21
88
. 30
57
330
22
22
3.8J
1500 7,8
100
◄

2

30
31
u
6
5.7
650
780
---
5.7
Analytical Results -Volatile Organic Compounds Soil Samples (April 1999)
Analyto (ug/kg) ·. :? > iitali<>o \c\>. . PCff <iiice .:;: · · · ·· · ····. · ··. · .. ·.·. · · · · · · ·· · · · · /~~:~::~t2~hl0roe_ih_&;..-, FfoiJ.ne)· ':(M=~ndi~:ii;l)'f~M~j':.;= -= =-,··=.=----=·-·_ .. -.·-·-=-·····-····-·=---.-·· if April i 999 :}\ S22211lliilillit , ... .•,•: peltoleum product)
.
:.t,':tisooi1A/i'''
;£DSOOe1·B)}{(:
· [)S0022A \ . /osi11i,a>>
if•• tis0054Afo \:•
h3osll06s.,,J/;
u,;·oso105aJU:
u·osma/%:
)DS0037A/Yi
\cisoi2se H ::soso,.1oc· NY
.::-.-::--oso1~1·,:1e\/\
fr/N0002111:1f{•
•• t100011·c J.!:•••·
•:\,:,SS00818:'J
\'i\ssoooic t••
Ff\ssooiiis
,:::.xsso154e/i
ICLP generated data
J -eslimali!td value
6J
120.J 19
2J
110
2J
13
18
2J
78000
1.2
1.3
1.1 0.,49J
N -preseumptMI evidence of preaenco d rna1erlal
----
12
1.9 N
2.2 2.1
400.J
180.J
29J
12J
20.J
0.53J
15J
18J
23 0.77J
--· --.. 1111' == &iii -
l!!!!!!I I!!!! !!!!!
Table 2-7
Analytical Results -Metals
Soil Samples
Analyte (mg/kg)
I!!!!!!! !!!!!!I ~ -I!!!!!! !!!!!I -. -I!!!!!!!!
\'.})j}\61ti~?{\\? :::,AJUMitttff? ~ \SMl~in-\~1~' \cialdJkf i::Ch-~ium\ r~,r --~~--!/ii&{\ lead :-~·~um iMlh9~~-:::Mckfdi .fPritfl~Uffi:: :~km!Un1' { April 1999')
15000 3.9J 52
13000 2.7J 80
13000 2.SJ 88
7IIOO 2.1J ◄8
1◄000 5.BJ 82
1◄000 5.1J 92
20000 3.2J ◄O
17000 UJ 3◄
21000 2.◄J ◄3
13000 2.6J ◄9·
13000 3.2J ◄9
(/DS006SA·,g/f 11000 2.9J 8◄
13000 1.9J so
. 1◄000 60
12000 2.6J 67
9000 UJ 61
15000 2.SJ 320
18000 3.JJ 56
20000 1.9J 220
16000 110
11000 1◄0
16000 9◄
21000 ◄◄
16000 81
J-estimated value
N -presumpUve evtdence of prnence of material
• • surface aoll sample (A)
0.28J
0.◄7J
0.39J
0.98J
0.36J
0.37J
0.◄◄J
0.◄6J
0.51J
0.37J
0.35J
0.38J
0.SJ
0.◄J
o.◄SJ
0.96J
0.99J
0.71J
2
0.72
0.53
0.◄3
0.62
0.76
1600J 38 4.o4J
1SOOJ 37 9.7J
1◄00.J 3◄ B.7J
1200.J 130 ◄.BJ
◄◄00.J 8◄ 11J
3000J 69 11J
◄20J 29 6J
◄30J ◄5 3.6J
630J 110 ◄.9J
1600J 55 6.2J
1700.J ◄1 6J
1300J 72 9.9J
1000J 19 69
2800.J 39 9.2J
2300J 56 1B
1◄00.J 7.5 31
3300J 5.3 11J
720J 76 20
1◄00.J 210 71
1◄00 16 20
1◄00 25 19
3200 12 7.7
880 22 3.7
1900 10 9.◄
59 5IIOOO 20 1300 210J 5.1J 590J
◄◄ 36000 26 1◄00 560J 5.9J 790J 0.76J
66 35000 19 1◄00 390J 5.◄J 660J
23 28000 3◄ 880 170J ◄.9J ◄80J
52 52000 160 2◄00 390J 15 520J
59 50000 120 2

◄
00 JBOJ 1◄ S30J
79 71000· 13 1◄00 87J 6.SJ 260J
66 59000 16 710 100.J 7.2J 160J
B2 73000 ◄O 1000 B6J 10 220J
37 36000 11 1700 160J 7.JJ ◄10J
33 39000 17 770 1S0J ◄.JJ 3◄0
◄1 ◄

1
0
0
0

30 950 ◄60J 5.JJ 260J
◄O 31000 12 2200 320J 8.BJ 220J
65 50000 31JN ◄

1
0
0

260J 12 600J
◄

2

33000 16 2300 260J 12 S30J
2◄ 15000 ◄.1 5500 320J 9.◄ 1500
70 31000 ◄.3 5300 680J 9.7J 590J
◄0 ◄8000 16JN 1100 270J 7.SJ 8◄0J
23 35000 3.9 13000 990J 57 1000J
◄◄ 26000 72 2000 320 10 1200
36 2◄000 ◄.8 1500 550 1.3 1700
60 27000 8 ◄900 ◄SO 8.7 2800
29 27000 11 · 2700 120 8 560
32 2

◄
000 6.B 5200 300 6.3 2100
1!!18 -
Table 2-7 continued
Analytical Results -Metals
Soil Samples
-'~---2.8
1.9J
1.8J
1.&J -IIF-=t~+=+=~t=~~ 2.5
2.5
3.5
2.8
3.6
2J
1.9J
2J
1.8J
2.4
1.7J
0.62J
1.2J
2.4
1J
200
160
170
210
180
210
240
220
240
170
160
170
370
240
1110
270
820
170
270
200 34
120 44J
120 40J
!M 57J
140 140J
130 1JOJ
260 27J
210 19J
270 25J
120 35J
120 33J
130 52J
100 42J
170 58J
as 50J
34 J5J
62 62J
150 28J
100 IIOJ
:ziS2 28
>•~)24 ~~--t--;-;--+--+-:~~-!-~=1 1.3
84 13
40 11
260 60 JO
43 24 ~ 39
22
50
1000
510
850
a.a
1
.9.8
.
210
210
71 n
78 31
58 51
iiiiiilil
liiiiiii: ;;a
Table 2-8
Analytical Results -Pesticides/PCBs
Soil Samples (April 1999)
An•lyt• (ug/kg)
,· • Stollon > }) <◄.◄'-000• 4,4''0i)T ◄,4''0ilE; ,_,,"""""' C:end,tn -~ . ~p1,;,,;; Cgain~loid.inei 'cfieldilii' i •ndtlri) ~ii~;,•n(bilt•i i,lipi...,j,i,ii • ilt~di>.~ ::,:.-_,,,,=.:ssoo21A:> ... , 1.4JN
12
2◄
8,3N
1.8J
1◄N 3.5J
3.3JN 1.3J
\ieA00211l . •. 0.32JN
J • esllmaled value
N -prBSumpUve evidence or presence or ma1erial
C • confirmed by GCMS
• • surface 11011 aampe
1.◄J
360
1300
0.8".JN ◄.3 2.2JN 3.6N
5.9 2.8J
12 J.J
0.68JN 0.52JN
5.9 0.5◄JN 1.◄J
0.22JN
== I!!!!
Table 2-9
Analytical Results -Extractable Organic Compounds (BNAs) Soil Samples (April 1999)
Analyto (uglkg)
ista!i2o ii t,o~Jnil~ · pyr,,n;( ii..,.;.~ 'i.~<z-,,11,11~i.voi>11ihatati\ ~~iioorrier c.;,;;;..,;,,~~< {i,n;d~lifkld.;.;..;poulldi' . .... r·ss0012At<•···
.:. )·ssooz1.o.•)• ••
. :-:: ·--.. -:.-·:-·,,
·•·•·SS0033Ai •
• -surface soll sample (A)
J -estlmaled value
63.J
45J
N -presumptive evidence d presence of material
43J
2400
610
960
7100
720
4900J
5900J
2000J
7500J
3800J
100JN 3500J
2200J
«OOJ
35000J
2000J
. nOOOJ
990JN 940J
2800.J
Table 2-10
Analytical Results -Volatile Organic Compounds
Soil Samples (August 1999)
111!!1!!, ==
,-~·.. J22 ) ::tee'} /G"~=;: :;~~,;i~Chbroeth~-, :';rwiii'ol&~m·'~~ui~{) ., ... -.. -.--•-•,-· ... ·-., ........... , . /{:}Rl21C·se}\\ }ibeiizw:. : \'carbori:ifisuifld&): '-Pi~\ /Ctnj1-'itii0rl&f' O.SOJ
if•Rl21ESB }
)}RL22CS8 L•
• Rt22ose / ••
RL22ESl3)}:(
Rl22FSB(/··
jiR1,22osa?•t•·
.RL23CSB{U
t)lit2ios11J/·
h)FfL:i3E{SB\)?'"
(/Rl.23FSB••••••?••
.,}}Rl230SB9•··•··
'./?itRLi◄EiB/i
i(Rl.24FSB}·\
ti<l24Hse•·•+<••
i/••/RL25HSB(••··••··
i\%iiL266ssiH
·•··••URL260SB\• •.•••.•..•
•/({Rl.27CSB \·)i
••;•)RL27ESB/(
,/ii.RL27FSB•••••••<
::;:t:t·Ruecse·:':·':;';:::,:
{\Rl280Sf3•;·•y
f•RL28Esilj\
RL2BFSB .)
){°\RL28HSB
J • estimated value
0.48.J
2.5
3.1
2.3
2
2.B
420J 84
5.7 1.7
4.1 D.59J
36 3.8
36 2.3
5800
JIIOJ O.BOJ
JJOJ 0.88
58 0.96
220J 5.8
0.84
140J 4.7
160J 8.6
15
170J 3.4
3200 43
20000 .
29 11
120J 17
1JOJ 13
1JOJ 14
4SOJ 110J
N • pmoumptlwo evidenced,._.,. d ma111fial
180J
400J
18
2.8
21
0.9
•••
19
64
5.9
87
170J
390
160J
SOOJ
3SOJ
390J
520
1.2
1.8
1.7
1.1
0.81
0.79J
N 0.72J
N
1.3
0.MJ
6
20JN
10JN
10JN
20JN
10JN
JOJN
20JN
10JN
70JN
20JN
20JN
5.8
3.9J
2.BJ
5.3
44
== == == == I!!!!!!
Table 2-10 continued
Analytical Results -Volatile Organic Compounds
Soil Samples (August 1999)
tt.:\/'( ~ ::. \I\ r;:1J)~ichkwoeth~-~~\ -.>:•~~-;)/4tkltii~he~:h :t;:lt1:~1-r1·111et~~~~-r,: ·.,Y\j:~-~~a~e>;: :,,,,._·R1:21css:'i/•
0,69J
•••RL2◄FSB)//
0.48.J
0.48.J
0.◄8J 9,2 18
u
1.9
1.5
0.48.J 1.5
1.5_ 2.7
J • eslimaled value
N • prneumpttwt eridence of presence d material
I!!!!! I!!!! --
I
D
0
u
0
I
I
I
I
I
I
I
I
I
I
I
I
I
I
EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A4l9
Ram Leather Site
048369.0121
Appendix 1
Site Maps and
Emergency Information
Ram Leather Site
53
Health & Safety Plan
Revision No. 0
December I 0, 2004
0
0
g
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·:~uNTY ll.~'·
PA~b:LBOUNOARY
:R.A1LR6Ao ·
.-.··:. ~ I. ,,
,-·200:
Source: DES Re~urce Gmups, Inc., sur1ey, AuglJSl 15, 2002.
l,lecklerburg Ca, Lal'\d Recor els Oiv ., ae11al photograet,, June :;:oo1.
Adapted from: ~ec~Jenburg Co. Land Reccrds Div., topographic attr.t:l;tes,
Octcber 2C02.
COM
Figure
Site Vicinity Map
Ram Leather Site
Charlotte, North Carolina
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ALBEMARLE ROAD
-----------------------------------------------------------........ ; ...... -.. -........ -.. ·:.·.·-:. -.... -.............................. ---. -. -....... -.. -. . . . . . . . . . . . . . . -. -.......................... .
'
r > Septic
.) Now Well Tanlc
! / OldWell Q
,,--' 0 -----..or------i I
') r \ -~-
/
Drum
Area
I . .1 Bo1lcr Blowout
) .-----==i
) Gra,;
Concrete
Pad
Existing
Building
Floor Drain
from Building to
Underneath Pad
Septic
Linc
1-' MW-2
GT~.·
~.-'\J
I
Trash
Pile
-' MW-J
Presumed?'
Dumpster
Location
Septic
Drain
Field
LEGEND:
railroad
El' monitor well •
Existing
Crushed Stone
Parking
Septic
lj Drain Field
Head Box ii
·-· ·-
Wooded Area
0
20'
Crushed Stone
Road Existing
L_ ______________________________ __,
Rc(crmec: COM federal l'r01rams Corpo~tion. Site Fca111rcs M.1p
Figure 2
Site Map
Ram Leather Site
Charlotte, North Carolina
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EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A4 I 9
Ram Leather Site
Hospital Emergency Route
Route to: Presbyterian Hospital
[phone]
200 Hawthorne Lane
Charlotte, NC 28204
See the following page for hospital route map.
1. Begin at the Ram Leather site, 15100 Albermarle Road.
Health & Safety Plan
Revision No. 0
December I 0, 2004
2. Go West (toward Coble Road) on Albemarle Road/NC-24 W/NC-27 W for 10.1 miles.
3. Tum Right onto East Independence Blvd/US-74 W/NC-27 Wand go 3.4 miles.
4. Tum slight Right onto ramp.
5. Merge onto East Independence Blvd, continue for 0.2 miles.
6. Tum left onto Elizabeth Avenue, go 0.2 miles.
7. Tum right onto Hawthorne Lane.
048369.0121 56
I Presbyterian Healthcare I Maps & Directions Page I of I
: Presh~HEALTHCARE Niaps & Directions
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200 Hawthorne Lane Charlotte NC 28204
Driving Directions j
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200 Hawthorne Lane Ii Charlotte
Address/Intersection City
NC l2a204 Llu_s_A _______ ,
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1 '1ti::./'"'Jf\f'L1
Driving Directions from 15100 Albemarle Rd, Charlotte, NC to 200 Hawthorne Ln, Charlotte, NC
S Send To Printer Back To Directions
Start: 15100 Albemarle Rd
Charlotte, NC
28227-6943 us
End: 200 Hawthorne Ln
Charlotte, NC
28204-2515 us
Distance: 14.43 miles
Total Estimated Time: 26 minutes
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About these results
Directions Distance
l'!!'l!'!l!I l Start out going WEST on ALBEMARLE RD/NC-24 W/NC-27 W toward lO.l miles -• COBLE RD.
~· ;: . ;~;~·;;~~;·~~t~~· I~~~;~~;~~~~·~~~;;~;:;;~;~~:;; ~:·· 3.4 miles
~ .. ;:··;~·;~·;~~~;~·I~~;·~~~~··r~·~~:......................................................................................... 0.3 miles
~···~~·· ~~;~·~ ~~~~· ~ !~.~~~~~;~~~~ ~~~~:. 0.2 miles
~ ~~· ;~~~·~~~~~~~ ~~;;~~~;~~:· . ... 0.2 miles
~:::i.:>~:r~:i~i~i:~~ti.:~i~~i:~~i:~~:-..... ................................................. <0.1 miles Ill End at 200 Hawthorne Ln, "Charlotte, NC 28204-2515 US
' -Q ~ ,:i>:1':~ ~ ' ~;(~"' .... r.••,J. ' 5 . , ,. , -.... 0c;:.:::;;$ m,
Start:
15100 Albemarle Rd
Charlotte, NC
28227-6943 us
End:
200 Hawthorne Ln
Charlotte, NC
28204-2515 us
I '" Sic ., d1 1 ,11 / l'I) :Y.i'l11\I,,, 1 ,I
'
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tto://www.maoauest.cnm/rlirectinns/main.arln?rln=nrt&mn=ma&11n=m&.o"=l &1 a=l, 1 nn°/4?0A Jh,,marl
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1? ;,:;nnna
I Driving Directions from 15100 Albemarle Rd, Charlotte, NC to 200 Hawthome_Ln, Charlotte, NC
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-•t;.:-C'i:i=;.;.'F} :.ll.i.l.'4):,.\'~. ,, 00',0
.... All rights reserved. Use Subject to
License/Copyright
Oft:5 ';'l:'J/.
······· These directions are Informational only. No
representation is made or warranty given as to their
....... content, road conditions or route usabillty or
expeditiousness. User assumes all risk of use .
............................................ ... MapQuest and its suppliers assume no responsibility
for any loss or delay resultlng from such use.
Page 2 of2
I Site Index I About I Partners I Advertise I Privacy Policy & Legal Notices© 2004 MapQuest.com, Inc. All rights reserved.
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htto://www.maoauest.com/directions/main.ado?do=ort&mo=ma&un=m&rm=l & 1 a= 1 51 00%20A lhemBrl ... 12/li/2004
-------------------
EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A419
Ram Leather Site
Organization
Police
Fire
EMS
Presbvterian Hospital
[phone]
200 Hawthorne Lane
Charlotte, NC 28204
Black & Veatch
Black & Veatch
Black & Veatch
Black & Veatch
USEPA
ADP Solutions
Poison Control
48369.0121
\
Table A-1
Emergency Contacts
Name Position
Mr. Darrel Steohens Chief
Mr. Luther Fincher Fire Marshall Chief
Mr. Luther Fincher Fire Marshall Chief
Ms. Colleen Farquharson Director of Nursing
Ms. Nancy Geller Project Manager
Ms. Darci Scherbak Site Safety Coordinator
Mr. Jack Schill, CIH, CSP Health and Safety Manager
Ms. Diane Gassman Workers Compensation
Ms. Beverly Hudson Work Assignment Manager
Dr. Elayne Thiersault Medical Monitoring
Carolinas Poison Center
58
Health & Safety Plan
Revision No. 0
December 10, 2004
Phone Number
911/ [phone]
911/ [phone]
911/ [phone]
[phone]
[phone] (w)
[phone] (h)
[phone] (w)
[phone] (w)
[phone] (h)
[phone] (m)
[phone]
[phone]
[phone]
[phone]
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EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A419
Ram Leather Site
048369.0 I 21
Appendix 2
Chemicals of Concern and
Applicable Regulatory Standards
Ram Leather Site
59
Health & Safety Plan
Revision No. 0
December I 0, 2004
--- --- - -- - ---
EPA Contract No.: 68-W99-043
Work Assi!,'llment No.: 369-RDRD-A419
Ram Leather Site
Table A-2
Chemicals of Concern and Applicable Regulatory Standards
Ram Leather Site
Contaminant Exposure Route TWA Exposure IOLH Hazard/Symptoms
(CAS No.) Limits
1. 1-Dichloroethane (DCA) Inhalation, NIOSH: 100 ppm 4000 ppm CNS depres: skin irrit; liver,
CAS # 75-34-3 Ingestion, Contact kidney damage
1. 1-Dichloroethene (DCE) Inhalation, NIOSH: Carcinogen Carcinogen Irritate and burn skin and eyes;
CAS # 75-35-4 Absorption, REL: 5 ppm Irritate nose and throat;
Ingestion, Contact Drowsiness, depression,
"drunken· feeling that can lead to
unconsciousness: Liver and
kidney damage: lcarc)
Tetrachloroethylene Inhalation, OSHA: 25 ppm 500 ppm Skin irritation, burns/drying/
(PCE) Ingestion, Skin NIOSH: Carcinogen cracking of skin; Irritation of
CAS # 127-18-4 Contact eyes, nose, mouth, throat;
Headache, dizziness, nausea,
vomitino. oassino out; fcarcl
Trichloroethylene (TCE) Inhalation, NIOSH: Carcinogen 1000 ppm Head, verti; vis dist, tremors,
CAS # 79-01-6 Ingestion, Skin 25ppm som, nau, vomit; irrit eyes; derm;
Contact OSHA: 50 ppm card arrhy, pares; [care)
ST: 220 ppm
Notes and Abbreviations for Table A-2.
JDLH Source:
OSHA PElJCarcinogen/ACGIH TL V Sources:
OSHA PEL:
U.S. Department of Health and Human Seivices. NIOSH Pocket Guide, 1990.
American Conference of Government Industrial Hygienists, Guide to Occupational Exposure Values 1992.
Occupational Safety and Health Administration Pennissible Exposure Limit.
!!!!I !!!!!
Health & Safety Plan
Revision No. 0
December I 0, 2004
Maximum Detected
Concentrations
1.1 µg/L
12 µg/kg soil
1200 µg/L water
78,000 µglkg soil
4.000 µg/L water
110 µg/kg soil
210 µg/L water
TWA:
IDLH
Time-weighted average exposure ooncentration for nonnal 8-hour (TL V, PEL) or up to a 10-hour (REL) work.day and 40-hour workweek.
Immediately dangerous to life or health concentrations.
Maximum Detected Concentrations Source:
ppm
µg/kg
48369.0121
EPA, IROD, September 2004
Parts per million
Microgram per kilogram
60
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EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A4!9
Ram Leather Site
048369.0121
Appendix 3
.Material Safety Data Sheets
Ram Leather Site
61
Health & Safety Plan
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EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A4l9
Ram Leather Site
MSDS
Health & Safety Plan
Revision No. 0
December 10, 2004
Table of Contents
The Material Safety Data Sheets for substances used in the completion of this project are located
in a public area of each vehicle. They are available to review during normal working hours.
Information in on-MSDS format may be included for the contaminants of concern.
Note: Although these are written by a specific manufacturer, they are not meant in anyway to
suggest that the waste products or contamination on the site come from that particular
manufacturer. They are intended to be used solely as an approximation for the waste
product to provide safety and health hazard information, including symptoms of exposure,
first-aid procedures, and spill control measures.
Diesel Fuel
Gasoline
Vermiculite
Portland Cement
Isopropanol
Reagent Alcohol
.Nitric Acid
Phosphoric Acid
Sulfuric Acid
Sodium Hydroxide
Hydrochloric Acid
Zero Oxygen Solution
Potassium Chloride
Lithium/Bromide Chloride in Thionyl
048369.0121
Chloroplatinic Acid
Hydrogen
Compressed Air
Methane
Organic Free Water
Alconox
Carbon Dioxide
Silicon Dioxide
Hexane
Isobutylene
Liquinox
Pure Gold Tablets
ABC Fire Extinguisher Dry Chemical Agent
Chloride
62
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M S D S
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* Canadian Centre for Occupational Health and Safety
RECORD NU:~BER
LANGUAGE
PRODUCT NAME(S)
*** IDENTIFICATION***
601627
ENGLISH
MIDDLE DISTILLATE (DYED OR CLEAR)
COMMERCIAL FUEL
DIESEL FUEL
DIESEL FUEL FOR EPC REFUELLING
DIESEL QUALITY FURNACE FUEL
DIESEL QUALITY HEATING OIL
ESSO COMMERCIAL FUEL
ESSO DIESEL FUEL
ESSO DIESEL QUALITY COM.MERCIAL FUEL
ESSO DIESEL QUALITY FURNACE FUEL
ESSO DIESEL QUALITY HEATING OIL
ESSO FURNACE FUEL
ESSO HEATING OIL
ESSO MARINE DIESEL FUEL
ESSO MARINE GAS OIL
ESSO RAILROAD DIESEL
ESSO RAILROAD DIESEL FUEL
ESSO RAILROAD DIESEL FUEL #3
ESSO TOBACCO CURING OIL
ESSO 3-GP-llM
ESSO 3-GP-lSM
FUEL OIL 75
FUEL OIL 76
FURNACE FUEL
HEATING OIL
MARINE DIESEL
MARINE GAS OIL
3-GP-llM
3-GP-lSM
PRODUCT IDENTIFICATION DATA
DATE OF MSDS
MSDS Number : 000116
1991-07-17
MANUFACTURER
ADDRESS
*** MANUFACTURER INFORMATION••*
Imperial Oil (Products Division)
111 St Clair Avenue West
Toronto Ontario
Canada MSW lKJ
Telephone: [phone]
*** SUPPLIER INFORMATION•••
SUPPLIER/DISTRIBUTOR Imperial Oil (Products Division)
ADDRESS 111 St Clair Avenue West
Toronto Ontario
Canada MSW lKJ
Telephone: [phone]
*** MATERIAL SAFETY DATA***
Date Prepared: July 17, 1991
Supersedes: June 0 2, 19 8 9 ,S Number : 000115
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Product Identifier: MIDDLE DISTILLATE (DYED OR CLEAR) COMMERCIAL FUEL
Application and Use:
DIESEL FUEL
DIESEL FUEL FOR EPC REFUELLING
DIESEL QUALITY FURNACE FUEL DIESEL QUALITY HEATING OIL ESSO COMMERCIAL FUEL
ESSO DIESEL FUEL
ESSO DIESEL QUALITY COMMERCIAL FUEL ESSO DIESEL QUALITY FURNACE FUEL ESSO DIESEL QUALITY HEATING OIL ESSO FURNACE FUEL
ESSO HEATING OIL
ESSO MARINE DIESEL FUEL
ESSO MARINE GAS OIL
ESSO RAILROAD DIESEL
ESSO RAILROAD DIESEL FUEL
ESSO RAILROAD DIESEL FUEL #3 ESSO TOBACCO CURING OIL
ESSO 3-GP-llM
ESSO 3-GP-lSM
FUEL OIL 75
FUEL OIL 76
FURNACE FUEL
HEATING OIL
MARINE DIESEL
MARINE GAS OIL
3-GP-llM
3-GP-lSM
Seasonally adjusted middle distillate for use in liquid fuel burning equipment for heating and/or as a fuel for use in an internal combustion engine of the compression ignition type
Product Description:
A complex mixture of aliphatic, olefinic, naphthenic and aromatic hydrocarbons.
REGULATORY CLASSIFICATION
WHMIS:
Class D, Division 2, Subdivision B: Toxic Material Class 8, Division 3: Combustible Liquids.
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TRANSPORTATION OF DANGEROUS GOODS INFORMATION
Shipping Name:
Class:
PIN Number:
Fuel oil
Flammable liquid 3.3
UN1202
Packing Group:III
Guide Number: 123
Please be aware that other regulations may apply.
TELEPHONE NU~BERS MANUFACTURER/SUPPLIER:
Emergency 24 hr. [phone]
Technical Info. [phone]
Imperial Oil (Products Division)
111 St. Clair Avenue. West
Toronto, Ontario
MSW 1K3
[phone]
2. REGULATED COMPONENTS
The following components are defined in accordance with sub-paragraph 13,a)
(i) to (iv) or paragraph 14(a) of the Hazard6us Products Act:
NAME
Fuel Oil No.2 >99.9 V/V
TYPICAL PHYSICAL & CHEMICAL PROPERTIES
Physical State: Liquid
Specific gravity: not available
Viscosity: 1.30 est at 40 deg C
to 11.00 cSt at 40 deg C
Vapour Density: 4
Boiling Point: 150 to 370 deg C
Evaporation rate: <l 1: n-butylacetate
Solubility in water: negligible
Freezing/Pour Point: not available
Odour Threshold: not available
Vapour Pressure: 4.000 kPa at 38 deg C
Density: 0.85 glee at 15 deg C
CAS #
68476-30-2
Appearance/odour: White or pale yellow liquid, petroleum odour
4. HEALTH HAZARD INFORMATION
NATURE OF HAZARD
INHALATION:
Negligible hazard at normal temperatures (up to 38 deg CJ.
High vapour concentrations are irritating to the eyes, nose, throat and
lungs; may cause headaches and dizziness; may be anesthetic and may cause
other central nervous system effects.
I
Elevated temperatures or mechanical action may form vapours, mists er 1 fumes which may be irritating to the eyes, nose, throat and lungs. Avoid breathing vapours or mists.
EYE CONTACT:
Slightly irritating, but will not injure eye tissue.
SKIN CONTACT:
I
I Irritating.
Frequent or prolonged contact may irritate the skin and cause a skin rash II (dermatitis). ti Low toxicity.
INGESTION: D
Low toxicity.
Small amounts of this liquid drawn into the lungs from swallowing or vomiting may cause severe health effects (e.g. bronchopneumonia or pulmonary edema).
CHRONIC:
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Lifetime skin painting tests indicate that materials of similar compositiol have produced skin cancer in experimental animals. The relationship of these results to humans has not been fully established.
ACUTE TOXICITY DATA:
Based on animal testing data from similar materials and products, the acute toxicity of this product is expected to be: Oral LOSO> 5000 mg/kg (Rat) Dermal LOSO > 2000 mg/kg (Rabbit) Inhalation LCSO > 2500 rng/m3 (Rat)
OCCUPATIONAL EXPOSURE LIMIT:
Manufacturer recommends:
100 ppm based on composition.
Local regulated limits may vary.
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5. FIRST AID MEASURES
INHALATION:
In emergency situations use proper respiratory protection to immediately remove the affected victim from exposure. Administer artificial respiration if breathing has stopped. Keep at rest. Call for prompt medical attention.
EYE CONTACT:
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Flush eyes with large amounts of water until irritation subsides. If I irritation persists, get medical attention.
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SKIN CONTACT:
Immediately flush ·,;ith large amounts of water. Use soap if available.
Remove contaminated clothing, including shoes, after flushing has begun.
If irritation persists, seek medical attention.
INGESTION:
DO NOT induce vomiting since it is important that no amount of the
material should enter the lungs (aspiration). Keep at rest. Get
prompt medical attention.
6. PREVENTIVE AND CORRECTIVE MEASURES
PERSONAL PROTECTION:
The selection of personal protective equipment varies, depending upon
conditions of use.
Where prolonged and/or repeated skin and eye contact is likely to occur,
wear safety glasses with side shields, long sleeves, and chemical
resistant gloves.
Where skin and eye contact is unlikely, but may occur as a result of
short and/or periodic e,xposures, wear long sleeves and safety glasses
with side shields.
Where concentrations in air may exceed the occupational exposure limits
given in Section 4 and where engineering, work practices or other means
of exposure reduction are not adequate, approved respirators may be
necessary to prevent overexposure by inhalation.
ENGINEERING CONTROLS:
The use of local exhaust ventilation is recommended to control
emissions near the source. Laboratory samples should be handled in a
fumehood. Provide mechanical ventilation of confined spaces.
HANDLING, STORAGE AND SHIPPING:
Keep containers closed. Handle and open containers with care.
Store in a cool, well ven~ilated place away from incompatible materials.
In keeping with good pe:rsonal hygiene practices, wash hands thoroughly
after handling the material.
Do not handle or store near an open flame, sources of heat, or sources
of ignition.
Material will accumulatE~ static charges which may cause a spark. Static
charge build-up could become an ignition source. Use proper grounding
procedure.
Empty containers may contain product residue. Do not pressurize
cut, heat, or weld empty containers. Do not reuse empty containers
without commercial cleaning or reconditioning.
LAND SPILL:
Eliminate source of ignition. Keep public away. Prevent additional
discharge of material, if possible to do so without hazard.
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Prevent spills from entering sewers, watercourses or low areas. Contain spilled liquid with sand or earth. Do not use combustible materials such I as sawdust.
Recover by pumping (use an explosion proof motor or hand pump), or by using a suitable absorbent.
Consult an expert on disposal of recovered material. Ensure disposal in compliance with government requirements and ensure conformity to local disposal regulations. Notify the appropriate authorities immediately. Take all additional action necessary to prevent and remedy the adverse effects of the spill.
WATER SPILL:
Remove from surface by skimming or with suitable absorbents. If allo·,,,ed by local authorities and environmental agencies, sinking and/or suitable dispersants may be used in unconfined waters. I Consult an expert on disposal of recovered material. Ensure disposal in compliance with government requirements and ensure conformity to local disposal regulations. Notify the appropriate authorities immediately. Take all additional action necessary to prevent and remedy the adverse effects of the spill.
7. FIRE AND EXPLOSION HAZARD
Flashpoint and method: >40 deg C PMCT
Autoignition: NA
GENERAL HAZARDS:
Flammable Limits: LEL: 0.7% UEL: 6.5%
Combustible Liquid; may form combustible mixtures at or above the flash point.
Toxic gases will form upon combustion.
Static Discharge; material may accumulate static charges which may cause an electrical fire.
FIRE FIGHTING:
use water spray to cool fire exposed surfaces and to protect personnel. Shut off fuel to fire.
Use foam, dry chemical or water spray to extinguish fire. Respiratory and eye protection required for fire fighting personnel. Avoid spraying water directly into storage containers due to danger of boilover.
A self-contained breathing apparatus (SCBA) should be used for all indoor fires and any significant outdoor fires. For small outdoor fires, which may easily be extinguished with a portable fire extinguisher, use of an SCBA may not be required.
HAZARDOUS COMBUSTION PRODUCTS:
Smoke, carbon monoxide, carbon dioxide and traces of oxides of sulphur
8. REACTIVITY DATA
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STABILITY:
This product is stable. Hazardous polymerization will not occur.
INCOMPATIBLE :•'.ATERIALS AND CONDITIONS TO A\'OID:
Strong oxidizing agents
9. NOTES
10. PREPARATION
Date Prepared:July 16, 1991
Prepared by: LUBRICANTS AND SPECIALTIES
Imperial Oil (Products Division)
111 St. Clair Avenue West
Toronto, Ontario
MSW 1K3
[phone]
CAUTION: '' The information contained herein relates only to this product or
material and may not be valid when used in combination with any other prodt1ct
material or in any process. If the product is not to be used for a purpose
under conditions which are normal or reasonably foreseeable, this
~nformation cannot be relied upon as complete or applicable. for greater
certainty, uses other than those described in Section l must be reviewed
with the supplier. The information contained herein is based on the
information available at the indicated date of preparation. This MSDS is for
the use of Essa Petroleum Canada customers and their employees and agents
only. Any further distribution of this MSDS by Essa Petroleum Canada
customers is prohibited without the written consent of Essa Petroleum Canada."
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Canadian Centre for Occupational Health and Safety
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RECORD NUMBER
LANGUAGE
~qoDUCT NAME(S)
1DUCT IDENTIFICATION DATA
.E Of MSDS
***IDENTIFICATION***
595116
ENGLISH
DIESEL FUEL
VAN WATERS & ROGERS MSDS NO.: LH2512
1991-12-19
*** SUPPLIER INFO~'IATION ***
SUPPLIER/DISTRIBUTOR
ADDRESS
EMERGENCY TELEPHONE NO. (SJ
Van Waters & Rogers Ltd (Canada) 9800 Van Horne Way
Richmond British Columbia
Canada V6X lWS
800-424-9300 (CHEMTREC)
*** MATERIAL SAFETY DATA•••
LH2Sl2.l DIESEL FUEL
VAN WATERS & ROGERS LTD. 9800 VAN HORNE WAY RICHMOND, 8.C. V6X lWS
WHMIS CODES: 8.3 D. 28
------------------------EMERGENCY ASSISTANCE-------------~------------
FOR EMERGENCY ASSISTANCE INVOLVING CHEMICALS CALL CHEMTREC . [phone].
I. IDENTIFICATION
SYNONYMS: None Known
CHEMICAL NAME: A complex mixture of aliphatic, olefinic, naphthenic and aromatic hydrocarbon
CHEMICAL FORMULA: Mixture C.A.S.NUMBER: Not available (mixture) --a.NS PORT:
Classification: 3.3 P.I.N.: 1202 PACKING GROUP: III Shipping Name: Fuel Oil Note: Section 2.23.2 exempt in container·4S4 litres or less WHMIS CLASSIFICATION: B-3; D-2B ---------------------------------------------·------------------------II. HAZARDOUS INGREDIENTS
1. Fuel Oil No. 2
C.A.S. #: 68476-30-2
LOSO-Oral: Not available
LCSO: Not available
Range% (w/w): 60-100
LOSO-Dermal: Not available
T.L.V.: Not established
III HEALTH HAZARDS ----------------------------------------------------------------------EFFECTS OF OVEREXPOSURE:
EYES: Slightly irritating, but will not injure eye tissue. SKIN: Frequent or prolonged contact may irritate the skin and cause dermatitis. · INHALATION: Negligible hazard at normal temperatures (up to 38C). High vapour concentrations are irritating to the eyes, nose, throat and lungs; may cause headaches and dizziness; may be anesthetic and may cause other central nervous system effects. Elevated temperatures or mechanical action may form vapours, mists or fumes which may be irritating to the eyes, nose, throat and lungs. Avoid breathing vapours or mists.. · INGESTION: Low toxicity. Small amounts of this liquid drawn into che lungs from swallowing or vomiting may cause severe health effects (e.g. bronchopneumonia or pulmonary edema).
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CHRONIC HEALTH HAZARDS: Lifetime skin painting tests indicate that
materials of similar composition have produced skin cancer 1n
~xperimental animals. The relationship of these results to humans has
·t been fully established.
-------------------------------------------------------------------
IV. FIRST AID ----------------------------------------------------------------------EYES: Flush with ~ater for at least 15 minutes. Get medical attention
if irritation persists.
SKIN: Immediately flush with large amounts of water. Use soap if
available. Remove contaminated clothing, including shoes, after
flushing has begun if irritation persists, seek medical attention.
MATERIAL SAFETY DATA SHEET
PRODUCT: DIESEL FUEL DATE: September 27, 1991
INHALATION: Rescuers should wear respiratory protection. Remove
immediately from contaminated area. Apply artificial respiration if
breathing has stopped. If breathing is difficult, administer oxygen.
INGESTION: Due to the possibility of aspiration into the lungs, do not
induce vomiting, keep at rest and call a physician.
NOTES TO PHYSICIAN: Treatment is directed at the control
and the clinical condition of the patient. There is
•ntidote.
of symptoms
no specific
·-------------------------------------------------------------------V. FIRE & EXPLOSION HAZARDS ----------------------------------------------------------------------FLASH POINT & method (C): 40 PMCT
FLAM.MABLE LIMITS(% in air):
LOWER: 0. 7
UPPER: 6.5
EXTINGUISHING MEDIA: Use dry chemical, carbon dioxide, alcohol foam,
or water spray.
SPECIAL FIRE FIGHTING PROCEDURES: Respirators
fire-fighting personnel. If possible to do so safely,
fire. Use water spray tri cool fire-exposed surfaces
personnel.
required for
shut off fuel to
and to protect
Avoid spreading burning liquid with water used for cooling containers.
When using water spray, boil-over may occur when the product
temperature reaches the boiling point of water.
UNUSUAL FIRE & EXPLOSION HAZARDS: Vapours from this product may travel
or be moved by air currents and be ignited by pilot lights, other
flames, smoking, sparks, heaters, electrical equipment, static
discharges or other ignition sources at locations distant from the
point of handling. ----------------------------------------------------------------------VI. PHYSICAL DATA ----------------------------------------------------------------------The following physical data are approximate only
~present specification values. They should only be
1text of this Material Safety Data Sheet.
-,.;ILING POINT (C): 150 -370
SPECIFIC GRAVITY (lSC): 0.85
and do not
used in the
VOLATILITY ( % ) : 100
APPEARANCE & ODOUR: White or pale yellow liquid with characteristic odour. ----------------------------------------------------------------------
VII. REACTIVITY -------------------------------------------------------------------STABILITY: Stable.
CONDITIONS TO AVOID: Heat, sparks and other sources of ignition. INCOMPATIBILITY: Strong oxidizing agents. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide and carbon dioxide on burning.
HAZARDOUS POLYMERIZATION: Will not occur. ----------------------------------------------------------------------
VIII. PREVENTIVE MEASURES ----------------------------------------------------------------------SPILLS & LEAK PROCEDURES:
MATERIAL SAFETY DATA SHEET PRODUCT: DIESEL FUEL DATE: September 27, 1991
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: LAND SPILL: Eliminate source of ignition. Keep public away. Prevent additional discharge of material, if possible to do so without hazard. Prevent spills from entering sewers, watercourses or low areas. Contain spilled liquid with sand or earth. Do not use combustible materials ;uch as sawdust.
Recover by pumping (use an explosion proof motor or hand pump), or by using a suitable absorbent.
Consult an expert on disposal' of recovered material. .Ensurg disposal in compliance with government requirements and ensure conformity to local disposal regulations. Notify the appropriate authorities immediately. Take all additional action necessary to prevent and remedy the adverse effects of the spill. WATER SPILL: Remove from surface by skimming or with suitable adsorbents. If allowed by local authorities and environmental agencies, sinking and/or suitable dispersants may be used in unconfined waters.
Consult an expert on disposal of recovered material. Ensure disposal in compliance with government requirements and ensure conformity to local disposal regulations. Notify the appropriate authorities immediately. Take all additional action necessary to prevent and remedy the adverse effects of the spill. WASTE DISPOSAL METHODS: Controlled incineration or use waste disposal service in accordance with federal, provincial and local regulations. In case of large spills warn public of downwind explosion hazard.
SPECIAL PROTECTION INFORMATION:
RESPIRATORY PROTECTION: Approved organic canister mask or air-supplied respirator.
VENTILATION: Local exhaust recommended. General mechanical ·rentilation suggested to maintain below TLV. Electrical and .,1echanical equipment should be explosion-proof.
PROTECTIVE GLOVES: Chemical resistant gloves.
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EYE PROTECTION: Goggles to prevent eye contact.
ADDITIONA.L PROTECTIVE EQUIPMENT: Rubber suit and boots.
~DDITIONA.L INFOR..'IATION:
HANDLING & STORAGE: Keep container closed. Store in a cool,
ell-ventilated place away from oxidizing agents and sources of
.gnition. Product is a static accumulator. Transfer equipment
should be properly grounded or bonded.
OTHER INFOR..'~~TION: Containers may retain hazardous residues when
------------~----------PREPARATION INFORMATION-------------------------
CONTACT MSDS CO-ORDINATOR, VAN WATERS & ROGERS LTD.
DURING BUSINESS HOURS, EASTERN TIME (416)-736-9299.
-------------------------------NOTICE----------------------------------
**VAN WATERS & ROGERS LTD. EXPRESSLY DISCLAIMS A.LL EXPRESSED OR IMPLIED
WARRANTIES OR MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE WITH
RESPECT TO THE PRODUCT PROVIDED.**
emptied and should be commercially cleaned before reuse.
IX. PREPARATION INFORMATION
PREPARED BY:
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RECORD NUMBER
LANGUAGE
PRODUCT NAME(S)
PRODUCT IDENTIFICATION
DATE OF MSDS
SUPPLIER/DISTRIBUTOR
ADDRESS
DATA
*** IDENTIFICATION***
594071
ENGLISH
DIESEL FUEL
VAN WATERS & ROGERS MSDS NO.: L0153
1991-12-19
*** SUPPLIER INFORMATION***
Van Waters & Rogers Ltd (Canada)
9800 Van Horne Way
Richmond British Columbia
Canada V6X lWS
EMERGENCY TELEPHONE NO.(S) 800-424-9300 (CHEMTREC)
*** MATERIAL SAFETY DATA***
'.53.2 DIESEL FUEL
VAN WATERS & ROGERS LTD.
WHMIS CODES:
9800 VAN HORNE WAY RICHMOND, 8.C. V6X 1~5
8.3 D.28
----------------------EMERGENCY ASSISTANCE---------------------------
FOR E:-!ERGEIICY ASS I STANCE INVOLVING CHEMICALS CALL CHEMTREC ( 800) 424-9300.
--------------------FOR PRODUCT AND SALES INFORMATION-------------------
CONTACT YOUR LOCAL VAN WATERS & ROGERS BRANCH OFFICE
-------------------PRODUCT IDENTIFICATION-------------------------------
PRODUCT NAME: DIESEL FUEL CAS NO.: UNASSIGNED COMMON NAMES/SYNONYMS: A COMPLEX MIXTURE VW&R CODE: L0153 OF ALIPHATIC, OLEFENIC, NAPHTHENIC AND AROMATIC HYDROCARBONS
FORMULA: MIXTURE
HAZARD RATING (NFPA 704)
HEALTH: l
FIRE: 2
REACTIVITY: 0
SPECIAL: NONE
DATE ISSUED: 06/91
SUPERCEDES: 06/88
HAZARD RATING SCALE:
O=MINIMAL J=SERIOUS
l=SLIGHT 4=SEVERE
2=MODERATE
-------------------------HAZARDOUS INGREDIENTS--------------------------
COMPONENT CAS NO. 1flXTURE OF ALIPHATIC OLEFINIC, NAPHTHENIC AND AROMATIC
HYDROCARBONS (UNREPORTED)
%
>99
EXPOSURE LIMITS, PPM
OSHA ACGIH .OTHER
PEL TLV LIMIT
100 100 NONE
HAZARD
COMBUSTIBLE
-------------------------PHYSICAL PROPERTIES----------------------------
BOILING POINT, DEG F: 356-698 MELTING POINT, DEG F: -21.2 SPECIFIC GRAVITY (WATER=l): 0.85
VAPOR PRESSURE, MM HG/20 DEG C: 30 VAPOR DENSITY (AIR=!): 4 WATER SOLUBILITY, %:
INSOLUBLE APPEARANCE AND ODOR: WHITE EVAPORATION RATE (BUTYL ACETATE=!): <l OR PALE YELLOW LIQUID; PETROLEUM ODOR
--------------------------FIRST AID MEASURES----------------------------
IF INHALED: REMOVE TO FRESH AIR. GIVE ARTIFICIAL RESPIRATION IF NOT BREATHING. GET IMMEDIATE MEDICAL ATTENTION.
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IN CASE OF EYE CONTACT: IMMEDIATELY FLUSH EYES WITH LOTS OF RUNNING I WATER FOR 15 MINUTES, LIFTING THE UPPER ANO LOWER EYELIDS OCCASIONALLY. GET IMMEDIATE MEDICAL ATTENTION.
IN CASE OF SKIN CONTACT: IMMEDIATELY WASH SKIN WITH LOTS OF SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND SHOES; WASH BEFORE REUSE. GET ,!CAL ATTENTION IF IRRITATION PERSISTS AFTER WASHING.
IF SWALLOWED: DO NOT INDUCE VOMITING. GET IMMEDIATE MEDICAL ATTENTION.
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IF VOMITING OCCURS SPONTANEOUSLY, KEEP VICTIM'S HEAD BELOW HIS HIPS TO
PREVENT HIS BREATHING THE VOMITUS INTO HIS LUNGS.
---------------------HEALTH HAZARD INFORMATION------------------------
:-!ARY ROUTES Of EXPOSURE: INHALATION, SKIN OR EYE CONTACT.
SIGNS AND SY:-!PTO:•'.S OF EXPOSURE
INHALATION: BREATHING VAPOURS MAY IRRITATE THE NOSE AND THROAT AND
CAUSE COUGHING AND CHEST DISCOMFORT, AND ANESTHETIC. MAY CAUSE HEAD-
ACHES, DIZZINESS AND OTHER CENTRAL NERVOUS SYSTEM EFFECTS.
EYE CONTACT: LIQUID AND MIST MAY IRRITATE THE EYES.
SKIN CONTACT: BRIEF CONTACT MAY DRY THE SKIN. PROLONGED OR RE-
PEATED CONTACT MAY IRRITATE THE SKIN, CAUSING DERMATITIS.
SWALLOWED: SWALLOWING THE LIQUID MAY RESULT IN VOMITING. IF
VOMITING OCCURS SPONTANEOUSLY, DO NOT ALLOW VOMITUS TO BE BREATHED INTO
THE LUNGS AS EVEN A SMALL QUANTITY IN THE LUNGS MAY RESULT IN CHEMICAL
PNEUMONITIS AND PULMONARY EDEMA/HEMORRHAGE.
CHRONIC EFFECTS OF EXPOSURE: LIFETIME SKIN PAINTING TESTS INDICATE THAT
MATERIAL OF SIMILAR COMPOSITION HAVE PRODUCED SKIN CANCER IN EXPERI-
MENTAL ANIMALS. THE RELATIONSHIP OF THESE RESULTS TO HUMANS HAS NOT
BEEN FULLY ESTABLISHED.
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: NONE REPORTED.
·--------------------------TOXICITY DATA-----------------------------
uRAL: NO DATA FOUND
DERMAL: NO DATA FOUND
INHALATION: NO DATA FOUND
CARCINOGENICITY: THIS MATERIAL IS NOT CONSIDERED TO BE A CARCINOGEN
BY THE NATIONAL TOXICOLOGY PROGRAM, THE INTERNATIONAL AGENCY FOR
RESEARCH ON CANCER, OR THE OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION.
OTHER DATA: NONE
-------------------------PERSONAL PROTECTION----------------------------
VENTILATION: LOCAL MECHANICAL EXHAUST VENTILATION CAPABLE OF MAIN-
TAINING EMISSIONS AT THE POINT OF USE BELOW THE PEL.
RESPIRATORY PROTECTION: IF USE CONDITIONS GENERATE VAPORS OR MISTS,
WEAR A NIOSH-APPROVED RESPIRATOR APPROPRIATE FOR THOSE EMISSION LEVELS.
APPROPRIATE RESPIRATORS MAY BE A FULL FACEPIECE OR A HALF MASK AIR-
PURIFYING CARTRIDGE RESPIRATOR EQUIPPED FOR ORGANIC VAPORS/MISTS, A
SELF-CONTAINED BREATHING APPARATUS IN THE PRESSURE DEMAND MODE, OR A
SUPPLIED-AIR RESPIRATOR.
~ PROTECTION: SAFETY GLASSES WITH SIDE SHIELDS. IT IS GENERALLY
~OGNIZED THAT CONTACT LENSES SHOULD NOT BE WORN WHEN WORKING WITH
CHEMICALS BECAUSE CONTACT LENSES MAY CONTRIBUTE TO THE SEVERITY OF AN
EYE INJURY.
PROTECTIVE CLOTHING: LONG-SLEEVED SHIRT, TROUSERS, SAFETY SHOES, IMPERVIOUS GLOVES, A.ND IMPERVIOUS APRON.
,ER PROTECTIVE :cEASURES: AN EYEWASH A.ND SAFETY SHOWER SHOULD BE NEARBY AND READY FOR USE.
--------------------FIRE AND EXPLOSION INFORMATION----------------------
FLASH POINT, DEG F: 104
METHOD USED: PMCC
EXTINGUISHING MEDIA: USE WATER SPRAY, DRY FOAM.
FLAMMABLE LIMITS IN AIR, %
LOWER: 0.7 UPPER: 5.0
CHEMICAL, CO2, OR ALCOHOL
SPECIAL FIRE FIGHTING PROCEDURES: FIRE FIGHTERS SHOULD WEAR SELF~ CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING. USE WATER SPRAY TO COOL NEARBY CONTAINERS AND STRUCTURES EXPOSED TO FIRE.
UNUSUAL FIRE AND EXPLOSION HAZARDS: EXTINGUISH ALL NEARBY SOURCES OF IGNITION. MAY FORM COMBUSTIBLE MIXTURES AT OR ABOVE THE FLASH POINT. FLAMMABLE/TOXIC GASES WILL FORM AT ELEVATED TEMPERATURES. TOXIC GASES WILL FORM UPON COMBUSTION MATERIAL MAY ACCUMULATE STATIC CHARGES WHICH MAY CAUSE AN ELECTRICAL FIRE.
-------------------------HAZARDOUS REACTIVITY---------------------------
STABILITY: STABLE POLYMERIZATION: WILL NOT OCCUR CONDITIONS TO AVOID: HEAT, SPARKS, AND OPEN FLAMES .
.'ERIALS TO AVOID: STRONG OXIDIZING AGENTS.
HAZARDOUS DECOMPOSITION PRODUCTS: MAY LIBERATE CARBON MONOXIDE AND CARBON DIOXIDE AND OXIDES OF SULFUR.
-----------------SPILL, LEAK, AND DISPOSAL PROCEDURES-------------------
ACTION TO TAKE FOR SPILLS OR LEAKS: LAND SPILL: ELIMINATE SOURCE OF IGNITION. KEEP PUBLIC AWAY. PREVENT ADDITIONAL DISCHARGE OR MATERIAL, IF POSSIBLE TO DO SO WITHOUT HAZARD. PREVENT SPILLS FROM ENTERING SEWERS, WATERCOURSES OR LOW AREAS. CON-TAIN SPILLED LIQUID WITH SAND OR EARTH. DO NOT USE COMBUSTIBLE MATERIALS SUCH AS SAWDUST.
RECOVER BY PUMPING (USE AND EXPLOSIION PROOF MOTOR OR HAND PUMP), OR BY USING A SUITABLE ABSORBENT.
CONSULT AN EXPERT ON DISPOSAL OF RECOVERED MATERIAL. ENSURE DISPOSAL IN COMPLIANCE WITH GOVERNMENT REQUIREMENTS AND ENSURE CONFORMITY TO LOCAL DISPOSAL REGULATIONS. NOTIFY THE APPROPRIATE AUTHORITIES IMMEDIATELY. TAKE ALL ADDITIONAL ACTION NECESSARY TO PREVENT AND REMEDY THE ADVERSE EFFECTS OF THE SPILL.
WATER SPILL:
REMOVE FROM SURFACE BY SKIMMING OR WITH SUITABLE ABSORBENTS. IF ALLOWED BY LOCAL AUTHORITIES AND ENVIRONMENTAL AGENCIES, SINKING AND/OR SUITABLE DISPERSANTS MAY BE USED IN UNCONFINED WATERS. 1SULT AN EXPERT ON DISPOSAL OF RECOVERED MATERIAL. ENSURE DISPOSAL .. COMPLIANCE WITH GOVERNMENT-REQUIREMENTS AND ENSURE CONFORMITY TO LOCAL DISPOSAL REGULATIONS. NOTIFY THE APPROPRIATE AUTHORITIES IMMED-
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IATELY. TAKE ALL ADDITIONAL ACTION NECESSARY TO PREVENT AND REMEDY
THE ADVERSE EFFECTS OF THE SPILL.
,POSAL METHODS: DISPOSE OF CONTAHINATED PRODUCT AND MATERIALS USED
:LEANING UP SPILLS OR LEAKS IN A MANNER APPROVED FOR THIS MATERIAL.
'--·•SULT APPROPRIATE FEDERAL, STATE AND LOCAL REGULATORY AGENCIES TO
ASCERTAIN PROPER DISPOSAL PROCEDURES.
NOTE: EMPTY CONTAINERS CAN HAVE RESIDUES, GASES AND MISTS AND ARE
SUBJECT TO PROPER WASTE DI?POSAL, AS ABOVE.
-------------------------SPECIAL PRECAUTIONS----------------------------
HANDLING AND STORAGE PRECAUTIONS: KEEP AWAY FROM HEAT, SPARKS, AND
FLAMES. STORE IN A COOL, DRY, WELL-VENTILATED PLACE AWAY FROM INCOM-
PATIBLE MATERIALS. VENT CONTAINER FREQUENTLY, AND MORE OFTEN IN WAfu~
WEATHER, TO RELIEVE PRESSURE. ELECTRICALLY GROUND ALL EQUIPMENT WHEN
HANDLING THIS PRODUCT AND USE ONLY NON-SPARKING TOOLS. KEEP CONTAINER
TIGHTLY CLOSED WHEN NOT IN USE. DO NOT USE PRESSURE TO EMPTY CONTAINER.
WASH THOROUGHLY AFTER HANDLING. DO NOT GET IN EYES, ON SKIN, OR ON
CLOTHING.
REPAIR AND MAINTENANCE PRECAUTIONS: DO NOT CUT, GRIND, WELD, OR DRILL
ON OR NEAR THIS CONTAINER.
OTHER PRECAUTIONS: CONTAINERS, EVEN THOSE THAT HAVE BEEN EMPTIED, WILL
RETAIN PRODUCT RESIDUE AND VAPORS. ALWAYS OBEY HAZARD WARNINGS AND
HANDLE EMPTY CONTAINERS AS If THEY WERE FULL.
----------------------PREPARATION INFORMATION--------------------------
CONTACT MSDS CO-ORDINATOR, VAN WATERS & ROGERS LTD.
DURING BUSINESS HOURS, EASTERN TIME (416)-736-9299.
------------------------------NOTICE------------------------------------
**VAN WATERS & ROGERS LTD. EXPRESSLY DISCLAIMS ALL EXPRESSED OR
IMPLIED WARRANTIES OF MERCHANTABILITY AND FITNESS FOR A PARTICULAR
PURPOSE WITH RESPECT TO THE"PRODUCT PROVIDED.**
------------------------------REVISION----------------------------------
06/91: ADDED INHALATION, UNUSUAL FIRE, HAZARDOUS DECOMPOSITION.
REVISED CHRONIC EFFECTS, FLASH POINT, SPILL, PROTECTIVE
CLOTHING, BOILING POINT, MELTING POINT.
* * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * *
*
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M S D S
Canadian Centre for Occupational Health and Safety
*
*
*
* * * * * * * * * * * * * * * * * * * * * * * * • * * * * * * * * .
*** IDENTIFICATION***
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* * * * * * * * * * * * * * * * * * * * * * * * * * * * * w w * *
M S D S *
*
* Canadian Centre for Occupational Health and Safety •
RECORD NUMBER
LANGUAGE
PRODUCT NA;'lE ( S)
PRODUCT IDENTIFICATION DATA
DATE OF MSDS
•** IDENTIFICATION***
588601
English
GASOLINE, BP REGULAR LEADED
Msds No: 2324
1992-04-20
*** MANUFACTURER INFORMATION***
MANUFACTURER
ADDRESS
SUPPLIER/DISTRIBUTOR
ADDRESS
BP Oil Company
200 Public Square
Cleveland Ohio
U.S.A. 44114-2375
Telephone: [phone]
*** SUPPLIER INFORMATION***
BP America
200 Public Square
Cleveland Ohio
U.S.A. 44114-2375
(General Assistance1
~MERGENCY TELEPHONE NO. (S) 800-362-8059 (In Ohio, 24-Hour Assistance)
800-321-8642 (Outside Ohio, 24-Hour Assistance)
800-424-9300 (CHEMTREC Assistance, 24-Hour)
**·* MATERIAL SAFETY DATA ***
24-HOUR EMERGENCY ASSISTANCE GENERAL ASSISTANCE -----------------------------------------------------------BP America(In Ohio):800-362-8059 216-441-8106
(Outside Ohio):800-321-8642
CHEMTREC Assistance:800-424-9300
MSDS Number> 2324 Version# 1
MANUFACTURER/SUPPLIER:
BP Oil Company
ADDRESS: 200 Public Square, Cleveland, OH 44114-2375
NFPA FIRE HAZARD
Flammability: 3
Heal th l
Reactivity 0
Spl.Hazards:
===----=====--=--==-=== PRODUCT IDENTIFICATION =======================IO=
TRADE NAME:
GASOLINE, BP REGULAR LEADED
Date: 04 / 2 0 / 9 2 -----------------------------------------------------------------------------
CAS NUMBER:
SYNONYM(S):
GASOLINE; MOTOR
1-!EMICAL FAMILY:
IYDROCARBON
.• -.,LECULAR FORMULA:
MOLECULAR WEIGHT:
MIXTURE
FUEL
MIXTURE
MIXTURE
PRODUCT CODE:
HIERARCHY:
P 16 J 5
040.040
--=--=------=-==-==-=== PRODUCT HAZARD SUMMARY -===================-==PH-'LTH
.JANGER!
HAR..~FUL OR FATAL IF SWALLOWED
ASPIRATION HAZARD IF SWALLOWEO--CAN ENTER LUNGS ANO CAUSE OA11AGE VAPORS YJ>.Y BE HAR..~FUL
YJ>.Y BE IRRITATING TO THE SKIN, EYES ANO RESPIRATORY TRACT LONG-TER..~ EXPOSURE TO VAPORS HAS CAUSED CANCER IN SOME LABORATORY ANI:1ALS
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F~~::;~~~~~;~----------------------------------------------------------------1
DANGER!
EXTREMELY FLAl1.MABLE LIQUID AND VAPORS VAPOR ~AY CAUSE FLASH FIRE D --------------------------.--------------------------------------------------REACTIVITY
STABLE
=========-======== PRODUCT HEALTH HAZARD INFORMATION =================HH=
1
INGESTION: ti MODERATELY TOXIC. Human oral LDLo = -10-JO gms. Aspiration into lungs may II cause pneumonitis. May cause gastrointestinal disturbances. Symptoms may include irritation, nausea, vomiting and diarrhea. May cause harmful central nervous system effects. Effects may include excitation, euphoria, headache, I dizziness, drowsiness, blurred vision, fatigue, tremors, convulsions, loss of consciousness, coma, respiratory arrest and death.
-1N: ----------------------------.--------------------------------------------1
.-\.CTICALLY NON-TOXIC. Rabbit dermal LOSO = >S ml/kg. SLIGHTLY IRRITATING. Repeated or prolonged contact may result in defatting, redness, itching, 1. inflammation, cracking and possible secondary infection. High pressure skin injections are SERIOUS MEDICAL EMERGENCIES. Injury may not appear serious at first; within a few hours, tissue will become swollen, discolored and e~:::::::_~~=~=~=-~===-~~:::_:~-:~:::::~~-:::::~~~: __________________________ • EYE:
May_cause_slight_transient_irritation. _______________________________________ 1 INHALATION:
May cause respiratory tract irritation. Exposure may cause central nervous system symptoms similar to those listed under "Ingestion" (see Ingestion I section). May also cause anemia and irregular heart rhythm. Repeated or prolonged exposures may cause behavioral changes. s~~~~~-;;~~~-~;;~~;~~-------------------------------------------------------,
May cause adverse liver and kidney effects based on tests with laboratory animals. A product of similar composition has been found to be carcinogenic to laboratory animals when given by inhalation. Also, a variety of I mutagenicity assays have been conducted that have yielded conflicting results
IARC has determined that there is limited evidence for the carcinogenicity gasoline in experimental animals and inadequate evidence fqr the carcinogenicity of gasoline in humans. (IARC Class--2B).
.. llliING: The use of any·hydrocarbon fuel in an area without adequate ventilation may result in hazardous levels of combustion products and I
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inadequate oxygen levels. IARC has determined that gasoline engine exhaust __
possibly carcinogenic to humans. (IARC Class--2B).
is product contains benzene. Benzene is carcinogenic to laboratory animals
n given by intubation or by inhalation. There is an association between
~ _upational exposure to benzene and human leukemia. Carcinogenic
determination: IARC--Human and Animal sufficient evidence of carcinogenicity;
(IARC Class--1); NTP--Known carcinogen; ACGIH--Suspected carcinogen.
Acute benzene poisoning causes central nervous system depression. Chronic
exposure aifects the hematopoietic system causing blood disorders including
anemia and pancytopenia. Mutagenic and clastogenic in mammalian and
non-mammalian test systems. Reproductive toxicant only at doses that are
maternally toxic, based on tests with animals.
====-=---------==--==--===----FIRST AID =============================FA=
INGESTION:
DO NOT INDUCE VOMITING BECAUSE OF DANGER OF ASPIRATING LIQUID INTO LUNGS. Get
immediate medical attention. If spontaneous vomiting occurs, monitor for
breathing difficulty.
SKIN CONTACT:
Remove contaminated clothing immediately. Wash area of contact thoroughly
with soap and water. Get medical attention if irritation persists. High
pressure skin injections are SERIOUS MEDICAL EMERGENCIES. Get immediate
medical attention.
EYE CONTACT:
~lush immediately with large amounts of water for at least 15 minutes.
~lids should be held away from the eyeball to ensure thorough rinsing. Get
Jical attention if irritation results.
INHALATION:
Remove affected person from source of exposure. If not breathing, ensure
clear airway and institute cardiopulmonary resuscitation (CPR). If breathing
is difficult, administer oxygen if available. Get immediate medical
attention.
========================= NOTES TO PHYSICIAN =========================PN=
INGESTION: The most important risk to assess is the extent of aspiration of
the product into the lungs since an acute chemical pneumonitis can rapidly
progress to respiratory failure. Gasping, coughing, and choking are
presumptive evidence of aspiration. It is suggested that all patients
suspected of hydrocarbon aspiration have base line chest x-rays. Immediate
hospitalization should be considered for asymptomatic children with an
abnormal chest x-ray, obtunded or hypoxic patients, intentional or massive
ingestions, and patients with abnormal chest x-rays with clinically
significant pulmonary disease.
Gastrointestinal symptoms are usually minor and pathological changes of the
liver and kidney are reported to be uncommon in acute intoxications.
Decontamination (induced emesis or lavage) is controversial and should be
considered on the merits of each individual case; of course the usual
precaution of an endotracheal tube should be considered prior to lavage.
irocarbons may increase the sensitivity of the myocardium to catecholamines;
__ ectrocardiographic monitoring may be indicated and careful consideration
should be given to the selection of bronchodilalators.
Acute central nervous system signs and symptoms may result from large ingestions or aspiration-induced hypoxia.
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\LATION ABUSE: Gasoline is one of the solvents used by chemical substance. ~ers. These patients may present with acute and/or chronic central nervou system signs or symptoms. They may also present with arrythmias.
In case of skin injection, consider prompt debridement of the wound to minimize necrosis and tissue loss.
PERSONAL PROTECTION INFOfu'!ATION EYE PROTECTION:
Avoid eye contact with this material. Wear safety glasses or chemical goggles. Provide facilities in the work area for immediately flushing the eyes.
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B -----------------------------------------------------------------------------SKIN PROTECTION:
1 Avoid skin contact. If skin contact is anticipated, protective clothing, including impervious gloves, should be worn. Wash hands if they come in contact with this material. Use good personal hygiene. Wear regularly cleaned work clothing. Showering and changing into street clothing after woriu is desirable. Product spilt on clothing may result in delayed evaporation anctJ a subsequent fire hazard. Wash contaminated clothing separately. If clothing is to be laundered by someone else, inform launderer of proper procedures. ----------------------------------------------------------------. __________ ff RESPIRATORY PROTECTION: IJ If exposure limits are exceeded or if irritation is experienced, NIOSH approved respiratory protection should be worn. Ventilation and other forms Ji r -engineering controls are often the preferred means for controlling chemic, 11 osures. Respiratory protection may be needed for non-routine or emergenc) situations.
========================= PHYSICAL PROPERTIES ========================PR= BOILING POINT: 26.67 -226.7 C (80 -440 F) SPECIFIC GRAVITY: 0.72 -0.74@ 60 F
MELTING POINT: NA
% VOLATILE: 100 @ 437 F
VAPOR PRESSURE: 760 MM HG@ 100 F
EVAPORATION RATE (WATER=l}: >l
VAPOR DENSITY (AIR=l): 1.2 AS VAPOR
VISCOSITY: ND
% SOLUBILITY IN WATER: NEGLIGIBLE
OCTANOL/WATER PARTITION COEFFICIENT:
POUR POINT: ND
pH: ND
APPEARANCE/ODOR:
CLEAR LIQUID WITH A STRONG HYDROCARBON ODOR.
====--===-=-=========== FIRE AND EXPLOSION DATA ====================--FE=
FLASH POINT: -37.000 C (-35 F} TCC
AUTOIGNITION TEMPERATURE: 444.000 C (833 F) FLAMMABILITY LIMITS IN AIR(% BY VOL.) LOWER:
1.400
FLAMMABILITY LIMITS IN AIR(% BY VOL.) UPPER: ·oo
~ ,IC FIREFIGHTING PROCEDURES:
Use dry chemical, alcohol foam, all purpose AFFF or carbon dioxide to
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extinguish fire. Water may be ineffective but should be used td cool
fire-exposed containers, structures and to protect personnel. If leak or
spill has not ignited, ventilate area and use water spray to disperse gas o:
•par and to protect personnel attempting to stop a leak. Use water to dil~:e
lls and to flush them away from sources of ignition. Do not flush down
~ .Jlic sewers or other drainage systems. Exposed firefighters must wear
MSHA/NIOSH appro•:ed positive pressure self-contained breathing apparatus wi:h
full face mask and full protective clothing. · -----------------------------------------------------------------------------UNUSUAL FIRE A.ND EXPLOSION HAZARDS:
Dangerous when exposed to heat or flame. Vapors form flammable or explosi•;e
mixtures with air at room temperature. Vapor or gas may spread to distant
ignition sources and flash back. Vapors may concentrate in confined areas.
Runoff to sewer may cause fire or explosion hazard. Containers may expl~de Ln
heat of fire. Irritating or toxic substances may be emitted upon thermal
decomposition.
==-------===========-=-===-REACTIVITY DATA ==========================RO=
STABILITY/INCOMPATIBILTY:
Stable under conditions of normal use. Avoid contact with strong oxidizers. -----------------------------------------------------------------------------HAZARDOUS REACTIONS/DECOMPOSITION PRODUCTS:
Combustion may.produce CO, CO2 and reactive hydrocarbons.
====================== ENVIRONMENTAL INFORMATION ==========.===========EI=
SPILL OR RELEASE TO THE ENVIRONMENT:
If your facility or operation has an ''Oil or Hazardous Substance Contingency
Plan'', activate its procedures.
Take immediate steps to stop and contain the spill. Caution should .. be
e.xercised regarding personnel safety and exposure to the spilled ma'.terial.
For technical advise and assistance related to chemicals, contact CHEMTREC
(800/424-9300) and your local fire department.
Notify the National Response Center, if required. Also notify appropriate
state and local regulatory agencies, the LEPC and the SERC. Contact the
local Coast Guard if the release is into a waterway.
Emergency Action:
Keep unnecessary people away; isolate hazard area and deny entry. Stay
upwind; keep out of low areas. (Also see Personal Protection Information
section.) Isolate for 1/2 mile in all directions if tank, rail car or tank
truck is involved in fire.
Spill or Leak Procedure:
Shut off ignition sources; no flares, smoking or flames in hazard area. Stop
leak if you can do it without risk. Water spray may reduce vapor; but it may
not prevent ignition in closed spaces. Small Spills: Take up with sand or
other noncombustible absorbent material and place into containers for later
disposal. Large Spills: Dike far ahead of liquid spill for later disposal.
Notification:
Clean Water Act (Oil Spills):
·ny spill or release, or substantial threat of release, of' this material to
,igable water (virtually any surface water) sufficient to cause a visible
_ .. een upon the water must be reported immediately to the National Response
Center (800/424-8802), as required by U.S. Federal Law. Failure to report may
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result in substantial civil and criminal penalties. Also conta=t the coast Guard and appropriate state and local regulatory agencies. D
CERCLA/SARA (Chemical Spills):
reportable quantity for this material is 333 * pound( s). ,,
This material contains one or more constituents regulated as hazardous substances under U.S. federal Law. Any spill or other release, or substantifl threat of release, of this material to the air, water or land (unless entire111 contained in the workplace) equal to or in excess of the reportable quantity· must be reported immediately to the National Response Center ( 800/-12-1-8802). Also contact appropriate state and local regulatory agencies. Contact the I Coast Guard if spilled into navigable waterways under their jurisdiction. Failure to report may result in substantial civil and criminal penalties.
* Calculated on the basis for whichever hazardous component provides the lowest value for: ,I
-------------------------~~-~-~-=~-~=~=~:: _________________________________ j WASTE DISPOSAL:
This substance, when discarded or disposed of, is not specifically listed as I hazardous waste in Federal regulations; however it could be characteristicall hazardous if it is considered toxic, corrosive, ignitable, or reactive according to Federal definitions (40 CFR 261). Additionally, it could be designated as hazardous according to state regulations. This substance cou1JI also become a hazardous waste if it is mixed with or comes in contact with a'--11 hazardous waste. Check 40 CFR 261 to determine whether it is a hazardous waste. If it is a hazardous waste, regulations at 40 CFR 262, 263, 264, 268 •. '270 apply. Chemical additions, processing or otherwise altering this .erial may make the waste management information presented in this MSDS Lncomplete, inaccurate or otherwise inappropriate. I
The transportation, storage, treatment, and disposal of this waste material must be conducted in compliance with all applicable Federal, state, and local regulations. _________________________________________________________________ •
SARA TITLE III INFORMATION:
Listed below are the hazard categories for the Superfund Amendments and Reauthorization Act (SARA) section 311/312 (40 CFR 370): Immediate Hazard: X
Delayed Hazard: X Fire Hazard: X
Pressure Hazard:
Reactivity Hazard: -
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This product contains the following toxic chemicals subject to toxic chemical release reporting requirements of the Superfund Reauthorization Act (SARA) Section 313 (40 CFR 372):
the annual I Amendments and
Component: CAS Number: Toluene 108-88-3 Xylene 1330-20-7 Benzene 71-43-2 1,2,4-Trimethylbenzene 95-63-6 Ethylbenzene 100-41-4 Cvclohexane 110-82-7
Maximum%
4.000
4.000
3.000
3.000
1.000
l. 000
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I ------------------------------------------------------------------------· I .. _JITIONAL ENVIRONMENTAL REGULATORY INFORMATION: This material contains a substance listed as a hazardous air pollutant under
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U.S. Federal regulations.
to its use.
See 40 CFR Part 61 for restrictions which may appl;
is material contains a mixture of substances, some of which are listed as
ic pollutants pursuant to 40 CFR 122.21, Appendix D, Tables II/III/V. An;
~ ~sual introduction of this substance into th.e facility's process streams,
stormwater and/or wastewater could result in the violation of U.S. Federal
Law. Facilities must notify the USEPA as soon as they know, or have reason to
believe, that any activity has occurred, or will occur, which would result in
the discharge of a toxic pollutant which is not regulated in the facility's
NPDES permit: Notification levels are described in 40 CFR 122.42(a)(l) and
122.42(a)(2). Refer to spill section for additional regulatory requirements.
There may be specific regulations at the local, regional or state level that
pertain to this material.
=======-==============-REGULATORY INFORMATION =======================RI=
This product contains ingredient(s) known to the State of California to cause
cancer, birth defects or other reproductive harm. --:=,:::::,_'"J
Contains Benzene. Consult OSHA Standard 1910.1028. Initial air monitoring
should be conducted to determine if exposures are above 0.5 ppm action limit
or l ppm PEL. If exposures are above, OSHA requirements apply for training,
medical surveillance, personal/protective equipment, regulated areas, etc.
The following Canadian Workplace Hazardous Materials Information System
(WHMIS) categories apply to this product:
Compressed Gas
Flammable/Combustible
X
Other Toxic Effects
X
BioHazardous
Oxidizer
Corrosive
Acutely Toxic
Dangerously Reactive
============ SPECIAL PRECAUTIONS/SUPPLEMENTAL INFORMATION ============SP=
HANDLING/STORAGE:
Store gasoline only in approved, clearly labeled containers. Never store in
glass or unapproved plastic containers.
Store in tightly closed containers in cool, dry, isolated, well-ventilated
area away from heat, sources of ignition and incompatibles. Ground lines and
equipment used during transfer to reduce the possibility of static
spark-initiated fire or explosion.
Use good personal hygiene practices. Wash hands before eating, drinking,
~oking, or using toilet facilities. Remove contaminated clothing and clean
:ore reuse. Shower after work using soap and water. Do not siphon this
~-□duct by mouth. Use only as a motor fuel. Do not use for cleaning,
pressure appliance fuel, or any other use. Do not store in unlabeled
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containers. Keep out oE reach oE children.
E~~;~-~~~;~~~~;~~------------------------------------------------------------1
Empty containers may contain toxic, flammable/combustible or explosive residL ·,apors. Do not cut, grind, drill, weld, reuse or dispose containers unles1· c ~uate precautions are taken against these hazards.
=======-===== TRANSPORTATION REQUIREMENTS (DOMESTIC LAND) D.O.T. PROPER SHIPPING NAME (49 CFR 172.101): GASOLINE, 3, D.O.T. HAZARD CLASS (49 CFR 172.101):
------------TR=
UN 1 2 0 3 , PG I I
3 •
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UN/NA CODE (49 CFR 172. 101): UN 1203 PACKING GROUP (49 CFR 172.101): FLAfU-IABLE LIQUID BILL OF LADING DESCRIPTION (49 CFR 172.202): GASOLINE, 3, UN D.0.T. LABELS REQUIRED (49 CFR 172. 101): FLAMMABLE LIQUID D.O.T. PLACARDS REQUIRED (49 CFR 172.504): FLAM.'IABLE LIQUID
1203, PG II
•• ================ INGREDIENTS/HEALTH HAZARD INFORMATION ---------------IN-COMPONENT I CAS NO. I % I EXPOSURE LIMITS -REF G~;~i1~;----------------------saa5=6i=9---99~99=iaa--;aa-~~;-(890-;;i;;~-;~~~1
oline may contain the following:
500 ppm
( 1480 mg/m3) STEL (ACGIHI
300 ppm (900 mg/m3) PEL;
500 ppm
(1500 mg/m3) STEL (OSHA.JI
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----------------------------------------------------------------------------, Toluene 108-88-3 0-4 50 ppm (188 mg/m3) TLV (
kin)
(ACGIH)
100 ppm (375 mg/m3) PEL;. 150 ppm
(560 mg/m3) STEL (OSHA)
100 ppm (375 mg/m3) TWA; 1.
150 ppm
(560 mg/m3) STEL (NIOSH)
---------------------------------------------------------------------------1 Xylene 1330-20-7 0-4 100 ppm (434 mg/m3) TLV;
150 ppm I (651 mg/m3) STEL (ACGIH)
100 ppm (435 mg/m3) PEL;
150 ppm
(655 mg/m3) STEL (OSHA) I
100 ppm (435 mg/m3) TWA;
150 ppm
(655 mg/m3) STEL (NIOSH) I
(
•. zene 71-43-2 0-3 10 ppm (32 mg/m3) TLV \ ....
GIH)
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1,2,4-Trimethylbenzene
Ethyl benzene
Cyclohexane
Remaining components not
determined hazardous and/or
hazardous components present
at less and 1.0% (0.1% for
carcinogens).
95-63-6 0-3
100-41-4 0-1
110-82-7 0-1
l ppm PEL; 5 ppm STEL '.)5
HA)
0. l ppm TWA; l ppm STE:. (
NIOSH)
25 ppm ( 123 mg/m3) TLV (A
CGIH)
25 ppm ( 125 mg/m3) PEL (0
SHA)
100 ppm (434 mg/m3) TLV;
125 ppm
(543 mg/m3) STEL (ACGlH)
100 ppm (435 mg/m3) PEL;
125 ppm
(545 mg/m3) STEL (OSHA)
100 ppm (435 mg/m3) TWA;
125 ppm
(545 mg/m3) STEL (NIOSH)
300 ppm (1030 mg/m3) TLV
(ACGIH)
300 ppm ( 10 5 0 mg/m3) PEL
(OSHA)
300 ppm (1050 mg/m3) TWA
(NIOSH)
NA
The OSHA Permissible Exposure Limits listed above were promulgated by OSHA in
1989. This standard was vacated by the U.S. Court of Appeals for the Eleventh
Circuit. Exposure limits defined in specific chemical standards found in
29 CFR 1910.1001-1048 are not covered by this ruling and are still
enforceable. -----------------------------------------------------------------------------
REVISION DATE: 20-apr-1992
COMPLETED BY:
REPLACES SHEET DATED: 21-jan-1991
BP OIL HSEQ DEPARTMENT ·----------------------------------------------------------------------------·---------------------------------------------------------------------------NOTICE: The information presented herein is based on data
considered to be accurate as of the date bf preparation of
this Material Safety Data Sheet. However, no warranty or representation, express or implied, is made as to the accuracy or completeness of the foregoing data and safety information, nor is any authorization given or implied to practice any patented invention without a license. In addition, no responsibility can be assumed by vendor for damage or injury resulting from abnormal use, from any failure to adhere to recommended practices, or from any hazards inherent in the nature of the product.
any
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S4037 -02
EfFect1ve. JS,'29/86
}}){ <·}::f'.t'),>~!\'.) 1·.." \;1,: .' ( ..
v: .. MAJER)~i/ · ...
;.'., -SAFETY DAT A
I;L:~~·~,t!.:\\,i-; .
P~ge -
I!:i!:iued. 08 ✓:8/S
···---··---·-·······--···----·-····-----··--------------·-·---------···-··-·--· SECTION I -PRODUCT IDENTIFICATION.
----------------····-··········-··-··-----------------·····-·····--·····-······ Product Name:
Formula:
Formula Wt:
CAS No.
NIOSH,RTECS No.
Common Synonym!:,:
Prod•.lct. Ci:ide~:
Sodium Hydroxide, SO~ Solution
NaOH
40.00
01310-73-2
WB490S000
Cau~tic Sada;
3727,372S
Sodium Hydrate; Lye
------·············-········-··--·-·-----·-····-------------------·····-······· PRECAUTIONARY LABELLING
-----------···--···-············-····--·-·---········--····-···············---■
~[[][]][a
SCVER( NONE IGlERAT'E EXTRDC
Laboratory Protective Ecuipmcnt
Pr,~aut1onary Label Stotemont,
POISON! DANGER!
CAUSES SEVERE BURNS
HAY BE FATAL IF SWALLOWED
Do not get ln eyes, on skin, on clot~ing.
Avo\d breathing vapor. Keep in tightly closed container.
ventilation. Wa~h thoroughly after handl1ng.
--------------------------------------------·······-··-··-····-···-···--···-•= SECTION II -HAZARDOUS COHPONENTS
------···-----------------------------------------···----····················· Comoonent
50
·····--·-··········-···············--·-----··········-····-·---------·-······· SECTION III -PHYSICA~ DATA
··-·····---------------------------------------------------······-····--······ Boiling Point: l42'C
Helt i ng Point : 12'C
288'Fl
S4'F l
Conti~ued on Pao~:
Uapor Pre~suretmmHgl l
2
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1-l'HE\I RF..'iF. IRL'H
S4037 -02 Sodium H~1drow1de, SO'\ Sr:ilution p~,...• EFfect1ve: 08/29,,,86
I~!or.i~d: I:~.,,, -----------··········-----···-·-·-·-·--····-·-·-·········-·····-·······---·
SECTION III -PHYSICAL DATA CCont1nuedl ···········································································1
Spec 1 F ic Grav1 t9: 1. 53 Evaporat 10n R.ste: t-J <H 20•ll
(Butyl Acetate•ll
Complete
Qippearance & Odor: Clear, colorle55 slight.!~, v1.!t,:or.1s l1qri1d: no oC.f1r II ···········································································11' SECTION IU -FIRE ANO EXPLOSION HAZARD DATA
Flammable L1m1ts: Upper -N/l'l ' Fire Extingy1;hinq Hedi& Use eKt1ngu1shin9 media appropriate for surrounding ftr~ I
Sceciat Fire-F1;htins Procedures I Flood ~1th ~ater, do not splatter or splash this material
Unu,uol Fire & Explosion Ho;ord, Reacts with most metals to produce hydrogen gas, ~hich can form an I ~xplosive mi~~ure witn air. ··············································································
Thr.,shold L1mi t Ualue C TLU✓TWA l: 2 mg/m 3 ppml
Permi,sible E•posure Limit < PEL l : 2 mg/m 3 ppm)
Toxicity: Loso Cipr-mousel<mg✓kgl 40
Carcinogenicity: NTP: No IARC: No z List: No OSHA reg: Nr,
Effect, of Overe•ao,urt
Inhalation of vapors may cause severe irritation or burns of the respirator~ system, pulmonary edema, or lung inflammation. Liquid may cause severe burns to skin and e~es. L1qu1d may eause permanent eye damage. Ingestion is harmful and may be f~tal. Ingestion may cause severe burning to mouth and stomach. Ingestion may cause nausea and vomiting.
Cont 1nued on Page: 3
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1-CHF.\I RF.SF.\RCH
ChtmutJ /rt TIit Contauur BuHi,tss''"
S4017 -02
£F~ect1ve 1:;g,,·2s,.-a8 P~ge
l••u~d, 08/23--5
-----------------------------·-········--··------------------------------------SECT ION 'J -HEAL TH HAZARD D"'TA <Continued l
---······-·--·-·----·······--------------------------··········-········-------·
Med1ral C?nd1t10"' G~n~rallY Aggravated Eu ~xco,ure
Norie Ident1.f1ed
Route, Of En:tru
1nhalat1on, 1ngest1on) eye contact, skin contact
Emera,ney and fir,t A1d Procedure,
C~LL A PHYSICIAN.
If ,wallowed, do NOT induce
water Follow with diluted
1.11th. water.
vomiting; if consctous,
vinegar, fruit JUtce or
give 14rge 4mcu~t~ cf
~httes of eggs. b~~~e-
If inhaled, remove to fresh air. IF not breatning, give art1F1c1al
resp1rat1on. If breathing 1s d1ff1cult, give ox~1gen.
In case of coritai::t, immediately flu5,)i eyes or skin r.,n+.h pll'!nt.~, of t.1~+.er
at le4st 15 ~1nute~ while removing contaminated clotn1ng and shoes
Wash clotn1ng before re-use
··-····-------·······-----··-·····--····----------·--·············--·-·-----=--SECTION UI REACTIUITY DATA
-------------·-··-···················--·--····-------···············--·----·--· St,sbllit," Stable
Conditions lo Avoid:
Incompatibles
Hazardous Polymerization: Wi 11 not" occur
moisture
organic materialsJ strong acids, most common metals,
water) zinc, aluminum, magnesium,
halogenated hydrocarbon•
··--·-··----··---------·-·-----····---·······-····-----·-····-------·----·---·· SECTION UII -SPILL ANO DISPOSAL PROCEDURES
------·······--···-···-······-···········-----·-········-··-··-········-------· Stec, to b~ taken in tn, event of a scill or d1,~har2,
Wear self-contained breathing apparatus and full prote~tive clothing. 5~:
le~k if you can do so without risk. Uent1late area. Car~fully neutral:ze
spill with dilute HCl Flush area w1tn flooding amount~ of t.1ater cu~e
c-5.ution.)
J. T. Baker·Neutracit-2R caustic neutralizer 1s recommended
for ,pill• of thi• product
Di,so,al Proceduro
Di•po•e in accordance ~ith all applicable federal, ,tats, and local
environmental regulations.
EPA Hazardou~ W,s•t~ Number: D002, D003 (Corro,ive, Reactive Wa,tel
········-····-·--·--·············-·········-···········-·········---·--········ SECTION UIII -INDUSTRIAL PROTECTIUE EQUIPMENT
·············------·-············--····--·-----------·················--··••:■■ Uent1lation: U~e general or lo~al exhau!t ventilation la m~et
Continued on Pag~ 4
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1-CHF.\1 Rf..,F.\Rl'H
Clur,ustr /,r The Cott1a111,r But1fleH . .,.
S4037 -02 Sodium Hydroxide~ 50% Solution P-!ge: Effective 09,29,96 Issued: oa,·2:3.~
Respiratory Protection:
TLU requirements.
Respiratory protection required if airborne
concentrat10n exce~ds TLU. At concentrat1ons up
to 60 ppm, 4_ high-efficiency p~cticulate
respirator 15 recommended. Above this lev~l. ~
self-contained breathing appar~tus 1s adv1sed.
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Eye/Skin Prot~ct1on: Safety goggles and f-sce shield, urnfcrm, I
· protective suit, rubber glove~ ar~ r~~ommended
-------------------·······--------------------------···········-·······-···-·· SECTION IX -STORAGE AND HANDLIN(; PREC:AIJTIONS
;:;:;:~:;:;~·;::::::·:::::·:::::···:::::·;:::::·················~-----······1
Sceeiol Precoution,
Keep container tightl9 clo5ed. Store in corros1on-proof area.
Isolate from incompatible materials.
Pcopec Shipping Name
Hazacd Cla••
UN/NA
Label•
R~poctable Quantity
INTERNATIONAL (I.Ho.
Sodium hydcoxide, •elution
Corro•ive matecial <liqu,dl
UN1824
CORROSIVE
1000 LBS.
Proper Shipping Name Sodium h')1drox1de) solution
Hazacd Cla•• 8
UN/NA UN1824
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~=~=~: .................... ~~!~~~!~! ............... ~ ..........................•
N/A • Not Applicable or Not Available
~~; information published in this Haterial Safet~, o~ta Sheo1Jt h~.'!t b~ll!n comp1 ll
from our experience and data presented 1n vari~us technical publication~. It _
the user's responsibility to determine the suitability of this information for
the adoption of necessary safet9 precautions. &J-, reserve tne right to r!'v1~.I!'.
Hater1al S~fety Data Sheets per1odical·ly as ne~ 1nformat1on become~ ~-:~1l~bl
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1-CHF.\I RF.SF.\RCH
H"3880 -02
Ef-Fect1·...1e: 88/07/86
Hydrochloric Acid P-,gs, l
I·-our d, 18.·"l s.·,g ······················································~········-········-·······
Product Na.me:
For-mula:
Formu\4 Wt:
SECTION I -PRncucT IDEIITIFICATION
H~1drochloric Acid
HCl
36.46
7647-01-0
MW4025000
CAS No.
NIOSH/RTECS No.
Comma n Synonym~ :
?reduct Code~:
Hur1at1c Acid; Chlorohydr1c Acid; Hydrochloride
9543,9539,9535,5367,9534,9544,95~9,9~12,4Bna,9519,95~n,q548
9540,9547,9546,9537
PRECAUTIONARY tnBELLING
•••••••••••••••,••••••••••••••••••••••••••••••••••••••••••••r;••••••••,••~•-•~••
8AKE:R SAf-T-OATA TH Su~tpm
POISON! DANGER!
CAUSES SEUERE BURl~S
HAY BE FATAL IF S~ALLOWED OR INHALED
Do not get 1n eyes, on ~kin, on cloth1n9.
Do not breathe vapor. Keep in tightly clo~ed container. Loosen clo~ure
caut10u~ly. U!te ""'1ith adequ.ate ventilation. Wa~n thcrough!y llfter
handling. In case of spill neutralize with sod~ a~h or lime and place 1,~
dry container.
······························································~·~-···•~••······· SECTION I I -HnZARDOl!S C011POr~EN':'S
·········································································~·····~ ens ~ro.
Hydrochloric Acid (23° 84umel
··········································································•~-•-· SECTION III -PHYSICAL DATA
801 ling Point; ll □'C C 23 o• Fl Uap~r Pres~urcCrnmHg!
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1-l'HE\I Rf.Sf. \Rl'H
H3880 -02 Hydrochlorsc Acid F-'-1sc 'I F.Ffect tve: 08/07/86 Iooued: 0::'./:S.· ····················································,········•~■■■T ■ra ■,~-■92•■ SECTION III -PHYSICAL DATA CC~ntinuedl •····••••••··•··••·••·••·••·•••···•·•••••·•T ■••·····•··•···••••,■■~■■~-■-■■r-■1
Helting Point: -2s•c C -t3•F> l.'apor O,,n,itytair•l l 1.3
Specific Gravity:
tH2 0•l l
Flaoh Point:
Flammable Limit,:
1.19
Complete (in all prop~rtion~l
Upper -N/A \
Fico £xt1ng4i3hipg H~dia
Ev4por~ti~n R~te:
(Butyl Ac,.t~te•ll
\ Uolatil,.s by Ucl~m~: 10:
Use extinguishing media appropriate For surrounding Fire.
Scec1ol Eice-Ficht+ng Proc1dur1a
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Firefighters should wear proper protective eq:uipmerit .:ind !">elF--cc.;:""1'ta,':.ne,~ I breathing apparatuo with Full f,.cepiece operated in po~i•.ive pre,,,,re med-. Hove containers from fire area it= it can b• done w1thc.11.1t r i:·,k. ~~c :..1.st..:r to keep f1re-e•posed containers cool. Do not get ~ater inside container$,
Unu~uol Fire & Ex;lo~ign Ha;ards Hay emit hydrogen gas upon contact
Ioxie Go;e3 Produced
hyd~ogen chloride, hydrogen gas
with metal.
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················-·····-·;;;;;~~-~-=-;;~~.;:;-;;;~;;·;~;;·············~---,·······1
····-···-····-------·------------···-···········-----------·-·········~----·-·· PEL and TLU listed denote ceiling limit.
Threohold Limit Ualue CTLU✓TWA>: 7
Permissible Exposure Limit CPELl: 7
Coral-rabbitl<mg/kgl
Cipr-mouael(mg/kgl
Cinhl-rat-lHl Cppml
3 mg/m (5
PP"':
900
.q n
212"1
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1-CHE\t RF.SF.\RLH
~3380 -02
EFFectlve: 08/07✓86
Hydrochloric Acid Fag e : _
houecl·. OS-'15.'86 ······················-·······················································~-SECTION U -HEALTH HAZARD DATA CContinuedl
••••••••••••••••••••••••••••••••••••••••••••••,••••••••,•••••••••,■~••••~-•••~•r
Carcinogen1c1ty: NT?: No !ARC: No Z Li:lt: No OSHA reg: Nn
Effect~ of Qvece•go;ure
In~~lat1on of vapor$ may cause pulmonary edem~, e1r~ulatory sy3t~m ccllap~e, damage to upper resp1rotory ~yatem, coll~pse. In~alation of vapors mey cause coug~1ng &nd difficult breathing. L1qu1d may cause severe burns to skin and eyea.
!ngeot,on ,, harmful and may be fatal.
Inge~t1on may cause severe burning to mouth and stom~ch.
Inge3t~on may cause nausea and vomiting.
Routes Of Entry
ingestion, inhalation, s~1n contact, eve contact
E~ergency and Eirtt Aid Procedure~
CALL A PHYSICIAN.
If swallowed, do NOT induce vomiting; if c0nac10us, give w,3ter, mllk~ or milk of magnesia.
If inhaled, remove to fresh air. If not breathing, g,ue artif,c,al reop,ration. If breathing is diff,cult, giue oxygen.
In case of contact, immediately f=luah eyes or a\cin t.aith plent.y of i..,4:er f,:.r at least 15 minutes ~hile removing contaminated clothir1g and ~hoes. Wash clothing before re-use.
Stabi llty: Stable
Incompatibles:
SECTION UI -REACTIVITY DATA
W\ l l not. cc-cur
heat, moisture
most common metals, water, amines, metal 0111d-.,s, ,3cet ic annydr 1de, propio lactor,e, \oil r;yl acetate,
mercuric sulfate, calcium phoaphide, Form~ld~hyd~,
alkalies, carbonates, ~tro~g bas~a,
sulfuric aeid, chloroaulfon,c aeid
Deeompooit1on Products: hydrogen chloride, hydrogen, chlorine ........................••.....•.....•...•................ , ....... , ..... , ...... .
SECTION VII -SPILL AND DISPOSnL PROCEDURES ····································································~-·,--., .... St~a~ to be taken in the event of A ~2111 or diochorae Wear self-eont5incd breathing apparatu5 and Full protect1ve cl0thi~0-~t~;: leak if you ean do oo without riok. Ventilate area. Neutral,:e op,11 w.th 5oda a~h or lime. With clean 5hovel, carefully place mater:~l in~o ~1c~n, dry container and cover; remove From area. Flu5h sp\ll are4 ~ith ~~ter.
J. T.
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1-CHE.\1 RESE \RCH
H3880 -02 H1>drochloric A,:1d p ''J•'-Effect1.·,.1e: 08/07/86 :~::.:......:.:-1:: "'!3/:-:;.· ·························································•~~--,·~-,·--~·--,~-~ SECTION UII -SPILL ANO OISPOSnL PROCEOUR~S rCont1nue~l
are recommended for ~pills of th1$ produ~t
Di,□o~al ?rgcedure
01$pO$e 1n accordance ~1th ~ll 4pplic~ble federal, stat", ,ind lc•~a,; ~n .... ·1ronmental regulat~ons. I
E?A H~zardous Waste Mumber: 000:! CCorrosi·.,e IJ-1ste l · ----------------;~~;~~~-~~~~-~-~~~~;;;~~~·;;~;;~~~~~-~;~~;~;.~:·-··----··------1
Uent 1 L~t ion:
Respirator~ Protection:
Eye/Skin Protection:
U~e general or local e)fh.!lust vent1lat.10'°"' trJ nir.et TtU requirements.
Respiratory protection reqlJ1red if a1rborn~ concentrat1on exceeds TLU. At con~~ntrdt1on3 u;-to 100 ppm, a chemical cartridge re$p1rat~r ~,th acid cartridge is recommended. r1bo•.;e t.his l~·. -d a aelF-contained breathing apparatu3 1~ a1~~,1~,~d
TH SAF-T-DATA Storage Colar Code: White
Special Precoution3
Keep container tightly closed. Store in c0rro~1on-pro0F ate~ Isolate From 1nco~pat1ble materials.
Do not store near 0x1diz\ng mater1~ls.
SECTION X -TRA~lSPORTAT!ON DATA ANO ADOITIO~IAL !N~ORHA'!'IO,:
DOHESIIC rp.o.r.
Proper Shipping Name
Hazard Cla,u
UN/NA
Labe h
Reportable Quantity
INTERNATIONAL (I.H.0.
Proper Shipping Name
Hazard Class
UN/NA
L<!be h
~ydr0chlor1c acid
Corr0si~e material (l1quidl
UN1789
CORRosr~•E
5000 LBS.
H~:drccMlor1c acid, ?>i..~lu~.io~•
8
U~11:-99
CORROSIL'E
-----·
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1-1 HF\I RESF \RlH
H3880 -02 Hydrochloric ~c1d
Ef fecti·,e: 08/07.··86
N/A • Not Appl1ca~le cc Not Available
?.3ge. 5
:~~uc.:d: :J? .. ·:~ .. ·es
The 1nformat1on published 1n this Haterial s~Fet~ Data Sh~et h~~ b~en co~pi:ed
from our e>e:per1ence and Cata presentr:d 1n various techn1c.:i.l publ 1cat.1ons :: .,_.
the user's responsibility to determine the suitability of th1!1 1nform.1t1cn fe-r-
the adoption of necessary ~~fety precautions. We re~erve the rig~t :o rr~1~e
Material Safety Data Sheets periodically as ne~ inform~t1on b~com~s ava~:a~!e
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I-CHE:>! RESE\RCH
S8234 -02
Effective: 09/08/86
Sulfur1.c Ac1.d Page: l
Issued: 09/09/86
-------··-········-------------·-------------·····-----·-··--·--····-·-··-------SECTION I -PRODUCT IDENTIFICATION
-----···------------······----------------------------------------···-----------Product Name:
Formula:
Formula Wt:
CAS No, :
NIOSH/RTECS No.:
Sulfuric Acid
H2 so 4
98.08
07664-93-9
WS5600000
Common Synonym~:
?rod1Jct .Code~:
Oil of Uitriol
5030,9691,9675,5340,9679,9687,9674,9686°,9694,9681,9698,9673
5432,5137,9685,4802,9684,9683,5643,9680,5374
------·-·······-····-····················--------------········--··---··--------PRECAUTIONARY LABELLING
-----------········-··--······-···-·········--·-----·······-------------------·-TH BAKER SAF-T-PATA Systpm
~[[J~Q
5C\>CR[ NtN: SC',0£ C<Tll[N: Laboratoru Protective Equipment
?recautionorv Lobel Statement~
POISON! DANGER!
HARHFUL IF INHALED
CAUSES SEUERE BURNS
HAY BE FATAL IF SWALLOWED
REACTS UIOLENTLY WITH WATER.
~kin, on clothing.
Keep in tightly closed container. Loosen closure
adequate ventilation. Wash thoroughly after
~o not get in eyes, on
Do not breathe vapor.
cautiously. Use with
handling. In case of
dry container,
5pill neutralize with 5cda a5h or lime and place in
········----··············-·················------------···-········--···---·-·· SECTION II -HAZARDOUS COHPONENTS
······-------------------------·----------------------------········-·-········· Component l CAS No.
Sulfuric Acid 90-100 7664-93-9
I
1-CHf.\l RESf.\RCH
I
·········----------------··-·····---------------------···--·-········-····-·-·--Bolling Point: 327•C 621.Fl Uapor Pressure (mmHg-l < 0 . 3 I Helt ing Point: -2•c 28 •Fl Uapor Denis 1 t y C air• 1 ) 3.'I
Specific Gravity·. l .8'1 Evaporation Rate: < l I cH 20•l l c Butyl Acetate•l l
SolubilityCH
2 0l: Complete (in all proportion" l ' Uolatiles by Uolume: i•VA I
Fla"h Point:
Flammable Limits: Upper -1,vA \
NFPA 70'1H Rating:
Lower -N✓

A

\
3-0-2 W
I fire Extingyi3hing Hedio Use dry chemical or carbon dioxide. Do not use water. I Sseciol Firo-fightins Proc1dur11 Firefighter" should wear proper protective equipment and self-contained I breathing apparatuo with full facepiece operated in po,.itive pre,.,.ure mode Do not get water 1ns1d■ containers.
UMu;uol Fire & Explosion Haiord3 B Reacts with most metals to produce h~drogen g~s, which can form an explosive mixture with air. A violent exothermic reaction occurs with water. $yffic1ent heat
1
may be produced to ignite combu,.tibl• material,..
Io~ic Gases Produeod
sulfur dioxide I ·················-·-······················--·--·-----·-·························
SECTION U -HEALTH HAZARD DATA ·····································-········-·································
Threshold Limit Ualue CTLU✓TWAl: 1
Permi,.aible Expo,.ure Limit CPELl: l
Toxicity: LD50 (oral-ratlCmg✓kgl
Carcinogenicity: NTP: No IARC: No
3 mg/m
ppm)
21'10
Z Li,.t: No OSHA reg: No
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C>ttmHII '" Tltt Co,uauttr B~IifTl'U,,.
58234 -02
Effective: 09/08/86
Sulfuric Acid P-oge : 3
I••ued: 09 ✓09 ✓86
------------·············-···············-····--·-···---·······-···········-·-·-SECTION U -HEALTH HAZARD DATA CContinuedl
-----·-·······-----------------············------------------··-----------------
Effect, of Qverexpo~ure
Inhalation of vapors may cause severe 1rr1tat10n of the respiratory system.
L1qu1d may cause severe burns to skin and eyes.
Ingestion 1s harmful and may be fatal.
Ingestion may cause nausea and vomiting.
Ingestion may cause severe burns to mouth, throat, and stomach. Hay have
adverse effect on kidney Function and may be fatal.
Chronic overexposure may result in lung damage.
Hed1cal Condition, Generally Aggravated Bu Expo3uro
None Identified
Rout~~ Of Entry
inhalation, ingestion, eye contact, skin contact
Emergency and Eir,t ~id Proceduro3
CALL A PHYSICIAN.
If swallowed, do NOT induce vomiting; if conscious, g1ve water, m1lK, or
m1lK of magnesia.
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen.
In ca~e of contact, immediately flush eyes or skin with plenty of water for
at least 15 minutes while removing contaminated clothing and ~hoes.
Wash clothing before re-use.
-------------------------------------------------------------------·······-----· SECTION UI -REACTIUITY DATA
---------------------------··············--······--------····-··----···-······--Stability: Stable Hazardous Polya,■rization: Will not occur·
Conditions to Avoid: moisture, heat
Incompatibles: water, most common metals, organic materials,
~trong reducing agents, combustible materials,
strong bases, strong oxidizing agents
Decomposition Products: oxides of sulfur
-------····-··-------------------------------------------------···-·------------SECTION UII -SPILL ANO DISPOSAL PROCEDURES
--------------------------------------------------------------------------------Stea~ to be token in tho event of o sa1ll or di3char20
Wear self-contained breathing apparatus and full protective clothing.
Stop leak if you can do so without risk. DO NOT use water
Neutralize spill and/or washin~ with soda ash or lime
With clean shovel, place material into clean, dry container and cover.
Move containerC•l from •p1ll area.
J. T. R R Baker Neutrasorb or Neutrasol ''Low Na•'' acid neutralizers
I
S8234 -02 Sulfuric Acid Page: J Effective: 09/08/86 Iooued:. 09,-09,-95 ·····--·--··;;;;i;~-~ii~:-;;;~~-~~;-;~;;;;~~-;;;~;;~;;;·:~:~;:~::~;-··-··------1
-------··-···········--·························--·--·-·-···-··-·---------------are recommended for spills of this product.
Di;po;al Procedure I Diopo•e in accordance ~ith all applicable Federal, otate, and local environmental regulations.
EPA Hazardouo Waote Number: 0002, D003 CCorrooive, Reactive Waotel I ········--·-···········-·····--··-···-·····---------·-··-···--·--·--------------................ ::::=~~-~;::.:.:~~~~~!=~=-~~~!=~~;~~-=~~::::~: ..................• Uent1lat1on: Use general or local e~haust vent1lat1on to meet ·
Respiratory Protection:
TLU requirement•.
None required where appropriate ventilation conditions exist. IF the TLU io exceeded, a oelf-contained breathing apparatus io advioed
Safety goggles and face ohield, uniforffl, protective suit, rubber gloves are recommended.
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---·-·-·······---;;~;~~~-~~-=-;;~;;~;-;~;-~~~;~;~~-;;;~~~;;;~;--·-·····------·--1
-----------------·-················----------·-··-···-···--··---·--·-··-----··--TH · SAF-T-DATA Storage Color Code: White
Special Preeaution~ I Keep container tightly clooed. Store in corrooion-proof area Keep eontaine~s cut of sun and away From heat. I --------------·-······-··········-··-··-··-·-----·······--·-········-·········--SECTION X -TRANSPORTATION DATA AND ADDITIONAL INFORHATION -----------------·····-···-·······-·--·-··----------·--··--·••.•········--······· DOHEST!C <D.Q.T.
Proper Shipping Name
Hazard Cla••
UN/NA
Labe h
Reportable Quantity
INTERNATIONAL CI.H 0.
Proper Shipping Name
Hazard Claos
UN/NA
Labe h
Sulfuric acid
Corrosive material Cliquidl UN1830
CORROSIUE
1000 LBS.
Sulphuric acid
B
UN1830
CORROSIUE ••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••r
N/A • Not Applicable or Not Available
The information publiohed in thi• Haterial Safety Data Sheet has been compiled
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I-< HF\I RhE \Rl'H
S8234 -02
Ef foct 1ve: 09/08/86
Sulfuric Acid Page: S
r.~ued: 09/09/86
--··--·----------------------------------------------------··········-·--·--··--from our experience and data presented in various technical publ1cat10ns. It is
the user's responsibility to determine the suitability of this information for
the adoption of necessary safety precautions. We reserve the right to rev1~e
Hater1al Safety Data Sheets periodically as new information becomes available.
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1-l'HDI RF.SURl'H
1-CH'.:~.1 Rl:SEARCH
23787-F Eic'..1-• C:•reet
Hayward, CA , < 3~5
N3660 -02
Effective: 09/10/66
N1. tr lC Ac id P~ge: 1
I,,ued: 09/12,.86
-------------···-····--------------·--·------·-----·--····--·-···-··----------·· SECTION I -PRODUCT IDENTIFICATION
--------------------······-····· ············---·-····· Product Name:
Formula:
Formula Wt:
CAS No.
NIOSH/RTECS No.:
Nitric Acid
HN03
63.01
7697-37-2
QU5775000
DILUTED T 0 3 5 %
Commo,-, Synonyms:
Product Code,:
Hydrogen Nitrate; Azot1c Acid
4601,9605,9602,9598,9606,9601,9597,S600,Sll3,9616,S371 ---------·-···········----------------·-----·-···········--·····-·-·-·····•·:••· PRECAUTIONARY LABELLING
---------------·····--·----·-----------------------····-········--·--···-~-----= TH BAKER SAF-T-PATA Sy)tem
Precautionary Label Stot~ments
POISON• DANGER! STRONG OXIDIZER -CONTACT WITH OTHER HATERTAL t1AY CAU::;E FIRF LIQUID AND UAPOR CAUSE SFUERE BURNS -HAY BF. FATAL IF SolALLOIJED HARHFlJL IF INHALED AND MAY CAUSE DELAYED LllNG It-UURY SPILLAGE HAY CAUSE FIRE OR LIBERATE DANGEROUS GAS Keep from c~ntact with clothing and other combust1hle material~. Do not ~tore near combustible materials. Do not get in e~e$, on skin} on ~loth1n9 Do not breathe vapor. Keep 1n tightly clo~ed container. U~e w1th ad~qu~·.e vent1lat10n. In case of Fire) use water spray~ alcohol f~am, dt·y ch~m\~al, or carbon dioxide. Flush spill area with waterspray.· · ----------·····--------------·-··--···--···············-···-·-------·-·········· SECTTON II -HAZARDOUS COHPONENTS
----------------------------········--········--·-···--···-·-···---··-···-······ Cgmponent
Nitric Ac id 65-75 7'6'.37-37-:
1-CHE\I RESE \Rl H
,-.3550 -02
Effective: 09/10/86
D
----------------------·-··;;~;;~~-;~;·:·;;~;~~~~-~~~~---·--········--·--··--·-,
-------------------------------------------------------------·········-··--·----
Melting Point:
Sp~cific Grav1ty:
rH 2O•ll
1
121 'C
-42'C
.41
Complete
Cclcrle~,
250'Fl
-44'Fl
(in all propr:irtion~)
liquid, with ,:hoking
Uapor Pres~ureCmmHg)
D Uapor Oen~ity<air•ll
Evaporation Rat.e: N/i~ 0 <Butyl Acetate•l)
' Uolat1le~ b~, Ua l 1Jm~ 1 on 0 odor.
Flash Point: NFPA 704H Rating:
'
3-0-0 OX'(
Fir~ Ext1n7y1sh1ng H~d1a
U5e t..1a.ter 5pra)i.
Sp~=1al F1r~-Fi1ht1~2 Procedures
' Lower -N.-'A D
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F1r~F19hter5 !.hould wear proper protective equipment a.nd ~elF-cont~:.ne-d I brea~h1ng apparatus with full Facep1ece operated 1n po~1t1ve pres~ure mod Move e~pos~d ccnta1ner5 from Fire area if 1t can be done without ri~k TJ~e ~a+er to ke~p f1r~-exp~sed contain~r~ cool~ do not get ~~ter in.~1d~
u~u~ual Fire & E•plo~1on Hozord5 I
Strong oxidizer Cont~ct with other material may cause fire.
~~~1c Ga~es Pc~duc,d I nitrogen oxides) ~ydrogen g~s
Thr~~hold Limit U<!lue < TL1J,TWA l s mg-'m 3 r2 ppm l I
Short-Term Exposure Limit CSTELl 10 mg/m 3 (4 ppm l
Perm15sible Exposur~ Limit c PEL l : s 3 r2 ppn, l mg.· m I
Carc1nogen1c1ty: NT?: No !ARC: Ne z L15t No OSHA reg· Na I E~Fec~~ of 0~,er~~co~ure
Inhalation of vapors m~y cause n~usea, uom1t1ng
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Chr,nnfl t,, T>it Co,uaintr Bu1111ns"'"
N3660 -02
EFFec:t1ve
N 1. tr 1 r: Ac 1. d ?age: 3
Is,ued: C?.'12/96
-----------------······---------····--·--·-·-------------------············--··· SECTION U -HEALTH HAZARD DATA CCont1nuedl
----------------············-·--······-···--------·-······················--···· headache
Inhalation of vapor~ may cau~e ~evere 1rr1tat1on of the r~~p1rat~ry ~~~~e~
Inhalation of vapor~ may cau~e coughing, ch~~t pain~, d1FF1culty brea~h1ng,
or uncon~c:10u~ne~~
Contact ~1th liquid or vapor ma9 cau~e ~evere 1rr1t~tion or b1Jrn~ of ~h~
~Kin, eyes, and mucou~ membrane~.
Inge~t1on may cau~e ~evere burns to m01Jth, throat, and ~t~mach. H~9 ~ave
adver~e effect on kidney function and may b~ Fatal
Inge~t1on 1s. harmful and ma~ be Fatal
~ed1cal Cond1tion5 Generally Aggravated 8\1 E~P05-Yte
None I dent 1 f 1ed
Rgyte:t OF Entrv
1nhalat10n) inge5t1on) eye cont~ct, ~kin ~ont~ct
E~ergencu and Firs.t Aid Proeedures
CALL A PHYSICIAN.
If s.1.1-5.llowed, do NOT indur:-e vom1t1ng~ 1F cr:in~c1r::it.1s.) g1·.;e wat.e:-, m;;.-c or
milk of magnes.ia.
If inhaled, remove to fre~h air If not breathing, g\~e art1f1c1al
resp1rat10~. If breathing 1s. d1Ff1cult, give O~\•g~n
In cas.e of con-t.act, 1mmed1ately flus.n ey~s. or s.k\.n wLth plent:; of w~· er for
at leas.t 15 minute~ while removing contaminated clotning and ~ho~s
w~s.n clothing before re-us.e. ----········-------·-·······--·---··-------·-----·--·--·-·············-•-=••~---SECTION UI -REACTIUITY DATA
············-···-··-·-········-····-------·-······--·-------··············•-=••· St.able ~1 l l not or:c~r
Incomp~t1bles· s.trong bases, combus.t1ble mater1,5.l~,
strong reducing agents, alkal1e~, mo~t cornn,on meta:s
org~n1c materials, alcohols., carbide
··------·-···--··--·----·---·-----------·--·-······-····················----···-SECTION UII -SPILL AND DISPOSAL PROCEDURES
----------------------------········-----·····-------------------~-=-••-------=-Ste g~ t.i l;ie ti2H:;n in t. h; §vent gf ,:a ~~111 ~c d15i:hacge
Wear 5elf-con+.a1ned breathing appl\ratu5 .,,nd full prrJtl'!ct:: •,•e :-:: 1 .:i '!', h 1 r:.; ;tot·
l~al< 1 f you can d~ ,o w1t.nout r l!-k.
s.oda a,h or l1me. oh th clean 5ho\.•el,
dry container and co•.;er ~ r~move From
Keep
J T.
combu5t1ble~ (1.100d, p~per, o 1 l
R Neutras.orb or R Neutra5ol
U~nt1late are,.,,, N~ U t, 1· ~ l l 'Z ii!" ~i?" l t...i ".. ~ h
carefully place mat.er1~l l I"', t 0 : : ~Cl,..,•
ar., a Fl,;, h 5pill ar~a W\. th r...:.a~er
etc ) ~!.14)) from s;lllled m~t~r:a:
"Lc,1..1.., tl~•"
N3660 -02
EFfective 09/l 0/86
Nitric Acid
are recommended for spills of this product
Disposal Procedure
Dispose 1n accordance w1tM all applicable federal, ~tate, and local
environmental regulations
EPA H~zardouo Waote Number: 0002 CCorrooive Wa•tel
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··········--------··-·---··-----------·-·-----·-···-·---------------------------................ ;::;;~~.~===·=-=~~~;;~=~=-:~~;::;;~:.:~~=:~:~; ................ ,
Uent1lat1on: U$e general or local exhau$t ventilation to me~t
Protect ion:
TLU requirements
Respiratory protection required 1f airborne
concentration e•ceeds TLU. At concentrat1on$ up
to 100 ppm, a chemic~l cartridge re~p1rator ~1th
acid cartridge 10 recommended. Above thio level,
a self-contained breathing apparalu$ i$-·adv1s~d.
Saf~ty goggle• and face oh1eld,
protective suit, ac1d-re~1~tant
recommended.
urnfcrm,
glove~ arl!
TH SAF-T-DATA Storage Color Code 'l'e llow
SpeC\41 Presaut1on3
Keep container tightly clo~ed. Store ~ep~rately and away from fl~mmable
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SECTION X -TRANSPORTATION DATA ANO AODITIOPlAL INFORMATION
••••••••••••••••••P•••••••••••••••••••••••••••••••••••••••••••••••••••••••••••••
DO,-,ESTIC cp.o T
Pr:iper-
H~z,5rd
UN/NA
Label•
Shipping
Cla••
Reportable Quantity
Hl,ERl;AT!ONAL C ! . H 0
Proper
Ha.za.r-d
UN,"NA
L-,bel,
Name
N1tr1c acid Cover 40~)
Oxidizer
UN2031
OXIDIZER, CORROSIVE
l00n LBS.
Nitric -5,:1d
8
UN:'n31
CORROSIVE
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N3660 -02
Effect1ve: 09/lQ/86
N1 tr-1c Ac 1d P~ge. S
r~~lH•_d: n9,,.12.-as
---···------------------------------------------------···-···-·····-···----------N/A • Not Applic4ble or Not Av4il4ble
The information published in this Material Safety Data Sheet has be~n comp11~1
From our experience and data presented 1n various technical publications Il l5
the user's responsibility to determine the suitability of this 1nformat1on fo~
the adoption of necessary safety precautions. We reserve the right to rev1~e
Hater1al Safety Data Sheets periodically as ne~ inforffiat1on becomes ava1lab!e
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'il1111BH~N~ I• instruments
Di,tributcd b~:
MA TERIAI. SAFETY DAT A SHEET
ZERO OXYGEN SOLUTION
m 71MO
SECTION I -PRODUCT IDENTlflCA TION
Produi:t :"'amt: Zero O,y1cn Solution
Chemical '."amc: Sodium mc1a-Bisulfitc. aqueous 'Mllution.
formula: ",,;a S 0 . • • l
Formula Wei1ht: 190.10
CAS. '."umber: ".1681-j74
Chemical Family: lnoraanic Salt
SECTION II • HAZAllDOUS COMPONENTS
SECTION V • HEAL TH HAZAllD DAT A
Thrrshold Limit \/111~ ITLV /TWA I:
Toxldty: LD.50 (oral-ratl:. SA
Erf ttts or Expc.ure:
Sodium mcta-Bisulfitc • ~~g m
lrri11tin1 to cyc:s. skin, and rc5p1ratory tract. ~hy ~ause
aller1ic reaction.
Pncautlonar, StOIII:
A.,.oid contact with eyes, skin. and clothin1. Wash 1horo1..:1hly
after handlina.
Emerrency and fint Aid Procedurf'S:
GET PHYS!CIAS IMMEDIATELY.
Ir eye contact. flush .,.,·ith plenty of wa1cr for al least 15
minutes. Get medical help.
Chemical Component C--o CAS. No. :"r111un of Huard
Ir swallowed. aivc two alasses of "'ater or milk. and :nducc
vomitin1 by s1ickin1 finaer down throat. ~c,·cr ai"c an~thing
by mou1h to an unconscious person. Contact medical a.s.smancc.
Sodium meia-Bisulfite < 4.0":"o 7681-$7-4
Water < 96.0"'o
SECTION Ill -PHYSICAL DATA
State: Liquid
Ap~aranct: Clear and Colorless
Boilin1 Point: > I 00 C
· .\1cltln1 Point: :"'1' A
Spe,ciflc Grnity: 1.02
Solubilily i"atcrl:~A
Odor: Sulfur Dio,;idc
Vapor PrHSurc (mm.H11: ~A
\'apor Ot-nsity lair=l): NA
[Yaponlion Rate: ~A
Starace Prttau1ions: Cool place.
SECTION IV
If skin contact. -.·ash e~posed area -.,.i1h soap and ,utcr. Get
mcdicai advice if irritation develops.
SECTION V1 · REACTIVTIY DATA
Stability: Stable
Haurdous Polymeradon: !'-Jone
Conditions to A •okl: None
Incompatibles: None
Decompo&itlon Products: He1tin1 emits toxic rumcs of
SO~ and Na 2o.
SECTION Vll
SPILL AND DISPOSAL PROCEDUR~
In C.. ot Spill o, --• Wear 1loves. and pick up spill with sponac.
Dlspolal l'Tocedun:
Oisp05e in accordance with all applicable federal. sute. and
local en"ironmcntal reaulations.
SECTION VID • TRANSPORATION DATA
Prope-r Shl'1Nnc Name: NA
Huard Claa: NA
FIRE AND EXPLOSION HAZARD DATA U~ Numbff: SA
Flash Point: NA
'ffPA Codes: Health: l
To1:ic GaHS ProcluC'NI: ~A
Fire Extln1uishin1 "hdla: SA
Pr1naO ,n L' 5 A.
Flammability: 0 Ructivity: 0
Note: The information in this document is bued on data
considered accurate. However Hanna lnstruments is :iot re•
sponsibile for the implied accuracy of the data or 1he :esults
obtained from iu use.
•~A . Defined as not applicable or not defined.
HANNA l!"o/SiRt.:ME!"o/TS. INC.
Po. Bo1 849
'-"oontoOCk~. RI 112•9'
Distrihutrd b~: D
D
MATERIAi. SAFETY DAT A SHEET I
OXYGEN PROBE ELECTROLYTE SOLUTION
ID 7041 I
SECTION I • PRODUCT IDENTIFICATION
Product ,ame: O,~aen Probe Electrol~te Solution
Chemical ,ame: Po1ass1um Chloride. aqueous Kilution.
Formula: KCI
CAS. ,umbtr: 7.U7-.l0-7
Chemical· Famil.": Inorganic' ~alt
SECTION II· HAZARDOUS COMPONENTS
SECTION V • HEALTH HAZARD DATA
Thrnhold limil \-'alue tTL\-'/TW.-\1: ~A
Toc1icilJ: LD50 (oral-rati· 'JA
EFfttu or E.,posurr:
lrritatin1 to e)e~.
Prtt■utionar, Ste,a:
A\01d contact v.i1h c~cs.
Emerlft'n(') and First Aid Procrdurn:
I
u
I
If e~e con1ac1. flush v.1th plenty of \loller ror JI le,m ill
m1nu1e~. Gc-1 medical help 1r imtat1on persist.\. II
Chemical Component "c, CAS .. !'-Jo. Nalure of Huard
I Potassium Chloride < !0.0°"c 7.W7-W-7
Water
SECTION Ill · PHYSICAL DATA
State: Liquid
.\p~arann: CleJr and Colorle\\
Boilin1 Poinl: > I 00 C
.\1ehinc Point: 'A
Spttirlc GraYil;W: 1.04
Solubility I water 1: 'A
Odor: ~one
\'apor Prnaure Imm H11: 'A
Vapor Dtnsily iair=II: ~A
E"apon1tion llatt: 'A
Storatt' Prccaution'.'I: '-one
SECTION IV
NA
FIRE AND EXPLOSION HAZARD DATA
fluh Polnl: ~ A
'iFPA Codes: NA
Toxic Gata Prod\K'H: Sone
fire Er.tln1uishin1 Media: '.\
SECTION VI • REACTIVITY DATA
Stabillly: Stable
Haurdous Polyfflff■tlon: ~one
Conditions to A"oid: :,,,Jone
lnrompatlbln:: Sone
Dtcompoddon Producu: ~one
SECTION VU
SPILL AND DISPOSAL PROCEDURES
In c-of Spill o, Dl..-!ta, .. , NA
oi.-1 PrO<ffure: NA
SECTION Vlll • TRANSPORATION DATA
Pr-Sht.,.;na Name: NA
Huard 0-: NA
L:N Number: ~A
I
I
I
I
I
I
I
~ate: The informalion in lhis document is based on data
considered accurate. Hov.ever Hanna Instruments is not ':'I
sponsibile for the implied accuracy or the data or the resu!
obtained from its use.
•SA . Defined u not applicable or not defined. I
HA~!'ri,A l!"'ri5TRCMESTS.. ISC. -I l'r11,tcd ,n I,.: S A.
P.O. 8o1 &49
""'oonM>Ci.ct. Ill !l211'i!l
- ---- - -
MALLINCKRODT
Material Safety Data Sheet
-1!!!1!11 l!!!!!l!I I!!!!!! l!!!!!!!I I!!!!!!
Mallinckrod1 pmw:k1 lhe information (Ofllained herein 111 SOOd rai1h
bul male• no rt:p,acatalion u lo i11 ('OfflJ)fthcftliweftCIII or 11tn1ncy.
lndililidualt rcttMq the inlorma1ion midi ucrrilc lhcir indc:ptndc:nl
jYdlJ'Mnl in dctcrminin1 iu appropri111cncu fOf • P-tdcular purpmc.
MAWNCICRODT MAKES NO kEl'llllSl!NT A TIONS, OR
WARRANlll'.S, Enlll!R l!XJ'RE.55 OR IMrLil!D; OP
MaUinruodt, Inc. Science Producu Division, P.O. Boa M Paris, KY 40361
REAGENT ALCOHOL
PRODUCT IDENTIFICATION:
fomnala CAS No.: Mid■ft
Molecular Wcipl: Nol applicable.
Chemical Ponnulll: Nol applicable.
Haurdoul lnpcdicall:
CAS #64-17-l: 90 porto clh)'I a1cobo1
C.AS "67-ll>-1: l pon1 mclh)'l alcobol
CAS ,'67-<ll-O: S pon1ioopropy11kobo1
PRECAtmONARY MEASURES
DANGDU MAY II& fATAI. If 5WAI..UJWKD.
H.UlMfUL If INHAliD. n AMI.UN IJ
AJYEcn Offl'IAL IQ:RWMIS SYSUN. MAW CA.UK at.lNDNUS.
C4UIU aaatr.A.110tt.
Kup away front lllcal, 1parb ud Oaa,c.
Kup coa.taiac:r clmcd.
Ute wiah adcqualc ¥COlilatKla.
Do DOI biuthc ¥11p0f.
Wuh lborou&Jlly aller handl"'I,
EMERGENCY/FIRST AID
Ir ,..lkMicd, indYCC 'flOfflitina iaunc4ia1dy by pvina; rwo PUICI ot
.,..,er and 11itkin1 ruapr ..._ ltuuet Keep pedeal'a bud bckM'
. hipa while ~111111. Ncwr p,tc UJlh"'I, by moutb 10 ea
uftC'Oftlriolll pc non-If lahalcd, rcmowc 10 rrnh aJr. Ir not
brnlhilll, pvc an if Kial rupiradoa. If brca1bin1 ii difficull, r,,c o.,sca. la ■II cue, caU ■ pllpician.
SEE Sl!CTION l.
DOT Huard Clau: Flammable Liquid
Sr&IJQN I nnkal Qplf
AA,i,ipca,-,c Ocu, -llqold.
<MarO.ms lltlcodor.
s,; rn:1 • .._.. __ .... ,_
..... """" 'll'C (172.4'1') (dlluol)
Mc11Jas"""" -114"C (-17J'I') (••->
Spodlk OrMJ(-ar•I): 0.79
Yapx l>cMIJ (Air• I): 1.6 (••-)
Yapx ,_,,,. (-Ha); SO@ Z5"C (77'1') (•-)
e.poncicla-: (C0.•l)ra. l.4(ctlluol)
SECQQN J Qq eM lnl I e lelmHlhl
fin:
P bl1 POl'~(prindpa1a.poacA1):
l"r\j ..,, IJ'C (SS"P).
AIOlaipkicla .._n,.re: 422°C (79)"1').
p t,, ......... , .. bJ'wlw:
kl • J.J; ocl • 19.
,r1 I 1 • --po111._.,m1at ....... •lpOIM-
fttrm+te lillkil IIOlodl at,,orwc.
flnt:a1 Media: Waoc,..,..,,...,...,....__,...,orca.--.
Spodal .._.._
la Iha cwut ol • r.,., wur foll pralC<tM -lwoi 111d
NIOSH ff!P n.wd 1e1f-1'0ftt■ieed "lrcaUlla1 appent .. whh run
rac,,cpiaa: opcralcd la tile ptalUl'C dc11111nd·01" OIIN:r politiw:
pRIMN mode. W■ler .,.., can be UICd lo edinpiah fira and
aNll firc~qaed oxal.aalen. Water may be ~ 10 Ru&tt apilll
--, rroa upmura ud to dilute spill& 10 aoa-llammabk
mut.rca.
Nt-"PA R•tlnp: ltc.allh: I Plammability J RuctMty O
l!!!!!!I l!!!!!I l!!!!!I l!!!!!!I
Ml!RCIIANTABIIIrt'. ~HNESS FOR A PAR·ncUIAR
PURPOSI! wrm RESPP.(T TO 11 II: INFORMA llON SET
R>Rlll lleREIN OR TO 1111! PROOU(T TO Wlll<ll llll'
INR>RMATION REFF.RS. ACCORJ)INGLY, MALLINCKROll r
WILL NOT DI! RESPONSIBI.P. fOR DAMAG!;s RESUL llN(;
PROM use OP OR IU!UANCE UPON nus INR>RMA llON.
Eaw:pzJ Tcltpltw N11mbrr: Jl4-91l•5000
sr:cnQN J Rwtb11J P.11
Slawtlry:
Slablc ...tcr Oldlaary tondUm ol mc •IIMI 11oraac.
Hua-. D ,...,._ rro.t.cta:
C.lllboll dioddll Md cubol-ew i-1. .. , torm .tac■ h«lcd lo
h +, 14#ic,a.
U.-.U ....,wrllalla:
'IMl ee+aewc doa u potywrtu.
1-pellblUlln:
StlOIII oadala. lihcr 1■tta. ?wop■ haJMka, alkali mc:1ala,
eel.al llpdridca. bydnzioc, ud .. a, other 1.ubs.lanca.
SECQON 1 In. /SP411 DtM9111 le{10R1ll91
Vutil■lc ■,a ol lcat M ,pill. lt.cmowc aU aourca ol
ipidoa. Clcaa-tlp pcmonncl n:qwirc pro1cc1M cloebin1 and
rapimlory pro1cclioa ,..., wpon. C.oa1aio and recowcr hqYid
wlllCa ~ C.oltect • llazardoul wute aftd alomil:c in •
a.kllblc RCRA lppVWltd C'OllltMl&lioCI cbambcr, or abM>rt, with
w,aak: llilc, dry uad, ur1la or llmilar -■aerial for dilpm.al
• ---11 a llCJIA ~ lacili'Y. Reponable o.-Jty (OA)(CWA/Cl!RCl.A~ SIDI Ila.--b)'I lkobol.
P.wrc rompli■eee witll local, IUle •Ad tcdc:nl rc:pla1iofts.
AD
E!IJcctiw: Dale: 04--0<Hl9 Supencdcs 07-13-87 St:cnoN 5 Unllb U•ur:4 la(-■Uog A. exrosURI! , HEALm emcrs l■uladaa: ~---•otlle •---a11bc oppcr ,aplntarJ .-. P I I 1 awa1ratkw-,a.Ndrc I _,,to 17"1L .......... C..cawpatrtdl.h+ t kM.tU 1 -•1n1ew. _,. Sldac.t■cti c--ir--.n--.or....,._to...,._ ................ E:,w c.■llld: ea.-.,.-s,-a...-, .. -,._.,, ...... --0,-lc~ n.--•IL..f<w I ::ca-,-..-w.c,...i .. ,-.. cw: .,...,..., ____ , ..... , .. _ Aan"rallo■ ., .......... C..lio■o: ,_...,.. with pre e±t:,. .. •-n or.,. ..--or lrapolnd :i.., or W.., ,_-, be --plible :o tlle elf-altlle-. -liiiil iili ililil liiii lilil Q, FJRSCA!P loulallo■: -to,,... air. If oot brea,....., f11wc anllldal . rapntlo■. lf_,,,. ___ .... ..,...c.u. .., IJM I I rt:-.• Ur al ,...._......_, SI 1 tJbfaMallwa .-a1_ .... _.._...,_ ... ,__ _, ... ...,.,,,...,_to _____ Call,.,... ~-ir...ppo111■1-.--.... --.... Sida Ire a _ _, ____ ........,w_. ............ """' -....---•-Uaia•ICLOat---•-...... orpcni<IL E,-111 w 1a-a1-,· II .,,._.,..wltkplealJ>al•r·r forat_U_ Callnpl; I•• C,JPXIQTY DATA (R11!CS. l!186) fwet,._u,,t,,dpol ; ••~Onln1U»> ._..,.... ____ ,.,ti..-REAGENT ALCOHOL v .. 111a11o■ s,-... , A IJ'IICm ol loca.l u,4/w ,CMraf uU1111 ii rcrommcndc:.d lo keep cm"°'" upo111ra bc'°9 lhit Airborne &po&urc Limiu. Local caha.a wni11U..k-. ■ pacrdy p«lcm:d bccaYIC ii tan con1rol tk e......-ol CM eoe!teleHI at hi aoun:c, pracn1in1 dilpcn6oa ol 61 lallo lM ..... M)ft. aru. l'k:alc 1c:fcr 10 llilc AOIJIH -t, .,_riot V·adlallca. A Muual cl lluonuncnd<d ,._. __ -odldoa,--.... el •-,kzllNL (NIOSH A,,......t} If Ille Tl.Vii -•fol,..,...,__. cartridp pntor-bo-■, le ...... "P 10 100 -lbe Tl.VO<,.., et I -•---...-bJ 11,, ...-.-,p11e,, ·· · 11-. Allea u :,.e-,pllodaur.nfaccplca I 51 .............. .., ... ..._ ...... ,...,, w_ ,.._ .... ,,,__ _. ._ '4:odJ ccwrlat dodll.l&, EJia I\ 1 k-et U..-icei-,._... ec.i.c, :c-....,_,. DOI be_,. _....__tllle_ _eye_,_..., end .,.i.t __ ,. _ uea. SKlJON 7 ltMen 1H Inst:! l1(oQMClop --..._ __ (I .. ----): Onl ... I.DJO: S6ll ,_,.,,. ..,.,. ..... -••cool, dr, ... t 5 IDcadoa...., fn::a W/ a,m wbc:rc lbc nrc haurd -.1'1-fw h; .. ·-Onl nt U»> _ ..,,.._ 5'Ja nbMI LIMO: I>~ lntnhr!oe fM LOO: l6flll ..-JIH. M-•--St'.CIJON t Q ,rhsl c-crp1 Mnam ..,.__ ,,, . -OSHA,__ B ; ro Ualt (PBL): 1000-(IWA) ._..,._ «JO-(IWA). SCIO-(Sll!l.) for.......,. -DI-(IWA).150-(Sll!l.)-for-=tllJI--AOIJIHn.-lak V-(11.V): -IIJOO-(IWA)betllJl-«JO-(IWA).,00-(Sll!l.) for.......,._ JOO-(IWA).150-(Sll!l.)-b _...,. --lilillil • ;;;a 11111 -,be-~•---II pn:f<rml. S.panlC fna ooidldae-C--n lboulcl be boeded 1DCI pou .... d for-to __ .,...._ Slon,e """ -,,... .,,...,. be,..,_,._ u. ...-.1ype 1ooll lftd equipmeol. ............................................................ REAGI! ==-== == --11!!!!1 1111111
- - ----- --- ---l!!!!l!!I I!!!!!! l!!!!!!!I I!!!!!!!!!!
MAL LI NC KR O DT M•llintbodl pnwida lhc lnf'oraalioa roat.aiocd IM:rcln la ,ood f•itlll
but makca 1k) rcp,ac•t•doo M 10 ill coep,cllcUMDCSI or KAIWJ. lndivid ........... , lhc lnfonaa1ion .... Cftm<c , ... ,, indcpcndcnl
j\tClpftcnl UI ck1crminia1 W app,oprialcaca for I partiaalar purpoac:.
MBROIANTABILin', fTlNESS PORA PARTICUl..AR
PURPOSE wrm RESPECT TO TIie INPORMATION St,f
PORTII HEREIN OR TO TIii! PRODUCT TO WIIIOI TIIP,
INPORMATION IU!PeRS. ACCORDINGLY, MALLlNCKROllT
WJU NOT ee RESPONSIBLE FOR DAMAGES RF..SUl.llN(j
PROM use OP OR RELIANCE UFON TIIIS INl'ORMAllON Material Safety Data Sheet MALLINCKRor,r MAJU!SNO lll!PRESlll'ITATioNS, oR WARRANTll!S, EllllBR l!XPIU!SS OR IMPLIED, OP
M1llincbodl, Inc. Science Producu Division, P.O. Dor M Paris, KY o40J61 t:aor1ooq Teloi-c-N•mber. Jl4-98J-SOOO
This Addendum Must Not Be
Detached from the MSDS
ldcnlifig SARA Jll Wbtt!Pcd!l
ARY copyto1 or rediMcibulion o( lhe MSDS
fflUK ipdude I copy O[ lhil pddfpdyffl
(Chem.Key: REAGE)
Addendum to Material Safety Data Sheet
REGULATORY STATIJS
Haurd Categorica for SARA
Section lll/3U Reporting
Acute Cbrooic Fire Prcuurc Rcactiw:
X X X
Product or Componenu
or Product:
SARA f!HS Sea. 302 SARA Soalon JU Chanlcab Cf!RCU Sec.lOJ RCRA
RO (RJa.) 11'0 (Ibo.) N.-LIii Cliankal Calegory RO (b.) Sec. 261.JJ
REAGENT ALCOHOL
E1hyl alcohol (64-17-S) -
Methyl alcohol (67-S<>-l) S"
bopropyl alcobol (67-63--0) S"
No
No
No
No
No
No
No
.Ya
Ya
SARA Segjon 302 EHS RO: Reponable Ouan1i1y or l!xtremely Hourdou1 Sub111na:, li11ed 11 40 CFR JSS.
No
No
No
No
SOOD
No
SARA Segjon 302 EHS J10: Thruhold Plannin& Quan1ity or l!xlremely Hazardou1 Sub1111n<1<. An .. erillt (•) following a Thruhold Plannin& Quan1i1y
aignifie.a 1ha1 if 1he maccri■I is a 10lld and h■a ■·panide Kio equal 10 or laracr 1han 100 mkromc1en. lhe Threahold Plannin& Ouan1iry • 10,000 LBS.
SARA Segjog Jll Chomjql•' To.ic Sub11ana:a aubjea 10 aMual rcleue reponing rcquircmen11 lilled 11 40 CFR Jn.65.
CERCIA Sec. 103: Comprehensive l!nviromen1al Raponac, Compenu1ion and Liability ACI (Supcrfund). Rcleuea 10 air, land or waler or lhete haurdous
wbscanccs which a:cecd lhc Reportable Ouan1iry (RO) mulf be reponed 10 1he National Response Cenler, (80()....424-8802); Li.Med al «» CFR .102 . .C
~: Resource Con1erva1ion and Rcclamacion Ad. Commercial chcmkal product wallet dcsignaccd u awle hazards and 10lllc under 40 CFR 261JJ
IH~ Af':1:1'.J'I' A I ('f\11()1
No
UIS4
No
D
ti
m
•
I
I
I
I
I
I
I
I
I
I
I
I
I
Te1e0none. ('~'l 273•3850
TWX: (910) 262·3052 Alar,cl'ler-. \A\
Telex: 26 S-4J AIOricn Ml
F-"X: 1"'1 2734979
ATTN: SAFETY OIREC TOR dLACK AND VElTC~
DATE: 07/12/98 CUST # 9Zl93Z P.O. # Llll44
1500 ~EAOOII LAl(E·'PK\IY KANSAS CITY MO 64114 HOLD FQR PICK UP 7/lZ IIIELAND
SAFETY D A T _A S H E E T
----------------IDENTIFICATION --------------
?ROJUCT:: 27063-6
CAS :: 67-66-3
NAME: CHlOROFORM, 99.9+1, HPLC GRADE
C:tk .. De. e Fe e(Y\ TOXICITY HAZARDS-----------------
RTECS ~ FS9100000 CrlLOROFORM IRR IT AT I ON OAT A AIHAAP 85JCAE AIHAAP 85JCAE
23,95,62 -,89,86 37,697,76 -,89,86
S~N-~BT 10 ~G/24H OPEN MLO SKN-R8T 500 MG/2~ ~LO EYE-~8T l't8 MG EYE-RAT 20 HG/Z'tH MOO TOXICITY OAT>. ORL-HMN LDLO:l'tO HG/KG IHL-HMN LCL0:25000 PPH/5H UNR-HAN LOL0:5't6 MG/KG J~L-RAT LOS0:908 MG/KG IHL-RAT LC50:'t7702 UG/M3/IH l?R-RAT LD50:39't MG/KG ORL-MUS LOS0:36 MG/KG SCU-MUS LOSQ:70~ HG/KG IPR-DOG LD50:1000 HG/KG ORL-GPG LOSO:szo HG/KG
32 ZWAA TABIA2 85DCAI JP FC02 ENVRAL ENVRAL ATSUOG JPETAB TXAPA9 GISAAA
B,275,74 3,231,33 2,73, 70
17,205,82 ltO,'tll,96 10,411,86 2,371,79 123,221,58
1Dlll9,67 18 3l,10,a3
R:VIE"S, STANDARDS, ANO REGULATIONS
-
AC~IH TLV-SUSPECTEO C4RCINOGEN BSINAB 5,130,86 ACGIH TLV-TWA 10 PPM 85INA8 5,130,86 MSHA STANOARO:AIR-CL 50 PPH (210 MG/M3) OTLWS* 3,14,73 OSHA STANOARO-AIR:CL 50 PPM FEREAC 39,23510,7't NIJSH REL TO Ci-iLOROFORH-AIR:CL 2 PPM/60/111 HHWR•• 31(1S),11S,85 NIOSH REL TO WASTE ANESTHETIC GASES ANO VAPORS-AIR:CL 2 PPM/lH MM~R•* 34(1S)t31S,85 E?A GENETOX PROGRAM 1986, POSITIVE: CARCINOGENICITY-MOUSE/RAT; S CEREVISIAE GENE CONVERSION EPA GENETOX PROGRAM 1986, POSITIVE: S CEREVISIAE-HOMOZYGOSIS; S CEREVISIAE-REVERSION EPA GENETOX PROGRAM 1986, NEGATIVE: CELL TRANSFORflll.-SA7/SHEI V79 CELL
CULTURE-GENE MUTATION E?A GENETOX PROGRAM 1986, INCONCLUSIVE: MAMMALIAN HICRONUCLEUS; SPERM MORPHOLOGY-MOUSE E~A TSCA CHEMICAL INVENTORY, 1986 E~A TSCA SECTION 8(E) STATUS REPORT 8EHQ-0979-031018EHQ-01S0-0324 E?A TSCA TEST SUBMISSION (TSCATS) DATA BASE, JUNE 1987 NIOSH CURRENT INTELLIGENCE BULLETIN 9, 1976 NIOSM ANALYTICAL METHOOS: SEE HYOllOCARBONS, HALOGENATED, 1003 NCI CARCINOGENESIS BIOASSAY (GAVAGE)ICLEAR EVIDENCE:MOUSE,RAT NCITR• NCI-CG-TR,1976 NTP FOURTH ANNUAL REPORT ON C4RCINOGENS, 198~ HEETS CRITERIA FOR PROPOSED OSHA MEDICAL RECORDS RULE FEREAC 't7,301t20,
az
ONLY SELECTED REGISTRY OF TOXIC EFFECTS OF CHEMICAL SU8ST4NCES (RTECS)
DATA IS PRESENTED HERE. SEE ACTUAL ENTRY IN RTECS FOR COMPLETE INFORMAT
-----•••-c_ ... ,, .. -~l11L --........ a-c._i.-. -0 ~&C.1!,Q .. , .• ..v·w •••• .. ,c:-,.._
·-1Clr\~l"II . ___ .. _,
•u 101\JQIIJII
17•--T-'"4111111..--. ·-·•=,.,. . _ _,........,.
OA..1 <lll!"l•1a
._ .... ----,,.0111 ... -.-..... ,o.___ ~.a--.. .., a--.._ T.,. T-!CPI~ II"\ •-,COi,._.,. T-••l'Ta-Q ,..._. !CIiio 1M-0117 h.l !OU* :rm
.. __
,_~., .. ,_,._.._o ,...._~., ...
Teieonone: 1•1'1 273-3850 I T"-NX. (910) 262·3052 .A.ldr1cnem Ml
Telex:: 26 843 Aldrich Mt
FAX: (•1•1 273-.979 I
SAFi:TY D A T A PA _I --"------------
---------------HEALTH HAZARD DATA---------------u ACUTE i:FFEC TS MAY 3E FATAL IF INHALED• SWALLOWED, OR ABSORBED THROUGH SKIN. VAPOR OR MIST IS IRRITATING TO THE EYES, MUCOUS ME'4BRANES AND UPPER D Ri:SPIRATORY TKACT. CAUSES SKIN IRRITATION. EXPOSURE CAN CAUSE: NAUSEA, DIZZINESS AND HEADACHE MAY CAUSE NERVOUS SYSTEM DISTURBANCES. CHRONIC EFFECTS CARCINOGEN. DAMAGE TO THE LIVER DAMAGE TO THE KIDNEYS DAMAGE TO THE HEART E(PJSURE TO ANO/OR CONSUMPTION OF ALCOHOL MAY INCREASE TOXIC EFFECTS.
I
I
FIRST AIO IN CASE OF CONTACT. IM'1EOIATELY A..USH EYES OR SKIN WITH COPIOUS fl AMOUNTS OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATE~(I CLOTHING AND SHOES. CONTAMINATION OF THE EYES SHOULD BE TREATED BY IMMEDIATE ANO PROLJNjtJ IR1UGATION WITH COo'IOUS AMOUNTS OF WATER. I IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL RESPIRAT[ON. IF BREATH[NG rs DIFFICULT, GIVE OXYGEN. CALL A PHYSICIAN. ~ASH CONTAMINATED CLOTHING BEFORE REUSE.
--------------------PHYSICAL DATA
MELTING POINT: -b3 C BOILING POINT: 60.5 C TO 61.5 C SPEClFIC GRAVITY: 1.492 VAPOR DENSITY: 4.1 '/A~OR PRESSUR:: lbO.O MM • 20 C
----------------
-----------FIRE ANO EXPLOSION HAZARD DATA---------
FLASH POINT: NONE EXTINGUISHING MEO(A NONCOM BU ST IBLE• USE EXTINGUISHING MEDIA APPROPRIATE TO SURROUNDING FIRE CONDITIONS. SPECIAL FIRE FIGHTING PROCEDURES . WEAR SELF-CuNTAINEO BREATHING APPARATUS ANO PROTECTIVE CLOTHING TO ,'REVENT CONTACT WITH SKIN ANO EYES. UNUSUAL FIRE AND ~XPLOSION HAZARDS tMlTS TOXIC FUMES UNDER FIRE CONDITIONS.
----------------REACTIVITY DATA---------------
INCOMPATI3ILITIES BASES ALUMINUM SENSITIVE TO LIGHT HAZARDOUS COMaUSTION QR. DECOKPOSITION PRODUCTS TOXIC FUMES OF: HYO~OGEN CHLO~IOE GAS PnOSGENE GAS CARdON HO~OXIDE, C4RSON DIOXIDE
-... ,,c,,~'"""" ~---uo11 .,,a.._
•-1111\>&al'III •-1nm-, ... ,o,,~11•1
·-... ~, .. , 11•--t-••1-s--,. t-••1:zr~,. f-_,....,,_,
••• ••11,,1a
------0-.-CIL•
._.._ __ "'-°"" _____ __
,o--...-~.o... ......
~••• T-.10'Ul'91Z,'!1
•-•C01JM,,,o1M '-••TTS-Q ••• u:i,1111-(11'1 ,.._. _,,,..~
---= a.-&CI •O
., __
T-1~11'· ,._,,,__D ..... _,_.., ..
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"\ A T E R I I L SAFETY D A T A
Te1epr-,o"'"e :•'.•1 271-3850
TiNX {9101 262-3052 Alor,cne-•.-l1
Telex. 26 SA3 AIOr1cn Ml
r"AX. (•Ul 273-4979
S H E E T PAGE:
---------------SPILL OR LEAK PROCEDURES--------------
5TEPS TJ BE TAKE~ IF MATERIAL IS ~ELEASEO OR SPILLED EVACUATE l~EA.
WtA~ SEL~-co~TAINED 9REATHING APPARATUS, RUBBER BOOTS ANO HEAVY RUdi\E~ GLOVES. A3SOR3 ON SAND OR VERMICULITE AND PLACE IN CLOSED CONTAINERS FOR DISPOSAL.
V~NTILITE AREA AND ~ASH SPILL SITE AFTER MATERIAL PICKUP IS COMPLETE. WASTE DISPOSAL METHOD THE "IATERIAL SHOULD BE IGNITED IN THE PRESENCE OF SODIUM CARBONATE AND SLAKED LIME (CALCIUM HYDROXIDE). THE SUBSTANCE SHOULD BE MIXED ~ITH VERMICULITE ANO THEN WITH THE ORY CAUSTICS, ~RAPPED [N PAPER AND BURNED IN A CHEMICAL INCINEftATOR EOU[PPEO WITH AN AFTERBURNER A.-.D SC RU BB ER•
D3SE 0 VE ALL FEDERAL, STATE , LOCAL LAWS ■
---PRECAUTIONS TO BE TAKEN IN HANDLING AND STORA~E ----
~EAR APPROPRIATE NICSH/"ISHA-APPROVEO RESPIRATOR, CHEMICAL-RESISTANT GLOVES, SAFETY GOGGLES, OTHER PROTECTIVE CLOTHING. USE ONLY IN A CHEMICAL FUME HOOD. SAFETY SHOWER AND ~YE 9ATH. DO NOT BREATHE VA?OR ■ AfOIO ALL CONTACT ■ DD NOT GET IN :YES, ON SKIN, ON CLOTHIN'... ~ASH THOROUGHLY AFTER HANDLING.
URCINOGEN ■ Hl,;HLY TOXIC ■
IR~! TANT• KEEP T[GHTLY CLJSEO. PROTECT FROM L[GHT. STORE IN A COOL QR.Y PLACE.
--------ADDITIONAL PRECAUTIONS ANO COMMENTS---------
ADDITIONAL !~FORMATION ST Ad IL IZ ED iol!Tri APPROX. O. 75i ETHANOL
THi: ABO\IE INFORl'1ATION IS BELIEVED TO BE CORRECT BUT DOES NOT PURPORT TO oE ALL INCLUSIVE ANO SHALL BE USED ONLY AS A GUIDE. ALDRICH SHALL ~OT BE HELD LIABLE FOR ANY DAMAGE RESULTING FROM HANDLING OR FROM CONTACT WITH THE ABO\IE PRODUCT. SEE REVERSE SIDE OF INVOICE OR PACKING SLI? FO~ ADDITIONAL TERMS ANO CONDITIONS OF SALE•
-·------.,.,Cf'C-.,v·1• ~•··· ---o-..c.~-. ~a..,,,c. •Q .. __ ,_,.,, Tl•--'-._.._.,.__ n..o...__ -------1-•IDC.._ .... ,...._ ·o-.--a..-..,-0.-,..""'-,_,,11:a1., .. ·--,ar1-r,o ._,..,,,,..... i:i-.-.c ... , ... ,_ !07•1'911!'11 ,_,._...._o ·-· uxv • ..._.
, __ ,.._,
,_,=1a.-o,11 ,_.,l'J:II_Q .... 1'13alll' .. •u ,ar,1oa,1 .... , .. ,,,,111 •u l'mllllo4'111 , .... I07•191 J1"'I
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MATERIAL SAFETt' DATA SHEci
~SOS 0 qE 0 •RED s•· Environmental Health Deot. Construction Products Cl,.
~-~-Grace & Ca.-C:nn. W. R. Grace & Co. _of Canada LtJ.
:2 hhlttemcre· ~,e. 294 Clements Rd. West
·:o;r.orid:;e. MA c,:'.~,) Ajax. Ontario, LIS 3C6
re:ephone Number for Information and Emergency Response
:~ 1-•S.0 : (5'7) ,·:-!<lQO !n Canada: [phone]
MSDS Humber: Z-01281 OOOUSA Cancels MSDS ~ Z-01201 Date: 05/08/1991
SECTION 1 -PRODUCT IDENTIFICATION
Trade Hames and Synonyms:
<SEE SECTION 12 FOR ADDITIONAL
PRODUCT IDENTIFICATION)
~crmula:
i"HDUSTRIAL VERMia.JLITE (LIBBY>·"
E,panded Vermiculite <Libby Montana
Source) Magnesium-Alumniosilic,te
Mineral
Insulating, Absorbing and Cushioning
Material
< Mg , Ca , K, Fe I l ) 3 (Si , A 1 , Fe 11 I ) 4
D1o<OH)z.H20
US# <Chemical •bstract Service): 01318-00-9
Transportation Hµ1rd CliSJificatign
PC..OPE~ SH!P?!~G: Not Applicable
~~z~RO CLASS: N6nhazardous
iO ►'HlF't(..HIQN a: Not Applicable
L•SEL' ;I REOUliED: Not Applicable
Surface Freight Classification:
NPCA-HMIS Hazard Index:
TOG CLASS: Nonhazardous
Vermiculite, Other Than Crude
o Health: 1 •
o Flarrmablllty: 0
o Reactivity: 0
o Persona 1 Protect I on: E
<See Section VIII)
SECTION 2 -HAZARDQJS INGREDIENTS/IDEHTITY IHFORMATION
INGREDIENT
<Chemical Name, 'I.
TOXICITY DATA LDso, LCso etc.
CAS#, & Common Namel By Ht, <See Section IX for Exposure Limits)
Resplrable Crystall1ne
Silica <Quartz>
CAS# 14808-60-7
Typ1cally
< 1 'X,
No Data Available
0397f
MATERIAL SAFETY DATA SHEET Page 2 of a
SECTION 3 -PHYSICAL DATA/CHEMICAL CHARACTERISTICS
3,: ; · '. r •"J o ') i n : . ~•ct Applicable Specific Gravity (HZO s I) Not
Applicable
~!::· •·es;ur• 1~m Hg. l Same as Water t Volatiles I0-40t as Water
Evaporation Rate Same as Water
S-:'·s::'li:·, in Water: Negligible
5:c·•. Oecsit·, 1#/cu. ftl: 5-10
<Butyl Acetate= ll
ll.li
•::eararce and Odor: Brown or gray free flowing aggregate,
slightly moist to touch, slight earthy
odor.
Cid9r Threshold:
N0 n e Es tab 1 i shed
SECTION 4 -FIRE AND EXPLOSION HAZARD DATA
Flash Point: None
Method Used: Not Applicable
N.F.P.A. Rating: Not Applicable
Extinguishing Media
Not Applicable
Special Fire Fighting Procedures
None
Unusual Fire and Explosion Hazards
None
SECTION 5 -REACTIVITY DATA
Flammable
Lil NA
Stable under normal cqndltjons <yes or nE YES
Limits:
!.J.E.1 NA
Not Applicable
Conditions or Materials to avoid <which may react or cause lnstabjlltyl:
Avoid contact with water reactive materials.
Hazardous Oecomgosltlon or Byproducts:
None Known
Hazardous Polymerlzatron:
I.I 11 not occur
Conditions to Avoid:
None Known
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MATERIAL SAFETl' DATA SHEET
SECT!OH 6 -HEALTH HAZARD DATA~ TOXICOLOCICAL PROPERTIES
::oclude al 1 known acute and chronic effects. signs. and symptoms of e•~cs~·e
:;ie,Jical conditions genera11y aggravated by exposure)
G;~~es ~f E~c-sure:
I~hala.ti~n:
i h i s Dr od u c t has been treated w i th w a t er to con tr o 1 and mi n \ mi : e
release cf ,irborne particulates. Dust that may be released in
handling may cause symptoms typical of nuisance dusts, including
cJughing, sneezing, and minor upper respiratory irritation. Dust
,cay also contain Respirable Crystalline Silica. See information be-
!cw regarding carcinogenicity _and long term health effects.
C.k, ~ ., and Eve:
Direct eye contact may cause miner ph~sical or mechanical irritation.
Skin contact not expected to cause any harmful effects.
!:igestiqn:
Not considered harmful by ingestion.
Carcinogenicity According to NTP, !ARC and OSHA:
Operations involving the use of vermiculite, may create atmospheres/
airborne dust containing Respirable Crystalline Silica. Resplrable
Crystalline Silica has been classified as a probable human carcinogen
by !ARC a unit of the Horld Health Organization. NTP has Included
Silica Crystalline <respirablel as a substance reasonably anticipated
to be a carcinogen based on sufficient animal and limited human data.
Long-term inhalation of Resplrable Crystalline Silica may cause lung
disease including silicosis and lung cancer. See exposure limits
specified in Section 9 of this MSDS.
SECTION 7 -EMERGENCY AND FIRST AID PROCEDURES
In case of EYE contact, do not rub eyes. Flush ~Ith plenty of ~ater
while holding eyelids apart. If Irritation, blinking or tearing occur
and persist, consult a physician.
Adverse health effects are not expected If SHALLOHEO. Consult a
physician If symptoms develop.
If INHALED, get fresh air. If symptoms persist, consult a physician.
:-:'1231 MATERIAL SAFETY DATA SHEET Page~ of 8
SECTION 8 -PREVENTIVE a CONTROL MEASURES
~ar~i~; S~a~e~e~:s:
C•LlT:ON' M~Y CAUSE SLIGHT iRRITA7iON.
CJ,itains T:tal and Respirable Crystalline Silica (Quartz) CASI/
14308-50-7 and Vermiculite CASI/ 1318-00-9 premoistened with water
to control dust.
Eye contact may cause minor physical irritation.
Inhalation of vermiculite dust may cause slight upper respiratory
i rri tat ion with coughing and sneezing.
Long-term inhalation of Respirable Crystal line Silica (Quartz> can
cause cancer, si I icosis and other lung disease hazard.
Pre(auti~narv Measures:
Avoid contact with eyes.
Avoid creating dust.
Eouip hoopers with dust covers where ao □I icable.
Provide adequate ventilation and respiratory orotection If
necessary.
Do not use in moisture sensitive applications or with
water-reactive chemicals.
Respiratory Protection:
A NIOSH Type TC-21C-XXX dust respirator is d~slrable If dust Is
created In handling. However, dust levels are expected to be minimal
as long as product remains moist.
Ven ti lHion:
Local Exhaust: Not generally required, but should be used where
available.
Meehan I cal: Not generally required, but should be used where
available.
S □ecial: None
Other: None
Skin Protection:
Not generally required.
Eve Protection:
Goggles recon'll1ended.
Other Protective Clothing or Equipment:
Normal work clothes.
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Z-0I281 MATERIAL SAFETY DATA SHEET Page 5 of 3
SECTION 8 -PREVENTIVE & CONTROL MEASURES CONTINUED
Hork/Hvgienic Practice1:
'lermicul i te:
Observe precautions noted above.
ls processed from ore mined at the llbby, Montana mining
operation. where H. R. Grace 1, Co. maintal_ns high qua I ity
standards. The natural geologic formation at Libby contains
other mineral components. in addition to vermiculite. One of
these is asbestiform tremolite (defined as asbestos by OSHAl.
Grace's mining and milling process significantly reduces the
tremol ite content before the vermicul lte concentrate is
shipped to the expanding plants. However, It may be possible
to detect tremol ite in the form of respirable fiber in this
product at levels of .0057. <50 parts per million> dry weight
or less. ·
On June 20, 1986, the United States Occupational Safety and
Health Administration <OSHA) established new, more stringent,
regulations regarding occupational exposure to airborne
asbestos fibers Including tremol lte (29 CFR 1910.1001 l.
OSHA regulations Include a permissible exposure level <PEU of
O.Z fibers/cc <8 hr. time weighted average), a 30 minute
excursion limit of 1 fiber/cc <effective Oct. 14, 1988) and an
action level of 0.1 fibers/cc (8 hr. time weighted average>.
In accordance with paragraph (j) (4) (I) of the regulation,
this product has been modified by the addition of water as a
binder to assure that "during any reasonable foreseeable use.
handl Ing, storage, disposal. processing, or transportation. no
airborne concentration of fibers ... In excess of the action
level and/or excursion limit will be released."
Grace has collected, and Is continuing to collect, objective
data In a variety of end use applications which, to date,
demonstrates that the addition of water to vermiculite can
· c·ontrol the airborne fiber concentrations below the action
~ \"evel and/or excursion limit. OSHA will allow employers to
~-tile such objective data as provided In paragraph (dl <2> < I 11 l
to show that their employees will not be exposed above the
action level and/or excursion limit as a result of using this
prDduct. Subsequent provisions of the regulation do not apply
where It has been determined that exposures are below these
levels as Indicated by the objective data collected by Grace.
Further Information regarding this objective data Is available
upon request.
~-JI 281 MATERIAL SAFETY DATA SHEET Page 6 of 8
Res2irab1e Section 2 of this MSOS indicates that this product can contain
·:r:ntalline 0.espirable Crystalline Silica (Quartz) at <11. by weight.
Siiic,C<~•Jart;:): Crystalline Silica <Quartz> is a naturally occurring mineral
that is commonly contained in materials that are mined from
,he earth's surface such as sand, 1 imestone, clay and gypsum.
Total Crystalline Silica <Quartz) Is comprised of respirable
and nonrespirable size particles. The health hazards
associated with quartz are tied to the respirable size
particles. We believe that the quartz pres~nt In vermiculite
is predominately nonrespirable due to particle size and water
addition. However, handling and processing may create
respirable particles. Therefore, potential exposures must be
considered.
... .:....
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Z-01281 1-!ATERIAL SAFETY DATA SHEET
SEC~ION 9 -HAZARQ(XJS INGREDIENTS EXPOSURE LIMITS -U.S. Only
~JU[SAIJ(~ ;~~Ti:JLAIES
·:.:. s .::r .'J/:..
ou~~r: tC~Ys~. s:L::!1
c~sa 1~302-60-7
~~5;:~:.3L~ JUST·
: ! s.= .•u
ror:..:.. ousi•
·::. $.:' ~◄A
PEL:
Total: IS mg/,,., 3
~espi rable: Smg/~
PE~/T'oiA O. lmg/mJ
as ,.esp; rable dust
E--posure Limits
A r. H
_fLV:
Total: 10 mg/m 3
TLV/T"SA O. lmg/,,,3
as respi rable dust
TLV/T~A: 10 ~g/,,,3
SECTION 10 -SPILL & DISPOSAL INFORMATION -U.S. Only
Page 7 0f a
None Estab1ished
NiOIH IOmg/,,,3
10 hr. T\.iA as Sil;,:a
None Establ i pe,::
Observing the above precautions, sweep up or shovel spilled material
and place in suitable containers for recycle or disposal. Dampen
with water spray or use other methods to clean spill which avoid
creating dust.
DI scard empty packaging promptly. Avoid excessive handl Ing of empty
packaging, which may result In unnecessary release of airborne
particulates.
According to EPl,_(40 CFR 261.3) waste of this product Is not defined
as hazardous . .::eotspose of all waste In accordance with federal, state
and local reguiaflons.
i:-0 I 281 MATERIAL SAFETY DATA SHEET
SECTION 11 -GOVERNMENT REPORTING I HFORMA TION -U. S. On 1 y
5,,.A Title III Reporting Informaticn
T!er I i II Hazard Categories: DELAYED-CHRONIC
IMMEDIATE-ACUTE
Contains Extremelv Hazardous-SARA Ill Section 302 Ingredient:
Comments:
Contains To,ic Chemical Release-SAR.A III Section 313 Ingredient:
Comments:
C:her Government Reporting Requirements:
Page a of a
NO
NO
Caiifor;ii~ Prop,:sition f.S: 0 roduct sold in the state of California is
labeled to comply with Propo11~ion 65.
Non-Hazardous Ingredient Disclosure:
~ater
SECTION 12 -PRODUCT IDENTIFICATION/TRADENAME ADDENDUM
The information contained \n this Material Safety Data Sheet \s applicable to
the following products:
None
"THE DATA INCLUDED HEREIN ARE PRESENTED ACCORDING TOH. R. GRACE & CO.-CONN's
PRACTICES CURRENT AT THE TIME OF PREPARATION HEREOF, ARE MADE AVAILABLE SOLELY FOR
THE CONSIDERATION, INVESTIGAT!ON AND VERIFICATION OF THE ORIGINAL RECIPIENTS HEREOF
AND DO NOT CONSTITUTE A REPRESENTATION OR HARRANTY FOil HHICH GRACE ASSU 1-IES LEGAL
RESPONSIBILITY. Il':" IS THE RESPONSIBILITY OF A RECIPIENT OF THIS DATA TO REHA IN
CURRENTLY INFORMED.ON CHEMICAL HAZARD INFORMATION, TO DESIGN AHO UPDATE ITS OHN
PROGRAM AND TO W>U!l,.Y HITH ALL NATIONAL, FEDERAL, STATE ANO LOCAL LAHS AND
REGULATIONS APPLICABLE TO SAFETY, OCCUPATIONAL HEALTH, RIGHT-TO-KNOH AND
ENVIRONMENTAL PROTECTION."
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-----Ccle-Pari71er Instrument Company·------------
-...:=-=.:--==· =:-' 7· _;:. ~-:::;.: -=~ :::~:
B & V WASTE SCIENCE TECHNOLOGY
FRANK SCHUSTER
6601 COLLEGE BLVD
OVERLAND PARK KS -66211
Your PO#: WSTP63526
Our RefO: 885731
Dear Customer,
06/30/92
Enclosed you will find the Material Safety Data Sheet(s) for
the Cole-Parmer product(s) which you ordered or requested.
Please retain this documentation in your permanent records in
accordance with OSHA's Hazard Communication Standard as defined
in 29 CFR 1910.1200.
Please note that Cole-Parmer does not in any way represent
itself as an expert in the chemical(s) described in the MSDS(s)
accompanying this letter. Cole-Parmer cannot assume any
liability for inaccurate or incomplete information contained in
the MSDS. If you have any questions or concerns related to the
safe handling of the product ( s), please contact .the
manufacturer(s) directly at the number found in Section I·
of the MSDS.
Thank you for your continued interest in Cole-Parmer Instrument
Company.
Sincerely yours,
COLE-PARMER INSTRtJMENT COMPANY
..
Regulatory Compliance Department
MSDS ID# MSDYSI.02 C-P ITEM NO: 01486-20 I
YSI Incorporated
1725 Brannum Lane, Box 279 I Yellow Springs, OH 45387 513 767-7241 · 800 343-4357 • Fax [phone] • Telex 205437
MATERIAL SAFETY DATA SHEET
Product: YSI 3140 Platinizing Solution
Components
Chloroplatinic acid Lead acetate
Balance -Water
CAS Number
16941121
301042
%
<5,0
<O. l
The hazards associated
constituent chemicals. materials are attached.
with this product are those related to the Material Safety Data Sheets for these
*****Multiple Component Spill or Leak Procedures*****
Steps to take if material is released or spilled
Wear appropriate protective equipment. Wipe up the spill with absorbent material. Wash the spill area.
Waste Disposal
Dispose of in accordance with local, state and federal regulations.
YSI, Inc, October 30, 1990
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MSDS IDU MSDYSI.02 C-P ITEM NO: 01486-20
1 of 2
********* MATERIAL SAFETY DATA SHEET*********
IDENTITY: CHLOROPLATINIC ACID
CAS NUMBER: 16941-12-1
PRODUCT U: 32-8600-00
TRADENA.MES/SYNONYMS: Chloroplatinic (IV) acid; hexachloroplatinic
acid; platinic chloride; chloroplatinic acid, solid;
hexachloroplatinic (IV) acid; dihydrogen hexachloroplatinate;
dihydrogen hexachloroplatinate (4+); UN2507.
CHEMICAL FAMILY: Inorganic acid.
MOLECULAR FORMULA: Cl6-Pt.2H MOLECULAR WEIGHT: 409.81
CERCLA RATINGS (Scale 0-3): Health•3 Fire=O Reactivity~o Persistence=3
NFPA RATINGS (Scale 0-4): Health=3 Fire=O Reactivity=O
I.
II.
III.
GENERAL INFORMATION------------------------~--------------------
MANUFACTURER'S NA.ME: CHEMICAL DYNAMICS CORPORATION
ADDRESS: Hadley Industrial Plaza, Hadley Road, P.O. Box 395
South Plainfield, NJ 07080
PHONE: [phone] Telex: 833-447
DATE PREPARED: 12/13/84, revised 7/9/85
INGREDIENTS-----------------------------------------------------HAZARDOUS:
·Chloroplatinic acid.
Exposure limits:
100%
OSHA TWA:
ACGIH TWA:
2µg(Pt) /ml
2µg(Pt) /ml
PHYSICAL/CHEMICAL CHARACTERISTICS-------------------------------
SPECIFIC GRAVITY: 2.4
MELTING POINT: 140°F. (60°C)
SOLVENT SOLUBILITY: Alcohol, ether.
WATER SOLUBILITY: Soluble.
APPEARANCE/ODOR: Brownish-yellow, very deliquescent,
crystalline mass.
IV. FIRE AND EXPLOSION HAZARD DATA----------------------------------
FLASH POINT: Non-flammable.
EXTINGUISHING MEDIA: Dry chemical, carbon dioxide, water spray
or foam:; for larger fires use water spray, fog or alcohol
foam (_1984 Emergency Response Guidebook, DOT P 5800.3.)
SPECIAL FIRF;FIGHTING PROCEDURES: Firefighters should wear
self-cohtained breathing apparatus with a full facepiece
operated in pressure-demand or other positive iressure
mode. Move container from fire area if possib e. Do not
scatter spilled material with more water than needed for
fire control. Dike fire control water for later disposal
(1984 Emergency Response Guidebook, DOT P 5800.3.) Use
agents suitable for surrounding fire. Avoid breathing
hazardous vapors, keep upwind (Bureau of Explosives,
Emergency Handling of Hazardous Materials in Surface
Transporation, 1981.)
UNUSUAL FIRE & EXPLOSION HAZARDS: Negligible fire and explosion
hazard when exposed to heat or flame.
2
MSDS ID# MSDYSI.02 C-P ITEM NO: 01486-20
V. REACTIVITY DATA-------------------------------------------------
REACTIVITY: Stable under normal temperatures and pressures.
CONDITIONS TO AVOID: May burn but does not ignite readily.
Flammable, poisonous gases may accumulate in tanks and
hopper cars. May ignite combustibles (wood, paper, oil,
etc.)
INCOMPATIBILITY: Bromine trifluoride -violent reaction.
HAZARDOUS DECOMPOSITION OR BYPRODUCTS: May release toxic and
corrosive fumes of hydrogen chloride under thermal
decomposition.
HAZARDOUS POLYMERIZATION: not known to occur.
VI. HEALTH HAZARD DATA----------------------------------------------TOXICITY: ivn-rat LDSO: 49 mg/kg
ipr-mus LOSO: 29 mg/kg
Chloroplatinic acid is a pulmonary and skin sensitizer and
primary skin irritant.
CARCINOGENICITY: None •.
HEALTH EFFECTS AND FIRST AID:
Inhalation: Irritant/sensitizer
Acute exposure:· May cause severe respiratory tract
irritation. Pulmonary sensitization may occur in
previously exposed persons.
Chronic exposure: Repeated exposure to concentrations of
2-20 µg Pt/ml may cause nose and upper respiratory
tract irritation with sneezing, cough, rhinnorhea,
chest tightness; and asthmatic wheezing with dyspnea
and cyanosis, all of which may become progressively
worse with further exposure. Relative lymphocytosis
and eosinophilia may occur. . ·
First Aid: Remove from exposure area to fresh air
immediately. If breathing has stopped, give
artificial respiration. ·Maintain airway and blood
pressure and administer oxygen if available. Keep
affected person warm and at rest. Administration of
oxygen should be performed by qualified personnel.
Get medical attention immediately.
Skin contact: Irritant/sensitizer
.Acute ~osure: ·May cause irritation or, on prolonged
contact, b~rns; Sensitization may occur in previously
exposed persons. Animal studies indicate the dermal
LD~O 'of the hexahydrate to be less than 2000 mg/kg.
Chronic exposure:. Repeated or prolonged exposure may cause
allergic hypersensitivity, contact dermatitis with
pruritis and urticaria, and sometimes eczematous
eruptions. ·
First Aid: Remove contaminated clothing and shoes
immediately. Wash affected area with soap or mild
detergent and large amounts of water until no evidence
of chemical remains (at least 15-20 minutes!) In case
of chemical bums, cover area with sterile, dry
dressing. Bandage securely, but not too tightly. Get
medical attention immediately.
3
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MSDS ID# MSDYSI.02 C-P ITEM NO: 01486-ZO
VI.
VII.
HEALTH HAZARD DATA----------------------------------------------
HEALTH EFFECTS AND FIRST AID:
Eye contact: Corrosive
Acute exposure: Direct contact may cause irritation,
burning sensation, lacrimation, and conjuctival
hyperemia, sometimes associated with photophobia.
Prolonged contact may cause burns with irreversible
damage. ·
Chronic exposure: Repeated or prolonged exposure may cause
conjunctivitis.
First Aid: Wash eyes immediately with large amounts of
water, occasionally lifting upper and lower lids,
until no evidence of chemical remains ( at least 15-20
minutes.) In case of burns, apply sterile bandages
loosely without medication. Get medical attention
immediately.
Ingestion: Acute exposure: Ingestion may cause sore throat, painful
swallowing, abdonimal pain, vomiting, and diarrhea.
Animal studies indicate the oral LD50 of the
hexahydrate is greater than 500 mg/kg.
Chronic exposure: Not reported to occur in humans.
First Aid: Do not use gastric lavage or emesis. Dilute
the acid immediately by drinking large quantities of
water or milk. If vomiting persists, administer .
fluids repeatedly. Ingested acid must be diluted
approximately 100 times to render it harmless to
tissues. (Driesbach, Handbook of Poisoning, 11th
ed.) Get medical attention.
Antidote: No specific antidote. Treat symptomatically and
supportively. · · · ·
PRECAUTIONS FOR SAFE HANDLING AND USE---------------------------
SPILL RESPONSE: Do not touch spilled material. Stop leak if
you can do it without.risk. For small spills, take up with
sand or other absorbent material and place into containers
for later disposal. For small dry spills, with clean
shovel place material into clean, dry container and cover.
Move containers from spill area. For larger spills, dike
far ahead of spill for later disposal. Keep unnecessary
people ,way. Isolate hazard area and deny entry.
WASTE DISPOSAL: Dispose of in accordance with federal, state
and loc-_al regulations.
VIII.CONTROL MEASURES----------------------------------------------
RESPIRATOR: 0.1 mg/ml: High efficiency particulate respirator with a full
facepiece. Supplied air respirator with a full facepiece,
helmet, or hood. Self-contained breathing apparatus with a
full facepiece.
2 mg/ml: Powered air-purifying respirator with a high
efficiency filter and full facepiece.
4
MSDS ID# MSDYSI.02 C-P ITEM NO: 01486-20
I
I
VIII-~~~~~T~SURES ----------------------------------------------'I
4 mg/m3: Type C supplied-air respirator with a full facepiece
operated in a pressure-demand or other positive pressure 1 mode or with a full facepiece, helmet, or hood operated in
continuous-flow mode.
Escape: Any escape self-contained breathing apparatus.
VENTILATION: Provide local exhaust ventilation and/or. general
dilution ventilation to meet permissible exposure limits.
PROTECTIVE GLOVES: Employee must wear appropriate protective
gloves to prevent contact with this substance.
EYE PROTECTION: Employee must wear splash-proof or
dust-resistant safety goggles and a faceshield to prevent
contact with this substance.
CLO?HING: Employee must wear appropriate protective
(impervious) clothing and equipment to prevent repeated or
prolonged skin contact with.this substance.
OTHER PROTECTIVE EQUIPMENT: 'Where there is a possibility that
an employee's eyes may be exposed to this. substance, the
employer shall provide an eyewash fountain within the
immediate.work area for emergency use.
IX. TRANSPORTATION DATA--------------------------------------------DOT Hazard classification (49CFR172.101): ORM-B
DOT Labeling requirements (49CFR172.l01 & 4172,402): None.
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*************************************************
DISCLAIMER I
The above information has been transferred to this format by .1·
Cole-Parmer Instrument Company, from a Material Safety Data Sheet
supplied by the manufacturer identified in Section I. The contents
of this MSDS have been represented to Cole-Parmer by the manufacturer I
to be complete and accurate.
If you have any questions related to the material provided herein,
1 contact the manufacturer directly at the address and phone number
given in section I of the MSDS.
Cole-Parmer does ~ot, in any way, represent itself as an expert in I
the chemical desQ:ibed in this MSDS and assumes no liability for any
incomplete or inaccurate information contained herein.
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MSDS ID/I MSDYSI. 02 C-P ITEM NO: 01486-20
2 of 2
********* MATERIAL SAFETY DATA SHEET*********
PRODUCT NAME: LEAD ACETATE TRIHYDRATE
SYNONYM(S): Acetic acid lead(2+) salt
FORMULA: CZ H4 02.1/2 Pb
CAT NO(S·): 113 6084; 113 6092; 113 6118
CHEM. NO(S): 01975; 55275
KODAK'S INTERNAL HAZARD RATING CODES: R: 3
KODAK ACCESSION NUMBER: 026331
S:2 .F:l C: 0
I.
II.
III.
IV.
v.
GENERAL INFORMATION---------------------------------------------
MANUFACTURER'S NAME: EASTMAN KODAK COMPANY
ADDRESS: 343 State Street
Rochester, NY 14650
716-722-5151 emergency health, safety, & environmental info.
800-225-5352 for all other purposes (NY call 716-458-4014)
DATE PREPARED: 4/21/89
HAZARDOUS INGREDIENTS-------------------------------------------
Component % ACGIH TLV(R) CAS #
Lead acetate trihydrate ca 100 0.15 mg/m3 301-04-2
..
PHYSICAL/CHEMICAL CHARACTERISTICS-------------------------------
SPECIFIC GRAVITY: Not·available.
VAPOR PRESSURE: Negligible.
MELTING POINT: 75°C (167°F)
EVAPORATION RATE(n-butyl acetate• 1): Negligible,
WATER SOLUBILITY (BY WEIGHT): Not available.
VOLATILE FRACTION BY WEIGHT: Negligible.
APPEARANCE/ODOR: White crystalline solid,
FIRE AND EXPLOSION HAZARD DATA----------------------------------
FLASH POINT: Not applicable,
EXTINGUISHING MEDIA:, Water spray, dry chemical, carbon dioxide.
SPECIAL FIRE FIGHTING PROCEDURES: Wear self-contained breathing
apparatus·and protective clothing. ·
UNUSUAL FIRE & EXPLOSION HAZARDS:. This material in sufficient
quantity and reduced particle size is capable of creating a
dust explosion; . . . •
REACTIVITY DA;JA -------------------------------------------------STABILITY: -STABLE X UNSTABLE
INCOMPATIBILITY: Strong oxidizers, acids, bases.
HAZARDOUS DECOMPOSITION OR BYPRODUCTS: Combustion will produce
carbon d1oxide amd probably carbon monoxide.
HAZARDOUS POLYMERIZATION: MAY OCCUR WILL NOT OCCUR X
6
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MSDS ID/I MSDYSI.02 C-P ITEM NO: 01486-20 I
VI.
:~~~H.Af~T~~TAOSHA-h;;-;;~;bii;h;d-;-p;~i;;ibi;-E;~~;~;;----I
Limit of 50 µg/m 3 for lead as an 8-hour time weighted
average. The OSHA final rule on lead should be consulted
before working with this compound. The rule can be found
in the Federal Register, 29 CFR sec. 1910,1025, ACGIH has
established a TLV of 0,15 mg/m3 of lead as an 8-hour time weighted average.
EXPOSURE EFFECTS: Possible cancer hazard. May cause cancer
based on animal data. Can cause adverse reproductive
effects, such as birth defects, miscarriages, or .
infertility. Many lead compounds have been identified as
causing toxic effects in the blood-forming organs, kidneys,
and central nervous system.
Inhalation: Harmful if inhaled.
Skin: Causes irritation. Harmful
skin.
Eye: Causes irritation.
Ingestion: Harmful if swallowed.
if absorbed through the
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Carcinogenicity status: This chemical has been identified as a
carcinogen or potential carcinogen by:
National Toxicology Program (Annual Report on Carcinogens)
International Agency for Research on Cancer(IARC) Monographs D
California: WARNING: Lead acetate is known to the State
of California to cause cancer.
B
ff
Reproductive.toxicology status:
California:-WARNING: This product contains lead, known to
the State of California to cause birth defects or
other reproductive harm.
EMERGENCY & FIRST AID PROCEDURES:
Inhalation: Remove to fresh air. Treat symptomatically. If
symptoms are present get medical attention.
Skin contact: In case of contact, immediately flush skin with
plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. If
symptoms are present after washing, get medical
attention. Wash contaminated clothing before
reuse. Destroy or thoroughly clean contaminated
shoes.
Eye contactt Immediately flush eyes with plenty of water for
at least 15 minutes and get medical attention.
If swallowed induce vomiting immediately as Ingestion:
-directed by medical personnel. Never give
anything by mouth to an unconscious person. Call
a physician or poison control center immediately.
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MSDS ID# MSDYSI.02 C-P ITEM NO: 01486-20
VII. PRECAUTIONS FOR SAFE HANDLING AND USE---------------------------
SPILL RESPONSE: Sweep up material and package in a
non-combustible container.
WASTE DISPOSAL: Contract with a licensed chemical waste
disposal agency. Discharge, treatment, or disposal may be
subject to federal, state and local laws,
PRECAUTIONS TO BE TAKEN IN HANDLING & STORAGE: Keep from
·· contact with oxidizing materials.
VIII.CONTROL MEASURES---------------~------~-----------------------
RESPIRATORY PROTECTION: If engineering controls are inadequate
to control dust concentrations to an acceptable level, a
NIOSH-approved dust respirator should be worn if needed.
If respirators are used, a program should be instituted to
assure compliance with OSHA Standard 29 CFR 1910,134,
VENTILATION: Use process enclosures, local exhaust ventilation
or other engineering controls to reduce.dust concentrations
to an acceptable level,
SKIN AND EYE PROTECTION: Protective gloves and clothing should
be worn, Safety glasses or goggles should be worn,
*************************************************
DISCLAIMER
The above information has been transferred to this format by
Cole-Parmer Instrument Company, from a Material Safety Data Sheet
supplied by the manufacturer identified in Section I, The contents
of this MSDS have been represented to Cole-Parmer by the manufacturer
to be complete and accurate.
If you have any questions related to the material provided herein,
contact the manufacturer directly at the address and phone number
given in section I of the MSDS,
Cole-Parmer does not, in any way, represent itself as an expert in
the chemical described in this MSDS and assumes no liability for any
incomplete or inaccurate information contained herein,
8
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\/IALLINCKRODT
1aterial Safety Data Sheet
----
Mallin,krodl provide& lhc Information ronlaincd hcn:in In good fai1h
bul maliu no rcprucnlallon H lo iu romprchcnaiYCnUI or a«uruy.
Individual, rcccivin& lhc ln(onnalion mu,1 ucrcilc 1hcir Independent
judpncnl in dt1cnninln1 i11 appropriatcncs.s for• panicular purpow:.
MJ\LLINCKRODT MJ\Kl!S NO IU:PRESl!NTA110NS, OR
WARRANlll!S, ErnlER EXPRESS OR IMPLll!D, OP
o1llinckrotl1, Inc."' Science Producu Diviiion, P.O. 801 M · Paris, KY 40361
SOPROPYL ALCOHOL
'RODUCT IDENTIFICATION:
,ynonym,: 2-propanol; uc-propyl alcohol; jsopropanol
·orm1,1la c.AS No.: 6 7-6J..--0
..tolccular Wcishl: 60.10
Chemical Formula: (Cll3)i CIIOII_
I hurdoua lnpdien11: bopropyt alcohol
l'llECAUTIONARY MEASURES
WA..,,.IN'CI flAMMAIL~ UQlllO. IIAI.MnJl.lf
.\WAU.OWlO oa 11'1lAUD. A.fRCTS Cl:KTI.AL NlRVOUS
SYSTEM. C.Ausr:s IRJ\JTATI01'4.
Ktep aw.y l,om hul, 'fM'k.s and flame.
Kup container cloud.
Ui.c wilh 1dequ11e ven1il•1ion.
Avoid bru1hin1 vap0r.
Wuh 1horoughly 1her h1ndlin&.
Avoid con11c1 with eyes, ,kin and clo1hin1.
EMERGENCY/FIRST AID
If iwallowed, &ivc .ntcr 10 drink. Induce \IOmi1in1 if medical help
i1 not immcdi11cly 1vail1ble. Never civc anyahin1 by moulh 10 1n
unconu-iou, r,cn.on. Ir inhaled, 1em0¥c lo huh air. U nOI
bn:alhinc, civc aniricial rupiRtlOn. U breathing 11 difficult,
cive Dl)'lcn. II\ cue of con1ac1, immedi11el)' n,uh iii.in or eye•
wilh plenly ol waler to, II lcall u minulCl. In •II cas.c, call.
ph)'1iciaR.
SEE SECllON 5.
DOT IL:wud Clau: Fhmm.1blc LiquiJ
S[COON I fhnlnl D@fl
Appunincc: Ocar, rolorteu liquid.
Odor. Rubbin& 1kohol.
Solubili1y: ~nfinilc In waler.
Boilin& Point: U"C (IBO'f).
Mcl1ln& Poini: -3\l"C (-121"f).
Spcclric poviry. 0. 79
VaporDcMily(Alr•I): :I.I
Vapor Prc&1urc (mm H&): lJ@ lO"C (68"f)
l!vaporalion Ralc: (o.-DUAC • I) U)
SECflON 2 Fffl end E•etoate'! lnfenn,tlon
fire:
A1mm1blc Liquid
Fluhpolni: lrC (H"P). (cloo<d cup).
Auloiphion lempcnilu~: JWC (750"'P).
f11mm1blc limits in air, 4J'o by \IOlume:
Id: 2.0; ucl: 12.0.
Explosion:
Above naih polnl, vapor-air mlrlurc, arc oplo&iw: wi1hiR
Oammablc limi11 n<Med aboilc. Con1ac1 with tln>n& oa.idiren may
uu1e tire or uplo&lon.
fire Eallnculshlnc Media:
Water ,pray, dry chemical, alcohol roam, or carbon dio1ide.
Water 1pny may be used lo keep fin: Cipo&ed conlainen cool.
Spcclal lnrormatlon:
In lhc evcnl ol • fire, wear full pro1ec1ivc clo1hin& and
NI0SI I-approved ,el(-<onlained brca1hin, appanlus wi1h full
fac-cpiecc opcn1ed in lhe pressure demand or other p<»ilivc
pruiurc mode. Wa1er may be us.cd 10 Ou,h 1pilb away from
uposurc1 and 10 dih,le 1pill1 lo non-Oammable ml1111rc1. Varon
on OOW' alone ,urfacu 10 di1tanl i1ni1lon 1ource and Oa1h
back.
NFPA R11ln~1: llt:■hh: I fl ■mmat., ) Ruc1ivi1y: 0
11!!!!!1 I!!!!! !!!!I ·~ =s
FOR S/P CAT I C4307 & ,
==
-5
Ml!ROIANTAIIILrl"Y, FTINl!SS l'OR A PARllCUIAR
PURPOSE wm, RESPl!CTT01lll! INFORMJ\TION Sl:T
l'ORTII lll!REIN OR TOllll! PRODUCrTC> WIIICII ·1111!
INFORMJ\llON REl-l!RS. ACCORDINGLY, MAI.I.INCKRODT
WILL NOT Ill! RP.5PONSIULI! l'OR DAMA(iES RESUL.llNG
PROM USE OP OR RliLIANCJ! UPON ·1111s INFORMAllON.
Emergency Telephone Numl1<r.) l ◄-981-5000
SECTION) Ruqlvl1J 1>11tp
Stablllly:
Shible under ordinary rondilions of 1.11,C anJ 11o~gc. llc ■I ■nd
1unliJt11 can conlribulc. 10 iMt ■bility.
ll■urdous Dtcomposhlon Pnxtuc1.s:
To1ic lqc_s and vapun 1uch II carbon monoaillc may I.Jc r-clc ■1cd in
• fire involving lw:,prop)'I alcohol.
llaurdous Polymuiullon:
Will ROI occur.
lncompatlblllllu:
llcal, 0•mc, ,iron& oaidi.tc.n., aceudehydc., chlorine, ethylene
oaide, hydrosen-palladiudl combination, hydroic.n pc.1011idc.-~ulfu1ic
acid combina1ion, pacu.slum 1ert-bu10Udc., hypochlorou1 acid,
i1J<xy1u,a1u, nilroform, pho61en~. oleum and pcrchlotic acid.
SECDON 4 L,.k/Splll Dlspo'"l lnfonnallon
Remcwc 11l 1o0uru:1 of igni1ion. Vc.ntil.alc. area of lc ■li. or
spill. Oun-up pcnonnel require protcc1ive clolhing and
rc1pi111tory proh:clion (,om vapon. Sm.all spills may tic.
•bsorbcd on paper towel, anJ evap0n1cd In a fume ho£)(]. Allow
el\ouch time for fumu 10 clue hood, !hen ignite p11oc.1 in a
1ui1able loca1l0fl away from rombu1tiblc ma1c.1i.al1. Conlain anJ
rcCO\'cr liquid for rcclamalion when pouitilc.. Larger spills
and k>I 1izc.1 can be rollcclcd u haurdous ~sic and .atomized
in• 1ui1able RCRA approved combu11ion chamber, or abso1l.icd
wilh vermiculite, dry unJ, canh or 1imilar ma1c.Oa1 fur
di1paul a1 hu.ardou, wa1lc in a RCM approved fui1i1y.
&sure compliance wilh local, ,1a1e and fcdc.n,I 1cgul,111ions.
/]L)
,,.,.nnnovr I\ I rn111}1
Etfcctivt. e: 04-06-89 Supersede, 07-13-87 SECOQN 5 Hnttb lhyrd lprorm■Uon A. exroSURE / Hl!ALDI EFFl!CTS labal■llon: May auac lrrti.t1on ol the nOK and throat F.xpolYrc to hip ronccn1ra1k»N hu • narcotic dfut. produdn1 l)'fflploml ol dtow1lna1, ~he, 111gcrtaa. ~ and pou&bly duUL lnrr,11oa: {,' ,' ~· May CliUK d.,,,..lnaa. u~ and death. Ouuoin1t1tlnal pailn, tt1mpa,. n•IIIKA. womillq. ud dlarfflu may abo ruulL The ainp_c lclhal DC lot• hurun IIMl11l1 • about 250 mla (SAX Si.db l!dhlon). Sida Contad: llu • dcf1tlln1 action ol lhc 1kln that can UUIC lnilatlon. May cavac lrrilatlon with • 11lncin1 effect and bum.in& acnaatN>a.. Eye Contad: Vapon m1y Inhale the qa. Spluhca may cause KYCrc lrritallon, s,c-aiblc corneal buru and eye dama,c. Cbl"Oalc Esposurr. Prolon,ed rot1Lact Mcb 1Ua may cauac mild lnitallon, dryins. cnckJn&,. or con1at1 dcnnalld• ally develop. Agn•atlon of Pn--cd1lln.1 Condlllons: Pcnou wi1h prc~PJtlna 1k.in dlsordc:n or eye problcma or impaired rupinlory functioa DIAJ' be more tuKCptiblc to lhc dfccu ol thc 111bllancc. --,_ ---lililliiil D FIRSTAIP labalatloa: llellNJll'C 10 frab air. Ir nae brcalhlns. pvc artlfadal ...,.nllon. 11 b, .. 1bl•1 lo dlllkvll. pc •-n<•-Call a phpklao. lap1llaa: Ohc .. ,er lo drint~ Induce womilln1 If medial help nol 11 inunedla1cly •wilablc. New:, pvc anythlna by mou1h 10 an UftC'OMdoua pc~. Ocl medical aucnUon lmmcdl1tcly. Ski■ llspaturr. Rcmow any contaminated d01bln1, Wuh 1tJn with IGlp or mild dclerpnl and water for 11 k.ul U minutu. Ot1 medical atlealk»a II lrri111kaa dcwlopl or pcnist&. ll:,e ll,rpasun,: Wuh c,a wi1h plen·ty ol water for at lu11 IS mlnulu, li(1in1 kJM:r 1od uppc·r cyclkll oa:uk»aally. Oc1 medical altention lmmcdlalcly. · C. TOXICITY DATA (RTECS. 1986) Onl nl LO,O: SMO mlf'k&-Skin nbblt LD50: ll pt/kl-Jnhaladon nl LCSO: 16000 ppm/811. Mu111ion rdercncu died Aquadc Taaklly ndn1 llm96: 1000-10 ppm. SECTtON f Qttu11Uon1I P,ntrol Mruur:rs Alrbnme llspasun, Umlla: --OSHA Pcnnlalblc l!iipolur< Umi1 (Pl!L): 400 pp,o (IWA), 500 ppm (STl!L) -ACOIII Thruhald Umll Value (Il.V): 400 ppm (IWA), 500 ppm (STl!L) liiliii liilill . ,----._ lillil --== ISOPROPYL ALCQJl{\L Venlllallaa Sysum: A system of locaJ aod/or ,coc,-1 uhaud ii ruommc:ndc.d 10 keep cmpkJycc csp,c»ura below lhc AJrbomc P..xpa1un: Limits. Local c.duUIII wnlilall,on • scnc,-Uy pn:ferrcd b«aw.c II can roalrol lhc cmlaba.l of the rontamJna111 al it1 IIOUfU.. prcwcn1ln1 dllJ'Crdoa ol II ln10 lhc ,cncnl worl. aru. F1c.u.c rdcr 10 1hc ACOIH document. •JndldlriaJ Vcn1i1a1k>n. A Manual al Ruommc:ndc. Pnctka•, moat recent cditk>a., for dctaila. P•naul Rnplratan: (NIOSII Appn)ffd) I( lhc 11.V II cattiedcd ,· fuU lattplc« chcnuca.l aruklic respirator m•y be worn. In acDCn.l. up IO lhc mu:imum UK ~nt,.tk>II 1pccmcc1 by 1hc_rapin1or 1upp1icr. AltematMly, a 1uppHcd air fllll lac::cpkct rapln.lor or alrtincd hood ma1 be "°m-Skin Protection: . Wur lmpc:tw>ul prolu,i.Jre dothln1,. lnclwdin1 boota, JIO¥U, l•b coea. apron or cownlll 10 prcwnl •tin roman. E:,e l'rolectlaa: Uac chtmkal .,.fcty aoatca ind/or• full f11tt 1hidd when: ,pluhln1 la pcmlblc. ConlaCt lcue11hou~ noe be wom -t.cn .c>nJng .-ilb th.Ill ma1criaL -Maintain c:yc wub (ouarain and qukt~rcDCh fadlilka In wort.. arc.a.. SECIJON I Stoon ·■ed Sortf■I [oform1Uon Pro1cc1 1phu1 phyakal dam•sc-S1on:: In • cool, dry wc:U-w.n1il11cd kKalion. my from any aru wht:rc lhc fin: haurd m1y be .a.le, Outaldc or dcuchcd 11onsc ii pn:ferrcd. Scpa~1c from oddidn1 m11criala. Coa11inen 1hould be bonded ind poundc:,I for 1randcn 1011\'0id 1111ic .-parb. S1ongc and u.w: areas 1hould be No Smokin1 afUI-Ute non..-part.idJ type 1oolli ind cquipmcn1. ···························································· ISAI.C -=:I --~ 1111111
----

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l!!!!!!!!!I == iiiiil ----
LL I N C KR O DT MallinckroJI rruvtdcs the Information con1aincd hcn:in In p>d railh
/I A bul makc:a no rcpru.cn111ion u lo ita comprchcn1Mnc:u or IC'C'\lncy.
11 lndMd .. la 1«<ivin1 lh< information mu,i uuri., lhcir lndcpcndcnl
Judpncnt In determining ill •ppropriatcnua for• ~r1icvl■r purpow:.
1terial Safety Data Sheet MAUINCKRouTMAKcsNo iuirRcsl!NrAnoNs,oR
WARRAN'lll'.S, l!fll ll!R l!XJ'Rl'.SS OR IM PLIED, OP
MER□IANrAIJIUIY, HINES.S FCJll A l'AR'llCUIAR
PURPOSI! wrrn RE.SPl!CrTO 'll 11! INFORMAllON Sl'.r
FORlll lU!Rl!IN OR TO 1111! l'ROOUCrTu WJIICJI ·111E
INl'ORMA'llON Rl'FEIIS ACCORDINGLY, MALLINCKRODT
WIil.. NOr Ill!. RESPONSIUIJ! 1:oR DAMA(iE.S RESUl.'llNCi
FROM USI.! 01' OR IU.!.UANC..1! UPON n11s INFOR.MAllON.
linck..1od1, Inc. Science Products Division. P.O. Box M Paris, KY 40361 EmuxrnCJ T .. lcphonc Numbtr. J 14-982-5000
n,is Addendum Musi Nol De
Deiached from the MSDS
hlen1i0es SARA JI] subs1ancc(s)
,ny copyin& or rcdj51rjbu1ion or the MSPS
IIUSI Include I copy or lhi\ addendum
(Chem.Key: ISALC)
r10due1 or Componcnu
of Product:
\OPROPYL ALCOIIOL (67-63-0)
Addendum to Material Safety Data Sheet
REGULATORYSTA11JS
Hazard Categories for SARA
Section Jll/312 Reporting
Acute Chtonic fire Pressure Reactive
X X X
SARA 1!11S Sect. 302 SARA Section 313 Chemicols
RO (lbs.) 11'0 (lbs.) Name LiSI Chemic.al Category
No No Yea No
SARA Senion )02 EIIS HQ: Reportable Ouan1i1y of Ex1rcmcly Hazardous Subslancc, lis1cd al 40 CFR )55.
Cl!RCIA s«.l03
RO (lbs.)
No
SAHA Section )02 EIIS Tl'Q: Threshold Planning Quantity of E••rcmcly lfaza,c.Jous Subslancc. An uu:risk (•) following a Tilfcsliolc.J l'l:rnning Quan1i1y
\i~nifie1. that if lhc ma1crial i1. a solid and has a paniclc size equal 10 01 larger lhan 100 micromc1cu, 1hc lluesholtl l'lanning Oua111i1y .. 10,000 LU.S.
i~lv\ .Senion JIJ Chemicals: Tu1ic Substances sulljccl lo annual release reportiug fC(luircmcnu lis1cd DI 40 Cflt J72.6S.
CFHCI.A Sec. Ill): Cu1111uchensivc Envi,omcni.11 Response, Compensation and Liabili1y Ac1 (Superfund). Releases In air, IJnll or water of 1)1c5,c ha1arll11u5.
~uh~tanccs which ncce,I the Hcponablc Quan1i1y (HO) mus1 be rcponcd lo the National Response Cenlcr, (800--42A-8802); Lis1cc.J al 40 CFH. ]02.4
JtCllA: Hcsour,,. Conscrva1iun and Rcclama1ion Act. Commucial chemical product wa5.lc:s desiena1cd as acu1c hazards and toxic under 40 CFR 261.JJ
RCRA
Sec. 21,L]J
No
rsnPH()J'YI. /\I .CO! IOL
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I
(@1, In-Situ Inc. 2'0 Sa ... _,, ~N•<I :i!l'fl'O't
;, :_ ii.J• I
'~,11:;i,.-,._ W"f'O"'.n;J !;T,e-.:,q:i_o '..!SJ,
PRODUCT SAFETY DATA SUMMARY
lt:;rn~z-~n ~,u,5.:-,1.~
f'>J· :.0~1!,z-a-;21
r-N::t, JIOt'l4'l...t,;U 1IN,S:n.J '-'µtl
Dace: Januar/ :4, 1991 Supercedes: ~one
Product Name: ln-S,t'J, Inc. Hermit Oata LogGers
Product Mace!: SEIOOOB. SclOGOC, SE.2000 ,bvironmental Data Loggers.
Hazard c:ass,Dlvlslon: L.:N3C91
' Product Hazard: LiU,ium O:,yhalidi Prima,y Barter,, Pack; pack ccmprtsid c1 500 cells
Chemistry System: Litllh.mvBror.-Jne Chloride in Thionyl Chloride
Chemical Formula: Li/BrCI In SOCl2
I. Toxic, c.iustlc or Irritant Content
Important Not,: Toe Batta!Y Container(l.t. the Oa:a Lo9ge<) should nae be opened or incinerated
since the lollcwing Ingredients concaintd wiL~in could be harmful under some circwnstancas II
e,posed.
Materials
Lithium is indud1d in this section due 10 its vigorous rtaction with water terming a
strong hydroxide. (CAS , 7439-93-2)
Thionyl Chloride. (CASI n19-0~7)
eromina. (CAS , n2s-s!-eJ
Chlcrint, (CAS I n62•50·5J
In ca.:• or accidenlal ingestion of a cen er its contents, obtain prompt medical adllfce.
n. Storage and Olsposat
Storage: Data logger operating and storage temperature Is •40'C lo +70'C. Do not subjeci data
logger or internal battery pack to temperalcres in excess of 100'C(212'F), Such abuse c:an resuit in
loss cl seal. leaka;e and/or cell explosion & pos.sible subsequent data 109ger expklslon.
In case of flre in an adjacent area. use water, CO 2• or dry chemical fir• extinguishers ii bane,y pack
remains in lhe data logger. In cases whera the data logger has been damaged and substquent
damage to the battery pack has cccurlld. er if the data logger is directly Involved in flame, use Ulh·
X(Graphile Base). In this case, uae no water. CO2 or halogen exUnguishers, Avoid fume
inhala:icn(UOH, SOCl2, S02, HCIJ.
Olsposat: In ord ■r ta maintain data logger integrity and warranty, do nal attempt to remove the
batt,xy pad<. Shol:ljd removal become necessary, lollow the procauttons u above and dispose of in
accordance with appropnata Federal, Slale atid loeal r89utations. . ~ .• .
-: • HI, Handling anG Use Precautions
Use: Do n01 use this product fer other than its original intended uu. This product contains no user-
servictabla parts. Ca not remove lront panel screws lor other than ernerg,ncy accus ta battery
pack. Maintenance-and ser,tc, snauld only be performed by In-Situ, Inc. er an authorized
represenra~ve. ·
Chargi~g: The cells comprising !he internal batle!Y pack at9 primary c:eG! and ara not dulgned to be
chargt<l 0r rec:,arged. The lns1rumen1 has no capaoility to do so. To at!empl to do so may cau.ss Iha
cells 10 !eak or explode.
' , ' ,... , -l , :::.:
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14 ,Ir. b.,gcnoy Con,,c1 Tel. No.: _ (.:lOL).7.SO-.o213..-----"".,
.,
--------·---. -·---·------_D.O.T. EMERGENCY RESPONSE GUIDE 40 =-~
PO"Tj;NTLl.l HAZAf!OS IIIR.E OR EXPLOSION
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0o 1\111 UM .. i., Ill' laa,,, . s-.1 ,r,,._ Dry :t'-•"' Ml'\• ~ llnic o,, 1VIO. \.Ill• 1'11'11: Ytlll'ldr.n •~ lr<:11 ara 1« h,.. i,i,m. ll'9"'lil.,fl ,.,.,: U.-.c i>y 1ai,1J t.i•H. :n \lo,..,,., or a-1 ;,aoi~ .. ,,....
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sn .. 1 olT :.v,i.110n scu,.-: /IQ .iuu. ""°'~ Of l\a!Tlff III n.1.1:11,co 11a. 0, l'IOI IOU~ 01.-..r. ll'lt:IOIQII ,_,,11.a ,...._,,._i; ~ IIU I l'Otl i:.\11 (tQ ll "l!!"OllNII
NC llfttt" 001 I~ l'IIIMII. :o "Ot i,'" ~ .,..;..i. a;rtl'.ai'lll lirfll4 Ory ,_... WIT.ti ei.., lflgwer l)IIC<: ~-...,~ Ir'!~ e11.111. ~ cant,a1n11 ano c~ '"°'"'·· -,o.,. ,:011~.,,,. IIQITI JIWI.,.... .,_.,, IIJCl1: 1\~ ua ••II u,u,:,, 0111,... 11~J:llt ~IClt\11"4 .1\1\lt'i.a...,.. p1ac. .,.,, i:n1111.,.,., 10, 1.artt a,;,ouit U¥ ~ 0-_ lfOllod -,,1r, r,.. """ OIAl:lCISII. ~ ~ .. ao• .-Ill Cl.asnc .,, ... Qr 1.1,:, D -.m,79 ~ac-.,,,.. l"IRST AID
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c:rnty ta IPI• O.SiC Oaacrigticft sr,o TKhni.;i! N.1.-:, 1111,r-o-by lft4 11'1100,r at ll'l■ DO 01 chis ram,, a,~ m SHwf'le\hw \ho sf'lioip•r eommoa,1y 1B••c :1t-»cr1r,t~n '":,,.d U tha toi:i ,t ltli.a fom,) ia l',sta,d 0, 1.0.f and H.AJl!Of Tl-It IUiT'IRIAL 11'1 :he T,1bl• Of lnUIII lao.lation wld llrotactlw Ac:aon Ctstarocll& Thia
~la LI pa,ti&1ly rwO'lld~°" the back DI :h• G1.1,C1ft ~• 1u rafteC! cn"t eommodl~ usig,-d Lo 1bilQ~ Nurl'TW. Us• IIU •"lr::rfm.iiol'I from 1n, tlbl• 1n ,aci.110,, :a ,,,. ~uicSe Pig• IP TH!AI. NO 'Ult. R1!lo ""'° CMICK TklE NAMl!I AHO NUMIEAI CASIIFut.Lr UCAUSI COMPU'T'lli.Y Dlf1'!RENT MA1AACOUS IIIAT!AtAU CAN' HAY! litAMU ANDIOfl HUIUIIRS WMlCl4 ARI AU.OST THE MMEI CIIIII'-, .__ 111 i..&a!l.,lll,A,Sfl.JI. 0-t11 l"(l'tCUI ~U1.WJIC 00. ~ • --..._ ·•-------·-··-·-·
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D.t.JE: 11/02/91
IWDEXI 159JJO,S4J1
ACCT: 02219,-01
c,r MO, uu5oo
PACE, 1
PO NIR: 11992.0200
••PHOSPHORIC ... cm. LIQUID"" ••PHOSPHORIC ACID. LIQUID••
• •PHOSPHORIC ACID. uau10• •
MATfRlAL SAfETY DATA SHHl
flSllEA SClfNllflC CHEMICAL DIVISION
I RfAGfNI LANf fAIR LAWN NJ 01410 IJOI) 796-1100
THIS INfQRMAIION 15 0ELIEYED TO BE ACCURATE AND AEPRESENlS Tllf 81:ST
INFORMATION CURHfNllY AVAILABU TO US HOWEVER, Wf M.4.11.E NO WARRANTY Of MERCHANTABILITY OR ANY OTHER WARRANT'r. EXPRESS OR IMPUfD, WITH AESPlCl 10
SUCH INFORMATION. ANO WE ASSI.JMf NO UA81LIT'I' RESULTING FROM ITS USE USERS SHOULD MAIC.£ THEIR OWN INVESTIGATIONS 10 DETERMINE THE SUITABILITY Of THE INFORMATION FOR THEIR PARTICULAR PURPOSES.
SU8SJANCE IDfNTlfLCATION
CAS-NUMBER 7064 JO· l
SUBSJANCE: ... PttOSt>HORIC ACID. LIQUID.,.
lRAOE NAMES/SYNONYMS·
:r{iE.::f8/!:PtR~c_p~fJg~~~O.:r1?.~1.?-r':.1J~~~~i-ttORIC ACID. SONAC; EVITS.
WC-REINIGER; STCC 4930241; UN 1805; A·24l. A:365; A·JM·P. A 260. HJ04P.
ACCIIIIQI
CHEMICA.l fAMllY:
INORGANIC ACID
PRODUCJ USE: lABORAlORY CHEMICAL
MOLfCUlAA fORMULA: HJ P-04
MOLECULAR WEIGHT: QI 00
CERCLA RAHNGS CSCALE O ]) HEALTH-] rnu:-o REACTIVITY-I PtRSISTtNCE-0 ~!'~-~~•~~~_I~-~~~ ~-~_I: _ !i_E_~L-~~~~ f-lRE·O REACTIVIJY-0
COMPONENTS ANO CONTAMINANTS
COMPONENT: PHOSPHORIC ACID
COMPONENT. WATER
EXPOSURE LIMITS:
PHOSPHORIC ACIQ: I MG/Ml OSHA TWA. J MG/Ml OSHA STEL
PERCENT H 0
PERCENT: 15.0
: :g::1 Q~~ l:&J .. ~W:t A.f:t l~t✓MJ NIOSH RECOMMENDED STEl
MEASUREMENT MfJHOD. SILICA GEL TUBE; SODIUM BICARBONATE/SODIUM CA.ROONArf.
ION CHROMATOGRAPHY; iNIOSH VOL. Ill I 7ll0l. INORGANIC ACIDS).
S000 POUNDS CfRClA SECTION 101 REPORTABLE QUANTITY
SUBJECT TO SARA SECTION Jll ANNUAL TOXIC CHEMICAL HELEASE REPORTING
.,.OSHA REVOltED TUE tlNAl RULE llMHS Of JANUARY 19. 1889 IN RESPONSE 10 TltE 11TH CIRCUIT couAr Of APPEALS DECISION jAfl CID V OSHA.I EfffCTIVE
JUN£ lO. 1883. Sff 2Q CfR 1910.1000 15a fR JSllalu ..
PHYSICAi.. DATA
DESCRIPTION ODORLESS. COLORLESS SYRUPY LIQUID.
BOILING POINJ: 316 f II~ CJ MELTING POINJ: 70 f Ill Ci
SPfCtflC GRAVITY: I 815 VAPOR PAESSURf_ 2.2 MMHG ltl ll C
EVAPORATION AATf: NOT AVAILABLE Ptt. I 5 (1' O IN SOLN
SOLUBILITY IN WATER: COMPLETE
SOLVENJ SOLUBILITY: SOLUBLE IN ALCOHOL
VISCOSITY. 21 CP ~ 20 C
tlHE AND EXPLOSION DATA
flH[ ANO I Xf'L OSION tiAlARO
NlGLIGIUlt tlHE t1A.LARU WttfN fXf'OSEU TO H(AI OH tlANil
I!!!! == --iiiil iiil - -
DATE1 11/02/93
IMOEk1 1~9ll05S477
ACCl1 02289S-01
CAY NOi A2USOO
PAC[, 2
~O NHH: 19192.0200
flRl:flGII I ING MfUIA DRY CHEMICAi. CARBON OIOXIOt. WAltR SPHAY OH REGUIAII 10AM
(1990 EMERGENCY RESl-'tJt.lSl <iUIUlOOOJ.. UOI P 5tl00 !>)
fOR lAIIGEll tlH(S, lJSt WAIUI Sl'IIAY fO(; OH llll;IJIAll fOAM
C19!:!0 fMEHGt.NCY HfSPONSt GUIUEOOOJ.. 001 P !:1800 !:ii
flHtflGltllNG MOVE t.:ONIAINLH tllOM IIIU Alli A If Y(JIJ CAN 110 II Wll/10111 111:,f Al'l"I l 1,11111 JN1. WAIER TO SIUlS OF CONl AINlRS 1 UAI ARE t )0'0S tO 10 ii AMI~ UN 111 WI I I Al I I H I Ult
IS our. STAY AWAY fHOM ENDS Qt-TANl'.S 11990 EMEHGtNCY Hl!:.f'UN!:.I 1,IJIIII uuo~.
DOT P !1600 5. GUIDI: PAGE tiOJ
-
USE AGlNI SUIIAOLE FOR IYPf Of flRE USl WAHR IN HOOIJ1Nl, (JUANIIIII:, A'.> Hll,
COOL CONTAINERS WIIH flOODING AMOIJNIS Of WATfH. Af'l'I J IIIOM A:, /All A U1:,IANt:t AS POSSIOLE AVOIU BREA I HING CORROSIVE VAPORS. Hff' UPWINO
TRANSPORTATION DATA
OtPARIMt:Nl Qt IHANSf'QHIAIION UAZAHU CLA!:.SitlCAIION 4~ t:IH IIJ IUI
CORROSIVE MA I f:.RIAL
DEPARTMENI or HtANSPOHIATION L.AOEUNG RlQUIHtMtNI!) 4~ UH II] IUI ANU
SUBPART E CORROSIVE
OEPARlMENT Of 1RANSPORIAIION f'ACr...AGIN~ ll(QUJl-llMlNIS 4Y Ctll 1/J 14!::i
EXCEPTIONS ◄9 Cfll 1/J 244
U~t:E~u~~~:1:~·t1t.:u.~y_s.~A ~~~~~l ~~I :~L~~~ :;!;!Ni'11 \'~~~M 4~,J::S r~:~ I~,.!' Ju~IIU)
EfffCTIVf DATE 0C10t:l[R I. 1991 110Wt:V£R. COMPIIANr.t Wllll ltll R(l.ULAIIONS IS
AUTHORIZED ON AND AfHR JANUARY I. 1991 (5!, FR 52402. IJl2J/90J
EXCEPT FOR EXPlOSIVES. INHALATION HAZARDS. AND INtl:CILOUS SlJltSIANClS lttt ffffCIIIJE OAT( fOR HAZARU COMMUNICAIION HfGUIRlM£NI!:,, IS ()(JtNUlO ro ocroern 1. 1991 15& FR ◄115.11. 0911,111911
US Ot:PAIIIMl:Nf Of THANSPOHJATION !:,,tllf'PIN<.i NAMt IU NUMtllH. ◄~ Clll 1/2 101
PUOSPHOHIC ACIO UN 1805
US. DEPARTMENT Of JRANSPOHIAIION IIALAHU Cl.ASS UH UII/ISION. 4lj CtH Ill IOI
I -CORROSIVE MA Tt:HIAL
US OEPARTMf:.NJ Qt TRANSPORIAIION PA.CJ.ING GROUf'. 49 CfH 112 IUI
PG 111
US. DEPARIMENT Of TRANSPORTATION LA8fllNG HtQUIREMf:.NIS. 49 CfR 112 101
ANO SUBPART f:
CORROSIVE
US. DEPARTMENT Of. TRANSPORlATION PACILAGING AUTHQRIZA TIONS
EKCEPTIONS: 49 CfR 113 15-◄ NON-OUU PACII.AGING 49 CfR 11] JO] auu PACKAGING: -◄9 CfR 113 241
US DEPARTMENT Of TRANSPORTAIION OUANIIIY llMIIAIIONS 49 CfR 1/2 IOI
PASSENGER AIRCRAn OH RAllCAH !::i l CARGO AIRCRAn ONl Y 60 L
IOJtlCITY
PHOSPHORIC ACID II-IRITATION OATA 595 MG/24 HOURS 51,1N HAUtUI Sl:VtHt. II~ M(; 1:Yf HAtJllll Sl:Vttll: TOXICITY DATA 2140 MGIJ.G SJ.IN RABiill L050. l!::,)O MG/Mi OHAL RAI LU50.
no:MG/ltG UNAEPORIEII MAN LULO.
CARCINOGEN STATUS NONE LOCAL EffECTS: CORROSIVE· IN11AlATION. 51(1N. EYE. INGESTION ACUTE TOIUCITY LEVEL: MODERATELY TOXIC 8Y INGESTION; SllGHILV TOJtlC BY UEHMAL
ABSORPTION TARGET EffECTS NO DATA A\/AllAOLf
AT INCREASED RISJ. tROM EXPOSUHE PERSONS WITH PRE fXISUNG RlSPIHAIORY OH
51'.IN DISEASE.
HEAL Ht EHlCIS ANO flHST AID
INIIALA I ION f'IIOSf'ttURIC ACIU
CORROSIVF SH INIOHMAIION ON ACIUII; COIIHUSJVlS
ACIDIC CORROSIVES ACIJI[ [Xf'OSIJRE MAY CAll'.>t HfSf'lflAIOIIY IHACr UIHIIAll<lN WIIII 1:uu(,ltlNG
Cll()l,ING, ANO f'O!:.SltllY UIIIINS Qt 111t MUCOUS MtMllllANl!:i Ol1•LH INIIIAI .
SYMf'IOMS MAY INCIUut lll.l./lN(S!:,, ll[AOACIIE. NAIISI.A ANO WtAM,il!)!:, IN 11
-
D.UE: ,l/02/93
ltllEXl 159Jx»,J477
•ccr: 0221,,-01
CAT M01 A242SOO
PAC(: l
PO NIA: 19992.0200
CA.SES PULMONARY EDEMA MAY llEVElOP. flHttH IMMEOIATU YIN Sf Vt Hf CASts. OR MORE ll~ELY AFTER A LAUNT PLRIQO Of ti 12 IIOUHS 1111: !:>YMPTOMS MAY JNClUUt: TIGHTNESS IN THE CHEST. OYSPNEA. fROIHY St'UTLJM. ANO CYANOSIS t'HYSICAL FINDINGS MAY INCLUDE HYPOTENSION. WEAll. RAPIU PULSE ANO MOISl RAUS RECOVERY MAY BE PROLONGED ANO RflAPSES ARE POSSIBIE IN SEVERE lltPOSUHES DEATH DUE TO ANO.ltlA MAY OCCUR WIIIUN A ffW HOUHS AtlfH ON!ifl Of PULMONAHY EDEMA SYMPTOMS QA FOLLOWING A RflAPSE CHRONIC EXPOSURE· DEPENDING ON THE CONCl:.NlRATION ANO UURAllON Of l:.llt'OSUH.I:. RfPfAlfO OR PAOLONGEO EXPOSURE MAY CAUSE EROSION Of THE TEETH. INFLAMMATORY AND ULCERATIVE CHANGES IN THf MOUTH. AND POSSIBLY JAW NECROSIS BRONCHIAl IRRITATION WITH COUGH AND FREQUENT ATTACII.S Of BRONCHIAL PHEUMONlA MAY OCCUR GASTROINIESTINAL DISlUHBANCES AHi:. ALSO POSSIBLE.
FIRST AIO· REMOVE fROM EXPOSURE AREA TO fRESII AIH IMMl:OIAlflY If l:lHl:AIIIINl> HAS STOPPED. GIVE ARllflClAL RESPIRAJION MAINTAIN AIRWAY ANO BlOOU PAESSURE AND AOMINISlER OXYGtN It AVAILABlf l(t"fp AfffCTED PUISON WA.HM ANO AT REST TREAT SYMPTOMATICAUY AND SUPPORTIVflY ADMINISTRATION Of OXYGEN SttOULD Bf PERtOHMED BY QUALIFIED PERSONNEL. GEJ MEDICAL AllENHON IMMECHA TEL Y.
Sl(IN CONTACT· PHOSPHORIC ACID. I CORROSIVE. ANIMAL STUOIES INDICATE THAT SKIN ABSORPTION MAY OCCUR. SEE INfOHMAIION ON ACJDIC CORROSIVES.
ACIDIC CORROSIVES. ACUTE EXPOSURE -DIRECT CONTACT MAY CAUSE SEVERE PAIN. BURNS AND POSSIBl Y BROWIMISH OR VELlOWiSH STAINS. BURNS MAY Bf DEEP WITH SHARP EDGES ANO Hl:AL SlOWL't WITH SCAR TISSUE fOAMAflON CHRONIC EKPOSUAE· EFFECTS OfPfNO ON THE CONCENTRATION ANO DURATION Of EXPOSURE REN:ATEO OR PAOLONGEO CONTACT MAY RESULT IN DERMATITIS OH EFFECTS SIMILAR 10 ACUTE EXPOSURE
flRST AID· REMOVE CONTAMINAlfO CLOIHING AND SHOES IMMEDIATELY WASH At'fECll:O AREA WITH SOAP OR MILD DETERGENT ANO LARGE AMOUNTS Of WATER UNTll NO EVIDENCE OF CHEMICAL REMAINS jAl LEAST 15 20 MINUTES) IN CASE Of CIIEMICAL BURNS. COVER AREA WITH STERILE. ORY DRESSING BANOAGf SECURELY. BUT NOT TOO TIGHTLY. GET MEDICAL ATTENTION IMMEDlATELY.
EYE CONTACT: PttOSPHOtUC ACID: CORROSIVE DIRECT CONTACT WITH AO IOM SOLUTION BUffEHtU 10 PH 2 5 CAUSED A MOOERAff. BRIEF STINGING SENSAIION. eur NO INJURY WHEN APPi IEU AS A SINGLE DROP IN HUMAN EYES. WHEN ADJUSTED TO PH ] 4. A DROP OF TUE SOLUTION CAUSED NO DISCOMFORT IRRIGATION Of RABBIT EYES FOR 5 MINUTES WITH PH l O SOLUTION CAUSED SLIGHT TRANSIENT EPiTHEllAL EDEMA ANO CONJUNCTIVAL HYPEREMIA. BUT THE EYE WAS NORMAL WITHIN 24 HOURS. WHEN INJECTED INTO THE CORNEAL SlROMA OR APPllED TO THE CORNEA. AFTER REMOVAl OF THE EPITIIELIUM. IT CAUSED DETECTABLE IHJURY BELOW PH 5.5 EYE BURNS MAY RESULT FROM SPLASHES Of CONCENTRATED SOLUTIONS. SEE INFORMAHON ON ACIDIC CORROSIVES.
ACIDIC CORROSIVES:
"i~"},E JJ~i~l:f;.fr•~EBCJR~~~I~fTE::fJEfi~J-:JfRf~~~E~'i~1:,':!~~L/:2b0f~p:•:E RECO\IEAS COMf"L.ETfLY. IN SEVERE CASES. THE EXTENT Of INJURY MAY NOl BE FULLY APPARENT FOR SEVERAL WEEKS ULTIMATELY. THE WHOLE CORNEA MAY BECOME DEEPLY VASCULARIZEO AND OPAQUE RESULTING IN BLINDNESS. IN THE WORST CASES. THE EYE MAY BE TOTAUY DESTROYED CHRONIC ElllPOSURE· EFFECTS DEPEND ON TttE CONCENTRAHON ANO DURATION Of EXPOSURE REPEATED OR PROLONGED CONTACT MAY CAUSE CONJUNCTl\11115 OR EffECTS AS IN ACUTE EXPOSURE.
Fltm1~~U~'i"Atift~:::~~~~'JNV.lT~~i't~t~~r~~TlH~;.~:~~ .. 0.5~~st~~AlL y LEAST 16· 20 MINUTfSI, COHTINUf IRRIGATING WITH NORMAL SALINE UNTIL TH£ PN KAS RETURNED TO NORMAL llO·to MINUTES!. COVER WITH STERILE BANDAGES Gfl MEDICAL ATTENTION IMMEDIATELY.
INGESTION: PHOSPHORIC ACID CORROSIVE.
SEE INFORMATION ON ACIDIC CORROSIVES
ACIDIC CORROSIVES: ACUTE EXPOSURE-MAr CAUSE CIRCUMORAL BURNS WITH DISCOLORATION ANO CORROSION OF THE MUCOUS MEMHRANf.S Of THE MOUTH. THROAT ANO ESOPHAGUS THfHE MAY BE IMMEOlAlE PAIN AND OifflCULTY OR INABlllTY TO SWAllOW OR SPfAI( EPIGIOl lAl EDEMA MAY RESULT IN RESPIRATORY DISTRESS ANO POSSIBLY ASPHYXIA MARHU THIRST. NAUSEA. VOMITING AHO DIARRHEA MAY OCCUH DEPENDING ON JHE AREA ANO DEGREE Of CORROSION. THE VOMITUS MAY CONIAIN fHtSH OR DARI(. BLOOD ANU lAllGt: SHREDS Of MUCOSA SHOCK MAY OCCUR WITH MAHII.ED HYPOTfNSIDN. WfAII. ANO RAPID PULSE. SHALLOW RESPIRATION. AND CLAMMY SIi.iN· CIRCUIATORY COLLAPSE MAY DEVELOP AND IF UNCORRECTED. LEAD TO RENAL FAILURE IN SEVERE CASES. GASTRIC ANO. 10 A LESSER DEGREE. ESOPHAGEAL PERFORATION MAY OCCUR WITH PERITONITIS ACCOMPANIED BY FEVER ANO ABDOMINAL RIGIDITY. ESOPHAGEAL. GASTRIC OR PYIOHIC STRIClURE MAY OCCUR WIT111N A fEW WElllS. OR MAY Of OHArEO FOR MONTHS OH t\lfN VEA.RS DEATH MAY RESULl WITHIN A SHORT TIME -- -----
P4GI .. DAfEI 11/Dl/9]
INOU1 1§9llOS5•H7
ACCT1 022895-01
CAJ N01 A242500 PO NBH: 19992.0200
FROM ASPUYXIA CIHCULAIUHY CQl!At'!)f 011 ASPIIIAIION 01 !VIN MINIIII AM(}IJNI~ If Q[Altl IS Ot:IAYl;U, JI MAY Ltf Out 10 t't'HIIONll15. !ilVllLf Nll'ltlllll!) 011 PNEUMONIA COMA ANO CONVUISIONS SOMt: llMt'S OU'.lJH 11:IIMINAll Y CHIIONIC fllPOSUHE Ot'PlNOINc.;·ON Tttl CONClNTIIAll(JN lifPIAllll INl;t~IION MAY RESUI TIN INfiAMMATOHr ANO ULCERATIVE CUANGI:.!) IN IHI. MUCOIJS M[MBHANlS Ot ltlE MOUIH ANO 0111lR UHCTS AS IN A.CUil INGESIION
tlAST AID DO NOi USt: GA!:>IIUC lAVAGl OH tMl!:>IS UHtJll ltll ACIIJ 1MMIU!AllLY BY DRINKING LAHGE QUANllTIES Of WAHR OR MILK If VOMIIING PfH~1:;15 AOMINISlER HUIOS REPEAHlll y· INGES IEU ACID MlJSI OE Oil Ill t tl At't'IIOXJMA Ill Y 100 FOLD TO RfNOfR If IIAHMlfSS TO llSSUtS MAINfAIN AIRWAY AN!I IHI Al SltUC"
1~::Ji~.:fr.:t:r~g~?t.Nif o~tii~.•Nl((hi2~rAt° dt?JJ.i ~~p~1~1! 1:t', 1J ~1:t'~~N J A.SPIRA TION
Ht.ACIIVIIY
REACIIVJIY H£ACIS MllUIY Wllll WAIEH ANO £VOLVLS tll:AI
INLOMt'A 118111 lltS t'ttQSPHOfUC ACIO BASES· VIOLENT REACllON CHLORIDES• SIAINLfSS SHU· AEAClS WHH U8ERAIION 01 t llt'L051Vl llfllllU~lN GAS FERROUS METALS ANO AllOYS Vt:HY COHIIO!i!Vl. t llt't:CIAll y WIil N IILA It II GRANITE ATTA.CHO DY 110T CONCENIHATEO ACIO METALS· HEACJS WIIH llUfRAIION Of f.llf'lOSIVf IIYUHOGtN «;AS NITROMEIHANf FORMS DEIONAHIE MIXllJRf PIASJICS, RUBBlfl. COAIINGS MAY IH Al JACHll PORCUAIN ATlACUO UY 1101 CONCfNTHAlfll ACIII SOOJUM IE I HA.IIYOHOtiORAll GENlHA I lS UEA I ANO MAY Ut l llt'I 0!)1Vl ON UAl"IIJ MIXING.
OECOMPOSIIION THERMAL OECOMPOSJIION MAY RHEA.SE TOXIC OXIUl:S m PtlO!)t'JIOlltJS
POl YMfRllAIION
IIA2AR00US POLYMERIZAllON HAS NOT BEEN REPORlEU 10 OCCUH UNUlH NOHMAL TEMPEAATUHES ANO PRESSURES
t'HEVENIATIVI::: Ml:ASUlltS
SI ORA GE ANO DISPOSAL
OBSERVE All FEDERAL. STATE ANO LOCAL REGULATIONS WHEN SIOHING OH 01!:>POSIN-.; Of THIS SUBSTANCE.
••STOHAGt:"•
PROTECT AGAINST PHYSICAL DAMAGE STORE IN COOL. ORY. WEU VENTHAlfO LOCATION. AWAY tHOM ANY AHEA WHERE THE flRE ttA.l.AHD MAY tl£ ACUH 4Ntf>A 4!J HAZAROOUS CHEMICALS DA.IA, 191!:il
STORE AWAY FROM INCOMPATIBLE SUBSTANCES
••DISPOSAL••
DISPOSAL MUSI Bf IN ACCORDANCE WITH SlANUAHUS APPUCAtHf 10 GlNlHAIORS 0. HA.LAROOUS WASTE. 40 CfR 282 fPA HAZARDOUS WASTE NUMtiEH 0002 100 POUND CERCLA SECTION 10] RtPORTA8lE QUANTITY ..............................................................................
CONDHIONS 10 AVOIU
MAY BURN BUT DOES NOT' IGNITE HEAUll Y flAMMAtil f. POISONOUS GA.Sf:!) MA't ACCUMULArf IN TANKS AND HOPPER CARS MAY IGNllf COMBUSlltlLES (WOOD. PAPLH. Oil, UC).
SPILL ANO HAil PHOClUUHES
SOIL SPILL· DIG A HOLIJING AfU:A SUCl1 AS A PII. PONO QA LAGOON 10 C:ONIA1N Sf'U I ANO llJ~I SURFACE flOW USING BAHHIER Of son. SANDHA<iS. fOAMfO t'OI YIJIIL IIIANl Oil IOAMI (J CONCRllE ABSORB UOUID MASS Wllll HY ASII OR CtMENT POWDER
NlUTRAlllt: SPILL WIIH StAHU llMl. SODIUM tilCAHllONAII:. 011 t.:llUSltlU IIMtSIUNt
AIR SPILL. l(NQO. DOWN VAPORS Wlltl WAIER SPRAY l(HP UPwlNO
WAlfH tJSt.0 10 l(NQC,.; OUWN VAl'OHS MAY 8{C0MI. (;OllHO!.IVl OH IOl\lC ANU 5tl0IJIII Ul CONTAINt.O PHOPl'HLY fOR IAlt:R UiSt'OSAL ---

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D.HE: ACCr: 0228H-01
HIDU1
11/02/9)
1§9~'1477 CAr M01 A20,oo PO NIR: 11112.0200
WATER SPILL NEUIRAlllf WITH AGHiCULTUHAl LIME. SLAHU llMl. CHUSlllO LIMfSIONf, OH SOU1UM
BICARBONA 1 E
USf MECHANICAL OAEOGfS OH LIi-JS TO tXlHACI IMMOBIUZt.0 MASSES Of POllUIION ANO
PAECINTATES.
OCCUPArlONAl SPILL
00 NOT TOUCll Sf'lLLfD MATfRIAL SlOP HAIi. If YOU CAN 00 H WIIUOIH fllSI!. fOA
SMALL SPILLS. TAllf UP WHH SANO OH orHER AtlSOAl:IENT MAH.RIAL AND PlAl:t INlO
CONfAINEAS fOA LATER DISPOSAL FOR SMALl DAY SPILLS. WIIH CLEAN SHOVH PIACf
MATERIAL INTO CLEAN. DR't' CONTAINER AND COVER MOVE CONTAINERS FROM SPILL
AREA FOR t.-.AGEA SPILLS. DIKE fAR AHEAD OF SPILL FOR LATER DISPOSAL. ltHP
UNNECESSARY PfOt'lE AWA'f. ISOLATE HAZA.AO AREA ANU OfN'( ENTR'f
REPORTABlE OUANTITV ~O~ !i,000 POUNDS rn1?.:1:r~:J11~i~~ l~ Ji ~~~A~~:'{1.:~c:,R1f~:1~r~nA1~tt~L~tfiw~NtJi• 1~:1~UIRlS
SUBSTANCE Bf IMMEOIATHV REPORTED 10 THE LOCAL EMERGENCY PLANNING COMMIIIH
~::I~ r~~sVt.!l1: £,-:ERRE%i~~:t:~NNJfR cg-,:~i1s~~~.16i cr:3_1it:0~...'f1J~~lR~~~~tft
f.\~MiAPC~tVflNe~~J.1:~~01:.~EglAm.: I~~ ~f~,~~4a,~02 OA 12021 H6-Z61~.IN THE
PROTECTIVE fOUIPMfNI
VENTILATION
PROVIDE LOCAL EXHAUST VENTILAllON SVSTfM TO MEET PUBLISHED EXPOSURE LIMITS
RESPIRATOR
THE FOLLOWING RESPIRATORS ANO MAXIMUM USE CONCENTRATIONS ARE RECOMMENDATIONS
ev THE U 5 UEPARTMENT Qt HEALTH ANO ttUMAN SERVICES. NIOSH POCII.H Gu10t ro
CHEMICAi HAZARDS. NIOSH CRllEAIA DOCUMENTS OR 8'( THE US DfPARTMlNT Of
lA80R. Ul CtR IQ 10 SUBPART 2
THE SPECIFIC HESPtRATOA SELECTED MUST UE BASEU ON CONTAMINATION HVhS tOUNO
IN THE WQHI!; PLACE. MUST NOT EXCEED THE WORll:.ING LIMIIS Of THE RESPIRATOR ANO
Bf JOINHV APPROVED ev THE NATIONAL INSTITUTE FOR OCCUPATIONAL SAtEn ANO
HEAlTH ANO THE MINE SAFETY ANO HEAl.TH ADMINISTRAllON (NIOSH-MSHA)
PHOSPHORIC ACID
25 MG/Ml· AN'( SUPPllfO·AIR RESPIRATOR OPERA.HO IN A CONTINUOUS HOW MOOE
50 MG/Ml ANV SUPPUEO·AIR RfSP1RATOR WITII A fUU FACfPlfCf.
ANY SfLF·CONTAINfO BAfAlHING APPARATUS WITH A FULL FACEPlt.CE
AN'f AIR·PUAIFVING FULL FACfPIECE AESPtRATOR WITH A
HlGH-EfflClfNCV PARTICULATE FILTER.
2000 MG/Ml· AN'( SUPPt.lEO-AIR RESPIRATOR WITH fUll FACEPtECE ANO OPERA TH> IN
A PRESSURE-OE MAND OR OTHER f'OSH IVE PRESSURE MOOE
ESCAPE ANV AIR PUAlf'flNG fUll FACEPlECE RESPIRATOR WITH A
HIGH-EFFICIENCY PARTICULATE flLrEH.
AH'( APf'RONUATE fSCAf'f-TYPf SELF-CONTAINED BREATHING APPARATUS.
FOR FIREFIGHTING AND OlHEA IMMEDIATELY DANGEROUS TO Liff OR HEALTH CONOIIIONS.
AN'f Sflf·CONTAINEO BREATHING APPARATUS THAT HAS A fUll fACfPIECE ANU IS
OPERATED IN A PRESSURE ·DEMAND OR OTHER POSlllVE PRESSURE MOOE
AN'f SUPPLIED-AIR RESPIRATOR THAT HAS A fUlL FACEPIECE ANO IS OPERAlEU IN A
PRESSURE-DEMAND OR OTHER POSlllVE·PRESSURf MOOE IN COMBINATION w,rn AN
AUXlllAR'f SELF-CONTAINED 8RfAlHING APf'AAATUS OPERATED IN PAESSURE-UEMANO
OR OTHER POSITIVE-PRESSURE MODE.
ClOTHING:
EMPlOVEf MUST WEAR APPROPRIATE PROTECllVE 1•MPERv1ous1 CLOTHING ANO fQUIPMENl
TO PREVENT ANV POSSUUUH Of SIi.iN CONTACT W lH lHIS SUdSTANCf.
GLOVES·
EMPLOYEE MUST WEAR APPROPRIATE PROTECTIVE GLOVES lO PREVENT CONTACT Wlltt THIS
SUBSTANCE.
hf PROHCTION·
EMPLO'(ff Musr WEAR SPLASlt·PROOF OR OUST·RESISIANI SAffT'( GOGGLES ANO A
FACESHllLO TO PREVENT CONTACT WITH THIS SUBSTANCE.
EMt.RGENC'f WASH fAClllTIES
'Wilt RE THfHt. IS ANV POSSIIIIUf'( TIIAI AN EMf'IOYH"S tvts ANll/OH SKIN MAY tu
ExPOSEO TO THIS SUl:lSU.NCE. lHE EMPtOVfR SHOUlU f'ROVIUE AN EVE WAStt IOIINIAIN
ANO QUICII:. UHENCtt SHOWER WITHIN THE IMMEDIATE WORII:. AREA fOR fMERUlNCY US[
PHlPAltAIION INJORMAIION
l'HEl'AH[D Br OCCUf'AIIONAl lit.Al 111 SEINICt.S.INC fOH flSJU:.H SCltNllflC GllOUt'.INC
flSlltH SCHNfll'" flSttER SOtNllflC
I!!!! == raa iiii ill --
OAJEi
IMUEX1
ll/D2/91
1StllOSS4H
I Rt.AGENT lANf:
fAIR IAWN. NJ 0/41U
201 196 /IUO
ACCT I 022ti'JS-OI
CU N01 A242SOO
NH'[AN. ONIA/UO
l(]l-116
bll llb !11114
AUIIIOfUlt.U tl'.,lltll :iCltNl1/1C. INC
PAG(: it
PO MtiR: 11192.0200
CREATION OATf 11/30/94 HlVISION DAit. Ul/14,!.J
Al)(llll(JNA.l INtOIIMATION
IIIIS INtORMATION IS U(llEVtO TO U[ ACCUHA1I:. AN/l Htl-'IH St NI::, 1111 Ill :,1
INtOHMATION CURHfNTIY AVAllABlf TO US 110WEVtH. Wl MAf.f NO \N,\HIIANI, Ill
MERCHANIABllll"I' OH ANY OlltlR WARHAN1"1'. l:'ll.t'Hf:iS OH IMl-'lltll WIIII Ill Sl'I I.I \II
SUCH INJORMATION. ANO Wl ASSUME NO IIABILIT"!' HfSUI IIN(; IH(JM HS usr u:.1 us
SIIOUIO MAH lilflH OWN INVESTIGAIIONS 10 OfrtHMIN[ llll SIJIIAtiU 11'1 01 llll
lNtORMAIION JOH lltflH PARIICUtAH l-'UHf>OSES
--
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MATERIAL SAFETY DATA SHEET
lOE.N TI rt' (Al Ul<!Q on L..A.l)dJ U1d LJs{J
HYOROSEP
HOI-.; 81.&JtA ap,aC.,,J. ..,,, ~ pcimltl«J. 11 •rir lf<l'ffl U ,_ ~Ool.t. o, no
a'lfomwJlon ts itr~ U.. •~ nw:A 0. ~ Ml hd<-.1" ~l
Section I
M.&n.ul.ac11.1rcr\ N.un,e ENCON SAFETY PRODUCTS
Addius {Numbo( SLteel. Gt,: SJ.11~ u,d ZJP G.od.eJ 6825 W. SAM HOUSTON PARKWAY N.
HOUSTON, TX 77041
USA
Section 11-Haz.ardous lngredienls/ldenlity lnformaUon
Emergency ldcphonc Numbct 71~-•~i;_,,,n
T.lephonc Hufflbct lo, Lnlomution 7,~_,1i;i;_,,,10
0.alc Prap~ed 01-01-91
Slgn.atutc ol Prep.arc, (aptiotul}
GABE HAZIE
t-uurdoi.n ~Ls ~lie Ov:mial lde.nllty;. Cottvnon N.ame(sl) OSH.A. PEJ.. ACGlHTLV
NONE
l, l' HEXAMEnrlLENE BIS-(5-(4-CHLOROPHENYL) BICUANIDE
DICLUCONAT'E C!!LORHEXIDINE GLUCONAT'E
Section Ill -Physical/Chemical CI\Macleristics
°°''1 n."''
\'.apor Pr.uure (nvn Hg.J N/A
V~ ?!Alty (AIR a 1) NA
Sol.ubfhlJ In V'l.alcr SOLUABLE
Appu,anc. &n4 0dot WATER LIKE
-Ion IV -Are and Explosion Hazard Oa 1..1
flu• Point IM•UIOd us.oi ) 200°F
&.tinguu.hing MOOG
N/A
s.p;aii Fite FigNlnQ Pfocodwru
N/A
~ Fite .llld up1os4on K&z.atds
N/A
SpecWc G,.a.,ly (H•O i:a 1) (1.01
Melling Poinl N/A
Ev&OOJ&tion A.Me
(Bulyf AUU.le • IJ
Fl.alnm.a.bM: LirnaU
N/A
AS H20
ou-.c, Limits
~ •;. {option.at}
.
ill N/A
...
UEl.
N/A
s:,:.. .. ,:, l...'r.:1~:o
Si.iO!o
lnco,-r:~ .. c,l,!y (M~t"n~,s 1u ,,..-o,.JJ
tiONE
~~•OOU'S
?o,T'"""r\l..lllon
µ Jy 0--...:-.r
'nill NO\ Cc.cul
Section VI -Health Haurd Data
Aoute(S)OI E.nuy: 1nn.u.ahon7
N/A
Hulin. Hu.itds (.A.cu/fl/ 4n4 Cnron,cJ NONE
C-Mcinog«\tcily: HTPl NO
S.ons ancl Symptoms ot €.ADoS1.1re
X
X
Co.-,<jll!O<IS 10 A.,old STORAGE OVER
ConddoOnS IO A"'°'4
NONE KNOWN
:.U.7
N A
) 7 °C
tnce.sliion7
N A
SKIN AND EYE IRRITANT \ll!EN EXPOSED TO CONCENTRATED DOSAGES ONLY
Me(l,c.al Conditions
Cene<ally AQon.vated by 000:wte: DERMATITIS
E.me-,g,ency An.cl F1n;1 Ard Ptoc:ieoaures
FLUSH WITH WATER
Section VII -Prac.autions for Safe Hanrlli~ ar.d U;e
Slc,ISiOB. T.aken in C.U.. Maten.al is Relc.a..s,.e,d o, Sp4&led FLUSH,WITH WATER
wu,. O•S{)OS.al Me1noo
FLUSH WITH WATER
PT«Juhons to Be TAken kl l"UrldlinQ M¥1 Stewing
DO NOT SPILL ON SKIN OR INTO EYES/EARS
Othel Prec.,,utio-,s
Section VIII -Control Measures
Raspuatocy Protec1ion (Sp«Jly Typ,.J
v.nUUhon l.cc.&j E,;tw.,sl
'OK
Prote<:th-9 ~s
YES
Otl\el Prc1ec1..,,. Oou·u~ Of £Qu1p,n,anl
NOT NEEDED
\'\10(11.J Hro•enic Pt-&c1iccs
NORMAL CARE IN HANDLING
OU>et
NIA
I Eye ProtectlOtl
CHEMICAL COCCLES
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* * * * * * * * * * * * * * * * * * * * * * * * * * • * * * * * *
M S D S •
*
•
• • Canadian Centre for Occupational Health and Safety •
* •• * • * * * * * * * * * * * * * * * * * * * * * * * * * * * *
RECORD NUMBER
LANGUAGE
PRODUCT NAME(S)
DATE OF MSDS
MANUFACTURER
ADDRESS
*** IDENTIFICATION***
480574
ENGLISH
Portland Cement Concrete
1991-03
*** MANUFACTURER INFORMATION***
RED-D-MIX CONCRETE
***
Post Office Box 65, Station B
Hamilton Ontario
Canada L8L· 7Vl
Telephone: [phone]
MATERIAL SAFETY DATA***
MATERIAL SAFETY DATA SHEET
( MSDS) ------------------------------------------------------------------------------·~cTION I -MATERIAL IDENTIFICATION AND USE ----------------------------------------------------------------------------..• dterial Name:
Chemical Name:
Portland Cement Concrete
Not applicable
Portland Cement Product Chemical Family:
Chemical Formula:
Trade Name & Synonyms:
Mixture cementitious material, aggregates and water
Ready mixed concrete; concrete
Molecular Weight: Not applicable
Material Use: Construction materials
------------------------------------------------------------------------------
SECTION II -HAZARDOUS INGREDIENTS OF MATERIAL ------------------------------------------------------------------------------Concrete is a mixture of inert gravel or rock, sand, Portland Cement and
water. It may also contain chemical admixtures and/or flyash and/or
granulated slag and/or silica fume, which have no effect on the hazards
associated with the use of the product. The chemical admixtures are present
in quantities comprising less than 1% of the material.
Hazardous Ingredients
Portland Cement (CAS 65997-15-1)
Quartz (SiO2) (CAS 14808-60-7)
Portlandite (Ca(OH)2) (CAS 1305-62-0)
10 -20
3 -7
2 -4
The hazardous ingredients in plastic (wet) concrete cannot become airborn.
·~wever, water added to the materials reacts with some of the ingredients
,rm calcium hydroxide, a corrosive chemical which will irritate the eyes
skin upon contact. Concrete dust from dried Portland Cement Concrete may
contain hazardous ingredients in sufficient concentrations to cause skin,
to
and
also
eye,
I
or_respiratory_irritation. ___________________________________________________ 1 SECTION III -PHYSICAL DATA FOR MATERIAL
sical State: Plastic until it becomes ;~lid-:~~~-;;~~i~;--------------·1
Guour and Appearance: Odourless, grey, plastic, flowable and granular
Odour Threshold: None
Specific Gravity: Normal range 1.5 to 2.9
Vapour Pressure: Not applicable
Vapour ,Density: Not applicable I
Evaporation Rate: Not applicable
Boiling Point: Not applicable
Freezing Point: (0 deg. C} I
Solubility in Water: 0.1%
pH: pH12 -pH13 I ------------------------------------------------------------------------------SECTION IV -FIRE AND EXPLOSION HAZARD OF MATERIAL -----------------------------------------------------------------------------1
Not applicable _
----------------------------------------------------------------------------, SECTION V -REACTIVITY DATA ------------------------------------------------------------------------------Not applicable I ------------------------------------------------------------------------------SECTION VI -TOXICOLOGICAL PROPERTIES OF MATERIAL
-)--Plastic-Concrete-------------------------------------------------------, 8
Toxicological Properties I
Plastic concrete has an alkalinity level of pH12 to pH13 which can cause
skin and eye irritation. 1 Route of Entry: Skin contact, eye contact, ingestion
Effects of Acute Exposure: Plastic concrete can cause alkali burns and
eye irritations and burns. Ingestion may I
cause irritation of the throat.
Effects of Chronic Exposure: Damage to the epidermis and dermis (outer
layers of skin}
( b} Hardened or "Set" Concrete
Sawing or other demolition techniques may result in exposure to dust which
contain hazardous ingredients of the constituent products as follows:
(i} Portland Cement and Portlandite
Toxicological Properties:
I
The hazardous ingredients when in contact with water,
hydroxide, with an alkalinity level of pH12 to pH13.
,n cause skin and eye irritation.
produce calcium ' This level of alkalinit
Route of Entry: I
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Skin contact, eye contact, inhalation, ingestion.
-ffects of Acute Exposure
01ent and wet cement mixtures can cry skin, cause alkali burns and irritate
__ ,e eyes and the upper respiratory tract. Ingestion can cause inflammation of
the throat.
Effects of Chronic Exposure:
.
Cement dust.can cause inflammation of the tissue lining, the interior of the
nose and the cornea (white) of the eye. Hyper-sensitive people may develop
allergic dermatitis.
Exposure Limits:
O. Reg. 654/86 (8hr TWAEV)* ........ 10 mg/m3 (total dust)
ACGIH (TLV-8hr TWA) ................ 10 mg/m3 (total dust)
MSHA ( 8hr -TWA) ................... 50 mppcf**
OSHA (PEL 8hr TWA) .............. : .. 50 mppcf
I * Time Weighted Average Exposure Value (for 8hr day -40hr week)
** Million particles per cubic foot
Portland Cement and Portlandite are not known to constitute a carcinogenic,
reproductive, teratogenic, or mutagenic hazards.
I ii) Quartz (Si02)
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nuute of Entry:
Skin contact, eye contact, inhalation chronic.
Effects of Acute Exposure:
Exposure to dust may irritate respiratory system, eyes and skin.
Effects of Chronic Exposure:
( l )
( 2 )
Chronic exposure to respirable dust at levels exceeding exposure limits
has caused pneunoconiosis.
Chronic exposure to respirable sand and gravel dust containing quartz at
levels exceeding exposure limits has caused silicosis, a serious and
progressive pnewnoconiosis which can be disabling, and in extreme
instances, lead to death. Symptoms may appear at any time, even years
after exposure has ceased. Symptoms of silicosis may include shortness
of breath, difficulty in breathing, coughing, diminished work capacity,
diminished chest expansion, reduction of lung volume and right heart
enlargement and/or failure. The only reliable method of detecting
silicosis is through a chest X-ray. Silicosis may aggravate other
chronic pulmonary conditions and may increase the risk of pulmonary
tuberculosis infection. Smoking aggravates the effects of silica
exposure.
LOSO of Material (Species and Route):
LC50 of Material (Species and Route):
Not applicable
Not applicable
I
Exposure Limits: I
Respirable silica dust -0.2 mg/metre3 (TWAEV) "AEV -Time Weighted Average Exposure Values I .r additional information on the above exposure limits, consult Ontario Regulations 654/86 and 769/83, amended 23/87.
Irritancy of Material: I
Respira~ory system, eyes, skin.
Carcinogenicity, Reproductive Effects, Teratogenicity, Mutagenicity: I
I As of the date of preparation of this MSDS:
( 1 ) Sand and gravel is not included on the ACGIH, IARC, NTP or OSHA lists potential carcinogens. of
I (2) Silica, in the form of crystalline Quartz and as a component of this material; is listed as a potential carcinogen by IARC, but not by ACGIHD NTP or OSHA. IARC (International Agency for Research on Cancer) has determined that there is sufficient evidence of carcinogenicity of crystalline silica to experimental animals, and that there is limited evidence of the carcinogenicity to humans. Limited evidence of I carcinogenicity indicates that causal interpretation is credible, but alternate explanations such as chance, bias or confounding factors could not adequately be excluded. There is no evidence that sand and gravel,-a teratogen, mutagen or has a reproductive effect. · -------------------------------------------------------------------------· "CTION VII -PREVENTATIVE MEASURES ---------------------------------------~-----------------------------------, Personal Equipment: Use gloves, boots and clothing to prevent
Engineering Controls (specify):
Leak and Spill Procedure:
Waste Disposal:
Handling Procedures and Equipment:
Storage Requirements:
Special Shipping Information:
skin contact. Wear safety glasses or
goggles to prevent contact with eyes. Wei an approved respirator if exposed to dust from hardened concrete when sawing or using other demolition methods. · Provide ventilation when sawing or using I other demolition techniques to maintain dust concentrations below exposure limits listed in Section VI. I Sweep and shovel into waste disposal containers. Flush with water hose for final clean-up of floors, walkways, etc. J At approved landfill or waste disposal sites in accordance with local regulation . As above.
Not applicable
Not applicable I
----------------------------------------------------------------------------1
SECTION VIII -FIRST AID MEASURES ------------------------------------------------------------------------------w~sh exposed areas of the body with soap and water; rigate eyes with large amounts of water; ~onsult a physician in cases of severe exposure; In case of accidental ingestion, drink two or three glasses of milk, call a
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physician and do not induce vomiting.
·-----------------------------------------------------------------------------;CTION IX -PREPARATION DATE OF MSDS ----------------------------------------------------------------------------
Prepared by:
Date:
Red-D-Mix Concrete
525 Victoria Avenue North
Hamilton, Ontario
LBL 7Vl
[phone]
March, 1991
.......................................
The information contained on this Material Data Safety Sheet is based on
hazard information from sources considered technically reliable and has been
prepared in good faith in accordance with available information. No warranty,
express or implied, is made and the supplier will not be liable for any
damages, losses, injuries or consequential damages which may result from the
use of or reliance on any information contained herein.
* * * * * * * * * * * * * * * • * * * • * * * * * * * • * * * *· * M S D S
Canadian Centre for Occupational Health and Safety
* * * * * * * * * * ~ * * • * * * * * * * * * * * • * * * * * * ..•
RECORD NUMBER
LANGUAGE
PRODUCT NAME(S)
DATE OF MSDS
MANUFACTURER
ADDRESS
SUPPLIER/DISTRIBUTOR
ADDRESS
-. ***IDENTIFICATION***
399509
ENGLISH
Portland Cement Concrete
1989-03
*** MANUFACTURER INFORMATION***
Perth Concrete Products Limited
Huron Concrete Supply Limited
Post Office Box 700
Stratford Ontario
Canada
*** SUPPLIER INFORMATION***
Perth Concrete Products Limited
Huron Concrete Supply Limited
Post Office Box 700
Stratford Ontario
Canada
*** MATERIAL SAFETY DATA***
MATERIAL SAFETY DATA SHEET
(MSDS) ---------------------------------------------------------------------------
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~~cTION I -MATERIAL IDENTIFICATION AND usE I =-----------------------------------=----=-=============================-=
nctterial Name: Portland Cement Concrete Chemical Name: Not applicable
Chemical Family: Portland Cement Product I Chemical Formula: Mixture cementitious material, aggregates and water
Trade Name & Synonyms:
Molecular Weight:
Material Use:
Ready mixed concrete; concrete
Not applicable
Construction materials I
----------------------------------------------------------------------------, SECTION II -HAZARDOUS INGREDIENTS OF MATERIAL ------------------------------------------------=---=======-===--===--=-======
Concrete is a mixture of inert gravel or rock, sand, Portland Cement and water .. It may also contain chemical admixtures and/or flyash and/or I granulated slag and/or silica fume, which have no effect on the hazards associated with the use of the product. The chemical admixtures are present in quantities comprising less than 1% of the material. I
Hazardous Ingredients %
Portland Cement (CAS 65997-15-1)
Quartz (Si02) (CAS 14808-60-7)
Portlandite (Ca(OH)2) (CAS 1305-62-0)
10 -20
3 -

7

2 -

4

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m~e hazardous ingredients in plastic (wet) concrete cannot become airborn. I wever, water added to the materials reacts with some of the ingredients t~ £Orm calcium hydroxide, a corrosive chemical which will irritate the eyes an' skin upon contact. Concrete dust from dried Portland Cement Concrete may al contain hazardous ingredients in sufficient concentrations to cause skin, ey, or respiratory irritation. · ;~~;~;~-~~~-=-~~;;~~~-~~;~-;;~-~;~~~~------------------------------------1
Physical State:
Odour and Appearance:
Odour Threshold:
Specific Gravity:
Vapour Pressure:
Vapour Density:
Evaporation Rate:
Boiling Point:
Freezing Point:
Solubility in Water:
pH:
Plastic until it
Odourless, grey,
granular
None
Normal range 1.5
Not applicable
Not applicable
becomes solid upon setti1
plastic, flowable and
to 2.9 I
Not applicable I Not applicable
(0 deg C)
pH12 -pH13 0.1, I
----------------------------------------------------------------------------SECTION IV -FIRE ANO EXPLOSION HAZARD OF MATERIAL = =========================================================================-1
Not applicable ------------------------------------------------------------------------------,CTION V -REACTIVITY DATA I ~====================================================-=====---------------
Not applicable -----------------------------------------------------------------------------.
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SECTION VI -TOXICOLOGICAL PROPERTIES OF MATERIAL
Ja) Plastic Concrete
Toxicological Properties
(b)
Plastic concrete has an alkalinity level of pH12 to pH13 which can cause
skin and eye irritation.
Route of Entry:
Effects of Acute Exposure:
Effects of Chronic Exposure:
Hardened or ''Set" Concrete
Skin contact, eye contact, ingestion
Plastic concrete can cause alkali burns and
eye irritations and burns. Ingestion may
cause irritation of the throat.
Damage to the epidermis and dermis (outer
layers of skin)
Sawing or other demolition techniques may result in exposure to dust
which may contain hazardous ingredients of the constituent products as
follows:
(i) Portland Cement and Portlandite
. Toxicological Properties:
The hazardous ingredients when in contact with water, produce calcium
hydroxide, with an alkalinity level of pH12 to pH13. This level of
alkalinity can cause skin and eye irritation.
Route of Entry: .,.--------------
Skin contact, eye contact, inhalation, i~gestion~
Effects of Acute Exposure:
Cement and wet cement mixtures can dry skin, cause alkali burns and
irritate the eyes and the upper respiratory tract. Ingestion can cause
inflammation of the throat.
Effect of Chronic Exposure:
Cement dust can cause inflammation of the tissue lining, the interior of
the nose and the cornea (white) of the eye. Hyper-sensitive people may
develop allergic dermatitis.
Exposure Limits:
0. Reg. 654/86 (8hr TWAEV)*
ACGIH (TLV-Bhr TWA)
MSHA (8hr -TWA) ..
OSHA (PEL 8hr TWA).
*
**
Time Weighted Average Exposure Value
(for 8hr day -40hr week)
Million particles per cubic foot
.10 mg/m3 (total dust)
.10 mg/m3 (total dust)
.50 mppcf**
.50 mppcf
Portland Cement and Portlandite are not known to constitute a carcinogenic, reproductive, teratogenic, or mutagenic hazards.
( ii) Quartz (SiO2)
Route of Entry:
Skin contact, eye contact, inhalation chronic.
Effects of Acute Exposure:
Exposure to dust may irritate respiratory system, eyes and skin.
Effect of Chronic Exposure:
(1) Chronic exposure to respirable dust at levels exceeding exposure limits has caused pneumoconiosis.
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( 2 ) Chronic exposure to respirable sand and gravel dust containing I quartz at levels exceeding exposure limits has caused silicosis, a serious and progressive pneumoconiosis which can be disabling, andll in extreme instances, lead to death. Symptoms may appear at any II time, even years after exposure has ceased. Symptoms of silicosis may include shortness of breath, difficulty in breathing, coughing diminished work capacity, diminished chest expansion, reduction ofl lung volume and right heart enlargement and/or failure. The only reliable method of detecting silicosis is through a chest x-ray. Silicosis may aggravate other chronic pulmonary conditions and mayl increase the risk of pulmonary tuberculosis infection. Smoking aggravates the effects of silica exposure.
LOSO of Material (Species and Route):
LCS0 of Material (Species and Route):
Exposure Limits:
Not applicable
Not applicable I
I Respirable silica dust -0.2 mg/metre3 (TWAEV) TWAEV -Time Weighted Average Exposure Values For additional information on the above exposure Regulations 654/86 and 769/83, amended 23/87.
limits, consult Ontaricl
Irritancy of Material: I Respiratory system, eyes, skin.
Carcinogenicity, Reproductive Effects, Teratogenicity, Mutagenicity: I ---------------

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As of the date of preparation of this MSDS:
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( 2 )
Sand and gravel is not included on the ACGIH, !ARC, NTP or OSHA lists of potential carcinogens.
Silica, in the form of crystalline Quartz and as a component of thJ material, is listed as a potential carcinogen by IARC, but not. by ACGIH, NTP or OSHA. IARC (International Agency for Research on I Cancer) has determined that there is sufficien~ evidence_of carcinogenicity of crystalline silica to experunental animals, and that there is limited evidence of the carcinogenicity to humans. 1
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Limited evidence of carcinogenicity indicates that casual
interpretation is credible, but alternate explanations such as
chance, bias or confounding factors could not adequately be
excluded. There is no evidence that sand and gravel is a teratogen,
mutagen or has a reproductive effect. -----------------------------------------------------------------------------SECTION VII -PREVENTATIVE MEASURES
Personal Equipment:
Engineering Controls (spe~ify):
Leak and Spill Procedure:
Waste Disposal:
Handling Procedures & Equipment:
Storage Requirements:
Special Shipping Information:
Use gloves, boots and clothing to prevent
skin contact. Wear safety glasses or
goggles to prevent contact with eyes. Wear
an approved respirator if exposed to dust
from hardened concrete when sawing or using
other demolition methods.
Provide ventilation when sawing or using
other demolition techniques to maintain
dust concentrations below exposure limits
listed in section VI.
Sweep and shovel into waste disposal
containers. Flush with water hose for
final clean-up of floors, walkways, etc.
At approved landfill or waste disposal
sites in accordance with local regulations.
As above.
Not applicable
Not applicable ------------------------------------------------------------------------------SECTION VIII -FIRST AID MEASURES
sh exposed areas of the body with soap and water;
_i:rigate eyes with large amounts of water;
Consult a physician in cases of .severe exposure;
In case of accidental ingestion, drink two or three glasses of milk,
call i physician and do not induce vomiting. ------------------------------------------------------------------------------SECTION IX -PREPARATION DATE OF MSDS
==============================================================================
Prepared by:
Date:
Ready Mixed Concrete
As~ociation of Ontario
325 Eddystone Avenue
Downsview, Ontario MJN lHB
March 1989
The information contained on this Material Safety Data Sheet is based on
hazard information from sources considered technically reliable and has been
prepared in good faith in accordance with available information. No warranty,
express or implied, is made and the supplier will not be liable for any
damages, losses, injuries or consequential damages which may result from the
use of or reliance on any information contained herein.
* * * * • * • * * * * * • * • •
* * * • * * * * * * * • * * • * • * •
M S D S • •
• • • • Canadian Centre for Occupational Health and Safety
* * • * * * * * • * * * * • * * * * * * * * * * * *
,·.iCORD NUMBER
LANGUAGE
PRODUCT NAME(S)
DATE OF MSDS
MANUFACTURER
ADDRESS
SUPPLIER/DISTRIBUTOR
ADDRESS
••• IDENTIFICATION•••
399505
ENGLISH
Portland Cement Concrete
1989-03
*** MANUFACTURER INFORMATION***
***
Grand Valley Concrete
Post Office Box 204
Oak Park Road
Paris Ontario
Canada
Telephone: [phone]
SUPPLIER INFORMATION***
Grand Valley Concrete
Post Office Box 204
Oak Park Road
Paris Ontario
Canada
Telephone: [phone]
*** MATERIAL SAFETY DATA***
MATERIAL SAFETY DATA SHEET
· (MSDS)
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I ------------------------------------------------------------------------------SECTION I -MATERIAL IDENTIFICATION AND USE II
--.-------------------------------------------------------------------------
Material Name: Portland Cement Concrete
Chemical Name: Not applicable
Chemical Family: Portland Cement Product I
Chemical Formula: Mixture cementitious material, aggregates and
Trade Name & Synonyms:
Molecular Weight:
Material Use:
water
Ready mixed concrete; concrete
Not applicable
Construction materials I
----------------------------------------------------------------------------. SECTION II -HAZARDOUS INGREDIENTS OF MATERIAL
=--=========================================================================--
Concrete is a mixture of inert gravel or rock, sand, Portland Cement and
water. It may also contain chemical admixtures and/or flyash and/or I
granulated slag and/or.silica fume, which have no effect on the hazards
associated with the use of the product. The chemical admixtures are present
in quantities comprising less than 1% of the material. I
Hazardous Ingredients %
----------------------Portland Cement (CAS 65997-15-1)
Quartz (Si02) (CAS 14808-60-7)
Portlandite (Ca(OH)2) (CAS 1305-62-0)
10 -20
3 - 7
2 - 4
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The hazardous ingredients in plastic (wet) concrete cannot become airborn.
4owever, water added to the materials reacts with some of the ingredients to
·rm calcium hydroxide, a corrosive chemical which will irritate the eyes and
en upon contact. Concrete dust from dried Portland Cement Concrete may also
.,ntain hazardous ingredients in sufficient concentrations to cause skin, eye,
or respiratory irritation. ------------------------------------------------------------------------------SECTION III -PHYSICAL DATA FOR MATERIAL
Physical St~te:
Odour and Appearance:
Odour Threshold:
Specific Gravity:
Vapour.Pressure:
Vapour Density:
Evaporation Rate:
Boiling Point:
Freezing Point:
Solubility in Water:
pH:
Plastic until it becomes solid upon setting
Odourless, grey, plastic, flowable and
granular
None
Normal range 1.5 to 2.9
Not applicable
Not applicable
Not applicable
Not applicable
(0 deg C)
0.1%
pHl2 -pHl3 ------------------------------------------------------------------------------SECTION IV -FIRE AND EXPLOSION HAZARD OF MATERIAL
=======-============----------------------====--============================-=
Not applicable ------------------------------------------------------------------------------SECTION V -REACTIVITY DATA
t applicable -----------------------------------------------------------------------------SECTION VI -TOXICOLOGICAL PROPERTIES OF MATERIAL --=-----------======--------------------=====----=-====== ... ·===· ====·=-----==
(a) Plastic Concrete
Toxicological Properties
( b)
Plastic concrete has an alkalinity level of pH12 to pH13 which can cause
skin and eye irritation.
Route of Entry:
Effects of Acute Exposure:
Effects of Chronic Exposure:
Hardened or "'Set"' Concrete
Skin contact, eye contact, ingestion
Plastic concrete can cause alkali burns and
eye irritations and burns. Ingestion may
cause irritation of the throat.
Damage to the epidermis and dermis (outer
layers of skin)
Sawing or other demolition techniques may result in exposure to dust
which may contain hazardous ingredients of the constituent products as
follows:
(i) Portland Cement and Portlandite
Toxicological Properties:
The hazardous ingredients when in contact with water, produce calcium
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hydroxide, with an alkalinity lev'i'l ,of pJ-!12 to pH13. This level of I alkalinity can cause skin and eye irri.tation.
Route of Entry:
Skin contact, eye contact, inh~lation:~ ingestio~.
Effects of Acute Exposure:
I
I Cement and wet cement mixtures can d·ry :skin,. ·cause alkali burns and ~rrjtate the eyes and the upper respir~tory tract. Ingestion can cause. 'inflammation of the throat.
Effect of Chronic Exposure:
Cement dust can cause inflammation of the tissue lining, the the nose and the cornea (white) of the eye. Hyper-sensitive develop allergic dermatitis.
interior ol
people may
Exposure Limits:
Q, Reg. 654/86 (8hr TWAEV)*
ACGIH (TLV-8hr TWA)
MSHA ( 8hr -TWA) . .
OSHA (PEL 8hr TWA),
*
**
Time Weighted Average Exposure Value
(for 8hr day -40hr week)
Million particles per cubic foot
... 10 mg/m3 (total dust)
.~;10 mg/m3 (total dust)
.SQ mppcf**
. . 50 mppcf
Portland Cement and Portlandite are not known to constitute a carcinogenic, reproductive, teratogenic, or mutagenic hazards.
(ii) Quartz (SiO2)
Route of Entry:
skin contact, eye contact, inhalation chronic.
Effects of Acute Exposure:
E,xpo~ure ;,O ·dust may irritate respiratory system, eyes and skin.
Effect of Chronic Exposure:
( 1 ) at levels exceeding exposure
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( 2 )
· ":chronic exposure to respirable dust
limlts has caused pneumoconiosis.
Chronic exposure to respirable sand and gravel dust containing I quartz at levels exceeding exposure limits has caused silicosis, a serious and progressive pneumoconiosis which can be disabling, and I in extreme instances, lead to death. Symptoms may appear at any time, even years after exposure has ceased. Symptoms of silicosis may include shortness of breath, difficulty in breathing, coughin~ diminished work capacity, diminished chest expansion, reduction c I lung volume and right heart enlargement and/or failure. The only reliable method of detecting silicosis is through a chest x-ray.
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Silicosis may aggravate other chronic pulmonary conditions and may
increase the risk of pulmOnary tuberculosis infection. Smoking
aggravates the effects Of silica exposure.
LOSO of Material (Species and Route): Not applicable
Not applicable LCSO of Material (Specie~ and Route):
.· ,.I --'
Exposure Limits:
Respirable silica dust -0.2 mg/metre) (TWAEV)
TWAEV -'Time Weighted Average Exposure Values
For additional information on.the above exposure
Regulations 654/86 and 769/83, amended 23/87.
limits, consul~Ohtario
Irritancy of Material:
Respiratory system, eyes, skin.
Carcinogenicity, Reproductive Effects, Teratogenicity, Mutagenicity: --------------------------------------------------------------------As of the date of preparation of this MSDS:
( 1) Sand and gravel;.:is not included on the ACGIH, IARC, NTP or OSHA
lists of potential carcinogens.
(2) Silica, in the form of crystalline Quartz and as a component of this
material, is listed as a potential carcinogen by IARC, but not by
ACGIH, NTP or OSHA. IARC (International Agency for Research on ·
Cancer) has determined that there is sufficient evidence of
carcinogenicity of crystalline silica to experimental animals, and
that there is limited evidence of the carcinogenicity to humans.
Limited evidence of carcinogenicity indicates that casual
interpretation is credible, but alternate explanations such as
chance, bias or confounding factors could not adequately be
excluded. There is no evidence that sand and gravel is a teratogen,
mutagen or has a reproductive effect.
------------------------------------------------------------------------------SECTION VII -PREVENTATIVE MEASURES =======---======================---==========-=========================-------
Personal Equipment:
Engineering Controls (specify):
Leak and Spill Procedure:
Waste Disposal:
ndling Procedures & Equipment:
orage Requirements:
Special Shipping Information:
Use gloves, boots and clothing to prevent
skin contact. Wear safety glasses or
goggles to prevent contact with eyes. Wear
an approved respirator if exposed .to dust
from hardened concrete when sawing.or using
other demolition methods. . .,-; ..
Provide ventilation when sawing·or using
other demolition techniques ~9 maintain
dust concentrations below e~posure limits
listed in section VI. -
Sweep and shovel into waste disposal
containers. Flush with water hose for
final clean-up of floors, walkways, etc.
At approved landfill or waste disposal
sites in accordance with local regulations.
As above.
Not applicable
Not applicable
------------------------------------------------------------------------------
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SECTION VIII -FIRST AID MEASURES. .·
w::~=::;~s=~=~~eas ~;=~~== b~di =::th ==~~p ~nci<~:~:;;. = ============== =====-==t Irrigate eyes·•··wit_h large amounts of Wi!.ter; . , . . ·nsul t a _physician in cases _of severe expos,ure ;: I case of a<;:_~Ig:1p11tal ingestion, driryk two or three glasses of milk, call a phys"iciah and do not induce vomiting .. .
SECTI~N 1{;::j iR~PJ\RATION = DATE gF = MSD;> • === ... === _, -=' == ===============-==)
P repat-~9.J,f'i .>:._L;. ~~ady i1ixec(c~d6'i:et:e -, ,,,J,e·,,:,-:.,... Associat'io·n · of ·ontario I
325 Edcty~\one. "Avenue·
Downsview·; Ontil'rio .: MJN lHB
March '1989 '" I
The information contained on this Material safety .-iJata Sheet is based on ha.:iar_,~ .Ciitti'Fn,iftion from sources con~idered tec'hnic:aJly reliable and has been I prepareq_ in'•·good faith in accordance with avaiJ,,a9le ·information. No warrant;,1111 expre~s or ~mplied, is made and the supplier wi1_\t .1!ot be liable for any darnaiJ.es,-: losses, injuries or consequential damagei(:·which may result from the I use c,.f ~!' reliance on any information contained ·.heiei'n . ..... ,.
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EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A419
Ram Leather Site
Appendix 4
Safety Meeting Checklist
Ram Leather Site
048369.0121 63
Health & Safety Plan
Revision No. 0
December I 0, 2004
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EPA Contract No.: 68-W99-043 Health & Safety Plan
Revision No. 0
December 10, 2004
Work Assignment No.: 369-RDRD-A419
Ram Leather Site
Ram Leather Site
Safety Meeting Checklist
Site Safety Coordinator
Attendee Initials
Date
SSC Initials
Review Immediate and Pertinent Work Plans
Collect Current Medical Monitoring Certificates
Collect Current Respirator Fit Test Record
Collect Current Training Certificates
Hazardous Waste Operations 40 hr (OSHA 1910.120)
Hazardous Waste Operations Refresher (OSHA 1910.120)
Hazardous Waste Operations Supervisor (OSHA 1910.120)
Confined Space Entry
Air Supplied Respirators
Monitoring Equipment ( other than Black & Veatch supplied)
First Aid/CPR
Other
Review Standing Safety Orders
Review personal protective equipment requirements
Review Emergency Action Plan
Anticipated emergency response discussed
Identify First Aid/CPR Trained Personnel to Team Members
Personnel trained to respond identified to team
Review Evacuation and Rally Procedures with Team Members
Conduct Chemical Hazard Training for Team Members
Detection Methods
Protective Measures
Location of MSDS
Labeling System used onsite
Signs/Symptoms of Overexposure
Review Communication Systems with Team Members
Internal System
048369.012 1 64
EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A419
Ram Leather Site
Ram Leather Site
Safety Meeting Checklist ( continued)
External System
Review Changes to HASP
Point Out Postings
Emergency Phone List
OSHA Poster
Subcontractor Safety
MSDS Submitted to Black & Veatch SSC
Emergency equipment
Hospital Emergency Route\Map
HASP
Reference materials
Note: Ifan item is not applicable, insert "NIA".
Health & Safety Plan
Revision No. 0
December I 0, 2004
Safety briefings are to be held prior to initiating any site activity an at such times as
necessary to ensure that employees are apprized of the site safety plan and that the plan
is followed.
048369.012 I 65
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EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A419
Ram Leather Site
Appendix 5
Medical Monitoring Examination Elements
Ram Leather Site
048369.0121 66
Health & Safety Plan
Revision No. 0
December I 0, 2004
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EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A419
Ram Leather Site
Medical Monitoring Examination Elements
Baseline
Medical History
Respirator User Assessment
Assessment for Hazardous Waste Worker
Physical Examination
Electrocardiogram (EKG)
Pulmonary function test
Chest X-ray
Audiometry
Vision Screen
·stool Occult Blood
Urinanalysis
Hematology
Blood Chemistry
Coagulation
Physician discretion exams
Biannual
Exit
Baseline minus the X-ray
Physician discretion exams
Baseline minus EKG and respirator user assessment
Physician discretion exams
Physician Discretion exams
Annual chest X-ray
Tetanus booster
Serum PCB levels
RBC Cholinesterase
Plasma Cholinesterase
Stress EKG
24 hr Dioxin in urine
Heavy metals in urine
048369.0 I 21 67
Health & Safety Plan
Revision No. 0
December l 0, 2004
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EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A419
Ram Leather Site
Appendix 6
Monitoring Equipment Action Levels
Ram Leather Site
048369.0121 68
Health & Safety Plan
Revision No. 0
December I 0, 2004
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EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A419
Ram Leather Site
I lnstrnment
0 2 Meter
( measure at source for
Lower Explosive Limit [LEL]
Meter, in breathing sane for
PPE)
LEL Meter
( measure at source)
Organic Vapor Analyzer
(OVA)
(Photoionization Detector
[PID] or Flame-Ionization
Detector [FID])
( measure in breathing zone)
Dust Meter
048369.0121
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Monitoring Equipment
Action Levels
Reading
Less than 19.5% 0 2•
Greater than 23% 0 2•
Up to 5% LEL.
5-10% LEL.
Greater than I 0% LEL
Background.
Up to 5 ppm above
background.
Greater than 5 ppm above
background.
< 2 milligrams per cubic
meter ( mg/m3l.
> 2 mg/m3•
69
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Health & Safety Plan
Revision No. 0
December I 0, 2004
Action I
Withdraw. Ventilate with
fresh air. Explosimeter
readings not valid if 0 2
<10%.
Withdraw. Explosion hazard.
Consult with Black & Veatch
HSM.
Continue activities.
Continue. ID source.
Withdraw. Explosion hazard.
Consult with Black & Veatch
HSM.
Level D
Level C
Withdraw. Consult with
Black & Veatch HSM.
Level D
Level C. Fullface respirator
with PI00 filters.
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EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A419
Ram Leather Site
048369.0121
Appendix 7
Decontamination Methods
Ram Leather Site
70
Health & Safety Plan
Revision No. 0
December I 0, 2004
---.. ..
EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A4l9
Ram Leather Site
Method• Surface
Soap and water Skin and
hands
Lava soap, soft brush, Skin and
and water hands
Tide or other Skin and
detergent (plain) hands
Mixture of 50% Tide Skin and
and 50% cornmeal hands
48369.0121
..
Action
Emulsifies and
dissolves
contaminant
Emulsifies,
dissolves, and
erodes
Emulsifies,
dissolves, and
erodes
Emulsifies,
dis_solves, and
erodes
,. -- -
Personnel Decontamination
Technique
Wash 2-3 minutes and
monitor. Do not wash more
than 3-4 times.
Use light pressure with heavy
lather. Wash for 2 minutes, 3
times. Rinse and monitor.
Use care not to scratch or
erode the skin. Apply lanolin
or hand cream to prevent
chapping.
Make into a paste. Use with
additional water with a mild
scrubbing action. Use care
not to erode the skin.
Make into a paste. Use with
additional water with a mild
scrubbing action. Use care
not to erode the skin.
71
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Advantages
Readily available and
effective for most
contamination.
Readily available and
effective for most
contamination.
Slightly more effective
than washing with soap.
Slightly more effective
than washing with soap.
- --
Health & Safety Plan
Revision No. 0
December l 0, 2004
Disadvantages
Continued washing
will defat the skin.
Indiscriminate
washing of other than
affected parts may
spread contamination.
Continued washing
will abrade the skin.
Will defat and abrade
skin and must be used
with care.
Will defat and abrade
skin and must be used
with care.
--
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EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A419
Ram Leather Site
Method• Surface
Vacuum cleaning Dry surfaces
Water All nonporous
surfaces
(metal,
painted,
plastic, etc.)
All surfaces
48369.0121 ---

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Area and Material Decontamination
Action Technique Advantages
Removes Use conventional vacuum Good on dry, porous
contaminated technique with efficient filter. surfaces. A voids water
dust by suction reactions.
Dissolves and For large surfaces. Hose with All water equipment may
erodes high pressure water at an be utilized. Allows
optimum distance of 15 to 20 operation to be carried
feet. Spray vertical surfaces at out from a distance.
an angle of incidence of 30° Contamination may be
to 40°; work from top to reduced by 50%. Water
bottom to avoid equipment may be used
decontamination. Work for solutions of other
upwind to avoid spray. decontaminating agents.
Determine cleaning rate
experimentally, if possible;
otherwise, use a rate of 4
square feet per minute.
Dissolves and For small surfaces. Blot up Extremely effective if
erodes liquid and handwipe with done immediately after
water and appropriate spill and on non-porous
commercial detergent. surfaces.
-... -72 -----
Health & Safety Plan
Revision No. 0
December I 0, 2004
Disadvantages
All dust must be
filtered out of exhaust.
Machine is
contaminated.
Drainage must be
controlled. Not
suitable for porous
materials. Oiled
surfaces cannot be
decontaminated. Not
applicable on dry
contaminated surfaces
(use vacuum); not
applicable on porous
surfaces such as wood,
concrete, canvas, etc.
Spray will be
contaminated.
Oflittle value in the
decontamination of
large areas,
longstanding
contaminants and
norous surfaces.
-iliiiil
---1111
EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A4 l 9
Ram Leather Site
Method* Surface
Steam Nonporous
surfaces
( especially
painted or
oiled surfaces)
Detergents Nonporous
surfaces
(metal,
painted, glass,
plastic, etc.)
48369.0121
--lilil -·--- ---
Area and Material Decontamination
Action Technique
Dissolves and Work from top to bottom and
erodes from upwind. Clean surface at
a rate of 4 square feet per
minute. The cleaning
efficiency of stream will be
greatly increased by using
detergent.
Emulsifies Rub surface I minute with a
contaminant rag moistened with detergent
and increases solution then wipe with dry
wetting power rag; use clean surface of the
of water and rag for each application. Use
efficiency of a power rotary brush with
steam pressure feed for more
efficient cleaning. Apply
solution from a distance with
pressure proportioned. -'Do not
allow solution to drip onto
other surface. Mist
application is all that is
necessary.
73
Advantages
Contamination may be
reduced approximately
90% on painted surfaces.
Dissolve industrial film
and other materials which
hold contamination.
Contamination may he
reduced by 90%.
Health & Safety Plan
Revision No. 0
December 10, 2004
Disadvantages
Stream subject to same
limitations as water.
Spray hazard makes
the wearing of
waterproof outfits
necessary.
May require personal
contact with surface.
May not he efficient
on longstanding
contamination.
--
-
EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A419 Ram Leather Site
Method* Surface
Complexing agents Nonporous
surfaces
(especially
unweathered
surfaces; i.e.,
po rust or
calcerous
growth)
Organic solvents Nonporous
sutfaces
(greasy or
waxed
surfaces, paint
or plastic
finishes, etc.)
48369.012] ---

-
-
Area and Material Decontamination
Action Technique
Forms soluble Complexing agent solution
complexes with should contain 3% (by
contaminated weight) of agent. Spray material surface with solution. Keep
surface moist 30 minutes by
spraying with solution
periodically. After 30
minutes, flush material off
with water. Complexing
agents may be used on
vertical and overhead surfaces
by adding chemical foam
(sodium carbonate or
aluminum sulfate).
Dissolves Immerse entire unit in solvent organic or apply by wiping procedure materials (oil, (see Detergents).
paint, etc.)
Advantages
Holds contamination in
solution. Contamination
may be reduced by 75%
in 4 minutes on
unweathered surfaces.
Easily stored; carbonates
and citrates are nontoxic,
noncorrosive.
Quick dissolving action.
Recovery of solvent
possible by distillation.
Health & Safety Plan
Revision No. 0
December l 0, 2004
Disadvantages
Requires application
for 5 to 30 minutes.
Little penetrating
power; of small value
on weathered surfaces.
Requires good
ventilation and fire
precautions. Toxic to
personnel. Material
bulky.
--74
-11111 -------
--
EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A419
Ram Leather Site
Method* Surface
Inorganic acids Metal surfaces
(especially
with porous
deposits; i.e.,
rust or
ca1cerous
growth);
circulatory
pipe systems
Acid mixtures: Nonporous
surfaces
Hydrochloric, ( especially
sulfuric, acetic, citric with porous
acids, acetates, deposits);
citrates circulatory
pipe systems
48369.0121
----- --I!!!!!!! !!!!! l!!!!!!I ==
Area and Material Decontamination
Action Technique
Dissolve Use dip-bath procedure for
porous deposits movable items. Acid should
be kept at a concentration of 1
to 2 normal (9 to 18%
hydrochloric, 3 to 6% sulfuric
acid). Leave on weathered
surfaces for I hour. Flush
surface with water, scrub with
a water-detergent solution,
and rinse. Leave in pipe
circulatory system 2 to 4
hours; flush with plain water,
a water-detergent solution,
then again with plain water.
Dissolves Same as for inorganic acids.
porous deposits A typical mixture consists of
0.1 gal. hydrochloric acid, 0.2
lb. sodium acetate, and I gal.
water.
75
Advantages
Corrosive action on metal
and porous deposits.
Corrosive action may be
moderated by addition of
corrosion inhibitors to
solution.
Contamination may be
reduced by 90"/o in I hour
(unweathered surfaces).
More easily handled than
inorganic acid solution.
Health & Safety Plan
Revision No. 0
December 10, 2004
Disadvantages
Personal hazard. Wear
goggles, rubber boots,
gloves, and aprons.
Good ventilation
required because of
toxicity and explosive
gases. Acid mixtures
should not be heated.
Possibility of
excessive corrosion if
used without
inhibitors. Sulfuric
acid not effective on
calcerous deposits.
Weathered surfaces
may require prolonged
treatment Same safety
precautions as required
for inorganic acids.
-
EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A4 l 9 Ram Leather Site
Method* Surface
Caustics: Painted
surfaces
lye (sodium (horizontal)
hydroxide), calcium
hydroxide, potassium
hydroxide
Trisodium phosphate Painted
surfaces
(vertical,
overhead)
Abrasion Nonporous
surfaces
48369.0121 -

-
---
Area and Material Decontamination
Action
Softens paint
(harsh method)
Softens paint
(mild method)
Removes
surfaces
--
Technique
Allow paint-remover solution
to remain on surface until
paint is softened to the point
where it may be washed off
with water. Remove
remaining paint with long-
handled scrapers. Typical
paint remover solution: 10
gal. water, 4 lb. lye, 6 lb.
boiler compound, 0.75 lb.
cornstarch.
Apply with 10% solution by
rubbing and wiping procedure
(see Detergent).
Use conventional procedures,
such as sanding, filing and
chipping; keep surface damp
to avoid dust hazard.
76 -

-
Advantages
Minimum contact with
contaminated surfaces.
Easily stored.
Contamination may be
reduced to tolerance in
one or two applications.
Contamination may be
reduced to as low a level
as desired.
Health & Safety Plan
Revision No. 0
December 10, 2004
Disadvantages
Personal hazard (will
cause burns). Reaction
slow; thus. it is not
efficient on vertical or
overhead surfaces.
Should not be used on
aluminum or
magnesium.
Destructive effect on
paint. Should not be
used on aluminum or
magnesium.
hnpractical for porous
surfaces because of
penetration by
moisture.
== ms 1!!!111! -
.. ---
EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A419
Ram Leather Site
Method• Surface
Sandblasting Nonporous
Vacuum blasting Porous and
nonporous
surfaces
------!!I!!! I!!!!! ==
Area and Material Decontamination
Action Technique
Removes Keep sand wet to loosen.
surfaces
Removes Hold tool flush to surface to
surfaces; traps prevent escape of
and controls contamination.
contaminated
waste
Advantages
Practical for large surface
areas.
Contaminated waste
ready for disposal. Safety
abrasion method.
Health & Safety Plan
Revision No. 0
December 10, 2004
Disadvantages
Impractical for porous
surfaces because of
penetration by
moisture.
Contamination of
equipment.
Begin with the first listed method and then proceed step by step to the more severe methods, as necessary.
48369.0121 77
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Attachment A
Task 1 Health and Safety Plan
Site Visit
Ram Leather Site
Charlotte, Mecklenburg County, North Carolina
December 10, 2004
Prepared by _____________ _
Darci M. Scherbak, P.E.
(Author)
Reviewed by _____________ _
Nancy Geller, P.E.
(Project Manager)
Approved by _____________ _
Jack Schill, CIH, CSP
(Black & Veatch OHS)
Date: ______ _
Date:
Date: ______ _
Expiration Date: December IO. 2005
The following Task Health and Safety Plan (HASP) is health and safety information specific to the
tasks described within. This Task HASP is an extension of the Site HASP and as such must be used
in conjunction with that document.
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Contents
1.0 Scope of Work . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . A-3
2.0 Site Background . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . A-4
2.1 Task Specific Background . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . A-4
3.0 Hazard Assessment . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . A-5
3.1 Chemical Hazards . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . A-5
3 .2 Physical Hazards . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . A-5
3.2.1 Site Walk-through ........................................... A-5
3.3 Overall Hazard Level . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . A-5
3.4 Personal Protective Equipment (PPE) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . A-5
4.0 Personnel Qualifications . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . A-7
4.1 Training Requirements ............................................... A-7
4.2 Medical Monitoring . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . A-7
5.0 Personal Protective Equipment . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . A-8
6.0 Monitoring Program . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . A-9
7.0 Site Control ........................................................... A-10
8.0 Safety and Emergency Procedures ......................................... A-11
9.0 Emergency Action Plan ............................ .' ..................... A-12
10.0 Team Member Responsibilities .......................................... A-13
I 1.0 Certification . .. . . . .. . . . . . .. . . . . .. . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . . . . A-14
12.0 Record of Changes A-15
Figure
Figure I Site Location Map
Table
Table 3-1 Task I Hazard Analysis
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EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A4l9
Ram Leather Site
1.0 Scope of Work
Task I Health & Safety Plan
Revision No. 0
December I 0, 2004
This Task Health and Safety Plan (HASP) applies to all Black & Veatch Special Projects, Corp.
(BVSPC) personnel that will be conducting the site walk-through visit.
The Black & Veatch field team will consist of the following members:
• Project Manager:
• Project Engineer and Site Safety Coordinator:
A-3
Nancy Geller
Darci Scherbak
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EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A419
Ram Leather Site
2.0 Site Background
Task l Health & Safety Plan
Revision No. 0
December l 0, 2004
The United States Environmental Protection Agency's (EPA's) identification Number for the Ram
Leather Site is NCD058754789. The Site is located at 15100 Albemarle Road (Route 24/27) in a
rural area of eastern Mecklenburg County, North Carolina, just west of the Cabarrus County line.
The site is located at 35' 13' 41" north latitude and 80' 36' 24.50" west longitude. The site is located
approximately four miles from the Charlotte city boundary.
Ram Leather Care restored leather goods and operated as a dry cleaning facility. Chlorinated
hydrocarbon chemicals [primarily tetrachloroethene (PCE) and petroleum hydrocarbons (mineral
spirits)] were used in the cleaning process. The Ram Leather facility operated from 1977 to 1993.
The building was constructed in 1967 and housed a construction business until 1977.
2.1 Task Specific Background
The dry cleaning facility is no longer in operation and the site is currently operating as a weekend
flea market. The site and the surrounding property is illustrated in Figure I. The site is surrounded
by residential property. To the south is a 14-acre privately owned parcel. A small fishing pond is
located on the I 4-acre parcel. To the east is the 8-acre privately owned parcel. To the north is
another privately owned parcel. To the west is the 18-acre privately owned parcel. A gravel road
running southeast from the Ram Leather Care driveway provides access to two residences.
A-4
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EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A419
Ram Leather Site
3.0 Hazard Assessment
3.1 Chemical Hazards
Task I Health & Safety Plan
Revision No. 0
December I 0, 2004
The work to be conducted under this Task HASP is not intrusive, therefore chemical hazards are
considered to be low. Contaminants of concern at the Ram Leather Site are listed in Appendix 2, Table
2-1 of the Site HASP. The table lists the exposure routes, allowable exposure levels for the chemicals,
signs and symptoms of exposure, immediately dangerous to life and health (IDLH) values, and Chemical
Abstracts Service (CAS) registry numbers.
3.2 Physical Hazards
Black & Veatch and their subcontracting personnel present during any of the previous listed activities will
wear modified level D safety equipment including steel toed boots. Potential physical hazards include slip,
trip, and fall hazards associated with an overgrown site. Additional potential physical hazards are
associated with vehicular traffic (for areas located near roadways). Biological hazards include insect bites,
snakes, and other pests associated with the overgrown areas of the site.
3.2.1 Site Walk-through
Physical hazards associated \vith the site walk-through include exposure from surface soil. Walk-through
locations near roadways potentially include vehicular traffic hazards. Walk-through locations near
overgrown brush and woodlands include environmental hazards such as snakes and spiders.
3.3 Overall Hazard Level
During a walk-through, the overall hazard level will be low as risk to contaminant exposure is reduced.
Table 3-1 presents a summaryofthe major hazards associated with primary.iask activitfos.' Appendix 6
of the Site HASP provides requirements for monitoring equipment and action levels.
3.4 Personal Protective Equipment (PPE)
Black & Veatch and its subcontractors will conduct the aforementioned tasks in modified level D, except
as otherwise noted in Table 3-1. If upgrade to Level C PPE is required, see Section 5.2 of the Site
HASP. Efforts will be made to eliminate or reduce physical contact with liquids and solids.
A-5
----------- --I!!!!!! !!!!!
EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A419
Ram Leather Site
Table 3-1
Task 1 Hazard Analysis
Principle Steps Potential Safety
or Health
Hazards
Site walk-through Accidents
visit involving vehicles
along roadways,
snakes in
overgrown areas.
Refer to Sections
3.2.1, 3.2.2, 3.2.3,
and 3.2.4;
exposure to
contaminant
concentrations.
Monitoring
Requirements
Visual Awareness.
A-6
Task 1 Health & Safety Plan
Revision No. 0
December 10, 2004
Action Levels Personal
Protective
EQuioment
No Change. Modified Level D.
Upgrade as
required.
Recommended
Controls
Make noise and
vibrations in
overgrown areas
to warn snakes of
your presence and
wear snake
gaters.
Training
Requirements
No modification.
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EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A419
Ram Leather Site
4.0 Personnel Qualifications
4.1 Training Requirements
Task I Health & Safety Plan
Revision No. 0
December I 0, 2004
Personnel, who will be working onsite at the Site, must present to the Black & Veatch site safety
coordinator (SSC) a certificate of completion of an initial 40-hour hazardous waste operations training
course and, or the most recent certificate of completion for an 8-hour refresher course. The course must
have been completed within the 12 months of the individual being onsite performing hazardous waste
operations. The training must comply with OSHA regulations found at 29 Code of Federal Regulations
(CFR) 1910.120(e). The certification must be presented to the SSC before site activities begin.
All personnel must complete a minimum of three days on-the-job training under the direct supervision
of a qualified SSC or site supervisor before they are qualified to work at a hazardous waste site
unsupervised.
Consistent with OSHA 29 CFR 1910.120 paragraph ( e )( 4), individuals serving in a supervisory role, such
as the field team leader or SSC, requires an additional 8 hours of training. Black & Veatch individuals
functioning in a SSC capacity shall also have at least 6 days of experience at the level of protection
planned for in this HASP. A SSC qualified at a given level of protection is also qualified as a SSC at a
lesser level of protection.
4.2 Medical Monitoring
All Black & Veatch personnel who engage in onsite operations at the Site must present, to the Black &
Veatch SSC, certification of completion, within the 24 months prior to the beginning of site activities,
a comprehensive medical monitoring examination. All subcontractor personnel who engage in hazardous
waste operations must present, to the Black & Veatch SSC, certification of completion, within 12 months
prior to the beginning of site activities, a comprehensive medical examination. The examination must
comply with OSHA regulation found at 29CFR 1910.120 et. seq. The certification must be signed by
a medical doctor and indicate any work limitations placed on the individual. The certification also must
specify that the individual is capable of working while wearing respiratory protective equipment. The
certification must be presented before site activities begin.
A-7
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EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A419
Ram Leather Site
5.0 Personal Protective Equipment
Task 1 Health & Safety Plan
Revision No. 0
December 10, 2004
Personnel protective equipment will be worn for this task as described in Section 3.4.
Please refer to Table 3-1 for task specific monitoring requirements. Information on additional monitoring
equipment requirements and action levels is discussed in Appendix 6 of the Site HASP.
Potential levels of protection and their specific PPE for this site are as follows:
Level D PPE: • • • • • • •
Tyvek for environmental sampling .
Boots, steel toe .
Outer boot covers, chemical-resistant, disposable .
Outer gloves, chemical-resistant ( 11 mil nitrile ) .
lnner gloves, chemical-resistant ( 4 mil nitrile ) .
Hardhat.
Safety glasses with side-shields .
Level D PPE -Modified
• Work clothes.
• Boots, steel toe.
See Section 5.2 of the Site HASP for Level C PPE Requirements.
A-8
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EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A419
Ram Leather Site
6.0 Monitoring Program
No modifications to Section 6.0 of the Site HASP are required.
A-9
Task I Health & Safety Plan
Revision No. 0
December I 0, 2004
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EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A419
Ram Leather Site
7 .0 Site Control
Task I Health & Safety Plan
Revision No. 0
December I 0, 2004
Black & Veatch will limit access of personnel to the work zones through the use of orange cones and
caution flagging to denote potentially hazardous work areas. Work zones, as discussed in the HASP
(Section 7.2), will be established prior to the performance of site activities.
Black & Veatch personnel will use the established hand signals when verbal communication is not
practical. Information on the nearest medical facility route to the facility, and emergency numbers is
included in Appendix 1 the Site HASP. A map depicting the hospital route as well as written directions
is included in the Site HASP.
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EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A419
Ram Leather Site
Task I Health & Safety Plan
Revision No. 0
December I 0, 2004
8.0 Safety and Emergency Procedures
Emergencies will be responded to as discussed in the Site HASP (Section 8.0).
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EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A4 l9
Ram Leather Site
9.0 Emergency Action Plan
Task l Health & Safety Plan
Revision No. 0
December I 0, 2004
The Emergency Action Plan, as discussed in section 9.0 of the Site HASP, will be implemented as
necessary under the guidelines of the Site HASP.
A-12
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EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A419
Ram Leather Site
10.0 Team Member Responsibilities
Task I Health & Safety Plan
Revision No. 0
December IO, 2004
Black & Veatch personnel are responsible for all safety during activities in this Task HASP.
Team members and responsibilities are as follows:
• •
Site Manager: Nancy Geller
Site Safety Coordinator: Darci Scherbak
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EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A4l9
Ram Leather Site
By my signature, I certify that:
11.0 Certification
Ram Leather Site
Certification Record
Task I Health & Safety Plan
Revision No. 0
December I 0, 2004
• I have read, I understand, and I will abide by this Task l Health and Safety Plan for the
Site.
Printed Name Si<mature Date Affiliation
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EPA Contract No.: 68-W99-043
Work Assignment No.: 369-RDRD-A419
Ram Leather Site
12.0 Record of Changes
Task I Health & Safety Plan
Revision No. 0
December I 0, 2004
Changes to this Task HASP must be made on the following form and submitted to the Black & Veatch
Project Manager (PM) and Health and Safety Manager (HSM) for their approval. Field activities related
to the potential for ·exposure to contaminants shall be halted until the Task HASP has been modified to
reflect changed conditions and the Black & Veatch HSM has reviewed or approved the changes. All field
team members who are affected by the changes must initial that they have been apprized of the changes.
REVISION
NUMBER SUBJECT SECTION/PAGE INITIALSffiA TE
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f-i--i+H-ttf-AA!LROAO
Source: DES R■!ilura, Gi,:,up:s, Irie., sur,ey, Augl.i$1: 1 ~. 2002.
Mecklel'l:lutg Co Lano Record3 OIY , anal pt,ctQgr.i~. Jura 2001.
Adap/ttd Jtom: Mecklenburg Co. Land Records Ow., topogaphic attrIb..tos,
cc10ber 2002.
CDM
Site Vicinity Map
Ram Leather Site
Charlotte, North Carolina