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HomeMy WebLinkAboutNCD982096653_19960329_Ram Leather Care Site_FRBCERCLA PA SI_Preliminary Assessment Site Inspection Volume II References 12 - 27-OCR-' ' I I ::_fl , ... i 1·. -1 ( ;,'..9 ,- ,·, ii ·[i g ! ~ :1 I STATE OF NORTH CAROLINA Depanli,ertt of Environment, Health, and Nmural Resources Division of Solid waste Management Superfund Section COMBINED PRELIMINARY ASS!::,"'SSMENTISITE INSPECTION VOLllMEII Ram Leather Care NCD 982 096 653 Charlotte, Mecklenbm·g County Reference No. 06303 March 1996 Jeanette Stanley Environmental Chemist Division of Solid Waste Management Superfund Sel'.tion I I I I I I I I I I I I I I I I I ·I PLANT LOCATIONS Arlington, Va. Asheville, N.C. Boston, Mass. Charlotte, N.C. Columbus, Ga. Detroit, Mich. Ft. Lauderdale, Fla. Jackson, Miss. Jacksonville, Fla Dallas,Tx. Houston, Tx. Mission, Ky. San Antonio, Tx. St. Louis, Mo. Philadelphia, Pa. Nov. 5, 1991 RECEiVED ·~-- SEP 2 6 1995 Ref. 12 SUPERFUND SECTION 15100 ALBEMARLE ROAD • CHARLOTTE, N.C. 28227 PHONE (704) 545-9737 Environmental Health & Natural Resources 59 Woodfin Place Asheville, N. C. 28802 ATTENTION: Spring Allen Dear Miss Allen: Enclosed you will find Bold Labs report of the findings at Ram Leather Care, Inc. Yours truly, ·RAM LEATHER CARE, INC. E/ W~s1'ene ECW:jw Enclosure WE LOVE SUEDE, LEATHER and FUR, and CLEAN IT LOVINGLY m m m m D D u D u D D D D II ANALYTICAL TESTING A CONSUL TING SERVICES P.O. BOX 31486 •CHARLOTTE.NC 28231 • TELEPHONE (704) 527-4183 • FAX: (7041525-0409 TECHNICAL AND FIELD DATA REPORT for Ram Leather Care Charlotte, North Carolina prepared by: BOLD RESEARCH LABS, INC. October 30, 1991 Scott T. Olson / Geology Supervisor reviewed and approved by: 449 SPRINGBROOK ROAD• CHARLOTTE, NC 28217 0 0 : m I D D D I I I I I. II. III. IV. V. VI. VII. VIII. IX. X. TABLE OF CONTENTS Introduction .............................................. . Scope and Purpose Site History Site Setting Topography and Drainage Soils Geology Investigation ............................................. . Borings Monitoring Well Installations Groundwater Sampling Investigation Results .................................... . Conclusion ................................................ . Appendix I -Maps: I. Gener21 Location Map 2. Adjacent Properties Map 3. Site Map Appendix 2 -Figures: I. Groundwater Contour Map Page 1 Page 5 Page 9 Page 11 2. Horizontal Extents of Soil Contamination 3. Horizontal Extent of Upper Aquifer Contamination 4. Horizontal Extent of Lower Aquifer (Bedrock) Contamination 5. Vertical Cross Section A-A' 6. Vertical Cross Section B-B' Appendix 3 -Soil Boring Logs Appendix 4 -W.ell Construction Records Appendix 5 -Tables: 1. Preliminary Water Analyses 2. Groundwater Analyses from Borings and Monitoring Wells 3. Soil Analyses 4. Water Level Measurements 5. Slug Test Appendix 6 -Lab Results illl w m m , m D 0 D D m m • m • I I I I I INTRODUCTION SCOPE Al\'D PURPOSE ML Cliff Worley, of Ram Leather Care, requested Bold Research Labs, Inc. to perform a subsurface investigation of the property located at 15100 Albemarle Road, Charlotte, North Carolina in response to a Notice of Violation received from the North Carolina Division of Environmental Management (NC DEM) on July 3, 1991. (See Appendix I for General Location Map). The investigation was designed to identify a possible source of the chlorinated hydrocarbon contamination, in addition to defining the horizontal and vertical extent of the soil and groundwater contamination. SITE HISTORY Ram Leather Care has been in operation since 1977, dry cleaning and restoring leather goods. The company uses chlorinated hydrocarbon chemicals (mainly tetrachloroethene) and petroleum hydrocarbons (mineral spirits) in the cleaning process. The wastes from these chemicals were put into a metal dumpster on site from 1977 to 1984. After 1984, 55 gallon drums were used to store the solvents; the drums were pumped regularly by Safety Kleen from 1986 to June, 1991, after which time, the drums were no longer used. They are currently empty and stored on site. On July 8, 1991, the NC DEM issued a Notice of Violation concerning discharge from the drums. Since 1984, wastes from the mineral spirits have been stored in an 1 .u D w w m m m· D D D m m m • I I I I I above ground waste tank which is supported by the concrete pad located on the west side of the building. The waste tank is pumped out and disposed of by Safety-Kleen. The pad also houses a tank holding the un-used mineral spirits. There is a subsurface industrial wastewater system in operation at the site. This system involves a septic drain field in the southern portion of the property. It has been in• operation since 1977 when the Ram Leather Care started business. A private water well was used at the site since 1965 when the property was first bought by E. Cliff Worley. On October 11, 1991, a new water well was installed to replace the old one. This new well was completed to a depth 5IO'. SITE SETTING Topography and Drainage There is a total relief of about 13' on the site, ranging from a basin in the northwest corner at 717.2', to the highest point of 730.4' in the south. Because the property is on a rise between three stream valleys, the surface drainage runs north, south, and east. There is a one story cement building approximately 9025 sq. ft. on the site, and the associated driveway and parking area are gravel. Therefore, most runoff water is absorbed into the ground, or directed 2 m m m m D n I I I I I I I I I I via the natural drainage pattern to one of the streams. The average precipitation is 43" /yr. 1 Surface drainage away from the concrete pad area is directed to the north and ultimately under the railroad and across Albemarle Road. (Please see Appendix 1 for Site Map.) Soils The soils at the Ram Leather Care site are classified as part of the Georgeville unit, common in Mecklenburg County. This unit, locally known as GeB2, is characterized by a silty clay loam. The grain size of the soil is quite fine; 60-95 % of the soil is able to pass through a seive size of 200. This confirms the fact that the soils originate from a fine grained slate parent rock (see the "Geology" section below for a description of the rock formation)2. · The surface layer consists of a yellowish red silty clay loam, approximately 5" thick. -·--~ -.~~--- There is about 4' of strongly acidic subsoil, the upper part of which is a red silty clay. The lower part of the subsoil is a red silty clay loam. The material underlying the subsoil is a brownish yellow, yellowish red, and strong brown silt loam, to approximately 9'. Due to the construction of a new drinking water well on 10-8-91 at the Ram Leather Care site, the depth to bedrock is known to be abanr 42', and the depth to the water table is about 12'. 'Soil survey of Mecklenburg Counf)', Nonh Carolina. United States Department of Agriculture, Soil Conservation Service. Issued June 1980. 2Soil Survey of Mecklenburg Counry, Nonh Carolina. 3 ,m m m m m D D u I m I I I I I I I I I The soil is low in organic matter, and has moderate permeability. The soil is well drained; water is removed from the area readily, but not rapidly. There is medium available water capacity, and medium surface runoff. The slope of the area ranges from 2 to 8 percent, as the soils lie on broad ridges on the uplands. 3 Geology The Ram Leather Care facility is located in the western edge of the Carolina Slate Belt of North Carolina. Classified as phyllites, these rocks are very fine in texture. The metavolcanic rock is characterized by interbedded felsic to mafic tufts and flowrock. The residuum from the fine grained slate forms the Georgeville series subsoil mentioned above. 4 INVESTIGATION The investigation was designed to determine the extent and concentration of chlorinated hydrocarbon and mineral spirits contamination in the soil and groundwater. Thus, soil borings and monitoring well installations were required. A Boring Log is located in Appendix 3, and Well Construction Records are located in Appendix 4. 3Soil survey of Mecklenburg Counry, Nonh Carolina. 4Geologic Map of Nonh Carolina, 1985. 4 -Ill m m m m D D D m m m I m • I I I I I Borings The soil borings were drilled in four series. Initially, two soil borings were advanced (B-1 on 9-18-91, and B'.2 on 9-19-91) using 8 1/2" hollow stem augers with a B-61 Mobile Drill Rig. These first two soil borings were drilled through the water table at potential source areas. Soil samples were taken at 5', 10', 15', and 20' in each boring. Additional soil samples were taken at 24' in B-1 and 25' in B-2. The samples were collected with a split spoon sampler which was decontaminated between samples using an Alconox Scrub, followed by a de-ionized water rinse. The samples were then contained in 4 oz. glass jars and sealed. Groundwater samples were also taken out of these borings. They were contained in 40 ml. VOA vials and sealed with teflon lined caps. All samples were stored in an ice filled cooler for shipment to the laboratory. Auger cuttings were contained in 55 gallon drums and stored on site. Once the necessary samples were taken, the bore holes were backfilled with native material taken from the back of the site. Refer to Appendix 5 Soil Analyses, for sample depths, and Appendix I Site Map for boring locations . The second group of borings in the series were advanced on 9-I 8-91 and 9-19-9 I in the septic drain field area to investigate the extent of soil contamination due to the releases of the septic drain field. Five borings were drilled (B-3 thru B-7) using a stainless steel hand auger, decontaminated as previously discussed. Soil samples were collected in 4 oz. glass jars, sealed, 5 10 D m m m m D D D D D I I I I I I I I and kept on ice for transportation to the lab. . The third group of soil borings in the series were hand augered near the drum storage area. B-9, drilled 9-20-91, was intended to further defif!e the horizontal contamination around B-1, and to show any impact resulting from the storage of the 55 gallon drums. B-10 (drilled 9-20-91) and B-15 thru 17 (drilled 10-21-91) were advanced to investigate the extent of soil contall)ination resulting from the B-1 source area. They were drilled approximately 20' apart, following the northerly path of surface runoff. Sampling and decontamination procedures were followed as previously described. The final borings in the series were advanced using a stainless steel hand auger. B-13 and B-14 were drilled 9-23-91, on each end of the culvert going underneath the Norfolk and Southern Railroad tracks; the culvert receives surface runoff from the B-1 area. The borings were drilled to find if contaminants had reached the railroad tracks, and to find if contaminants had crossed the tracks, possibly impacting property located across Albemarle Road. The two borings were drilled to a depth of 6' each, and samples were taken at that depth. The samples were contained in 4 oz. glass jars and sealed. All samples collected from the soil borings were transported to the lab in an ice chest in order to maintain sample integrity. Samples were tested for Halogenated and Aromatic Volatile Organics, following EPA guidelines for Methods 601 and 602. Some samples were also tested for Mineral Spirits. Refer to Appendix 5 for Data Table. 6 . all D w w m m D D D m m • m I I I I I I Monitoring Well Installations Three monitoring wells were installed (RLI, RL2, and RL3) on 9-24-91 and 9-25-91 under NC DEM Permit #59-1061-WM-0724. In an effort to efficiently confirm the horizontal extent of groundwater contamination in the table aquifer, the groundwater lab data from the soil borings above were used to plan the locations of the monitoring wells RLl-3. (See Appendix 1 for well locations on the site map.) The well borings were drilled using a B-61 Mobile Drill Rig equipped with 8 1/2" hollow stem augers. The soil was sampled using a split spoon sampler at depths of 10' and 20' in each well. Sampling procedures and decontamination were the same as previously discussed. Boring B-8 (RL-3) was drilled on 9-20-91 to a depth of 20'; boring B-11 (RL-1) was drilled on 9-23-91 to a depth of 30', and boring B-12 (RL-2) was drilled on 9-24-91 to a depth of31.65'. The bore holes were completed as 2" wells using flush screwed Sch. 40 PVC casing and screen. The wells were constructed in accordance with the DHENR regulations and guidelines, and finished with 4" steel above ground locking well protectors, It was discovered that the drinking water well on site had been contaminated by the water table aquifer via a cracked casing. On 10/8/91, Ram Leather Care had Mullins Well Drilling install a new 6" water well to a depth of 510'. The well was sampled on 10/11/91 and the results are shown in Appendix 5. 7 aO D D I I m m D D D I m I m I I I I I Groundwater Sampling Each of the monitoring wells was developed and sampled on 9/27/91. Approximately three static well volumes were bailed from each well using a disposable teflon bailer. The wells were then allowed to equilibrate prior to collecting the groundwater samples. Samples were contained in 40 ml. VOA vials and sealed with teflon caps. In order to maintain sample integrity, the samples were transported to the lab in an ice chest. Lab analyses on the water samples were performed in accordance with EPA Methods 601 and 602 for Halogenated and Aromatic Volatile Organics. The water samples were also tested for Mineral Spirits. Appendix 5 summarizes the results of the lab analyses for both soil and groundwater. INVESTIGATION RESULTS Soil and groundwater data indicate that the two main sources of contamination were old wastes leaking from the dumpster, and the concrete pad area used to store mineral spirits and waste drums. The pad area could have been contaminated by surface spills, waste drum leakage, and the floor drain that exits the building under the pad. Monitoring Well RL-1 was reported at I ug/1. Monitoring Wells RL-2 & 3 were reported as Not Detected. The new water well was reported at 9 ug/1. It appears that the new 8 ~o D D m m m I D D D I I m I I I I I I water well has been slightly contamin_ated by the water contained in the underlying fracture rock. The data from the monitoring wells indicate that the horizontal extent of contamination within the upper (water table) aquifer is fairly confined to the source areas around the concrete pad (primary source) and the dumpster area. However, it appears that slight contamination has migrated to the septic drain field via the septic tank and previously used water from the old well. Based on laboratory results previously conducted by Mecklenburg County Health. Department and confirmed by Bold Research Labs, it appears that the horizontal extent of groundwater contamination within the fractured bedrock extends to the White House (south east of Ram) and across Albemarle Road to the Parnell House. On 10/21/91, a "slug test" was conducted on Monitoring Well RL-3. The well was bailed down and allowed to equilibrate over a recorded time period. The "slug test" data are shown in Appendix 5, Table 5. The results show a relatively low to moderate hydraulic conductivity, which describes the rate at which the water can move through the permeable soil medium. Soil contamination has been determined to be fairly isolated around the concrete pad and along the surface water drainage path. The horizontal extent of soil contamination does not extend to the railroad tracks, therefore, we can conclude that the off-site contaminants have not spread due to surface runoff. No soil contamination was found to be present where the existing 9 .u 0 D D m m m I D D I m m I I I I I I empty drums are stored. (The levels of soil contamination within B-2 are fairly insignificant and should not require remedial action.) Ram Leather Care has provided potable water to itself and all houses where contamination has been shown to be present. The small levels of contamination indicate that these water wells are on the outer fringe of the horizontal extent of the bedrock aquifer contamination. CONCLUSIONS * A packer test should be performed in the new water well to determine the vertical extent of contaminaiion. The well should then be re-cased and sealed to prevent the vertical migration of the contaminants, thus allowing only "clean" water to be extracted and used by the facility. * The dumpster is no longer used to dispose of any hazardous wastes. All previously stored waste and current wastes have been properly disposed of by Safety-Kleen. * The old well is no longer in use, but remains open for possible groundwater remediation extraction. The old well should be grouted to a depth just below the determined vertical extent of contamination. * Soil contamination around the pad area can be remediated by a series of vapor extraction 10 .g D m I m D D D I D D B m m I m I m m wells and vacuum pumps. Further soil testing will be required to determine the proper design. * Groundwater will need to be extracted by a series of pumping wells, and treated by releasing the volatile compounds through an air stripping tower. The treated water can then be used in the facility's boiler system, or can be directly discharged to the septic· tank. * This report is submitted to the NC Division of Environmental Management as a preliminary site assessment. A complete remediation closure plan will be submitted following the final assessment approval. 11 .m m m I D ,u APPENDIX 1 R Maps: m General Location Map Adjacent Properties Map Site Map • I I I I I I I ·I I I :1 MAP 1 GENERAL LOCATION MAP D I I QT ,0 c:o..,n .0...0 ----.-_ ... , RAM LEATHER CARE SITE C O U "' r ;, C 2 C z r C C I z m -. -THER CARE RAM LEA Vicinity Map . 9 Adjacent show1n _ . _ Propert1e I\S>K !39 I _ _,.....-··~ I "- I I 1 I I • 1ALE: , 1 = 2ss· RAM LEATHER CARE ....,_ House /3 p.G'- 1 _. _A 9 l.... I :5 8 AC. t P ID-~ m m m I D D I • • •-·- I I I I I (.// SCALE: 111 = 66 1 I N I ~~ ~- ~~~ ~ m \!, ~~ G IJ I I I Grass ---· ·--- MW-RL-2 0 (B-12) B-5 Septic B-7 Drain • Field • B-3 e e B 6 ~ eB-_<j_ ep ic qraln. ield Head Box . MW--RL-3 ( B-8) ~~ ~ H ~. z: l'. i. Trash Pile ~ i1l ~ ' Q l!\ . 0 ,. z:. ., I I I B-14e / N 6 b • 43 • 3 o != I Dumpster Grass MW--RL-1 ~ (B-11) \,IJ :-< -{) C, 0 m m m I D D I m I I I: I I I I APPENDIX 2 Figures: 1. Groundwater Contour Map 2. Horizontal Extents of Soil Contamination 3. Horizontal Extent of Upper Aquifer Contamination 4. Horizontal Extent of Lower Aquifer Contamination 5. Vertical Cross Section A-A' 6. Vertical Cross Section B-B' H I I I I I: 1. I I Figure 1 RAM LEATHER CARE N Groundwater Contour Map 11 .~ ' z: ' 111 I···----+--'-_________ _ I ~ C z:.. m ""\ B-5 • 8 _7 ·. Sep~ic • Dram O B-JI Field B-3 -~ • 8-6 epic rain, ie Head x I ! . MW:-RL-3 $ (B-8) 86. 4791 I I I Figure 2 RAM LEATHER CARE Horizontal Extents of Soil Contamina~inn I I ✓ ~~ ~-~o~ -z: z: m " 1/1 1: ~~ tJ Q I\ I I I --·····--- MW-RL-2 0 (B-12) I -N~FOLK e; .SOUI".l:lflW_ ··-··-·-.h!.C.E.MAIZ( f' ROAD ~ i r:: z:.. . rn ) 8-5 · Septic • B-7 Drain ,.-: B-~ Field B--!. • • .e -5 . MW-RL-3 5 ~ •• 'fF~~l~c _____ J 'f:!rain . ield (B-B) Head Box I I I Sept I£; Line I I I 0 · 11----------· _____ ..__ _________________ R;w ' SCALE: 1" = 66' I I D m m m I , I I I •• I I Figure 3 RAM LEATHER CARE N Hori zo_nta l Extent of I Upper Aquifer Contamination ~1t ~o~ -z: ~m ~i tl lJ -----i--------· . MW-RL-2 0 (B-12) , ~ C z:.. rn "'\ B-5 • 8 Septic .-7 Drain 8 B-~ Field B-3 eCJ e -6 ~~p ic qrain .Field Head Box Septic;. Line J-_·F, ,/0fro rea I . MW;RL-3 S ( B-8) 0 I I IIJ I 8 l/' . t N r-11 ' r- . ----------AL-e.£M42( e ROAD l■1-· _____________ _._ __________________ R/w SCALE: 1" = 66' .r, CO /fL I ,, a.- r 1':::IUI t:: "'t . RAM LEATHER CARE Horizontal Extent of Lower Aquifer Contaminati J .. ~eO Well 01 1f3K !39 B I _ _,,,,···~ I ' I I I • SCALE: 1" = 285'' ' • ' ' ' II I ); // ' It II ,, I ,, ,, ,, \ ~ ~ ~AM LEATHER ' CARE \ ' ---- I 6 AC. IP ---- / ~LVI/, -\-- I N I I D D D m. -~~t ~2~ w ij Ill tl m I I I ff· RAM LEATHER CARE Vertical Cross Sections A-A' and B-B' Grass ~ C z:.. m Open area B-5 , • Septic B-7 Drain • • • e B-~ Field B-3 e ~p . ..,,l•~c....,..--.6-,----' tj;aln . e Head Box _)f' ,. to u /' --····--- MW-RL-2 f; Tank /B-l7 (B-12) I B-14e A' -----------~-----'------~---0 I) ·-·--·--j,./_"~~-'-' c:.e-JZ"oAD I I I ■1-, ---------------------------------R/w · SCALE: 1" = 66' I: --. l!!!!!!I -!!!!!Ill l!EII -= .. la! --l!!l!!!!!I 1!!53 -l!:!i:I -=:I == . ;;;a . liiiii liiiiil iiiiil -.. . -· Figure 5 I 04 102 100 98 96 94 92 90 88 G6 84 82 80 78 76 74 72 70 ! 60 58 56 A RL-1 SCALE Vert i ca 1 : I" • 8' Horizontal: I" • 50' I I I , I Vertical Cross Section A-A' Estimated Extent of B-1 ' Vertical Contamination ' Dark red compacted silty clay.,A. Orange to brown silty clay .A with coarse aggregates A' RL-3 Greyish to brown slightly sedimentized silty clay. Greyish to brown highly weathered s 1 ate. ~-----------~~-~---Figure 6 B SCALE: Vertical: .J"=8' Horizontal : l" = 50' Vertical Cross Section B-B' I I \ \ B' New Dark red compacted silty clay. Orange to brown silty clay • with coarse aggregates Greyish to brown slightly sedimentized silty clay. Greyish to brown highly weathered slate · I I I I ' I ' m u D APPENDIX 3 ' m Soil Boring Logs m ii I g I I I: 1: I 1: I: 1· I l I I ' I m g D m I I D I I Boring Number: Client: Location: Sample Depth 0 5 15 20 25 BOLD RESEARCH LABS, INC. (704) 527-4183 Charlotte, North Carolina SOIL BORlNG LOG B-1 Ram Lea1her Care 15100 Albemarle Road Charloue, Nonh Carolina 28227 Soil Description 0-3' Yellowish red silty clay loam with gravel size aggregates intermixed. 3-5' Red silty clay 5-IO' Brownish yellow to yellowish red highly weathered slate that crushes to a silt loam 10-18' Red silty clay, with pockets of gray clay. 18-24' Greyish brown, fine to medium foliated slightly sedimentized silty clay. 24' Auger refusal -Restrictive layer. Boring terminated. Comments Grassy surface 6' Strong odor in soil li.'. Odor still noticeable in soil. NUTE: B-1 was Orweo wJth a B-bl Mobile 0nll ng on \1-1 ~-~ I to a depth ol L4 ·. I - I I I a i D D ' B m ' I n I I ' I 1· 1: I· I ; ' ' Boring Number: Client: Location: Sample Depth 0 -· - - - 5 - - - - 10 - - - - 15 - - - - 20 - - - - 25 BOLD RESEARCH LABS, INC. (704) 527-4183 Charlotte, North Carolina SOIL BORING LOG B-2 Ram Learher Care 15100 Albemarle Road Char/oue, Nonh Carolina 28227 Soil Description 0-3' Yellowish red silty clay loam with gravel size aggregates intermixed. ~ Red silty clay. .s.:.fil Brownish yellow to yellowish red highly weathered slate that crushes tq a silt loam. 10-22' Greyish to brown, fine to medium foliated slightly sedimentized silty clay with coarse to gravel size aggregates intermixed. Comments Grassy surface ~uTE: B-2 was dnllea with a B,61 Mobile dnll n g on 9-19-\ to a 0e th 01 LL . p ' I I I I I I I I I I m I g D D m I I I Boring Number: Client: Location: Sample Depth 0 - - - - 5 - - - - 10 - - - - 15 - - - - 20 - - - - 25 BOLD RESEARCH LABS, INC. (704) 527-4183 Charlotte, North Carolina SOIL BORING LOG B-3 Ram Leather Care 15100Albemarle Road Charloue, Nonh Carolina 28227 Soil Description 0-3' Yellowish red silty clay loam with gravel size aggregates intermixed. 3-7' Red silty clay Comments NOTE: B-3 drilled with a stainless steel hand auger 9-18-91 to a depth of 7'. I I I I I I I I I I I g I I u D m m I I Boring Number: Client: Location: Sample Depth 0 - - - - 5 - - - - 10 - - - - 15 - - - - 20 - - - - 25 BOLD RESEARCH LABS, INC. (704) 527-4183 Charlotte, North Carolina SOIL BORING LOG B-4 Ram Leather Care 15100 Albemarle Road Charlotte, Nonh Carolina 28227 Soil Description 0-3' Yellowish red silty clay loam with gravel size aggregates intermixed. 1'. Boring terminated -bore hole filled with water. Comments Grassy, well vegetated surface. NOTE: B-4 dnlled with a stainless steel hand auger on ':1-ll:S-, 1 to a depth ot :r. I I I I I I I I I I ' • I '1 I g D D I i Boring Number: Client: Location: Sample Depth 0 - - - - 5 - - - - 10 - - - - 15 - - - - 20 - - - - 25 . . BOLD RESEARCH LABS, INC. (704) 527-4183 Charlotte, North Carolina SOIL BORING LOG B-5 Ram Leather Care 15100 Albemarle Road Char/oue, Nonh Carolina 28227 Soil Description 0-3' Yellowish red silty clay loam wit)1 gravel size aggregates intermixed. 3-5' Red silty clay. ~ Brownish yellow highly weathered slate with pockets of gray clay. Comments Grassy, well vegetated surface. ~uTE: B-5 dnuea wllh a stainless steel hand auger on !:1-1 \HI I to a depth ot lY. I I I I I I I I I I • I I g I I D I m Boring Number: Client: Location: Sample Depth 0 - - - - 5 - - - - 10 - - - - 15 - - - - 20 - - - - 25 NuTE: B-o was dn BOLD RESEARCH LABS, INC. (704) 527-4183 Charlotte, North Carolina SOIL BORING LOG B-6 Ram Leather Care 15100 Albemarle Road Charlotte, Nonh Carolina 28227 Soil Description 0-3' Yellowish red silty clay loam with gravel size aggregates intermixed. l:J1r Yellowish red highly weathered slate that crushes to a silt loam; some pockets of gray clay. Comments Grassy, well vegetated surface. lied with a stainless steel hand au er on 9-19-91 to a de th ot JU'. g p I I I I I I I I I I m g I I I I I I I Boring Number: Client: Location: Sample Depth 0 - - - - 5 - - - - 10 - - - - 15 - - - - 20 - - - - 25 BOLD RESEARCH LABS, INC. (704) 527-4183 Charlotte, North Carolina SOIL BORING LOG B-7 Ram Leather Care 151 (X) Albemarle Road Charlo//e, Nonh Carolina 28227 Soil Description 0-3' Yellowish red silty clay loam with gravel size aggregates intermixed. 3-:.N:. Yellowish red highly weathered slate that crushes to a silty loam; some pockets of gray clay. Comments Grassy, well vegetated surface. ~uTE: B-7 was dn 1ea w!lh a stainless steel hand auger on ':1-1':l-':l l to a de th ot lU'. p •I I I I I I I I I I m I I I D I m I I -Boring Number: Client: Location: Sample Depth 0 - - - - 5 - - - - 10 - - - - 15 - - - - 20 - - - - 25 BOLD RESEARCH LABS, INC. (704) 527-4183 Charlotte, North Carolina SOIL BORING LOG B-8 Ram Learher Care 15100Albemar/e Road Charloue, Nonh Carolina 28227 Soil Description Q:li:_ Orange brown silty clay. 8-17' White to light brown highly weathered slate that crushes to a silt loam. 17-20' Grayish to brown, foliated, slightly sedimentized silty clay with coarse to gravel size aggregates intermixed. Comments Grassy surface. .• ,uTE: B-8 was dn lea usmg a B-61 Mobile dnlJ ng on ~-20-'I to a de th of Lu·. p el I I I I I I I I I m I I D D I I I I Boring Number: Client: Location: Sample Depth 0 - - - - 5 - - - - 10 - - - - 15 - - - - 20 - - - - 25 ~uTE: B-\1 was dn BOLD RESEARCH LABS, INC. (704) 527-4183 Charlotte, North Carolina SOIL BORING LOG B-9 Ram Lea1her Care 15100 Albemarle Road Charloue, Nonh Carolina 28227 Soil Description Comments 0-3' Yellowish red silty clay loam with Grassy surface. gravel size aggregates intermixed. 11.:. Red silty clay. !Jea usin g a hand au er on \I-LU-9 I to a de th or /'. g p • I I I I I I I I I I • I I I D I m I I Boring Number: Client: Location: Sample Depth 0 - - - - 5 - - - - 10 - - - - 15 - - - - 20 - - - - 25 BOLD RESEARCH LABS, INC. (704) 527-4183 Charlotte, North Carolina SOIL BORING LOG B-10 Ram Leather Care 15100 Albemarle Road · Charloue, Nonh Carolina 28227 Soil Description 0-3' Yellowish red silty clay with gravel size aggregates intermixed. 3-7' Red silty clay 7-10' Red silty clay with pockets of gray clay. Comments Grassy surface. Strong odor noticeable in soil throughout boring. NOTE: B-IU was dnlled usin g a hand auger on \1-20-\11 to a cepth ot JU'. •I I I I I I I I I I I I I D I I I I I Boring Number: Client: Location: Sample Depth 0 - - - - 5 - - - - 10 - - - - 15 - - - - 20 - - - - 25 NUTE: B-11 was ct BOLD RESEARCH LAI3S, INC. (704) 527-4183 Charlotte, North Carolina SOIL BORING LOG B-11 Ram Leather Care 15100 Albemarle Road Charloue, Nonh Carolina 28227 Soil Description ~ Dark red, compacted silty clay. 2:.U:. Orange to brown silty clay with coarse gravel size aggregates intermixed. I 3-17' Grayish to brown foliated slightly sedimentized clay with gravel size aggregates intermixed. 17-30' Grayish to brown highly weathered slate. nJJed usm g a B-bl Mobile dnll n · on 9-2: g Comments Grassy surface. -91 to a ae tn ot 30'. p ~1 I I I I I I I I I m n n I D I I I I Boring Number: Client: Location: Sample Depth 0 5 10 15 20 25 BOLD RESEARCH LABS, INC. (704) 527-4183 Charlotte, North Carolina SOIL BORING LOG B-12 Ram Leather Care 15100Albemarle Road Char/oue, Nonh Carolina 28227 · Soil Description Q:Q.'. Dark red slightly sandy clay. 6-7' Light brown slightly sandy clay. 7-18' Brownish yellow slightly sedimentized clay with gravel size aggregates intermixed. 18-35' Strong brown highly weathered slate; strata of smokey quartz aggregates throughout. Comments Grassy surface. NUTE: B-1:L was dn11ea using a B-ol Mobile dnJJ ng on :I-L4-:ll to a depth ot j:, . •I I I I I I I g I g I I I I I I I • I Boring Number: Client: Location: Sample Depth 0 - - - - 5 - - - - 10 - - - - 15 - - - - 20 - - - - 25 BOLD RESEARCH LABS, INC. (704) 527-4183 Charlotte, North Carolina SOIL BORING LOG B-13 Ram Leather Care 15100 Albemarle Road Charlotte, Nonh Carolina 28227 Soil Description l2:.6..'. Dark red, compacted silty clay. Comments Grassy surface. 'IUTE: B-13 was drilled usm g a stainless steel hand au er on g -26-91 to a de th of 6'. p •I I I I I I I m I B M I D I I I I I I Boring Number: Client: Location: BOLD RESEARCH LABS; INC. (704) 527-4183 Charlotte, North Carolina SOIL BORING LOG B-14 Ram Leather Care 15100 Albemarle Road Charlotte, Nonh Carolina 28227 Sample Depth Soil Description Comments 0 0-6' Dark red, compacted silty clay. Grassy surface. 5 10 15 20 25 ~uTE: B-14 was dnlled with a stainless steel hand auger to a depth of 6'. •I I I I I I • I m I I I D D I I I I I Boring Number: Client: Location: Sample Depth 0 5 10 15 20 25 BOLD RESEARCH LABS, INC. (704) 527-4183 Charlotte, North Carolina SOIL BORING LOG B-15 Ram Leather Care 15100 Albemarle Road Charloue, Nonh Carolina 28227 Soil Description 0-5' Red silty clay loam. .2.:.1..Q.'. Red silty clay with pockets of unconsolidated smokey quart. Comments Grassy surface. ~UTE: B-15 was dnlled using a hand auger on lU-21-\11 to a c epth ot Ju·. ~ I I I m g I D H n D I I R D I m m I I Boring Number: Client: Location: Sample Depth 0 - - - - 5 - - - - 10 - - - - 15 - - - - 20 - - - - 25 BOLD RESEARCH LABS, INC. (704) 527-4183 Charlotte, North Carolina SOIL BORING LOG B-16 Ram Leather Care 15100 Albemarle Road Char/oue, Nonh Carolina 28227 Soil Description 0-5' Red silty clay loam. 5-1 0' Brownish red silty clay with smokey quartz aggregates. Comments Grassy surface. ~UTE: B-16 was drilled USin g a stainless steel hand au er on g U-21-':ll to a de th of Ju . p I I I g I D I n R I I m D I I m m I I Boring Number: Client: Location: Sample Depth 0 - - - - 5 - - - - 10 - - - - 15 - - - - 20 - - - - 25 BOLD RESEARCH LABS, INC. (704) 527-4183 Charlotte, North Car_olina SOIL BORING LOG B-17 Ram Leather Care 15100Albemarle Road Charlotte, Nonh Carolina 28227 Soil Description 0-5' Red silty clay loam. ~ Brownish red silty clay with ~ockets of semi-consolidated smokey quartz. Comments Grassy surface. Strong odor noticeable in soil throughout boring. ~u 1 E: B-17 was drilled using a stainless steel hand auger on IU-21-\11 to a depth ol JU'. 11 • • m APPENDIX 4 I Well Construction Records g I I I I I I I m I I I I I ------------- ·-· OrvlSlOH 0, E>MA0Nt.E><TAL ......,..,_QEtr.e(T -QAO>CIWAT'EJt SECT)ON r -P.O. IOJC 27687 -RAUIOH,N.C. 27111, l'KINE (011) 73~·60U I WELL CONSTRUCTION RECORD i'JLLINCl CONTRACTOR Bold Research Labs, Inc. "ILLER REGISTRATION NUMBER __ ___:1..::0.:..7=-9 ____ _ t ~LL LOCATION: (Sl'low skelch of It'll location below} Nearest Town: Charlotte, North Carolina 1 15100 Albemarle Road l(Foad. Community, or SuO~•vision and Loi No.) _ OWNER Mr. _E. Cliff Worley (( DDRESS Ram Leather Care, 15100 Albemarle Road {Street or Roule No.} Charlotte, North Carolina 28227 City or Town Stale 9-24-91 USE OF WELL Zip Code Monitoring 110• TE DRILLED DIITOT AL DEPTH 31. 791 CUTTINGS COLLECTED [2g Yes O No D)ES WELL REPLACE EXISTING WELL 7 0 Yes 5'J No IS~ATIC WATER LEVEL: 16. l6 FT. □ abova TOP OF CASING, Ill below TOP OF CASING IS 2, 48 FT. ABOVE LAND SURFACE. illYIELD (Qpm): ______ METHOD OF TEST. ow•TER ZONES (depth):----------------- IC~LORINA TION: C ,stNG Type Amount Wall Thickness Depth o,ame\er or W81Qhl/Ft. Mater1a1 I F"rom +2.48 To 19.31Ft. 2" Sch. 40 PVC From To Ft. I From To Fi. CaouT: Qeplh Material Method I F"rom o.oo To 18.31F1, Cement Mix eour From To FI. 2. ~:REEN I Oeprh Diameter S101 Size Ma1er1a1 Ffom 19. 31 To 29. 31 Ft. 2" i'\. • 01 ,n_ PVC I Fr.>m To FI. i'\, ,n. From To Fl. i'\, n 3. CRAVEL PACK: DepIh Size Ma1tria1 I-From 19. 31 To 29. 31 Ft. fine silica sand I From ____ To ___ FL . REMARKS. Bentonite seal (3/8 Pellets) from 18. 31 I I DO HEREBY CERTIFY THAT THIS WELL WAS CONSTRUC STANDARDS, ANO THAT A COPY OF THIS RECORD HAS 8 StGNA FOR OFFICE USE ONLY Ouad. No. _______ Serial No. ___ _ Lat. LonQ. ____ Pc __ Mln0< 8a1ln _____________ _ Basin Code _____________ _ Header Ent. _______ GW-1 Ent. __ _ STATE WELL CONSTRUCTION 59_ 1 OGl-WM-0724 PERMIT NUMBER: RL-1 county: Mecklenburg Depth From To 0 - 9 1 9 -131 13 -171 17 -301 DRILLING LOG F0rma1ion Description Dark red compacted silty clay. Orange to brown silty clay witi coarse gravel size aggregates 1 nterm1xed. Grayish to brown foliated sligr s,ed1mentlzed clay with gravel size aggregates intermixed. Grayish to brown highly weathered slate. II additional space is needed use back of lum. LOCATION SKETCH ($how direction and d1s1ance trom at least two State Roads, er otr-ier map '!'erence poin1s) +-Albemarle Road ➔ ... Norfo • RL-3 & Southern RR-. I I R L-2 ); I/ It II I, ,, ,, ,, ,, ,, RAM LEATHER CAR_E House WELL CONSTRUCTION QA TE ----- •I I I I I I I I I I I n I D I I I I I STEEL PIPE 211 Sch. 40 PVC Pipe BENTON I TE PROJECT: Ram Leather Care 15100 Albemarle Road Charlotte, NC 28227 CAP .,,--Manhole Cover _..v---· PVC L<;>cklng Expansion Plug 1' STICK UP 2.4 ' DEPTH TO TOP OF SAND BACKFILL 19. 31 1 TOTAL DEPTH OF WELL 31. 79' MONITORING WELL DIAGRAM BOLD RESEARCH LABS, INC. WELL# RL-1 . 449 Springbrook Road P.O. Box 31466 CHARLOTTE, NORTH CAROLINA 28231-1486 PERMIT# 59-1061-IVM-0724 I ,r1AAQJH.J. OU~ C,, M..A. T'\..fV..1. Atso.,te(S A.NJ C~T'Y O(vn,C)P\,,E)(T OIVl-5,ION 0, [NVlROM,,V(T,tJ. "4AX,C.Ofl.EHT -OAO>CIWAT'U' ~CTION FOR OFFICE USE ONLY P.O. 801 27887 -A.AJ..!.IGH.N.C.21911, l"HONE <a 1g) 733-~93 I WELL CONSTRUCTION RECORD Lia CONTRACTOR _B_o_ld_R_e_s_e_a_rc_h_L_a_b_s_,_I n_c_. __ ·r REGISTRATION NUMBER 1079 LL LOCATION: (Sho ..... Skl!Ch ol lht localion below} 1 Town: Charlotte, North Carolina 15100 Albemarle Road ommundy. or Subd1v,sion .1nd Lot No.) ,1R Mr. E. Cliff Worley ss Ram Leather Care, 15100 Albemarle Road Charlotte, NoA'h•t;g•rg!fr\'aNo) 28227 Outd. No. ______ _ S•nal No. ___ _ Lat. _______ LonQ. ____ Po __ "'41nor Basin ______________ _ Ba sin Code ______________ _ Haader En1. ______ _ Gw-, Ent __ _ STATE WELL CONSTRUCTION 59-1061-WM-0724 PERMIT NUMBER: County: 0101ri From To 0 -6' 6 -7' RL-2 Mecklenburg ORILLl~JG LOG Dark red slightly sandy clay. Light browr slightly sandy clay. I CHy or Town Stale Z10 Codt DRILLED 9-26-91 Monitoring USE OF WE LL _____ ..::.._ ________ _ !IIIL DEPTH 3l. 65 1 CUTTINGS COLLECT.ED E'.IYes O No 7 -18' I WELL REPLACE EXISTING WELL? 0 Yos C8 No ------ Brownish yellow slightly sedimentiZ< clay with gravel size aggregates intermixed. •TIC WATER LEVEL: 14, 40 FT. o above TOP OF CASING. (21 below loP OF CASING Is _2_·_4_2 __ n. ABOvE LAND suRr ACE. '° (Qom): METHOD Of TEST 18 -35' Strong brown highly weathered slat strata of smokey quartz aggregates .ER ZONES (deo1n). -------------------------throu~hout. .__ORlNA T!ON: Type Amount IING Deon, 01ame1tr Wall Th,c'lness or Weu~l"II/FI F,om _+_2_._4_2_ To 19. 23 fl. 2" Sch. 40 I From ____ To ___ F1. ___ _ From ____ To---FI.---- Ma.11na1 PVC Depth Material 0.00 To 18.23r1. Cement Mix Method pour II From ____ To ___ F1. ______ _ nJaEEN Depth o,ame1er Ill F rem 19.23 To 29.23FI. 2" _,_ ,01 ----,n. FrJm ____ To ___ F1. ____ ., ____ ,n. II From ____ To ___ F1. ____ ., ____ ,n. Ill• VEL PACK: Oeoth From 19, 23 To 29. 23FI. From To ___ Fl. Siu Fine Silica ------ Material Sand =,.., AK s, --:s=-e-n-to-n i t e Sea I ('-:3:-/:-8-=P-e.,..,11,...e_t_s ,...) I I DO HEREBY CERTIFY THAT THIS WELL WAS CONSTRUCT STANDARDS. ANO THAT A CoPY Of THIS RECORD HAS BE II aoci111ona1 soace is needed use 'tlac'I. 01 tr .. ·.,., LOCATION SKETCH (Show d1rec11on a.nd d11tance lrom a1 1eas1 two S1a1e Aoads. or 01ner mao ,,1er1nc1 00in1s} .,,_ Albemarle Road ... Norfo & S0uthern Rf'<..., I I • RL-3 RAM Rt-2 )/ I/ It Ii I I ,, ,, ,, LEATHER CARE "' ,, House WELL CONSTRUCTION DATE ➔ SuD"'ul o,,o.ni1 10 o,,..,,,ol'I ot E ,..,1 101'\~tl'\1,1 l.t,,,.J~•-, .. , J'".3 ce::, :: .. ,•i , ... ~i;• ··'" .. ,,,--Manhole Cover _..v----· PVC Lc;,cklng Exµanslon Plug --'--- STEEL PIPE STICK UP 2.42' I I 2" Sch. 40 PVC Pipe ___ -4..q. DEPTH TO TOP OF SAND BACKFILL 19. 23' I I I I I I I I m D I I T BENTON I TE 1' ... . .. ... ::;, :·', ~1-,. :r,. ,:··: ,'', :::::. ;:, S A H O ____.M' c ,:; --.. ,·:: ~·••', ::: PVC SCREEN -:· ·:: -----11-,'•·....,.·. i•'• i:: :_i,: DEPTH Of PVC SCREEN . . , . !:, ~-; 19.23' to 29.23' ,·;:, ••, ·::: ::; 1 •'•• I, ::{ :!: ... , .. •'• ·,:, CAP :', ·:• --1.;,,,.i:::,;:;:i, .. u:11:,, :i PROJECT: TOTAL DEPTH OF \./ELL 31. 65' MONITORING WELL DIAGRAM Ram Leather Care 15100 Albemarle Road Charlotte, NC 28227 BOLD RESEARCH LABS, INC. WELLi RL-2 449 Springbrook Road P.O. Box 31486 PERMITi CHARLOTTE, NORTH CAROLINA 28231·1486 59-1061-WM-0724 )RTH CJ.,AO.JN..I. 0(1'AJn")r.EJ(T 0/l NATU\AL flltl:~5 AMO eOl,M.,.Nrr O(V'(\.~ I Cl VI~ ON Of (HV1 R0M.E NT .l.l M,.IJ,U,. OE "-'£HT -OAO>Cl WA Tt:R $EC T ION -P.O. BOX 21687 • fl.AU1QH,H.C.21611, ~ (I U) 733.5,043 I ... WELL CONSTRUCTION RECORD Inc. .,G CONTRACTOR Bold Research Labs IILLER REGISTRATION NUMBER ____ 1~0_7~9 ____ _ Ti:C '110N· (ShOw s>eics ol 1se locai,on below) " 1 • Charlotte, North Carolina ... eares . own. _____________________ _ -II-: J s 1 oo Albemarle Road o •. C .:mmL,n1ly. or Subdrv1S10n and Loi No) OWNER Mr. E. Cliff Worley ,,ESS Ram Leather Care, 15100 Albemarle Road (StreeLor Rq1,11e No.) Charlotte, North caroIIna 28227 C11y or. Town Staie z,o Code 'I o=,cLED 9-26-91 USE OF WELL Monitoring 10 L )£PH< 20. O' CUTTINGS COLLECTED ~ Yu O No --\\cLL REPL>CE EX1ST1NG WELL' 0 Yes 0 No rll1c '/IA TEA LEVEL. 13· 59 FT, 0 above TOP OF C>SING, X) below TOF OF OSING IS 2. 38 FT. ABOVE LAND SURFACE. 'I (;om) ______ METHOD OF TEST _______ _ ..... R ZONE s (deoth): ------------------ tRl•;..1. 1'10N· Type CASIN ·, I Fi:-, Oeoth + 2. 38 To 7. 62 Fi::-:, To lF,,~ To . G u· ~tOlh a F ,-0.00 To 6, 62 F : .-i To Deotn 7.62 F·;.~ I,,~---- F·.:-i ___ _ To17.62 To To Oeo1r-i f ·: m _7_._6_2_ To17,62 Amounl Wall Th,c\neH Diameter or We19ht1F1 Material FI 2" Sch. 40 PVC ---- 'I. FI. M.11er,a1 Mt lhOd 'I. Cement Mix pour FI. Q,ameltf s101 Size Material FI. 2" in. . 01 '"· PVC ,1 in. ,n Ft. "'· "' Siu. Ma11,,a1 FI. Fine Silica Sand FOR OFFICE USE ONLY Ou1d. No, _______ S•rial No. ___ _ Lat. _______ Lono. ____ Pc __ Mln0< Basin ______________ _ Basin Code ______________ _ Htader Enl. _______ QW-1 Ent, __ _ STATE WELL CONSTRUCTION . PERMIT NUMBER: 59-1061-WM-0724 R L-3 Mecklenburg 0101h From 0 -8' 8 -17' To 17 -201 DRILLING LOG Formation OeScription 0 range brown silty clay. White to light brown highly weathered slate that crushes to a silt loam. Grayish to brown, foliated, slightly sedimentized silty clay with coarse to gravel size J aggregates intermixed. II additional soace is neeaed use back ol fr,rm LOCATION SKETCH (Show arr1c11on and d1sunc1 !tom a1 11as1 two S1a1, Roaas. or olf\er mac, ,~lerence 001n1s) <f-Albemarle Road ➔ 0 RL-3 11 RL-2 ),' I/ It // RAM LEATHER CARE , IM:;::-B-e-n-to-;i~-e-S_e_a_l 'r'3/8 Pellets} from 6, 62 to 7.62 1 HO\.JSC I 1 DO HEREBY CERTIFY THAT THIS WELL W>S CONSTAUC ST>ND>RDS, AND THAT A COPY o; THIS RECORD HAS BE SIGNA TU WITH •~ NCAC ZC WELL CONSTAuCTION OWNER. ,,,,--Manhole Cover o;==_=.J.~...----· PVC L9cklng Expansion Plu_g __ STEEL PIPE STICK UP 2•381 I I. I I I I I I I I I I BORIHG ___ _ DEPTH TO TOP OF SAHD BACKFILL 7. 62' BENTON I TE I PROJECT: I Ram Leather Care 15100 Albemarle Road Charlotte, NC 29227 CAP BASE OF GRO T SEAL 6·62' 1' TOTAL DEPTH OF WELL 20. 0' MONITORING WELL DIAGRAM BOLD RESEARCH LABS, INC. WELLi RL-3 449 Springbrook Road PERMIT# P.O. Box 31488 CHARLOTTE, NORTH CAROLINA 28231·1486 59-1061-WM~ 0724 W'--___ _.., ______ ........_ ___ _ n I I I I I I I I I a I I n APPENDIX 5 Tables: 1. Preliminary Water Analyses 2. Groundwater Analyses from Borings and Monitoring Wells 3. Soil Analyses 4. Water Level Measurements 5. Slug Test 'I I I I I I I I I I I g I I I I LAB ANALYSES FOR RAM LEATHER CARE TABLE I · Preliminary Water Analyses (measurements in ug/1) Boiler Pond Septic Old RL Blowout Water Tank Well Head Chloroform 9 540 260 Chlorobenzene 2 1,2-Dichloroethane 1 12 Tetrachloroethene 66 578 Cis-1,3-Dichloropropene 21 Trans-1,2-Dichloroethene 21 Methylene chloride 19 1, 1, I-Trichloroethane 2 Trichloroethene 124 Bromodichloromethane Toluene 29 Isopropyl Ether 171 I Note: Blank Space = Not Detected m I White Parnell House Outside Well Faucet Head 41 8 7 8 9 5 I I I I I I I I I I B I I I I I m m! I TABLE2 Groundwater Analyses from Soil Borings and Monitoring Wells (measurements in ug/1) B0 ! B-2 B-8 (RL-3) B-11 (RL-1) B-12 (RL-2) I, 1-Dichloroethane 28 1,2-Dichloroethane 11 Trans-1,2-Dichloroethene 13 Methylene Chloride 78 Tetrachloroethene 50060 1201 3 I, I, I-Trichloroethane 6697 26 I, I ,2-Trichloroethane 112 Trichloroethene 830 10 Toluene 13 Methyl-tert-butyl ether 45 I I MWRL-1 I MWRL-2 I MWRL-3 Tetrachloroethene (ug/1) I Mineral Spirits (mg/I) <.25 <.25 <.25 Note: Blank Space = Not Detected NC DEM groundwater standard for Tetrachloroethene is . 7 ug/1. NC DEM drinking water standard for Tetrachloroethene is 5 ug/1. 2 I New Water Well I 9 <.25 I Soil testing in new water well Table 3 Soil Analyses I I (measurements in ug/kg) RL-DW-JO' RL-DW-20' RL-DW-30' RL-DW-40' Halogenated Volatile Organics Mineral Spirits (mg/kg) <.5 <.5 I Borings I I I I n I m I I (measurements in ug/kg) Tetrachloroethene I, I, I-Trichloroethane Mineral Spirits (mg/kg) (measurements in ug/kg) 1, I, 1-Trichloroethane Mineral Spirits (mg/kg) (measurements in ug/kg) I Tetrachloroethene (measurements in ug/kg) 1 1 Tetrachloroethene I B-1 5' 26584 89 B-3 4' 16 <.5 B-8 10' I B-15 4' m Note: Blank Space = Not Detected ft, D B-1 B-1 B-1 JO' 15' 20' 2868 28 7 4 <.5 B-3 B-4 B-5 7' 2' 4' 31 <.5 .5 .5 B-8 B-9 B-10 B-11 20' 7' 10' 10' I I 15503 I B-15 B-16 10' 4' .6 <.5 B-1 B-2 B-2 B-2 24' 5' 10' 15' 19 15 52 1 <.5 . <.5 <.5 B-5 B-6 B-6 JO' 4' JO' .5 <.5 <.5 B-11 B-12 B-12 20' JO' 20' I 21 I I B-16 B-17 10' 4' 380 RL-DW-50' <.5 B-2 B-2 20' 25' 334 31 30 30 <.5 B-7 B-7 4' 10' <.5 <.5 B-13 B-14 6' 6' I I I B-17 10' 2417 •I I I I I I I I Monitoring Well: RL-1 RL-2 RL-3 TABLE4 Water Level Measurements. Water Water Level2 Water Water Level Water Elevation1 9/27/91 Elevation 9/30/91 Elevation (Top of 9/27/91 9/30/91 Casing) 101.875' I 16.16' 85.715' 17.13' 84.745' 102.646' 14.40' 88.246' 14.70' 87.946' 100.229' 13.59' 86.639' 13.75' 86.479' I 1Elevations are based on the concrete slab elevation at Ram Leather Care, front door being I 00'. I 2Measured by an electronic water level indicator. ! I m I I I m m D D Table 5 •• 1.0· .9 j ·t i t I I I :-~ • -1 · · : ! ·I· I ! .. .8 ___ I .7--- .6 •.. I .5--· I .4 ___ I .3 __ _ I I :..-i:="f · 1 ;Ff:J.j -i-~-J..:: s; r.·•·· 1,i.::I : -·•·· ------. :-.::-.--:: : ' h/ho -H--;:; ---'+---· I I I I I I D . 1 ·-- ~ +i--: . ·,;·'-t-~t· .09--~:"'. i ! ,=J"_L-....i .os __ i.:,:..:.--1.-r:i ~i ·("'!"·i .06 .. ,=.:.:.:.·~.:.:. =i=-! .05 .. "-'-',-'·:. ~:.:~== 1-.1~··:.:=-1. ':" ·I:;.: ·.to- t:~:~~,; ~f"- --~::...:~::. --~ -:-r_____r: 1-7=·:..:::::: ::, . -.:.::. _____ ....._ - :~.:..:~1: :t: --I. ·1-t--1--r- .01 1500 3000 4500 6000 ...Ram Leather Care Slug Test -' - ~ .... .... ' : ' 7500 ' ' ' ,- ' ' . o I I I --~-'II! -. - - ~~ : -.. . . -- ·- --- .......:...:: --== -t:::. - -1-· •···· --:-.t:..-,-,----:r::-:-::: r=Et=:-. =~-:.-;-~~ ,..... .... ,_~,.....,-•---... t......-,-,-1-+-1-'· _--; 1---.. Li: .:,._,_r= ·-,._., --+-. i---+-- ' . ' . ' ' ' ' ' t-' ' I t ' I I I ' I t--r,t--,--... -H-:i.::--_: :.:. T ' --•-·· ' ' ··-,-I•-• ' ' ' ' I 9000 10500 12000 13500 15000 16500 time (seconds) ' ' ' ' ' I ' ' ' ~1 I I I I I I I I I I I I I w m I D I Elapsed Time Seconds Static 0 300 600 900 1500 2400 3300 4200 5100 6000 6900 7800 8700 9600 10500 11400 12300 13200 · 14100 Ram Leather Care Slug Test Monitoring Well RL-3 Depth to Change in Water Water Level (h) Feet 14.50 16.71 2.21 (h0) 15.31 0.81 15.21 0.71 15.16 0.66 15.08 0.58 14.99 0.49 14.96 0.46 14.90 0.40 14.85 . 0.35 14.82 0.32 14.76 0.26 14.73 0.23 14.70 0.20 14.67 0.17 14.63 0.13 14.62 0.12 14.58 0.08 14.56 0.06 14.51 ' 0.01 h/h0 1.000 0.366 0.321 0.299 0.263 0.222 0.208 0.181 0.158 0.145 0.118 0.104 0.090 0.077 0.059 0.054 0.036 0.027 0.005 ll I I I I I I I I I I I I I I I I w I D Slug Test, cont. r = .083 feet R = .083 feet L = 10 feet K = r2 In (L/R) 2LT0 K = <.083)2 !n(I0/.083) 2(10)(450) K = {.006891{4.79161 (9000) TO = the time for the head to rise to 37% of the initial change. K = <.033) = 3.66 x J0·6 ft./sec. = .316 ft./day 9000 -1 I I I I m I I D D I I I D I I I m m . APPENDIX 6 Lab Results •I I I I I PRELTh11NARY WATER ANALYSES I :1 I • I I I I I m 0 I I I I I I I I I I I I I I D I I I I ( Bold Re~~0~!ch Labs) ANALYTICAL TESTING & CONSULTING SERVICES P.O. BOX 31486 •CHARLOTTE.NC 28231 • TELEPHONE {704) 527-4183 • FAX: (704) 525--0409 October 28. 1991 Ram Leather Care Attn: E. Cliff Worlev 15100 Albermarle Rd Charlotte. N. C. 28227 Dear Mr. Worlev: Below are 1'esults of analvsis of 2 samoles received for examination on Julv 17. 1991: Custo ■er Code: RAM Phone N,.,mber: (704) 545-9737 LAB I.D. AA0&853 Bold ID Number G889Gl-2 Bold Customer Number 6745 Collection Date: 07/15/91 Collection Time: 16:00 Submittal Date: 07/17/91 Submittal Time: 08:31 Customer Samele I.D#: BOILER BLOWOUT TEST PARAMETER UNITS TEST RESULT Multicomoonent analvsis: HALOGENA,TED VOLATILE ORGANICS BROMODICHLOROMETHANE uo/L Not Det BROMOFORM u □/L Not Det BROMOMETHANE u □/L Not Det CARBON TETRACHLORIDE u □/L Not Det CHLOROBENZENE u □/L Not Det 2-CHLOROETHYLVINYL ETHER u □/L Not Det CHLOROFORM u □/L 9 CHLOROMETHANE u □/L Not Det DIBROMOCHLOROMETHANE uo/L Not Det 1.2-DICHLOROBENZENE u □/L Not Det 1.3-DICHLOROBENZENE u □/L Not Det 1.4-DICHLOROBENZENE u □/L Not Det DICHLORODIFLUOROMETHANE u □/L Not Det 1.1-DICHLOROETHANE u □/L Not Det 1.2-DICHLOROETHANE u □/L l 1. 1-DICHLOROETHENE u □/L Not Det TRANS-1.2-DICHLOROETHENE u □/L Not Det 1.2-DICHLOROPROPANE u □/L Not Det CIS-1.3-DICHLOROPROPENE u □/L Not Det TRANS-1.3-DICHLOROPROPENE u □/L Not Det METHYLENE CHLORIDE u □/L Not Det 1. 1.2.2-TETRACHLOROETHANE u □/L Not Det TETRACHLOROETHENE u□/L 66 1.1. I-TRICHLOROETHANE u □/L Not Det 449 SPRINGBROOK ROAD• CHARLOTTE, NC 28217 DETECTION LIMIT l l l l l ·l 1 1 l l l l l l l l l l l l l l l l I I I I I I I I I I I I a I I I m I ANALYTICAL TESTING & CONSUL TING SERVICES P.O. BOX 31486 •CHARLOTTE.NC 28231 • TELEPHONE (704) 527-4163 • FAX: (704) 525-0409 Ram Leather Care Pace: 2 October 28. 1'391 HALOGENATED VOLATILE ORGANICS <continued): 1.1.2-TRICHLOROETHANE IJ □/L Not Det TRICHLOROETHENE u □/L Not Det TRICHLOROFLUOROMETHANE uc/L Not Det VINYL CHLORIDE IJ □/L Not Det CHLOROETHANE u □/L Not Det CIS-1.2-DICHLOROETHENE u □/L Not Det ETHYLENE BROMIDE u □/L Not Det IPE u □/L Not Det MTBE u □/L Not Det BTEX uc/L Not Det 1 1 1 1 1 1 1 1 1 1 ------------------------------------------------------------------------ Comments: watet~ form outside oioe Custc ■er Code: RAM Phone N•.tmber: (704) 545-9737 LAB I.D. AA0&854 Bold ID Number G88'3G1-2 Bold Customer Number &745 Collection Date: 07/15/91 Collection Time: 1&:30 Submittal Date: 07/17/'31 Submittal Time: 08:31 Customer Sam □le I.D#: POND WATER ------------------------------------------------------------------------ TEST PARAMETER UNITS TEST RESULT DETECTION LIMIT ------------------------------------------------------------------------ Multicom □onent analvsis: HALOGENATED VOLATILE ORGANICS BROMODICHLOROMETHANE IJ □/L Not Det 1 BROMOFORM uc/L Not Det 1 BROMOMETHANE IJ □/L Not Det 1 CARBON TETRACHLORIDE u □/L Not Det 1 CHLORDBENZENE u □/L Not Det 1 2-CHLOROETHYLVINYL ETHER ,.,o/L Not Det 1 CHLOROFORM u □/L Not Det 1 CHLOROMETHANE 1.1 □/L Not Det 1 DJBROMOCHLOROMETHANE •.tc/L Not Det 1 1.2-DICHLOROBENZENE u □/L Not Det 1 1.3-DICHLOROBENZENE '·'° /L Not Det 1 1.4-DICHLOROBENZENE u □/L Not Det 1 DICHLORODIFLUOROMETHANE u□/L Not Det 1 1.1-DICHLOROETHANE u □/L Not Det 1 1.2-DICHLOROETHANE u□/L Not Det 1 1.1-DICHLOROETHENE uo/L Not Det 1 TRANS-1.2-DJCHLOROETHENE IJ □/L Not Det 1 1.2-DICHLOROPRDPANE ,.,□ /L Not Det 1 CIS-1.3-DJCHLOROPROPENE u □/L Not Det 1 TRANS-1.3-DICHLOROPROPENE IJ □/L Not Det 1 METHYLENE CHLORIDE u □/L Not Det 1 449 SPRINGBROOK ROAD• CHARLOTTE, NC 28217 I I I I I I I I I I I I m m u ANALYTICAL TESTING & CONSUL TING SERVICES P.O. BOX 31486 • CHARLOTTE, NC 28231 • TELEPHONE (704) 527-4183 • FAX: {704) 525--0409 Ram Leather Care Pace: 3 October 28. 1991 HALOGENATED VOLATILE ORGANICS 1. 1.2.2-TETRACHLOROETHANE TETRACHLOROETHENE 1. 1.1-TRICHLOROETHANE 1. 1.2-TRICHLOROETHANE TRICHLOROETHENE TRICHLOROFLUOROMETHANE VINYL CHLORIDE CHLOROETHANE CIS-1.2-DICHLOROETHENE ETHYLENE BROMIDE IPE MTBE BTEX. (continued}: u □/L uc/L u □/L u □/L u □/L u □/L u □/L ,.,□/L u □/L u□/L u □/L ,.,□ /L u □/L Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det Not Det 1 1 1 1 1 1 1 1 1 1 1 1 1 ------------------------------------------------------------------------ Comments: water from oond on orooertv Please advise should vou have ouestions concernin □ these data. Resoectfullv submitted. Gradv W. Burcin Laboratorv Mana □er 449 SPRINGBROOK ROAD• CHARLOTTE, NC 28217 I I I I I I I I I I I D m u u ANALYTICAL TESTING & CONSUL TING SERVICES P.O. BOX 31486 •CHARLOTTE.NC 28231 • TELEPHONE [704) 527..4183 • FAX: (704) 525-0409 October 28. 1991 Ram Leather Care Attn: E. Cliff Worlev 15100 Albermarle Rd Charlotte. N.C. 28227 Dear Mr. Worley: Bel~w are results of analvsis of 1 samole received for examination on Julv 18. 1991: Custo ■er Code: RAM Phone LAB J.D. AA0&925 Bold ID Collection Date: 07/18/91 Number: (704) 545-9737 Nurnbet· Gg11G1 Bold Custorner_N1Jmber Collection Time: 11:30 Submittal Date: 07/18/91 Submittal Time: 13:38 Customer Samole I.D#: SEPTIC TANK ------------------------------------------------------------------------ TEST PARAMETER UNITS TEST RESULT DETECTION LIMIT ------------------------------------------------------------------------ Multic6moonent analvsis: HALOGENATED VOLATILE ORGANICS BROMODICHLOROMETHANE u □/L Not Det 1 BROMOFORM ,,c/L Not Det 1 BROMOMETHANE u □/L Not Det 1 CARBON TETRACHLORIDE u □/L Not Det 1 CHLOROBENZENE u □/L Not Det 1 2-CHLOROETHYLVINYL ETHER u □/L Not Det 1 CHLOROFORM u □/L 54121 1 CHLOROMETHANE 1.10/L Not Det ·1 DIBROMOCHLOROMETHANE u □/L Not Det 1 1.2-D!CHLOROBENZENE u □/L Not Det 1 1.3-DICHLOROBENZENE u□/L Not Det 1 1.4-DICHLOROBENZENE u □/L Not Det 1 DICHLOROD!FLUOROMETHANE u□/L Not Det 1 1. 1-D I CHLOROETHANE ua/L Not Det 1 1.2-DICHLOROETHANE u □/L 12 1 1. 1-DICHLOROETHENE u □/L Not Det 1 TRANS-1.2-DICHLOROETHENE u □/L Not Det 1 1.2-DICHLOROPROPANE uc/L Not Det 1 CIS-1.3-DICHLOROPROPENE u □/L 21 1 TRANS-1.3-DICHLOROPROPENE ,.,□ /L Not Det 1 METHYLENE CHLORIDE u □/L Not Det 1 1. 1.2.2-TETRACHLOROETHANE u □/L Not Det 1 TETRACHLOROETHENE u □/L Not Det 1 1. 1. 1-TR I CHLOROETHANE u □/L Not Det 1 449 SPRINGBROOK ROAD• CHARLOTTE, NC 28217 I I I I I I I I I I I I g I I I m Bold Research Labs Incorporated ANALYTICAL TESTING & CONSUL TING SERVICES Ram Le at her cl.?eBOX 31486 •CHARLOTTE.NC 28231, TELEPHONE (704) 527-4183, FAX: (704) 525-0409 Pace: 2 October 28. l'l'Jl. HALOGENATED VOLATILE ORGANICS 1.1.2-TRICHLOROETHANE TRICHLOROETHENE TRICHLOROFLUOROMETHANE VINYL CHLORIDE CHLO ROE THANE CIS-1.2-DICHLOROETHENE ETHYLENE BROMIDE !PE MTBE BENZENE TOLUENE ETHYLBENZENE XYLENE (continued): uc/L uc/L uc/L uc/L u □ /L ,.,□ /L u □/L uc/L u □/L u □/L uc/L uc/L uc/L Not Det Not Det Not Det Not Det Not Det Not Det Not Det 171 Not Det Not Det 2'J Not Det Not Det Multicomoonent analvsis: AROMATIC VOLATILE ORGANICS BENZENE CHLOROBENZENE 1.2-DICHLOROBENZENE 1.3-DICHLOROBENZENE 1.4-DICHLOROBENZENE ETHYL BENZENE TOLUENE XYLENE METHYL-TERT-BUTYL ETHER ISOPROPYL ETHER ,.,□/L uc/L uc/L ,.,c/L uc/L u □/L u □/L ,.,c/L uc/L u □/L Not Det Not Det Not Det Not Det Not Det Not Det 29 Not Det Not Det 171 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 ------------------------------------------------------------------------ Comments: water from seotic tank clean out Please advise should vo1J have □uestians concet'nino these data. Resoectfullv submitted. Gradv W. Burcin Laboratorv Manaoe1' 449 SPRINGBROOK ROAD• CHARLOTTE, NC 28217 I I I I I I I I I I I I I I D I m m ANAL YTtCAL TESTING & CONSULTING SERVICES P.O. BOX 31486 • CHARLOTTE, NC 28231 • TELEPHONE (704) 527~183 • FAX: [704) 525-0409 October 28. 1'3'31 Ram Leather Care Attn: E. Cliff Worlev 15100 Albermarle Rd Charlotte. N. C. 28227 Dear Mr. Worley: Below are results of analvsis of 3 samoles received for examination on Au □ust 1. 19'31: Cust □■er Code: RAM Ph one Number: ( 704) 545-9737 LAB I.D. AA07201 Bold ID Number G126Hl-3 Bold Customer Number 6745 Collection Date: 08/01/'31 Collection Time: 12:30 Submittal Date: 08/01/91 Submittal Time: 14:52 Custo~er Samele I.D#: RL WELL HEAD ------------------------------------------------------------------------ TEST PARAMETER UNITS TEST RESULT DETECTION LIMIT ------------------------------------------------------------------------ Mr.1lt icomoonent analvsis: HALOGENATED VOLATILE ORGANICS BROMODICHLOROMETHANE u □/L Not Det I BROMOFORM uo/L Not Det I BROMOMETHANE u □/L Not Det I CARBON TETRACHLORIDE u□/L Not Det 1 CHLORDBENZENE uo/L 2 I 2-CHLORDETHYLVINYL ETHER u□/L Not Det ·1 CHLOROFORM ll □/L 26121 I CHLO ROM ETHANE uo/L Not Det 1 DIBROMOCHLOROMETHANE u □/L Not Det 1 1.2-DICHLOROBENZENE u □/L Not Det I 1.3-DICHLOROBENZENE u□/L Not Det 1 1.4-DICHLORDBENZENE u D /L Not Det 1 DICHLORODIFLUOROMETHANE u□/L Not Det I 1.1-DICHLOROETHANE uo/L Not Det I 1.2-DICHLOROETHANE uo/L Not Det I 1.1-DICHLOROETHENE uo/L Not Det I TRANS-1.2-DICHLOROETHENE u □/L 21 I 1.2-DICHLOROPROPANE uo/L Not Det 1 CIS-1.3-DICHLOROPROPENE u □/L Not Det I TRANS-1.3-DICHLOROPROPENE IJ □/L Not Det l METHYLENE CHLORIDE IJ □/L l '3 l 1. 1.2.2-TETRACHLOROETHANE uc/L Not Det l TETRACHLOROETHENE u □/L 578 1 l. 1. 1-TRICHLOROETHANE uo/L 2 I 449 SPRINGBROOK ROAD• CHARLOTTE, NC 28217 I I I I I I I I I I , I I I I I I I I ANALYTICAL TESTING & CONSUL TING SERVICES P.O. BOX 31486 •CHARLOTTE.NC 28231 • TELEPHONE f704) 527-4183 • FAX: £7()4) 525-0409 Ram Leather Care Pace: 2 October 28. 1'3'31 HALOGENATED VOLATILE ORGANICS (continued) : 1.1.2-TRICHLOROETHANE u □/L Not Det 1 TRICHLOROETHENE u □/L 124 1 TRICHLOROFLUOROMETHANE u □/L Not Det 1 VINYL CHLORIDE u□/L Not Det 1 CHLOROETHANE u □/L Not Det 1 CIS-1.2-DICHLOROETHENE u □/L Not Det 1 ETHYLENE BROMIDE u □/L Not Det 1 IPE u□/L Not Det 1 MTBE u □/L Not Det 1 BTEX u □/L Not Det 1 ------------------------------------------------------------------------ Custo ■er Code: RAM Phone N•.1mber: (704) 545-'3737 LAB I.D. AA07202 Bold ID Number G12&H1-3 Bold Customer Number &745 Collection Date: 08/01/'31 Collection Time: 12:30 Submittal Date: 08/01/'31 Submittal Time: 14:52 Customer Sam □le I.D#: WH WELL HEAD ------------------------------------------------------------------------ TEST PARAMETER UNITS TEST RESULT DETECoTION LIMIT ------------------------------------------------------------------------ M1-1lticomoor.ent ~nalvsis: HALOGEr,ATED VOLATILE ORGANICS BROMODICHLOROMETHANE ,.,□ /L 5 1 BROMOFORM u □/L Not Det l BROMOMETHANE u □/L Not Det l CARBON TETRACHLORIDE UCJ /L Not Det l CHLOROBENZENE u □/L Not Det 1 2-CHLOROETHYLVINYL ETHER uo/L Not Det .1 CHLOROFORM u □/L 41 l CHLOROMETHANE u □/L Not Det l DIBROMOCHLOROMETHANE u □/L Not Det 1 1.2-DICHLOROBENZENE u□/L Not Det 1 1.3-DICHLOROBENZENE u □/L Not Det l 1.4-DICHLOROBENZENE uo/L Not Det 1 DICHLORODIFLUOROMETHANE uo/L Not Det l 1, 1-DICHLOROETHANE ,.,o/L Not Det 1 1.2-DICHLOROETHANE l\□/L Not Det l 1. 1-DICHLOROETHENE u □/L Not Det 1 TRANS-1.2-DICHLOROETHENE u □/L Not Det 1 1.2-DICHLOROPROPANE uo/L Not Det 1 CIS-1.3-DICHLOROPROPENE u□/L Not Det 1 TRANS-1.3-DICHLOROPROPENE uo/L Not Det l METHYLENE CHLORIDE u□/L 8 1 1. 1.2.2-TETRACHLOROETHANE uo/L Not Det 1 TETRACHLOROETHENE uo/L 8 1 449 SPRINGBROOK ROAD• CHARLOTTE, NC 28217 I I I I I I I I I I I I I I I m ANALYTICAL TESTING & CONSUL TING SERVICES P.O. BOX 31486 • CHARLOTTE, NC 28231 • TELEPHONE {704) 527-\183 • FAX: (704) 525-0409 Ram Leather Care Pace: 3 October 28. 1991 HALOGENATED VOLATILE ORGANICS (contin'-led): 1.1. 1-TRICHLOROETHANE uc/L Not Det 1 1.1.2-TRICHLOROETHANE uo/L Not Det 1 TRICHLOROETHENE uc/L Not Det 1 TRICHLOROFLUOROMETHANE uo/L Not Det 1 VINYL CHLORIDE uo/L Not Det 1 CHLOROETHANE uc/L Not Det 1 CIS-1.2-DICHLOROETHENE uc/L Not Det 1 ETHYLENE BROMIDE uo/L Not Det 1 IPE uo/L Not Det 1 MTBE uo/L Not Det 1 BTEX uc/L Not Det 1 ------------------------------------------------------------------------ Custo ■er Code: RAM Phone Number: 17041 545-9737 LAB l.D. AA07203 Bold ID Number G126Hl-3 Bold Customer Number 6745 Collection Date: 08/01/91 Collection Time: 12:30 Submittal Date: 08/01/9'. Submittal Time: 14:52 Customer Samole I.D#: PAR OUTSIDEFAU ------------------------------------------------------------------------ TEST .:•ARAMETER UNITS TEST RESULT DETECTION LIMIT ------------------------------------------------------------------------ M1Jlticomoonent analvsis: HALOGENATED VOLATILE ORGANICS BROMOD!CHLOROMETHANE uo/L Not Det 1 BROMOFORM uc/L Not Det 1 BROMOMETHANE uc/L Not Det 1 CARBON TETRACHLORIDE uo/L Not Det 1 CHLOROBENZENE uc/L Not Det 1 2-CHLOROETHYLVINYL ETHER uc/L Not Det 1 CHLOROFORM uo/L Not Det 1 CHLOROMETHANE •.10 /L Not Det 1 DIBROMOCHLOROMETHANE uo/L Not Det 1 1.2-DICHLOROBENZENE uo/L Not Det 1 1.3-DICHLORDBENZENE uo/L Not Det 1 1.4-DICHLOROBENZENE uc/L Not Det 1 DICHLORODIFLUOROMETHANE uc/L Not Det 1 1.1-DICHLOROETHANE uo/L Not Det 1 1.2-DICHLOROETHANE uo/L Not Det 1 1. 1-DICHLOROETHENE uo/L Not Det 1 TRANS-1.2-DICHLOROETHENE ,,o/L Not Det 1 1.2-DICHLOROPROPANE uo/L Not Det 1 CIS-1.3-DICHLOROPROPENE ,,o/L Not Det 1 TRANS-1.3-DICHLOROPROPENE uo/L Not Det 1 METHYLENE CHLORIDE ua/L 9 1 1. 1.2.2-TETRACHLOROETHANE uo/L Not Det 1 449 SPRINGBROOK ROAD• CHARLOTTE, NC 28217 I I I I I I I I I I I I I I I m ANALYTICAL TESTING & CONSUL TING SERVICES P.O. BOX 31486 •CHARLOTTE.NC 28231 • TELEPHONE (704) 5274183 • FAX: (704) 525--0409 Ram Leather Care Pace: 4 October 28. 1991 HALOGENATED VOLATILE ORGANICS (cont inuedl: TETRACHLOROETHENE uc/L 7 1. 1. 1-TRICHLOROETHANE uc/L Not Det 1. 1.2-TRICHLOROETHANE uc/L Not Det· TRICHLOROETHENE uc/L Not Det TRICHLOROFLUOROMETHANE uc/L Not Det VINYL CHLORIDE uc/L Not Det CHLO ROE THANE u □/L Not Det CIS-1.2-DICHLOROETHENE u □/L Not Det ETHYLENE BROMIDE uc/L Not Det IPE IJC/L Not Det MTBE u □/L Not Det BTEX uc/L Not Det Please advise should vou have auestions concernin □ these data. Resoectfullv submitted. Gra.clL\ W. bUJ1~..:.. Gra.dv W. B•.ircin Laboratorv Manacer 449 SPRINGBROOK ROAD• CHARLOTTE, NC 28217 1 1 1 1 1 1 1 1 1 1 1 1 •• I I I 'I ii I 'I I I I I I I I ·1 I 'I I SOIL BORINGS and WATER LABORATORY REPORTS I I I I I I I I I I I I I I I I I m Bold Research Labs Incorporated ANALYTICAL TESTING & CONSUL TING SERVICES P.O. BOX 31486 •CHARLOTTE.NC 28231 • TELEPHONE (7041527-4183 • FAX: (704) 525--0409 1--·•.t· t :1:: E. Cl l ff v::, ·:· ~-::-·.- : ~ ~ 0~1 ~lbet·~at·lE ~d Customer Code: RAM G~=~• LAB I.D. AA08079 Bc~d 12 E ;:::~:.·:c,.= C.1 F !•: !:, ~.:::•:7·.ei;.-,E ._. h~.: ,:: :~~~BG!~ ~~-1i~~C~i~OR1D~ l . .::.-c rc~,;_o~::j[~[l~ZE!"lE l a :?:-DI CriL..C1 P.or.: r-~ z E:-'.:: :.. 4-DIC~!:_OROEENZEr:~ DICHLORC~IFLLJQRQ~[THAN~ 1. 1-DICHLOROETHAtJE 1.2-DICHLOROET~ANE 1. 1-D ICl~~'=•FC'ET•'E! ,E TRA\IS-1. 2-[1: c:·!-!LD:=::ci==ih~r,!~ 1:2~DltriLOROP~OP~l·'.E C!S-1.3-L!C~LORQPRO~•~r(~ TRANS-1.2-DICh~OROP~□PENE ~~T~~YLEN~ CH~ORlDC 1. 1. 2. C:'-TETF:HCHLOf'DETHHt✓E TETRPCHLOROET~iE~.:~ Cf .C: 1 ·.:~/kr: ,_,, □ / j-:; □ '-'· □ / ~ □ l_'.Q / IJ. C I_'.'::/ k □ 1_:_ O ,' P. C ".l= I~'.~ 1_1.8/l-:o ,_:_ C! :' 1-: C; ·-t~/~c •_to/ k o '.'.~/I-:~ :J::::: /\-: C u □/ko uo/k~ uc;/k □ 1_to/ko u □/k~ TE'.=T i:.,:: .. c.:• 1: T . ·----' 0 RGC.:r~ I c~ \).-.... I; [~t ~,; :·t DEt r·, =: = ,, t ~; :,t [,o+ t·,.: t. Di;t r,!:: t [,e1:.· f•i .-.... • -C [, (: t ~-lot Det i-: .:-t Let :-.: C; -t L-2t j•,: a !-[,~ t N~t I\et N:•t Det Nc,t Det I'~ C· ': Det ~~ ~t Det p; .,, t Dat riot Det 1,~ ::-t Det r~a t Det Nc•t Det Not Det Net Det 2~=;84 449 SPRINGBROOK ROAD• CHARLOTTE, NC 28217 [·::::-:: ~ !J~·-.: I : '< l T i ,-,. ...,., .;. .... - 10~' 10('.1 1 :Z,,i~l 1 C,:iJ 100 1 [1!2• 1121 121 1 131?t 100 I I I I I I I I I ANALYTICAL TESTING & CONSUL TING SERVICES Ram LE at t-, er C2f'rOtSOX 31486 •CHARLOTTE.NC 28Z31 • TELEPHONE (704) 527~163 • FAX:. {704) 525-0409 Paae: 2 OctotEr 30. 19'l1 HALOGENATED VOUH!LE ORGANICS (cont ir:1.led): 1. 1. 1-TRICHLOROETHANE u □/ko Net Det 1.1.2-TR!CHLOROETHANE 'J.□/ku Not Det TRICHLOROETHENE u □/ho Nut Det TRICHLOROFLUOROMETHANE •.to/ k □ Not Det VI 1-JYL CHLORIDE IJ □ / k □ ~~Gt Det I~·E 1.t □/k □ Nc·t [,et t"'.TBE l.t □/l-,:□ I,,: t Det PTC:X uo/ko N~t Det M!NERRLS s1:•JF.ITS mo/~~□ es.0 1 (lt2: 10:Z: !OC. 10,~ 10~ 10:2\ 1 iz~0 100 .5 ------------------------------------------------------------------------ Commer.ts: borino neat· tank oad. Customer Code: RAM Ph~~e N1lrn~2r·: (704) 545-~7~7 LAB I.D. AA08080 Ecld !D Number G2S2~-21 Eold Cust~rnE~-N~~b~~ S?~~ c~llectio~ Date: 0g;18/Sl cc:le=~iGG Time: 14:20 S·.tt~itt2l [·~te: 0S/20/~l ;~t □itt2l ~-i~e: 02:0S Cr.\stcrr.~·r· Sarr.=•le I. Df':: B-1. 10' ------------------------------------------------------------------------ Tl:~-T ~•Af-::AIT'\ETEF: TCST R:=:SULT ------------------------------------------------------------------------ I ~·Jltic0~c0~ert 2~2lvsis: HALOG[N~:T[D VOLATILE ORG~NICS t:!:/kc '-~□/~.□ l.l □/1--;Q u.u/1-:□ 1.\U/k □ '.\DI k □ 1.10 / ~ D uo/ko •.:□I~'. c 1.l □/ko 1-1.0/\.-:□ ua/ko uo/ko u □/ko u □/ko 1.\0 / k D 1~0 / k D l.l □/k □ IJ □ /k:J 1.1.0/ko IJQ/h:Q 1.1 □ /kn I-let Det Nc-t Det Nc·t [•et ~-lot Det Net Det Nc•t Det t~c-t DEt tfot Det ~~-:-t D•?t tfot Det r<e:t Det Nc,t Det Not Det Not Det l,ut Det Not Det Not Det Not Det l·<ct Det Nut Det Net Det Not Det I I H I ffl E ~:IJ'.·'.OF Ct ~:l•l EF:O!f"iCMETH1~:~E CARSON TETRACH~ORIDE CHLOF:DEEf\Z Er'-!E CHLfJROlTH~ic,JE 2-CH~ORDET!-{YLVINYL ETHER CHLO~:O"OR:,, DIBROMOCHLORO~~THA~E l.2-D!CHLORD2ENZENE 1.3-DICHLOROBENZEl~E 1.4-D!CHLOROBENZENE DICHLORODIFLUOROMETHANE 1. 1-D I CHLOROETHAl"E 1.2-DICHLOROETHANE 1. 1-DICHLC•RCETHENE TRANS-1.2-D!CHLORCETHENE l.2-DICHLOROPROPANE CIS-1.~-DICHLOR□PROPENE TRANS-!. :O-DICHLOROPROPENE ~ETHYLENE CHLORIDE 449 SPRINGBROOK ROAD • CHARLOTTE, NC 28217 1 (1C1 ~ (HJ 1 ('Hj · 1 (:ci2! .100 1 (.'l 0 10t?J 10121 100 100 100 100 100 100 1.01?1 ll2t0 100 10121 I I I I I I I I I I I I I I n D m m Bold Research Labs Incorporated ANALYTICAL TESTING & CONSULTING SERVICES Ram Le at her C J,0,!JOX 31486 •CHARLOTTE.NC 28231 • TELEPHONE [704) 527-4183 • FAX, {704) 5254<09 Pace: 3 October 312\. 1991 HALOGENATED VOLATILE ORGANICS (continued): 1. 1.2.2-TETRACH~OROETHA~E TE-TRACHLOROETHENE 1. 1. 1-TR I CHLOROETHANE 1. 1.2-TRICHLOROETHANE TRICHLOROETHENE TRICHL□ROFLUORO~ETHANE l.'!NYL CHLORIDE IPE MTEE BTEX MINERALS S!=IRITS u □/k □ u □/ko •.to I k D u □/k □ Ua/ko 1.1,0/k □ 1.1.0/k □ u □/ko uc/ko u□/1--'.□ r.i □/k □ Net Det 2868 Net Det Not Det Not De t Not Det Net Det Net Det t\J,:,t DEt Nc,t De t 7. 12\ 112\0 101l• 1~10 1012\ 100 1 e1121 1 0iJi 10(~l ~ 01zi 1 Qll~l ------------------------------------------------------------------------ Cc,r.:r.:er:ts: ~orinc neer tank 02d Custo ■er Code: RAM P~.or-:e N,.:_r,=,e~·: {70-4) '::·~-5-S727 LAB I.D. AA08081 Fcl~ ID N:!mbet· G3g8H-21 Bal~ c~sto~e~-N·~~bet· S7~S Cc!le=tic~ Date: 0~/18/~1 CcllectiG~ Ti □e: 15:00 EJbmitt2i ~ate: 0S/20/Sl Ci.lstc·r..2"r'' Eamole la Cr#: B-1. 15' ------------------------------------------------------------------------ TE:C:T ~•ARAMETER TEST RESULT LETECT l or-~ LI t'r~ IT -------------------------------------------------------------------------- ~1J!ti=c~oonent analvsis: HALOGENATED VOLATILE ORGANICS ERQl1GCIC~LORD~ETH~NE 2 R~1~DFOR!'1 CA~BON TETRACH~ORIDE Ci-:L..QROE E~JZ ENE C!-::...o RC1E::T ~i:1:,~E 2-C!·'.LOR:OETHYL') ! NYL ETHER CHLOROFORM CHLOFiOl~ETHANE DIBROMOCHLOROMETHANE 1.2-DICHLOROBENZEl~E 1.3-DICHLOROBENZENE 1.4-DICHLOROBENZENE DICHLORODIFLUOROMETHANE 1.1-DICHLOROETHANE 1.2-DICHLOROETHANE 1. 1-D I CHLOROETHENE TRANS-1.2-DlCHLOROETHENE 1.2-D!CHLOROPROOANE CIS-1.~-DICHLOROPROPENE •~~.•k~ ~0t [•et ,_:,c/k □ 1_1,0/ko l.\:J / k O 1Jo/ko u □/1-:□ uc/i-<o IJQ/\-:Q uo/:--:o u □/ko 1.10/ 1-:: 0 1.1.□/k □ l.l □/k □ 1.•.0/k □ •.to/k □ :.i.□ / k □ UD / k D •.i.o/ko 1_:0/k □ •~□ I k o Not Det !-.Jct Get r~ut L12t Not DEt Not [•d Not Det 1-Jc,t Det ~\ct Det Nc,t Det Not Det ~,at Det Nc,t Det Not Det Not Det Not Det Not Det N-ct Det Not Det 449 SPRINGBROOK ROAD • CHARLOTTE, NC 28217 ! (', 10 · 1 Cl 1 ~' ! ,:, 10 10 1 C• 1 (1 10 10 10 10 112\ 10· 10 1 ('l 10 I I I I I I I I I I I I I n I m ffl ( 13old Re~~0~!Ch Labs] ANALYTICAL TESTING & CONSULTING SERVICES Ram Le at r. er C.sP,Oaiox 31486 •CHARLOTTE.NC 28231 • TELEPHONE (704) 527-4183 • FAlt (704) 525-0409 Pace: 4 October 30. 1991 HALOGENATED VOLATILE ORGANICS <continued): TRANS-1.3-DICHLOROPROPENE uo/ko METHYLENE CHLORIDE uo/ko 1. 1. 2. 2-TETFCJ'<C:cic..OROETH>'l'!E uo/ko TETRACHLOROETHENE uo/ko 1. 1. 1-TR I cH:._QF;[;ETHH~~~ 1. 1.2-TRICHLOROETHANE TRICHLOROETHENE TRICHLOROFLUOROMETHANE ,, I NYL CHLO F: I DE IPE !",:EE BTEX t~INEFHL'::, S!="·lRITS uo/1--'.c lJ □ / ~; □ lJ0 /i-< 0 i.to/ko IJO/~{Q 1.t □/k □ IJ!J/!-<□ 1.:.C!/Ko mo/ko Not Det Not Det N·ot Det 28 Ncot Det Not [,et Not Det Not Det Net Det ~!at Det t\e:t D~t Ni:t Det 4.0 10 10 10 10 10 1 Q', 10 10 10 1 0. 10 :0 ------------------------------------------------------------------------ Co!:'.r.:er.t s: borino nea~' tank oad Customer Code: RAM Ph::~:E r·~1.trr:!::::-€t"! (70-'r) 54=:.-s7:::,.7 LAB I.D. AA08082 Bold ID N·.1~ber G3~3~-21 Bcld C,.tstc~~~ N~nb5~ ~-7~~ Collection Date: 0g/18/91 [Glle=tion Ti~e: 15:20 SiJbmitt~r DatE: 0~/21~/Sl c~15tomer Sarnole I.D#: B-1.20' TE':O T l='H RH~l::::T ER UNITS ~ultico~~o~e~t a~alvsis: H~LOSENATED VOLATILE ORGANICS I? ~:Ot":OD ! C.1-:LDR:Jt<C:::T:-h:.iriE E~::Jl<DFOR!,,: E.ROr':DMC:THHf'~E CP..~E.CJN T!::."TKACt1LDt~ ID~ CHLOROBENZEr~E CHLOROETHAr,iE 2-CHLOROETHYLv:rJYL ETHER CHLOROFORM C'-lLOROi"ETHAI JE DIBROMOCHc..OPO~!ET'-l~NE 1.2-DICHLOROBENZENE 1. 3-DICHLOROEEr,ZENE 1.4-DICHLOROBENZENE DICHLORDDIFLUOROMETHANE 1. 1-DI CHLOROETHAt,JE 1.2-DICHLOROETHANE L 1-DICHLOROETHENE ~RANS-1.2-DICH~OSOET~~~~ 1_•.c /kc u □/ko uo/1-.:□ 1.'.C I k C! l.'.::J / I-: .:::3 l_lD / ~'. 0 1_·.□ /l-'. C '.\D/ko uo/ko u□/k □ u □/ko '-',□ I k D 1_:0/k □ ·.t □/k □ 1.\0 / l{D :_·.[i/k □ N~t DE-t Net [ie t Net Det ~bt Det ~,ct [;et Not Det ~kt Det Nc•t Det Not Det Not Det Not Det Not Det r•.)ot Det t~c,t Det Nwt Det J\lc,t Det 449 SPRINGBROOK ROAD• CHARLOTTE, NC 28217 r.c:ccrror·! LIMIT ~ C) 1C: 10 10 10 10 10 10 i0 10 10 10 10 10 10 10 I I I I I I I I I I I I I I ANAL YTJCAL TESTING & CONSUL TING SERVICES Ram Le at her C;f194lQX 31486 •CHARLOTTE.NC 28231 • TELEPHONE (704) 527-4183 • FA)C (704) 525--0409 ~·ace: 5 October 30. lSSl HALOGENATED VOLATILE ORGANICS 1,2-DICHLOROPROOA~E CIS-1.3-DICHLDRDPROPENE TRANS-1.2-DICHLOROPROPENE METHYLENE CHLORIDE 1. 1.2.2-TETRACHLOROETHA~lE TETRACHLOROETHENE l. 1. 1-T F. I CHLO ROETHHNE •. 1.2-TRICHLOR □ETHANE TR 1 C!-ii_OROETHEt·~E TRICHLOR□~LUOROMETHANE 'JHNL CHLORIDE !PE ~•1TEE: ETEX :'~: t·~EFS-1~S Si="· IR I TS (continued): IJ □ / k 0 ,.,□ I k □ uo/kc u □/ko 1_;0/ko 1.l □ / ~ □ 1.1.0 / k 0 •.lo/k □ 1.l □/k □ uo/1-:□ uo/k:3 •.•.o/ko '.•.c/kc U:J / k o mo/s.o Nat Det Nat Det Not Det Nat Det Nat Det Not Det Net Det Not Det Nat Det Not Det Net Det Not Det Net Det Not I:Oet ------------------------------------------------------------------------- Cc~:,er:: s ! bo~·in □ rea~-ta~k cad Customer Code: RAM Phone N·~sbeY: LAB I.D. AA08083 Sold !D Nu~ber Ccllectian Date: 0~/18/Si ~·.:t~ittal Cate: OS/20/Sl Cu~~ome~--~a~ole !.D#: B-1.24' ,: 704) =-~ =,-r=_:1737 c:~E~-2: Ee!~ C-~s~0me~- Ccllec~icn Ti~9: 1;:00 S1ib~itt~~ Ti~~: 02:C~ -----------------------------·------------------------------------------- TE'.::T PHP.~WIETER UNITS TEST RE~-UL T DE'TC.CT~Or< LI !"!IT -------------------------------·----------------------------------------- Mwlticocoa~ent a~alvsis: BRO~O[!C~LDror~ETH~!·l~ B0:~'.·;o=ci:'.r"I E S:C':<~~<ETi-:i=,:<E CRRBO'.~ TETRACH~OR~DE CHLOROBDJ Z Et',E CHLOROC:H-:,4:,E 2-CHLOROETHYLVINYL ETHER CHLOROFORM CHLOROt0 ETHi:,fE DIBROMOCH~O?OM~T~ANE 1.2-DICHLOR □BENZENE 1~3-Dl[HLO~osi~ZE~~E 1.4-DICHLOROBENZENE D!CHLORODIFLUDROMETHANE : • 1-D I CHLOROCTHRt,JE 1.2-DICHLOROETHArJE HRLOGENATED VOLATILE :.=.c ,' k o l,I. □ / k :i 1.\0 / 1--: C !.tu/ k □ IJO / h: 0 1_'_iJ/ko l.l □ / k C ,.,.o/ko 1.~0/k □ •.: o / k □ i.to/k □ uo/ho u □/ko 1_1.0/ko uo/k □ uo/ko ORGR's!CS t-.{e,t De~ r,:ot Det !,~-:) t Det Not Det Nc,t Det t'~:, t Det t·4 c-t Det Not Det ~ ~ C: t Det t,o t Det t·Jot Det ~~ot Det Net Det Not [,et Net Det Not D2t 449 SPRINGBROOK ROAD• CHARLOTTE, NC 28217 · 1 iZ: 1 ,.,., -''-- • I I I I I I I I I I I I I I I I D m m Bold Research Labs Incorporated ANALYTICAL TESTING & CONSUL TING SERVICES Re,. m Le at her CcP'IO.EBOX 31486 •CHARLOTTE.NC 28231 • TELEPHONE [704) 527-4183 • FAX: (704) 525-0409 Pa □e: E, October 30. 19',1 HALOGENATED VOLATILE ORGANICS 1. 1-DICHLOROETHENE TRANS-1.2-DICHLOROETHENE 1.2-DICHLOROPROPANE CIS-1.3-DICHLOROPROPENE TRANS-1.3-DICHLOROPROPEl~E METHYLENE CHLORIDE 1. l. 2 ... 2-':ET~:ACHLOROETHA~·-!E TETRACHLOROETHENE 1. 1. >Tc:JCHLORCJETHANE 1. 1.2-TRICHLOROETHANE TR I CHLOROETHEr,JE TRICHLOROFLUGROMETHANE <.'It·tYL CHc_OF:!DE IPE t<::·.::: B'.E)'. t'r'. I r<Er-:,HL.S S.C· 1 HI TS (continued): u□/ko u□/k □ uo/k □ l.l□/k □ uc/k □ uo/ko uc/1{:J u □/k □ u □/ko ,.,o/k □ uo/k □ •-i □/k □ u □/k □ 1_1.0/1-'.□ 1.',C /)-: 0 l_l.~ / k [! c,o/k □ Not Det Not Det Not Det Not Det Not De t h!cf; Det N-:t Det 1'3 fkt Det Not Det Not Det Not Det ~~ut Det ~kt Det Nc·t De t r,!~t Det 1. ,z, ------------------------------------------------------------------------ Comr.:e,;t~: bo,·i~2 nea,~ tank oad Custo ■er Code: RAM Pt--.o-:-:e N1.'.r.:::-e·,·: ,:704; 1545-:172-7 LAB I.D. AA08084 E-0!d ID N·.•.r.:'::e~-G~S2-H-~i Bs:C c:,_,.st:~e:· N=.tn=c:·,-t/L::: Collection Date: 0S/lg/91 Cclle=ti~~ Ti~2: 10:00 s~t~itt~l D~te: 0~/2C/S1 Cu~to~e1· Samele I.D#: B-2.5' ------------------------------------------------------------------------- TE~-T ~1P.RH~,,:~TER ut.ITS TEST ~E~-UL.. T LIMI"T" ------------------------------------------------------------------------ t:•.1.lt icor:i~orie:1t 3neo.lvsis: Ht=1LOGE~~~iTED vrn _ _r~; I LE ORG;:V-1 I CS BROKODIC~~OROt~ETH~!~E ._1.c / }-': C t,~ C· t Det : 1?· E !"Q:,10""0~"'. i_:.o / k □ r,: :,t [•et :c. BROMOMETHHNE r.1 □ik □ r-.;.:t C·E t 10 CARE,□:·~ TET F<HCr-·'.L..O~ I CE ;_i.~/ko NGt Det 10 CHLOROBENZEl!E u □/ko NGt Det :c CHLOROETHAt,E llC! / k □ tfot Det 1 Q1 2-CHLOROETl~YLVIt~YL ETl-'EF: IJQ /1-: C ~-~ ,:. t Det 10 CHLOR0"0":M uo/k □ Not Det 10 CHLO ROM,:THR!·iE uc/1-:c Net Det 20 DIBRO~OCHLORO~ET~AN[ •_1.0/k □ Not Det 10 1.2-DICHLORDBENZENE 1.10/ko Net Det ~ ;".', a' 1 • .3-D1 CH~CIF:OE:NZEnE ,.,□/ka ~~ot Det 10 1.4-DICHLOROBENZENE 1.10/ko Not Det 10 DICHLORODI~LUOROMETHANE •.1.0/ko Not Det 10 449 SPRINGBROOK ROAD • CHARLOTTE, NC 28217 I I I I I I I I I I I I I I ANALYTICAL TESTING & CONSUL TING SERVICES Ra_ m Le at he t"" Ca1r9~X 31486 •CHARLOTTE.NC 28231 • TB..EPHONE f704) 527--4183 • FAX: (704) 525-0409 Pace: 7 October 3121. 1991 HALOGENATED VOLATILE ORGANICS 1, 1-DICHLOROETHA~E 1.2-DICHLOROETHANE 1. 1-DICHLOROETHE~E TRANS-1.2-DICHLOROETHENE 1.2-D!CHLOROPROPANE CIS-1.3-DICHLORO~•ROPENE TRANS-1.3-DICHLCROPRO~•ENE METHYLENE CHLORIDE l. 1. 2. 2-TETRACHLOROETHA!'>/E TETRACHLOROETHENE , . , . 1-T r, l Cf~L_OROETHAt,JE 1.1.2-TR!CHLOROETHANE TRICHLOROETHENE TRICHLOROFLUORO~ETHANC VI ~~':'L CHLO RI [iE T r,C' ... r-.,_ t•::E.::=: BT~X ~:I\:Er,;:i:i~=-Sl='lRITS (cont ini.ted): 1.tc/1-':□ uo/ko 1.1c /ko LL □/ k □ uo/k □ uo/ko uo/ko u □/k □ '-'c,/k □ I.'.□/ k 0 uo/ko Lt□/ k a . uo/k □ !JO/ k □ uc/kc u □/ko •.,co/kc, me/I--□ Not Det Not Det Not Det Not Det Net Det Not· Det N~t Det Not Det ~~c.t Det 15 Net Det Not Det Not Det Net Det t,kt Det r-.:1:it Det r·-L:-": Det Nc,t [iet 10 1 e:, 111! 10 10 10 10 10 10 10 10 10 10 10 1 e: 1 lZl ---------------------"--------------------------------------------------- Customer Code: RAM Ph~::e t\•.:r.:be·r·: (704) 545-9727 LAB I.D. AA08085 P.Gld ID r-..J 1.1.mbe~-C=2c:~e~-~::::1 Eclc::'. C·.t-:.tcmc::':"· t,~•-1.rt-=,-~/L:5 C~llection D2t~: 09/19/91 Collecti~~ Time: 10:30 s,~~~itt~l D2te: 0S/20/Sl C•.•.sto □er Sa □ole I. D*t: P.-2. 10' TEST l="'P.F=:HMC::TER Multi=o~oo~ent analviis: HA~OGENATED VO~ATILE P.ROMODICHLORO~ETHANE uo/ko ERO~QFORM '!C/k □ BROMOMETHANE u □/k □ CARBON TETR~CH~ORIDE uo/k □ CHLOROP.ENZENE CHLOF:OETHANE 2-:--CHLO.ROETHYL'...1 n-r·t'L ETHEF: CHLOROFORM CH;_QROMETHH~~E DIBRO~OC~LO~O~'.~T~lA~E 1.2-DICHLOROBENZENE 1.~-DICHLOROB~!~ZENE uo/k □ ,.:□/kn :_,_e: / k o ,_1.0/ko un/ko •.'.c/kc u □/ku TEST RES1J~T CRG~INI CS N·:·t · Det Mat uet t\!e; t Det Nut Det t,ot Det Nc,t Det r~ c-t Det N :it Det Net [•et Nt•t Det N,:t Dct N·:it Det 449 SPRINGBROOK ROAD• CHARLOTTE, NC 28217 DETCCTI □r·,,; LIMIT 10 I I I I I I I I I I I I I I I I ANALYTICAL TESTING & CONSUL TING SERVICES Ram Le at her CcPrOS30X 31486 •CHARLOTTE.NC 28231 • TELEPHONE [704) 527-4183 • FAX: (704) 525-0409 i:·a □e: 8 October 30. 1'391 HALOGENATED VOLATILE ORGANICS 1.4-DICHLOROEENZENE DICHLORODIFLUOROMETHANE 1. 1-D I CHLOF:OETf-:A!<C:: 1.2-DJCHLOROETHANE 1. 1-D I cr.:_oRD::::THEi,a: TRANS-1.2-DICH~ORO[THENE 1.2-DICHLDROPROPANE CJS-1.3-DJCHLOROPROPENE TRANS-1.3-DICHLOROPROPENE METHYLENE CHLORIDE 1. ~. 2. 2-TET;::.~c!-:LDR0ETHHr··~= TETRACHLOROETHENE l. • .1.. l-TS.1:1-!LOFOETHA!~E 1. 1. 2-TF::C!-lL..Or-GE::THrl;~E: Tr:. I CHL.O~,OC:lHEt,!E TRICHLOROFLUDROMETHANE tJ I l<.':"L CHLOf: I [·E Ii:·E >:"":EE E'.EX r--:Ir·~c:r:,;::--i'....S :;:.;:•r PITS (cont ir1ued): 1.10/ko •.t □/ko •.c □ /kc uo/ko uo/k □ l.l □ / k □ IJ O / k D 1.to/ko :.i.o/ku 1.1 D / k O 1.1c/)--:c '-l □/ko 1.1.cik □ uo/k □ uc/k □ l.l::J / k D 1JO / k C '.to/ k □ ·.,c I k □ mo/!-·.c Net DE t Not Det ~--~-:-t Det N:it Det riot Det Not Det Not Det Not Det t-:ct Det Not Det Not Det 52 Not Det Not Det Not Det Ne:t Det N-2t Det Not I•et rJct D=t N·:-t D12t i. 1 10 10 10 1('1 1 Q: 10 10 10 10 10 1 Q"1 10 10 1 C· 10 --------------------------------------------------------------------- Customer Code: RAM Phc,;-,e t·~:_'.r..bc·.-: (7:z.0·1: 54=-~7;::.7 LAB I.D. AA0808E, Bold J[, l·brr,:,e·,-52921-'-21 ccld [,_:stoce,-l,'_:c:::·· ,-:,,:,s Co:lection De.-tE: 01:'/1Si/'.:il c~~l~::ti::, Tir.:~: 11:00 S:Jbmitt~l Dats: 0~/20/Sl C•.•.-=:tcr.e':'" Sa.~ole I. [i;;': B-2. 1'5' TES: ~•H;-:~'.-':E:. ":~ ~ UNITS Mi.\ 1 ti CG m ~-C•:": e:it <;,7"",alvsis: ~PL.OC:,E\!r.iTED VOLATILE E ROM OD IC ~:...Of=C-tl".[T!··'.P.i-..:E IJQ /l-: Q ERO:':OFOR:•, l.lG / k □ E,ROt-.OMETHRl·JC 1.t □ / 1-< o CARP.ms TETRACHLORIDE ,.,w/~~ CHLDRDEENZENE L.t □/k □ CHL.OROETHRl,E l.t □/k □ 2-CHLOROETHYLV!NYL ETHER r~tc/k □ CHLOROFDRI•, i.t,□/ko C !-i~O RO'.r~'.:::T~:H!'JE i_l.C /1-< C D!ERO!~OCHL.ORO~~THANE !.'.□/ 1--: □ TE:::T F:ESULT ORGR!·-!I CS Net Det Not Det Not Det r~ot Det Not Det 1, o t Det Nc-t Det t,ot Det Not Det Not Det 449 SPRINGBROOK ROAD• CHARLOTTE, NC 28217 ·L'ETCCT ! or-~ LI'.~: T 10 1('1 ,0 10 10 10 10 10 10 10 I I I I I I I I I I I I I I I I m m ANALYTICAL TESTING & CONSUL TING SERVICES Ram Le at her C£1:JeJOX 31486 •CHARLOTTE.NC 28231 • TELEPHONE [704) 527--4183 • FAY.: f704) 52:5--0409 Pace: ':i Octobe,· 30. 1'391 HALOGENATED VOLATILE ORGANICS 1.2-DICHLOROBENZENE 1.3-DICHLOROBENZENE 1.4-DICHLOROBENZENE D!CHLORODIFLUOROMETHANE 1. 1-DJCHLO~□[TliA~~ 1.2-DICHLOROETHANE 1. 1-D!CHLOSC~T~iE~JE TRANS-1.2-L!C~l~OROETHENE 1.2-DICHLOROPROPANE CIS-1.3-DICHLOROPROPENE TRANS-1.3-DICHLOROPROPENE METHYLENE CHLORIDE 1 ••• -· 2-TE;F.i:i:::--::._oF]E":HHhiE TETRAC~~~ORO~T~ENE .... 1. 1-Tr. IC!·'.L:J:'DETl-:i=:t<:":: 1. 1. 2-T!==:IC~L.O~'.OE.~HRr·-~E TF. I CHLC:F=•E-:-i-;Ct~E TRICHLOROFLUCROMETH~NE 1) I r·~YL C!••:~c~ ! DE I l=" !: (cor,t inued): uo/kc uo/ko u □/k □ uo/ko '·'·" I 1-: C 1.\0 / 1--: 0 1.tc/k □ 1 • .1.0/ka u □/ko uo/k □ u □/k □ uo/ko IJO / k □ 1.1. Q / i-: !J •.•.o I k □ uc:;iko ;.'.C: I kc =.:.c / !.; C ,_;_s/ko r.:c/l-.c Not Det Not Det Net uEt Not Det t\c·t Det t~~t [•Et Ncot Det Not Det Not Det Not Det ~~ot Det t,ot Det t,:.:t DEt Not Det Net Det N::it Det Net uet N,:-t Det t-~ Ct [:et ~-!:-I: Det ~\);:.t [·Et t·,ict [•et < • '5 10 10 12· 10 10 10 10 1 Q, 10 10 ~0 10 1121 10 10 10 1 IZ, 10 ------------------------------------------------------·------------------ c~r.:r.:E-1,ts: b~~·in □ ~e~t~ d~:m □ste~~ Customer Code: RAM P!-.o:-.e ~\-.•.m=::Et·: (70/,:• S4S-S727 LAB I.D. AA08087 Ei:,ld ID h:•;,rnb(·~-C:::;S2h-21 E.'c!d C•.'.stDn;·r· ~<:.r.::-~~-~7.:+:: Ce:lle-::tion De.te: 0CJ/1Si/<":!1 C-:,llecti:·r: Tir.,e: 1~:2:e: 51Jbrnittal Dite: 0S/20/Sl S 1JbmittEl ~i~e: C~:0S c~stomer Samole I.D#: B-2.20, -----------------------------------------------------·--------------------- TEST PA'iA~'ETER UNITS TEST RESULT C·ETCC~-IO!"~ !... I~! T -------------------------------------------------------------------------- M 1.t l t i corn c, c, r, er-, t o:-,al vsi s: HAL..DGE:'\r--1TED VOLATILE ORGRNICS Bf~OMODIC~iLORO~~THA~E u.□ /~,c Net Det 10 BRO!".OFOF:'.~ u:i/kc: N~t Det 1 C" E-ROr•~□r--,ETHAr·~::: 1.1.□/ko Net Det lC Ci'.=iREO'.·J "T [T t':HCHL..O R 1 DE :_:o/k □ Not Det 10 Cf-'LOROBENZENE u □/ko Not Det .10 CHLOROETH;::NE l.'.:l I K:} Not Det 10 2-CHLOROETHYLVINYL ETr1ER IJ □ / I-: ::l t--~ Ct [·e: 1 C'! CHLORO'""ORM u:::1/~o Not D£t 10 449 SPRINGBROOK ROAD• CHARLOTTE, NC 28217 ~ I I I I I I I I I I I I I I I I I ft ANALYTICAL TESTING & CONSUL TING SERVICES Re.-m Le 2. the r C~a30X 31486 •CHARLOTTE.NC 28231 • TELEPHONE (704} 527--4183 • FAX: (704) 525-0409 ~-~ce: 10 October 30. 1991 HALOGENATED VOLATILE ORGANICS CHLOROt'.ETHAr;E DIBROMOCHLOROMETHANE 1.2-DICHLORDBENZENE 1.3-DICHLOROBENZENE 1.4-DICHLOR □BENZENE DICHLORODIFLUOROMETHANE 1. 1-D I CHLDRDETHHNE 1.2-DICHLOROETHANE 1. 1-D I CHLOROETHEt~E T RA:-~s-1. 2-D I C.:HL0F:0~THt:~ .;c 1.2-DICHLOROPR □PANE CIS-1.3-DICHLOROPROPENE TFAr~'.=.-1. 2-D I C!~LO ROP F:Oi=·EN[ ~ETHYLENE CHLORIDE 1. 1. 2. 2-'.E:'~,HCHLIJG.C•::=-:-:---:1:.:·:~ 7ETRACH~OR0£THENE 1. 1. 1-TR!Cl-~~080[Ti-ii:-1'.•'.E: 1. 1.2-TRIC~i~OROETHA~E TR I CHLOROETHEr:E TRICHLOROFLUOROMETHPNE ) : N\'L C~LO~ I DE I ;::•c:: C'Jr:;mer-it s ~ b □l·i~G ~ea~~ du □~stet~ (continued): I.ti:::/ k [j l.l □/k □ uo/~<□ u □/1-:o uc/kc I_\ D / k 0 ·.·.o/ f--'.c •.1.c / ~: o 1.1.0 /\-; C •..to/kc u □/k □ 1_1.0/k □ VGlh"□ '.'.CI k D 1_:c /kc 1.:c/ko •.·.□/kc ;_to/k □ l.iO / ~:□ •.iO /\.-: D l_!,O /1-< □ l.',0 / !-: :J .-.~/kc 1_:. :J / 1-: 0 r.:c/ko Not Det Not Det Not Dot Nc;t Det tfot Det Nc:t. Det !-l,:t C·.:t Not uet ~~ct [•et Not Det Not [,et N0t D~t ~kt [ct Net De~ ~\let I)Et 334 30 tfot Det Not Det ffot DEt t<c:-t DE·t Not Det ~~-:-t [·et Not [!et i:... • ..:, Custo ■er Code: RAM ~,:-.o::e ~<·.1:.it:e·:·: (70Lr) 545-97:::,7 LAB I.D. AA08088 Es!d ID t~•~□ber· G2~2H-21 E:l~ s~~tc62t· Collectio~ Date: 0~/1S/S1 s~:~~itt~l Date: 0~/20/S: C1~Eto~e~ Samole I.D~: B-2.25' TEST PARAMETER Mi.t l ti com DO ii E-r;t 2,r.alvsis: BROM OD 1 [~-::....c1 :=;-:o'.~.ETHHt·~E EROMO"ORM 2-qc,~□-~":::!1-:H\'.E CARBO:,; TET;;:ACHLO?7:!DE CH~ORGEENZENE CHLOROETHAt,E UNITS .HH:....OG~NATED 'v1D'....AT I ~E 1_:c/!--:!:! :.to/k □ ,_1.0/ko 1-li::i/ko u □/k □ •JD/ k :J TEST RESULT O,lGANICS Net Det Net Det Not Det tJ::) t Det Net Det Not Det 449 SPRINGBROOK ROAD• CHARLOTTE, NC 28217 10 10 10 10 10 10 10 : c- 1 t?l 10 10 10 10 10 10 DETECTION LI~:IT ! Q, 1 c, 10 10 10 1~ I I I I I I I I I I I I I I I D ANALYTICAL TESTING & CONSUL TING SERVICES Ram Le at h Er C~~X 31486 •CHARLOTTE.NC 28231 • TELEPHONE (7041527-4183 • FAX: [704) 525-0409 Pe.□e: 11 October 30. 1':c51 HALOGENATED VOLATILE ORGANICS Cco~tinuedl: 2-CHLOROETHYLUINYL ETHEP uc/~c CHLOROFORM u □/k □ CHLOROt'f.ETl-:At-~E DIBROMOCHLOROMETHANE 1.2-DICHLOPOEENZENE 1.3-DICHLOROBENZENE 1.4-DICHLORDEE~ZENE D!CHLORODIFLUOROMETHRNE 1. 1-D I Cf-'.LORC•ETf~A!·-1E 1.2-D:CHLOROETHANE l. 1-CIC~~~OROETl-:ENE TRANS-1.2-D!CHLORO~T~~~E 1.2-DICHLOROPROPANE CIS-!.3-D!CHLOR0~1RO~EN~ T~At~s-:.~-[ICHLOROPRO~ENE METHYL~~~ CHLQRID~ 1. 1. 2. 2-T!::TF:PCt-!LtJRQET!-{H'.'J~ TETRQCH~OROETHENE : • : • 1-TS: lJ:~·L .... CS:OCTl-:Af'~E 1. 1. 2-T"ICi-:~Ci;,:O~Tr1i=:~-::: Th! C~'.L._Or-:CiET~::!·!E. TR~C~LORO~~UQPO~~T~.0t~E ·: r t·~-✓L c:..JLOF I ei::: ~~":E-E e.TE)'. Ccrr.~er,t s: ~c~·in □ ~e~!~ d~rn □ster~ 1.1.0/k □ r.:.c:/ko ,_,o/kc, t.to/ko U:J/k □ '.1.C / i-; C. UC/~: 0 l.\U / i-< C 1.1.0/ko i.~o/l-,;o u □/~c, 1_;.c/ke: i.t □/k □ 1_,,c i 1-: ~ I}::;/ k :.J ·.-~/l-:c ·.\ :J / :-: ::; Cust □11er Code: RAM ;:•:--,=,-,~ f·l•-•.r.:::e,-: (7'?',) 545-9737 t·-!:: t Det Not Det t·; ,J t Det Not Det t·fot Det t-!Qt Det N:t Det Not Det t·~ c, "'.: De~ Nc,t Det Net Det Not Det Net Det N•Jt [•et ~-~ ct Dct· t-~ Q-: D:t t·' ,-_ -1- ' ' -·-!:.·E: t-..! Qt Det ~. ~, r-.:ot Det N:t [' ·= t ~ L:.,t ['et N-:t I:: Et (\l,J.. , ~ C [,et :-~ :-"'; [-;;: tfot [·et < ~ ~ 1 I} 10 10 10 10 112-· 10· 10 10 10 10 10 10 10 10 LAB I.D .. AA08089 P.:ilC IC· ~-:.·.n:ie~· C:~-1:<2'.~-:·: !:-:ld C·.tstcmer ~~,.~::::, E-.7.:,-::- Callection Date: 0S/1S,'Sl [Gllec~i0~ ~~me: 0S:45 Eub~ittal Date: 0S/20/Si S=;b~ittal 7-i~e: 08:09 Customer Samole I.D#: B-1 WATSR TEST PARAMETER ~~lticom8onent analvsis: SF:IJ!:;Q[; I CHLQROl"iETHH'.<:::: E~0!1':0:=-0F'.'.Y: E, S:C~·1CH11ETHAt·~E U'HTS TEST RESULT HALDGEN~TEC l □LATILE ORGA~ICS ~:=,'L Net Det '-'-~ /L •-·-~ /L ,_,c /L l·/ot [,et Net Det Net Det 449 SPRINGBROOK ROAD • CHARLOTTE, NC 28217 DETECT Iot..J LIMIT 1 1 I I I I I I I I I I I I I I I I ( Bold Re~~0~!ch Labs] ANALYTICAL TESTING & CONSUL TING SERVICES Ram Le at her Ccf')OffiOX 31486 •CHARLOTTE.NC 28231 • TELEPHONE [704) 527-4183 • FAX: f704) 525-0409 Pa □e: 12 October 20. 1'391 HALOGENATED VOLATILE ORGANICS CHLOROBENZ El:E 2-CHLOROETHYLVINYL ETHER CHLOROFORM CHLOROMETHA~E DIBROMOCHLOROMETHANE 1.2-DICHLOROBENZENE 1.3-DICHLDR□e~NZENE 1.4-DICHLOROBENZENE DICHLORODIFL~□R□METHANE 1. 1-DICHL~ROETHANE 1.2-DICHLOROETHANE 1. 1-DICHLOROETHENE Tr::.1:i.!--::.-~. 2-DIC:-'.:....OROETHE~·~E 1.2-DIC~i:...O~□~•RDPA~E CI~-1.3-DICHLOROPRO~·::::t;E TFANS-1.3-DICH~OROPR□r•E~E M=T~YLEK~ Ci~LORIDE 1. !.2.2-TETRAC~~OROET~~~E :'ET Rl=C H:....O i:;:1:)E T~~[~<E 1. 1. 1-TRIC:HL.DRDET~iA'.~E : . ~. 2-TF I CHLOR.C.)i.::Tl-:~~>:~ TRIC~~~ORO~LUORO~ET~ANE \1INYL CH'..-OF!DE ci-::...o~OE"THHt·~E c:s-1.2-~IC~~ORDETH~l~E E~-:--i'·.fL-E;-~~ E ;=.-:-:-·. ! [·E MTB'.:: I i:•z: P,::::r-~ZEi~E TOL.UEi·~[Z E'.:-'.\!LP-E:::~--! Z E>.:E XYLEt-:-=: ( c o:-,t i n•.,ed) 1_,c/L l.lO /L ,.:□ /L uo/L l.'.LI /L ,.,□ /L IJ □/L u □/L IJ.0 /L •:.□IL ._,c /:...._ i:.o/L t_; C / ;_ u □/~ •.i.c/L ,.,o/L :_tc, " ~ ,_,o /L '.t.c /L · •. c /L =.•.c /L ·.:c /t_ IJ. c /L ._1.:::J/L u.o/L 1_:w/L ,_,c/L I_I.D /:...... !.tC/L :.i □ /~ l.lU /L i_t:: /L :_\C /L_ t~c t Det Not Det N:•t Dct Not Det !'~Ct Dot Not Det r~ut Det Neit Det Net Det -.~ .::.c t·,,; Gt Det !'~ :,t Dd 13 Not Det N-:-t Det ~<-:-t DE·t 78 ~JG t Det ':12'0S0 66'i7 l 12 830 Not Det t-~ ot I•et Nc-t Det ~-! ct De:t N-:t De-t 41::, Net Det ~~ ot Det 13 Not Det t-. -:.. ... ·-... Dst 1 1 1 1 1 1 -1 1 1 ' • 1 1 1 1 1 1 : ' 1 1 ' • l 11:0 : G;: --------------------------------------------------------------------------- Ci:r.ir.:e-:-,ts: water~ f1·om jc~i~~ Custo ■er Code: RAM P~one N,_,.rnt:::-e-r: LAB I.D. AA080'i0 Bald !D Collection Date: 09/19/'il S 1Jb~itt2l D2te: eS/20/~l C~stcEe~ Sa~ole I.Of: B-2 WATER E':. : C C ·.<.st c r., er Collection Time: 14:00 S·JtQitt~l Ti~e: OS:0g ---------------------------~--------------------------------------------- TEST F~~-U~ T ------·------------------------------------------------------------------ 449 SPRINGBROOK ROAD• CHARLOTTE, NC 28217 I ANAL YTJCAL TESTING & CONSUL TING SERVICES Ram Le at he,-C£i0~X 31486 •CHARLOTTE.NC 2"231 • TELEPHONE (704) 527-4183 • FAX, (704) 525-0409 Pace: 13 I October 30. 1991 Multicomoo~ont analvsis: HALCCENATED VOLATILE BROMODICHLOROMETHANE BROMOFORM BROMOMETHANE CARBON TETRACHLORIDE CYLOROPENZENE 2-CHLOROETHYLV!NYL ETHER CHLOROFORM Cr-!LORQMETf--iANE D!BROMOCHLORO~ETHAN~ :.2-DICf--iLOR □BENZENE 1.Z-DICHLOROBENZENE l.4-DIC~LQROBENZE~~~ □:CHLORODIFLUOROMETHANE 1. 1-DICHLOR:JETrcA~:E 1.2-DICHLOROETr-!A~E ;.. 1-DIC!-:i._OF:OETHE!~C TRA~S-1.2-D!CH~OROETHENE 1.-~--D!:~~~O·ROPROPANE TR~~S-1.3-DICHLORO~•RGPENE ~ETYYLENE CHLOFIDE l. ~. ;:.·. 2-TETRf-iCH:...□R;:1 ::l!-~:A'."<E TETRACHLOROETHENE :. 1. 1-T~:!Cl-:'._C:RDE:T~H~-t~ 1. 1. 2-TR I CH'._ORDETHA~~E T; I Cl-'LQROETHC:!'.C ~P:CH'._OR□FLUORO~ETHAf~E 1) 1 t<>'L C!-iLC1f': [•~ C~'._ORQETH~::'.!::: '=°TU''I c-·•,•-::--... 11.....~, .. - u □/L ,.,o/L ,.,□ /L ,_,c /L 1_lo/L uc/L '.l □ /L l.'.C /L uo/L 1.10/L uo/L !JO/~ 'JO /L uc/L u □/L .. r, /' ._,_, - •_1,0/L uo/L u □/L 'J!::/L :_tc/L· uo/L_ i_•.::i/L l.l □ /L ,_,,c /L. •;.!J /L uc/L or.:ecr.1, r cs Net Det ~~ -: t !;et N:,t Det ~>JO t D2t tfot Det t·Jc t Dot t,ot Det N·:t C·et Not DEt ,, C: t Det Not Det t,~ :. t C-et Net Det Nr-+-[et 1 ' • Not Dct Nut Det ~-\ -,l.. [•=. '" --' :~ ~t [·;;:t I<:• t [;::: Not Det ~~ ·= t De: 1201 2C l\!:t [; et :0 t,!ot Det \:~ Det r--i 'J t Det f\~•2 t [; t; t: Not Det Not Det ~-'.ct [et NGt [;et MulticomoJ~e~t 2~2lvti5: AR8~~TIC VOL_ATI~E [' F:G :,:;n I CS BENZENE CHLOROEENZENE 1.2-DICH~ORCBENZENE 1. 3-DI cH:_oROBEi~ZEt~E 1.4-DICHLOROEENZENE ETHYL BEh!Z EI\I~ TQLUEt:E )'.Y~Ef·~r: M~THYL-TEFT-BJTY~ ETHER I S'.JPF::OPYL [THER I•-. /! _,_ i -- uo/L '-'-□ /L u □/L u □/L ;_,_2 .IL :_:,c /L 1_1,0/L. t-~ ;:, t Dot Not -Det Nc,t Det Not Det Not Det ~~ ~t Det Net Det i..1,.. + .\; -., Det 1-,J,:~ [,et Not Det 1 1 1 I 1 I I 1 1 I 1 1 1 1 1 1 1 1 I 1 I I I I I I I I I I I I I I ffl ------------------------------------------------------------------------- I 449 SPRINGBROOK ROAD• CHARLOTTE, NC 28217 I I I I I I I I I I I D I m m D I ANALYTICAL TESTING & CONSUL TING SERVICES Ram Le at J-: er Ca'IOmDX 31486 • CKAALOTTE. NC 28231 • TELEPHONE [7041527-4183 • FAX, [7041525-0409 Pa □e: 14 October 30. 1991 Comments: water fr~om borin □ Custo ■er Code: RAM Phone Number: (704) 545-9737 LAB I.D. AA08091 Bold ID N~abe~ E398H-21 Pcld Customer Collection Date: 09/18/91 Collection Time: 11:00 Eu~~ittal D~te: 09/20/~1 Customet~ Samole I.D#: B-3.4, TEST PARAMETER UNITS TCST RESULT ~74S DCTCS:"IO'.\: LI '.Y:l T ------------------------------------------------------------------------ Mu~tico~co~ent £nalvsis: HALOGENATED VOLATI~E PF□ M □DICHLOROMETHArlE ~□/kc E-F:O~OFOR:V: PFOMOMETHANE CHLOROBENZENE CHLOROETHA~,E C!-t .... OROFOt::M C!~'......O ROt"".ETHPl·-!E 2!ERD'.~□CH~ORO~~TH~~~ :.2-DICHLOROBENZENE :.3-DICHLOROBCr~ZE~~ 1.4-DICHLOR □BENZENE DICHLORODIFLUOROMETHANE 1. 1 -[, I CHLO,CJETHA\'E 1.2-DIC~LOROETHANE 1. 1-D!C!-:LOROETHE\IC T F.At·:~---1. ~-DI C!-IL._DF:·oE:"~E~-.:~ 1.2-DICHLOROPROPA~!E CIS-1.3-DICHLORO~·RO~ENE TRANS-1.3-D!CHLOROPROPENE METHYLENE CHLORIDE 1. 1. 2. 2-TETRi::CHLORO=:THA~<E TETRACHLOROETHENE 1. 1. 1-TRICHLOROETH!'/;C 1. 1.2-TRICHL.ORDETHANE TR I CHLOF:OETHEl<E TRICHLOROFLUOF:OMETHArlE VINYL CHLORIDE !PE l~TEE BTEX f"INERAL.S SP!RITE uc/kc ;_1,:::/kc l.l □ / ''. C ,_,o/ko ,_,c / \-,;.:::: I.T.□/k □ • .. ::/kc u □/k □ l.l□1 /k □ 1_:_01/kc uc·/kc 1.=.i:: / 1-: C 1:.~/k!J 1.•.:::::i,/kc 'JC/~ D 1•1 • .: / :-< C u::i(ko r.1c/k □ 1.,c/ka I.~□ > k 0 1:.=fk:i UD / k C 1.10 / K □ t.l □/k □' 1.\2 /1-: 0 1.1.□/ko r.:o)l,c □::::GA~·.J ! C£ .. ' -~-[,d· 1 c, " -. Net [, '= -!:: 10 Nc-t Det lC: .. , -~ l'O·..; c. r, -J. ~e, ! 12! Nc·t Det ,, .i.•.:..· Not Det 1 :z, r<-: t [,Et ' ,, .;. '• r~ ::-t [1 e-t ' ,0. H' r-~w t [,2t : ::?• ~~c-t [•et ' ~ --.:..· r,J Ct Det .!.le".' ~~wt [•et 1 ;21 I·' -• . -. [·et 10 Not Det 10 t-<ct [•Et 1 C-: ~~ ot Det 10 t< c_ t DEt 10 N~t [,•e -t 1 Ci t-..! Ct Dt: t ·1 I? ~<:, t Det !Ci ~-~st Cet 10 N'2t [•et 1 e, h'.at Det :o ~-iot Det !0 :E : Cl ~~c,t Det 10 Net Det : ;zi I\! :it Det 10 Nat Det 10 Not Det 1 Q1 Nc.t DEt 10 \l::t ['et 1 Q1 < 5 ~ . . ---------------------------·---------------------------------------------- 449 SPRINGBROOK ROA.D • CHARLOTTE, NC 28217 I I I I I I I I I I D I I I 0 ANALYTICAL TESTING & CONSUL TING SERVICES Ram Le at her C£lG~X 31486 •CHARLOTTE.NC 28231 • TELEPHONE (704) 5274183 • FAX: (704) 525-0409 Pace: 15 October 30. 1 c.c. •. --. Comments: borin □ neat' sectic dr'ain box Custo ■er Code: RAM Phone N>.1mber: (704) 545-5737 LAB I.D. AA08092 Bold ID N·Jrnb~r-G3~8H-21 Bold _C 1Jst0mer Nurnbet· S745 CollectiGn Date: 05/18/gl Collectio~ Time: 11:20 S1Jbmittal D2te: 09/20/Sl ·c~stcne~ Sa~~le !.D~: E-3.7~ ------------------------------------------------------------------------ iEST PARA:1ETER TEST i;:::::SUL T ------------------------------------------------------------------------ Mu!ticamoone~t a~2lvsis: BRO!~CDICHLORO~ETHANE F RO:---':D!='O R~ HALOGE~ATED VOLATILE i.tc / 1-::::; CH:....GF:□b:'.\!ZEt\E C!••:'....C ROET\-!rl~ :E 2-CHLOROETHYLVINYL ETHER CHLO F:O'C ":~ C i-!LO r.□~'i~T:-!At·!E DIB~DMOCHLOROM~THA~E :.2-~:c~~OROBENZENE 1.2-D!C~~OROBENZ~~-:E i.4·-I·!C~~LOROBE~ZE~~E 1. 1-LI CHLOROETHi'.'ll,E 1.2-DICHLOROETHANE 1. 1-·DICHLOROETHENE :. ~-=:![:-!:.....DG:[t~•FGr·r-:!·:E C!S-1.3-D!C~'....OPOPRO~•E~E ~F~~~~~-:.3-DIC~ILORQ~•R0~1Et~~ ~ETHYLEtJE CH~O~IDE 1. 1.2.2-TETRACHLOROETHA~E TETRACHLDR□ETHENE 1. 1. 1-TRICHLOROETHANE 1.1.2-TRIC~:L □RO~THA~E TR I Ci-lLOROE•HEt--:E TRICHLOROF~UOROMETH~l~~E I..' I '.<Y:._ CHLORIDE I!='E MTEE BTEX MI~JERALS EPIRITE '.'.DI~ D '._\ □ / !-: □ 1.,0/ko :~,o/ku u □/1-:□ ! ',.., / k D -·-1' ' 'JC/ k C ,.,c1/ko uo/k □ t.\c./ko 1.1.c/kc uc/ko ,_;,.:;/ 1-: s 1.10/kc u □/ko ·.:o/krc ;_i.c/\.i.□ uo/1-:c l.t= / k D u □/ko '.:.c / 1-: □ uc/ko '.t □/1-:□ 1.1.0/ko I.'.□ I:-:□ u □/kc uo/kc u□/H □ u □~k □ mo/ko ORGA~-!I CS N~t DEt 1 IZ1 N:.t D = t :0 t, l ,-_ +-. ~ -\., ['E ":" : e• ~~0t Det 10 Net Det :0 i-.lG t Det 10 Nc-t Det 1.0 Not Det i Ci '.'·l-: t [,• 2 t '"' t·l:,t [,~t 10 r·-~ ·=· t C·st 1C ~,t ':It I•et 10 !'<ot Det !0 Net [., et 10 Not Dot 10 ~-~ ::, t Det 1 (', N:-t Det 1 1:~ i~ ·=· t Det 18 t.1 r + .. ~· ~ Dat : C" :"-'.: t [·et 10 ~ht j) +-e • 117·, t< :-t [1s-t 10 Not Det 10 t-.!e:t Det 10 -; ' ~ ,-,, -· ... ·- Not Det 1 e, t'~ Ct Det :1.i:' ~Jot Det 10 Not Det 10 Not Det _10 Not Det 10 t' ..... ,_. Det 10 < ~ :': ..., ------------------------------------------------------------------------- 449 SPRINGBROOK ROAD • CHARLOTTE, NC 28217 I I I I I I ( Bold Re~~ 0 ~!ch Labs) ANAL YTlCAL TESTING & CONSUL TING SERVICES Ram Le a.the r CcPtOa30X 31486 • CHARLOTTE, NC 28231 • TELEPHONE (704) 527-4183 • FAX: (704) 525--0409 P.;.ce: lb October 20. 1991 Comments: borino neat' seotic d~'ain box Custo ■er Code: RAM PJ-.011E ~~1.:r.1t:JE1··: (704) 54=·-972:7 LAB I.D. AA08093 Bold ID Number G398H-21 Bold Customer Number E,745 Ccllectic~ Date: 09/lE/91 S:ib~ittal Date: 0g/20/91 Customer· Sa~cle I.D#: B-4.2' Cclle:::tic,r, Time: 11:2\l, Su~mitt~l Time: 03:09 ------------------------------------------------------------------------ TEST PP.RP.ME:"ER RESULT C•EiCCT Io:-; LI 2 l· :" ----------------------------------------------------·---------------------- I M~lticocconent analvsis: HALOGENATED VOLATILE !.•.~/ko 1.tc/k~ i.,;. Ii-:= '.'..: / :-: 2 ORGANICS ~~-:.t; Det I I I I D m I 0 I E~'J~10~0RM E,F:or::0METHANE CARBON TETRACHLORIDE c~:_oPCE Et·) ::Er-.;::: c:-:~D ~O~T!-:A:~E 2-C~:!_C ROETHYL ',;: ~ ~y;_ C!-::.....O!..;:QFOP.~"1 rT• ,,-.-~ I ; ·,c... ."\ C HL:J RO'.~·:E Tl-:H~·~E D!BR~~GC~~OROM~THANE ~.2-DICHLOROEENZZ!•:: 1.4-DIC~~~O~OEENZE~:E D!C~LQRODIFLUORO~ETHA~E : . 1-:nCl-!LOROETHh~~~ :.2-D!CH~OROETHANE 1. 1-r:: C1-·'.i...OF.OE7 HENE T s:;:..:-1s-:. 2-D ! C:-!~ORO!::THE~~~ 1. 2-CrICt-~:.....c~:o::-•Ror-·At<:: CIS-1.3-CICHLOR □~·RQ~ENE ~ETHYLENE CH~ORIDE 1. 1.2.2-TETRAc~:_opoc~~~~NE TETRACH'-OROETHENE l. l. 1-TRICHLOROETHA!<E 1. 1.2-~RICHLOROETHAr~E TR I EH'-OROETHE:::: TR I CHL-DEOFLLIC1RQM~THA~~~ IPE MTJ::.E BTEX ►,,,T;'":"'0-• ~ I,. i,,L:. ._H._.::., SPIR!:"S .'. s: / :-: = •.1.0/~o 1_1,::/kc '-l=/k □ 1_:_c/~o 1_:_:J / \-; iJ :_-.~ I kc ,_d/ko 1.:d / :..; C 1_\d/k □ ud/ko 1.•.01 /k □ ' ' ,..1 'i . D •. '--, I I", 110·/kc •• I • 1.'.[! /k C 1.,0/k!J i_:_u / \-; e: 1.t □/ko 1.\:.:/h:c u □/ko :.tc/k □ 1_,.u/kc :_:,c / I..; C '-'□/k □ 1.1 □/kc l.l!J / 1-: 0 r.□/ko Not r-~c t ~~Gt t'-~::; Not :\•:·: Nc,t r-.~c:. t r~ot N:,t ~~vt ~<: t Net ~'~: t Not (·~ -: t ~~ :· t !'-lot r,! :·t ~•; ,: t Not (·~ C· ~ N·Jt !\ct Not .t~ct Nc,t r< 2 t Nat r,1.:-t Not DEt Dct D~t :,,:: ":: Det [, ~ +_ Det Det Det Dst D~t r::~: r:-et [-J.. • C > Det Get [•et Dct D=> "": . ' [,r.:+- Det D::: t D~t Det Det Det Det Det Det Det Det 0. ~ " . ,-:-. ,;_ ,.: :J 10 1 iz; 10 10 10 10 18 ------------------------------------------------------------------------ 449 SPRINGBROOK ROAD • CHARLOTTE, NC 28217 I I I n 0 D I I m m D R D ANALYTICAL TESTING & CONSUL TING SERVICES ' Ram Le at her CcPJO£BOX 31486 •CHARLOTTE.NC 28231 ~ ~PHONE (704) 527-41B3 • FAX: (704) 525-0409 i=',a.ce: 17 Octabe,· 20. 1991 Comments: borin □ 101 s . ..,;. fror.: £ec,tic dr2,in C-·:-:--: Custo ■er Code: RAM Phcne N:Jm~E~': (704) 545-g737 LAB I.D. AA08094 Ecld ID N~~ter· G398~-2: Eold.C:Jsto~e7• ~~~be~-G7l~S Collection Date: 09/lE/Sl Col!ectiQn Ti~e: 1~:00 Submittal Date: 09/20/91 S 1~bmittal Time: Q18:09 [:J·:::t:-:.:er =:ar..c-} e ~-::::,rr: E-5. 4" ------------------------------------------------------------------------ ":E'::T P1'::r=:A!":::::EF: ................. , ....... ,..., .. ...,_ . ._,_' -L.-. ------------------------------------------------------------------------- ~-~lticonoonent a~alYsis: HALO~=NATED VOLAT!LE ORSANICS BROMODICHLORCMETHANE 1.tQ'/l~o Ne~ Det BRO~OFOR~ 1~=/ko Net Det BG":CJMD~·:ZTHH~JE CPRBO~ T~TRACHLOR!CE C~:...OS,8SE'.·~:E~![ C:~'.._O RQC:T!-IA~ ~E 2-CH~ORD~THY~1JINYL ET~ER c:--i._O'=\O~D~::-,1 CHLOFOl"E Ti-' .. '°f .'E OIBROMOCHLOROMETHRNE :.2-DIC~i~OROE-ENZEl·iE : • ::::-r:,:C~l'.....OF:OE'-E~~Z!:::N£: l.4-D!C~~ORCE~NZENE ::CHLORC~!F~UORO~ETHANE 1 • 1 -DIC :-'.-.__O F.QET\-:;~l·-~= 1.2-D!C~!LOR □~THA~E 1. 2 -L l CYLORO:::THt:r,;E. TRA~S-1.2-DICHLOROETHSNE C:2-1.Z-~ICH~ORQ;·RCPENE ! r:::,~~ ~ S-1. 2: -· !: : CHi....O P.Q~• r.:ir-::: ~:::: ~~THYLENE [H'.,_O~:LE 1. ! . 2.. 2-TET~.:-'-:1:~!....ORC!::.THf-t'.·;~ TETRACHLORO~T~~~~ 1. 1. 1-TRICHLOROEH.,PNE 1. 1. 2-TR l CHLOR:OETHRr-1'::: TR I CHLOROETHEr,~E TRICHLORO~LUORO~ETHRNE VI N'lL CHLOR ! :JE IP~ f":Tf'E BTEX tv:rr·~ERALS s~·IF:ITS l.'.C I~: D 1.,s/ko i.\iJ / 1-: [; :.·.c .-'kc ;;.c/1--:c :.t!::iko l.'.:J / k □ '.: G i I~: c ·.1c/k:: :.·.c/l<:: :.:c / !-: C: I.'.□ / k □ :.t C / ~-; C 1.1-C / k □ l.l □ /k:: ,.:u /, k C 1.l □/k □ r:o/kc ~-~.~t [1e:t i'J:,t De-t ~~::t [Et C-et [; ~ t l::t; t [,et [1st r._:,: t DEt ~'-'. C ":: [· 2 t ~::-t [•Gt r~c,t D~-t r'~.:t Det r.1,.._.:. [1Et i\:ct [1-=t !~-: t Dst r-:c-t [·-=t N:,t CE·t r-.:ct D!::'t Net Det flct Det r;c,t Det Nc-t Det l\!Jt Det ~-'.i::-t Det ~~:it Det 0.S 10 1C. lC ------------------------------------------------------------------------ 449 SPRINGBROOK ROAD• CHARLOTTE, NC 28217 I I I I I I I I I g I I n m m I ANALYTICAL TESTING & CONSUL TING SERVlCES Ram Le a.th E: r Ca,ioEBOx 31486 •CHARLOTTE.NC 28231 • TE~PHONE (704) 527-4183 • FAX: (704) 525-0409 P2.::ie: 18 October 30. lS'-31 Comments: borin □ 20' s. of seot ic d·r·2.in box Customer Code: RAM P~a~e ~~nber: 1704) 545-9727 LAB l.D. AA08095 Bc!d ID Nuc~c~ G398H-21 Bold Custon•~ N~m~•~ E7 45 Collection D&te: 09/lE/91 SubGittal D~te: 0g/20/Sl Ci.,stome~~ Sar..Qle I. D~f: B-5. 10' Collectic-1. TimE: 1t:,:0C', S~bmittal Time: 08:0S -------------------------------------------------------------------·----- TEET i=''ARAMETER T ~C-T c....:' RESIJLT L'ETEC ~ I 'J~·,' L Ir"". IT ------------------------------------------------------------------------ E,ROi11Clt'1ETHAr~E CARBON TETRACHLORIDE C 1--::_o ~'.JE Et'~ Z E!'<E Cf-iLO c':OET!-:,1:,:::: C ~::__o ~:D~0 ~::r1 C :~L.O:=:".Qt··:E T!..!,Hr<E 1 • 2-C.> I CH~O F:QE,!:::l'~: Et·~E 1.3-D!CHLO~OB~NZENE :.~-DICHL0R0EENZENE D!CH~0R0L~FL~0R0METHANE 1.2-D!CH~~?0~T~~~~E : . : -I.· I C:--'.~0R0ET!~Et·~E l .'2-D I CHLCROPROi='ANE CIS-1.3-DICHLOR □;·R □PErJ~ TRANS-1.3-D!CHLOROPR □PE~E METHYLENE CHLORIDE 1. 1. 2. 2-TE:-Fr-:ci-:~0R0ETHA~~E ;"ET RAC.:-!L0 ~0E:"::-'.~'.-E.::: 1. 1. l-TFICHL[1 q□E"T~A'.·-JE 1. 1.2-TR!CHLOROETHA~!~ TRICHLOROETHENE TRICHLOROFLU □RO~ETHA~E VINYL CHLOF:!DE I~·E ...,.. .... r r-, .. ' i:..:. P.T~X r~: Ir<~:r~HL~ ~~.:-! r:: I TS '-'· t::. / I-< C! l.i □/\.-'.Q uc/k □ :.t: /k □ 1_;:J/~'.!:; •.:c/ko u □'/ k o u □'/1--:c. •.•.c/1--:= l.\0 / ~: :J ._._ C. / k C u □/kC! i.,.c 1/ k !: 1.t □ / h □ ,_:,□/:--:□ •Jc/\..:□ ·.•.c /e: C ·_,_:::/kc 1.:□ /ko u □ I e: o ,.:.c/kc uc/k □ •.:□/kc uo/kn 1_1_0/kc •.:c) 1--: ~ mc/kQ 0 F:1:-;i:-:r·~ 1 CS ~,.: c--I; ~Et N·:it L' Et NGt Let N-::lt Det tJ =· t Det ~-'.Ct DE t r-: :-t C·e t Not D =' t ~--i =· t [·et i,lot [•~t ,,~ t Det r~o t Dct N c-t Dd ~,ct D~t t-:,:t Let N::t [•~t Net Det Net Det t-~ -~ t Det Nat I:1 = t Net [-et ~~ i:• t Det ~:ct De-t ~-!ot De: r·~c•t Det ~-.!ct Det ~~ 0 t Det r~ ei t Det Not Det Nct Det Ne-: r:-~ t Net Det 0. ~ ~ !0 : C, 10 10 1 Q: ------------------------------------------------------------------------ 449 SPRINGBROOK ROAD• CHARLOTTE, NC 28217 I I I I I I I I I I I n I I D m Ra.rr. Leat!-,er ~-2.::ie: 19 ANALYTICAL TESTING & CONSUL TING SERVICES [@{j!>OX 31486 •CHARLOTTE.NC 28231 • TELEPHONE (704) 527-4183 • FAX: (704) 525-0409 October 20. !591 Comments: borin □ 30, s.of s2~tic d,·ain b~x Customer Code: RAM Phc~e ~um~er~: (704) 545-~737 LAB I.D. AA08095 e~ld ID N-J~~e~-G298H-21 Bol~ C~:stome~ ~--~~E~-:7~~ Col:ecti~~ Cat~: 0~/lS/Sl :: .\b'.1:ittal D2.te: e<:-12011:;:1 -------------------------------------------------------------------------- TES:" Ur., -Tc ' .. ' ...... "'!"EST RE:2-Ul.. T DET:ZCT ~ Ot·-~ ------------------------------------------------------------------------- CARS~~~ ~~TqAC~LO?!DE :1-::....2 R'.]P.Et-~ Z Et·~~ Cy:_[! F'J:::: :" :-:p,:-~E ~-C~~L□r8CT~YL~!t;YL E7!·!~~ DIC~:....CRODIFLUOROMETHANE TRHh.'.S-1. ~-DI C!-:LOF.OPF.Or:·_El<i::: ~ETHYLEN~ C~~CRIDE 1. 1. 2. Z-:'ET;-;r:-.:::-:LCFC1C:::Tf·:P'.·~C TETRACHLCRO:T~;~r~E 1. 1. 1-:r::rc·~_;,_c,r::J:::::~~(J<~ TR I CHLORO:::Tr:EN::: TR!CHLOROF~~~~o:~=TH~irJE ,'l!i'fL CHLORIDE ! t-•E t·'.":E,i: E,EX 1_;::::/~c -.lC / k C :_'_c/kc '.l □/\.,,c ,_·_c. / >: C ·_,_(: ik:i 1.16/ko 1_1.~ / k ::i ' ·.:i;:, / k G ·.1~ / k □ ' 1.'.1;/ko : •. ::::/!-:c IJC / k □ ,_,c I kc ,_,.CI~:□ 1.t □/kc ·., . .:.Ii-;□ :_1_:: / \..·. :J 1 •• 6 / !-: C :.1:1/ko ,.,.c /kc 1.1.0/ko r.10/k;: 1.:ci/ko ;.:□/1-:c ~-' --I,.. -:-. _ . .a.. . ' --.. ;_• -- r--~:it Ds-t r·~ c-t D: t N:it Det i<~t Dct (,lc,t :<: t (,) ~t l.t --1-l'i ·-\.- "' -"" '" ... " I.' --1- [•;::t [Et [·~t [•,~t i:·E t DEt [.,.:: J; N::,t [1£:t ,--~ -=· t ['· ~ t ~,!:,t Det ~<c,-:; [1et t·-:ct Det ~~:-t Get· ~--!:1t Det '.<ct Det r,ot D~t ~·~ut Det Not Det ~,teit L·r: t ~-Jct Det 10 10 10 10 1 (" ------------------------------------------------------------------------- 449 SPRINGBROOK ROAD• CHARLOTTE, NC 28217 I I I I I I I I I I I I I a I n n I ANAL YTJCAL TESTING &:CONSUL TING SERVICES Re. :n LE i=, t t-, er Car.otBOX 31486 • CHARLOTTE, NC 28231 • TELEPHONE {704) 527-4183 • FAX: (704) 525-0409 Pe.oe: 20 October 30. 1951 Comments: borin □ 30' L-J. of sec,t i·= drain box Custo ■er Code: RAM LAB I. D. AA08097 !='hone N•.tr..be~-: '(704) 5LiS-S727 Bold ID N~~~e~· G39EH-21 Bald c~st □~e~· Ccllecticn Date: 05/1~/91 ~:Jbmi":tal Dc:,te: !l-S/21?,/':!1 C:.,.stom=t· 5-e.ccl<:: I.['~~: E-£: .. 1e,· TEST PARAMETER C~llec~ic~ Time: 12:00 s~b~ittal Tin~: Q:3:0g TE'.::T RESULT ~-~lticom~o~e~t a~alvsis: HALOGE~AT~D VOLATILE ORGArJICS E-:\C!'.!'\O~ORt'( J?.r:;or-:or-:!::THAr·~E CARBO~ TETRAC~:~CRIDE C~LO~~oe.E~~ZENE CHc_Ofa:DETHA~-!E 2-CHLQ~O~THY~~I~~·tL ET~~R C!·< ... OFOFOF:i"1 c.:--::__o S. ·J:-'E":\-:h:'.::: 1.2-D!C~~OROE.ENZENE 1.2--D!CHLC~09~~z=N~ 1.~-D!CHLOROEENZE~lE DICHLORODIFLUOROMETH~NC i. :-LIC~~OR~ETH~~~E 1.2-r:CHLCROSTHA~E :. 1-rrc:!-::__or.:ic:1-!r:::::r<E l. 2-·T,1::: CHL C) ~:Qf.•RQPi:-~!<::":: CIS-1.3-DICH~O~O~•RO~•E~JE TRAl~S-1.2-DICHLOROPROP~~~E METHYLENE CHLORIDE 1. 1. 2. 2-TETF,AC'!LORCJCTHA'.!::: TETRACHLORQET~{Er~E 1. 1.1-TRIC~!LDR □ETHANE 1. 1.2-TR!C~ILOPOETHAr~~ TR I CHc_OROETHC:-:::: TRICHLO~OFLUO~CJ~ETHA~E VINYL CHLORIDE IPE MTE-~ E-:"~>'. t<:r-~::RA'.....'.=-sr·IP.I;"':: :__:: / k:: ·_:.::;/kc ·.lW / ~: □ 1_·_ C / i< C =.:c/kc · .. c/l-;:. .. -I'. -·••;_;I .-. _, ·-·~ / l-: = ·_·.::i / ~: = 1.tD/ko ,_._j /kc ._,.:J; :-: ~ _·_::::/ko ,.,o I k □ 1.:0°/ k □ :_1.t.:. / ~:::: I_'.= /J-:Q iJQ/i-<C uc/ k a :_:=/he 1.t:l / k D r.: C / \.-: !: >.:ct IJ£•t ~-~.:t Det ~·~:it Det r:-:t D::t ~~ -: t ~-lot uet r,.J,:-t I 1E·t '.\let De:: ~<-: t [•,:; +: r-:c..-: c•~t ~-.!ut Det t:0t DEt r,c,t [,et Det Det Net C-et Det Det t]Gt' Det t-.: •=· t C· e· t ~-.!~-t; Det ( . :: 449 SPRINGBROOK ROAD• CHARLOTTE, NC 28217 . ,"), .:. .,_: 1.0 18 1 C· :o 10 -:c-, 10 . ,, ...... 10 1.0 10 I I I I I I I I I I I I I n D n ! D I ( Bold Re~!; 0 ~!ch Labs) ANAL YTlCAL TESTING & CONSUL TING SERVICES Ram Le at he,-Cif',Elel()X 31486 • CHARLOTTE, NC 28231 • TELEPHONE (7041527-41B3 • FAXc (7041525-0409 Pcoe: 21 October 30. 1'3':ll Comments: bori77.□ 30' h. of sec,t ic drair, bcx Custo ■er Code: RAM ~'hGne Nu~ber: ·(704) 545-S737 LAB I.D. AA080qB Bold ID Nunber G3SSH-21 Bcld C~stc □eY N-~~be~ =t~~ Collection Date: 0~/lS,'~1 s~t~ittal Date: e~/20/91 C•.s~te:r.i::::· Se.r;;=le I. C'~t: E-7. '◄·' TE::T ~·HFZrlt'r1E7'.::: R CbllE~ticn Time: lS:00 s~~~ittal Time: 08:0~ ~-J!tico~8o~e~t analvsis: HALOSE~~AT~D VO~A~I~E ORGRrJICS ERO!~C:rc~~LORO~E~HA~E ~c/~-□ Net Det ERO~O~ORM t:~/k □ ~ct ~~t CARE~N ~:TR~:~~~Q~:~E c:-:;_~ FQEE:i-.: ZEt-E C ~'.:... D ?iO~ 7~":H>;:::. 1. 1-D I CHL.CIR:J~THH~~E 1.2-DICH:...□RO[THA~E : • 1-u:cH:.....OFOETi---!E'."<.;E :"F:Ht-J-=:.-:. 3-L I C~-'.LC1P.:y:::•F,O\:·E~-!E MET~YLEr~~ c~:~o~:~E 1. 1. 2. 2-TE:Ff'l'.:f-'LGF:GETHf'INE TETRAC~LOROETH~tJ~ 1. 1. !-TRICHLOROETHANE 1. 1. 2-TF:I:!--H ... ORD::T!-lA>~E: TR I CHLOc:OC:THE~,: ~ R ! CHL0?:0:-"~U:•~:Ot""'.:::: ~H~ ~:. 1..' 1 t·JYL C~LC'.";_ I ['f:.: MTEE ETEX !YiI!'-:EPA:....S ~PI RIT5: ·.1.:. ,' ~; :J •.tc/1-:c ,_,_ o / k !::::! ,_,.::: I k ::i :_,_ C / ;.: :: •-··=I\-: o . -I\. -•• -I I• I- . 1;.C: / i-<: C ,_,c, I k:i ,_·.□/kc ·_;:::: / i-: C ,_.,::::; / \-: C ,_._ :J / I-: C 1_\c/k::! ·_,_!:!/kc ·-'· C / !-'. D I.\C/~;:J · •. G / 1-: C: l_l_:::!/1-'.i: i.·.C /kc lji::J/:"":[l ud/1-<c iJ~/k:::::i r,;~/l-:□ r-..::t ['E~: ~<Jt D=-- r-~;:: t c r:: t f,!: t [':-t (·:.:.: DE t l\c,t [ic.+- r~ C· '; [· t:: t \1<:•t D-:t r--; C· t [' \:; t ~-~~t C-t.-t ~~Gt Det r-~c-t L'~t N:t Dst ~J:,t D~+ ~-I .• J.-T"". --1-:, -·. -:.:~ ,._' -J, ~Jr:, t Net ~,-:-t [·et C·e t [•et Det Not Det '.•.;.:.t Det Na:,t Det f,ot Det Not Det N~t Dr::t !--~:it L•et { . s 449 SPRINGBROOK ROAD• CHARLOTTE, NC 28217 '.~ .L\:..' 10 10 10 I I I I I I I I I I I I I D I ANALYTICAL TESTING & CONSUL TING SERVICES Ra r.1 LE at r. Er Ca'lQ.€BOX 31486 •CHARLOTTE.NC 28231 • TELEPHONE [704) 527-4183 • FAX: (704) 525-0409 1=·2.::Je: 22 O2tober 30. lS~l Comments: borina 30'SW.cf seotic drai~ box Custo ■er Code: RAM ~·~o~e Nu~ber: (704) S4S-~737 LAB I.D. AA08099 Bold ID Nuc~er G398H-21 Bol~_Customer N:~~be~-~7Lt5 C:llectio~ G6tc: 0S/19/gl Su~mittal Date: 09/20/91 [:.1.stc.mer S,;,:::u:e i.D:tt: B-7.10' CGlle=tic~ Tiree: l&:00 Subm.ittal Time: 08:09 ------------------------------------------------------------------------- TC::ST r:·P.RP.METE R TEST RESc.JLT c.::::~·ccT: □:·! LI;,:,_-,- ----------------·---------------------------------------------------------- M~:tic □~~8nent analvsis: e :=::::;·,',GU! CHI...OROr':ETf--'.f:i!~i:::: B?Cit":C1~0~~ B F-:D!'"':O~~~T~!'=i~·~C:: CA~BON TETRACHLO~ID~ C!-::.....ORC:1E E!·~Z E'.':: CHL C) ?o=. Ti-u=ir--'.~ 2-C:~~OR□E-:-~YLV:NYL ETHER 1.2-DIC~~LORCBE~ZEl~E :.3-DICHLCRODE~~ZENE 1. 4-r•Ic!-::.._c1rcc:::r·~::E~~c DIC~:LO~:ODI~LUORQ~~THANE :. l-L·ICH:_[1F;:JC""'.'H~~~'C 1.2-DIC~~QSO~T~~A~~ : . 1-C I c~~:..OF:OETl-:Et~E 1.2-C!CHLORO~•RO~•~t~C C!S-1.3-DICHLOR□~·RO~·ENE HR~OGENATED VOLATILE l.iC/1--:□ •_,::, I k :i :_tc ,' !-: .:: '.l:il~-:o 1.t:J/ko i_;_::/k::: t•.c. I k:: ,_,_c/kc '-'·9 / 1-: :J ·--~/kt l_l~ / k □ :_; ~I / i-: :J u.:::/ka :.t0:11-<c ,_,_o'/k □ ' '.t[; Ii--: C uc/k::; -:-~-~-;:,;·~ -1. • 2 -LJ I c1-::..o ROI=°' ~:o:-·E'. :: ·.=.c/kc 1.1.c / k □ I.'.□ ;'h C ,_,c/ko IJ □ / i-:C u □/ko 1~;.□/kc IJ □/~:□ u □1/k~ ,.•.□/ko '.~C 1 / !-: C. ,_,o/ko mo/ko METHYLENE C~L□R:D: 1. 1. 2. 2-TCTRRCHLOROETl-;l'="~t<C:: TETRACHLOF.o=n·:EIE 1. 1. 1-TRICHLOROETHANE 1. 1.2-TR!C~~ORO~~HA~=. TR I CHLO~:OET,:Et:E TR I CHLO~OF!.....UOR-0'.r".'.::THi:i>~E V E:YL Cl-'LOR I[•[ IP!.=: !"":"TE-E BT:::X t<IN[RALS S~·JRIT:C ORGANICS I, o t Det ~~ C, t [,et N.:·t [·et ~<ct D?t •.· -~ L'.::t .·• ·-" t ~ C, t Det t~•=· t C.et ~~ C, t Det !"\ct Let t",!:it Det r~-: t DE t ~~: t eat t<-: t [at r·-.: e: t D2t r,~: t C<=-t- ~-lat Det t•' -~ ;-.:....-\. DEt ~~c-t Dot Net Det Net Det Ne~ Dct N~t Det r~ot Det ~~ ot Det t'~c t Det NGt Det Net Det t·~Dt Det N~·t Det Not Det ~-~ -:· t DEt Not Det ( . 5 1C 10 10 10 10 ~o 1 C' 1 (:1 :0 1 (:.' ------------------------------------------------------------------------ 449 SPRINGBROOK ROAD • CHARLOTTE, NC 28217 I I I I I I I I I I I I n 0 I ANALYTICAL TESTING & CONSUL TING SERVICES F:a m Le at he~-C.f.f>,¥:)X 31486 • CHARLOTTE, NC 28231 • TELEPHONE (704) 527-4183 • FAX: [704) 525--0409 October 20. 1<:-g1 Comments: borin □ 30'SW.of ~e=tic d~·ai~ tcx Please advise shculd vo~ have auestions concEr~i~o these d2~~- Rescectfullv s~~mittej. 449 SPRINGBROOK ROAD• CHARLOTTE, NC 28217 I I I I I I I I I I I D D Bold Research Labs lncoroorated ANALYTICAL TESTING & CONSUL TING SERVICES P.O. BOX 31486 •CHARLOTTE.NC 28231 • TELEPHONE (704) 5274183 • FAX: [704) 525-0409 October 2.0. 1~:il Ra~ Le~thet"' Care Att:.: E. Cliff W'J~·l::v 15100 Alberrna1--le Rd 2.82~7 Customer Code: RAM -~=~e '.l~c~•~: '704) 5~5-g7i7 LAB I.D. AA08113 E-::-1·:' :Dr~=-·.:::::-~-~-ti-;~~:!~:. B:l:! C;.:t-:r,-:·.· I·<·-·.:.:~~?"' ~-7.'.f~ c2:lecticn Date: 09/20/~l S: .. t~i~tal D~te: 0S/22/S: C=_i.stc•r.:E-~-';:2.r..::le I. Dt: B-2 .• 10.' -------------------------------------------------------·---------------·------- :"EST e::c:;: c:::·-~ !.... ! :-,1: 7· --------------------------------------------------------------------------- P~C~OCIC~LO~Q~ETHANE I ?8'."'.0!='"0F::-1 E-R~'.",0!':".ETH:':i~ ~E CARBO~ TETRASH~ORIDE 2-C~~LOROETHYL.V!NYL E7!~ER C ,-:LO ROF O F:M CHLOROMET'-'.Al,E DIE?OMOCHLOR0'.1~THAt~E 1. 2-DIC!-ll .... Of'=:OGEl,:2~~~E 1.3-D!C~LOROBE~~Z~NE 1,4-DICHLOROEENZEt!E D!CH~OR □DIFLUOROMETHA~~ 1. 1-DIC!-'.LOROETHAt·iC 1.2-DICH~OROETHA~E 1. 1-DICHLOROCTHENE TRP.~~S.;_:. 2-['l[:-lL.C~:•E:'T~~~~~ ! . 2-D I :r--:LO r.:ll='PO::·r!:<E :;!1:::--1. 3-D![!-!LORC::PRD~ENE 7Ri~N~-:.2-CICHLOR□r•~CP~~lC uc/ko 1.lC / k::: ·.:.c/k:; '.'. C / h::: •;.:i/kc I 1J,□/ku l.'. ;:_ / I-: ::_ '.'.CI~:!:: ,.,.::.., : .. ::. '.t □ / 1--: C 1•1.::::i / ~: o •.:c/~::: :.1::i / k C ,.:co I 1-: w l.t □/k"::i • , -.1. 1, .. _, I.. N-:,t ~; .:, t N0t Det r. __ ., .., ,.: ·. :_; ~ t Let [;=+ DEt Det [;Ct Det Det Det Det ~~Gt [1et t<wt DEt ~~:-+.: De-l: 1. 1. 2. 2-~·ETF:HCHi....OP.0'..::Tt-!HNE 1.t □/~c N-:t D~~ -:-:::, F.AC.r:LOr:0!::1 ''C:,E. 449 SPRINGBROOK RGAD r. CHARLOTTE, NG'Qs2,=r- 10 1C 10 10 10 I I I I I I I I I D I I ANALYTICAL TESTING & CONSUL TING SERVICES P.O. BOX 31486 •CHARLOTTE.NC 28231 • TELEPHONE [704) 527-4183 • FAX: (704) 525-0409 Ram Leatt-,e>' Ca:· e Pace: 2 October 30. 1S5::.. HALOGENP.TED VDL .. ATIL.E ORSA~-~ I CS (cGntinued} l. 1. 1-TP I CHLO ROETHA: ::C: l.li:::J / 1--: 0 N~t Det 1. 1.2-TRICH~OROETHAN~ u □/ko Nat Det TR I CHLOROETHG;E l.'.□ /h:0 Nc-t Det TRICHLOR □~LUOR□METHANE ,.,a/ka r: ct Det t,/ I NYL CH:_QP. I DE •.1.0/kc Net Det IPE u.o/ka r<c,t Det !Y1TE-E 1 •• C /]-: C Net Det ETEX l_l::J / k □ l\:c,t Det 10 10 10 1 ('1 1 iZI 10 10 10 --------------------------------------------------------------------- Customer Code: RAM ·r-•~.c-:-.-:;;: ~..::_:.:::=-e~-= (7~4) 5 11s-g727 LAB I.D. AA08114 Bol~ !D N•~~~e:.· 402~~1 5:ld C1:st0~~~~ l~-~~~s =cllectic~ Date: 09/20/Si ------------------------------------------------------------------------- T~ET ;:::•P,R1l'.":~""."EF: TEE-T F:£:S'._I:_ T ------------------------------------·----------------------------------------- EPO~J[!C~LOF0~~7·1~A:·;~ E ?Qr~o~or=;:~,; E r::0~~10\~ETHf-l:<Z CA~9QN :"ETRRC~~ORID~ C'. -:!....D RCtEEr-~zc::r-~E c~~c ~oc: ~~~ ~£: 2--· c:::~:....DPCJZT!-{Y!.... 1.' I ~~y:_ ETHCP. = ~:~o :-:ci:7"cl ~.;'."_ C\--i;_QF;Q;"":!~ T~,qr:::: DIB~O~OCHLOROMETH~N~ !.2-L!C~:....□~OEENZEt~~ : . 2-DI CH!...OROE'E~~ZE~1E :. 4-D!CHLCF:DEENZEr~E DICHL.ORODI~~UORD~ETHArJE 1. 1-DIC'.-L.OPOET~A;·:C 1.2-DICHLORO~THAN~ 1. 1-DIC!--:L□r.:□ET'-'.E'!E TRANS-1.2-DICH~ORDETHENE 1.2-DICH~OROPROPA~IE c:s-1. 2:-DICH~OR□,•F:□;·c:,E TSANS-1.2-DICHLOR0~1Ra~·ENE ~ET~'.Y!....E~lE C~lL □RID~ 1. :. • 2. 2-TETRAC:H~CF:OCT~Pi'~E :}.CI k:: ;_,_= / ~: ~ 1.',C_ /~'. C '.'.::3 / ~: 0 '.td,, i.::: 1.•.d/kc :_,_:_:t :' :-: :: i.-.::.1 / ~::.; :_,_ d _: i-: c. ·;.c/1--:o ,_·.u; ~~ □ l.'.C / ~-. C l.',8 / 1-: Q ,_.:::/!-:□ 1.=.c/ Lr. ·u.□/i-:c ,_:_ C /I-·:: ~~ 2 t 2s"t r·-~c:•t L<=,.1-- r,i-:-t Det N:t [•2t r-~,:; t [:::;: t "-! -+ ' .. ..: . D = t r,-;: t [i:; +- !\! :, t [),::.;.. ~~-:-t [·st N:t [:2t !< = t [--= ~ ~J:: t [,et ,,.: t Dct ~,.: ut Det t,• -.. Dct . ' .. · '- r.: :-t Det Net Det N:-t Det Not Det ~~ ot Det Net Det ~.! ~ .. ,.,._. '-Det ~< C: DEt N-:,t [•et r,:c: [•c > 449 SPRINGBROOK ROAD• CHARLOTTE, NC 28217 10 10 10 10 I I I I I I I I I I I I D D m m ( Bold Re~~0~!ch Labs J ANALYTICAL TESTING & CONSUL TING SERVICES P.O. BOX 31486 • CHARLOTTE, NC 28231 • TELEPHONE (704) 527-4183 • FAX: (704) 525-0409 Ram Leather Ca~'E Pace: 3 October 30. 1'3'31 HALOGENATED VOLATILE ORGANICS 1. 1.2-TRICHLOROETHANE TRICHLOROETHENE TRICHLCROFLUOROMETHA~E '-.,1 ! ~~YL CHLORIDE I ::·E MTE',E ETEX (cont ini.te:l): uo/ko uo/ko IJC/k □ 1~t!:! / ~'. □ uc/kc u □/k □ 1_•,0/l-:c: Net Det Not Det Nat Det Not Det Nc>t Det ~¼c· t Det N~t Dct Custo ■er Code: RAM i:·hor.e N,.,mbe·,: (704) 545-'3737 LAB I.D. AA08115 Bol~ ID Nu □be~ 403Hl Po!~ C~stcme~ Csllectic~ Date: 0g,'20/S~ s-~~□i~t~l Date: 0S/22/S1 C·~:tcm~t' s~~tle I.D~: 8-S.7~ TE'.cT ~•A P.P.:V:~T[ P. E ~8i"".':·L: C!-:~Q RIJ!"'.CT\··'.A~'.E E' RO~O!="O ~·~- E-R[i~Q~,ETr'.A:·-~E CARBON TETRACHLORIDE Cf-'.L.0 F--QB[r,; Z Ef-.JE C!-1!...0S:OETHA~✓~ 2-C~~OPOETHYLVIr~Y~ ET!~ER c~:.._[lp~~CIR~; D!E?O~OC~~O?Q~~THA~~ 1.2-DIC~LOROBC~:c~~c 1 • :: -[1: c:-:L □ :=::ot=.r ~z ::::r·-.!'.'=: 1.4-DICHL □R □BENZENE DICHLORODIFLUOR □~ETHANE 1. 1-DICl-:LOROETc-'.R'.K 1.2-DICHCOROETHANE 1. 1-DICH~OF:OCTf-!EtHO:: TRAt·✓S-1. 2-DICI-ILC?DET!-!ENE l. 2-D I C!--:LORO!='~;:J:-•A~·:;:::: CIS-1. :O-DICHLORO~•RO~'ENE TRRt:S-1. 3-DICHLOFOPROPENE METHYLENE CHLORIDE l. 1.2.2-TETRACHLOROETHANE T~TR~CHLOROETHENE 1. 1. 1-TR ! CHLOROETi-'.::;~,:~ !. 1.2-TR!C~~OROE~HAN~ Sub~ittal Ti~e: 02:47 Ut!l TS 1.tc I kn ,_._ D / ~'. C I.lei/he. 1_i.d/k □ l_l?:.1/k:i i_:, C.I / ~; □ 1_:_d; k :! :.:~-/ 1,0 ,_i.:r/~□ U~-/;..:: C t'.C / ~ :::! 1_·.c/ko 1;.0 / ~: C i.tc/1-:::::; •;.::i/ko I_\Q '/ \ •. C. 1.1 □ ~ 1-: Cl '.\□1/ka uo/ko u.:::/k □ 1:.c/l-:□ 1.,c/kc I.'.□/ k~ TEST ..-, r-r I fl -.. .---""-~....;;,_' D?::GA~< l CS N-• -C De: t t~ ': t D-et "!•• ~ Det '~;.. s Not Det r-.iot Det ~.J::,t Det Not Det N:t [•~t "' -. ~ . ~ ·-\.· C·e t !\: -. t-'~ --•. Det h'c t Det !\! , . .;.. [' =. r,;,:, t D2t Not D2t ~~ c-t Dat ~~ct [·et .... -~ Det C Not Det Net Det Net Det Ncot Det t, :,t Det Not Det r-:a t Det ~~: t [ct ~ot [1': t 449 SPRINGBROOK ROAD• CHARLOTTE, NC 28217 10 10 1 C·. !0 10 : ('1 10 L'~T;:•:T ! CJ;·.~ '..... I ;":IT , ;..,, .:. ·- 1 Q1 1 . ..,, -C' 1 (:1 IC 1 e, :c 10 10 . : (:1 . ·" .:.-..· ! c_, 10 :0 1 r? !0 1 ('1 10 :!.O 10 10 10 10 10 10 1 1!_, I I I I I I I I I I a 0 D I ffl ANAL YTK:Al TESTING & CONSUL TING SERVICES P.O. BOX 31486 •CHARLOTTE.NC 28231 • ~PHONE (704) 527-4183 • FAX:. (704)525-0409 Ram Lea.ther Care Pa □e: 4 October 30. 1C3~1 HALOGENATED VOLATILE ORGANICS TR I CHLOROETrEr;E TRICHLOROFLUOROMETHANE VINYL CHLORIDE IPE MTBC: !?TEX (cont inueC:): u □ / V . o •-t □/k □ !JC/!-<o ,_,o/k □ uo/k □ Custo11er Code: RAM Pt-.a:oe r,uc,be,·: <704) 545-9727 ~~Gt Det Nc,t Det N~t Det Nut Det Net r:,et Nut Det 10 LAB I.D. AA08116 E:ld ID N~□b•~ 402Hl Bold C~s~:□e~ Nu □ber 67~S Ccllecticn Date: 09/20/91 S1Jbcittal D~tE: C~/23/~1 C·.;stc-~E~~ S2.I!'!=,l= I. D#: B-10. 10' :"EST ~~.:tico~cone~t ~nalvsis: EF::J:10[' ! C~'.'.._[1?01"".ETHANE E ?JMCJ:=Q.t::i"1 CA~EO:~ ~E~RACH~OR!DE C!-:LD ~:CG[\•,! Z Et·,;:=.:: Cf-L_O ?.C:iETHA~~E 2-CHLOFDETH"{LVINY~ ETHER CrLDROFC!Rt". Cl-!;...ORO~E:THHNE CIBR□:~□CHLOPO~ETHA~E 1.2-DIC~LOPDBE~ZE~~E ~-~-D!CHLOROBENZEN~ 1.~-2IC~i~OROEENZE:~E DICHLORODIFLUOROMETHANE ! . 1-D I C~';_O~OE~HA~~:: 1.2-DICHLOROETHA~E 1. 1-D I CHLOC:OCT!--'Et!E TRANS-1.2-DICHLC!ROETHENE 1.2-DICHLQRO~·Ro~·Ar;E CIS-l.3~DICHLOROPROr·~~~ TRANS-1.3-DICH~ORO~•~□~•Ei•~= METHYLENE CHLORIDE I. 1.2.2-TETFACHLORC!ETHANE T~TRA:~~ORO~THE~E 1. 1. 1-TR I CHLC!ROETHA'.·1E 1. 1.2-TRICHLOROETHA~E TE I C!--{_ORCH:Tl-'.E!-!E UNITS ,_,_o/1-<:c •.i.~ I k o 1_.~ I kc '.'.~/!-:::; I tJ.C / !--: C: -'---~/ko i}.::. / i.,_":i '.\O /\..-,;□ 1.1.0/l-<c !.\:'.: / 1--□ '.'. = / k □ u □/~·.c: •.u: / I-: o '.!□/k □ ·.t~/kc ·.•.□ I e. □ l.'.0 /I-;.::: uo/h:::i 1_·.C / k 0 •.10/k~ lJC/]..;C: i.t:./k □ '.CC/ I-'. C '.t □/1--:□ ,,.elk □ TE'.=:" R::.~:u;_ '. O~:C:P~~ICS ~\C: t Det t\ ~ t ['~ t I<::-t D.: t t< 0 4: [·et t·~·=· t [,st t·~ C• t [1et r-! C, t Det Not Det Not Det N :it Det >,. --1--[· = t " --r-i :t Det i\-: t [·: t ~.;: t [=t N __ .._ L c Det t-bt Det N-:t Det Ne-t Det N-4 --Det ts Ct Det t·~ C· t Det Not Det Not Det :5503 ~~ ·J t [·et ~\ C•t Det ~~ =· t J:ct 449 SPRINGBROOK ROAD • CHARLOTTE, NC 28217 r-:::=c T 1 or< LI ririlT ~ ,.,. ,.,., ,-,. ~ ,(.•·-·--· l iZ·:Z":· 1 C-,:~1:,?. lC:0:3 1 :2,~0 : (}00 .• ,-,.,">, . ..,., -'-.••.:. .... 10(",0 ~ OC'·:J 1 t?:0:21 :1200 : ~0:2: :C--C0 : (10:.:...~ :000 1000 1 c,oc-, 1000 1c:,z:0 1 Q',;z:~ 10~:2! I I I I I I I I I I g I H I m ANAL YTJCAL TESTING & CONSUL TING SERVICES P.O. BOX 31486 •CHARLOTTE.NC 28231 • TB.EPHONE (704) 527.-4183 • FAX: (704) 525-0409 Ram Leat,!-:er Care Pace: 5 October 30. 1':?Sl HALOGENATED VO~ATI~~ CRGANICS (cc~tin~led) TRICHLDROFLUORO~ETHANE ua/ka VINYL CHLORIDE u □/k □ IPE uo/ko ~~BE !?TEX 1_·.s I k □ :_; o / !-:.o C1Jsto11er Code: RAM Pt-1:-n~ i'~•-~:.!:Jsi·: (704) ~~st Not Not l'-~ot t-.!-::it S4S-~727 Det Det Det Det Det 1000 100-J 1 c.0:: 1 t?,?:C: LAB I.D. AAl218117 Ecole :D N·.tJ:'!:C' 1+03H~ Bold Cust~mer N1imbet· ~745 ~clle=ti:~ ~~te: 0s1201g1 SJbraittal D~te: 0S/23/S1 S•J~nitt~l Tim~: 03:47 BPC:.AaO:-'OF:---1 E,:,'.Q~~D~ETHAt·~E 2-C: !-'.L..O F:C:ET~\YL... 1,,1 I '.·lY~ ETl-:E F: c:-:;._o R0~~1E Tf-'.A:'"~'.::: r!E~O:::oc~LO?~~ET~P~IE 1.2-D:~•-:~□?□EE~lZErJ~ 1.3-DICl~~OPCEE~~z~r~~ : . 4-[: I CHl....ORO[·.:~~ZE~<!:: D!Cl~~o~~[!!F~UCPQ\:!~~HA~~c :. • ~-DI c~:!....o:=::c:::THH~·~z: :.2-DICH~OROETHA'.·lE 1. 1-DIC~~ORO~THEN~ TRANS-l.2-DICHLOROETHENE 1.2-DIC~LOR □f•ROPA~E CIS-l.3-D!CHLOROPPO~ENE TRANS-1. ::.-[, I C!-l~O!?O~•~CJ!:··E:::•.l::: tv:ETHYL.El~[ C ;--i:...o-F: I DE 1. :.2.2-~ETPAC~LOPOETHANE TETRACHLOFOET~Et·!E 1. l. 1-TR!CH~OROETHA~~ 1. l. 2-TRICHLOF:OCTl-,A!·,E TR I CH:....O ~Q~T!-:£:t·f~ TR!CH!....DROFLUQRO!~ET~AtJ~ '.JI t~Y:... C~-!~OR ID!::: uo/l..... '.\O /'.._ ·.·.c /L UC /L · +.·.c I;_ i;.o/L ,_,o /L '-'· ~ ~/ ;_ I '-',C YL ,_,_:: :.'L ._,.::: / L.. ·_,oiL I.\U/L '.'.□ /L ·.,c /L I}. :1 / L_ '.l!:J /L !.•.c/L '.t.□ /L l_!_:J/L U'.J /L ORGANICS t" -+-., .. :,.. o~t "·' -.. : ~ -~ Det ~-~ C· t C·c t ~' -.... [)~t _,.;,_, '- ~-' -..... ;', ;,_ \., [';; t N--., -' Det i .. '.c, t [•et t~ ~t Det ~~S· t Let r-~1: t [Jet ~-l :· t DE t ~~ ot Det t-! -.i.. ' • ..: l ['2t Not Pet t·~o t Det t-.,1,:,t Det Nc-t ['et Nat Det t~c-t Det Not Det Not Det N:t Det -r ~ ei t Det Net Det ~-~wt Det Net [·et \!:,t ['et 449 SPRINGBROOK ROAD• CHARLOTTE, NC 28217 rr,i:-:-r..,.... .. r,►._• --'~-! .:. ,_.;,O 1 1 1 1 1 1 l 1 l 1 l 1 1 1 1 1 I I I I I I I I I I m m ANALYTICAL TESTING & CONSUL TING SERVICES P.O. BOX 31486 •CHARLOTTE.NC 28231 • TELEPHONE (704) 527-4183 • FAX: (704) 525--0409 Ram Lec-,t~.er C2.-:-·e Pa □e: E, October :;,~. 1991 HALOGENATED VOLATILE ORGANICS CHLOROETHAt,E CIS-1.2-DICHLOROETHENE ETHYLEN~ BRO~~ I SE !PE MTE'.E f!TEX Gre,d . .., l-I. B1.i.t· o i :-, ~2b:~atorv ~a~2c2t· ( er;,;,": i !"";1.te:I} 1.1.C/L 1.to /L u □/L u □/L :.:o/L J.i.[J / !... hiGt Not Net Not Nc·t Nwt Det Det Det Det !)et [•et 449 SPRINGBROOK ROAD• CHARLOTTE, NC 28217 1 1 1 l 1 I I I I I ANAL VTICAL TESTING & CONSUL TING SERVICES P.O. BOX 31486 •CHARLOTTE.NC 28231 • TELEPHONE {704) 527-4183 • FAX:. {704) 525-0409 October 2C. 19"i1 Ra □ Le5the!-C2~-E Htt:-:: E. Clif'7 We:~·lev 1Sl00 Alj2r·nar·le Rd Ct--.a.dotte. f!. C. 28227 I De 2-~-r-r:·:·. l-!or le v: I I I I I B 0 m m Below &~·e r·esults 0f ~~&:vsis of 4 C'.: Sec.te~be-;,· 24. 1cc1 • Customer Code: RAM ~'~:~E ~J~m~e~-= (7e4) .S~~-~727 LAB !.D. AA0813~ E:l~ !~ N,~mbe~-G412Hl-~ P:ld C~tstc~€:-~~~~~E~-E,74S Collecticn Date: 0S/22/g1 S·:~citt&l D~te: e~/2~,'51 -:--:::ST PARA:--:ETEF ~~ltice:~oone~t aralv:i:: E.RO~OD!C~~ORO~ST~·iA~E I: FO'.':".O!=""C~!Y. ~.;:;:□'.Y:J:"'.ETHP.\:E CPPBON TETRACi~LORIDE C ~'.'.....0 ROE-!::r-.!Z ~~-~:::: ~1--'.:_c :=.GETl'":At ~E: 2-c~:_oR □ST~iYLV!~~YL ET~[R CH'...ORQFORt~ CHL.OROtt;E::T~At~E DIEROl~OC!~LOPOMETH~~~E 1.2-DICHLOROBE~ZE~~ 1.3-DJCHLORQEENZENE 1.4-D!CHLOROBENZEr~E DICHLORODIFLUOROMETHANE 1. 1-DICH'...OR□ETHANE 1.2-DICH'...OROETHA'.!E 1. 1~01CH~OROETHE~E 7"RAKS~l.2-DiCHLOROETHENE 1.2-DIC~!~OR□;·R □PA~~~ C!S-1.3-DICHLOROPROPENE H:~;_']~,E~-!A:c:r::, !.1 o;_H: r LE ;_;_::;I/ k :::i :_: c:/ kc 1.l □1/k □ I.(□/~(□ I.\C / k 0 uc/J..:c :.•.o/1-:c ·.:C / \-: C ".\CO I k Cl 1_•.c / 1-: !J '.'.□I,: □ u.c/~c '.l□ lk!J 1.r.□/l-:0 ·.:c / k o 1.;!:./ko •;.c / ~. C 1.t □ I k □ □PGi::1:--ncs r-.!:, t Dct t"~ C· t S' ~ t ~,!c,t [•~t 'kt DEt r-~Gt Det Nc-t Det ~-,Jc, t Det N.:t Let ~~: "t [-c:-t r-.; ·= t C·=:t ~< c-t D·2t ~~ct [,et Not Det ~\-:, t Det r-iot Det J-\ct Det N :Jt Det ~~Ct Det r-ivt Det t·~ C· t [ et TRR~S-1.2-DICHLOR□~•R□~•ENE uo/ko NGt Dst ~ETHYLENE CH~ORIDE 1~0/k □ Net r~t :. • ~. ::. 2-:"E::::TRf'.=\Cf-'.!.....OROET!--h~~~E :_,c/k!:J rJ:,t D:t TETF:,:.Cf-lLOF:OETHEt:::: 449 SPRINGBROOK ROAD'-CHARLOTTE, Ne 28217 10 10 10 I I I I I I I I I g D n m ANALYTICAL TESTING & CONSUL TING SERVICES P.O. BOX 31486 •CHARLOTTE.NC 28231 • ~PHONE (704) 527-4183 • FAX: (704) 525--0409 Ra.m Le-att-,e'!'~ C2.~~e Pa □e: 2 October 3121. 1991 HALOGENATED VOLATILE O~GAN!CS 1. 1. 1-TR I CHLOROETHm,E 1.1.2-TRICHLOROETHANE TRICHLOROETHENE TR!CHLORO~LUOROMETHArlE \..1 I~~YL CHLORIDE MTEZ (c:·orit ir:uE:::; u'c I k o u □/ko 1.t □/kc 1.,e:/k □ l.lC / k C 1.'.0 / 1-: □ IJO / I"\ C: '.t::: / K. □ ii~ t Det Not Det N e:t Det · r\wt Det Net Det N.o t Det ~~Ct L'r..: t Ne:t D=t 10 10 10 :0 ------------------------------------------------------------------·------ Comments: t· •.t::. r. Custo ■er Code: RAM i='!-:::.e ~~-.\r.;::-e:·: (7C>:4) ~L1.S-·S727 LAB I.D. AA08137 2-~lC ·re, i·>:.c~e:·,· :L;::!-::'..-4 E~lG C•.c;~::;:e'!'· ~~1;_1:1::e·.-,::.c;.:: Ccllectic~ Date: 0S/23/91 s~b~itt~: c~te: 0S/24/S1 c~stG~E?" s2~=!e !.Df: BOR!~J[ ------------------------------------------------------------------------- T::ST RC':: 1_1:_ T DET~CT I or·~ L.P,:J T ------------------------------------------------------------------------ E RO'."-'.:COF:'.':': E ?2:'"".0::~E::"T H~{~~;:: CYL._Q~1::ETHAr~E 2-CHLORO~THYLVINYL ~T~~ER CHL_O POFORl"'i CHLORO~:::T~:A:,~~ CI e F:O".::JCHLO r::o:--::::-;-c:r 1:c: 1.2-D!C~~ORDB~NZEN~ 1. 3-[, I CH~OF.OEEr'~ZCr'![ 1.4-DICH~OROBENZENE DICHLORODIFLUOROMETHANE 1.1-DICHLOR□ETHANE 1.2-D!CHLOROETHANE 1. 1-DICHLOROETHENE T:=:~:l·:-~-1. 2-L' I CH'.._090E7HE~~:.:: !.2-D!C~~OROPRO~•AN~ CI '::-1. ::,-r: I CHLOROPROPE:·,E TF.ANS-1.3-DIC~LORO~ROPEN~ METHYLENE CHLORIDE '.1:::1 /k.c; ,.•.c/kc •.L □/l--:o :Jo/ k ~ 1.\C,/ k □ :)_c/kc u::!/ k □ • .. c'/ k Q 1.ic,/k □ I 1.1::: / L c •~o·/ k □ l.'.0 / ].: C ·.'.□ / k C :_1.c / 1.-: C •.to'/ k o 1J □/ko I.\C / k Q O~'.::i~.:-~IC~- Not Det 1.1 _ .. I:et ; ~ ._. \,, N: t Det >' -.. Us+; ;,•_; . i':~t Det ~: ;::, t De: t ,-I -.. u~ .. )"•.·-' ;--~-= t [-st ~~ :,t Det t\' C: t [12 t r-,: :-t Det 'N-:t Det r-:c,t Det Not Det tfot Det ~~ ~ t DEt N ~t Det t·~o t Det ~--.!: t [·et N-:-t [•et 1\!c,t Det r,~ •~ t Det 449 SPRINGBROOK ROAD• CHARLOTTE, NC 28217 lG lC. 1 IC 10 .1 C :0 ,-,. .;_ ._, . ,., .1 •.· 10 :.0 ~e -c, 1 i.;_,, ' l) 10 : :J 10 10 ~ t~': 1C: 10 :c: I I I I I I I I I I n B m I ANALYTICAL TESTING & CONSUL TING SERVICES P.O. BOX 31486 • CHARLOTTE, NC 28231 • TELEPHONE {704) 527-4183 • FAX: (704) 525-0409 Rar.; LeathEt"' Ca"?"~e Pace: 3 October 20. 1C3S1 HALOGENATED VOLATILE ORGANICS (cc~ti~uedl 1. 1.2.2-TETRACHLORCETHAflE T~TRAC~~OROETH~NE 1. 1. 1-TRlCH:...O~OETHAt~:::: 1.1.2-~R!CH~OROETHA~E TRlCHt....ORfJETHEr-.!E TR!CHLOR □FLUDR □METHA~E IPE t-1TEE 1.1.e!/kc un/ku 1-1.:: / k 0 l.~2 / t-'. 0 i.ta / k a '-lC/ko !.\O / k ~ 1_1c/kc ;_ic/ko t...: C:; Det ~-!ot Det Nc-t Det ·Not Det ~l~t Det N-:,t Det f' -~ ... ·-., Det Nat Det Net Det Not Dot 10 10 10 10 1 C,, 10 ---------------------------------.------------------------------- Customer Code: RAM P~c~• LAB I. D. AAQIB13B Ee ld H· F-::·D~".OfC•Rr,: E P.~;---:o:--,,-.:=:~.r;i~ ~E CPE30'.·~ TETRACHLCRID~ C~LOROF □R:"", CHLOROME~f-:;ir,E DIBRO~OCHLOPOMETHANE 1.2-DICH~OR □EENZENE 1.2-DIC~~OROEE~ZE~;E 1. 4-D!CHLO~OBEr~z~N::: 2!C~~~QRODIFLUOR0~1ETHANE 1. 1-DlC~1LOROETHA:~E i. 2 -· D ! [!--;:_QP2ET!-~;:;:·1E l. 1-DICHLOROET~t~NE TPANS-1.2-DJCHLOROETHENE : . 2-C· ! CHL...OF:O~·pc:~•f'=1~-'.E: CIS-~.3-:!C~LORO~'R □~·Et~E ~~LC~Et·lAT~D VOLATILE !:.,1/~·n _, ~I '..., 1.'.C / !-: D .. d1r,.c uo/i-::::: :_•.c/kc 1.1• Ci / K !::l :_;o/1-<c IJ :l / ~: □ :;. C. / I•'. C 1.:.0 / ~: ~ 1.:c.'kc .. ,□1/k~ u □Yk □ l.t □ ( k □ uo/k □ '.'.C! / k □ u □/1-;o ·.,□I k ~ 1.,0/kc T~ST F:::-U'....: oc:Gr:n•:rcs ~~ot I::? -t l-..!-:-t L'i= t "' -...... [:=:-t I,; -• • t·~ Ct DEt r<: t r:·::: t ~'-.!-: t DEt r--1c.,t Det t\ -=· t Det N:it Det r,:c,t Det ~~ :-t Det t-' -"--Det i~:. t Det Net Det r~ot DEt Net Det ~..:: t Det '.'~ Cc t D ~ +- ~-::-t I' est :-..: ,:-t r--"" -,;:: . 449 SPRINGBROOK ROAD • CHARLOTTE, NC 28217 ' T ,-_.; T .... -' ',I. • 10 ~c ·10 -.-,. I I I I I I I I n n R I ( Bold Re~~ 0 ~!Ch Labs) ANALYTICAL TESTING & CONSUL TING SERVICES P.O. BOX 31486 •CHARLOTTE.NC 28231 • TELEPHONE (704) 527-41 B.3 • FAX: (704) 525-0409 Ram Leathet· Care Paoe: 4 October 30. 1S91 HALOGENATED VOLATILE ORG~~ICS TRANS-1.3-DICHLOROPROPENE METHYLENE CHLORIDE 1. 1.~.2-T~TRACHLOPOETHANE TETRACHLORO~iH~N~ 1. 1. 1-TRICHLOROCTHPN[ 1.1.2-TF-~IC!-L.qRO!:::THHN~ T~ I C!-:"L..OROET!-:Er~E TR!CHLDR □FL~OROM~THA~~ ~'HNL CHLORIDE !PE MTF'E E,T~J'. Ce::a:r.;e:-.t :c: ,_. '. -I-.. ;;; . (cont ir:1.te::!) uo/t<o uo/ku 1.1.c /ko tc= I k o 1-:c/\-:o •.•.a/ko 1.10 /kc l.'.□ I k [l ·.,o/ko :_:_o/ke! ·.,o/ko '-'.~ / l-: .J ' Customer Code: RAM ~'~~~2 N•!s~sr: (704) 545-~737 t,ct Det ~-lat [Jet r:ot Det Not r·-:c t r-.:i:t Det DEt [1 et [£ t Det Dt:t Det N~t Det ~~-:t Det 10 :c 10 10 LAB I.D. AA0813q Bold ID N1J~~e~-[L112~1-4 B~:d C~sta □e~-r~.(~~e·· -~4~ C::lectic~ ~ate: 0~/23,'?1 S.:~~itt~: D2t~: CS/24/Sl .S~t~it~~l Ti~:: 07~24 C1.1.st :c;,;e~-SE; .. :Wl e I. [Jt: SP~-1;:•'.._~ 1. B-i4 ~-;!ticcc=cr~~~ ~~al~sil: HA~OG~'.~ATE[= ~1OLATILE DR~~IJDICH~O?O~ZTHANE u=/~o BROMOFOR~ ~t □/ko C~L..OROET!~A!·~E 2-CHL□ROET~iYLVI~YL ETH~R CHLOROFORM CHLOROMETcH'\:,E DIBROMOCHLORO~ETHA!·~~ 1.2-~ICHLQROPE~JZEN~ 1.2-C!CH~OROBE~JZENC :.4-DICH~OROBENZEtJ~ D l C!-'.~1JP8D I 1=Luo~:O~E":!-'.P(·;:::. :. 1-CICHLCRO£THANE :.2-DICHL □RDETHANE I. 1-DICHLOR □ETHENE '-· O / k D uc/k;: ·.·.C / 1-(C 1.:~ / \-< D '.'. C: / !-'. 0 l.\'::l/1-:c :.<2/kc ORC:.A:'; I CS ~l :-t r·e-: ~-~ ,: t [• E: t ~--~ ,:. :-Det ~I: t Dr: +- ~-le-t [•et t' -+ '~ ..... ~ [·et ... ' -.:.... L•~t .. , -. f\; C, t Det ."-~-:-t Det Nc-t Det ~-lat Det ~✓ c-t Det Not Det Net [-et ~~: t [1et t'\ct Dct f.lJ t D~t 449 SPRINGBROOK ROAD• CHARLOTTE, NC 28217 . ,-., ;.. ,_. 10 I I I I I I I I I n D 0 D I ANALYTICAL TESTING & CONSUL TING SERVICES P.O. BOX 31486 •CHARLOTTE.NC 28231 • TELEPHONE (704) 527--1183 • FAX: (704152S-0409 Ram Lee.the"?"· Care !="•ace: 5 October 30. 191:;1 · HALOGENATED VOLATILE ORGANICS TRANS-1.2-DICHLOROETHE~E 1.2-DICHLORO~ROPANE CIS-1.3-DICHLOROPROPENE TF:A~~S-:. 2,-D ~ CHLO R□;::•R □;:•Et\!E METHYLENE CHLORIDE 4 1._.2-TETRACHLDROETHA~~S TETRACHLOROETHENE 1. 1. 1-TRICH~OR~ETHAr~~ .i.. 1. 2-TRIC!-i:_□ROETHHt'~E TR I C~:L □RDETH:C:NE 7RIC~LOROFLUORO~~THA~~E \..1 1>~--:✓'..... C!-L ... Or: .. IDE IP~ (, ru_J L\ LL) '3llJ\c1 [:·~.:.:-., l,,-J. E 1•1.r·ci·:. ~~-~o~-2t::·v ~2Gac2~- --- (cor.tir:ued): l.lC / f...; □ 1.,□/kl:l uc/k □ uo/~c :.(□/h:□ '-' D / k D 'J □/1,c _uo/Kc 1.(.::::/]-<□ uo/k □ '-<□ I ho :.!:i/kc :.•.c/ko :.1.c/ko ._,c/k= !"!ct D~t N:,t C·:::t Not [·et Not Det t,-:t Det Net Det ~,-ct Dct ~-~Gt Det t<ct Det Not Det r<:t Det ~~at Det i'~ot _Ds t ~-~c•t DE~ 449 SPRINGBROOK ROAD • CHARLOTTE, NC 28217 10 I I I I I I I I I I I I I I n I u ANALYTICAL TESTING & CONSUL TING SERVICES P.O. BOX 31486 •CHARLOTTE.NC 28231 • TELEPHONE (7041527-4183 • FAX: (704) 525-0409 Rc.r:; Le,;,.the';·· C2."!--e Attr,: E. Cliff ~c-lEv ~'5100 Alterma.r·le C>--,.a.,·ldte. tL C. E-elow are t'et·~lts of 2.nalvsis c~ 1 c-:-. Se=·t-=mbe~--2-'-:. JS'·?i: Customer Code: RAM ~·:-,Q:-,= ~~-•.r::::~r: ~7t04~ LAB I. D. AA08140 Be :co :L ,.; .-.::i::a·· L;; 2,''. c~:le=tio~ Date: 0~/~4/Sl E~~~itt~: Da~e: 0~/24/Sl ------------------------------------------------------------------------ TC':": :: C ·=: ': .,. ,. ____ , :::c:::r: ~-: c;:-: !.... I~: IT ---------------------------------------------------------------------------- E S:J!"':8C· ~ CHLO F:Oi":E:::T!··;r~t<E:" BR0M0!'"0R~'. 2-C~ILORO~THYLVINYL ETHER Cl-:LCJROFOP:V: CHLC'F:0METHA~,E D!EROXOCHLORO~ETHAl·JE 1.2-DICHLOROBENZENE 1 ._3-D I Cf~'.:....OR.OE!::t-~ Z E~1:E 1.4-DICHL0R0BE~ZE~E DICHLDR□DIFLU0R0METHAl~E 1. 1-DICHLDR0ETHANE 1. 2-D I CHL0R0ETHAtlE 1. 1-DICH~ORDETHENE TRANS-1. 2-DICHLD'::OETHEt,E l.·2-DICHL0R0PR0PANE ::rs-1. 2-DIC!-'.LDR □r:·F0:::·El)E TRA~!S-1.3-DICH~□R□~•ROPENE ~ETHYLENE CHLORIDE 1.·:.2.~-TETRACH~OROETHAt~~ TE·1-RACHLOROETHENE ._, _ _c /L . uci/L .'.::::i /L ' " :;.~I'- ·.1.Q _IL uc/L... 1.1.c /L l.'.□/L i.:c/°'- IJ □/L ,.,.::::i /L i.i.C /L u □/!.... :_i_ C /L. :J;: ,'~ 1.tu/L 1.:.c/L '.'.::: /L 'JD /i... c:r:~-;~>11 c:s !~ ~ t D s-t r~o t Det ~-· -"--r::et . ~ -· ;. ~, :-: [-.::.~ N,: t [-=: t :'< C -!:. [:et ~~ ,:, J,: L·~ t lo. I --'-=~~ t ; ~ -. r~ -:-: [·~ t Nwt Det ~~ -:• t D at t·,,:,t Det NGt Det r·-i e: t Det Nc,t Det l\!:Jt Det Nc,t Det Not Det Net Det Net :_,Et I·:: t Cet N8t Det .:.: 1. 1. 1-,RI CHL0R0ETHi;\49-SPRINGBROOK RGAt,, • CHARLOTTE, NG~82'f'7" 1 l 1 1 1 - 1 1 'I I I I I I I I I I I I I I I I D u ANALYTICAL TESTING & CONSUL TING SERVICES P.O. BOX 31486 •CHARLOTTE.NC 28231 • TELEPHONE (704) 527-4183 • FAX: (7041525--0409 Ram Leather Ca.~-e Pa □e: 2 October 3'21. · 19':t 1 HALOGENATED VOLATILE ORGANICS (continue~> l. 1.2-TRIC~LOP □ETHANE TRICHLOROETHENE TRICHLOR □~LU □ROMETHANE VINYL CHL_ORIDE CHLOROETHANE CIE-1.2-DICHLOROETHENE ETHYLENE BROMIDE IP:.:: tc".TE-E B.,.EX t.t□ /L ,.,o /L uc/L i_to/L u □/L '.\O /L 1_:c /;_ 1.t::::i /L •.·.c /L 'J □/~ Not Det Nvt Det Net Det Not Det N~t Det Ne;-t Det Not Det ~~ ot [ic4--. ~-.j Ct Det Nc.t D 12 t 1 1 1 1 1 ------------------------------------------------------------------------ Ccr.imer,ts: C: t· z.,..:: •.; L,;. E ,_._ !" c i r. La~c~atot·v ~&~~□er 449 SPRINGBROOK ROAD • CHARLOTTE, NC 28217 I I I I I I I I I I I I I g B u ANAL YTlCAL TESTING & CONSUL TING SERVICES P.O. BOX 31486 •CHARLOTTE.NC 28231 • TELEPHONE (704) 527-4183 • FAX: (7D4) 525-0409 Octc·ber 30. l':'l! Ram Leathe:~ Cat~e At t n : E. C l i ff W c,· l e ,, 1 ':: 1 00 A 1 be 'r-m ~. ~-l e C~,ot· l ut·t 2. ~~-C. 2222:7 Selow a~e r~s~lts c~ 2~alvsi£ of~ sa~~les t·~c2ive~ fo:· exa~i~a~io~ en Seote~~e~· 2S. 1g;1: Customer Code: RAM ~1~c~2 Nucbei~: (70~: ~4~-S737 LAB I.D. AA0811S0 E,~,:::·rD r,.:1_·,rn'.:·(='r" [JL::-s:-1:-2 E,.:lC C•.istc:lil~-:--~,:.tr:1b-=-·--t:-7~'1'.: Collectio~ pate: 09/2~/~1 ~ :.t::-r.: it t c. l C·=-,.t ~: 0'=: / 2~ /·:··: ----------------------------------------------------------------------------- L.::T::C""."":!:O'.·.'. ~~:,·.I: ------------------------------------------------------------------------- !? R'J~,.., 1:J :, I C :-~:_ C1 r=:Oi':E T!-'.Hf,~ E 2:-_,Jl"'.C\~[l~M C!-'.:...O F:CEEr·~ Z Ei<E c:-:L...o :=;:0~1!-:;::J:: CH:...O"iOFO'<t~ DIBRO~OCH~OROMETHP~-JE 1. 2-D I C!<'.....OP.OP,!::t~ZEtJE 1.3-DICH~ORCBE~;zE~:~ 1. 4-DICHLORO!?-E~~ZEr,1E DICHLORODIFLUOROMETH~~~ 1.1-D!C~l-□ROETHANE l.2-DICH:...OROETH~NE 1.1-D!CHLOROCTHENE TRANS-1.2-CICYLOROETHE~E l.2-r!Ci-~L...OROPROPANE CIS-1.3-DICH~OROP~□~·c~~z TR~~S-1.2-DIC~~ORO~RO~'E!~E ·.·.:::/ko :_:_c / 1-: C · ... □/ko '-'·= :',.; C ••1.C / k:::: '.t'2/~::.i uti/kc. :_,j / ~: □ 1.(0 / ].•. Q 1.\0 /~;CJ .·.CI 1-:o '.".C / j-( C ,.·.a I k 8 ·.1.c/l-:0 =.::::/ ~: = uo/1--:c ~~THYL...CNE CHLOR!DE uc/k □ C r::C:-P:·-~ IC~, t·~ :-t Det f\.;::,t Det \'. :-t D '= t ... ,,. ,._ L'<'-' >.· Det , .• -+-Det . ' -... ~-! C: t Det t·. -•. '~ -· .. [1e t N0t D::t r-~ ~ t Dct ~/ :,t Det !\! =· t Det t ~ :, t Det Ncot Det ~-Jot Det ~~0 t Det Not Det Ncot Det r, c•t Det N,ct Det t,l_ +-Det ,,~ ... t·!: t ['Et t\: :, t L1et 1.~.2.2-TETRACHLOROETHA~l~ uc/kc r~~t Cet -:-:::rRAci--::...oro==THENc 449 SPRINGBROOK RGAD'-CHARLOTTE, Ne"2sf# 10 1 Q, 10 I I I I I I I I I I I I I I D u ANAL YTJCAL TESTING~ CONSUL TING SERVICES P.O. BOX 31486 •CHARLOTTE.NC 28231 • TE,LEPHONE {704) 527-4183 • FAX: (704) 525-0409 Ram Leather· Care Pace: ·2 October 20. 1991 HALOGENATED VOLATILE ORGANICS Ccontin~edl 1. 1.1-TRICHLO~□ETHANE 1. 1.2-TRICHLOR□ETHANE TRICHLOROETf-'ENE TR!CHLORO~LUORO~ETHANE V!NYL CHLORIDE I;:•~ r<TEE BTEX 1.to/l-:0 u □/ko ,_,_Q/kc 1.t:i/k:i t.lG / \-: C u □/ko uc/hc 1.:0/\.-:0 Net Det i~::,t Det Nat Det ·Not Det t,~ C· t Det Not Det t-..! c-t Det t-.!8t D12 t ------------------------------------------------------------------------ Customer Code: RAM ~·her-is r·'1u:::t::.e·:··: {704) 545-S737 LAB I.D. AA081Cl1 Ec,lC lD N•.,r.i~e)· G:42SH:..-.::: EclC C=.•.stc:-De~--~<·:.:c:t:-~:-· ~7.!.i'::· Collectio~ Late: 0S/24/gl S:1tmittal Date: 09/25/'?1 C·1st~mer S2~~le I.D#: E-12.20' ------------------------------------------------------------------------ ":EST J:·ARA~1CTER 1 J>,,ITTO:: _, ..... -TES:" F:CSIJLT -------------------------------------------------------------------------- ~~lti=o~o0~e~t a~2lvsis: E.RO~QC!C~~:....ORO~~THANE ~i. ~:Dr--:oi--o ~:f"', ~~LOSE~~~1CD V~~ATI~E t_lQ / \-,; ~ CHLDROEENZEt'>IE cr'.'.._['~OETH~.\N[ 2-· C! ~:....o :::2:::I-'.\'L ~-· ~ t--~·':'L ET HE F C~-::__ ~ FOFO F;tyi CHLC f?IJr,.:ET!-:P~<l::: C!BRO~OCHLOR8~~~~R~JE 1.2-DICHLOR □BENZ~N~ 1.4-DICf-'L □ROPENZENE DICHLDRODIFLU~POMET~~At~~ 1. 1-DIC•!LC~OETf-'AtlE 1.2-DICHLO~OET~A~~E 1. 1-DICHLOROETHE~E TRANS-1,2-DlCHLOROETHENE 1. 2-DI [HLOROe•R·oPAJ•'E C!S-1.2-DICHLOROPRO~ENE TRe;J·:S-1. 2-D ICHLOROVi::OPENE ME~~YLENE CHLORID~ 1. 1. 2. 2-·TETRACHLOROETHA'.iE 7S~RACHLOROETH~N~ 1. ~-1-·:-r:.~c1-::....0!~0ETHP.NE ·-1.::;/Ko :.•.C / k o :_1.0/kc l_',Q / k D .. l ,'I' -_\i' I ,-.... 1;,G/l-::: IJQ/\~ □ I :.'.~/:..:□ ,_,.d/kc l_'.D / k D uo/kc :_,.S:, / ~: □ 1.1.c/l-:= •-·-□ / k ::1 l_l D / k 0 •_1.0/ ~: □ l_lO / \.-: C 1•1.:J/ko I_I_L:VkD ;_,_c/k □ 1_:.c / 1-: C '}SI k □ ,.,c I k □ D~::-~i>~lC~ Net Det J,ct Det r.:.:t [•at N-::t D;;t t·~ct !::2t :-~-::t L-:::t :-:ct Det hlc-t Det r,\:,t Det N:•t Det ~<:it [,~t N::t [',::t [\~: t t·~ Cit \!Jt Not Det [:Et Det Det Det Det Det Dat Dd I'.• Et D~t [-et 449 SPRINGBROOK ROAD• CHARLOTTE, NC 28217 10 ·1 (,"- :i.12', 10 10 ANALYTICAL TESTING & CONSULTING SERVICES P.O. BOX 31486 •CHARLOTTE.NC 28231 • TELEPHONE (704] 527-4183 • FAX: (704) 525--0409 Ram Leather Ce.re Paoe: 3 October 30. 1'3'31. HALOGENATED VOLATILE ORGANICS 1.1.2-TRICHLOR□ETHANE TRICHLORO:C:THENE TRICHLOROFLUORO~ETHANE VHNL CHLORIDE Ie'E MTEE ETEX (cor1t ini_led) uc/ko l.l □ / k 0 l.lO / 1-: 0 '.t □/k □ 1.~c /kc r.i.o/k □ u □/ko N:'t Det tJot Det Not C·e t N:•t Det ~Jct Dtt Nc,t Det Net Det 10 10 !C' 10 : I? 10 J..C I I I I I I ------------------------------------------------------------------------ I ResGectfullv submitt&d. I I I I I I I I D I 449 SPRINGBROOK ROAD• CHARLOTTE, NC 28217 I I I I I I I I I I I I I D D I ANALYTICAL TESTING & CONSUL TING SERVICES P.O. BOX 31486 •CHARLOTTE.NC 28231 • TELEPHONE (704) 527--4163 • FAX: {704) 525-0409 OctGbe,· 2C. 1991 R2.r.1 Le c.t h et· C c-:r·· e 1~tt,.: E. Cliff J.,;c:·lcv !5100 Albet'm~~le Fd Cr".c.:-luttE. N.C. 28227 Eela1, at·e re~~lts of analvsis of 1 er: ~ecter.:t.e:· 25. lSS-~: Customer Code: RAM !='~.o;-,e ~-1:;_r.:'.:s·:·: (7tl!-~) 5 1~!:-9737 LAB I.D .. AA08159 E:·l::'. ~D ;~1.1r.:=.er G1-'.i-27H! Bcld C•Jstor:-.i;:-~--r\,;.c::.-e·:· E:-7~'::- C:l!e=tior ~ate: 0S/2~/~1 ~~t~itt~l Di.t~: 0S/2S/S1 C·1Etornrr Samele I.D*~= B-12 I ' -,-~,::....- -----------------------------------.-----------------------------------· ~~:tic~~~o~~nt ~~alvsi~: HALDGE~ATED VO~A~!~E Ef~O!~O~!C~LORO~ETl~Ar~~ i}o/L PSQ'.~OFOR~: ~~/~ 2·-C ~~C.1 ~;'.OET!-·:Y~ V ! '. ~·1L.. ET!-:::: F: C!-oLO R:OFO RM CHL.ORO~ETH~~-~~ CIBSO~OC~'....QRO~ET~:Rtl~ 1.2-D!C~LOROB£r~ZEN~ 1.3-DICHLGROBENZE~E 1.4-DICHL.OROBEt~ZE~~E DICHLORODIFLLlOFOMETHANE 1.1-DICHLOROETH~NE 1.2-D!CHLOROETHANE L ! -DI CHLO ROC:THE~!E TRAliS-1.2-DICHLOPOETHENE 1.2--CiCHLOR □~·ROPANE C: I 5-~. 3-D I C!-i'..__ORQ!-•r:.o:-•::r~E TR~tJS-!.2-D!CH:_□ROPRO~•E~J= ~ZT~-{~E~~E C!~LORIDE 1.·.0/'._ 1.:c/i_ :.i.::i /L •:.o/L •.t:::i/'.... l.iC/L ·.1.~/L 1_J /L :_:,~ /L. 1.•.c /L •.:.□/L 1.~□ /L U!::) / L, 1:.c/:... uc/'.... l.',i:, /:._ 0 ~C:-.C)>~ l CS !'J: t ['t:t ~~c:t [:~t Nc-t [ct ~~ eit Let ~,' -,. :"'-_ ..... I'._. . .... I:: - r,!a:it Det r,1 -,._ !:·Et N-~t [•et r,1 -... ' --[1= t N,::,t ['et Ne: t Det N-:,t Det :· ~: "'; Det N~t Det t,: t Det Not Det ~;ct Det N:>t Det Nut I:'E t ~~o t e-~ C C ~~ c-t [2t 1.:. 2. 2-TETRHC!--IL □r~□~T~lrlN~ 1.lc/L ~-'.-:,t [1:t TE~RACHLOROETHENE ~□/L ~~ct Det 1. 1. 1-T RI CHLOf'IOETH14~ SPRINGBROOK R(9Ai!. • CHARLOTTE, NG'28l!'f1: 1 1 1 1 1 ; 1 1 1 1 I I I I I I I I I I I I g I I ANALYTICAL TESTING & CONSUL TING SERVICES P.O. BOX 31486 •CHARLOTTE.NC 28231 • TELEPHONE (704) 527-4183 • FAX: [704) 525-0409 Ram Le&thet' Cat·e ~·a □e: 2 October 30. 1S91 HALOGENATED VOLATILE ORGANICS 1. 1.2-TRICHLOROETHANE TR I CHLO ,WETHENE TRICHLOR□FLUOROMETHANE VINYL CHl_ORJDE CHl_OROETHANE CJS-1.2-D!CHLOROETHENE ETHYLEIJE BROt"'.IDE JC•:C •,-:--p7 I,.-·- BTEX C-:::;rr.mer,t s: ot·o•.t:ld1-";2.t er (cont i;1ued) : •.:.c./L N.::-t Ds·t ll □/~ Not Det u.□ /L Nc-t Det uo/L Not Det uc/L · Not Det IJG/L Not Det :.i_::::. / L ~ot Oct l.iC/L Nat Det l.'.W/L N;:, t Det IJO/L "I-.+ '" ._ " Det 449 SPRINGBROOK ROAD• CHARLOTTE, NC 28217. • • 1 1 1 1 • 1 1 1 I I I I I I I I I I I I D u I ( Bold Re~~ 0 ~rch Labs) ANALYTICAL TESTING·& CONSUL TING SERVICES P.O. BOX 31486 • CHARLOTTE NC 28231 • TELEPHONE (704) 527--41B3 • FAX: (704) 525-0409 \'.=-ltt.:-.: E. Ci i ff L-J~.-.· 1 ~1.1 :~:~~ Albe)·~al·]e ~□ Bel~w ere results cf a~~lvsis of 7 sancles t~eceivej for examin~tic~ CustoNer Code: RAM LAB I.D. AA08532 10/21/Sl C::71~~-7 f.:--~,j :..:.__._~tC':\~·:· C0llect10~ 11re: !~:20 ~~.lti=omoa~e~t analy~is: H~LOGEN~-r[D VOLA~l~E fSOMODICHLORO~ETY~~J~ 119/k~ BRU~O~UR~ iJg/k~ E f:. :.:ir11CW1ET!...J_~: ~[ :_, ~ / k;: C~?BO~~ TET~ACHLO~!D~ •Jg/k~ CHL0~08Et~ZENE ug/kg CHLOROETHANE ug/kg 2-C~~OR0~1-H1'LVlr~·{L ETHER C:--'L U ~-<0~' ll Rl"r: C HLfJF==1r:iETHPt'.I'.:: DlERUMOCHLOROME"rHANE 1.2-DICHLOROEENZENE 1,2-DICHLORDBENZENE 1.4-DICHLORO~ENZENE DICHLORODIFLUDROMETHANE 1 ~ 1-D I CFLOFCiET:--iA!-.:E 1,2-DICHLOROETHANE l. 1-DlCHLOROE::lHEr,E TRANS-1 1 2-DICHLORDETHENE 1.2-D!CHLOR □~•ROPANE ClS-i~3-D!CHLORO~•RO~·~NE TRAris-1.3-DICHLORO~·ROPENE l.il:;)/kp 1.1q/ 1-·g ug/kg I}_ C: / k ~ i.1g / k ~ u~ I k ~· ug/kg l.\g/kg l.tg/~.g l.'.0/1--:~ 1_1.g / k ~ 1_1,g/l-:g ug/1--:g qr·c.1 I: ·r • ·----I Of;:GHr-: 1 c:; r·~ c-t i:Et ~,ic,t t':'t f',~ ,:, t [ct r.iot ri?t r·J ,:• t [:e--:: ~~ ot Dst r, o t DEt r-.!c,t Uet. r-.J :-t De t r,.;ot LJet t-..:c. t [Et r·~ c,t Det Net Det ~-.:ot Det t\:ut Det Not Det NGt Det Not Det Not· Det 1Jc, t Det Nc•t Det ME1HYLENE CkLORIDl~ ug/kg Not Det 1, 1. 2. c'-TETRACriLOROETH,C,l·iE <Jg/kg r,c,t Det TETRACHLOROETHEr,:=. 449 SPRINGBROOK J'i'oA6~ CHARLOTTE NC28~1''? -10 j:Z, 1 t?: 1 ll 10 10 I I I I I I I I I I I I I I D D I ANAL YT}CAL TESTING & CONSUL TING SERVICES P.O. BOX 31486 •CHARLOTTE.NC 28231 • TELEPHONE (704) 527-4163 • FAX:. f704) 525-0409 Ra.m Leather Care Page: 2 October 31, 1551 HALOGENATED VOLATILE ORGANICS 1, 1,1-TRICHLOROETHANE 1,1,2-TRICHLOROETHANE TRI CHLOROETHEl>JE TRJCHLOROFLUOROMETHANE V Ir>JYL CHI_OR l DE !PE MTE-E BTEX MINERALS SPIRITS (cont ini.ted): '-'Q/kg '-'Q/kg ug/k~ ,_,_g/kg IJQ /kg '-<glkg 1_1 g /kg ,.,g/kg mg/kg N-ct Det Not Det Net Det Not Det Not Det Not Det Not Det Not IJet M1Jlticomponent analysis: AROMATIC VOLATILE ORGANICS BENZEt,E CH'....O ROBEt, Z ENE 1,2-DICHLOROBENZENE 1,3-DICHLOROBENZENE 1,4-DJCHLOROBENZENE ETHVLBENZc.r,E TDLUEt\JE x'YLENE METHYL TERT BUTYL ETHER ug/J.,:g ug/kg I.( g /)..; Q ,.og/kg ug/Kg ,_1,g/ kg 1_>.g/~i[;! ,_,g/kg '.'.C /kg l.tg/ kg Custo ■er Code: RAM !='hone Numb1:r: (704) 54~-Sl73? ~~c•t Det Nc,t Det N,:,t Det Not Det t·Jc-t Det t,ot IJet Not Det Not Det N::•t Det Nwt Det LAB I.D. AA08533 B·JlC: ID ~;ur.,t::,E·~--l::S71H:!.-7 Eoid Custornei· l\~ur.ibe:r 67.:i~- Collec-tio:1 D='te: ,10/21/<::11 Coll-ect1,Jn Time: 12:0'.:::, S•.1.br:itt~.l Di=te: 10/22/91 Customer Sample I.D#: 815-10' TE-=.T l='AF:HMETER S1Jbmitta.l Time: 11:'::.,E: TE::T R[SUL T fT11.1l t icomponent ar,2.lysis: HHLDGEi·~ATED ~•O~AT ILE ORGAI, I CS B ROMOIJ I CHL.OF:Oi"ETHA• ,E '~lQ /kg !""~C· t Det BROMOFORM 1.1.g/kg Not Det BROMOMETHANE I.I q I 1-,, ~ Nc,t Det CARBON TETRACHLORIDE ,.,g/kg Not Det CHLOROBEhiZENE 1.1g/~g Net Det CHLOROETHANE •.19 I kg Nwt Det 2-CHLOROETHVLVINYL ETHER 1.1g / 1-:g Nc-t Det CHLDROF □f;:M ,.,g/kg Not Det CHLOROrt,ETHANE '-'t,/kg Not Det DIBROMOCHLOROMETHANE ,_,.g I kg Not Det 1,2-DJCHLOROBENZENE ua/ka Net Det 1,3-DlCHLOROBENZENE ug/kg Not Det 449 SPRINGBROOK ROAD• CHARLOTTE, NC 28217 · DETECT l Dr) 1 t:1 10 1 I;_'; 1 l,:1 1 C:1 10 l ~1 10 1 Ql 1 e, 10 10 I I I I I I I I I I I I I I I ANALYTICAL TESTING & CONSUL TING SERVICES Ram P.O. BOX 31486 •CHARLOTTE.NC 28231 • TELEPHONE f704) 527.-4183 • FAX: £704) 525-0409 LEa.tr1e!~ Care- Page: 3_ October 31, lS':ll HALOGENATED VOLATILE ORGANICS (continued!: 1,4-D!CHLDROBENZENE D!CHLORODIFLUDRDMETHANE 1, 1-DICHLOROETHANE 1,2-D!CHL□ROETHANE I, 1-DICHLOROETHENE TRANS-1,2-DICHLDROETHENE 1,2-DICHLORODROPANE CIS-1,3-DICHLORDPRODENE TRANS-1,3-DICHLDR □PROPENE METHYLENE CHLORIDE 11 I, 2, 2-TETRA:::HLOF:OETHAl!E TETRACHLOROETHENE 1, 1, 1-TR!CHLOROETHAt-JE 1,1,2-TRICHLOROETHANE "tF I CHLORL'ETHEt·~E TRlCHLOR□~LUORDMETHANE l)INYL CH:....O~:I[,E I Vi:: t,.,1TE-E BTEX r•ilh!~:-:.Al...S ·:::i..:•1F:ITS 1.1t; /kg e<g/kg 1.tq/kg ug/kg ,.,g/l<g •.tg /kg IJg/kg ug/kg ug/kg ug/kg ug/kg ug/kg 1.1.~/kg ug/k~ u.g/kg '}.; / ~·-Q ;_:g / :-: g ug/kg '-'~ /kg ug/k9 r,ct [,Et N.~t Det t-.Jot Det Not Det N•Jt Det Not Det Net Det Not Det Net Det l\!.::t Det ~J.Jt Det Nc•t Det t-J,:,t Det Not Det Not L•e t f\!~ t I.1e t !\-: t: [~c: 01:,t 8et ~,J,: t [1 Et t.J-::,t L•et ,, ~. M~lticomoo~ent ~~2ly~is: ARO~ATlC VOLATILE ORGANICS PE!-,ZEt·IE CHLOROBENZENE 1.2--GICt~LO~~SE~~ZE!·~~ l~~-DlC~~O~OBENZENE 1.4-DICHLORCBENZENE F:'T :-!YL BEt ~ Z E~JE Tu:_uEt<E :,: YLE_t\tE ME7"HYL TEFT BUT.iL ETHER I SO,'RCJC'YL ETHER Custo ■er Code: RAM Pnonp Number: LAB I. D. AA08534 Bo l,: ;r., ,,,.1~te·,· Collection Dat•: 10/21/Sl Submittal Date: 10/22/Sl Customer Sa~~le-I.D#: Bl~-41 TE'::T C<ARRMETER I_I. q I~-~ •J.g/~.g 1_:.!;; kg '-'~ I kg ug/kg l.tg/kg ,_,_g /kg 1_1.q/kg 1.tg / !-< Q ,.,g/~g r,L:•t Det N,-,r Vet ~,t.:,t Det Nc,t Det Not D= t Not Let ~-lot [iet Not Det Nc,t Uet < 704) ~-it =--S.72,7 ~57lHJ-7 B0ld C1 .. stcmer Collection Time: 14:45 S1.1b~itt&l Time: 11:56 Ut<ITS TEST RESULT I M~lticomoonent analysis: H~LOGENAlED VO~A~IL~ ORGANICS I 449 SPRINGBROOK ROAD • CHARLOTTE, NC 28217 DETECTION LI~, 17 I I I I I I I I I I I I I I I I I I Bold Research Labs Incorporated ANALYTICAL TESTING & CONSUL TING SERVICES P.O. BOX 31486 •CHARLOTTE.NC 28231 • TELEPHONE (704) 527-4183 • FAX: {704) 525-0409 R.a.m Leather Care Page: 4 October 31, 1991 HALOGENATED VOLATILE ORGANICS BROMODICHLOROMETHANE BROMOFORM BROMOMETHANE CARBON TETRACHLORIDE CHLOROEEl>JZEr,E CHLOROETHA~JE 2-CHLpROETHYLVINYL ETHER CH:__[1ROFORM CHLOROMETHAl<E D!BROMOCHLOROMETHANE 1,2-DICHLOROBENZENE !,3-D!CHLOROBENZENE 1~4-DICHLOROBENZE\~E DICHLORODIFLUOFOMETAANE 1. :-DICHi....OROCTHANE 1.2-Dl[H:__QROETHANE 1. 1-D ! CHLIJROE,HEIJE T~ANS-1,2-DICHLOROETHENE 1~2-DICHLOROP~~O~'ANE CJS-1,3-DICHLOROPRDPENE T RAt:5-1, 2-D l [HLOROPRO"'ENE 1 ~ 1. 2! 2-TETR~-=tC7LC,RDETHH/·!E TETRACHLOROETHENE J.~ 1~ 1-Tf;.!C.HL_OROETHANE 1.1,2-,RJCHLOROETHANE T FI Cr.L 1.::JRO~T~E~~E TRICHLOROFLUOROMETHA~E VINYL CHLOS. I [,E l ~•::::. 11TEE BTEX r,:Jt:EFALS f.::,1 F:;TS (continued): ,_,_q/kg •.tg/kg '-'-Q/kg ug/ kg ug/f.'.g •.tg/kg 1_1_9 ,' \.( g ug/kg IJQ /kg ug/kg 1.1.g/kq ,.,r:i I k r:i 1.1g /1-: g ug/kg :-1.~ / k ~ •.19/i-'g :.19/kg 1.,.;:ifkg I.lg/kg i.•.g I ~-9 1.q:;i/kg u.g/1-'.q ·) g / 1-: g i_:_~ /kg ug/kg '-'g/kg ug / ~'. g ug/kg '.(c;/kq l}.g I 1--< g r ... 9 /kg ug/kg r,,g/k(; Multicomponent analysi~: BENZErJE CHLOROBENZENE 1,2-DICHLOROBENZENE 1,3-DICHLOROBENZENE 1, 4_-D I CHLOF:OPEra EN!:: AROMATIC VOLATILE :.1.g/kg ETHYLBEra E:,E TOLUEl'...:E XYLENE METHYL TERT BUTYL ETHER I SOPR□::'YL ETHER '-'r:J /kg :Jg/ k !; '-'-9/kg u.q/1-'.g '.tg/kg uo/e:g IJ g /kg u.g/kg 1_1,g / ~ g Nc-t Det Not Det Not !)et Not Det Nc•t Det Not De t Nc,t Det Not Det l✓ct Det riot Det Nc·t Det Nc•t Det Not Det N.:.t [,Et Nc:,t S1Et N~t Det t,c-t DE t r,:0t Det r,-:-t Det i"-'c-t Det r-Jc,t C-et !\ic,t D~t ~~C,t [.Et rJc,t Det Not D?t r~-ot [let h!c,t [let l,ot Det ~~~t [>12t t.,J -:, t [1 E i: Nc,t Det ', 5 DSG;:.H~lCS l·,c-t Det Nc-t Det l✓ot Det Not Det Nc-t Det :'slot Det Not Det Not Det l·JQt Det r,ot D~t 10 10 l (1 10 10 10 10 10 10 10 l 0 10 10 10 llZ1 10 10 l l,,..1 ~ tZI l Q', 1 Q1 10 1 ('I . ~ C 1 :z. 10 10 10 ---------------.--------------------------------------------------------- 449 SPRINGBROOK ROAD • CHARLOTTE, NC 28217 I I I I I I I I I I I I I I I I I I Bold Research Labs lncoroorated ANALYTICAL TESTING & CONSUL TING SERVICES P.0 BOX 31486 •CHARLOTTE.NC 28231 • TELEPHONE {704\ 527-41B3 • FAX: {704) 525-0409 Ram Leather Care · Page: 5 October 31, 1991. Custo ■er Code: RAM LAB I.D. AA08535 ~•ho:,e Br,ld I[; 10/21/':Jl· Collection Date: N1_1r.1 ber: ( 704) 545-~737 ~um~et· G571H1-7 Bold Customet- Collection Time: 14:45 S1Jbrnitt&l Time: 11:5€:, Submittal Dste: 10/22/91 Customer Samele I.D•: Bl&-10' ------------------------------------------------------------------------ TEST ~•ARRMETER ur·nTs ~~lticarn □one~t analysis: BRO~ODICHLOROMETHANE 8RO!r'\OFGF'~1 BRote.OMETHANE HALOSENAT~D VOLATILE IJ g /kg C~RBON T~TRACHLORIDE Ct--iLOROBE~-~ ZEr~E CHLO f.'CJE. ·1 HA1,c. 2-CHLORCEl-HYLVIF✓YL ETHER CH:_:] ROMETHr=-1r-lE DIBRO~OCHLOROME1~lA~JE i,2-DJCHLORDBENZENE 1,3-LJCHLOROBENZENE 1. 4·-C, I C!-:L.D~:C,P,CiJZE~.JE D!LHLORU~lFL..UOROMETHANE l, , -DI CHLOROETHAf'1E 1,2-DlCHLOROE~HqNE 1 ~ 1-D l C.f--::_p:-:DC:T~Er·..:E TRA!~S-1,2-D!CHLOROETHEt~E 1~2-DICHL.ORO~•ROPANE CIS-1,3-DICHLORO~•ROPENE TRANS-1,3-DiCi~LORO~•R0~1 EF✓E METHYLENE CHLORIDE 1, 1, 2, 2-TETRACHLOROETHANE TETRACHLOROETHENE 1, 1, 1-TRJCHLORDET~r,:'-1E 1, 1, 2-TRICnLOrlOEH~Hl;E TR I CHLORDElHEi':E TRICHLOROFLUOROMETHANE VINYL CHLOF: 1 DE IPE MTE'-E !:-TEX r..-; ItS:ERh·;__ '::. SP IF I TS •.lg/kg ui;:;/kg '-'-ei/~:g •.'.□I~--g 1.1.~ / k q '.\t;' IP. g '-'.;.i~g I.'.~/ kg ,_! g / ;..: ;: . ug/Kg ,_,g/Kg ug/;...:~ ug/kg •J~ / k ~ '.\g/!-<:; I_' g / ~; g ug/kg ,.1 ~ I 1-<· ~ :_:,g/1-· g_ ug/kQ 1_1.g/kg I_I. c;= / k R '-'9 I kg +_:g/!"°'.~ u~/kg 1_;~/ 1-:i; 1.tg/kg 1.19 / 1-.· !:; l}.~/~g IJq / ~'. g '-'S: I kg i,,g.11-:g IE'3T RESIJLT ORGANICS Not Det Not [,et r,ot Det i·✓ :it D~ t Nc,t [J=t Not Det r'-lc-t De-t N :·t D:t t·~c t [,e. t =-~c,t I et N,ot Det !·,c-t I1e"': r; ,:-t Det rJo t De t Not Det NJt Det I-~ c-t Det N::1t Det !'~c,t [·~ t ~Jc, t Det Nc-t Get !\,:,t Det h!c•t Det Not Det :~ -:-t D~t r~ ot Det Nc-t [;Et Not Det N-ot Det Not Det Nc,t Det Not Det < C ..., M~lticam~onent a~alysis: ~ROMATlC VOLATILE ORGANICS P.!~t-J:ZENE CH:....OROBEt...;ZEt·-.!E uq/1--:g :_1g/k~ r,0t Det Not r,~t 449 SPRINGBROOK ROAD• CHARLOTTE, NC 28217 DETECT IC'., :... IM IT 10 1 ('1 1 ~-, .10 10 10 10 10 10 ) QI 1 l) 10 10 • I I I I I I I I I I I I I I I I I I I ANALYTICAL TESTING & CONSUL TING SERVICES P.O. BOX 31486 •CHARLOTTE.NC 28231 • TELEPHONE (704) 527-4183 • FAX: (704} 525--0409 Ram Leather· C~l·e Page: 6 October 31, 1991 AROMATIC VOLATILE ORGAr, l CS (cont ini.ted): 1,2-DICHLOROBENZENE ug/kg r,ot Det 1,3-DICHLOROBENZENE ug/kg Not Det l,4-DICHLOROBENZENE •.<g/kg Not Det ETHYLP.El'\ZENE ug/kg Not Det TOLUEr'>IE ug/kg Nc.t Det xv:_ENE. ug/kg Not Det METHYL TERT E-UT'fL ETHER ug/kg t,ot [;Et I 5De•ROPYL ETHER ug/k~ Not Det 10 10 i0 10 1 () 10 · 10 10 ------------------------------------------------------------------------ Phone Customer Code: RAM LAB I.D. AA08536 8Gld ID ll'/2l/c; l N•.•.mber: (704) 545-9737 N11~bet· G571Hl-7 B0ld C11stomer· Collection. Time: 1&:05 S:.i.br..ittc: ·~·l;:;c: 11 ;50-!::-t_1_tr::ittc.l Dc-.te: 10/22/Sl Custome'r· 58.rn~,lE I.D#: P.17-4' ~EST PAPAr'f:ET!:.R Ut~JTS TE'.=, P.::su:..._ T Multicomponent 2n2lvsis: HqL□GEr(~TED VOLATILE ORGANICS B~Q~;GDlC~~~ORO~El·~~t-:E E.ROtr~C)F D~;:r,: b ;c;·o~10t"iET~~At·..,:1~ CAR8 □:J TElRACHi...ORIDE CHLOROP-EMZEt,::: C'iLOROETHAr,E 2-CHLOROETHYLV!NYL El-HER CHLD'1Of'CJRM CHLO~rn(,SETHAr·!E DlBRUMGCHLORO~[T~Ar~~ 1, c·-DI CHL.C• F.OEEr·J Z El<:C: 1, 2.-D: CHLOROi;,E~.:?=."~~:_: 1,4-DJCHLOROPENZE~E DICHLORODIFLUOROMETHANt 1,1-DICHLOROETHA'~E l,2-DICHLOROETHANE 1, 1-DJCHLDROETHENE TRANS-1,2-DICHLOROETHENE 1,2-DICHL.ORO~•ROPAt✓E CIS-1,3-DICHLOROPROPENE TRANS-1,3-DICHLOROPROPENE METHYLE~E CHLORIDE 1, 11 2,2-1.ETRACHLOROETHANE TETRACHLOROETHENE l, 1, 1-TRJCHLOFOETHAr!E 1_;~: kg N.::•t Det 'Jg/~'. g r-'.at Det 1_1 g / j-: g r,:.t L'et :.19 /kg ~J ,Jt Det ug /1-:g N0t Det. •.tg/kg Not [>et 1.1,g / 1-: g Nc·t Det IJg / k ~ Not Det ug/kg r"•:• t Det u~/~; Not De-~ IJQ /kg r'-l-:-t [,et 1_1.g /kg r,c.t Det ug/k~ t·~ c:. t Det •.tg/k.g N0t Det ug/1--:g N,:.t Det 1_1_g I kg t.:c,t Det ;J ~ I kg Not Det ,_i_g/kg r~c..t Det ug/kg N:t Det l_l g /kg r~ 0 t Det •.t9/kg Nwt Det ug/kg Not Det 1_tg / 1--: g r·J o t Det •.tg/ kg 38('1 ug/kg Not Det 449 SPRINGBROOK ROAD• CHARLOTTE, NC 28217 DETECT I O'.·J L Hll' 10 1 n , .. 10 10 ',~ "~· l "'1 10 10 -:; C'l 1 (:, ! .;,: 1 e1 j_Ql 10 1(1 113 10 1 ('l ~ !~1 l ll J 0 10 10 10 i. :21 I I I I I I I I I I I I I I I I I I ANALYTICAL TESTING & CONSUL TING SERVICES P.O. BOX 31486 •CHARLOTTE.NC 28231 • TELEPHONE (704) 527-4183 • FAX: (704) 525-0409 Ram Leather Care Page: 7 October 31, !59, HALOGENATED VOLATILE ORGANICS 1~ 1,2-TRICHLOROET~iA~~~ TRICHLOROETHENE TRICHLOROFLUOROMETHANE VINYL CHLORIDE IPE MTBE BTEX MIN!:::RR'._~ S~'IPITS ( c or,t i r, 1.1ed) ug/kg ug/kg ug/kg ,.,g/kg ,.,.g/kq ug/kg IJ g /kg mg/~,; M1.1lticornpo~e~t 2n2lysis: AF:OMi:.TIC VOUHJLE BE:·JZE~~E CHLOROBEtEENE 1,2-DICHLOROBENZENE 1.3-D!CHLOR □BENZENE 1,4-DICHLOROBENZENE EHiYLEENZENE TOLU:2.r~E XYLE~-lE ~~THYL T~~T B~TY~ E~H~R I SOPROr:•y L ETHE F.· ug/L;g ug/kg ,.,g/kg u.q/kg ug/kg 1.•.g / k ;J =.i~/k;:; i.:.c / f--.::: ug/kg '·'9 /kg r, o t Det ~~ot Det Not Det N~t Det Net [;e i: Nc,t Det N•Jt Det < ~ -~ O'°GHtH CS NGt Det l·,c t Cet r,!ot [,:::, +- N,:-t Det r..:o t DEt Nc•t l)e t N1;,t [l S-t l~ -: t DI;;": r ~ -~-t Dat r~ C, t -. LE-'·· 10 1 Q1 1 ". 1 lit ------------------------------------------------------------------------- Custo~er Code: RAM ~h0n~ LAB I.D. AA08537 Bold ID Collecti0n D2te: 10/21/Sl su=•mittc1.l Dc<.te: 10/22/gl N•is~et· G571~1-7 B0ld Customer Collection Time: 16:05 S•.1.t·!!1itt2,l Time: 11:':'•~· E:745 ------------------------------------------------------------------------ TEST C•A,',A:~E"TE:R Ut< I TE T.--C --' t:..-.-·' LCTEC-i l Ot-: ---------------------------------------------------------------~---·----- Ml1lticom~a~ent ~n2lysi£: BROMODICHLOROMETHANE BROMOFOR'~ EROMOt1ETHf'i';'.c CARBON TETRA=HLORID: CHLOROBEr-J'Z Et-..!E CHLOROETHA'!E 2-CHLOROETHYLVINYL ETHER CHLOROFORM CHLOROl<ETHA~'E DIBROMOCHLOROME1HANE 1,2-DICHLOROBENZENE 1,3-DICHLOROBENZENE l! 4-DICHL.IJRCIP.ENZEt✓E HALDG[~~lED VO~ATILE ORGAr~1cs :.19 /kg 1-1g/kg ur;/k; ,.,~/kg :_lg/kg ug/kg r_: g / h: g ug/kg 1_r,q/kg ,.,.g I kg I_\ Cj / 1-r g ,.•.g/kg l_t~/kg Nc,t Det ~~ot Det r·,,:t Det Not Det Net Det Not Det t-~c,t Det Not Det N·:, t Det Nc•t Det Net Det Not [1et i-..lct Det 449 SPRINGBROOK ROAD• CHARLOTTE, NC 28217 10 10 1 (': 10 1 0 10 I I I I I I I I I I I I I I I I I ANALYTICAL TESTING & cciisul. TING SEAVlCES P.O. BOX 31486 • CHAALOm. NC 28231 • TELEPHONE {704) 527--4183 • F~: {704) 525--0409 Ram Leatt-,e-r Care Page: 8 October 31, 19"11 HALOGENATED VOLATILE ORGANICS D!CHLORODIFLU□ROMETHANE 1,1-DICHLOROETHANE 1,2-DICHLOROETHANE 1, 1-D!CHLOROETHENE TR~NS-1~.2-DICHLOROETHE~:E 1,2-DICHLOROPROPANE CIS-1,3-DICHLOROPROPENE TRANS-1 1 3-DICHLOROPROPENE METHYLENE CHLORIDE 1, 1,2,2-TETRACHLOROETHANE TETRACHLOROETHENE 1, 1,1-TR!CHLOROETHANE 1, 1, 2-T~.IC~LO~:OE-:-H;,.~-~E TF: I CHL._01=::0ETHEr~::::: T F: CHLOF~Clr-·:...uQF\Jt:"1ETH1~h!E ':I NYL CHe-OR I DE I e·E M:!?E E'TE/ tv; ~ rs;~~ Rf'-E .. S ~:~• l PIT E: E-~:-~zEt<:.:, Ct-!l_OG.OE.Er-~z Er~E 1, :.:-DIC:rt~OS'CIE',[t~Z~NE 1~ 3-DIC!-:LOROBENZEtJE 1,4-DICHLOROBENZENE ETHYLE'ENZEriE TOLUENE i {LEt·!E MEl.HYL TEPT 2UTYL ETHER (cont ini.ted): 1.1.g / ~: g ug/kg ,.,g/kg ug/kg ug/Kg l.\g /kg ug/kg ug/kg 1.1,g/l-:g ,.,,;/kg ug/kg •.•.g/kg ,_:_ ~ / k g ,.,g/kg 1_:.~/~:g ug/kg ug /1-;g ug/kg u.g _I/.-' g ;o ~ I kg 1.!g /kg :J !; / I.; g ,.,g/kg IJQ /kg ,.,g/kg '.t g / k r;: !_1,f; / !-'. g 1_1.g /kg ,.,.g/kg 1.tg /kg t,ct Det Not Det Not Det Not Det N c-t 0!;t Nc,t Det t,c t Det Not Det Not Det tfot Det i:41 7 tiot Det N:.t DE-t f-~ Gt Det NGt Det r~ot Det Nc,t L:e t r~ -:-t [let t✓c t Det ~ C -_.!. ,_. !\!ot DE-t t·,:t Ce': Not Det t,c,t Let i~ot Det Not Det 74 Not Det t-~-:-t ['ft 10 ➔ ,.,., .l •.:.· 1 (1 i0 10 1 ('i .10 -·"': .:. :_• -----------------------------------------------------------·------------- Custo ■er Code: RAM LAB I.D. AAl'\8538 Pr-.c·:--1e t-~1.,mbEi"': (704) '.:".45-9737 B0ld ID N•~m~eY G571Hl-7 B0ld Custo~e•--Number Collection D2te: 10/21/Sl Submittil Date: 10/22/Yl Customer Sa~cle !.Dti: NEW WELL C0llecti0~ Ti~;: lS:10 S 1.l b rn it t e-.1 Ti m E : 1 1 : 5£:. ------------------------------------------------------------------------- TEST ~•ARR'1ETER TEST RESULT ---------------------------------------. -------------------------··· Multico~ponent analysis: HALOGENATED VOLATILE ORGANICS E'ROMOD!CHLOROMETHANE ug/L l 449 SPRINGBROOK ROAD• CHARLOTTE, NC 28217 I I I I I I I I I I I I I I I I I I ANALYTICAL TESTING & CONSUL TING SERVICES Ram Le~.ther Page: 9 October 3l, P.O. BOX 31486 •CHARLOTTE.NC 28231 • TELEPHONE [704) 527-4183 • FAX: [704) 525--0409 Care 1991 HALOGENATED VOLATILE ORGANICS (continued): BRO~OFOR~ ug/L BROMOMETHANE ug/L _CARBON TETRACHLORIDE ug/L CHLOROBENZE~E 2-C!~L~RQETHYLVINYL ETHER CH:_QRO'°ORM CHLORDMETHANE DIBROMOCHLOROMETHANE 1,2-DICHLDROEENZENE 1,3-DICHLDROBENZENE 1:4-DIC~{LOROB~NZE~~E CICHLORODIFLUORO~ET~i~~~t 1, 1-G I CHLDROETHANE 1,2-D!CHLOROE~~~NE 1 ~ 1-0 I CHLOP.Q~T~Et--.!E TRANS-1,2-DILHLOROETHENE 1,2-DICHLOROPROPA!~E CIS-1,3-DlCHLORO~RO~•ENE T;; A~~:: -1 • 2-DIC !-l;_o K Dr:, ::::o;:·Et ;~ 1, 1, 2, ~--,-ETRl'iCHLORDETHAt,r: TETRACH:_OROETHENE 1, 1. 1-TFI[H:_opoET~P.hlE 1, ~, 2-TFdCHL...OS:CIE.1HAr~~ TF. I CHLDROETHE~·!E ~RICHLOROFLUORO~ETHANE '..;I!-,!·/;_ C:-!LO~. l !:·':: C i.-'.'_O :=::Cl~ ""'."~•;Ai•JE .. ,, ..... .:. .-C. MTEE ETEX. MlNER"IL S~'!F:ITS Multico~pc~e~t Er~ly;iE: BENZENE cH:_□ROBCt,ZENE 1,2-DICH~OR□D:~zErJ~ 1,3-DICHLOROBENZE~E 1,4-DICH'-OPOBENZENE TD'-UE.NE i YL[r·-~E METHYL-TEPT-BUTVL ETHER I SOPRC,PYi.... ETHEF h:~1Jt0~HT IC: ug/L :_,_g / L_ •.1g/L u g /L ug/L 1.tg /L ug/L ug/L ug/L ug/L 1_,_g/L •.cg IL ·_:_ g ,' L '·'· g ''- :_:.; / L ·_1g/L ug /L. ,.,.g/L 1_1.g/L t.<.g/L ug/L l).!:;/L 'Jg/L 1.r.c; /L l_\g/L :.•.g / L l_\g/L ,_._q /L m~/L 1v'OLA1."" IL.:: l.\g /L 1_1.~/L_ ,.,g /L ug/L ug/L '.\~, ,, ~ l_lg/L •Jg/L 1;.~ IL. 1.tq/L N~-t DEt N :>t Det Net Det Not Det t'-J.:,t Det r-.J 'J t [1et N•:t [·Et Not [1et Net Det r"lc·t Det r\! ::, t Det ~ I --I-DEt I~ -' Not Det r-< ·=· t Det N:::-t Det r--.;c,t Det Nc-t Det Net [let !'JC t [e ': r·..i ::> t Det r-~ •::--:: [:-: t 2Q15 r-1-:t [1E t t,.:c-t U12t s r~ot Det r,:-:-t [,,= t ,., --I-[1:-. -I-i, ..... t·-..:o t D~t :,o t D~-t I':,:, t [:· ~ t N:•t [l :-t r,~ :, t DE t ( 2:., OP~Pr-;1c~- ~ ~ ::, t Det 1,: ,: t DEt Net Det r.' -..i.. I'-,•_.; •~ Det Not Det ti Gt DEt Not. Det Not. DEt Ncot De t r,,: t Det 1 1 I 1 l 1 1 1 ; 1 l 1 - 1 1 ; 1 1 l 1 1 ------------------------------------.--------------------------------------- 449 SPRINGBROOK ROAD • CHARLOTTE, NC 28217 I I I I I I I I I I I I I I I I I I ANALYTICAL TESTING & CONSUL TING SERVICES P.O. BOX 31486 •CHARLOTTE.NC 28231 • TELEPHONE (704) 527.-4183 • FAX: (704) 525-0409 Reo.m Lec.ther Care Page: 10 October 31, 1991 Please advise should you have questions_ concer'ning these data. Respectfully 51_1bmitted~ G1·5Cy l.-J .• E-·.•.r·gi:: Labor·atory Managet~ 449 SPRINGBROOK ROAD• CHARLOTTE, NC 28217 ·• I I I I I I I I I I I I I I I I I I MONITORING WELL LABORATORY REPORTS I I I I I I I I I I I I I I I I I I I ANALYTICAL TESTING & CONSUL TING SERVICES P.O. BOX 31486 •CHARLOTTE.NC 28231 • TELEPHONE (7041527-4183 • FAX: (704) 525--0409 Ra~ Les.the:'· Ca~~e .i=:tt:-.: E. C:iff ~o:--~c·,,• :s100 Pl~erc~.r·le Rj B~!o~ a~~e ~·es~lts cf an~.lvsis cf~ sa~cles re~eivej f~r exs~inat~=~ a;; S&c-ter:;~-~:-27. 1S51: Customer Code: RAM ;:·~.:-:.cc· t-~'-~r.'.t:.~~-: ("7,:::-,!"T) 51;2-:-7:::7 LAB I. D. AA08200 Ec:d :!:D t·l·.u::ti;;;:· C:4::AH!·-2 Eold C=.-.s: c•:::£~-:,;,_-;.:::;:·· C 7l..::" C~llecticn D~te: 09/27/91 ----------------------------·---·----------------------------------·--------- M .·.l t i·=c-□c·:-:-.e:-1-t E.-.c:-.: ,. :. ::. s: Hn:...OC:-[r·-~ATED .',..'OLP.T!L.E 2 RO!'1Q[, IC f-'.LOF □t..-;ETHG'."~~ ·-•□ .' L 9~2~0~□R~ :.:c/L B RLi'..-.C;~~E:TH~~<= CA~BQf~ TETRAC~LOR:[-~ CH'.__[:[::,JP'.:::t-.:: El<£: .:-<~~::_c,:::□=THY:.....'"'' I NYL ETH~R C !-i'....C ?"::•~□ f:::·: DIBR □MOCHLO~OMETHA11~ 1.2-DIC~LOROB~~~ZENE 1.3-DIC~~ORCGC~~ZENE 1.4-DICH:...G~□B:t~ZEN~ DICHLORGCIFLUORO~ETHAr~E 1. 1-DICHLCRD~~HArJ~ 1.2-D!CHLOROETHANE 1. 1-DICHLO?O~T~l~r~c TRA'!S-1.2-DICHLOROETHENE I. 2-D I CHL0R0PF:0e'8'.E c:s-:.2-·[!CH~ORJ~·R □PEt·!E TRA~S-1.3-D!C~L.ORO~•R □~'ENE i~ETHYLE!~E CH~ORIDE : • : • .=:. 2-TETRHC~·:~C1~0:::::;Hr-IM:. :_;_c /:... •.t:J /L " 1.:,.0 / I.- '.'.t: /L i_;_c /L.. '·'" /L .,c /L i_:o ;:... 1.,c /L !_\OIL.. l_l~/L 1.tc/L l.t □/L ORG~i!~ IC~- Not Cct ~~:: t [,et ~\!-= t Dst . ' -... D~t 1"-'-' \.. r-~ =· t ~-Et N-:,t [•~t t .. ~ ~-D'c:t ,·. -· . Not [12t ~;Ct Dt:; t Ne-": De: N,:.:-t [·ct Not [•et t\c-t DEt ~-lot Det NDt Det Not Det N:t Det ti·= t Det t.i --1,. r .-.... '' ·-. -; \.. r,: t D~+ I\=· t D~t Not DEt TETRACl·~~O~OZTl~~!~Z G □/L 1 : • : • 1-T F: I Cf-lL0R0ET'-114:is:SPRINGBROOK RGA'~ • CHARLOTTE, NG'<!S:h,t : ~~-==:· :o:-~ ~I:---;!; ! 1 1 1 1 1 I I I I I I I I I I I I I I I I I ANALYTICAL TESTING & CONSUL TING SERVICES P.O. BOX 31486 •CHARLOTTE.NC 28231 • Ta..EPHONE (704) 527-41B3 • FAX: (7041525-0409 Ram Le~ther Care Pace: 2 October 30. 19',!· HALOGENATED VO~ATILE OPGAr~ICS <ccntinu&d) 1. 1. 2-TR I CH'._QROET~A~·'.E 1.~c /~ TR I CHLDROETHEfsS TRICHLOROFLUOROMETHANS VINYL CHLOF:IDE C!-:~□F0ETHHt·~E C!E-1.2-r!CH~ORO~THE~~ ETHYLENE BROr'I DE IPE MiE'E BT.EX i',INERAL Se'IRITS 1.l □ /L 1.1.0/L 1.to /L '.1.C /L t.tc/L uc/L 1.',0 /~ ".., /1 •.,..., I - 1.10 /L mQ /L Customer Cade: RAM ~'~c~e ~!~cber: (704) ~~=-~727 "'.ct Dct l'~ot C•et ~-ict Det Nc•t Det ~Jct Det N~t Det l'~ot D'=t t·Jct [et r·Jc t [·E:: Not De-: < • 25 l l 1 1 1 1 i LAB I.D. AA0B201 Bold ID ~~:_;:.1.~2~-G~::4!-'.1-2. E•,cl::::! C•J!::tc·r.1e:-· t~:.:mbe·.-t:?Li:= Cclle=tion D~te: 09/27/S: S·.•-~l:!i-:-!:2.! De.-!:e: 09/~7/':l: [1_.s-+:: r.,e·:· ~2.:-::~l e I.[·#: Mt•J~.:_,=, ERO~Q[:CHL.~ROMETHA~lE E ~:O'."".C::=-□P.:~. [, I E-R□:...-;o·:H:.....OROr,.-;E:T:-!r::·-!E 1.2-DICH~OF □E~~ZENE ~. 3-DI ci-::.....0P:1EE~~ZE~<E 1.4-DICHL0R0BENZEr~~ DICHLORODI~LUOROMETHAf!E 1,1-DICHLOROETHRNE 1.2-DIC~~LOROET~~~~~E 1! 1-D!CHL0R0ETH~r~E TRA.'"·JS-1. 2.-DIC:HL0R0ETHEiJE 1.2-D·!CHLDR □~•ROC•A~JE C!S-:.3-DICHLOR □~ROPENE TRANS--1.3-D!CHLORO~•RO~•ENE METHYLENE CHLORIDE 1.!.2.~-TETRACHLORDETHANE :.c/L 1_:_Q /L '.'.C /~ uc/L 1.:~ /L '.l:::::. IL. 1 •• :::::./L I.'. C::: / :._ uc/L l_l,C /L 1.,c/L :.1.c /L 1.1.c/L •;.o/L 1.1.:::i /L T[:=T hESUL.T D!=:E-;~:~ I CS 10:: t [;e:: t ~' --1-!:·2t : ,._ ~--!-= t [: ~ t ~-:e: t Det f.;.: t De.t ~-!-:, t [-st Net [·et • I --1-I'-;·-• w [,,:; t !·~-= t DEt ri :-t Dc·t ~-!,.... -1-• ~ ,.__ "w D-s: t r-~vt De:t t"\ c-t Det Nc,t Det N.:it Det t~ot Det Net Det Nc,t Det Net Det r~c,t Det Nc-t Det Not Llet 449 SPRINGBROOK ROAD• CHARLOTTE, NC 28217 :..... I>: IT 1 1 1 1 1 1 1 1 1 I I I I I I I I I I I I I I I I I I ANALYTICAL TESTING & CONSUL TING SERVICES P.O. BOX 31486 •CHARLOTTE.NC 28231 • TELEPHONE (704) 527~183 • FAX: (704) 525-0409 Ra~ Leat~er· Car·e P~□e: 3 October· 3121. 1':<'31 HALOGENATED VOLATILE ORGANICS Cccntin~edl TETRACHLCROETHENE u □/L 1. 1.1-TR!CHLOROETHA~E u □/L 1. 1. 2-""'.""F.ICHLORO:::ThAt·lE TR 1 C:-'.:....OFOETl-!ENE TR I CH!_OROF!....UOFO~ETHr:.~·~E V~r.JYL.. CH'._OS'.IDE CH~QROET~h\'.E CIS-:.2-D!CHLOROETHENE ETHYLEl'~E BR8l1 I DE IP~ '.~'.:E:::: ET~i C°::•1 \~·TYC': ..... ~. ' ... ' - , ' UU, i... uc/L •.:a/L 1.1.0/L I.le/:_ ·.u:/L l.'.□/L r.!C/L t·:i: t Det Not De-t r ~ ·=· "= Det I'-~ u-+: Det Nc•t Det Net Det t·J Ct Det '.fr.t Det Net Det t·J-:-t Dot !\,: .-.l. GE t N :,t Det < -:-,c:-~- 1 1 1 ------------------------------------------------------------------------ Customer Code: RAM r:-~.:::-.~ ~<-_.:::"::;:· ~ ,;;,:::. i_::t.iS-~<7 :;7 LAB I.D. AA08202 So~d IG t~~~je.· ~~S4H1-·2 Ecld C1:stc~Et· ~~~~er S74~ Cc!!E=~i:~ c~te: C9,'~7/~1 s~~~~t~€.l Dat~; 0?/~7/~1 C·.-.=.t-:-:::;;·:· Ec-.r..~lE I,[;~::<~-!'..::.:._~ . ::;-, -:-::---· . -· ._, ------------------------------------------------------------------------- TE~T u)",• T "1"'='.. T,, .. .,. . C:.-::l: REsu;_ T L'C"TC=T: O\'. ~I~\ IT ---------------------------------------------------------------------------- ERO~ODIC~LOPO~CTHAN~ EF:O~~J:="OS'.~1 B r:::□t-1c:~: T!-~P.:·:E CA~E □r~ TETRAC~ILO~!~E c~:..OROBEr·-~Z i:::::,;c 2-C~LOROETHYLVINYL ETHER C'-:LOS:OFCr::r~ CHLOROMETHA~-~=- DI ERO~OCHLORO~ETHA~!E 1.2-DICHLOR~B~NZENE 1.4-DICHLO~□DENZENE DICHLORODI~~UCRO~~THA!~E 1.1-DICHLOROET~A~=. :. 1-D:CHLOROETH:::.tJE TRAr;~-:.2-D!CH:-.□ROETHEI~~ 1.2-D![H:__□RO~·RO~•AN~ c::;:~--:. 2-·[;!CHLOF.Clf:•ROPE!·.:~ TRR~~S-1.3-DICHLOR □~·R □~=zr~~ 1_;:::: / '..... ,_:_ C. / '..... r.•.c ,' L. uo/L UC,'!_ I_\J:i/L :.i:: /L :_;_a /L i.:.:/L i.tC /L._ '.::: /:.... ORGA\'.ICS Net De-t ~-~ c, t I·et t-~:: [:Et : ~ :.t Det : ~,: t Det t~c-t ~et Net C,ct ~-1 :-t DEt ~~ ::: D2t r-~ ~ t Det :·~: t Det ~~ot Det Ni:• t Det Not Det N-:-t Det r,i C·t D~t !,>:•t D2t ,_ I -+ ... -·. [,~t t, ! •·, +-. "·--I:ie t Not I1 et 449 SPRINGBROOK ROAD• CHARLOTTE, NC 28217 1 . 1 1 1 1 1 1 1 1 1 1 1 I I I I I I I I I I I I I I I I I I I ANALYTICAL TESTING & CONSUL TING SERVICES P.O. BOX 31486 •CHARLOTTE.NC 28231 • TELEPHON~ {704) 527-4183 • FAX: (704) 525--0409 Co~·e PC\oe: 4 October 30. i ~91 HALOGENATED VOLP.TILE ORGANICS METHYLEN~ CH~OR!DE 1. 1.2.2-TETRACHLOROETHA~~ TETRACHLOR□ETHENE 1. 1. 1-TRIC~LCRO~TH~~~z 1.,. 2-TRICHLC•F;OETHi=c',:E TRICHLOROCTHENE TRlCHLDPOFLUOROMEl-HA~:E V Jr,YL Cf-'LORI D:c C)-'.'.....CRCET!--!A:·lE C!S-1.2-DICHL □ROET~iENE ETf-'YLENE ERO:·: I C-E T r,C:--,-.... MTEE ETEX '.·· H-.'.E!~t-~i._ -=:;.:,IS: I:·~ (cor,t in 1.1.ed) 1_;_c /\... l.l □/L uo/L uo/L •.i.e./~ l.l □/L '.l □/L ;_,.c /L t.l □/L I_\O /L vc/L I_\C /L •.<8/L ~c/~ t ~:: t Det Mc,t Det Net Det Not Det Net r:·e t ~~at r, r::. +-__ , J\'ct Det NGt Det ~-l ~ t Let N~t Det N:t Det ~-~u-t Dst Not De-!: N:t Det ( t 2:: 449 SPRINGBROOK ROAD• CHARLOTTE, NC 28217 .::::'. ,:, : 2 .• 1 1 1 1 l 1 1 1 l I I I I I I I I I I I I I I I I I I :1 -NEW DRINKING WELL _ BORING and WATER LABORATORY REPORTS I I I I I I I I I I I I I I I I I Bold Research Labs lncoroorated ANALYTICAL TESTING & CONSUL TING SERVICES P.O. BOX 31486 •CHARLOTTE.NC 28231 • TELEPHONE (704) 527-4183 • FAX: (704} 525-0409 ~a~ Leat~et· ca~·e ~:tt:-.: E. Cliff ~-1C•.~l~v 15100 A!be~·~a~le Rd Ct-.2.!·lctt,:::. ~~.C.. 2f::-227 Customer Code: ·RAM ;:-,~:c:-.E f-..'.!.•.:::::-;:·r·: (7C.·!:) =A-S-S•:'27 LAB I.D. AA'218342 B-::c ID i'<•.tr.,;:. .. :;, C:':::::>H:-S S:-:.j CJ.:.tc □e"r"· >·.tr.:::-~ Collectia~ Date: !e/03/Sl ~-:.t:sittal D..:.te: 10/0·~/S: c~s~o~?~ ~a~~le I.Ct: R~-DW-10 ------------------------------------------------------------------------- ----------------------------------------·---------------------------------- EFO~ODICHLOROMETHANE P.R0,1 □r:-□RM E P.D:~~□t":[THA!'~E CARBON TETR~CHLORIDE C!--!:....O~-~EE'.•~:: Et--'.E er--:~ 'J :=-,o::-r-1--::=::N~ 2-C:. !·JL[I F:C•E:"i-f'{L t,,' I ;-;~'L ET!··'.[~ C~.L..D"OFO"CI CHL..OROMETHr::;t;c DIBROMOCHL..OROMETHANE 1.2-DICHL..OROBENZENE 1. 3-D I CHL...OF:O~-CNZ E~~C 1.4-DICHLOROEE~JZENC DICHLOROI1IFLUQRO~ETH~N~ 1. 1-D I CHL..OROE:HH!'iE f. 2-Dl CH!....OROET.HH:<E 1. 1-DICHLOROETHENE TRANS-1.2-D!CH~OROETH~r~E l. 2-DICHL..OROPROP1-il,E CIS-1.3-DICHLORO~·ROPENE T F::-!~-!':;.-: • 2-D ! C~-'.L~F:0'.=' RQr-•E~ !E METHYLE~E C~~ORID~ 'JD/ k :::! 1.1.c/kc 1_1.0 / 1-:□ --.' ! • -.• • ...; I r. I.. :_i_C; ,' ~ ::J '-'· [2 / )-.: ::::; ,_,_,:; I kc '-'□ I k □ ,_;_o/kc .:□/~::J 1-to/ko -•-□/ko •.i.c / k o 1.~c/ko '-'□ I k □ •.t □/ko i;.= /1-: Q ·.!□ I l-: ::i ~-1. 2.. 2--TC:'f7:H[!-::_Q~:OETHANE uo/1-:□ OPSi::;·,!ICS .. , -+ • 'i '-' • Det N:,t [,et r,d [•Et r-~ c-t DEt Nc-t DEt ~J-:-t DE t t,J,:, t D~t t·-!ot [,et ~ ~ C: t Det ~-.!0t [et t'-lu t Det ~.::, t Det r.,_; Ct Det ~ ~ --t Det ~~-J t Det t·~ct Det Not Det Net Det N0t Det N-:it Det 1-.::-t C·e t ~~ :::,t ['d r-:.:-t [,2: -:-E:RPCC:L..Oc'.OET~-:E'.'1E 449 SPRINGBROOK RGAl3'" CHARLOTTE, NG~s;h:t- 10 , , ... , .:. ·.,_ 10 10 I I I I I I I I I I I I I I I I I I ANAL YllCAL TESTING & CONSUL TING SERVICES P.O. BOX 31486 •CHARLOTTE.NC 28231 • TELEPHONE (704) 527-4183 • FAX: (704) 525--0409 Ram Leather Care Pace: 2 October 30. 159l HALOGENATED VOLATILE OREAN!CS 1.1.l-TRICHLOROETHANE l. 1.2-TRICHLOROETHA~E TRICHLOROETHErlE TRICHL□R □~LUORO~ETHANE VINYL CHLO"lDE IPE MTBE BTEX Mlt·~EFPL~ SPIRITS <co::t in 1.1edJ: •.10 I k o u □/ko 1.~0/k □ !_I_C /1-: □ l_t(i/)•;Q u □/ko t.~□ I k o u.o /ko mo/k □ t,!ct Det Not Det Net Det r·~ :,t Det Nc,t Det Nc,t Det Nc.t Det Not [JE•"t ( ~ J 1 (~I 1 Qt 10 10 10 ------------------------------------------------------------------------ Si.~=lej bv Calli~~ Well ~r~illi~~ [·:·i:-,1-:i:-,c:: wc.ter t.-.1 2ll. Customer Code: RAM LA-:.·: I. D. AA08343 !3-::,ld ID 10/08/'Jl Collectic-:1 Da,te: t··.J ·_, r.:: ;::-·i-: N 1_1.rr:t,21· s~tb~itt~l c~te: 1010~1~1 C1J;ts~er· Sa~ole I.D#: RL-DW-20 ---------------------------------------------------------------------------- ,---.... 'c::.: PH~:t=-~'.~E:"EF TES:' PE'=U'._T --------------------------------------------------------------------·----- BROXODICHLOROMETHANE BRO'10'-ORi". E RQ~Oi ... ETf-·'.A!'lE CARBO~~ TETRAC~~~ORIDE CH!.__O:=::□ETHH:·•·!!.=:: 2-CH~DROETHYLV!NYL ET~~~ CHLOROFOR.M CHLOR □t<ETH(-!l·JE DIBROMOCHLOROMETHANE 1.2-DICHLOROBENZENE 1.3-DICHLOROBENZENE 1.4-D!CHLOROEENZENE ~ICHLORODIFLUOROMETHANE 1. 1-D I CHLOROET~Hr-~'.::: 1.2-DICHLOROETHANE 1. 1-DICHLOROETHENE TRANS-1.2-DICHLOROETHENC 1.2-DICHLORO~R □PANE C!S--!. 2-DIC!-lLOROr:•F;O~•Et~E 1_;0/h:o 1_'.C / ~:u !_l~ /1-::J uo/kc 1_•.c / \-: D ,_,_:J / k ::i 1.10/l.-:r:. u.o/Kc l.'.C· / I< O ,.·.~/ka uc/k □ ,_,.c/ko i.•.G/1--:o 1_•,:.J / 1-: 0 1-l□/ko ·-•-□ I k ::i I.~□ I I.-:□ u □/k □ ORGA~-ncs t~ ~ t Det ~-~ ot Det t-.J,:. t [·et Nc:-t Det ~~ C· t C = t Nc•t C•et N :-t Dr: t Not Det Not Det Nc,t Det ~~Gt Det t~ :, t Det N:,t Det Nd Det Ne:· t Det Net Det Net Dat NQt Det Net Det Net Det 449 SPRINGBROOK ROAD• CHARLOTTE, NC 28217 lC 10 · 1 C' 1 Q1 :. ('': ::. (:, I I I I I I I I I I I I I I I I I I ANALYTICAL TESTING & CONSUL TING SERVICES P.O. BOX 31486 .'CHARLOTTE.NC 28231 • TELEPHONE (704) 527-4183 • FAX: (704) 525-0409 R.2.r.t Lee.the·:· Cc-.'!'·E ~·aoe: ::, October 30. 1991 HALOGENATED VOLATILE ORGANICS TRANS-1.3-DICHLOROPROPENE METHYLENE CHLORIDE 1. 1. 2. 2-TETRACf;LOROETHA!,E TETRACHLOROETHENE 1. 1. 1-TRICHL_OROCTl{P'.cE 1. 1.2-TRICHLOROETHANE TS I CHL.DR02:THEt,;E TR!CH~ORO~LUORO~ETHANE VI hiYL CY:.....O~: ID!::: IPE t~.,.8C E"'."EX Mil'~EF:A'......S Sl='·I~:IT~ (cG:-1t inued): uc/k □ ,.,o/k □ 1.l □/ko l.l □/k □ ,:.elk □ •.to/k □ '.tc/kc 1.~0/k □ IJQ/ 1-: 0 u □/k □ t.tc./kc !.l □/k □ mc:/k □ (:Ct Det Not Det Not Oet Not Det Net Di:: t·l-:·t De,t (1~-:-t [;et Not Oct t·' -,I,. . ",_ ~ [Et Not Det t·~c t Det )'~:it D ~ t ( e . ~ ------------------------------------------------------------------------- £~~s:ed bv Colli~s W2ll C•~·illinc D:·i.--,i•:i:-:c. Wc.ter· Well. Customer Cade: RAM LAB I. D. AA08344 ~-t-,ci:e Bole:! IC. C:.llectia:1 D~ ... te: 10/Q"i£:./'::1 E1Jt~ittal Date: 1C/0S/Sl Custo~e?-Sa~ole I.D#: RL-DW-30 S:.-.bmittal Ti □e: 1'=-: 10 ----------------------------------------------------------------------------- TE~T ·1=,~:S:~4:'':~T~ R ------------------------------------------------------·------------------ M: .. ltico~~~nent analvsis: HALOGENATED VOLATILE E.r:;Dt~DD ! C!~LQ?•:•~·:ET!-'.:"-l!'<E E ROMOFOF::v1. E, r::□:"'.:J~CTHJ-.~·;E CARBOtJ TETRACi~~ORID~ CHLOROE-Et·~ZE~·~E _C~LO ROE:" i-'.t-:'.·~E: ·2-CHLOROETHYLVINYL ETl~EP CHLOROFOR"'. CHLOROMETHA'.·!E DIBROMOCHLOROMETHANE 1.2-D!CHLORCBE~ZENE 1.2-DICHLORODENZENE 1.~-D:CHLOROPENZENE DICH~ORODI~L~ORD~ETHANE 1. 1-[!CHLOROETHAtlE 1.2-GICHLOROETHANE ,.,□/k □ uc/h □ :_\ :J / ~: !J 1_1.0/kc: 1_;0 / i-: 0 '.'.□ /~'. Q ;_,, D / 1-: C ,.,.□ I k □ :;.c /1-: □ 1.,0/~'.8 l.'.C / 1--: C u □/1-.o 1.~c/ko L.'.:::i ( ko ORG;::.n C 3 t'\ =· t Dct ~~ :-t [:et t'-) .: t Dct N:-t Det t·~:-t :--,, -.lo .., t: \. 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BOX 31486 •CHARLOTTE.NC 28231 • TELEPHONE {704) 527~183 • FAX: f704) 525--0409 Ram Leat~Et· Care P·a □e: 4 October 20. 19g 1 · HALOGENATED VOLATILE ORGANICS (=ontinued) 1. 1-DICHLOROETHENE TRANS-1.2-DICHLDROETHENE 1.2-DICHLORDPRDPANE CIS-1.3-DICHLORO~•RDPENE TRANS-1.3-DICHLCROPROPENE METHYLENE CHLORIDE 1. 1.2.2-TETPACHLOROETHANE TETRACHLOROETHENE : . 1. 1-TRICHLORO~THA~-~C 1. 1.2-TR!C~l~CROETHANE TR I CHLOROETHE!•iE TRICH~OROFLUOROM~THA~E VINYL CHLORIC-E IPE MTBE !?.TEX uc/ke: u □/k::J 1.to / k □ •.,□ I k ::i uo/ko 1.~0/ka ,:.o/k □ ·.,o I k::, ,.,□/k □ u □/1-:□ •.to/\.-:~ ,_,o/ko •.·.□/he :.~C: / l-< 0 ,:.elk~ rr:c./l-:c Nat Det N:it D '= t ~~ C, t Det t,~ Gt Det r< :-t [l '= t Not Det ~J 8 t r:-ct ~~ct Uet t~ Ct [ct r(c-t Let Not Det No-: r:-et r>Jc· t Dct r-Jwt Det ~';Ct [Ct !'J-:-t Det 12. s 10 10 :0 1C: 10 10 -------------------·----------------------------------------------------- Customer Code: RAM LAB I. D. AA08345 Ei-c ~ d I[· 10/0e.;r::_:i 1 ~i~b~ittal o~te: 10;og;s: i::::· .=.t:r.:ittc.l Tir:iE: lt:: 10 C·Jstomer Sa~□le I.D#: RL-D~~-40 -~E<.::-T PA~:i=w=TE::: I J,.•"T TC: ..... : ,.I.'-· Multicomconent a~alvsis.: HALOGE~JATED VOL~TILE BRDMODICHLOROMETHA~E BROMDFOR?"'. P RO~O~ETl·'.Ar·~C CARBON TETRAC~~LO~!D~ CHLOROPStsZD'.E CHLOROETHA'.,E 2-CHLOPOETHYLVINYL ETHER CHLORor□RM CHLOFOMETHANE DIBRDMOCHLOROMETHANE 1.2-c:c:~LCR □P:N:ENE !. • 3-D! C:HLO~:'JE:•:.::~-iZE~~::: ,.le/kc u □/~-:s 1.:0 / 1-:e; :J □/ko '}.c. / k □ 1_;_c;/ko IJO / k !:] ,_,_o/~c 1.1_::. / k □ 1.tC / ~: ::::! I.'.:!/ k:: ORC:~1t·~~ c:;. r: ct [et l'J: t Det t"~ ·=· t [•et ~~ :, t Det ~~ C: t Det Nc,t Det ~~ C· t Det N0t Det ~-: = t Det N: t J:•et r-~,:-t L·t::·t r ~ C· -:: [l r, +--' 449 SPRINGBROOK ROAD• CHARLOTTE, NC 28217 10 10 I I I I I I I I I I I I I I ANALYTICAL TESTING & CONSUL TING SERVICES P.O. BOX 31486 •CHARLOTTE.NC 28231 • TELEPHONE (704) 527-4183 • FAX: (704) 525--0409 R~m Leathe?· Cat·e October 20. lS'il HALOGENATED VOLATILE ORGANICS Cc~ntinuedl 1.4-DICHLOROBENZEtlE uo/ko DICHLORODIFLUOROMETHANE uo/ko 1. 1-DICHLOROETHANE uo/kc 1.2-CICHLOROETHANE 1. 1-!:; ! CH:_or.~E""'."'.-IEt·'.E TRANS-1.2-D!C~~LORO~THEN~ 1. 2-[·1Ci~LORC1~·F.o;:·pr·-.:~ C!S-1.3-D!C~LORO~·R □r~NE TP.ANS-1. 2-D I CHLO RO,-·P.□i:•Et•,E METH'(LD~C: CH:..□ RI DE 1. 1.2.2-TETRl~CHLOROET~A~J~ TETR!::1Cl-l!....O ::::□ETH~~~~ .: . 1. !-7'F:! CJ-::..cr-:c::-THP.:<E -:-'.~ I Cl--::.-QF:OE":~!E~-:== TRIC~~ORO~~UDRQ~~T~A~E :; I t·~Y!.... CH:....01'.: DE I J:•!=: r'.".T!? E !?TEX uo/h:□ 1.ts/k □ ·:.□ .' ~; C ;_\::/kc uo II-<□ 1J □ / J...: 0 ,_, D / k □ 1_:c ,✓ \-: □ : .. i:./kc ·.•.CI k D ·.tc/k:J ·.tc/Ko ·.:.□/\..:□ !_; □ / !-: :: :.\~/~::i Customer Code: RAM P:-.c-:-:~ f,'..:r.:':!E'(•~ ·'.701+) S/:1::•-')72'7 Net Det t~ot Det Net Det ~~-J t Det t··.'.Ct Di::t N0t D'= t r-~c t Det !\!c-t Det Nat Det Not Det Net Ds t ~~ ::, : D-2t t ~ ·= t DEt ~~ ,:, -: Det !< •: l: est N-:)t Det t< = t [1~t Not Det r< ct Get N:·t D~t ( e - 10 .:.·:. 10 LAB I .. D. AA0834b E,.:,; _ _j :r:-h!:;.2t:-e~· GS!t,!-'.1-5 Pu~c' '.::• .. ;:~:~::·.-:·:._:r.::::";·:~ ~71.,=: C~:: E ·=ti C :"1 I..•~"t E?: ! ,Z,/.Z,,£./';:: 1=•.".tri:itt.=,l [:=,":~: :c./0S/S·: TEST !=•ARP~E::TER Multico~~c~e~t an2lvsis: ~~PLOGE~ATED VOLRTIL~ BROtv:OD I CHLC1ROf"'.ETHH~·![;: u.□ / 1--: c BROMDFORM ~8/k □ C~PB8N TETRACH~OR!DE .t::/k □ 1:H:....OROE;Ef<Z'.::( ~~ 1.tc / 1-: s :\--!'_Q;-:,J::T!-li'."-lNE 2-CH~ Ct.~OETl-.'YL \,i I t-.!Y:.... ETHEF.· C ~:....O t':OF"O F::--: 1.\□/ko ,_,c/J./o ,_:.o/h:o TE'.=T DRGA'.HCS ~\Ct Det ~~ot [,et l\1c t Det tJ"at Det r ~ :• t [,et Nc-t ['et Nc-t Cet ~-\:,t I'et 449 SPRINGBROOK ROAD• CHARLOTTE, NC 28217 [•E:::::cT 1 or·.\ :... I :1; IT 10 I I I I I I I I I I I I I I I I ANALYTICAL TESTING & CONSUL TING SERVICES P.O. BOX 31486 •CHARLOTTE.NC 28231 • TELEPHONE [704) 527-4183 • FAX: (704) 525-0409 Ram Leat~et· Care Pace: b October 30. 1991 HALOGENATED VOLATILE ORGANICS Cccntiruedl: CHLDR0'•1ETHR~!E DIBROMOCHLORDMETHANE 1.2-DICHL□RDBENZENE 1.3-DICHLDROBENZENE 1.4-DICHLOROPENZENE DICHLORODIFLUOR□METHANE 1. :-DICHLOROETHANE 1.2-C!CH~OROETHA~E 1. 1-[' I CHLOROETHEt<C TRANS-1.2-DICHL□ROETHENE 1.2-DICHLOR□~•ROPANE CIS-1.3-DICHLDRDPROPENE TRANS-:1.~-DICHLORO~ROPEl~E ~ETHYLENE CH~ORID~ 1. 1. 2. 2-TZTl"::HCf-::....O~:tJETHA~\J!:: :.. 1. 1-TF-'.IC!-~'....OROETHAt•~E :. 1.2-TR!CH~OROE~~A~~~ TF: I C~LC:~QC.T:-:~:~E TR!C~~OROFLUCR:~~~HANE i :::,r. ►.•-;c,r.-,-, '.__ E--:-EX '.•', l ~·!E~:((_'.:: :.;::-: PIT~- S~.~~led bv Ccllins ~Jell Dt·il!i~□ [J":·i,.kir:c l<.:.-:r·:· ~<ell. G'l"·e.d 'J W. 8,..1,1· c i ,, ~2.b::.r2.t ot·v ~2.na~er '-lC! / f-: C: 1.l □/~o '"" /k D u □/k □ 1.:. C! / ~\ C I.~=/ k O ;_·::: / k C I}□/ k = : .. c /kc i.t □/ko 1.:.c/kc •.•.c/ko 1.l □/!--:c •.:□/kc 1.:~/!-:c ·.10/~:s 1.1c/k:: .'.C / '-: C 1.1.c:/k □ •·. c / l-: :i ;_;:..J / k !:: ·.:=/k= rt1=/kc t·-!c t J::et l'Jc-t Det Nc,t Det Not Det Nc-t D2t t~Gt DE·t t,:t [•et Nc,t Det Nc_.t Dat I\;-~ • C Det r,o t Det :,-: t Det Net Det !'-Jot Det t1 -.. ._ ' Dct .. ,,.. .. ,•,,_; \, Det ~<: t r, -,i.. -"" ._ r-.\~-t [;et ~~(; t DEt ~-:•:, t Det hlc t Det f~C:t Det t< Ct r:, <= t :)ct [·~t < ~ 449 SPRINGBROOK ROAD• CHARLOTTE, NC 28217 : 0 . 10 11? 10 !C-. I I I I I I I I I I I I I D ( Bold Re~~ 0 ~!ch Labs) ANALYTICAL TESTING & CONSUL TING SERVICES P.O. BOX 31486 •CHARLOTTE.NC 28231 • TELEPHONE [704) 527-4183 • FAX: (704) 525-0409 October 20. 1c.c: Ram Le2t~e~-Cat-e H: t ~-. : [. C ~ i ff ~.' -:-r l e ._. :~:0~· Alb2~~~2~·!e Rj E~la~: 2t~e t·es1jlts cf a~2lv~is of 1 -::-. O=t~tt·,-i4. 1c.8 : • Customer Code: RAM ~~~re LAB I. D. AR08363 F: >: :c ,-,.,~.,. ·-· ·-. s~t~itt~1 D~tE: :0,•:~1s1 C~sto~et· S2c~le I.D~: N~W ~AT~? S .. ~~itt~.l Tlc~: c:~4~ •: :-::-.O ~;_ •=1'."".E. ;·:--:H!,J::: C!ER0~10C~~OROM~TH~'.·~ 1.2-D!C!~~ORQEENZE~E 1.3-DICHLOROB~NZE~JE 1.4-DICHLOROEENZE~~E D!CHLORODIFLUOROMETHANE 1. 1-DIC~~OROZT!·~P~!E 1.2~DICH~OROETHAt~~ 1. 1-DICH~OROETHENE 7 RAN5-1.2-DICHLO~OETHENE l.2-DICHLOROPROPANE CIS-1.3-DICH~ORQPRO~•E~~ TR~~~S-1.3-DIC~~OROPRO~E~·:E ~ETHYLE~J~ CH~ORID~ :. !.2.2-TETRACHLOROET~At·:C 110::::-' I ........ ___ '.1.C /L ·.l.□/L u::/L :_,:.:/:.... 1.:c /L 1_,_0/L '.iC/L uo/L ,.,c /L i_;,c/l... :_:::::i /~ ".-I' '-•...,; ,I ._ uo/L ·.1.::: ;:.... ,_,:i /:.... :_tc .IL """C:-c.-r i',!:,t [,:...·•-: !•;:t [;st ~-'-+ [:::t '.'~c•: Ds·t ,.·.--~ DE-t t--1:t Det t<.:t [,•(::t ~4:,t Det J,kt Det \::-t Det ~·~c-t Det l'~:::t Det r,ot Det Nat Det 449 SPRINGBROOK ROAD • CHARLOTTE, NC 28217 1 1 I I I I I I I I I I I I I I I I I I ~ Bold Research Labs Incorporated ANALYTICAL TESTING & CONSUL TING SERVICES P.O. BOX 31486 •CHARLOTTE.NC 28231 • TELEPHONE (704) 527-4183 • FAX: £704) 525-0409 fi.a.m Leather Ce-.re Pace: 2 October 20. • C. C 1 .1. ., ., - HALOGENATED VOLATILE ORGANICS l. 1.2-TRICHLOROETHANE TRICHLOROETHC:NC: TRICHLOROFLUORO~ETHANE VINYL CHLORIDE C!-ILORCJETHAr--~E CIS-1.2-DICHLOROETH~~~ ETHYLE~"1E BF:8~i". 1 [,E I~•~ MTEE E-:-EX Mlt'JERt'::.L_ Sl=·IF:ITS ( c er-it i n1.•.ed) IJ □/L 1.1.0/L ·.tc/L uo/L uc/'..... '·'·:: / l- u~/L '.•.□/L ·.,o/L r:,□/L Net Det N0t Det Net Det Not Det Nc:t Det Nc,t Det Net Dt:t N c, +; Det Ne+; C-et N-· . -·,., Det ( . 25 1 l 1 1 l 1 1 -----------------------------------------------------------------------·- Ccr.:;.:e:-.t;: ":~T?=:L t:~;-;:1~ =· 10, ...J -.+ -.... c, , .. c;-,. 449 SPRINGBROOK ROAD• CHARLOTTE, NC 28217 I foil survey of i'fecklenburg County, INorth Carolina I United States Department of Agriculture I Soil Conservation Service · in cooperation with . Ill Mecklenburg County Board of Commissioners and D North Carolina Agricultural Experiment Station II rl Ref. 13 I I MECKLENBURG COUNTY, NORTH CAROLINA Wilkes soils. The included areas, each less than 5 acres, I make up 20 to 40 percent of this map unit. The organic matter content is low in the surface layer of this Enon soil. Permeability is slow, the available water I I I I I ·· I . ' !.• capacity is medium, the shrink-swell potential is high, and surface runoff is medium. The subsoil ranges from strongly acid through mildly alkaline. Depth to bedrock is below 60 inches. The water table is below 6 feet. Most of the acreage is woodland and pasture. The rest is cropland. This soil has moderately high potential for most crops. Good tilth can be maintained by returning crop residue to the soil. Erosion is a hazard if cultivated crops are grown. Minimum tillage and the use of cover crops, in- cluding grasses and legumes, reduce runoff and help to control erosion. The potential is moderate for broadleaf and needleleaf trees.· The dominant trees are loblolly pine, Virginia pine, shortleaf pine, eastern redcedar, white oak, red oak, hickory, yellow-poplar, sweetgum, and sycamore. The dominant understory species are dogwood, redbud, holly, sourwood, and black cherry. The clayey subsoil is the main limitation in woodland use and management. This soil has low potential for most urban uses be- cause of the slow permeability, the high shrink-swell po- tential, and the low strength. The slow permeability sig- nificantly limits the absorption of effluent in septic tank absorption fields. This limitation can be partly overcome by modifying the field or by increasing the size of the absorption area, or both. Corrective measures for shrink swell include strengthening the footings and foundations and removing excess moisture. Increasing the size of the footings and, where appropriate, placing structures on slabs are measures commonly used to overcome low strength. The potential is· moderate for camp areas and playgrounds because of the slow permeability. It is high for most other kinds of recreation. Capability subclass is Ille. The woodland group is 4c. EnD-Enon sandy loam, 8 to 15 percent slopes. This well drained soil is on side slopes on the uplands. Mapped areas are oblong and range from 4 to 80 acres. Typically, the surface layer is brown sandy loam about 7 inches thick. The subsoil is 29 inches thick. The upper part is yellowish brown sandy clay loam, the middle part is yellowish brown clay, and the lower part is yellowish brown clay loam. The underlying material to a depth of 60 inches is light olive brown clay loam and sandy loam. Included with this soil in mapping are a few areas where the surface layer is fine sandy loam or loam and a few eroded areas where the surface layer is sandy clay loam or clay loam, and a few intermingled areas of Mecklenburg, Vance, and Wilkes soils. The included areas, each less than 5 acres, make up 20 to 40 percent of this mapping unit. The organic matter content is low in the surface layer of this Eno_n soil. Permeability is slow, the available water 11 capacity is medium, the shrink-swell potential is high, and surface runoff is rapid. The subsoil ranges from strongly acid to mildly alkaline. Depth to bedrock is below 60 inches. The water table is below 6 feet. Most of the acreage is woodland and pasture. The rest is cropland. This soil has moderate potential for most crops. Good tilth can be maintained by returning the crop residue to the soil. Erosion is a hazard if cultivated crops are grown. Minimum tillage and the use of cover crops, in- cluding grasses and legumes, help to control erosio_n in cultivated areas. This soil has moderate potential for broadleaf and needleleaf trees. The dominant trees are loblolly pine, Virginia pine, shortleaf pine, eastern redcedar, white oak, red oak, hickory, yellow-poplar, sweetgum, and syca- more. The dominant understory species are dogwood, redbud, holly, sourwood. and black cherry. The clayey subsoil is the main limitation in woodland use and man- agement. This soil has low potential for most urban uses be- cause of the slow permeability, the high shrink-swell po- tential, and the low strength. The slow permeability sig- nificantly limits the absorption of effluent in septic tank absorption fields. This limitation can partly be overcome by modifying the field or by increasing the size of the absorption area, or both. Corrective measures for shrink swell include strengthening the footings and foundations and removing the excess moisture. Increasing the size of the footings and, where appropriate, placing structures on slabs are measures commonly used to overcome low strength. ·The potential is high for paths and trails and low for playgrounds because of the slope. It is moderate for most other kinds of recreation because of the slow permeability and the slope. The capability subclass is IVe. The woodland group is 4c. ~Georgeville silty clay loam, 2 to 8 percent s~roded. This well drained soil is on broad ridges on the uplands. Mapped areas are oval and range from 6 to several hundred acres. Typically, the surface layer is yellowish red silty clay loam about 5 inches thick. The subsoil is 44 inches thick. The upper part is red silty clay, and the lower part is red silty clay loam. The underlying material to a depth of 11 0 inches is brownish yellow, yellowish red, and strong brown silt loam. Included with this soil in mapping are a few areas of rills and shallow gullies, a few uneroded areas where the surface layer is darker brown and iess clayey than is typical for the Georgeville soil, and a few areas where the subsoil is browner. Also included are a few intermin- gled areas of Cecil, Goldston, and Lignum soils. The included areas, each less than 5 acres, make up 1 0 to 20 percent of this map unit. · I I I I I I I I I I I I I I I I I I I 12 The organic matter content is low in the surface layer of this Georgeville soil. Permeability is moderate, the available water capacity is medium, the shrink-swell po- tential is low, and surface runoff is medium. The subsoil is strongly acid or very strongly acid. Dept11 to bedrock is more than 60 inches. The water table is below 6 feet. Most of the acreage is cropland. The rest is pasture or woodland. This soil has high potential for corn, soybeans, pas- ture, hay, and horticultural crops. Because the surface layer is thin, this soil is difficult to keep in good tilth. The surface layer commonly crusts as it dries after a hard · rain or becomes cloddy if worked when wet, both of which affect germination and cause poor or uneven crop growth. Minimum tillage, the return of crop residue to the .soil, and the use of cover crops, including grasses and legumes, improve tilth, reduce runoff, and help to control erosion. The potential is moderate for broadleaf or needleleaf trees. The dominant trees are loblolly pine, shortleaf pine, yellow-poplar, hickory, white oak, red oak, sweet- gum, and ash. The main understory species are dog- wood, sourwood, · redbud, black cherry, and holly. The clayey subsoil is the main limitation in woodland use and management. This soil has high to moderate potential for most urban uses. The moderate permeability is a limitation for seplic tank absorption fields. This limitation generally· can be overcome by modifying the field or by increasing the size of the absorption area, or both. The potential is only moderate for recreation because of the clayey subsoil. The capability subclass is Ille. The woodland group is 4c. GeD2-Georgeville silty clay loam, 8 to 15 percent slopes, eroded. This well drained soil is on side slopes on the uplands. Mapped areas are oblong and range from 4 to 60 acres. Typically, the surface layer is yellowish red silty clay loam about 5 inches thick. The subsoil is 44 inches t11ick. The upper part is red silty clay, and the lower part is red silty clay loam. The underlying. material to a depth of 110 inches is brownish yellow, yellowish red, and strong brown silt loam. Included with this soil in mapping are a few uneroded areas where the surface layer is darker brown and less clayey than is typical for the Georgeville soil, a few areas of rills and shallow gullies, and a few small areas where the subsoil is browner. Also included are a few· intermin- gled areas of Cecil and Goldston soils. The included areas, each less than 5 acres, make up 10 to 20 percent of this map unit. The organic matter content is low in the surface layer of this Georgeville soil. Permeability is moderate, the available water capacity is medium, the shrink-swell po- tential is low, and surface runoff is medium. The subsoil . SOIL SURVEr is.strongly acid or very strongly acid. Depth to bedrock i~ more than 60 inches. The water table is below 6 feet. Most of the acreage is cropland. The rest is pasture rn woodland. This soil has moderate potential for corn. soybeans pasture, hay, and horticultural crops. Because the sur- face layer is thin, the soil is difficult to keep in good tilt11. The surface layer commonly crusts as it dries after E hard rain or becomes cloddy if worked when wet, both o· which affect germination and cause poor or uneven cro, growth. Minimum tillage, the return of crop residue to thE soil, and the use of cover crops, including grasses anc legumes, improve tilth, reduce runoff, and help to contrc erosion. This soil has moderate potential for broadleaf anc needleleaf trees. The dominant trees are loblolly pine shortleaf pine, yellow-poplar. hickory, white oak, red oak sweetgum, and ash. The main understory species arc- dogwood, sourwood, redbud, black cherry, and holly. The clayey subsoil is the main limitation in woodland use an, management. The potential is· moderate for most urban uses be cause of the slope and the moderate permeability. Th, slope limitation can generally be overcome by specie planning, design, or maintenance. The moderate perme ability is a limitation for septic tank absorption fields The effects of permeability on septic tank absorptior fields generally can be overcome by modifying the fiel, or by increasing the size of the absorption area, or boll·, Erosion is a hazard if the ground cover is removed. Th, potential is dominantly moderate for recreation becaus, of the slope and the clayey subsoil. The capability subclass is Vie. The woodland group i 4c. GoB-Goldston staty silt loam, 2 to 8 percen slopes. This well drained soil is on ridges and sid slopes of the Piedmont Uplands. Mapped areas are con manly· irregular and range from 4 to 20 acres. Typically, the surface layer is brown slaty silt loar about 2 inches thick. The subsurface layer is mottle pale brown and very pale brown slaty silt loam 6 inche thick. The subsoil is brownish yellow slaty silt loam inches thick. The underlying material to a depth of 2 inches is light yellowish brown slaty silt loa.11. It is abo, 75 percent by volume rock fragments. Below this is fra, tured, slightly weathered, fine-grained Carolina slat rock. Included with this soil in mapping are a few arec where there is slate bedrock at or near the surface ar some small areas of Georgeville and Lignum soils. Tr included areas, each less than 4 ·acres, make up 1 0 20 percent of this map unit. The organic matter content is low in the surface lay, of this Goldston soil. Permeability is moderately rapi the available water capacity is very low, the shrink-sw, potential is low, and surface runoff is medium. The su· - --- - - - -- - - - - >fl.I I I I I I I I I I I I I I I I I I I ii NORTH CAROLINA DEPARTMENT OF CONSERVATION AND DEVELOPMENT GEORGE R. ROSS, DIRECTOR DIVISION OF MINERAL RESOURCES JASPER L. STUCKEY, STATE GEOLOGIST BULLETIN NUMBER 63 Ref 14 GEOLOGY AND GROUND WATER IN THE Charlotte Area, North Carolina BY H. E. LEGRAND AND M. J. MUNDORFF GEOLOGISTS, U. S. GEOLOGICAL SURVEY • PREPARED COOPERATIVELY BY THE GEOLOGICAL SURVEY, UNITED STATES DEPARTMENT OF THE INTERIOR • 1952 \ 1. ,. i I I -I I !1' ,, I l ii 1 I 1 I I I 66 GEOLOGY AND GROUND WATER IN THE CHARLOTTE AREA, NOllTH CAROLINA MECKLENBURG COUNTY (Area 542 square 111iles; population in 1D50, 1:)7,052) GeogTaphy anli physiography.-Mecklenburg County, in the southeast part of the Charlotte area, is the most densely populated county in the area. Charlotte, the only city, is the county seat; it is the largest I city in the State and had a population of 133,219 according to the 1950 U. S. census. The county is the center of the textile industry of the Stale, many of lhe n,ills lying in the close environs of Charlotte. That part of the Piedmont Province that includes Mecklenburg County consists of a series of mod- I erately level interstream areas which are appreciably hilly near the larger streams. ?:\o hills stand out prominently above the general level of the upland. The highest land in lhe county is near Davidson, in the extreme northern part of the county, where the altitude is slightly more than S50 feet above sea level, and the lowest land is on the Catawba River at the South Carolina line, where the altitude is about 520 I I I I I I I I I I I I I feet. The western part of Mecklenburg County is drained by the Catawba River, whereas the eastern part is drained by small streams tributary to Rocky River, which itself is in the drainage basin of the Pee Dee River. The n1ajo~ divide forn1ed by these drainage syste111s extends fron1 Davidson in the north through Derita to the vicinity of Matthews .. The Catawba River flows southward along the wes_tern border of the county, whereas the Rocky River flows .along the northeast part. These rivers are only 10 miles apart in the northern part of the county, and as a consequence the interstream area is narrow and much dissected. On the other hand, Catawba.and Rocky Rivers in the southern part of the county are more widely spaced which results in longer tributaries of lower gradients extending lo the major divide. Thus, the topogra- phy in the southern part is rather gentle. Geology.-The most striking feature of the geology of .Mecklenburg County is the near absence of schistose rocks (fig. 17). With the exception of a thin belt of slaty rocks in the extreme east, the rocks of the county are, for the 1nost part, 1nassive and are generally 13.cking in regional structural trends. Rocks of the Carolina slate belt occur in the southeastern part of the county where they extend south- ward fron1 Cabarrus County. Although several types of rock occur within .the belt ·only two are shown on the accompanying geologic map; they are the greens tone and undifferentiated rocks, including slates and associated volcanic rocks. The slates are generally composed of dense. fine-grained siliceous material. At least a part of the slate is ,vell bedded and resen1bles the slate at :ill'lonroe,:.!8 which is a distinctive part of the Carolina slate belt. The slates, as a rule, are well joinLed and possess a genller clit) than other rocks in the Charlotte area. With the exception of the rocks of the Carolina slate belt in lhe east. the rocks of Mecklenburg County belong to the diorite-granite complex or are believed to be associated with it. Gabbro-dioritc is widely ex- posed along N. C. Route 49 south of Shopton in the southwest part. of the county. lt is a massive metlium- to coarse-grained dark colored igneous rock cmnposecl 1nostly of pyroxene or hornblende and plagioclase feldspars. It is exposed in a few road cuts and as isolated boulders above the generally flat land surface. It is locally referred to as "blackjack" and is the source of the Mecklenburg soil type.'" The extent of the gabbro-diorite to the south in South Carolina is not known, but it is bountied in i\Iecklenburg County by rocks_ of the cliorite-granite complex. I The diorite-granite complex proper covers a large area around Charlotte. Bodies of diorite are local- ly separate fr0111 bodies of granite, but as a whole the two rocks are too closely intermixed to 111ap sepa- rately. Outcrops are not common enough to ascertain the predominance of one type over the other except in a general way. However, the granite component is everywhere conspicuous and appears to make up the grei'ter part of the complex. It appears to be subordinate rn the dioi-ite in a band bordering the gab-· bro-diorite in the soi,th and along the Cabarrus County line in the northeast. Rocks in the northern part of the county do not fall easily into the classification of rocks designetl for the Charlotte area. They are granitic but contain considerable hornblende and biotite in places. They ~.istuckey, J. L., Personal communication. ~Report on Mecklenburg County Soils, Agriculturr., and Industry: North Carr,li1rn Dept. Agrir:ulture County Soil Report ;'fo. 1. vol. 38, no. 4, 11. 32, ID_l'i. I I I I I I I I I I I I I I I I I I I GEOLOGY AND GROUND WATER IN THE CHARLOTTE AREA, NORTH CAROLINA EXPLANATION □ ~· 122] Gabbro•diori!e and allil!'d t,a,ie /Odi Diorite and ~rJnite <1iorL\e prodomiruM Granite and diorite iranile predominant w m Greenslone Sla!e and undif!crent,at~d volcJnic roc~s Arrangement o! unds, Ono above the other. does not indicate chronolog,cal sequence. All units are Paleozo,c ai;e or older. Geolo~,c boundM,es are appro,imate Scale Miles o=----'=,,,,.'-~' Leather Mecklenburg County, NC I J~·10' ii ., GEOLOGIC MAP OF MECKLENBURG COUNTY CeolCiY by M, J. Mundorif ind Ii. E. LeGril)d. FIGURE 17.-GEOLOGIC MAP OF MECKLENBURG COUNTY. 67 I 68 I I I I I I I I I I I I I I : '! I I ~ -I I :,, GEOLOGY AND GROUND WATER IN THE CHARLOTTE AREA, NORTH CAROLINA Shopton OP" . ,zz, tzz, ·" " zi .Jo z5 26, ,c-zz-n" "Zs.z, ~~•.-1•ill• pro~ .,, ,, ·" "SJ rt, . ,ez rJ, ,f ,s'.so rs" ..,, 6Q. '&t \ MAP OF MECKLENBURG COUNTY SHOWING LOCATION OF WELLS , / 167, 170. '168 ,rJ ,,1 m / 0 / , $CALE J.lllES 2 / , / ' FIGURE 18.-MAP OF MECKLENBURG COUNTY SHOWING LOCATION OF WELLS. I I I I I I I I I I I I I I I I I I I GEOLOGY AND GROUND WATER IN THE CHARLOTTE AREA, NORTH CAROLINA 69 are shown on the geologic map of Mecklenburg County as predominantly granite although they contain a greater quantity of black minerals than other granites in the Charlotte area. These rocks appear to have the same composition as those of the di.orite-granite complex if a con1plete 111ixing of diorite and granite had occurred. Thus this approximate equivalence and the juxtaposition of these rocks suggest that they may be genetically related and that the hornblende-biotite granite in the northern part of the county may represent a nearly complete rnixing of the diorite and granite con1ponents. The soil derived fro1n the hornblende-biotite granite has a deeper color than soils from other gran- ites of the Charlotte area and contains many yellow ttakes of vermiculite. The rock weathers deeply, owing to the sharp relief in its area of outcrop, thus allowing a thick zone of weathering above the general water table. Grou1ul water.-Nearly all domestic water supplies and three municipal water supplies are obtained from wells (fig. 18). Dug wells are extensively used for domestic supplies in rural districts. Normally they are from about 15 to 50 feet deep ancl 2½ to .4 feet in diameter. As these wells cannot easily penetrate hard rock, they generally yield adequate water as long as the water table does not fall below the surface of the hard rock, or more specifically as long as the water table does not fall below the bottom of the well. Where the bedrock lies at or near the surface, as in much of the area underlain by diorite and gabbro in the south- western part of the county, wells may not be dug deep enough to prevent them from going dry during long periods of dry weather. Records of more than 245 drilled wells are given in the tables of well data ·for Mecklenburg County. i\'lany of these, especially in the rural areas, were core-drilled with chilled shot and are 2 or 3 inches in diameter. Their cheapness makes them suitable for domestic nse, but inasmuch as 7 or 8 gallons a min- ute is the maximum rate at which water can be removed from a 2-inch well by a deep-well pump they are not generally used where large supplies of water are desired. Most industrial and public-supply wells are drilled with a percussion drill and are from 4 to 8 inches in diameter. The large-diamet,r wells might encounter fractures and cracks than missed by small-diameter wells. · Also, more water can be pumped from a large-diameter well. Also, pumps with greater capacities can be installed in the larger wells. The rocks penetrated by wells in Mecklenburg County are chiefly granite and diorite. The gabbroid rocks, occurring mostly in the southwestern part of the county, are included, for the purposes of ground- water ,lescription, with the diorite. A few wells in the eastern part of the connty are drilled in slate bnt complete data on these wells are lacking. As the diorite and granite are rather closely intermingled, some wells doubtless penetrate both rocks. Table .13 presents characteristics of the wells as related to rock types and topographic locations. T,rnu: 13.-SU.\LU.\ftl OF DATA ON l'VELT.S IX 1TECKLENllURG CoUX'l.'Y ACCORDING TO ROCK TYPE ! ! YieltJ (gallon~ a minute) ' I l'nccnt of well~ I :-.nmlicr of ,\ vcraic yielding l gallon Trl'E 01· Rocic I well,; depth a minute or i (feet) R..'lnge Avera'tC Per foot less. I of well ' Dioritc ... ----------·------········ II J 1 j 1-i.'i Jj .9 o. 153 ' Granite ................ ____________ 54 I 12' 2-65 11.5 .092 0 All wells .........• , •......••.... ·I 9S I 132 i-i5 14 .3 .109 l I 1 Drilled wdl! ~ iuchc~ or mor~ iu Ji~metcr. I lo I I I I I I I I GEOLOGY AND GROlJND WATER IN THE CHARLOTTE AREA, NORTH CAROLINA Sc:\l!>(,\J{).'" OF D.\T.-\ OX WELI.S IX ::\IECKI.E:'-IH .. 'Hl: Cnt;XTY (Drilled wells 3 inches or more in diameter) TYPE OF Roci: Diotite .... -------··--------------·· Graulte ...... --~. ____ ............ __ ... . All .,,,ells.---------------------.... ToroGRAPHIC LOCATlO~ Hill.·······------------------···-- FlnL ....................... -----.--·····- Slope _____________________ --------- Draw _____________________________ _ Valley ___________ ._ .. _ .. -... -· ..... ACCORDING TO ROCK TYPE 30 36 66 A~·crage depth (foeL) 155 136 144 YidJ (g:illona :i minute) :1-i5 14 .!i 3-100 IS. t !'er foot of wrH .l-l.i .109 . !2S Perr.cot of wdlli yielding I g::illon :i minute or lcs:i. 0 ACCORDING TO TOPOGRAPHIC LOCATION Numbl'r of wells 41 Avrr:1ge depth (feet) 125 119 lH IH 97 Yicl,! (g:11\ons ,1 minute) Percent of wells l~--~---~---1 _yielding I gallon l-65 S.5 2-40 1:l.1 '.!-j,5 15.0 5-iii 2-U P,:r foot of,,.·ell 0.06S .l!O • I 10 . 173 .082 a 111ic1ute or less. ,- 0 0 0 I According to table 13 wells in diorite have greater yield and average yield per foot of well than wells in granite. The average yield of all diameters for which information is available in diorite is 17.9 gallons a minute as compared with an average of 11.5 gallons a minute for wells in granite. If only 3-inch and • larger wells are considered, those in diorite yield 22.G gallons a minute and those in granite 14.8 gallons a 1uinute. Although granite occurs extei1sively throughout the county, the data on wells do not indicate that it yields more water at one place than another, if topography is disregarded. The same condition holds true lfor the diorite. According to topographic location, wells on hills yield less water than wells on any other topographic site, yielding only .068 gallons a minute per foot of well. This is slightly more than one-thirct of the yield of wells in the most favorable locations, draws, that yield .173 gallon a minute per foot of • well. 1;hus wells in draws have an average depth of 144 feet and an average yield of 24.9 gallons a mi-n- ute. The average. yield might be appreciably higher if only 3-inch and larger wells were considered. As no particular part of the county can be designated as unusually poor and no part as exceptionally • good, it appears advisable to give c01isiderable attention to local conditions in locating a well. West of the slate belt, diorite, the best aquifer, occurs sporadically in almost every square 1nile. Thns in 1nany·cases it is possible to locate a well in the dark-colored diorite or gabbro without sacrificing convenience of loca- l tion. As topography is an important consideration, the location of wells in lowlands or especially in draws should be attempted if relatively large yields are desired. The quality of ground water in Mecklenburg County is good almost everywhere. (See table of anal- • -ysis.) Analyses of water from wells penetrating granite in Mecklenburg County vary considerably in the concentration of dissolved mineral solids. This is doubtless due to the penetration of one or more small bodies of dioritic material in the granite. By virtue of their relatively insoluble mineral constituents the -granites should contain water lower in mineral matter. Analyses of water from wells 27, 133, and 180 I suggest that, although the predominant rock is granite, a large part of the mineral matter in solution comes from dioritic or mafic bodies penetrated by the wells. _ I I I I I I I I I I I I I I I I I I I I GEOLOGY AND GROUND WATER IN THE CHARLOTTE AREA, NORTH CAROLINA 71 Well 235, at Pineville, drilled in a large area of dark-colored gabbroid rocks, yields water containing 395 parts per million dissolved solids. Although this water is considered more or less typical of that in gabbro-cliorite, it is doubtful if any of the ground waters in the county greatly exceed this in mineral mat~ . ter: most of the ground waters should contain rnuch less. Temperatures range from 59" to 63" F and average 61" F. )Iunicipnl supplies.-Huntersville, population 763 (1940 census), obtains its supply from deep wells. l''our deep wells have been drilled for the municipal supply and yields of 5, 9, 22, and 35 gallons a minute are reported for individual wells. The well yielding 5 gallons a minute originally yielded 20, and the well yielding 9 gallons a minute originally yielded 40. The decline in yields in these two wells may be due to interference of wells. In 1945 the average daily use was 30,000 gallons. The water is not treated. The chemical quality· of the water, as shown by the analysis of well 27, is good. Matthews, population 486 (1940 census), obtains its water from a deep well drilled in greenstone, which yields 20 gallons a minute. The water is not treated. i \rdl j I i !)1111,.1,t:lt Type of w,·11 •I¼ n1ilc~ NE. of !luntcrsvillc... JI. G. lln1.dforJ ..... __ _ Sherril ..••. ___ •• __ . Cr-Dr ____ Jo _______ -_____ _ R. G. Summers •••. -.. Earl TorreMe •• _ ••.. Cr-Dr 4 milrs ~E of lluutersvillc ..... John G. Caldwell J. lf. Stillwell .......••••.....•••....••.... Cr-Dr D.i.vidso11 ..............•...... Davidson Cotton !llill:i Inc. ________________ ·•--·-······--------Cr-Dr .••• do ••••• __ • ____________ • ___ •••• do .• __ ._.·----__ ._ .. _. __ •••.. ·-. _____ . Cr-Dr ~ 1··--do .... --··--·----·-··----· D~!~~~~-~~~-~-~-u-e~-· Jim RoUliins _____ •• _ S ! Coruelius ••.... -··--·-·-·-----Cornelius .Mills. Inc._ .. ----·-·-·-······-·-· i !.I i•--·do ..••.. 10 j. __ .tlo ..•... ·····-····----·--. ___ do_·····-····--··. \\'. A. Kirkley ••. -·· i I! ! ... do ... •---·-··············· ._ .. tlo. __ ·-· -······--.... d"···-·· I'.! l•-··,1"··--·-·······--········· Cc,n Yarn Milb •• ·-··· ·······----··-···•·- 1:l i· ... do .•.•....•••• ---···--·-·-____ do •••• -·-··--·-··· ·----·-·······-··--- 1 ! , H{ mile~\\". of Corneliu8 •• _ ... ;',Ir,. ;'l!ary C. Hnger._. ·······-···--·•··•·- 1.5 [ !}1 mile~\\', nf llu11tcrwille .. __ ;'\!rs . .I. C. Lllythc .. _ .. --•·--·•··--····-·-· lfl i ..• _Jo·-··-··-··-·--·-···--··· Joe L. Blythe .•••..... ·····-···-· 1; I. ... Jo .. ·--······•·--··-·-----.I. L. XorkeL.----·-·· ····--······-····--- 1~ I ,5 111ib SI\'. of l!untcr~villc .. __ . \\'. 0. Hollingsworth_ .. ·····-···········-·- l\J i ••.. Jo.·-··-··--·•·-··-······-Long Creek High Cr-Dr Cr-Dr Cr-Dr Cr-Dr Cr-Dr C'r-Dr Cr-Dr Cr-Dr D,g Cr-Dr Cr-Dr Cr-Dr I School. ....... --·--Hickory Drilling Co .. Dr '.!IJ 1 '.! 111ib S. of Huutcrsvillc._._.__ l'ri~ou C:.imp .. ·-·--··· --··-··· .•... ·-··-·-Cr-Dr ! '.! 1 i I~; 11,iks .':i. of Hun!crsl'ill,: .•••.... _do .. ·-_ ... __ ....•••. -·. ___ ..•• _. _ •••.• ,,,, I IH mik~ S. of Huntersville __ . __ County Sanatorium ___ . ···---····-·-·----·- C'r-Or D, 23 1 •••• do ..•••• ·-····-·-····-·-·-•. __ do._. ____ ··-·--·-···--··----·--······· Dr 2-l lluntersville ...• ---·------·-·· Town well L·-·-····-··----······-·--·-·-Dr ~1; 1 .... .Jo .. ·----··--·-·-····-·-·-Town wdl :1 .• ----···· . .\!>e~nathr--•····-·· Dr Ralph HuhUins .•. -.. Dr Depth nf well (feet) mo 83 70 85 80± Di,11nct1ir of wcll (iuch.,~) Depth of Water level ca:iim: (feet l,clo"· (feet) Hurf:.cc) 60 -·-----~-- 22 r.o-so ··-·---·-· -······· --········ 100 l\5 127 106 55 UO± 160 " 30 1i5 125 IOl 225 " 120+ 140+ 70 210 97 " 5 35 !)0 ..... ·-···----· 30 100 ·····-·--· 100 o; " Total hard- Yieh.J ness (field (~.f,.rr,,) tc-,c1s) (p,p.111.) Jb;.IIAlllCS nranite. Adequate yield, alightly hard "·a.ter. Flat. t:ranite. Water sli~htly hard. Hill. 2-3 ···-··-·----r.r1rniie. Modcratc!v aoft 1nter. Hill. 6+ ·--·····-·--C.ranite; 61° F. Hard water. Hill. 65 62½° F. Well at ma.chine shop. Draw. H ·········-·· i wells in group. Aggreg-ale 11 15 so 60 50 -··-·-··· - 5 ···---·-·-·· J¾ ------·----- 3 jQ s+ 6 15 11 ' jQ ~5 60 25 100 35 ,0 55 65 50 yield 14 g.p.'w. to suction pump. When drilled 6 of the i wellil flowed. Draw. Rock: at 30 feet. Slope. Rock: reported at 90 feet. Schi5t. Flat. Schist. Flat. Schist. Water level 60 feet below 9Urface when pumped at 20 g.p.m. Flat. Schist. Flat. t;chist. Draw. Do. Schist. Hill. Schistose tliorite. Hill. Do. &histose diorite. Slope. Schistose diorite. Granite. 62½° F. Hill. Granite. 60½° F. Rock 20 feel. Hill. Crarnile. 5\.1}~0 1". Valley. 62° F. 63° F. Draw. ,t 62° F. Originally 110 ft. deep, 8 in. in diameter. Yielded 40 g.p.ru. Filled with sand ,111d will! redrilled. Draw . 62½° F. Draw. Granite. Originally yielded 20 g.p.m. Draw. I I I \\',:IJ ! IIU, GEOLOGY AND GROUND WATER IN THE CHARLOTTE AREA, NORTH CAROLINA D1u1,ii,;11 Type of ,-.-ell Depth of wdl (fcrt) ; Diameter 1• of well {inchi:,,} Dcptti ca.siui:: (fr.-t) i Total h11.nl-l \\"a.ter level ucss (fidd l(rcet lx:!ow Yield t~t~) !urface) 1 (g.Ji.:n.) , 75 llEM.rni;:s I ,p.p.m.) i' I I ---------1---------1-------1-----1----1---___ , ____ j ________ _ I I I IOU !l\!) 170 ;; l 172 :.l% n,ilf~ ;\\\'. of ;l!int IlilL· ___ _ ~ 11:il~s ;\\\", of ;ltiu~ Hill ______ _ '.i.1 f miics :\G. of .Mint Hill .•••• ~.1 j 111i\c.i :-::E. of ).lint lli\l ____ _ Clear Cnek Xcgro :-,[;sc.h~~~~;i~·j_~~:::: ::::::::::::::::::::1 ~;-Dr ?Ila.son l\"allace .•...... Mu!li~ ...•....•.... \ Cr-Dr Cl;·_;_~:_~~c·k·~i~~··-··-A. E .. neavcr .......• l Cr-Dr Allen and llrooks {,mnuig Cu ....•.•.•...............•.•• Cr-Dr ! _ :;, ",:::i!,-s _ ;\ !•:. of ;11 iut lli!l ... _ -\ :.•·-i' 111ill-E. of ,\lir1l llill. ....... ! •.. du _______________________ _ .\lint llill ••... --------··-····· -,-.du ....... ___ ----··,·-· __ ..•.......• ;; t 1~;i::~;-:-::::::r,i:~;.;:::::::::::: t,~: Ki11g~r,.ft !lo~i,:rr Cr-Dr :\Ii~---------------Everett ~[ullis ___ . __ Cr-Dr ..• 1h>.-·-···----······-" -·--· C. J .. McEwen. __ . ____ Du1wan ... ·-····---Cr-Dr Cr-Dr -.. do .. _ .• _._.--·. __ ._._..... R. J .• \fcEwen ,\: Sou_. W. C .. \!ullis.--.. _. _ 1 .• do .. _ ..•• _._._. ____ ._ ..•. _ C. J. ~leEwcn _ . _____ . __ .•.... __ • ·-. __ . _. .. -.du._ -··-·----··---···-·--\\', F'. Haigler •.. -•--·-E. ;\\nllis ..... ~.--.- D"' _Cr-Dr lil ~1,f mill'"~\\". u[ ;\\int Hill .•••. E. :-.t. Gray_···-------:-.fulliL •..••••. --·-C'r-Dr 175 ~!·'t 111ib :-.'E. ul' .\li1tthcws ..... L. H. Yantllc •.... _. __ E .. \lulli~·-··-----·· Cr-Dr J;r; \~-'\ milts E. o[ :<!atthew~ ...••.. D. ll. Query ...•. _ .•.• Sam Allen ••.•....•• Cr-Dr J ;; :<tau hews .. __ .. _. ____ ._.·-.__ E. 11 I. Rcnfron_ .. ·-... \\'. Doua!i.l~lJIL ... __ . Cr-Dr 17S ..•. Jo·-·-·-···-··-······--··· L. ll. YanJlc .. __ .. ___ Abm1:i.thr.-•....... Cr-Dr l.!I .... ,lo ... ··--·-·-··--·---···· ...• do.·--············ \\"ill 1-ln!li~ .••.. -... Cr-Dr 17:b .... Jo .. •-·-···-··-····---···· ...• t!o. ______ ·--·-···· \\'alLcr ,\\JcruathJ'_ .• Dr I 11% ..•• do ________________________ C. I.. ~e:d ............ Ben Ay~ock .......• Dr I I I I I I I I I 11'0 --.. Lh, ... --···-··--··· ···---· B. D. Fundt:rliurk .•. --\\". Ahcrnathy .. ~-·· Dr Iii! ...• rl"···-·-··-·········-····· .. __ \lo ... •-~·-····---· .... J11 •• ·--·······-· Dr 1S1 -·-·Jo. :-.!:it thews School. ..••..... do .......... _... Dr 1~~~ .... do .--··-······-·--Town ......••.. ·-···· Ben Aycock ........ Dr l."rl 1:\-:( lllil,•s i\\\'. of ?l!atthc\\"s .•• -Cirlyle Tho111pso11 .. _.. Sam Allen _____ .··-· Or lSl :\mil<'~X\\".o[:-.btthcws ... -.. J.fi.Fowlcr .. __ Dr p,;5 ,;~ ~ 1niJt,s ~!•;, of ClwrlMtc .. -. __ J .. J. Al..crs._. __ ....•.. lblph llohl,i11N. .. . . . l lr I Sri .... d<,·-··· ··-·-········-····· John L. Hu11tur --····· \\'. A. Kitldcy... ..• Dr 11\1) do I T. Ir. Pritck1rd.-·•·-· H:ilph Rol,bins. Dr j 111il,•s SE. of C)mlultc........ F. \\". AlcxauJer ..••........ •·--····-Cr-Dr l r,.i\~~ \\". ()( ~!atthc,ws ...••..• i Pmvide11ceSchuol. ........•.•.....••...... Cr-Dr :;J,, u,il,·:1 \\". ,.f :-.1:iLtlww,; ...... · Eli II. :'iprini;:1.... !lcn .\no,·k.... Dr ..•• do .....•••....... -.....•...... du •............... \\", A. Kirklci·. Cr-Dr r, u1ib S. ()f Charl()tte. C.R. Collins.......... i\!011tgor11ery ·-·-···· Cr-Dr ti 1nib :-i. o['Char\oltc. .. ...... C. n. Col!i11s •... -..... Ralph Rol,hins...... Dr .... du ....•.........•.•........... do ......••........ Beu ,\ycock .•...... Dr ~; -~ _wi\~~ 8. ,1: Charlotte .. ~ ... ·[ ,:ha_ron _Schuol_-···· .•• _ ...•. ·_-............. Dr ,l 1,11\c:1 l), of (.harlutl~ ....•.••. , ;:,pr1ngimle !h1rr. _.... llo!,l,i11~. .. • . . . . . . . . Cr-Dr 1!·.j 111ilc,~ ;\I•:. of Pi11<·vil1u ...... 1 Harke;• Bro:1. Xur."Jr)I, Inc................ Dug 3 u1i!cs XE. of Pineville........ Dr. A. :-.L \\"hj~u:m\._. ·-·-········· ....... Cr-Dr 1un ...• do ... ·-· •• _ ....•......••...... do ........ . Cr-Dr ~00 ..•• do ...........••••.......••.... dn ...........••.• Halpli Robl,i11s ...... Dr WI ..•• do •...•...... -·-········-· .... Jo .............•. \\".A.Kirkley ...... c;-Dr ~;~ miles X. of Pinrvi!le ....••. ~1-.( rnilcs ~-or PirH·villc ... _ ... 1 miles::,;_ of l'iucvillc .....•... ?llr~. Eu11icc E. Smilh._ ......•.......• _ Dr. T .. '-J. Recd .....•• ·-·················· I-1. B. Smith. ·-·--·•··I \LA. l~irkler •....• Dn~ Cr-Dr Cr-Dr 01 235 170 ll0 17S 1::1 190 l00% 43 105 !.I~ 100 125 74 ;5 18i 87 ~00 125 50 9'1 !(;.5 UG H7 155 100 l!JII 150 JSIJ 60 1/JO (i5 1:r: 1:rn. '.?Q'.) 102 2G2 C.5 200 !-JO 30 ,'i .'i/S :1 ;o 50 .JO ll0 110 Jn.o;- 12 25 IS 18 ~ 5/Si::::-:::: ::::: ..... 1-· .•••. " \ ::ll 17 Lo~O 18.00 :m l5.0:? ------··----1 4S !---."--___ ... o __ _ 60 3 2-3 12-!5 12 5.5 .so ,'.,5 6 50 2½' •...••..• 10-12 18 20 1-1 un 15 18 15 ' ,'HO 2!1 12 35 ill 55 " 55 45 05 150 --·--··--·1·--··-·· ---·-------·-·---- S5 35 Dra11,•. Soft waler. Hilt. Granite. Soft 11,11-ter. Hill Hill. Slate. Xot in ust". Slope. l•l1t. Slate. Soft watr.r. Hill. Iii!!. Slope. Draw. Hill. Soft water. Slupe. Dynamited well to yield. Slope. Slorc. llill. Slupe. &!ft water. Slope. Do. \\"ell at barn. u~etl for dumrstic uses anti swimming pool. :1tonc. Draw. Grcenstone. UscJ for domes- tic uses and swimming pool. Draw. Aua\ysis iu talilc. Supplie~ six busincssc~ and four families. . Granite. Draw. \\"ell · at st:i.b!c. Gra11ite. Drnw. \\"ell dymauitcd to incrca5e yield. Grcen.~tone. Distrilmtiou not yet iusta!led. Slope. Granite. Hill. Hill. Dioritc. Slope, Dioritc. Flat. Granite. Slope. Slope. Dr:,w. Ur~custouc. F,at. Dioritc. Hill. Slopt. Gat,1,ru. Draw . FL.t. Soft water. Slope. Grceu~loue.! Fl:i.t. Dioritc: ..\bar1Joncd; not auffi~ cic11t water. Hill. Diorite. Abandoul.'d; pumped sand. Hill. Diorite. Dr:i.w. Dioricc. Slop('. Sort water. Hill. lir:111i1e. Hill. llil!. I I I I I I I I I I 11 I I I I I I I I I NORTH CAROLINA DEPARTMENT OF CONSERVATION. AND DEVELOPMENT WILLIAM P. SAUNDERS, Director DIVISION OF MINERAL RESOURCES JASPER L. STUCKEY, State Geologi,it BULLETIN NUMBER 71 EXPLANATORY TEXT FOR Ref. 15 GEOLOGIC MAP OF NORTH CAROLINA By JASPER L. STUCKEY and STEPHEN G. CONRAD RALEIGH 1968 I I I I I I I I I I I I I I I I I I I The diabase intrusives are massive, c1-ystal- line. unmetamorphosed rock that varies in color frcm dark gray, grayish black to nearly black. The minerals and textures present are those commonly found in normal diabase, except some of the larger sills which more nearly ap- proach gabbro in composition. In general, the dikes form low ridges ancl divides, but in the Deep River basin, they are an important influence on drainage patterns. The direction of flow of sev- ;ral streams in the area is determined in part by the trends of the dikes. Many springs occur along these dikes, and it has been learned from experience that water-well sites located near dikes are more likely to furnish good yields. Outcrops are common in the form of boulders, which were produced by spheroidal weathering along the _joints in the rock. Two types of soil, one a brown or grayish-brown, silty loam and the other a dark red to brownish-red heavy clay loam, occur over areas of diabase. Both soil types are underlain with yellow to dark red, sticky clays. METAYOLCANIC ROCKS Metavolcanic rocks occur in three distinct geo- graphic areas in North Carolina. First and most important is the Carolina Slate Belt which actually consists of two belts, one lying across the central part of the State, and the other lying along the eastern edge of the Piedmont Plateau and viestern edge of the Coastal Plain. Second is the Grand- father Mountain Window, which lies partly in the Blue Ridge area and partly in the Piedmont Pla- teau in Avery, Watauga, Caldwell, Burke, and Mc- Dowell Counties. Third is a relatively small area known as the Mount Rogers volcanic group which lies in the northwestern corner of Ashe County. PRECAMBRIAN OR LOWER PALEOZOIC!?) CAROLINA SLATE BELT Rocks of the Caro.lina Slate Belt, because of their complex character and well defined cleavage, have been called slates. Actually, they consist of volcanic-sedimentary formations, composed of slates, breccias, tuft's, .and flows. The flows are interbedded with the breccias and tuft's, while the tuffs pass gradationally into slates. These rocks vary from acid or rhyolitic to basic or andesitic in composition and generally have a well developed cleavage, which gives them a slaty appearance. 26 Rocks of the Carolina Slate Belt series actually form t"'o belts in the State. The first ancl most important of these, and the one which Olmstead (1825) ·first' called the Great Slate Formation, crosses the central part of the State in a northeast direction from Anson and Union Counties on the south to Granville and Person Counties on the north. This belt varies in \\'iclth from 25 to 60 mile~ and consi~b; of metavolcanic rocks intruded at many places by younger granites, described above. The second belt, in which metarnlcanic rocks are exposed as irregular bodies of vnrying size and shape, lies along the eastern edge of the Piedmont Plateau and western edge of the Coastal Plain. This belt, in which Kerr (1875, p. 131) first recognized rocks similar to those of the Great Slate Formation of Olmstead, begins in Richmond County on the south, varies greatly in width, and continues in a.northeast direction to Northampton County on the north. Olmstead (1825), Emmons (1856), and Kerr (1875) considered the rocks of the slate belt as sedimentary in origin but described them as slates, containing beds of porphyry: hon,~ or whetstune slate, breccia, and conglomerate. Emmons (1856) placed the rocks in the Taconic System, while Kerr (1875) chu:isecl them as Huronian in ,ige. which. according to hi8 geologic column, is a division ot the Archean. Williams (1894) recognized for the first time the presence of volcanic rocks in the slates. He described exposures of volcanic flows, breccias, and tuffs, which had been sheared into slates by dynamic metamorphism. Nitze and Hanna (1896) recognized volcanic rocks in the slate belt and considered the Bedded argillites (volcanic slate) of the present map as younger than the volcanics and called them Monroe slates. It is now recognized that the Monroe slates repre- sent a better bedded. less metamorphosed portion of the slate-belt rocks. Following the work of Williams (1894), reporis by Laney (1910 and 1917), Pogue (1910), and Stc1ckey (1928) emphasized the importance of volcanic rocks in the slate belt b,,t did not over- look entirely the presence of sedimentary maierial. These authors considered the rocks of the slate belt to be largely of volcanic derivation but recog- nized the presence of considernble sedimentary (nonvolcanic) material and classed the whole se- ries as laicl down by sedimentary procet5sct-. Mapping carried out for the compilation of the present map tended to vel'ify the above findings. Rocks which may he classed a~ flows 1 breccias1 I tuft's, and 8hales or slates were found to be present. I All of these, except flows, contain considerable amounts of nonvolcanic materials. The flows. breccias, tuffs, >'end slates are all interbeclded and I do not occupy any definite stratigraphic'positions in the series, The flows vary from rhyolite, thl'ough a udesite, to basalt. The rhyolites and anc\~.:-;it~s Yary frum fine grained to coarsely por- 1 ph,'.-ritic. while tht~ basalts arc often amygclaloiclal. The bn:!cl'.ia::-\·ary from rhyolitic to andesitic. in -:ompu:-;ition ancl in size from an inch to nearly a I foot in diameter. The fragments of the breccias arc, in turn, fragmental, apparently of a pyro- cbstic origin, Some of the fragments in the I \Jt'C(;L:ias are sharply angular, while many are rnuncled, indicating transportation and deposition, The tuffs are generally of acid composition and composed of fragments less than an inch in diam- I eteL These fragments, which vary from angular to rounded, are embeclcled in much fine-grained I I I I I I I I I I I rnaterial apparently of nonvolcunic origin. Be- ginning at Siler City. Chatham County, and con- tinuing southwest for 15 to 20 miles are several beds of quartz conglomerate, varying in width frcm a few inches to 250 feet and of unkno\\'n length, The quartz pebbles are less than an inch in diameter and well rounded, further indicating sedimentary processes, The shales or slates, which arc generally well bedded, are composed of fine- grained volcanic material and much land waste. Finally, much of the finer material in the breccias, tuffs, and portions of the shales or slates strong·ly resembles rnetasiltstone and metagraywacke of surne of the metagraywacke rocks in other areas1 further indicating sedimentary origin, In \;iew of the above facts, there is a strong trend 011 the part of some workers to drop the term metavolcanic and use one that defines the rock more nearly a~ 8ediments. That idea was considered for the present map but was discarded in fa\'Or oi' meta\'Olcanics, since the rocks of the .-;;late belt are largely of vo1canll'. origii11 nnd the terminology has been in the literature for more than sixty years. C\o fossils have been cliscovere,l in the slate belt, ,11H.I tht.: age of th(~ rot:ks is not known. Fur many year:-they were classed ~~.s Prccambl'lan., while in recent years there has been a trend towards classing them as lower Paleozoic, On the present map, they are clast:)ed as PrecamlJrian or Lower Faleozoic ( '!), They have been divided ill to three unit!--, Febic volcanic:::;1 1\tlafic volcanics. and Bed- ded argillites (volcanic slate), Felsic Volcanics (fvs) Rocks of the Felsic volcanics unit occupy about half of the Carolina Slate Belt in the central part of the State and are the only rocks shown in that portion of the belt lying along the eastern part of the Piedmont Plateau and western part of the Coastal Plain, In the central part of the State, rocks of the Felsic volcanics unit occupy much of the eastern part of the Carolina Slate Belt north- ca:-~t of Anson1 Ric.;hmond, and Stanly Counties. The rocks of the Felsic volcanics unit are com- pesecl largely of materials of volcanic flow or frag- mental origin, The flows are essentially rhyolite, while the -fragmental materials vary from rhyo- litic to dacitic in composition, The frngmental rocks consist of breccia and coarse and fine tuff, with coarse and fine tuff making· up the greater portion of the unit Lenses of bedded slate and mafic volcanics, too small to show on the map, are present in this unit. The rhyolitc occurs a8 narrow bands and lenses intcrbedded with the breecia and tuff, It is dense and indistinctly porphyritic with a dark gray to bluish color, and, on fresh surfaces, shows a greasy luster. Flow lines are often present and are best seen on weathered surfaces, while amygdaloidal structure is also present. In porphyritic speci- mens the minerals are plugioclase, orthoclase, and quartz, None of the rhyolite outcrops show any effects of metamorphism. The fragmental rocks consist of breccia and coarse and fine tuff, The coarse tuff predominates and contains the breccia and fine tuft as interbed- ded bands and lenses, The fragments composing these rocks are angular to well rounded and vary in size from nearly a foot to a fraction of an inch in diameter, The larger fragments are internally fragmental, while the finer material grades into Bedded argillites (volcanic slate), At places, \vithin a fe\v inches1 fine fragmental rock grades into a rock sho\\'ing uedding planes, When freshly broken, the rock proves to be made up of quartz· and feldspar grains and rock fragments, some of which show a flow structure, set in a dense bluish or greenish grounclmass. In general, the roeks of this unit have a light gray to greenish colur. In the central part of the State, the rocks of the Felsic volcanics unit vary fron1 massive to schistose, At places, the fragmental texture of the rock may be seen, but much of the rock has ueen strongly metamorphosed and possesses a \\'ell defined slaty cleavage that strikes northeast- 27 I I I I I I I I I I I I I I I I I southwest and dips to the northwe~t in the south- ern part of the area and to the southeast in the northern part. The felsic volcanics weather to a light gray soil usually underlain by yellow to light- reel clav. The !aver of soil and clay is usually thick, ;ncl outcrops of fresh rock are not abuncl- ant. Along the eastern part of the Piedmont Plateau and western edge of the Coastal Plain, all the meta volcanics of the Carolina Slate Belt are shown as the Felsic volcanics unit on the present map. The rocks are deeply weathered and covered by a thick layer of soil. As a result, outcrops of fresh rock are scarce. and mapping is difficult. Mun- clorff (1946) sh.owed these rocks on the legend of his map as Slates, schists, and metamorphosed ·volcanics. He considered the series as metamor- phosed sedimentary ancl igneous rocks, including lavas. tuft's, and breccias. He did not mention rhyolite or rocks of a mafic character but did refer to a coarse breccia near Roanoke Rapids. In the coui-se of fieldwork for the present map no rhyo- lite was seen, but small amounts of breccia and in one or two places small outcrops of mafic volcanics too small to show on the present map, we1·e ob- served. In general, the rOcks uf this ar~a consist uf coarse to fine tuft' and bedded slate, with which bodies of gneiss and schist are present in many places. The tuft's and bedded slates are present throughout the area in about equal amounts. In some places, bedded slate predominates, and in others tuft's predominate. These rocks are usually altered near igneous intrusions to garnetiferous mica schist, mica hornblende schist, or biotite schist. Some bodies of gneiss and schist not ap- parently related to igneous intrusives are present and probably represent metamorphosed non\'ol- canic sediments. Six miles west of Smithfield, Johnston Countv, on the east side of U. S. Hig-h- way 70, is a large outcrop that resembles quartzite and contains kyanite crystals. It may be siliceous sediment metamorphosed to quartzite, or it may be a silicified tuft'. Similar outcrops, except for the kyanite, are found north of Princeton in -the eastern part of Johnston County. The bedded slates are dark blue to greenish gray when fresh and become various shades of yellow and reel when weathered, while the tuft's, g-neisses. and schists are generally gray, yellow, or brown. All these rocks have been moderately. metamorphosed and contain a cleavage that strikes northeast and stands nearly vertical. I 28 I Mofic Volcanics (mvs) Rocks of the :\fafic volcanics unit are sho,Yn on the present map only in the northern t,,·o-thirds of Carolina Slate Belt in the central part of the State. They are scattered throughout the area but are mo1·e abundant along the \,·es-tern ~ide. The rocks of this unit consist largely of flows and fragmental materials of volcanic origin. The flows vary from anclesite to basalt, while the frag- mentals are generally andesitic in composition. Lenses of bedded slate and felsic volcanics, too small to show on the map, nre present in thi~ unit. The anclesite and basalt occur as narro,,· bands and lenses interbedded with the fragmentals. The anclesite is dark green in color, usually massive or fine grained, hut occasionally coarsely porphyritic. A coarse porphyritic variety, with hornblende crystals up to two inches long, occurs in western Randolph C~unty. The basalt is dark to nearly black and often amygdaloidal. Both the andesite and basalt are characterized by the lack of a well defined cleavage. lvlinerals present consist of epidote, plagioclase, quartz, secondary calcite, and iron oxides. Epidote is the most abundant min- eral present, giving the rock its green color. The fragmentals consist of breccias and tuffs of andesitie composition. often intermixed with rnuc.h fine-grained material. In places these rocks are fine grained and lack the fragrnental appearance. In such areas, one of which may be seen along U. S. Highway 64 for a mile west of Haw River. the rock strongly resembles a graywacke. The breccias and tuft's contain much epidote and often have a greenish color. Other colors vary-from dark gray to nearly black. In addition to epiclote, plagioclase, and quartz, secondary calcite and iron oxides a1·e present. The mafic fragmentals are not as strongly metamorphosed as the felsic .frag- mentals but contain a cleavage that strikes north- east and dips to the northwest in the southern part of the area and to the southeast in the northern part. These rocks are usually covered with a thick layer of dark-reel residuum. Bedded Argillites (Volcanic Slate) (or) Becldecl argillites (volcanic slate). commonly re- ferred to as slate, bedded slate, or volcanic slate, occur in the southern part of the Carolina Slate Belt in the central part of the State ancl extend north as far .as the central. part of Davidson and Randolph Counties. A few small areas ·are shown on the east sirle of the belt in Montgomery, i\!oore. I I I I I I I .. I;.• I:." I' .. • i •. , .. I I I I I I I ... ·---... S!JRVFV ! tsl Vl::STI GA,TI tJ 1'>lS 80-44 f·\~;J.::r;~:J in cco;)cr~:liof·1 ,vith the l\,:;;·L(~ C2roiina Ocp;F\TnCnt ·of Nillurzd :-.:_,.::.~C)L11·ccs J.r~d Co1J1n1uni~y Deve;oprr:cnt I I I I I I I I I I I I I I I I ·1 I •• Ui'-ilTl:D STATES D I: fJ A f(I 1\·1 E 1'-; T OF T 1-1 E INT I: I{ IO I{ CE()LOC!CAL SUl{VEY 13asic El0:111ents of Grou11cl-\iVater Hydrology . \i\/ith Refer·ence to Co11clitio11s 111 North Ca1·oli11a By Ralph C Heath US Geological Survey v\/2 ter-R.esou r-ces In ves tiga tio ns Open-File Repon 80-44 Prepared in cooperation wi!h !he . North Carolina Depanment of Natural l~esources and Communily Development Raleigh, l'-iorth Carolina ·10so ,,;; I I I I I I I I I I I I I I I I I I United States l)epartrnent of the Interior CECIL !J. ;\f'-!!JRUS, Scuet1ry CEOLOGICAL SURVEY H. \,v. Me11;1rcl, Director GEOLOGIC;\!. SURVEY Post Office Box 2857 Raleigh, North Cirolina 27602 ~ Copies of ;his r·cport 1nay be purchased from:· U.S. GEOLOGIC/',1. SURVEY Open~Filc Services Section Br;inch of Distribuiion - BO·x 25·125; r-cdcral Centc:r Denver, Colorado· 80225 II I I I I I I I I I I I I I I I I I I I Rock Units and Aquifers in the Piedrnont,ancl /Vlountains D -~~B.11~ . ..-.; ,,_ : '-'-~ ''-\$.:C,u.:,.!c) I (~ ~(Sub.,:,:,) I 6 ;':;:~~~:: P •• ,_sr~s L _____ _ Tne rocks underlying the Piedmont and mountains can be ·divided into two groups: (1) bedrock, and (2) saorolile (or residuum). The saprolite under:ieS the \and surface and ranges in thickness from a foot or two near ·bedrock outcrops to more than 100 ft. Bedrock underlies the saproli:e and is the parent rock from which the saprolite was derived in the process referred to as weathering. I .. iany stream valleys, especially those oi larger strecrns, are underlain by a layer of _-ma.teri2I similar in composition to saprolite. This materi2I. wt-iich has been deposited by the streams during floods, _is correctly referred to . as alluvium. However, to avoid .unnecessary complications, we ,·.,ill lump the allu•;ium in with the saprolite for the purpose of this discussion. The bedrock underlying th~ Piedmont and mountains consists of many diffeiellt types of igneous and metamorphosed igneous and sedimentary ro·cks .. The Generalized Geologi- cal t,iap of North Carolina ac.companying the discussion of WATER-BEAfllNG flOCKS · divides the bedrocx in the Piedmont and mountains into six units. The 1:500,000 scale Geologic tvlap ol ~lorth Carolina, published in 1958, divides the bedrock in the same area into :\3 differ·ent units. But, a much larger number of units have t,eeri identified and are shown on large scale geologic maps. · The bedrock units differ from each other in mineral composition 2nd· other geologic characteristics. Fortunately, these differences do not result i~ large differences in hydraulic characteristics so that it is possible to combine the bedrock units into a relatively small number of hydrogeologic units. The accompanying map shows the hycfro- geologic units into which the bedrock in the Piedi-nont and mountains has been divided by t11e U.S Geological Survey and the North Carolina Groundwater Section. The most productive hydrogeologic units are the Great Smoky Mountain ·belt .and the Blue flidge-lnner Piedmont belt. The least produclive units are th·e Carolina Slate Belt and the Triassic Basins. The Charlotte Belt is intermediate in productivity. i I ' l I I i I I ' I I I I I I I I I I I I I I I I I I I (_~ ,ou n d-V./ ;:i tcr ';itua tio n in the Piedrnor:t ,incl /'v'\ountains Tl1e saprofite (we21herec1 r·ock) that forms tr.e \and surface. in \he Piedmont and mountains consists ci unconsolidated granu- lar material. It thus cor:tains water in ti1e pore s_paces betv1r2-en rock particles. Tl1e /Jeo·rock, oc, the other hand, does 1101. have any signiiicant intergranu!ar .(primary) porosity. \t contains water, instead, in sheet-. !ike openings formeci alo11g lrc1ct\Jres (that is, brea~s in the othe,wise "solid" rock). Fractures in bedrock are of t•::o types: (1) joints, wl1ich are bre2ks alo11g v,ihich them has bee11 no ciilfcrnntial move;1~enl; ar'ld (2) fnufts, 1Nhich are breaks along whict-, ll,e adjacent rocks have undergone ditfer8nti2•1 movement. Fau.lts are for1ri8d dLning ec,rthquakes and Qene::·ally contain l2rger and more e;,.;\ensive cp~nings tll2.n thcise developed along joints. Joints, hov✓ever, ere far more numerous th;Jn fa u I ts. Fractures (jcints and fa·ults) are-more abundant under ,10.i!eys, dr2ws, and other sul"l2ce depression::. than under hills. ln fact, 27 gcologis:s assur.1e. tha1 it is the presence of frcclures thal determined the position of valleys in t11e first place. Fractures tend to be 1T10re closely-spaced 2nd the openings developed along them tend to be larger near t!7e surface of t!1e bedrock. i✓1ost fractures appear to be non water-bearing below a depth of 300 to 400 ft. Large water-bearing ope·nings, penetrated below this dept!, are probably associated with faults. The grnund-water system in the Piedmont ar1d mountains is recl1cfrged by precipitation on the inters1re2m areas. A part of t11e precipitation infiltrates tlirough the unsa_tu- r~ted zone to t_he water talJle, which normally occurs in the saprolite. Ground water moves laterally and downward ir1:-ough the saprol_ite to points of ground-· 'Nater seepoge (sµrings) on the hillsides and to tli8 streams in the adj;:!cent valleys. Sarne of the '.vater in the sapro.lite a!so moves downward inio the bedrock and, thereafter, through the l_racturcs to the adjacent v::lleys. I Hydraulic Ch;c1r2cterrstics I Pic-d rnont and tv't o u 11 ta i 11 Ground-V✓atcr Systen·1 of the I I I I I I I I ~_,, STORAGE Ill BED ROU: I One of the most basic concepts of grouncJ- v,1ater hydrology is that aquifers function both I 2s reser·voirs, in 'Nhich 'Noter is in storaae and as pipeline$, v1hich transmit water fro_m, one point to another. This is referred to as the I rescr'✓oir-pipe/ine concept. This concept forms. a useful be.sis on \,.Vl~ich to discuss the hydraulic c(1cir2cteristics of the Piedmont and moun!ain grounCJ-1,•,1atcr system. I The reservoir (storage) function of aquifers dcpe:lds on the poro~ily. The oipeline function depends 011 :he l1yd1·aul1c conductivity ancl ihe I thickness of t11e aquiier. The appro;-:irnaie r2.1·1ge in porosity and l1ydraulic conductivity for i~e saprolite and tieclrock is shown in the ,follo1:,1ing table. I I I I 28 Rock type Saprolile Bedrock Porosity in percent 20-30 0. 1-1 Hydr;:,ulic conduc\i•;ity In feel per day 1-20 1-20 The above values suggest that the principal diilerence between saprolile and bedrock is in water-storage capacity. In other 1,vords, the s2prolite l,as the capacity to s.to,e a much larger quantity of water than does the becirock. This is not the entire story, hov1ever. · As we noteci 2bo.ve, the capacity of an aquifer lo transmit water d?pends both on t1ydraulic conductivity and on aquifer thickness. The par; of the bedrock containing water-bL~aring fr·ac\ur:es is se 1,1er0I ti1-r1es thicker th3n the saprolile. I I I I I I I I I I I I I I I I I I I 1Ne c?.n then, wit~1out gre,:i\ e:Tor, 1.1iew the grouncl-v.-aier system in the Piedrno11t a1:d rnountains as consisting of a saprolite reser- voir overlying 3 bed roe~; pipeline consisting oi nurnerous small, infe1·c6;·1r:ected pipes. In the vicinity of a pumping well the bedroc:~ fractures ("pipes") convey water frorn the s<-:proli\e reservoir to. the 1,,vell. The yield of a well drawing from fractured bedrock depe11ds on several I actors. The most important of these are believed to be: I. The number, size, areal extent, and degree of interconnection of t11e fractures~· penetrated by the well, 2. The thickness of saturated saproiite in the vicinity of the well and the specific yield of the saprolite, and 29 J. The hydraulic conductivi\y of the s2pro- lite. and the nature of the hydraulic con- nection bet\veen the _s3pr·olite 3nc1 the- bedrock. The number and the size oi the iractures contioi \he rate at which water· can enter the well. The areal extent and degree of intercon- nection of the, frpctur·es control the si::e of the area thal supplies water to the well. Tl1e thickness and the specific yield ol the saprolite dete,·mines the volume of watei- availab\e from storage in the saprolite. The hydraulic conductivity ot the saprolite and the nature of the hydraulic connection between the saprolite and the bedrock determines the rate al vihich water can drain from the saprolile into the bedrock fractures. I I I I I I I I I I I I I I I I I I I TO: FROM: DATE: File Jeanette Stanley Environmental Chemist NC Superfund Section December 20, 1995 SUBJECT: Ram Leather NCO 982 096 653 Charlotte, Mecklenburg County, NC Ref. 16 I performed a house count on the area within 4 miles of the Ram Leather site. There are eight homes within 1/4 mile of the site, three of which are contaminated with tetrachloroethylene (PCE). There were eight employees at Ram Leather at the time the well contamination was discovered and the population of these three homes is eight. This was determined during previous telephone conversations, as documented at Reference 10 in the Site Investigation For those areas > 1/4 mile to 4 miles from the site, I counted those homes outside areas of water lines. I reasonably excluded the homes in areas of community wells.· I multiplied the number of homes by the persons per household census data (attached) and then added the community well populations within the respective distance rings to this figure. The 1990 census shows that Mecklenburg and Cabarrus Counties have 2.50 persons per household. The populations per distance ring is: Distance # homes Subtotal population Community well 0 -1/4 > 1/4 -1/2 mile > 1/2 - 1 mile > 1 - 2 mile >2 - 3 mile > 3 - 4 mile 5 X 2.5 = 12 10 X 2.5 = 25 84 X 2.5 = 210 286 X 2.5 = 715 303 X 2.5 = 757 799 X 2.5 = 1,997 population ( + 8 workers + 8 residents) 0 430 1,305 311 2,125 Total population = 28 25 640 2,020 1,068 4,122 I I I I I I I I I I I I I I I I I I \ .. : .. ' . ;:-_:(.,::: i.!!:•.::: ·. d: \,,_,i; ::;;;,:;";.;~• 1~_;_·:1.iv:,1i,::. ::_::~ ;;~~;:.--,ii;:,,,. :r.i:::~· 1-;~:,~L;..0 c:: -;·;;:~. c;_:-,·'.:L'; ~ [C:Sf;&(/i:IIV """""--~ M~; """"' = !ir.:«m ! 1 ~l.---C::'! ,~~w. ~ [~ lt~ ~ ' """""""""" ts;t..'l,.i#iillt~....,__ ! ~@£!I I ~~" :ki't-li?." ~ """""""' ~ I ~ i. ~-' ~ ~ :z. 1990 Census of. Populatioi1 and Housing Summary Population and Housing Characteristics North Carolina "" """' ,, ' ------= -...:m ~1!r-; ' Gffi:'-3U.N-.WiA ~~ ' ~~ ' ~ l ~ l'::'.·~ ~ ~ ~ ~if~\!it®m~1c!&hffli@..•Vi ,t•-&/,hl~.\14¥¾#\#it@~u: 814@-lfffij ......... -........, I I I I I I I I I I I ,, \ I ' i ' ., ! I '/ ,, ,. I ,, ,. ,, ' ' I ;1 ' I I I I Table G. 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"" "' l.U ' ' .. l.11 ,m '" SUMolARY POPV..A TION .,ND HOUSING CHARACTERISTICS NORTH CAROLI/IA NOTE: The population counts set forth herein are subject 10 possible cOrr1::ction for undercount or overcount. TI1e Uni1ed States Department or Commerce is considering whether to cor_reCt these counts and•wiH publish corrected counts, if any, not later than July 15, 1991, O·-,-. ... ~· -·· \I I r.": " ' " " ,, ~ .. . ' \II "" " '" n a ~ " <; n " . ' ,l; " ',~ 11~ a " q " n f l:O: " < Ill ~ ~ ' ' " " '., • I:<.:-> 1:1 '" . " IT::! n . " " . "' "' 1(! • '., " n " en I I"~ ' !J I\' "" " '"' " . • < !,I , " ;~ ;\) " ' "' . " n• ,, . '" ~ I~ . ' '" 105 I ,I-, MEMO I I I I I I I I I I I I I I I I TO: FROM: File Jeanette Stanley Environmental Chemist NC Superfund Section DATE: October 26, 1995 SUBJECT: Ram Leather NCD 982 096 653 Charlotte, Mecklenburg County, NC ~ I plotted the community wells witltin 4 miles of the site on the USGS topographic map and determined which wells fell within which target distance limits. The wells and populations are listed below. Target Distance TQtal Per Limit Community Well System Population Served Ring 0 -1/4 mile none > 1/4 -112 miles None > 112 - I miles Howell's Facility 430* 430 > 1 - 2 miles Country Hills SID 220 Clear Meadows SID 156 Edgewood Hills 89 Long Creek Elementary School 800 Dulin's Grove Church Day care 40 1305 >2 - 3 miles Cedar Park MHP 309 Bradfield Farms SID 3 ...ill >3 - 4 miles Stone's Throw MHP 355 Silverton MHP 142 Bradfield Farms SID 1054 Wilson Woods SID 76 Forest Brook SID 71 Bainbridge SID 376 Elliott's Rest Home 26 Festival on Mint Hill 25 2125 *Exact location and population served determined by telephone conversation and field trip (See memos dated September 29, 1995 and September 22, 1995). I I I I I I I I I I I I I I I I I I I PAGE ' PMMGRJD STATE N.C. PUBLIC WATER SUPPLY SYSTEM 09/13/95 ACTIVE sYSTEMS GR!O LATITUDE, 351030 / 351730,' LONGITUDE: 0803200., 0904030 PWS ID SYSTEM NAME RES.PERSON SOURCE SOURCE TYPE POPULATION WORK Ptf'NE SOURCE NAME TYPE AVAIL. 113106 CABARRUS WOODS/CAMBRIDGE 5/D C CABARRUS WOOOS✓CAMBRIDGE 5,-0 C CABARRUS WOODS,.CAMBRIDGE S/D C CABARRUS WOODS/CAMBRIDGE S/D C CABARRUS WOODS/CAMBRIDGE S/D C 113113 EDGEWOOD HILLS WATER SYSTEM C EDGEWOOD HILLS IJATER SYSTEM C 1131 73 CEDAR PARK MHP C CEDAR PARK MHP C \13193 WEATHERSTONE S/0 C 113204 HOWELL'S CHILD CARE CENTER C I 13217 SIMES IAROW MAP C STONES THROW MHP C ! 13219 SILVERTON S/0 C SILVERTON S✓D C 113◄1 ◄ 113418 ROEi( RI ER BA T G:I RS I 113◄73 BE'fllEC ULI 2TH CH Ii ► I l 13◄7S,...;,o111 Uiil i I BAI I Cli 160210 160218 160219 160229 160230 1602◄◄ 160262 160263 16026◄ 160272 16027S APPLECREEK-FARMWOOD B COUNTRY HILLS S/0 COUNTRY HILLS S/0 WILSON WOODS S/0 LAWYERS STATION LAWYERS STATION CLEAR MEADOWS S/D CLEAR MEADOWS S/0 BRANTLEY OAKS S/D BRANTLEY OAKS S/D WILLOWS CREEK S/D C C C C C C C C C C C FORESTBROOK S/D C BRADFIELD FARMS S✓D C BRADFIELD FARMS S/D C BRADFIELD FARMS-PHASES 9 Ii.. 10 C STONE MTN AT FARMWOOD NORTH C STONE MTN AT FARMWOOD NORTH 160"107 E RR !!(ER SE, 86£ C ' Ii 160"108 ;;!GBWSB J PRESPVTCRlA►I C 1:1Fi91 160"109 .J... 1R ,I IP.UEr 6BbcF eLUB ►I 160"120 <dlLGROOE LAI •~EsS I (S.►'"'\'G REEi'F to 160430 160"1"1! 160"157 ]60"162 LONG CREEK ELEM SCHOOL BAIN ELEM SCHOOL lll:it;I J fiRl31;lE ADVAl<ii CHR1S11At.C I 160512 Pii!L EJEI. ii I itC!,Bi IERIAil Ch 16051"1 I Iii, llLL BAPIISI CHURCH p p l,Ulil l!lLL bAFilSI CHURCH -----rt- Mltil lllbcbc aep:ns:r 61 1:1 M!W HI I:: SAP i 1S I CADNLR " N 188S 70◄5257990 WELL ! BBS 70"152S7990 WELL !B85 70◄5257990 WELL \ 8B5 70◄5257990 WELL I BBS 70◄5257990 WEt..L B9 704"1781785 WELL 89 70"1"1787785 WELL 309 70"15356161 WELL 309 70"153S6161 WELL 120 70"1788,..97 WELL ',Jc~;~:~;;{i~~ ~~tt 355 704◄559635 WELL 1"12 70"1"1782785 WELL 1◄ 2 70"1"1782785 WELL 30 70◄888290"1 WELL 70 70"1522:l'l 17 WELL '20 I WELL 75 WELL ! 2"1 70"15257990 WELL 220 7045257'390 WELL 220 70◄5257990 WELL 76 70"156◄2£. 15 WELL 686 70"18475738 WELL 686 70"18"175738 WELL 156 70◄56"13'..15 WELL 156 70"1S6"126 l S, WELL 39 I 800222$07 WELL 39 ! 800222SE.07 tJELl I 22 800222SE.07 WELL 71 B00222SE.07 WELL 105"1 7047889497 WELL 10S"1 70"17889497 WELL 3 70◄788'497 WELL 0 70"1"1782785 WELL O 704"178278S WELL 270 704S◄ 5~JO'I WELL 350 70"15372279 WELL 25 70"15◄51653 WELL I 25 70◄5"151228 WELL 800 704343&'.l"IO WELL 920 7043"13E(:,"IO WELL 225 7045730942 WELL I 00 7045"1S'3259 WELL 300 70◄5"1561 72 WELL 250 70◄ 5 ◄ 59451 WELL 250 70◄5"1594s I WELL 2S0 7045◄59451 WELL 250 70◄5"159"!5 l WELL i " BROOKSTEAD DR G p ,. PLAZA RD EXT G e " SNOW DR G p " STARWOOD RD G p " BOWSBY COURT G p " G p " G p " G p " G p " G p G p " G p " G p " G p ., G p G p G p G p G p " G p " G p " G p " G p " G p ,, G p " G 0 " G p " G p " G p " G p " G p " G p ,. G p " G p " G p " G p G p G p " " " •·1)-~ ~ " ·tr- / ,, ',' LATITUDE LONGITUDE 3515"12 3S1630 351630 351630 351538 351510 351510 351620 351620 351 700 35!"11S 351717 35171S 351528 351530 95 5$0 351616 3Sl 8 E 3515•6 351033 351251 3512◄8 351217 3510"12 351039 351230 351230 3S1600 351600 351612 351 I 16 3S1512 351S18 351"1"10 351605 351600 SI 410 tl:i3C 35!325 351030 ' s+s•s 903838 901015 :~;~;r.~""t;.-,./,. .. --B89856 90381i6 s---eeaesi;; •.J ·.'.) J c, I I I I I I I I I I I I I I ,:,-,...,. ,,.;-~ ;.,.,,,,, • ••., •e ·/.~~-~--' C \. l l PACE PMMCA!O STATE N.C. PUBLIC WATER SUPPLY SYSTEM 09/13/95 ACTIVE S'i'STEMS GRID LATITUDE, 351030 / 351730,!LONCITUDE: 0803200 ,, 080-4030 RES.PERSON SOURCE SOURCE Pl.JS ID SYSTEM NAME TYPE POPULATION WORK Pl()NE SOURCE NAME ------ 160515 ARI::! J8T81c B F'Ti5T C!IIIRCV 225 70-45◄5375 I WELL 160577 0f.:1fR RB 1:1 ITbD /:Cli;"fl7'8Bl6T Ii ,t ,oo 70-45-456785 WELL !6063<? Cl i:AR CRliliY ?PPHS:t El URE I Ii ,oo 70-45456£,08 WELL !60723 III! £0'1 CRQP E: B PT!!:!T e ll:IREII 11 ,oo 70◄ 5 ◄ 551;25 WELL 1607-46 BAINBRIDGE S/0 C ,,. 70<15257990 WELL BAINBRIDGE S/0 C ,,. 70'15257990 WELL 160787 ELLIOTS REST HOME P 26 70'15-455833 WELL 16081 ◄ DULIN"S GROVE Cl-f.JRCH DAYCARE P ,o 70◄545~680 WELL 160832 FESTIVAL ON MINT HILL C 25 70'4-4781785 WELL / / -2 rn, /aa Cose-fr-'<, f/-,//J 5/D (1t) CleCVL mealow5 sjf) (IJ) Ed~ wox/. fl-, !Is (.!:, ) '2 " L"°:~ 6-zc,.K £(,,.,, ?.£.(t) J)J,·n '.5 6-rv,e [h,,,J, ,t'.)d ccJZe. (_0 7~-3 rn,/-0 C.,da,i Ptt-11< mtfl (o ') Br, J f,dc/ r,,rm5 {/h= 9-i1D) tJ') TYPE AVAIL. LATITUDE LONGITUDE 0------ C ' p 35115◄ :~~:;~/ 0 ' p 35115◄ ' p 351130 803825-p ' p 351325 eo::nis-L ' p 351100 803700 -Q / 3 -f 5forye'-5 --rJ,,-, w hff!f ( F) 5,/v,r-f,.,.. 5/IJ ( v) Brad/11/tzvM.5 sjo (fl,;) w,/J"' µ,,,,,Li s;o (rn) h,r,st &r,o/<. s/n (/!) ,B~;nhr.J'f 5/o ( o) Et!,,t/:o "f:est /ftJm.<-. {P) p,5f,,, I " //11, f //,'!/ &( I I MEMO I I I I I I I I I I I I I I I I I TO: FROM: DATE: . SUBJECT: Superfund Section Staff kancnc Stanley Environmental Chemist NC Superfund Section January 2, 1996 Update on Status of Wellhead Protection Programs in N.C. I spoke with Mr. Randy Prillaman, Hydrogeologist, NC DEM (919) 715-6187. He said that the Wellhead Protection Area implementation plan written by him and submitted to US EPA in late December 1994 has been approved. This plan calls for protection of a whole area based on· a calculation using recharge rate and pumping rate as variables. North Carolina now has primacy in approval of wellhead protection areas. None have yet been implemented. The Rural Water Association is preparing to submit several applications for wellhead proptection, but none have yet been received or approved. Some areas he expects to be the first to have wellhead protection areas are Gaston County, the Town of Black Mountain, and numerous small communities affiliated with the North Carolina Rural Water Association. Gaston County has delineated wells and completed a contaminant source inventory. •• I I Ref. 17 I MEMO I I I I I I I I ·• I I I I I I I I TO: File FROM: Jeanette Stanley L?--~ Environmental Chemist NC Superfund Section DATE: October 13, 1995 SUBJECT: Ram Leather NCD 982 096 653 Charlotte, Mecklenburg County, NC I reviewed the results from the organic analyses conducted on samples taken on September 26, 1995 during the Site Inspection. I noted that the Parnell well was highly contaminated, 204 ppb tetrachloroethylene. I reviewed old analytical results on her water supply and these are much higher than the old levels. I called her stepson, Mr. Jack Parnell, (615) 396-2000. He was not in and I left a message on his answering machine. I called Mrs. Ruth Parnell (704) 545-4324. I informed her that her water was contaminated with the same chemical as before, only higher. I explained that even though her new well tested clean in 1994, tetrachloroethylene is heavier than water and it siriks. I called the Worley residence at (704) 888-6320. There was no answer. I then called Mrs. Worley at her work number, (704) 485-2604. I informed her that Mrs. Parnell's well was contaminated. I explained that I understood that Mr. Worley had supplied clean water in the past and that Mrs. Parnell had told him to stop supplying water when she installed the new well. I wanted to give Mr. Worley the opportunity to supply clean water to Mrs. Parnell as soon as possible. I I MEMO I I I I I I I I I I I I I I I I I TO: File FROM: Jeanette Stanley 9&;;;10 , Environmental Chemist NC Superfund Section DATE: October 16, 1995 SUBJECT: Ram Leather NCD 982 096 653 Charlotte, Mecklenburg County, NC On Friday, October 13, 1995, I called Mike Taylor, Environmental Scientist, US EPA Waste Management Division (404) 347-3931 ext. 6112. He performed the first emergency response on the Ram Leather Site and determined that levels were not high enough to warrant emergency removal. I discussed the situation with the Parnell well, i. e., she had installed a new, deep well and had assumed that it would remain clean. She discontinued drinking bottled water. I had recently tested it and found 204 ppb PCE in her well. Mr. Taylor suggested that I resample the well. If the second sample indicates that the level remains this high (above the emergency level of 70 (ug/L)). I should then again request1an Emergency Removal action. In Friday, October 13, I attempted to reach Kimberly Stevens (704) 336-3982 with Mecklenburg County Department of Environmental Protection but was unable to make contact with her. She has recently sampled wells in the area. I then spoke with Lisa Corbitt, Mecklenburg County Department of Environmental Protection (704) 336-5500. She said that she would sample Mrs. Parnell's well this afternoon. I left a message on Mrs. Parnell's answering machine (404) 545-4324 that Lisa would be there to sample her well again. I '•ld LO.I:. ~ MECKLENBURG COUNTY ENVIRONMENTAL PROTECTION LABORATORY ~:~~-Li';' Oopt.: /.tlG1 labl.D.•: [ .• s...,lod: LJ(-}lc;:. [UCK[g__ Project: capt P,fsl+mPL<f., , ... , 1S101 FH0emer1c., 12.ood (olc/u hou.te) Date Rec'd: h,gg5 I\ Ceo s...,lod: jll1HJ- lod By: R ;O"ili-L~.\ Delivered to Lab On: Dato: 5/1fj qf; Tl .. : z: 6f° r ii.~ DAM wPM Tf•: I I I I I I I I I to s...,lod: 5' r;,_, rz:t>J ~ Delivered By:r;Ji.Lt/i,0 O,~ical r,_.._itian tnor;anic a __________ x __________ x __________ % Organic: 0 Moisture □ ltadioactivi~ Air Groal' Alpha □ Gr-oaa Beta a '.later Groaa Alpha a Gross Beta a Jlf i see l l M"ll!!GLIS Asbestos a -----pt:1/rtr -----pt:1/rtr ______ pt:1/l ______ pt;l/l _______ % ChlorOl)hyll o □ , ____ _.;._I¢ _______ SI Corrosivi ty a Dfaaolved Oxygen a ------Fonaoldehydo a --------a --------a -------a --------a -------- lnoC9!!JiC Mon Net■b Acidity O -----·----·--PID Alkalinity a----- Blcarl>onau C _________ ppo Aggcnate Oroanjq BCll, □, __________ pja ca, a pja o II and Graue □ - Carl>onatc □ __________ -Ph.,.,I □, ________ - Chloride □ PPIII Surfactant □, ________ - Chlodne, Rnidual O pt:a Orp,fq Color a ""it• Acid Herbicide O Report auac:hed Cyanide, Total □ PP111 Orvanlc Acid □ ______ pja Fluoride □ PPIII PCB O R-rt attaclled Harchna □ ~ Pesticide O Re,:,ort anllc:Md Nitrogen, Amnani• □. ______ _ -N~tr~gen, Nitrate+ N1tr1te O ______ _ Nitrogen, Nitrate □•----'----- Nitrogen, Nitrite □. _____ _ Nitrogen, ro 0 tal Kjaldohl • _________ PP111 p11 a ... 1 .. Phosphorus, Or-tho 0. ______ _ Phosphorus, Total 0.-'------- Phosphorua, Total otoaolved a Residue, Filterable □. _____ _ A.Hidue, f)i,1~1 ided □------ A.esidue, Total □ ______ _ ------Sl)eeific Q ________ UlftO/CII Conductance Sul fate O _________ _ -Sulfide □, _________ _ - . Seaivolatile O Rep,rt attacftlld TPH O __________ - VOC ~ R-,t attaclled Ntneral !'!Sil! Al □ ____ -____ - CaO -- coo --Cu □ --,.a -• MgO --Mn □ --, a -• SI □ --Ha □ --Sn □ -pi:,b zn □ -• 0 --Turbidity □ ________ _ NT\J Tqxfc Neta\• TCLP Metala 0 Sb □ ____ 1¢ _____ pja All FIElD DATA MlST BE RECDIDED TO IIAIIITAIN CHAIN OF CJSTCl)T •• a Pl'I> - Ba a Pl'I> pja I Aemarics: _________________________ _ Bo O 1¢ pja Cd □ 1¢ pja Cr □ 1¢ pja I Pb □ 1¢ pja Hg □ J,r:,b pja HI □ -pja s • a 1¢ pja Ag □ 1¢ pja · n a PIG ~ a Pl'I> ----- I I I I I I I I I I I I I I I I I I I I MECKLENBURG COUNTY DEPARTMENT OF ENVIRONMENTAL PROTECTION ENVIRONMENTAL LABORATORY Field I.D.#: Project: site Sampled: Lab I. D. #: ...J-/l/,_f/4-1/7"--- Date Sampled: Sample Matrix: Water Volatile Organics Sample Detection Organics-Volatiles Results Limits Method Parameter (ug/1) (ug/1) Acetone < 100 100 8240B ( f) , 524.1 ( i) , 624 (g) Acrolein < 100 100 8240B ( f) , 524.1 ( i l , 624 /al Acrvlonitrile < 100 100 8240B ( f) , 524.1 ( i) , 624 (al Benzene < 5 5 8240B ( f) , 524.1 ( i) , 624 (g) Bromodichloromethane < 5 5 8240B ( f) , 524.1 ( i) , 624 (g) Brornoform < 5 5 8240B ( f) , 524.1 ( i) , 624 (g) 2-Butanone < 100 100 8240B ( f) , 524.1 ( i) , 624 (g) Carbon Disulfide < 5 5 8240B ( f) , 524.1 ( i) , 624 (g) . Carbon Tetrachloride < 5 5 8240B ( f) , 524.1 ( i) , 624 (g) Chlorobenzene < 5 5 8240B ( fl , 524.1 ( i l , 624 /al Chloroform < 5 5 8240B ( f) , 524.1 ( i l , 624 (al Chlorodibromomethane < 5 5 8240B ( f) , 524.1 ( i) , 624 (g) Chloroethane < 10 10 8240B ( f) , 524.1 ( i) , 624 ( gl 2-Chloroethyl Vinyl Ether < 10 10 8240B ( f) , 524.1 ( i) , 624 (g) 1,2-Dichlorobenzene < 5 5 8240B ( f) , 524.1 ( i) , 624 ( g) 1,3-Dichlorobenzene < 5 5 8240B ( f) , 524.1 ( i), 624 (g) 1,4-Dichlorobenzene < 5 5 8240B ( f) , 524.1 ( i) , 624 (g) 1,1-Dichloroethane < 5 5 8240B ( f) , 524.1 (il, 624 /al 1,2-Dichloroethane < 5 5 8240B ( f) , 524.1 (i), 624 In\ 1,1-Dichloroethylene < 5 5 8240B ( f) , 524.1 ( i) , 624 (g) cis-1,2-Dichlorethene < 5 5 8240B ( f) , 524.1 ( i) , 624 ( g) trans-1,2-Dichloroethene < 5 5 8240B ( f), 524.1 ( i) , 624 (g) 1,2-Dichloropropane < 5 5 8240B ( f) , 524.1 ( i) , 624 (g) cis-1,3-Dichloropropene < 5 5 8240B ( f) , 524.1 ( i) , 624 (g) trana-1,3-Dichlorapropene < 5 5 8240B ( f) , 524.1 ( i) , 624 ( g) Ethvlbenzene < 5 5 8240B ( f) , 524.1 ( i l , 624 ( al 2-Hexanone < 50 50 8240B ( f) , 524.1 ( i l, 624 (a) 4-Methyl-2-Pentanone < 50 50 8240B ( f) , 524.1 ( i) , 624 (g) Methyl Bromide < 10 10 8240B ( f) , 524.1 ( i) , 624 (g) Methyl Chloride < 10 10 8240B ( f) , 524.1 ( i) , 624 (g) (f) Test Methods for Evaluating Solid Waste, Physical/Chemical Methods, SW 846 (g) 40 CFR, part 136 (i) Methods for the Determination of Organic Compounds (EPA 1988) I. I I I I I I I I I I I I I I I I I I I MECKLENBURG COUNTY DEPARTMENT OF ENVIRONMENTAL PROTECTION ENVIRONMENTAL LABORATORY Project: Field I.D.#: Lab I.D.#: Site Sampled: Date Sampled: Sample Matrix: Water Volatile Organics,=n<I Sample Detection Organics-Volatiles Results Limits Method Parameter (uq/ll tua/1) Methylene Chloride < 5 5 8240B ( f) ' 524.1 ( i) ' MTBE < 5 5 8240B ( f) ' 524.1 ( i) , Styrene < 5 5 8240B ( f) ' 524.1 ( i) , 1,1,2,2 Tetrachloroethane < 5 5 8240B ( f) , 524.1 ( i) , Tetrachloroethylene < 5 5 8240B ( f) ' 524.1 ( i) , Toluene < 5 5 8240B ( f) , 524.1 ( i), 1,1,1-Trichloroethane < 5 5 8240B ( f) , 524.1 ( i) , 1,1,2-Trichloroethane < 5 5 8240B ( f) ' 524.1 Ii l , Trichloroethylene < 5 5 8240B ( f) , 524.1 C i l , Trichlorofluoromethane < 10 10 8240B ( f) , 524. 1 ( i) , Vinyl Acetate < 50 50 8240B ( f) ' 524.1 ( i), Vinyl Chloride < 10 10 8240B ( f) , 524.1 ( i) , Xylenee (total) < 5 5 8240B ( f) , 524. 1 ( i) , 624 (g) 624 (g) 624 (g) 624 (0) 624 (g) 624 (g) 624 (q) 624 I al 624 !al 624 (g) 624 (g) 624 ( g) 624 (g) ( f) ( g) ( i) Teet Methods for Evaluating Solid Waste, Physical/Chemical Methods, SW 846 40 CFR, part 136 Methods for the Determination of Organic Compounds (EPA 1988) • Source Saft1)led: S~led By: Delivered to Lab On: Cate s....,le-d: ,f; q) Time: //;I{) ~ I Ch-ical C,_...ition · I I I I I I I I I I Incu·;anic 0 _________ x __________ x. _________ x. Organic □ Moiiuur• □ Radioactivirt Air Grosl' •tpna □ Grose Beu □ -----pt:.1/ri' _____ p1:.11r \Jeter Groaa Alpha a ------pt:.1/~ Groaa Beta □ ______ pt:.1/L JI f see l l a"1eCU1, Asbntoa □ ________ x Chloropnyl l a □ ppb Corrosivity □ SI Dfaaolved Oxygen O A:111 FoMIOldehyde □ ppa □ -□ -□ """' □ """' I notpnj C Ian Netat■ Acidity O ·-----------Alkalinity □ ___ _ Bicarbonate C ________ _ Carbonate □ _________ _ Chloride □ Chlo.-ine, Rnidual 0 ------Color □ u,it■ C'flll\ide, Taul □-------Fluoride O ________ _ Ha-•□. _________ _ Nltr09en, Amncnia □. ______ _ Nftr~gen, Nitrate+ Nitr1te O ______ _ Nitrogen, Nitrate □, ______ _ Nitrogen, Nitrite 0 Nitrogen, Total Kjeldahl □, ________ _ --------~ □---------u,i u Phosphorus, Ortho □. ______ _ --Phosphorus, Tot■l □------­ Phosphorus, Total Dluolved □ PP8 RniciJe, Filterable □------ppa Rnlct., Suai,encled □-------RniciJe, Taul a_______ - Specific □ ________ l.llllo/c:m Conductance Sulfate O _________ _ -Sulfide □, _________ _ - A99Cfflt! Qrgpnjg BIJI,□. __________ _ ca,□ -Oil lll'G Greue 0 ______ - Ph-I □---------Surfactant □. ________ ppa Orpnjfl Acid Hari>lcldo □ R-• attacllad orvanic Acid □ _______ _ PCB □ R_,., atiacllad Pntlclde □ R-• a••- . seaivolattle a Report •ttadled TPN □ __________ - VOC /i-R-t aUacllad Ninon\ P!!UI• Al □ ____ ppa ____ 1¢ ea a---------• coo --cu □ ppa Pl"' Fa □ ppa Pl"' •vo -• Nn □ --K □ ppa ppb SI □ ppa ppb Na □ ppa Pl"' Sn □ --Zn □ -Pl"' □ -ppb Turbidity □ ________ _ NTU Togfc s.et■ll TClP N°'ala □ Sb □ ___ _ ppb -IOTE: All FIELD DATA JII.JST BE REa'.IIDED TD NAIIITAllf CHAii OF CJSTtDT uc ___ _ ppb -I A:enarks: Ba □ ___ _ a.a ___ _ Cd □ ___ _ ppb -ppb -ppb -Cr □----ppb -I Pb □ ___ _ ,,a ___ _ ppb -ppb -NI □----ppb -Sa □ ___ _ ppb -r _ ;i._. I Laboratory Oirecto_r: g-,c __ _ lo \<?!~ Tl □ __ _ □---- ppb -P!>b Pl- ppb -.I I I I I I I I I I I I I I I I I I D --1 MECKLENBURG COUNTY DEPARTMENT OF ENVIRONMENTAL PROTECTION ENVIRONMENTAL LABORATORY Project: Field I.D.#: Lab I.D. #: Site Sampled: Date Sampled: Sample Matrix: Water Volatile Organics . Sample Detection Organics-Volatiles Results Limits Method Parameter ( ug/ 1) (ug/1) Acetone < 100 100 8240B ( f) , 524.1 ( i) , Acrolein < 100 100 8240B ( f) , 524.1 (i), Acrylonitrile < 100 100 8240B (fl , 524.1 ( i) , Benzene < 5 5 8240B ( f) , 524.1 ( i) , Bromodichloromethane < 5 5 8240B ( f) , 524.1 ( i) , Bromoform < 5 5 8240B ( f) , 524.1 ( i) , 2-Butanone < 100 100 8240B ( f) , 524.1 ( i) , Carbon Disulfide < 5 5 8240B ( f) , 524.1 ( i) , Carbon Tetrachloride < 5 5 8240B ( f) , 524.1 ( i), Chlorobenzene < 5 5 8240B ( f) , 524.1 ( i), Chloroform < 5 5 8240B ( f) , 524.1 ( i) , Chlorodibromomethane < 5 5 8240B ( f) , 524.1 ( i) , Chloroethane < 10 10 8240B ( f) , 524.1 ( i) , 2-Chloroethyl Vinyl Ether < 10 10 8240B ( f) , 524.1 ( i) , 1,2-Dichlorobenzene < 5 5 8240B ( f) , 524.1 ( i) , 1,3-Dichlorobenzene < 5 5 8240B ( f) , 524.1 ( i) , 1,4-Dichlorobenzene < 5 5 8240B ( f) , 524.1 ( i) , 1,1-Dichloroethane < 5 5 8240B ( f) , 524.1 ( i) , 1,2-Dichloroethane < 5 5 8240B ( f) , 524.1 ( i) , 1,1-Dichloroethylene < 5 5 8240B ( f) , 524.1 ( i) , cis-1,2-Dichlorethene < 5 5 8240B ( f) , 524.1 ( i) , trans-1,2-Dichloroethene < 5 5 8240B ( f) , 524.1 ( i) , 1,2-Dichloropropane < 5 5 8240B ( f) , 524.1 ( i) , cis-1,3-Dichlorop~opene < 5 5 8240B ( f) , 524.1 ( i) , trans-1,3-Dichloropropene < 5 5 8240B ( f) , 524.1 ( i) , Ethylbenzene < 5 5 8240B ( f) , 524.1 ( i) , 2-Hexanane < 50 so 8240B ( f) , 524.1 ( i) , 4-Methyl-2-Pentanone < 50 50 8240B ( f) , 524.1 ( i) , Methyl Bromide < 10 10 8240B ( f) , 524.1 ( i), Methyl Chloride < 10 10 8240B ( f) , 524.1 ( i) , 624 (g) 624 (q) 624 ( g) 624 (g) 624 (g) 624 (g) 624 (g) 624 (g) 624 (g) 624 ( q I 624 (q) 624 (g) 624 (g) 624 (g) 624 (g) 624 (g) 624 (g) 624 (qi 624 (qi 624 (g) 624 (g) 624 ( g) 624 ( g) 624 (g) 624 (g) 624 (q) 624 (g) 624 (g) 624 (g) 624 (g) (f) Test Methods for Evaluating Solid Waste, Physical/Chemical Methods, SW 846 (g) 40 CFR, part 136 (i) Methods for the Determination of Organic Compounds (EPA 1988) I I I I I I I I I I I I I I I I D D MECKLENBURG COUNTY DEPARTMEN'r OF ENVIRONMENTAL PROTECTION ENVIROHMEHTAL LABORATORY Project: Site Sampled: Sample Matrix: ~ Organics-Volatiles Parameter Methylene Chloride MTBE styrene 1,1,2,2 Tetrachloroethane Tetrachloroethylene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethvlene Trichlorofluoromethane Vinyl Acetate Vinyl Chloride Xylenes (total) Field I.D.#: Lab I.D.#: · Date Sampled: Volatile OrganicS,con<I sample Detection Results Limits tun/1) (ua/1) < 5 5 8240B ( f) • < 5 5 8240B ( f) • < 5 5 8240B ( f) , < 5 5 8240B ( f) • < 5 5 8240B ( f) • < 5 5 8240B (fl . <· 5 5 8240B ( f ) , < 5 5 8240B ( f) ·, < 5 5 8240B ( =) , < 10 10 8240B ( f) , < so so 8240B ( f) • < 10 10 8240B ( f) • < 5 5 8240B ( f) , Method 524.1 ( i) • 524.1 ( i), 524.1 ( i) , 524.1 ( i) , 524.1 ( i) , 524.1 ( i), 524.1 . { i) , 524.1 (i), 524. 1 Ii l , 524.1 ( i) , 524.l ( i), 524.'. ! :. ) , 524.1 ( i) , 624 ( g) 624 ( g) 624 (g) 624 (0) 624 (g) 624 (g) 624 (q) 624 {g) 524 /al 624 (g) 624 ( g) 624 ( g) 624 ( g) ( f) Test Methods for Evalu·ating Solid Waste, Physical/Chemical Methods, SW 846 (g) 40 CFR, part 136 (i) Methods for the Determination of organic Compounds (EPA 1988) --··---------·· .,- ~ MEC~~~~~~G COUNTY ENVIRONMENTAL PROTECTION LABORATORY C___D '' · ' -. ~ Dept.: fl/&_ lab I.D. t: .ite S-led: lobed !,(/11f<,an !fffJy5°,J.~~ Project: mpL k'f~tnfLv l.oor ... , l.501,i 111/Jonftr ;e !{cl llec'd By: /[51 Cl~ ;j . 1Mcet Oate Sarroled: I I I I I I I I I Ol!.9ical C itian Inorganic □ ________ x __________ .% Or-genie a Moiilture 0 _________ x. Radioactivi:tt" Air Grost Alph■ 0 -----pCI/_, Gros■ Bet■ 0 -----pCI/,., Water Groaa Alpha □ Gron Btlt■ 0 Ill i scel l anecua Asbntos 0 ______ pCl/l ______ pCl/l ________ x Ch lorop,yl l o 0 . ______ Pill> _______ SI Corrosivity 0 Dissolved Oxygen a -------Formaldehyde a -------a --------a --------a --------a ------- Oau Rec'd: 0elivered to Lab On: Tim: Dato: 6 / / 19,> T iaw: //.' 3cJ g: l II: Delivered By: I <:{t.Ve/JS Jnar:,enjc Mon Metal■ A99CS:9at! Orp1jq Acidity a ·-----·-----eco, □. __________ - Alkal inlty O _________ -CCCI □----------- Bicarbonate C _________ -OIi and Graue □------- Carbonate a -Phenol □--------- Chloride O -Surfactant O - Chlodne, RHidulil O ~ Orpnjq Color O i.,lta Acid Norbfcfde O 1-t attached Cyanide, Total O PSD Or;anic Actd O ______ - Fluoride O ________ _ Pl"' PCS O a_,t attached HerGiesa □-----------s:,s::a Pesticide a Report attached Nltroten, AmnDni ■ a Nitrogen, Nitrite Nitrate+ 0 Nltr09en, Nitrate 0 Nltroaen, Nitrite a Nitrogen, Kjeldahl Tot ■l a pit a ---- · Seaivolatile O Repon attadNd TPN O _________ - V0C 'J a_,t Utoclted Mineral !!tttla Al O ____ -____ 111D caa_____ • uilt ■ Co O ____ -_____ l'ID Phoaphon,s, ortho □---------cu a -l'ID Phoaphon,s, Total O -Fo O -l'ID Phos~arus, Total Dlaoolvod a A:niciJe, Filterable a Residue, susi:i ldedO Residue, Total a Specific □ Conductance Sul fate a Sulfide a ' Turtildfty 0 ----UD'\o/cm --NTU Ng □ -l'ID Mn □ --, a -• SI O -l'ID ~-□ --Sn □ -l'ID Zn □ -- a -• Tm;jc Metal! TCLP Metal• □ Sb O ____ l'ID _____ - ALL FJELD DATA -,sf BE REcatDED TO NAllfTAJN CHAii OF OJSTCDY As O Pill> - I A.emarks: a.a • - a. a Pill> - Cd O Pill> - c, a Pill> - Pb O ppb - Hg O Pill> - NI O Pill> - So O Pill> - Ag O Pill> -. Tl O f'!"> PP' a Pill> ____ - I I I I I I I I I I I I I I I I I D I MECKLENBURG COUNTY DEPARTMENT OF ENVIRONMENTAL PROTECTION ENVIRONMENTAL LABORATORY Project: Field I.D.#: Lab I.D.#: Site Sampled: Date Sampled: Sample Matrix: ~ater Volatile Organics Sample Detectio'n Organics-Volatiles Results Limits Method Parameter (ug/1) (ug/1) Acetone < 100 100 8240B ( f) , 524.1 ( i) , Acrolein < 100 100 8240B ( f) , 524.1 ( i) i Acrvlonitrile < 100 100 8240B ( f), 524.1 (i), Benzene < s s 8240B ( f) , 524.1 ( i) , Bromodichloromethane < s s 8240B ( f) , 524.1 ( i) , Brornoform < s s 8240B ( f), 524.1 ( i) , 2-Butanone ' < 100 100 8240B ( f), 524.1 ( i) , Carbon Disulfide < 5 s 8240B ( f) , 524.1 ( i), Carbon Tetrachloride < 5 5 8240B ( f) , 524.1 (i), Chlorobenzene < 5 s 8240B (fl, 524.1 ( i) , Chloroform < 5 5 8240B ( f) , 524.1 ( i) , Chlorodibromomethane < 5 5 8240B ( f) , 524.1 ( i) , Chloroethane < 10 10 8240B ( f) , 524.1 ( i) , 2-Chloroethyl Vinyl Ether < 10 10 8240B ( f) , 524.1 ( i) , 1,2-Dichlorobenzene < 5 5 8240B ( f) , 524.1 ( i) , 1,3-DichlorcbenzBne < 5 5 8240B ( f) , 524.1 ( i) , 1,4-Dichlorobenz~ne < s s 8240B ( f) , 524.1 ( i) , I 1, 1-Dichloroethan·e < s s 8240B ( f), 524.1 ( i l , 1,2-Dichloroethane < s s 8240B ( f), 524.1 ( i) , 1,1-Dichloroethylene < s s 8240B ( f) , 524.1 ( i) , cis-1,2-Dichlorethene < 5 5 8240B ( f), 524.1 ( i) , trans-1,2-Dichloroethene < 5 5 8240B ( f), 524.1 ( i) , . 1,2-Dichloropropane < 5 s 8240B ( f), 524.1 ( i) , cis-1,3-Dichloropropene < 5 5 8240B ( f) , 524.1 ( i) , trans-1,3-0ichlorcipropene < 5 s 8240B ( f), 524.1 ( i) , Ethvlbenzene : < 5 5 8240B ( f), 524.1 ( i) , 2-Hexanone < so so 8240B ( f) , 524.1 ( i l , 4-Methyl-2-Pentanone < 50 so 8240B ( f) , 524.1 ( i) , Methyl Bromide < 10 10 8240B ( f), 524.1 ( i) , Methyl Chloride < 10 10 8240B ( f) , 524.1 ( i) , 624 (g) 624 (q) 624 (q) 624 (g) 624 (g) 624 (g) 624 (g) 624 (g) 624 (g) 624 (Ol 624 (q) 624 (g) 624 (g) 624 (g) 624 (g) 624 (g) 624 ( g) 624 (ol 624 ( q) 624 (g) 624 ( g) 624 (g) 624 (g) 624 (g) 624 (g) 624 ( q) 624 ( q) 624 (g) 624 (g) 624 (g) (f) Test Methods for Evaluating Solid Waste, Physical/Chemical Methods, SW 846 (g) 40 CFR, part 136 (i) Methods for the Determination of Organic Compounds (EPA 1988) I I I I I I I I I I I I I I I I I MECKLENBURG COUNTY DEPAR'.l!MENT OF ENVIRONMENTAL PROTECTION ENVIRONMEN'XAL LABORATORY Project: Field I.D.#: Lab I.D.#: 1ar: Site Sampled: Date Sampled: sample Matrix: Water Volatile Organics,=nU Sample Detection Organics-Volatiles Results Limits Method Parameter ( ua / l) (ua/1) Methylene Chloride < 5 5 8240B (fl , 524.1 ( i l , MTBE < 5 5 8240B ( f l , 524.1 ( i) ' Styrene < 5 5 8240B ( f) ' 524.1 ( i) ' 1,1,2,2 Tetrachloroethane < 5 5 8240B ( f) ' 524.1 ( i) ' Tetrachloroethylene < 5 5 8240B ( f)' 524.1 ( i) ' Toluene < 5 5 8240B ( f) ' 524.1 ( i) , 1,1,1-Trichloroethane < 5 5 8240B ( f) ' 524.1 (il, 1,1,2-Trichloroethane < 5 5 8240B ( f) , 524. 1 ( i) , Trichloroethvlene < 5 5 8240B (fl , 524.1 (i), ' Trichlorofluoromethane < 10 10 8240B ( f) , 524.1 ( i) , Vinyl Acetate < so so 8240B ( f) ' 524.l ( i) , Vinyl Chloride < 10 10 8240B ( f) , 524.l ( i) , Xylenes (total) < 5 5 8240B ( f) , 524.l ( i) , 624 (gl 624 (g) 624 (g) 624 ( Q) 624 ( g) 624 (g) 624 l<TI 624 (q) 624 (al 624 (g) 624 (g) 624 (g) 624 (g) (f) Test Methods for Evaluating Solid Waste, Physical/Chemical Methods, SW 846 (g) 40 CFR, part 136 (i) Methods for the Determination of Organic compounds (EPA 1988) liite Sancled: J)A:IC Tu,cke_r a.,, ... , 15229 P:IOrmAfle. ,--, Project: Bcocl Delivered to Lab On: Rec'd By: Dau Rec'd: Tl•: 11ource Sancled: -/-1-..u1.d lancled By: °t([)~S..wW.;.1· .-11:.C1.>f\~dl.l.... ____ _ . ct Time: 1·:z;~ Dau: ~/Zf/ C,) Tia.: ~: 35e:: Del lvered By: '1( ciJI(J..f/l/\,'.;\ O\eaieal r5-:??!•tian Jnorpnic Man Net■ta -'99rnate Oraanie Inorganic D __________ x. Acidity □~--------sa,, □, ___________ - I I I I I I I I I Organic 0 ___________ x Alkalinity □____ -ca, □ - Noi8ture 0 ___________ % Blcarbcnate C _________ -Oil and Gro ... 0 - Radioactivi~ Air Gross' •lciha □ Gros■ Beta □ Water Gros■ Alpha □ Gross Beta □ "iscell.-.ea.a Asbestos □ -----pC!/.', -----pCI/.' ------pC!/L ______ pCI/L ________ x. Chlorophyll ■ □ , ______ Pl>b ______ SI Carros i vi ty □ Oi ■aolved Oxygen □ ------Fonnaldehyoe □ --------· □ --------□ --------□ --------□ -------- Carbonate □ -Ph ... l a - Chloride □ -Surfactant □ - Chlodne, RHidual O _____ _ ~ Orpnjq Color □ ----------111it■ Acid Heriltcide O Report attac:tled Cyanide, Total O _______ _ -Organic Acid D _______ -· Fluoride O _________ _ -PCB O R-t lttoclled H■ra.s• □, __________ _ -Pesticide □ R-t •tt- Nttr09en, Aa:monia O, ______ _ -. Seaivolatile O Report ■ttactaed :1~~1,:n, Nttr~t• • -------Nttr09en, Nitrate □, ______ _ Nitrogen, Nitrite □, ______ _ Nitrogen, To 0 tal ljoldahl , ________ _ TPN □ ,---------- V0C D"a_,t lttaclled Njnerg\ !!!Silt A.l D ca C -l'ID -l'ID ~ □---------co D -l'ID Phosphorus, ortho O, ______ _ cu D -l'ID Phoap\onm, Total □, ______ _ ,. a --Phosphorus, Total D!&a0lved □ _______ - Residue, Filterable □, ______ - Rntdua, c,mr ded □, _______ - Residue, Total O _______ - Specific □ ________ Ull'lo/cm Conductance "9 a ""a ' D SID Na □ Sn a -----Pl"' -l'ID ----Sul fate O __________ _ -zn C --Sulfide □, __________ _ -C -Pl"' Turbidity □ ________ _ lfTU Toxjc Metal! TCl.P Jletala 0 Sb □ ___ _ Pl"' -All FJEL.D DATA "-'ST BE REa:ltDED T0 MIIITAllf CHAU OF OJSTa)T Al □----Pl"' -a.c ___ _ Pl"' -I A.emerli:.s: ___________________________ _ B•□---- Cd □ ___ _ Pl"' -Pl"' - I I Dau Comoleted: ________________________ _ I Laboratory Director: I ·.··r ".!" ..•• ..,1 era ___ _ Pb □ ___ _ Hg □---­ NI □---­ S•□---- Ag □ ___ _ TLC ___ _ Pl"' -Pl"' -Pl"' -Pl"' -Pl"' -ppb --P!'b ~ Pl"' - I I I I I I I I I I I I I I I I I MECKLENBURG COUNTY DEPARTMENT OF' ENVIRONMENTAL PROTECTION ENVIRONMENTAL LABORATORY Project: Site Sampled: Field I.D.#: Lab I.D.#: Date sampled: ztfz i ' Sample Matrix: Water Volatile Organics Sample Detection Organics-Volatiles Results Limits Method Parameter ( ug/ 1) (ug/1) Acetone < 100 100 8240B ( f) , 524.1 ( i) , Acrolein < 100 100 8240B (fl , 524.1 ( i) , Acrvlonitrile < 100 100 8240B ( f) , 524.1 ( i l , Benzene < 5 5 8240B ( f) , 524.1 ( i) , Bromodichloromethane < 5 5 82408 ( f) , 524.1 ( i) , Bromoform < 5 5 8240B ( f) , 524.1 ( i) , 2-Butanone < 100 100 8240B ( f) , 524.1 ( i) , carbon Disulfide < 5 5 8240B ( f) , 524.1 ( i) , Carbon Tetrachloride < 5 5 8240B ( f) , 524.1 ( i) , Chlorobenzene < 5 5 8240B (fl, 524.1 Ii), ·chloroform < 5 5 8240B ( f) , 524.1 !il, Chlorodibromomethane < 5 5 8240B ( f) , 524.1 (i), Chloroethane < 10 10 8240B ( f) , 524.1 ( i) , 2-Chloroethyl Vinyl Ether < 10 10 82408 ( f) , 524.1 ( i) , 1,2-Dichlorobenzene < 5 5 8240B ( f) , 524.1 ( i) , 1,3-0ichlorobenzene < 5 5 8240B ( f) , 524.1 ( i) , 1,4-Dichlorobenz~ne < 5 5 8240B ( f) , 524.1 ( i) , 1,1-Dichloroethane < 5 5 8240B ( f) , 524.1 (i), 1,2-Dichloroethane < 5 5 8240B ( f) , 524.1 (i), 1,1-Dichloroethylene < 5 5 8240B ( f) , 524.1 ( i) , cis-1,2-Dichlorethene < 5 5 8240B ( f) , 524.1 ( i) , trans-1,2-Dichloroethene < 5 5 8240B ( f) , 524.1 ( i) , 1,2-Dichloropropane < 5 5 8240B ( f) , 524.1 ( i) , cis-1,3-Dichloropropene < 5 5 8240B ( f), 524.1 ( i) , trans-1,3-Dichloropropene < 5 5 8240B ( f) , 524.1 ( i) , •Ethvlbenzene < 5 5 8240B ( f) , 524.1 Cil, 2-Hexanone < 50 50 8240B ( f) , 524.1 (i), 4-Methyl-2-Pentanone < 50 so 8240B ( f) , 524.1 ( i) , Methyl Bromide < 10 10 8240B ( f ) , 524.1 ( i) , Methyl Chloride < 10 10 8240B ( f) , 524.1 ( i) , 624 (g) 624 (al 624 (al 624 (g) 624 (g) 624 (g) 624 (g) 624 (g) 624 (g) 624 (al 624 (al 624 (g) 624 (g) 624 (g) 624 (g) 624 (g) 624 (g) 624 Io\ 624 (al 624 (g) 624 (g) 624 (g) 624 (g) 624 (g) 624 (g) 624 ( al 624 (al 624 ( g) 624 (g) 624 (g) (f) Test Methods for Evaluating Solid Waste, Physical/Chemical Methods, SW 846 (g) 40 CFR, part 136 (i) Methods for the Determination of organic Compounds (EPA 1988) I I I I I I I I I I I I I I I I I MECKLENBURG COUNTY DEPAIU'MENT OF ENVIRONMENTAL PROTECTION ENVIROHMEIITAL LABORATORY Project: Site Sampled: Field I.D.#: Lab I.D.#: Date ·sampled: /9V Sample Matrix: Water Volatile OrganicS,con,1 Sample Detection organics-Volatiles Results Limits Method Parameter (uer/1) (uer/1) Methylene Chloride < 5 5 8240B ( f) , 524.1 ( i) , MTBE < 5 5 8240B ( f) , 524.l ( i), Styrene < 5 5 8240B ( f) , 524.1 ( i), 1,1,2,2 Tetrachlorcethane < 5 5 8240B ( f) , 524.1 ( i) , Tetrachloroethylene < 5 5 8240B ( f) , 524.1 ( i), Toluene < 5 5 8240B ( f) , 524.1 ( i) , 1,1,1-Trichloroethane < 5 5 8240B (fl , 524.1 (ii, 1,1,2-Trichloroethane < 5 5 8240B ( f) , 524.1 'i) , Trichloroethvlene < 5 5 8240B ·( f \ , 524.1 : .:.. \ , Trichlorofluoromethane < 10 10 8240B ( f) , 524.1 ( i) , Vinyl Acetate < 50 50 8240B ( f) , 524.1 ( i) , Vinyl Chloride < 10 10 8240B ( f) , 524.l :' i) , Xylenea (total) < 5 5 8240B ( f) , 524.1 ( i) , 624 (er' 624 (g) 624 (gl 624 (n) 624 ( g) 624 (g) 624 ,-, 624 <er\ 624 (al 624 (g) 624 (g) 624 (g) 624 (g) (f) Teat Methods for Evaluating Solid Waste, Physical/Chemical Methods, SW 846 (g) 40 CFR, part 136 (i) Methods for the Determination of Organic Compounds (EPA 1988) I ·,. ~ECK\~!~R~ ~OUNTY ENVIRONMENTAL PROTECTION LABORATORY , ,.,Ji .D.•: ---·-·-• ---•--• ,_ Dept.: /1 )(J Lab 1.0. ,, 1H I t . S.,,.,led: t (Y\ . mo H ~ ress: 1400£ A'!hemar:le -Road, f ::nu Ht Project: .... fb ....... r?-L~P.~es __ iW_{).,_G_- 0el ivered to Lab On: Rec'd By: 01u Rec'd: Ti•: () A) ..eoJl JUN 1 1995 _I_J_,_t [ __ ~-t ree S~led: ~led By: Dau: oj:f.f 9 S-Time: //•'3o ~ Delivered By: K .5ta.t:~ I I I Olmical rr:-??!itian• lnorvanic □ __________ x. __________ x __________ x Or-ganic □ Moisture 0 Radioactivirt Air Gros~ i.lph■ □ -----r,:.11-.r Grosa Beta □ -----r,:.11-.r Water lnoCP!ic Man Net■t! A990'9!tl Organje Acidity O _______ -Boo,o. ___________ ppa Alkalinity □____ -CCX) □, __________ - Bicarbonate C _________ -Oil and GrHae 0. ______ ppa Carbonate O Pl=8 Phonal □----------ppa Chloride □ -SurfactantO. ________ ppa Chlo1"ine, Residual O pf:D Orpnjfl Color O 111it■ Acid Hortlicide □ a_,t attacllod Cyanide, Total a _______ _ 01'"9anic Actd O _______ - Fluoride O _________ _ PCB o a_,t attacllod Groaa Alpha 0 ______ fi:.I/L ______ fi:.I/L Haraina □-----------Pf:111 Pesticide O Report attached I I I I I Gross Beu □ Ni see l l M"leOl.a Asbestos □ _________ x. Chloropt1yll a 0 . ______ ppb _______ s1 Carros i vi ty □ Dissolved Oxygen □ -------Fonaaldehyoe □ --------a -------□ --------□ --------a -------- Nttrogffl, Ammni ■ □, ______ _ Nitrogen, Nitrate+· Nitrite □ Nltro9en, Nitrate □, ______ _ Nitrog-,, Nitrite □, ______ _ Nitrogen, Total ljeldahl □, _________ - pN □----------t.nha Phoaphorus, Ortho □------­ Phosphorus, Total □------­ Phoapharus, Tot0al Dlaaol-_______ ppa Rnicu,, Filterable □------ppa RestCUI, Sirq .ded □------- Residue, Total □ _______ - Specific □ ________ i.m'lo/cm Conductance Sulfate O __________ _ -· Sulfide □------------ seaivolatt le □ Report 1ttac:Md TPM O __________ _ VOC ~Rl!>Ort attached Ntnent Net■t1 Al C -ppb Ca 0 -ppb Co 0 -ppb cu a -ppb fo a -ppb Mg 0 -ppb Mn 0 -ppb l a -ppb SI 0 -ppb No 0 -ppb Sn 0 -ppb zn o -ppb 0 -ppb I Turbidity O ________ _ NTU Toxfc Met■l• I IIOTE: All FIELD DATA IC.IST BE REamJED TO N.AIIITAIII CHAii OF CJSTCJJ'f TCLP Metala □ SbO ___ _ Aa a ___ _ ppb -ppb -I Renarks: ___________________________ _ Bao ___ _ BeO ___ _ Cd □ ___ _ ppb -ppb -ppb -Cr □----ppb -Pb □ ___ _ ppb -Hg □ ___ _ ppb -I Cate Con:olated: JUN 2 7 1995 Ni □---- So0 ___ _ AgO ___ _ ppb -ppb -ppb -1 · Laboratory Director: Tl □ ___ _ □--- ~ ppa ppb -....... : ..... -: ~ ,•• L" ,;:'-•'-l I I I I I I I I I I I I I I I n D I MECKLENBURG COUNTY DEPARTMENT OF ENVIRONMENTAL PROTECTION ENVIRONMENTAL LABORATORY Project: Field I.D.#: Site Sampled: Lab I.D.#: Date Sampled: 1(1/1 Sample Matrix: Water Volatile Organics Sample Detection Organics-Volatiles Results Limits Method Parameter (ug/1) (ug/1) Acetone < 100 100 8240B ( f) , 524.1 ( i) , Acrolein < 100 100 8240B I fl, 524.1 ( i) , Acrylonitrile < 100 100 8240B ( f) , 524.1 ( i) , Benzene < 5 5 8240B ( f) , 524.1 ( i) , Bromodichloromethane < 5 5 8240B ( f) ' 524.1 ( i) , Bromoform < 5 5 8240B ( f) , 524.1 ( i), 2-Butanone < 100 100 8240B ( f) , 524.1 ( i) , Carbon Disulfide' < 5 5 B240B ( f) , 524.1 ( i) , Carbon Tetrachloride < 5 5 8240B ( f) , 524.1 ( i) , Chlorobenzene < 5 5 8240B I fl, 524.1 (i), Chloroform < 5 5 8240B ( f) , 524.1 (i), Chlorodibromomethane < 5 5 8240B ( f) , 524.l ( i) , Chloroethane < 10 10 8240B ( f) , 524.1 ( i) , 2-Chloroethyl Vinyl Ether < 10 10 8240B ( f) , 524.1 ( i) , ' 1,2-Dichlorobenzene < 5 5 8240B ( f) , 524.1 ( i) ' 1,3-Dichlorobenzene < 5 5 8240B ( f) ' 524.1 ( i) , 1,4-Dichlorobenzene < 5 5 8240B ( f) , 524.1 ( i), 1,1-Dichloroethane < 5 5 8240B ( f) , 524.1 ( i l , 1,2-Dichloroethane < 5 5 8240B ( f) ' 524.1 ( i), 1,1-Dichloroethylene < 5 s 8240B ( f) , 524.1 ( i) , cis-·1, 2-Dichlorethene < s 5 8240B ( f) , 524.1 ( i) , trans-1,2-DichlorOethene < s 5 8240B ( f) , 524.1 ( i) ' 1,2-Dichloropropane < 5 s 8240B ( f) ' 524.1 (i), cis-1,3-Dichloropropene < s 5 8240B ( f) , 524.1 ( i) ' trans-1,3-Dichloropropene < 5 5 8240B ( f) ' 524.1 ( i) , Ethvlbenzene < 5 5 8240B ( f) , 524.1 (i), 2-Hexanone < 50 50 8240B ( f ) , 524.1 ( i l, 4-Methyl-2-Pentanone < so 50 8240B ( f) , 524.1 ( i) , Methyl Bromide < 10 10 8240B ( f) , 524.1 ( i) , Methyl Chloride < 10 10 8240B ( f) ' 524.1 ( i) , 624 (g) 624 lal 624 /al 624 (g) 624 (g) 624 (g) 624 (g) 624 (g) 624 (g) 624 (q) 624 /al 624 (g) 624 (g) 624 (g) 624 (a) 624 (g) 624 (g) 624 (al 624 (q) 624 ( g) 624 (g) 624 (g) 624 (g) 624 (g) 624 (g) 624 (al 624 /al 624 (g) 624 (q) 624 (g) (f) Test Methods for Evaluating Solid Waste, Physical/Chemical Methods, SW 846 (g) 40 CFR, part 136 (i) Methods for the Determination of Organic Compounds (EPA 1988) I I I I I I I I I I I I I I I I MECKLENBURG COUNTY DEPARTMENT OF ENVIRONMENTAL PROTECTION ENVIRONMENTAL LABORATORY Project: Site Sampled: Field I.D.#: Lab I.D.#: Date Sampled: IC'{/ I Sample Matrix: Water Volatile OrganicS,con,1 Sample Detection Organics-Volatiles Results Limits Method Parameter (uq/1) (ug/1) Methylene Chloride < 5 5 8240B ( f) • 524.1 ( i) • MTBE < 5 5 8240B ( f). 524.1 ( i). Styrene < 5 5 8240B ( f) , 524.1 ( i}, 1,1,2,2 Tetrachloroethane < 5 5 8240B ( f) • 524.1 ( i) , Tetrachloroethylene < 5 5 8240B ( f) • 524.1 ( i) , Toluene < 5 5 8240B ( f) , 524.1 ( i}, 1,1,1-Trichloroethane < 5 5 8240B ( f} , 524.1 ·Ci l , 1,1,2-Trichloroethane < 5 5 8240B ( f) , 524.1 lil, Trichloroethvlene < 5 5 8240B ( f) • 524.l ( i} ' Trichlorofluoromethane < 10 10 8240B ( f} , 524.l ( i} , Vinyl Acetate < so so 8240B ( f} ' 524.1 ( i) ' Vinyl Chloride < 10 10 8240B ( f) • 524.1 ( i} , Xylenes (total} < 5 5 8240B ( f} , 524.1 ( i) , 624 (g) 624 (g) 624 (g) 624 (g) 624 (g) 624 (g) 624 (g) 624 (q) 624 (q) 624 (q) 624 (q) 624 ( q) 624 (g) (f) Test Methods for Evaluating Solid Waste, Physical/Chemical Methods, SW 846 (g) 40 CFR, part 136 (i) Methods for the Determination of Organic Compounds (EPA 1988) '•ld,; :.(,,--..MEC::L~N~~:~~ COUNTY DE:~:RON~~$;L PROTECTION LABO~~ ~~D~:: Project: IYIIL 8errrm8e, Re-c'd By: t e S...,led: 1/f(fn Hr!drefh r ... , 11 ;10B roo/e, l{evd t r;e SatTl>led: led By: r· f 7Z!jJ}f I I I I I I I D I I te SMEiled: Oleaical rs-:r-ition Inorganic a __________ %. __________ % _________ x Or-genie □ Jlloi&ture 0 Radi oactivi !:i Ah- Grosl'-Alpha O Gross Beta a Water Groaa Alpha a Gross Beta a Ni~llSleOUS Asbestos a ------pCl/a' -----pCI/,., ______ pCt/L ______ pCt/L ________ x Chlorop'lyll a 0 . ______ F¢ _______ SI Carros i vi ty a Dissolved Oxygen 0 ------Fonaoldehyde 0 --------a -------a --------a --------a ------- Delivered to Lab On: Ti•: _1'-'S-:;....:;"2--_0_~. Doto: .~/tS/95~ Tiaw: 2-: 35" ~ Delivered e/ ( SQ;)f',M Jmr:,anic Man Netats As,cnate oCPlie Acidity O ·-----•----·---aoo,o, ___________ pi,a Alkalinity O ______ _ -CCII O -Bicarbonate C _________ PJ11 Oil and Graue a. ______ - C.rl>onllte O -Phenol □, _________ - Chloride D PJ11 surtacurn:: □, ________ - Chlodne, Residual a ~ Or,pnjg Color O '-'lits Acid Herbicide O Report auadled Cyanide, Total O PfSI Org.,ic Acid O _______ - Fluoride .□ -PCS O Report lttodled Han:hna O ppa, Pesticide O Report attached Nitr09en1 AmDania □. ______ _ -· Seaivolatile O Report attached Nitrogen, Nitrate• Nitrite □ TPH O __________ pi,a Nltro;en, Nitrate □. ______ _ Nltrogw,, Nitrogen, , Kjoldahl Nitrite 0. ______ _ voe Ir 1_,, attodled Nfnerp\ '!!tilt To~al ----------111ita ~ □--------- Al □----C.0 ___ _ coo ___ _ Phoa~orus, ortho o. ______ _ -cuo ___ _ Ph~arus, Total O, ______ _ Pl'■ Fo □ ___ _ Phosphorus, Total Dlaaolwd □ - RHic:ia, Filterable □. ______ Pl'■ Ania.», c:,n:~1 died □. _______ - Rnidue,. Total O _______ - Specific O ________ I.JZilO/CII concu: tance "90 ___ _ Mn □ ___ _ K □----SIO ___ _ No □ ____ _ Sn □ ___ _ s,ulfate a __________ _ -Zn □ ___ _ sul ttc1o a ·-----------□----Turbidity O ________ _ NTU Toxjc !'!SI\I TCL.9 Metala 0 Sb □ ___ _ ------------- Fl!'b ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb I'll■ lil'.JTE: All FJELD DATA flJST BE RECCRDED TO MAINTAIN CHAii OF aJS'l'lXtf Aa □ ___ _ Fl!'b I'll■ a.a ___ _ Fl!'b -Bo □ ___ _ Fl!'b -Cd □ ___ _ -I'll■ I Cr □---- Pb □ ___ _ Hg □---- Fl!'b I'll■ Fl!'b -Fl!'b - I I Laboratory O_.i rector: La::crato:r' C< NI □----1 ~□---- Oate Conmleted: -----------''-'------,-....J.-------Ag □ ___ _ _____ {J.;:.·~_/_·~_, ~_.,_~_·._·•_I_'_· .. _fL ____ ~ \9:,9);1 □□-=-==== s~~ Fl!'b -Fl!'b -Fl!'b -· PP' ppa Fl!'b I'll■ I I I I I I I I I I I I I I I I I I MECKLENBURG COUNTY DEPARTMENT OF ENVIRONMENTAL PROTECTION ENVIRONMENTAL LABORATORY Project: Field I.D.#: Lab I.D. #: Site Sampled: Date Sampled: Sample Matrix: Water Volatile Organics Sample Detection Organics-Volatiles Results Limits Method Parameter (ug/1) (ug/1) Acetone < 100 100 8240B ( f) ' 524.1 ( i)' Acrolein < 100 100 8240B ( f) ' 524. 1 < i) , Acrvlonitrile < 100 100 8240B ( f)' 524.1 ( i) ' Benzene < 5 5 8240B ( f) ' 524.1 ( i) ' Brornodichloromethane < 5 5 8240B ( f) ' 524.1 ( i) ' Bromoform < 5 5 8240B ( f) ' 524.1 ( i) ' 2-Butanone < 100 100 8240B ( f) ' 524.1 ( i) ' Carbon Disulfide < 5 5 8240B ( f) ' 524.1 ( i) ' Carbon Tetrachloride < 5 5 8240B ( f) ' 524.1 ( i) ' Chlorobenzene < 5 5 8240B ( f) , 524.1 ( i I , Chloroform < 5 5 8240B ( f) ' 524.1 ( i) ' Chlorodibromomethane < 5 5 8240B ( f) ' 524.1 ( i) ' Chloroethane < 10 10 8240B ( f) ' 524.1 ( i) ' 2-Chloroethyl Vinyl Ether < 10 10 8240B ( f) ' 524.1 ( i) ' 1,2-Dichlorobenzene < 5 5 8240B ( f) ' 524.1 ( i) ' 1,3-Dichlorobenzene < 5 5 8240B ( f) ' 524.1 ( i) ' 1,4-Dichlorobenzene < 5 5 8240B ( f) ' 524.1 ( i) ' 1,1-Dichloroethane < 5 5 8240B ( f) ' 524.1 ( i) ' 1,2-Dichloroetharie < 5 5 8240B ( f) ' 524.1 (i), 1,1-Dichloroethy~ene < 5 5 8240B ( f) ' 524.1 ( i) ' cis-1,2-Dichlorethene < 5 5 8240B ( f) ' 524 .1 ( i) ' trans-1,2-Dichloroethene < 5 5 8240B ( f) ' 524.1 ( i)' 1,2-Dichloropropane < 5 5 8240B ( f)' 524.1 ( i) ' cis-1,3-Dichloropropene < 5 5 8240B ( f) ' 524.1 ( i) ' trans-1,3-DichlorOpropene < 5 5 8240B ( f) ' 524.1 ( i) ' Ethylbenzene < 5 5 8240B ( f) ' 524.1 ( i) ' 2-Hexanone < so 50 8240B ( f) ' 524.1 ( i) ' 4-Methyl-2-Pentanone < 50 50 8240B ( f) ' 524.1 ( i)' Methyl Bromide < 10 10 8240B ( f) ' 524.1 ( i) ' Methyl Chloride < 10 10 8240B ( f) ' 524.1 ( i) ' 624 (g) 624 <a) 624 <al 624 (g) 624 (g) 624 (g) 624 (g) 624 (g) 624 (g) 624 (a\ 624 (al 624 (g) 624 (g) 624 ( g) 624 (g) 624 ( g) 624 ( g) 624 ( q) 624 (g) 624 (g) 624 (g) 624 (g) 624 (g) 624 (g) 624 (g) 624 (al 624 !al 624 (g) 624 ( g) 624 (g) (f) Test Methods for Evaluating Solid waste, Physical/Chemical Methods, SW 846 (g) 40 CFR, part 136 (i) Methods for the Determination of Organic Compounds (EPA 1988) I I I I I I I I I I I I I I I I I D u MECKLENBURG COUNTY DEPARTMENT OF ENVIRONMENTAL PROTECTION ENVIRONMENTAL LABORATORY Project: Field I.D.#: Lab I.D.#: Site Sampled: Date Sampled: Sample Matrix: ~ Volatile OrganicS,ccn,1 sample Detection Organica-Volat~les Results Limits Method Parameter (uq/1) (uq/1) Methylene Chloride < 5 5 8240B ( f) ' 524.1 ( i) ' MTBE < 5 5 8240B ( f) ' 524.1 ( i) ' Styrene < 5 5 8240B ( f) ' 524.1 ( i) ' 1,1,2,2 Tetrachloroethane < 5 5 8240B ( f) ' 524.1 ( i) ' Tetrachloroethylene < 5 5 8240B ( f)' 524.1 ( i) ' Toluene < 5 5 8240B ( f) ' 524.1 ( i) ' 1,1,1-Trichloroethane < 5 5 8240B ( f) ' 524.l ( i l , 1,1,2-Trichloroethane < 5 5 8240B ( f) ' 524.1 ( i \' Trichloroethylene < 5 5 8240B ( f) ' 524.1 ( i) ' Trichlorofluorcmethane < 10 10 8240B ( f) ' 524.1 ( i) ' Vinyl Acetate < so so 8240B ( f) ' 524.1 ( i) ' Vinyl Chloride < 10 10 8240B ( f) ' 524.1 ( i) ' Xylenes (total) < 5 5 8240B ( f) ' 524.1 ( i) ' 624 ( g) 624 (q) 624 (0) 624 (g) 624 ( g) 624 ( g) 624 ( q) 624 (q) 624 (Ol 624 (g) 624 (g) 624 ( g) 624 ( g) (f) Test Methods for Evaluating Solid Waste, Physical/Chemical Methods, SW 846 (g) 40 CFR, part 136 (i) Methods for the Determination of Organic Compounds (EPA 1988) I ✓ •. ;J ~~C~,L~~~RG COUNTY ENVIRONMENTAL PROTECTION LABORATORY ;•ld l.t.l: ~ . .,., ... "I 0Ol)t.: II )Q Lab I.D. ,, I; u S_,led: P4Jfl} f'fll /// ,1,_J Project: (fj/J{ ff{}IJfr}f!.f, ddress: /l4al.f-tobf..e 8toA Rec'd By: Dau Rec'd: './loJJl..Qt Delivered to Lab On: Tim: lource San'C)led: _,led By: Date: slejqt[ Tl .. : ,2: SS-~ I 'SJ_ 0el ivered By: 11~~/f',rl) Oleaical cs-n,itian I nor;:ga,i c Nan Met■h Asscnate 0rpaniq 1Y79 Inorganic □ ________ % _________ % __________ % Acidity □ ·-----·----·--ppa BCO, □. ___________ ppo I I I I I I I I I Or-ganic 0 Alkalinity □____ ppa CCCI □•----'-------- Moiilture 0 Bicarbonate C _________ ppa Oil and Grana □, ______ - lladioactivitf Air Cari>onatc □ __________ PPI Phanol □. _________ - Clllortda O ppa Surfactant O - Ciroar •lph■ 0 Gros■ Set■ □ -----pCl/a' -----pCl/a' Chlodne, Residual O _____ _ Color 0 Cyanida, Total O _______ _ PP11 Ot:9P!jq __________ la"lit■ Acid HerDlclde O Report at1:ac:hed -orv.,ic Acid a _______ - \later Fluoride. a _________ _ ppa PCB O Report attached Groaa AlJ:i,■ □ ______ pCI/L H■rchtsa □, __________ _ -Pesttctda O Report attached Groa■ Beta □ _______ pCI/L · Nltr011en, _._,ia □, ______ _ -seaivolati le a Report attached Miscellanea.a Nitrogen, Nitrat• • Nitrite □ _______ _ Asbntoa □ _________ X Nltro,aen, Nitrate 0, ______ _ Chlorophyll a □ Corroaivity □ ______ Pf'b _______ SI Diaaolved Cxwen a -------Fora,ldel,yae □ --------□ --------□ --------□ --------□ ------- Nitrogen, Nitrite □, ______ _ Nitrogen, To0tal Kjaldahl , ________ _ -1.nita pH □---------Phosphorus, Ortho □, ______ _ Phoaptlana, Total □. ______ _ Phoaphorus, Tot0al 0tuolvod _______ PPI Residue, Filterable O. ______ ppo Rnta.ae, Suspanded O,______ ppa Residue, Total a _______ ppa Spectf;c □ ________ UW'lo/m Conductance Sulfate a __________ _ -Sulfide □, _________ _ -Turbidity O ________ _ NT\J ALL FIELD DATA ICUff BE REcarDED TO ICAIVTAIM CHAIM OF ar.mDf TPH O .-----------voe t' R-.:,ort attached Mhaa& Net•l1 Al 0 ca a Co 0 cu a Fe 0 1111 a ""a K a St 0 Na 0 Sn a Zn a a Tazfc Neta\1 TCLP Matall 0 SbO ___ _ A10 ___ _ ---Pf'b --------------Fl"' -PP" ---pp, - Pf'b ---II Aemarits: ---------------------------- e.a ___ _ a.a ___ _ CdO ___ _ ------Cr □------PbO ___ _ --HgO ___ _ --Ni □------I Oate c...,leted: -----=='--::=--------------- Sa □----Ag0 ___ _ Pf'b -Pf'b -1 · Lalx>ratory o irector: TlO ___ _ \~~~ a __ fl'I> ppa ppb - I I I I I I I I I I I I I I I I I I I I MECKLENBURG COUNTY DEPARTMENT OF ENVIRONMENTAL PROTECTION ENVIRONMENTAL LABORATORY Project: Site Sampled: Field I.D.#: Lab I.D.#: Date Sampled: L9tJ' Sample Matrix: Water Volatile Organics Sample Detection Organics-Volatiles Results Limits Method Parameter (ug/1) (ug/1) Acetone < 100 100 8240B ( f) , 524.1 ( i) , Acrolein < 100 100 8240B ( f) ' 524. 1 ( i \ ' Acrylonitrile < 100 100 8240B ( f \ ' 524.1 ( i) ' Benzene < 5 5 8240B ( f) , 524.1 (i), Bromodichloromethane < 5 5 8240B ( f) ' 524.l ( i) ' Bromoform < 5 5 8240B ( f) ' 524.1 ( i) , 2-Butanone < 100 100 8240B ( f) , 524.1 ( i), Carbon Disulfide < 5 5 8240B ( f) , 524.1 ( i) , Carbon Tetrachloride < 5 5 8240B ( f) ' 524.1 ( i) ' Chlorobenzene < 5 5 8240B ( f) , 524.l ( i \ , Chloroform < 5 5 8240B ( f) ' 524.1 ( i) ' Chlorodibromomethane < 5 5 8240B ( f) , 524.1 ( i) , Chloroethane < 10 10 8240B ( f) ' 524.1 ( i) , 2-Chloroethyl Vinyl Ether < 10 10 8240B ( f) ' 524.1 ( i) ' 1,2-Dichlorobenzene < 5 5 8240B ( f) , 524.1 ( i) ' 1,3-Dichlorobenzene < 5 5 8240B ( f) ' 524.1 ( i), 1,4-Dichlorobenzene < 5 5 8240B ( f) ' 524.l ( i) , l,l-Dichloroethane < 5 5 8240B ( f) ' 524.l ( i \ ' 1,2-Dichloroethane < 5 5 8240B ( f)' 524.1 (i), 1,1-Dichloroethylene < 5 5 8240B ( f) ' 524.1 (i)' . cis-1,2-Dichlorethene < 5 5 8240B ( f)' 524.l ( i) , trans-1,2-Dichloroethene < 5 5 8240B ( f) ' 524.1 ( i) ' 1,2-Dichloropropane < 5 5 8240B ( f) ' 524.1 (i), cis-1,3-Dichloropropene < 5 5 8240B ( f) ' 524.l ( i) ' trans-1,3-Dichloropropene < 5 5 8240B ( f) ' 524.l ( i) ' Ethvlbenzene < 5 5 8240B ( f) ' 524.l ( i) ' 2-Hexanone < 50 50 8240B ( f)' 524.l ( i) ' 4-Methyl-2-Pentanone < 50 50 8240B ( f) ' 524.1 ( i) ' Methyl Bromide < 10 10 8240B ( f)' 524.l ( i) ' Methyl Chloride < 10 10 8240B ( f) ' 524.1 ( i) , 624 (g) 624 (er) 624 (q\ 624 (g) 624 (g) 624 ( g) 624 (g) 624 ( g) 624 (g) 624 I al 624 101 624 (q) 624 ( g) 624 (g) 624 ( g) 624 ( g) 624 ( g) 624 ( g) 624 lo\ 624 ( g) 624 (g) 624 (g) 624 (g) 624 ( g) 624 (g) 624 (q) 624 (q\ 624 (g) 624 (g) 624 (g) (f) Test Methods for Evaluating Solid waste, Physical/Chemical Methods, SW 846 (g) 40 CFR, part 136 (i) Methods for the Determination of Organic Compounds (EPA 1988) I I I I I I I I I I I I I I I I MECKLENBURG COUNTY DEPARTMENT OF ENVIRONMENTAL PROTECTION ENVIRONMENTAL LABORATORY Project: Field I.D.#: Lab I. D. #: Site Sampled: Date Sampled: Sample Matrix: ~ Volatile OrganicSt=n<I Sample Detection Organics-Volatiles Results Limits Method Parameter (uo/1) ( ua /1) Methylene Chloride < 5 5 8240B ( f) ' 524.1 ( i) ' MTBE < 5 5 8240B ( f) ' 524.1 ( i)' Styrene < 5 5 8240B ( f) ' 524.1 ( i)' 1,1,2,2 Tetrachloroethane < 5 5 8240B ( f) ' 524.1 ( i) ' Tetrachloroethylene < 5 5 8240B (fl , 524.1 ( i) ' Toluene < 5 ·s 8240B ( f)' 524.1 ( i) , 1,1,1-Trichloroethane < 5 5 8240B (fl , 524.1 · ( i l , 1,1,2-Trichloroethane < 5 5 8240B ( f)' 524.1 ( i) , Trichloroethvlene < 5 5 8240B ( f) , 524.1 ( i) ~ Trichlorofluoromethane < 10 10 8240B ( f) , 524.1 ( i) ' Vinyl Acetate < so so 8240B ( f) , 524. 1 ( i) , Vinyl Chloride < 10 10 8240B ( f) , 524.1 ; i) , Xylenes (total) < 5 5 8240B ( f) , 524.l ( i) , 624 (g) 624 (g) 624 (g) 624 (g) 624 ( g) 624 ( g) 624 lo) 624 ( q) 624 ( g) 624 (g) 624 (g) 624 ( g) 624 (g) ( f) Test Methods for Evaluat_ing Solid Waste, Physical/Chemical Methods, SW 846 (g) 40 CFR, part 136 (i) Methods for the Determination of Organic compounds (EPA.1988) .. /3''l-/.3d-C'/ I . / MECKLENBURG COUNTY ENVIRONMENTAL PROTECTION LABORATORY Field 1.0,#: Lab 1.0. f: fr(O Project: A.ec'd By: ()N _;_::e I,. sanoted: /'}, Ive -- ''"'ress: /5/55 IJ/)tHJ(tr/e,, f?,£ Date Rec'd: JUN 1 1995 t ree s.,..,led: -fatµ'..,_.ef""'------- .,..,,ed By: I{ S&i-1?.M.J Delivered to lab On: Dau: .¢/1! 11,., //,-:7<' ~ Ire s....,led: 6/{( 1/5 ri-= 1::§L ~ Del lvered By: ![ @f/ftD · , . 0,'9ical cs-n-ition 1no,.,.,ic Mon Net■ts A99cn,te Or;:pnjq I I I I I I I I I I Inorganic □ __________ %. Acidity O -----------·--BCCI, □. __________ - Organic 0 __________ %. _________ %. Moii,ture 0 Radioactivin'. Air Grose' Al P"I• □ Gros■ Bet■ □ 'I.later Groaa Alr;:i,■ 0 Gross Bet ■ □ N f see l l m"ll!OUII Asbestos □ _____ pCltri' -------pCl/ri' ______ pCI/L ______ pCI/L Chlorop,yl l • □ ________ %. ______ F¢ _______ SI Corro• i vi ty □ Di ■aolved Oxygen 0 ------Fonnaldehydt □ -------□ --------□ --------□ --------□ -------- Alkalinity □ ________ -CCCI □ - Blcarl>onat• C ----------Oil and Graue □ -ca.-,,uc □ __________ -Phanol □. ________ - C,lorlde □ -Surfactant □ - Chlodne, Resh:iual O ______ -Orp,jq Color O i.rii ti Acid Heo-blclde □ R-t attachc Cyanide, Tot■l □ ______ _ Organic Acid O _______ - Fluoride □ ________ _ PCB O Report attlldlad Hara>eH □----------Pesticide O Repor1: lttachod Nitrogen, AmtDnia □. ______ _ . S•ivol1ti le O Repw1: attached Nitrogen, Nitrate+ Nitrite O ______ _ Nhro9en, Nitrate □, ______ _ Nitrogen, Nitrite a. _____ _ Nitrogen, To0ul Kjeldahl , ________ _ - TPH □ ,-----------voe u('a-rt attadled Nfnenl !!!Sile Al 0 ___ _ caa ___ _ -F¢ --pit □---------..,ha Co 0 ------Phoap'lon,s, Ortho 0 ______ _ cua ___ _ --Phoap"lon.a, Total 0 ______ _ ,.c ___ _ --Phosphorus, Total Di ■aolv.d O A8 RniciJe, Filterable a. ______ - Rnlca,e, s...._-□. ______ - : Residue, Total O _______ - Specific O ________ ll!ilO/CII Ccnduc:iance M;O ___ _ MnO ___ _ K □----SI 0 ___ _ Na □ ___ _ Sn □ ___ _ ---F¢ -F¢ -F¢ -F¢ -F¢ Sul fate O _________ _ -Zn □ ___ _ --Sulfide □-----------□-----F¢ Turilldlty □ ________ _ NTU TOJ[jC lllet!l• TCLP Metal• □ Sb □ ___ _ F¢ -IIOTE: ALL FIELD DATA 9IJST BE REaJtDm rO NAIITAllf CHAIM OF CUSTmT A•□----F¢ - 11 liemark.s: ------------~------------- Ba □ ___ _ "Be □---- Cd □ ___ _ F¢ -F¢ -F¢ -D Cr □----PbO ___ _ H;□ ___ _ F¢ -pp, -F¢ -JUN 2 7 1995 NI □---- Se □ ___ _ F¢ -F¢ -A;□ ___ _ F¢ -1 · Laboratory Di rector: Tl □---- □---- ~ Pl- F¢ - I I I I I I I I I I I I I I I I I I I I MECKLENBURG COUNTY DEPARTMENT OF ENVIRONMENTAL PROTECTION ENVIRONMENTAL LABORATORY Project: Field I.D.;!: Lab I.D. #: /C(V Site Sampled: Date Sampled: Sample Matrix: ~ Volatile Organics Sample Detection Organics-Volatiles Results Limits Method Parameter (ug/1) (ug/1) Acetone < 100 100 8240B •(f), 524.1 ( i) ' Acrolein < 100 100 8240B (fl, 524.1 ( i l , Acrvlonitrile < 100 100 8240B ( f), 524.1 ( i) ' Benzene < 5 5 8240B ( f) , 524.1 ( i) , Bromodichloromethane < 5 5 8240B ( f) , 524.1 ( i) , Bromoform < 5 5 8240B ( f) , 524.1 ( i) ' 2-Butanone < 100 100 8240B ( f) , 524.1 ( i) , Carbon Disulfide < 5 5 8240B ( f), 524.1 ( i) , Carbon Tetrachloride < 5 5 8240B ( f) , 524.1 ( i), Chlorobenzene < 5 5 8240B < fl , 524.1 Ii l, Chloroform < 5 5 8240B I f) , 524.1 < i l , Chlorodibromomethane < 5 5 8240B ( f) , 524.1 { i) , Chloroethane < 10 10 8240B ( f) , 524.1 ( i) , 2-Chloroethyl Vinyl Ether < 10 10 8240B ( f) ' 524.1 ( i) , 1,2-Dichlorobenzene < 5 5 8240B ( f) , 524.1 ( i) , 1,3-Dichlcirobenzene < 5 5 8240B ( f) , 524.1 ( i) , 1,4-Dichlorobenzene < 5 5 8240B ( f) , 524.1 ( i) , 1,1-Dichloroethane < 5 5 8240B ( f) , 524.1 ( i l, 1,2-Dichloroethane < 5 5 8240B ( f) ' 524.1 I i) , 1,1-Dichloraethylene < 5 5 8240B ( f) , 524.1 ( i) ' cis-1,2-Dichlorethene < 5 5 8240B ( f) ' 524.1 ( i) , trans-1,2-Dichlorcethene < 5 5 8240B ( f) , 524.1 ( i) ' 1,2-Dichloropropane < 5 5 8240B ( f) ' 524.1 ( i) , cie-1,3-Dichloropropene < 5 5 8240B ( f) , 524.1 ( i) , trans-1,3-Dichloropropene < 5 5 8240B ( f) , 524.1 ( i) ' Ethvlbenzene < 5 5 8240B ( f) , 524.1 ( i l , 2-Hexanone < so 50 8240B ( f) ' 524.1 Ii l, 4-Methyl-2-Pentanone < so 50 8240B ( f) ' 524.1 ( i), Methyl Bromide < 10 10 8240B ( f) ' 524.1 ( i) ' Methyl Chloride < 10 10 8240B ( f) ' 524.1 ( i)' . 624 ( g) 624 (al 624 (q) 624 (g) 624 (g) 624 (g) 624 (g) 624 (g) 624 (g) 624 (al 624 (al 624 (g) 624 (g) 624 (g) 624 (g) 624 (g) 624 ( g) 624 (al 624 (al 624 (g) 624 (g) 624 (g) 624 (g) 624 (g) 624 ( g) 624 (g) 624 (al 624 (g) 624 (g) 624 (g) (f) Test Methods for Evaluating Solid Waste, Physical/Chemical Methods, SW 846 (g) 40 CFR, part 136 (i) Methods for the Determination of Organic Compounds (EPA 1988) I I I I I I I I I I I I I I MECKLENBURG COUNTY DEPARTMENT OF ENVIRONMENTAL PROTECTION ENVIRONMENTAL LABORATORY Project: Field I.D.#: Lab I.D.#: Site Sampled: Date Sampled: Sample Matrix: Water Volatile OrganicS,=nU Sample Detection Organics-Volatiles Results Limits Method Parameter tuo/1) (unil) Methylene Chloride < 5 5 8240B ( f) , 524.1 ( i) , MTBE < 5 5 8240B ( f), 524.1 ( i) ' Styrene < 5 5 8240B ( f) ' 524.1 ( i) ' 1,1,2,2 Tetrachloroethane < 5 5 8240B ( f) ' 524.1 ( i) ' Tetrachloroethylene < 5 5 8240B ( f), 524.1 ( i) ' Toluene < 5 5 8240B ( f) , 524.1 ( i) ' 1,1,1-Trichloroethane < 5 5 8240B ( f) ' 524.1 ( i l , 1,1,2-Trichloroethane < 5 5 8240B ( f) ' 524.1 ( i) ' Trichloroethvlene < 5 5 8240B ( f) ' 524.1 Ii l , Trichlorofluoromethane < 10 10 8240B ( f) ' 524.1 ( i) ' Vinyl Acetate < so 50 8240B ( f) , 524.1 ( i) ' Vinyl Chloride < 10 10 8240B ( f) ' 524.1 ( i) ' Xylenes (total) < 5 5 8240B ' ( f) , 524.1 ( i) ' 624 (g) 624 (g) 624 (g) 624 (q) 624 (g) 624 (g) 624 (q) 624 (al 624 IOI 624 (g) 624 (g) 624 (g) 624 ( g) (f) Test Methods for Evaluating Solid Waste, Physical/Chemical Methods, SW 846 (g) 40 CFR, part 136 (i) Methods for the Determination of Organic Compounds (EPA 1988) MECKLENBURG COUNTY ENVIRONMENTAL PROTECTION LABORATORY . .._ .. , ..... .::.....~.:. ..._., _.i._L:. :• Oept.: _ _./.eaLa:.)Q_;a·=''--· ------- I;,. •-led: Dq-1e llJJ\01.r odru,, l'S?DI {A) A:ltxrK-/H?lf. Project: t<d. IO<Jree •-led: '-~4J!sl.!.lt!.!Cwf _______ _ -led By: -I<· 5ft:Ufro<A Delivered to Lab On: Dato: 6/ / /C}<; Tl .. : ///Jp t< C'S tJJ,Li WA, J -•u S_,led: 6/ f / 9 ~ QI')/ ~ Ti•: ~ CFN { I 0el fvered By: lnonpnic Mm Net■b Inor;anic □ __________ % Acidity O ·-----•------I Organic □ X Moi■ture □ X -Blearbonau C _________ - Altai intty O _____ _ Radioaetivhy I Afr Gros&' Alpha O ______ pCl/a' Gron Bou O ______ pCt/a' I Water Carbonate a PPII Chloride O - Chlodne, Rnidual □ PP11 Color □ lllita Cyanide, Total O ______ _ Fluoride □ ________ _ Groaa Alpha □ ______ pCI/L ••-• a _________ _ Lab I .D. I: I f\/Z- Rec'd By: Date Rec'd: JUN J 1995 Tl•: Agga,ase 0CP'tiFI BaJ1 □, __________ - cai a - 0 II and Groue O - PhfflOl O - surfactant a ppa Or:,pnjg Acid Heri>lclde O Report attached Org.,ic Acid O _______ - PCB O R-rt attached I Crosa Bet■ a ______ pCI/L Nttr01en, Mm:lnil 0, ______ _ · Seaivolatfle O lepx-t attadled m JIii I see l l .-.e01.a Asbestos a ________ x Chlorophyll • 0 , ______ f'Pb ______ SI Corroaivi ty a Di ■aolved Oxygen O Nitrogen, Nitrate+ Nitrite O ______ _ Nitrog:en, Nftr■te □, ______ _ Nitrogen, Nitrite □, _____ _ 'Nitrogen, To 0 tal ljoldahl , ________ _ TPM O .-----------voe Ir' a_,., oetacnea Nfnenpl Metal! Al □---- Co □ ___ _ -ppb -f'Pb n Fol"llllldehydo a --------------pit O __________ ..-.tta Co O ___ _ -ppb a --------Phosphorus, Ortho □,_______ -Cu O ___ _ -a D a a ----------------------- Phosp'lorua, Tot:■l □, ______ _ Phosphorus, Total Dlsaolved C - RnlciJe, FIiterable □. ______ - Rnidue, ~•rsr M:ied □.______ PP" Residue, Taul O _______ - Specific □ ________ Ulilo/aa Conductance Sul fate O _________ _ -Sulfide □-----------Turbidity O ________ _ NTU ALL FIELD DATA lllJST BE RECXJmED TO KAJlfTAJN CHAii OF OJSTCl)T I A.emeries: _________________________ _ I I Fe □ ___ _ -Mva ___ _ -11na ___ _ -l □-----St □-----NaO ___ _ -Sn □ ___ _ -Zn □ ___ _ -a ___ _ -Toxic Net!ll TCLP Metal■ 0 Sb □ ___ _ A•□---- Ba □ ___ _ Boa ___ _ Cd □ ___ _ Cr □----PbO ___ _ ••□---­ Ni □----SeC ___ _ Ag □ ___ _ Tl □---­ □---- f'Pb f'Pb f'Pb f'Pb f'Pb f'Pb f'Pb f'Pb f'Pb f'Pb f'Pb Pl"' f'Pb ppb ppb f'Pb f'Pb ppb f'Pb ppb ppb ppb ppb -----------l'P' - I I I I I I I n D I I I I I I I I MECKLENBURG COUNTY DEPARTMENT OF ENVIRONMENTAL PROTECTION ENVIRONMENTAL LABORATORY Project: Field I.D.#: Lab I.D.#: , CCZ-- Site Sampled: Date Sampled: Sample Matrix: Water Volatile Organics Sample Detection Organics-Volatiles Results Limits Method Parameter (ug/1) (ug/1) Acetone < 100 100 8240B ( f) , 524.1 ( i) , Acrolein < 100 100 8240B (fl, 524.1 ( i \ , Acrvlonitrile < 100 100 8240B ( f) , 524.1 ( i l, Benzene < 5 5 8240B ( f) , 524.1 ( i) ' Bromodichloromethane < 5 5 8240B ( f) , 524.1 ( i) , Bromoform < 5 5 8240B ( f) , 524.1 ( i) , 2-Butanone < 100 100 8240B ( f) , 524.1 ( i) , Carbon Disulfide < 5 5 8240B ( f) , 524.l ( i) , Carbon Tetrachloride < 5 5 8240B ( f) , 524.1 ( i) ' Chlorobenzene < 5 5 8240B (fl, 524.l <il, Chloroform < 5 5 8240B ( f) , 524 .1 < i l , Chlorodibromomethane < 5 5 8240B ( f) , 524.l ( i) , Chloroethane < 10 10 8240B ( f) , 524.1 ( i) ' 2-Chloroethyl Vinyl Ether < 10 10 8240B ( f) , 524.1 ( i) , 1,2-Dichlorobenzene < 5 5 8240B ( f) , 524.1 ( i) , 1,3-0ichlorobenzen'e < 5 5 8240B ( f) , 524.1 ( i) , 1,4-Dichlorobenzene < 5 5 8240B ( f) , 524.1 ( i) , 1,1-Dichloroethane < 5 5 8240B ( f) , 524.1 ( i \ , 1,2-Dichloroethane. < 5 5 8240B ( f) , 524.1 Ii), 1,1-Dichloroethylene < 5 5 8240B ( f) , 524.1 ( i) , cis-1,2-Dichlorethene < 5 5 8240B ( f) , 524.1 ( i) , trans-1,2-Dichloroethene < 5 5 8240B ( f) , 524.1 ( i) , 1,2-Dichloropropane < 5 5 8240B ( f) , 524.1 ( i) , cis-1,3-Dichloropropene < 5 5 8240B ( f), 524.1 ( i) , trans-1,3-Dichloropropene < 5 5 8240B ( f) , 524.1 ( i) ' Ethvlbenzene < 5 5 8240B ( f) , 524 .1 ( i) , 2-Hexanone < 50 50 8240B ( fl , 524.1 Iii, 4-Methyl-2-Pentanone < 50 50 8240B ( f) , 524.1 ( i) , Methyl Bromide < 10 10 8240B ( f) , 524.1 ( i) , Methyl Chloride < 10 10 8240B ( f) , 524.1 ( i) , 624 (g) 624 (q) 624 /al 624 (g) 624 (g) 624 (g) 624 (g) 624 (g) 624 (g) 624 (ql 624 /al 624 (g) 624 (g) 624 (g) 624 (g) 624 (g) 624 ( g) 624 ( al 624 (q) 624 (g) 624 (g) 624 (g) 624 (g) 624 (g) 624 (g) 624 (al 624 (al 624 (g) 624 (g) 624 (g) (f) Teat Methods for Evaluating Solid Waste, Physical/Chemical Methods, SW 846 (g) 40 CFR, part 136 (i) Methods for the Determination of organic Compounds (EPA 1988) I I I I I I I g D u I I I I I I I I MECKLENBURG COUNTY DEPARTMENT OF ENVIRONMENTAL PROTECTION ENVIRONMENTAL LABORATORY Project: Field I.D.#: Lab I.D.#: Site Sampled: Date Sampled: Sample Matrix: ~ Volatile OrganicS,oon<I Sample Detection Organics-Volatiles Results Limits Method Parameter (uq/ll lua/1) Methylene Chloride < 5 5 8240B ( f) ' 524.1 ( i) ' MTBE < 5 5 8240B ( f) ' 524.1 ( i) ' Styrene < 5 5 8240B ( f) ' 524.1 ( i) ' 1,1,2,2 Tetrachloroethane < 5 5 8240B ( f) ' 524.1 ( i), Tetrachloroethylene < 5 5 8240B ( f) , 524.1 ( i) , Toluene < 5 5 8240B ( f) ' 524.1 ( i) , 1,1,l-Trichloroethane < 5 5 8240B If l , 524.1 ·Ii l , 1,1,2-Trichloroethane < 5 5 8240B ( f) , 524.1 ( i l , Trichloroethylene < 5 5 8240B ( fl , 524.l Ii), Trichlorofluoromethane < 10 10 8240B ( f) , 524.1 ( i), Vinyl Acetate < so so 8240B ( f) , 524.1 ( i) , Vinyl Chloride < 10 10 B240B ( f) ' 524.1 ( i) , Xylenes (total) < 5 5 8240B ( f) , 524.1 ( i) , 624 (g) 624 (gl 624 (g) 624 (,.,) 624 (g) 624 (g) 624 la\ 624 la\ 624 I al 624 (g) S24 (g) 624 (a) 624 (g) (f) Test Methods for Evaluating Solid Waste, Physical/Chemical Methods, SW 846 (g) 40 CFR, part 136 , (i) Methods for the Determination of Organic Compounds (EPA 1988) ~.~,cneNsURG C0UN,V eMR0NM""~er:'CTI0N CAS0RAT00, field l.0.#: 1 0()'1r::_8 Oept.: ___________ Lab 1.0. f: ,I Sa/!Oled: ms. ta:ne i I (futh Project:---------llec'd By: •ddress: //f'//S f}lbe1'1'7dr/e, f?d sic• s...,led: WE:c c.. l!-1:=11i) ' Delivered to Lab On: Date Rec'd: Tim: Sa/!Oled By: {. G,b,tt: ol Samled: /0 /Jv/9 5 r1 .. , LdQ.. ~ Cato: /oltt(:ir Ti•: flP ~ r 9 Oel ivered By: .,!. {hcl.:, 1tl O,eaical rs-?'9:!ition lnaC9!!!jC Men tlet■\1 Aoacnate Or:,p,icl 1:~::i~ Q ----------:• ::::::l~y-□-:::::_-_•-----=~---~ :. :~• ~1 ir ·.·~--·~~w--~----= Jlloiilture □ X Blcarb:nat• C ________ ,_ ppr. ~ll ~ f.:·:\;r..~:.. ::I ~ I Carbonate O __________ ppo Ph.-..1 □. ________ ppo Radioactivity - Clllorlde C ppo Surfactant □. ________ ppo Air - . Ctllodne, Rnic::lual O ------~ Orpnjq Grosa' Alpha O ______ pCi/ .. I Color C ..,;ti Acid Hert>icide C R-t att- Grosa Bet■ □ pCt/lr Cyanide, Total C ppo or-vanic Acid D _______ ppo Water Fluoride O ppa PCB O Repx-t attached I Groaa Alpha O pCi/L Ha..-U C ppo Pesticide O Re~n Ht- Groaa Bet■ 0 ______ pCI/L Nhroten, Amaani ■ a ppo · Seaivolat t le D Report atuehed • I D D D I •• I I JIii i scell aneaus Asbestos □ Clllorop,yll • D ----" '-------PP' _______ s1 Carros iv; ty a 0 i aaol ved oxvven U ------______ ppo Fonaaldeh.,ce □ a □ a a ______ ppo _______ ppo --------_______ ppo Nitrogen, Ntirat• + Nitrt te ~hr09en, Nttr■t■ 0 Nitrogen, Wlti"ite a Nitrogen, To~al Kjeldohl TPH C ppo / voe J>:'lt-t attached -!!hw.1 &i Net■il ppo Al C ppo ppo ; ca;( 31,S -pll □---------'61it• co D -Phosp'lorus, ortho o ______ _ Pholpl,orus, Total D _______ _ PhosP,orus, Total Diuolved O ______ _ A:esidl.m, Fflterabl1 a. _____ _ ·11esi-, S1mf .ded □. _____ _ Residue, Total O ______ _ Specif;c □ _______ _ Conductance ppo , cu i{ '!{,J;J, -os ppo ppo, '·1 fo,ic ppo Mg !.:., "2..'.;j -ppo i Mn {/l. '1 . /JJS ppo ppo ppo K_O ppo SIC ppo ppo W•~ ff, B) l.lli\o/cm ' ppo Sn a ppo Sulfate O _________ _ ppo Zn a ppo Sulfide □. _________ _ ppo a ppo Turi>idity O ________ _ WTU Tefc Met■&I TCI.P Metal ■ C Sb C pp, NOTE: ALL FJELD DATA ~-y BE IECCRDED TO U.IlfTAllf CHAii OF a.rsTa>T 1-■,f( L_/Q pp, t Be.l(' pp, Remarks: /a•~ -e,~ / Cd~ £--Z... pp, l Cr _)I.. .(:::j pp, '?.. /Pb~ .:.s pp, / "'f < 0,..., pp, , WI ..(/ Q pp, /Se, <;i pp, pp, Date Coaole~ed: --------,-.;._c.....------------1 · (, i Ag_)(, L.. '> Tl C Pl"' □ pp, Laboratory Director: I <D.10 <'.0,025: ppl ------pp, pp, pp, pp, pp, pp, pp, ppl ppo ppl ppl ppo ppo ppl ppo ppl ppl ppo PP' ppo I / / / , I I I I I I I m u 0 ll I m I I I I I NBCXLENBURG COUJITY DBPAR!rXBHT OP' EHVIROJDIEN'rAL PROTECTION EHVIROIOIE!nAL LABORM:ORY Project: Field I.D.#: Lab I.D. #: Site Sampled: ------------Date Sampled: Sample Matrix: Water Volatile Organics Sample Detection Organics-Volatiles Results Limits Method Parameter (ug/l) (ug/l) Acetone < 100 100 82408 ( f) , 524.1 ( i) ' Acrolein < 100 100 82408 If), 524.1 Ii>, Acrvlonitrile < 100 100 82408 ( f), 524.1 ( i) ' Benzene < 5 5 82408 ( f) ' 524.1 ( i) ' 8romodichloromethane < 5 5 82408 ( f) ' 524.1 ( i) ' .. Bromoform < 5 5 82408 ( f) ' 524.1 ( i) ' 2-Butanone < 100 100 82408 ( f) ' 524.1 ( i) ' Carbon Disulfide < 5 5 82408 ( f) ' 524.1 ( i) ' Carbon Tetrachloride < 5 5 82408 ( f) ' 524.1 ( i) ' Chlorobenzene < 5 5 82408 ( f) ' 524.1 (i), Chloroform < 5 5 82408 If), 524.l Ii), Chlorodibromomethane < 5 5 82408 ( f) , 524.1 ( i) , Chloroethane < 10 10 82408 (f), 524.1 ( i), 2-Chloroethyl Vinyl Ether < 10 10 82408 ( f) , 524.1 ( i) , 1,2 Dibromethane < 5 5 82408 ( fl , 524.1 ( i) , 1,2-Dichlorobenzene < 5 5 82408 ( f) , 524.1 ( i) , 1,3-Dichlorobenzene < 5 5 82408 ( f) , 524.1 ( i) , 1,4-Dichlorobenzene < 5 5 82408 If l , 524.1 ( i l , 1,1-Dichloroethane < 5 5 82408 ( f) , 524.1 ( i l , 1,2-Dichloroethane < 5 5 82408 (fl , 524.1 Ii) , 1,1-Dichloroethvlene < 5 5 82408 ( fl , 524.1 ( i) , cis-1,2-Dichlorethene < 5 5 82408 ( f) , 524.1 ( i) ' trana-1,2-Dichloroethene < 5 5 82408 ( f) ' 524.1 ( i) , 1,2-Dichloropropane < 5 5 82408 ( f) , 524.1 ( i), cia-1,3-Dichloropropene < 5 5 82408 ( f) , 524.1 ( i) , trans-1,3-Dichloropron,::,ine < 5 5 82408 If l , 524.1 Cil, Ethvlbenzene < 5 .5 82408 If l , 524.1 /il, 2-Hexanone < so 50 82408 ( f) , 524.l ( i) , 4-Methyl-2-Pentanone < so 50 82408 ( f) , 524.l ( i) , Methyl Bromide < 10 10 82408 ( f) , 524.l ( i) ' Methyl Chloride < 10 10 82408 ( f) , 524.l ( i) , 624 (g) 624 /al 624 ( q) 624 (a) 624 (q) 624 (a) 624 (g) 624 (g) 624 ( g) 624 (q) 624 /al 624 (q) 624 (g) 624 (al 624 ( q) 624 ( g) 624 (g) .624 (q) 624 la) 624 (a) 624 ( q l 624 (g) 624 ( g l 624 (g) 624 ( g) 624 Cal 624 /q) 624 (g) 624 (al 624 ( q l 624 ( g) (f) Teat Methods for Evaluating Solid Waste, Physical/Chemical Methods, SW 846 (g) 40 CFR, part 136 (i) Methods for the Determination of Organic Compounds (EPA 1988) I I I I I I D I I I I I I I I I lfRCTI ll'l!l\'IJJlG COUHTY DBPlUCDIBIIT OP' BHVIROHKIDl'XAL PROTl!CTIOH BHVIROllJCBMTAL LABoRAroRY Project: Field I.D.#: Lab I.D.#: Site Sampled: Date Sampled: Sample Matrix: Water Volatile OrganiCStoonU Sample Detection Organice-Volatilee Results Limits Method Parameter (ua/1) (ua/l) Methylene Chloride < 5 5 82408 lfl, 524.l (i), MTBE < 5 5 82408 ( f) • 524.l (i), Styrene < 5 5 8240B ( f) , 524.l (i), 1,1,2,2 Tetrachloroethane < 5 5 8240B ( f) • 524.1 ( i) • Tetrachloroethvlene 61-<a 5 8240B (f), 524.1 ( i) • Toluene < 5 5 82408 ( f) • 524.1 ( i) • 1,1,1-Trichloroethane < 5 5 8240B ( f) • 524.1 ( i) , 1,1,2-Trichloroethane < 5 5 82408 ( f) I 524.1 ( i) , Trichloroethvlene .c;--5 82408 <fl , 524.1 ( i) • Trichlorofluoromethane < 10 10 8240B ( f) , 524.l ( i l , Vinvl Acetate < 5 5 82408 ( fl , 524.l ( i) • Vinyl Chloride < 10 10 8240B ( f) • 524.1 ( i) , Xylenee (total) < 5 5 82408 ( fl , 524.1 ( i) • 624 (q) 624 (q) 624 (al 624 (q) 624 (q) . 624 (g) 624 (g) 624 (g) 624 IOI 624 (g) 624 (0) 624 (q) 624 (g) (f) Teet Methods for Evaluating Solid Waste, Physical/Chemical Methods, SW 846 (g) 40 CFR, part 136 (i) Methods for the Determination of Organic Compounds (EPA 1988) I I I I I I g 0 I I I I I I MEl\'10 TO: File FROM: Jeanette Stanley Environmental Chemist NC Superfund Section DATE: July 24, 1995 SUBJECT: Ram Leather NCO 982 096 653 Charlotte, Mecklenburg County, NC Ref 18 I traced the surface water pathways from the Ram Leather site. There are two surface water pathways leading from the site. The northern surface water pathway flows overland and crosses under 24/27 in a culvert into ditch. Overland flow continues for about 2000 feet as an intermittent stream until the intermittent stream joins another stream. This stream continues for 1000 feet and enters a pond that is 800 feet long. The outfall from the pond is a perennial stream, an unnamed tributary to Caldwell Creek. In 1200' the UT to Caldwell Creek flows into Caldwell Creek. This stream segment flows through a 65-acre wetland. The total wetland frontage from the pond outfall to 2 miles downstream along Caldwell Creek is 4 miles. Caldwell Creek then becomes a linear wetland for 1.2 miles and flows past two small wetlands along this route (one 5-acre and one 7-acre wetland). Caldwell Creek exits the linear wetland and flows for another 5 miles and passes a total wetland frontage of about 1500'. At 8.9 miles below the probable point of entry (PPE), Caldwell Creek flows in the Rocky River. This 15-miles surface water pathway ends on the Rocky River about one mile downstream of Route 601. There are no additional wetlands along the Rocky River portion of the surface water pathway. The southeastern surface water pathway flows overland for 1000' to a pond that is 200' long. The outflow from this pond is an intermittent stream which enters another pond in 1200'. In 2.2 miles, Wiley Branch flows into Clear Creek. At 7.3 miles below the PPE, Clear Creek flows into the Rocky River. This 15-miles surface water pathway ends on the Rocky River one mile upstream of Rt. 200. The first wetland along the southeastern surface water pathway is at 1000' below the PPE in Wiley Branch. This is a linear wetland which continues for 1000'. The stream then flows for 1200' along a 7-acre wetland (total frontage 1200'). Wiley Branch then flows another 600' along a linear wetland and flows for ;1800' past an 8-acre wetland (total frontage 1800'). Wiley Branch again becomes a linear wetlahd until it enters Clear Creek. Clear Creek has a total wetland frontage of 1.2 miles. There are no wetlands along the Rocky River portion of this 15-miles surface water pathway. I I I I I I I I u I 0 0 B m I I MEMO TO: File FROM: Jeanette Stanley Environmental Chemist NC Superfund Section DATE: August 25, 1995 SUBJECT: Ram Leather NCD 982 096 653 Charlotte, Mecklenburg County, NC Ref. 19 I made copies of the Wetland Inventory maps Harrisburg, N. C., Concord, N. C., Mint Hill, N. C. and Midland, N. C. I drew distance circles around the site and used·a highlighter to show HRS-qualified wetlands. I then used a planimeter and measured the acreage of each wetland area. This map is attached. The HRS-wetland areas within the Target Distance Limits of the site are as follows: 0 -1/4 mile 0 acres > 1/4 -1/2 mile 0 acres > 1/2 - 1 m i l e 45 acres > 1 - 2 miles 128 acres >2 - 3 miles 258 acres > 3 - 4 miles 203 acres I visited the Natural Heritage Office of the North Carolina Department of Parks and Recreation on the 7th floor of the Archdale Building in Raleigh, NC. I viewed the USGS topographic maps and marked species of concern on the attached copy of the wetlands inventory maps. For those sitings outside the four-mile air target distance limit but along the 15-mile surface water pathway, I made a copy of the Natural Heritage Map and noted species and siting number. I then determined the status of each species. There are no endangered species withir. the target distance limits of the site. The following species, their distance from the site and thei! status is shown on the following page. I I I I I I 0 I I I I I I Surface Water Pathway Air Pathway Species Status Distance from PPE Distance from site Lotus helleri (#4) (Carolina Birdfoot) NC -Candidate 1.2 miles(Caldwell Creek) > 1 - 2 miles US -Candidate (low priority) Rare or uncommon in NC, Globally rare and local throughout range Silphium NC -Candidate 1.4 miles(Caldwell Creek) > 1 - 2 miles terebinthinaceum (#3)US -None (Prairie Dock) Imperilled in NC but Globally Secure Lotus helleri (#2) Lotus helleri (#2) see above see above Anemone berlandieri NC -Candidate (Southern Anemone) US -None Imperilled in NC Air Pathway only 6.5 miles (Clear Creek) 13 .8 miles (Clear Creek) Globally rare and local throughout range Arabis missouriensis NC -Candidate 14.0 miles (Clear Creek) (Missouri Rockcress)US -None NC -Critically imperilled Globally Secure < 1 - 2 miles Amorpha schwerinii (Piedmont Indigo Bush) NC - S i g n i f i c a n t l y Rare US -None 14.6 miles (Clear Creek NC -Rare or uncommon Globally rare and local through out range At 14.7 miles from the PPE to the Clear Creek Surface water pathway lies the Rock River/ Morgan's Bluff, a Registered Natural Heritage Area. Several Natural areas of statewide significance are 14 -15 miles downstream from the PPE to the Clear Creek surface water pathway. I I I I I I I D u I I I I I I I I I I .MEMO TO: FROM: File Jeanette Stanley Environmental Chemist NC Superfund Section DATE: October 16, 1995 SUBJECT: Ram Leather NCD 982 096 653 Charlotte, Mecklenburg County, NC Ref. 20 I calculated the stream flow for numerous points along both surface water pathways and reviewed the stream flow data in order to determine the dilution weights for these streams. For the northern surface water pathway, Caldwell Creek flow rate is less than 10 cfs until it is within 0.6 mile of the Rocky River, so the first 8.3 miles of the surface water pathway is a minimal stream. The next 0.6 mile of the surface water pathway has a flow rate slightly greater than 10 cfs, making it a small to moderate stream. The Rocky River, or the remainder of the surface water pathway is a moderate to large stream, having a flow in the range of 300 -400 cfs. For the southeastern surface water pathway, Wiley Branch has a flow rate of 4.6 cfs just above the point where it enters Clear Creek 2.4 miles below the probable point of entry (PPE), making Wiley Branch a minimal stream. Clear Creek has a flow rate of 10.8 cfs above the point where Wiley Branch enters and a flow of 30.8 cfs near the point where it flows into the Rocky River 7.3 miles below the PPE, making the Clear Creek segment of the surface water pathway a small to moderate stream. The Rocky River has a flow rate of 786 ~fs below the entrance of Clear Creek. The flow rate of the Rocky River at a point below the end of the surface water pathway is 945 cfs, so the last 7. 7 miles of the surface water pathway is the Rocky River which is classified as a moderate to large stream under the Hazard Ranking System. . . . . . . . . . . . . ::,···:::::: . . ' . . . . . .. , .... . .. . .... . .. . .... . .. . .... . .. . .... . .. .. ... . ... ······· ............ ············ ;:::::::::·: 111111 . . . . . . . . . . ' . :::::::::::: ,,1 .... ,,,,,, .. . .... . .. .. ... . --···-·· .. . .... . .. . ... .. .. , ... .. .. . .... . .. . .... . ............ ············ ............ ............ . . . . . . . . . . . . ············ ......... .. ······ .. ······ .. . .... . .. . .... . .. . .... . .. . .... . .. ······ .. . ..... ............ IIii ............ ............ ······--···· ............ . . . . . . . . . . . . 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' ..... . : ... :::::: U.S. GEOLOGICAL SURVEY OPEN-FILE REPORT 83-211 · DRAINAGE AREAS OF ... ·· ·••••··•··SELECTED SITES ON STREAMS · . .... ).:1N NORTH CAROLINA Prepared in cooperation with the North Carolina Department of Natural . Resources and Community Development j,g, .. ill•'··· ) I'. t' ' fi\ir,¼!.> -;',.<>:' ~,;.II"{,' .. ... };~;,,,i· l1'" •' ~1~,i•.•.;· : :C j .:' ,ti1::i;-. ;' : ~-> / :, ·tj ; h-.:'. __ _ •t!!/1'" !·-~~-\:· 11•· ,. j1,,; . ffl'lt\, :r.· ,-. :,<, • ;1;•.u .) · 1w:.•,=~.· · ~7;1-•· i~ .... " .. -~ "·'.· ' iJ:~iIF~\?: r.g'" ,-,, ! ; ,. " . ~lr, J~:i:i:: \. ~\~ .. :.?i:';.: ,,:er,i::•,l: ,1,,1.. :~~~l-:'1•ii .. ,i.:: ' , ••• ··11· i f.1}'.:1(i:,.: ~,~~;;ii::: ,~fG!'i:.,11 Hi■ fi;T.ifil:::;.i: ,. ... 1·· ... [h'·;.j,1:ii!;:i w~ft!~j};~ , . .,"""'',~:.::·, •: 11; IZi~\t~;.~::j 11:., l;Jfi,f;•;!i'it ~-'"" ,r•: .. , I, ini,,,.,,1, lJfti-/:;1f' IJ .. ~'i,>,I !Hi ~-,-u\~~ilii:/1: .iJ~ l., -'.'' 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STANFIF.LO RClCl{Y R NR STANF!EL D ' ISLMO C' l\fl LOCUST ISLAND C AT $R 1130 NR STANFJF.LO ISLMO CAT SR 111S NR STANFJELO i.UCIJ18E"R C AT SR 1 l :10 NA OA!<BOP:0 CUCLl"f1ER CAT SR 1117 NR STANFIELD ISLAND C AT SR 110'3 NP STANF!FLO ISLAl'G (' r.f't SfAl'FJEl D JSI.ANO C AT MTH NR (\A!<80RO 02l247"34f-0 CRISCO R AT SR l!:Q Nf> NEW SAI.E"M 0<?12479470 t;R!SCO R AT MTH NR f'€W SAI..E'M 021247":HSO "!ll('KY R TRfB NR NEW SAi.EM 021247'3800 RDC'f(Y R AT NC 205 NR OAl<BCIRO 021247"3E25 P.QCKY R TRl8 AT MTH I'S! l1Al<fl.0:.0 021247'9fl50 0212479875 0212480fl00 0212480'903 0212480"350 0212481300 0212482300 0212482400 0212482700 021248277S 02124827:15 0212483500 Oc!l248492S 021.:!48495() 0212485100 1~CLDWATFA 8 AT SR 1103 ~l'l. OAl<EIOFIQ COLDWA TFR 8 AT SR I I 00 I\R OA!<BORO ROC!<Y R AT ~ NC 74,:! rP OAKl'IOFIO ~ILBE'.RTS C AT MTH NR OAK0ClRO ROCKY R TR fB AT MTH I'S! OAl<80RO ROC!<Y R NR OAKBORO LC'NC C AT SR 1454 NR R!CKF"IELO LONG C AT NC 49 NR RICI-FIELD LCNG C NFI R!CH'"JEl.O !_('Ifs/(; C TRIS AT MTH NR MILL!W.PORT Ll"ING C TR 1B AT MTH NR PL. YLER I ONG C NR PLYLER l. LONG C NFI NF."W L(Nl()N L. LONG C AT PALESU/'£ l LC'f\lG C AS TCW-S C AT AL.8E:MAR!.E QRAINAGE """" (SQ Ml) "38.?. 2.72 2. 41 2.44 B. 49 : 1. 4 12.4 5. 58 a. 33 5Je.. I. 10 $"2. I. 54 '·"' 3. ·;;o u,; 12. E. ~ ~-22. S """-' ..,.-.:C;. l.E.3 8. S,:) 11.0 IE-.40 c!J.4 i:!4.Q 2.80 e.. 48 12. l 4l.4 1.58 ~ a.·n 14. '3 1e..r, 3. 77 2.03 ID.8 13. 5 18.4 3€-. ':' 38. I 47.3 48.5 l. '34 ~ B.25 4 .2, o. 74 7.55 o. 74 ll.7 7~ _..,_ '° 7. E-6 10. 7 2. 8'3 '•.':'4 I'/. i?. 13.2 22.0 2.30 3. 85 2.45 ~ 1 0 1 2.46 5.07 75~ __.--r.,., 2. 30 763. 5.2•3 5.80 lC.G 3. 24 3. 4'3 27.S 1.21 2. 76 6.S2 SlrE ~" 02 '" '" 20 20 ,., 351851 351654 351€.51 3SIS47 35161 7 02 351€00 20 3516-07 CO 3S1537 20 :?51533 20 3S1516 20 3514M oc 351315 20 351403 20 351332 20 351214 20 3S114\ c!O 351229 2'1 35130') 20 351258 oc 351 [40 20 3S1108 20 350856 20 3S0826 20 3S074", 20 3507?.B 20 3S072E, 20 350726 02 350'314 20 350350 20 351014 02 35105'2. 20 351133 20 351043 Oc! 351010 20 35(1",04 CONC 80275a 80,?316 803141 803304 803126 803008 B0.?512 '""""' '"""'' BOi:!822 802842 802"315 803237 803038 803758 80362'3 80344R 80335'~ 803244 B0314~, 80304 \ 803808 B03'BO 803753 RQJE,11 803440 803440 80320'3 BOJSIJ 803440 803228 803042 802842 802B24 803":127 OUM MAMIS Mel.NT PLEASA.'lf MCU'-,JT PLEASAr,iT CO-JCDRO SE CONCORD SE CCNCORO SE CCNCOPO SE 1'"0 .. NT PLEAs.<.NT r-'O..Nl" PLEASANT /'O..NT PLEASANT MQU'IT PLEASANT STAI--FlELO STANl"IE:l.t' M IDLAt-<O MIDLAl'-0 /11JNT HILL MIOLAt-0 MlDLAJ's() MlDLAUJ M!DLAM'.l MlOLAr-0 MIGLANO MINT HILL MINT Hll.L MINT f.l!LL 8A!<ERS BA!<ERS 81',1,(ERS Ml OLANO MIDLANO M!OLANJ M!C)L.>,N() Ml OLANO STN-FlELO STANFIE:'.LO MAT>HE"WS <!O JSCE-15 8037S4 /'IATTHEWS 20 350608 1303504 8A!<F.RS 20 350&32 803346 RAl<EPS 20 3S04l8 803853 MATTHEWS 20 3503\4 8037c!5 8Al<FRS 20 3S0352 cc 350451 CO 35CE2E 02 3507,,4 20 350817 20 350841 20 3509'•'.'l 20 350)55 20 35Ci~46 oc 350753 20 )S0-)4"3 Cc! 35 12SB c!C 3SLJ56 20 3S1214 20 351144 20 35103") 02 350'355 02 351 538 20 35135:l 20 351243 20 351357 c!O 3St302 20 351216 02 35:151 20 351047 20 350850 20 350958 20 3S1007 20 351003 20 351031 20 3,;11s2 20 351050 20 35105?. 20 351140 20 351130 02 351142 20 352821 11 3Sc!BO<! 02 352€-24 20 352437 20 352328 02 35.2251 20 35,2544 20 35a421 20 35a200 80361.J 803442 803256 803.:!14 803021 80281 7 802720 80?.711 802~,l 7 8D2f.34 SC'+:!450 ao2e,,-,. 80c!S18 B02558 802522 80,:!437 802351 80240,::, 802328 802307 SA~ERS BA!<EP!, RA!<ER3 MIDLAt-0 Ml Ol.ANfJ STANFIELD STANFIELD STANF"IELD '5TANF!~L0 STAl'F!ELD STANFIE:LO STANFIELD STANFIELD STMF"lELO STAl'-IF"IELO STANFIELD Sft;/',JFIELO r-o.__'-T Pt. EA SANT STANFlFLO STANFlELO 8Gc!l43 0AK80RC1 802233 STANFIELD 802255 SfAl'-FlELO 802228 DAl<BORO 802216 CW-:BDRO 80c!218 OAK8DPO 802140 C,A!<80RO 801:04 7 OA!<RORD 802044 OA!<BORO 801"31"3 OAl<BDPO B0!945 80 ! "3?."3 801830 801 735 801 70€, 801658 801 737 801727 801€-28 801532 801S03 801448 801223 801146 80115S OAKBORO OAASORO OA1<80RO OAl<SORO rJA!<SDRO OAKBORO MOUNT PI_EA._<;ANT MO.NT PLEASANT P10LJNT PLEASANT r-"O..fJT PLEASANT MOL.NT PLEASAtH ALBEMARLE A.L8EMI-RLE 1-,LBEMARLE ALBEMARLE c□u,1:"f COO<' 02~ 02S 025 025 025 oas 02S 025 02,;, 02S 025 02S oas 025 119 _J ;1')_;0,1> 1-1b,J✓t,, 6;(_ll la 025_7•lf"/ m ~3,.'., m-<A ,-{ !IS ~v· ""b I IS 113 l ;·~ 1 T"' I 7'3 1 7') 17'3 1n 1 73 l 7) '" ,ti, t7·)-1 """OU 179 l7) l 7') 17") 17") 17""3 l 7'3 173 17') 17") 17) l 7'3 \ 7") 167 \7'3-17') i;< \7'; \f,7 167 tf,7 ,,, JIS7 17•3-1€•7 167 1€,7 1f,7 J(,7 167 167 ,s, 17":1 1 79 "' 1€,7 !E-7 ,s, ,s, 167-"' 17':l I 7·~ 167 ,s, "' ,,, \€-7 l~-7 ,., 1€,7 "' i1lR / q~) /or)o W I 11Jv1.;.\P C)F MEAN AN'NUA.L RUNOFF FOR ·rFIE II~ 0 n1,H EASrfER.N, SO Ul'J-IEASrl'ERN I f\Nl) ntvf!D-~'\TLAN1·rc-UNI1"ED Srff\_'TES, \1V1\TER YEARS 1951-80 ]3v . . , D . --. l·Viliiam R .. Krug, Warren A .. Gebert, Davi cl J. Graczyk, U.S. Geologic1l Survey; Donalcl L Stevens, Jr., Eastern Oregon State College; mBillry P. Rochelle, Northrop Services, lnc.; und M. Robbins Church, U.S. Environmental Protection Agency lu s GEOLOGICAL SURVEY I-water-Resources Investigations Report 88-4094 n J>repared in cooperation with the US ENVIRON1vfENTAL PROTECTION AGENCY I I I D I I I •• I Madiso11, Wisconsin 1990 • ( , a I D I m ij ,11 i sit)Jl.S thJt. thl.! methods thc1t used the arei.1-\"-'cighted ;1\·r:r:1,½f c;f the clrain::-igc zin~a or the centroid of the l! r:i i nc1~l· ;1 re::: produced somewhat !Jeth:r corrc·i<.ltinns- tilat is, the interecept WJS closer to zero. thi.:-: stzmclard errnr.s ,.,·ere small, ,u1d the correlation coefficients 1,vcrc larger. These methods have sligluly grc~1ter po\,·cr to predicr actual runoff /-\c\di tio,wl srni-islica! investigation iou nd no significant differences in reliability of the runoff estimates among the <.He~1s. No significant differences existed in the errors for stations with drainogc areas of differing size. USE OF MEAN ANNUAL RUNOFF MAP Mean annual runoff for a site can be estimated from the runoff map by several methods. The simplest n1ethod of estiinating the runoff is to locate the site on the runoff map and to identify the runoff conlour nearest the site. This method, however, is less accurate than other methods. The most accurate method is to draw the drainage basin on the runoff map, anc! use the runoff contours to divide the basin into bands of differ- ing runoff. The area of each of the bands within the drainage basin is then determined. The areas of the separate bands are then used to compute a weightec\ average runoff for the basin. For example, if 50 percent of the basin is in an area of 18 in/yr (inclies per year) of runoff, 30 percent in an area of 20 in/vr of runoff and 20 percent in an area of 22 in/yr of runoff the mean annual runoff would be calculated as follows: 0.5 xl8 + 0.3 X 20 + 0.2 X 22 = 19.4 l{unoff tstimatt!d ·rrom tile rnap is in inches per yl'ar, avcri.lgeci over the entire dr;linabc basin. ?vh1ltiply this value by the dr;1inagc arc:J, in squ~ne miles. ;ind divide by 1:rso to convert t'lJ mc,111 annu<.J\ disch;1rge, in cut)ic feet JH..:!· sccotHl. l n tho:.:: ~tl)1Jvc exam.pie, assuml"' l"t1l' clrai11~1ge an::1 uf the siri.: is JOO 1ni::. The mean :1nnu:il discharge, in cubic feet pe: second, would be: 19.'I ,10011:i s:o =143 The runoff n1,1p \.\'as prep;:n1.:d to allow cstirnation of mean annual runoff at sites where no strea1nflow data are available. The 1naµ reprc:se::nls mean annual runoff for areas with natural Janel cover. Caution shoulc\ be used in applying the map to csti1natc runoff for areas that are not natural land areas. The runoff map should not be used for areas, such as large urban areas, where the land cover has been altered in ways that would change the amount of runoff. The runoff map is not applicable for lakes or bays, for coastal wetlands affected by tides, for streams controlled by reservoirs large enough to influence the total annual strearnflow, or for streams with substantial diversions. Local features could cause the runoff at a particular site to differ substantially from the r'lnoff indicated by the runoff map. The geology of the drainage basin might cause substantial amounts of ·water to enter or leave the basin as ground wnter. This could substan- tially increase or decrease the runoff. For example, a strean1 with a sn1all drainage area tbal includes a large spring pr0bably wolllcl have higher average stream flow than indicated by the runoff map. Ji1ble 5.-Descriptive statistics of errors i11 esti111uted ru11off at 93 test sta tio11s Method Mean .Standard Standard absolute lvtcan error of deviation vtllue ll\Ci\ll Error in inches Area.weigh led 2.0 -0.35 0.30 2.9 Centroid 2.2 -.71 .33 3.l GtS 2.7 -i.74 .37 .1.6 Nearest-inch 2.8 -1.77 .38 3.1 Nearest contour 2.8 -1.79 .:~~) 3.8 Percent error ------ Area-weighted 9.0 -0.54 13 12.9 .,. Centroid 9.8 -.71 1.4 13.5 GIS 12.0 -6.42 t.6 lS.9 Nearest-inch 12. 1 -6.20 1.6 t5.6 Nearest-contour 12.2 -6.26 J. 6 15.8 . t/ \ . ,, '. I n R D I n D D D I I I I Site Name: Ram Leather Site Number: NCD 982 096 653 Site Location: Charlotte, Mecklenburg, N.C. Latitude: 35 13 41.0 Longitude: 80 36 24.5 Date: October 18, 1995 Calculation Results Distance from Site Location Population Per Ring Cumulative 0 to 1/4 mile 48 48 > 1/4 to 1/2 mile 186 234 > 1/2 to l mile 422 656 >l to 2 miles 1,396 2,052 >2 to 3 miles 2,437 4,489 >3 to 4 miles 4,987 9,476 Number of Households Per Ring Cumulative 14 14 56 70 135 205 483 688 888 1,576 1,827 3,403 Ref. 21 Note: The populations and number of households within specified target distance rings were calculated for the NC Superfund Section by the NC State Center for Geographic Information and Analysis using the 1990 US Census data. These values were calculated by summing the population and the number of households data for each census block located within each target ring. For census blocks lying only partially within the ring, the per cent area of the block within the ring was multiplied by the population and household densities of the block. D D I I I D D I I I I I I I I I TO: FROM: DATE: File Jeanene Stanley Environmental Chemist NC Superfund Section December 18, 1995 SUBJECT: Ram Leather NCD 982 096 653 Charlotte, Mecklenburg County, NC Ref. 22 I spoke with Tim Lowder, City Engineer, Concord (704) 786-6161 ext. 303. He indicated that no additional water lines have been added in the Cabarrus County system in the area of the Ram Leather site since the 1994 map was made (attached). The current water line system ends at the intersection of Albemarle Road and Flowes Store Road. Mr. Lowder said that tentative plans have been made to extend water lines to the Pioneer Mill Road intersection along Albemarle Road, but this is contingent upon a developer's plans to build a golf course/ housing development in this area. If completed, this new extension will terminate about 1 mile northeast of the Ram Leather site. Mr. Lowder said that Cabarrus County has just completed relocating water lines along Albemarle Road up to the Flowes Store Road intersection because a new 4-lane highway is being built and the water line was in the way of this construction. The highway construction ends about 1000' west of the Flowes Store Road intersection. I spoke with Mr. Hafiz Shafei, Civil Engineer I, Planning and Analysis Section, Charlotte Mecklenburg Utility Departtnent (704) 391-5173. He said that there have not been any new water lines installed within four miles of the Ram Leather site since the 1993 map was drawn (attached). The current water line ends at Wilgrove-Mint Hill Road. He did say that the 10-year plan includes extension of the water line to Rt. 51 and up Rocky River Church to Camp Stewart Road, but he does not know exactly when this expansion will occur. Mr. Shafei said that the 4-lane extension on Albemarle Road from Charlotte ends in the vicinity of Clear Creek School. Hence, the only section of Albemarle Road that has not yet been improved with a four-lane expansion is an approximately 2 1/2 mile long stretch starting about 1 mile west of the site and extending about 1 1/2 mile east of the site. In view of this, even if funds were available, it seems unwise to install a water line until this segment of highway construction is complete. Mr. Lowder also said that due to the presence of the .railway between the Ram Leather site and the Albemarle Road, it is likely that any highway expansion will be on the north side of the railway. This may impact some of the residences. I I I I I I I 5001 I I I I I I I I I ; 0000 12000 ~ \', _/.t_ ....... ~··· ,.:......._..,......_,_ y~ L1 -' # ' D ,,,.1-~ f/. ~t 540000 I ~000 '.:3COOO 160()ll / I '/ r-~~ d.· --·"'""~ .. ,• ; ~----'~·~··-'_' -~-·-• _;i,-. ::~::..::;f,.~¾,// l f _/ .,...- ./, " i\ ·,:,. > ' ./ (( i ( I I : •tw.-.-,,,., . ~ lf;QQQ - ---l!l!l!I ----- LEGEND -EX. MAJOR WATER SYS!EM -PREVIOUSLY FUNDED --l'IBSf YEAR l'UNIIE!l -FUNDS IDENTIFIED ------IINFINANCED -10 YEAR NEEDS · All 'nlue lined road.s h;:i.·10:) t~Xist.i.nc ;\;-.:'i.:~ 7.-i:::~.-:. A J..1 · other categories are not in exi.<;; i:.C:.:n{P-ri. E of Drjcember tSSJ. · These f~.mde(.r li.~tings' are planned extent.ions for future· construction. The accompanyin~ pages list project Ir (Prj No,) and dates of funding, Some streets show an existing blu9 main with a projected Rreen para- lell extension. This t, is to upgrade and repla- the weakening blue main. -:$ee Pr j. 2. in NE part of County , /h,wJ,~M-,n1,, l¼f, hf,...;Ti,, 124,c (-ft. ."i. FMM,L, NC So,kt,./w,) --1111 - CHAR10TIE-MECK1ENBURG UTIUTY DEPARTMENT CAPITAL IMPROVEMENT PROGR~M FY 94 -98 WATER PROJECTS RKV1SED 02/26/93 GRAPHIC SCALE IN FEET 0 15000 30000 F'!NRNf+ftP!t\:.,ngf@MtW;J SCALE 1" -15000' .. .. 1 r r , 5 i 1 SW t#'J )H :rtrr I ------:" , ·-~----~/~/ __ ,.~ ------· HARRISBURG, N.C. S0"45' 35•n•:,o• CHARLOTTE SE CHARLOTTE ,, 0 SCALE I .400() , ... , ' '. I ••L □ 1 .... D,o ..... ACl'll:AIJE GUIDE SYSTEM SUBSYSTEM SUBSYSTEM '"" SYSTEM Oth11r ,nformat,on including a narrative repon concerning th wetland res~1.1rces rlcp1cte,;I on !hrs document may b6 available. For onformatton, contact. 1 -TIDAL Reglon•I Cir&Ctor !ARCE) R•gion 1\1 U.S. F,sh and Wildlife SeMce 7~, Spring Street S,W. Atl•nu,, Georg,., 30303 M -MARINE 1 -SUBTIDAL 1 .,_ .... ., "'"" '-"' -UNCO,,SO• IO~TOO •o"°" 1C.....G,~•I "'"' , .. •o.., .. 2 -LOWER PEIIOIN1AL ,., _,,.,.,..,o R -RIVEl'II E ' ' ' 3 -UPPJ¥1 PERENNIAl j NATIONAL WETLANDS INVENTORY UNITED STATES DEPARTMENT OF THE INTERIOR SPECIAL NOTE Tn,s documen1 was preoa,ed p,omar,ty b'j ',weoscop1c anaiy,is of hl9h altitude •e-,al p'101<>gtaph• WUl•~~,were 1d"""f,ed on ,~e phorngrap''i based on ve,;e•at,on >11iblo hyd,olo;v. and geog,aphy "' •<<o,<1<1nco wo1h Clo.1,ifice· 1,on of Wofl1ndo ~nd O.Oepwo11r l'~bot.i• .,, tll<I ln410<I State, 1rws1CBS . 79/31 Oecemt>e, 191111 The 111,,a1 pholo9raph< 1Voically ,~lloc• oond.,,ons du, ~q •~• >;1>C1f,o iea, and soaMn when 1•,ey were talen Jn a,'dotoon.rh••• ,. • ma,g,n of s.,o, ,nt>eron, ,n the USP o! the ~er,al pi,ot"llraphs Th"s, a deoa 'ed on tho 9 ro"nd ,od "''"""•I •nolvs,s of a OlnQle •••• "'lil\l '"""'' ,n a ,ev,s,on ,1 the wetland '>Oun-Oar,es ~<tabt,shed througn ~hot<>groph,o •nte,p,ete, ,on :n •dd•h>n some sm,11 weOlaM• Ondlhose ol;,ocured b• dense tore~, oove• may no, i,,, ,noludt!d on th,s document Feoo, •• S•ete and local rPaulatcrv "'l~nc,~, wlth/u'IJ<ho loon oeor wetla0 0• mo, <M1m and <lescnbe w<ttlM"! 1n o d1Horent ,,,.n,., .en !hat used ,nth,. ,n,01110,-Tl)o,,e ,, no auompt. ,n c 'he '""' des,gn <l< p,odc,e16 ol th,s ""'"n• torv to dof,nr tr"'"" •s of wop,,.otory 1u,,,o,c,,on '1 any Fedocal. Sm~ o, local gove,nmen, "' to ..s1abl•sl< ,h~ geogrop~,cal scope of,.., '"""'"'O<V p,09rams o! g~e<n "'""' ag•ncie P<o,aon• .,,..,di"O to •n9•Q• ;,. octv,ueo "'v~lv,ng .,,, ',t,c,• on, w th,r o, aciJ• , ,, to ..,_..,.g ,,;.__, l,oa• •""uld ... k ,r,o •dv>oo <>f ffpp,..,,., •• Fe,:!e,•l~lote SYMBOLOGY 0:AMPLE bYSllM I S~~~YSICM ' l I ASS IJEM2t SLJBCL/IS~ WAlFH HGIMl unAND 1NON WfTLANO, R20WH < c:•,c,,,, OCEPWATEc~ l-lA811A', NOTES TO THE USER • We,land• wh,ch ha~e been lrr,jd eum,nac1 ••• •"lliuttG on ohe "'•Pb¥ an .,,.,,,k (') • Add,tmns o, corre<:110"" !o the we,l1n<ls ,nl,>r"1atl0n a,oolovod on 1h1s map ore80l,c,1ed Pl•-lorwatd ..,.., ,nlonn•"on to IM addr0ru ,nd,cit!ed • Sub5vs,ems. c1.,se,. 5"bcl1un, an,; W•••• Rq,ma on ha/,cs wore developed 1pec1!ocelly for NATloMl,L WETLANDS INVENTO~Y rn-mg • Some a,eas des,gnrued as lldSB. MS8W, OIi 114S8J (INTERMITTENT STREAM$) may not m,•,n tile <1111,no• 1,0n or wa?land • Th,s mop ~•es th& cla., Unconsol,dated Shore IUSI On ea,her NWI mB?" that cl~•· WH """'~""'~ Buch/ Bar !BBi. or Flat (FLI Su~lu .. , rema•n !l>e .. me ,n bot~ AERIAL PHOTOGRAPHY • or k>cel ogone,•• eoncorn,~g ap~c,hed .._..,.,., •"11,(i,,to,y P"'ll'am• 1nd otopn.iory Juroed,c~on• <1>11 may111:Heot ouch •ot•~•tlH I: 0 -~"m•nly ,epresents upland areas. bu, rnov include unclass,hed W"11ond• such as man-mod1f1.,.J "'•••, non ph010-iden11!,able UHS end/er un,ntennonol omro•""'• OATE ___)~:___183 SCALE. 1;58 00Q TYPE CIR DATE ___t-.J_ __ SCALe ' '.,,., > •~"•• v,,ko•~ • H,~, "0 • ..,, "'"' > "'"'-" ,,,,,,,. ,..,, . .,,.,_, '""'" E -ESTUARINE .. AQl),,oca,o ' ., .. , , ............ ... . , ........... ""' '""'-"'"""'"'"""' ............ ,.,,,." L -LACUSTRINE •<-o.-, ,., .. ,_ ,0,...., 4 -INTERMITTftliT ' 5 -UNKNOWN Pt;RENNIAL es -c•.co,..ouo•TfO ·-· '"-"'"""' ·-' M.., ,.,.,.~ ,,...,. .... .. ,,.. l 1 , ..... "'""' ' '""' ' .. • o, .... 1 •~ .. , ..... ,.~ ... i,oo,,.V•Ka,., . ,,~,,,,, "''""' ' "'""•-, __ ·-'"~"' Oe, O;,o ... ,,R ', .. -. .,- • c-G•••~ "~' , .. '<>•,•n< MODIFl!:RS 1 ., .. , ,-~·-· ,,00 .. ,.,....., . '~,,,., ''"""' ,u..,now,,....,,._ ·-~,, ...... -' . " • ' ' I CONCORD SE, N. C. • • SCALE t'.24000 • 0,o .. - ACREAGl GUICE -1(00 "' T I Kil.Of""" 20 ICrM U.S. Q~PARTMENT OF THE INJ&t f)SH ANO WILDLIFE SEAVIC!, (llher information 1neluding a narrative NIPoM eonceming the -11and rasourees dap,ctad on this document may ba avail a bl,:,,. For mformatton, c:onuict:-, -,_ I 1· 1991 0 '"'°"'"' ... "'"~"""' ,._, ..... ,,.,,_ --~··-,..,,., .. ·-,,,.. ..... , ,i_,, .. .. SPECIAL MODIFIERS Regional Clractor (ARCE) Region lV U.S. Fl1h and Wildlifll SllfYlce 76 Spring StrNt S.W. Atlanta, GN,ul■ 30303 111 -MARINE ~--,-~-~~----1--, UI -\,r,r:o•<:IQ(-TEQ _,. ·--·-, .. •o.-- .., _ _,.n,, • I R -RIYERINI!. 2 -LOWER PERENNIAi. ... -•-o ·-~ ··-· , __ ,._ ·-.. _ , __ ... _ _,,,,..,...: ,_ ,, __ _ ,.,., ... ,_ .,...,, .. ,. ...... ·---·-·- -smc,..,a,o n '~""' oo """'-..,. ,.,....,ffl.., ...., ........ -....,_ ,.,. -C'-""' n .. ""'"""'"' "'-«sm; ..... ,"""'' 4 ........ .,.,..,"" '°""' --,..,.....,. ... , .. __ ,.,. -'" •• "'""'"''" 1 )• oc,ell··""""-"" -""""-,,;_!, ' ..,,,.. . ,. ' 1,,,.,,.G_ ,,,..J ' ,.. 4 -'~E!lMITTENT 5 ~ lJ-NJo:NOWlill'ERENNIAL .. ,,, , c,_.,;,_, . -·~ ·~ ~ .... l ·-· "" -""°"""""°'"° ...__ --· ... -, .... ,., •• -. ,_, I ,_, ' . ' .,,..,,....,....__ ,-..... ~ .. "'"'-· ·•-.--.. -' ", .. ,.., ·~-~- '"°""' "''"' ,._ ·~-·'"'- i ~ , . ._.,.,,_ • s,,., .... , ........ , . .._. 0 ,.__.,,_ "-"'··~ ·-·-~-· , ......... ~ .... . , ... ""' ._,., ,_,_ ..,,..,.. .......... • .. _,. ____ .... ____ ............. -...... -, __ _ ,.,, _ _,_,.. .... .,_,_..., .. _ .. __ _, __ .,_,,.._i>,.. II, ........ _ ..... ........,_ Non-Tidal " .... --~i ....... , "''•·--•"-' .... ~ ... ., ..... .. ,_,_,_ .,_ ,,-..,,.., .. ,_..,, ·•-· •1.-•w ,.,_,..., ·- • C-al lllllnlty 11n11Y pJ M ·--·, :·,'_,,. -~ ,._ .. _ ,--w ·- ·---• -;I, • ' :=:.. ·-, ' ' ' . 000 " "'. . . . . . . ~ . ,S l II I~. 1~: ,. \ '1 ~ MIDLAND, N.C. PARTMENT OF THE INTERIOR ISH ANO WILDLIFE SERvtCE ·~---, __ -· ' .. ,_.__ .. • ~-:;. II'' ·-·-·--> >E...,,_, SPECIAL MODIREIIS SYSTEM SUBSYSTEM - SY8TfM SUBSYSTEM - A GEOCHEMICAL ATLAS OF NORTH CAROLINA by Jeffrey C. Reid NORTH CAROLINA GEOLOGICAL SURVEY BULLETIN 93 STATE OF NORTH CAROLINA JAMES . UNT .. R r.o li'.R » RALEIGH MAY 1991 (REVISED 1993) DEPARTMENT OF ENVIRONMENT, HEALTH AND NATURAL RESOURCES ~ ,..., ' N w I I -- - - - 0 0 O 0 .. 0 • 0 • ·** 0 • • • Cu (Copper) Symbol PPM Percent of data 1 · 2 16.3 1\ Number of Samples: 46 1 0 0 3 · 5 48.3 Sc a I e I : 1 , 5 8 4 , 0 0 0_ * 6 · 8 71.3 I 0 1 S 50miles • 9 · 215 100 83 82 I 81 80 79 - --I -- Cr (Chromium) o t_ a I N um b e r o f S amp I _e s : 45 8 7 S c a I e 1 : 1 , 5 8 4 , O O 0 . 5 I 0 2 l I 50 mi J., -I --I!!!!!!!!!! l!!!!l!!I Symbol • * • I == I PPM 2.5 5 · 6 7 · 11 12·3,010 liiii liiiii I -- --I **• * *· . * •• . . • • • • ___. • :---'· ·c:·~4-.~,,-,' ea er h ,. · .e rlotte, Mecklenbu ounty, NC,._' ·: .; ':'._,•:· • 982 096 653 : . . 0-*·•"-o~· ... : .. :-. 0 . . "' .. •• Percent of data 24. 7 43.5 74.2 100 -- - - 11!!!!!!1 l!!!!!!!I l!!!!!I I!!!!!!! l!!!!!I Fe (Iron) T o t o I Number 0 f Somples: 6 3 3 0 5 c a I e t : I , 5 8 4 , 0 0 0 1 D n ~o mi-I,, == Symbol * • 1111111a 0 -•• • • ·** •• PPM 2,500 · 12,400 12,500 · 22,900 23,000 · 29,300 liiiiil liiil Percent of data 25.1 49.9 61.7 39,400 · 358,100 100 lilili --- * • . ~ ""' . ..... . , . . .,-... An (Manganese) al Number of Samples: 5 27 3 S c a I e I , 5 6 4 , 0 0 0 l 0 l 5 5G mi I H 0 .... \ * 0 * ;;;a • 00°. 00 •• • . 0. O O 0 * 0 • • o, 0 *: • : o. • D ' • • 0, 0 0 .. Symbol 0 * • •* • PPM 20 · 210 220 · 500 510 · 960 970-11,620 liiii ----liiil 0 *. . 0 • • ·* ·o . it"-:+-e•:+:e *0 00 oo * • •:+=+; · Percenl of data 24.5 50.1 74.8 100 -:Jt?!od'oo * 0 00 0 0 **. • 0 • 0 • ..o (I : -·: 0 . * . 0 • 0 •• . -.il\a< • • • 0 0 •• * * * 0 • *•. : .,.,. 0 - - .J.. - - -I Pb (Lead) T o t o I Number 0 f Samples: 0 9 6 S c o I e 1 : 1 , 5 8 4 , 0 0 0 S I 0 1 S -50 mi Its I - ' 00 - - - Symbol !!!!!I PPM 5 10 -12 13 -2,597 I "' == ~ liiiii I Percent of data 56.8 80.4 100 RO 79 I ·• ,, . -' ' • .. I ' ' ' . ~-> . ,•• ' . ' ,. ' , .. ··i '1" -~' ,,, ' \. I ,1·/ \ \~\ 1\··\' ••. ,,_, t.J,)i 11\\,, ,, ~ .J• • '~ ,I .,J' f • • , ,. ' \' \' .. • ' ' ·' l • I i i- i I I '\ l I'<\ I ) I I ,i i I ' I I I /: 1\ ·!j '-.,_ 1\ ~ ""1 . " 1; . ,,, -......_ "'-', " \c\' \ 'l) I I~ i 0 ''K, "',, I \.j ~ '-.,_ INl)EX AN ENCYCI_O/'EDIA OF CHlcMICALS. DRUGS. AND BIOLOCICALS !'UBi.JC HEALTR [IBRAR'il'•, ... 0,1/iS!ON OF HEAL TH SERVICES f'. O. BOX 2091 'l/\\.E.IGIH, NORTH CAROLINA 2760? "" " ~ TENTH EDITION Martha \Vindl10lz, Editor Sus~tn BudavarL Co-Cditor Rosemary F. Blurnctti. Associate Editor Elizabeth S. Otterbein. Assiswnt Editor Published by MERCK & CO., INC, R A H W A Y , ~J . J . , U . S . A . 19 8 3 Reference. 25 · 9450 l, 1,2 ~Trichlor!>Cthanc 9450. 1,1,2-Trichlorol'thanc. \/111yl t1·i<:hloriUc Cil·l/::JJ; 1110! wt 133.-12. C 18.UO%, H 2.27'X,, Cl 79.73%. C1i 1 C!- CHC11. l'rcpd by cataly1ic chlorir1ation of cthanc or clhy). <:nc: Joseph, U.S. pat. 1,752,401 and !'ye:. U.S. pac. 2,752,- 402 (hoih 19.Sli lo 1),)1'); Rcy1rnlrk U.S. pal. "2,783,286 (I\)_<.·; ·10 Olin ,\.fathie.,011) dry deaning. In the n1:tclui uf 01·ganic cl1cn1ic;,I,;, pharm~::_•: ccuticals, such :1.\ c/1loroacetic acid. '!HERAi' I.Ar· Analgesic (rnl111l<1tion). ll!EH.A!' CA'i' (vr:r): /11hala111 /JiiC.'illieric I'.,mfla1m11at.,k liquid; pk,is,un nd0r: di0 1.-!416; s<1/idif --J5"; lip llJ-1/4•: nfJI l.•171) ln~,,I in w;itt.:i; lllis<: wi1}1 ,ilcohul, c[hcr, aJ1d 111:iny •ltlia (Jrg,,11i~· !iql1id.~. 1.,1)~ 0 orally in nHs· 0.5H ml/kg, H. I~ Slllyth f't al. Am. Ind lly!'.-/1.uoc. J. 30,470 (!%9) .9453, Trichlorof!uoromcthane. Tric/i IPH>rnonofluo;g/t n1ctl1«nc; f111,,rn11ich!u1·,>11,c11l:111c: Fre,JI\ I]: _F1igcn ·1 \;.' .'\rctuu ~l CC!JF; rn.il wt IJ7 .. \H C 8.74'.',;'.,, Cl 77.43%, F JJ.8J%. l'n:rn· He1111c, 01xll11ic· H.,:a,:1io11s 2, (A (1944).: Mamir:' Fa11h, Keyes & Clark's lnd11.Hria/ Clremica/J, F: A.:' Lowenhcim, /v1. K. ,\-lora11, Eds. (Wiley-lntcrsc1c1Jcc, New• USE Solve1H foi fais, wa.v:',, na(ur,d resins, alkal,)ids. Caution: l1Tita_ting to cycs, lTllK'U\IS m..:mbral/c~. and, 1n high coI1cns, 11arcn11c. 9451. 2,2,.2-Trirhlorot"t/1,inol. · Tri~·hloroethyl ,iko!iul. CiH3CIJO; 11101 wt l•l:l ,12. C 16.08%, ff 2.02';;,, Cl 71. J './',',;,, 0 I0.7J'J:,. CCIJCl!/.11!. !'repd by r..:du<..tion of lh,; cone~- r,mdi11g ,:stcr, a<:id diloridc, ur acid wi1h lithium alwni11u111 hydride Siuog e1 ,J/., J ,·!111. Chc111. S,;c. 71, 1710 (1949). Manufacture b_y 1<:dt1ctio11 of chloral hydral,: wi1Ji an ;,mine boranc: Chamberlain, 5cl1cc::ht,:r. U.S. jl.tl. 2,li9H,J79 (]')5') to C.illery Che,11.l. Jlyg1n\cnpic: li,1uid, ,:1l1cr,:a! odo1 :\i 1().11' \ct11ps ii c1y:,- tallizt:s in rhur11bic tahlei.~. 111p ;11 1~•; lip 151-153°; dfg 1.55. Sol in about 12 1>.irt.\ w:1tcr: 111i~cible 11i1h alcohfJ/ or t:ther. pl/ of ;iq soln i~ -~·6, h111 on i,1·0Jonged ,·n111;,c1 wiih w:i1e1 snni',: free acid is fnnned A."1!r'j1 k'c// r:ln,,'d and prurect,:d from lighr. LD50 or;1ily in rat.\: _(JCX-) mg/_kg, fir.mt/boo/..:. of '/(uicol- ogy _vol. I, W .'-. Src:.;ror, Ed. (Saun,kr~. Phi)addph1;1, !')55) Pr .102-303. THEKt\l' C,\T: 9452. Trich/oroethylenc. Trich/oro.,_•1he11c; ,:tliir1yl tri- c.:hl\)J'\(k; Tri-Clc11c: Tridc11..:; T1 iknc: Trichlonw; Trichlo- rc,1; Algylcn; Trirnar: Trili11c; Tri: Trc1hvl..:nc; \\'eslr(>~o/: Ch!orylcn; GcJnalgcnc: Germalgc11c c\HCJJ; rnol wt 131.40. C 18.28%, Ii 0.77'/4,, CJ 80.G5';.;,_ cc1;=CHC/. u~unlly prepd frorn sym-tctrachloroc1!1a11c by climi11atio11 l1f HCJ (by boiling w11h limd: (,'er. p;lt. 171,900, lly p:1ssi11g tclrnch!oroetha11,: vapor ovc:1 CaCJ2 C<1taly.<,1 ,It 300"· Ccr. pat. 263,457; without catalyst nt 450-470°: Brit. pat. 575,- 530 (1946 to du i'ont) Review of mfg procc.\scs: S. A. Miller, Chem.·l'mc,!s.1· 1.:.:ng. 47, 2(,-f: (J,)6b); Faith, Kt:ycs & Clark's lnd11s1ria/ Ch,'111ica/s. F. A Lowcnlwirn, ,\.1. K. Moran, Eds. (Wilcy-lntcrscicncc, New Yor·k, 4th ed .. 1975) pp 844-8-fS. Toxicity :ind me!aholi.\111 E. Browning, '/()xic- ity ,me/ Afi!lubolism of l11d11.1·1rinl Sv/-.-,-111s (F,Js(:1·icr. N<.:1\ York, 1965) PP I s:1-212, York, ·hh ed., 1975) Pl' :'!25-JJ0. -Liquid a1·1e1nps hdow 2J.7". 1:aint cchcre.il od,)r Non- flamniabl,; .. dl7-' l.4:14: d;;, 5.0-1 (ai1· = I) 111p -l 11' bp 1 1,11 2J.T; bp,11>(1 -1-1>.IL bplllO ··-'J.!": hru>O -2}(1° bp,,o -321', bp,111 -39.0~; bp1,1 -49.T:_ hprn -·59Jt, hp~ --67.6°; _bp 10 -84.J". Crll tc111p l'J8°: cnt prc:ss. 4J.2 atm (6}5 lb/sq incli, ab~) nhu 1.3865. IJipnlc 11101nc11t 0A5. l'rac1ic.1ily inso! in. water. Sol in alcohol, ether, other, organic snlvents. LeSS• 1 - toxic lhlln carbon dioxide,-h111 dccornposes into harmfllJ'.;· nwtc1ials hy flunies or high heal. .,,-, USF, In 1dng.:1·atio11 1nacllin,:1')' rcquirir1!i" r·drigerant cf.~_. k..:1i1·c ;it negative prc:ss11re.~ As aerosol propdl:l.nr. CGri-',~, I rinn-r\-f,1y (J<; ri;11crnic in high concc111rario11s. ' :;.'~/;\, f•/01e: Con~ult latc.q Govcrnrnenr rcgu/arions on u~c .. a's"'; ... : Hcrosol pmpdl1111t. _'.;\t?t 9454. 3;4,6-Trichloro-2-11i1 rophe11ol. 2.a)'-./itr11-J,4,6-1ri: fr; clilorophcnol: 2,4,5-trichJuru-6-11i1ru11!1c110/; Dowlap .. ·c 6 ._,,,,;0~, HiCl3N03; 1110/ wt 2·12.4•1. C 29.72%, H 0.8.1%, Cl 43.87%,\>t_\·. N 5.78%, 0 19.80%. l'rcrd hy dissolving 2.4,5-trichlorO?g;(,., phenol in glaci:1I acc1ic acid and lrcatlng with coned fll_t1;-fC,~'f/ acid: Kohn, Fink, Mnnur.1-h 58, 7.1 (!9.ll); Harrison et'a/ .. ;J:<}.;:I; J. Ch,•n,. ·'"' 1943, 235. . <I¼11! '1~~ ii ~{j~f.j l'alc yellow cry~tnls frorn petr· eEhc::r,·mp 92-91' ''.k~T~ USE: To c.:ornbat the ~e;, !a1111,r.:_y, .111 eel-like fish wh1cI1.,~i• attacks trout, especia!ly in ihc Grc'at Likes region -~ ~';w,;,..I • > ~ ,,l .. 9455. 2,4,5-Trichloroplienol. Col!unnsoJ; Dow1c1de l½''--;j C6HJCI30: lllOI IV( 197.46. C 3(i.49•;;_,, H !.5J%, 0 8,!0~}/;_.cl,;,iin~; .~3.87%. !'repel by_ tr<:a!ing i,2.4,S-1c1rad1lorobcnze,_1~.·\Y!~'tlf;"-\fj rncthanolic Na OH 01 aLltocl,1vc at !60° for. several hrs: '-~~r-,;t~] rison er al., J. Che111. Soc. 1943. 2J5; Agfa, Ger. pat. 4IJ,?~-2~~(i- (l 925): Clwni. 7,?nlr. 1.92.:i, ! . 2-! ! I · ·;;;:~ . No11flamnwbl<.:, 111obilt liquid. Charal·tnistic odor rcse111- bling that of chloroform. di l.4'.104; df 1..1695; df0 1A649. YarN dc11.\iry: ·l.53 (air = 1.00). Solidifies a1 --84.R°. bp7f,(I 86.7°; hp-$<XI 67.0"; bp11"1 48.0°; hr1r,) JIA-0; hpf,!J 20.0"; bplU -1.0·; bplO -12.4"; bps -22.8°: hp]_[) --43.8"; nil !.479]4; 11&5 l.45560. Pr:tctic-ally insol in water; rni~c wi1h ether, :ilcohol. chlor,)fonn. Dis~o/vcs mu~i fixed a11d v()latilc oils. Slowly dee (with fonnn of HCJ) by light ir'1 the presence of moist11re. Tricl1Jorllcihylene f(lr mcdiCinal purpo.~es 111;1y <..'.Ontain so111t; tliymol or ,1nu11oniun1 carbonate (nut more than 20 nig/l(XJ rnl) :1,; a ~lahili1er. lnduqdal grade.~ of lri- d1lorncthyle11c rnay conr,1in other s1ahili1er.\ such a.~ tri- e!hanolmninc .~tear at<.: •rnd c1e~ol. l"l)}(I ora!Jy'in ra1s: 4.92 nil/kg: LC (4 hr,) ill ral.\: 8000 ppni, Smyth N ri/., .11h f11d. !lyg. Anoe J. 30,470 (1'!69) Ca11tio11· Use 1,·itlr 11dequ,1tc 1•en1ilano.,; l'n.::serve lriclilo- r0o::thylcne in .~e<1kd, /ight-resis!ant arnpu/s or in frnngihle, · light~n:sista11t gla~.~ tubes Avoid prol,mged cxpu~un:·(,f lhe prc)duct to CXCt\ssivc he:11 It must b<.: d1~jll'llSed in the _un- 0pc11,:d glass Cn'111ainc,· i11 whid1 it wa~. pJnccd by the 1na1,11-facrnrer. ;,:;,, Needle.~ fr-o!ll alcohol or li~roi_n. Stru;ig phenolic o~J..5'1. mr 67". Sublime~. br7.v; 248", bp760 253". Weak monob!lf_. acid. K :1t 25°· = 4.J >< IO-~. So!y (g/ JOO g of sol_vt:,~t.{a_~ 25"): acetone 615; bel!Zcnc 16]: carbon tctrachlonde;,N'. ether 525; cknatured alcohol formula JO, 525; mclhanol 6 ! liquid pctrnlnturn (ai 50°) 5(,; soyhea11 L,il 79; toluene.,'. .... water <0.2. LD_,0 orn!Jy in ral.~: 0.82 g/kg. Dcic!!~.a!!.n• Fi·d. !'roe. 2, 7(, (J 9-IJ). , .. Si1_ditm) ~nlr scsquih~·dra1c, Oowici<fr IJ. Flakes fprepd:tc; <:ordrng to U.'S. pat. i,991,Jl9 (193.5 to Dow)J.· Solu_b_i~.~ (g/JOO g solvent .ir 25"); acdonc 16J;.denatmed·a_lf~-= formula JO, 186; ethylene gly<.:o/ 33; rne1ha1_)01·24,.\,'7';~ lh,mon '/Ox/L'.ity: 1\1odcn11c c.,po~ur.:~ c;111 -cuu.~t: .\y111p- torns similar 1o alcohol inchriaiion. J!igh.:r cr.11icns c.;111 !i;ive · nar..:otic eff.:ct. Ocalhs (1ccurring after he;iVy l'X[)()Sure have been attribu'ted to ventriculnr f1brilla1ion.' Liver injury is 110t definitely. establi\l1t·d in occ11patinrial t'\P<h111'c.~. r()1111d !o I · induce hepa1ocdlt1lHr carTinornas in Na;io11a) Cnn.::..:r.l11s1i-/ lute rests.on ni1cc Chem. <t: eng, Ne'w.1·,<;4, 4 (Apr._<;, 1976). ljSE Solvent fo1 facs. wa;v:s·, re.,ins. cJils, rubber, pain1~ .. / and varnishe:~. So/v,:nt_for cdlulos..: es'ic1s and ether~. Use,! 1 / f,!: .~(>lv..:nl c.\t1«crirm 111. many indu.~1ric:~. In ,lcgrc:isi1_1g. iri higc 1378 J 13. pH of satd aq soln I l.0-13.0. . . ..."·':.l:• Co111f)lcx with lrii.~_obutyl p!1_ospha1e, CIHJ f?./=t~:r~h chlor1.1x. l'rqm: lloudlcnnc-\\allrand el al., Ir. P ·. -, (196! i'o l'echincy). Liquid. iip0_01 94-IOJ•. US!c:: Fungicide, haclcricidc ._'.:'s'J 9456·. 2,,(6-T~ichlorop/1enol. Dowicide 2S; Orn;~·~~ H_/::130; 111ul wt !97..tii. C .fo.-19'/4, 0 ~-10%, ,If I. .,_,.~•.•.1 I I I 11 11 . l II II; i i . .• i ' \ : I! . I I I Ii ( Ii I Ii I I I I I /-/awley·s Condensed Chemical Dictionary TWELFTH EDITION Revised by Richard J. Lewis, Sr. ~ VAN NOSTRAND REINHOI_D COMPANY ~ ---c--~------New York Copyright© 1993 by Van Nos11·,:11d Hci11huld Libi·ary or Congress Catalog Card Number 92-1895 I ISBN 0---t,12-01 ! 31-8 Al! rights reserved. Cenain portiom of 1his wo1k@ 1930, 1920. 1919 by The Chc111ical C:w:ilog Cu., !nc., and 1987, 198!, 1977, 197 I, 1966, 1956, 1950 ~y Van Nostrand Reinhold. No part of this work covered by tile copyright hc-rcon may ho.: rcprnduccd or used in any form or by any mc:.rn~--graphic, electronic, or mechanical, including phl)• 1ocopying, rccordi ng, 1api11!!, or i11l01 t)l:l! ional ~to1·agc and re1 ricv.-il systcllls-without wriltcn permission of the publi~hcr. · · Printed in the United Stat<!S of A111c-iic:1 Published by Van Norn and Reinhold 115 Fifth r\YCllllC New York, NY 10003 Ch:1prnan a11d Hall 2-(, Uc.,uudary Row London, St:1 RHN Thuma~ Nclsun ,.\11s11·:1lb !02 Dodd~ Street So111b 1\lelbournc 3205 Vic1oria, t\u,~tralia Nel.,011 Canada I! 20.llirchmouni Koad Scarborough, Ontario ,\1 \K 5Ci4, C111:ul:'\ 16 is 14 13 12 11 10 9 S 6 5 4 J, 2 Lilmuy llf Cung1 css Cataloging-in-l 'ubli.:a( ion Data (011<.lcns-:d cl1c:nic:1l clictlonary. Hav'l'lcy's condcn~cd cl1-:1nical dictiCT11a1 :, .--12th d./rcvi~i:d by Richrnd J. L~·wi.s.;·Sr· p. cn1. 1Sf3N 0.~,i42-0l 13 l-8 !. Chcmistry__:_Dictionarics. 1. llawlcy. (icssncr Goodiich, 1905-!98'.\ II. Lewis. Richa1d.l .. S1. fll. Title. l)O5.C5 1992 540; .J-dc20 92-l 895 l CIP ;; UL a · aa:nrw.zr . AZ&lX am:.::azuwwwt41!/Jt4CD.®W w .iiEUQ.~,mr:;;.;;wK& ~ 149 N ,N,BIS(2-II Y!lROX YETI I\'!.) Hazard: Toxic by ingestion. A carcinogen. TLV: Q.001 ppm in air. C,,H ,(CNH7H ,,), Properties: Amber 10 red liquid, d 0.90, fp 7.2C. Con1bu.stible. Use: Gasoline antioxidant and sweetener. ,, Use: Intermediate for ion-exchange resins; labo- ratory reag,cnt. i:;. · 3 J-bis(chloromcth:yl)o.xctnnc. Sec'' Penton.'' } ' \~ bis(p-chlorophcno.xy)m-cthanc. (C1Cr,H/J);;CH2• ,/ properties: Solid, rnf)'65C, insoluble in water and ~·. oils, soluble in ether and acetone. ri;is(2-cthylhc.,yl)phthalate. c,,1-1,p,. Liquicil ~.sed 111 vacuum pumps. ,_J Use: Acaricic.Jc. 2,2-bis(p-chlorophcnyl)-J, 1-dichlorocthanc. See TDE. I, l-bis(p-chlorophcnyl)cth;1nol. See di(p-chlorophenyl)cthano!. : .1, I' -bis(p-chlorophcnyl)-2,2 ,2-trichlorcthanol. ( 4 A' -dichloro-a-t rich loromet hy I benzh yd ro I; Kelthane). CCl3C(C6H,Cl),O)f An alcohol analog of DDT. · Hazard: Toxic by inhalation and ingestion. Use: Miticidc. ,· bis-cyclopcn tadlcnyliron. Sec clicydopentad ien- ', yliron. ·· bis(2, 6-d iel hy I phcnyl)carb odi i m ide. l' ,· (CH2H,),C6H3NCNC6H3(C2H,),. f,; Properties: Light yellow to red-brown liquid with · faintly acrid odor, ct 1.007 (20/20C), bp 192-194C (0.4 mm Hg), refr index 1.591 (2JC). Solu-ble in organic solvents. Combustible. Hazard: Toxic_ by inhalation. Damaging to eyes. Use:· Stabiliiers in polyester and urethane sys-tems, intermediate for textile chemicals and pharmaceuticals. :(· .{i 2,6-bis(dimcthylaminomcthyl)cyclohcx:inonc. ~ [(CH3),NCH2J,C6H.0. 'er Properties: D 0.95 (20C). ~.· Use: Preservative for aqueous paint systems, ca-(·· sein, pigment dis·persions, and adhesives. r~,6-bis(dimCthylaminomcthyl)cyclohex:rnone f. dihydroehloride. C,,H14N1O·2HCI. ~--Properties: Free-nowing, white to off-white crys- {' talline salt. •'fi· Use: Preservative for aqueous systems, latex ~1·: paints,• acthesiv.e.s coatings, wax emulsions, ca- sein, and starch solution. \. bis(I ,3-dimethylbulyl)amine. ':' .,[(CH3),CH2CH2CH(CH3)J,NH. :;,I)opertie_s: Liquid, d 0.772-0.778 (20/20C), dis-~,ltiHation range 179._0-205C, bulk cl 6.5 lb/gal, ';.flash p 160F(71.IC). Combustible. 't ~it.;t . ": · N ,N' -bis(l ,4-dimelhylpentyl)-p-phenylcne- f~~dillmine. (diheptyl•p-phenylenediamine). i..N .. \. N, N-his( t -Cthyl-3-mcthyl pent yl)-p-phcnyl cnc- diaminc. C6H4(NHC8H 17)z. Properties: Dark, reddish-brown liquid; d ap-proximately 0.90; bulk d 7.5 lb/gal. Combusti- ble. Use: Antioxidant for polyunsaturated elasto- mcr.s. 2 ,2-his(p-ctl_tylphcnyl)-l, l-dichlorocthnnc. Sec I, l -clichloro-2,2-bis(p-cthylphenyl)ethane. hiscthylx:inlhogcn. (C2H5OCSS}i. Properties: Yellow needles, onion-like odor, mp 28-32C, insoluble in water, freely .soluble in benzene, ether, petroleum fractions. Grade: 580Jo soluble in oil. Use: Weed control, rubber accelerator, fungi- cide. 1 , 3-b is(J-glyci d oxyp ropyl) tel n1 mcth yld isi I oxanc. [OCH2CHCl-l2O(CH2),Si(CH2),l,O. Properties: Liquid, d 0.99 (25C), refr index 1.4500 (25C), bp approximately !85C (2 mm Hg). Soluble in acetone and benzene, insoluble in water. Flash p ·300F ( 149C). Combustible. Use: Chemical intermediate. hishydroxycoumarin. [3 ,3' -rnethylcnebis( 4-hydr- oxycoumarin)dicoumaro!J: C19H 1206. Properties: White or creamy-white crystalline powder, faint pleasant odor and slightly bitter taste, mp 287-293C. Readily soluble in solutions of fixed alkali hydroxides, slightly soluble in chloroform, almost insoluble in water, alcohol, and ether. Derivation: (I) Originally extracted from spoiled sweet clover; (2) synthetically from methyl ace-tylsalicylate sodium and formaldehyde. Grade: USP. Hazard: May c.iuse hemorrhage. Use: Anticoagulant for blood. bis( 1-hyd ro:xycycl ohcxyl) pcrox id e. C6Hto(OH),O2. Properties: Fine, white powder; mp 66-68C. Ac- tive oxygen 6·.6% min. Hazard: Dangerous fire risk in contact with or-ganic materials. Strong oxidizing agent. Use: Catalyst for polymeriz.1tion of polyester res- ins. N ,N-bis(2-hydroxycthyl)ulkylaminc. Clear liq-uid used as an antistatic for blow molding appli- DIIIUTY LP! I ENYL l'IIOSPHATlc 374 linc-(satisfics ASTM D910-64T as antioxidant in aviation gasoline), prevents decomposition or tetracthyl !cad in gasoline. Hazard: Fire risk in contact with organic materi- als. Use:·Oxidizing agent. dihulylphenyl phosph:itc. (DBPP; phosphoric acid, dibutyl phenyl ester). CAS: 2528-36-1. C14HvP04• dibutylsebaeate. (DBS). C4H,OCO(CH1)sOCOC4H9• Properties: Clear liquid with butanolic odor, mw 286.26, sp g 0.0691 (23/25C), bp 131-132C, vap press 0.007 mm Hg at 25C, flash p l29C, insolu- ble in water. Properties: Clear, colorless,-odorless liquid; bp 349C (760 mm Hg), I SOC (3 mm Hg); fp -I IC; d 0.936 (20/20C); wt/gal 7.81 lb (20C); refr index 1.4395 (25C); flash p 350F ( l 76C). Insolu- ble in water. Combustible. Hazard: Combustible. TLV: 0.3 ppm in air. Use: Hydraulic fluids. dibutyl phosphate. (di-n-butyl phosphate). CAS: 107-66-4. Properties: Pale amber liquid, mw 210.21, mp (decomposes above I00C), vap press < I mm Hg at 20C. Hazard: TLV: l ppm .. Rcspiratory-tract irritant. Use: Organic catnlyst an<l anti foaming agent. dibutylphosphitc. CAS: 1809-19-4. (C4l-190)2PHO. Properties: Water-white liquid, bp 95C (I mm Hg), d 0.9860 (25C), refr index 1.4228 (25C), flash p l20F (49C}, soluble in corlunon organic solvents. Combustible. Hazard: Moderate fire risk. Use: Solvent, antioxidant, intermediate. dilrntyl phthalate. CAS: 84-74-2. C6 H4(COOC,l-i9)1. . . Properties: Colorless, odorless, stable, oily liq- uid; d 1.0484 (20/20C); fp -35C; viscosity 0.203 poise (20C): distillation range 227-235 (37 mm Hg); flash p (COC) 340F (171C); wt/gal 8.72 lb (20C); refr index 1.4915 (25C); bp 340.0C; vap press 1.11 mm Hg (i 50C); miscible with common organic solvents; insoluble in water. Combustible', al.ltoign temperature ap- proximately 750F (398.BC). Derivation: By treating n-butyl alcohol with phthalic anhydride followed by purification, which results in a product unusually free from odor and color. Grade: Technical, 99-100% dibutyl phthaiate. Hazard: Toxic. TLV: 5 mg/m3 of air. Use: Plasticizer in nitrocellulose lacquers, elasto. mers, explosives, nail polish, and .solid rocket propellants; solvent for perfume oils; perfume fixative; textile lubricating agent; .safety glass; insecticides; printing inks; resin solvent; paper coatings; adhesives; insect repellent for textiles .. Grade: Technical. .. Use: Plasticizer, rubber softener, dielectric liq-·_,, uid, cosmetics and perfumes, sealing food c~n-} tainers, navoring. , // ! _, N, N-dihutylstcaramide. C 17 H3 5CON(C4H9)i. Properties: Yellow liquid, d 0.860 (20/20C), boil-,• ing range 173-175C (0.4 mm Hg), flash p 420F._; (215C), fatty-acid odor. Combustible. di-n-butyl suCcinatc. C12H2204. _.,,~~ Properties: Colorless liquid, bp 120C, fp -29C,\ d 0.977, refr index 1.43. Derivation: Reaction of butyl cinic;1cid. Use: Insect repe_llcnt. di-tert-hutyl sulfide. (butyl sulfide). [(Cl-13),Cl,S. :-',\ Properties: Liquid, fp -I IC, boiling range 29.7.- 303F, cl 0.8316, wt/gal 6.93 Jb, rcfr index 1.411 (20C), flash p 125F (51.6C). Combustible. ,cf· Hazard: Moderate fire risk. Use: Intermediate, flavoring. . di butyl lartrate. :~. C,H,OOCCH,OCJ-1,0COOC,H,. . 'Vk Properties: Light tan liquid, mp 21C, bp appr,oITT imately 204C (26 mm Hg), refr index I ,44 (20C), flash p 195F (90.5C) (CC), combustiW autoign temperature 544F (284.4C), wt/ga_IJ0 lb (20C). Miscible with the common orgam~, so vents, oils, hydrocarbons. :._t:. Use: Solvent and plasticizer for cellulose ~~. and ethers, e!astomcrs, lubricant; rubbe_r, fabrics; lacquers; dopes; transfer inks. 2,5-di-tert-butylquinone. [C(CH1hlzC<,H202. Properties:·Yellow powder; mp 149-lSIC; in.sol- uble in water; soluble in alcohol, acetone, ethyl acetate, and benzene. dibutylthiourea. C.1H9NHCSNHC4H9. :• Properties: White to light tan powder; ffi{?,}: 69C; slightly soluble in water; soluble in -~~,t no!, ether, acetone, benzene, ethyl acetate_;_\~s uble in gasoline. J,:';, Use: Corrosion inhibitor, for pickling ca~t 1i:,9: carbon steel, reduci_ng corrosion of fcrro~s;,., als and alurninuin alloys in brine, interrn~~] di hu lyltinhis(lauryl) rncrcaptidc. (C4H9),Sn(SC11 l·l"),. . ,,_. Yellow liquid, tin content 18.5%, solub~e !R enc and heptane. · · DICALCIUM SILICATE 376 dic:ilcium silicate. 2CaO·SiO2. One of lhc com- ponents of ccme,it. Non-combustjblc. Occurrence: Obtained as a by-product in clcccric furnace operation Use: Used to neutralize acid soils. Sec cement, Portland. "Dicalile." TM for a group of products made from either diatomitc or perlitc, used in filters and filter aids. See also dintomaceous earth. dicamha. (generic name for 3-6-dichloro-o-anisic acid (2-methoxy-3 ,6-dichlorobenzoic acid). HOOC(Cl)C6H2Cl(OCHiJ. Properties: Crystals, mp 114-116C, slightly solu- ble.in water, moderately soluble in xylene, very soluble in alcohol. Use: Herbicide, pest control. dicapryl adipatc. C8H17OOC(CH2),COOC8H17 • Properties: Almost water-white liquid, bp 213- 2l6.5C (4 mm Hg), flash p 352F (I 77C). Com- bustible. Use: Plasticizer for vinyl resins and cellulose es- ters. Sec also capryl compounds. dicapryl phthalatc. (DCP, di-(2-octy!)phthal- ote). (C8H17OOC)2C1,H,. Properties: Colorless, viscous liquid; bp 227- 234C (4.5 mm Hg); fp -60C; rcfr index 1.480 (20C); ct 0.965 (25C); nash p 395F (201 C); insol- uble in water; compatible with vinyl chlori_de resins and some cellulosic resins. Combustible. Use: Monomeric plasticizer for vinyl and ce!lu- !osic resins. See also ca pry I compounds. dicaprj') scbacatc. C8H 17OOC(CH1)8COOC8H 17• Properties: Light sfraw-colored liquid, bp 23 l .5- 239C (4 mm Hg), nonvolatile, gives excellent low-temperature flexibility, flash p 445 F (229C). Combustible. Use: Plasticizer for vinyl resins and acrylonitrile rubber. Sec al.so capryl con~pounds. dicaplhoi1. (generic na[ne for O-(2-chloro-4- nitrophenyl) O,O-cliniethyl phosphorothioate). (CH3Ol,P(:S)OC6H3(Cl)NO2• Properties: White solid; mp 51-52C; insoluble in waier; soluble in acetone, cyclohexanonc, ethylacetate, toluene, and xylene. Hazard: Cholinesterase inhibitor. Use may be re- stricted. Use: Insecticide. dicarhoxylic acid. A carboxylic acid containing two -COOH-groups, e.g., adipic, oxalic, phthalic, sebacic, and ma\eic acids. dicctyl. Sec dotriacontanc. dicetyl cl her. (dihexadecyl ether). Properties: Crystals, mp 54C, bp decomposes at 300C, d 0.8117 (54/4C) Use: Electrical insulators, water repellents, lubri- cants in plastic molding and processing, anti- static substances, chemical intermediate. .dicctyl sulfide. (dihexadecyl thioethcr; dihexa- decyl sulfide). (C161-lll),S .. Properties: Solid, mp 57-58C, bp decomposes, d 0.8253 (60/4C). Use: Organic synthesis (formation of sulfonium compounds). clichlobcnil. (generic name for 2,6-dichloro- benzonitrile). Cl(Cl)C6 H3CN. Properties: White solid, mp l 44C. Almost insolu- ble in water, soluble in organic solvents. Hazard: Toxic by ingestion and inhalation. Use: Herbicide. dichli•f cnthion. (0 ,O-diethyl-O-2,4-dichloroph enyl phosphorothioate). CAS: 97-17-6. c101-1"c120,Ps. Properties: Colorless liquid, bp 165C (0.3 mm Hg), d 1.30, refr index 1.52, slightly soluble in water, soluble in organic solvents. Hazard: Cholinesterase inhibitor, use may be re- stricted. Use: Pesticide. dichlone. (Generic name for 2,3-dichloro-1,4- naphthoquinone). CAS: 117-80-6. C10H4C1202. Properties: Yellow needles; mp l 93C; soluble in xylene and o-dichlorobenzene; slightly soluble in ethyl alcohol, glacial acetic acid, and.carbon tetrachloride; almost insoluble in water. Hazard: Toxic by ingestion and inhalation, irri- tant to skin and eyes. Use: Seed disinfectant, fungicide for foilage and textiles, insecticide, organic. catalyst. d ichlo r:1111 in c-T. (p-tol uenesul f ondichloroamide). CI-I3C6I·I,SO2NCl2. . Properties: Pale yellow crystals containing not less than -280Jo nor more than 30% active chlo- rine. Chlorine odor; stable when pure, decom- posed slowly by air, rapidly by impurities, petro- latums, kerosene, olive oil, and alcohol. Soluble in glacial acetic acid, chlorinated paraffin hy- drocarbons, eucalyptol, benzene, chloroform, and carbon tetrachloride; almost insoluble in waler; mp BOC.· Derivation: Product of the reaction between to!u- \ •:: f,1 ,. \ .~, 't ' , ··; -~;,• ),, -·~ ~it \\1 .',;;;. . ::; ·\1), 1~:t ·,.:so ~,\. )k-i'it~ .. ,,.,,,, ~f iJ;;rt,•. rti,r. -?,~'@ iii, ;<i-',li~· £ft ' ~'m'. ·, ~ ~· , ... t. 1,.1• . • }','T1-' ,ti;:;~ -'.. > ~ .} ..i -:,:· ·\ :,~ ., ., -f \ :t ,g :, ~; . ~ ; :·• ' ' i -·~ \ . •. 'i; i~f·rcon" j/)11 l'onr]. ·ri\·1 fo1· ;1 :;l'l'iL'S 11i· i'luorn- -~'.-carbon pnxiu(l~ US'..'d in 1l'1'1·iger:.lliu11 ;111d ,1ir- i.-, conditioning cqu1plll<..'ll\. ,1s hlowin1:; :1g1:111.,. rirc- 7.(:xiinguishing: :1gcn1s, and clc~rning fluid.\ :111d ~\olvcrns. ?·,;ropcrtil'.'.>: C:k;ir. 1v:nl'r-whitc iil!Uids: l':ipu:-~ ;\'·havt: 11 ;:1ild so1,1~".dia: ct!v~rc,i\ odor ;ind :·11 c no! ; _· irrit ;II i 11g; cssc111 i:il !y st ;1 bk :1 nd i nen. No 1i-i'la111·· _,::_ mabk, 11(1nc.\plosivc Nvncorrosivc. Fnr list- '.:";~-,.ing of .spcci fie 1 YP'-'~. Sl'C fluornca rbon. ·t'.·:vore: Many 1ypcs C(lrHai11 chlorini.: as well as nu~ ·~1~ orine :111d should be c:!llcd chlorofluorocarbons :-·· !V11 /'om]. See l, 1, 1-chlmodifluo- 1n11 l10111]. syrn-tttrachlorodi!1uom-. ~}~'reon C-51-12" \!)11 l'onr\. Sec pcrfluorodi- ;.: met llylcyclobu t a11e ?·· '?l"°Frcon E'' ! !Ju !'<!llr). Ti\·1 fur a Sl·rics of' llydro- ·ggen cn<kapped lt'lrarluorocthylent:: cpo.\id·~ Tpo!ymers having <1 DP up tu I 0, boili11g, range .0•-39-'-l90C, high dielcum: constant. >' Use: Cool:in\s in cll'crrnnil' devices, ~-. ·.•f, Frl'undlid1 isotherm. Tht: ri.;l:1tionsliip buwccn ··1hc amount or a substan(T adsorbed and the concen1ra1io11 of the sol11te: X I :::= Ken Ill ;• .).'·when: xis 1he amount aclSl)rbcd, 111 the weight or {~_:.: adsorbent, c ihc rnncc11t1aiion or· prcss11re, and -Kand II COllSUUll~. Freu 1111 's acid. l -Napht hylarn inc > ,(i-d isu ! rnnic acid. Freund sy11!hesis. F()!'ln:t1io11 nf alicyclic hydro- carbon~ by till' ;1ctic,n nr sodiu111 (17reund) 01 zinc (Ciust:1vson'l 011 opc11-cllai11 dihalo curn- pouncls; l ,J-did1lnropropa11c derived from the chlorina!ion of propane obtained fro111 n;11un_d gas is cyclizcd in the Hass procc~s by 1rcati11g with :1.inc dust in aqueous ,dcohol in the pr<..'Scnct: of sodium ioclick :is c;nalyst. . ~driction. ;\ soft ~rnci extrrn1ely tacky tnixtun: l)I. ;.~ ..... rubber and softrnc; :ipplicd to a f.1bric by 111c:1t1~ of a three-ml! c:dcnder. The cliffcrer"11ial speed of the calender mils drives the material into th<.: intersiiccs of the hbric. forming ;1 .'strongly acl_-:;,,1 hcrcnt coating Uni..:ured friction on a light ,--shectmg 1s used for electrical insulating or fric- ~-:·,.;':~ion tape. Heavy-weave fobric coated wi1h high- ::"/'gradc friction (rubber plus softener and curing · agents) i~ us(;d as pile.~ in tirt: carcases, 1ra11smis- .,i(1;\ bells. :ind 01h.:1 la111i11atetl produc:., whi,.:h are '-'uka11i?.t·d. .See :lisl1 c:1\cnder. Frii•d1·!-Cr:1f1s reaction . .'\ type l)I-n::1c11on i!l- Yolving :1nh:·dro11s :duminu111 ch!urick ;uid si111- ila1 111et:dlic llalidt.::s as cata!ysb, Jiscovercd in 1877 by Charles Friedel, a French dicmist (1832-18'.Y)), <1nd James Mason Crafts, an Amt.::rican chemist (1830-1917), during join! rc- sca,·ch in FraJKl'; it ilas bcen developed since l11e11 Cor lllany important industrial uses, exem- plified by the condensation or c1hyl chloride and benzene to ronn ,,:thylbenzeoc irnd the manufac- ture of acctophcnonc fro111 acctyl chloride and bcnzcnt:._Thc name ls 110w applied to a wide va- riety of acicl-catalyzcd organic re.tctions. Use: ,.\lkyl;uion and :1cylatin11 in general. Snme c.-..:a1nple:-. :11t· the produc1io11 of hig,h-u.ctanc g:1s- oline, cu111c11c, dctcrgcnl al\..:ylate, and various p\as1ic-, ;ind l'lastomers. Frietll:icndcr synthc:-.is. Base-catalyzed conc!en• ~:uion of 2-aminobenzalclchydes with kcto11cs to fL1rm quinolinl' derivatives. Fries rcarranj.!,Clllent. Rearrangement of phenolic esters w o-,rnd/or p-phenolic kctoncs on heat- ing with aluminum clllOride or other Lewis acid c:11:llys1s. Fries ruk. The-most stable form of a po!y11uclear hydrocarbon is that in which the mc1ximum nurnb~r of rings has the bcnzenoid arrangement of three double bonds. A benzcnoid electronic conrigur:11ion is energetically 'rcivored :rnd, l lii.:1 Cf ,.H'e, l)<trl iculal'!y ::.t ;1ble. frit. A ground g!ass used in making g!azes and -~n:imr\s :ind :dso for m;1king so-called Crit seals. Finely pow.de red glaSs 111ay be called a f'ri\. The 1cr111 is also used ·for finely gru1111cl inorganic minerals, rni.\cd with fluxes and coloring agents which turn in!o a gb1ss or enamel 011 heating. F ri!seh-l\11 I te11 berg-\\'ict:liell re:1rrangc111 en I. Tile ri:;1rrang.crne11t of l, l-diaryl-2-haloethyl- encs to di.1ryl :ll'l'tylcne:-; wirh strong ba.<;es . "Flt-:\'" [Goodrich]. T~-1 fo1 11 :-.cries uf b11L:1- dieneanyloni1dlc clastomeric polymers and·la- tc\cs. Pr°npcnics: Oil ,lnd solvent rcsis-1a11cc combined with good. fle:-.:ibility. nnd rcsis1ancc to low tcm, pcr:1tu1es, water absorption, and pcrmancqt set. Usi.:: Oil-resistant seals, shoe soles, gasoline hose·, belt conveyors, •plasticizers, pape·r saturation, adllesivcs,·lcathc1 t'inishes, and carpet backing. ··:, ; . ·:t: . t· ··1 .. • ·,; ' I I/ r I I I I I I I I , I I 1• 11 I 11 I I I I ORGANIC CHEMISTRY Third Edition ROBERT THORNTON MORRISON ROBERT NEILSON BOYD New York University I ALLYN AND BACON, INC. BOSTON I ' ' I ' © COPYRIGHT 1973 BY ALLYN AND BACON, INC. © CO/'YRIGIIT !966 BY ALLYN AND lJACON, INC. ID COPYRIGHT 1959 IJY ALLYN AN!YBACON, INC. 470 ATLANTIC AVENUE, BOSTON ALL RIGIITS RESERVED Nv part of !ht' 11io1cri1il pruleclcd by this copyrighl not ire may b,, t('prod11c('d or 111ifized in uny form or hy any 1m'a11s, clcctro11ic or mcclw11iral, i11clmli11g photocur1yi11g, rN·ordi11,:, or hy any informa- lional slt!ra,:c m11I rc1rie11al .l'.\'Sf<'III, without wri11e11 per111i~sio11 from the cupyrig/,/ 011'1/er. LIBRARY OF CONQRESS CATALOG CARD NUMBER: 72-91904 PRINTED IN THE UNITED STATES OF AMERICA i ' I i t' t 156 ALKENI~S I. STRUCTURE AND I'Rl~PARATJON CHAP. 5 The most important of these methods of prcpnration-sincc they are the most generally applicable-arc the dchydrohalogenation of alkyl halides and the dehydra- tion of alcohols. Both methods suffer from the disadvantage that, where the struc- ture permits, hydrogen can be eliminated from the car'bon on either side of the carbon bearing the -X or -OH; this frequently produces isomers. Since· the isomerism usually involves only the position of the double bond, it is not important in the cases where we plan to convert the alkcnc•into an alkanc. As we shall see later, alkyl halides are generally prepared from the correspond;. ing alcohols, and hence-both these methods ultimately involve preparation from alcohols; however, dchydrohalogenation generally leads to fewer complications and is often the preferred method despite the extra step in the sequence. Dehalogenation of vicinal (Latin: vicinalis, neighboring) diha!ides is severely limited by the fact that these dihalicles are themselves generally prepared rrom the. alkenes. However, it is sometimes useful to convert an alkcnc to a dihalidc while we perform some operation on another part of the molecule, and then to regenerate the alkene by treatment with zinc; this procedure i.S referred to as protecting the double.bond. When a pure cis-or trans-a!kene is wanted, uncontaminated with its stcrcoiso- rncr, it can often be prepared by·reduction of an alkyne with the proper reagent (Sec. 8.9). 5.12 Dchyclrohalogenation of alkyl halides Alkyl halides arc converted into alkenes by dchydrohalogcnation: elimination of the eleli1e11ts of hydrogen halide. Dehydrohalogcnntion involves removal of the halogen atom together with a hydrogen atom from a carbon adjacent to the one Dchydrohalogenation: elimination of I-IX I I -C-C-+ KOH (alcoholic) ~,- 1 I I I -C=C-+ KX + H20 Alkcnc H X Alkyl halide bearing the halogen. It is not surprising that the reagent required for the elimina- tion of what amounts to a molecule of acid is a strong base. The alkene is prepared by simply hiating together the alkyl halide and a solution of potassium hydroxide in ~lcohol. For example: CH3CH2 CH,CI 11-Propyl chloride CH3CH2CH2CH,CI 11-llutyl chloride CH 3Cl·l2CHCH3 I Cl St!c-Butyl chloride KOH (ale) CH 3CH=Cl-!2 Propylene CH3CH2CH=Cl-!2 l-llt1tene 2-Butene S0"/4 KOH (ale) c1-1,c1-1c1-1, I Cl lsopropy! chloride l-Bulene 20/o ·•• . -, I I I SEC. 5.IJ ;,.1ECHANISl\-l OF DEHYDHOHALOCENATION 157 As we can sec, in some cases this reaction yields a single alkene, and: in other cases yields a mixture. 11-Butyl chloride, for example, can eliminate hydrogen only from _C-2 and hence ~,jc(ds only I-butene. sec-Butyl chloride, on the other hand, can elimillatc hydrogcn from either C-l or C-3 and hence yields both I-butene and 2-butcnc. Where the two a!kcnes can be formed, 2-butene is the chief product; this fact Hts into a general pattern for clchydrohalogenation which is discussed in Sec. 5.14. 5.13 Mechanism of dehydrohalogenation The function of hydroxide ion is to pull a hydrogen ion away from carbon; simultaneously a halide ion separates and the double bond forms. We should -c I rcprt'.H'ntcd as -,X lt I , 1 -C-C---> C=C + x-+ 11 20 1C1 / , II \__OH- whcre arro\\'S show the direction of electron shift notice that, in contrast to free radical ·reactions, the breaking of the C-H and C-X bonds occurs i11 an unsymmetrical fashion: hydrogen relinquishes both electrons to carbon, and halogen retains both electrons. The electrons left behind by hydrogen arc now available for formation of the second bond (lhe .,,. bond) bet\vcen the carbon atoms. for the breaking of the carbon-hydrogen and What supplies the energy carbon-halogen bonds? (a) First, there is formation of the bond between the hydrogen ion and the very strong base, hydroxide ion. (b) Next, there is formation of the.,,. bond which, although weak, does supply about 70 kcal/mole of energy. --., .•.. : "-7~::':.~-·:'"!~'~"\l':,..., ' 158 ALKENES I. STRUCTURE AND PREPARATION CHAP. 5 (c) Finally-and this is extremely important-there is the energy of salvation of the halide ions. Alcohol, like water, is a polar solvent. A liberated halide ion is surrounded by a cluster of these polar molecules; each solvent !110lccu!c is oriented so that the positive end of its dipole is near the negative ion (Fig. 5.6). Figure 5.6. Ion-dipole interaction: solvatcd halide ion. Although each of these ion-d1j,ole bonds (Sec. 1.21) is weak, in the aggregate they supply a great deal of energy. (We should recall that the ion-dipole bonds in hydrated sodium and chloride ions provide the cnc.rgy for the breaking down of the sodium chloride crystalline lauicc, a process which in the absence of water requires a temperature or 801°.) Just as a hydrogen ion is pulle<{ out of the molecule by a hydroxide ion, so a halide -ion is pulled out by solvent 1110/ecu/es. The free-radical reactions of the alkanes, which we studied in Chap. 3, are. chiefly gas phase reactions. It is significant that ionic reactions (like the one just cliscusscd) occur chiefly in solution. (\Ve shall return to dchyclrohalogcnation artel· we have learned a little more chemistry (Sec. 14.20), and have a look at the evidence for this mechanism.) 5.14 Orientation and reactivity in dehydrohalogenation In cases where a mixture of isomeric alkenes can be formed, which isomer, if any, will predominate? Study of many dehydrohalogenation reactions has shown that one isomer generally does predominate, and that it is possible; to predict which isomer this will be-that is, to predict the orientation of elimination-on the basis of molecular structure. CH3CH2CJ·l llrCH3 CH I ' CH 3CH 2 CllrCH3 KO!! (ale) KOii (ale) KOH (:de) CH 3Cii=CHC1·13 and CH 3Cl·i 2CJ·l=CH2 Sl°/4 191/a CH 3CH2Cl-l=CHCH3 71% CH I ' CH 3CH=CCH.1 71½ and CH 3CH 2CH2Cl·l=CH, 29% and CH3 I CH 3CH2C=CH2 29½ Once more, orientation is determined by the relative rates of competing reactions. For sec-butyl bromidc1 attack by base at any one of three hydrogens SE ( t! gc Jll W• fc tn Ii ti ·1 I. SEC. 5.14 ORIENT,\TION AND. l<l<:ACTJ\'ITY IN DEHYDl{Oi-lALOGl~.r,.,,:ATION 159 (those on C-1) can lead to the formation or I-butene; attack at either oftv•rn hydro- gens (on C-3) can lead to the.formation of 2-butenc. \Ve see that 2-butcne is the rrcferrccl product-that is, is f'o1:mccl faster-despite a probability factor of 3:2 working against its formation. The other examples fit the same pattern: the pre- ferred product is the alkcnc that has the greater number of alkyl groups attached to the doubly-bonclccl carbon atoms. Ease of formation of alkencs I 11 Sec. 6.4 we shall /ind evidence that the stability of alkcncs follows exactly the same sequence. Stability of alkcnes In dchydrohalogcnation, the more stable the alkcne the more easily it is formed. Examination of' the transition state involved shows that it is reasonable that the more stable alkcnc should be formed raster: X I I -C-C- 1 I H 011-- Transition state: pertly formed do11ble bond The double bond is partly formed, and the transition state has thus acquired a\kcnc character. Factors that stabilize an alkcnc also stabilize an incipient alkene in the transition state. Alkenc stability not only determines orie11tatio11 of dchydrohalogenation, but also is an important factor in determining the reactivity of an alkyl halide toward elimination, as.shown at the top of the next page. Reactant -Product Relative rates Rc!otiue rate.~ per H CH3Cll20r -----+ CH1=CH1 1.0 1.0 CH_1CH 2CI-12Br -CH3CI·I=CH2 3.3 5.0 CI-! 3CI-I llrCH_1 -CH_1CI·I=CH2 9.4 4.7 (CH3),C8r -----+ (Cl-lJ)3C=CH2 120 40 As one proceeds along a series of alkyl halides from IO to 2° to 3°, the structure' by definition becomes more branched at the carbon carrying the halogen. This increased branching has two-results: it provides a greater number of hydrogens for attack by base, and hence a more favorable probability factor toward elimination; and it leads to a more highly branched, more stable alkene, and hence a more stable transition state and lower E,1ct. As a result of this combination of factors, in dehydrohalogcnation .the order of reactivity of RX is 3° > 2° > 1 °. 252 ALKYNES AND DIENES CHAP. R Coal --> coke r 2000~ C C H20 a 2 ~ Limestone -->-CaO An alternative synthesis, based on petroleum) is displacing the carbide process. This involves the controlled, high-temperature partial oxidation of methane. 6CH4 + 0 2 ~ 2HCaeCH + 2CO + 10H2 (The economic feasibility of this process is partly due to use of side-products: carbon mo1ioxidc and hydrogen for production of alcohols, and some hydrogen as fuel to main_tain the oxidation temperature.) Enormous quantities of acetylene are consumed each year. Dissolved under pressure in acetone contained in tanks, it is sold to be used as fuel for the oxyacet-ylene torch. It is· the organic starting material for the large-scale synthesis of important organic compounds, including acetic acid and a number of unsaturated compounds that arc used to make plastics and synthetic rubber. Many of the ·synthetic uses of acetylene have grown out of work done in Germany before and during World War II by W. Reppe (at the I. G. Farbenindustrie). Aimed at replacing petroleum (scarce in Germany) by the more abundant coal ~is the prim• ary organic source, this work has revolutionized the industrial chemistry of acct· ylene. 8.6 Preparation of alkynes A carbon-carbon triple bond is formed in the same way as a double bond: elimination of atoms or groups from two adjacent carbons. The groups eliminated W X I I -c-c--> I I y z wx I I -C=C-~ -ease- and the reagents used arc essentially the same as·in the preparations of alkenes. PREPARATION OF ALKYNES 1. Dehydrohalogenation of alkyl dihalid.es. Discussed in Sec. 8.6. Example: H H I I -C-C- * * KOH (ale) NaNH2 -CaeC- CH3CH=CH2 ~ CH3CH-CH2 KOH (ale) I I CH3CH=CHBr N,NH, CH3C=CH Br Br 1,2.Dibromopropane (Propylene .bromide) 1 •Bromo•l ·propcne Propyne s I I I I I I 1 SEC. 8.6 l'HEl':\lUT!ON OF AU'\YNES 253 2. Reaction of sodium ncctylidcs with Jlrimary alkyl halides. Discussed in Sl.'.c. 8.12. Examples: NaN!h or Na mct:11 -Ces.c:-Na' + RX -:• -Ca:eSC-R + NaX (R musr be 1") Sodium a,t:tylidc l-1-lcxync ( 11-JJu tyl.\Cct ylcnc) Sodium 11-pcntybcetylidc 11-Pcntyl ch!oride 6-Dodecyne 3. Dchalogenation of tc!rnhalitlcs. Discussed in Sec. 8.(). Example: X X I I -C-C-+ 2Zn -, -CEC-+ 2ZnX2 I I X X Br Br I I CH,-C-CH . I I llr llr Zn -, CH,-C=2CH Propync Dchydrohalogcnati o n of vicinal dihalides is particularly useful since the di- halides themselves arc readily obtained from the corresponding alkencs by addition of halogen. This amounts to conversion-by several steps-of a double bond into a triple bond. Dchydroha!ogcnati o n can generally be carried out in two stages as shown. H H I I -C-C- 1 I X X KOi! (ale) H I -C=C- * A vinyl halide Very 1mrcactiue Carried through only the first stage, it is a valuable method for preparing un- saturated halides. The halides thus obtained, with halogen attached directly to doubly-bonded carbon, arc called vinyl halides, and are very unrcactivc (Sec. 25.5). Under mild conditions, therefore, dehydrohalogenatio n stops at the vinyl halide stage; more vigorous conditions-use of a stronger base-arc required for alkync formation, Reaction of sodium acctylidcs with alkyl halid<'s permits conversion of smaller alkyncs into larger ones. Practically, the reaction is limited to the use of primary halides because of the great tendency for secondary and tertiary halides to undergo a side reaction, elimination; this point will be discussed further (Sec. 8.12) after we have learned soir1cthing about the nature of acetylides, Oehalogenation of tetrahalides is severely limited by the fact that these halides are themselves generally prepared from the alkyncs. As is the case with the double --II II, Ill !di Iii • • I . -~ Document Control No. 4400-03-ACJH Revision 1 REIVlEDlAL INVESTIGATION REPORT ABC ONE-HOUR DRY CLEA..NERS JACKSONV1LLE, NORTH CAROLINA November 1992 REGION IV Work Assignment Nci. 03-419E U.S. EPA Contract No. 68-W9-0057 Roy F. \Veston, Inc. 1880-H Beaver Ridge Circle Norcross, Georgia 30071 \VESTON \V. 0. No. 04400-003-021-0071-00 Reference. 27 ill 11·1 1ti1 \rl 1. ll This document was preparecl b:.1 Roy F. V✓eston, !nc. e;,:pressly tor EP/\. It s/11.11: not be 1eleased or disclosr~d. in who!c: or in par:, wiHrnut the e·1_pft!!;S wri11en pe1r-:1ission of EPP.. P.emedial investigation Hepon ABC One-Hour CleanerJ, inc. ,Jacksonville, Onslow County, North Cirolino Section: 6 · Revision: 1 Da1e· November 1992 Page· 16of23 variable ancl clegradatio11 may or may not occur, clepending 011 subsurface conclitions (e.g., the presence of nutrients, microorganisms, etc.). If conditions arc favorable, PCE may' be progr·cssivcly broken down to TCE, 1,2-DCE, vinyl· chloride, and possibly to carbon clioxide. As is shown on Figure 6-2, of the three possible cliehloroethene isomers, I, 1-DCE is the least common and several studies report that cis-1 ,2- DCE is formed preferentially to trans-1,2-DCE. One possible explanation is that during reductive dechlorination, a chloride ion and free radical are formed. Because water is typically the medium in which the reaction occurs, the most polar fon11 of the radical is favored (cis 1,2- DCE). As also shown on Figure 6-2, chloroethane may fom1 from the reductive dechlorination of cis-1,2-DCE (or as shown, from the degradation of 1,1-DCA) without the iritennediate formation of vinyl chloride); however, the preferred product from the dechlorination of cis-1,2- DCE is vinyl chloride. The relative rate of dechlorination decreases as chlorines are sequentially removed; therefore, degradation of PCE is much faster than that of TCE or the DCE isomers; and reductive dechlorination of vinyl chloride is slower still. As such, vinyl chloride 1s persistent and the foITT1ation of carbon dioxide or ethylene is rather slow. Its degradation is enhanced by the presence of methane (Vogel et al, 1987). Carbon dioxide is the end product of organic degradation (oxidation). Several PCE/TCE degradation products (shown on Figure 6-2) throug!1 vinyl chloride have been detected in the groundwater at the ABC site. Studies have shown that the presence of alkylbenzenes (e.g., toluene) can accelerate the anaerobic dechlorination of chlorinated solvents (Sewell and Gibson, 199 l). Aerobic biodegradation may be important for the less halogenated hydrocarbons (Vogel et al, 1987). A biotic clehalogenation has also been reported in the literature (Vogel et al, 1987). 1 1/112 -----·- Ci Ci \; = c/ / ""-------Cl Cl Cl Cl "'-c c/ = / ---"" ' Cl H ' ' '-l ETRACHlOROETHENE (PCE) TRICHLOROETHENE (TCE) 1. 1, 1 TRICHLOROETHANE / (TCA) H . I H-C I H PREDo,mwrr REACTION PATHWAYS ---REACTIO!/ IDENTIFIED IN SOME STUDIES ---:---REACTION RARELY OR NEVER OCCURS Cl I -C-CI I Cl "' ' H o I ~ H-C C I "-H OH ACETIC ACID -·----- - cis -1 ,2 -DiCHLOROETHENE (c-DCE) Cl / -- "'-c = / H Cl "" C = / H --- H c/ "'-c1 CHLOROETHANE (CA) H H I I H-C C --H I ' I Cl H Ci H "" / C = c' < / " / H H trans -" 1 ,2 -DICHL0ROCTHEN[ ,,-...-VlfJYL CHLORIDE " (t-DCE) , / H "'-c = / H / 1,1 -DICHLOROETHENE 1, 1 DCE) H H I I H-C C -Cl I I H Cl H I -H-C I Cl --·--- 0 C --0 ,.;' / C.A.f~BOi·l DIO.XIOE ,/ ---- H H ' / 'c / = C / "" H H H i 0 C --H -I I H C --0 1, 1 -DICHLOROETHANE CHLOROETHNIE CAPBON DIOXID,: ( 1, 1 DCA) (CA) nGURR e-2 DEHA.LOGENA TION OF CRLORJN.t. Tf.D ETHENRS AND ETIJANES