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HomeMy WebLinkAboutNCD980840409_20090206_Charles Macon Lagoon Drum_FRBCERCLA SPD_Lower Macon Groundwater Remediation System Suspension Request-OCRI I I I I I I I I I I I I I I I I I I Chemistry and Engineering Solutions in the Environmental Industry February 6, 2009 Ms. Giezelle Bennett Remedial Project Manager United States Environmental Protection Agency, Region 4 61 Forsyth Street, S.W. Atlanta, Georgia 30303-3104 Re: Lower Macon Groundwater Remediation System Suspension Request Macon/Dockery NPL Site Cordova, North Carolina IC Project No.: 0004-001 Dear Ms. Bennett: //f://i ic' rr' , -,1 I' l I~ SUPERFUND SECTION On behalf of the Macon Dockery Site Group (MDSG), lrminger Consulting, Inc. (JC) is pleased to submit this request for suspension of the Lower Macon groundwater remediation system at the Macon Dockery NPL site located in Cordova, North Carolina. A portion of the United States Geological Survey topographic map of the Laurinburg quadrangle showing the approximate location of the site is attached to this letter as Figure I. A site map of the Lower Macon system is provided as Figure 2. Macon Dockery Site History Remediation at the Macon Dockery site was initiated on February 22, 1996, with the start-up of a Soil Vapor Extraction (SVE) system and four separate groundwater remediation systems. The SVE system was installed in the area of former Lagoon 7 to remediate vadose zone soils beneath the former lagoon. Remediation goals for soil beneath Lagoon 7 were met and the request for closure of the SVE system was approved in a letter from the United States Environmental Protection Agency (EPA) dated May 19, 2000. Abandonment of the SVE system began December 27, 200 I, and was completed on April 26, 2002. Abandonment of the SVE system is documented in the "Soil Vapor Extraction Abandonment Report" dated November 8, 2002. A request to suspend operation of the Lower Dockery Remediation System was submitted to EPA on February 11, 2004. The suspension request was based on a comparison of analytical data to performance standards. The suspension request was approved by EPA and the remediation system was turned off on March I 0, 2004. Lower Macon Groundwater Remediation System The Lower Macon remediation system is supplied with groundwater from five extraction wells using jet pump technology. A 20-horsepower recirculation pump located at the remediation lrmingcr Consulting, Inc. 7015 Erinbrook Drive. Concord. North Carolina 28025 (704) 795-1585 (voice and fax) (704)701-9099 (cell) stcveirminger@ctc.net I I I I I I I I I I I I I I I I I I I Ms. Giezelle Bennett lower Macon System Suspension Request Page2 February 6, 2009 system equipment compound circulates water to all five wells in a closed loop system. Smaller pipes connected to the main loop are used to create a venturi through an eductor located down the well. At the equipment compound, the water flows through two parallel bag filters then into the feed tank. The bag filter assists with suspended solids and metals removal. A six-inch diameter PVC pipe flows water by gravity from the feed tank to the low-profile air stripper. The air stripper aerates the groundwater to promote the volatilization of volatile organic compounds (VOCs) and their subsequent removal through the offgas stack of the air stripper. Other equipment accompanying the air stripper include a blower, effluent sump, an inlet screen and damper, and a steel demister. Treated water flows by gravity out of the effluent sump to two infiltration galleries where it reenters the ground. Lower Macon Remediation System Performance Since start-up in 1996, the system has maintained an average annual operational percentage of approximately 82% (as reported in the 2008 Annual Operation and Maintenance Report). The production rate is not measured directly because the treated water from the Lower Macon system is combined with the treated water from the Upper Macon system prior to the flow meter. However, the combined systems have treated over I I 0,000,000 gallons of water since start-up. No modifications have been made to the system since 1996. System downtime is attributed to repair work as the result of malfunctioning pumps, power interruption, freeze damage, blower malfunctions, and high sump water level alarms in the air stripper. Lower Macon Remediation System Effectiveness Lower Macon system influent and effluent samples were collected weekly for the first month of system operation and monthly thereafter for the first year. In 1997, the MDSG was allowed to begin quarterly system influent and effluent sampling. In June 2000, the MDSG was granted permission to begin semi-annual sampling of system influents, but was still required to conduct quarterly system effluent sampling. Lower Macon groundwater remediation system influent and effluent samples are presently collected semi-annually and quarterly, respectively. A review of historical laboratory analytical results for the Lower Macon system influent samples indicates that since January 28, 2006, all organic and inorganic parameter concentrations have consistently been below the Performance Standards specified in the "Performance Standards Verification Plan" dated October I 994. A summary of the influent sample results is included in Table 1, which is attached to this letter. Groundwater samples for the Lower Macon site are collected from groundwater monitoring wells MW-13 and MW-22. A review of historical laboratory analytical results for groundwater samples collected from well MW-22 indicate that concentrations of VOCs have not exceeded the Performance Standards since July 30, 2002, when 1,1-dichloroethene was reported in the groundwater sample at a concentration of 7 .3 ug/L, which is greater than the performance standard of7.0 ug/L. A review of the historical data from well MW-22 indicates that inorganic parameters have been below performance standards since January 28, 2005, when manganese was reported in the groundwater sample at a concentration of 290 ug/L which is greater than the performance standard of 50 ug/L. I I I I I I I I I I I I I I I I I I I Ms. Giezel/e Benne// lower Macon System Suspension Request PageJ February 6, 2009 A review of historical laboratory analytical results for groundwater samples collected from well MW-13 indicates that concentrations ofVOCs have not exceeded the Performance Standards since 1998. A review of the historical data from well MW-13 indicates that manganese concentrations remain above the performance standard of 50 ug/L. In August 2008, a groundwater sample collected from well MW-13 was reported with a manganese concentration of 450 ug/L. Beryllium was reported in the groundwater sample collected in August 2008 at a concentration of 1.9 ug/L, which is greater than the performance standard for beryllium of 1.0 ug/L. Other inorganic parameters have been below performance standards since August 19, 2006, when lead and vanadium were reported in the groundwater sample at a concentration of 27 ug/L and 99 ug/L, respectively. The performance standards for lead and vanadium are 15 ug/L, and 50 ug/L, respectively. A chronological summary of the analytical groundwater sample results is provided in Table 2 which is attached to this letter. Background Concentrations Inorganic concentrations greater than the Performance standard reported in groundwater samples collected from well MW-13 are consistent with background concentrations reported in the North Carolina Geological Survey (NCGS) Open-File Report 93-19 dated July 1993. This report lists the concentrations of nine inorganic parameters reported in 23 groundwater samples collected in Richmond County. The NCGS report reports analytical results in units of parts per billion which are approximately equivalent to micrograms per Liter. Manganese was reported in 21 of the 23 groundwater samples. The Manganese concentrations ranged from a high of 867 parts per billion (ppb) to a low of 6 ppb. The average of the 21 results is IO I ppb. The manganese concentrations reported by the NCGS in Richmond County are consistent with the concentrations observed in the Lower Macon monitoring wells, which supports the conclusion that the manganese concentrations are naturally occurring background concentration. The NCGS report did not analyze groundwater samples for lead, vanadium, or beryllium. Excerpts of the report are contained in Attachment I. The 1993 NCGS Open-File Report 93-19 reported the results of stream sediment samples collected in Richmond County and analyzed for numerous inorganic parameters. Twenty-seven sediment samples were analyzed for manganese and vanadium. The manganese results ranged from a high of 670 parts per million (ppm) to a low of 20 ppm with an average concentration of 126 ppm. The vanadium results ranged from a high concentration of l00 ppm to a low of lO ppm with an average concentration of 30 ppm. Twenty-eight sediment samples were analyzed for beryllium and lead. The beryllium results ranged from a high of 2.5 parts per million (ppm) to a low of less than the detection limit of 0.5 ppm. Thirteen of the sediment samples were reported to be less than the detection limit of 0.5 ppm for beryllium. Of the remaining 15 sediment samples, the average beryllium concentration reported was 0.8 ppm. The lead results ranged from a high concentration of 27 ppm to a low of less than the detection limit of IO ppm. Sixteen of the sediment samples were reported to be less than the detection limit of IO ppm for lead. Of the remaining 12 sediment samples, the average lead concentration reported was 14 ppm. While sediment sample analytical concentrations cannot be compared directly to groundwater concentrations, the presence of these parameters above the detection limit support the conclusion that their low concentrations at the site are naturally occurring and representative of background conditions. In I 999, the NCGS used the 1993 stream sediment sample data to create geochemistry maps which indicate naturally occurring concentrations of inorganics in stream sediment samples I I I I I I I I I I I I I I I I I I I Ms. G iezel/e Benne/I Page4 February 6, 2009 lower Macon System Suspension Request collected in the site area. Copies of the NCGS geochemistry maps of manganese, vanadium, and lead concentrations in stream sediment for the piedmont of North Carolina are provided in Attachment 2. Effect of Suspended Solids Irminger Consulting, Inc. prepared comparison charts, which reveal trends associated with concentrations of inorganics and suspended solids. The charts are provided in Attachment 3. The charts indicate that high concentrations of suspended solids correlate with high concentrations of inorganics. This data demonstrates that high concentrations of inorganic compounds are associated with high suspended sediment, and are not dissolved at these concentrations. Conclusion Sufficient technical justification to warrant the suspension of the Lower Macon groundwater pump and treat system is summarized in the list below. • VOC concentrations have not exceeded the Performance Standards since 2002 in well MW-22 and 1998 in well MW-13; • Inorganic concentrations in well MW-22 have not exceeded the Performance Standards since January 2005; • Inorganic concentrations in wells MW-13 and MW-22 are consistent with naturally occurring concentrations reported by the North Carolina Geological Society; • Laboratory analytical results and comparison charts demonstrate a correlation between high concentrations of suspended sediment and high concentrations of inorganics in wells MW-13 and MW-22. This data indicates that the inorganics are not dissolved in the groundwater at these concentrations; and, • Influent concentrations to the remediation system have been below the Performance Standards for all parameters, organic and inorganic, for three years, since January 2006. Based on the justification listed above, the MDSG requests authorization from EPA to turn off the Lower Macon remedial equipment. lrminger Consulting and the MDSG appreciate your assistance on this matter. Should you have any questions, please contact us at (704) 795-7075. Sincerely, IRMINGER CONSULTING, INC. I' . _(;' e___ _ul-. .. J/ C:::'-----:-- Steven E. lrmihger, P.E. -:'. ! , ,, ·;' Senior Engi11eer • cc: MDSG members / David Mattison. DENR Superfund. ·✓ I I I I I I I I FIGURES I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I 0 FIGURE I Topographic Location Map Macon Dockery Site -Cordova, North Carolina 0.2 0.4 0.6 0.8 Map center is UTM 17 606188E 3862309N (WGS84/NAD83) Rockingham quadrangle -TopoZonc Pro elevation display Projection is UTM Zone 17 NAD83 Datum M=-7.681 G=0.665 ei 0 ------------------- UM-6 UM-5 UM-2 MW-23 ® ® MW-21 lnflllral!on Gallery Lagoon I I IJ ~Lagoo 10 MW-13 ® ~ ~ L E G E N D ® Monitor Well Location ® MW-22 ]~~===~==r=====~~===r=========;:::: N IRMINGER CONSULTING, INC. J/ad• II)': SEI Oat.: 01-20-2005 QQQ4-QQ1~Ch-.-d-,,,,.-.·-SE-I+-----~ ,.. .,,. nl#narntl: 0004001 MACON DOCKERY SITE CROUP UPPER/LOWER MACON I I I I I I I I TABLES I I I I I I I I I I I -- - Sample Date Location LM Influent 2/22/1996 2/23/1996 2/24/1996 2/25/1996 2/28/1996 3/8/1996 311611996 4/3/1996 5/3/1996 6/5/1996 7/30/1996 I ln/1996 2/4/1997 (DUP) 2/4/1997 5/12/1997 817/1997 11/13/1997 2/5/1998 5/711998 8/711998 11/4/1998 2/11/1999 5/13/1999 8/5/1999 11/3/1999 2/16/2000 5/8/2000 8/2/2000 l/18/2001 7/11/2001 1/15/2002 7131/2002 1/28/2003 7/10/2003 1/13/2004 6/28/2004 1/27/2005 8/25/2005 1/28/2006 8/2/2006 1/28/2007 7/29/2007 2/3/2008 8/23/2008· Remediabon Performance St NA -Not Analyzed - Chloro-form (uftlT \ 14 13 8.9 8.2 3 <l.O <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 1.6 l.l <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 ... <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <LO <1.0 <1.0 <1.0 <1.0 ug/L -micrograms per liter DUP -Duplicate --- I, 1 -Dichloro-1,1 • Dichlom Cis/trans-1,2-,than, cthcnc DicbJorocthcnc (uon., (uon., (uon) 26 9.1 4.4 29 II 4.9 30 13 4.9 31 13 S 32 IS S.6 9.S 1.6 2.4 8.1 1.8 2.4 7.3 2.6 2.3 8.6 2.7 2.9 12 4.7 3.4 17 6.6 <1.0 II 3.3 2.2 9.8 2.1 2.4 9.0 1.8 2.1 S.3 2.4 6.4 13.0 <1.0 1.2 9.S 1.8 <10 13.0 1.9 1.2 12.0 2.l 1.6 16.0 I.I I 13.0 1.3 <1.0 13.0 2.2 1.3 10,0 1.4 <1.0 7.8 1.0 <1.0 2.0 <1.0 I.I <1.0 <1.0 1.4 1.9 <1.0 <1.0 11.0 2.7 1.2 Not Sampled 6.1 2.8 1.0 4.S 1.7 <1.0 Not Sampled <1.0 <1.0 <1.0 Not Sampled 1.7 1.3 <2.0 Not Sampled <1.0 3.3 <2.0 1.2 12 1.4 2.1 23 2.9 <1.0 1.2 <1.0 3.9 3.9 <1.0 <1.0 1.8 <1.0 <1.0 2.6 <1.0 <1.0 <1.0 <1.0 3500 7 70 - Methylene chloride (uan \ <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 System <2.0 <2.0 System <2.0 System <5.0 System <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 - - - - TABLE 1 Influent Analytical Results Lower Macon System Macon Dockery Sita Richmond County, North Carolina Tctrachloro-1,1,1-Trichloro-Trichloro- etbene ,than, cthcnc (uan.\ (uu/1 .) (uo/T) 2 14 3.3 2.1 IS 3.6 2.7 17 4.S 2.6 17 4.4 2.4 17 4 <1.0 2.S I.I <1.0 34 1.4 I 4 4.7 <1.0 4.2 4.6 <1.0 S.3 4.9 <1.0 67 4.1 <l.0 S.2 4.S <1.0 4.4 3.7 <1.0 3.8 3.1 2 <l.O 8.3 <LO 4.4 3.3 <1.0 3.3 1.9 <1.0 4.1 3.4 <1.0 4.1 3.7 <1.0 4.4 3.5 <1.0 4.1 3.0 <1.0 3.7 3.6 <l.O 41 3.7 <1.0 3.4 2.4 <1.0 <1.0 I <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 4.7 S.I Dowo ... ... <1.0 2.8 3.4 <1.0 1.2 1.4 Down <1.0 <1.0 <1.0 Down <1.0 <1.0 1.8 Down <1.0 <1.0 <1.0 3.1 <1.0 <1.0 S.S 1.6 2.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 200 2.8 Toluene (uo/T \ 15 18 I 7 ll 4.2 <1.0 <1.0 <l.O <1.0 4.6 <1.0 <l.O <l.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <LO <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 1000 • Acetone reported 8/23/2008 at 42 ug/L. - Chromium (uo/1 \ <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <1.0 <IO <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 Not <10 <10 Not <IO Not <10 Not <10 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 - - - - - - Manga-Suspended Barium nos, Zin, Cadmium Lead Solids (uall) (uu/T) ,,,.n' (uu/T ) (ua/1) ,. ·") 77 130 120 <0.30 S.S <5.0 81 140 130 <0.30 S <5.0 86 160 160 <0.30 4.4 <5.0 86 160 160 <0.30 3.2 <5.0 100 ISO 240 <0.30 3.3 <5.0 <SO 72 S2 <0.30 <3.0 7 <SO S3 S7 <0.30 <3.0 <5.0 <SO 72 44 <0.30 <3.0 7 24 31 27 <0.30 <3.0 <5.0 <SO 21 24 <0.30 <3.0 S <SO 20 <20 <0,30 <3.0 6 <SO 6.4 <20 <0.30 <3.0 <5.0 34 19 <20 <0.30 <3.0 <5.0 34 16 <20 <0.30 <3.0 <5.0 <SO <5,0 <20 <0,30 <3.0 <5,0 <SO <5.0 <20 <0.30 <3.0 NA <SO 55.1 <20 <0.30 <3.0 <5.0 <SO II <20 <0.30 <3.0 <5.0 <SO <5.0 <20 <0,30 <3,0 <5.0 <SO 17 <20 <0.30 <3.0 <5.0 S8 99 <20 <0.30 S.O 40 <SO 8.8 <20 <0,30 <3.0 9.0 <SO 70 <20 2S <3.0 <5.0 <SO <5.0 <20 <0.30 6.4 <5.0 <SO 6.1 <20 <0.30 <3.0 <5.0 <SO 6.0 39 <0.30 <3.0 <5.0 <SO 6.4 <20 <0.30 <3.0 <5.0 <50 <5.0 <20 <0.30 <3.0 <5.0 Sampled System Down ... <50 7.3 <20 <0,30 <3,0 12 <SO 8.6 <20 <0.30 <3.0 <5.0 Sampled System Dowo <SO 8.2 <20 <0.30 <3.0 20 Sampled System Dowo <SO <5.0 <20 <0.30 <3.0 II Sampled System Dowo <SO <5,0 <20 <0.3 <3.0 <5.0 2S <5.0 <20 <0.30 NA <5.0 26 <5.0 <20 <0.30 <1.5 <5.0 S. I <5.0 <20 <0.30 <1.5 <5.0 6.7 <5.0 <20 NA <1.5 <5.0 S.9 <5.0 <20 <0.30 <1.5 <5.0 <5.0 7.7 <20 <0.50 <1.5 <5.0 S.4 8.0 24 <0.50 <1.5 <5.0 1000 5000 IS indicates exceedance of a performance standard. -- - 2/14/19% 2/14/1996 512/1996 7/30/1996 l J/6/1996 2/411997 S/12/1997 8/6/1997 I Ill 1/1997 2/S/1998 516/1998 Bn/1998 l 1/411998 2/10/1999 5/13/1999 8/5/1999 I Jn/1999 2/16/2000 518/2000 81212000 1/17/2001 7/11/2001 l/16n002 7/30/2002 lf2&/2003 7/10/2003 l/]J/2004 6/28/2004 1/27/2005 7/31/2005 8/19/2006 7129/2007 8/23/200! <1.0 <1.0 <1.0 <2.0 u <1.0 <2.0 <2 0 <S <1.0 <2.0 <1.0 <1.0 <J.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 - 80 76 63 " 66 " 99 61 62 67 )5 39 24 " 29 IS II 's 64 40 1.8 Not No< No< No< 4.4 <1.0 LO <1.0 <1.0 <1.0 <LO <1.0 - 25 20 IS 24 17 12 " 42 <S 11 14 12 6.8 3.7 64 26 1.7 1.2 LO <1.0 <1.0 Sam.pied Sampled s.,,,1'<1 ,.,, .. 1.9 <1.0 <LO <LO <LO <LO <1.0 <1.0 - 4.9 4.9 <1.0 4 2.3 l.l 2.2 <2.0 <S 1.6 <2.0 <1.0 <1.0 <1.0 <1,0 <l.O <1.0 <1.0 <1.0 <1.0 <1.0 ""'"' O,,Jo °"'"' °"'"' <1.0 <2.0 <1.0 <20 <1.0 <1.0 <1.0 <1.0 <2.0 <2.0 <2.0 <4.0 <2.0 <2.0 <4 0 <40 <JO <2.0 <4.0 <2.0 <2.0 <2 0 <2.0 <20 <2.0 <2,0 <20 <2.0 <2.0 D,y D,y D,y D,y <2.0 <5.0 <5.0 <2.0 <20 <2.0 <2.0 <2 0 Remediation Performance Stand&rc HOO 70 NA•NotAnalyzed DL--Dilution our-~,. - 27 <1.0 ll <2.0 <1.0 1.2 <2.0 <2.0 <S <1.0 <2 0 <1.0 <i.O <1.0 <1.0 <1.0 <i.O <1.0 <1.0 <1.0 <1.0 Collditions Conditions onditions Conditions <1.0 <1.0 <1.0 <J.O <1.0 <LO <i.O <1.0 9\E " 47 67 48 so " 40 l5 49 l8 40 25 22 " 17 12 9.4 ,., , 7 3.1 4.2 1.0 I 5 <1.0 <1.0 <J.0 <J.0 <1.0 200 - - - --Table 2 Groundwater Quality Summary Macon/Dockery Site Richmond County, North Carolina Page 1 of 2 14 12 <2.0 5.2 48 54 6.B <2.0 <S l.6 4.4 SJ 2.2 25 2.2 <1.0 <l.O <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <l.O <1.0 <1.0 <l,O <l.O <1.0 2.B <1.0 <1.0 180 <2.0 <1.0 <1.0 <2.0 <2.0 <5 <1.0 <2.0 <l.O <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1,0 <1.0 <1.0 u <1.0 <1.0 2.5 14 12 <2.0 <2.0 <S <1.0 <2.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1,0 <1.0 <1.0 <1.0 NA NA <1.0 <l.0 <1.0 <1.0 <1.0 <1.0 <LO <J.0 <2 0 <1.0 <1.0 <2 0 <2.0 <l <1.0 <2,0 <1.0 <1.0 <1.0 <LO <J.O <1.0 <LO <1.0 <1.0 <1.0 <1,0 NA NA <1.0 <1.0 <1.0 <1.0 <1.0 \11\)\\ <l.O <l.O <l.O <6.0 <l.O <l.O <6.0 <6.0 <IS <l 0 <6.0 <3.0 <l.O <l.O <3,0 <l.O <l.O <l.O <l.O <l.O <l.O <l.O NA NA <l.O <l.O <3.0 <l.O <3.0 400 <JO <10 <10 <JO <JO <10 <20 <20 <SO <10 <20 <JO <JO <JO <JO <JO <JO <10 <JO <JO <JO <10 NA NA <10 <JO <JO <10 <10 JSOO 27 <10 20 27 16 14 14 IS 11.9 11 <JO <JO 18 27 25 l6 " 20 JO 17 1l No< No< No< No< 10 <JO 47 <JO IS 47 IS IB so indicates an execedance of the performance standard - '" <SO 780 960 520 570 280 560 '" l 10 140 170 360 860 59-0 1000 600 340 450 SJO 520 Sampled Sampled Sampled Sampled 170.0 120.0 560 210 410 820 20 480 1000 <5.0 <5.0 <5.0 s., <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 6.6 <5,0 <S.O <l.O <5.0 <5.0 DU< D~ °"' Du, <1.0 <1.0 34 NA NA S.I 0.76 1.9 - 870 <5,0 \11\)\\ 1500 760 850 320 760 440 390 \JO ISO 410 \JOO 800 1400 750 400 560 660 '" To To To To 160 54 760 210 49-0 1100 260 450 so - - <40 65 120 <40 <SO <20 <40 79 160 <40 110 260 <40 60 110 <40 58 130 <40 <SO 52 <40 60 140 <40 <SO 93 <40 <SO 82 <-40 <SO 46 <40 <SO 62 <40 <50 130 <40 100 260 <40 60 180 <40 130 260 43 SI 560 <-40 <50 84 <40 <50 130 <40 <50 100 <40 <SO 83 DI)' Conditions DI)' Conditions Dry onditions DI)' onditions <40 ~o 38.o <40 <SO 43.0 <40 67 ISO NA NA 2B NA ?.'A 83 25 99 200 6.9 19 45 9.3 31 74 100 51\0\1 <0.30 <0.30 <0.30 0.31 <0,30 <0.30 <0.30 <0.30 <!,O <0.30 <O JO <OJO <0.30 <O.JO 0.39 <OJO <0,30 <0.30 <O.JO <0,)0 <0.30 <0.54 KA NA NA NA NA NA NA - 17 <J.0 20 ll ll 16 6.2 8.7 , , 7.3 <l.O <l.O 7.1 27 16 2B 14 <l.O ,., !l.O B.1 <l.O <l.O 20 <3.0 9.9 27 5.4 9.1 IS - 1.7 <0.20 14 0.53 <0.20 042 O.SJ 0.31 <0.20 0.37 <0.20 0.22 0.30 <020 0.50 0.25 0.47 0 22 0.36 0.22 0,43 <0.20 <0.20 <0.20 <0.20 <0.20 0.28 0.20 <0.20 <JO <JO <10 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA 154 - 910 <S.O 2100 2000 730 870 400 1200 84 150 17 17 420 !SOO 640 1600 780 260 460 69-0 1900 66 <5.0 880 110 120 1000 140 940 -- MW22 - 2/14/\996 51211996 7/30/1996 11/6/1996 2/4/1997 5/12/1997 8/7/1997 11/11/1997 215/1998 516/1998 8/6/1998 I 1/4/1998 2/10/1999 5/13/1999 8/5/1999 11/311999 2/16/2000 S/8/2000 11/2/2000 1/17/2001 7/20/2001 1/1512002 7/30/2002 1/28/2003 7/10/2003 l/ll/2004 6/28/2004 J/28/2005 7/31/2005 8/19/2006 7/29/2007 8/23/2008 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1,0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1,0 <1.0 <1.0 <1.0 <20 <2.0 <2.0 <1.0 <1.0 <1.0 <1.0 <I.0 <1.0 <1.0 <1.0 - '' J.6 2.2 J.I 4 I 4.4 '' 8.6 9.4 " 7.3 4.7 '6 14 \J 14 l.7 47 ,0 47 21 ,.6 J.7 11 4.8 1.9 2.0 2.0 - 6J l.J 44 34 '6 65 4.2 6.2 42 44 u <LO <1.0 <1.0 <LO <1.0 <1.0 <1.0 <1.0 lO <!.O <2.0 7.J l.1 J. I <LO <LO 1.7 <1.0 <1.0 <1,0 <1.0 1.4 <1.0 l.l <1.0 <1.0 <1.0 I.I " J.I J.I 1.8 1.7 2.4 2.2 2.6 2.6 2.6 1.7 12 <1.0 <2.0 28 <2.0 <2.0 <2.0 <1.0 <1.0 <1.0 <1.0 <1.0 Remediation Performance Standar, 3500 70 NA "' Not Analyzed DL "' Dilution OUP • duph,;w - <2 0 <2.0 <2 0 <2.0 <2.0 <2.0 <20 <2.0 <2.0 <2 0 <20 <20 <2.0 <2 0 <2 0 <20 <2.0 <2.0 <20 <2.0 <2.0 <4.0 <40 <40 <2.0 <5,0 <S.O <2.0 <2.0 <2.0 <2.0 <2.0 - <1.0 1.4 <1.0 <J.O <1.0 <1.0 <1.0 <1.0 <1.0 1.7 <1,0 <l.O <1.0 <!.0 <1.0 <1.0 <1.0 <i.O <1.0 <1.0 <1.0 <2.0 <2.0 <2.0 <1.0 <1.0 <1.0 <1.0 <1,0 <LO <1.0 <1.0 J.2 1.7 1.8 1.9 2.7 2.9 2 8 26 2.4 1.5 <1.0 <1.0 <LO <LO <1.0 <1.0 1.l 1.4 2.0 l.l J.7 4.7 43 1.8 <LO <1.0 1.0 <1.0 <1.0 <1.0 <1.0 200 - - - Table 2 - -Groundwater Quality Summary Macon/Dockery Site Richmond County, North Carolina Page 2 of 2 l.\ 2.l 2.J J.4 4.J 4.7 J.I 4.4 2 8 4.J J.9 22 2.4 2.9 23 2.9 2.4 28 22 1.6 <2.0 <2.0 <2.0 <1.0 <1.0 <1.0 <1,0 <1.0 <1.0 <1.0 <l.O 2.8 <20 <2.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1,0 <1.0 <2.0 <2.0 <2 0 <1.0 <1.0 <1.0 <J.0 <1.0 <1.0 <1,0 <1.0 <2.0 <2.0 <1.0 <1,0 <1.0 <1.0 <1.0 <1,0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <2.0 <2.0 <2.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <2 0 <2.0 <1.0 <1.0 <1.0 <LO <1.0 <l.O <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <l.0 <1.0 <l.0 <1.0 <l.0 <1.0 <1.0 <2.0 <2 0 <2.0 <1.0 <i.0 <1.0 <J.O <1.0 <1.0 <1.0 <1.0 1000 <6.0 <6.0 <J.0 <J.O <J.O <J.O <J.O <J.0 <J.O <J.O <3,0 <3.0 <J.0 <3.0 <3,0 <J.O <J.O <J.O <J.O <J.O <J.O <6.0 <60 <6.0 <J.O <2 0 <2.0 <3.0 <J.O <J.O <J.O <J.O 400 <20 <20 <JO <JO <JO <JO <10 <JO <JO <JO <10 <JO <JO <10 <10 <JO <10 <10 <JO <JO <JO <20 <20 <20 <10 <2l <2l <10 <JO <10 <JO <10 JlOO 41 13 \l <JO 11 17 <10 <JO 11 ll 13 <JO 11 11 <10 11 <JO 19 JO <JO 10 II <JO <JO <JO <10 12 <JO 5.4 <S.O <S.0 <S.O " indicates an exceed= of I.be performance standard 270 110 7J <,0 93 67 71 <,0 79 100 82 <,0 83 64 7J " <,0 120 200 60 <,0 81 <,0 <,0 <,0 <,0 <,0 NA 6.7 6.1 16 <,0 - <l.O <S.0 <S,0 <S.0 <5.0 <5,0 <S.0 <5.0 <5.0 <S.O <5.0 <5.0 <5.0 <S.0 <5.0 <5.0 <5.0 <S.O <5.0 <5.0 <5.0 <S.O <5.0 <S.0 <1.0 <1.0 <1.0 NA NA "·' "' "' 1000 - 2200 780 6,0 270 760 480 520 24' 630 770 6,0 310 610 460 480 ,20 240 940 1700 410 110 ,oo 180 210 44 11 13 290 12 14 42 <S.O ,0 <40 <40 <40 <40 <40 <40 <40 <40 <40 <40 <40 <40 <40 <40 <40 <40 <40 <40 <40 <40 <40 <40 <40 <40 <40 <40 <40 NA NA 1.7 7.2 LJ 100 - 160 " '" <,0 <,0 '" '" <,0 '" '" <lO <lO '" <,0 '" '" <,0 62 120 <,0 <,0 <,0 <,0 <,0 <,0 '" <,0 NA NA <S.0 <l.O <5.0 ,0 - 260 " " 39 93 67 60 37.7 " 82 66 37 63 48 " " <20 100 180 66 <20 ll 22 22 <20 <20 .. NA <20 <20 <20 <20 ,ooo <0,30 <O.J0 <O.J0 "JO <0,30 <O,J0 <O.J0 <1.0 <O.J <O.J <O.J0 <O,J0 <0,30 <0.30 <O.J0 <0.30 <0,J0 <0.30 <0.30 <0.30 <0.30 <0.30 <0.30 <0.30 <0.46 NA NA <0,30 <l).30 NA NA NA - 39 ll ll 43 12 9.J 7.6 <J.O 10 10 10 <J.O 7.1 8.0 8.1 7.4 <J.O 13.0 24.0 4.l <3.0 7.1 <J.O <J.O <J.0 <J.O <J.O 4.6 <J.5 <1.5 <1.5 <J.5 ll - NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA I.I <10 <JO NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA 1'4 - 800 230 260 170 260 JOO 240 \JO JJO 290 210 120 340 180 280 310 " ,., 980 260 lJ 210 88 140 22 17 14 41 60 7.0 12 <S.0 I I I I I I I I ATTACHMENT 1 I I I I I I I I I I I I I I I I I I I I I I I I I I I I r I I I I Listing of Concentrations of Variables of Stream Sediment, Stream Water, and Groundwater for the Laurinburg and Florence 30 x 60 -Minute Quadrangles -NURE Database by Robert H. Carpenter and Jeffrey C. Reid .,. 78" 37° 81 • eo• 79• . -~ '•~i 36011-El ...... l ...,, ... 36(171.El lt.OTl-F.I )6076-El ''''"' wvnu:wu GAW< """""" sourn aosTON EMPORIA NORFOLK VlltCUflA BEACH 83° ~ --.. ---.2,_ 30· ------------- /~1-,U -~· ' :,~1 _,., ,....., 3f,07'1-A.1 361'J78-AI RO"NOKF. 3',011,.,'I "' ·-·~1T1..ICJ( JOHNSQNOTv "'°"' lllll'tSTOf".SALE.'1 """""°"° H£NVCRSON' =n• ~~~~ i..::~~~OIJNI) ••• ..... ,,..-, 36° -J -·-· _,; ; ~~-.. _; ""'" -JSDU-EI SS(ISl.£1 3!,016-EI .,; ~El 30 ~" 35,079..F.l lS(ln.El ,,.,,.,, K? PL YMOUlll --.i .,wmco _85° -H><kORV "'"""'"" C>WO.""' ==• AOCXY lllOUN'T __ ...,; i 30' • --.. ~ .. ' ·::·.:·-'·-·2.-._.: i ~1o~ lSOlll-Al ~"(~"!!.,,,,, JS(lff;-AI SSOll-,,\I ,..,,_., ~-Al 35073-AI 3:$077,/1.1 '!Wnl,-AI c,.PE w,TTEAAS F(')"' ... /'UI, I.AXE ,.,.-----CHARtom: l50UTHERN PINES rAYETTI:\1U£ KINS10~ l!;A:,'BORO .-_ , , _ '~ \ . .-:,/ -. .. ""'""' 82° '-----34107B-El ·~ .. £1 ..... .,,. TOCCOA J4Qn.El 34DIO-El :,,,[! EtlZJIOCrnTO\I,.';,; NEW Rl\-'ER .. MOfl£HL\D CITY lANCASTER 1.AUR. 1:RG ., 30• s• ••• BJ• ·•· 76' 81 • :;I079,"'1 340711-.\1 3'077,/11.] nDRE."iCE: , \littnnlLLE 11.'ll.MINGTON 340 ' . 34° so• ------~~--:i.,an.f;\ D07J.EI """" ""'"' CME"-"' 33°30' 79° 78 . 303"30" 77 NORTH CAROLINA GEOLOGICAL SURVEY OPEN-FILE REPORI' 93--19 State of North Carolina James B. Hunt, Jr., Governor July, 1993 ! Department of Environment, Health and Natural Resources Jonathan B. Howes, Secretary Division of Land Resources Charles H. Gardner, Director and State Geologist 3 7 JO' 35• s• . .mse~~-. '-----+-__.,,,.,--:±:'--,e,:-,b-+-•-----..--•• ...,,,.-~,~dl----¼---+I Figure 3. Groundwater Sites -Laurinburg and Florence 30 x 60 Minute -Quadrangles ~r _;tBtf&\23~ 1111---·•----+,I----! • •fllll'1 1Ul • • .ill62I • t-19 ---- - ------ - ------ UURINBUIIO 1001( QUADIIAJIOU • GllQJIIDIIATEA Lab f County Lat Lore pll Conil u Br Cl f Mg "" Na V U/cond Al Dy ID ta/<tl ppb pp, pp, pp, pp, pp, pp, pp, xlODD """ pp, 4483 Al504 34.11249 79.8836 8.0 50 0.024 82DD 1160 112 IB60 •D.1 0.4 57 -0.001 4484 A1505 34.8204 79.11510 6.4 50 0.023 11800 20 7070 -0.1 0.4 101 D.510 4485 A1506 34.8201 79.1948 5.8 20 0.022 N · 7170 N -o. 1 1.1 21 -0.001 4486 11507 34.8625 79.7951 6.6 JO 0.018 14 5400 450 11 1090 -o. 1 D.6 21 -0.001 4487 A1508 34.8651 79.8507 6.2 20 0.011 27 5900 93 2260 4620 D.2 0.5 16 ·O.DDI 4488 Al509 34.9006. 79.8301 6.6 40 0.015 6300 1070 16 211D ·O. 1 0.3 61 ·0.001 4489 1151.0 34.9196 79.7894 6.6 115 0.015 51 7800 . 3530 397 8650 -o. 1 o. 1 1a •0.001 4490 11511 34.9583 79.8523 6.5 60 0.040 16 8500 20 460 15 4470 •0.1 0.6 65 0.230 4491 11512 34.9991 19.11563 6.9 90 0.016 37 9700 42 41DD 114 9280 -o. 1 0.4 14 -0;001 4501 Al522 34.9516 19. 71191 6.5 100 0.013 9200 224 4270 867 9720 -o. 1 o. 1 23 -0.001 4502 11523 34.9589 79.ffl7 7.5 99 0.038 17 3900 60 6510 248 M -o. 1 0.3 17 .-0.001 4503 11524 34.8651 79.6868 6.7 34 0.025 20 6100 17 M ·0.1 0.7 15 •0.001 4504 11525 34.8226 79.6847 6.2 36 0.071 13 4100 430 108 2770 -o. 1 1 .9 25 0.290 4505 11526 34.8210 19.7272 6.2 ·11 0.034 2200 14 101D -o. 1 3.0 22 •0.001 4506 11527 34.8675 79.7373 7.0 29 0.027 18 2900 660 9 1880 o. 1 0.9 23 -0.001 4507 11528 34.909Z 19.7394 5.3 48 0.040 JO. 7200 520 24 5640 -o. 1 o.8 112 0.160 4508 11529 34.9117 79.6812 5.2 17 0.040 50 4800 6 190 -0.1 Z.3 27 0.050 4509 11530 34.9143 79.6364 5.8 9 0.015 17 2400 9 14 730 •O. I 1.6 19 -0.001 4510 11531 34.9669 79.6845 6.0 II 0.028 18 2900 19 530 11 1250 -o. 1 Z.5 32 0.030 4511 11532 34. 9470 79.6311 6.7 16 0.016 14 3100 330 81 1750 -o. 1 1.0 21 -0.001 4512 11533 34.8710 19.6240 6.0 24 0.078 3700 1070 a 2270 -o. 1 3.2 31 D.170 4527 11548 34.9823 19.6076 5.5 96 0.160 11 5600 9670 20 5260 -o. 1 1.6 146 5.600 4528 11549 34.9270 19.5839 6.2 13 0.053 19 3100 ,, 320 6 1070 -o. 1 4.0 25 0.100 01 34.7324 79.4303 3.4 Z60 0.198 79 21400 47 2980 169 16430 -o. 1 0.7 701 · 1.630 4893 SC502 34.7252 79.4722 5.3 120 0.203 17700 TT 19390 -o. 1 1.6 76 -0.001 4894 SC503 34.6877 19.4306 3.9 99 o. 110 41 8300 58 14630 -0.1 1. 1 76 -0.001 4895 SC504 34.6635 ·-79.4669 4.1 75 0.217 20 10900 66 15190 -o. 1 2.8 111 -0.001 4896 Sc50, 34 .6974 19.4718 3.0 380 0.113 10 26700 45 4450 127 2"40 •D. 1 0.3 1130 -0.001 4897 SC506 34.6937 79.5119 4.2 50 0.085 35 8000 53 13850 •0. 1 1.7 109 -0.001 4898 sc507 34.7244 79.5079 4.5 50 0.004 44 6900 12 43 12150 -o. 1 0.0 102 ·0.001 4899 SCSOI 34. 7545 19.5090 3.4 82 0.315 25 11100 41 1160 50 16190 -o. 1· 3.8 215 -0.001 4900 _ SC509 34. 7487 19.5482 7.7 99 0.032 33 9100 21 75 14550 ·0.1 0.3 81 -0.001 4901 SCS10 34. 7308 79.5474 4.5 38 0.036 62 8000 43 12780 -o. 1 0.9 122 •0.001 4902 Sc511 34.7'526 79.5832 4.4 125 0.162 16600 21 2140 96 16660 -o. 1 1.3 192 1.450 4903 sc512 34.7889 79.6256 3.8 168 0.oao 17 21100 1780 72 22470 •0. 1 0.4 JOB ·0.DDI 4904 SCS13 34. 7905 19.5592 3.8 102 o. 141 26 10600 59 3520 67 13830 ·0.1 1 .3 802 1.280 Page 1a -- - --- -- - - -- 1+----d;;c--:--..i.~~mm--+-.~=,~w=---+----r'<e...~"==-->,.-,+, Rl&t l-RINJ Rll25-• • l2ll • lfl(IC8 Figure 2. Stream Sediment Sites • Laurinburg and Florence 30 x 60 Minute -Quadrangles .... 2 - - --- - - I ·-·- ------- - - - - -- - - --- - LAURINBURG 100K IIIIADRANGLE • STREAM SEDIMUT Lab I CNlty Lat Long pH card u Th Hf Al Co ,. lfn •• Be Tl V Dy !u LI SID Yb Lu Au ID IIO/<a -------ppo ---"""' """' -----5064 RI081 34.5207 19,3138 6.3 70 S.J 9 14 44000 66 22800 270 300 6.9 1G200 70 0.2 1 .2 29 J 4.2 0.5 5G65 RB08l 34.5727 19,3419 5,2 40 5.5 35 30 6000 166 5800 30 M 1.5 6600 20 11.2 ·1.0 82 16 • 0.8 5066 RBa&J 34.6274 19.Jm 6,0 80 6.0 30 40 2600 105 ·5000 60 100 1.5 lOOO 10 5.9 ·1.D 70 11 • 0.4 5067 RB084. 34.6499 19.3441 5.3 70 4.5 23 33 4400 77 7600 50 100 1.5 4800 20 4.7 •1.D 58 7 • M 5068 RB085 34.6280 19.3661 4.7 30 8.4 41 45 1800 169 -5000 50 M 1,9 3500 10 8.5 -1 .o 123 16 3. I 0.6 5069 RI086 34.5990 19.3955 5.8 70 9.1 51 61 4200 191 6500 80 100 1,4 5800 20 8.9 ·I ,D 119 19 4, I 0.7 5D70 RBD87 34.6475 19,4145 5.9 65 J.O 8 15 12000 49 6500 160 2110 1.8 5300 20 2.7 •1,0 23 4 1,5 0.3 5071 RBD88 34,6191 19.391111 4,8 80 5.6 26 27 9700 107 8600 40 100 3.5 5500 20 4,4 ·I .O 19 8 M D,3 5072 Rlla&9 34,7162 19.3310 5.5 110 8.D 29 37 8500 138 5500 40 100 3.5 4900 20 4,8 ·1.0 '11 9 M 0.6- 507.l -34.7381 19,2883 5.4 45 6.6 ,o 46 M 40 •5000 N M I .2 1000 M 1.6 N 33 I M D.2 5D74 RB091 34.6814 19.2983 s.o 60 5.8 21 21 6300• 19 ·5000 60 100 2.6 6700 JO 5.8 ·1.0 l4J 9 M 0.5 5075 RB092 34.6440 19,2492 5.1 60 14.5 66 62 5400 307 8900 100 100 3.4 9200 40 14,6 ·I ,0 210 27 6.5 I .3 5076 R8093 34.6262 19. 1907 6,0 80 17, I 94 64 8300 409 7700 90 2110 4.9 7000 30 15.9 ·1,0 215 34 7,5 1,3 0,035 5184 RIG25 34.9591 19.6658 6.7 20 5.0 34 20 23500 149 12500 70 N 5.3 6400 40 a.a ,., 67 11 5.3 0.9 5185 RI026 34,9538 19.6545 6.4 15 5.4 33 22 2500 125 6400 80 400 4,0 6600 20 4.9 -1.0 66 8 3.0 •0,2 5186 RI027 34.8787 19.6408 5.7 15 3.9 18 t8 3300 82 ·5000 40 200 2,8 4300 20 s.o -1.0 52 12 3.0 0.7 5187 11028 34.9100 19.5803 5.7 10 2.6 13 13 1600 29 ·5000 50 N 2.0 4600 TO 2.7 .,.o 28 4 2.0 0.3 5188 RI029 34.8600 19.6562 5;7 20 7.5 st 47 5400 234 5300 60 N 3,4 6100 20 7.7 3.5 99 25 4.7 1.2 5189 RIOJO 34,8114 19.6663 5.2 22 J,4 17 22 72110 67 ·5000 40 200 3.5 3700 · 20 3,5 ·I ,D 40 ' 2,6 0.2 0.040 5190 RI031 34.8068 19,7061 ,., 25 2. 1 13 10 17500 60 10300 30 100 5,9 3500 30 T,3 ·1,0 30 5 1,6 0.2 5191 RI032 34.8263 19.6828 ,., 20 2,6 6 13 3200 62 •5000 40 100 2.4 3600 10 3,2 .,.o 29 3 1.3 -0.2 5192 RI033 34.8452 19.6993 5.3 20 11,7 85 81 5700 389 ·5000 50 TOO 4,7 5000 20 10,3 .,.o 185 42 9.0 I .2 5193 RI034 34.8016 19.1937 5, I 25 7.5 31 32 3900 124 ·5000 70 100 2.5 7100 20 7,8 ·1,4 95 15 ,.a 0.5 5194 RI035 34.8512 19,7513 5.7 20 13. T 91 62 2300 440 •5000 TDD 1JOD 4.5 8600 30 17.6 ·1.6 207 50 13,5 1,7 5195 RI036 34.8437 19,7575 5.7 20 16.3 97 50 3900 352 •5000 130 " 2.8 6900 JO 14.5 •1,2 204 31 6.5 ,. 1 5196 RI037 34.9112 19,1926 6.2 30 23,6 239 69 12900 1080 12600 290 " 8. 1 10300 40 19,6 ., .o 543 122 19.7 2.2 51'11 R1038 34.8752 19.8126 5,4 30 1,4 3 8 10100 29 ·5000 100 200 1.4 3600 10 1,3 ·1.0 11 2 " N 5198 RI039 34.8608 19.8232 5.6 35 3.6 19 16 8800 80 ·5000 150 500 3.4 6600 30 4.1 ·1.7 42 8 " 0.6 5199 Rl040 34,8516 19.7752 5.2 23 21 .3 · 107 85 2600 448 ·5000 ,oo 2110 4,6 9800 30 21.0 5.3 258 32 13.4 1.2 5200 RI041 34,8286 19,8166 5.3 23 5. 1 35 26 3900 178 •SOOD 20 100 2,3 3700 10 4.6 " 81 18 2.2 0.4 5201 RIG42 34.8386 19.9000 6. 1 50 10.3 62 56 40300 226. 21100 670 2700 12.3 8400 70 17.3 7.2 144 21 8,7 1 ., 5202 RIG43 34.8547 19.8357 5.9 40 7,2 42 25 47000 215 2JOOO 100 500 7.9 4200 50 8,9 -1.0 93 21 8.4 0.9 5203 RI044 34.9023 19,7438 5.8 25 47.2 247 162 15500 1119 moo 320 zoo TO,] 21000 100 74,D N 601 98 25,3 4.4 5204 RID45 34.9033 19,7160 6.0 30 20,8 155 56 4100 781 ·7700 100 200 5.6 9100 30 29,0 ·1,1 IU 90 14,1 1,7 5205 RI046 34.9396 19.7063 5,6 20 15,6 110 44 6000 375 ,eoo 80 zoo 4,1 7100 IO 11,, •1,0 Ill .. ,, .• ,., 5206 RID47 34,9718 19.7655 5,6 40 49,9 477 110 11300 2424 10900 150 1,00 1,0 tlOO IO .,., .. , 1M .. ... ,._.,,. ··, . 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I 117 65 6700 465 4J800 70 1000 7,7 1000 10 4.9 z.o 2115 ]9 11,6 2,5 5222 11063 34.985] 79.5374 6,8 40 5,4 39 14 8900 216 34200 270 1900 11.z 1400 20 z. 1 l.8 8Z 20 4,9 1. 7 5223 RI064 34.9781 79.8025 N N 6.8 41 17 24700 153 20200 70 zoo 4.4 6600 40 6.0 -1.0 87 IZ 3.6 0.5 5498 SCOOI 34.7321 79.4495 5.5 190 7.5 38 57 18700 144 11500 60 100 Z.4 8400 40 9.0 .,.o 73 I] 4.5 o.8 5499 scooz 34.7068 79.4440 5,] 248 7.2 29 5] 5000 127 ·5000 N N ].I 2900 10 0.9 ·1 .o 65 9 6.0 0.8 5500 SCOO] 34.6667 79.4717 6.] 55 7.6 ]I 54 10500 120 ·5000 N N ].I ]ZOO ]0 N •1,0 n 9 ].7 0.6 5501 SC004 34.611\lOS 79.5015 5.4 111 8.0 ]6 49 5900 168 10000 60 100 z.5 6500 20 6.] ·1 .4 84 1] 4.4 0.5 5502 sta05 34.mo 79.5297 5.5 122 10.] 65 61 5800 287 7500 N N 2.8 23100 20 0.4 -1.0 139 Z5 5.8 1 .z 550] SC006 34.n!O 79.5710 5,Z 59 6.Z 25 42 6400 9Z ·5000 60 100 2.8 4700 20 4,5 -1.0 56 8 4.] 0.7 5504 SC007 34. 7683 79.5668 N N 2.4 11 11 ]700 44 6100 60 100 2. I 5300 zo 1.9 .,.o 21 1 1.2 0.2 5505 SC008 34.8125 79.5819 5.9 141 5.3 N N 16100 N N 40 N N 5900 40 7.0 N N N N N 5506 SC009 34.8022 79.6098 5.6 18 18.4 87 67 .3400 378 8700 90 100 3.8 7000 20 18.0 •1.4 210 12 10.0 1,7 5507 SC010 34,53,18 79.6151 5.6 61 23.5 103 73 3300 412 5900 90 100 5.1 5900 20 19.3 2.8 241 zz 13.3 2, 1 5508 SCOII 34.8416 79,5548 5. 1 27 18,5 100 90 8900 437 8500 N N 4.7 7000 30 N •1.0 233 37 11.Z 1 .6 5509 SC01Z 34.5343 79.5269 6.1 6Z 15.2 6Z 56 2100 260 •5000 50 100 Z.4 4300 10 11,8 .,., 158 23 6.9 1.0 5510 SC013 34.8165 79.4111 6.3 44 14. I 68 103 7000 311 ·5000 40 100 Z.6 6500 20 12.1 ·1.9 170 IZ 7.6 1. 1 5511 SC014 34. 7619 79.4897 6.3 6Z 10.z 47 55 10800 192 9000 N N 4.6 9700 20 0.5 N 109 z 5.8 0.8 5512 SC015 34.7601 79.4104 6.] 112 10,9 54 65 17500 238 5300 N N 4, I N 30 0.4 •1,3 125 15 7, I 1 .5 551] SC016 34.9122 79.51611 4.7 IZ 18.0 99 96 ;mo 455 •5000 70 100 3.6 8000 20 14.7 3, 1 234 30 12, t 1.6 5514 SC0l7 34.9298 79.5528 5.0 15 13,Z 68 5D 8000 300 7600 60 100 3.6 5000 20 11.0 ·t,7 141 22 6.0 1 .o 5515 IC018 34,9633 79.-s.2 10 33.6 151 131 2600 6119 •5000 so 100 3.8 -5400 20 25,3 N 400 55 12.Z 1.7 5516 SC019 _34,9908 79,5188 5.5 11 31.0 144 86 7800 679 ·500D 120 100 9.2 10500 SD 27,7 ·1.D 362 47 16.9 2.9 5517 scozo 34.9041 79.4737 5. 1 19 8.7 35 37 7500 152 •5000 N N 3.7 4700 zo N ·1.0 86 12 5.0 0.9 5518 SC021 34.9541 79.4199. 4.7 9 20.z 95 55 28100 438 8400 70 100 6.2 8100 50 19,9 -1.0 217 32 11.5 2.2 5519 SCOZ2 34.9881 79.4485 4.9 ·10 29.7 155 156 2400 683 10400 120 100 3.4 10400 30 34.0 •1.9 ]66 59 17.Z 2.3 5521 SCOZ4 34,9817 79.4067 4.9 11 26,8 131 107 1300 594 5000 80 100 4.Z -20 21.9 3,5 306 46 15,0 z.1 5522 8COZ5 34.9598 79.3901 4.9 10 27.4 168 135 1700 745 6400 N N 3.2 5900 20 1,8 •1.7 400 ]1 15.7 Z.3 5523 SCOZ6 34.9126 79.4280 6. 1 Z6 6.9 28 38 1900 114 ·5000 N N 1.6 N 2D 0,3 -1.0 6Z 10 4. 1 o.8 5524 SC027 34.88]5 79.3885 5.7 28 42.6 182 216 3300 859 5600 so N 4.4 9200 ]D 26,5 N ~ 29 10,7 2. 1 5525 scoza 34-~ 79,4176 N N N 5] 70 6500 230 •5000 N N 1.5 N N 0.6 ·1.] 121 19 5.4 1.2 5526 SC029 34.8382 79.4305 6. 1 44 10,9 49 65 ]100 215 5100 50 100 z.o 5600 20 9.9 ·1.6 111 20 5.8 o.8 5527 SC030 34.7438 79.3612 6.5 250 55.4 ]11 307 7600 1340 -5000 110 500 5.4 12300 40 43.6 3.8 751 104 20.6 3.9 5528 SC031 34.8159 79.3952 6.4 58 8,0 32 51 3200 138 ·5000 40 100 4. 1 4700 10 7.9 I .9 78 11 . 4.5 o.8 5529 SC05Z 34.7876 79.4395 5.9 81 10,0 42 75 15300 174 14500 50 100 Z.3 6500 40 6.9 ·1,7 99 15 4.4 0.9 Page 8 ----------- UL.alNBURG !oat< IIUADAAIIGLE • SUPPLENl!ITAL ITIUII BEi) IM!NT Lab I Cou"lty Lat Long Ux Ag Al Be Be Ca Co Cr Cu K ID --pp,, ---pp,, -pp, pp, 3317 RID25 34.9591 79.6658 11.2 ·0.1 6 5 D.5 •100 •5 •5 ·2 •1000 3318 11626 34.9538 79.6545 1.7 0.2 2 7 0.5 ·100 ·5 ·5 3 1000 3319 RID27 34.8787 79.6408 3.3 0.3 ·5 •0.5 •100 ·5 ·5 ·2 ·1000 3320 RI028 34.9100 79.5803 2.6 o. 1 1 5 ·0.5 ·100 5 ·5 •2 1000 3321 Rt029 34 .8600 79.6562 2.4 0.2 1 5 •0.5 •100 ·5 ·5 ·2 ·1000 3322 11030 34.8114 79.6663 2.5 0.2 a ·5 •0.5 ·100 ·5 ·5 ·2 ·1000 3323 Rt031 34.8068 79.7061 1 .4 0.3 2 7 •0.5 •100 •5 ·5 ·2 1000 3324 Rt032 34.8263 79.6828 1.2 o.z 2 7 ·0.5 •100 ·5 ·5 ·2 ·1000 3325 11033 34.8452 79.6993 2.9 -o. 1 1 •5 ·D. 5 •100 ·5 ·5 ·2 1000 3326 11034 34.8016 79.1937 2.9 -o. 1 4 ·5 0.5 ·100 ·5 ·5 ·2 1000 3327 RJ035 34.8512 79. 7513 7.3 ·0. 1 1 5 •0.5 ·100 ·5 7 2 ·1000 3328 11036 34.8437 79. r.;:-, 3.7 ·0. 1 2 7 ·0.5 •100 ·5 5 6 2000 3329 11037 34.9112 79.7926 1~~9 •0. 1 2 5 0.5 100 5 ·5 4 2000 mo 11038 34.8752 79.8126 1.3 •0. 1 1 7 0.5 ·100 5 ·5 2 •1000 . 3331 11039 34.8608 79.11232 2.2 ·0. 1 7 ·0,5 •100 5 5 2 2000 3332 11040 34.8516 79.7752 12.8 -o. 1 15 ·0.5 ·100 5 6 2 1000 3333 11041 34.8286 79.8166 1.4 ·0. 1 3 ·5 ·0.5 ·100 5 . ·5 ·2 ·1000 m4 AI042 34.83116 1'9.9000 1.8 •0. 1 2 5 1.0 100 10 12 9 4000 3335 11043 34.8547 79.8357 0.8 ·0. 1 3 5 0.5 ·100 7 7 3 ·1000 3336 11044 34.9023 79.7438 12.1 ·0. 1 2 7 0.5 • 100 ·5 a 3 1000 3337 11045 34.9033 79.7160 9.5 •0. 1 1 5 •0.5 ·100 ·5 •5 ·2 ·1000 3338 RI046 34.9396 79.7063 7.8 ·0. 1 0 ·5 0.5 ·100 ·5 8 2 · 1000 3339 RI047 34.9718 79.7655 7.6 ·D. 1 1 10 0.5 ·100 •5 5 2 2000 pqe 12 - LI pp, ·5 ·5 5 •5 ·5 ·5 ·5 •5 ·5 ·5 5 ·5 5 ·5 5 5 ·5 ID 10 5 5 6 5 -- "9"°Nbll ppn --ppn ·200 ·2 5 ·5 ·200 ·2 25 ·5 ·200 ·2 5 ·5 ·200 2 20 ·5 •200 •2 5 ·5 •200 ·2 5 ·5 ·200 ·2 10 ·5 200 ·2 25 •5 450 •2 25 10 350 ·2 25 10 250 ·2 40 10 350 ·2 40 10 1650 ·2 25 10 200 ·2 40 5 450 ·2 25 5 300 ·2 50 ·5 ·200 •2 25 7 32'.i0 ·2 2'.i 20 550 ·2 10 •5 250 •2 50 ·5 2'.i0 ·2 15 15 200 3 20 ·5 750 3 25 5 ----- p@se&nsr w Y Zn Pl"' -Pl"'PPIPP"'PIA -- 1000 • ID ·I ·5 ·2 ·5 5 1000 •10 ·I ·5 ·2 ·5 ·5 700 •10 ·I ·5 ·2 •5 ·5 700 ·10 •1 ·5 ·2 ·5 •5 700 ·10 ·1 ·5 ·2 •5 ·5 800 •10 1 ·5 ·2 5 ·5 700 •10 •1 ·5 •2 ·5 ·5 700 ·10 •1 •5 •2 5 ·5 1000 17 ·1 ·5 2 20 ·5 800 • 10 ·1 •5 ·2 ·5 ·5 1000 •10 ·I •5 ·2 ·5 ·5 1100 •10 •1 ·5 •2 15 ·5 1100 10 1 .5 ·2 10 7 900 ·10 ·1 •5 ·2 ·5 ·5 700 ·10 1 5 ·2 ·5 ·5 1100 •10 ·1 .5 ·2 5 ·5 700 • 10 ·1 ·5 ·2 ·5 ·5 800 10 ·5 ·2 10 25 900 ·10 ·5 ·2 10 5 1200 15 1 -5 ·2 5 ·5 1000 10 2 ·5 ·2 l5 ·5 900 ,, ·1 ·5 ·2 5 •5 1500 10 ·5 ·2 150 •5 ·1 ------------------- LAIIRIIIJIUIG 100lt QUADRANGLE • !iUl'PLEIENTAL STREAM S!DIICEMT @)s. Lob f County Let Long Ux Ag As Be Be Ce Co er Cu l LI Mg Mo Mb II p Sn Sr V y Zn ID ppa """ """ ppa PP" PP" Pf'III PP" Pfllll """ ppn PP" ppa ppa ppa ppa """' """' """ PP" """ """ ""' 3340 11048 34.9908 79.7530 5,6 •0, 1 3 15 0,5 ·100 5 8 z 3000 6 BOO .z 45 5 1000 IZ 1 ·5 .z Z5 5 335Z 11061 34.9361 79,8166 z.o o.z m Z.5 100 1Z 6 11 11000 1Z 1650 .z Z5 7 800 Z7 -1 ·5 .z ·5 45 3353 RI06Z 34, 998Z 79,8671 2.6 •0.1 47 1 .5 100 7 74 7 14000 9 1750 -2 15 10 1100 1Z •1 5 .z 5 Z5 3354 11063 34.9853 79.8374 1,3 o. 1 4 5 1 .o 300 1Z Z3 7 11000 ,, -.z 15 15 1000 ,z 1 10 .z •5 Z7 RI064 34.9781 79.8025 1,2 -0, 1 3 ·5 0.5 •100 ·5 11 4 1000 8 450 ·Z 35 7 700 1Z 1 15 2 5 10 -SC001 34, 73Z1 79.4495 -o. 1 0,, 5 zo ·0.5 ·100 ·5 -5 15 ·1000 9 450 3 5 ·5 800 17 •1 ., .z ·5 1Z 3601 SC002 34.7068 79,4440 -o. 1 •0, 1 4 zo ·0,5 ·100 •5 -5 3 ·1000 •5 -zoo ·2 5 -5 BOO 1Z 1 ·5 -z •5 5 3602 scDlJ3 34,6667 79.4717 •0,1 -o. 1 4 12 0,5 •100 ·5 -5 5 •1000 6 300 .z 5 -5 800 110' 3 ·5 .z 35 15 3603 SC004 34 .6896 79.5015 -o. 1 -o. 1 9 1Z 0,5 ·100 ·5 ·5 4 ·1000 5 700 .z 15 ·5 900 1Z 5 ·5 .z 65 5 3604 SC005 34, 7290 79.5Z97 •0.1 •0, 1 4 17 •0.5 ·100 -5 ·5 3 ·1000 5 700 -2 15 •5 900 • 10 3 10 -z 15 5 3605 SC006 34. 7Z50 79,5710 0,1 -o. 1 z 1Z 0.5 ·100 -S ·5 3 ·1000 7 650 3 10 ·5 900 ·10 •1 5 -z 70 7 3606 SC007 54.7183 79.56611 -o. 1 •0,1 3 5 0,5 •100 ·5 ·5 z 1000 6 650 -2 ·5 5 500 •10 4 ·5 -z 45 7 3607 SCOOB 54.8125 79.5879 0,2 •0, 1 4 .1 -o.5 ·100 ·5 ·5 4 1000 6 300 '2 ·5 ·5 500 ·10 1 ·5 .z ·5 5 3608 BC009 54.802Z 79.609a o. 1 •0, 1 1 5 0.5 ·100 •5 ·5 z 1000 5 750 2 5 ·5 800 •10 •1 ·5 •2 55 -5 3609 SC010 34.8318 79.6151 0,3 -o. 1 2 ·5 0,5 •100 ·5 -5 z 1000 ·5 550 •2 10 •5 700 •10 3 ·5 .z 95 ·5 3610 BC011 54.8416 79.5548 o., -o., 2 7 ·0.5 •100 ·5 •5 15 1000 5 500 3 10 •5 800 • 10 2 ·5 -2 15 65 3611 SC012 34.8343 79.5269 0, 1 -o. 1 2 5 , .o ·100 ·5 ·5 2 1000 ·5 550 2 ·5 •5 800 •10 1 -5 •2 20 •5 361Z SC013 54.8163 79.4811 o.,. -o., z ·5 0,5 -100 ·5 -5 3 1000 6 650 z 15 ·5 900 •10 1 5 ·2 20 10 3613 St014 34. 7619 79,4897 -o. 1 -o. 1 3 10 0,5 •100 ·5 -5 3 1000 5 950 -z 10 1 1000 ·10 3 ·5 -z 10 7 3614 SC015 34.7601 79,4104 -o. 1 -o. 1 3 •5 0,5 ·100 ·5 -5 3 1000 7 700 3 10 -5 800 ·10 1 5 •2 10 10 3615 BC016 34, 9122 79.5169 0,3 -o. 1 1 IZ 0.5 •100 •5 ·5 z ·1000 ·5 zoo .z 5 •5 aoo ·10 3 ·5 -z 120 5 3616 SC017 34,9298 79.5528 0,1 -o. 1 0 5 0.5 ·100 ·5 ·5 3 1000 6 350 z 5 ·5 900 17 -1 ·5 -z 45 10 3617 sco1a 34,0633 79.5666 0,3 -0, 1 3 5 0,5 •100 ·5 ·5 3 1000 5 550 -z 15 5 1200 10 ·1 ·5 .z 170 ·5 3618 SC019 34. 9908 79.5188 0.3 -0.1 . 4 ·5 0,5 •100 -5 •5 5 1000 5 650 -2 5 ·5 1000 •10 3 5 2 95 ·5 3619 SC020 34,9041 79,4737 0,1 •0,1 z ·5 0.5 ·100 ·5 ·5 z ·1000 ·5 350 2 5 ·5 500 ·10 1 ·5 ·2 5 ·5 3620 SC021 34.9541 79.4899 o.z ·0,, 4 ·5 0,5 •100 ·5 ·5 4 1000 5 650 3 5 -5 1000 ·10 ·1 ·5 -z 10 -5 3621 scozz 34,9881 79.4485 D.Z -o., 3 ·5 0,5 •IOD ·5 6 2 1D00 ·5 500 .z 5 ·5 110D •10 ., ·5 -z 100 ·5 3623 SC024 34,9817 79,4067 0,4 -0.1 1 ·5 •0.5 ·100 ·5 5 -z •1000 •5 650 -z 5 ·5 1000 ·10 1 ·5 •2 185 -5 36Z4 SCOZ5 34.9598 79,3901 4,Z -o., z ·5 0,5 •100 5 ·5 3 1000 ·5 750 -z 5 ·5 1000 10 1 ·5 -z Z95 -5 3625 SCOZ6 34, 91Z6 79.4280 0,, -0, 1 1 1 ·0,5 ·100 ·5 ·5 z 1000 ·5 400 .z 5 -5 700 •10 z ·5 .z 45· •5 36Z6 SC027 34.8835 79.3885 0.5 -0.1 1 10 •0,5 100 ·5 7 3 ·1000 5 500 .z 10 ·5 1000 12 1 5 .z Z95 ·5 36Z7 sco2a 34 .8807 79.4176 o. 1 •D. 1 z -5 •0,5 ·100 ·5 ·5 3 1000 5 400 .z ·5 17 800 • 10 3 ·5 .z ·5 1 3628 SCOZ9 34,8382 79.4303 0.1 D.1 , 7 ·0,5 •100 ·5 ·5 z 1000 ·5 450 .z ·5 5 600 •ID 3 ID .z 5 5 36Z9 SCO]O 34,7438 79.361Z 0.4 D. 1 0 12 •D.5 100 ·5 -5 7 zooo ·5 1JOD .z 15 7 1000 3Z 3 5 .z Z20 65 5630 SC031 34.8159 79,395Z 0, 1 -o., 5 D.5 ·IDO ·5 z IOOD ·5 450 ·5 -10 10 ·5 3631 SC03Z 34, 7876 79,4395 •D. 1 o. 1 3 1Z 0,5 ·100 ·5 ·5 6 1000 11 400 -z 15 5 700 35 ·5 -z 10 zz P1190 13 I I I I I I I I ATTACHMENT 2 I I I I I I I I I I I ------------------- Lead in Stream Sediment ,.r, '~_,..-~>-\ , .. i~ . r· (--\..-_ 'l 'l, / . / ' :,.,~'" L.,__ -.:....--..._ -~ ,.,,/'" Inflection Point Pb(ppm) Ii] 5 iJ 1] Ii] 15 0 20 11 25 G-id Cell Interpolated Thematic Grd C=II =1 : miles North Carolina Geological Survey, 1999 l miles 100 I * I Approximate Site Location I ------------------- Manganese in Groundwater Inflection Point Mn (ppb) North Carolina Geological Survey, 1999 [ii 12.5 □ 25 il 5J 0 100 Ii 200 3rid Cell nt:~rpolctej -hematic Gri:J C=II ;; ' .5 mi es •ti ) ~·· ' I"-, ... ~ ' I ,, .,J ·;/q·• 0 I Sl miles 100 I * I Approxima1e Site Location I ";, 5 ;r\ ------------------- Vanadium in Stream Sediment Inflection Point V (ppm) Ii] .::11.25 Ii 22.5 Ii] 45 90 ii >'80 Grid :sll lntsrpola:ed T1:!matic '.::rid C:! I =1.5 milES North Carolina Geological Survey, 1999 0 Sl 100 I * I Approximate Site Loca1ion I I I I I I I I I I I I I I I I I I I ATTACHMENT 3 ------------------- ;;.c .. .. N N .. .. N N V, 8 V, 0 V, V, 8 V, § V, ✓,,. 0 0 0 0 0 0 0 :-,; 0 0 0 0 0 0 0 0 0 0 0 > <..9 2/1/1996 ~ 3>6 ~ "' <..9..9 9/1/1996 "" 6 4/1/1997 ~ ..9..9 ¾ :.> 11/1/1997 ~ ..9..9 6/1/1998 ¾ :.> ~ 1/1/1999 cl' ..9.s, "6 o' 8/1/1999 V, ~ <..9 ~ 3>c!' 3/1/2000 ~ <..9 10/1/2000 <!!., 3>.s, ~ ;;.c <..9..9 5/1/2001 ✓6 3> 12/1/2001 ~ ¾~ 7/1/2002 > "'?°'b 2/1/2003 ?, ¾ 9/1/2003 % l.b.,, ¾ 4/1/2004 ~ l.b"' 11/1/2004 ~ ~ l.b_,, 6/1/2005 ¾ 1/1/2006 %, Oo,,. ½ 8/1/2006 ~ l.bs 3/1/2007 ;g., "q,> I 10/1/2007 5/1/2008 I I s: I I s: ~ ~ ;: --i --i ;: V, V, ., V, V, ., I :, I :, "' 3 N 3 "' 1-1-., ., :, ~ ~ :, w 11) N 11) V, C C V, 11) 11) c c ~ ~ C C I I I I I I I I I I I I I I I I I I I 0 U) U) I'-CX) en en 0 ..... N N ..,.. st "' "' U) I'-CX) en en en en en en 0 0 0 0 0 0 0 0 0 0 0 en en en en en en 0 0 0 0 0 0 0 0 0 0 0 ..... ..... ..... ..... ..... ..... N N N N N N N N N N N --------------------------------------------------------------------..... ..... ..... ..... ..... ..... ..... ..... ..... ..... ..... ..... ..... ..... ..... ..... ..... --------------------------------------------------------------------N ..... CX) "' N ..... CX) "' N ..... CX) "' N ..... CX) "' N ..... ..... ..... ..... Note: Prior to January 17th 2001, the laboratory detection limit was 5ug/L which is equal to a value of 1,000 on the graph. MW-13 -Beryllium {ug/L X 200} -TSS{mg/L) -------------------z ..... ..... ~ ,._, ,. "' 00 0 ,._, 0 0 8 8 0 0 ~ 0 0 0 0 0 0 2/1/1996 2/1/1996 9/1/1996 "C "C 9/1/1996 :J. :J. 4/1/1997 0 0 4/1/1997 ~ ~ 00 11/1/1997 "' "' 11/1/1997 00 6/1/1998 ~~ 6/1/1998 --1/1/1999 1/1/1999 :,-:,- (I) (I) Q. Q. 8/1/1999 8/1/1999 ii 3/1/2000 3/1/2000 0 0 10/1/2000 10/1/2000 ::, :::, 5/1/2001 3 3 5/1/2001 ;:;: ;::;.: 12/1/2001 i3' o' 12/1/2001 ~ ~ Z< 7/1/2002 7/1/2002 -· Dl " :::, 2/1/2003 ,_. Dl 2/1/2003 ~ Q. :; c· 9/1/2003 9/1/2003 el 3 4/1/2004 .... ~ 4/1/2004 o"' 11/1/2004 C: 01 11/1/2004 'E!.o 6/1/2005 r c: 6/1/2005 co ;:, 1/1/2006 1/1/2006 8/1/2006 8/1/2006 3/1/2007 3/1/2007 10/1/2007 10/1/2007 5/1/2008 5/1/2008 I I s:: ~ vi r-<D I V, " 3 a. N '2 ~ ~ N s r- X ..... I I I I s:: --i r-< z V, <D " ;;· ~ V, " :, 3 a. " ,,. '2 a. ~ ~ ~ i:" '2 I s r-3 ~ i--i. X '2 r-w V, ~ X s ,._, r-.9 X s ,._, .9