NCD980729602_20000517_Jadco-Hughes_FRBCERCLA RA_Treated Water Effluent and Associated Data QA Validation - File 6 2000-OCR

CONESTOGA-ROVERS
& ASSOCIATES
651 Colby Drive, Waterloo, Ontario, Canada N2V 1 C2
Telephone: [phone] Fax: [phone] www.CRAworfd.com
TO: Dan Kieswetter
FROM: Anita Kieswetter/ev/395 9(
RE: Data Quality Assessment and Validation for
Two Liquid Samples Collected from the
Jadco-Hughes Site in Belmont, North Carolina
(Lot # 120425)
DATE: May 17, 2000
The following details a data quality assessment and validation for results generated by Analytical Services, Inc. (AS!) of Norcross, Georgia for two liquid samples collected from the above-referenced Site. Sample collection was conducted on April 5, 2000. The samples were selectively analyzed for volatile organic compounds (VOC), base-neutral and acid extractable organic compounds (BNA), polychlorinated biphenyls (PCB), cyanide, oil and grease (O&G), target analyte list (TAL) metals, total suspended solids (TSS), biological oxygen demand (BOD), and ammonia. The quality assurance criteria were established by the associated quality assurance project plan and the National Function Guidelines1. The samples are identified in Table 1. The analytical methodologies are listed in Table 2.
Holding Time Periods
The holding time periods are presented in Table 3. On the basis of the sample collection and analysis dates referenced on the chain-of-custody forms and the analytical reports provided by ASI, all extractions and analyses were performed within the required holding time periods. Thus, no qualifications were required.
Method Blank Samples
Contamination of samples contributed by laboratory conditions.or procedures was monitored by the concurrent preparation and analysis of method blank samples. The method blank samples were free from target analytes, above the detection limits, indicating that no significant laboratory contamination occurred.
Surrogate Compound Percent Recoveries (Surrogate Recoveries)
Individual sample performance for the VOC, BNA, and PCB pararneters were monitored by surrogate recoveries. The surrogate recoveries were within the control limits for the reported analyses, therefore, no qualifications were required.
Application of quality assurance criteria was consistent with "National Functional Guidelines for Organic Data Review," revised February 1994 and "National Functional Guidelines for Inorganic Data Review," revised February 1994.
ISO 9001
• CRA MEMORANDUM Page2
Matrix Spike/Matrix Spike Duplicate (MS/MSD) Percent Recoveries~ Organic Analyses
To assess the long term accuracy and precision of the analytical method on various matrices, MS/MSD percent recoveries and the relative percent difference (RPO) of the recoveries are determined. Some SVOC, PCB and VOC MS/MSD percent recoveries were outside control limits; however, no sample qualifications were required as qualifications are not granted on MS/MSD data alone. Also, the MS/MSD samples chosen for analysis were non-project specific. The remainder of the MS/MSD percent recoveries and RPD data were within control limits, indicating an adequate level of accuracy and precision was achieved. No qualifications were granted.
Matrix Spike (MS) Percent Recoveries -Inorganic Analyses
The percent recovery data from matrix spike samples were monitored to determine the effects of sample matrix on the accuracy of the inorganics and metals sample preparation and measurement methods.
The MS sample recoveries for metals and inorganics analyses met laboratory-established control limits with the exception of the MS/MSD recoveries for lead and sodium. However, as the MS/MSD samples analyzed were not project specific, no data qualifications were required.
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD) Results
ASI provides and analyzes LCS/LCSD samples in order to further assess the method accuracy and precision. All LCS/LCSD recoveries for target compounds met acceptance criteria with various exceptions in the BNA analyses. Qualifications were required on this basis. All other LCS/LCSD recoveries fell within established control limits. Refer to Table 4 for necessary qualifications.
Laboratory Duplicate Analyses
To monitor the precision of the laboratory analytical methods, laboratory duplicate samples were analyzed for select methods. The laboratory duplicate RPO data were within control limits indicating an adequate level of precision was achieved for these select methods.
Trip Blank Analysis
Potential VOC cross-contamination by diffusion of target compounds through the septum seal of the sample vial into the investigative samples during shipment and storage was monitored by means of a trip blank sample. The trip blank sample was free from detectable concentrations of target analytes indicating that no significant cross-contamination occurred.
Overall Assessment
The data provided by ASI were found to exhibit acceptable levels of accuracy and precision and may be used with the qualifications presented in Table 4.
CRA 3669M~mo39S-Tl
•
TABLE I
SUMMARY OF SAMPLE IDENTIFICATION NUMBERS
JADCO-HUGHES SITE
BELMONT, NORTH CAROLINA
W-3669-JC-040500-149
W-3669-JC-040500-150
Parameters
voe
BNA
PCB
Cyanide
TALMetals
TSS
BOD
Ammonia
Oil and Grease
Notes:
•
TABLE2
. SUMMARY OF ANALYTICAL METHODS
JADCO-HUGHES SITE
BELMONT, NORTH CAROLINA
Methods
MCAWW 1
MCAWW
MCAWW
MCAWW
MCAWW
MCAWW
SM 2
MCAWW
MCAWW
624
625 ·
608
335.2
200 (series)
160.2
5210B
350.3
1664
1 "Methods for Chemical Analysis of Water and Wastes," EPA 600/ 4-79-020, revised March 1983, and subsequent updates.
2 "Standard Methods for the Examination of Water and Wast~water," APHA, 16th edition, 1985 and subsequent updates.
CRA 3669Memo395·T2
Parameters
VOC, Cyanide
BNA,PCB
TALMetals
(excluding mercury)
•
TABLE3
SUMMARY OF HOLDING TIME PERIODS
JADCO-HUGHES SITE
BELMONT, NORTH CAROLINA
Holding Time Periods
' \
14 days from sample collection to completion of analysis
7 days from sample collection to extraction
40 days from extraction to completion of analysis
6 months from sample collection to completion of analysis
Mercury, Oil and Grease,
Ammonia
28 days from sample collection to completion of analysis .
BOD 48 hours from sample collection to beginning of analysis
TSS 7 days from sample collection to completion of analysis
CRA 3669Memo39S· TI
Sample
W-3669-JC-040500-150
LCS -Laboratory Control Sample.
ND -Not detected.
TABLE 4
SUMMARY OF DATA QUALIFICATIONS
JADCO-HUGHES SITE
BELMONT, NORTH CAROLINA
QA/QC Analysis Parameter
LCS/LCSD 4-bromophenyl phenyl ether
bis(2-chloroethoxy)methane
bis(2-chloroisopropyl)ether
hexachlorobenzene
3,3' -dichlorobenzidine
2,4-dinitrotoluene
2,6-dinitrotoluene
di-n-octylphthalate
nitrobenzene
n-nitrosodi-n-propylamine
benzoic acid I
'
2-chlorophenol
2-nitrophenol
Result Qualified
(µg!L) Result
ND(lO) lOUJ
ND{lO) 10 UJ
ND{lO) 10 UJ
ND(lO) 10 UJ
ND(20) 20 UJ
ND{20) 20 UJ
ND(20) 20 UJ
ND(lO) 10 UJ
ND(lO) lOUJ
ND{lO) 10 UJ
ND(50) 50 UJ
ND(lO) 10 UJ
ND(50) 50 UJ
UJ -The parameter was not detected above the sample reporting limit. The sample reporting limit is estimated. J -The result is an estimated value.
CRA 3669Memo395-T4
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A/s1]) I A',. S 1 , __ A_,_A_~_Y_T_I_C_A_L_· _S_E __ R_~,----v_· E_S,_I N_c __ Environmental Monitoring & Laboratory Analysis
11 O Technology Parkway Norcross, GA 30092
[phone] FAX [phone]
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Waterloo, ON 1112\t c1 Ci . ··
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We appreciate the opportunity to provide the analy1ical support for your project. The analytical results in this report are based upon information supplied by you, the client, and are for your exclusive use. If you have any questions regarding this data package, please do not hesitate to call.
Project Manager
Analytical Services Inc., Norcross Laboratory maintains the following certifications, approvals, and accreditations: Georgia laboratory Certification No.'s: 812/351/1301; Alabama laboratory I.D. No.: 41090; Arkansas Certification; California Laboratory Certification No.:2290; Connecticut Laboratory LD. No.: PH-0250; Florida Certification No.'s: 87403/E87315 and Florida QA Plan No.: 910158G; National Sanitation Foundation International Certification No.: 04180; North Carolina Certification No.: 381; North Dakota Certification No.: R·116; Oklahoma laboratory r.o. 9907; South Carolina laboratory 1.0. No.: 98011 ·, Tennessee Laboratory J.D. No.: 02994; United_ States Army Corps of Engineers•MRD Certification: USDA Soil Import license No.: S·36027; and Virginia Laboratory I.D. No.: 00026. All analysis performed by or under the supervision of a Georgia Drinking Water or Wastewater Certified Analyst. Analyst certification numbers available upon request.
This report may not be reproduced, except in full, without written aoornv;al frnm t.no'""--' ~--·
ASI •== •-· A N A L Y T I C A L S E R V I C E S, I N C.
ENVIRONMENTAL MONITORING & LABO RA TORY ANALYSIS
110 TECHNOLOGY PARKWAY• NORCROSS GA 30092 [phone] • [phone] FAX
April 19, 2000
Case Narrative ASI Sample 120425
Two water samples were collected on April 5, 2000 and arrived at ASI on April 6, 2000. One trip blank accompanied the samples. The cooler temperature upon arrival at ASJ was 2° C. Samples were logged into LIMS as AS] report 120425 for analysis of VOA, BNA, PCBs, oil and grease, ammonia, metals, TSS, BOD, and cyanide. All holding times were met.
PCBs were analyzed in batch 56588 using EPA method 608. The MS/MSD recoveries for PCB l016 were high due to the sample matrix. The day blank for April 7 had a low S2 surrogate recovery. The blank was re-analyzed and all surrogates were within acceptance range. All other measurement quality objectives were met.
Base/Neutrals and Acids were analyzed in batches 57011/57012 using EPA method 625. In both batches, several LCS/LCSD recoveries were below acceptance range. In batch 57012, the MS recoveries were low for benzoic acid and 2-nitrophenol. All LCS/LCSD and MS/MSD recoveries were within control limits. In batch 57011, the S2 surrogate recoveries were high for the LSC/LCSD and MS/MSD. The S3 surrogate recovery was high for the MS. In batch 57012, the S3 surrogate recoveries were high for the LCS/LCSD and MS/MSD. No dilutions were made and all other measurement quality objectives were met.
Volatile organics were analyzed in batch 57074 using EPA method 624. MS/MSD recoveries were slightly low for carbon tetrachloride and tetrachloroethene. All recoveries were within control limits. No dilutions were made and all other measurement quality objectives were met for VOA analysis.
Target Analyte List metals were analyzed by JCP in batch 56491 using EPA method 200.7 and GF AA in batch 56467 using EPA methods 279.2, 270.2, and 239.2. Mercury was analyzed by CV AA in batch 56262 using EPA method 245.1. The MS/MSD/PDS recoveries were low for sodium. The MS/PDS recoveries were high for lead. The PDS recovery was high for potassium. All other measurement quality objectives were met for T AL metals.
BOD was analyzed in batch 57063 using Standard method 52 lO B. The LCS recovery for the high standard was slightly above acceptance range but within control limts. The sample was reported as estimated due to a blank result that was outside of acceptance limits. All other measurement quality objectives were met.
•
TSS was analyzed in batch 57124 using EPA method 160.2 All measurement quality objectives were met.
Ammonia nitrogen was analyzed in batch 56165 using EPA method 350.3. All measurement quality objectives were met.
Cyanide was analyzed in batch 57154 using EPA method 335.2. All measurement quality objectives were met.
Oil and grease was analyzed in batch 57220 using EPA method 1664. There was no sample available to be analyzed for the MSD. All other measurement quality objectives were met.
c~
Qua Ii ty Assurance
•-•-I AS I I A N AL y T I C A L s E R V I ~ E S, I N C 0 _____ E_n_v_i-ro_n_m_e_n_t_a_l _M_o_n_it_o_ri_n_g_&_L_a_b_o_ra_t_o_ry_A_n_a_ly-s-is ____ _
Conestoga-Rovers & Associates
651 Colby Drive
Waterloo, ON N2V -1 C2 ·
Attention: Ms. Anita Kieswetter
Report No. 120425-1
11 0 Technology Parkway Norcross. GA 30092
[phone] FAX [phone]
Laboratory Report
Sample Description
Conestoga-Rovers & Associates
April 19, 2000
Water, composite, Jadco-Hughes, Project #3669, W-3669-JC-040500-149, 04/05/2000, 15:00, received 04/06/2000
Analytical
Method Analyte Result
General Chemistry
SM 5210 B Biochemical Oxygen Demand (BOD5) BOLE
! EPA350.3 Ammonia Nitrogen (N)
EPA 160.2 Total Suspended Solids
Metals
EPA 200.7 Total Aluminum (Al)
EPA 200.7 Total Antimony (Sb)
EPA 200.7 Total Arsenic (As)
EPA 200.7 Total Barium (Ba)
EPA200.7 Total Beryllium (Be)
EPA 200.7 Total Cadmium (Cd)
EPA200.7 Total Calcium (Ca)
EPA 200.7 Total Chromium (Cr)
EPA200.7 Total Cobalt (Co)
EPA 200.7 Total Copper (Cu)
EPA 200.7 Total Iron (Fe)
EPA 239.2 Total Lead (Pb)
EPA 200.7 Total Magnesium (Mg)
EPA200.7 Total Manganese (Mn)
EPA 245.1 Total Mercury (Hg)
EPA 200.7 Total Nickel (Ni)
EPA 200.7 Total Potassium (K)
EPA 270.2 Total Selenium (Se)
EPA 200.7 Total Silver (Ag)
EPA 200.7 Total Sodium (Na)
BDL • Below Detection Limit
E -Estimated concentration
0.1
5
Target Analyte List -Metals
BDL
BDL
BDL
0.05
BDL
BDL
32
BDL
BDL
BDL
0.2
BDL
9.8
0.12
BDL
BDL
2.5
BDL
BDL
8.4
Detection Limit Units
5 mg/L
0.1 mg/L
5 mg/L
0.2 mg/L
0.05 mg/L
0.01 mg/L
0.01 mg/L
0.001 mg/L
0.005 mg/L
0.05 mg/L
0.01 mg/L
0.05 mg/L
0.02 mg/L
0.1 mg/L
0.003 mg/L
0.05 mg/L
0.015 mg/L
0.0002 mg/L
0.02 mg/L
0.2 mg/L
0.005 mg/L
0.01 mg/L
0.05 mg/L
Page 1 of 2 ·
Report No. 120425-1
Sample Description
Conestoga,Rovers & Associates
•-April 19, 2000
Water, composite, Jadco-Hughes, Project #3669, W-3669-JC-040500-149,-04/05/2000, 15:00, received 04/06/2000
Analytical
Method Analyte
EPA 279.2 Total Thallium (Tl)
EPA 200.7 Total Vanadium {V)
EPA 200.7 Total Zinc (Zn)
BDL -Below Detection Limit
E -Estimated concentration
Result Detection Limit Units
BDL 0.002 mg/L BDL 0.02 mg/L
0.15 0.02 mg/L
Page 2 of 2
•-•-I AS· I AN AL y TIC AL s ERV~ Es, INC B _____ E_n_v_i_ro_n_m_e_n_t_a_l_M_o_n_it-o-ri_n_g_&_L_a_b_o_ra_t_o_ry_A_n_a_ly_s
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____ _
Conestoga-Rovers & Associates
651 Colby Drive
· Waterloo, ON N2V -1C2
Attention: Ms. Anita Kieswetter
Report No. 120425-2
11 0 Technology Parkway Norcross, GA 30092
[phone] FAX [phone]
Laboratory Report
Sample Description
Conestoga-Rovers & Associates
April 19, 2000
Water, grab, Jadco-Hughes, Project #3669, W-3669-JC-040500-150, 04/05/2000, 15:30, received 04/06/2000
Analytical
Method
EPA 335.2
EPA 1664
EPA624
EPA624
EPA624
EPA624
EPA624
EPA624
EPA624
EPA 624
EPA624
EPA624
EPA624
EPA624
EPA624
EPA624
EPA624
EPA 624
EPA 624
EPA624
EPA624
EPA624
EPA624
Analyte
General Chemistry
pH (on s_ite)
Total Cyanide (CN)
Oil and Grease
Volatile Organics
Acetone
Benzene
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Dibromochloromethane
1, 1-Dichloroethane
1,2-Dichloroethane
1, 1-Dichloroethene
1,2-Dichloroethene (total)
1 ,2-Dichloropropane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethylbenzene
BDL -Below Detection Limit
Result
7.7
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
· BDL
BDL
BDL
4 '
BDL
BDL
BDL
BDL
BDL
14
BDL
BDL
BDL
BDL
Deiection Limit
0.01
6
100
2
10
10
10
100
5
2
10
5
2
10
10
2
2
2
2
2
2
2
2
Units
mg/L
mg/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
, ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Page 1 of 4 ·
. ' •== • Report No. 120425-2
April 19, 2000 Sample Description
Conestoga,Rovers & Associates Water, grab, Jadco-Hughes, Project #3669, W-3669-JC-040500-150, 04/05/2000, 15:30, received 04/06/2000
Analytical
Method Analyte Result Detection Limit Units
EPA 624 2-Hexanone BDL 50 ug/L EPA 624 Methylene chloride BDL 10 ug/L EPA624 1, 1,2,2-Tetrachloroethane BDL 2 ug/L EPA 624 Tetrachloroethene BDL 2 ug/L EPA 624 Toluene BDL 2 ug/L EPA624 1, 1, 1-Trichloroethane BDL 2 ug/L EPA 624 1, 1,2-Trichloroethane BDL 2 ug/L EPA 624 Trichloroethene ,5 2 ug/L EPA624 Vinyl chloride BDL 10 ug/L EPA 624 Xylenes BDL 2 ug/L .
Acid Extractable Organics
EPA 625 Benzoic Acid BDL 50 ug/L EPA 625 4-Chloro-3-methylphenol BDL 10 ug/L EPA 625 2-Chlorophenol BDL 10 ug/L EPA 625 2,4-Dichlorophenol BDL 10 ug/L EPA 625 2,4-Dimethylphenol BDL, 10 ug/L EPA 625 2,4-Dinitrophenol BDL 50 ug/L EPA 625 4,6-Dinitro-2-methylphenol BDL 50 ug/L EPA 625 2-Methylphenol BDL 10 ug/L EPA 625 4-Methylphenol BDL 10 ug/L EPA 625 2-Nitrophenol BDL 50 ug/L EPA 625 4-Nitrophenol BDL 50 ug/L EPA 625 Pentachlorophenol BDL 20 ug/L EPA625 Phenol BDL 10 ug/L EPA625 2,4,6-Trichlorophenol BDL 10 ug/L EPA625 2,4,5-Trichlorophenol BDL 10 ug/L
Base/Neutral Extractable Organics
EPA 625 Acenaphthene BDL 10 ug/L EPA 625 Acenaphthylene BDL 10 ug/L EPA 625 Anthracene BDL 10 ug/L EPA625 Benzo(a)anthracene BDL 10 ug/L EPA625 Benzo(b )fluoranthene BDL 10 ug/L EPA 625 Benzo(k)fluoranthene BDL 10 ug/L EPA 625 Benzo(a)pyrene BDL 10 ug/L EPA 625 Benzo(ghi)perylene BOL 10 ug/L EPA 625 Benzyl butyl phthalate BDL 10 ug/L EPA 625 Bis(2-chloroethyl)ether BDL 10 ug/L EPA625 Bis(2-chloroethoxy)methane BDL 10 ug/L EPA625 Bis(2-ethylhexyl)phthalate BDL 10 ug/L
BDL -Below Detection Limit
Page 2 of 4 ·
•== •-Report No. 120425-2
April 19, 2000 Sample Description
Conestoga-Rovers & Associates Water, grab, Jadco-Hughes, Project #3669, W-3669-JC-040500-150, 04/05/2000, 15:30, received 04/06/2000
Analytical
Method Analyte Result Detection Limit Units
EPA 625 Bis(2-chloroisopropyl}ether BDL 10 ug/L EPA 625 4-Bromophenyl phenyl ether BDL 10 ug/L EPA 625 4-Chloroaniline BDL 20 ug/L EPA625 2-Chloronaphthalene BDL 10 ug/L EPA 625 4-Chlorophenyl phenyl ether BDL 10 ug/L EPA 625 Chrysene BDL 10 ug/L EPA 625 Dibenzo(a,h}anthracene BDL 10 ug/L EPA 625 Oibenzofuran BDL 10 ug/L EPA625 Di-n-butylphthalate BDL 10 ug/L EPA 625 1,3-Dichlorobenzene BDL 10 ug/L EPA 625 1,2-Dichlorobenzene BDL 10 ug/L EPA 625 1,4-Dichlorobenzene BDL 10 ug/L EPA625 3,3'-Dichlorobenzidine BDL 20 ug/L EPA 625 Diethylphthalate BDL 10 ug/L EPA 625 Dimethylphthalate BDL 10 ug/L EPA 625 2 ,4-Dinitrotoluene BDL 20 ug/L EPA 625 2,6-Dinitrotoluene BDL 20 ugil EPA 625 Di-n-octylphthalate BDL 10 ug/L EPA625 Fluoranthene BDL 10 ug/L EPA625 Fluorene BDL 10 ug/L EPA 625 Hexachlorobenzene BDL 10 ug/L EPA 625 Hexachlorobutadiene BDL 10 ug/L EPA 625 Hexachlorocyclopentadiene BDL 10 ug/L EPA 625 Hexachloroethane BDL 2 ug/L EPA 625 lndeno(1,2,3-cd)pyrene BDL 10 ug/L EPA625 lsophorone BDL 10 ug/L EPA 625 2-Methylnaphthalene BDL 10 ug/L EPA625 Naphthalene BDL 10 . ug/L EPA 625 2-Nitroaniline BDL 50 ug/L EPA 625 3-Nitroaniline BDL 50 ug/L EPA625 4-Nitroaniline BDL 50 ug/L EPA625 Nitrobenzene BDL 10 ug/L EPA 625 N-Nitrosodiphenylamine BDL 10 ug/L EPA 625 N-Nitrosodi-n-propylamine BDL 10 ug/L EPA 625 Phenanthrene BDL 10 ug/L EPA 625 Pyrene BDL 10 ug/L EPA 625 1,2,4-Trichlorobenzene BDL 10 ug/L
PCB's
EPA 608 PCB 1016 BDL 1.0 ug/L EPA 608 PCB 1221 BDL 1.0 ug/L
BDL -Below Detection Limit
Page 3 of 4
Report No. 120425-2
Sample "Description
Conestoga-.Rovers & Associates
•-April 19, 2000
Water, grab, Jadco-Hughes, Project #3669, W-3669-JC-040500-150, 04/05/2000, 15:30, received 04/06/2000
Analytical
Method Analyte Result Detection Limit Units
EPA608 PCB 1232 BDL 1.0 ug/L EPA608 PCB 1242 BDL 1.0 ug/L EPA608 PCB 1248 BDL 1.0 ug/L EPA608 PCB 1254 BDL 1.0 ug/L EPA 608 PCB 1260 BDL 1.0 ug/L
BDL -Below Detection Limit
Page 4 of 4
.,_ •-~ ANALYTICAL SERV~.ES, INC ~-----E-n-v-ir_o_n_m_e_n-ta_l_M_o_n_ito-r-in_g_&_L_a_b_o_r_a_to
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110 Technology Parkway Norcross, GA 30092 [phone] FAX [phone]
Laboratory Report Conestoga-Rovers & Associates
651 ColbyDrive
Waterloo, ON N2V -1 C2
Attention: Ms. Anita Kieswetter
Report No. 120425-3
Sample Description
Conestoga-Rovers & Associates
April 19, 2000
Water, Jadco-Hughes>Project #3669, W-3669-JC-040500-150, Trip Blank, received 04/06/2000
Analytical
Method
EPA 624
EPA 624
EPA 624
EPA 624
EPA624
EPA624
EPA624
EPA 624
EPA 624
EPA 624
EPA 624
EPA624
EPA 624
EPA 624
EPA 624
EPA 624
EPA 624
EPA 624
EPA 624
EPA 624
EPA 624
EPA 624
EPA 624
EPA 624
EPA 624
EPA 624
Analyte
Volatile Organics
Acetone
Benzene
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone
Carbon disulfide
·· Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Dibromochloromethane
1, 1-Dichloroelhane
1,2-Dichloroethane
1, 1-Dichloroethene
1,2-Dichloroelhene (total)
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethylbenzene
2-Hexanone
Methylene chloride
1, 1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
BDL -Below Detection Limit
Result
BDL
BDL
BDL ·
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL.
BDL
BDL
BDL
BDL
BDL
BDL
BDL
Detection Limit Units
100 ug/L
2 ug/L
10 ug/L
10 ug/L
10 ug/L
100 ug/L
5 ug/L
2 ug/L
10 ug/L
5 ug/L
2 ug/L
10 ug/L
10 , ug/L
2 ug/L
2 ug/L
2 ug/L
2 ug/L
2 ug/L
2 ug/L
2 ug/L
2 ug/L
50 ug/L
10 ug/L
2 ug/L
2 ug/L
2 ug/L
Page 1 of2
Report No. 120425-3
Sample Description
Conestoga,Rovers & Associates
•-April 19, 2000
Water, Jadco-Hughes, Project #3669, W-3669-JC-040500-150, Trip Blank, received 04/06/2000
Analytical
Method Analyte Result Detection Limit Units
EPA 624 1, 1, 1-Trichloroethane BDL 2 ug/l EPA624 1, 1,2-Trichloroethane BDL 2 ug/l EPA624 Trichloroethene BDL 2 ug/L EPA624 Vinyl chloride BDL 10 ug/l EPA 624 Xylenes BDL 2 ug/l
BDL -Below Detection limit
Page 2 of 2
Matrix : Aqueous
Lab Control Information
Analyte
PCB 1016
PCB 1260
Matrix Spike Information
Analyte
PCB 1016
PCB 1260
•
Analytical Services Inc. Batch QC For Report Number : 120.425
PCB's
Page 1
Batch # 56588 Method : EPA 8082 I 608
LC LCD LC %Recovery RPD %Rec %Rec RPD Range Range
100 98 2 64 -124 0 -29 109 105 4 67 -124 0 -23
MS MSD MS %Recovery RPD %Rec %Rec RPD Range Range
162 147 10 62 -126' 0 -34 113 113 0 58 -124 0 -23
•
Analytical Services Inc. Batch QC Surrogate Recovery
PCB's Matrix Aqueous Batch# 56588 Method
Sample
119313
119313MS
119313MSD
119362
56588BLK
56588LCS
56588LCSD
120265-1
120265-2
120265-3
120265-4
120299
DAYBL04/05
120299RA
DAYBL04/07
120425-2
DAYBL04/07RA
120299RA2
120299RR
DAYBL04/13
Sl
S2
% Recovery Objectives
Tetrachloro-m-xylene
Decachlorobiphenyl
File Sl S2
031400027B 97 93 031400029B 80 108 031400030B 71 99 031400028B 87 104 031400024B 6? 61 031400025B 88 70 031400026B 85 66 041000B022B 104 100 041000B023B 115 106 041000B024B 97 104 041000B025B 93 102 041000B021B 55 20 041000B020B 91 88 041100081B 53 21 041100060B 55 39 041100073B 95 87 041100060B 70 60 041100081B 60 22 041300006B 57 25 041300003B 98 93
S3
46 -115
42 -126
S4
Page 2
EPA 8082 /.608
S5 S6
Q.C. Information for Batch# 56588 Page 3 Printed: 04/19/00 14:50:46
Analyte
PCB 1016
PCB 1221
PCB 1232
PCB 1242
PCB 1248
PCB 1254
PCB 1260
Blank Results Information PCB's Method : EPA 8082 / 608
Blank
Result
BDL
BDL
BDL
BDL
BDL
BDL
BDL
Detection
Limit
1.0
1.0
1. 0
1. 0
1.0
1.0
1.0
•-=-•-
Page 4 Q.C. Information for Batch# 56588 Printed: 04/19/00 14:50:46
Sample Batch Information
PCB's Method: EPA 8082 / 608
Preparation Preparation Analysis Sample ID Date Time By Notes Date Time By Inst 56588BLK 03/14/00 1000 JG/JH/R 03/14/00 1715 ELK GC4 56588LCS 03/14/00 1000 JG/JH/R 03/14/00 1731 ELK GC4 56588LCSD 03/14/00 1000 JG/JH/R 03/14/00 174 7 ELK GC4 119313MS 03/14/00 1000 JG/JH/R 03/14/00 1836 ELK GC4 119313MSD 03/14/00 1000 JG/JH/R 03/14/00 1852 ELK GC4 119313 03/14/00 1000 JG/JH/R 03/14/00 1803 ELK GC4 119362 03/14/00 1000 JG/JH/R 03/14/00 1819 ELK GC4 DAYBL04/05 04/05/00 1000 JG/JH/R 04/11/00 0500 SPC GC4 120265-1 04/05/00 1000 JG/JH/R 04/11/00 0532 SPC GC4 120265-2 04/05/00 1000 JG/JH/R 04/11/00 0548'SPC GC4 120265-3 04/05/00 1000 JG/JH/R 04/11/00 0604 SPC GC4 120265-4 04/05/00 1000 JG/JH/R 04/11/00 0620 SPC GC4 DAYBL04/07 04/07/00 0900 JG/KCE 04/11/00 2101 JRS GC4 120425-2 04/07/00 0900 JG/KCE 04/12/00 2149 JRS GC4 120299 04/05/00 1000 JG/JH/R 04/11/00 0516 SPC GC4 120299RA I I , 04/12/00 1159 JRS GC4 120299RR 04/13/00 0800 JG/JH/R · 04/13/00 1902 ELK GC4 DAYBL04/13 04/13/00 0800 JG/JH/R 04/13/00 1814 ELK GC4 DAYBL04/07RA I I 04/12/00 1829 JRS GC4 120299RA2 I I 04/12/00 1950 JRS GC4
•-==-•
Analytical Services Inc. Batch QC For Report Number :120425
Base Neutrals
Page 5
Matrix: Aqueous Batch# 57011 Method : EPA 625
Lab Control Information
Analyte
Acenaphthene
Acenaphthylene
Acetophenone
Aniline
Anthracene
Benzidine
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(ghi)perylene
Benzo(k)fluoranthene
Benzyl butyl phthalate
4-Bromophenyl phenyl ether Bis(2-chloroethoxy)methane
Bis{2-chloroethyl)ether
Bis(2-chloroisopropyl)ether
Carbazole · 2-Chloronaphthalene
4-Chlorophenyl phenyl ether Chrysene
n-Decane
Dibenzo(a,h)anthracene
Di-n-butylphthalate
2,3-Dichloroaniline
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
3,3'-Dichlorobenzidine
Diethylphthalate
Dimethylphthalate
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Ji-n-octylphthalate
:i-Docosane
:i-Dodecane
1-Eicosane
3is(2-ethylhexyl)phthalate n uoranthene
.0 luorene
!exachlorobenzene
!exachlorobutadiene
fexachloroethane
,-Hexadecane
ndeno(l,2,3-cd)pyrene
·sophorone
LC
%Rec
69
69
59
57
73
119
71
70
62
68
76
70
68
62
54
25
69
66
68
69
33
64
71
32
46
43
44
63
49
29
56
60
50
60
40
60
61
70
70
70
47
41
58
67
64
LCD
%Rec
70
71
64
60
74
134
70
70
67
67
68
76
69
64
54
26
70
66
70
69
33
64
74
36
47
44
45
66
52
29
65
69
58
66
41
64
68
71
72
69
48
41
62
67
67
LC
RPD
1
2
8
6
1
12
0
1
7
2
10
9
2
3
1
3
1
0
3
1
1
1
5
9
3
3
2
6
6
3
16
13
15
9
2
7
11
1
3
2
2
0
7
1
5
%Recovery
Range
63 -96
63 -106
25 -125
25 -125
69 -107
7 -142
58 -108
67 -110
53 -121 ·
52 -112
60 -128
42 -98
72 -106
64 -99
46 -90
30 -95
25 -125
65 -95
67 -106
61 -109
25 -125
55 -118
43 -108
25 -125
41 -85
36 -79
40 -82
72 -152
D -66
D -32
61 -101
69 -109
58 -129
25 -125
25 -125
25 -125
62 -113
68 -112
64 -102
75 -112
35 -90
38 -78
25 -125
46 -121
51 -89
RPD
Range
0 -22
0 -21
0 -30
O·-30
0 -22
0 -280
0 -23
0 -23
0 -29
0 -27
0 -29
0 -28
0 -22
0 -23
0 -23
0 -25
0 -30
0 -22
0 -24
0 -27
0 -30
0 -26
0 -25
0 -30
0 -27
0 -26
0 -23
0 -26
0 -36
0 -41·
0 -20
0 -24
0 -28
0 -30
0 -30
0 -30
0 -26
0 -25
0 -24
0 -23
0 -24
0 -22
0 -30
0 -24
0 -23
Analytical Services Inc. Batch QC For Report Number :120425
Base Neutrals
Page 6
Matrix: Aqueous Batch# 57011 Method: EPA 625
Lab Control Information LC Analyte %Rec
1-Methylphenanthrene 76 Naphthalene 58 Nitrobenzene 58 N-Nitrosodi-n-propylamine 58 n-Octadecane · 58 Phenanthrene 72 Pyrene 73 Pyridine 31 alpha-Terpineol 41 n-Tetradecane 56 1,2,4-Trichlorobenzene 53
Matrix Spike Information MS Analyte %Rec
Acenaphthene 72 Acenaphthylene 74 Acetophenone 66 Aniline 67 Anthracene 76 Benzidine 139 Benzo(a)anthracene 73 Benzo(a)pyrene 71 Benzo(b)fluoranthene 68 Benzo(ghi)perylene 68 Benzo(k)fluoranthene 69 Benzyl butyl phthalate 85 1-Bromophenyl phenyl ether 71 3is(2-chloroethoxy)methane 65 3is(2-chloroethyl)ether 58 3is(2-chloroisopropyl)ether 28 carbazole 72 2-Chloronaphthalene 69 1-Chlorophenyl phenyl ether 72 :hrysene 70 1-Decane 41 libenzo(a,h)anthracene 64 li-n-butylphthalate 77 '.,3-Dichloroaniline 37 .,2-Dichlorobenzene 53 .,3-Dichlorobenzene 50 ,4-Dichlorobenzene 51 ,3'-Dichlorobenzidine 71
LCD
%Rec
77
59
60
64
64
71
73
32
43
61
53
MSD
%Rec
69
70
60
59
73
134
72
70
63
66
73
84
67
60
52
24
70
65
69
70
36
64
76
34
48
44
46
68
LC
RPD
1
1
3
10
10
1
1
4
4
8
1
MS
RPD
5
6
9
12
4
3
1
1
8
2
6
2
5
8
11
13
2
6
4
1
12
1
2
7
10
12
10
4
%Recovery
Range
25 -125
50 94
60 -98
62 -98
25 -125
68 -107
58 -108
25 -125
25 125
25 -125
45 -91
%Recovery
Range
55 -103
53 -112
25 -125
25 -125
51 -121
6 -149
50 -119
51 -124
45 -130
42 -114
51 -131
37 -108
61 -114
50 -109
38 -93
19 -96
25 -125
59 -97
54 -118
55 -109
25 -125
39 -118
39 -110
25 -125
25 -110
29 -87
28 -98
39 -171
RPD
Range
0 -30
0 23
0 -24
0 -24
0 -3 0
0 -22
0 -22
0 -30
0 30
0 -30
0 -21
RPD
Range
0 -30
0 -31
0 -30
0 -30
0 -27
0 -37
0 -30
0 -29
0 -30
0 -31
0 -33
0 -32
0 -24
0 -27
0 -28
0 -32
0 -30
0 -32
0 -28
0 -27
0 -30
0 -29
0 -33
0 -30
0 -28
0 -30
0 -27
0 -28
•-== •-
Page 7 Analytical Services Inc. Batch QC Base Neut_rals
Matrix : Aqueous Batch # 57011 Method : EPA 625
Matrix Spike Information MS MSD MS %Recovery RPD Analyte %Rec %Rec RPD Range Range
Diethylphthalate 47 48 1 D -66 0 -36 Dimethylphthalate 30 26 12 D -47 0 -41 2,4-Dinitrotoluene 67 64 5 54 -103 0 -22 2,6-Dinitrotoluene 71 66 7 58 -114 0 -28 Di-n-octylphthalate 62 61 3 55 -137 0 -36 n-Docosane 68 66 3 25 -125 0 -30 n-Dodecane 49 43 12 25 -125 0 -30 n-Eicosane 66 64 3 25 -125 0 -30 Bis(2-ethylhexyl)phthalate 72 70 2 61 -118 0 -31 Fluoranthene 74 72 3 52 121 0 27 Fluorene 75 72 4 56 -111 0 -27 Hexachlorobenzene 72 68 5 52 -133 0 -28 Hexachlorobutadiene 56 51 11 36 -100 0 -26 Hexachloroethane 49 45 10 37 -80 0 -22 n-Hexadecane 65 61 6 25 -125 0 -30 Indeno(l,2,3-cd)pyrene 68 66 3 36 -117 0 -28 Isophorone 69 62 10 43 -94 0 -29 1-Methylphenanthrene 79 78 1 25 -125 0 -30 Naphthalene 63 57 10 46 -102 0 -25 Nitrobenzene 62 57 9 50 -100 0 -26 N-Nitrosodi-n-propylamine 67 61 10 51 -103 0 -32 n-Octadecane 66 64 3 25 -125 0 -30 !'henanthrene 73 71 3 61 -113 0 -26 Pyrene 76 75 1 49 -121 0 -28 ?yridine 42 38 10 25 -125 0 -30 ,lpha-Terpineol 46 41 10 25 -125 0 -30 1.-Tetradecane 67 62 8 25 -125 0 -30 l,2,4-Trichlorobenzene 58 53 9 46 -95 0 -23
•-== •-
Page 8 Analytical Services Inc. Batch QC Surrogate Recovery
Base Neutrals Matrix Aqueous Batch # 57011" Method EPA 625
% Recovery Objectives
Sl Nitrobenzene-d5 35 -114 S2 Benz{a)anthracene-dl2 21 -110 S3 Pyridine-d5 10 -98
Sample File Sl S2 S3 S4 S5 S6
57011BLK Al790 59 81 28 57011LCS Al792 74 247 62 57011LCSD Al794 78 252 85 120262-2MS Al796 82 257 126 120262-2MSD Al798 74 253 89 .120262-2 Al800 68 82 27 120241-1 Al802 75 96 40 DAYBL04/05 Al804 79 99 46 120299 Al806 68 89 36 DAYBL04/06 Al830 68 92 53 120310-2 Al832 63 81 26 120370 Al834 75 91 48 DAYBL04/07 C4061 62 68 41 120400-2 C4063 68 88 36 120425-2 C4065 60 80 33 120412 C4067 50 62 21 AANote: FV=5ML
DAYBL04/12 C4093 70 74 37 120591-2 C4095 67 76 28 DAYBL04/13 Al904 66 84 40 120585-1 Al906 80 101 44 120595-2 Al908 71 89 44 120595-2DUP Al910 65 87 47 120613-2 Al912 71 102 51 DAYBL04/14 Al914 59 79 40 120626 Al916 61 83 41 120720-2 Al918 79 99 27 DAYBL04/17 Al942 66 96 38 120727-2 Al944 34 42 22 120617-2 Al946 30 22 0
Q.C. Information for Batch# 57011
•-
Page 9 Printed: 04/19/00 14:50:48
Blank Results Information Base Neutrals Method: EPA 625
Analyte
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
Benzo(ghi)perylene
Benzyl butyl phthalate
Bis(2-chloroethyl)ether
Bis(2-chloroethoxy)methane
Bis(2-ethylhexyl)phthalate
Bis(2-chloroisopropyl)ether
4-Bromophenyl phenyl ether 4-Chloroaniline
2-Chloronaphthalene
4-Chlorophenyl phenyl ether Chrysene
Dibenzo(a,h)anthracene
Dibenzofuran
Di-n-butylphthalate
1,3-Dichlorobenzene
1,2-Dichlorobenzene
1,4-Dichlorobenzene
3,3'-Dichlorobenzidine
Diethylphthalate
Dimethylphthalate
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Di-n-octylphthalate
Fluoranthene
Fluorene
Hex~chlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadiene
Hexachloroethane
~ndeno(l,2,3-cd)pyrene
Isophorone ' 2;-Methylnaphthalene
l>/aphthalene
2-Nitroaniline ' 3-Nitroaniline ' 4-Nitroaniline
Nitrobenzene ' ~-Nitrosodiphenylamine
~-Nitrosodi-n-propylamine
Phenanthrene
I P.yrene
1~2,4-Trichlorobenzen~
I
Blank
Result
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
Detection
Limit
10
10
10
10
10
10
10
10
10
10·
.10
10
10
10
20
10
10
10
10
10
10
10
10
10
20
10
10
20
20
10
10
10
10
10
10
2
10
10
10
10
50
50
50
10
10
10
10
10
10
•==-•
Page 10 Q.C. Information for Batch# 57011 Printed: 04/19/00 14:50:48
Sample Batch Information
Base Neutrals Method : EPA 625
Preparation Preparation Analysis Sample ID Date Time By Notes Date Time By Inst 57011BLK· 04/04/00 1000 JG/JH/R 04/05/00 1942 RAC 5973A 57011LCS 04/04/00 1000 JG/JH/R 04/05/00 2045 RAC 5973A 57011LCSD 04/04/00 1000 JG/JH/R 04/05/00 2147 RAC 5973A 120241-1 04/04/00 1000 JG/JH/R 04/06/00 0156 RAC 5973A DAYBL04/05 04/05/00 1000 JG/JH/R 04/06/00 0258 RAC 5973A 120299 04/05/00 1000 JG/JH/R 04/06/00 0400 RAC 5973A 120262-2MS 04/05/00 1000 JG/JH/R 04/05/00 2249 RAC 5973A 120262-2MSD 04/05/00 1000 JG/JH/R 04/05/00 2351 RAC 5973A 120262-2 04/05/00 1000 JG/JH/R 04/06/00 0054 RAC 5973A DAYBL04/06 04/06/00 1000 JG/RP 04/07/00 1724·RAC 5973A 120310-2 04/06/00 1000 JG/RP 04/07/00 1826 RAC 5973A 120370 04/06/00 1000 JG/RP 04/07/00 1929 RAC 5973A DAYBL04/07 04/07/00 0900 JG/KCE 04/11/00 2208 RAC 5973B 120400-2 04/07/00 0900 JG/KCE 04/11/00 2314 RAC 5973B 120412 04/07/00 0900 JG/KCE 04/11/00 0125 RAC 5973B 120425-2 04/07/00 0900 JG/KCE 04/12/00 1219 RAC 5973B DAYBL04/12 I I 04/13/00 0109 RAC 5973B 120591-2 I I 04/13/00 0215 RAC 5973B DAYBL04/13 04/13/00 0800 JG/JH 04/15/00 0456 RAC 5973A 120585-1 04/13/00 0800 JG/JH 04/15/00 0558 RAC 5973A 120585-2 04/13/00 0800 JG/JH I I 120595-2DUP 04/13/00 0800 JG/JH 04/15/00 0803 RAC 5973A 120613-2 04/13/00 0800 JG/JH 04/15/00 0905 RAC 5973A DAYBL04/l4 04/14/00 0800 JG/JH 04/15/00 1009 RAC 5973A 120626 04/14/00 0800 JG/JH 04/15/00 1112 RAC 5973A 120720 04/14/00 1700 JG/JH I I 120595-2 04/13/00 0800 JG/JH 04/15/00 0701 RAC 5973A 120720-2 04/14/00 1700 JG/JH 04/15/00 1216 RAC 5973A DAYBL04/17 04/17/00 0830 JG/JH 04/17/00 2024 RAC 5973A 120727-2 04/17/00 0830 JG/JH 04/17/00 2127 RAC 5973A 120617-2 04/17/00 0830 JG/JH 04/17/00 2230 RAC 5973A DAYBL04/18 04/18/00 0830 JG/JH I I 120813 04/18/00 0830 JG/JH I I 120834 04/19/00 0930 JG/JH/R I I 120837-2 04/19/00 0930 JG/JH/R I I DAYBL04/19 04/19/00 093 0 JG/JH/R I I
•-
Analytical Services Inc. Batch QC For Report Number : 120425
Acids
Page 11
Matrix: Aqueous Batch# 57012 Method: EPA 625
Lab Control Information
Analyte
Benzoic Acid
4-Chloro-3-methylphenol
2-Chlorophenol
o-Cresol
p-Cresol
2,4-Dichlorophenol
2,4-Dimethylphenol
2,4-Dinitrophenol
4,6-Dinitro-2-methylphenol
2-Nitrophenol
4-Nitrophenol
Pentachlorophenol
Phenol
2,4,6-Trichlorophenol
Matrix·Spike Information
Analyte
Benzoic Acid
4-Chloro-3-methylphenol
2-Chlorophenol
o-Cresol
p-Cresol
2,4-Dichlorophenol
2,4-Dimethylphenol
2,4-Dinitrophenol
4,6-Dinitro-2-methylphenol
2-Nitrophenol
4-Nitrophenol
Pentachlorophenol
Phenol
2,4,6-Trichlorophenol
LC
%Rec
18
61
51
50
47
56
58
29
42
46
27
63
25
64
MS
%Rec
10
63
53
53
50
56
58
20
35
44
26
60
26
65
LCD
%Rec
10
63
53
53
50
56
58
20
35
44
26
60
26
65
MSD
%Rec
34
69
57
58
57
62
21
34
46
51
45
63
41
71
LC
RPD
59
4
3
5
6
0
1
34
19
4
3
4
3
2
MS
RPD
110
8
7
9
14
9
94
51
28
14
54
4
46
8
%Recovery
Range
25 -125
59 -100
53 -88
25 -125
25 -125
55 -101
57 -95
5 -104
35 -134
46 -98
17 -52
58 -109
18 -45
58 -101
%Recovery
Range
25 -125
53 -106
51 -89
25 -125
25 -125
50 -106
21 -105
5 -104
11 -149
46 -98
16 -85
30 -109
21 -69
56 -102
RPD
Range
0 -30
0 -23
0 -17
0 -30
0 -30
0 -17
0 -25
0 -42
0 31
0 -30
0 -29
. 0 -22
0 -22
0 -19
RPD
Range
0 -30
0 -30
0 -25
0 -30
0 -30
0 -26
0 -30
0 -42
0 -31
0 -30
0 33
0 -28
0 -29
0 -22
•-== •
Page " ~ ~,; Analytical Services Inc. Batch QC Surrogate Recovery
Acids Matrix Aqueous Batch# 57012 Method EPA 625
% Recovery Objectives
Sl 2-Fluorophenol 21 -100 S2 Phenol-d5 10 -94 S3 Pentafluorophenol 10 -50
Sample File Sl S2 S3 S4 S5 S6
57012BLK Al791 46 28 19 57012LCS Al 793 50 31 63 57012LCSD Al785 49 32 59 120262-2MS Al787 68 53 87 120262-2MSD Al 789 62 51 84 120262-2 Al801 43 27 19 120241-1 Al803 53 32 25 DAYBL04/05 Al805 62 40 14 DAYBL04/06 Al831 59 38 21 120310-2 Al833 41 27 20 120370 Al835 43 28 13 DAYBL04/07 C4062 36 26 15 120400-2 C4064 38 25 14 120425-2 C4066 35 24 13 120412 C4068 33 27 9 ''Note: FV=5ML
DAYBL04/12 C4094 53 36 19 120591-2 C4096 40 27 29 DAYBL04/13 Al905 45 27 17 120585-1 Al907 50 42 31 120595-2 Al909 56 41 31 120595-2DUP Al911 69 41 31 120613-2 Al913 75 45 35 DAYBL04/14 Al915 48 28 20 120626 Al917 55 34 25 120720-2 Al919 52 34 17 DAYBL04/17 Al943 53 33 27 120727-2 Al945 44 30 22 120617-2 Al947 12 8 3
Q.C. Information for Batch# 57012
•
Page 13 Printed: 04/19/00 14:50:49
Blank Results Information
Acids Method : EPA 625.
Analyte
Benzoic Acid
4-Chloro-3-methylphenol
2-Chlorophenol
2,4-Dichlorophenol
2,4-Dimethylphenol
2,4~Dinitrophenol
4,6-Dinitro-2-methylphenol
2-Methylphenol
4-Methylphenol
2-Nitrophenol
4-Nitrophenol
Pentachlorophenol
Phenol
2,4,6-Trichlorophenol
2,4,5-Trichlorophenol
Blank
Result
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
Detection
Limit
50
10
10
10
10
50
50
10
10
50
50
20
10
10
10
•==-•
Page :;_4 Q.C. Information for Batch# 57012 Printed: 04/19/00 14:50:49
Sample Batch Information
Acids Method : EPA 625
Preparation Preparation Analysis Sample ID Date Time By Notes Date Time By Inst 57012BLK 04/04/00 1000 JG/JH/R 04/05/00 2013 RAC 5973A 57012LCS 04/04/00 1000 JG/JH/R 04/05/00 2116 RAC 5973A 57012LCSD 04/04/00 1000 JG/JH/R 04/05/00 2218 RAC 5973A 120262-2MS 04/04/00 1000 JG/JH/R 04/05/00 2320 RAC 5973A 120262-2MSD 04/04/00 1000 JG/JH/R 04/06/00 0023 RAC 5973A 120262-2 04/04/00 1000 JG/JH/R 04/06/00 0125 RAC 5973A 120241-1 04/04/00 1000 JG/JH/R 04/06/00 0227 RAC 5973A DAYBL04/05 04/05/00 1000 JG/JH/R 04/06/00 0329 RAC 5973A 120299 04/05/00 1000 JG/JH/R I I DAYBL04/06 04/06/00 1000 JG/RP 04/07/00 1755·RAC 5973A 120310-2 04/06/00 1000 JG/RP 04/07/00 1857 RAC 5973A 120370 04/06/00 1000 JG/RP 04/07/00 2000 RAC 5973A DAYBL04/07 04/07/00 0900 JG/KCE 04/11/00 2241 RAC 5973B 120400-2 04/07/00 0900 JG/KCE 04/11/00 2346 RAC 5973B ·120412 04/07/00 0900 JG/KCE 04/12/00 0158 RAC 5973B 120425-2 04/07/00 0900 JG/KCE \ 04/12/00 1252 RAC 5973B DAYBL04/12 04/12/00 0730 JH/JG '04/13/00 0142 RAC 5973B 120591-2 04/12/00 0730 JH/JG 04/13/00 0248 RAC 5973B DAYBL04/13 04/13/00 0800 JG/JH 04/15/00 0527 RAC 5973A 120585-1 04/13/00 0800 JG/JH 04/15/00 0629 RAC 5973A 120595-2 04/13/00 0800 JG/JH 04/15/00 0732 RAC 5973A 120595-2DUP 04/13/00 0800 JG/JH 04/15/00 0834 RAC 5973A 120613-2 04/13/00 0800 JG/JH 04/15/00 0937 RAC 5973A DAYBL04/14 04/14/00 0800 JG/JH 04/15/00 1040 RAC 5973A 120626 04/14/00 0800 JG/JH 04/15/00 1144 RAC 5973A 120720 04/14/00 1700 JG/JH I I 120720-2 04/14/00 1700 JG/JH 04/15/00 1249 RAC 5973A DAYBL04/17 04/17/00 0830 JG/JH 04/17/00 2055 RAC 5973A 120727-2 04/17/00 0830 JG/JH 04/17/00 2159 RAC 5973A 120617-2 04/17/00 0830 JG/JH 04/17/00 2302 RAC 5973A DAYBL04/18 04/18/00 0830 JG/JH I I 120813 04/18/00 0830 JG/JH I I 120834 04/19/00 0930 JG/JH/R I I 120837-2 04/19/00 0930 JG/JH/R I I DAYBL04/19 04/19/00 0930 JG/JH/R I I
•
Analytical Services Inc. Batch QC For Report Number :120425 Volatile Organics
Page 15
Matrix: Aqueous Batch# 57074 Method : EPA 624
Lab Control Information
Analyte
Benzene
Bromodichloromethane
Bromoform
Bromomethane
Carbon tetrachloride
Chlorobenzene
Chloroethane
2-Chloroethylvinyl ether Chloroform
Chloromethane
Dibromochloromethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethylbenzene
Methylene chloride
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
LC
%Rec
99
99
88
100
87
106
125
67
99
111
88
104
110
98
98
109
102
102
94
89
107
107
112
84
100
89
104
99
118
93
LCD
%Rec
99
103
94
105
90
107
121
67
98
111
91
109
103
98
96
111
109
103
94
90
108
106
119
89
100
89
105
102
121
92
LC
RPD
1
4
6
5
4
1
4
0
0
0
4
5
7
0
2
2
7
1
0
2
1
0
6
5
0
1
1
3
3
1
%Recovery
Range
79 -121
86 -124
67 -131
50 -212
86 -132
90 -12 7
72 -149
4 9 -14 6
83 -122 ·
70 -128
79 -132
88 -127
80 -122
80 -121
81 -126
75 -127
80 -118
85 -119
83 -121
81 -124
83 -121
77 -118
84 -119
82 -123
83 -117
80 -125
85 -121
91 -125
70 -146
67 -131
RPD
Range
0 -12
0 -15
0 -29
0 -17
0 -15
0 -21
0 -15
0 -19
0 -13
0 -15
0 -24
0 -19
0 -14
0 -13
0 -14
0 -18
0 -13
0 C 14
0 -14
0 -16
0 -13
0 -12
0 -18
0 -19
0 -13
0 -13
0 -16
0 -12
0 -14
0 -14
•-==-•
Analytical Services Inc. Batch QC Volatile Organics
Page 16
Matrix : Aqueous Batch# 57074 Method : EPA 624
Matrix Spike Information
Analyte
Benzene
Bromodichlorornethane
Brornoforrn
Brornornethane
Carbon tetrachloride
Chlorobenzene
Chloroethane
2-Chloroethylvinyl ether Chloroform
Chlorornethane
Dibrornochlorornethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
cis-1,'3-Dichloropropene
trans-1,3-Dichloropropene
Ethylbenzene ·
Methylene chloride
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluorornethane
Vinyl chloride
NC~ Not Calculated
MS
%Rec
100
97
85
92
82
107
93
0
98
110
84
106
99
100
99
107
104
103
85
83
101
109
122
81
98
87
109
103
110
92
MSD
%Rec
102
100
88
94
84
107
88
0
101
112
89
110
98
100
101
103
98
105
91
89
103
106
126
81
101
88
112
103
106
92
MS
RPD
2
3
4
3
2
0
5
NC
3
2
6
4
1
0
2
4
6
2
7
7
1
2
3
1
3
2
3
1
3
1
%Recovery
Range
87 -127
91 -128
67 -131
61 -221
86 -132
90 -127
77 -155
D -130
83 -13 6
67 137
79 -132
88 -127
80 -129
86 -132
88 -135
77 -138
83 -127
88 -127
81 -132
80 -132
87 -129
79 -131
84 -133
82 -123
86 -124
85 -131
89 -129
91 -125
73 -154
72 -13 6
RPD
Range
0 -16
0 -17
0 -29
0 -26
O·-15
0 -21
0 -20
0 -124
0 -19
0 21
0 -24
0 -19
0 -16
0 -18
0 -20
0 -25
0 -17
0 -16
0 -22
0 -23
0 -15
0 -18
0 -27
0 -19
0 -17
0 -13
0 -22
,0 -16
0 -17
0 -17
•== •-
Page 17 Analytical Services Inc. Batch QC Surrogate Recovery
Volatile Organics Matrix Aqueous Batch # 57074 Method EPA 624
% Recovery Objectives
Sl l,2-Dichloroethane-d4 76 -119 S2 Toluene-dB 88 -110 S3 Ethylbenzene-dl0 75 -115 S4 4-Brom6fluorobenzene 86 -115
Sample File Sl S2 S3 S4 S5 S6
57074LCS A0389 102 102 102 103 57074LCSD A0390 102 101 102 99 57074BLK A0381 97 92 97 95 DAYBL04/07 A0423 102 101 102 100 120115 A0424 90 97 100 97 120287 A0425 98 100 103 98 120115MS A0438 103 100 99 99 120115MSD A0439 103 100 97 98 DAYBLK 04/07 A0428 98 100 100 99 120309-2 A0440 97 100 101 103 120310 A0441 101 105 98 104 120400-2 A0442 105 99 101 102 DAYBLK 04/12 A0507 99 107 106 100 120488-1 A0510 107 109 104 97 120488-2 A0511 106 107 · 102 101 120488-3 A0512 104 108 102 107 '"Note: 1:2500 DILUTION
120488-4 A0513 99 105 103 104 "Note: 1:2500 DILUTION
120501-2 A0514 103 106 104 103 '"Note: 1:5 DILUTION
120501-3 A0515 108 108 103 104 '"Note: 1:5 DILUTION
120501-4 A0516 105 108 105 100 '"Note: 1:5 DILUTION
120501-5 A0517 108 108 104 102 '"Note: 1:5 DILUTION
120299 A0518 99 107 107 103 120440 A0519 102 107 103 99 '"Note: 1:5 DILUTION
Matrix
Sample
120488-4D
AANote:
•
Analytical Services Inc. Batch QC Surrogate Recovery
Volatile Organics Aqueous Batch# 57074 Method
% Recovery Objectives
Sl l,2-Dichloroethane-d4 76 -S2 Toluene-dB 88 -S3 Ethylbenzene-dl0 75 -S4 4-Bromofluorobenzene 86 -
File Sl S2 S3 S4
A0523 96 106 102 99 1:5000 DILUTION
DAYBLK 04/13 A0524 101 105 105 103 120650-1 A0550 104 97 99 105 AANote: 1:10 DILUTION
120650-2 A0551 106 98 99 109 AANote: 1:10 DILUTION
120425-2 A0552 101 96 101 98 120425-3 A0553 104 96 99 97 120412 A0554 99 98 101 103
Page 18
EPA 624
119
110
115
115
S5 S6
Q.C. Information for Batch# 57074
•
Page 19 Printed: 04/19/00 14:50:51
Blank Results Information Volatile Organics Method : EPA 624
Analyte
Acetone
Benzene
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Dibromochloromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethene
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethyl benzene
2-Hexanone
Methylene chloride
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Vinyl chloride
Xylenes
Blank
Result
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
. BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
Detection
Limit
100
2
10
10
10
100
5
2
10
5
2
10
10
2
2
2
2
2
2
2
2
50
10
2
2
2
2
2
2
10
2
•==-•
Page 20 Q.C. Information for Batch# 57074 Printed: 04/19/00 14:50:51
Sample Batch Information Volatile Organics Method : EPA 624
Preparation Preparation Analysis Sample ID Date Time By Notes Date Time By Inst 57074LCS I I 04/06/00 1305 REG VOAl 57074LCSD I I 04/06/00 1332 REG VOAl 57074BLK I I 04/06/00 0825 JC VOAl DAYBL04/07 I I 04/07/00 0415 DR VOAl 120115 I I 04/07/00 0821 SW VOAl 120287 I I 04/07/00 0848 LP VOAl 120115MS I I 04/07/00 1626 REG VOAl 120115MSD I I 04/07/00 1652 REG VOAl DAYBLK 04/07 I I 04/07/00 1048 DR VOAl 120309-2 I I 04/07/00 1719 DR VOAl 120310 I I 04/07/00 1 745 DR VOAl 120400-2 I I 04/07/00 1812 DR VOAl DAYBLK 04/12 I I 04/12/00 1955 DR VOAl 120488-1 I I 04/12/00 2115 DR VOAl 120488-2 I I 04/12/00 2141 DR VOAl 120488-3 I I 04/12/00 2208 DR VOAl 120488-4 I I 04/12/00 2234 DR VOAl 120501-2 I I 04/12/00 2301 DR VOAl 120501-3 I I 04/12/00 2328 DR VOAl 120501-4 I I 04/12/00 2354 DR VOAl 120501-5 I I 04/13/00 0021 DR VOAl 120299 I I 04/13/00 004 7 DR VOAl 120440 I I 04/13/00 0114 DR VOAl 120488-4D I I 04/13/00 1014 DR VOAl DAYBLK 04/13 I I 04/13/00 1050 DR VOAl 120650-1 I I 04/13/00 2244 DR VOAl 120650-2 I I 04/13/00 2311 DR VOAl 120425-2 I I 04/13/00 2337 DR VOAl 120425-3 I I 04/14/00 0004 DR VOAl 120412 I I 04/14/00 0030 DR VOAl
•-== •-
Page 21 Analytical Services Inc. Batch QC For Report Number :120425
QC Batch General Information
Batch Analysis Blank Prep. Number Analyte Method Matrix Result Method
56262 Hg EPA 245.1 Aqueous < 0.0002 56467 Pb EPA 239. 2 A·queous < 0.0020 56467 Tl EPA 279.2 Aqueous < 0.0020 56467 Se EPA 270.2 Aqueous < 0.0030 56491 Ag EPA 200 .. 7 Aqueous < 0.0100 56491 Al EPA 200.7 Aqueous < 0.1000 56491 As EPA 200.7 Aqueous < 0.0100 56491 Ba EPA 200.7 Aqueous < 0.0100 56491 Be EPA 200.7 Aqueous < 0.0010 56491 Ca EPA 200.7 Aqueous < 0.0500 56491 Cd EPA 200.7 Aqueous < 0.0030 56491 Co EPA 200.7 Aqueous < 0.0100 56491 Cr EPA 200.7 Aqueous < 0.0100 56491 Cu EPA 200.7 Aqueous < 0.0200 56491 Fe EPA 200.7 Aqueous < 0. 04 00 56491 K EPA 200.7 Aqueous < 0.2000 56491 Mg EPA 200.7 Aqueous\ < 0.0500 56491 Mn EPA 200.7 Aqueous, < 0.0150 56491 Na EPA 200.7 Aqueous < 0.0500 56491 Ni EPA 200.7 Aqueous < 0.0200 56491 Sb EPA 200.7 Aqueous < 0.0060 56491 V EPA 200.7 Aqueous < 0.0200 56491 Zn EPA 200.7 Aqueous < 0.0200 57063 BOD<5 hi SM 5210 B Aqueous < 5.0000 57063 BOD<5 low SM 5210 B Aqueous < 5.0000 57124 TSS EPA 160.2 Aqueous < 5.0000 57154 CN EPA 335.2 Aqueous < 0.0100 57165 NH3-N EPA 350.3 Aqueous < 0.1000 57220 O/G EPA 1664 Aqueous < 5.0000 ~~Note LACK OF SAMPLE FOR MSD. BATCH PASSES ON MS,LCS,LCSD.
;. •== •-
Page 22 Analytical Services Inc. Batch QC For Report Number :120425
Lab Control Information
Batch LC LCD LC %Recovery RPD Number Analyte Method %Rec %Rec RPD Range Range
56262 Hg EPA 245.1 103 105 2 76 -124 0 -20 56467 Pb EPA 239.2 105 111 6 76 -124 0 -20 56467 Tl EPA 279.2 94 100 6 76 -124 0 -20 56467 Se EPA 270.2 102 111 8 76 -124 0 -20 56491 Ag EPA 200.7 102 103 1 85 -115 0 -20 56491 Al EPA 200.7 93 93 0 81 -105 0 -10· 56491 As EPA 200.7 98 98 0 84 -105 0 -11 56491 Ba EPA 200.7 95 92 3 84 -102 0 -10 56491 Be EPA 200.7 95 96 1 84 -104 0 -10 56491 Ca EPA 200.7 93 92 1 83 -109 0 -10 56491 Cd EPA 200.7 95 95 0 82 -109 0 -11 56491 Co EPA 200.7 92 92 0 83 -104 0 -11 56491 Cr EPA 200.7 96 97 1 82 -104 0 -10 56491 Cu EPA 200.7 98 98 0 82 -102 0 -10 56491 Fe EPA 200.7 96 97 1 80 -104 0 -12 56491 K EPA 200.7 109 107 2 85 -115 0 -20 56491 Mg EPA 200.7 91 91 0 82 -106 0 -9 56491 Mn EPA 200.7 93 94 1 84 -102 0 -14 56491 Na EPA 200.7 100 96 4 85 -115 0 -20 56491 Ni EPA 200.7 94 94 0 82 -103 0 -10 56491 Sb EPA 200.7 97 96 1 85 -106 0 -11 564 91 V EPA 200.7 92 93 1 81 -103 0 -11 56491 Zn EPA 200·. 7 100 99 1 83 -105 0 -11 57063 BOD<S hi SM 5210 B 108 100 8 81 -107 0 -12 37063 BOD<S low SM 5210 B 101 106 5 81 -107 0 -12 57124 TSS EPA 160.2 100 98 2 60 -140 0 -40 37154 CN EPA 335.2 91 91 0 75 -125 0 -30 37165 NH3-N EPA 350.3 108 106 2 75 -125 0 -30 57220 0/G EPA 1664 43 64 39 32 -103 0 -40
1atrix Spike Information
Batch MS MSD MS %Recovery RPD Number Analyte Method %Rec %Rec RPD Range Range
;5252 Hg EPA 245.1 104 101 3 60 -132 0 -36 ;6467 Pb EPA 239.2 164 112 38 18 -144 0 -37 ;6467 Tl EPA 279.2 108 81 29 45 -· 139 0 -27 ;6467 Se EPA 270.2 92 69 29 5 -148 0 -39 6491 Ag EPA 200.7 106 103 3 64 -136 0 -16 6491 Al EPA 200.7 93 91 2 61 -123 0 -is 6491 As EPA 200.7 102 100 2 80 -109 0 -12 64 91 Ba EPA 200.7 90 89 1 71 -110 0 -11 6491 Be EPA 200.7 99 97 2 78 -107 0 -11 64 91 Ca EPA 200.7 94 90 4 55 -. 122 0 -18 6491 Cd EPA 200.7 97 95 2 76 -114 0 -11 6491 Co EPA 200.7 93 91 2 74 -105 0 -12
•== • --
Page 2, ,J Analytical Services Inc. Batch QC For Report Number :120425
Matrix Spike Information
Batch MS MSD MS %Recovery_ RPD Number Analyte Method %Rec %Rec RPD Range Range
56491 Cr EPA 200.7 98 96 2 70 -111 0 -12 56491 Cu EPA 200.7 99 98 1 73 -110 0 -15 56491 Fe EPA 200.7 97 96 1 63 -113 0 -19 56491 K EPA 200.7 170 162 5 59 -174 0 -18 56491 Mg EPA 200.7 89 87 2 72 -110 0 -14 56491 Mn EPA 200.7 94 92 2 70 -111 0 -14 56491 Na EPA 200.7 28 23 20 43 -157 0 -37 56491 Ni EPA 200.7 95 93 2 70 -110 0 -14 56491 Sb EPA 200.7 99 98 1 77 -115 0 -12 56491 V EPA 200.7 95 93 2 69 -111 0 -14 56491 Zn EPA 200.7 99 97 2 71 -111 0 -16 57124 TSS EPA 160.2 110 110 0 76 -124 0 -23 57154 CN EPA 335.2 99 101 2 60 -128 0 -13 57165 NH3-N EPA 350. 3 114 116 2 75 -125 0 -30 57220 0/G EPA 1664 73 0 NC 34 -100 0 -18
Post Digestion Spike Information Batch PDS %Recovery Number Analyte Method %Rec Range
56467 Pb EPA 239. 2 149 76 -124 56467 Tl EPA 279.2 86 76 -124 56467 Se EPA 270.2 96 76 -124 56491 Ag EPA 200.7 114 85 -115 56491 Al EPA 200.7 101 85 -115 56491 As EPA 200.7 109 85 -115 56491 Ba EPA 200.7 102 85 -115 56491 Be EPA 200.7 106 85 -115 56491 Ca EPA 200.7 90 85 -115 56491 Cd EPA 200.7 104 85 -115 56491 Co EPA 200.7 101 .85 -115 56491 Cr EPA 200.7 106 85 -115 56491 Cu EPA 200.7 109 85 -115 56491 Fe EPA 200.7 106 85 -115 56491 K EPA 200.7 127 85 -115 56491 Mg EPA 200.7 91 85 -115 56491 Mn EPA 200.7 103 85 -115 56491 Na EPA 200.7 73 85 -115 56491 Ni EPA 200.7 103 85 -115 56491 Sb EPA 200.7 107 85 -115 56491 V EPA 200.7 103 85 -115 56491 Zn EPA 200.7 106 85 -115
•
Analytical Services Inc. Batch QC For Report Number :120425
Unspiked Sample Duplicate Information Batch
Number
57063
57124
57154
57165
Analyte
BOD<5 hi
TSS
CN
NH3-N
Method
SM 5210 B
EPA 160.2
EPA 335.2
EPA 350. 3
Sample 1 Sample
RPD RPD
0 0 o· 8
0 0
0 0
Page 24
2 RPD
Range
0 -12
0 -23
0 -13
0 -30
·'.
•-== •-
Page 25 Q.C. Information for Batch# 56262 For Report Number :120425
Sample Batch Information
Analysis : Hg
Preparation Preparation Analysis Sample ID Tag Date Time By Notes Date Time By Inst
56262BLANK Hg 04/07/00 0840 RAF AQU 04/07/00 1225 RAF HGl 56262LCS Hg 04/07/00 0840 RAF AQU 04/07/00 1228 RAF HGl 56262LCSD Hg 04/07/00 0840 RAF AQU 04/07/00 1230 RAF HGl 120389MS Hg 04/07/00 0840 RAF AQU 04/07/00 1233 RAF HGl 120389MSD Hg 04/07/00 0840 RAF AQU 04/07/00 1235 RAF HGl 120425-lDUP Hg 04/07/00 0840 RAF AQU 04/07/00 1238 RAF HGl 120325 Hg 04/07/00 0840 RAF AQU 04/07/00 1240 RAF HGl 120425-1 Hg 04/07/00 0840 RAF AQU 04/07/00 1242 RAF HGl 120389 Hg 04/07/00 0840 RAF AQU 04/07/00 1245 RAF HGl 120441-1 Hg 04/07/00 0840 RAF AQU 04/07/00 1247 RAF HGl 120441-2 Hg 04/07/00 0840 RAF AQU 04/07/00 1255 RAF HGl 120441-3 Hg 04/07/00 0840 RAF AQU 04/07/00 1257 RAF HGl 120441-4 Hg 04/07/00 0840 RAF AQU 04/07/00 1300 RAF HGl 120441-5 Hg 04/07/00 0840 RAF AQU 04/07/00 1302 RAF HGl 120441-6 Hg 04/07/00 0840 RAF AQU 04/07/00 1305 RAF HGl 120441-7 Hg 04/07/00 0840 RAF AQU 04/07/00 1307 RAF HGl 120441~8 Hg 04/07/00 0840 RAF AQU 04/07/00 1310 RAF HGl 120441-9 Hg 04/07/00 0840 RAF AQU 04/07/00 1312 RAF HGl 120441-10 Hg 04/07/00 0840 RAF AQU 04/07/00 1315 RAF HGl
. I • •== •-
Page 25 Q.C. Information for Batch# 56467 For Report Number : 120425
Sample Batch Information
Analysis : Pb, Tl, Se
Preparation Preparation Analysis Sample ID Tag Date Time By Notes Date Time By Inst
120267 As 04/07/00 0855 EG GFAA 04/10/00 1507 DCF AA3 56467BLANK As 04/07/00 0855 EG GFAA 04/10/00 1507 DCF AA3 56467LCS As 04/07/00 0855 EG GFAA 04/10/00 1507 DCF AA3 56467LCSD As 04/07/00 0855 EG GFAA 04/10/00 1507 DCF AA3 120347-20MS As 04/07/00 0855 EG GFAA 04/10/00 1507 DCF AA3 120347-20MSD As 04/07/00 0855 EG GFAA 04/10/00 1507 DCF AA3 120347-21PDS As 04/07/00 0855 EG GFAA 04/10/00 1507 DCF AA3 120347-22DUP As 04/07/00 0855 EG GFAA 04/10/00 1507 DCF AA3 120193-3RR As 04/07/00 0855 EG GFAA 04/10/00 1507 DCF AA3 120193-lRR As 04/07/00 0855 EG GFAA 04/10/00 1507 DCF AA3. 120347-20 As 04/07/00 0855 EG GFAA 04/10/00 1507 DCF AA3 120347-21 As 04/07/00 0855 EG GFAA 04/10/00 1507 DCF AA3 120347-22 As 04/07/00 0855 EG GFAA 04/10/00 1507 DCF AA3 120347-23 As 04/07/00 0855 EG GFAA 04/10/00 1507 DCF AA3 120384-2 As 04/07/00 0855 EG GFAA 04/10/00 1507 DCF AA3 120425-1 As 04/07/00 0855 EG GFAA 04/10/00 1507 DCF AA3 120347-20 As 04/07/00 0855 EG DISSOLVED 04/10/00 1507 DCF AA3 120347-21 As 04/07/00 0855 EG DISSOLVED 04/10/00 1507 DCF AA3 120347-22 As 04/07/00 0855 EG DISSOLVED 04/10/00 1507 DCF AA3 120347-23 As 04/07/00 0855 EG DISSOLVED 04/10/00 1507 DCF AA3 56467BLANK Pb 04/07/00 0855 EG GFAA 04/11/00 1059 DCF AA3 56467LCS Pb 04/07/00 0855 EG GFAA 04/11/00 1059 DCF AA3 56467LCSD Pb 04/07/00 0855 EG GFAA 04/11/00 1059 DCF AA3 120347-20MS Pb 04/07/00 0855 EG GFAA 04/11/00 1059 DCF AA3 120347-20MSD Pb 04/07/00 0855 EG GFAA 04/11/00 1059 DCF AA3 120347-21PDS Pb 04/07/00 0855 EG GFAA· 04/11/00 1059 DCF AA3 120347-22DUP Pb 04/07/00 0855 EG GFAA 04/11/00 1059 DCF AA3 120193-3RR Pb 04/07/00 0855 EG GFAA 04/11/00 1059 DCF AA3 120193-lRR Pb 04/07/00 0855 EG GFAA 04/11/00 1059 DCF AA3 120267 Pb 04/07/00 0855 EG GFAA 04/11/00 1059 DCF AA3 120347-20 Pb 04/07/00 0855 EG GFAA 04/11/00 1059 DCF AA3 120347-21 Pb 04/07/00 0855 EG GFAA 04/11/00 1059 DCF AA3 120347-22 Pb 04/07/00 0855 EG GFAA 04/11/00 1059 DCF AA3 120347-23 Pb 04/07/00 0855 EG GFAA 04/11/00 1059 DCF AA3 120384-2 Pb 04/07/00 0855 EG GFAA 04/11/00 1059 DCF AA3 120425-1 Pb 04/07/00 0855 EG GFAA 04/11/00 1059 DCF AA3 l20347-20 Pb 04/07/00 0855 EG DISSOLVED 04/11/00 1059 DCF AA3 l20347-21 Pb 04/07/00 0855 EG DISSOLVED 04/11/00 1059 DCF AA3 i.20347-22 Pb 04/07/00 0855 EG DISSOLVED 04/11/00 1059 DCF AA3 1_20347-23 Pb 04/07/00 0855 EG DISSOLVED 04/11/00 1059 DCF AA3 i6467BLANK Cd 04/07/00 0855 EG GFAA 04/11/00 0904 DCF AAl i6467LCS Cd 04/07/00 0855 EG GFAA 04/11/00 0904 DCF AAl i6467LCSD Cd 04/07/00 0855 EG GFAA 04/11/00 0904 DCF AAl .20347-20MS Cd 04/07/00 0855 EG GFAA 04/11/00 0904 DCF AAl· .20347-20MSD Cd 04/07/00 0855 EG GFAA 04/11/00 0904 DCF AAl .2 034 7 -2 lPDS Cd 04/07/00 0855 EG GFAA 04/11/00 0904 DCF AAl .20347-22DUP Cd 04/07/00 0855 EG GFAA 04/11/00 0904 DCF AAl 20193-3RR Cd 04/07/00 0855 EG GFAA 04/11/00 0904 DCF AAl
' ' I, •~ •-
Page 27 Q.C. Information for Batch# 56467 For Report Number :120425
Sample Batch Information
Analysis : Pb, Tl, Se
Preparation Preparation Analysis Sample ID Tag Date Time By Notes Date Time By Inst
120193-lRR Cd 04/07/00 0855 EG GFAA 04/11/00 0904 DCF AAl 120267 Cd 04/07/00 0855 EG GFAA 04/11/00 0904 DCF AAl 120347-20 Cd 04/07/00 0855 EG GFM 04/11/00 0904 DCF AAl 120347-21 Cd 04/07/00 0855 EG GFM 04/11/00 0904 DCF AAl 120347-22 Cd 04/07/00 0855 EG GFM 04/11/00 0904 DCF Ml 120347-23 Cd 04/07/00 0855 EG GFAA 04/11/00 0904 DCF Ml 120384-2 Cd 04/07/00 0855 EG GFM 04/11/00 0904 DCF Ml 120425-1 Cd 04/07/00 0855 EG GFM 04/11/00 0904 DCF Ml 120347-20 Cd 04/07/00 0855 EG DISSOLVED 04/11/00 0904 DCF AAl 120347-21 Cd 04/07/00 0855 EG DISSOLVED 04/11/00 0904 DCF AAl 120347-22 Cd 04/07/00 0855 EG DISSOLVED 04/11/00 0904 DCF AAl 120347-23 Cd 04/07/00 0855 EG DISSOLVED 04/11/00 0904 DCF AAl 56467BLANK Tl 04/07/00 0855 EG GFM 04/11/00 1127 DCF AA2 56467LCS Tl 04/07/00 0855 EG GFAA 04/11/00 1127 DCF AA2 56467LCSD Tl 04/07/00 0855 EG GFAA 04/11/00 1127 DCF AA2 120347-20MS Tl 04/07/00 0855 EG GFAA 04/11/00 1127 DCF AA2 120347-20MSD Tl 04/07/00 0855 EG GFAA 04/11/00 1127 DCF AA2 120347-21PDS Tl 04/07/00 0855 EG GFAA 04/11/00 1127 DCF AA2 120347-22DUP Tl 04/07/00 0855 EG GFAA 04/11/00 1127 DCF M2 120193-3RR Tl 04/07/00 0855 EG GFAA 04/11/00 1127 DCF AA2 120193-lRR Tl 04/07/00 0855 EG GFAA 04/11/00 1127 DCF AA2 120267 . Tl 04/07/00 0855 EG GFAA 04/11/00 1127 DCF M2 120347-20 Tl 04/07/00 0855 EG GFAA 04/11/00 1127 DCF M2 120347-21 Tl 04/07/00 0855 EG GFAA 04/11/00 1127 DCF AA2 120347-22 Tl 04/07/00 0855 EG GFAA 04/11/00 1127 DCF AA2 120347-23 Tl 04/07/00 0855 EG GFAA 04/11/00 1127 DCF AA2 120384-2 Tl 04/07/00 0855 EG GFAA 04/11/00 1127 DCF M2 120425-1 Tl 04/07/00 0855 EG GFAA 04/11/00 1127 DCF M2 120347-20 Tl 04/07/00 0855 EG DISSOLVED 04/11/00 1127 DCF AA2 120347-21 Tl 04/07/00 0855 EG ·DISSOLVED 04/11/00 1127 DCF AA2 120347-22 Tl 04/07/00 0855 EG DISSOLVED 04/11/00 1127 DCF AA2 120347-23 Tl 04/07/00. 0855 EG DISSOLVED 04/11/00 1127 DCF AA2 56467BLANK Be 04/07/00 0855 EG ·GFAA 04/11/00 1333 DCF AA3 56467LCS Be 04/07/00 0855 EG GFAA 04/11/00 1333 DCF AA3 56467LCSD Be 04/07/00 0855 EG GFAA 04/11/00 1333 DCF AA3 120347-20MS Be 04/07/00 0855 EG GFAA 04/11/00 1333 DCF AA3 120347-20MSD Be 04/07/00 0855 EG GFM 04/11/00 1333 DCF AA3 120347-21PDS Be 04/07/00 0855 EG GFAA 04/11/00 1333 DCF AA3 120347--22DUP Be 04/07/00 0855 EG GFAA 04/11/00 1333 DCF AA3 120193-3RR Be 04/07/00 0855 EG GFAA 04/11/00 1333 DCF AA3 120193-lRR Be 04/07/00 0855 EG GFAA 04/11/00 1333 DCF AA3 120267 Be 04/07/00 0855 EG GFAA 04/11/00 1333 DCF AA3 120347-20 Be 04/07/00 0855 EG GFAA 04/11/00 1333 DCF AA3 120347-21 Be 04/07/00 0855 EG GFAA 04/11/00 1333 DCF AA3 120347-22 Be 04/07/00 0855 EG GFAA 04/11/00 1333 DCF AA3 120347-23 Be 04/07/00 0855 EG GFAA 04/11/00 1333 DCF AA3 120384-2 Be 04/07/00 0855 EG GFAA 04/11/00 1333 DCF AA3 120425-1 Be 04/07/00 0855 EG GFAA 04/11/00 1333 DCF AA3
•= •-
Page 28 Q.C. Information for Batch# 56467 For Report Number :120425
Sample Batch Information
Analysis : Pb, Tl, Se
Preparation Preparation Analysis Sample ID Tag Date Time By Notes Date Time By Inst
120347-20 Be 04/07/00 0855 EG DISSOLVED 04/11/00 1333 DCF AA3 120347-21 Be 04/07/00 0855 EG DISSOLVED 04/11/00 1333 DCF AA3 120347-22 Be 04/07/00 0855 EG DISSOLVED 04/11/00 1333 DCF AA3 120347-23 Be 04/07/00 0855 EG DISSOLVED 04/11/00 1333 DCF AA3 56467BLANK Se 04/07/00 0855 EG GFAA 04/11/00 1502 DCF AAl 56467LCS Se 04/07/00 0855 EG GFAA 04/11/00 1502 DCF AAl 56467LCSD Se 04/07/00 0855 EG GFAA 04/11/00 1502 DCF AAl 120347-20MS Se 04/07/00 0855 EG GFAA 04/11/00 1502 DCF AAl 120347-20MSD Se 04/07/00 0855 EG GFAA 04/11/00 1502 DCF AAl 120347-21PDS Se 04/07/00 0855 EG GFAA 04/11/00 15-02 DCF AAl. 120347-22DUP Se 04/07/00 0855 EG GFAA 04/11/00 1502 DCF AAl 120193-3RR Se 04/07/00 0855 EG GFAA 04/11/00 1502 DCF AAl 120193-lRR Se 04/07/00 0855 EG GFAA 04/11/00 1502 DCF AAl 120267 Se 04/07/00 0855 EG GFAA 04/11/00 1502 DCF AAl 120347-20 Se 04/07/00 0855 EG GFAA 04/11/00 1502 DCF AAl 120347-21' Se 04/07/00 0855 EG GFAA 04/11/00 1502 DCF AAl 120347-22 Se 04/07/00 0855 EG GFAA 04/11/00 1502 DCF AAl 120347-23 Se 04/07/00 0855 EG GFAA 04/11/00 1502 DCF AAl 120384-2 Se 04/07/00 0855 EG GFAA 04/11/00 1502 DCF AAl 120425-1 Se 04/07/00 0855 EG GFAA 04/11/00 1502 DCF AAl 120347-20 Se 04/07/00 0855 EG DISSOLVED 04/11/00 1502 DCF AAl 120347-21 . Se 04/07/00 0855 EG DISSOLVED 04/11/00 1502 DCF AAl 120347-22 Se 04/07/00 0855 EG DISSOLVED 04/11/00 1502 DCF AAl 120347-23 Se 04/07/00 0855 EG DISSOLVED 04/11/00 1502 DCF AAl 56467BLANK Sb 04/07/00 0855 EG GFAA 04/12/00 1124 DCF AAl 56467LCS Sb 04/07/00 -0855 EG GFAA 04/12/00 1124 DCF AAl 56467LCSD Sb 04/07/00 0855 EG GFAA 04/12/00 1124 DCF AAl 120347-20MS Sb 04/07/00 0855 EG GFAA 04/12/00 1124 DCF AAl 120347-20MSD Sb 04/07/00 0855 EG GFAA 04/12/00 1124 DCF AAl 120347-21PDS. Sb 04/07/00 0855 EG GFAA 04/12/00 1124' DCF AAl 120347-22DUP Sb 04/07/00 0855 EG GFAA 04/12/00 1124 DCF AAl 120193-3RR Sb 04/07/00 0855 EG GFAA 04/12/00 1124 DCF AAl 120193-lRR Sb 04/07/00 0855 EG GFAA 04/12/00 1124 DCF AAl 120267 Sb 04/07/00 0855 EG GFAA 04/12/00 112.4 DCF AAl 120347-20 Sb 04/07/00 0855 EG .GFAA 04/12/00 1124 DCF AAl 120347-21 Sb 04/07/00 0855 EG GFAA 04/12/00 1124 DCF AAl 120347-22 Sb 04/07/00 0855 EG GFAA 04/12/00 1124 DCF AAl 120347-23 Sb 04/07/00 0855 EG. GFAA 04/12/00 1124 DCF AAl 120384-2 Sb 04/07/00 0855 EG GFAA 04/12/00 1124 DCF AAl 120425-1 Sb 04/07/00 0855 EG GFAA 04/12/00 1124 DCF AAl 120347-20 Sb 04/07/00 0855 EG DISSOLVED 04/12/00 1124 DCF AAl 120347-21 Sb 04/07/00 0855 EG DISSOLVED 04/12/00 1124 DCF AAl L20347-22 Sb 04/07/00 0855 EG DISSOLVED 04/12/00 1124 DCF AAl 1_20347-23 Sb 04/07/00 0855 EG DISSOLVED 04/12/00 1124 DCF AAl
,-• •==
Page 29 Q.C. Information for Batch# 56491 For Report Number :12042'.::i
Sample Batch Information Analysis Ag, Al, As, Ba, Be, Ca, Cd, Co, Cr, Cu, Fe, K, Mg, Mn, Na, Ni Sb V Zn
Preparation Preparation Analysis Sample ID Tag Date Time By Notes Date Time By Inst
56491BLANK 04/13/00 0815 SER TRACE 04/13/00 1255 FBS ICPc 56491LCS 04/13/00 0815 SER TRACE 04/13/00 1258 FBS ICP3 56491LCSD 04/13/00 0815 SE.R TRACE 04/13/00 1301 FBS ICP3 120464-lMS 04/13/00 0815 SER TRACE 04/13/00 1305 FBS ICP3 120464-lMSD 04/13/00 0815 SER TRACE 04/13/00 1308 FBS ICP3 120404-lPDS 04/13/00 0815 SER TRACE 04/13/00 1311 FBS ICP3 120404-2DUP 04/13/00 0815 SER TRACE 04/13/00 1314 FBS ICP3 120633 04/13/00 0815 SER TRACE 04/13/00 1334 FBS ICP3 120394 04/13/00 0815 SER TRACE 04/13/00 1-337 FBS IC!'3 120395-2 04/13/00 0815 SER TRACE 04/13/00 1340 FBS ICP3 120400-1 04/13/00 0815 SER TRACE 04/13/00 1343 FBS ICP3 120404-1 04/13/00 0815 SER TRACE 04/13/00 1321 FBS ICP3 120404-2 04/13/00 0815 SER TRACE 04/13/00 1324 FBS ICP3 120409 04/13/00 0815 SER TRACE 04/13/00 134 7 FBS ICP3 120425-1 04/13/00 0815 SER TRACE 04/13/00 1350 FBS ICP3 120434-1 04/13/00 0815 SER TRACE 04/13/00 1353 FBS ICP3 120438-1 04/13/00 0815 SER TRACE 04/i3/00 1356 FBS ICP3 120438-3 04/13/00 0815 SER TRACE 04/13/00 1400 FBS ICP3 120440 04/13/00 0815 SER TRACE 04/13/00 1426 FBS ICP3 120460 04/13/00 0815 SER TRACE 04/13/00 1430 FBS ICP3 120461 04/13/00 0815 SER TRACE 04/13/00 1433 FBS ICP3 120464-1 04/13/00 0815 SER TRACE 04/13/00 1317 FBS ICP3 120484 04/13/00 0815 SER TRACE 04/13/00 1436 FBS ICP3 120490-1 04/13/00 0815 SER TRACE 04/13/00 1440 FBS ICP3 120494-1 04/13/00 0815 SER TRACE 04/13/00 1443 FBS ICP3 120505 04/13/00 0815 SER TRACE 04/13/00 1446 FBS ICP3 120507 04/13/00 0815 SER TRACE 04/13/00 1449 FBS ICP3
, , I , •--:-•-
Page 30 Q.C. Information for Batch # 570.63 For Report Number :120425
Sample Batch Information
Analysis : BOD<5 hi, B0D<5 low
Preparation Preparation Analysis Sample ID Tag Date Time By Notes Date Time By Inst
57063BLK 04/06/00 0915 CJ/KS YSI5100 04/11/00 1110 CJ/KS 57063LCS 04/06/00 0915 CJ/KS YSI5100 04/11/00 1110 CJ/KS 57063LCSD 04/06/00 0915 CJ/KS YSI5100 04/11/00 1110 CJ/KS 57063LCSLOW 04/06/00 0915 CJ/KS YSI5100 04/11/00 1110 CJ/KS 57063LCSLOWD 04/06/00 0915 CJ/KS YSI5100 04/11/00 1110 CJ/KS 120318-1 04/06/00 0915 CJ/KS YSI5100 04/11/00 1110 CJ/KS 120318-2 04/06/00 0915 CJ/KS YSI5100 04/11/00 1110 CJ/KS 120320-5 04/06/00 0915 CJ/KS YSI5100 04/11/00 1110 CJ/KS 120323 04/06/00 0915 CJ/KS YSI5100 04/11/00 1110 CJ/KS 12 0325 04/06/00 0915 CJ/KS YSI5100 04/11/00 1110 CJ/KS 120336 04/06/00 0915 CJ/KS YSI5100 04/11/00 1110 CJ/KS 120336DUP 04/06/00 0915 CJ/KS YSI5100 04/11/00 1110 CJ/KS 120339-1 04/06/00 0915 CJ/KS YSI5100 04/11/00 1110 CJ/KS 120340 04/06/00 0915 CJ/KS YSI5100 04/11/00 1110 CJ/KS 120342 04/06/00 0915 CJ/KS YSI5100 04/11/00 1110 CJ/KS 120364-1 04/06/00 0915 CJ/KS YSI5100 04/11/00 1110 CJ/KS 120383 04/06/00 1115 CJ/KS YSI5100 04/11/00 1110 CJ/KS 120378 04/06/00 1115 CJ/KS YSI5100 04/11/00 1110 CJ/KS 57063BLK2 04/06/00 0915 CJ/KS YSI5100 04/11/00 1110 CJ/KS 57063LCS2 04/06/00 0915 CJ/KS YSI5100 04/11/00 1110 CJ/KS 57063LCSD2 04/06/00 0915 CJ/KS YSI5100 04/11/00 .1110 CJ/KS 57063LCSLOW2 04/06/00 0915 CJ/KS YSI5100 04/11/00 1110 CJ/KS 57063LCSLOWD2 04/06/00 0915 CJ/KS YSI5100 04/11/00 1110 CJ/KS 120381-1 04/06/00 1115 CJ/KS YSI5100 04/11/00 1110 CJ/KS 120398-1 04/06/00 1115 CJ/KS YSI5100 04/11/00 1110 CJ/KS 120398-2 04/06/00 1115 CJ/KS YSI5100 04/11/00 1110 CJ/KS 120399-1 04/06/00 1115 CJ/KS YSI5100 04/11/00 1110 CJ/KS 120399-2 04/06/00 1115 CJ/KS YSI5100 04/11/00 1110 CJ/KS 120425-1 04/06/00 1115 CJ/KS YSI5100 04/11/00 1110 CJ/KS 120425DUP 04/06/00 1115 CJ/KS YSI5100 . 04/11/00 1110 CJ/KS 120397-1 04/06/00 1115 CJ/KS YSI5100 04/11/00 1110 CJ/KS 120397-2 04/06/00 1115 CJ/KS YSI5100 04/11/00 1110 CJ/KS 120401-1 04/06/00 1115 CJ/KS YSI5100 04/11/00 1110 CJ/KS 120412 04/06/00 1115 CJ/KS YSI5100 04/11/00 1110 CJ/KS 120417 04/06/00 1115 CJ/KS YSI5100 04/11/00 1110 CJ/KS 57063BLK3 04/06/00 0915 CJ/KS YSI5100 04/11/00 1110 CJ/KS 57063LCS3 04/06/00 0915 CJ/KS YSI5100 04/11/00 1110 CJ/KS 57063LCSD3 04/06/00 0915 CJ/KS YSI5100 04/11/00 1110 CJ/KS 57063LCSLOW3 04/06/00 0915 CJ/KS YSI5100 04/11/00 1110 CJ/KS 57063LCSLOWD3 04/06/00 0915 CJ/KS YSI5100 04/11/00 1110 CJ/KS 57063BLKCBOD 04/06/00 0915 CJ/KS YSI5100 04/11/00 1110 CJ/KS 57063LCSCBOD 04/06/00 0915 CJ/KS YSI5100 04/11/00 1110 CJ/KS 57063LCSDCBOD 04/06/00 0915 CJ/KS YSI5100 04/11/00 1110 CJ/KS 120417 04/06/00 1115 CJ/KS YSI5100 04/11/00 1110 CJ/KS CBOD 120417DUP 04/06/00 1115 CJ/KS YSI5100 04/11/00 1110 CJ/KS CBOD 120.392-2 04/06/00 1330 CJ/KS YSI5100 04/11/00 1110 CJ/KS 120392-1 04/06/00 1330 CJ/KS YSI5100 04/11/00 1110 CJ/KS 120405-1 04/06/00 1400 CJ/KS YSI5100 04/11/00 1110 CJ/KS
Sample ID
120405-2
120428
120426
• == •
Q.C. Information for Batch# 57063 Page 31 For Report Number :120425
Tag
Sample Batch Information
Analysis : BOD<5 hi, BOD<5 low
Preparation Preparation Analysis Date Time By Notes Date Time
04/06/00 14 00 CJ/KS YSI5100 04/11/00 1110 04/06/00 1400 CJ/KS YSI5100 04/11/00 1110 04/06/00 1400 CJ/KS YSI5100 04/11/00 1110
By
CJ/KS
CJ/KS
CJ/KS
Inst
'./. •-. 0::-::-:.-:'.
Page 32 Q.C. Information for Batch# 57124 For Report Number :120425
Sample Batch Information
Analysis : TSS
Preparation Preparation Analysis Sample ID Tag Date Time By Notes Date Time By Inst
57124BLK I I 04/10/00 0900 EAH 57124LCS I I 04/10/00 0900 EAH 57124LCSD I I 04/10/00 0900 EAH 120461MS I I 04/10/00 0900 EAH 120461MSD I I 04/10/00 0900 EAH 120465 I I 04/10/00 0900 EAH 120495-1 I I 04/10/00 0900 EAH 120495-2 I I 04/10/00 0900 EAH 120495-3 I I 04/10/00 0900 EAH 120438-1 I I 04/10/00 09,00 EAH 120438-3 I I 04/10/00 0900 EAH 120433-1 I I 04/10/00 0900 EAH 120434-1 I I 04/10/00 0900 EAH 120425-1 I I 04/10/00 0900 EAH 120378-1 I I 04/10/00 0900 EAH 120397-1 I I 04/10/00 0900 EAH 120397-2 I I 04/10/00 0900 EAH 120400-2 I I 04/10/00 0900 EAH 120423 I l 04/10/00 0900 EAH 120424-1 I I 04/10/00 0900 EAH 120424-2 I I 04/10/00 0900 EAH 120424-3 I I 04/10/00 0900 EAH 120427-1 I I 04/10/00 0900 EAH 120461 I I 04/10/00 0900 EAH 120461DUP I I 04/10/00 0900 EAH 120465DUP I I 04/10/00 0900 EAH 120426 I I 04/10/00 0900 EAH
' 'i ' •-.: •--
Page 33 Q.C. Information for Batch# 57154 For Report Number :120425
Sample Batch Information
Analysis : CN
Preparation Preparation Analysis Sample ID Tag Date Time By Notes Date Time By Inst
57154BLK 04/11/00 1225 JKM MIDI DIST A 04/11/00 1540 JKM GEN 57154LCS 04/11/00 1225 JKM MIDI DIST A 04/11/00 1540 JKM GEN C -57154LCSD 04/11/00 1225 JKM MIDI DIST A 04/11/00 1540 JKM GEN = 120464-2MS 04/11/00 1225 JKM MIDI DIST A 04/11/00 1540 JKM GEN = 120464-2MSD 04/11/00 1225 JKM MIDI DIST A 04/11/00 1540 JKM GEN C -57154CALCHK5 04/11/00 1225 JKM MIDI DIST A 04/11/00 1540 JKM GEN = 57154CALCHK15 04/11/00 1225 JKM MIDI DIST A 04/11/00 1540 JKM GEN 5 120540-2 04/11/00 1225 JKM MIDI DIST A 04/11/00 1540 JKM GEN 5 120464-2 04/11/00 1225 JKM MIDI DIST A 04/11/00 1540 JKM GEN 5 120540-2DUP 04/11/00 1225 JKM MIDI DIST A 04/11/00 15,40 JKM GEN 5 120321-2RR 04/11/00 1415 JKM MIDI DIST B 04/12/00 1320 JKM GEN 5 120401-2 04/11/00 1415 JKM MIDI DIST B 04/12/00 1320 JKM GEN 5 120346-6 04/11/00 1415 JKM MIDI DIST B 04/12/00 1320 JKM GEN 5 120381-2 04/11/00 1415 JKM MIDI DIST B 04/12/00 1320 JKM GEN 5 120425-2 04/11/00 1415 JKM MIDI DIST B 04/12/00 1320 JKM GEN 5 120494-2 04/11/00 1415 JKM MIDI DIST B 04/12/00 1320 JKM GEN 5 120400-2 04/11/00 1415 JKM MIDI DIST B 04/12/00 1320 JKM GEN 5 120362-1 04/11/00 1415 JKM MIDI DIST B 04/12/00 1320 JKM GEN 5 120425-2DUP 04/11/00 1415 JKM MIDI DIST B 04/12/00 1320 JKM GEN 5 57154LCS-TRIP 04/11/00 1415 JKM MIDI DIST B 04/12/00 1320 JKM GEN 5 120218-3RR 04/11/00 1730 JKM MIDI DIST A 04/12/00 1320 JKM GEN 5 120384-1 04/11/00 1730 JKM MIDI DIST A 04/12/00 1320 JKM GEN 5 120490-1 04/11/00 1730 JKM MIDI DIST A 04/12/00 1320 JKM GEN 5 120585-4 04/11/00 1730 JKM MIDI DIST A 04/12/00 1320 JKM GEN 5 120577 04/11/00 1 730 JKM MIDI DIST A 04/12/00 1320 JKM GEN 5 57154LCS QUAD 04/11/00 1730 JKM MIDI DIST A 04/12/00 1320 JKM GEN 5
•-• ·-
Page 34 Q.C. Information for Batch# 57165 For Report Number :12042'.;
Sample Batch Information
Analysis : NH3-N
Preparation Preparation Analysis .Sample ID Tag Date Time By Notes Date Time By Inst
57165BLK 04/11/00 1050 JW 04/11/00 1500 JW 0-9, 57165LCS 04/11/00 1050 JW 04/11/00 1500 JW 0-92 57165LCSD 04/11/00 1050 JW 04/11/00 1500 JW 0-92 57165CALCK 04/11/00 1050 JW 04/11/00 1500 JW 0-92 120398-2MS 04/11/00 1050 JW 04/11/00 1500 JW Oc92 120398-2MSD 04/11/00 1050 JW 04/11/00 1500 JW 0-92 120398-2 04/11/00 1050 JW 04/11/oo. 1500 JW 0-92 120398-2DUP 04/11/00 1050 JW 04/11/00 1500 JW 0-92 120425-1 04/11/00 1050 JW 04/11/00 1500 JW 0-92 120425-lDUP 04/11/00 1050 JW 04/11/00 1,500 JW 0-92 120501-1 04/11/00 1050 JW 04/11/00 1500 JW 0-92 120397-2 04/11/00 1050 JW 04/11/00 1500 JW 0-92 120399-2 04/11/00 1050 JW 04/11/00 1500 JW 0-92 120482 04/11/00 1050 JW 04/11/00 1500 JW 0-92 120490-1 04/11/00 1050 JW 04/11/00 1500 JW 0-92, 120526-4 04/11/00 1050 JW 04/11/00 1500 JW 0-921 120381-1 04/11/00 1050 JW 04/11/00 1500 JW 0-921 120398-1 04/11/00 1050 JW 04/11/00 1500 JW 0-92( 120399-1 04/11/00 1050 JW 04/11/00 1500 JW 0-92( 120478-1 04/11/00 1050 JW 04/11/00 1500 JW 0-92( 120470-10 04/11/00 1050 JW 04/11/00 1500 JW 0-92( 120440 04/11/00 1050 JW 04/11/00 1500 JW 0-92( 120489 04/11/00 1050 JW 04/11/00 1500 JW 0-92( 120535 04/11/00 1050 JW 04/11/00 1500 JW 0-92( 120417 04/11/00 1050 JW 04/11/00 1500 JW 0-92( 120434-1 04/11/00 1050 JW 04/11/00 1500 JW 0-92( 120480-1 04/11/00 1050 JW 04/11/00 1500 JW 0-92( 120480-2 04/11/00 1050 JW 04/11/00 1500 JW 0-92(
,· / .. •-= ~ " • •----
Page 35 Q.C. Information for Batch# 57220 For Report Number :120425
Sample Batch Information
Analysis : 0/G
Preparation Preparation Analysis Sample ID Tag Date Time By Notes Date Time By Inst
57220BLK I I 04/13/00 1015 TS/MH 57220LCS I I 04/13/00 1015 TS/MH 57220LCSD I I 04/13/00 1015 TS/MH 120425 I I 04/13/00 1015 TS/MH 120425MS I I 04/13/00 1015 TS/MH 120600-2 I I 04/13/00 1015 TS/MH 120417 I I 04/13/00 1015 TS/MH 120517-2 I I 04/13/00 1015 TS/MH 120590-6 I I 04/13/00 1015 TS/MH 12 0415 I I 04/13/00 1015 TS/MH 120520-1 I I 04/13/00 1230 TS/MH 120520-2 I I 04/13/00 123 0 TS/MH 120520-3 I I 04/13/00 1230 TS/MH 120325-1 I I 04/13/00 1230 TS/MH 120438-2 I I 04/13/00 1230 TS/MH 120438-4 I I 04/13/00 1230 TS/MH 120595-2 I I 04/13/00 1230 TS/MH 120578-2 I I 04/13/00 1230 TS/MH 120490-2 I I 04/13/00 1230 TS/MH 120585-2 I I 04/13/00 1420 TS/MH 120495-4 I I 04/13/00 1420 TS/MH 120519-2 I I 04/13/00 1420 TS/MH 120433-2 I I 04/13/00 1420 TS/MH 120520-1 I I TPH 04/13/00 1420 TS/MH 120520-2 I I TPH 04/13/00 1420 TS/MH 120520-3 I I TPH 04/13/00 1420 TS/MH 120585-2 I I TPH 04/13/00 1420 TS/MH 120578-2 I I TPH 04/13/00 1230 TS/MH
RETURN RESULTS TO CAA OFFICE NOTED:
_ Balon Rouge, LA (504) 292·9007 _ Charlotte, NC (704) 676--0502 CRA Services V 1 vJ3 ~s
DOCUMENT No. 2 6 1 2 Q -; _ Houston, TX [phone] _ Nashville, TN [phone] ENGINEERING, ENVIRONMENTAL, CONSTRUCTION SERVICES I Lot.f-Z.~urchase Order No. Z); A"Ec-r1t
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_ Oklahoma c;1y, OK [phone] _ Shmveport, LA (318) 888·3?03 CHAIN OF CUSTODY RECORD _ Titusville,FL [phone] X t.Jc:i.,H-.-\ao, Dnt4r10. --· ('5't'/)1Z.<;° -,3'!'/
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TO:
FROM:
CONESTOGA-ROVERS & ASSOCIATES
651 Colby Drive
Waterloo, Ontario, Canada N2V 1 C2
MEMORANDUM
Dan Kieswetter ·
Anita Kieswetter / ev /388 ~
RE: Data Quality Assessment and Validation for
Two Liquid Samples Collected from the
Jadco-Hughes Site in Belmont, North Carolina
(Lot# 115472)
• TELEPHONE: [phone] (Colby Ottice)
[phone] (Bathurst Office)
FACSIMILE: [phone]
REF.NO.: 3669
DATE: January 3, 2000
The following details a data quality assessment and validation for results generated by Analytical Services,
Inc. (AS!) of Norcross, Georgia for two liquid samples collected from the above-referenced Site. Sample
collection was conducted on December 2, 1999. The samples. were selectively analyzed for volatile organic
compounds (VOC), base-neutral and acid extractable organic compounds (BNA), polychlorinated biphenyls
(PCB), cyanide, oil and grease (O&G), target analyte list (TAL) metals, total suspended solids (TSS),
biological oxygen demand (BOD), and ammonia. The quality assurance criteria were established by the
associated quality assurance project plan and the National Function Guidelines1. The samples are identified
in Table l. The analytical methodologies are listed in Table 2.
Holding Time Periods
The holding time periods are presented in Table 3. On the basis of the sample collection and analysis dates
referenced on the chain-of-custody forms and the analytical reports provided by ASI, all extractions and
analyses were performed within the required holding time periods. Thus, no qualifications were required.
Method Blank Samples
Contamination of samples contributed by laboratory conditions or procedures was monitored by the
concurrent preparation and analysis of method blank samples. The method blank samples were free from
target analytes, above the detection limits, indicating that no significant laboratory contamination occurred.
Surrogate Compound Percent Recoveries (Surrogate Recoveries)
Individual sample performance for the VOC, BNA, and PCB parameters were monitored by surrogate
recoveries. The surrogate recoveries were within the control limits for the reported analyses.
Application of quality assurance criteria was consistent with "National Functional Guidelines for Organic Data
Review," revised February 1994 and "National Functional Guidelines for Inorganic Data Review," revised February
1994.
l.
CRA MEMORANDUM • Page2
Matrix Spike/Matrix Spike Duplicate (MS/MSD) Percent Recoveries -Organic Analyses
To assess the long term accuracy and precision of the analytical method on various matrices, MS/MSD
percent recoveries and the relative percent difference (RPO) of the recoveries are determined. The PCB
MS/MSD and some BNA MS/MSD percent recoveries were slightly outside control limits; however, no
sample qualifjcations were required as LCS and surrogate recoveries fell within limits and as qualifications
are not granted on MS/MSD data alone. Also, the MS/MSD samples chosen for analysis were non-project
specific. The remainder of the MS/MSD percent recoveries and RPO data were within control limits,
indicating an adequate level of accuracy and precision was achieved. No qualifications were granted.
Matrix Spike (MS) Percent Recoveries -Inorganic Analyses
The percent recovery data from matrix spike samples were monitored to determine the effects of sample
matrix on the accuracy of the inorganics and metals sample preparation and measurement methods.
The MS sample recoveries for metals and inorganics analyses met laboratory-established control limits with
a couple exceptions. However, as the MS/MSD samples analyzed were not project specific, no data
qualifications were required.
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD) Results
ASI provides and analyzes LCS/LCSD samples in order to further assess the method accuracy and
precision. The LCS recoveries for tetrachloroethene in the VOC analysis and 3,3'-dichlorobenzidine in the
BNA analysis fell below control limits. Qualification of the data were deemed necessary and the results
were qualified. Refer to Table 4 for necessary qualifications.
-c
Laboratory Duplicate Analyses
(
To monitor the precision of the laboratory analytical methods, laboratory duplicate samples were analyzed
for select methods. The laboratory duplicate RPO data were within control limits indicating an adequate
level of precision was achieved for these select methods.
Trip Blank Analysis
Potential VOC cross-contamination by diffusion of target compounds through the septum seal of the
sample vial into the investigative samples during shipment and storage was monitored by means of a trip
blank sample. The trip blank sample was free from detectable concentrations of target analytes indicating
that no significant cross-contamination occurred.
Overall Assessment
The data provided by ASI were found to exhibit acceptable levels of accuracy and precision and may be
used with the qualifications presented in Table 4. It should be noted that 2-chloroethyl vinyl ether is
susceptible to degradation in ·acidic conditions which may have affected sample results.
CRA 3669Memo388-Tl
•
TABLEl.
SUMMARY OF SAMPLE IDENTIFICATION NUMBERS
JADCO-HUGHES SITE
BELMONT, NORTH CAROLINA
W-3669-MC-120299-141
W-3669-MC-120299-142
Parameters
voe
BNA
PCB
Cyanide
TALMetals
TSS
BOD
Ammonia
Oil and Grease
Notes:
•
TABLE2
SUMMARY OF ANALYTICAL METHODS
JADCO-HUGHES SITE
BELMONT, NORTH CAROLINA
Methods
MCAWW 1
MCAWW
MCAWW
MCAWW
MCAWW
MCAWW
SM2
MCAWW
MCAWW
624
625
608
335.2
200 (series)
160.2
5210 B
350.2
1664
1 "Methods for Chemical Analysis of Water and Wastes," EPA 600/ 4-79-020, nivised
March 1983, and subsequent updates.
2 "Standard Methods for the Examination of Water and Wastewater," APHA, 16th edition,
1985 and subsequent updates.
CRA 3669Mcmo388-T2
Parameters
VOC, Cyanide
BNA,PCB
TALMetals
(excluding mercury)
•
TABLE3
SUMMARY OF HOLDING TIME PERIODS
JADCO-HUGHES SITE
BELMONT, NORTH CAROLINA
Holding Time Periods
14 days from sample collection to completion of analysis
7 days from sample collection to extraction
40 days from extraction to completion of analysis
6 months from sample collection to completion of analysis
Mercury, Oil and Grease,
Ammonia
28 days from sample collection to completion of analysis
BOD 48 hours from sample collection to beginning of analysis
TSS 7 days from sample collection to completion of analysis
CRA 3669Memo388. TJ
Sample
W-3669-MC-120299-142
J Estimate value.
ND Not detected.
•
TABLE4
SUMMARY OF QUALIFICATIONS
JADCO-HUGHES SITE
BELMONT, NORTH CAROLINA
QA/QC Analysis
LCS
Parameter
tetrachloroethene
3,3'-dichlorobenzidine LCS
•
Result
(µgll)
ND(2)
ND (20)
Qualified
Result
2 UJ
20 UJ
UJ The parameter was not detected above the sample reporting limit. The sample reporting limit
is estimated.
CRA 3669Memo388-T4