NCD980729602_19980831_Jadco-Hughes_FRBCERCLA RA_Treated Water Effluent and Associated Data QA Validation - File 2 January - August 1998-OCR

········•·'······ . .-. '' ... · ... •"
A/sD
I
ASI A N A L V T I C A L S E R V I C E S l, I N C .
I
ENVIRONMENTAL MONITORING & LABORATORY ANALYSIS
110 TECHNOLOGY PARKWAY• NORCROSS. GA 30092
[phone] • FAX [phone]
31 August 98
Case Narrative ASI Sample 98590
d . I These samples were collected on 19 August 98 an arrived at AS! on 20 August
I 98. The sample temperatures were noted at 2 degrees Celsius upon arrival at ASL The
I samples were logged into LIMS as AS! sample 98590 for analysis oflead and cyanide.
Lead in water was analyzed in batch 41106 using EPA method 239.2. 1 High
MS/MSD recoveries were noted in lead. Otherwise measurement quality objectives were
met. . I
Cyanide in water was analyzed in batch 41326 using EPA method 335.2! All
measurement quality objectives were met and the analysis was unexceptional.
Respectfully yours,
9=71~
Jon Neuhaus
Quality Assurance
CHEC!([D . .t.,G,\!i-.i!:;T
PRELltv.:N,\fW DATA
Date
lnithils. .. p.16___ I .
A Unit of American Analytical Services, Inc.
• • I
ASI A N A L Y T I C A L S E R V I C E S! , I N C .
Conestoga-Rovers
1351 Oakbrook Drive
Suite 150
Norcross, GA 30093
' ENVIRONMENTAL MONITORING & LABORATORY ANALYSIS
110 TECHNOLOGY PARKWAY • NORCROSS, GA 30092
[phone] • FAX [phone]
LABORATORY REPORT
I
September 12, 1998
I '
Attention: Mr. Rob Brachowski Report No.I 98590-1
I ' Sample Description
Water, composite, Jadco Hughes, Project #3609, W-3669-MC-081998-001,
08/19/98, 13:30, received 08/20/98
RESULTS
Metals
Total Lead (Pb) (EPA 239.2) .................. .
North Carolina Laboratory I.D. No. 381
Result
(mg/1)
0.007
,Detection
I Limit
' (mg/1)
0.005
Respectfully submitted,
~-!la~
Projed: ~'ager
·ranee
I
A Unit of American Analytical Services, Inc.
• • I
I
ASI ANALYTICAL SERVICES:, INC.
Conestoga-Rovers
1351 Oakbrook Drive
Suite 150
Norcross, GA 30093
I ENVIRONMENTAL MONITORING & LABORATORY ANALYSIS
110 TECHNOLOGY PARKWAY • NORCROSS, GA 30092
(770) 734·4200 • FAX [phone]
LABORATORY REPORT
September ;2, 1998
Attention: Mr. Rob Brachowski Report No. 98590-2
I
Sample Description I
I
Water, grab, Jadco Hughes, Project #3609, W-3669-MC-081998-001:, 08/19/98,
13:40, received 08/20/98
RESULTS
Total Cyanide (CN) (mg/1) (EPA 335.2) ...... , .. .
~Torth C',i.r0lin<1 Lc1bor,itory T.D N0. 381
Result
0.01
Detection
Limit
0.01
Respectfully submitted,
bfuL/ 1/tUb
Project Man'ager
I
'
A Unit of American Analytical Services, Inc.
• •
Analytical Services Inc. Batch QC
For Report Number :98590
QC Batch General Information
Analysis
Method
Batch
Number
41106
.......... Note
41326
Analyte
Pb EPA 239.2
QC PASSES ON LCS,LCSD,PDS
CN EPA 335.2
Lab Control Information
Batch
Number
41106
41326
Analyte
Pb
CN
Method
EPA 239.2
EPA 335.2
Matrix Spike Information
Batch
Number Analyte Method
41106 Ph EPA ? '9 ?
41326 CN EPA 335.2
Post Digestion Spike Information
Batch
Number Analyte Method
41106 Pb EPA 239.2
Unspiked Sample Duplicate Information
Batch
Number Analyte Method
41326 CN EPA 335.2
Matrix
Aqueous <
Aqueous <
LC LCD LC
%Rec %Rec RPD
105 106 1
104 107 3
MS MSD MS
%Rec %Rec RPO
150 150 ()
105 102 3
PDS
%Rec
115
Sample 1 Sample
RPO RPO
0 0
Page 1
Blank Prep.
Result Method
0.0050
0.010:0
I i
I
%Recovery RPD
Range1 Range
76 -124 0 -20
75 -125 0 -30
%Recovery RPD
Range: Range
76 -l.?4 n -20
75 -125 0 -30
%Recovery
Rangel
I
76 -124
2 RPO
Range
0 -30
Sample ID
41106BLANK
41106LCS
41106LCSD
9_8507-lMS
98507-lMSD
98507-2PDS
98507-2DUP
98431-2
98431-3
98431-4
98431-5
98431-6
98507-1
98507-2
98507-3
98507-4
98590-1
98462-6
98507-lD
98507-2D
98507-3D
98507-4D
41106BLANK
41106LCS
41106LCSD
98507-lMS
98507-lMSD
98507-2PDS
98507-2DUP
98431-2
98431-3
98431-4
98431-5
98431-6
98507-1
98507-2
98507-3
98507-4
98590-1
98462-6
98507-lD
9B507-2D
9B507-3D
9B507-4D
41106BLANK
41106LCS
41106LCSD
98507-lMS
• •
I
Q.C. Information for Batch# 41106
Page 2
For Report Numbe~ :98590
Sample Batch Information
Analysis : Pb
Preparation
Tag Date Time By
Cu 08/24/9B 1120 LLP
Cu OB/24/98 1120 LLP
Cu 08/24/98 1120 LLP
Cu 0B/24/9B 1120 LLP
Cu 08/24/9B 1120 LLP
Cu 08/24/9B 1120 LLP
Cu 08/24/98 1120 LLP
Cu 08/24/9B 1120 LLP
Cu 0B/24/9B 1120 LLP
Cu 0B/24/9B 1120 LLP
Cu 0B/24/9B 1120 LLP
Cu 0B/24/9B 1120 LLP
Cu 08/24/9B 1120 LLP
Cu 0B/24/9B 1120 LLP
Cu 08/24/98 1120 LLP
Cu 0B/24/9B 1120 LLP
Cu OB/24/98 1120 LLP
Cu 08/24/98 1120 LLP
Cu 08/24/98 1120 LLP
Cu 08/24/98 1120 LLP
Cu 08/24/98 1120 LLP
C11 08/24/98 112() LLP
Pb 08/24/98 1120 LLP
Pb 0B/24/9B 1120 LLP
Pb 08/24/98 1120 LLP
Pb 08/24/98 1120 LLP
Pb 08/24/98 1120 LLP
Pb 08/24/98 1120 LLP
Pb 08/24/98 1120 LLP
Pb 08/24/98 1120 LLP
Pb 08/24/98 1120 LLP
Pb 08/24/98 1120 LLP
Pb 08/24/98 1120 LLP
Pb 08/24/98 1120 LLP
Pb 08/24/98 1120 LLP
Pb 08/24/98 1120 LLP
Pb 08/24/98 1120 LLP
Pb 08/24/98 1120 LLP
Pb 08/24/98 1120 LLP
Pb 08/24/981120 LLP
Pb 08/24/98 1120 LLP
Pb 08/24/98 1120 LLP
Pb 08/24/98 1120 LLP
Pb 08/24/98 1120 LLP
Tl 08/24/98 1120 LLP
Tl 08/24/98 1120 LLP
Tl 08/24/98 1120 LLP
Tl 08/24/98 1120 LLP
Preparation
Notes
GFAA
GFAA
GFAA
GFAA
GFAA
GFAA
GFAA
GFAA
GFAA
GFAA
GFAA
GFAA
GFAA
GFAA
GFAA
GFAA
GFAA
GFAA
GFAA
GFAA
GFAA
SFAA
GFAA
GFAA
GFAA
GFAA
GFAA
GFAA
GFAA
GFAA
GFAA
GFAA
GFAA
GFAA
GFAA
GFAA
GFAA
GFAA
GFAA
GFAA
GFAA
GFAA
GFAA
GFAA
GFAA
GFAA
GFAA
GFAA
'
Analys·is
Date Time By I
08/24/9B
08/24/98
08/24/98
08/24/98
08/24/98
08/24/98
08/24/98
08/24/98
08/24/98
08/24/98
08/24/9B
08/24/98
08/24/9B
08/24/98
08/24/98
08/24/98
08/24/98
08/24/9B
08/24/98
OB/24/98
08/24/98
08/24/98
08/24/98
08/24/98
08/24/98
08/24/98
08/24/98
08/24/98
08/24/98
08/24/98
08/24/98
08/24/98
08/24/98
08/24/98
08/24/98
08/24/98
08/24/98
08/24/98
08/24/98
08/24/98
08/24/98
08/24/98
08/24/98
08/24/98
08/24/98
08/24/98
08/24/98
08/24/98
1005 MLR
10:10 MLR ' 1310 MLR
13•10 MLR
13:10 MLR
13°10 MLR
13'1.0 MLR
13'1.0 MLR
13'1.0 MLR
13'1.0 MLR
1310 MLR
13'1.0 MLR
1310 MLR
13'1.0 MLR
1310 MLR
1310 MLR
13l0 MLR
13iO MLR
1310 MLR
1310 MLR
1310 MLR
11to MLR
1529 MLR
1529 MLR
1529 MLR
15~9 MLR
1529 MLR
1529 MLR
1529 MLR
1529 MLR
15~9 MLR
1529 MLR
1529 MLR
1529 MLR
1529 MLR
1529 MLR
15~9 MLR
1529 MLR ' 1529 MLR ' 152,9 MLR
1529 MLR
152'9 MLR
' 1529 MLR
1529 MLR
155!9 MLR
1559 MLR
15519 MLR
155'.9 MLR
Inst
AAl
AAl
AAl
AAl
AAl
AAl
AAl
AAl
AAl
AAl
AAl
AAl
AAl
AAl
AAl
AAl
AAl
AAl
AAl
AAl
AAl
IVU
AAl
AAl
AAl
AAl
AAl
AAl
AAl
AAl
AAl
AAl
AAl
AAl
AAl
AAl
AAl
AAl
AAl
AAl
AAl
AAl
AAl
AAl
AA2
AA2
AA2
AA2
• •
.Page 3
Q.C. Information for Batch# 41106 For Report Number :98590
Sample Batch Information
Analysis : Pb
Preparation Preparation Analysis
Sample ID Tag Date Time By Notes Date TiJme By Inst
98507-lMSD Tl 08/24/98 1120 LLP GFAA 08/24/98 1559 MLR AA2
98507-2PDS Tl 08/24/98 1120 LLP GFAA 08/24/98 1559 MLR AA2
08/24/98 08/24/98 ' 98507-2DUP Tl 1120 LLP GFAA 15'59 MLR AA2
98431-2 Tl 08/24/98 1120 LLP GFAA 08/24/98 15159 MLR AA2
08/24/98 08/24/98 ' 98431-3 Tl 1120 LLP GFAA 1559 MLR AA2
Tl 08/24/98 08/24/98 ' 98431-4 1120 LLP GFAA 15,59 MLR AA2
98431-5 Tl 08/24/98 1120 LLP GFAA 08/24/98 1559 MLR AA2
98431-6 Tl 08/24/98 1120 LLP GFAA 08/24/98 1559 MLR AA2
98507-1 Tl 08/24/98 1120 LLP GFAA 08/24/98 1559 MLR AA2
98507-2 Tl 08/24/98 1120 LLP GFAA 08/24/98 1559 MLR AA2
98507-3 Tl 08/24/98 1120 LLP GFAA 08/24/98 1559 MLR AA2
98507-4 Tl 08/24/98 1120 LLP GFAA 08/24/98 1559,MLR AA2
98590-1 Tl 08/24/98 1120 LLP GFAA 08/24/98 1559 MLR AA2
98462-6 Tl 08/24/98 1120 LLP GFAA 08/24/98 15?9 MLR AA2
98507-lD Tl 08/24/98 1120 LLP GFAA 08/24/98 1559 MLR AA2
98507-2D Tl 08/24/98 1120 LLP GFAA 08/24/98 1559 MLR AA2
98507-3D Tl 08/24/98 1120 LLP GFAA 08/24/98 1559 MLR AA2
98507-4D Tl 08/24/98 1120 LLP GFAA 08/24/98 1559 MLR AA2 i
.. • •
I .Page 4
Q.C. Information for Batch# 41326 For Report Number :98590
Sample Batch Information
Analysis : CN
Preparation Preparation Analysis
Sample ID Tag Date Time.By Notes Date Time By Inst
I
41326BLK 08/25/98 0810 PRR MIDI-DIST 08/25/98 1215 PRR GENS
08/25/98 0810 PRR 08/25/98 ' 41326LCS MIDI-DIST 12•15 PRR GENS
41326LCSD 08/25/98 0810 PRR MIDI-DIST 08/25/98 ' 1215 PRR GENS
98588-4MS 08/25/98 0810 PRR MIDI-DIST 08/25/98 ' 1215 PRR GENS
98588-4MSD 08/25/98 0810 PRR MIDI-DIST 08/25/98 12h.s PRR GENS
08/25/98 0810 PRR MIDI-DIST 08/25/98 ' 98588-4 1215 PRR GENS
98588-5 08/25/98 0810 PRR MIDI-DIST 08/25/98 ' 1215 PRR GENS
98590-2 08/25/98 0810 PRR MIDI-DIST 08/25/98 1215 PRR GENS
98576-19 08/25/98 1130 PRR MIDI-DIST 08/25/98 1600 PRR GENS
41326CAL5 08/25/98 1130 PRR MIDI-DIST 08/25/98 1600 PRR GENS
41326CAL15 08/25/98 1130 PRR MIDI-DIST 08/25/98 1600 PRR GENS
98576-20 08/25/98 1130 PRR MIDI-DIST 08/25/98 1600 PRR GENS
98627 08/25/98 1130 PRR MIDI-DIST 08/25/98 1600 PRR GENS
98627DUP 08/25/98 1130 PRR MIDI-DIST 08/25/98 1600 PRR GENS
98595-1 08/25/98 1130 PRR MIDI-DIST 08/25/98 1600 PRR GENS
98468 08/25/98 1130 PRR MIDI-DIST 08/25/98 1600 PRR GENS
98588-15 08/25/98 1345 PRR MIDI-DIST 08/26/98 0845 PRR GENS
98588-6 08/25/98 1345 PRR MIDI-DIST 08/26/98 0815 PRR GENS
98450 08/25/98 1345 PRR MIDI-DIST 08/26/98 0845 PRR GENS
98647-2 08/25/98 1345 PRR MIDI-DIST 08/26/98 0845 PRR GENS
98442 08/25/98 1345 PRR MIDI-DIST 08/26/98 0845 PRR GENS
384 56 08/25/<JR 1.145 PR.R MIDI-DIST 08/26/98 0845 PRR GENS
98456DUP 08/25/98 1345 PRR MIDI-DIST 08/26/98 0845 PRR GENS
98441-1 08/25/98 1345 PRR MIDI-DIST 08/26/98 0845
' PRR GENS
I
~ '78' <::C,C, y Z.3
CRA SHIPPED TO (Laboratory Name): ,A-v,~.,.\-c ~l'l'<-' ~vuc"-CS ~ .
CONESTOGA-ROVERS & ASSOCIATES, INC. \ \ 0 T -Et '1, V\. t ·. (_ry1> 'J p, "~1-.1.L..L',, /\l c, < v0 <:.. s (',_ rt '3 CD't 2.. 1351 Oakbrook Drive Suite 150 REFERENCE NUMBER: -PROJECT NAME: Norcross, GA 30093 404-441-0027 -
CHAIN OF CUSTODY RECORD 966c7 'Jc..<lcc ttUoV-0_:,
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TIME: Jbo..::.· ® TIME: I,...'"' J
RELINjlfUISHED BY: ,,, DATE: RECEIVED BY: DATE:
® -@ TIME: .TIME: -
RELINQUISHED BY:---------DATE: RECEIVED BY: DATE:
@ TIME: © TIME:
METHOD OF SHIPMENT: ~'{)'c,._)( AIR BILL NUMBER: 86loJ319 \05'1
White . Fully Executed Ccpy SAMPLE TEAM: RECll~ED F~~ LABORATORY BY: ·-
Yellow . Receiving Laboratory Copy ~, c \"C.,_,,\ 'I'\· C v'LP N2 0517 1
Pink Sampler Ccpy /
Goldenrod . Chemist Copy Ir ..2, AAa01~Yo..d. L~ -:::. ;;i.e..., ' DATE ¥' (';XJ L '/ ;I TIME: /2..45 -z. C.CfUT,
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,. • A/SD
ASI A N A L Y T I C A L S E R V I C E s\ , I N C .
27 August 98
I
ENVIRONMENTAL MONITORING & LABORATORY ANAL'r:SIS
110 TECHNOLOGY PARKWAY• NORCROSS, GA 30092
[phone] • FAX [phone]
C, /C'(" ~r-r : . .._, _ _.J\r.:._J AG;\!NST
PFiEU~ilNARY DATA
Case Narrative AS! Sample #98135 Data ---,",,._l-'-r:..,• (<...2'1.!.,. __ 1993
lnltlals Ph3
These samples were collected on 6 August 98 and amved at AS! on 7 August 98.
All conditions for proper preservation and shipment were met. The samples were 'logged
into LIMS as sample 98135 for analysis of BNA, VOC, PCB's, metals, pH, aminonia-
' nitrogen, BOD, 0/G, TSS, and cyanide. \
Acids-in water were analyzed in batch 40911 using EPA method 625. Phenol and ' 2,4-Dimethylphenol exhibited high MS/MSD recoveries. A recovery for MS/MS_D 2,4-
Dinitrophenol was not calculated. A high MS RPO was noted for 2-Nitrophenol. ' Otherwise measurement quality objectives were met. 1
Base neutrals in water were analyzed in batch 40912 using EPA method 625.
Low recoveries for MS/MSD were noted in Bis(2-chloroisopropyl)ether and 1,4-
Dichlorobenzene. An MS was not calculated for Anthracene. A low MS recovery of I,
2, 4 -Trichlorobenzene was noted. 2, 6 -Dinitrotolulene exhibited a high MS recovery
and a MSD was not calculated. Otherwise measurement quality objectives were me't.
VOC in water was analyzed in batch 40691 using EPA method 624.1 All
measurement quality objectives were met and the analyses were unexceptional. 1
' PCB's in water were analyzed in batch 40966 using EPA method 608. MS/MSD
was not calculated. Otherwise measurement quality objectives were met. !
Mercury was analyzed in batch 40468 using EPA method 245.1. I All
measurement quality objectives were met and the analysis was unexceptional. I
Selenium was analyzed in batch 40711 using EPA method 270.2. Low recoveries
I for MS/MSD and PDS were noted for selenium. Otherwise measurement quality
objectives were met. i
Lead was analyzed in batch 40711 using EPA method 239. 2. All measurement
quality objectives were met and the analysis was unexceptional. i
Zinc, .silver, arsenic, barium, beryllium, cadmium, copper, chromium, magne~ium,
nickel, antimony, aluminum, cobalt, iron, manganese, sodium, vanadium, and calciJm in
water were analyzed in batch 40727 using EPA method 200.7. A high recovery forlPDS
was noted for sodium. Otherwise measurement quality objectives were met. 1
pH was analyzed in batch 40887 using EPA method 150.1. All measure~ent
quality objectives were met and the analysis was unexceptional. I
Ammonia-nitrogen was analyzed in batch 40934 using EPA method 350.2., All
measurement.quality objectives were met and the analysis was unexceptional. i
BOD was analyzed in batch 40945 using SM 52108. All measurement qu,ality
objectives were met and the analysis was unexceptional.
0/G was analyzed in batch 40950 using EPA method 1664. A high MS reco\>ery
was noted. There was no MSD or sample duplicate due to lack of sample. Otherwise'
i
A I I nit nf Ami=irir.:=in An:::ih,tir.::tl ~Prvir.P~. lnr..
• •
ASI A N A L Y T I C A L S E R V I C E S'. , I N C .
ENVIRONMENTAL MONITORING & LABORATORY ANAL':SIS
110 TECHNOLOGY PARKWAY• NORCROSS, GA 30092
[phone] • FAX [phone]
measurement quality objectives were met.
I TSS was analyzed in batch 40958 using EPA method 160.2. All measurement
quality objectives were met and the analysis was unexceptional. 1
Cyanide was analyzed in batch 41016 using EPA method 335.2.1 All
measurement quality objectives were met and the analysis was unexceptional. '
Respectfully yours,
1~ rfL
Jon Neuhaus
Quality Assurance
A t !nit nf AmPrir.~n An~lutir.~I ~Prvir:P~. lnr:.
,, • • I
I
ASI AN ALY TIC AL SERVICES\, I NC.
I
ENVIRONMENTAL MONITORING & LABORATORY ANALYSIS
110 TECHNOLOGY PARKWAY• NORCROSS, GA30092 !
[phone] • FAX [phone]
Conestoga-Rovers
1351 Oakbrook Drive
Suite 150
Norcross, GA 30093
LABORATORY REPORT
Attention: Mr. Rob Brachowski
Sample Description
I
September 1, 1998
I
Report No. I 198135-1 I
I
Wastewater, composite, Jadco-Hughes, Project #3669, W-3669-MC-080698-102,
08/06/98, 13:30, received 08/07/98 !
RESULTS
Biochemical Oxygen Demand (BOD5 ) (mg/1)
(SM 5210 B) ............................ .
Ammonia Nitrogen (NJ (mg/1; (El'A .:ISU.:.C:J ....... .
Total Suspended Solids (mg/1) (EPA 160. 2) .... .
Target Analyte List -Metals
Metals
Total Aluminum (Al) (EPA 200. 7) .............. .
Total Antimony (Sb) (EPA 200. 7) .............. .
Total Arsenic (As) (EPA 200. 7) ............... .
Total Barium (Ba) (EPA 200. 7) ................ .
Total Beryllium (Be) (EPA 200. 7) ............. .
Total Cadmium (Cd) (EPA 200. 7) ............... .
Total Calcium (Ca) (EPA 200. 7) ............... .
Total Chromium (Cr) (EPA 200. 7) .............. .
Total Cobalt {Co) {EPA 200. 7) ................ .
Total Copper (Cu) (EPA 200. 7) ................ .
Total Iron (Fe) (EPA 200. 7) .................. .
Total Lead (Pb) (EPA 239.2) .................. .
BDL -Below Detection Limit
Result
BDL
l:l!JL
BDL
(mg/1)
BDL
BDL
BDL
0.05
BDL
BDL
35
BDL
BDL
BDL
BDL
0.05
A Unit of American Analvtical Services, Inc.
Detection
I • • , L1.m1.t
I
5
U.l
5 '
I (mg11)
I 0.2
0.05
0.01
0.01
0.001
0.005
0.05
0.01
0.05
0.02
0.1
0.003
,. • •
Conestoga-Rovers
Page 2 of 2
Wastewater, composite, Jadco-Hughes, Project #3669,
08/06/98, 13:30, received 08/07/98
RESULTS
Metals
Total Magnesium (Mg) (EPA 200. 7) ............. .
Total Manganese (Mn) (EPA 200. 7) ............. .
Total Mercury (Hg) (EPA 245 .1) ............... .
Total Nickel (Ni) (EPA 200. 7) ................ .
Total Potassium (K) (EPA 200. 7) .............. .
Total Selenium (Se) (EPA 270. 2) .............. .
Total Silver (Ag) (EPA 200. 7) ............... ..
Total Sodium (Na) (EPA 200. 7) ................ .
Total Thallium (Tl) (EPA 279.2) .............. .
Total Vanadium (V) (EPA 200. 7) ............... .
Total Zinc (Zn) (EPA 200. 7) .................. .
BDL -Below Detection Limit
North Carolina Laboratory I.D. No. 381
September 11, 1998
Report No ·i 98135-1
'
W-3669-MC-~80698-102,
Result
(mg/1)
10
0.017
BDL
BDL
2.0
BDL
BDL
12
BDL
BDL
0.10
i
I Detection
i
I
I
!
I
Limit
(mg/1)
0.05
0.015
0.0002
0.02
0.2
0.005
0.01
0.05
0.002
0.02
0.02
submitted, I
,. • •
ASI A N A L Y T I C A L S E R V I C E S1 , I N C .
ENVIRONMENTAL MONITORING & LABORATORY ANAL'r;SIS
110 TECHNOLOGY PAR'r{)NAY • NORCROSS, GA 30092
[phone] • FAX [phone]
Conestoga-Rovers
1351 Oakbrook Drive
Suite 150
Norcross, GA 30093
LABORATORY REPORT
Attention: Mr. Rob Brachowski
Sample Description
September 1, 1998
I
I
Report No. 1 98135-2
I
' Wastewater, grab, Jadco-Hughes, Project #3669, W-3669-MC-080698-103,
08/06/98, 13:40, received 08/07/98
RESULTS
Detection
Result I Limit
pH (laboratory) (EPA 150 .1) .................. . 7.66
Total Cyanide (CN) (mg/1) (EPA 335.2) ......... . 0.02 0.01
Oil and Grease (mc,J/li (EPA 1664) ............. . BDL 6
Volatile Organics (EPA 624) (ug/1) (ug/1)
Acetone ..................................... . BDL 100
Benzene ..................................... . BDL 2
Bromodichloromethane ........................ . BDL 10
Bromoform ................................... . BDL 10
Bromomethane ................................ . BDL I 10
2-Butanone .................................. . BDL 1100
Carbon disulfide ............................ . BDL 5
Carbon tetrachloride ........................ . BDL 2
Chlorobenzene ............................... . BDL 10
Chloroethane ................................ . BDL 5
Chloroform .................................. . 79 2
Chloromethane ............................... . BDL 10
Dibromochloromethane ........................ . BDL 10
1, 1-Dichloroethane .......................... . BDL 2
1, 2-Dichloroethane .......................... . 8 2
1, 1-Dichloroethene .......................... . BDL 2
l, 2 -Dichloroethene (total) .................. . 58 2
BDL -Below Detection Limit
A Unit nf Amflrican Analvtical Services. Inc.
,.
Conestoga-Rovers
Page 2 of 4
•
Wastewater, grab, Jadco-Hughes, Project #3669,
08/06/98, 13:40, received 08/07/98
RESULTS
Volatile Organics (EPA 624)
1, 2-Dichloropropane ......................... .
cis-1, 3-Dichloropropene ..................... .
trans-1,3-Dichloropropene ................... .
Ethylbenzene ................................ .
2 -Hexanone .................................. .
Methylene chloride .......................... .
1,1,2,2-Tetrachloroethane ................... .
Tetrachloroethene ........................... .
Toluene ..................................... .
1,1,1-Trichloroethane ....................... .
1,1,2-Trichloroethane ....................... .
Trichloroethene ............................. .
Vinyl chloride .............................. .
Xylenes ..................................... .
Acid Extractable Organics (EPA 625)
Benzuic: Ac:.icl ................................ .
4-Chloro-3-methylphenol ..................... .
2 -Chlorophenol .............................. .
2, 4 -Dichlorophenol .......................... .
2, 4 -Dimethylphenol .......................... .
2, 4-Dinitrophenol. .......................... .
4,6-binitro-2-methylphenol .................. .
2 -Methylphenol .............................. .
4 -Methylphenol .............................. .
2-Nitrophenol ............................... .
4-Nitrophenol. .............................. .
Pentachlorophenol ........................... .
Phenol ...................................... .
2, 4, 6 -Trichlorophenol ....................... .
2, 4, 5-Trichlorophenol ....................... .
BDL -Below Detection Limit
•
September 11, 1998
Report No.1 98135-2
I
W-3669-MC-080698-103, I
' I
Detection
Result ' Limit
(ug/1) (ug/1)
BDL 2
BDL 2
BDL 2
BDL 2
BDL 50
BDL 10
BDL 2
BDL 2
BDL 2
BDL 2
BDL 2
10 2
BDL 10
BDL 2
(ug/1) (ug/1)
BDL 50
BDL 10
BDL 10
BDL 10
BDL 10
BDL 50
BDL 50
BDL 10
BDL 10
BDL 50
BDL 50
BDL 20
BDL 10
BDL 10
BDL 10
],
Conestoga-Rovers
Page 3 of 4
• •
September ,1, 1998
Report No.I 98135-2
I
Wastewater, grab, Jadco-Hughes, Project #3669, W-3669-MC-080698-103,
08/06/98, 13:40, received 08/07/98
RESULTS
,
Detection
Result I Limit '
Base/Neutral Extractable Organics (EPA 625) (ug/1) I (ug/1)
Acenaphthene ................................ . BDL 10
Acenaphthylene .............................. . BDL 10
Anthracene .................................. . BDL 10
Benzo(a)anthracene .......................... . BDL 10
Benzo(b)fluoranthene ........................ . BDL 10
Benzo(k)fluoranthene ........................ . BDL 10
Benzo(a)pyrene .............................. . BDL 10
Benzo(ghi)perylene .......................... . BDL 10
Benzyl butyl phthalate ...................... . BDL 10
Bis(2-chloroethyl)ether ..................... . BDL 10
Bis(2-chloroethoxy)methane .................. . BDL 10
Bis(2-ethylhexyl)phthalate .................. . BDL 10
Bis(2-chloroisopropyl)ether ................. . BDL 10
4-Bromophenyl phenyl ether .................. . BDL 10
4-Chloroaniline ............................. . BDL 20
2-Chloronaphthalene ......................... . BDL 10
4-Chlorophenyl phenyl ether .................. . BDL 10
Cl1r:r·ser1e .................................... . BIJL llJ
Dibenzo(a,h)anthracene ...................... . BDL 10
Dibenzofuran ................................ . BDL 10
Di-n-butylphthalate ......................... . BDL 10
1, 3-Dichlorobenzene ......................... . BDL 10
1, 2-Dichlorobenzene ......................... . BDL I 10
1,4-Dichlorobenzene ......................... . BDL 10
3, 3' -Dichlorobenz idine ...................... . BDL 20
Diethylphthalate ............................ . BDL 10
Dimethylphthalate ........................... . BDL 10
2, 4-Dinitrotoluene .......................... . BDL 20
2, 6-Dinitrotoluene .......................... . BDL 20
Di-n-octylphthalate ......................... . BDL 10
Fluoranthene ................................ . BDL 10
Fluorene .................................... . BDL 10
Hexachlorobenzene ........................... . BDL 10
Hexachlorobutadiene ......................... . BDL 10
Hexachlorocyclopentadiene ................... . BDL I 10
Hexachloroethane ............................ . BDL 2
Indeno (1, 2, 3 -cd) pyrene ...................... . BDL 10
Isophorone .................................. . BDL 10
BDL -Below Detection Limit
,.
Conestoga-Rovers
Page 4 of 4
•
I
September 11, 1998
Report No.1 98135-2
Wastewater, grab, Jadco-Hughes, Project #3669, W-3669-MC-080698-103,
08/06/98, 13:40, received 08/07/98 I
RESULTS
Detection
Result I Limit
Base/Neutral Extractable Organics (EPA 625) (ug/1) I (ug/1) I !
2-Methylnaphthalene ......................... . BDL I 10
Naphthalene ................................. .
2-Nitroaniline .............................. .
BDL I 10
BDL 50
3-Nitroaniline .............................. . BDL 50
4-Nitroaniline .............................. . BDL 50
Nitrobenzene ................................ . BDL 10
N-Nitrosodiphenylamine ...................... . BDL 10
N-Nitrosodi-n-propylamine ................... . BDL 10
Phenanthrene ................................ . BDL 10
Pyrene ...................................... .
1, 2, 4 -Trichlorobenzene ...................... .
BDL 10
BDL 10
PCB's (EPA 608) (ug/1) I (ug/1)
PCB 1016 .................................... . BDL 1.0
PCB 1221 .................................... . BDL 1.0
PCB 1232 .................................... . BDL 1.0
PCB 1242 .................................... . BDL l >'J
PCB 1248 .................................... . BDL 1.0
PCB 1254 .................................... . BDL 1.0
PCB 1260 .................................... . BDL 1.0
BDL -Below Detection Limit
North Carolina Laboratory I.D. No. 381
I
Respectfully submitted, ~u·x4f~
Project M~er -~ Quali t Assura:nce
• • ' I
ASI ANALYTICAL SERVICES:, INC.
I
ENVIRONMENTAL MONITORING & LABORATORY ANALY,SIS
110 TECHNOLOGY PARKWAY• NORCROSS, GA 30092
[phone] • FAX [phone]
LABORATORY REPORT
I
' '
Conestoga-Rovers
1351 Oakbrook Drive
Suite 150
September 1, 1998
I
Norcross, GA 30093
Attention: Mr. Rob Brachowski
Sample Description
Report No. 198135-3 I
I
Wastewater, Jadco-Hughes,
I
Project #3669, Trip Blank, received q8/07,98
RESULTS
I
I D,etection
Result Limit
Volatile Organics (EPA 624) (ug/1) (ug/1)
Benzene ..................................... . BDL 2
Bromodichloromethane ........................ . BDL 10
Bromofurm ................................... . BDL lU
Bromomethane ................................ . BDL I 10
Carbon tetrachloride ........................ . BDL 2
Chlorobenzene ............................... . BDL 10
Chloroethane ................................ . BDL 5
2-Chloroethylvinyl ether .................... . BDL 10
Chloroform .................................. . BDL 2
Chloromethane ............................... . BDL 10
Dibromochloromethane ........................ . BDL 10
l,2-Dichlorobenzene ......................... . BDL 10
l, 3-Dichlorobenzene ......................... . BDL 10
l,4-Dichlorobenzene ....... : .................. . BDL 10
l, l-Dichloroethane .......................... . BDL 2
l, 2 -Dichloroethane .......................... . BDL 2
l, 1-Dichloroethene .......................... . BDL 2
trans-1,2-Dichloroethene .................... . BDL 2
l, 2-Dichloropropane ......................... . BDL 2
cis-1,3-Dichloropropene ..................... . BDL 2
trans-1,3-Dichloropropene ................... . BDL 2
Ethylbenzene ................................ .
Methylene chloride .......................... .
BDL 2
BDL 10
BDL -Below Detection Limit
A Unit of American Analvtical Services, Inc.
,.
Conestoga-Rovers
Page 2 of 2
• •
September 11, 1998
Report No.I 98135-3
I Wastewater, Jadco-Hughes, Project #3669, Trip Blank, received 08/07,98
I
RESULTS
Volatile Organics (EPA 624)
1,1,2,2-Tetrachloroethane ................... .
Tetrachloroethene ........................... .
Toluene ..................................... .
1, 1, 1-Trichloroethane ....................... .
1, 1, 2-Trichloroethane ....................... .
Trichloroethene ............................. .
Trichlorofluoromethane ........ · .............. .
Vinyl chloride ........... • ................... .
Xylenes ..................................... .
BDL -Below Detection Limit
North Carolina Laboratory I.D. No. 381
Result
(ug/1)
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
I
Detection
\ Limit
(ug/1)
2
2
2
2
I 2
I· 2
I 10
I
10
3
,. • •
Analytical Services Inc. Batch QC
For Report Number :98135
Acids
Page 1
Matrix : Aqueous Batch# 40911 Method: EPA 625
Lab Control Information
Analyte
4-Chloro-3-methylphenol
2-Chlorophenol
2,4-Dichlorophenol
2,4-Dimethylphenol
2,4-Dinitrophenol
4,6-Dinitro-2-methylphenol
2-Nitrophenol
4-Nitrophenol
Pentachlorophenol
Phenol
2,4,6-Trichlorophenol
Matrix Spike Information
Analyte
4-Chloro-3-methylphenol
2-Chlorophenol
~.4-Dichlorophenol
2,4-Dimethylphenol
2,4-Dinitrophenol
4,6-Dinitro-2-methylphenol
2-Nitrophenol
4-Nitrophenol
Pentachlorophenol
Phenol
2,4,6-Trichlorophenol
NC= Not Calculated
LC
%Rec
83
73
82
87
39
61
81
28
91
34
87
MS
%Rec
69
60
GL'.
179
0
0
19
17
57
787
70
LCD
%Rec
90
78
89
92
61
83
86
31
102
37
90
MSD
%Rec
95
66
·, 1
218
0
11
41
19
67
848
76
LC
RPD
9
7
8
6
43
30
6
11
11
8
4
MS
RPD
32
9
l'....i
20
NC
NC
72
11
17
7
8
%Recovery
Range
23 -97
27 -123
39 -135
32 -119
10 -191
10 -181
19 -182
10 -80
9 -103
12 -89
37 -144
%Recovery
Range
23 -97
27 -123
J:J lJS
32 -119
10 -191
10 -181
19 -182
10 -80
9 -103
12 -89
37 -144
RPD
Range
0 -42
0 -40
0 -40
0 -40
0 -50
0 -93
0 -40
0 -50
0 -50
0 -42
0 -40
RPD
Range
0 -42
0 -40
V 40
0 -40
0 -50
0 -93
0 -40
0 -50
0 -50
0 -42
0 -40
,. • •
Page 2
Analytical Services Inc. Batch QC
Surrogate Recovery
Acids
Matrix Aqueous Batch# 40911 Method EPA 625
%-Recovery Objectives
Sl 2-Fluorophenol 21 -100
S2 Phenol-d5 10 -94
Sample File Sl S2 S3 S4 S5 S6
40911BLK B7800 47 33
40911LCS B7801 48 30
40911LCSD B7802 48 31
98026-1 B7808 55 40
AANote: ACID ONLY
98058-2 B7809 43 31
98060-1 B7876 40 30
97982 B7879 37 53
.......... Note: 1:10 DILUTION
97982MS B7882 49 26
AANote: 1:10 DILUTION
97982MSD B7883 54 3.0
''Nots; 1:10 DILUT10N
98135-2 B7836 35 23
98175 B7928 31 23
98029-1 B7929 51 33
98029-2 B7932 47 23
98029-3 B7933 29 15
98029-4 B7936 33 18
98029-5 B7937 32 18
98029-6 B7940 44 23
98029-7 B7941 32 18
98029-8 Al696 36 24
98029-9 Al698 35 23
98029-10 Al699 26 17
98029-lODUP Al702 25 14
,. •
Q.C. Information for Batch# 40911
•
Page 3
Printed: 09/01/98 10:50:36
Blank Results Information
Acids Method: EPA 625
Blank Detection
Analyte Result Limit
Benzoic Acid BDL 50
4-Chloro-3-methylphenol BDL 10
2-Chlorophenol BDL 10
2,4-Dichlorophenol BDL 10
2,4-Dimethylphenol BDL 10
2,4-Dinitrophenol BDL 50
4,6-Dinitro-2-methylphenol BDL 50
2-Methylphenol BDL 10
4-Methylphenol BDL 10
2-Nitrophenol BDL 50
4-Nitrophenol BDL 50
Pentachlorophenol BDL 20
Phenol BDL 10
2,4,6-Trichlorophenol BDL 10
2,4,5-Trichlorophenol BDL 10
• •
Page 4
Q.C. Information for Batch# 40911 Printed: 09/01/98 10:50:36
Sample Batch Information
Acids Method : EPA 625
Preparation Preparation Analysis
Sample ID Date Time By Notes Date Time By Inst #
40911BLK 08/09/98 0800 SB/JS 08/12/98 0554 RAC 5971
40911LCS 08/09/98 0800 SB/JS 08/12/98 0630 RAC 5971
40911LCSD 08/09/98 0800·SB/JS 08/12/98 0706 RAC 5971
98026-1 08/09/98 0800 SB/JS 08/12/98 1047 RAC 5971
98058-2 08/09/98 0800 SB/JS 08/12/98 1124 RAC 5971
98060-1 08/09/98 0800 SB/JS 08/14/98 0585 RAC 5971
97972-1 08/09/98 0800 SB/JS 08/14/98 0935 RAC 5971
97982MS 08/09/98 0800 SB/JS 08/14/98 1320 RAC 5971
97982MSD 08/09/98 0800 SB/JS 08/14/98 1357 RAC 5971
97982 08/09/98 0800 SB/JS 08/14/98 1049 RAC 5971
98135-2 08/11/98 1700 SB/JS 08/14/98 1644 RAC 5971
98029-1 08/12/98 0600 CP/JS 08/16/98 0319 RAC 5971
98029-2 08/12/98 0600 CP/JS 08/16/98 0509 RAC 5971
98029-3 08/12/98 0600 CP/JS 08/16/98 0546 RAC 5971
98029-4 08/12/98 0600 CP/JS 08/16/98 0735 RAC 5971
98029-5 08/12/98 0600 CP/JS 08/16/98 0812 RAC 5971
98029-6 08/12/98 0600 CP/JS 08/16/98 1001 RAC 5971
98029-7 08/12/98 0600 CP/JS 08/16/98 1037 RAC 5971
98029-8 08/12/98 0600 CP/JS 08/17/98 0105 RAC 5973
98029-9 08/12/98 0600 CP/JS 08/17/98 0208 RAC 5973
98029-10 08/12/98 0600 CP/JS 08/17/98 0240 RAC 5973
98U29-10DUP 08/12/98 0600 CP/JS 08/17/98 041S RAC 5973
98175 08/12/98 0600 CP/JS 08/16/98 0242 RAC 5971
,. • •
Page 5
Analytical Services Inc. Batch QC
For Report Number :98135
Base Neutrals
Matrix : Aqueous Batch # 40912 Method : EPA 625
Lab Control Information LC LCD LC %Recovery RPD
Analyte %Rec %Rec RPD Range Range
Acenaphthene 64 77 18 46 -118 0 -31
Acenaphthylene 69 81 15 33 -145 0 -40
Anthracene 79 89 12 27 -133 0 -40
Benzi dine 50 64 24 10 -200 0 -100
Benzo(a)anthracene 65 65 0 33 -143 0 -40
Benzo(b)fluoranthene 75 90 18 24 -159 0 -40
Benzo(k)fluoranthene 71 87 21 11 -162 0 -42
Benzo (a) pyrene . 73 84 15 17 -163 0 -40
Benzo(ghi)perylene 66 72 8 10 -219 0 -56
Benzyl butyl phthalate 61 65 6 10 -152 0 -40
Bis(2-chloroethyl)ether 58 64 9 10 -150 0 -50
Bis(2-chloroethoxy)methane 80 89 11 33 -184 0 -43
Bis(2-ethylhexyl)phthalate 89 Bl 9 10 -158 0 -40
Bis(2-chloroisopropyl)ether 36 39 8 36 -166 0 -46
4-Bromophenyl phenyl ether 85 98 15 53 -127 0 -40
2-Chloronaphthalene 71 86 19 60 -118 0 -40
4-Chlorophenyl phenyl ether 78 92 16 28 -158 0 -33
Chrysene 71 71 0 17 -168 0 -48
Dibenzo(a,h)anthracene 65 74 12 10 -227 0 -70
Di-n-butylphthalate 72 88 20 10 -118 0 -50
1,3-Dichlorobe11zene 49 Sl 4 lU 17:;: u r. ,". ~v
1,2-Dichlorobenzene 55 58 5 32 -129 0 -40
1,4-Dichlorobenzene 52 53 2 36 -97 0 -28
3,3'-Dichlorobenzidine 113 117 4 10 -262 0 -100
Diethylphthalate 51 63 22 10 -114 0 -40
Dimethylphthalate 33 32 4 0 -110 0 -40
2,4-Dinitrotoluene 83 79 5 24 -96 0 -38
2,6-Dinitrotoluene 80 99 21 50 -158 0 -40
Di-n-octylphthalate 102 111 8 10 -146 0 -50
Fluoranthene 79 94 17 26 -137 0 -40
Fluorene 66 78 17 59 -129 0 -40
Hexachlorobenzene 91 105 15 10 -152 0 -40
Hexachlorobutadiene 53 61 13 24 -116 0 -40
Hexachloroethane 50 51 3 40 -113 0 -40
Indeno(l,2,3-cd)pyrene 66 74 11 10 -171 0 -45
Isophorone 70 77 10 21 -196 0 -60
Naphthalene 58 65 10 21 -133 0 -40
Nitrobenzene 79 90 13 35 -180 0 -40
N-Nitrosodi-n-propylamine 86 91 6 41 -116 0 -38
Phenanthrene 75 85 13 54 -120 0 -40
Pyrene 70 66 5 26 -127 0 -31
1,2,4-Trichlorobenzene 58 67 14 44 -142 0 -28
• •
Page 6
Analytical Services Inc. Batch QC
Base Neutrals
Matrix : Aqueous Batch # 40912 Method : EPA 625
Matrix Spike Information MS MSD MS %Recovery RPD
Analyte %Rec %Rec RPD Range Range
Acenaphthene 54 57 4 46 -118 0 -31
Acenaphthylene 57 52 11 33 -145 0 -40
Anthracene 0 60 NC 27 -133 0 -40
Benzi dine 72 66 9 10 -200 0 -100
Benzo(a)anthracene 49 52 5 33 -143 0 -40
Benzo(b)fluoranthene 42 45 8 24 -159 0 -79
Benzo(k)fluoranthene 47 56 18 11 -162 0 -42
Benzo(a)pyrene 41 45 9 17 -163 0 -40
Benzo(ghi)perylene 29 28 1 10 -219 0 -56
Benzyl butyl phthalate 34 41 20 10 -152 0 -40
Bis(2-chloroethyl)ether 41 45 9 10 -150 0 -50
Bis(2-chloroethoxy)methane 79 84 6 33 -184 0 -43
Bis(2-ethylhexyl)phthalate 87 91 4 10 -158 0 -40
Bis(2-chloroisopropyl)ether 18 24 26 36 -166 0 -46
4-Bromophenyl phenyl ether 55 55 1 53 -127 0 -40
2-Chloronaphthalene 61 63 3 60 -118 0 -40
4-Chlorophenyl phenyl ether 63 63 1 28 -158 0 -33
Chrysene 49 52 6 17 -168 0 -48
Dibenzo(a,h)anthracene 31 30 3 10 -227 0 -70
Di-n-butylphthalate 36 48 29 10 -118 0 -50
1,3-Dichlorobenzene 31 35 11 10 -172 0 -40
1,2-Dichlorobenzene 37 4U 8 J2 129 (J 40
1,4-Dichlorobenzene 34 35 3 36 -97 0 -28
3,3'-Dichlorobenzidine 37 40 8 10 -262 0 -100
Diethylphthalate 0 0 NC 10 -114 0 -40
Dimethylphthalate 0 0 NC 0 -110 0 -40
2,4-Dinitrotoluene 0 0 NC 24 -96 0 -38
2,6-Dinitrotoluene 187 0 NC 50 -158 0 -40
Di-n-octylphthalate 84 96 13 10 -146 0 -50
Fluoranthene 60 59 0 26 -137 0 -40
Fluorene 62 61 1 59 -121 0 -40
Hexachlorobenzene 55 60 9 10 -152 0 -40
Hexachlorobutadiene 36 40 8 24 -116 0 -40
Hexachloroethane 11 0 NC 40 -113 0 -40
Indeno(l,2,3-cd)pyrene 30 29 2 10 -171 0 -45
Isophorone 50 61 21 21 -196 0 -60
Naphthalene 91 108 16 21 -133 0 -40
Nitrobenzene 11 12 14 35 -180 0 -40
N-Nitrosodi-n-propylamine 73 90 21 41 -116 0 -38
Phenanthrene 67 67 1 54 -120 0 -40
Pyrene 57 58 2 26 -127 0 -31
1,2,4-Trichlorobenzene 43 48 11 44 -142 0 -28
NC= Not Calculated
• •
Analytical Services Inc. Batch QC
Surrogate Recovery
Base Neutrals
Matrix Aqueous Batch# 40912 Method
% Recovery Objectives
Sl
Sample File
40912BLK B7803
40912LCS B7804
40912LCSD B7805
98058-2 B7810
98069-1 B7874
AANote: BN only
98060-1 B7875
97972-1 B7878
AANote: BN only
97982 B7880
AANote: 1:10 DILUTION
97982MS B7881
A"'Note: 1:10 DILUTION
98139 B7834
AANote: BN only
98135-2
97982MSD
"'""Note: 1:10
98104-2
98106-1
98106-2
98106-3
98106-4
98175
98029-1
98029-2
98029-4
98029-6
98029-7
98029-5
98029-9
98029-10
98029-l0DUP
98029-8
B7835
B7837
DILUTION
B7919
B7920
B7922
B7923
B7926
B7927
B7930
B7931
B7935
B7939
B7942
B7938
Al697
Al700
Al701
B7943
Nitrobenzene-d5
Sl S2
92
82
94
89
77
58
82
73
84
44
91
76
43
56
70
Bl
65
62
102
82
77
86
69
48
57
58
55
78
35 -114
S3 S4
Page 7
EPA 625
S5 S6
•
Q.C. Information for Batch# 40912
•
Page 8
Printed: 09/01/98 10:50:39
Blank Results Information
Base Neutrals Method: EPA 625
Analyte
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
Benzo(ghi)perylene
Benzyl butyl phthalate
Bis(2-chloroethyl)ether
Bis(2-chloroethoxy)methane
Bis(2-ethylhexyl)phthalate
Bis(2-chloroisopropyl)ether
4-Bromophenyl phenyl ether
4-Chloroaniline
2-Chloronaphthalene
4-Chlorophenyl phenyl ether
Chrysene
Dibenzo(a,h)anthracene
Dibenzofuran
Di-n-butylphthalate
1,3-Dichlorobenzene
1,2-Dichlorobenzene
1,4-Dichlorobenzene
3,3'-Dichlorobenzidine
Diethylphthalate
Dimethylphthalate
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Di-n-octylphthalate
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadiene
Hexachloroethane
Indeno(l,2,3-cd)pyrene
Isophorone
2-Methylnaphthalene
Naphthalene
2-Nitroaniline
3 -Ni troaniline
4-Nitroaniline
Nitrobenzene
N-Nitrosodiphenylamine
N-Nitrosodi-n-propylamine
Phenanthrene
Pyrene
1,2,4-Trichlorobenzene
Blank
Result
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
Detection
Limit
10
10
10
10
10
10
10
10
10
10
10
10
10
10
20
10
10
10
10
10
10
lU
10
10
20
10
10
20
20
10
10
10
10
10
10
2
10
10
10
10
50
50
50
10
10
10
10
10
10
• •
Page 9
Q.C. Information for Batch# 40912 Printed: 09/01/98 10:50:40
Sample Batch Information
Base Neutrals Method : EPA 625
Preparation Preparation Analysis
Sample ID Date Time By Notes Date Time By Inst #
40912BLK 08/09/98 0800 SB 08/12/98 0743 RAC 5971
40912LCS 08/09/98 0800 SB 08/12/98 0819 RAC 5971
40912LCSD 08/09/98 0800 SB 08/12/98 0856 RAC 5971
98058-2 08/09/98 0800 SB 08/12/98 1201 RAC 5971
98069-1 08/09/98 0800 SB 08/14/98 0744 RAC 5971
98060-1 08/09/98 0800 SB 08/14/98 0821 RAC 5971
97972-1 08/09/98 0800 SB 08/14/98 1012 RAC 5971
97982 08/09/98 0800 SB 08/14/98 1206 RAC 5971
97982MS 08/09/98 0800 SB 08/14/98 1243 RAC 5971
98139 08/11/98 1700 JC/SB 08/14/98 1529 RAC 5971
98135-2 08/11/98 1700 JC/SB 08/14/98 1606 RAC 5971
97982MSD 08/11/98 0800 SB 08/14/98 1721 RAC 5971
98029-1 08/12/98 0600 CP/JS 08/16/98 0356 RAG 5971
98029-2 08/12/98 0600 CP/JS 08/16/98 0432 RAC 5971
98029-4 08/12/98 0600 CP/JS 08/16/98 0659 RAC 5971
98029-6 08/12/98 0600 CP/JS 08/16/98 0925 RAC 5971
98029-7 08/12/98 0600 CP/JS 08/16/98 1114 RAC 5971
98029-8 08/12/98 0600 CP/JS 08/16/98 1150 RAC 5971
98029-5 08/12/98 0600 CP/JS 08/16/98 0848 RAC 5971
98029-9 08/12/98 0600 CP/JS 08/17/98 0136 RAC 5973
98029-10 08/12/98 0600 CP/JS 08/17/98 0312 RAC 5973
98029 -lC:!.:.11Jt' 08/12/98 0600 CP/J·s O'd/l'J/98 0343 RAC 5973
98029-3 08/12/98 0600 CP/JS 08/17/98 0433 RAC 5973
97951 08/09/98 0800 SB . I I
98026-1 08/09/98 0800 SB I I
98104-2 I I 08/15/98 2114 RAC 5971
98106-1 I I 08/15/98 2151 RAC 5971
98106-2 I I 08/15/98 2304 RAC 5971
98106-3 I I 08/15/98 2340 RAC 5971
98106-4 I I 08/16/98 0103 RAC 5971
98175 I I 08/16/98 0206 RAC 5971
98136-1 I I 08/17/98 0447 RAC 5973
.. • •
Analytical Services Inc. Batch QC
For Report Number :98135
Volatile Organics
Page 10
Matrix: Aqueous Batch# 40961 Method: EPA 624
Lab Control Information
Analyte
Benzene
Bromodichloromethane
Bromoform
Bromomethane
Carbon tetrachloride
Chlorobenzene
Chloroethane
2-Chloroethylvinyl ether
Chloroform
Chloromethane
Dibromochloromethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans-l,3·Dichloropropene
Ethylbenzene
Methylene chloride
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
LC
%Rec
102
100
91
197
87
107
112
80
102
98
94
111
107
109
101
101
102
98
104
103
101
109
97
98
104
96
95
102
102
111
99
LCD
%-Rec
98
103
99
209
90
106
108
97
98
89
101
109
104
107
98
99
98
96
103
101
102
106
97
98
103
91
95
99
100
108
94
LC
RPD
4
3
9
6
3
2
3
20
4
10
7
2
3
2
3
2
4
3
1
2
1
3
1
0
1
5
1
3
2
3
5
%Recovery
Range
37 -151
35 -155
45 -169
D -242
70 -140
37 -160
14 -230
D -305
51 -138
D -273
53 -149
18 -190
59 -156
18 -190
59 -155
49 -155
D -234
54 -156
D -210
D -227
11 183
37 -162
D -221
46 -157
64 -148
47 -150
52 -162
52 -150
71 -157
17 -181
D -251
RPD
Range
0 -20
0 -20
0 -20
0 -20
0 -20
0 -20
0 -20
0 -20
0 -20
0 -20
0 -20
0 -20
0 -20
0 -20
0 -20
0 -20
0 -20
0 -20
0 -20
0 -20
0 :; ()
0 -20
0 -20
0 -20
0 -20
0 -20
0 -20
0 -20
0 -20
0 -20
0 -20
• •
Page 11
Analytical Services Inc. Batch QC
Volatile Organics
Matrix : Aqueous Batch # 40961 Method : EPA 624
Matrix Spike Information MS MSD MS %Recovery RPD
Analyte %Rec %Rec RPD Range Range
Benzene 107 107 0 37 -151 0 -20
Bromodichloromethane 116 119 3 35 -155 0 -20
Bromoform 117 121 4 45 -169 0 -20
Bromomethane. 184 225 20 D -242 0 -20
Carbon tetrachloride 103 106 3 70 -140 0 -20
Chlorobenzene 116 115 1 37 -160 0 -20
Chloroethane 117 117 0 14 -230 0 -20
2-Chloroethylvinyl ether 1 1 13 D -305 0 -20
Chloroform 112 112 0 51 -138 0 -20
Chloromethane 99 96 3 D -273 0 -20
Dibromochloromethane 116 121 4 53 -149 0 -20
1,2-Dichlorobenzene 122 119 2 18 -190 0 -20
1,3-Dichlorobenzene 113 108 5 59 -156 0 -20
1,4-Dichlorobenzene 120 115 4 18 -190 0 -20
1,1-Dichloroethane 110 110 0 59 -155 0 -20
1,2-Dichloroethane 111 112 1 49 -155 0 -20
1,1-Dichloroethene 104 107 3 D -234 0 -20
trans-1,2-Dichloroethene 103 103 0 54 -156 0 -20
1,2-Dichloropropane 113 113 0 D -210 0 -20
cis-1,3-Dichloropropene 111 113 2 D -227 0 -20
trans-1,3-Dichloropropene 112 113 1 17 -183 0 -20
Ethylbenzeue 114 lLJ l 37 162 iJ -20
Methylene chloride 105 106 1 D -221 0 -20
1,1,2,2-Tetrachloroethane 117 113 3 46 -157 0 -20
Tetrachloroethene 106 105 1 64 -148 0 -20
Toluene 99 100 1 47 -150 0 -20
1,1,1-Trichloroethane 103 105 1 52 -162 0 -20
1,1,2-Trichloroethane 114 115 1 52 -150 0 -20
Trichloroethene 106 106 0 71 -157 0 -20
Trichlorofluoromethane 115 117 2 17 -181 0 -20
Vinyl chloride 101 103 1 D -251 0 -20
• •
Page 12
Analytical Services Inc. Batch QC
Surrogate Recovery
Volatile Organics
Matrix Aqueous Batch# 40961 Method EPA 624
% Recovery Objectives
Sl l,2-Dichloroethane-d4 76 -119
S2 Toluene-dB 88 -110
S3 Ethylbenzene-dl0 75 -115
S4 4-Bromofluorobenzene 86 -115
Sample File Sl S2 S3 S4 S5 S6
40961LCS A5516 106 106 106 105
40961LCSD A5517 108 106 106 106
40961BLK A5518 106 105 104 105
98174-1 A5519 108 106 105 107
98174-2 A5520 109 105 101 105
98174-2DUP A5521 110 105 102 104
98174-2MS A5522 109 105 106 105
98174-2MSD A5523 111 106 106 104
98174-3 A5524 112 100 97 104
98174-4 A5525 109 105 103 102
98174-5 A5526 112 105 101 104
98174-lD A5527 108 104 103 104
AANote: DF=5
97982 A5530 111 106 99 103
98135-2 A5533 108 105 102 105
98135-2DUP A5534 109 106 102 102
98135-3 A5535 111 106 102 103
98029-1 B7978 116 100 95 90
98029-2 B7979 108 99 98 92
98029-3 B8009 117 95 97 90
98029-4 B7998 108 101 98 93
98029-5DUP B7999 114 101 96 91
98029-6 B8000 109 100 97 91
98029-7 B8001 111 99 97 91
98029-8 B8002 115 100 95 90
98029-9 B8003 111 99 97 87
98029-10 B8004 116 99 95 88
98136-1 B7991 102 98 99 88
•
Q.C. Information for Batch# 40961
•
Page 13,
Printed: 09/01/98 10:50:43
Blank Results Information
Volatile Organics Method: EPA 624
Analyte
Acetone
Benzene
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Dibromochloromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethene
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethylbenzene
2-Hexanone
Methylene chloride
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Vinyl chloride
Xylenes
2-Chloroethylvinyl ether
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,2-Dichloroethene
Trichlorofluoromethane
Blank
Result
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
Detection
Limit
100
2
10
10
10
100
5
2
10
5
2
10
10
2
2
2
2
2
2
2
2
so
10
2
2
2
2
2
2
10
2
10
10
10
10
2
10
• •
Page 14
Q.C. Information for Batch# 40961 Printed: 09/01/98 10:50:43
Sample Batch Information
Volatile Organics Method EPA 624
Preparation Preparation Analysis
Sample ID Date Time By Notes Date Time By Inst #
40961LCS I I 08/11/98 1911 LLP VOAl
40961LCSD I I 08/11/98 1938 LLP VOAl
40961BLK I I 08/11/98 2005 LLP VOAl
98174-1 I I 08/11/98 2031 LLP VOAl
98,174-2 I I 08/11/98 2058 LLP VOAl
98174-2DUP I I 08/11/98 2124 LLP VOAl
98174-2MS I I 08/11/98 2151 LLP VOAl
98174-2MSD I I 08/11/98 2238 LLP VOAl
98174-3 I I 08/11/98 2304 LLP VOAl
98174-4 I I 08/11/98 2331 LLP VOAl
98174-5 I I 08/11/98 2357 LLP VOAl
98174-lD I I 08/12/98 0024 LLP VOAl
97982 I I 08/12/98 0144 TLW VOAl
98135-2 I I 08/12/98 0303 TLW VOAl
98135-2DUP I I 08/12/98 0330 TLW VOAl
98135-3 I I 08/12/98 0356 TLW VOAl
98029-1 I I 08/14/98 2110 LLP VOA2
98029-2 I I 08/14/98 2134 LLP VOA2
98029-3 I I 08/15/98 2010 TLW VOA2
98029-4 I I 08/14/98 1548 LLP VOA2
98029-SDUP I I 08/14/98 1611 LLP VOA2
98029-6 ' / ()8/14/98 1615 LLP VOA2 I ' 98029-7 I I 08/14/98 1659 LLP VOA2
98029-8 I I 08/14/98 1724 LLP VOA2
98029-9 I I 08/14/98 1748 LLP VOA2
98029-10 I I 08/14/98 1812 LLP VOA2
98136-1 I I 08/14/98 1230 LLP VOA2
• •
Analytical Services Inc. Batch QC
For Report Number :98135
PCB's
Page 15
Matrix: Aqueous Batch# 40966 Method: EPA 608
Lab Control Information
Analyte
PCB 1016
PCB 1260
Matrix Spike Information
Analyte
PCB 1016
PCB 1260
NC; Not Calculated
LC
%Rec
76
85
MS
%Rec
0
0
LCD
%Rec
124
133
MSD
%Rec
0
0
LC
RPD
48
44
MS
RPD
NC
NC
%Recovery
Range
so -150
50 -150
%Recovery
Range
50 -150
50 -150
RPD
Range
0 -50
0 -50
RPD
Range
0 -so
0 -50
•'
Matrix
Sample
40966BLK
40966LCS
40966LCSD
98135-2
• •
Analytical Services Inc. Batch QC
Surrogate Recovery
PCB's
Aqueous Batch# 40966 Method
Sl
S2
% Recovery Objectives
Tetrachloro-m-xylene
Decachlorobiphenyl
File Sl S2
081298012R 95 79
081298013R 52 71
081298014R 110 94
081198021F 91 117
S3
47 -113
10 -139
S4
Page 16
EPA 608
S5 S6
PCB
PCB
PCB
PCB
PCB
PCB
PCB
•
Q.C. Information for Batch# 40966
•
Page 17
Printed: 09/01/98 10:50:44
Blank Results Information
PCB's Method : EPA 608
Blank Detection
Analyte Result Limit
1016 BDL 1. 0
1221 BDL 1. 0
1232 BDL 1.0
1242 BDL 1.0
1248 BDL 1.0
1254 BDL 1.0
1260 BDL 1.0
Sample ID
40966BLK
40966LCS
40966LCSD
98175
98175MS
98175MSD
98135-2
• •
Q.C. Information for Batch# 40966
Page 18
Printed: 09/01/98 10:50:44
Sample Batch Information
PCB's Method : EPA 608
Preparation· Preparation Analysis
Date Time By Notes Date Time By
08/10/98 0800 SB/JC 08/11/98 2232 JPH
08/10/98 0800 SB/JC 08/11/98 2251 JPH
08/10/98 0800 SB/JC 08/11/98 2310 JPH
08/11/98 1300 SB/JC I I
08/11/98 1300 SB/JC I I
08/11/98 1300 SB/JC I I
08/11/98 1300 SB/JC 08/11/98 2013 JQZ
Inst #
GC-4
GC-4
GC-4
GC-3
• •
Page 19
Analytical Services Inc. Batch QC
For Report Number :98135
QC Batch General Information
Batch Analysis Blank Prep.
Number Analyte Method Matrix Result Method
40468 Hg EPA 245.1 Aqueous < 0.0002
>-"Note MS/MSD FOR 98135
40468 Hg EPA 245.1 Aqueous < 0.0002
AANote MS/MSD FOR 98174
40711 Se EPA 270.2 Aqueous < 0.0050
.......... Note QC PASSES ON LCS,LCSD
40711 Pb EPA 239.2 Aqueous < 0.0050
,...,..Note Batch passes on LCS/LCSD/MS/MSD
40727 Zn EPA 200.7 Aqueous < 0.0200
40727 Ag EPA 200.7 Aqueous < 0.0100
40727 As EPA 200.7 Aqueous < 0.0100
40727 Ba EPA 200.7 Aqueous < 0.0100
40727 Be EPA 200.7 Aqueous < 0.0010
40727 Cd EPA 200.7 Aqueous < 0.0010
40727 Cr EPA 200.7 Aqueous < .0.0050
40727 Cu EPA 200.7 Aqueous < 0.0100
40727 Mg EPA 200.7 Aqueous < 0.0500
40727 Ni EPA 200.7 Aqueous < 0.0100
40727 Sb EPA 200.7 Aqueous < 0.0100
40727 Al EPA 200.7 Aqueous < 0.1000
40727 Co EPA 200.7 Aqueous < 0.0100
40727 Fe EPA 200.7 Aqueous < 0.0400
40727 Mn EPA 200.7 Aqueous < 0.0100
40727 Na EPA 200.7 Aqueous < 0.0500
40727 V EPA 200.7 Aqueous < 0.0100
40727 Ca EPA 200.7 Aqueous < 0.0500
40887 pH EPA 150.1 Aqueous 0.0000
40934 NH3-N EPA 350.2 Aq/Solid < 0.1000
40945 BOD<5 hi SM 5210 B Aqueous < 5.0000
40945 BOD<5 low SM 5210 B Aqueous < 5.0000
40950 0/G EPA 1664 Aqueous 0.0000
40958 TSS EPA 160.2 Aqueous < 5.0000
41016 CN EPA 335.2 Aqueous < 0.0100
• •
Page 20
Analytical Services Inc. Batch QC
For Report Number :98135
Lab Control Information
Batch LC LCD LC %Recovery RPD
Number Analyte Method %Rec %Rec RPD Range Range
40468 Hg EPA 245.1 102 103 1 76 -124 0 -20
40468 Hg EPA 245.1 102 103 1 76 -124 0 -20
40711 Se EPA 270.2 114 114 0 76 -124 0 -20
40711 Pb EPA 239.2 84 83 1 76 -124 0 -20
40727 Zn EPA 200.7 93 93 0 85 -115 0 -20
40727 Ag EPA 200.7 100 100 0 85 -115 0 -20
40727 As EPA 200.7 91 92 1 85 -115 0 -20
40727 Ba EPA 200.7 94 94 0 85 -115 0 -20
40727 Be EPA 200.7 94 95 1 85 -115 0 -20
40727 Cd EPA 200.7 90 91 1 85 -115 0 -20
40727 Cr EPA 200.7 92 93 1 85 -115 0 -20
40727 Cu EPA 200.7 93 93 0 85 -115 0 -20
40727 Mg EPA 200.7 92 93 1 85 -115 0 -20
40727 Ni EPA 200.7 89 90 1 85 -115 0 -20
40727 Sb EPA 200.7 97 98 1 85 -115 0 -20
40727 Al EPA 200.7 97 97 0 85 -115 0 -20
40727 Co EPA 200.7 93 94 1 85 -115 0 -20
40727 Fe EPA 200.7 94 95 1 85 -115 0 -20
40727 Mn EPA 200.7 94 95 1 85 -115 0 -20
40727 Na EPA 200.7 110 110 0 85 -115 0 -20
40727 V EPA 200.7 94 95 1 85 -115 0 -20
40727 Ca EPA 200.7 94 95 1 85 -115 0 -20
40887 pH EPA 150.1 100 100 (J 8 (J 12() (J 20
40934 NH3-N EPA 350.2 92 94 2 75 -125 0 -30
40945 BOD<5 hi SM 5210 B 98 95 3 81 -118 0 -30
40945 BOD<5 low SM 5210 B 112 88 24 81 -118 0 -30
40950 O/G EPA 1664 55 70 24 32 -103 0 -40
40958 TSS EPA 160.2 99 99 0 60 -140 0 -40
41016 CN EPA 335.2 113 110 3 75 -125 0 -30
Matrix Spike Information
Batch MS MSD MS %Recovery RPD
Number Analyte Method %Rec %Rec RPD Range Range
40468 Hg EPA 245.1 97 91 6 76 -124 0 -20
40468 Hg EPA 245.1 97 100 3 76 -124 0 -20
40711 Se EPA 270.2 32 29 10 76 -124 0 -20
40711 Pb EPA 239.2 80 87 8 76 -124 0 -20
40727 Zn EPA 200.7 81 82 1 76 -124 0 -20
40727 Ag EPA 200.7 91 91 0 76 -124 0 -20
40727 As EPA 200.7 81 83 2 76 -124 0 -20
40727 Ba EPA 200.7 83 85 2 76 -124 0 -20
40727 Be EPA 200.7 85 87 2 76 -124 0 -20
40727 Cd EPA 200.7 80 82 2 76 -124 0 -20
40727 Cr EPA 200.7 83 85 2 76 -124 0 -20
40727 Cu EPA 200.7 84 86 2 76 -124 0 -20
• •
Page 21
Analytical Services Inc. Batch QC
For Report Number :98135
Matrix Spike Information
Batch MS MSD MS %Recovery RPD
Number Analyte Method %Rec %Rec RPD Range Range
40727 Mg EPA 200.7 81 84 4 76 -124 0 -20
40727 Ni EPA 200.7 78 80 3 76 -124 0 -20
40727 Sb EPA 200.7 86 88 2 76 -124 0 -20
40727 Al EPA 200.7 87 89 2 76 -124 0 -20
40727 Co EPA 200.7 82 84 2 76 -124 0 -20
40727 Fe EPA 200.7 85 86 1 76 -124 0 -20
40727 Mn EPA 200.7 84 86 2 76 -124 0 -20
40727 Na EPA 200.7 100 100 0 76 -124 0 -20
40727 V EPA 200.7 85 87 2 76 -124 0 -20
40727 Ca EPA 200.7 79 84 6 76 -124 0 -20
40934 NH3-N EPA 350.2 94 96 2 75 -125 0 -30
40950 0/G EPA 1664 118 0 NC 32 -103 0 -40
40958 TSS EPA 160.2 100 102 2 60 -140 0 -40
41016 CN EPA 335.2 108 105 3 75 -125 0 -30
Post Digestion Spike Information ·
Batch PDS %Recovery
Number Analyte Method %Rec Range
ljQ'lll Sc: EPA 270 . .?. 3 ~~ 7G j_24
40727 Zn EPA 200.7 95 85 -115
40727 Ag EPA 200.7 100 85 -115
40727 As EPA 200.7 95 85 -115
40727 Ba EPA 200.7 96 85 -115
40727 Be EPA 200.7 98 85 -115
40727 Cd EPA 200.7 91 85 -115
40727 Cr EPA 200.7 94 85 -115
40727 Cu EPA 200.7 98 85 -115
40727 Mg EPA 200.7 96 85 -115
40727 Ni EPA 200.7 93 85 -115
40727 Sb EPA 200.7 100 85 -115
40727 Al EPA 200.7 101 85 -115
40727 Co EPA 200.7 96 85 -115
40727 Fe EPA 200.7 99 85 -115
40727 Mn EPA 200.7 98 85 -115
40727 Na EPA 200.7 120 85 -115
40727 V EPA 200.7 98 85 -115
40727 Ca EPA 200.7 95 85 -115
• •
Analytical Services Inc. Batch QC
For Report Number :98135
Unspiked Sample Duplicate Information
Sample Batch
Number
40887
40934
40945
40958
41016
Analyte
pH
NH3-N
BOD<5 hi
TSS
CN
Sample 1
Method RPD RPD
EPA 150.1 0 0
EPA 350.2 0 0
SM 5210 B 0 0
EPA 160.2 0 17
EPA 335.2 0 0
Page 22
2 RPD
Range
0 -20
0 -30
0 -30
0 -40
0 -30
• •
Page 23
Q.C. Information for Batch# 40468 For Report Number :98135
Sample Batch Information
Analysis : Hg, Hg
Preparation Preparation Analysis
Sample ID Tag Date Time By Notes Date Time By Inst
40468BLANK HG 08/10/98 0831 FBS 08/10/98 1311 FBS HGl
40468LCS HG 08/10/98 0831 FBS 08/10/98 1313 FBS HGl
40468LCSD HG 08/10/98 0831 FBS 08/10/98 1316 FBS HGl
98135-lMS HG 08/10/98 0831 FBS 08/10/98 1318 FBS HGl
98135-lMS HG 08/10/98 0831 FBS 08/10/98 1320 FBS HGl
98134-lDUP HG 08/10/98 0831 FBS 08/10/98 1323 FBS HGl
98029-10 HG 08/10/98 0831 FBS 08/10/98 1252 FBS HGl
98029-9 HG 08/10/98 0831 FBS 08/10/98 1250 FBS HGl
98043 HG 08/10/98 0831 FBS 08/10/98 1255 FBS HGl
98134-1 HG 08/10/98 0831 FBS 08/10/98 1214 FBS HGl
98134-2 HG 08/10/98 0831 FBS 08/10/98 1216 FBS HGl
98134-3 HG 08/10/98 0831 FBS 08/10/98 1218 FBS HGl
98134-4 HG 08/10/98 0831 FBS 08/10/98 1221 FBS HGl
98134-5 HG 08/10/98 0831 FBS 08/10/98 1223 FBS HGl
98134-6 HG 08/10/98 0831 FBS 08/10/98 1226 FBS HGl
98134-7 HG 08/10/98 0831 FBS 08/10/98 1228 FBS HGl
98134-8 HG 08/10/98 0831 FBS 08/10/98 1230 FBS HGl
98134-9 HG 08/10/98 0831 FBS 08/10/98 1233 FBS HGl
98134-10 HG 08/10/98 0831 FBS 08/10/98 1235 FBS HGl
98134-11 HG 08/10/98 0831 FBS 08/10/98 1243 FBS HGl
98134-12 HG 08/10/98 0831 FBS 08/10/98 1245 FBS HGl
98135-1 HG 08/lU/98 0831 FBS U8/1U/'.:J8 lJJU FBS HGl
98174-1 HG 08/10/98 0831 FBS 08/10/98 1248 FBS HGl
98174-2 HG 08/10/98 0831 FBS 08/10/98 1332 FBS HGl
98164-1 HG 08/10/98 0831 FBS 08/10/98 1257 FBS HGl
98164-2 HG 08/10/98 0831 FBS 08/10/98 1300 FBS HGl
98174-2MS HG 08/10/98 0831 FBS 08/10/98 1325 FBS HGl
98174-2MSD HG 08/10/98 0831 FBS 08/10/98 1328 FBS HGl
,· • •
Page 24
Q.C. Information for Batch# 40711 For Report Number :98135
Sample Batch Information
Analysis : Se, Pb
Preparation Preparation Analysis
Sample ID Tag Date Time By Notes Date Time By Inst
40711BLANK Se 08/10/98 1020 DCF/DMKGFAA 08/12/98 1016 MLR AAl
40711LCS Se 08/10/98 1020 DCF/DMKGFAA 08/12/98 1016 MLR AAl
40711LCSD Se 08/10/98 1020 DCF/DMKGFAA 08/12/98 1016 MLR AAl
98135-lMS Se 08/10/98 1020 DCF/DMKGFAA 08/12/98 1016 MLR AAl
98135-lMSD Se 08/10/98 1020 DCF/DMKGFAA 08/12/98 1016 MLR AAl
97984PDS Se 08/10/98 1020 DCF/DMKGFAA 08/12/98 1016 MLR AAl
97984DUP Se 08/10/98 1020 DCF/DMKGFAA 08/12/98 1016 MLR AAl
97912 Se 08/10/98 1020 DCF/DMKGFAA 08/12/98 1016 MLR AAl
98044-1 Se 08/10/98 1020 DCF/DMKGFAA 08/12/98 1016 MLR AAl
98044-2 Se 08/10/98 1020 DCF/DMKGFAA 08/12/98 1016 MLR AAl
98044-3 Se 08/10/98 1020 DCF/DMKGFAA 08/12/98 1016 MLR AAl
98044-4 Se 08/10/98 1020 DCF/DMKGFAA 08/12/98 1016 MLR AAl
98044-5 Se 08/10/98 1020 DCF/DMKGFAA 08/12/98 1016 MLR AAl
98044-6 Se 08/10/98 1020 DCF/DMKGFAA 08/12/98 1016 MLR AAl
98044-7 Se 08/10/98 1020 DCF/DMKGFAA 08/12/98 1016 MLR AAl
98044-8 Se 08/10/98 1020 DCF/DMKGFAA 08/12/98 1016 MLR AAl
98135-1 Se 08/10/98 1020 DCF/DMKGFAA 08/12/98 1016 MLR AAl
97984 Se 08/10/98 1020 DCF/DMKGFAA 08/12/98 1016 MLR AAl
40711BLANK As 08/10/98 1020 DCF/DMKGFAA 08/12/98 1259 MLR AAl
40711LCS As 08/10/98 1020 DCF/DMKGFAA 08/12/98 1259 MLR AAl
40711LCSD As 08/10/98 1020 DCF/DMKGFAA 08/12/98 1259 MLR AAl
98Ll5 -lM.S As 08/10/98 1020 DCF'/DMKGFAA 08/12/98 125,i MLR AAl
98135-lMSD As 08/10/98 1020 DCF'/DMKGFAA 08/12/98 1259 MLR AAl
97984PDS As 08/10/98 1020 DCF/DMKGF'AA 08/12/98 1259 MLR AAl
97984DUP As 08/10/98 1020 DCF/DMKGF'AA 08/12/98 1259 MLR AAl
97912 As 08/10/98 1020 DCF/DMKGF'AA 08/12/98 1259 MLR AAl
98044-1 As 08/10/98 1020 DCF/DMKGFAA 08/12/98 1259 MLR AAl
98044-2 As 08/10/98 1020 DCF/DMKGFAA 08/12/98 1259 MLR AAl
98044-3 As 08/10/98 1020 DCF/DMKGFAA 08/12/98 1259 MLR AAl
98044-4 As 08/10/98 1020 DCF/DMKGFAA 08/12/98 1259 MLR AAl
98044-5 As 08/10/98 1020 DCF/DMKGFAA 08/12/98 1259 MLR AAl
98044-6 As 08/10/98 1020 DCF/DMKGFAA 08/12/98 1259 MLR AAl
98044-7 As 08/10/98 1020 DCF/DMKGF'AA 08/12/98 1259 MLR AAl
98044-8 As 08/10/98 1020 DCF/DMKGFAA 08/12/98 1259 MLR AAl
98135-1 As 08/10/98 1020 DCF/DMKGFAA 08/12/98 1259 MLR AAl
97984 As 08/10/98 1020 DCF/DMKGFAA 08/12/98 1259 MLR AAl
40711BLANK Pb 08/10/98 1020 DCF/DMKGFAA 08/14/98 1005 MLR AAl
40711LCS Pb 08/10/98 1020 DCF/DMKGFAA 08/14/98 1005 MLR AAl
40711LCSD Pb 08/10/98 1020 DCF/DMKGFAA 08/14/98 1005 MLR AAl
98135-lMS Pb 08/10/98 1020 DCF/DMKGF'AA 08/14/98 1005 MLR AAl
98135-lMSD Pb 08/10/98 1020 DCF/DMKGFAA 08/14/98 1005 MLR AAl
97984PDS Pb 08/10/98 1020 DCF/DMKGFAA' 08/14/98 1005 MLR AAl
97984DUP Pb 08/10/98 1020 DCF/DMKGFAA 08/14/98 1005 MLR AAl
97912 Pb 08/10/98 1020 DCF'/DMKGFAA 08/14/98 1005 MLR AAl
98044-1 Pb 08/10/98 1020 DCF/DMKGFAA 08/14/98 1005 MLR AAl
98044-2 Pb 08/10/98 1020 DCF/DMKGFAA 08/14/98 1005 MLR AAl
98044-3 Pb 08/10/98 1020 DCF/DMKGFAA 08/14/98 1005 MLR AAl
98044-4 Pb 08/10/98 1020 DCF/DMKGF'AA 08/14/98 1005 MLR AAl
• •
Page 25
Q.C. Information for Batch# 40711 For Report Number :98135
Sample Batch Information
Analysis : Se, Pb
Preparation Preparation Analysis
Sample ID Tag Date Time By Notes Date Time By Inst
98044-5 Pb 08/10/98 1020 DCF/DMKGFAA 08/14/98 1005 MLR AAl
98044-6 Pb 08/10/98 1020 DCF/DMKGFAA 08/14/98 1005 MLR AAl
98044-7 Pb 08/10/98 1020 DCF/DMKGFAA 08/14/98 1005 MLR AAl
98044-8 Pb 08/10/98 1020 DCF/DMKGFAA 08/14/98 1005 MLR AAl
98135-1 Pb 08/10/98 1020 DCF/DMKGFAA 08/14/98 1005 MLR AAl
97984 Pb 08/10/98 1020 DCF/DMKGFAA 08/14/98 1005 MLR AAl
40711BLANK Tl 08/10/98 1020 DCF/DMKGFAA 08/14/98 1435 MLR AA2
40711LCS Tl 08/10/98 1020 DCF/DMKGFAA 08/14/98 1435 MLR AA2
40711LCSD Tl 08/10/98 1020 DCF/DMKGFAA 08/14/98 1435 MLR AA2
98135-lMS Tl 08/10/98 1020 DCF/DMKGFAA 08/14/98 1435 MLR AA2
98135-lMSD Tl 08/10/98 1020 DCF/DMKGFAA 08/14/98 1435 MLR AA2
97984PDS Tl 08/10/98 1020 DCF/DMKGFAA 08/14/98 1435 MLR AA2
97984DUP Tl 08/10/98 1020 DCF/DMKGFAA 08/14/98 1435 MLR AA2
97912 Tl 08/10/98 1020 DCF/DMKGFAA 08/14/98 1435 MLR AA2
98044-1 Tl 08/10/98 1020 DCF/DMKGFAA 08/14/98 1435 MLR AA2
98044-2 Tl 08/10/98 1020 DCF/DMKGFAA 08/14/98 1435 MLR AA2
98044-3 Tl 08/10/98 1020 DCF/DMKGFAA 08/14/98 1435 MLR AA2
98044-4 Tl 08/10/98 1020 DCF/DMKGFAA 08/14/98 1435 MLR AA2
98044-5 Tl 08/10/98 1020 DCF/DMKGFAA 08/14/98 1435 MLR AA2
98044-6 Tl 08/10/98 1020 DCF/DMKGFAA 08/14/98 1435 MLR AA2
98044-7 Tl 08/10/98 1020 DCF/DMKGFAA 08/14/98 1435 MLR AA2
;J8044-ll 'l'l 08/10/98 1020 DCF/DMKGFAA 08/14/98 1435 MLR AA2
98135-1 Tl 08/10/98 1020 DCF/DMKGFAA 08/14/98 1435 MLR AA2
97984 Tl 08/10/98 1020 DCF/DMKGFAA 08/14/98 1435 MLR AA2
. . •
Q.C. Information for Batch# 40727
Page 26
For Report Number :98135
Analysis
Sample ID
40727BLANK
40727LCS
40727LCSD
98135-lMS
98135-lMSD
98154PDS
98154DUP
97978-1
98119-2
98135-1
98148-1
98148-2
98154
98164-1
98164-2
98165-12
98165-13
98165-14
98166
98181-1
98181-2
98179
98014-1
98017
98127
98060-1
98060-2
Sample Batch Information
Zn, Ag, As, Ba, Be, Cd, Cr, Cu, Mg, Ni, Sb; Al, Co, Fe, Mn, Na
V Ca
Preparation
Tag Date Time By
08/12/98 0920 RCP
08/12/98 0920 RCP
08/12/98 0920 RCP
08/12/98 0920 RCP
08/12/98 0920 RCP
08/12/98 0920 RCP
08/12/98 0920 RCP
08/12/98 0920 RCP
08/12/98 0920 RCP
08/12/98 0920 RCP
08/12/98 0920 RCP
08/12/98 0920 RCP
08/12/98 0920 RCP
08/12/98 0920 RCP
08/12/98 0920 RCP
08/12/98 0920 RCP
08/12/98 0920 RCP
08/12/98 0920 RCP
08/12/98 0920 RCP
08/12/98 0920 RCP
08/12/98 0920 RCP
08/12/98 0920 RCP
08/12/98 0920 RCP
08/12/98 0920 RCP
08/12/98 0920 RCP
08/12/98 0920 RCP
08/12/98 0920 RCP
Preparation
Notes
TRACE
TRACE
TRACE
TRACE
TRACE
TRACE
TRACE
TRACE
TRACE
TRACE
TRACE
TRACE
TRACE
TRACE
TRACE
TRACE
TRACE
TRACE
TRACE
TRACE
TRACE
TRACE
TRACE
TRACE
TRACE
TRACE
TRACE
Analysis
Date Time By
08/13/98 0301 MAB
08/13/98 0305 MAB
08/13/98 0309 MAB
08/13/98 0313 MAB
08/13/98 0317 MAB
08/13/98 0321 MAB
08/13/98 0325 MAB
08/13/98 0337 MAB
08/13/98 0912 MAB
08/13/98 0329 MAB
08/13/98 0916 MAB
08/13/98 0920 MAB
08/13/98 0333 MAB
08/13/98 0924 MAB
08/13/98 0928 MAB
08/13/98 0932 MAB
08/13/98 0936 MAB
08/13/98 0940 MAB
08/13/98 0944 MAB
08/13/98 0948 MAB
08/13/98 1000 MAB
08/13/98 1004 MAB
08/13/98 1007 MAB
08/13/98 1012 MAB
08/13/98 1016 MAB
08/13/98 1020 MAB
08/13/98 1024 MAB
Inst
ICP2
ICP2
ICP2
ICP2
ICP2
ICP2
ICP2
ICP2
ICP2
ICP2
ICP2
ICP2
ICP2
ICP2
ICP2
ICP2
ICP2
ICP2
ICP2
ICP2
ICP7.
ICP2
ICP2
ICP2
ICP2
ICP2
ICP2
' . • •
Page 27
Q.C. Information for Batch# 40887 For Report Number :98135
Sample Batch Information
Analysis : pH
Preparation Preparation Analysis
Sample ID Tag Date Time By Notes Date Time By Inst
40887LCS I I 08/07/98 1530 NL
40887LCSD I I 08/07/98 1530 NL
40887CALCK I I 08/07/98 1530 NL
98135-2 I I 08/07/98 1530 NL
98136-1 I I 08/07/98 1530 NL
98140 I I 08/07/98 1530 NL
98133-1 I I 08/07/98 1530 NL
98133-2 I I 08/07/98 1530 NL
98133-3 I I 08/07/98 1530 NL
98124-1 I I 08/07/98 1530 NL
98124-2 I I 08/07/98 1530 NL
98124-3 I I 08/07/98 1530 NL
98124-3DUP I I 08/07/98 1530 NL
98155-2 I I 08/07/98 1530 NL
98155-3 I I 08/07/98 1530 NL
98155-4 I I 08/07/98 1530 NL
98155-5 I I 08/07/98 1530 NL
98155-6 I I 08/07/98 1530 NL
98155-7 I I 08/07/98 1530 NL
98155-8 I I 08/07/98 1530 NL
98155-9 I I 08/07/98 1530 NL
q8J.55-10 I I ()8/()7/98 1530 NL
98155-11 I I 08/07/98 1530 NL
98155-llDUP I I 08/07/98 1530 NL
98147 I I 08/07/98 1530 NL
,. . . • •
Page 28
Q.C. Information for Batch# 40934 For Report Number :98135
Sample Batch Information
Analysis : NH3-N
Preparation Preparation Analysis
Sample ID Tag Date Time By Notes Date Time By Inst
40934BLK 08/11/98 1310 BG 08/11/98 1555 BG GENES
40934LCS 08/11/98 1310 BG 08/11/98 1555 BG GENES
40934LCSD 08/11/98 1310 BG 08/11/98 1555 BG GENES
40934CAL 08/11/98 1310 BG 08/11/98 1555 BG GENES
98135-lMS 08/11/98 1310 BG 08/11/98 1555 BG GENES
98135-lMSD 08/11/98 1310 BG 08/11/98 1555 BG GENES
98167 08/11/98 1310 BG 08/11/98 1555 BG GENES
98168 08/11/98 1310 BG 08/11/98 1555 BG GENES
98170-1 08/11/98 1310 BG 08/11/98 1555 BG GENES
98170-2 08/11/98 1310 BG 08/11/98 1555 BG GENES
98028-1 08/11/98 1310 BG 08/11/98 1555 BG GENES
98028-lDUP 08/11/98 1310 BG 08/11/98 1555 BG GENES
98028-2 08/11/98 1310 BG 08/11/98 1555 BG GENES
98028-3 08/11/98 1310 BG 08/11/98 1555 BG GENES
98028-4 08/11/98 1310 BG 08/11/98 1555 BG GENES
98028-5 08/11/98 1310 BG 08/11/98 1555 BG GENES
98028-6 08/11/98 1310 BG 08/11/98 1555 BG GENES
98028-7 08/11/98 1310 BG 08/11/98 1555 BG GENES
98135-1 08/11/98 1310 BG 08/11/98 1555 BG GENES
98135-lDUP 08/11/98 1310 BG 08/11/98 1555 BG GENES
98084-10 08/11/98 1310 BG 08/11/98 1555 BG GENES
98078-2 08/11/98 1310 BG 0fl/11./98 1555 BG GENF.5
98078-16 08/11/98 1310 BG 08/11/98 1555 BG GENES
98094 08/11/98 1310 BG 08/11/98 1555 BG GENES
98084-7 08/11/98 1310 BG 08/11/98 1555 BG GENES
98078-5 08/11/98 1310 BG 08/11/98 1555 BG GENES
98078-13 08/11/98 1310 BG 08/11/98 1555 BG GENES
98170-3 08/11/98 1310 BG 08/11/98 1555 BG GENES
• •
Q.C. Information for Batch# 40945
Page 29
For Report Number :98135
Sample ID
40945BLK
40945LCS
:40945LCSD
98078-12
98078-15
98092-8
98092-8DUP
98092-9
98092-10
98092-11
98092-12
98092-13
98092-14
98092-15
98092-16
98092-17
98105-1
98105-2
98105-3
98105-4
98105-5
98105-'1
98105-7
98105-8
98094
98076
98108
98115-1
40945BLK2
40945LCSLOW
40945LCSDLOW
40945LCSCBOD
40945LCSDCBOD
98113
98116
98120-1
98122-2
98125
98126
98130
98160-1
98160-lDUP
98160-2
98160-3
98160-4
98160-5
98160-6
98156-5
Sample Batch Information
Analysis : BOD<5 hi, BOD<5 low
Preparation
Tag Date Time By
08/07/98 0730 JRG/PRR
08/07/98 0730 JRG/PRR
08/07/98 0730 JRG/PRR
08/07/98 0730 JRG/PRR
08/07/98 0730 JRG/PRR
08/07/98 0730 JRG/PRR
08/07/98 0730 JRG/PRR
08/07/98 0730 JRG/PRR
08/07/98 0730 JRG/PRR
08/07/98 0730 JRG/PRR
08/07/98 0730 JRG/PRR
08/07/98 0730 JRG/PRR
08/07/98 0730 JRG/PRR
08/07/98 0730 JRG/PRR
08/07/98 0730 JRG/PRR
08/07/98 0730 JRG/PRR
08/07/98 0850 JRG/PRR
08/07/98 0850 JRG/PRR
08/07/98 0850 JRG/PRR
08/07/98 0850 JRG/PRR
08/07/98 0850 JRG/PRR
08/07/98 085n JRG/PRR
08/07/98 0850 JRG/PRR
08/07/98 0850 JRG/PRR
08/07/98 0730 JRG/PRR
08/07/98 0730 JRG/PRR
08/07/98 0850 JRG/PRR
08/07/98 1245 JRG/PRR
08/07/98 0730 JRG/PRR
08/07/98 0730 JRG/PRR
08/07/98 0730 JRG/PRR
08/07/98 0730 JRG/PRR
08/07/98 0730 JRG/PRR
08/07/98 1245 JRG/PRR
08/07/98 1245 JRG/PRR
08/07/98 1245 JRG/PRR
08/07/98 1245 JRG/PRR
08/07/98 1245 JRG/PRR
08/07/98 1245 JRG/PRR
08/07/98 1245 JRG/PRR
08/07/98 1330 JRG/PRR
08/07/98 1330 JRG/PRR
08/07/98 1330 JRG/PRR
08/07/98 1330 JRG/PRR
08/07/98 1330 JRG/PRR
08/07/98 1330 JRG/PRR
08/07/98 1330 JRG/PRR
08/07/98 1330 JRG/PRR
Preparation
Notes
Analysis
Date Time By
08/12/98 0740 JRG/PRR
08/12/98 0740 JRG/PRR
08/12/98 0740 JRG/PRR
08/12/98 0740 JRG/PRR
08/12/98 0740 JRG/PRR
08/12/98 0740 JRG/PRR
08/12/98 0740 JRG/PRR
08/12/98 0740 JRG/PRR
08/12/98 0740 JRG/PRR
08/12/98 0740 JRG/PRR
08/12/98 0740 JRG/PRR
08/12/98 0740 JRG/PRR
08/12/98 0740 JRG/PRR
08/12/98 0740 JRG/PRR
08/12/98 0740 JRG/PRR
08/12/98 0740 JRG/PRR
08/12/98 0740 JRG/PRR
08/12/98 0740 JRG/PRR
08/12/98 0740 JRG/PRR
08/12/98 0740 JRG/PRR
08/12/98 0740 JRG/PRR
08/12/98 0740 JRG/PRR
08/12/98 0740 JRG/PRR
08/12/98 0740 JRG/PRR
08/12/98 0740 JRG/PRR
08/12/98 0740 JRG/PRR
08/12/98 0740 JRG/PRR
08/12/98 0740 JRG/PRR
08/12/98 0740 JRG/PRR
08/12/98 0740 JRG/PRR
08/12/98 0740 JRG/PRR
08/12/98 0740 JRG/PRR
08/12/98 0740 JRG/PRR
08/12/98 0740 JRG/PRR
08/12/98 0740 JRG/PRR
08/12/98 0740 JRG/PRR
08/12/98 0740 JRG/PRR
08/12/98 0740 JRG/PRR
08/12/98 0740 JRG/PRR
08/12/98 0740 JRG/PRR
08/12/98 0740 JRG/PRR
08/12/98 0740 JRG/P~R
08/12/98 0740 JRG/PRR
08/12/98 0740 JRG/PRR
08/12/98 0740 JRG/PRR
08/12/98 0740 JRG/PRR
08/12/98 0740 JRG/PRR
08/12/98 0740 JRG/PRR
Inst
..
Sample ID
98135-1
98142
98143-1
98143-2
98143-3
98143-4
98143-5
98143-6
98143-7
98143-8
40945BLK3
98143-9
98143-10
98143-11
98143-12
98145-1
98152
98158-1
98158-2
98140
98136-2
98112
98113
• •
Q.C. Information for Batch# 40945
Page 30
For Report Number :98135
Sample Batch Information
Analysis : BOD<5 hi, BOD<5 low
Preparation
Tag Date Time By
Preparation
Notes
08/07/98 1615 JRG/PRR
08/07/98 1615 JRG/PRR
08/07/98 1615 JRG/PRR
08/07/98 1615 JRG/PRR
08/07/98 1615 JRG/PRR
08/07/98 1615 JRG/PRR
08/07/98 1615 JRG/PRR
08/07/98 1615 JRG/PRR
08/07/98 1615 JRG/PRR
08/07/98 1615 JRG/PRR
08/07/98 0730 JRG/PRR
08/07/98 1615 JRG/PRR
08/07/98 1615 JRG/PRR
08/07/98 1615 JRG/PRR
08/07/98 1615 JRG/PRR
08/07/98 1720 JRG/PRR
08/07/98 1750 JRG/PRR
08/07/98 1750 JRG/PRR
08/07/98 1750 JRG/PRR
08/07/98 1750 JRG/PRR
08/07/98 1750 JRG/PRR
08/07/98 1750 JRG/PRR
08/07/98 1245 JRG/PRR CBOD
Analysis
Date Time By
08/12/98 0740 JRG/PRR
08/12/98 0740 JRG/PRR
08/12/98 0740 JRG/PRR
08/12/98 0740 JRG/PRR
08/12/98 0740 JRG/PRR
08/12/98 0740 JRG/PRR
08/12/98 0740 JRG/PRR
08/12/98 0740 JRG/PRR
08/12/98 0740 JRG/PRR
08/12/98 0740 JRG/PRR
08/12/98 0740 JRG/PRR
08/12/98 0740 JRG/PRR
08/12/98 0740 JRG/PRR
08/12/98 0740 JRG/PRR
08/12/98 .0740 JRG/PRR
08/12/98 0740 JRG/PRR
08/12/98 0740 JRG/PRR
08/12/98 0740 JRG/PRR
08/12/98 0740 JRG/PRR
08/12/98 0740 JRG/PRR
08/12/98 0740 JRG/PRR
0 8 _/12 / 9 8 0 74 0 ,JRG/PRR
08/12/98 0740 JRG/PRR
Inst
Sample ID
40950BLK
40950LCS
40950LCSD
98051-2
98136-1
98104-2
98097-2
98153-2
98122-1
98169-2
98169-2MS
98052-2
98120-2
98135-2
•
Q.C. Information for Batch# 40950
Page 31
For Report Number :98135
Sample Batch Information
Analysis : 0/G
Preparation Preparation Analysis
Tag Date Time By Notes Date Time By
I I 08/11/98 1000 CB/KC
I I 08/11/98 1000 CB/KC I I 08/11/98 1000 CB/KC
I I 08/11/98 1000 CB/KC
I I 08/11/98 1000 CB/KC
I I 08/11/98 1000 CB/KC
I I 08/11/98 1000 CB/KC
I I 08/11/98 1000 CB/KC
I I 08/11/98 1000 CB/KC
I I 08/11/98 1000 CB/KC
I I 08/11/98 1000 CB/KC
I I 08/11/98 1600 CB/KC
I I 08/11/98 1600 CB/KC
I I 08/11/98 1600 CB/KC
Inst
...
Sample ID
40958BLK
40958LCS
40958LCSD
98135-lMS
98135-lMSD
98068
98071
98072
98079-1
98136-2
98156-5
98160-1
98160-2
98160-3
98160-4
98113
98116
98120-1
98125
98130
98135-1
98144-1
98153-1
98158-1
98158-2
98079-lDUP
98153-lDUP
• •
Q.C. Information for Batch# 40958
Page 32
For Report Number :98135
Sample Batch Information
Analysis : TSS
Preparation
Tag Date Time By
Preparation
Notes
I I
I I
I I
I I
I I
I I
I I
I I
I I
I I
I I
I I
I I
I I
I I
I I
I I
I I
I I
I I
I I I I
I I
I I
I I
I I
I I
Analysis
Date Time By
08/11/98 0800 JLP
08/11/98 0800 JLP
08/11/98 0800 JLP
08/11/98 0800 JLP
08/11/98 0800 JLP
08/11/98 0800 JLP
08/11/98 0800 JLP
08/11/98 0800 JLP
08/11/98 0800 JLP
08/11/98 0800 JLP
08/11/98 0800 JLP
08/11/98 0800 JLP
08/11/98 0800 JLP
08/11/98 0800 JLP
08/11/98 0800 JLP
08/11/98 0800 JLP
08/11/98 0800 JLP
08/11/98 0800 JLP
08/11/98 0800 JLP
08/11/98 0800 JLP
08/11/98 0800 JLP
08/11/98 0800 ,TT,P
08/11/98 0800 JLP
08/11/98 0800 JLP
08/11/98 0800 JLP
08/11/98 0800 JLP
08/11/98 0800 JLP
Inst
•, , .. • .,
Page 33 Q.C. Information for Batch# 41016 For Report Number :98135
Sample Batch Information
Analysis : CN
Preparation Preparation Analysis Sample ID Tag Date Time By Notes Date Time By Inst
41016BLK 08/14/98 1130 PRR 08/14/98 1545 PRR GEN 41016LCS 08/14/98 1130 PRR 08/14/98 1545 PRR GEN 41016LCSD 08/14/98 1130 PRR 08/14/98 1545 PRR GEN 98135-2MS 08/14/98 1130 PRR 08/14/98 1545 PRR GEN 98135-2MSD 08/14/98 1130 PRR 08/14/98 1545 PRR GEN 98135-2 08/14/98 1130 PRR 08/14/98 1545 PRR GEN 98135-2DUP 08/14/98 1130 PRR 08/14/98 1545 PRR GEN 98081-1 08/14/98 1130 PRR 08/14/98 1545 PRR GEN 98017 08/14/98 1130 PRR 08/14/98 1545 PRR GEN 98029-1 08/14/98 1550 PRR 08/14/98 1650 PRR GEN 41016CAL5 08/14/98 1550 PRR 08/14/98 1650 PRR GEN 41016CAL15 08/14/98 1550 PRR 08/14/98 1650 PRR GEN 98100-2 08/14/98 1550 PRR AMENABLE 08/14/98 1650 PRR GEN 98100-2DUP 08/14/98 1550 PRR AMENABLE 08/14/98 1650 PRR GEN 98029-2 08/14/98 1550 PRR 08/14/98 1650 PRR GEN 98029-3 08/14/98 1550 PRR 08/14/98 1650 PRR GEN 98029-4 08/14/98 1550 PRR 08/14/98 1650 PRR GEN 98029-5 08/14/98 1550 PRR 08/14/98 1650 PRR GEN 98044-8RR 08/14/98 1700 PRR 08/14/98 2050 PRR GEN 98060-lRR 08/14/98 1700 PRR 08/14/98 2050 PRR GEN 98193-13RR 08/14/98 1700 PRR 08/14/98 2050 PRR GEN 98134-6RR OR/14/913 170() PRR 08/14/98 2050 PRR GEN 98134-7RR 08/14/98 1700 PRR 08/14/98 2050 PRR GEN 98134-lORR 08/14/98 1700 PRR 08/14/98 2050 PRR GEN 98106-2 08/14/98 1700 PRR 08/14/98 2050 PRR GEN 98106-3 08/14/98 1700 PRR 08/14/98 2050 PRR GEN 98106-4 08/14/98 1700 PRR 08/14/98 2050 PRR GEN 98136-1 08/14/98 2115 PRR 08/14/98 2230 PRR GEN 98190 08/14/98 2115 PRR 08/14/98 2230 PRR GEN
,><$ I r,"' ~ ~Si¾ q~ \_?,S
CRA SHIPPED 10 (Laboratory Name): f\\,,.S\, \y\---L~\ ,5,~v\A( • .Qc:, .Tv--Q . • . t
11 (2, 7 e.cV\"'-f. \05::, v'tv\Lw~ , N.r,vc:v6 $-s (;,1,1i ! CONESTOGA-ROVERS & ASSOCIATES, INC. "Jcl'D92. 1351 Oakbrook Drive Suite 150 REFERENCE NUMBER: PROJECT NAME: '· . Norcross, GA 30093 404-441-0027 . .
CHAIN OF CUSTODY RECORD 3GE-°\ pJ.co -~las.
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SEQ; IATE
SAMPLE zz f:!J <:i..v u '6 < .E' l'."' TIME SAMPLE NUMBER 0
NO. TYPE 0
' 8/6/90 1330 lllr36t.ct Yvse.-nP.Oo"<B-f0'.1 rL_ ~ l '> ~ / \).. ~L _,,,tq, \
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RELIN~HE~t,:,.e /J j -y---DATE: 8 It 1'18 RECEIVED BY: Cc;_ Vk.JC. DATE: QI 1-. J 9 'tJ
(i) ·,A,,:, >t1~ TIME: /S'30 (2) TIME: '1530
R:l./l"OUISHED BY: p' DATE: RECEIVED BY: DATE:
® TIME: @ TIME:
RELINQUISHED BY: DATE: RECEIVED BY: DATE:
@ TIME: © TIME:
METHOD OF SHIPMENT: F<i.:D0C AIR BILL NUMBER: 8 Cl 03 '3+<t'f'\ n ...,.q ..
"TEAM· RECEIVED FOR LABORAlOAY BY: \ -' .f'IJ; White . Fully Executed Copy SAMP\ !V\LcV'CL.a\ ~-CvJ2 Yellow . Receiving Laboratory Copy i' ,-, _g. "" .,f-1~ A-1·c.-011"-"i JO -□512 ·
Pink . Sampler Copy 'I• \I\ 11 ~-
Goldenrod . Chemist Copy DATE: I'\· "'X TIME: 6( D)
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1007(FORMS) -DEC 6, 93 -REV.D -(AF-01) 0 () tJ"'._ _::;:>,....., ~--...L
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CRA
1351 Oakbrook Drive
Suite #150
Norcross, Georgia 30093
[phone]
TO: Jeanne Chew
• •
MEMO
REFERENCE NO: 3669
FROM: Robert Brachowski/rb/36 DATE: August 21, 1998
RE: Data Quality Assessment and Validation for Three Water Samples
Collected from the Jadco-Hughes Site in Belmont, North Carolina
(Lot # 97566 and 97835)
The following details a data quality assessment and validation for results generated by
Analytical Services, Inc. (ASI) of Norcross, Georgia for three water samples collected from the
above-referenced Site. Sample collection was conducted on July 22 and 30, 1998. The samples
were selectively analyzed for volatile organic compounds (VOCs), base-neutral and acid
extractable organic compounds (BNA), polychlorinated biphenyls (PCBs), cyanide, oil and
grease (O&G), pH, target analyte list (TAL) metals, total suspended solids (TSS), biological
oxygen demand (BOD), and ammonia. The quality assurance criteria were established by the
associated quality assurance project plan and the analytical methods1. The samples are
identified in Table l. The analytical methodologies are listed in Table 2.
Holding Time Periods
The holding time periods are presented in Table 3. The pH parameter should be analyzed for
in the field immediately after sampling; therefore, the pH analysis was performed outside the
allowable holding time period and the data for sample W-3669-MC-072298-098 should be
qualified as estimated U) for this parameter. On the basis of the sample collection and analysis
dates referenced on the chain-of-custody forms and the analytical reports provided by ASI, the
remainder of the extractions and analyses were performed within the required holding time
periods.
Method Blank Samples
Contamination of samples contributed by laboratory conditions or procedures was monitored
by the concurrent preparation and analysis of method blank samples. The method blank
samples were free from target analytes above the detection limits indicating that no significant
laboratory contamination occurred.
1 Application of quality assurance criteria was consistent with "National Functional Guidelines for
Organic Data Review," revised February 1994 and "National Functional Guidelines for Inorganic Data
Review," revised February 1994.
A-/sD ..
.... • •
June 30, 1998 Reference No. 3669
-2-
Surrogate Compound Percent Recoveries (Surrogate Recoveries)
Individual sample performance for the VOC, BNA, and PCB parameters were monitored by
surrogate recoveries. The surrogate recoveries were within the control limits for the reported
analyses.
Matrix Spike/Matrix Spike Duplicate (MS/MSD) Percent Recoveries
To assess the long term accuracy and precision of the analytical method on various matrices,
MS/MSD percent recoveries and the RPO of the recoveries are determined. The TAL metals
MS/MSD percent recovery data for selenium were outside the control limits; therefore, the
quantitation limits for sample W-3669-MC-072298-099 should be qualified as estimated (UJ) for
this analyte. Some other MS/MSD percent recoveries and RPO data were outside the control
limits; however, no sample qualification was required. The remainder of the MS/MSD percent
recovery and RPO data were within the control limits indicating an adequate level of accuracy
and precision was achieved.
Laboratm:y Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD) Results
AS! provides and analyzes LCS/LCSD in order to further assess the method accuracy and
precision. The LCS/LCSD data were within the control limits indicating the method achieved
an adequate level of accuracy and precision.
Laboratory Duplicate Analyses
To monitor the precision of the laboratory analytical methods, laboratory duplicate samples
were analyzed for select methods. The laboratory duplicate RPO data were within the control
limits indicating an adequate level of precision was achieved for these select methods.
Trip Blank Analysis
Potential VOC cross-contamination by diffusion of target compounds through the septum seal
of the sample vial into the investigative samples during shipment and storage was monitored
by means of a trip blank sample. The trip blank sample was free from detectable concentrations
of target analytes indicating that no significant cross-contamination occurred.
Overall Assessment
Violation of holding time and MS/MSD criteria resulted in sample qualification as noted in the
previous text and following tables. The remainder of the data was found to exhibit acceptable
levels of accuracy and precision and may used without qualification.
I.•
3669-M-36-Tl
• •
TABLE!
SUMMARY OF THE SAMPLE IDENTIFICATION NUMBERS
ASSOCIATED WITH THE SAMPLES COLLECTED FROM THE
JADCO-HUGHES SITE IN
BELMONT, NORTH CAROLINA
W-3669-MC-072298-098
W-3669-MC-072298-099
W-3669-MC-073098-100
• •
TABLE2
ANALYTICAL METHODS ASSOCIATED WITH THE
SAMPLES COLLECTED FROM THE JADCO-HUGHES SITE IN
BELMONT, NORTH CAROLINA
Parameters Methods
voe MCAWW 1 624
BNA MCAWW 625
PCB MCAWW 608
Cyanide MCAWW 335.2
pH MCAWW 150.1
TALMetals MCAWW 200 (series)
TSS MCAWW 160.2
BOD SM' 5210 B
Ammonia MCAWW 350.2
Oil and Grease HEMJ 1664
Notes:
1 "Methods for Chemical Analysis of Water and Wastes," EPA 600/4-79-020, revised March 1983.
2 "Standard Methods for the Examination of Water and Wastewater," APHA, 16th edition, 1985.
3"'N-Hexane Extractable Material and Silica Gel Treated N-Hexane Extractable Material by Extraction and
Gravimetry," EPA-821-B-94-004, January 1995.
3669-M-36,.TI
• •
TABLE3
HOLDING TIME PERIODS ASSOCIATED WITH THE SAMPLES
COLLECTED FROM THE JADCO-HUGHES SITE IN
BELMONT, NORTH CAROLINA
Parameters
VOC, Cyanide
BNA,PCB
pH
TAL Metals
(excluding mercury)
Holding Time Periods
-14 days from sample collection to completion of analysis
- 7 days from sample collection to extraction
-40 days from extraction to completion of analysis
-Analyze as soon as possible
- 6 months from sample collection to completion of analysis
Mercury, Oil and Grease, -28 days from sample collection to completion of analysis
Ammonia
BOD -48 hours from sample collection to beginning of analysis
TSS - 7 days from sample collection to completion of analysis
3669-M-J&-n
.. • •
ASI ANALYTICAL SERVICES, INC.
ENVIRONMENTAL MONITORING & LABORATORY ANALYSIS
110 TECHNOLOGY PARKWAY• NORCROSS, GA 30092
[phone] • FAX [phone]
Rec'd CRA
AUG i 5 1996
19 August 98
Case Narrative ASI Sample #97835
This sample was collected on 30 July 98 and arrived at ASI on 31
July 98. All conditions for proper preservation and shipment were met.
The sample was logged into LIMS as ASI sample #97835 for VOA analysis
of carbon disulfide.
VOC analysis in water for carbon disulfide was analyzed in batch
#40827 using EPA method 624. Measurement quality objectives were met
and analysis was unexceptional.
Respectfully yours,
Jon Neuhaus
Quality Assurance
A Unit of American Analvtical Services, Inc.
• •
ASI ANALYTICAL SERVICES, INC.
ENVIRONMENTAL MONITORING & LABORATORY ANALYSIS
110 TECHNOLOGY PARKWAY• NORCROSS, GA 30092
[phone] • FAX [phone]
Conestoga-Rovers
1351 Oakbrook Drive
Suite 150
Norcross, GA 30093
LABORATORY REPORT
Attention: Mr. Rob Brachowski
Sample Description
August 19, 1998
Report No. 97835
Water, grab, Jadco-Hughes, Project #3669, W-3669-MC-073098-100, 07/30/98,
14:35, received 07/31/98
RESULTS
Volatile Organics (EPA 624)
Carbon disulfide ............................ .
BDL -Below Defection Limit
North Carolina Laboratory I.D. No. 381
Result
(ug/1)
BDL
Detection
Limit
(ug/1)
2
Respectfully submitted,
¥:ow~ -~~tr
A Unit of American Analytical Services, Inc.
• •
Page 1
Analytical Services Inc. Batch QC
For Report Number :97835
Volatile Organics
Matrix : Aqueous Batch # 40827 Method : EPA 624
,ab Control Information LC LCD LC %Recovery RPD
Analyte %Rec %Rec RPD Range Range
lenzene 82 89 8 37 -151 0 -20
lromodichloromethane 92 102 11 35 -155 0 -20
3romoform 89 99 11 45 -169 0 -20
lromome thane 75 78 4 D -242 0 -20
:arbon tetrachloride 81 87 7 70 -140 0 -20
:hlorobenzene 133 113 16 37 -160 0 -20
:hloroethane 191 222 15 14 -230 0 -20
J-Chloroethylvinyl ether 14 16 9 D -305 0 -20
:hloroform 87 94 7 51 -138 0 -20
:hloromethane 67 72 7 D -273 0 -20
Jibromochloromethane 90 102 13 53 -149 0 -20
L,2-Dichlorobenzene 157 131 18 18 -190 0 -20
L,3-Dichlorobenzene 103 109 6 59 -156 0 -20
L,4-Dichlorobenzene 114 109 4 18 -190 0 -20
L,1-Dichloroethane 78 85 8 59 -155 0 -20
L,2-Dichloroethane 85 94 10 49 -155 0 -20
L,1-Dichloroethene 71 76 6 D -234 0 -20
:rans-1,2-Dichloroethene 78 .82 4 54 -156 0 -20
L,2-Dichloropropane 86 96 11 D 210 0 20
~is-1,3-Dichloropropene 88 98 10 D 227 0 .. 20
:rans-1,3-Dichloropropene 87 101 14 17 -183 0 -20 ·
~thylbenzene 92 100 8 37 -162 0 -20
~ethylene chloride 80 86 7 D -221 0 -20
1,1,2,2-Tetrachloroethane 95 105 10 46 -157 0 -20
retrachloroethene 92 102 10 64 -148 0 -20
roluene 88 96 9 47 -150 0 -20
1,1,1-Trichloroethane 82 89 8 52 -162 0 -20
1,1,2-Trichloroethane. 96 107 10 52 -150 0 -20
Trichloroethene 98 96 2 71 -157 0 -20
Trichlorofluoromethane 76 80 5 17 -181 .0 -20
Vinyl chloride 69 72 5 D -251 0 -20
• •
Page 2
Analytical Services Inc. Batch QC
Volatile Organics
Matrix : Aqueous Batch # 40827 Method : EPA 624
,atrix Spike Information MS MSD MS %Recovery RPD
Analyte %Rec %Rec RPD Range Range
,enzene 101 100 1 37 -151 0 -20
,romodichloromethane 107 107 0 35 -155 0 -20
,romoform 102 104 1 45 -169 0 -20
.romomethane 107 119 11 D -242 0 -20
:arbon tetrachloride 108 105 3 70 -140 0 -20
:hlorobenzene 141 89 45 37 -160 0 -20
:hloroethane 105 257 84 14 -230 0 -20
.-Chloroethylvinyl ether 7 76 166 D -305 0 -20
:hloroform 105 103 2 51 -138 0 -20
:hloromethane 95 91 5 D -273 0 -20
Jibromochloromethane 105 104 1 53 -149 0 -20
., 2-Dichlorobenzene 108 78 32 18 -190 0 -20
.,3-Dichlorobenzene 113 115 2 59 -156 0 -20
.,4-Dichlorobenzene 106 100 6 18 -190 0 -20
.,1-Dichloroethane 106 101 5 59 -155 0 -20
.,2-Dichloroethane 105 102 2 49 -155 0 -20
.,1-Dichloroethene 102 97 5 D -234 0 -20
:rans-1,2-Dichloroethene 103 103 1 54 -156 0 -20
.,2-Dichloropropane 102 103 0 D -210 0 -20
:is-1,3-Dichloropropene 105 105 0 D -227 0 -20
:rans-1,3-Dichloropropene 104 105 1 17 -183 0 -20
ithylbenzene 103 102 1 37 162 0 20
lethylene chloride 105 104 2 D -221 0 -20
.,1,2,2-Tetrachloroethane 107 109 1 46 -157 0 -20
~etrachloroethene 98 100 2 64 -148 0 -20
~oluene 100 99 1 47 -150 0 -20
,,1,1-Trichloroethane 107 105 2 52 -162 0 -20
:,1,2-Trichloroethane 109 109 0 52 -150 0 -20
rrichloroethene 116 103 12 71 -157 0 -20
rrichlorofluoromethane 109 106 3 17 -181 0 -20
Tinyl chloride 100 99 1 D -251 0 -20
• •
Page 3
Analytical Services Inc. Batch QC
Surrogate Recovery
Volatile Organics
Matrix Aqueous Batch# 40827 Method EPA 624
% Recovery Objectives
Sl 1,2-Dichloroethane-d4 76 -119
S2 Toluene-dB 88 -110
S3 Ethylbenzene-dl0 75 -115
S4 4-Bromofluorobenzene 86 -115
Sample File Sl S2 S3 S4 S5 S6
40827BLK B7581 105 99 113 95
40827LCS B7610 103 101 114 101
40827LCSD B7611 103 103 113 102
40827BLK2 B7612 106 101 115 97
97835 B7608 104 100 115 94
97835DUP B7609 107 100 113 93
97890-5 B7613 102 98 88 135
AANote: MATRIX EFFECT
97890"0 5DMS B7626 103 102 114 · 103
AANote: DF=l00
97890-5DMSD B7614 102 101 114 102
.......... Note: DF=l00
97890-5D B7616 112 101 112 97
AANote: DF=50
97890-5D2 B7615 90 99. 113 93
AANote: DF=l00
97731-1 B7619 108 101 113 99
97809-1 B7621 107 102 113 96
97904 B7620 106 101 111 97
97807-2 B7622 139 102 107 101
97807-3 B7623 113 101 112 97
97807-4 B7624 116 101 110 97
97807-5 B7625 130 102 106 98
97890-5D3 B7640 112 99 92 96
AANote: DF=200
97809-lDUP B7656 106 100 93 93
97731-lDUP B7655 106 100 94 96
97708-4 B7617 108 100 110 92
97708-5 B7618 115 100 109 94
98046 A5394 108 105 107 102
97807-2DUP A5384 106 104 107 103
• •
Q.C. Information for Batch# 40827
Page 5
Printed: 08/19/98 17:23:39
Analyte
Carbon disulfide
Blank Results Information
Volatile Organics Method: EPA 624
Blank
Result
BDL
Detection
Limit
2
• • •
Page 6
Q.C. Information for Batch# 40827 Printed: 08/19/98 17:23:39
Sample Batch Information
Volatile Organics Method EPA 624
Preparation Preparation Analysis
oimple ID Date Time By Notes Date Time By Inst #
0827BLK I I 08/05/98 0941 RFA VOA2
0827LCS I I 08/05/98 2147 RFA VOA2
0827LCSD I I 08/05/98 2211 RFA VOA2
0827BLK2 I I 08/05/98 2234 RFA VOA2
7835 I I 08/05/98 2026 RFA VOA2
7835DUP I I 08/05/98 2049 RFA VOA2
7890-5 I I 08/05/98 2113 RFA VOA2
7890-5DMS I I 08/05/98 2258 RFA VOA2
7890-5DMSD I I 08/05/98 2321 RFA VOA2
7890-5D I I 08/06/98 0008 RFA VOA2
7890-5D2 I I 08/05/98 2344 RFA VOA2
7731-1 I I 08/06/98 0119 RFA VOA2
7809-1 I I 08/06/98 0206 RFA VOA2
7904 I I 08/06/98 0142 RFA VOA2
7807-2 I I 08/06/98 0230 RFA VOA2
7807-3 I I 08/06/98 0253 RFA VOA2
7807-4 I I 08/06/98 0317 RFA VOA2
7807-5 I I 08/06/98 0340 RFA VOA2
7890-5D3 I I 08/06/98 1721 RFA VOA2
7809-lDUP I I 08/06/98 2338 LLP VOA2
8046 I I 08/08/98 1336 RFA VOAl
7731-lDUP ' ! 08/06/98 2315 RFA VOA2 ,' I
7708-4 I I 08/06/98 0032 RFA VOA2
7708-5 I I 08/06/98 0055 RFA VOA2
7807-2DUP I I 08/07/98 2155 LLP VOAl
·7807-5DUP I I 08/07/98 2222 LLP VOAl
•7927 I I 08/12/98 0117 LLP VOAl
•7984 I I 08/12/98 0237 LLP VOAl
17963 I I 08/12/98 0210 LLP VOAl
•8106-4 I I 08/12/98 1239 LLP VOAl
>8106-3 I I 08/12/98 1212 LLP VOAl
18009 I I 08/12/98 1305 LLP. VOAl
18175 I I 08/12/98 1331 LLP VOAl
1B009D I I 08/12/98 1627 LLP VOAl
J8175DUP I I 08/12/98 1654 LLP VOAl
l7927DUP I I 08/12/98 1504 LLP VOAl
l7963-2DUP I I 08/12/98 1530 LLP VOAl
l7984DUP I I 08/12/98 1557 LLP VOAl
-
CAA SHIPPED TO (Laboratory Name): A \l\u, \'f he"'\ 5,~..,,_,, c-O.:S ·"J:"""v,.C',
CONESTOGA-ROVERS & ASSOCIATES, INC. 110 T.ec\-\..-..('lcJj'S ~k.,o.y ,f,..{0 ,c,o$s. t;i4-3od'12.
1351 Oakbrook Drive Suite 150
Norcross, GA 30093 404-441-0027 REFERENCE NUMBER: PROJECT NAME:
CHAIN OF CUSTODY RECORD ;;66°1 ~co lfus!.a ~~ °17'9-.~'S
•
r .
/~~ U) i151/ I/Ill// PRINTED yn l c.h>-{ Ntlf"l;--Z.. a:
SAMPLER'S 'VI k,e/ ¢:;' C ... w
SIGNATURE: II LC • V!.11. Ol!, REMARKS NAME: d~
SEO. SAMPLE zz
DATE TIME SAMPLE NUM8ER 0
NO. TYPE u
I ti ?l:J/<;8 llJ.35""' Lu -366'1 · YJ,\C-Ot 3[JC7 /!l -/OU Jk.._.. 3 Ix ·T,J .. ),.,,,J a -tJ;::. , , DO LJ q "-
l f:'loc..u l?c,._le ()1-<,,..,.\J _,: 20 ~ """ .,.....
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V
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I
I
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~
I
I • TOTAL NUMBER OF CONTAINERS .3
RELIN,2~0 B-S,_,,? / • ~ DATE: 7 / ?,J/Q ':I REClEIVED BY: Ff!X.x DATE:~ I :,u/'t iJ
<D ,/A,/ -,/ TIME: /630 ® TIME: /6'30
REL)"'OUISHED BY: DATE: RECEIVED BY: DATE: 7/31 }'-1~
® TIME: @ TIMEl"A \ C
RELINQUISHED BY: DATE: RECEIVED BY: DATE:
@ TIME: © TIME:
METHOD OF SHIPMEN'!: K~X AIR BILL NUMBER: 80 I 4te 5t"?i'2£ -
White . Fully Executed Copy SAMPLE TEAM ~cva ( . ·-:;__~D ~rR ~ '\.'\; \R~'\ ~ ('\ . -·
Yellow Receiving Laboratory Copy M\.c -, {) • . \ . l 1, N2 0515· .
Pink . Sampler Copy ~rE: .-, \ s.~ (\ '{ TIME: f'h'1~<:=:::, Goldenrod . Chemist Copy .
,nm,~m•M~I -nH: I\ 93 -REV.D -(AF-01)
ASI
7 August. 1998
•
ANALYTICAL SERVICES, INC.
ENVIRONMENT AL MONITORING & LABORATORY ANALYSIS
l lOTECHNOLOGY PARKWAY• NORCROSS, GA 30092
[phone] • FAX [phone]
CHE:Cf··:r:J /c.(:,A/NST
PRCL.i;, .. ~:f·J/,Sl'( D/\TA
8ato 'c /17: NV:
Case Narrative AS! Sample #97566
These aqueous sample were collected on 22 July. 1998 and anived at ASI on 23 July. 1998.
All conditions for proper preservation· and shipment were met. The samples were logged into
LIMS as AS! sample #97566 for determination of VOA. 13NA. PCB. Cyanide. oil & grease.
pH. metals. TSS. 8OD5. and ammonia. A trip blank accompanied the samples.
PCB were analyzed in batch #40096 using EPA Method 608. All measurement quality
objectives were met and the analysis was unexceptional.
BNA extractablcs were analyzed in batch #40102 for the acids and batch# 40103 for
the BN using EPA Method 625. All measurement quality objectives were met and the analysis
was unexceptional.
VOC were analyzed in batch #40126 using EPA Method 624. Recovery of
chloroethane in the batch MS/MSD was high, otherwise measurement quality objectives were
met.
Mercury was analyzed in batch #39295 using EPA Method 245.1. The analysis was
unexceptional.
ICP metals were analyzed in batch #40248 using EPA Method 200.7. PDS recoveries
of Fe and Na were slightly low and high. respectively. Otherwise measurement quality
objectives were met.
GFAA metals were analyzed in batch #40242 using EPA Method 270.2 for selenium
and 279.2 for thallium. MS/MSD recoveries were slightly low. and high, respectively.
Otherwise measurement quality objectives were met.
'' • •
BOD5 was analyzed in batch #40421 using SMt8 5210 B. Ammonia was analyzed in
batch #40481 using EPA Method 350.2. pH was analyzed in batch #40483 using EPA Method
150.1. TSS was analyzed in batch #40486 using EPA Method 160.2. Cyanide was analyzed
in batch #40501 using EPA Method 335.2. Oil & Grease was analyzed in batch #40508 using
EPA Method 1664. All measurement quality objectives were met and the analyses were
unexceptional.
Respectfully yours:
j)/4
Roy-Keith Smith. PhD
AMM. QAM. OTD
2
. ) '' • •
ASI ANALYTICAL SERVICES, INC.
ENVIRONMENTAL MONITORING & LABORATORY ANALYSIS
110 TECHNOLOGY PARKWAY • NORCROSS, GA 30092
[phone] • FAX [phone]
Conestoga-Rovers
1351 Oakbrook Drive
Suite 150
Norcross, GA 30093
LABORATORY REPORT
Attention: Mr. Rob Brachowski
Sample Description
August 7, 1998
Report No. 97566-1
Wastewater, composite, Jadco-Hughes, Project #3669, W-3669-MC-072298-099,
07/22/98, 13:30, received 07/23/98
RESULTS
Biochemical Oxygen Demand (BOD,) (rng/1)
ISM 5210 B) ............................ .
Ammonia Nitrogen \NJ \mg/1) iEPA 3:ill.2) ....... .
Total Suspended Solids (mg/1) (EPA 160.2) .... .
Target Analyte List -Metals
Metals
Total Aluminum (Al) (EPA 200. 7) .............. .
Total Antimony (Sb) (EPA 200. 7) .............. .
Total Arsenic (As) (EPA 200: 7) ............... .
Total Barium {Ba) (EPA 200. 7) ................ .
Total Beryllium (Be) (EPA 200. 7) ............. .
Total Cadmium (Cd) (EPA 200. 7) ............... .
Total Calcium (Ca) (EPA 200. 7) ............... .
Total Chromium (Cr) (EPA 200. 7) .............. .'
Total Cobalt (Co) (EPA 200. 7) ................ .
Total Copper (Cu) (EPA 200. 7) ................ .
Total Iron (Fe) (EPA 200. 7) .................. .
Total Lead (Pb) (EPA 239.2) .................. .
BDL -Below Detection Limit
Result
BDL
BDL
BDL
(mg/1)
BDL
BDL
BDL
0.06
BDL
BDL
43
BDL
BDL
BDL
BDL
BDL
A I !nit nf Amori,:::,n An::,h,tir:::il ~oruir:oc:; lnr:.
Detection
Limit
5
0.1
5
(mg/1)
0.2
0.05
0.01
0.01
0.001
0.005
0.05
0.01
0.05
0.02
0.1
0.003
"
Conestoga-Rovers
Page 2 of 2
• •
August 7, 1998
Report No. 97566-1
Wastewater, composite, Jadco-Hughes, Project #3669, W-3669-MC-072298-099,
07/22/98, 13:30, received 07/23/98
RESULTS
Metals
Total Magnesium (Mg) (EPA 200. 7) ............. .
Total Manganese (Mn) (EPA 200. 7) ............. .
Total Mercury (Hg) (EPA 245 .1) ............... .
Total Nickel (Ni) (EPA 200.7) ................ .
Total Potassium (K) (EPA 200. 7) .............. .
Total Selenium (Se) (EPA 270.2) .............. .
Total Silver (Ag) (EPA 200. 7) ................ .
Total Sodium (Na) (EPA 200.7)., .............. .
Total Thallium (Tl) (EPA 279.2) .............. .
Total Vanadium (V) (EPA 200.7) ............... .
Total Zinc (Zn) (EPA 200. 7) .................. .
BDL -Below Detection Limit
North Carolina Laboratory I.D. No. 381
Result
(mg/1)
12
0.12
BDL
BDL
3.3
BDL
BDL
12
BDL
BDL
0.08
Detection
Limit
(mg/1)
0.05
0.015
0.0002
0.02
0.2
0.005
0.01
0.05
0.002
0.02
0.02
, ' '' • •
ASI ANALYTICAL SERVICES, INC.
ENVIRONMENTAL MONITORING & LABORATORY ANALYSIS
110 TECHNOLOGY PARKWAY • NORCROSS, GA 30092
[phone] • FAX [phone]
Conestoga-Rovers
1351 Oakbrook Drive
Suite 150
Norcross, GA 30093
LABORATORY REPORT
Attention: Mr. Rob Brachowski
Sample Description
August 7, 1998
Report No. 97566-2
Wastewater, grab, Jadco-Hughes, Project #3669, W-3669-MC-072298-098,
07/22/98, 13:00, received 07/23/98
RESULTS
Detection
Result Limit
pH (laboratory) (EPA 150 .1) .................. . 7.87
Total Cyanide (CN) (mg/1) (EPA 335. 2) ......... . BDL 0.01
Oil and Grease (mg/lJ (EPA 1664J ............. . BDL 6
Volatile Organics (EPA 624) (ug/1) (ug/1)
Acetone ..................................... . BDL 100
Benzene ..................................... . BDL 2
Bromodichloromethane ........................ . BDL 10
Bromoform ................................... . BDL 10
Bromomethane ................................ . BDL 10
2-Butanone .................................. . BDL 100
Carbon disulfide ........................ · .... . 40 5
Carbon tetrachloride ...... : ................. . BDL 2
Chlorobenzene ............................... . BDL 10
Chloroethane ................................ . BDL 5
Chloroform .................................. . 72 2
Chloromethane ............................... . BDL 10
Dibromochloromethane ........................ . BDL 10
1, 1-Dichloroethane .......................... . BDL 2
1,2-Dichloroethane .......................... . 98 2
1,1-Dichloroethene .......................... . BDL 2
1,2-Dichloroethene (total) .................. . 59 2
BDL -Below Detection Limit
A I lnit nf AmPrir.~n An:=ilvtir,:=il Services. Inc.
''
Conestoga-Rovers
Page 2 of 4
• •
August 7, 1998
Report No. 97566-2
Wastewater, grab, Jadco-Hughes, Project #3669, W-3669-MC-072298-098,
07/22/9B, 13:00, received 07/23/9B
RESULTS
Detection
Result Limit
Volatile Organics (EPA 624) (ug/1) (ug/1)
1,2-Dichloropropane ......................... . BDL 2
cis-1,3-Dichloropropene ..................... . BDL 2
trans-1,3-Dichloropropene ................... . BDL 2
Ethylbenzene ................................ . BDL 2
2 -Hexanorie .................................. . BDL 50
Methylene chloride .......................... . BDL 10
1,1,2,2-Tetrachloroethane ................... . BDL 2
Tetrachloroethene .· .......................... . BDL 2
Toluene ..................................... . 2 2
1,1,1-Trichloroethane ....................... . BDL 2
1,1,2-Trichloroethane ....................... . BDL 2
Trichloroethene ............................. . 11 2
Vinyl chloride .............................. . BDL 10
Xylenes ..................................... . BDL 2
Acid Extractable Organics (EPA 625) (ug/1) (ug/1)
Benzoic Acid ................................ . BDL so
4 -Chloro-3 -methylphenol. ..................... . BDL 10
2-Chlorophenol .............................. . BDL 10
2, 4 -Dichlorophenol .......................... . BDL 10
2, 4-Dimethylphenol .......................... . BDL 10
2, 4-Dinitrophenol. .......................... . BDL so
4,6-Dinitro-2-methylphenol .................. . BDL so
2-Methylphenol .............................. . BDL 10
4-Methylphenol .............................. . BDL 10
2-Nitrophenol ............................... . BDL 50
4-Nitrophenol ............................... . BDL so
Pentachlorophenol ........................... . BDL 20
Phenol ........................ : ............. . BDL 10
2, 4, 6 -Trichlorophenol ....................... . BDL 10
2, 4, 5-Trichlorophenol. ...................... . BDL 10
BDL -Below Detection Limit
. '
Conestoga-Rovers
Page 3 of 4
• •
August 7, 1998
Report No. 97566-2
Wastewater, grab, Jadco-Hughes, Project #3669, W-3669-MC-072298-098,
07/22/98, 13:00, received 07/23/98
RESULTS
Detection
Result Limit
Base/Neutral Extractable Organics (EPA 625I (ug/1) (ug/1)
Acenaphthene ................................ . BDL 10
Acenaphthylene .............................. . BDL 10
Anthracene .................................. . BDL 10
'Benzo(a)anthracene .......................... . BDL 10
Benzo(b)fluoranthene ........................ . BDL 10
Benzo(k)fluoranthene ........................ . BDL 10
Benzo(a)pyrene .............................. . BDL 10
Benzo ( ghi) perylene .......................... . BDL 10
Benzyl butyl phthalate ...................... . BDL 10
Bis(2-chloroethyl)ether ..................... . BDL 10
Bis(2-chloroethoxy)methane .................. . BDL 10
Bis(2-ethylhexyl)phthalate .......... : ....... . BDL 10
Bis(2-chloroisopropyl)ether ................. . BDL 10
4-Bromophenyl phenyl ether .................. . BDL 10
4-Chloroaniline ............................. . BDL 20
2-Chloronaphthalene ......................... . BDL 10
4-Chlorophenyl phenyl ether ................. . BDL 10
Chrysene .................................... . BDL lO
Dibenzo(a,h)anthracene ...................... . BDL 10
Dibenzofuran ................................ . BDL 10
Di-n-butylphthalate ......................... . BDL 10
1, 3 -Dichlorobenzene ......................... . BDL 10
1,2-Dichlorobenzene ......................... . BDL 10
1, 4 -Dichlorobenzene ......................... . BDL 10
3, 3' -Dichlorobenzidine ...................... . BDL 20
Diethylphthalate ............................ . BDL 10
Dimethylphthalate ........................... . BDL 10
2, 4-Dinitrotoluene .......................... . BDL 20
2, 6-Dinitrotoluene ........ ; ................. . BDL 20
Di-n-octylphthalate ......................... . BDL 10
Fluoranthene ................................ . BDL 10
Fluorene .................................... . BDL 10
Hexachlorobenzene ........................... . BDL 10
Hexachlorobutadiene ......................... . BDL 10
Hexachlorocyclopentadiene ................... . BDL 10
Hexachloroethane.: .......................... . BDL 2
Indeno ( 1, 2, 3 -cd) pyrene ...................... . BDL 10
Isophorone ................................... . BDL 10
BDL -Below Detection Limit
Conestoga-Rovers
Page4 of 4
• •
August 7, 1998
Report No. 97566-2
Wastewater, grab, Jadco-Hughes, Project #3669, W-3669-MC-072298-098,
07/22/98, 13:00, received 07/23/98
RESULTS
Detection
Result Limit
Base/Neutral Extractable Organics (EPA 625) (ug/1) (ug/1)
2-Methylnaphthalene ......................... . BDL 10
Naphthalene ................................. . BDL 10
2-Nitroaniline .............................. . BDL 50
3-Nitroaniline .............................. . BDL 50
4-Nitroaniline .............................. . BDL 50
Nitrobenzene ................................ . BDL 10
N-Nitrosodiphenylamine ...................... . BDL 10
N-Nitrosodi-n-propylamine ................... . BDL 10
Phenanthrene ..... • ........................... . BDL 10
Pyrene ...................................... . BDL 10
1,2,4-Trichlorobenzene ...................... . BDL 10
PCB' s (EPA 608) (ug/1) (ug/1)
PCB 1016 .................................... . BDL 1.0
PCB 1221 .................................... . BDL 1.0
PCB 1232 .................................... . BDL 1.0
PCB 1242 .................................... . BDL l.U
PCB 1248 .................................... . BDL 1.0
PCB 1254 ...... : ............................. . BDL 1.0
PCB 1260 .................................... . BDL 1.0
BDL -Below Detection Limit
North Carolina Laboratory I.D. No. 381
. ' • •
ASI ANALYTICAL SERVICES, INC.
ENVIRONMENTAL MONITORING & LABORATORY ANALYSIS
110 TECHNOLOGY PARKWAY • NORCROSS, GA 30092
[phone] • FAX [phone]
Conestoga-Rovers
1351 Oakbrook Drive
Suite 150
Norcross, GA 30093
LABORATORY REPORT
Attention: Mr. Rob Brachowski
Sample Description
August 7, 1998
Report No. 97566-3
Water,, Jadco-Hughes, Project #3669, Trip Blank,,, received 07/23/98
RESULTS
Detection
Result Limit
Volatile Organics (EPA 624) (ug/1) (ug/1)
Acetone ..................................... . BDL 100
Benzene ..................................... . BDL 2
Bromodichloromethane ........................ . BDL lO
Bromoform ................................... . BDL 10
Bromomethane ................................ . BDL 10
2-Butanone .................................. . BDL 100
Carbon disulfide ............................ . BDL 5
Carbon tetrachloride ........................ . BDL 2
Chlorobenzene ............................... . BDL 10
Chloroethane ................................ . BDL 5
Chloroform .................................. . BDL 2
Chloromethane ............................... . BDL 10
Dibromochloromethane ........................ . BDL 10
1, 1-Dichloroethane ......... · ................. .
1, 2-Dichloroethane .......................... .
1, 1-Dichloroethene .......................... .
1,2-Dichloroethene (total) .................. .
1, 2-Dichloropropane ......................... .
cis-1, 3-Dichloropropene ..................... .
trans-1,3-Dichloropropene ................... .
Ethylbenzene ................................ .
2 -Hexanone .................................. .
BDL 2
BDL 2
BDL 2
BDL 2
BDL 2
BDL 2
BDL 2
BDL 2
BDL 50
Methylene chloride .......................... . BDL 10
BDL -Below Detection Limit
A I lnit nf Am~rir;;::in An;::ilvtir.:::11 Servir.es. Inc.
Conestoga-Rovers
Page 2 of 2
• •
August 7, 1998
Report No. 97566-3
Water,, Jadco-Hughes, Project #3669, Trip Blank,,, received 07/23/98
RESULTS
Volatile Organics (EPA 624)
1,1,2,2-Tetrachloroethane ................... .
Tetrachloroethene ........................... .
Toluene ..................................... .
1,1,1-Trichloroethane ....................... .
1,1,2-Trichloroethane ....................... .
Trichloroethene ............................. .
Vinyl chloride .............................. .
Xylenes ..................................... .
BDL -Below Detection Limit
North Carolina Laboratory I.D. No. 381
Result
(ug/1)
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
Detection
Limit
(ug/1)
2
2
2
2
2
2
10
2
• •
Analytical Services Inc. Batch QC
For Report Number :97566
Organochlorine Pesticides
Page 1
Matrix: Aqueous Batch# 40096 Method: EPA 608
Lab Control Information
Analyte
BHC-gamma (Lindane)
Heptachlor
Aldrin
Dieldrin
Endrin
4,4'-DDT
Matrix Spike Information
Analyte
BHC-gamma (Lindane)
Heptachlor
Aldrin
Dieldrin
Endrin
4, 4' -DDT
-----·-· --·-·-·· --·-·--· ·-·-------· . --···-···---------. -·-.
LC
%Rec
93
78
85
96
103
69
MS
%Rec
84
83
83
89
90
76
LCD
%Rec
77
61
61
70
71
57
MSD
%Rec
80
78
85
86
93
86
LC
RPD
18
24
33
31
37
20
MS
RPD
4
7
2
3
4
12
%-Recovery
Range
32 -127
34 -111
42 -122
36 -146
30 -147
25 -160
%Recovery
Range
32 -127
34 -111
42 -122
36 -146
30 -147
25 -160
RPD
Range
0 -40
0 -40
0 -40
0 -40
0 -40
0 -40
RPD
Range
0 -40
0 -40
0 -40
0 -40
0 -40
0 -40
• •
Page 2
Analytical Services Inc. Batch QC
Surrogate Recovery
Organochlorine Pesticides
Matrix Aqueous Batch# 40096 Method EPA 608
,_ • Recovery Objectives
Sl Dibutylchlorendate 14 -161
S2 Tetrachloro-rn-xylene 47 -113
S3 Decachlorobiphenyl 0 -139
Sample File Sl S2 S3 S4 S5 S6
40096BLK 071898006R 109 56 61
40096LCS 071898007R 130 55 90
40096LCSD 071898008R 103 52 64
96962-lMS 071898009R 122 78 80
96962-lMSD 071898010R 100 72 48
96962-1 071898011R 97 86 23
96962-2 071898012R 88 64 56
97126 071898013R 61 70 20
96985 071898014R 73 55 38
97039-1 071898017R 100 63 75
97056-1 071898018R 84 49 57
96973 071898019R 46 22 27
97039-lRR 072198030R 0 65 36
97258 072198053R 145 70 110
97436 072198067R :i.27 iJ 7 JIJ
97556-1 072498003R 0 73 77
"'"'Note: 608 BUT PCB ONLY
97556-2 072498009R 0 82 96
........ Note: 608 BUT PCB ONLY
97566-2 072498010R 0 81 124
""'Note: 608 BUT PCB ONLY
97617 072998016R 47 38 35
97731-1 072998041R 23 28 14
97644-17 072998042R 177 82 96
97644-17 D 073098064R 39 12 27
"'"'Note: Surrogates diluted out l0X
97617DUP 080198012R 71 46 31
97644-15 080198013R 28 111 20
97777-2 080698021R 47 114 90
97809-2 080698010R 146 67 69
PCB
PCB
PCB
PCB
PCB
PCB
PCB
• •
Q.C. Information for Batch# 40096
Page 3
Printed: 08/07/98 16:04:35
Blank Results Information
Organochlorine Pesticides Method
Blank
Analyte Result
1016 BDL
1221 BDL
1232 BDL
1242 BDL
1248 BDL
1254 BDL
1260 BDL
EPA 608
Detection
Limit
1.0
1.0
1. 0
1.0
1.0
1.0
1.0
• •
Page 4
Q.C. Information for Batch# 40096 Printed: 08/07/98 16:04:35
Sample Batch Information
Organochlorine Pesticides Method : EPA 608
Preparation Preparation Analysis
Sample ID Date Time By Notes Date Time By Inst #
40096BLK 07/13/98 1600 SB 07/14/98 1314 JQZ GC-3
40096LCS 07/13/98 1600 SB 07/14/98 1343 JQZ GC-3
40096LCSD 07/13/98 1600 SB 07/14/98 1412 JQZ GC-3
96962-lMS 07/13/98 1600 SB 07/14/98 1540 JQZ GC-3
96962-lMSD 07/13/98 1600 SB 07/14/98 1639 JQZ GC-3
96962-1 07/13/98 1600 SB 07/14/98 1708 JQZ GC-3
96962-2 07/13/98 1600 SB 07/14/98 1737 JQZ GC-3
97126 07/13/98 1600 SB 07/14/98 1806 JQZ GC-3
96985 07/13/98 1600 SB 07/14/98 1835 JQZ GC-3
97039-1 07/13/98 '1600 SB 07/14/98 1933 JQZ GC-3
97056-1 07/13/98 1600 SB 07/14/98 2002 JQZ GC-3
96973 07/13/98 1600 SB 07/14/98 2032 JQZ GC-3
97258 07/17/98 0800 SB/JC 07/23/98 0247 JQZ GC-3
97436 07/22/98 0800 SB/JC 07/23/98 1041 JQZ GC-3
97039-lRR 07/22/98 13 00 SB/JC 07/22/98 1702 JPH ·GC-4
97556-1 07/23/98 1300 SB/JC 07/24/98 1306 JQZ GC-3
97566-2 07/24/98 0900 SB/JC 07/24/98 1558 JQZ GC-3
97556-2 07/24/98 0900 SB/JC 07/24/98 1526 JQZ GC-3
97617 07/27/98 1600 SB/JC 07/29/98 1708 JQZ GC-3
97731-1 07/29/98 0800 SB 07/30/98 0547 JQZ GC-3
97644-17 07/29/98 0800 SB 07/30/98 0646 JQZ GC-3
97644-17 D ' 07/30/98 ·1'.J06 JQZ GC-c
I I
97644-15 07/28/98 0800 SB 08/01/98 0031 JQZ GC-3
97617DUP 07/28/98 0800 SB 08/01/98 2325 JQZ GC-3
97777-2 08/05/98 1600 SB 08/06/98 2116 JQZ GC-3
97809-2 08/05/98 1600 SB 08/06/98 1604 JQZ GC-3
•
Page 5
Analytical Services Inc. Batch QC
For Report Number :97566
Acids
Matrix : Aqueous Batch # 40102 Method : EPA 625
Lab Control Information LC LCD LC %Recovery RPD
Analyte %Rec %Rec RPD Range Range
4-Chloro-3-methylphenol 71 80 12 23 -97 0 -42
2-Chlorophenol 68 71 5 27 -123 0 -40
2,4-Dichlorophenol 77 82 6 39 -135 0 -40
2,4-Dimethylphenol 74 79 7 32 -119 0 -40
2,4-Dinitrophenol 88 95 8 10 -191 0 -50
4,6-Dinitro-2-methylphenol 120 92 27 10 -181 0 -93
2-Nitrophenol 93 99 5 19 -182 0 -40
4-Nitrophenol 37 43 13 10 -80 0 -50
Pentachlorophenol 97 93 5 9 -103 0 -50
Phenol 27 27 0 12 -89 0 -42
2,4,6-Trichlorophenol 80 87 8 37 -144 0 -40
Matrix Spike Information MS MSD MS %-Recovery RPD
Analyte %Rec %Rec RPD Range Range
4-Chloro-3-methylphenol 91 86 5 23 -97 0 -42
2-Chlorophenol 77 78 1 27 -123 0 -40
2,4-Dichlorophenol 88 86 3 39 -135 0 -40
2,4-Dimethylphenol ao 74 8 ·•, ') ~~ i.19 0 '-:10
2,4-Dinitrophenol 119 112 6 10 -191 0 -·so
4,6-Dinitro-2-methylphenol 149 152 2 10 -181 0 -93
2-Nitrophenol 103 97 5 19 -182 0 -40
4-Nitrophenol 73 77 6 10 -80 0 -50
Pentachlorophenol 88 95 7 9 -103 0 -50
Phenol 46 48 4 12 -89 0 -42
2,4,6-Trichlorophenol 91 91 0 37 -144 0 -40
Matrix
Sample
40102BLK
40102LCS
40102LCSD
96962-2MS
96962-2MSD
96962-1
96962-2
97258
97617
97635-1
97635-2
97635-3
97644-17
97566-2
97436
97566-:C:DUP
97644-15
97777-2
97809-2
• •
Analytical Services Inc. Batch QC
Surrogate Recovery
Acids
Aqueous Batch# 40102 Method
% Recovery Objectives
Sl 2-Fluorophenol 21 -
S2 Phenol-d5 10 -
File Sl S2 S3 S4
B7187 40 24
B7188 40 22
B7189 40 24
B7190 57 39
B7196 56 39
B7193 38 22
B7194 31 19
All94 32 20
Al350 21 21
Al351 42 29
Al352 46 32
Al353 38 32
Al354 49 37
Al253 28 11
Al251 52 29
Al255 33 15
B7573 31 16
B7570 37 31
B7643 24 27
Page 6
EPA 625
100
94
S5 S6
•
Q.C. Information for Batch# 40102
•
Page 7
Printed: 08/07/98 16:04:36
Blank Results Information
Acids Method : EPA 625
Analyte
Benzoic Acid
4-Chloro-3-methylphenol
2-Chlorophenol
2,4-Dichlorophenol
2,4-Dimethylphenol
2,4-Dinitrophenol
4,6-Dinitro-2-methylphenol
2-Methylphenol
4-Methylphenol
2-Nitrophenol
4-Nitrophenol
Pentachlorophenol
Phenol
2,4,6-Trichlorophenol
2,4,5-Trichlorophenol
Blank
Result
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
Detection
Limit
50
10
10
10
10
50'
50
10
10
50
50
20
10
10
10
. ' • •
Page 8
Q.C. Information for Batch# 40102 Printed: 08/07/98 16:04:36
Sample Batch Information
Acids Method: EPA 625
Preparation Preparation Analysis
Sample ID Date Time By Notes Date Time By Inst #
40102BLK 07/14/98 0800 SB/JC 07/14/98 2148 RAC 5971
40102LCS 07/14/98 0800 SB/JC 07/14/98 2224 RAC 5971
40102LCSD 07/14/98 0800 SB/JC 07/14/98 2301 RAC 5971
96962-2MS 07/14/98 0800 SB/JC 07 /15/98' 0240 RAC 5971
96962-2MSD 07/14/98 0800 SB/JC 07/15/98 0316 RAC 5971
96962-1 07/14/98 0800 SB/JC 07/15/98 0127 RAC 5971
96962-2 07/14/98 0800 SB/JC 07/15/98 0203 RAC 5971
97258 07/17/98 0800 SB/JC 07/21/98 2159 TAS 5973
97324 07/17/98 0800 SB/JC I I
97436 07/22/98 0800 SB/JC 07/24/98 2303 RAC 5973
97566-2 07/24/98 0900 SB/JC 07/25/98 1211 RAC 5973
97566-2DUP 07/24/98 0900 SB/JC 07/25/98 0119 RAC 5973
97617 07/27/98 1000 SB/JC 07/28/98 2304 RAC 5973
97635-1 07/27/98 1000 SB/JC 07/28/98 2339 RAC 5973
97635-2 07/27/98 1000 SB/JC 07/29/98 1214 RAC 5973
97635-3 07/27/98 1000 SB/JC 07/29/98 1248 RAC 5973
97644-17 07/29/98 0800 SB/JC 07/29/98 0123 RAC 5973
97644-15 07/29/98 0900 LAR 08/03/98 1102 TAS 5971
97777-2 07/31/98 0900 SB/JS 08/03/98 0914 RAC 5971
97809-2 08/04/98 0900 SB/JS 08/06/98 1222 RAC 5971
. ' • •
Analytical Services Inc. Batch QC
For Report Number :97566
Base Neutrals
Page 9
Matrix: Aqueous Batch# 40103 Method: EPA 625
Lab Control Information
Analyte
Acenaphthene
Acenaphthylene
Anthracene
Benzidine
Benzo(a)anthracene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
Benzo(ghi)perylene
Benzyl butyl phthalate
Bis(2-chloroethyl)ether
Bis(2-chloroethoxy)methane
Bis(2-ethylhexyl)phthalate
Bis(2-chloroisopropyl)ether
4-Bromophenyl phenyl ether
2-Chloronaphthalene
4-Chlorophenyl phenyl ether
Chrysene
Dibenzo(a,h)anthracene
Di-n-butylphthalate
1,3-Dichlorobenzene
1,2-Dichlorobenzene
l,4~Dichlorobenzene
3,3'-Dichlorobenzidine
Diethylphthalate
Dimethylphthalate
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Di-n-octylphthalate
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachloroethane
Indeno(l,2,3-cd)pyrene
Isophorone
Naphthalene
Nitrobenzene
N-Nitrosodi-n-propylamine
Phenanthrene
Pyrene
1,2,4-Trichlorobenzene
LC
%Rec
89
90
105
49
75
78
119
105
107
62
60
81
71
60
96
84
89
80
107
98
57
60
57
98
34
3
51
120
88
115
92
99
59
58
106
71
74
91
73
100
65
67
LCD
%Rec
96
99
108
49
79
81
113
103
106
65
69
89
72
52
98
94
96
84
106
95
65
70
64
104
31
3
50
125
86
112
99
99
67
66
105
80
86
103
85
102
68
79
LC
RPD
8
10
2
1
5
3
6
2
1
5
13
10
1
15
2
12
7
5
1
3
l3
14
12
6
8
21
1
4
3
3
7
1
14
13
1
12
15
12
15
2
4
16
%-Recovery
Range
46 -118
33 -145
27 -133
10 -200
33 -143
24 -159
11 -162
17 -163
10 -219
10 -152
10 -150
33 -184
10 -158
36 -.166
53 -127
60 -118
28 -158
17 -168
10 -227
10 -118
10 172
32 -129
36 -97
10 -262
10 -114
0 -110
24 -96
50 -158
10 -146
26 -137
59 -129
10 -152
24 -116
40 -113
10 -171
21 -196
21 -133
35 -180
41 -116
54 -120
26 -127
44 -142
RPD
Range
0 -31
0 -40
0 -40
0 -100
0 -40
0 -40
0 -42
0 -40
0 -56
0 -40
0 -so
0 -43
0 -40
0 -46
0 -40
0 -40
0 -33
0 -48
0 -70
0 -so
n ~o
0 -4 0
0 -28
0 -100
0 -40
0 -40
0 -38
0 -40
0 -so
0 -40
0 -40
0 -40
0 -40
0 -40
0 -45
0 -60
0 -40
0 -40
0 -38
0 -40
0 -31
0 -28
• •
Page 10
Analytical Services Inc. Batch QC
Base Neutrals
Matrix : Aqueous Batch # 40103 Method : EPA 625
Matrix Spike Information MS MSD MS %Recovery RPD
Analyte %Rec %Rec RPD Range Range
Acenaphthene 83 93 12 46 -118 0 -31
Acenaphthylene 84 94 11 33 -145 0 -40
Anthracene 100 105 5 27 -133 0 -40
Benzidine 61 46 29 10 -200 0 -100
Benzo(a)anthracene 79 78 1 33 -143 0 -40
Benzo(b)fluoranthene 77 88 13 24 -159 0 -79
Benzo(k)fluoranthene 102 108 6 11 -162 0 -42
Benzo(a)pyrene 97 104 8 17 -163 0 -40
Benzo(ghi)perylene 98 110 11 10 -219 0 -56
Benzyl butyl phthalate 72 73 0 10 -152 0 -40
Bis(2-chloroethyl)ether 56 67 18 10 -150 0 -50
Bis(2-chloroethoxy)methane 73 88 18 33 -184 0 -43
Bis(2-ethylhexyl)phthalate 75 76 1 10 -158 0 -40
Bis(2-chloroisopropyl)ether 42 42 0 36 -166 0 -46
4-Bromophenyl phenyl ether 89 99 11 53 -127 0 -40
2-Chloronaphthalene 79 92 15 60 -118 0 -40
4-Chlorophenyl phenyl ether 84 93 11 28 -158 0 -33
Chrysene 84 83 1 17 -168 0 -48
Dibenzo(a,h)anthracene 99 110 10 10 -227 0 -70
Di-n-butylphthalate 96 102 6 10 -118 0 -50
1,3-Dichlorobenzene 53 64 19 10 -172 0 -40
1,2-Dichlorobenzene 58 ·12 21 32 -129 Q 40
1,4-Dichlorobenzene 53 63 18 36 -97 0 -28
3,3'-Dichlorobenzidine 107 105 1 10 -262 0 -100
Diethylphthalate 49 40 21 10 -114 0 -40
Dimethylphthalate 7 7 2 0 -110 0 -40
2,4-Dinitrotoluene 52 47 10 24 -96 0 -38
2,6-Dinitrotoluene 109 122 11 50 -158 0 -40
Di-n-octylphthalate 82 90 10 10 -146 0 -50
Fluoranthene 105 110 5 26 -137 0 -40
Fluorene 86 95 10 59 -121 0 -40
Hexachlorobenzene 92 100 8 10 -152 0 -40
Hexachlorobutadiene 57 69 18 24 -116 0 -40
Hexachloroethane 56 67 18 40 -113 0 -40
Indeno(l,2,3-cd)pyrene 98 109 11 10 -171 0 -45
Isophorone 65 77 17 21 -196 0 -60
Naphthalene 66 82 22 21 -133 0 -40
Nitrobenzene 84 99 17 35 -180 0 -40
N-Nitrosodi-n~propylamine 70 84 18 41 -116 0 -38
Phenanthrene 94 100 6 54 -120 0 -40
Pyrene 68 70 3 26 -127 0 -31
1,2,4-Trichlorobenzene 63 75 17 44 -142 0 -28
. '
Matrix
Sample
40103BLK
40103LCS
40103LCSD
96962-2MS
96962-2MSD
96962-1
96962-2
96962-1D
A"Note:
97258
97324
""'Note:
97617
97635-1
97635-2
97635-3
97644-17
97566-2
97436
97566-2DUP
97644-15
97777-2
97809-2
• •
Analytical Services Inc. Batch QC
Surrogate Recovery
Base Neutrals
Aqueous Batch# 40103 Method
i Recovery Objectives
Sl Nitrobenzene-d5 35 -
File Sl S2 S3 S4
B7190 84
B7191 81
B7192 92
B7199 72
B7200 85
B7197 73
B7198 69
B7214 53
1:10
All95 54
All96 47
BN ONLY
Al355 55
Al356 58
Al3S7 78
Al358 54
Al359 52
Al254 60
Al252 73
Al256 47
B7573 55
B7569· 82
B7644 66
Page 11
EPA 625
114
S5 S6
. ' •
Q.C. Information for Batch# 40103
•
Page 12
Printed: 08/07/98 16:04:39
Blank Results Information
Base Neutrals Method: EPA 625
Analyte
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
Benzo(ghi)perylene
Benzyl butyl phthalate
Bis(2-chloroethyl)ether
Bis(2-chloroethoxy)methane
Bis(2-ethylhexyl)phthalate
Bis(2-chloroisopropyl)ether
4-Bromophenyl phenyl ether
4-Chloroaniline
2-Chloronaphthalene
4-Chlorophenyl phenyl ether
Chrysene
Dibenzo(a,h)anthracene
Dibenzofuran
Di-n-butylphthalate
1,3-Dichlorobenzene
1,2-Dichlorobenzene
1,4-Dichlorobenzene
3,3'-Dichlorobenzidine
Diethylphthalate
Dimethylphthalate
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Di-n-octylphthalate
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadiene
Hexachloroethane
Indeno(l,2,3-cd)pyrene
Isophorone
2-Methylnaphthalene
Naphthalene
2-Nitroaniline
3-Nitroaniline
4-Nitroaniline
Nitrobenzene
N-Nitrosodiphenylamine
N-Nitrosodi-n-propylamine
Phenanthrene
Pyrene
1,2,4-Trichlorobenzene
Blank
Result
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL ·
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
Detection
Limit
10
10
10
10
10
10
10
10
10
10
10
10
10
10
20
10
10
10
10
10
10
10
10
10
20
10
10
20
20
10
10
10
10
10
10
2
10
10
10
10
50
50
50
10
10
10
10
10
10
• • •
Page 13
Q.C. Information for Batch# 40103 Printed: 08/07/98 16:04:39
Sample Batch Information
Base Neutrals Method EPA 625
Preparation Preparation Analysis
S,ample ID Date Time By Notes Date Time By Inst #
40103BLK 07/14/98 0800 SB/JC 07/14/98 2337 RAC 5971
40103LCS 07/14/98 0800 SB/JC 07/15/98 1214 RAC 5971
40103LCSD 07/14/98 0800 SB/JC 07/15/98 1250 RAC 5971
96962-2MS 07/14/98 0800 SB/JC 07/15/98 0505 RAC 5971
96962-2MSD 07/14/98 0800 SB/JC 07/15/98 0541 RAC 5971
96962-1 07/14/98 0800 SB/JC 07/15/98 0352 RAC 5971
96962-2 07/14/98 0800 SB/JC 07/15/98 0429 RAC 5971
96962-lD I I 07/15/98 1434 TAS 5971
97258 07/17/98 0800 SB/JC 07/21/98 2234 RAC 5973
97324 07/17/98 0800 SB/JC 07/21/98 2308 RAC 5973
97436 07/22/98 0800 SB/JC 07/24/98 2337 RAC 5973
97566-2 07/24/98 0900 SB/JC 07/25/98 1245 RAC 5973
97566-2DUP 07/24/98 0900 SB/JC 07/25/98 0153 RAC 5973
97617 07/27/98 1000 SB/JC 07/29/98 0157 RAC 5973
97635-1 07/27/98 1000 SB/JC 07/29/98 0232 RAC 5973
97635-2 07/27/98 1000 SB/JC 07/29/98 0306 RAC 5973
97635-3 07/27/98 1000 SB/JC 07/29/98 0340 RAC 5973
97644-17 07/29/98 1000 SB/JC 07/29/98 0415 RAC 5973
97644 -15 · 07/29/98 1200 LAR 08/03/98 1102 TAS 5971
97777-2 07/31/98 0900 SB/JS 08/03/98 0838 RAC 5971
97809-2 08/04/98 0900 SB/JS 08/06/98 1257 RAC 5971
• •
Analytical Services Inc .. Batch QC
For Report Number :97566
Volatile Organics
Page 14
Matrix: Aqueous Batch# 40126 Method: EPA 624
Lab Control Information
Analyte
Benzene
Bromodichloromethane
Bromoform
Bromomethane
Carbon tetrachloride
Chlorobenzene
Chloroethane
2-Chloroethylvinyl ether
Chloroform
Chloromethane
Dibromochloromethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans-l,3-Dichloroprope11<2
Ethylbenzene
Methylene chloride
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
.Vinyl chloride
LC
%Rec
93
106
101
109
104
97
225
116
101
94
111
97
98
100
102
101
100
100
100
102
106
96
96
112
100
93
100
103
98
109
100
LCD
%Rec
84
95
92
108
94
87
223
108
88
83
102
92
87
90
87
91
90
85
90
92
36
87
88
100
91
83
91
95
88
95
87
LC
RPD
11
12
10
1
10
11
1
8
14
13
8
5
11
10
15
11
10
16
10
10
10
10
9
11
9
11
9
8
11
14
14
%Recovery
Range
37 -151
35 -l.55
45 -169
D -242
70 -140
37 -160
14 -230
D -305
51 -138
D -273
53 -149
l.8 -190
59 -156
18 -190
59 -155
49 -155
D -234
54 -156
D -210
D -227
i7 -183
37 -162
D -221
46 -157
64 -14 8
47 -150
52 -162
52 -150
71 -157
17 -181
D -251
RPD
Range
0 -20
0 -20
0 -20
0 -20
0 -20
0 -20
0 -20
0 -20
0 -20
0 -20
0 -20
0 -20
0 -20
0 -20
0 -20
0 -20
0 -20
0 -20
0 -20
0 -20
Q 20
0 -20
0 -20
0 -20
0 -20
0 -20
0 -20
0 -20
0 -20
0 -20
0 -20
• •
Page 15 Analytical Services Inc. Batch QC Volatile Organics
Matrix : Aqueous ·Batch # 40126 Method : EPA 624
Matrix Spike Information MS MSD MS %Recovery RPD Analyte %Rec %Rec > RPD Range Range
Benzene 100 100 0 37 -151 0 -20 Bromodichloromethane 103 110 6 35 -155 0 -20 Bromoform 91 103 12 45 -169 0 -20 Bromomethane 117 110 6 D -242 0 -20 Carbon tetrachloride 105 109 3 70 -140 0 -20 Chlorobenzene 103 107 4 37 -160 0 -20 Chloroethane 233 238 2 14 -230 0 -20 2-Chloroethylvinyl ether 2 2 8 D -305 0 -20 Chloroform 106 108 2 51 -138 0 -20 Chloromethane 95 93 2 D -273 0 -20 Dibromochloromethane 104 113 9 53 -149 0 -20 1,2-Dichlorobenzene 111 119 7 18 -190 0 -20 1,3-Dichlorobenzene 99 104 6 59 -156 0 -20 1,4-Dichlorobenzene 109 114 5 18 -190 0 -20 .1,1-Dichloroethane 104 108 4 59 -155 0 -20 1,2-Dichloroethane 107 109 2 49 -155 0 -20 1,1-Dichloroethene 101 101 0 D -234 0 -20 trans-1,2-Dichloroethene 96 99 3 54 -156 0 -20 1,2-Dichloropropane 103 106 3 D -210 0 -20 cis-1,3-Dichloropropene 98 104 6 D -227 0 -20 rrans-1,3-Dichloropropene 101 108 7 17 -183 0 -20 Ethylbenzene 105 105 0 37 -162 0 -20 Methylene chloride 109 112 3 D -221 0 -20 1,1,2,2-Tetrachloroethane 109 116 6 46 -157 0 -20 Tetrachloroethene 95 98 3 64 -148 0 -20 Toluene 98 99 1 47 -150 0 -20 1,1,1-Trichloroethane 101 103 2 52 -162 0 -20 1,1,2-Trichloroethane 105 112 6 52 -150 0 -20 Trichloroethene 95 95 0 71 -157 0 -20 Trichlorofluoromethane 114 112 2 17 -181 0 -20 Vinyl chloride 101 98 3 D -251 0 -20
• • •
Page 16
Analytical Services Inc. Batch QC
Surrogate Recovery
Volatile Organics
Matrix Aqueous Batch# 40126 Method EPA 624
% Recovery Objectives
Sl l,2-Dichloroethane-d4 76 -119
S2 Toluene-dB 88 -110
S3 Ethylbenzene-dl0 75 -115
S4 4-Bromofluorobenzene 86 -115
Sample File Sl S2 S3 S4 S5 S6
40126LCS B7103 103 99 103 98
40126LCSD B7104 103 99 102 97
40126BLK B7105 86 100 98 93
96985 B7120 108 100 100 96
96962-1 B7121 104 100 100 98
96962-lD B7122 107 101 100 96
........ Note: DF=5
96962-2 B7123 106 101 101 95
96962-3 B7124 109 100 101 100
96962-4 B7143 105 100 99 95
96962-5 B7126 104 102 99 95
96962-2DUP B7127 114 99 99 97
96962-21✓.S 87128 106 101 102 95
96962-2MSD B7129 109 100 162 96
96973 B7130 107 100 102 93
97119-6 B7131 109 100 102 92
97185 B7132 111 100 100 93
97126 B7133 95 96 105 87
97055-1 B7134 116 102 99 94
96962-3D B7135 105 99 101 94
""'Note: DF=5
96962-4D B7136 104 98 101 93
,,.. ... Note: DF=50
97167 A4965 104 100 101 105
97436 A4982 101 101 102 104
97464 A4983 102 101 102 102
97566-2 A5092 100 100 108 97
97566-3 A5093 104 100 107 98
97594 A5096 117 105 104 99
97635-1 A5097 100 99 108 95
97635-2 A5098 106 100 107 97
97635-3 A5099 101 100 109 97
97566-2DUP B7430 114 105 105 101
-. . •
Q.C. Information for Batch# 40126
Page 17
Printed: 08/07/98 16:04:41
Blank Results Information
Volatile Organics Method: EPA 624
Analyte
Acetone
Benzene
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Dibromochloromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethene
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethyl benzene
2-Hexanone
Methylene chloride
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Vinyl chloride-
Xylenei,
Blank
Result
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
Detection
Limit
100
2
10
10
10
100
5
2
10
5
2
10
10
2
2
2
2
2
2
2
2
SU
10
2
2
2
2
2
2
10
2
• • •
Page 18
Q.C. Information for Batch# 40126 Printed: 08/07/98 16:04:41
Sample Batch Information
Volatile Organics Method EPA 624
Preparation Preparation Analysis
Sample ID Date Time By Notes Date Time By Inst #
40126LCS I I 07/14/98 1051 RFA VOA2
40126LCSD I I 07/14/98 1115 RFA VOA2
40126BLK I I 07/14/98 1138 RFA VOA2
96985 I I 07/14/98 1745 RFA VOA2
96962-1 I I 07/14/98 1808 RFA VOA2
96962-lD I I 07/14/98 1832 RFA VOA2
96962-2 I I 07/14/98 1855 RFA VOA2
96962-3 I I 07/14/98 1919 RFA VOA2
96962-4 I I 07/14/98 1943 RFA VOA2
96962-5 I I 07/14/98 2006 RFA VOA2
96962-2DUP I I 07/14/98 2030 RFA VOA2
96962-2MS I I 07/14/98 2054 RFA VOA2
96962-2MSD I I 07/14/98 2117 RFA VOA2
. 97119-6 I I 07/14/98 2204 RFA VOA2
97185 I I 07/14/98 2228 RFA VOA2
97126 I I 07/14/98 2251 RFA VOA2
96962-3D I I 07/15/98 0830 RFA VOA2
96962-4D I I 07/15/98 0853 RFA VOA2
96973 I I 07/14/98 2141 RFA VOA2
97055-1 I I 07/14/98 2315 RFA VOA2
97167 I I 07/23/98 1347 RFA VOAl
97436 I I 07/23/98 2118 TLW '✓OAl
97474 I I 07/23/98 2145 TLW VOAl
97464 I I 07/23/98 2145 TLW VOAl
97566-2 I I 07/28/98 2103 TLW VOAl
97566-3 I I 07/28/98 2129 TLW VOAl
97594 I I 07/28/98 2248 TLW VOAl
97635-1 I I 07/28/98 2315 TLW VOAl
97635-2 I I 07/28/98 2341 TLW VOAl
97635-3 I I 07/29/98 00.07 TLW VOAl
97566-2DUP I I 07/29/98 2216 LLP VOA2
.. • •
Page 19
Analytical Services Inc. Batch QC
For Report Number :97566
QC Batch General Information
Batch Analysis Blank Prep.
Number Analyte Method Matrix Result Method
39295 Hg EPA 245.1 Aqueous < 0.0002
40242 Se EPA 270.2 Aqueous < 0.0100
""""Note BATCH PASSES ON LCS/LCSD
40242 Tl EPA 279.2 Aqueous < 0.0020
AANote BATCH PASSES ON LCS/LCSD
40248 Ag EPA 200.7 Aqueous < 0.0100
40248 Al EPA 200.7 Aqueous < 0.2000
,,,,..,.,,Note BATCH PASSES ON LCS/LCSD
40248 As EPA 200.7 Aqueous < 0.0100
40248 Ba EPA 200.7 Aqueous < 0.0100
40248 Be EPA 200.7 Aqueous < 0.0010
40248 Ca EPA 200.7 Aqueous < 0.0500
40248 Cd EPA 200.7 Aqueous < 0.0030
40248 Co EPA 200.7 Aqueous < 0.0100
40248 Cr EPA 200.7 Aqueous < 0.0100
40248 Cu EPA 200.7 Aqueous < 0.0100
40248 Fe EPA 200.7 Aqueous < 0.0400
,._ .... Note BATCH PASSES ON LCS/LCSD
40248 K EPA 200.7 Aqueous < 0.2000
........ Note BATCH PASSES ON LCS/LCSD
40248 Mg EPA 200.7 Aqueous < 0.0500
40248 Mn EPA 200.7 Aqueous < 0.0150
40248 Na EPA 200.7 Aqueous < 0.0500
"'""Note BATCH PASSES ON LCS/LCSD
40248 Ni EPA 200.7 Aqueous < 0.0200
40248 Sb EPA 200.7 Aqueous < 0.0500
40248 V EPA 200.7 Aqueous < 0.0200
40248 Zn EPA 200.7 Aqueous < 0.0200
40421 BOD<5 hi SM 5210 B Aqueous < 5.0000
40421 BOD<5 low SM 5210 B Aqueous < 5.0000
40481 NH3-N EPA 350.2 Aq/Solid < 0.1000
40483 pH EPA 150.1 Aqueous 0.0000
40486 TSS EPA 160.2 Aqueous < 5.0000
40501 CN EPA 335.2 Aqueous < 0.0100
40508 O/G EPA .1664 Aqueous 0.0000
,.. .... Note LACK OF SAMPLE FOR MSD. BATCH PASSES FOR MS/LCS/LCSD
'. . • •
Page 20
Analytical Services Inc. Batch QC
For Report Number :97566
Lab Control Information
Batch LC LCD LC %Recovery RPD
Number Analyte Method %Rec %Rec RPD Range Range
39295 Hg EPA 245.1 92 97 5 76 -124 0 -20
40242 Se EPA 270.2 120 116 3 76 -124 0 -20
40242 Tl EPA 279.2 116 104 11 76 -124 0 -20
40248 Ag EPA 200.7 98 96 2 85 -115 0 -20
40248 Al EPA 200.7 89 88 1 85 -115 0 -20
40248 As EPA 200.7 97 95 2 85 -115 0 -20
40248 Ba EPA 200.7 97 95 2 85 -115 0 -20
40248 Be EPA 200.7 92 91 1 85 -115 0 -20
40248 Ca EPA 200.7 99 97 2 85 -115 0 -20
40248 Cd EPA 200.7 95 93 2 85 -115 0 -20
40248 Co EPA 200.7 88 86 2 85 -115 0 -20
40248 Cr EPA 200.7 88 86 2 85 -115 0 -20
40248 Cu EPA 200.7 91 92 1 85 -115 0 -20
40248 Fe EPA 200.7 94 94 0 85 -115 0 -20
40248 K EPA 200.7 110 110 0 85 -115 0 -20
40248 Mg EPA 200.7 94 93 1 , 85 -115 0 -20
40248 Mn EPA 200.7 91 89 2 85 -115 0 -20
40248 Na EPA 200.7 99 101 2 85 -115 0 -20
40248 Ni EPA 200.7 99 97 2 85 -115 0 -20
40248 Sb EPA 200.7 100 100 0 85 -115 0 -20
40248 V EPA 200.7 92 90 2 85 -115 0 -20
40248 Zn EPA 200.7 97 95 2 85 -115 0 -20
40421 BOD<5 hi SM 5210 B 104 109 5 81 -118 G -30
40421 BOD<5 low SM 5210 B 108 105 3 81 -118 0 -30
40481 NH3-N EPA 350.2 98 100 2 75 -125 0 -30
40483 pH EPA 150.1 101 101 0 80 -120 0 -20
40486 TSS EPA 160.2 98 95 3 60 -140 0 -40
40501 CN EPA 335.2 102 99 3 75 -125 0 -30
40508 0/G EPA 1664 63 67 6 32 -103 0 -40
Matrix Spike Information
Batch MS MSD MS %Recovery RPD
Number Analyte Method %Rec %Rec RPD Range Range
39295 Hg EPA 245.1 97 98 1 76 -124 0 -20
40242 Se EPA 270.2 73 80 9 76 -124 0 -20
40242 Tl EPA 279.2 179 179 0 76 -124 0 -20
40248 Ag EPA 200.7 97 97 0 76 -124 0 -20
40248 Al EPA 200.7 83 83 0 76 -124 0 -20
40248 As EPA 200.7 97 97 0 76 -124 0 -20
40248 Ba EPA 200.7 96 96 0 76 -124 0 -20
40248 Be EPA 200.7 92 92 . 0 76 -124 0 -20
40248 Ca EPA 200.7 87 93 7 76 -124 0 -20
40248 Cd EPA 200.7 93 93 0 76 -124 0 -20
40248 Co EPA 200.7 87 87 0 76 -124 0 -20
40248 Cr EPA 200.7 87 87 0 76 -124 0 -20
. ' • •
Page 21
Analytical Services Inc. Batch QC
For Report Number :97566
Matrix Spike Information
Batch MS MSD MS %-Recovery RPD
Number Analyte Method %Rec %Rec RPD Range Range
40248 Cu EPA 200.7 85 85 0 76 -124 0 -20
40248 Fe EPA 200.7 77 77 0 76 -124 0 -20
40248 K EPA 200.7 120 120 0 76 -124 0 -20
40248 Mg EPA 200.7 91 93 2 76 -124 0 -20
40248 Mn EPA 200,7 89 89 0 76 -124 0 -20
40248 Na EPA 200.7 120 120 0 76 -124 0 -20
40248 Ni EPA 200.7 96 96 0 76 -124 0 -20
40248 Sb EPA 200.7 100 100 0 76 -124 0 -20
40248 V EPA 200.7 91 91 0 76 -124 0 -20
40248 Zn EPA 200.7 92 96 4 76 -124 0 -20
404 81 NH3-N EPA 350.2 102 102 0 75 -125 0 -30
40486 TSS EPA 160.2 94 100 6 60 -140 0 -40'
40501 CN EPA 335.2 102 101 1 75 -125 0 -30
40508 0/G EPA 1664 82 0 NC 32 -103 0 -40
Post Digestion Spike Information
Batch PDS %Recovery
Number Analyte Method %Rec Range
40242 Se EPA 270.2 89 76 -124
40242 Tl EPA 279.2 108 76 -124
40248 Ag EPA 200.7 104 85 -115
40248 Al EPA 200.7 91 85 -115
40248 As EPA 200.7 104 85 -115
40248 Ba EPA 200.7 104 85 -115
40248 Be EPA 200.7 100 85 -115
40248 Ca EPA 200.7 100 85 -115
40248 Cd EPA 200,7 101 85 -115
40248 Co EPA 200.7 88 85 -115
40248 Cr EPA 200,7 88 85 -115
40248 Cu EPA 200,7 99 85 -115
40248 Fe EPA 200.7 83 85 -115
40248 K EPA 200.7 91 85 -115
40248 Mg EPA 200.7 100 85 -115
40248 Mn EPA 200.7 98 85 -115
40248 Na EPA 200.7 138 85 -115
40248 Ni EPA 200.7 105 85 -115
40248 Sb EPA 200.7 108 85 -115
40248 V EPA 200.7 99 85 -115
40248 Zn EPA 200.7 104 85 -115
.. . • •
Analytical Services Inc. Batch QC
For Report Number :97566
Unspiked Sample Duplicate Information
Batch
Number
40421
40481
40483
40486
40501
Analyte
BOD<5 hi
NH3-N
pH
TSS
CN
Method
SM 5210 B
EPA 350.2
EPA 150.1
EPA 160.2
EPA 335.2
Sample 1 Sample
RPD RPD
6 0
0 0
0 0
0 0
0
Page 22
2 RPD
Range
0 -30
0 -30
0 -20
0 -40
0 -30
,. ' • •
Page 23
Q.C. Information for Batch# 39295 For Report Number :97566
Sample Batch Information
Analysis : Hg
Preparation Preparation Analysis
Sample ID Tag Date Time By Notes Date Time By Inst
39295BLANK HG 07/27/98 0755 FBS 07/27/98 1223 FBS HGl
39295LCS HG 07/27/98 0755 FBS 07/27/98 1225 FBS HGl
39295LCSD HG 07/27/98 0755 FBS 07/27/98 1228 FBS HGl
97397-lMS HG 07/27/98 0755 FBS 07/27/98 1230 FBS HGl
97397-lMSD HG 07/27/98 0755 FBS 07/27/98 1233 FBS HGl
97397-5DUP HG 07/27/98 0755 FBS 07/27/98 1235 FBS HGl
97397-1 HG 07/27/98 0755 FBS 07/27/98 1237 FBS HGl
97397-2 HG 07/27/98 0755 FBS 07/27/98 1242 FBS HGl
97397-3 HG 07/27/98 0755 FBS 07/27/98 1314 FBS HGl
97397-4 HG 07/27/98 0755 FBS 07/27/98 1316 FBS HGl
97397-5 HG 07/27/98 0755 FBS 07/27/98 1240 FBS HGl
97397-6 HG 07/27/98 0755 FBS 07/27/98 1245 FBS HGl
97397-7 HG 07/27/98 0755 FBS 07/27/98 1319 FBS HGl
97397-8 HG 07/27/98 0755 FBS 07/27/98 1321 FBS HGl
97397-9 HG 07/27/98 0755 FBS 07/27/98 1252 FBS HGl
97397-10 HG 07/27/98 0755 FBS 07/27/98 1254 FBS HGl
97397-11 HG 07/27/98 0755 FBS 07/27/98 1323 FBS HGl
97397-12 HG 07/27/98 0755 FBS 07/27/98 1326 FBS HGl
97397-13 HG 07/27/98 0755 FBS 07/27/98 1257 FBS HGl
97397-14 HG 07/27/98 0755 FBS 07/27/98 1259 FBS HGl
97397-15 HG 07/27/98 0755 FBS 07/27/98 1328 FBS HGl
97397-16 HG 07/27/98 0'/5S FBS 07/27/98 1331 FBS HGl
97397-17 HG 07/27/98 0755 FBS 07/27/98 1333 FBS HGl
97397-18 HG 07/27/98 0755 FBS 07/27/98 1302 FBS HGl
97556-1 HG 07/27/98 0755 FBS 07/27/98 1304 FBS HGl
97566-1 HG 07/27/98 0755 FBS 07/27/98 1306 FBS HGl
' •
Q.C.
Sample ID
40242BLANK
40242LCS
40242LCSD
97566-lMS
97566-lMSD
97534-22PDS
97534-22DUP
97566-1
97620
97634-4
97534-23
97534-24
97534-21
97534-22
97644-11
97644-13
97644-3
97644-5
97644-7
97644-9
97655
40242BLANK
40242LCS
40242LCSD
97566-lMS
97566-lMSD
97534-22PDS
97534-22DUP
97566-1
97620
97634-4
97534-23
97534-24
97534-21
97534-22
97644-1
97644-11
97644-13
97644-3
97644-5
97644-7
97644-9
97655
40242BLANK
40242LCS
40242LCSD
97566-lMS
97566-lMSD
• •
Page 24
Information for Batch# 40242 For Report Number :97566
Sample Batch Information
Analysis : Se, Tl
Preparation Preparation Analysis
Tag Date Time By Notes Date Time By Inst
Se 07/27/98 0915 RCP GFAA 07/28/98 0800 DCM AAl
Se 07/27/98 0915 RCP GFAA 07/28/98 0800 DCM AAl
Se 07/27/98 0915 RCP GFAA 07/28/98 0800 DCM AAl
Se 07/27/98 0915 RCP GFAA 07/28/98 0800 DCM AAl
Se 07/27/98 0915 RCP GFAA 07/28/98 0800 DCM AAl
Se 07/27/98 0915 RCP GFAA 07/28/98 0800 DCM AAl
Se 07/27/98 0915 RCP GFAA 07/28/98 0800 DCM AAl
Se 07/27/98 0915 RCP GFAA 07/28/98 0800 DCM AAl
Se 07/27/98 0915 RCP GFAA 07/28/98 0800 DCM AAl
Se 07/27/98 0915 RCP GFAA 07/28/98 0800 DCM AAl
Se 07/27/98 0915 RCP GFAA 07/28/98 0800 DCM AAl
Se 07/27/98 0915 RCP GFAA 07/28/98 0800 DCM AAl
Se 07/27/98 0915 RCP GFAA 07/28/98 0800 DCM AAl
Se 07/27/98 0915 RCP GFAA 07/28/98 0800 DCM AAl
Se 07/27/98 0915 RCP GFAA 07/28/98 0800 DCM AAl
Se 07/27/98 0915 RCP GFAA 07/28/98 0800 DCM AAl
Se 07/27/98 0915 RCP GFAA 07/28/98 0800 DCM AAl
Se 07/27/98 0915 RCP GFAA 07/28/98 0800 DCM AAl
Se 07/27/98 0915 RCP GFAA 07/28/98 0800 DCM AAl
Se 07/27/98 0915 RCP GFAA 07/28/98 0800 DCM AAl
Se 07/27/98 0915 RCP GFAA 07/28/98 0800 DCM AAl
Tl 07/27/98 0915 RCP .GFAA 07/28/98 1400 DCM AA2
Tl 07/27/98 0915 RCP GFAA 07/28/98 1400 DCM AA2
Tl 07/27/98 0915 RCP GFAA 07/28/98 1400 DCM AA2
Tl 07/27/98 0915 RCP GFAA 07/28/98 1400 DCM AA2
Tl 07/27/98 0915 RCP GFAA 07/28/98 1400 DCM AA2
Tl 07/27/98 0915 RCP GFAA 07/28/98 1400 DCM AA2
Tl 07/27/98 0915 RCP GFAA 07/28/98 1400 DCM AA2
Tl 07/27/98 0915 RCP GFAA 07/28/98 1400 DCM AA2
Tl 07/27/98 0915 RCP GFAA 07/28/98 1400 DCM AA2
Tl 07/27/98 0915 RCP GFAA 07/28/98 1400 DCM AA2
Tl 07/27/98 0915 RCP GFAA 07/28/98 1400 DCM AA2
Tl 07/27/98 0915 RCP GFAA 07/28/98 1400 DCM AA2
Tl 07/27/98 0915 RCP GFAA 07/28/98 1400 DCM AA2
Tl 07/27/98 0915 RCP GFAA 07/28/98 1400 DCM AA2
Tl 07/27/98 0915 RCP GFAA 07/28/98 1400 DCM AA2
Tl 07/27/98 0915 RCP GFAA 07/28/98 1400 DCM AA2
Tl 07/27/98 0915 RCP GFAA 07/28/98 1400 DCM AA2
Tl 07/27/98 0915 RCP GFAA 07/28/98 1400 DCM AA2
Tl 07/27/98 0915 RCP GFAA 07/28/98 1400 DCM AA2
Tl 07/27/98 0915 RCP GFAA 07/28/98 1400 DCM AA2
Tl 07/27/98 0915 RCP GFAA 07/28/98 1400 DCM AA2
Tl 07/27/98 0915 RCP GFAA 07/28/98 1400 DCM AA2
Pb 07/27/98 0915 RCP GFAA 07/29/98 1444 DCM AAl
Pb 07/27/98 0915 RCP GFAA 07/29/98 1444 DCM AAl
Pb 07/27/98 0915 RCP GFAA 07/29/98 1444 DCM AAl
Pb 07/27/98 0915 RCP GFAA 07/29/98 1444 DCM AAl
Pb 07/27/98 0915 RCP GFAA· 07/29/98 1444 DCM AAl
• •
Page 25
Q.C. Information for Batch# 40242 For Report Number :97566
Sample Batch Information
Analysis : Se, Tl
Preparation Preparation Analysis
Sample ID Tag Date Time By Notes Date Time By Inst
97534-22PDS Pb 07/27/98 0915 RCP GFAA 07/29/98 1444 DCM AAl
97534-22DUP Pb 07/27/98 0915 RCP· GFAA 07/29/98 1444 DCM AAl
97566-1 Pb 07/27/98 0915 RCP GFAA 07/29/98 1444 DCM AAl
97620 Pb 07/27/98 0915 RCP GFAA 07/29/98 1444 DCM AAl
97634-4 Pb 07/27/98 0915 RCP GFAA 07/29/98 1444 DCM AAl
97534-23 Pb 07/27/98 0915 RCP GFAA 07/29/98 1444 DCM AAl
97534-24 Pb 07/27/98 0915 RCP GFAA 07/29/98 1444 DCM AAl
97534-21 Pb 07/27/98 0915 RCP GFAA 07/29/98 1444 DCM AAl
97534-22 Pb 07/27/98 0915 RCP GFAA 07/29/98 1444 DCM AAl
97644-1 Pb 07/27/98 0915 RCP GFAA 07/29/98 1444 DCM AAl
97644-11 Pb 07/27/98 0915 RCP GFAA 07/29/98 1444 DCM AAl
97644-13 Pb 07/27/98 0915 RCP GFAA 07/29/98 1444 DCM AAl
97644-3 Pb 07/27/98 0915 RCP GFAA 07/29/98 1444 DCM AAl
97644-5 Pb 07/27/98 0915 RCP GFAA 07/29/98 1444 DCM AAl
97644-7 Pb 07/27/98 0915 RCP GFAA 07/29/98 1444 DCM AAl
97644-9 Pb 07/27/98 0915 RCP GFAA 07/29/98 1444 DCM AAl
97655 Pb 07/27/98 0915 RCP GFAA 07/29/98 1444 DCM AAl
40242BLANK As 07/27/98 0915 RCP GFAA 07/28/98 1201 DCM AAl
40242LCS As 07/27/98 0915 RCP GFAA 07/28/98 1201 DCM AAl
40242LCSD As 07/27/98 0915 RCP GFAA 07/28/98 1201 DCM AAl
97566-lMS As 07/27/98 0915 RCP GFAA 07/28/98 1201 DCM AAl
97566-lMSD As 07/27/98 0915 RCP GFAA 07/28/98 1201 DCM AAl
97534-22PDS As 07/27/98 0915 RCP GFAA 07/28/98 1201 DCM AAl
97534-22DUP As 07/27/98 0915 RCP GFAA 07/28/98 1201 DCM AAl
97566-1 As 07/27/98 0915 RCP GFAA 07/28/98 1201 DCM AAl
97620 As 07/27/98 0915 RCP GFAA 07/28/98 1201 DCM AAl
97634-4 As 07/27/98 0915 RCP GFAA 07/28/98 1201 DCM AAl
'97534-23 As 07/27/98 0915 RCP GFAA 07/28/98 1201 DCM AAl
97534-24 As 07/27/98 0915 RCP GFAA 07/28/98 1201 DCM AAl
97534-21 As 07/27/98 0915 RCP GFAA 07/28/98 1201 DCM AAl
97534~22 As 07/27/98 0915 RCP GFAA 07/28/98 1201 DCM AAl
97644-11 As 07/27/98 0915 RCP GFAA 07/28/98 1201 DCM AAl
97644-13 As 07/27/98 0915 RCP GFAA 07/28/98 1201 DCM AAl
97644-3 As 07/27/98 0915 RCP GFAA 07/28/98 1201 DCM AAl
97644-5 As 07/27/98 0915 RCP GFAA 07/28/98 1201 DCM AAl
97644-7 As 07/27/98 0915 RCP GFAA 07/28/98 1201 DCM AAl
97644-9 As 07/27/98 0915 RCP GFAA 07/28/98 1201 DCM AAl
97655 As 07/27/98 0915 RCP GFAA 07/28/98 1201 DCM AAl
J •
Q.C.
Analysis
Sample ID
40248BLANK
40248LCS
40248LCSD
97566-lMS
97566-lMSD
97438PDS
97438DUP
97438
97526-1
97620
97649-1
97434-1
97434-2
97448-1
97549-1
97549-2
97556-1
97583-2
97566-1
97586-2
97659-1
97659-2
97608-11
97608-13
97448-2
97468-1
97468-2
• •
Page 26
Information for Batch# 40248 For Report Number :97566
Sample Batch Information
Ag, Al, As, Ba, Be, Ca, Cd, Co, Cr, Cu, Fe, K, Mg, Mn, Na, Ni
Sb V Zn
Preparation Preparation Analysis
Tag Date Time By Notes Date Time By Inst
07/28/98 0950 DCF TRACE 07/28/98 1712 MAB ICP2
07/28/98 0950 DCF TRACE 07/28/98 1716 MAB ICP2
07/28/98 0950 DCF TRACE 07/28/98 1720 MAB ICP2
07/28/98 0950 DCF TRACE 07/28/98 1724 MAB ICP2
07/28/98 0950 DCF TRACE 07/28/98 1728 MAB ICP2
07/28/98 0950 DCF TRACE 07/28/98 1732 MAB ICP2
07/28/98 0950 DCF TRACE 07/28/98 1736 MAB ICP2
07/28/98 0950 DCF TRACE 07/28/98 1744 MAB. ICP2
07/28/98 0950 DCF TRACE 07/28/98 1748 MAB ICP2
07/28/98 0950 DCF TRACE 07/28/98 1800 MAB ICP2
07/28/98 0950 DCF TRACE 07/28/98 1804 MAB ICP2
07/28/98 0950 DCF TRACE 07/28/98 1808 MAB ICP2
07/28/98 0950 DCF TRACE 07/28/98 1812 MAB ICP2
07/28/98 0950 DCF TRACE 07/28/98 1816 MAB ICP2
07/28/98 0950 DCF TRACE 07/28/98 1820 MAB ICP2
07/28/98 0950 DCF TRACE 07/28/98 1824 MAB ICP2
07/28/98 0950 DCF TRACE 07/28/98 1828 MAB ICP2
07/28/98 0950 DCF TRACE 07/28/98 1832 MAB ICP2
07/28/98 0950 DCF TRACE 07/28/98 1740 MAB ICP2
07/28/98 0950 DCF TRACE 07/28/98 1844 MAB ICP2
07/28/98 0950 DCF TRACE 07/28/98 1511 MAB ICP2
07/28/98 0950 DCF TRACE 07/28/98 1513 MAB ICP2
07/28/98 0950 DCF TRACE 07/28/98 1848 MAB ICP2
07/28/98 0950 DCF TRACE 07/28/98 1852 MAB ICP2
07/28/98 0950 DCF TRACE 07/28/98 1856 MAB ICP2
07/28/98 0950 DCF TRACE 07/28/98 1900 MAB ICP2
07/28/98 0950 DCF TRACE 07/28/98 1904 MAB ICP2
' . . • •
Page 27
Q.C. Information for Batch# 40421 For Report Number :97566
Sample Batch Information
Analysis : BOD<5 hi, B0D<5 low
Preparation Preparation Analysis
Sample ID Tag Date Time By Notes Date Time By Inst
40421BLK 07/24/98 0725 ET/JG 07/29/98 0645 ET/JG
40421LCS 07/24/98 0725 ET/JG 07/29/98 0645 ET/JG
40421LCSD 07/24/98 0725 ET/JG 07/29/98 0645 ET/JG
97560 07/24/98 0730 ET/JG 07/29/98 0645 ET/JG
97560DUP 07/24/98 0730 ET/JG 07/29/98 0645 ET/JG
97542-1 07/24/98 0730 ET/JG 07/29/98 0645 ET/JG
97542-2 07/24/98 0730 ET/JG 07/29/98 0645 ET/JG
97574 07/24/98 0730 ET/JG 07/29/98 0645 ET/JG
97545-2 07/24/98 0730 ET/JG 07/29/98 0645 ET/JG
97545-1 07/24/98 0730 ET/JG 07/29/98 0645 ET/JG
97566-1 07/24/98 0730 ET/JG 07/29/98 0645 ET/JG
97579-1 07/24/98 0730 ET/JG 07/29/98 0645 ET/JG
97579-2 07/24/98 0730 ET/JG 07/29/98 0645 ET/JG
97579-3 07/24/98 0730 ET/JG 07/29/98 0645 ET/JG
97579-4 07/24/98 0730 ET/JG 07/29/98 0645 ET/JG
97579-5 07/24/98 0730 ET/JG 07/29/98 0645 ET/JG
97579-6 07/24/98 0730 ET/JG 07/29/98 0645 ET/JG
97579-7 07/24/98 0730 ET/JG 07/29/98 0645 ET/JG
97579-8 07/24/98 0730 ET/JG 07/29/98 0645 ET/JG
97579-9 07/24/98 0730 ET/JG 07/29/98 0645 ET/JG
97579-10 07/24/98 0730 ET/JG 07/29/98 0645 ET/JG
97579-11 07/24/98 0730 ET/JG 07/29/98 0645 ET/JG
97579-12 07/24/98 0730 ET/JG 07/29/98 0645 ET/JG
97579-13 07/24/98 0730 ET/JG 07/29/98 0645 ET/JG
97579-14 07/24/98 0730 ET/JG 07/29/98 0645 ET/JG
40421BLK2 07/24/98 0725 ET/JG 07/29/98 0645 ET/JG
40421LCSLOW 07/24/98 0725 ET/JG 07/29/98 0645 ET/JG
40421LCSDLOW 07/24/98 0725 ET/JG 07/29/98 0645 ET/JG
40421CBOD LCS 07/24/98 0725 ET/JG 07/29/98 0645 ET/JG
40421CBOD LCSD 07/24/98 0725 ET/JG 07/29/98 0645 ET/JG
97606 07/24/98 1230 ET/JG 07/29/98 0645 ET/JG
97593 07/24/98 1230 ET/JG 07/29/98 0645 ET/JG
97593DUP 07/24/98 1230 ET/JG 07/29/98 0645 ET/JG
97590 07/24/98 1230 ET/JG 07/29/98 0645 ET/JG
97591 07/24/98 1230 ET/JG 07/29/98 0645 ET/JG
97612 07/24/98 1230 ET/JG 07/29/98 0645 ET/JG
97612 07/24/98 1230 ET/JG CBOD 07/29/98 0645 ET/JG
97618 07/24/98 1230 ET/JG 07/29/98 0645 ET/JG
97622-1 07/24/98 1230 ET/JG 07/29/98 0645 ET/JG
97627-3 07/24/98 1230 ET/JG 07/29/98 0645 ET/JG
97627-2 07/24/98 1230 ET/JG 07/29/98 0645 ET/JG
97627-1 07/24/98 1230 ET/JG 07/29/98 0645 ET/JG
97615-1 07/24/98 1230 ET/JG 07/29/98 0645 ET/JG
97620 07/24/98 1600 ET/JG 07/29/98 0645 ET/JG
97635-1 07/24/98 1700 ET/JG 07/29/98 0645 ET/JG
97635-2 07/24/98 1700 ET/JG 07/29/98 0645 ET/JG
40421BLK3 07/24/98 0725 ET/JG 07/29/98 0645 ET/JG
97648 07/24/98 1815 ET/JG 07/29/98 0645 ET/JG
. .
Sample ID
97635-3
97644-1
97644-3
97644-5
97644-7
97644-9
97644-11
97644-13
97650
• •
Q.C. Information for Batch# 40421
Page 28
For Report Number :97566
Sample Batch Information
Analysis : BOD<5 hi, BOD<5 low
Preparation Preparation Analysis
Tag Date Time By Notes Date Time By
07/24/98 1700 ET/JG 07/29/98 0645 ET/JG
07/24/98 1815 ET/JG 07/29/98 0645 ET/JG
07/24/98 1815 ET/JG 07/29/98 0645 ET/JG
07/24/98 1815 ET/JG 07/29/98 0645 ET/JG
07/24/98 1815 ET/JG 07/29/98 0645 ET/JG
07/24/98 1815 ET/JG 07/29/98 0645 ET/JG
07/24/98 1815 ET/JG 07/29/98 0645 ET/JG
07/24/98 1815 ET/JG 07/29/98 0645 ET/JG
07/24/98 1815 ET/JG 07/29/98 0645 ET/JG
Inst
. . . • •
Page 29
Q.C. Information for Batch# 40481 For Report Number :97566
Sample Batch Information
Analysis : NH3-N
Preparation Preparation Analysis
Sample ID Tag Date Time By Notes Date Time By Inst
40481BLK 07/27/98 1050 BG 07/27/98 1455 BG GENES
40481LCS 07/27/98 1050 BG 07/27/98 1455 BG GENES
40481LCSD 07/27/98 1050 BG 07/27/98 1455 BG GENES
40481CAL 07/27/98 1050 BG 07/27/98 1455 BG GENES
97566-lMS 07/27/98 1050 BG 07/27/98 1455 BG GENES
97566-lMSD 07/27/98 1050 BG 07/27/98 1455 BG GENES
97569-1 07/27/98 1050 BG 07/27/98 1455 BG GENES
97569-2 07/27/98 1050 BG 07/27/98 1455 BG GENES
97569-2DUP 07/27/98 1050 BG 07/27/98 1455 BG GENES
97569-3 07/27/98 1050 BG 07/27/98 1455 BG GENES
97569-4 07/27/98 1050 BG 07/27/98 1455 BG GENES
97567 07/27/98 1050 BG 07/27/98 1455 BG GENES
97563-1 07/27/98 1050 BG 07/27/98 1455 BG GENES
97563-2 07/27/98 1050 BG 07/27/98 1455 BG GENES
97462-2 07/27/98 1050 BG 07/27/98 1455 BG GENES
97465-2 07/27/98 1050 BG 07/27/98 1455 BG GENES
97465-4 07/27/98 1050 BG 07/27/98 1455 BG GENES
97566-1 07/27/98 1050 BG 07/27/98 1455 BG GENES
97566-lDUP 07/27/98 1050 BG 07/27/98 1455 BG GENES
97434-2 07/27/98 1050 BG 07/27/98 1455 BG GENES
97601-4 07/27/98 1050 BG 07/27/98 1455 BG GENES
97541-5 07/27/98 1050 BG 07/27/98 1•155 BG GENES
97541-12 07/27/98 1050 BG 07/27/98 1455 BG GENES
97541-2 07/27/98 1050 BG 07/27/98 1455 BG GENES
97541-15 07/27/98 1050 BG 07/27/98 1455 BG GENES
97499 07/27/98 1050 BG 07/27/98 1455 BG GENES
97462-1 07/27/98 1050 BG 07/27/98 1455 BG GENES
97524-1 07/27/98 1050 BG 07/27/98 1455 BG GENES
' . • •
Page 30
Q.C. Information for Batch# 40483 For Report Number :97566
Sample Batch Information
Analysis : pH
Preparation Preparation Analysis
Sample ID. Tag Date Time By Notes Date Time By Inst
40483CALCHK I I 07/23/98 2000 JN ORION
40483LCS I I 07/23/98 2000 JN ORION
40483LCSD I I 07/23/98 2000 JN ORION
97553 I I 07/23/98 2000 JN ORION
97557-2 I I 07/23/98 2000 JN ORION
97566-2 I I 07/23/98 2000 JN ORION
97566-2DUP I I 07/23/98 2000 JN ORION
97579-1 I I 07/23/98 2000 JN ORION
97579-2 I I 07/23/98 2000 JN ORION
97579-3 I I 07/23/98 2000 JN ORION
97579-4 I I 07/23/98 2000 JN ORION
97579-5 I I 07/23/98 2000 JN ORION
97579-6 I I 07/23/98 2000 JN ORION
97579-7 I I 07/23/98 2000 JN ORION
97579-8 I I 07/23/98 2000 JN ORION
97579-9 I I 07/23/98 2000 JN ORION
97579-10 I I 07/23/98 2000 JN ORION
97579-l0dup I I 07/23/98 2000 JN ORION
97579-11 I I 07/23/98 2000 JN ORION
97579-12 I I 07/23/98 2000 JN ORION
97579-13 I I 07/23/98 2000 JN ORION
97579-14 ! I 07/23/98 2000 JN ORION
97542-1 I I 07/23/98 2000 JN ORION
97542-2 I I 07/23/98 2000 JN ORION
97574 I I 07/23/98 2000 JN ORION
• •
Page 31
Q.C. Information for Batch# 40486 For Report Number :97566
Sample Batch Information
Analysis : TSS
Preparation Preparation Analysis
Sample ID Tag Date Time By Notes Date Time By Inst
40486BLK 7 I 07/24/98 0800 JLP
40486LCS I I 07/24/98 0800 JLP
40486LCSD I I 07/24/98 0800 JLP
97566-lMS I I 07/24/98 0800 JLP
97566-lMSD I I 07/24/98 0800 JLP
97480 I I 07/24/98 0800 JLP
97495-1 I I 07/24/98 0800 JLP
97496-1 I I 07/24/98 0800 JLP
97498-1 I I 07/24/98 0800 JLP
97501 I I 07/24/98 0800 JLP
97481-1 I I 07/24/98 0800 JLP
97524-1 I I 07/24/98 0800 JLP
97525-1 I I 07/24/98 0800 JLP
97527 I I 07/24/98 0800 JLP
97560 / I 07/24/98 0800 JLP
97566-1 I I 07/24/98 0800 JLP
97564-1 I I 07/24/98 0800 JLP
97541-1 I I 07/24/98 0800 JLP
97541-4 I I 07/24/98 0800 JLP
97541-7 I I 07/24/98 0800 JLP
97541-9 I I 07/24/98 0800 JLP
97541-10 ; ' U7/24/:i8 usoo JLP I
97541-11 I I 07/24/98 0800 JLP
97541-14 I I 07/24/98 0800 JLP
97574 I I 07/24/98 0800 JLP
97566-lDUP I I 07/24/98 0800 JLP
97524-lDUP I I 07/24/98 0800 JLP
• •
Page 32
Q.C. Information for Batch# 40501 For Report Number :97566
Sample Batch Information
Analysis : CN
Preparation Preparation Analysis
Sample ID Tag Date Time By Notes Date Time By Inst
40501BLK 07/27/98 1425 EKT MIDI-DIST 07/28/98 0745 EKT GEN
40501LCS 07/27/98 1425 EKT MIDI-DIST 07/28/98 0745 EKT GEN
40501LCSD 07/27/98 1425 EKT MIDI-DIST 07/28/98 0745 EKT GEN
40501CAL5 07/27/98 1425 EKT MIDI-DIST 07/28/98 0745 EKT GEN
40501CAL15 07/27/98 1425 EKT MIDI-DIST 07/28/98 0745 EKT GEN
97566-2MS 07/27/98 1425 EKT MIDI-DIST 07/28/98 0745 EKT GEN
97566-2MSD 07/27/98 1425 EKT MIDI-DIST 07/28/98 0745 EKT GEN
96906AT1 07/27/98 1425 EKT MIDI-DIST 07/28/98 0745 EKT GEN
97566-2 07/27/98 1425 EKT MIDI-DIST 07/28/98 0745 EKT GEN
97566-2DUP 07/27/98 1425 EKT MIDI-DIST 07/28/98 0745 EKT GEN
I
Sample ID
40508BLK
40508LCS
40508LCSD
97584
97566-2
97602
97524-2
97620
97579-15
97570
97570MS
97555
97646-2
97645
97646-2
97645
97584
• •
Q.C. Information for Batch# 40508
Page 33
For Report Number :97566
Sample Batch Information
Analysis : O/G
Preparation
Tag Date Time By
I I
I I
I I
I I
I I
I I
I I
I I
I I
I I
I I
I I
I I
I I
I I
I I
I I
Preparation
Notes
SILICA GEL
SILICA GEL
SILICA GEL
SILICA GEL
Analysis
Date Time By
07/27/98 1110 CB/KC
07/27/98 1110 CB/KC
07/27/98 1110 CB/KC
07/27/98 1110 CB/KC
07/27/98 1110 CB/KC
07/27/98 1110 CB/KC
07/27/98 1110 CB/KC
07/27/98 1110 CB/KC
07/27/98 1110 CB/KC
07/27/98 1110 CB/KC
07/27/98 1110 CB/KC
07/27/98 1335 CB/KC
07/27/98 1335 CB/KC
07/27/98 1335 CB/KC
07/27/98 1110 CB/KC
07/27/98 1110 CB/KC
08/04/98 1530 CB/KC
Inst
CRA SHIPPED TO (Laboralory Name): f\-v,.p.\.'( 1-l.c.J '.:?e;:-v<-"'> rr---c. \l i' L , \µ 'Z.., L
CONESTOGA-ROVERS & ASSOCIATES, INC. \u::, 1-t.'C¼~ 0)-ft)::.. -. , Nv, c. v c !->, t:;' l'-1' 3 CT'A :2._
1351 Oakbrook Drive Suite 150 REFERENCE NUMBER: l>RDJECT NAME:
Norcross, GA 30093 404-441-0027 Jcka ld-v5k:ts-~ \lf C\ 1 "5W-o CHAIN OF CUSTODY RECORD 3669
(/) M~~~v SAMPLER'S 1/1 (d. .£/,/ o~ · ~:~;,Eo VY\ ~c;,\ ~ YV?-
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RELINOUJ' //a ::.Y: /; lj,( £~ DATE: :l/,;U..,1y /!I RECEIVED BY: 0-v,'c'''><"
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® TIME: © TIME:
METHOD OF SHIPMENT: r~· D£?< AIR BILL NUMBER: 'Ef 6 I Q331--"\ 1 I? 'f
White Fully Execuled Copy SAMPLE TEAtt \ RE)J;ve_j FOR LABORATO~ BY:
Yellow Receiving Laboratory Copy VV\lC c,e ~-('. L:.:. C..x tfi'.\li:> D(Ni?,1<7 IJ 7'1 N~ 0620·
Pink . Sampler Copy ( 0J, ~~~I (',Oh DA~: "),.]., \) q I( Goldenrod . Chemist Copy TIME: O't'.w
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CRA
1351 Oakbrook Drive
Suite #150
Norcross, Georgia 30093
[phone]
TO: Jeanne Chew
•
FROM: Robert Brachowski / rb / 34
•
MEMO
REFERENCE NO: 3669
DATE: June 30, 1998
RE: Data Quality Assessment and Validation for Two Water Samples
Collected from the Jadco-Hughes Site in Belmont, North Carolina
(Lot # 95752)
The following details a data quality assessment and validation for results generated by
Analytical Services, Inc. (ASI) of Norcross, Georgia for two water samples collected from the
above-referenced Site. Sample collection was conducted on June 3, 1998. The samples were
selectively analyzed for volatile organic compounds (VOCs), base-neutral and acid extractable
organic compounds (BNA), polychlorinated biphenyls (PCBs), cyanide, oil and grease (O&G),
pH, target analyte list (TAL) metals, total suspended solids (TSS), biological oxygen demand
(BOD), and ammonia. The quality assurance criteria were established by the associated quality
assurance project plan and the analytical methods1. The samples are identified in Table 1. The
analytical methodologies are listed in Table 2.
Holding: Time Periods
The holding time periods are presented in Table 3. The pH parameter should be analyzed for
in the field immediately after sampling; therefore, the pH analysis was performed outside the
allowable holding time period and the data for sample W-3669-MC-060398-099 should be
qualified as estimated (J) for this parameter. On the basis of the sample collection and analysis
dates referenced on the chain-of-custody forms and the analytical reports provided by ASI, the
remainder of the extractions and analyses were performed within the required holding time
periods.
Method Blank Samples
Contamination of samples contributed by laboratory conditions or procedures was monitored
by the concurrent preparation and analysis of method blank samples. The method blank
samples were free from target analytes above the detection limits indicating that no significant
laboratory contamination occurred.
1 Application of quality assurance criteria was consistent with "National Functional Guidelines for
Organic Data Review," revised February 1994 and "National Functional Guidelines for Inorganic Data
Review," revised February 1994.
• •
June 30, 1998 Reference No. 3669
-2 -
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD) Results
AS! provides and analyzes LCS/LCSD in order to further assess the method· accuracy and
precision. The LCS/LCSD data were within the control limits indicating the method achieved
an adequate level of accuracy and precision.
Surrogate Compound Percent Recoveries (Surrogate Recoveries)
Individual sample performance for the VOC, BNA, and PCB parameters were monitored by
surrogate recoveries. The surrogate recoveries were within the control limits for the reported
analyses.
Matrix Spike/Matrix Spike Duplicate (MS/MSD) Percent Recoveries
To assess the long term accuracy and precision of the analytical method on various matrices,
MS/MSD percent recoveries and the RPO of the recoveries are determined. The outlying
MS/MSD percent recovery and RPO data as well as the required sample qualifications are
provided in Table 4. The remainder of the MS/MSD percent recovery and RPO data were
within the control limits indicating an adequate level of accuracy and precision was achieved.
Laboratory Duplicate Analyses
To monitor the precision of the laboratory analytical methods, laboratory duplicate samples
were analyzed for select methods. The laboratory duplicate RPO data were within the control
limits indicating an adequate level of precision was achieved for these select methods.
Trip Blank Analysis
Potential VOC cross-contamination by diffusion of target compounds through the septum seal
of the sample vial into the investigative samples during shipment and storage was monitored
by means of a trip blank sample. The trip blank sample was free from detectable concentrations
of target analytes indicating that no significant cross-contamination occurred.
Overall Assessment
Violation of holding time and MS/MSD criteria resulted in sample qualification as noted in the
previous text and following tables. The remainder of the data was found to exhibit acceptable
levels of accuracy and precision and may used without qualification.
' -r
3669-M-34-Tl
• •
TABLE I
SUMMARY OF THE SAMPLE IDENTIFICATION NUMBERS
ASSOCIATED WITH THE SAMPLES COLLECTED FROM THE
JADCO-HUGHES SITE IN
BELMONT, NORTH CAROLINA
W-3669-MC-060398-098
W-3669-MC-060398-099
' • •
TABLE2
ANALYTICAL METHODS ASSOCIATED WITH THE
SAMPLES COLLECTED FROM THE JADCO-HUGHES SITE IN
BELMONT, NORTH CAROLINA
Parameters Methods
voe SW-846 1 8260B
BNA SW-846 8270C
PCB SW-846 8082
Cyanide MCAWW 2 335.2
pH MCAWW 150.1
TALMetals MCAWW 200 (series)
TSS MCAWW 160.2
BOD SM 3 5210 B
Ammonia MCAWW 350.2
Oil and Grease HEM• 1664
Notes:
1 "Test Methods for Evaluating Solid Wastes, Physical/Chemical Methods," 3"' edition, June 1997 with its
revisions and updates.
2 "Methods for Chemical Analysis of Water and Wastes," EPA 600/ 4-79-020, revised March 1983.
3 "Standard Methods for the Examination of Water and Wastewater," APHA, 16th edition, 1985.
4 "N-Hexane Extractable Material and Silica Gel Treated N-Hexane Extractable Material by Extraction and
Gravimetry," EPA-821-B-94-004, January 1995.
3&69-M-:}4-TI.
• •
TABLE3
HOLDING TIME PERIODS ASSOCIATED WITH THE SAMPLES
COLLECTED FROM THE JADCO-HUGHES SITE IN
BELMONT, NORTH CAROLINA
Parameters
VOC, Cyanide
BNA,PCB
pH
TAL Metals
(excluding mercury)
Holding Time Periods
-14 days from sample collection to completion of analysis
- 7 days from sample collection to extraction
-40 days from extraction to completion of analysis
-Analyze as soon as possible
- 6 months from sample collection to completion of analysis
Mercury, Oil and Grease, -28 days from sample collection to completion of analysis
Ammonia
BOD -48 hours from sample collection to beginning of analysis
TSS - 7 days from sample collection to completion of analysis
3669-M-34·T3
• • •
TABLE4
OUTLYING MS/MSD PERCENT RECOVERY AND RPD DA TA
ASSOCIATED WITH THE SAMPLES COLLECTED FROM THE
JADCO-HUGHES SITE IN BELMONT, NORTH CAROLINA
MS/MSD '"
Percent
Parameter Compound Recoveries
voe Trichloroethene NA'41
Toluene NA
TALMetals Barium 82
Calcium 81
Cadium 84,83
Copper 81
Iron 83
Magnesium 83
Manganese 83
Vandium 79, 74
Selenium 52,40
~
(1) MS/MSD -Matrix Spike/Matrix Spike Duplicate
(2) RPO -Relative percent difference
Control
Limits RPD '"
NA 27
NA 24
[85-115] NA
[85-115] NA
[85-115] NA
[85-115] NA
[85-115] NA
[85-115) NA
185-115) NA
[85-115) NA
176-124) 26
(3) The following samples should be qualified for the associated compound as follows:
RPD
Control
Limits
[14]
[13]
NA
NA
NA
NA
NA
NA
NA
NA
[20]
J -Positive results for the associated compound should be qualified as an estimated value.
UJ -The quantitation limit for the associated compound should he qualified as ;m estimated valu~.
(4) NA -Not applicable
Associated
Samples (JJ
W-3669-MC-060398-099
W-3669-MC-060398-099
W-3669-MC-060398-098
W-3669-MC-060398-098
W-3669-MC-060398-098
W-3669-MC-060398-098
W-3669-MC-060398-098
W-3669-MC-060398-098
W-3669-MC-060398-098
W-3669-MC-060398-098
W-3669-MC-060398-098
• • •
ASI ANALYTICAL SERVICES, INC.
ENVIRONMENTAL MONITORING & LABORATORY ANALYSIS
110 TECHNOLOGY PARKWAY • NORCROSS, GA 30092
[phone] • FAX [phone] CH:_:_:·,·:': ·: ..',:·,ii,~ PR' · ·· · . "'~::n; 1:.t....,;.•,i.'·i,"'Fi"·/ DATA
Date ..2L!L? y ---
18 June, 1998
Case Narrative Report 95752
lnltltils 12)6 --·-----
Rec'd Cl=?A
JUN 2 9 199B
The samples were collected on 3 June, 1998 and received by AS! 4 June, 1998.
One VOA vial for the trip blank broke in transit as shown on the Cooler Discrepancy
Forrn. All other conditions for proper sample receipt were met as indicated on the Chain
of Custody. The samples were logged into the LIMS as report 95752 for the following
analyses as per client request: PCB (EPA 8082), BNA (EPA 8270), VOA (EPA 8260),
Metals (EPA 200.7, 245.1, 270.2, 239.2), BOD (SM 5210 B), NH3 (EPA 350.2), CN
(EPA 335.2), pH (EPA 150.1), 0/G (EPA 1664) and TSS (EPA 160.2). All holding
times for sample preparation and analysis were met with exception of pH which is best
analyzed in the field.
PCB analysis (EPA 8082) met all data quality objectives.
BNA analysis (EPA 8270) gave acceptable spike and surrogate recoveries. The
MS/MSD sample was diluted at l: IO to bring target analytes into calibration range.
VOA analysis (EPA 8260) gave high MSRPD for Trichloroethene and Toluene.
Samples 95752-3 and 95752-7MSD gave low Toluene-d8. All surrogates were
acceptable for 95752-3DUP, 95752-7 and 95752-7MS. All other spike and surrogate
recoveries were acceptable. Samples 95752-1, 95752-2, 95752-3, 95752-3DUP, 95752-5
and 95752-20 were analyzed at dilution factor 5; 95752-21 at dilution factor 50; and
95752-20 was reanalyzed at dilution factor 200 and 95752-2 l at 500 to bring target ·
analytes into calibration range.
Metals analysis (EPA 200.7) gave high MS/MSD/PDS for As; low MS/MSD for
Cd; low MS/MSD/PDS for V; low MSD for Ba, Ca, Cu, Fe, Mg, Mn, and Tl. All ICP
lab controls were acceptable. Hg analysis (EPA 245.1) met all data quality objectives.
Se analysis (EPA 270.2) gave low MS/MSD/PDS. Pb analysis (EPA 239.2) gave low
PDS. All GF lab controls were acceptable.
BOD analysis (SM 5210 B) gave a low recovery for LCS low. The batch passes
on LCS high, LCSD high and LCSD low.
NH3 analysis (EPA 350.2) met all data quality objectives.
CN analysis (EPA 335.2) met all data quality objectives.
pH analysis (EPA 150.1) met all data quality objectives.
0/G analysis (EPA I 664) had insufficient sample.for MSD. The batch passes on
LCS/LCSD/MS.
fl I , ... a ,..f 11...,...,..,.;,.....,,.. 1\...,..,1,,ti,-.._-.I ~n,.,,i,-.n,:, ,...,,..
• •
TSS analysis (EPA 160.2) met all data quality objectives.
Julia E. Martin
Quality Assurance
• •
ASI ANALYTICAL SERVICES, INC.
ENVIRONMENTAL MONITORING & LABORATORY ANALYSIS
110 TECHNOLOGY PARKWAY• NORCROSS, GA 30092
[phone] • FAX [phone]
LABORATORY REPORT
Conestoga-Rovers June 29, 1998
1351 Oakbrook Drive
Suite 150
Norcross, GA 30093
Attention: Mr. Michael Cruz Report No. 95752-12
Sample Description
Water, composite, Jadco-Hughes, Project #3669, W-3669-MC-060398-098,
06/03/98, 11:15, received 06/04/98
RESULTS
Biochemical Oxygen Demand (BOD,) (mg/1)
(SM 5210 B) ............................ .
Total Suspended Solids (mg/1) ( EPA 16 0. 2) .... .
Ammonia Nitrogen (N) (mg/1) (EPA 350.2) ....... .
Target Analyte List -Metals
Metals
Total Aluminum (Al) (EPA 200. 7) .............. .
Total Antimony (Sb) (EPA 200. 7) .............. .
Total Arsenic (As) ( EPA 2 0 0. 7) ............... .
Total Barium (Ba) (EPA 200. 7) ................ .
Total Beryllium (Be) (EPA 200. 7) ............. .
Total Cadmium (Cd) (EPA 200. 7) ............... .
Total Calcium (Ca) (EPA 200. 7) ............... .
Total Chromium (Cr) (EPA 200. 7) .............. .
Total Cobalt (Co} (EPA 200. 7) ................ .
Total Copper (Cu} (EPA 200. 7) ................ .
Total Iron (Fe} (EPA 200. 7) .................. .
Total Lead (Pb} (EPA 239.2) .................. .
BDL -Below Detection Limit
. ---'' .•. --' ,,... --·
Result
BDL
BDL
0.2
(mg/1)
BDL
BDL
BDL
0.04
BDL
BDL
32
BDL
BDL
BDL
BDL
BDL
,_ -
Detection
Limit
5
5
0.1
(mg/1)
0.2
0.05
0.01
0.01
0.001
0.005
0.05
0.01
0.05
0.02
0.1
0.003
Conestoga-Rovers
Page 2 of 2
• •
June 29, 1998
Report No. 95752-12
Water, composite, Jadco-Hughes, Project #3669, W-3669-MC-060398-098,
06/03/98, 11:15, received 06/04/98
RESULTS
Metals
Total Magnesium (Mg) (EPA 200. 7) ............. .
Total Manganese (Mn) (EPA 200. 7) ............. .
Total Mercury (Hg) (EPA 245. 1) ............... .
Total Nickel (Ni) (EPA 200.7) ................ .
Total Potassium (K) (EPA 200. 7) .............. .
Total Selenium (Se) (EPA 270. 2) .............. .
Total Silver (Ag) (EPA 200. 7) ................ .
Total Sodium (Na) (EPA 200. 7) ................ .
Total Thallium (Tl) (EPA 279.2) .............. .
Total Vanadium (V) (EPA 200. 7) ............... .
Total Zinc (Zn) (EPA 200. 7) .................. .
Total Zinc (Zn) (EPA 200. 7) .................. .
BDL -Below Detection Limit
North Carolina Laboratory I.D. No. 381
Result
(mg/1)
10
BDL
BDL
BDL
2.1
BDL
BDL
8.4
BDL
BDL
0.03
0.03
Detection
Limit
(mg/1)
0.05
0.015
0.0002
0.02
0.2
0.005
0.01
0.05
0.002
0.02
0.02
0.02
Respectfully submitted,
)fuµ_· i/c«_JJ-0:
Project' Manliger ne~.
,)'Quality Assurance
l-·
• •
ASI ANALYTICAL SERVICES, INC.
ENVIRONMENTAL MONITORING & LABORATORY ANALYSIS
110 TECHNOLOGY PARKWAY • NORCROSS, GA 30092
[phone] • FAX [phone]
LABORATORY REPORT
Conestoga-Rovers June 29, 1998
1351 Oakbrook Drive
Suite 150
Norcross, GA 30093
Attention: Mr. Michael Cruz Report No. 95752-13
Sample Description
Water, grab, Jadco-Hughes, Project #3669, W-3669-MC-060398-099, 06/03/98,
11:10, received 06/04/98
RESULTS
Detection
Result Limit
Total Cyanide (CN) (mg/1) (EPA 335.2) ......... . BDL 0.01
Oil and Grease (mg/1) (EPA 1664) ............. . BDL 5
pH (laboratory) (EPA 150.1) .................. . 7.78
Volatile Organics (EPA 8260) (ug/1) (ug/1)
Acetone ..................................... . BDL 100
Acrolein .................................... . BDL 50
Acrylonitrile ............................... . BDL 50
Benzene ..................................... . BDL 2
Bromobenzene ................................ . BDL 10
Bromochloromethane .......................... . BDL 10
Bromodichloromethane ........................ . BDL 10
Bromoform ................................... . BDL 10
Bromomethane ................................ . BDL 10
2-Butanone .................................. . BDL 100
n-Butylbenzene .............................. . BDL 10
sec-Butylbenzene ............................ . BDL 10
tert-Butylbenzene. , ......................... . BDL 10
Carbon disulfide ............................ . BDL 5
Carbon tetrachloride ........................ . BDL 2
Chlorobenzene ............................... . BDL 10
Chloroethane ................................ . BDL 5
BDL -Below Detection Limit
"
Conestoga-Rovers
Page 2 of 5
• •
June 29, 199B
Report No. 95752-13
Water, grab, Jadco-Hughes, Project #3669, W-3669-MC-06039B-099, 06/03/98,
11:10, received 06/04/9B
RESULTS
Detection
Result Limit
Volatile Organics (EPA B260) (ug/1) (ug/1)
Chloroform .................................. . 69 2
Chloromethane ............................... . BDL 10
2-Chlorotoluene ............................. . BDL 10
4-Chlorotoluene ............................. . BDL 10
2-Chloroethylvinyl ether .................... . BDL 10
Dibromochloromethane ........................ . BDL 10
1,2-Dibromo-3-chloropropane ................. . BDL 10
1, 2 -Dibromoethane ........................... . BDL 10
Dibromomethane .............................. . BDL 10
1,2-Dichlorobenzene ......................... . BDL 10
1,3-Dichlorobenzene ......................... . BDL 10
1, 4 -Dichlorobenzene ......................... . BDL 10
Dichlorodifluoromethane ..................... . BDL 10
1,1-Dichloroethane .......................... . BDL 2
1, 2-Dichloroethane .......................... . BDL 2
1, 1-Dichloroethene .......................... . BDL 2
cis-1,2-Dichloroethene ...................... . 12 2
trans-1,2-Dichloroethene .................... . BDL 2
1, 2 -Dichloropropane ......................... . BDL 2
1, 3-Dichloropropane ......................... . BDL 2
2, 2 -Dichloropropane ......................... . BDL 2
1, 1-Dichloropropene ....................... ; .. BDL 2
cis-1, 3 -Dichloropropene ..................... . BDL 2
trans-1,3-Dichloropropene ................... . BDL 2
Ethylbenzene ................................ . BDL 2
Hexachlorobutadiene ......................... . BDL 10
2 -Hexanone .................................. . BDL 10
Isopropylbenzene ............................ . BDL 10
p-Isopropyltoluene .......................... .
Methylene chloride .......................... .
BDL 10
BDL 5
4-Methyl-2-pentanone ........................ . BDL 10
Naphthalene ................................. . BDL 10
n-Propylbenzene ............................. . BDL 10
Styrene ..................................... . BDL 5
1,1,1,2-Tetrachloroethane ................... . BDL 2
1,1,2,2-Tetrachloroethane ................... . BDL 2
Tetrachloroethene ........................... . BDL 2
Toluene ..................................... . BDL 2
BDL -Below Detection Limit
Conestoga-Rovers
Page 3 of 5
• •
June 29, 1998
Report No. 95752-13
Water, grab, Jadco-Hughes, Project #3669, W-3669-MC-060398-099, 06/03/98,
11:10, received 06/04/98
RESULTS
Detection
Result Limit
Volatile Organics (EPA 8260) (ug/1) (ug/1)
l, 2, 3-Trichlorobenzene ...................... .
l, 2, 4-Trichlorobenzene ...................... .
l, 1, 1-Trichloroethane ....................... .
1,1,2-Trichloroethane ....................... .
BDL 10
BDL 10
BDL 2
BDL 2
Trichloroethene ............................. . BDL 2
Trichlorofluoromethane ...................... . BDL 10
1,2,3-Trichloropropane ...................... .
1, 2, 4 -Trimethylbenzene ...................... .
1, 3, 5 -Trimethylbenzene ...................... .
BDL 10
BDL 10
BDL 10
Vinyl acetate ............................... .
Vinyl chloride .............................. .
m+p-Xylene .................................. .
o-Xylene .................................... .
Xylenes (total) ............................. .
BDL 10
BDL 10
BDL 5
BDL 5
BDL 5
Acid Extractable Organics (EPA 8270) (ug/1) (ug/1)
4-Chloro-3-methylphenol ..................... . BDL 10
2 -Chlorophenol .............................. . BDL 10
2, 4 -Dichlorophenol .......................... . BDL 10
2, 4 -Dimethylphenol .......................... . BDL .10
4,6-Dinitro-2-methylphenol .................. .
2, 4 -Dini trophenol ........................... .
BDL so
BDL so
2 -Methylphenol. ............................. .
4 -Methylphenol .............................. .
2-Nitrophenol ............................... .
4-Nitrophenol ............................... .
Pentachlorophenol ........................... .
BDL 10
BDL 10
BDL so
BDL 50
BDL 20
Phenol ...................................... . BDL 10
2, 4, 5-Trichlorophenol. ...................... . BDL 10
2,4,6-Trichlorophenol ....................... . BDL 10
BDL -Below Detection Limit
Conestoga-Rovers
Page 4 of 5
• •
June 29, 1998
Report No. 95752-13
Water, grab, Jadco-Hughes, Project #3669, W-3669-MC-060398-099, 06/03/98,
11:10, received 06/04/98
RESULTS
Detection
Result Limit
Base/Neutral Extractable Organics (EPA 8270) (ug/1) (ug/1)
Acenaphthene ................................ . BDL 10
Acenaphthylene .............................. . BDL 10
Anthracene .................................. . BDL 10
Benzoic Acid ................................ . BDL so
Benzo (a) anthracene ........................... . BDL 10
Benzo(b)fluoranthene ........................ . BDL 10
Benzo ( k) fl uoranthene ........................ . BDL 10
Benzo ( ghi) perylene .......................... . BDL 10
Benzo ( a) pyrene .............................. . BDL 10
Benzyl Alcohol .............................. . BDL 20
Bis(2-chloroethoxy)methane .................. . BDL 10
Bis (2-chloroethyl) ether ..................... . BDL 10
Bis(2-chloroisopropyl)ether ................. . BDL 10
Bis(2-ethylhexyl)phthalate .................. . BDL 10
4-Bromophenyl phenyl ether .................. . BDL 10
Benzyl butyl phthalate ...................... . BDL 10
4-Chloroaniline ............................. . BDL 20
2-Chloronaphthalene ......................... . BDL 10
4-Chlorophenyl phenyl ether ................. . BDL 10
Chrysene .................................... . BDL 10
Dibenzo(a,h)anthracene ...................... . BDL 10
Dibenzofuran ................................ . BDL 10
Di-n-butylphthalate ......................... . BDL 10
l,3-Dichlorobenzene ......................... . BDL 10
l, 4 -Dichlorobenzene ......................... . BDL 10
1, 2 -Dichlorobenzene ......................... . BDL 10
3, 3' -Dichlorobenzidine ...................... . BDL 20
Diethylphthala te ............................ . BDL 10
Dimethylphthalate ........................... . BDL 10
2, 4 -Dinitrotoluene .......................... . BDL 20
2, 6-Dinitrotoluene .......................... . BDL 20
Di-n-octylphthalate ......................... . BDL 10
Fluoranthene ................................ . BDL 10
Fluorene .................................... . BDL 10
Hexachlorobenzene ........................... . BDL 10
Hexachlorobutadiene ......................... . BDL 10
Hexachlorocyclopentadiene ................... . BDL 10
Hexachloroethane ............................ . BDL 2
BDL -Below Detection Limit
Conestoga-Rovers
Page 5 of 5
• •
June 29, 1998
Report No. 95752-13
Water, grab, Jadco-Hughes, Project #3669, W-3669-MC-060398-099, 06/03/98,
11:10, received 06/04/98
RESULTS
Detection
Result Limit
Base/Neutral Extractable Organic·s (EPA 8270) (ug/1) (ug/1)
Indeno ( 1, 2, 3-cd) pyrene ...................... . BDL 10
I sophorone .................................. . BDL 10
2 -Methylnaphthalene ......................... . BDL 10
Naphthalene ................................. . BDL 10
2 -Ni troaniline .............................. . BDL 50
3-Nitroaniline .............................. . BDL 50
4-Nitroaniline .............................. . BDL 50
Nitrobenzene ................................ . BDL 10
N-Nitrosodimethylamine ...................... . BDL 10
N-Nitrosodiphenylamine ...................... . BDL 10
N-Nitrosodi-n-propylamine ................... . BDL 10
Phenanthrene ................................ . BDL 10
Pyrene ...................................... . BDL 10
1,2,4-Trichlorobenzene ...................... . BDL 10
PCB's (EPA 8082) (ug/1) (ug/1)
PCB 1016 .................................... . BDL 1.0
PCB 1221 .................................... . BDL 1.0
PCB 1232 .................................... . BDL 1.0
PCB 1242 .................................... . BDL 1.0
PCB 1248 .................................... . BDL 1. 0
PCB 1254 .................................... . BDL 1. 0
PCB 1260 .................................... . BDL 1.0
BDL -Below Detection Limit
North Carolina Laboratory I.D. No. 381
Respectfully submitted,
}AAu·/Jcu~
... Project Man!i.ger
(: y .
'~'c(___. ~
(;Quality Assurance
CRA
1351 Oakbrook Drive
Suite #150
Norcross, Georgia 30093
[phone]
TO: Jeanne Chew
•
FROM: Robert Brachowski/vad/33
•
MEMO-
REFERENCE NO: 3669
DATE: May 28, 1998
RE: Data Quality Assessment and Validation for Three Water Samples
ColJected from the Jadco-Hughes Site in Belmont, North Carolina
(Lot# 94733 and 95164)
The folJowing details a data quality assessment and validation for results generated by
Analytical Services, Inc. (ASI) of Norcross, Georgia for three water samples colJected from the
above-referenced Site. Sample collection was conducted on May 6 and 19, 1998. The samples
were selectively analyzed for volatile organic compounds (VOCs), base-neutral and acid
extractable organic compounds (BNA), polychlorinated biphenyls (PCBs), cyanide, oil and
grease (O&G), pH, target analyte list (T AL) metals, total suspended solids (TSS), biological
oxygen demand (BOD), and ammonia. The quality assurance criteria were established by the
associated quality assurance project plan and the analytical methods1. The samples are
identified in Table l. The analytical methodologies are listed in Table 2.
Holding Time Periods
The holding time periods are presented in Table 3. The pH paramet_er should be analyzed for
in the field immediately after sampling; therefore, the pH analysis was performed outside the
allowable holding time period and the data for sample W-3669-MC-050698-096 should be
qualified as estimated (J) for this parameter. On the basis of the sample collection and analysis
dates referenced on the chain-of-custody forms and the analytical reports provided by ASI, the
remainder of the extractions and analyses were performed within the required holding time
periods.
Method Blank Samples
Contamination of samples contributed by laboratory conditions or procedures was monitored
by the concurrent preparation and analysis of method blank samples. The method blank
samples were free from target analytes above the detection limits indicating that no significant
laboratory contamination occurred.
1 Application of quality assurance criteria was consistent with "National Functional Guidelines for
Organic Data Review," revised February 1994 and 'National Functional Guidelines for Inorganic Data
Review," revised February 1994.
• •
May 28, 1998 Reference No. 3669
- 2 -
Laboratory Control Sample/Laborat01:y Control Sample Duplicate (LCS/LCSD) Results
ASJ provides and analyzes LCS/LCSD in order to further assess the method accuracy and
precision. The LCS/LCSD data were within the control limits indicating the method achieved
an adequate level of accuracy and precision.
Surrogate Compound Percent Recoveries (Surrogate Recoveries)
Individual sample performance for the VOC, BNA, and PCB parameters were monitored by
surrogate recoveries. The surrogate recoveries were within the control limits for the reported
analyses.
Matrix Spike/Matrix Spike Duplicate (MS/MSD) Percent Recoveries
To assess the long term accuracy and precision of the analytical method on various matrices,
MS/MSD percent recoveries and the RPO of the recoveries are determined. The TAL metals
MS/MSD percent recoveries for selenium, barium, and potassium were outside the control
limits; therefore, the sample W-3669-MC-050698-095 should be qualified as estimated 0) for the
associated detected compounds and the quantitation limits should be qualified as estimated
(UJ) for associated non-detected compounds. The TAL metals MS/MSD percent recoveries for
zinc were outside the control limits; therefore, the data for sample W-3669-MC-051998-097
should be qualified as estimated 0) for this analyte. Some other MS/MSD data were outside
the control limits; however, no sample qualification was deemed necessary. The remainder of
the MS/MSD percent recovery and RPO data were within the control limits indicating an
adequate level of accuracy and precision was achieved.
Laboratory Duplicate Analyses
To monitor the precision of the laboratory analytical methods, laboratory duplicate samples
were analyzed for select methods. The laboratory duplicate RPO data were within the control
limits indicating an adequate level of precision was achieved for these select methods.
Trip Blank Analysis
Potential VOC cross-contamination by diffusion of target compounds through the septum seal
of the sample vial into the investigative samples during shipment and storage was monitored
by means of a trip blank sample. The trip blank sample was free from detectable concentrations
of target analytes indicating that no significant cross-contamination occurred.
Overall Assessment
Violation of holding time and MS/MSD criteria resulted in sample qualification as noted in the
previous text. The remainder of the data was found to exhibit acceptable levels of accuracy and
precision and may used without qualification.
•
TABLEl
SUMMARY OF THE SAMPLE IDENTIFICATION NUMBERS
ASSOCIATED WITH THE SAMPLES COLLECTED FROM THE
JADCO-HUGHES SITE IN
3669-M-33-Tl
BELMONT, NORTH CAROLINA
W-3669-MC-050698-095
W-3669-MC-050698-096
W-3669-MC-051998-097
• •
TABLE2
ANALYTICAL METHODS ASSOCIATED WITH THE
SAMPLES COLLECTED FROM THE JADCO-HUGHES SITE IN
BELMONT, NORTH CAROLINA
Parameters Methods
voe MCAWW 1 624
BNA MCAWW 625
PCB MCAWW 608
Cyanide MCAWW 335.2
pH MCAWW 150.1
TALMetals MCAWW 200 (series)
TSS MCAWW 160.2
BOD SM 2 5210 B
Ammonia MCAWW 350.2
Oil and Grease HEM 3 1664
Notes:
1 "Methods for Chemical Analysis of Water and Wastes," EPA 600/ 4-79-020, revised March 1983.
2 "Standard Methods for the Examination of Water and Wastewater," APHA, 16th edition, 1985.
'"N-Hexane Extractable Material and Silica Gel Treated N-Hexane Extractable Material by Extraction and
Gravimetry," EPA-821-B-94-004, January 1995.
3669-M-33-TI
• •
TABLE3
HOLDING TIME PERIODS ASSOCIATED WITH THE SAMPLES
COLLECTED FROM THE JADCO-HUGHES SITE IN
BELMONT, NORTH CAROLINA
Parameters
VOC, Cyanide
BNA, PCB
pH
TALMetals
(excluding mercury)
Holding Time Periods
-14 days from sample collection to completion of analysis
- 7 days from sample collection to extraction
-40 days from extraction to completion of analysis
-Analyze as soon as possible
- 6 months from sample collection to completion of analysis
Mercury, Oil and Grease, -28 days from sample collection to completion of analysis
Ammonia
BOD -48 hours from sample collection to beginning of analysis
TSS - 7 days from sample collection to completion of analysis
3669-M-33-TI
ASI
• •
ANALYTICAL SERVICES, INC.
ENVIRONMENTAL MONITORING & LABORATORY ANALYSIS
110 TECHNOLOGY PARKWAY • NORCROSS, GA 30092
[phone] • FAX [phone]
Rec'd CRA
MA.Y 2 7 1998
20 May, 1998
Case Narrative Report 94733
The samples were collected on 6 May, 1998 and received by ASI 7 May,
1998. The samples were received at 0°C, but all other conditions for proper sample
receipt were met as indicated on the Chain of Custody. The samples were logged into the
LIMS as report 94733 for the following analyses as per client request: PCB (EPA 608),
BNA (EPA 625), VOA (EPA 624), Metals (EPA 200.7, 245.1, 270.2, 279.2, 239.2), BOD
(SM 52108), NH3 (EPA 350.2), pH (EPA 150.1), CN (EPA 335.2), 0/G (EPA 1664) and
TSS (EPA 160.2). All holding times for sample preparation and analysis were met with
exception of pH which should be analyzed on-site during sampling.
PCB analysis (EPA 608) gave high MSRPD for all spiking compounds. The
individual MS/MSD recoveries as well as all LCS/LCSD/LCSRPD recoveries were
acceptable. All surrogate recoveries were also within acceptance limits.
BNA analysis (EPA 625) met all data quality objectives.
VOA analysis (EPA 624) gave high MSRPD for 2-Chloroethylvinyl ether. All
other spikes and all surrogates were acceptable.
Metals analysis (EPA 200.7) gave high MSD for Ag, Cr, Cu, Mn, K; high
MS/MSD for Ba, Be and Cd; low PDS for Ag. All other spike recoveries were
acceptable. Hg analysis (EPA 245.1) met all data quality objectives. Se analysis (EPA
270.2) gave low MS/MSD. Tl analysis (EPA 279.2) met all data quality objectives. Pb
analysis (EPA 239.2) met all data quality objectives.
BOD analysis (SM 5210) gave an invalid I st DUP RPO, but all other quality
controls were acceptable.
NH3 analysis (EPA 350.2) met all data quality objectives.
pH analysis (EPA 150.1) gave acceptable recoveries for all quality controls.
CN analysis (EPA 335.2) met all data quality objectives.
0/G analysis (EPA 1664) gave acceptable LCS/LCSD/MS. There was
insufficient sample to run MSD.
TSS analysis (EPA 160.2) met all data quality objectives.
(}a;~
Quality Assurance
A Unit of American Analytical Services. Inc.
• •
ASI ANALYTICAL SERVICES, INC.
Conestoga-Rovers
1351 Oakbrook Drive
Suite 150
Norcross, GA 30093
ENVIRONMENTAL MONITORING & LABORATORY ANALYSIS
110 TECHNOLOGY PARKWAY • NORCROSS, GA 30092
[phone] • FAX [phone]
LABORATORY REPORT
May 20, 1998
Attention: Mr. Rob Brachowski Report No. 94733-1
Sample Description
Wastewater, composite, Monthly, Jadco-Hughes, Project #3669, W-3669-MC-
050698-095, 05/06/98, 13:15, received 05/07/98
RESULTS
Biochemical Oxygen Demand (BOD5 ) (mg/1)
(SM 5210 B) ............................ .
Ammonia Nitrogen (N) (mg/1) (EPA 350.2) ....... .
Total Suspended Solids (mg/1) (EPA 160. 2) .... .
Target Analyte List -Metals
Metals
Total Aluminum (Al) (EPA 200. 7) .............. .
Total Antimony (Sb) (EPA 200. 7) .............. .
Total Arsenic (As) (EPA 200. 7) ............... .
Total Barium (Ba) (EPA 200. 7) ................ .
Total Beryllium (Be) (EPA 200. 7) ............. .
Total Cadmium (Cd) (EPA 200. 7) ............... .
Total Calcium (Ca)(EPA 200.7) .............. ..
Total Chromium (Cr) (EPA 200. 7) .............. .
Total Cobalt (Co) (EPA 200. 7) ................ .
Total Copper (Cu) (EPA 200. 7) ................ .
Total Iron (Fe) (EPA 200.7) .................. .
Total Lead (Pb)(EPA 239.2) ................. ..
BDL -Below Detection Limit
Result
BDL
BDL
BDL
(mg/1)
BDL
BDL
BDL
0.05
BDL
BDL
29
BDL
BDL
BDL
0.10
BDL
A Unit of American Analytical Services, Inc.
Detection
Limit
5
0.1
5
(mg/1)
0.2
0.05
0.01
0.01
0.001
0.005
0.05
0.01
0.05
0.02
0.1
0.003
Conestoga-Rovers
Page 2 of 2
• •
May 20, 1998
Report No. 94733-1
Wastewater, composite, Monthly, Jadco-Hughes, Project #3669, W-3669-MC-
050698-095, 05/06/98, 13:15, received 05/07/98
RESULTS
Metals
Total Magnesium (Mg) (EPA 200. 7) ............. .
Total Manganese (Mn) (EPA 200. 7) ............. .
Total Mercury (Hg) (EPA 245 .1) ............... .
Total Nickel (Ni) (EPA 200. 7) ................ .
Total Potassium (K) (EPA 200. 7) .............. .
Total Selenium (Se) (EPA 270.2) .............. .
Total Silver (Ag) (EPA 200.7) ................ .
Total Sodium (Na) (EPA 200. 7) ................ .
Total Thallium (Tl) (EPA 279.2) .............. .
Total Vanadium (V) (EPA 200. 7) ............... .
Total Zinc (Zn) (EPA 200. 7) .................. .
BDL -Below Detection Limit
Result
(mg/1)
8.0
BDL
BDL
BDL
1. 7
BDL
BDL
11
BDL
BDL
0.22
Detection
Limit
(mg/1)
0.05
0.015
0.0002
0.02
0.2
0.005
0.01
0.05
0.002
0.02
0.02
Respectfully submitted, ~~~
CJ-:c~ G'Quality Assurance
• ••
ASI ANALYTICAL SERVICES, INC.
Conestoga-Rovers
1351 Oakbrook Drive
Suite 150
Norcross, GA 30093
ENVIRONMENTAL MONITORING & LABORATORY ANALYSIS
110 TECHNOLOGY PARKWAY • NORCROSS, GA 30092
[phone] • FAX [phone]
LABORATORY REPORT
May 20, 1998
Attention: Mr. Rob Brachowski Report No. 94733-2
Sample Description
Wastewater, grab, Monthly, Jadco-Hughes, Project #3669, W-3669-MC-050698-
096, 05/06/98, 13:50, received 05/07/98
RESULTS
Detection
Result Limit
pH (laboratory) (EPA 150 .1) .................. .
Total Cyanide (CN) (mg/1) (EPA 335.2) ......... .
7.79
BDL 0.01
Oil and Grease (mg/1) (EPA 1664) .......... ,, .. BDL 5
Volatile Organics (EPA 624) (ug/1 l (ug/1)
Acetone ..................................... . BDL 100
Benzene ..................................... . BDL 2
Bromodichloromethane ........................ , BDL 10
Bromoform ................................... . BDL 10
Bromomethane ................................ . BDL 10
2-Butanone .................................. . BDL 100
Carbon disulfide ............................ . BDL 5
Carbon tetrachloride ........................ . BDL 2
Chlorobenzene ................ · ............... . BDL 10
Chloroethane ................................ . BDL 5
Chloroform .................................. . 28 2
Chloromethane ............................... . BDL 10
Dibromochloromethane ........................ . BDL 10
1, 1-Dichloroethane .......................... . BDL 2
l, 2 -Dichloroethane .......................... . 2 2
1, 1-Dichloroethene .......................... . BDL 2
1,2-Dichloroethene (total) .................. . 6 2
BDL -Below Detection Limit
A Unit of American Analytical Services, Inc.
Conestoga-Rovers
Page 2 of 4
• •
May 20, 1998
Report No. 94733-2
Wastewater, grab, Monthly, Jadco-Hughes, Project #3669, W-3669-MC-050698-
096, 05/06/98, 13:50, received 05/07/98
RESULTS
Detection
Result Limit
Volatile Organics (EPA 624) (ug/1) (ug/1)
1, 2 -Dichloropropane ......................... . BDL 2
cis-1, 3-Dichloropropene ..................... . BDL 2
trans-1,3-Dichloropropene ................... . BDL 2
Ethylbenzene ................................ .
2-Hexanone .................................. .
BDL 2
BDL 50
Methylene chloride .......................... .
1,1,2,2-Tetrachloroethane ................... .
Tetrachloroethene ........................... .
BDL 10
BDL 2
BDL 2
Toluene ..................................... . BDL 2
1,1,1-Trichloroethane ....................... . BDL 2
1, 1, 2-Trichloroethane ....................... . BDL 2
Trichloroethene ............................. . 2 2
Vinyl chloride .............................. .
Xylenes ....................... · .............. .
BDL 10
BDL 2
Acid Extractable Organics (EPA 625) (ug/1) (ug/1)
Benzoic Acid ................................ . BDL 50
4-Chloro-3-methylphenol ..................... . BDL 10
2-Chlorophenol. ............................. . BDL 10
2, 4-Dichlorophenol. ......................... . BDL 10
2, 4-Dirnethylphenol .......................... . BDL 10
2,4-Dinitrophenol.., ........................ . BDL 50
4,6-Dinitro-2-methylphenol .................. . BDL 50
2-Methylphenol .............................. . BDL 10
4 -Methylphenol .............................. . BDL 10
2 -Nitrophenol ............................... . BDL 50
4-Nitrophenol. .............................. .
Pentachlorophenol ........................... .
BDL 50
BDL 20
Phenol ...................................... . BDL 10
2, 4, 6-Trichlorophenol. ...................... . BDL 10
2, 4, 5-Trichlorophenol ....................... . BDL 10
BDL -Below Detection Limit
Conestoga-Rovers
Page 3 of 4
• •
May 20, 1998
Report No. 94733-2
Wastewater, grab, Monthly, Jadco-Hughes, Project #3669, W-3669-MC-050698-
096, 05/06/98, 13:50, received 05/07/98
RESULTS
Detection
Result Limit
Base/Neutral Extractable Organics (EPA 625) (ug/1) (ug/1)
Acenaphthene ................................ .
Acenaphthylene .............................. .
Anthracene ................................... .
BDL 10
BDL 10
BDL 10
Benzo (a) anthracene .......................... . BDL 10
Benzo (b) fluoranthene ........................ . BDL 10
Benzo (k) fluoranthene ........................ . BDL 10
Benzo (a) pyrene .............................. .
Benzo (ghi) perylene .......................... .
Benzyl butyl phthalate ...................... .
Bis(2-chloroethyl)ether ..................... .
BDL 10
BDL 10
BDL 10
BDL 10
Bis(2-chloroethoxy)methane .................. . BDL 10
Bis(2-ethylhexyl)phthalate .................. .
Bis(2-chloroisopropyl)ether ................. .
BDL 10
BDL 10
4-Bromophenyl phenyl ether .................. .
4-Chloroaniline ............................. .
BDL 10
BDL 20
2 -Chloronaphthalene ......................... .
4-Chlorophenyl phenyl ether ................. .
Chrysene .................................... .
Dibenzo(a,h)anthracene ...................... .
BDL 10
BDL 10
BDL 10
BDL 10
Dibenzofuran ................................ . BDL 10
Di-n-butylphthalate ......................... .
1, 3-Dichlorobenzene ......................... .
BDL 10
BDL 10
1, 2-Dichlorobenzene ......................... . BDL 10
1, 4 -Dichlorobenzene ......................... . BDL 10
3,3'-Dichlorobenzidine ...................... . BDL 20
Diethylphthalate ............................ .
Dimethylphthalate ........................... .
BDL 10
BDL 10
2, 4-Dinitrotoluene .......................... . BDL 20
2, 6-Dinitrotoluene .......................... . BDL 20
Di-n-octylphthalate ......................... . BDL 10
Fluoranthene ................................ . BDL 10
Fluorene .................................... . ' BDL 10
Hexachlorobenzene ........................... . BDL 10
Hexachlorobutadiene ......................... . BDL 10
Hexachlorocyclopentadiene ................... . BDL 10
Hexachloroethane ............................ . BDL 2
Indeno ( 1, 2, 3 -cd) pyrene ...................... . BDL 10
Isophorone .................................. . BDL 10
BDL -Below Detection Limit
Conestoga-Rovers
Page 4 of 4
• •
May 20, 1998
Report No. 94733-2
Wastewater, grab, Monthly, Jadco-Hughes, Project #3669, W-3669-MC-050698-
096, 05/06/98, 13:50, received 05/07/98
RESULTS
Detection
Result Limit
Base/Neutral Extractable Organics (EPA 625) (ug/1) (ug/1)
2 -Methylnaphthalene ......................... .
Naphthalene ................................. .
2-Nitroaniline .............................. .
BDL 10
BDL 10
BDL 50
3-Nitroaniline .............................. . BDL 50
4-Nitroaniline .............................. . BDL 50
Nitrobenzene ................................ . BDL 10
N-Nitrosodiphenylamine ...................... .
N-Nitrosodi-n-propylamine ................... .
Phenanthrene ................................ .
BDL 10
BDL 10
BDL 10
Pyrene ...................................... .
1,2,4-Trichlorobenzene ...................... .
BDL 10
BDL 10
PCB' s (EPA 608) (ug/1 l (ug/1)
PCB 1016 .................................... . BDL 1.0
PCB 1221 .................................... . BDL 1.0
PCB 1232 .................................... . BDL 1.0
PCB 1242 .................................... . BDL 1.0
PCB 1248 .................................... . BDL 1.0
PCB 1254 .................................... . BDL 1.0
PCB 1260 ................................... : . BDL 1.0
BDL -Below Detection Limit
• •
ASI ANALYTICAL SERVICES, INC.
Conestoga-Rovers
l351 Oakbrook Drive
Suite 150
Norcross, GA 30093
ENVIRONMENTAL MONITORING & LABORATORY ANALYSIS
110 TECHNOLOGY PARKWAY • NORCROSS, GA 30092
[phone] • FAX [phone]
LABORATORY REPORT
May 20, l998
Attention: Mr. Rob Brachowski Report No. 94733-3
Sample Description
Water, grab, Monthly, Jadco-Hughes, Project #3669, Trip Blank, recieved
05/07/98
RESULTS
Detection
Result Limit
Volatile Organics (EPA 624) (ug/1) (ug/1)
Acetone ..................................... . BDL 100
Benzene ..................................... . BDL 2
Bromodichloromethane ........................ . BDL 10
Bromoform ................................... . BDL 10
Bromomethane ................................ . BDL 10
2-Butanone .................................. . BDL 100
Carbon disulfide ............................ . BDL 5
Carbon tetrachloride ........................ . BDL 2
Chlorobenzene ............................... . BDL 10
Chloroethane ................................ . BDL 5
Chloroform .................................. . BDL 2
Chloromethane ............................... . BDL 10
Dibromochloromethane ................. · ....... . BDL 10
l, 1-Dichloroethane .......................... . BDL 2
l, 2-Dichloroethane .......................... . BDL 2
l, l-Dichloroethene .......................... . BDL 2
l,2-Dichloroethene (total) .................. . BDL 2
l, 2 -Dichloropropane ......................... . BDL 2
cis-1,3-Dichloropropene ..................... . BDL 2
trans-1,3-Dichloropropene ................... . BDL 2
Ethylbenzene ................................ . BDL 2
2-Hexanone .................................. . BDL 50
BDL -Below Detection Limit
A Unit of American Analytical Services, Inc.
Conestoga-Rovers
Page 2 of 2
• •
May 20, 1998
Report No. 94733-3
Water, grab, Monthly, Jadco-Hughes, Project #3669, Trip Blank, recieved
05/07/98
RESULTS
Detection
Result Limit
Volatile Organics (EPA 624) (ug/1) (ug/1)
Methylene chloride .......................... . BDL 10
1,1,2,2-Tetrachloroethane ................... . BDL 2
Tetrachloroethene ........................... . BDL 2
Toluene ..................................... . BDL 2
1, 1, 1-Trichloroethane ....................... . BDL 2
1,1,2-Trichloroethane ....................... . BDL 2
Trichloroethene ............................. . BDL 2
Vinyl chloride .............................. . BDL 10
Xylenes ..................................... . BDL 2
BDL -Below Detection Limit
Respectfully submitted,
¥103/:ct~~
CLE~
Zbuality Assurance
• •
Page 1
Analytical Services Inc. Batch QC
For Report Number : 94 733
Base Neutrals
Matrix : Aqueous Batch # 38316 Method : EPA 625
Lab Control Information LC LCD LC %Recovery RPD
Analyte %Rec %Rec RPD Range Range
Acenaphthene 73 80 9 46 -118 0 -31
Acenaphthylene 82 84 3 33 -145 0 -40
Anthracene 84 93 10 27 -133 0 -40
Benzi dine 94 92 2 10 -200 0 -100
Benzo(a)anthracene 78 85 9 33 -143 0 -40
Benzo(b)fluoranthene 91 102 12 24 -159 0 -40
Benzo(k)fluoranthene 76 91 17 11 -162 0 -42
Benzo(a)pyrene 84 95 12 17 -163 0 -40
Benzo(ghi)perylene 73 82 11 10 -219 0 -56
Benzyl butyl phthalate 85 93 9 10 -152 0 -40
Bis(2-chloroethyl)ether 57 71 21 10 -150 0 -50
Bis(2-chloroethoxy)methane 73 89 20 33 -184 0 -43
Bis(2-ethylhexyl)phthalate 87 97 10 10 -158 0 -40
Bis(2-chloroisopropyl)ether 60 74 20 36 -166 0 -46
4-Bromophenyl phenyl ether 81 87 8 53 -127 0 -40
2-Chloronaphthalene 76 83 9 60 -118 0 -40
4-Chlorophenyl phenyl ether 79 88 11 28 -158 0 -33
Chrysene 75 86 15 17 -168 0 -48
Dibenzo(a,h)anthracene 80 89 12 10 -227 0 -70
Di-n-butylphthalate 88 97 9 10 118 0 -50
1,3-Dichlorobenzene 48 58 19 10 -172 0 -40
1,2-Dichlorobenzene 51 59 16 32 -129 0 -40
1,4-Dichlorobenzene 48 59 20 36 -97 0 -28
3,3'-Dichlorobenzidine 118 135 14 10 -262 0 -100
Diethylphthalate 65 72 11 10 -114 0 -40
Dimethylphthalate 39 43 11 0 -110 0 -40
2,4-Dinitrotoluene 76 86 12 24 -96 0 -38
2,6-Dinitrotoluene 78 90 14 50 -158 0 -40
Di-n-octylphthalate 103 120 15 10 -146 0 -50
Fluoranthene 83 91 9 26 -137 0 -40
Fluorene 74 87 16 59 -129 0 -40
Hexachlorobenzene 85 92 8 10 -152 0 -40
Hexachlorobutadiene 55 63 14 24 -116 0 -40
Hexachloroethane 45 54 19 40 -113 0 -40
Indeno(l,2,3-cd)pyrene 74 83 11 10 -171 0 -45
Isophorone 74 87 17 21 -196 0 -60
Naphthalene 60 69 14 21 -133 0 -40
Nitrobenzene 64 80 22 35 -180 0 -40
N-Nitrosodi-n-propylamine 70 85 19 41 -116 0 -38
Phenanthrene 82 89 9 54 -120 0 -40
Pyrene 78 87 10 26 -127 0 -31
1,2,4-Trichlorobenzene 58 66 13 44 -142 0 -28
• •
Page 2
Analytical Services Inc. Batch QC
Base Neutrals
Matrix : Aqueous Batch # 38316 Method : EPA 625
Matrix Spike Information MS MSD MS %Recovery RPD
Analyte %Rec %Rec RPD Range Range
Acenaphthene 77 67 13 46 -118 0 -31
Acenaphthylene 81 74 9 33 -145 0 -40
Anthracene 83 73 13 27 -133 0 -40
Benzidine 110 92 18 10 -200 0 -100
Benzo(a)anthracene 79 67 16 33 -143 0 -40
Benzo(b)fluoranthene 86 77 11 24 -159 0 -79
Benzo(k)fluoranthene 83 70 17 11 -162 0 -42
Benzo(a)pyrene 84 73 14 17 -163 0 -40
Benzo(ghi)perylene 74 64 15 10 -219 0 -56
Benzyl butyl phthalate 84 73 14 10 -152 0 -40
.Bis(2-chloroethyl)ether 67 60 11 10 -150 0 -50
Bis(2-chloroethoxy)methane 81 73 10 33 -184 0 -43
Bis(2-ethylhexyl)phthalate 87 75 15 10 -158 0 -40
Bis(2-chloroisopropyl)ether 72 65 10 36 -166 0 -46
4-Bromophenyl phenyl ether 79 69 14 53 -127 0 -40
2-Chloronaphthalene 80 72 11 60 -118 0 -40
4-Chlorophenyl phenyl ether 81 72 12 28 -158 0 -33
Chrysene 75 65 14 17 -168 0 -48
Dibenzo(a,h)anthracene 80 70 14 10 -227 0 -70
Di-n-butylphthalate 86 75 13 10 -118 0 -50
1,3-Dichlorobenzene 68 64 6 10 -172 0 -40
1,2-Dichlorobenzene 68 64 6 32 -129 0 -40
1,4-Dichlorobenzene 68 64 5 36 -97 0 -28
3,3'-Dichlorobenzidine 125 107 15 10 -262 0 -100
Diethylphthalate 64 63 0 10 -114 0 -40
Dimethylphthalate 37 41 11 0 -110 0 -40
2,4-Dinitrotoluene 79 69 14 24 -96 0 -38
2,6-Dinitrotoluene 81 71 14 50 -158 0 -40
Di-n-octylphthalate 101 88 13 10 -146 0 -50
Fluoranthene 80 70 14 26 -137 0 -40
Fluorene 77 68 13 59 -121 0 -40
Hexachlorobenzene 85 74 14 10 -152 0 -40
Hexachlorobutadiene 71 66 8 24 -116 0 -40
Hexachloroethane 65 61 6 40 -113 0 -40
Indeno(l,2,3-cd)pyrene 75 65 14 10 -171 0 -45
Isophorone 80 70 12 21 -196 0 -60
Naphthalene 72 65 11 21 -133 0 -40
Nitrobenzene 73 69 4 35 -180 0 -40
N-Nitrosodi-n-propylamine 79 71 11 41 -116 0 -38
Phenanthrene 80 70 13 54 -120 0 -40
Pyrene 78 67 15 26 -127 0 -31
1,2,4-Trichlorobenzene 72 66 9 44 -142 0 -28
• •
Analytical Services Inc. Batch QC
Surrogate Recovery
Base Neutrals
Matrix Aqueous Batch# 38316 Method
% Recovery Objectives
Sample
38316BLK
38316LCS
38316LCSD
94627-1
94627-2
94627-2MS
94627-2MSD
94582-1
AANote:
94582-2
,._,._Note:
94655-2
94704-1
94683-2
94733-2DUP
94733-2
94754-2
94774-1
94778-2D
Sl
File
B5722
B5723
B5724
B5728
B5729
B5730
B5731
B5736
BN only
B5737
BN only
AANote: 1:10
B5767
B5768
B5769
B5815
B5816
B5817
B5818
B5821
DILUTION
94778-2 A9217
Nitrobenzene-d5
Sl S2
59
71
85
35
75
78
70
61
BO
54
71
53
85
84
45
57
66
174
AANote: Matrix interference
35 -114
S3 S4
Page 3
EPA 625
S5 S6
•
Q.C. Information for Batch# 38316
•
Page 4
Printed: 05/20/98 20:37:25
Blank Results Information
Base Neutrals Method: EPA 625
Analyte
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
Benzo(ghi)~erylene
Benzyl butyl phthalate
Bis(2-chloroethyl)ether
Bis(2-chloroethoxy)methane
Bis(2-ethylhexyl)phthalate
Bis(2-chloroisopropyl)ether
4-Bromophenyl phenyl ether
4-Chloroaniline
2-Chloronaphthalene
4-Chlorophenyl phenyl ether
Chrysene
Dibenzo(a,h)anthracene
Dibenzofuran
Di-n-butylphthalate
1,3-Dichlorobenzene
1,2-Dichlorobenzene
1,4-Dichlorobenzene
3,3'-Dichlorobenzidine
Diethylphthalate
Dimethylphthalate
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Di-n-octylphthalate
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadiene
Hexachloroethane
Indeno(l,2,3-cd)pyrene
Isophorone
2-Methylnaphthalene
Naphthalene
2-Nitroaniline
3-Nitroaniline
4-Nitroaniline
Nitrobenzene
N-Nitrosodiphenylamine
N-Nitrosodi-n-propylamine
Phenanthrene
Pyrene
1.,2,4-Trichlorobenzene
Blank
Result
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
Detection
Limit
10
10
10
10
10
10
10
10
10
10
10
10
10
10
20
10
10
10
10
10
10
10
10
10
20
10
10
20
20
10
10
10
10
10
10
2
10
10
10
10
50
50
50
10
10
10
10
10
10
• •
Page 5
Q.C. Information for Batch# 38316 Printed: 05/20/98 20:37:25
Sample Batch Information
Base Neutrals Method: EPA 625
Preparation Preparation Analysis
Sample ID Date Time By Notes Date Time By Inst #
38316BLK 05/07/98 0900 SB/LR 05/08/98 2306 RAC 5971
38316LCS 05/07/98 0900 SB/LR 05/08/98 2341 RAC 5971
38316LCSD 05/07/98 0900 SB/LR 05/08/98 1217 RAC 5971
94627-2MS 05/07/98 0900 SB/LR 05/09/98 0348 RAC 5971
94627-2MSD 05/07/98 0900 SB/LR 05/09/98 0424 RAC 5971
94627-1 05/07/98 0900 SB/LR 05/09/98 0237 RAC 5971
94627-2 05/07/98 0900 SB/LR 05/09/98 0313 RAC 5971
94582-1 05/07/98 0900 SB/LR BN ONLY 05/09/98 0721 RAC 5971
94582-2 05/07/98 0900 SB/LR BN ONLY 05/09/98 0756 RAC 5971
94655-2 05/07/98 0900 SB/LR 05/10/98 1257 RAC 5971
94683-2 05/07/98 0900 SB/LR 05/10/98 0205 RAC 5971
94704-1 05/07/98 0900 SB/LR 05/10/98 0131 RAC 5971
94733-2 05/11/98 1000 LSJ 05/12/98 0352 RAC 5971
94754-2 05/11/98 1000 LSJ 05/12/98 0426 RAC 5971
94774-1 05/11/98 1000 LSJ 05/12/98 0500 RAC 5971
94778-2 05/11/98 1000 LSJ 05/14/98 2156 RAC 5970
94733-2DUP 05/11/98 1000 LSJ 05/12/98 0318 RAC 5971
94975 05/15/98 0900 J,S,L I I
94778-2D I I 05/12/98 0757 RAC 5971
• •
Analytical Services Inc. Batch QC
For Report Number :94733
Acids
Page 6
Matrix : Aqueous Batch # 38317 Method : EPA 625
Lab Control Information LC LCD LC %Recovery RPD
Analyte %Rec %Rec RPD Range Range
4-Chloro-3-methylphenol 56 48 14 23 -97 0 -42
2 -Chloropheno 1 64 43 40 27 -123 0 -40
2,4-Dichlorophenol 40 46 14 39 -135 0 -40
2,4-Dimethylphenol 73 51 36 32 -119 0 -40
2,4-Dinitrophenol 54 35 42 10 -191 0 -50
4,6-Dinitro-2-methylphenol 74 44 51 10 -181 0 -93
2-Nitrophenol 51 43 17 19 -182 0 -40
4-Nitrophenol 28 17 47 10 -80 0 -so
Pentachlorophenol 67 43 44 9 -103 0 -50
Phenol 27 20 33 12 -89 0 -42
2,4,6-Trichlorophenol 70 46 40 37 -144 0 -40
Matrix Spike Informat.ion MS MSD MS %Recovery RPD
Analyte %Rec %Rec RPD Range Range
4-Chloro-3-methylphenol 60 65 9 23 -97 0 -42
2-Chlorophenol 45 58 26 27 -123 0 -40
2,4-Dichlorophenol 48 62 24 39 -135 0 -40
2,4-Dimethylphenol 44 46 6 32 -119 0 -40
2,4-Dinitrophenol 21 24 17 10 -191 0 -50
4,6-Dinitro-2-methylphenol 55 57 5 10 -181 0 -93
2-Nitrophenol 44 57 27 19 -182 0 -40
4-Nitrophenol 31 34 8 10 -80 0 -so
Pentachlorophenol 50 54 7 9 -103 0 -50
Phenol 32 39 19 12 -89 0 -42
2,4,6-Trichlorophenol 48 61 22 37 -144 0 -40
Matrix
Sample
38317BLK
38317LCS
38317LCSD
94627-1
94627-2
94627-2MS
94627-2MSD
94655-2
94704-1
94655-2D
AANote:
94733-2DUP
94683-2D
A"""Note:
94733-2
94754-2
94774-1
94778-2
94683-2
""Note:
• •
Analytical Services Inc. Batch QC
Surrogate Recovery
Acids
Aqueous Batch# 38317 Method
Sl
S2
File
B5725
B5726
B5727
B5732
B5733
B5734
B5735
B5770
B5771
B5810
l:l00;SURR.
B5820
B5808
% Recovery Objectives
2-Fluorophenol
Phenol-d5
Sl
33
42
29
32
29
38
53
27
41
DILUTED OUT
59
37
S2
22
26
18
22
18
30
37
20
28
36
10
1:10 DILUTION
B5811
B5812
B5813
B5814
A9216
Matrix interference
55
46
44
59
4
34
28
31
29
5
S3
21 -100
10 -94
S4
Page 7
EPA 625
S5 S6
•
Q.C. Information for Batch# 38317
•
Page 8
Printed: 05/20/98 20:37:26
Blank Results Information
Acids Method: EPA 625
Analyte
Benzoic Acid
4-Chloro-3-methylphenol
2-Chlorophenol
2,4-Dichlorophenol
2,4-Dimethylphenol
2,4-Dinitrophenol
4,6-Dinitro-2-methylphenol
2-Methylphenol
4-Methylphenol
2-Nitrophenol
4-Nitrophenol
Pentachlorophenol
Phenol
2,4,6-Trichlorophenol
2,4,5-Trichlorophenol
Blank
Result
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
Detection
Limit
50
10
10
10
10
50
50
10
10
50
50
20
10
10
10
• •
Page 9
Q.C. Information for Batch# 38317 Printed: 05/20/98 20:37:26
Sample Batch Information
Acids Method : EPA 625
Preparation Preparation Analysis
Sample ID Date Time By Notes Date Time By Inst #
38317BLK 05/07/98 0900 SB/LR 05/09/98 1251 RAC 5971
38317LCS 05/07/98 0900 SB/LR 05/09/98 0126 RAC 5971
38317LCSD 05/07/98 0900 SB/LR 05/09/98 0202 RAC 5971
94627-2MS 05/07/98 0900 SB/LR 05/09/98 0610 RAC 5971
94627-2MSD 05/07/98 0900 SB/LR 05/09/98 0645 RAC 5971
94627-1 05/07/98 0900 SB/LR 05/09/98 0459 RAC 5971
94627-2 05/07/98 0900 SB/LR 05/09/98 0535 RAC 5971
94655-2 05/07/98 0900 SB/LR 05/10/98 0240 RAC 5971
94683-2 05/07/98 0900 SB/LR 05/14/98 2123 RAC 5970
94704-1 05/07/98 0900 SB/LR 05/10/98 0315 RAC 5971
94733-2 05/11/98 1000 LJS 05/12/98 0102 RAC 5971
94754-2 05/11/98 1000 LJS 05/12/98 0136 RAC 5971
94774-1 05/11/98 1000 LJS 05/12/98 0210 RAC 5971
94778-2 05/11/98 1000 LJS 05/12/98 0244 RAC 5971
94733-2DUP 05/11/98 1000 LJS 05/12/98 0723 RAC 5971
94655-2D I I 05/12/98 0028 RAC 5971
94655-2DD I I 05/12/98 0028 RAC 5971
94975 05/15/98 0900 J,S,L I I
94683-2D I I 05/12/98 2320 RAC 5971
Matrix: Aqueous
Lab Control Information
Analyte
BHC-gamma (Lindane)
Heptachlor
Aldrin
Dieldrin
Endrin
4,4'-DDT
Matrix Spike Information
Analyte
BHC-gamma (Lindane)
Hept:achlor
Aldrin
Dieldrin
Endrin
4, 4' -DDT
• •
Page
Analytical Services Inc. Batch QC
For Report Number :94733
Organochlorine Pesticides
Batch # 38406 Method : EPA 608
LC LCD LC %Recovery
%Rec %Rec RPD Range
44 51 13 32 -127
50 59 17 34 -111
47 52 10 42 -122
46 52 13 36 -146
47 54 13 30 -147
57 61 8 25 -160
MS MSD MS %Recovery
%Rec %Rec RPD Range
40 90 77 32 -127
46 110 82 34 -111
44 97 76 42 -122
42 95 78 36 -146
45 100 76 30 -147
58 122 72 25 -160
10
RPD
Range
0 -40
0 -40
0 -40
0 -40
0 -40
0 -40
RPD
Range
0 -40
0 -40
0 -40
0 -40
0 -40
0 -40
• •
Page 11
Analytical Services Inc. Batch QC
Surrogate Recovery
Organochlorine Pesticides
Matrix Aqueous Batch# 38406 Method EPA 608
%-Recovery Objectives
Sl Dibutylchlorendate 14 -161
S2 Tetrachloro-m-xylene 47 -113
S3 Decachlorobiphenyl 0 -139
Sample File Sl S2 S3 S4 S5 S6
38406BLK 050698060F 117 63 89
38406LCS 050698061F 136 81 95
38406LCSD 050698062F 104 61 71
94627-lMS 050698063F 131 72 90
94627-lMSD 050698064F 129 82 90
94627-1 050698065F 127 58 115
94627-2 050698066F 132 106 131
94626-1 050698067F 55 38
.,_....,Note: PCB ONLY
94733-2 051198057F 48 75
"'"'Note: PCB ONLY
94704-1 051198058F 95 83 90
94778-2 051198059F 37 45 20
94774-1 051198074F 135 71 77
94704-lDUP 051198075F 57 72 30
94822 051198076F 148 92 37
PCB
PCB
PCB
PCB
PCB
PCB
PCB
• •
Q.C. Information for Batch# 38406
Page 12
Printed: 05/20/98 20:37:26
Analyte
1016
1221
1232
1242
1248
1254
1260
Blank Results Information
Organochlorine Pesticides Method
Blank
Result
BDL
BDL
BDL
BDL
BDL
BDL
BDL
EPA 608
Detection
Limit
1.0
1. 0
1. 0
1.0
1.0
1.0
1.0
• •
Page 13
Q.C. Information for Batch# 38406 Printed: 05/20/98 20:37:26
Sample Batch Information
Organochlorine Pesticides Method : EPA 608
Preparation Preparation Analysis
Sample ID Date Time By Notes Date Time By Inst #
38406BLK 05/07/98 1500 SB/LR 05/08/98 2022 JQZ GC-3
38406LCS 05/07/98 1500 SB/LR 05/08/98 2022 JQZ GC-3
38406LCSD 05/07/98 1500 SB/LR 05/08/98 2116 JQZ GC-3
94627-lMS 05/07/98 1500 SB/LR 05/08/98 2116 JQZ GC-3
94627-lMSD 05/07/98 1500 SB/LR 05/08/98 2143 JQZ GC-3
94627-1 05/07/98 1500 SB/LR 05/08/98 2210 JQZ GC-3
94627-2 05/07/98 1500 SB/LR 05/08/98 2237 JQZ GC-3
94626-1 05/07/98 1500 SB/LR PCB ONLY 05/08/98 2305 JQZ GC-3
94733-2 05/11/98 1400 SB/LR PCB ONLY 05/13/98 0218 JQZ GC-3
94704-1 05/11/98 1400 SB/LR 05/13/98 0245 JQZ GC-3
94704-lDUP 05/11/98 1400 SB/LR 05/13/98 1318 JQZ GC-3
94774-1 05/11/98 1400 SB/LR 05/13/98 1223 JQZ GC-3
94778-2 05/11/98 1400 SB/LR 05/13/98 0339 JQZ GC-3
94822 05/11/98 1400 SB/LR PEST ONLY 05/13/98 1318 JQZ GC-3
94923 05/14/98 0900 SB/JW I I
94957 05/14/98 0900 SB/JW I I
94963 05/14/98 0900 SB/JW I I
94975 05/15/98 0900 J,S,L I I
• •
Page 14
Analytical Services Inc. Batch QC
For Report Number :94733
Volatile Organics
Matrix : Aqueous Batch # 38475 Method : EPA 624
Lab Control Information LC LCD LC %Recovery RPD
Analyte %Rec %Rec RPD Range Range
Benzene 98 105 6 37 -151 0 -20
Bromodichloromethane 100 '1'.11 11 35 -155 0 -20
Bromoform 106 118 10 45 -169 0 -20
Bromomethane 152 155 1 D -242 0 -20
Carbon tetrachloride 101 107 5 70 -140 0 -20
Chlorobenzene 97 108 11 37 -160 0 -20
Chloroethane 126 140 10 14 -230 0 -20
2-Chloroethylvinyl ether 93 86 8 D -305 0 -20
Chloroform 97 103 6 51 -138 0 -20
Chloromethane 97 110 13 D -273 0 -20
Dibromochloromethane 112 120 7 53 -149 0 -20
1,2-Dichlorobenzene 97 105 8 18 -190 0 -20
1,3-Dichlorobenzene 99 110 11 59 -156 0 -20
1,4-Dichlorobenzene 97 104 7 18 -190 0 -20
1,1-Dichloroethane 95 103 8 59 -155 0 -20
1,2-Dichloroethane 95 104 10 49 -155 0 -20
1,1-Dichloroethene 105 125 18 D -234 0 -20
trans-1,2-Dichloroethene 99 108 9 54 -156 0 -20
1,2-Dichloropropane 97 108 11 D -210 0 -20
cis-l,3~Dichloropropene 103 110 7 D -227 0 -20
trans-1,3-Dichloropropene 104 115 10 17 -183 0 -20
Ethylbenzene 97 106 9 37 -162 0 -20
Methylene chloride 99 104 5 D -221 0 -20
1,1,2,2-Tetrachloroethane 100 114 13 46 -157 0 -20
Tetrachloroethene 120 115 5 64 -148 0 -20
Toluene 105 112 7 47 -150 0 -20
1,1,1-Trichloroethane 99 104 5 52 -162 0 -20
1,1,2-Trichloroethane 111 119 7 52 -150 0 -20
Trichloroethene 105 112 6 71 -157 0 -20
Trichlorofluoromethane 112 119 6 17 -181 0 -20
Vinyl chloride 125 134 7 D -251 0 -20
• •
Page 15
Analytical Services Inc. Batch QC
Volatile Organics
Matrix : Aqueous Batch # 38475 Method : EPA 624
Matrix Spike Information MS MSD MS %Recovery RPD
Analyte %Rec %Rec RPD Range Range
Benzene 105 106 1 37 -151 0 -20
Bromodichloromethane 99 110 10 35 -155 0 -20
Bromoform 121 115 6 45 -169 0 -20
Bromomethane 87 88 1 D -242 0 -20
Carbon tetrachloride 109 106 2 70 -140 0 -20
Chlorobenzene 110 108 1 37 -160 0 -20
Chloroethane 118 121 3 14 -230 0 -20
2-Chloroethylvinyl ether 2 3 31 D -305 0 -20
Chloroform 103 97 6 51 -138 0 -20
Chloromethane 71 77 9 D -273 0 -20
Dibromochloromethane 105 119 13 53 -149 0 -20
1,2-Dichlorobenzene 111 110 2 18 -190 0 -20
1,3-Dichlorobenzene 113 108 5 59 -156 0 -20
1,4-Dichlorobenzene 107 107 0 18 -190 0 -20
1,1-Dichloroethane 105 103 2 59 -155 0 -20
1,2-Dichloroethane 109 110 1 49 -155 0 -20
1,1-Dichloroethene 140 114 20 D -234 0 -20
trans-1,2-Dichloroethene 108 102 6 54 -156 0 -20
1,2-Dichloropropane 101 111 9 D -210 0 -20
cis-1,3-Dichloropropene 102 110 7 D -227 0 -20
trans-1,3-Dichloropropene 103 113 9 17 -183 0 -20
Ethylbenzene 109 108 1 37 -162 0 -20
Methylene chloride 111 108 3 D -221 0 -20
1,1,2,2-Tetrachloroethane 113 109 3 46 -157 0 -20
Tetrachloroethene 106 118 10 64 -148 0 -20
Toluene 100 112 12 47 -150 0 -20
1,1,1-Trichloroethane 105 106 0 52 -162 0 -20
1,1,2-Trichloroethane 106 123 15 52 -150 0 -20
Trichloroethene 112 120 7 71 -157 0 -20
Trichlorofluoromethane 109 106 2 17 -181 0 -20
Vinyl chloride 101 104 3 D -251 0 -20
• •
Analytical Services Inc. Batch QC
Surrogate Recovery
Volatile Organics
Matrix Aqueous Batch# 38475 Method
% Recovery Objectives
Sl l,2-Dichloroethane-d4 76 -
S2 Toluene-dB 88 -
S3 Ethylbenzene-dl0 75 -
S4 4-Bromofluorobenzene 86 -
Sample File Sl S2 S3 S4
38475BLK1 A3203 93 102 100 97
38475LCS A3227 93 103 99 96
38475LCSD A3228 92 104 101 101
94733-2 A3252 97 95 97 102
94733-2DUP A3253 97 91 99 98
94733-2MS A3254 95 93 103 97
94733-2MSD A3255 92 104 100 96
94733-3 A3256 98 93 97 97
38475BLK2 A3245 95 101 100 104
Page 16
EPA 624
119
110
115
115
S5 S6
•
Q.C. Information for Batch# 38475
•
Page 17
Printed: 05/20/98 20:37:28
Blank Results Information
Volatile Organics Method: EPA 624
Analyte
Acetone
Benzene
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Dibromochloromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethene
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethylbenzene
2-Hexanone
Methylene chloride
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,l-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Vinyl chloride
Xylenes
Blank
Result
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
Detection
Limit
100
2
10
10
10
100
5
2
10
5
2
10
10
2
2
2
2
2
2
2
2
50
10
2
2
2
2
2
2
10
2
• •
Q.C. Information for Batch# 38475
Page 18
Printed: 05/20/98 20:37:28
Sample Batch Information
Volatile Organics Method EPA 624
Preparation Preparation Analysis
Sample ID Date Time By Notes Date Time By
38475BLK1 I I 05/11/98 0957 LLP
38475LCS I I 05/11/98 2017 LLP
38475LCSD I I 05/11/98 2042 LLP
94733-2 I I 05/11/98 1410 LLP
94733-2DUP I I 05/11/98 1434 LLP
94733-2MS I I 05/11/98 1459 LLP
94733-2MSD I I 05/11/98 1523 LLP
94733-3 I I 05/11/98 1548 LLP
38475BLK2 I I 05/12/98 1143 LLP
Inst #
VOAl
VOAl
VOAl
VOAl
VOAl
VOAl
VOAl
VOAl
VOAl
QC Batch
Batch
Number
37841
A"'Note
37841
,.."Note
38335
,,._,...Note
38335
38335
38337
........ Note
38337
38337
38337
......... Note
38337
......... Note
38337
38337
AANote
38337
38337
""Note
38337
......... Note
38337
38337
38337
......... Note
38337
38337
38337
38337
38337
38337
38403
38425
"""Note
• •
Analytical Services Inc. Batch QC
For Report Number :94733
General Information
Analysis
Analyte Method
Hg EPA 245.1
MS/MSD info. for 94627-2
Hg EPA 245.1
MS/MSD info. for 94733-1
Se EPA 270.2
BATCH PASSES ON LCS/LCSD.
Tl EPA 279.2
Pb EPA 239.2
Ag EPA 200.7
Batch passes on LCS/LCSD/MS
Al EPA 200.7
As EPA 200.7
Ba EPA 200.7
BATCH PASSES ON LCS/LCSD/PDS
Be EPA 200.7
BATCH PASSES ON LCS/LCSD
Ca
Cd
BATCH
Co
Cr
BATCH
EPA 200.7
EPA 200.7
PASSES ON LCS/LCSD/PDS
EPA 200.7
EPA 200.7
PASSES ON LCS/LCSD/PDS
Cu EPA 200.7
BATCH PASSES ON LCS/LCSD/PDS
Fe
Mg
EPA 200.7
EPA 200.7
EPA 200.7
Matrix
Aqueous <
... · Aqueous <
Aqueous <
Aqueous <
Aqueous <
Aqueous <
Aqueous <
Aqueous <
Aqueous <
Aqueous <
Aqueous
Aqueous·
Aqueous
Aqueous
<
<
<
<
Aqueous <
Aqueous
Aqueous
Aqueous
<
<
< Mn
BATCH PASSES ON LCS/LCSD/MS/PDS
Na
Ni
Sb
V
Zn
K
pH
EPA 200.7
EPA 200.7
EPA 200.7
EPA 200.7
EPA 200.7
EPA 200.7
EPA 150.1
EPA 1664
Aqueous <
Aqueous <
Aqueous <
Aqueous <
Aqueous <
Aqueous <
Aqueous
Aqueous
Page 19
Blank
Result
0.0002
0.0002
0.0050
0.0020
0.0020
0.0100
0.1000
0.0100
0.0100
0.0010
0.0500
0.0030
0.0400
0.0100
0.0200
0.0400
0.0500
0.0100
Prep.
Method
0/G
LACK OF SAMPLE FOR MSD. BATCH PASSES ON LCS/LCSD
0.0500
0.0200
0.0060
0.0200
0.0200
0.0500
0.0000
0.0000
AND MS.
QC Batch
Batch
Number
38435
38435
38440
38467
38513
• •
Analytical Services Inc. Batch QC
For Report Number :94733
General Information
Analysis
Analyte Method Matrix
BOD<5 hi SM 5210 B Aqueous <
BOD<5 low SM 5210 B Aqueous <
CN EPA 335.2 Aqueous <
TSS EPA 160.2 Aqueous <
N EPA 350.2 Aq/Solid <
Lab Control Information
Batch LC LCD LC
Number Analyte Method %Rec %Rec RPD
37841 Hg EPA 245.1 78 81 4
37841 Hg EPA 245.1 78 81 4
38335 Se EPA 270.2 100 102 2
38335 Tl EPA 279.2 117 112 4
38335 Pb EPA 239.2 105 108 3
38337 Ag EPA 200.7 100 105 5
38337 Al EPA 200.7 91 89 2
38337 As EPA 200.7 94 92 2
38337 Ba EPA 200.7 92 89 3
38337 Be EPA 200.7 97 94 3
38337 Ca EPA 200.7 98 95 3
38337 Cd EPA 200.7 110 110 0
38337 Co EPA 200.7 96 93 3
38337 Cr EPA 200.7 95 93 2
38337 Cu EPA 200.7 90 96 6
38337 Fe EPA 200.7 89 87 2
38337 Mg EPA 200.7 96 92 4
38337 Mn EPA 200.7 96 93 3
38337 Na EPA 200.7 92 88 4
38337 Ni EPA 200.7 96 96 0
38337 Sb EPA 200.7 95 89 7
38337 V EPA 200.7 91 88 3
38337 Zn EPA 200.7 98 110 12
38337 K EPA 200.7 92 89 3
38403 pH EPA 150.1 98 98 0
38425 O/G EPA 1664 78 76 3
38435 BOD<5 hi SM 5210 B 101 100 1
38435 BOD<5 low SM 5210 B 98 98 0
38440 CN EPA 335.2 81 80 1
38467 TSS EPA 160.2 95 100 5
38513 N EPA 350.2 98 102 4
Page 20
Blank Prep.
Result Method
5.0000
5.0000
0.0200
5.0000
0.1000
%Recovery RPD
Range Range
76 -124 0 -20
76 -124 0 -20
76 -124 0 -20
76 -124 0 -20
76 -124 0 -20
85 -115 0 -20
85 -115 0 -20
85 -115 0 -20
85 -115 0 -20
85 -115 0 -20
85 -115 0 -20
85 -115 0 -20
85 -115 0 -20
85 -115 0 -20
85 -115 0 -20
85 -115 0 -20
85 -115 0 -20
85 -115 0 -20
85 -115 0 -20
85 -115 0 -20
85 -115 0 -20
85 -115 0 -20
85 -115 0 -20
85 -115 0 -20
80 -120 0 -20
32 -103 0 -40
81 -118 0 -30
81 -118 0 -30
75 -125 0 -30
60 -140 0 -40
75 -125 0 -30
• •
Page 21
Analytical Services Inc. Batch QC
For Report Number :94733
Matrix Spike Information
Batch MS MSD MS %Recovery RPD
Number Analyte Method %Rec %Rec RPD Range Range
37841 Hg EPA 245.1 96 104 8 76 -124 0 -20
37841 Hg EPA 245.1 93 90 3 76 -124 0 -20
38335 Se EPA 270.2 27 27 0 76 -124 0 -20
38335 Tl EPA 279.2 100 100 0 76 -124 0 -20
38335 Pb EPA 239.2 78 85 9 76 -124 0 -20
38337 Ag EPA 200.7 115 125 8 85 -115 0 -20
38337 Al EPA 200.7 110 110 0 85 -115 0 -20
38337 As EPA 200.7 110 110 0 85 -115 0 -20
38337 Ba EPA 200.7 120 120 0 85 -115 0 -20
38337 Be EPA 200.7 120 120 0 85 -115 0 -20
38337 Ca EPA 200.7 110 110 0 85 -115 0 -20
38337 Cd EPA 200.7 120 130 8 85 -115 0 -20
38337 Co EPA 200.7 110 110 0 85 -115 0 -20
38337 Cr EPA 200.7 110 120 9 85 -115 0 -20
38337 Cu EPA 200.7 110 120 9 85 -115 0 -20
38337 Fe EPA 200.7 110 110 0 85 -115 0 -20
38337 Mg EPA 200.7 110 110 0 85 -115 0 -20
38337 Mn EPA 200.7 110 120 9 85 -115 0 -20
38337 Na EPA 200.7 110 110 0 85 -115 0 -20
38337 Ni EPA 200.7 110 110 0 85 -115 0 -20
38337 Sb EPA 200.7 110 110 0 85 -115 0 -20
38337 V EPA 200.7 110 110 0 85 -115 0 -20
38337 Zn EPA 200.7 100 100 0 85 -115 0 -20
38337 K EPA 200.7 110 120 9 85 -115 0 -20
38425 0/G EPA 1664 83 0 NC 32 -103 0 -40
38440 CN EPA 335.2 85 84 . 1 75 -125 0 -30
38467 TSS EPA 160.2 78 90 14 60 -140 0 -40
38513 N EPA 350.2 100 98 2 75 -125 0 -30
Post Digestion Spike Information
Batch PDS %Recovery
Number Analyte Method %Rec Range
38335 Se EPA 270.2 76 76 -·124
38335 Tl EPA 279.2 105 76 -124
38335 Pb EPA 239.2 97 76 -124
38337 Ag EPA 200.7 76 85 -115
38337 Al EPA 200.7 92 85 -115
38337 As EPA 200.7 98 BS -115
38337 Ba EPA 200.7 94 85 -115
38337 Be EPA 200.7 100 85 -115
38337 Ca EPA 200.7 104 85 -115
38337 Cd EPA 200.7 114 85 -115
38337 Co EPA 200.7 100 85 -115
38337 Cr EPA 200.7 100 85 -115
38337 Cu EPA 200.7 92 85 -115
Post Digestion Spike
Batch
Number Analyte
38337 Fe
38337 Mg
38337 Mn
38337 Na
38337 Ni
38337 Sb
38337 V
38337 Zn
38337 K
• •
Analytical Services Inc. Batch QC
For Report Number :94733
Information
PDS
Method %Rec
EPA 200.7 88
EPA 200.7 100
EPA 200.7 98
EPA 200.7 98
EPA 200.7 100
EPA 200.7 98
EPA 200.7 94
EPA 200.7 102
EPA 200.7 96
Unspiked Sample Duplicate Information
Sample Batch Sample 1
Number Analyte Method RPD RPD
38403 pH EPA 150.1 0 0
38435 BOD<5 hi SM 5210 B 6
38440 CN EPA 335.2 0 0
38467 TSS EPA 160.2 0 0
38513 N EPA 350.2 0 0
Page 22
%Recovery
Range
85 -115
85 -115
85 -115
85 -115
85 -115
85 -115
85 -115
85 -115
85 -115
2 RPD
Range
0 -20
0 -30
0 -30
0 -40
0 -30
• •
Page 23
Q.C. Information for Batch# 37841 For Report Number :94733
Sample Batch Information
Analysis : Hg, Hg
Preparation Preparation Analysis
Sample ID Tag Date Time By Notes Date Time By Inst
37841BLANK HG 05/08/98 0825 FBS 05/08/98 1311 FBS HGl
37841LCS HG 05/08/98 0825 FBS 05/08/98 1314 FBS HGl
37841LCSD HG 05/08/98 0825 FBS 05/08/98 1316 FBS HGl
94627-2MS HG 05/08/98 0825 FBS 05/08/98 1319 FBS HGl
94627-2MSD HG 05/08/98 0825 FBS 05/08/98 1321 FBS HGl
94627-lDUP HG 05/08/98 0825 FBS 05/08/98 1323 FBS HGl
94733-1 HG 05/08/98 0825 FBS 05/08/98 1330 FBS HGl
94539-15 HG 05/08/98 0825 FBS 05/08/98 1340 FBS HGl
94539-16 HG 05/08/98 0825 FBS 05/08/98 1343 FBS HGl
94583-1 HG 05/08/98 0825 FBS 05/08/98 1352 FBS HGl
94583-2 HG 05/08/98 0825 FBS 05/08/98 1355 FBS HGl
94583-3 HG 05/08/98 0825 FBS 05/08/98 1357 FBS HGl
94583-4 HG 05/08/98 0825 FBS 05/08/98 1359 FBS HGl
94583-5 HG 05/08/98 0825 FBS 05/08/98 1402 FBS HGl
94603-1 HG 05/08/98 0825 FBS 05/08/98 1415 FBS HGl
94603-2 HG 05/08/98 0825 FBS 05/08/98 1418 FBS HGl
94603-3 HG 05/08/98 0825 FBS 05/08/98 1420 FBS HGl
94603-4 HG 05/08/98 0825 FBS 05/08/98 1422 FBS HGl
94603-5 HG 05/08/98 0825 FBS 05/08/98 1425 FBS HGl
94626-1 HG 05/08/98 0825 FBS 05/08/98 1453 FBS HGl
94627-1 HG 05/08/98 0825 FBS 05/08/98 1328 FBS HGl
94627-2 HG 05/08/98 0825 FBS 05/08/98 1326 FBS HGl
94633-1 HG 05/08/98 0825 FBS AKA 94539-18 05/08/98 1345 FBS HGl
94633-2 HG 05/08/98 0825 FBS AKA 94539-19 05/08/98 1347 FBS HGl
94633-3 HG 05/08/98 0825 FBS AKA 94539-20 05/08/98 1350 FBS HGl
94539-14 HG 05/08/98 0825 FBS 05/08/98 1333 FBS HGl
94733-lMS HG 05/08/98 0825 FBS 05/08/98 1437 FBS HGl
94733-lMSD HG 05/08/98 0825 FBS 05/08/98 1439 FBS HGl
94733-lDUP HG 05/08/98 0825 FBS 05/08/98 1435 FBS HGl
• •
Page 24
Q.C. Information for Batch# 38335 For Report Number :94733
Sample Batch Information
Analysis : Se, Tl, Pb
Preparation Preparation Analysis
Sample ID Tag Date Time By Notes Date Time By Inst
38335BLANK Se 05/12/98 1045 DCF GFAA 05/14/98 0950 DCM AAl
383_35LCS Se 05/12/98 1045 DCF GFAA 05/14/98 0950 DCM AAl
38335LCSD Se 05/12/98 1045 DCF GFAA 05/14/98 0950 DCM AAl
94733-lMS Se 05/12/98 1045 DCF GFAA 05/14/98 0950 DCM AAl
94733-lMSD Se 05/12/98 1045 DCF GFAA 05/14/98 0950 DCM AAl
94663-3PDS Se 05/12/98 1045 DCF GFAA 05/14/98 0950 DCM AAl
94663-3DUP Se 05/12/98 1045 DCF GFAA 05/14/98 0950 DCM AAl
94733-1 Se 05/12/98 1045 DCF GFAA 05/14/98 0950 DCM AAl
94759-1 Se 05/12/98 1045 DCF GFAA 05/14/98 0950 DCM AAl
94763-1 Se 05/12/98 1045 DCF GFAA 05/14/98 0950 DCM AAl
94763-2 Se 05/12/98 1045 DCF GFAA 05/14/98 0950 DCM AAl
94776 Se 05/12/98 1045 DCF GFAA 05/14/98 0950 DCM AAl
94626-1 Se 05/12/98 1045 DCF GFAA 05/14/98 0950 DCM AAl
94663-1 Se 05/12/98 1045 DCF GFAA 05/14/98 0950 DCM AAl
94663-2 Se 05/12/98 1045 DCF GFAA 05/14/98 0950 DCM AAl
94663-3 Se 05/12/98 1045 DCF GFAA 05/14/98 0950 DCM AAl
94683-1 Se 05/12/98 1045 DCF GFAA 05/14/98 0950 DCM AAl
94705-1 Se 05/12/98 1045 DCF GFAA 05/14/98 0950 DCM AAl
94722-7 Se 05/12/98 1045 DCF GFAA 05/14/98 0950 DCM AAl
94752 Se 05/12/98 1045 DCF GFAA 05/14/98 0950 DCM AAl
94780-1 Se 05/12/98 1045 DCF GFAA 05/14/98 0950 DCM AAl
94805-1 Se 05/12/98 1045 DCF GFAA 05/14/98 0950 DCM AAl
94805-2 Se 05/12/98 1045 DCF GFAA 05/14/98 0950 DCM AAl
94821 Se 05/12/98 1045 DCF GFAA 05/14/98 0950 DCM AAl
94822 Se 05/12/98 1045 DCF GFAA 05/14/98 0950 DCM AAl
94830-1 Se 05/12/98 1045 DCF GFAA 05/14/98 0950 DCM AAl
94865-7 Se 05/12/98 1045 DCF GFAA 05/14/98 0950 DCM AAl
38335BLANK As 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AAl
38335LCS As 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AAl
38335LCSD As 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AAl
94733-lMS As 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AAl
94733-lMSD As 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AAl
94663-3PDS As 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AAl
94663-3DUP As 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AAl
94733-1 As 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AAl
94759-1 As 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AAl
94763-1 As 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AAl
94763-2 As 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AAl
94776 As 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AAl
94626-1 As 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AAl
94663-1 As 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AAl
94663-2 As 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AAl
94663-3 As 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AAl
94683-1 As 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AAl
94705-1 As 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AAl
94722-7 As 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AAl
94752 As 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AAl
94780-1 As 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AAl
• •
Page 25
Q.C. Information for Batch# 38335 For Report Number :94733
Sample Batch Information
Analysis : Se, Tl, Pb
Preparation Preparation Analysis
Sample ID Tag Date Time By Notes Date Time By Inst
94805-1 As 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AAl
94805-2 As 05/12/98 1045 DCF .GFAA 05/15/98 1130 DCM AAl
94821 As 05/12/98 1045 ·,ncr,· GFAA 05/15/98 1130 DCM AAl
94822 As 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AAl
94830-1 As 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AAl
94865-7 As 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AAl
38335BLANK Tl 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AA2
38335LCS Tl 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AA2
38335LCSD Tl 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AA2
94733-lMS Tl 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AA2
94733-lMSD Tl 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AA2
94663-3PDS Tl 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AA2
94663-3DUP Tl 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AA2
94733-1 Tl 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AA2
94759-1 Tl 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AA2
94763-1 Tl 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AA2
94763-2 Tl 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AA2
94776 Tl 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AA2
94626-1 Tl 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AA2
94663-1 Tl 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AA2
94663-2 Tl 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AA2
94663-3 Tl 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AA2
94683-1 Tl 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AA2
94705-1 Tl 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AA2
94722-7 Tl 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AA2
94752 Tl 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AA2
94780-1 Tl 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AA2
94805-1 Tl 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AA2
94805-2 Tl 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AA2
94821 . Tl 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AA2
94822 Tl 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AA2
94830-1 Tl 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AA2
94865-7 Tl 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AA2
38335BLANK Tl 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AA2
38335LCS Tl 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AA2
38335LCSD Tl 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AA2
94733-lMS Tl 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AA2
94733-lMSD Tl 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AA2
94663-3PDS Tl 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AA2
94663-3DUP Tl 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AA2
94733-1 Tl 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AA2
94759-1 Tl 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AA2
94763-1 Tl 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AA2
94763-2 Tl 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AA2
94776 Tl 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AA2
94626-1 Tl 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AA2
94663-1 Tl 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AA2
94663-2 Tl 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AA2
• •
Page 26
Q.C. Information for Batch# 38335 For Report Number :94733
Sample Batch Information
Analysis : Se, Tl, Pb
Preparation Preparation Analysis
Sample ID Tag Date Time By Notes Date Time By Inst
94663-3 Tl 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AA2
94683-1 Tl 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AA2
94705-1 Tl 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AA2
94722-7 Tl 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AA2
94752 Tl 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AA2
94780-1 Tl 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AA2
94805-1 Tl 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AA2
94805-2 Tl 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AA2
94821 Tl 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AA2
94822 Tl 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AA2
94830-1 Tl 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AA2
94865-7 Tl 05/12/98 1045 DCF GFAA 05/15/98 1130 DCM AA2
38335BLANK Pb 05/12/98 1045 DCF GFAA 05/15/98 1800 DCM AA2
38335LCS Pb 05/12/98 1045 DCF GFAA 05/15/98 1800 DCM AA2
38335LCSD Pb 05/12/98 1045 DCF GFAA 05/15/98 1800 DCM AA2
94733-lMS Pb 05/12/98 1045 DCF GFAA 05/15/98 1800 DCM AA2
94733-lMSD Pb 05/12/98 1045 DCF GFAA 05/15/98 1800 DCM AA2
94663-3PDS Pb 05/12/98 1045 DCF GFAA 05/15/98 1800 DCM AA2
94663-3DUP Pb 05/12/98 1045 DCF GFAA 05/15/98 1800 DCM AA2
94733-1 Pb 05/12/98 1045 DCF GFAA 05/15/98 1800 DCM AA2
94759-1 Pb 05/12/98 1045 DCF GFAA 05/15/98 1800 DCM AA2
94763-1 Pb 05/12/98 1045 DCF GFAA 05/15/98 1800 DCM AA2
94763-2 Pb 05/12/98 1045 DCF GFAA 05/15/98 1800 DCM AA2
94776 Pb 05/12/98 1045 DCF GFAA 05/15/98 1800 DCM AA2
94626-1 Pb 05/12/98 1045 DCF GFAA 05/15/98 1800 DCM AA2
94663-1 Pb 05/12/98 1045 DCF GFAA 05/15/98 1800 DCM AA2
94663-2 Pb 05/12/98 1045 DCF GFAA 05/15/98 1800 DCM AA2
94663-3 Pb 05/12/98 1045 DCF GFAA 05/15/98 1800 DCM AA2
94683-1 Pb 05/12/98 1045 DCF GFAA 05/15/98 1800 DCM AA2
94705-1 Pb 05/12/98 1045 DCF GFAA 05/15/98 1800 DCM AA2
94722-7 Pb 05/12/98 1045 DCF GFAA 05/15/98 1800 DCM AA2
94752 Pb 05/12/98 1045 DCF GFAA . 05/15/98 1800 DCM AA2
94780-1 Pb 05/12/98 1045 DCF GFAA 05/15/98 1800 DCM AA2
94805-1 Pb 05/12/98 1045 DCF GFAA 05/15/98 1800 DCM AA2
94805-2 Pb 05/12/98 1045 DCF GFAA 05/15/98 1800 DCM AA2
94821 Pb 05/12/98 1045 DCF GFAA 05/15/98 1800 DCM AA2
94822 Pb 05/12/98 1045 DCF GFAA 05/15/98 1800 DCM AA2
94830-1 Pb 05/12/98 1045 DCF GFAA 05/15/98 1800 DCM AA2
94865-7 Pb 05/12/98 1045 DCF GFAA 05/15/98 1800 DCM AA2
38335BLANK Cd 05/12/98 1045 DCF GFAA 05/18/98 0721 DCM AAl
38335LCS Cd 05/12/98 1045 DCF GFAA 05/18/98 0721 DCM AAl
38335LCSD Cd 05/12/98 1045 DCF GFAA 05/18/98 0721 DCM AAl
94733-lMS Cd 05/12/98 1045 DCF GFAA 05/18/98 0721 DCM AAl
94733-lMSD Cd 05/12/98 1045 DCF GFAA 05/18/98 0721 DCM AAl
94663-3PDS Cd 05/12/98 1045 DCF GFAA 05/18/98 0721 DCM AAl
94663-3DUP Cd 05/12/98 1045 DCF GFAA 05/18/98 0721 DCM AAl
94733-1 Cd 05/12/98 1045 DCF GFAA 05/18/98 0721 DCM AAl
·94759-1 Cd 05/12/98 1045 DCF GFAA 05/18/98 0721 DCM AAl
• •
Page 27
Q.C. Information for Batch# 38335 For Report Number :94733
Sample Batch Information
Analysis : Se, Tl, Pb
Preparation Preparation Analysis
Sample ID Tag Date Time By Notes Date Time By Inst
94763-1 Cd 05/12/98 1045 DCF GFAA 05/18/98 0721 DCM AAl
94763-2 Cd 05/12/98 1045 DCF GFAA 05/18/98 0721 DCM AAl
94776 Cd 05/12/98 1045 DCF GFAA 05/18/98 0721 DCM AAl
94626-1 Cd 05/12/98 1045 DCF GFAA 05/18/98 0721 DCM AAl
94663-1 Cd 05/12/98 1045 DCF GFAA 05/18/98 0721 DCM AAl
94663-2 Cd 05/12/98 1045 DCF GFAA 05/18/98 0721 DCM AAl
94663-3 Cd 05/12/98 1045 DCF GFAA 05/18/98 0721 DCM AAl
94683-1 Cd 05/12/98 1045 DCF GFAA 05/18/98 0721 DCM AAl
94705-1 Cd 05/12/98 1045 DCF GFAA 05/18/98 0721 DCM AAl
94722-7 Cd 05/12/98 1045 DCF GFAA 05/18/98 0721 DCM AAl
94752 Cd 05/12/98 1045 DCF GFAA 05/18/98 ·0721 DCM AAl
94780-1 Cd 05/12/98 1045 DCF GFAA 05/18/98 0721 DCM AAl
94805-1 Cd 05/12/98 1045 DCF GFAA 05/18/98 0721 DCM AAl
94805-2 Cd 05/12/98 1045 DCF GFAA 05/18/98 0721 DCM AAl
94821 Cd 05/12/98 1045 DCF GFAA 05/18/98 0721 DCM AAl
94822 Cd 05/12/98 1045 DCF GFAA 05/18/98 0721 DCM AAl
94830-1 Cd 05/12/98 1045 DCF GFAA 05/18/98 0721 DCM AAl
94865-7 Cd 05/12/98 1045 DCF GFAA 05/18/98 0721 DCM AAl
• •
Q.C. Information for Batch# 38337
Page 28
For Report Number :94733
Analysis
Sample ID
38337BLANK
38337LCS
38337LCSD
94733-lMS
94733-lMSD
94719-lPDS
94733-lDUP
94719-1
94719-2
94719-3
94719-4
94726-1
94731
94750-4
94750-5
94750-6
94754-1
94763-1
94763-2
94771-1
94771-2
94776
94827
94733-1
94624
94306-lRR
94683-1
Sample Batch Information
Ag, Al, As, Ba, Be, Ca, Cd, Co, Cr, Cu, Fe, Mg, Mn, Na, Ni, Sb
V Zn K
Preparation
Tag Date Time By
05/12/98 1215 RCP
05/12/98 1215 RCP
05/12/98 1215 RCP
05/12/98 1215 RCP
05/12/98 1215 RCP
05/12/98 1215 RCP
05/12/98 1215 RCP
05/12/98 1215 RCP
05/12/98 1215 RCP
05/12/98 1215 RCP
05/12/98 1215 RCP
05/12/98 1215 RCP
05/12/98 1215 RCP
05/12/98 1215 RCP
05/12/98 1215 RCP
05/12/98 1215 RCP
05/12/98 1215 RCP
05/12/98 1215 RCP
05/12/98 1215 RCP
05/12/98 1215 RCP
05/12/98 1215 RCP
05/12/98 1215 RCP
05/12/98 1215 RCP
05/12/98 1215 RCP
05/12/98 1215 RCP
05/12/98 1215 RCP
05/12/98 1215 RCP
Preparation
Notes
TRACE
TRACE
TRACE
TRACE
TRACE
TRACE
TRACE
TRACE
TRACE
TRACE
TRACE
TRACE
TRACE
TRACE
TRACE
TRACE
TRACE
TRACE
TRACE
TRACE
TRACE
TRACE
TRACE
TRACE
TRACE
TRACE
TRACE
Analysis
Date Time By
05/13/98 0906 MCW
05/13/98 0910 MCW
05/13/98 0914 MCW
05/13/98 0918 MCW
05/13/98 0921 MCW
05/13/98 0925 MCW
05/13/98 0929 MCW
05/13/98 0936 MCW
05/13/98 0940 MCW
05/13/98 0951 MCW
05/13/98 0955 MCW
05/13/98 0959 MCW
05/13/98 1002 MCW
05/13/98 1006 MCW
05/13/98 1010 MCW
05/13/98 1014 MCW
05/13/98 1017 MCW
05/13/98 1021 MCW
05/13/98 1032 MCW
05/13/98 1039 MCW
05/13/98 1044 MCW
04/13/98 1048 MCW
05/13/98 1052 MCW
05/13/98 0929 MCW
05/13/98 1055 MCW
05/13/98 1059 MCW
05/13/98 1103 MCW
Inst
ICPl
ICPl
ICPl
ICPl
ICPl
ICPl
ICPl
ICPl
ICPl
ICPl
ICPl
ICPl
ICPl
ICPl
ICPl
ICPl
ICPl
ICPl
ICPl
ICPl
ICPl
ICPl
ICPl
ICP2
ICPl
ICPl
ICPl
• •
Q.C. Information for Batch# 38403
Page 29
For Report Number :94733
Sample Batch Information
Analysis : pH
Preparation Preparation Analysis
Sample ID Tag Date Time By Notes Date Time By
38403CALCHK I I 05/07/98 1800 JN
38403LCS I I 05/07/98 1800 JN
38403LCSD I I 05/07/98 1800 JN
94733-2 I I 05/07/98 1800 JN
94735 I I 05/07/98 1800 JN
94723 I I 05/07/98 1800 JN
94724 I I 05/07/98 1800 JN
94725 I I 05/07/98 1800 JN
94768-2 I I 05/07/98 1800 JN
94731 I I 05/07/98 1800 JN
94720-1 I I 05/07/98 1800 JN
94720-2 I I 05/07/98 1800 JN
94633-4 I I 05/07/98 1800 JN
94633-4DUP I I 05/07/98 1800 JN
94633-2 I I 05/07/98 1800 JN
94633-3 I I 05/07/98 1800 JN
94778-2 I I 05/07/98 1800 JN
94780-3 I I 05/07/98 1800 JN
94780-3DUP I I 05/07/98 1800 JN
Inst
410A
410A
410A
410A
410A
410A
410A
410A
410A
410A
410A
410A
410A
410A
410A
410A
410A
410A
410A
Sample ID
38425BLK
38425LCS
38425LCSD
94754-2
94771-1
94771-2
94750-1
94750-2
94750-3
94733-2
94733-2MS
94775
94726-2
94727-2
IDA
IDA DUP
IDA-TRIP
IDA-QUAD
• •
Q.C. Information for Batch# 38425
Page 30
For Report Number :94733
Sample Batch Information
Analysis : 0/G
Preparation Preparation Analysis
Tag Date Time By Notes Date Time By
l I 05/08/98 0930 CR/CB
I I 05/08/98 0930 CR/CB
I I 05/08/98 0930 CR/CB
I I 05/08/98 0930 CR/CB
I I 05/08/98 0930 CR/CB
I I 05/08/98 0930 CR/CB
I I 05/08/98 0930 CR/CB
I I 05/08/98 0930 CR/CB
I I 05/08/98 0930 CR/CB
I I 05/08/98 0930 CR/CB
I I 05/08/98 0930 CR/CB
I I 05/08/98 1300 CR/CB
I I 05/08/98 1300 CR/CB
I I 05/08/98 1300 CR/CB
I I 05/08/98 1300 CB
I I 05/08/98 1300 CB
I I 05/08/98 1300 CB
I I 05/08/98 1300 CB
Inst
• •
Page 31
Q.C. Information for Batch# 38435 For Report Number :94733
Sample Batch Information
Analysis : BOD<5 hi, BOD<5 low
Preparation Preparation Analysis
Sample ID Tag Date Time By Notes Date Time By Inst
38435BLK 05/08/98 0730 8R/AS/L 05/13/98 0730 AS/BR/L
38435LCS 05/08/98 0730 BR/AS/L 05/13/98 0730 AS/BR/L
38435LCSD 05/08/98 0730 BR/AS/L 05/13/98 0730 AS/BR/L
94761 05/08/98 0730 BR/AS/L 05/13/98 0730 AS/BR/L
94761DUP 05/08/98 0730 BR/AS/L 05/13/98 0730 AS/BR/L
94725 05/08/98 0730 BR/AS/L 05/13/98 0730 AS/BR/L
94780-1 05/08/98 0730 BR/AS/L 05/13/98 0730 AS/BR/L
94764-2 05/08/98 0730 BR/AS/L 05/13/98 0730 AS/BR/L
94764-3 05/08/98 0730 BR/AS/L 05/13/98 0730 AS/BR/L
94777 05/08/98 0730 BR/AS/L 05/13/98 0730 AS/BR/L
94776 05/08/98 0730 BR/AS/L 05/13/98 0730 AS/BR/L
94733-1 05/08/98 0730 BR/AS/L 05/13/98 0730 AS/BR/L
94696-5 05/08/98 0730 BR/AS/L 05/13/98 0730 AS/BR/L
94696-6 05/08/98 0730 BR/AS/L 05/13/98 0730 AS/BR/L
94768-1 05/08/98 0730 BR/AS/L 05/13/98 0730 AS/BR/L
94771-1 05/08/98 0730 BR/AS/L 05/13/98 0730 AS/BR/L
94771-2 05/08/98 0730 BR/AS/L 05/13/98 0730 AS/BR/L
94787-1 05/08/98 1200 BR/AS/L 05/13/98 0730 AS/BR/L
94795-1 05/08/98 1200 BR/AS/L 05/13/98 0730 AS/BR/L
DILBLK2 05/08/98 1200 BR/AS/L 05/13/98 0730 AS/BR/L
38435LCSLOW 05/08/98 1200 BR/AS/L 05/13/98 0730 AS/BR/L
38435LCSDLOW 05/08/98 1200 BR/AS/L 05/13/98 0730 AS/BR/L
94822 05/08/98 1315 0R/AS/L 05/13/98 0730 AS/BR/L
94822DUP 05/08/98 1315 BR/AS/L 05/13/98 0730 AS/BR/L
94786-1 05/08/98 1315 BR/AS/L 05/13/98 0730 AS/BR/L
94786-2 05/08/98 1315 BR/AS/L 05/13/98 0730 AS/BR/L
94794-1 05/08/98 1315 BR/AS/L 05/13/98 0730 AS/BR/L
94794-1 05/08/98 1315 BR/AS/LCBOD 05/13/98 0730 AS/BR/L
94794-2 05/08/98 1315 BR/AS/LCBOD 05/13/98 0730 AS/BR/L
94794-2 05/08/98 1315 BR/AS/L 05/13/98 0730 AS/BR/L
94794-3 05/08/98 1315 BR/AS/L 05/13/98 0730 AS/BR/L
94794-3 05/08/98 1315 BR/AS/LCBOD 05/13/98 0730 AS/BR/L
94794-4 05/08/98 1315 BR/AS/LCBOD 05/13/98 0730 AS/BR/L
94794-4 05/08/98 1315 BR/AS/L 05/13/98 0730 AS/BR/L
94789-1 05/08/98 1315 BR/AS/L 05/13/98 0730 AS/BR/L
94789-2 05/08/98 1315 BR/AS/L 05/13/98 0730 AS/BR/L
94789-3 05/08/98 1315 BR/AS/L 05/13/98 0730 AS/BR/L
94789-4 05/08/98 1315 BR/AS/L 05/13/98 0730 AS/BR/L
94821 05/08/98 1315 BR/AS/L 05/13/98 0730 AS/BR/L
94815 05/08/98 1315 BR/AS/L 05/13/98 0730 AS/BR/L
94817 05/08/98 1315 BR/AS/L 05/13/98 0730 AS/BR/L
38435LCSCBOD 05/08/98 1315 BR/AS/L 05/13/98 0730 AS/BR/L
94809-1 05/08/98 1500 BR/AS/L 05/13/98 0730 AS/BR/L
94804-1 05/08/98 1500 BR/AS/L 05/13/98 0730 AS/BR/L
94803-8 05/08/98 1500 BR/AS/L 05/13/98 0730 AS/BR/L
94793 05/08/98 1315 BR/AS/L 05/13/98 0730 AS/BR/L
94825 05/08/98 1500 BR/AS/L 05/13/98 0730 AS/BR/L
94823 05/08/98 1500 BR/AS/L 05/13/98 0730 AS/BR/L
Sample ID
94841-1
94841-2
94830-1
• •
Q.C. Information for Batch# 38435
Page 32
For Report Number :94733
Tag
Sample Batch Information
Analysis : BOD<5 hi, BOD<5 low
Preparation Preparation Analysis
Date Time By Notes Date Time
05/00/90 1500 BR/AS/L 05/13/98 0730
05/08/98 1500 BR/AS/L 05/13/98 0730
05/08/98 1500 BR/AS/L 05/13/98 0730
By
AS/BR/L
AS/BR/L
AS/BR/L
Inst
• •
Page 33
Q.C. Information for Batch# 38440 For Report Number :94733
Sample Batch Information
Analysis : CN
Preparation Preparation Analysis
Sample ID Tag Date Time By Notes Date Time By Inst
38440BLK 05/11/98 0930 LH MIDI-DIST 05/11/98 1145 LH GENES
94549-2MS 05/11/98 0930 LH MIDI-DIST 05/11/98 1145 LH GENES
38440LCS 05/11/98 0930 LH 'REPORTED 05/11/98 1145 LH GENES
94549-2MSD 05/11/98 0930 LH MIDI-DIST 05/11/98 1145 LH GENES
38440LCSD 05/11/98 0930 LH REPORTED 05/11/98 1145 LH GENES
38440CAL5 05/11/98 0930 LH REPORTED 05/11/98 1145 LH GENES
38440CAL15 05/11/98 0930 LH REPORTED 05/11/98 1145 LH GENES
94549-2 05/11/98 0930 LH MIDI-DIST 05/11/98 1145 LH GENES
94549-2DUP 05/11/98 0930 LH MIDI-DIST 05/11/98 1145 LH GENES
94505-19 05/11/98 0930 LH MIDI-DIST 05/11/98 1145 LH GENES
94538-2 05/11/98 1230 LH MIDI-DIST 05/11/98 1500 LH GENES
94536-2 05/11/98 1230 LH MIDI-DIST 05/11/98 1500 LH GENES
94571-1 05/11/98 1230 LH MIDI-DIST 05/11/98 1500 LH GENES
94633-1 05/11/98 1230 LH MIDI-DIST 05/11/98 1500 LH GENES
94633-2 05/11/98 1230 LH MIDI-DIST 05/11/98 1500 LH GENES
94633-3 05/11/98 1230 LH MIDI-DIST 05/11/98 1500 LH GENES
94633-4 05/11/98 1230 LH MIDI-DIST 05/11/98 1500 LH GENES
94655-2 05/11/98 1230 LH MIDI-DIST 05/11/98 1500 LH GENES
94844 05/11/98 1230 LH MIDI-DIST 05/11/98 1500 LH GENES
94844DUP 05/11/98 1230 LH MIDI-DIST 05/11/98 1500 LH GENES
94733-2 05/11/98 1430 LH MIDI-DIST 05/12/98 0630 LH GENES
94763-1 05/11/98 1430 LH MIDI-DIST 05/12/98 0630 LH GENES
94705-2 05/11/98 1430 LH MIDI-DIST 05/12/98 0630 LH GENES
94706-1 05/11/98 1430 LH MIDI-DIST 05/12/98 0630 LH GENES
94708-2 05/11/98 1430 LH MIDI-DIST 05/12/98 0630 LH GENES
94708-2DUP 05/11/98 1430 LH MIDI-DIST 05/12/98 0630 LH GENES
94731 05/11/98 1430 LH MIDI-DIST 05/12/98 0630 LH GENES
94738-2 05/11/98 1430 LH MIDI-DIST 05/12/98 0630 LH GENES
94822 05/11/98 1430 LH MIDI-DIST 05/12/98 0630 LH GENES
94774-1 05/11/98 1430 LH MIDI-DIST 05/12/98 0630 LH GENES
• •
Page 34
Q.C. Information for Batch# 38467 For Report Number :94733
Sample Batch Information
Analysis : TSS
Preparation Preparation Analysis
Sample ID Tag Date Time By Notes Date Time By Inst
38467BLK I I 05/11/98 0945 PM/ADM
38467LCS I I 05/11/98 0945 PM/ADM
38467LCSD I I 05/11/98 0945 PM/ADM
94733-lMS I I 05/11/98 0945 PM/ADM
94733-lMSD I I 05/11/98 0945 PM/ADM
94781-1 I I 05/11/98 0945 PM/ADM
94782-1 I I 05/11/98 0945 PM/ADM
94719-1 I I 05/11/98 0945 PM/ADM
94719-2 I I 05/11/98 0945 PM/ADM
94719-3 I I 05/11/98 0945 PM/ADM
94719-4 I I 05/11/98 0945 PM/ADM
94719-5 I I 05/11/98 0945 PM/ADM
94719-6 I I 05/11/98 0945 PM/ADM
94726-1 I I 05/11/98 0945 PM/ADM
94727-1 I I 05/11/98 0945 PM/ADM
94733-1 I I 05/11/98 0945 PM/ADM
94758-1 I I 05/11/98 0945 PM/ADM
94776 I I 05/11/98 0945 PM/ADM
94723 I I 05/11/98 0945 PM/ADM
94724 I I 05/11/98 0945 PM/ADM
94725 I I 05/11/98 0945 PM/ADM
94731 I I 05/11/98 0945 PM/ADM
94734-1 I I 05/11/98 0945 PM/ADM
94 735 I I 05/11/98 0945 PM/ADM
94787-1 I I 05/11/98 0945 PM/ADM
94733-lDUP I I 05/11/98 0945 PM/ADM
94735DUP I I 05/11/98 0945 PM/ADM
• •
Page 35
Q.C. Information for Batch# 38513 For Report Number :94733
Sample Batch Information
Analysis : N
Preparation Preparation Analysis
Sample ID Tag Date Time By Notes Date Time By Inst
38513BLK 05/14/98 1015 BG 05/14/98 1500 BG GENES
3B513LCS 05/14/9B 1015 BG 05/14/9B 1500 BG GENES
3B513LCSD 05/14/9B 1015 BG 05/14/9B 1500 BG GENES
3B513CAL 05/14/9B 1015 BG 05/14/9B 1500 BG GENES
94733-lMS 05/14/9B 1015 BG 05/14/9B 1500 BG GENES
94733-lMSD 05/14/9B 1015 BG 05/14/9B 1500 BG GENES
94733-1 05/14/98 1015 BG 05/14/9B 1500 BG GENES
94733-lDUP 05/14/9B 1015 BG 05/14/9B 1500 BG GENES
94704-15 05/14/98 1015 BG 05/14/9B 1500 BG GENES
94B86-l 05/14/9B 1015 BG 05/14/9B 1500 BG GENES
94B86-2 05/14/9B 1015 BG 05/14/9B 1500 BG GENES
94B86-2DUP 05/14/9B 1015 BG 05/14/98 1500 BG GENES
94886-3 05/14/9B 1015 BG 05/14/98 1500 BG GENES
94786-2 05/14/9B 1015 BG 05/14/98 1500 BG GENES
94786-l 05/14/98 1015 BG 05/14/98 1500 BG GENES
94735 05/14/98 1015 BG 05/14/9B 1500 BG GENES
94804-1 05/14/98 1015 BG 05/14/9B 1500 BG GENES
94795-1 05/14/98 1015 BG 05/14/9B 1500 BG GENES
94809-1 05/14/98 1015 BG 05/14/9B 1500 BG GENES
94 756 05/14/98 1015 BG 05/14/98 1500 BG GENES
94695-6 05/14/98 1015 BG 05/14/98 1500 BG GENES
94B22 05/14/98 1015 BG 05/14/9B 1500 BG GENES
. 94609 05/14/9B 1015 BG 05/14/9B 1500 BG GENES
94794-4 05/14/98 1015 BG 05/14/9B 1500 BG GENES
94794-2 05/14/98 1015 BG 05/14/98 1500 BG GENES
94794-1 05/14/98 1015 BG 05/14/9B 1500 BG GENES
94794-3 05/14/9B 1015 BG 05/14/98 1500 BG GENES
9477B-l 05/14/9B 1015 BG 05/14/9B 1500 BG GENES
' I r--:> -, '? CRA SHIPPED TO (Laboratory Name): /tv., \.;hr•\ V . V 7:lt\J;·(__._,--:r;.,,E.
CONESTOGA-ROVERS & ASSOCIATES, INC. 110 ·1 +;.C(\i.,.c,l('. :' )-f'c: .. ·1· i,._-r>;,-, (\/c ( c ;·17::;; {, fj ·srY.'?'7.. 1351 Oakbrook Drive Suite 150 Norcross, GA 30093 404-441-0027 REFERENCE NUMBER: PROJECT NAME: --, r:t 1 J(cc\.n, H-u~L,qy CHAIN OF CUSTODY RECORD ~) :-~ .
"' AAM"W#Ji# ASl#W153 SAMPLER'S .11>-,/ .. {'.1.J .(;.-;;,-------·PRINTED I· 1 -h: / l\l-c.-. 1..
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RELINQ ::;21~,£; 1,, .6 DATE: (c,1 .ot:;-: 5 RECEIVED BY: F<::_ r:: <zx DATE: {/i/C•[/~3 (i) / ,-::, TIME: I "I 00 @ TIME: /~·ao REl.)}IOUISHED BY: •· DATE: RECEIVED BY: DATE: @ TIME: @ TIME: RELINQUISHED BY: DATE: RECEIVED BY: DATE: @ TIME: © TIME:
METHOD OF SHIPMENT: r£ot_x 9b I 6 "3':>rtt o 3 7 AIR BILL NUMBE~,__..,.~;~.3 )CJ/ C_3 T"' ~ //-
White . Fully Executed Copy SAMPLE TEAM: \ I'\' (v4-~rvy · ~ -Yellow . Receiving Laboratory Copy 0.':i q-\ "\(:-'' '//,/ N~ 0627 ?Ink . Sampler Copy / -L'/,,rf Of.;) 7::i-Goldenrod . Chemist Copy .c::: DATE: , >/ -r1<? TIME: \ ' . :007(FORMS) -DEC 6, 93 -REV.D -(AF-01) ;c-e ~1wMi fa,,,r · tJ=<:. ' .,:J 11.:: I ( ~ i.cy,; If J '
• •
ASI ANALYTICAL SERVICES, INC.
26 May, 1998
ENVIRONMENTAL MONITORING & LABORATORY ANALYSIS
110 TECHNOLOGY PARKWAY • NORCROSS, GA 30092
[phone] • FAX [phone]
Case Narrative Report 95164
The sample was collected on 19 May, l 998 and received by AS[ 20 May, 1998.
Conditions for proper sample receipt were met as indicated on the Chain of Custody. The
sample was logged into the LIMS as report 95164 for Metals (EPA 200. 7). All holding
times for sample preparation and analysis were met.
Metals analysis (EPA 200. 7) gave low MS/MSD for Zn. All other quality
controls were acceptable.
Julia E. Martin
Quality Assurance
A Unit of American Analytical Services, Inc.
• •
ASI ANALYTICAL SERVICES, INC.
Conestoga-Rovers
1351 Oakbrook Drive
Suite 150
Norcross, GA 30093
ENVIRONMENTAL MONITORING & LABORATORY ANALYSIS
110 TECHNOLOGY PARKWAY • NORCROSS, GA 30092
[phone] • FAX [phone]
LABORATORY REPORT
May 27, 1998
Attention: Mr. Rob Brachowski Report No. 95164
Sample Description
Water, Jadco Hughes, Project #3669, Sample W-3669-MC-051998-097, 05/19/98,
14:10, received 05/20/98
RESULTS
Metals
Total Zinc (Zn) (EPA 200.7) .................. .
Result
(mg/1)
0.13
Detection
Limit
(mg/1}
0.02
.c~
Quality Assurance
A Unit of American Analytical Services, ·1nc.
• •
Page 1
Analytical Services Inc. Batch QC
For Report Number :95164
QC Batch
Batch
Number
38381
......... Note
General Information
Analysis
Analyte Method
Zn EPA 200.7
BATCH PASSES ON LCS/LCSD/PDS
Lab Control Information
Batch
Number Analyte Method
38381 Zn EPA 200.7
Matrix Spike Information
Batch
Number Analyte Method
38381 Zn EPA 200.7
Post Digestion Spike Information
Batch
Number Analyte Method
38381 Zn EPA 200.7
Matrix
Aqueous <
LC LCD
%Rec %Rec
86 88
Blank
Result
0.0200
LC %Recovery
RPD Range
2 85 -115
MS
%Rec
MSD MS
%Rec RPD
%Recove~y
Range
83
PDS
%Rec
99
83 0 85 -115
%Recovery
Range
85 -115
Prep.
Method
RPD
Range
0 -20
RPD
Range
0 -20
• •
Page 2
Q.C. Information for Batch# 38381 For Report Number :95164
Sample Batch Information
Analysis : Zn
Preparation Preparation Analysis
Sample ID Tag Date Time By Notes Date Time By Inst
38381BLANK 05/21/98 1000 DCF TRACE 05/22/98 1004 MCW ICP2
38381LCS 05/21/98 1000 DCF TRACE 05/22/98 1008 MCW ICP2
38381LCSD 05/21/98 1000 DCF TRACE 05/22/98 1012 MCW ICP2
95164MS 05/21/98 1000 DCF TRACE 05/22/98 1017 MCW ICP2
95164MSD 05/21/98 1000 DCF TRACE 05/22/98 1021 MCW ICP2
94138-lPDS 05/21/98 1000 DCF TRACE 05/22/98 1025 MCW ICP2
95164DUP 05/21/98 1000 DCF TRACE 05/22/98 1029 MCW ICP2
95164 05/21/98 1000 DCF TRACE 05/22/98 1034 MCW ICP2
95156 05/21/98 1000 DCF TRACE 05/22/98 1042 MCW ICP2
95141-1 05/21/98 1000 DCF TRACE 05/22/98 1150 MCW ICP2
95139-3 05/21/98 1000 DCF TRACE 05/22/98 1158 MCW ICP2
95139-1 05/21/98 1000 DCF TRACE 05/22/98 1154 MCW ICP2
95138-1 05/21/98 1000 DCF TRACE 05/22/98 1038 MCW ICP2
95085-1 05/21/98 1000 DCF TRACE 05/22/98 1203 MCW ICP2
95085-10 05/21/98 1000 DCF TRACE 05/22/98 1249 MCW ICP2
95085-2 05/21/98 1000 DCF TRACE 05/22/98 1207 MCW ICP2
95085-3 05/21/98 1000 DCF TRACE 05/22/98 1211 MCW ICP2
95085-4 05/21/98 1000 DCF TRACE 05/22/98 1215 MCW ICP2
95085-5 05/21/98 1000 DCF TRACE 05/22/98 1220 MCW ICP2
95085-6 05/21/98 1000 DCF TRACE 05/22/98 1224 MCW ICP2
95085-7 05/21/98 1000 DCF TRACE 05/22/98 1228 MCW ICP2
95085-8 05/21/98 1000 DCF TRACE 05/22/98 1241 MCW ICP2
95085-9 05/21/98 1000 DCF TRACE 05/22/98 1215 MCW ICP2
95099-1 05/21/98 1000 DCF TRACE· 05/22/98 1253 MCW ICP2
95099-2 05/21/98 1000 DCF TRACE 05/22/98 1258 MCW ICP2
95052-1 05/21/98 1000 DCF TRACE 05/22/98 1302 MCW ICP2
95052-2 05/21/98 1000 DCF TRACE 05/22/98 1306 MCW ICP2
QCBLANK 05/21/98 1000 DCF TRACE 05/22/98 1310 MCW ICP2
i (~
CRA SHIPPED TO (Laboratory Name): (\w.\,A\c,\ )<?Vvl( <'.':, '.:'I'.,. C --C\'S \\o~ CONESTOGA-ROVERS & ASSOCIATES, INC. \ 'O \ E:c¼-.clc ','j 1:C-.,\.i.-....;Do, 1\/c:a(•<' S -'> l</4 3co'l ::i....
1351 Oakbrook Drive Suite 150
Norcross, GA 30093 404-441-0027 REFERENCE NUMBER: PROJECT NAME:
·J,A: ld-&sL: >< CHAIN OF CUSTODY RECORD 366 c, . C
., ~io/////17 / a:
SAMPLER'S /}/.4/1 ',?f/e,<-J.,,, PRINTED ~ \ I'\\ C ... w
SIGNATURE: •//,c NAME: Y'/\ IC. -'· • Vv<· 0~ REMARKS d ;!
SEQ. ,~E TIME ' SAMPLE zz
SAMPLE NUMBER 0
NO. TYPE u
I ,,(/19/y'B 111-0 L~•-.J;6G9-MC.-OS-l"J<; 6 -re.··+ ,Ac l i-.
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RELINQUISHED BY~ _,.\ ~ ( DATE: 05'lt~ i" 6 ®CEIVED BY: p:c:zf>£f. DATE: N;-f l'T Jc, fJ
(j) \ 1\ . .,,.,.\ ✓...., TIME: ftl '.) ,: TIME: l7c -"',--:ci
RELINQUISHED BY: DATE: RECEIVED BY: DATE:
® TIME: @ TIME:
RELINQUISHED BY: DATE: RECEIVED BY: DATE:
@ TIME: © TIME:
METHOD OF SHIPMENT: ~CZ...'O~f.. AIR BILL NUMBER: ~olo3J 1-q I OU
White Fully Executed Copy SAMPLE TEAM: • u~•-•IVE~\LA~RATOAY BY: . MN( ( ,A-----, • 1 ..(', A l
.. -
Yellow .. Receiving Laboratory Copy N2, 0939·
Pink .. Sampler Copy .
o::::::.\ 7 f'\\c...o Goldenrod .. Chemist Copy " ~ . " ~ ·.-\-.. .\. D'\ . fl =-('..c DATE: TIME: D\Su
1007(FORMS) -DEC S. 93 -REV.D -(AF-01) I \-\-:. \ I'-~) \ I
CRA
1351 Oakbrook Drive
Suite #150
Norcross, Georgia 30093
[phone]
TO: Jeanne Chew
• •
MEMO
REFERENCE NO: 3669
FROM: Robert Brachowski/jo/32 .,t!,f, DATE: April 28, 1998
RE: Data Quality Assessment and Validation for Two Water Samples
Collected from the Jadco-Hughes Site in Belmont, North Carolina
(Lot# 93874)
The following details a data quality assessment and validation for results generated by
Analytical Services, Inc. (AS!) of Norcross, Georgia for two water samples collected from the
above-referenced Site. Sample collection was conducted on April 8, 1998. The samples were
selectively analyzed for volatile organic compounds (VOCs), base-neutral and acid extractable
organic compounds (BNA), polychlorinated biphenyls (PCBs), cyanide, oil and grease (O&G),
pH, target analyte list (TAL) metals, total suspended solids (TSS), biological oxygen demand
(BOD), and ammonia. The quality assurance criteria were established by the associated quality
assurance project plan and the analytical methods1. The samples are identified in Table 1. The
analytical methodologies are listed in Table 2.
Holding Time Periods
The holding time periods are presented in Table 3. The pH parameter should be analyzed for
in the field immediately after sampling; therefore, the pH analysis was performed outside the
allowable holding time period and the data for sample W-3669-MC-040898-094 should be
qualified as estimated CT) for this parameter. On the basis of the sample collection and analysis
dates referenced on the chain-of-custody forms and the analytical reports provided by AS!, the
remainder of the extractions and analyses were performed within the required holding time
periods.
Method Blank Samples
. Contamination of samples contributed by laboratory conditions or procedures was monitored
by the concurrent preparation and analysis of method blank samples. The method blank
samples were free from target analytes above the detection limits indicating that no significant
laboratory contamination occurred.
1 Application of quality assurance criteria was consistent with "National Functional Guidelines for
Organic Data Review," revised February 1994 and "National Functional Guidelines for Inorganic Data
Review," revised February 1994.
• •
April 28, 1998 Reference No. 3669
-2-
Laboratory Control Sample/Laboratory Control Sample Duplicate /LCS/LCSD) Results
AS! provides and analyzes LCS/LCSD in order to further assess the method accuracy and
precision. The outlying LCS/LCSD percent recovery and relative percent difference (RPD) data
as well as required sample qualifications are provided in Table 4. The remainder of the
LCS/LCSD data were within the control limibfindicating the method achieved an adequate
level of accuracy and precision. ·
Surrogate Compound Percent Recoveries (Surrogate Recoveries)
Individual sample performance for the VOC, BNA, and PCB parameters were monitored by
surrogate recoveries. The surrogate recoveries were within the control limits for the reported
analyses.
Matrix Spike/Matrix Spike Duplicate (MS/MSD) Percent Recoveries
To assess the long term accuracy and precision of the analytical method on various matrices,
MS/MSD percent recoveries and the RPD of the recoveries are determined. The BNA
MS/MDS RPD data for 1, 2, 4-trichlorobenzene and 2, 4-dinitrophenol were outside the control
limits; therefore, the quantitation limits for sample W-3669-MC-040898-094 should be qualified
as estimated (UJ) for these analytes. The TAL metals MS/MSD percent recoveries for sodium
and selenium were outside the control limits; therefore, the sample W-3669-MC-040898-093
should be qualified as estimated CT) for the associated detected compounds and the quantitation
limits should be qualified as estimated (UJ) for associated non-detected compounds. Some
other MS/MSD data were outside the control limits; however, no sample qualification was
deemed necessary. The remainder of the MS/MSD percent recovery and RPD data were within
the control limits indicating an adequate level of accuracy and precision was achieved.
Laboratory Duplicate Analyses
To monitor the precision of the laboratory analytical methods, laboratory duplicate samples
were analyzed for select methods. The BOD laboratory duplicate RPD data were outside the
control limits; therefore, the quantitation limit for sample W-3669-MC-040898-093 should be
qualified as estimated (UJ) for this parameter. The remainder of the laboratory duplicate RPD
data were within the control limits indicating an adequate level of precision was achieved for
these select methods.
Trip Blank Analysis
Potential VOC cross-contamination by diffusion of target compounds through the septum seal
of the sample vial into the investigative samples during shipment and storage was monitored
by means of a trip blank sample. The trip blank sample was free from detectable concentrations
of target analytes indicating that no significant cross-contamination occurred.
• •
April 28, 1998 Reference No. 3669
-3 -
Overall Assessment
Violation of holding time, MS/MSD, LCS/LSCD and laboratory duplicate criteria resulted in
sample qualification as noted in the previous text and following tables. The remainder of the
data was found to exhibit acceptable levels of accuracy and precision and may used without
qualification.
•
TABLEl
SUMMARY OF THE SAMPLE IDENTIFICATION NUMBERS
ASSOCIATED WITH THE SAMPLES COLLECTED FROM THE
JADCO-HUGHES SITE IN
3669•M•32-TI
BELMONT, NORTH CAROLINA
W-3669-MC-040898-093
W-3669-MC-040898-094
Parameters
voe
BNA
PCB
Cyanide
pH
• •
TABLE2
ANALYTICAL METHODS ASSOCIATED WITH THE
SAMPLES COLLECTED FROM THE JADCO-HUGHES SITE IN
BELMONT, NORTH CAROLINA
Methods
MCAWW 1 624
MCAWW 625
MCAWW 608
MCAWW 335.2
MCAWW 150.1
TALMetals MCAWW 200 (series)
TSS MCAWW 160.2
BOD SM 2 5210 B
Ammonia MCAWW 350.2
Oil and Grease HEM3 1664
Notes:
• "Methods for Chemical Analysis of Water and Wastes," EPA 600/4-79-020, revised March 1983.
2 "Standard Methods for the Examination of Water and Wastewater," APHA, 16th edition, 1985.
3 "N-Hexane Extractable Material and Silica Gel Treated N-Hexane Extractable Material by Extraction and
Gravimetry," EPA-821-B-94-004, January 1995.
3669-M-32-TI
• •
TABLE3
HOLDING TIME PERIODS ASSOCIATED WITH THE SAMPLES
COLLECTED FROM THE JADCO-HUGHES SITE IN
BELMONT, NORTH CAROLINA
Parameters
VOC, Cyanide
BNA, PCB
pH
TAL Metals
(excluding mercury)
Holding Time Periods
-14 days from sample collection to completion of analysis
-

7

days from sample collection to extraction
-40 days from extraction to completion of analysis
-Analyze as soon as possible
-

6

months from sample collection to completion of analysis
Mercury, Oil and Grease, -28 days from sample collection to completion of analysis
Ammonia
BOD -48 hours from sample collection to beginning of analysis
TSS -

7

days from sample collection to completion of analysis
3669-M-32·T3
• •
TABLE4
OUTLYING LCS/LCSD PERCENT RECOVERY AND RPD DATA
ASSOCIATED WITH THE SAMPLES COLLECTED FROM THE
JADCO-HUGHES SITE IN BELMONT, NORTH CAROLINA
LCS/LCSD "'
Percent Control
Parameter Compound Recoveries Limits
TAL Metals Silver 120 [85-115]
Aluminum 82 [85-115]
Arsenic 81 [85-115)
Barium 81 [85-115)
Cadmium 80 [85-115)
Cobalt 81 [85-115)
Chromium 81 [85-115)
Copper 79 [85-115)
Iron 82 [85-115]
Manganese 83 [85-115)
Nickel 79 [85-115)
Antimony 79 [85-115)
Zinc 78 [85-115]
(1) LCS/LCSD-Laboratory Control Sample/Laboratory Control Sample Duplicate
(2) RPO -Relative percent difference
(3) The associated samples should be qualified as follows:
RPD
Control
RPD"' Limits
NA 1'1 NA
NA NA
21 [20)
NA [20)
21 [20)
21 [20)
21 [20)
NA NA
NA NA
NA NA
NA NA
NA NA
21 [20]
J -Positive results for the associated compound should be qualified as an estimated quantity.
UJ -The quantitation limit for the associated compound should be qualified as an estimated value.
(4) NA -Not applicable
(5) NR -No sample qualification required.
CRA 3669-M-32-T4
Page 1 of1
Associated
Samples"'
NR 151
W-3669-MC-040898-093
W-3669-MC-040898-093
W-3669-MC-040898-093
W-3669-MC-040898-093
W-3669-MC-040898-093
W-3669-MC-040898-093
W-3669-MC-040898-093
W-3669-MC-040898-093
W-3669-MC-040898-093
W-3669-MC-040898-093
W-3669-MC-040898-093
W-3669-MC-040898-093
ASI
• •
ANALYTICAL SERVICES, INC.
ENVIRONMENTAL MONITORING & LABORATORY ANALYSIS
110 TECHNOLOGY PARKWAY • NORCROSS, GA 30092
[phone] • FAX [phone]
22 April, 1998
Case Narrative Report 93874
The samples were collected on 8 April, 1998 and received by AS! 9 April,
1998. The samples were received at 0°C, but all other conditions for proper sample
receipt were met as indicated on the Chain of Custody. The samples were logged into the
LIMS as report 93874 for the following analyses as per client request: PCB (EPA 608),
BNA (EPA 625), VOA (EPA 624), Metals (EPA 200.7, 245.1, 270.2, 279.2, 239.2), BOD
(SM 5210), NH3 (EPA 350.2), pH (EPA 150.1), CN (EPA 335.2), 0/G (EPA 1664) and
TSS (EPA I 60.2). All holding times for sample preparation and analysis were met with
exception of pH which should be analyzed on-site during sampling.
PCB analysis (EPA 608) met all data quality objectives.
BN analysis (EPA 625) gave high MSD for 1,4-Dichlorobenzene and Pyrene;
high MSRPD for 1,2,4-Trichlorobenzene. All other spikes.and all surrogates_ were
acceptable. Acid analysis (EPA 625) gave high MSD for Pentachlorophenol; high
MSRPD for 2,4-Dinitrophenol. All other spikes and all surrogates were acceptable.
VOA analysis (EPA 624) gave high MSRPD for 2-Chloroethylvinyl ether. All
other spikes and all surrogates were acceptable.
Metals analysis (EPA 200. 7) gave acceptable recoveries for at least one lab
control and the average of both lab controls for every analyte. ICP analysis also gave
acceptable recoveries for matrix spikes with exception of Ag, Na and V. Hg analysis
(EPA 245.1) met all data quality objectives. Se analysis (EPA 270.2) gave low
MSD/PDS. Tl analysis (EPA 279.2) gave high MS/MSD and low PDS. Pb analysis
(EPA 239.2) gave high MS/MSD and low PDS. All other GF quality controls were
acceptable.
BOD analysis (SM 5210) gave high 2nd DUP RPD, but all other quality controls
were acceptable.
NH3 analysis (EPA 350.2) met all data quality objectives.
pH analysis (EPA 150.1) gave acceptable recoveries for all quality controls.
CN analysis (EPA 335.2) met all data quality objectives.
0/G analysis (EPA 1664) gave acceptable LCS/LCSD/MS. There was
insufficient sample to run MSD.
TSS analysis (EPA 160.2) met all.data quality objectives.
Qt::_~ 0
Julia E. Martin
Quality Assurance
A Unit of American Analytical Services, Inc.
• •
ASI ANALYTICAL SERVICES, INC.
ENVIRONMENTAL MONITORING & LABORATORY ANALYSIS
110 TECHNOLOGY PARKWAY • NORCROSS, GA 30092
[phone] • FAX [phone]
Conestoga-Rovers
1351 Oakbrook Drive
Suite 150
Norcross, GA 30093
LABORATORY REPORT
Attention: Mr. Rob Brachowski
Sample Description
April 22, 1998
Report No. 93874-1
Wastewater, composite, Monthly, Jadco-Hughes, Project #3669, W-3669-MC-
0408-093, 04/08/98, 14:00, received 04/09/98
RESULTS
Biochemical Oxygen Demand (BOD5 ) (mg/1)
(SM.5210 B) ............................ .
Ammonia Nitrogen (N) (mg/1) (EPA 350.2) ....... .
Total Suspended Solids (mg/1) (EPA 160.2) .... .
Target Analyte List -Metals
Metals
Total Aluminum (Al) (EPA 200. 7) .............. .
Total Antimony (Sb) (EPA 200. 7) .............. .
Total Arsenic (As) (EPA 200. 7) ............... .
Total Barium (Ba) (EPA 200. 7) ................ .
Total Beryllium (Be) (EPA 200. 7) ............. .
Total Cadmium (Cd) (EPA 200. 7) ............... .
Total Calcium (Ca) (EPA 200. 7) ............... .
Total Chromium (Cr) (EPA 200. 7) .............. .
Total Cobalt (Co) (EPA 200. 7) ................ .
Total Copper (Cu) (EPA 200 .7) ................ .
Total Iron (Fe) (EPA 200. 7) .................. .
Total Lead (Pb)(EPA 239.2) .................. .
BDL -Below Detection Limit
Result
BDL
BDL
BDL
(mg/1)
BDL
BDL
BDL
0.06
BDL
BDL
34
BDL
BDL
BDL
BDL
BDL
A Unit of American Analytical Services, Inc.
Detection
Limit
5
0.1
5
(mg/1)
0.2
0.05
0.01
0.01
0.001
0.005
0.05
0.01
0.05
0.02
0.1
0.003
Conestoga-Rovers
Page 2 of 2
• •
April 22, 1998
Report No. 93874-1
Wastewater, composite, Monthly, Jadco-Hughes, Project #3669, W-3669-MC-
0408-093, 04/08/98, 14:00, received 04/09/98
RESULTS
Metals
Total Magnesium (Mg) (EPA 200. 7) ............. .
Total Manganese (Mn) (EPA 200. 7) ............. .
Total Mercury (Hg) (EPA 245 .1) ............... .
Total Nickel (Ni) (EPA 200. 7) ................ .
Total Potassium (K) (EPA 200. 7) .............. .
Total Sele_nium (Se)(EPA 270.2) .............. .
Total Silver (Ag) (EPA 200.7) ................ .
Total Sodium (Na) (EPA 200. 7) ................ .
Total Thallium (Tl) (EPA 279.2) .............. .
Total Vanadium (V) (EPA 200. 7) ............... .
Total Zinc (Zn) (EPA 200. 7) .................. .
BDL -Below Detection Limit
Result
(mg/1)
9.9
0.02
BDL
BDL
2.8
BDL
BDL
17
BDL
BDL
0.06
Detection
Limit
(mg/1)
0.05
0.015
0.0002
0.02
0.2
0.005
0.01
0.05
0.002
0.02
0.02
Respectfully submitted, --~14:-~
. Proj_ecriar/.ager
!'-r C.. ~__A::::::_
c-Quality Assurance
• •
ASI ANALYTICAL SERVICES, INC.
ENVIRONMENTAL MONITORING & LABORATORY ANALYSIS
110 TECHNOLOGY PARKWAY • NORCROSS, GA 30092
[phone] • FAX [phone]
LABORATORY REPORT
Conestoga-Rovers
1351 Oakbrook Drive
Suite 150
April 22, 1998
Norcross, GA 30093
Attention: Mr. Rob Brachowski Report No. 93874-2
Sample Description
Wastewater, grab, Monthly, Jadco-Hughes, Project #3669, W-3669-MC-0408-094,
04/08/98, 13:45, received 04/09/98
RESULTS
Detection
Result Limit
pH (laboratory) (EPA 150 .1) .................. .
Total Cyanide (CN) (mg/1) (EPA 335. 2) ......... .
8.02
BDL 0.01
Oil and Grease (mg/1) (EPA 1664) ............. . 6 6
Volatile Organics (EPA 624) (ug/1) (ug/1)
Acetone ..................................... . BDL 100
Benzene ..................................... . BDL 2
Bromodichloromethane ........................ . BDL 10
Bromoform ................................... . BDL 10
Bromomethane ................................ . BDL 10
2-Butanone .................................. . BDL 100
Carbon-disulfide ............................ . BDL 5
Carbon tetrachloride ........................ . BDL 2
Chlorobenzene ............................... . BDL 10
Chloroethane ................................ . BDL 5
Chloroform .................................. . 9 2
Chloromethane ............................ : .. . BDL 10
Dibromochloromethane ........................ . BDL 10
1, 1-Dichloroethane .......................... . BDL 2
1,2-Dichloroethane .......................... . 3 2
1, 1-Dichloroethene .......................... . BDL 2
1, 2-Dichloroethene (total) .................. . 7 2
BDL -Below Detection Limit
A Unit of American Analytical Services, Inc.
Conestoga-Rovers
Page 2 of 4
• •
April 22, 1998
Report No. 93874-2
Wastewater, grab, Monthly, Jadco-Hughes, Project #3669, W-3669-MC-0408-094,
04/08/98, 13:45, received 04/09/98
RESULTS
Detection
Result Limit
Volatile Organics (EPA 624) (ug/1) (ug/1)
1, 2-Dichloropropane ......................... . BDL 2
cis-1,3-Dichloropropene ..................... . BDL 2
trans-1,3-Dichloropropene ................... . BDL 2
Ethylbenzene ................................ . BDL 2
2 -Hexanone .................................. . BDL 50
Methylene _chloride .......................... . BDL 10
1,1,2,2-Tetrachloroethane ................... . BDL 2
Tetrachloroeth_ene ........................... . BDL 2
Toluene ..................................... . BDL 2
1, 1, 1-Trichloroethane ....................... . BDL 2
1, l, 2 -Trichloroethane ....................... . BDL 2
Trichloroethene ............................. . 4 2
Vinyl chloride .............................. . BDL 10
Xylenes .............. · ......... :· ............. . BDL 2
Acid Extractable Organics (EPA 625) (ug/1) (ug/1)
Benzoic Acid ................................ . BDL 50
4-Chloro-3-methylphenol ..................... . BDL 10
2 -Chlorophenol. ............................. . BDL 10
2, 4-Dichlorophenol .......................... . BDL 10
2, 4-Dimethylphenol. ......................... . BDL 10
2, 4-Dinitrophenol. .......................... . BDL 50
4,6-Dinitro-2-methylphenol .................. . BDL 50
2-Methylphenol. ............................. . BDL 10
4-Methylphenol .............................. . BDL 10
2-Nitrophenol. .............................. . BDL 50
4-Nitroph_enol ............................... . BDL 50
Pentachlorophenol ........................... . BDL 20
Phenol ...................................... . BDL 10
2,4,6-Trichlorophenol. ...................... . BDL 10
2,4,5-Trichlorophenol. ...................... . BDL 10
BDL -Below Detection Limit
Conestoga-Rovers
Page 3 of 4
• •
April 22, 1998
Report No. 93874-2
wastewater, grab, .Monthly, Jadco-Hughes, Project #3669, W-3669-MC-0408-094,
04/08/98, 13:45, received 04/09/98
RESULTS
Detection
Result Limit
Base/Neutral Extractable Organics dEPA 625) (ug/1) (ug/1)
Acenaphthene ................................. . BDL 10
Acenaphthylene .............................. . BDL 10
Anthracene .................................. . BDL 10
Benzo(a)anthracene .......................... . BDL 10
Benzo (b) fluoranthene ........................ . BDL 10
Benzo (k) fl.uoranthene ........................ . BDL 10
Benzo(a)pyrene .............................. . BDL 10
Benzo(ghi)perylene .......................... . BDL 10
Benzyl butyl phthalate ...................... . BDL 10
Bis(2-chloroethyl)ether ..................... . BDL 10
Bis(2-chloroethoxy)methane .................. . BDL 10 .
Bis(2-ethylhexyl)phthalate ......•............ BDL 10
Bis(2-chloroisopropyl)ether ................. .
4-Bromophenyl phenyl ether .................. .
BDL 10
BDL 10
4-Chloroaniline ............................. . BDL 20
2-Chloronaphthalene ......................... . BDL 10
4-Chlorophenyl phenyl ether ................. . BDL 10
Chrysene .................................... . BDL 10
Dibenzo(a,h)anthracene ...................... . BDL 10
Dibenzofuran ................................ . BDL 10
Di-n-butylphthalate ......................... . BDL 10
1, 3-Dichlorobenzene ......................... . BDL 10
1, 2-Dichlorobenzene ......................... . BDL 10
1, 4-Dichlorobenzene ......................... . BDL 10
3, 3' -Dichlorobenzidine ...................... . BDL 20
Diethylphthalate ............................ . BDL 10
Dimethylphthalate ......................... , .. BDL 10
2, 4-Dinitrotoluene .......................... . BDL 20
2,6-Dinitrotoluene .......................... . BDL 20
Di-n-octylphthalate ......................... . BDL 10
Fluoranthene ................................ . BDL 10
Fluorene .................................... . BDL 10
Hexachlorobenzene ........................... . BDL 10
Hexachlorobutadiene ......................... . BDL 10
Hexachlorocyclopentadiene ................... . BDL 10
Hexachloroethane ............................ . BDL 10
Indeno(l,2,3-cd)pyrene ...................... . BDL 10
Isophorone .................................. . BDL 10
BDL -Below Detection Limit
Conestoga-Rovers
Page 4 of 4
• •
April 22, 1998
Report No. 93874-2
Wastewater, grab, .Monthly, Jadco-Hughes, Project #3669, W-3669-MC-0408-094,
04/08/98, 13:45, received 04/09/98
RESULTS
Detection
Result Limit
Base/Neutral Extractable Organics (EPA 625) (ug/1) (ug/1)
2-Methylnaphthalene ......................... .
NapJ:ithalez:ie: ................................ .
2-Nitroaniline .............................. .
BDL 10
BDL 10
BDL 50
3-Nitroaniline .............................. . BDL 50
4 -Nitroaniline .............................. . BDL 50
Nitrobenz~ne ................................ .
N-Nitrosodiphenylamine ...................... .
N-Nitrosodi-n-propylamine ................... .
Phenanthrene ................................ .
BDL 10
BDL 10
BDL 10
BDL 10
Pyrene ...................................... .
1,2,4-Trichlorobenzene ...................... .
BDL 10
BDL 10.
PCB' s (EPA 608) (ug/1) (ug/1)
PCB 1016 .................................... . BDL 1. 0
PCB 1221 .................................... . BDL 1.0
PCB 1232 .................................... . BDL 1.0
PCB 1242 .................................... . BDL 1.0
PCB 1248 .................................... . BDL 1.0
PCB 1254 .................................... . BDL 1.0
PCB 1260 .................................... . BDL 1.0
BDL -Below Detection Limit
North Carolina Laboratory I.D. No. 381
(~ e_ ' )~_z:::__
c.Quality Assurance
• •
ASI ANALYTICAL SERVICES, INC.
Conestoga-Rovers
l351 Oakbrook Drive
Suite 150
Norcross, GA 30093
ENVIRONMENTAL MONITORING & LABORATORY ANALYSIS
110 TECHNOLOGY PARKWAY • NORCROSS, GA 30092
[phone] • FAX [phone]
LABORATORY REPORT
April 22, 1998
Attention: Mr. Rob Brachowski Report No. 93874-3
Sample Description
Water, Monthly, Jadco-Hughes, Project #3669, Trip Blank, 04/08/98,
received 04/09/98
RESULTS
Detection
Result Limit
Volatile Organics (EPA 624) (ug/1) (ug/1)
Benzene ..... , ............ , ......... , ........ . BDL 2
Bromodichloromethane ..... , ....... , .. , ....... . BDL 10
Bromoform. , .... , ............................ . BDL 10
Bromomethane ................................ . BDL 10
Carbon tetrachloride ........................ . BDL 2
Chlorobenzene ............ , .... , ............. . BDL 10
Chloroethane ....... , ............. , .......... . BDL 5
2-Chloroethylvinyl ether .................... .
Chloroform .................................. .
BDL 10
BDL 2
Chloromethane ................. , ............. . BDL 10
Dibromochloromethane., ...................... , BDL 10
1, 2-Dichlorobenzene. , ....................... ,
1, 3-Dichlorobenzene .... , . , .................. .
1, 4-Dichlorobenzene ......................... .
1,1-Dichloroethane .......................... ,
1,2-Dichloroethane ............. , ....... , .... .
1,1-Dichloroethene ..... , ..... , .............. .
trans-1,2-Dichloroethene .................... .
BDL 10
BDL 10
BDL 10
BDL 2
BDL 2
BDL 2
BDL 2
1, 2-Dichloropropane ......................... .
cis-1,3-Dichloropropene ..................... .
BDL 2
BDL 2
trans-1,3-Dichloropropene., ................. . BDL 2
Ethylbenzene ................................ . BDL 2
BDL -Below Detection Limit
A Unit of American Analytical Services, Inc.
Conestoga-Rovers
Page 2 of 2
• •
April 22, 1998
Report No. 93874-3
Water, Monthly, Jadco-Hughes, Project #3669, Trip Blank, 04/08/98,
received 04/09/98
RESULTS
Volatile Organics (EPA 624)
Methylene chloride .......................... .
1,1,2,2-Tetrachloroethane ................... .
Tetrachloroethene ........................... .
Toluene ..................................... .
1,1,1-Trichloroethane ....................... .
1, 1, 2 -Trichloroethane ....................... .
Trichloroethene ............................. .
Trichlorofluoromethane ...................... .
Vinyl chloride .............................. .
Xylenes ..................................... .
BDL -Below Detection Limit
Result
(ug/1)
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
Detection
Limit
(ug/1)
10
2
2
2
2
2
2
10
10
2
Project Manger
C).-t:_-~
~Quality Assurance
• •
Analytical Services Inc. Batch QC
For Report Number :93874
Organochlorine Pesticides
Page 1
Matrix : Aqueous Batch # 37464 Method : EPA 8080 I 608
Lab Control Information LC LCD LC %Recovery RPD
Analyte %Rec %Rec RPD Range Range
Heptachlor 105 110 5 34 -111 0 -40
Aldrin 95 100 5 42 -122 O· -40
Dieldrin 92 98 6 36 -146 0 -40
Endrin 93 100 7 30 -147 0 -40
4,4'-DDT 104 115 10 25 -160 0 -40.
BHC-gamma (Lindane) 96 100 4 32 -127 0 -40
Matrix Spike Information MS MSD MS %Recovery RPD
Analyte %Rec %Rec RPD Range Range
Heptachlor 60 57 6 34 -111 0 --40
Aldrin 63 62 2 42 -122 0 -40·
Dieldrin 69 48 37 36 -146 0 -40
Endrin 63 63 0 30 -147 0 -40
4, 4' -DDT 54 37 37 25 -160 0 -40
BHC-gamma (Lindane) 56 58 2 32 -127 0 -40
Matrix
Sample
37464BLK
37464LCS
37464LCSD
93394
93256-13
93435
93394MS
93394MSD
93574
93667-1
93793-1
93854
93805-6 D
AANote:
93874-2
AANote:
93874-2DUP
AANote:
•
Analytical Services Inc. Batch QC
Surrogate Recovery
Organochlorine Pesticides
Aqueous Batch# 37464 Method
% Recovery Objectives
Sl Dibutylchlorendate 14 -
S2 Tetrachloro-m-xylene 47 -
S3 Decachlorobiphenyl 10 -
File Sl S2 S3 S4
033198021F 117 77 80
033198022F 123 82 100
033198023F 135 83 112
033198040F 71 71 59
033198019F 61 61 37
040298008F 135 62
040698004R 137 98 104
040698005F 125 79 102
040698007F 68 27 23
040798031F 64 62 29
041398020F 89 83 62
041398021F 67 68 39
041398022F 38 16 13
Surrogates diluted out 3X
041398033F 77 108
608 PCB ONLY
041398036F 59 69
608 PCB ONLY
37464BLKPCB 041398032F 86 94
AANote: 608 PCB BLK
Page 2
EPA 8080 / 608
161
113
139
S5 S6
PCB
PCB
PCB
PCB
PCB
PCB
PCB
• •
Q.C. Information for Batch# 37464
Page 3
Printed: 04/22/98 17:43:44
Blank Results Information
Organochlorine Pesticides Method : EPA 8080 I 608
Blank Detection
Analyte Result Limit
1016 BDL 1.0
1221 BDL 1.0
1232 BDL 1. 0
1242 BDL 1.0
1248 BDL 1.0
1254 BDL 1. 0
1260 BDL 1.0
• •
Page 4
Q.C. Information for Batch# 37464 Printed: 04/22/98 17:43:44
Sample Batch Information
Organochlorine Pesticides Method EPA 8080 / 608
Preparation Preparation Analysis
Sample ID Date Time By Notes · Date Time By Inst #
37464BLK 03/30/98 0800 TB 03/31/98 2050 JQZ GC-3
37464LCS 03/30/98 0800 TB 03/31/98 2114 JQZ GC-3
37464LCSD 03/30/98 0800 TB 03/31/98 2138 JQZ GC-3
93256-13 03/30/98 0800 TB 03/31/98 2026 JQZ GC-3
93394 03/30/98 0800 TB 03/31/98 0700 JQZ GC-3
93435 04/01/98 1500 JW 04/02/98 1651 JQZ GC-3
93574 04/03/98 1500 JW 04/06/98 1512 JQZ GC-3
93394MS 04/03/98 1500 JW 04/06/98 1322 JQZ GC-3
93394MSD 04/03/98 1500 JW 04/06/98 1448 JQZ GC-3
93667-1 04/07/98 0900 JW/SB 04/08/98 0748 JQZ GC-3
93805-6 04/13/98 1400 JW/SB I I
93793-1 04/13/98 1400 JW/SB 04/13/98 1805 JQZ GC-3
93854 04/13/98 1400 JW/SB 04/13/98 1632 JQZ GC-3
93874-2 04/13/98 1400 JW/SB PCB ONLY 04/14/98 1334 JQZ GC-3
93805-6 D I I I 04/13/98 1926 JQZ GC-3
93874-2DUP 04/13/98 1400 JW/SB PCB ONLY 04/14/98 1523 JQZ GC-3
37464BLKPCB 04/13/98 1400 JW/SB PCB ONLY 04/14/98 1307 JQZ GC-3
• •
Page 5
Analytical Services Inc. Batch QC
For Report Number :93874
Base Neutrals
Matrix : Aqueous Batch # 37611 Method : EPA 625
Lab Control Information LC LCD LC %Recovery RPD
Analyte %Rec %Re·c; RPD Range Range
Acenaphthene 74 85 13 46 -118 0 -31
Acenaphthylene 78 91 15 33 -145 0 -40
Anthracene 74 87 16 27 -133 0 -40
Benzidine 47 49 6 10 -200 0 -100
Benzo{a)anthracene 68 83 20 33 -143 0 -40
Benzo(b)fluoranthene 78 108 33 24 -159 0 -40
Benzo(k)fluoranthene 97 135 33 11 -162 0 -42
Benzo(a)pyrene 75 91 20 17 -163 0 -40
Benzo(ghi)pe~ylene 63 75 17 10 -219 0 -56
Benzyl butyl phthalate 60 72 17 10 -152 0 -40
Bis(2-chloroethyl)ether 78 91 16 10 -150 0 -50
Bis(2-chloroethoxy)methane 91 103 12 33 -184 0 -43
Bis(2-ethylhexyl)phthalate 71 88 21 10 -158 0 -40
Bis(2-chloroisopropyl)ether 89 81 10 36 -166 0. -46
4-Bromophenyl phenyl ether 76 91 18 53 -127 0 -40
2-Chloronaphthalene 76 88 14 60 -118 0 -40
4-Chlorophenyl phenyl ether 71 83 15 28 -158 0 -33
Chrysene 67 Bl 19 17 -168 0 -48
Dibenzo(a,h)anthracene 72 85 16 10 -227 0 -70
Di-n-butylphthalate 71 BO 13 10 -118 0 -50
1,3-Dichlorobenzene 56 67 18 10 -172 0 -40
1,2-Dichlorobenzene 60 71 18 32 -129 0 -40
1,4-Dichlorobenzene 57 69 18 36 -97 0 -28
3,3'-Dichlorobenzidine 107 131 20 10 -262 0 -100
Diethylphthalate 21 28 28 10 -114 0 -40
Dimethylphthalate 2 2 1 0 -110 0 -40
2,4-Dinitrotoluene 75 90 18 24 -96 0 -38
2,6-Dinitrotoluene 74 89 18 50 -158 0 -40
Di-n-octylphthalate 69 88 24 10 -146 0 -50
Fluoranthene 76 90 16 26 -137 0 -40
Fluorene 75 87 15 59 -129 0 -40
Hexachlorobenzene 86 105 19 10 -152 0 -40
Hexachlorobutadiene 40 47 17 24 -116 0 -40
Hexachloroethane 51 64 23 40 -113 0 -40
Indeno(l,2,3-cd)pyrene 64 75 16 10 -171 0 -45.
Isophorone 70 79 13 21 -196 0 -60
Naphthalene 83 84 1 21 -133 0 -40
Nitrobenzene 73 82 12 35 -180 0 -40
N-Nitrosodi-n-propylamine 74 90 20 41 -116 0 -38
Phenanthrene 76 90 17 54 -120 0 -40
Pyrene 63 79 22 26 -127 0 -31
1,2,4-Trichlorobenzene 63 71 13 44 -142 0 -28
• •
Page 6
Analytical Services Inc. Batch QC.
Base Neutrals
Matrix : Aqueous Batch # 37611 Method : EPA 625
Matrix Spike Information MS MSD MS %Recovery RPD
.Analyte %Rec %Rec RPD -Range Range
Acenaphthene 82 92 12 46 -118 0 -31
Acenaphthylene 87 99 14 33 -145 0 -40
Anthracene 84 99 17 27 -133 0 -40
Benzi dine 66 71 8 10 -200 0.-100
Benzo(a)anthracene 79 108 31 33 -143 0 -40
Benzo(b)fluoranthene 109 112 3 24 -159 0 -79
Benzo(k)fluoranthene 101 117 14 11 -162 0 -42
Benzo(a)pyrene 94 129 32 17 -163 0 -40.
Benzo(ghi)perylene 58 73 24 10 -219 0 -56
Benzyl butyl _phthalate 92 128 33 10 -152 0 -40
Bis(2-chloroethyl)ether 86 116 30 10 -150 0 -50
Bis (2-chloroethoxy)methane · 103 141 31 33 -184 0 -43
Bis(2-ethylhexyl)phthalate 101 137 30 10 -158 0 -40
Bis(2-chloroisopropyl)ether 73 100 31 36 -166 0 -46
4-Bromophenyl phenyl ether 87 103 16 53 -127 0 -40
2-Chloronaphthalene 86 99 14 60 -118 0 -40
4-Chlorophenyl phenyl ether 81 93 13 28 -158 0 -33
Chrysen·e · 76 105 32 17 168 0 48
Dibenzo(a,h)anthracene 63 80 24 10 -227 0 -70
Di-n-butylphthalate 89 104 15 10 -118 0 -50
1,3~Dichlorobenzene 72 95 27 10 -172 0 -40
1,2-Dichlorobenzene 77 102 28 32 -129 0 -40
1,4-Dichlorobenzene 75 99 28 36 -97 0 -28
3,3'-Dichlorobenzidine 61 81 28 10 -262 0 -100
Diethylphthalate 84 97 14 10 -114 0 -40
Dimethylphthalate 86 89 4 0 -110 0 -40
2,4-Dinitrotoluene 91 90 1 24 -96 0 -38
2,6-Dinitrotoluene 87 100 14 50 -158 0 -40
Di-n-octylphthalate 129 125 3 10 -146 0 -50
Fluoranthene 82 97 16 26 -137 0 -40
Fluorene 85 97 13 59 -121 0 -40
Hexachlorobenzene 99 116_ 16 10 -152 0 -40
Hexachlorobutadiene 58 78 29 24 -116 0 -40
Hexachloroethane 74 97 26 40 -113 0 -40
Indeno(l,2,3-cd)pyrene 57 73 24 10 -171 0 -45
Isophorone 79 108 31 21 -196 0 -60
Naphthalene 77 104 29 21 -133 0 -40
Nitrobenzene 82 110 29 35 -180 0 -40
N-Nitrosodi-n-propylamine 85 115 30 41 -116 0 -38
Phenanthrene 84 98 15 54 -120 0 -40
Pyrene 96 131 31 26 -127 0 -31
1,2,4-Trichlorobenzene 81 108 29 44 -142 0 -28
Matrix
Sample
37611BLK
37611LCS
37611LCSD
93574
AANote:
93570
93577
93592-1
AANote:
93612-2MS
93612-2MSD
93628
AANote:
93612-1
93612-2
93578
93667-1
AANote:
93874-2
93805-6
93824
93854
93874-2DUP
93793-1
93882-10
93948-2
93398-1
• •
Analytical Services Inc. Batch QC
Surrogate Recovery
Base Neutrals
Aqueous Batch# 37611 Method
% Recovery Objectives
Sl Nitrobenzene-d5 35 -
File Sl S2 S3 S4
. B5177 70
B5178 69
B5179 78
B5153 17
MATRIX EFFECT
B5154 42
B5155 60
B5156 67
BN only
B5187 81
B5188 74
B5190 31
MATRIX EFFECT
B5185 74
B5186 75
B5189 55
B5192
MATRIX EFFECT
A8922 88
A8925 68
A8938 40
A8940 104
A8943 83
A8944 43
A8946 96
A8949 85
B5345 89
Page 7
EPA 625
114
S5 S6
•
Q.C. Information for Batch# 37611
•
Page 8
Printed: 04/22/98 17:43:46
Blank Results Information
Base Neutrals Method: EPA 625
Blank Detection
Analyte Result Limit
Acenaphthene BDL 10
Acenaphthylene BDL 10
Anthracene BDL 10
Benzo(a)anthracene BDL 10
Benzo(b)fluoranthene BDL 10
Benzo(k)fluoranthene BDL 10
Benzo(a)pyrene BDL 10
Benzo(ghi)perylene BDL 10
Benzyl butyl phthalate BDL 10
Bis (2-ch_loroethyl) ether BDL 10
Bis(2-chloroethoxy)methane BDL 10
Bis(2-ethylhexyl)phthalate BDL 10
Bis(2-chloroisopropyl)ether BDL 10
4-Bromophenyl phenyl ether BDL 10
4-Chloroaniline BDL 20
2-Chloronaphthalene BDL 10
4-Chlorophenyl phenyl ether BDL 10
Chrysene BDL 10
Dibenzo(a,h)anthracene BDL 10
Dibenzofuran BDL 10
Di-n-butylphthalate BDL 10
1,3-Dichlorobenzene BDL 10
1,2-Dichlorobenzene BDL 10
1,4-Dichlorobenzene BDL 10
3,3'-Dichlorobenzidine BDL 20
Diethylphthalate BDL 10
Dimethylphthalate BDL 10
2,4-Dinitrotoluene BDL 20
2,6-Dinitrotoluene BDL 20
Di-n-octylphthalate BDL 10
Fluoranthene BDL 10
Fluorene BDL 10
Hexachlorobenzene BDL 10
Hexachlorobutadiene BDL 10
Hexachlorocyclopentadiene BDL 10
Hexachloroethane BDL 10
Indeno(l,2,3-cd)pyrene BDL 10
Isophorone BDL 10
2-Methylnaphthalene BDL 10
Naphthalene BDL 10
2-Nitroaniline BDL so
3-Nitroaniline BDL so
4-Nitroaniline BDL so
Nitrobenzene BDL 10
N-Nitrosodiphenylamine BDL 10
N-Nitrosodi-n-propylamine BDL 10
Phenanthrene BDL 10
Pyrene BDL 10
1,2,4-Trichlorobenzene BDL 10
• •
Page 9
Q.C. Information for Batch# 37611 Printed: 04/22/98 17:43:46
Sample Batch Information
Base Neutrals Method: EPA 625
Preparation Preparation Analysis
Sample ID Date Time By Notes Date Time By Inst #
37611BLK 04/03/98 0800 TB/JW 04/07/98 1916 RAC 5971
37611LCS 04/03/98 0800 TB/JW 04/07/98 1953 RAC 5971
37611LCSD 04/03/98 0800 TB/JW 04/07/98 2028 RAC 5971
93574 04/03/98 0800 TB/JW 04/04/98 0226 RAC 5971
93570 04/03/98 0800 TB/JW 04/04/98 0300 RAC 5_971
93577 04/03/98 0800 TB/JW 04/04/98 0333 RAC 5971
93578 04/03/98 0800 TB/JW 04/08/98 0230 RAC 5971
93592-1 04/03/98 0800 TB/JW 04/04/98 0407 RAC 5971
93612-1 04/03/98 1500 JW/TB BN ONLY 04/08/98 1205 RAC 5971
93612-2 04/03/98 1500 JW/TB 04/08/98 1242 RAC 5971
93612-2MS 04/03/98 1500 JW/TB 04/08/98 0118 RAC 5971
93612-2MSD 04/03/98 1500 JW/TB 04/08/98 0154 RAC 5971
93628 04/06/98 0900 JW/SB 04/08/98 0307 RAC 5971
93667-1 04/07/98 0900 JW/SB 04/08/98 0419 RAC 5971
93805-6 04/13/98 0900 JW/SB 04/17/98 1734 TAS 5970
93874-2DUP 04/13/98 1400 JW/SB 04/18/98 0445 RAC 5970
93874-2 04/13/98 1400 JW/SB 04/17/98 1540 RAC 5970
93793-1 04/13/98 1400 JW/SB 04/18/98 0523 RAC · 5970 ·
93824 04/13/98 1400 JW/SB 04/18/98 0138 RAC 5970
93854 04/13/98 1400 JW/SB 04/18/98 0253 RAC 5970
93882-10 04/14/98 1400 JW/SB 04/18/98 0637 RAC 5970
93948-2 04/17/98 0900 JW/SB 04/18/98 0828 RAC 5970
93398-1 04/17/98 0900 JW/SB 04/17/98 2220 TAS 5971
• •
Page 10
Analytical Services Inc. Batch QC
For Report Number :93874
Acids
Matrix : Aqueous Batch # 37612 Method : EPA 625
Lab Control Information LC LCD LC %Recovery RPD
Analyte %Rec. %Rec RPD Range Range
4-Chloro-3-methylphenol 85 85 0 23 -97 0 -42
2-Chlorophenol 80 84 4 27 -123 0 -40
2,4-Dichlorophenol 84 91 8 39 -135 0 . -40
2,4-Dimethylphenol 84 92 9 32 -119 0 -40
2,4-Dinitrophenol 14 13 6 10 -191 0 -50
4,6-Dinitro-2-methylphenol 125 108 14 10 -181 0 -93
2-Nitrophenol 84 88 4 19 -182 0 -40
4-Nitrophenol 42 51 20 10 -80 0 -50
Pentachlorop~enol 97 102 5 9 -103 0 -50
Phenol 37 42 12 12 -89 0 -42
2,4,6-Trichlorophenol 113 93 19 37 -144 0 -40
Matrix Spike Information MS MSD MS %Recovery RPD
Analyte %Rec %Rec RPD Range Range
4-Chloro-3-methylphenol 83 94 13 23 -97 0 -42
2-Chlorophenol 83 88 6 27 -123 0 -40
2,4-Dichlorophenol 86 93 7 39 -135 0 -40
2,4-Dimethylphenol 60 58 3 32 -119 0 -40
2,4-Dinitrophenol 96 182 62 10 -191 0 -50
4,6-Dinitro-2-methylphenol 116 158 31 10 -181 0 -93
2-Nitrophenol 87 94 7 19 -182 0 -40
4-Nitrophenol 57 74 26 10 -80 0 -50
Pentachlorophenol 99 125 23 9 -103 0 -50
Phenol 55 58 5 12 -89 0 -42
2,4,6-Trichlorophenol 108 117 8 37 -144 0 -40
Matrix
Sample
37612BLK
37612LCS
37612LCSD
93574
AANo.te:
93570
93577
93612-2MS
93612-2MSD
93628
AANote:
93612-1
93612-2
93578
93574D
AANote:
93628D
A"'Note:
93667-lD
AANote:
93667-1
AANote:
93874-2
93805-6
93824
93854
93874-2DUP
93793-1
93882-10
93948-2
93398-1
• •
Analytical Services Inc. Batch QC
Surrogate Recovery
Acids
Aqueous Batch# 37612 Method
% Recovery Objectives
Sl 2-Fluorophenol 21 -
S2 Phenol-d5 10 -
File Sl S2 S3 S4
B5174 66 42
B5175 65 39
B5176 69 44
B5150 7 4
MATRIX EFFECT;DO 1:10
B5151 31 21
B5152 34 22
B5182 84 60
B5183 40 30
B5196 20 40
MATRIX EFFECT;DO 1:10
B5180 52 34
B5181 73 56
B5184 21 34
B5191 41 22
1:10 DILUTION
B5194 46 15
1:10 DILUTION
B5193 32 3
1:10 DILUTION MATRIX EFFECT
B5195 3
MATRIX EFFECT;DO 1:10
A8923 40 28
A8924 29 23
A8939 24 17
A8941 33 33
A8942 32 27
A8945 29 32
A8947 46 38
A8948 26 24
B5343 58 37
Page 11
EPA 625
100
94
S5 S6
•
Q.C. Information for Batch# 37612
•
Page 12
Printed: 04/22/98 17:43:47
Blank Results Information
Acids Method: EPA 625
Analyte
Benzoic Acid
4-Chloro-3-methylphenol
2-Chlorophenol
2,4-Dichlorophenol
2,4-Dimethylphenol
2,4-Dinitrophenol
4,6-Dinitro-2-methylphenol
2-Methylphenol
4-Methylphenol
2-Nitrop_henol
4-Ni trophenol
Pentachlorophenol
Phenol
2,4,6-Trichlorophenol
2,4,5-Trichlorophenol
Blank
Result
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
Detection
Limit
so
10
10
10
10
so
so
10
10
so
so
20
10
10
10
• •
Page 13
Q.C. Information for Batch# 37612 Printed: 04/22/98 17:43:47
Sample Batch Information
Acids Method: EPA 625
Preparation Preparation Analysis
Sample ID Date Time By Notes Date Time By Inst #
37612BLK 04/03/98 0800 TB/JW 04/07/98 1727 RAC 5971
37612LCS 04/03/98 0800 TB/JW 04/07/98 1804 RAC 5971
37612LCSD 04/03/98 0800 TB/JW 04/07/98 1840 RAC 5971
93574 04/03/98 0800 TB/JW 04/03/98 1245 RAC 5971
93570 04/03/98 0800 TB/JW 04/04/98 0119 RAC 5971
93577 04/03/98 0800 TB/JW 04/04/98 0152 RAC 5971
93578 04/03/98 0800 TB/JW 04/07/98 2329 RAC 5971
93612-1 04/03/98 1500 JW/TB 04/07/98 2105 RAC 5971
93612-2 04/03/98 1500 JW/TB 04/07/98 2141 RAC 5971
93612-2MS 04/03/98 1500 JW/TB 04/07/98 2217 RAC 5971
93612-2MSD 04/03/98 1500 JW/TB 04/07/98 2253 RAC 5971
93628 04/06/98 0900 JW/SB 04/08/98 0644 RAC 5971
93667-1 04/07/98 0900 JW/SB 04/08/98 0608 RAC 5971
93574D I I 04/08/98 0343 RAC 5971
93628D I I 04/08/98 0532 RAC 5971
93667-lD I I 04/08/98 0455 RAC 5971
93805-6 04/13/98 0900 JW/SB 04/17/98 1656 TAS 5970
93874-2DUP 04/13/98 1400 JW/SB 04/18/9.S 0408 RAC 5970
93874-2 04/13/98 1400 JW/SB 04/17/98 1617 RAC 5970
93793-1 04/13/98 1400 JW/SB 04/18/98 0600 RAC 5970
93824 04/13/98 1400 JW/SB 04/18/98 0216 RAC 5970
93854 04/13/98 1400 JW/SB 04/18/98 0330 RAC 5970
93882-10 04/14/98 1400 JW/SB 04/18/98 0714 RAC 5970
93948-2 04/17/98 0900 JW/SB 04/18/98 0751 RAC 5970
93398-1 04/17/98 0900 JW/SB 04/17/98 2103 TAS 5971
• •
Page 14
Analytical Services Inc. Batch QC
For Report Number :93874
Volatile Organics
Matrix : Aqueous Batch # 37907 Method : EPA 624
Lab Control Information LC LCD LC %Recovery RPD
Analyte %Rec %Rec RPD Range Range
Benzene 99 104 6 37 -151 0 -20
Bromodichloromethane 100 93 7 35 -155 0 -20
Bromoform 114 104 9 45 -169 0 -20
Bromomethane 106 98 8 D -242 0 -20
Carbon tetrachloride 95 97 2 70 -140 0 -20
Chlorobenzene 99 103 4 37 -160 0 -20
Chloroethane 91 90 0 14 -230 0 -20
2-Chloroethylvinyl ether 101 122 18 D -305 0 -20
Chloroform 97 104 7 51 -138 0 -20
Chloromethane 89 84 6 D -273 0 -20
Dibromochloromethane 114 104 9 53 -149 0 -20
1,2-Dichlorobenzene 103 103 1 18 -190 0 -20
1,3-Dichlorobenzene 102 108 6 59 -156 0 -20
1,4-Dichlorobenzene 96 101 5 18 -190 0 -20
1,1-Dichloroethane 96 102 6 59 -155 0 -20
1,2-Dichloroethane 102 105 3 49 -155 0 -20
1,1-Dichloroethene 89 96 8 D 234 0 -20
trans-1,2-Dichloroethene 96 100 4 54 -156 0 -20
1,2-Dichloropropane 102 103 1 D -210 0 -20
cis-1,3-Dichloropropene 101 95 6 D -227 0 -20
trans-1,3-Dichloropropene 100 91 9 17 -183 0 -20
Ethylbenzene 97 103 6 37 -162 0 -20
Methylene chloride 91 99 8 D -221 0 -20·
1,1,2,2-Tetrachloroethane 110 104 5 46 -157 0 -20
Tetrachloroethene 112 96 15 64 -148 0 -20
Toluene 98 99 1 47 -150 0 -20
1,1,1-Trichloroethane 97 102 5 52 -162 0 -20
1,1~2-Trichloroethane 106 98 7 52 -150 0 -20
Trichloroethene 94 102 9 71 -157 0 -20
Trichlorofluoromethane 95 94 1 17 -181 0 -20
Vinyl chloride 96 91 5 D -251 0 -20
• •
Page 15
Analytical Services Inc. Batch QC
Volatile Organics
Matrix : Aqueous Batch # 37907 Method : EPA 624
Matrix Spike Information MS MSD MS %Recovery RPD
Analyte %Rec %Rec RPD Range Range
Benzene 115 112 3 37 -151 0 -20
Bromodichloromethane 113 109 4 35 -155 0 -20
Bromoform 103 102 0 45 -169 0 -20
Bromomethane 99 102 4 D -242 0 -20
Carbon tetrachloride 108 107 2 70 -140 0 -20
Chlorobenzene 112 110 2 37 -160 0 -20
Chloroethane 99 97 2 14 -230 0 -20
2-Chloroethylvinyl ether 8 1 167 D -305 0 -20
Chloroform 129 127 2 51 -138 0 -20
Chloromethane 96 102 .. 6 D -273 0 -20
Dibromochloromethane 114 116 2 53 -149 0 -20
1,2-Dichlorobenzene 111 110 1 18 -190 0 -20
1,3-Dichlorobenzene 112 111 1 59 -156 0 -20
1,4-Dichlorobenzene 110 106 4 18 -190 0 -20
1,1-Dichloroethane 108 107 2 59 -155 0 -20
1,2-Dichloroethane 118 117 1 49 -155 0 -20
1,1-Dichloroethene 98 96 2 D -234 0 -20
trans-1~2-Dichloroethene 108 104 ·3 54 156 0 -20
1,2-Dichloropropane 116 112 3 D -210 0 -20
cis-1,3-Dichloropropene 107 108 1 D -227 0 -20
trans-1,3-Dichloropropene 101 103 2 17 -183 0 -20
Ethylbenzene 116 113 3 37 -162 0 -20
Methylene chloride 106 105 1 D -221 0 -20
1,1,2,2-Tetrachloroethane 110 115 5 46 -157 0 -20
Tetrachloroethene 97 99 2 64 -148 0 -20
Toluene 115 115 0 47 -150 0 -20
1,1,1-Trichloroethane 111 107 4 52 -162 0 -20
1,1,2-Trichloroethane 113 110 2 52 -150 0 -20
Trichloroethene 116 113 3 71 -157 0 -20
Trichlorofluoromethane 99 100 1 17 -181 0 -20
Vinyl chloride 105 102 3 D -251 0 -20
• •
Page 16
Analytical Services Inc. Batch QC
Surrogate Recovery
Volatile Organics
Matrix Aqueous Batch# 37907 Method EPA 624
% Recovery Objectives
Sl 1,2-Dichloroethane-d4 76 -119
S2 Toluene-dB 88 -110
S3 Ethylbenzene-dl0 75 -115
S4 4-Brornofluorobenzene 86 -115
Sample File Sl S2 S3 S4 S5 S6
37907BLK A2530 102 100 101 97
93874-_2 A2532 104 99 97 98
93874-2MS A2533 102 103 103 101
93874-2MSD A2534 99 105 104 99
93874-2DUP A2535 104 100 99 97
93874-3 A2536 104 99 100 96
37907LCS A2476 106 103 100 102
37907LCSD A2488 106 100 100 101
94154-1 A2719 107 104 99 103
94154-2 A2720 102 101 104 104
93917-2 A2685 111 105 99 108
93917-3 A2686 113 106 101 111
93917-4 A2687 111 110 102 109
93917-5 A2688 111 109 100 107
93917-6 A2689 122 105 97 107
94125-4 A2690 107 110 102 109
94125-6 A2691 111 108 98 107
93917-6DUP A2700 99 103 99 70
93917-6DUP2 A2716 109 101 100 99
•
Q.C. Information for Batch# 37907
•
Page 17
Printed: 04/22/98 17:43:49
Blank Results Information
.Volatile Organics Method: EPA 624
Analyte
Acetone
Benzene
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroet_hane
Chloroform
Chloromethane
Dibromochloromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethene
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethylbenzene
2-Hexanone
Methylene chloride
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Vinyl chloride
Xylenes
2-Chloroethylvinyl ether
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,2-Dichloroethene
Trichlorofluoromethane
Blank
Result
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
Detection
Limit
100
2
10
10
10
100
5
2
10
5
2
10
10
2
2
2
2
2
2
2
2
50
10
2
2
2
2
2
2
10
2
10
10
10
10
2
10
• •
Page 18
Q.C. Information for Batch# 37907 Printed: 04/22/98 17:43:49
Sample Batch Information
.Volatile Organics Method EPA 624
Preparation Preparation Analysis
Sample ID Date Time By Notes Date Time By Inst #
37907BLK I I 04/15/98 2027 LLP VOAl
93874-2 I I 04/15/98 2118 LLP VOAl
93874-2MS I I 04/15/98 2144 LLP VOAl
93874-2MSD I I 04/15/98 2210 LLP VOAl
93874-2DUP I I 04/15/98 2235 LLP VOAl
93874-3 I I 04/15/98 2301 LLP VOAl
37907LCS I I 04/14/98 1931 LLP VOAl
37907LCSD I I 04/14/98 2051 LLP VOAl
94154-1 I I 04/21/98 1611 LLP VOAl
94154-2 I I 04/21/98 1641 LLP VOAl
93917-2 I I 04/20/98 2153 LLP VOAl
93917-3 I I 04/20/98 2219 LLP VOAl
93917-4 I I 04/20/98 2245 LLP VOAl
93917-5 I I 04/20/98 2311 LLP VOAl
93917-6 I I 04/20/98 2337 LLP VOAl
94125-4 I I 04/21/98 0003 LLP VOAl
94125-6 I I 04/21/98 0029 LLP VOAl
93917-6DUP I I 04/21/98 1050 LLP VOAl
93917-6DUP2 I I 04/21/98 1849 RFA VOAl
QC Batch
Batch
Number
37516
37687
AANote
37687
AANote
37687
AANote
37687
A.A.Note
37687
........ Note
37687
AANote
37687
AANote
37687
.......... Note
37687 AANote
37687
AANote
37687
AANote
37687
AANote
37687
AANote
37687
AANote
37687
AANote
37687
AANote
• •
Page 19
Analytical Services Inc. Batch QC
For Report Number :93874
General Information
Analysis
Analyte Method
Hg
Ag
BATCH
EPA 245.1
EPA 200.7
PASSES ON LCS/MS-LCS/LCSD
Matrix
Aqueous
Aqueous
AVE 115
<
<
Al EPA 200.7 Aqueous <
BATCH PASSES ON LCSD/MS/MSD-LCS/LCSD AVE 91
As EPA 200.7 Aqueous <
BATCH PASSES ON LCSD/MS/MSD-LCS/LCSD AVE 91
Ba EPA 200.7 Aqueous <
BATCH PASSES ON LCSD/MS/MSD-LCS/LCSD AVE 90
Be EPA 200.7 Aqueous <
BATCH PASSES ON LCSD/MS/MSD-LCS/LCSD AVE 90
Ca EPA 200.7 Aqueous <
BATCH PASSES ON LCS/LCSD/MS/MSD
Blank
Result
0.0002
0.0100
0.1000
0.0100
0.0100
0.0010
0.0300
Cd EPA 200.7 Aqueous < 0.0050
BATCH PASSES ON LCSD/MS/MSD-LCS/LCSD AVE 90
Co EPA 200.7 Aqueous < 0.0400
BATCH PASSES ON LCSD/MS/MSD-LCS/LCSD AVE 91
Cr EPA 200.7 Aqueous < 0.0050
BATCH PASSES ON LCSD/MS/MSD-LCS/LCSD AVE 91
Cu EPA 200.7 Aqueous < 0.0100
BATCH PASSES ON LCSD/MS/MSD/PDS-LCS/LCSD AVE 88
Fe EPA 200.7 Aqueous < 0.0200
BATCH PASSES ON LCSD/MS/MSD-LCS/LCSD AVE 91
K EPA 200.7 Aqueous < 0.1200
BATCH PASSES ON LCS/LCSD/MS/MSD
Mg EPA 200.7 Aqueous < 0.0100
BATCH PASSES ON LCS/LCSD/MS/MSD
Mn EPA 200.7 Aqueous < 0.0100
BATCH PASSES ON LCSD/MS/MSD-LCS/LCSD AVE 92
Na EPA 200.7 Aqueous < 0.0500
BATCH PASSES ON LCS/LCSD
Ni EPA 200.7 Aqueous < 0.0100
BATCH PASSES ON LCSD/MS/MSD-LCS/LCSD AVE 88
Prep.
Method
• •
Page 20
QC Batch
Batch
Number
37687
AANote
Analytical Services Inc. Batch QC
For Report Number :93874
General Information
Analysis
Analyte Method Matrix
Sb EPA 200.7 Aqueous <
BATCH PASSES ON LCSD/MS/MSD-LCS/LCSD AVE 88
37687 V EPA 200.7 Aqueous <
AANote BATCH PASSES ON LCS/LCSD
37687
,,,_,..,Note
37694
AANote
37694
......... Note
37694
.,..,...Note
Zn EPA 200.7 Aqueous
BATCH PASSES ON LCSD/MS/MSD-LCS/LCSD AVE
Se EPA 270.2 Aqueous
QC PASSES ON LCS,LCSD,MS
Tl EPA 279.2 Aqueous
QC PASSES ON LCS,LCSD
Pb EPA 239.2 Aqueous
QC PASSES ON LCS,LCSD
<
87
<
<
<
Blank
Result
0.0060
0.0200
0.0200
0.0030
0.0020
0.0020
37759 BOD<5 hi SM 5210 B. Aqueous < 5.0000
......... Note
37759
37817
3-7864
37875
37884
AANote
37923
Lab Control
Batch
Number
37516
37687
37687
37687
37687
37687
37687
37687
37687
37687
2ND DUP FAILED/BATCH PASSES ON ALL OTHER QC DATA
BOD<5 low SM 5210 B Aqueous < 5.0000
N EPA 350.2 Aq/Solid < 0.1000
pH EPA 150.1 Aqueous 0.0000
CN EPA 335.2 Aqueous < 0.0200
0/G EPA 1664 Aqueous 0.0000
LACK OF SAMPLE FOR MSD. BATCH PASSES ON LCS/LCSD AND MS.
TSS EPA 160.2 Aqueous < 5.0000
Information
LC LCD LC %-Recovery
Analyte Method %Rec %Rec RPD Range
Hg EPA 245.1 96 97 1 76 -124
Ag EPA 200.7 110 120 9 85 -115
Al EPA 200.7 82 100 20 85 -115
As EPA 200.7 81 100 21 85 -115
Ba EPA 200.7 81 99 20 85 -115
Be EPA 200.7 80 99 21 85 -115
Ca EPA 200.7 110 100 10 85 -115
Cd EPA 200.7 80 99 21 85 -115
Co EPA 200.7 81 100 21 85 -115
Cr EPA 200.7 81 100 21 85 -115
Prep.
Method
RPD
Range
0 -20
0 -20
0 -20
0 -20
0 -20
0 -20
0 -20
0 -20
0 -20
0 -20
• •
Page 21
Analytical Services Inc. Batch QC
For Report Number :93874
Lab Control Information
Batch LC LCD LC %Recovery RPD
Number Analyte Method %-Rec %Rec RPD Range Range
37687 Cu EPA 200.7 79 97 20 85 -115 0 -20
37687 Fe EPA 200.7 82 100 20 85 -115 0 -20
37687 K EPA 200.7 97 91 6 85 -115 0 -20
37687 Mg EPA 200.7 110 100 10 85 -115 0 -20
37687 Mn EPA 200.7 83 100 19 85 -115 ·O -20
37687 Na EPA 200.7 98 93 5 85, -115 0 -20
37687 Ni EPA 200.7 79 97 20 85 -115 0 -20
37687 Sb EPA 200.7 79 97 20 85 -115 0 -20
37687 V EPA 200.7 110 91 19 85 -115 0 -20
37687 Zn EPA 200.7 78 96 21 85 -115 0 -20
37694 s~ EPA 270.2 92 98 6 76 -124 0 -20
37694 Tl EPA 279.2 114 123 8 76 -124 0 -20
37694 Pb EPA 239.2 120 119 1 76 -124 0 -20
37759 B0D<5 hi SM 5210 B 92 92 0 81 -118 0 -30
37759 B0D<5 low SM 5210 B 92 99 7 81 -118 0 -30
37817 N EPA 350.2 98 98 0 75 -125 0 -30
37864 pH EPA 150.1 98 98 0 80 -120 0 -20
37875 CN EPA 335.2 80 83 4 75 -125 0 -30
37884 0/G EPA 1664 53 67 23 32 -103 0 -40
37923 TSS EPA 160.2 96 102 6 60 -140 0 -40
Matrix Spike Information
Batch MS MSD MS %Recovery RPD
Number Analyte Method %Rec %Rec RPD Range Range
37516 Hg EPA 245.1 97 97 0 76 -124 0 -20
37687 Ag EPA 200.7 110 120 9 85 -115 0 -20
37687 Al EPA 200.7 98 94 4 85 -115 0 -20
37687 As EPA 200.7 99 96 3 85 -115 0 -20
37687 Ba EPA 200.7 98 93 5 85 -115 0 20
37687 Be EPA 200.7 98 94 4 85 -115 0 -20
37687 Ca EPA 200.7 98 89 10 85 -115 0 -20
37687 Cd EPA 200.7 97 93 4 85 -115 0 -20
37687 Co EPA 200.7 91 88 3 85 -115 0 -20
37687 Cr EPA 200.7 98 95 3 85 -115 0 -20
37687 Cu EPA 200.7 94 90 4 85 -115 0 -20
37687 Fe EPA 200.7 100 98 2 85 -115 0 -20
37687 K EPA 200.7 110 110 0 85 -115 0 -20
37687 Mg EPA 200.7 100 97 3 85 -115 0 -20
37687 Mn EPA 200.7 99 95 4 85 -115 0 -20
37687 Na EPA 200.7 130 120 8 85 -115 0 -20
37687 Ni EPA 200.7 94 91 3 85 -115 0 -20
37687 Sb EPA 200.7 97 92 5 85 -115 0 -20
37687 V EPA 200.7 130 120 8 85 -115 0 -20
37687 Zn EPA 200.7 90. 91 1 85 -115 0 -20
37694 Se EPA 270.2 77 72 7 76 -124 0 -20
• •
Analytical Services Inc. Batch QC
For Report Number :93874
Matrix Spike Information
Batch MS MSD MS
Number Analyte Method %Rec %Rec RPD
37694 Tl EPA 279.2 143 163 13
37694 Pb EPA 239.2 183 186 2
3781 7 N EPA 350.2 100 100 0
37875 CN EPA 335.2 87 82 6
37884 O/G EPA 1664 74 0 NC
37923 TSS EPA 160.2 106 106 0
Post Digestion Spike. Information
Batch PDS
Number Analyte Method %Rec
37687 Ag EPA 200.7 190
37687 Al EPA 200.7 120
37687 As EPA 200.7 120
37687 Ba EPA 200.7 120
37687 Be EPA 200.7 120
37687 Ca EPA 200.7 230
37687 Cd EPA 200.7 120
37687 Co EPA 200.7 110
37687 Cr EPA 200.7 120
37687 Cu EPA 200.7 110
37687 Fe EPA 200.7 100
37687 K EPA 200.7 43
37687 Mg EPA 200.7 160
37687 Mn EPA 200.7 120
37687 Na EPA 200.7 84
37687 Ni EPA 200.7 110
37687 Sb EPA 200.7 120
37687 V EPA 200.7 160
37687 Zn . EPA 200.7 110
37694 Se EPA 270.2 47
37694 Tl EPA 279.2 7
37694 Pb EPA 239.2 71
Unspiked Sample Duplicate Information
Batch Sample 1 Sample
Number Analyte Method RPD RPD
3 7759 ' BOD<5 hi SM 5210 B 14 37
37817 N EPA 350.2 0 3
37864 pH EPA 150.1 0
37875 CN EPA 335.2 0 0
37923 TSS EPA 160.2 0 0
Page 22
%-Recovery RPD
Range Range
76 -124 0 -20
76 -124 0 -20
75 -125 0 -30
75 -125 0 -30
32 -103 0 -40
60 -140 0 -40
%Recovery
Range
85 -115
85 -115
85 -115
85 -115
85 ~ 115
85 -115
85 -115
85 -115
85 -115
85 -115
85 -115
85 -115
85 -115
85 -115
85 -115
85 -115
85 -115
85 -115
85 -115
76 -124
76 -124
76 -124
2 RPD
Range
0 -30
0 -30
0 -20
0 -30
0 -40
• •
Page 23
Q.C. Information for Batch# 37516 For Report Number :93874
Sample Batch Information
Analysis : Hg
Preparation Preparation Analysis
Sample ID Tag Date Time By Notes Date Time By Inst
37516BLANK HG 04/13/98 0725 FBS 04/13/98 1141 FBS HGl
37516LCS HG 04/13/98 0725 FBS 04/13/98 1144 FBS HGl
37516LCSD HG 04/13/98 0725 FBS 04/13/98 1146 FBS HGl
93874-lMS HG 04/13/98 0725 FBS 04/13/98 1148 FBS HGl
93874-lMSD HG 04/13/98 0725 FBS 04/13/98 1151 FBS HGl
93874-lDUP HG 04/13/98 0725 FBS 04/13/98 1153 FBS HGl
93804 HG 04/13/98 0725 FBS 04/13/98 1158 FBS HGl
93844-1 HG 04/13/98 0725 FBS 04/13/98 1200 FBS HGl
93874-1 HG 04/13/98 0725 FBS 04/13/98 1156 FBS HGl
93881 HG 04/13/98 0725 FBS 04/13/98 1203 FBS HGl
93895-lT HG 04/13/98 0725 FBS TOT 04/13/98 1210 FBS HGl
93895-2T HG 04/13/98 0725 FBS TOT 04/13/98 1212 FBS -HGl
93895-3T HG 04/13/98 0725 FBS TOT 04/13/98 1215 FBS HGl
93895-4T HG 04/13/98 0725 FBS TOT 04/13/98 1217 FBS HGl
93895-5T HG 04/13/98 0725 FBS TOT 04/13/98 1220 FBS HGl
93895-6T HG 04/13/98 0725 FBS TOT 04/13/98 1222 FBS HGl
93895-7T HG 04/13/98 0725 FBS TOT 04/13/98 1224 FBS HGl
93895-lD HG 04/13/98 0725 FBS NEAT 04/13/98 ·1227 FBS HGl
93895-2D HG 04/13/98 0725 FBS NEAT 04/13/98 1229 FBS HGl
93895-3D HG 04/13/98 0725 FBS NEAT 04/13/98 1237 FBS HGl
93895-4D HG 04/13/98 0725 FBS NEAT 04/13/98 1239 FBS HGl
93895-5D HG 04/13/98 0725 FBS NEAT 04/13/98 1341 FBS HGl
93895-6D HG 04/13/98 0725 FBS NEAT 04/13/98 1244 FBS HGl
93895-7D HG 04/13/98 0725 FBS NEAT 04/13/98 1246 FBS HGl
• •
Page 24
Q.C. Information for Batch# 37687 For Report Number :93874
Sample Batch Information
Analysis Ag, Al, As, Ba, Be, Ca, Cd, Co, Cr, Cu, Fe, K, Mg, Mn, Na, Ni
Sb V Zn
Preparation Preparation Analysis
Sample ID Tag Date Time By Notes Date Time By Inst
37687BLANK 04/13/98 0915 KSP TRACE 04/14/98 0219 MAB ICP2
37687LCS 04/13/98 0915 KSP TRACE 04/14/98 0222 MAB ICP2
37687LCSD 04/13/98 0915 KSP TRACE 04/14/98 0226 MAB ICP2
93874-lMS 04/13/98 0915 KSP TRACE 04/14/98 0230 MAB ICP2
93874-lMSD 04/13/98 0915 KSP TRACE 04/14/98 0234 MAB ICP2
93805-lPDS 04/13/98 0915 KSP TRACE 04/14/98 0237 MAB ICP2
93874-lDUP 04/13/98 0915 KSP TRACE 04/14/98 0241 MAB ICP2
93805-1 04/13/98 0915 KSP TRACE 04/14/98 0248 MAB .ICP2
93805-2 04/13/98 0915 KSP TRACE 04/14/98 0252 MAB ICP2
93805-3 04/13/98 0915 KSP TRACE 04/14/98 0342 MAB ICP2
93805-4 04/13/98 0915 KSP TRACE 04/14/98 0346 MAB ICP2
93805-5 04/13/98 0915 KSP TRACE 04/14/98 0350 MAB ICP2
93805-7 04/13/98 0915 KSP TRACE 04/14/98 0354 MAB ICP2
93809 04/13/98 0915 KSP TRACE 04/14/98 0357 MAB ICP2
93837 04/13/98 0915 KSP TRACE 04/14/98 0401 MAB ICP2
93853-11 04/13/98 0915 KSP TRACE 04/14/98 0532 MAB ICP2
93853-13 04/13/98 0915 KSP TRACE 04/14/98 0535 MAB ·ICP2
93853-2 04/13/98 0915 KSP TRACE 04/14/98 0405 MAB ICP2
93853-5 04/13/98 0915 KSP TRACE 04/14/98 0524 MAB ICP2
93853-8 04/13/98 0915 KSP TRACE 04/14/98 0528 MAB ICP2
93871-1 04/13/98 0915 KSP TRACE 04/14/98 0518 MAB ICP2
93808 04/13/98 0915 KSP TRACE 04/14/98 0522 MAB ICP2
93805-6 04/13/98 0915 KSP TRACE 04/14/98 0539 MAB ICP2
93874-1 04/13/98 0915 KSP TRACE 04/14/98 0245 MAB ICP2
93679-1 04/13/98 0915 KSP TRACE 04/14/98 0425 MAB ICP2
93679-2 04/13/98 0915 KSP TRACE 04/14/98 0429 MAB ICP2
93700 04/13/98 0915 KSP TRACE 04/14/98 0543 MAB ICP2
• •
Page 25
Q.C. Information for Batch# 37694 For Report Number :93874
Sample Batch Information
Analysis : Se, Tl, Pb
Preparation Preparation Analysis
Sample ID Tag Date Time By Notes Date Time By Inst
37694BLANK As 04/14/98 0835 KSP GFAA 04/15/98 1109 MLR AAl
37694LCS As 04/14/98 0835 KSP GFAA 04/15/98 1109 MLR AAl
37694LCSD As 04/14/98 0835 KSP GFAA 04/15/98 1109 MLR AAl
93874-lMS As 04/14/98 0835 KSP GFAA 04/15/98 1109 MLR AAl
93874-lMSD As 04/14/98 0835 KSP · GFAA 04/15/98 1109 MLR AAl
93733PDS As 04/14/98 0835 KSP GFAA 04/15/98 1109 MLR AAl
93874-lDUP As 04/14/98 0835 KSP GFAA 04/15/98 1109 MLR AAl
93687-22 As 04/14/98 0835 KSP GFAA 04/15/98 1109 MLR AAl
93687-23 As 04/14/98 0835 KSP GFAA 04/15/98 1109 MLR AAl
93687-24 As 04/14/98 0835 KSP GFAA 04/15/98 1109 MLR AAl
93733 As 04/14/98 0835 KSP GFAA 04/15/98 1109 MLR AAl
93874-1 As 04/14/98 0835 KSP GFAA 04/15/98 1109 MLR AAl
93881 As 04/14/98 0835 KSP GFAA 04/15/98 1109 MLR AAl
93897-1 As 04/14/98 0835 KSP GFAA 04/15/98 1109 MLR AAl
93897-2 As 04/14/98 0835 KSP GFAA 04/15/98 1109 MLR AAl
93898 As 04/14/98 0835 KSP GFAA 04/15/98 1109 MLR AAl
37694BLANK . Se 04/14/98 0835 KSP GFAA 04/15/98 1316 MLR AAl
37694LCS Se 04/i4/98 0835 KSP GFAA 04/15/98 1316 MLR AAl
37694LCSD Se 04/14/98 0835 KSP GFAA 04/15/98 1316 MLR AAl
93874-lMS Se 04/14/98 0835 KSP GFAA 04/15/98 1316 MLR AAl
93874-lMSD Se 04/14/98 0835 KSP GFAA 04/15/98 1316 MLR AAl
93733PDS Se 04/14/98 0835 KSP GFAA 04/15/98 1316 MLR AAl
93874-lDUP Se 04/14/98 0835 KSP GFAA 04/15/98 1316 MLR AAl
93687-22 Se 04/14/98 0835 KSP GFAA 04/15/98 1316 MLR AAl
93687-23 Se 04/14/98 0835 KSP GFAA 04/15/98 1316 MLR AAl
93687-24 Se 04/14/98 0835 KSP GFAA 04/15/98 1316 MLR AAl
93733 Se 04/14/98 0835 KSP GFAA 04/15/98 1316 MLR AAl
93874-1 Se 04/14/98 0835 KSP GFAA 04/15/98 1316 MLR AAl
93881 Se 04/14/98 0835 KSP GFAA 04/15/98 1316 MLR AAl
93897-1 Se 04/14/98 0835 KSP GFAA 04/15/98 1316 MLR AAl
93897-2 Se 04/14/98 0835 KSP GFAA 04/15/98 1316 MLR AAl
93898 Se 04/14/98 0835 KSP GFAA 04/15/98 1316 MLR AAl
37694BLANK Tl 04 /14/98 0835 KSP GFAA 04/15/98 1608 MLR AAl
37694LCS Tl 04/14/98 0835 KSP GFAA 04/15/98 1608 MLR AAl
37694LCSD Tl 04/14/98 0835 KSP GFAA 04/15/98 1608 MLR AAl
93874-lMS Tl 04/14/98 0835 KSP GFAA 04/15/98 1608 MLR AAl
93874-lMSD Tl 04/14/98 0835 KSP GFAA 04/15/98 1608 MLR AAl
93733PDS Tl 04/14/98 0835 KSP GFAA 04/15/98 1608 MLR AAl
93874-lDUP Tl 04/14/98 0835 KSP GFAA 04/15/98 1608 MLR AAl
93687-22 Tl 04/14/98 0835 KSP GFAA 04/15/98 1608 MLR AAl
93687-23 Tl 04/14/98 0835 KSP GFAA 04/15/98 1608 MLR AAl
93687-24 Tl 04/14/98 0835 KSP GFAA 04/15/98 1608 MLR AAl
93733 Tl 04/14/98 0835 KSP GFAA 04/15/98 1608 MLR ·AAl
93874-1 Tl 04/14/98 0835 KSP GFAA 04/15/98 1608 MLR AAl
93881 Tl 04/14/98 0835 KSP GFAA 04/15/98 1608 MLR AAl
93897-1 Tl 04/14/98 0835 KSP GFAA 04/15/98 1608 MLR AAl
93897-2 Tl 04/14/98 0835 KSP GFAA 04/15/98 1608 MLR AAl
93898 Tl 04/14/98 0835 KSP GFAA 04/15/98 1608 MLR AAl
• •
Page 26
Q.C. Information for Batch# 37694 For Report Number :93874
Sample Batch Information
Analysis : Se, Tl, Pb
Preparation Preparation Analysis
Sample ID Tag Date Time By Notes Date Time By Inst
37694BLANK Pb 04/14/98 0835 KSP GFAA 04/16/98 1330 MLR AA2
37694LCS Pb 04/14/98 0835 KSP GFAA 04/16/98 1330 MLR AA2
37694LCSD Pb 04/14/98 0835 KSP GFAA 04/16/98 1330 MLR AA2
93874-lMS Pb 04/14/98 0835 KSP GFAA 04/16/98 1330 MLR AA2
93874-lMSD Pb 04/14/98 0835 KSP · GFAA 04/16/98 1330 MLR AA2
93733PDS Pb 04/14/98 0835 KSP GFAA 04/16/98 1330 MLR AA2
93874-lDUP Pb 04/14/98 0835 KSP GFAA 04/16/98 1330 MLR AA2
93687-22 Pb 04/14/98 0835 KSP GFAA 04/16/98 1330 MLR AA2
93687-23 Pb 04/14/98 0835 KSP GFAA 04/16/98 1330 MLR AA2
93687-24 Pb 04/14/98 0835 KSP GFAA 04/16/98 1330 MLR AA2
93733 Pb 04/14/98 0835 KSP GFAA 04/16/98 1330 MLR AA2
93874-1 Pb 04/14/98 0835 KSP GFAA 04/16/98 1330 MLR AA2
93881 Pb 04/14/98 0835 KSP GFAA 04/16/98 1330 MLR AA2
93897-1 Pb 04/14/98 0835 KSP GFAA 04/16/98 1330 MLR AA2
93897-2 Pb 04/14/98 0835 KSP GFAA 04/16/98 1330 MLR AA2
93898 Pb 04/14/98 0835 KSP GFAA 04/16/98 1330 MLR AA2
37694BLANK Sb 04/14/98 0835 KSP GFAA 04/16/98 1147 MLR AAl
37694LCS Sb 04/14/98 0835 KSP . GFAA 04/16/98 1147 MLR AAl
37694LCSD Sb 04/14/98 0835 KSP GFAA 04/16/98 1147 MLR AAl
93874-lMS Sb 04/14/98 0835 KSP GFAA 04/16/98 1147 MLR AAl
93874-lMSD Sb 04/14/98 0835 KSP GFAA 04/16/98 1147 MLR AAl
93733PDS Sb 04/14/98 0835 KSP GFAA 04/16/98 1147 MLR AAl
93874-lDUP Sb 04/14/98 0835 KSP GFAA 04/16/98 1147 MLR AAl
93687-22 Sb 04/14/98 0835 KSP GFAA 04/16/98 1147 MLR AAl
93687-23 Sb 04/14/98 0835 KSP GFAA 04/16/98 1147 MLR AAl
93687-24 Sb 04/14/98 0835 KSP GFAA 04/16/98 1147 MLR AAl
93733 Sb 04/14/98 0835 KSP GFAA 04/16/98 1147 MLR AAl
93874-1 Sb 04/14/98 0835 KSP GFAA 04/16/98 1147 MLR AAl
93881 Sb 04/14/98 0835 KSP GFAA 04/16/98 1147 MLR AAl
93897-1 Sb 04/14/98 0835 KSP GFAA 04/16/98 1147 MLR AAl
93897-2 Sb 04/14/98 0835 KSP GFAA 04/16/98 1147 MLR AAl
93898 Sb .04/14/98 0835 KSP GFAA 04/16/98 1147 MLR AAl
37694BLANK Cd 04/14/98 0835 KSP GFAA 04/17/98 0849 MLR AAl
37694LCS Cd 04/14/98 0835 KSP GFAA 04/17/98 0849 MLR AAl
37694LCSD Cd 04/14/98 0835 KSP GFAA 04/17/98 0849 MLR AAl
93874-lMS Cd 04/14/98 0835 KSP GFAA 04/17/98 0849 MLR AAl
93874-lMSD Cd 04/14/98 0835 KSP GFAA 04/17/98 0849 MLR AAl
93733PDS Cd 04/14/98 0835 KSP GFAA 04/17/98 0849 MLR AAl
93B74-lDUP Cd 04/14/98 0835 KSP GFAA 04/17/98 0B49 MLR AAl
93687-22 Cd 04/14/9B 0B35 KSP GFAA 04/17/98 0B49 MLR AAl
93687-23 Cd 04/14/9B 0B35 KSP GFAA 04/17/98 0B49 MLR AAl
93687-24 Cd 04/14/9B 0B35 KSP GFAA 04/17/98 0B49 MLR AAl
93733 Cd 04/14/9B 0B35 KSP GFAA 04/17/98 0849 MLR ·AA1
93874-1 Cd 04/14/98 0835 KSP GFAA 04/17/98 0B49 MLR AAl
93881 Cd 04/14/98 0B35 KSP GFAA 04/17/9B 0849 MLR AAl
93897-1 Cd 04/14/9B 0B35 KSP GFAA 04/17/98 0849 MLR AAl
93897-2 Cd 04/14/98 0835 KSP GFAA 04/17/98 0B49 MLR AAl
93B98 Cd 04/14/98 0B35 KSP GFAA 04/17/9B 0B49 MLR AAl
, • •
Information
Page 27
Q.C. for Batch# 37694 For Rep_ort Number :93874
Sample Batch Information
Analysis : Se, ·Tl, Pb
Preparation Preparation Analysis
Sample ID Tag Date Time By Notes Date Time By Inst
37694BLANK Be 04/14/98 0835 KSP GFAA 04/17/98 1059 MLR AAl
37694LCS Be 04/14/98 0835 KSP GFAA 04/17/98 1059 MLR AAl
37694LCSD Be 04/14/98 0835 KSP GFAA 04/17/98 1059 MLR AAl
93874-lMS Be 04/14/98 0835 KSP GFAA 04/17/98 1059 MLR AAl
93874-lMSD Be 04/14/98 0835 KSP . GFAA 04/17/98 1059 MLR AAl
93733PDS Be 04/14/98 0835 KSP GFAA 04/17/98 1059 MLR AAl
93874-lDUP Be 04/14/98 0835 KSP GFAA 04/17/98 1059 MLR AAl
93687-22 Be 04/14/98 0835 KSP GFAA 04/17/98 1059 MLR AAl
93687-23 Be 04/14/98 0835 KSP GFAA 04/17/98 1059 MLR AAl
93687-24 Be 04/14/98 0835 KSP GFAA 04/17/98 1059 MLR AAl
93733 Be 04/14/98 0835 KSP GFAA 04/17/98 1059 MLR AAl
93874-1 Be 04/14/98 0835 KSP GFAA 04/17/98 1059 MLR AAl
93881 Be 04/14/98 0835 KSP GFAA 04/17/98 1059 MLR AAl
93897-1 Be 04/14/98 0835 KSP GFAA 04/17/98 1059 MLR AAl
93897-2 Be 04/14/98 0835 KSP GFAA 04/17/98 1059 MLR AAl
93898 Be 04/14/98 0835 KSP GFAA 04/17/98 1059 MLR AAl
• •
Page 28
Q.C. Information for Batch# 37759 For Report Number :93874
Sample Batch Information
Analysis : BOD<5 hi, BOD<5 low
Preparation Preparation Analysis
Sample ID Tag Date Time By Notes Date Time By Inst
37759BLK 04/10/98 1600 LH/SK 04/15/98 0630 LH/SK
37759LCS 04/10/98 1600 LH/SK 04/15/98 0630 LH/SK
37759LCSD 04/10/98 1600 LH/SK 04/15/98 0630 LH/SK
93754-1 04/10/98 1820 LH/SK 04/15/98 0630 LH/SK
93754-lDUP 04/10/98 1820 LH/SK 04/15/98 0630 LH/SK
93754-2 04/10/98 1820 LH/SK 04/15/98 0630 LH/SK
93786-1 04/10/98 1820 LH/SK 04/15/98 0630 LH/SK
93786-2 04/10/98 1820 LH/SK 04/15/98 0630 LH/SK
93757-1 04/10/98 1820 LH/SK 04/15/98 0630 LH/SK
93760-1 04/10/98 1820 LH/SK 04/15/98 0630 LH/SK
93748-1 04/10/98 1820 LH/SK 04/15/98 0630 LH/SK
93748-2 04/10/98 1820 LH/SK 04/15/98 0630 LH/SK
93748-3 04/10/98 1820 LH/SK 04/15/98 0630 LH/SK
93748-4 04/10/98 1820 LH/SK 04/15/98 0630 LH/SK
93772-1 04/10/98 1820 LH/SK 04/15/98 0630 LH/SK
93772-2 04/10/98 1820 LH/SK 04/15/98 0630 LH/SK
93776 04/10/98 1820 LH/SK 04/15/98 0630 LH/SK
93777 04/10/98 1820 LH/SK .04/15/98 0630 LH/SK
93779-1 04/10/98 1820 LH/SK 04/15/98 0630 LH/SK
93783 04/10/98 1820 LH/SK 04/15/98 0630 LH/SK
93784 04/10/98 1820 LH/SK 04/15/98 0630 LH/SK
93802 04/10/98 1820 LH/SK 04/15/98 0630 LH/SK
37759BLK2 04/10/98 1820 LH/SK 04/15/98 0630 LH/SK
37759LCSLOW 04/10/98 1820 LH/SK 04/15/98 0630 LH/SK
37759LCSDLOW 04/10/98 1820 LH/SK 04/15/98 0630 LH/SK
93865-1 04/10/98 1820 LH/SK 04/15/98 0630 LH/SK
93865-lDUP 04/10/98 1820 LH/SK 04/15/98 0630 LH/SK
93898 04/10/98 1820 LH/SK 04/15/98 0630 LH/SK
93818-1 04/10/98 1820 LH/SK 04/15/98 0630 LH/SK
93822 04/10/98 1820 LH/SK 04/15/98 0630 LH/SK
93820-1 04/10/98 1820 LH/SK 04/15/98 0630 LH/SK
93874-1 04/10/98 1820 LH/SK 04/15/98 0630 LH/SK
93823-1 04/10/98 1820 LH/SK 04/15/98 0630 LH/SK
93844-1 04/10/98 1820 LH/SK 04/15/98 0630 LH/SK
93873-1 04/10/98 1820 LH/SK 04/15/98 0630 LH/SK
93850-1 04/10/98 1820 LH/SK 04/15/98 0630 LH/SK
93846 04/10/98 1820 LH/SK 04/15/98 0630 LH/SK
93843 04/10/98 1820 LH/SK 04/15/98 0630 LH/SK
93845 04/10/98 1820 LH/SK 04/15/98 0630 LH/SK
93868-1 04/10/98 1820 LH/SK 04/15/98 0630 LH/SK
93868-2 04/10/98 1820 LH/SK 04/15/98 0630 LH/SK
93827-1 04/10/98 1820 LH/SK 04/15/98 0630 LH/SK
93827-2 04/10/98 1820 LH/SK 04/15/98 0630 LH/SK
93827-1 04/10/98 1820 LH/SK CBOD 04/15/98 0630 LH/SK
93827-2 04/10/98 1820 LH/SK CBOD 04/15/98 0630 LH/SK
93829-3 04/10/98 1820 LH/SK 04/15/98 0630 LH/SK
93829-3 04/10/98 1820 LH/SK CBOD 04/15/98 0630 LH/SK
CBODLCS 04/10/98 1820 LH/SK 04/15/98 0630 LH/SK
' • •
Page 29
Q.C. Information for Batch# 37759 For Report Number :93874
Sample Batch Information
Analysis : BOD<5 hi, BOD<5 low
Preparation Preparation Analysis
Sample ID Tag Date Time By Notes Date Time By Inst
CBODLCSD 04/10/98 1820 LH/SK 04/15/98 0630 LH/SK
37759BLK3 04/10/98 1820 LH/SK 04/15/98 0630 LH/SK
93829-1 04/10/98 1820 LH/SK 04/15/98 0630 LH/SK
93829-2 04/10/98 1820 LH/SK 04/15/98 0630 LH/SK
93829-1 04/10/98 1820 LH/SK CBOD 04/15/98 0630 LH/SK
93829-2 04/10/98 1820 LH/SK CBOD 04/15/98 0630 LH/SK
93841 04/10/98 1820 LH/SK 04/15/98 0630 LH/SK
93836 04/10/98 1820 LH/SK 04/15/98 0630 LH/SK
93839 04/10/98 1820 LH/SK 04/15/98 0630 LH/SK
93851 04/10/98 1820 LH/SK 04/15/98 0630 LH/SK
93857AT1 04/10/98 1820 LH/SK 04/15/98 0630 LH/SK
93854 04/10/98 1820 LH/SK 04/15/98 0630 LH/SK
93787-1 04/10/98 1820 LH/SK 04/15/98 0630 LH/SK
93787-2 04/10/98 1820 LH/SK 04/15/98 0630 LH/SK
93787-3 04/10/98 1820 LH/SK 04/15/98 0630 LH/SK
93787-4 04/10/98 1820 LH/SK 04/15/98 0630 LH/SK
93787-5 04/10/98 1820 LH/SK 04/15/98 0630 LH/SK
93787-6 04/10/98 1820 LH/SK 04/15/98 0630 LH/SK
93787-7 04/10/98 1820 LH/SK 04/15/98 0630 LH/SK
93787-8 04/10/98 1820 LH/SK 04/15/98 0630 LH/SK
93787-9 04/10/98 1820 LH/SK 04/15/98 0630 LH/SK
93787-10 04/10/98 1820 LH/SK 04/15/98 0630 LH/SK
• •
Page 30
Q.C. Information for Batch# 37817 For Report Number :93874
Sample Batch Information
Analysis : N
Preparation Preparation Analysis
Sample ID. Tag Date Time By Notes Date Time By Inst
37817BLK 04/13/98 0730 BG 04/13/98 1530 BG GENES
37817LCS 04/13/98 0730 BG 04/13/98 1530 BG GENES
37817LCSD 04/13/98 0730 BG 04/13/98 1530 BG GENES
37817CAL 04/13/98 0730 BG 04/13/98 1530 BG GENES
93874-lMS 04/13/98 0730 BG 04/13/98 1530 BG GENES
93874-lMSD 04/13/98 0730 BG 04/13/98 1530 BG GENES
93874-1 04/13/98 0730 BG 04/13/98 1530 BG GENES
93874-lDUP 04/13/98 0730 BG 04/13/98 1530 BG GENES
93702-2 04/13/98 0730 BG 04/13/98 1530 BG GENES
93702-2DUP 04/13/98 0730 BG 04/13/98 1530 BG GENES
93865-1 04/13/98 0730 BG 04/13/98 1530 BG GENES
93843 04/13/98 0730 BG 04/13/98 1530 BG GENES
93709 04/13/98 0730 BG 04/13/98 1530 BG GENES
93764 04/13/98 0730 BG 04/13/98 1530 BG GENES
·93857AT1 04/13/98 0730 BG 04/13/98 1530 BG GENES
93833 04 /13 /98 0730 BG 04/13/98 1530 BG GENES
93711-1 04/13/98 0730 BG 04/13/98 1530 BG GENES
93844-1 04/13/98 0730 BG 04/13/98 1530 BG GENES
93777 04/13/98 0730 BG 04/13/98 1530 BG GENES
93823-1 04/13/98 0730 BG 04/13/98 1530 BG GENES
93714 04/13/98 0730 BG 04/13/98 1530 BG GENES
93829-3 04/13/98 0730 BG 04/13/98 1530 BG GENES
93625 04/13/98 0730 BG 04/13/98 1530 BG GENES
93827-2 04/13/98 0730 BG 04/13/98 1530 BG GENES
93827-1 04/13/98 0730 BG 04/13/98 1530 BG GENES
93750 04/13/98 0730 BG 04/13/98 1530 BG GENES
93829-2 04/13/98 0730 BG 04/13/98 1530 BG GENES
93829-1 04/13/98 0730 BG 04/13/98 1530 BG GENES
' ' ' . • •
Q.C. Information for Batch# 37864
Page 31
For Report Number :93874
,ample ID Tag
l7864CALCHK
l7864LCS
l7864LCSD
33909
33909DUP
33874-2
Sample Batch Information
Analysis : pH
Preparation Preparation
na·te Time By Notes
I 7
I I
I I
I I
I I
I I
Analysis
Date Time By
04/13/98 1730 JN
04/13/98 1730 JN
04/13/98 1730 JN
04/13/98 1730 JN
04/13/98 1730 JN
04/13/98 1730 JN
Inst
410A
410A
410A
410A
410A
410A
Sample ID
37884BLK
37884LCS
37884LCSD
938l8-2
93820-2
93823-2
93848-2
93848-3
93849
93874-2
93874-2MS
• •
Q.C. Information for Batch# 37884
Page 33
For Report Number :93874
Tag
Sample Batch Information
Analysis : O/G
Preparation Preparation
Date Time By Notes
7 7
I I
I I
I I
I I
I I
I I
I I
I I
I I
I I
Analysis
Date Time By
04/l4/98 0830 BG/CL
04/l4/98 0830 BG/CL
04/l4/98 0830 BG/CL
04/l4/98 0830 BG/CL
04/l4/98 0830 BG/CL
04/l4/98 0830 BG/CL
04/l4/98 0830 BG/CL
04/l4/98 0830 BG/CL
04/l4/98 0830 BG/CL
04/l4/98 0830 BG/CL
04/l4/98 0830 BG/CL
Inst
. ' \ . • •
Page 34
Q.C. Information for Batch# 37923 For Report Number :93874
Sample Batch Information
Analysis : TSS
Preparat.ion Preparation Analysis
Sample ID Tag Date Time By Notes Date Time By Inst.
37923BLK I I 04/15/98 0800 ADM
37923LCS I I 04/15/98 0800 ADM
37923LCSD I I 04/15/98 0800 ADM
93874-lMS I I 04/15/98 0800 ADM
93874-lMSD I I 04/15/98 0800 ADM
93854DUP I I 04/15/98 0800 ADM
93907-2DUP I I 04/15/98 0800 ADM
93868-1 I I 04/15/98 0800 ADM
93868-2 I I 04/15/98 0800 ADM
93874-1 I I 04/15/98 0800 ADM
93865-1 I I 04/15/98 0800 ADM
93829-1 I I 04/15/98 0800 ADM
93829-2 I I 04/15/98 0800 ADM
93829-3 I I 04/15/98 0800 ADM
93836 I I 04/15/98 0800 ADM
93839 I I 04/15/98 0800 ADM
93841 I I 04/15/98 0800 ADM
93851 I I 04/15/98 0800 ADM
93854 I I 04/15/98 0800 ADM
93907-1 I I 04/15/98 0800 ADM
93907-2 I I 04/15/98 0800 ADM
93864-1 I I 04/15/98 0800 ADM
V lJ .:> I 1 '-<
CRA SHIPPED TO (Laboratory Name): A"'-c,\'{ ,kc:,\ .5-e'-V\t-'<~ ~-
CONESTOGA-ROVERS & ASSOCIATES, INC. I Io \ ec\,""-cla 5 ":> \[)o•); . ..,,_, °'--;;>, \"l_c,vCvc,s:;, C..r,, 3c:o"I?....
1351 Oakbrook Drive · Suite 150 REFERENCE NUMBER: PROJECT NAME: Norcross, GA 30093 404-441-0027 '.3669 'J° ~c.~ \t0 s \.,.e.s., CHAIN OF CUSTODY RECORD
SAMPLER'S II///Ut1~ ~ M•:·~H.ii:V PRINTEO\f\ \_ t t,l C: u. w O:!, REMARKS SIGNATURE: NAME: __ '.),c. -n_e • vc? 0 i!
SEQ. /foe SAMPLE zz ~c:i <: {J ()~ .... ~ ~~ ~ Q':-TIME SAMPLE NUMBER 0
NO. TYPE " co .Q. 'C' ' f-:.
j Nlloa!ctB /'-/m LV · "'¼6 'i-\"'If' · , !'I -09 ~ 1k '-/-',( >( 'I, ( O""'-n05,k ,,-.1-~ .
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TOTAL NUMBER OF CONTAINERS
RELIN~ BY:~,zµ( ~ DATE: OJ/I Oll/9 0 RECEIVED BY: KI/J CZ)( DATE: OJ/ O f3 /Cf'{:}
© ',,(,£/, U' TIME: If <n @ TIME: 76~0
RELM'lOUISHED BY: ,. DATE: RECEIVED BY: DATE:
@ TIME: @ TIME:
RELINQUISHED BY: DATE: RECEIVED BY: DATE:
@ TIME: © TIME:
METHOD OF SHIPMENT: F<O E.?C ' AIR BILL NUMBER: go\ 033 79 /J '-/ o
White . Fully Executed Copy SAMPLE TEAl RECEIVED FOR LABO' fedEx[ --
Yellow . Receiving Laboratory Copy lY\, e,¼.v I'\. c✓,J7 . ® 999/ 896 □ /ss3]J N~ 0632 1
Pink . Sampler Copy la q I <l'l '""'"" "'""'"''"" ~ Goldenrod . Chemist Copy , lnATE: TIME: ; LtUPPIJAPl.fTAB •
,,/Z ///,,l:) ~
',,. _/ ', '<;ry, . "JI.. ,>~() \ o!./:{ /t1t,f 1M7t!=nm.A~\ -nFr. fi. 93 -REV.O -(AF-01) 1 (, re .
...
CRA
1351 Oakbrook Drive
Suite #150
Norcross, Georgia 30093
[phone]
•
TO: Jeanne Chew
FROM: Robert Brachowski/rb/28
•
MEMO
REFERENCE NO: 3669
DATE: March 3, 1998
RE: Data Quality Assessment and Validation for Three Water Samples Collected
from the Jadco-Hughes Site in Belmont, North Carolina
(Lot #91476)
The following details a data quality assessment and validation for results generated by
Analytical Services, Inc. (ASI) of Norcross, Georgia for three water samples collected
from the above-referenced Site. Sample collection was conducted on February 3, 1998.
The samples were selectively analyzed for volatile organic compounds (VOCs), base-
neutral and acid extractable organic compounds (BNA), polychlorinated biphenyls
(PCBs), cyanide, oil and grease (O&G), pH, target analyte list (TAL) metals, total
suspended solids (TSS), biological oxygen demand (BOD), and ammonia. The quality
assurance criteria were established by the associated quality assurance project plan and
the analytical methods1. The samples are identified in Table 1. The analytical
methodologies are listed in Table 2.
Holding Time Periods
The holding time periods are presented in Table 3. On the basis of the sample collection
and analysis dates referenced on the chain-of-custody forms and the analytical reports
provided by ASI, the extractions and analyses were performed within the required
holding time periods.
Method Blank Samples
Contamination of samples contributed by laboratory conditions or procedures was
monitored by the concurrent preparation and analysis of method blank samples. The
method blank samples were free from target analytes above the detection limits
indicating that no significant laboratory contamination occurred.
1 Application of quality assurance criteria was consistent with "National Functional Guidelines for
Organic Data Review," revised February 1994 and "National Functional Guidelines for Inorganic Data
Review," revised February 1994.
I ' • •
March 3, 1998 Reference No. 3669
- 2 -
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD) Results
ASI provides and analyzes LCS/LCSD in order to further assess the method accuracy
and precision. The LCS/LCSD relative percent difference (RPO) data for lead were
outside the control limits; therefore, the quantitation limit for sample W-3669-MC-
020398-089 should be qualified as estimated (UJ) for this analyte. The LCS/LCSD RPO
data for Oil and Grease were outside the control limits; therefore, the quantitation limit
for sample W-3669-MC-020398-090 should be qualified as estimated (UJ) for this
parameter. The remainder of the LCS/LCSD data were within the control limits
indicating the method achieved an adequate level of accuracy and precision.
Surrogate Compound Percent Recoveries (Surrogate Recoveries)
Individual sample performance for the VOC, BNA, and PCB parameters were
monitored by surrogate recoveries. The surrogate recoveries were within the control
limits for the reported analyses.
Matrix Spike/Matrix Spike Duplicate (MS/MSD) Percent Recoveries
To assess the long term accuracy and precision of the analytical method on various
matrices, MS/MSD percent recoveries and the RPO of the recoveries are determined.
The outlying MS/MSD percent recovery and RPO data as well as required sample
qualifications are provided in Table 4. The remainder of the MS/MSD percent recovery
and RPO data were within the control limits indicating an adequate level of accuracy
and precision was achieved.
Laboratory Duplicate Analyses
To monitor the precision of the laboratory analytical methods, laboratory duplicate
samples were analyzed for select methods. The laboratory duplicate RPO data were
within the control limits indicating an adequate level of precision was achieved for
these select methods.
• •
March 3, 1998 Reference No. 3669
-3-
Trip Blank Analysis
Potential VOC cross-contamination by diffusion of target compounds through the
septum seal of the sample vial into the investigative samples during shipment and
storage was monitored by means of a trip blank sample. The trip blank sample was free
from detectable concentrations of target analytes indicating that no significant cross-
contamination occurred.
Overall Assessment
Violation of LCS/LSCD and MS/MSD criteria resulted in sample qualification as noted
in the previous text and following tables. The remainder of the data were found to
exhibit acceptable levels of accuracy and precision and may used without qualification.
• •
TABLEl
SUMMARY OF THE SAMPLE IDENTIFICATION NUMBERS
ASSOCIATED WITH THE SAMPLES COLLECTED FROM THE
JADCO-HUGHES SITE IN
3669-M-ZS. Tl
BELMONT, NORTH CAROLINA
W-3669-MC-020398-088
W-3669-MC-020398-089
W-3669-MC-020398-090
• •
TABLE2
ANALYTICAL METHODS ASSOCIATED WITH THE
SAMPLES COLLECTED FROM THE JADCO-HUGHES SITE IN
BELMONT, NORTH CAROLINA
Parameters Methods
voe EPA I 624
BNA EPA 625
PCB EPA 608
Cyanide EPA 335.2
Oil and Grease EPA 1664
pH EPA 150.1
TALMetals EPA 200 (series)
TSS EPA 160.2
BOD EPA 405.1
Ammonia EPA 350.2
1 "Methods for Chemical Analysis of Water and Wastes," EPA 600/4-79-020, revised March 1983.
• • •
TABLE3
HOLDING TIME PERIODS ASSOCIATED WITH THE SAMPLES
COLLECTED FROM THE JADCO-HUGHES SITE IN
BELMONT, NORTH CAROLINA
Parameters
VOC, Cyanide
BNA,PCB
pH
TAL Metals
(excluding mercury)
Holding Time Periods
-14 days from sample collection to completion of analysis
- 7 days from sample collection to extraction
-40 days from extraction to completion of analysis
-Analyze as soon as possible
- 6 months from sample collection to completion of analysis
Mercury, Oil and Grease, -28 days from sample collection to completion of analysis
Ammonia
BOD -48 hours from sample collection to beginning of analysis
TSS - 7 days from sample collection to completion of analysis
3669-M-28-T3
• .• • • TABLE4
OUTLYING MS/MSD PERCENT RECOVERY AND RPO DATA
ASSOCIATED WITH THE SAMPLES COLLECTED FROM THE
JADCO-HUGHES SITE IN BELMONT, NORTH CAROLINA
Parameter Compound
voe Chloroethane
Chloroethane
2-Chloroethylvinyl ether
Trichlorofluoromethane
BNA 4-Chloro-3-methylphenol
2, 4-Dimethylphenol
2, 4-Dinitrophenol
TALMetals Lead
Thallium
Silver
Sodium
Vanadium
Notes:
(1) MS/MSD -Matrix Spike/Matrix Spike Duplicate
(2) RPO -Relative percent difference
MS/MSD fl/
Percent
Recoveries
NA<•>
NA
NA
NA
17,20
0, 0
0, 0
170, 170
146,146
140, 135
140,140
190, 190
(3) The associated samples should be qualified as follows:
RPD
Control Control
Limits RPD r,i Limits
NA 24 [20]
NA 24 [20]
NA 22 [20]
NA 21 [20]
[23-97] NA NA
[32-119] NA NA
[10-191] NA NA
[76-124] NA NA
[76-124] NA NA
[76-124] NA NA
[76-124] NA NA
(76-124] NA NA
J -Positive results for the associated compound should be qualified as an estimated quantity.
UJ -The quantit.ation limit for the associated compound should be qualified as an estimated value.
(4) NA-Not applicable
(5) NR -No sample qualification required.
CRA 3669-M-28-T4
Associated
Samples r,,
W-3669-MC-020398-088
W-3669-MC-020398-090
NR<5>
NR
W-3669-MC-020398-090
W-3669-M C-020398-090
W-3669-MC-020398-090
W-3669-MC-020398-089
W-3669-MC-020398-089
W-3669-MC-020398-089
W-3669-MC-020398-089
W-3669-MC-020398-089
ASI • ANALYTICAL • SERVICES,
ENVIRONMENTAL MONITORING & LABORATORY ANALYSIS
110 TECHNOLOGY PARKWAY• NORCROSS, GA 30092
[phone] • FAX [phone]
TRANSMITTAL LETTER
A/sf>
I N C .
To: Mr. Rob Brachowski
Company: Conestoga-Rovers
1351 Oakbrook Drive
Suite 150
Norcross,GA 30093
Date: 2/20/98
Report No. 91476
Site: Jadco-Hughes
Please find enclosed analytical results for samples received on 2/4/98.
These analyses were performed in accordance with approved state and
federal procedures and all applicable QC criteria were met.
We appreciate the opportunity to provide analytical support for your
project. If you have any questions regarding this data package, please
do not hesitate to call.
Respectfully submitted,
Project Managef
D:a.i2 ___ 5_/ 2:-_{1.f_ ___ _
::-.:i'i:i'.--~---·
A Unit of American Analytical Services, Inc.
ASI • ANALYTICAL • SERVICES,
ENVIRONMENTAL MONITORING & LABORATORY ANALYSIS
110 TECHNOLOGY PARKWAY• NORCROSS, GA 30092
[phone] • FAX [phone]
20 February, 1998
Case Narrative Report 91476
I N C .
The samples were collected on 3 February, 1998 and received by AS! 4 February,
1998. Conditions for proper sample receipt were met as indicated on the Chain of
Custody. The samples were logged into LIMS as report 91476 for the following analyses
as per client request: BOD (EPA 405.1), NH3 (EPA 350.2), TSS (EPA 160.2), Metals
(EPA 200.7, 239.2, 270.2, 279.2, 245.1), pH (EPA ISO.I), CN (EPA 335.2), O&G (EPA
1664), BNA (EPA 625), PCB (EPA 608), and VOA (EPA 624). All holding times for
sample preparation and analysis were met with the exception of pH which is best
analyzed in the field.
BOD analysis (EPA 405.1) met all data quality objectives.
NH3 analysis (EPA 350.2) met all data quality objectives.
TSS analysis (EPA 160.2) met all data quality objectives.
Metals analysis (EPA 200.7) gave high MS/MSD/PDS for Ag and Na, high
MS/MSD for V, high PDS for K, and low PDS for Ca, Cr, Mg, and Fe. Pb analysis (EPA
239.2) gave high MS/MSD. Se analysis (EPA 270.2) gave low MS/MSD and high PDS.
Tl analysis (EPA 279.2) gave high MS/MSD. All other quality controls were acceptable.
-Hg analysis (EPA 245.1) met all data quality objectives.
pH analysis (EPA 150.1) met all data quality objectives.
CN analysis (EPA 335.2) met all data quality objectives.
O&G analysis (EPA 1664) had insufficient sample for MSD and high LCSRPD.
The batch passes on individual lab control recoveries and the MS.
BNA analysis (EPA 625) gave low MS/MSD for 4-Chloro-3-methylphenol, 2,4-
Dimethylphenol, and 2,4-Dintrophenol due to matrix. All other spikes and surrogates
were acceptable.
PCB analysis (EPA 608) met all data quality objectives.
VOA analysis (EPA 624) gave high MSRPD for Chloroethane, 2-
Chloroethylvinyl ether, and Trichlorofluoromethane but individual MS/MSD recoveries
were acceptable. 4-Bromofluorobenzene was slightly low for the MSD but was
acceptable in the MS and original sample. All other spikes and surrogates were
acceptable.
Adrea N. Tuck
Assistant QA Manager
A Unit of American Analytical Services, Inc.
• ANALYTICAL • SERVICES, I N C . ASI ENVIRONMENTAL MONITORING & LABORATORY ANALYSIS
110 TECHNOLOGY PARKWAY• NORCROSS, GA 30092
[phone] • FAX [phone]
Conestoga-Rovers
1351 Oakbrook Drive
Suite 150
Norcross, GA 30093
LABORATORY REPORT
Attention: Mr. Rob Brachowski
Sample Description
February 20, 1998
Report No. 91476-1
Wastewater, composite, Jadco-Hughes, Project #3669, W-3669-MC-020398-089,
02/03/98, 11:30, received 02/04/98
RESULTS
Biochemical Oxygen Demand (BOD5 ) (mg/1)
(EPA 405.1) ............................ .
Ammonia Nitrogen (N) (mg/1) (EPA 350.2) ....... .
Total Suspended Solids (mg/1) (EPA 160. 2) .... .
Target Analyte List -Metals
Metals
Total Aluminum (Al) (EPA 200. 7) .............. .
Total Antimony (Sb) (EPA 200. 7) .............. .
Total Arsenic (As) (EPA 200. 7) ............... .
Total Barium (Ba) (EPA 200. 7) ............... ..
Total Beryllium (Be) (EPA 200. 7) ............. .
Total Cadmium (Cd) (EPA 200. 7) ............... .
Total Calcium (Ca) (EPA 200.7) ............... .
Total Chromium (Cr) (EPA 200. 7) .............. .
Total Cobalt (Co) (EPA 200. 7) ................ .
Total Copper (Cu) (EPA 200. 7) ................ .
Total Iron (Fe) (EPA 200. 7) .................. .
Total Lead (Pb) (EPA 239.2) .................. .
BDL -Below Detection Limit
Result
BDL
BDL
BDL
(mg/1)
BDL
BDL
BDL
0.06
BDL
BDL
37
0.02
BDL
BDL
0.31
BDL
A Unit of American Analytical Services, Inc.
Detection
Limit
5
0.1
5
(mg/1)
0.2
0.05
0.01
0.01
0.001
0.005
0.05
0.01
0.05
0.02
0.1
0.003
Conestoga-Rovers
Page 2 of 2
• •
February 20, 1998
Report No. 91476-1
Wastewater, composite, Jadco-Hughes, Project #3669, W-3669-MC-020398-089,
02/03/98, 11:30, received 02/04/98
RESULTS
Metals
Total Magnesium (Mg) (EPA 200.7) ............. .
Total Manganese (Mn) (EPA 200. 7) ............. .
Total Mercury (Hg) (EPA 245. 1) ............... .
Total Nickel (Ni) (EPA 200. 7) ................ .
Total Potassium (K) (EPA 200. 7) .............. .
Total Selenium (Se) (EPA 270.2) .............. .
Total Silver (Ag) (EPA 200. 7) ................ .
Total Sodium (Na) (EPA 200. 7) ................ .
Total Thallium (Tl) (EPA 279.2) .............. .
Total Zinc (Zn) (EPA 200. 7) .................. .
Total Vanadium (V) (EPA 200. 7) ............... .
BDL -Below Detection Limit
North Carolina Laboratory I.D. No. 381
Result
(mg/1)
9.7
0.06
BDL
BDL
2.8
BDL
BDL
7.2
BDL
0.03
BDL
Detection
Limit
(mg/1)
0.05
0.015
0.0002
0.02
0.2
0.005
0.01
0.05
0.002
0.02
0.02
Respectfully submitted, ¼ µ/ 1£/U{
Project Manflger
0~1rrr-e1=-
Quality Assurance
•
ASI • ANALYTICAL • SERVICES,
ENVIRONMENTAL MONITORING & LABORATORY ANALYSIS
110 TECHNOLOGY PARKWAY • NORCROSS, GA 30092
[phone] • FAX [phone]
LABORATORY REPORT
I N C .
Conestoga-Rovers
1351 Oakbrook Drive
Suite 150
February 20, 1998
Norcross, GA 30093
Attention: Mr. Rob Brachowski Report No. 91476-2
Sample Description
Wastewater, grab, Jadco-Hughes, Project #3669, W-3669-MC-020398-088,
02/03/98, 11:30, received 02/04/98
RESULTS
Detection
Result Limit
Volatile Organics (EPA 624) (ug/1) (ug/1)
Acetone ..................................... . BDL 100
Benzene ..................................... . BDL 2
Bromodichloromethane ........................ . BDL 10
Bromoform ................................... . BDL 10
Bromomethane ................................ . BDL 10
2-Butanone .................................. . BDL 100
Carbon disulfide ............................ . BDL 5
Carbon tetrachloride ........................ . BDL 2
Chlorobenzene ............................... . BDL 10
Chloroethane ................................ . BDL 5
Chloroform .................................. . 110 2
Chloromethane ............................... . BDL 10
Dibromochloromethane ........................ . BDL 10
1, 1-Dichloroethane .......................... . BDL 2
1, 2 -Dichloroethane .......................... . 49 2
l, 1-Dichloroethene .......................... . BDL 2
1, 2-Dichloroethene (total) .................. . 100 2
1, 2 -Dichloropropane ......................... . BDL 2
cis-1, 3-Dichloropropene ..................... . BDL 2
trans-1,3-Dichloropropene ................... . BDL 2
Ethylbenzene ................................ . BDL 2
2-Hexanone .................................. . BDL 50
BDL -Below Detection Limit
A Unit of American Analytical Services, Inc.
Conestoga-Rovers
Page 2 of 2
• •
February 20, 1998
Report No. 91476-2
Wastewater, grab, Jadco-Hughes, Project #3669, W-3669-MC-020398-088,
02/03/98, 11:30, received 02/04/98
RESULTS
Detection
Result Limit
Volatile Organics (EPA 624) (ug/1) (ug/1)
Methylene chloride .......................... . BDL 10
1,1,2,2-Tetrachloroethane ................... . BDL 2
Tetrachloroethene ........................... . 9 2
Toluene ..................................... . 3 2
1, 1, 1-Trichloroethane ....................... . BDL 2
1, 1, 2-Trichloroethane ....................... . BDL 2
Trichloroethene ............................. . 64 2
Vinyl chloride .............................. . BDL 10
Xylenes ..................................... . 4 2
BDL -Below Detection Limit
North Carolina Laboratory I.D. No. 381
Respectfully submitted,
Y/4a«·x¼
ProjectM~
GctAAQur~ Quality'Assurance
ASI • ANALYTICAL • SERVICES,
ENVIRONMENTAL MONITORING & LABORATORY ANALYSIS
110 TECHNOLOGY PARKWAY• NORCROSS, GA 30092
[phone] • FAX [phone]
LABORATORY REPORT
I N C .
Conestoga-Rovers
1351 Oakbrook Drive
Suite 150
February 20, 1998
Norcross, GA 30093
Attention: Mr. Rob Brachowski Report No. 91476-3
Sample Description
Wastewater, grab, Jadco-Hughes, Project #3669, W-3669-MC-020398-090,
02/03/98, 11:30, received 02/04/98
RESULTS
Detection
Result Limit
pH (laboratory) (EPA 150.1) .................. . 7.85
Total Cyanide (CN) (mg/1) (EPA 335.2) ......... . BDL 0.01
Oil and Grease (mg/1) (EPA 1664) ............. . BDL 6
Volatile Organics (EPA 624) (ug/1) (ug/1)
Acetone ..................................... . BDL 100
Benzene ..................................... . BDL 2
Bromodichloromethane ........................ . BDL 10
Bromoform ................................... . BDL 10
Bromomethane ................................ . BDL 10
2 -Bu tanone .................................. . BDL 100
Carbon disulfide ............................ . BDL 5
Carbon tetrachloride ........................ . BDL 2
Chlorobenzene ............................... . BDL 10
Chloroethane ................................ . BDL 5
Chloroform .................................. . 100 2
Chloromethane ............................... . BDL 10
Dibromochloromethane ........................ . BDL 10
1, 1-Dichloroethane .......................... . BDL 2
1, 2 -Dichloroethane .......................... . 18 2
1, 1-Dichloroethene .......................... . BDL 2
1,2-Dichloroethene (total) .................. . 50 2
BDL -Below Detection Limit
A Unit of American Analytical Services, Inc.
Conestoga-Rovers
Page 2 of 4
• •
February 20, 1998
Report No. 91476-3
Wastewater, grab, Jadco-Hughes, Project #3669, W-3669-MC-020398-090,
02/03/98, 11:30, received 02/04/98
RESULTS
Detection
Result Limit
Volatile Organics (EPA 624) (ug/1) (ug/1)
1, 2 -Dichloropropane ......................... . BDL 2
cis-1,3-Dichloropropene ..................... . BDL 2
trans-1,3-Dichloropropene ................... . BDL 2
Ethylbenzene ................................ . BDL 2
2 -Hexanone .................................. . BDL 50
Methylene chloride .......................... . BDL 10
1,1,2,2-Tetrachloroethane ................... . BDL 2
Tetrachloroethene ........................... . 3 2
Toluene ..................................... . BDL 2
1,1,1-Trichloroethane ....................... . BDL 2
1,1,2-Trichloroethane ....................... . BDL 2
Trichloroethene ............................. . 24 2
Vinyl chloride .............................. . BDL 10
Xylenes ..................................... . BDL 2
Acid Extractable Organics (EPA 625) (ug/1) (ug/1)
Benzoic Acid ................................ . BDL 50
4-Chloro-3-methylphenol ..................... . BDL 10
2-Chlorophenol .............................. . BDL 10
2,4-Dichlorophenol .......................... . BDL 10
2, 4 -Dimethylphenol .......................... . BDL 10
2, 4-Dinitrophenol. .......................... . BDL 50
4,6-Dinitro-2-methylphenol .................. . BDL 50
2-Methylphenol .............................. . BDL 10
4-Methylphenol .............................. . BDL 10
2-Nitrophenol ............................... . BDL 50
4-Nitrophenol ............................... . BDL 50
Pentachlorophenol ........................... . BDL 20
Phenol ...................................... . BDL 10
2, 4, 6-Trichlorophenol. ...................... . BDL 10
2, 4, 5-Trichlorophenol ....................... . BDL 10
BDL -Below Detection Limit
Conestoga-Rovers
Page 3 of 4
• •
February 20, 1998
Report No. 91476-3
Wastewater, grab, Jadco-Hughes, Project #3669, W-3669-MC-020398-090,
02/03/98, 11:30, received 02/04/98
RESULTS
Detection
Result Limit
Base/Neutral Extractable Organics (EPA 625) (ug/1) (ug/1)
Acenaphthene ................................ . BDL 10
Acenaphthylene .............................. . BDL 10
Anthracene .................................. . BDL 10
Benzo (a) anthracene .......................... . BDL 10
Benzo(b)fluoranthene ........................ . BDL 10
Benzo (k) fluoranthene ........................ . BDL 10
Benzo (a) pyrene .............................. . BDL 10
Benzo (ghi) perylene .......................... . BDL 10
Benzyl butyl phthalate ...................... . BDL 10
Bis ( 2-chloroethyl) ether ..................... . BDL 10
Bis(2-chloroethoxy)methane .................. . BDL 10
Bis(2-ethylhexyl)phthalate .................. . BDL 10
Bis(2-chloroisopropyl)ether ................. . BDL 10
4-Bromophenyl phenyl ether .................. . BDL 10
4-Chloroaniline ............................. . BDL 20
2 -Chloronaphthalene ......................... . BDL 10
4-Chlorophenyl phenyl ether ................. . BDL 10
Chrysene .................................... . BDL 10
Dibenzo(a,h)anthracene ...................... . BDL 10
Dibenzofuran ................................ . BDL 10
Di-n-butylphthalate ......................... . BDL 10
1, 3 -Dichlorobenzene ......................... . BDL 10
1, 2 -Dichlorobenzene ......................... . BDL 10
1, 4-Dichlorobenzene ......................... . BDL 10
3, 3' -Dichlorobenzidine ...................... . BDL 20
Diethylphthalate ............................ . BDL 10
Dimethylphthalate ........................... . BDL 10
2, 4 -Dini trotol uene .......................... . BDL 20
2, 6 -Dini trotoluene .......................... . BDL 20
Di-n-octylphthalate ......................... . BDL 10
Fluoranthene ................................ . BDL 10
Fluorene .................................... . BDL 10
Hexachlorobenzene ........................... . BDL 10
Hexachlorobutadiene ......................... . BDL 10
Hexachlorocyclopentadiene ................... . BDL 10
Hexachloroethane ............................ . BDL 2
Indeno ( 1, 2, 3 -cd) pyrene ...................... . BDL 10
I sophorone .................................. . BDL 10
BDL -Below Detection Limit
Conestoga-Rovers
Page 4 of 4
• •
February 20, 1998
Report No. 91476-3
Wastewater, grab, Jadco-Hughes, Project #3669, W-3669-MC-020398-090,
02/03/98, 11:30, received 02/04/98
RESULTS
Detection
Result Limit
Base/Neutral Extractable Organics (EPA 625) (ug/1) (ug/1)
2 -Methylnaphthalene ......................... . BDL 10
Naphthalene ................................. . BDL 10
2-Nitroaniline .............................. . BDL so
3-Nitroaniline .............................. . BDL so
4-Nitroaniline ........................ • ...... . BDL so
Ni trobenzene ................................ . BDL 10
N-Nitrosodiphenylamine ...................... . BDL 10
N-Nitrosodi-n-propylamine ................... . BDL 10
Phenanthrene ................................ . BDL 10
Pyrene ...................................... . BDL 10
1, 2, 4 -Trichlorobenzene ...................... . BDL 10
PCB's (EPA 608) (ug/1) (ug/1)
PCB 1016 .................................... . BDL 1. 0
PCB 1221 .................................... . BDL 1.0
PCB 1232 .................................... . BDL 1.0
PCB 1242 .................................... . BDL 1. 0
PCB 1248 .................................... . BDL 1.0
PCB 1254 .................................... . BDL 1. 0
PCB 1260 .................................... . BDL 1. 0
BDL -Below Detection Limit
North Carolina Laboratory I.D. No. 381
Resp~~~tted,
ProjectMaager
a_~/2lkAL,
Quality Assurance
ASI • ANALYTICAL • SERVICES,
ENVIRONMENTAL MONITORING & LABORATORY ANALYSIS
110 TECHNOLOGY PARKWAY• NORCROSS, GA 30092
(770) 734·4200 • FAX (770) 734·4201
LABORATORY REPORT
I N C .
Conestoga-Rovers
1351 Oakbrook Drive
Suite 150
February 20, 1998
Norcross, GA 30093
Attention: Mr. Rob Brachowski Report No. 91476-4
Sample Description
Water, Jadco-Hughes, Project #3669, Trip Blank, received 02/04/98
RESULTS
Detection
Result Limit
Volatile Organics (EPA 624) (ug/1) (ug/1)
Acetone ..................................... . BDL 100
Benzene ..................................... . BDL 2
Bromodichloromethane ........................ . BDL 10
Bromoform ................................... . BDL 10
Bromomethane ................................ . BDL 10
2 -Butanone .................................. . BDL 100
Carbon disulfide ............................ . BDL 5
Carbon tetrachloride ........................ . BDL 2
Chlorobenzene ............................... . BDL 10
Chloroethane ................................ . BDL 5
Chloroform .................................. . BDL 2
Chloromethane ............................... . BDL 10
Dibromochloromethane ........................ . BDL 10
1, 1-Dichloroethane .......................... . BDL 2
1, 2-Dichloroethane .......................... . BDL 2
1, 1-Dichloroethene .......................... . BDL 2
1,2-Dichloroethene (total) .................. . BDL 2
1,2-Dichloropropane ......................... . BDL 2
cis-1,3-Dichloropropene ..................... . BDL 2
trans-1,3-Dichloropropene ................... . BDL 2
Ethylbenzene ................................ . BDL 2
2-Hexanone .................................. . BDL 50
Methylene chloride .......................... . BDL 10
BDL -Below Detection Limit
A Unit of American Analytical Services, Inc.
Conestoga-Rovers
Page 2 of 2
• •
February 20, 1998
Report No. 91476-4
Water, Jadco-Hughes, Project #3669, Trip Blank, received 02/04/98
RESULTS
Volatile Organics (EPA 624)
1,1,2,2-Tetrachloroethane ................... .
Tetrachloroethene ........................... .
Toluene ..................................... .
1,1,1-Trichloroethane ....................... .
1,1,2-Trichloroethane ....................... .
Trichloroethene ............................. .
Vinyl chloride .............................. .
Xylenes ..................................... .
BDL -Below Detection Limit
North Carolina Laboratory I.D. No. 381
Result
(ug/1)
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
Detection
Limit
(ug/1)
2
2
2
2
2
2
10
2
Respectfully submitted,
Qug,(,/ ilcuJUt
Project Manl,ger
Uet\AJ. 9,,/\T~c___
Quality Assurance
• •
Page 1
Analytical Services Inc. Batch QC
For Report Number :91476
Volatile Organics
Matrix : Aqueous Batch # 35982 Method : EPA 624
Lab Control Information LC LCD LC %Recovery RPD
Analyte %Rec %Rec RPD Range Range
Benzene 114 116 2 37 -151 0 -20
Bromodichloromethane 119 122 3 35 -155 0 -20
Bromoform 124 122 2 45 -169 0 -20
Bromomethane 144 133 8 D -242 0 -20
Carbon tetrachloride 123 125 1 70 -140 0 -20
Chlorobenzene 119 117 2 37 -160 0 -20
Chloroethane 127 130 2 14 -230 0 -20
2-Chloroethylvinyl ether 138 129 7 D -305 0 -20
Chloroform 122 128 5 51 -138 0 -20
Chloromethane 112 97 14 D -273 0 -20
Dibromochloromethane 119 116 2 53 -149 0 -20
1,2-Dichlorobenzene 114 113 0 18 -190 0 -20
1,3-Dichlorobenzene 124 119 4 59 -156 0 -20
1,4-Dichlorobenzene ,112 114 2 18 -190 0 -20
1,1-Dichloroethane 119 127 7 59 -155 0 -,20
1,2-Dichloroethane 121 122 1 49 -155 0 -20
1,1-Dichloroethene 112 114 1 D -234 0 -20
trans-1,2-Dichloroethene 116 122 5 54 -156 0 -20
1,2-Dichloropropane 122 124 2 D -210 0 -20
cis-1,3-Dichloropropene 126 121 4 D -227 0 -20
trans-1,3-Dichloropropene 126 119 5 17 -183 0 -20
Ethylbenzene 122 119 3 37 -162 0 -20
Methylene chloride 116 122 5 D -221 0 -20
1,1,2,2-Tetrachloroethane 118 113 4 46 -157 0 -20
Tetrachloroethene 123 115 7 64 -148 0 -20
Toluene 116 113 2 47 -150 0 -20
1,1,1-Trichloroethane 124 128 3 52 -162 0 -20
1,1,2-Trichloroethane 126 120 5 52 -150 0 -20
Trichloroethene 119 120 1 71 -157 0 -20
Trichlorofluoromethane 127 128 1 17 -181 0 -20
Vinyl chloride 115 117 1 D -251 0 -20
• • Page 2
Analytical Services Inc. Batch QC
Volatile Organics
Matrix : Aqueous Batch # 35982 Method : EPA 624
Matrix Spike Information MS MSD MS %Recovery RPD
Analyte %Rec %Rec RPD Range Range
Benzene 99 117 17 37 -151 0 -20
Bromodichloromethane 94 105 12 35 -155 0 -20
Bromoform 99 87 13 45 -169 0 -20
Bromomethane 121 133 9 D -242 0 -20
Carbon tetrachloride 107 127 17 70 -140 0 -20
Chlorobenzene 100 123 20 37 -160 0 -20
Chloroethane 103 131 24 14 -230 0 -20
2-Chloroethylvinyl ether 4 5 22 D -305 0 -20
Chloroform 107 126 17 51 -138 0 -20
Chloromethane 95 115 19 D -273 0 -20
Dibromochloromethane 91 103 13 53 -149 0 -20
1,2-Dichlorobenzene 99 119 18 18 -190 0 -20
1,3-Dichlorobenzene 95 86 10 59 -156 0 -20
1,4-Dichlorobenzene 101 115 13 18 -190 0 -20
1,1-Dichloroethane 110 128 16 59 -155 0 -20
1,2-Dichloroethane 103 126 20 49 -155 0 -20
1,1-Dichloroethene 107 120 11 D -234 0 -20
trans-1,2-Dichloroethene 107 127 17 54 -156 0 -20
1,2-Dichloropropane 97 102 5 D -210 0 -20
cis-1,3-Dichloropropene 89 103 15 D -227 0 -20
trans-1,3-Dichloropropene 91 107 17 17 -183 0 -20
Ethylbenzene 102 122 18 37 -162 0 -20
Methylene chloride 103 123 18 D -221 0 -20
1,1,2,2-Tetrachloroethane 102 87 16 46 -157 0 -20
Tetrachloroethene 96 107 11 64 -148 0 -20
Toluene 91 101 10 47 -150 0 -20
1,1,1-Trichloroethane 114 120 6 52 -162 0 -20
1,1,2-Trichloroethane 92 106 14 52 -150 0 -20
Trichloroethene 103 117 13 71 -157 0 -20
Trichlorofluoromethane 111 138 21 17 -181 0 -20
Vinyl chloride 105 121 14 D -251 0 -20
• • Page 3
Analytical Services Inc. Batch QC
Surrogate Recovery
Volatile Organics
Matrix Aqueous Batch# 35982 Method EPA 624
% Recovery Objectives
81 l,2-Dichloroethane-d4 76 -119
82 Toluene-dB 88 -110
83 Ethylbenzene-dl0 75 -115
84 4-Bromofluorobenzene 86 -115
Sample File 81 82 83 84 85 86
35982BLK B2744 109 92 91 94
35982LCS A0739 99 104 102 100
35982LCSD A0740 103 102 101 94
91357 B2760 110 104 101 105
9134 7 B2761 118 100 103 106
91290 B2762 114 104 100 109
91131-2 B2763 115 101 101 99
91131-3 B2764 114 99 95 99
91131-4 B2765 114 100 94 97
91131-5 B2766 114 103 96 103
91357D B2767 114 99 95 92
AANote: DF=5
91393-4 B2768 119 101 101 115
91393-4D B2768 106 97 101 105
AANote: DF=l0
91393-4D2 B2793 124 95 107 113
"'"'Note: DF=50
91347MS A0743 103 96 101 90
91347MSD A0744 101 91 103 69
91646-4 Cl353 99 98 96 99
91646-5 Cl354 100 100 96 99
91646-5D Cl328 96 99 98 98
91476-2 Cl348 100 97 93 97
91476-3 Cl349 96 98 94 98
91476-4 Cl350 96 96 90 98
35982BLK2 Cl329 97 98 97 99
91429 Cl334 100 102 100 104
91467-2 Cl335 103 98 91 103
91411-1 B3098 102 100 96 102
91411-2 B3099 95 96 89 98
91487 B3100 100 98 94 99
91450-2 B3106 92 95 95 101
•
Q.C. Information for Batch# 35982
• Page 4
Printed: 02/20/98 10:37:50
Blank Results Information
Volatile Organics Method: EPA 624
Analyte
Acetone
Benzene
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Dibromochloromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethene
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethylbenzene
2-Hexanone
Methylene chloride
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Vinyl chloride
Xylenes
Blank
Result
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
Detection
Limit
100
2
10
10
10
100
5
2
10
5
2
10
10
2
2
2
2
2
2
2
2
50
10
2
2
2
2
2
2
10
2
• • • Page 5
Q.C. Information for Batch# 35982 Printed: 02/20/98 10:37:50
Sample Batch Information
Volatile Organics Method : EPA 624
Preparation Preparation Analysis
Sample ID Date Time By Notes Date Time By Inst #
35982BLK I I 02/02/98 1931 LLP VOA2
35982LCS I I 02/04/98 1015 LLP VOAl
35982LCSD I I 02/04/98 1042 LLP VOAl
91357 I I 02/02/98 0843 LLP VOA2
91347 I I 02/02/98 0909 LLP VOA2
91290 I I 02/02/98 0933 LLP VOA2
91131-2 I I 02/02/98 0957 LLP VOA2
91131-3 I I 02/02/98 1021 LLP VOA2
91131-4 I I 02/02/98 1045 LLP VOA2
91131-5 I I 02/02/98 1108 LLP VOA2
91357D I I 02/02/98 1132 LLP VOA2
91393-4 I I 02/02/98 1156 LLP VOA2
91393-4D I I 02/02/98 1227 LLP VOA2
91393-4D2 I I 02/03/98 2206 RFA VOA2
91347MS I I 02/04/98 1204 LLP VOAl
91347MSD I I 02/04/98 1231 LLP VOAl
91646-4 I I 02/11/98 1044 LLP VOA3
91646-5 I I 02/11/98 110 LLP VOA3
91646-5D I I 02/11/98 1247 LLP VOA3
91476-2 I I 02/11/98 1318 LLP VOA3
91476-3 I I 02/11/98 1344 LLP VOA3
91476-4 I I 02/11/98 1410 LLP VOA3
91429 I I 02/11/98 1603 LLP VOA3
91467-2 I I 02/11/98 1640 LLP VOA3
35982BLK2 I I 02/11/98 1218 LLP VOA3
91411-1 I I 02/12/98 1415 TLW VOA2
91411-2 I I 02/12/98 1439 TLW VOA2
91487 I I 02/12/98 1504 TLW VOA2
91450-2 I I 02/12/98 1 730 TLW VOA2
t • • Page 6
Analytical Services Inc. Batch QC
For Report Number :91476
Acids
Matrix : Aqueous Batch # 36057 Method : EPA 625
Lab Control Information LC LCD LC %-Recovery RPD
Analyte %Rec %Rec RPD Range Range
4-Chloro-3-methylphenol 91 88 4 23 -97 0 -42
2-Chlorophenol 72 68 6 27 -123 0 -40
2,4-Dichlorophenol 80 75 7 39 -135 0 -40
2,4-Dimethylphenol 77 78 2 32 -119 0 -40
2,4-Dinitrophenol 24 16 40 10 -191 0 -50
4,6-Dinitro-2-methylphenol 86 46 59 10 -181 0 -93
2-Nitrophenol 76 68 12 19 -182 0 -40
4-Nitrophenol 49 34 36 10 -80 0 -50
Pentachlorophenol 102 73 34 9 -103 0 -50
Phenol 32 30 5 12 -89 0 -42
2,4,6-Trichlorophenol 84 72 16 37 -144 0 -40
Matrix Spike Information MS MSD MS %Recovery RPD
Analyte %Rec %Rec RPD Range Range
4-Chloro-3-methylphenol 17 20 18 23 -97 0 -42
2-Chlorophenol 51 51 1 27 -123 0 -40
2,4-Dichlorophenol 53 53 1 39 -135 0 -40
2,4-Dimethylphenol 0 0 NC 32 -119 0 -40
2,4-Dinitrophenol 0 0 NC 10 -191 0 -50
4,6-Dinitro-2-methylphenol 51 25 69 10 -181 0 -93
2-Nitrophenol 80 72 11 19 -182 0 -40
4-Nitrophenol 81 67 19 10 -80 0 -50
Pentachlorophenol 72 44 49 9 -103 0 -50
Phenol 22 22 3 12 -89 0 -42
2,4,6-Trichlorophenol 78 74 5 37 -144 0 -40
NC = Not Calculated
Matrix
Sample
36057BLK
36057LCS
36057LCSD
91476-3
91476-3MS
91476-JMSD
• •
Analytical Services Inc. Batch QC
Surrogate Recovery
Acids
Aqueous Batch# 36057 Method
% Recovery Objectives
Sl 2-Fluorophenol 21 -
S2 Phenol-d5 10 -
File Sl S2 S3 S4
B3823 44 25
B3824 45 27
B3825 43 25
B3835 42 26
B3873 26 19
B3874 26 18
Page 7
EPA 625
100
94
S5 S6
•
Q.C. Information for Batch# 36057
• Page 8
Printed: 02/20/98 10:37:53
Blank Results Information
Acids Method: EPA 625
Blank Detection
Analyte Result Limit
Benzoic Acid BDL 50
4-Chloro-3-methylphenol BDL 10
2-Chlorophenol BDL 10
2,4-Dichlorophenol BDL 10
2,4-Dimethylphenol BDL 10
2,4-Dinitrophenol BDL 50
4,6-Dinitro-2-methylphenol BDL 50
2-Methylphenol BDL 10
4-Methylphenol BDL 10
2-Nitrophenol BDL 50
4-Nitrophenol BDL 50
Pentachlorophenol BDL 20
Phenol BDL 10
2,4,6-Trichlorophenol BDL 10
2,4,5-Trichlorophenol BDL 10
Sample ID
36057BLK
36057LCS
36057LCSD
91476-3
91476-3MS
91476-3MSD
91941
92010-1
92005
92005DUP
• •
Q.C. Information for Batch# 36057
Page 9
Printed: 02/20/98 10:37:53
Sample Batch Information
Acids Method : EPA 625
Preparation Preparation Analysis
Date Time By Notes Date Time By
02/06/98 0900 JW 02/09/98 1938 TAS
02/06/98 0900 JW 02/09/98 2011 TAS
02/06/98 0900 JW 02/09/98 2044 TAS
02/06/98 0900 JW 02/10/98 0210 TAS
02/06/98 0900 JW 02/11/98 0442 TAS
02/06/98 0900 JW 02/11/98 0515 TAS
02/19/98 0900 JW/CM I I
02/19/98 0900 JW/CM I I
02/19/98 0900 JW/CM I I 02/19/98 0900 JW/CM I I
Inst#
5971
5971
5971
5971
5971
5971
• •
Analytical Services Inc. Batch QC
For Report Number :91476
Base Neutrals
Page 10
Matrix: Aqueous Batch# 36058 Method: EPA 625
Lab Control Information
Analyte
Acenaphthene
Acenaphthylene
Anthracene
Benzidine
Benzo(a)anthracene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
Benzo(ghi)perylene
Benzyl butyl phthalate
Bis(2-chloroethyl)ether
Bis(2-chloroethoxy)methane
Bis(2-ethylhexyl)phthalate
Bis(2-chloroisopropyl)ether
4-Bromophenyl phenyl ether
2-Chloronaphthalene
4-Chlorophenyl phenyl ether
Chrysene
Dibenzo(a,h)anthracene
Di-n-butylphthalate
1,3-Dichlorobenzene
1,2-Dichlorobenzene
1,4-Dichlorobenzene
3,3'-Dichlorobenzidine
Diethylphthalate
Dimethylphthalate
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Di-n-octylphthalate
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachloroethane
Indeno(l,2,3-cd)pyrene
Isophorone
Naphthalene
Nitrobenzene
N-Nitrosodi-n-propylamine
Phenanthrene
Pyrene
1,2,4-Trichlorobenzene
LC
%Rec
83
84
98
183
70
116
93
97
74
68
59
79
87
62
95
83
98
78
82
91
54
57
57
134
21
2
68
87
110
99
92
99
62
53
83
76
70
71
83
95
74
66
LCD
%Rec
90
90
105
167
77
121
105
104
78
76
66
86
98
69
101
89
102
84
85
97
59
63
63
145
18
2
84
92
125
105
99
106
66
56
88
84
78
79
88
102
83
73
LC
RPD
8
6
7
9
8
4
12
7
4
10
11
9
12
11
5
6
4
7
3
6
8
10
10
8
15
31
21
6
13
6
7
7
6
5
6
11
11
11
7
7
12
10
%Recovery
Range
46 -118
33 -145
27 -133
10 -200
33 -143
24 -159
11 -162
17 -163
10 -219
10 -152
10 -150
33 -184
10 -158
36 -166
53 -127
60 -118
28 -158
17 -168
10 -227
10 -118
10 -172
32 -129
36 -97
10 -262
10 -114
0 -110
24 -96
50 -158
10 -146
26 -137
59 -129
10 -152
24 -116
40 -113
10 -171
21 -196
21 -133
35 -180
41 -116
54 -120
26 -127
44 -142
RPD
Range
0 -31
0 -40
0 -40
0 -100
0 -40
0 -40
0 -42
0 -40
0 -56
0 -40
0 -50
0 -43
0 -40
0 -46
0 -40
0 -40
0 -33
0 -48
0 -70
0 -50
0 -40
0 -40
0 -28
0 -100
0 -40
0 -40
0 -38
0 -40
0 -50
0 -40
0 -40
0 -40
0 -40
0 -40
0 -45
0 -60
0 -40
0 -40
0 -38
0 -40
0 -31
0 -28
• • Page 11
Analytical Services Inc. Batch QC
Base Neutrals
Matrix : Aqueous Batch # 36058 Method : EPA 625
Matrix Spike Information MS MSD MS %Recovery RPD
Analyte %Rec %Rec RPD Range Range
Acenaphthene 88 96 10 46 -118 0 -31
Acenaphthylene 87 94 8 33 -145 0 -40
Anthracene 99 1.08 9 27 -133 0 -40
Benzidine 137 160 15 10 -200 0 -100
Benzo(a)anthracene 77 81 5 33 -143 0 -40
Benzo(b)fluoranthene 111 124 11 24 -159 0 -79
Benzo(k)fluoranthene 111 98 12 11 -162 0 -42
Benzo(a)pyrene 99 107 9 17 -163 0 -40
Benzo(ghi)perylene 74 77 4 10 -219 0 -56
Benzyl butyl phthalate 108 110 2 10 -152 0 -40
Bis(2-chloroethyl)ether 66 74 11 10 -150 0 -50
Bis(2-chloroethoxy)methane 80 88 9 33 -184 0 -43
Bis(2-ethylhexyl)phthalate 113 120 6 10 -158 0 -40
Bis(2-chloroisopropyl)ether 71 78 10 36 -166 0 -46
4-Bromophenyl phenyl ether 99 109 9 53 -127 0 -40
2-Chloronaphthalene 88 94 7 60 -118 0 -40
4-Chlorophenyl phenyl ether 103 111 8 28 -158 0 -33
Chrysene 77 83 7 17 -168 0 -48
Dibenzo(a,h)anthracene 81 85 4 10 -227 0 -70
Di-n-butylphthalate 102 111 8 10 -118 0 -50 1,3-Dichlorobenzene 65 68 5 10 -172 0 -40
1,2-Dichlorobenzene 67 71 6 32 -129 0 -40
1,4-Dichlorobenzene 67 73 7 36 -97 0 -28
3,3'-Dichlorobenzidine 139 149 7 10 -262 0 -100
Diethylphthalate 67 58 15 10 -114 0 -40
Dimethylphthalate 18 19 9 0 -110 0 -40
2,4-Dinitrotoluene 78 85 9 24 -96 0 -38 2,6-Dinitrotoluene 75 83 10 50 -158 0 -40
Di-n-octylphthalate 132 128 3 10 -146 0 -50 Fluoranthene 85 94 10 26 -137 0 -40 Fluorene 98 106 8 59 -121 0 -40
Hexachlorobenzene 102 108 6 10 -152 0 -40
Hexachlorobutadiene 81 85 6 24 -116 0 -40
Hexachloroethane 57 60 5 40 -113 0 -40
Indeno(l,2,3-cd)pyrene 81 85 5 10 -171 0 -45 Isophorone 71 78 10 21 -196 0 -60 Naphthalene 78 84 7 21 -133 0 -40 Nitrobenzene 72 77 7 35 -180 0 -40
N-Nitrosodi-n-propylamine 82 90 9 41 -116 0 -38 Phenanthrene 98 105 8 54 -120 0 -40 Pyrene 115 115 0 26 -127 0 -31 1,2,4-Trichlorobenzene 78 85 9 44 -142 0 -28
Matrix
Sample
36058BLK
36058LCS
36058LCSD
91476-3
91476-3MS
91476-3MSD
• •
Analytical Services Inc. Batch QC
Surrogate Recovery
Base Neutrals
Aqueous Batch# 36058 Method
% Recovery Objectives
Sl Nitrobenzene-d5 35 -
File 81 82 83 84
B3826 81
B3827 71
B3828 77
B3836 69
B3875 72
B3876 75
Page 12
EPA 625
114
85 86
•
Q.C. Information for Batch# 36058
• Page 13
Printed: 02/20/98 10:37:58
Blank Results Information
Base Neutrals Method: EPA 625
Analyte
Acenaphthene
Acenaphthylene
Anthracene
Benzo
Benzyl butyl phthalate
Bis
4-Bromophenyl phenyl ether
4-Chloroaniline
2-Chloronaphthalene
4-Chlorophenyl phenyl ether
Chrysene
Dibenzo
Dibenzofuran
Di-n-butylphthalate
1,3-Dichlorobenzene
1,2-Dichlorobenzene
1,4-Dichlorobenzene
3,3'-Dichlorobenzidine
Diethylphthalate
Dimethylphthalate
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Di-n-octylphthalate
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadiene
Hexachloroethane
Indeno
Isophorone
2-Methylnaphthalene
Naphthalene
2-Nitroaniline
3-Nitroaniline
4-Nitroaniline
Nitrobenzene
N-Nitrosodiphenylamine
N-Nitrosodi-n-propylamine
Phenanthrene
Pyrene
1,2,4-Trichlorobenzene
Blank
Result
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
Detection
Limit
10
10
10
10
10
10
10
20
10
10
10
10
10
10
10
10
10
20
10
10
20
20
10
10
10
10
10
10
2
10
10
10
10
50
50
50
10
10
10
10
10
10
Sample ID
36058BLK
36058LCS
36058LCSD
91476-3
91476-3MS
91476-3MSD
91941
92010-1
92005
92005DUP
•
Q.C. Information for Batch# 36058
• Page 14
Printed: 02/20/98 10:37:58
Sample Batch Information
Base Neutrals Method: EPA 625
Preparation Preparation Analysis
Date Time By Notes Date Time By
02/06/98 0900 JW 02/09/98 2116 TAS
02/06/98 0900 JW 02/09/98 2149 TAS
02/06/98 0900 JW 02/09/98 2222 TAS
02/06/98 0900 JW 02/10/98 0242 TAS
02/06/98 0900 JW 02/11/98 0548 TAS
02/06/98 0900 JW 02/11/98 0620 TAS
02/19/98 0900 JW/CM I I
02/19/98 0900 JW/CM I I
02/19/98 0900 JW/CM I I
02/19/98 0900 JW/CM I I
Inst#
5971
5971
5971
5971
5971
5971
Matrix : Aqueous
Lab Control Information
Analyte
PCB 1016
PCB 1260
Matrix Spike Information
Analyte
PCB 1016
PCB 1260
• •
Analytical Services Inc. Batch QC
For Report Number :91476
PCB's
Page 15
Batch # 36120 Method : EPA 608/8082
LC LCD LC %Recovery RPD
%Rec %Rec RPD Range Range
78 65 18 50 -150 0 -50
88 74 17 50 -150 0 -50
MS MSD MS %Recovery RPD
%Rec %Rec RPD Range Range
92 78 16 50 -150 0 -50
89 85 5 50 -150 0 -50
Matrix
Sample
36120BLK
36120LCS
36120LCSD
91476-3
91476-3MS
91476-3MSD
91556
91674-1
91674-2
91674-3
91674-4
91674-5
• •
Analytical Services Inc. Batch QC
Surrogate Recovery
PCB's
Aqueous Batch# 36120 Method
% Recovery Objectives
Sl Tetrachloro-m-xylene 50 -
S2 Decachlorobiphenyl 50 -
File Sl S2 S3 S4
020998051F 92 128
020998052F 77 94
020998053F 63 80
020998054F 80 100
020998055F 76 93
020998056F 76 93
021398034F 125 160
021798091F 96 110
021798092F 100 113
021798093F 85 92
021798094F 106
021798095F 125 169
Page 16
EPA 608/8082
150
150
S5 S6
• •
Q.C. Information for Batch# 36120
Page 17
Printed: 02/20/98 10:37:59
Analyte
PCB 1016
PCB 1221
PCB 1232
PCB 1242
PCB 1248
PCB 1254
PCB 1260
Blank Results Information
PCB's Method: EPA 8082
Blank
Result
BDL
BDL
BDL
BDL
BDL
BDL
BDL
Detection
Limit
1.0
1.0
1.0
1.0
1.0
1.0
1.0
• •
Q.C. Information for Batch# 36120
Page 18
Printed: 02/20/98 10:37:59
Sample Batch Information
PCB's Method : EPA 8082
Preparation Preparation Analysis
Sample ID Date Time By Notes Date Time By Inst #
36120BLK 02/06/98 0900 JW/CM PCB 02/10/98 1826 JQZ GC-3
36120LCS 02/06/98 0900 JW/CM PCB 02/10/98 1855 JQZ GC-3
36120LCSD 02/06/98 0900 JW/CM PCB 02/10/98 1924 JQZ GC-3 91476-3 02/06/98 0900 JW/CM PCB 02/10/98 1953 JQZ GC-3 91476-3MS 02/06/98 0900 JW/CM PCB 02/10/98 2022 JQZ GC-3 91476-3MSD 02/06/98 0900 JW/CM PCB 02/10/98 2251 JQZ GC-3
91556 02/10/98 0900 JW/CM PCB 02/16/98 1439 JQZ GC-3 91674-1 02/11/98 0900 JW/CM PCB 02/18/98 0306 JQZ GC-3
91674-2 02/11/98 0900 JW/CM PCB 02/18/98 0330 JQZ GC-3
91674-3 02/11/98 0900 JW/CM PCB 02/18/98 0354 JQZ GC-3 91674-4 02/11/98 0900 JW/CM PCB 02/18/98 0418 JQZ GC-3
91674-5 02/11/98 0900 JW/CM PCB 02/10/98 0442 JQZ GC-3
91796-1 02/16/98 1000 TB PCB I I 91796-lDUP 02/16/98 1000 TB PCB I I 91796-2 02/16/98 1000 TB PCB I I 91796-2DUP 02/16/98 1000 TB PCB I I 91894-1 02/17/98 1400 JW/CM PCB I I 91894-2 02/17/98 1400 JW/CM PCB I I 91894-3 02/17/98 1400 JW/CM PCB I I 91894-4 02/17/98 1400 JW/CM PCB I I 91894-5 02/17/98 1400 JW/CM PCB I I 91894-6 02/17/98 1400 JW/CM PCB I I
91894-7 02/17/98 1400 JW/CM PCB I I 91968-1 02/19/98 1700 JW/CM PCB I I 91968-2 02/19/98 1700 JW/CM PCB I I 91968-3 02/19/98 1700 JW/CM PCB I I
• •
Analytical Services Inc. Batch QC
For Report Number :91476
QC Batch General Information
Batch Analysis
Number Analyte Method
35466
AANote
35466
AANote
35466
,.,...,Note
35469
AANote
35469
35469
35469
35469
35469
35469
35469
35469
35469
35469
35469
35469
35469
35469
AANote
35469
35469
35469
35469
35991
35991
36033
36082
36086
36217
Se EPA 270.2
QC PASSES ON LCS,LCSD
Pb EPA 239.2
QC PASSES ON LCS,LCSD,PDS
Tl EPA 279.2
QC PASSES ON LCS,LCSD,PDS
Ag EPA 200.7
BATCH PASSES ON LCS/LCSD
Al EPA 200.7
As EPA 200.7
Ba EPA 200.7
Be EPA 200.7
Ca EPA 200.7
Cd EPA 200.7
Co EPA 200.7
Cr EPA 200.7
Cu EPA 200.7
Fe EPA 200.7
K EPA 200.7
Mg EPA 200.7
Mn EPA 200.7
Na EPA 200.7
BATCH PASSES ON LCS/LCSD
Ni
Sb
Zn
V
EPA 200.7
EPA 200.7
EPA 200.7
BOD<5 hi
EPA 200.7
EPA 405.1
BOD<5
pH
CN
low EPA 405.1
EPA 150.1
EPA 335.2
EPA 245.l
EPA 1664
Matrix
Aqueous <
Aqueous <
Aqueous <
Aqueous <
Aqueous <
Aqueous <
Aqueous <
Aqueous <
Aqueous <
Aqueous <
Aqueous <
Aqueous <
Aqueous <
Aqueous <
Aqueous <
Aqueous <
Aqueous <
Aqueous <
Aqueous <
Aqueous <
Aqueous <
Aqueous <
Aqueous <
Aqueous <
Aqueous
Aqueous <
Aqueous <
Aqueous
Page 19
Blank
Result
0.0050
0.0030
0.0020
0.0100
0.1000
0.0100
0.0100
0.0010
0.0100
0.0050
0.0100
0.0100
0.0100
0.0100
0.2000
0.0100
0.0100
0.0100
0.0100
0.0100
0.0200
0.0200
5.0000
5.0000
0.0000
0.0200
0.0002
0.0000
Prep.
Method
AANote
Hg
O/G
BATCH PASSES ON ALL DATA.RPD OF LCS FAILS.NO SAMPLE FOR MSD
36234
36239
N
TSS
EPA 350.2
EPA 160.2
Aq/Solid <
Aqueous <
0.1000
5.0000
• • Page 20
Analytical Services Inc. Batch QC
For Report Number :91476
Lab Control Information
Batch LC LCD LC %Recovery RPD
Number Analyte Method %Rec %Rec RPD Range Range
35466 Se EPA 270.2 95 101 6 76 -124 0 -20
35466 Pb EPA 239.2 95 120 23 76 -124 0 -20
35466 Tl EPA 279.2 120 99 19 76 -124 0 -20
35469 Ag EPA 200.7 118 120 2 76 -124 0 -20
35469 Al EPA 200.7 92 89 3 76 -124 0 -20 35469 As EPA 200.7 94 93 1 76 -124 0 -20 35469 Ba EPA 200.7 96 94 2 76 -124 0 -20 35469 Be EPA 200.7 93 92 1 76 -124 0 -20 35469 Ca EPA 200.7 88 87 1 76 -124 0 -20 35469 Cd EPA 200.7 91 90 1 76 -124 0 -20
35469 Co EPA 200.7 94 93 1 76 -124 0 -20
35469 Cr EPA 200.7 89 87 2 76 -124 0 -20 35469 Cu EPA 200.7 95 93 2 76 -124 0 -20
35469 Fe EPA 200.7 91 89 2 76 -124 0 -20 35469 K EPA 200.7 120 110 9 76 -124 0 -20 35469 Mg EPA 200.7 91 89 2 76 -124 0 -20
35469 Mn EPA 200.7 92 90 2 76 -124 0 -20 35469 Na EPA 200.7 99 97 2 76 -124 0 -20 35469 Ni EPA 200.7 98 97 1 76 -124 0 -20
35469 Sb EPA 200.7 100 100 0 76 -124 0 -20 35469 Zn EPA 200.7 89 88 1 76 -124 0 -20 35469 V EPA 200.7 95 94 1 76 -124 0 -20 35991 BOD<5 hi EPA 405.1 94 91 3 81 -118 0 -30 35991 BOD<5 low EPA 405.1 90 88 2 81 -118 0 -30 36033 pH EPA 150.1 99 99 0 80 -120 0 -20 36082 CN EPA 335.2 92 97 5 75 -125 0 -30 36086 Hg EPA 245.1 99 102 3 76 -124 0 -20 36217 O/G EPA 1664 64 42 42 32 -103 0 -40 36234 N EPA 350.2 100 104 4 75 -125 0 -30 36239 TSS EPA 160.2 101 96 5 60 -140 0 -40
Matrix Spike Information
Batch MS MSD MS %Recovery RPD Number Analyte Method %Rec %Rec RPD Range Range
35466 Se EPA 270.2 39 62 46 76 -124 0 -20 35466 Pb EPA 239.2 170 170 0 76 -124 0 -20 35466 Tl EPA 279.2 146 146 0 76 -124 0 -20 35469 Ag EPA 200.7 140 135 4 76 -124 0 -20 35469 Al EPA 200.7 90 90 0 76 -124 0 -20 35469 As EPA 200.7 90 90 0 76 -124 0 -20 35469 Ba EPA 200.7 95 95 0 76 -124 0 -20 35469 Be EPA 200.7 90 90 0 76 -124 0 -20 35469 Ca EPA 200.7 85 80 6 76 -124 0 -20 35469 Cd EPA 200.7 85 85 0 76 -124 0 -20 35469 Co EPA 200.7 90 90 0 76 -124 0 -20
• • Page 21
Analytical Services Inc. Batch QC
For Report Number :91476
Matrix Spike Information
Batch MS MSD MS %Recovery RPD Number Analyte Method %Rec %Rec RPD Range Range
35469 Cr EPA 200.7 80 80 0 76 -124 0 -20 35469 Cu EPA 200.7 85 85 0 76 -124 0 -20
35469 Fe EPA 200.7 80 85 6 76 -124 0 -20
35469 K EPA 200.7 120 120 0 76 -124 0 -20
35469 Mg EPA 200.7 85 85 0 76 -124 0 -20
35469 Mn EPA 200.7 85 90 6 76 -124 0 -20
35469 Na EPA 200.7 140 140 0 76 -124 0 -20
35469 Ni EPA 200.7 95 95 0 76 -124 0 -20 35469 Sb EPA 200.7 100 100 0 76 -124 0 -20
35469 Zn EPA 200.7 85 85 0 76 -124 0 -20 35469 V EPA 200.7 190 190 0 76 -124 0 -20 36082 CN EPA 335.2 103 101 2 75 -125 0 -30
36086 Hg EPA 245.l 99 96 3 76 -124 0 -20 36217 0/G EPA 1664 80 0 NC 32 -103 0 -40
36234 N EPA 350.2 104 102 2 75 -125 0 -30
36239 TSS EPA 160.2 88 94 7 60 -140 0 -40
Post Digestion Spike Information
Batch PDS %Recovery
Number Analyte Method %Rec Range
35466 Se EPA 270.2 144 76 -124
35466 Pb EPA 239.2 119 76 -124
35466 Tl EPA 279.2 104 76 -124
35469 Ag EPA 200.7 120 85 -115
35469 Al EPA 200.7 99 85 -115
35469 As EPA 200.7 91 85 -115
35469 Ba EPA 200.7 98 85 -115
35469 Be EPA 200.7 93 85 -115
35469 Ca EPA 200.7 44 85 -115 35469 Cd EPA 200.7 88 85 -115
35469 Co EPA 200.7 92 85 -115
35469 Cr EPA 200.7 78 85 -115
35469 Cu EPA 200.7 98 85 -115
35469 Fe EPA 200.7 53 85 -115
35469 K EPA 200.7 120 85 -115
35469 Mg EPA 200.7 53 85 -115 35469 Mn EPA 200.7 90 85 115
35469 Na EPA 200.7 140 85 -115
35469 Ni EPA 200.7 97 85 -115 35469 Sb EPA 200.7 100 85 -115
35469 Zn EPA 200.7 87 85 -115
35469 V EPA 200.7 93 85 -115
• •
Analytical Services Inc. Batch QC
For Report Number :91476
Unspiked Sample Duplicate Information
Batch
Number
35991
36033
36082
36234
36239
Analyte
BOD<5 hi
pH
CN
N
TSS
Method
EPA 405.1
EPA 150.1
EPA 335.2
EPA 350.2
EPA 160.2
Sample 1 Sample
RPD RPD
12 0
0 0
3 0
0 2
0 17
Page 22
2 RPD
Range
0 -30
0 -20
0 -30
0 -30
0 -40
• • Page 23
Q.C. Information for Batch# 35466 For Report Number :91476
Sample Batch Information
Analysis : Se, Pb, Tl
Preparation Preparation Analysis
Sample ID Tag Date Time By Notes Date Time By Inst
91384-13 Se 02/06/98 0845 KSP GFAA 02/07/98 1319 MLR AAl 91384-14 Se 02/06/98 0845 KSP GFAA 02/07/98 1319 MLR AAl
35466BLANK Se 02/06/98 0845 KSP GFAA 02/07/98 1319 MLR AAl
35466LCS Se 02/06/98 0845 KSP GFAA 02/07/98 1319 MLR AAl
35466LCSD Se 02/06/98 0845 KSP GFAA 02/07/98 1319 MLR AAl
91476-lMS Se 02/06/98 0845 KSP GFAA 02/07/98 1319 MLR AAl 91476-lMSD Se 02/06/98 0845 KSP GFAA 02/07/98 1319 MLR AAl 91459-lPDS Se 02/06/98 0845 KSP GFAA 02/07/98 1319 MLR AAl 91476-lDUP Se 02/06/98 0845 KSP GFAA 02/07/98 1319 MLR AAl 91429 Se 02/06/98 0845 KSP GFAA 02/07/98 1319 MLR AAl 91459-1 Se 02/06/98 0845 KSP GFAA 02/07/98 1319 MLR AAl 91476-1 Se 02/06/98 0845 KSP GFAA 02/07/98 1319 MLR AAl 35466BLANK As 02/06/98 0845 KSP GFAA 02/07/98 1458 MLR AAl 35466LCS As 02/06/98 0845 KSP GFAA 02/07/98 1458 MLR AAl 35466LCSD As 02/06/98 0845 KSP GFAA 02/07/98 1458 MLR AAl 91476-lMS As 02/06/98 0845 KSP GFAA 02/07/98 1458 MLR AAl 91476-lMSD As 02/06/98 0845 KSP GFAA 02/07/98 1458 MLR AAl 91459-lPDS As 02/06/98 0845 KSP GFAA 02/07/98 1458 MLR AAl 91476-lDUP As 02/06/98 0845 KSP GFAA 02/07/98 1458 MLR AAl 91384-13 As 02/06/98 0845 KSP GFAA 02/07/98 1458 MLR AAl 91384-14 As 02/06/98 0845 KSP GFAA 02/07/98 1458 MLR AAl 91429 As 02/06/98 0845 KSP GFAA 02/07/98 1458 MLR AAl 91459-1 As 02/06/98 0845 KSP GFAA 02/07/98 1458 MLR AAl 91476-1 As 02/06/98 0845 KSP GFAA 02/07/98 1458 MLR AAl 35466BLANK Pb 02/06/98 0845 KSP GFAA 02/09/98 1112 MLR AAl 35466LCS Pb 02/06/98 0845 KSP GFAA 02/09/98 1112 MLR AAl 35466LCSD Pb 02/06/98 0845 KSP GFAA 02/09/98 1112 MLR AAl 91476-lMS Pb 02/06/98 0845 KSP GFAA 02/09/98 1112 MLR AAl 91476-lMSD Pb 02/06/98 0845 KSP GFAA 02/09/98 1112 MLR AAl 91459-lPDS Pb 02/06/98 0845 KSP GFAA 02/09/98 1112 MLR AAl 91476-lDUP Pb 02/06/98 0845 KSP GFAA 02/09/98 1112 MLR AAl 91384-13 Pb 02/06/98 0845 KSP GFAA 02/09/98 1112 MLR AAl 91384-14 Pb 02/06/98 0845 KSP GFAA 02/09/98 1112 MLR AAl 91429 Pb 02/06/98 0845 KSP GFAA 02/09/98 1112 MLR AAl 91459-1 Pb 02/06/98 0845 KSP GFAA 02/09/98 1112 MLR AAl 91476-1 Pb 02/06/98 0845 KSP GFAA 02/09/98 1112 MLR AAl 35466BLANK Tl 02/06/98 0845 KSP GFAA 02/09/98 1311 MLR AA2 35466LCS Tl 02/06/98 0845 KSP GFAA 02/09/98 1311 MLR AA2 35466LCSD Tl 02/06/98 0845 KSP GFAA 02/09/98 1311 MLR AA2 91476-lMS Tl 02/06/98 0845 KSP GFAA 02/09/98 1311 MLR AA2 91476-lMSD Tl 02/06/98 0845 KSP GFAA 02/09/98 1311 MLR AA2 91459-lPDS Tl 02/06/98 0845 KSP GFAA 02/09/98 1311 MLR AA2 91476-lDUP Tl 02/06/98 0845 KSP GFAA 02/09/98 1311 MLR AA2 91384-13 Tl 02/06/98 0845 KSP GFAA 02/09/98 1311 MLR AA2 91384-14 Tl 02/06/98 0845 KSP GFAA 02/09/98 1311 MLR AA2 ·91429 Tl 02/06/98 0845 KSP GFAA 02/09/98 1311 MLR AA2 91459-1 Tl 02/06/98 0845 KSP GFAA 02/09/98 1311 MLR AA2 91476-1 Tl 02/06/98 0845 KSP GFAA 02/09/98 1311 MLR AA2
• • Page 24
Q.C. Information for Batch# 35469 For Report Number :91476
Sample Batch Information
Analysis Ag, Al, As, Ba, Be, Ca, Cd, Co, Cr, Cu, Fe, K, Mg, Mn, Na, Ni
Sb Zn V
Preparation Preparation Analysis
Sample ID Tag Date Time By Notes Date Time By Inst
91351-4 02/06/98 0935 KSP TRACE 02/06/98 1443 MCW ICP2 91428-6 02/06/98 0935 KSP TRACE 02/06/98 1507 MCW ICP2 91459-1 02/06/98 0935 KSP TRACE 02/06/98 1510 MCW ICP2 35469BLANK 02/06/98 0935 KSP TRACE 02/06/98 1416 MCW ICP2 35469LCS 02/06/98 0935 KSP TRACE 02/06/98 1419 MCW ICP2 35469LCSD 02/06/98 0935 KSP TRACE 02/06/98 1422 MCW ICP2 91476-lMS 02/06/98 0935 KSP TRACE 02/06/98 1425 MCW ICP2 91476-lMSD 02/06/98 0935 KSP TRACE 02/06/98 1428 MCW ICP2 91518PDS 02/06/98 0935 KSP TRACE 02/06/98 1431 MCW ICP2 91476-lDUP 02/06/98 0935 KSP TRACE 02/06/98 1434 MCW ICP2 91498 02/06/98 0935 KSP TRACE 02/06/98 1440 MCW ICP2 91518 02/06/98 0935 KSP TRACE 02/06/98 1513 MCW ICP2 91504-1 02/06/98 0935 KSP TRACE 02/06/98 1516 MCW ICP2 91504-2 02/06/98 0935 KSP TRACE 02/06/98 1520 MCW ICP2 91523 02/06/98 0935 KSP TRACE 02/06/98 1523 MCW ICP2 91524-1 02/06/98 0935 KSP TRACE 02/06/98 1526 MCW ICP2 91525 02/06/98 0935 KSP TRACE 02/06/98 1529 MCW ICP2 91526 02/06/98 0935 KSP TRACE 02/06/98 1532 MCW ICP2 91476-1 02/06/98 0935 KSP TRACE 02/06/98 1437 MCW ICP2 91508-1 02/06/98 0935 KSP TRACE 02/06/98 1535 MCW ICP2 91508-2 02/06/98 0935 KSP TRACE 02/06/98 1545 MCW ICP2 91479-1 02/06/98 0935 KSP TRACE 02/06/98 1548 MCW ICP2 91479-2 02/06/98 0935 KSP TRACE 02/06/98 1551 MCW ICP2 91479-3 02/06/98 0935 KSP TRACE 02/06/98 1554 MCW ICP2 91479-4 02/06/98 0935 KSP TRACE 02/06/98 1557 MCW ICP2 91496 02/06/98 0935 KSP TRACE 02/06/98 1600 MCW ICP2 91508-lMS/QC 02/06/98 0935 KSP TRACE 02/06/98 1603 MCW ICP2 91508-lMSD/QC 02/06/98 0935 KSP TRACE 02/06/98 1609 MCW ICP2
• • Page 25
Q.C. Information for Batch# 35991 For Report Number :91476
Sample Batch Information
Analysis : BOD<5 hi, BOD<5 low
Preparation Preparation Analysis
Sample ID Tag Date Time By Notes Date Time By Inst
35991BLK 02/04/98 0830 SLK/ARS 02/09/98 0830 SLK/ARS
35991LCS 02/04/98 0830 SLK/ARS 02/09/98 0830 SLK/ARS
35991LCSD 02/04/98 0830 SLK/ARS 02/09/98 0830 SLK/ARS
91428-1 02/04/98 0830 SLK/ARS 02/09/98 0830 SLK/ARS
91428-lDUP 02/04/98 0830 SLK/ARS 02/09/98 0830 SLK/ARS
91428-2 02/04/98 0830 SLK/ARS 02/09/98 0830 SLK/ARS
CBODLCS 02/04/98 0830 SLK/ARS 02/09/98 0830 SLK/ARS
CBODLCSD 02/04/98 0830 SLK/ARS 02/09/98 0830 SLK/ARS
91400 02/04/98 0830 SLK/ARS 02/09/98 0830 SLK/ARS
91411-1 02/04/98 0830 SLK/ARS 02/09/98 0830 SLK/ARS
91411-2 02/04/98 0830 SLK/ARS 02/09/98 0830 SLK/ARS
91427-1 02/04/98 0830 SLK/ARS 02/09/98 0830 SLK/ARS
91427-2 02/04/98 0830 SLK/ARS 02/09/98 0830 SLK/ARS
91430-1 02/04/98 0830 SLK/ARS 02/09/98 0830 SLK/ARS
91430-2 02/04/98 0830 SLK/ARS 02/09/98 0830 SLK/ARS
91429 02/04/98 0830 SLK/ARS 02/09/98 0830 SLK/ARS
91435-2 02/04/98 0830 SLK/ARS 02/09/98 0830 SLK/ARS
91437 02/04/98 0830 SLK/ARS 02/09/98 0830 SLK/ARS
91438-2 02/04/98 0830 SLK/ARS 02/09/98 0830 SLK/ARS 91440-2 02/04/98 0830 SLK/ARS 02/09/98 0830 SLK/ARS 91451-1 02/04/98 1200 SLK/ARS 02/09/98 0830 SLK/ARS
91446-1 02/04/98 1200 SLK/ARS 02/09/98 0830 SLK/ARS
35991LCSLOW 02/04/98 1200 SLK/ARS 02/09/98 0830 SLK/ARS
35991LCSDLOW 02/04/98 1200 SLK/ARS 02/09/98 0830 SLK/ARS
35991BLK2 02/04/98 1200 SLK/ARS 02/09/98 0830 SLK/ARS
91461 02/04/98 1450 SLK/ARS 02/09/98 0830 SLK/ARS 91456-1 02/04/98 1450 SLK/ARS 02/09/98 0830 SLK/ARS
91456-lDUP 02/04/98 1450 SLK/ARS 02/09/98 0830 SLK/ARS 91456-2 02/04/98 1450 SLK/ARS 02/09/98 0830 SLK/ARS 91456-3 02/04/98 1450 SLK/ARS 02/09/98 0830 SLK/ARS
91328RR 02/04/98 1450 SLK/ARS 02/09/98 0830 SLK/ARS
91464-1 02/04/98 1450 SLK/ARS 02/09/98 0830 SLK/ARS
91464-3 02/04/98 1450 SLK/ARS 02/09/98 0830 SLK/ARS 91465-1 02/04/98 1545 SLK/ARS 02/09/98 0830 SLK/ARS 91465-2 02/04/98 1545 SLK/ARS 02/09/98 0830 SLK/ARS 91466-1 02/04/98 1545 SLK/ARS 02/09/98 0830 SLK/ARS
91466-2 02/04/98 1545 SLK/ARS 02/09/98 0830 SLK/ARS
91467-1 02/04/98 1545 SLK/ARS 02/09/98 0830 SLK/ARS
91468 02/04/98 1545 SLK/ARS 02/09/98 0830 SLK/ARS 91473-1 02/04/98 1545 SLK/ARS 02/09/98 0830 SLK/ARS 91473-2 02/04/98 1545 SLK/ARS 02/09/98 0830 SLK/ARS
91475 02/04/98 1545 SLK/ARS 02/09/98 0830 SLK/ARS 91472-1 02/04/98 1545 SLK/ARS 02/09/98 0830 SLK/ARS 91474-1 02/04/98 1545 SLK/ARS 02/09/98 0830 SLK/ARS
91474-2 02/04/98 1545 SLK/ARS 02/09/98 0830 SLK/ARS
91476-1 02/04/98 1640 SLK/ARS 02/09/98 0830 SLK/ARS 91477-3 . 02/04/98 1640 SLK/ARS 02/09/98 0830 SLK/ARS 91477-3 02/04/98 1640 SLK/ARSCBOD 02/09/98 0830 SLK/ARS
Sample ID
91478-1
91478-2
•
Q.C. Information for Batch# 35991
• Page 26
For Report Number :91476
Sample Batch Information
Analysis : BOD<5 hi, BOD<5 low
Preparation
Tag Date Time By
Preparation
Notes
02/04/98 1640 SLK/ARSCBOD
02/04/98 1640 SLK/ARSCBOD
Analysis
Date Time By
02/09/98 0830 SLK/ARS
02/09/98 0830 SLK/ARS
Inst
• •
Q.C. Information for Batch# 36033
Page 27
For Report Number :91476
Sample Batch Information
Analysis : pH
Preparation Preparation Analysis
Sample ID Tag Date Time By Notes Date Time By Inst
36033LCS I I 02/04/98 1800 JN 410A 36033LCSD I I 02/04/98 1800 JN 410A 36033CALCHK I I 02/04/98 1800 JN 410A 91456-1 I I 02/04/98 1800 JN 410A 91456-lDUP I I 02/04/98 1800 JN 410A 91456-2 I I 02/04/98 1800 JN 410A
91456-3 I I 02/04/98 1800 JN 410A 91467-1 I I 02/04/98 1800 JN 410A 91467-2 I I 02/04/98 1800 JN 410A 91465-2 I I 02/04/98 1800 JN 410A 91476-3 I I 02/04/98 1800 JN 410A 91471 I I 02/04/98 1800 JN 410A 91475 I I 02/04/98 1800 JN 410A 91482-2 I I 02/04/98 1800 JN 410A 91473-1 I I 02/04/98 1800 JN 410A 91486-2 I I 02/04/98 1800 JN 410A 91489-3 I I 02/04/98 1800 JN 410A 91489-2 I I 02/04/98 1800 JN 410A 91489-4 I I 02/04/98 1800 JN 410A 91489-1 I I 02/04/98 1800 JN 410A 91486-2DUP I I 02/04/98 1800 JN 410A
' • •
Q.C. Information for Batch# 36082
Page 28
For Report Number :91476
Sample Batch Information
Analysis : CN
Preparation Preparation Analysis
Sample ID Tag Date Time By Notes Date Time By Inst
36082BLK 02/08/98 0915 ARS MIDI-DIST 02/08/98 1145 ARS GENES 36082LCS 02/08/98 0915 ARS MIDI-DIST 02/08/98 1145 ARS GENES 36082LCSD 02/08/98 0915 ARS MIDI-DIST 02/08/98 1145 ARS GENES 91386-2MS 02/08/98 0915 ARS MIDI-DIST 02/08/98 1145 ARS GENES 91386-2MSD 02/08/98 0915 ARS MIDI-DIST 02/08/98 1145 ARS GENES 91332-34 02/08/98 0915 ARS MIDI-DIST 02/08/98 1145 ARS GENES
91332-35 02/08/98 0915 ARS MIDI-DIST 02/08/98 1145 ARS. GENES 91336-2 02/08/98 0915 ARS MIDI-DIST 02/08/98 1145 ARS GENES 91346 02/08/98 0915 ARS MIDI-DIST 02/08/98 1145 ARS GENES 91386-2 02/08/98 0915 ARS MIDI-DIST 02/08/98 1145 ARS GENES 9134 7 02/08/98 1115 ARS MIDI-DIST 02/08/98 1340 ARS GENES 36082CAL5 02/08/98 1115 ARS MIDI-DIST 02/08/98 1340 ARS GENES 36082CAL15 02/08/98 1115 ARS MIDI-DIST 02/08/98 1340 ARS GENES 91458-5 02/08/98 1115 ARS MIDI-DIST 02/08/98 1340 ARS GENES 91458-6 02/08/98 1115 ARS MIDI-DIST 02/08/98 1340 ARS GENES 91458-7 02/08/98 1115 ARS MIDI-DIST 02/08/98 1340 ARS GENES 91486-1 02/08/98 1115 ARS MIDI-DIST 02/08/98 1340 ARS GENES 91476-3 02/08/98 1115 ARS MIDI-DIST 02/08/98 1340 ARS GENES 91472-1 02/08/98 1115 ARS MIDI-DIST 02/08/98 1340 ARS GENES 91434-2 02/08/98 1115 ARS MIDI-DIST 02/08/98 1340 ARS GENES 91467-2 02/08/98 1310 ARS MIDI-DIST 02/08/98 1500 ARS GENES 91467-2DUP 02/08/98 1310 ARS MIDI-DIST 02/08/98 1500 ARS GENES 91429 02/08/98 1310 ARS MIDI-DIST 02/08/98 1500 ARS GENES 91429DUP 02/08/98 1310 ARS MIDI-DIST 02/08/98 1500 ARS GENES 91444-1 02/08/98 1310 ARS MIDI-DIST 02/08/98 1500 ARS GENES 91444-2 02/08/98 1310 ARS MIDI-DIST 02/08/98 1500 ARS GENES 91540-1 02/08/98 1310 ARS MIDI-DIST 02/08/98 1500 ARS GENES '91515 02/08/98 1310 ARS MIDI-DIST 02/08/98 1500 ARS GENES 91543 02/08/98 1310 ARS MIDI-DIST 02/08/98 1500 ARS GENES
• • •
Q.C. Information for Batch# 36086
Page 29
For Report Number :91476
Sample Batch Information
Analysis : Hg
Preparation Preparation Analysis
Sample ID Tag Date Time By Notes Date Time By Inst
91476-1 HG 02/10/98 0840 FBS 02/10/98 1258 FBS HGl 36086BLANK HG 02/10/98 0840 FBS 02/10/98 1244 FBS HGl 36086LCS HG 02/10/98 0840 FBS 02/10/98 1247 FBS HGl
36086LCSD HG 02/10/98 0840 FBS 02/10/98 1249 FBS HGl 91476-lMS HG 02/10/98 0840 FBS 02/10/98 1251 FBS HGl
91476-lMSD HG 02/10/98 0840 FBS 02/10/98 1253 FBS HGl 91476-lDUP HG 02/10/98 0840 FBS 02/10/98 1256 FBS HGl 91661 HG 02/10/98 0840 FBS 02/10/98 1329 FBS HGl 91486-1 HG 02/10/98 0840 FBS 02/10/98 1300 FBS HGl 91489-1 HG 02/10/98 0840 FBS 02/10/98 1303 FBS HGl 91489-2 HG 02/10/98 0840 FBS 02/10/98 1305 FBS HGl 91489-3 HG 02/10/98 0840 FBS 02/10/98 1312 FBS HGl 91489-4 HG 02/10/98 0840 FBS 02/10/98 1314 FBS HGl 91556 HG 02/10/98 0840 FBS 02/10/98 1317 FBS HGl 91574-1 HG 02/10/98 0840 FBS 02/10/98 1319 FBS HGl 91658 HG 02/10/98 0840 FBS 02/10/98 1321 FBS HGl
Sample ID
36217BLK
36217LCS
36217LCSD
91544
91390
91420-2
91408
91526
91590
91476-3
91476-3MS
91408
91449-2
91452-2
91447-2
• •
Q.C. Information for Batch# 36217
Page 30
For Report Number :91476
Sample Batch Information
Analysis : O/G
Preparation
Tag Date Time By
I I
I I
I I
I I
I I
I I
I I
I I
I I
I I
I I
I I
I I
I I
I I
Preparation
Notes
SILICA GEL
SILICA GEL
SILICA GEL
Analysis
Date Time By
02/09/98 1020 TD NK
02/09/98 1020 TD NK
02/09/98 1020 TD NK
02/09/98 1020 TD NK
02/10/98 1545 NK
02/10/98 1545 NK
02/10/98 1545 NK
02/09/98 1020 NK TD
02/09/98 1020 NK TD
02/09/98 1020 NK TD
02/09/98 1020 NK TD
02/09/98 1020 NK TD
02/09/98 1530 NK TD
02/09/98 1530 NK TD
02/09/98 1530 NK TD
Inst
, I ,, • •
Q.C. Information for Batch# 36234
Page 31
For Report Number :91476
Sample Batch Information
Analysis :N
Preparation Preparation Analysis
Sample ID Tag Date Time By Notes Date Time By Inst
36234BLK 02/10/98 0845 BG 02/10/98 1330 BG GENES
36234LCS 02/10/98 0845 BG 02/10/98 1330 BG GENES 36234LCSD 02/10/98 0845 BG 02/10/98 1330 BG GENES 36234CAL 02/10/98 0845 BG 02/10/98 1330 BG GENES 91476-lMS 02/10/98 0845 BG 02/10/98 1330 BG GENES 91476-lMSD 02/10/98 0845 BG 02/10/98 1330 BG GENES
91476-1 02/10/98 0845 BG 02/10/98 1330 BG GENES 91476-lDUP 02/10/98 0845 BG 02/10/98 1330 BG GENES 91489-1 02/10/98 0845 BG 02/10/98 1330 BG GENES
91489-2 02/10/98 0845 BG 02/10/98 1330 BG GENES 91489-3 02/10/98 0845 BG 02/10/98 1330 BG GENES 91489-4 02/10/98 0845 BG 02/10/98 1330 BG GENES 91461 02/10/98 0845 BG 02/10/98 1330 BG GENES 91467-1 02/10/98 0845 BG 02/10/98 1330 BG GENES 91403 02/10/98 0845 BG 02/10/98 1330 BG GENES 91550-10 02/10/98 0845 BG 02/10/98 1330 BG GENES 91477-4 02/10/98 0845 BG 02/10/98 1330 BG GENES 91477-4DUP 02/10/98 0845 BG 02/10/98 1330 BG GENES 91593-3 02/10/98 0845 BG 02/10/98 1330 BG GENES 91437 02/10/98 0845 BG 02/10/98 1330 BG GENES 91524-1 02/10/98 0845 BG 02/10/98 1330 BG GENES 91534-1 02/10/98 0845 BG 02/10/98 1330 BG GENES 91520 02/10/98 0845 BG 02/10/98 1330 BG GENES 91473-1 02/10/98 0845 BG 02/10/98 1330 BG GENES 91530-1 02/10/98 0845 BG 02/10/98 1330 BG GENES 91541 02/10/98 0845 BG 02/10/98 1330 BG GENES 91550-7 02/10/98 0845 BG 02/10/98 1330 BG GENES 91400 02/10/98 0845 BG 02/10/98 1330 BG GENES
Sample ID
36239BLK
36239LCS
36239LCSD
91505-4MS
91505-4MSD
91505-2DUP
91474-6DUP
91428-3
91428-4
91428-5
91474-4
91474-5
91474-6
91506-1
91506-2
91505-3
91505-4
91520
91505-1
91505-2
91476-1
91512-1
91511
91526
91515
• •
Q.C. Information for Batch# 36239
Page 32
For Report Number :91476
Sample Batch Information
Analysis : TSS
Preparation
Tag Date Time By
I I
I I
I I
I I
I I
I I
I I
I I
I I
I I
I I
I I
I I
I I
I I
I I
I I
I I
I I
I I
I I
I I
I I
I I
I I
Preparation
Notes
Analysis
Date Time By
02/09/98 1315 ADM
02/09/98 1315 ADM
02/09/98 1315 ADM
02/09/98 1315 ADM
02/09/98 1315 ADM
02/09/98 1315 ADM
02/09/98 1315 ADM
02/09/98 1315 ADM
02/09/98 1315 ADM
02/09/98 1315 ADM
02/09/98 1315 ADM
02/09/98 1315 ADM
02/09/98 1315 ADM
02/09/98 1315 ADM
02/09/98 1315 ADM
02/09/98 1315 ADM
02/09/98 1315 ADM
02/09/98 1315 ADM
02/09/98 1315 ADM
02/09/98 1315 ADM
02/09/98 1315 ADM
02/09/98 1315 ADM
02/09/98 1315 ADM
02/09/98 1315 ADM
02/09/98 1315 ADM
Inst
•
CRA SHIPPED 10 (Laboratory Name): j+-Y\CA \..i hct.l ';?eV'L:'\(€S x,,....c.
•
CONESTOGA-ROVERS & ASSOCIATES, INC. ltD ·Tee. \,,,"'o\t.?fl" Pc.. t--l..LA" , Ncve.-t)S.5 CA 500"1:Z
1351 Oakbrook Drive Suite 150 REFERENCE NUMBER: PROJECT NAME: Norcross, GA 30093 404-441-0027 3667 Tc..!cc l+u s L, ~.s: \NO#CJ I 4 7 b CHAIN OF CUSTODY RECORD
SAMPLER'S_/4 · /
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SIGNATURE· ~ NAME: 0~ f;~;:ait~~~ ~~ REMARKS
SEQ. YoATE SAMPLE zz
NO. TIME SAMPLE NUMBER ,TYPE 8
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RELINQ••-.. W-~L .. ./? u e, DATE: A7IQ)/ C/B @CEIVED BY:f-ai f?X DATE: (Y)./r..fJ IV<7
G) / ////.,{, . --~ /"'/ TIME: ·14oc} TIME: jjou
REL1fipl11SHED BY: DATE: RECEIVm ,4 J DATE: =1 -;:;;;Ja9
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RELINQUISHED BY: DATE: RECEIVED BY: DATE:
@ TIME: © TIME:
METHOD OF SHIPMEN'!' IF<i..D9'l( AIR BILL NUMBER: eo 1 03J '9-q oq s-r
White . Fully Executed Copy SAMPLETk: REC]l~Ejl FOR ~BORAlORY BY: ~ ". 0 6,pti:;.. / (l'h-tt_1.t-,lN3) [~( ~
Yellow . Receiving Laboratory Copy Yr'l1 C ol N Cvv-Z. -A/r,/ ,·. 1--1 . "0 • N~ ·. 06121
Pink Sampler Copy
:ATE: _1/t1/q9 TIME: Ot/ 50 Goldenrod . Chemist Copy
1007(FORMS) -DEC 6, 93 -REV.D -(AF-01) 1
MPSj988/5 □□5/261/
• •
ASI ANALYTICAL SERVICES, INC.
23 January, 1998
ENVIRONMENTAL MONITORING & LABORATORY ANALYSIS
110 TECHNOLOGY PARKWAY• NORCROSS, GA 30092
[phone] • FAX [phone]
Case Narrative Report 90698
The samples were sampled on 29 December, 1997 through 9 January, 1998 and
arrived at ASI on IO January, 1998. All conditions for proper sample receipt were met as
indicated on the chain ofcustody. The samples were logged into LIMS as report 90698
for the following analyses per client's request: Aqueous samples-pH (EPA 150.1),
Cyanide (EPA 335.2), Oil and Grease (EPA 1664), BNA (EPA 625), Pest/PCB (EPA
608), and VOA (EPA 624). All holding times for sample preparation and analysis were
met.
The pH analysis (EPA 150.1) met all data quality objectives.
Cyanide analysis (EPA 335.2) met all data quality objectives.
Oil and Grease analysis (EPA 1664) met all data quality objectives. 90698-2 was
used as the matrix spike sample but there was not enough for the duplicate.
BNA analysis (EPA 625) gave low Benzidine and 3,3 '-Dichlorobenzidine for the
MS/MSD. All other spikes and surrogates were acceptable.
Pest/PCB analysis (EPA 608) gave a high surrogate recovery for the duplicate
sample 90698-2. The results for the original analysis of 90698-2 were reported. All
other spikes and surrogates were acceptable.
VOA analysis (EPA 624) gave a high MSRPD for Chloroform. All other spikes
and surrogates were acceptable.
AdreaN. Tuck
Assistant QA Manager/ Project Manager
! ;c :-.'(-l-l./'11-__
( i,,);·,.~ ........ _ .. _,
A Unit of American Analytical Services, Inc.
I' • •
ASI ANALYTICAL SERVICES, INC.
Conestoga-Rovers
1351 Oakbrook Drive
Suite 150
Norcross, GA 30093
ENVIRONMENTAL MONITORING & LABORATORY ANALYSIS
110 TECHNOLOGY PARKWAY • NORCROSS, GA 30092
[phone] • FAX [phone]
LABORATORY REPORT
January 22, 1998
Attention: Mr. Neil Pickard Report No. 90698-1
Sample Description
Wastewater, composite, Jadco-Hughes, Project #3669, W-3669-MC-10898-086,
01/09/98, 12:35, received 01/10/98
RESULTS
Analysi_s cancelled per client request.
Project Man ger
Q~nTtwc
Quality Assurance
A Unit of American Analytical Services, Inc.
I ' • •
ASI ANALYTICAL SERVICES, INC.
ENVIRONMENTAL MONITORING & LABORATORY ANALYSIS
110 TECHNOLOGY PAR~AY • NORCROSS, GA 30092
[phone] • FAX [phone]
LABORATORY REPORT
Conestoga-Rovers January 22, 1998
1351 Oakbrook Drive
Suite 150
Norcross, GA 30093
Attention: Mr. Neil Pickard Report No. 90698-2
Sample Description
Wastewater, grab, Jadco-Hughes, Project #3669, W-3669-MC-10898-084,
01/08/98, 12:00, received 01/10/98
RESULTS
Detection
Result Limit
pH (laboratory) (EPA 150 .1) .................. . 7.85
Total Cyanide (CN) (mg/1) (EPA 335.2) ......... . BDL 0.01
Oil and Grease (mg/1) (EPA 1664) ............. . BDL 5
Volatile Organics (EPA 624) (ug/1) (ug/1)
Acetone ..................................... . BDL 100
Benzene ..................................... . BDL 2
Bromodichloromethane ........................ . BDL 10
Bromoform ................................... . BDL 10
Bromomethane ................................ . BDL 10
2-Butanone .................................. . BDL 100
Carbon disulfide ............................ . BDL 5
Carbon tetrachloride ........................ . BDL 2
Chlorobenzene ............................... . BDL 10
Chloroethane ................................ . BDL 5
Chloroform .................................. . 110 2
Chloromethane ............................... . BDL 10
Dibromochloromethane ........................ . BDL 10
1, 1-Dichloroethane .......................... . BDL 2
1, 2-Dichloroethane .......................... . 10 2
1,1-Dichloroethene .......................... . BDL 2
1,2-Dichloroethene (total) .................. . 50 2
BDL -Below Detection Limit
A Unit of American Analytical Services, Inc.
Conestoga-Rovers
Page 2 of 4
• •
January 22, 1998
Report No. 90698-2
Wastewater, grab, Jadco-Hughes, Project #3669, W-3669-MC-10898-084,
01/08/98, 12:00, received 01/10/98
RESULTS
Detection
Result Limit
Volatile Organics (EPA 624) (ug/1) (ug/1)
1, 2-Dichloropropane ......................... . BDL 2
cis-1,3-Dichloropropene ..................... . BDL 2
trans-1,3-Dichloropropene ................... . BDL 2
Ethylbenzene ................................ . BDL 2
2-Hexanone .................................. . BDL 50
Methylene chloride .......................... . BDL 10
1,1,2,2-Tetrachloroethane ................... . BDL 2
Tetrachloroethene ........................... . BDL 2
Toluene ..................................... . BDL 2
1,1,1-Trichloroethane ....................... . BDL 2
1, 1, 2-Trichloroethane ....................... . BDL 2
Trichloroethene ............................. . 10 2
Vinyl chloride .............................. . BDL 10
Xylenes ..................................... . BDL 2
Acid Extractable Organics (EPA 625) (ug/1) (ug/1)
Benzoic Acid ................................ . BDL 50
4-Chloro-3-methylphenol ..................... . BDL 10
2-Chlorophenol .............................. . BDL 10
2, 4-Dichlorophenol .......................... . BDL 10
2, 4-Dimethylphenol .......................... . BDL 10
2, 4-Dinitrophenol. .......................... . BDL 50
4,6-Dinitro-2-methylphenol .................. . BDL 50
2-Methylphenol .............................. . BDL 10
4 -Methylphenol .............................. . BDL 10
2-Nitrophenol ............................... . BDL 50
4-Nitrophenol. .............................. . BDL 50
Pentachlorophenol ........................... . BDL 20
Phenol ...................................... . BDL 10
2,4,6-Trichlorophenol ....................... . BDL 10
2,4,5-Trichlorophenol ....................... . BDL 10
BDL -Below Detection Limit
I'
Conestoga-Rovers
Page 3 of 4
• •
January 22, 1998
Report No. 90698-2
Wastewater, grab, Jadco-Hughes, Project #3669, W-3669-MC-10898-084,
01/08/98, 12:00, received 01/10/98
RESULTS
Detection
Result Limit
Base/Neutral Extractable Organics (EPA 625) (ug/1) (ug/1)
Acenaphthene ................................ . BDL 10
Acenaphthylene .............................. . BDL 10
Anthracene .................................. . BDL 10
Benzo (a) anthracene .......................... . BDL 10
Benzo(b)fluoranthene ........................ . BDL 10
Benzo (k) fluoranthene ........................ . BDL 10
Benzo ( a) pyrene .............................. . BDL 10
Benzo (ghi) perylene .......................... . BDL 10
Benzyl butyl phthalate ...................... . BDL 10
Bis(2-chloroethyl)ether ..................... . BDL 10
Bis(2-chloroethoxy)methane .................. . BDL 10
Bis(2-ethylhexyl)phthalate .................. . BDL 10
Bis(2-chloroisopropyl)ether ................. . BDL 10
4-Bromophenyl phenyl ether .................. . BDL 10
4-Chloroaniline ............................. . BDL 20
2-Chloronaphthalene ................. : ....... . BDL 10
4-Chlorophenyl phenyl ether ................. . BDL 10
Chrysene .................................... . BDL 10
Dibenzo(a,h)anthracene ...................... . BDL 10
Dibenzofuran ................................ . BDL 10
Di-n-butylphthalate ......................... . BDL 10
1, 3-Dichlorobenzene ......................... . BDL 10
1, 2-Dichlorobenzene ......................... . BDL 10
1, 4-Dichlorobenzene ......................... . BDL 10
3, 3' -Dichlorobenzidine ...................... . BDL 20
Diethylphthalate ............................ . BDL 10
Dimethylphthalate ........................... . BDL 10
2,4-Dinitrotoluene .......................... . BDL 20
2,6-Dinitrotoluene .......................... . BDL 20
Di-n-octylphthalate ......................... . BDL 10
Fluoranthene ................................ . BDL 10
Fluorene .................................... . BDL 10
Hexachlorobenzene ........................... . BDL 10
Hexachlorobutadiene ......................... . BDL 10
Hexachlorocyclopentadiene ................... . BDL 10
Hexachloroethane ............................ . BDL 2
Indeno ( 1, 2, 3 -cd) pyrene ...................... . BDL 10
Isophorone .................................. . BDL 10
BDL -Below Detection Limit
I' f .
Conestoga-Rovers
Page 4 of 4
• •
January 22, 1998
Report No. 90698-2
Wastewater, grab, Jadco-Hughes, Project #3669, W-3669-MC-10898-084,
01/08/98, 12:00, received 01/10/98
RESULTS
Detection
Result Limit
Base/Neutral Extractable Organics (EPA 625) (ug/1) (ug/1)
2-Methylnaphthalene ......................... . BDL 10
Naphthalene ................................. . BDL 10
2-Nitroaniline .............................. . BDL 50
3 -Ni troani 1 ine .............................. . BDL 50
4-Nitroaniline .............................. . BDL 50
Nitrobenzene ................................ . BDL 10
N-Nitrosodiphenylamine ...................... . BDL 10
N-Nitrosodi-n-propylamine ................... . BDL 10
Phenanthrene ................................ . BDL 10
Pyrene ...................................... . BDL 10
1, 2, 4-Trichlorobenzene ...................... . BDL 10
PCB's (EPA 608) (ug/1) (ug/1)
PCB 1016 .................................... . BDL 1.0
PCB 1221 .................................... . BDL 1.0
PCB 1232 .................................... . BDL 1.0
PCB 1242 .................................... . BDL 1.0
PCB 1248 .................................... . BDL 1.0
PCB 1254 .................................... . BDL 1. 0
PCB 1260 .................................... . BDL 1. 0
BDL -Below Detection Limit
North Carolina Laboratory I.D. No. 381
Resp~~~:tted,
Project Ma/Jager ~n Ll,uj_c._
Quality Assurance
• •
ASI ANALYTICAL SERVICES, INC.
ENVIRONMENTAL MONITORING & LABORATORY ANALYSIS
110 TECHNOLOGY PARKWAY • NORCROSS, GA 30092
(770) 734•4200 • FAX (770) 734•4201
LABORATORY REPORT
Conestoga-Rovers January 22, 1998
1351 Oakbrook Drive
Suite 150
Norcross, GA 30093
Attention: Mr. Neil Pickard Report No. 90698-3
Sample Description
Wastewater, grab, Jadco-Hughes, Project #3669, W-3669-MC-10898-085,
01/08/98, 12:38, received 01/10/98
RESULTS
Detection
Result Limit
Volatile Organics (EPA 624) (ug/1 l (ug/1)
Acetone ..................................... . BDL 100
Benzene ..................................... . BDL 2
Bromodichloromethane ........................ . BDL 10
Bromoform ................................... . BDL 10
Bromomethane ................................ . BDL 10
2-Butanone .................................. . BDL 100
Carbon disulfide ............................ . BDL 5
Carbon tetrachloride ........................ . BDL 2
Chlorobenzene ............................... . BDL 10
Chloroethane ................................ . BDL 5
Chloroform .................................. . 140 2
Chlorornethane ............................... . BDL 10
Dibromochloromethane ........................ . BDL 10
1, 1-Dichloroethane .......................... . 2 2
1,2-Dichloroethane .......................... . 30 2
1,1-Dichloroethene .......................... . BDL 2
1,2-Dichloroethene (total) .................. . 100 2
1, 2-Dichloropropane ......................... . BDL 2
cis-1,3-Dichloropropene ..................... . BDL 2
trans-1,3-Dichloropropene ................... . BDL 2
Ethylbenzene ................................ . BDL 2
2-Hexanone .................................. . BDL 50
BDL -Below Detection Limit
A Unit of American Analytical Services, Inc.
Conestoga-Rovers
Page 2 of 2
• •
January 22, 1998 Report No. 90698-3 Wastewater, grab, Jadco-Hughes, Project #3669, W-3669-MC-10898-085,
01/08/98, 12:38, received 01/10/98
RESULTS
Volatile Organics (EPA 624)
Methylene chloride ..........................
. 1,1,2,2-Tetrachloroethane
................... . Tetrachloroethene ...........................
. Toluene .....................................
. 1, 1, 1-Trichloroethane .......................
. 1, 1, 2 -Trichloroethane .......................
. Trichloroethene .............................
. Vinyl chloride ..............................
. Xylenes .....................................
. BDL -Below Detection Limit North Carolina Laboratory I.D. No. 381
Result
(ug/1)
BDL
BDL
6
3
BDL
BDL
30
BDL
BDL
Detection
Limit
(ug/1)
10
2
2
2
2
2
2
10
2
Res~~itted,
/), ~:ojec M nager
~f\,cw.,t_
Quality Assurance
.. • •
ASI ANALYTICAL SERVICES, INC.
ENVIRONMENTAL MONITORING & LABORATORY ANALYSIS
110 TECHNOLOGY PARKWAY• NORCROSS, GA 30092
[phone] • FAX [phone]
LABORATORY REPORT
Conestoga-Rovers January 22, 1998
1351 Oakbrook Drive
Suite 150
Norcross, GA 30093
Attention: Mr. Neil Pickard Report No. 90698-4
Sample Description
Wastewater,, Jadco-Hughes, Project #3669, Trip Blank, 12/29/97,, received
01/10/98
RESULTS
Detection
Result Limit
Volatile Organics (EPA 624) (ug/1) (ug/1)
Acetone ..................................... . BDL 100
Benzene ..................................... . BDL 2
Bromodichloromethane ........................ . BDL 10
Bromoform ................................... . BDL 10
Bromomethane ................................ . BDL 10
2 -Butanone .................................. . BDL 100
Carbon disulfide ............................ . BDL 5
Carbon tetrachloride ........................ . BDL 2
Chlorobenzene ............................... . BDL 10
Chloroethane ................................ . BDL 5
Chloroform .................................. . BDL 2
Chloromethane ............................... . BDL 10
Dibromochloromethane ........................ . BDL 10
1, 1-Dichloroethane .......................... . BDL 2
1, 2-Dichloroethane .......................... . BDL 2
1, 1-Dichloroethene .......................... . BDL 2
1,2-Dichloroethene (total} .................. . BDL 2
1,2-Dichloropropane ......................... . BDL 2
cis-1,3-Dichloropropene ..................... . BDL 2
trans-1,3-Dichloropropene ................... . BDL 2
Ethylbenzene ................................ . BDL 2
2 -Hexanone .................................. . BDL 50
BDL -Below Detection Limit
A Unit of American Analytical Services, Inc.
.. ,,
Conestoga-Rovers
Page 2 of 2
• •
January 22, 1998
Report No. 90698-4
Wastewater,, Jadco-Hughes, Project #3669, Trip Blank, 12/29/97,, received
01/10/98
RESULTS
Volatile Organics (EPA 624)
Methylene chloride .......................... .
1,1,2,2-Tetrachloroethane ................... .
Tetrachloroethene ........................... .
Toluene ..................................... .
1, 1, 1-Trichloroethane ....................... .
1,1,2-Trichloroethane ....................... .
Trichloroethene ............................. .
Vinyl chloride .............................. .
Xylenes ..................................... .
BDL -Below Detection Limit
North Carolina Laboratory I.D. No. 381
Result
(ug/1)
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
Detection
Limit
(ug/1)
10
2
2
2
2
2
2
10
2
Respectfully submitted, </t@-~
Quality Assurance
I• I' • •
Analytical Services Inc. Batch QC
For Report Number :90698
Acids
Page 1
Matrix : Aqueous Batch # 35326 Method : EPA 625
Lab Control Information LC LCD LC %Recovery RPD
Analyte %Rec %Rec RPD Range Range
4-Chloro-3-methylphenol 82 71 15 23 -97 0 -42
2-Chlorophenol 68 56 20 27 -123 0 -40
2,4-Dichlorophenol 86 72 18 39 -135 0 -40
2,4-Dimethylphenol 81 68 18 32 -119 0 -40
2,4-Dinitrophenol 44 39 13 10 -191 0 -50
4,6-Dinitro-2-methylphenol 60 80 28 10 -181 0 -93
2-Nitrophenol 77 67 14 19 -182 0 -40
4-Nitrophenol 28 32 13 10 -80 0 -50
Pentachlorophenol 58 77 27 9 -103 0 -50
Phenol 34 29 18 12 -89 0 -42
2,4,6-Trichlorophenol 78 70 11 37 -144 0 -40
Matrix Spike Information MS MSD MS %Recovery RPD
Analyte %Rec %Rec RPD Range Range
4-Chloro-3-methylphenol 87 80 7 23 -97 0 -42
2-Chlorophenol 69 65 6 27 -123 0 -40
2,4-Dichlorophenol 103 100 3 39 -135 0 -40
2,4-Dimethylphenol 58 59 2 32 -119 0 -40
2,4-Dinitrophenol 16 11 41 10 -191 0 -50
4,6-Dinitro-2-methylphenol 11 27 80 10 -181 0 -93
2-Nitrophenol 51 58 12 19 -182 0 -40
4-Nitrophenol 52 52 1 10 -80 0 -50
Pentachlorophenol 73 66 10 9 -103 0 -50
Phenol 59 58 2 12 -89 0 -42
2,4,6-Trichlorophenol 80 76 5 37 -144 0 -40
,, ,. • • Page 2
Analytical Services Inc. Batch QC
Surrogate Recovery
Acids
Matrix Aqueous Batch# 35326 Method EPA 625
% Recovery Objectives
81 2-Fluorophenol 21 -100
82 Phenol-d5 10 -94
Sample File 81 82 83 84 85 86
35326BLK B3235 58 39
35326LCS B3236 50 31
35326LCSD B3237 39 27
90524-2 A7395 47 49
90526-1 A7396 46 48
90526-lMS A7397 56 65
90526-lMSD A7398 53 64
90548 A7399 47 52
90524-2D A7406 56 60
.,.. ..... Note: 1:10
90646 A7459
.......... Note: MATRIX EFFECT
' 90666 A7460 42 32
90559 A7461 44 47
.......... Note: SAME AS 90628
90633-1 A7462 54 57
90646D A7463
.......... Note: l:l0;MATRIX EFFECT
90666D A7468 50 25
AANote: 1:10
90790-1 A7483 40 28
90795-1 A7484 38 28
90796-1 A7485 43 30
90786 A7486 31 22
90698-2 A7487 45 31
90698-2DUP A7488 44 31
90816 A7518 40 28
I' •
Q.C. Information for Batch# 35326
• Page 3
Printed: 01/22/98 18:19:21
Blank Results Information
Acids Method: EPA 625
Analyte
Benzoic Acid
4-Chloro-3-methylphenol
2-Chlorophenol
2,4-Dichlorophenol
2,4-Dimethylphenol
2,4-Dinitrophenol
4,6-Dinitro-2-methylphenol
2-Methylphenol
4-Methylphenol
2-Nitrophenol
4-Nitrophenol
Pentachlorophenol
Phenol
2,4,6-Trichlorophenol
2,4,5-Trichlorophenol
Blank
Result
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
Detection
Limit
50
10
10
10
10
50
50
10
10
50
50
20
10
10
10
'' '' • • Page 4
Q.C. Information for Batch# 35326 Printed: 01/22/98 18:19:21
Sample Batch Information
Acids Method : EPA 625
Preparation Preparation Analysis
Sample ID Date Time By Notes Date Time By Inst #
35326BLK 01/07/98 0830 TB 01/07/98 1745 TAS 5971
35326LCS 01/07/98 0830 TB 01/07/98 1819 TAS 5971
35326LCSD 01/07/98 0830 TB 01/07/98 1853 TAS 5971
90524-2 01/08/97 0830 TB/JW 01/08/98 1924 TAS BNAl
90526-1 01/08/97 0830 TB/JW 01/08/98 1957 TAS BNAl
90526-lMS 01/08/97 0830 TB/JW 01/08/98 2030 TAS BNAl
90526-lMSD 01/08/97 0830 TB/JW 01/08/98 2102 TAS BNAl
90548 01/08/97 0830 TB/JW 01/08/98 2136 TAS BNAl
90524-2D I I 01/09/98 0720 TAS BNAl
90646 01/12/98 0900 JW 01/13/98 1552 TAS 5970
90666 01/12/98 0900 JW 01/13/98 0424 TAS 5970
90559 01/12/98 0900 JW 01/13/98 0456 TAS 5970
90633-1 01/12/98 0900 JW 01/13/98 0528 TAS 5970
90628 01/12/98 0900 JW SAME AS 90559 I I
90698-2 01/14/98 1530 JW 01/15/98 1945 TAS 5970
90698-2DUP 01/14/98 1530 JW 01/15/98 2019 TAS 5970
90646D I I 01/13/98.0600 TAS 5970
90666D I I 01/13/98 0845 TAS 5970
90790-1 01/15/98 1000 TB/JW 01/15/98 1728 TAS 5970
90795-1 01/15/98 1000 TB/JW 01/15/98 1803 TAS 5970
90796-1 01/15/98 1000 TB/JW 01/15/98 1837 TAS 5970
90786 01/15/98 1000 TB/JW 01/15/98 1911 TAS 5970
90816 01/16/98 0800 TB 01/17/98 0219 TAS 5970
'' '' • • Page 5
Analytical Services Inc. Batch QC
For Report Number :90698
Base Neutrals
Matrix : Aqueous Batch # 35327 Method : EPA 625
Lab Control Information LC LCD LC %Recovery RPD
Analyte %Rec %Rec RPD Range Range
Acenaphthene 77 105 31 46 -118 0 -31
Acenaphthylene 76 97 25 33 -145 0 -40
Anthracene 93 117 23 27 -133 0 -40
Benzidine. 179 187 4 10 -200 0 -100
Benzo(a)anthracene 89 110 21 33 -143 0 -40
Benzo(b)fluoranthene 86 126 38 24 -159 0 -40
Benzo(k)fluoranthene 96 105 8 11 -162 0 -42
Benzo(a)pyrene 94 122 26 17 -163 0 -40
Benzo(ghi)perylene 117 149 24 10 -219 0 -56
Benzyl butyl phthalate 76 91 18 10 -152 0 -40
Bis(2-chloroethyl)ether 54 78 37 10 -150 0 -50
Bis(2-chloroethoxy)methane 74 105 34 33 -184 0 -43
Bis(2-ethylhexyl)phthalate 79 97 20 10 -158 0 -40
Bis(2-chloroisopropyl)ether 69 99 35 36 -166 0 -46
4-Bromophenyl phenyl ether 98 120 20 53 -127 0 -40
2-Chloronaphthalene 82 108 27 60 -118 0 -40
4-Chlorophenyl phenyl ether 85 115 30 28 -158 0 -33
Chrysene 89 110 21 17 -168 0 -48
Dibenzo(a,h)anthracene 121 156 26 10 -227 0 -70
Di-n-butylphthalate 83 107 25 10 -118 0 -50
1,3-Dichlorobenzene 56 79 33 10 -172 0 -40
1,2-Dichlorobenzene 62 88 34 32 -129 0 -40
1,4-Dichlorobenzene 93 83 12 36 -97 0 -28
3,3'-Dichlorobenzidine 110 143 26 10 -262 0 -100
Diethylphthalate 60 63 4 10 -114 0 -40
Dimethylphthalate 12 17 29 0 -110 0 -40
2,4-Dinitrotoluene 83 92 10 24 -96 0 -38
2,6-Dinitrotoluene 84 107 24 50 -158 0 -40
Di-n-octylphthalate 73 99 30 10 -146 0 -50
Fluoranthene 95 123 25 26 -137 0 -40
Fluorene 77 106 32 59 -129 0 -40
Hexachlorobenzene 106 130 20 10 -152 0 -40
Hexachlorobutadiene 78 104 28 24 -116 0 -40
Hexachloroethane 72 82 12 40 -113 0 -40
Indeno(l,2,3-cd)pyrene 116 149 25 10 -171 0 -45
Isophorone 72 101 34 21 -196 0 -60
Naphthalene 79 110 32 21 -133 0 -40
Nitrobenzene 72 105 38 35 -180 0 -40
N-Nitrosodi-n-propylamine 84 103 20 41 -116 0 -38
Phenanthrene 92 118 25 54 -120 0 -40
Pyrene 89 107 19 26 -127 0 -31
1,2,4-Trichlorobenzene 80 100 22 44 -142 0 -28
'' ,, • • Page 6
Analytical Services Inc. Batch QC
Base Neutrals
Matrix : Aqueous Batch # 35327 Method : EPA 625
Matrix Spike Information MS MSD MS %-Recovery RPD
Analyte %Rec %Rec RPD Range Range
Acenaphthene 73 76 4 46 -118 0 -31
Acenaphthylene 72 76 6 33 -145 0 -40
Anthracene 74 74 0 27 -133 0 -40
Benzi dine 0 0 NC 10 -200 0 -100
Benzo(a)anthracene 100 110 10 33 -143 0 -40
Benzo(b)fluoranthene 81 88 8 24 -159 0 -79
Benzo(k)fluoranthene 63 61 3 11 -162 0 -42
Benzo(a)pyrene 70 75 6 17 -163 0 -40
Benzo(ghi)perylene 54 56 4 10 -219 0 -56
Benzyl butyl phthalate 62 66 6 10 -152 0 -40
Bis(2-chloroethyl)ether 59 66 11 10 -150 0 -50
Bis(2-chloroethoxy)methane 81 89 9 33 -184 0 -43
Bis(2-ethylhexyl)phthalate 76 78 2 10 -158 0 -40
Bis(2-chloroisopropyl)ether 94 106 12 36 -166 0 -46
4-Bromophenyl phenyl ether Bl 83 2 53 -127 0 -40
2-Chloronaphthalene 66 68 4 60 -118 0 -40
4-Chlorophenyl phenyl ether 93 88 5 28 -158 0 -33
Chrysene 66 72 B 17 -168 0 -48
Dibenzo(a,h)anthracene 62 64 2 10 -227 0 -70
Di-n-butylphthalate 70 69 1 10 -118 0 -50
1,3-Dichlorobenzene 58 61 6 10 -172 0 -40
1,2-Dichlorobenzene 82 88 7 32 -129 0 -40
1,4-Dichlorobenzene 48 50 4 36 -97 0 -28
3,3'-Dichlorobenzidine 0 0 NC 10 -262 0 -100
Diethylphthalate 49 50 3 10 -114 0 -40
Dimethylphthalate 17 22 23 0 -110 0 -40
2,4-Dinitrotoluene 58 52 10 24 -96 0 -38
2,6-Dinitrotoluene 64 65 1 50 -158 0 -40
Di-n-octylphthalate 77 76 1 10 -146 0 -50
Fluoranthene 67 66 1 26 -137 0 -40
Fluorene 75 79 4 59 -121 0 -40
Hexachlorobenzene 85 91 6 10 -152 0 -40
Hexachlorobutadiene 99 108 9 24 -116 0 -40
Hexachloroethane 64 69 B 40 -113 0 -40
Indeno(l,2,3-cd)pyrene 60 64 6 10 -171 0 -45
Isophorone 65 76 16 21 -196 0 -60
Naphthalene 94 97 4 21 -133 0 -40
Nitrobenzene 73 85 14 35 -180 0 -40
N-Nitrosodi-n-propylamine 62 67 8 41 -116 0 -38
Phenanthrene 86 BO 7 54 -120 0 -40
Pyrene 63 64 1 26 -127 0 -31
1,2,4-Trichlorobenzene 94 104 11 44 -142 0 -28
NC~ Not Calculated
. ' '' • •
Analytical Services Inc. Batch QC
Surrogate Recovery
Base Neutrals
Matrix Aqueous Batch# 35327 Method
% Recovery Objectives
81 Nitrobenzene-d5 35 -114
Sample File 81 82 S3 S4
35327BLK B3238 83
35327LCS B3239 78
35327LCSD B3240 110
90505-2 B3241 91
90500-1 B3242 79
90505-2D B3243
AANote: l:l00;SURR. DILUTED OUT
90524-2 A7400 170
AANote: MATRIX EFFECT
90526-1 A7401 121
......... Note: MATRIX EFFECT
90526-lMS A7402 73
90526-lMSD A7403 88
90548 A7404 78
90523-2 A7405 62
90524-2D A7407 142
AANote: 1:10 MATRIX EFFECT
90524-2DD A74087
........ Note: 1:100 SURR. DILUTED OUT
90646 A7464
AANote: FV=5ML;MATRIX EFFECT
90666 A7465 80
90559 A7466 52
AANote: SAME AS 90628
90633-1 A7467 58
90666D A7469 38
AANote: 1:10
90790-1 A7489 52
90795-1 A7490 61
90796-1 A7491 55
90791-2 A7492 39
90786 A7493 60
Page 7
EPA 625
S5 S6
'' • •
Analytical Services Inc. Batch QC
Surrogate Recovery
Base Neutrals
Matrix Aqueous Batch# 35327 Method
Sample
90698-2
90698-2DUP
90816
Sl
File
A7494
A7495
A7519
% Recovery Objectives
Nitrobenzene-d5
Sl
76
68
60
S2
35 -114
S3 S4
Page 8
EPA 625
S5 S6
' ' •
Q.C. Information for Batch# 35327
• Page 9
Printed: 01/22/98 18:19:23
Blank Results Information
Base Neutrals Method: EPA 625
Analyte
Acenaphthene
Acenaphthylene
Anthracene
Benzo
Benzyl butyl phthalate
Bis
4-Bromophenyl phenyl ether
4-Chloroaniline
2-Chloronaphthalene
4-Chlorophenyl phenyl ether
Chrysene
Dibenzo
Dibenzofuran
Di-n-butylphthalate
1,3-Dichlorobenzene
1,2-Dichlorobenzene
1,4-Dichlorobenzene
3,3'-Dichlorobenzidine
Diethylphthalate
Dimethylphthalate
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Di-n-octylphthalate
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadiene
Hexachloroethane
Indeno
Isophorone
2-Methylnaphthalene
Naphthalene
2-Nitroaniline
3-Nitroaniline
4-Nitroaniline
Nitrobenzene
N-Nitrosodiphenylamine
N-Nitrosodi-n-propylamine
Phenanthrene
Pyrene
1,2,4-Trichlorobenzene
Blank
Result
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
Detection
Limit
10
10
10
10
10
10
10
20
10
10
10
10
10
10
10
10
10
20
10
10
20
20
10
10
10
10
10
10
2
10
10
10
10
50
50
50
10
10
10
10
10
10
• • Page 10
Q.C. Information for Batch# 35327 Printed: 01/22/98 18:19:23
Sample Batch Information
Base Neutrals Method : EPA 625
Preparation Preparation Analysis
Sample ID Date Time By Notes Date Time By Inst #
90505-2 01/07/98 0830 TB BN ONLY 01/08/98 0730 TAS 5971
90500-1 01/07/98 0830 TB BN ONLY 01/08/98 0803 TAS 5971
35327BLK 01/07/98 0830 TB 01/07/98 1926 TAS 5971
35327LCS 01/07/98 0830 TB 01/07/98 2000 TAS 5971
35327LCSD 01/07/98 0830 TB 01/08/98 0657 TAS 5971
90524-2 01/08/97 0830 TB 01/08/98 2208 TAS BNAl
90526-1 01/08/97 0830 TB 01/08/98 2242 TAS BNAl
90526-lMS 01/08/97 0830 TB 01/08/98 2315 TAS BNAl
90526-lMSD 01/08/97 0830 TB 01/08/98 2348 TAS BNAl
90548 01/08/97 0830 TB 01/09/98 0021 TAS BNAl
90523-2 01/08/97 0830 TB BN ONLY 01/09/98 0054 TAS BNAl
90505-2D I I 01/08/98 0849 TAS 5971
90524-2D I I 01/09/98 0753 TAS 5970B
90524-2DD I I 01/09/98 0854 TAS 5970
90646· 01/12/98 0900 JW 01/13/98 0632 TAS 5970
90666 01/12/98 0900 JW 01/13/98 0703 TAS 5970
90559 01/12/98 0900 JW 01/13/98 0735 TAS 5970
90633-1 01/12/98 0900 JW 01/13/98 0807 TAS 5970
90628 01/12/98 0900 JW SAME AS 90559 I I
90698-2 01/14/98 1530 JW 01/15/98 2344 TAS 5970
90698-2DUP 01/14/98 1530 JW 01/15/98 0018 TAS 5970
90666D I I 01/13/98 0917 TAS 5970
90790-1 01/15/98 1000 TB/JW 01/15/98 2053 TAS 5970
90791-2 01/15/98 1000 TB/JW BN ONLY 01/15/98 2236 TAS 5970
90795-1 01/15/98 1000 TB/JW 01/15/98 2127 TAS 5970
90796-1 01/15/98 1000 TB/JW 01/15/98 2201 TAS 5970
90786 01/15/98 1000 TB/JW 01/15/98 2310 TAS 5970
90816 01/16/98 0800 TB 01/17/98 0253 TAS 5970
.. • •
Analytical Services Inc. Batch QC
For Report Number :90698
Organochlorine Pesticides
Page 11
Matrix : Aqueous Batch # 35501 Method : EPA 8080 I 608
Lab Control Information LC LCD LC %Recovery RPD
Analyte %Rec %Rec RPD Range Range
BHC-gamma (Lindane) 82 94 14 32 -127 0 -40
Heptachlor 80 92 14 34 -111 0 -40
Aldrin 87 97 11 42 -122 0 -40
Dieldrin 89 100 12 36 -146 0 -40
Endrin 83 96 15 30 -147 0 -40
4,4'-DDT 60 71 17 25 -160 0 -40
Matrix Spike Information MS MSD MS %Recovery RPD
Analyte %Rec %Rec RPD Range Range
BHC-gamma (Lindane) 77 95 21 32 -127 0 -40
Heptachlor 76 94 21 34 -111 0 -40
Aldrin 81 99 20 42 -122 0 -40
Dieldrin 82 102 22 36 -146 0 -40
Endrin 77 96 22 30 -147 0 -40
4, 4' -DDT 58 73 23 25 -160 0 -40
'. • • Page 12
Analytical Services Inc. Batch QC
Surrogate Recovery
Organochlorine Pesticides
Matrix Aqueous Batch# 35501 Method EPA 8080 / 608
% Recovery Objectives
Sl Dibutylchlorendate 14 -161
S2 Tetrachloro-m-xylene 47 -113
S3 Decachlorobiphenyl 10 -139
Sample File Sl S2 S3 S4 S5 S6
35501BLK 010998012F 108 97 108
35501LCS 010998013F 106 101 123
35501LCSD 010998014F 116 92 136
90577-1 010998015F 113 90 114
90577-lDUP 010998016F 107 89 111
90577-2 010998017F 99 89 132
90577-2MS 010998018F 96 101 126
90577-2MSD 010998019F 117 95 133
90620 010998020F 114 78 88
90662-1 011298017F 94 104
AANote: PCB ONLY
90662-2 011298018F 87 106
"'"'Note: PCB
90662-3 011298019F 86 122
AANote: PCB
90662-4 011298020F 78 96
........ Note: PCB
90666 011298020F 108 180 119
90559 011298021F 138 68 80
35501BLKPCB 011298016F 81 52
AANote: PCB
90633-1 011298023F
90628 011298021F 108 180 119
90690 011698016F 37 56 787
90790-1 011698049F 86 85 78
35501BLKPCB 011698050F 96 130
AANote: PCB ONLY
90633-lRR 011698061F 87 52 56
90698-2 011698053F 28 93 125
90698-2DUP 011698054F 28 97 140
90721 011698074F 49 94 135
90796-1 011698076F 102 84 134
Matrix
Sample
90795-1
• •
Analytical Services Inc. Batch QC
Surrogate Recovery
Organochlorine Pesticides
Aqueous Batch# 35501 Method
% Recovery Objectives
Sl Dibutylchlorendate 14 -
S2 Tetrachloro-m-xylene 47 -
S3 Decachlorobiphenyl 10 -
File Sl S2 S3 S4
011698077F 95 93 92
Page 13
EPA 8080 / 608
161
113
139
S5 S6
-. ' • • Page 14
Q.C. Information for Batch# 35501 Printed: 01/22/98 18:19:25
Blank Results Information
Organochlorine Pesticides Method : EPA 8080 I 608
Blank Detection
Analyte Result Limit
PCB 1016 BDL 1. 0
PCB 1221 BDL 1.0
PCB 1232 BDL 1.0
PCB 1242 BDL 1.0
PCB 1248 BDL 1.0
PCB 1254 BDL 1. 0
PCB 1260 BDL 1. 0
• • Page 15
Q.C. Information for Batch# 35501 Printed: 01/22/98 18:19:25
Sample Batch Information
Organochlorine Pesticides Method EPA 8080 I 608
Preparation Preparation Analysis
Sample ID Date Time By Notes Date Time By Inst #
90577-1 01/09/98 0730 TB/JW 01/09/98 1806 JQZ GC-3
90577-2 01/09/98 0730 TB/JW 01/09/98 1912 JQZ GC-3
90577-2MS 01/09/98 0730 TB/JW 01/09/98 1945 JQZ GC-3
90577-2MSD 01/09/98 0730 TB/JW 01/09/98 2018 JQZ GC-3
90577-lDUP 01/09/98 0730 TB/JW 01/09/98 1839 JQZ GC-3
35501BLK 01/09/98 0730 TB/JW 01/09/98 1627 JQZ GC-3
35501LCS 01/09/98 0730 TB/JW 01/09/98 1700 JQZ GC-3
35501LCSD 01/09/98 0730 TB/JW 01/09/98 1733 JQZ GC-3
90620 01/09/98 0730 TB/JW 01/09/98 2051 JQZ GC-3
90666 01/12/98 1400 TB/JW 01/13/98 0053 JQZ GC-3
90559 01/12/98 1400 TB/JW 01/13/98 0126 JQZ GC-3
90633-1 01/12/98 1400 TB/JW 01/13/98 0159 JQZ GC-3
90662-1 01/12/98 1400 TB/JW PCB ONLY 01/12/98 2242 JQZ GC-3
90662-2 01/12/98 1400 TB/JW PCB ONLY 01/12/98 2314 JQZ GC-3
90662-3 01/12/98 1400 TB/JW PCB ONLY 01/12/98 2347 JQZ GC-3
90662-4 01/12/98 1400 TB/JW PCB ONLY 01/13/98 0020 JQZ GC-3
35501BLKPCB 01/12/98 1400 TB/JW PCB ONLY 01/17/98 1019 JQZ GC-3
90.628 01/12/98 1400 TB/JW SAME AS 90559 01/13/98 0126 JQZ GC-3
90690 01/13/98 0900 JW 01/16/98 1540 JQZ GC-3
90721 01/13/98 0900 JW 01/17/98 2329 JQZ GC-3
90698-2 01/14/98 1530 JW 01/17/98 1230 JQZ GC-3
90698-2DUP 01/14/98 1530 JW 01/17/98 1230 JQZ GC-3
90633-lRR 01/14/98 1530 JW 01/17/98 1621 JQZ GC-3
90790-1 01/15/98 1000 TB/JW 01/17/98 0946 JQZ GC-3
90795-1 01/15/98 1000 TB/JW 01/18/98 0100 JQZ GC-3
90796-1 01/15/98 1000 TB/JW 01/18/98 0035 JQZ GC-3
,, • • Page 16
Analytical Services Inc. Batch QC
For Report Number :90698
Volatile Organics
Matrix : Aqueous Batch # 35648 Method : EPA 624
Lab Control Information LC LCD LC %Recovery RPD
Analyte %Rec %Rec RPD Range Range
Benzene 100 105 5 37 -151 0 -20
Bromodichloromethane 96 105 9 35 -155 0 -20
Bromoform 101 108 7 45 -169 0 -20
Bromomethane 113 117 4 D -242 0 -20
Carbon tetrachloride 96 101 5 70 -140 0 -20
Chlorobenzene 98 105 7 37 -160 0 -20
Chloroethane 97 102 4 14 -230 0 -20
2-Chloroethylvinyl ether 112 118 5 D -305 0 -20
Chloroform 96 101 5 51 -138 0 -20
Chloromethane 86 91 6 D -273 0 -20
Dibromochloromethane 101 111 9 53 -149 0 -20
1,2-Dichlorobenzene 91 99 8 18 -190 0 -20
1,3-Dichlorobenzene 101 106 6 59 -156 0 -20
1,4-Dichlorobenzene 95 103 8 18 -190 0 -20
1,1-Dichloroethane 101 105 4 59 -155 0 -20
1,2-Dichloroethane 97 104 7 49 -155 0 -20
1,1-Dichloroethene 110 106 4 D -234 0 -20
trans-1,2-Dichloroethene 96 101 5 54 -156 0 -20
1,2-Dichloropropane 103 109 6 D -210 0 -20
cis-1,3-Dichloropropene 98 106 8 D -227 0 -20
trans-1,3-Dichloropropene 97 105 9 17 -183 0 -20
Ethylbenzene 99 104 5 37 -162 0 -20
Methylene chloride 102 112 9 D -221 0 -20
1,1,2,2-Tetrachloroethane 104 109 5 46 -157 0 -20
Tetrachloroethene 99 102 4 64 -148 0 -20
Toluene 97 106 9 47 -150 0 -20
1,1,1-Trichloroethane 94 101 7 52 -162 0 -20
1,1,2-Trichloroethane 101 110 8 52 -150 0 -20
Trichloroethene 86 94 8 71 -157 0 -20
Trichlorofluoromethane 113 117 4 17 -181 0 -20
Vinyl chloride 92 91 0 D -251 0 -20
" •' • • Page 17
Analytical Services Inc. Batch QC
Volatile Organics
Matrix : Aqueous Batch # 35648 Method : EPA 624
Matrix Spike Information MS MSD MS %Recovery RPD
Analyte %Rec %Rec RPD Range Range
Benzene 106 101 4 37 -151 0 -20
Bromodichloromethane 98 97 1 35 -155 0 -20
Bromoform 100 99 1 45 -169 0 -20
Bromomethane 116 113 3 D -242 0 -20
Carbon tetrachloride 99 99 0 70 -140 0 -20
Chlorobenzene 102 100 2 37 -160 0 -20
Chloroethane 102 100 3 14 -230 0 -20
2-Chloroethylvinyl ether 93 86 7 D -305 0 -20
Chloroform 96 72 29 51 -138 0 -20
Chloromethane 94 87 9 D -273 0 -20
Dibromochloromethane 101 104 2 53 -149 0 -20
1,2-Dichlorobenzene 95 93 2 18 -190 0 -20
1,3-Dichlorobenzene 107 100 6 59 -156 0 -20
1,4-Dichlorobenzene 99 98 1 18 -190 0 -20
1,1-Dichloroethane 110 105 5 59 -155 0 -20
1,2-Dichloroethane 125 120 3 49 -155 0 -20
1,1-Dichloroethene 114 108 6 D -234 0 -20
trans-1,2-Dichloroethene 105 100 5 54 -156 0 -20
1,2-Dichloropropane 109 104 4 D -210 0 -20
cis-1,3-Dichloropropene 101 100 1 D -227 0 -20'
trans-1,3-Dichloropropene 99 99 1 17 -183 0 -20
Ethylbenzene 104 100 4 37 -162 0 -20
Methylene chloride 119 114 4 D -221 0 -20
1,1,2,2-Tetrachloroethane 106 101 5 46 -157 0 -20
Tetrachloroethene 102 102 0 64 -148 0 -20
Toluene 104 101 2 47 -150 0 -20
1,1,1-Trichloroethane 99 95 5 52 -162 0 -20
1,1,2-Trichloroethane 104 102 2 52 -150 0 -20
Trichloroethene 117 114 3 71 -157 0 -20
Trichlorofluoromethane 116 117 1 17 -181 0 -20
Vinyl chloride 96 91 6 D -251 0 -20
.i •• • • Page 18
Analytical Services Inc. Batch QC
Surrogate Recovery
Volatile Organics
Matrix Aqueous Batch# 35648 Method EPA 624
% Recovery Objectives
Sl 1,2-Dichloroethane-d4 76 -119
S2 Toluene-dB 88 -110
S3 Ethylbenzene-dl0 75 -115
S4 4-Bromofluorobenzene 86 -115
Sample File Sl S2 S3 S4 S5 S6
35648LCS C0876 96 98 97 93
35648LCSD C0877 95 97 96 92
35648BLK C0852 94 98 100 93
90698-2 C0871 97 99 97 90
90698-2MS C0872 94 98 98 94
90698-2MSD C0873 93 98 97 92
90698-2DUP C0874 92 98 97 92
90698-3 C0875 95 97 96 92
90698-4 C0878 91 93 91 86
90931-1 C0897 96 98 97 91
90931-2 C0898 96 96 95 91
90838-1 C0899 95 97 95 92
90795-2 C0900 96 98 96 92
90790-2 C0901 95 97 96 93
90817-1 C0902 92 96 97 91
90721 C0903 92 98 96 90
90721D C0912 94 97 96 91
AANote: DF=5
90796-2 C0906 98 97 95 93
90786 C0907 94 97 96 90
90816 C0908 97 98 96 92
•
Q.C. Information for Batch# 35648
• Page 19
Printed: 01/22/98 18:19:27
Blank Results Information
Volatile Organics Method: EPA 624
Analyte
Acetone
Benzene
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Dibromochloromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethene
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethylbenzene
2-Hexanone
Methylene chloride
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Vinyl chloride
Xylenes
Blank
Result
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
Detection
Limit
100
2
10
10
10
100
5
2
10
5
2
10
10
2
2
2
2
2
2
2
2
50
10
2
2
2
2
2
2
10
2
. . " .. • • Page 20
Q.C. Information for Batch# 35648 Printed: 01/22/98 18:19:27
Sample Batch Information
Volatile Organics Method : EPA 624
Preparation Preparation Analysis
Sample ID Date Time By Notes Date Time By Inst #
35648LCS l I 01/18/98 2135 LLP VOA3
35648LCSD I I 01/18/98 2201 LLP VOA3
35648BLK I I 01/18/98 1026 LLP VOA3
90698-2 I I 01/18/98 1923 LLP VOA3
90698-2MS I I 01/18/98 1950 LLP VOA3
90698-2MSD I I 01/18/98 2016 LLP VOA3
90698-2DUP I I 01/18/98 2042 LLP VOA3
90698-3 I I 01/18/98 2109 LLP VOA3
90698-4 I I 01/18/98 2274 LLP VOA3
90931-1 I I 01/19/98 1520 LLP VOA3
90931-2 I I 01/19/98 1547 LLP VOA3
90795-2 I I 01/19/98 1641 LLP VOA3
90790-2 I I 01/19/98 1708 LLP VOA3
90817-1 I I 01/19/98 1735 LLP VOA3
90721 I I 01/19/98 1801 LLP VOA3
90721D I I 01/19/98 0850 LLP VOA3
90796-2 I I 01/19/98 1920 LLP VOA3
90786 I I 01/19/98 1947 LLP VOA3
90816 I I 01/19/98 2013 LLP VOA3
90838-1 I I 01/19/98 1614 LLP VOA3
a, " •• • • Page 21
Analytical Services Inc. Batch QC
For Report Number :90698
QC Batch General Information
Batch Analysis Blank
Number Analyte Method Matrix Result
35533 CN EPA 335.2 Aqueous < 0.0200
35541 pH EPA 150.1 Aqueous 0.0000
35638 0/G EPA 1664 Aqueous 0.0000
,,..""Note BATCH PASSES ON ALL DATA. LACK OF SAMPLE FOR MSD.
Lab Control Information
Batch LC LCD LC %Recovery
Number Analyte Method %Rec %Rec RPO Range
35533 CN EPA 335.2 96 91 5 75 -125
35541 pH EPA 150.1 102 102 0 80 -120
35638 0/G EPA 1664 64 84 27 32 -103
Matrix Spike Information
Batch MS MSD MS %Recovery
Number Analyte Method %Rec %Rec RPO Range
35533 CN EPA 335.2 91 93 2 75 -125
35638 0/G EPA 1664 67 0 NC 32 -103
Unspiked Sample Duplicate Information
Batch Sample 1 Sample 2
Number Analyte Method RPO RPO
35533 CN EPA 335.2 0 0
35541 pH EPA 150.1 1
Prep.
Method
RPO
Range
0 -30
0 -20
0 -40
RPO
Range
0 -30
0 -40
RPO
Range
0 -30
0 -20
• • . ' .. • • Page 22
Q.C. Information for Batch# 35533 For Report Number :90698
Sample Batch Information
Analysis : CN
Preparation Preparation Analysis
Sample ID Tag Date Time By Notes Date Time By Inst
35533BLK 01/12/98 1100 ARS MIDI-DIST 01/12/98 1415 ARS GENES
35533LCS 01/12/98 1100 ARS MIDI-DIST 01/12/98 1415 ARS GENES
35533LCSD 01/12/98 1100 ARS MIDI-DIST 01/12/98 1415 ARS GENES
89710-lRRMS 01/12/98 1100 ARS MIDI-DIST 01/12/98 1415 ARS GENES
89710-lRRMSD 01/12/98 1100 ARS MIDI-DIST 01/12/98 1415 ARS GENES
89710-lRR 01/12/98 1100 ARS MIDI-DIST 01/12/98 1415 ARS GENES
90583-2 01/12/98 1100 ARS MIDI-DIST 01/12/98 1415 ARS GENES
90626 01/12/98 1100 ARS MIDI-DIST 01/12/98 1415 ARS GENES
90594 01/12/98 1100 ARS MIDI-DIST 01/12/98 1415 ARS GENES
90608 01/12/98 1345 ARS MIDI-DIST 01/12/98 1710 ARS GENES
35533CAL5 01/12/98 1345 ARS MIDI-DIST 01/12/98 1710 ARS GENES
35533CAL15 01/12/98 1345 ARS MIDI-DIST 01/12/98 1710 ARS GENES
90633-1 01/12/98 1345 ARS MIDI-DIST 01/12/98 1710 ARS GENES
90559 01/12/98 1345 ARS MIDI-DIST 01/12/98 1710 ARS GENES
90666 01/12/98 1345 ARS MIDI-DIST 01/12/98 1710 ARS GENES
90646 01/12/98 1345 ARS MIDI-DIST 01/12/98 1710 ARS GENES
90661-2 01/12/98 1345 ARS MIDI-DIST 01/12/98 1710 ARS GENES
90661-2DUP 01/12/98 1345 ARS MIDI-DIST 01/12/98 1710 ARS GENES
90646 01/12/98 1600 ARS MIDI-DIST 01/12/98 1815 ARS GENES
90650-2 01/12/98 1600 ARS MIDI-DIST 01/12/98 1815 ARS GENES
90653-1 01/12/98 1600 ARS MIDI-DIST 01/12/98 1815 ARS GENES
90698-2 01/12/98 1600 ARS MIDI-DIST 01/12/98 1815 ARS GENES
90698-2DUP 01/12/98 1600 ARS MIDI-DIST 01/12/98 1815 ARS GENES
90698-2MS 01/12/98 1600 ARS MIDI-DIST 01/12/98 1815 ARS GENES
90698-2MSD 01/12/98 1600 ARS MIDI-DIST 01/12/98 1815 ARS GENES
90685 01/12/98 1600 ARS MIDI-DIST 01/12/98 1815 ARS GENES
90694-5 01/12/98 1600 ARS MIDI-DIST 01/12/98 1815 ARS GENES
• •
Q.C. Information for Batch# 35541
Page 23
For Report Number :90698
Sample ID Tag
35541CALCHK
35541LCS
35541LCSD
90699
90699DUP
90711
90698-2
90716
90717
90718
90719
90722-1
90722-2
90722-3
Sample Batch Information
Analysis : pH
Preparation Preparation
Date Time By Notes
7 7
I I
I I
I I
I I
I I
I I
I I
I I
I I
I I
I I
I I
I I
Analysis
Date Time By
01/12/99 1800 JN
01/12/98 1800 JN
01/12/98 1800 JN
01/12/98 1800 JN
01/12/98 1800 JN
01/12/98 1800 JN
01/12/98 1800 JN
01/12/98 1800 JN
01/12/98 1800 JN
01/12/98 1800 JN
01/12/98 1800 JN
01/12/98 1800 JN
01/12/98 1800 JN
01/12/98 1800 JN
Inst
410A
410A
410A
410A
410A
410A
410A
410A
410A
410A
410A
410A
410A
410A
Sample ID
35638BLK
35638LCS
35638LCSD
90846
90694-2
90613
90713
90683-2
90698-2
90698-2MS
90846
90685
90678-1
• •
Q.C. Information for Batch# 35638
Page 24
For Report Number :90698
Sample Batch Information
Analysis : O/G
Preparation
Tag Date Time By
7 7
I I
I I
I I
I I
I I
I I
I I
I I
I I
I I
I I
I I
Preparation
Notes
SILICA GEL
Analysis
Date Time By
0l/16/98 1200 TD NK
01/16/98 1200 TD NK
01/16/98 1200 TD NK
01/16/98 1200 TD NK
01/16/98 1200 TD NK
01/16/98 1200 TD NK
01/16/98 1200 TD NK
01/16/98 1200 TD NK
01/16/98 1200 TD NK
01/16/98 1200 TD NK
01/16/98 1430 TD NK
01/16/98 1430 TD NK
01/16/98 1430 TD NK
Inst
CRA SHIPPED TO (Laboratory Name): A r'1 o-1 y h CG\ l Se.rv'i c..e::., I.-tc.. -• CONESTOGA-ROVERS & ASSOCIATES, INC. .
110 Te..:.1.-.vtol"".t/ ..p-,(,. k ...,o,,., /Jorcro.:;$, GA -::\Doq:z.. WOlt-9o&q9 . 1351 Oakbrook Drive Suite 150
Norcross, GA 30093 404-441-0027 REFERENCE NUMBER: . 1 PROJECT NAME: !
CHAIN OF CUSTODY RECORD .3'G:>"-9 J=.clco f-L..,0~es II )11<1-, /,~A~•, ""•
SAMPLER'S ~:/4Lif-,,:;?_. -RINTED W\ \ .e\ t-\ C
en -~L{j/J/IJ Cotct,~ ~ a: ... "' O,!; SIGNATURE: · ."{. . "" A NAME: lC. 'Cl.., ' Vvo di! ~~i:P/d<·t:; ft~Pt--!'1~7
REMARKS
SEO. .
SAMPLE zz e:M~ TIME SAMPLE NUMBER 0 NO. TYPE "' I ' 1f'=1i (1.00 w-3!olo9 -t-/lG -1tziSCJ8 -o8t./-A-,., lt../ ')(' y '>( )< 1--I" Cvo.."1 <;c..-~lR. ol.
2. 01 /os/1e, ['Ll'e) LU-3 66"1-W,.<:_ -I "189 8 -0 gs-I¼-;s >< G... ""'-k S.c-...~r.,~. .
3 ~,./V:"ttlf-:;.. -"Tr•,t:"J ~ ~c,,... ......... \<..._. It~ 3 y' P<c" ,claJ... i,_r /.c-.b Lf . ' .
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• •
ATTACHMENT B
LABO RA TORY AND DATA VALIDATION REPORTS
CAA 3669Town·103-TPs
CRA
1351 Oakbrook Drive
Suite #150
Norcross, Georgia 30093
. [phone]
•
TO: Jeanne Chew
FROM: Robert Brachowski/rb/25
• A-/SD
MEMO
REFERENCE NO: 3669
DATE: January 2, 1998
RE: Data Quality Assessment and Validation for Three Water Samples Collected
from the Jadco-Hughes Site in Belmont, North Carolina
(Lot # 89647)
The following details a data quality assessment and validation for results generated by
Analytical Services, Inc. (ASI) of Norcross, Georgia for three water samples collected
from the above-referenced Site. Sample collection was conducted on December 4, 1997.
The samples were selectively analyzed for volatile organic compounds (VOCs), base-
neutral and acid extractable organic compounds (BNA), polychlorinated biphenyls
(PCBs), cyanide, oil and grease (O&G), pH, target analyte list (TAL) metals, total
suspended solids (TSS), biological oxygen demand (BOD), and ammonia. The quality
assurance criteria were established by the associated quality assurance project plan and
the analytical methods1. The samples are identified in Table 1. The analytical
methodologies are listed in Table 2.
Holding Time Periods
The holding time periods are presented in Table 3. The pH analysis was performed
outside of the allowable holding time period; therefore, the data for sample W-3669-JU-
120497-081 should be qualified as estimated (J) for this parameter. The BOD analysis
was performed outside the allowable holding time period; therefore, the quantitation
limit for sample W-3669-JU-120497-083 should be qualified as estimated (UJ) for this
parameter. On the basis of the sample collection and analysis dates referenced on the
chain-of-custody forms and the analytical reports provided by ASI indicated that the
remainder of the extractions and analyses were performed within the required holding
time periods.
1 Application of quality assurance criteria was consistent with "National Functional Guidelines for
Organic Data Review," revised February 1994 and "National Functional Guidelines for Inorganic Data
Review," revised February 1994.
• •
January 2, 1998 Reference No. 3669
-2-
Method Blank Samples
Contamination of samples contributed by laboratory conditions or procedures was
monitored by the concurrent preparation and analysis of method blank samples. The
method blank samples were free from target analytes above the detection limits
indicating that no significant laboratory contamination occurred.
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD) Results
ASI provides and analyzes LCS/LCSD in order to further assess the method accuracy
and precision. The TAL metals LCS relative percent difference (RPD) data for lead were
outside the control limits; therefore, the quantitation limit for sample number W-3669-
JU-120497-083 should be qualified as estimated (UJ) for this analyte. The O&G LCS
RPD data were outside the control limits; therefore, the quantitation limit for sample W-
3669-JU-120497-081 should be qualified as estimated (UJ) for this parameter. The VOC
LCS RPD data for 1,3-dichlorobenzene were outside the control limits; however, no
sample qualification was necessary since this was a non-project specific analyte. The
remainder of the LCS/LCSD data were within the control limits indicating the method
achieved an adequate level of accuracy and precision.
Surrogate Compound Percent Recoveries (Surrogate Recoveries)
Individual sample performance for the VOC, BNA, and PCB parameters were
monitored by surrogate recoveries. The surrogate recoveries were within the control
limits for the reported analyses.
Matrix Spike/Matrix Spike Duplicate (MS/MSD) Percent Recoveries
To assess the long term accuracy and precision of the analytical method on various
matrices, MS/MSD percent recoveries and the RPD of the recoveries are determined.
Some TAL metals MS/MSD percent recovery data were outside the control limits;
however, no sample qualification was necessary. The remainder of the MS/MSD
percent recovery and RPD data were within the control limits indicating an adequate
level of accuracy and precision was achieved.
• •
January 2, 1998 Reference No. 3669
-3-
Trip Blank Analysis
Potential cross-contamination by diffusion of the target compounds through the septum
seal into the samples during shipment and storage was monitored by means of a trip
blank sample. The trip blank sample was free from detectable concentrations of target
analytes indicating that no significant cross-contamination occurred.
Overall Assessment
Violation of holding time and LCS criteria resulted in sample qualification as noted in
the previous text. The remainder of the data were found to exhibit acceptable levels of
accuracy and precision and may used without qualification.
• •
TABLEl
SUMMARY OF THE SAMPLE IDENTIFICATION NUMBERS
ASSOCIATED WITH THE SAMPLES COLLECTED FROM THE
JADCO-HUGHES SITE IN
BELMONT, NORTH CAROLINA
W-3669-JU-120497-081
W-3669-JU-120497-082
W-3669-JU-120497-083
• •
TABLE2
ANALYTICAL METHODS ASSOCIATED WITH THE
SAMPLES COLLECTED FROM THE JADCO-HUGHES SITE IN
BELMONT, NORTH CAROLINA
Parameters Methods
voe EPA I 624
BNA EPA 625
PCB EPA 608
Cyanide EPA 335.2
Oil and Grease EPA 1664
pH EPA 150.1
TALMetals EPA 200 (series)
TSS EPA 160.2
BOD EPA 405.1
Ammonia EPA 350.2
1 "Methods for Chemical Analysis of Water and Wastes," EPA 600/4-79-020, revised March 1983.
3669-M-25-TI
, •
TABLE3
HOLDING TIME PERIODS ASSOCIATED WITH THE SAMPLES
COLLECTED FROM THE JADCO-HUGHES SITE IN
BELMONT, NORTH CAROLINA
Parameters
VOC, Cyanide
BNA,PCB
pH
TAL Metals
(excluding mercury)
Holding Time Periods
· 14 days from sample collection to completion of analysis
• 7 days from sample collection to extraction
· 40 days from extraction to completion of analysis
· Analyze as soon as possible
• 6 months from sample collection to completion of analysis
Mercury, Oil and Grease, · 28 days from sample collection to completion of analysis
Ammonia
BOD -48 hours from sample collection to beginning of analysis
TSS • 7 days from sample collection to completion of analysis
3669·M-25-T3