NCD980729602_19971219_Jadco-Hughes_FRBCERCLA RA_Treated Water Effluent and Associated Data QA Validation - File 1 1997-OCR

ASI
•.
-~!,J.,,,:; .
•
ANALYTICAL SERVICES,
ENVIRONMENTAL MONITORING & LABORATORY ANALYSIS
110 TECHNOLOGY PARKWAY • NORCROSS, GA 30092
[phone] • FAX [phone]
19 December, 1997
L ..... .
Case Narrative Report 8964 7
The samples were collected on 4 December, 1997 and received by AS!
INC.
6 December, 1997. Conditions for proper sample receipt were met as indicated on the
Chain of Custody. The samples were logged into the LIMS as report 89647 for the
following analyses as per client request: PCB (EPA 608), BNA (EPA 625), VOA (EPA
624), Metals (EPA 200.7, 270.2, 239.2, 279.2, 245.1), BOD (EPA 405.1), CN (EPA
335.2), pH (EPA ISO.I), O/G (EPA 1664), NH3 (EPA 350.2) and TSS (EPA 160.2). All
holding times for sample preparation and analysis were met with exception of pH which
is best analyzed in the field, and BOD which is set on Wednesdays and Fridays while
these samples were received on a Saturday.
PCB analysis (EPA 608) met all data quality objectives.
BNA analysis (EPA 625) met all data quality objectives.
VOA analysis (EPA 624) gave high LCSRPD for 1,3-Dichlorobenzene and high
1,2-Dichloroethane-d4 for 89634-4MSD. All spike and surrogate recoveries were
acceptable.
Metals analysis (EPA 200.7) gave high blanks for Ca and Na which led to
elevated detecion limits for those elements. The recovery for MS was high for Na; PDS
was low for Ag, Al, Ba, Ca, Cd, Cu, Mg, Na, Ni and Zn. Se analysis (EPA 270.2) gave
high PDS. Pb analysis (EPA 239.2) gave high LCSRPD. Tl analysis (EPA 279.2) gave
low MS/MSD/PDS. All other quality controls were acceptable. Hg analysis (EPA 245.1)
met all data quality objectives.
BOD analysis (EPA 405.1) gave acceptable recoveries for all lab controls and
duplicates.
CN analysis (EPA 335.2) met all data quality objectives.
pH analysis (EPA 150.1) met all data quality objectives.
0/G analysis (EPA 1664) had insufficient sample for MSD and high LCSRPD.
The batch passes on individual lab control recoveries and the MS.
NH3 analysis (EPA 350.2) met all data quality objectives.
TSS analysis (EPA 160.2) met all data quality objectives.
0--~~
Julia E. Martin
Quality Assurance
L2,,, __ l-l-_fj __ _
lnHl:::'.:-. _//M, __ _
A Unit of American Analytical Services, Inc.
Rec'd. CRA
DEC 2 9 1997
, '
ASI ANALYTICAL SERVICES, INC.
ENVIRONMENTAL MONITORING & LABORATORY ANALYSIS
110 TECHNOLOGY PARKWAY • NORCROSS, GA 30092
[phone] • FAX [phone]
LABORATORY REPORT
Conestoga-Rovers February 12, 1998
1351 Oakbrook Drive
Suite 150
Norcross, GA 30093
Attention: Mr. Neil Pickard Report No. 89647-1
Sample Description
Water, composite, J2.dco-!c-lughes, Project #3663, W-3669-JU-120497-033,.
12/04/97, 13:30, received 12/08/97
RESULTS
Biochemical Oxygen Demand (BOD5 ) (mg/1)
(EPA 405 .1) ............................ .
Ammonia Nitrogen (N) (mg/1) (EPA 350.2) ....... .
Total Suspended Solids (mg/1) (EPA 160.2) .... .
Target Analyte List -Metals
Metals
Total Aluminum (Al) (EPA 200. 7) .............. .
Total Antimony (Sb) (EPA 200. 7) .............. .
Total Arsenic (As) (EPA 200. 7) ............... .
Total Barium (Ba) (EPA 200. 7) ................ .
Total Beryllium (Be) (EPA 200. 7) ............. .
Total Cadmium (Cd) (EPA 200. 7) ............... .
Total Calcium (Ca) (EPA 200. 7) ............... .
Total Chromium (Cr) (EPA 200. 7) .............. .
Total Cobalt (Co) (EPA 200. 7) ................ .
Total Copper (Cu) (EPA 200.7) ................ .
Total Iron (Fe) (EPA 200. 7) .................. .
Total Lead (Pb) (EPA 239.2) .................. .
BDL -Below Detection Limit
Result
BDL
BDL
BDL
(mg/1)
BDL
BDL.
BDL
0.05
BDL
BDL
45
BDL
BDL
BDL
BDL
BDL
A Unit of American Analytical Services, Inc.
Detection
Limit
5
0.1
5
(mg/1)
0.2
0.05
0.01
0.01
0.001
0.005
0.8
0.01
0.05
0.02
0.1
0.003
' '
Conestoga-Rovers
Page 2 of 2
• •
February 12, 1998
Report No. 89647-1
Water, composite, Jadco-Hughes, Project #3669, W-3669-JU-120497-083,
12/04/97, 13:30, received 12/08/97
RESULTS
Metals
Total Magnesium (Mg) (EPA 200. 7) ............. .
Total Manganese (Mn) (EPA 200. 7) ............. .
Total Mercury (Hg)(EPA 245.1) ............... .
Total Nickel (Ni) (EPA 200. 7) ................ .
Total Potassium (K) (EPA 200. 7) .............. .
Total Selenium {Se) (EPA 270.2) .............. .
Total Silver (Ag){EPA 200.7) ................ .
Total Sodium (Na) (EPA 200. 7) ................ .
Total Thallium {Tl) (EPA 279.2) .............. .
Total Zinc (Zn) (EPA 200. 7) .................. .
Total Vanadium (V} (EPA 200. 7) ............... .
BDL -Below Detection Limit
North Carolina Laboratory I.D. No. 381
Result
(mg/1)
13
BDL
BDL
BDL
3.2
BDL
BDL
9.9
BDL
BDL
BDL
Detection
Limit
(mg/1)
0.05
0.015
0.0002
0.02
0.2
0.005
0.01
0.1
0.002
0.02
0.02
Respectful~y-l!a.bmitted,
~au~ roject Manger Qe·~
.Quality Assurance
, '
ASI
• ANALYTICAL SERVICES, INC.
ENVIRONMENTAL MONITORING & LABORATORY ANALYSIS
110 TECHNOLOGY PARKWAY • NORCROSS, GA 30092
[phone] • FAA [phone]
LABORATORY REPORT
Conestoga-Rovers December 19, 1997
1351 Oakbrook Drive
Suite 150
Norcross, GA 30093
Attention: Mr. Neil Pickard Report No_ 89647-2
Sample Description
Water, grab, Jadco-Hughes, Project #3669, W-3669-JU-120497-081, 12/04/97,
13:45, received 12/08/97
RESULTS
Detection
Result Limit
pH (laboratory) (EPA 150 -l) ___ . ____ . ___ . _ .. __ _ 7.81
Total Cyanide (CN) (mg/1) (EPA 335.2) .. _. ___ .. _ BDL 0.01
Oil and Grease (mg/1) (EPA 1664) ___ . _. _. ____ . _ BDL 7
Volatile Organics (EPA 624) (ug/1) (ug/1 l
Acetone _______ - . - - -....... ______ . ____ ... ____ _ BDL 100 Benzene_ . _______ , . , .. _ .. , ........ ___ .... ____ _ BDL 2
Bromodichloromethane ............ ·----·· ·-----BDL 10
Bromoform ___ -. _ ..... _ ............. ____ ..... __ _ BDL 10 Bromomethane _ ... ______ . _ . _ ...... _________ .. __ BDL 10 2-Butanone ____ ... _ . _______ .. _ . ____________ .. __ BDL 100 Carbon disulfide. ___ . ___ . _ .. _. _. _________ .. __ BDL 5 Carbon tetrachloride. _____________ .. ______ .. _ BDL 2 Chlorobenzene _ . ---__ . __ . _____ . ____ . _______ .. _ BDL 10 Chloroethane __ . _________________ . ___ .. ____ .. _ BDL 5 Chloroform ___ .. _______ . ________ .. _ ..... ____ . _ 100 2 Chloromethane. ------_. _________ .. ____ .. _____ _ BDL 10 Dibromochloromethane __________ ... _____ .. ____ _ BDL 10 1, 1-Dichloroethane ____ .. ____ .. _ . _________ . __ _ BDL 2 1, 2-Dichloroethane ___ . _ ... ____ .. _______ . _ . __ _ 13 2 1,1-Dichloroethene __ ... _ .. _ ..... _________ ... _ BDL 2
1,2-Dichloroethene (total) .... -------------·-36 2
BDL -Below Detection Limit
A Unit of American Analytical Services, Inc.
Conestoga-Rovers
Page 2 of 4
•
December 19, 1997
Report No. 89647-2
Water, grab, Jadco-Hughes, Project #3669, W-3669-JU-120497-081, 12/04/97,
13:45, received 12/08/97
RESULTS
Detection
Result Limit
Volatile Organics (EPA 624) (ug/1) (ug/1)
1, 2 -Dichloropropane ......................... . BDL 2
cis-1, 3-Dichloropropene ..................... . BDL 2
trans-1,3-Dichloropropene ................... . BDL 2
Ethylbenzene ................................ . BDL 2
2-Hexanone .................................. . BDL 50
Methylene chloride .......................... . BDL 10
1, 1, 2, 2-Tetrachloroethane ........... · ........ . BDL 2
Tetrachloroethene ........................... . BDL 2
Toluene ..................................... . BDL 2
1,1,1-Trichloroethane ....................... . BDL 2
1, 1, 2-Trichloroethane ....................... . BDL 2
Trichloroethene ............................. . 13 2
Vinyl chloride .............................. . BDL 10
Xylenes ..................................... . BDL 2
Acid Extractable Organics (EPA 625) (ug/1) (ug/1)
Benzoic Acid ................................ . BDL 50
4-Chloro-3-methylphenol ..................... . BDL 10
2 -Chlorophenol. ............................. . BDL 10
2, 4-Dichlorophenol. ......................... . BDL 10
2, 4 -Dimethylphenol. ......................... . BDL 10
2, 4-Dinitrophenol. .......................... . BDL 50
4,6-Dinitro-2-methylphenol .................. . BDL 50
2 -Methyl phenol .............................. . BDL 10
4-Methylphenol .............................. . BDL 10
2-Nitrophenol. .............................. . BDL 50
4-Nitrophenol ............................... . BDL 50
Pentachlorophenol ........................... . BDL 20
Phenol ...................................... . BDL 10
2, 4, 6-Trichlorophenol ....................... . BDL 10
2,4,5-Trichlorophenol ....................... . BDL 10
BDL -Below Detection Limit
Conestoga-Rovers
Page 3 of 4
•
December 19, 1997
Report No. 89647-2
Water, grab, Jadco-Hughes, Project #3669, W-3669-JU-120497-081, 12/04/97,
13:45, received 12/08/97
RESULTS
Detection
Result Limit
Base/Neutral Extractable Organics (EPA 625) (ug/1) (ug/1)
Acenaphthene ................................ . BDL 10
Acenaphthylene .............................. . BDL 10
Anthracene .................................. . BDL 10
Benzo(a)anthracene .......................... . BDL 10
Benzo (b) fluoranthene ........................ . BDL 10
Benzo (k) fluoranthene ........................ . BDL 10
Benzo(a)pyrene .............................. . BDL 10
Benzo (ghi) perylene .......................... . BDL 10
Benzyl butyl phthalate ...................... . BDL 10
Bis(2-chloroethyl)ether ..................... . BDL 10
Bis(2-chloroethoxy)methane .................. . BDL 10
Bis(2-ethylhexyl)phthalate .................. . BDL 10
Bis(2-chloroisopropyl)ether ................. . BDL 10
4-Bromophenyl phenyl ether .................. . BDL 10
4 -Chloroaniline ............................. . BDL 20
2 -Chloronaphthalene ......................... . BDL 10
4-Chlorophenyl phenyl ether ................. . BDL 10
Chrysene .................................... . BDL 10
Dibenzo(a,h)anthracene ...................... . BDL 10
Dibenzofuran ................................ . BDL 10
Di-n-butylphthalate ......................... . BDL 10
1, 3-Dichlorobenzene ......................... . BDL 10
1, 2-Dichlorobenzene, ......................... . BDL 10
1, 4 -Dichlorobenzene ......................... . BDL 10
3, 3' -Dichlorobenzidine ...................... . BDL 20
Diethylphthalate ............................ . BDL 10
Dimethylphthalate ........................... . BDL 10
2, 4-Dinitrotoluene .......................... . BDL 20
2, 6 -Dini trotol uene .......................... . BDL 20
Di-n-octylphthalate ......................... . BDL 10
Fluoranthene ................................ . BDL 10
Fluorene .................................... . BDL 10
Hexachlorobenzene ........................... . BDL 10
Hexachlorobutadiene ......................... . BDL 10
Hexachlorocyclopentadiene ................... . BDL 10
Hexachloroethane ............................ . BDL 2
Indeno (1, 2, 3-cd) pyrene ...................... . BDL 10
Isophorone .................................. . BDL 10
BDL -Below Detection Limit
Conestoga-Rovers
Page 4 of 4
•
December 19, 1997
Report No. 89647-2
Water, grab, Jadco-Hughes, Project #3669, W-3669-JU-120497-081, 12/04/97,
13:45, received 12/08/97
RESULTS
Detection
Result Limit
Base/Neutral Extractable Organics (EPA 625) (ug/1) (ug/1)
2-Methylnaphthalene ......................... . BDL 10
Naphthalene ................................. . BDL 10
2-Nitroaniline .............................. . BDL 50
3-Nitroaniline .............................. . BDL 50
4-Nitroaniline .............................. . BDL 50
Ni trobenzene ................................ . BDL 10
N-Nitrosodiphenylamine ...................... . BDL 10
N-Nitrosodi-n-propylamine ................... . BDL 10
Phenanthrene ................................ . BDL 10
Pyrene ...................................... . BDL 10
1, 2, 4 -Trichlorobenzene ...................... . BDL 10
PCB' s (EPA 608) ( ug/1) (ug/1)
PCB 1016 .................................... . BDL 1.0
PCB 1221 .................................... . BDL 1.0
PCB 1232 .................................... . BDL 1.0
PCB 1242 .................................... . BDL 1.0
PCB 1248 .................................... . BDL 1. 0
PCB 1254 .................................... . BDL 1.0
PCB 1260 .................................... . BDL 1.0
BDL -Below Detection Limit
North Carolina Laboratory I.D. No. 381
roJ ect Man er
G~~~ Quality Assurance
ASI
• ANALYTICAL SERVICES, INC.
ENVIRONMENTAL MONITORING & LABORATORY ANALYSIS
110 TECHNOLOGY PARKWAY• NORCROSS, GA 30092
(770) 734·4200 • FAX (770) 734·4201
LABORATORY REPORT
Conestoga-Rovers December 19, 1997
1351 Oakbrook Drive
Suite 150
Norcross, GA 30093
Attention: Mr. Neil Pickard Report No. 89647-3
Sample Description
Water, grab, Jadco-Hughes, Project #3669, W-3669-JU-120497-082, 12/04/97,
13:15, received 12/08/97
RESULTS
Volatile Organics (EPA 624)
Acetone ..................................... .
Benzene ..................................... .
Bromodichloromethane ........................ .
Bromoform ................................... .
Bromomethane ................................ .
2-Butanone .................................. .
Carbon disulfide ............................ .
Carbon tetrachloride ........................ .
Chlorobenzene ............................... .
Chloroethane ................................ .
Chloroform .................................. .
Chloromethane ............................... .
Dibromochloromethane ........................ .
1,1-Dichloroethane .......................... .
1,2-Dichloroethane .......................... .
1, 1-Dichloroethene .......................... .
1, 2-Dichloroethene (total) .................. .
1, 2-Dichloropropane ......................... .
cis-1,3-Dichloropropene ..................... .
trans-1,3-Dichloropropene ................... .
Ethylbenzene ................................ .
2 -Hexanone .................................. .
BDL -Below Detection Limit
Result
(ug/1)
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
130
BDL
BDL
BDL
21
BDL
61
BDL
BDL
BDL
BDL
BDL
A Unit of American Analytical Services, Inc.
Detection
Limit
(ug/1)
100
2
10
10
10
100
5
2
10
5
2
10
10
2
2
2
2
2
2
2
2
50
' '
Conestoga-Rovers
Page 2 of 2
•
December 19, 1997
Report No. 89647-3
Water, grab, Jadco-Hughes, Project #3669, W-3669-JU-120497-082, 12/04/97,
13:15, received 12/08/97
RESULTS
Volatile Organics (EPA 624)
Methylene chloride .......................... .
1,1,2,2-Tetrachloroethane ................... .
Tetrachloroethene ........................... .
Toluene ..................................... .
1, 1, !-Trichloroethane ....................... .
1, 1, 2-Trichloroethane ....................... .
Trichloroethene ............................. .
Vinyl chloride .............................. .
Xylenes ..................................... .
BDL -Below Detection Limit
North Carolina Laboratory I.D. No. 381
Result
(ug/1)
BDL
BDL
3
2
BDL
BDL
27
BDL
BDL
Detection
Limit
(ug/1)
10
2
2
2
2
2
2
10
2
Respectfully submitted,
~-ffe!-/1½
Project Ma~ager
¼~i~-
ASI • ANALYTICAL SERVICES, INC.
ENVIRONMENTAL MONITORING & LABORATORY ANALYSIS
110 TECHNOLOGY PARKWAY• NORCROSS, GA30092
[phone] • FAX [phone]
LABORATORY REPORT
Conestoga-Rovers December 19, 1997
1351 Oakbrook Drive
Suite 150
Norcross, GA 30093
Attention: Mr. Neil Pickard Report No. 89647-4
Sample Description
Water, Jadco-Hughes, Project #3669, Trip Blank, 11/24/97, received 12/08/97
RESULTS
Detection
Result Limit
Volatile Organics (EPA 624) (ug/1) (ug/1)
Acetone ..................................... . BDL 100
Benzene ..................................... . BDL 2
Bromodichloromethane ........................ . BDL 10
Bromoform ................................... . BDL 10
Bromomethane ................................ . BDL 10
2-Butanone .................................. . BDL 100
Carbon disulfide ............................ . BDL 5
Carbon tetrachloride ........................ . BDL 2
Chlorobenzene ............................... . BDL 10
Chloroethane ................................ . BDL 5
Chloroform .................................. . BDL 2
Chloromethane ............................... . BDL 10
Dibromochloromethane ........................ . BDL 10
1, 1-Dichloroethane .......................... . BDL 2
1, 2-Dichloroethane .......................... . BDL 2
1, 1-Dichloroethene .......................... . BDL 2
1,2-Dichloroethene (total) .................. . BDL 2
1, 2-Dichloropropane ......................... . BDL 2
cis-1,3-Dichloropropene ..................... . BDL 2
trans-1,3-Dichloropropene ................... . BDL 2
Ethylbenzene ................................ . BDL 2
2 -Hexanone .................................. . BDL 50
Methylene chloride .......................... . BDL 10
BDL -Below Detection Limit
A Unit of American Analytical Services, Inc.
Conestoga-Rovers
Page 2 of 2
•
December 19, 1997
Report No. 89647-4
Water, Jadco-Hughes, Project #3669, Trip Blank, 11/24/97, received 12/08/97
RESULTS
Volatile Organics (EPA 624)
1,1,2,2-Tetrachloroethane ................... .
Tetrachloroethene ........................... .
Toluene ..................................... .
1, 1, 1-Trichloroethane ....................... .
1, 1, 2 -Trichloroethane ....................... .
Trichloroethene ............................. .
Vinyl chloride .............................. .
Xylenes ..................................... .
BDL -Below Detection Limit
North Carolina Laboratory I.D. No. 381
Result
(ug/1 l
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
Detection
Limit
(ug/1)
2
2
2
2
2
2
10
2
~~ 6uaiity Assurance
•
Analytical Services Inc. Batch QC
For Report Number :89647
Acids
Page 1
Matrix : Aqueous Batch # 34479 Method : EPA 625
Lab Control Information LC LCD LC %Recovery RPD
Analyte %Rec %Rec RPD Range Range
4-Chloro-3-methylphenol 75 80 7 23 -97 0 -42
2-Chlorophenol 57 70 19 27 -123 0 -40
2,4-Dichlorophenol 64 75 15 39 -135 0 -40
2,4-Dimethylphenol 69 80 15 32 -119 0 -40
2,4-Dinitrophenol 64 68 7 10 -191 0 -50
4,6-Dinitro-2-methylphenol 68 73 7 10 -181 0 -93
2-Nitrophenol 58 69 18 19 -182 0 -40
4-Nitrophenol 47 47 0 10 -80 0 -50
Pentachlorophenol 69 71 3 9 -103 0 -50
Phenol 28 33 15 12 -89 0 -42
2,4,6-Trichlorophenol 68 73 7 37 -144 0 -40
Matrix Spike Information MS MSD MS %Recovery RPD
Analyte %Rec %Rec RPD Range Range
4-Chloro-3-methylphenol 78 79 2 23 -97 0 -42
2-Chlorophenol 62 71 13 27 -123 0 -40
2,4-Dichlorophenol 66 74 11 39 -135 0 -40
2,4-Dimethylphenol 57 65 13 32 -119 0 -40
2,4-Dinitrophenol 92 58 45 10 -191 0 -50
4,6-Dinitro-2-methylphenol 74 65 12 10 -181 0 -93
2-Nitrophenol 69 70 2 19 -182 0 -40
4-Nitrophenol 78 68 13 10 -80 0 -50
Pentachlorophenol 66 55 18 9 -103 0 -50
Phenol 45 50 11 12 -89 0 -42
2,4,6-Trichlorophenol 67 72 8 37 -144 0 -40
• Page 2
Analytical Services Inc. Batch QC
Surrogate Recovery
Acids
Matrix Aqueous Batch# 34479 Method EPA 625
% Recovery Objectives
Sl 2-Fluorophenol 21 -100
S2 Phenol-d5 10 -94
Sample File Sl S2 S3 S4 S5 S6
34479BLK B2498 53 38
""ANote: AKA 89345-6
34479LCS B2500 45 31
34479LCSD B2501 55 37
89345-3 B2504 50 34
89345-3DUP B2505 47 32
89345-4 B2506 50 34
89345-4MS B2507 61 50
89345-4MSD B2508 67 55
89448 B2565 28 31
89539 B2598 42 60
89555-1 B2600 53 32
89593 B2667 29 35
89610-4 B2668 33 20
89534-1 B2669 48 30
89559-1 B2670 61 15
89593D B2702 31 40
AANote: 1:10
89604-2 B2704 38 28
89647-2 B2707 56 27
89632-1 B2713 48 34
89563-1 B2757 30 16
89616-3 B2758 58 34
89625-1 B2759 52 36
Q.C. Information for Batch# 34479
• Page 3
Printed: 12/19/97 19:13:08
Blank Results Information
Acids Method: EPA 625
Analyte
Benzoic Acid
4-Chloro-3-methylphenol
2 -Chlorophenol
2,4-Dichlorophenol
2,4-Dimethylphenol
2,4-Dinitrophenol
4,6-Dinitro-2-methylphenol
2-Methylphenol
4-Methylphenol
2-Nitrophenol
4-Nitrophenol
Pentachlorophenol
Phenol
2,4,6-Trichlorophenol
2,4,5-Trichlorophenol
Blank
Result
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
Detection
Limit
50
10
10
10
10
so
50
10
10
50
50
20
10
10
10
•
Page 4
Q.C. Information for Batch# 34479 Printed: 12/19/97 19:13:09
Sample Batch Information
Acids Method : EPA 625
Preparation Preparation Analysis
Sample ID Date Time By Notes Date Time By Inst #
89345-3 12/01/97 0900 JW 12/02/97 0107 TAS 5971
89345-4 12/01/97 0900 JW 12/02/97 0212 TAS 5971
89345-4MS 12/01/97 0900 JW 12/02/97 0245 TAS 5971
89345-4MSD 12/01/97 0900 JW 12/02/97 0317 TAS 5971
89345-3DUP 12/01/97 0900 JW 12/02/97 0140 TAS 5971
34479BLK 12/01/97 0900 JW 12/01/97 2152 TAS 5971
34479LCS 12/01/97 0900 JW 12/01/97 2257 TAS 5971
34479LCSD 12/01/97 0900 JW 12/01/97 2330 TAS 5971
89448 12/04/97 0900 JW 12/04/97 2037 TAS 5971
89539 12/05/97 0900 JW HEAVY EMULSION 12/07/97 2223 TAS 5971
89555-1 12/05/97 0900 JW 12/07/97 2328 TAS 5971
89593 12/07/97 0930 TB HEAVY EMULSION 12/10/97 1749 TAS 5971
89610-4 12/07/97 0930 TB EMULSION 12/10/97 1822 TAS 5971
89534-1 12/07/97 0930 TB 12/10/97 1856 TAS 5971
89559-1 12/07/97 0930 TB HEAVY EMULSION 12/10/97 1929 TAS 5971
89563-1 12/07/97 0930 TB EMULSION 12/14/97 0220 TAS 5971
89625-1 12/07/97 0930 TB 12/14/97 0326 TAS 5971
89604-2 12/07/97 0930 TB ACID ONLY 12/12/97 0107 TAS 5971
89616-3 12/07/97 0930 TB EMULSION 12/14/97 0253 TAS 5971
89632-1 12/09/97 0830 JW/TB 12/11/97 0555 TAS 5971
89647-2 12/09/97 0830 JW/TB 12/12/97 0243 TAS 5971
89593D I I 12/12/97 0003 TAS 5971
• • Page 5
Analytical Services Inc. Batch QC
For Report Number :89647
Base Neutrals
Matrix : Aqueous Batch # 34480 Method : EPA 625
Lab Control Information LC LCD LC %Recovery RPD
Analyte %Rec %Rec RPD Range Range
Acenaphthene 86 82 5 46 -118 0 -31
Acenaphthylene 85 81 5 33 -145 0 -40
Anthracene 90 88 2 27 -133 0 -40
Benzidine 138 133 4 10 -200 0 -100
Benzo(a)anthracene 88 84 5 33 -143 0 -40
Benzo(b)fluoranthene 77 76 0 24 -159 0 -40
Benzo(k)fluoranthene 115 110 4 11 -162 0 -42
Benzo(a)pyrene 88 85 4 17 -163 0 -40
Benzo(ghi)perylene 87 78 11 10 -219 0 -56
Benzyl butyl phthalate 81 78 4 10 -152 0 -40
Bis(2-chloroethyl)ether 59 54 9 10 -150 0 -50
Bis(2-chloroethoxy)methane 77 71 8 33 -184 0 -43
Bis(2-ethylhexyl)phthalate 94 89 6 10 -158 0 -40
Bis(2-chloroisopropyl)ether 65 51 23 36 -166 0 -46
4-Bromophenyl phenyl ether 91 84 7 53 -127 0 -40
2-Chloronaphthalene 78 74 6 60 -118 0 -40
4-Chlorophenyl phenyl ether 90 86 5 28 -158 0 -33
Chrysene 90 85 6 17 -168 0 -48
Dibenzo(a,h)anthracene 87 79 10 10 -227 0 -70
Di-n-butylphthalate 93 86 8 10 -118 0 -50
1,3-Dichlorobenzene 51 46 10 10 -172 0 -40
1,2-Dichlorobenzene 56 51 9 32 -129 0 -40
1,4-Dichlorobenzene 54 48 12 36 -97 0 -28
3,3'-Dichlorobenzidine 99 95 5 10 -262 0 -100
Diethylphthalate 30 28 8 10 -114 0 -40
Dimethylphthalate 3 2 23 0 -110 0 -40
2,4-Dinitrotoluene 80 77 4 24 -96 0 -38
2,6-Dinitrotoluene 77 73 6 50 -158 0 -40
Di-n-octylphthalate 93 93 0 10 -146 0 -50
Fluoranthene 92 87 6 26 -137 0 -40
Fluorene 91 88 4 59 -129 0 -40
Hexachlorobenzene 94 88 6 10 -152 0 -40
Hexachlorobutadiene 52 49 6 24 -116 0 -40
Hexachloroethane 47 42 11 40 -113 0 -40
Indeno(l,2,3-cd)pyrene 88 80 10 10 -171 0 -45
Isophorone 70 64 8 21 -196 0 -60
Naphthalene 70 66 7 21 -133 0 -40
Nitrobenzene 74 69 7 35 -180 0 -40
N-Nitrosodi-n-propylamine 82 74 10 41 -116 0 -38
Phenanthrene 89 88 1 54 -120 0 -40
Pyrene 88 87 0 26 -127 0 -31
1,2,4-Trichlorobenzene 60 57 6 44 -142 0 -28
. • Page 6
Analytical Services Inc. Batch QC
Base Neutrals
Matrix : Aqueous Batch # 34480 Method : EPA 625
Matrix Spike Information MS MSD MS %Recovery RPD
Analyte %Rec %Rec RPD Range Range
Acenaphthene 90 87 4 46 -118 0 -31
Acenaphthylene 90 86 4 33 -145 0 -40
Anthracene 90 90 0 27 -133 0 -40
Benzidine 148 151 2 10 -200 0 -100
Benzo(a)anthracene 86 86 1 33 -143 0 -40
Benzo(b)fluoranthene 60 46 26 24 -159 0 -79
Benzo(k)fluoranthene 113 87 26 11 -162 0 -42
Benzo(a)pyrene 87 85 2 17 -163 0 -40
Benzo(ghi)perylene 88 100 13 10 -219 0 -56
Benzyl butyl phthalate 83 77 7 10 -152 0 -40
Bis(2-chloroethyl)ether 67 61 9 10 -150 0 -50
Bis(2-chloroethoxy)methane 82 77 6 33 -184 0 -43
Bis(2-ethylhexyl)phthalate 89 88 1 10 -158 0 -40
Bis(2-chloroisopropyl)ether 78 70 11 36 -166 0 -46
4-Bromophenyl phenyl ether 88 87 2 53 -127 0 -40
2-Chloronaphthalene 85 79 7 60 -118 0 -40
4-Chlorophenyl phenyl ether 93 90 3 28 -158 0 -33
Chrysene 88 90 2 17 -168 0 -48
Dibenzo(a,h)anthracene 87 100 14 10 -227 0 -70
Di-n-butylphthalate 86 86 0 10 -118 0 -50
1,3-Dichlorobenzene 64 58 10 10 -172 0 -40
1,2-Dichlorobenzene 70 62 12 32 -129 0 -40
1,4-Dichlorobenzene 66 59 10 36 -97 0 -28
3,3'-Dichlorobenzidine 97 109 12 10 -262 0 -100
Diethylphthalate 15 16 4 10 -114 0 -40
Dimethylphthalate 1 1 6 0 -110 0 -40
2,4-Dinitrotoluene 84 93 10 24 -96 0 -38
2,6-Dinitrotoluene 82 86 5 50 -158 0 -40
Di-n-octylphthalate 89 78 13 10 -146 0 -50
Fluoranthene 88 92 4 26 -137 0 -40
Fluorene 93 91 3 59 -121 0 -40
Hexachlorobenzene 91 90 1 10 -152 0 -40
Hexachlorobutadiene 68 62 10 24 -116 0 -40
Hexachloroethane 64 56 14 40 -113 0 -40
Indeno (l·, 2, 3 -cd) pyrene 88 100 13 10 -171 0 -45
Isophorone 73 70 4 21 -196 0 -60
Naphthalene 77 73 6 21 -133 0 -40
Nitrobenzene 82 78 5 35 -180 0 -40
N-Nitrosodi-n-propylamine 92 84 9 41 -116 0 -38
Phenanthrene 92 88 4 54 -120 0 -40
Pyrene 84 77 10 26 -127 0 -31
1,2,4-Trichlorobenzene 70 65 8 44 -142 0 -28
•
Analytical Services Inc. Batch QC
Surrogate Recovery
Base Neutrals
Matrix Aqueous Batch# 34480 Method
% Recovery Objectives
Sl Nitrobenzene-d5 35 -
Sample File Sl S2 S3 S4
34480BLK B2499 71
AANote: AKA 89345-6
34480LCS B2502 76
34480LCSD B2503 73
89345-3 B2509 74
89345-3DUP B2510 59
89345-4 B2511 78
89345-4MS B2512 87
89345-4MSD B2513 82
89448 B2563 62
89539 B2601 37
89555-1 B2602 73
89538-2 B2603 64
89538-2D B2628 59
AANote: 1:10
89593 B2671 54
89610-4 B2672 66
89534-1 B2673 99
89559-1 B2674 39
89632-1 B2705 61
89647-2 B2706 69
89563-1 B2708 40
89616-3 B2709 56
89625-1 B2710 69
Page 7
EPA 625
114
S5 S6
Q.C. Information for Batch# 34480
• Page 8
Printed: 12/19/97 19:13:11
Blank Results Information
Base Neutrals Method: EPA 625
Analyte
Acenaphthene
Acenaphthylene
Anthracene
Benzo
Benzyl butyl phthalate
Bis
4-Bromophenyl phenyl ether
4-Chloroaniline
2-Chloronaphthalene
4-Chlorophenyl phenyl ether
Chrysene
Dibenzo
Dibenzofuran
Di-n-butylphthalate
1,3-Dichlorobenzene
1,2-Dichlorobenzene
1,4-Dichlorobenzene
3,3'-Dichlorobenzidine
Diethylphthalate
Dimethylphthalate
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Di-n-octylphthalate
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadiene
Hexachloroethane
Indeno
Isophorone
2-Methylnaphthalene
Naphthalene
2-Nitroaniline
3-Nitroaniline
4-Nitroaniline
Nitrobenzene
N-Nitrosodiphenylamine
N-Nitrosodi-n-propylamine
Phenanthrene
Pyrene
1,2,4-Trichlorobenzene
Blank
Result
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
Detection
Limit
10
10
10
10
10
10
10
20
10
10
10
10
10
10
10
10
10
20
10
10
20
20
10
10
10
10
10
10
2
10
10
10
10
50
50
50
10
10
10
10
10
10
• • Page 9
Q.C. Information for Batch# 34480 Printed: 12/19/97 19:13:11
Sample Batch Information
Base Neutrals Method : EPA 625
Preparation Preparation Analysis
Sample ID Date Time By Notes Date Time By Inst #
89345-3 12/01/97 0900 JW 12/02/97 0349 TAS 5971
89345-4 12/01/97 0900 JW 12/02/97 0454 TAS 5971
89345-4MS 12/01/97 0900 JW 12/02/97 0527 TAS 5971
89345-4MSD 12/01/97 0900 JW 12/02/97 0559 TAS 5971
89345-3DUP 12/01/97 0900 JW 12/02/97 0422 TAS 5971
34480BLK 12/01/97 0900 JW 12/01/97 2224 TAS 5971
34480LCS 12/01/97 0900 JW 12/02/97 0002 TAS 5971
34480LCSD 12/01/97 0900 JW 12/02/97 0035 TAS 5971
89448 12/04/97 0900 JW 12/04/97 1931 TAS 5971
89538-2 12/05/97 0900 JW BN ONLY 12/08/97 0106 TAS 5971
89539 12/05/97 0900 JW 12/08/97 0001 TAS 5971
89555-1 12/05/97 0900 JW 12/08/97 0034 TAS 5971
89593 12/07/97 0930 TB HEAVY EMULSION 12/10/97 2003 TAS 5971
89610-4 12/07/97 0930 TB EMULSION 12/10/97 2037 TAS 5971
89534-1 12/07/97 0930 TB 12/10/97 2111 TAS 5971
89559-1 12/07/97 0930 TB HEAVY EMULSION 12/10/97 2144 TAS 5971
89563-1 12/07/97 0930 TB EMULSION 12/12/97 0315 TAS 5971
89625-1 12/07/97 0930 TB 12/12/97 0419 TAS 5971
89616-3 12/07/97 0930 TB EMULSION 12/12/97 0347 TAS 5971
89538-2D I I 12/09/97 2022 TAS 5971
89632-1 12/09/97 0830 JW/TB 12/12/97 0139 TAS 5971
89647-2 12/09/97 0830 JW/TB 12/12/97 0211 TAS 5971
•
Analytical Services Inc. Batch QC
For Report Number :89647
Organochlorine Pesticides
Page 10
Matrix : Aqueous Batch # 34578 Method : EPA 8080 I 608
Lab Control Information LC LCD LC %-Recovery RPD
Analyte %Rec %Rec RPD Range Range
BHC-gamma (Lindane) 87 87 0 32 -127 0 -40
Heptachlor 85 86 1 34 -111 0 -40
Aldrin 83 84 1 42 -122 0 -40
Dieldrin 89 88 1 36 -146 0 -40
Endrin 89 88 1 30 -147 0 -40
4,4'-DDT 78 75 4 25 -160 0 -40
Matrix Spike Information MS MSD MS %Recovery RPD
Analyte %Rec %Rec RPD Range Range
BHC-gamma (Lindane) 68 68 0 32 -127 0 -40
Heptachlor 52 52 0 34 -111 0 -40
Aldrin 48 47 2 42 -122 0 -40
Dieldrin 58 54 7 36 -146 0 -40
Endrin 63 57 10 30 -147 0 -40
4,4'-DDT 55 49 12 25 -160 0 -40
• • Page 11
Analytical Services Inc. Batch QC
Surrogate Recovery
Organochlorine Pesticides
Matrix Aqueous Batch# 34578 Method EPA 8080 / 608
% Recovery Objectives
81 Dibutylchlorendate 14 -161
82 Tetrachloro-m-xylene 47 -113
83 Decachlorobiphenyl 10 -139
Sample File 81 82 83 84 85 86
34578BLK 120497060F 74 85 96
34578LCS 120497061F 73 113 80
34578LCSD 120497062F 68 62 76
89616-3MS 120897031F 63 87 54
89616-3MSD 120897032F 58 58 39
89555-1 120897063F 76 Bl 101
89539 120497064F 62 85 81
34578BLKPCB 120897016F 99 102
89563-1 120897016F 89 74 67
89610-3 120897018F 10 34 9
89534-1 120897019F 105 112 120
89582-1 120897037F 101 95
AANote: PCB ONLY
89582-2 120897029F 95 77
AANote: PCB ONLY
89559-1 120897030F 114 149 118
89593 120897033F 76 73 86
89616-3 120897036F 57 61 70
89672-11 121097013R 91 121
>-"'Note: PCB ONLY
89690-1 121197026F 62 65 63
89647-2 121097010R 99 114
,,.. .... Note: PCB ONLY
89665-2 121097014R 74 68
AANote: PCB ONLY
89632-1 121097015R Bl 80 71
89610-3RR 121197018F 15 44 14
89684 12119702BF 15 17 7
89696-1 121197029F 91 87 114
89559-lDUP 121197030F 76 112 66
89684RR 121797020F 28 55 83
PCB
PCB
PCB
PCB
PCB
PCB
PCB
Q.C. Information for Batch# 34578
• Page 12
Printed: 12/19/97 19:13:12
Blank Results Information
Organochlorine Pesticides Method: EPA 8080 / 608
Blank Detection
Analyte Result Limit
1016 BDL 1.0
1221 BDL 1. 0
1232 BDL 1.0
1242 BDL 1. 0
1248 BDL 1.0
1254 BDL 1. 0
1260 BDL 1.0
• • Page 13
Q.C. Information for Batch# 34578 Printed: 12/19/97 19:13:12
Sample Batch Information
Organochlorine Pesticides Method : EPA 8080 I 608
Preparation Preparation Analysis
Sample ID Date Time By Notes Date Time By Inst #
89539 12/05/97 0900 JW 12/06/97 0321 RAC GC-3
89555-1 12/05/97 0900 JW 12/06/97 0248 RAC GC-3
34578BLK 12/05/97 0900 JW 12/06/97 0109 RAC GC-3
34578LCS 12/05/97 0900 JW 12/06/97 0142 RAC GC-3
34578LCSD 12/05/97 0900 JW 12/06/97 0215 RAC GC-3
89616-3 12/08/97 0900 JW 12/09/97 1631 RAC GC-3
89616-3MS 12/08/97 0900 JW 12/09/97 1352 RAC GC-3
89616-3MSD 12/08/97 0900 JW 12/09/97 1424 RAC GC-3
89593 12/08/97 0900 JW 12/09/97 1456 RAC GC-3
89610-3 12/08/97 1400 JW 12/09/97 0205 RAC GC-3
89534-1 12/08/97 1400 JW 12/09/97 0238 RAC GC-3
89559-1 12/08/97 1400 JW 12/09/97 1247 RAC GC-3
89563-1 12/08/97 1400 JW 12/09/97 0133 RAC GC-3
89582-1 12/08/97 1400 JW PCB ONLY 12/09/97 1701 RAC GC-3
89582-2 12/08/97 1400 JW PCB ONLY 12/09/97 1217 RAC GC-3
34578BLKPCB 12/08/97 1400 JW PCB ONLY 12/09/97 0100 RAC GC-3
89632-1 12/09/97 0830 JW/TB 12/10/97 1632 RAC GC-3
89647-2 12/09/97 0830 JW/TB PCB ONLY 12/10/97 1402 RAC GC-3
89665-2 12/09/97 0830 JW/TB PCB ONLY 12/10/97 1602 RAC GC-3
89672-11 12/09/97 1400 TB 12/10/97 1532 RAC GC-3
89690-1 12/10/97 1400 JW 12/12/97 1048 RAC GC-3
89696-1 12/10/97 1400 JW 12/12/97 1227 RAC GC-3
89684 12/10/97 1400 JW 12/12/97 1154 RAC GC-3
89610-3RR 12/10/97 1400 JW 12/12/97 0709 RAC GC-3
89559-lDUP 12/11/97 1400 JW 12/12/97 1300 RAC GC-3
89684RR I I 12/18/97 0826 RAC GC-3
• Page 14
Analytical Services Inc. Batch QC
For Report Number :89647
Volatile Organics
Matrix : Aqueous Batch # 34793 Method : EPA 624
Lab Control Information LC LCD LC %Recovery RPD
Analyte %Rec %Rec RPD Range Range
Benzene 83 100 18 37 -151 0 -20
Bromodichloromethane 98 115 16 35 -155 0 -20
Bromoform 86 84 2 45 -169 0 -20
Bromomethane 102 107 4 D -242 0 -20
Carbon tetrachloride 100 110 10 70 -140 0 -20
Chlorobenzene 74 87 15 37 -160 0 -20
Chloroethane 81 92 12 14 -230 0 -20
2-Chloroethylvinyl ether 92 99 8 D -305 0 -20
Chloroform 111 124 11 51 -138 0 -20
Chloromethane 98 88 11 D -273 0 -20
Dibromochloromethane 88 93 5 53 -149 0 -20
1,2-Dichlorobenzene 84 102 20 18 -190 0 -20
1,3-Dichlorobenzene 80 100 22 59 -156 0 -20
1,4-Dichlorobenzene 82 95 14 18 -190 0 -20
1,1-Dichloroethane 108 122 12 59 -155 0 -20
1,2-Dichloroethane 109 125 14 49 -155 0 -20
1,1-Dichloroethene 90 102 12 D -234 0 -20
trans-1,2-Dichloroethene 100 112 12 54 -156 0 -20
1,2-Dichloropropane 92 99 8 D -210 0 -20
cis-1,3-Dichloropropene 99 115 15 D -227 0 -20
trans-1,3-Dichloropropene 93 107 14 17 -183 0 -20
Ethylbenzene 90 82 10 37 -162 0 -20
Methylene chloride 100 114 13 D -221 0 -20
1,1,2,2-Tetrachloroethane 87 103 17 46 -157 0 -20
Tetrachloroethene 104 96 8 64 -148 0 -20
Toluene 77 92 17 47 -150 0 -20
1,1,1-Trichloroethane 119 133 11 52 -162 0 -20
1,1,2-Trichloroethane 85 94 11 52 -150 0 -20
Trichloroethene 93 99 6 71 -157 0 -20
Trichlorofluoromethane 127 130 3 17 -181 0 -20
Vinyl chloride 107 96 11 D -251 0 -20
• • Page 15
Analytical Services Inc. Batch QC
Volatile Organics
Matrix : Aqueous Batch # 34793 Method : EPA 624
Matrix Spike Information MS MSD MS %Recovery RPD
Analyte %Rec %Rec RPD Range Range
Benzene 90 98 9 37 -151 0 -20
Bromodichloromethane 105 108 3 35 -155 0 -20
Bromoform 87 75 16 45 -169 0 -20
Bromomethane 99 102 2 D -242 0 -20
Carbon tetrachloride 100 109 9 70 -140 0 -20
Chlorobenzene 79 71 11 37 -160 0 -20
Chloroethane 87 92 6 14 -230 0 -20
2-Chloroethylvinyl ether 93 95 3 D -305 0 -20
Chloroform 127 116 9 51 -138 0 -20
Chloromethane 116 130 11 D -273 0 -20
Dibromochloromethane 90 79 13 53 -149 0 -20
1,2-Dichlorobenzene 95 86 11 18 190 0 20
1,3-Dichlorobenzene 90 87 4 59 -156 0 -20
1,4-Dichlorobenzene 95 88 7 18 -190 0 -20
1,1-Dichloroethane 115 113 2 59 -155 0 -20
1,2-Dichloroethane 122 128 5 49 -155 0 -20
1,1-Dichloroethene 100 94 6 D -234 0 -20
trans-1,2-Dichloroethene 103 98 5 54 -156 0 -20
1,2-Dichloropropane 93 95 3 D -210 0 -20
cis-1,3-Dichloropropene 109 118 8 D -227 0 -20
trans-1,3-Dichloropropene 106 96 11 17 -183 0 -20
Ethylbenzene 95 95 1 37 -162 0 -20
Methylene chloride 103 99 4 D -221 0 -20
1,1,2,2-Tetrachloroethane 101 93 8 46 -157 0 -20
Tetrachloroethene 71 70 1 64 -148 0 -20
Toluene 85 79 6 47 -150 0 -20
1,1,1-Trichloroethane 128 120 7 52 -162 0 -20
1,1,2-Trichloroethane 89 80 11 52 -150 0 -20
Trichloroethene 101 108 7 71 -157 0 -20
Trichlorofluoromethane 131 126 3 17 -181 0 -20
Vinyl chloride 106 113 6 D -251 0 -20
• • Page 16
Analytical Services Inc. Batch QC
Surrogate Recovery
Volatile Organics
Matrix Aqueous Batch# 34793 Method EPA 624
% Recovery Objectives
Sl 1,2-Dichloroethane-d4 76 -119
S2 Toluene-dB 88 -110
S3 Ethylbenzene-dl0 75 -115
S4 4-Bromofluorobenzene 86 -115
Sample File Sl S2 S3 S4 S5 S6
34793BLK SC093 109 93 91 94
AANote: AKA 89634-6
89634-3 SC089 110 90 89 100
89634-3D SC090 114 94 92 98
""Note: DF=5
89634-4 SC091 112 88 91 96
89634-5 SC092 107 96 103 92
34793LCS SC094 111 92 92 107
34793LCSD SC095 108 91 92 96
89634-4MS SC096 112 94 94 106
89634-4MSD SC097 124 88 93 97
89414-2 SC098 110 90 89 102
89647-2 SC099 113 88 92 95
89647-3 SC104 96 100 103 99
89647-4 SCl0l 103 104 98 101
89634-4DUP SC105 107 94 98 102
89704 SC142 114 90 89 101
89563-1 SC207 93 110 105 99
89625-2 SC208 102 108 102 100
89770 SC209 108 100 98 92
89684 SC210 108 101 95 96
89714-1 SC249 89 100 106 93
89714-2 SC250 102 99 98 98
89810-2 SC251 100 100 100 93
89801 SC252 105 103 99 96
89929 SC253 108 95 92 89
89852 SC254 107 97 100 92
89844 SC255 99 97 100 97
Q.C. Information for Batch# 34793
• Page 17
Printed: 12/19/97 19:13:14
Blank Results Information
Volatile Organics Method: EPA 624
Analyte
Acetone
Benzene
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Dibromochloromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethene
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethylbenzene
2-Hexanone
Methylene chloride
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Vinyl chloride
Xylenes
Blank
Result
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
Detection
Limit
100
2
10
10
10
100
5
2
10
5
2
10
10
2
2
2
2
2
2
2
2
50
10
2
2
2
2
2
2
10
2
• Page 18
Q.C. Information for Batch# 34793 Printed: 12/19/97 19:13:14
Sample Batch Information
Volatile Organics Method : EPA 624
Preparation Preparation Analysis
Sample ID Date Time By Notes Date Time By Inst #
34793BLK I 7 12/11/97 2334 LLP VOAl
89634-3 I I 12/11/97 2144 LLP VOAl
89634-3D I I 12/11/97 2212 LLP VOAl
89634-4 I I 12/11/97 2239 LLP VOAl
89634-5 I I 12/11/97 2307 LLP VOAl
34793LCS I I 12/12/97 0002 LLP VOAl
34793LCSD I I 12/12/97 0029 LLP VOAl
89634-4MS I I 12/12/97 0057 LLP VOAl
89634-4MSD I I 12/12/97 0124 LLP VOAl
89414-2 I I 12/12/97 0151 LLP VOAl
89647-2 I I 12/12/97 0219 LLP VOAl
89647-3 I I 12/12/97 0632 LLP VOAl
89647-4 I I 12/12/97 0700 LLP VOAl
89634-4DUP I I 12/12/97 0729 LLP VOAl
89704 I I 12/13/97 0110 LLP VOAl
89563-1 I I 12/15/97 0822 LLP VOAl
89625 I I 12/15/97 0850 LLP VOAl
89770 I I 12/15/97 0917 LLP VOAl
89684 I I 12/15/97 0945 LLP VOAl
89625-2 I I 12/15/97 0850 LLP VOAl
89714-1 I I 12/16/97 0624 LLP VOAl
89714-2 I I 12/16/97 0652 LLP VOAl
89810-2 I I 12/16/97 0720 LLP VOAl
89801 I I 12/16/97 0748 LLP VOAl
89929 I I 12/16/97 0816 LLP VOAl
89852 I I 12/16/97 0844 LLP VOAl
89844 I I 12/16/97 0917 LLP VOAl
QC Batch
Batch
Number
34030
34615
AANote
34615
34615
AANote
34618
AA.Note
34618
,,..,...Note
34618
34618
AANote
34618
34618
......... Note
34618
AANote
34618
34618
34618 AANote
34618
34618
34618
AANote
34618
34618
AANote
34618
AANote
34618
34618
AANote
34618
• Page 19
Analytical Services Inc. Batch QC
For Report Number :89647
General Information
Analysis
Analyte Method
Hg EPA 245.1
EPA 270.2
0
Se
BATCH PASSES ON LCS/LCSD/MS/MSD
Matrix
Aqueous
Aqueous
DATA
<
<
Blank
Result
0.0002
0.0030
Pb EPA 239.2 Aqueous < 0.0020
Tl
BATCH
EPA 279.2
PASSES ON LCS/LCSD
Aqueous < 0.0020
DUE TO MATRIX INTERFERENCE
Ag EPA 200.7 Aqueous <
BATCH PASSES ON LCS/LCSD/MS/MSD DATA
Al EPA 200.7 Aqueous <
BATCH PASSES ON LCS/LCSD/MS/MSD DATA
As
Ba
BATCH
Be
Ca
BATCH
EPA 200.7
EPA 200.7
PASSES ON LCS/LCSD/MS/MSD
EPA 200.7
EPA 200.7
PASSES ON LCS/LCSD/MS/MSD
Aqueous
Aqueous
DATA
Aqueous
Aqueous
DATA;DL
<
<
<
ADJUSTED
Cd EPA 200.7 Aqueous <
BATCH PASSES ON LCS/LCSD/MS/MSD DATA
Co
Cr
Cu
BATCH
Fe
K
Mg
BATCH
Mn
Na
BATCH
EPA 200.7
EPA 200.7
EPA 200.7
PASSES ON LCS/LCSD/MS/MSD
Aqueous
Aqueous
Aqueous
DATA
EPA 200.7
EPA 200.7
EPA 200.7
PASSES ON LCS/LCSD/MS/MSD
Aqueous
Aqueous
Aqueous
DATA
EPA 200.7
EPA 200.7
PASSES ON LCS/LCSD/MSD
Aqueous
Aqueous
DATA
<
<
<
Ni EPA 200.7 Aqueous <
BATCH PASSES ON LCS/LCSD/MS/MSD DATA
Sb
Zn
BATCH
V
EPA 200.7
EPA 200.7
PASSES ON LCS/LCSD/MS/MSD
EPA 200.7
Aqueous
Aqueous
DATA
Aqueous
<
<
0.0050
0.0200
0.0030
0.0100
0.0010
0.8000
0.0030
0.0100
0.0050
0.0100
0.0400
0.0400
0.0100
0.0150
0.1000
0.0200
0.0060
0.0200
0.0200
Prep.
Method
•
Analytical Services Inc. Batch QC For Report Number :89647
QC Batch General Information
Batch Analysis
Number Analyte Method Matrix
34710 pH EPA 150.1 Aqueous 34720 BOD<5 hi EPA 405.1 Aqueous < 34720" BOD<5 low EPA 405.1 Aqueous < 34730 CN EPA 335.2 Aqueous < 34 739 N EPA 350.2 Aq/Solid < 34805 TSS EPA 160.2 Aqueous < 34814 O/G EPA 1664 Aqueous AANote BATCH PASSES LCS,LCSD,MS.RPD OF LCS FAILS.LACK
Lab Control Information
Batch LC LCD LC Number Analyte Method %Rec %Rec RPD
34030 Hg EPA 245.1 92 90 2 34615 Se EPA 270.2 113 116 3 34615 Pb EPA 239.2 119 83 36 34615 Tl EPA 279.2 87 97 11 34618 Ag EPA 200.7 110 120 9 34618 Al EPA 200.7 91 100 9 34618 As EPA 200.7 94 100 6 34618 Ba EPA 200.7 89 97 9 34618 Be EPA 200.7 95 100 5 34618 Ca EPA 200.7 95 100 5 34618 Cd EPA 200.7 90 98 9 34618 Co EPA 200.7 100 110 10 34618 Cr EPA 200.7 100 110 10 34618 Cu EPA 200.7 91 99 8 34618 Fe EPA 200.7 100 110 10 34618 K EPA 200.7 100 110 10 34618 Mg EPA 200.7 96 100 4 34618 Mn EPA 200.7 100 110 10 34618 Na EPA 200.7 110 120 9 34618 Ni EPA 200.7 87 96 10 34618 Sb EPA 200.7 95 100 5 34618 Zn EPA 200.7 90 92 2 34618 V EPA 200.7 100 110 10 34710 pH EPA 150.1 100 100 0 34720 BOD<5 hi EPA 405.1 99 99 0 34720 BOD<5 low EPA 405.1 94 92 2 34730 CN EPA 335.2 96 97 1 34739 N EPA 350.2 102 102 0 34805 TSS EPA 160.2 94 84 11 34814 O/G EPA 1664 76 47 47
Page 20
Blank Prep.
Result Method
0.0000
5.0000
5.0000
0.0200
0.1000
5.0000
0.0000
OF SAMPLE MSD
%Recovery RPD
Range Range
76 -124 0 -20
76 -124 0 -20
76 -124 0 -20
76 -124 0 -20
76 -124 0 -20
76 -124 0 -20
76 -124 0 -20
76 -124 0 -20
76 -124 0 -20
76 -124 0 -20
76 -124 0 -20
76 -124 0 -20
76 -124 0 -20
76 -124 0 -20
76 -124 0 -20
76 124 0 -20
76 -124 0 -20
76 -124 0 -20
76 -124 0 -20
76 -124 0 -20
76 -124 0 -20
76 -124 0 -20
76 -124 0 -20
80 -120 0 -20
81 -118 0 -30
81 -118 0 -30
75 -125 0 -30 75 -125 0 -30
60 -140 0 -40
32 -103 0 -40
• •
Page 21
Analytical Services Inc. Batch QC
For Report Number :89647
Matrix Spike Information
Batch MS MSD MS %Recovery RPD
Number Analyte Method %Rec %Rec RPD Range Range
34030 Hg EPA 245.1 86 87 1 76 -124 0 -20
34615 Se EPA 270.2 97 93 4 76 -124 0 -20
34615 Pb EPA 239.2 106 103 3 76 -124 0 -20
34615 Tl EPA 279.2 55 59 7 76 -124 0 -20 34618 Ag EPA 200.7 120 120 0 76 -124 0 -20
34618 Al EPA 200.7 99 94 5 76 -124 0 -20
34618 As EPA 200.7 100 98 2 76 -124 0 -20
34618 Ba EPA 200.7 96 91 5 76 -124 0 -20
34618 Be EPA 200.7 100 98 2 76 -124 0 -20
34618 Ca EPA 200.7 97 86 12 76 -124 0 -20
34618 Cd EPA 200.7 97 93 4 76 -124 0 -20
34618 Co EPA 200.7 110 100 10 76 -124 0 -20
34618 Cr EPA 200.7 110 100 10 76 -124 0 -20
34618 Cu EPA 200.7 99 94 5 76 -124 0 -20
34618 Fe EPA 200.7 100 89 12 76 -124 0 -20
34618 K EPA 200.7 120 120 0 76 -124 0 -20
34618 Mg EPA 200.7 100 98 2 76 -124 0 -20
34618 Mn EPA 200.7 110 100 10 76 -124 0 -20 34618 Na EPA 200.7 140 120 15 76 -124 0 -20
34618 Ni EPA 200.7 94 89 5 76 -124 0 -20 34618 Sb EPA 200.7 100 98 2 76 -124 0 -20
34618 Zn EPA 200.7 95 86 10 76 -124 0 -20
34618 V EPA 200.7 110 110 0 76 -124 0 -20 34730 CN EPA 335.2 98 99 1 75 -125 0 -30
34739 N EPA 350.2 104 106 2 75 -125 0 -30
34805 TSS EPA 160.2 94 90 4 60 -140 0 -40 34814 0/G EPA 1664 84 0 NC 32 -103 0 -40
Post Digestion Spike Information
Batch PDS %Recovery
Number Analyte Method %Rec Range
34615 Se EPA 270.2 128 76 -124
34615 Pb EPA 239.2 115 76 -124
34615 Tl EPA 279.2 61 76 -124
34618 Ag EPA 200.7 73 85 -115
34618 Al EPA 200.7 80 85 -115
34618 As EPA 200.7 86 85 -115
34618 Ba EPA 200.7 79 85 -115
34618 Be EPA 200.7 86 85 -115
34618 Ca EPA 200.7 44 85 -115
34618 Cd EPA 200.7 81 85 -115
34618 Co EPA 200.7 91 85 -115 34618 Cr EPA 200.7 90 85 -115
34618 Cu EPA 200.7 80 85 -115
34618 Fe EPA 200.7 89 85 -115
.. •
Analytical Services Inc. Batch QC
For Report Number :89647
Post Digestion Spike Information
Batch PDS
Number Analyte Method %Rec
34618 K EPA 200.7 97
34618 Mg EPA 200.7 83
34618 Mn EPA 200.7 86
34618 Na EPA 200.7 35
34618 Ni EPA 200.7 78
34618 Sb EPA 200.7 85
34618 Zn EPA 200.7 73
34618 V EPA 200.7 94
Unspiked Sample Duplicate Information
Batch Sample 1 Sample
Number Analyte Method RPD RPD
34710 pH EPA 150.1 0
34720 BOD<5 hi EPA 405.1 2 7
34730 CN EPA 335.2 0 0
34739 N EPA 350.2 0 13
34805 TSS EPA 160.2 0 0
Page 22
%Recovery
Range
85 -115
85 -115
85 -115
85 -115
85 -115
85 -115
85 -115
85 -115
2 RPD
Range
0 -20
0 -30
0 -30
0 -30
0 -40
• •
Page 23
Q.C. Information for Batch# 34030 For Report Number :89647
Sample Batch Information
Analysis : Hg
Preparation Preparation Analysis
Sample ID Tag Date Time By Notes Date Time By Inst
3403 0BLAN.K HG 12/09/97 2000 MB 12/10/97 0929 FBS HGl
34030LCS HG 12/09/97 2000 MB 12/10/97 0931 FBS HGl
34030LCSD HG 12/09/97 2000 MB 12/10/97 0934 FBS HGl
89672-lMS HG 12/09/97 2000 MB 12/10/97 0936 FBS HGl
89672-lMSD HG 12/09/97 2000 MB 12/10/97 0941 FBS HGl
89672-5DUP HG 12/09/97 2000 MB 12/10/97 0943 FBS HGl
89672-1 HG 12/09/97 2000 MB 12/10/97 0943 FBS HGl
89672-11 HG 12/09/97 2000 MB 12/10/97 0948 FBS HGl
89672-5 HG 12/09/97 2000 MB 12/10/97 0945 FBS HGl
89647-1 HG 12/09/97 2000 MB 12/10/97 0950 FBS HGl
89662-1 HG 12/09/97 2000 MB 12/10/97 0957 FBS HGl
89681 HG 12/09/97 2000 MB 12/10/97 0959 FBS HGl
89697-1 HG 12/09/97 2000 MB 12/10/97 1002 FBS HGl
89697-2 HG 12/09/97 2000 MB 12/10/97 1004 FBS HGl
89697-3 HG 12/09/97 2000 MB 12/10/97 1006 FBS HGl
89697-4 HG 12/09/97 2000 MB 12/10/97 1008 FBS HGl
89697-5 HG 12/09/97 2000 MB 12/10/97 1011 FBS HGl
89697-6 HG 12/09/97 2000 MB 12/10/97 1013 FBS HGl
89697-7 HG 12/09/97 2000 MB 12/10/97 1015 FBS HGl
89697-8 HG 12/09/97 2000 MB 12/10/97 1018 FBS HGl
89697-9 HG 12/09/97 2000 MB 12/10/97 1027 FBS HGl
89702-1 HG 12/09/97 2000 MB 12/10/97 1030 FBS HGl
89702-2 HG 12/09/97 2000 MB 12/10/97 1032 FBS HGl
WS-040-1 HG 12/09/97 2000 MB 0.5ML/100ML 12/10/97 1039 FBS HGl
WS-040-2 HG 12/09/97 2000 MB 0.5ML/100ML 12/10/97 1042 FBS HGl
• • • Page 24
Q.C. Information for Batch# 34615 For Report Number :89647
Sample Batch Information
Analysis : Se, Pb, Tl
Preparation Preparation Analysis
Sample ID Tag Date Time By Notes Date Time By Inst
34615BLANK Se 12/09/97 0830 KP GFAA 12/10/97 0714 MTK AAl
34615LCS Se 12/09/97 0830 KP GFAA 12/10/97 0714 MTK AAl
34615LCSD Se 12/09/97 0830 KP GFAA 12/10/97 0714 MTK AAl
89558-19MS Se 12/09/97 0830 KP GFAA 12/10/97 0714 MTK AAl
89558-19MSD Se 12/09/97 0830 KP GFAA 12/10/97 0714 MTK AAl
89558-20PDS Se 12/09/97 0830 KP GFAA 12/10/97 0714 MTK AAl
89558-20DUP Se 12/09/97 0830 KP GFAA 12/10/97 0714 MTK AAl
89558-18 Se 12/09/97 0830 KP GFAA 12/10/97 0714 MTK AAl
89558-19 Se 12/09/97 0830 KP GFAA 12/10/97 0714 MTK AAl
89558-20 Se 12/09/97 0830 KP GFAA 12/10/97 0714 MTK AAl
89593 Se 12/09/97 0830 KP GFAA 12/10/97 0714 MTK AAl
89603-1 Se 12/09/97 0830 KP GFAA 12/10/97 0714 MTK AAl
89604-1 Se 12/09/97 0830 KP GFAA 12/10/97 0714 MTK AAl
89611-12 Se 12/09/97 0830 KP GFAA 12/10/97 0714 MTK AAl
89611-13 Se 12/09/97 0830 KP GFAA 12/10/97 0714 MTK AAl
89622-1 Se 12/09/97 0830 KP GFAA 12/10/97 0714 MTK AAl
89637-23 Se 12/09/97 0830 KP GFAA 12/10/97 0714 MTK AAl
89637-24 Se 12/09/97 0830 KP GFAA 12/10/97 0714 MTK AAl
89647-1 Se 12/09/97 0830 KP GFAA 12/10/97 0714 MTK AAl
89672-1 Se 12/09/97 1300 KP GFAA 12/10/97 0714 MTK AAl
89672-5 Se 12/09/97 1300 KP GFAA 12/10/97 0714 MTK AAl
89672-11 Se 12/09/97 1300 KP GFAA 12/10/97 0714 MTK AAl
34615BLANK As 12/09/97 0830 KP GFAA 12/10/97 1059 MTK AA2
34615LCS As 12/09/97 0830 KP GFAA 12/10/97 1059 MTK AA2
34615LCSD As 12/09/97 0830 KP GFAA 12/10/97 1059 MTK AA2
89558-19MS As 12/09/97 0830 KP GFAA 12/10/97 1059 MTK AA2
89558-19MSD As 12/09/97 0830 KP GFAA 12/10/97 1059 MTK AA2
89558-20PDS As 12/09/97 0830 KP GFAA 12/10/97 1059 MTK AA2
89558-20DUP As 12/09/97 0830 KP GFAA 12/10/97 1059 MTK AA2
89558-18 As 12/09/97 0830 KP GFAA 12/10/97 1059 MTK AA2
89558-19 As 12/09/97 0830 KP GFAA 12/10/97 1059 MTK AA2
89558-20 As 12/09/97 0830 KP GFAA 12/10/97 1059 MTK AA2
89593 As 12/09/97 0830 KP GFAA 12/10/97 1059 MTK AA2
89603-1 As 12/09/97 0830 KP GFAA 12/10/97 1059 MTK AA2
89604-1 As 12/09/97 0830 KP GFAA 12/10/97 1059 MTK AA2
89611-12 As 12/09/97 0830 KP GFAA 12/10/97 1059 MTK AA2
89611-13 As 12/09/97 0830 KP GFAA 12/10/97 1059 MTK AA2
89622-1 As 12/09/97 0830 KP GFAA 12/10/97 1059 MTK AA2
89637-23 As 12/09/97 0830 KP GFAA 12/10/97 1059 MTK AA2
89637-24 As 12/09/97 0830 KP GFAA 12/10/97 10·59 MTK AA2
89672-1 As 12/09/97 1300 KP GFAA 12/10/97 1059 MTK AA2
89672-5 As 12/09/97 1300 KP GFAA 12/10/97 1059 MTK AA2
89672-11 As 12/09/97 1300 KP GFAA 12/10/97 1059 MTK AA2
34615BLANK Pb 12/09/97 0830 KP GFAA 12/10/97 1259 MTK AAl
34615LCS Pb 12/09/97 0830 KP GFAA 12/10/97 1259 MTK AAl
34615LCSD Pb 12/09/97 0830 KP GFAA 12/10/97 1259 MTK AAl
89558-19MS Pb 12/09/97 0830 KP GFAA 12/10/97 1259 MTK AAl
89558-19MSD Pb 12/09/97 0830 KP GFAA 12/10/97 1259 MTK AAl
·' . • •
Page 25
Q.C. Information for Batch# 34615 For Report Number :89647
Sample Batch Information
Analysis : Se, Pb, Tl
Preparation Preparation Analysis
Sample ID Tag Date Time By Notes Date Time By Inst
89558-20PDS Pb 12/09/97 0830 KP GFAA 12/10/97 1259 MTK AAl
89558-20DUP Pb 12/09/97 0830 KP GFAA 12/10/97 1259 MTK AAl
89558-19 Pb 12/09/97 0830 KP GFAA 12/10/97 1259 MTK AAl
89558-20 Pb 12/09/97 0830 KP GFAA 12/10/97 1259 MTK AAl
89622-1 Pb 12/09/97 0830 KP GFAA 12/10/97 1259 MTK AAl
89672-11 Pb 12/09/97 1300 KP GFAA 12/10/97 1259 MTK AAl
34615BLANK Cd 12/09/97 0830 KP GFAA 12/11/97 0658 MTK AAl
34615LCS Cd 12/09/97 0830 KP GFAA 12/11/97 0658 MTK AAl
34615LCSD Cd 12/09/97 0830 KP GFAA 12/11/97 0658 MTK AAl
89558-19MS Cd 12/09/97 0830 KP GFAA 12/11/97 0658 MTK AAl
89558-19MSD Cd 12/09/97 0830 KP GFAA 12/11/97 0658 MTK AAl
89558-20PDS Cd 12/09/97 0830 KP GFAA 12/11/97 0658 MTK AAl
89558-20DUP Cd 12/09/97 0830 KP GFAA 12/11/97 0658 MTK AAl
89558-19 Cd 12/09/97 0830 KP GFAA 12/11/97 0658 MTK AAl
89558-20 Cd 12/09/97 0830 KP GFAA 12/11/97 0658 MTK AAl
89622-1 Cd 12/09/97 0830 KP GFAA 12/11/97 0658 MTK AAl
34615BLANK Be 12/09/97 0830 KP GFAA 12/11/97 0909 MTK AAl
34615LCS Be 12/09/97 0830 KP GFAA 12/11/97 0909 MTK AAl
34615LCSD Be 12/09/97 0830 KP GFAA 12/11/97 0909 MTK AAl
89558-19MS Be 12/09/97 0830 KP GFAA 12/11/97 0909 MTK AAl
89558-19MSD Be 12/09/97 0830 KP GFAA 12/11/97 0909 MTK AAl
89558-20PDS . Be 12/09/97 0830 KP GFAA 12/11/97 0909 MTK AAl
89558-20DUP Be 12/09/97 0830 KP GFAA 12/11/97 0909 MTK AAl
89558-19 Be 12/09/97 0830 KP GFAA 12/11/97 0909 MTK AAl
89558-20 Be 12/09/97 0830 KP GFAA 12/11/97 0909 MTK AAl
89622-1 Be 12/09/97 0830 KP GFAA 12/11/97 0909 MTK AAl
89672-11 Be 12/09/97 1300 KP GFAA 12/11/97 0909 MTK AAl
34615BLANK Sb 12/09/97 0830 KP GFAA 12/11/97 1152 MTK AAl
34615LCS Sb 12/09/97 0830 KP GFAA 12/11/97 1152 MTK AAl
34615LCSD Sb 12/09/97 0830 KP GFAA 12/11/97 1152 MTK AAl
89558-19MS Sb 12/09/97 0830 KP GFAA 12/11/97 1152 MTK AAl
89558-19MSD Sb 12/09/97 0830 KP GFAA 12/11/97 1152 MTK AAl
89558-20PDS Sb 12/09/97 0830 KP GFAA 12/11/97 1152 MTK AAl
89558-20DUP Sb 12/09/97 0830 KP GFAA 12/11/97 1152 MTK AAl
89558-19 Sb 12/09/97 0830 KP GFAA 12/11/97 1152 MTK AAl
89558-20 Sb 12/09/97 0830 KP GFAA 12/11/97 1152 MTK AAl
89622-1 Sb 12/09/97 0830 KP GFAA 12/11/97 1152 MTK AAl
34615BLANK Tl 12/09/97 0830 KP GFAA 12/11/97 1437 MTK AAl
34615LCS Tl 12/09/97 0830 KP GFAA 12/11/97 1437 MTK AAl
34615LCSD Tl 12/09/97 0830 KP GFAA 12/11/97 1437 MTK AAl
89558-19MS Tl 12/09/97 0830 KP GFAA 12/11/97 1437 MTK AAl
89558-19MSD Tl 12/09/97 0830 KP GFAA 12/11/97 1437 MTK AAl
89558-20PDS Tl 12/09/97 0830 KP GFAA 12/11/97 1437 MTK AAl
89558-20DUP Tl 12/09/97 0830 KP GFAA 12/11/97 1437 MTK AAl
89558-19 Tl 12/09/97 0830 KP GFAA 12/11/97 1437 MTK AAl
89558-20 Tl 12/09/97 0830 KP GFAA 12/11/97 1437 MTK AAl
89593 Tl 12/09/97 0830 KP GFAA 12/11/97 1437 MTK AAl
89604-1 Tl 12/09/97 0830 KP GFAA 12/11/97 1437 MTK AAl
. _,
Sample ID
89622-1
89647-1
89672-11
89647-1
•
Q.C. Information for Batch# 34615
Page 26
For Report Number :89647
Tag
Tl
Tl
Tl
Pb
Sample Batch Information
Analysis : Se, Pb, Tl
Preparation Preparation
Date Time By Notes
12/09/97 0830 KP GFAA
12/09/97 0830 KP GFAA
12/09/97 1300 KP GFAA
12/09/97 0830 KP GFAA
Analysis
Date Time By
12/11/97 1437 MTK
12/11/97 1437 MTK
12/11/97 1437 MTK
12/10/97 1259 MTK
Inst
AAl
AAl
AAl
AAl
·'" . • •
Page 27
Q.C. Information for Batch# 34618 For Report Number :89647
Sample Batch Information
Analysis Ag, Al, As, Ba, Be, Ca, Cd, Co, Cr, Cu, Fe, K, Mg, Mn, Na, Ni
Sb Zn V
Preparation Preparation Analysis
Sample ID Tag Date Time By Notes Date Time By Inst
34618BLANK 12/10/97 0920 KP TRACE 12/10/97 2242 MAB ICP2
34618LCS 12/10/97 0920 KP TRACE 12/10/97 2246 MAB ICP2
34618LCSD 12/10/97 0920 KP TRACE 12/10/97 2249 MAB ICP2
89634-3MS 12/10/97 0920 KP TRACE 12/10/97 2253 MAB ICP2
89634-3MSD 12/10/97 0920 KP TRACE 12/10/97 2257 MAB ICP2
89634-4PDS 12/10/97 0920 KP TRACE 12/10/97 2301 MAB ICP2
89634-4DUP 12/10/97 0920 KP TRACE 12/10/97 2312 MAB ICP2
89395 12/10/97 0920 KP TRACE 12/10/97 2315 MAB ICP2
89557-1 12/10/97 0920 KP TRACE 12/10/97 2358 MAB ICP2
89557-2 12/10/97 0920 KP TRACE 12/11/97 0001 MAB ICP2
89559-1 12/10/97 0920 KP TRACE 12/11/97 0005 MAB ICP2
89579-1 12/10/97 0920 KP TRACE 12/11/97 0009 MAB ICP2
89594-1 12/10/97 0920 KP TRACE 12/11/97 0012 MAB ICP2
89632-2 12/10/97 0920 KP TRACE 12/11/97 0016 MAB ICP2
89634-3 12/10/97 0920 KP TRACE 12/10/97 2304 MAB ICP2
89634-4 12/10/97 0920 KP TRACE 12/10/97 2308 MAB ICP2
89647-1 12/10/97 0920 KP TRACE 12/11/97 0020 MAB ICP2
89652-1 12/10/97 0920 KP TRACE 12/11/97 0023 MAB ICP2
89662-1 12/10/97 0920 KP TRACE 12/11/97 0035 MAB ICP2
89664 12/10/97 0920 KP TRACE 12/11/97 0038 MAB ICP2
89681 12/10/97 0920 KP TRACE 12/11/97 0042 MAB ICP2
• •
Q.C. Information for Batch# 34710
Page 28
For Report Number :89647
Sample ID Tag
34710CALCHK
34710LCS
34710LCSD
89621-2
89621-2DUP
89654-1
89655-1
89647-2
Sample Batch Information
Analysis : pH
Preparation Preparation
Date Time By Notes
I I
I I
I I
I I
I I
I I
I I
I I
Analysis
Date Time By
12/08/97 0800 JN
12/08/97 0800 JN
12/08/97 0800 JN
12/08/97 0800 JN
12/08/97 0800 JN
12/08/97 1800 JN
12/08/97 1800 JN
12/08/97 1800 JN
Inst
410A
410A
410A
410A
410A
410A
410A
410A
• • Page 29
Q.C. Information for Batch# 34720 For Report Number :89647
Sample Batch Information
Analysis : BOD<5 hi, BOD<5 low
Preparation Preparation Analysis
Sample ID Tag Date Time By Notes Date Time By Inst
34720BLK 12/10/97 0715 AS/SK 12/15/97 1010 ARS
34720LCS 12/10/97 0715 AS/SK 12/15/97 1010 ARS
34720LCSD 12/10/97 0715 AS/SK 12/15/97 1010 ARS
89692-1 12/10/97 0715 AS/SK 12/15/97 1010 ARS
89692-lDUP 12/10/97 0715 AS/SK 12/15/97 1010 ARS
89692-2 12/10/97 0715 AS/SK 12/15/97 1010 ARS
34720CBODLCS 12/10/97 0715 AS/SK 12/15/97 1010 ARS
34720CBODLCSD 12/10/97 0715 AS/SK 12/15/97 1010 ARS
89641-1 12/10/97 0715 AS/SK 12/15/97 1010 ARS
89641-3 12/10/97 0715 AS/SK 12/15/97 1010 ARS
89654-2 12/10/97 0715 AS/SK 12/15/97 1010 ARS
89655-2 12/10/97 0715 AS/SK 12/15/97 1010 ARS
89660-2 12/10/97 0715 AS/SK 12/15/97 1010 ARS
89660-3 12/10/97 0715 AS/SK 12/15/97 1010 ARS
89660-4 12/10/97 0715 AS/SK 12/15/97 1010 ARS
89647-1 12/10/97 0715 AS/SK 12/15/97 1010 ARS
89676-1 12/10/97 0715 AS/SK 12/15/97 1010 ARS
89676-2 12/10/97 0715 AS/SK 12/15/97 1010 ARS
89681 12/10/97 0715 AS/SK 12/15/97 1010 ARS
89676-3 12/10/97 0715 AS/SK 12/15/97 1010 ARS
89690-1 12/10/97 0715 AS/SK 12/15/97 1010 ARS
34720BLK2 12/10/97 1230 AS/SK 12/15/97 1010 ARS
34720LCSLOW 12/10/97 1230 AS/SK 12/15/97 1010 ARS
34720LCSDLOW 12/10/97 1230 AS/SK 12/15/97 1010 ARS
89771-1 12/10/97 1230 AS/SK 12/15/97 1010 ARS
89771-lDUP 12/10/97 1230 AS/SK 12/15/97 1010 ARS
89669-1 12/10/97 0715 AS/SK 12/15/97 1010 ARS
89669-2 12/10/97 0715 AS/SK 12/15/97 1010 ARS
89700-2 12/10/97 0715 AS/SK 12/15/97 1010 ARS
89700-3 12/10/97 0715 AS/SK 12/15/97 1010 ARS
89561 12/10/97 1230 AS/SK 12/15/97 1010 ARS
89706-1 12/10/97 1230 AS/SK 12/15/97 1010 ARS
89708-1 12/10/97 1230 AS/SK 12/15/97 1010 ARS
89711-2 12/10/97 1230 AS/SK 12/15/97 1010 ARS
89712-1 12/10/97 1230 AS/SK 12/15/97 1010 ARS
89713-1 12/10/97 1230 AS/SK 12/15/97 1010 ARS
89714-2 12/10/97 1230 AS/SK 12/15/97 1010 ARS
89712-1 12/10/97 1230 AS/SK 12/15/97 1010 ARS
89737-2 12/10/97 1700 AS/SK 12/15/97 1010 ARS
89715-1 12/10/97 1700 AS/SK 12/15/97 1010 ARS
89718-1 12/10/97 1700 AS/SK 12/15/97 1010 ARS
89719 12/10/97 1700 AS/SK 12/15/97 1010 ARS
89721 12/10/97 1700 AS/SK 12/15/97 1010 ARS
89604-lRR 12/10/97 1700 AS/SK 12/15/97 1010 ARS
89738.-1 12/10/97 1700 AS/SK 12/15/97 1010 ARS
34720DILBLK 12/10/97 1700 AS/SK 12/15/97 1010 ARS
89747-1 12/10/97 1700 AS/SK 12/15/97 1010 ARS
89747-2 12/10/97 1700 AS/SK 12/15/97 1010 ARS
Sample ID
89731-1
89732-1
89732-3
89733-1
89734-1
89737-1
89737-3
89737-4
89755
89751
•
Q.C. Information for Batch# 34720
Page 30
For Report Number :89647
Tag
Sample Batch Information
Analysis : BOD<5 hi, BOD<5 low
Preparation Preparation Analysis
Date Time By Notes Date Time
12/10/97 1700 AS/SK 12/15/97 1010
12/10/97 1700 AS/SK 12/15/97 1010
12/10/97 1700 AS/SK 12/15/97 1010
12/10/97 1700 AS/SK 12/15/97 1010
12/10/97 1700 AS/SK 12/15/97 1010
12/10/97 1700 AS/SK 12/15/97 1010
12/10/97 1700 AS/SK 12/15/97 1010
12/10/97 1700 AS/SK 12/15/97 1010
12/10/97 1820 AS/SK 12/15/97 1010
12/10/97 1700 AS/SK 12/15/97 1010
By
ARS
ARS
ARS
ARS
ARS
ARS
ARS
ARS
ARS
ARS
Inst
,, • • .
Page 31
Q.C. Information for Batch# 34730 For Report Number :89647
Sample Batch Information
Analysis : CN
Preparation Preparation Analysis
Sample ID Tag Date Time By Notes Date Time By Inst
34730BLK 12/09/97 1345 ARS MIDI-DIST 12/09/97 1635 ARS GENES
34730LCS 12/09/97 1345 ARS MIDI-DIST 12/09/97 1635 ARS GENES
34730LCSD 12/09/97 1345 ARS MIDI-DIST 12/09/97 1635 ARS GENES
89607-2MS 12/09/97 1345 ARS MIDI-DIST 12/09/97 1635 ARS GENES
89607-2MSD 12/09/97 1345 ARS MIDI-DIST 12/09/97 1635 ARS GENES
89607-2 12/09/97 1345 ARS MIDI-DIST 12/09/97 1635 ARS GENES
89652-2 12/09/97 1345 ARS MIDI-DIST 12/09/97 1635 ARS GENES
89652-2DUP 12/09/97 1345 ARS MIDI-DIST 12/09/97 1635 ARS GENES
89625-2 12/09/97 1345 ARS MIDI-DIST 12/09/97 1635 ARS GENES
89625-2DUP 12/09/97 1345 ARS MIDI-DIST 12/09/97 1635 ARS GENES
89469-1 12/09/97 1545 ARS MIDI-DIST 12/10/97 0620 ARS GENES
34730CAL5 12/09/97 1545 ARS MIDI-DIST 12/10/97 0620 ARS GENES
34730CAL15 12/09/97 1545 ARS MIDI-DIST 12/10/97 0620 ARS GENES
89469-2 12/09/97 1545 ARS MIDI-DIST 12/10/97 0620 ARS GENES
89469-3 12/09/97 1545 ARS MIDI-DIST 12/10/97 0620 ARS GENES
89469-6 12/09/97 1545 ARS MIDI-DIST 12/10/97 0620 ARS GENES
89469-8 12/09/97 1545 ARS MIDI-DIST 12/10/97 0620 ARS GENES
89469-9 12/09/97 1545 ARS MIDI-DIST 12/10/97 0620 ARS GENES
89469-10 12/09/97 1545 ARS MIDI-DIST 12/10/97 0620 ARS GENES
89469-18 12/09/97 1545 ARS MIDI-DIST 12/10/97 0620 ARS GENES
89469-21 12/09/97 1745 ARS MIDI-DIST 12/10/97 0650 ARS GENES
89469-22 12/09/97 1745 ARS MIDI-DIST 12/10/97 0650 ARS GEMES
89469-23 12/09/97 1745 ARS MIDI-DIST 12/10/97 0650 ARS GEMES 89469-24 12/09/97 1745 ARS MIDI-DIST 12/10/97 0650 ARS GEMES
89469-25 12/09/97 1745 ARS MIDI-DIST 12/10/97 0650 ARS GEMES 89644-1 12/09/97 1745 ARS MIDI-DIST 12/10/97 0650 ARS GEMES 89651-1 12/09/97 1745 ARS MIDI-DIST 12/10/97 0650 ARS GEMES
89651-2 12/09/97 1745 ARS MIDI-DIST 12/10/97 0650 ARS GEMES 89647-2 12/09/97 1745 ARS MIDI-DIST 12/10/97 0650 ARS GEMES
. • • . '
Page 32
Q.C. Information for Batch# 34739 For Report Number :89647
Sample Batch Information
Analysis : N
Preparation Preparation Analysis
Sample ID Tag Date Time By Notes Date Time By Inst
34739BLK 12/10/97 0600 BG 12/10/97 1045 BG GENES
34739LCS 12/10/97 0600 BG 12/10/97 1045 BG GENES
34739LCSD 12/10/97 0600 BG 12/10/97 1045 BG GENES 34739CAL 12/10/97 0600 BG 12/10/97 1045 BG GENES
89662-lMS 12/10/97 0600 BG 12/10/97 1045 BG GENES
89662-lMSD 12/10/97 0600 BG 12/10/97 1045 BG GENES
89662-1 12/10/97 0600 BG 12/10/97 1045 BG GENES
89662-2 12/10/97 0600 BG 12/10/97 1045 BG GENES 89662-3 12/10/97 0600 BG 12/10/97 1045 BG GENES
89665-1 12/10/97 0600 BG 12/10/97 1045 BG GENES
89469-21 12/10/97 0600 BG 12/10/97 1045 BG GENES
89469-21DUP 12/10/97 0600 BG 12/10/97 1045 BG GENES
89469-22 12/10/97 0600 BG 12/10/97 1045 BG GENES
89469-24 12/10/97 0600 BG 12/10/97 1045 BG GENES
89469-25 12/10/97 0600 BG 12/10/97 1045 BG GENES
89469-23 12/10/97 0600 BG 12/10/97 1045 BG GENES 89647-1 12/10/97 0600 BG 12/10/97 1045 BG GENES 89606-2 12/10/97 0600 BG 12/10/97 1045 BG GENES 89606-2DUP 12/10/97 0600 BG 12/10/97 1045 BG GENES 89571-1 12/10/97 0600 BG 12/10/97 1045 BG GENES 89576 12/10/97 0600 BG 12/10/97 1045 BG GENES 89579-1 12/10/97 0600 BG 12/10/97 1045 BG GENES 89535 12/10/97 0600 BG 12/10/97 1045 BG GENES 89622-1 12/10/97 0600 BG 12/10/97 1045 BG GENES 89606-3 12/10/97 0600 BG 12/10/97 1045 BG GENES 89660-1 12/10/97 0600 BG 12/10/97 1045 BG GENES 89660-3 12/10/97 0600 BG 12/10/97 1045 BG GENES 89660-4 12/10/97 0600 BG 12/10/97 1045 BG GENES
• '' . • •
Page 33
Q.C. Information for Batch# 34805 For Report Number :89647
Sample Batch Information
Analysis : TSS
Preparation Preparation Analysis
Sample ID Tag Date Time By Notes Date Time By Inst
34805BLK 7 7 12/10/97 1600 ADM
34805LCS I I 12/10/97 1600 ADM
34805LCSD I I 12/10/97 1600 ADM
89696-2DUP I I 12/10/97 1600 ADM
89692-2DUP I I 12/10/97 1600 ADM
89683-3MS I I 12/10/97 1600 ADM
89683-3MSD I I 12/10/97 1600 ADM
89683-3 I I 12/10/97 1600 ADM
89690-1 I I 12/10/97 1600 ADM
89698-4 I I 12/10/97 1600 ADM
89674-3 I I 12/10/97 1600 ADM
89674-4 I I 12/10/97 1600 ADM
89676-1 I I 12/10/97 1600 ADM
89676-2 I I 12/10/97 1600 ADM
89676-3 I I 12/10/97 1600 ADM
89692-1 I I 12/10/97 1600 ADM
89692-2 I I 12/10/97 1600 ADM
89692-3 I I 12/10/97 1600 ADM
89692-4 I I 12/10/97 1600 ADM
89692-5 I I 12/10/97 1600 ADM
89696-2 I I 12/10/97 1600 ADM
89647-1 I I 12/10/97 1600 ADM
89655-1 I I 12/10/97 1600 ADM
89654-1 I I 12/10/97 1600 ADM
89681 I I 12/10/97 1600 ADM
89699-1 I I 12/10/97 1600 ADM
89699-2 I I 12/10/97 1600 ADM
• . '
Sample ID
34814BLK
34814LCS
34814LCSD
89599
89531-2
89534-2
89647-2
89615
89472
89696-2
89696-2MS
•
Q.C. Information for Batch# 34814
Page 34
For Report Number :89647
Tag
Sample Batch Information
Analysis : 0/G
Preparation Preparation
Date Time By Notes
I l
I I
I I
I I
I I
I I
I I
I I
I I
I I
I I
Analysis
Date Time By
12/12/97 1330 TD
12/12/97 1330 TD
12/12/97 1330 TD
12/12/97 1330 TD
12/12/97 1330 TD
12/12/97 1330 TD
12/12/97 1330 TD
12/12/97 1330 TD
12/12/97 1330 TD
12/12/97 1330 TD
12/12/97 1330 TD
Inst
\1
CRA SHIPPED TO (Laboratory Name): A,vAL-YTicAL.. ~\/Iles, rtJc..,. WO# ~C/&4'7 •
CONESTOGA-ROVERS & ASSOCIATES, INC. 110 "To' Cl-h.>oU>t.. v 7'""· wAV ,J•-",. "'· s5. r.A -z.ooq 2... • .. 1351 Oakbrook Drive Suite 150 REFERENCE NUMBER: PROJECT NAME: ,
Norcross, GA 30093 404-441-0027
CHAIN OF CUSTODY ~CORD 3f49 .J\tx::.o -J.luc.f.(e.s
£:/k//£:L'I U) MAAM~~wll/ f'R~J,ED __jlj,J g _
a:
SAMPLER'S l/m-o/L IL W OJ!; SIGNATURE: ~~ REMARKS
SEQ. V~TE SAMPLE ~~:§i.(J CJo/c * "''•
NO. TIME SAMPLE NUMBER TYPE 8 •1~-r• JJ •
I 17/rAJq1 1345 UJ • 3hG.'l-J~-12.o+'l?-001 Ao i I ')( " 'I< ')( X X r.,::--<"' A ;!'L! .
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s.-ro.P Ft.ow ~ 7o0, '31oz.
~ ..-? TOTAL NUMBER OF CONTAINERS "Z.o . , . ,
RELINQUISHED~ f'/ -"t:£_/ DATE: 121':>/"17 RECEIVED BY: U1') EK ~!fl~ DATE: (1.J5/°t7
(i) " --C• TIME:(000 ® Tl~~ 1000
RELIN~BY: DATE: RECEIVED BY: OAT.
® TIME: @ . TIME:
RELINQUISHED BY: DATE: @CEIVEDBY:g,.,,; //4.•, P".>..e-1, DATE: i,i/1, /q"?
@ TIME: TIME: ·/Jd<'() ,
6oto33rlOCf 13 METHOD OF SHIPMENT: i=-eneMc... EXPRESS AIR BILL NUMBER:
WhHe -Fully Executed Copy SAMPLE TEAM: R:r~~ORATORY BY: --
Yell--Receiving Laboratory Copy .Jo i:J.,J /A7ECJ{.. N2 0546· Pink -Sampler Copy
DATE: / [).Iii. q7 TIME, rl?oo. Goldenrod -Chemist Copy
1007(FORMS) -DEC 6, 93 -REV.D -(AF-01) ~ ? ' ~. d"1 k.al ,'nkcf-I Ct' -;p H =-I { tytef:, AJH 3)