NCD980557656_20050615_NC State University (Lot 86 Farm Unit 1)_FRCBERCLA SAP QAPP_Report of Results - May 2005 Groundwater Monitoring Event-OCR

I
I
I
I
I
I
I
I
I
:I
I
I
I
PIEDMONT GEOLOGIC, P .C.
Environmental Consultants
6003 Chapel Hill Rd., Suite !09 • Raleigh, NC 27607 • Tel: [phone]
REPORT OF RESULTS:
MAY 2005 GROUNDWATER MONITORING EVENT
Lot 86 Fann Unit No. I Site
North Carolina State University
Raleigh, North Carolina
PREPARED FOR:
North Carolina State University
Environmental Health and Safety Center
Raleigh, North Carolina 27695
. PREPARED BY:
Piedmont Geologic, P.C.
6003 Chapel Hill Road, Suite I 09
Raleigh, North Carolina 27607
June 15, 2005
g
n
u
D
u
D
D
D
R
I
I
I
I
I
REPORT CERTIFICATION
Report of Results: May 2005 Groundwater Monitoring Event
North Carolina State University, Lot 86 Farm Unit No. I Site
June 15, 2005
This Report of Results: M_ay 2005 Groundwater Monitoring Event for the North Carolina State University,
Lot 86 Fann Unit No. I Site in Raleigh, North Carolina has been prepared under the responsible charge of
the following Professional Geologist registered in the State of North Carolina.
Peter J. Dressel
Printed Name Signature
Date
PIEDMONT GEOLOGIC, P.C. II
I
g
a
0
D
0
D
D
D
I
I
I
I
I
I
1.0
2.0
2.1
2.2
2.3
2.4
3.0
4.0
Report of Results: May 2005 Groundwater Monitoring Event
North Carolina State University, Lot 86 Farm Unit No. I Site
June 15, 2005
TABLE OF CONTENTS
Page No.
INTRODUCTION ............................................................................................................................ .4
BACKGROUND ................................................................................................................................ 4 ·
FACILITY LOCATION AND DESCRIPTION ............................................................................................... .4
SITE HtSTOR Y ....................................................................................................................................... 5
CURRENT EXTENT OF CONTAMINATION ............................................................................................... 5
FACILITY GEOLOGIC/HYDROGEOLOGIC SEHING .................................................................................. 6
GROUNDWATER SAMPLING AND ANALYSIS PROCEDURES ........................................... 7
GROUNDWATER SAMPLING AND ANALYSIS RESULTS ..................................................... 9
Appendices
A Groundwater sampling forms
B Laboratory reports
Figures
2
3
4
5
6
7
8
Tables
I
2
3
Site location map
Site map
Groundwater potentiometric surface contour map: shallow wells
Groundwater potentiometric surface contour map: intennediate wells
Groundwater potentiometric surface contour map: deep wells
Groundwater chloroform isoconcentration contour map: shallow wells: May 2005
Groundwater chloroform isoconccntration contour map: intermediate wells: May 2005
Groundwater chloroform isoconcentration contour map: deep wells: May 2005
Groundwater level data
Summarized results of laboratory analysis; groundwater samples collected May 2005
Summarized results of field analysis; groundwater samples collected May 2005
PtEIJMONTGEOLOGIC, P.C. iii
I
I
g
g
u
1.0 INTRODUCTION
Report of Results: May 2005 Groundwater Monitoring Event
North Carolina State University, Lot 86 Farm Unit No. I Site
June 15, 2005
This report presents the methods and results of groundwater sampling and analysis activities conducted in
May 2005 for the North Carolina State University (NCSU), Lot 86, Farm Unit# I site (the "site"), located
in Raleigh, Wake County, North Carolina. The sampling/analysis event was conducted in accordance with
the following controlling documents.
• Groundwater Sampling and Analysis Plan, dated April 15, 2004, prepared by Piedmont Geologic;
• Groundwater Sampling Quality Assurance Plan, dated April 15, 2004, prepared by Piedmont
Geologic.
• Letter from Piedmont Geologic to the North Carolina Department of Environment and Natural D Resources (NCDENR), Superfund Branch, Waste Management Division, dated March 25, 2005,
RE: Request for Revisions to laboratory QA/QC Requirements.
D
R
u
I
I
I
I
I
I
Following is site background information, a description of May 2005 groundwater sampling and analysis
procedures, and results of field and laboratory analysis of May 2005 groundwater samples. Supporting
sampling/analysis documentation is provided in appendices.
2.0 BACKGROUND
2.1 Facility Location and Description
The site location is shown in Figure I, and a site map is provided as Figure 2. The site is located on the
west side of Raleigh, Wake County North Carolina, near Carter-Finley Stadium, immediately south of the
southern right-of-way of Wade Avenue Extension, a limited access highway that connects to Interstate 40.
The approximately 1.5-acre site is located on and surrounded by state-owned property. The site is secured
by a chain-link fence with a padlock on the gate. The si.te is covered with grass and no structures are
present. A large grass covered area, west of the site and Carter-Finley stadium is used for parking during
stadium events.
PIEDMONT GEOLOGIC, P.C. 4
I
g
I
g
D
H
D
D
I
I
I
I
I
2.2 Site History
Report of Results: May 2005 Groundwater Monitoring Event
North Carolina State University, Lot 86 Farm Unit No. I Site
June 15, 2005
NCSU selected lot 86 of Farm Unit No. I in 1969 as a burial site for hazardous chemical waste generated at
the University's educational and research laboratories. Burial of waste was discontinued in November 1980 ·
to comply with regulations promulgated under the Resource Conservation and Recovery Act (RCRA).
The chemical wastes were placed in trenches located in the northwestern portion of the site. The trenches
were approximately 8 feet deep and varied from 50 to 150 feet long. After filling, about 3 feet of native soil
that was excavated during trench construction was used as cover material. Later the area was seeded with
grass. The types of chemicals reported to have been buried at the site include solvents, pesiicides,
inorganics, acids ,md bases. Although some of the liquid chemicals disposed of during the initial site
operation were poured into the trenches, both liquids and solid chemicals were generally buried in metal,
glass or plastic containers.
The site was placed on the National Priority List (NPL) in October 1984, based on the results from an
inspection completed in June of that year.
2.3 Current Extent of Contamination
During the period or January 19 to September 21, 1999, remedial action activities were conducted on the
Lot 86 waste trench area. The remedial technology specified in the Record of Decision to address waste
material buried in the trenches, as well as contaminated soils adjacent to the trenches, was in situ mixing
and encapsulation. The goal of the shallow soil mixing was to stabilize and solidify the waste materials in
the disposal trenches and in the soils surrounding the trenches, thereby eliminating further leaching from the
disposal area. During implementation of the remedy approximately 2,240 tons of cement was used to
stabilize almost 10,090 cubic yards of waste material and impacted soil.
Groundwater monitoring at the site has been conducted for approximately 15 years. The most prevalent
chemicals in groundwater continue to be VOCs, with chlorinated compounds (chloroform, methylene
chloride, and carbon tetrachloride) found in the highest concentrations. The shallow groundwater has
evidenced the most impact with only trace materials of contaminants detected in the deep wells. Highest
concentrations have been consistently observed immediately downgradicnt of the landfill waste trenches,
with a rapid decrease with distance away from the site.
PIEDMONT GEOLOGIC, P.C. 5
I
I
I
I
n
0
n
D
D
D
I
I
I
I
I
I
Report of Results: May 2005 Groundwater Monitoring Event
North Carolina State University, Lot 86 Farm Unit No. I Site
June 15, 2005
2.4 Facility Gcologic/Hydrogcologic Setting
The site lies within the upland division of the Piedmont Physiographic Province of the Eastern United
States. The Piedmont occurs as a wide belt extending along the eastern margin of the Appalachian
Mountains extending from Alabama to the southern Hudson Valley of New York.
Overburden soils, referred to as Saprolitc, are described as typical Piedmont materials including silts, clays,
sandy/clayey silts, and sandy/silty clays with minor amounts of fine to medium gravel. The generalized
lithology is described as several feet of silty clay that transitions into micaceous sandy silt with depth.
Materials become increasingly harder and denser with increasing depth, eventually transitioning into
weathered rock then competent crystalline bedrock. Saprolite retains aspects of the parent bedrock, such as
fractures and foliations. The residual soil/saprolite stratum at the site has been described to range in
thickness from 70 to 87 feet, although bedrock has been encountered at depths as shallow as 3 feet.
Bedrock has been mapped in the area of the site as felsic gneiss and schist. The unit consists offelsic
metamorphic rocks interlayered with mica-garnet schist, biotite gneiss, and hornblende gneiss. The rocks
are described as occurring in a northeast-trending band approximately 4 miles wide in the west Raleigh
area.
Groundwater in the area of the site occurs in the overburden soils and the underlying bedrock, generally
under water-table (unconfined) conditions. Shallow groundwater is recharged by infiltration of
precipitation through the ground surface. Recharge varies seasonally, with most occurring in the winter
months when evapotranspiration losses are lowest.
Groundwater in bedrock occurs along zones of secondary porosity, such as fractures, bedding planes, and
foliations. The transrnissivity of bedrock is dependent on the size and interconnectivity of these features.
Bedrock is recharged primarily by the overlying soil/saprolite.
Groundwater flows at the site predominantly toward the west-northwest in the shallow, intermediate, and
bedrock strata. Measured depths to groundwater in the shallow, water table, monitoring wells are typically
30 to 40 feet below grade in the former source area. A listing of site monitoring wells is provided in Table
I. The site monitoring wells may be classified as shallow, intermediate, and deep monitoring wells by the
following convention.
PIEDMONT GEOLOGIC. P.C. 6
I
g
g
n
u
u
6
D
R
I
I
I
I
I
I
I
Cl ·r, f ass, 1cation o Momtonm!
Well Classification
Shallow
Intermediate
Deen
Report of Results: May 2005 Groundwater Monitoring Event
Nonh Carolina State University, Lot 86 Fann Unit No. I Site
June 15, 2005
W II b ) e s JV I epth
Elevation of Screened Interval Formation Intercepted by
(feet relative to National Screened Interval
Geodetic Vertical Datum,
NGVD)
382-413 Residual soils/saorolite
355 -377 Sanrolite/weathered rock
<345 Comoetent crvstalline bedrock
Observed horizontal potentiometric gradients in the shallow, intermediate, and deep hydrostratigraphic units
have ranged from 0.016 ft/ft to 0.022 ft/ft.
3.0 GROUNDWATER SAMPLING AND ANALYSIS PROCEDURES
Groundwater-sampling activities were completed from May 3 to 13, 2005. Copies of groundwater sampling
forms are provided in Appendix A. All non-dedicated sampling equipment was cleaned prior to each use in
accordance with the procedures described in the site groundwater sampling/analysis workplan. Purge water
and equipment cleaning wastewater was transferred to labeled 55-gallon drums and staged within the site
fence for future management by NCSU.
As the initial phase of the sampling activities, groundwater levels and well depths were measured in each
monitoring well on May 3, 2005 using an optical interface probe, which distinguishes between non-aqueous
phase liquid (NAPL) and water. NAPL was not detected in any site monitoring wells.
Following gauging, monitoring wells to be sampled were purged of static groundwater in accordance with
the procedures in the site groundwater sampling/analysis workplan. Each monitoring well was purged of
three static volumes of groundwater, or until dry, using a submersible pump with dedicated pump tubing or
a dedicated, disposable polyethylene bailer. Following the removal of each static volume of groundwater
during purging, field measurements of purge water pH, temperature, specific conductance, and dissolved
oxygen were collected using pre-calibrated field meters.
Usage of a pump versus bailer in the purging process was dependent on the standing column of groundwater
in the monitoring well. Monitoring wells containing less than 3-feet of standing water were purged using a
bailer. An attempt was made to minimize the groundwater flow rate during purging with either the pump or
hailer.
Groundwater samples were collected from each monitoring well within 24 hours of the conclusion of
purging. Samples were collected using bottom loading, dedicated, disposable hailers and nylon rope. Upon.
PIEDMONT GEOI.OGIC, P.C. 7
I
n
n
0
H
D
D
I
I
I
I
I
I
I
Report of Results: May 2005 Groundwater Monitoring Event
North Carolina State University, Lot 86 Farm Unit No. I Site·
June 15, 2005
collection, each sample was transferred to labeled, laboratory prepared containers and promptly placed on
ice in a cooler. In addition to the groundwater samples, two duplicate groundwater samples and two field
rinseate blanks were collected during the sampling event. The rinseate blanks were collected using the
following procedure.
I. A new/clean bailer was rinsed with distilled/deionized water;
2. The bailer was filled with distilled/deionized water;
3. The water was poured into laboratory prepared containers, and the containers were placed on ice with
the groundwater samples.
In addition to field blanks, a trip blank provided by the laboratory accompanied each shipment of samples
to the laboratory.
The May 2005 groundwater and QA/QC samples were shipped under chain of custody via overnight courier
to Environmental Science Corp. in Mt. Juliet, Tennessee (NC Certification No. 375) and analyzed for the
following.
• Volatile organics by EPA Method 62300;
• RCRA metals by EPA Method 6010;
• Mercury by EPA Method 7470;
• Dissolved iron by EPA Method 6010;
• Methane, ethane, ethene by EPA Method 8015;
• Alkalinity, chloride, nitrate, sulfate by EPA Method 300/9056;
• Total organic carbon by EPA Method 9060.
The May 2005 groundwater samples were analyzed in the field for the following using pre-calibrated,
direct-read field meters and a flow-through cell.
• pH;
• Temperature;
• Specific conductance;
• Dissolved oxygen;
•
•
Oxidation/reduction potential; ~~o+-f1.1.eq_Svrc.J
Turbidity .
PtEDMONTGEOLOGIC, l'.C. 8
I
I
I
.I
I
g
I
u
D
6
I
I
I
I
I
Report of Results: May 2005 Groundwater Monitoring Event
North Carolina State University, Lot 86 Fann Unit No. I Site
June 15, 2005
4.0 GROUNDWATER SAMPLING AND ANALYSIS RESULTS
Site groundwater-level data are presented in Table I. Groundwater potentiometric-surface contour maps
based on May 2005 groundwater levels in the shallow, intermediate, and deep monitoring wells are
provided as Figures 3, 4, and 5. Results of laboratory analysis of May 2005 groundwater samples are listed
in Table 2, and results of field analysis of May 2005 groundwater samples are listed in Table 3.
Groundwater chloroform isoconcentration contour maps for the shallow, intermediate, and deep monitoring
wells are provided as Figures 6, 7, and 8.
PIEDMONT GEOLOGIC, P.C. 9
I
I
I
I
I
I
I
g
n
D
n
D
I
•
I
I
I
I
I PIEDMONT GEOLOGIC, P.C.
Report of Results: May 2005 Groundwater Monitoring Event
North Carolina State University, Lot 86 Farm Unit No. I Site
June 15, 2005
FIGURES
I
I
I
I
I
I
g
D
H
n
u
I
I
I
I
I
z
0
8
c:i "' I:,
""
FIGURE 1: USGS Quadrangle Map Excerpt
78°43,000' w WGS84 78°42.000' W
78°43.000' W WGS84 78°42.000' W
~tm FUT IUD METtRS
Primod 6cm. TOPOI ODIi Ne.!ional Oeoppb: Hoktinp ("lll'WW.topo.com)
z
0 0 0
~ 0 "' "'
z
0 0 0 w
0 "' "'
z
g
0 ~ 0 "' "'
I
I
I
I
I
I
0
D
D
I
I
I
I
I
I
I
MW43De
eMW43
LEGEND
MW33
0
[Z2J
Monitoring Well
Waste Burial Area
{Source Area)
Fenced Area
..._,._.;.., • Edge of Wooded
Area
MW46 e
MW45 e
Undeveloped Property
NCSU Practice
Football Fields
0
PD
200· · 400'
PIEDMONT GEOLOGIC, P.C.
Environmental Consultants
Site Map
Carolina State U~iversity 2420
Lot 86 -Ra!ei h, North Carolina 2
I
I
I
I
I
I
I
I
0
0
D
I
I
I
I
I
I
MW15
395.95
MW430
392.59
MW10 --1---=;'1--Jwa.~ 400.81
MW35S
400.65
MW09
DRY
MW37 -...l.-----f
405.26
MW05A -JI---.
405.29
MW36S
405.01
MW05
405.17
LEGEND
MW02
MW47
405.74
M
, 406.
-
~
408.08
Shallow Monitoring Well with
Groundwater Potentiometric Surface
Elevation (ft.)
Groundwater Potentiometric
-4o4 -Surface Contour
Undeveloped
~--MW01B o 405.19
•. I',
--------------;;o·· -............
.__ Grass Me .
Xlj''•·---. .._ dtari
02
8.08
. -----
"MW4Cl.
410.14
5.22 MW32 W01)
~ 409.36 ~::: \
\ 414.79
0 200' 400'
PIEDMONT GEOLOGIC, P.C.
PD
Environmental Consultants
flTlD( l " 6/2/05 FIG-3.dw
Groundwater Potentiometric Surface
Contour Map: Shallow Wells: 5/3/05
North Carolina State University 2519
lot86 Figure:
Ralei h, North Carolina 3
I
I
I
I
I
I
a
D
H
D
D
I
I
I
I
I
I
LEGEND
MW17I
~
401.35
MW17I
401.35
MW121--I---J
405.66
Intermediate Monitoring Well with
Groundwater Potentiometric Surface
Elevation (ft.)
Groundwater Potentiometric -400-Surface Contour (ft.)
Undeveloped Property
NCSU Practice Football
Fields
PD
0 -200' 400'
PIEDMONT GEOLOGIC, P.C.
Environmental Consultants
Groundwater Potentiometric Surface
Contour Map: Intermediate Wells: 5/3/05
roJec o.:
North Carolina State University 2519
Lot86 Firure:
Ralei h, North Carolina 4
/
I
I
I
I
I
I
I
n
0
D
R
I
I
I
I
I
I
MW43D0
390.49
MW35D
401.45
MW36D _J'-_/...-+-r-"
405.26
LEGEND
MW36D
~
405.26
Deep Monitoring Well with Groundwater
Potentiometric Surface Elevation (ft.)
Groundwater Potentiometric -406-Surface Contour (ft.)
7.80
PD
-::~ ·;;;;;.
·~-. ndoned)
,.._.._.
0 200' 400'
PIEDMONT GEOLOGIC, P.C.
Environmental Consultanl<,
Groundwater Potentiometric Surface
Contour Map: Deep Wells: 5/3/05
fOJCC O.:
North Carolina State University 2519
Lot 86 Firurc:
Raleigh, North Carolina 5
I
I
I
I
I
I
I
g
n
D
n
I
I
I
I
I
I
LEGEND
MW16
"" 22,000
MW43D0
0 MW43 ·
11
Mwfa--
. <1.0 0
MW15"
MW10-1r+ ..
MW46
<1.0, r,11
MW35S, ---....-.f-_____ _
<1.0 ,
Monitoring Well with Groundwater
Chloroform Concentration (µg/L)
Waste Burial Area
(Source Area)
Chloroform lsoconcentration -l O,OOO-Contour (µg/L)
MW45 0 <1.0,
Undeveloped
NCSU Practice Football
Fields
PD
w
0 200' 400'
PIEDMONT GEOLOGIC, P.C.
Environmental Consultants
runnt a : " 6/2/05 FIG-6.dw
Groundwater Chlorofonn lsoconcentration
Contour Map: Shallow Wells: May 2005
fOJtC O,:
North Carolina State University 2519
Lot 86 Figure:
Raleigh, North Carolina 6
I
I
I
I
I
I
I
I
n
D
D
D
I
I
I
I
I I
I
LEGEND
MW161 ..,
390
rn
-1,000-
Monitoring Well with Groundwater
Chloroform Concentration (µg/L)
Waste Burial Area
(Source Area)
Chloroform lsoconcentration
Contour (µg/L)
NCSU Practice Football
Fields
PD
w
0 200' 400'
PIEDMONT GEOLOGIC, P.C.
Environmental Consultants
Groundwater Chloroform lsoconcentration
Contour Map: Intermediate Wells: May 2005
roJec o.:
North Carolina State University 2519
Lot86 Fi1ure:
Raleigh, North Carolina 7
0
I
I
I
I
I
I
I
g
u
I
H
D
I
I
I
I
I
I
LEGEND
MW43D
li'l
2.1
-1,000 -
0
MW43D
2. 1 •
Monitoring Well with Groundwater
Chloroform Concentration (µ.g/L)
Waste Burial Area
(Source Area)
Chloroform lsoconcentration
Contour (µg/L)
Undeveloped Property
NCSU Practice Football
Fields
PD
0 200' 400'
PIEDMONT GEOLOGIC, P.C.
Environmental Consultants
rawm,: a e: I c:
612105 FIG-8.dw
Groundwater Chloroform lsoconcentration
Contour Map: Deep Wells: May 2005
roJec o.:
North Carolina State University 2519
Lot 86 Figure:
Raleigh, North Carolina 8
I
I
I
I
I
I
I
I
I
I
I
D
I
R
I
m
m
I
I PIEDMONT GEOLOGIC, l'.C.
Report of Results: May 2005 Groundwater Monitoring Event
North Carolina State University, Lot 86 Farm Unit No. I Site
June 15, 2005
TABLES
I
I
I
I
I
I
I
I
g
I
u
D
D
D
I
Well I.D.
MW-I
MW-lA
MW-lB
MW-2
MW-3
MW-3A
MW-3B
MW-5
MW-SA
MW-5B
MW-6
MW-7
MW-8
MW-9
MW-10
MW-II
MW-lll
MW-12
MW-121
MW-l2D
MW-13
MW-l3D
MW-15
MW-16
MW-161
MW-16D
MW-17
MW-171
MW-l7D
MW-27
MW-27A
MW-29
MW-32
MW-33
MW-34SR
MW-34DR
MW-35S
MW-35D
Northing
747,972.81
747,968.37
747,972.08
747,934.50
747,831.30
747,833.58
747,829.10
747,91 l.73
747,917.ll
747,913.31
747,987.81
747,972.40
747,936.68
747,984.18
748,035.32
747,987.24
747,982.67
748,035.37
748,031.08
748,048.21
748,099.25
748,122.47
748,078.43
748,009.06
748,004.62
748,024.15
748,068.64
748,062.71
748,087.86
747,678.44
747,687.36
747,565.34
747,760.44
747,760.99
747,694.98
747,702.24
747,989.14
747,991.91
TABLE I
GROUNDWATER LEVEL DATA
MAY 3, 2005
North Carolina State University
Lot 86 Site
Raleigh, North Carolina
Easting Well Class Top of Casing Depth to Ground• Groundwater
Elevation (ft)(l water (ft)(2) Elevation (ft)(l)
2,083,713.47 shallow 439.30 34.23 405.07
2,083,717.18 shallow 438.92 33.70 405.22
2,083,718.51 shallow 438.25 33.06 405. l 9
2,083,791.44 shallow 448.74 40.66 408.08
2,083,724.81 shallow 445.39 38.74 406.65
2,083,714.96 shallow 443.15 36.67 406.48
2,083,716.16 intermediate 443.66 35.75 407.91
2,083,684.29 shallow 441.26 36.09 405. l 7
2,083,685.48 shallow 439.81 34.52 405.29 ,
2,083,688.75 intermediate 440.13 34.89 405.24
2,083,695.81 shallow 438.6 l 33.95 404.66
2,083,759.49 shallow 441.94 34.97 406.97
2,083,831.30 shallow 447.85 39.44 408.4 l
2,083,569.82 shallow 442.52 DRY NA
2,083,584.16 shallow 438.09 37.28 400.81
2,083,904.54 shallow 430.01 19.98 410.03
2,083,914.92 intermediate 434.29 24.86 409.43
2,083,726.83 shallow 427.24 22.50 404.74
2,083,738.92 intcnnediate 430.70 25.04 405.66
2,083,735.45 deen 427.45 19.82 407.63
2,083,498.80 shallow 423.82 26.68 397.14
2,083,503.49 deen 423.43 26.38 397.05
2,083,447.10 shallow 432.38 36.43 395.95
2,083,822.21 shallow 427.94 19.27 408.67
2,083,832.41 intcnnediate 432.14 23.52 408.62
2,083,819.82 deen 428.98 21.18 407.80
2,083,615.41 shallow 425.09 23.77 401.32
2,083,626.56 intermediate 427.74 26.39 40 l.35
2,083,612.19 deeo 425.44 24.05 401.39
2,083,751.29 shallow 448.26 38.52 409.74
2,083,749.28 shallow 448.55 38.75 409.80
2,083,753.75 shallow 447.67 39.56 408.l l
2,084,186.72 shallow 438.15 28.79 409.36
2,084,157.91 intermediate 441.38 32.05 409.33
2,083,926.43 shallow 454.82 40.03 414.79
2,083,936.61 deen 454.71 40.09 414.62
2,083,565.01 shallow 443. 12 42.47 400.65
2,083,552.20 deen 444.69 43.24 40 l.45
(continued)
Pagel of2
I
I
I
I
I
I
I
I
I
I
n
D
R
I
I
I
TABLE I (continued)
GROUNDWATER LEVEL DATA
MAY 3,2005
North Carolina State University
Lot 86 Site
Raleigh, North Carolina
Well I.D. Northing Easting Well Class Top of Casing
Elevation (ft)(!
MW-36S 747,905.86 2,083,672.19 shallow 442.71
MW-36D 747,898.07 2,083,671.54 deeo 442.87
MW-37 747,964.33 2,083,718.54 shallow 440.88
MW-38 747,959.35 2,083,794.05 deeo 445.38
MW-40 747,908.53 2,084,062.93 shallow 435.47
MW-41 748,239.12 2,083,608.18 shallow 421.17
MW-411 748,235.91 2,083,619.56 intcnnediate 421.57
MW-41D 748,278.60 2,083,583.47 deeo 420.67
MW-42 748,149.51 2,083,907.73 shallow 427.25
MW-421 748,155.61 2,083,896.58 intermediate 426.68
MW-43 748,526.66 2,083,396.75 shallow 440.59
MW-43D 748,532.52 2,083,416.56 deeo 438.01
MW-45 748,342.75 2,083,907.91 shallow 447.50
MW-46 748,444.92 2,083,683.30 shallow 451.35
MW-47 747,787.80 2,083,636.72 shallow 441.11
(I) Measured m feet relative to site datum.
(2) Measured relative to top-of-casing reference point.
NA= Not Applicable
Page 2 of2
Depth to Ground
water (ft)(2)
37.70
37.61
35.62
37.36
25.33
24.49
23.39
22.38
20.41
18.71
48.00
47.52
46.25
54.46
35.37
Groundwater
Elevation (ft)(!)
405.01
405.26
405.26
408.02
410.14
396.68
398.18
398.29
406.84
407.97
392.59
390.49
401.25
396.89
405.74
I
I
I
I
I
I
I
I
I
I
I
I
D
I
I
I
TAHLE2
SUMMARIZED RESULTS OFLAllORATORY ANALYSIS
GROUNDWATER SAMPLES COLLECTED MAY 2005
North Carolina State University
Lot 86 Site
Ralei~h, North Carolina
Sample I.D.: MW-2 MW-3 MW-6 MW-8 MW-11 MW-lll
Sample Date: 5/13/05 5/13/05 5/12/05 5/13/05 5/12/05 5/11/05
SM Method 6230D (ug/L)
Benzene 1,500 6,000 90 <1.0 <10 <1.0
Bromobenzcnc <100 <250 <10 <1.0 <10 <1.0
BromochloromeU1anc <100 <250 <10 <1.0 <10 <1.0
Bromodichloromcthane <100 <250 1,200 <1.0 <10 <1.0
Bromoform <100 <250 <10 <1.0 <10 <1.0
Bromomethane <100 <250 <10 <1.0 <10 <1.0
n-Butvlbenzcne <100 <250 <10 <1.0 <10 <1.0
scc-Butvlbenzcnc <100 <250 <10 <1.0 <10 <1.0
tcrt-Butvlbcnzene <100 <250 <10 <1.0 <10 <1.0
Carbon tetrachloride 940 870 450 250 <10 <1.0
Chlorobenzcne 160 <250 11 <1.0 <10 <l.0
Chlorodibromomcthane <100 <250 <10 <1.0 <10 <1.0
Chloroethanc <100 <250 <10 <1.0 <10 <1.0
Chloroform 25,000 41,000 9,500 8,200 1,500 <1.0
ChloromeU1anc <IOO <250 <10 <1.0 <10 <1.0
2-Chlorotoluenc <100 <250 <10 <1.0 <10 <1.0
4-Chlorotolucnc <100 <250 <10 <1.0 <10 <l.0
1,2-Dibromo-3-chloropropane 260 <250 33 <1.0 <10 <1.0
1,2-Dichlorobenzcnc <100 <250 53 <1.0 <10 <l.0
1,3-Dichlorobenzcne <100 <250 <10 <1.0 <10 <1.0
1,4-Dichlorobenzene <100 <250 <10 <1.0 <10 <1.0
Dichlorodillouromcthane <100 <250 <10 <1.0 <10 <1.0
I, 1 'DichloroeUiane <100 <250 . <10 <1.0 <10 <1.0
1,2-DichloroeUiane 140 430 110 <1.0 <10 <1.0
I, l-DichloroeU1cne <100 <250 11 <1.0 <10 <1.0
cis-l ,2-DichloroeUienc <100 <250 <10 <1.0 <10 <l.0
trans-1,2-DichloroeUiene <100 <250 <10 <1.0 <10 <1.0
1,2-Dichloronrooane 11,000 4,300 3,000 210 <10 <1.0
1,3-Dichloroorooane 130 <250 <10 <1.0 <10 <l.0
2,2-Dichloropropane <100 <250 <10 <1.0 <10 <1.0
I, 1-Dichloronroocnc <100 <250 <10 <1.0 <10 <l.0
Diisooronvl eU1cr <500 <1,200 <50 <5.0 <50 <5.0
Eth vi benzene 150 <250 <10 <1.0 <10 <1.0
Hexachlorobutadiene <100 <250 <10 <1.0 . <10 <1.0
lsooroovlbenzenc <100 <250 <10 <1.0 <10 <1.0
o-Isooronvllolucnc <100 <250 <10 <1.0 <10 <l.0
MeU1vlcnc chloride 1,600 6,500 370 14 <50 <5.0
Methvl ten-butyl cU1cr <500 <1,200 <50 <5.0 <50 <5.0
NaohUialenc <500 <1,200 <50 <5.0 <50 <5.0
n-Pronvlbcnzenc <100 <250 <10 <1.0 <10 <1.0
(contmued)
PIEDMONT GEOLOGIC, P. C. Page I of IO
MW-12 MW-121 MW-12D
5/13/05 5/12/05 5/11/05
4,800 <50 <l.0
<2,000 <50 <1.0
<2,000 <50 <1.0
<2,000 <50 <l.0
<2,000 <50 <1.0
<2,000 <50 <l.0
<2,000 <50 <1.0
<2,000 <50 <1.0
<2,000 <50 <1.0
<2,000 54 <l.0
<2,000 <50 <1.0
<2,000 <50 <1.0
<2,000 <50 <1.0
45,000 4,200 180
<2,000 <50 <1.0
<2,000 <50 <1.0
<2,000 <50 <l.0
3,800. <50 <l.0
<2,000 <50 <1.0
<2,000 <50 <1.0
<2,000 <50 <1.0
<2,000 <50 <l.0
<2,000 <50 <l.0
<2,000 <50 <1.0
<2,000 ·<50 <1.0
<2,000 <50 <l.0
<2,000 <50 <1.0
22,000 <50 <l.0
<2,000 <50 <1.0
<2,000 <50 <1.0
<2,000 <50 <1.0
<10,000 <250 <5.0
<2,000 <50 <1.0
<2,000. <50 <1.0
<2,000 <50 <1.0'
<2,000 <50 <l.0
<10,000 <250 <5.0
<10,000 <250 <5.0
<10,000 <250 <5.0
<2,000 <50 <1.0
I
I
I
I
I
I
I
I
I
I
I
I
TABLE 2 (continued)
SUMMARIZED RESULTS OF LABORATORY ANALYSIS
GROUNDWATER SAMPLES COLLECTED MAY 2005
North Carolina State University
Lot 86 Site
Raleieh, North Carolina
Samplel.D.: MW-2 MW-3 MW-6 MW-8 MW-11 MW-Ill
Samnle Date: 5/13/05 5/13/05 5/12/05 5/13/05 5/12/05 5/11/05
SM Method 6230D (ug/L)
Stvrene <100 <250 <10 <1.0 <10 <1.0
1, 1, 1,2-Tetrachloroethane <100 <250 <10 <i.0 <10 <1.0
1, 1,2,2-Tetrachiorocthane <100 <250 15 <i.0 <10 <1.0
Tetrachloroethene 960 260 240 210 38 <1.0
1,2,3-Trichlorobcnzcne <100 <250 <10 <1.0 <10 <1.0
I ,2,4-Trichlorobcnzenc <100 <250 <10 <1.0 <10 <1.0
I, 1.1-Trichlorocthane 140 <250 13 <1.0 <10 <1.0
I, I ,2-Trichloroethane <100 <250 <10 <1.0 <10 <1.0
TrichlorocU1ene 710 2,100 350 90 14 <1.0
Trichloroflouromethane <100 <250 <10 1.8 <10 <1.0
1,2,3-Trichloroorooane 260 <250 22 <i.0 <10 <1.0
1,2,4-TrimeU1vlbcnzene <100 <250 <10 <1.0 <10 <1.0
1,3,5-Trimethvibcnzene <100 <250 <10 <1.0 <10 <1.0
Toluene 2,700 1,200 <50 <5.0 <50 <5.0
Vinvl chloride <100 <250 <10 <i.0 <10 <1.0
Xvlcnes 710 <750 <30 <3.0 <30 <3.0
EPA Method 6010 (mg/L)
Arsenic 0.034 <0.02 <0.02 <0.02 <0.02 0.037
Barium 0.94 0.7 0.39 0.025 0.018 0.12
Cadium 0.0081 <0.005 <0.005 <0.005 <0.005 <0.005
Chromium <0.01 <0.01 <0.01 <0.01 <0.01 <0.01
Iron 0.23 1.5 <0.1 <0.1 <0.1 3.2
Lead <0.05 <0.005 <0.005 <0.005 <0.005 <0.005
Man1mnese 65 12 6.4 0.06 0.75 3.7
Selenium <0.2 <0.02 0.021 <0.02 <0.02 0.025
Silver <0.01 <0.01 <0.01 <0.01 <0.01 <0.01
El'A Method 7470 (mg/L)
Mercurv <0.0002 <0.0002 <0:0002 <0.0002 <0.0002 <0.0002
EPA Method 8015 (mg/L)
McUiane <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
EUiane <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
EUicne <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
EPA Method 300/9056 (mg/L)
Alkalinitv 42 76 36 110 44 78
Chloride 200 15 41 4 2.6 7.5
Nitrate 0.46 <0.1 <0.1 0.54 o:n <0.1
Sulfate 5.7 <5.0 <5.0 <5.0 <5.0 <5.0
SM Method 9060 (mg/L)
Total Or~anic Carbon 81 23 7.7 <1.0 2.4 6.8
PIEDMONT GEOLOGIC, P. C. Page 2 of IO
MW-12 MW-121 MW-12D
5/13/05 5/12/05 5/11/05
<2,000 <50 <1.0
<2,000 <50 <1.0
<2,000 <50 <1.0
<2,000 91 <1.0
<2,000 <50 <1.0
<2,000 <50 <1.0
<2,000 <50 <1.0
<2,000 <50 <1.0
<2,000 110 1.6
<2,000 <50 <1.0
<2,000 <50 <1.0
<2,000 <50 <1.0
<2,000 <50 <1.0
<10,000 <250 <5.0
<2,000 <50 <1.0
<6,000 <150 <3.0
<0.02 <0.02 <0.02
0.38 0.0074 0.019
0.0065 <0.005 <0.005
<0.01 <0.01 <0.01
<0.1 <0.1 <0.1
<0.005 <0.005 <0.005
13 0.073 <0.01
<0.02 <0.02 <0.02
<0.01 <0.01 <0.01
<0.0002 <0.0002 <0.0002
<1.0 <1.0 <1.0
<1.0 <i.0 <1.0
<1.0 <1.0 <1.0
22 27 89
50 1.9 1.9
<0.1 0.17 <0.1
<5.0 <5.0 7.4
90 <1.0 <1.0
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
TABLE 2 (continued)
SUMMARIZED RESULTS OF LAllORATORY ANALYSIS
GROUNDWATER SAMPLES COLLECTED MAY 2005
North Carolina State University
Lot 86 Site
Raleivh, North Carolina
Sample I.D.: MW-13 MW-13D MW-16 MW-161 MW-16D MW-17 MW-171 MW-17D MW-27
Samnle Date:
SM Method 6230D (ug/L)
Benzene
Bromobcnzene
Bromochloromethane
Bromodichloromet11ane
Bromoform
BromomcUrnne
n-Butvlbcnzene
scc-Butvlbenzene
tcrt-Butvlbenzene
Carbon tetrachloride
Chlorobcnzene
Chlorodibromomethane
Chloroctliane
Chloroform
ChloromcUiane
2-Chlorotoluene
4-Chlorotoluenc
1,2-Dibromo-3-chloropropane.
1,2-Dichlorobenzene
1,3-Dichlorobcnzene
I .4-Dichlorobcnzene
Dichiorodiflouromethane ·
I, 1-Dichloiocthane
1 .2-Dichloroethane
I, l-Dichloroctl1ene
cis-1,2-Dichloroethene
trans-l ,2-Dichloroctl1cne
1,2-Dichloronronanc
1,3,Dichloroorooane
2,2-Dichlorooropane
1, 1-Dichloronrooene
Diisooroovl etl1er
Etl1vlbcnzcne
Hexachlorobutadiene
lsooronvlbcnzene
o-lsooroovltoluenc
Mctlwlene chloride
Mctlwl tert-butvl etl1cr
Nanht..halcne
n-Pronvlbcnzene
PIEDMONT GEOLOGIC, P.C.
5/6/05
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<5.0
<1.0
<1.0
<1.0
<1.0
<5.0
<5.0
<5.0
<1.0
5/10/05 5/13/05 5/11/05
<1.0 860 <1.0
<1.0 <50 <1.0
<1.0 <50 <1.0
<1.0 <50 <1.0
<1.0 <50 <1.0
<1.0 <50 <1.0
<1.0 <50 <1.0
<1.0 <50 <1.0
. <1.0 <50 <1.0
<l.O 210 <1.0
<1.0 150 <1.0
<1.0 <50 .<1.0
<1.0 <50 <1.0
<1.0 22,000 390
<1.0 <50 <1.0
<1.0 <50 <1.0
<1.0 <50 <1.0
<1.0 <50 <1.0
<1.0 <50 <1.0
<1.0 <50 <1.0
<1.0 <50 <1.0
<1.0 <50 <1.0
<1.0 <50 <1.0
<1.0 <50 <1.0
<1.0 <50 <1.0
<1.0 <50 <1.0
<1.0 <50 <1.0
<1.0 2,900 II
<1.0 <50 <1.0
<1.0 <50 <1.0
<1.0 <50 <1.0
<5.0 <250 <5.0
<1.0 58 <1.0
<1.0 <50 <1.0
<1.0 <50 . <1.0
<1.0 <50 <1.0
<5.0 650 <5.0
<5.0 <250 <5.0
<5.0 <250 <5.0
<1.0 <50 <1.0
(contmucd)
Page 3 of IO
5/10/05 5/12/05 5/12/05 5/12/05 5/10/05
<1.0 11,000 760 <10 <1.0
<1.0 <50 <5.0 <10 <1.0
<1.0 <50 <5.0 <10 <1.0
<1.0 <50 6.5 <10 <1.0
<1.0 <50 <5.0 <10 <1.0
<1.0 <50 <5.0 <10 <1.0
<1.0 <50 <5.0 <10 <1.0
<1.0 <50 <5.0 <10 <1.0
<1.0 <50 <5.0 <10 · <1.0
<1.0 50 25 210 10
<1.0 <50 <5.0 <10 <1.0
<1.0 <5.0 <10 <LO
<1.0 <5.0 <10 <1.0
4.7 850 680 1,200 17
<1.0 <50 <5.0 <10 <1.0
<1.0 <50 <5.0 <10 <1.0
<1.0 <5.0 <10 <LO
1.9 <50 <5.0 <10 <1.0
<1.0 <50 <5.0 <10 <1.0
<1.0 <50 <5.0 · <10 <1.0
<1.0 <50 <5.0 <10 <1.0
<1.0 <50 <5.0 <10 <1.0
<1.0 <50 <5.0 <10 <1.0.
<1.0 <50 <5.0 <10 <1.0
<1.0 <50 <5.0 <10 <1.0
<1.0 <50 <5.0 <10 <1.0
<1.0 <50 <5.0 <10 <1.0
2.9 160 240 54 10
<1.0 <50 <5.0 <10 <1.0
<1.0 <50 <5.0 <10 <1.0
<1.0 <50 <5.0 <10 <1.0
<5.0 <250 <25 <50 <5.0
<1.0 <50 <5.0 <10 <1.0
<1.0 <50 <5.0 <10 <1.0
<1.0 <5.0 <10 <1.0
<1.0 <50 <5.0 <10 <1.0
<5.0 <250 29 <50 <5.0
<5.0 <250 <25 <50 <5.0
<5.0 <250 <25 <50 <5.0
<1.0 <5.0 <10 <1.0
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
TABLE 2 (continued)
SUMMARIZED RESULTS O•' LABORATORY ANALYSIS
GROUNDWATER SAMPLES COLLECTED MAY 2005
North Carolina State University
Lot 86 Site
Ralei2h, North Carolina
Sample I.D.: MW-13 MW-13D MW-16 MW-161 MW-16D MW-17
Samole Date: 5/6/05 5/10/05 5/13/05 5/11/05 5/10/05 5/12/05
SM Method 6230D (ug/L)
Stvrene <1.0 <1.0 <50 <1.0 <1.0 <50
I, I, 1,2-Tetrachloroethane <1.0 <1.0 <50 <1.0 <1.0 <50
I, 1,2,2-Tetrachloroethane <1.0 <1.0 <50 <1.0 <1.0 <50
Tetrachloroethene <1.0 <1.0 860 <1.0 <1.0 <50
1,2,3-Trichlorobenzene <1.0 <1.0 <50 <1.0 <1.0 <50
1,2,4-Trichlorobenzene <1.0 <1.0 <50 <1.0 <1.0 <50
1, 1, I-Trichloroethane <1.0 <1.0 <50 <1.0 <1.0 <50
1, 1,2-Trichloroethane <1.0 <1.0 700 <1.0 <1.0 <50
Trichloroethene <1.0 <1.0 1,400 <1.0 <1.0 85
Trichloroflouromethane <1.0 <1.0 <50 <1.0 <1.0 <50
1,2,3-Trichloroorooane <1.0 <1.0 <50 <1.0 <1.0 <50
1,2,4-Trimethvlbenzene <1.0 <1.0 <50 <1.0 <1.0 <50
1,3,5-Trimethvlbenzene <1.0 <1.0 <50 <1.0 <1.0 <50
Toluene <5.0 <5.0 630 <5.0 <5.0 <250
Vinvl chloride <1.0 <1.0 <50 <1.0 <1.0 <50
Xvlenes <3.0 <3.0 270 <3.0 <3.0 <150
EPA Method 6010 (mg/L)
Arsenic 0.051 <0.02 <0.02 <0.02 <0.02 <0.02
Barium 1.4 0.01 0.18 0.018 0.Dll 0.026
Cadium <0.005 <0.005 <0.005 <0.005 <0.005 <0.005
Chromium <0.01 <0.01 <0.01 <0.01 <0.01 <0.01
Iron <0.1 <0.1 2.1 <0.1 <0.1 0.31
Lead 0.0052 <0.005 <0.005 <0.005 <0.005 <0.005
Manr!anese 2.5 0.094 22 0.17 <0.01 0.2
Selenium <0.02 0.025 <0.02 <0.02 <0.02 <0.02
Silver <0.01 <0.01 <0.01 <0.01 <0.01 <0.01
EPA Method 7470 (mg/L)
Mercurv <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002
EPA Method 8015 (mg/L)
Methane <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
Ethane <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
Ethene <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
EPA Method 300/9056 (mg/L)
Alkalinitv 360 69 40 52 56 48
Chloride 9.7 1.6 6.0 1.8 1.2 4.2
Nitrate 22 <0.1 <0.1 <0.1 <0.1 <0.1
Sulfate <5.0 <5.0 5.5 <5.0 <5.0 <5.0
SM Method 9060 (mg/L)
Total Oreanic Carbon <1.0 3.1 10 <1.0 9.2 7.6
PIEDMONT GEOLOGIC. P.C. Page 4 of 10
MW-171 MW-17D MW-27
5/12/05 5/12/05 5/10/05
<5.0 <10 <1.0
<5.0 <10 <1.0
<5.0 <10 <1.0
<5.0 38 <1.0
<5.0 <10 <1.0
<5.0 <10 <1.0
<5.0 <10 <1.0
7.0 <10 <1.0
34 63 4.2
<5.0 <10 <1.0
6.6 <10 <1.0
<5.0 <10 <1.0
<5.0 <10 <1.0
<25 <50 <5.0
<5.0 <10 <1.0
<15 <30 <3.0
<0.02 <0.02 <0.02
0.017 0.Q35 0.018
<0.005 <0.005 <0.005
<0.01 0.021 <0.01
<0.1 <0.1 <0.1
<0.005 <0.005 <0.005
0.12 <0.01 0.049
<0.02 0.053 <0.02
<0.01 <0.001 <0.01
<0.0002 <0.0002 <0.0002
<1.0 <1.0 <1.0
<1.0 <1.0 <1.0
<1.0 <1.0 <1.0
36 30 47
2.4 1.7 2.9
<0.1 <0.1 0.41
<5.0 <5.0 <5.0
<1.0 <1.0 <1.0
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
TABLE 2 (continued)
SUMMARIZED RESULTS OF LABORATORY ANALYSIS
GROUNDWATER SAMPLES COLLECTED MAY 2005
North Carolina State University
Lot 86 Site
Ralei~h, North Carolina
Sample I.D.: MW-29 MW-33 MW-34SI MW-34SI MW-34D1 MW-35S
(2)
Samnle Date: 5/6/05 5/6/05 5/11/05 5/11/05 5/10/05 5/6/05
SM Method 6230D (ug/L)
Benzene <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
Bromobcnzcne <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
Bromochloromcthanc <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
Bromodichloromethanc <1.0 <1.0 <1.0 <1.0 <1.0 <1.0.
Bromoform <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
Bromomclhanc <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
n-Butvlbcnzenc <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
sec-Butvlbcnzene <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
· tcrt-Butvlbcnzcne <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
Carbon tetrachloride <1.0 <1.0 "<1.0 <1.0 <1.0 <1.0
Chlorobcnzcne <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
Chlorodibromome01ane <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
ChlorocOrnne <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
Chloroform <1.0 <1.0 II 9.8 1.0 <1.0
ChloromcOianc <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
2-Chlorotolucnc <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
4-Cblorotoluenc <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
1, 2-Dibromo-3-cbloronropane <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
1,2-Dichlorobcnzenc <1.0 <1.0 <1.0 <LO <1.0 <1.0
1,3-Dichlorobcnzenc <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
1,4-Dichlorobenzene <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
Dichlorodinouromc01anc <1.0. <1.0 <1.0 <1.0 <1.0 <1.0
I, 1-DichloroeOianc <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
1,2-Dichloroethanc <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
I, l -Dichloroe01ene <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
cis-1,2-Dichloroe01ene <LO <1.0 <1.0 <1.0 <1.0 <1.0
trans-1,2-Dichloroethene <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
1,2-Dichloronronanc <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
1,3-Dichlorooronanc <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
2,2-Dichloronropanc <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
1, 1-Dichloronronene <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
Diisonronvl ether <5.0 <5.0 <5.0 <5.0 <5.0 <5.0
E01vlbcnzcne <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
Hcxachlorobutadiene <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
lsopronvlbcnzcne <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
p-lsooronvltolucnc <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
Methvlcnc chloride <5.0 <5.0 <5.0 <5.0 <5.0 <5.0
Methvl tert-butvl e01er <5.0 <5.0 <5.0 <5.0 <5.0 <5.0
Naphthalene <5.0 <5.0 <5.0 <5.0 <5.0 <5.0
n-PronuJbcnzenc <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
(contmued)
PIEDMONT GEOLOGIC, P. C. Page 5 or lO.
MW-35D MW-36S MW-36D
5/13/05 5/13/05 5/12/05
<1.0 1,200 <1.0
<1.0 <50 <1.0
<1.0 <50 <1.0
<1.0 920 <1.0
<1.0 <50 <1.0
<1.0 .<50 <1.0
<1.0 <50 <1.0
<1.0 <50 <1.0
<1.0 <50 <1.0
<1.0 570 <1.0
<1.0 65 <1.0
<1.0 <50 <1.0
<1.0 <50 <1.0
4.0 19,000 26
<1.0 <50 <1.0
<1.0 <50 <1.0
<1.0 <50 <1.0
<1.0 1,200 <1.0
<1.0 <50 <1.0
<1.0 <50 <1.0
<1.0 <50 <1.0
<1.0 <50 <1.0
<1.0 <50 <1.0
<1.0 710 <1.0
<1.0 <50 <1.0
<1.0 <50 <1.0
<1.0 <50 <1.0
<1.0 1,700 28
<1.0 <50 <1.0
<1.0 <50 <LO
<1.0 <50 <1.0
<5.0 <250 <5.0
<1.0 <50 <1.0
<1.0 <50 <1.0
<1.0 <50 <1.0
<1.0 <50 <1.0
<5.0 1,700 <5.0
<5.0 <250 <5.0
<5.0 <250 <5.0
<1.0 <50 <1.0
I
I
I
I
I
I
I
I
I
I
I
I
ii
I
iii
I
:1
I
'1
I I I
TABLE 2 (continued)
SUMMARIZED RESULTS OF LABORATORY ANALYSIS
GROUNDWATER SAMPLES COLLECTED MAY 2005
North Carolina State University
Lot 86 Site
Ralei vb, North Carolina
Sample I.D.: MW-29 MW-33 MW-34S1 MW-34S~ IMW-34D1 MW-35S
(2)
Samnle Date: 5/6/05 5/6/05 5/11/05 5/11/05 5/10/05 5/6/05
SM Method 6230D (ug/L)
Stvrene <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
1, 1, 1,2-Tetrachlorocthanc <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
1, 1,2,2-Tetrachloroctliane <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
Tetrachloroct11ene <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
1,2,3-Trichlorohcnzene <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
1,2,4-Trichlorohcnzene <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
1, 1, 1-Trichlorocthanc <1.0 <1.0 <LO <1.0 <1.0 <1.0
1, 1,2-Trichloroctlianc <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
Trichlorocthene <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
TrichloroOourometJrnnc <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
1,2,3-Trichloroorooane ·<1.0 <1.0 <1.0 <1.0 <1.0 <1.0
1,2,4-Trimethvlhcnzene <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
1,3,5-Trimetlivlhcnzene <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
Toluene <5.0 <5.0 <5.0 <5.0 <5.0 <5.0
Vinvl chloride <LO· <1.0 <1.0 <1.0 <1.0 <1.0
Xvlcnes <3.0 <3.0 <3.0 <3.0 <3.0 <3.0
EPA Method 6010 (mg/L)
Arsenic <0.02 <0.02 <0.02 <0.02 <0.02 <0.02
Barium 0.015 0.0074 0.32 0.32 0.043 0.03
Cadium <0.005 <0.005 <0.005 <0.005 <0.005 <0.005
Chromium <0.01 <0.01 <0.01 <0.01 <0.01 0.019
Iron <0.1 <0.1 <0.1 <0.1 <0.1 <0.1
Lead <0.005 <0.005 <0.005 <0.005 <0.005 <0.005
MallQllilCSe <0.01 <0.01 0.072 0.07 <0.01 0.012
Selenium <0.02 <0.02 <0.02 <0.02 0.03 <0.02
Silver <0.01 <0.01 <0.01 <0.01 <0.01 <0.01
EPA Method 7470 (mg/L)
Mercurv <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002
EPA Method 8015 (mg/L)
Methane <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
Ethane <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
Ethene <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
EPA Method 300/9056 (mg/L)
Alkalin it v · 52 29 15 <10 40 28
Chloride 2.3 1.7 4.4 4.4 1.6 2.2
Nitrate 0.39 <0.1 0.38 0.37 <0.1 0.59
Sulfate <5.0 <5.0 <5.0 <5.0 <5.0 <5.0
SM Method 9060 (mg/L)
Total Org·anic Carbon <1.0 <1.0 <1.0 7.0 <1.0 <1.0
PIEDMONT GEOLOGIC, P.C. Page 6 of 10
MW-35D MW-36S MW-36D
5/13/05 5/13/05 5/12/05
<1.0 <50 <1.0
<1.0 <50 <1.0
<1.0 <50 <1.0
<1.0 78 4.9
<1.0 <50 <1.0
<1.0 <50 <1.0
<1.0 <50 <1.0
<1.0 <50 <1.0
<1.0 530 7.1
<1.0 <50 <1.0
<1.0 <50 <1.0
<1.0 <50 <1.0
<1.0 <50 <1.0
<5.0 <250 <5.0
<1.0 <50 <1.0
<3.0 <150 <3.0
<0.02 <0.02 <0.02
0.0059 0.33 0.0082
0.027 0.0058 <0.005
<0.01 <0.01 <0.01
<0.1 <0.1 <0.1
<0.005 <0.005 <0.005
0.1 16 0.023
0.022 <0.02 0.03
<0.01 <0.01 <0.01
<0.0002 <0.0002 <0.0002
<1.0 <1.0 <1.0
<1.0 <1.0 <1.0
<1.0 <1.0 <1.0
56 32 39
1.6 45 3.0
0.11 <0.1 <0.1
<5.0 <5.0 <5.0
<1.0 45 <1.0
I
I
I
I
I
I
I
I
I
I
11
\1
' 11
I
!I
I
!I
I
I ii
:1
II
I
ii
I
TABLE 2 (continued)
SUMMARIZED RESULTS OF LAJIORATORY ANALYSIS
GROUNDWATER SAMPLES COLLECTED MAY 2005
North Carolina State University
Lot 86 Site
Raleieh, North Carolina
Sample I.I),: MW-37 MW-38 MW-40 MW-41 MW-411 MW-41D
Samnle Date: 5/13/05 5/5/05 5/10/05 5/5/05 5/5/05 5/10/05
SM Method 62301) (ug/L)
Benzene 4,200 <1.0 <1.0 <1.0 <1.0 <1.0
Br6mobenzcne <100 <1.0 <1.0 <1.0 <1.0 <1.0
Bromochloromethane <100 <1.0 <1.0 <1.0 <1.0 <1.0
Bromodichloromcthanc <100 <1.0 <1.0 <1.0 <1.0 <1.0
Bromofonn <100 <1.0 <1.0 <1.0 <1.0 <1.0
BromomeLhane <100 <1.0 <1.0 <1.0 <1.0 <1.0.
n-Btitvlhenzcne <100 <1.0 <1.0 <1.0 <1.0 <1.0
scc-Butvlbcnzenc <100 <1.0 <1.0 <1.0 <1.0 <1.0
lert-Butvlhenzenc <100 <1.0 <1.0 <1.0 <1.0 <1.0
Carbon tetrachloride 1,600 <1.0 <1.0 <1.0 <1.0 1.0
Chlorobcnzcne 180 <1.0 <1.0 <1.0 <1.0 <1.0
Chlorodibromomclhanc <100 <1.0 <1.0 <1.0 <1.0 <1.0
Chloroethane <100 <1.0 <1.0 <1.0 <1.0 <1.0
Chloroform 68,000 <1.0 110 <1.0 <1.0 4.2
Chloromel11ane <100 <1.0 <1.0 <1.0 <1.0 <1.0
2-Chlorotoluenc <100 <1.0 <LO <1.0 <1.0 <1.0
4-Chlorotolucne <100 <1.0 <1.0 <1.0 <1.0 <1.0
1,2-Dibromo-3-chloroorooanc 730 <1.0 <1.0 <1.0 <1.0 <1.0
1,2-Dichlorohenzcnc <100 <1.0 <1.0 <1.0 <1.0 <1.0
1,3-Dichlorohenzcnc <100 <1.0 <1.0 <1.0 <1.0 <1.0
1,4-Dichlorohenzcne <100 <1.0 <1.0 <1.0 <1.0 <1.0
Dichlorodiflouromcthane <100 <1.0 <1.0 <1.0 <1.0 <1.0
I, 1-Dichloroellrnnc <100 <1.0 <1.0 <1.0 <1.0 <1.0
1,2-Dichloroethane 920 <1.0 <1.0 <1.0 <1.0 <1.0
I, l-Dichloroell1ene <100 <1.0 <1.0 <1.0 <1.0 <1.0
cis-l ,2-Dichloroell1ene <100 <1.0 <1.0 <1.0 <1.0 <1.0
traos-1,2-Dichloroethcnc <100 <1.0 <1.0 <1.0 <1.0 <1.0
1,2-Dichloroorooane 1,400 <1.0 <1.0 <1.0 <1.0 <1.0
· 1,3-Dichloronronane <100 <1.0 <1.0 <1.0 <1.0 <1.0
2,2-Dichloroorooane <100 <1.0 <1.0 <1.0 <1.0 <1.0
I, 1-Dichloroorooene <100 <1.0 <1.0 <1.0 <1.0 <1.0
Diisonronvl ether <500 <5.0 <5.0 <5.0 <5.0 <5.0
Ethvlbcnzcnc <100 <1.0 <1.0 <1.0 <1.0 <1.0
Hexachlorobutadiene <100 <1.0 <1.0 <1.0 <1.0 <1.0
lsonronulbcnzene <100 <1.0 <1.0 <1.0 <1.0 <1.0
o-1 sonronvl to! uene <100 <1.0 <1.0 <1.0 <1.0 <1.0
Mcthvlene chloride 14,000 <5.0 <5.0 <5.0 <5.0 <5.0
Mel11vl tcn-hutvl cl11er .<500 <5.0 <5.0 <5.0 · <5.0 <5.0
Nachllialenc <500 <5.0 <5.0 <5.0 <5.0 <5.0
n-Proovlhenzenc <100 <1.0 <1.0 <1.0 <1.0 <1.0
(contmued)
PIEDMONT GEOLOGIC, P. C. Page 7 of 10
MW-42 MW-42 MW-421
(1)
5/5/05 5/5/05 5/10/05
<1.0 <1.0 <1.0
<1.0 <1.0 <1.0
<1.0 <1.0 <1.0
<1.0 <1.0 . <1.0
<1.0 <1.0 <1.0
<1.0 <1.0 <1.0
<1.0 <1.0 <1.0
<1.0 <1.0 <1.0
<1.0 <1.0 <1.0
<1.0 <1.0 <1.0
<1.0 <1.0 <1.0
<1.0 <1.0 <1.0
<1.0 <1.0 <1.0
<1.0 <1.0 <1.0
<1.0 <LO· <1.0
<1.0 <LO <1.0
<1.0 <1.0 <1.0
<1.0 <1.0 <1.0
<1.0 <1.0 <1.0
<1.0 <1.0 <1.0
<1.0 <1.0 <1.0
<1.0 <1.0 <1.0
. <1.0 <1.0 <1.0
<1.0 <1.0 <1.0
<1.0 <1.0 <1.0
<1.0 <1.0 <1.0
<1.0 <1.0 <1.0
<1.0 <1.0 <1.0
<1.0 <1.0 <1.0
<1.0 <1.0 <1.0
<1.0 <1.0 <1.0
<5.0 <5.0 <5.0
<1.0 <1.0 <1.0
<1.0 <1.0 <1.0
<1.0 <1.0 <1.0
<1.0 <1.0 <1.0
<5.0 <5.0 <5.0
<5.0 <5.0 <5.0
<5.0 <5.0 <5.0 ·
<1.0 <1.0 <1.0
I
I
I
I
I
I
I
I
ii :.
' ii
:1
I
TABLE 2 (continued)
SUMMARIZED RESULTS OF LABORATORY ANALYSIS
GROUNDWATER SAMPLES COLLECTED MAY 2005
North Carolina State University
Lot 86 Site
Ralei~h. North Carolina
Sample I.D.: MW-37 MW-38 MW-40 MW-41 MW-411 MW-41D
Samnle Date: 5/13/05 5/5/05 5/10/05 5/5/05 5/5/05 5/10/05
SM Method 6230D (ug/L)
Stvrene <100 <1.0 <1.0 <1.0 <1.0 <1.0
1,1,1,2-Tetrachloroethane <100 <1.0 <1.0 <1.0 <1.0 <1.0
I, 1,2,2-Tetrachloroethane <100 <1.0 <1.0 <1.0 <1.0 <1.0
Tetrachloroethene 280 <1.0 <1.0 <1.0 <1.0 <1.0
1,2,3-Trichlorobenzene <100 <1.0 <1.0 <1.0 <1.0 <1.0
1,2,4-Trichlorobenzene <100 <1.0 <1.0 <1.0 <1.0 <1.0
I, I, I -Trichloroethane <100 <1.0 <1.0 <1.0 <1.0 <1.0
l, 1,2-Trichloroethane <100 <1.0 <1.0 <1.0 <1.0 <1.0
Trichloroethene 970 <1.0 <1.0 <1.0 <1.0 <1.0
Trichloroflouromethane <100 <1.0 <1.0 <1.0 <1.0 <1.0
1,2,3-Trichloronronane <100 <1.0 <1.0 <1.0 <1.0 <1.0
1,2,4-Trimethv !benzene <100 <1.0 <1.0 <1.0 <1.0 <1.0
1,3,5-Trimethvlbenzene <100 <1.0 <1.0 <1.0 <1.0 <1.0
Toluene <500 <5.0 <5.0 <5.0 <5.0 <5.0
Vinv! chloride <100 <1.0 <1.0 <1.0 <1.0 <1.0
Xvlenes 300 <3.0 <3.0 <3.0 <3.0 <3.0
EPA Method 6010 (mg/L)
Arsenic <0.02 <0.02 <0.02 <0.02 <0.02 <0.02
Barium 0.17 0.017 0.014 0.03 0.022 0.0067
Cadium <0.005 <0.005 <0.005 <0.005 <0.005 <0.005
Chromium <0.01 <0.01 <0.01 <0.01 <0.01 <0.01
Iron <0.1 <0.1 <0.1 <0.1 <0.1 <0.1
Lead <0.005 <0.005 <0.005 <0.005 <0.005 <0.005
Man11anese 2.0 <0.01 0.05 0.039 0.035 0.01
Selenium <0.02 <0.02 <0.02 <0.02 <0.02 <0.02
Silver <0.01 <0.01 <0.01 <0.01 <0.01 <0.01
EPA Method 7470 (mg/L)
Mercurv <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002
EPA Method 8015 (mg/L)
Methane <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
Ethane <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
Ethene <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
EPA Method 300/9056 (mg/L)
Alkalinitv 37 84 23 46 18 17
Chloride 17 1.6 3.3 9.3 1.8 1.7
Nitrate <0.1 <0.1 0.73 1.0 0.2 <0.1
Sulfate <5.0 <5.0 <5.0 <5.0 <5.0 <5.0
SM Method 9060 (mg/L)
Total Or£anic Carbon 9.2 <1.0 <1.0 <1.0 <1.0 <1.0
PIEDMONT GEOLOGIC, P.C. Page 8 of 10
MW-42 MW-42 MW-421
(I)
5/5/05 5/5/05 5/10/05
<1.0 <1.0 <1.0
<1.0 <1.0 <1.0
<1.0 <1.0 <1.0
<1.0 <1.0 <1.0
<1.0 <1.0 <1.0
<1.0 <1.0 <1.0
<1.0 <1.0 <1.0
<1.0 <1.0 <1.0
<1.0 <1.0 <1.0
<1.0 <1.0 <1.0
<1.0 <1.0 <1.0
<1.0 <1.0 <1.0
<1.0 <1.0 <1.0
<5.0 <5.0 <5.0
<1.0 <1.0 <1.0
<3.0 <3.0 <3.0
<0.02 <0.02 <0.02
0.014 0.017 0.007
<0.005 <0.005 <0.005
<0.01 <0.01 <0.01
<0.1 <0.1 <0.1
<0.005 <0.005 <0.005
0.13 0.14 0.QJI
<0.02 <0.02 0.021
<0.01 <0.01 <0.01
<0.0002 <0.0002 <0.0002
<1.0 <1.0 <1.0
<1.0 <1.0 <1.0
<1.0 <1.0 <1.0
11 13 25
3.7 3.6 4.1
1.3 1.3 0.22
<5.0 <5.0 <5.0
<1.0 <1.0 2.1
I
I TABLE 2 (continued)
SUMMARIZED RESULTS OF LABORATORY ANALYSIS
GROUNDWATER SAMPLES COLLECTED MAY 2005
I North Carolina State University
Lot 86 Site
I Ralei h North Carolina
Sample I.D.: MW-43 MW-43D MW-45 MW-46 MW-47 FB-1 FB-2
(3) (4)
Sam le Date: 5/10/05 5/10/05 5/5/05 5/5/05 5/10/05 5/6/05 5/11/05 I SM Method 6230D (ug/L)
Benzene <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
Bromobcnzene <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 ii BromochloromeU1ane <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
Bromodichloromcthane <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 I .
I Bromoform <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 \I <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
<1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
' <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
' \I tert-But !benzene <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
Carbon tetrachloride <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
Chlorobcnzene <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
ii Chlorodibromomethane <1.0 <1.0 <1.0 <1.0 <LO <1.0 <LO
Chlorocthane <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
I Chloroform 11 2.1 <1.0 <1.0 I.I <1.0 <1.0 I I ChloromeUiane <1.0 <1.0 <1.0 <LO <1.0 <1.0 <1.0 I 2-Chlorotoluene <1.0 <1.0 <1.0 <1.0 <1.0 <LO <1.0
4-Chlorotoluene <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
I 1,2-Dihromo-3-chloro ro anc <LO <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 • 1,2-Dichlorobcnzene <1.0 <1.0 · <LO <1.0 <1.0 <1.0 <1.0
1,3-Dichlorobcnzenc <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 I 1,4-Dichlorobcnzenc <1.0 <1.0 <1.0 <1.0 <1.0 <LO <LO ..
I DichlorodiflouromeUiane <1.0 <1.0 <1.0 <1.0 <1.0 <LO <1.0 ,~ . -
I, I -DichloroeU1ane <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 --~ B4«• 1,2-Dichloroethane <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 :~· ,. ' I I, l-DichlorocU1cnc <1.0 ~D m
<1.0 <1.0 <1.0 <1.0 <1.0 <1.0
cis-1,2-DichlorocU1ene <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 ·~~ "'J'~ . ,,., ,,.,
trans-1,2-DichlorocU1enc <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
' <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 D <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
<1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 I
I <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0. ~ -.
m <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 ~ ~~
<1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 ~~ ~~m,
<1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 ~ -.
<1.0 <1.0 <1.0 <1.0 <1.0 ~ ~~ I <1.0 <1.0 . ' -~,:' .
<1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 ~ ~ .
<5.0 <5.0 il.!i/l .. ' -' I <5.0 <5.0 <5.0 <5.0 <5.0
I <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 w~~ I ,,..,.,.,'" .,
<5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 ~~,
I <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 tffi'=q:
I (continued) 11 I
I
I: PIEDMONT GEOLOGIC, P. C. Page 9 of IO I
I
I
I
I
I
I
:1 I
I ii
I
11
11
I
!I
'1
I
I
I I
I
I I
I I
I I
Sample I.D.:
Sam le Date:
SM Method 6230D (ug/L)
St ene
1, I, l ,2-Tetrachloroell1anc
1, 1,2,2-Tetrachloroelliane
Tetrachlorocthcnc
1,2,3-Tricblorobcnzene
1,2,4-Trichlorobcnzene
I, I, 1-Tricbloroelliane
I, 1,2-Trichloroelliane
. Vin I chloride
X lenes ·
EPA Method 6010 (mg/L)
Arsenic
Barium
Cadium
Chromium
Iron
Lead
Man ancse
Selenium
Silver
EPA Method 7470 (mg/L)
Mercur
EPA Method 8015 (mg/L)
Methane
Ethane
Ethcne
EPA Method 300/9056 (mg/L)
Alkalinit
Chloride
Nitrate
Sulfate
SM Method 9060 (mg/L)
Total Or anic Carbon
TABLE 2 (continued)
SUMMARIZED RESULTS OF LABORATORY ANALYSIS
GROUNDWATER SAMPLES COLLECTED MAY 2005
North Carolina State University
Lot 86 Site
Ralei h, North Carolina
MW-43 MW-431) MW-45 MW-46 MW-47 FB-1
(3)
5/10/05 5/10/05 5/5/05 5/5/05 5/10/05 5/6/05
<1.0 <1.0 <1.0 <1.0 <1.0 <1.0
. <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
<1.0 <1.0 <1.0 <1.0 <1.0 <1.0
<1.0 <1.0 <1.0 <1.0 <1.0 <1.0
<1.0 <1.0 <1.0 <1.0 <1.0 · <1.0
<1.0 <1.0 <1.0 <1.0 <1.0 <1.0
<1.0 <1.0 <1.0 <1.0 <1.0 <1.0
<1.0 <1.0 <1.0 <1.0 <1.0 <1.0
<1.0 <1.0 <1.0 <1.0 <1.0 <1.0
<1.0 <1.0 <1.0 <1.0 <1.0 <1.0
<1.0 <1.0 <1.0 <1.0 <1.0 <1.0
<1.0 <1.0 <1.0 <1.0 <1.0 <1.0
<1.0 <1.0 <1.0 <1.0 <1.0 <1.0
<5.0 <5.0 <5.0 <5.0 <5.0 <5.0
<1.0 <1.0 <1.0 <1.0 <1.0 <1.0
<3.0 <3.0 <3.0 <3.0 <3.0 <3.0
<0.02 <0.02 <0.02 <0.02 <0.02 <0.02
0.02 0.013 0.027 0.041 0.025 0.011
<0.005 <0.005 <0.005 <0.005 <0.005 <0.005
<0.01 <0.01 0.029 0.018 <0.01 <0.01
<0.1 <0.1 0.1 0.12 <0.1 <0.1
<0.005 <0.005 <0.005 <0.005 <0.005 <0.005
0.019 0.31 0.18 0.37 0.42 <0.01
<0.02 <0.02 <0.02 <0.02 <0.02 <0.02
<0.01 <0.01 <0.01 <0.01 <0.01 <0.01
<0.0002 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002
<1.0 <1.0 <1.0 <1.0 <1.0 <1.0
<1.0 <1.0 <1.0 <1.0. <1.0 <1.0
<1.0 <1.0. <1.0 <1.0 <1.0 <1.0
17 23 14 12 27 120
1.7 1.9 3.0 5.9 1.9 <1.0
<0.1 <0.1 <0.1 1.7 <0.1 <0.1
<5.0 <5.0 <5.0 <5.0 <5.0 <5.0
<1.0 <1.0 <1.0 <1.0 <1.0 <1.0
(!) Duplicate san1ple; labeled "MW-60" in chain of custody and laboratory report.
(2) Duplicate sample; labeled "MW-61" in chain of custody and laboratory report.
(3) Field rinseate blank; labeled "MW-62" in chain or custody and laboratory report.
(4) Field rinscate blank; labeled "MW-63" in chain of custody and lahoratory report.
PIEDMONT GEOLOGIC, P.C Page IO of 10
FB-2
(4)
5/11/05
<1.0
<1.0
<1.0·
<1.0
<1.0
<1.0
<1.0
<1.0
. <1.0
<1.0
<1.0
<1.0
<1.0
<5.0
<1.0
<3.0
<0.02
<0.005
<0.005
<0.01
<0.1
<0.005
<0.01
<0.02
<0.01
<1.0
<1.0
<1.0
<10
<1.0
<0.1
<5.0
<1.0
'\~
,_·~
. ·•·"""'"' ~~
----------------- - - - -- - -----TABLE 3 µvJ -\9? SUMMARIZED RESULTS OF FIELD ANALYSIS
GROUNDWATER SAMPLES COLLECTED MAY2005
North Carolina State University
Lot 86 Site
Raleh,h, North Carolina
Sample I.D.: MW-2,., MW-3 MW-6 v 'MW-8.,, MW-11 MW-111 MW-12 MW-121 MW-12D MW-13
Samole Date: 5/13/05 5/13/05 5/12/05 · 5/13/05 5/12/05 5/11/05 5/13/05 5/12/05 5/11/05 5/06/05
Field Analysis
oH 5.54 5.51 5.15 5.54 6.21 6.25 5.58 6.03 6.31 5.53
Temnerature (°C) 21.3 20.6 22.3 21.2 21.6 18.8 18.1 22.1 21.3 16.3
Soecific Conductance (umhos/cm) 518 145.9 155.9 40.3 49.5 173.6 151.2 49.9 162.7 178.2
Dissolved Oxv0 en (m2/L) 3.64 2.75 4.48 6.38 6.91 '07 2.96 4.61 5.19 8.47
Turbidity (NTlJ) 32.73 5.85 45.63 3.74 3.89 (NM.I 9.36 15.73 6.31 16.16
Samplel.D.: MW-13D MW-16 MW-161 MW-16D MW-17 MW-171 MW-17D MW-27 MW-29 MW-33
Sample Date: 5/10/05 5/13/05 5/11/05 5/10/05 5/12/05 5/12/05 5/12/05 5/10/05 5/6/05 5/6/05
Field Analysis
oH 6.39 5.72 6.05 7.63 6.54 6.15 8.56 5.57 5.76 5.78
Temnerature (°C) 19.2 21.2 19.8 19.3 23.2 19.1 19.3 20.7 17.0 15.3
Soecific Conductance (umhos/cm) 75.5 118.1 96.0 185.7 67.9. 24.7 135.1 40.4 32.1 67.4
Dissolved Oxv2en (m2/L) 4.91 d1 5.35 3.27 2.90 3.57 2.68 6.32 7.17 8.67 6.68
Turbiditv (NTU) 41.= 4.76 1019 86.40 26.52 4.69 21.18 88.95 157.1 6.61
Samplel.D.: ~1\V-34SR MW-34DR MW-35S MW-35D MW-36S MW-36D MW-37 MW-38 MW-40 MW-41
Sample Date: 5/11/05 5/10/05 5/6/05 5/13/05 5/13/05 5/12/05 5/13/05 5/5/05 5/10/05 5/5/05
Field Analysis
DH 5.45 6.11 5.61 6.57 5.33 6.14 5.28 6.92 5.19 5.30
Temoerature (°C) 19.1 18.9 15.2 17.9 21.6 23.2 18.7 18.9 18.6 19.7
Soecific Conductance (umhos/cm) 37.7 98.1 32.0 121.8 168.1 108.5 100.5 137.6 33.5 64.6
Dissolved Oxv0 en (m2/L) 8.90 7.02 6.83 2.75 5.13 5.36 5.28 5.61 10.08 8.05
Turbiditv (NTU) 51.98 50.42 221.1 102.4 32.-76 5.87 88.75 24.76 439.3 311.4
Sample I.D.: MW-411 MW-41D MW-42 MW-421 MW-43 MW-43D MW-45 _MW-46 MW-47
Sample Date: 5/5/05 5/10/05 5/5/05 5/10/05 5/10/05 5/10/05 5/5/05 5/5/05 5/10/05
Field Analysis
pH 5.58 6.31 5.44 6.22 5.50 5.84 6.16 5.28 6.28
Tem""rature (°C) 19.3 20.7 19.2 20.8 21.6 19.1 17.3 18.4 18.7
Snecific Conductance (umhos/cm) 28.8 49.5 40.2 78.5 34.2 57.2 37.2 45.6 62.4
Dissolved Oxvoen (mull ) 9.51 7.84 9.02 7.25 9.10 3.31 10.02 9.86 5.35
Oxidation Reduction Potential (mv) NM NM NM NM NM NM NM NM NM
Turbiditv (NTU) 55.49 11.73 150.6 14.36 99.64 8.62 49.78 163.9 54.88
NM = Not Measured
0 PIEDMON'F GEOLOGIC, P.C.
I
I
I
I
I
I
I
11
I
\I
11
' I
ii I
' I
'
I
I '
I I
I
PIEDMONT GEOLOGIC, P.C.
Report of' Results: May 2005 Groundwater Monitoring Event
North Carolina State University, Lot 86 Farm Unit No. I Site
June 15, 2005
APPENDIX A
GROUNDWATER SAMPLING FORMS
I
I
I
I
I
I
11
I !I
I
\I
:1
I
!I
111
!I I
'1
I I I
I
I
I
I
'
9
I I
I
'
GROUNDWATER SAMPLING FORM
CLIENT: NCSU PROJECT NAME: Lot 86GW
PROJECT LOCATION: Raleigh, NC . PROJECT NO.: 2519
SAMPLING PERSONNEL: J Ganey & S Satterthwaite
Welll.D.: MW-2 Well Tvne: Monitorino
Well Diameter (in.): 3 Reference Point: Too of Casinq
Elevation of Reference Point (ft.): 448.74 Well Gauging Meter: Heron lntertace Probe
Deoth to Water (ft.): 40.66 Depth to Bottom lft.1: 51.83
Water Column (ft.): 11.17x _0.37 _ gal/ft. = 4.13 gal
conversion factor 1 well volume
Three Well Volumes = 12.4 gal
Puroe Methoc: submersible oumo . Purqe Date: 5/13/05 I
Purqe Volume lnal.): 4.1 dn1 Purge Time: Start 0915 Ston 0918
Well Volumes Removed 1 2 3 4 5 6 7
nH 5.51
Temp. l'C) 18.1
Specific Conductance (umohs/cm\ 524
Dissolved Oxvaen (mg/L) 1.61
Sample Characteristics silty
Sample Date: 5/13/2005 Sample Methoc: bailer
Sample Time: 1100
Samele Containers Filled
No. Tvne Preservative Analvsis
1 500ml None Alkalinitv
1 125 ml None 9056 Chloride, Sulfate bv IC
2 40ml HCI Ethane, Ethene, Methane
2 40 ml HCI 6230D Volatiles
1 250ml None Iron, Dissolved
1 250ml HNO3 Manaanese, RCRA Metals
1 125 ml H2SO4 9056 Nitrate bv IC
1 250ml HCI TOC
Field Measurements of Sample:
lnH 5.54 Oakton nH/Con 10 Meter
Temo (' C) 21.3 Oakton oH/Con 10 Meter
SPecific Conductance (umohs/cm) 518 Oakton pH/Con 10 Meter
Dissolved Ownen (mall) 3.64 YSI Mocel 95 Meter
Turbidity (NTU) 32.73 Hach Ferrous Iron Kit
Sample Characteristics . clear .
Weather Conditions: Overcast; upper 60s
Remarks: Collected radiation sample (2 gal. sample container)
PIEDMONT GEOLOGIC, P.C.
I
I
I
I
I
I
ii
I 11 I
11
I
I
\I
I
I
11
\1
I
I
' I
I
I
I
I I
I
M
I
' n
GROUNDWATER SAMPLING FORM
CLIENT: NCSU PROJECT NAME: Lot 86GW
PROJECT LOCATION: Raleigh, NC PROJECT NO.: 2519
SAMPLING PERSONNEL: J Ganey & S Satterthwaite
Welll.D.: MW-19 Well Tvne: Monitorina
Well Diameter /in.I: 3 Reference Point: Top of Casino
Elevation of Reference Point (ft.): 445.39 Well Gauging Meter: Heron Interface Probe
Depth to Water (ft.): 38.74 Depth to Bottom (ft.): .
50.18
Water Column (ft.): 11.44 X ~0.37 _ gal/ft. = 4.23 gal
conversion factor 1 well volume
Three Well Volumes -12.7 gal
Puroe Method: submersible pump Puroe Date: 5/13/05
Purae Volume tnal.l: 4.2 dry Purae Time: Start 0946 Stop 0950
Well Volumes Removed 1 2 3 4 5 6 7
nH 5.86
Temp. <'C) 18.9
Soecific Conductance (umohs/cm) 141.7
Dissolved O,omen (mall) 4.81
Sample Characteristics clear
Sample Date: 5/13/2005 SamPle Method: bailer
Sample Time: 1145
Samele Containers Filled
No. Tvoe Preservative Analysis
1 500ml None Alkalinitv
1 125 ml None 9056 Chloride, Sulfate bv IC
2 40ml HCI Ethane, Ethene, Methane
2 40ml HCI 6230D Volatiles
1 250ml None Iron, Dissolved
1 250ml HN03 Manaanese, RCRA Metals
1 125 ml H2SO4 9056 Nitrate bv IC
1 250ml HCI TOC
Field Measurements of Samole:
□H 5.51 Oalkton pH/Con 10 Meter
Temp/° C) 20.6 Oalkton oH/Con 10 Meter
Soecific Conductance /umohs/cm) 145.9 Oalkton oH/Con 10 Meter
Dissolved Ownen (mail) 2.75 YSI Model 95 Meter
Turbiditv /NTUI 5.85 Hach Ferrous Iron Kit
Sample Characteristics clear
Weather Conditions: Overcast; upper 60s; slight breeze
Remarks: Collected radiation sample (2 gal. sample .container)
PIEDMONT GEOLOGIC, P.C.
't
I
I
I
I
I
I
I
I
!I
I
:1
I
\I
\I
I
:1
I
'
I
I I
I e I
' n
I
D
I
GROUNDWATER SAMPLING FORM
CLIENT: NCSU PROJECT NAME: Lot 86 GW
PROJECT LOCATION: Raleigh, NC PROJECT NO.: 2519
SAMPLING PERSONNEL: J Ganey & S Satterthwaite
Welll.D.: MW-6 Well Tvne: Monitorina
Well Diameter /in.): 3 Reference Point: Top of Casin<J
Elevation of Reference Point (ft.): 438.61 Well Gauging Meter: Heron Interface Probe
Deoth to Water (ft.): 33.95 Deoth to Bottom m.l: 43.66
Water Column (ft.): 9.71 X _0.37 _gal/ft. = 3.59 gal
conversion factor 1 well volume
Three Well Volumes = 10.8 gal
Purae Method: bailer Pur□e Date: 5/11/05
Pur□e Volume foal.): 10 Purae Time: Start 1607 Stoo 1646
Well Volumes Removed 1 2 3 4 5 6 7
nH 5.38 5.25 5.24
Temo. {°C) 18.8 18.7 18.1
Soecific Conductance (umohs/cml 146.1 143.6 141.5
Dissolved Ownen (moil) 2.60 2.68 3.83
Sample Characteristics silty silty silty
Same le Date: 5/12/2005 Samole Method: bailer
Same le Time: 1215
Sam□le Containers Filled
No. Tv□e Preservative Analysis
1 500ml None Alkalinitv
1 125 ml None 9056 Chloride, Sulfate bv IC
2 40 ml HCI Ethane, Ethene, Methane
2 40ml HCI 6230D Volatiles
1 250ml Nooe Iron, Dissolved
1 250ml HNO3 Manaanese, RCRA Metals
1 125 ml H2SO4 9056 Nitrate bv IC
1 . 250ml HCI TOG
Field Measurements of Samele:
,H 5.15 Oaikton □H/Con 1 O Meter
Temo (' Cl 22.3 Oaikton oH/Con 1 O Meter
Soecific Conductance (umohsicm) 155.9 Oaikton oH/Con 1 O Meter
Dissolved o~men fm□/Ll 4.48 YSI Model 95 Meter
Turbiditv (NTUl 45.63 Hach Ferrous Iron Kit
Samele Characteristics s. cloudy
Weather Conditions: Sunny; low 80s; calm
Remarks:
PIEDMONT GEOLOGIC, P.C.
I
I
I
I
I
I
:I
I
!I
I
\I
I
11
I
II
I
I
I
I
I
I
I
I
!
m
I
u
I
0
I
m
GROUNDWATER SAMPLING FORM
CLIENT: NCSU PROJECT NAME: Lot86GW
PROJECT LOCATION: Raleigh, NC PROJECT NO.: 2519
SAMPLING PERSONNEL: J Ganey & S Satterthwaite
Well I.D.: MW-8 Well T vne: Monitorino
Well Diameter (in.): 3 Reference Point: Too of Casino
Elevation of Reference Point (fl.\: 447.85 Well Gauging Meter: Heron lntertace Probe
Deeth to Water (ft.\: 39.44 Deeth to Bottom (ft.\: 53.30
Water Coiumn (ft.): 13.86 X ~0.37 _ gaVft. = 5.13 gal
conversion factor 1 well volume
Three Well Volumes = 15.4 gal
Purae Methoc: bailer Purae Date: 5/12/05 I
Purne Volume rnal.): 15 Purne Time: Start 1406 Stnn 1517
Well Volumes Removed 1 2 3 4 5 6 7
oH 6.35 5.72 5.83
Temo. (°C\ 20.0 19.6 20.0
Seecific Conductance rumohs/cm\ 50.2 43.3 45.5
Dissolved O=nen (mall) 5.63 4.46 4.21
Same le Characteristics clear clear clear
Samele Date: 5/13/2005 Samele Methoc: bailer
Samele Time: 0830
Samnle Containers Filled
No. Tvee ~,eservative Analysis
1 500ml None Alkalinilv
1 125 ml . None 9056 Chloride, Sulfate bv IC
2 40ml HCI Ethane, Ethene, Methane
2 40ml HCI 6230D Volatiles
1 250ml None Iron, Dissolved
1 250ml HNO3 Manaanese, RCRA Metals
1 125 ml H2SO4 9056 Nitrate bv IC
1 250 ml HCI TOC
Field Measurements of Samole:
oH 5.54 Oakton pH/Con 1 O Meter
Teme (° C) 21.2 Oakton eH/Con 10 Meler
Soecific Conductance (umohs/cml 40.3 Oakton oH/Con 10 Meter
Dissolved Ownen (mail) 6.38 YSI Mocel 95 Meter
Turbiditv fNTU\ 3.74 Hach Ferrous Iron Kit
Sample Characteristics clear
Weather Conditions: Overcast; mid 60s; calm
Remarks:
PIEDMONT GEOLOGIC, P.C.
I
I
I
I
I
I
I
I
I
H I
'
GROUNDWATER SAMPLING FORM
CLIENT: NCSU PROJECT NAME: Lot86 GW
PROJECT LOCATION: Raleigh, NC PROJECT NO.: 2519
SAMPLING PERSONNEL: J Ganey & S Satterthwaite
Well I.D.: MW-11 Well Tvne: Monitorina
Well Diameter fin.): 4 Reference Point: Too of Casino
Elevation of Reference Point (ft.): 430.01 Well Gauging Meter: Heron Interlace Probe
Depth to Water (ft.): 19.98 Denth to Bottom (ft.): 29.44
Water Column (ft.): 9.46 X ~0.65_ gal/ft. = 6.15gal
conversion factor 1 well volume
Three Well Volumes -18.4 gal
Puroe Method: submersible oump Purae Date: 5/11 /05 I
Purae Volume lnal.): 6.1 drv Puroe Time: Start 1429 Stop 1439
Well Volumes Removed 1 2 3 4 5 6 7
nH 6.75
Temo. (°C) 19.9
Specific Conductance (umohs/cm) 48.6
Dissolved Ownen (moll\ 7.30
Sample Characteristics clear
Sample Date: 5/12/2005 Samole Method: bailer
Samnle Time: 1047
Samele Containers Filled
No. Tvne Preservative Analvsis
1 500ml None Alkalinity
1 125 ml None 9056 Chloride, Sulfate by IC
2 40ml HCI Ethane, Ethene, Methane
2 40ml HCI 6230D Volatiles
. 1 250ml None Iron, Dissolved
1 250ml HNO3 Manoanese, RCRA Metals
1 125 ml H2SO4 9056 Nitrate bv IC
1 250ml HCI TOC
Field Measurements of Samele:
nH 6.21 Oakton pH/Con 10 Meter
Temo (° C) 21.6 Oakton oH/Con 10 Meter
Soecific Conductance fumohs/cm) 49.5 Oakton PH/Con 10 Meter
Dissolved O=nen (moil) 6.91 YSI Model 95 Meter
Turbidity (NTU) 3.89 Hach Ferrous Iron Kit
Sample Characteristics clear
Weather Conditions: Sunny; mid-upper 70s; slight breeze
Remar1<s:
PIEDMONT GEOLOGIC, P.C.
I
I
I
I
I
I
,1
\1
I
\I
!1
I
!I
\1
I
ii
'
11
I
I
I
I
I
I
i
I
!
GROUNDWATER SAMPLING FORM
CLIENT: NCSU PROJECT NAME: Lot86GW
PROJECT LOCATION: Raleigh, NC PROJECT NO.: 2519
SAMPLING PERSONNEL: J Ganey
Welll.D.: MW-11I Well Tvne: Monitorina
Well Diameter {in.): 2 Reference Point: Too of Casino
Elevation of Reference Point (ft.): 434.29 Well Gauaina Meter: Heron lntertace Probe
Deoth to Water /ft.\: 24.86 Death to Bottom /ft.\: 67.52
Water Column (ft.): 42.66 X ~0.16_ gal/ft. = 6.83 gal
conversion faclor 1 well volume
Three Well Volumes = 20.5 gal
Purae Method: submersible oumo Puroe Date: 5/11/05 I
Purne Volume /nal.): 20.5 Pur□eTime: Start 1205 Stop 1218
Well Volumes Removed 1 2 3 4 5 6 7
nH 6.23 6.26 6.32
Temp. (°C) 19.1 18.7 18.8
Snecific Conductance {umohs/cm) 159.5 171.8 176.5
Dissolved Ownen /mail\ 1.17 1.81 1.25
Sample Characteristics clear clear clear
Sample Date: 5/11/2005 Samnle Method: bailer
Samole Time: 1233
Same le Containers Filled
No. Tvoe Preservative Analysis
1 500 ml None Alkalinitv
1 125 ml None 9056 Chloride, Sulfate by IC
2 40 ml HCI Ethane, Ethene, Methane
2 40ml HCI 6230D Volatiles
1 250 ml None Iron, Dissolved
1 250ml HNO3 Manoanese, RCRA Metals
1 125 ml H2SO4 9056 Nitrate by IC
1 250ml HCI TOG
Field Measurements of Samole:
aH 6.25 Oakton pH/Con 10 Meter
Terna(° C) 18.8 Oakton aH/Con 1 O Meter .
Specific Conductance (umohs/cm) 173.6 Oakton aH/Con 1 O Meter
Dissolved Ownen (moil) 3.07 YSI Model 95 Meter
Turbiditv /NTU\ Hach Ferrous Iron Kit
Sample Characteristics clear
Weather Conditions: Sunny; low 80s; calm
Remarks:
PIEDMONT GEOLOGIC, P.C.
I
I
I
I
I
I
\1
I
ii
\I
I
I
I I I
I
I
I I
I
I
I
I I
I
I
GROUNDWATER SAMPLING FORM
.
CLIENT: NCSU PROJECT NAME: Lot 86GW
PROJECT LOCATION: Raleigh, NC PROJECT NO.: 2519
SAMPLING PERSONNEL: J Ganey & S Satterthwaite
Well I.D.: MW-12 Well Tune: Monitorina
Well Diameter.fin.\: 4 Reference Point: Too of CasinQ
Elevation of Reference Point (ft.): 427.24 Well Gauging Meter: Heron lntertace Probe
Deeth to Waler /fl.\: 22.5 Den th lo Bottom /ft.): 34.38
Water Column (ft.): 11.88 X _0.65_ gaVft. = 7.72 gal
conversion factor 1 well volume
Three Well Volumes -23.2 gal
Purae Method: submersible pump Purae Date: 5/13/05 I
Purae Volume lnal.l: 7.7 drv Purce Time: Start 1111 Stoe 1116
Well Volumes Removed 1 2. 3 4 5 6 7
"H 5.33
Teme. /°C\. 17.4
Seecific Conductance /umohs/cm\ 162.6
Dissolved O,vnen /mo/Ll 1.37
Sample Characteristics s. cloudy
Samele Date: 5/13/2005 Samele Method: bailer
Samele Time: 1300
Samole Containers Filled
No. Tvne Preservative Analvsis .
1 . 500 ml None Alkalinity
1 125 ml None 9056 Chloride, Sulfate by IC
2 40 ml HCI Ethane, Ethene, Methane
2 40ml HCI 6230D Volatiles
1 250ml None Iron, Dissolved
1 250ml HNO3. Manoanese, RCRA Metals
1 125 ml H2SO4 9056 Nitrate bv IC
1 250ml HCI TOC
Field Measurements of Sample:
nH 5.58 Oakton oH/Con 1 O Meter
Temp{° Cl 18.1 Oakton pH/Con 10 Meter
Snecific Conductance (umohs/cm) 151.2 Oakton oH/Con 1 O Meter .
Dissolved o~,nen (moll\ 2.96 YSI Model 95 Meter
Turbiditv /NTU\ 9.36 Hach Ferrous Iron Kit
Sample Characteristics clear
Weather Conditions: Overcast; mid 60s; calm
Remarks: Collected MS/MSD Sample
PIEDMONT GEOLOGIC, P.C.
I
I
I
I
I
I
:1
!1
I ii
I
\I
ii
!1
i ii I
' ii
I
I
' ' I
I
I
=g
I I
GROUNDWATER SAMPLING FORM
CLIENT: NCSU PROJECT NAME: Lot86GW
PROJECT LOCATION: Raleigh, NC PROJECT NO.: 2519
SAMPLING PERSONNEL: J Ganey & S Satterthwaite
Well I.D.: MW-12I Well Tvne: Monitorina
Well Diameter (in.): 2 Reference Point: ·Ton of CasinQ
Elevation of Reference Point (ft.): 430.70 Well Gauging Meter: Heron Interface Probe
Deoth to Water (ft.\: 25.04 Deoth to Bottom (ft.\: 72.99
Water Column (fl.): 47.95 X _0.16_ gal/ft. = 7.67 gal
conversion factor 1 well volume
Three Well Volumes = 23.0 gal
Purae Method: submersible oumo Purqe Date: 5/11/05 I
Purae Volume (qal.): 7.7 dr. Purge Time: Start 1500 Stop 1510
Well Volumes Removed 1 2 3 4 5 6 7
DH 6.19 -
Temp. (°C) 19.1
Specific Conductance (umohs/cm\ 45.6
Dissoived O=nen (mg/L) 1.69
Sample Characteristics siltv
Samr le Date: 5/12/2005 Sample Method: baller
Samr le Time: 1114
SamDle Containers Filled
No. Tvne Preservative Analysis
1 500ml None Alkalinitv
1 125 ml None 9056 Chloride, Sulfate bv IC
2 40 ml HCI Ethane, Ethene, Methane
2 40ml HCI 6230D Volatiles
1 250 ml None Iron, Dissolved
1 . 250ml HNO3 Manaanese, RCRA Metals
1 125 ml H2SO4 9056 Nitrate bv IC
1 250ml HCI TOC
Field Measurements of Samele:
DH 6.03 Oakton DH/Con 1 O Meter
TemD(°C) 22.1 Oakton oH/Con 10 Meter
Soecific Conductance (umohs/cm\ 49.9 Oakton nH/Con 10 Meter
Dissolved Oxvnen (m!liL) 4.61 YSI Model 95 Meter
Turbidity (NTU) 15.73 Hach Ferrous Iron Kit
Sample Characteristics clear
Weather Conditions: Sunny; upper?Os;breezy
Remarks:
PIEDMONT GEOLOGIC, P.C.
I
I
I
I
I
I
I
11
I :1
I I 11
I
11
I
11
I
11
I
ii I I
11
I
I
I I
I I
m I
I
I
GROUNDWATER SAMPLING FORM
CLIENT: NCSU PROJECT NAME: Lot86GW
PROJECT LOCATION: Raleigh, NC PROJECT NO.: 2519
SAMPLING PERSONNEL: J Ganey
Welll.D.: MW-12D Well Tvoe: Monitorina
Well Diameter (in.): 2 Reference Point: Too of Casino
Elevation of Reference Point (ft.): 427.45 Well Gauging Meter: Heron lntertace Probe
Depth to Water (ft.): 19.82 Depth to Bottom /fl.\: 107.00
Water Column (ft.): 87, 18 X _0.16_ gal/fl. = 13.95gal
conversion factor 1 well volume
Three Well Volumes = 41.8gal
Purae Method: submersible oumo Purge Date: 5/11 /05 I
Purae Volume lnal. ): 13.9 dn Puroe Time: Start 1048 Stop 1111
Well Volumes Removed 1 2 3 4 5 6 7
oH 6.17
Temp. r°C) 19.5
Specific Conductance (umohs/cm\ 164.1
Dissolved Oxvaen (mg/L) 3.64
Sample Characteristics clear
Sam, le Date: 5/11/2005 Sample Method: bailer
Sample Time: 1123
Samele Containers Filled
No. Tvne Preservative Analvsis
1 500ml None Alkalinitv
1 125 ml None 9056 Chloride, Sulfate bv IC
2 40ml HCI Ethane, Ethene. Methane
2 40ml HCI 6230D Volatiles
1 250ml None Iron, Dissolved
1 250ml HNO3 Manoanese, RCRA Metals
1 125 ml H2SO4 9056 Nitrate by IC
1 250ml HCI TOG
Field Measurements of Sarni: le:
oH 6.31 Oakton PH/Con 10 Meter
Temp(° Cl 21.3 Oakton nH/Con 10 Meter
Soecific Conductance (umohs/cm) 162.7 Oakton oH/Con 10 Meter
Dissolved Ownen (ma/Ll 5.19 YSI Model 95 Meter
Turbiditv (NTU) 6.31 Hach Ferrous Iron Kit
Sample Characteristics clear
Weather Conditions: Sunny; upper 70s; calm
Remarks: Collected Field Blank #2 (MW-63)
PIEDMONT GEOLOGIC, P.C.
I
I
I
I
I
I
I
I
I
\1
I
ii
I
1,1
I
\1
i
'.I
I
'1
I
I
I I
I
D I '
D
I
I I
I
GROUNDWATER SAMPLING FORM
CLIENT: NCSU PROJECT NAME: Lot 86 GW
PROJECT LOCATION: Raleigh, NC PROJECT NO.: 2519
SAMPLING PERSONNEL: J Ganey
Well I.D.: MW-13 Well Tvoe: Monitorina
Well Diameter (in.l: 4 Reference Point: Too of Casina
Elevation of Reference Point (ft.): 423.82 Well Gauging Meter: Heron Interface Probe
Depth to Water (ft.): 26.68 Depth to Bottom fft.1: 31.11
Water Column (ft.): 4.43 X _o.65_ gavft. = 2.88 gal
conversion factor 1 well volume
Three Well Volumes = 8.6 gal
Purae Method: sUbmersible cum□ Purge Date: 5/05/05
Purae Volume rnal.): 3.0 drv Puroe Time: Start 1459 Stoo 1505
Well Volumes Removed 1 2 3 4 5 6 7
. nH 4.96
Temp. (°C) 18.1
Specific Conductance (umohs/cm\ 172.2
Dissolved O"men (mg/L) 8.25
Sample Characteristics clear
Sample Date: 5/6/2005 Same le Method: baller
Sample Time: 0849
Sam, le Containers Filled
No. Tvpe Preservative Analvsis
1 500ml None Alkalinitv
1 125 ml None 9056 Chloride, Sulfate bv IC
2 40ml HCI Ethane, Ethene, Methane
2 40ml HCI 6230D Volatiles
1 250ml None Iron, Dissolved
1 250ml HNO3 Manaanese, RCRA Metals
1 125 ml H2SO4 9056 Nitrate bv IC
1 250ml HCI TOG
Field Measurements of Sample:
oH 5.53 Oakton aH/Con 1 O Meter
Temp(° C) 16.3 Oakton pH/Con 10 Meter
Soecific Conductance (umohs/cm) 178.2 Oakton oH/Con 10 Meter
Dissolved Ownen (mq/L) 8.47 YSI Model 95 Meter
Turbidity (NTU) 16.16 Hach Ferrous Iron Kit
Sample Characteristics clear
Weather Conditions: Rainy; low 50s; breezy .
Remarks:
PIEDMONT GEOLOGIC, P.C.
I
I
I
I
I
I
I
I
I
I
I
I
I
I
\I I
\1 I II
I
I
GROUNDWATER SAMPLING FORM
CLIENT: NCSU PROJECT NAME: Lot 86 GW
PROJECT LOCATION: Raleigh, NC PROJECT NO.: 2519
SAMPLING PERSONNEL: J Ganey
Well I.D.: MW-13D Well Tvne: Monitorino
Well Diameter <in.): 2 Reference Point: Tnn of Casina
Elevation of Reference Point (ft.): 423.43 Well Gauging Meter: Heron Interface Probe
De□th to Water (ft.): 26.38 De□th to Bottom (fl.): 100.00
. · Water Column (ft.): 73.62 X ~0.16 _ gaVft. = 11.78 gal
conversion factor 1 well volume
Three Well Volumes -35.3 gal
Purae Method: submersible oump Purae Date: 5/09/05
Purae Volume lnal.): 23.6 Purae Time: Start 1041 Stoo 1058
.
Well Volumes Removed 1 2 3 4 5
nH 5.88 5.92 .
Temp. (°C) 18.9 19.1
Soecific Conductance (umohslcm) 74.9 69.6
Dissolved Ow0 en lmQ/L) 2.01 5.32
Sample Characteristics s. cloudy clear
Samole Date: 5/1012005 Samnle Method: bailer
Sam□le Time: 0945
Samele Containers Filled
No. Tvne Preservative Analvsis
1 500ml None Alkalinity
1 125 ml None 9056 Chloride, Sulfate by IC
2 40ml HCI Ethane, Ethene, Methane
2 40ml HCI 6230D Volatiles
1 250ml None Iron, Dissolved
1 250ml HNO3 Manaanese, RCRA Metals
1 125 ml H2SO4 9056 Nitrate bv IC
1 250ml HCI TOG
Field Measurements of Sample:
DH 6.39 Oakton oH/Con 1 O Meter
Temo (° C) 19.2 Oakton oH/Con 1 o Meter
Soecific Conductance lumohs/cm) 75.5 Oakton □H/Con 10 Meter
Dissolved O=nen (mall) 4.81 YSI Model 95 Meter
Turbiditv INTU) 41.69 Hach Ferrous Iron Kit
Sample Characteristics clear
Weather Conditions: Sunny; mid 50s; breezy
Remarks:
I I PIEDMONT GEOLOGIC, P.C.
I ;
.
6 7
I
I
I
I
I
I
I
I
I
I
I
I
I
:1
:1
I
\I
I
\I
!
I
GROUNDWATER SAMPLING FORM
CLIENT: NCSU PROJECT NAME: Lot86GW
PROJECT LOCATION: Raleigh, NC PROJECT NO.: 2519
SAMPLING PERSONNEL: J Ganey & S Satterthwaite
Welll.D.: MW-16 Well Tvne: Monitorina
Well Diameter lin.): 3 Reference Point: Top of Casino
Elevation of Reference Point (ft.): 427.94 Well Gauging Meter: Heron lntertace Probe
Deoth to Water /It.\: 19.27 Deoth to Bottom /ft.\: 32.75
Water Column (ft.): 13.48 X ~0.37 _ gal/ft. = 4.99 gal
conversion.factor 1 well volume
Three Well Volumes = 15.0 gal
Purae Method: bailer Purne Date: 5/12/05 I
Pur□ e Volume /aal.\: 15 Purae Time: Start 1415 Stop 1520
Well Volumes Removed 1 2 3 4 5 6 7
oH 6.25 5.61 6.04
Temo. (°C) 19.7 19.5 19.3
Soecific Conductance (umohs/cm) 125.0 128.8 124.9
Dissolved O=0 en /mall\ 3.05 2.86 2.09
Sample Characteristics s. cloudv clear clear
Samole Date: 5/13/2005 Samole Method: bailer
Samole Time: 0915
Samnle Containers Filled
No. Tvoe Preservative Analysis
1 500ml None Alkalinitv
1 125 ml None 9056 Chloride, Sulfate bv IC
2 40ml HCI Ethane, Ethene, Methane
·2 40ml HCI 6230D Volatiles
1 250ml None Iron, Dissolved
1 250 ml HNO3 Manoanese, RCRA Metals
1 125 ml H2SO4 9056 Nitrate bv IC
1 250ml HCI TOG '
Field Measurements of Sample:
nH 5.72 Oakton oH/Con 1 O Meter
Temo (° C) 21.2 Oakton oH/Con 1 O Meter
Saecific Conductance (umohs/cm) 118.1 Oakton oH/Con 1 O Meter
Dissolved o~'"en /mall\ 5.35 YSI Model 95 Meter
Turbiditv INTU\ 4.76 Hach Ferrous Iron Kit
Sample Characteristics clear
Weather Conditions: Overcast; .mid 60s; slight breeze
Remarks:
PIEDMONT GEOLOGIC, P.C.
I '
I
I
I
I
I
I
I
I
I
I
I
I
I
I
ii
I
;1
ii
I
GROUNDWATER SAMPLING FORM
CLIENT: NCSU PROJECT NAME: Lot 86 GW
PROJECT LOCATION: Raleigh, NC PROJECT NO.: 2519 .
SAMPLING PERSONNEL: J Ganey
Well I.D.: MW-16I Well T vne: Monitonna .
Well Diameter (in.): 2 Reference Point: Too of Casino
Elevation of Reference Point (fl.): 432.14 Well Gauging Meter: Heron Interface Probe
Deoth to Water /ft.\: 23.52 Deoth to Bottom ltt. l: 64:54
Water Column (ft.): 41.02 X ~0.16_ gal/fl. = 6.56 gal
conversion laclor 1 well volume
Three Well Volumes = 19.7 gal
Purae Methoc: submersible pump Purae Date: 5/11 /05
Purae Volume 1nal.): 19.7 PuraeTime: Start 1000 Stop 1021
Well Volumes Removed 1 2 3 4 5 6 7
nH 5.75 5.82 5.88
Temp. ('Cl 18.6 18.7 19.0
S□ecific Conductance (umohs/cm) 102.7 99.9 97.2 .
Dissolved Ownen /mall\ 3.41 2.48 2.07
Sample Characteristics silty silty silty
Sam□le Date: 5/11/2005 Sam□le Methoc: bailer
Samole Time: 1031
Samnle Containers Filled .
No. Tv□e Preservative Analysis
1 500ml None Alkalinitv
1 125 ml None 9056 Chloride, Sulfate bv IC
2 40ml HCI Ethane, Ethene. Methane
2 40 ml HCI 6230D Volatiles
1 250ml None lron,'Dissolved
1 250ml HNO3 Manaanese, RCRA Metals
1 . 125 ml H2SO4 9056 Nitrate by IC
1 250ml HCI TOC
Field Measurements of .Samele:
□H 6.05 Oak ton pH/Con 1 O Meter
Temp/° Cl 19.8 Oakton □H/Con 1 O Meter
Soecific Conductance /umohs/cml 96 Oakton oH/Con 10 Meter
Dissolved Ownen /ma/Ll 3.27• YSI Mocel 95 Meter
Turbiditv /NTU\ 1019 Hach Ferrous Iron Kit
Sample Characteristics· silty
Weather Conditions: Sunny; low 70s; slight breeze
Remarks:
PIEDMONT GEOLOGIC,. P.C.
I
I
I
I
I
I
I
I
I
I
\1
:I
\1
I
'
I
M
I
GROUNDWATER SAMPLING FORM
CLIENT: NCSU PROJECT NAME: Lot 86 GW
PROJECT LOCATION: Raleigh, NC PROJECT NO.: 2519
SAMPLING PERSONNEL: J Ganey
Welll.D.: MW-16D Well T""'e: MonitorinQ
Well Diameter /in.\: 2 Reference Point: Tl'V\ of CasinA
Elevation of Reference Point (ft.): 428.98 Well Gauging Meter: Heron lntertace Probe
Deoth to Water lft.): 21.18 Denth to Bottom {ft.): 90.00
Water Column (ft.): 68.82 X _0.16 -gal/ft. = 11.01 gal
conversion factor 1 well volume
Three Well Volumes = 33.0 gal
Purae Method: submersible oumo . Purae Date: 5/09/05
Purne Volume I nal.): 11 drv Puroe Time: Start 1108 Stop 1123
Well Volumes Removed 1 2 3 4 5
nH 11.34
Temp. (°C) 18.6
S□ecific Conductance {umohs/cm) 93.2
Dissolved Ownen (mail\ 2.29
Sample Characteristics clear
Samnle Date: 5/10/2005 Samnle Method: baller
Samole Time: 1053
Samele Containers Filled
No. Tvne Preservative Analvsis
1 500ml None Alkalinity
1 125 ml None 9056 Chloride, Sulfate by IC
2 40ml HCI Ethane, Ethene, Methane
2 40ml HCI 6230D Volatiles
1 250ml None Iron, Dissolved
1 250ml HNO3 Manaanese, RCRA Metals
1 125 ml . H2SO4 9056 Nitrate bv IC
1 250ml HCI TOG
Field Measui-ements of Sample:
nH 7.63 Oak ton oH/Con 10 Meter
Tern□(° C\ 19.3 Oakton oH/Con 1 O Meter
Soecific Conductance (umohs/cm) 185.7 Oakton □H/Con 1 O Meter
Dissolved O=nen /mail\ 2.9 YSI Model 95 Meter
Turbiditv INTU\ 86.40 Hach Ferrous Iron Kit
Sample Characteristics s. cloudy
Weather Conditions: Sunny;upper50s; breeTI•
Remarks:
D PIEDMONT GEOLOGIC, P.C,
I
6 7
I
I
I
I
I
I
I
I
I
I
I
I
I
I
11
I
!1
I
'
'
::.1
I
GROUNDWATER SAMPLING FORM
CLIENT: NCSU PROJECT NAME: Lot86 GW
PROJECT LOCATION: Raleigh, NC PROJECT NO.: 2519
SAMPLING PERSONNEL: J Ganey & S Satterthwaite
. Welll.D.: MW-17 Well T vne: Monitorinn
Well Diameter /in.\: 2 Reference Point: Too of Casino
Elevation of Reference Point (ft.): 425.09 Well Gauging Meter: Heron lntertace Probe
D""th to Water (ft.\: 23.77 Deoth to Bottom lft.\: 31.49
Water Column (ft.): 7.72 X _0.16_gal/ft. = 1.24 gal
conversion factor 1 well volume
Three Well Volumes -3.7 gal
Purne Method: submersible pump Purqe Date: 5/1 1/05
Purae Volume lnal.\: 1.2 div Purge Time: Start 1327 Stoo ·1330
Well Volumes Removed 1 2 3 . 4 5 6 7
nH 6.21
Tern□. ('C) 19.6
S□ecific Conductance lumohs/cm\ · 64.3
Dissolved O=•0 en (mnlL) 1.49
Sample Characteristics s. cloudy
Sam□le Date: 5/12/2005 Same le Method: bailer
· Samnle Time: 0855
Sam, le Containers Filled
No. Tvne Preservative Analvsis
1 500ml None Alkalinitv
1 125 ml None 9056 Chloride, Sulfate bv IC
2 40ml HCI Ethane, Ethene, Methane
2 40ml HCI 6230D Volatiles
1 250ml None Iron, Dissolved
1 250ml HNO3 Manaanese, RCRA Metals
1 125 ml H2SO4 9056 Nitrate bv IC
1 250ml HCI TOG
Field Measurements of Samole:
nH 6.54 Oakton □H/Con 10 Meter
Temp(' C) 23.2 Oakton □H/Con 10 Meter
Snecific Conductance rumohs/cm) 67.9 Oakton nH/Con 10 Meter
Dissolved o~men (mo/U 3.57 YSI Model 95 Meter
Turbiditv (NTU\ 26.52 Hach Ferrous Iron Kit
Sample Characteristics . · clear
Weather Conditions: Sunny; low-mid 70s; slight breeze
Remarks:
PIEDMONT GEOLOGIC, P.C.
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
:I
I
ii
I
11
GROUNDWATER SAMPLING FORM
.
CLIENT: NCSU PROJECT NAME: Lot86 GW
PROJECT LOCATION: Raleigh, NC PROJECT NO.: 2519
SAMPLING PERSONNEL: J Ganey & S Satterthwaite
Welll.D.: MW-171 Well Tvne: Monitorino
Well Diameter (in.): 2 Reference Point: Too of Casina
Elevation of Reference Point (ft.): 427.74 Well Gauging Meter: Heron Interface Probe
Deoth to Water lft.l: 26.39 Deoth to Bottom m.l: 63.26
Water Column (ft.): 36.87 X _0.16_ gaYft. = 5.90 gal
conversion factor 1 well volume
Three Well Volumes = 17.7 gal
Purae Meth<Xl: submersible oumo Puroe Date: 5/11/05 I
Purqe Volume lnal.): 17.7 Purge Time: Start 1336 Sloe 1359
Well Volumes Removed 1 2 3 4 5 6 7
nH 5.44 5.24 4.96
Temo. ('Cl 18.9 18.9 19.1
Soecific Conductance (umohs/cm) 22.8 23.1 23.0
Dissolved Oxvnen {mq/L) 1.65 1.13 1.04
Samele Characteristics clear clear clear
Samele Date: 5/12/2005 Same le Meth<Xl: bailer
Samele Time: 0945
Same le Containers Filled
No. Tvne Preservative An~lusis
1 500ml None Alkalinitv
1 125 ml None 9056 Chloride, Sulfate bv IC
2 40ml HCI Ethane, Ethane, Methane
2 40ml HCI 6230D Volatiles
1 250ml None Iron, Dissolved
1 250ml HNO3 Man□anese, RCRA Metals
1 125 ml H2SO4 9056 Nitrate bv IC
1 250ml HCI · TOG
Field Measurements of Sample:
DH 6.15 Oakton nH/Con 10 Meter
Tern □ (° Cl 19.1 Oakton oH/Con 10 Meter
Soecific Conductance (umohs/cm) 24.7 Oakton oH/Con 10 Meter
Dissolved Oxvaen {mq/L) 2.68 YSI M<Xlel 95 Meter
Turbiditv {NTUl 4.69 Hach Ferrous Iron Kit
Sample Characteristics clear
Weather Conditions: Sunny; low-mid 70s; slight breeze
Remarks:
PIEDMONT GEOLOGIC, P.C.
I
I
I
I
I
I
I
I
I
I
I
I
ii
I \I
GROUNDWATER SAMPLING FORM
CLIENT: NCSU PROJECT NAME: Lot86GW
PROJECT LOCATION: Raleigh, NC PROJECT NO.: 2519
SAMPLING PERSONNEL: J Ganey & S Satterthwaite
Welll.D.: MW-17D Well Tvne: Monitorina
Well Diameter fin.): 2 Reference Point: Too of Casino
Elevation of Reference Point (ft.): 425.44 Well Gauging Meter: Heron Interface Probe
Death to Water lft.): 24.05 Death ta Bottom /ft.\: 105.00
Water Column (ft.): 80.95 X _0.16_ gal/ft. = 12.95 gal
conversion factor 1 well volume
Three Well Volumes = 38.9 gal
Purae Method: submersible oumo Purae Date: 5/11/05
Purae Volume lnal.l: 13.0 drv Puroe Time: Start 1408 Stop 1421
Well Volumes Removed 1 2 3 4 5 6 7
□H 9.29
Temp. ('C) 19.1
Specific Conductance (umohs/cml 176.6
Dissolved o~,nen /mail) 5.83
Sample Characteristics clear
Samele Date: 5/12/2005 Sample Method: bailer
Same le Time: 1024
Samele Containers Filled
. No. Tvne Preservative Analvsis
1 500ml None Alkalinity
1 125 ml None 9056 Chloride, Sulfate bv IC
2 40 ml HCI Ethane, Ethene, Methane
2 40ml HCI 6230D Volatiles
1 250ml Non·e Iron, Dissolved
1 250ml HNO3 Manaanese, RCRA Metals
1 125 ml H2SO4· 9056 Nitrate bv IC
1 250 ml HCI TOG
Field Measurements of Sample:
>H 8.56 Oakton oH/Con 10 Meter
Temp(' Cl 19.3 Oakton pH/Con 1 O Meter
Soecific Conductance (umohs/cm) 135.1 Oakton oH/Con 10 Meter
Dissolved o~men Imo/LI 6.32 YSI Model 95 Meter
Turbiditv INTUI 21.18 Hach Ferrous Iron Kit
Sample Characteristics clear
Weather Conditions: Sunny; low-mid 70s; slight breeze
Remarks:
PIEDMONT GEOLOGIC, P.C.
I
I
I
I
I
I
I
I
I
I
I
I
GROUNDWATER SAMPLING FORM
CLIENT: NCSU PROJECT NAME: Lot 86GW
PROJECT LOCATION: Raleigh, NC PROJECT NO.: 2519
SAMPLING PERSONNEL: J Ganey
Welll.D.: MW-27 Well Tune: Monitorino
Well Diameter lin.l: 2 Reference Point: Tnn of Casina
Elevation of Reference Point (ft.): 448.26 Well Gauging Meter: Heron Interface Probe
Denth to Water (ft.): 38.52 Denth to Bottom (fl.): 45.94
Water Column (ft.): 7.42 X _o.16_gavtt. = 1.19 gal
conversion factor 1 well volume
Three Well Volumes -3.6 gal
Purae Method: submersible pump Purae Date: 5/09/05
Purae Volume lnal.l: 1.2 drv . Purce Time: Start 1448 Stoa 1455
Well Volumes Removed 1 2 3 4 5
nH 6.17
Terna. ('Cl 22.7
Saecific Conductance (umohs/cml 39.1
Dissolved O--"en (mq/L) 5.87
Samole Characteristics silty
Samole Date: 5/10/2005 Samole Method: baller
Samnle Time: 1444
Samele Containers Filled
No. Tvne Preservative An:,itvsis
1 500ml None Alkalinity
1 125 ml None 9056 Chloride, Sulfate by IC
2 40ml HCI Ethane, Ethene, Methane
2 40ml HCI 6230D Volatiles
1 250ml None Iron, Dissolved
1 250 ml HNO3 Manoanese, RCRA Metals
1 125 ml H2SO4 9056 Nitrate bv IC
1 250ml HCI TOC
Field Measurements of Sample:
,H 5.57 Oakton oH/Con 1 O Meter
Temo (' C) 20.7 Oakton pH/Con 1 O Meter
Soecific Conductance (umohs/cm) 40.4 Oakton oH/Con 10 Meter
Dissolved Ownen /ma/Ll 7.17 YSI Model 95 Meter
Turbiditv /NTUl 88.95 Hach Ferrous Iron Kit
Sample Characteristics s. cloudy
Weather Conditions: Sunny; mid-upper 70s; calm
Remarks:
PIEDMONT GEOLOGIC, P.C.
6 7
I
I
I
I
I
I
I
I
I
I
I
:I
:
ii
I II
I
I
GROUNDWATER SAMPLING FORM
CLIENT: NCSU PROJECT NAME: Lot86GW
PROJECT LOCATION: Raleigh, NC PROJECT NO.: 2519
SAMPLING PERSONNEL: J Ganey
Well I.D.: MVV-29 Well TvDe: Monitorina
Well Diameter On.): 2 Reference Point: Tnn of Casino
Elevation of Reference Point (ft.): 447.67 Well Gauging Meter: Heron lntertace Probe
Dec th to Water (ft.): 39.56 Deoth to Bottom /ft.\: 52.08
Water Column (ft.): 12.52 X _0.16_ gal/ft. = 2.00 gal
conversion factor -~ well volume
Three Well Volumes = 6.0 gal
Puroe Method: submersible numo Purqe Date: 5/05/05
Purqe Volume (qal.): 6.0 Purge Time: Start 1522 Stop 1527
Well Volumes Removed 1 2 3 4 5 6 7
DH 5.25 5.09 5.21
Temp. (°C) 18.8 18.7 18.3
Specific Cooductance (umohs/cm\ 30.7-32.2 24.4
Dissolved O1<Vnen (mg/L) 7.83 8.03 8.13
Sample Characteristics silty silty silty
Sample Date: 5/6/2005 Samr le Method: bailer
Samnle Time: 0946
Sam, le Containers Filled
No. Tvne Preservative Analvsis
1 500ml None Alkalinitv
1 125 ml Nooe 9056 Chloride, Sulfate bli IC
2 40ml HCI Ethane, Ethene, Methane
2 40ml HCI 6230D Volatiles
1 250ml None Iron, Dissolved
1 250 ml HNO3 Manaanese, RCRA Metals
1 125 ml H2SO4 9056 Nitrate by IC
1 250ml HCI TOC
Field Measurements of Sample:
nH 5.76 Oak ton pH/Con 10 Meter
Temp(° C) 17.0 Oakton DH/Con 10 Meter
SDecific Cooductance (umohs/cml 32.1 Oakton DH/Con 10 Meter
Dissolved Ownen (mQ/l) 8.67 YSI Model 95 Meter
Turbidity (NTU) 157.10 Hach Ferrous Iron Kit
Sample Characteristics silty
Weather Conditions: Moderate rain; low 50s; very breezy
Remarks:
PIEDMONT GEOLOGIC, P.C.
I
I
I
I
I
I
I
I
I
I
I
ii
I
GROUNDWATER SAMPLING FORM
CLIENT: NCSU PROJECT NAME: Lot86 GW
PROJECT LOCATION: Raleigh, NC PROJECT NO.: 2519
SAMPLING PERSONNEL: J Ganey
Welll.D.: MW-33 Well T\/ne: Monitorina
Well Diameter /in.\: 2 Reference Point: Too of Casino
Elevation of Reference Point (ft.): 441.38 Well Gauging Meter: Heron Interface Probe
Depth to Water (ft.): 32.05 Den th to Bottom (ft.): 60.35
Water Column (ft.): 28.30 X ~0.16 _ gavft. = 4.53 gal
conversion factor 1 well volume
Three Well Volumes -13.6 gal
Puroe Method: bailer Purae Date: 5/06/05
Purae Volume lnal.): 13.6 Purae Time: Start 1153 Stop 1247
Well Volumes Removed 1 2 3 4 5
nH 6.01 6.00 5.92
Temo. <'C\ 14.7 15.0 15.8
Soecific Conductance (umohs/cm) 73.7 64.9 59.2
Dissolved O,runen (moil) 5.27 6.74 · 7.34
Samele Characteristics clear clear clear
Sample Date: 5/6/2005 Sample Method: bailer
Samnle Time: 1316
Sample Containers Filled
No. Tvne Preservative Analvsis
1 500ml None Alkalinitv
1 125 ml None 9056 Chloride, Sulfate by IC
2 40ml HCI Ethane, Ethene, Methane
2 40ml HCI 6230D Volatiles
1 250ml None Iron, Dissolved
1 250ml HNO3 Manoanese, RCRA Metals
1 125 ml H2SO4 9056 Nitrate bv IC
1 250 ml HCI TOG
Field Measurements of Samole:
,H 5.78 Oakton oH/Con 10 Meter
Temp(' C) 15.3 Oakton PH/Con 1 O Meter
Snecific Conductance (umohs/cm) 67.4 Oak ton pH/Con 1 O Meter
Dissolved o~,nen <moll\ 6.68 YSI Model 95 Meter
Turbiditv (NTU\ 6.61 Hach Ferrous Iron Kit
Sample Characteristics clear
Weather Conditions: Light rain; upper 40s; breezy
Remarks: Collected MW-33 MS/MSD sample
,. PIEDMONT GEOLOGIC, P.C.
6 7
I
I
I
I
I
I
I
I
I
I
I
ii
I
ii
I
:1
GROUNDWATER SAMPLING FORM
CLIENT: NCSU PROJECT NAME: Lot 86 GW
PROJECT LOCATION: Raleigh, NC PROJECT NO.: 2519
SAMPLING PERSONNEL: J Ganey
Well I.D.: MW-34SR Well Tvoe: Monitorina
Well Diameter (in.): 2 Reference Point: Too of Casino
Elevation of Reference Point (ft.): 454.58 Well Gauging Meter: Heron lntertace Probe
Denth to Water (ft.): 40.03 Depth to Bottom (ft.l: 49.58
Water Column (ft.): 9.55 X _0.16_ gal/ft. = 1.53 gal
conversion factor 1 well volume
Three Well Volumes -4.6 gal .
PurQe Method: submersible oumo PurQe Date: 5/11/05
Purae Volume /oal.): 4.6 Purae Time: Start 0841 Stoo 0847.
Well Volumes Removed 1 2 3 4 5 6 7
nH 6.37 5.97 5.69
Temp. (°C) 18.8 18.1 18.1
Soecific Conductance (umohs/cm\ 34.4 36,9 37.9
Dissolved Oxvaen (mg/L) 9.37 9.44 9.56
Sample Characteristics silty silty silty
Samele Date: 5/11/2005 Samele Method: baller
Sample Time: 0907
Samele Containers Filled
No. Tvne Preservative Analvsis
1 500ml None Alkalinitv
1 125 ml None 9056 Chloride; Sulfate by IC
2 40 ml HCI Ethane, Ethene, Methane
2 40ml HCI 6230D Volatiles
1 250ml None Iron, Dissolved
1 250ml HNO3 Man□anese, RCRA Metals
1 125 ml H2SO4 9056 Nitrate bv IC
1 250ml HCI TOG
Field Measurements of Samr le:
nH 5.45 Oakton oH/Con 10 Meter
Temp (°C) 19.1 Oakton pH/Con 1 O Meter
Specific Conductance (umohs/cm\ 37.7 Oakton nH/Con 10 Meter
Dissolved Oxvoen (mg/L) 8.90 YSI Model 95 Meter
Turbiditv (NTU\ 51.98 Hach Ferrous Iron Kit
Sample Characteristics s. silty .
Weather Conditions: Sunny; low-mid 60s; slight breeze
Remarks: Collected Duplicate #2 (MW-61)
. Collected radiation sample (2 gal. sample container)
PIEDMONT GEOLOGIC, P.C.
I
I
I
I
I
I
I
I
I
I
I
!I
:1
I·
:1
I
ll
I
I
I
GROUNDWATER SAMPLING FORM
CLIENT: NCSU PROJECT NAME: Lot86GW
PROJECT LOCATION: Raleigh, NC PROJECT NO.: 2519
SAMPLING PERSONNEL: J Ganey
Welll.D.: MW-34DR Well Tvee: Monitorino
Well Diameter (in.l: 2 Reference Point: Tnn of Casina
Elevation of Reference Point (ft.): 454.58 Well Gauging Meter: Heron lntertace Probe
De,th to Water (ft.): 40.09 Deoth to Bottom /ft.\: 101.00
Water Column (ft.): 60.91 X _0.16_ gaVft. = 9.75 gal
conversion factor 1 well volume
Three Well Volumes = 29.2 gal
Purce Method: submersible oumn Purqe Date: 5/09/05
Purae Volume (aal.l: 10.0 drv Purge Time: Start 1005 Stoe 1019
Well Volumes Removed 1 2 3 4 5 6 7
DH 5.78
Teme. (°C) 19.6 .
Soecific Conductance (umohs/cm' 103.5
Dissolved Oxvoen (mg/L) 7.60
Sample Characteristics s. cloudy
Samele Date: 5/10/2005 Samr le Method: bailer
Samele Time: 0900
Samr le Containers Filled
No. Tvne Preservative Analvsis
1 5oomL None Alkalinitv
1 125 ml None 9056 Chloride, Sulfate by IC
2 40ml HCI Ethane, Ethene, Methane
2 40ml HCI 6230D Volatiles
1 250ml None Iron, Dissolved
1 250ml HNO3 Manaanese, RCRA Metals
1 125 ml H2SO4 9056 Nitrate bv IC
1 250ml HCI TOC
Field Measurements of Sample:
DH 6.11 . Oakton eH/Con 1 O Meter .
Temp(' C) 18.9 Oakton eH/Con 1 O Meter
Specific Conductance (umohs/cml 98.1 Oakton nH/Con 10 Meter
Dissolved o~nen (mg/L) 7.02 YSI Model 95 Meter
Turbidity (NTUl 50.42 Hach Ferrous Iron Kit
Sample Characteristics clear
Weather Conditions: Sunny; mid 50s; breezv
Remarks:
PIEDMONT GEOLOGIC, P.C.
I
I
I
I
I
I
I
I
I
I
ii. I .
I
ii
I I
GROUNDWATER SAMPLING FORM
CLIENT: NCSU PROJECT NAME: Lot86GW
PROJECT LOCATION: Raleigh, NC PROJECT NO.: 2519
SAMPLING PERSONNEL: J Ganey
Welll.D.: MW-35S Well Tvne: Monitorino
Well Diameter lin.): 2 Reference Point: Too of Casino
Elevation of Reference Point (ft.): 443.12 Well Gauging Meter: Heron lntertace Probe
Deoth to Water /ft.\: 42.47 Deoth to Bottom ltt.l: 52.17
Water Column (ft.): 9.70 X ~0.16_ gal/ft. = 1 .55 gal
conversion factor 1 well volume
Three Well Volumes = 4.7 gal
Puroe Method: baller Purae Date: 5/05/05 I
Purae Volume lnal.): 4.8 Pur□e Time: Start 1539 Stop 1600
Well Volumes Removed 1 2 3 4 5
,H 5.15 5.08 4.98
Temp. (°Cl 17.2 17.2 17.3
Soecific Conductance (umohs/cm\ 30.8 30.3 28.7
Dissoived O=nen (ma/Ll 6.11 ·6.40 6.38
Sample Characteristics silty siltv silty
Sam□le Date: 5/6/2005 Samele Method: bailer
Samele Time: 1029
Samele Cootalners Filled
No. Tvoe Preservative Analysis
1 500ml None Alkalinitv
1 125 ml None 9056 Chloride, Sulfate bv IC
2 40ml HCI Ethane, Ethene, Methane
2 40ml HCI 6230D Voiatiles
1 250ml None Iron, Dissolved
1 250 ml HNO3 Manaanese, RCRA Metals
1 125 ml H2SO4 9056 Nitrate bv IC
1 250ml HCI TOG
Field Measurements of Samele:
oH 5.61 Oakton pH/Con 10 Meter
Temp(° Cl 15.2 Oaktoo oH/Con 10 Meter
Snecific Conductance (umohs/cm) 32 Oakton oH/Con 10 Meter
Dissolved Ow0 en rma/L) 6.83 YSI Model 95 Meter
Turbiditv (NTUl 221.10 Hach Ferrous Iron Kit
Sample Characteristics silty
Weather Conditions: Moderate rain; mid 50s; very breezy
Remarks: Collected field blank sample (MW-62)
I PIEDMONT GEOLOGIC, P.C.
I '
6 7
I
I
I
I
I
I
I
I
I
I
,I
i
\I
I
:1
I
:1
I
!I
\1
'I
'1
I
I
I
GROUNDWATER SAMPLING FORM
CLIENT: NCSU PROJECT NAME: Lot86 GW
PROJECT LOCATION: Raleigh, NC PROJECT NO.: 2519
SAMPLING PERSONNEL: J Ganey & S Satterthwaite
Welll.D.: MW-35D Well Tv□e: Mooitorin□
Well Diameter rin.\: 2 Reference Point: T~ of Casino
Elevation of Reference Point (ft.): 444.69 Well Gauging Meter: Heron lntertace Probe
Denth to Water {ft.): 43.24 Depth to Bottom /ft.\: 147.00
Water Column (ft.): 103.76 X _0.16_ gal/ft. = 16.60 gal
conversion factor 1 well volume
Three Well Volumes = 49.8 gal
Pur□e Method: submersible oumo Purqe Date: 5/13/05 I
Purae Volume lnal.\: 16.6 drv PuraeTime: Start 1044 Stop 1058
Well Volumes Removed 1 2 3 4 5 6 7
□H 6.11
Temp. ('C) 17.6
Seecific Conductance /umehsicm\ 134.0
Dissolved Oxvnen /mail) 4.57
Samele Characteristics cloudy
Samele Date: 5/13/2005 Sam~ le Method: bailer
Samele Time: 1253
Sam( le Containers Filled
No. Tvne Preservative Analvsis
1 500 ml None Alkalinitv
1 125 ml None 9056 Chloride, Sulfate bv IC
2 40 ml HCI Ethane, Ethene, Methane
2 40ml HCI 6230D Volatiles
1 250ml None Iron, Dissolved
1 250ml HNO3 Man□anese, RCRA Metals
1 125 ml H2SO4 9056 Nitrate bv IC
1 250ml HCI TOC
Field Measurements of Samnle:
nH 6.57 Oakton eH/Con 10 Meter
Temn 1° C) 17.9 Oakton nH/Con 10 Meter
Soecific Conductance (umohs/cm) 121.8 · Oakton eHiCon 10 Meter
Dissolved Qxvnen /mail\ 2.75 YSI Model 95 Meter
Turbiditv INTU\ 102.40 Hach Ferrous Iron Kit
Sample Characteristics s. cloudy
Weather Conditions: Overcast; mid 60s; calm
Remarks:
PIEDMONT GEOLOGIC, P.C.
I
I
I
I
I
I
I
I
I
I
I
11 I
:1
I
:1
I I
:1
I
!I
'
GROUNDWATER SAMPLING FORM
CLIENT: NCSU PROJECT NAME: Lot 86 GW
PROJECT LOCATION: Raleigh, NC PROJECT NO.: 2519
SAMPLING PERSONNEL: J Ganey & S Satterthwaite
Welll.D.: MW-36S Well T vne: Monitorina
Well Diameter (in.): 2 Reference Point: T nn of Casina
Elevation of Reference Point (ft.): 442.71 Well Gauging Meter: Heron lntertace Probe
Deoth to Water lft.l: 37.7 Deoth to Bottom /fl.\: 52.27
Water Column (ft.): 14.57 X ~0.16_ gaVft. = 2.33 gal
conversion factor 1 well volume
Three Well Volumes = 7.0 gal
Purae Methoc: submersible oumo Purae Date: 5/13/05
Pur□e Volume lnal.): 7.0 PurneTime: Start 0845 Stoo 0855
Well Volumes Removed 1 2 3 4 5.
nH 5.54 5.27 5.11
Temp. ('C) 18.4 18.4 18.6
Soecific Conductance (umohs/cm) 175.6 177 178.6
Dissolved Ovimen (ma/Ll 1.12 1.94 1.67
Sample Characteristics silty silty clear
Samele Date: 5/13/2005 Samele Methoc: bailer
Samele Time: 1000
Samnle Containers Filled
No. Tvee Preservative Analvsis
1 500ml None Alkalinitv
1 125 ml None 9056 Chloride, Sulfate by IC
2 40ml HCI Ethane, Ethane, Methane
2 40ml HCI 6230D Volatiles
1 250ml None Iron, Dissolved
1 250ml HNO3 Manoanese, RCRA Metals
1 125 ml H2SO4 9056 Nitrate bv IC
1 250 ml HCI TOG
Field Measurements of Samole:
nH 5.33 Oakton oH/Con 1 O Meter
Temp(° C\ 21.6 Oakton oH/Con 10 Meter
Snecitic Conductance (umohs/cm) 168.1 Oakton oH/Con 1 O Meter
Dissoived o~'"en lmQ/L) 5.13 YSI Mocel 95 Meter
Turbiditv /NTU\ 32.76 Hach Ferrous Iron Kit
Sample Characteristics s. cloudy
Weather Conditions: Overcast; mid 60s; breezy
Remarks:
I PIEDMONT GEOLOGIC, P.C.
I
6 7
I
I
I
I
I
I
I
I
I
I
ii
I
GROUNDWATER SAMPLING FORM
CLIENT: NCSU PROJECT NAME: Lot 86 GW
PROJECT LOCATION: Raleigh, NC PROJECT NO.: 2519
SAMPLING PERSONNEL: J Ganey & S Satterthwaite
Well I.D.: MW-36D Well Tvne: Monitorina
Well Diameter (in.): 2 Reference Point: T"'" of Casinn
Elevation of Reference Point (ft.l: 442.87 Well Gauging Meter: Heron Interface Probe
D=th to Water (ft.l: 37.61. Depth to Bottom (ft.l: 114.30
Water Column (ft.): 76.69 X _0.16_ gaVft. = 12.27 gal
. conversion factor 1 well volume
Three Well Volumes = 36.8 gal
Purne Method: submersible oumo Puroe Date: 5/11/05
Purne Volume lnal.): 12.3 drv PurQe Time: Start 1537 Sto□ 1552
Well Volumes Removed 1 ·2 3 4 5
nH 6.15
Tern□. ('C) 19.4
S□ecific Conductance (umohs/cm\ 103.9
Dissolved Ownen (ma/LI 1.75
Samole Characteristics clear
Sam□le Date: 5/12/2005 Samele Method: bailer
Samole Time: 1151
Samele Containers Filled
No. Type Preservative Analvsis
1 500ml None Alkalinitv
1 125 ml None 9056 Chloride, Sulfate bv IC
2 40ml HCI Ethane, Ethene, Methane
2 40ml HCI 6230D Volatiles
1 250 ml None Iron, Dissolved
1 250ml HNO3 Mannanese, RCRA Metals
1 125 ml H2SO4 9056 Nitrate bv IC
1 250 ml HCI TOG
Field Measurements ot Samele:
nH 6.14 Oakton nH/Con 10 Meter
Temp(° C) 23.2 Oakton oH/Con 1 O Meter
Snecitic Conductance (umohs/cm) 108.5 Oakton nH/Con 10 Meter
Dissolved o~'"en lma/L) 5.36 YSI Model 95 Meter
Turbiditv (NTU\ 5.87 Hach Ferrous Iron Kit
Sample Characteristics clear
Weather Conditions: Sunny; low 70s; calm
Remarks: Collected radiation sample (2 gal. sample container)
m PIEDMONT GEOLOGIC, P.C.
I
I
6 7
.
I
I
I
I
I
I
I
I
I
I
I
I
GROUNDWATER SAMPLING FORM
CLIENT: NCSU PROJECT NAME: Lot86 GW
PROJECT LOCATION: Raleigh, NC PROJECT NO.: 2519
SAMPLING PERSONNEL: J Ganey & S Satterthwaite
Well 1.D.: MW-37 Well T""e: Monitorino
Well Diameter /in.\: 2 Reference Pcint: Too of Casino
Elevation of Reference Point (ft.): 440.88 Well Gauging Meler: Heron Interlace Probe
Depth to Waler (ft. l: 35.62 Donth to Bollom (ft.): 51.54
Water Column (ft.): 15.92 X _0.16_ gal/ft. = 2.55 gal
conversion factor 1 well volume
Three Well Volumes -7.6 gal
Purae Method: submersible pump Purne Date: 5/13/05
Purae Volume tnal.\: 7.6 Purce Time: Start 1017 Stop 1021
Well Volumes Removed 1 2 3 4 5
"H 5.89 5.56 5.35
Temp. (°C\ 17.9 17.7 17.8
Soecific Conductance (umohs/cm) 98.1 108.6 94.0
Dissolved Oxvnen (mQ/L) 2.08 1.91 2.17
Sample Characteristics silty silty silty
Sample Date: 5/13/2005 Sample Method: bailer
Sam□le Time: 1200
Samole Containers Filled
No. Tvne Preservative Analvsis
1 500ml None Alkalinitv
1 125 ml None 9056 Chloride, Sulfate by IC
2 40ml HCI Ethane, Ethene, Methane
2 40ml HCI 6230D Volatiles
1 250ml None Iron, Dissolved
1 250ml HNO3 Manoanese, RCRA Metals
1 125 ml H2SO4 9056 Nitrate bv IC
1 250ml HCI TOG
Field Measurements of Sample:
>H 5.28 Oakton pH/Con 10 Meler
Temp(° Cl 18.7 Oakton □H/Con 10 Meter
Specific Conductance (umohs/cml 100.5 Oakton oH/Con 1 O Meler
Dissolved Ow0 en /mail) 5.28 YSI Model 95 Meter
Turbiditv /NTU\ 88.75 Hach Ferrous Iron Kit
Sample Characteristics s. cloudy
Weather Conditions: Overcast; upper 60s; breezy
Remarks: Collected radiation sample (2 gal. sample container)
PIEDMONT GEOLOGIC, P.C.
6 7
I
I
I
I
I
I
11
I
11
I
I
\I
\I
:1
!
:1
\I
ii
'
I
I
GROUNDWATER SAMPLING FORM
CLIENT: NCSU PROJECT NAME: Lot86 GW
PROJECT LOCATION: Raleigh, NC PROJECT NO.: 2519
SAMPLING PERSONNEL: J Ganey
Welll.D.: MW-38 Well Tvne: Monitorinn
Well Diameter lin.l: 2 Reference Point: Tl'V't. of Casinn
Elevation of Reference Point (ft.): 445.38 Well Gauging Meter: Heron lntertace Probe
Deoth to Water /ft.l: 37.36 Deoth to Bottom /ft.\: 107.10
Water Column (ft.): 69.74 X _0.16_ gal/ft. = 11.16gal
conversion factor 1 well volume
Three Well Volumes · = 33.5 gal
Puroe Method: submersible oump Purae Date: 5/04/05 I
Purne Volume lnal.\: 11.2dni Puroe Time: Start 1343 Stoo 1400
Well Volumes Removed 1 2 3 4 5 6 7
DH 6.35
Temn. 1°Cl 18.3
Soecific Conductance (umohs/cm) 144.3
Dissolved O"'men /moil\ 3.06
Sample Characteristics s. cloudy
Samole Date: 5/5/2005 Sarni le Method: bailer
Samole Time: 1319
Sam, le Containers Filled
No. Tvne Preservative Analvsis
1 500ml None Alkalinitv
1 125 ml None 9056 Chloride, Sulfate bv IC
2 40ml HCI Ethane, Ethene, Methane
2 40ml HCI 6230D Volatiles
1 250ml None Iron, Dissolved
1 250ml HNO3 Manaanese, RCRA Metals
1 125 ml ' H2SO4 9056 Nitrate bv IC
1 250ml HCI TOG
Field Measurements of Sample:
nH 6.92 Oakton oH/Con 10 Meter
Temp/° C) 18.9 Oakton oH/Con 1 O Meter
Soecific Conductance /umohs/cm) 137.6 Oakton nH/Con 10 Meter
Dissolved Ownen lmo/L) 5.61 YSI Model 95 Meter
Turbiditv INTU\ 24.76 Hach Ferrous Iron Kit
Sample Characteristics clear
Weather Conditions: Overcast; low 60s; breezy
Remarks: Collected radiation sample (2 gal. sample container)
PIEDMONT GEOLOGIC, P.C.
I
I
I
I
I
I
I
I
11
\1
!I
I
!1 I
11
11
\1
iii
\I
\I
11
GROUNDWATER SAMPLING FORM
CLIENT: NCSU PROJECT NAME: Lot86 GW
PROJECT LOCATION: Raleigh, NC PROJECT NO.: 2519
SAMPLING PERSONNEL: J Ganey
Well 1.D.: MW-40 Well Tvne: Monitorinn
Well Diameter /in.\: 2 Reference Point: Ton of Casinn
Elevation of Reference Point (ft.): 435.47 Well Gauging Meter: Heron Interface Probe
Decth to Water <ft.\: 25.33 Decth to Bottom /ft.\: 36.97
Water Cc,umn (ft.): 11.64 X _0.16_ gaYft. = 1.86 gal
conversion factor 1 well volume
Three Well Vc,umes = 5.6 gal
Purne Method: submersible oumo Purae Date: 5/09/05 I
Purne Volume lnal.l: 5.6 Puroe Time: Start 1412 Ston 1416
Well Volumes Removed 1 2 3 4 5 6 7
nH 6.41 6.30 6.20
Temp. (°C) 19.3 19.0 18.9
Scecific Conductance /umohs/cm\ 33.7 35.4 32.3
Dissolved o~nen /mail) 7.68 7.72 7.72
Sample Characteristics silty silty silty
Samnle Date: 5i10/2005 Sarni le Method: bailer
Samele Time: 1400
Sam, le Containers Filled
No. Tvne Preservative . Analvsis
1 500ml None Alkalinitv
1 125 ml None 9056 Chloride, Sulfate bv IC
2 40ml HCI Ethane, Ethene, Methane
2 40 ml HCI 6230D Volatiles
1 250ml None Iron, Dissolved
1 250ml HNO3 Mannanese, RCRA Metals
1 125 ml H2SO4 9056 Nitrate bv IC
1 250ml HCI TOG
Field Measurements of Samele:
nH · 5.19 Oakton nH/Con 10 Meter
Temp(° C) 18.6 Oakton □H/Con 10 Meter
Scecific Conductance /umohs/cm\ 33.5 Oakton □H/Con 1 O Meter
Dissolved O,omen (mail) 10.08 YSI Model 95 Meter
Turbiditv /NTU\ 439.30 Hach Ferrous Iron Kit
Sample Characteristics silty
Weather Conditions: Sunny; mid 70s; calm
Remarks:
PIEDMONT GEOLOGIC, P.C.
I
I
I
I
I
I
I
I
I
I
I
I
ii
I 1•
ii '
II
\1
11
I
ii
GROUNDWATER SAMPLING FORM
CLIENT: NCSU PROJECT NAME: Lot86GW
PROJECT LOCATION: Raleigh, NC PROJECT NO.: 2519
SAMPLING PERSONNEL: J Ganey
Well I.D.: MW-41 · Well Tvne: Monitorino
Well Diameter (in.): 2 Reference Point: Tnn of Casina
Elevation of Reference Point (ft.): 421.17 Well Gauging Meter: Heron Interface Probe
Death to Water /ft.\: 24.49 Death to Bottom /ft.\: 33.33
Water Cciumn (ft.): 8.84 X ~0.16_ gaVft. = 1.41 gal
conversion factor 1 well volume
Three Well Volumes = 4.2 gal
Purce Method: submersible oumo Purae Date: 5/04/05 I
Purne Volume lnal.): 4.2 PuraeTime: Start 1255 Stop 1300
Well Volumes Removed 1 2 3 4 5 6 7
,H 5.26 5.15 5.01
Temp. ('Cl 20.3 20.0 19.8
Soecific Conductance (umohs/cm) 48.5 44.8 73.4
Disscived o~men /mall\ 7.48 7.79 7.89
Sample Characteristics silty siltv siltv
Samnle Date: 5/5/2005 Samele Method: bailer
Samale Time: 1246
Samr le Cootalners Filled
No. Tvne Preservative Analysis
1 500ml None Alkalinitv
1 125 ml None 9056 Chloride, Sulfate bv IC .
2 40 ml HCI Ethane, Ethene, Methane
2 40ml HCI 6230D Volatiles
1 250ml Nooe Iron, Dissolved
1 250ml HNO3 Manaanese, RCRA Metals
1 125 ml H2SO4 9056 Nitrate bv IC
1 250ml HCI TOG
Field Measurements of Samole:
nH 5.3 Oakton pH/Con 1 O Meter
Temp(' C\ 19.7 Oakton aH/Coo 10 Meter
Soeclfic Conductance (umohs/cm) 64.6 Oakton pH/Con 1 O Meter
Dissolved Ow0 en (mQ/L) 8.05 YSI Model 95 Meter
Turbiditv INTU\ 311.40 Hach Ferrous Iron Kit
Sample Characteristics siltv
Weather Conditions: Overcast; low 60s; breezy
Remarks:
PIEDMONT GEOLOGIC, P.C.
I
I
I
I
I
I
I
I
I
I
GROUNDWATER SAMPLING FORM
CLIENT: NCSU PROJECT NAME: . Lot 86 GW
PROJECT LOCATION: Raleigh, NC PROJECT NO.: 2519
SAMPLING PERSONNEL: J Ganev
Well I.D.: MW-41I Well Tvne: Monitorinq
Well Diameter lin.\: 2 Reference Point: Ton of Casino
Elevation of Reference Point (ft.): 421.57 Well Gauging Meter: Heron lntertace Probe
Deoth to Water /ft.\: 23.39 Deoth to Bottom rlt.\: 60.11
· Water Column (ft.): 36.72 X _0.16_ gal/ft. = 5.88 gal
conversion factor 1 well volume
Three Well Volumes -17.6 gal
Purne Method: submersible numn Purne Date: 5/04/05 I
Purae Volume tnal.\: 12.5 drv Purae Time: Start 1234 Stoo 1248
Well Volumes Removed 1 2 3 4 5
"H 5.51 5.42
Temo. (°C\ 19.6 20.1
Soecific Conductance lumohs/cm\ 32.1 28.1
Dissolved o~nen fma/L\ 8.66 8.62
Samole Characteristics clear silty
Samnle Date: 5/5/2005 Samele Method: bailer
Samole Time: 1222
Samele Containers Filled
No. Tune Preservative Analvsis
1 500ml None Alkalinitv ..
1 125 ml None 9056 Chloride, Sulfate bv IC
2 40ml HCI Ethane, Ethene, Methane
2 . 40ml HCI 6230D Volatiles
1 250 ml None Iron, Dissolved
1 250ml HNO3 Manoanese, RCRA Metals
1 125 ml H2SO4 9056 Nitrate bv IC
1 250ml HCI TOG
Field Measurements of Samnle:
nH 5.58 Oakton nH/Con 1 O Meter
Temo /° C) 19.3 Oakton oH/Con 1 O Meter
Snecific Conductance tumohs/cm\ 28.8 Oakton oH/Con 1 O Meter
Dissolved Ownen lmn/L\ 9.51 YSI Model 95 Meter
Turbiditv INTU\ 55.49 Hach Ferrous Iron Kit
Sample Characteristics s. cloudy
Weather Conditions: Overcast; low 60s; breezy
Remarks:
PIEDMONT GEOLOGIC, P.C.
6 7
.
I
I
I
I
I
I
I
I
ii
\1
I
\I
\I
:1
I
\I
I
II I
'I
I
I I
I
a
I
GROUNDWATER SAMPLING FORM
CLIENT: NCSU PROJECT NAME: Lot 86GW
PROJECT LOCATION: Raleigh, NC PROJECT NO.: 2519
SAMPLING PERSONNEL: J Ganey
Welll.D.: MW-410 Well Tune: Monitorino
Well Diameter /in.\: 2 Reference Point: Tnn of CasinQ
Elevation of Reference Point (ft.): 420.67 Well Gauging Meter: Heron lntertace Probe
DeDlh to Water m.\: 22.38 DeDlh to Bottom /fl.\: 90.00 .
Water Column (fl.): 67.62 X _0.16 -gal/fl. = 10.82 gal
. conversion factor 1 well volume
Three Well Volumes = 32.5 gal
Purae Method: submersible pump Purae Date: 5/09/05
Purae Volume laal.1:. 10.8 drv Purce Time: Start 1142 Sinn 1155
Well Volumes Removed 1 2 3 4 5 6 7
nH 8.43
TemD. ('C) 19.6
SDecific Conductance lumohs/cm1 47.7
Dissolved Ownen (mQ/L) 7.51
Samele Characteristics clear
Same le Date: 5/10/2005 SamDle Method: bailer
Samnle Time: 1122
SamDle Containers Filled
No. Tvne Preservative Analvsis
1 500ml None Alkaiinitv
1 125 ml None 9056 Chloride, Sulfate by IC
2 40ml HCI Ethane, Ethene, Methane
2 40ml HCI 6230D Volatiles
1 250ml None Iron, Dissolved
1 250 ml HNO3 Manoanese, RCRA Metals
1 125 ml H2SO4 9056 Nitrate by IC
1 250ml HCI TOC
Field Measurements of Samele:
nH 6.31 Oakton DH/Con 1 O Meter
TemD (' C\ 20.7 Oakton DH/Con 10 Meter
Soecific Conductance (umohs/cm) 49.5 Oakton DH/Con 1 O Meter
Dissolved Ownen lmo/U 7.84 YSI Model 95 Meter
Turbiditv /NTU1 11.73 Hach Ferrous Iron Kit
Sample Characteristics clear
Weather Conditions: Sunnv; low 60s; breezy
Remarks:
PIEDMONT GEOLOGIC, P.C.
I
I
I
I
I
I
I
I
I
:1
\1
\1
I
ii
I 11
! ii
I
\I
\I
'I
II
GROUNDWATER SAMPLING FORM
CLIENT: NCSU PROJECT NAME: Lot 86GW
PROJECT LOCATION: Raleigh, NC PROJECT NO.: 2519
SAMPLING PERSONNEL: J Ganey
Welll.D.: MW-42 Well Tvne: Monitorina
Well Diameter /in.\: 2 Reference Point: Ton of Casinn
Elevation of Reference Point (ft.): 427.25 Well Gauging Meler: Heron lntertace Probe
Deolh to Water (fl.\: 20.41 Deolh to Bottom (fl.): 34.85
Water Column (fl.): 14.44 X _0.16_ gal/fl. = 2.31 gal
conversion factor ~ well volume
Three Well Volumes = 6.9 gal
Purne Method: submersible pump Puroe Date: 5/04/05
Purae Volume lnal.\: 6.9 PurQe Time: Start 1210 Ston 1215
Well Volumes Removed 1 2 3 4 5 6 7
nH 5.46 5.28 5.13
Temp. /°C) 19.4 19.6 20.1
Seecific Conductance (umohs/cml 39.1 37.8 41.6
Dissolved Ownen (mo/LI 7.23 7.44 7.52
Sample Characteristics silty silty silty
Samele Date: 5/5/2005 . Samile Method: bailer
Samele Time: 1141
Samile Containers Filled
No. Tvne. Preservative AnaJvsis
1 500 ml None Alkalinitv
1 125 ml None 9056 Chloride, Sulfate bv IC
2 40ml HCI Ethane, Ethene, Methane
2 40ml HCI 6230D Volatiles
1 250ml None Iron, Dissolved
1 250 ml HNO3 Mannanese, RCRA Metals
1 125 ml H2SO4 9056 Nitrate bv IC
1 250ml HCI TOC
Field Measurements of Samole:
oH 5.44 Oakton oH/Con 10 Meter
Temp(° C) 19.2 Oakton eH/Con 10 Meter
Snecific Conductance (umohs/cm) 40.2 Oakton nH/Con 10 Meter
Dissolved o~men /mo/LI 9.02 YSI Model 95 Meter
Turbiditv (NTU\ 150.60 . Hach ·Ferrous Iron Kit
Sample Characteristics silty
Weather Conditions: Overcast; upper 50s; caJm
Remarks: Collected duplicate #1 (MW-60)
PIEDMONT GEOLOGIC, P.C.
I
I
I
I
I
I
I
I
I
I
11
I
\I
I ii
I
I
\I
\1
i 11
I
:1
I
\I
'.I
I I
GROUNDWATER SAMPLING FORM
CLIENT: NCSU · PROJECT NAME: Lot86GW
PROJECT LOCATION: Raleigh, NC PROJECT NO.: 2519
SAMPLING PERSONNEL: J Ganey
Welll.D.: MW-42I Well T"'..,_e: Monitorinn
Well Diameter /in.\: 2 Reference Point: Too of Casina
Elevation of Reference Point (fl.): 426.68 Well Gauging Meter: Heron Interface Probe
D00th lo Water /fl.\: 18.71 Deelh to Bollom (ft. l: 59.47.
Water Column (fl.): 40.76 X _0.16 -gal/ft. = 6.52 gal
conversion factor 1 well volume
Three Well Volumes = 19.6 gal
Purne Method: submersible numn Purae Date: 5/09/05 I
Purne Volume lnal.\: 19.6 Purne Time: Start 1201 St~ 1219
Well Volumes Removed 1 2 3 4 5 6 7
nH 8.44 8.36 8.33
Temp. (°C\ 19.7 19.4 19.5
Snecific Conductance lumohs/cm\ 104.1 104.8 104.2
Dissolved O--0 en lmn/L\ 1.71 1.65 1.31
Sample Characteristics silty clear clear
Samele Date: 5/10/2005 Samele Method: bailer
Samnle Time: 1149
Samnle Containers Filled
No. T"ne Preservative Analvsis
1 500ml None Alkalinitv
1 125 ml None 9056 Chloride, Sulfate bv IC
2 40ml HCI Ethane, Ethene, Methane
2 40ml HCI 6230D Volatiles
1 250ml None Iron, Dissolved
1 250 ml HNO3 Mannanese, RCRA Metals
1 125 ml H2SO4 9056 Nitrate bv IC
1 250ml HCI TOC
Field Measurements of Samr le:
nH 6.22 Oakton nH/Con 1 O Meter
Temp(° C) 20.8 Oaklon eH/Con 10 Meter
Snecific Conductance fumohs/cm\ 78.5 Oakton eH/Con 1 o Meter
Dissolved o~'"en lmn/L\ 7.25 YSI Model 95 Meter
Turbidin, INTUl 14.36 Hach Ferrous Iron Kit
Sample Characteristics clear
Weather Conditions: Sunnv; mid 60s; breezy
Remarks:
PIEDMONT GEOLOGIC, P.C.
I
I
I
I
I
I
I
I
I
I
ii
i
ii
\1
I
!I i
!I
I II
i
GROUNDWATER SAMPLING FORM
CLIENT: NCSU PROJECT NAME: Lot86GW
PROJECT LOCATION: Raleigh, NC PROJECT NO.: 2519
SAMPLING PERSONNEL: J Ganey
Well I.D.: MW-43 Well Tvoe: Monitorina
Well Diameter (in.): 2 Reference Point: Too of Casino
Elevation of Reference Point (ft.): 440.59 Well Gauging Meter: Heron lntertace Probe
Den th to Water ((t.): 48.00 Depth to Bottom lft.l: 62.96
.
Water Column (ft.): 14.96 X _0.16_ gal/ft. = 2.39 gal
conversion factor 1 well volume
Three Well Volumes = 7.2 gal
Puroe Methoc: submersible oumo Purae Date: 5/09/05 I
Purne Volume lnal.): 7.2 Purce Time: Start 1337 st~ 1352
Well Volumes Removed 1 2 3 4 5 6 7
oH 7.10 7.04 6.91
Temp. <'C) 19.3 19.7 19.6
Snecific Conductance (umohs/cm) 31.6 32.6 32.0
Dissolved o~men /mail\ 8.36. 8.43 8.60
Sample Characteristics silty silty clear
Sample Date: 5/10/2005 Samr le Methoc: baller
Samnle Time: 1308
Samr le Containers Filled
No. Tvne Preseivative Analvsis
1 500ml None Alkalinitv
1 125 ml None 9056 Chloride, Sulfate bv IC
2 40ml HCI Ethane, Ethene, Methane
2 40 ml HCI 6230D Volatiles
1 250ml None •
1fron, Dissolved
1 250ml HNO3 Manoanese, RCRA Metals
1 125 ml H2SO4 9056 Nitrate bv IC
1 250ml HCI TOG
Field Measurements of Samole:
nH 5.50 Oakton oH/Con 10 Meter
Temp I' C) 21.6 Oakton nH/Con 10 Meter
Soecific Conductance tumohs/cm) 34.2 Oakton nH/Con 1 O Meter
Dissolved o~nen (ma/U 9.10 YSI Mocel 95 Meter
Turbiditv INTU\ 99.64 Hach Ferrous Iron Kit
Sample Characteristics silty
Weather Conditions: Sunny; upper 70s; breezy
Remarks:
PIEDMONT GEOLOGIC, P.C.
I
I
I
I
I
I
I
I
I
I I
I '. 11
I
111
I ii
i ii
I
!I
I·
;1
I I
ii
\1 I
'I
I
I
GROUNDWATER SAMPLING FORM
CLIENT: NCSU PROJECT NAME: Lot 86 GW
PROJECT LOCATION: Raleigh, NC PROJECT NO.: 2519
SAMPLING PERSONNEL: J Ganey
Well I.D.: MW-43D Well T vne: Monitorinn
Well Diameter (in.\: 2 Reference Point: Too of Casino
Elevation of Reference Point (ft.): 438.01 Well Gauging Meter: Heron lntertace Probe
Deeth to Water (ft.): 47.52 D~th to Bottom /ft.I: 106.00
Water Column (ft.): 58.48 X _0.16_ gaVft. = 9.36 gal
conversion factor 1 well volume
Three Well Volumes -28.1 gal
Purne Method: submersible pump · Purqe Date: 5/09/05
Purae Volume (aal. \: 10.0 drv Purge Time: Start 1244 Stoe 1258
Well Volumes Removed 1 2 3 4 5 6 7
nH 7.66
Temp. (°C\ 18.7
Seecific Conductance /umohsicml 52.9
Dissolved O,runen (mail\ 1.37
Sample Characteristics clear
Samele Date: 5i10i2005 Samele Method: bailer
Same le Time: 1235
Samele Containers Filled
No. T"ne Preservative Analvsis
1 500 ml None Alkalinitv
1 125 ml None 9056 Chloride, Sulfate bv IC
2 40 ml HCI Ethane, Ethene, Methane
2 40ml HCI 6230D Volatiles .
1 250ml None Iron, Dissolved
1 250ml HNO3 Mannanese, RCRA Metals
1 125 ml H2SO4 9056 Nitrate bv IC
1 250ml HCI TOG
Field Measurements of Samele: .
nH 5.84 Oakton □H/Con 1 O Meter
Temp(° C\ 19.1 Oakton eHiCon 10 Meter
Snecific Conductance fumohs/cm) 57.2 Oakton nHiCon 10 Meter
Dissolved O""nen /mail\ 3.31 YSI Model 95 Meter
Turbiditv (NTU\ 8.62 Hach Ferrous Iron Kit
Sample Characteristics clear
Weather Conditions: Sunny: upper 60s -low 70s: breezy
Remarks:
PIEDMONT GEOLOGIC, P.C.
I
I
I
I
I
I
I
I
I :,
I
\1
\I
\1
I ii
' I
11
I
\I
I
II
I
I
GROUNDWATER SAMPLING FORM
CLIENT: NCSU PROJECT NAME: Lot86GW
PROJECT LOCATION: Raleigh, NC PROJECT NO.: 2519
SAMPLING PERSONNEL: J Ganey
Welll.D.: MW-45 Well Tvne: Monitorin□
Well Diameter /in.\: 2 Reference Point: T~ of Casino
Elevation of Reference Point (ft.): 447.50 Well Gauging Meter: Heron Interface Probe
Deoth to Water /ft.l: 46.25 Deoth to Bottom /ft.\: 62.66
Water Column (ft.): 16.41 X _0.16_ gaYft. = 2.63 gal
conversion factor 1 well volume
Three Well Volumes = 7.9 gal
Puroe Method: submersible oumo PurQe Date: 5/04/05 I
Purae Volume /nal.l: 6.0 drv Purce Time: Start 1028 Stoo 1036
Well Volumes Removed 1 2 3 4 5 6 7
oH 6.96 6.64
Temp. ("Cl 18.4 19.7
Snecific Conductance (umohslcml 35.6 32.5
Dissolved O~men /mall\ 13.53 11.38
Sample Characteristics silty silty
Samele Date: 5/5/2005 Same le Method: bailer
Samnle Time: 0855
Same le Containers Filled
No. Tvne Preservative Anoh,sis .
1 500ml None Alkalinitv
1 · 125 ml None 9056 Chloride, Sulfate bv IC
2 40ml HCI Ethane, Ethene, Methane
2 40ml HCI 6230D Volatiles
1 250ml None Iron, Dissolved
1 250ml HNO3 Manoanese, RCRA Metals
1 125 ml . H2SO4 9056 Nitrate bv IC
1 250ml HCI TOC
Field Measurements of Samele:
nH · 6.16 Oakton oH/Con 10 Meter
Temp 1° C) 17.3 Oakton nH/Con 10 Meter
Soecific Conductance /umohs/cm\ 37.2 Oak ton oH/Con 10 Meter
Dissolved Own.en /ma/Ll 10.02 YSI Model 95 Meter
Turbiditv INTUl 49.78 Hach Ferrous Iron Kit
Sample Characteristics clear
Weather Conditions: Sunny; mid 50s; calm
Remarks:
PIEDMONT GEOLOGIC, P.C.
I
I
I
I
I
I
I
I
I
I
I
GROUNDWATER SAMPLING FORM
CLIENT: NCSU PROJECT NAME: Lot 86GW
PROJECT LOCATION: Raleigh, NC PROJECT NO.: 2519
SAMPLING PERSONNEL: J Ganey
Well I.D.: MW-46 Well T vne: Monitorinn
Well Diameter rin.l: . 2 Reference Point: Too of Casino
Elevation of Reference Point (It.): 451.35 Well Gauging Meter: Heron lntertace Probe
Donth to Water (ft.): . 54.46 Deoth to Bottom /ft. I: 62.77
Water Column (ft.): 8.31 X _0.16_gaYft. = 1.33 gal
conversion factor 1 well volume
Three Well Volumes = 4.0 gal
Purne Method: submersible oump Purqe Date: 5/04/05 1
Purae Volume lnal.l: 2.6 div Purge Time: Start 1125 Stoa 1128
Well Volumes Removed 1 2 3 4 5
nH 5.09 5.15
Terna. (°Cl 22.5 20.1
Soecilic Conductance /umohs/cml 65.8 40.5
Dissolved Ownen /moll) 7.44 9.16
Sample Characteristics silty siltv
Samole Date: 5/5/2005 Sam, le Method: bailer
Samnle Time: 1024
Sam; le Containers Filled
No. Tvne Preservative Analvsis
1 500ml None Alkalinitv
1 125 ml None 9056 Chloride, Sulfate bv IC
2 40 ml HCI Ethane, Ethene, Methane
2 40ml HCI 6230D Volatiles
1 250ml None 1ron, Dissolved
1 250ml HNO3 · Mannanese, RCRA Metals
1 125 ml H2SO4 9056 Nitrate bv IC
1 250ml HCI TOG
Field Measurements of Samole:
nH 5.28 Oakton oH/Con 10 Meter
Terna 1° Cl 18.4 Oakton oH/Con 10 Meter
Soecific Conductance /umohs/cm) 45.6 Oakton oH/Con 1 O Meter
Dissolved Ownen lmn/Ll 9.86 YSI Model 95 Meter
Turbiditv INTUl 163.90 Hach Ferrous Iron Kit
Sample Characteristics silty
Weather Conditions: Sunny; upper 50s; calm
Remarks:
PIEDMONT GEOLOGIC, P.C.
6 .7
.
I
I
I
I
I
1•
II
'
!1
I
II
\1
I
II
I ;1
ii
:1
I
ii
'1
I
i
I
' I I I
I
GROUNDWATER SAMPLING FORM
CLIENT: NCSU PROJECT NAME: Lot 86 GW
PROJECT LOCATION: Raleigh, NC PROJECT NO.: 2519
SAMPLING PERSONNEL: J Ganey
Welll.D.: MW-47 Well Tvne: Monitorino
Well Diameter On.): 2 Reference Point: Ton of CasinQ
Elevation of Reference Point (ft.): 441.11 Well Gauging Meter: Heron Interface Probe
D=th to Water (ft.): 35.37 Deoth to Bottom ltt.): 120.00
Water Column (ft.): 84.63 X _0.16_ gal/ft. = 13.54 gal
conversion fac!Of 1 · well volume
Three Well Volumes = 40.6 gal
Purce Method: submersible oump Purce Date: 5/09/05
Purce Volume (cal.): 40.6 Purge Time: Start 0913 Stoa 0950
Well Volumes Removed 1 2 3 4 5 6 7.
DH 6.35 6.07 5.87
Temo. ('C) 18.4 18.7 18.7
Soecific Conductance (umohs/cm) 59.5 62.2 61.5
Dissolved Ownen (mq/L) 8.98 8.53 8.47
· Sample Characteristics clear siltv silty
Samr le Date: 5/10/2005 Samele Method: bailer
Samele Time: 0828
Samele Containers Filled
No. T"ne Preservative Analvsis
1 500ml None Alkalinitv
1 125 ml None 9056 Chloride, Sulfate bv IC
2. 40ml HCI Ethane, Ethene, Methane
2 40mL HCI 6230D Volatiles
1 250ml None Iron, Dissolved
1 250mL HNO3 Manoanese, RCRA Metals
1 125 ml H2SO4 9056 Nitrate bv IC
1 250ml HCI TOG
Field Measurements of Samr le:
nH 6.28 Oak ton oH/Con 10 Meter
Temp·(' C) 18.7 Oakton oH/Con 1 0 Meter
Soecific Conductance (umohs/cm) 62.4 Oakton oH/Con 1 O Meter
Dissolved Oxv□en (mq/l) 5.35 YSI Model 95 Meter
Turbiditv /NTU\ 54.88 Hach Ferrous Iron Kit
Sample Characteristics clear
Weather Conditions: Sunny; mid 50s; calm
Remarks:
PIEDMONT GEOLOGIC, P.C.
I
I
I
I
:1
\1
\1
\1
11
I
11
I
' ii
I
11 :.
i ii
1:1
II
'
I I
I
' i.~
PIEDMONT GEOLOGIC, P.C.
Report of Results: May 2005 Groundwater Monitoring Event
No11h Carolina State University, Lot 86 Farm Unit No. 1 Site
June 15, 2005
APPENDIX B
LABORATORY REPORTS
I
I
I
I
I
I
I
I
ii
11
I
11
I
II
I
ii
II
I
I
I
I
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 06, 2005
Description NC State University
Sample ID MW-38
Collected By J. Ganey
Collection Date 05/05/05 13,19
Parameter
Methane
Chloride
Nitrate
Sulfate
Alkalinity
Ethane
Ethene
TOC (Total Organic Carbon)
Mercury
Arsenic
Barium
Cadmium
Chromium
Iron,Dissolved
Lead
Manganese
Selenium
Silver
Volatile Organics
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon Tetrachloride
Chlorobenzene
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #86
Result Det. Limit
BDL 1000
1600 1000
BDL 100
BDL 5000
84000 10000
BDL 1000
BDL 1000
BDL 1000
BDL 0.20
BDL 20.
17. 5.0
BDL 5.0
BDL 10.
BDL 100
BDL s.O
BDL 10.
BDL 20.
BDL 10.
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1. 0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
Det. Limit -Estimated Quantitation Limit{EQL)
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Eat. 1970
May 16,2005
ESC Sample#
Site ID
Project #
Units Method
ppb 8015M
ug/1 9056
ug/1 9056
ug/1 9056
ug/1 310.2
ppb 8015M
ppb 8015M
ug/1 9060
ug/1 7470A
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 60108
ug/1 6010B
ug/1 60108
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
Ll98075-01
2519
Date
05/09/05
05/06/05
05/06/05
05/06/05
05/11/05
05/09/05
05/09/05
05/12/05
05/12/05
05/09/05
05/09/05
05/09/05
05/09/05
05/08/05
05/09/05
05/09/05
05/09/05
05/09/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
Laboratory Certification Numbers:
C-TN-01
Dil.
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
00109, WV -233
Page 1 of 39
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 06, 2005
Description NC State University
Sample ID MW-38
Collected By J. Ganey
Collection Date 05/05/05
Parameter
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
i,2-Dibromo-3-Chloropropane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
·trans-1, 2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
Di-isopropyl ether
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
p-Isopropyltoluene
Methylene chloride
Methyl tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
BDL -Below Detection Limit
13:19
REPORT OF ANALYSIS
Lot #86
Result
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
B~L
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
Det. Limit
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
5.0
5.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
Det. Limit -Estimated Quantitation Limit(EQL)
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax {615) 758-5859
Tax I.D. 62-0814289
Est. 1970
May 16,2005
ESC Sample
Site ID
Project #
Units Method
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
# L198075-01
2519
Date
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
Laboratory Certification Numbers:
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN -C-TN-01
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA -00109, WV
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Page 2 of 39
I
I
I
I
I
I
Dil.
1 I 1
1
1
1 I 1
1
1
1
ti
1
ti
1
1
ti
1
1
ti
1
1
ti
1
ti 1
1 11
I
I
I
I
I
I
I
I
I
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 06, 2005
Description NC State University
Sample ID MW-38
Collected By J. Ganey
Collection Date 05/05/05
Parameter
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Toluene
Vinyl chloride
Xylenes, Total
BDL -Below Detection Limit
13,19
REPORT OF ANALYSIS
Lot #86
Result
BDL
BDL
BDL
BDL
BDL
BDL
BDL
net. Limit
1.0
1.0
1.0
1.0
5.0
1.0
3.0
Det. Limit -Estimated Quantitation Limit(EQL)
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
Fax {615) 758-5859
Tax I.D. 62-0814289
Est. 1970
May 16,2005
ESC Sample#
Site ID
Project#
Units Method
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
Ll98075-01
2519
Date
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
Laboratory Certification Numbers:
C-TN-01
Oil.
1
1
1
1
1
1
1
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA 00109, WV -233
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Note:
The reported analytical results relate only to the sample submitted.
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported: 05/16/05 18:11 Printed: 05/16/05 18:12
Page 3 of 39
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 06, 2005 Description NC State University
Sample ID MW-41
Collected By J. Ganey Collection Date 05/05/05 12 :46
Parameter
Methane
Chloride
Nitrate
Sulfate
Alkalinity
Ethane
Ethene
TOC (Total Organic Carbon)
Mercury
Arsenic
Barium
Cadmium
Chromium
Iron,Dissolved
Lead
Manganese
Selenium
Silver
Volatile Organics
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon Tetrachloride
Chlorobenzene
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #86
Result Det. Limit
BDL 1000
9300 1000
1000 100
BDL 5000
46000 10000
BDL 1000
BDL 1000
BDL 1000
BDL 0 .20
BDL 20.
30. 5.0
BDL 5.0
BDL 10.
BDL 100
BDL 5.0
39. 10.
BDL 20.
BDL 10.
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
Det. Limit -Estimated Quantitation Limit(EQL)
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 16, 2005
ESC Sample# L198075-02
Site ID
Project# 2519
Units
ppb
ug/1
ug/1
ug/1
ug/1
ppb
ppb
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
Method
8015M
9056
9056
9056
310.2
8015M
8015M
9060
7470A
6010B
.6010B
6010B
6010B
6010B
6010B
6010B
60108
6010B
6230D
6230D
6230D
62300
62300
6230D
62300
62300
6230D
6230D
6230D
Date
05/09/05
05/06/05
05/06/05
· 05/06/05
05/11/05
05/09/05
05/09/05
05/12/05
05/12/05
05/09/05
05/09/05
05/09/05
05/09/05
05/08/05
05/09/05
05/09/05
05/09/05
05/09/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
Laboratory Certification Numbers:
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Page 4 of 39
C-TN-01
00109, WV
I
I
I
I
I
I
Oil.
1 I
1
1
1 I 1
1 11
1
11
1
1 ~.
1
1 ii
1 ~· 1 ~. 1
1 11
231
I
I
I
I
I
I
I
I
I
I
,I
I
ii
I II
:1
\I
11
I
I
I
I
I
a
I
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 06, 2005
Description NC State University
Sample ID MW-41
Collected By J. Ganey
Collection Date 05/05/05 12:46
Parameter
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
l,2-Dibromo-3-Chloropropane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
Di-isopropyl ether
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
p-Isopropyltoluene
Methylene chloride
Methyl tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #86
Result Det. Limit
B0L 1.0
B0L 1.0
B0L 1.0
B0L 1.0
B0L 1.0
B0L 1.0
B0L 1.0
B0L 1.0
B0L 1.0
B0L 1.0
B0L 1.0
B0L 1. 0
B0L 1.0
B0L 1.0
B0L 1.0
B0L 1.0
B0L 1.0
B0L 1.0
B0L 1.0
B0L 1.0
B0L 5.0
B0L 1.0
B0L 1. 0
B0L 1.0
B0L 1.0
B0L 5.0
B0L 5.0
B0L 5.0
B0L 1.0
B0L 1.0
B0L 1.0
B0L 1.0
B0L 1.0
B0L 1.0
B0L 1.0
B0L 1. 0
B0L 1.0
B0L 1.0
Det. Limit -Estimated Quantitation Limit(EQL)
12065 Lebanon Rd.
Mt. Juliet, TN 37122
(615} 758-5858
l-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 16, 2005
ESC Sample #
Site ID
Project#
Units Method
ug/1 6230D
ug/1 62300
ug/1 6230D
ug/1 62300
ug/1 62300
ug/1 62300
ug/1 62300
ug/1 6230D
ug/1 62300
ug/1 62300
ug/1 6230D
ug/1 62300
ug/1 62300
ug/1 62300
ug/1 6230D
ug/1 6230D
ug/1 62300
ug/1 62300
ug/1 6230D
ug/1 6230D
ug/1 62300
ug/1 6230D
ug/1 62300
ug/1 6230D
ug/1 62300
ug/1 62300
ug/1 62300
ug/1 62300
ug/1 6230D
ug/1 62300
ug/1 62300
ug/1 62300
ug/1 62300
ug/1 62300
ug/1 62300
ug/1 62300
ug/1 62300
ug/1 62300
Ll98075-02
2519
Date
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
Laboratory Certification Numbers:
C-TN-01
Dil.
1
1
1
1
l
1
l
1
1
l
1
1
l
1
1
1
1
l
1
1
1
1
1
1
1
1
1
1
1
l
l
l
1
1
1
l
l
1
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
00109, WV -233
Pages of 39
ENVIRONMENTAL
SCIENCE CORP.
REPORT OF ANALYSIS
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
Mr. John Harper
Piedmont Geologic May 16,2005
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
May 06, 2005 Date Received
Description NC State University Lot #86
Sample ID
Collected By
Collection Date
Parameter
MW-41
J. Ganey
05/05/05 12,46
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Toluene
Vinyl chloride
Xylenes, Total
BDL -Below Detection Limit
Result
BDL
BDL
BDL
BDL
BDL
BDL
BDL
Det. Limit -Estimated Quantitation Limit(EQL)
Det. Limit Units
1.0 ug/1
1.0 ug/1
1.0 ug/1
1.0 ug/1
5.0 ug/1
1.0 ug/1
3.0 ug/1
Laboratory Certification Numbers:
ESC Sample#
Site ID
Project#
Method
6230D
6230D
6230D
6230D
6230D
6230D
6230D
L198075-02
2519
Date
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
AIHA -100789, AL -40660, CA -l-2327, CT-PH-0197, FL -E87487, GA -923, IN -C-TN-01
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA -00109, WV
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Note:
The reported analytical results relate only to the sample submitted.
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported: 05/16/05 18:11 Printed: 05/16/05 18:12
Page 6 of 39
I
I
I
I
I
I
Oil.
1 I 1
1
1
1 I 1
1
I
I
I
I
I
I
I
I
233
I
I
I
11
'
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 06, 2005
Description NC State Unive~sity
Sample ID MW-411
Collected By J. Ganey
Collection Date 05/05/05 12,22
Parameter
Methane
Chloride
Nitrate
Sulfate
Alkalinity
Ethane
Ethene
TOC (Total Organic Carbon)
Mercury
Arsenic
Barium
Cadmium
Chromium
Iron,Dissolved
Lead
Manganese
Selenium
Silver
Volatile Organics
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon Tetrachloride
Chlorobenzene
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #86
Result Det. Limit
BDL 1000
1800 1000
200 100
BDL 5000
18000 10000
BDL 1000
BDL 1000
BDL 1000
BDL 0 .20
BDL 20.
22. 5.0
BDL 5.0
BDL 10.
BDL 100
BDL 5.0
35. 10.
BDL 20.
BDL 10.
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1. 0
BDL 1.0
BDL 1. 0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1. 0
Det. Limit -Estimated Quantitation Limit(EQL)
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
l-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 16,2005
ESC Sample#
Site ID
Project#
Units Method
ppb 8015M
ug/1 9056
ug/1 9056
ug/1 9056
ug/1 310.2
ppb 8015M
ppb 8015M
ug/1 9060
ug/1 7470A
ug/1 60108
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 60108
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
L198075-03
2519
Date
05/09/05
05/06/05
05/06/05
05/06/05
05/11/05
05/09/05
05/09/05
05/12/05
05/12/05
05/09/05
05/09/05
05/09/05
05/09/05
05/08/05
05/09/05
05/09/05
05/09/05
05/09/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
Laboratory Certification Numbers:
C-TN-01
Oil.
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
l
1
1
1
1
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
00109, WV -233
Page 7 of 39
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 06, 2005
Description NC State University
Sample ID MW-411
Collected By J. Ganey
Collection Date 05/05/05 12,22
Parameter
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-Chloropropane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
Di-isopropyl ether
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
p-Isopropyltoluene
Methylene chloride
Methyl tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #86
Result Det. Limit
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 5.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 5.0
BDL 5.0
BDL 5.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1. 0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
Det. Limit -Estimated Quantitation Limit(EQL)
12065 Lebanon Rd.
Mt. Juliet, TN 37122
(615) 758-5B58
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 16,2005
ESC Sample # Ll98075-03
Site ID
Project# 2519
Units
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
Method
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
Date
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
Laboratory Certification Numbers:
AIIIA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN C-TN-01
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA -00109, WV
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Page 8 of 39
I
I
I
I
I
I
Dil.
1 I 1
1
1
1 I 1
1
1
1
1 I 1
1
1
1 I 1
1
1
1
1 I 1
1
1
1
1 I 1
1
1
1
1 I 1
1
1
1 ~· 1 11
I
I
I
I
I
I
I
I
I
I
I
I
I
D
I
g
I
I
I
I
I
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 06, 2005
Description NC State University
Sample ID MW-41I
Collected By J. Ganey
Collection Date 05/05/05 12,22
Parameter
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Toluene
Vinyl chloride
Xylenes, Total
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #86
Result Det. Limit
BDL 1.0
BDL 1.0
BDL 1. 0
BDL 1.0
BDL 5.0
BDL 1. 0
BDL 3.0
Det. Limit -Estimated Quantitation Limit(EQL)
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 16,2005
ESC Sample#
Site ID
Project#
Units Method
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
L198075-03
2519
Date
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
05/11/05
Laboratory Certification Numbers:
C-TN-01
1
1
1
1
1
1
1
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA 00109, WV -233
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Note:
The reported analytical results relate only to the sample submitted.
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported, 05/16/05 18,11 Printed, 05/16/05 18,13
Page 9 of 39
ENVIRONMENTAL
SCIENCE CORP.
REPORT OF ANALYSIS
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
May 06, 2005 Date Received
Description NC State University Lot #86
Sample ID
Collected By
Collection Date
Parameter
Methane
Chloride
Nitrate
Sulfate
Alkalinity
Ethane
Ethene
MW-42
J. Ganey
05/05/05 11,41
TOC (Total Organic Carbon)
Mercury
Arsenic
Barium
Cadmium
Chromium
Iron,Dissolved
Lead
Manganese
Selenium
Silver
Volatile Organics
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon Tetrachloride
Chlorobenzene
BDL -Below Detection Limit
Result
BDL
3700
1300
BDL
11000
BDL
BDL
BDL
BDL
BDL
14.
BDL
BDL
BDL
BDL
130
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
Det. Limit -Estimated Quantitation Limit(EQL)
Det. Limit
1000
1000
100
5000
10000
1000
1000
1000
0 .20
20.
5.0
5.0
10.
100
5.0
10.
20.
10.
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 16,2005
ESC Sample # Ll98075-04
Site ID
Project # 2519
Units Method Date
ppb 8015M 05/09/05
ug/1 9056 05/06/05
ug/1 9056 05/06/05
ug/1 9056 05/06/05
ug/1 310.2 05/11/05
ppb 8015M 05/09/05
ppb 8015M 05/09/05
ug/1 9060 05/12/05
ug/1 7470A 05/12/05
ug/1 6010B 05/09/05
ug/1 6010B 05/09/05
ug/1 6010B 05/09/05
ug/1 6010B 05/09/05
ug/1 6010B 05/08/05
ug/1 6010B 05/09/05
ug/1 60108 05/09/05
ug/1 6010B 05/09/05
ug/1 6010B 05/09/05
ug/1 6230D 05/14/05
ug/1 6230D 05/14/05
ug/1 6230D 05/14/05
ug/1 6230D 05/14/05
ug/1 6230D 05/14/05
ug/1 6230D 05/14/05
ug/1 6230D 05/14/05
ug/1 6230D 05/14/05
ug/1 6230D 05/14/05
ug/1 6230D 05/14/05
ug/1 6230D 05/14/05
Laboratory Certification Numbers:
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN -C-TN-01
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA 00109, WV
A2 -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Page 10 of 39
I
I
I
I
I
I
Oil.
1 I 1
1
1 I 1
1 11
1 11
1
1
~I
1
1 ii
1 ~· 1 ~. 1
1 11
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 06, 2005
Description NC State University
Sample ID MW-42
Collected By J. Ganey
Collection Date 05/05/05 11,41
Parameter
Chlorodibromomethane
Chlo roe thane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-Chloropropane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-0ichloropropane
2,2-0ichloropropane
1,1-0ichloropropene
Di-isopropyl ether
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
p-Isopropyltoluene
Methylene chloride
Methyl tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #86
Result Det. Limit
BOL 1.0
BOL 1.0
BOL 1.0
SOL 1.0
BOL 1.0
BOL 1.0
BOL 1.0
BOL 1.0
BOL 1.0
BOL 1.0
BOL 1.0
BOL 1.0
BOL 1.0
BOL 1.0
SOL 1.0
BOL 1.0
BOL 1.0
BOL 1.0
BOL 1.0
BOL 1.0
BOL 5.0
BOL 1.0
BOL 1.0
BOL 1. 0
BOL 1.0
BOL 5.0
BOL 5.0
BOL 5.0
BOL 1. 0
BOL 1.0
BOL 1.0
BOL 1.0
BOL 1.0
BOL 1.0
BOL 1.0
SOL 1.0
BOL 1.0
BOL 1.0
Det. Limit -Estimated Quantitation Limit(EQL)
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767 5859
Fax [phone]
Tax 1.0. 62-0814289
Est. 1970
May 16,2005
ESC Sample#
Site ID
Project#
Units Method
ug/1 62300
ug/1 6230D
ug/1 62300
ug/1 62300
ug/1 62300
ug/1 6230D
ug/1 62300
ug/1 62300
ug/1 62300
ug/1 62300
ug/1 62300
ug/1 62300
ug/1 62300
ug/1 62300
ug/1 6230D
ug/1 62300
ug/1 62300
ug/1 62300
ug/1 62300
ug/1 6230D
ug/1 62300
ug/1 62300
ug/1 62300
ug/1 62300
ug/1 6230D
ug/1 6230D
ug/1 62300
ug/1 62300
ug/1 6230D
ug/1 62300
ug/1 62300
ug/1 62300
ug/1 6230D
ug/1 62300
ug/1 62300
ug/1 62300
ug/1 6230D
ug/1 62300
Ll98075-04
2519
Date
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
Laboratory Certification Numbers:
AIIIA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN C-TN-01
Oil.
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA -00109, WV -233
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Page 11 of 39
ENVIRONMENTAL
SCIENCE CORP.
REPORT OF ANALYSIS
12065 Lebanon Rd.
Mt. Juliet, TN 37122
{615) 758-58S8
1-800-767-5859
Fax [phone]
Tax l.D. 62-0B14289
Est. 1970
Mr. John Harper
Piedmont Geologic May 16,2005
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 06, 2005
Description NC State University
Sample ID MW-42
Collected By J. Ganey
Collection Date 05/05/05 11:41
Parameter
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trime~hylbenzene
1,3,5-Trimethylbenzene
Toluene
Vinyl chloride
Xylenes, Total
BDL -Below Detection Limit
Lot #86
Result
BDL
BDL
BDL
BDL
BDL
BDL
BDL
Det. Limit -Estimated Quantitation Limit(EQL)
Det. Limit Units
1.0 ug/1
1.0 ug/1
1.0 ug/1
1.0 ug/1
5.0 ug/1
1.0 ug/1
3.0 ug/1
(
Laboratory Certification Numbers:
ESC Sample#
Site ID
Project #
Method
6230D
6230D
6230D
6230D
6230D
6230D
6230D
L198075-04
2519
Date
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
sentative
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN -C-TN-01
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA -00109, WV
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Note:
The reported analytical results relate only to the sample submitted.
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported, 05/16/05 18,11 Printed, 05/16/05 18,13
Page 12 of 39
I
I
I
I
I
I
Oil.
1
1 I
1
1
1
1
1 I
I
I
I
I
I
I
I
I
233
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 06, 2005
Description NC State University
Sample ID MW-45
Collected By J. Ganey
Collection Date 05/05/05 08,55
Parameter
Methane
Chloride
Nitrate
Sulfate
Alkalinity
Ethane
Ethene
TOC (Total Organic Carbon)
Mercury
Arsenic
Barium
Cadmium
Chromium
Iron,Dissolved
Lead
Manganese
Selenium
Silver
Volatile Organics
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon Tetrachloride
Chlorobenzene
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #86
Result Det. Limit
BDL 1000
3000 1000
BDL 100
BDL 5000
14000 10000
BDL 1000
BDL 1000
BDL 1000
BDL 0.20
BDL 20.
27. 5.0
BDL 5.0
29. 10.
100 100
BDL 5.0
180 10.
BDL 20.
BDL 10.
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1. 0
BDL 1.0
BDL 1.0
Det. Limit -Estimated Quantitation Limit(EQL)
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5B59
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 16,2005
ESC Sample#
Site ID
Project#
Units Method
ppb 8015M
ug/1 9056
ug/1 9056
ug/1 9056
ug/1 310.2.
ppb 8015M
ppb 8015M
ug/1 9060
ug/1 7470A
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 60108
ug/1 6010B
ug/1 60108
ug/1 -6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
L198075-05
2519
Date
05/09/05
05/06/05
05/06/05
05/06/05
05/11/05
05/09/05
05/09/05
05/12/05
05/12/05
05/09/05
05/09/05
05/09/05
05/09/05
05/08/05
05/09/05
05/09/05
05/09/05
05/09/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
Laboratory Certification Numbers:
C-TN-01
Dil.
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
l
1
1
1
1
1
1
1
1
l
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910 00109, WV -233
Page 13 of 39
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 06, 2005
Description NC State University
Sample ID MW-45
Collected By J. Ganey
Collection Date 05/05/05 08,55
Parameter
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-Chloropropane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane.
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
Di-isopropyl ether
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
p-Isopropyltoluene
Methylene chloride
Methyl tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #86
Result Det. Limit
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1. 0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 5.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 5.0
BDL 5.0
BDL 5.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1. 0
BDL 1.0
BDL 1.0
BDL 1.0
Det. Limit -Estimated Quantitation Limit(EQL)
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
l-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 16,2005
ESC Sample # Ll98075-0S
Site ID
Project# 2519
Units
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
Method
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
Date
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
Laboratory Certification Numbers:
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Page 14 of 39
C-TN-01
00109, WV
I
I
I
I
I
I
Dil.
1 I 1
1
1
1 I 1
1
1
1
1 I 1
1
1
1
1 I 1
1
1
1
1 I 1
1
1
1 I 1
1
1
1
1 I 1
1
1
1
1 I 1
1
1
1
I
2331
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 06, 2005
Description NC State University
Sample ID MW-45
Collected By J. Ganey
Collection Date 05/05/05 08,55
Parameter
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Toluene
Vinyl chloride
Xylenes, Total
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #86
Result net. Limit
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 5.0
BDL 1.0
BDL 3.0
Det. Limit -Estimated Quantitation Limit(EQL)
12065 Lebanon Rd.
Mt. Juliet, TN 37122
(615) 758-5B58
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 16,2005
ESC Sample# Ll98075-05
Site ID
Project# 2519
Units
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
Method
6230D
6230D
6230D
6230D
6230D
6230D
6230D
Date
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
Laboratory Certification Numbers:
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN C-TN-01
Oil.
1
1
1
1
1
1
1
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA 00109, WV -233
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Note:
The reported analytical results relate only to the sample submitted.
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported: 05/16/05 18:11 Printed: 05/16/05 18:13
Page 15 of 39
ENVIRONMENTAL
SCIENCE CORP.
REPORT OF ANALYSIS Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 06, 2005
Description NC State University Lot #86
Sample ID MW-46
Collected By J. Ganey
Collection Date 05/05/05 10,24
Parameter Result
Methane BDL
Chloride 5900
Nitrate 1700 Sulfate BDL
Alkalinity 12000
Ethane BDL
Ethene BDL
TOC {Total Organic Carbon) BDL
Mercury BDL
Arsenic BDL
Barium 41.
Cadmium BDL
Chromium 18. Iron,Dissolved 120
Lead BDL
Manganese 370 Selenium BDL
Silver BDL
Volatile Organics
Benzene BDL
Bromobenzene BDL
Bromochloromethane BDL Bromodichloromethane BDL
Bromoform BDL
Bromomethane BDL
n-Butylbenzene BDL
sec-Butylbenzene BDL
tert-Butylbenzene BDL
Carbon Tetrachloride BDL
Chlorobenzene BDL
BDL -Below Detection Lim.it
Det. Limit -Estimated Quantitation Limit{EQL)
Det. Limit
1000
1000
100
5000
10000
1000
1000
1000
0.20
20.
5.0
5.0
10.
100
5.0
10.
20.
10.
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
Units
ppb
ug/1
ug/1
ug/1
ug/1
ppb
ppb
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
Laboratory Certification Numbers:
12065 Lebanon Rd.
Mt. Juliet, TN 37122
{615) 758-5858
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 16, 2005
ESC Sample#
Site ID
Project#
Method
8015M
9056
9056
9056
310.2
8015M
8015M
9060
7470A
6010B
6010B
6010B
6010B
6010B
6010B
6010B
6010B
6010B
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
L198075-06
2519
Date
05/09/05
05/06/05
05/06/05
05/06/05
05/11/05
05/09/05
05/09/05
05/12/05
05/12/05
05/09/05
05/09/05
05/09/05
05/09/05
05/08/05
05/09/05
05/09/05
05/09/05
05/09/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN -
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
C-TN-01
00109, WV
Page 16 of 39
I
I
I
I
I
I
Dil.
1 I 1
1
1 I 1
1
1 I
1
1 I 1
1
1
1 I 1
1
1
1 I 1
1
1 I 1
1
1
1
1 I 1
1
1
1
I
2331
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
! I
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 06, 2005
Description NC State University
Sample ID MW-46
Collected By J. Ganey
Collection Date 05/05/05 10,24
Parameter
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-Chloropropane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
Di-isopropyl ether
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
p-Isopropyltoluene
Methylene chloride
Methyl tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #86
Result Det. Limit
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1. 0
BDL 1. 0
BDL 1.0
BDL 1.0
BDL 1. 0
BDL 1. 0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 5.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 5.0
BDL 5.0
BDL 5.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1. 0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
Det. Limit -Estimated Quantitation Limit(EQL)
12065 Lebanon Rd.
Mt. Juliet, TN 37122
{615) 7S8-5858
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 16,2005
ESC Sample#
Site ID
Project#
Units Method
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
L198075-06
2519
Date
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
Laboratory Certification Numbers:
C-TN-01
Oil.
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
00109, WV -233
Page 17 of 39
ENVIRONMENTAL
SCIENCE CORP.
REPORT OF ANALYSIS Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 06, 2005
Description NC State University Lot #86
Sample ID MW-46
Collected By J, Ganey
Collection Date 05/05/05 10:24
Parameter Result
Trichlorofluoromethane BDL 1,2,3-Trichloropropane BDL
1,2,4-Trimethylbenzene BDL 1,3,5-Trimethylbenzene BDL
Toluene BDL Vinyl chloride BDL
Xylenes, Total BDL
BDL -Below Detection Limit
Det. Limit -Estimated Quantitation Limit(EQL)
Det. Limit
1.0
1.0
1.0
1.0
5.0
1.0
3.0
Units
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
Laboratory Certification Numbers:
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 16,2005
ESC Sample# L198075-06
Site ID
Project# 2519
. Method
6230D
6230D
6230D
6230D
6230D
6230D
6230D
Date
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA C-TN-01
00109, WV
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -99_8093910
Note:
The reported analytical results relate only to the sample submitted.
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported: 05/16/05 18:11 Printed: 05/16/05 18:13
Page 18 of 39
I
I
I
I
I
I
Dil.
1 I 1
1
1
l I l
1
I
I
I
I
I
I
I
2331
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 06, 2005
Description NC State University
Sample ID MW-60
Collected By J. Ganey Collection Date 05/05/05 11,41
Parameter
Methane
Chloride
Nitrate
Sulfate
Alkalinity
Ethane
Ethene
TOC (Total Organic Carbon)
Mercury
Arsenic
Barium
Cadmium
Chromium
Iron,Dissolved
Lead
Manganese
Selenium
Silver
Volatile Organics
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon Tetrachloride
Chlorobenzene
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #86
Result Det. Limit
BDL 1000
3600 1000
1300 100
BDL 5000
13000 10000
BDL 1000
BDL 1000
BDL 1000
BDL 0.20
BDL 20.
17. 5.0
BDL 5.0
BDL 10.
BDL 100
BDL 5.0
140 10.
BDL 20.
BDL 10.
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1. 0
BDL 1.0
BDL 1. 0
BDL 1.0
BDL 1.0
Det. Limit -Estimated Quantitation Limit{EQL)
12065 ·Lebanon Rd./~'
Mt. Juliet, TN 3712~ ............... .,.
[phone] ~
1-800-767-5859
Fax {615} 758-5859
Tax I.D. 62-0814289
Est. 1970
May 16,2005
ESC Sample #
Site ID
Project#
Units Method
ppb 8015M
ug/1 9056
ug/1 9056
ug/1 9056
ug/1 310.2
ppb 8015M
ppb 8015M
ug/1 9060
ug/1 7470A
ug/1 6010B
ug/1 60108
ug/1 6010B
ug/1 60108
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
Ll98075-07
2519
Date Oil.
05/09/05 1
05/06/05 1
05/06/05 1
05/06/05 1
05/11/05 1
05/09/05 1
05/09/05 1
05/12/05 1
05/12/05 1
05/08/05 1
05/08/05 1
05/08/05 1
05/08/05 1
05/08/05 1
05/09/05 1
05/08/05 1
05/09/05 1
05/08/05 1
05/14/05 1
05/14/05 1
05/14/05 1
05/14/05 1
05/14/05 1
05/14/05 1
05/14/05 1
05/14/05 1
05/14/05 1
05/14/05 1
05/14/05 1
Laboratory Certification Numbers:
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Page 19 of 39
C-TN-01
00109, WV -233
ENVIRONMENTAL
SCIENCE CORP.
REPORT OF ANALYSIS Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 06, 2005
Description NC State University Lot #86
Sample ID MW-60
Collected By J. Ganey
Collection Date 05/05/05 11:41
Parameter Result
Chlorodibromomethane BDL
Chloroethane BDL Chloroform BDL Chloromethane BDL
2-Chlorotoluene BDL
4-Chlorotoluene BDL
1,2-Dibromo-3-Chloropropane BDL 1,2-Dichlorobenzene BDL
1,3-Dichlorobenzene BDL 1,4-Dichlorobenzene BDL
Dichlorodifluoromethane BDL 1,1-Dichloroethane BDL
1,2-0ichloroethane BDL 1,1-Dichloroethene BDL
cis-1,2-0ichloroethene BDL
trans-1,2-Dichloroethene BDL
1,2-Dichloropropane BDL
1,3-0ichloropropane BDL
2,2-Dichloropropane BDL 1,1-Dichloropropene BDL
Di-isopropyl ether BDL Ethylbenzene BDL
Hexachlorobutadiene BDL
Isopropylbenzene BDL
p-Isopropyltoluene BDL
Methylene chloride BDL
Methyl tert-butyl ether BDL
Naphthalene BDL
n-Propylbenzene BDL
Styrene BDL
l,l,1,2-Tetrachloroethane BDL
1,1,2,2-Tetrachloroethane BDL Tetrachloroethene BDL
1,2,3-Trichlorobenzene BDL
1,2,4-Trichlorobenzene BDL
1,1,1-Trichloroethane BDL
1,1,2-Trichloroethane BDL
Trichloroethene BDL
BDL -Below Detection Limit
Det. Limit -Estimated Quantitation Limit{EQL)
Det. Limit
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
5.0
5.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
l-800-767-5859
Fax (615} 758-5859
Tax I.D. 62-0814289
Est. 1970
May 16,2005
ESC Sample # Ll98075-07
Site ID
Project# 2519
Units
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
Method
6230D
6230D
.6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
62300
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
62300
6230D
6230D
6230D
6230D
Date
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
Laboratory Certification Numbers:
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Page 20 of 39
C-TN-01
00109, WV
I
I
I
I
I
I
Oil.
1 I 1
1
1
1 I 1
1
1
1
~I
1
1
~I
1
1
~I
1
ti 1
1
ti
1
1
~I
1
1
I
231
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 06, 2005
Description NC State University
Sample ID MW-60
Collected By J. Ganey Collection Date 05/05/05 11:41
REPORT OF ANALYSIS
Lot #86
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 16,2005
ESC Sample# Ll98075-07
Site rD
Project# 2519
Parameter Result Det.. Limit Units Method Date Oil.
Trichlorofluoromethane BDL 1.0 ug/1 1,2,3-Trichloropropane BDL 1.0 ug/1 1,2,4-Trimethylbenzene BDL 1.0 ug/1 1,3,5-Trimethylbenzene BDL 1.0 ug/1
Toluene BDL 5.0 ug/1 Vinyl chloride BDL l. 0 ug/1 Xylenes, Total BDL 3.0 ug/1
BDL -Below Detection Limit
Det. Limit -Estimated Quantitation Limit(EQL)
Laboratory Certification Numbers:
6230D
6230D
6230D
6230D
6230D
6230D
6230D
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN C-TN-01
l
l
l
l
l
l
l
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA 00109, WV -233
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910 Note:
The reported analytical results relate only to the sample submitted.
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported: 05/16/05 18:11 Printed: 05/16/05 18:13
Page 21 of 39
ENVIRONMENTAL
SCIENCE CORP.
REPORT OF ANALYSIS Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
May 06, 2005 Date Received
Description NC State University Lot #86
Sample ID
Collected By
Collection Date
Parameter
Volatile Organics
Benzene
Bromobenzene
Bromochloromethane
TRIP BLANK
J. Ganey
05/05/05 00,00
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon Tetrachloride
Chlorobenzene
Chlorodibromomethane
Chlo roe thane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
l,2-Dibromo-3-Chloropropane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
Di-isopropyl ether
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
p-Isopropyltoluene
Methylene chloride
BDL -Below Detection Limit
Result
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
Det. Limit -Estimated Quantitation Limit(EQL)
Det. Limit
1.0
1.0
1.0
1.0
1.0
1.0
1. 0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
Units
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
Laboratory Certification Numbers:
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 16,2005
ESC Sample#
Site ID
Project#
Method
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
L198075-08
2519
Date
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
C-TN-01
00109, WV
Page 22 of 39
I
I
I
I
I
I
Dil.
11
1
1
ti
l
1
ti
1
ti l
l
~I
1
1
ti
1
l
ti
l
1
ti
1 11
23t
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
ENVIRONMENTAL
SCIENCE CORP.
REPORT OF ANALYSIS
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
May 06, 2005 Date Received
Description NC State University Lot #86
Sample ID
Collected By
Collection Date
Parameter
TRIP BLANK
J. Ganey
05/05/05 00,00
Methyl tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Toluene
Vinyl chloride
Xylenes, Total
BDL -Below Detection Limit
Result
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
Det. Limit -Estimated Quantitation Limit(EQL)
Det. Limit
5.0
5.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
3.0
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 16,2005
ESC Sample # Ll98075-08
Site ID
Project # 2519
Units Method Date
ug/1 6230D 05/14/05
ug/1 6230D 05/14/05
ug/1 6230D 05/14/05
ug/1 6230D 05/14/05
ug/1 6230D 05/14/05
ug/1 6230D 05/14/05
ug/1 6230D 05/14/05
ug/1 6230D 05/14/05
ug/1 6230D 05/14/05
ug/1 6230D 05/14/05
ug/1 6230D 05/14/05
ug/1 6230D 05/14/05
ug/1 6230D 05/14/05
ug/1 6230D 05/14/05
ug/1 6230D 05/14/05
ug/1 6230D 05/14/05
ug/1 6230D 05/14/05
ug/1 6230D 05/14/05
ug/1 6230D 05/14/05
Laboratory Certification Numbers:
C-TN-01
Dil.
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA 00109, WV -233 AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Note:
The reported analytical results relate only to the sample submitted.
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported: 05/16/05 18:11 Printed: 05/16/05 18:13
Page 23 of 39
Sample#
L198075-04
L198075-05
L198075-06
L198075-07
L198075-08
Attachment A
List of Analytes with QC Qualifiers
Analyte
Chloroethane
Chloromethane
Dichlorodifluoromethane
Chloroethane
Chloromethane
Dichlorodifluoromethane
Alkalinity
Chloroethane
Chloromethane
Dichlorodifluoromethane
Chloroethane
Chloromethane
Dichlorodifluoromethane
Chloroethane
Chloromethane
Dichlorodifluoromethane
Qualifier
J4
J4
J4
J4
J4
J4
J3
J4
J4
J4
J4
J4
J4
J4
J4
J4
Page 24 of 39
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Qualifier
J3
J4
Attachment B
Explanation of QC Qualifier Codes
Meaning
The associated batch QC was outside the established quality control range
for precision.
The associated batch QC was outside the established quality control range
for accuracy.
Qualifier Report Information
ESC utilizes sample and result qualifiers as set forth by the EPA Contract Laboratory Program and
as required by most certifying bodies including NELAC. In addition to the EPA qualifiers adopted
by ESC, we have implemented ESC qualifiers to provide more information pertaining to our analytical
results. Each qualifier is designated in the qualifier explanation as either EPA or ESC.
Data qualifiers are intended to provide the ESC client with more detailed information concerning
the potential bias of reported data. Because of the wide range of constituents and variety of
matrices incorporated by most EPA methods,it is common for some compounds to fall outside of
established ranges. These exceptions are evaluated and all reported data is valid and useable
unless qualified as 'R' (Rejected).
Definitions
Accuracy -The relationship of the observed value of a known sample to the
Precision
Surrogate -
true value of a known sample. Represented by percent recovery and
relevant to samples such as: control samples, matrix spike recoveries,
surrogate recoveries, etc.
The agreement between a set of samples or between duplicate samples.
Relates to how close together the results are and is represented by
Relative Percent Differrence.
Organic compounds that are similar in chemical composition, extraction,
and chromatography to analytes of interest. The surrogates are used to
determine the probable response of the group of analytes that are chem-
ically related to the surrogate compound. Surrogates are added to the
sample and carried through all stages of preparation and analyses.
Control Limits (AQ)
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
31-119
12-134
51-141
Nitrobenzene-d5 43-118 Dibromfluoromethane 70-130
2-Fluorobiphenyl 45-128 Toluene-dB 70-130
Terphenyl-dl4 43-137 4-Bromofluorobenzene 70-130
TIC Tentatively Identified Compound: Compounds detected in samples that are
not target compounds, internal standards, system monitoring compounds,
or surrogates.
(SS)
70-130
70-130
70-130
Page 25 of 39
ENVIRONMENTAL
SCIENCE CORP.
Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Anal te
Quality Assurance Report
Level II
L198075
.~:~l?.9 i; a:~ :<?:tY/ 13. Iarik'·· Result::,." Units bate Anal zed
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 16, 2005
Batch
ChlOride:t•·· .· ................ •·····•······•····•···· ·••·•·••····•·})•n·tt)t·t?c:1}> •)/}\mg/T\ +• •f:0.5/0.6/0.5\ 12/05 t):')l'IG20.0:aa.6)•': •· ..
Nitrate ·· < .1 mg/1 05/06/05 12,05 WG200886
Sulfate < 5 mg/1 05/06/05 12, OS WG200886
·•··•·•t•.•?}t{•••t ••·••••••·•·•tt.·••••?I•.••• ;;[~j{•i •·••••••.••••tJi;Jg}JJ •·••}i/6~ ··•·••••··•·••••i~@}Ji.6&6· .. •·· Chloride
Nitrate
sulfat.e>
Arsenic
.B.A.i:i:lliriJ/:C?::
Cadmium
Chromium Lead\/·''=·•:•--
Manganese
Selenium $, i'."l:Y.¢i){'''' ::-·, ..
Iron,Dissolved
1@3f?\::tf8t;[ti/gt~;;:{if11 Carbon)
< .1 mg/1 05/06/05 16,05 WG201000 · ·· · ·· ······•· · .. ~•• 5}" ···•·· ·•· •·•••• \mg/1· ··/o5/0.6/.0S ••16\05) •••:xw:.a2Q10Qo./
< 1
<
<
r:·•r:··t:!4;I~~f6l:~!~~~ri;·h"ri"'} ·••··•··•·>••··••+>•········•·r•····•)d{····•~••\:g:g1 t•·(()•···••t•·fr••·rm~jt tt>g§·~t·t·~gg .. g§··:·:g.g ···•·<••·~g~gf!!~······•·r••·•····
1,1,2,2-Tetrachloroethane < .001 mg/1 05/11/05 05,00 WG201492
1/r-;2cTrichl6roethane• >· ·· ••••· -.:~ -:•.oon• ····· ··•··· \mg/1•.•t •+o5/H/o5 )o5.•foo · •/wG201492 ·.·.·
1,1-Dichloroethane < .001 mg/1 · · 65/11/05 05,00 ·· WG201492
1,1-Dichloroethene < .001 mg/1 05/11/05 05,00 WG201492
I
I
I
I
r·:r:~~ft~~~f~t~~:gt!~t+ ······••?••·•·•••t•······ t••···· fii:ix:ggr<•·• ·•····•·tutt~n tt••····+<g.~jff1g~· ·•gg;gg •·••·tn•••··•~gigi!·~·~··t•·······•·•·•·
1,2,3-Trichloropropa!le < .001 mg/1 05/11/05 05,00 WG201492 I
L;2;4•;.Trichlorobehzene\ · · ·· •·• \.< :001• ••• >• • •••••mg/1 ••• ••• 05/11/05 os ,o.o·•• WG20.1492 • · ·.·· • ·••• ••• • ••f l,2,4~·Trimethylbenzene · < .001 mg/1 ··· ·· 05/11/05 05,00 WG201492
l,2-Dibromo-3~Chloropropane < .002 mg/1 05/11/05 05,00 WG201492 ·t :~!gl~~.~~~~!!~!.~;:r·•··•········•.• .... •.·.· .. ·.·.•.·.··.·.·•·•·•··•····••·····•···•···•···•·•·········.·•x;·····;:g.gf ·•···············•·•··•··•·•·•·?):?l·•••?• ···?r•·g1~·i·tig1 ·g1·::g·g···· ·············:1~gnf i?I•·········· •·•·······•tt••··· t.•·.·· .. ·•·• .• ·.··.1
1/3'/5\Trimethylbenzene/t• t.• ·••··••··< /•.o.or •••••·••·• ··•••?••••mglT••• ••\{05/H/.95• .o5.,.oo I••••W.G20H9.2•?•• 1,3-Dichlorobenzene < .001 mg/1 05/11/05 05:00 WG201492
1,3-Dichloropropane < .001 mg/1 05/11/05 05:00 WG201492 1.::-;:_4·::::,oiC:hlciii.ObE!i\z_en:~t\t }<::\•'.' oo i=,=· . .:-,:,,·=·=·' · ,,:,:::,:<.-/\(ITLg/ 1 ··· · U/:os/lt/ os·· ·as·::· o o=t=,=,,,· · ."7(;2_0_:1."4·5)2::=t===···
2, 2~bichloropropane. ~ .66i mg/1 os/ii/65 05 ,oiJ WG201492
2-Chlorotoluene < .001 mg/1 05/11/05 05,00 WG201492
4/ChlOrcitoluehe•••••••• .·.···• ···•···· ·••·•·•• ·•·•••·•·• •••••·•••••••••••••••• • ••••••••••••••••••?< Y:'0.01/ • •••••••( ••••/•••tmg/1{ •/C::••O 5/11-/0 5• 0 5 , 0 0 •II il'IG2014 92 t• ·· •.•.·
Benzene < . 001 mg/1 · .·· 05/11/05 05, 00 WG201492
Bromobenzene < .001 mg/1 05/11/05 05,00 WG201492
Br.om<ichl.i,r:o.irtettiari.EiJ.\.·••• ·••••·••••••••••·••••••••·••·••••t•.•/•••·(•·••··•••t••••·•••t<)/o·o•t••· ••t••··•·•·••ii••••• t•riig/1. /•.i••••f•••••OS/Tf/05 ·•os·,·o O •• <•••·•••••WG2014. 9.2•·•·••> Bromodichloromethane < . 001 mg/1 05/ll/05 ·o"s .. Co·o WG201492
Bromoform < .001 mg/1 05/11/05 05,00 WG201492
Broinoinetha.ne \ ••• .••·· ••••· ·••X }oar -:.mg/I)•·· /•\05/11/05 .. 05 ,oo•• / .wG201492··•·· Carbon Tetracfrloride < . 001 mgfl ·. 65/ll/05 05, 00 WG201492
g~i6i6~ibi6Z6metharie•• •··•··••·•·•···•··••·••··•·•·•··· ... •.•·•·•·····•,,•···•·•·•·•·•···•-::::-:r•••e:<·.· i_·.g
0
g
0
.. i
1
.. r· ••••• ••·•••••••Y>•;m§g;/.i
1
..-x• >t•·g
0
.. ~
5
j
1
i
1
i
1
j
1
go· .~
5
... • g
0
.. ~
5
;_:. go g
0
.. \ ~wJGJ
2
g
0
i
1
!
4
.. ~
9
~
2
. t····· th1or6'e·1:hane ..................... .
Chloroform < .005 mg/1 05/11/05 05,00 WG201492 I
Page 26 of 39
I
I
I ENVIRONMENTAL
SCIENCE CORP.
I Piedmont Geologic Mr. John Harper
6003 Chapel Hill Road Suite 109 I Raleigh, NC 27607
I
Quality Assurance Report
Level II
Ll98075
'dC~~-ti()t*.~?tY}.B.'.t~ii~/? Result Units Date Anal zed
Page 27 of 39
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I .D. 62-0814289
Est. 1970
May 16, 2005
Batch
ENVIRONMENTAL
SCIENCE CORP.
Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
cis-1,2-Dichloroethene
Analyte
chloridet··
Chloride··-·
Nitrate
Nifi.-ate/:::::r,=, sulfate
Sulfate
1eA1i:g:~:id~1::,·::::,x
Chloride ~t ~~!ft:f:/·.C-=··· ..
Sulfate sul.fate··
TDC (Total <?.1:9i3.~~-c Carbon) X'i'R!I{1~Iifi;t:::r:,--..
Alkalinity
Anal te
Chlo:ride:/ '"' '· Nitrate
Sulfate :8-Ji:::ftd::<: ::
Nitrate sulfate'c.·.
Arsenic .B_i3:ii1Jitj\\{/
Cadmium
Chromium
Quality Assurance Report
Level II
Ll98075
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 16, 2005
< .001 mg/1 05/14/05 02,35 WG201995
Units :·:·:· DUP_lfa::_at.e\\ .. ReSUlt ····oti.plic'ate RPD Limit Ref Samp Batch
f::,:L.~-~Cfr:},;,t.C)fYt:c;;_ojitfOl 'sarnp1e/r: Units Known Val ·t{e"SU1t···· % Rec Limit Batch
Page 28 of 39
I
I
I
I
I
I
I
I ENVIRONMENTAL
SCIENCE CORP.
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
I Piedmont Geologic
Mr. John Harper
Tax I.D. 62-0814289
Est. 1970
6003 Chapel Hill Road Suite 109
NC 27607
Quality Assurance Report
Level II
Ll98075 May 16, 2005 I Raleigh,
teadt••>·••·••···· ······························· .. ·····.··.·· •::c>mg/r•· • >tt · .. ·.·.· ·•••::::'ti•coa::· ·•· ••::::• •t100::••· ••··:05~1ts· ·•·cwa201050> ··
% Rec Limit Batch
toc/1Tota1 •··orgariic••\carb.oril\•··· •·••••·•·••••t(•t<•·•••·•••<t.\•.mg/1 \ (4·• <I• Jt•·••·•••r3\.40 LifrttI. (07••,o• r•·0.5{ll.s> •••·1wa2.0119.2 .. •r::::••
Ethane ppm 1000 860. 86.0 60-122 WG201256
~ir~1~~ ··································.·•.···.··.·.•.•·.·.·.··.•.· ·.···.··•·•·••·•·····•·••·•·•·•·····•·•···••···•·····•·• 7~~~ ? ·····•rggg <. ··•·•···•·•·•·•·•·•·•~n:r ·.·.· ·.···.· g<g <<t}5I21 t~g~gf~t~ /
lrf~.t.:C\iiY..
1,1,1,2-Tetrachloroethane mg/1 .02 0.0168 83.9 68-125 WG201492 1i·?rt!!f!!t!~~!!~!~!iii~it ·•·••f{)( ) v!it) ·•·::::t•······~··g~) ·•· f?•••ti{g:g!!~{>• t•·•Jl;i:;!:· t<•·!~·~til ·••t.~g!·gt:!!}••··•·::c••··
.1>1;oichlor6etharie···•······ ·····•. ···· ·············· >•••<•••·••·••ing/1}: • f.02> r • ·•·••••··oyo22of<• • /? 110\/ ••t••••5•0+11.o •••Jwa2ot~92>•·· i.: .. i".:.·i:ii'Ch"i°O.rOetheile mg/1 .02 0.0222 . ·11f·;·· 67-137 WG201492 li:l:isi;t~~[~f~i!~b~: ) ...... ·····.·•·•·•·•·• >miH F ••••• >iglr .·.·.·.·.··.·.•.•.•.· /gig Hi c•····· .... ·.·.·.···.·.··ii:i ( li~f~i tHg~gNili··
.i;.~;!.=.I~tfu~t.~if~:lii:li: tt u i• ? t tfu~~.•i •••••• n••tig~.> t••·•·••?•·•gi.gi~~•+••••·• "'"'••?>}•••~ .. ~:·~ ·.•tr•·•••!!·=ii~.t •·••v.~§~.gi4•~·~•·•r··•··
llii•~•~ii~Iiiiii~iiii;••:•:•;•:•;;.: ... t•· ••• ><ii rilii> •·••·t••·<ti··lir r <•·· tI.~••i.~iiiin• <<••··•<1ii·! i t:ii~•iii• •<~il.~Hii >·>•·•·
1,3,5-Trimethylbenzene mg/1 02 O 0157 78 4 67-121 WG201492 1•1tJ.:Cofchliir9bEinz•e·n,t•i>••••••.:r•····• ·•·•·••·····•·•·•·••J••·•mg/1•t•••• ···•·•·••·•••·•Io4••::··· ·?·••··••···•••····•··o)•o•1;;,i:•• ··.·•··•·•••···•••••··••·••••41•;•0 ••·•·•<·•···•.•,;·7·'1·2·6 ••••>.wa.2•01.49.2.\.•>••
1,3-Dichloropropane mg/1 .02 0.0162 81.1 71-114 WG201492
1,4-Dichlorobenzene mg/1 .02 0.0182 90.8 72-118 WG201492
I
f:ghfi$~2~f~tri~paile/ (%~Ji 4 > :g~r •g:gf~j .. ···•·•·•···· \l~i:t·· .•.•.··.·•··~r1~t <:g~gr:~~:·····
4-Chlorotoluene mg/1 .02 0.0157 .78.6 67-126 WG201492 Benzene·•· /ti/ <•itt•t <•••••<&<< bing/Ii•· /\0.2\ •·••·••·•·•::;:9,01.90/? >?••t>••·t9.5\2 • ?••\63\121) •··twa20149·2:••·····•·•·•
Bromobenzene mg/1 .02 0.0168 84.1 73-123 ····wa2014gi···
Bromochloromethane mg/1 .02 0.0216 108. 66-128 WG201492 I !!~;~!f ~t:::om.,thanf•• ·•······ ······•·•·+·••·••••·•·•·•·•·•••••·•••·•·>•••••·•••·•••:~·~·fi••• ?•··••·>g;•·I• · ·•··••••·<ii•••>••>.g:•g.}·~i <•· t•9~:••~•· r ·••;~:fj~ <••·L~§~·&I!~~ti•
Carboh\.Tefriic.hforide .. .. ·••.•·',• e:~~i? • :g}? .. ... /g.:g~.~i\ /1it;I. >••·~6ci~; •.• ~g~g}!~tr
Chl0r6b'e·n·zelle · ·· ··· mg/1 .02 i:>"":·bi6·i 83 .3 ?t~·121 ··wG2cii492·· ·
I Chlorodibromomethane mg/1 . 02 o. 0161 BO. 3 67-117 WG201492
§~Ittt~8t~net .rt>• ·········••t H •.t~~;f+ ·••t;rg.~>?••·· >••·••·•·•·•·• \••g:g~·sE·•t•·•· ····••··•·\i•iii:~···· ::r:~srir· ··T:g~gr:•~·~{·•·•·•·······
•. ~E·.·h.~t: ... •·h~ ... :Y{.i.1·. ;br.~e···.;n-iz .. :.,e' .••.. ~nf.~e·.·.: ... •.· .... ~ .•.•. •.··.••r·;•.•••··•••~•·····•.••·m.: ...•. • .. •.••~•••.•··••.·h•t·••····•·:•.••••.••·•··n.a···•·••··.•·: .•. · .. ·.•.••e·•.•.•.•.•.• ... •.•.·.•·····••·.·.•.·•.••.•.•·· ••·?•••·•··•·•••?.·•t••·c .• ••Wi••)••·~lii ii?t••·s•·l·~•i,: •·•>••.•<••·t .. l'.·!i~!· i) t•••!•~j•·~· r.·/it~·~ii }//~ii~~!·1·!/?> ................. ··.···. •Iing/1( ···• •?02 •• • I••·•o•····o160>I • :':'80· 1· ······••o\o)?· ..... \WG20T492)•••· Hexachlorobutadiene .,, .... mg)l'·· ,:·::,::,:,:_:_~-··0°2"''···-...... ·-.:··::-:,::=:=·(:(·(j"f6-4.,:,:-:-·. --=·-··.-: ·5j(~·2 64 -107 WG2014 92
I ~:~~;r~n~~[i~~r~!el:.he,:' tmi~~ ig~r··.·•· ... >>g)gi!lr ···•···•·•·•·•·•···•·•·•.•·•·•···••·•ii:l ··•···•i~~Hir r.;g~H;i~?
n-Butylbenzene mg/1 .02 0.0166 83.1 68-124 WG201492
nf Prop'fl.""n~eiii>•·••• •••••·•·••.Jt•t +<••· ttv·•• Jmg/1•.:•·• •• .+••••c:o.2•v ? •···•·••·r? t\o :.of.5.4 t ::::•t•••·•••••r•·•••·•••·7 5•••·0 t•··•r•••••··6?/12.4••· ··•••·rwa201~•92• I Naphthalene mg/1 .04 0.0194 48.4 77-140 ·wG20149.i
Page 29 of 39
I
ENVIRONMENTAL
SCIENCE CORP.
Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
!toluene
Analyte
Quality Assurance Report
Level II
Ll98075
m /1 .02 0.0159
;tabiii:iltofy control silmple)
Units Known ·var· Result
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 16, 2005
79.5 65-125 WG201492
% Rec Limit Batch
I
I
I
I
I
I
I ENVIRONMENTAL
SCIENCE CORP.
12065 Lebanon Rd.
Mt. Juliet, TN 37122
{615) 758-5858
1-800-767-5859
Fax [phone]
I Piedmont Geologic
Mr. John Harper
Tax I.D. 62-0814289
Est. 1970
6003 Chapel Hill Road Suite 109 Quality Assurance Report
Level II I Raleigh, NC 27607
Ll98075
.02
May 16, 2005
mg/1 0.0179 89.7 67-124 WG201995
.,:,·Ji~P9.!~.t:9_lj,::::_.G9i.i.t:to1 i:.$*-rt1Pl¢}?l Units Known Val Result % Rec Limit Batch
tt~~-b'<?#-~~_o_cy:yc;~n~t_¢>_1\,_s~mp~:~: )?~P.:i.:rc:~:~:~·:}t Units LCSD Res Ref Res RPO Limit %Rec Batch
mg/1 1.04 1. 04 o.oo 20 104. WG201062
···.·······•···•·····•r•·•·•···•~~;t··· •n•>}:!ir• ·····•·····••t•;n1~·•·········· ::&:••i~➔~ ·•·•Ii<· ··•<i1:•6·••··•··· ··•····wa;ttrt;··
li:i:t?tI~~it~~l~~ci~;ha.rie ' . }%§jF ><rgHa/ <g:g}!·~··· rrr:i~•.·.· \t~• . {~t~~)} ><:g~gf{~~t···•···
1,1,2,2-Tetrachloroethane mg/1 0.0165 0.0158 4.52 13 •82.5 WG201492
1••;•1•;2\:i:,:ichlciroi,tllarie{••/?t.•· •·•·•••••·•··••••••tt•·•·<·•·i.•·t•••·••·irig/l• ••t>Lo.,.0.1.5•9 ifto:•0•1.51/\ ··•·s<•19 (9.••••···• /\I\1 9.?6) t•• /wc;:20•149.2••
1t.;.t;gi~~li;iii~i~ie .. r· .................... ;i~lr }tg~ii r.gig!!~. ·•·•·•·t:H· .. H< ....... Ht •·•·•·•·······•·•·•~g~gHi! ... · .... . 1,2;3-Trichloroben·zene mg/1··· ··oiol77 .. ··o.Ol89··· 6·:47 14 ··00·:;,••••••i•wa2ol49//.
lii.~ .. :}iiit2~t6f6b~irn:ri: t x ).~§ji; .g;gt~~ ·t g;gi;{y ~:~.~ + i~ r •·•n!j)iit \:g~gi!~.~ r··· ·
1,2,4-Trimethylbenzene mg/1 0.0150 0.0150 0.0477 14 75.2 ·wG201492.
1,2-Dibromo-3-Chloropropane mg/1 0.0177 0.0164 7.58 15 88.3 WG201492
i:}igt@~i§~§~rn!~te y· 1 ffi§~·f( vg:g~~; grggI 2 r?~! < g• <fi{~·· t :g}g}:·~~ r ..
I ~'.l~I~i~f~;igf[;ig[•frieI ··············E!~f tg?gf i~ .?>g!Hil 4:ii r~iw > i!!~ +ijg~gi:il t··
1,3-Dichloropropane mg/1 0.0171 0.0162 5.56 11 85.7 WG201492
11i.4.\l)f~hlciol:i.¢rizerie) • t irig/1•: to\019.0/ ro.001s2 > 4074 ?13) {~5/2 {WG.201492 / ..
Page 31 of 39
I
ENVIRONMENTAL
SCIENCE CORP.
Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
2,2-Dichloropropane
Quality Assurance Report
Level II
L198075
mg/1 0.0226 0.0231 1. 99 10
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 16, 2005
113. WG201492
I
I
I
I
ttJ-!*l)_~~~:t~tt.Y./G9.iitfq_1:r:s~:ri.tPJ¢ {Pt.iP.J:J¢~tf: .,;. I
:cAn=acclc<y_,tc,ec._ ________________ oeU_,,nc,i_st_es'--=LC:C:-=SC:D'---"R"'e'-'s'--"R"'e'-'f'---'R"'e'-'s'-· __ _,R0cPc,De..._--'L"-i"· mc,i=-· t=-%:,_R,oe,,_c=-__ B,,,,_a-"t=c-"h-----~
I
Page 32 of 39
I
I
I ENVIRONMENTAL
SCIENCE CORP.
I Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road
27607 I Raleigh, NC
2-Chlorotoluene
I
I
Suite 109 Quality Assurance Report Level II
L198075
mg/1 0.0177 0.0181 2.20 26
1206S Lebanon Rd.
Mt. Juliet, TN 37122
(615} 758-5858
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 16, 2005
88.3 WG201995
\/.i:.i~l?.9l.~.t:¢ifi\.C,¢f_ri_tt9.+'(S~finpp~ iiPiJP.;t;:\"¢~1:.¢.t\ . Units LCSD Res Ref Res RPD Limit %Rec Batch
Page 33 of 39
ENVIRONMENTAL
SCIENCE CORP.
Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Analyte
Quality Assurance Report
Level II
L198075
Units \\:_~-~.t.t4;~t~Pt1<¢<:\ MS Res Ref Res
Page 34 of 39
TV
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 16, 2005
% Rec Limit · Ref Samp Batch
I
I
I
I
I
I
I ENVIRONMENTAL
SCIENCE CORP.
I Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road I Raleigh, NC
Alkalinity
al te
1 Analyte
I
27607
Suite 109 Quality Assurance Report
Level II
L198075
mg/1 72 .0 15.0 50
)?~~.t:#}~?.?P~}~¢?f Units MS Res Ref Res TV
Page 35 of 39
12065 Lebanon Rd.
Mt. Juliet, TN 37122
{615) 758-5858
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 16, 2005
114. 80-120 L198011-01 WG201562
% Rec Limit Ref Sam Batch
Limit %Rec Ref Samp Batch
ENVIRONMENTAL
SCIENCE CORP.
Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Quality Assurance Report
Level II
L198075
12065 Lebanon Rd.
Mt. Juliet, TN 37122
{615) 758-5858
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 16, 2005
I
I
I
I
Chloride:<)•••••·•··•••·· N"i trat"e··-·-·-· ·
Sulfate Ehr ~:tr a:~,)::::::::::-·-::: .. ··
.... ··.·.··•.•.•·.·.• ........ •.•······· / E!il t !!:!J r:r:1~{ i t!~·! x ~·g J n~: ttH!I~!!g! :g!gg·!!I
........ ···············•·······································•~iit••· ...... :!;.fat•·· ••·r:I:.!.t ······· t•?·••t.: gi .·········•···~•i•··•·•i ........ !!~I I•)rtti!g;!.~.g.t. ~~i~n, Nitrate $4J:(ii t.:¢\:/:t·
Arsenic
~.ilfillffi{(>:'-/·
Cadmium
Chromium
.~¢*41///LJ:Ht Manganese
Selenium
_s_iTYer:)
Iron,Dissolved
Page 36 of 39
I
I
I ENVIRONMENTAL
SCIENCE CORP.
I Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109 I R~leigh, NC 27607
Meth:fltert~butyF ether
nal te
I
Quality Assurance Report
Level II
L198075
12065 Lebanon Rd.
Mt. Juliet, TN 37122
{615) 758-5858
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 16, 2005
.r::c:r:>mg/F: :::::::::070210::c ::,,:,0''(0199::,:: ::5,;·4a:,:; :::::co::::,,,,,,, ::::ios': '\\'t19.71oaco2 ''WO201492
?\r.1*tt~·trspi~e:-:::=offp1J·c:':1t::e\\ UnifS. M:Sb ·ReS ·Ref· Re·s.. ·1fPD Limit %Rec Ref Sam Batch
ENVIRONMENTAL
SCIENCE CORP.
Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Methylene chloride
Analyte
Quality Assurance Report
Level II
Ll98075
mg/1 0.0208 0.0206 1.02
?tfv1.cil:ii){_)sp_i)(e"_/DiiP.lT¢a;~:e)\ UnifS MSD ··ReS. ·Ref· ·Res·· . RPO
22
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 16, 2005
I
I
I
I
104. Ll98093-02 WG201995
Limit %Rec Ref Samp Batch I
ri\s_uty}beonzene/· i i ing/I/ }0)0198• }Oi0191 • 3}3.5/ )27\ i99)0 ){tl9.8093/02. WG201995
n-Propylbenzene mg/1 o. 0193 · ·· · o·:·0193 o. 0691 26 96. 5 ·t19909·3~02 WG2di991
Naphthalene mg/1 0.0191 0.0191 0.190 25 95.6 L198093-02 WG20199
pfisopJ'opnto1:;,en:e •··· · ·····•fo,9/r •• ···to?o106 ··t>o/ol.06) nro••io206•· 20 ····<? 92\9 •• /Ll98093/o.2 ,wG20199 sec-Butylbenzene mg/1 .. --.... h.•;···0·1Ef7 ······ o·:·cng·o · ·· ·-r~'4y·· ·:iO g·J'.-6· ·-····Li"9BD93-·b2 WG26'i'99s
!!f~!j~itt~~~~~~r····· i'Eli~ > i:~!ii 1 ~:l~!i 1 tl~il)) ii >lh; / l~ili(i~ii ~il~·~•iil
.traris<172/oichloroe.therie)••• ·····.·.· .. ·············•···•····•·it• •mg/F• ·\t•o}o231 \\\0\:02.23/I 3/~.3•• r24r•····· ·116< ,?\L190093/02 ·•wG201995
!!f g~j~ii!iiii0rEh~n7
····••·••···················••·••······•······•·····••··•··· •····••7··\Eli~. ·····••t••~·••il;•iI· +••·•·••l:·!·:li~i t<•·•ii·ii12>i!. >+••····••iili ·•·····•·······~~lili•l·~~i. ·~ii•l•I1i,
Batch number /Run number/ Sample number cross reference
WG201062, R232401 R232402, Ll98075-01 02 03 04 05 06 07 WG201058, R232418, L198075-01 02 03 04 05 06 07
WG201256, R232504, L198075-0l 02 03 04 05 06 07 WG201000, R232516, Ll98075-0l 02 03 04 06 07 WG200886, R232526, L198075-05
WG201492, R232763, Ll98075-01 02 03 WG201192, R232855, Ll98075-01 02 03 04 05 06 07
WG201562, R232893, L198075-01 02 03 04 05 06 07 WG201391, R233043, L198075-01 02 03 04 05 06 07
WG201995, R233333, L198075-04 05 06 07 08
* denotes out of limit range result. See Attachment B of standard report for list of qualifiers.
**Calculations are performed prior to rounding of reported values
Page 38 of 39
I
I
I
I
I
I
I
I
I
I
I
I
I ENVIRONMENTAL
SCIENCE CORP.
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
I Piedmont Geologic
Mr. John Harper
Tax I.D. 62-0814289
Est. 1970
6003 Chapel Hill Road Suite 109 Quality Assurance Report
Level II I Raleigh, NC 27607
L198075
May 16, 2005
I
I
I
I
I
I
I
I
I
I
I
I
I
I
ESC Level 2 Data Package
The data package includes a summary of the analytic results of the quality.
control samples required by the SW-846 or CWA methods. The quality control
samples include a method blank, a laboratory control sample, and.the matrix
spike/matrix spike duplicate analysis. If a target parameter is outside
the method limits, every sample that is effected is flagged with the
appropriate qualifier in Appendix B of the analytic report.
Method Blank -an aliquot of reagent water carried through the
entire analytic process. The method blank results indicate if
any possible contamination exposure during the sample handling,
digestion or extraction process, and analysis. Concentrations of
target analytes above the reporting limit in the method blank are
qualified with the 11 B11 qualifier.
Laboratory Control Sample is a sample of known concentration
that is carried through the digestion/extraction and analysis
process. The percent recovery, expressed as a percentage of the.
theoretical concentration, has statistical control limits
indicating that the analytic process is "in control". If a
target analyte is outside the control limits for the laboratory
control sample or any other control sample, the parameter is
flagged with a "J4 11 qualifier for all effected samples.
Matrix Spike and Matrix Spike Duplicate -is two aliquots of an
environmental sample that is spiked with known concentrations of
target analytes. The percent recovery of the target analytes
also has statistical control limits. If any recoveries that are
outside the method control limits, the sample that was selected
for matrix spike/matrix spike duplicate analysis is flagged with
either a "JS11 or a 11J6". The relative percent difference (%RPO)
between the matrix spike and the matrix spike duplicate
recoveries is all calculated. If the RPD is above the method
limit, the effected samples are flagged with a "J3" qualifier.
Page 39 of 39
-------------,;;;;: -Alternate billing information: Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh,NC 27607
Report to: Email: Mr. John Harper pjilressel@piedmontgeologic. Project
:tity/State Description: NC State University Lot #86 t:oUected ~c.J, it,"' rJC.., Client Project #: Lab Project # v . Phone: [phone]
JS-Ii A>:: [phone] PIEGEO-NC STATE UNIV -..ollected by (print): J": , -• Site/Facility ID#; P.O.#: ,;J.SJ 'I l:ollected by (signatire): !Rush? ! ( Lab MUST Be Notified ) Date Results Needed 1~ ()~ _Same Day. . .. 200% S.J...~.1./,1 ..
_Next Day .. .100%
Email? _No ~Yes _Two Day. . .50% No. Packe<l on fee N y
FA>:? ' No Yes of
Cntrs Sample ID Comp/Grab Matrix* Depth Date Time
M•·•-•O (,..r. L GW -o,/a:;1.,:, l~i'l 10 IV, J. I • '( I GW -I J'IC, 10 mw . '-I[ GW I~ 10 l'"Y\l,.J-'IJ. GW II 'i I 10 i"Ylk/' 4f;' GW 085°"> 10 mw· ~(. GW -/oJ'f 10 WI i,v-(,I) . ,, GW -. , . II 'ii 10 '-r;.."/1 ,~,--~ GW IO ' GW IO
*Matrix: S5 -Soil GW -Groundwater WW -Wastewater DW-Drinking Water OT -Other, ___ _
R,mackSi Quote#P!EGEO032405S
Rellnqu1shed
--------AnaJvsrs/l .ontamer /1-Jreservatrve Chain1Cus1 ii ti"''" :~~f ,,t.:;;f
!Ii\\,~' !~11~; \e•~ ,~,, 11f; -_ !\ft;v t!~tt· ~/~ *J:i:!I ~-ci.'\f .fiiii!i i\~i -.~. !;rn';ltr ,Pl: /'~' r• ~--~-t1Jt~ "'""'~ lf,;:.,k; ~_;, _-:{ ~-~}t\ ~WE \9:--,~ ~M!!l;t!' f ',:if¼\ ,..4~·''? {:1')' -{·, ~i;,•;j ~1 ~~ ,,~.ii'? 1£\fif t,Oi1': l)lift fr:'• i'i ~ .~ ,='~ ~52{ Zf,;d'.5f "' ~:llll " ~,fr C\ '-~.,,.? :.-"d:!i 0.. i..o:,_ ... r,j.::....} !ll "' {)'01 0 "tiu,, " K?-z~l z f':'T''i '-0.. ff'·• 1~,r ' \-~~ w l!b' 0 f?i~f §!P . ,¥ z 0.. .,,:: ijsi Cl ";: _:j ,ro•: '1l ,j<!;Jl z;,o{ ·:,::i::~ ::i:: ~-'E!' <"!V)'f, 0.. ~:'.'"""',r s ia,'N~ @ I,. Si ~.'o! t'Tflc;t }3!~ 0 ~•.Yti V) ~.:2& s N !!tu·':: ~~t1 I C tf;i§j'., 0
Jo;:} 0 0 -·•,:,;..c:{
V) '-t/ilI ·11;::Et· ~
~-~:"f! 0 -0 . ;},';!..
" .... 1vr. kat :s ,. ~§~ i;F ~-0 .~e::::>~. -;:; ;r.:_2r-,.~;~~ "' &izg; -"' "RLc:::,t "' ~-cxN ~ ;i;_C!:)fl i5 ~.;:::,• ~t··:t( i;.),~i! ~L\:,.
i.'.~'• X i~"i X x·" ;•. 'Ii
-~~~r~ X t,X:,'! X :t}XJ1
' '1 '!)(;,' !-.,,.11 X IX1!! X ·x·· t.,~ tXt';;~
i-.. 1~ .<i• X i~f.i. X },,Xit,, , ..... ,,., tx-~ X }Xiii X t·Xtli
f1~:i X ,t_X:13 X p,~f
!·~1~ X .1x::1; -~--"~ X f.:x~t ,. , __ ,f1 i,X::fill X ~X"~fj X tx~ :.;x1.~ "·'··""' X :~Xf X fi,x,~
[~•?:, Page of -.1~ 'Jr_i _ _k "".~-l.
&~tli ~t .... ,. .;:r~\I Prepared by: r~~ • ENVIRONMENTAL 'Ut 1~'r ;:,;,~ ~,.., ;jlH~_t_d :,\~~ SCIENCE CORP.
12065 Lebanon Road ,g\v,~f;
i'(l~ Mt. Juliet. TN 37122
st M' ,-.: -y
Phone [phone] ;f_{:;)J:
Vi .,,..,....,. f-~ [phone] N ;jg{~-~ FAX ::i:: 0 ' -~,pf w B./-t.).J ::i:: 0.. i,~cn11: ' Cl 1¥'1 -il; ..0 tM~~( ;,;w1~-r.,,: ;,.::.'\·.~ o1~-. ... 'l"~'t---~, . ..,; "'-'-~·J ~!~;,•,r:1,.·'lc. -t•"l•'.;Y'."':!~ ·,:(lati.us6 ·only)1,, .l =5 \i~~~' ~ J'.Acctnu PIEGE0i14Jo' ~~f.:'\Vt'!1~•kA:_,.?r; s iit'~·~ 1-'· ~ ';'£..: . .-;::~~i':''·;~r],,.,.._ \ '!:-=-' "..! .... s \-1,
In 504'71•~,~~6 V) {%Et. N 0 :• -ion st t ·"' OS;: ;i~i~ J-<-" 0 ~:shipped Via :-.:::: Fe -~·~. 1, riiund~C'•JA, "' J{:!;)_; M ./:: N ~.,,,.:t =' c~.«n:_ ~hf.,,. '" . .. -'2::0:~ so z ~~ili1~ > Remarks/Contaminant Sample # (lab only)
X 1x::: X :-v);_--· .•"'-',c;:J:
X 1N:-_1l X ,\;,; '·-.. ,B .,., ·:,r~-:
X !'}~~ X ;. •,~ ,~ "-"i:;9;'
X f~}] X I -·t :: '
X :i~s!f X 8,:", • ,,,...;,
•., X ~~~~ X ~ I:2:W...;;
X :'X_,\1 X ,·is \::"'.., t,...,_,.,··, ( Ji,,
X ~x~ X ,,~, ,?'f:)'~ J;,
X ::~X<~; X ~;
pH ______ _ Temp
Other Flow ______ _
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
• ENVIRONMENTAL SCIENC1-
Cooler Receipt Form
Cooler Received On: 6/c,,,k_,t;: and Opened On: ~ By:
l. Temperature of cooler when opened: ·?. 21"" Degrees Celsius
2. Were custody seals on outside of cooler and intact? -/\14 YES NO
a. If yes, what kind and where: ------------~----
b. Were the signature and date correct?
3. Were custody seals on containers intact? ---1{4
4. Were custody papers inside cooler?
5. Were custody papers properly filled out (ink, signed, etc.)
6. Did you sign the custody papers in the appropriate place?
7. What kind of packing material was used? @ubhlewr;;)
8. Was sufficient ice used (if appropriate)?
9. . Did all bottles arrive in good condition?
l 0. Were all bottle labels complete? (#, date, signed, pres, etc)?
l l. Did all bottle labels and tags agree with custody papers?
12. Were correct bottles used for the analyses requested?
13. If applicable, was an observable VOA headspace present?
14. Was sufficient amount of sample sent in each bottle?
15. Were correct preservatives used?
16.-Corrective action taken, if necessary:
YES
YES
·(@
Q
~
Peanuts Other
l1G
6is:,
~
§
@
YES
as,·
~
a. Name of person contacted: See attached for resolution if needed
b. Date: _______ _
NO
NO
NO
NO
NO
None
NO
NO
NO
NO
NO
6
NO
NO
\
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
-12065 Lebanon Rd.
Mt. Juliet, TN 37122
ENVIRONMENTAL [phone]
1-800-767-5859
SCIENCE CORP. Fax [phone]
Tax I .D. 62-0814289
Est. 1970
REPORT OF ANALYSIS
Mr. John Harper May 17,2005
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
ESC Sample # L198282-01
Date Received May 07, 2005
Description NC State University Lot #86
Site ID
Sample ID MW-13
Project # 2519
Collected By J Ganey
Collection Date 05/06/05 08,49
Parameter Result Det. Limit Units Method Date Dil.
Methane BDL 1000 ppb 8015M 05/09/05 1
Chloride 9700 1000 ug/1 9056 05/07/05 1
Nitrate 22000 1000 ug/1 .9056 05/07/05 10
Sulfate BDL 5000 ug/1 9056 05/07/05 1
Alkalinity 360000 100000 ug/1 310.2 05/11/05 10
Ethane BDL 1000 ppb 8015M 05/09/05 1
Ethene BDL 1000 ppb 8015M 05/09/05 1
TOC (Total Organic Carbon) BDL 1000 ug/1 9060 05/12/05 1
Mercury BDL 0.20 ug/1 7470A 05/13/05 1
Arsenic 51. 20. ug/1 6010B 05/08/05 1
Barium 1400 5.0 ug/1 6010B 05/08/05 1
Cadmium BDL 5.0 ug/1 60108 05/08/05 1
Chromium BDL 10. ug/1 6010B 05/08/05 1 Iron,Dissolved BDL 100 ug/1 6010B 05/09/05 1
Lead 5.2 5.0 ug/1 6010B 05/08/05 1
Manganese 2500 10. ug/1 6010B 05/08/05 1
Selenium BDL 20. ug/1 6010B 05/08/05 1
Silver BDL 10. ug/1 6010B 05/08/05 1
Volatile Organics
Benzene BDL 1.0 ug/1 6230D 05/14/05 1
Bromobenzene BDL 1. 0 ug/1 6230D 05/14/05 1 Bromochloromethane BDL 1.0 ug/1 6230D 05/14/05 1 Bromodichloromethane BDL 1.0 ug/1 6230D 05/14/05 1
Bromoform BDL 1.0 ug/1 6230D 05/14/05 1 Bromomethane BDL 1.0 ug/1 6230D 05/14/05 1
n-Butylbenzene BDL 1. 0 ug/1 6230D 05/14/05 1
sec-Butylbenzene BDL 1.0 ug/1 6230D 05/14/05 1 tert-Butylbenzene BDL 1.0 ug/1 6230D 05/14/05 1
Carbon Tetrachloride BDL 1.0 ug/1 6230D 05/14/05 1
Chlorobenzene BDL 1.0 ug/1 6230D 05/14/05 1
BDL -Below Detection Limit
Det. Limit -Estimated Quantitation Limit(EQL)
Laboratory Certification Numbers:
C-TN-01 AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
00109, WV -233
Page 1 of 31
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 07, 2005
Description NC State University
Sample ID MW-13
Collected By J Ganey Collection Date 05/06/05 08,49
Parameter
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-Chloropropane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
Di-isopropyl ether
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
p-Isopropyltoluene
Methylene chloride
Methyl tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,l,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #86
Result Det. Limit
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 5.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 5.0
BDL 5.0
BDL 5.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
Det. Limit -Estimated Quantitation Limit(EQL)
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
l-800-767-5859
Fax [phone]
Tax I .D. 62-0814289
Est. 1970
May 17,2005
ESC Sample#
Site ID
Project#
Units Method
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 62300
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
Ll98282-01
2519
Date
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
Laboratory Certification Numbers:
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Page 2 of 31
C-TN-01
00109, WV
I
I
I
I
I
I
Oil.
l I 1
l
l
1 I 1
l
1
l
ii
1
l ~· 1
l
ii
l
ti l
1
ti
1
1
~I
1
1 I
231
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 07, 2005
Description NC State University
Sample ID MW-13
Collected By J Ganey
Collection Date 05/06/05 08 ,49
REPORT OF ANALYSIS
Lot #86
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 17,2005
ESC Sample#
Site ID
Project#
Ll98282-0l
2519 .
Parameter Result Det. Limit Units Method Date Dil.
Trichlorofluoromethane BDL 1.0 ug/1 6230D
1,2,3-Trichloropropane BDL 1.0 ug/1 6230D
1,2,4-Trimethylbenzene BDL 1.0 ug/1 6230D
1,3,5-Trimethylbenzene BDL 1.0 ug/1 6230D
Toluene BDL 5.0 ug/1 6230D
Vinyl chloride BDL 1.0 ug/1 6230D Xylenes, Total BDL 3.0 ug/1 6230D
BDL -Below Detection Limit
Det. ·Limit -Estimated Quantitation Limit(EQL)
Laboratory Certification Numbers:
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Note:
The reported analytical results relate only to the sample submitted.
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
C-TN-01
1
1
1
1
1
1
1
00109, WV -233
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported: 05/17/05 18:12 Printed: 05/17/05 18:13 I Page 3 of 31
I
ENVIRONMENTAL
SCIENCE CORP.
REPORT OF ANALYSIS
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
May 07, 2005 Date Received
Description NC State University Lot #86
Sample ID
Collected By
Collection Date
Parameter
Methane
Chloride
Nitrate
Sulfate
Alkalinity
Ethane
Ethene
MW-29
J Ganey
05/06/05 09,46
TOC (Total Organic Carbon)
Mercury
Arsenic
Barium
Cadmium
Chromium
Iron,Dissolved
Lead
Manganese
Selenium
Silver
Volatile Organics
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromornethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon Tetrachloride
Chlorobenzene
BDL -Below Detection Limit
Result
BDL
2300
390
BDL
52000
BDL
BDL
BDL
BDL
BDL
15.
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
Det. Limit -Estimated Quantitation Limit(EQL)
Det. Limit
1000
1000
100
5000
10000
1000
1000
1000
0 .20
20.
5.0
5.0
10.
100
5.0
10.
20.
10.
1.0
1.0
1.0
1. 0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
12065 Lebanon Rd.
Mt. Juliet, TN 37122
{615) 758-5858
l-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 17, 2005
ESC Sample # Ll98282-02
Site ID
Project # 2519
Units Method Date
ppb 8015M 05/09/05
ug/1 9056 05/07/05
ug/1 9056 05/07/05
ug/1 9056 05/07/05
ug/1 310.2 05/12/05
ppb 8015M 05/09/05
ppb 8015M 05/09/05
ug/1 9060 05/12/05
ug/1 7470A 05/13/05
ug/1 6010B 05/08/05
ug/1 6010B 05/08/05
ug/1 6010B 05/08/05
ug/1 6010B 05/08/05
ug/1 6010B 05/09/05
ug/1 6010B 05/08/05
ug/1 6010B 05/08/05
ug/1 6010B 05/08/05
ug/1 60108 05/08/05
ug/1 6230D 05/16/05
ug/1 6230D 05/16/05
ug/1 6230D 05/16/05
ug/1 6230D 05/16/05
ug/1 6230D 05/16/05
ug/1 6230D 05/16/05
ug/1 6230D 05/16/05
ug/1 6230D 05/16/05
ug/1 6230D 05/16/05
ug/1 6230D 05/16/05
ug/1 6230D 05/16/05
Laboratory Certification Numbers:
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN -C-TN-01
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA -00109, WV
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Page 4 of 31
I
I
I
I
I
I
Dil.
1 I 1
1
1 I 1
1
1 I
1
:1
1 ~. 1
1 ii
1 ~.
l
1 ~· 1
1 I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 07, 2005
Description NC State University
Sample ID MW-29
Collected By J Ganey
Collection Date 05/06/05 09:46
Parameter
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
l,2-Dibromo-3-Chloropropane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
Di-isopropyl ether
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
p-Isopropyltoluene
Methylene chloride
Methyl tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #86
Result Det. Limit
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1. 0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 5.0
BDL 1. 0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 5.0
BDL 5.0
BDL 5.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
Det. Limit -Estimated Quantitation Limit{EQL)
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 17,2005
ESC Sample#
Site ID
Project#
Units Method
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
Ll98282-02
2519
Date
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
Laboratory Certification Numbers:
C-TN-01
Dil.
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
00109, WV -233
Page 5 of 31
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
·Raleigh, NC 27607
Date Received May 07, 2005
Description NC State University
Sample ID MW-29
Collected By J Ganey
Collection Date 05/06/05 09,46
Parameter
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Toluene
REPORT OF ANALYSIS
Lot #86
Result Det. Limit Units
BDL 1.0 ug/1
BDL 1.0 ug/1
BDL 1.0 ug/1
BDL 1.0 ug/1
BDL 5.0 ug/1
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I .D. 62-0814289
Est. 1970
May 17,2005
ESC Sample#
Site ID
Project#
Method
6230D
6230D
6230D
6230D
6230D
Ll98282-02
2519
Date
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05 Vinyl chloride BDL 1.0 ug/1 6230D 05/16/05
Xylenes, Total BDL 3.0 ug/1 6230D 05/16/05
BDL -Below Detection Limit
Det. Limit -Estimated Quantitation Limit(EQL)
Laboratory Certification Numbers:
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN C-TN-01
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA -00109, WV
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Note:
The reported analytical results relate only to the sample submitted.
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported: 05/17/05 18:12 Printed: 05/17/05 18:13
Page 6 of 31
I
I
I
I
I
I
Oil.
1 I 1
1
1
1 I 1
1
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
ENVIRONMENTAL
SCIENCE CORP.
REPORT OF ANALYSIS
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
May 07, 2005 Date Received
Description NC State University Lot #86
Sample ID
Collected By
Collection Date
Parameter
Methane
Chloride
Nitrate
Sulfate
Alkalinity
Ethane
Ethene
MW-33
J Ganey
05/06/05 13,16
TOC (Total Organic Carbon)
Mercury
Arsenic
Barium
Cadmium
Chromium
Iron,Dissolved
Lead
Manganese
Selenium
Silver
Volatile Organics
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon Tetrachloride
Chlorobenzene
BDL -Below Detection Limit
Result
BDL
1700
BDL
BDL
29000
BDL
BDL
BDL
BDL
BDL
7.4
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
Det. Limit -Estimated Quantitation Limit(EQL)
Det. Limit
1000
1000
100
5000
10000
1000
1000
1000
0.20
20.
5.0
5.0
10.
100
5.0
10.
20.
10.
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 17,2005
ESC Sample # Ll98282-03
Site ID
Project # 2519
Units Method Date
ppb 8015M 05/09/05
ug/1 9056 05/07/05
ug/1 9056 05/07/05
ug/1 9056 05/07/05
ug/1 310.2 05/12/05
ppb 8015M 05/09/05
ppb 8015M 05/09/05
ug/1 9060 05/12/05
ug/1 7470A 05/13/05
ug/1 6010B 05/08/05
ug/1 6010B 05/08/05
ug/1 6010B 05/08/05
ug/1 6010B 05/08/05
ug/1 6010B 05/09/05
ug/1 6010B 05/08/05
ug/1 6010B 05/08/05
ug/1 6010B 05/08/05
ug/1 6010B 05/08/05
ug/1 6230D 05/14/05
ug/1 6230D 05/14/05
ug/1 6230D 05/14/05
ug/1 6230D 05/14/05
ug/1 6230D 05/14/05
ug/1 6230D 05/14/05
ug/1 6230D 05/14/05
ug/1 6230D 05/14/05
ug/1 6230D 05/14/05
ug/1 6230D 05/14/05
ug/1 6230D 05/14/05
Laboratory Certification Numbers:
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN C-TN-01
Dil.
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA 00109, WV -233
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Page 7 of 31
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 07, 2005
Description NC State University
Sample ID MW-33
Collected By J Ganey
Collection Date 05/06/05 13,16
Parameter
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
l,2-Dibromo-3-Chloropropane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
Di-isopropyl ether
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
p-Isopropyltoluene
Methylene chloride
Methyl tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #86
Result Det. Limit
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 5.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 5.0
BDL 5.0
BDL 5.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
Det. Limit -Estimated Quantitation Limit{EQL)
Units
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
Laboratory Certification Numbers:
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 17,2005
ESC Sample# Ll98282-03
Site ID
Project# 2519
Method
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
62300
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D ·
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
Date
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
AIIIA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN C-TN-01
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA 00109, WV
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Page 8 of 31
I
I
I
I
I
I
Dil.
1 I 1
1
1
1 I 1
1
1
1
ti
1
1
1 I 1
1
1
ti 1
1
~I 1
1
ti
1
1
ii
1
1 I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 07, 2005
Description NC State University
Sample ID MW-33
Collected By J Ganey
Collection Date 05/06/05 13,16
REPORT OF ANALYSIS
Lot #86
12065 Lebanon Rd.
Mt. Juliet, TN 37122
(615} 758-5858
l-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Eat. 1970
May 17,2005
ESC Sample# Ll98282-03
Site ID
Project# 2519
Parameter Result Det. Limit Units Method Date Dil.
Trichlorofluoromethane BDL 1.0 ug/1 6230D 1,2,3-Trichloropropane BDL 1.0 ug/1 6230D 1,2,4-Trimethylbenzene BDL 1.0 ug/1 6230D 1,3,5-Trimethylbenzene BDL 1.0 ug/1 6230D Toluene BDL 5.0 ug/1 6230D Vinyl chloride BDL 1.0 ug/1 6230D Xylenes, Total BDL 3.0 ug/1 6230D
BDL -Below Detection Limit
Det. Limit -Estimated Quantitation Limit(EQL)
Laboratory Certification Numbers:
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910 Note:
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
C-TN-01
1
1
1
1
1
1
1
00109, WV -233
The reported analytical results relate only to the sample submitted.
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported: 05/17/05 18:12 Printed: 05/17/05 18:13 I Page 9 of 31
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 07, 2005
Description NC State University
Sample ID MW-35S
Collected By J Ganey
Collection Date 05/06/05 10,29
Parameter
Methane
Chloride
Nitrate
Sulfate
Alkalinity
Ethane
Ethene
TOC (Total Organic Carbon)
Mercury
Arsenic
Barium
Cadmium
Chromium
Iron,Dissolved
Lead
Manganese
Selenium
Silver
Volatile Organics
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon Tetrachloride
Chlorobenzene
BDL -Below Detection Liffiit
REPORT OF ANALYSIS
Lot #86
Result Det. Limit
BDL 1000
2200 1000
590 100
BDL 5000
28000 10000
BDL 1000
BDL 1000
BDL 1000
BDL 0.20
BDL 20.
30. 5.0
BDL 5.0
19. 10.
BDL 100
BDL 5.0
12. 10.
BDL 20.
BDL 10.
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
Det. Limit -Estimated Quantitation Limit{EQL)
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax {615) 758-5859
Tax I.D. 62-0814289
Est. 1970
May 17,2005
ESC Sample#
Site ID
Project#
Units Method
ppb 8015M
ug/1 9056
ug/1 9056
ug/1 9056
ug/1 310.2
ppb 8015M
ppb 8015M
ug/1 9060
ug/1 7470A
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
Ll98282-04
2519
Date
05/09/05
05/07/05
05/07/05
05/07/05
05/12/05
05/09/05
05/09/05
05/12/05
05/13/05
05/08/05
05/08/05
05/08/05
05/08/05
05/09/05
05/08/05
.05/08/05
05/08/05
05/08/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
Laboratory Certification Numbers:
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Page 10 of 31
C-TN-01
00109, WV
I
I
I
I
I
I
Oil.
1 I 1
1
1 I 1
1
1 I
1
1 I 1
1
1
1 I 1
1
1
1 I 1
1
1 I 1
1
1
1
1 I 1
1
1
1 I
2331
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 07, 2005
Description NC State University
Sample ID MW-35S
Collected By J Ganey
Collection Date 05/06/05 10,29
Parameter
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-Chloropropane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
Di-isopropyl ether
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
p-Isopropyltoluene
Methylene chloride
Methyl tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #86
Result Det. Limit
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1. 0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1. 0
BDL 1.0
BDL 1.0
BDL 5.0
BDL 1.0
BDL 1.0
BDL 1. 0
BDL 1.0
BDL 5.0
BDL 5.0
BDL 5.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1. 0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1. 0
Det. Limit -Estimated Quantitation Limit(EQL)
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 17,2005
ESC Sample#
Site ID
Project#
Units Method
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
Ll98282-04
2519
Date
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
Laboratory Certification Numbers:
C-TN-01
Dil.
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -· 81002, WI -998093910 00109, WV -233
Page 11 of 31
ENVIRONMENTAL
SCIENCE CORP.
REPORT OF ANALYSIS Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 07, 2005
Description NC State University Lot #86
Sample ID MW-35S
Collected By J Ganey
Collection Date 05/06/05 10,29
Parameter Result
Trichlorofluoromethane BDL
1,2,3-Trichloropropane BDL 1,2,4-Trimethylbenzene BDL
1,3,5-Trimethylbenzene BDL
Toluene BDL Vinyl chloride BDL Xylenes, Total BDL
BDL -Below Detection Limit
Det. Limit -Estimated Quantitation Limit(EQL)
Det. Limit
1.0
1.0
1.0
1.0
5.0
1.0
3.0
Units
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
Laboratory Certification Numbers:
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 17,2005
ESC Sarrple # L198282-04
Site ID
Project# 2519
Method
6230D
6230D
6230D
6230D
6230D
6230D
6230D
Date
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN C-TN-01
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA -00109, WV
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Note:
The reported analytical results relate only to the sample submitted.
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported: 05/17/05 18:12 Printed: 05/17/05 18:13
Page 12 of 31
I
I
I
I
I
I
Dil.
1 I 1
1
1
1 I 1
1
I
I
I
I
I
I
I
2331
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
,I
!
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 07, 2005
Description NC State University
Sample ID MW-62
Collected By J Ganey
Collection Date 05/06/05 10,29
Parameter
Methane
Chloride
Nitrate
Sulfate
Alkalinity
Ethane
Ethene
TOC (Total Organic Carbon)
Mercury
Arsenic
Barium
Cadmium
Chromium
Iron,Dissolved
Lead
Manganese
Selenium
Silver
Volatile Organics
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon Tetrachloride
Chlorobenzene
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #86
Result Det. Limit
BDL 1000
BDL 1000
BDL 100
BDL 5000
120000 10000
BDL 1000
8DL 1000
8DL 1000
8DL 0.20
8DL 20.
11. 5.0
8DL 5.0
8DL 10.
8DL 100
8DL 5.0
8DL 10.
BDL 20.
BDL 10.
BDL 1.0
8DL 1.0
BDL 1.0
8DL 1.0
8DL 1.0
BDL 1.0
8DL 1.0
8DL 1.0
8DL 1.0
8DL 1.0
BDL 1.0
Det. Limit -Estimated Quantitation Limit(EQL)
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 17,2005
ESC Sample#
Site ID
Project#
Units Method
ppb 8015M
ug/1 9056
ug/1 9056
ug/1 9056
ug/1 310.2
ppb 8015M
ppb 8015M
ug/1 9060
ug/1 7470A
ug/1 6010B
ug/1 60108
ug/1 60108
ug/1 60108
ug/1 60108
ug/1 60108
ug/1 60108
ug/1 6010B
ug/1 6010B
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
L198282-05
2519
Date
05/09/05
05/07/05
05/07/05
05/07/05
05/12/05
05/09/05
05/09/05
05/12/05
05/13/05
05/08/05
05/08/05
05/08/05
05/08/05
05/09/05
05/08/05
05/08/05
05/08/05
05/08/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
Labora~ory Certification Numbers:
C-TN-01
Dil.
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
00109, WV -233
Page 13 of 31
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 07, 2005
Description NC State University
Sample ID MW-62
Collected By J Ganey
Collection Date 05/06/05 10,29
REPORT OF ANALYSIS
Lot #86
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 17,2005
ESC Sample #
Site ID
Project#
L198282-05
2519
I
I
I
I
I
I
Parameter Result Det. Limit Units Method Date Oil.
Chlorodibromomethane BDL 1.0 ug/1 6230D Chloroethane BDL 1.0 ug/1 6230D Chloroform BDL 1.0 ug/1 6230D
Chloromethane BDL 1.0 ug/1 .6230D 2-Chlorotoluene BDL 1.0 ug/1 6230D
4-Chlorotoluene BDL 1.0 ug/1 6230D 1,2-Dibromo-3-Chloropropane BDL 1.0 ug/1 6230D 1,2-Dichlorobenzene BDL 1.0 ug/1 6230D 1,3-Dichlorobenzene BDL 1.0 ug/1 6230D
1,4-Dichlorobenzene BDL 1.0 ug/1 6230D Dichlorodifluoromethane BDL 1.0 ug/1 6230D 1,1-Dichloroethane BDL 1.0 ug/1 6230D 1,2-Dichloroethane BDL 1. 0 ug/1 6230D
1,1-Dichloroethene BDL 1. 0 ug/1 6230D cis-1,2-Dichloroethene BDL 1.0 ug/1 6230D
trans-1,2-Dichloroethene BDL 1.0 ug/1 6230D
1,2-Dichloropropane BDL 1.0 ug/1 6230D 1,3-Dichloropropane BDL 1.0 ug/1 6230D
2,2-Dichloropropane BDL 1.0 ug/1 6230D 1,1-Dichloropropene BDL 1.0 ug/1 6230D Di-isopropyl ether BDL 5.0 ug/1 6230D Ethylbenzene BDL 1.0 ug/1 6230D Hexachlorobutadiene BDL 1.0 ug/1 6230D
Isopropylbenzene BDL 1.0 ug/1 62300 p-Isopropyltoluene BDL 1.0 ug/1 62300
Methylene chloride BDL 5.0 ug/1 62300
Methyl tert-butyl ether BDL 5.0 ug/1 6230D
Naphthalene BDL 5.0 ug/1 6230D n-Propylbenzene BDL 1.0 ug/1 6230D Styrene BDL 1.0 ug/1 6230D 1,1,1,2-Tetrachloroethane BDL 1.0 ug/1 6230D 1,1,2,2-Tetrachloroethane BDL 1.0 ug/1 6230D
Tetrachloroethene BDL 1.0 ug/1 6230D
1,2,3-Trichlorobenzene BDL 1.0 ug/1 6230D
1,2,4-Trichlorobenzene BDL 1. 0 ug/1 6230D
1,1,1-Trichloroethane BDL 1.0 ug/1 6230D
1,1,2-Trichloroethane BDL 1.0 ug/1 6230D
Trichloroethene BDL 1.0 ug/1 6230D
BDL -Below Detection Limit
Det. Limit -Estimated Quantitation Limit(EQL)
Laboratory Certification Numbers:
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Page 14 of 31
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05;1·4/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
C-TN-01
00109, WV -
1 I 1
1
1 ~.
1
1 ~· 1
1 ~· 1 ~. 1
1 ~.
1
1 ~· 1
1 ~· 1
1 I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 07, 2005
Description NC State University
Sample ID MW-62
Collected By J Ganey
Collection Date 05/06/05 10,29
REPORT OF ANALYSIS
Lot #86
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 17,2005
ESC Sample# Ll98282-05
Site ID
Project# 2519
Parameter Result Det. Limit Units Method Date Dil.
Trichlorofluoromethane BDL 1. 0 ug/1 6230D
1,2,3-Trichloropropane BDL 1.0 ug/1 6230D 1,2,4-Trimethylbenzene BDL 1.0 ug/1 6230D
1,3,5-Tri~ethylbenzene BDL 1.0 ug/1 6230D Toluene BDL 5.0 ug/1 6230D Vinyl chloride BDL 1.0 ug/1 6230D
Xylenes, Total BDL 3.0 ug/1 6230D
BDL -Below Detection Limit
Det. Limit -Estimated Quantitation Limit(EQL)
Laboratory Certification Numbers:
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910 Note:
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
C-TN-01
1
1
l
1
1
1
1
00109, WV -233
The reported analytical results relate only to the sample submitted.
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported: 05/17/05 18:12 Printed: 05/17/05 18:13
Page 15 of 31
ENVIRONMENTAL
SCIENCE CORP.
REPORT OF ANALYSIS
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
May 07, 2005 Date Received
Description NC State University Lot #86
Sample ID
Collected By
Collection Date
Parameter
Volatile Organics
Benzene
Bromobenzene
TRIPBLANK
J Ganey
05/06/05 00,00
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon Tetrachloride
Chlorobenzene
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-Chloropropane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-0ichloroethane
1,1-0ichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-0ichloropropane
1,3-Dichloropropane
2,2-0ichloropropane
1,1-Dichloropropene
Di-isopropyl ether
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
p-Isopropyltoluene
Methylene chloride
BDL -Below Detection Limit
Result
BDL
BDL
BDL
BOL
BOL
BDL
BDL
BDL
BOL
BOL
BOL
BDL
BOL
BDL
BDL
BOL
BOL
BOL
BOL
BOL
BOL
BDL
BOL
BOL
BDL
BOL
BOL
BOL
BDL
BOL
BOL
BOL
BOL
BOL
BOL
BOL
BDL
Det. Limit -Estimated Quantitation Limit(EQL)
Det. Limit
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1. 0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1. 0
5.0
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
l-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 17, 2005
ESC Sample# Ll98282-07
Site ID
Project# 2519
Units
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
Method
6230D
6230D
62300
6230D
6230D
6230D
6230D
62300
62300
62300
62300
62300
62300
62300
6230D
62300
62300
62300
6230D
62300
6230D
62300
62300
62300
62300
62300
62300
62300
62300
62300
62300
62300
62300
6230D
62300
62300
6230D
Date
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
Laboratory Certification Numbers:
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Page 16 of 31
C-TN-01
00109, WV
I
I
I
I
I
I
Oil.
1 I 1
1
1 I 1
1
1
1
1 I 1
1
1
1
ii
1
ii 1
1
ii 1
1
ii
1
1
ii
1
1 I
231
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
ENVIRONMENTAL
SCIENCE CORP.
REPORT OF ANALYSIS
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
May 07, 2005 Date Received
Description NC State University Lot #86
Sample ID
Collected By
Collection Date
Parameter
Methyl tert-butyl
Naphthalene
n-Propylbenzene
Styrene
TRIPBLANK
J Ganey
05/06/05 00,00
ether
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,l-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Toluene
Vinyl chloride
Xylenes, Total
BDL -Below Detection Limit
Result
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
Det. Limit -Estimated Quantitation Limit(EQL)
Det. Limit
5.0
5.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
3.0
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 17, 2005
ESC Sample#
Site ID
Project#
Units Method
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
L198282-07
2519
Date
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
05/14/05
Laboratory Certification Numbers:
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN -C-TN-01
Oil.
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA -00109, WV -233
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Note:
The reported analytical results relate only to the sample submitted.
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported: 05/17/05 18:12 Printed: 05/17/05 18:13
Page 17 of 31
Sample#
Ll98282-01
Ll98282-03
Ll98282-04
Ll98282-0S
Ll98282-07
Attachment A
List of Analytes with QC Qualifiers
Analyte
Carbon Tetrachloride
Chloroethane
Chloroform
Chloromethane
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
cis-1,2-Dichloroethene
2,2-Dichloropropane
1,1-Dichloropropene
Di-isopropyl ether
1,1,1-Trichloroethane
Trichlorofluoromethane
Vinyl chloride
Alkalinity
Chloroethane
Chloromethane
Dichlorodifluoromethane
Trichlorofluoromethane
Vinyl chloride
Alkalinity
Chloroethane
Chloromethane
Dichlorodifluoromethane
Trichlorofluoromethane
Vinyl chloride
Chloroethane
Chloromethane
Dichlorodifluoromethane
Trichlorofluoromethane
Vinyl chloride
Chloroethane
Chloromethane
Dichlorodifluoromethane
Trichlorofluoromethane
Vinyl chloride
Qualifier
JS
J4JS
JS
J4JS
J4JS
JS
JS
JS
JS
JS
JS
JS
J4JS
J4JS
J6
J4
J4
J4
J4
J4
J3
J4
J4
J4
J4
J4
J4
J4
J4
J4
J4
J4
J4
J4
J4
J4
Page 18 of 31
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Qualifier
J3
J4
JS
JG
Attachment B
Explanation of QC Qualifier Codes
Meaning
The associated batch QC was outside the established quality control range
for precision.
The associated batch QC was outside the established quality control range
for accuracy.
The sample matrix interfered with the ability to make any accurate
determination; spike value is high
The sample matrix interfered with the ability to make any accurate
determination; spike value is low
Qualifier Report Information
ESC utilizes sample and result qualifiers as set forth by the EPA Contract Laboratory Program and
as required by ITKJst certifying bodies including NELAC. In addition to the EPA qualifiers adopted
by ESC, we have implemented ESC qualifiers to provide more information pertaining to our analytical
results. Each qualifier is designated in the qualifier explanation as either EPA or ESC.
Data qualifiers are intended to provide the ESC client with more detailed information concerning
the potential bias of reported data. Because of the wide range of constituents and variety of
matrices incorporated by most EPA methods,it is common for some compounds to fall outside of
established ranges. These exceptions are evaluated and all reported data is valid and useable
unless qualified as 'R' (Rejected).
Definitions
Accuracy -The relationship of the observed value of a known sample to the
true value of a known sample. Represented by percent recovery and
relevant to samples such as: control samples, matrix spike recoveries,
surrogate recoveries, etc.
Precision The agreement between a set of samples or between duplicate samples.
Surrogate -
Relates to how close together the results are and is represented by
Relative Percent Differrence.
Organic compounds that are similar in chemical composition, extraction,
and chromotography to analytes of interest. The surrogates are used to
determine the probable response of the group of analytes that are chem-
ically related to the surrogate compound. Surrogates are added to the
sample and carried through all stages of preparation and analyses.
Control Limits (AQ)
2-Fluorophenol
Phenol-as
2,4,6-Tribromophenol
31-119
12-134
51-141
Nitrobenzene-dS 43-118 Dibromfluoromethane 70-130
2-Fluorobiphenyl 45-128 Toluene-dB 70-130
Terphenyl-dl4 43-137 4-Bromofluorobenzene 70-130
TIC Tentatively Identified Compound: Compounds detected in samples that are
not target compounds, internal standards, system monitoring compounds,
or surrogates.
(SS)
70-130
70-130
70-130
Page 19 of 31
ENVIRONMENTAL
SCIENCE CORP.
Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Anal te
Chloride < : ,,,, ...
Nitrate .... ·
Sulfate 1ff1~::Ar~'/t:r·-... -
Barium .cadtniUID\:':::::::=::,,,=,=-==-..... -·
ChrOm'i uTit
Lead
~-~fi9~~~:~:~)(::·:·:•:••''
Selenium
Silver
1i'1ti1~::;::Bi:;:~~ttl!Jtt=\::::':':::::•:':·
Quality Assurance Report
Level II
L198282
/!)J./~P.9.t¥.t:9tY.\13,~'a'iik\:· Result Units "ifate Anal zed
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 17, 2005
Batch
'':'}05/07/05 l5.i5.3/ :::•:c:;:::c:wG20l074:/::c:···
· o5/o'IN5 15,53 wi:;201014·
05/07/05 15,53 WG201074
<
<
1
<
1,1,1,2-Tetrachloroethane < .001 mg/1 05/14/05 18,27 WG202168
l}l;:l',Trichloroethane'. ::···· . •\ .~),001:i ······ ·: mg/T· :(05/14/.05 '18:27 ,,, 'WG202168':••••·····
1,1,2,2-Tetrachloroethane < .001 mg/1 05/14/05 18,27 WG202168.
1,1,2-Trichloroethane < .001 mg/1 05/14/05 18:27 WG202168
T:''J."Dichlciroethariet : ••:: -::-\:}\:?\:'\\,:i:::'\\:'/'':::t<: :-001::: fmg/1/ •:)\o5/14/o51a·,21 }.:':. wc::;20.:qG.a/
1:T~bichl6roet:herie··· < . 001 mg/1 05/14/05 Ia, ;h WG202168
I
I
I
I
lf2/3C.TrichloroberiZene ....... '\i• :001::::: ··· .. ·. /'·•'mg/1? 0:\05/14/05:': 18:,:21: ::o: :wG20216.8( ···.·••·.·.•··. ,,,,,,,.,,,.,/ 1, 1-Dichloropropene < • 001 mg/1 05/14/05 18, 27 WG202168 I
1, 2, 3:..Trichloi-opropane < . 001 mg/1 ·· .. os/i4)os 18: 27 WG202168
1,2,4-Trichlorobenzene < .001 mg/1 05/14/05 18:27 WG202168 i;}:tt~::i%:;:1~2~igi:;gt;;~~~:t ::• i '§§II <m§'ii tg.~1/u'igr rn\j} x·· ug;g~f~·f " :: "
t+~:gtg~ti{~~rn;J;~f· ·•··· \ {;ggi I .fu§ji) ?g~;i:{g~.:••i~l~; •.•. }ug~g~i~~} •.•• rl
l,2~Dichloropropane < .001 mg/1 05/14/05 18,27 WG202168
1,3,5-Trimethylbenzene < .001 mg/1 05/14/05 18:27 WG202168 l/i:JSPi'.¢tj.l"tj~,99¢.6Z:~t¢./)/::·· . ::·<: _:_-;··.o_o 1\/::· . '''}l/ffig/1}\" :'=\/0? 11·::v,o 5 =-.ra:::2 7.''" ,, .. )'WG2021"6 a,:
1, 3-Dichloropropane < · .601·· mg/1 · · 05/14/05 ·1a::i.f wd:fo2i6a
1,4-Dichlorobenzene < .001 mg/1 05/14/05 18,27 WG202168 ·~:~;;~~~g~~t~~~~parie): .·.·. ··. !niggi t { %§Ji:< ::::g~;i:}g~ tt~•;~; ·/ug~gir~~ ::··
4-Chlorotoluene < .001 mg/1 05/14/05 18,27 WG202168 :i6!:;g!;;tiJ~i. " : <ggrr ······· ... "·m§;rr •gt'itf1g~ il]}? ug~gif~·f"
Bromochloromethane < .001 mg/1 05/14/05 18,27 WG202168
!~~E~!~[~:::Olllethane} :: . n ;··· :ggt( /Ein··· igtn·~··gi ·-·~!:!; L~g~g!tii·•·•············ . ?\I
ca.rl:lori\Te(ra\hJ()ride{ · ···· · ·.·.·.·· ?< :001t···· · •• mg/r //05/1'4/o.5 1ae21 ?wG20216B· t···
Chlorobenzene < ·.061 mg/1 05/14/05 ·ia,21 .. wd26i16ii
Chlorodibromomethane < .001 mg/1 05/14/05 18:27 WG202168 I
Page 20 of 31
I
I
I ENVIRONMENTAL
SCIENCE CORP.
I Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109 I Raleigh, NC 27607
nal te
I
Quality Assurance Report
Level II
L198282
HtP.~_PC?t.~.~¢.fYt.~_r~tj~:?:: Result. Units Date Anal zed
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 17, 2005
Batch
ENVIRONMENTAL
SCIENCE CORP.
Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
cis-1,2-Dichloroethene
Analyte
Analyte
ChlOiiae·,,,,,;-:•:-:-
tii'trat·ei ·
Sulfate Ji'f ~! 1I f¾t{ytx ,-:-,-· ·--
A~-~-~-~-i.~-~-~.Y. ...
Xi°ka-r:1·~rt\/' ··
Analyte
Barium
Quality Assurance
Level II
Report
12065 Lebanon Rd.
Mt. Juliet, TN 37122
{615) 758-5858
1-800-767-5859
Fax [phone]B59
Tax I.D. 62-0814289
Est. 1970
May 17, 2005
Ll98282
< .001 mg/1 05/16/05 16,09
(~i9.J?.¢:~~t9fYj)3J-:~t*\t Result'·--Units Date Analyzed
Units )\Dl.lp"l:_i:C'~-te\:::·, Re·su.1t·. ·ouplicate
••••••<tfl!l<'ill ff••··tvo•,••o.o•• (·•· /o}oo
mg/1 0.00 0.00
mg/1 0.00 o.oo
11.0
RPD Limit
o/oo· ••••+20+ o: Oo 20
0.00 20
, · LiibOrab)fY}.CC)#ti:-:OJ\ -~~tj\p1:e::n··
Units Known Val Result % Rec
Page 22 of 31
WG202267
Batch
Ref Samp Batch
}L19B736'0l
Limit Batch
I
I
I
I
I
I
I
I ENVIRONMENTAL
SCIENCE CORP.
I Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road I Raleigh, NC 27607
Suite 109 Quality Assurance Report
Level II
L198282
r<4fq<?~¥t_.t::9.TYt.G<:>¥.ittgJ r.~~tnpi:¢:rr Units Known Val Result
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-B00-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 17, 2005
% Rec Limit Batch
ENVIRONMENTAL
SCIENCE CORP.
Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
trans-1,2-Dichloroethene
Quality Assurance Report
Level II
Ll98282
mg/1 .02 0.0239 120.
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I .D. 62-0814289
Est. 1970
May 17, 2005
59-138 WG202168
I
I
I
I
_An_a_1_y_t_e _________________ ~u~J-=i:f~t-=t_P_C?_.t_:~~:~=:9~:~~:~~-~~:._c~,v~:~~I~-~-·9_:.i_:-~-:.:~-:~:~~:t~·:i=:~=J_t:_::: ___ %~R~e=c~--L=im=i-=t __ =B=a'-'t"c"'h'---_ _:I
.'.1\f.i:Chli:>i9itti€i_rie;::,:u;1::<C:}{:\)/
Trichlorofluoromethane
Vinyl chloride ::,;:y_:i;-¢fi¢_fh\tT~~-ap\-/:"· .....
Page 24 of 31
I
I
I ENVIRONMENTAL
SCIENCE CORP.
I Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109 I Raleigh, NC 27607
Vinyl chloride
lnalyte
I
I
Quality Assurance Report
Level II
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
l-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 17, 2005
Ll98282
mg/1 .02 0.0180 90.2 46-133 WG202267
<::·.~:~J?C?.#.~~:-~.fl.J.G9tjt)(Ol ::_s;amp_1e1r: Units Known Val ··ReSult"··· % Rec Limit Batch
\IJ.i8_1:)9:fi=it9tY.:hG9D,.~#.9V/s~riiPJ"~ \pµp}f¢~t~t1\! . Units LCSD Res Ref Res RPD L1m1t %Rec Batch
Page 25 of 31
ENVIRONMENTAL
SCIENCE CORP.
Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Quality Assurance Report
Level II
L198282
12065 Lebanon Rd.
Mt. Juliet, TN 37122
(615} 758-5858
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 17, 2005
•:\}}'' riicj/1}/::•• 0::0213: :} 0}0210 ::: 1·:1s·•··•·•··· ··i:1/} X •106•:: \ :}WG202l6a••· •·.
Page 26 of 31
I
I
I
I
I
I
I
I ENVIRONMENTAL
SCIENCE CORP.
I Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109 I Raleigh, NC 27607
Carbon Tetrachloride
IAnalyte
Quality Assurance Report
Level II
L198282
mg/1 0.0186 0.0180 3.23 17
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 17, 2005
92.8 WG202267
::<J;.~~l,~i\i_~:¢itit~.C>tj_t).\>1:7{SiiinPJ~: :PiiP.I:fC*_t:_¢.)? Units LCSD Res Ref Res RPD Limit %Rec Batch
·\:;::.Mtit>iiX?f3P~•-ke:·:,::::: Analyte Units MS.ReS ··Ref ReS TV % Rec Limit Ref Samp Batch
'
mg/1 47.0 29.0 50 36.0 80-120 L198282-03 WG201732 · JJ/i {[7{ rg:cid ·· ;gt · iiK:s l6tl~6 tiiiI~~!~I i[l811~I;
1 ~.'.'ESc'EX O .0025 0 .00 .003 85 .3 70-130 L198282-04 WG201903
·1:·1;·1;2:+;;tfibi{i8i'6~fi{;;;;··········••·· ·· ········ · ·•·•···•·····•···•••·•·•·;;;g/i·•·•·•·•·•· •<•3:3;~~ ! 6'.6Bi·•· rI:b;: •·••·•TfJ}it•· ··•g4c;c;;•·· •··•••ti•;;iJ·':/'.bi ·•·;.;g;;;•;fIJ•
1,1,1-Trichloroethane mg/1 0.0304 o.oo .02 152. 54-143 Ll98282-0l WG202168 1 i;r;2)2cTetrachTQroethaf1e / ····· ·········· ········· · ing/1) 0,0225 •a.coo :;02 \1120 i5B-13.4 r,19.s2a2,01.wG.202.16s
Page 27 of 31
I
ENVIRONMENTAL
SCIENCE CORP.
Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
1,1,2-Trichloroethane
Anal te
:ch~·qf_f¢.~)) Nitrate
Sulfate
Quality Assurance Report
Level II
Ll98282
mg/1 0.0217 0.00 .02
. M~ ~.:c"iX,{,Si:>i}c"et_P.UPliC"a te,:::r Units MSD Res Ref Res RPD
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 17, 2005
108. 58-125 Ll98282-01 WG202168
Limit %Rec Ref Sam Batch
I
I
I
I
> :i~r 4f ~1 1ftk .. 5'.24\ ·• _20.: } 90}2 . s: 6:i 2() 92.2
Ll_9_82_8_2/0_3 WG201074
Ll98282-03 WG201074
Ll98282-03 WG2010I mg/1 45.4 42.9 5.66 20 90.7
Page 28 of 31
I
I
I ENVIRONMENTAL
SCIENCE CORP.
I Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109 I Raleigh, NC 27607
Lalyte
I
I
Quality Assurance Report
Level II
Ll98282
/\~*i::i;:~}C.\:.~1::i:i~¢\:PliPii¢~J.:e)( Units MSD Res Ref Res RPD
mg/1 76.0
}(( ~J'){'}' 4 3 . 0
72.0
47.0
Page 29 of 31
5.41
8.89
12065 Lebanon Rd.
Mt. Juliet, TN 37122
(615) 758-585B
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 17, 2005
Limit %Rec Ref Samp Batch
20
20
122. Ll98011-01 WG201562
28. 0 tr~~IIJtif Uc!isi1~2
ENVIRONMENTAL
SCIENCE CORP.
Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Hexachlorobutadiene
Analyte
Quality Assurance Report
Level II
Ll98282
m /1 0.0207 0.0215 3.91
l\:·:~*¢tt:>C.)_$.PIK¢>P:iiPJJ¢_~_t;j~\) Units MSD Res Ref Res RPO
Batch number /Run number/ Sample number cross reference
WG201075: R232365: Ll98282-01 02 03 04 05
WG201271: R232509: Ll98282-0l 02 03 04 05
WG201074: R232521: Ll98282-01 02 03 04 05
WG201166: R232623 R232624: Ll98282-0l 02 03 04 05
WG201562: R232893: Ll98282-0l
WG201732: R232985: Ll98282-02 03 04 05
WG201769: R233096: Ll98282-0l 02 03 04 05
WG201902: R233148: Ll98282-0l 02 03
WG201903: R233250: Ll98282-04 05
WG202168: R233430: Ll98282-01 03 04 05 07
WG202267: R233453: L198282-02
22
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 17, 2005
103. Ll98282-0l
Limit %Rec Ref Samp
* denotes out of limit range result. See Attachment B of standard report for list of qualifiers.
**Calculations are performed prior to rounding of reported values
Page 30 of 31
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I ENVIRONMENTAL
SCIENCE CORP.
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
l-800-767-5859
Fax [phone]
I Piedmont Geologic
Mr. John Harper
Tax I.D. 62-0814289
Est. 1970
6003 Chapel Hill Road Suite 109 Quality Assurance Report
Level II I Raleigh,
I
I
I
I
I
I
I
I
I
I
I
I
I
I
'I
NC 27607 May 17, 2005
Ll98282
ESC Level 2 Data Package
The data package includes a summary of the analytic results of the quality
control samples required by the SW-846 or CWA methods. The quality control
samples include a method blank, a laboratory control sample, and the matrix
spike/matrix spike duplicate analysis. If a target parameter is outside
the method limits, every sample that is effected is flagged with the
appropriate qualifier in Appendix B of the analytic report.
Method Blank -an aliquot of reagent water carried through the
entire analytic process. The method blank results indicate if
any possible contamination exposure during the sample handling,
digestion or extraction process, and analysis. Concentrations of
target analytes above the reporting limit in the method blank are
qualified with the "B" qualifier.
Laboratory Control Sample -is a sample of known concentration
that is carried through the digestion/extraction and analysis
process. The percent recovery, expressed as a percentage of the
theoretical concentration, has statistical control limits
indicating that the analytic process is "in control". If a
target analyte is outside the control limits for the laboratory
control sample or any other control sample, the parameter is
flagged with a "J4" qualifier for all effected samples.
Matrix Spike and Matrix Spike Duplicate -is two aliquots of an
environmental sample that is spiked with known concentrations of
target analytes. The percent recovery of the target analytes
also has statistical control limits. If any recoveries that are
outside the method control limits, the sample that was selected
for matrix spike/matrix spike duplicate analysis is flagged with
either a 11 JS 11 or a 11 J6". The relative percent difference (%RPO)
between the matrix spike and the matrix spike duplicate
recoveries is all calculated. If the RPD is above the method
limit, the effected samples are flagged with a "J3" qualifier.
Page 31 of 31
· Piedmont ·Geologic
6003 Chapel Hill Road Suite I 09
Raleigh,NC 27607
Alternate billing information: Analys1s/Gonta1ner/t-'reservattve
trp.1-(p1 .,, GW ,i, ttJ'\ 10 ,X{. X h~';! X
TI? GW 10 :x;t X txc:•; X ,,x;-j:;Jl X i~~l X
GW 10 tx;::!i X >X!/l X IXig X l[•X~I X
Prepared by:
Chain of Cust'1~
Pagefi~
I I
• ENVIRONMENT AL
SCIENCE CORP.
12065 Lebanon Road
Mt Juliet, TN 3 7 I 22
Phone [phone]
FAX [phone]
"Matrix: SS -Soil GW -Groundwater WW -Wastewater OW -Drinking Water OT -Other ___ _ pH _____ _ Temp
Other Rcnmks, Quote#PIEGEO032405S Flow -------
uished by: (Signature) Date:
ed
hed ~ ) -----------------
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
• ENVIRONMENTAL SCIENCE CORP.
Cooler Receipt Form
Cooler Received On: §°-?-o5 and Opened On: y/--0~
ifignature)
I. Temperature of cooler when opened: _'3_,_/ __ Degrees Celsius
2. Were custody seals on outside of cooler and intact? YES NO
a. If yes, what kind and where:
b. Were the signature and date correct? YES NO
3. Were custody seals on containers intact? YES NO
4. Were custody papers inside cooler? ~ NO
5. Were custody papers properly filled out (ink, signed, etc.) -~ NO
6. Did you sign the custody papers in the appropriate place? ~ NO
7. What kind of packing material was used? ~ Peanuts Other None
8. Was sufficient ice used (if appropriate)? ~ NO
9. Did all bottles arrive in good condition? @S2 NO
10. Were all bottle labels complete?(#, date, signed, pres, etc)? ~ NO
11. Did all bottle labels and tags agree with custody papers? ~ NO
12. Were correct bottle's used for the analyses requested? ~ NO
13. If applicable, was an observable VOA headspace present? YES ®
14. Was sufficient amount of sample sent in each bottle? ~ NO
15. Were Correct preservatives used? G) NO
16.-Corrective action taken, if necessary:
a. Name of person contacted: See attached for resolution if needed
b. Date: _______ _
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
-12065 Lebanon Rd.
Mt. Juliet, TN 37122
ENVIRONMENTAL [phone]
1-800-767-5859
SCIENCE CORP. Fax [phone]
Tax I.D. 62-0814289
Est. 1970
REPORT OF ANALYSIS
Mr. John Harper May 19,2005
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
ESC Sample # Ll98587-01
Date Received May 11, 2005
Description NC State University Lot #86
Site ID
Sample ID MW-13D
Project # 2519 Collected By J Ganey
Collection Date 05/10/05 09:45
Parameter Result Det. Limit Units Method Date Dil.
Methane BDL 1000 ppb 8015M 05/11/05 1
Chloride 1600 1000 ug/1 9056 05/11/05 1 Nitrate BDL 100 ug/1 9056 05/11/05 1
Sulfate BDL 5000 ug/1 9056 05/11/05 1
Alkalinity 69000 10000 ug/1 310.2 05/18/05 1
Ethane BDL 1000 ppb 8015M 05/11/05 1
Ethene BDL 1000 ppb 8015M 05/11/05 1
TOC (Total Organic Carbon) 3100 1000 ug/1 9060 05/12/05 1
Mercury BDL 0.20 ug/1 7470A 05/16/05 1
Arsenic BDL 20. ug/1 6010B 05/12/05 1 Barium 10. 5.0 ug/1 6010B 05/12/05 1 Cadmium BDL 5.0 ug/1 6010B 05/12/05 1 Chromium BDL 10. ug/1 6010B 05/12/05 1 Iron, Dissolved BDL 100 ug/1 6010B 05/12/05 1 Lead BDL 5.0 ug/1 6010B 05/12/05 1 Manganese 94. 10. ug/1 6010B 05/12/05 1 Selenium 25. 20. ug/1 6010B 05/12/05 1 Silver BDL 10. ug/1 6010B 05/12/05 1
Volatile Organics
Benzene BDL 1.0 ug/1 6230D 05/15/05 1 Bromobenzene BDL 1.0 ug/1 6230D 05/15/05 1 Bromochloromethane BDL 1.0 ug/1 6230D 05/15/05 1
Bromodichloromethane BDL 1.0 ug/1 6230D 05/15/05 1 Bromoform BDL 1.0 ug/1 6230D 05/15/05 1 Bromomethane BDL 1.0 ug/1 6230D 05/15/05 1 n-Butylbenzene BDL 1. 0 ug/1 6230D 05/15/05 1 sec-Butylbenzene BDL 1.0 ug/1 6230D 05/15/05 1 tert-Butylbenzene BDL 1.0 ug/1 6230D 05/15/05 1 Carbon Tetrachloride BDL 1.0 ug/1 6230D 05/15/05 1 Chlorobenzene BDL 1.0 ug/1 6230D 05/15/05 l
BDL -Below Detection Limit
Det. Limit -Estimated Quantitation Limit(EQL)
Laboratory Certification Numbers:
C·TN-01 AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY· 11742, NJ -81002, WI· 998093910
00109, WV -233
Page 1 of SO
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 11, 2005
Description NC State University
Sample ID MW-13D
Collected By J Ganey
Collection Date 05/10/05 09 ,45
Parameter
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-Chloropropane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
Di-isopropyl ether
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
p-Isopropyltoluene
Methylene chloride
Methyl tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #86
Result Det. Limit
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1. 0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 5.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 5.0
BDL 5.0
BDL 5.0
BDL 1. 0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
Det. Limit -Estimated Quantitation Limit(EQL)
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I .D. 62-0814289
Est. 1970
May 19,2005
ESC Sample # Ll98587·01
Site ID
Project# 2519
Units
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
Method
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
62300
6230D
6230D
6230D
6230D
62300
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
Date
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
Laboratory Certification Numbers:
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Page 2 of 50
C-TN-01
00109, WV
I
I
I
I
I
I
Oil.
1 I 1
1
1
1 I 1
1
1
1
1 I 1
1
1
1
1 I 1
1
1
1 ii 1
1
~I 1
1
ti
1
1
~I
1
1
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 11, 2005
Description NC State University
Sample ID MW-13D
Collected By J Ganey
Collection Date 05/10/05 09,45
REPORT OF ANALYSIS
Lot #86
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 19,2005
ESC Sample # Ll98587-0l
Site ID
Project# 2519
Parameter Result Det. Limit Units Method Date Dil.
Trichlorofluoromethane BDL 1.0 ug/1 6230D 1,2,3-Trichloropropane BDL 1.0 ug/1 6230D 1,2,4-Trimethylbenzene BDL 1. 0 ug/1 6230D 1,3,5-Trimethylbenzene BDL 1.0 ug/1 6230D Toluene BDL 5.0 ug/1 6230D Vinyl chloride BDL 1.0 ug/1 6230D Xylenes, Total BDL 3.0 ug/1 6230D
BDL -Below Detection Limit
Det. Limit -Estimated Quantitation Limit(EQL)
Laboratory Certification Numbers:
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Note:
The reported analytical results relate only to the sample submitted.
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
C-TN-01
1
1
1
1
1
1
1
00109, WV -233
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported: 05/19/05 13:02 Printed: 05/19/05 13:04 I Page 3 of 50
I
ENVIRONMENTAL
SCIENCE CORP.
REPORT OF ANALYSIS Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
May 11, 2005 Date Received
Description NC State University Lot #86
Sample ID
Collected By
Collection Date
Parameter
Methane
Chloride
Nitrate
Sulfate
Alkalinity
Ethane
Ethene
MW-16O
J Ganey
05/10/05 10,53
TOC (Total Organic Carbon)
Mercury
Arsenic
Barium
Cadmium
Chromium
Iron,Dissolved
Lead
Manganese
Selenium
Silver
Volatile Organics
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon Tetrachloride
Chlorobenzene
BDL -Below Detection Limit
Result
BDL
1200
BDL
BDL
56000
BDL
BDL
9200
BDL
BDL
11.
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
8DL
8DL
8DL
8DL
8DL
8DL
8DL
8DL
8DL
Det. Limit -Estimated Quantitation Limit(EQL)
Det. Limit
1000
1000
100
5000
10000
1000
1000
1000
0.20
20.
5.0
5.0
10.
100
5.0
10.
20.
10.
1.0
1. 0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax {615) 758-5859
Tax I.D. 62-0814289
Est. 1970
May 19,2005
ESC Sample # Ll98587-02
Site ID
Project # 2519
Units Method Date
ppb 8015M 05/11/05
ug/1 9056 05/11/05
ug/1 9056 05/11/05
ug/1 9056 05/11/05
ug/1 310.2 05/18/05
ppb 8015M 05/11/05
ppb 8015M 05/11/05
ug/1 9060 05/12/05
ug/1 7470A 05/16/05
ug/1 60108 05/12/05
ug/1 60108 05/12/05
ug/1 6010B 05/12/05
ug/1 6010B 05/12/05
ug/1 6010B 05/12/05
ug/1 60108 05/12/05
ug/1 6010B 05/12/05
ug/1 6010B 05/12/05
ug/1 60108 05/12/05
ug/1 6230D 05/15/05
ug/1 6230D 05/15/05
ug/1 6230D 05/15/05
ug/1 6230D 05/15/05
ug/1 6230D 05/15/05
ug/1 6230D 05/15/05
ug/1 6230D 05/15/05
ug/1 6230D 05/15/05
ug/1 6230D 05/15/05
ug/1 6230D 05/15/05
ug/1 6230D 05/15/05
Laboratory Certification Numbers:
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Page 4 of so
C-TN-01
00109, WV
I
I
I
I
I
I
Dil.
1 I 1
1
:1
1
1 I
1
:1
1
1 ii 1
1 ii
1
ti
1
1
ti
1
1
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 11, 2005
Description NC State University
Sample ID MW-16D
Collected By J Ganey
Collection Date 05/10/05 10,53
Parameter
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-Chloropropane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
Di-isopropyl ether
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
p-Isopropyltoluene
Methylene chloride
Methyl tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #86
Result Det. Limit
BDL 1.0
BDL 1.0
4.7 1.0
BDL 1.0
BDL 1.0
BDL 1.0
1.9 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1. 0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
2.9 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 5.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 5.0
BDL 5.0
BDL 5.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1. 0
BDL 1. 0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL l. 0
Det. Limit -Estimated Quantitation Limit(EQL)
12065 Lebanon Rd.
Mt. Juliet, TN 37122
(615} 758-5858
1-800-767-5B59
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 19,2005
ESC Sample#
Site ID
Project#
Units Method
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
Ll98587-02
2519
Date
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
Laboratory Certification Numbers:
C-TN-01
Dil.
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
l
1
l
1
1
1
1
l
1
1
1
1
l
1
1
1
1
1
1
l
l
1
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
00109, WV -233
Page 5 of SO
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 11, 2005
Description NC State University
Sample ID MW-16D
Collected By J Ganey Collection Date 05/10/05 10,53
Parameter
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Toluene
Vinyl chloride
Xylenes, Total
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #86
Result Det. Limit
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1. 0
BDL 5.0
BDL 1.0
BDL 3.0
Det. Limit -Estimated Quantitation Limit(EQL)
Units
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
Laboratory Certification Numbers:
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 19,2005
ESC Sample #
Site ID
Project#
Method
6230D
6230D
6230D
6230D
6230D
62300
6230D
Ll98587-02
2519
Date
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
C-TN-01
00109, WV
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910 Note:
The reported analytical results relate only to the sample submitted.
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported: 05/19/05 13:02 Printed: 05/19/05 13:04
Page 6 of so
I
I
I
I
I
I
Oil.
1 I 1
1
1
1 I 1
1
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 11, 2005
Description NC State University
Sample ID MW-27
Collected By J Ganey
Collection Date 05/10/05 14:44
Parameter
Methane
Chloride
Nitrate
Sulfate
Alkalinity
Ethane
Ethene
TOC (Total Organic Carbon)
Mercury
Arsenic
Barium
Cadmium
Chromium
Iron,Dissolved
Lead
Manganese
Selenium
Silver
Volatile Organics
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon Tetrachloride
Chlorobenzene
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #86
Result Det. Limit
BDL 1000
2900 1000
410 100
BDL 5000
47000 10000
BDL 1000
BDL 1000
BDL 1000
BDL 0.20
BDL 20.
18. 5.0
BDL 5.0
BDL 10.
BDL 100
BDL 5.0
49. 10.
BDL 20.
BOL 10.
BOL 1.0
BOL 1.0
BOL 1.0
BOL 1.0
BOL 1.0
BOL 1.0
BOL 1.0
BDL 1.0
BOL 1.0
10. 1.0
BOL 1.0
Det. Limit -Estimated Quantitation Limit{EQL)
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax (615) 75B-5859
Tax I.D. 62-0814289
Est. 1970
May 19,2005
ESC Sample#
Site ID
Project#
Units Method
ppb 8015M
ug/1 9056
ug/1 9056
ug/1 9056
ug/1 310.2
ppb 8015M
ppb 8015M
ug/1 9060
ug/1 7470A
ug/1 6010B
ug/1 60108
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 60108
ug/1 6010B
ug/1 62300
ug/1 6230D
ug/1 62300
ug/1 62300
ug/1 62300
ug/1 62300
ug/1 62300
ug/1 62300
ug/1 62300
ug/1 62300
ug/1 6230D
Ll98587-03
2519
Date
05/11/05
05/11/05
05/11/05
05/11/05
05/18/05
05/11/05
05/11/05
05/13/05
05/16/05
05/12/05
05/12/05
05/12/05
05/12/05
05/12/05
05/12/05
05/12/05
05/12/05
05/12/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
Laboratory Certification Numbers:
C-TN-01
Dil.
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,0W21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910 00109, WV -233
Page 7 of SO
.,
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 11, 2005
Description NC State University
Sample ID MW-27
Collected By J Ganey
Collection Date 05/10/05 14,44
REPORT OF ANALYSIS
Lot #86
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
l-B00-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 19, 2005
ESC Sample#
Site ID
Project#
L198587-03
2519
I
I
I
I
I
I Parameter Result Det. Limit Units Method Date Dil.
Chlorodibromomethane BDL 1.0 ug/1 6230D Chloroethane BDL 1.0 ug/1 6230D
Chloroform 17. 1.0 ug/1 6230D Chloromethane BDL 1.0 ug/1 6230D
2-Chlorotoluene BDL 1.0 ug/1 6230D
4-Chlorotoluene BDL 1.0 ug/1 6230D l,2-Dibromo-3-Chloropropane BDL 1.0 ug/1 6230D 1,2-Dichlorobenzene BDL 1.0 ug/1 6230D 1,3-Dichlorobenzene BDL 1.0 ug/1 6230D
1,4-Dichlorobenzene BDL 1.0 ug/1 62300
Dichlorodifluoromethane BDL 1.0 ug/1 6230D 1,1-Dichloroethane BDL 1.0 ug/1 6230D
1,2-Dichloroethane BDL 1.0 ug/1 6230D
1,1-Dichloroethene BDL 1.0 ug/1 6230D cis-1,2-Dichloroethene BDL 1.0 ug/1 6230D
trans-1,2-Dichloroethene BDL 1.0 ug/1 6230D 1,2-Dichloropropane 10. 1.0 ug/1 6230D 1,3-Dichloropropane BDL 1.0 ug/1 6230D 2,2-Dichloropropane BDL 1.0 ug/1 6230D 1,1-Dichloropropene BDL 1.0 ug/1 6230D
Di-isopropyl ether BDL 5.0 ug/1 6230D
Ethylbenzene BDL 1.0 ug/1 6230D
Hexachlorobutadiene BDL 1. 0 ug/1 6230D
Isopropylbenzene BDL 1.0 ug/1 6230D p-Isopropyltoluene BDL 1. 0 ug/1 6230D
Methylene chloride BDL 5.0 ug/1 6230D Methyl tert-butyl ether BDL 5.0 ug/1 6230D
Naphthalene BDL 5.0 ug/1 6230D n-Propylbenzene BDL 1.0 ug/1 6230D
Styrene BDL 1.0 ug/1 6230D 1,1,1,2-Tetrachloroethane BDL 1.0 ug/1 6230D
1,1,2,2-Tetrachloroethane BDL 1.0 ug/1 6230D
Tetrachloroethene BDL 1.0 ug/1 6230D
1,2,3-Trichlorobenzene BDL 1.0 ug/1 6230D
1,2,4-Trichlorobenzene BDL 1.0 ug/1 6230D
1,1,1-Trichloroethane BDL 1.0 ug/1 6230D 1,1,2-Trichloroethane BDL 1.0 ug/1 6230D
Trichloroethene 4.2 1.0 ug/1 6230D
BDL -Below Detection Limit
Det. Limit -Estimated Quantitation Limit(EQL)
Laboratory Certification Numbers:
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Page 8 of 50
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
C-TN-01
00109, WV -
t I
1
t I 1
1
ti
1
1
ti
1
1
ti
1
ti 1
1
ti 1
1
ti
1
1
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 11, 2005
Description NC State University
Sample ID MW-27
Collected By J Ganey
Collection Date 05/10/05 14:44
REPORT OF ANALYSIS
Lot #86
12065 Lebanon Rd.
Mt. Juliet, TN 37122
(615) 758-5B58
l-B00-767-5959
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 19,2005
ESC Sample# L1985B7-03
Site ID
Project# 2519
Parameter Result Det. Limit Units Method Date Oil.
Trichlorofluoromethane BDL 1.0 ug/l 6230D
1,2,3-Trichloropropane BDL 1.0 ug/l 6230D 1,2,4-Trimethylbenzene BDL 1.0 ug/l 6230D 1,3,5-Trimethylbenzene BDL 1.0 ug/l 6230D Toluene BDL 5.0 ug/l 6230D Vinyl chloride BDL 1.0 ug/l 6230D Xylenes, Total BDL 3.0 ug/l 6230D
BDL -Below Detection Limit
Det. Limit -Estimated Quantitation Limit(EQL)
Laboratory Certification Numbers:
AIHA -100789, AL -40660, CA -1-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Note:
The reported analytical results relate only to the sample submitted.
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
C-TN-01
1
1
1
1
1
1
1
00109, WV -233
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported: 05/19/05 13:02 Printed: 05/19/05 13:04 I Page 9 of 50
g
I'
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 11, 2005
Description NC State University
Sample ID MW-34DR
Collected By J Ganey
Collection Date 05/10/05 09,00
Parameter
Methane
Chloride
Nitrate
Sulfate
Alkalinity
Ethane
Ethene
TOC (Total Organic Carbon)
Mercury
Arsenic
Barium
Cadmium
Chromium
Iron,Dissolved
Lead
Manganese
Selenium
Silver
Volatile Organics
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon Tetrachloride
Chlorobenzene
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #86
Result Det. Limit
BDL 1000
1600 1000
BDL 100
BDL 5000
40000 10000
BDL 1000
BDL 1000
BDL 1000
BDL 0.20
BDL 20.
43. 5.0
BDL 5.0
BDL 10.
BDL 100
BDL 5.0
BDL 10.
30. 20.
BDL 10.
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
Det. Limit -Estimated Quantitation Limit{EQL)
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 19,2005
ESC Sample#
Site ID
Project#
Units Method
ppb 8015M
ug/1 9056
ug/1 9056
ug/1 9056
ug/1 310.2
ppb 8015M
ppb 8015M
ug/1 9060
ug/1 7470A
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
L198587-04
2519
Date
05/11/05
05/11/05
05/11/05
05/11/05
05/18/05
05/11/05
05/11/05
05/13/05
05/16/05
05/12/05
05/12/05
05/12/05
05/12/05
05/12/05
05/12/05
05/12/05
05/12/05
05/12/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
Laboratory Certification Numbers:
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN C-TN-01
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA -00109, WV
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Page 10 of 50
I
I
I
I
I
I
Dil.
1 I 1
1
1 I 1
1
1 I
1
1 I 1
1
1 I 1
1
1
1
1 I 1
1 ~· 1
1
1 I 1
1
1
1 I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 11, 2005
Description NC State University
Sample ID MW-34DR
Collected By J Ganey
Collection Date 05/10/05 09,00
Parameter
Chlorodibromomethane
Chlo roe thane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
l,2-Dibromo-3-Chloropropane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
Di-isopropyl ether
Ethylbenzene
Hex.achlorobutadiene
Isopropylbenzene
p-Isopropyltoluene
Methylene chloride
Methyl tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #86
Result Det. Limit
BDL 1.0
BDL 1. 0
1. 0 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL l.O
BDL l. 0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 5.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 5.0
BDL 5.0
BDL 5.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
Det. Limit -Estimated Quantitation Limit(EQL)
12065 Lebanon Rd.
Mt. Juliet, TN 37122
{615) 758-5858
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 19,2005
ESC Sample#
Site ID
Project#
Units Method
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
Ll98587-04
2519
Date
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
Laboratory Certification Numbers:
C-TN-01
Dil.
l
l
l
l
l
l
l
l
1
1
1
1
l
1
1
1
1
l
1
l
1
1
1
1
1
l
l
1
1
1
l
l
l
l
1
1
l
1
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
00109, WV -233
Page 11 of so
ENVIRONMENTAL
SCIENCE CORP.
REPORT OF ANALYSIS
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Eat. 1970
Mr. John Harper
Piedmont Geologic May 19, 2005
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 11, 2005
Description NC State University
Sample ID MW-34DR
ESC Sample # L198587-04
Lot #86
Site ID
Project# 2519 Collected By J Ganey
Collection Date 05/10/05 09,00
Parameter Result Det. Limit Units Method
Trichlorofluoromethane BDL 1.0 ug/1 6230D
1,2,3-Trichloropropane BDL 1.0 ug/1 6230D
1,2,4-Trimethylbenzene BDL 1.0 ug/1 6230D 1,3,5-Trimethylbenzene BDL 1.0 ug/1 6230D
Toluene BDL 5.0 ug/1 6230D Vinyl .chloride BDL 1.0 ug/1 6230D Xylenes, Total · BDL 3.0 ug/1 6230D
BDL -Below Detection Limit
Det. Limit -Estimated Quantitation Limit(EQL)
Laboratory Certification Numbers:
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Note:
The reported analytical results relate only to the sample submitted.
Date
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
C-TN-01
00109, WV
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported: 05/19/05 13:02 Printed: 05/19/05 13:04
Page 12 of 50
I
I
I
I
I
I
Oil.
1 I 1
1
1
1 I 1
1
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
ENVIRONMENTAL
SCIENCE CORP.
REPORT OF ANALYSIS
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
May 11, 2005 Date Received
Description NC State University Lot #86
Sample ID
Collected By
Collection Date
Parameter
Methane
Chloride
Nitrate
Sulfate
Alkalinity
Ethane
Ethene
MW-40
J Ganey
05/10/05 14,00
TOC (Total Organic Carbon)
Mercury
Arsenic
Barium
Cadmium
Chromium
Iron,Dissolved
Lead
Manganese
Selenium
Silver
Volatile Organics
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon Tetrachloride
Chlorobenzene
BDL -Below Detection Limit
Result
8DL
3300
730
8DL
23000
8DL
8DL
8DL
8DL
8DL
14.
8DL
8DL
BDL
BDL
50.
8DL
8DL
8DL
8DL
8DL
8DL
8DL
BDL
8DL
8DL
8DL
8DL
BDL
Det. Limit -Estimated Quantitation Limit(EQL)
Det. Limit
1000
1000
100
5000
10000
1000
1000
1000
0 .20
20.
5.0
5.0
10.
100
5.0
10.
20.
10.
1.0
1.0
1. 0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-08142B9
Est. 1970
May 19,2005
ESC Sample#
Site ID
Project#
Units
ppb
ug/1
ug/1
ug/1
ug/1
ppb
ppb
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
Method
8015M
9056
9056
9056
310.2
8015M
8015M
9060
7470A
6010B
60108
60108
60108
6010B
60108
60108
6010B
6010B
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
L198587-05
2519
Date
05/11/05
05/11/05
05/11/05
05/11/05
05/18/05
05/11/05
05/11/05
05/13/05
05/16/05
05/12/05
05/12/05
05/12/05
05/12/05
05/12/05
05/12/05
05/12/05
05/12/05
05/12/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
Laboratory Certification Numbers:
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN C-TN-01
Dil.
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA -00109, WV -233
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Page 13 of so
ENVIRONMENTAL
SCIENCE CORP.
REPORT OF ANALYSIS
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 11, 2005
Description NC State University Lot #86
Sample ID MW-40
Collected By J Ganey
Collection Date 05/10/05 14:00
Parameter Result
Chlorodibromomethane BDL
Chloroethane BOL
Chloroform 110
Chloromethane BDL
2-Chlorotoluene BDL
4-Chlorotoluene BDL
1,2-Dibromo-3-Chloropropane BDL
1,2-Dichlorobenzene BOL
1,3-Dichlorobenzene BOL
1,4-Dichlorobenzene BDL
Dichlorodifluoromethane BDL
1,1-Dichloroethane BDL
1,2-Dichloroethane BDL
1,1-Dichloroethene BDL
cis-1,2-Dichloroethene BDL
trans-1,2-Dichloroethene BOL
1,2-Dichloropropane BDL
1,3-Dichloropropane BOL
2,2-Dichloropropane BOL
1,1-Dichloropropene BOL
Di-isopropyl ether BDL
Ethylbenzene BDL
Hexachlorobutadiene BDL
Isopropylbenzene BDL
p-Isopropyltoluene BDL
Methylene chloride BOL
Methyl tert-butyl ether BOL
Naphthalene BOL
n-Propylbenzene BDL
Styrene BDL
1,1,1,2-Tetrachloroethane BOL
1,1,2,2-Tetrachloroethane BDL
Tetrachloroethene BDL
1,2,3-Trichlorobenzene BDL
1,2,4-Trichlorobenzene BOL
1,1,1-Trichloroethane BDL
1,1,2-Trichloroethane BDL
Trichloroethene BOL
BDL -Below Detection Limit
Det. Limit -Estimated Quantitation Limit(EQL)
Det. Limit
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
5.0
5.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 19,2005
ESC Sample#
Site ID
Project#
Units Method
ug/1 62300
ug/1 62300
ug/1 6230D.
ug/1 62300
ug/1 6230D
ug/1 6230D
ug/1 62300
ug/1 6230D
ug/1 62300
ug/1 62300
ug/1 6230D
ug/1 6230D
ug/1 62300
ug/1 62300
ug/1 6230D
ug/1 62300
ug/1 62300
ug/1 6230D
ug/1 6230D
ug/1 62300
ug/1 6230D
ug/1 6230D
ug/1 62300
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 62300
ug/1 62300
ug/1 62300
ug/1 62300
ug/1 62300
ug/1 62300
ug/1 62300
ug/1 62300
ug/1 6230D
ug/1 6230D
ug/1 6230D
Ll98587-05
2519
Date
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
Laboratory Certification Numbers:
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Page 14 of so
C-TN-01
00109, WV
I
I
I
I
I
I
Dil.
1
1
1 I
1
1
1
1 I 1
1
1
1
1 I
1
1
1
1
1 I
1
1
1
1
1 I
1
1
1
1
1 I
1
1
1
1 I 1
1
1
1
1 I
1
1 I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 11, 2005
Description NC State University
Sample ID MW-40
Collected By J Ganey Collection Date 05/10/05 14, 00
Parameter
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Toluene
Vinyl chloride
Xylenes, Total
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #86
Result Det. Limit
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 5.0
BDL 1.0
BDL 3.0
Det. Limit -Estimated Quantitation Limit(EQL)
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]B59
Tax I.D. 62-0814289
Est. 1970
May 19,2005
ESC Sample#
Site ID
Project#
Units Method
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
Ll98587-05
2519
Date
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
sentative
Laboratory Certification Numbers:
C-TN-01
Oil.
l
l
1
1
1
l
l
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA 00109, WV -233
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910 Note:
The reported analytical results relate only to the sample submitted.
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported: 05/19/05 13:02 Printed: 05/19/05 13:04
Page 15 of so
I
ENVIRONMENTAL
SCIENCE CORP.
REPORT OF ANALYSIS
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
May 11, 2005 Date Received
Description NC State University Lot #86
Sample ID
Collected By
Collection Date
Parameter
Methane
Chloride
Nitrate
Sulfate
Alkalinity
Ethane
Ethene
MW-41D
J Ganey
05/10/05 11,22
TOC (Total Organic Carbon)
Mercury
Arsenic
Barium
Cadmium
Chromium
Iron,Dissolved
Lead
Manganese
Selenium
Silver
Volatile Organics
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon Tetrachloride
Chlorobenzene
BDL -Below Detection Limit
Result
BDL
1700
BDL
BDL
17000
BDL
BDL
BDL
BDL
BDL
6.7
BDL
BDL
BDL
BDL
10.
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
1.0
BDL
Det. Limit -Estimated Quantitation Limit(EQL)
Det. Limit
1000
1000
100
5000
10000
1000
1000
1000
0.20
20.
5.0
5.0
10.
100
5.0
10.
20.
10.
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 19,2005
ESC Sample # Ll98587-06
Site ID
Project # 2519
Units Method Date
ppb 8015M 05/11/05
ug/1 9056 05/11/05
ug/1 9056 05/11/05
ug/1 9056 05/11/05
ug/1 310.2 05/18/05
ppb 8015M 05/11/05
ppb 8015M 05/11/05
ug/1 9060 05/13/05
ug/1 7470A 05/16/05
ug/1 6010B 05/12/05
ug/1 6010B 05/12/05
ug/1 6010B 05/12/05
ug/1 6010B 05/12/05
ug/1 6010B 05/12/05
ug/1 6010B 05/12/05
ug/1 6010B 05/12/05
ug/1 6010B 05/12/05
ug/1 60108 05/12/05
ug/1 6230D 05/15/05
ug/1 6230D 05/15/05
ug/1 6230D 05/15/05
ug/1 6230D 05/15/05
ug/1 6230D 05/15/05
ug/1 6230D 05/15/05
ug/1 6230D 05/15/05
ug/1 6230D 05/15/05
ug/1 6230D 05/15/05
ug/1 6230D 05/15/05
ug/1 6230D 05/15/05
Laboratory Certification Numbers:
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Page 16 of so
C-TN-01
00109, WV
I
I
I
I
I
I
Dil.
1 I 1
1
1 I 1
1
1 I
1
:1
1 ~. 1
1 ii
1 ~· 1
1 ~· 1 11
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 11, 2005
Description NC State University
Sample ID MW-41D
Collected By J Ganey
Collection Date 05/10/05 11:22
Parameter
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-Chloropropane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethe~e
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
Di-isopropyl ether
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
p-Isopropyltoluene
Methylene chloride
Methyl tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #86
Result Det. Limit
BOL l. 0
BOL 1.0
4.2 1.0
BOL 1.0
BOL 1.0
BOL 1.0
BOL 1.0
BOL 1.0
BOL 1.0
BOL 1.0
BOL 1.0
BOL l. 0
BOL 1.0
BOL 1.0
BOL 1.0
BOL 1. 0
BOL 1.0
BOL 1.0
BOL 1.0
BOL 1.0
BOL 5.0
BOL 1.0
BOL 1.0
BOL 1.0
BOL 1.0
BOL 5.0
BOL 5.0
BOL 5.0
BOL l. 0
BOL 1.0
BOL 1.0
BOL 1.0
BOL 1.0
BOL 1.0
BOL 1.0
BOL l. 0
BOL 1.0
BOL 1.0
Det. Limit -Estimated Quantitation Limit(EQL)
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-08142B9
Est. 1970
May 19,2005
ESC Sample#
Site ID
Project#
Units Method
ug/1 62300
ug/1 62300
ug/1 62300
ug/1 62300
ug/1 62300
ug/1 62300
ug/1 62300
ug/1 6230D
ug/1 62300
ug/1 6230D
ug/1 6230D
ug/1 62300
ug/1 62300
ug/1 6230D
ug/1 62300
ug/1 62300
ug/1 6230D
ug/1 62300
ug/1 62300
ug/1 62300
ug/1 62300
ug/1 6230D
ug/1 62300
ug/1 6230D
ug/1 62300
ug/1 62300
ug/1 6230D
ug/1 62300
ug/1 6230D
ug/1 6230D
ug/1 62300
ug/1 62300
ug/1 62300
ug/1 62300
ug/1 62300
ug/1 62300
ug/1 6230D
ug/1 6230D
Ll98587-06
2519
Date
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
Laboratory Certification Numbers:
C-TN-01
Dil.
l
l
l
l
1
l
1
l
l
l
1
1
l
l
l
l
l
l
l
l
l
l
1
l
l
l
1
l
1
l
1
l
l
l
l
l
l
l
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
00109, WV -233
Page 17 of 50
I,
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 11, 2005
Description NC State University
Sample ID MW-41D
Collected By J Ganey
Collection Date 05/10/05 11,22
Parameter
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Toluene
Vinyl chloride
Xylenes, Total
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #86
Result Det. Limit
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 5.0
BDL 1.0
BDL 3.0
Det. Limit -Estimated Quantitation Limit(EQL)
Units
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
Laboratory Certification Numbers:
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax {615) 758-5859
Tax I.D. 62-0814289
Est. 1970
May 19,2005
ESC Sample#
Site ID
Project#
Method
6230D
6230D
6230D
6230D
6230D
6230D
6230D
Ll98587-06
2519
Date
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
entative
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
C-TN-01
00109, WV
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Note:
The reported analytical -results relate only to the sample submitted.
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported: 05/19/05 13:02 Printed: 05/19/05 13:04
Page 18 of so
I
I
I
I
I
I
Oil.
ti
1
1 ~·
I
I
I
I
I
I
I
I 233
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 11, 2005
Description NC State University
Sample ID MW-42I
Collected By J Ganey
Collection Date 05/10/05 11:49
Parameter
Methane
Chloride
Nitrate
Sulfate
Alkalinity
Ethane
Ethene
TOC (Total Organic Carbon)
Mercury
Arsenic
Barium
Cadmium
Chromium
Iron,Dissolved
Lead
Manganese
Selenium
Silver
Volatile Organics
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon Tetrachloride
Chlorobenzene
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #86
Result Det. Limit
BDL 1000
4100 1000
220 100
BDL 5000
25000 10000
BDL 1000
BDL 1000
2100 1000
BDL 0 .20
BDL 20.
7.0 5.0
BDL 5.0
BDL 10.
BDL 100
BDL 5.0
11. 10.
21. 20.
BDL 10.
BDL 1.0
BDL 1. 0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
Det. Limit -Estimated Quantitation Limit(EQL)
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 19,2005
ESC Sample#
Site ID
Project#
Units Method
ppb 8015M
ug/1 9056
ug/1 9056
ug/1 9056
ug/1 310.2
ppb 8015M
ppb 8015M
ug/1 9060
ug/1 7470A
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
Ll98587-07
2519
Date
05/11/05
05/11/05
05/11/05
05/11/05
05/18/05
05/11/05
05/11/05
05/13/05
05/16/05
05/12/05
05/12/05
05/12/05
05/12/05
05/12/05
05/12/05
05/12/05
05/12/05
05/12/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
Laboratory Certification Numbers:
C-TN-01
Dil.
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
00109, WV -233
Page 19 of so
t.
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 11, 2005
Description NC State University
Sarrple ID MW-421
Collected By J Ganey
Collection Date 05/10/05 11 :49
Parameter
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-Chloropropane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
Di-isopropyl ether
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
p-Isopropyltoluene
Methylene chloride
Methyl tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #86
Result Det. Limit
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 5.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 5.0
BDL 5.0
BDL 5.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1. 0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
Det. Limit -Estimated Quantitation Limit{EQL)
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax {615) 758-5859
Tax I.D. 62-0814289
Est. 1970
May 19,2005
ESC Sample# L198587-07
Site ID
Project# 2519
Units
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
Method
6230D
6230D
6230D
6230D
6230D
6230D
62300
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
Date
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
Laboratory Certification Numbers:
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Page 20 of so
C-TN-01
00109, WV
I
I
I
I
I
I
Dil.
1 I 1
1
1
1 I 1
1
1
1
ti
1
1
ti
1
ti 1
1
ti
1
1
ti
1
1 ~· 1
1 I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 11, 2005
Description NC State University
Sample ID MW-42I
Collected By J Ganey
Collection Date 05/10/05 11:49
Parameter
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Toluene
Vinyl chloride
Xylenes, Total
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #86
Result Det. Limit
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 5.0
BDL 1.0
BDL 3.0
Det. Limit -Estimated Quantitation Limit(EQL)
1206S Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 19,2005
ESC Sample#
Site ID
Project#
Units Method
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
Ll98587-07
2519
Date
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
Laboratory Certification Numbers:
C-TN-01
Oil.
1
1
1
1
1
1
1
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA 00109, WV -233
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Note:
The reported analytical results relate only to the sample submitted.
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported: 05/19/05 13:02 Printed: 05/19/05 13:04
Page 21 of so
I "
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedrront Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received
Description
Sample ID
Collected By
Collection
Parameter
Methane
Chloride
Nitrate
Sulfate
Date
Alkalinity
Ethane
Ethene
May
NC State
MW-43
J Ganey
05/10/05
TOC (Total Organic Carbon)
Mercury
Arsenic
Barium
Cadmium
Chromium
Iron,Dissolved
Lead
Manganese
Selenium
Silver
Volatile Organics
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon Tetrachloride
Chlorobenzene
BDL -Below Detection Limit
11, 2005
University
13,08
REPORT OF ANALYSIS
Lot #86
Result
BDL
1700
BDL
BDL
17000
BDL
BDL
BDL
BDL
BDL
20.
BDL
BDL
BDL
BDL
19.
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
Det. Limit
1000
1000
100
5000
10000
1000
1000
1000
0 .20
20.
5.0
5.0
10.
100
5.0
10.
20.
10.
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
Det. Limit -Estimated Quantitation Limit{EQL)
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 19, 2005
ESC Sample # L198587-08
Site ID
Project # 2519
Units Method Date
ppb 8015M 05/11/05
ug/1 9056 05/11/05
ug/1 9056 05/11/05
ug/1 9056 05/11/05
ug/1 310.2 05/18/05
ppb 8015M 05/11/05
ppb 8015M 05/11/05
ug/1 9060 05/13/05
ug/1 7470A 05/16/05
ug/1 6010B 05/12/05
ug/1 6010B 05/12/05
ug/1 6010B 05/12/05
ug/1 6010B 05/12/05
ug/1 6010B 05/12/05
ug/1 6010B 05/12/05
ug/1 6010B 05/12/05
ug/1 6010B 05/12/05
ug/1 6010B 05/12/05
ug/1 6230D 05/15/05
ug/1 6230D 05/15/05
ug/1 6230D 05/15/05
ug/1 6230D 05/15/05
ug/1 6230D 05/15/05
ug/1 6230D 05/15/05
ug/1 6230D 05/15/05
ug/1 6230D 05/15/05
ug/1 6230D 05/15/05
ug/1 6230D 05/15/05
ug/1 6230D 05/15/05
Laboratory Certification Numbers:
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Page 22 of so
C-TN-01
00109, WV
I
I
I
I
I
I
Dil.
1 I
1
1
1 I 1
1 11
1
11
1
1
~I
1
1 ii
1
~I
1
1 ii 1
1 11
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 11, 2005
Description NC State University
Sample ID MW-43
Collected By J Ganey
Collection Date 05/10/05 13,08
Parameter
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-Chlorop~opane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
Di-isopropyl ether
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
p-Isopropyltoluene
Methylene chloride
Methyl tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene I
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #86
Result Det. Limit
BDL 1.0
BDL 1. 0
11. 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1. 0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 5.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 5.0
BDL 5.0
BDL 5.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
Det. Limit -Estimated Quantitation Limit(EQL)
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 19,2005
ESC Sample #
Site ID
Project#
Units Method
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
L198587-08
2519
Date
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
·05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
Laboratory Certification Numbers:
C-TN-01
Dil.
l
l
1
l
l
1
l
l
1
l
l
l
1
1
l
l
1
l
l
1
l
l
l
l
l
l
1
1
1
1
1
1
l
l
1
l
l
1
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
00109, WV -233
Page 23 of 50
l.1'
ENVIRONMENTAL
SCIENCE CORP.
REPORT OF ANALYSIS
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax (615} 758-5859
Tax I.D. 62-0814289
Est. 1970
Mr. John Harper
Piedmont Geologic May 19, 2005
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 11, 2005
Description NC State University
Sample ID MW-43
ESC Sample# L198587-08
Lot #86
Site ID
Project# 2519 Collected By J Ganey
Collection Date 05/10/05 13,08
Parameter Result Det. Limit Units Method
Trichlorofluoromethane BDL 1.0 ug/1 6230D 1,2,3-Trichloropropane BDL 1.0 ug/1 6230D
1,2,4-Trimethylbenzene BDL 1.0 ug/1 6230D
1,3,5-Trimethylbenzene BDL 1.0 ug/1 6230D
Toluene BDL 5.0 ug/1 6230D Vinyl chloride BDL 1.0 ug/1 6230D
Xylenes, Total BDL 3.0 ug/1 6230D
BDL -Below Detection Limit
Det. Limit -Estimated Quantitation Limit(EQL)
Laboratory Certification Numbers:
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Note:
The reported analytical results relate only to the sample submitted.
Date
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
C-TN-01
00109, WV
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported: 05/19/05 13:02 Printed: 05/19/05 13:04
Page 24 of SO
I
I
I
I
I
I
Oil. ~• 1
1
ti
I
I
I
I
I
I
I
I 233
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
D
I
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 11, 2005
Description NC State University
Sample ID MW-43D
Collected By J Ganey
Collection Date 05/10/05 12 ,35
Parameter
Methane
Chloride
Nitrate
Sulfate
Alkalinity
Ethane
Ethene
TOC (Total Organic Carbon)
Mercury
Arsenic
Barium
Cadmium
Chromium
Iron,Dissolved
Lead
Manganese
Selenium
Silver
Volatile Organics
Benzene
Bromobenzene
Bromochloromethane
Brornodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon Tetrachloride
Chlorobenzene
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #86
Result Det. Limit
BDL 1000
1900 1000
BDL 100
BDL 5000
23000 10000
BDL 1000
BDL 1000
BDL 1000
BDL 0 .20
BDL 20.
13. 5.0
BDL 5.0
BDL 10.
BDL 100
BDL 5.0
310 10.
BDL 20.
BDL 10.
BDL 1.0
BDL 1.0
BDL 1.0
BDL l. 0
BDL l. 0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
Det. Limit -Estimated Quantitation Limit(EQL)
12065 Lebanon Rd.
Mt. Juliet, TN 37122
(615) 758-585B
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 19,2005
ESC Sample #
Site ID
Project#
Units Method
ppb 8015M
ug/1 9056
ug/1 9056
ug/1 9056
ug/1 310.2
ppb 8015M
ppb 8015M
ug/1 9060
ug/1 7470A
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
Ll98587-09
2519
Date
05/11/05
05/11/05
05/11/05
05/11/05
05/18/05
05/11/05
05/11/05
05/13/05
05/16/05
05/12/05
05/12/05
05/12/05
05/12/05
05/12/05
05/12/05
05/12/05
05/12/05
05/12/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
Laboratory Certification Numbers:
C-TN-01
Oil.
l
l
l
1
l
l
1
l
1
l
1
1
1
l
1
1
l
1
l
1
l
1
1
l
1
l
1
l
l
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
00109, WV -233
Page 25 of so
ENVIRONMENTAL
SCI-ENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 11, 2005
Description NC State University
Sample ID MW-43D
Collected By J Ganey
Collection Date 05/10/05 12'35
Parameter
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-Chloropropane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
Di-isopropyl ether
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
p-Isopropyltoluene
Methylene chloride
Methyl tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #86
Result Det. Limit
BDL 1.0
BDL 1.0
2.1 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 5.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 5.0
BDL 5.0
BDL 5.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
Det. Limit -Estimated Quantitation Limit(EQL)
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 19,2005
Units
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ESC Sample#
Site ID
Project#
Method
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
Ll98587-09
2519
Date
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
Laboratory Certification Numbers:
AIHA -100789, AL -40660, CA -1-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Page 26 of SO
C-TN-01
00109, WV
I
I
I
I
I
I
Oil.
1 I l
l
l
l I l
l
l
l
ii
l
ii 1
l
ii
l
l
ii
l
l
ii
1
l
ii
l 11
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 11, 2005
Description NC State University
Sample ID MW-43D
Collected By J Ganey
Collection Date 05/10/05 12,35
Parameter
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Toluene
Vinyl chloride
Xylenes, Total
BDL -Below·Detection Limit
REPORT OF ANALYSIS
Lot #86
Result Det. Limit
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 5.0
BDL 1.0
BDL 3.0
Det. Limit -Estimated Quantitation Limit(EQL)
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax r.o. 62-0814289
Est. 1970
May 19,2005
ESC Sample#
Site ID
Project#
Units Method
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
Ll98587-09
2519
epre
Date
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
Laboratory Certification Numbers:
C-TN'-01
Oil.
1
1
1
1
1
1
1
AIHA -100789, AL -40660, CA -1-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA 00109, WV -233
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Note:
The reported analytical results relate only to the sample submitted.
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported: 05/19/05 13:02 Printed: 05/19/05 13:04
Page 27 of SO
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 11, 2005
Description NC State University
Sample ID MW-47
Collected By J Ganey
Collection Date 05/10/05 08,28
Parameter
Methane
Chloride
Nitrate
Sulfate
Alkalinity
Ethane
Ethene
TOC (Total Organic Carbon)
Mercury
Arsenic
Barium
Cadmium
Chromium
Iron,Dissolved
Lead
Manganese
Selenium
Silver
Volatile Organics
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon Tetrachloride
Chlorobenzene
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #86
Result Det. Limit
BDL 1000
1900 1000
BDL 100
BDL 5000
27000 10000
BDL 1000
BDL 1000
BDL 1000
BDL 0.20
BDL 20.
25. 5.0
BDL 5.0
BDL 10.
BDL 100
BDL 5.0
420 10.
BDL 20.
BDL 10.
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
Det. Limit -Estimated Quantitation Limit(EQL)
12065 Lebanon Rd.
Mt. Juliet, TN 37122
(615) 758-585B
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 19,2005
ESC Sample#
Site ID
Project#
Units Method
ppb 8015M
ug/1 9056
ug/1 9056
ug/1 9056
ug/1 310.2
ppb 8015M
ppb 8015M
ug/1 9060
ug/1 7470A
ug/1 6010B
ug/1 6010B
ug/1 60108
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 60108
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
L198587-10
2519
Date
05/11/05
05/11/05
05/11/05
05/11/05
05/18/05
05/11/05
05/11/05
05/13/05
05/16/05
05/12/05
05/12/05
05/12/05
05/12/05
05/12/05
05/12/05
05/12/05
05/12/05
05/12/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
Laboratory Certification Numbers:
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
. AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Page 28 of SO
C-TN-01
00109, WV
I
I
I
I
I
I
Oil.
1 I
1
1
1 I 1
1
1 I
1
1 I 1
1
ti
1
1
1 I 1
1
ti
1
1
1 I 1
1
1
1 I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 11, 2005
Description NC State University
Sample ID MW-47
Collected By J Ganey
Collection Date 05/10/05 08,28
Parameter
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-Chloropropane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
Di-isopropyl ether
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
p-Isopropyltoluene
Methylene chloride
Methyl tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #86
Result Det. Limit
BDL 1.0
BDL 1.0
l. l 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 5.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 5.0
BDL 5.0
BDL 5.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
Det. Limit -Estimated Quantitation Limit(EQL)
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 19,2005
ESC Sample#
Site ID
Project#
Units Method
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
Ll98587-10
2519
Date
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
Laboratory Certification Numbers:
C-TN·Ol
Dil.
l
1
l
l
1
l
1
l
l
l
l
1
l
l
l
l
1
l
l
l
l
l
l
l
l
1
l
l
1
l
1
l
1
l
l
l
1
1
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910 00109, WV -233
Page 29 of 50
ENVIRONMENTAL
SCIENCE CORP.
REPORT OF ANALYSIS
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5B59
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
Mr. John Harper
Piedmont Geologic
May 19,2005
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
ESC Sample# Ll98587-10
Date Received May 11, 2005
Description NC State University Lot #86
Site ID Sample ID MW-47
Collected By J Ganey
Project# 2519
Collection Date 05/10/05 08,28
Parameter Result Det. Limit Units Method
Trichlorofluoromethane BDL 1.0 ug/1 6230D
1,2,3-Trichloropropane BDL 1.0 ug/1 6230D 1,2,4-Trimethylbenzene BDL l.O ug/1 6230D
1,3,5-Trimethylbenzene BDL 1.0 ug/1 6230D Toluene BDL 5.0 ug/1 6230D
Vinyl chloride BDL 1.0 ug/1 6230D
Xylenes, Total BDL 3.0 ug/1 6230D
BDL -Below Detection Limit
Det. Limit -Estimated Quantitation Limit(EQL)
Laboratory Certification Numbers:
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Note:
The reported analytical results relate only to the sample submitted.
Date
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
C-TN-01
00109, WV
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported: 05/19/05 13:02 Printed: 05/19/05 13:04
Page 30 of so
I
I
I
I
I
I
Oil.
i I
1
1 ~·
I
I
I
I
I
I
I
I 233
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
0
D
ENVIRONMENTAL
SCIENCE CORP.
REPORT OF ANALYSIS
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
May 11, 2005 Date Received
Description NC State University Lot #86
Sample ID
Collected By
Collection Date
Parameter
Volatile Organics
Benzene
Bromobenzene
TRIP BLANK
J Ganey
05/10/05 00,00
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon Tetrachloride
Chlorobenzene
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-Chloropropane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
Di-isopropyl ether
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
p-Isopropyltoluene
Methylene chloride
BDL -Below Detection Limit
Result
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
Det. Limit -Estimated Quantitation Limit(EQL)
Det. Limit
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1. 0
1.0
1.0
1.0
1. 0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1. 0
1. 0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1. 0
1.0
5.0
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax (615} 758-5859
Tax I.D. 62-0814289
Est. 1970
May 19,2005
ESC Sample#
Site ID
Project#
Units Method
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
Ll98587-ll
2519
Date
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
Laboratory Certification Numbers:
C-TN-01
Dil.
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
00109, WV -233
Page 31 of 50
ENVIRONMENTAL
SCIENCE CORP.
REPORT OF ANALYSIS
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
l-B00-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
Mr. John Harper
Piedmont Geologic May 19,2005
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received
Description May 11, 2005
NC State University Lot #86
TRIP BLANK
ESC Sample# Ll98587-ll
Site ID Sample ID
Collected By
Collection Date
Project# 2519
J Ganey
05/10/05 00,00
Parameter Result Det. Limit Units Method
Methyl tert-butyl ether BDL 5.0 ug/1 6230D Naphthalene BDL 5.0 ug/1 6230D n-Propylbenzene BDL 1.0 ug/1 6230D Styrene BDL 1.0 ug/1 6230D 1,1,1,2-Tetrachloroethane BDL 1.0 ug/1 6230D 1,1,2,2-Tetrachloroethane BDL 1.0 ug/1 6230D Tetrachloroethene BDL 1.0 ug/1 6230D 1,2,3-Trichlorobenzene BDL 1.0 ug/1 6230D 1,2,4-Trichlorobenzene BDL 1.0 ug/1 6230D 1,1,1-Trichloroethane BDL 1.0 ug/1 6230D 1,1,2-Trichloroethane BDL 1.0 ug/1 6230D Trichloroethene BDL 1.0 ug/1 6230D Trichlorofluoromethane BDL 1.0 ug/1 6230D 1,2,3-Trichloropropane BDL 1.0 ug/1 6230D 1,2,4-Trimethylbenzene BDL 1. 0 ug/1 6230D 1,3,5-Trimethylbenzene BDL 1. 0 ug/1 6230D Toluene BDL 5.0 ug/1 6230D Vinyl chloride BDL 1.0 ug/1 6230D Xylenes, Total BDL 3.0 ug/1 6230D
BDL -Below Detection Limit
Det. Limit -Estimated Quantitation Limit{EQL)
Laboratory Certification Numbers:
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Note:
The reported analytical results relate only to the sample submitted.
Date
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
C-TN-01
00109, WV
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported: 05/19/05 13:02 Printed: 05/19/05 13:04
Page 32 of 50
I
I
I
I
I
I
Dil.
1 I 1
1
1
1 I 1
1
1
1
1 I 1
1
1
ii 1
1 11
I
I
I
I
I 233
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
ENVIRONMENTAL
SCIENCE CORP.
REPORT OF ANALYSIS
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
May 11, 2005 Date Received
Description NC State University Lot #86
Sample ID
Collected By
Collection Date
Parameter
Volatile Organics
Benzene
Bromobenzene
TRIP BLANK
J Ganey
05/10/05 00,00
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon Tetrachloride
Chlorobenzene
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-Chloropropane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
Di-isopropyl ether
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
p-Isopropyltoluene
Methylene chloride
BDL -Below Detection Limit
Result
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
Det. Limit -Estimated Quantitation Limit(EQL)
Det. Limit
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1. 0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
l-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 19,2005
ESC Sample#
Site ID
Project#
Units Method
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
Ll98587·12
2519
Date
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
05/16/05
Laboratory Certification Numbers:
C-TN-01
Dil.
1
l
1
1
l
1
1
l
1
1
l
l
l
1
1
l
1
l
1
1
1
l
l
l
l
1
l
l
1
1
1
1
l
l
l
l
1
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN· 2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910 00109, WV -233
Page 33 of 50
ENVIRONMENTAL
SCIENCE CORP.
REPORT OF ANALYSIS Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
May 11, 2005 Date Received
Description NC State University Lot #86
Sample ID
Collected By
Collection Date
Parameter
TRIP BLANK
J Ganey
05/10/05 00,00
Methyl tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Toluene
Vinyl chloride
Xylenes, Total
BDL -Below Detection Limit
Result
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
Det. Limit -Estimated Quantitation Limit(EQL)
Det. Limit
5.0
5.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
3.0
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 19,2005
ESC Sample # L198587-12
Site ID
Project # 2519
Units Method Date
ug/1 6230D 05/16/05
ug/1 6230D 05/16/05
ug/1 6230D 05/16/05
ug/1 6230D 05/16/05
ug/1 6230D 05/16/05
ug/1 6230D 05/16/05
ug/1 6230D 05/16/05
ug/1 6230D 05/16/05
ug/1 6230D 05/16/05
ug/1 6230D 05/16/05
ug/1 6230D 05/16/05
ug/1 6230D 05/16/05
ug/1 6230D 05/16/05
ug/1 6230D 05/16/05
ug/1 6230D 05/16/05
ug/1 6230D 05/16/05
ug/1 6230D 05/16/05
ug/1 6230D 05/16/05
ug/1 6230D 05/16/05
Laboratory Certification Numbers:
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN C-TN-01
KY· 90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA 00109, WV
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Note:
The reported analytical results relate only to the sample submitted.
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported: 05/19/05 13:02 Printed: 05/19/05 13:04
Page 34 of so
I
I
I
I
I
I
Dil.
1
1 I 1
1
1
1
1 I
1
1
1
1
1 I
1
1
1
1
1 I
1
1 I
I
I
I
I
I 233
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
t)
Sample#
Ll98587-05
Ll98587-10
Attachment A
List of Analytes with QC Qualifiers
Analyte
Chloroform
Sil Ver
Qualifier
E
J6J3
Page 35 of 50
Qualifier
E
J3
J6
Attachment B
Explanation of QC Qualifier Codes
Meaning
GTL (EPA) -Greater than upper calibration limit: Actual value is known to
be greater than the upper calibration range.
The associated batch QC was outside the established quality control range
for precision.
The sample matrix interfered with the ability to make any accurate
determination; spike value is low
Qualifier Report Information
ESC utilizes sample and result qualifiers as set forth by the EPA Contract Laboratory Program and
as required by most certifying bodies including NELAC. In addition to the EPA qualifiers adopted
by ESC, we have implemented ESC qualifiers to provide more information pertaining to our analytical
results. Each qualifier is designated in the qualifier explanation as either EPA or ESC. ·
Data qualifiers are intended to provide the ESC client with more detailed information concerning
the potential bias of reported data. Because of the wide range of constituents and variety of
matrices incorporated by most EPA methods.it is common for some compounds to fall outside of
established ranges. These exceptions are evaluated and all reported data is valid and useable
unless qualified as 'R' (Rejected).
Definitions
Accuracy -The relationship of the observed value of a known sample to the
Precision
true value of a known sample. Represented by percent recovery and
relevant to samples such as: control samples, matrix spike recoveries,
surrogate recoveries, etc.
The agreement between a set of samples or between duplicate samples.
Relates to how close together the results are and is represented by
Relative Percent Differrence.
Surrogate -Organic compounds that are similar in chemical composition, extraction,
and chromatography to analytes of interest. The surrogates are used to
determine the probable response of the group of analytes that are chem-
ically related to the surrogate compound. Surrogates are added to the
sample and carried through all stages of preparation and analyses.
2-Fluorophenol
Phenol-dS
2,4,6-Tribromophenol
31-119
12-134
51-141
Control Limits (AQ)
Nitrobenzene-dS 43-118 Dibromfluoromethane 70-130
2-Fluorobiphenyl 45-128 Toluene-dB 70-130
Terphenyl-dl4 43-137 4-Bromofluorobenzene 70-130
TIC -Tentatively Identified Compound: Compounds detected in samples that are
not target compounds, internal standards, system monitoring compounds,
or surrogates.
(SS)
70-130
70-130
70-130
Page 36 of 50
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
J
I
I ENVIRONMENTAL
SCIENCE CORP.
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
I Piedmont Geologic
Mr. John Harper
Tax I.D. 62-0814289
Est. 1970
6003 Chapel Hill Road Suite 109 I Raleigh, NC 27607
Quality Assurance Report
Level II
Ll98587
May 19, 2005
\{'.~-/~P9.!~f¢:ff?_~lahk?/
Result Uni ts Date Anal zed Batch
.. . ... . .. . ................... :\ :•</(02 :: ··• ....... )mgll•> ?:05/l.2/0.5 •12,02: :)?WG201596?
< .005 mg/1 05/12/05 12,02 WG201596
< .005 mg/1 05/12/05 12,02 WG201596
?tt• • :•t?[<. \C:otf) •)tt•t\:)mg/T It•>t•o5/T2/05 :12 io2 /{)\WG2Q:1:.5.96):\ ••••·· < .005 ······m9 /1··········· os/l.2/cis 12,02 wG201596
< .01 mg/1 05/12/05 12,02 WG201596 ·.... ·•• • < •)02i ••·· :c:•: :}.rng/1 : /{}05/12/.05 •12 .. ,.02::)•: C::WG.2.0159.6.:/ •••·
< · .oi mg/1 05/12/05 12,02 WG201596
< 1 mg/1 05/11/05 20,57 WG201640 ?L\:t•<·:•r/< r,tJt:::: ::c::::: :v:::•ttrng/1·/r xt:o5/H/o5 ·•20•,·57\ \:::c::wG2or64o>••···
< 5 mg/1 ·· ·05/11/os 20, 57 WG201640
1
< I 1,f1frf2\Tefrachrori::ietllari¢}•::c•: ·····•·····•·•·••·······••:" y:oor('f :c:;c::: •:::m9zr •: :\::::05/i.5/05•· 1:ox.5.3: \iwG2021s5t 1, 1, 1-Trichloroethane < • 001 mg/1 .. ... 05/15/05 10 's:i ... WG2D2is5
1,1,2,2-Tetrachloroethane < .001 . mg/1 05/15/05 10,53 WG202185 I [Egf ~~~~~~H~:~t'ri". y·. . ... , ~ !Ht) +~~1 (g·;·~·t!igi ·H:ii. t ~!H~~!ir ::c>·
:f;s;~~:ittrn~t~i~~;~~!;;;;f :c {•\ ?:.::••in: :•::::::::cj••···••:§§t·:•:;c ··••:•:••:c:c::••::c+~n·•••\ ·:g.~1f~jg.~ ·•·1zi:~~ ·······:•rt•:•:g§gtf·:·~•:••··••:·•·•·•·•·······
11!~::~~H!;t~~f~~;!:~:· :1 :gg}>" +:j~ / g!~~!~g!. H:!ii <~g~g~t!!r:·•·•·•
1,2-Dibromo-3-Chloropropane < .002 mg/1 05/15/05 10,53 WG202185
1 ·t;i~~li~ti~Ii!~~i~;:~: } '. ) .. · .... · ( I•······;~•~·t ?.·.·· :};~~l)iI•••·•···i!il!}~!··• .. t~•:J.·Ii•••· ?•~ii~~[;i(::•:·:·•·•·•·•······.
1,3-Dichlorobenzene < .001 ... mg/1 05/15/05 10,53 WG20218.S
l, 3-Dichloropropane < .001 mg/1 • ••••••05/1.5/05 10 ,53 WG202185 I rs:§t6~i~i~~~6i:~:r j>ggf < :1i < gg1/t~j§g· t§i~r c:g~.gH:·g\
2-Chlorotoluene < . 001 mg/1 05/15/05 10, 53 WG202185
4:Cch16ro.to1u·enet•:••····· • ••::.,?<0.0:1·:•·• ••?•• •••fmg/r ::• >o5/1s/05·· •10.,53 · ••twG2021a5r··
I iii;i~~16;:6!etharie i •· : :Ht + /;i~} :: •r::g!i.t!•~.g! .. :HiU ····r ~g~gi~!! t•······
Broiiiodichloromethane· ... ·.:,· .cfiff mg/1 05/15/05 10, 53 WG202185
Bromoform < .001 mg/1 05/15/05 10,53 WG202185 ·1 ~~~~~~.,~~~~!;;~itilJ! " '' •: :ggft <;::~~r •g~}t~}g§ ·:•tg;~~ :g~g~f~t/·.
Chlorobenzene < .001 mg/1 05/15/05 10,53 WG202185
Ch-l"Oi6dib'i'OiiiOiriethariet·· ~> /.0.9.f:)./:',,,•• /(ri:tg/1\:::" :,•:<\}QS/15/0? ;T0'{53· :}\\)~q~_,C)JtE(~\) Chloroetharie ......... ··• . < .001 mg/1 05/15/05 fo;53 WG202185 I Chloroform < . 005 mg/1 05/15/05 10, 53 WG202185
Page 37 of so
I
I'
ENVIRONMENTAL
SCIENCE CORP.
Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Analyte
Quality Assurance Report
Level II
Ll98587
)La_bOt£t.tOiYJ:.!318tj~// Result.· ·· ··· "t:Jnfts .... D2lte Analyzed
Page 38 of so
12065 Lebanon Rd.
Mt, Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 19, 2005
Batch
I
I
I
I
······•····<\I
:••:·•·:.•,{'1
:•:.:::::•: :,:,{:,,,,.:t I
<1
I
I
I
I ENVIRONMENTAL
SCIENCE CORP.
I Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road
I Raleigh, NC 27607
Dichlorodifluoromethane
IAnalyte
I AlkEllfiiity:::::::,:,:::::::···
Analyte
I
I Ethene
I
Suite 109 Quality Assurance
Level II
Ll98587
< .001 mg/1
Report
05/16/05 04,24
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
l-B00-767-5859
Fax {615) 758-5859
Tax I.D. 62-0814289
Est. 1970
May 19, 2005
WG202202
'.J:P~.;>.9t:~.~-9#Y/J~J':~tjK// Result. Units Date Analyzed Batch
·:mg/L: ?23•:o··•. > ?23,oC:· · .. ··.··;,o;oo···· x20:·· .· .··.· Ll9BSB7'09 \WG202660
·<Labci"t"at_O:iY\Coriti_Ol "'""Saffiple·,·
Units Known Val Result % Rec Limit Batch
1000 910. 91.0 67-113 WG201626
Page 39 of 50
ENVIRONMENTAL
SCIENCE CORP.
Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Quality Assurance Report
Level II
Ll98587
Metharie<••·•·••···. · · ··•·•·•·••··•·•·••··••·•·•···•·••·•·······•··•··················••·•······•••·•·••·•····••·•·•···•·••···•·r?••·•·•:ppm •••··•·••••••...:(10·0·0 •••:::•••••••··••:::x.100.0••••••
Analyte /C::1.i:~.9¢##.~:.9tY:.C:..G9P(¢01 /$~iriPl:¢\J: Units Known Val Result
20 17.5
Page 40 of so
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 19, 2005
I
I
I
I
•••100./••· ••:::c:+s6~121 ••:::c:wG201626•: ••c·•·
% Rec Limit Batch
I
I
I ENVIRONMENTAL
SCIENCE CORP.
I Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109 I Raleigh, NC 27607
Tetrachloroethene
Analyte
Quality Assurance Report
Level II
Ll98587
m /1 .02 0.0163
Page 41 of so
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 19, 2005
81. 3 63-134 WG202185
% Rec Limit Batch
ENVIRONMENTAL
SCIENCE CORP.
Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Trichloroethene
Analyte
Quality Assurance Report
Level II
Ll98587
m /1 .02 0.0195
:.::\~fil:i~ff:a;t:C>.ti:L.~Orit'iOl/ $~tjipl:¢):
Units Known Va1 Result
Trichlorafluoromiithariii••·• r•·•· ••·•····•··•.•···•·r•·•·•••••·•••••• t fing/1·. •••·tc •. \c•o•2•••t+· •·• t•··•·•••·•t•·•\ofo;io•3•t>• Vl"Ilyi Chi"Oifae· -------------.. ...... mg/1 . 02 o. 0190
Xylenes, Total mg/1 .06 0.0540 ~=;;:8{i':Y)';I;'='=':'
Alkaliriit
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 19, 2005
97.5 74-120 WG202202
% Rec Limit Batch
Anal te i('.·4?.D?ti:i~(?.fy/qtjtj~fO :)/{S~ritP;I.;Ef ::pµpfi¢.~{~ -,-:, Units LCSD Res Ref Res RPO Limit %Rec Batch
Are=ienrc=:::::: .-. =·· ·-Bar1 um-····
Cadmium
_Ch:iOriliUi'fi:(: Leii'd ____________ _
Mangane_9:e_ selenium:?::=::::/·· Siiver· ......
Ethene ~¢.1::.h~fi¢t·
Chloride Nit'rater.t,·:·
Sulf,ite ..
mg/1 17.6 17.6
..... •t[ng/1 ••• \3}75//•· • 73;75
··· mg/1 17.4 17.5
TOC (Total Organic; Carbon) tn9/l_
1f6~Y ti:;::~::1'i ::::g:;~~:~:fi~ ··c"a'rb°O·~·J·· .......... · ....... --:-:-:-:•:•:-:=··:'.:':'·'·':':'='·=='=':';g7:(·',=··•:---
3.47 3.58
3.50 3. 94
0.276 20 87.9 WG201640
·····•o)Tl6 •• 20 •••• \93>.T· .··•· WG20.164o·•
0.494 20 87.2 WG201640
3.29
11.9
20
20
86.7
98.6
I:I:Eftit~r6~g!t~t~t"ri" •... ·.····•·•·····.··• •7 ~g;r ·•···•·•······g:g~la • t:gi~r ··•···•~>~is•·• /n•· .. '~~:~ .· ·:g~g~t:·~r··
1,1,2,2-Tetrachloroethane mg/1 0.0188 0.0182 2.85 16 93.8 WG202185
l/1Y2c.Trichl6roethane • /.•/mg/1/ • •o.Jo.175 • /0/01.65} •••· 5 .19• •· 16•• ·••)87)4 • \• •wG20218S(· l, 1-D·ichloro·ethane · mg/1 o. 0211 o. 0205 i. 99. 2i· 105. WG202185
1,1-Dichloroethene mg/1 0.0209 0.0207 0.901 17 104. WG202185
1/l"Dic:hlofoproperie /•)•······· .. •\mg/1 tt•t{ofo.1.8.8} •• //0\.O.:P.71 /5i82// /17 ·······•94}1/ //WG2021.85// 1,2;3~Trichlorobeiizene .... mg/1 0.0220 0.0225 i:20 19 . iio.·· wd202iss·
1, 2, 3-Trichloropropane mg/1 0. 0213 0. 0197 7. 83 18 107. WG202185
I
I
I
I
l\2}4cTric:hloroberi.zen·e <•••· ....... ••••tmg/1 .· ••0i.0234 • ••(0t.0225) ()3\63. •//10/ •·•·· 58\4 •••••••<WG202185•/
ii··i·•~i!i~i~iii~~iiiiiij.;?P~.~·~·.·. ··••.·~li·l•·)•·•·•····· ·.ij.~.i.i~··· ·••••·••·~ i••li.~! ••••··••7i.il;·•I ·li· ···••••·••·•·••••ii~•;· ·•···•···.·•··•·••~iil•ilii·••••r•· ·.·.··•·r.•·•·••••··•••t•I
1,2-Dichloropropane mg/1 0.0188 0.0179 4.78 18 93.8 WG202185
1/3/5/Trimethylherizene ••• • ···••····•··•<•• •·•···••••••••·•·•••mg/1 ••···•o.:>01.6.s •.t+o.xo159• ...... 3.0.7.o ••• /n. ••·t•••••t82\.?>• •x wG20218s tt.•t··•••••••••·•·· 1,3-Dichlorobenzene mg/1 0.0179 0.0177 1.27 17 44.8 WG202185
1,3-Dichloropropane mg/1 0.0183 0.0174 5.12 11 91.5 WG202185 f;}:gt·~~rn~~i~~;:~! t . , %%~Ji •· ·•··grg~~f >tg·:g~g~> ii:}~/ Y~}i •t~·~:• :g~g~f~tr··•········.
2-Chlorotoluene mg/1 0.0169 0.0164 3.41 26 84.7 WG202185 I
Page 42 of so
I
I
I ENVIRONMENTAL
SCIENCE CORP.
I Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109 I Raleigh, NC 27607
A\"chl0i6t:Ohierie<ft<·>····.
Lalyte
Quality Assurance Report
Level II
Ll98587
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5B59
Fax (615) 75B-5859
Tax I.D. 62-0814289
Est. 1970
May 19, 2005
?\:iiig/l ,i/'o,·0113/:: :0::0159 \?2,66 //:u. t):(s6,'6 <?:/:.wa2021ssc/:,,,, .....
}}~¢l:~¢l~~:qxYt,<:.9.fl.~f9~\:'Sei.XnP.r~ :H?.~PJA¢~-~-~>< . units LCSD Res Ref Res RPO Limit %Rec Batch
Page 43 of 50
ENVIRONMENTAL
SCIENCE CORP.
Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Bromochloromethane
Analyte
Mercury K:i:~:~TI~~I'~:9;:,:=::::,,:,:,:,
Analyte
f\#.'8.~PJ:¢: .... Barium
Cadmium
£-~~grtji\l.rii)!?
Manganese
Se"le'iiiUffi''' Sitve·r
c:;hlijrj_de/·
Nitrate
Sulfate
Quality Assurance Report
Level II
Ll98587
m /1 0.0234 0.0229 1. 93 17
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-08142B9
Est. 1970
May 19, 2005
117. WG202202
:;J·P.~}J.Qr?.t?:t.Y,\q§ti.tt.<?._:t:::,:S{t~P.E~ :;:p4·p_~J_¢~t~L':' .. Units LCSD Res Ref Res RPO Limit %Rec Batch
mg/1 0.0028 0.0028 2.82 20 96.0 WG202275
-:,,,,,,,=_ME(ti}~)'.$P~.lc~)Y
Units MS Res Ref Res TV % Rec Limit Ref Samp Batch
I
I
I
I
··•.· ;;ir :!:F ligg 1:x tH: H!Uf HHHfH ~g~HHI
ellitff;itt\••· ···•<·•·<•········•·r•·········•·){··•·· >••··•······••t•••t•t•••>r·•···••····· t·.···•·•gt)i1 <g3••c1 / ··••+••······ ~'.tgI )•·.•gi·· ··ti~'.f •Jg)f]l•···· titJgi9i!81 wdi8it!iii
~M~:~: ·•·•·•·•·•·••··· ··· ;:;~;t< 4t:}1 . \g:6~g . Jo.•·· I~:~· :g:t~g> •.. ti::.~:~ig} :~~gt~ll
WG201759
Page 44 of 50
I
I
I ENVIRONMENTAL
SCIENCE CORP.
I Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road I Raleigh, NC 27607
Lalyte
I
Suite 109 Quality Assurance Report
Level II
Ll98587
Units t\:_r-1:_~tt:~~\~Pt~~/\ MS Res Ref Res TV
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax (615} 758-5859
Tax I.D. 62-0814289
Est. 1970
May 19, 2005
% Rec Limit Ref Samp Batch
ENVIRONMENTAL
SCIENCE CORP.
Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
1,1,1,2-Tetrachloroethane
Analyte
Quality Assurance Report
Level II
L198587
mg/1 0.0181 0.0000 .02
Units
::::·:'::·Ma tiIX\$Pt_J{~}/ MS''•"•Re·s·.. Ref Res TV
Page 46 of SO
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-B00-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 19, 2005
90.5 57-133 L198654-02
% Rec Limit Ref Samp
I
I
I
I
I
I
I
I ENVIRONMENTAL
SCIENCE CORP.
I Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109 I Raleigh, NC 27607
Analyte
li~ttl9:r:n:::::::-,-,-·
Cadmium Chi6ffii Uiri)t\,:,:
l:~irir~ti<••••·· ·s11ver··· ····
l~tf·gt~:f_e\Jf?'
Sulfate
Quality Assurance Report
Level II
Ll98587
Units MSD Res Ref Res RPD
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
l-B00-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 19, 2005
Limit %Rec Ref Samp Batch
.. • fug/L )(50}9} )53\5(:: 1\.8.7. {20•• } •9s{o• {l,198587/09 WG201.622
.... ing/1. 4. 96 5. 22 4. 93 20 99. 3 .. Ll98587~09 WG2016i2
mg/1 50.8 53.3 4.90 20 102. Ll98587-09 WG201622
lt~!~~i~r ..... ·····•·•··•·•··•·••·•••···•···•·······•··•····<•••·•~~Ji •..•• ••••·il:I•·••<r··• X[•B>tr·•·••····• •·•••·•·•••• I:t·r• ••·•··>;g·•···••··· ••··?Ii!i• •·•·<•··t1g~Ig1laf jJ~B1~IO
sulfate\ ·••••••<•••••·•·•? •tfu§ji . >••4i•:!:•· ·><4~:.~ .. 0 <•••~•::·~ Ut••••~g ••·• n:t:~. •rtt;:~.:;.cg~··• .~.~~•g•i~!.g
1.04 1.05 0.576 20 104. Ll98587-10 WG201759
Page 47 of 50
ENVIRONMENTAL
SCIENCE CORP.
Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
!benzene
Analyte
Quality Assurance Report
Level II
L198587
m /1 0.0174 0.0179 2. 72
rr:11a~r:tX.?EiI.filt.¢tpup_r~¢~t:fX\ Units MSD Res Ref Res RPO
Page 48 of 50
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 19, 2005
I
I
I
I
26 87.0 L198587-10 WG202185
Limit %Rec Ref Samp Batch
I
I
I ENVIRONMENTAL
SCIENCE CORP.
I Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109 I Raleigh, NC 27607
n-Butylbenzene
Mercury
Quality Assurance Report
Level II
L198587
mg/1 0.0150 0.0159 5. 71
;;·;IM*tt~:~\~Pi~¢?P4P~·~¢.il.t:¢\:/ Units MSD Res Ref Res RPO
mg/1 0.0031 0.0029 6.56
I Batch number /Run number/ Sample number cross reference
I
I
I
I
I
I
I
WG201626,
WG201596,
WG201640,
WG201622,
WG201769,
WG201770,
WG201759,
WG202185,
WG202202,
WG202275,
WG202660,
R232821, L198587-01 02 03 04
R232972 R232973, L198587-02
R233021, L198587-03 05 08
R233023, L198587-01 02 04 06
R233096, L198587-01 02
R233097, L198587-03 04 05 06 R233123, L198587-01 02 03 04
R233361, L198587-01 02 03 04
R233362, L198587-11 12
R233488, L198587-01 02 03 04
R233808, L198587-01 02 03 04
05 06 07 08 09 10
03 04 05 06 07 08 09 10 01
07 09 10
07 08 09 10
05 06 07 08 09 10
05 06 07 08 09 10
05 06 07 08 09 10
05 06 07 08 09 10
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 19, 2005
27 74.9 L198654-02 WG202202
Limit %Rec Ref Samp Batch
20 105. L198650-01 WG202275
I
* denotes out of limit range result. See Attachment B of standard report for list of qualifiers.
**Calculations are performed prior to rounding of reported values
Page 49 of 50
I
ENVIRONMENTAL
SCIENCE CORP.
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax {615) 758-5859
Tax I.D. 62-0814289
Est. 1970 Piedmont Geologic
Mr. John Harper
_60_03 Chapel Hill Road Suite 109 Quality Assurance Report
Level II ... ~ 4 • • 1~.a•le1gh, NC 27607 May 19, 2005
Ll98587
ESC Level 2 Data Package
The data package includes a summary of the analytic results of the quality
control samples required by the SW-846 or CWA methods. The quality control
samples include a method blank, a laboratory control sample, and the matrix
spike/matrix spike duplicate analysis. If a target parameter is outside
the method limits, every sample that is effected is flagged with the
appropriate qualifier in Appendix B of the analytic report.
Method Blank -an aliquot of reagent water carried through the
entire analytic process. The method blank results indicate if
any possible contamination exposure during the sample handling,
digestion or extraction process, and analysis. Concentrations of
target analytes above the reporting limit in the method blank are
qualified with the "B 11 qualifier.
Laboratory Control Sample -is a sample of known concentration
that is carried through the digestion/extraction and analysis
process. The percent recovery, expressed as a percentage of the
theoretical concentration, has statistical control limits
indicating that the analytic process is "in control". If a
target analyte is outside the control limits for the laboratory
control sample or any other control sample, the parameter is
flagged with a 11 J4" qualifier for all effected samples.
Matrix Spike and Matrix Spike Duplicate -is two aliquots of an
environmental sample that is spiked with known concentrations of
target analytes. The percent recovery of the target analytes
also has statistical control limits. If any recoveries that are
outside the method control limits, the sample that was selected
for matrix spike/matrix spike duplicate analysis is flagged with
either a "JS11 or a 11 J6". The relative percent difference (%RPO)
between the matrix spike and the matrix spike duplicate
recoveries is all calculated. If the RPO is above the method
limit, the effected samples are flagged with a "J3" qualifier.
Page so of so
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
----Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh,NC 27607
---

-
--Alternate billing information: -

-
-

-
Analvsts/l onta1ner/Preservat1ve -
Prepared by:
-

-
Chain of Custo9'y Pagept-Yf:1
I ~
• ENVIRONMENTAL
SCIENCE CORP.
12065 Lebanon Road
Mt. Juliet, TN 37122
Phone [phone]
FAX [phone]
-
,,.,. 11, l) Gw 1053 101,-~:ie'I x :xi, x rxt x ~~j x ,,:,<if'.,.: '81c:
mw -;;n GW l'i'f'f 10 [X.\il x I~~: x .f.Xi x IX,;, x ,.,,,,,c;,~, 1•-fi,i.
mw-3'1M GW 0100 10 rx:~1 X l•Xf'\ X (~:lj X IX't: X ·~~? "'• :.
t-----'-l'll~W"'--'-"-l/o~~---+------+--+-G-W--+--,--+-t----+-',':--'40=..,oc_+--1 o---t•'::;X-:;;/1;.;-_ :c:X+i?XCC· :"cit; --:X::--ii--':,X'-f,jst', ~x;-ijw';'-:x"'~;tcX;-;-t------t~c'5 ;, ·""i
m-., -'{/1\ GW IIJ:t IO lX'-i X iX.i'l!i X i:Xi~ X 1:X~" X ~ ,)i~;
m,.,-1./Ji) i/ GW ·" , i~¾" 10 tX'l X ~X:i~I X 1'•X.-i'! X 1ixnx ,,!!.•(''~'
*Matrix: SS -Soil GW • Groundwater WW -Wastewater OW -Drinking Water OT -Other ___ _
Remark" Quote#PIEGEO032405S
Relinquished by: (Signature)
::::1-.-.=-.A
elin 1shed ~,¢, .. (S~{'atiur8 • l'°•t~,· l·~ll"·,.~~,., ,, .¾;: ~ ,~·
elinqu1shed ·~(siQ.n8f re)
-'>
pH ______ _
Flow ------
amples retume vra: -t<;:ondi ·
D FedEx □Courier :t·?'._
~Temp:P:1,: (!J}f;,t:'-~. ~Botlles1Received: ·, 'z{:wiJ;::wft_ 1t:f5.rr.~t1fi.:
Temp
Other
~#.iZiJ/~10.:~:tt_ii ~~:-~--~2,";~;'iI ~0,t<;.,:.
'
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh,NC 27607
Sample ID Comp/Grab
,,,,.,-'17
Alternate billing information: Ana1vs1s/c onta1ner/Preservat1ve
Matrix• Depth
GW
Prepared by:
Chain oJ yustoJ)
Page)1ot-KJ
;;I. J.
• ENVIRONMENT AL
SCIENCE CORP.
12065 Lebanon Road
Mt. Juliet, TN 37122
Phone [phone]
FAX [phone]
GW
GW
1 o :!Xi~ X ;~ill X ~i X ;i~J X · · .~ R\,, .__ , 1~1ili\1 i):'(i .:11•: '.._-f---+---f---+~1~0--#!;_x;,~~l~X~~~x~_. "'~.~~x;..--J·~;;.x~. ·"'!!\:f..:x~t'!,.~x,_~'1li~( ~x;..--i..,,.,"",;u:,_~,m!!M~.t..-,f.li~~ ,; \:' ;;
10 1~~ x cx,!,l x 12:X~! x ~•x~ x · , ~ GW
GW
GW
GW
GW
GW
1 o H~; X l".{'(li X ii'.~!~ X
1 o ::x•t x t~l!il x ~x~1 x i;:X] X
·~~~~ X ,sx,]1/ X ;:X~ X
txir x liX'f~ x :,xJ,'1 x
IO ~~~t,J X ;l~~ X ll~i
10 ~Xf X
10 l?.X~ X
X r~!i X
-
*Matrix: SS -Soil GW -Groundwater WW -Wastewater OW -Drinking Water OT -Other ___ _ pH _______ Temp
Remarks, Quote#PIEGEO032405S Flow _____ _ Other
Relinquished by: (Signature) Date: Time: p es retume via:
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
• ENVIRONMENTAL SCIENCE CORP.
Cooler Receipt Form
Client: ---'--------'p--'-'=-r------'t~. ·-=c'---=b"-.o_·-__________ _
Cooler Received On: !:'-1 /-i, 5 and Opened On: .S-/ /-o $ By: ja's-,::-n S&·
l. Temperature of cool.er when opened: 2 · ~
(Sign:?=~
Degrees Celsius
2. Were custody seals on outside of cooler and intact? YES NO
a. If yes, what kind and where:----------------~
b, Were the signature and date correct?
3. Were custody seals on containers intact?
Were custody papers inside cooler?
Were custody papers properly filled out (ink, signed, etc.)
YES
YES
:§,Q
~
4.
5.
6.
7.
8.
9.
10.
Did you sign the custody papers in the appropriate place? ~
What icind of packing material was used? ~eanuts Other
Was sufficient ice used (if appropriate)?
Did all bottles arrive in good condition?
Were all bottle labels complete?(#, date, signed, pres, etc)?
11. Did all bottle labels and tags agree with custody papers?
12. Were correct bottles used for the analyses requested?
13. If applicable, was an observable VOA headspace present?
14. Was sufficient amount of sample sent in each bottle?
I 5. Were correct preservatives used?
16. Corrective action taken, if necessary:
Q s
~
~
YES
~. (3/
a. Name of person contacted: See attached for resolution if needed
b. Date: _______ _
NO
NO
NO
NO
NO
None
NO
NO
NO
NO
NO
NO
NO
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 12, 2005
Description NC State University
Sample ID MW-111
Collected By J. Ganey
Collection Date 05/11/05 12: 33
Parameter
Methane
Chloride
Nitrate
Sulfate
Alkalinity
Ethane
Ethene
TOC (Total Organic Carbon)
Mercury
Arsenic
Barium
Cadmium
Chromium
Iron,Dissolved
Lead
Manganese
Selenium
Silver
Volatile Organics
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon Tetrachloride
Chlorobenzene
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #86
Result Det. Limit
BDL 1000
7500 1000
BDL 100
BDL 5000
78000 10000
BDL 1000
BDL 1000
6800 1000
BDL 0 .20
37. 20.
120 5.0
BDL 5.0
BDL 10.
3200 100
BDL 5.0
3700 10.
25. 20.
BDL 10.
BDL 1.0
BDL 1. 0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
Det. Limit -Estimated Quantitation Limit(EQL)
12065 Lebanon Rd.
Mt. Juliet, TN 37122
(615) 758-585B
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 22,2005
ESC Sample#
Site ID
Project#
Units Method
ppb 8015M
ug/1 9056
ug/1 9056
ug/1 9056
ug/1 310.2
ppb 8015M
ppb 8015M
ug/1 9060
ug/1 7470A
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 60108
ug/1 6010B
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
L198803-0l
2519
Date
05/13/05
05/12/05
05/12/05
05/12/05
05/18/05
05/13/05
05/13/05
05/17/05
05/16/05
05/15/05
05/15/05
05/15/05
05/15/05
05/14/05
05/15/05
05/15/05
05/15/05
05/15/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
Laboratory Certification Numbers:
C-TN-01
Oil.
1
1
1
1
1
l
1
1
1
1
l
1
1
1
l
1
1
1
1
1
1
1
1
1
1
l
1
l
l
. AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910 00109, WV -233
Page 1 of 48
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 12, 2005
Description NC State University
Sample ID MW-111
Collected By J. Ganey
Collection Date 05/11/05 12,33
Parameter
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotolu'ene
1,2-Dibromo-3-Chloropropane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-0ichloroethane
1,1-0ichloroethene
cis-1,2-Dichloroethene
trans-1,2-0ichloroethene
1,2-Dichloropropane
1,3-0ichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
Di-isopropyl ether
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
p-Isopropyltoluene
Methylene chloride
Methyl tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #86
Result Det. Limit
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 5.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 5.0
BDL 5.0
BDL 5.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1. 0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
Det. Limit -Estimated Quantitation Limit(EQL)
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax {615) 756-5859
Tax I.D. 62-0814289
Est. 1970
May 22,2005
ESC Sample# L198803-01
Site ID
Project# 2519
Units
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
Method
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
62300
62300
6230D
6230D
6230D
6230D
62300
62300
6230D
6230D
6230D
6230D
6230D
6230D
62300
62300
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
Date
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
Laboratory Certification Numbers:
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Page 2 of 48
C-TN-01
00109, W
I
I
I
I
I
I
Oil.
1 I 1
1
1
1 I 1
1
1
1
1 I 1
1
1
1
1 I 1
1
1
ti 1
1
ti 1
1
ii
1
1
~I
1
1 I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 12, 2005
Description NC State University
Sample ID MW-llI
Collected By J. Ganey
Collection Date 05/11/05 12, 33
REPORT OF ANALYSIS
Lot #86
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax r.o. 62-0814289
Est. 1970
May 22,2005
ESC Sample# L198803-01
Site ID
Project# 2519
Parameter Result Det. Limit Units Method Date Oil.
Trichlorofluoromethane BDL 1.0 ug/1 1,2,3-Trichloropropane BDL 1.0 ug/1
1,2,4-Trimethylbenzene BDL 1.0 ug/1 1,3,5-Trimethylbenzene BDL 1.0 ug/1 Toluene BDL 5.0 ug/1 Vinyl chloride BDL 1.0 ug/1 Xylenes, Total BDL 3.0 ug/1
BDL -Below Detection Limit
Det. Limit -Estimated Quantitation Limit(EQL)
Laboratory Certification Numbe $:
6230D
6230D
6230D
6230D
6230D
6230D
6230D
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
Representative
-923, IN C-TN-01
1
1
1
1
1
1
1
AIHA
KY -90010,
-100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E~7487,
KYUST -0016,. NC -ENV375,DW21704, ND -R-140, SC -84' , TN
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -
-2006, VA 00109, WV -233
998093910 Note:
The reported analytical results relate only to the sample submitted.
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported: 05/22/05 08:43 Printed: 05/22/05 08:44 I Page 3 of 48
I
I.
ENVIRONMENTAL
SCIENCE CORP.
. Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 12, 2005
Description NC State University
Sample ID MW-12D
Collected By J. Ganey
Collection Date 05/11/05 11:23
REPORT OF ANALYSIS
Lot #86
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 22,2005
ESC Sample#
Site ID
Project#
L198803-02
2519
Parameter Result Det. Limit Units Method Date Dil.
Methane BDL 1000 ppb 8015M 05/13/05
Chloride 1900 1000 ug/1 9056 Nitrate BDL 100 ug/1 9056 Sulfate 7400 5000 ug/1 9056
05/12/05
05/12/05
05/12/05
Alkalinity 89000 10000 ug/1 310.2 05/18/05
Ethane BDL 1000 ppb 8015M 05/13/05
Ethene BDL 1000 ppb 8015M 05/13/05
TOC (Total Organic Carbon) BDL 1000 ug/1 9060 05/17/05
Mercury BDL 0.20 ug/1 7470A 05/16/05
Arsenic BDL 20. ug/1 6010B Barium 19. 5.0 ug/1 6010B
Cadmium BDL 5.0 ug/1 6010B Chromium BDL 10. ug/1 6010B Iron,Oissolved BDL 100 ug/1 6010B Lead BDL 5.0 ug/1 6010B
05/15/05
05/15/05
05/15/05
05/15/05
05/14/05
05/15/05 Manganese BDL 10. ug/1 6010B Selenium BDL 20. ug/1 60108
Silver BDL 10. ug/1 6010B
05/15/05
05/15/05
05/15/05
Volatile Organics
Benzene BDL 1.0 ug/1 6230D Bromobenzene BDL 1.0 ug/1 6230D Bromochloromethane BDL 1.0 ug/1 6230D Bromodichloromethane BDL 1.0 ug/1 6230D
Bromoform BDL 1.0 ug/1 6230D
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05 Bromomethane BDL 1.0 ug/1 6230D 05/18/05 n-Butylbenzene BDL 1.0 ug/1 6230D sec-Butylbenzene BDL 1.0 ug/1 6230D tert-Butylbenzene BDL 1.0 ug/1 6230D
Carbon Tetrachloride BDL 1.0 ug/1 6230D Chlorobenzene BDL 1.0 ug/1 6230D
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
BDL -Below Detection Limit
Det. Limit -Estimated Quantitation Limit{EQL)
Laboratory Certification Numbers:
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN -C-TN-01
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA -00109, Wv -
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Page 4 of 48
1
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 12, 2005 Description NC State University
Sample ID MW-12D
Collected By J. Ganey
Collection Date 05/11/05 11'23
Parameter
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-Chloropropane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
Di-isopropyl ether
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
p-Isopropyltoluene
Methylene chloride
Methyl tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #86
Result Det. Limit
BDL 1.0
BDL 1.0
180 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1. 0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 5.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 5.0
BDL 5.0
BDL 5.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1. 0
BDL 1.0
BDL 1.0
1.6 1.0
Det. Limit -Estimated Quantitation Limit(EQL)
12065 Lebanon Rd.
Mt. Juliet, TN 37122
{615) 758-5858
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 22,2005
ESC Sample#
Site ID
Project#
Units Method
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 62300
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
Ll98803-02
2519
Date
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
Laboratory Certification Numbers:
C-TN-01
Oil.
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910 00109, WV -233
Page S of 48
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 12, 2005
Description NC State University
Sample ID MW-120
Collected By J. Ganey
Collection Date 05/11/05 11,23
Parameter
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Toluene
Vinyl chloride
Xylenes, Total
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #86
Result Det. Limit
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 5.0
BDL 1.0
BDL 3.0
Det. Limit -Estimated Quantitation Limit(EQL)
Units
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
Laboratory Certification Numbe s:
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 22,2005
ESC Sample#
Site ID
Project#
Method
6230D
6230D
6230D
6230D
6230D
6230D
6230D
Ll98803-02
2519
Date
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
Representative
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -8 487,
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84v-,:4,--,,a
-923, IN C-TN-01
-2006, VA -00109, WV
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -
Note:
The reported analytical results relate only to the sample submitted.
998093910
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported: 05/22/05 08:43 Printed: 05/22/05 08:44
Page 6 of 48
I
I
I
I
I
I
Oil.
1 I 1
1
1
1 I 1
1
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
-12065 Lebanon Rd.
Mt. Juliet, TN 37122
ENVIRONMENTAL [phone]
1-800-767-5859
SCIENCE CORP. Fax [phone]
Tax I .D. 62-0814289
Est. 1970
REPORT OF ANALYSIS Mr. John Harper May 22,2005 Piedmont Geologic
6003 Chapel Hill Road Suite 109 Raleigh, NC 27607
ESC Sample # Ll98803-03 Date Received May 12, 2005
Description NC State University Lot #86
Site ID Sample ID MW-161
Project # 2519 Collected By J. Ganey
Collection Date 05/11/05 10,31
Parameter Result Det. Limit Units Method Date Oil.
Methane BDL 1000 ppb 8015M 05/13/05 1
Chloride 1800 1000 ug/1 9056 05/12/05 1 Nitrate BDL 100 ug/1 9056 05/12/05 1 Sulfate BDL 5000 ug/1 9056 05/12/05 1
Alkalinity 52000 10000 ug/1 310.2 05/18/05 1
Ethane BDL 1000 ppb 8015M 05/13/05 1
Ethene BDL 1000 ppb 8015M 05/13/05 1
TOC (Total Organic Carbon) BDL 1000 ug/1 9060 05/17/05 1
Mercury BDL 0 .20 ug/1 7470A 05/17/05 1
Arsenic BDL 20. ug/1 6010B 05/15/05 1 Barium 18. 5.0 ug/1 6010B 05/15/05 1 Cadmium BDL 5.0 ug/1 6010B 05/15/05 1 Chromium BDL 10. ug/1 6010B 05/15/05 1 Iron,Dissolved BDL 100 ug/1 6010B 05/14/05 1 Lead BDL 5.0 ug/1 6010B 05/15/05 1 Manganese 170 10. ug/1 6010B 05/15/05 1 Selenium BDL 20. ug/1 6010B 05/15/05 1 Silver BDL 10. ug/1 6010B 05/15/05 1
Volatile Organics
Benzene BDL 1.0 ug/1 6230D 05/18/05 1 Bromobenzene BDL 1.0 ug/1 6230D 05/18/05 1 Bromochloromethane BDL 1. 0 ug/1 6230D 05/18/05 1 Bromodichloromethane BDL 1.0 ug/1 6230D 05/18/05 1 Bromoform BDL 1.0 ug/1 6230D 05/18/05 1 Bromomethane BDL 1.0 ug/1 6230D 05/18/05 1 n-Butylbenzene BDL 1.0 ug/1 6230D 05/18/05 1 sec-Butylbenzene BDL 1.0 ug/1 6230D 05/18/05 1 tert-Butylbenzene BDL 1.0 ug/1 6230D 05/18/05 1 Carbon Tetrachloride BDL 1.0 ug/1 6230D 05/18/05 1 Chlorobenzene BDL 1.0 ug/1 6230D 05/18/05 1
BDL -Below Detection Limit
Det. Limit -Estimated Quantitation Limit(EQL)
Laboratory Certification Numbers:
C-TN-01 AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910 00109, WV -233
Page 7 of 48
I I
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 12, 2005 Description NC State University
Sample ID MW-161
Collected By J. Ganey
Collection Date 05/11/05 10,31
REPORT OF ANALYSIS
Lot #86
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5B59
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 22,2005
ESC Sample # L198803-03
Site ID
Project # 2519
I
I
I
I
I
I
Parameter Result Det. Limit Units Method Date Dil.
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
l,2-Dibromo-3-Chloropropane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
Di-isopropyl ether
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
p-Isopropyltoluene
Methylene chloride
Methyl tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
BDL -Below Detection Limit
BDL
BDL
390
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
11.
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
Det. Limit -Estimated Quantitation Limit{EQL)
1.0 ug/1
1.0 ug/1
1.0 ug/1
1.0 ug/1
1.0 ug/1
1.0 ug/1
1.0 ug/1
1.0 ug/1
1.0 ug/1
1.0 ug/1
1.0 ug/1
1.0 ug/1
1.0 ug/1
1. 0 ug/1
1. 0 ug/1
1.0 ug/1
1.0 ug/1
1.0 ug/1
1.0 ug/1
1.0 ug/1
5.0 ug/1
1.0 ug/1
1.0 ug/1
1.0 ug/1
1.0 ug/1
5.0 ug/1
5.0 ug/1
5.0 ug/1
1.0 ug/1
1.0 ug/1
1.0 ug/1
1.0 ug/1
1.0 ug/1
1.0 ug/1
1.0 ug/1
1.0 ug/1
1. 0 ug/1
1.0 ug/1
Laboratory Certification Numbers:
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Page a of 48
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
C-TN-01
00109, WV -
1 I 1
1
1
1 I 1
1
1
1
1 I 1
1
1
1
1 I 1
1
1
1 I 1
1
1
1
1 I 1
1
1
1
ti
1
1
1 I 1
1
1
1
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May
Description NC State
Sample ID MW-16I
Collected By J. Ganey
Collection Date 05/11/05
Parameter
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Toluene
Vinyl chloride
Xylenes, Total
BDL -Below Detection Limit
12, 2005
University
10,31
REPORT OF ANALYSIS
Lot #86
Result
BDL
BDL
BDL
BDL
BDL
BDL
BDL
Det. Limit
1.0
1.0
1.0
1.0
5.0
1.0
3.0
Det. Limit -Estimated Quantitation Limit(EQL)
Laboratory Certification
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197,
12065 Lebanon Rd.
Mt. Juliet, TN 37122
{615) 758-5858
1-800-767-5859
Fax [phone]
Tax r.o. 62-0814289
Est. 1970
May 22,2005
ESC Sample# L198803-03
Site ID
Project# 2519
Units
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
Method
6230D
6230D
6230D
6230D
6230D
6230D
6230D
Date
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
SC Representative
-923, IN -C-TN-01
Oil.
1
1
1
l
1
1
1
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84 04, -2006, VA 00109, WV -233 AZ -0612, MN -047-999-395, NY -11742, NJ -81002, 998093910 Note:
The reported analytical results relate only to the sample submitted.
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported: 05/22/05 08:43 Printed: 05/22/05 08:44 I Page 9 of 48
I
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 12, 2005
Description NC State University
Sample ID MW-34SR
Collected By J. Ganey
Collection Date 05/11/05 09:07
REPORT OF ANALYSIS
Lot #86
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 22,2005
ESC Sample#
Site ID
Project#
L198803-04
2519
Parameter Result Det. Limit Units Method Date Dil.
Methane BDL 1000 ppb 8015M
Chloride 4400 1000 ug/1 9056 Nitrate 380 100 ug/1 9056
Sulfate BDL 5000 ug/1 9056
Alkalinity 15000 10000 ug/1 310.2
Ethane BDL 1000 ppb 8015M
Ethene BDL 1000 ppb 8015M
TDC (Total Organic Carbon) BDL 1000 ug/1 9060
Mercury BDL 0.20 ug/1 7470A
Arsenic BDL 20. ug/1 6010B Barium 320 5.0 ug/1 6010B
Cadmium BDL 5.0 ug/1 6010B
Chromium BDL 10. ug/1 6010B Iron,Dissolved BDL 100 ug/1 6010B Lead BDL 5.0 ug/1 6010B Manganese 72. 10. ug/1 6010B
Selenium BDL 20. ug/1 6010B
Silver BDL 10. ug/1 6010B
Volatile Organics
Benzene BDL 1.0 ug/1 6230D
Bromobenzene BDL 1.0 ug/1 6230D Bromochloromethane BDL 1.0 ug/1 6230D
Bromodichloromethane BDL 1.0 ug/1 6230D Bromoform BDL 1.0 ug/1 6230D Brol"OC)methane BDL 1.0 ug/1 6230D n-Butylbenzene BDL 1.0 ug/1 6230D
sec-Butylbenzene BDL 1.0 ug/1 6230D tert-Butylbenzene BDL 1.0 ug/1 6230D
Carbon Tetrachloride BDL 1.0 ug/1 6230D Chlorobenzene BDL 1. 0 ug/1 6230D
BDL -Below Detection Limit
Det. Limit -Estimated Quantitation Limit{EQL)
Laboratory Certification Numbers:
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA -
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Page 10 of 48
05/13/05
05/12/05
05/12/05
05/12/05
05/18/05
05/13/05
05/13/05
05/17/05
05/17/05
05/15/05
05/15/05
05/15/05
05/15/05
05/14/05
05/15/05
05/15/05
05/15/05
05/15/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
C-TN-01
00109, WV -
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
u
I
I
I
I
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 12, 2005
Description NC State University
Sample ID MW-34SR
Collected By J. Ganey
Collection Date 05/11/05 09:07
Parameter
Chlorodibromomethane
Chlo roe thane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
l,2-Dibromo-3-Chloropropane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
Di-isopropyl ether
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
p-Isopropyltoluene
Methylene chloride
Methyl tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #86
Result Det. Limit
BDL 1.0
BDL 1.0
11. 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1. 0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1. 0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 5.0
BDL 1.0
BDL 1. 0
BDL 1.0
BDL 1.0
BDL 5.0
BDL 5.0
BDL 5.0
BDL 1.0
BDL 1.0
BDL 1. 0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1. 0
BDL 1.0
Det. Limit -Estimated Quantitation Limit(EQL)
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 22,2005
ESC Sample#
Site ID
Project#
Units Method
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 62300
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
Ll98803-04
2519
Date
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
Laboratory Certification Numbers:
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN C-TN-01
Oil.
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA 00109, WV -233
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Page 11 of 48
ENVIRONMENTAL
SCIENCE CORP.
REPORT OF ANALYSIS Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 12, 2005 Description NC State University Lot #86
Sample ID MW-34SR
Collected By ·J. Ganey
Collection Date 05/11/05 09:07
Parameter Result
Trichlorofluoromethane BDL 1,2,3-Trichloropropane BDL
1,2,4-Trimethylbenzene BDL 1,3,5-Trimethylbenzene BDL Toluene BDL
Vinyl chloride BDL
Xylenes, Total BDL
BDL -Below Detection Limit
Det. Limit -Estimated Quantitation Limit(EQL)
Det. Limit
1.0
1.0
1.0
1.0
5.0
1.0
3.0
Laboratory Certification
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197,
Units
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 22,2005
ESC Sample #
Site ID
Project#
Method
6230D
6230D
6230D
6230D
6230D
6230D
6230D
Ll98803-04
2519
Date
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
ESC Representative
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84 , TN -2006, VA
C-TN-01
00109, WV
AZ -0612, r,m -047-999-395, NY -11742, NJ -81002, WI -998093910
Note:
The reported analytical results relate only to the sample submitted.
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported: 05/22/05 08:43 Printed: 05/22/05 08:44
Page 12 of 48
I
I
I
I
I
I
Dil.
1 I 1
1
1
1 I 1
1
I
I
I
I
n
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
D
I
I
I
I
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 12, 2005
Description NC State University
Sample ID MW-61
Collected By J. Ganey
Collection Date 05/11/05 09,07
Parameter
Methane
Chloride
Nitrate
Sulfate
Alkalinity
Ethane
Ethene
TOC (Total Organic Carbon)
Mercury
Arsenic
Barium
Cadmium
Chromium
Iron,Dissolved
Lead
Manganese
Selenium
Silver
Volatile Organics
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon Tetrachloride
Chlorobenzene
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #86
Result Det. Limit
BDL 1000
4400 1000
370 100
BDL 5000
BDL 10000
BDL 1000
BDL 1000
7000 1000
BDL 0.20
BDL 20.
320 5.0
BDL 5.0
BDL 10.
BDL 100
BDL 5.0
70. 10.
BDL 20.
BDL 10.
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
Det. Limit -Estimated Quantitation Limit(EQL)
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0B14289
Est. 1970
May 22,2005
ESC Sample#
Site ID
Project#
Units Method
ppb 8015M
ug/1 9056
ug/1 9056
ug/1 9056
ug/1 310.2
ppb 8015M
ppb 8015M
ug/1 9060
ug/1 7470A
ug/1 6010B
ug/1 6010B
ug/1 60108
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
L198803-05
2519
Date
05/13/05
05/12/05
05/12/05
05/12/05
05/18/05
05/13/05
05/13/05
05/17/05
05/17/05
05/15/05
05/15/05
05/15/05
05/15/05
05/14/05
05/15/05
05/15/05
05/15/05
05/15/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
Laboratory Certification Numbers:
C-TN-01
Dil.
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910 00109, WV -233
Page 13 of 48
''
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 12, 2005
Description NC State University
Sample ID MW-61
Collected By J. Ganey
Collection Date 05/11/05 09,07
Parameter
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-Chloropropane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
Di-isopropyl ether
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
p-Isopropyltoluene
Methylene chloride
Methyl tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
l,l,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,l-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #86
Result Det. Limit
BDL 1.0
BDL 1.0
9.8 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1. 0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1. 0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 5.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 5.0
BDL 5.0
BDL 5.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
Det. Limit -Estimated Quantitation Limit(EQL)
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I .o. 62-0814289
Est. 1970
May 22, 2005
ESC Sample#
Site ID
Project#
Units Method
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
Ll98803-05
2519
Date
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
Laboratory Certification Numbers:
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN -C-TN-01
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA 00109, WV
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Page 14 of 48
I
I
I
I
I
I
Dil.
1
1 I 1
1
1
1
1 I
1
1
1
1
1 I
1
1
1
1
1 I
1
1
1
1
1 I
1
1
1
1 I 1
1
1
1
1 I
1
1
1
1
1 I
1
1 I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
D
D
I
I
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 12, 2005
Description NC State University
Sample ID MW-61
Collected By J. Ganey
Collection Date 05/11/05 09,07
Parameter
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Toluene
Vinyl chloride
Xylenes, Total
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #86
Result Det. Limit
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 5.0
BDL 1.0
BDL 3.0
Det. Limit -Estimated Quantitation Limit(EQL)
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 22,2005
ESC Sample#
Site ID
Project #
Units Method
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
L198803-05
2519
Date
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
Laboratory Certification Numbe
-923, IN C-TN-01
Dil.
1
1
1
1
1
1
1
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -7487,
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84 ,
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI Note:
-2006, VA 00109, WV -233
998093910
The reported analytical results relate only to the sample submitted.
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported, 05/22/05 08,43 Printed, 05/22/05 08,44
Page 15 of 48
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 12, 2005
Description NC State University
Sample ID MW-63
Collected By J. Ganey
Collection Date 05/11/05 11,23
Parameter
Methane
Chloride
Nitrate
Sulfate
Alkalinity
Ethane
Ethene
TOC {Total Organic Carbon)
Mercury
Arsenic
Barium
Cadmium
Chromium
Iron,Dissolved
Lead
Manganese
Selenium
Silver
Volatile Organics
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon Tetrachloride
Chlorobenzene
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #86
Result Det. Limit
8DL 1000
8DL 1000
8DL 100
8DL 5000
8DL 10000
8DL 1000
8DL 1000
8DL 1000
8DL 0.20
8DL 20.
8DL 5.0
8DL 5.0
8DL 10.
8DL 100
8DL 5.0
8DL 10.
BDL 20.
BDL 10.
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1. 0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
Det. Limit -Estimated Quantitation Limit(EQL)
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax {615) 758-5859
Tax I.D. 62-0814289
Est. 1970
May 22,2005
ESC Sample#
Site ID
Project#
Units Method
ppb 8015M
ug/1 9056
ug/1 9056
ug/1 9056
ug/1 310.2
ppb 8015M
ppb 8015M
ug/1 9060
ug/1 7470A
ug/1 60108
ug/1 60108
ug/1 60108
ug/1 60108
ug/1 60108
ug/1 60108
ug/1 6010B
ug/1 6010B
ug/1 60108
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
Ll98803-06
2519
Date
05/13/05
05/12/05
05/12/05
05/12/05
05/18/05
05/13/05
05/13/05
05/17/05
05/17/05
05/15/05
05/15/05
05/15/05
05/15/05
05/14/05
05/15/05
05/15/05
05/15/05
05/15/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
Laboratory Certification Numbers:
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Page 16 of 48
C-TN-01
00109, WV
I
I
I
I
I
I
Dil.
1 I 1
1
1 I 1
1 11
1
:1
1 ~. 1
1 ii
1 ~· 1
1 ~· 1 lg
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
g
D
I
I
D
ENVIRONMENTAL
SCIENCE CORP.
REPORT OF ANALYSIS
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
May 12, 2005 Date Received
Description NC State University Lot #86
Sample ID
Collected By
Collection Date
Parameter
MW-63
J. Ganey
05/11/05 11, 23
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-Chloropropane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
Di-isopropyl ether
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
p-Isopropyltoluene
Methylene chloride
Methyl tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
BDL -Below Detection Limit
Result
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BriL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
Det. Limit -Estimated Quantitation Limit(EQL)
Det. Limit
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1. 0
1.0
1.0
1.0
1.0
1. 0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
5.0
5.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 22,2005
ESC Sample#
Site ID
Project #
Units Method
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 62300
ug/1 6230D
Ll98803-06
2519
Date
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
Laboratory Certification Numbers:
C-TN-01
Oil.
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910 00109, WV -233
Page 17 of 48
'.
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 12, 2005
Description NC State University
Sample ID MW-63
Collected By J. Ganey
Collection Date 05/11/05 11,23
Parameter
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Toluene
Vinyl chloride
Xylenes, Total
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #86
Result Det. Limit
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 5.0
BDL 1.0
BDL 3.0
Units
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 22,2005
ESC Sample# L198803-06
Site ID
Project# 2519
Method
6230D
6230D
6230D
6230D
6230D
6230D
6230D
Date
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
SC Representative
I
I
I
I
I
I
Dil.
t I
1
1 ~·
I
I
I
I
I
I
Det. Limit -Estimated Quantitation Limit(EQL)
Laboratory Certification Numbers:
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487,
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN
-923, IN
-2006, VA
C-TN-01 I
00109, WV -233
AZ -0612, MN -047-999:395, NY -11742,' NJ -81002, WI -
Note:
The reported analytical results relate only to the sample submitted.
998093910
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported: 05/22/05 08:43 Printed: 05/22/05 08:44
Page 18 of 48
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
n
D
I
I
I
I
ENVIRONMENTAL
SCIENCE CORP.
REPORT OF ANALYSIS
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
May 12, 2005 Date Received
Description NC State University Lot #86
Sample ID
Collected By
Collection Date
Parameter
Volatile Organics
Benzene
Bromobenzene
TRIP BLANK
J. Ganey
05/11/05 00,00
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon Tetrachloride
Chlorobenzene
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-Chloropropane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
Di-isopropyl ether
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
p-Isopropyltoluene
Methylene chloride
BDL -Below Detection Limit
Result
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
Det. Limit -Estimated Quantitation Limit(EQL)
Det. Limit
1. 0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1. 0
1.0
1.0
1.0
1.0
1. 0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1. 0
1. 0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 22, 2005
ESC Sample #
Site ID
Project#
Units Method
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
Ll98803-07
2519
Date
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
Laboratory Certification Numbers:
C-TN-01
Oil.
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
AIHA -100789, AL -40660, CA -1-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910 00109, WV -233
Page 19 of 48
ENVIRONMENTAL
SCIENCE CORP.
REPORT OF ANALYSIS
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
May 12, 2005 Date Received
Description NC State University Lot #86
Sample ID
Collected By
Collection Date
Parameter
Methyl tert-butyl
Naphthalene
n-Propylbenzene
Styrene
TRIP BLANK
J. Ganey
05/11/05 00, 00
ether
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Toluene
Vinyl chloride
Xylenes, Total
BDL -Below Detection Limit
Result
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
Det. Limit -Estimated Quantitation Limit(EQL)
Det. Limit
5.0
5.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1. 0
1.0
1.0
1.0
5.0
1.0
3. 0
12065 Lebanon Rd.
Mt. Juliet, TN 37122
(615} 758-5858
1-800-767-5859
Fax [phone]B59
Tax I.D. 62-0814289
Est. 1970
May 22,2005
ESC Sample# L198803-07
Site ID
Project# 2519
Units
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
Method
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
Date
'05/10/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
05/18/05
Laboratory Certification Numbe s:
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E'>-••0 --, GA -923, IN -C-TN-01
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA 00109, WV
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Note:
The reported analytical results relate only to the sample submitted.
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported: 05/22/05 08:43 Printed: 05/22/05 08:44
Page 20 of 48
I
I
I
I
I
I
Dil.
1 I 1
1
1·
1 I 1
1
1
1
1 I 1
1
1 ~. 1
1 11
I
I
n
I
I 233
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
n
D
m
I
,1
,1
Sample#
Ll98803-0l
Ll98803-02
Ll98803-03
L198803-04
Attachment A
List of Analytes with QC Qualifiers
Analyte
Tetrachloroethene
Chloride
Nitrate
Sulfate
Chloroform
Tetrachloroethene
Chloroform
Dichlorodifluoromethane
o·ichlorodifluoromethane
Qualifier
J4
J3
J3
J3
E
J4
E
J4
J4
Page 21 of 48
Qualifier
E
J3
J4
Attachment B
Explanation of QC Qualifier Codes
Meaning
GTL (EPA) -Greater than upper calibration limit: Actual value is known to
be greater than the upper calibration range.
The associated batch QC was outside the established quality control range
for precision.
The associated batch QC was outside the established quality control range
for accuracy.
Qualifier Report Information
ESC utilizes sample and result qualifiers as set forth by the EPA Contract Laboratory Program and
as required by most certifying bodies including NELAC. In addition to the EPA qualifiers adopted
by ESC, we have implemented ESC qualifiers to provide more information pertaining to our analytical
results. Each qualifier is designated in the qualifier explanation as either EPA or ESC.
Data qualifiers are intended to provide the ESC client with more detailed information concerning
the potential bias of reported data. Because of the wide range of constituents and variety of
matrices incorporated by most EPA methods,it is conman for some compounds to fall outside of
established ranges. These exceptions are evaluated and all reported data is valid and useable
unless qualified as 'R' (Rejected).
Definitions
Accuracy -The relationship of the observed value of a known sample to the
Precision
true value of a known sample. Represented by percent recovery and
relevant to samples such as: control samples, matrix spike recoveries,
surrogate recoveries, etc.
The agreement between a set of samples or between duplicate samples.
Relates to how close together the results are and is represented by
Relative Percent Differrence.
Surrogate -Organic compounds that are similar in chemical composition, extraction,
and chromotography to analytes of interest. The surrogates are used to
determine the probable response of the group of analytes that are chem-
ically related to the surrogate compound. Surrogates are added to the
sample and carried through all stages of preparation and analyses.
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
31-119
12-134
51-141
Control Limits (AQ)
Nitrobenzene-d5 43-118 Dibromfluoromethane 70-130
2-Fluorobiphenyl 45-128 Toluene-dB 70-130
Terphenyl-d14 43-137 4-Bromofluorobenzene 70-130
TIC -Tentatively Identified Compound: Compounds detected in samples that are
not target compounds, internal standards, system monitoring compounds,
or surrogates.
(SS)
70-130
70-130
70-130
Page 22 of 48
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I ENVIRONMENTAL
SCIENCE CORP.
12055 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
I Piedmont Geologic
Mr. John Harper
Tax I.D. 62-0814289
Est. 1970
6003 Chapel Hill Road Suite 109 I Raleigh, NC 27607
al te
Quality Assurance Report
Level II
Ll98803
?)/iiP'?f~t:.:i:?iY/~1..irlk?''''' Result. Units tfa.te Anal zed
May 22, 2005
Batch
........ -... -...... -.... -.-...... -... -.-.-....... ,.·:-·-·,:.:,:,-:t\:::::::=:j'{'/:·::}(:~J 1
< .1
< 5
< .1 mg/1 05/14/05 08,17 WG201964
< 1 •·••/•:::er :}:::: ";,;t/i r "· ••3·g•)t~';a€'· 08, 59 :c::• '"l!iai'6it•;·;""·' ..
1t1ej::¢liry.}if:::·:· :···:-::••:·••::::::.·:·::::.: .. ,:.::--::•:-::•.::-:::::··::•·'·'"+::+:.: -::•.•:••-:::::.:·<t)'00.02.•···••·•••: :-::-::,:::::-:-:-•mg/I\?•· •:•::-•:.o.~/.16./Q.5 :,,17 •. ,:s1 ·:,::,t\1o192.o:~.2_1.5•••:::•:·•·•·•····
Mercury < .0002 mg/1 05/17/05 03,18 WG202365
f:T'.f:}i~!2:'l[i;ib;bl8;!~! < _ 001 / ;,;~yr• t~Jf\/&g 17, 44 ~g;3~gJ: r··
li:~:~;lir~iii!i~iiiilh .. ri¢ <~ :Uir >!~}+ rgijN~giI NlH• I iiig~i~i,··.
1,1-Dichloroethane < .001 mg/1 05/17/05 17,44 WG202529
l g••1c,ori:h1or6e.theriet•·•>c ·······••:-::: •·· •:: :::::/ :•• >·:•.<t:>o:01J ::-:: :C::?itrng/1 /J::c:05/17/os :•:1,T,4.4 t>••wG202529:.t::--•··· · 1 '. l;Dichloropropenei" · < . 001 mg/1 ········ · ·05/17 /05 1 7, 44 WG202529 1, 2 ,3-Trichlorobenzene < • 001 mg/1 05/17 /05 1 7, 44 WG202529
T/2/3.c.T.r.ic::hl.c:ii:-.opr9parie ••t::/(j{C.: •?.OOl}f(C •••••t•)mg/1) ::(:\05/17/.05 •:r7, 44 : ))WG202529{: :• ··
1,2,4-Trichlorobenzene < .001 mg/1 · · ··05/i7/0·5 ·17·044 · "\'1c;:fo2529·· .. · 111, 2, 4-Trimethylbenzene < . 001 mg/1 05/1 7 /05 1 7, 44 WG202529 0I:~i§t~~f~~~~i~~~~~0P"0J?a:ne·•·•·•·· r :>:ggf ; t ~~n >g~jgnftW:H· <:g~g·~~~:>
1,2-Dichloroethane < .001 mg/1 05/17/05 17,44 WG202529
Dl. :.·,i•·~!t!!t~!!~i!!!~!e.\.n/·e·•·.·•.:. > •·•···•·•···•··••·····•·•·•···•·•·•·•·····•·•···•·•·•·•·•·····•·••::: ]gf? <~iir )grnig!' ff::: t ii!g!!l!2 .....
F3/Dfc:hlor('proparie•••:r.-.--.•· ······ ··,·• •••••···•••··•·•·• •·•• \< t;o_orr: •· ::::,+.m9/r. ::::•::05/17/05 (1-7.,44 :::.:\wG202s29Y••·· 1'.4;Dichlorobenzene ·· < .001 mg/1 ···········05/17/05 17,44······ ·wG202529
2 ,.2-.Di.c.hloroprog~r~ < • 001 mg/1 05/17 /05 1 7, 44 WG202529 l~:§~i6i6t6IU;R: n ·:}:ggrx ~1r··· <gg}f~)gg t}(!! x:g;g·}g~!>•·····
Benzene < .001 mg/1 05/17/05 17,44 WG202529
B.romob.enzenet••:-:::::--• ·•tt'•••:::: ·· ···• ::•;-•:·•'•''•< .:<::::001:: ,, •••• ,:.:•••t.\mg/1 :k••:I•••o5/p_/05\ 17,44::'. ://wq2.02.52~:.:••· ·.···
I Bromochloromei:han·e .. . . < • 001 mg/1 05/1 7 /OS 17: 44 WG202529
Bromodichloromethane < .001 mg/1 05/17/05 17:44 WG202529 :t~~~!tt~f;;~:::•••<•+•>•• \).)} :.:••··•:•••:<:<::::-;::·::-;;-::::::::::::.::-•• ::·::•:·:g:g{ )•· ...... , .... :::-··•:r~~j f ,., •• ,,,.•,·•ggJ·H1·Z; ''t'li: :·•r ·•:t :giz·~;;~Ir••::••
Carbon Tetrachloride < .001 mg/1 05/17/05 17,44 WG202529
I chloropenzerie'•/ t:t••••:.: •· ············ • ·•c:-:•J••: < : < r::0.01 ·fr •.•:>··•••· {mg/lJ· .:::/05/17/05: 1.1·, 4.4:::.: •·•··•wG202529< .., ...
Chlorodibromomethane. < • 001 mg/1 .. 05/1 7 /05· 17, 44 WG202529
Chloroethane < • 001 mg/1 05/1 7 /05 1 7, 44 WG202529 §~f ~t~!~~~~•;;~ ... r,·rt +I•••·•x•,xr,••'>,••ft+FY• ,._..,, .• , ! >·:·.g.gi' ·•·•·•·····•·•·•·•·•<••·•::t~'ii ... ,., ..• •·•·•·•·••·••··g ~}I+) g.g' ··i·~·•:·:! :·.,:t··~§;g~.g·~·~··••:\>·••:·.·•· I cis-1, 2-Dichloroethene < • 001 mg/1 05/1 7 /05 17, 44 WG202529
Page 23 of 48
ENVIRONMENTAL
SCIENCE CORP.
Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Analyte
Quality Assurance Report
Level II
Ll98803
:tJ~~J?.9t~-~?tY:::':.~J-~t~:::.:::: Result Units Date Analyzed
Page 24 of 48
12065 Lebanon Rd.
Mt. Juliet, TN 37122
{615) 758-5858
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 22, 2005
Batch
I
I
I
I
I
I
I ENVIRONMENTAL
SCIENCE CORP.
I Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109 I Raleigh, NC 27607
Hexachlorobutadiene
Lalyte
Quality Assurance Report•
Level II
L198803
< .001 mg/1 05/18/05 09,13
\:t:P~.ti.?i*tC?IY:3.13.fiihK\f Result Units Date Analyzed
Page 25 of 48
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 22, 2005
WG202603
Batch
ENVIRONMENTAL
SCIENCE CORP.
Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Meth lene chloride
Analyte
Quality Assurance Report
Level II
L198803
< . 005 m /1 05/18/05 11,42
\/P~J:f.C?t..¥.·.t.·q;r;:v,t.~.ra:h~d/ Result Units Date Analyzed
Page 26 of 48
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 22, 2005
WG202651
Batch
WG202661
I
I
I
I
I
I ENVIRONMENTAL
SCIENCE CORP.
I Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109
I Raleigh, NC 27607
Methyl tert-butyl ether
IAnalyte
n
'
Quality Assurance Report
Level II
Ll98803
< .001 mg/1 05/19/05 12,10
t\P~Ji<:>t~-~·9:t\i/·.?.J*-rj~\ ... Result. Units Date Analyzed
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 22, 2005
WG202676
Batch
ENVIRONMENTAL
SCIENCE CORP.
Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
n-Pro lbenzene
Analyte
Anal te
Quality Assurance Report
Level II
L198803
< .001 m /1 05/19/05
,.·J:1j_~_9_'?t~t9t,Y:t~.1:ijtJ:1K/
13,02
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 22, 2005
WG202859
Result Units Date Analyzed Batch
Units RPD Limit Ref Sam Batch
. . .. .. \ )I •tmg/1} •< 7c'59/< / •Q.:C5o•···•· Lt11,· '20? {t•t•L.198803\og ?WCl201879 .. ·mg/1 240. 250. Coo ·20· Ll98844-21 WG2.01879
I
I
I
I
Ch-16i'"idE!'i/::·::....-·· ·chro"r'iae' ··
Nitrate Nifr·atE{/-)F::··:-"."."··
Sulfate
Sulfate
mg/1 0.00 0.00 0.00 20 L198803-0l WG201879 .·.··.·.·.·.· ..... · ............................................................. ,, ......... ,, .... , ......... ?••~;~r) ::~••:6g.,••·•·•··•··• ~·;g••!·•~·~o /({lI'.g~•• •··•<!·g <•·• A•·••••ftt!i!~•!·•~··gf •··•••·;~II•~·;•~.,
!fattt+zlti• atif~r2•• Eifgi~i• ••·••·t•>•·••••ti~)I >•••·~iJ'. •·· >•.• +•••~@&: r•.•x•••·•tt•·• .t• 6'.4fd u i6>· ......•. , .. •··•t•·•ttiiJgi:s~ •···•·•·w&s·s·r;;;!;
·•···• rrig/{ /(2.3/.ot'· \23 '.Q/ (ll{QO }\\2.0' · · \Ll9B.???fo9f ··•WG2QZ.6.6.ol
Alkalinity mg/1 0.00 0.00 0.00 20 Ll98803-06 WG202661 Alkalinity::•·••·· ··.···.····.·····.··.·····.·.· .. · .. · .. ·.•···· ·•·• ··········•··••·•···•·••rnq/ht• 230•:••• ·•r...:·••••2so•,·•••••• a•C33•••· \?20?• •·•··•i•••Ll99076·o.oa :•.wG202661•
cAn,,,,,ac,lc1Yc.,tc,e,_ ________________ ,,u,,~"'f-"g-"·:'-15_\?_:r_:s;-"·:~"'.O"'"~,.,-~"':.~,_c~t_,::~c!--i'-i-:O_l_' '_,"~,,t"~'-':-~":.i,..,"tc..>_U_'1 __ _:%,___,R"ee,C,c___~L=im"'=.i=.t __ B,,_aSc.'ct=.cc!h __ __!I
Ethene
Arsenic B~iiiUffif::c:':::: ·cactmiUID
Chromium tead-'=>ttc:x Man•g·a·iiti·;i;i
Selenium S_:i.J:V.et;.'/'".
Iron,Dissolved
85.0 67-113 WG201948
Page 28 of 48
I
I ENVIRONMENTAL
SCIENCE CORP.
I Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109 I Raleigh, NC 27607
1,1,1-Trichloroethane
Lalyte
n
Quality Assurance Report
Level II
mg/1
Ll98803
.02
Page 29 of 48
0.0177
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 22, 2005
88.3 62-133 WG202529
% Rec Limit Batch
ENVIRONMENTAL
SCIENCE CORP.
Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
1,1-Dichloroethane
Quality Assurance Report
Level II
L198803
mg/1 .02 0.0207
Page 30 of 48
103.
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 22, 2005
51-135 WG202603
I
I
I
I
I
I ENVIRONMENTAL
SCIENCE CORP.
I Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109
I Raleigh, NC 27607
1,2,3-Trichlorobenzene
IAnalyte
R
I'
Quality Assurance Report
Level II
L198803
mg/1 .02 0.0221.
/?Lab()~i3.:t::o:ryrcont"ro1::: __ i:;_amp:re"::::,?' Units·· . Kn6wii ·va:1·· ...... ReSull:
Page 31 of 48
12065 Lebanon Rd.
Mt. Juliet, TN 37122
(615} 758-5858
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 22, 2005
111. 57-152 WG202651
% Rec Limit Batch
ENVIRONMENTAL
SCIENCE CORP.
Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
1,1-Dichloro ro ene
Analyte
Quality Assurance Report
Level II
L198803
m /1 .02 0.0153
_\Jialt¢il:.~t·C?.w:".~Ontro1 ::-samp_rift
Uni ts Known Vii't.. Re Sutt·
Page 32 of 48
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 22, 2005
76.3 63-125 WG202676
% Rec Limit Batch
I
I
I
I
I
I
I ENVIRONMENTAL
SCIENCE CORP.
I Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109
I Raleigh, NC 27607
1,2,4-Trichlorobenzene
IAnalyte
n Analyte
R Iron,Dissolved
Quality Assurance Report
Level II
Ll98803
mg/1 0 0.0254
\\~?PO#¥l"t§fy/qontro1 :,:~a;mp_1e?t' Units Known Vat· ·ReSult'.
mg/1 1.04 1. 02 1. 94
Page 33 of 48
12065 Lebanon Rd.
Mt. Juliet, TN 37122
(615) 75B-5858
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 22, 2005
0.00 49-153 WG202859
% Rec Limit Batch
20 104. WG201964
ENVIRONMENTAL
SCIENCE CORP.
Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Quality Assurance Report
Level II
Ll98803
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax (615) 75B-5859
Tax I.D. 62-0814289
Est. 1970
May 22, 2005
I
I
I
I
nr.r;~.P-i'.r:?:~?tY-tf¢tj._t~?.r<s?_~P_1.¢;: pµp_:i;:i:c;~-~¢::::J: I
"An=acclc,Y.ctccec...._ ________________ U,cn=i"-t"s----"L-=C"S"D----"R-=e-=s----"R-=e'-"f---"R-=e::esc__---"R"'P-'D'--'L"i'-'m""i"t'--%'-'R"'e='c'------'B"'a"'t"'c"'h'-'--------
Page 34 of 48
I
I
I ENVIRONMENTAL
SCIENCE CORP.
I Piedmont Geologic Mr. John Harper
6003 Chapel Hill Road Suite 109
I Raleigh, NC 27607
Trichlorofluoromethane
IAnalyte
''
Quality Assurance Report
Level II
L198803
mg/1 0.0203 0. 0192 5.59 19
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Eat. 1970
May 22, 2005
101. WG202529
\}[,~99r'.ai.~<?ti/G¢>)i._t;X¢J{:'s!=iIDPJ'¢: :PiiP;l/fC~-~-¢\f Units LCSD Res Ref Res RPD Limit %Rec Batch
t??'\tng/1'} :\o/017 .. 7 ')/0}0l:69 '{)'4\50) "i7 /}\'88/5 \{ \WG2.02529/ :-,:·•···
mg/1 · · · ··o .·0105 o. 0683 3. 20 17 118. WG202529 ·
Page 35 of 48
ENVIRONMENTAL
SCIENCE CORP.
Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Quality Assurance Report
Level II
Ll98803
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax (615} 758-5859
Tax I.D. 62-0814289
Est. 1970
May 22, 2005
I
I
I
I
}{4~.P9.i'.ii,~9#Y.{C'.<?ri,t).~tj_]){$~'mPli1 :::pµ:p1:~•¢*_~¢{b:' I
:.,An=ac,l_,y_,t-'e'--------------------'U""n""1"-' t,c:S,:_L,;C""SD=:...R=e-"s-----"R'=e-=f-----"R'=e-"s'----"R°"P-"D'--"L'-'i°"m"i'-'t'--'%'-'R"e"c'----'Be,a,.:t,.:ccch"---------
Page 36 of 48
I
I ENVIRONMENTAL
SCIENCE CORP.
I Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109 I Raleigh, NC 27607
Alkalinit
nalyte
Quality Assurance Report
Level II
L198803
m /1 44.0 40.0 9.52 20
1206S Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0B14289
Est. 1970
May 22, 2005
110. WG202661
t\L.~P§r~.t9i.Y:FC::ftj..t.:¢<?J:.t:s~\\1PJ$ ?P~P.ri·c:.~_t;.¢.\:'.:-units LCSD Res Ref Res RPO Limit %Rec Batch
1)/J)f}irig/l """'·:/)0\'0218 \(C:0}O2.2.3 /)/2)'39. )/J7/?' "109';\{ iW(l2.02859)::t
mg/1 0.0186 0.0200 7.29 17 92.8 WG202859.
Page 37 of 48
ENVIRONMENTAL
SCIENCE CORP.
Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
1,1,2,2-Tetrachloroethane
Analyte
Analyte
Ch-1 Oi'Tde·::r::::::;:-:-: .. 'Ni t'i··a"te ....
Quality Assurance Report
Level II
Ll98803
m /1 0.0210 0.0207 1. 87 16
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 22, 2005
105. WG202859
.-?-~~b.¢>fa_t¢?~Y:(C_O_ri_~#◊-~?:s~TripJ'¢1 J:>j.iP_rJS*~Et:·w Units LCSD Res Ref Res RPO Limit %Rec Batch
:\\M~t:·?;iX'\$P'ikit\
Units MS Res Ref Res TV % Rec Limit Ref Samp Batch
Page 38 of 48
I
I
I
I
I
I
I ENVIRONMENTAL
SCIENCE CORP.
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax {615) 758-5859
I Piedmont Geologic
Mr. John Harper
Tax I.D. 62-0814289
Est. 1970
6003 Chapel Hill Road Suite 109
I Raleigh, NC 27607
Quality Assurance Report
Level II
Ll98803
May 22, 2005
(lfate mg/1
lyte units
51.8 7.40
'::::.<:Mat·riX{$Pi·.l:c¢\/ M"S"''·Re·s .. ··-Ref Res
so 88.9 80-120 L198803-02 WG201879
TV % Rec Limit Ref Samp Batch
) nig/1 /<i)•986/ \ )0\00) 1/ , • \9.8\6}7.5/:L2.5. \L1988Q9>01 •••l'IG20196.0 mg/1 1.12 o'.o·sgif 1 106. 75-125 .. ··Li988b9'.ci1 WG201960
mg/1 1.06 0.00 1 106. 75-125 Ll98809-01 WG201960
· · ······ ··· ········• t·•· •<• ,\\ing/1 • • :.1<9.3 • ::·•.o.>oo. >I•1t• ••• • •• 103" :.7sco125 :::.n .. 19eeo9°01 :.w.G2.01.9.6.o mg/1 1. 02 o. 00 1 ....... fo2:· ·7~i:·y25 ·r..i9ssog'.·<if. WG201960
mg/1 1.80 0.778 1 102. 75-125 L198809-0l WG201960
}ing/1 0\9?4 { 0}0270 ·•1: k 94i7.75{l:25 (I,198809/01 WG201960
.. mg/1 0.984 0.00 1 98.4 75-125 ··1,191fso9~cii ·wc;2iii<i6·o·
:ripii/J?iiisc,lyecl •{ / \ ing/1/ /0\989 /0.\00 ( 1 . t98\9 ]Sf125 •fL198803/06 l'IC,201_964•
ITOC (Total (),'9~.!'i.9. Carbon) mg/1 27. 7 6. BO 20 105. 80-120 Ll98803-0l WG201992 ~!;!~~~~ +• . i~Jf / 0.0029 a.aa ··•··· -~~I ~iiI\0-130 tfiJiI&16i Mt~aJI~f
.M.er.ciiiiii <•••:·:r t t•·•t•·•··· ? t•·•·•:•:rr·•····•·•·· ·····•·······•·•·•.••····•·:·:••mg/I·••••· ••·•·•·•···••o,•.002.9•••·•·• ·•·•·•o:•;o.o• r·•····•·c.003.•••· ·•rt.9.7•:··3•· .70.,130 )\L.19.9.o?.6.\Q.1 wG.?Q236s·•
1, 1, 1, 2-Tetrachloroethane mg/1 O. 0200 O. 00 . 02 100. 57-133 Ll98922-02 WG202603
1••·1,;tfTiichJ:or6ethiiri¢ •:•r•:: • nig/1( ?• oto23·a•:: <•o•coot•• :.;02\t ?119\ /(54\143 t 1,190922<02 wq20260.3 1'.1;2;2-Tetrac.hloroetha·r1e· mg/1 0.0213 0.00 .02 107. 58-134 ···r..19B!i22~02 WG202603
ll!~~gi!~~[~l!~~!~i101 n <m!~} f lig~H· <g+gg• !gl ······.·ti~i ... iiIHi utiiii~Egi ~iUiigi
1,1.;D.ichloroi,.ropene ...... •.•··············••.• .................. mg//1 .... 0,0222 ... 0.00 ..... ,02 ........ Jll. .. S8:126 Ll98922;02. WG202.603 lt~!!=!~t~~ig~gi~~H~:.. r;;jr· .... rg~[f .. •·gigg· .. '.gl (1g!~: !i!t~·~· xtiiii~l=g~ ~ilgUgf
r:~~ttrttmts~~.~~f~!~~ti;~!;t?? 9 %§~}> /g:g~5:\ >g:gg59 :g;} {ag:r \~·~:'}~r >n~:·~~~(g~ ~g~g}~gJ
I ~:iigtI~lg~~!!~!i~! r 1 E!1i... >g '.Ii[i +g '.•gg t ~g~? ) Hi+ ··ii;Hi rlHH~i~·H ~g§gi!g!•·
1,3,5-Trimethylbenzene mg/1 0.0263 0.0024 .02 120. 54-125 Ll98922-02 WG202603
1'.;3CDichloioberizerie• I• •••••• ••••••••••••••••••••••••••••••••••••••••••••t•mg/l• ,t••••.0\0.201) q,,ofOOf ?{'.'02:'.: ••r••1.00\ '.:'.:47'•12a•• XL198922°02 ·•wG202603
1 i:~~gH~tiigliit~g~ i t /E!~.i\ .. ·····••<g; .. g.i.~.~ •.• tgi .. gg ···?••:•·g~ •.•.•. t ........ ·:ii.: f::I.~tii .•. yt~iii~·~a~ ... ~gig~!Ii ..
2-Chlorotoluene mg/1 0. 0206 0. 00 . 02 •••\a'/ . ·si~i:JS Ll98922-02 WG2026o:J·
4-Chlorotoluene mg/1 0.0204 0.00 .02 102. 57-123 Ll98922-02 WG202603 I i::~~6~:;;~;;;!{! 2 +m§'ii < g:g;5~··· > g:gg ug.~t ?fai< ?~f:Hi >ti~:~~~~g~ ~g~g1~g}
:rnm6a~~;::I61;J%~~th!n,,· ••····.·.··•••··.. t• xm§ji9 ·•·ug:g~ti +g:gg :g.~? t•ig~; )~!cij~ r.tt~:~~~:g} ~g~g}~.gj. u :~6fu~~~~~ane .... . . . fu§ji g: gi~i g: gg : g~ ~t ~ ~f iji ti~:~~f g~ ~g~g~~gj
§~f~~~gI~;,~ttilc,ride t %§jft \g:g~~i + >g:gg· +:gi+ · i6ii >;iig~ tI~:~·~}'.g3 ~gig~igr
n ·~~il~liii:::r?}hane I? t?t~l~·i ••<i•~:·i·i•ij •••It•··i•·:•ii. >:iiii. ?iH:> i1·~~i·i·· t~!lllll·~ii •··~iiiii·~i·•
Bf~{i~ti~ii~1~~~:J:h"'!'E!. \ '%§Ji >g:g;[~··· tg>gg; '.{} ifaU \~f:H•~ 1tf~~·~·~;:g~i:g~g§~g~··
m !i~it~i~!!!~t!~:!i~~!)G)? ?%~!~~ j g!g~~i } g!gg ( :g~ t,i~i:\ •·iiHii ttttiHi~~·gi ~iiziig!•·
Isopropylbenzene mg/1 0.0220 0.00 .02 llO. 59-127 Ll98922-02 WG202603
• ~;;~~rrr~:i~~f~J:r~ret:her•· t <;§Ji ••·•·•·•./g:g~t~ /grgg·· t :gJ •fg~c >il:}!} tti:i~t~tgI• ~g~.g~ig}
Page 39 of 48
I
I'
ENVIRONMENTAL
SCIENCE CORP.
Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
n-But lbenzene
Analyte
Quality Assurance Report
Level II
Ll98803
m /1 0.0206 0.00 .02
Units \:/:.~i:i.-~r~~\~P~.J:c¢:t:·: MS Res Ref Res TV
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 22, 2005
103. 47-124 Ll98922-02 WG202603
% Rec Limit Ref Sarnp Batch
I
I
I
I
~;;~!~!!i~r:::::::··· •···.·.·········•········• / ~iii trn~t··• )/gtgg 7 :Ir (~!l!6 ii!~nt ni1i~I~g~ ~g~gngi1
sec:Sllu~il1,.,iize.iie)•/ •·· ·· ······••mg/T· • •?<o/0212r :•\o\ooyx ••io2, tr.106\ t•s{c12.1\t t19sn2\02 :wa202603. Styrene mg/1 .... cLci20·4 0.00 ~·02 102. 55-121 Ll98922Cb2 WG202603 i!i!:!~{;;i~iit:R:t···· ······ · ···· ····.·.·.·.···.· f !jt> > g:II!it <g!gg > !gI< +~ii:4 riitHI ttl!Ui~·~•gi ~g~giigil
trans-1,2-Dichloroethene mg/1 0.0230 o.oo .02 115. 52-139 Ll98922-02 WG202603
Tr•ichlofoetherie?(• \·· \:)• ••·· •·••··· ·<\riig/F·•· ·•·I0}020B·• • \Q\o.o.• t?•'.02} ••• ··104•, .\57/P5)C L19B.9.22\02• .WG202603•
Trfrhforofluororiiettiarie mg/1 · 0:0246 o.oo .02 12:J. 42-134 Ll9sn2so2 wt:20·26031
Vinyl chloride mg/1 0.0257 0.00 .02 128. 44-132 Ll98922-02 WG202603
Xylehiiii/ T.6.ta.l·· ··•··········· } riig/1 \ 0./069.B\ )Oioo· }06 : (:,16) }5.4\}29)/ r;I~B~.22\0~• WG20.?e03 ..
Page 40 of 48
I
I
I ENVIRONMENTAL
SCIENCE CORP.
I Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109 I Raleigh, NC 27607
p-Isopropyltoluene
IAnalyte
I
Quality Assurance Report
Level II
L198803
mg/1 0.0219 0.00 .02
Units /\;·.~-~-~~:~~)9Pf~¢\/ MS Res Ref Res TV
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 22, 2005
110. 52-126 L198809-08 WG202651
% Rec Limit Ref Samp Batch
ENVIRONMENTAL
SCIENCE CORP.
Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
sec-But !benzene
Analyte
Quality Assurance Report
Level II
L198803
m /1 0.0220 0.00 .02
units :-:::::::::Ma ti~?.Cl:::.$PtJ{~f?:C. M·g .. ··Re·g· Ref Res TV
Page 42 of 48
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 22, 2005
110. 54-127 L199056-01 WG202676
% Rec Limit Ref Samp Batch
I
I
I
I
I
I
I ENVIRONMENTAL
SCIENCE CORP.
I Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109 I Raleigh, NC 27607
.Toluene
Analyte
Quality Assurance Report
Level II
Ll98803
mg/1 0.0185 0.00 .02
Units, i}\1'1:~.t:#.:i.~?§P;.k¢/? MS Res Ref Res TV
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax {615) 758-5859
Tax I.D. 62-0814289
Est. 1970
May 22, 2005
92.3 57-126 Ll99148-01 WG202859
% Rec Limit Ref Samp Batch
.. ·.·· 1T1g/l/ <o{Ol85) t 0/00 /02 /~2\5 '.52{13.9 /L199148/0i WG202859.
mg/1 0.0106 o.oo .02 93.o 57-135 ···t199i40·:·01 wcj202as!f
mg/1 0.0165 0.00 .02 82.3 42-134 Ll99148-01 WG202859 i>~'ii < g::g~N rg:§gs~ :g~••• t 1~~:4 ~fit~·~• >tf~~I!~·~•gr ~g~g~·~·~·~·•
{C}1_i:i:t:fi?CJ~Pikefl)uP_lfC:~.t'ie\Y
Units MSD Res Ref Res RPO Limit %Rec Ref Samp Batch
Page 43 of 48
I
ENVIRONMENTAL
SCIENCE CORP.
Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Chlorobenzene
Analyte
Quality Assurance Report
Level II
L198803
mg/1 0.0200 0.0201 0.733
t)t-1_~_ttfKt~P~K¢:/P:4P.Pi¢~~--~ffl Units MSD Res Ref Res RPD
Page 44 of 48
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 22, 2005
I
I
I
I
22 99.9 L198922-02
Limit %Rec Ref Samp
WG202601 Batch
I
I
I ENVIRONMENTAL
SCIENCE CORP.
I Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109 I Raleigh, NC 27607
Chloroform
IAnalyte
I.
Quality Assurance Report
Level II
L198803
mg/1 0.0148 0.0151 2.22
\HM.~~#.ti~.k~PtK¢.\I?:4't>.Pi¢.~J::~It Units MSD Res Ref Res RPD
Page 45 of 48
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 22, 2005
20 74.0 L198809-08 WG202651
Limit %Rec Ref Samp Batch
ENVIRONMENTAL
SCIENCE CORP.
Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Chloromethane
Analyte
Quality Assurance Report
Level II
Ll98803
mg/1 0.0125 0.0127 1. 79
tC~*-.~:f::ij(/?Pt~¢.1!?4PJA¢~:t:.~::::r Units MSD Res Ref Res· RPO
Page 46 of 48
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-08142B9
Est. 1970
May 22, 2005
I
I
I
I
23 62.4 Ll99056-01 WG202676
Limit %Rec Ref Samp Batch I
I
I
I ENVIRONMENTAL
SCIENCE CORP.
I Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109 I Raleigh, NC 27607
Dichlorodifluoromethane
IAnalyte
Quality Assurance Report
Level II
Ll98803
mg/1 0.0284 0.0308 8.32
JJ~~tt~:~.t.E;PJ~~/P:4PJ'I¢~~:it::t Units MSD Res Ref Res RPO
I Batch number /Run number/ Sample number cross reference
WG201948, R233027, Ll98803-01 02 03 04 05 06
I WG201879, R233192, L198803-01 02 03 04 05 06 WG201960, R233264, Ll98803-01 02 03 04 05 06
WG201964, R233308, Ll98803-0l 02 03 04 05 06
WG202275, R233488, Ll98803-0l 02
WG202529, R233557, Ll98803-01 02
I WG202365, R233581, Ll98803-03 04 05 06
WG201992, R233591, Ll98803-01 02 03 04 05 06
WG202651, R233624, Ll98803-05 07
WG202603, R233697, Ll98803-03 WG202676, R233748, Ll98803-06
I WG202661, R233803, Ll98803-06
WG202660, R233808, Ll98803-01 02 03 04 05
WG202859, R234062, Ll98803-04
I
D
D
I
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 22, 2005
25 142. Ll99148 01 WG202859
Limit %Rec Ref Samp Batch
* denotes out of limit range result. See Attachment B of standard report for list of qualifiers.
**Calculations are performed prior to rounding of reported values
Page 47 of 48
ENVIRONMENTAL
SCIENCE CORP.
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.e. 62-0814289
Est. 1970 Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109 Quality Assurance Report
Level II
Raleigh, NC 27607 May 22, 2005 , , .. L198803
ESC Level 2 Data Package
The data package includes a summary of the analytic results of the quality
control samples required by the SW-846 or CWA methods. The quality control
samples include a method blank, a laboratory control sample, and the matrix
spike/matrix spike duplicate analysis. If a target parameter is outside
the method limits, every sample that is effected is flagged with the
appropriate qualifier in Appendix B of the analytic report.
Method Blank -an aliquot of reagent water carried through the
entire analytic process. The method blank results indicate if
any possible contamination exposure during the sample handling,
digestion or extraction process, and analysis. Concentrations of
target analytes above the reporting limit in the method blank are
qualified with the "B" qualifier.
Laboratory Control Sample -is a sample of known concentration
that is carried through the digestion/extraction and analysis
process. The percent recovery, expressed as a percentage of the
theoretical concentration, has statistical control limits
indicating that the analytic process is "in control". If a
target analyte is outside the control limits for the laboratory
control sample or any other control sample, the parameter is
flagged with a "J4" qualifier for all effected samples.
Matrix Spike and Matrix Spike Duplicate -is two aliquots of an
environmental sample that is spiked with known concentrations of
target analytes. The percent recovery of the target analytes
also has statistical control limits. If any recoveries that are
outside the method control limits, the sample that was selected
for matrix spike/matrix spike duplicate analysis is flagged with
either a "JS" or a "J6". The relative percent difference (%RPD) between the matrix spike and the matrix spike duplicate
recoveries is all calculated. If the RPD is above the method
limit, the effected samples are flagged with a "J311 qualifier.
Page 48 of 48
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
R
I
I
I
Piedmont Geologic
6003 Chapel Hill Road Suite I 09
Raleigh,NC 27607
Sample ID Comp/Grab
frlw' ,;;r,-,
l'\>\t.,, (.J
· Ir: A "12. les~ le. -,
Matrix*
GW
GW
GW
GW
GW
GW
GW
GW
GW
Alternate billing information:
Depth Date
r,s-/11 /or
' ,
·Matrix: SS • Soil GW -Groundwater WW -Wastewater DW -Drinking Water OT -Other, ___ _
Rema,ksc Quote#PIEGEO032405S
Relinquished by: (Signature) Date: Time:
o, fll lo, 13/o
ate: 1me:
ate: 1me:
o'io1
o'io7
Ii :23
10 l,~J X :;x;Ji
10 yX:iR X
X
:·Xw X
10 i:x,. X
I -+e-{~X:"' X
10 1·x: X
10 ~X~:} X
··.x:llll X
~X~1t X
'·X-2!!1X
,~,(IX
X:' X
~x•·• X
¥:X:~ X
c.,X:j, X
x~x
tgj X it~~ X
~x~
1;,-x.-1 x 1~xlll1 x
Prepared by:
• ENVIRONMENTAL
SCIENCE CORP.
12065 Lebanon Road
Mt. Juliet, TN 37122
Phone [phone]
FAX [phone]
Remarks/Contaminant Sample# (lab only)
pH ______ _ Temp
Flow _______ Other
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
g
n
0
R
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 13, 2005
Description NC State University
Sample ID MW-17
Collected By JG-SS
Collection Date 05/12/05 08:55
Parameter
Methane
Chloride
Nitrate
Sulfate
Alkalinity
Ethane
Ethene
TOC (Total Organi7 Carbon)
Mercury
Arsenic
Barium
Cadmium
Chromium
Iron,Dissolved
Lead
Manganese
Selenium
Silver
Volatile Organics
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon Tetrachloride
Chlorobenzene i
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #86
Result Det. Limit
BDL 1000
4200 1000
BDL 100 BDL 5000
48000 10000
BDL 1000
BDL 1000
7600 1000
BDL 0.20
BDL 20.
26. 5.0
BDL 5.0
BDL 10.
310 100
BDL 5.0
200 10.
BDL 20. BDL 10.
11000 so.
BDL 50.
BDL · so.
BDL 50.
BDL 50.
BDL 50.
BDL 50.
BDL 50.
BDL 50.
50. 50.
BDL 50.
Det. Limit -Estimated Quantitation Limit(EQL)
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
l-800-767-5859
Fax [phone]
Tax I .D. 62-0814289
Est.. 1970
May 23,2005
ESC Sample#
Site ID
Project #
Units Method
ppb 8015M
ug/1 9056
ug/1 9056
ug/1 9056
ug/1 310.2
ppb 8015M
ppb 8015M
ug/1 9060
ug/1 7470A
ug/1 60108
ug/1 60108
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
Ll98996-0l
2519
Date
05/13/05
05/13/05
05/13/05
05/13/05
05/18/05
05/13/05
05/13/05
05/18/05
05/17/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
Laboratory Certification Numbers:
C-TN-01
Oil.
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
50
50
50
50
50
50
50
50
50
50
50
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
00109, WV -233
Page 1 of 47
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
REPORT OF ANALYSIS
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 13, 2005 Description NC State University Lot #86
Sample ID MW-17
Collected By JG-SS
Collection Date 05/12/05
Parameter
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-Chloropropane
1,2-Dichlorobenzene 1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane 1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
Di-isopropyl ether
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
p-Isopropyltoluene
Methylene chloride
Methyl tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,l-Trichloroethane
l,l,2-Trichloroethane
Trichloroethene
BDL -Below Detection Limit
08:55
Result
BDL
BDL
850
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
160
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
85.
Det. Limit -Estimated Quantitation Limit(EQL)
Det. Limit
50.
50.
50. so.
50. so. so.
50. so.
50. so. so.
50.
50. so.
50.
50. so.
50.
50.
250
50. so.
50.
50.
250
250
250
50.
50.
50.
50. so.
50 .. so.
50. so. so.
Units
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
Laboratory Certification Numbers:
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 23,2005
ESC Sample # Ll98996-01
Site ID
Project # 2519
Method Date
6230D 05/19/05
6230D 05/19/05
6230D 05/19/05
6230D 05/19/05
6230D 05/19/05
6230D 05/19/05
6230D 05/19/05
6230D 05/19/05
6230D 05/19/05
6230D 05/19/05
6230D 05/19/05
6230D 05/19/05
6230D 05/19/05
6230D 05/19/05
6230D 05/19/05
6230D 05/19/05
6230D 05/19/05
6230D 05/19/05
6230D 05/19/05
6230D 05/19/05
6230D 05/19/05
6230D 05/19/05
6230D 05/19/05
6230D 05/19/05
6230D 05/19/05
6230D 05/19/05
6230D 05/19/05
6230D 05/19/05
6230D 05/19/05
6230D 05/19/05
6230D 05/19/05
6230D 05/19/05
6230D 05/19/05
6230D 05/19/05
6230D 05/19/05
6230D 05/19/05
6230D 05/19/05
6230D 05/19/05
C-TN-01
Dil.
50
50 so so so so
50 so so
50
50
50
50 so
50 so so so
50
50
50
50
50 so
50
50 so so
50
50
50
50
50
50
50 so
50 so
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910 00109, WV -233
Page 2 of 47
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 13, 2005 Description NC State University
Sample ID MW-17
Collected By JG-SS Collection Date 05/12/05 08:55
REPORT OF ANALYSIS
Lot #86
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-76 7-5859
Fax [phone]
Tax I.D. 62-0814289
Bat. 1970
May 23,2005
ESC Sample# L198996-01
Site ID
Project# 2519
Parameter Result Det. Limit Units Method Date Oil.
Trichlorofluoromethane BDL 50. ug/1 6230D 1,2,3-Trichloropropane BDL 50. ug/1 62300 1,2,4-Trimethylbenzene BDL 50. ug/1 6230D 1,3,5-Trimethylbenzene BDL 50. ug/1 6230D Toluene BDL 250 ug/1 6230D Vinyl chloride BDL 50. ug/1 6230D Xylenes, Total BDL 150 ug/1 6230D
BDL -Below Detection Limit
Det. Limit -Estimated Quantitation Limit{EQL)
Laboratory Certification Numbers:
AIHA -100789, AL -40660, CA -1-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -RNV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910 Note:
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
C-TN-01
50
50
50
50
50
50
50
00109, WV -233
The reported analytical results relate only to the sample submitted.
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported: 05/23/05 13:28 Printed: 05/23/05 13:30
Page 3 of 47
ENVIRONMENTAL
SCIENCE CORP.
REPORT OF ANALYSIS Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
May 13, 2005 Date Received
Description NC State University Lot #86
Sample ID
Collected By
Collection Date
Parameter
Methane
Chloride
Nitrate
Sulfate
Alkalinity
Ethane
Ethene
MW-171
JG-SS
05/12/05 09:45
TOC (Total Organic Carbon)
Mercury
Arsenic
Barium
Cadmium
Chromium
Iron,Dissolved
Lead
Manganese
Selenium
Silver
Volatile Organics
Benzene
Bromobenzene Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene tert-Butylbenzene
Carbon Tetrachloride
Chlorobenzene
BDL -Below Detection Limit
Result
BDL
2400
BDL BDL
36000
BDL
BDL
BDL
BDL
BDL
17.
BDL
BDL
BDL
BDL
120
BDL BDL
760
BDL BDL
6.5
BDL BDL
BDL
BDL BDL
25.
BDL
Det. Limit -Estimated Quantitation Limit(EQL)
Det. Lim.it
1000
1000
100
5000
10000
1000
1000
1000
0.20
20.
5.0
5.0
10.
100
5.0
10.
20.
10.
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-80 0-767-585 9
Fax [phone]
Tax I.O. 62-0814289
Eet. 1970
May 23,2005
ESC Sample # Ll98996-02
Site ID
Project # 2519
Unite Method Date
ppb 8015M 05/13/05
ug/1 9056 05/13/05
ug/1 9056 05/13/05 ug/1 9056 05/13/05
ug/1 310.2 05/18/05
ppb 8015M 05/13/05
ppb 8015M 05/13/05
ug/1 9060 05/18/05
ug/1 7470A 05/17/05
ug/1 6010B 05/15/05
ug/1 6010B 05/15/05
ug/1 6010B 05/15/05
ug/1 60108 05/15/05
ug/1 60108 05/15/05
ug/1 60108 05/15/05 ug/1 6010B 05/15/05
ug/1 60108 05/15/05
ug/1 60108 05/15/05
ug/1 6230D 05/19/05
ug/1 6230D 05/19/05
ug/1 6230D 05/19/05
ug/1 6230D 05/19/05
ug/1 6230D 05/19/05
ug/1 6230D 05/19/05
ug/1 6230D 05/19/05
ug/1 6230D 05/19/05
ug/1 6230D 05/19/05 ug/1 6230D 05/19/05
ug/1 6230D 05/19/05
Laboratory Certification Numbers:
C-TN-01
Dil.
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
5
5
5
5
5
5
5
5
5
5
5
AIHA -100789, AL -40660, CA -1-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910 00109, WV -233
Page 4 of 47
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
n
0
D
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 13, 2005
Description NC State University
Sample ID MW-171
Collected By JG-SS Collection Date 05/12/05 09:45
Parameter
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-Chloropropane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
Di-isopropyl ether
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
p-Isopropyltoluene
Methylene chloride
Methyl tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #86
Result net. Limit
BDL 5.0
BDL 5.0
680 5.0
BDL 5.0
BDL 5.0
BDL 5.0
BDL 5.0
BDL 5.0
BDL 5.0
BDL 5.0
BDL 5.0
BDL 5.0
BDL 5.0
BDL 5.0
BDL 5.0
BDL 5.0
240 5.0
BDL 5.0
BDL 5.0
BDL 5.0
BDL 25.
BDL 5.0
BDL 5.0
BDL 5.0
BDL 5.0
29. 25.
BDL 25.
BDL 25.
BDL 5.0
BDL 5.0
BDL 5.0
BDL 5.0
BDL 5.0
BDL 5.0
BDL 5.0
BDL 5.0
7.0 5.0
34. 5.0
Det. Limit -Estimated Quantitation Limit(EQL)
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 23,2005
ESC Sample#
Site ID
Project#
Units Method
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
Ll98996-02
2519
Date
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/0S
Laboratory Certification Numbers:
C-TN-01
Dil.
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5·
5
5
5
5
5
5
5
5
5
5
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV37S,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910 00109, WV -233
Page 5 of 47
ENVIRONMENTAL
SCIENCE CORP.
REPORT OF ANALYSIS Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 13, 2005 Description NC State University Lot #86
Sample ID MW-171
Collected By JG-SS
Collection Date 05/12/05 09:45
Parameter Result
Trichlorofluoromethane BDL 1,2,3-Trichloropropane 6.6 1,2,4-Trimethylbenzene BDL 1,3,5-Trimethylbenzene BDL Toluene BDL Vinyl chloride BDL Xylenes, Total BDL
BDL -Below Detection Limit
Det. Limit -Estimated Quantitation Limit(EQL)
Det. Limit
5.0
5.0
5.0
5.0
25.
5.0
15.
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
l-800-767-5859
Fax {615) 758-5859
Tax I.D. 62-0814289
Est. 1970
May 23,2005
Units
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ESC Sample# L198996-02
Site ID
Project# 2519
Method
6230D
6230D
6230D
6230D
6230D
6230D
6230D
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
Laboratory Certification Numbers:
C-TN-01
5
5
5
5
5
5
5
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA 00109, WV -233 AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910 Note:
The reported analytical results relate only to the sample submitted.
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported: 05/23/05 13:28 Printed: 05/23/05 13:30
Page 6 of 47
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
u
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
g
I
ENVIRONMENTAL
SCIENCE CORP.
REPORT OF ANALYSIS Mr. John Harper Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
May 13, 2005 Date Received
Description NC State University Lot #86
Sample ID
Collected By
Collection Date
Parameter
Methane
Chloride
Nitrate
Sulfate
Alkalinity
Ethane
Ethene
MW-17D
JG-SS
05/12/05 10:29
TOC (Total Organic Carbon)
Mercury
Arsenic
Barium
Cadmium
Chromium
Iron,Dissolved
Lead
Manganese
Selenium
Silver
Volatile Organics
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon Tetrachloride
Chlorobenzene
BDL -Below Detection Limit
Result
BDL
1700
BDL
BDL
30000
BDL
BDL
BDL
BDL
BDL
35.
BDL
21.
BDL
BDL
BDL
53.
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
210
BDL
Det. Limit -Estimated Quantitation Limit(EQL)
Det. Limit
1000
1000
100
5000
10000
1000
1000
1000
0.20
20.
5.0
5.0
10.
100
5.0
10.
20.
10.
10.
10.
10.
10.
10.
10.
10.
10.
10.
10.
10.
12065 Lebanon Rd.
Mt. Juliet, TN 37122
(615) 75B-5858
1-800-767-5859
F;u: [phone]
Tax I.O. 62-06142B9
8st. 1970
May 23,2005
ESC Sample # L198996-03
Site ID
Project # 2519
Units Method Date
ppb 8015M 05/13/05
ug/1 9056 05/13/05
ug/1 9056 05/13/05
ug/1 9056 05/13/05
ug/1 310.2 05/18/05
ppb 8015M 05/13/05
ppb 8015M 05/13/05
ug/1 9060 05/18/05
ug/1 7470A 05/17/05
ug/1 6010B 05/15/05
ug/1 6010B 05/15/05
ug/1 6010B 05/15/05
ug/1 60108 05/15/05
ug/1 60108 05/15/05
ug/1 60108 05/15/05
ug/1 6010B
ug/1 60108
05/15/05
05/15/05
ug/1 6010B 05/15/05
ug/1 6230D 05/20/05
ug/1 6230D
ug/1 6230D
05/20/05
05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05 ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D
ug/1 6230D
05/20/05
05/20/05
Laboratory Certification Numbers:
C-TN-01
Dil.
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
10
10
10
10
10
10
10
10
10
10
10
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910 00109, WV -233
Page 7 of 47
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 13, 2005 Description NC State University
Sample ID MW-17D
Collected By JG-SS Collection Date 05/12/05
Parameter
Chlorodibromomethane
Chloroethane Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
l,2-Dibromo-3-Chloropropane 1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
Di-isopropyl ether
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
p-Isopropyltoluene
Methylene chloride
Methyl tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane Trichloroethene
BDL -Below Detection Limit
10:29
REPORT OF ANALYSIS
Lot #86
Result
BDL
BDL
1200
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
54.
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
38.
BDL
BDL
BDL
BDL
63.
Det. Limit
10.
10.
10.
10.
10.
10.
10.
10.
10.
10.
10.
10.
10.
10.
10.
10.
10.
10.
10.
10. so.
10.
10.
10.
10.
50. so.
50.
10.
10.
10.
10.
10.
10.
10.
10.
10.
10.
Det. Limit -Estimated Quantitation Limit{EQL)
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
l-800-767-5859
Fax [phone]B59
Tax I.D. 62-0814289
Est. 1970
May 23,2005
ESC Sample # Ll98996-03
Site ID
Project # 2519
Units Method Date
ug/1 6230D 05/20/05 ug/1 6230D 05/20/05
ug/1 6230D
ug/1 6230D 05/20/05 05/20/05 ug/1 6230D
ug/1 6230D
05/20/05
05/20/05 ug/1 6230D 05/20/05 ug/1 6230D
ug/1 6230D
05/20/05
05/20/05 ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05 ug/1 6230D 05/20/05
ug/1 6230D 05/20/05 ug/1 6230D
ug/1 6230D 05/20/05
05/20/05
ug/1 6230D 05/20/05 ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05 ug/1 6230D 05/20/05
ug/1 6230D 05/20/05 ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05 ug/1 6230D 05/20/05 ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05 ug/1 6230D 05/20/05
ug/1 6230D 05/20/05 ug/1 6230D 05/20/05 ug/1 6230D 05/20/05
ug/1 6230D 05/20/05 ug/1 6230D 05/20/05 ug/1 6230D
ug/1 6230D
05/20/05
05/20/05 ug/1 6230D 05/20/05
Laboratory Certification Numbers:
C-TN-01
Dil.
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910 00109, WV -233
Page 8 of 47
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
n
n
D
D
I
I
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 13, 2005
Description NC State University
Sample ID MW-17D
Collected By JG-SS
Collection Date 05/12/05 10:29
REPORT OF ANALYSIS
Lot #86
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax {615) 758-5859
Tax I.D. 62-0814289
Est. 1970
May 23,2005
ESC Sample# L198996-03
Site ID
Project# 2519
Parameter Result Det. Limit Units Method ===="'----------------==='----'CO"'-'-'===---"=='---'-===----~D~a~t~e=-~~D~il
Trichlorofluoromethane BDL 10. ug/1 1,2,3-Trichloropropane BDL 10. ug/1 1,2,4-Trimethylbenzene BDL 10. ug/1 1,3,5-Trimethylbenzene BDL 10. ug/1 Toluene BDL 50. ug/1 Vinyl chloride BDL 10. ug/1 Xylenes, Total BDL 30. ug/1
BDL -Below Detection Limit
Det. Limit -Estimated Quantitation Limit{EQL)
Laboratory Certification Numbers:
6230D
6230D
6230D
6230D
6230D
6230D
62300
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
C-TN-01
10
10
10
10
10
10
10
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910 Note:
00109, WV -233
The reported analytical results relate only to the sample submitted.
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported: 05/23/05 13:28 Printed: 05/23/05 13:30
Page 9 of 47
I,
ENVIRONMENTAL
SCIENCE CORP.
REPORT OF ANALYSIS Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
May 13, 2005 Date Received
Description NC State University Lot #86
Sample ID
Collected By
Collection Date
Parameter
Methane
Chloride
Nitrate
Sulfate
Alkalinity
Ethane
Ethene
MW-11
JG-SS
05/12/05 10:47
TOC (Total Organic Carbon)
Mercury
Arsenic
Barium
Cadmium
Chromium
Iron,Dissolved
Lead Manganese
Selenium
Silver
Volatile Organics
Benzene
Bromobenzene Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon Tetrachloride
Chlorobenzene
BDL -Below Detection Limit
Result
BDL
2600
770
BDL
44000
BDL
BDL
2400
BDL
BDL
18.
BDL
BDL
BDL
BDL
750
BDL
BDL
BDL
BDL BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL BDL
Det. Limit -Estimated Quantitation Limit(EQL)
Det, Limit
1000
1000
100
5000
10000
1000
1000
1000
0.20
20.
5.0
5.0
10.
100
5.0
10.
20.
10.
10.
10.
10.
10.
10.
10.
10.
10.
10.
10.
10.
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I .0. 62-0814289
Est. 1970
May 23,2005
ESC Sample # Ll98996-04
Site ID
Project # 2519
Units Method Date
ppb 8015M 05/13/05
ug/1 9056 05/13/05
ug/1 9056 05/13/05
ug/1 9056 05/13/05
ug/1 310.2 05/18/05
ppb 8015M 05/13/05
ppb 8015M 05/13/05
ug/1 9060 05/18/05
ug/1 7470A 05/17/05
ug/1 60108 05/15/05
ug/1 60108 05/15/05
ug/1 60108 05/15/05
ug/1 60108 05/15/05
ug/1 60108 05/15/05
ug/1 6010B 05/15/05
ug/1 60108 05/15/05
ug/1 60108 05/15/05
ug/1 60108 05/15/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
Laboratory Certification Numbers:
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Page 10 of 47
C-'I'N-01
00109, WV
I
I
I
I
I
I
Dil.
1
1
1 I
1
1
1 I
1
1
1 I
1
1
1
1 I
1
1
1
1
1 I
10
10
10
10 I
10
10
10
10
10
10 I
10
I
-233 ·1
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 13, 2005 Description NC State University
Sample ID MW-11
Collected By JG-SS Collection Date 05/12/05 10:47
Parameter
Chlorodibromomethane
Chloroethane Chloroform
Chloromethane
2-Chlorotoluene 4-Chlorotoluene
1,2-Dibromo-3-Chloropropane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
Di-isopropyl ether
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
p-Isopropyltoluene
Methylene chloride
Methyl tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #B6
Result Det. Limit
BDL 10.
BDL 10.
1500 10.
BDL 10.
BDL 10.
BDL 10.
BDL 10.
BDL 10.
BDL 10.
BDL 10.
BDL 10.
BDL 10.
BDL 10.
BDL 10.
BDL 10.
BDL 10.
BDL 10.
BDL 10.
BDL 10.
BDL 10.
BDL so.
BDL 10.
BDL 10.
BDL 10.
BDL 10.
BDL so.
BDL 50.
BDL so.
BDL 10.
BDL 10.
BDL 10.
BDL 10.
3B. 10.
BDL 10.
BDL 10.
BDL 10.
BDL 10.
14. 10.
Det. Limit -Estimated Quantitation Limit(EQL)
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 23,2005
ESC Sample#
Site ID
Project#
Units Method
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 62300
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
L198996-04
2519
Date
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
Laboratory Certification Numbers:
C-TN-01
Oil.
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
00109, WV -233
Page 11 of 47
I,
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 13, 2005 Description NC State University
Sample ID MW-11
Collected By JG-SS
Collection Date 05/12/05 10:47
Parameter
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Toluene
Vinyl chloride
Xylenes, Total
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #86
Result Det. Limit
BDL 10.
BDL 10.
BDL 10.
BDL 10.
BDL 50.
BDL 10.
BDL 30.
Det. Limit -Estimated Quantitation Limit(EQL)
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 23,2005
Units
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ESC Sample# L198996-04
Site ID
Project# 2519
Method
6230D
6230D
6230D
6230D
6230D
6230D
6230D
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
Laboratory Certification Numbers:
C-TN-01
10
10
10
10
10
10
10
AIHA -100789, AL -40660, CA -1-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -B4004, TN -2006, VA 00109, WV -233
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Note:
The reported analytical results relate only to the sample submitted.
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported: 05/23/05 13:28 Printed: 05/23/05 13:30
Page 12 of 47
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
ENVIRONMENTAL
SCIENCE CORP.
REPORT OF ANALYSIS Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
May 13, 200s Date Received
Description NC State University Lot #86
Sample ID
Collected By
Collection Date
Parameter
Methane
Chloride
Nitrate
Sulfate
Alkalinity
Ethane
Ethene
. MW-121
JG-SS
05/12/05 11: 14
TOC (Total Organic ci3.rbon)
Mercury
Arsenic Barium
Cadmium
Chromium
Iron,Dissolved
Lead
Manganese Selenium
Silver
Volatile Organics
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform.
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon Tetrachloride
Chlorobenzene
BDL -Below Detection Limit
Result·
BDL
1900
170
BDL
27000
BDL
BDL
BDL
BDL
OUL
7.4
BDL
BDL
BDL
BDL
73.
BDL
BDL
BpL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
54.
BDL
Det. Limit -Estimated Quantitation Limit(EQL)
Det. Limit
1000
1000
100
5000
10000
1000
1000
1000
0.20
20.
5.0
5.0
10.
100
5.0
10.
20.
10.
50.
50.
50.
50.
50.
50. so.
50.
50.
50. so.
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767~5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 23,2005
ESC Sample#
Site ID
_Project #
Units 'Method
ppb 8015M
ug/1 9056
ug/1 9056
ug/1 9056
ug/1 310.2
ppb 8015M
ppb 8015M
ug/1 9060
ug/1 7470A
ug/1 60108
ug/1 60108
ug/1 6010B
ug/1 60108
ug/1 6010B
ug/1 6010B
ug/1 60108
ug/1 6010B
ug/1 60108
ug/1 6230D
ug/1 6230D ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
L198996-05
2519
Date
05/13/05
05/13/05
05/13/05
05/13/05
05/18/05
05/13/05
05/13/05
05/18/05
05/17/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/20/05 ·
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
Laboratory Certification Numbers:
C-TN-01
Dil.
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
50
50
50
50
50
50
50
50
50
50
50
AIHA -100789, AL -40660, CA -1-2327, CT-PH-0197, FL -EB7487, GA -923, IN
KY -90010, K':ruST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
00109, WV -233
Page 13 of 47
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 13, 2005 Description NC State University
Sample ID MW-121
Collected By JG-SS
Collection Date 05/12/05 11: 14
Parameter
Chlorodibromomethane
Chlo roe thane
Chloroform
Chloromethane
2-Chlorotoluene·
4-Chlorotoluene
1,2-Dibromo-3-Chloropropane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-0ichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
Di-isopropyl ether
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
p-Isopropyltoluene
Methylene chloride
Methyl tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #86
Result Det. Limit
BDL 50.
BDL 50.
4200 50.
BDL 50.
BDL 50.
BDL 50.
BDL 50.
BDL so.
BDL 50.
BDL so.
BDL 50.
BDL 50.
BDL 50.
BDL 50.
BDL 50.
BDL so.
BDL 50.
BDL 50.
BDL . 50.
BDL so.
BDL 250
BDL 50.
BDL 50.
BDL 50.
BDL so.
BDL 250
BDL 250
BDL 250
BDL 50.
BDL 50.
BDL 50.
BDL 50.
91. 50.
BDL 50.
BDL 50.
BDL 50.
BDL 50.
llO 50.
Det. Limit -Estimated Quantitation Limit(EQL)
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax l.D. 62-0814289
Est. 1970
May 23,2005
ESC Sample#
Site ID
Project#
Units Method
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 62300
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
L198996-05
2519
Date
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
Laboratory Certification Numbers:
C-TN-01
Dil.
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50 so
50
50
50 so
50
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
00109, WV -233
Page 14 of 47
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
D
D
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 13, 2005
Description NC State University
Sample ID MW-121
Collected By JG-SS
Collection Date 05/12/05 11:14
Parameter
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Toluene
Vinyl chloride
Xylenes, Total
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #86
Result Det. Limit
BDL 50.
BDL so.
BDL 50.
BDL 50.
BDL 250
BDL 50.
BDL 150
Det. Limit -Estimated Quantitation Limit(EQL)
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax {615) 758-5859
Tax I.D. 62-0814289
Est. 1970
May 23,2005
ESC Sample# L198996-05
Site ID
Project# 2519
Units Method Date Oil.
ug/1 6230D 05/20/05 50
ug/1 6230D 05/20/05 50 ug/1 62300 05/20/05 so ug/1 6230D 05/20/05 50
ug/1 6230D 05/20/05 50 ug/1 6230D 05/20/05 50
ug/1 6230D 05/20/05 50
Laboratory Certification Numbers:
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Note:
The reported analytical results relate only to the sample submitted.
C-TN-01
00109, WV -233
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported: 05/23/05 13:28 Printed: 05/23/05 13:30
Page 15 of 47
ENVIRONMENTAL
SCIENCE CORP.
REPORT OF ANALYSIS Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
May 13, 2005 Date Received
Description NC State University Lot #86
Sample ID
Collected By
Collection Date
Parameter
Methane
Chloride
Nitrate
Sulfate
Alkalinity
Ethane
Ethene
MW-36D
JG-SS
05/12/05 11: 51
TOC (Total Organic Carbon)
Mercury
Arsenic
Barium Cadmium
Chromium
Iron,Dissolved
Lead
Manganese
Selenium
Silver
Volatile Organics
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon Tetrachloride
Chlorobenzene
BDL -Below Deteption Limit
Result
BDL
3000
BDL
BDL
39000
BDL
BDL
BDL
BDL
BDL
8.2
BDL
BDL
BDL
BDL
23.
30.
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
Det. Limit -Estimated Quantitation Limit(EQL)
Det. Limit
1000
1000
100
5000
10000
1000
1000
1000
0.20
20.
5.0
5.0
10.
100
5.0
10.
20.
10.
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
12065 Lebanon Rd.
Mt. Juliet, TN 37122
(615) 758-5B58
l-800-767-5859
Fax [phone]
Tax I .D. 62-0814289
Est. 1970
May 23,2005
ESC Sample # L198996-06
Site ID
Project # 2519
Units Method Date
ppb 8015M 05/13/05
ug/1 9056 05/13/05
ug/1 9056
ug/1 9056
05/13/05
05/13/05
ug/1 310.2 05/18/05
ppb 8015M 05/13/05
ppb 8015M 05/13/05
ug/1 9060 05/18/05
ug/1 7470A 05/17/05
ug/1 60108 05/15/05
ug/1 60108 05/15/05
ug/1 60108 05/15/05
ug/1 60108 05/15/05
ug/1 60108 05/15/05
ug/1 60108 05/15/05
ug/1 60108 05/15/05
ug/1 6010B 05/15/05
ug/1 60108 05/15/05
ug/1 6230D
ug/1 6230D
05/20/05
05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D
ug/1 6230D
ug/1 6230D
05/20/05
05/20/05
05/20/05
ug/1 6230D
ug/1 6230D
05/20/05
05/20/05
ug/1 6230D 05/20/05
Laboratory Certification Numbers:
C-TN-01
Oil.
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
00109, WV -233
Page 16 of 47
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
m
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 13, 2005
Description 'NC State University
Sample ID MW-36D
Collected By JG-SS
Collection Date 05/12/05 11:51
Parameter
Chlorodibromometha~e
Chloroethane
Chlorofonn
Chloromethane 2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-Chloropropane
1,2-Dichlorobenzene
1,3-Dichlorobenzeile
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropahe
2,2-Dichloropropane
1,1-Dichloropropene
Di-isopropyl ether
Ethylben2ene
Hexachlorobutadiene
Isopropylben2ene
p-Isopropyltoluene
Methylene chloride
Methyl tert-butyl ether
Naphthalene
n-Propylben2ene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #86
Result Det. Limit
BDL 1.0
BDL 1.0
26. 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
28. 1.0
BDL 1.0
BDL 1.0
BDL 1.0
8DL 5.0
BDL 1.0
BDL 1.0
BDL 1.0 BDL · 1.0
BDL 5.0
BDL 5.0
BDL 5.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
4.9 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0 7.1 1.0
Det. Limit -Estimated Quantitation Limit(EQL)
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax l.D. 62-0814289
Est. 1970
May 23,2005
ESC Sample#
Site ID
Project#
Units Method
ug/1 6230D
ug/1 6230D
ug/1 6230D ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
L198996-06
2519
Date
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05 05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
Laboratory Certification Numbers:
C-TN-01
Oil.
l
l
l
l
l
l
l
l
l
l
l
l
l
l
l
l
l
l
l
l
l
l
l
l
l
l
l
l
l
l
l
l
l
l
l
l
l
l
AIHA -100789, AL -40660, CA -1-2327, CT-PH-0197, FL -B87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
00109, WV -233
Page 17 of 47
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 13, 2005 Description NC State University
Sample ID MW-36D
Collected By JG-SS Collection Date 05/12/05 11:51
Parameter
Trichlorofluoromethane
1,2,3-Trichloropropane 1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Toluene
Vinyl chloride
Xylenes, Total
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #86
Result Det. Limit
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 5.0
BDL 1.0
BDL 3.0
Det. Limit -Estimated Quantitation Limit(EQL)
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 23,2005
ESC Sample# L198996-06
Site ID
Project# 2519
Units Method Date Dil.
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D ug/1 6230D
ug/1 6230D
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
1
1
1
l
1
1
1
Laboratory Certification Numbers:
C-TN-01 AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA 00109, WV -233
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Note:
The reported analytical results relate only to the sample submitted.
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported: 05/23/05 13:28 Printed: 05/23/05 13:30
Page 18 of 47
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
g
D
u
I
D
I
I
I
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 13, 2005
Description NC State University
Sample ID MW-6
Collected By JG-SS
Collection Date 05/12/05 12:15
Parameter
Methane
Chloride
Nitrate
Sulfate
Alkalinity
Ethane
Ethene
TOC (Total Organic Carbon)
Mercury
Arsenic
Barium
Cadmium
Chromium
Iron,Dissolved
Lead
Manganese
Selenium
Silver
Volatile Organics
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
8romomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon Tetrachloride
Chlorobenzene
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #86
Result Det. Limit
BDL 1000
41000 1000
BDL 100
BDL 5000
36000 10000
BDL 1000
BDL 1000
7700 1000
BDL 0.20
BDL 20.
390 5.0
BDL 5.0
BDL 10.
BDL 100
BDL 5.0
6400 10.
21. 20.
BDL 10.
90. 10.
BDL 10.
BDL 10.
1200 10.
BDL 10.
BDL 10.
BDL 10.
BDL 10.
BDL 10.
450 10.
11. 10.
Det. Limit -Estimated Quantitation Limit(EQL)
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5B59
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 23,2005
ESC Sample#
Site ID
Project#
units Method
ppb 8015M
ug/1 9056
ug/1 9056
ug/1 9056
ug/1 310.2
ppb 8015M
ppb 8015M
ug/1 9060
ug/1 7470A
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 60108
ug/1 6010B
ug/1 60108
ug/1 6010B
ug/1 6010B
ug/1 60108
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
Ll98996-07
2519
Date
05/13/05
05/13/05
05/13/05
05/13/05
05/18/05
05/13/05
05/13/05
05/18/05
05/17 /05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/15/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
Laboratory Certification Numbers:
C-TN-01
Dil.
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
10
10
10
10
10
10
10
10
10
10
10
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
K'l -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
00109, WV -233
Page 19 of 47
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 13, 2005
Description NC State University
Sample ID MW-6
Collected By JG-SS
Collection Date 05/12/05
Parameter
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane 2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-Chloropropane
1,2-Dichlorobenzene 1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane 1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
Di-isopropyl ether
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
p-Isopropyltoluene
Methylene chloride
Methyl tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
BDL -Below Detection Limit
12 :15
REPORT OF ANALYSIS
Lot #86
Result
BDL
BDL
9500
BDL
BDL
BDL
33.
53.
BDL
BDL
BDL
BDL
ll0
11.
BDL
BDL
3000
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
370
BDL
BDL
BDL
BDL
BDL
15.
240
BDL
BDL
13.
BDL
350
Det. Limit
10.
10.
10.
10.
10.
10.
10.
10.
10.
10.
10.
10.
10.
10.
10.
10.
10.
10.
10.
10.
50.
10.
10.
10.
10.
50.
50.
50.
10.
10.
10.
10.
10.
10.
10.
10.
10.
10.
Det. Limit -Estimated Quantitation Limit(EQL)
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 23,2005
ESC Sample # L198996-07
Site ID
Project # 2519
Units Method Date
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05 ug/1 62300 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05 ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
Laboratory Certification Numbers:
C-TN-01
Oil.
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
AIHA -1007B9, AL -40660, CA -I-2327, CT-PH-0197, FL -EB7487, GA -923, IN
K'f -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
00109, WV -233
Page 20 of 47
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
0
D
I
I
I
ENVIRONMENTAL
SCIENCE CORP.
REPORT OF ANALYSIS Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109 Raleigh, NC 27607
May 13, 2005 Date Received
Description NC State University Lot #86
Sample ID
Collected By
Collection Date
MW-6
JG-SS
05/12/05 12: 15
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene Toluene
Vinyl chloride
Xylenea, Total
BDL -Below Detection Limit
BDL
22.
BDL
BDL
BDL
BDL
BDL
Det. Limit -Estimated Quantitation Limit(EQL)
10.
10.
10.
10.
50.
10.
30.
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Eat. 1970
May 23,2005
ESC Sample# Ll98996-07
Site ID
Project# 2519
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
· 6230D
62300
6230D
6230D
6230D
6230D
6230D
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
Laboratory Certification Numbers:
C-TN-01
10
10
10
10
10
10
10
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA 00109, WV -233
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Note:
The reported analytical results relate only to the sample submitted.
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported: 05/23/05 13:28 Printed: 05/23/05 13:30
Page 21 of 47
ENVIRONMENTAL
SCIENCE CORP.
REPORT OF ANALYSIS
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
May 13, 2005 Date Received
Description NC State University Lot #86
Sample ID
Collected By Collection Date
Parameter
Volatile Organics
Benzene
TRIP BLANK
JG-SS
05/12/05 00: 00
Bromobenzene
Bromochloromethane Bromodichloromethane
Bromoform
Bromomethane n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon Tetrachloride
Chlorobenzene
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-ChlorotOluene
1,2-Dibromo-3-Chloropropane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
Di-isopropyl ether
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
p-Isopropyltoluene
Methylene chloride
BDL -Below Detection Limit
Result
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
Det. Limit -Estimated Quantitation Limit(EQL)
Det. Limit
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
l-800-767-5859
Fax [phone]
Tax 1.0. 62-0814289
Est. 1970
May 23,2005
ESC Sample # Ll98996-08
Site ID
Project # 2519
Units Method Date
ug/1 6230D 05/19/05
ug/1 6230D 05/19/05
ug/1 6230D
ug/1 6230D
05/19/05
05/19/05
ug/1 6230D 05/19/05
ug/1 6230D 05/19/05
ug/1 6230D 05/19/05
ug/1 6230D 05/19/05
ug/1 6230D
ug/1 6230D
05/19/05
05/19/05
ug/1 6230D 05/19/05
ug/1 6230D 05/19/05
ug/1 6230D 05/19/05
ug/1 6230D 05/19/05
ug/1 6230D 05/19/05
ug/1 6230D 05/19/05
ug/1 6230D
ug/1 6230D
05/19/05
05/19/05
ug/1 6230D 05/19/05
ug/1 6230D 05/19/05
ug/1 6230D 05/19/05
ug/1 6230D 05/19/05
ug/1 6230D
ug/1 6230D
05/19/05
05/19/05
ug/1 6230D 05/19/05
ug/1 6230D 05/19/05
ug/1 6230D 05/19/05
ug/1 6230D 05/19/05
ug/1 6230D 05/19/05
ug/1 6230D 05/19/05
ug/1 6230D
ug/1 6230D
ug/1 6230D
05/19/05
05/19/05
05/19/05
ug/1 6230D 05/19/05
ug/1 6230D 05/19/05
ug/1 6230D
ug/1 6230D
05/19/05
05/19/05
Laboratory Certification Numbers:
C-TN-01
Dil.
1
1
1
1
1
1
1
1
1
1
l
l
1
1
1
1
l
l
1
l
1
1
1
l
1
1
1
1
1
1
1
1
1
1
1
1
1
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
00109, WV -233
Page 22 of 47
I
I
I
I
I
I
I
I
I
I
I
I
I
B
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
ENVIRONMENTAL
SCIENCE CORP.
REPORT OF ANALYSIS
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
May 13, 2005 Date Received
Description NC State University Lot #86
Sample ID
Collected By
Collection Date
Parameter
Methyl tert-butyl
Naphthalene
n-Propylbenzene
Styrene
TRIP BLANK
JG-SS
05/12/05 00:00
ether
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Toluene
Vinyl chloride
Xylenes, Total
BDL -Below Detection Limit
Result
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
Det. Limit -Estimated Quantitation Limit(EQL)
Det. Limit
5.0
5.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
3. 0
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
l-800-767-5859
Fax [phone]B59
Tax I.D. 62-0814289
Est. 1970
May 23,2005
ESC Sample#
Site ID
Project#
units Method
ug/1 6230D
ug/1 6230D
ug/1 62300
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
Ll9B996-0B
2519
Date
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
05/19/05
· Laboratory Certification Numbers:
C-TN-01
Oil.
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA 00109, WV -233
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Note:
The reported analytical results relate only to the sample submitted.
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported: 05/23/05 13:28 Printed: 05/23/05 13:30
Page 23 of 47
Sample#
L198996-01
L198996-02
L198996-03
Ll98996-04
L198996-05
Ll98996-07
Attachment A
List of Analytes with QC Qualifiers
Analyte
Benzene
Dichlorodifluoromethane
Benzene
Chloroform
Dichlorodifluoromethane Chloroform
1,1-Dichloroethene
Chloroform
1,1-Dichloroethene Chloroform
1,1-Dichloroethene
Bromodichloromethane
1,2-Dichloropropane
Qualifier
E
J4
E
E
J4
E
J3
E
J3
E
J3
E
E
Page 24 of 47
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Qualifier
E
J3
J4
Attachment B
Explanation of QC Qualifier Codes
Meaning
GTL (EPA) -Greater than upper calibration limit: Actual value is known to
be greater than the upper calibration range.
The associated batch QC was outside the established quality control range
for precision.
The associated batch QC was outside the established quality control range
for accuracy.
Qualifier Report Information
ESC utilizes sample and result qualifiers as set forth by the EPA Contract Laboratory Program and
as required by most certifying bodies including NELAC. In addition to the EPA qualifiers adopted
by ESC, we have implemented ESC qualifiers to provide more information pertaining to our analytical
results. Each qualifier is designated in the qualifier explanation as either EPA or ESC. Data qualifiers are intended to provide the ESC client with more detailed information concerning
the potential bias of reported data. Because of the wide range of constituents and variety of
matrices incorporated by most EPA methods,it is common for some compounds to fall outside of
established ranges. These exceptions are evaluated and all reported data is valid and useable
unless qualified as 'R' (Rejected).
Definitions Accuracy -The relationship of the observed value of a known sample to the
true value of a known sample. Represented by percent recovery and
relevant to samples such as: control samples, matrix spike recoveries,
surrogate recoveries, etc.
Precision The agreement between a set of samples or between duplicate samples.
Surrogate -
Relates to how close together the results are and is represented by
Relative Percent Differrence.
Organic compounds that are similar in chemical composition, extraction,
and chiomotography to analytes of interest. The surrogates are used to
determine the probable response of the group of analytes that are chem-
ically related to the surrogate compound, Surrogates are added to the
sample and carried through all stages of preparation and analyses.
Control Limits (AQ)
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
31-119
12-134
51-141
Nitrobenzene-d5 43-118 Dibromfluoromethane 70-130
2-Fluorobiphenyl 45-128 Toluene-dB 70-130
Terphenyl-d14 43-137 4-Bromofluorobenzene 70-130
TIC Tentatively Identified Compound: Compounds detected in samples that are
not target compounds, internal standards, system monitoring compounds,
or surrogates.
(SS)
70-130
70-130
70-130
Page 25 of 47
I
Summary of Remarks For Samples Printed 05/23/05 at 13:30:48 I
TSR Signing Reports: 064 RS -Desired TAT I
Sample: L19B996-01 Account: PIEGEO Received: 05/13/05 07:30 Due Date: 05/20/05 00:00 RPT Date: 05/23/0S 13:28 Sample: L198996-02 Account: PIEGEO Received: 05/13/05 07:30 Due Date: 05/20/05 00:00 RPT Date: 05/23/05 13:28 I Sample: L198996-03 Account: PIEGEO Received: 05/13/05 07:30 Due Date: 05/20/05 00:00 RPT Date: 05/23/0S 13 :28 Sample: L198996-04 Account: PIEGEO Received: 05/13/05 07:30 Due Date: 05/20/05 00:00 RPT Date: 05/23/05 13 :28 Sample: Ll98996-05 Account: PIEGEO Received: 05/13/05 07:30 Due Date: 05/20/05 00:00 RPT Date: 05/23/05 13:28 I Sample: L198996-06 Account: PIEGEO Received: 05/13/05 07:30 Due Date: 05/20/05 00:00 RPT Date: 05/23/05 13 ~28 Sample: L198996-07 Account: PIEGEO Received: 05/13/05 07:30 Due Date: 05/20/05 00:00 RPT Date: 05/23/05 13:28 Sample: L198996-08 Account: PIEGEO Received: 05/13/05 07:30 Due Date: 05/20/05 00:00 RPT Date: 05/23/05 13: 28
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
ENVIRONMENTAL
SCIENCE CORP.
Piedmont Geologic Mr. John Harper
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Analyte
TOC (Total Organic Carbon);
Ethane
Etherie
Methane
Arse"nic Barium
Cadmium
ChrOrriiUm, Lead
Manganese
Seleniii.m Sil'Ve"r
Chloi"ide Nitrate·
Sulfate
Iron,Disso1Vea
Mercury.
TOC (Total Organic Carbon)
Alkalinity
1,1,1,2-Teti-achloroethane
1, 1, 1-Trichloroethan·e
1,1,2,2-Tetrachloroethane
1, 1, 2-.Tri'chlor0€.t:.hahe ,·!
1,1-Dichloroethane 1,1-Dichloroethene
1,:1-Dich~orcipl'."opene ·.".
1,2,3-Trichlorobenzene
1, 2, 3-Trichlor_opropane
1·, 2, 4-Trichlorobe:nzerl.e
1,2,4-Tifmethylbenzene
1,2-Dibromo-3-Chloropropane
1,2-Dichl'oiobE!nzerie .. ' · · !
1, 2:..oichloi-oethane •·
1,2-Dichloropropane
1', 3, 5,-Triniethylbenzene•,
1,3-Dichlorobenzene
1,3-Dichloropropane
1\ 4-Dichloicibeilzene
2, 2-Dichlorop·ropa.ne
2-Chlorotoluene
4~ChlOr6tOltiE!ri."e
Benzene
Bromobenzene
Bromochloromethane
Bromodichlorom·ethari.e
Bromoform
Bromomethane
Carbon Tetrachloride
Chlorobenzene
Chlorodibromomethane
Chloroetha"ne
Chloroform
Quality Assurance Report
Level II
L198996
Laboratory Blank
Result Units Date Analyzed
<(l mg/1 05/17/05 20:33
< .01 ppm 05/13/05 00:00 < 1 ·:01 ppm 05/13/05 oo"': oo < .01 ppm 05/13/05 00:00
~: .02 mg/1 05/15/05 10:37 < .005 mg/1 05/15/05 10:37 < .005 mg/1 05/15/05 10:37 '< 1•• 01,_, ing/1 05/15/05~ 10J37 < .005 mg/1 05/15/05 10:37 < .01 mg/1 05/15/05 10:37 ~< :.·02 mg/1· 05/15/05· 10,!37 < .01 mg/1 05/15/05 10 :37
< 1 mg/1 05/13/05 18:25 < .1 mg/1 05/13/05 18:25 < 5 mg/1 05/~3/05 18:25
< '.1 mg/1 os/15/05 00:51
< ·.0002 mg/1-·05/17/05 18:15
< 1 mg/1 05/18/05 22:23
,_ ...
< 10 mg/1 05/18/05 16:00
< 1• 001· mg/1 05/19/05/12:10· < .001 mg/1 05/19/05 12:10 < .001 mg/1 05/19/05 12:10 '< .{:001. mg/1' ·05/19/05 12:10 < .001 mg/1 05/19/05 12:10 < .001 mg/1 05/19/05 12:10 < ·. 001 ;mg/1 _05/19/.05', 12: 10 < . o"o1 mg/1 05/19/05 12:10 < .001 mg/1 05/19/05 12:10 < ·. 001' mg/1 05/19/05-12:10:." < .001 mg/1 05/19/05 12:10 < .002 mg/1 05/19/05 12:10
.< '! 001' ing/1 ., 05/19/05~1~:10. < ;001 mg/1 05/19/05 12:10 < .001 mg/1 05/19/05 12:10 ,c' . ooi:-: .ITlg/1'' 05/1.9/05 12·:·10 < .001 mg/1 05/19/05 12:10 < .001 mg/1 05/19/05 12:10 . ~· :001 mg/1 ·05/-19/05·· 12: 10 < :001 mg/1 05/19/05 12: 10 < .001 mg/1 05/19/05 12:10 < . 001. · mg/1 05/19/05 ·12: 10· < .001 mg/1 05/19/05 12:10 < .001 mg/1 05/19/05 12:10 < •1001 mg/1 05/19/05 _;,12: 10
< :001 mg/1 ·05/19/05 12,10 < .001 mg/1 05/19/05 12:10 < •1001 mg/1 05/19/05 12:10 < .001 mg/1 05/19/05 12:10 < .001 mg/1 05/19/05 12:10 < .001 mg/1 05/1'9/05 12:10 < .001 mg/1 05/19/05 12:10 < .005 mg/1 05/19/05 12:10
Page 26 of 47
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
l-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 23, 2005
Batch
'WG201994
WG202007
.. WG202007
WG202007
WG202030
WG202030
WG202030 ,:WG202030
WG20203.0
WG202030
WG202030
WG202030
WG202036 ·
WG202036
WG202036
WG202097
'WG202457·
WG202605
wG202663
WG202676
WG202676
WG202676
WG20267,6.
WG202676
WG202676
·WG202676
WG202676
WG202676
WG20267,6
WG202676
WG202676
WG202676
WG202676
WG202676
WG202676
WG202-676
WG202676
WG2026_7.6
WG202676
WG202676
WG202676
WG202676
WG202676
WG202676
WG202676
WG202676
WG202676
WG202676
WG202676
WG202676
WG202676
WG202676
ENVIRONMENTAL
SCIENCE CORP.
Piedmont Geologic Mr. John Harper
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Chloromethane,
Analyte
cis-1,2-Dichloroethene
Di-isoproPyl ether
Dichlorodifluoromethane
Eth)'lbenzene,. ·.
Hexachlorobutadiene Isopropylbenzene
Methyl t.ert-butrl ,ether Methylene chloride
n-Butylbenze_ne
n-_Propylbenzene .
Naphthalene
p-Isopropyltoluene
seC-Butylbeniene· Styrene
tert-Butylbenzene
Tetrachloiciethene Toluene
trans-1,2-Dichloroethene Trichloroethene · '·'
Trichlorofluoromethane
Vinyl chloride
Xylenes, Total_
1,1,1,2-Tetrachloroethane
1, 1, 1;:'TriCh:)..oroethane .. "
1,1,2,2-Tetrachloroethane
1,1,2-Trichloroethane
1, 1-DichlOrciethaiie
1,1-Dichlorciethene
1, 1-Dichloroprop_ene
1, 2, 3-TrichlorOberiz'ene ·
1,2,3-Trichloio}?rol)ane
1,2,4-Trichlorobenzene
1, 2, 4-Trime_thylben·zene:
1,2-Dibromo-3-Chloropropane
1,2-Dichlorobenzene
1, 2-'Dichlo_i:-o_ethahe[.•,
1,2-Dichloropropane
1,3,5-Trimethylbenzene
1, 3-Dichl"o'robe"nz·e_ne'·, ·
1,3-Dichloroproparie
1,4-Dichlorobenzene
2';2-:-Dichl6roj;>i-6p·an·e: .: ,
2-Chlorotoluene
4-Chlorotoluene
Berizerie"., · ·, ," · '.·
s·romobenzene
Bromochloromethane
BromodichlorolTlethane
Bromofcirin
Bromomethane
Carbon Tetiachloride"
Chlorobenzerie -
Chlorodibromomethane
Chloroethane
Chlorof6rm
Chloromethane
cis-1,2-Dichloroethene
Di-isopropyl ether
Quality Assurance Report
Level II
< • 001
Result
< . 001
< .001
< .001
< :001
< .001
< .001
< .:001
< . 0·05
< .001
< .001.
< .005
< .001
< :001
< .001
< .001
. < ·. 001
< .005
< .001
< :001
< .001
< .001
< .003
< .001
< .001
< .001
< .001 < .001
< .001
< .001 < .001·
< :001
< .001
'< . 001··
< .002
< .001
·< .001
< .001
< .001 · .• •; <<.,. :001·
< .001
< .001
.. ",'< ; OOli.
< .001
< .001
•< :·001.
< .001
< .001
< .001
< .001
< .001
'< .001
< .001
< .001
< .001
< .005
< .001
< .001
< .001
Ll98996
mg/1 05/19/05 12:10
Laboratory Blank
Units Date Analyzed
mg/1 05/19/05 12: 10 . mg/1 05/19/05 12:10 mg/1 05/19/05 12:10 mg/1 05/19/05 12:10.\'. mg/1 05/19/05 12:10 mg/1 05/19/05 12:10 'mg/1 05/19/05.'12 i 10 mg/1 05/19/05 12:10 mg/1 05/19/05 12:10 ",mg/1 05/19/05 12 :·10. mg/1 05/19/05 12:10 mg/1 05/19/05 12:10 mg/1 '05/19/05. 12: 10 mg/1 05/19/05 12:10 mg/1 05/19/05 12:10 mg/1 ·05/19/05, 12: 10
mg/1 05/19/05 12:10 mg/1 05/19/05 12:10 mg/1 05/19/05 12:10 mg/1 05/19/05 12: fo mg/1 05/19/05 12:10 mg/1 . 05/1~/05-_12: 10
mg/1 05/19/05 13:02 mg/1 .. 05/19/05 13,: 02 mg/1 05/19/05 13:02 mg/1 05/19/05 13:02 mg/1 05/19/05 13: 02 mg/1 05/19/05 13:02 mg/1 05/19/05 13: 02 ·mg/1 05/19/05 ,13: 02 mg/1 05/19/05 13: 02 mg/1 05/19/05 13: 02
mg/1 05/19/05 13··: 02 mg/1 05/19/05 13 :02 mg/1 05/19/05 13:02
'mg/1 05/19/05 13':'02
mg/1 05/19/05 13:02 mg/1 05/19/05 13:02 ·,mg/1 05/.19/05' 13:! 02·
mg/1 05/19/05 13: 02 mg/1 05/19/05 13: 02 ing/1 · ,05/1_9/05 ·:13: 02 . mg/1 05/19/05 13,02 mg/1 05/19/05 13: 02 mg/1 05/19/0_5--·13:: 02 mg/1 05/19/05 13: 02 mg/1 05/19/05 13: 02 ,mg/1 05/19/05 ·13 :'02 mg/1 05/19/05 13 :02 mg/1 05/19/05 13,02 mg/1 05/19/05 13 ,02 mg/1 05/19/05 13 :02 mg/1 05/19/05 13: 02 ing/1 05/19/05 13·: 02 mg/1 05/19/05 13: 02
mg/1 05/19/05 13: 02 mg/1 05/19/05 13: 02 mg/1 05/19/05 13: 02
Page 27 of 47
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 23, 2005
WG202676
Batch
WG202676
WG202676
WG202676
;WG202676 ·
WG202676
WG202676
,-WG2_0_2676 ..
WG202676
WG202676
WG202676
WG202676
WG202676
WG202676
WG202676
WG202676
WG202676
WG202676
WG202676
WG202676
WG2026i6.
WG202676
WG202676
WG202859
WG202859
WG202859
WG202859
WG202859
WG202859
WG202859
WG202859
WG202859
WG202859
WG202859.
WG202859
WG202859
WG202859
WG202859
WG202859
WG202859
WG202859
WG202859
WG202859
WG202859
WG202859
WG202859
WG202859
WG202859
WG202859
WG202859
WG202859
WG202859
WG202859
WG202859
WG202859
WG202859
WG202859
WG202859
WG202859
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
D
D
I
I
I
ENVIRONMENTAL
SCIENCE CORP.
Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Dichlorodifluoromethane
Analyte
Ethylbep.zene .
Hexachlorobutadiene
Isohropylbenzene Met yl t€(rt:..butrl-ether
Methylene chloride n-Butylbenz_ene n-Propylbenzene ,,
Naphthalene
p-Isoprolb!~ol~~~e sec-Buty enzene.-·•·
Styrene
tert-Butylbenzene
Tetrachloroethene'.
Toluene
trans-1,2-Dichloroethene
Trichloroethene ,,
Trichloiofluoromethane
Vinyl_ chloride
Xyle"nes., · Toti3.l
1,1,1,2-Tetrachloroethane 1·,·l·,·l~Trichloroet_hane.
1,1,2,2-Tetrachloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane ., . l,l-Dichl0i6ethene
1,1-Dichloropropene
1, 2•;3 '.:.Trichlorobenzerie
1,2,3-TrichlorciproPane
1,2,4-Trichlorobenzene
1, 2 ,.4_-1_iJ:I!lethYlbenZ-enif .
1,2-Dibromo-3-Chloropropane
1,2-Dichlorobenzene 1, 2..:oichlOroethane ,• :·
1,2-Dichloropropane
1, 3, 5-Tri_methylbenzene
1;3-Dichl(frobenzene ;"" ~
1,3-Dichlorobropane 1,4-Dichloro enzene
2, 2~Dichloropropane:-, .. .
2-Chlorotoluene
4-Chlorotoluene Benierie/ ':_;·-::-,··
Bromobenzene
Bromochloromethane BrOmodichloroinetha:ne '
Bromoforin
Bromomethane
Cil.l."bon Tetrachloride
ChlorObenZene
Chlorodibromomethane
Chloioethane · ' Chloroform
Chloromethane
ci_s-1, 2-Dichloroethene
Di-isopro~yl ether
Dichlorodifluoromethane
Ethylbenzene
Hexachlorobutadiene
Quality Assurance Report
Level II
L198996
< .001 mq/1 05/19/05 13: 02
Result Laboratory·Blank
Units Date Analyzed
< .001 mg/1 05/1.9/05 13·: 02 < .001 mg/1 05/19/05 13: 02
< .001 mg/1 05/19/05 13: 02 ,< · ;oor mg/1 05/19/05 '13·: 02
< .oos mg/1 05/19/05 13 :02
< .001 mg/1 05/19/05 13 :02
,'.< ·:001·-, ,mg/1 05/19/05 ·13 :02
< .005 mg/1 05/19/05 13:02
< .001 mg/1 05/19/05 13: 02 .. < .lOOl · mg/T !05/19/05 13 :'02 ·
< .001 mg/1 05/19/05 13: 02
< .001 mg/1 05/19/05 13: 02
< .001 mg/1 05/19/05 13: 02
< .005 mg/1 05/19/05 13 :02
< .001 mg/1 05/19/05 13:02 ,< .1001 _ mg/1 05/19/05 1-3 :02
< ."Oo"l mg/1 05/19/05 13: 02 < .001 mg/1 05/19/05 13: 02
< :003· ing/1 05/19/05 13 :.02
< .001 mg/1 05/20/05 03: 09 '.i;:" .001 mg/1 05/20/05 03:09 < .001 mg/1 05/20/05 03:09
< .001 mg/1 05/20/05 03:09
< :001 ·mg/1·· '05/20/.05 03:09
< .001 mg/1 05/20/05 03:09
< .001 mg/1 05/20/05 03:09
< .001· .mg/1 ··05/.20/05 03 :·09
< . 0·01 mg/1 05/20/05 03:09
< .001 mg/1 05/20/05 03:09
< . 001, i" mg/1 05/20/05 03":09
< ~002 mg/1 ·05/20/05 03:09
< .001 mg/1 05/20/05 03:09
< . 001 ,_.. mg/1 05/20/05 ·03 :'09
< . 0·01. mg/1 05/20/05 03:09
< .001 mg/1 05/20/05 03:09 < .001 mg/1 •05/20/05 03,:09·.
< .001 mg/1 05/20/05 03:09
< .001 mg/1 05/20/05 03:09 ·; ~ :001, .mg/1 05/20/05 :o.3: 09 < .001 mg/1 05/20/05 03:09
< .001 mg/1 05/20/05 03:09 < ·;·0011• •• ''mg/1. ·.· 05/20/05· 03,09
< .001 mg/1 05/20/05 03: 09
< .001 mg/1 05/20/05 03:09
.< ,; 001 ing/1 05/20/05 03i09
< .001 mg/1 05/20/05 03:09
< .001 mg/1 05/20/05 03:09
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-585.9
Fax [phone]
Tax I.D. 62-0814289
Eat. 1970
May 23, 2005
WG202859
Batch
WG202859
WG202859
WG202859
·WG202859
WG202859
WG202859 ·,WG202859
WG202859
WG202859
WG202859 · WG202859
WG202859
WG202859
WG202859 WG202859
.WG202859
WG202859
WG202859
WG202859
WG202862
WG202862
WG202862
WG202862 WG202862
WG202862
WG202862
WG202862
WG202862
WG202862
WG202862 WG2028.62
WG202862 WG202862-·
WG202862
WG202862
WG202862.
WG202862 WG202862 WG202862-··
WG202862
WG202862 '.WG202862
WG202862
WG202862
WG202862 ·
WG202862
WG202862 < :001 mg/1 05/2.0/.05. 03, 09 · .WG202862· .001 mg/1 05/20/05 03 !09 < WG202862 < .001 mg/1 05/20/05 03 :09 WG202862
< ;:oor mg/1 05/20/05 03,09 WG202862··
< .0·05 mg/1 05/20/05 03:09 WG202862 < .001 mg/1 05/20/05 03:09 WG202862 < .001 mg/1 05/20/05 03: 09 WG202862 < .001 mg/1 05/20/05 03': 09 WG202862
< .001 mg/1 05/20/05 03:09 WG202862
< .001 mg/1 05/20/05 03:09 . WG202862 < .001 mg/1 05/20/05 03:09 WG202862
Page 28 of 47
ENVIRONMENTAL
SCIENCE CORP.
Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
IsopropYlbenzene
Analyte
Methyl tert:-butyl:~ether
Methylene chloride
n-Butylbenzene
n7 P?:'opylbenzene. ·
Naphthalene
p-Isopropyltoluene sec-B_utylb_enzene
Styrene tert-Butylbenzene
Tetrachloioethene.
Toluene trans-1,2-Dichloroethene Ttichloroetheil.e:
Trichl6rofluo:t:"omethane' Vinyl chloride
Xyletle's, ~'-TotaJ:
Analyte
roc-·(Total organic. ca;-bon)
Chloride
Nitrate' ..
Sulfate
TOC /{Total Organic.;:Cal:"bon)
Alkalinity
Alkalinity;
Analyte
Toe··. (Total Orgariic Carbon)
Ethane
Etheiie'.
Methane
Arsenic
Barfuin
Cadmium
Chioritiuffi.
Lead
Manganese
Selenium
Silver
Chloride
Nitrate
Sulfate
Iron,Dissolved
Merctitj,
TOC {Total Organic Carbon)
f,;
.-.~ ~
. ,
Quality Assurance Report
Level II
12065 Lebanon Rd.
Mt. Juliet, m 37122
{615) 758-5658
1-800-767-58 59
Fax {615) 758-5859
Tax I.D. 62-0814289
Est. 1970
L198996
mg/1
May 23, 2005
< • 001 05/20/05 03,09 WG202862
Result Laboratory. Blank:
Units Date Analyzed Batch
< :·001 .m9'/l : 05/20/05 _.03 :09 ·'·•WG202862· < .005 ing/1 05/20/05 03:09 WG202862
< .001 mg/1 05/20/05 03:09 WG202862 '< .,::._001 ··mg/1 05/20/05 03':09 'WG202862
< .005 mg/1 05/20/05 03:09 WG202862 < .001 ~g/1 05/20/05 03:09 WG202862 < ;;'.001· .'mg/1' :05/20/05_'·~03: 09. .'WG202862 ·
< .001 mg/1 05/20/05 03:09 WG202862
< .001 mg/1 05/20/05 03:09 WG202862 '< .::001· . ·.mg/1 05/20/ 05·.·03.: 09 . WG202862'
< . 0·05 mg/1 05/20/05 .. 03, 09 . WGi02862
< .001 mg/1 05/20/05 03:09 WG202862 .< -.'001 mg/L 05/20/05 03 ::o9. WG202862 < . 0·01 mg/1 05/20/05 03:09 WG202862 < .001 mg/1 05/20/05 03:09 WG202862 .-.< · .. 003°'., ·, · ritg/-1•, 05/20/05" 03·: 09 . -WG202862. ·
Units
,Duplic_ate --.
Result Duplicate RPD Limit Ref Samp Batch
·, irig/I.: 2 .61, 2 ~,70 3 .47 20· L199~03-07 · WG.2_01994
mg/1 30.4 30. 0 1.29 20 L199003-03 WG202036 ·mg/1 :,,_0~.213. . ','0".200 '·6."35· ''.·20'' L199003,-93 WG202036 mg/1 10.6 11. 0 3.57 20 Ll99003-03 WG202036
·. mg/1 :i" 0.'00 ''. .o. 00 0.00 20 ',Ll99303-04 WG202605
mg/1 80.0 110. 31. 6 20 L198964-0l WG202663 .mq/l>.•·.46.0 :•~;: -, 40. 0 ,,L·, 14 :o; 20 :a., :L199177-:02' ., WG202663
~, Laboratory ·,COntrOl-sarriple
Units Known Val Result ' Rec Limit Batch
mgf:l •, 4 3.97 99~ ~ ·'"' 85'-115 WG20l99_4:
ppm--· 1000 1000 100. 60-122 WG202007 ppm.·· 1000 .~910: '.91. 0 . •·:67.;"'113 WG202007" ppm 100·0 790. 79.0 56-121 WG202007
•'mg/1 ,.-1 r. 02·• · :1.02_._._ . _ 8_5:7,115:.-,.,MG202030 .. . . ing/1 1 1.06 106. 85-115 WG202030 mg/1 1 1.10 110. 85-115 WG202030 mg/1 :1,. 1'!04 ,104·: ·85-.115 .WG202030 mg/1 1 1.05 105. 85-115 WG202030 mg/1 1 1.04 104. 85-115 WG202030 mg/I,·· 1' r:o? '107 .. 95::115 . '.WG202030
mg/1 1 0.980 98.0 85-115 WG202030
,mg/1" 20 17,i.8 88.-8 -. :05.-_115 WG202036 mg/1 4 3.83 95.8 85-115 WG202036 mg/1 20 18.3 91. 7 90-110 WG202036
mg/{ ' wG202091 1.13 0.990 87.6 85-115
·mgfl. .-003 0 :00272. 90. 7 · ·05-115 WG202457
mg/1 4 3. 74 93.5 85-115 WG202605
Page 29 of 47
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I • 12065 Lebanon Rd.
Mt. Juliet, TN 37122
ENVIRONMENTAL [phone]
1-800-767-5859
SCIENCE CORP. •= {615) 758-5859 I Tax I.O. 62-0814289
Est. 1970 Piedmont Geologic
I Mr. John Harper
6003 Chapel Hill Road Suite 109 Quality Assurance Report
Level II Raleigh, NC 27607 May 23, 2005 L198996
I Alkalinity !!'S/1 40 44.0 110. 85-115 WG202663
·Laboratory Control Sample Analyte Units Known Val Result \ Rec Limit Batch
I 1,1,1;2-Tetrachloroethane mg/1 ;02 0.0222 111. 61"".134 WG202676 1,1,1-Trichloroethane mg/1 .02 0.0174 87.0 62-133 WG202676 1,1,2,2-Tetrachloroethane mg/1 .02 0.0187 93.4 66-124 WG202676 1, 1, 2-Trichloroetharie · · mg/1 .'02 0.0187 93 .6 · 62-124 WG202676 1,1-Dichloroethane mg/1 .02 0.0151 75.7 51-135 WG202676 1,1-Dichloroethene mg/1 .02 0.0183 91.5 68-136 WG202676 I 1, 1-DichlOfopi:'ppene;:~::: . mg/1 · .02 ·o .·0153 ,76 .·3· . 63-125 WG2026,76 · 1,2,3-Trichlorobenzene mg/1 .02 0 .·0184 91. 8 57-152 WG202676 1,2,3-Trichloroh"ropane mg/1 .02 0.0198 98.8 62-138 WG202676 1·~·2, 4-Trichlor·o enzene ' . mg/1 .02 0·;0174 .". 86 ;0_·: 49:.:153 WG202676 1,2,4-Trimethylbenzerie mg/1 .02 0.0187 93.6 61-128 WG20267.6 I 1, 2-Dibromo-3-Chloroprop_ane mg/1 .02 0.0170 85.0 50-139 WG202676 1', 2.-Di"chloi'obenz·ene '· · mg/1 .02~ 0.0185" 92·:·6 54-135 WG202676 1,2-Dichloroethane mg/,1 .02 0.0149 74.6 61-131 WG202676 1,2-Dichlorohrobane mg/1 .02 0.0160 80.1 64-126 WG202676 1,3,5-Triffiet yl_enzene mg/,1 .02 0.0198 99 .1: 65-;126 WG202676 1,3-Dichlorobenzerie mg/1 .02 0.0208 104: 45-143 WG202676 I 1,3-Dichloropropane mg/1 .02 0.0193 96.4 71-114 WG202676 1,.4-Dic~lorobenzene mg/-1 .02 0.0179 09·_-5 48-138. WG202676 2,2-Dichloropropane mg/1 .02 0.0162 81.2 52-140 WG202676 2-Chlorotoluene mg/1 . 02 0.0206 103 . 61-134 WG202676 4-;Chlorotoluene mg/1 .02 0:0200 99.8 67'-129 WG202676 I Benzene mg/1 .'02 0.0145 72 .4 63-121 WG202676 Bromobenzene mg/1 . 02 0.0232 116 . 70-130 WG202676 BI:'omochl'orc:iffiethane mg/1 . 02·. 0.0163 81·.4 66.-125 WG202676 Bromodichloi-omethaile· mg/1 .02 0.0169 84 .5 64-127 WG202676 Bromoform mg/1 .02 0.0211 105. 60-139 WG202676 Bi.-omometh.i_ne , ,. , mg/f: .02 .0>0196, '97.9 ·30-125 WG202676 I Carbon Tetrachloride mg/1 .02 0.0180 0·9_ 0 50.:.140 WG202676 Chlorobenzene mg/1 .02 0.0221 111. 70-126 WG202676 Chl"oi:-Odibl:'ciTI\Orriethai).e mg/1 .02 0. 022_4. 112 ;, 62-132 WG202676 Chloroethane mg/1 .02 0.0190 95.1 43-146 WG202676 Chloroform mg/1 .02 0.0148 74.2 65-121 WG202676 I ChlOi-ometfame mg/1·. .02 0;0141 .70 .3 45-131 WG202676 cia-1,2-Dichloroethene mg/1 .02 0.0163 81.4 68-123 WG202676 Di-isopro~yl ether mg/1 .02 0.0131 65.4 58-127 WG202676 DichlorodifluOromethilne mg/1 ;02 0.0157: .,~a ;4 24-.155-WG202676 Ethylbenzene mg/1 .02 0.0211 106. 70-121 WG202676 Hexachlorobutadiene mg/1 .02 0.0173 86.7 60-119 WG202676 I IBohrOPYlbe-nzen·e,. '• ~ ~· ,mg/1 .02· · 0,. 0229 114. ;"68:-,128 WG202676 Met yl tert-butyl ether mg/1 .02 0.0145 72.6 51-137 WG202676 Methylene chloride mg/1 .02 0.0144 71.9 53-131 WG202676 h-B,itylbenze"ne.· ..-~~_,; ,: mg/1 ,.02 . .o:. 0·162 '·. 81'.0; . 59_...:.134 WG202676 n-Propylbenzene mg/1 .02 0.0205 103. 68-123 WG202676
D Naph_thalene mg/1 .02 0.0177 88.4 54-150 WG202676 p-.I s6prop}'l tol_iieli.e ing/1· .02 o·. 0201 -103. 64-132: .WG202676 sec-Butylbenzene mg/1 . 02 0.0215 107 . 67-124 WG202676 Styrene mg/1 .02 0.0193 96.5 68-123 WG202676 tert-Butylbenzene mg/1 .02 0.0226 113: 68-128 WG202676 Tetrachloroethene mg/1 .02 0.0236 118. 63-134 WG202676 D Toluene mg/1 .02 0.0171 85.5 65-120 WG202676 trans :-1 ;· 2-Dichloroethene mg/1 .. 02· 0\·0164 02·.1 59-138 WG202676 Trichloroethene · mg/1 .02 o·. 0109 94.7 74-120 WG202676 Trichlorofluoromethane mg/1 .02 0.0184 92.2 49-121 WG202676 Vinyl chloi:-ide mg/~ ;02 0.0158 .79.0 46-133 WG202676
m
Xylenes, Total mg/1 .06 0.0647 108. 68-124 WG202676
1,1,1,2-Tetrachloroethane mg/1· .02 0.0223 112. 1 61-134 WG202859 1,1,1-TrichlOroethane mg/1 .02 0.0200 99.8 62-133 WG202859
I Page 30 of 47
I
I
ENVIRONMENTAL
SCIENCE CORP.
Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
1,1,2,2-Tetrachloroethane
Analyte
1°; 1, 2-;-,Trichloroethane
l,l-Dichl0r6etharie
1,1-Dichloroethene 1 ;· 1'-'·DichlOi-oprOJ?E!ne . ,_.
1,2,3-Trichlorobenzene
1, 2,. 3-Trichlor_opropane 1:;-2 ~-4 :..Trichlorobenzene·,
1,2,4-Trimethylhenzene
1,2~Dibromo~3-Chloropropane
_1·, 2'-D_i.chlorobenzen·e,-.--,,'; '!'.·:, .,
1,2-Dichloroethane 1,2-Dichloropropane
-1-,.3·, s-=Trimethyl_benZene
1,3-Dichlorobenzene 1,3-Dichloropropane
1·,·.4-Dichlorobenzen"e-··
2, 2-DiChlciroJ?i.-6parie·"
2-Chlorotoluene
_4 ·...: Chloi'otoli.,fene ·
Benzene
Bromobenzene
BiOmoChlo:t"ollle"thane ·.~ Broinodichloi'ometha.Il.e
Bromoform
BI:'omoffiethane-: · , ..
CarhOn Tefrachloride
Chlorobenzene
Chlorodib'rOTTIOmetharie :: . ChloroethariE! ·· ·
Chloroform
Chl'oroiri'eth.i:ine :: . , ., ..
c1s.:.i, 2-DiChloroethene'
Di~isopro~yl ether Dichlorod1fluoromethaile, Ethylberizene
Hexachlorobutadiene
Is_oPfopylbeinZene-, . _·r'•,'._I •
Methyl tert-butyl ether
Methylene chloride Il::-Buty_lben_iene·: ·, \ ',' · • .>,.
n-Propylbenzene
Naphthalene
P~:-'ISop·roPYltOlue:ne,
sec-Butylbenzene
Styrene
t_e_r_tfautylDeriz~ne··
Tetrachloroethene
Toluene
tiaiiS-'_l·, 2:;ni:Chlo_ro_ethene
Trichloroel:hene ·
Trichlorofluoromethane
Viriyl. chlor'i_de .,, ;
Xylenes, Total
1,-1'~·1, 2-Tetrachlol'.'oethaile
1,1,1-TiiChlo'r6ethane
1,1,2,2-Tetrachloroethane
1-,.1, 2-TI'icP,loroE!thane
1,1-Dichloroethane
Quality Assurance Report Level II
L198996
mg/1 .02 0.0207
Laboratory, Control Sample Units Known Val Result
mg/1 .02 0.0215 mg/1 .02 0.0209 mg/1 .02 0.0248 mg/1· ·-. 02 0 ;'0207 mg/1 .02 0.0255 mg/1 .02 0.0202 ing/1'. _0::.',1, ._o·~ 0254.
mg/1 .02 0.0208 mg/1 .02 0.0213 mg/1' -;~ 04 _,;._0 .0214: mg/1 .02 0.0204 mg/1 .02 0.0203 mg/1 :02 ;.0.0215, mg/1 .04 0.0214 mg/1 .02 0.0212 mg/1 <02 ·o·:0201
mg/1 .02 0.0219 mg/1 .02 0.0213 mg/1 i:02 o.-~·0216. mg/1 .02 0.0205 mg/1 .02 0.0209 mg/1 .·02 ;o :·0196 mg/1 .02 0.0184 mg/1 .02 0.0238 mg/T·• ·. 02· ,0,'; 0197 mg/1 .02 0.0209 mg/1 .02 0.0215 mg/L :-02· .;o. 0205 mg/1 .. •0·2 0.0228 mg/1 .02 0.0190 ing/1 ''.·02 o·:~0255
mg/1 .02 0; 02i4 mg/1 .02 0.0202
mg/1' ,_:02 . .o·. 0351' mg/1 .·02 0. 0221 mg/1 .02 0.0192 . mg/r·. · -:02 '0':0223 mg/1 .02 0.0207 mg/1 .02 0.0181 mg/1' .02· · o_. 0214•:
mg/1 :02 0.0214 mg/1 .04 0.0245 mg/1 ···.:02 0 :0225 mg/1 .02 o·.·0211
mg/1 .02 0.0215 'mg/1 , ~·02 o·:·0219
mg/1 . ·02 0.0209
mg/1 .02 0.0198 mg/1 :·02 o·. 0226
mg/1 .02 0.0203 mg/1 .02 0.0192 mg/1 :. ! 02· :.s;O; 0219 ~
mg/1 .06 0.0649
mg/1 · .:02 o·. 0222
mg/1 .02 0.0187 mg/1 .02 0.0195 mg/1 .02 O·. 0198
mg/1 .02 0.0187
Page 31 of 47
I
12065 Lebanon Rd.
Mt. Juliet, TN 37122 I
[phone]
l-800-767-5859
Fax [phone]
Tax I.D. 62-0814289 I
Est. 1970
I
May 23, 2005
103. 66-124 WG202859 I • Rec Limit Batch
108. 62-124'• WG202859
104. 51-135 WG202859
124. 68-136 WG202859 I
103. .63-125' · WG202859i ·
127. 57-152 WG202859 101. 62-138 WG202859
.~: 0. 00 49·_-153 ·, WG202859
104. 61-128 WG202859 106. 50-139 WG202859 I
, ,.\53 ;5 54·.:.:-i,35., J·WG202859
102. 61-131 WG202859 102. 64-126 WG202859
108': 65il26 WG202859 53.6 45-143 WG202859 I 106, 74-118 WG202859
103. 48-138 WG202859 109. 52-140 WG202859 106. 61-134 WG202859
108. · 67-129 · .WG202859 102. 63-12!' WG202859 I
105. 70-130 WG202859 98;1 66.-125 WG202859
§1.9 54..:127 WG202859
119. 60-139 WG202859 98'A 30:125 . WG202859
105. 59:...140 WG202859
I
108. 70-126 WG202859 103•: ',62-132 WG202859
114. 43-146 WG202859.
95.1 65-121 WG202859 · 120· .. 45-131'\ WG202859 I
112. 68-123 WG202859
101. 58-127 WG202859
17.6. 24-155',' WG202859 110. 70-121 WG202859 96.1 60-119 WG202859 I ~-111.:; i68.-128:, ·•.WG202859.', 103. 51-137 WG202859
90.7 53-131 WG202859
10,7(. . 59-.::134 :WG202859 107. 68-123 WG202859
61.3 54-150 WG202859 I
113·.:·.'. 64~132 WG202859. 108. 67-124 WG202859 107. 68-123 WG202859
·.:110 . ... 68-:128;· ·;WG202859
105. 63-134 WG202859 I 99.0 65-120 WG202859
113. 59-138, •WG202859 102. 74-120 ·wG2ci2859
96.1 49-121 WG202859
109. '46:..133 WG202859
108. 68--124 WG202859 I
111. 61-134 WG202862
93.4 62-133 WG202862
97.4 66-124 WG202862
99.2 62-124 WG202862
93.7 51-135 WG202862
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
ENVIRONMENTAL
SCIENCE CORP.
Piedmont Geologic
Mr. John Harper 6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
111-Dichloroethene
Analyte
1,1-Dichloropropene ,
1,2,3-TrichlorobellZene
1,2,3-Trichloropropane
1, 2-, 4 --:Trichrorobe"nze·ne 1,2,4-Trimethylbenzene
1,2-Dibromo-3-Chloropropane
1,2,Dichlorobenze~e, 1,2-Dichloroethane
1,2-Dichloropropane
1, J·,.s..:Trimethylbenzene
1,3-Dichlorobenzene
1,3-Dichloropropane 1,4-Dichlorobenzene 2,2-Dichloropropane
2-Chlorotoluene ,4";:-,Chlorot"ol"uene ,)· .1 Benzene
Bromobenzene
Bi"cimochloromethane ,. ,
Bromodichloromethane Bromoform
~!~~~~ei~~~!ch10ride' ·
Chlorobenzene
Chlorodibrom6ffiethane chloroethaii.e
Chloroform
Cl_ilc;>ro~etI;ariEi ,:_ , . .
cis-1,2-Dichloroethene
Di-isopro~yl ether
Diclilorodiflllor6metharie
Eth}'lberizene-
Hexachlorobutadiene
Isop·ropylbenzene· . .
Methyl tert-butrl ether
M_ethylene chloride
n-Butylbenzeirie '· ·
n-Propylbenzene
Naphthale_ne
p-I soPrcipyl tOlt.ienei-•/,,:
sec-Butylbenzene
Styrene
tert:-Btitylbenze_ne· ·. 'j
Tetrachloroethene
Toluene .
trariS -·1,_ 2 -Dichlor6etli.ene
Trichloroethene
Trichlorofluoromethane Viriyl,chloride
Xylenes, Total
1,1;1,2:-TetrilChloroethane
1,1,1-Trichloroethane
1,1,2,2-Tetrachloroethane
1 t 1,· 2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,1-'-Dichloroprope'ne
1,2,3-Trichlorobenzene
Quality Assurance Report
Level II
L198996
mg/1 .02 0.0202
, Laboratory Control Sarriple
Units Known Val Result
mg/-1 ;. 02 0.0174 mg/1 .02 0.0201 mg/1 .02 0.0212 mg/1 0 · 0-:0192 mg/1 .02 0.0193 mg/1 .02 0.0180 rng/1, .'04 0-:0179 mg/1 :0·2 0. 0183 mg/1 .02 0.0204 -mg/1. ·:02 0.0203 mg/1 .04 0.0206 mg/1 .02 0.0198
mg/1 .02 0.0174 mg/1 .02 0.0200 mg/1 .02 0.0206 rng/1 .'02 .· 0 .'0199,. mg/1 .02 0.0173 mg/1 .02 0.0202 rrig/1 .02 ·0.0177 mg/1 .02 ·0.0109
mg/1 .02 0.0241 mg/1 .02 0.0144~, mg/1 .02 0.0200 mg/1 .02 0.0203 mg/1· .02 , 0.021'4". mg/1 .02 0. 0184
mg/1 .02 0.0184 mg/1 .02 0.0199 mg/1 .02 0.0193
mg/1 .02 0.0167 mg/1" :02 ·O .,0295 mg/1 .02 0.0217
mg/1 .02 0.0188 mg/1 .02 "'O•. 0216 mg/1 .02 0.0179 mg/1 .02 0.0152 mg/1 :02 .o,-: 0168-mg/1 .02 0.0200 mg/1 .04 0.0189 · .. mg/L :02: 0; 0213°· mg/1 .02 0.0206 mg/1 .02 0.0205 rng/1 ."02, 01. 0220. mg/1 .02 0.0190 mg/1 .02 0.0185 mg/1 . 02 ·_o·; 0193 .
mg/1 .02 0.0182 mg/1 .02 0.0169 mg/1· .02 0.0183 mg/1 .06 0.0608
mg/1. .02 0:0222 mg/1 .02 0.0197
mg/1 .02 0.0203 mg/.l"-· . 02 o·. 0216 mg/1 .02 0.0196 mg/1 .02 0.0225 mg/1 .02 o:·0106 mg/1 .02 0.0235
Page 32 of 47
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax {615) 758-5859
Tax I .D. 62-0814289
Eat. 1970
May 23, 2005
101. 68-136 WG202862
\ Rec Limit Batch
86 .9·' 63-:125 WG202862
100. 57-152 WG202862
106. 62-138 WG202862 :or. oo· 49-153 WG202862
96.5 61·-1i8 WG202862
90.1 50-139 WG202862 44 :0 · ;'.54';135. WG202862
91.5 61-131 WG202862 102. 64-126 WG202862
102. 65-126 WG202862
51.6 45-143 WG202862 98.9 74-118 WG202862 87.-.1 ,48-138 WG202862,'
99.8 52-140 WG202862 103. 61-134 WG202862 '99.3 6T-.129 WG202862 86.7 63-121 WG202862
101. 70-130 WG202862
88'."5 66-125· WG202862 .. ,
94.4 64-127 WG202862
121. 60-139 WG202862
,'71-. 8 :30-125 WG202862-
99.8 58-140 WG202862 102. 70-126 WG202862
107. '. 62:-132,, WG202862.· 92.1 43-146 WG202s'62
91. 9 65-121 WG202862
99.4 . 45-.131' WG202862 96.4 68-123 WG202862
83.3 58-127 WG202862 147. '24.2:155 WG202862
109. 70-121 WG2o"2862 93. 9 60-119 WG202862
108.J 68-:128· WG202862
89.7 51-137 WG202862 76.1 53-131 WG202862
' 93·~ 9. . ,,59_·:;134 WG202862 100. 68-123 WG202862
47 .1 54-150 WG202862
107. 64'.!132·"' . ·WG202862· 103. 67-124 WG202862
102. 68-123 WG202862
110: .. 6a·.:.12a· :WG202862 ' 94. 9 63-134 WG202862
92.5 65-120 WG202862 96". 7 . 597.138_ WG202862
91. 0 74-120 WG202862
84.4 49-121 WG202862 . ;,91.4 , 46-133 WG202862
101. 68-124 WG202862
·111. 61-13·4 WG203114
98.4 62-13.3 WG203114
101. 66-124 WG203114 108. 62:...124 WG203114
98.2 51-135 WG203114 112. 68-136 WG203114
92.9 63-125 WG203114 118. 57-152 WG203114
ENVIRONMENTAL
SCIENCE CORP.
Piedmont Geologic Mr. John Harper
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
1,2,3-Trichloropropane
Analyte
1,2,4-Trichlorobenzene
1, 2, ·4 -Trimethylbenzene
1,2-Dibromo-3-Chloropropane
1,2-Dichlorobenzeile :·~' · 1,2-Dichloroethane
1,2-Dichloropropane
1.,-3·, 5-:..;Trime_thylbenzeirie ·
1,3-Dichlorobenzene
1, _3-DichloropJ:opane 1';4-'Dichlorobenzene
2,2-Dichloropropane
2-Chlorotoluene 4.:::chlorotol\Jene Benzene
Bromobenzene
Bromochlorcirnethaiie . ,
Brornodichlorornethalle Bromoform
BrOmomethane, .. ,·
Carbon Tetrachloride Chlorobenzene
Chlorodibromomethane Chloroethane Chloroform Chloromethane , . . .
c"is-1,2-Dichloroethene
Di-isopro~yl ether Dichlorcidifl\lorometharie Ethylbenzene ·
Hexachlorobutadiene IsoprOpylbenzene . •::½.:·~ :>:
Methyl tert-butyl ether
Methylene chloride
n-Butylberizene n-Propylbenzene Naphthalene
p~IsoprOpyltOluene '. sec-Butylbenzene
Styr~ne _tert-Butylbeilzene TetrachlorOethene Toluene
t_:t'.3._ns~1·;2_-Di'chi:or6ethE!ne ·
Trichloroethene
Trichlorofluoromethane Vfo.yl "'chl"oride ·'. ,.'(·
Xylenes, Total
Analyte
TOC {Total Organic Carb_on)
Ethane
Ethene'. ·
Methane
Arsenic
Barium
Quality Assurance Report
Level II
Ll98996
mg/1 .02 0.0256
Laboratory Control Sample Units Known Val Result
mg/1 mg/1
mg/1
mg/1 mg/1
mg/1 mg/1
mg/1
mg/1
. mg/1. mg/1
mg/1
mg/1 mg/1 mg/1
mg/l
mg/1
mg/1
mg/1
mg/1 mg/1
mg/1 mg/1 mg/1
mg/1 mg/1
mg/1
mg/1'
mg/1 mg/1 mg/r:··
mg/1 mg/1
mg/1· .·
mg/1 mg/1 11· mg .• mg/1
mg/1
.:mg/1 mg/1
mg/1
mg/-1 mg/1
mg/1
·mg/1.
mg/1
.02
.02
.02
·. 02 .02
.02 .'02·~'
.02
.02 , :; 02
.02
.02
.'."02
.02
.02
<02·
.02
.02
.,02'
.02
.02
;'02
.02
.02 ._",;_02·
.02
.02
.02
.02
.02 .'02 ·.·
.02
.02 :02.
.02
.02
'."02•'
. 02
.02
"' '02 , .. ,: 02
.02 . ·::,_'02 ~ ·.
. .'02
.02
.. , ... '021.:
. 06
0.0246
0.0205
0.0226
.0.0203
0.0208
0.0220
o·:-021'4
o·. 0215
0. 0214
0.0197
0.0222
0.0221
0. 0213·
0.0180
0.0208 ·o. 019,7
0.0205
0.0246
·O. 0160
0.0205
0.0208
0.0240
0. 0181'
0.0192
0. 0197.
0.0189
0.0177
0;0294'
0.0207
0.0203
'O :'0224
0.0198
0.0161
0.0185
0.0210
0.0230 o:: 0223·
0.0211
0.0219
0. 0222.
0.0195
-0.0190
0:0200
0.0196
0.0183
0. 018'4
0.0626
12065 Lebanon Rd.
Mt. Juliet, TN 37122
(615) 75B-5858
1-800-767-5859
Fax [phone]
Tax l.D. 62-0814289
Est. 1970
May 23, 2005
128.
\' Rec
123· ..
103·.
113.
102'. .
104.
110.
.107;,.
108.
107.
98.5
111.
111.
·106 .·
89.8
104. ;98·. 6
102.
123.
·--80·.2
102.
104.
·-120:
90.7
95.8
· 98 :5
94.4
88.7
147.
104.
101.
112'.--
98. 9
80.5
92·:3
105,
115.
·111;
105 .
110. ·111~
97.5
94.8
100.
98.0
91.3
.. 9L9 . 104 .
62-138 WG203114
Limit Batch
49-153· ,-WG203114·
61-128 WG203114
50-139 WG203114
54;135 WG203114
61-131 WG203114
64-126 WG203114
65"-126' ·· .. WG203114.
45-143 WG203114
74-118 WG203114 ·49;:139· 'WG2031·14
52-140 WG2o'3114
61-134 WG203114
67'-129 WG203114
63-121 WG203114
70-130 WG203114
'66,-125 WG203114 064:127 WG203114
60-139 WG203114
30~125 WG203114
58-140 WG203114
70-126 WG203114
62-·132 'WG203114
43-146 WG203114
65-121 WG203114
45-131 WG203114
68-123 WG203114
58-127 WG203114 24'-155 . · ,WG203114
70-121 WG203114
60-119 WG203114
68'-;128~ :-WG203114'
51-13i WG203114
53-131 WG203114
59.-:1-34 WG203114
68-123 WG203114
54-150 WG203114
64-132 .. \WG203114 ·
67-124 WG203114
68-123 WG203114
·;652128 ,·,WG203114, .
63-134 WG203114
65-120 WG203114
59'-138: WG203114'.
74~120 WG203114
49-121 WG203114
46~133'·,,-, WG203114
68-124 WG203114
Laboratory Ccint:iol Sample Duplica_te Units LCSD Res Ref Res RPD Limit \Rec Batch
mg/1
ppm ppm·
ppm
mg/1
mg/1
3 .93 .
980.
· 880'.
800.
1.03
1.07
3.97
1000
910.
790.
1. 02
1.06
Page 33 of 47
'l'.01
2.02
.3 :35
1.26
0.976
0.939
20
11
15
15
20·
20
98';3·
98.0 88·:·o
80.0
103-.
107.
WG20199,4·
WG202007
WG202007'
WG202007
WG202030
WG202030
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
n
D
D
D
ENVIRONMENTAL
SCIENCE CORP.
Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Cadmium
Analyte
Chromium Lead ·
Manganese Selenium,
Silvel:'
Chlo'ride
Nitrate
Sulfate
Iron,.Dissol ved 1-
MEircury.
~~ (T_otal Organic Carbon)
Alkalinity
1, 1, 1, 2:-~etrachlorOet;haiie •. f_ 1,1,1-Trichloroethane .
1,1,2,2-Tetrachloroethane
1, 1 ~ 2:...Trichloroethanef, : .. { 1,1-Dichloroethane
1,1-Dichloroethene
1,r-Di"chlo'ropropene_, l -,. 1
1,2,3-Trichlorobenzene
1, 2, 3-Trichl_oropropane
l', 2, 4 ..:.Tri_Ch_lo_l:'obenz'eri.e"
1, 2, 4-Tr'imethylbenzene·
1,2-Dibromo-3-Chlor9propan~
1, 2-Dfi:::hlorObenzene'"· · · · '
1, 2·-oichloroethane·
1,2-Dichloropropane
1 ;-3, s_-Tl'.'iniethylberiierie
1,3-Dichlorobenzene
1,3-Dichloropropane
1, 4·"'."oichlo'rohenzene ·-
2, 2-Dichloropropane
2-Chlorotoluene
4 -Chl'or·otoliierie·
Benzene
Bromobenzene
Brrim0Chl6romethane ,., }',
Bromodichloromethane
Bromoform
Brorooffletharie. ,
Carbon Tetrachloride
Chlorobenzene
ChlorOdibiOmomethane
Chlo roe thane
Chloroform
ChlorolTlethane
ciB-1,2-Dichloroethene
Di-isopro~yl ether
Dichlorodifluoromethane
Ethylbe'i1zene
Hexachlorobutadiene
Isopropylbenzene
Methyl tert-butyl ether
Quality Assurance Report
Level II
Ll98996
mg/1 1.12 1.10 1.80 20
Laboratory Control Sample Duplicate
Units LCSD Res Ref Res RPD Limit
mg/1 ·1.05 1. 04, 0.957. 20
mg/1 1.06 1.05 0. 948 20 mg/1 1.05 1.04 0.957 20
mg/1 1. 09" 1:·07 l.'85 20 mg/1 0.990 0.980 1. 02 20
mg/1 ,,•_17 .. 7. ,: 17.8\ 0--;563 • 20 mg/1 3.78 3.83 1.44 20
mg/1 18.8 18.3 2.34 20 •. J' :, '· .. · ... , 0. 9"76 . ' mg/1 0.990 2.04 20
mg/1 0.0030 0.0027 12.1 20
mg'.,l 3.89 3.74 3.91 20
mg'/1 46. 0 44.0 4.44 20
mg/1 0.0233 0.0222 4;92. 17
mg/1 0.0182 0.0174 4.57 17
mg/1 0.0190 0.0187 1. 89 16
'mg/1 0. 0184-.. 0 .,018,7 1. 78 16,. ·
mg/1 0.0159 0.0151 5.07 22
mg/1 0.0192 0.0183 4.95 17
mg/1 o•:·0159 . 0:0153 4·; 02: 17·
mg/1 0.0204 0.0184 10.6 19
mg/1 0.0200 0.0198 1.07 18 cmg/1 . 0_;"0195 . 0.0174' 11 :'6\ · ·20
mg/1 0,0202 0.0187 7.51 18 mg/1 0.0173 0.0170 1.90 19
mg/1·:: .-.•·0.0100 0{0185 1.23 ·16
mg/1 0.0151 0.0149 1.36 15
mg/1 0.0163 0.0160 1. 82 18 mg/,1 . .. 0.0208 0::-019.8 4.63 · 17
mg/1 0.0220 0.0208 5.92 0 mg/1 0.0197 0.0193 2 .17 11
mg/1· ·.:.· ,0. 0187 0 .'0179 4 :41 17 ·
mg/1 0.0170 0.0162 4.40 21
mg/1 0.0215 0.0206 4.29 26
•::mg,i · o·. 0209. 0 .·0200· _'4':64;.' -17.
mg/1 0.0148 0.0145 2.29 16
mg/1 0.0242 0.0232 4.28 16
mg/cl. 0.0165" 0.0163 1·.32 .1_7 mg/1 0.0179 0.0169 5.42 17 mg/1 0.0224 0. 0211 6.13 15
mg/1 -,0. 0192 0:0196. 2.17 21
mg/1 0.0184 0.0180 2.46 17
mg/1 0.0226 0.0221 2.20 16
mg/1 . o·: 0223 o .9224 0.173 15 mg/1 0.0193 0.0190 1. 70 24
mg/1 0.0154 0. 0148 3.87 15 •mg/1 : ·o\ 01'43 0.0141' 1.50 22
mg/1 0.0166 0.0163 1.81 15 mg/1 0.0135 0.0131 2.85 18
mg/1 0.0158 :o. 0157 0.542 22 mg/1 0.0218 0.0211 2.93 17
mg/1 0.0200 0.0173 14.5 18 mg/1 0.0237 0.0229 3.68 17 mg/1 0.0147 0. 0145 1.54 18
Page 34 of 47
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.O. 62-0814289
Est. 1970
May 23, 2005
112. WG202030
\Rec Batch
105. ·WG202030_
106. WG202030
105. WG202030
, .109. WG202030
99.0 WG202030
00·. 3 WG202036
94.4 WG202036
93.9 WG202036
. .. -:;:.
85.8 WG202097
102. WG202457
97.2 WG2.02605 .: ...
11s·. WG202663
117. WG202676
91.1 WG202676
95.1 WG202676
· ,92: 0 '.· .· WG202676
79.7 WG202676
96.2 WG202676
79.4"· -WG202676
10·2. WG202676
99.9 WG202676
97;5 -WG202676
101. WG202676
86.6 WG202676
93.8 WG202676
75.6 WG202676
81. 5 WG202676 . l 104. WG202676
110. WG202676
98.5 WG202676
93,. 6 · WG202676
84.8 WG202676
107. WG202676
:105 . .-:WG20267,6
74 .1 WG202676
121. WG202676
82i-5' WG202676'
89.3 WG202676
112. WG202676
95·. 8-.WG202676-
92.0 WG202676
113. WG202676
112. ,WG202676
96. 7 WG202676
77.1 WG202676
711'.4 WG202676:
82.9 WG202676
67.3 WG202676
78.8 WG202676
109. WG202676
100. WG202676
119. WG202676
73.7 WG202676
ENVIRONMENTAL
SCIENCE CORP.
Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Methylene chloride
Analyte
_il-Butylbenzene
n-Propylbenzene
?,1aphthalene
p-;Iaopropylt'oluene.
sec-Butylbenzene
Styrene
tert-Butylbenzehe , -;
Tetrachloroethene
Toluene
tri:llla .:.1 , 2 _:;. Dfchloroethehe Trichloroethene ·
Trichlorofluoromethane Vinyl" ,chlOride'·
Xylenes, Total
·l, 1, 1·, 2-TetraclilOroE.!thane. ·
1,1,1-Trichlciioethane 1,1,2,2-Tetrachloroethane
1, 1; 2'-.Ti'i'chloi-oethane ·
1,1-Dichloroethane
1,1-Dichloroethene
r; 1'.-Dichlorop:i:-operie
1,2,3-Trichlorobenzene
1,2,3-Trichloropropane
1:;•2, 4-TrichlOrobenzene
1,2,4-TrimethylbenZene
1_, 2-D_ibromo_:-3_-Chloropropane -1,2~nichlojotiE!ii.zeri.E! ·,.'f'_:-'.'·· · ·
1,2-Dichloroethane
1_, 2_-Dichlo~opropane
-1,-3 ,·s-~ririi~thy~ben:~~n~ 1,3-Dichlorobenzene
1,3-Dichloropropane
1·~ 4-Dichl"Orobenzene·
2,2-Dichloropropane
2-Chlorotoluene
4-:chlorot6luene .•.'·:.
Benzene
Bromobenzene Bi:'omochlo"rom'etha:rie ..... ·: ''!
Bromodichloromethane
Bromoform
Bromo'methahe\ ~->~ ,_-:_-.-, ..
Carbon Te'trachloride
Chlorobenzene
Chlo'rciditil'.'ott\ometh"ane
Chloroethane
Chloroform
Chlororrietharie · : ,-. ·
cis-1,2-Dichloroethene
Di-is9pro~yl eth~r
Dichlorodi:fluoromethane Ethylberizene· ..
Hexachlorobutadiene·
Isopropylhenzene··,
Methyl_ tert-butrl ether
Methylene chloride
n-Butylbenzene
n-Propylbenzene
I
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone] I
1-800 -76 7-58 S9 •= {615) 758-5859
Tax I.D. 62-0814289 I
Est. 1970
Quality Assurance Report Level II
May 23, 2005 L198996
I
mq/1 0. 0145 0. 0144 1.19 17 72.7 WG202676
Laboratory Control' , Sample Duplicate Units LCSD Res Ref Res RPD Limit \Rec Batch
I
mg/1 ,0,. 01 73, . ,0. 0162· 6:23 19 ·86 .3 WG202676 . mg/1 0. 0213 0.0205 3.85 17 107. WG202676 mg/1 0.0187 0.0177 5.35 17 93.3 WG202676
mg/1· . 0. 0222 0'; 0207 6.94 .18 ·,,11-1''.· WG202676 mg/1 0.0224 0.0215 4.52 18 112. WG202676 mg/1 0.0207 0.0193 6.88 17 103. WG202676 mg/1· 0 :0236. · Q"/0226, -: 4,; 04 ·1•7:.' •'·118: WG202.676
mg/1 0.0241 0.0236 2.02 18 120. WG202676 mg/1 0.0177 0.0171 3.46 18 88.5 WG202676 . ,mg/1· ', 0.0159 o·. 0164 3"'.'08 22 79-i-6 ·. ·:g~~~t~: mg/1 0.0197 0.0189 3.68 16 98.3 mg/1 0.0193 0.0184 4.28 19 96,3 WG202676 mg/1 ,0 '.'0157 :o. 0158 . 0 .'431 -17 78.7 WG202676.· mg/1 0.0661 0.0647 2.06 17 110. WG202676
I
I
I
,mg/1-0:0218 .o·:0223 2. 39,._ 17. 109. WG2028591
mg/1 0.0186 0.0200 7.29 17 92.8 WG202859 mg/1 0.0210 0.0207 1.87 16 105. WG202859 .. mg/1. ·-.0 :.02_07 0:-0215 -3 .81 ·16 104 ... WG202859· mg/1 0.0199 0.0209 4 .92-22 99.4 WG202859 mg/1 0.0224 0.0248 10.2 17 112. WG202859
I
\ mg/1 ·0-~01-94 _;.o·. 0201 6 :,0l'., · -~l 7:'. '97.2 . WG202859'· mg/1 0. 023'9 0.0255 6 .13 19 120. WG202859 mg/1 0.0209 0.0202 3 .39 18 105. WG202859
{ ;, 'mg/1 ,·0.0239 -. o_·. 0254:. ; 6::'40 20 2 . .-39;--. ,.:.WG202859;,,.
mg/1 0.0200 0.0208 3. 79' 18 100. WG202859 mg/1 0. 0213 0. 0213 0 .132 19 106. WG202859 mg/1-·0:-0190: · -,o·.,0214. '-7!.'69".-'_ 16' !49;'6 WG20_2859; mg/1 0. 019·0 0.0204 6.97 15 ·gs :·o WG202859
mg/1 0. 0211 0.0203 3.87 18 106. WG202859 mg/1 o::02or 0 .'0215:-:: --3 .62 17 ·"-'104'. WG202859
mg/1 o .'oioa· o·:02i-f 2.90 25 · s2·. ·1 WG202859 mg/1 0.0208 0.0212 1.70 15 104. WG202859 . mg/I-·o ._0190_ 0. 0207'" 4 .44·: ··-17 ."99'.0 · .. WG202859 mg/1 0.0205 0.0219 6.63 21 10·2. WG202859 mg/1 0.0209 0. 0213 1.65 26 105. WG202859 "mg/1_--· ,.o .·0205 o·.-021'6 .. 5 :23-~ 17,' ;103":'..-·~WG202859 .-mg/1 0.0190 0.0205 7 .63. 16 94.9 WG202859 mg/1 0.0201 0.0209 4 .14 16 100. WG202859 mg/1 •_o·:•0205·', 0:0196 .:4':54, 17 103 :: ·. WG2_02859;
mg/1 0.0191 0.0184 3.99 17 95.7 WG202859 mg/1 0.0230 0.0238 3.46 15 115. WG202859 mg/1 ·-o:·016s ·0:0197 17-.'6';: ;·,21 82 :5, · · ·WG202859:-., mg/1 0.0190 o·.·020·9 9.55 17 95.0 WG202859 mg/1 0.0212 0.0215 1.34 16 106. WG202859 mg/1", 0.021-7 ·-0.0205_. <,5."52 15" ,108. WG202859 mg/1 0.0205 0.0228 10.3 24 103. WG202859 mg/1 0.0181 0.0190 5.13 15 90.4 WG202859 mg/1 0. 0238:• ·o.02s5 .6';99 22 \·119~-· WG202859 mg/1 0.0209 0.0224 7.09 15 104. WG202859 mg/1 0.0188 0.0202 7.52 18 93.8 WG202859 mg/·l-· 0.'0329 · .o·.0351 .6"~45 22 :-: .. .':165";' WG202859
mg/1 0. 0211· 0.0221 4. 72 17 105. WG202859 mg/1 0.0186 0.0192 3.24 18 93.0 WG202859 mg/1 0", 0212 . O·. 0223 4:84 17 106.--WG202859 ' mg/1 0.020·0 0.0207 0. 725 18 104. WG202859
mg/1 0.0170 0.0181 6.25 17 85.2 WG202859 mg/1 o:.·0190 -0~021'4 7-. 78 . 19 99.-2 WG202859
mg/1 0.0202 0.0214 5.38 17 101. WG202859
I
I
I
I
I
I
I
Page 35 of 47 R
H
D
I
I
I
I
I
I
I
I
I
I
I
I
I
I
n
H
D
ENVIRONMENTAL
SCIENCE CORP.
Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Naphthalene
Analyte
p~rsopropyltoluene
sec-Butylbenzene
Styrene
tert~But}'lbenzene.
Tetrachloroethene
Toluene
t·ra:ns.-1,·2.;nichlor6ethehe
Trichloroethene
Trichlorofluoromethane
Vinyl: .chloride. ·
Xylenes, Total
1, 1, 1, 2:-.Tet:iachloroethane
1,1,1-Trichloroethane
1,1,2,2-Tetrachloroethane
1,1,2...:TriChl'oroetharie'
1,1-Dichloroethane ·
1,1-Dichloroethene
l,1-Dich_lcii6Propene
1, 2, 3·-Trichlorobenzene
1,2,3-Trichloropropane
1, 2·,-4-;"Ti-ichlorobenzene
1,2,4-Trimethylbenzerie
l,2-Dibromo-3-Chloropropane
1-·2-oi'chlorObenzell.e··,, ·. .•.. 1
1:2~Dichlo:ioetharie · · '
1,2-Dichloropropane
1, 3 ;5 -,Ti"i_trie.thylbeni~rie
1,3-Dichlorobenzene
1,3-Dichloropropane
1, 4-,DiChloro_beniene ,,
2,2-Dichl"oropro!)arie
2-Chlorotoluene
.4-Chlorotol'uene·.:
Benzene
Bromobenzene
BrOmochlorofuethane> .. , 1 ·
Bromodichloromethane
Bromoform
Biomometharl.e · . , ,,,,_
Carbon Tetrachloride
Chlorobenzene
Chlor0dibi-Om6methane' · ·. j
Chloroethane -
Chloroform
ChlOroniethalle. ·. . . . -:; .
cis-1,2-Dichloroethene
Di-isopro~yl ether
Dichloiod1flUorofflethane
Ethylbe"nzene
Hexachlorobutadiene
IsOpropylbenzene ..
Methyl tert-butyl ether
Methylene chloride
h-ButylbenZe~e
n-Propylbenzene
Naphthalene
P-rsopropyltoluene
sec-Butylbenzene
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
Quality Assurance Report
Level II
Ll98996
May 23, 2005
mq/1 0.0243 0.0245 1.11 17 60.6 WG202859
Laboratory Control. Sample
Units LCSD Res Ref Res
Duplicate•
RPO Limit \Rec Batch
mg/1 0:0217 0.0225 -3 .93 18 108. WG202859
mg/1 0.0205 0.0217 5.43 18 103. WG202859
mg/1 0.0209 0.0215 2.80 17 104. WG202859 mg/1 :0-:0212 0.0219 3 .49 . 17· 106. . WG202859
mg/1 o'. 0197 0.0209 5.96 18 98.5 WG202859 mg/1 0.0192 0.0198 3.35 18 95.8 WG202859 . ffig/1• O·. 0218 0.0226 3;._70 •22, 109'. •WG202859 mg/1 0.0199 0.0203 2.17 16 99.4 WG202859
mg/1 0.0172 0.0192 10.8 19 86.2 WG202859 mg/~. o·. 0204 (0". 0219 . 7. 27 ·17-,· :102 ~-WG202859, mg/1 0.0618 0.0649 4.90 17 103. WG202859
mg/,1 .0.0200 0-. 0222. 10.7 17' 99·. 9 'WG202862 mg/1 0.0193 0.0187 3.35 17 96.6 WG2028-62
mg/.1 0.0183 0.0195 6.02 16 91. 7 WG202862
mg/1·; 0 ?0179 0.0198: .10 .1· 16 89.6 ·WG202862 mg/1 0.0194 0.0187 3.54 22 97.1 WG202862
mg/1 0.0203 0.0202 0.808 17 102. WG202862 mg/1 0.0174, 0.0114 ... o-.375 17 87.·. 2 WG202862 mg/1 0.0198 0. 0201 1.36 19 99.1 WG202862
mg/1 0.0183 0.0212 14.6 18 91.4 WG202862 mg/L· ·0.0195 0. 0192 1.57 20 1 :·95 WG202862 mg/1 0.0189 0.0193 2.14 18 94.4 WG202862 mg/1 0.0198 0.0180 9.61 19 99.2 WG202862 mg/1 0.0184 ,o·.0179 2. 75.-· 16 46 .'1 WG202862 mg/1 0.0191 0.0183 4.14 15 95.3 WG202862
mg/1 0.0176 0.0204 14.7 18 88.2 WG202862 mg/-1 ,0. 0199 · 0.0203 2 .10•· 17 99·.4 · WG202862 . mg/1 0.0191 0.0206 7.79 25 47.7 WG202862
mg/1 0.0201 0.0198 1.56 15 100. WG202862
mg/-1· ·o·:·0100 '0.0174' _, '3·:"1:7: <.17 ', 89.9 WG202862.
mg/1 0.0193 0.0200 3.24 21 96.6 waio20·62
mg/1 0.0203 0.0206 1. 56 26 101. WG202862 mg/T· ·0.0192 0:0199 J·:46, (17 95.9 WG202862
mg/1 0.0171 0.0173 1.64 16 85.3 WG2028.62
mg/1 0.0199 0.0202 1.41 16 99.5 WG202862 mg/1' .-o ·:0190: 0.0177 1 ~-65 17 90 ;'0 WG202862 mg/1 0. 019'7 0.0189 4 .12 17 98.3 WG202862 mg/1 0.0224 0. 0241 7.29 15 112. WG202862 ing/1'. 0 .'0141 ·0.0144 1.67·, '•21•,, ,10:6· WG202862 mg/1 o·. 0101 o·:0200 6. 71 17 93 .. 4 WG202862 mg/1 0.0193 0.0203 5.11 16 96.6 WG202862 . mg/1 '-"o·~-0200 0~0214 ·. 2·_47 ·15 . 104. WG202862 mg/1 0.0193 0.0184 4. 53 24 96.4 WGi02862 mg/1 0.0175 0.0184 4.71 15 87.6 WG202862
mg/1 o·. 0199 ·0.0199· ._0.111 22 99'.6 WG202862,
mg/1 o·. 0202 0.0193 4.51 15 101. WG202862 mg/1 0.0171 0.0167 2.53 18 85.5 WG202862
mg/1 0.0292 0.0295 1.0~ 22 146". WG202862 mg/1 0.0193 0.0217 11. 7 17 96.5 WG202862 mg/1 0.0181 0.0188 3.79 18 90.4 WG202862
mg/1 0.0204 0.0216 5 .'44 17, 102. WG202862 mg/1 0.0178 0 :0179 0.902 18 88.9 WG202862
mg/1 0.0157 0. 0152 3.36 17 78.7 WG202862 mg/1 0 .,0173 ·O. 0168 3·.23 19 86". 7 WG202862 mg/1 0.0195 0.0200 i".37 17 97.7 WG202862 mg/1 0.0193 0,0189 2.53 17 48.3 WG202862 mg/1 0.0208 0;0213 2.59 18 104'-. WG202862 mg/1 0.0198 0.0206 4. 08 18 99.0 WG202862
Page 36 of 47
ENVIRONMENTAL
SCIENCE CORP.
Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Styrene
Analyte
tert'-BU.ty_lbenZene
Tetrachloioethene
Toluene
tranei-1, 2·-oiclilOroe.theiie
Trichloroethene ·
Trichlorofluoromethane
Vin}'! ';,:Chlori'de·: ('.;!,').'.-'·
Xylenes, Total
1,.1', 1-;. 2 .:.Tetrachlciroethane ·
1,1,i-Trichloroethane
1,1,2,2-Tetrachloroethane
17, 1 ;" 2_;:;_Trfchloroethane
1,1-Dichloroethane
1,1-Dichloroethene
·l·, 1.:0.fchl'oropr'o)?ene . 1,2,3-Trichlorobenzene
1, 2, 3-Trichloropropane_
1,· 2-, 4-Trfi:::hlorobenzerie 1,2,4-TrimethYlbenzene
1, 2-Dibromo-3-Ch_loropropane
l ;"2'~DiChlcir6benzene ' .• ·· · ·.
1,2-Dichloroethane
l_,_ 2-Dichloropropane
1_', 3; 5~Trimethylbenzene.
1, 3-Dichl"orobenz'ene
1,3-Dichlorohropane
•l-;_4.:.n~c~loro "E;D:2:e~_~;i: · ._;· •,
2,2-Dichloropropane
2-Chlorotoluene
.4-: Chlorotoh.ief1e?/7· f:1, : Benzene
Bromobenzene Broinochlo"rometharie·.~, ~•--._ ..
Bromodichloromethane
Bromoform
Bromom:E!:thane_·•: ·:::.~-~"~~{·. t '
Carbon Tetrachloride
Chlorobenzene Chl"o'rddibi-.6m6methaI1e ,-..
'chlO:i:-Ciethane
Chloroform
Chfifr_Omethaii.e_: .... ~ ..
cis-1,2-Dichloroethene
Di-isopro~yl ether
DichloiodiflUofoffiethatle Ethylbenzene --. --. .
Hexachlorobutadiene
Iscipropylbenzene·1:
Methyl tert-butyl e'i:'.her Methylene chloride
n-:Bl;1tylbenZene_
n-Propylbenzene
,,")
Naphthalene
p-:-Isopropyltol_uerie
sec-Butylbenzene
Styrene
tert:-_Butylb_enzene
Tetrachloroethene
. ' ,·, •f',
Quality Assurance Report
Level II
mg/1
L198996
0.0201 0.0205 2.14
Laboratory Control: Sample Duplic·ate
17
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.O. 62-0814289
Est. 1970
May 23, 2005
100. WG202862
Units LCSD Res Ref Res RPD Limit \Rec Batch
mg/1. 0.0213, 0.0220 3.49 17 .. 106. WG202862
mg/1 0.0195 0.0190 2.54 18 97.3 WG202862
mg/1 0.0181 0.0185 2.17 18 90.5 WG202862
mg/1 ,••·O. 0189.: 0:0193 2.38 · · 22 94.4· -WG202862
rng/1 0.0194 0.0182 6.17 16 96.8 WG202862
mg/1 0.0171 0.0169 1.19 19 85.4 WG202862 mg/1, :0-:01 72 -· . ·o ~-0103 5~_ 88 · 17. 86'.2 . WG202862',
mg/1 0.0580 0.0608 4,70 17 96.7 WG202862
ing/1' -"'.O·;p228\-,o ;'0222.o;,: 2 :95 : ·17. 11·4,-; ·WG203114"
mg/1 0.0190 0.0197 3 .'57 17 94. 9 WG203114
mg/1 0.0218 0.0203 7.17 16 109. WG203114
mg/r :o :·0200· ::o ."021_6:" ,3,': 63;: >:16 . 104; ·, WG203114
mg/1 0. ·0196 0.0196 0. 0013 22 98.2 WG203114
mg/1 0.0189 0.0225 17.4 17 94.5 WG203114
mg/1 -~.o. 0101 . O"-:: 018-6, .,,·.2:·69-•,_ · 17 9_0 .:4 WG203114
mg/1 0.0228 0.0235 . 3°. 29 -19 114. WG203114
rng/1 0.0223 0.0256 14.1 18 111. WG203114
mg/1 7-"' ·_O, 0221_.. 0 .·024'6" .1_01.·6 -· 20 · .. 111. WG203114
mg/1 0.0215 0.0205 4. 85 18 108. WG203114
mg/1 0.0211 0.0226 6.78 19 106. WG203114
mg/1'. •, 0 .-0184 ,o·:.0203 .-·9>72_c ,-16 92·.2" WG2031·14
mg/1 0.0215 0.0208 3.33 15 101:· WGi03114
mg/1 0.0203 0.0220 7.95 18 101. WG203114
mg/I":;' :,;·;·10: .. 0223' ;,s_o;:·021"4 . 4;24, 1-7-· ·112:,_ :. -<:.:WG203114 mg/1 0.0230 0.0215 6.64 25 115. WG203114
mg/1 _ 0. 0225 0.0214 4.70 15 112. WG203114
mg/F.-·: -~ o•:0191· o·:019_1 -3. 03 17 · 95 :'6 •· WG203114
mg/1 0.0205 0.0222 7.98 21 103. wa20·3114
mg/1 0,0226 0.0221 2,23 26 113. WG203114
·mg/1 " · 0', 0234 O·; 0213 ··9.-38'.,I• ,·17 , 117';.• WG203114·
mg/1 0,0172 0.0180 4. 06 16 86.2 WG203114
mg/1 0,0224 0.0208 7.49 16 112. WG203114
mg/1 . ,c O: 0193· · 0; 0197, ;2 ,'29 17. 96 .4· WG203114
mg/1 0.0190 0.0205 7.71 17 94.8 WG203114
mg/1 0:0257 0.0246 4.58 15 129. WG203114 mg/1 ,, _o·. 0151 ·:0.0160· 5 .87;,• 21 15·::1. WG203114·
mg/1 0.0194 0.0205 5.50 17 96.9 WG203114
mg/1 0.0221 0.0208 6.05 16 111. WG203114
. ·,'mg/I> .:-.0::.023.0 ,:· 0':'0240 ,4": 39;';, .c'15_ ;-115_~: :.~-;· WG20.Jl·14 mg/1 0,0185 O :0101 1. 89 24 92.4 WG203114
mg/1 0.0175 0.0192 9.16 15 87.4 WG203114
· mg;1, ', ,.o :.010_0 o•.:0191. ··;-4;41 ·:.··22 ·.94·';2' ~WG2031l4 ·
mg/1 0.0198 0. 018.9 4.88 15 99.1 WG203114
mg/1 0.0174 0.0177 1. 80 18 87.1 WG203114
mg/1 · o·. 0295 :0:0294. _0:493. ·22' 148". WG203114
mg/1 0.0211 0.0207 1. 78 17 105. WG203114
mg/1 0.0194 0.0203 4.51 18 97.0 WG203114
mg/-1 O: 0230 _o_. 0224 · 2 .-34 17 -115; WG20311'4
mg/1 0.0191 0.0198 3.58 18 95.4 WG203114
mg/1 0.0158 0.0161 1. 69 17 79.1 WG203114
mg/1" . ·. ,o. 0191 .o·;·Ol85 · · 3·: 53 19. 95 :'6· · WG203fl4. ·
mg/1 0,0219 0.0210 4.43 17 110. WG203114
mg/1 0,0207 0.0230 10.6 17 103. WG203114
mg/1 0,0230 0.0223 -3 .10 18 115:. WG203114
mg/1 0.0218 0.0211 3.65 18 109·_ WG203114
mg/1 0,0225 0.0219 2.63 17 113. WG203114
mg/1 .• ,0.0227 0 :·0222 2.36 17 113·.·. WG203114
mg/1 0,0215 0.0195 9.64 18 107. WG203114
Page 37 of 47
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
D
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
D
H
D
ENVIRONMENTAL
SCIENCE CORP.
Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Toluene
Analyte
trans-:1, 2,-:-Dichloroethene
Trichloroethene · ·
Trichlorofluoromethane
Vinyl: chloride u
Xylenes, Total
Analyte
TOC (Total Org.inic Carbori)" ;}.
Arsenic
Barium
Cadmium
Chromium
Lead
Manganese
Selenium
Silver
Nitrate
Iron,Dissolved
Mercury
~c {Tot?:~ .. or~~nic_
Alk~lini~}.
. ,.
l, 1,-r, 2 ..:Tet·racli_l'oroeth.iirie; !'''
1,1,1-TrichlOroethane
1,1,2,2-Tetrachloroethane
1 .. , •l ~ · 2_-:Trr chloroetlian.e ':---: n
1,1-Dichloroethane
1,1-Dichloroethene
1 ~ -1 ~ Dichloro'pi:-_op·ene · '. -~-·
1,2,3-Trichlorobenzene
1,2,3-Trichloropropane
1, 2, 4-Tr~chrorobellz_ene ~
1,2,4-Trimethylbenzene
1,2-Dibromo-3-Chloropropane
1, 2-Dichlorobenzen'e' •.... :-·
1,2-Dichloroethane
1,2-Dichlorohrobane
-1:, 3, 5;-"Trim·et Yl enzene ~· ·
1,3-Dichlorobenzene
. ., .. ,
1,3-Dichlorobropane
1,4-DiChlOI'o enzerie.
2,2-Dichloiopropane
2-Chlorotoluene
.· ~
4'-Chlorotoluene
Benzene
Bromobenzene
Biomochloiomethane
Bromodichlo"romethane
Bromoform
Bromomethane
Carbon Tetrachloride
,.
.
Quality Assurance Report
Level II
Ll98996
mg/1 0.0191 0.0190 1.03 18
12065 Lebanon Rd.
Mt. Juliet, TN 37122
{615) 758-585B
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 23, 2005
95.7 WG203114
Laboratory Control Sample Duplicate Units LCSD Res Ref Res
mg/1· 0. 0193. 0.0200 mg/1 0.0197 0.0196
mg/1 0.0167 0.0183 mg/.1· .•,0.0170 .Q. 0184 mg/1 0.0634 0.0626
Units MS
Matrix <Spike.
Res Ref Res
mgfl 20.5 .-r s,:2:-00
mg/1 1.04 0.00 ··mg/1· 1;44 0 ;·390-
mg/1 1.10 0.00 mg/1 1.02 0.00
.'mg/1 1.02 o·; oo
mg/1 7.29 6 .40 mg/1 1.10 0.0210
-mg/1' 0. 980" 0.00
mg/1 4.79 0.00
,';'• ,.·J
0.988 mg/1 0.00
:mg/) 0.0029 "!LOO
mg/1 20.5 0.00
I
mg/1 43.0 22.0
·mg;1 0.-0236 0:00
mg/1 0. 0183 0.00
mg/1 0.0184 0.00 · mg/,I 0.'0192 o_.oo mg/1 0.0151 0.00 mg/1 0.0177 0.00 mg/1 · .'.o·. 0153· 0.00
mg/1 0.0186 0.00 mg/1 0.0203 0.00
mg/-1 0.0172 ; 0·."00. ·
mg/1 0.0193 0.00 mg/1 0.0187 0.00 : mg/-1' 0.0183 · o·.oo
mg/1 0.0156 0.00 mg/1 0.0155 0.00 ,--mg/1. 0.02·01· ·o.oo
mg/1 0.0201 0.00 mg/1 0.0202 0.00 . mg/1. .o·-.0173 o·:oo
mg/1 0.0162 0.00 mg/1 0.0210 0.00 mg/1, o ·. 0197_ 0:00
mg/1 0.0140 0.00 mg/1 0.0236 0.00
mg/1 0.-0160 0.00 mg/1 0.017·3 0.00
mg/1 0.0:210 0.00 mg/1 0.0146 0.00
mg/1 0.0185 0.00
Page 38 of 47
RPD Limit \Rec Batch
3.70-22 96.3 WG203114
0.662 16 98.6 WG203114
8.71
7-.59
1. 22
TV
:20
1
1
1
1
1
1
1 1··
5
1.13
:0_03··
20
SD
·. 02.
.02
.02
:02
.02
.02
-. 02
.02
.02
:·02
.02
.02
:02
.02
.02
.02
.02
.02
.02
.02
.02
:02
.02
.02
.02
.02
.02
.02
.02
19 83.7 WG203114
17 85.2 WG203114 17 106. WG203114
• Rec Limit Ref Samp Batch
92.5 80-::120· L198851-0:7 'WG201994
104. 75-125 Ll98996-07 WG202030
.. 105. :. 75-125 ·Ll98996-07 WG202030
110. 75-125 Ll98996-_:07 WG202030
102 . 75-125 Ll98996-07 WG202030 102·, 75.-,-125 .. _ L198996:.07 .WG202030
89.2 75-125 Ll98996.:.07 WG202030
108. 75-125 Ll98996-07 WG202030 ~9_0·.-0 75-"125 . Ll98996·:..·07·. WG202030
~-?~•-7 80-120 L199027-02 WG202036 . •. ' . '--!, "-.; ·;,-5-125 Li98996--06 WG2020'97 87.5
· ··98; O'' 7,0;:130 ' Ll99076-:,16 WG202457
102. 80-120 L199303-04 WG202605
. ..
42.0 80-120 Ll.'99177-08 WG202663
·118.:· 57..:133 · 'Ll99056.::01 WG202!;>,76
91°. 7 54-143 L199056-0l WG202676
91.9 58-134 Ll99056-01 WG202676
95.9 59.::125 · L199056;01 WG2026_76
75.3 53-136 L199056-01 WG202676
88.4 58-145 Ll99056-01 WG202676
76.6 58-126' ·•L199056":01 WG202676
93.1 48-127 Ll99056~01 WG202676
102. 57-145 Ll99056-01 WG202676
,:~.: 86·:1_ ,41--;127 · -L199056-.0l WG202676
96.5 52-125 Ll99056-0l WG202676
93.7 44-138 Ll99056-0l WG202676
91 :5·-5_0'~.127; L199056~01'. WG202676
78.2 54-145 L199056-0l ·wG202676
77.7 55-135 L199056-01 WG202676
101. 54-125 Ll99056_..;.0L·WG202676
101. 47-128 Ll99056-0l WG202676
101. 72-110 Ll99056-0l WG202676
86·;6 _47::-123: L199_056'...~0l WG202676
80.8 44-143 L199056-01 WG202676
105. 51-135 L199056-0l WG202676
98. 7 57-123 · L199056.:..01 .. WG202676
70.1 51:_134 Ll99056-01 WG202676
118. 60-131 Ll99056-0l WG202676
80.2 58-1·35 Ll99056-:-0l ,WG202676
86.4 54-139 L199056-0l WG202676
109. 52-144 Ll99056-0l WG202676
73. 0 21.:131 L199056..:_ol WG202676
92.3 51-147 L199056-01 WG202676
ENVIRONMENTAL
SCIENCE CORP.
Piedmont Geologic Mr. John Harper
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Chlorobenzene
Analyte
Chlorodibromomethane
Chloroethane · ·
Chloroform
Chloromethane·; _ . _. ,
cis-1,2-Dichloroethene
Di-isoproJi>yl e_th_er
Dichl"orodifl\loromethane Ethylbenzene--.
Hexachlorobutadiene
Isopiop}'lbenze·rie_. , ._" ,~ _ ,,
Methyl tert-butyl ether
Methylene chloride n..:.But}'lberizene'
n-Propylbenzene
Naphthalene p,)sopr6pYltol\lene
sec-Butylbenzene
Styrene.
tert:-Butylbenzene Tetrachloroethene Toluene
tralls·:-1, 2..:.nichloroethene · Trichloroethene Trichlorofluoromethane
V,inyl' chlO:dde
Xylenes, Total
1 fl, 1, 2-Tetrachlo"roeth'aii:e' 1,1,1-Trichloroethaii.e ·
1,1,2,2-Tetrachloroethane 1·, 1·;-2'-.Triclilo'rOeitliaiie' 1, i-DichlOi:-o·e·thii.ti.€!. --.
1,1-Dichloroethene
1, 1-DichlOrOpiOpene:::··· -~-~--
1, 2, 3-Trichlorobenzene
1, 2, 3_-TrichloroprC)p_ane
-1, 2, 4 .:::Tifmeth}"lbe_nzene~-· :; · .. -
1,2-Dibromo-3-Chloropropane
1,2-Dichlorobenzene 1', 2:.Dichl'.oroetharie ;_~ . .~--~:-,· ·;, 1,2-Dichloropropane
1, 3, 5_-Trimethylbenzene 1';'3:-D~ChrorOb~nz_ene ,"': 1,3-Dichloropropane
1,4-Dichlorobenzene
2, 2-D_:i,chl6"r0P!'0Pa~e ··; 2-Chlorotoluene
4-Chlorotoluene Benzene· .. ·~.-.. Bromobenzene
Bromochloromethane BromodiChloromethane Bromoform ··
Bromomethane ·_carbon1 Teit_ra:_chlori"de
Chloiobenzene
Chlorodibromomethane
Chloroethane ·
Chloroform
Quality Assurance Report
Level II
mg/1
Unite
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1 mg/1·
mg/1
mg/1
1198996
0.0221 0.00
.Matrix Spike
MS Res Ref Res
0.0242 0.00
0.0173 o .o·o
0.0153 0.00
;O :·0127 ·. 0 .:oo
0.0157 0.00
0. 0131 0.00
0.0156 o·.-oo
0. 0216 0.00
0.0176 0.00
.02
TV
.02
.02
.02
, :02
.02
.02
.02
.02
.02
mg/1 ,1, ,0. 0229, o·.-oo. · .02 ·
mg/1 0.0144 0.00 .02
mg/1 0.0139 0.00 .02
mg/1 \o•. 0163 0/00 :02
mg/1 o.·0203 0.00 . 02
mg/1 0.0189 0.00 . 02 mg/I·.·. · 0 .··0206 o.oo ·:02 ..
mg/1 0.0220 0.00 . 02 mg/1 0.0194 0.00 .02
mg/1 0-.10234 0 :OO· .. :02:
mg/1 0.104 0.0800 . 02
mg/1 0.0163 0.00 .02
mg/1 0~0152 0.00 , .02 :·
mg/1 o'.·0193 0.00 .02 mg/1 0.0189 0.00 .02
mg/1' :o :·01'44 0.00 ... 02
mg/1 o·. 0636 0.00 . 06
mg"/1 0 :-0220 0-.00 .-02
mg/1 0.0177 0.00 .02
mg/1 0.0196 0.00 .02
ing/1 0, 0205-o·;oo: .1·.-... 02
mg/1 0.0188 0.00 .02
mg/1 0.0200 0.00 .02
ing/1. o·.0110. o. oo·-~ ·~: :02
mg/1 0,0193 0.00 .02
mg/1 0.0211 0.00 .02
. -mg/1 o:019a O·. 000_2·; ~·02 ..
mg/1 0.0202 0.00 .02
mg/1 0.0182 0.00 .04
:mg/ls ... 0/0176 0. 00 · .02
mg/1 0.0213 0.00 .02
mg/1 0.0196 0.0000 .02
12065 Lebanon Rd.
Mt. Juliet, TII 37122
[phone]
1-800-767-5859
Frut [phone]
Tax I .0. 62-0814289
Eat. 1970
May 23, 2005
111. 59-125 1199056-01 WG202676
% Rec Limit Ref Samp Batch
121. 57-133 Ll99056-01-WG202676
86.5 38-153 L199056.:01 WG202676
76.7 55-133 L199056-0l WG202676
63·;5' 39-135 L199056--01-WG202676
78.4 64-126 L199056-01 WG202676
65.5 53-132 L199056-01 WG202676
11 :·a• 26-el53, .L199056-01 ,WG202676
ioa. 55-125 L199056-0l WG202676
88.1 51-109 L199056-01 WG202676
115 •. ;, 59.:-121·. L199056-0l WG202676
72 .1 50-137 L19905.6-01 WG202676
69.7 44-143 L199056-01 WG202676
8L3 .47=-124 -L199056-01 WG202676
102 . 53-154 L199056-0l WG202676
94.6 45-141 L199056-01 WG202676
103·. ·s2-:126',. L199.056.~.01 ·WG202676
110 . 54-127 L199056-01 WG202676
96.9 55-121 L199056-0l WG202676
117·. · · 57.,:12s •..:'·L199:o5_6~ oi_ WG202676
122 . 53-128 L199056-0l WG202676
81.7 57-126 L199056-01 WG202676
-·76'-. 0 052.;.139 ·;L199056-'01· WG202676
96.4 57-135 L199056.:.01 WG202676
94.4 42-134 L199056-0l WG202676
.12•.·o 4·4·-132· •,.L199056-0l -WG202676
106 . 54-129 L199056-,iOl WG202676
110. 57~133 L199148-01' WG202859
88.6 54-143 L199148-01 WG202859
97.9 58-134 L199148-01 WG202859
102 ;: ;58--'125' L1991'48~01'--WG202859 -9·4. 0 53-136 L199148-01 WG202859
100. 58-145 L199148-01 WG202859
·: 84'.8 58':'12'6 Ll99148-01" WG202859
96.4 48-127 Ll99148-0l WG202859
106. 57-145 L199148-01 WG202859
'· 97 '. 9 52-125 ·L199148-01 WG202859
101. 44-138 L199148_:0l WG202859
45.6 50-127 Ll99148-01 WG202859
;_,as .1· s{.::145 \L199148-~0l· WG202859
107. 55-135 L199148-01 WG202859
98.0 54-125 L199148-0l WG202859
.mg/1" · 0•;'0196' · , .o ;_ oo ... > :.-o.4 ;\.·· ,:.:4a ;·9,<41.:._120· \ Li991'4 8 ~O_b !WG2_02 85 9
mg/1 0.0196 0.00 .02 98.2 64-125 L199148-0l WG202859
mg/1 0.0178 0.00 .02 89.1 47-47 Ll99148-0l WG202859
• ... _mg/L. 0.0192.· 0;00~~··>02· _96·:2 '44'-;143' ."·Ll99148·.:01 WG202859
mg/1 o·. 0206 0.0000 .02 103: 51-135 L199148-01 WG202859
mg/1 0.0205 0.00 .02 102. 57-123 L199148-0l WG202859
mg/1. 0.0171 0:00 ' . 02· 85:5'51-134 Ll99148-01 WG202859
mg/1 0.0210 0.0000 .02 105. 60-131 L199148-01 WG202859
mg/1 0.0164 0.00 .02 81.9 58-135 L199148-0l WG202859
mg/1 0.0226 0. 004_3 . 02 91.4 -54--139 L199148~01.WG202859
mg/1 0.0231 0.00 .02 116. 52-144 L199148-01 WG202859
mg/1 0. 0148 0.00 .02 73.8 21-131 L199148-01 WG202859
.mg/1. 0.0190 0 .-00 .02 9.4. 9 51-147 L199148-01 WG202859
mg/1 o·. 02fo 0.00 .02 105. 59-125 L199148--o'l WG202859
mg/1 0. 0216 0.00 .02 108. 57-133 Ll99148-01 WG202859
mg/1 0;0189 0.00 '. 02 · 94.7 38-153 L199148-01 WG202859
mg/1 0. 0421 0.0260 .02 eo·.5 55-133 L199148-01 WG202859
Page 39 of 47
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
D
I
I
I
I
I
I
I
I
I
I
I
I
I
I
u
D
ENVIRONMENTAL
SCIENCE CORP.
Piedmont Geologic
Mr. Jolm Harper
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Chloromethane
Anal e
cis-.1, 2-Dichloroethene
Di-isopro~yl ether
Dichlorodifluoromethane
Eth}'lbenzene
Hexachlorobutadiene
Isopropylbenzene
Methyl<_tert-but:yL ether·'
Methyle·ne chloride
n-Butylbenzene
n:;-P:iopylben~ene·
Naphthalene
p-_lsopropyltoluene
aec:..sutylbenzene · ··
Styrene
tert-Butylbenzene
TetrachlorCiethene "?:.
Toluene
trana-1,2-Dichloroethene
Tri_chIOr6etherie~ t·/ ;_..·,, ·,.
TrichlorofluoromethcU"l'e
Vinyl chloride
Xyle"ries, . T6ta1· /
1,1,1,2-Tetrachloroethane
1,,-r, 1'-TriChloroetliclne,, .
1, 1, 2 ,·2-TetrclChlcil:"O-etha!l.Ei
1,1,2-Trichloroethane
1, 1-Dichl'OI:'Oethane ,·
1,1-DiChloroethene
1,1-Dichloropropene
1-", 2, 3-Trichlorob"en·zene f'
l,2,3~Trichl6ropr0parie
1, 2, 4-Trimethylben~en_e
1·, 2-:-Dibromo·-3-Chlot"ciPi-cipane i -·
1,2-Dichlorobenzene
1,2-Dichloroethane
l', 2._Dichloropropane
1,3,5-Trimethylbenzene
1,3-Dichlorobenzene
1:,·3~Di9hl_orop:ropane_ .. · ,;1:, .,
1,4-Dichlorobenzene
2,2-Dichloropropane
2;ChlOi"9tolueile' .. :·1..-',;,.~ :,;,, ·f •,
4-Chlorotoluene
Benzene
Bromobenzene ) ;·.~
Bromochloromethane
Bromodichloromethane
sromoform. ·
Bromomethane
Carbon Tetrachloride
Chlorobe"nzene ·
Chlorodibromomethane
Chlo roe thane
Chloroform
Chloromethane
cia-1,2-Dichloroethene
Di-isoproi;>yl• ether ' ,
Dichlorod1fluoromethane
Quality Assurance Report
Level II
lllg/1
Units
.mg/.1
mg/1 mg/1
·.' · ,.'mg/,1-·
mg/1
mg/1
·mg/X,· mg/1
mg/1 mg/•l. mg/1.
mg/1
ing/1·
mg/1
mg/1 ·mg/1"
mg/1
mg/1
mgh mg/1
mg/1
mgf:l
mg/1
mg/L.· mg/1
mg/1 ing/~ •. ·
mg/1
mg/1
.• <mg/h
mg/1 mg/1
";ing/1'
mg/1 mg/1 • mg/1-.
mg/1
mg/1
mg/1•:·.
mg/1
mg/1
. mg/1·
mg/1
mg/1
mg/1
mg/1
mg/1
ing/1 ·,
mg/1
mg/1 mg/1'
mg/1
mg/1
: .. mg/1.
mg/1
mg/1 -mg/1
mg/1
L198996
0.0220 0.00
Matrix Spike
MS Res Ref Res
.02
TV
·0.0192 _Q;OO .02
0.0176 0.00 :02
0.0308 0.00 .02
0 .. 0211 ,·o;·oo .-02
0.0191 0.00 .02
0.0219 0.0000 .02
· · 0~0106 o:~o · · ~-02
0.0145 ·o.·oo .02
0.0178 0.0000 .02
'·, 0.0204 .-0.0001 .02
0."0178 0.00 .04
0.0215 0.0000 .02
·0:0200 ·.0~0001 .02
0.0101 0.0006 .02
0.0221 0.00 ,02
·0.0196.·~-\o·.oo .:·02 ·
0,0185 0.00 .'02·
0.0185 0.00 .02
010106 ~\o:oo .102
0.0165 .. 0.00 .02
0.0177 0.00 .02
·o: 0617 ·:o·. oooe . 06 ·
0.0228 0.00 .02
•o:·0190., .. 0.00 .02-
o.·02i3 ··o.oo .02
0.0215 0.00 .02
,0. 0184 ,,,0: 00 -.·02
o.~196 o.oo .02
0.0180 0.00 .02
.0•';'0183 0-.-00---. •.•·:02
·o.0·202 o·:oo .02
0.0195 0.00 .02
o:•:0194 · .o. oo,_ . 02
0.0181 0.00 .04
0.0208 0.00 .02
0.0180 .0.00 .02
0.0199 0.00 .02
0,0205 0.00 .04 :o .. 0219, ·::: o. oo .. 02:·
0.0172 0.00 .02
0.0197 0.00 .02
-0::0212 .. •o-.:oo · ·:·02
o. 0203 o. oo· :02·
0.0169 0.00 .02
0'.0214 0;,00 ·:02
0.0180 o:oo .02
0.0202 0.00 .02
-0:0234 0;00 .02
0.0146 0.00 .02
0.0196 0.00 .02
0. 0227 0 .-00 .'02
0.0218 0.00 .02
0.0166 0.00 .02
0.0180 0·.·00 ~02
0.0174 0.00 .02
0.0199 0.00 .02
0.0171 o:oo .·02
0.0236 0.00 .02
Page 40 of 47
12065 Lebanon Rd.
Mt. Juliet, Til 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.O. 62-0814289
Eat. 1970
May 23, 2005
110. 39-135 Ll99148-01 WG202859
% Rec Limit Ref Sam Batch
96.0 .64-126 Ll99148',-01 WG202859
87.8 53-132 L199148-01 WG202859
154. 26-153 Ll99148-01 WG202859
-108. 55:-125-, L199l48"";01· WG202859
95.5 51-109 Ll99148-0l WG202859
109. 59-127 L199148-0l WG202859
'93-.0 50:-137,'·~Ll99148.:..01 WG202859
72.5 44-143 L199148-0l WG202859
88.9 47-124 L199148-01 WG202859
101 .. · 53:..124-.. L1991"48-.01 WG202859
44.4 45-141 L199148-01 WG202859
107. 52-126 L199148-01 WG202859
103. 54'7'127 ·L199148-01 WG202859
50.0 55-121 L199148-01 WG202859
111. 57-128 L199148-01 WG202859
'98'.1 53-128 Ll9914e·-ol WG202859
92.3 57-126 L199148-0l WG202859
92.5 52-139 L199148-01 WG202859
."93'.0, 5?'.-135 Ll99148-01'. WG202859
82.3 42-134 L199148-01 WG202859
88.4 44-132 L199148-01 WG202859
lOL. 5~-129 'L199148-0l WG202859
114. 57-133 L199140-01 WG202862
~9s.·1 54·:-143 L199140~01 ·WG202862
107. 58-134 L199140-01 WG2028.62
107. 58-125 L199140-0l WG202862
92·; 2 53-136..-''..L1991_40,-.0l ,WG202B.62
98.0 58~145 L199140-01 WG202862
90.1 58-126 L199140-01 WG202862
" :91; 7 48-:127'· ··,L1991'40-:0l· -WG202862
101. 57-145 L199140-0l WG202862
97.7 52-125 L199140-01 WG202B62
96. 8 44-.138 ., ·L199140·:.-01 WG202862
45.4 50-127 L199140--01 WG202862
104. 54-145 Ll99140-0l WG202862
.89.-8 55:.:135 _L199140::-0l 'WG202862
99.7 54-125. L199140-01 WG202862
51.3 47-128 L199140-01 WG202862
110 ~· · "64,.:.,12_5' .. '.,L1991·40!.,0l WG202B.62
86.l 47-47 L199140-01 WG202862
98.5 44-143 Ll99140-01 WG202862
106:'•-51"-1-35 ·,"L199140.:.01·-wG202062
101, 57-12J° L199140-01 WG202862
84.5 51-134 Ll99140-01 WG202862
107' .. 60..:131 '. L199140-'0l";WG202B.62
. a·9.8 58-135 L199140-01 WG202862
101. 54-139 L199140-01 WG202862
117: 52-_14_4 ~,L199140-01 'WG202862
73. 2 ·21-131 'L199140H-01 WG202862
97.8 51-147 L199140-0l WG202862
114· .. 59,-125-'. L199140,7,0l WG202862
109. 57-133 L199140-0l WG202862
83.1 38-153 L199140-01 WG202862
89.8 55::-1·33:"L199140-:'0l' WG202862
87 .2 39-135 L199-l40-0l WG202862
99.3 64-126 L199140-01 WG202862
85.6_537132 Ll99140-0l_ WG202862
118. 26-153 L199140-01 WG202862
ENVIRONMENTAL
SCIENCE CORP.
Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Ethylbenzene
Analyte
Hexachlorobutadiene IsOp"roPylbenZerie . .
Methyl_ tert-butyl ether Methylene-chloride, ·
n-Butylbenzene
n-Propylbenzen_e Naphthalene:. · ; -.
p-Isopropyltoluene sec-Butylbenzene Styrene:: '.C:-: ,
tert-Butylbenzene Tetrachloroethene
Toltlerie::-. -'"
trans-1;2-riichloroethene
Trichloroethene
TriChlOrofluOroffiethane VinYl chloiide
Xylenes, Total • :·· _.,-,,,, • ,' . . '. t, ••.•
i' 1; 1, i-Te'tr"ach10rOethan·e
1,1,1-Trichloroethane 1'·, 1', 2', 2.:...Tet:rachlor'6ethane
1,1,2-Trichloroethane
1,1-Dichloroethane
·l·, 1~Dichloio'etherie·.
1,1-DichloroproPene
1,2,3-Trichlorobenzene
-1. ,·2, 3.:-Ti-iChlOioproparie
1,2,4-TrichlOrobenzene
1,2,4-Trimethylbenzene
l' / 2 :: Dibidrrici7" 3_'-:'ChloioPiciP.ine
1,2-Dichlorobenzene
1,2-Dichloroethane
l', 2:..nichl'Orop:iopaiie"•
1,3,5-Trimethylbenzene
1,3-Dichlorobenzene
1'·, 3-DiChlol:'opio1iaile· 1,4-Dichlorobenzene
2,2-Dichloropropane 2-·ChrorotOlue!le, .. .,. /'
4-Chloro-toluene· "
Benzene Bri:miobehz·ene·•·_ . , ·> 1,:,-• · ..... • -s ....
Bromochlorom"etharie
Bromodichloromethane Bici[(lofoim'.1'."..·"·~<-:"~--:•.:" \· •,,. · "~-· ~· · •·
BromometliaI1.~ .
Carbon Tetrachloride
·Chlorobenzene · . ,-.
Chlorodibromomethane
Chloroethane
Chloroform·
Chloromethane
cis-1,2-Dichloroethene
Di-isciprop'y-r· ether
DichlorodifluOromethane
Ethylbenzene
Hexachl"orobutadiene
tsoi;>ropylbE'!nzene
Quality Assurance Report
Level II
Ll98996
mg/1 0. 0214 0.00 . 02
Matrix Spike
Units MS Res Ref Res TV
mgil 0.0186 · ,·O. 00 .02
mg/1 o.·0214 0,00 .02 mg/1 0.0182 0.00 .02
iitg/1·'.: · ·' 0·:'0145 .. :;·0'.:00 .02
mg/1 0.0154 0.00 .02 mg/1 0.0198 0.00 .02
mg/1 · ff. 0169 :· .~o :_oo. :·04
mg/1 0.0210 0.00 .02
mg/1 0.0206 0.00 .02
. mg/1 ,or•. 0196". 0'.·00 ,":02
mg/1 0.0225 o .·oo .02
mg/1 0.0193 0.00 .02
mg/1 0:0186 0. 00. .. :02 mg/1 0.0188 0.00 .02
mg/1 0.0197 0.00 .02 mg/1; · ,0:0161· ·o. oo .,:02 mg/1 0.0152 o·. oo .02
mg/~ 0.0620 o,. 0000 .06 ,,;·,. __ \. ~.,<•·
mg/1 a.Do 0.0193 .02
mg/1 0,0175 0.00 .02
mg/1•·" ··,.,o: 0162 o·:oo ;·02
mg/1 0.0167 0.00 .02
mg/1 0.0169 0.00 .02
mg/1· · ·,_o·. 0114 ,0. 00 .02 mg/1 0.0164 o .·oo .02
mg/1 0.0163 0.00 .02 . mg/1· 0.0191·_ o,.-. 00 '. 02., mg/1 o·:0151 0.00 .02
mg/1 0.0179 0.00 .02 ·mg/1 ,:,r,: 0~0156 ).:;J',_D;;00:,,;, .. 02,:~•:
mg/1 o: 0176 0.00 .02 mg/1 0.0167 0.00 .02
107 .
t Rec
.·93 .1
107.
91. 0
72 .5.
76.9
99.2
'. 42.-:-3
105.
103.
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 23, 2005
55-125 Ll99140-0l WG202862
Limit Ref Samp Batch
51-:109 L199140-0l ·WG202862
59-127 Li9914.0-0l WG202862
50-137 L199140-01 WG202862 44..:143' ·L1991"40.::01 WG202862
47-124 L199140-01 WG202862
53-124 Ll99140-01 WG202862
·45:-141<. ;Ll991·40.::*o,l'.. WG202862
52-126 L199140-01 WG202862
54-127 L199140-0l WG202862
.,97.·. 8 ,55~-121·· Ll99140.;.01·, WG202862
113. 57-128 Ll99140-01 WG202862
96.5 53-128 Ll99140-01 WG202862
93·.-2 57.~126 L199140;.:.01• .WG202862
94.1 52-139 Ll99140-0l WG202862
98.5 57-135 Ll99140-0l WG202862
__ 00~·7· 42:..·134 L199140-0l' WG2028.62
15 :0 44-132 Ll99140--0l WG:i028.62
103. 54-129 Ll99140-0l WG202862 ... , ' • '"'~;• .;••~?,.,•,J\~•~\ '·/ J ( ,,: 57~{3'3 96.6 L199475-02 WG203114
87.5 54-143 Ll99475-02 WG203114
01-:-·2 5_8_il34 Ll99475-02 ·WG2031-14
83.7 58-125 Ll99475--02 WG203114
84.4 53-136 Ll99475-02 WG203114
87.2•'58-;.145 ,L199475-02 WG203114
81. 9 50-12·6 Ll99475-02 WG203114
81.3 48-127 L199475-02 WG203114
:· 95. 3 57-145" · Ll99475:;__02', WG203114
78.4 41-127 Ll99475-02 WG203114
89.7 52-125 Ll99475-02 WG203114
L:·}.·.78::2 ·44·::130 . Ll:994_15·_7_0_2 WG203114
88.1 50-127 Ll99475-02 WG203114
83.6 54-145 Ll99475-02 WG203114 ·mg/F :.-:o·:oi64\r_ •::;o~oo·i.< ·/02· . ! ~ ,. ,,82. 2 55"'-,135·, ·Li99475-'02 WG203114 Ll99.475-02 mg/1 0.0198 0.00 .02 99.1 54-125 WG203114
mg/1 0.0194 0.00 .02 97.0 47-128 Ll99475-02 WG203114 ·m9;1-o.·.-0183 -;.-o\ oo :02 91.6 '64-125:1 · Ll99475.:.02 .. WG203114
mg/1 0.0156 0.00 .02 78.1 47-123 Ll99475-02 WG203114
mg/1 0.0190 0.00 .02 95.0 44-143 Ll99475-02 WG203114 . mg/Y., .. o :0192·, · o·. oo .02: .,._,96"; 2 ~51-::135\ _:Ll99_4 75'-.02,. WG2 03114
mg/1 0.0184 0.00 .02 92.2 57-123 Ll99475-02 WG203114
mg/1 0.0152 0.00 .02 76.1 51-134 Ll99475-02 WG203114
tfug/1\,Ji ,}; 0(;018,4 '· ::.O·:·oo, ... : 02· . 92::'0'..~_60_;:131 L19_9_475.::02 i_WG203_1-14
mg/1 0,0154 0.0011 .02 71.2 58-135 Ll99475-02 WG203114 mg/1 0.0169 0.00 .02 84.5 54-139 Ll99475-02 WG203114 ••ing/1' _ ,o_.~·0205/i.,?OlO.O -~ --;~02''(( ·_:102·.t: .s_2'.:f4'4: · ',L199,4 75.?~02 .:WG2 03114
mg/1 0.0119 0.00 .02 59.3 21-131 Ll99475-02 WG203114
mg/1 0.0184 o.oo .02 92.2 51-147 L199475-02 WG203114
mg/1 , 0'. 0189 · ·o: 0,0·'.; .02 94 .4 '59:-125 'L199475:-02· WG203114
mg/1 0,0199 0 .00 .02 99.S 57-133 Ll99475·--02 WG203114
mg/1 0.0157 0.00 .02 78.6 38-153 Ll99475-02 WG203114
ing/1 0.0165 o_. oo·; · :02 82 :5 55·.;.133 . 'L199.4 75-02' •WG203114
mg/1 0.0101 0.00 .02 90.7 39-135 Ll99475-02 WG203114
mg/1 0.270 0.290 .02 0.0 64-126 L199475-02 WG2D3114
·mg/1· o·:. 01_4a _._• ~, ,.o·. oo, -.02 74·. l 53'-132 -L199_475;;:02 WG203114
mg/1 0.0280 0.00 .'02 140. 26-153 L199475-02 WG203114
mg/1 0.0182 0.00 .02 90.9 55-125 Ll99475-02 WG203114
··1.ritg/l. 0:0168 ·· o·. oo ;02 84.1 51:..109 Ll99475f02 WG203114
mg/1 0.0200 0.00 .02 99·_ 9 59-127 Ll99475-02 WG203114
Page 41 of 47
I
I
I
I
I
I
I
I
I
I
I
I
I
I
n
n
g
I
I
I
I
I
I
I
I
I
I
I
I
I
I
D
D
I
ENVIRONMENTAL
SCIENCE CORP.
Piedmont Geologic
Mr. John Harper 6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Methyl tert-butyl ether
Analyte
Methylene chloride n-Butylbenzene
n-Propylbenzene
Naphthalene p-Isopropyltoluene
sec-Butylbenzene
Styrene ,:1·; :· ·: •• •
tert-Butylbenzene
Tetrachloroethene Toluene.-.-... ,-,.. · ' , ... ; 1, ., •
trans-1,2-Dichloroethene
Trichloroethene
TriChlorofluoromethane 1'
Vinyl chloride
Xylenes, Total
Analyte
TOC. (Total Organic CarbOn): L
Arsenic
Barium ;
Cadmium
Chromium
Lea_d . , "
Manganese
Selenium
Silver:·.
Nitrate
~~o~,-6[fis61;;d
Mercury
~~ _JT~~al Organ.i~ Carbon)
Alkalinity
1,; 1, 1, 2 :TetrachlorOetha:rie · ) '.
1, 1, 1-TiichlOroe'thalle·
1,1,2,2-Tetrachloroethane
1-,·1-,; 2.~TriChlOroethane ·,:. · ·''
1, 1-Dichloroethane ..
1,1-Dichloroethene
1-, 1:..o_ichloi-oprOpene~ ·l
1,2,3-Trichlorobenzene
1,2,3-Trichloropropane
1,·2, ·4·-TtichlOrobenzene
1,2,4-TrimethylbellZene
1,2-Dibromo-3-Chloropropane
1, 2-Dichlorobeniene·•
1,2-Dichloroetharie
1,2-Dichloropropane
1, 3~ 5·-Ti-imethylbenzene
1,3-Dichlorobenzene
1, 3-D_ichloropropane
1-, 4-Dichloiobenzene
Quality Assurance Report Level II
L198996
mg/1 0.0155 0.00 .02
Units
Matrix Spike
MS Res Ref Res . TV
mg/1 o·. 0126 o~oo .02 mg/1 0.0158 0.00 .02 mg/1 0.0181 0.00 .02 mg/1 0:0155 · ,0:'00 . 02 ..
mg/1 0.0187 0.00 .02 mg/1 0.0191 0.00 .02 . mg/1 0.017.8 o·:oo .02
mg/1 0.0196 o .·oo .02 mg/1 0.0231 0.0065 .02
mg/"f., 0.0158 0.00 .. ,,: .. ;02 mg/1 o.'0200 0.0034 .02 mg/1 0.0308 0.0140 .02 mg/,1 o·. 0154 0.00 ·.02
mg/1 0.0200 0.0052 .02
mg/1 0.0544 0.00 .06
, Matrix· Spike Duplicate
77.7
\ Rec
63.1·
79.2
90.3
7,7'. 7
93.4
95.6
88'; 8
98.2
83.1
78."9
83.1
84.2
7.7. 2
74.1
90.7
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax {615) 758-5859
Tax l.D. 62-0814289
Est. 1970
May 23, 2005
50-137 L199475-02 WG203114
Limit Ref Samp Batch
44-143 Ll99475-.02 WG203114
47-124 Ll99475-02 WG203114
53-154 Ll99475-02 WG203114 45-141 Ll99475-02 WG203114
52-126 Ll99475-02 WG203114
54-127 Ll99475-02 WG203114 55--;121 Ll99_475;-:02 ,WG203114
57-128 Ll99475-02 WG203114
53-128 Ll99475-02 WG203114 57-126, · Ll99.4,75.:.02.,WG2031·14
5:i-139 Ll99475-02 WG203114
57-135 Ll99475-02 WG203114
42-134 ·Ll99475-02 WG203114
44-132 L199475-02 WG203114
54-129 Ll99475-02 WG203114
Units MSD Res Ref Res RPD Limit \-Rec Ref Samp Batch
mg/1 20.7 20.S
mg/1 1.04 1.04
mg/1 1.45'•: ·: 1.44.
mg/1 1.10 1.10 mg/1 1.02 1.02 mgf,l L03': 1. 02·.
mg/1 7.29 7.29 mg/1 1.09 1.10 mg/1 0'.983 0. 980.
mg/1
' 5.29 4 .,79
;,.g11 .: 0. 9°9°4 0.988
·mg/1 o-.'0020 0 ·:_0029
mg/t 20.5 20.5
mg/1 S{o 43.0
. :mg/r . 0.0225-0:0236,
mg/1 0.0168 o·. 0103·
mg/1 0.0183 0.0184
.nig/F o-.·0191· .-0':0192"
mg/1 0.0147 0.0151 mg/1 0.0174 0.0177
mg/1 0\ 0144 0.'0153 mg/1 0.0185 0.0186 mg/1 0.0187 0.0203 mg/1 ·0·.0175 0 .'0172· mg/1 0.0186 0.0193
mg/1 0.0187 0.0187 mg/1· 0.0179 0.0183 mg/1 0.0150 0.0156
mg/1 0.0157 0.0155 mg/1 0 :·0193 0.0201 mg/1 0.0199 0.0201 mg/1 0.0193 0.0202 mg/1 0.0162 0.0173
Page 42 of 47
0.826 20
0.0963 20 . 0".694 20
0.182 20
0.490 20
0 .487 --20
0.0549 20
0. 548 20
0.306 20 ·
10.0 20
0.605 20
1. 72 20.
0.195 20
' ·,·· 28.0 20
-4 .65 21
8.74 22
0.209 27
-0 :426 ·19·
2.53 22
1.45 15
6 .03·.,, · 20;
0.610 26
8.46 24
1.42 26
3.59 26
0.0706 27
1,9.7 20
3.97 21
0.778 20
4.11 57
1.19 25
4.76 11
6.88 18
93.3
104.
106: 11·0.
102.
103 ..
88.8
107.
98:3
106.
88.0
96.3
102.
70.0
·11·3 ~, ,
0·4. 0
91.7
95.5'
73.4
87.1
72-.1,
92.6
93.3
87.3
93.1
93.7
89.-7
75'.2
78.4
96.6
99.3
96.4
80:9
L198851~07 WG201994
L198996-07 WG202030
L198996-07 WG202030
Ll98996-07 WG202030
Ll98996-07 WG202030
· L198996-07 WG202030
Ll98996-07 WG202030
Ll98996-07 WG202030
Ll98996-07 WG202030
L199027-02 WG202036 ..
' Wai62o97 Ll98996-06
Ll99076-16· WG?02457
Ll99303-04 WG202605
' wcii'cii663 Ll99177-08
Ll99056-0l WG202676
L199056--01 WG202676
L199056-0l WG202676
L199056~.01 -WG202676
Ll99056-01 WG202676
L199056-01 WG202676
Ll99056-0l' WG202676
Ll99056-0l WG202676
L199056-0l WG202676
Ll99056-0l WG202676
L199056-01 WG202676
Ll99056-01 WG202676
Ll99056-0l WG202676
Ll99056-0l WG202676
L199056-0l WG202676
Ll99056-0l WG202676
Ll99056-0l WG202676
L199056-0l WG202676
Ll99056-0l WG202676
ENVIRONMENTAL
SCIENCE CORP.
Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
21 2-Dichloropropane
Analyte
2-Chlorotoluene 4-Chlor·ot'Oluene
Benzene
BromObenzene . , .
BromochlOromethane
Bromodichloromethane Bromoforme·: · •,· .' · ·'.
BroffioTI\ethail.e · · ·
Carbon Tetrachloride
.Chlot:'Oberizene: '.,_,-.,,;,.;',~
Chlorodibromomethane
Chloroethane Chloroforin·
Chloiomethane
cis-1,2-Dichloroethene Di-is_opiOJi>yl-· ether.·:· -··0·_~~.
Dichlorodifluoromethane Ethylbenzene
Hf!xa·Chloi:-6btitadiehe ,
Isopi:-opylbenierie
Methyl tert-butrl ether ~ethylene. Chloride'.! -· -. ~ ,.
n-Butylbenzene
n-Propylbenzene
N?Pht~lene, . , .... ". p-Isopropyltoluene
sec-Butylbenzene Styrene ,::e,,-·?t·t{ •:r<_-(•.-:
tert-Butylbenzene Tetrachloroethene Tol_ueil.Ef,.\'.S_';:",-~·;:;", :, . . , .
trans-1,2-Dichloroethene Trichloroethene
Trichlob:>fllioromethan·e
vinyl chloride
Xylenes, Total
',., >-)~,;-;, ·:~~.;_ '• ••.c·,/•' •·• ._
1,1,1,2-Tetrachloroethane 1,1,1-Trichloroethane 1; 1; 2·, 2.-:Tetra_·c_hlo"r:o'e_t_hane
1,1,2-Trichloroethane 1,1-Dichloroethane
1~ 1'.~DiChloroethene .
1,1-Dichloropropene 1,2,3-Trichlorobenzene 1, 2, 3-Tr.fChl_or.oProparie_
1,2,4-Trichlorobenzene 1,2,4-Trimethylbenzene
1, 2-Di}?rom0.~3 !Chlo_ro"propane
1,2-Dichlorobenzene
1,2-Dichloroethane
1-~ 2:..oichlm;OprO"paile.. . 1,3,5-Trimethylbenzene
1,3-Dichlorobenzene 1, 3-Dichlo_l:'cipropane
1,4-Dichlorobenzene 2,2-Dichloropropane
2~ChloI'ot6luene'
4-Chlorotoluene
' ,.
Quality Assurance Report
Level II
12065 Lebanon Rd.
Mt. Juliet, TN 37122
{615) 758-5858
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Eat. 1970
May 23, 2005
mq/1
Ll98996
0.0151 0.0162 6.65 19 75.6 L199056-01 WG202676
Matrix,Spike Duplicate
Units MSD Res Ref Res RPD Limit \Rec Ref Samp Batch
0-. 0202 0. 0210
0 :0194 0. 0197
0.0136 0.0140
0.0227 .0.·0236
0.0161 0.0160
0.0170 0.0173
.mg/1
mg/1
mg/1 ,mg/1
mg/1 mg/1 ·mg/l·
mg/1
mg/1
mg/1
mg/1 mg/1
· '.0~0224·.· ::o·.021s
0.0156 0.0146
0.0172 0.0185
o:·021s-.,;10:,022i.-.
0.0229 0.0242
0.0171 0.0173
. 0.0150 .o·:,0153·
0.0125 0.0127
· mg/1 mg/1
mg/1 ing/l
mg/1
mg/1 mg/1 · mg/1
mg/1
mg/1· mg/1 mg/1
mg/l
mg/1 mg/1
.riig/T :i,' mg/1
mg/1 _·,mg/1-. ~
mg/1
mg/1 ,mg/1
mg/1 mg/1
0.0159 0.0157
0 .'0130 0; 0131'
0.0143 0.0156
0.0209 0.0216 ·. o·.0101. 0.01-16 ·
0.0224 0.0229
0.0140 0.0144
0.0140 . 0'.>01'39~-
0.0154 0.0163
0.0198 0.0203
0·. 0180 ~~-" 0 ;·0189
0.0200 o.o"io6
0.0208 0.0220 ,0-.-0197, 0·.-0194"
0.0223 0.'0234
0.0998 0.104 of'o163' -,.:. •o-~01631 •
o·:0150 · o. 015i
0.0185 0.0193
.... 0 .'01 75·;. • 0. 0189'
0.0140 0.0144
0.0618 0.0636
'-.,•0-}:-\.1,.:;. .,._.<•; ·' ·-,· ·mg1i '' . '-o·:·0~2'411',--' o~0"2i6'
mg/1 0.0182 0.0177 · ·:. tng/L .-0·. 0200 ,~ 0':·0196·
mg/1 0. 0207 ·~ 0 .'0205
mg/1 0.0191 0.0188
mg/1 ,:0-.0192 · 0~·0200
mg/1 0.0176 0.0170
mg/1 0.0225 0.0193
mg/1' ·O": 0224 •.•·,':.0. 0211
mg/1 ·o. 0225 o. 0109
mg/1 0.0207 0.0198
. mg/1 '0 '. 0216, . 0_;'0202
mg/1 0.0199 0.0182
mg/1 0.0187 0.0176
mg/1 · o :0176-o. 0213 mg/1 0.0207 0.0196
mg/1 0.0207 0.0196 mg/1 0. 0196 . ' .o. 0196 mg/1 0.0187 0.0178
mg/1 0.0190 0.0192
mg/1 0.0222 0.0206
mg/1 0.0204 0.0205
Page 43 of 47
3.91· 28
1. 79' 25
2.89 18
3 .-52' 22
0.0376 19
1. 90 19
2.69, 21
6.97 24
7.12 23
1'.31 22
5.73 19
1. 20 25
2·; 05 20
1. 79 23
1. 56 18 ·o·. ·4ts • 20_.
0· .·4s 25
3.18 20 ·2·:90·, ·22
2.27 26
3.24 21
0. 488·. ,22,
5.36 27
2.41 26
,5.22 '25
2.8-6 20·
5.64 20
1. 74 27
4.69 26
4.43 24
0:469 26 ·
l. 67 24
4.27 23 7'.33" ·21.
2.71 24
2.91 24
9.57 21
2.44 22
~-l'.-90. ·27 1.37 1'9
1. 68 22
3·:00,-15:
3.47 20·
15.6 26
,: .·6::15 · 24
17.4 26
4.12 26 1':oa ·21
8. 72 20
6.20 21
,19:·5' 20
5.36 27
5.52 25
0.272 ·19 ·4.68 18
1. 51 19
7.40• 28
0.343 25
101;
96.9
68.1
114·. ·
80.3
84.8
112:
78.2
85.9
109. ':'
114.
85.5
, 75'; 1,
62.4
79.6 •6s·:2
71.5
105.
9_0:.,r--
112.
69.8 ', 1,,70':,0:-
77 .·1
99.1
89·'. 0--~-100 ..
104. 98 .'6
112.
99.2
81'."4
74.8
92.4 87': 7
70.1
103.
L199056:..01 WG202676
Ll99056-0l WG202676
L199056-0l WG202676
L199056-0l WG202676
Ll99056-0l WG202676
Ll99056-0l WG202676
·Ll99056-0l WG202676
Ll99056-0l WG202676
Ll99056-0l WG202676
Ll99_056~.01· ,WG202676
Ll99056-0l WG202676
Ll99056-01 WG202676
: L199056:..ol WG202676
L199056-0l WG202676
Ll99056-0l WG202676
L199056;01· WG202676
L199056-01 WG202676
Ll99056-01 WG202676
Ll99056-01 WG202676
Ll99056-01 WG202676
Ll99056-01 WG202676 tt::·g~t-gi· :g;g;.~;~
L199056-01 WG202676
-L199056:..01.WG202676
Ll9905·6.:0l WG202-676
Ll99056-01 WG202676 Ll99056.C01' WG202676
Ll99056-01 WG202676
L199056-01 WG202676
'Ll99056~01 WG202676
L19"9'056-0l WG202676
Ll99056-01 WG202676
Ll99056:.0l WG202676
Ll99056-01 WG202676
Ll99056-0l WG202676
121. L199148-0l WG202859
90.8 Ll99148-0l WG202859
99 ;'8 Ll9_9_1'48/0l WG202859
104. Ll99148-0l WG202859
95.6 Ll99148-0l WG202859
·96';'2 ,_,· 'Ll99148;-fol WG202859
87-.8-. Ll99148-0l WG202859
113. L199148-0l WG202859
112·." L199148.-;-0~--WG202859
2.25 WG202859
102. Ll99148-01 WG202859
108 .·· Ll99148.::01 'WG202859
4-9. 8 Ll9914.8-0l WG202859
93.7 Ll99148-0l WG202859
.8,7. 8 Ll99l48:..,01 WG202859
103. Ll99148-0l WG202859
51.7 Ll99148-01 WG202859
97 .. 9 · Ll99148-0l WG202859
93.4 Ll99148-0l WG202859
94.8 Ll99148-0l WG202859
1-10-.' Ll991'48-01 WG202859
102·; Ll99148-0l WG202859
I
I
I
I
I
I
I
I
I
I
I
I
I
I
n
H
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
n
0
D
I
ENVIRONMENTAL
SCIENCE CORP.
Piedmont Geologic Mr. John Harper
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Benzene
Analyte
Bromoben.zene ..
Bromochloromethane
Bromodichloromethane
Bromofortri,
Bromomethane Carbon Tetrachloride
~i~~~~ig;~-~~~ethane
Chloroethane
Chl"orciforin · •··. {•.~:.
Chloromethane
cis-1,2-Dichloroethene
Di-isopropyL ether Dichlorodifluoromethane
Ethylbenz_ene Hexachlor6butadiene IB6propylbenzene
Methyl tert-_butyl ether Methylen·e:-_c:hlciride' ····;
n-Butylbenzene
n-Propylbenzene
Naphthalerie~·,.,_, .··
p-Isopropyltoluene sec-Butylbenzene
St)'.iehe!_ _ .. · f ., ·.
tert-Butylbenzene
Tetrachloroethene Tol_uene, , _,: .. · _ . ,
trans-1,2-Dichloroethene
Trichloroethene
TrichlorofliiorOmetha:rie
Vinyl chl6ride
~ylen€;S, Total
-"-• .
1,1,1,2-Tetrachloioethane
1,1,1-Trichloroethane
1, 1' ,·2, 2'-TetrachlorOethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1•; 1-Di.chloh)ethene.
1,1-Dichli::iropiopene
1,2,3-Trichlorobenzene
1';'2 ;:3-TriChlori::ipr-6p"ane,
1,2,4-Trichlorobenzene
1, 2, 4-Trimethylberizene_
1', 2:..nibroino-3-_ChlorOp"ropane,\.
1, 2-Dichlorobenzene -'
1,2-Dichloroethane
1, 2:-Dicl1,19i6prop.in¢ ...
1,3,5-Trimethylbenzene
1,3-Dichlorobenzene
1,3-DichloroProParie
1,4-Dichlorobenzene
2,2-Dichloropropane
2-Chlorotoluene
4-Chlorotoluene
Benzene
Bromobenzene
Bromochloromethane
Quality Assurance Report
Level II
L198996
mg/1 0.0168 0.0171 1. 72 18
Matrix Spike Duplicat·e
Units MSD Res Ref Res RPD Limit
mg/I: 0;0215 0 ;'0210 2.16 22 mg/1 0.0178 0.0164 8.23 19 mg/1 0.0226 0.0226 0.0781 19
mg/1 0 .. 0253 0.0231 .·9 .02 :.:21
mg/1 0.0141 0.0148 4. 32 24 mg/1 0.0191 0.0190 0.865 23
mg/L. ·o·. 0216' · 0.0210. ':2. 76 22
mg/1 0.0236 0.0216 8 .·a1 19 mg/1 0.0194 0.0189 2.59 25 mg/1 0'; 0430, 0:0421' ·.2. 01 20 mg/1 0.0215 0.0220 i,42 23 mg/1 0.0190 0.0192 1.25 18
mg/1 0.0171 0.'0176 2.85 20 mg/1 0.0284 0.0308 8.32 25
mg/1 0.0220 0.0217 1.41 20 mg/1 0.'0191 0 .·0191 0.0834 22 mg/1 0.0223 O. 0219 1. 82 26
mg/1 0.0180 0.0186 3.26 21 mg/1 · 0. 01'4.7 ··_0:.00145 1:::24 ·22
mg/1 o.oi'a5 0.0178 3.86 27
mg/1 0.0208 0.0204 2.19 26 mg/1 0.0202. .·o-. 0110·. 12.8 25
mg/1 0.0213 0.0215 0. 794 20 mg/1 0.0212 0.0208 1.83 20 mg/1 , o·.10091·. 0:0101 9.57 27 mg/1 0.0226 0.0221 1.91 26 mg/1 0.0211 0.0196 7.18 24
mgJr .0.0177: 0.0185 3. 95 , 26 '· mg/1 0.0186 0.0185 0. 60,6 24
mg/1 0.0195 0.0186 4 .85 23 mgf,l 0. 0171. • 0-/0165: ;3_'.:76 · •'"',21:
mg/1 0.0169 0.0177 4.76 24 mg/1 0.0630 0.0617 2 .21 24 . r. .-,. ~-,:· (
mg/1 0.0236 0.0228 3.67 21 mg/1 0.0184 0.0190 3.07 22
mg/1 0.0193 ·O. 0213 10.3",.-· 27 mg/1 0.0196 0.0215 9 .13 19
mg/1 0.0184 0.0184 0.0811 22 "mg/1 0.0198 o·. 0195 0.731 15 mg/1 0.0174 0.0180 3.53 20 mg/1 0.0180 0.0183 1. 99 26
mg/1 --o :0199';<.'.', -o·;:0202 ,:1.32 k:24,
mg/1 0.0158 0.0161 1. 78 26 mg/1 0.0184 0.0195 6.11 26
mg/1 o·. 0190 0:'0194 2 ;·11 ·27' mg/1 0.0190 0.0181 4 .41 20
mg/1 0.0189 0.0208 9.37 21 mg/1 0: 018,7 0.0180 3. 94 20 mg/1 0.0203 0.0199 1.66 27
mg/1 0.0188 0.0205 8 .69 25 n\g/1 0.0198 0.0219. 9.92 19 mg/1 0.0175 0.0172 1. 84 18
mg/1 0.0181 0.0197 8.44 19 mg/1 0.0203. 0:0212 4·_55 28
mg/1 0.0192 0.0203 5 .40 25 mg/1 0.0173 0.0169 2.59 18
mg/1 0.0206 0.0214 .,·3 ;54 ,22 mg/1 0.0171 0.0180 5.07 19
Page 44 of 47
12065 Lebanon Rd.
Mt. Juliet, TN 37122
(615) 75B-5858
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 23, 2005
84. 0 Ll99148-0l WG202859
\-Rec Ref Samp Batch
107" L199148:'·01 WG202859
88.9 Ll99148-0l WG202859
91.3 Ll99148-01 WG202859
127:;-·L199148:.01 WG202859
70.7 L199148-01 WG202859
95.7 Ll99148-01 WG202859
108':' Ll991'48;-0l WG202859
118. L199148-01 wG20·20s9
97.2 L199148-0l WG202859
84·. 8 · I.199148:;-0l ·WG202859
107. L199148-01 WG202859
94.8 Ll99148-0l WG202859
85.4 L199148-01 WG202859
142. Ll99148-0l WG202859
110. Ll99148-01 WG202859
95':S Ll99148-01 WG202859
111. Ll99148-01 WG202859
90.0 Ll99148-0l WG202859
73.4 Ll99148--01 WG202859
92.4 L199148-0l WG202859
103. L199148-01 WG202859
50·.5 · Ll99148-01· WG202859
106. L199148-0l WG202859
105. Ll99148-0l WG202859
45~4 Ll9914B,;01,.WG202859
113. Ll99148--01 WG202859
105. L199148-0l WG202859
88 .. 7,. L199_14B:~ol WG202859
93.1 Ll99148-01 WG202859
97.6 Ll99148-0l WG202859 . -85·.'5 ·, Ll'9914 a:..or wG202a59
84.3 Ll99148:0l WG202859
104. Ll99148-01 WG202859
118. Li9,9140-01 WG202862
92.2 1199140-01 WG202862 96-.3 L199140::-0l WG202862
98.0 L199140-01 WG202862
92.1 Ll99140-0l WG202862 ·99_ 8 L199140~_01" WG202862
87.0 Ll99140-01 WG202862
89.9 L199140-0l WG202862
-991:s" '' L199140'-0l WG202862
1.58 WG202862
91. 9 Ll99140-01 WG202862 90:·0 L199l40..:01 'WG202862
47.4 L199140-0l WG202862 94.6 L199140-01 WG202862
93.4 L199140-01 WG202862 101·. L199140.:01 WG202862
47. 0 Ll99140-0l WG202862
• 99 ::1. -·L1991'4o::-oi--WG202862
87.7 L199140:.01 WG202862
90.6 Ll99140-01 WG202862
101. ,L199140-01 WG202862
96.1 L199140-0l WG202862
86.7 Ll99140-0l WG202862
103. L199140-01 WG202862
85.3 L199140-0l WG202862
ENVIRONMENTAL
SCIENCE CORP.
Piedmont Geologic Mr. John Harper
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Bromodichloromethane
Analyte
Brornoform
Broinci"mE!:thane
Carbon Tetrachloride
Chlorobeniene •, .-
Chlorodibromomethane
Chloroethane
Chlciroform:t.~,
Chloromethane
cis-1,2-Dichloroethene oi:isop:t"i:i1;>yV.et_he_r -",. ,. . ,
Dichlorodifluoromethane
Ethylbenzene
HeXachlorobut·adiene
Isopropylbenzene
Methyl tert-bu_tyl eth~r Methylene. chlor_ide·;' ': ·
n-Butylbenzene
n-Propylbenzene
Naphthalerie_. ·. ••·. ·, , ' p-Isopropyltoluene
sec-Butylbenzene
Styrene ·, _'. ,:"-,
tert-Butylbenzene
Tetrachloroethene
T61!,!_e:'ne ,~-;;-· .', '. · ..
trans-1,2-Dichlorciethene
Trichloroethene
T:iichl'o:iofllloromethane--
Vinyl chloiide Xylenes, Total
'{ 1:·1, i:.'T~t•r·ach1oi:-~·~ti~~
1,1,1-Trichloroethane
1, 1·;·2 ,·2:-Tetrachlor'oethElne': 1,1,2-Trichloroethane
1,1-Dichloroethane
1·,:l-,-Di'chloi:o_ethene
1,1-Dichloropropene
1,2,3-Trichlorobenzene
1, 2·; 3_·.::_Tr'_i:chr6r_ohropaJ:le
1,2,4-Trichloro enzene
1,2,4-Trimethylbenzene
·l; 2-;D~bromo·~3e-_Chlcir"cipr0Pane
1,2-Dichlorobenzene
1,2-Dichloroethane
1;,·2:..nichro'roprOpane,:, ..
1,3,5-Trimethylbenzene
1,3-Dichlorobenzene
'''C :· :;-'
1·, _3_--:DiChloropi-oi;>aile .
1,4-Dichlorobenzene
2,2-Dichloropropane
2:-.,chlo'r6toluene
4-Chlorotoluene
Benzene
Bromobenzene .
BromochlOrOmethane
Bromodichloromethane Bi:-omofcirm
Bromometh.3.ri.e
. ~\
Quality Assurance Report Level II
mg/1
L198996
0.0183 0.0202 9.51
, Matr_ix Spike Duplicate . Units MSD Res Ref Res RPD
mg/1 0.0235 0 .·0234 0'484
mg/1 0.0125 0,0146 15.8
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
l-800-?67-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 23, 2005
19 91. 6 Ll99140-0l WG202862
Limit \Rec Ref Samp Batch
21 ,118. L199140-01 WG202862
24 62.5 L199140_:01 WG202862 rng/1 0.0196 0.0196 0.0912 23 97.8 L199140-01 WG202862
mg/1 0.0199 0 .·0227. :1-3 .-3 . 22 · 99·_5 L199140-01 WG202862 rng/1 0. 0213 0.0218 2.60 19 106. L199140-01 WG202862 mg/1 0.0184 0.0166 10.4 25 92.2 Ll99140-0l WG202862 ,mg/1' o':-0180 0.0180' ·::o ::439. .20-.,, ·,90 :2 ,L199140-01'· WG202862
mg/1 0.0169 0.0174 3.20 23 84.5 Ll99140-01 WG202862
mg/1 0.0176 0.0199 12.3 18 87.8 Ll99140-0l WG202862 rng/1 0';017_3, · ,o·.-0111 'l.·15 20 ',86":'6' ·, :,L1991'40-:0l' WG202862 mg/1 0.0223 0 :0236 5.60 25 112. Ll99140-01 WG202862
mg/1 0.0207 0.0214 3.13 20 104. Ll99140-0l WG202862 mg/1 0 ;01 72 O~Ol86 0·.23·. 22 0s .-0 L199140.;:-,0l WG202862 mg/1 0. 0213 0.0214 0.235 26 107. Ll99140-0l WG202862
rng/1 0.0186 0.0182 2.22 21 93.1 L199140-0l WG202862 mg/1 0.0152 0.0145 4.96 22 76:2 L199140::01 WG202862 rng/1 0.0156 0.0154 1.61 27 78.2 L199140-01 WG202862
mg/1 0.0196 0.0198 1.25 26 98.0 Ll99140-01 WG202862
mg/1 0;0165 ·o·. 0169 2;62 25, · 41;.2· Ll99140-0l WG202862 rng/1 0.0192 0.0210 9.16 20 95.8 L199140-01 WGi02862
mg/1 0.0201 0.0206 2.50 20 100. Ll99140-01 WG202862
·rng/1 . 0 .·0203: .. " O·: 0196 -3 :·87 27 102. .-L199140-;-,01 .WG202862
rng/1 0.0217 0.0225 3.98 26 108. Ll99140-0l WG202862 rng/1 0.0206 0.0193 6.60 24 103. Ll99140-01 WG202862 mg/1 _Oa\0171. o·.·0106 · 8. 92. 26 85.3 Ll9914o:..or' WG202862
mg/1 0.0171 0.0188 9.32 24 85 .·7 L199140-01 WG202862 rng/1 0.0187 0.0197 5.09 23 93.6 L199140-01 WG202862
mg/F-: 0,:0157 .. 0 :·0161 · 2 ."91 21 ,79.;4, :L199140;.;0l. WG202862 rng/1 0.0160 0.0152 5.27 24 7'9_ 9 Ll99140-0l WG202862
rng/1 0.0590 0.0620 4.86 24 98.3 L199140-0l WG202862
\·:\'· . ,,.~, ., •· .. , _; ; :::,., •, ,'y //,· -~ .• • _: :i: .
mg/1 0.0199 ·o. 0193· 2. 79 21 99.4 Ll99475-02 WG203114 mg/1 0.0179 0,0175 2.17 22 89.4 Ll99475-02 WG203114 _mg/1" 0:0171 0_.;0162v-.r.5·.31 ·,,,; 27, -.. 05·.6--L199475':-02-WG203114
mg/1 0.0175 0.0167 4.62 19 87.7 L199475-02 WG203114 rng/1 0.0157 0.0169 6.98 22 78.7 L199475-02 WG203114
mg/1 J,'.,, 0'.,0185 ,·0.:-01 7,4' .. ·_ ·.5 :98 . . 15 ~-92\ 61 L199475-02 ;WG203114
mg/1 0.0170 0.0164 3.63 20 84.9 Ll99475-02 WG203114 mg/1 0.0190 0.0163 15.6 26 95.1 L199475-02 WG203114 mg/1, >,:o:. 0193 0.0191 . ,L26 24 ._·95·-;·5 Ll994,7_5;"'.02 _WG203114
mg/1 0.0174 0.0157 10.6 26 87.2 L199475-02 WG203114 mg/1 0.0177 0.0179 1.23 26 88.6 L199475-02 WG203114 ,_mg/1 · 0,.-0111•.-i::·0_;0156.'. ·,.9_·.-21 .-27. ·85:~·,7 ~ · L19 9_4 .7.5·'-, 02., WG2 _03114
mg/1 0. 01 72 0.0176 2.22 20 86.1 L199475-02 WG203114
mg/1 0.0179 0.0167 6 .61 21 89.3 Ll99475-02 WG203114 'mg/1,, 0.0181 o·.'0164.·.i: ,9::50: ·20 . 9"6·;-4. Ll99475-02·-WG203114
mg/1 0.0187 0.0198 6.06 57 93.3 L199475·-02 WG203114 mg/1 0.0189 0.0194 2.90 25 94.3 Ll99475-02 WG203114
. rng/1 0.'0186 · 0 '.'0183: ,,1_.; 54 19 93'.0 · ,.L199475;c02 WG203114
mg/1 0.0175 0.0156 11.5 18 87.7 Ll99475-02 WG203114
rng/1 0.0193 0.0190 1.41 19 96.3 Ll99475-02 WG203114
mg/1·. 0.0197 0.0192 2·~ 34 28 :90-:,5 · L199,4.75;;":02, WG203114
mg/1 0.0181 0.0184 1.8-5 25 90.5 Ll99475-02 WG203114
rng/1 0.0150 0.0152 1. 59 18 74.9 Ll99475-02 WG203114
mg/1 -0.0190 0:0184 · · 3 .27 22· 95·.'0 L199475-02 WG203114
rng/1 0.0169 0. 015'4 9.30 19 78.7 L199475-02 WG203114
rng/1 0.0188 0.0169 10.6 19 94.0 L199475-02 WG203114
mg/1 0.0246 0.0205 ;t.8 .3 .. 21 123; L199475-02 WG203114
rng/1 0.0118 0.0119 0. 849 24 58.8 Ll99475-02 WG203114
Page 45 of 47
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
H
D
ENVIRONMENTAL
SCIENCE CORP.
Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Carbon Tetrachloride
Analyte
Chlorobenzene ,
Chlorodibromomethane
Chloroethane
Chl"oroform. Chloromethane
cis-1,2-Dichloroethene
Di":-iso()i-o~yl ether-: _;:.,
Dichlorodifluoromethane
Ethylbenzene
Hexachlorobutadie"ri"e :. Isopropylbenzene
Methyl tert-butyl ether
Methylene "chloride·-· ·,. ·
n-Butylbenzene
n-Propylbenzene Naphthalene-:_,,:, ..
p-Isopropyltoluene
eec-Butylbenzene
Quality Assurance Report
Level II
mg/1
L198996
0.0192 0. 0184 4.31
,Matrix Spike.Duplicate
UnitS MSD Res Ref Res RPD
ing/1 0.0189 -0.: 0189. 0.0469
mg/1 0. 019-6 0.0199 1.33
mg/1 0.0155 0.0157 1.36
mg/1. O·'. 0164 0.0165 · 0. 821
mg/1 0.0164 0.0181 10.3
mg/1 0.239 0.270 12.0
,mg/r .· .. 0.-0156. ,Q :01'48. ·s .37 .
mg/1 0.0277 0 ."0280 0. 936 ·
mg/1 0.0187 0.0182 2.97
;._ 'mg/1'_ '1·,./(0':-_0190. ::o,::.·0168 12 .,0.
mg/1 0.0195 0.0200 2.68
mg/1 0.0163 0.0155 5.09
mg/1· 0. 0135, 0':0126 6.46
mg/1 0.0168 0.0158 5.98
mg/1 0.0181 0.0181 0.487
• mg/1 o·: 0183 0.0155 16 .3'.'
mg/1 0.0195 0.0187 4 .47
mg/1 0.0194 0.0191 1.51
23
Limit
22
19
25
·20
23
18
20
25
20
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax l.D. 62-0814289
Est. 1970
May 23, 2005
96.2 L199475-02 WG203114
\Rec Ref Samp Batch
94 ;•5 L199475.:.02 WG203114
98.1 L199475-02 WG203114
77.6 L199475-02 WG203114
81.9. ··L199475_-02 WG203114
81. 8 Ll99475-02 WG203114
0.00 L199475-02 WG203114
.78'.2 .. ·--Ll99475-02 .WG203114
139. L199475-02 WG203114
93.6 L199475-02 WG203114
22 \ 9,4 .9 ··L199475.::.02· WG203114
L199475:._02 26 97.3 WG203114
21 81.7 Ll99475-02 WG203114
22 '67.'3 . -L199475:.:.·02 WG203114
27 84.1 L199475-02 WG203114
26 90.7 L199475-02 WG203114
25 91'.4 Ll99475-.02 WG203114
20 97.6 L199475-02 WG203114
20 97.1 L199475-02 WG203114
styrerie"< ~--: ... ~.;-._:. ;'... , ~· '· mg/1' 0\ 0182,. o·; 0110 2 ."16 ' · 27 go·. 0 L199,47S·.:.-02. WG203114
tert-Butylbenzene
Tetrachloroethene
Toltiene·· . , ··.-:. .. ~ ·: •
t rans-1, 2 -o·iChloroel:.li.ene
Trichloroethene
TrichloroflUoromethane
Vinyl chloride
Xylenes, Total
. ·•·•; '. ·~ .
mg/1 0.0204
mg/1 0.0245
mg/1 •o:. 0168
mg/1 0.0194
mg/1 0.0289
mg/1 ,o·. 0163·
mg/1 0.0191
mg/1 0.0549
0.0196
0.0231
·.o .•0150
o'.02o"o
0.0308
.o·.:01s4_ ..
0.0200
0.0544
Batch number /Run number/ Sample number cross reference
WG202007: R233129: Ll98996-0l 02 03 04 05 06 07
WG202097: R233208: Ll98996-0l 02 03 04 05 06 07
WG202030: R233266: L198996-0l 02 03 04 05 06 07
WG202036: R233432: L198996-0l 02 03 04 05 06 07
WG201994: R233592: L198996-01 02 03 04 05
WG202457: R233652: L198996-0l 02 03 04 05 06 07
WG202676: R233748: L198996-08
WG202663: R233800: L198996-0l 02 03 04 05 06 07
WG202605: R233804: L198996-06 07
WG202859: R234062: L198996-0l 02
WG202862: R234063: Ll98996-06 07
WG203114: R234091: Ll98996-03 04 05
3.89 26 102. Ll99475-02 WG203114
5.78 24 89.9 L199475-02 WG203114
5.98 26", 83 .-0 L199475702,. WG203114
3.32 24 79. 8 Ll99475-02 WG203114
6.55 23 74.4 Ll99475-02 WG203114
5.24 21 · .. 81·_. 3. Ll99475-'02 ,WG203114
4. 9'4 24 69.3 L199475.::02 WG203114
0.852 24 91.5 Ll99475-02 WG203114
* denotes out of limit range result. See Attachment B of standard report for list of qualifiers. * * Calculations are performed prior to rounding of reported values
Page 46 of 47
ENVIRONMENTAL
SCIENCE CORP.
12065 Lebanon Rd.
Mt. Juliet, TN 37122
{615) 758-5858
l-800-767-5859
Fax [phone]
Piedmont Geologic
Mr. John Harper
Tax l.D. 62-0814289
Eat. 1970
6003 Chapel Hill Road Suite 109 Quality Assurance Report
Level II Raleigh, NC 27607 May 23, 2005
Ll98996
ESC Level 2 Data Package
The data package includes a sununary of the analytic results of the quality
control samples required by the SW-846 or CWA methods. The quality control
samples include a method blank, a laboratory control sample, and the matrix
spike/matrix spike duplicate analysis. If a target parameter is outside
the method limits, every sample that is effected is flagged with the
appropriate qualifier in Appendix B of the analytic report.
Method Blank -an aliquot of reagent water carried through the
entire analytic process. The method blank results indicate if any possible contamination exposure during the sample handling,
digestion or extraction process, and analysis. Concentrations of
target analrtes above the reporting limit in the method blank are qualified with the "B" qualifier:
Laboratory Control Sample -is a sample of known concentration
that is carried through the digestion/extraction and analysis
process. The percent recovery, expressed as a percentage of the theoretical concentration, has statistical control limits
indicating that the analytic process is "in control". If a
target analyte is outside the control limits for the laboratory control sample or any other control sample, the parameter is
flagged with a "J4" qualifier for all effected samples.
Matrix Spike and Matrix Spike Duplicate -is two aliquots of an
environmental sample that is spiked with known concentrations of
target analytes. The percent recovery of the target analytes
also has statistical control limits. If any recoveries that are
outside the method control limits, the sample that was selected for matrix spike/matrix spike duplicate analysis is flagged with
either a "JS" or a "J6". The relative percent difference (\RPD) between the matrix spike and the matrix spike duplicate
recoveries is all calculated. If the RPD is above the method
limit, the effected samples are flagged with a "J3" qualifier.
Page 47 of 47
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
D
I
I
iiii -!l!!I !!!!I ·. -== . == ailil liiii ---
Alternate billing information:
'1"1 I,._, .• 11 G.-Lv -
sl ,~ /o5
si,a o5 ic? i5 -'5ii;;, lo5 -
s.,I 1B:I 93
•Matrix: SS ;o;t~id r3'Jt:.;.;r~~r v1-Wastewater DW -Drinking Water OT -Otr"r
Remarks: Y G
R ed by: (Signature) Date: Time:
1---f=-'.rl-() IS//)/
Re y; ( Date: Time:
Relinquished by: (
L -
Date: Time:
---------
pH
Prepared by:
Chain of Custody
Page-1__of__i_
• ENVIRONMENT AL
SCIENCE CORP.
12065 Lebanon Road
Mt Juliet TN 37122
Phone [phone]
Phone [phone]
FAX [phone]
______ Temp
I
I
I
I
I
I
I
I
e
u
I
n
I
I
ENVIRONMENTAL
SCIENCE CORP.
REPORT OF ANALYSIS
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
May 14, 2005 Date Received
Description NC State University Lot #86
Sample ID
Collected By
Collection Date
Parameter
Methane
Chloride
Nitrate
Sulfate
Alkalinity
Ethane
Ethene
MW-8
JG-SS
05/13/05 08,30
TOC (Total Organic Carbon)
Mercury
Arsenic
Barium
Cadmium
Chromium
Iron,Dissolved
Lead
Manganese
Selenium
Silver
Volatile Organics
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon Tetrachloride
Chlorobenzene
BDL -Below Detection Limit
Result
BDL
4000
540
BDL
110000
BDL
BDL
BDL
BDL
BDL
25.
BDL
BDL
BDL
BDL
60.
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
250
BDL
Det. Limit -Estimated Quantitation Limit(EQL)
Det. Limit
1000
1000
100
5000
50000
1000
1000
1000
0 .20
20.
5.0
5.0
10.
100
5.0
10.
20.
10.
1.0
1. 0
1.0
1.0
1.0
1.0
1.0
1. 0
1.0
50.
1.0
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 24,2005
ESC Sample # Ll99177-01
Site ID
Project # 2519
Units Method Date
ppb 8015M 05/16/05
ug/1 9056 05/15/05
ug/1 9056 05/15/05
ug/1 9056 05/15/05
ug/1 310.2 05/18/05
_ppb 8015M 05/16/05
ppb 8015M 05/16/05
ug/1 9060 05/19/05
ug/1 7470A 05/19/05
ug/1 60108 05/17/05
ug/1 6010B 05/17/05
ug/1 60108 05/17/05
ug/1 60108 05/17/05
ug/1 6010B 05/17/05
ug/1 6010B 05/17/05
ug/1 6010B 05/18/05
ug/1 6010B 05/17/05
ug/1 6010B 05/17/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/22/05
ug/1 6230D 05/20/05
Laboratory Certification Numbers:
C-TN-01
Oil.
1
1
1
1
5
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
50
1
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
00109, WV -233
Page 1 of 46
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 14, 2005
Description NC State University
Sample ID MW-8
Collected By JG-SS
Collection Date 05/13/05 08:30
Parameter
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
l,2-Dibromo-3-Chloropropane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
Di-isopropyl ether
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
p-Isopropyltoluene
Methylene chloride
Methyl tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,l-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #86
Result Det. Limit
BDL 1.0
BDL 1.0
8200 50.
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1. 0
BDL 1. 0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
210 50.
BDL 1.0
BDL 1.0
BDL 1.0
BDL 5.0
BDL 1. 0
BDL 1.0
BDL 1.0
BDL 1.0
14. 5.0
BDL 5.0
BDL 5.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
210 50.
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
90. 50.
Det. Limit -Estimated Quantitation Limit(EQL)
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 24,2005
ESC Sample# Ll99177-01
Site ID
Project# 2519
Units
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
Method
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
Date
05/20/05
05/20/05
05/22/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/22/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/22/05
05/20/05
05/20/05
05/20/05
05/20/05
05/22/05
Laboratory Certification Numbers:
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Page 2 of 46
C-TN-01
00109, WV
I
I
I
I
I
I
Dil.
ti
1
1 I 1
1
1
1
1 I 1
1
1
1
ti
1
1 I 1
1
1
1
1 I 1
1
1
1
1 I 1
1
1
50 ~· 1
501
I
I
I
I
I
I
I
I
I
I
I
0
D
I
D
I
I
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 14, 2005
Description NC State University
Sample ID MW-8
Collected By JG-SS
Collection Date 05/13/05 08:30
REPORT OF ANALYSIS
Lot #86
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax (615} 758-5859
Tax I.D. 62-0814289
Est. 1970
May 24,2005
ESC Sample#
Site ID
Project#
L199177-01
2519
Parameter Result Det. Limit Units Method Date Dil.
Trichlorofluoromethane 1.8 1.0 ug/1 1,2,3-Trichloropropane BDL 1.0 ug/1 1,2,4-Trimethylbenzene BDL 1.0 ug/1 1,3,5-Trimethylbenzene . BDL 1.0 ug/1 Toluene BDL 5.0 ug/1 Vinyl chloride BDL 1.0 ug/1 Xylenes, Total , BDL 3. 0 ug/1
Terri BDL -Below Detection Limit
Det. Limit -Estimated Quantitation Limit(EQL)
Laboratory Certification Number
6230D
6230D
6230D
6230D
6230D
6230D
6230D
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
Representative
C-TN-01
1
1
1
1
1
1
1
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA 00109, WV -233
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910 Note:
The reported analytical results relate only to the sample submitted.
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported: 05/23/05 18:20 Printed: 05/24/05 09:28 I Page 3 of 46
I
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 14, 2005
Description NC State University
Sample ID MW-16
Collected By JG-SS
Collection Date 05/13/05 09,15
Parameter
Methane
Chloride
Nitrate
Sulfate
Alkalinity
Ethane
Ethene
TOC (Total Organic Carbon)
Mercury
Arsenic
Barium
Cadmium
Chromium
Iron,Dissolved
Lead
Manganese
Selenium
Silver
Volatile Organics
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon Tetrachloride
Chlorobenzene
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #86
Result Det. Limit
BDL 1000
6000 1000
BDL 100
5500 5000
40000 10000
BOL 1000
SOL 1000
10000 1000
BDL 0 .20
BDL 20.
180 5.0
BOL 5.0
BOL 10.
2100 100
BOL 5.0
22000 10.
BDL 20.
BDL 10.
860 50.
BOL 50.
BOL 50.
BOL 50.
BOL 50.
BDL 50.
BDL 50.
BDL 50.
BDL 50.
210 50.
150 50.
Det. Limit -Estimated Quantitation Limit(EQL)
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-08142B9
Est. 1970
May 24, 2005
ESC Sample#
Site ID
Project#
Units Method
ppb 8015M
ug/1 9056
ug/1 9056
ug/1 9056
ug/1 310.2
ppb 8015M
ppb 8015M
ug/1 9060
ug/1 7470A
ug/1 60108
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 62300
ug/1 62300
ug/1 6230D
ug/1 62300
ug/1 6230D
ug/1 6230D
Ll99177-02
2519
Date
05/16/05
05/15/05
05/15/05
05/15/05
05/18/05
05/16/05
05/16/05
05/19/05
05/19/05
05/17/05
05/17/05
05/17/05
05/17/05
05/17/05
05/17/05
05/18/05
05/17/05
05/17/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
Laboratory Certification Numbers:
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Page 4 of 46
C-TN-01
00109, WV
I
I
I
I
I
I
Oil.
1 I 1
1
1 I 1
1
1 I
1
1 u 1
1
1
1 I 1
1
1
1 I 1
50
ii
50
50
HI
50
50 I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
D
I
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 14, 2005
Description NC State University
Sample ID MW-16
Collected By JG-88
Collection Date 05/13/05 09:15
Parameter
Chlorodibromomethane
Chlo roe thane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
l,2-Dibromo-3-Chloropropane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
Di-isopropyl ether
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
p-lsopropyltoluene
Methylene chloride
Methyl tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroetharie
Tetrachloroethene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #86
Result Det. Limit
BDL so.
BDL so.
22000 500
BDL so.
BDL so.
BDL 50.
BDL so.
BDL so.
BDL 50.
BDL so.
BDL so.
BDL 50.
BDL 50.
BDL so.
BDL 50.
BDL 50.
2900 500
BDL 50.
BDL so.
BDL so.
BDL 250
58. so.
BDL so.
BDL 50.
BDL 50.
650 250
BDL 250
BDL 250
BDL 50.
BDL so.
BDL 50.
BDL 50.
860 50.
BDL so.
BDL 50.
BDL so.
700 so.
1400 50.
Det. Limit -Estimated Quantitation Limit(EQL)
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
l-B00-76?-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 24,2005
ESC Sample#
Site ID
Project#
Units Method
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 62300
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 62300
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
Ll99177-02
2519
Date
05/20/05
05/20/05
05/22/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/22/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
Laboratory Certification Numbers:
C-TN-01
Oil.
50
50
500
50
50
50
50
50
50
50
50
50
50
50
50
50
500
50
50 so
50
50
50
50
50
50 so
50
50
50
50
50
50
50
50
50
50
50
AIHA -100789, AL -40660, CA -1-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
00109, WV -233
Pages of 46
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 14, 2005
Description NC State University
Sample ID MW-16
Collected By JG-SS
Collection Date 05/13/05 09:15
Parameter
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Toluene
Vinyl chloride
Xylenes, Total
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #86
Result Det. Limit
BDL so.
BDL so.
BDL so.
BDL 50.
630 250
BDL 50.
270 150
Det. Limit -Estimated Quantitation Limit(EQL)
Laboratory Certification
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 24,2005
ESC Sample#
Units
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
Terri
Site ID
Project #
Method
6230D
6230D
6230D
6230D
62300
6230D
6230D
Ll99177-02
2519
Date
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
resentative
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, GA 923, IN C-TN-01
00109, WV KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -840M.,-'!T'I" 2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Note:
The reported analytical results relate only to the sample submitted.
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported, 05/23/05 18,20 Printed, 05/24/05 09,28
Page 6 of 46
I
I
I
I
I
I
Oil.
501 so
50
50 sol 50
50
I
I
I
I
I
I
I
I
H
I
I
I
I
I
I
I
I
I
I
n
I
I
n
D
I
I
I
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 14, 2005
Description NC State University
Sample ID MW-36S
Collected By JG-SS
Collection Date 05/13/05 10:00
Parameter
Methane
Chloride
Nitrate
Sulfate
Alkalinity
Ethane
Ethene
TDC (Total Organic Carbon)
Mercury
Arsenic
Barium
Cadmium
Chromium
Iron.Dissolved
Lead
Manganese
Selenium
Silver
Volatile Organics
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon Tetrachloride
Chlorobenzene
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #86
Result Det. Limit
BDL 1000
45000 1000
BDL 100
BDL 5000
32000 10000
BDL 1000
BDL 1000
45000 1000
BDL 0 .20
BDL 20.
330 5.0
5.8 5.0
BDL 10.
BDL 100
BDL 5.0
16000 10.
BDL 20.
BDL 10.
1200 so.
BDL 50.
BDL so.
920 50.
BDL 50.
BDL so.
BDL 50.
BDL 50.
BDL so.
570 50.
65. 50.
Det. Limit -Estimated Quantitation Limit{EQL)
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
l-B00-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 24,2005
ESC Sample#
Site ID
Project#
Units Method
ppb 8015M
ug/1 9056
ug/1 9056
ug/1 9056
ug/1 310.2
ppb 8015M
ppb 8015M
ug/1 9060
ug/1 7470A
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 62300
ug/1 6230D
Ll99177-03
2519
Date
05/16/05
05/15/05
05/15/05
05/15/05
05/18/05
05/16/05
05/16/05
05/19/05
05/19/05
05/17/05
05/17/05
05/17/05
05/17/05
05/17/05
05/17/05
05/18/05
05/17/05
05/17/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
Laboratory Certification Numbers:
C-TN-01
Oil.
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
50
50
50
50
50
50
50
50
50
50
50
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-'395, NY -11742, NJ -81002, WI -998093910
00109, WV -233
Page 7 of 46
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 14, 2005
Description NC State University
Sample ID MW-36S
Collected By JG-SS
Collection Date 05/13/05
Parameter
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
l,2-Dibromo-3-Chloropropane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
Di-isopropyl ether
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
p-Isopropyltoluene
Methylene chloride
Methyl tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
BDL -Below Detection Limit
10:00
REPORT OF ANALYSIS
Lot #86
Result
BDL
BDL
19000
BDL
BDL
BDL
1200
BDL
BDL
BDL
BDL
BDL
710
BDL
BDL
BDL
1700
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
1700
BDL
BDL
BDL
BDL
BDL
BDL
78.
BDL
BDL
BDL
BDL
530
Det. Limit
50.
50.
1000
50.
50.
50.
50.
50.
50.
50.
50.
50.
50.
50.
50.
50.
50.
50.
50.
50.
250
50.
50. so.
50.
250
250
250
50.
50.
50.
50.
50.
50.
50.
50.
50.
50.
Det. Limit -Estimated Quantitation Limit(EQL)
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 24,2005
ESC Sample # Ll99177-:03
Site ID
Project # 2519
Units Method Date
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/22/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 .6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
Laboratory Certification Numbers:
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Page, 8 of 46
C-TN-01
00109, WV
I
I
I
I
I
I
Oil.
50, 50
100
50 501 50
50
50
50
501 50
50
50
50
501 50
50
50
501 50
50
50
50
ii
50
50
ii
50
50
ii
50
50 I
231
I
I
I
I
I
I
I
I
I
I
I
0
I
I
I
D
I
I
I
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 14, 2005
Description NC State University
Sample ID MW-36S
Collected By JG-SS
Collection Date 05/13/05 10:00
REPORT OF ANALYSIS
Lot #86
12065 Lebanon Rd.
Mt. Juliet, TN 37122
(615) 758-5B58
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 24,2005
ESC Sample # Ll99177-03
Site ID
Project# 2519
Parameter Result Det. Limit Units Method Date
Trichlorofluoromethane BDL so. 1,2,3-Trichloropropane BDL so. 1,2,4-Trimethylbenzene BDL so,
1,3,5-Trimethylbenzene BDL so.
Toluene 'BDL 250 Vinyl chloride BDL so, Xylenes, Total BDL 150
Ter BDL -Below Detection Limit
□et. Limit -Estimated Quantitation Limit{EQL)
Laboratory Certification Numb
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
6230D
6230D
6230D
6230D
6230D
6230D
6230D
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
C Representative
C-TN-01
Oil.
50
50 so
50
50
50
50
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA -
AZ -0612; MN -047-999-395, NY -11742, NJ -81002, WI -998093910 Note:
00109, WV -233
The reported analytical results relate only to the sample submitted.
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported, 05/23/05 18,20 Printed, 05/24/05 09,28 I Page 9 of 46
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 14, 2005
Description NC State University
Sample ID MW-2
Collected By JG-SS
Collection Date 05/13/05 11,00
Parameter
Methane
Chloride
Nitrate
Sulfate
Alkalinity
Ethane
Ethene
TOC {Total Organic Carbon)
Mercury
Arsenic
Barium
Cadmium
Chromium
Iron,Dissolved
Lead
Manganese
Selenium
Silver
Volatile Organics
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromofonn
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon Tetrachloride
Chlorobenzene
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #86
Result Det. Limit
BOL 1000
200000 2000
460 100
5700 5000
42000 10000
BOL 1000
BDL 1000
81000 1000
BDL 0.20
34. 20.
940 5.0
8.1 5.0
BOL 10.
230 100
BOL so.
65000 100
BOL 200
BDL 10.
1500 100
BOL 100
BOL 100
BOL 100
BOL 100
BOL 100
BOL 100
BDL 100
BOL 100
940 100
160 100
Det. Limit -Estimated Quantitation Limit(EQL)
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-08142B9
Est. 1970
May 24,2005
ESC Sample #
Site ID
Project#
Units Method
ppb 8015M
ug/1 9056
ug/1 9056
ug/1 9056
ug/1 310.2
ppb 8015M
ppb 8015M
ug/1 9060
ug/1 7470A
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 60108
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6230D
ug/1 62300
ug/1 6230D
ug/1 62300
ug/1 6230D
ug/1 62300
ug/1 6230D
ug/1 6230D
ug/1 62300
ug/1 6230D
ug/1 6230D
Ll99177-04
2519
Date
05/16/05
05/17/05
05/15/05
05/15/05
05/18/05
05/16/05
05/16/05
05/19/05
05/19/05
05/17/05
05/17/05
05/17/05
05/17/05
05/17/05
05/18/05
05/18/05
05/18/05
05/17/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
Laboratory Certification Numbers:
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,0W21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Page 10 of 46
C-TN-01
00109, W
I
I
I
I
I
I
1
1
1
1 LI
10 iol
100 1001 100
100
100
100 1001 100
100
100 1001
2331
I
I
I
I
I
I
I
I
I
I
I
g
D
I
I
g
D
I
I
I
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 14, 2005
Description NC State University
Sample ID MW-2
Collected By JG-SS
Collection Date 05/13/05 11:00
Parameter
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-Chloropropane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-0ichloroethane
1,2-0ichloroethane
1,1-0ichloroethene
cis-1,2-Dichloroethene
trans-1,2-0ichloroethene
1,2-0ichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
Di-isopropyl ether
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
p-Isopropyltoluene
Methylene chloride
Methyl tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #86
Result Det. Limit
BDL 100
BDL 100
25000 2000
BDL 100
BDL 100
BDL 100
260 100
, BDL 100
BDL 100
BDL 100
BDL 100
BDL 100
140 100
BDL 100
BDL 100
BDL 100
11000 2000
130 100
BDL 100
BDL 100
BDL 500
150 100
BDL 100
BDL 100
BDL 100
1600 500
BDL 500
BDL 500
BDL 100
BDL 100
BDL 100
BDL 100
960 100
BDL 100
BDL 100
140 100
BDL 100
710 100
Det. Limit -Estimated Quantitation Limit{EQL)
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-08142B9
Est. 1970
May 24,2005
ESC Sample#
Site ID
Project#
Units Method
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 62300
ug/1 6230D
ug/1 6230D
ug/1 62300
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 62300
ug/1 62300
ug/1 62300
ug/1 62300
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 62300
ug/1 62300
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 62300
ug/1 6230D
ug/1 62300
ug/1 62300
ug/1 62300
ug/1 6230D
ug/1 62300
ug/1 6230D
ug/1 6230D
L199177-04
2519
Date
05/20/05
05/20/05
05/22/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/22/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
Laboratory Certification Numbers:
C-TN-01
Oil.
100
100
2000
100
100
100
100
100
100
100
100
100
100
100
100
100
2000
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, r-1N -047-999-395, NY -11742, NJ -81002, WI -998093910
00109, WV -233
Page 11 of 46
ENVIRONMENTAL
SCIENCE CORP.
REPORT OF ANALYSIS
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax (615} 758-5859
Tax I.D. 62-0814289
Est. 1970
Mr. John Harper
Piedmont Geologic May 24,2005
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 14, 2005
Description NC State University
Sample ID MW-2
ESC Sample# Ll99177-04
Lot #86
Site ID
Project# 2519
Collected By JG-SS
Collection Date 05/13/05 11,00
Parameter Result Det. Limit Units Method Date
Trichlorofluoromethane BDL 100 ug/1 6230D 05/20/05
1,2,3-Trichloropropane 260 100 ug/1 6230D 05/20/05 1,2,4-Trimethylbenzene BDL 100 ug/1 6230D 05/20/05
1,3,5-Trimethylbenzene BDL 100 ug/1 6230D 05/20/05
Toluene 2700 500 ug/1 6230D 05/20/05
Vinyl chloride BDL 100 ug/1 6230D 05/20/05
Xylenes, Total 710 300 ug/1 6230D 05/20/05
Representative
BDL -Below Detection Limit
Det. Limit -Estimated Quantitation Limit(EQL)
Laboratory Certification Numb rs:
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E874~~.
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -
Note:
The reported analytical results relate only to the sample submitted.
-923, IN
-2006, VA
998093910
C-TN-01
00109, WV
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported: 05/23/05 18:20 Printed: 05/24/D5 09:28
Page 12 of 46
I
I
I
I
I
I
Oil.
100 I 100
100
100 1001 100
100
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
D
I
I
I
D
I
I
I
ENVIRONMENTAL
SCIENCE CORP.
REPORT OF ANALYSIS
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
May 14, 2005 Date Received
Description NC State University Lot #86
Sample ID
Collected By
Collection Date
Parameter
Methane
Chloride
Nitrate
Sulfate
Alkalinity
Ethane
Ethene
MW-3
JG-SS
05/13/05
TOC (Total Organic Carbon)
Mercury
Arsenic
Barium
Cadmium
Chromium
Iron,Dissolved
Lead
Manganese
Selenium
Silver
Volatile Organics
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon Tetrachloride
Chlorobenzene
BDL -Below Detection Limit
11: 45
Result
BDL
15000
BDL
BDL
76000
BDL
BDL
23000
BDL
BDL
700
BDL
BDL
1500
BDL
12000
BDL
BDL
6000
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
870
BDL
Det. Limit -Estimated Quantitation Limit(EQL)
Det. Limit
1000
1000
100
5000
10000
1000
1000
1000
0. 20
20.
5.0
5.0
10.
100
5.0
10.
20.
10.
250
250
250
250
250
250
250
250
250
250
250
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I .D. 62-0814289
Est_ 1970
May 24,2005
ESC Sample # Ll99177-05
Site ID
Project # 2519
Units Method Date
ppb 8015M 05/16/05
ug/1 9056 05/15/05
ug/1 9056 05/15/05
ug/1 9056 05/15/05
ug/1 310.2 05/18/05
ppb 8015M 05/16/05
ppb 8015M 05/16/05
ug/1 9060 05/19/05
ug/1 7470A 05/22/05
ug/1 6010B 05/17/05
ug/1 6010B 05/17/05
ug/1 6010B 05/17/05
ug/1 6010B 05/17/05
ug/1 6010B 05/17/05
ug/1 6010B 05/17/05
ug/1 6010B 05/18/05
ug/1 60108 05/17/05
ug/1 6010B 05/17/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 62300 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
Laboratory Certification Numbers:
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN -C-TN-01
Dil.
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
250
250
250
250
250
250
250
250
250
250
250
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA 00109, WV -233
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Page 13 of 46
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 14, 2005
Description NC State University
Sample ID MW-3
Collected By JG-SS
Collection Date 05/13/05 11:45
Parameter
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
l,2-Dibromo-3-Chloropropane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
Di-isopropyl ether
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
p-Isopropyltoluene
Methylene chloride
Methyl tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #86
Result Det. Limit
BDL 250
BDL 250
41000 2500
BDL 250
BDL 250
BDL 250
BDL 250
BDL 250
BDL 250
BDL 250
BDL 250
BDL 250
430 250
BDL 250
BDL 250
BDL 250
4300 250
BDL 250
BDL 250
BDL 250
BDL 1200
BDL 250
BDL 250
BDL 250
BDL 250
6500 1200
BDL 1200
BDL 1200
BDL 250
BDL 250
BDL 250
BDL 250
260 250
BDL 250
BDL 250
BDL 250
BDL 250
2100 250
Det. Limit -Estimated Quantitation Limit(EQL)
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax
Tax
, Est.
May 24,2005
ESC Sample #
Site ID
Project#
Units Method
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 62300
ug/1 62300
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 62300
ug/1 62300
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
[phone]
I.D. 62-0814289
1970
Ll99177-05
2519
Date
05/20/05
05/20/05
05/22/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
Laboratory Certification Numbers:
AIHA ;;-, 100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Page 14 of 46
C-TN-01
00109, WV
I
I
I
I
I
I
Dil.
250J 250
250
250 2501 250
250
250
250 2501 250
250
250
250 2501 250
250
250 2501 250
250
250
250 2501 250
250
250
250 2501 250
250
250
250 2501 250
250
250
250
I
2331
I
I
I
I
I
I
I
I
I
I
n
D
I
I
D
I
I
I
I
I
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 14, 2005
Description NC State University
Sample ID MW-3
Collected By JG-SS
Collection Date 05/13/05 11:45
Parameter
Trichlorofluoromethane I
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Toluene
Vinyl chloride
Xylenes, Total
BDL -Below Detection Limit
REPORT OF ANALYSIS
.Lot #86
Result Det. Limit
BDL 250
BDL 250
BDL 250
BDL 250
1200 1200
BDL 250
BDL 750
Det. Limit -Estimated Quantitation Limit(EQL)
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 24,2005
ESC Sample#
Site ID
Project#
Units Method
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
Ll99177-05
2519
Date
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
epresentative
Laboratory Certification Numbe s:...._ __ _____
C-TN-01
Oil.
250
250
250
250
250
250
250
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -£87487, GA -923, IN
KY -90010, KYUST · 0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA 00109, WV -233
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Note:
The reported analytical results relate only to the sample submitted.
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported: 05/23/05 18:20 Printed: 05/24/05 09:28
Page 15 of 46
ENVIRONMENTAL
SCIENCE CORP.
REPORT OF ANALYSIS
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
May 14, 2005 Date Received
Description NC State University Lot #86
Sample ID
Collected By
Collection Date
Parameter
Methane
Chloride
Nitrate
Sulfate
Alkalinity
Ethane
Ethene
MW-37
JG-SS
05/13/05 12, 00
TOC (Total Organic Carbon)
Mercury
Arsenic
Barium
Cadmium
Chromium
Iron,Dissolved
Lead
Manganese
Selenium
Silver
Volatile Organics
Benzene
Bromobenzene
·Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon Tetrachloride
Chlorobenzene
BDL -Below Detection Limit
Result
BDL
17000
BDL
BDL
37000
BDL
BDL
9200
BDL
BDL
170
BDL
BDL
BDL
BDL
2000
BDL
BDL
4200
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
1600
180
Det. Limit -Estimated Quantitation Limit(EQL)
Det. Limit
1000
1000
100
5000
10000
1000
1000
1000
0 .20
20.
5.0
5.0
10.
100
5.0
10.
20.
10.
100
100
100
100
100
100
100
100
100
100
100
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 24,2005
ESC Sample# : L199177-06
Site ID
Project # 2519
Units
ppb
ug/1
ug/1
ug/1
ug/1
ppb
ppb
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
Method
8015M
9056
9056
9056
310.2
8015M
8015M
9060
7470A
6010B
6010B
6010B
6010B
6010B
6010B
6010B
6010B
6010B
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
6230D
Date
05/16/05
05/15/05
05/15/05
05/15/05
05/18/05
05/16/05
05/16/05
05/19/05
05/19/05
05/17/05
05/17/05
05/17/05
05/17/05
05/17/05
05/17/05
05/18/05
05/17/05
05/17/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
Laboratory Certification Numbers:
AIHA -100789, AL· 40660, CA· I-2327, CT-PH-0197, FL· E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Page 16 of 46
C-TN-01
00109, WV
I
I
I
I
I
I
Dil.
1
1 I
1
1 I 1
1
1 I
1
1 I 1
1
1 I 1
1
1
1
1 I 1
100 1001 100
100
100
100 1001 100
100
100 1001
I
I
I
I
I
I
I
I
I
I
I
H
n
I
I
0
I
I
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 14, 2005
Description NC State University
Sample ID MW-37
Collected By JG-SS
Collection Date 05/13/05 12:00
Parameter
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-Chloropropane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
Di-isopropyl ether
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
p-Isopropyltoluene
Methylene chloride
Methyl tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #86
Result Det. Limit
BDL 100
BDL 100
68000 2000
BDL 100
BDL 100
BDL 100
730 100
BDL 100
BDL 100
BDL 100
BDL 100
BDL 100
920 100
BDL 100
BDL 100
BDL 100
1400 100
BDL 100
BDL 100
BDL 100
BDL 500
BDL 100
BDL 100
BDL 100
BDL 100
14000 10000
BDL 500
BDL 500
BDL 100
BDL 100
BDL 100
BDL 100
280 100
BDL 100
BDL 100
BDL 100
BDL 100
970 100
Det. Limit -Estimated Quantitation Limit{EQL)
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 24,2005
ESC Sample#
Site ID
Project#
Units Method
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 62300
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
Ll99177-06
2519
Date
05/20/05
05/20/05
05/22/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/22/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
Laboratory Certification Numbers:
C-TN-01
Dil.
100
100
2000
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
2000
100
100
100
100
100
100
100
100
100
100
100
100
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN -
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
00109, WV -233
Page 17 of 46
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 14, 2005
Description NC State University
Sample ID MW-37
Collected By JG-88
Collection Date 05/13/05 12:00
Parameter
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Toluene
Vinyl chloride
Xylenes, Total
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #86
Result Det. Limit
BDL 100
BDL 100
BDL 100
BDL 100
BDL 500
BDL 100
300 300
□et. Limit -Estimated Quantitation Limit(EQL)
Laboratory Certification
Units
ug/1
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
12065 Lebanon Rd.
Mt. Juliet, TN 37122
{615) 758-5858
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 24,2005
ESC Sample# Ll99177-06
Site ID
Project# 2519
Method
6230D
6230D
6230D
6230D
6230D
62300
6230D
Date
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
epresentative
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, , -923, IN C-TN-01
00109, WV KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -
Note:
The reported analytical results relate only to the sample submitted.
-2006, VA
998093910
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported: 05/23/05 18:20 Printed: 05/24/05 09:28
Page 18 of 46
I
I
I
I
I
I
Oil.
100 I 100
100
100
100 I 100
100
I
I
I
I
I
I
I
I
233
I
I
I
I
I
I
I
I
I
I
I
I
D
I
I
0
I
I
I
I
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 14, 2005 Description NC State University
Sample ID MW-35D
Collected By JG-SS
Collection Date 05/13/05 12:53
Parameter
Methane
Chloride
Nitrate
Sulfate
Alkalinity
Ethane
Ethene
TOC (Total Organic Carbon)
Mercury
Arsenic
Barium
Cadmium
Chromium
Iron,Dissolved
Lead
Manganese
Selenium
Silver
Volatile Organics
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon Tetrachloride
Chlorobenzene
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #86
Result Det. Limit
. BDL 1000
1600 1000
ll0 100
BDL 5000
56000 10000
BDL 1000
BDL 1000
BDL 1000
BDL 0 .20
BDL 20.
5.9 5.0
27. 5.0
BDL 10.
BDL 100
BDL 5.0
100 10.
22. 20.
BDL 10.
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
Det. Limit -Estimated Quantitation Limit(EQL)
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
l-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 24,2005
ESC Sample#
Site ID
Project#
Units Method
ppb 8015M
ug/1 9056
ug/1 9056
ug/1 9056
ug/1 310.2
ppb 8015M
ppb 8015M
ug/1 9060
ug/1 7470A
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 6010B
ug/1 60108
ug/1 6010B
ug/1 6010B
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
Ll99177-07
2519
Date
05/16/05
05/15/05
05/15/05
05/15/05
05/18/05
05/16/05
05/16/05
05/19/05
05/19/05
05/17/05
05/17/05
05/17/05
05/17/05
05/17/05
05/17/05
05/19/05
05/17/05
05/17/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
Laboratory Certification Numbers:
C-TN-01
Dil.
1
l
1
1
1
1
1
1
l
1
1
1
l
1
1
1
1
l
l
1
1
1
1
1
l
l
1
1
1
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
00109, WV -233
Page 19 of 46
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 14, 2005
Description NC State University
Sample ID MW-35D
Collected By JG-SS
Collection Date 05/13/05 12,53
Parameter
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
l,2-Dibromo-3-Chloropropane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
Di-isopropyl ether
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
p-Isopropyltoluene
Methylene chloride
Methyl tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #86
Result Det. Limit
BDL 1.0
BDL 1.0
4.0 1. 0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1. 0
BDL 1.0
BDL 1.0
BDL 1. 0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 5 .o
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 5.0
BDL 5.0
BDL 5.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1. 0
BDL 1.0
BDL 1. 0
BDL 1. 0
BDL 1. 0
BDL 1.0
BDL 1. 0
Det. Limit -Estimated Quantitation Limit{EQL)
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax (615} 758-5859
Tax I.D. 62-0814289
Est. 1970
May 24,2005
ESC Sample#
Site ID
Project #
Units Method
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 62300
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
Ll99177-07
2519
Date
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
Laboratory Certification Numbers:
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Page 20 of 46
C-TN-01
00109, WV
I
I
I
I
I
I
Dil.
1
1
1 I
1
1
1
1
1 I
1
1
1
1
1
1
1
1
1 I
1
1
1
1
1 I
1
1
1
1
1 I
1
1
1
1 I 1
1
1
1
1 I
1
1 I
2331
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
0
D
I
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 14, 2005
Description NC State University
Sample ID MW-35D
Collected By JG-SS
Collection Date 05/13/05 12,53
Parameter
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Toluene
Vinyl chloride
Xylenes, Total
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #86
Result Det. Limit
BDL 1.0
BDL 1.0
BDL 1.0
BDL 1.0
BDL 5.0
BDL 1. 0
BDL 3.0
Det. Limit -Estimated Quantitation Limit(EQL)
Laboratory Certification
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197,
12065 Lebanon Rd.
Mt. Juliet, TN 37122
(615) 75B-5858
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 24,2005
Units
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ESC Sample# Ll99177-07
Site ID
Project# 2519
Method
6230D
6230D
6230D
6230D
6230D
6230D
6230D
-923, IN
Date
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
C-TN-01
Oil.
1
1
1
1
1
1
1
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -Note:
-2006, VA -00109, WV -233
998093910
The reported analytical results relate only tO the sample submitted.
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported: 05/23/05 18:20 Printed: 05/24/05 09:28
Page 21 of 46
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 14, 2005
Description NC State University
Sample ID MW-12
Collected By JG-SS
Collection Date 05/13/05 13, 00
Parameter
Methane
Chloride
Nitrate
Sulfate
Alkalinity
Ethane
Ethene
TOC (Total Organic Carbon)
Mercury
Arsenic
Barium
Cadmium
Chromium
Iron,Dissolved
Lead
Manganese
Selenium
Silver
Volatile Organics
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon Tetrachloride
Chlorobenzene
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #86
Result Det. Limit
8DL 1000
50000 1000
8DL 100
8DL 5000
22000 10000
8DL 1000
8DL 1000
90000 1000
8DL 0 .20
8DL 20.
380 5.0
6.5 5.0
8DL 10.
8DL 100
8DL 5.0
13000 10.
8DL 20.
8DL 10.
4800 2000
8DL 2000
8DL 2000
8DL 2000
8DL 2000
8DL 2000
8DL 2000
8DL 2000
8DL 2000
8DL 2000
8DL 2000
Det. Limit -Estimated Quantitation Limit(EQL)
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 24, 2005
ESC Sample#
Site ID
Project#
Units Method
ppb 8015M
ug/1 9056
ug/1 9056
ug/1 9056
ug/1 310. 2
ppb 8015M
ppb 8015M
ug/1 9060
ug/1 7470A
ug/1 6010B
ug/1 60108
ug/1 60108
ug/1 60108
ug/1 60108
ug/1 60108
ug/1 60108
ug/1 6010B
ug/1 6010B
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
Ll99177-08
2519
Date
05/16/05
05/15/05
05/15/05
05/15/05
05/18/05
05/16/05
05/16/05
05/19/05
05/19/05
05/17/05
05/17/05
05/17/05
05/17/05
05/17/05
05/17/05
05/18/05
05/17/05
05/17/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
Laboratory Certification Numbers:
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Page 22 of 46
C-TN-01
00109, WV
I
I
I
I
I
I
Dil.
1 I 1
1
1 I 1
1
1 I
1
1 I 1
1
1
1 I 1
1
1
1 I 1
2000 2001 200
200
2000
2000 2001 200
200
2000
2000
H
I
I
I
I
I
I
I
I
I
I
n
R
I
I
D
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 14, 2005
Description NC State University
Sample ID MW-12
Collected By JG-SS
Collection Date 05/13/05 13, 00
Parameter
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-Chloropropane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
Di-isopropyl ether
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
p-Isopropyltoluene
Methylene chloride
Methyl tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #86
Result Det. Limit
BOL 2000
BOL 2000
45000 2000
BOL 2000
BOL 2000
BOL 2000
3800 2000
BOL 2000
BOL 2000
BOL 2000
BOL 2000
BDL 2000
BOL 2000
BOL 2000
BOL 2000
BOL 2000
22000 2000
BOL 2000
BDL 2000
BOL 2000
, BDL 10000
BOL 2000
BDL 2000
BOL 2000
BDL 2000
BDL 10000
BOL 10000
BOL 10000
BOL 2000
BDL 2000
BOL 2000
BOL 2000
BOL 2000
BOL 2000
BOL 2000
BOL 2000
BOL 2000
BOL 2000
Det. Limit -Estimated Quantitation Limit(EQL)
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 24,2005
ESC Sample#
Site ID
Project#
Units Method
ug/1 62300
ug/1 6230D
ug/1 6230D
ug/1 62300
ug/1 62300
ug/1 6230D
ug/1 62300
ug/1 6230D
ug/1 62300
ug/1 62300
ug/1 62300
ug/1 6230D
ug/1 62300
ug/1 62300
ug/1 62300
ug/1 62300
ug/1 62300
ug/1 6230D
ug/1 62300
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 62300
ug/1 6230D
ug/1 6230D
ug/1 62300
ug/1 62300
ug/1 62300
ug/1 6230D
ug/1 62300
ug/1 62300
ug/1 62300
ug/1 6230D
ug/1 62300
ug/1 62300
ug/1 6230D
ug/1 6230D
ug/1 62300
Ll99177-08
2519
Date
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
Laboiatory Certification Numbers:
C-TN-01
Oil.
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
00109, Wv -233
Page 23 of 46
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Date Received May 14, 2005
Description NC State University
Sample ID MW-12
Collected By JG-SS
Collection Date 05/13/05 13,00
Parameter
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Toluene
Vinyl chloride
Xylenes, Total
BDL -Below Detection Limit
REPORT OF ANALYSIS
Lot #86
Result Det. Limit
BDL 2000
BDL 2000
BDL 2000
BDL 2000
BDL 10000
BDL 2000
BDL 6000
Det. Limit -Estimated Quantitation Limit(EQL)
Units
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
Laboratory Certification Numb s:
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62 0B14289
Est. 1970
May 24,2005
ESC Sample#
Site ID
Project#
Method
6230D
6230D
6230D
6230D
6230D
6230D
6230D
Ll99177-08
2519
Date
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
05/22/05
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL 87487, -923, IN C-TN-01
00109, WV KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC - , TN
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -
Note:
The reported analytical results relate only to the sample submitted.
-2006, VA
998093910
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported: 05/23/05 18:20 Printed: 05/24/05 09:28
Page 24 of 46
I
I
I
I
I
I
Dil.
2001 200
2000
2000 2001 200
200
I
I
I
I
D
I
I
I 233
I
I
I
I
I
I
I
I
I
I
I
I
I
n
0
R
I
I
g
D
D
ENVIRONMENTAL
SCIENCE CORP.
REPORT OF ANALYSIS
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
May 14, 2005 Date Received
Description NC State University Lot #86
Sample ID
Collected By
Collection Date
Parameter
Volatile Organics
Benzene
Bromobenzene
TRIP BLANK 1
JG-SS
05/13/05 00, 00
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon Tetrachloride
Chlorobenzene
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-0ibromo-3-Chloropropane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-0ichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
Di-isopropyl ether
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
p-Isopropyltoluene
Methylene chloride
BDL -Below Detection Limit
Result
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
· BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
.BDL
Det. Limit -Estimated Quantitation Limit(EQL)
Det. Limit
1.0
1.0
1. 0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax (615) 75B-5859
Tax I.D. 62-0814289
Est. 1970
May 24,2005
ESC Sample#
Site ID
Project #
Units Method
.ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 62300
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 62300
ug/1 6230D
ug/1 62300
ug/1 62300
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 62300
ug/1 62300
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 62300
ug/1 62300
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
Ll99177-09
2519
Date
05/21/05
05/21/05
05/21/05
05/21/05
05/21/05
05/21/05
05/21/05
05/21/05
05/21/05
05/21/05
05/21/05
05/21/05
05/21/05
05/21/05
05/21/05
05/21/05
05/21/05
05/21/05
05/21/05
05/21/05
05/21/05
05/21/05
05/21/05
05/21/05
05/21/05
05/21/05
05/21/05
05/21/05
05/21/05
05/21/05
05/21/05
05/21/05
05/21/05
05/21/05
05/21/05
05/21/05
05/21/05
' Laboratory Certification Numbers:
C-TN-01
Dil.
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
AIHA -100789, AL~ 40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
00109, WV -233
Page 25 of 46
ENVIRONMENTAL
SCIENCE CORP.
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
May 14, 2005
REPORT OF ANALYSIS
Date Received
Description NC State University Lot #86
Sample ID
Collected By
Collection Date
TRIP BLANK 1
JG-SS
05/13/05 00,00
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-08142B9
Est. 1970
May 24,2005
ESC Sample # L199177-09
Site ID
Project # 2519
Parameter Result Det. Limit Units Method Date
Methyl tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Toluene
Vinyl chloride
Xylenes, Total
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
5.0 ug/1
5.0 ug/1
1.0 ug/1
1.0 ug/1
1.0 ug/1
1.0 ug/1
1.0 ug/1
1.0 ug/1
1.0 ug/1
1.0 ug/1
1.0 ug/1
1.0 ug/1
1.0 ug/1
1. 0 ug/1
1.0 ug/1
1.0 ug/1
5.0 ug/1
1.0 ug/1
3. 0 ug/1
6230D 05/21/05
6230D 05/21/05
62300 05/21/05
6230D 05/21/05
6230D 05/21/05
6230D 05/21/05
6230D 05/21/05
6230D 05/21/05
6230D 05/21/05
6230D 05/21/05
62300 05/21/05
62300 05/21/05
6230D 05/21/05
6230D 05/21/05
6230D 05/21/05
6230D 05/21/05
6230D 05/21/05
6230D 05/21/05
6230D 05/21/05
Representative
BDL -Below Detection Limit
Det. Limit -Estimated Quantitation Limit(EQL)
Laboratory Certification Numb
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84 , TN
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -
Note:
The reported analytical results relate only to the sample submitted.
-923, IN
-2006, VA
998093910
C-TN-01
00109, WV
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported: 05/23/05 18:20 Printed: 05/24/05 09:28
Page 26 of 46
I
I
I
I
I
I
Oil.
1
1 I 1
1
1
1
1 I
1
1
1
1
1 I
1
1
1
1
1 I
1
1 I
I
I
I
I 233
I
I
I
I
I
I
I
I
I
I
I
I
I
D
I
I
I
D
D
ENVIRONMENTAL
SCIENCE CORP.
REPORT OF ANALYSIS
Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Su~te 109
Raleigh, NC 27607
May 14, 2005 Date Received
Description NC State University Lot #86
Sample ID
Collected By
Collection Date
Parameter
Volatile Organics
Benzene
Bromobenzene
TRIP BLANK 2
JG-SS
05/13/05 00, 00
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon Tetrachloride
Chlorobenzene
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-Chloropropane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
Di-isopropyl ether
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
p-Isopropyltoluene
Methylene chloride
BDL -Below Detection Limit
Result
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
· BDL
BDL
BDL
BDL
BDL
BDL
,BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
Det. Limit -Estimated Quantitation Limit(EQL)
Det. Limit
1.0
1.0
1.0
1. 0
1.0
1.0
1.0
1. 0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1. 0
1.0
1. 0
1.0
1.0
1.0
1. 0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5959
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 24,2005
ESC Sample #
Site ID
Project#
Units Method
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 62300
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
ug/1 6230D
Ll99177-10
2519
Date
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
05/20/05
Laboratory Certification Numbers:
C-TN-01
Oil.
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, FL -E87487, GA -923, IN
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
00109, WV -233
Page 27 of 46
ENVIRONMENTAL
SCIENCE CORP.
REPORT OF ANALYSIS Mr. John Harper
Piedmont Geologic
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
May 14, 2005 Date Received
Description NC State University Lot #86
Sample ID
Collected By
Collection Date
Parameter
TRIP BLANK 2
JG-SS
05/13/05 00, 00
Methyl tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Toluene
Vinyl chloride
Xylenes, Total
BDL -Below Detection Limit
Result
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
Det. Limit -Estimated Quantitation Limit(EQL)
Det. Limit
5.0
5.0
1.0
1.0
1.0
1.0
1.0
1. 0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1. 0
3.0
Laboratory Certification
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 24, 2005
ESC Sample # Ll99177-10
Site ID
Project # 2519
Units Method Date
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05 ug/1 62300 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
ug/1 6230D 05/20/05
Representative
AIHA -100789, AL -40660, CA -I-2327, CT-PH-0197, E87487, GA -923, IN C-TN-01
KY -90010, KYUST -0016, NC -ENV375,DW21704, ND -R-140, SC -84004, TN -2006, VA
AZ -0612, MN -047-999-395, NY -11742, NJ -81002, WI -998093910
Note:
The reported analytical results relate only to the sample submitted.
00109, Wv
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported: 05/23/05 18:20 Printed: 05/24/05 09:28
Page 28 of 46
I
I
I
I
I
I
Oil.
1
1 I
1
1
1
1
1 I
1
1
1
1
1 I
1
1
1
1
1 I
1
1 I
I
I
I
I
I 233
I
I
I
'I
I Sample#
I Ll99177-01
L199177-04
Ll99177-08
I
I
I
I
I
I
g
I
D
n
I
I
I
I
D
'I
Attachment A
List of Analytes with QC Qualifiers
Analyte
Tetrachloroethene
Lead
Selenium
Iron,Dissolved
Manganese
Alkalinity
Dichlorodifluoromethane
Qualifier
E
0
0
J3
V
J6,J3
JS
Page 29 of 46
Qualifier
E
J3
JS
J6
0
V
Attachment B
Explanation of QC Qualifier Codes
Meaning
GTL (EPA) -Greater than upper calibration limit: Actual value is known to
be greater than the upper calibration range.
The associated batch QC was outside the established quality control range
for precision.
The sample matrix interfered with the ability to make any accurate
determination; spike value is high
The sample matrix interfered with the ability to make any accurate
determination; spike value is low
(ESC) Sample diluted due to matrix interferences that impaired the ability
to make an accurate analytical determination. The detection limit is
elevated in order to reflect the necessary dilution.
(ESC) -Additional QC Info: The sample concentration is too high to
evaluate accurate spike recoveries.
Qualifier Report Information
ESC utilizes sample and result qualifiers as set forth by the EPA Contract Laboratory Program and
as required by most certifying bodies including NELAC. In addition to the EPA qualifiers adopted
by ESC, we have implemented ESC qualifiers to provide more information pertaining to our analytical
results. Each qualifier is designated in the qualifier explanation as either EPA or ESC.
Data qualifiers are intended to provide the ESC client with more detailed information concerning
the potential bias of reported data. Because of the wide range of constituents and variety of
matrices incorporated by most EPA methods,it is common for some compounds to fall outside of
established ranges. These exceptions are evaluated and all reported data is valid and useable
unless qualified as 'R' (Rejected) .
Definitions
Accuracy -The relationship of the observed value of a known sample to the
Precision
Surrogate
true value of a known sample. Represented by percent recovery and
relevant to samples such as: control samples, matrix spike recoveries,
surrogate recoveries, etc.
The agreement between a set of samples or between duplicate samples.
Relates to how close together the results are and is represented by
Relative Percent Differrence.
Organic compounds that are similar in chemical composition, extraction,
and chromotography to analytes of interest. The surrogates are used to
determine the probable response of the group of analytes that are chem-
ically related to the surrogate compound. Surrogates are added to the
sample and carried through all stages of preparation and analyses.
Control Limits (AQ)
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
31-119
12-134
51-141
Nitrobenzene-dS 43-118 Dibromfluoromethane 70-130
2-Fluorobiphenyl 45-128 Toluene-dB 70-130
Terphenyl-dl4 43-137 4-Bromofluorobenzene 70-130
TIC Tentatively Identified Compound: Compounds detected in samples that are
not target compounds, internal standards, system monitoring compounds,
or surrogates.
(SS)
70-130
70-130
70-130
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
ENVIRONMENTAL
SCIENCE CORP.
Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Quality Assurance Report
Level II
L199177
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62 0814289
Est. 1970
May 24, 2005
I
I
I
I
An=~a~l~y~t~e ________________ __,R~e~s~u~l~t~?_.T_L_-~_b_.:o_::~_:.a_::t~:i~:~~-{~--~~=;:~i-=a_n_·k_·D~::a~·•~t~e_A=n~a~lLy~z~e~d'-------=B~a~t~c~h'-----------1
_C_hl'¢i;r i dE(/
Nitrate
Sulfate
1itlt!1~,::crtt:.:::=-·-:-:-•,: ... ·-
Ethene
Me_thai\E!W/?
Arsenic aari:um~);-:-;·:·:·-'··· ·· ·cactm:tt1m···,·
·-,::-;:,:.::··1/)''
< .1
< 5 . :-:;:•: :_:-: :.:.::''\\?:\:{)/\:\:it/}:&:'.:la'i
< • 01
-....-.-.··--·-·.,,,,:.:,:,\:=.< tto_:L\}:/?:
:'\mg/1\
mg/1
mg/1
?'. 05/J.5/05 o.o ,37
05/15/05 00,37
05/15/05 00,37
••iWG202141\•••
WG202141
WG202141
ppm • J~)iiJi~ si\da tGibit~~·•.·•·.•··
ppm 05/16/05 00,00 WG202243
ftpplli ,:::,:• t·\?0.5./J,6/.o5. ,o.oo.; oo\ :·,·twG20.2243.
< .02 mg/1 05/17/05 01,16 WG202250
·····.···.· .. ·. ··.·.·····•·•:>< ···too.s)( •· :::·•··t •,Jllig/-Ty• ·tt'fo5/17/05 ••oi-Y16:> \{wG2.022s.o:,:···•·••••·
< .005 mg/1 05/17/05 Ol,16. WG202250
Chromium Leaa::· ·
Manganese
Selenium
< .01 mg/1 05/17/05 01,16 WG202250 .......... · ..... ·· · ... ·· ··· · · ·. · ··• • ••;•• < .:005•/ ··" /mg/1"' •··y· 05/17 /05· .01,15' • •twG202250:·
< .01 mg/1 05/1B/05 20,15 wG20225'o
$. t ·3:-:Y:~_Y.:'/::C:'
Iron,Dissolved
1~hi;1tt(t~<,
:TC?.G)J '.1'9.t:~J \:J~:r'.9(:ftjJ¢{.~~tti.¢?i1 ))}}?-
< .02 mg/1 05/17/05 01,16 WG202250 ·•>< :01\••·•• \}ins/X• •:(os/11(.05 :01,1·6: ·· ·-<wG2.o.225.o•
< .1 mg/1
< 1 · ,,::: • \) ••• ::,xi~Yr·· ·
••···.•••••·n<•••·s•?1 ,>••· tftitititms·11
05/17/05 02,47
6~)i4)6J 07 '40
WG202251
WG202392
I
<
I:i:ttitit~t6~~i~~~;~h.>ne·· .. ····· ········ .. .. : >ggf> r~gjr .. §tjjg}g~. i➔;!i . ..,. :g~gi§;! ····•·•·········•·••·•··•·•······•·•··•·•· ,,rl
1,1,2,2-Tetrachloroethane < .001 mg/1 05/20/05 17:46 WG203024 l:/1}12';.:Ti"'iC:l1li:ff6'~t_ha'_i1e·:·"''•" .... ,,•,•·::<·=:\'.00·lt"• ,::fritg/.:1} :·y/}/Q,5/20/..0:5 '''l·-7 :··f6: "/\{WG203'02.4.
1, 1-n°i"chloro·e·thane < • 001 mg/1 05/20/05 1 7: 46 WG203024
1,1-Dichloroethene < .001 mg/1 05/20/05 17:46 WG203024 I :f/-1.':i:Pt¢h_l:c>i;.OP_i;_9'i):en::i~:/L::):t:>:·· '.'·:tt/'))).':\_< (/.9..() ~\\)?·':::=:::· }(:)ng/1 0 5 /_2 0/0 5 /!/?.})~. _:_,_,,,::_:)WG2 03·02'4''='·"' .
1,2,3-Trichlorobenzene < .001 mg/1 (;"5/26/05 17:46 WG'.io':f(:f.24
1 _ _,_2_,_3_~_T:r::i_chl_o_r9pr_()P_i:l:_n_~ < .001 mg/1 05/20/05 17:46 WG203024
-l,•2;.4cTrichlorobenzene.}/ •.-•::::•••• ::If•?:} ::•:••':::(/<}\001): } .. •••.,(}{.f:: .. mg/J: )i?\:,05/.20./05 •17c"46 WG20302.4\ 1,2,.4"-Ti-inleth)'lb.er-i"Zene··· < .001 mg/1 05/20/05 ··1··j";-"45· WG203024
1,2-Dibromo-3-Chloropropane < .002 mg/1 05/20/05 17:46 WG203024
1·2:,nI·chloroberizerie':•• ·• ·••·•.·· ..... ..,, ••••.•• •····•··;• • ..,...,. .... ••···•··•·•••<••<oor·)r• •••••••· ?•}{ing/1 •·• :>::os/20/05 ttT,4.6 ···••:t:J•wG.2_o302.4•/,:,·•·•••·
.t;.:i.~.•~~.~~tZ~·~i~ii;R~ene•••···•·· ········•.•·•····~·••::•.ggt... . .. .._~!;l ...... •·tr.:••·g!.~.·~.g.~.g! ..•.. tl.::i .. ···<v~g~g!g~!··•·•·•·•·····•···· ······················.· ... ·.·.·.·.·.· ·.····•.•··
1, 3-Dichlorobenzene < . 001 ffig/1. 05/20/05 1 7: 46 WG203024
l_i_..3.~Di_chlorop:n;:,p(ifle < . 001 mg/1 05/20/05 17: 46 WG203024 1./4•,.Dibhloroben.zene·· .•.• )<•(oor. . ..... ing/1·· 05/20/05· •n,46 ..... WG203024·
2,2:Dichlciropropane < .001 mg/1 05/20/05 17,46 WG:203024
2-Chlorotoluene < .001 mg/1 05/20/05 17,46 WG203024
4+,Chlorbtbltiehe\ ...... /:.:.. i /• 001,: . •• • •)\mg/L•··· . ··••OS/20/05 :p•,46.•:·• \{WG203024 ....
Benzene < .001 mg/1 05/20)05 17,46 WG203024
Bromobenzene < .001 mg/1 05/20/05 17:46 WG203024 :t~~~~~8~f-~:t~~~t~!J~>:l: //:?='='"=':'-'/\•:::,i}):~ig.F · (m~1T rJg:g·Jig}g~:: l➔={ti (<'n\:.gJg~g.§{i=:
Bromoform < .001 mg/1 05/20/05 17,46 WG203024
Brorriomethane•••••••••• • J•••r••••••••••••• · · .. ······.·.·.••·•·•·•·• ••:••/::\)/\'::i.\/001••> \llig/T\ ;:,,.• •OS'/20/05 ••:1.7 ,4.6 .:t•/\1'1.G.2.03 . .024.
Carbon TetraC1iiC/t.<i'd'e· < .001 mg/1 ..... -◊-5/26/os 17:46 WG203024
Chlorobenzene < . 001 . _ ._._ .. mg_/1 05/20/05 17: 46 WG203024 ChlOiOdibiciiii.Ome)::.hane:•-"" <:-···::~'00!'::='.";,·,·C<····, .. ,-.,:.,, .. :rng/1-: ·,:·,::-:=::,-:.:c.-os/20/05 /1-7.="::°4'6 ;::,,-,,=.:::::-.wG203·02·4--:c:':=::;_::,.:-
chlO:r"6E!'thariii'" "' ..... , """ < ~'o'o'i ing/1 ""ci'S/.:2°0/6"5 •'i 7·:·:,r6 WG:~(ci'.fb'24"'""
Chloroform < .005 mg/1 05/20/05 17,46 WG203024 n
Page 31 of 46
I
I ENVIRONMENTAL
SCIENCE CORP.
I Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109 I Raleigh, NC 27607
IAnalyte
I
Quality Assurance Report
Level II
Ll99177
--, . .,
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 24, 2005
···•··•:•:•?:;::,::,;:ooi ' ···•••· ·••t?,ii,g/1'·:,··. \.05/20/05\17/46/ ••••:wG203024'
·--·:·;µ~_p_o~~.tq:r;y1)3.·~•~tjK::>::
Result Units Date Analyzed Batch
ENVIRONMENTAL
SCIENCE CORP.
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
I
I
I Piedmont Geologic
Mr. John Harper
Tax I.D. 62-0814289
Est. 1970
6003 Chapel Hill Road Suite 109 Quality Assurance Report
Level II Raleigh, NC 27607
cis-1,2-Dichloroethene
Analyte
Pf\:i:S9't:if9PY.l\.:e·,thei-:::"::_:\:'\{\=:):/ Dichlorodifluoromethane Ethylbenzene
HeXa'ChlO"i·ObUt,i'di,'ene:: ·r sopropy1benz"e·ne·· ····
Methyl __ .t:.E=.J:t-_bt1ty_l __ ~-~~er M_e_1;J1y1_e_n:~>:.C.h.lo_:r-_i_de.:i · · ··
n-Butylbenzene
n-Propylbenzene
Ll99177
May 24, 2005 I
< . 001 mg/1 05/22/05 14,09 WG203235
?\:La)?Pt:a;.t:C?t:.Y)_Bf~ri~'::=::= Result Units Date Analyzed Batch I
••?>••?>••••> {<)001/ {/•\ f /nig/1 ))05/22/05 }14/09 ,}/)(WG203235.
< .001 mg/1 .. 05/22/cis 14,09 WG203235
< . 001 . mg/1 05/22/05 14, 09 WG203235
< ~ 'ggt "' ~~1/i t g~1/~;jg~. tf:g~.• r>~g§gH~·~· /
< .001 mg/1 05/22/05 14,09 WG203235
s /005)( ·.· >/mg/1) \o.S/22./05 ··1+!0~} }WG203235···
·~ . 001 mg/1 05/22/05 14, 09 WG203235 ······. >:--1
~cip~_t_}:i_a;Pitie):/??/)\'f:\/:-
p-I sopropyl toluene
sec-Butylbenzene s.f'./r·eB.e/:/::-0/f:'.?t?\:\:-,.=-
ter·t"-ButYit>eOzei-i"e
Tetrachloroethene
< . 001 mg/1 05/22/05 14, 09 WG203235 ········ ················· • .. ),7-:005:--•·•· ··.· ·•?••irig/II•• •·\.o5/22/05.T4·,•09•/· +w.G.20.323.5 •:::•··
< .001 mg/1 .. 05/22/05 i4i09 WG203235 ii
:T¢'-.l.\Je"ti:¢::'.\\,_=:.::,,,,:,-,=,,:,='·:::=,-·-=,,,,,,:-:'.'·/:\::::::\\:.=,,=::,,-,_,, .. trans-1,2-Dichloroethene
Trichloroethene
Tr;fCtilCfr(ff:l\i()_r'Qinethane·:/} Viii.Yi c·h"ioifctEi · · ··· ·
X lenes, Total
Analyte
·chlOi icte···,:,·:c;::,;x· -· .. _ ... _. ........... :,,,.,:·:-., .. :::,:::::-:_::':::/?
·chlOii"cte··
Nitrate Niti'ate.:;
Siitf a"t:Et
Sulfate
18J1{ ,b:jf(:i~--
Toc )(Tqfal organic c;;;rbon)/
Alkalinity Alkitl"iriit)'/='::
Ethene ~e.trya·net·
Arsenic
B'ii'rillrrV> tadrrd. um··· -
Chromium L:E;-ii"d'''
Manganese
Selenium SilV'e"r?/.:/:::::•
< .001 mg/1 •••••05/22/05 14,09 WG203235
:--:--• :--••••C::/\}<}/9:oL}• •:--•• •t•.\itig/1 {/i-":"••05/22/05 ••14/09{ ·••)WG203235
< • 001 mg/1 05/22/05 14 ,09 ·····wG2ci3235
< .001 mg/1 05/22/05 14,09 WG203235
./< ):005) }ing/1 \05/22/05 ·•14/09 X (WCl2.03235/
< . 001 mg/1 ············ os/i2Ns· ·1,Lo9···· WG203235
< • 001 mg/1 05/22/05 14, 09 WG203235
•····•.•·····•···•·· <Uo.0.1 t ing/1} t0.5/22/05.14;09 ..... •wG203235\·
< .001 mg/1 05/22/05 14,09 WG203235
< .003 m /1 05/22/05 14,09 WG203235
Units ?> pupric·a_tet):= Re.Sult .... o·Uplicate RPD Limit Ref Samp Batch
i.:.:tm§/1 ••··· ... ••·• .. >i4•!oiiJ ......... <t>•••4./oo•: .. ·r•·· •.t/1.:,.4.3)/ .•••. 2.0• .. •>··
mg/1 50.1 50.0 0.165 20
mg/1 0.537 0.540 0.498 20
........ •··? .. (ing/1 ... :.0.::-00 ....... o:;oo/f -.-. .. \o:oo to:2
2
0
0
. /
ing/t o.oo o.oo o.oo
\Ll99.177.f0l WG.202.14111
L199177-08 WG2021411
Ll99177-01 WG202141
/Ll99177·,oa.. WG20214r•
···•tt•~·~t;~:•g•~·· .. ~i.;.I.~.tiJI mg/1 0.00 o.oo o.oo 20
. ~~){i ···•·•·• l:bf iFfi. . f~; 20 ·;:r~I@~;:;} · WG202392
0\00./ ·--•••• ... (\0\00/• •·•••::; .. ••to•c"ooo: \\20/ • •••••••••}\Ll99303/04 ?IWG20260i
·····••·••••·······••·•·•··•···•• •+fu§~i .. ._.. ..... :~.;g::-:>• ..._ ...... t .. !g••:••o ·n•••···· i~•;·~<••••· ... ~g ................. ).ti~~i~.~.~g~ •·\~g~g~~~~··
:::::::µ~_l?C?.t~.~<Jt..Y';"·:9otjtto1 :::~art\Phf'-::="'' Units Known Val ··Re·sult Batch
Page 33 of 46
I
I ENVIRONMENTAL
SCIENCE CORP.
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
I Piedmont Geologic Mr. John Harper
Tax I.D. 62-0814289
Est. 1970
6003 Chapel Hill Road Suite 109 I Raleigh, NC 27607
Quality Assurance Report
Level II
L199177
May 24, 2005
Iron,Dissolved
IAnalyte
mg/1 1 1.06 106. 85-115 WG202251
'<:L:aoq:¢a;t:ODi/:ccfrifiOl '\·_$amp1e-:::?::
Units···· "kri.ow'Il ·val Resul't'.. % Rec
3.74
1,1,1,2-Tetrachloroethane mg/1 .02 0.0209 104. 61-134 WG203024
1,1-Dichloroethene mg/1 :62·· · ·· ··(i":·Cl:2°6·0· 130. 68-136 WG2D3024
1,1-Dichloropropene mg/1 .02 0.0236 118. 63-125 WG203024
If:~ ;t~!~I~~t~!~!I~~:~!? ..... ··•·• ,t ··•·••··•···•··• !i?t ·····•·· <If ..... ·~'l!~·!·•····•·•······· } t~t: .·•· \H~iii··· \.~gUtgnJ•··
Xi?./4\Ti'ime~liyit,eri·:i.,riii+>+t>I ··•••·4,.-. •·•···••·••.-y mg/r \/.fo:zt>••?•••·· ·.-_. ··•·· ·0\02.23: /: :ur••111•: ·····ro:6.1'•12.0 <twG203024/ y·
1,2-Dibromo-3-Chloropropane ing/1 .02 0.0207 103. 50-139 · ·· WG.iif3·02·4
111,2-Dichlorobenzene mg/1 .02 0.0209 104. 54-135 WG203024 11 ·1)2/Df¢hl¢roe.t:hisfrie_, }ft•> t•,Y• ?Y•AH?i •png/l•?H ·•·• < o 2;.-.••·· ·• ··•··· ······---o·io 212 ··•/' ·• •lo 6•-c····· ········ 51•,131.;. twG2 o 3 o 2.4
1, 2-Dichloropropane mg/1 : '62 ·ct: o'.ifit· 108. ·6·,f.:."i:2°6 wc;2·03·b'i4
l/_3 /,5-_'l'ri.rn~.~h:Y.P=>.t:!11~7~~ .,,:,,-•.~g/1 . 02 0. 0226 113. 65-126 WG203024 1 ·r:}=gl~~~~~~!!~~:~r 1 (/ MF .. ·r. ·;i?I i ig:fy ... i;g·!H{ \nrt '~!.~ti!< \;giglg~r·•·•·•···
•2/2.iDi.c.hlc,rc,pr_opa.ni! ........ · • ••• •· ::·••,Ah ··• •>•· iiig/1 002./i• ............. q •. \o:":_0.23.8)0 ......... ...-.-;+11~}}; .··+:5.2cl40{ ••tWG203024\i;•·
2-Chlorotoluene mg/1 .02 o. 0231 115. 61-134 ··wGio''.:f<fi°4··· I i~~~!~!i~~t~t\':r ···•· r Ei~1 /g! , ...... ···•···•.· <gigiI~·•·; 'l~~; •·>~.i~iiI >>ngigig~! ;r
Bromochloromethane mg/1 .02 0.0198 99.2 66-125 WG203024 I !~!;~t!l!!!:~met~aneft• ·.•;•.··•··+·i••·•··· .. ·•··r;!:t• .·••}•.•'.·•••t•.•:•g·!····· ·····•·•••i<••·r•.•··•··•<;g,··gI~·i/·\·•·· ············•·Irgi··1:j/ i!l~tii {,~glg·!:g·~:····•l·.·····
8~i~i6g!~;~~~hloride?· ··.·.·.··.·. r;~;r·· ··.·.·r'.gf<. >g>g~{fi > Ifft:·· ) ~~if!gL )\:is~~·g;:<
Chlorodibromomethane mg/1 .02 0.0205 103. 62-132 WG203024 0 §~fgig~~t!rie v ···.·w • } t~1f ·•·•···• r:g;· . <g<g~~r . . >Jgr: ........ {~iHr·• < :gig}gsf r
~t~;~;;;:gt~hloroetherie.< .-.nt •·<;~;}> ;g~. ·r •···•·g+g·~i~••······· · · ·--i~~> \:~:;g~ .•...... :g~g~.g~: .-. 6i-isoP:t:'6"PY1··e·t·her· .. mg/1 .02 (f.-o"ioo 100. 58-127 WG203024 ·D Dichlorodifluoromethane mg/1 .02 0.0198 98.8 24-155 WG203024 ~;-tr-;-~iQ~~gt:g:~1di'1!~1!H=L<t?}> . .-,4:, :t:\f?/<m§jI ::=:g.r)'"::,, ··--:;.:;:,:.:.._;.::;,:,:;;'_g.?-~-~}~> ..... · ·=····:=<:)?11r:-::}t·· ---:-::---~{=·Ii~?-? ):g§gig;1:,,,-·
Isop1"0[)ylb~11zene mg/1 . 02 o. 0234 117. 68-128 WG203024
I Me,thyl\ter.t/butyl\etheic ••i<•f<,·•••+tm•·· ···••ttirig/l :Co2f/ ..................... 0,0199} •ft•\H,/99\3{ ft•51\i3)••-;-·•)W()203.0i4{•••··
Methylene chloride mg/1 .02 0:0199 99.5 53-131 WG203024
n-Butylbenzene . . .mg/1. . 02 O. 0241 121. 59-134 WG203024
n/Piopyl.berizerie(/.i • ..... • •••••. <+••Limt-...... mg/1-< 02•• ..... ··•· ·••+0.:0231\i ••• ···•t/115·' <t•··z68/12.3/ i\WG203024••········ Naphthalene mg/1 ... ······.·o:z . o··:0215 107. 54-150 WG2b)o:i4 I ~~.~+~~t~l'.si;%ilt~B:·•······· .. <••··•••i(··)+••:•·t· •. •···•••11·•;\ ··••t•······;~ji •···t••·•LS•·•:·g~. <•.•· Li)(\g;.g;t~\) i••••>·.••·•·•ii:; \~.t:}~ir ·••\:g~g~gI!·••··••··• Styrene mg/1 .02 0.0220 110. 68-123 WG203024
tert-Butylbenzene mg/1 .02 0.0235 118. 68-128 WG203024
Tet.rachlorciethene ·•· ·· •L•t• .tmg/1\ _._:02 -... ·t• ·•·• i/.oJo.2_3.s:r •r••••o.--.11.~;: ?• .fr!•6.3CJ"J4\• ••wG203024;7..-·· I T6t\.i'ene----·-,. --·· mg/1 .02 0.0208 104. 65-120 ··wctt"o"'.:fdi,{.
Page, 34 of 46
I
ENVIRONMENTAL
SCIENCE CORP.
Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
trans-1,2-Dichloroethene
Analyte
Quality Assurance Report
Level II
Ll99177
mg/1 .02 0.0234
':/:.1=i:~l?¢ft;¥~.s>J}i\.COrit'iOl 1·19.¥11lPl_e/t:
Units Known Va1·· Result
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 24, 2005
117. 59-138 WG203024
% Rec Limit Batch
Vinyl chloride mg/1 .02 0.0189 94.4 46-133 WG203024
J(yl.<eiles//T.o.ta.p/ ••' ·r•.•·r .:•{/.\ ::t:J• ,:}ng/1 {i::f .:.0.6.. : /JO\Q§65\ :: . > •111,··•• · · ·::\68°124· /wg203.02.• ·
I
I
I
I
I
I
t:f:~~ifU~[~~~iI~!~lt![]· • )\2!~t<· >1zi> rg!gti!··•·· •<rli:~>· rittii···· •·\~g~gigi!•·I
1,1,2-Trichloroethane mg/1 .02 0.0185 92.4 62-124 WG203096
t:};~J~~tgh~~I6ll:Riene ,·.• ··· ··· ···· ···.··.·.·· .. ffi§{i :g~ ·•···•···•·•·•· ,g;g~!}, ··· ,1~!: I,~~+i~~r • r:g~g~g~.~ +II
1, i, 3·~Trichloropropan·e mg/1 . 02 0: o"2i"4 fQ·i. 62-138 ····wct2o"3_o_ii6
1,2,4-Trichlorobenzene mg/1 .02 0.0248 124. 49-153 WG203D96
1,2-Dichlorobenzene mg/1 .02 0.0217 109. 54-135 WG203096
LI2'cDichlof6ethiiri<it"··• ···••·••· •••••••••••·••••••••• ..... , ••••• , •} ·+ {rng/1): ..... •r.02.:n ... ••:••·· :o/0209 ........ , •• \10~< \61/131! (fl-lG203.09.6))
·1,2-Dichloropi-oPane mg/1 .02 0.0184 92.0 64-126 WG203096
1,3,5-Trimethylbenzene mg/1 .02 0.0197 98.5 65-126 WG203096 11
r; 3/ nichloroberizerie?•• •·••· ••·•••· ••••••• •••••• ••••••••· •···· :·•t• \rng/l t•••> \0.2:t• ••. • ·I •t••\o :0.2.i:s · ti:,? .::..10.a,;J •. : .. :.: .. J~.5/.143 .• :)•)iG203 o:9.6 \ Ulli i,3-D'ichl6i-oPToPal1e. ..TT\g/1 .02 0.0195 97.3 74-118 WG203096
t+:~:-~-gt-¢hi:6~_6i;i~i-@:::Jv :c:?:=/:>:t:::::::,:e:/:r:::-:?:r.s\<>}It:caj§-:1::t :"Jt:::-::5:g_~r> ':i::-:>,l:': >:i//_g (g. ~-t-;:, · ·· ... "?ti:~,:!)a> ?< ':'";:~ ,~ i_}~,, r:::.:.~~~ ~}g:;-~: I
2-Chlorotoluene mg/1 . 02 o. 0201 101. 61-134 WG203096
4-Chlorotoluene mg/1 . 02 o. 0208 104. 67-129 WG203096 -:~g~~~~:g:;:!1i{~t:::.:::::::: ,ths1r:tr(>t§·; r r =' :::-:r::=1:::g ~.:::>:,::;::-:,· · ·· ---_,.,-,.,:::-=-::::g:':::.~ ~=ii·:.·::,::·= \{_:::>:::;: 5-r~·§ (:=,.-,::-,-= -~ ii· ~1 ~x:·: :.?= :g.;-~ lg .~-fr··· ·
:i6;6-dr·§hr-6i·6~~-th·:ne,· · --:::;§~}::t 0··--· .·-·:<-:g;,:,,,=···· · :?:::::\g.:~{i-~~ =<r -·=··tl:~~'+7· ., .. ,,.,.,:/~.:-ii}~. ·:-::\::,::g3.g5-g~~?:=:·,, --1
Bromoform .... . . mg/1 :02 . o. 0187 93. 4 6CJ'i39 . wc;2o3o96
Bromomethane mg/1 .02 0.0135 67.4 30-125 WG203096 carho"ir-_::.Te c: ra:ch1·or icte>:r,::-::::-:······ :'t}:\ajg;..1:v .. , .... ,., ... ·=·=,:,:,:o 2·,, ··::,:,:,:•:,,.::·:,:,:,:.-,:::-::ttt:.o. \.9 ~.to· :-:::::::.:·=·f'':t\tt.~.5 :r:=?? ,,,,.,-=,,-=,:: 5 0 :::::-i>i o ,, ?:::c.wq2 q,-to.~:6JJ -:.::-,-.
g~Iiiiiii[iii~;t~~ne········· ··················.·.·.·.·.·.··.·.·.·.··.·.·· .. ·.·.·.·.·.· .•.•. · .•...•. /E!it ...... •·•·•···•···•·• ;g!······· •·•••··••·····g:;gli:g .. :•t···• t•ti•~.i!.;.g <t••••t·~Iit~i ...... / .. ij!!gig:iix •.•
Chlor·omethane ·mg/1 ·· .02 0.0192 96.0 45-131 WG203096
cis-1,2-Dichloroethene mg/1 .02 0.0191 95.6 68-123 WG203096 ~I8~t~t~~f¥i~~;~ttrn:~z········ .............. )~§;r/•·• ng~ t <fgf;f> <rI~'7 I~!iN•~·· r:gig~g~fi <I
~lRr~~iat86Utadierie\••· ···••·•••···· ••••••••••••••••••••• //fu§Ji:. ::::.•: >fgI:.•• ····•·•· .•... <g>gg~ •:. ·•>?(•:;t;J ::: /.~.g~:t.it .:g~.g.~g~~/ Isopropyibenzene mg/1 . 02 o. 0201 100. 68-128 ... wG2o'.lo96.
Methyl tert-butyl ether mg/1 .02 0.0205 102. 51-137 WG203096 I
Me·. ·.th.·. y·.1.··e .. ne.·.-,.::.:c·. · .h.1 .. -cir. •·.i. d. ·"· ·.·.•.::.,:. -·-·-·.·-• .. •.•-·-·.· · ----·,.·.·,.-.--· ......... -.-.. -.-.•_-.... -.-..... ·········· · · ·11·· .,. __ ....... ··-·-·.· ._.,.,.o 2··---·-· ....... · ·· ......... -······o · · o 19·6 ·• 9 8' =.:':1: ,_" ···· :. 5.3·:;.··· 1·3·1= -· ····-· · wG2 o 3·0 9 6 •. ·--· ri'Butylbenzemi'. . .. ·••••• ............. ············•·::·:·••·:t••:•m§ll.,... ..•... •:C/02· .... .. ..• 0 "o2o'3 .............. Toi·:·· .... · .. · ... 59''.·i:3:j' ··••wc;26:io<:it· t
n-Propylbenzene mg/1 .02 0.0193 96.7 68-123 WG203096
Naphthal/iiie ( •····. : ( (ti,g/1 /02) . .( 0/02.23• \ {1J1// •·••540150.. WG203096 ?/····· p-Isopropyltoluene mg/1 .02 0.0202 101. 64-132 WG203096
sec-Butylbenzene mg/1 .02 0.0194 97.1 67-124 WG203096 f·~tt~~uttf;;~~I~~t· ·.·· . /.fu§/i ·r. >gs r<g:grbr"' •· If~fU. {t~nrr ·:gjg}g~t··.
Tetrachloroethene . mg/1 . 02 O. 0201 101. 63-134 WG203096 I
T6.1uerie Di L . ?)t"'· ·•···•·•mg/1 ··.·.· /,02 ·/\ •t otol.8.4\ ···•·· ..•.•. · .•. · .•••••• 92fo \6.5.Cl20i/ •·••1-1G.203b96'; ••
trans-1,2-Dichloroethene mg/1 .02 0.0200 100. 59-138 WG203096
Trichloroethene mg/1 .02 0.0190 94.9 74-120 WG203096
0I~t~l~h~8~Y~f'iriietharie /%§Ji ? ,g~ .· .. · .. · g:gi:r :~<f :~::gr :g;g~g~f \I
Page 35 of 46
I
I
I ENVIRONMENTAL
SCIENCE CORP.
I Piedmont Geologic Mr. John Harper
6003 Chapel Hill Road Suite 109 I Raleigh, NC 27607
Xylenes, Total
IAnalyte
I
I
Quality Assurance Report
Level II
Ll99177
mg/1 .06 0.0596
/:::'I/a;:t~ot~J:¢::CyJ.G~i'.tt.:t·.¢J: (~~rtiP1¢\)< Units Known Val Result
Page 36 of 46
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 24, 2005
99.3 71-116 WG203096
% Rec Limit Batch
ENVIRONMENTAL
SCIENCE CORP.
Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Arsenic
Quality Assurance Report
Level II
Ll99177
\(r;?J::?qj~ t:;¢>ry.::, .. G9i:i t rq_;t:'' _s;iimp1~: :ptjp~i:i~:ate?::-,
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-B00-767-5859
Fax [phone]
Tax I.D. 62-08142B9
Est. 1970
May 24, 2005
Units LCSD Res Ref Res RPO Limit %Rec Batch
800. 14.0 15 92.0 WG202243
O)iii ••):(C{(9./15i )\15) s.o)o ??i\l:IG2.02243}
mg/1 1.00 0.990 1.01 20 100. WG202250
t}i .}/.•• \.)/lilg/1} •·•tY0.6), •••c.1: 0..3·•• : ( ).2 cB . .7 }i •20>• :C" 106,:C/ \WG202250i ...
mg/1 1. 09 1. 06 2. 79 · 26 109. wd2oii5o
I
I
I
I
B"aiiiiffi
Cadmium
Chromium Le~ctt·
Manganese
Selenium
mg/1 1. 03 1. 01 1. 96 20 103. WG202250 I
................ · ...•• • Crng/1· << ·F•Q2 ••• ... ::1;,00:))" :'\l"'.'9.B. \)•20/ :·}(1.0.2/) '•)tWG202250/C •• : 't? ·rn
.mg/1 0.990 0.980 1.02 20 99.0 WG202250
S. ~Jy'¢.i\\(/C
Iron,Dissolved :~hTJ1?idl . <·:
: .. : .: ·<.•:.::·:,. :t rr:•. ,<%~~.i .::: .... ,.~::~~o r.,.,: ... t:,~}o. r :::.:~ :~.~ t,.;.g /Hi~~Jor ::~;g;;~g.,. ·
1.06
17.7
0.00
0.229
20
20
106.
88.3
WG202251
WG202392
i:l:r~~It~rti~!~~~~;hane• ·.·.··.•.·.·.··.·.··., wmg1r \g<g~·~1•·· \ g<gi~r }iff >N .· if~ir:.·. ):g}gig~f? }I
1,1,2,2-Tetrachloroethane mg/1 0.0196 0.0219 11.0 16 97.9 WG203024 f [gHH~i~:[~:~tne/ . \C?I~;;r) )tHi:•··· {~)Hii··• l]i:i(~~ <I~f . I~g~H~!! .. II
1)J.\picll.lCJropr6!)erif <;? ·· · ····· •(.mg/1\· '> oco23s:· · •0,:0235•:· ··o ··499 • 17·•·· · nae;/ ••·wG203024••· ·
1, 2, 3 -Trichlorobenzene · · fllg/1.. ·· ·· ·cL--□2::i?··· ··a .'02·:fi · ·:.::.: .. ~/'.':.6'5 .... ·1·9 i'i'4 '.' ··,·.-wd2oj·o"i4'
1, 2, 3 ~Trichl_orc,Prt?pa_!1E! ... _mg/1 0. 0195 0. 0202 3. 60 18 97. 3 WG203024 1.=·=-2,===:4-·f.Tricti-lOi"oberiz·en"e· :::=,=::,=mg/:l \{\0f.025_0/:":= \W\.02i-1"2 })/3:}-l-?) //2.0 1-2_5\\ :)/?{1?J.G2q3·02":4-::,.:., i·: 2 :--,i~-Triffie·thylb·enzel1e· ....... _ mg/ 1 a. 0218 o. 0223 2. 12 18 109. WG203024
1,2-Dibromo-3-Chloropropane mg/1 0.0190 0.0207 8.54 19 94.9 WG203024 12•oii:hlorciberizerie •••• ·· ·· • •·•·· mg/r ··0·····0206•·• ··•0"··0209· •>.••1.·.•.•,.5.3.· 1•6 .... •·•·1•03<. ··••·.WG20·3·02·4·: ··.··.·••"·"• .. • i}:/·o"i°"ChiO:ro",ithane···-> ·· · --,::::-:::-m9)i' "=,-=::,-.:::\f:'o"f~fs( ·:.:·\:,-'·~·-o:ii'"::/ ····· 6 .. _ .. :f'i ·· · i-s· -~l9 _-;f · wCf20·3·024 ,',:::::,,:,:,= ... =::.:::.:.:.:
t,~:~~iNZcitRiW!Riehe ...... ·.· ...... · .... · m~?t r ,g;g;~6 ···t·g .. ;.g~~.~ }~(66{:: itr \i~Z.; ••t••~g~g{g;:, iii
1'.3:Dichi6robenz.ene mg/1 ··o.·0219 0.0227 ··· 3·_·97"· o 109. WG203024
1,3-Dichloropropane mg/1 0.0211 0.0204 3.16 15 105. WG203024 I:sc:§f~~rnt~gt;;i:~: <••··• · >m~:f1 tg:§fI~·· >g,gI~~ .. : •. <l'sTgJ ir•···· ·I~;< > :gigig~:•··•
2-Chlorotoluene mg/1 0.0223 0.0231 3.19 26 112. WG203024
:4/Chlorotc:,rueneJ••··· · •. ···.· 1T1g/.1: ·•.::q :0225· -:o:.02JQ} ·•·•2/oa,: •·17• •: 1.P\/ \i/WG203024·;•:••••···
Benzene mg/1 o. 0215 · o. 0222 · 3. 22 16 108. WG203024
Bromobenzene mg/1 o. 0213 o. 021 7 1. 92 16 106. WG203024 :~~::~-~8~tt~:~~~t~~·g=;t:>' ·· · · .. -.·.··-:-..-:-::-<;g?f1' >}<g.:=:=:gi~~ :>tt~?-gf~--~ :-tt::-i'.:(}§t <>t} \==-~i==:=t= ,,,J:/:=::g§g.}~~f
Bromoform mg/1 0.0198 0.0208 5.24 15 98.9 WG203024
Brornomet.hane/ (: .( :t• c.·• . •·• :c:,: : ... '\: /) lllg/T /\)Q/0180 \0/0181 }:O'i33.B••• ·21,:··· 90•2. ••·•wG203024••···
Carbon Tetrachloride mg/1 0.0239 0.0243 1.57 17 120. WG203024
Chlorobenzene mg/1 O. 0223 O. 0221 O. 779 16 111. WG203024
Chl"OiOdihiOTT\Orrietfriirie\/"' -·······,:.::··.:==rng/l\{: ·-:·=r:o::?0208'·: {:\()\'._02o_s,/=: ')-F)62\ ({{?/:}? -:=\:tJ>.•:l)?)'j/ WG203024\:'):;:e,: ·cti.ioroe"thane·· ......... ···· m9;1 · o·.'ti2iD·.·.-. -□-.02i3 ·· 1·:-4Et· 24 10s. ···-t·ici2·0:rci:z"4.
Chloroform mg/1 0.0209 0.0207 0.886 15 104. WG203024 I
Page 37 of 46
I
I
I ENVIRONMENTAL
SCIENCE CORP.
I Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109 I Raleigh, NC 27607
Quality Assurance Report
Level II
Ll99177
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 24, 2005
....................•. ,. ,., .. ·•>:crrig/f\ ••??•0(0213 ·•·/o'/0225 • ••<s·•·51/: ·• 22 .. C106 :'/ ·\WG203024/
·::\1.;abqr·a tO'iY/:"_COri(f.O 1 :·:· s~:mpJ¢ ::·oupTiCa t Et\:·
Units LCSD Res Ref Res .... ·1fpb"··-.. -_L.imit %Rec Batch
mg/1 0.0192 0.0198 3.03 17 96.0 WG203096
lb }%§)1 tg<gf~:\ ffg:<gt~i/ •~>~; <r;· /~J>~·· uTTg;g·~g~it
mg/1 0.0172 0.0185 7.41 16 85.8 WG203096
·.·.·.• ? %§;r <g;g~ii W:§;i: cr:9~· r 19•: J iJ? ?<TTg~gig~.~ , ..... .
mg/1 0.0182 0.0190 4.28 17 91.2 WG203096
) %§1/fW } g<gf ;~/ \ g:·g~f! ff:~; / r:···· {~I 3r >TTg;gfg:~r••·•······
., mg/1 0.0230 0.0248 7.57 20 115. WG203096
••••· .mg/1 :\(0/010,i: .. •ro;,0192 •·"A :12 •Jy10: )J.:~t:0.u ••iiWG203095\•••··· mg/1 o.0147 0.0152 9.50 19 73.4 .···· ··wc;ib:ib95···
mg/1 0.0202 0.0217 7.11 16 101. WG203096
•••·•··•?·fmg/1':/·• :oro2·04•• . .,\0\020.9•• . .,/2730•·• ·;-;::-
1
15
8
. y· \Ito2\( :,wG203095/
mg/1 ().0181 0.0184 1.90 90.3 WG20.3096.
mg/1 0.0188 0.0197 4.51 17 94.2 WG203096 ... %§gr j g>gfg~ a g<gfit l:[5 > 1I < }~·?b" TTg~gig~~ ..
mg/1 0.0206 0.0217 4.82 17 103. WG203096
•··•••••••mg/1/' !Yo/0211 •··•:o/o.229f •\•,;;35/• • 21\• ·••1'00,t: ._..iwq203095••·•• ·
.mg/1 . 0.0191 0.0201 5.27 26 95.4 WG203096
mg/1 0.0197 0.0208 5.77 17 98.3 WG203096
. ?•• • ••••• ···••·t(1119/l',.,,. •O<OL?..8\ ::to:,o:r,07/ f/4/9.3 \}•1'~ )/:.0.9.•:1'(\• /.WG203096, ............. .
mg/1 O. 0201 O. 0208 3. 52 16 100. WG2bjb95·
mg/1 0.0205 0.0213 3.58 17 103. WG203096
mg/It ?f or•on6•••· 0\0103 \4 :n······•·· · 11 \ a.1/9t · wG203096/.
mg/1 0.0102 0.0101 ·2.34. 1s· 91,2 ·wG203095.
mg/1 0.0141 0.0135 4.35 21 70.4 WG203096
t·.:.mg/1{\ {0'.,0200/ •t•o:-co210· )\40'~8·· i?l?i •?·t•tOO/{ ·•>-':•.WG203.0Q6\t· ........... .
mg/1. 0.0195 ""o.6266 5.49 16 97.6 WG203096
mg/1 0.0181 0.0190 4.96 15 90.4 WG203096 ········t~;r+ :g:gfgf /g gt~•r ... (~;J~•g 2 ;f·· )\~•~3x /TTg~gig:~<)
mg/1 0.0190 0.0191 0.763 15 94.9 WG203096
i%§Ji1 tA~tgJ~I' <g :g}~} 'I :f~• \ }~7 \fi~I~+ ·tTTg~.g~g~f .......
Page 38 of 46
I
ENVIRONMENTAL
SCIENCE CORP.
Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Eth !benzene
Analyte
Hex·achtorobuta·ctiene· r"s·oi:>ropy1be"r1zene· .....
Methyl ____ te_i,-;~-:-_buty_l -~_the_r f:-'l_~thyJeri:~_::-:Shl()):J_d_f::_ · ..... .
n-Butylbenzene
n-:: Propyl_b~n-~1:=.n~_ Na.Pht_lla_l_ffrl~\\{:}/t:HL:i:: p-Isopropyltoluene
sec-Butylbenzene
s_ ¢.Y_t:¢ii~ /?/:\tJ::://\_:::/t' .
tert-Butylbenzene Tetrachloroethene ,ro.~:u:e:ne·tiH=tit:::::::<tJ::::::::::::r:::,::'Ht\:':'::::,:r::::w:::,': trans-1,2-Dichloroethene
Trichloroethene
:TiiCh10i'Of-lllciiOmethane .. :?>" v1ny1•··c111or1ae· ·
_J(y_le:me!3 ,_ Total
Quality Assurance Report
Level II
Ll99177
m /1 0.0184 0.0193
0.0028
4.34
3.45
17
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62 0814289
Est. 1970
May 24, 2005
92.2 WG203096
Batch
:1\tl:'i=A/.?\.T.${i:Ei.¢tP.:¢t.9¢.~l:i:S:fi¢i/t :=-=>::c::::mg/1:::,:· ·:-:,:/0\0_1;_9_1 '\to_/{) r.~1.-:-:-..:::= ·''·3:-':':s.7:Jt: '''·l7F .. -.,,.,/9.?_:'-/f:i_\>=· ·:==·.wG2 03 2 3 s<='==,=,--·.·.··
1,1,1-Trichloroethane ···mg/1.. 0.0206 ·. ()."oi94. 6.···oi ... i'7. 103. WG:ib3235
t+1+It¾iT¢.~{tj:~g~~h~.hln:i:ne .:·-:;:;.,::::::::,:=·\f):=):]{/J\/=·::fug-J,.i;t '=')ii,{}g,t;_i./ tt~:+i:t:;_;b )};).~_;:di\;. i{:· -~_;_::,}\: <-:x::g~g~}~~
1,1-Dichloroethane mg/1 0.0211 0.0198 6.31 22 105. WG203235
1,1-Dichloroethene mg/1 0.0249 0.0238 4.55 17 125. WG203235
:t,')Tf p i_¢_h 1oropr9p·Efri¢:)(,t}>: = · · · ·mg/1\i << o :_:.9. 2 o ~ t ··,:,:·==o .=;· o 19 4··· · ·.=,::::=-4·= /6 s:··· ., • , 1-:7: · :·=-=-::::-::: 1 o-L/\/ =:.:wG2 o 3 2 3 5 ·-, ,.·. · 1, ·2·;·3 :.:Tii"Chloiob·enzE!rie . ffig/1 o. 0189 ·ct·oi 75i .. ···5·:·2a· 19 ... g·_if·_--5··. ··wcfa·o3·2°3S
I
I
I
I
t,~:{::g:t6~tg~gg~ri~:rii r ( .( < ;§;t x tg;.gf~.~ ••. 1 g+gt:~·•• xii~.~} . s~•cr }~fi• r~~IgI~~~.. < .11
·1:2:·4·...:·Trii-nethY1b·enzene· mg/1 0.0197 0.0190 3.61 18 98.5 WG203235 fl
1,2:Dibromo:3-Chloror,ro,>ane mg/1 0.0179 0.0162 9.85 19 89.5 WG203235 r:--i~--g.fg~t-~t-6-~·th:;~~-1:::-:·.=:"···· · ····· :;.·m§J'i::: >.>r:g.:::,:gf:-:6· /t ~-?gr~-~-,, .t+i:~i~ ,..1; ::·:-::,.,::::-:::~ .. g.·:tl7,.,. /:=::g~.g~~}r:·;;:
l,_2-Dichloropropane mg/1 0.0184 0.0178 3.29 18 91.9 WG203235
1/3/5°Ti:iiiiet'hylheirizeriet fiiig/If ?•0•0202··· t/0:0195 3}11 (17 /101\ .tl'.IG<.03.<.3.5
1,3-Dichlorobenzene mg/1 0.0198 0.0195 1.31 17 99.0 WG203235
1,3-Dichloropropane mg/1 0.0196 0.0187 5.04 15 98.l WG203235 rt:§t~~rntg~;6;:~:<· ··· .r~§~t \./g?g}g~· ig;gf~.g >~'f~c·· ;i ····•·•··•··i~I~· ?:g~g}IIr/ ··.·.··.··.· /I
li~~i~~1;t1;itiiri:/ \ ;1;~ r g+gliir g+g~ii ri+ir fi< ? Ul+ <~g~zii!ir/
Bromobenzene mg/1 0.0202 0.0198 2.21 16 101. WG203235 :1~:~g~8~r~:t;~~ig;-~:i--:::_ e>,<,>:<:::::+:<::.::,:;::;t:r=>&:::::-:::\rr:::::m~J-r :/)r·:g.::::gi~-~ ::::::e::-,g?:g:t~~ :=:,rr·r:·-~wrf .. ,·r; ·-1i~}-·").:g§g~1~~}( ...
Bromoform mg/1 0.0192 0.0185 4.05 15 96.1 WG203235 g!r~~~:!i!~!~hi~;Ill: ....................... •.·•·•····•·••·•· / ;i:r r·~·nr (~}nn···• tfi\!!)/ ··•tr )!If 2 n~g~g·1·~1;+ + I
@ig;g~~~tri:c:,me(h"rie /. ,; (~§ji\ >g<gf~{ tgtg}~·~ i{i53 <<•.}~·•••· ••••··••·•·~!'.i j~g~g~1~r
Chloroform mg/1 0.0200 0.0186 7.66 15 100. WG203235 I
Ch1oroiiietharie• •·•••/·••· •••· ·••···•• ••iiig/r ·••·•••••·••9/020.7••• ••Q}020T \•••·2.?96( •\22 •\\1·04/( //:W.G203235.t•••••••••• ••\\ •
cis-1,2-Dichloroethene mg/1 0.0205 0.0198 3.82 15 ·· ... ib3.·. WG203235
Di-isopropyl ether mg/1 0.0173 0.0164 5.26 18 86.4 WG203235
Di"ChlOiOdif.ltiOiOme·tharie ,:::.==·:ing/.-·F /}}}0_):{)_3.Q_-?.: :j).:.(}_,'(Q}:9._3. =::}}/(});_Ei.:3_,4} :.:::-22 ?t/=.::-.~s.:2_/\ /)t.¼'.C3:~ . .9:~.?~.?:>: Ei:tl:y"1b·enz·ene ............ · ··· .. ==·=·=·,mg;{ o. 0202 o. 0195 3. 02 'Pi 101. wG203235 I
Page 39 of 46
I
I
I ENVIRONMENTAL
SCIENCE CORP ..
I Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109 I Raleigh, NC 27607
Hexachlorobutadiene
Analyte
I -i/,}ri{¾iI~;r~-~g_l~~~-~:~-r:0=+:~\:::,::::-.'",·C-"-"<""" i"; i :··2 :'2-·Tetr·,::i°ch16r·o"eth~n~ ·
1,1,2-Trichloroethane iJ' /1} p:i¢hlOfO:ethit"rfe:)t?}(?"'" ...
Quality Assurance Report
Level II
Ll99177
mg/1 0.0182 0.0180 1.41 18
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 24, 2005
91. 2 WG203235
)/~$_pg_r_aJ<?!Y:{.<::_¢_tj.tfqr?sa\np~-e \p~p_1:ic~1=:¢/·::-·
Units LCSD Res Ref Res RPO Limit %Rec Batch
!.\)Ma_t_:t:_fi_t:sPJk~)\
Units ,MS Res Ref Res TV % Rec Limit Ref Samp Batch
\ lllg/L) 101' /!5.0 ;o { \50. .> .. 1.0.3\ /8..00~20) Ll99177C08. WG20214l
mg/1 5.16 o.oo 5 103. 80-120 Li9<JlffC69 WG2b2i4i
mg/1 53.6 0.00 50 107. 80-120 L199177-08 WG202141
. ~~)i? 1. 02 8/EB ( 1 102. I ~~:{Ig £{991\?~0s mm&JJQJ
mg/1 1.39 0.380 1 101. 75-125 L199177-08 WG202250 . t~~n•· < fg~ ·< g:gg 65··i < }gr. ;g:H~··• ti:RN:g: ~g~g~~;g
mg/1 0.984 0.00 1 98.4 75-125 L199177-08 WG202250
?mg/1 (13)8 ( 13,0( /1 t.83\3. 75/125• It19•9.i77/08 w.0.202.2.s.o• mg/1 .... 1:·00 0.00 . ·1· 100. ')5·:125 L199177-08 WG202250
mg/1 0.983 0.00 1 98.3 75-125 L199177-08 WG202250
mg/1 0.0196 0.00 .02 98.1 57-133 L199325-01 WG203024 · ·;1 ·. ,·o 022·6 ·······o····oo ·.••·.••· .. ·• .. r . .-: .. 02 ··1·1·3······ ·54 143····· L1993·25·····01· wG20302·4·
%~/1 ii•o:0217 { o: 00 .•.•. : o2 • io<J': >sa:i"J;f Li.99325~01 WG20So24
mg/1 0.0192 0.00 .02 96.2 58-125 L199325-01 WG203024 . ........ %~Ji> :g<gn~• >f: gg :< :g~•· > f ~l' >~f±tJti• •tt~i~·;~tgt ••·Tiglg~g.~f • •t:i ;~1~~H~~~~iiii~ener·· r:·2 :·i:~>rr·rcht6r6'pr"opane···
mg/1 0.0215 0.00 .02 108. 58-126 L199325-01 WG203024
................ ' mg/I )0i0193 \ .. o.·.o .. o .. '.02 ( • 96,.6 48.C.1.27\ L.19.9.3.2S\Ol WG203024
mg/1 •··· 'o .0221· 0. 00 ... ·:·o;f 110. 57-145 L199325-01 ·wG203024
I 1,2,4-Trichlorobenzene :rr 2 ~'>rtTr: t ITT:e .t ri y 1_1:1e nz\~ ne tt::-t:::::>:<::::=.,::::·. -1,2-Dibromo-3-Chloropropane
1,2-Dichlorobenzene
-1>>2 :~-oi·ch1oro"ethani:f, -:t':·· I 1: 2~ri{clil6rOproparie
I
\ %~ji•r·· .,g;gI~.H {Jg .. > :g; .. }~:i ~t};~r tgIU~igi ~g;g~g~!
mg/1 0.0223 o.oo .02 112. ·440130· Ll99325-01 wc;2030·24
mg/1 ·o.0179 0.00 .02 89.3 50-127 L199325-01 WG203024
111g/l r ·o .. 022si r o./o.o \02.. / )13, .54,14.5.\ L.1.99.3.2.5S01 wG203024
mg/1 . ··o:02f9·· o.oo .02 110. 55-135 L199325-01 wG203624
Page 40 of 46
ENVIRONMENTAL
SCIENCE CORP.
Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Quality Assurance Report
Level II
L199177
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 24, 2005
1,3,5-Trirnethylbenzene rng/1 0.0198 0.00 .02 98.8 54-125 L199325-0l WG203024
Page 41 of 46
I
I
I
I
I
I ENVIRONMENTAL
SCIENCE CORP.
I Piedmont Geologic Mr. John Harper
6003 Chapel Hill Road Suite 109· I Raleigh, NC 27607
1,3-Dichlorobenzene
IAnalyte
I
I
Quality Assurance Report
Level II
L199177
mg/1 44.9 0.00 .02
Units "..:.icJ1.a_tifJ.~L~Pti<¢·-::::::: MS Res Ref Res TV
Page 42 of 46
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 24, 2005
112. 47-128 L199177-08 WG203235
% Rec Limit Ref Samp Batch
ENVIRONMENTAL
SCIENCE CORP.
Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Quality Assurance Report
Level II
L199177
Page 43 of 46
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 24, 2005
I
I
I
I
I
I
I ENVIRONMENTAL
SCIENCE CORP.
I Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109 I Raleigh, NC 27607
Trichlorofluoromethane
I
Quality Assurance Report
Level II
L199177
mg/1 0.0194 0.0169 13.8
i,>M.ii.tt.:~><::·.~Pik¢./:DiiPkt¢.¢1te/· Units MSD Res Ref Res RPD
Page 44 of 46
21
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 24, 2005
97.0 L199325-01 WG203024
Limit %Rec Ref Samp Batch
ENVIRONMENTAL
SCIENCE CORP.
Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109
Raleigh, NC 27607
Quality Assurance Report
Level II
Ll99177
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
May 24, 2005
I
I
I
I
Vin l chloride m /1 35.4 38.1 7. 39 24 88.4 Ll99177-08 WG203235
Analyte
:'· :>:·: M_a t_r:tX :. -.~Pt ~¢'-/pi/PI:~t:_a_t ¢:\.-
unit S MSD Res Ref Res RPD Limit %Rec Ref Samp Batch
Batch number /Run number I Sample number cross reference
WG202243, R233305, Ll99177-0l 02 03 04 05 06 07 08
WG202141, R233433, Ll99177-01 02 03 04 05 06 07 08 WG2022SO, R233465, Ll99177-01 02 03 04 05 06 07 08 WG202251, R233467, L199177-01 02 03 04 OS 06 07 08
WG202392, R233586, L199177-04
WG202663, R233800, Ll99177-01 02 03 04 05 06 07 08 WG202605, R233804, Ll99177-01 02 03 04 05 06 07 08 WG202783, R233937, Ll99177-01 02 03 04 06 07 08
WG203024, R234073, Ll99177-09 10
WG203096, R234093, Ll99177-01 02 03 04 05 06
WG203208, R234103, Ll99177-05
WG203235, R234184, Ll99177-01 02 03 04 05 06 07 08
* denotes out of limit range result. See Attachment B of standard report for list of qualifiers.
**Calculations are performed prior to rounding of reported values
Page 45 of 46
I
I
I
I
I
I
I
I
I
I
I
I
I
.,,..1 ' .-.\..,1
•·
I
ENVIRONMENTAL
SCIENCE CORP.
Piedmont Geologic
Mr. John Harper
6003 Chapel Hill Road Suite 109
12065 Lebanon Rd. )
Mt. Juliet, TN 37122 (·, [phone]
1-800-767-5859
Fax [phone] ~
Tax I.D. 62-0814289 (
Est. 1970 I
I Raleigh, NC 27607
Quality Assurance Report
Level II
Ll99177
May 24, 2005
I
I
I
I
I
I
I
11
ll
I
I
I
I
I
II
ESC Level 2 Data Package
The data package includes a summary of the analytic results of the quality
control samples required by the SW-846 or CWA methods. The quality control
samples include a method blank, a laboratory control sample, and the matrix
spike/matrix spike duplicate analysis. If a target parameter is outside
the method limits, every sample that is effected is flagged with the
appropriate qualifier in Appendix B of the analytic report.
Method Blank -an aliquqt of reagent water carried through the
entire analytic process. The method blank results indicate if
any possible contamination exposure during the sample handling,
digestion or extraction process, and analysis. Concentrations of
target analytes above the reporting limit in the method blank are
qualified with the 11 B" qualifier.
Laboratory Control Sample -is a sample of known concentration
that is carried through the digestion/extraction and analysis
process. The percent reCovery, expressed as a percentage of the
theoretical concentration, has statistical control limits
indicating that the analytic process is "in control". If a
target analyte is outside the control limits for the laboratory
control sample or any other control sample, the parameter is
flagged with a "J4° qualifier for all effected samples.
Matrix Spike and Matrix Spike Duplicate -is two aliquots of an
environmental sample that is spiked with known concentrations of
target analytes. The percent recovery of the target analytes
also has statistical control limits. If any recoveries that are
outside the method control limits, the sample that was selected
for matrix spike/matrix spike duplicate analysis is flagged with
either a "JS" or a 11 J6". The relative percent difference (%RPD)
between the matrix spike·and the matrix spike duplicate
recoveries is all calculated. If the RPD is above the method
limit, the effected samples are flagged with a "J3" qualifier.
Page 46 of 46
' ' '
,
s;ompany Name/Address: Alternate billing information:
.· c-,1:'0TI'OII\ GrectoiL
\oCo'::, ~ \\,\\ ic. ~¼. \6\
Q-.c.\6~"' l\)c. a-11001
Phone: C\ \C\ 'l,S'I C\,oc
FAX:
Collected by: ~& ,,. 'oS
Collected by (signature):
~~aJ5uf,~ r;~ 0.7
Packed on Ice N Y
Sample ID
Client Project#: E.sc Key:
. 8."S \"\ F, C -·l\)C. $\0<\e. \lf\, II
Site/Facility ID#: P.O.#:
!Rush?! ( Lab MUST Be Notified )
__ Same Day ....... 200%
__ Next Day ........ 100%
__ Two Day..... .50%
Comp/Grab Matrix* Depth
Dat~ Results Needed:
. (l(\o,C,.ft\
Email? _No.i._Yes
FAX? b_No_Yes
Date Time
•Mftlix'B -ofi,,g~ GW -Groundwat';t)WW -Wastewater
Remarks: )t:' pLs. fi.d,..,.,_ f'..,..,-n:: C::
DW -Drinking Water OT -Other ___ _
Date:
S-1·3-0
Date:
Date:
Time:
H: q5
Time:
Time:
Received by: (Signature)
Received by: (Signatur-
-cJ
' ,:: ~ -~ ' ·-. .. ...: ~-· Chain of Custody
· Page_l_of_L.
Prepared by:
• ENVIRONMENT AL
SCIENCE CORP.
12065 Lebanon Road
Mt Juliet, TN 37122
Phone [phone]
Phone [phone]
FAX [phone]
pH ______ Temp
Flow