NCD980557656_20021022_NC State University (Lot 86 Farm Unit 1)_FRCBERCLA SAP QAPP_Final Report of Results May - July 2002 Groundwater Sampling and Analysis Event-OCR

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PIEDMONT GEOLOGIC, P.C.
Environmental Consultants
6003 Chapel Hill Rd .. Suite 109 • Raleigh, NC 27607 • Tel: [phone] • Fax: [phone]
FINAL REPORT OF RESULTS:
MAY-JULY 2002 GROUNDWATER SAMPLING
AND ANALYSIS EVENT 1 ·-·-----
;n) _ ij; (G _~ ~ ~J [ ~.-~I
Lot 86 Site
North Carolina State University
Raleigh, North Carolina
PREPARED FOR:
North Carolina State University
Environmental Health and Safety Center
Raleigh, North Carolina 27695
PREPARED BY:
Piedmont Geologic, P.C.
6003 Chapel Hill Road, Suite I 09
Raleigh, North Carolina 27607
October 22, 2002
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Jl]. NOV 1 2 2002 1lt !
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1.0
2.0
2.1
Report of Results: May-July 2002 Groundwater Sampling and Analysis Event
North Carolina State University, Lot 86 Site
October 22, 2002
TABLE OF CONTENTS
Page No.
INTRODUCTION ............................................................................................................................. 3
BACKGROUND ................................................................................................................................ 3
FACILITY LOCATION AND DESCRIPTION ................................................................................................ 3
2.2 SITE HISTORY ....................................................................................................................................... 4
2.3
2.4
3.0
4.0
CURRENT EXTENT OF CONTAMINATION ...........................................••.................................................. 4
FACILITY GEOLOGtC/HYDROGEOLOGIC SETTING .................................................................................. 5
GROUNDWATER SAMPLING AND ANALYSIS PROCEDURES ......................... ___ .... 6
GROUNDWATER SAMPLING AND ANALYSIS RESULTS ..................................................... 8
Appendices
A Groundwater sampling forms
B Summary laboratory reports
Figures
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4
Tables
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Site map
Groundwater potentiometric surface contour map: shallow monitoring wells
Groundwater potentiometric•surface contour map: intermediate monitoring wells
Groundwater potentiometric surface contour map: deep monitoring wells
Groundwater level data
Summarized results of laboratory analysis; groundwater samples collected May-July 2002
Summarized results of field analysis; groundwater samples collected May 2002
PIEDMONT GEOLOGIC, P.C. II
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1.0 INTRODUCTION
Report of Results: May-July 2002 Groundwater Sampling and Analysis Event
North Carolina State University, Lot 86 Site
October 22, 2002
This report presents the methods and results of a May-July 2002 groundwater sampling and analysis event
for the North Carolina State University (NCSU), Lot 86, Farm Unit# 1 site (Site), located in Raleigh, Wake
County, North Carolina. The sampling/analysis event was conducted in accordance with the following
controlling documents.
• Gro11ndwater Sampling and Analysis Plan, dated May 3, 2002, prepared by Piedmont Geologic;
• Gro11ndwater Sampling Quality Assurance Plan, dated May 3, 2002, prepared by Piedmont I Geologic.
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Following is site background information, a description of May-July 2002 groundwater sampling and
analysis procedures, and results of field and laboratory analysis of May-July 2002 groundwater samples.
Supporting sampling/analysis documentation is provided in appendices. The Level Ill laboratory data
package is provided as a companion volume to this report.
2.0 BACKGROUND
2.1 Facility Location and Description
A site map is provided as Figure 1. The Site is located on the west side of Raleigh, Wake County North
Carolina, near Carter-Finley Stadium, immediately south of the southern right-of-way of Wade Avenue
Extension, a limited access highway that connects to Interstate 40.
The approximately 1.5-acre site is located on and surrounded by state-owned property. The Site is secured
by a chain-link fence with a padlock on the gate. The Site is covered with grass and no structures are
present. A large grass covered area, west of the site and Carter-Finley stadium is used for parking during
stadium events.
PIEDMONT GEOLOGIC, P.C. 3
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2.2 Site History
Report of Results: May-July 2002 Groundwater Sampling and Analysis Event
North Carolina Stale University, Lot 86 Site
· October 22, 2002
NCSU selected lot 86 of Farm Unit No. 1 in 1969 as a burial site for hazardous chemical waste generated at
the University's educational and research laboratories. Burial of waste was discontinued in November 1980
to comply with regulations promulgated under the Resource Conservation and Recovery Act (RCRA).
The chemical wastes were placed in trenches located in the northwestern portion of the Site. The trenches
were approximately 8 feet deep and varied from 50 to 150 feet long. After filling, about 3 feet of native soil
that was excavated during trench construction was used as cover material. Later the area was seeded with
grass. The types of chemicals reported to have been buried at the site include solvents, pesticides,
inorganics, acids and bases. Although some of the liquid chemicals disposed of during the initial site
operation were poured into the trenches, both liquids and solid chemicals were generally buried in metal,
glass or plastic containers.
The Site was placed on the National Priority List (NPL) in October 1984, based on the results from an
inspection completed in June of that year.
2.3 Current Extent of Contamination
During the period of January 19 to September 21, 1999, remedial action activities were conducted on the
Lot 86 waste trench area. The remedial technology specified in the Record of Decision to address waste
material buried in the trenches, as well as contaminated soils adjacent to the trenches, was in situ mixing
and encapsulation. The goal of the shallow soil mixing was to stabilize and solidify the waste materials in
the disposal trenches and in the soils surrounding the trenches, thereby eliminating further leaching from the
disposal area. During implementation of the remedy approximately 2,240 tons of cement was used to
stabilize almost 10,090 cubic yards of waste material and impacted soil.
Groundwater monitoring at the Site has been conducted for approximately 15 years. The most prevalent
chemicals in groundwater continue to be VOCs, with chlorinated compounds ( chloroform, methylene
chloride, and carbon tetrachloride) found in the highest concentrations. The shallow groundwater has
evidenced the most impact with only trace materials of contaminants detected in the deep wells. Highest
concentrations have been consistently observed immediately downgradient of t_he landfill waste trenches,
with a rapid decrease with distance away from the Site.
PIEDMONT GEOLOGIC, P.C. 4
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Report of Results: May-July 2002 Groundwater Sampling and Analysis Event
North Carolina State University, Lot 86 Site
October 22, 2002
2.4 Facility Gcologic/llydrogcologic Setting
The Site lies within the upland division of the Piedmont Physiographic Province of the Eastern United
States. The Piedmont occurs as a wide belt extending along the eastern margin of the Appalachian
Mountains extending from Alabama to the southern Hudson Valley of New York.
Overburden soils, referred to as Saprolite, are described as typical Piedmont materials including silts, clays,
sandy/clayey silts, and sandy/silty clays with minor amounts of fine to medium gravel. The generalized
lithology is described as several feet of silty clay that transitions into micaceous sandy silt with depth.
Materials become increasingly harder and denser with increasing depth, eventually transitioning into
weathered rock then competent crystalline bedrock. Saprolite retains aspects of the parent bedrock, such as
fractures and foliations. The residual soil/saprolite stratum at the Site has been described to range in
thickness from 70 to 87 feet, although bedrock has been encountered at depths as shallow as 3 feet.
Bedrock has been mapped in the area of the site as felsic gneiss and schist. The unit consists of felsic
metamorphic rocks interlayered with mica-garnet schist, biotite gneiss, and hornblende gneiss. The rocks
are described as occurring in a northeast-trending band approximately 4 miles wide in the west Raleigh
area.
Groundwater in the area of the Site occurs in the overburden soils and the underlying bedrock, generally
under water-table (unconfined) conditions. Shallow groundwater is recharged by infiltration of
precipitation through the ground surface. Recharge varies seasonally, with most occurring in the winter
months when evapotranspiration losses are lowest.
Groundwater in bedrock occurs along zones of secondary porosity, such as fractures, bedding planes, and
foliations. The transmissivity of bedrock is dependent on the size and interconnectivity of these features.
Bedrock is recharged primarily by the overlying soil/saprolite.
Groundwater flows at the Site predominantly toward the west-northwest in the shallow, intermediate, and
bedrock strata. Measured depths to groundwater in the shallow, water table, monitoring wells are typically
30 to 40 feet below grade in the former source area. A listing of Site monitoring wells is provided in Table
1. The Site monitoring wells may be classified as shallow, intermediate, and deep monitoring wells by the
following convention.
PIEDMONT GEOLOGIC, P.C. 5
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Report of Results: May-July 2002 Groundwater Sampling and Analysis Event
North Carolina State University, Lot 86 Site
October 22, 2002
Classification of Monitorin~ Wells bv Dcoth
Well Classification Elevation of Screened Interval . Formation Intercepted by
(feet relative to National Screened Interval
Geodetic Vertical Datum,
NGVD)
Shallow 382-413 Residual soils/sanrolite
Intermediate 355 -377 Saorolite/wcathered rock
Deen 295 -345 Comnetent crvstalline bedrock
Observed horizontal potentiometric gradients in the shallow, intermediate, and deep hydrostratigraphic units
have ranged from 0.016 ft/ft to 0.022 ft/ft.
3.0 GROUNDWATER SAMPLING AND ANALYSIS PROCEDURES
Initial groundwater-sampling activities were conducted from May 20 to 30, 2002. In response to the results
of laboratory analysis of the May 2002 groundwater samples, additional groundwater sampling/analysis was
conducted in July 2002. The July 2002 activities included only monitoring well MW-43.
Groundwater sampling/analysis activities were conducted in accordance with the controlling documents
listed in Section l .O. Copies of sampling forms that were completed during the sampling event are
contained in Appendix A. All non-dedicated sampling equipment was cleaned prior to each use in
accordance with the procedures described in the Site groundwater sampling/analysis workplan. Purge water
and equipment cleaning wastewater was transferred to labeled 55-gallon drums and staged within the Site
fence for future management by NCSU.
As the initial phase of the sampling activities, groundwater levels and well depths were measured in each
monitoring well on May 20, 2002 using an optical interface probe, which distinguishes between non-
aqueous phase liquid (NAPL) and water. NAPL was not detected in any site monitoring wells. Monitoring
wells MW-9, MW-15, MW-42 were found to be dry during the gauging activities and were removed from
the sampling list.
Following gauging, monitoring wells to be sampled were purged of static groundwater in accordance with
the procedures in the Site groundwater sampling/analysis workplan. Each monitoring well was purged of
three static volumes of groundwater, or until dry, using a submersible pump with dedicated pump tubing or
a dedicated, disposable polyethylene bailer. Following the removal of each static volume of groundwater
during purging, field measurements of purge water pH, temperature, specific conductance, and dissolved
oxygen were made using pre-calibrated field meters.
PIEDMONT GEOLOGIC, P.C. 6
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Report of Results: May-July 2002 Groundwater Sampling and Analysis Event
North Carolina State University, Lot 86 Site
October 22, 2002
Usage of a pump versus bailer in the purging process was dependent on the standing column of groundwater
in the monitoring well. Monitoring wells containing less than 3-feet of standing water were purged using a
bailer. An attempt was made to minimize the groundwater flow rate during purging with either the pump or
bailer.
During preparation for purging, monitoring wells MW-33 and MW-35D were found to contain blockages
within the well casings that prevented insertion of a pump or bailer to the water table. Efforts to sample
these wells were abandoned following an unsuccessful attempt to clear the blockages using a grappling
hook.
Groundwater samples were collected from each monitoring well within 24 hours of the conclusion of
purging. Samples were collected using bottom loading, dedicated, disposable hailers and nylon rope. Upon
collection, each sample was transferred to labeled, laboratory prepared containers and promptly placed on
ice in a cooler. In addition to the groundwater samples, three field rinsate blanks were collected during the
sampling event using the following procedure.
I. A new/clean bailer was rinsed with distilled/deionized water;
2. The bailer was filled with distilled/deionized water;
3. The water was poured into laboratory prepared containers, and the containers were placed on ice with
the groundwater samples.
In addition to field blanks, a trip blank provided by the laboratory accompanied each shipment of samples
to the laboratory.
The May 2002 samples were shipped under chain of custody via overnight courier to Pace Analytical
Services of Huntersville, North Carolina and analyzed for the following.
• Volatile organics by EPA Method 6230D;
• RCRA metals by EPA Method 30 I 0/60 IO;
• Mercury by EPA Method 7470;
• Dissolved iron by EPA Method 30 I 0/60 IO;
• Methane, ethane, ethene by EPA Method 381 0;
• Alkalinity, chloride, nitrate, sulfate by EPA Method 300.0;
• Total organic carbon by EPA Method 53 I0C.
PIEDMONT GEOLOGIC, P.C. 7
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Report of Results: May-July 2002 Groundwater Sampling and Analysis Event
North Carolina State University, Lot 86 Site
October 22, 2002
In addition, duplicate May 2002 groundwater samples were analyzed in the field for the following using
pre-calibrated, direct-read field meters and a flow-through cell.
• pH;
• Temperature;
• Specific conductance;
• Dissolved oxygen;
• Oxidation/reduction potential;
• Turbidity.
Trip blanks from the May 2002 sampling event were analyzed only for volatile organics by EPA Method
6230D.
Due to a shipping delay, the final shipment of samples during the week of May 20, 2002 arrived at the
laboratory out of compliance for temperature, and the affected samples, from monitoring wells MW-2,
MW-3, MW-6, MW-8, MW-12, MW-16, MW-17, MW-36S, MW-37, could not be analyzed. In response,
the monitoring wells were re-sampled on May 29 and 30, 2002 using the same sampling/analysis procedures
described above, and submitted to Pace Analytical Services for the laboratory analyses listed above.
In response to the results of laboratory analysis of the May 22, 2002 groundwater sample from monitoring-
well MW-43, additional groundwater samples were collected from the well on July 16, 2002. One
groundwater sample and one duplicate groundwater sample were collected from MW-43 during the July
event, along with one field rinsate blank, using the same procedures described above.
The July 2002 samples were shipped under chain of custody via overnight courier to Pace Analytical
Services. One of the groundwater samples from MW-43, the field blank, and the trip blank were analyzed
for volatile organics by EPA Method 6230D. The duplicate groundwater sample from MW-43 was
submitted by Pace Analytical Services to Paradigm Analytical Laboratories, Inc. in Wilmington, North
Carolina and analyzed for volatile organics by EPA Method 6230D.
4.0 GROUNDWATER SAMPLING AND ANALYSIS RESULTS
Site groundwater-level data are presented in Table I. Groundwater potentiometric-surface contour maps
based on May 2002 groundwater levels in the shallow, intermediate, and deep monitoring wells are
provided as Figures 2, 3, and 4, respectively. Summarized results of laboratory analysis of the May-July
PIEDMONT GEOLOGIC, P. C. 8
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Report of Results: May-July 2002 Groundwater Sampling and Analysis Event
North Carolina State University, Lot 86 Site
October 22, 2002
2002 groundwater samples arc listed in Table 2, and results of field analysis of the May 2002 groundwater
samples are listed in Table 3.
Summary laboratory reports ofresults arc provided in Appendix B. The Level III laboratory data package
with case narrative is provided as a companion volume to this report.
PIEDMONT GEOLOGIC, P.C. 9
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I PIEDMONT GEOLOGIC, P.C.
Report of Results: May-July 2002 Groundwater Sampling and Analysis Event
North Carolina State University, Lot 86 Site
October 22, 2002
FIGURES
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<C32
MW46 ♦
MW43 ♦
<C:1
t.445
II
II
II
MW09
$w35S
MW35D
NOTES:
MW34S
-$$--Mw34D
NCSU Practice
F oofball Fields
1. Site map based on survey drawings '"We-II
\
\
LEGEND
MW33
MW14
♦
4 Monitoring Well
['.:'.:'.:'.:'.t] Waste Burial Area (Source Area)
--Fenced Area
............_,, Edge of Wooded Area
SCALE: 1" = 100' -------- -0 100· 200·
PIEDMONT GEOLOGIC, P.C.
EnvironmenW Consultant.,
and Feature Locations", doted July 29, 1997;
'"Road Location and Drill Position Location• h.i!miiET"----'-----'--'-'--'==...J.-'-"'"-'--"""'1
doted November 18, 1997; and "Monitor Well
and Headwall Location Mop" doted August 4,
1998; all by Murphy Hobson Socks.
2. Waste burial area per Marshall Miller and
Associates, December 1999. PD
Site Mop
2246
Lot 86
Rolei h, North Carolina
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i)-MW43
390.34
MW35S
398.35
MW29 fo>
406.67
MW34S
409.71
"#..w34D
NCSU Practice
football fields
MW14 ♦
/)
//
/
fa _.,./
~_,/'
//
PD
LEGEND
MW33
-$-Monitoring Well with Groundwater
( 405.91 )Potentiometric Surface Contour (ft.)
_406_ Groundwater Potenliometric
Surface Contour
0
SCALE: 1" = 1 oo·
100· 200·
PIEDMONT GEOLOGIC, P.C.
Environmental Consultants
Dnwflt.c Date: !CAD rue: 10 18 02 FIG.-2
Groundwater Potentiomelric Surface
Contour Map: Shallow Wells
Det.ailod:: Cient: Project No,;
2246 PD North Carolina State University
Chected: Location.:
PD
Lot 86
Rolei h, North Carolina 2
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MW46
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I MW43 •
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<=-1
M♦5
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II I I -$-MW13
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II.§ I I
ll;l1
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MW34S
#MW34D
NCSU Practice
Football netds
PD
LEGEND
MW33
-$-Intermediate Monitoring Well
405.91 with Groundwater Polentiometric
Surface Elevation (ft.)
--403-Groundwater Polentiomelric
Surface Contour
( ) Doto Nat Used In Contour;ng
0
SCALE: 1" ~ 100'
' 100· 200·
PIEDMONT GEOLOGIC, P.C.
Environmental Consultants
AC&D P'ile:
FIG.-3
Groundwater Potenliomelric Surface
Contour Map: Intermediate Wells
DeWled.! Client: Project No.:
2246 PD North Carolina State University
Checked: Loc.tioD: Lot 86
PD Rolei h, North Carolina
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-1--
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MW43 +
MW46 +
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MW32
NCSU Practice
Football Flelds
PD
LEGEND
MW36D + Deep Monitoring Well with
402.01 Groundwater Potentiometric Surface
Elevation (ft.)
_406_ Groundwater Potentiometric
Surface Contour
0
SCALE: 1" = 1 DO'
100· 200·
PIEDMONT GEOLOGIC, P.C.
Environmental Consultants
"'-UCDM »..te: I>n: Date 5/20 02 7 1 02
ACAD rue:
FIG.-1
Groundwater Potentiometric Surface
Contour Mop: Deep Wells
Detaikd: Client: Project. No.:
2246 PD North Carolina State University
Checked: Location: Lot 86
PD Ralei h, North Carolina
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I PIEDMONT GEOLOGIC, P.C.
Report of Results: May-July 2002 Groundwater Sampling and Analysis Event
North Carolina State University, Lot 86 Site
October 22, 2002
TABLES
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TABLE I
GROUNDWATER LEVEL DATA
MAY 20, 2002
North Carolina State Unh·ersity
Lot 86 Site
Raleigh, North Carolina
Well LD. Northing Easting Well Class Top of Casing Depth to Ground
Elevation (ft)(! water (ft)(2)
MW-2 747,934.50 2,083,791.44 shallow 445.17 44.66
MW-3 747,831.30 2,083,724.81 shallow 445.39 42.04
MW-6 747,987.81 2,083,695.81 shallow 438.6 I 37.32
MW-8 747,936.68 2,083,831.30 shallow 447.85 43.61
MW-II 747,987.24 2,083,904.54 shallow 430.01 25.58
MW-Ill 747,982.67 2,083,914.92 intermediate 434.29 37.45
MW-12 748,035.37 2,083,726.83 shallow 427.24 26.23
MW-121 748,031.08 2,083,738.92 intennediate 430.70 28.93
MW-13 748,099.25 2,083,498.80 shallow 423.82 28.96
MW-15 748,078.43 2,083,447.10 shallow 432.38 DRY
MW-16 748,009.06 2,083,822.21 shallow 427.94 24.63
MW-161 748,004.62 2,083,832.41 intennediate 432.14 28.55
MW-17 748,068.64 2,083,615.41 shallow 425.09 26.64
MW-171 748,062.71 2,083,626.56 intermediate 427.74 29.16
MW-27 747,678.44 2,083,751.29 shallow 448.26 42.00
MW-29 747,565.34 2,083,753.75 shallow 447.67 41.00
MW-33 747,760.99 2,084,157.9 I i ntenncdiate 441.38 35.47
MW-34S 747,476.60 2,084,052.23 shallow 439.57 29.86
MW-34D 747,469.41 2,084,050.80 deep 440.13 27.58
MW-35S 747,989.14 2,083,565.0 I shallow 443.12 44.77
MW-35D 747,991.91 2,083,552.20 deeo 444.69 45.80
MW-36S 747,905.86 2,083,672.19 shallow 442.71 40.79
MW-36D 747,898.07 2,083,671.54 deep 442.87 40.86
MW-37 747,964.33 2,083,718.54 shallow 440.88 39.11
MW-38 747,959.35 2,083,794.05 deep 445.38 42.65
MW-40 747,908.53 2,084,062.93 shallow 435.47 29.63
MW-41 748,239.12 2,083,608.18 shallow 421.17 26.14
MW-411 748,235.91 2,083,619.56 intermediate 421.57 26. 16
MW-42 748,149.51 2,083,907.73 shallow 427.25 DRY
MW-421 748,155.6 I 2,083,896.58 intennediate 426.68 24.13
MW-43 748,526.66 2,083,396.75 shallow 440.59 50.25
MW-45 748,342.75 2,083,907.91 shallow 447.50 50.16
MW-46 748,444.92 2,083,683.30 shallow 451.35 57.16
(I) Measured in feet relative to site datum.
(2) Measured relative to top-of-casing reference point.
Groundwater
Elevation (ft)(!)
400.51
403.35
401.29
404.24
404.43
396.84
401.01
401.77
394.86
DRY
403.31
403.59
398.45
398.58
406.26
406.67
405.91
409.71
412.55
398.35
398.89
401.92
402.01
401.77
402.73
405.84
395.03
395.41
DRY
402.55
390.34
397.34
394.19
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TABLE 2
SUMMARIZED RESULTS OF LABORATORY ANALYSIS
GROUNDWATER SAMPLES COLLECTED MAY-JULY 2002
North Carolina State University
Lot 86 Site
Raleigh, North Carolina
Samplel.D.: MW-2 MW-3 MW-6 MW-8 MW-8 MW-11
Duo.
Date Samoled: 5/30/02 5/30/02 5/29/02 5/29/02 5/29/02 5/23/02
SM Method 6230D (ug/L)
Benzene 5,300, 8,500• 770. <250 <250 <100
Bromobenzenc <1,000 <1,000 <500 <250 <250 <100
Bromochloromethane <1,000 <1,000 <500 <250 <250 <100
Bromodichioromet11ane <1,000. <1,000, <500-<250· <250. <100.
Bromoform <1,000 <1,000 <500 <250 <250 <100
Bromcthanc <1,000 <1,000 <500 <250 <250 <100
n-Butvibcnzene <2,000 <2,000 <1,000 <500 <500 <200
scc-Butvlbcnzene <1,000 <1,000 <500 <250 <250 <100
tert-Butvibcnzene <1,000 <1,000 <500 <250 <250 <100
Carbon Tetrachloride 2,900 • 2,800 · 1,600. 590 • 650 · <100·
Chlorobcnzene <1,000 <1,000 <500 <250 <250 <100
Chloroclhane <1,000 <1,000 <500 <250 <250 <100
Chloroform• 38,000 • 40,000-17,000, 11,000. 12,000 · 7,600•
Chioromethane <4,000 <4,000 <2,000 <1,000 <1,000 <400
2-Chlorotoiuene <1,000 <1,000 <500 <250 <250 <100
4-Chiorotoiuene <1,000 <1,000 <500 <250 <250 <100
i ,2-Dibromo-3-chloroorooane <4,000 <4,000 <2,000 <1,000 <1,000 <400
Dibromochiorometliane <1,000 <1,000 <500 <250 <250 <100
1,2-Dibromoethane (EDB) 67,000 • 2,200 , 1,200, 470. 500, <100.
Dibromomelhane <1,000 <1,000 <500 <250 <250 <100
1,2-Dichlorobcnzene <2,000 <2,000 <1,000 <500 <500 <200
1,3-Dichiorobcnzene <2,000 <2,000 <1,000 <500 <500 <200
1.4-Dichlorobcnzene <2,000 <2,000 <1,000 <500 <500 <200
Dichiorodiflouromethane <1,000' <1,000 . <500, <250 · <250, <100
1, 1-Dichloroetlrnne <1,000 <1,000 <500 <250 <250 <100
1,2-Dichloroethane <1,000. <1,000-<500 · <250• <250. <100·
1, 1-Dichioroelhene <1,000 <1,000 <500 <250 <250 <100
cis-1,2-Dichloroethene <1,000 <1,000 <500 <250 <250 <100
IIans-1,2-Dichioroethene <1,000 <1,000 <500 <250 <250 <100
1,2-Dichioroorooane 18,000, 6,200 • 2,600· <250 · <250• <100·
1,3-Dichioroorooane <1,000 <1,000 <500 <250 <250 <100
2,2-Dichloronronane <1,000 <1,000 <500 <250 <250 <100
i .1-Dichloroorooenc <1,000 <1,000 <500 <250 <250 <100
cis-1,3-Dichloronrooene <1,000 <1,000 <500 <250 <250 <100
IIans-1,3-Dichlorooroncne <1,000 <1,000 <500 <250 <250 <100
Diisooroovi etlwr <1,000 <1,000 <500 <250 <250 <100
Etlivlbcnzene <1,000 <1,000 <500 <250 <250 <100
Hexach ioro-l ,3-butadiene <4,000 <4,000 <2,000 <1,000 <1,000 <400
lsooronvlbcnzene <1,000 <1,000 <500 <250 <250 <100
n-Isonronvltoiuene <2,000 <2,000 <1,000 <500 <500 <200
Met11vlene Ci\loride <4,000 · 9,200 · <2,000 · <1,000 • <1,000 <400•
Metl1vl tert-butvi et11er <1,000 <1,000 <500 <250 <250 <100
Naohtlialene <4,000 9,200 <2,000 <1,000 <1.000 <400
n-Pron~,tbcnzcnc <1,000 <l,000 <500 <250 <250 <100
PIEDMONT GEOLOGIC, P.C.
(contmucd)
Page 1 of 10
MW-111 MW-12
5/23/02 5/30/02
<10 13,000 •
<10 <1,000
<10 <1,000
<10. <1,000,
<10 <1,000
<10 <1,000
<20 <2,000
<10 <1,000
<10 <1,000
11 • 6,900,
<10 <1,000
<10 <1,000
450 • 100,000·
<40 <4,000
<10 <1,000
<10 <1,000
<40 <4,000
<10 <1,000
<10 -6,900,
<10 <1,000
<20 <2,000
<20 <2,000
<20 <2,000
<10• <1,000 .
<10 <1,000
<10, <1,000.
<10 <1,000
<10 <1,000
<10 <1,000
<10. 23,000,
<10 <1,000
<10 <1,000
<10 <1,000
<10 <1,000
<10 <i,000
<10 <1,000
<10 <1,000
<40 <4,000
<10 <1,000
<20 <2,000
<40, 19,000·
<10 <l,000
<40 19,000
<10 <1,000
/
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TABLE 2 (continued)
SUMMARIZED RESULTS OFLAllORATORY ANALYSIS
GROUNDWATER SAMPLES COLLECTED MAY-JULY 2002
North Carolina State University
Lot 86 Site
Raleieh, North Carolina
Sample I.D.: MW-2 MW-3 MW-6 MW-8 MW-8 MW-11
Dun.
Date Samnled: 5/30/02 5/30/02 5/29/02 5/29/02 5/29/02 5/23/02
SM Method 6230D (ug/L)
Stvrene <1,000 <1,000 <500 <250 <250 <100
I, I, 1,2-Tetrachloroethane <1,000 <1,000 <500 <250 <250 <100
I, 1,2,2-Tetrachloroethane <1,000 <1,000 <500 <250 <250 <100
Tetrachloroetl1ene <1,000' <l,000• <500, <250, <250 • <100'
Toluene 6,100 • 2,700• <500 · <250 · <250 · <100 ·
1,2,3-Trichlorobenzene <4,000 <4,000 <2,000 <i,000 <1,000 <400
1,2,4-Trichiorobenzene <4,000 <4,000 <2,000 <1,000 <1,000 <400
1, 1,1-Trichloroethane <1,000. <1,000• <500 · <250 · <250 · <100,
I, 1,2-Trichloroethane <1,000 • <1,000, <500 · <250, <250 · <100
Trichloroethene <1,000' 3,400 , 630 · <250 · <250, <100,
Trichloroflourometl1ane <1,000, <1,000• <500, <250, <250 · <100,
1,2,3-Trichloronronanc <1,000 • <1,000 • <500, <250, <250, <100·
1,2,4-Trimetlivlbenzenc <i,000 <i,000 <500 <250 <250 <100
1,3,5-Trimethvlbenzene <1,000 <1,000 <500 <250 <250 <100
Vinvl chloride <1,000 <1,000 <500 <250 <250 <100
M&P Xviene <1,000 · <1,000· <500 · <250· <250• <100·
O-Xvicne <1,000 . <1,000, <500 · <250 · <250 · <100,
EPA Method 3010 / 6010 (mg/L)
Arsenic 0.0090 0.013 <0.0050 <0.0050 <0.0050 <0.0050
Barium 1.3 0.57 0.52 0.23 0.028 0.039
Cadium 0.0019 <0.0010 <0.00IO <0.0010 <0.0010· <0.00IO
Chromium 0.011 0.0024 0.055 0.015 0.0058 0.0043
Lead 0.013 0.0091 0.0079 <0.0050 <0.0050 <0.0050
Manoanese 50 13 7.9 0.082 0.093 2.1
Selenium 0.035 0.010 0.0056 <0.0050 <0.0050 <0.0050
Silver 0.0062 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020
EPA Method 7470 (mg/L)
Mercurv 0.060 <0.00020 0.00054 <0.00020 <0.00020 <0.00020
EPA Method 3010 / 6010 (mg/L)
Dissolved Iron <0.050 3.7 <0.050 <0.050 <0.050 0.34
EPA Method 3810 (mg/L)
Methane <10 <10 <10 <10 <10 <10
Etliane <20 <20 <20 <20 <20 <20
EU1enc <20 <20 <20 <20 <20 <20
EPA Method 300.0 (mg/L)
Alkalinitv 65 70 20 12 10 28
Chloride 210 7.8 48 4.7 4.7 4.5
Nitrate 6.6 <0.10 0.20 0.64 0.62 0.17
Sulfate 2.8 2.2 1.2 I.I I.I 14
SM Method 5310C (mg/L)
Total Oroanic Carbon 99 56 14 4.2 2.8 19
PIEDMONT GEOLOGIC, P.C. Page 2 of 10
MW-111 MW-12
5/23/02 5/30/02
<10 <1,000
<10 <1,000
<10 <1,000
<10• <1,000.
470 · 9,600 ·
<40 <4,000
<40 <4,000
10 , <i,000.
<10' <1,000 •
<10' <1,000,
<10' <1,000·
<10 <i,000·
<10 <1,000
<10 <1,000
<10 <1,000
<10 1,900 ·
<10' <1,000'
0.013 <0.0050
0.092 0.37
<0.0010 0.0044
0.013 <0.0020
<0.0050 <0.0050
2.0 13
<0.0050 0.010
<0.0020 <0.0020
<0.00020 0.00027
0.68 <0.050
23 <10
<20 <20
<20 <20
75 2.5
3.3 55
<0.10 0.32
2.7 <1.0
4.2 80
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TABLE 2 (continued)
SUMMARIZED RESULTS OF LABORATORY ANALYSIS
GROUNDWATER SAMPLES COLLECTED MAY-JULY 2002
North Carolina State University
Lot 86 Site
Raleigh, North Carolina
Sample I.D.: MW-121 MW-13 MW-16 MW-161 MW-17 MW-171
Date Samnled: 5/23/02 5/22/02 5/30/02 5/23/02 5/30/02 5/23/02
SM Method 6230D (ug/L)
Benzene <5.0, <0.5, 2,900 • <0.50 • 7,400 • 340 ·
Bromobenzcne <5.0 <0.5 <500 <0.50 <10 <0.50
Bromochloromcthane <5.0 <0.5 <500 <0.50, <10 <0.50
Bromodichloromethane <5.0 , <0.5 . <500 • <0.50 · <10. <0.50 .
Bromoform <5.0 <0.5 <500 <0.50 <10 <0.50
Bromethanc <5.0 <0.5 <500 <0.50 <10 <0.50
n-Butvlbenzcnc <10 <1.0 <1,000 <1.0 <20 <1.0
scc-Butvlbenzcne <5.0 <0.5 <500 <0.50 <10 <0.50
tcrt-Butvlbenzene <5.0 <0.5 <500 <0.50 <10 <0.50
Carbon Tetrachloride 170 . <0.5, 1,900 , <0.50 · 28 16
Chlorobenzenc <5.0 <0.5 <500 <0.50 <10 <0.50
Chloroetl1ane <5.0 <0.5 <500 <0.50 <10 <0.50
Chloroform 1,600, <0.5 · 35,000• 160 • 190, 230
Chlorometliane <20 <2.0 <2,000 <2.0 <40 <2.0
2-Chlorotoluene <5.0 <0.5 <500 <0.50 <10 <0.50
4-Chlorotoluene <5.0 <0.5 <500 <0.50 <10 <0.50
1,2-Dibromo, 3-ch loroorooane <20 <2.0 <2,000 <2.0 <40 <2.0
DibromochloromcU1anc <5.0 <0.5 <500 <0.50 <10 <0.50
1,2-Dibromoetlianc (EDB) 16 • <0.5, 8,900, <0.50• 28, 10 .
Dibromomcthane <5.0 <0.5 <500 <0.50 <10 <0.50
1,2-Dichlorobenzcnc <10 <1.0 <1,000 <1.0 <20 <1.0
1,3-Dichlorobenzene <10 <1.0 <1,000 <1.0 <20 <1.0
1,4-Dichlorobenzcnc <10 <1.0 <1,000 <1.0 <20 <1.0
Dichlorodiflourometlianc 13 <0.5 <500 , <0.50 • <10 • <0.50 ·
I, l-DichloroeU1ane <5.0 <0.5 <500 <0.50 <10 <0.50
1,2-Dichloroetliane <5.0 ' <0.5 . <500, <0.50 <10 . 2.1
1, 1-Dichloroethene <5.0 <0.5 <500 <0.50 <10 2.1
cis-l ,2-DichloroeU1cne <5.0 <0.5 <500 <0.50 <10 2.1
trans-1,2-Dichloroethene <5.0 <0.5 <500 <0.50 <10 2.1
1,2-Dichloroorooanc 34 · <0.5, 5,400 · 1.9 . 31 , 130
1,3-Dichloronronanc <5.0 <0.5 <500 <0.50 <10 2.1
2,2-Dichlorooronane <5.0 <0.5 <500 <0.50 <10 2.1
1, 1-Dichlorooronene <5.0 <0.5 <500 <0.50 <10 2.1
cis-1,3-Dichloroorooeoe <5.0 <0.5 <500 <0.50 <10 2.1
trans-1,3-Dich loroorooene <5.0 <0.5 <500 <0.50 <10 2.1
Diisonronvl eU1er <5.0 <0.5 <500 <0.50 <10 2.1
Ethvlbenzene <5.0 <0.5 <500 <0.50 <10 2.1
Hexach loro-1,3-butadiene <20 <2.0 <2,000 <2.0 <40 <2.0
lsooroovlbenzene <5.0 <0.5 <500 <0.50 <10 2.1
n-lsooroovltoluene <10 <1.0 <1,000 <1.0 <20 <1.0
Metl1vlenc Chloride <20 , <2.0 · <2,000 <2.0 · 68' 20.
MeU1vl tert-butvl ether <5.0 <0.5 <500 <0.50 <10 2.1
Nanhtlialene <2.0 <2.0 <2,000 <2.0 <40 <2.0
n-PronvJbcnzenc <5.0 <0.5 <500 <0.50 <10 2.1
PIEDMONT GEOLOGIC, P.C.
(contmucd)
Page 3 of 10
MW-27 MW-29
5/22/02 5/22/02
<0.50• <0.5 •
<0.50 <0.5
<0.50 <0.5
<0.50 <0.5
<0.50 <0.5
<0.50 <0.5
<1.0 <1.0
<0.50 <0.5
<0.50 <0.5
12 <0.5 ,
<0.50 <0.5
<0.50 <0.5
13 • <0.5,
<2.0 <2.0
<0.50 <0.5
<0.50 <0.5
<2.0 <2.0
<0.50 <0.5
<0.50 . <0.5·
<0.50 <0.5
<1.0 <1.0
<1.0 <1.0
<1.0 <1.0
1.2 . <0.5.
<0.50 <0.5
<0.50 · <0.5 ·
<0.50 <0.5
<0.50 <0.5
<0.50 <0.5
6.2 • <0.5 •
<0.50 <0.5
<0.50 <0.5
<0.50 <0.5
<0.50 <0.5
<0.50 <0.5
<0.50 <0.5
<0.50 <0.5
<2.0 <2.0
<0.50 <0.5
<1.0 <1.0
<2.0 • <2.0·
<0.50 <0.5
<2.0 <2.0
<0.50 <0.5
✓
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TABLE 2 (continued)
SUMMARIZED RES UL TS OF LABORATORY ANALYSIS
GROUNDWATER SAMPLES COLLECTED MAY-JULY 2002
North Carolina State University
Lot 86 Site
Ralei~h, North Carolina
Sample I.D.: MW-121 MW-13 MW-16 MW-161 MW-17 MW-171
Date Samnled: 5/23/02 5/22/02 5/30/02 5/23/02 5/30/02 5/23/02
SM Method 6230D (ug/L)
Stvrene <5.0 <0.5 <500 <0.50 <10 2.1
I, 1, 1,2-Tetrachlorocthane <5.0 <0.5 <500 <0.50 <10 2.1
I, 1,2,2-TetracblorocUianc <5.0 <0.5 <500 <0.50 <10 2.1
Tetrachlorocthene 130 • <0.5 · 1,500· <0.50· <10 <0.50
Toluene <5.0 · <0.5 • 5,000 · <0.50 · 19 , <0.50,
1,2,3-Trichlorobcnzene <2.0 <2.0 <2,000 <2.0 <40 <2.0
1,2,4-Trichlorobcnzene <2.0 <2.0 <2,000 <2.0 <40 <2.0
1, 1, 1-Trichloroethane <5.0 , <0.5 • <500, <0.50 · <10 ' <0.50 .
I, 1,2-TrichlorocUianc 28 · <0.5 · <500 • <0.50 · <10 1.7 •
TrichlorocU1ene 110 • <0.5 ' 2,700 · 1.2 • 57 • 13 '
TrichloroflouromeUiane <5.0 · <0.5 . <500· <0.50· <10' <0.50 ·
1,2,3-Trichloronronane <5.0 <0.5 • <500 • <0.50• <10• 3.6 ·
1,2,4-Trimethvlbcnzcne <5.0 <0.5 <500 <0.50 <10 <0.50
l ,3,5-TrimeU1vlbcnzene <5.0 <0.5 <500 <0.50 <10 <0.50
Vinvl chloride <5.0 <0.5 <500 <0.50 <10 <0.50
M&PXvlene <5.0 · <0.5 · <500• <0.50 · 23 <0.50 ·
0-Xvlene <5.0, <0.5 • 510 · <0.50 • <10 <0.50 •
EPA Method 3010 / 6010 (mg/L)
Arsenic 0.024 <0.0050 <0.0050 <0.0050 0.0079 <0.0050
Barium 0.090 0.12 0.13 0.14 0.13 0.019
Cadium 0.0013 <0.0010 <0.0010 <0.0010 <0.0010 <0.0010
Chromium 0.0040 <0.0020 <0.0020 0.060 0.022 0.012
Lead 0.0062 <0.0050 <0.0050 0.0050 0.022 <0.0050
Manoanese 0.25 0.61 16 0.34 1.2 0.22
Selenium <0.0050 <0.0050 0.010 <0.0050 <0.0050 <0.0050
Silver <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020
EPA Method 7470 (mg/L)
Mercurv . <0.00020 <0.00020 0.00079 <0.00020 0.00027 <0.00020
EPA Method 3010 / 6010 (mg/L)
Dissolved Iron 0.17 <0.050 0.72 1.3 <0.050 <0.050
EPA Method 3810 (mg/L)
MeU1ane <10 <10 <10 <10 <10 <10
Ethane <20 <20 <20 <20 <20 <20
Ethene <20 <20 <20 <20 <20 <20
EPA Method 300.0 (mg/L)
Alkalinilv 25 15 52 85 5 7.5
Chloride 2.3 5.6 6.3 2.0 3.7 2.5
Nitrate 0.43 4.4 <0.10 0.35 0.39 0.22
Sulfate 2.0 <1.0 4.0 2.1 1.0 <1.0
SM Method 5310C (mg/L)
Total Oroanic Carbon I.I 3.0 54 <0.50 5.6 0.86
PIEDMONT GEOLOGIC. P.C. Page4 of JO
MW-27 MW-29
5/22/02 5/22/02
<0.50 <0.5
<0.50 <0.5
<0.50 <0.5
<0.50 · <0.5 ·
<0.50, <0.5•
<2.0 <2.0
<2.0 <2.0
<0.50 • <0.5 •
<0.50 • <0.5 •
2.7 • <0.5-
1.3 . <0.5 ·
<0.50 · <0.5 •
<0.50 <0.5
<0.50 <0.5
<0.50 <0.5
<0.50 · <0.50 •
<0.50, <0.50.
<0.0050/ ~
0.051/.• 0.020
<0.0010" <0.0010
0.0055 0.0050
0.0058 <0.0050
0.45 0.017
<0.0050 <0.0050
<0.0020 <0.0020
<0.00020 <0.00020
<0.050 <0.050
<10 <10
<20 <20
<20 <20
10 18
3.2 1.9
0.58 <0.10
1.2 1.2
2.2 <0.50
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TAIILE 2 (continued)
SUMMARIZED RESULTS OF LAIIORATORY ANALYSIS
GROUNDWATER SAMPLES COLLECTED MAY-JULY 2002
North Carolina State University
Lot 86 Site
Raleh,h, North Carolina
Sample I.D.: MW-34S MW-34D MW-35S MW-36S MW-36D MW-36D
Dun.
Date Samnled: 5/20/02 5/20/02 5/22/02 5/30/02 5/22/02 5/22/02
SM Method 6230D (ug/L)
Benzene <0.5 · <0.5 . <0.5 . 5,200, <IO ' <25 •
Bromobcnzene <0.5 <0.5 <0.5 <500 <10 <25
Bromochloromethane <0.5 <0.5 <0.5 <500 <10 <25
Bromodichlorometl1ane <0.5, <0.5, <0.5 3,300. <10. <25 -
Bromoform <0.5 <0.5 <0.5 <500 <10 <25
Brometl1ane <0.5 <0.5 <0.5 <500 <10 <25
n-Butvlbcnzene <1.0 <1.0 <1.0 <1,000 <20 <50
sec-But,lbcnzene <0.5 <0.5 <0.5 <500 <10 <25
tert-Butvlbcnzene <0.5 <0.5 <0.5 <500 <10 <25
Carbon Tetrachloride <0.5 . <0.5 . <0.5 · 2,900 54 . 61·
Chlorobcnzene <0.5 <0.5 <0.5 <500 <10 <25
Chlorocthane <0.5 <0.5 <0.5 <500 <10 <25
Chloroform <0.5 • <0.5 <0.5 . 34,000 • 1,200 1,100 .
Chlorometl1ane <2.0 <2.0 <2.0 <2,000 <40 <100
2-Chlorotoluenc <0.5 <0.5 <0.5 <500 <10 <25
4-Chlorotoluene <0.5 <0.5 <0.5 <500 <10 <25
1,2-Dibromo-3-chloroorooane <0.5 <0.5 <0.5 <500 <10 <25
Dibromochlorometl1anc <0.5 <0.5 <0.5 <500 <10 <25
1,2-Dibromocthane (EDB) <0.5 <0.5 ' <0.5 • 19,000· 22 <25
Dibromomcthanc <0.5 <0.5 <0.5 <500 <IO <25
1,2-Dichlorobcnzene <1.0 <1.0 <1.0 <1,000 <20 <50
1,3-Dichlorobcnzcnc <1.0 <1.0 <1.0 <1,000 <20 <50
1,4-Dichlorobcnzcne <1.0 <1.0 <1.0 <1,000 <20 <50
Dichlorodiflouromethane <0.5 <0.5 <0.5 · <500 • <IO <25 •
1, l-Dichloroctl1ane <0.5 <0.5 <0.5 <500 <10 <25
1,2-Dichlorocthanc <0.5, <0.5 . <0.5 • 1,400 . <10 . <25 •
1, l-Dichloroctl1ene <0.5 <0.5 <0.5 <500 <10 <25
cis-l ,2-Dichloroctl1ene <0.5 <0.5 <0.5 <500 <10 <25
trans-l ,2-Dichloroctl1enc <0.5 <0.5 <0.5 <500 <10 <25
1,2-Dich loronrooane <0.5 . <0.5• <0.5 · 2,100 • 14 , <25 •
1,3-Dichloronronanc <0.5 <0.5 <0.5 <500 <10 <25
2,2-Dichloroorooane <0.5 <0.5 <0.5 <500 <10 <25
l, 1-Dichloroorooene <0.5 <0.5 <0.5 <500 <10 <25
cis-1,3-Dichloronrooene <0.5 <0.5 <0.5 <500 <10 <25
trans-1,3-Dichloronro=ne <0.5 <0.5 <0.5 <500 <10 <25
Diisooroovl ether <0.5 <0.5 <0.5 <500 <10 <25
Etl1vlbcnzene <0.5 <0.5 <0.5 <500 <10 <25
Hexachloro-l,3-bu~1diene <2.0 <2.0 <2.0 <2,000 <40 <100
lsonronvlbcnzene <0.5 <0.5 <0.5 <500 <IO <25
n-Isooroovltoluene <1.0 <1.0 <1.0 <1,000 <20 <50
',:> Metl1vlcne Chloride <0.50. <0.5i:Z. <0.5<1.~ <500.f/, ,o <10""1( <25L,..,
Methvl tert-butvl etl1er <0.5 <0.5 <0.5 <500 <10 <25
Naohtlialene <2.0 <2.0 <2.0 <2,000 <40 <100
n-PronuJOCnzcnc <0.5 <0.5 <0.5 <500 <10 <25
PIEDMONT GEOLOGIC, P.C.
(contmucd)
Page 5 of 10
MW-37 MW-38
5/30/02 5/23/02
3,600 · <0.5
<500 <0.5
<500 <0.5
<500 • <0.5-
<500 <0.5
<500 <0.5
<1,000 <1.0
<500 <0.5
<500 <0.5
4,200 . <0.5 .
<500 <0.5
<500 <0.5
55,000 · <0.5•
<2,000 <2.0
<500 <0.5
<500 <0.5
<500 <0.5
<500 <0.5
<500 · <0.5 ·
<500 <0.5
<1,000 <1.0
<1,000 <1.0
<1,000 <1.0
<500 · <0.5 ,
<500 <0.5
700 · <0.5,
<500 <0.5
<500 <0.5
<500 <0.5
<500 <0.5 ·
<500 <0.5
<500 <0.5
<500 <0.5
<500 <0.5
<500 <0.5
<500 <0.5
<500 <0.5
<2,000 <2.0
<500 <0.5
<1,000 <1.0
<500r z. >() <0.5<1.~
<500 <0.5
<2,000 <2.0
<500 <0.5
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TAIILE 2 (continued)
SUMMARIZED RESULTS OFLAHORATORY ANALYSIS
GROUNDWATER SAMPLES COLLECTED MAY-JULY 2002
North Carolina State University
Lot 86 Site
Raleieh, North Carolina
Sample I.D.: MW-34S MW-34D MW-35S MW-36S MW-36D MW-36D
Duo.
Date Samoled: 5/20/02 5/20/02 5/22/02 5/30/02 5/22/02 5/22/02
SM Method 6230D (ug/L)
Stvrene <0.5 <0.5 <0.5 <500 <10 <25
I, I, 1,2-Tetrachlorocthane <0.5 <0.5 <0.5 <500 <10 <25
I, 1,2,2-Tetrachloroctliane <0.5 <0.5 <0.5 <500 <10 <25
Tetrachlorocthene <0.5 <0.5 • <0.5 <500 • <10. <25,
Toluene <0.5 • <0.5 · <0.5 • 690 • <10 • <25 ,
1,2,3-Trichlorobenzene <2.0 <2.0 <2.0 <2,000 <40 <100
1,2,4-Trichlorobenzene <2.0 <2.0 <2.0 <2,000 <40 <100
1,1, I-Trichloroethane <0.5 · <0.5, <0.5 <500 · <10 <25 •
l, 1,2-Trichloroctliane <0.5 , <0.5 <0.5 , <500 • <10' <25 •
Trichloroctl1ene <0.5 · <0.5 <0.5 • 1,800, 18 • <25 ·
Trichloroflourometl1ane <0.5, <0.5 <0.5 · <500 · <10 . <25
1,2,3-Trichloroorooanc <0.5 . <0.5 • <0.5 · <500 • <10 . <25 ·
1,2,4-Trimethvlbenzene <0.5 <0.5 <0.5 <500 <10 <25
1,3,5-Trimethvlbenzene <0.5 <0.5 <0.5 <500 <10 <25
Vinvl chloride <0.5 <0.5 <0.5 <500 <10 <25
M&PXvlene <0.5 <0.5 • <0.5· <500 <10. <25
O-Xvlene <0.5 , <0.5 , <0.5 , <500 <10• <25 ,
EPA Method 3010 / 6010 (mg/L)
Arsenic <0.0050 <0.0050 <0.0050 <0.0050 0.037 0.036
Barium 0.037 · 0.044 0.073 0.35 <0.0050 <0.0050
Cadium <0.0010 <0.0010 <0.0010 0.0029 <0.0010 <0.0010
Chromium <0.0020 0.019 0.037 0.037 0.0054 0.0081
Lead <0.0050 <0.0050 0.0098 0.010 <0.0050 <0.0050
Man•anese 0.0089 0.033 0.42 15 0.012 0.0096
Selenium <0.0050 <0.0050 <0.0050 0.01 I <0.0050 <0.0050
Silver <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020
EPA Method 7470 (mg/L)
Mercury. <0.00020 <0.00020 <0.00020 0.0029 <0.00020 <0.00020
EPA Method 3010 / 6010 (mg/L)
Dissolved' Iron . <0.050 0.052 <0.050 <0.050 <0.050 <0.050
EPA Method 3810 (mg/L)
Methane 22 21 <10 <10 <10 <10
Ethane <20 <20 <20 <20 <20 <20
EU1enc <20 <20 <20 50 <20 <20
EPA Method 300.0 (mg/L)
Alkalinilv 120 55 10 18 65 70
Chloride 18. 2.5 2.5 39 2.2 2.0
Nitrate 0.25 0.53 0.66 <0.10 0.13 <0.10
Sulfate 18. 2.7 1.4 1.5 3.0 3.0
SM Method 5310C (mg/L)
Total Or~anic Carbon 5.4 2.1 1.0 75 <0.50 <0.50
PIEDMONT GEOLOGIC, P.C. Page 6 of 10
MW-37 MW-38
5/30/02 5/23/02
<500 <0.5
<500 <0.5
<500 <0.5
<500· <0.5 ,
<500 • <0.5,
<2,000 <2.0
<2,000 <2.0
<500 • <0.5,
<500 · <0.5 .
1,200 • <0.5 ..
<500, <0.5 ·
<500 • <0.5 ,
<500 <0.5
<500 <0.5
<500 <0.5
<500 <0.5 .
<500, <0.5.
<0.0050 <0.0050
0.43 0.016
<0.0010 <0.0010
0.030 0.0038
0.QJI <0.0050
4.0 0.031
<0.0050 <0.0050
<0.0020 <0.0020
0.0012 <0.00020
<0.050 <0.050
<10 <10
<20 <20
<20 <20
60 120
24 1.9
0.13 <0.10
1.4 3.5
22 0.83
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TABLE 2 (continued)
SUMMARIZED RESULTS OF LAIIORATORY ANALYSIS
GROUNDWATER SAMPLES COLLECTED MAY-JULY 2002
North Carolina State University
Lot 86 Site
RaleiPh, North Carolina
Sample I.D.: MW-40 MW-41 MW-411 MW-421 MW-43 MW-43
Date Samoled: 5/22/02 5/22/02 5/22/02 5/22/02 5/22/02 7/16/02
SM Method 6230D (ug/L)
Benzene <0.50 • <0.5 <0.5 • <0.50 • <0.50 ' <0.50 •
Bromobcnzcne <0.50 <0.5 <0.5 <0.50 <0.50 <0.50
Bromochloromethanc <0.50 <0.5 <0.5 <0.50 <0.50 <0.50
Bromodichloromclbane <0.50. <0.5 <0.5 • <0.50 • <0.50 <0.50,
Bromoform <0.50 <0.5 <0.5 <0.50 <0.50 <0.50
Bromctlianc <0.50 <0.5 <0.5 <0.50 <0.50 <0.50
n-Butvlbcnzcne <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
scc-Butvlbcnzenc <0.50 <0.5 <0.5 <0.50 <0.50 <0.50
tcn-Butvlbcnzene <0.50 <0.5 <0.5 <0.50 <0.50 <0.50
Carbon Tetrachloride <0.50 · <0.5 • <0.5 . <0.50, <0.50-<0.50 ,
Chlorobcnzene <0.50 <0.5 <0.5 <0.50 <0.50 <0.50
Chloroetl1anc <0.50 <0.5 <0.5 <0.50 <0.50 <0.50
Chloroform 13 • <0.5 · <0.5 , 0.91 , 8.1 , IO •
Chlorometliane <2.0 <2.0 <2.0 <2.0 <2.0 <2.0
2-Chlorotolucne <0.50 <0.5 <0.5 <0.50 <0.50 <0.50
4-Chlorotolucnc <0.50 <0.5 <0.5 <0.50 <0.50 <0.50
1,2-Dibromo-3-chlorooronane <2.0 <2.0 <2.0 <2.0 <2.0 <2.0
Dibromochloromelbane <0.50 <0.5 <0.5 <0.50 <0.50 <0.50
1,2-Dibromoelbanc (EDB) <0.50· <0.5· <0.5 • <0.50 • <0.50 , <0.50 •
Dibromometlianc <0.50 <0.5 <0.5 <0.50 <0.50 <0.50
1,2-Dichlorobenzcnc <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
1,3-Dichlorobenzenc <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
1,4-Dichlorobenzenc <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
Dichlorodiflourometlianc <0.50 , <0.5 ' <0.5. <0.50 • <0.50 . <0.50,
1, 1-Dichloroelbane <0.50 <0.5 <0.5 <0.50 <0.50 <0.50
1,2-Dichloroetliane <0.50 · <0.5 • <0.5 • <0.50 • <0.50 • <0.50 ·
I, l-Dichloroetl1cne <0.50 <0.5 <0.5 <0.50 <0.50 <0.50
cis-1,2-Dichloroetl1cnc <0.50 <0.5 <0.5 <0.50 <0.50 <0.50
trans-l ,2-Dichloroetl1cnc <0.50 <0.5 <0.5 <0.50 <0.50 <0.50
1,2-Dichloroorooanc <0.50 • <0.5, <0.5, <0.50 <0.50• <0.50 ·
1,3-Dichloroorooanc <0.50 <0.5 <0.5 <0.50 <0.50 <0.50
2,2-Dichloronronanc <0.50 <0.5 <0.5 <0.50 <0.50 <0.50
I, 1-Dichlorooro=nc <0.50 <0.5 <0.5 <0.50 <0.50 <0.50
cis-1,3-Dichlorooronene <0.50 <0.5 <0.5 <0.50 <0.50 <0.50
trans-1,3-Dichlorooroncnc <0.50 <0.5 <0.5 <0.50 <0.50 <0.50
Diisooronvl ctl1cr <0.50 <0.5 <0.5 <0.50 <0.50 <0.50
Elbvlbenzenc <0.50 <0.5 <0.5 <0.50 <0.50 <0.50
Hexachloro-1,3-butadiene <2.0 <2.0 <2.0 <2.0 <2.0 <2.0
lsonroovlbcnzenc <0.50 <0.5 <0.5 <0.50 <0.50 <0.50
n-Isooroovltolucne <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
Mcthvlene Chloride <2.0 • <2.0 <2.0 <2.0• <2.0, <2.0
Metl1vl tert-butvl ctl1cr <0.50 <0.5 <0.5 <0.50 <0.50 <0.50
Naohtlialcnc <2.0 <2.0 <2.0 <2.0 <2.0 <2.0
n-Prom1lbenzcnc <0.50 <0.5 <0.5 <0.50 <0.50 <0.50
PIEDMONT GEOLOGIC, P.C.
(contmucd)
Page 7 of IO
MW-43 MW-45
Duo.
7/16/02 5/22/02
<0.50 <0.5,
<0.50 <0.5
<0.50 <0.5
<0.50· <0.5 ·
<0.50 <0.5
<0.50 <0.5
<1.0 <1.0
<0.50 <0.5
<0.50 <0.5
<0.50• .<0.5 ·
<0.50 <0.5
<0.50 <0.5
10 <0.5 ,
<2.0 <2.0
<0.50 <0.5
<0.50 <0.5
<2.0 <2.0
<0.50 <0.5
<0.50 · <0.5,
<0.50 <0.5
<1.0 <1.0
<1.0 <1.0
<1.0 <1.0
<0.50 • <0.5.
<0.50 <0.5
<0.50, <0.5 •
<0.50 <0.5
<0.50 <0.5
<0.50 <0.5
<0.50· <0.5·
<0.50 <0.5
<0.50 <0.5
<0.50 <0.5
<0.50 <0.5
<0.50 <0.5
<0.50 <0.5
<0.50 <0.5
<2.0 <2.0
<0.50 <0.5
<1.0 <1.0
<2.0, <2.0,
<0.50 <0.5
<2.0 <2.0
<0.50 <0.5
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TABLE 2 (continued)
SUMMARIZED RESULTS OF LABORATORY ANALYSIS
GROUNDWATER SAMPLES COLLECTED MAY-JULY 2002
North Carolina State University
Lot 86 Site
Raleigh, North Carolina
Sample I.D.: MW-40 MW-41 MW-411 MW-421 MW-43 MW-43
Date Samnled: 5/22/02 5/22/02 5/22/02 5/22/02 5/22/02 7/16/02
SM Method 6230D (ug/L)
Stvrene <0.50 <0.5 <0.5 <0.50 <0.50 <0.50
1, 1, 1,2-Tetrachloroetbane <0.50 <0.5 <0.5 <0.50 <0.50 <0.50
1, 1,2,2-Tetrachloroetbane <0.50 <0.5 <0.5 <0.50 <0.50 <0.50
Tetrachloroethcne <0.50 , <0.5 • <0.5 · <0.50 · <0.50 · <0.50 .
Toluene <0.50 • <0.5 <0.5 <0.50 · <0.50 • <0.50,
1,2,3-Trich lorobenzene <2.0 <2.0 <2.0 <2.0 <2.0 <2.0
1,2,4-Trichlorobenzene <2.0 <2.0 <2.0 <2.0 <2.0 <2.0
1, 1, 1-Trichloroetbane <0.50 • <0.5, <0.5 • <0.50 • <0.50, <0.50 ,
l, 1,2-Trichloroetbane <0.50 • <0.5 · <0.5 · <0.50 · <0.50 . <0.50 •
Trichloroethene <0.50 · <0.5 · <0.5, <0.50 • <0.50 · <0.50,
Trichloro0ourometbaue <0.50' <0.5 · <0.5 • <0.50 · <0.50 <0.50,
1,2,3-Trichloroorooaue <0.50, <0.5 <0.5. <0.50 • <0.50· <0.50 ·
1,2,4-Trimctli vi benzene <0.50 <0.5 <0.5 <0.50 <0.50 <0.50
1,3,5-Trimctbvlbenzcnc <0.50 <0.5 <0.5 <0.50 <0.50 <0.50
Vinvl chloride <0.50 <0.5 <0.5 <0.50 <0.50 <0.50
M&P Xvlene <0.50, <0.5• <0.5 . <0.50 , <0.50. <0.50 ·
O-Xvlene <0.50 · <0.5 · <0.5 <0.50 · <0.50 · <0.50
EPA Method 3010 / 6010 (mg/L)
Arsenic 0.010 0.020 <0.0050 <0.0050 0.0058 NA
Barium 0.16 0.50 · 0.029 • 0.048 0.050 · NA
Cadium <0.0010 <0.0010 0.0010 0.0035 <0.0010 NA
Chromium 0.052 0.061 0.041 0.052 0.049 NA
Lead 0.014 0.035 <0.0050 <0.0050 0.0062 NA
ManQanese 0.59 4.4 0.072 0.43 0.28 NA
Selenium <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 NA
Silver <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 NA
EPA Method 7470 (mg/L)
Mercurv <0.00020 <0.0020 <0.00020 <0.00020 <0.00020 NA
EPA Method 3010 / 6010 (mg/L)
Dissolved Iron 0.084 0.17 0.12 0.18 0.092 NA
EPA Method 3810 (mg/L)
Metlianc <10 <10 <10 <10 <10 NA
Ethane <20 <20 <20 <20 <20 NA
Etbene <20 <20 <20 <20 <20 NA
EPA Method 300.0 (mg/L)
Alkalinitv 7.5 10 15 65 15 NA
Chloride 4.1 7.2 2.4 2.2 2.7 NA
Nitrate 0.59 0.78 0.29 0.16 0.15 NA
Sulfate <1.0 3.6 1.4 3.2 1.3 NA
SM Method 5310C (mg/L)
Total Ornanic Carbon 0.50 0.74 0.82 0.60 0.63 NA
PIEDMONT GEOLOGIC. P. C. Page 8 of 10
MW-43 MW-45
Dup.
7/16/02 5/22/02
<0.50 <0.5
<0.50 <0.5
<0.50 <0.5
<0.50 · <0.5 ·
<0.50 • <0.5 ·
<2.0 <2.0
<2.0 <2.0
<0.50 • <0.5 •
<0.50 · <0.5 ,
<0.50, <0.5 ,
<0.50 , <0.5 ·
<0.50, <0.5 ·
<0.50 <0.5
<0.50 <0.5
<0.50 <0.5
<0.50, <0.5.
<0.50, <0.5 •
NA 0.049
NA 0.17 ,
NA <0.0010
NA 0.062
NA 0.020
NA 1.2
NA <0.0050
NA <0.0020
NA <0.00020
NA <0.050
NA <10
NA <20
NA <20
NA 20
NA 2.8
NA 0.88
NA <1.0
NA <0.50
I
I TAIILE 2 (continued)
SUMMARIZED RESULTS OF LABORATORY ANALYSIS
GROUNDWATER SAMPLES COLLECTED MAY-JULY 2002
I North Carolina State University
Lot 86 Site
I Sample 1.0.: MW-46 Field Bia Trip Blank Trip Blank Trip Blank
Date Sam led: 5/22/02 5/22/02 5/29/02 7/16/02 5/22/02 5/29/02 7/16/02
I SM Method 62300 (ug/L)
/ Benzene <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
Bromobcnzene <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
I BromochloromeU1anc <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
BromOOichloromcthane ./ <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
Bromoform <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
I <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<1.0 <LO <LO <LO <LO <LO <LO
sec-But lbcnzcnc <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
tert-But !benzene <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 I Carbon Tetrachloride ./ <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
Chlorobcnzene <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
ChlorocU1ane <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
I Chloroform ./ <0.5 19 <0.5 <0.5 <0.5 <0.5 <0.5
Chlorometbane <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0
2-Chlorotolucnc <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
I 4-Chlorotoluene <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 ~ -
1,2-Dibromo03-chloro ro anc <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 ~~
DibromochloromeUiane <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 ffl-!,'j\l ,; -. -.
1,2-Dibromoethanc (EDB) / <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 ,. -,
I ··" ' DibromomeU1ane <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 ' -
1,2-Dichlorobenzene <LO <LO <1.0 <LO <LO <LO <1.0
1,3-Dichlorobenzene <1.0 <LO <LO <1.0 <LO <1.0 <1.0 I 1,4-Dichlorobenzene <LO <1.0 <1.0 <1.0 <1.0 <1.0 <1.0
DichlorodiflouromcUianc ✓ <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
1, 1-DichlorocUianc <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
I 1,2-DichlorocU1ane / <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
1,1-Dichloroctbene <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
cis-1,2-Dichloroctbene <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
I <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
/ <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
I <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
'I
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0
I <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<LO <LO <1.0 <LO <LO <1.0 <LO
/ <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0
I <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
I (continued)
PIEDMONT GEOLOGIC, P.C. Page 9 of 10 ~
I
I TABLE 2 (continued)
SUMMARIZED RESULTS OF LABO RA TORY ANALYSIS
GROUNDWATER SAMPLES COLLECTED MAY-JULY 2002
I North Carolina State University
Lot 86 Site
I Sample I.D.: MW-46 Field Blan Trip Blank Trip Blank Trip l!lank
Date Sam led: 5/22/02 5/22/02 5/29/02 7/16/02 5/22/02 5/29/02 7/16/02
I SM Method 6230D (ug/L)
St enc <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
I, 1, 1,2-Tetrachlorocthane <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
I I, 1,2,2-Tetrachlorocthanc <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
Tetrachlorocthcnc ,/ <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
Toluene / <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
I 1,2,3-Trichlorobcnzenc <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0
1,2,4-Trichlorobcnzenc <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0
1,1, I-Trichloroethane / <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
I, 1,2-Trichlorocthane / <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 I Trichlorocthcnc / <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
Trichloroflouromethanc / <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
1,2,3-Trichlor anc / <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
I 1,2,4-Trimeth ,enc <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
Vin I chloride <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
I M&P X Jene / <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
0-X Jene / <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5
EPA Method 3010 / 6010 (mg/L)
I Arsenic 0.0059 <0.0050 <0.0050 NA NA NA NA
Barium 0.15 , <0.0050 <0.0050 NA NA NA NA
Cadium <0.0010 <0.0010 <0.0010 NA NA NA NA
Chromium 0.051 <0.0020 <0.0020 NA NA NA NA I Lead 0.016 <0.0050 <0.0050 NA NA NA NA
Man ancsc 1.4 <0.0050 <0.0050 NA NA NA NA
Selenium <0.0050 <0.0050 <0.0050 NA NA NA NA
I Silver <0.0020 <0.0020 <0.0020 NA NA NA NA
EPA Method 7470 (mg/L)
Mcrcur <0.00020 <0.00020 <0.00020 NA NA NA NA
I EPA Method 3010 / 6010 (mg/L)
Dissolved Iron <0.050 <0.50 <0.050 NA NA NA NA
EPA Method 3810 (mg/L)
I -Methane <10 <10 <10 NA NA NA NA
EU1ane <20 <20 <20 NA NA NA NA
Ethcnc <20 <20 <20 NA NA NA NA
,I EPA Method 300.0 (mg/L)
Alkalinit 5.0 5.0 5.0 NA NA NA NA
Chloride 5.8 <1.0 <1.0 NA NA NA NA
Nitrate 1.2 <0.10 <0.10 NA NA NA NA
I Sulfate <1.0 <1.0 <1.0 NA NA NA NA
SM Method 5310C (mg/L) 1111 Total Or anic Carbon 0.64 <0.50 2.2 NA NA NA NA ..
I NA= Nol analyzed.
I PIEDMONT GEOLOGIC, P.C. Page 10 of 10
-------------------TABLE3
SUMMARIZED RESULTS OFFIELD ANALYSIS
GROUNDWATER SAMPLES COLLECTED MAY 2002
North Carolina State University
Lot 86 Site
Raleigh, North Carolina
Sample I.D.: MW/ MW-3 MW-6 MW-8 MW-11 MW-111 MW-12 MW-121 MW-13 MW-16
/ ./ ✓ / / / ,/ I ./
Samole Date: 5/30/02 5/30/02 5/29/02 5/29/02 5/23/02 5/23/02 5/30/02 5/23/02 5/22/02 5/30/02
Field Analysis
oH 5.32 5.94 4.98 4.91 5.36 5.91 4.64 5.69 5.50 5.81
Temperature (°C) 19.9 20.7 18.3 19.2 19.6 20.7 21.1 20.9 16.4 18.9
Soecific Conductance (umhos/cm) 712 178.9 177 50.4 120.5 146.7 190 71.4 88.8 137.1
Dissolved Oxvoen (mo/L) 3.14 2.06 2.75 3.46 0.23 0.51 2.48 1.18 2.00 2.23
Oxidation Reduction Potential (mv) 4 3 3 3 37 24 7 -50 2.96 5
Turbiditv (NTlJ) 14.3 20.5 36.5 8.33 71.5 16.3 7.81 473 13.1 36.5
Sample I.D.: MW-161 MW-17 MW-171 MW-27 MW-29 MW-34S MW-34D MW-35S MW-36S MW-36D
/ ✓ ./ / ./ ./ ./ / / ./
Samole Date: 5/23/02 5/30/02 5/23/02 5/22/02 5/22/02 5/20/02 5/20/02 5/22/02 5/30/02 5/22/02
field Analysis
oH 5.92 4.88 4.85 4.92 5.18 6.69 5.60 5.05 4.68 6.12
Temrerature (°C) 18.9 17.9 20.7 16.7 17.8 17.1 14.9 18.2 19.9 22.5
Soecific Conductance (umhos/cm) 112.8 41.3 29.7 44.8 33.2 236 57.7 35.9 187 139.1
Dissolved Oxvgen (mg/L) 2.39 2.59 0.77 0.62 3.30 4.52 7.25 0.71 1.85 1.05
Oxidation Reduction Potential (mv) -83 4 41 303 319 238 306 292 4 208
Turbidity (NTlJ) 477 15 47.3 862 9.28 >1,000 399 862 31.3 8.98
Sample I.D.: MW-37 MW-38 MW-40 MW-41 MW-411 MW-421 MW-43 MW-45 MW-46
I / / ./ ./ / ~ /
Sample Date: 5/30/02 5/23/02 5/22/02 5/22/02 5/22/02 5/22/02 5/22/02 5/22/02 5/22/02
Field Analysis
oH 4.74 6.75 4.81 4.79 4.90 5.65 5.62 5.03 4.78
Temoerature (°C) 18 18.9 16.4 15.7 16.1 16.2 13.4 13.5 14.0 ii!'~~
Soecific Conductance (umhos/cm) 127.5 176.2 37.8 42.0 30.4 115.4 48.7 37.4 53.3 ii Dissolved Oxvoen (mo/L) 2.52 1.47 2.53 2.17 2.0 1.39 5.62 4.45 4.89 . .
Oxidation Reduction Potential (mv) 4 -183 269 333 327 224 233 300 302
Turbidity (NTlJ) 27.4 1.72 10.8 81.0 73.0 128 404 10.0 >1,000
PIEDMONT GEOLOGIC, P.C.
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PIEDMONT GEOLOGIC, P.C.
Report of Results: May-July 2002 Groundwater Sampling and Analysis Event
North Carolina State University, Lot 86 Site
October 22, 2002
APPENDIX A
GROUNDWATER SAMPLING FORMS
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GROUNDWATER SAMPLING FORM
CLIENT: North Carolina State University PROJECT NAME: Lot 86
PROJECT LOCATION: Lot 86, Raleigh, NC PROJECT NO.: 2246
SAMPLING PERSONNEL: Matt James SAMPLING DATE: 5/24/02
John Harper SAMPLING METHOD: Bailer
Well l.D.: MW-2 Well Type: Monitoring
Well Diameter (in.): 3 Reference Point: Top of Casing
Gauge Date: 5/20/02 Well Gauging Meter: ORS Probe
Depth to Water (ft.): 44.66 Depth to Bottom (ft.): 52.07
Water Column (ft.): 7.41 .35 x gaVft. = __ 2.6 ___ gal
conversion factO( 1 well volume
Three Well Volumes = 7.8 gal
Purge Method: Gruncllos Purge Date: 5/23/02 I
Purge Volume (gal.): 3.5 gal drv Purge Time: Start 1740 Stop 1800
Well Volumes Removed 1 2 3 4
pH 5.44
Temp. ('C) 17.7
Specnic Conductance (umohs/cm) 620
Dissolved Oxygen (mg/L) 1.53
Oxidation/Reduction Potential (mv) 172 turbidity-160
Sample Characteristics S.Clear
Sample ID: MW-2
Sample Time: Start 1600 Stop
Sample Containers Filled
No. Type Preservative Analysis
4 40 ml voa HCL 6230D
4 40 ml voa H,so, TOG
2 40 ml crimp voa HCL Methane
1 500 ml plastic None Dissolved Metals
1 500 ml plastic None Chloride, nitrate, sulfate
1 500 ml plastic HNO3 RCRA Metals (8) + Mn
Field Measurements of Sample:
pH 5.29 Cole-Parmer pH/Con 10 Meter
Temp(' C) 22.1 Cole-Parmer pH/Con 10 Meter
Specttic Conductance (umohs/cm) 686 Cole-Parmer pH/Con 10 Meter
Dissolved Oxygen (mg/L) 0.75 YSI Model 95 Meter
Oxidation/Reduction Potential (mv) 1 Digi-Sense Model 5938 pHIORP Meter
Ferrous Iron (mg/L) NIA Hach Ferrous Iron Kit
Turbidity (NTU) 24.9 Hach 2100P Turbidimeter
Sample Characteristics Clear
Weather Conditions: Sunny 90
Remarks: I think a bailer is in the bottom of the well; pump unable to reach bottom;
Well dry wait 5 min. to restart purge; Dry again wait an additional 5 min. to restart purge. Mean smell from well H2O.
I . p IEDMONT GEOLOGIC, P.C.
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GROUNDWATER SAMPLING FORM
CLIENT: North Carolina State University PROJECT NAME: Lot 86
PROJECT LOCATION: Lot 86, Raleigh, NC PROJECT NO.: 2246
SAMPLING PERSONNEL: Matt James SAMPLING DATE: 5/30/02
John Harper SAMPLING METHOD: Bailer
Well I.D.: MN-2 Well Type: Monitoring
Well Diameter (in.): 3 Reference Point: Top of Casing
Gauge Date: 5/20/02 Well Gauging Meter: ORS Probe
Depth to Water (ft.): 44.66 Depth to Bottom (ft.): 52.07
Water Column (ft.): 7.41 .35 x gaVft. = __ 2.6 __ gal
conversion factor 1 well volume
Three Well Volumes = 7.8 gal
Purge Method: Grundfos Purge Date: 5/29/02
Purge Volume (gal.): 3.0 gal drv Purge Time: Start 1315 Stop 1330
Well Volumes Removed 1 2 3 4
pH 5.43
Temp. (°C) 19.4
Specific Conductance (umohs/cm) 258
Dissolved Oxygen (mg/L) 1.57
Oxidation/Reduction Potential (mv) 5
Sample Characteristics Clear
Sample ID: MN-2
Sample lime: Start 1000 Stop
Sample Containers Filled
No. Type Preservative Analysis
4 40 ml voa HCL 6230D
4 40 ml voa H,so, TOG
2 40 ml crimp voa HCL Methane
1 500 ml plastic None Dissolved Metals
1 500 ml plastic None Chloride, nitrate, sulfate
1 500 ml plastic HNO3 RCRA Metals (8) + Mn
Field Measurements of Sample:
pH 5.32 Cole-Parmer pH/Con 10 Meter
Temp(' C) 19.9 Cole-Parmer pH/Con 1 0 Meter
Spectlic Conductance (umohs/cm) 712 Cole-Parmer pH/Con 10 Meter
Dissolved Oxygen (mg/L) 3.14 YSI Model 95 Meter
Oxidation/Reduction Potential (mv) 4 Digi-Sense Model 5938 pH/ORP Meter
Ferrous Iron (mg/L) N/A Hach Ferrous Iron Kit
Turbidity (NTU) 14.3 Hach 21 00P T urbidimeter
Sample Characteristics Clear
Weather Conditions: Sunny 90
Remarks:
I p IEDMONT GEOLOGIC, P.C.
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GROUNDWATER SAMPLING FORM
CLIENT: North Carolina State University PROJECT NAME: Lot 86
PROJECT LOCATION: Lot 86, Raleigh, NC PROJECT NO.: 2246
SAMPLING PERSONNEL: Matt James SAMPLING DATE: 5/24/02
John Harper SAMPLING METHOD: Bailer
Well I.D.: MW-3 Well Type: Monitoring
Well Diameter (in.): 3 Reference Point: Top of Casing
Gauge Date: 5/20/02 Well Gauging Meter: ORS Probe
Depth to Water (ft.): 42.04 Depth to Bottom (ft.): 50.06
Water Column (ft.): 8.02 .35 x gaVft. = _2.8 __ gal
conversion factor 1 well volume
Three Well Volumes = 8.4 gal
Purge Method: Grundfos Purge Date: 5/24/02 I
Purge Volume (qal.): 5 gal drv Purge lime: Start 0910 Stop 0940
Well Volumes Removed 1 2 3 4
pH 5.76 5.96
Temp. ('C) 17.3 17.6
Spec~ic Conductance (umohs/cm) 118 157.1
Dissolved Oxygen (mg/L) 0.69 2.55
OxidatiorvReduction Potential (mv) -189 -148 turbidity= 153
Sample Characteristics Clear Clear
Sample ID: MW-3
Sample lime: Start 1030 Stop
Sample Containers Filled
No. Type Preservative Analysis
4 40 ml voa HCL 6230D
4 40 mlvoa H,so, TOC
2 40 ml crimp voa HCL Methane
1 500 ml plastic None Dissolved Metals
1 500 ml plastic None Chloride, nitrate, sulfate
1 500 ml plastic HNO3 RCRA Metals (8) + Mn
Field Measurements of Sample:
pH 5.92 Cole-Parmer pH/Con 1 O Meter
Temp(' C) 22.1 Cole-Parmer pH/Con 10 Meter
Specific Conductance (umohs/cm) 175.5 Cole-Parmer pH/Con 1 O Meter
Dissolved Oxygen (mg/L) 1.15 YSI Model 95 Meter
OxidatiorvReduction Potential (mv) -1 Digi-Sense Model 5938 pH/ORP Meter
Ferrous Iron (mg/L) N/A Hach Ferrous Iron Kit
Turbidity (NTU) 6.02 Hach 2100P Turbidimeter
Sample Characteristics Clear
Weather Conditions: Sunny 90
Remarks: 3 gal dry; wait 5 min. to restart purge; 1 gal dry; wait 5. min to restart purge.
Well dry wait 5 min. to restart purge; Dry again wait an additional 5 min. to restart purge. Mean smell from well H2O.
I · p IEDMONT GEOLOGIC, P.C.
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GROUNDWATER SAMPLING FORM
CLIENT: North Carolina State University PROJECT NAME: Lot 86
PROJECT LOCATION: Lot 86, Raleigh, NC PROJECT NO.: 2246
SAMPLING PERSONNEL: Matt James SAMPLING DATE: 5/30/02
John Harper SAMPLING METHOD: Bailer
Well I.D.: MW-3 Well Type: Monitoring
Well Diameter (in.): 3 Reference Point: Top of Casing
Gauge Date: 5/20/02 Well Gauging Meter: ORS Probe
Depth to Water (ft.): 42.04 Depth to Bottom (ft.): 50.06
Water Column (ft.): 8.02. .35 x gaVft. = _2.8 __ gal
conversion factor 1 well volume
Three Well Volumes = 8.4 gal
Purge Method: Grundfos Purge Date: 5/29/02 I
Purge Volume (gal.): 5 gal drv Purge Time: Start 1445 Stop 1515
Well Volumes Removed 1 2 3 4
pH 5.84 5.93
Temp. ("C) 19 18.7
Specific Conductance (umohs/cm) 149.9 157.7
Dissolved Oxygen (mg/L) 1.24 1.72
OxidatiorvReduction Potential (mv) 2 0
Sample Characteristics S. Clear Clear
Sample ID: MW-3
Sample Time: Start 1020 Stop
Sample Containers Filled
No. Type Preservative Analysis
4 40 ml voa HCL 6230D
4 40 ml voa H2SO, TOC
2 40 ml crimp voa HCL Methane
1 500 ml plastic None Dissolved Metals
1 500 ml plastic None Chloride, nitrate, sulfate
1 500 ml plastic HNO3 RCRA Metals (8) + Mn
Field Measurements of Sample:
pH 5.94 Cole-Parmer pH/Con 10 Meter
Temp(' C) 20.7 Cole-Parmer pH/Con 10 Meter
Specific Conductance ( umohs/cm) 178.9 Cole-Parmer pH/Con 1 0 Meter
Dissolved Oxygen (mg/L) 2.06 YSI Model 95 Meter
OxidatiorvReduction Potential (mv) 3 Digi-Sense Model 5938 pH/OAP Meter
Ferrous Iron (mg/L) N/A Hach Ferrous Iron Kit
Turbidity (NTU) 20.5 Hach 21 00P Turbidimeter
Sample Characteristics Clear
Weather Conditions: Sunny 90
Remarks: Split methane bottles between MW-3 and MW-12; Due to shortage of methane bottles.
I p IEDMONT GEOLOGIC, P.C.
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GROUNDWATER SAMPLING FORM
CLIENT: North Carolina State University PROJECT NAME: Lot 86
PROJECT LOCATION: Lot 86, Raleigh, NC PROJECT NO.: 2246
SAMPLING PERSONNEL: Matt James SAMPLING DATE: 5/24/02
John Harper SAMPLING METHOD: Bailer
Well I.D.: MW-6 Well Type: Monitoring
Well Diameter (in.): 3 Reference Point: Top of Casing
Gauge Date: 5/20/02 Well Gauging Meter: ORS Probe
Depth to Water (ft.): 37.32 Depth to Bottom (ft.): 42. 79
Water Column (ft.): 5.5 .35 x gaVft. = _1.9 ___ gal
conversion factor 1 well volume
Three Well Volumes = 5.7 gal
Purge Method: Grundfos Purge Date: 5/23/02 I
Pume Volume (gal.): 5.7 Purge lime: Start 1445 Stop 1515
Well Volumes Removed 1 2 3 4
pH 4.70 4.62 4.62
Temp. ('C) 18.5 18.0 18.1
Specific Conductance (umohs/cm) 184 171 173
Dissolved Oxygen (mg/L) 0.1 0.35 0.61
Oxidation'Reduction Potential (mv) 289 292 287
Sample Characteristics S. Clear S. Clear S. Clear
Sample ID: MW-6
Sample lime: Start 1140 Stop
Sample Containers Filled
No. Type Preservative Analysis
4 40 mlvoa HCL 6230D
4 40 ml voa H,so, TOC
2 40 ml crimp voa HCL Methane
1 500 m I plastic None Dissolved Metals
1 500 ml plastic None Chloride, nitrate, sulfate
1 500 ml plastic HNO3 RCRA Metals (8) + Mn
Field Measurements of Sample:
pH 4.81 Cole-Parmer pH/Con 1 O Meter
Temp(° C) 21.6 Cole-Parmer pH/Con 1 O Meter
Specific Conductance (umohs/cm) 182 Cole-Parmer pHVCon 1 O Meter
Dissolved Oxygen (mg/L) 0.47 YSI Model 95 Meter
Oxidation'Reduction Potential (mv) 130 Digi-Sense Model 5938 pHVORP Meter
Ferrous Iron (mg/L) N/A Hach Ferrous Iron Kit
Turbidity (NTU) 19.1 Hach 2100P Turbidimeter
Sample Characteristics Clear
Weather Conditions: Sunny 80
Remarks:
I · P tEDMONT G EOLOGtc, p_c_
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GROUNDWATER SAMPLING FORM
CLIENT: North Carolina State University PROJECT NAME: Lot 86
PROJECT LOCATION: Lot 86, Raleigh, NC PROJECT NO.: 2246
SAMPLING PERSONNEL: Matt James SAMPLING DATE: 5/29/02
John Harper SAMPLING METHOD: Bailer
Well I.D.: MW-6 Well Type: Monitoring
Well Diameter (in.): 3 Reference Point: Top of Casing
Gauge Date: 5/20/02 Well Gauging Meter: ORS Probe
Depth to Water (ft.): 37.32 Depth to Bottom (ft.): 42.79
Water Column (ft.): 5.5 .35 x gaVft. = _1.9 ___ gal
conversion factor 1 well volume
Three Well Volumes = 5.7 gal
Purge Method: Grundfos Purge Date: 5/29/02 I
Purge Volume (gal.l: 4.0 gal dry Purge Time: Start 1030 Stop 1045
Well Volumes Removed 1 2 3 4
pH 4.88 4.89
Temp. ('C) 17.1 17.1
Spec~ic Conductance (umohs/cm) 185 177
Dissolved Oxygen (mg/L) 1.79 0.87
OxidatiorvReduction Potential (mv) 5 3
Sample Characteristics S. Clear Clear
Sample ID: MW-6
Sample Time: Start 1715 Stop
Sample Containers Filled
No. Type Preservative Analysis
4 40 ml voa HCL 6230D
4 40 mlvoa H,so, TOC
2 40 ml crimp voa HCL Methane
1 500 ml plastic None Dissolved Metals
1 500 ml plastic None Chloride, nitrate, sulfate
1 500 ml plastic HNO, RCRA Metals (8) + Mn
Field Measurements of Sample:
pH 4.98 Cole-Parmer pH/Con 1 O Meter
Temp(' C) 18.3 Cole-Parmer pH/Con 10 Meter
Specttic Conductance (umohs/cm) 177 Cole-Parmer pH/Con 1 O Meter
Dissolved Oxygen (mg/L) 2.75 YSI Model 95 Meter
OxidatiorvReduction Potential (mv) 3 Digi-Sense Model 5938 pH/ORP Meter
Ferrous Iron (mg/L) N/A Hach Ferrous Iron Kit
Turbidity (NTU) 36.5 Hach 2100P Turbidimeter
Sample Characteristics Clear
Weather Conditions: Sunny 90
Remarks: MS-MSD sample taken@ 1730 from MW-6.
I p IEDMONT GEOLOGIC, P.C.
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GROUNDWATER SAMPLING FORM
CLIENT: North Carolina State University PROJECT NAME: Lot 86
PROJECT LOCATION: Lot 86, Raleigh, NC PROJECT NO.: 2246
SAMPLING PERSONNEL: Matt James SAMPLING DATE: 5/24/02
John Harper SAMPLING METHOD: Bailer
Well I.D.: MW-8 Well Type: Monitoring
Well Diameter (in.): 3 Reference Point: Top of Casing
Gauge Date: 5/20/02 Well Gauging Meter: ORS Probe
Depth to Water (ft.): 43.61 Depth to Bottom (ft.): 53.39
Water Column (ft.): 6.78 .35 x gaVft. = _5.4 __ gal
conversion factor 1 well volume
Three Well Volumes = 7.1 gal
Purge Method: Grundfos Purge Date: 5/23/02 I
Purae Volume (gal.): 2.5 gal drv Purge Time: Start 1315 Stop 1355
Well Volumes Removed 1 2 3 4
pH 4.58
Temp. ('C) 19.2
Specific Conductance (umohs/cm) 41.4
Dissolved Oxygen (mg/L) 0.14 Turbidity= 6.38
Oxidation/Reduction Potential (mv) 322
Sample Characteristics Clear
Sample ID: MW-8
Sample Time: Start 1110 Stop
Sample Containers Filled
No. Type Preservative Analysis
4 40 ml voa HCL 6230D
4 40 ml voa H,so, TOC
2 40 ml crimp voa HCL Methane
1 500 ml plastic None Dissolved Metals
1 500 ml plastic None Chloride, nitrate, sulfate
1 500 ml plastic HNO3 RCRA Metals (8) + Mn
Field Measurements of Sample:
pH 4.95 Cole-Parmer pH/Con 1 O Meter
Temp(° C) 22.3 Cole-Parmer pH/Con 1 O Meter
Specific Conductance (umohs/cm) 52.5 Cole-Parmer pH/Con 10 Meter
Dissolved Oxygen (mg/L) 0.98 YSI Model 95 Meter
Oxidation/Reduction Potential (mv) 116 Digi-Sense Model 5938 pH/OAP Meter
Ferrous Iron (mg/L) N/A Hach Ferrous Iron Kit
Turbidity (NTU) 8.63 Hach 2100P Turbidimeter
Sample Characteristics Clear
Weather Conditions: Sunny 75
Remarks: 1.5 gal dry; wait 5 min. to restart purge; 1 gal dry; wait 5 min to restart purge.
I p IEDMONT GEOLOGIC, P.C.
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GROUNDWATER SAMPLING FORM
CLIENT: North Carolina State University PROJECT NAME: Lot 86
PROJECT LOCATION: Lot 86, Raleigh, NC PROJECT NO,: 2246
SAMPLING PERSONNEL: Matt James SAMPLING DATE: 5/29/02
John Harper SAMPLING METHOD: Bailer
Well I.D.: MW-8 Well Type: Monitoring
Well Diameter (in.): 3 Reference Point: Top of Casing
Gauge Date: 5/20/02 Well Gauging Meter: ORS Probe
Depth to Water (ft.): 43.61 Depth to Bottom (ft.): 53.39
Water Column (ft.): 9.8 .35 x gaVft, = _3.4 ___ gal
conversion factor 1 well volume
Three Well Volumes = 10.2 gal
Purge Methoo: Grundfos Purge Date: 5/29/02
Puma Volume (qal.): 3.0 gal dry Purge lime: Start 1000 Stop 1015
Well Volumes Removed 1 2 3 4
pH 5.27
Temp. (°C) 17.7
Specific Conductance (umohs/cm) 40.5
Dissolved Oxygen (mg/L) 2.72
Oxidation/Reduction Potential (mv) 9
Sample Characteristics Clear
Sample ID: MW-8
Sample lime: Start 1650 Stop
Sample Containers Filled
No. Type Preservative Analysis
4 40 ml voa HCL 6230D
4 40 ml voa H2SO4 TOG
2 40 ml crimp voa HCL Methane
1 500 ml plastic None Dissolved Metals
1 500 ml plastic None Chloride, nitrate, sulfate
1 500 ml plastic HNO3 RCRA Metals (8) + Mn
Field Measurements of Sample:
pH 4.91 Cole-Parmer pH/Con 10 Meter
Temp(" C) 19.2 Cole-Parmer pH/Con 1 o Meter
Specific Conductance (umohs/cm) 50.4 Cole-Parmer pH/Con 10 Meter
Dissolved Oxygen (mg/L) 3.46 YSI Model 95 Meter
Oxidation/Reduction Potential (mv) 3 Digi-Sense Model 5938 pH/OAP Meter
Ferrous Iron (mg/L) N/A Hach Ferrous Iron Kit
Turbidity (NTU) 8.33 Hach 21 00P Turbidimeter
Sample Characteristics Clear
Weather Conditions: Sunny 90
Remarks: FB-2@ 1630; MW-8 Dup@ 1700.
.• PIEDMONT GEOLOGIC, P.C.
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GROUNDWATER SAMPLING FORM
CLIENT: North Carolina State University PROJECT NAME: Lot 86
PROJECT LOCATION: Lot 86, Raleigh, NC PROJECT NO.: 2246
SAMPLING PERSONNEL: Mall James SAMPLING DATE: 5/23/02
John Harper SAMPLING METHOD: Bailer
Well I.D.: MW-11 Well Type: Monitoring
Well Diameter (in.): 4 Reference Point: Top of Casing
Gauge Date: 5/20/02 Well Gauging Meter: ORS Probe
. Depth to Water (ft.): 25.58 Depth to Bottom (ft.): 29.35
Water Column (ft.): 3.77 .65 X gaVft. = -2.5 ___ gal
conversion factor 1 well volume
Three Well Volumes = 7.4 gal
Purge Method: Grundfos Purge Date: 5/22/02 I
Pume Volume (qal.): 2.8 gal drv Purge Time: Start 1736 Stop 1749
Well Volumes Removed 1 2 3 4
pH 5.40
Temp. ("C) 16.2
Specific Conductance (umohs/cm) 103.9
Dissolved Oxygen (mg/L) 0.76
OxidatiorvReduction Potential (mv) -22 Turbidity= 25.6
Sample Characteristics Clear
Sample ID: MW-11
Sample Time: Start 1130 Stop
Sample Containers Filled
No. Type Preservative Analysis
4 40 mlvoa HCL 6230D
4 40 ml voa H2SO4 TOC
2 40 ml crimp voa HCL Methane
1 500 ml plastic None Dissolved Metals
1 500 ml plastic None Chloride, nitrate, sulfate
1 500 ml plastic HNO3 RCRA Metals (8) + Mn
Field Measurements of Sample:
pH 5.36 Cole-Parmer pH/Con 1 0 Meter
Temp ("C) 19.6 Cole-Parmer pH/Con 1 0 Meter
Specific Conductance (umohs/cm) 120.5 Cole-Parmer pH/Con 10 Meter
Dissolved Oxygen (mg/L) 0.23 YSI Model 95 Meter
OxidatiorvReduction Potential (mv) 37 Digi-Sense Model 5938 pH/OAP Meter
Ferrous Iron (mg/L) N/A Hach Ferrous Iron Kit
Turbidity (NTU) 71.5 Hach 21 00P Turbidimeter
Sample Characteristics Clear
Weather Conditions: Sunny 70
Remarks: Dry after 1.5 gal; wait 5 min. to restart purge; Dry after 2.5 gal; wait 5 min. to restart; Dry after 2.8 gal
I p IEDMONT GEOLOGIC, P.C.
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GROUNDWATER SAMPLING FORM
CLIENT: North Carolina State University PROJECT NAME: Lot 86
PROJECT LOCATION: Lot 86, Raleigh, NC PROJECT NO.: 2246
SAMPLING PERSONNEL: Matt James SAMPLING DATE: 5/23/02
John Harper SAMPLING METHOD: Bailer
Well I.D.: MW-11 I Well Type: Monitoring
Well Diameter (in.): 2 Reference Point: Top of Casing
Gauge Date: 5/20/02 Well Gauging Meter: ORS Probe
Depth to Water (ft.): 37.45 Depth to Bottom (ft.): 67.97
Water Column (ft.): 30.52 .16 x gaVft. = _4.9 ___ gal
conversion factor 1 well volume
Three Well Volumes = 15.0 gal
Purge Method: Grundfos Purqe Date: 5/22/02
Purge Volume (qal.): 15 Purge Time: Start 1705 Stop 1718
Well Volumes Removed 1 2 3 4
pH 5.72 5.84 5.94
Temp. ('C) 16.4 16.5 16.4
Specific Conductance (umohs/cm) 137.1 140.9 141.4
Dissolved Oxygen (mg/L) 0.41 0.29 0.35
OxidatiorvReduction Potential (mv) -2 -92 -102 Turbidity= 27.6
Sample Characteristics Clear Cloudy Clear
Sample ID: MW-11 I
Sample Time: Start 1040 Stop
Sample Containers Filled
No. Type Preservative Analysis
4 40 ml voa HCL 6230D
4 40 ml voa H2SO4 TOG
2 40 ml crimp voa HCL Methane
1 500 ml plastic None Dissolved Metals
1 500 ml plastic None Chloride, nitrate, suttate
1 500 m I plastic HNO3 RCRA Metals (8) + Mn
Field Measurements of Sample:
pH 5.91 Cole-Parmer pH/Con 10 Meter
Temp(' C) 20.7 Cole-Parmer pH/Con 10 Meter
Specific Conductance (umohs/cm) 146.7 Cole-Parmer pH/Con 10 Meter
Dissolved Oxygen (mg/L) 0.51 YSI Model 95 Meter
OxidatiorvReduction Potential (mv) 24 Digi-Sense Model 5938 pH/ORP Meter
Ferrous Iron (mg/L) NIA Hach Ferrous Iron Kit
Turbidity (NTU) 16.3 Hach 2100P Turbidimeter
Sample Characteristics Clear
Weather Conditions: Sunny 70
Remarks: Dry after 12.5 gal; wait 5 min. to restart purge.
I p IEDMONT GEOLOGIC, P.C.
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GROUNDWATER SAMPLING FORM
CLIENT: North Carolina State University PROJECT NAME: Lot 86
PROJECT LOCATION: Lot 86, Raleigh, NC PROJECT NO.: 2246
SAMPLING PERSONNEL: Matt James SAMPLING DATE: 5/24/02
John Harper SAMPLING METHOD: Bailer
Well l.D.: MW-12 Well Type: Monitoring
Well Diameter (in.): 4 Reference Point: Top of Casing
Gauge Date: 5/20/02 Well Gauging Meter: ORS Probe
Depth to Water {ft.): 26.23 Depth to Bottom {ft.): 34.18
Water Column (ft.): 7.95 .65 x gaVft. = _5.2 __ gal
conversion factor 1 well volume
Three Well Volumes = 16 gal
Purge Method: Grundfos Purge Date: 5/24/02 I
Purge Volume (gal.): 6.5 gal div Purge Time: Start 1000 Stop 1030
Well Volumes Removed 1 2 3 4
pH 4.53
Temp. ('C) 16.7
Specific Conductance (umohs/cm) 192.2
Dissolved Oxygen (mg/L) 1.46
OxidatiorvReduction Potential (mv) 72 Turbidity= 5.99
Sample Characteristics Clear
Sample ID: MW-12
Sample Time: Start 1730 Stop
Sample Containers Filled
No. Type Preservative Analysis
4 40 mlvoa HCL 6230D
4 40 mlvoa H,so, TOC
2 40 ml crimp voa RCc Mebldne
1 500 ml plastic None Dissolved Metals
1 500 ml plastic None Chloride, nitrate, sulfate !
1 500 ml plastic HNO3 RCRA Metals (8) + Mn
Field Measurements of Sample:
pH 5.11 Cole-Parmer pH/Con 10 Meter
Temp(' C) 20.6 Cole-Parmer pH/Con 1 0 Meter
Spec~ic Conductance (umohs/cm) 44.3 Cole-Parmer pH/Con 1 0 Meter
Dissolved Oxygen (mg/L) 0.45 YSI Model 95 Meter
OxidatiorvReduction Potential (mv) 0 Digi-Sense Model 5938 pH/OAP Meter
Ferrous Iron (mg/L) N/A Hach Ferrous Iron Kit
Turbidity (NTU) 6.72 Hach 21 00P Turbidimeter
Sample Characteristics Clear
Weather Conditions: Sunny 80
Remarks: 3 gal dry; wait 5 min. to restart purge; 2 gal dry wait 5 min to restart purge; 1.5 gal dry.
I I p IEDMONT GEOLOGIC, P.C.
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GROUNDWATER SAMPLING FORM
CLIENT: North Carolina State University PROJECT NAME: Lot 86
PROJECT LOCATION: Lot 86, Raleigh, NC PROJECT NO.: 2246 I
SAMPLING PERSONNEL: Matt James SAMPLING DATE: 5/23/02
John Harper SAMPLING METHOD: Bailer
Well I.D.: MW-12I Well Type: Monitoring
Well Diameter (in.): 2 Reference Point: Top of Casing
Gauge Date: 5/20/02 Well Gauging Meter: ORS Probe
Depth to Water (ft.): 28.93 Depth to Bottom (ft.): 66.46
Water Column (ft.): 37.53 .16 x gaVft. = ~6.0 __ gal
conversion factor 1 well volume
Three Well Volumes = 18 gal
Purge Method: Grundfos Purge Date: 5/22/02 I
Purge Volume (gal.): 24 Purge Time: Start 1555 Stop 1613
Well Volumes Removed 1 2 3 4
pH 6.85 5.99 5.88 5.77
Temp. ("C) 16.5 17.0 16.6 16.6
Spec~ic Conductance (umohslcm) 55.2 48.9 54.3 54.1
Dissolved Oxygen (mg/L) 0.89 0.43 0.58 a.so
OxidatiorvReduction Potential (mv) 242 268 269 257 Turbidity=
Sample Characteristics S. Clear Cloudy S. Cloudy Cloudy
Sample ID: MW-12I
Sample Time: Start 0940 Stop
Sample Containers Filled
No. Type Preservative 1' . Ana ysIs
4 40 ml voa HCL 6230D
4 40 ml voa H,so, TOG
2 40 ml crimp voa HCL Methane
1 500 ml plastic None Dissolved Metals
1 500 ml plastic None Chloride, nitrate, sulfate
1 500 ml plastic HNO, RCRA Metals (8) + Mn
Field Measurements of Sample:
pH 5.69 Cole-Parmer pH/Con 10 Meter
Temp(° C) 20.9 Cole-Parmer pH/Con 1 o Meter
Specific Conductance (umohslcm) 71.4 Cole-Parmer pH/Con 1 O Meter
Dissolved Oxygen (mg/L) 1.18 YSI Model 95 Meter
OxidatiorvReduction Potential (mv) -50 Digi-Sense Model 5938 pl-VORP Meter
Ferrous Iron (mg/L) N/A Hach Ferrous Iron Kit
Turbidity (NTU) 473 Hach 2100P Turbidimeter
Sample Characteristics Clear
Weather Conditions: Sunny 80
Remarks:
I p IEDMONT G EOLOG/C, P.C.
>1,000
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GROUNDWATER SAMPLING FORM
CLIENT: North Carolina State University PROJECT NAME: Lot 86
PROJECT LOCATION: Lot 86, Raleigh, NC PROJECT NO.: 2246
SAMPLING PERSONNEL: Matt James SAMPLING DATE: 5/30/02
John Harper SAMPLING METHOD: Bailer
Well I.D.: MW-12 Well Type: Monitoring
Well Diameter (in.): 4 Reference Point: Top of Casing
Gauge Date: 5/20/02 Well Gauging Meter: ORS Probe
Depth to Water (ft.): 26.23 Depth to Bottom (ft.): 34.18
Water Column (ft.): 8.0 .65 X gal/ft. = _5.2 __ gal
conversion factor 1 well volume
Three Well Volumes = 15.5 gal
Purge Method: Grundfos Purge Date: 5/29/02 I
Purae Volume (gal.\: 7 aal drv Purge Time: Start 1530 Stop 1600
Well Volumes Removed 1 2 3 4
pH 4.61
Temp. (°C) 17.7
Specific Conductance (umohs/cm) 186.5
Dissolved Oxygen (mg/L) 1.28
Oxidatior>'Reduction Potential (mv) 4
Sample Characteristics Clear
Sample ID: MW-12
Sample Time: Start 1200 Stop
Sample Containers Filled
No. Type Preservative Analysis
4 40 ml voa HCL 6230D
4 40 mlvoa H,so, TOC
2 40 ml crimp voa HCL Methane
1 500 ml plastic None Dissolved Metals
1 500 ml plastic None Chloride, nitrate, sulfate
1 500 ml plastic HNO, RCRA Metals (8) + Mn
Field Measurements of Sample:
pH 4.64 Cole-Parmer pH/Con 1 0 Meter
Temp(' C) 21.1 Cole-Parmer pH/Con 1 0 Meter
Specific Conductance (umohs/cm) 190 Cole-Parmer pH/Con 10 Meter
Dissolved Oxygen (mg/L) 2.48 YSI Model 95 Meter
Oxidatior>'Reduction Potential (mv) 7 Digi-Sense Model 5938 pH/ORP Meter
Ferrous Iron (mg/L) N/A Hach Ferrous Iron Kit
Turbidity (NTU) 7.81 Hach 21 00P Turbidimeter
Sample Characteristics Clear
Weather Conditions: Sunny 80
Remarks:
I p IEDMONT GEOLOGIC, P.C.
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GROUNDWATER SAMPLING FORM
CLIENT: North Carolina State University PROJECT NAME: Lot 86
PROJECT LOCATION: Lot 86, Raleigh, NC PROJECT NO.: 2246
SAMPLING PERSONNEL: Matt James SAMPLING DATE: 5/22/02
John Harper SAMPLING METHOD: Bailer
Well l.D.: MW-13 Well Type: Monitoring
Well Diameter (in.): 4 Reference Point: Top of Casing
Gauge Date: 5/20/02 Well Gauging Meter: ORS Probe
Depth to Water (ft.): 28.96 Depth to Bottom (tt.): 31.16
Water Column (tt.): 2.20 .65 x gaVft. = _1.4 __ gal
conversion factor 1 well volume
Three Well Volumes = 4.3 gal
Purge Method: Grundfos Purge Date: 5/21 /02 I
Purge Volume (gal.): 4.3 Purge Time: Start 1311 Stop 1526
Well Volumes Removed 1 2 3 4
pH 5.07 4.79 4.86
-•mp. ('C) 16.3 16.4 16.4
Specific Conductance (umohs/cm) 147.0 112.1 118.4
Dissolved Oxygen (mg/L) 4.81 4.09 4.06
Oxidation/Reduction Potential (mv) 265 263 263 Turbidity=
Sample Characteristics S. Cloudy Cloudy S. Cloudy
Sample ID: MW-13
Sample Time: Start 1051 Stop
Sample Containers Filled
No. Type Preservative Analysis
4 40 ml voa HCL 6230D
4 40 mlvoa H,so, TOC
2 40 ml crimp voa HCL Methane
1 500 ml plastic None Dissolved Metals
1 500 ml plastic None Chloride, nitrate, sulfate
1 500 ml plastic HNO3 RCRA Metals (8) + Mn
Field Measurements of Sample:
pH 5.5 Cole-Parmer pH/Con 1 O Meter
Temp(° C) 16.4 Cole-Parmer pH/Con 1 O Meter
Specific Conductance (umohs/cm) 88.8 Cole-Parmer pH/Con 10 Meter
Dissolved Oxygen (mg/L) 2 YSI Model 95 Meter
Oxidation/Reduction Potential (mv) 2.96 Digi-Sense Model 5938 pH/ORP Meter
Ferrous Iron (mg/L) N/A Hach Ferrous Iron Kit
Turbidity (NTU) 13.1 Hach 2100P Turbidimeter
Sample Characteristics Clear
Weather Conditions: Sunny Low 60's
Remarks:
I p IEDMONT GEOLOGIC, P.C.
48.7
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GROUNDWATER SAMPLING FORM
CLIENT: North Carolina State University PROJECT NAME: Lot 86
PROJECT LOCATION: Lot 86, Raleigh, NC PROJECT NO.: 2246
SAMPLING PERSONNEL: Matt James SAMPLING DATE: 5/24/02
John Harper SAMPLING METHOD: Bailer
Well l.D.: MW-16 Well Type: Monitoring
Well Diameter (in.): 3 Reference Point: Top of Casing
Gauge Date: 5/20/02 Well Gauging Meter: ORS Probe
Depth to Water (ft.): 24.63 Depth to Bottom (ft.): 32.67
Water Column (ft.): 8.04 .35 x gaVft. = _2.8 __ gal
conversion factor 1 well volume
Three Well Volumes = 8.4 gal
Purge Method: Grunofos Purge Date: 5/25/02 I
Purge Volume (gal.): 5 gal dry Purge Time: Start 1530 Stop 1550
Well Volumes Removed 1 2 3 4
pH 5.41 5.45
Temp. (°C) 17.1 17.6
Specific Conouctance (umohs/cm) 134.1 136.5
Dissolved Oxygen (mg/L) 0.33 0.26 Turbidity= 22.1
Oxidatior/Reduction Potential (mv) -96 -117
Sample Characteristics Clear Clear
Sample ID: MW-16
Sample Time: Start 1200 Stop
Sample Containers Filled
No. Type Preservative Analysis
4 40 ml voa HCL 6230D
4 40 mlvoa H,so, TOG
2 40 ml crimp voa HCL Methane
1 500 ml plastic None Dissolved Metals
1 500 ml plastic None Chloride, nitrate, sulfate
1 500 ml plastic HNO, RCRA Metals (8) + Mn
Field Measurements of Sample:
pH 5.38 Cole-Parmer pH/Con 1 O Meter
Temp(° C) 20.9 Cole-Parmer pH/Con 1 O Meter
Specific Conouctance (umohs/cm) 137.3 Cole-Parmer pH/Con 1 O Meter
Dissolved Oxygen (mg/L) 0.58 YSI Model 95 Meter
Oxidatior/Reduction Potential (mv) -112 Digi-Sense Model 5938 pH/OAP Meter
Ferrous Iron (mg/L) N/A Hach Ferrous Iron Kit
Turbidity (NTU) 6.45 Hach 2100P Turbidimeter
Sample Characteristics Clear
Weather Conditions:
Remarks: Dry 1.5 gal; wait 5 min. to restart purge; 1.5 gal dry; wait 5 min. to restart purge; dry after 5 gal.
PIEDMONT GEOLOGIC, P.C.
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GROUNDWATER SAMPLING FORM
CLIENT: North Carolina State University PROJECT NAME: Lot 86
PROJECT LOCATION: Lot 86, Raleigh, NC PROJECT NO.: 2246
SAMPLING PERSONNEL: Matt James SAMPLING DATE: 5/23/02
John Harper SAMPLING METHOD: Bailer
Well I.D.: MW-16I Well Type: Monitoring
Well Diameter (in.): 2 Reference Point: Top of Casing
Gauge Date: 5/20/02 Well Gauging Meter: ORS Probe
Depth to Water (ft.): 28.55 Depth to Bottom (ft.): 61.00
Water Column (ft.): 32.45 .16 x gaVft. = _5.2 __ gal
conversion factor 1 well volume
Three Well Volumes = 16 gal
Purge Method: Grundfos Purge Date: 5/22/02 I
Purge Volume (gal.): 15.5 gal dry Purge Time: Start 1433 Stop 1458
Well Volumes Removed 1 2 3 4
pH 5.81 5.98 6.02
Temp. ('C) 16.5 16.9 16.7
Specttic Conductance (umohs/cm) 116.9 107.3 102.7
Dissolved Oxygen (mg/L) 0.62 0.67 0.71 Turbidity= >1,000
OxidatiorvReduction Potential (mv) 327 312 273
Sample Characteristics Cloudy Cloudy Silty
Sample ID: MW-16I
Sample Time: Start 0830 Stop
Sample Containers Filled
No. Type Preservative Analysis
4 40 ml voa HCL 6230D
4 40 ml voa H,so, TOC
2 40 ml crimp voa HCL Methane
1 500 ml plastic None Dissolved Metals
1 500 m I plastic None Chloride, nitrate, sulfate
1 500 ml plastic HNO3 RCRA Metals (8) + Mn
Field Measurements of Sample:
pH 5.92 Cole-Parmer pH/Con 1 0 Meter
Temp(' C) 18.9 Cole-Parmer pH/Con 1 0 Meter
Specific Conductance (umohs/cm) 112.8 Cole-Parmer pH/Con 1 0 Meter
Dissolved Oxygen (mg/L) 2.39 YSI Model 95 Meter
OxidatiorvReduction Potential (mv) -83 Digi-Sense Model 5938 pH/OAP Meter
Ferrous Iron (mg/L) N/A Hach Ferrous Iron Kit
Turbidity (NTU) 477 Hach 21 00P Turbidimeter
Sample Characteristics S. Clear
Weather Conditions:
Remarks: Dry 8gal; wait 5 min. to restart purge; 11 gal dry; wait 5 min. to restart purge;
.• PIEDMONT GEOLOGIC, P.C.
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GROUNDWATER SAMPLING FORM
CLIENT: North Carolina State University PROJECT NAME: Lot 86
PROJECT LOCATION: Lot 86, Raleigh, NC PROJECT NO.: 2246
SAMPLING PERSONNEL: Matt James SAMPLING DATE: 5/30/02
John Harper SAMPLING METHOD: Bailer
Well I.D.: MW-16 Well Type: Monitoring
Well Diameter (in.): 3 Reference Point: Top of Casing
Gauge Date: 5/20/02 Well Gauging Meter: ORS Probe
Depth to Water (ft.): 24.63 Depth to Bottom (ft.): 32.67
Water Column (ft.): 8.04 .35 x gaVft. = _2.8 __ gal
conversion factor 1 well volume
Three Well Volumes = 8.4 gal
Purge Method: Grundfos Purge Date: 5129102
Purge Volume (gal.): 3.5 gal drv Purge Time: Start 1100 Stop 1115
Well Volumes Removed 1 2 3 4
pH 5.45
Temp. (0C) 18.2
Specific Conductance (umohslcm) 127.3
Dissolved Oxygen (mg/L) 0.82
Oxidation/Reduction Potential (mv) 10.31
Sample Characteristics Clear
Sample ID: MW-16
Sample Time: Start 0830 Stop
Sample Containers Filled
No. Type Preservative Analysis
4 40 mlvoa HCL 6230D
4 40 ml voa H,so, TOC
2 40 ml crimp voa HCL Methane
1 500 ml plastic None Dissolved Metals
1 500 ml plastic None Chloride, nitrate, sulfate
1 500 ml plastic HNO, RCRA Metals (8) + Mn
Field Measurements of Sample:
pH 5.81 Cole-Parmer pH/Con 10 Meter
Temp(" C) 18.9 Cole-Parmer pH/Con 1 O Meter
Specific Conductance (umohslcm) 137.1 Cole-Parmer pH/Con 10 Meter
Dissolved Oxygen (mg/L) 2.23 YSI Model 95 Meter
Oxidation/Reduction Potential (mv) 5 Digi-Sense Model 5938 pH/OAP Meter
Ferrous Iron (mg/L) NIA Hach Ferrous Iron Kit
Turbidity (NTU) 36.5 Hach 2100P Turbidimeter
Sample Characteristics Clear
Weather Conditions:
Remarks:
I p IEDMONT GEOLOGIC, P.C.
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GROUNDWATER SAMPLING FORM
CLIENT: North Carolina State University PROJECT NAME: Lot 86
PROJECT LOCATION: Lot 86, Raleigh, NC PROJECT NO.: 2246
SAMPLING PERSONNEL: Matt James SAMPLING DATE: 5/24/02
John Harper SAMPLING METHOD: Bailer
Well I.D.: MW-17 Well Type: Monitoring
Well Diameter (in.): 2 Reference Point: Top of Casing
Gauge Date: 5/20/02 Well Gauging Meter: ORS Probe
Depth to Water (ft.): 26.64 Depth to Bottom (ft.): 31.39
Water Column (ft.): 4.75 .16 x gaVft. = _0.8 __ gal
conversion factor 1 well volume
Three Well Volumes = 2.4 gal
Purge Method: Grundfos Purge Date: 5/23/02
Purge Volume (gal.): 0.8 gal drv Purge Time: Start 1620 Stop 1640
Well Volumes Removed 1 2 3 4
pH 4.86
Temp. (°C) 17.6
Specific Conductance (umohs/cm) 36.7
Dissolved Oxygen (mg/L) 0.92
OxidatiorvReduction Potential (mv) 184
Sample Characteristics S. Clear
Sample ID: MW-17
Sample Time: Start 1220 Stop
Sample Containers Filled
No. Type Preservative Analysis
4 40 mlvoa HCL 6230D
4 40 ml voa H,so, TOG
2 40 ml crimp voa HCL Methane
1 500 ml plastic None Dissolved Metals
1 500 ml plastic None Chloride, nitrate, sulfate
1 500 ml plastic HNO3 RCRA Metals (8) + Mn
Field Measurements of Sample:
pH 5.05 Cole-Parmer pH/Con 1 O Meter
Temp(° C) 21.1 Cole-Parmer pH/Con 1 O Meter
Specific Conductance (umohs/cm) 43.7 Cole-Parmer pH/Con 10 Meter
Dissolved Oxygen (mg/L) 0.55 YSI Model 95 Meter
OxidatiorvReduction Potential (mv) 37 Digi-Sense Model 5938 pH/ORP Meter
Ferrous Iron (mg/L) N/A Hach Ferrous Iron Kit
Turbidity (NTU) 14.9 Hach 2100P Turbidimeter
Sample Characteristics Clear
Weather Conditions: Sunny 80 degrees
Remarks: 0.5 gal dry; wait 5 min. to restart purge; 0.25 gal dry.
I p IEDMONT GEOLOGIC, P.C.
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GROUNDWATER SAMPLING FORM
CLIENT: North Carolina State University PROJECT NAME: Lot 86
PROJECT LOCATION: Lot 86, Raleigh, NC PROJECT NO.: 2246
SAMPLING PERSONNEL: Matt James SAMPLING DATE: 5/23/02
John Harper SAMPLING METHOD: Bailer
Well I.D.: MW-17 I Well Type: Monitoring
Well Diameter (in,): 2 Reference Point: Top of Casing
Gauge Date: 5/20/02 Well Gauging Meter: ORS Probe
Depth to Water (ft.): 29.16 Depth to Bottom (ft.): 63.53
Water Column (ft.): 34.37 .16 X gaVft. = _5.5 __ gal
conversion factor 1 well volume
Three Well Volumes = 16 gal
Purge Method: Grundfos Purge Date: 5/22/02 I
Purge Volume (gal.): 23gal dry Purge Time: Start 1628 Stop 1649
Well Volumes Removed 1 2 3 4
pH 4.85 4.75 4.54 4.26
Temp. ("C) 15.9 16.3 16.4 16.7
Specttic Conductance (umohs/cm) 27.2 24.3 24.1 18.7
Dissolved Oxygen (mg/L) 0.68 57 0.61 0.61 Turbidity=
OxidatiorvReduction Potential (mv) 357 361 374 392
Sample Characteristics S. Cloudy Cloudy Cloudy Cloudy
Sample ID: MW-17I
Sample 1ime: Start 1010 Stop
Sample Containers Filled
No. Type Preservative Analysis
4 40 ml voa HCL 6230D
4 40 ml voa H,so, TOG
2 40 ml crimp voa HCL Methane
1 500 ml plastic None Dissolved Metals
1 500 m I plastic None Chloride, nitrate, sulfate
1 500 ml plastic HNO, RCRA Metals (8) + Mn
Field Measurements of Sample:
pH 4.85 Cole-Parmer pH/Con 1 O Meter
Temp(" C) 20.7 Cole-Parmer pH/Con 10 Meter
Specific Conductance (umohs/cm) 29.7 Cole-Parmer pH/Con 1 O Meter
Dissohled Oxygen (mg/L) 0.77 YSI Model 95 Meter
OxidatiorvReduction Potential (mv) 41 Digi-Sense Model 5938 pH/ORP Meter
Ferrous Iron (mg/L) NIA Hach Ferrous Iron Kit
Turbidity (NTU) 47.3 Hach 2100P T urbidimeter
Sample Characteristics Clear
Weather Conditions: Sunny 70 degrees
Remarks:
I p IEDMONT GEOLOGIC, P.C,
35.3
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GROUNDWATER SAMPLING FORM
CLIENT: North Carolina State University PROJECT NAME: Lot 86
PROJECT LOCATION: Lot 86, Raleigh, NC PROJECT NO.: 2246
SAMPLING PERSONNEL: Matt James SAMPLING DATE: 5/30/02
John Harper SAMPLING METHOD: Bailer
Well 1.D.: MW-17 Well Type: Monitoring
Well Diameter (in.): 2 Reference Point: Top of Casing
Gauge Date: 5/20/02 Well Gauging Meter: ORS Probe
Depth to Water (ft.): 26.64 Depth to Bottom (ft.): 31.39
Water Column (ft.): 4.75 .16 x gaVft. = _0.8 __ gal
conversion factOf 1 well volume
Three Well Volumes = 2.4 gal
Purge Method: Grunclfos Purge Date: 5/29/02 I
Purge Volume (Qal.): 1 gal drv Purge lime: Start 1115 Stop 1130
Well Volumes Removed 1 2 3 4
pH 5.31
Temp. ("C) 21.1
Spec~ic Conductance (umohs/cm) 34.4
Dissolved Oxygen (mg/L) 1.01
Oxidation'Reduction Potential (mv) 3
Sample Characteristics Cloudy
Sample ID: MW-17
Sample Time: Start 0845 Stop
Sample Containers Filled
No. Type Preservative Analysis
4 40 ml voa HCL 6230D
4 40 ml voa H,so, TOG
2 40 ml crimp voa HCL Methane
1 500 ml plastic None Dissolved Metals
1 500 ml plastic None Chloride, nitrate, sulfate
1 500 ml plastic HNO3 RCRA Metals (8) + Mn
Field Measurements of Sample:
pH 4.88 Cole-Parmer pH/Con 1 o Meter
Temp(" C) 17.9 Cole-Parmer pH/Con 1 O Meter
Specific Conductance (umohs/cm) 41.3 Cole-Parmer pH/Con 10 Meter
Dissolved Oxygen (mg/L) 2.59 YSI Model 95 Meter
Oxidation'Reduction Potential (mv) 4 Digi-Sense Model 5938 pH/OAP Meter
Ferrous Iron (mg/L) N/A Hach Ferrous Iron Kit
Turbidity (NTU) 15 Hach 2100P Turbidimeter
Sample Characteristics Clear
Weather Conditions: P. Cloudy 74 degrees
Remarks:
P /EDMONT GEOLOGIC, P.C.
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GROUNDWATER SAMPLING FORM
CLIENT: North Carolina State University PROJECT NAME: Lot 86
PROJECT LOCATION: Lot 86, Raleigh, NC PROJECT NO.: 2246
SAMPLING PERSONNEL: Matt James SAMPLING DATE: 5/21/02
John Harper SAMPLING METHOD: Bailer
Well I.D.: MW-27 Well Type: Monitoring
Well Diameter (in.): 2 Reference Point: Top of Casing
Gauge Date: 5/20/02 Well Gauging Meter. ORS Probe
Depth to Water (ft.): 42.00 Depth to Bottom (ft.): 45.96
Water Column (ft.): 3.96 .16 x gaVft. = _0.63 __ gal
conversion factor 1 well volume
Three Well Volumes -1.9 gal
Purge Method: Bailer Purge Date: 5/21/02 I
Purge Volume (gal.\: 2.2 Orv Purge lime: Start 1727 Stop 1748
Well Volumes Removed 1 2 3 4
pH 4.96
Temp. ("C) 16.7
Specific Conductance (umohs/cm) 44.2
Dissolved Oxygen (mg/L) 2.2
Oxidation/Reduction Potential (mv) 296
Sample Characteristics Cloudy
Sample ID: MW-27
Sample Time: Start 1243 Stop
Sample Containers Filled
No. Type Preservative Analysis
4 40 ml voa HCL 6230D
4 40 ml voa H,so, TOC
2 40 ml crimp voa HCL Methane
1 500 m I plastic None Dissolved Metals
1 500 ml plastic None Chloride, nitrate, sulfate
1 500 m I plastic HNO3 RCRA Metals (8) + Mn
Field Measurements of Sample:
pH 4.92 Cole-Parmer pH/Con 10 Meter
Temp ("C) 16.7 Cole-Parmer pH/Con 1 0 Meter
Specific Conductance (umohs/cm) 44.8 Cole-Parmer pH/Con 10 Meter
Dissolved Oxygen (mg/L) 0.62 YSI Model 95 Meter
Oxidation/Reduction Potential (mv) 303 Digi-Sense Model 5938 pH/OAP Meter
Ferrous Iron (mg/L) N/A Hach Ferrous Iron Kit
Turbidity (NTU) 862 Hach 21 00P Turbidimeter
Sample Characteristics Clear
Weather Conditions:
Remarks: Dry after 2.2 gal; very slow to recharge.
I p IEDMONT G EOLOGIC, P.C.
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GROUNDWATER SAMPLING FORM
CLIENT: North Carolina State University PROJECT NAME: Lot 86
PROJECT LOCATION: Lot 86, Raleigh, NC PROJECT NO.: 2246
SAMPLING PERSONNEL: Matt James SAMPLING DATE: 5/22/02
John Harper SAMPLING METHOD: Bailer
Well 1.D.: MW-29 Well Type: Monitoring
Well Diameter (in.): 2 Reference Point: Top of Casing
Gauge Date: 5/20/02 Well Gauging Meter: ORS Probe
Depth to Water (ft.): 41.00 Depth to Bottom (ft.): 53.18
Water Column (ft.): 12.18 .16 x gaVft. = _1.9 __ gal
conversion factor 1 well volume
Three Well Volumes = 5.8 gal
Purge Method: Grundfos Purge Date: 5/21/02 I
Purge Volume (gal.): 2.2 Dry Purge Time: Start 1328 Stop 1348
Well Volumes Removed 1 2 3 4
pH 4.89
Temp. ("C) 16.7
Specific Conductance (umohs/cm) 33.7
Dissolved Oxygen (mg/L) 7.16
Oxidatior/Reduction Potential (mv) 287 Turbidity= 53.4
Sample Characteristics Clear
Sample ID: MW-29
Sample Time: Start 1111 Stop
Sample Containers Filled
No. Type Preservative Analysis
4 40 ml voa HCL 6230D
4 40 ml voa H,so, TOC
2 40 ml crimp voa HCL Methane
1 500 ml plastic None Dissolved Metals
1 500 ml plastic None Chloride, nitrate, sulfate
1 500 ml plastic HNO3 RCRA Metals (8) + Mn
Field Measurements of Sample:
pH 5.18 Cole-Parmer pH/Con 1 0 Meter
Temp (°C) 17.8 Cole-Parmer pH/Con 1 0 Meter
Spec~ic Conductance (umohs/cm) 33.2 Cole-Parmer pH/Con 10 Meter
Dissolved Oxygen (mg/L) 3.3 YSI Model 95 Meter
Oxidatior/Reduction Potential (mv) 319 Digi-Sense Model 5938 pH/OAP Meter
Ferrous Iron (mg/L) N/A Hach Ferrous Iron Kit
Turbidity (NTU) 9.28 Hach 21 00P Turbidimeter
Sample Characteristics Clear
Weather Conditions:
Remarks: Dry after 2.2 gal; waited 1 0 min. to restart purge; Dry after 0.3 gal.
•· PIEDMONT GEOLOGIC, P.C.
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GROUNDWATER SAMPLING FORM
CLIENT: North Carolina State University PROJECT NAME: Lot 86
PROJECT LOCATION: Lot 86, Raleigh, NC PROJECT NO.: 2246
SAMPLING PERSONNEL: Matt James SAMPLING DATE: Not sampled; see below.
John Harper SAMPLING METHOD: Bailer
Well l.D.: MW-33 Well Type: Monitoring
Well Diameter (in.): 2 Reference Point: Top of Casing
Gauge Date: 5/20/02 Well Gauging Meter: ORS Probe
Depth to Water (ft.): 35.47 Depth to Bottom (ft.): 62.45
Water Column (ft.): .16 x gaVft. = gal
conversion factOf 1 well volume
Three Well Volumes -gal
Purge Method: I
Purge Time: Start Stop
Well Volumes Removed 1 2 3 4
pH
Temp. ("C)
Specmc Conductance (umohs/cm)
Dissolved Oxygen (rng/L)
Oxidatior/Reduction Potential (mv)
Sample Characteristics
Sample ID:
Sample Time: Start Stop
Sample Containers Filled
No. Type Preservative Analysis
Field Measurements of Sample:
pH Cole-Parmer pH/Con 10 Meter
Temp(° C) Cole-Parmer pH/Con 1 O Meter
Specific Conductance ( umohs/cm) Cole-Parmer pH/Con 1 O Meter
Dissolved Oxygen (mg/L) YSI Model 95 Meter
Oxidatior/Reduction Potential (mv) Digi-Sense Model 5938 pH/OAP Meter
Ferrous Iron (mg/L) Hach Ferrous Iron Kit
Turbidity (NTU) Hach 2100P Turbidimeter
Sample Characteristics
Weather Conditions:
Remarks: Tubing for well purging is about 5 feet below top of casing; unable to remove tubing and unable to place
submersible pump down well for purging.
PIEDMONT G EOLOG/C, P.C.
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GROUNDWATER SAMPLING FORM
CLIENT: North Carolina Stale University PROJECT NAME: Lot 86
PROJECT LOCATION: Lot 86, Raleigh, NC PROJECT NO.: 2246
SAMPLING PERSONNEL: Matt James SAMPLING DATE: 5/20/02
John Harper SAMPLING METHOD: Bailer
Well l.D.: MW-34 s Well Type: Monitoring
Well Diameter (in.): 2 Reference Point: Top of Casing
Gauge Date: 5/20/02 Well Gauging Meter: ORS Probe
Depth to Water (ft.): 29.86 Depth to Bottom (ft.): 31.57
Water Column (ft.): 1.71 .16 x gaVft. = _0.3 __ gal
conversion factor 1 well volume
Three Well Volumes = 0.9 gal
Purge Method: Bailer Purge Date: 5/20/02
Purge Volume (gal.): 0.9 Purge Time: Start 1633 Stop 1650
Well Volumes Removed 1 2 3 4
pH 5.96 6.56 6.69
Temp. ('C) 16.5 15.2 17.1
Spedic Conductance (umohs/cm) 250.0 265 236
Dissolved Oxygen (mg/L) 1.72 3.71 4.52
Oxidation/Reduction Potential (mv) N/A N/A N/A
Sample Characteristics Turbid Turbid Turbid
Sample ID: MW-34 s ·
Sample lime: Start 1730 Stop
Sample Containers Filled
No. Type Preservative Analysis
4 40 ml voa HCL 6230D
4 40 ml voa H,so, TOC
2 40 ml crimp voa HCL Methane
1 500 ml plastic None Dissolved Metals
1 500 ml plastic None Chloride, nitrate, sulfate
1 500 ml plastic HNO3 RCRA Metals (8) + Mn
Field Measurements of Sample:
pH 6.69 Cole-Parmer pH/Con 1 0 Meter
Temp(' C) 17.1 Cole-Parmer pH/Con 10 Meter
Spedic Conductance (umohs/cm) 236 Cole-Parmer pH/Con 10 Meter
Dissolved Oxygen (mg/L) 4.52 YSI Model 95 Meter
Oxidation/Reduction Potential (mv) 238 Digi-Sense Model 5938 pH/OAP Meter
Ferrous Iron (mg/L) 0.6 Hach Ferrous Iron Kit
Turbidity (NTU) > 1,000 Hach 21 COP Turbidimeter
Sample Characteristics Turbid
Weather Conditions:
Remarks:
I p IEDMONT GEOLOGIC, P.C.
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GROUNDWATER SAMPLING FORM
CLIENT: North Carolina State University PROJECT NAME: Lot 86
PROJECT LOCATION: Lot 86, Raleigh, NC PROJECT NO.: 2246
SAMPLING PERSONNEL: Matt James SAMPLING DATE: 5/20/02
John Harper SAMPLING METHOD: Bailer
Well l.D.: MW-34 d Well Type: Monitoring
Well Diameter (in.): 2 Reference Point: Top of Casing
Gauge Date: 5/20/02 Well Gauging Meter: ORS Probe
Depth to Water (ft.): 27.58 Depth to Bottom (ft.): 52.16
Water Column (ft.): 24.6 .16 x gaVft. = _3.9 __ gal
conversion factor 1 well volume
Three Well Volumes = 11.8 gal
Purge Method: Grundfos Purge Date: 5/20/02
Purge Volume (gal.): 11.8 Purge lime: Start 1530 Stop 1615
Well Volumes Removed 1 2 3 4
pH 5.51 5.14 5.03
Temp. ("C) 18.2 17.9 16.9
Specific Conductance (umohs/cm) 40.9 44.0 43.4
Dissolved Oxygen (mg/L) 8.81 7.68 7.91
Oxidation/Reduction Potential (mv) N/A N/A N/A
Sample Characteristics Cloudy Cloudy S. Clear
Sample ID: MW-34 d
Sample Time: Start 1700 Stop
Sample Containers Filled
No. Type Preservative Analysis
4 40 ml voa HCL 6230D
4 40 ml voa H,so, TOC
2 40 ml crimp voa HCL Methane
1 500 m I plastic None Dissolved Metals
1 500 ml plastic None Chloride, nitrate, sulfate
1 500 m I plastic HNO3 RCRA Metals (8) + Mn
Field Measurements of Sample:
pH 5.60 Cole-Parmer pH/Con 1 o Meter
Temp (0 C) 14.9 Cole-Parmer pH/Con 10 Meter
Specific Conductance (umohs/cm) 57.7 Cole-Parmer pH/Con 1 O Meter
Dissolved Oxygen (mg/L) 7.25 YSI Model 95 Meter
Oxidation/Reduction Potential (mv) 306 Digi-Sense Model 5938 pH/ORP Meter
Ferrous Iron (mg/L) 0.6 Hach Ferrous Iron Kit
Turbidity (NTU) 399 Hach 2100P Turbidimeter
Sample Characteristics S. Clear
Weather Conditions:
Remarks: 3 feet below H2O table; dry after 0.5 gal; Dropped 5 feet; dry after 5 gal; Dropped 10 feet; dry after 3 gal;
Dropped to 4 feet from bottom. finished purge
I p IEDMONT GEOLOGIC, P.C.
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GROUNDWATER SAMPLING FORM
CLIENT: North Carolina State University PROJECT NAME: Lot 86
PROJECT LOCATION: Lot 86, Raleigh, NC PROJECT NO.: 2246
SAMPLING PERSONNEL: Matt James SAMPLING DATE: 5/22102
John Harper SAMPLING METHOD: Bailer
Well l.D.: MW-35 s Well Type: Monitoring
Well Diameter (in.): 2 Reference Point: Top of Casing
Gauge Date: 5/20/02 Well Gauging Meter: ORS Probe
Depth to Water (ft.): 44.77 Depth to Bottom (ft.): 52.15
Water Column (ft.): 7.38 .16 X gal/ft. = _1.2 __ gal
conversion factor 1 well volume
Three Well Volumes = 3.6 gal
Purge Method: Grundfos Purge Date: 5/21/02 I
Purge Volume (gal.\: 3.6 Purge lime: Start 1645 Stop 1701
Well Volumes Removed 1 2 3 4
pH 5.16 4.92 4.80
Temp. ("C) 15.9 16.0 16.1
Specific Conductance (umohs/cm) 32.7 30.5 27.8
Dissolved Oxygen (mg/L) 2.35 2.34 2.73
OxidatiorvReduction Potential (mv) 289 309 311
Sample Characteristics Cloudy Cloudy Silty
Sample ID: MW-35 s
Sample lime: Start 1223 Stop
Sample Containers Filled
No. Type Preservative Analysis
4 40 mlvoa HCL 6230D
4 40 ml voa H,so, TOG
2 40 ml crimp voa HCL Methane
1 500 ml plastic None Dissolved Metals
1 500 ml plastic None Chloride, nitrate, suttate
1 500 ml plastic HNO3 RCRA Metals (8) + Mn
Field Measurements of Sample:
pH 5.05 Cole-Pamier pH/Con 1 0 Meter
Temp (' C) 18.2 Cole-Pamier pH/Con 1 0 Meter
Specific Conductance (umohs/cm) 35.9 Cole-Parmer pH/Con 1 0 Meter
Dissolved Oxygen (mg/L) 0.71 YSI Model 95 Meter
OxidatiorvReduction Potential (mv) 292 Digi-Sense Model 5938 pH/ORP Meter
Ferrous Iron (mg/L) N/A Hach Ferrous Iron Kit
Turbidity (NTU) 862 Hach 21 00P Turbidimeter
Sample Characteristics Cloudy
Weather Conditions:
Remarks: Dry after 3 gal.
•. PIEDMONT GEOLOGIC, P.C.
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GROUNDWATER SAMPLING FORM
CLIENT: North Carolina State University PROJECT NAME: Lot 86
PROJECT LOCATION: Lot 86, Raleigh, NC PROJECT NO.: 2246
SAMPLING PERSONNEL: Matt James SAMPLING DATE: Not sampled; see below.
John Harper SAMPLING METHOD: Bailer
Well l.D.: MW-35 D Well Type: Monitoring
Well Diameter (in.): 2 Reference Point: Top of Casing
Gauge Date: 5/20/02 Well Gauging Meter: ORS Probe
Depth to Water (ft.): 45.80 Depth to Bottom (ft.):
Waler Column (fl.): .16 x gaVft. = gal
conversion factor 1 well volume
Three Well Volumes -gal
Purge Method: I
Purge lime: Start Stop
Well Volumes Removed 1 2 3 4
pH
Temp. ("C)
Specific Conductance (umohs/cm)
Dissolved Oxygen (mg/L)
OxidationlReduclion Potential (mv)
Sample Characteristics
Sample ID:
Sample Time: Start Stop
Sample Containers Filled
No. Type Preservative Analysis
Field Measurements of Sample:
pH Cole-Parmer pH/Con 1 0 Meler
Temp ("C) Cole-Parmer pH/Con 10 Meter
Specific Conductance (umohs/cm) Cole-Parmer pH/Con 1 0 Meter
Dissolved Oxygen (mg/L) YSI Model 95 Meter
OxidationlReduction Potential (mv) Digi-Sense Model 5938 pH/OAP Meter
Ferrous Iron (mg/L) Hach Ferrous Iron Kit
Turbidity (NTU) Hach 21 00P Turbidimeler
Sample Characteristics
Weather Conditions:
Remarks: Well obstructed about 20 feet below top of casing; unable to purge or sample.
I p IEDMONT GEOLOGIC, P.C.
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GROUNDWATER SAMPLING FORM
CLIENT: North Carolina State University PROJECT NAME: Lot 86
PROJECT LOCATION: Lot 86, Raleigh, NC PROJECT NO.: 2246
SAMPLING PERSONNEL: Matt James SAMPLING DATE: 5/24/02
John Harper SAMPLING METHOD: Bailer
Well I.D.: MW-36 s Well Type: Monitoring
Well Diameter (in.): 2 Reference Point: Top of Casing
Gauge Date: 5/20/02 Well Gauging Meter: ORS Probe
Depth to Water (ft.): 40.79 Depth to Bottom (ft.): 52.67
Water Column (ft.): 11.4 .16 X gal/ft. = -1.8 __ gal
conversion factor 1 well volume
Three Well Volumes = 5.5 gal
Purge Method: Grundfos Purge Date: 5/23/02
Purge Volume (!'.lal.): 5.5 Purge Time: Start 1815 Stop 1840
Well Volumes Removed 1 2 3 4
pH 4.86 4.76 4.67
Temp. ("C) 17.8 19.6 17.6
Specific Conductance (umohs/cm) 193 192.9 194.3
Dissolved Oxygen (mg/L) 0.80 0.82 0.80 Turbidity= >1,000
Oxidation/Reduction Potential (mv) 252 254 266
Sample Characteristics Turbid S. Clear S. Clear
Sample ID: MW-36 s
Sample Time: Start 1520 Stop
Sample Containers Filled
No. Type Preservative Analysis
4 40 mlvoa HCL 6230D
4 40 ml voa H,so, TOG
2 40 ml crimp voa HCL Methane
1 500 ml plastic None Dissolved Metals
1 500 ml plastic None Chloride, nitrate, sulfate
1 500 ml plastic HNO3 AGRA Metals (8) + Mn
Field Measurements of Sample:
pH 4.70 Cole-Parmer pH/Con 1 O Meter
Temp (°C) 22.1 Cole-Parmer pH/Con 10 Meter
Specific Conductance (umohs/cm) 188 Cole-Parmer pH/Con 1 O Meter
Dissolved Oxygen (mg/L) 0.65 YSI Model 95 Meter
Oxidation/Reduction Potential (mv) 1 Digi-Sense Model 5938 pH/OAP Meter
Ferrous Iron (mg/L) N/A Hach Ferrous Iron Kit
Turbidity (NTU) 10 Hach 2100P Turbidimeter
Sample Characteristics Clear
Weather Conditions:
Remarks: Very bad smell from well; Irritant
I p IEDMONT GEOLOGIC, P.C.
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GROUNDWATER SAMPLING FORM
CLIENT: North Carolina Stale University PROJECT NAME: Lot 86
PROJECT LOCATION: Loi 86, Raleigh, NC PROJECT NO.: 2246
SAMPLING PERSONNEL: Matt James SAMPLING DATE: 5/22/02
John Harper SAMPLING METHOD: Bailer
Well l.D.: MW-36 d Well Type: Monitoring
Well Diameter (in.): 2 Reference Point: Top of Casing
Gauge Date: 5/20/02 Well Gauging Meter: ORS Probe
Depth lo Water (ft.): 40.86 Depth to Bollom (ft.): 125
Water Column (ft.): 84.2 .16 x gaVft. = _13 __ gal
conversioo factrn 1 well volume
Three Well Volumes = 40 gal
Purge Method: Grundfos Purge Date: 5/21/02
Purge Volume (gal.): 40 Purge Time: Start 1517 Stop
Well Volumes Removed 1 2 3 4
pH 6.31 6.30 6.32
Temp. (°C) 19.9 18.5 18.5
Specmc Conductance (umohs/cm) 145 135.5 135.0
Dissolved Oxygen (mg/L) 0.95 1.11 0.97 Turbidity=
Oxidation/Reduction Potential (mv) 83 158 143
Sample Characteristics Clear Clear Clear
Sample ID: MW-36 d
Sample Time: Start 1151 Stop
Sample Containers Filled
No. Type Preservative Analysis
4 40 ml voa HCL 6230D
4 40 ml voa H,so, TOG
2 40 ml crimp voa HCL Methane
1 500 ml plastic None Dissolved Metals
1 500 ml plastic None Chloride, nitrate, suttate
1 500 ml plastic HNO3 RCRA Metals (8) + Mn
Field Measurements of Sample:
pH 6.12 Cole-Parmer pH/Con 1 0 Meter
Temp (0 C) 22.5 Cole-Parmer pH/Con 1 0 Meter
Specific Conductance (umohs/cm) 139.1 Cole-Parmer pH/Con 1 0 Meter
Dissolved Oxygen (mg/L) 1.05 YSI Model 95 Meter
1615
0.98
Oxidation'Reduction Potential (mv) 208 Digi-Sense Model 5938 pH/ORP Meter
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Ferrous Iron (mg/L) N/A
Turbidity (NTU) 8.98
Sample Characteristics Clear
Weather Conditions: Sunny 65
Remarks: Duplicate tabled MW-36 Dup; Blank labled FB-1
I p IEDMONT GEOLOGIC, P.C.
Hach Ferrous Iron Kit
Hach 21 00P Turbidimeter
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GROUNDWATER SAMPLING FORM
CLIENT: North Carolina State University PROJECT NAME: Lot 86
PROJECT LOCATION: Lot 86, Raleigh, NC PROJECT NO.: 2246
SAMPLING PERSONNEL: Matt James SAMPLING DATE: 5/30/02
John Harper SAMPLING METHOD: Bailer
Well l.D.: MW-36 s Well Type: Monitoring
Well Diameter (in.): 2 Reference Point: Top of Casing
Gauge Date: 5/20/02 Well Gauging Meter: ORS Probe
Depth to Water (ft.): 40.79 Depth to Bottom (ft.): 52.67
Water Column (ft.): 11.4 .16 X gaVft. = _1.8 __ gal
conversion factor 1 well volume
Three Well Volumes = 5.5 gal
Purge Method: Grundfos Purge Date: 5/29/02 I
Purge Volume (gal.\: 5.5 Purge lime: Start 1400 Stop 1430
Well Volumes Removed 1 2 3 4
pH 5.05 4.91 4.82
Temp. ("C) 18.7 17.9 17.5
Specific Conductance (umohs/cm) 177 177 181
Dissolved Oxygen (mg/L) 1.44 2.91 0.88
OxidatiorvReduction Potential (mv) 5 4 3
Sample Characteristics Turbid Turbid Cloudy
Sample ID: MW-36 s
Sample lime: Start 0930 Stop
Sample Containers Filled
No. Type Preservative Analysis
4 40 ml voa HCL 6230D
4 40 ml voa H,so, TOC
2 40 ml crimp voa HCL Methane
1 500 ml plastic None Dissolved Metals
1 500 ml plastic None Chloride, nitrate, suttate
1 500 ml plastic H_NO3 RCRA Metals (8) + Mn
Field Measurements of Sample:
pH 4.68 Cole-Parmer pH/Con 10 Meter
Temp(" C) 19.9 Cole-Parmer pH/Con 10 Meter
Specific Conductance (umohs/cm) 187 Cole-Parmer pH/Con 1 O Meter
Dissolved Oxygen (mg/L) 1.85 YSI Model 95 Meter
OxidatiorvReduction Potential (mv) 4 Digi-Sense Model 5938 pH/OAP Meter
Ferrous Iron (mg/L) N/A Hach Ferrous Iron Kit
Turbidity (NTU) -31.3 Hach 2100P Turbidimeter
Sample Characteristics Clear
Weather Conditions:
Remarks:
1 · PIEDMONT GEOLOGIC, P.C.
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GROUNDWATER SAMPLING FORM
CLIENT: North Carolina State University PROJECT NAME: Lot 86
PROJECT LOCATION: Lot 86, Raleigh, NC PROJECT NO.: 2246
SAMPLING PERSONNEL: Matt James SAMPLING DATE: 5/24102
John Harper SAMPLING METHOD: Bailer
Well I.D.: MW-37 Well Type: Monitoring
Well Diameter (in.): 2 Reference Point: Top of Casing
Gauge Date: 5/20/02 Well Gauging Meter: ORS Probe
Depth to Water (ft.): 39.11 Depth to Bottom (ft.): 50.43
Water Column (ft.): 39.11 .16 x gaVft. = _1.8 __ gal
conversion factor 1 well volume
Three Well Volumes = 5.4 gal
Purge Method: Grundfos Purge Date: 5/23/02 I
Purge Volume (gal.\: 5.4 Purge Time: Start 1650 Stop 1710
Well Volumes Removed 1 2 3 4
pH 4.72 4.69 4.68
Temp. (°C) 17.3 16.8 16.9
Specific Conductance (umohs/cm) 83.3 66.6 79.6
Dissolved Oxygen (mg/L) 1.08 1.05 0.97 Turbid= >1,000
Oxidation/Reduction Potential (mv) -14 74 170
Sample Characteristics Turbid Turbid Turbid
Sample ID: MW-37
Sample Time: Start 1300 Stop
Sample Containers Filled
No. Type Preservative Analysis
4 40 ml voa HCL 6230D
4 40 mlvoa H,so, TOC
2 40 ml crimp voa HCL Methane
1 500 ml plastic None Dissolved Metals
1 500 ml plastic None Chloride, nitrate, sulfate
1 500 ml plastic HNO3 RCRA Metals (8) + Mn
Field Measurements of Sample:
pH 5.18 Cole-Parmer pH/Con 1 0 Meter
Temp(° C) 22.1 Cole-Parmer pH/Con 1 0 Meter
Specific Conductance (umohs/cm) 139 Cole-Parmer pH/Con 1 0 Meter
Dissolved Oxygen (mg/L) 0.18 YSI Model 95 Meter
Oxidation/Reduction Potential (mv) · -2 Digi-Sense Model 5938 pH/ORP Meter
Ferrous Iron (mg/L) N/A Hach Ferrous lron Kit
Turbidity (NTU) 45.6 Hach 21 00P Turbidimeter
Sample Characteristics Clear
Weather Conditions: Sunny 85
Remarks: MS-MSD @ 1340
'I p IEDMONT GEOLOGIC, P.C.
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GROUNDWATER SAMPLING FORM
CLIENT: North Carolina State University PROJECT NAME: Lot 86
PROJECT LOCATION: Lot 86, Raleigh, NC PROJECT NO.: 2246
SAMPLING PERSONNEL: Matt James SAMPLING DATE: 5/30/02
John Harper SAMPLING METHOD: Bailer
Well I.D.: MW-37 Well Type: Monitoring
Well Diameter (in.): 2 Reference Point: Top of Casing
Gauge Date: 5/20/02 Well Gauging Meter: ORS Probe
Depth to Water (ft.): 39.11 Depth to Bottom (ft.): 50.43
Water Column (ft.): 39.11 .16 x gaVft. = _1.8 __ gal
conversion factor 1 well volume
Three Well Volumes = 5.4 gal
Purge Method: Grundfos Purge Date: 5/29/02 I
Purge Volume (gal.): 3.0 Drv Purge Time: Start 1145 Stop 1215
Well Volumes Removed 1 2 3 4
pH 4.95
Temp. (°C) 19.8
Spec~ic Conductance (umohs/cm) 110.2
Dissolved Oxygen (mg/L) 1.10
Oxidation'Reduction Potential (mv) 4
Sample Characteristics Turbid
Sample ID: W/N-37
Sample Time: Start 0900 Stop
Sample Containers Filled
No. Type Preservative Analysis
4 40 ml voa HCL 6230D
4 40 mlvoa H,so, TOG
2 40 ml crimp voa HCL Methane
1 500 ml plastic None Dissolved Metals
1 500 ml plastic None Chloride, nitrate, sulfate
1 500 ml plastic HNO3 RCRA Metals (8) + Mn
Field Measurements of Sample:
pH 4.74 Cole-Parmer pH/Con 1 o Meter
Temp (0 C) 18.0 Cole-Parmer pH/Con 1 O Meter
Specnic Conductance (umohs/cm) 127.5 Cole-Parmer pH/Con 10 Meter
Dissolved Oxygen (mg/L) 2.52 YSI Model 95 Meter
OxidatiorvReduction Potential (mv) 4 Digi-Sense Model 5938 pH/ORP Meter
Ferrous Iron (mg/L) N/A Hach Ferrous Iron Kit
Turbidity (NTU) 27.4 Hach 2100P Turbidimeter
Sample Characteristics Clear
Weather Conditions: P. Sunny 77
Remarks:
I p IEDMONT GEOLOGIC, P.C.
GROUNDWATER SAMPLING FORM
CLIENT: North Carolina State University PROJECT NAME: Lot 86
PROJECT LOCATION: Lot 86, Raleigh, NC PROJECT NO.: 2246
SAMPLING PERSONNEL: Matt James SAMPLING DATE: 5/23/02
John Harper SAMPLING METHOD: Bailer
Well I.D.: MW-38 Well Type: Monitoring
Well Diameter (in.): 2 Reference Point: Top of Casing
Gauge Date: 5/20/02 Well Gauging Meter: ORS Probe
Depth to Water (ft.): 42.65 Depth to Bottom (ft.): 110
Water Column (ft.): 67.35 .16 x gaVft. = _11 __ gal
conversion factor 1 well volume
Three Well Volumes = 33 gal
Purge Method: Grundfos Purge Date: 5/22/02
Purge Volume (gal.): 18 Orv Purge lime: Start 1509 Stop 1540
Well Volumes Removed 1 2 3 4
pH 8.37 8.22
Temp. ("C) 17.5 179.0
Specific Conductance (umohs/cm) 140.5 168.6
Dissolved Oxygen (mg/L) 0.53 0.35
OxidatiorvReduction Potential (mv) 184 64 Turbidity= 3.50
Sample Characteristics Clear Clear
Sample ID: MW-38
Sample nme: Start 0910 Stop
Sample Containers Filled
No. Type Preservative Analysis
4 40 mlvoa HCL 6230D
4 40 ml voa H,so, TOC
2 40 ml crimp voa HCL Methane
1 500 ml plastic None Dissolved Metals
1 500 ml plastic None Chloride, nitrate, sulfate
1 500 ml plastic HNO3 AGRA Metals (8) + Mn
Field Measurements of Sample:
pH 6.75 Cole-Parmer pH/Con 10 Meter
Temp(° C) 18.9 Cole-Parmer pH/Con 10 Meter
Specffic Conductance (umohs/cm) 176.2 Cole-Parmer pH/Con 10 Meter
Dissolved Oxygen (mg/L) 1.47 YSI Model 95 Meter
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Ferrous Iron (mg/L) N/A Hach Ferrous Iron Kit
Turbidity (NTU) 1.72 Hach 2100P Turbidimeter
Sample Characteristics Clear
Weather Conditions:
I Remarks: 13 gal Dry; Wait 5 min. to restart purge; Dry after 15; Wait 5 min.; 18 gal dry.
I p IEDMONT GEOLOGIC, P.C.
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GROUNDWATER SAMPLING FORM
CLIENT: North Carolina State University PROJECT NAME: Lot 86
PROJECT LOCATION: Lot 86, Raleigh, NC PROJECT NO.: 2246
SAMPLING PERSONNEL: Matt James SAMPLING DATE: 5/20/02
John Harper SAMPLING METHOD: Bailer
Well I.D.: MW-40 Well Type: Monitoring
Well Diameter (in.): 2 Reference Point: Top of Casing
Gauge Date: 5/20/02 Well Gauging Meter: ORS Probe
Depth to Water (ft.): 29.63 Depth to Bottom (ft.): 37.24
Water Column (ft.): 7.61 .16 X gaVft. = _1.2 __ gal
conversion factor 1 well volume
Three Well Volumes = 3.7 gal
Purge Method: Grundfos Purge Date: 5/21/02 I
Purqe Volume (gal.): 3.7 Purge lime: Start 1432 Stop 1447
Well Volumes Removed 1 2 3 4
pH 4.50 4.42 4.35
Temp. ("C) 15.7 16.1 15.9
Specific Conductance (umohs/cm) 36.7 33.1 31.0
Dissolved Oxygen (mg/L) 4.75 4.66 4.65
Oxidation/Reduction Potential (mv) 272 285 297 Turbidity= 727.00
Sample Characteristics Turbid Clear S. Clear
Sample ID: MW-40
Sample Time: Start 1131 Stop
Sample Containers Filled
No. Type Preservative Analysis
4 40 ml voa HCL 6230D
4 40 ml voa H2SO4 TOC
2 40 ml crimp voa HCL Methane
1 500 ml plastic None Dissolved Metals
1 500 m I plastic None Chloride, nitrate, sulfate
1 500 m I plastic HNO3 RCRA Metals (8) + Mn
Field Measurements of Sample:
pH 4.81 Cole-Parmer pH/Con 1 0 Meter
Temp(' C) 16.4 Cole-Parmer pH/Con 1 0 Meter
Specific Conductance (umohs/cm) 37.8 Cole-Parmer pH/Con 10 Meter
Dissolved Oxygen (mg/L) 2.53 YSI Model 95 Meter
Oxidation/Reduction Potential (mv) 269 Digi-Sense Model 5938 pH/ORP Meter
Ferrous Iron (mg/L) N/A Hach Ferrous Iron Kit
Turbidity (NTU) 10.8 Hach 21 00P Turbidimeter
Sample Characteristics Clear
Weather Conditions: Sunny 65
Remarks: 13 gal Dry; Wait 5 min. to restart purge; Dry after 15; Wait 5 min.; 18 gal dry.
. • PIEDMONT GEOLOGIC, P.C.
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GROUNDWATER SAMPLING FORM
CLIENT: North Carolina State University PROJECT NAME: Lot 86
PROJECT LOCATION: Lot 86, Raleigh, NC PROJECT NO.: 2246
SAMPLING PERSONNEL: Matt James SAMPLING DATE: 5/20/02
John Harper SAMPLING METHOD: Bailer
Well I.D.: MW-41 Well Type: Monitoring
Well Diameter (in.): 2 Reference Point: Top of Casing
Gauge Date: 5/20/02 Well Gauging Meter: ORS Probe
Depth to Water (ft.): 26.14 Depth to Bollom (ft.): 28.19
Water Column (ft.): 2.05 .16 x gaVft. = _0.33 __ gal
conversion factor 1 well volume
Three Well Volumes = 1.0 gal
Purge Method: Bailer Purge Date: 5/21/02
Purge Volume (gal.): 1.5 Purge Time: Start 1108 Stop 1141
Well Volumes Removed 1 2 3 4
pH 4.52 4.56 4.48
Temp. ('C) 16.8 17.1 16.8
Specific Conductance (umohs/cm) 34.0 36.2 43.6
Dissolved Oxygen (mg/L) 6.42 4.60 4.58
Oxidation/Reduction Potential (mv) 318 337 351 Turbidity= >1,000
Sample Characteristics Turbid Cloudy Turbid
Sample ID: MW-41
Sample Time: Start 0928 Stop
Sample Containers Filled
No. Type Preservative Analysis
4 40 ml voa HCL 6230D
4 40 ml voa H,so, TOC
2 40 ml crimp voa HCL Methane
1 500 ml plastic None Dissolved Metals
1 500 ml plastic None Chloride, nitrate, suifate
1 500 ml plastic HNO, RCRA Metals (8) + Mn
Field Measurements of Sample:
pH 4.79 Cole-Parmer pH/Con 1 0 Meter
Temp(° C) 15.7 Cole-Parmer pH/Con 10 Meter
Specific Conductance (umohs/cm) 42.0 Cole-Parmer pH/Con 10 Meter
Dissolved Oxygen (mg/L) 2.17 YSI Model 95 Meler
Oxidation/Reduction Potential (mv) 333
.
Digi-Sense Model 5938 pH/ORP Meler
Ferrous Iron (mg/L) N/A Hach Ferrous Iron Kit
Turbidity (NTU) 81 Hach 21 00P Turbidimeter
Sample Characteristics Clear
Weather Conditions: Sunny 60
Remarks:
I p IEDMONT GEOLOGIC, P.C.
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GROUNDWATER SAMPLING FORM
CLIENT: North Carolina State University PROJECT NAME: Lot 86
PROJECT LOCATION: Lot 86, Raleigh, NC PROJECT NO.: 2246
SAMPLING PERSONNEL: Matt James SAMPLING DATE: 5/20/02
John Harper SAMPLING METHOD: Baller
Well l.D.: MW-41I Well Type: Monitoring
Well Diameter (in.): 2 Reference Point: Top of Casing
Gauge Date: 5/20/02 Well Gauging Meter: ORS Probe
Depth to Water (ft.): 26.16 Depth to Bottom (ft.): 60.14
Water Column (ft.):33.98 .16 x gaVft. = _5.4 __ gal
conversion factor 1 well volume
Three Well Volumes -16 gal
Purge Method: Grundfos Purae Date: 5/21 /02 I
Purge Volume (gal.): 16 Purge Time: Start 1111 Stop 1136
Well Volumes Removed 1 2 3 4
pH 4.54 4.37 4.44
Temp. (0C) 17.6 17.4 18.6
Specific Conductance (umohs/cm) 28.7 27.6 28.3
Dissolved Oxygen (mg/L) 6.02 5.13 5.12
Oxidation/Reduction Potential (mv) 325 337 336 Turbidity= 448.00
Sample Characteristics Clear Clear S. Cloudy
Sample ID: MW-41I
Sample Time: Start 0953 Stop
Sample Containers Filled
No. Type Preservative Analysis
4 40 ml voa HCL 6230D
4 40 ml voa H,so, TOG
2 40 ml crimp voa HCL Methane
1 500 ml plastic None Dissolved Metals
1 500 ml plastic None Chloride, nitrate, sulfate
1 500 ml plastic HNO3 RCRA Metals (8) + Mn
Field Measurements of Sample:
pH 4.90 Cole-Parmer pH/Con 1 O Meter
Temp(' C) 16.1 Cole-Parmer pH/Con 10 Meter
Specific Conductance (umohs/cm) 30.40 Cole-Parmer pH/Con 10 Meter
Dissolved Oxygen (mg/L) 2.00 YSI Model 95 Meter
Oxidation/Reduction Potential (mv) 327 Digi-Sense Model 5938 pH/ORP Meter
Ferrous Iron (mg/L) N/A Hach Ferrous Iron Kit
Turbidity (NTU) 73.0 Hach 2100P Turbidimeter
Sample Characteristics Clear
Weather Conditions: Sunny 60
Remarks:
• . PIEDMONT GEOLOGIC, P.C.
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GROUNDWATER SAMPLING FORM
CLIENT: North Carolina State University PROJECT NAME: Lot 86
PROJECT LOCATION: Lot 86, Raleigh, NC PROJECT NO.: 2246
SAMPLING PERSONNEL: Matt James SAMPLING DATE: 5/20/02
John Harper SAMPLING METHOD: Bailer
Well I.D.: MW-42I Well Type: Monitoring
Well Diameter (in.): 2 Reference Point: Top of Casing
Gauge Date: 5/20/02 Well Gauging Meter: ORS Probe
Depth to Water (ft.): 24.13 Depth to Bottom (ft.): 52.08
Water Column (ft.):27.95 .16 x gaVft. = _4.5 __ gal
conversion factOf 1 well volume
Three Well Volumes = 13 gal
Purge Method: Grundfos Purge Date: 5/21 /02 I
Purge Volume (gal.): 15 Purge Time: Start 1150 Stop 1208
Well Volumes Removed 1 2 3 4
pH 5.59 5.80 5.91
Temp. (°C) 16.9 16.9 16.9
Specific Conductance (umohs/cm) 126.3 126.6 126.2
Dissolved Oxygen (mg/L) 0.52 0.42 0.40
Oxidation/Reduction Potential (mv) 130 76.0 64.0 Turbidity= 138.00
Sample Characteristics Cloudy Cloudy S. Cloudy
Sample ID: MW-42I
Sample Time: Start 1023 Stop
Sample Containers Filled
No. Type Preservative Ana~sis
4 40 ml voa HCL 6230D
4 40 ml voa H,so, TOC
2 40 ml crimp voa HCL Methane
1 500 ml plastic None Dissolved Metals
1 500 m I plastic None Chloride, nitrate, sulfate
1 500 ml plastic HNO, RCRA Metals (8) + Mn
Field Measurements of Sample:
pH 5.65 Cole-Parmer pH/Con 10 Meter
Temp (°C) 16.2 Cole-Parmer pH/Con 1 o Meter
Specific Conductance (umohs/cm) 115.4 Cole-Parmer pH/Con 10 Meter
Dissolved Oxygen (mg/L) 1.39 YSI Model 95 Meter
Oxidation/Reduction Potential (mv) 224 Digi-Sense Model 5938 pH/ORP Meter
Ferrous Iron (mg/L) NIA Hach Ferrous Iron Kit
Turbidity (NTU) 128.0 Hach 21 00P Turbidimeter
Sample Characteristics Clear
Weather Conditions: Sunny 60
Remarks:
11 PIEDMONT G EOLOG/C, P.C.
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GROUNDWATER SAMPLING FORM
CLIENT: North Carolina State University PROJECT NAME: Lot 86
PROJECT LOCATION: Lot 86, Raleigh, NC PROJECT NO.: 2246
SAMPLING PERSONNEL: Matt James SAMPLING DATE: 5/22/02
John Harper SAMPLING METHOD: Bailer
Well l.D.: MW-43 Well Type: Monitoring
Well Diameter (in.): 2 Reference Point: Top of Casing
Gauge Date: 5/20/02 Well Gauging Meter: ORS Probe
Depth to Water (ft.): 50.25 Depth to Bottom (ft.): 60.82
Water Column (ft.): 10.57 .16 x gaVft. = -1.7 __ gal
conversion factor 1 well volume
Three Well Volumes = 5.1 gal
Purge Method: Grundfos Purge Date: 5/21/02
Purge Volume (gal.\: 6.9 Purge Time: Start 0908 Stop 0928
Well Volumes Removed 1 2 3 4
pH 4.53 4.53 4.42 4.44
Temp. (°C) 16.6 16.8 17.5 17.2
Specrtic Conductance (umohs/cm) 41.6 38.7 33.1 33.3
Dissolved Oxygen (mg/L) 8.20 8.02 8.84 9.09
Oxidation/Reduction Potential (mv) 347 338.0 291.0 306 Turbidity= 460.00
Sample Characteristics Turbid Turbid Turbid Turbid
Sample ID: MW-43
Sample Time: Start 0741 Stop
Sam pie Containers Filled
No. Type Preservative Analysis
4 40 mlvoa HCL 6230D
4 40 ml voa H,so, TOC
2 40 ml crimp voa HCL Methane
1 500 ml plastic None Dissolved Metals
1 500 ml plastic None Chloride, nitrate, sulfate
1 500 ml plastic HNO3 RCRA Metals (8) + Mn
Field Measurements of Sample:
pH 5.62 Cole-Parmer pH/Con 1 O Meter
Temp(° C) 13.4 Cole-Parmer pH/Con 1 o Meter
Specific Conductance (umohs/cm) 48.7 Cole-Parmer pH/Con 10 Meter
Dissolved Oxygen (mg/L) 5.62 YSI Model 95 Meter
Oxidation/Reduction Potential (mv) 233 Digi-Sense Model 5938 pH/ORP Meter
Ferrous Iron (mg/L) NIA Hach Ferrous Iron Kit
Turbidity (NTU) 404 Hach 2100P Turbidimeter
Sample Characteristics S. Cloudy
Weather Conditions: Sunny 60
Remarks: Dry after 2.o gal; Dry after 5.2 gal. Dry after 6.9 gal.
:I p IEDMONT GEOLOGIC, P.C.
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GROUNDWATER SAMPLING FORM
CLIENT: North Carolina State University PROJECT NAME: Lot 86
PROJECT LOCATION: Lot 86, Raleigh, NC PROJECT NO.: 2246
SAMPLING PERSONNEL: Matt James SAMPLING DATE: 7/16/02
John Harper SAMPLING METHOD: Bailer
Well I.D.: MW-43 Well Type: Monitoring
Well Diameter (in.): 2 Reference Point: Top of Casing
Gauge Date: 5/20/02 Well Gauging Meter: ORS Probe
Depth to Water (ft.): 50.69 Depth to Bottom (ft.): 63.00
Water Column (ft.): 12.31 .16 X gaVft. = -2.0 __ gal
conversion factor 1 well volume
Three Well Volumes = 6.0 gal
Purge Method: Grundfos Purge Date: 7/16/02 I
Purge Volune: 6.0 Purge Time: Start 0920 Stop 0950
Well Volumes Removed 1 2 3 4
pH 5.47 5.09 4.70
Temp. ("C) 19.0 18.8 19.0
Specific Conductance (umohs/cm) 43.7 37.7 30.8
Dissolved Oxygen (mg/L) 7.77 7.75 7.62
Oxidation/Reduction Potential (mv) NM NM NM
Sample Characteristics Turbid S. Cloudy S. Clear
Sample ID: MW-43
Sample Time: Start 1030 Stop
Sample Containers Filled
No. Type Preservative Analysis
4 40 ml voa HCL 6230D
Field Measurements of Sample:
pH 4.77 Cole-Parmer pH/Con 1 0 Meter
Temp(° C) 18.9 Cole-Parmer pH/Con 1 0 Meter
Spectlic Conductance (umohs/cm) 32.1 Cole-Parmer pH/Con 1 0 Meter
Dissolved Oxygen (mg/L) 7.36 YSI Model 95 Meter
Oxidation/Reduction Potential (mv) NM Digi-Sense Model 5938 pH/ORP Meter
Ferrous Iron (mg/L) NM Hach Ferrous Iron Kit
Turbidity (NTU) NM Hach 21 00P Turbidimeter
Sample Characteristics Cloudy
Weather Conditions: Sunny 88
Remarks: Collected field blank (FB-3) at 1020; collected MW-43DUP at 1040; collected MW-43 MS/MSD at 1050.
PIEDMONT GEOLOGIC, P.C.
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GROUNDWATER SAMPLING FORM
CLIENT: North Carolina State University PROJECT NAME: Lot 86
PROJECT LOCATION: Lot 86, Raleigh, NC PROJECT NO.: 2246
SAMPLING PERSONNEL: Matt James SAMPLING DATE: 5/20/02
John Harper SAMPLING METHOD: Bailer
Well l.D.: MW-45 Well Type: Monitoring
Well Diameter (in.): 2 Reference Point: Top of Casing
Gauge Date: 5/20/02 Well Gauging Meter: ORS Probe
Depth to Water (ft.): 50.16 Depth to Bottom (ft.): 64.50
Water Column (ft.): 14.34 .16 x gaVft. = -2.3 __ gal
conversion factor 1 well volume
Three Well Volumes = 6.9 gal
Purge Method: Grundfos Purge Date: 5/21/02 I
Purge Volume (gal.): 6.9 Purge Time: Start 1021 Stop 1052
Well Volumes Removed 1 2 3 4
pH 4.33 4.35 4.38
Temp. ('C) 16.0 19.0 18.9
Specific Conductance (umohs/cm) 37.1 36.4 35.0
Dissolved Oxygen (mg/L) 6.61 6.15 5.75
Oxidation/Reduction Potential (mv) 320 290 298 Turbidity= >1,000
Sample Characteristics Turbid Turbid Turbid
Sample ID: MW-45
Sample Time: Start 0821 Stop
Sample Containers Filled
No. Type Preservative Analysis
4 40 ml voa HCL 6230D
4 40 ml voa H,so, TOG
2 40 ml crimp voa HCL Methane
1 500 ml plastic None Dissolved Metals
1 500 ml plastic None Chloride, nitrate, sulfate
1 500 ml plastic HNO3 AGRA Metals (8) + Mn
Field Measurements of Sample:
pH 5.03 Cole-Parmer pH/Con 10 Meter
Temp(° C) 13.5 Cole-Parmer pH/Con 10 Meter
Specific Conductance (umohs/cm) 37.4 Cole-Parmer pH/Con 10 Meter
Dissolved Oxygen (mg/L) 4.45 YSI Model 95 Meter
Oxidation/Reduction Potential (mv) 300 Digi-Sense Model 5938 pH/OAP Meter
Ferrous Iron (mg/L) N/A Hach Ferrous Iron Kit
Turbidity (NTU) 10 Hach 2100P Turbidimeter
Sample Characteristics S. Cloudy
Weather Conditions: Sunny 60
Remarks: Dry after 3.5 gal; Dry after 5.2 gal. Dry after 7.0 gal.
I. p IEDMONT GEOLOGIC, P.C.
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GROUNDWATER SAMPLING FORM
CLIENT: North Carolina State University PROJECT NAME: Lot 86
PROJECT LOCATION: Lot 86, Raleigh, NC PROJECT NO.: 2246
SAMPLING PERSONNEL: Matt James SAMPLING DATE: 5/20/02
John Harper SAMPLING METHOD: Bailer
Well I.D.: MW-46 Well Type: Monitoring
Well Diameter (in.): 2 Reference Point: Top of Casing
Gauge Date: 5/20/02 Well Gauging Meter: ORS Probe
Depth to Water (ft.): 57.16 Depth to Bottom (ft.): 61.20
Water Column (ft.): 4.04 .16 x gaVft. = -0.65 __ gal
conversion factor 1 well volume
Three Well Volumes = 1.9 gal
Purge Method: Bailer Purge Date: 5/21 /02 I
Purge Volume (gal.): 2.0 Purge lime: Start 0946 Stop 1016
Well Volumes Removed 1 2 3 4
pH 4.43 4.13 4.18
Temp. ('C) 15.3 15.2 15.3
Specific Conductance (umohs/cm) 55.0 59.7 53.9
Dissolved Oxygen (mg/L) 8.02 7.62 7.60
Oxidation/Reduction Potential (mv) 379 376 375 Turbidity= >1,000
Sample Characteristics Silty Cloudy Cloudy
Sample ID: MW-46
Sample Time: Start 0759 Stop
Sample Containers Filled
No. Type Preservative Analysis
4 40 ml voa HCL 6230D
4 40 mlvoa H,so, TOG
2 40 ml crimp voa HCL Methane
1 500 ml plastic None Dissolved Metals
1 500 ml plastic None Chloride, nitrate, sulfate
1 500 ml plastic HNO3 RCRA Metals (8) + Mn
Field Measurements of Sample:
pH 4.78 Cole-Parmer pH/Con 1 O Meter
Temp(' C) 14.0 Cole-Parmer pH/Con 10 Meter
Spec~ic Conductance (umohs/cm) 53.3 Cole-Parmer pH/Con 1 O Meter
Dissolved Oxygen (mg/L) 4.89 YSI Model 95 Meter
Oxidation/Reduction Potential (mv) 302 Digi-Sense Model 5938 pH/ORP Meter
Ferrous Iron (mg/L) N/A Hach Ferrous Iron Kit
Turbidity (NTU) >1,000 Hach 2100P Turbidimeter
Sample Characteristics S. Cloudy
Weather Conditions: Sunny 85
Remarks:
I p IEDMONT GEOLOGIC, P.C.
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I PIEDMONT GEOLOGIC, P.C.
Report of Results: May-July 2002 Groundwater Sampling and Analysis Event
North Carolina State University, Lot 86 Site
October 22, 2002
APPENDIXB
SUMMARY LABORATORY REPORTS
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ace Analytical™
www.pacelabs.com
June 29, 2002
Hr. Pete Dressel
Piedmont Geolog_ic
6003 Chapel _Hill Road
Suite 113 ,·
RaleighiNC 27607
/ . /./_,_,_ ,.
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
/. I ,,·. ,· /;,'.· RE:
-"'./' .,. .
Lab Project Number: ·9233015
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Client Project ID: NCSU Lot 86/2246
Dear Hr. Dressel:
Enclosed are the analytical results for sample(s) received by the laboratory Hay 21, 2002through Hay 30, 2002
Results reported herein conform to the most current NELAC standards, where applicable, unless otherwise narrated
in the body of the report.
If you have any questions concerning this report. please feel free to contact me.
Sincerely,
~~fdJ
Kristi Tart
[e-mail]
Project Manager
Enclosures
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
.-ZJ~. ?i□~aC\t
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
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ace Analytical™
www.pacelabs.com
. !
Lab Sample No: 922276217
Client Sample IO: MW-34S .:;;_-
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Lab Project Number: 9233015
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-001
Matrix: Water
Date Collected: 05/20/02 17:30
Date Received: 05/21/02 14:10
Parameters Results Units Report Limit .J1L --'A"'n,,,a.,_ly,.,,z"'ed,___,,B.,_y CAS No.
Metals
Metals by Trace ICP
Arsenic
Barium
Cadmium
Chromium
Lead ,-·' _;-·
.,,_,, ·-•'
Prep/Method: EPA 3010 I EPA 6010
ND mg/l 0.0050 1.0 06/04/02 18:50 DJR 7440·38-2
0.037 mg/l 0.0050 1.0 06/04/02 18:50 DJR 7440-39-3
ND mg/l 0.0010 1.0 06/04/02 18:50 DJR 7440-43-9
ND mg/l 0.0020 1.0 06/04/02 18:50 DJR 7440-47-3
ND mg/l 0.0050 1.0 06/04/02 18:50 DJR 7439-92-1
Mangariese
I /S~le'~ium ., ,
__ ,f''. ,,.---Silver
~-~ .:-·.. Date Digested
0. 0089 mg/l
ND mg/l
ND mg/l
0.0050 1.0 06/04/02 18:50 DJR 7439-96-5
0.0050 1.0 06/04/02 18:50 DJR 7782-49-2
0.0020 1,0 06/04/02 18:50 DJR 7440-22-4
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Mercury, CVMS, in Water
Mercury
Wet Chemistry
Ion Chromatography
Chloride
Nitrate
Sulfate
Alkalinity, Total
Alkalinity, Total
GC Volatiles
GC voes in Water
Benzene
Bromobenzene
Bromochlorornethane
Bromodichloromethane
Bromoform
Bromomethane
n-8utylbenzene
sec-Butyl benzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
05/22/02
Method: EPA 7470
ND mg/l 0.00020 1.0 06/03/02 LBG 7439-97-6
Method: EPA 300.0
18. mg/l
0.25 mg/l
1.0
0.10
1.0
1.0 05/21/02
1. 0 05/21/02
1.0 05/21/02
CBJ 16887-00-6
CBJ
18, mg/l CBJ
Method: EPA 310.1
120 mg/l 1.0 1.0 05/21/02 HEH
Method: SM 62300
ND ug/l 0.50 1.0 05/30/02 08:52 KTV
ND ug/l 0.50 1.0 05/30/02 08:52 KTV
ND ug/l 0.50 1.0 05/30/02 08:52 KTV
ND ug/l 0.50 1.0 05/30/02 08:52 KTV
ND ug/l 0.50 1.0 05/30/02 08:52 KTV
ND ug/l 0,50 ( 1.0 05/30/02 08:52 KTV
ND ug/l 1.0 1.0 05/30/02 08:52 KTV
ND ug/l 0.50 1.0 05/30/02 08:52 KTV
ND ug/l 0.50 1.0 05/30/02 08:52 KTV
ND ug/l 0.50 1.0 05/30/02 08:52 KTV
ND ug/l 0.50 1.0 05/30/02 08:52 KTV
ND ug/l 0.50 1.0 05/30/02 08:52 KTV
ND ug/l 0.50 1.0 05/30/02 08:52 KTV
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,,,.,~ .. ,, /,1 'I~",. .. " ... I1neac11
71-43-2
108-86-1
74.97.5
75-27-4
75-25-2
74-83-9
104-51-8
135-98-8
98-06-6
56-23-5
108-90-7
75-00-3
67-66-3
Page: 1
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
ace Analytical™
www.pacelabs.com
Lab Sample No: 922276217
Client Sample ID: MW-34S
Parameters
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1.2-Dibromo-3-chioropropane
Di bromochlorometh;ne
1.2-Dibromo~th~·ne (EDB}
Dibro.mo~eth;ne
1.2'0ichlorobenzene ✓ . ,'
Results
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Lab Project Number: 9233015
Client Project ID: NCSU Lot 86/2246
Phone: [phone]
Fax: [phone]
Project Sample Number: 9233015-001
Matrix: Water
Date Collected: 05/20/02 17:30
Date Received: 05/21/02 14:10
Reoort Limit JlL Analyzed By CAS No.
2.0 1.0 05/30/02 08:52 KTV 74-87-3
0.50 1.0 05/30/02 08:52 KTV 95-49·8
0.50 1.0 05/30/02 08:52 KTV 106-43-4
2.0 1.0 05/30/02 08:52 KTV 96-12-8
0.50 1.0 05/30/02 08:52 KTV 124-48-1
0.50 1.0 05/30/02 08:52 KTV 106-93-4
0.50 1.0 05/30/02 08:52 KTV 74-95·3
1.0 1.0 05/30/02 08:52 KTV 95-50-1
/1;"3°-Di chl orobenzene /4 _;i .4-Dichlorobenzene ,,
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Units
ug/1
ug/1
ug/1
ug/l
ug/l
ug/l
ug/l
ug/1
ug/l
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/l
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/l
ug/1
ug/1
ug/l
ug/1
ug/1
1.0 1.0 05/30/02 08:52 KTV 541-73-1
1.0 1.0 05/30/02 08:52 KTV 106-46-7
Dichlorodifluoromethane
1,1-Dichloroethane
1.2-Dichloroethane
1.1-Dichloroethene
cis-1,2-Dichloroethene
trans-1.2-Dichloroethene
1.2-Dichloropropane
1.3-0ichloropropane
2.2-Dichloropropane
1.1-Dichloropropene
cis-1,3-0ichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethyl benzene
Hexachloro-1,3-butadiene
Isopropylbenzene (Cumene}
p-lsopropyltoluene
Methylene chloride
Methyl-tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1.1. 2. 2-Tetrachl oroetha_ne
Tetrachloroethene
Toluene
1.2,3-Trichlorobenzene
1.2,4-Trichlorobenzene
1.1.1-Trichloroethane
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
0.50 1.0 05/30/02 08:52 KTV 75-71-8
0.50 1.0 05/30/02 08:52 KTV 75-34-3
0.50 1.0 05/30/02 08:52 KTV 107-06-2
0.50 1.0. 05/30/02 08:52 KTV 75-35-4
0.50 1.0 05/30/02 08:52 KTV 156-59-2
0.50 1.0 05/30/02 08:52 KTV 156-60-5
0.50 1.0 05/30/02 08:52 KTV 78-87-5
0.50
0.50
0.50
0.50
0.50
0.50
0.50
2.0
0.50
1.0
2.0
0.50
2.0
0.50
0.50
0.50
0.50
0.50
0.50
2.0
2.0
0.50
1.0 05/30/02 08:52 KTV 142-28-9
1.0 05/30/02 08:52 KTV 594-20-7
1.0 05/30/02 08:52 KTV 563-58-6
1.0 05/30/02 08:52 KTV 10061-01-5
1.0 05/30/02 08:52 KTV 10061-02-6
1.0 05/30/02 08:52 KTV 108-20-3
1.0 05/30/02 08:52 KTV 100-41-4
1.0 05/30/02 08:52 KTV 87-68-3
1.0 05/30/02 08:52 KTV 98-82-8
1.0 05/30/02 08:52 KTV 99-87-6
1.0 05/30/02 08:52 KTV 75-09-2
1.0 05/30/02 08:52 KTV 1634-04-4
1.0 05/30/02 08:52 KTV 91-20-3
1.0 05/30/02 08:52 KTV 103-65-1
1.0 05/30/02 08:52 KTV 100-42-5
1.0 05/30/02 08:52 KTV 630-20-6
1.0 05/30/02 08:52 KTV 79-34-5
1.0 05/30/02 08:52 KTV 127-18-4
1.0 05/30/02 08:52 KTV 108-88-3
1.0 05/30/02 08:52 KTV 87-61-6
1.0 05/30/02 08:52 KTV 120-82-1
1.0 05/30/02 08:52 KTV 71-55-6
Page: 2
REPORT OF LABORATORY ANALYSIS Laboratory Certification IDs
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
.., ,~ •tco~0~
o'~, ffiOt::iaC\1
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
I
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ace Analytical™
www.pacelabs.com
Lab Sample No: 922276217
Client Sample ID: MW-34S a
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Lab Project Number: 9233015
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-001
Matrix: Water
Date Collected: 05/20/02 17:30
Date Received: 05/21/02 14:10
I
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Parameters Results Units Re~ort Limit ....!lL Anal ~zed 8~ CAS No. Q!!tl_ Reglmt
I
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromettiane·
1. 2. 3-Tri ch 1 oropiOPa'n'~
1.2.4-Trimethyib~Ozene
1,3.5-Trimethylbenzene
Vinyl .chloride
m&p-Xyl:~e
I /i,Xylene
.,,_:-' i-Chloro-3-fluorobenzene (S)
:·ft;.·· ,
I
I
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I
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I.
I
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I
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
ND ug/1 0.50 1.0 05/30/02 08:52 KTV
ND ug/1 0.50 1.0 05/30/02 08:52 KTV
ND ug/1 0.50 1.0 05/30/02 08:52 KTV
ND ug/1 0.50 1.0 05/30/02 08:52 KTV
NO ug/1 0.50 1.0 05/30/02 08:52 KTV
ND ug/1 0.50 1.0 05/30/02 08:52 KTV
ND ug/1 0.50 1.0 05/30/02 08:52 KTV
ND ug/1 0.50 1.0 05/30/02 08:52 KTV
ND ug/1 0.50 1.0 05/30/02 08:52 KTV
108 t 1.0 05/30/02 08:52 KTV
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
{~~~ ffiOt!!aC\\
79-00-5
79-01-6
75-69-4
96-18·4
95-63-6
108-67·8
75-01-4
95-47-6
625-98-9
Page: 3
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
ace Analytical™
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone] www.pacelabs.com
Lab Project Number: 9233015
Lab Sample No: 922276225
Client Sample ID: MW-34D
Parameters
Metals
Metals by Trace ICP
Arsenic
Barium
Cadmium
Chromium . ·
Lead,.,~ :/"
Manganese
,,sei'e~ium ,,.,,., · ·s··· 1 _/,1 •. _;--1 ver
,,,,.; :· .. Date Digested /
Mercury. CVAAS, in Water
Mercury
Wet Chemistry
Ion Chromatography
Chloride
Nitrate
Sulfate
Alkalinity, Total
Alkalinity, Total
GC Volatiles
GC voes in Water
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butyl benzene
tert-Butylbenzene
Carbon tetrachloride
Chl orobenzene
Chl oroethane
Chloroform
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
Results Units
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015·002
Matrix: Water
Date Collected: 05/20/02 17:00
Date Received: 05/21/02 14:10
Report Limit ...!)£_ Analyzed By CAS No. ~ RegLmt
Prep/Method: EPA 3010 / EPA 6010
ND mg/7
0.044 mg/7
ND mg/7
0.019 mg/7
ND mg/7
0.033 mg/7
ND mg/7
ND mg/7
Method: EPA 7470
ND mg/l
Method: EPA 300.0
2.5 mg/7
0.53
2.7
mg/l
mg/7
Method: EPA 310.1
55. mg/7
Method: SM 62300
ND ug/7
ND ug/1
ND ug/7
ND ug/7
ND ug/1
ND ug/7 .
ND ug/7
ND ug/7
ND ug/1
ND ug/7
ND ug/7
ND ug/7
ND ug/7
0.0050 1.0 06/04/02 18:55 DJR 7440-38·2
0.0050 1.0 06/04/02 18:55 DJR 7440-39·3
0.0010 1.0 06/04/02 18:55 DJR 7440-43·9
0.0020 1.0 06/04/02 18:55 DJR 7440-47-3
0.0050 1.0 06/04/02 18:55 DJR 7439-92-1
0.0050 1.0 06/04/02 18:55 DJR 7439°96-5
0.0050 1.0 06/04/02 18:55 DJR 7782-49·2
0.0020 1.0 06/04/02 18:55 DJR 7440-22·4
05/22/02
0.00020 1.0 06/03/02 LBG 7439-97-6
1.0 1.0 05/21/02 CBJ 16887-00-6
CBJ 0.10
1.0
1.0
0.50
0.50
0.50
0.50
0.50
0.50
1.0
0.50
0.50
0.50
0.50
0.50
0.50
1.0 05/21/02
I. 0 05/21/02
I. 0 05/21/02
CBJ
HEH
1.0 05/30/02 09:39 KTV
1.0 05/30/02 09:39 KTV
1.0 05/30/02 09:39 KTV
1.0 05/30/02 09:39 KTV
1.0 05/30/02 09:39 KTV
1.0 05/30/02 09:39 KTV
1.0 05/30/02 09:39 KTV
1.0 05/30/02 09:39 KTV
1.0 05/30/02 09:39 KTV
1.0 05/30/02 09:39 KTV
1.0 05/30/02 09:39 KTV
1.0 05/30/02 09:39 KTV
1.0 05/30/02 09:39 KTV
71-43-2
108-86·1
74.97.5
75-27-4
75-25-2
74-83-9
104-51·8
135-98·8
98-06-6
56-23-5
108-90-7
75-00·3
67-66-3
Page: 4
REPORT OF LABORATORY ANALYSIS Laboratory Certification IDs
LA Wastewater 04034 This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,~ Ace0• l~~ iinelac1t
VA Drinking Water 213
FL NELAP E87627
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I ace Analytical™
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone] www.pacelabs.com
I
I
I
I
Lab Sample No: 922276225
Client Sample ID: MW-340
Parameters
Chloromethane
2 · Chl orotol uene
4-Chl orotol uene '.
1.2-Dibromo-3·chiorop~opane
Di bromoch l oroniet.ha'ne
1.2-Dibromoethane (EDB)
Di bro~~~i:h~ne
1. 2 ,o_i chl orobenzene
I , 1.3-Dichlorobenzene
,,,, ;;"'. :,1 .4 •Di chlorobenzene
. ,, ·,., · Di chlorodi fl uoromethane . ,,
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1,1-Dichloroethane
1.2-Dichloroethane
1.1-Dichloroethene
cis-1.2-Dichloroethene
trans-l.2·Dichloroethene
1.2-Dichloropropane
1.3-Dichloropropane
2,2-Dichloropropane
1.1-Dichloropropene
cis-1.3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethyl benzene
Hexachloro-1.3-butadiene
Isopropylbenzene (Cumene)
p-Isopropyltoluene
Methylene chloride
Methyl-tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1.1.1.2-Tetrachloroethane
1.1.2.2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2.3-Trichlorobenzene
1.2.4-Trichlorobenzene
1.1.1-Trichloroethane
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
I
Results
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Units
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ugn
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
Lab Project Number: 9233015
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-002
Matrix: Water
Date Collected: 05/20/02 17:00
Date Received: 05/21/02 14:10
Report Limit .JlL Anal yzed 8 y CAS No.
2.0 1.0 05/30/02 09:39 KTV 74-87-3
0.50 1.0 05/30/02 09:39 KTV 95-49-8
0.50 1.0 05/30/02 09:39 KTV 106-43-4
2.0 1.0 05/30/02 09:39 KTV 96-12-B
0.50 1.0 05/30/02 09:39 KTV 124-48·1
0.50 1.0 05/30/02 09:39 KTV 106-93-4
0.50 1.0 05/30/02 09:39 KTV 74-95-3
1.0 1.0 05/30/02 09:39 KTV 95-50-1
1.0 1.0 05/30/02 09:39 KTV 541-73-1
1.0 1.0 05/30/02 09:39 KTV 106-46-7
0.50 1.0 05/30/02 09:39 KTV 75-71-8
0.50 1.0 05/30/02 09:39 KTV 75-34-3
0.50 1.0 05/30/02 09:39 KTV 107-06-2
0.50 1.0 05/30/02 09:39 KTV 75-35-4
0.50 1.0 05/30/02 09:39 KTV 156-59-2
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
2.0
0.50
1.0
2.0
0.50
2.0
0.50
0.50
0.50
0.50
0.50
0.50
2.0
2.0
0.50
1.0 05/30/02 09:39 KTV 156-60-5
1.0 05/30/02 09:39 KTV 78-87•5
1.0 05/30/02 09:39 KTV 142-28-9
1.0 05/30/02 09:39 KTV 594-20-7
1.0 05/30/02 09:39 KTV 563-58-6
1.0 05/30/02 09:39 KTV 10061-01-5
1.0 05/30/02 09:39 KTV 10061-02·6
1.0 05/30/02 09:39 KTV 108-20-3
1.0 05/30/02 09:39 KTV 100-41-4
1.0 05/30/02 09:39 KTV 87-68·3
1.0 05/30/02 09:39 KTV 98-82-8
1.0 05/30/02 09:39 KTV 99-87-6
1.0 05/30/02 09:39 KTV 75-09-2
1.0 05/30/02 09:39 KTV 1634-04-4
1.0 05/30/02 09:39 KTV 91-20-3
1.0 05/30/02 09:39 KTV 103-65-1
1.0 05/30/02 09:39 KTV 100-42-5
1.0 05/30/02 09:39 KTV 630-20-6
1.0 05/30/02 09:39 KTV 79-34-5
1.0 05/30/02 09:39 KTV 127-18-4
1.0 05/30/02 09:39 KTV 108-88-3
1.0 05/30/02 09:39 KTV 87-61-6
1.0 05/30/02 09:39 KTV 120-82-1
1.0 05/30/02 09:39 KTV 71-55-6
Page: 5
REPORT OF LABORATORY ANALYSIS Laboratory Certification IDs
LA Wastewater· 04034 This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,~ •cca~ ~~ 'n' ·-•~c· ff/_~ \\
VA Drinking Water 213
FL NELAP E87627
ace Analytical™
www.pacelabs.com
Lab Sample No: 922276225
Client Sample ID: MW-34D
Parameters
1,1.2-Trichloroethane . ,.,, ..•
Trichloroethene
Trichlorofluoromet~ane
1. 2. 3-Tri chl oropr9pane
1. 2. 4-Tri methyl benzene
1. 3. 5-Trimet_hylbenzene
Vinyl chloride
m&p-Xjl~~e
/ •,•
Results
ND
ND
ND
ND
ND
ND
ND
ND
ND
Units
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
Lab Project Number: 9233015
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-002
Matrix: Water
Date Collected: 05/20/02 17:00
Date Received: 05/21/02 14:10
Reoort Limit ...QL Analrzed Br CAS No. !l!!tl_ RegLmt
0.50 1.0 05/30/02 09:39 KTV 79-00-5
0.50 1.0 05/30/02 09:39 KTV 79-01-6
0.50 1.0 05/30/02 09:39 KTV 75-69-4
0.50 1.0 05/30/02 09:39 KTV 96-18-4
0.50 1.0 05/30/02 09:39 KTV 95-63-6
0.50 1.0 05/30/02 09:39 KTV 108-67-8
0.50 1.0 05/30/02 09:39 KTV 75-01-4
0.50 1.0 05/30/02 09:39 KTV
0.50 1.0 05/30/02 09:39 KTV 95-47-6 ,,o-;.Xylene
/,;<·--i°-Chloro-3-fl uorobenzene (SJ
._,,, ',-·
101
ug/1
t 1.0 05/30/02 09:39 KTV 625-98-9
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~/
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.
,,. •cco~ ~'~~ ;1nelac1,
Page: 6
Laboratory Certification IDs I
LA Wastewater 04034
VA Drinking Water 213 1 FL NELAP E87627
I
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I. .,,-,(.~, :· .. ,,
I
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'
ace Analyticar·
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone] www.pacelabs.com Lab Project Number: 9233015
Lab Sample No: 922276258
Client Sample ID: MW-34S DISSOLVED
Parameters Results
Metals
Units
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-003
Matrix: Water
Date Collected: 05/20/02 17:30
Date Received: 05/21/02 14:10
Report Limit ...QL -~A""n"'a-'-1 y,.,zeaed,,____,,B.,_y _,C'-"AS'-"'No,..,._ lli@}_ RegLmt
Dissolved Metals, Trace ,ICP
Iron. Dissolved
Prep/Method: EPA 3010 / EPA 6010
Date Digested
/
' :,,.-
/ /:_::,-· ,,
Oate: 06/29/02
LabQralQry QertificaliQn IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
ND rng/1 0.050 1.0 06/03/02
05/22/02
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
/~~ ffi0€1d.C\\.
DJR 7439-89-6
Page: 7
LabQratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
ace Analytical™
www.pacelabs.com
Lab Sample No: 922276266
Client Sample ID: MW-34D DISSOLVED
~Pa~r;am"':ec't~er~s~----~,,.· ,..: '.,..c-' -""Re"'s"'ul'-'t,,,s __ Metals Units
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Lab Project Number: 9233015
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Prqject Sample Number: 9233015·004
Matrix: Water
Date Collected: 05/20/02 17:00
Date Received: 05/21/02 14:10
Report Limit ...QL -~Ac::n,,,a.,_l y..,z"'-ed,,____,,8"'---y CAS No.
Dissolved Metals, Trace I_CP Prep/Method: EPA 3010 I EPA 6010
Iron, Dissolved
Date Digested
,,·<,. ,._ ;r ,..·:•)
0.052 mg/1 0.050 I. 0 06/03/02
05/22/02
DJR 7439-89·6
,.(--:-::~,,./
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({_.;•:-,.,
;.-,·
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,~ ~cca~ ,,~ iRPl~C'\:
Page: 8 I
Laboratory Certification IDs I
LA Wastewater 04034
VA Drinking Water 213 1 FL NELAP E87627
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I/ /h,. ...
/
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ace Analytical™
Pace Analytical Services, Inc.
9800 Kincey Avenue, S_uite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone] www.pacelabs.com Lab Project Number: 9233015
Lab Sample No: 922282611
Client Sample ID: MW-13
Parameters
Metals
Metals by Trace ICP
Arsenic
Barium
Cadmium
Chromium _
Lead
Ha_ng3ne.Se
. ..:~e1e~ium
,.,.-•Silver
Date Digested
Mercury, CVAl>S. in Water
Mercury
Wet Chemistry
Ion Chromatography
Chloride
Nitrate
Sulfate
Alkalinity, Total
Alkalinity. Total
GC Volatiles
GC voes in Water
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butyl benzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Oate: 06/29/02
LaboratQr~ Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
' .
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-005
Matrix: Water
Date Collected: 05/22/02 10:51
Date Received: 05/23/02 16:10
Results Units Report Limit...![_ Analyzed By CAS No.
Prep/Method:
ND
0.12
ND
ND
ND
0.61
ND
ND
EPA 3010 I EPA 6010
mg/1 0.0050
mg/1 0.0050
mg/l 0.0010
mg/1 0.0020
mg/1 0.0050
mg/1 0.0050
mg/1 0.0050
mg/1 0.0020
Method: EPA 7470
1.0 06/05/02 00:39 DJR 7440-38-2
1.0 06/28/02 DJR 7440-39·3
1.0 06/05/02 00:39 DJR 7440-43-9
1.0 06/05/02 00:39 DJR 7440-47-3
1.0 06/05/02 00:39 DJR 7439-92-1
1.0 06/05/02 00:39 DJR 7439-96-5
1.0 06/05/02 00:39 DJR 7782-49-2
1.0 06/05/02 00:39 DJR 7440-22-4
05/30/02
ND mg/1 0.00020 1.0 06/03/02 LBG 7439-97-6
Method: EPA 300.0
5.6 mg/1
4.4 mg/l
1.0
0.10
1.0
1. 0 05/24/02
1. 0 05/24/02
1. 0 05/24/02
CBJ 16887-00-6
CBJ
ND mg/l CBJ
Method: EPA 310.1
15. mg/l 1.0 1.0 05/31/02 HEH
Method: SM 6230D
ND ug/l 0.50 1.0 05/30/02 10:26 KTV
ND ug/l 0.50 1.0 05/30/02 10:26 KTV
ND ug/l 0.50 1.0 05/30/02 10:26 KTV
ND ug/l 0.50 1.0 05/30/02 10:26 KTV
ND ug/l 0.50 1.0 05/30/02 10:26 KTV
ND ug/l 0.50 1.0 05/30/_02 10:26 KTV
ND ug/l 1.0 1.0 05/30/02 10:26 KTV
ND ug/l 0.50 1.0 05/30/02 10:26 KTV
ND ug/l 0.50 1.0 05/30/02 10:26 KTV
ND ug/1 0.50 1.0 05/30/02 10:26 KTV
ND ug/l 0.50 1.0 05/30/02 10:26 KTV
ND ug/l 0.50 1.0 05/30/02 10:26 KTV
ND ug/l 0.50 1.0 05/30/02 10:26 KTV
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,• •cco4 .~, ff1□eld.C1\
71-43-2
108-86-1
74-97-5
75-27-4
75-25-2
74-83-9
104-51-8
135-98-8
98-06-6
56-23-5
108-90-7
75-00-3
67-66-3
Page: 9
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
ace Analytical™
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone] www.pacelabs.com
Lab Sample No: 922282611
Client Sample ID: MW-13
Lab Project Number: 9233015
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-005
Matrix: Water
Date Collected: 05/22/02 10:51·
Date Received: 05/23/02 16:10
Parameters
Chloromethane
2-Chlorotoluene
, ·,: :·/ Results -==""--Units
ug/l
ug/1
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/1
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/1
ug/l
ug/l
ug/1
ug/l
ug/l
ug/l
ug/1
ug/l
ug/1
ug/1
ug/l
ug/l
ug/l
Report Limit....![_ Analyzed By CAS No.
.' 4-Chlorotoluene //:-:. -
1. 2-0i bromo-3 -chl orop~opane
Di bromochloronietha~e
1,2-Dibromo;th~ne (EDB)
Di bromolll~th'a.ne
1. 2 · Di ~hl~ orobenzene
,.,fj{[); chl orobenzene •✓.-<>1 ,4-0i chlorobenzene
, .. -:_.::-,. · Oichlorodi fl uoromethane
,.· 1,1-Dichloroethane
1.2-0ichloroethane
1.1-Dichloroethene
cis-1.2-Dichloroethene
trans-1,2-Dichloroethene
1.2-0ichloropropane
1,3-0ichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1.3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethyl benzene
Hexachloro-1.3-butadiene
Isopropylbenzene (Cumene)
p-lsopropyltoluene
Methylene chloride
Hethyl-tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1.1.1,2-Tetrachloroethane
1,1,2.2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1.2,4-Trichlorobenzene
1,1,1-Trichloroethane
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
/ ND
ND
ND
NO
ND
ND
ND
NO
ND
ND
ND
NO
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
2.0 1.0 05/30/02 10:26 KTV 74-87-3
0.50
0.50
2.0
0.50
0.50
0.50
1.0
1.0
1.0
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
2.0
0.50
1.0
2.0
0.50
2.0
0.50
0.50
0.50
0.50
0.50
0.50
2.0
2.0
0.50
1.0 05/30/02 10:26 KTV 95-49-8
1.0 05/30/02 10:26 KTV 106-43-4
1.0 05/30/02 10:26 KTV 96-12-8
1.0 05/30/02 10:26 KTV 124-48-1
1.0 05/30/02 10:26 KTV 106-93-4
1.0 05/30/02 10:26 KTV 74-95-3
1.0 05/30/02 10:26 KTV 95-50-1
1.0 05/30/02 10:26 KTV 541-73-1
1.0 05/30/02 10:26 KTV 106-46-7
1.0 05/30/02 10:26 KTV 75-71-8
1.0 05/30/02 10:26 KTV 75-34-3
1.0 05/30/02 10:26 KTV 107-06-2
1.0 05/30/02 10:26 KTV 75-35-4
1.0 05/30/02 10:26 KTV 156-59-2
1.0 05/30/02 10:26 KTV 156-60-5
1:0 05/30/02 10:26 KTV 78-87-5
1.0 05/30/02 10:26 KTV 142-28-9
1.0 05/30/02 10:26 KTV 594-20-7
1.0 05/30/02 10:26 KTV 563-58-6
1.0 05/30/02 10:26 KTV 10061-01-5
1.0 05/30/02 10:26 KTV 10061-02-6
1.0 05/30/02 10:26 KTV 108-20-3
1.0 05/30/02 10:26 KTV 100-41-4
1.0 05/30/02 10:26 KTV 87-68-3
1.0 05/30/02 10:26 KTV 98-82-8
1.0 05/30/02 10:26 KTV 99-87-6
1.0 05/30/02 10:26 KTV 75-09-2
1.0 05/30/02 10:26 KTV 1634-04-4
1.0 05/30/02 10:26 KTV 91-20-3
1.0 05/30/02 10:26 KTV 103-65-1
1.0 05/30/02 10:26 KTV 100-42-5
1.0 05/30/02 10:26 KTV 630-20-6
1.0 05/30/02 10:26 KTV 79-34-5
1.0 05/30/02 10:26 KTV 127-18-4
1.0 05/30/02 10:26 KTV 108-88-3
1.0 05/30/02 10:26 KTV 87-61-6
1.0 05/30/02 10:26 KTV 120-82-1
1.0 05/30/02 10:26 KTV 71-55-6
Page: 10
REPORT OF LABORATORY ANALYSIS Laboratory Certification IDs
LA Wastewater 04034 This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc. VA Drinking Water 213
FL NELAP E87627
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
ace Analytical™
www.pacelabs.com
Lab Sample No: 922282611
Client Sample ID: HW-13
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NG 28078
Lab Project Number: 9233015
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-005
Matrix: Water
Date Collected: 05/22/02 10:51
Date Received: 05/23/02 16:10
I
I
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I
Parameters Results Units RellQrt Limit ....!lL AnallZed 8~ CAS No. lli!tl_ RegLmt
1.1.2-Trichloroethane
Tri chl oroethene
Trichlorofluoromethane
1. 2, 3 · Tri chl oropropari°e
1,2 ,4-Trimethylbenzene
1,3.5-Trimethylbenzene
Vinyl,chloi'ide
~p-Xyle~e
I h·ci;X,Yl ene .,., ,<··~ 1-Chloro-3-fluorobenzene (S)
.,,;1,
I
I
I
I
I
I
I
I
I
I
I
I
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
ND ug/1 0.50 1.0 05/30/02 10:26 KTV
ND ug/1 0.50 1.0 05/30/02 10:26 KTV
ND ug/1 0.50 1.0 05/30/02 10:26 KTV
ND ug/1 0.50 1.0 05/30/02 10:26 KTV
ND ug/1 0,50 1.0 05/30/02 10:26 KTV
ND ug/1 0.50 1.0 05/30/02 10:26 KTV
ND ug/1 0.50 1.0 05/30/02 10:26 KTV
ND ug/1 0,50 1.0 05/30/02 10:26 KTV
ND ug/1 0.50 1.0 05/30/02 10:26 KTV
101 t 1,0 05/30/02 10:26 KTV
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analylical Services, Inc.
'~ Iin~ac~
79-00·5
79·01·6
75-69•4
96·18·4
95·63·6
108-67·8
75-01-4
95-47-6
625-98-9
Page: 11
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
ace Analytical™
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
www.pacelabs.com
Lab Project Number: 9233015
Lab Sample No: 922282629
Client Sample ID: HW-27
Parameters
Metals
Metals by Trace ICP
Arsenic
Barium
Cadmium
_Chromium •
Lead ,,,.. ,,. · ·· -,,.y· M~ng~nese
/se1€nium
~·/ :>··Silver ,,,.-•/' :-~;. •' Date Digested
Mercury, CVMS. in Water
Mercury
Wet Chemistry
Ion Chromatography
Chloride
Nitrate
Sulfate
Alkalinity, Total
Alkalinity, Total
GC Volatiles
GC voes in Water
Benzene
Bromobenzene
Bromochlorornethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butyl benzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
Results Units
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-006
Matrix: Water
Date Collected: 05/22/02 12:43
Date Received: 05/23/02 16:10
Report Limit ...QL._ Analyzed By CAS No.
Prep/Method: EPA 3010 I EPA 6010
ND
0.053
ND
0.0055
0.0058
0.45
ND
ND
mg/l
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
Method: EPA 7470
ND mg/1
Method: EPA 300.0
3.2 mg/1
0.58 mg/1
1.2 mg/1
Method: EPA 310.1
10. mg/1
Method: SM 6230D
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
12. ug/1
ND ug/1
ND ug/1
13. ug/1
0.0050 1.0 06/05/02 00:44 DJR 7440-38-2
0.0050 1. 0 06/28/02 DJR 7440-39-3
0.0010 1.0 06/05/02 00:44 DJR 7440-43-9
0.0020 1.0 06/05/02 00:44 DJR 7440-47-3
0.0050 1.0 06/05/02 00:44 DJR 7439-92-1
0.0050 1.0 06/05/02 00:44 DJR 7439-96-5
0.0050 1.0 06/05/02 00:44 DJR 7782-49·2
0.0020 1.0 06/05/02 00:44 DJR 7440-22·4
05/30/02
0.00020 1.0 06/03/02 LBG 7439-97-6
1.0
0.10
1.0
1.0
0.50
0.50
0.50
0.50
0.50
0.50
1.0
0.50
0.50
0.50
0.50
0.50
0.50
1.0 05/24/02
1.0 05/24/02
1.0 05/24/02
C8J 16887-00-6
C8J
C8J
1.0 05/31/02 HEH
1.0 05/30/02 11:13 KTV 71-43·2
1.0 05/30/02 11:13 KTV 108-86·1
1.0 05/30/02 11:13 KTV 74.97.5
1.0 05/30/02 11:13 KTV 75·27-4
1.0 05/30/02 11:13 KTV 75-25·2
1.0 05/30/02 11:13 KTV 74-83-9
1.0 05/30/02 11:13 KTV 104-51-8
1.0 05/30/02 11:13 KTV 135-98-8
1.0 05/30/02 11:13 KTV 98-06-6
1.0 05/30/02 11:13 KTV 56-23-5
1.0 05/30/02 11:13 KTV 108-90-7
1.0 05/30/02 11:13 KTV 75-00-3
1.0 05/30/02 11:13 KTV 67-66-3
Page: 12
REPORT OF LABORATORY ANALYSIS Laboratory Certification IDs I
LA Wastewater 04034 This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,~ •tca4 ~-· inelaat
VA Drinking Water 213 1 FL NELAP E87627
I
I,
I
I
I
I
ace Analytical™
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suile 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone] www.pacelabs.com
Lab Sample No: 922282629
Client Sample ID: MW-27
Lab Project Number: 9233015
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-006
Matrix: Water
Date Collected: 05/22/02 12:43
Date Received: 05/23/02 16:10
Parameters Results Units
ug/l
ug/l
ug/l
ug/l
ug/l
ug/1
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/l
ug/1
ug/l
ug/l
ug/1
ug/1
ug/1
ug/1
ug/l
ug/l
ug/1
ug/1
ug/l
ug/1
ug/l
ug/1
ug/1
ug/1
ug/1
ug/1
Report Limit ....!lf.._ Analyzed By CAS No.
I
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1.2-Dibromo-3-chfo'ropropane
Di bromochlor:orii~tha·ne
1,2-Dibromo,thane (EDB)
Oibromomethane . ' 1.2~Dichlorobenzene
,/ ( 3•:oi ch l orobenzene I,,.,/;;,,-, '1, 4 -Di chlorobenzene
, .,.r · Dichlorodifluoromethane
,,. 1. 1-Dichloroethane
I
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I
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I
I
I
I
I
I
I
1,2-Dichloroethane
1,1-Dichloroethene
cis-1.2-0ichloroethene
trans-1,2-Dichloroethene
1.2-Dichloropropane
1,3-Dichloropropane
2.2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1.3-Dichloropropene
Di i sopropyl ether
Ethyl benzene
Hexachloro.-1. 3 -butadi ene
Isopropylbenzene (Cumene)
p-lsopropyltoluene
Methylene chloride
Methyl-tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1.1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2.3-Trichlorobenzene
1,2.4-Trichlorabenzene
1,1.1-Trichloroethane
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.2
ND
ND
ND
ND
ND
6.2
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2.0 1.0 05/30/02 11:13 KTV 74-87-3
0.50 1.0 05/30/02 11:13 KTV 95-49-8
0.50
2.0
0.50
0.50
0.50
1.0
1.0
1.0
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
2.0
0.50
1.0
2.0
0.50
2.0
0.50
0.50
0.50
0.50
0.50
0.50
2.0
2.0
0.50
1.0 05/30/02 11:13 KTV 106-43-4
1.0 05/30/02 11:13 KTV 96-12-8
1.0 05/30/02 11:13 KTV 124-48-1
1.0 05/30/02 11:13 KTV 106-93-4
1.0 05/30/02 11:13 KTV 74-95-3
1.0 05/30/02 11:13 KTV 95-50-1
1.0 05/30/02 11:13 KTV 541-73-1
1.0 05/30/02 11:13 KTV 106-46-7
1.0 05/30/02 11:13 KTV 75-71-8
1.0 05/30/02 11:13 KTV 75-34-3
1.0 05/30/02 11:13 KTV 107-06-2
1.0 05/30/02 11:13 KTV 75-35-4
1.0 05/30/02 11:13 KTV · 156-59-2
1.0 05/30/02 11:13 KTV 156-60-5
1.0 05/30/02 11:13 KTV 78-87-5
1.0 05/30/02 11:13 KTV 142-28-9
1.0 05/30/02 11:13 KTV 594-20-7
1.0 05/30/02 11:13 KTV 563-58-6
1.0 05/30/02 11:13 KTV 10061-01-5
1.0 05/30/02 11:13 KTV 10061-02-6
1.0 05/30/02 11:13 KTV 108-20-3
1.0 05/30/02 11:13 KTV 100-41-4
1.0 05/30/02 11:13 KTV 87-68-3
1.0 05/30/02 11:13 KTV 98-82-8
1.0 05/30/02 11:13 KTV 99-87-6
1.0 05/30/02 11:13 KTV 75-09-2
1.0 05/30/02 11:13 KTV 1634-04-4
1.0 05/30/02 11:13 KTV 91-20-3
1.0 05/30/02 11:13 KTV 103-65-1
1.0 05/30/02 11:13 KTV 100-42-5
1.0 05/30/02 11:13 KTV 630-20-6
1.0 05/30/02 11:13 KTV 79-34-5
1.0 05/30/02 11:13 KTV 127-18-4
1.0 05/30/02 11:13 KTV 108-88-3
1.0 05/30/02 11:13 KTV 87-61-6
1.0 05/30/02 11:13 KTV 120-82-1
1.0 05/30/02 11:13 KTV 71-55-6
Page; 13
REPORT OF LABORATORY ANALYSIS Laboratory Certification IDs
LA Wastewater 04034 This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
~ lnelaa1
VA Drinking Water 213
FL NELAP E87627
ace Analytical™
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
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I
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I
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I
www.pacelabs.com
_Lab Sample No: 922282629
Client Sample ID: MW-27
Parameters
1,1.2-Trichloroethane
Trichloroethene ,,1·
Tri chlorofl uoromethane,•
1. 2. 3-Tri chl oroprdpa~~
1.2.4-Trimethy\be~zene
1, 3. 5-Trim,frhyl benzene
Vinyl .chloride ~,,,.• m&p.-Xylene ., .· /~;Xylene
✓4 •·1-Chloro-3-fluorobenzene (S) --~>/
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 990D6
Lab Project Number: 9233015
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-006
Matrix: Water
Date Collected: 05/22/02 12:43
Date Received: 05/23/02 16:10
Results Units
ug/l
ug/l
ug/l
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
Reoort Limit Jl.L Anal lZed Bl CAS No. ~ RegLrnt
ND
2. 7
1.3
ND
ND
ND
ND
ND
ND
102 t
0.50 1.0 05/30/02 11:13 KTV
0.50 1.0 05/30/02 11:13 KTV
0.50 1.0 05/30/02 11:13 KTV
0.50 1.0 05/30/02 11:13 KTV
0.50 1.0 05/30/02 11:13 KTV
0.50 1.0 05/30/02 11:13 KTV
0.50 1.0 05/30/02 11:13 KTV
0.50 1.0 05/30/02 11:13 KTV
0.50 1.0 05/30/02 11:13 KTV
1.0 05/30/02 11:13 KTV
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Anal)'1ical Services, Inc.
79-00-5
79-01-6
75-69-4
96-18-4
95-63-6
108-67-8
75-01-4
95-47-6
625-98-9
Page: 14
Laboratory Certification IDs I
LA Wastewater 04034
VA Drinking Water 213 1 FL NELAP E87627
I
I
I
I
I
ace Analyticaf"
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone] www.pacelabs.com Lab Project Number: 9233015
I
Lab Sample No: 922282637
Client Sample ID: MW-35S
Parameters
Metals
Metals by Trace ICP
Arsenic
Barium
Cadmium
Chromium .. / Lead ,. •·
MangcJneS;
.; ' 1'·:Se 1 eni um I / ;,. ·'Sn ver
.. ··. ·• Date Digested
f .,.'r
I Mercury. CVAAS, in Water
Mercury
I Wet Chemistry
Ion Chromatography
Chloride
Nitrate
I Sulfate
Alkalinity, Total
I Alkalinity, Total
GC Volatiles
I GC VDCs in Water
Benzene
Bromobenzene
Bromochloromethane
I Bromodichloromethane
Bromoform
Bromomethane
I n·Butylbenzene
sec-Butyl benzene
tert-8utylbenzene
Carbon tetrachloride I Chlorobenzene
Chloroethane
Chloroform
I
Date: 06/29/02
I
I Laboratort QertifiQation IDs
NC Wastewater 12
NC Drinking Water 37706
I SC 99006
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-007
Matrix: Water
Date Collected: 05/22/02 12:23
Date Received: 05/23/02 16:10
Results Units Report Limit ..QE__ Analyzed By CAS No. !lgtl.. RegLmt
Prep/Method: EPA 3010 / EPA 6010
ND mg/1 0.0050 1.0 06/05/02 00:48 DJR 7440-38-2
O .073 mg/1 0.0050 1.0 06/28/02 DJR 7440-39-3
ND mg/1 0.0010 1.0 06/05/02 00:48 DJR 7440-43-9
0 .037 mg/1 0.0020 1.0 06/05/02 00:48 DJR 7440-47-3
0.0098 mg/1 0.0050 1.0 06/05/02 00:48 DJR 7439-92-1
0.42 mg/1 0.0050 1.0 06/05/02 00:48 DJR 7439-96-5
ND mg/1 0.0050 1.0 06/05/02 00:48 DJR 7782-49-2
ND mg/1 0.0020 1.0 06/05/02 00:48 DJR 7440-22-4
05/30/02
Method: EPA 7470
ND mg/1 0.00020 1. 0 06/03/02 LBG 7439-97-6
Method: EPA 300.0
2.5 mg/1
0.66 mg/1
1.0
0.10
1.0
1.0 05/24/02
1.0 05/24/02
1.0 05/24/02
C8J 16887-00-6
CBJ
1.4 mg/1 C8J
Method: EPA 310.1
10. mg/1 1.0 1. 0 05/31/02 HEH
Method: SM 6230D
ND ug/1 0.50 1.0 05/30/02 12:00 KTV
ND ug/1 0.50 1.0 05/30/02 12:00 KTV
ND ug/1 0.50 1.0 05/30/02 12:00 KTV
ND ug/1 0.50 1.0 05/30/02 12:00 KTV
ND ug/1 0.50 1.0 05/30/02 12:00 KTV
ND ug/1 0.50 1.0 05/30/02 12:00 KTV
ND ug/1 1.0 1.0 05/30/02 12:00 KTV
ND ug/1 0.50 1.0 05/30/02 12:00 KTV
ND ug/1 0.50 1.0 05/30/02 12:00 KTV
ND ug/1 0.50 1.0 05/30/02 12:00 KTV
ND ug/1 0.50 1.0 05/30/02 12:00 KTV
ND ug/1 0.50 1.0 05/30/02 12:00 KTV
ND ug/1 0.50 1.0 05/30/02 12:00 KTV
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent ot Pace Analytical Services, Inc.
,~ •Ceo~
l?~~ F10e@C\1
71-43-2
108-86-1
74-97-5
75-27-4
75-25-2
74-83-9
104-51-8
135-98-8
98-06-6
56-23-5
108-90-7
75-00-3
67-66-3
Page: 15
Laboratory Qertification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
Pace Analytical Services, Inc. I
ace Analytical™ 9800 Kincey Avenue, Suite 100
Hunlersville, NC 28078 I Phone: [phone] www.pacelabs.com Fax: [phone] Lab Project Number: 9233015
Client Project ID: NCSU Lot 86/2246 I Lab Sample No: 922282637 Project Sample Number: 9233015-007 Date Co 11 ected: 05/22/02 12:23 Client Sample ID: MW-35S Matrix: Water Date Received: 05/23/02 16:10
Parameters Results Units Re122rt Limit .JlL Anal ~zed B~ CAS No. !l!!tl_ Reglmt I Chloromethane ·' ND ug/1 2.0 1.0 05/30/02 12:00 KTV 74-87-3 2-Chlorotoluene ND ug/1 0.50 1.0 05/30/02 12:00 KTV 95-49-8 I 4-Chlorotoluene ND ug/1 0.50 1.0 05/30/02 12:00 KTV 106-43-4
1. 2 ·Di bromo-3-~h~.?rapropane ND ug/1 2.0 1.0 05/30/02 12:00 KTV 96-12-8
Dibromochloromethane ND ug/1 0.50 1.0 05/30/02 12:00 KTV 124-48-1
1.2-Dibromo,tha~e (EDB) ND ug/1 0.50 1.0 05/30/02 12:00 KTV 106-93-4 I Di bromometliane ND ug/1 0.50 1.0 05/30/02 12:00 KTV 74-95-3 1. 2 -Di chi orobenzene ND ug/1 1.0 1.0 05/30/02 12:00 KTV 95-50-1 ,, . ,,"
I ,,; 1-. 3 -Di chl orobenzene ND ug/1 1.0 1.0 05/30/02 12:00 KTV 541-73-1 _,.,:S; .. ••i, 4 -Di chl orobenzene ND ug/1 1.0 1.0 05/30/02 12:00 KTV 106-46-7 , _:,· ~:::~-,.-Dichlorodifluoromethane ND ug/1 0.50 1.0 05/30/02 12:00 KTV 75-71-8 1.1-Dichloroethane ND ug/1 0.50 1.0 05/30/02 12:00 KTV 75-34-3 I 1,2-Dichloroethane ND ug/1 0.50 1.0 05/30/02 12:00 KTV 107-06-2 1.1-Dichloroethene ND ug/1 0.50 1.0 05/30/02 12:00 KTV 75-35-4 cis-1.2-Dichloroethene ND ug/1 0.50 1.0 05/30/02 12:00 KTV 156-59-2 trans-1.2-Dichloroethene ND ug/1 0.50 1.0 05/30/02 12:00 KTV 156-60-5 I 1.2-Dichloropropane ND ug/1 0.50 1.0 05/30/02 12:00 KTV 78-87-5 1.3-Dichloropropane ND ug/1 0.50 1.0 05/30/02 12:00 KTV 142-28-9 2.2-Dichloropropane ND ug/1 0.50 1.0 05/30/02 12:00 KTV 594-20-7 I 1.1-Dichloropropene ND ug/1 0.50 1.0 05/30/02 12:00 KTV 563-58-6
cis-1.3-Dichloropropene ND ug/1 0.50 1.0 05/30/02 12:00.KTV 10061-01-5
trans-1,3-Dichloropropene ND ug/1 0.50 1.0 05/30/02 12:00 KTV 10061-02-6 Diisopropyl ether ND ug/1 0.50 1.0 05/30/02 12:00 KTV 108-20-3 I Ethyl benzene ND ug/1 0.50 1.0 05/30/02 12:00 KTV 100-41-4 Hexachloro-1,3-butadiene ND ug/1 2.0 1.0 05/30/02 12:00 KTV 87-68-3 Isopropylbenzene (Cumene) ND ug/1 0.50 1.0 05/30/02 12:00 KTV 98-82-8 I p-lsopropylto 1 uene ND ug/1 1.0 1.0 05/30/02 12:00 KTV 99-87-6 Methylene chloride ND ug/1 2.0 1.0 05/30/02 12:00 KTV 75-09-2 Methyl-tert-butyl ether ND ug/1 0.50 1.0 05/30/02 12:00 KTV 1634-04-4 I Naphtha 1 ene ND ug/1 2.0 1.0 05/30/02 12:00 KTV 91-20-3 n-Propylbenzene ND ug/1 0.50 1.0 05/30/02 12:00 KTV 103-65-1 Styrene ND ug/1 0.50 1.0 05/30/02 12:00 KTV 100-42-5
1,1,1,2-Tetrachloroethane ND ug/1 0.50 1.0 05/30/02 12:00 KTV 630-20-6 I 1,1,2,2-Tetrachloroethane ND ug/1 0.50 1.0 05/30/02 12:00 KTV 79-34-5 Tetrachloroethene ND ug/1 0.50 1.0 05/30/02 12:00 KTV 127-18-4
Toluene ND ug/1 0.50 1. 0 05/30/02 ·12: 00 KTV 108-88-3 I 1,2,3-Trichlorobenzene ND ug/1 2.0 1.0 05/30/02 12:00 KTV 87-61-6 1,2,4-Trichlorobenzene ND ug/1 2.0 1.0 05/30/02 12:00 KTV 120-82-1 1.1,1-Trichloroethane ND ug/1 0.50 1.0 05/30/02 12:00 KTV 71-55-6 I
Date: 06/29/02 Page: 16
I
Laboratory Certification IDs
NC Wastewater 12 REPORT OF LABORATORY ANALYSIS Laboratory Certification IDs I
LA Wastewater 04034 · NC Drinking Water 37706
SC 99006
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,~ •cco" ~,K~~ f/DOOC\1
VA Drinking Water 213
FL NELAP E87627 I
I
~ ace Analytical™
www.pacelabs.com
Lab Sample No: 922282637
Client Sample ID: MW·35S : ,'
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Lab Project Number: 9233015
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015·007
Matrix: Water
Date Collected: 05/22/02 12:23
Date Received: 05/23/02 16:10
I
I
I
I
Parameters Results Units
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
Reoort Limit ...!lL Analized Bi CAS No. !l!!tl._ RegLmt
I
1.1,2·Trichloroethane
Trichloroethene
Tri chl orofl uoromethane · -, .. I 1. 2. 3 · Tri chl or?propane
1.2.4-Trimethylbenzene . ' 1,3,5-Trime~hylbenzene
Vinyl chloride ., -,,,
m&p,~ylene
I ./.<J:.Xylene
,/ ;.'l·Chloro•3·fluorobenzene (S)
/ ' <'.i'--
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I
I
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
ND
ND
. ND
ND
ND
ND
ND
ND
ND
101 X
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
1.0 05/30/02 12:00 KTV
1.0 05/30/02 12:00 KTV
1.0 05/30/02 12:00 KTV
1.0 05/30/02 12:00 KTV
1.0 05/30/02 12:00 KTV
1.0 05/30/02 12:00 KTV
1.0 05/30/02 12:00 KTV
1.0 05/30/02 12:00 KTV
1.0 05/30/02 12:00 KTV
1.0 05/30/02 12:00 KTV
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
.,ff~1~•-,, &ne1aCTh
79·00·5
79·01·6
75.59.4
96·18·4
95.53.5
108·67·8
75·01·4
95.47.5
625·98·9
Page: 17
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
ace Analytical™
www.pacelabs.com
Lab Sample No: 922282645
Client Sample ID: MW-36D
Parameters
Metals
Metals by Trace ICP
Arsenic
Barium
Cadmium
Chromium ,
' Lead .· ./ _,h,.Y
Results
Prep/Method:
0.037
ND
ND
0.0054
-ND
0.012
ND
ND
Lab Project Number: 9233015
Pace Analytical Services, In/.·• I
9800 Kincey Avenue. Suite 100
Huntersville, NC 28078
Phone: [phone] I
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-008
Matrix: Water
Date Collected: 05/22/02 11:51
Date Received: 05/23/02 16:10
Units Report Limit ..m:_ -~An~a~l~yz~e~d~~8y~ -~C~A~S~N~o~. _ Q!1tl_ Reglmt
EPA 3010 / EPA 6010
mg/1 0.0050
mg/1 0.0050
mg/1 0.0010
mg/1
mg/1
mg/1
mg/1
mg/1
0.0020
0.0050
0.0050
0.0050
0.0020
1.0 06/05/02 00:53 DJR 7440-38·2
1.0 06/28/02 DJR 7440-39-3
1.0 06/05/02 00:53 DJR 7440-43-9
1.0 06/05/02 00:53 DJR 7440-47·3
1.0 06/05/02 00:53 DJR 7439-92-1
1.0 06/05/02 00:53 DJR 7439-96-5
1.0 06/05/02 00:53 DJR 7782-49·2
1.0 06/05/02 00:53 DJR 7440-22·4
M~~g~nese
,,,.,•se1enium
/(;.;,,·'$; l ver
,/~ . .,. Date Digested 05/30/02
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
)
Mercury, CVAAS, in Water
Mercury
Wet Chemistry
Ion Chromatography
Chloride
Nitrate
Sulfate
Alkalinity. Total
Alkalinity. Total
GC Volatiles
GC VOCs in Water
Benzene
Bromobenzene
Bromochloromethane
Bro1TK>dichloromethane
Bromoform
Bromomethane
n-Butyl benzene
sec-Butyl benzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 377D6
SC 99006
Method: EPA 7470
ND mg/1
Method: EPA 300.0
2.2 mg/1
0 .13 mg/1
3.0 mg/1
Method: EPA 310.1
65. mg/1
Method: SH 6230D
ND ug/1
ND ug/1
ND
ND
ND
ND
ND
ND
ND
54.
ND
ND
1200
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
0.00020 1.0 06/03/02
1.0 1.0 05/24/02
0.10 1.0 05/24/02
1.0 1.0 05/24/02
1.0 1.0 05/31/02
10.
10.
10.
10.
10.
10.
20.
10.
IO.
10.
10.
10.
25.
20. 0 05/30/02
20.0 05/30/02
20.0 05/30/02
20.0 05/30/02.
20.0 05/30/02
20.0 05/30/02
20.0 05/30/02
20.0 05/30/02
20.0 05/30/02
20.0 05/30/02
20.0 05/30/02
20.0 05/30/02
50.0 05/30/02
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,• •cc,,~ , ..... ~~. ,•'/ lei rn •. "•• 01□ ac,, ,, . . J,
L8G 7439-97-6
CBJ 16887-00-6
CBJ
C8J
HEH
KTV 71-43-2
KTV 108-86· l
KTV 74-97-5
KTV 75-27-4
KTV 75-25-2
KTV 74-83-9
KTV 104-51·8
KTV 135-98-8
KTV 98-06-6
KTV 56-23-5
KTV 108-90-7
KTV 75-00-3
KTV 67-66-3
Page: 18
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
I
I.
' ace Analyticalru
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
I www.pacelabs.com Lab Project Number: 9233015
Phone: [phone]
Fax: [phone]
I
I
I
I
Lab Sample No: 922282645
Client Sample ID: MW-36D
Parameters
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloroffietha~e ,·-,·
1.2-Dibronriethane (EDB)
Di bromametha"ne
1,2-Dichlorobenzene . ,,.,.
/~1.3-0ichlorobenzene I ,-c·,
// '1.4-Dichlorobenzene
.. ;-,, Di chl orodi fl uoromethane
· 1,1-Dichloroethane
I
I
I
I
I
I
I
I
I
I
I
I
1,2-Dichloroethane
1,1-0ichloroethene
cis-1.2-Dichloroethene
trans-1,2-0ichloroethene
1.2-Dichloropropane
1,3-Dichloropropane
2.2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethyl benzene
Hexachloro-1,3-butadiene
Isopropylbenzene (Cumene)
p-Isopropyltoluene
Methylene chloride
Methyl-tert-butyl ether
Naphthalene
n-Propyl benzene
Styrene
1,1,1.2-Tetrachloroethane
1.1.2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1.2.3-Trichlorobenzene
1,2,4-Trichlorobenzene
1.1.1-Trichloroethane
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
Client Project ID: NCSU Lot 86/2246
Results
ND
ND
ND
ND
ND
22.
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
14.
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Units
ug/l
ug/l
ug/1
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/1
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/1
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/1
ug/l
ug/l
ug/l
ug/l
ug/1
ug/l
ug/l
ug/1
ug/l
Project Sample Number: 9233015-008
Matrix: Water
Report Limit .J!L Analyzed
40. 20.0 05/30/02
10. 20.0 05/30/02
10. 20.0 05/30/02
40. 20.0 05/30/02
10. 20.0 05/30/02
10. 20. 0 05/30/02
10. 20.0 05/30/02
20. 20. 0 05/30/02
20. 20.0 05/30/02
20. 20, 0 05/30/02
10. 20.0 05/30/02
10. 20. 0 05/30/02
10. 20.0 05/30/02
10. 20.0 05/30/02
10. 20.0 05/30/02
10. 20.0 05/30/02
10. 20. 0 05/30/02
10. 20.0 05/30/02
10. 20.0 05/30/02
10. 20.0 05/30/02
10. 20.0 05/30/02
10. 20. 0 05/30/02
10.
10.
40.
10.
20.
40.
10.
40.
10.
10.
10.
10.
10.
10.
40.
40.
10.
20.0 05/30/02
20.0 05/30/02
20.0 05/30/02
20.0 05/30/02
20.0 05/30/02
20.0 05/30/02
20.0 05/30/02
20.0 05/30/02
20.0 05/30/02
20.0 05/30/02
20.0 05/30/02
20.0 05/30/02
20.0 05/30/02
20.0 05/30/02
20.0 05/30/02
20.0 05/30/02
20.0 05/30/02
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full, .
without the written consent of Pace Analytical Services, Inc.
~~~ ....
//·) 'Ir::"" "'·--11ne ac1\
Date Collected: 05/22/02 11:51
Date Received: 05/23/02 16:10
By CAS No. Q!!tl_ RegLmt
KTV 74-87-3
KTV 95-49-8
KTV 106-43-4
KTV 96-12-8
KTV 124-48-1
KTV 106-93-4
KTV 74-95-3
KTV 95-50-1
KTV 541-73-1
KTV 106-46-7
KTV 75-71-8
KTV 75-34-3
KTV 107-06-2
KTV 75-35-4
KTV 156-59-2
KTV 156-60-5
KTV 78-87-5
KTV 142-28-9
KTV 594-20-7
KTV 563-58-6
KTV 10061-01-5
KTV 10061-02-6
KTV 108-20-3
KTV 100-41-4
KTV 87-68-3
KTV 98-82-8
KTV 99-87-6
KTV 75-09-2
KTV 1634-04-4
KTV 91-20-3
KTV 103-65-1
KTV 100-42-5
KTV 630-20·6
KTV 79-34-5
KTV 127-18-4
KTV 108-88·3
KTV 87-61-6
KTV 120-82-1
KTV 71-55-6
Page: 19
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
ace Analytical™
www.pacelabs.com
Lab Sample No: 922282645
Client Sample ID: HW-360
Parameters Results Units
l,l,2·Trichloroethane /. ND ug/l
Tri chl oroethene 18. ug/l
Tri chl orofl uorome.th.aiie · ND ug/l
1.2.3-Trichloropropane ... NO ug/l
1.2 .4-Tri met_hyl ~enzene ND ug/l
1. 3. 5-Trimethyi benzene ND ug/l
Vinyl c~joride ND ug/l
m&p-Xj,lene ND ug/l
/o)yiene ND ug/l
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Lab Project Number: 9233015
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-008 Date Collected: 05/22/02 11:51
Matrix: Water Date Received: 05/23/02 16:10
Regort Limit __Q[_ Anal vzed Si CAS No. ~ RegLmt
10. 20.0 05/30/02 KTV 79-00·5
10. 20. 0 05/30/02 KTV 79-01-6
10. 20. 0 05/30/02 KTV 75-69-4
10. 20. 0 05/30/02 KTV 96-18-4
10. 20.0 05/30/02 KTV 95-63-6
10. 20. 0 05/30/02 KTV 108-67-8
10. 20. 0 05/30/02 KTV 75-01-4
10. 20. 0 05/30/02 KTV
10. 20. 0 05/30/02 KTV 95-47-6 /:-;'::,.✓i-Chloro-3-fluorobenzene (SJ 99 t ,., .. -,._.,,. 1. 0 05/30/02 KTV 625-98·9
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, ,.
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,~ •eco., ..... "'~+ ff1oolaat
Page: 20
Laboratory Certification IDs I
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627 I
I
ace Analytical™
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone] www.pacelabs.com Lab Project Number: 9233015
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Lab Sample No: 922282652
Client Sample ID: MW-40
Parameters
Metals
Metals by Trace ICP
Arsenic
Barium
Cadmium
Chromium . ·-.:
L d / ·· ea_,/·>/
. M~nganese .. .,,
I ... ,/_§e1enium
/>'Silver ., ,,,,
,-:i·'" Date Digested .-
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Mercury, CVMS. in Water
Mercury
Wet Chemistry
Ion Chromatography
Chloride
Nitrate
Sulfate
Alkalinity, Total
Alkalinity, Total
GC Volatiles
GC voes in Water
Benzene
Bromobenzene
8romochloromethane
Bromodichloromethane
Bromoform
Bromornethane
n-8utylbenzene
sec-Butyl benzene
tert-8utylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Oate: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-009
Matrix: Water
Date Collected: 05/22/02 11:31
Date Received: 05/23/02 16:10
Results Units Report Limit ...lli:.._ _ __,,,An-"'a"-ly,.,z,se,._d _ _.8"--y CAS No.
Prep/Method: EPA 3010 / EPA 6010
0.010 mg/1 0.0050
0.16 mg/1 0.0050
ND mg/1 0.0010
0.052 mg/1 0.0020
0.014 mg/1 0.0050
0.59 mg/1 0.0050
ND mg/1 0.0050
ND mg/1 0.0020
Method: EPA 7470
1.0 06/05/02 00:58 DJR 7440-38-2
1.0 06/28/02 DJR 7440-39-3
1.0 06/05/02 00:58 DJR 7440-43-9
1.0 06/05/02 00:58 DJR 7440-47-3
1.0 06/05/02 00:58 DJR 7439-92-1
1.0 06/05/02 00:58 DJR 7439-96-5
1.0 06/05/02 00:58 DJR 7782-49-2
1.0 06/05/02 00:58 DJR 7440-22-4
05/30/02
ND mg/1 . 0. 00020 1. 0 06/03/02 L8G 7439-97-6
Method: EPA 300.0
4.1 mg/1
0.59 mg/1
ND mg/1
Method: EPA 310.1
7.5 mg/1
Method: SM 62300
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
13. ug/1
1.0 1.0 05/24/02 CBJ 16887-00-6
C8J 0.10 1.0 05/24/02
1.0 1.0 05/24/02 CBJ
1.0 1.0 05/31/02 HEH
0.50
0.50
0.50
0.50
0.50
0.50
1.0
0.50
0.50
0.50
0.50
0.50
0.50
1.0 05/30/02 13:33 KTV 71-43-2
1.0 05/30/02 13:33 KTV 108-86-1
1.0 05/30/02 13:33 KTV 74-97•5
1.0 05/30/02 13:33 KTV 75-27-4
1.0 05/30/02 13:33 KTV 75-25-2
1.0 05/30/02 13:33 KTV 74-83-9
1.0 05/30/02 13:33 KTV 104-51-8
1.0 05/30/02 13:33 KTV 135-98-8
1.0 05/30/02 13:33 KTV. 98-06-6
1.0 05/30/02 13:33 KTV 56-23-5
1.0 05/30/02 13:33 KTV 108-90•7
1.0 05/30/02 13:33 KTV 75-00·3
1.0 05/30/02 13:33 KTV 67-66-3
Page: 21
REPORT OF LABORATORY ANALYSIS Laboratory Certification IDs
This report shall not be reproduced. except in full,
without the written consent of Pace Analytical Services, Inc.
"~1'"•, ", ?1neaC\\
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
ace Analytical™
Pace Analytical Services, Inc.
· 9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
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www.pacelabs.com
Lab Sample No: 922282652
Client Sample ID: MW-40
,·
Lab Project Number: 9233015
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-009
Matrix: Water
Date Collected: 05/22/02 11:31
Date Received: 05/23/02 16:10
Parameters Results Units
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/1
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
u9/l
ug/l
ug/l
ug/l
ug/l
ug/l
u9/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/1
ug/1
ug/l
ug/1
ug/l
ug/l
Reoort Limit JlL Analyzed By CAS No. lli!tl_ RegLmt Chloromethane
2-Chloroto l uene
4-Chlorotoluene ,(
1. 2-0i bromo-3-chl oropropane
Di bromochl oro~'t:h~-~e ,{,' ,:, . 1,2-0ibromoethane (EDB)
Di bromolll~t~~ne .; .r l,2·0~chlorobenzene < ·:;;· /'.f 3-0i chl orobenzene
/~:,, · 1.4-01chlorobenzene
/~>-Di chl orodi fl uoromethane C r
_,, 1.1-Dichloroethane
1.2-0ichloroethane
1,1-Dichloroethene
cis-1,2-0ichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2.2-Dichloropropane
l.l·Dichloropropene
cis•l.3-Dichloropropene
trans-1,3-0ichloropropene
Oiisopropyl ether
Ethyl benzene
Hexachloro-1.3-butadiene
Isopropylbenzene (Cumene)
p-Isopropyltoluene
Methylene chloride
Hethyl-tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1.1.2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1.1.1-Trichloroethane
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
NO
2.0 1.0 05/30/02 13:33 KTV 74-87-3
0.50 1.0 05/30/02 13:33 KTV 95-49-8
0.50 1.0 05/30/02 13:33 KTV 106-43•4
2.0 1.0 05/30/02 13:33 KTV 96-12-8
0.50 1.0 05/30/02 13:33 KTV 124-48-1
0.50 1.0 05/30/02 13:33 KTV 106-93-4
0.50 1.0 05/30/02 13:33 KTV -74-95-3
1.0 1.0 05/30/02 13:33 KTV 95-50-1
1.0 1.0 05/30/02 13:33 KTV 541-73-1
1.0 1.0 05/30/02 13:33 KTV 106-46-7
0.50 1.0 05/30/02 13:33 KTV 75-71-8
0.50 1.0 05/30/02 13:33 KTV 75-34-3
0.50 1.0 05/30/02 13:33 KTV 107-06-2
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
2.0
0.50
1.0
2.0
0.50
2.0
0.50
0.50
0.50
0.50
0.50
0.50
2.0
2.0
0.50
1.0 05/30/02 13:33 KTV 75-35-4
1.0 05/30/02 13:33 KTV 156-59-2
1.0 05/30/02 13:33 KTV 156-60-5
1.0 05/30/02 13:33 KTV 78-87-5
1.0 05/30/02 13:33 KTV 142-28-9
1.0 05/30/02 13:33 KTV 594-20-7
1.0 05/30/02 13:33 KTV 563-58-6
1.0 05/30/02 13:33 KTV 10061-01-5
1.0 05/30/02 13:33 KTV 10061-02-6
1.0 05/30/02 13:33 KTV 108-20-3
1.0 05/30/02 13:33 KTV 100-41-4
1.0 05/30/02 13:33 KTV 87-68-3
1.0 05/30/02 13:33 KTV 98-82·8
1.0 05/30/02 13:33 KTV 99-87-6
1.0 05/30/02 13:33 KTV 75-09-2
1.0 05/30/02 13:33 KTV 1634-04-4
1.0 05/30/02 13:33 KTV 91-20-3
1.0 05/30/02 13:33 KTV 103-65-1
1.0 05/30/02 13:33 KTV 100-42·5
1.0 05/30/02 13:33 KTV 630-20-6
1.0 05/30/02 13:33 KTV 79-34-5
1.0 05/30/02 13:33 KTV 127-18-4
1.0 05/30/02 13:33 KTV 108-88-3
1.0 05/30/02 13:33 KTV 87-61-6
1.0 05/30/02 13:33 KTV 120-82-1
1.0 05/30/02 13:33 KTV 71-55-6
Page; 22
REPORT OF LABORATORY ANALYSIS Laboratory Certification IDs I
LA Wastewater 04034 This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,,_., ,. •eco~0~
o'/~,. fint:!ld.C11
VA Drinking Water 213
FL NELAP E87627 I
I
ace Analytical™
www.pacelabs.com
Lab Sample No: 922282652
Client Sample ID: MW-40
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Lab Project Number: 9233015
Phone.· 704.875.9092
Fax: [phone]
Client Project JD: NCSU Lot 86/2246
Project Sample Number: 9233015-009
Matrix: Water
Date Collected: 05/22/02 11:31
Date Received: 05/23/02 16:10
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I Parameters Results Units Reoort Limit ..QL Anal :tzed B~ CAS No. Q\!tl_ RegLmt
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1,1,2-Trichloroethane
Tri chl oroethene
Trichlorofluoromethane-
1,2,3·Tri chlorop(opahe
1,2,4-Trimethylbenzene
1,3,5-Trimeth)'ibenzene
~-. ••••y Vinyl chloride ./ .. ,,.
m&p-Xylene / _;-'
I ,-,o-.Xylene /,,,,
/-,...-1-Chl oro· 3 · fl uorobenzene (S) . '.' _,, ·_,..r
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Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
ND ug/1 0.50 1.0 05/30/02 13:33 KTV
ND ug/1 0.50 1.0 05/30/02 13:33 KTV
ND ug/1 0,50 1.0 05/30/02 13:33 KTV
ND ug/1 0.50 1.0 05/30/02 13:33 KTV
ND ug/1 0.50 1.0 05/30/02 13:33 KTV
ND ug/1 0.50 1.0 05/30/02 13:33 KTV
ND ug/1 0.50 1.0 05/30/02 13:33 KTV
ND ug/1 0.50 1.0 05/30/02 13:33 KTV
ND ug/1 0.50 1.0 05/30/02 13:33 KTV
102 X 1.0 05/30/02 13:33 KTV
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc. ~~,~"af+ .... t1neac\t
79-00·5
79-01·6
75.59.4
96·18·4
95·63·6
108-67-8
75-01·4
95.47.5
625·98·9
Page: 23
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
ace Analytical™ .
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
I
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www.pacelabs.com
Lab Project Number: 9233015
Lab Sample No: 922282710
Client Sample ID: MW-41
Parameters
Metals
Metals by Trace ICP
Arsenic
Barium
Cadmium .,
Chromium.>;•"' >
Mercury, CVMS, in Water
Mercury
Wet Chemistry
Ion Chromatography
Chloride
Nitrate
Sulfate
Alkalinity, Total
Alkalinity, Total
GC Volatiles
GC voes in water
Benzene
Bromobenzene
Broroochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butyl benzene
tert·Butylbenzene
Carbon tetrachloride
Chl orobenzene
Chloroethane
Chloroform
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
Client Project ID: NCSU Lot 86/2246
i Project Sample Number: 9233015·010 Date Collected:
Matrix: Water Date Received:
Results Units Re~rt Limit ...!lf_ Anal ~zed B~ CAS No. ·
Prep/Method:
0.020
0.50
ND
0.061
EPA 3010 / EPA 6010
0.035
4.4
ND
ND
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/l
Method: EPA 7470
ND mg/1
Method: EPA 300.0
7.2 mg/l
0.78
3.6
mg/1
mg/l
Method: EPA 310.1
10. mg/1
Method: SH 6230D
ND ug/1
ND ug/1
ND ug/1
ND ug/l
ND ug/1
ND ug/1
ND ug/l
ND ug/l
ND ug/l
ND ug/l
ND ug/l
ND ug/1
ND ug/l
0.0050 1.0 06/05/02 01:03 DJR 7440·38·2
0.0050 1. 0 06/28/02 DJR 7440·39-3
0.0010 1.0 06/05/02 01:03 DJR 7440·43·9
0.0020 1.0 06/05/02 01:03 DJR 7440·47-3
0.0050 1.0 06/05/02 01:03 DJR 7439·92·1
0.0050 1.0 06/05/02 01:03 DJR 7439·96·5
0.0050 1.0 06/05/02 01:03 DJR 7782·49-2
0.0020 1.0 06/05/02 01:03 DJR 7440·22-4
05/30/02
0.00020 1.0 06/03/02 LBG 7439·97-6
1.0 1.0 05/24/02 CBJ 16B87·00-6
CBJ 0.10
1.0
1.0
0,50
0.50
0.50
0.50
0.50
0.50
1.0
0.50
0.50
0.50
0.50
0.50
0.50
1. 0 05/24/02
1.0 05/24/02
1.0 05/31/02
CBJ
HEH
1.0 05/30/02 14:21 KTV
1.0 05/30/02 14:21 KTV
1.0 05/30/02 14:21 KTV
1.0 05/30/02 14:21 KTV
1.0 05/30/02 14:21 KTV
1.0 05/30/02 14:21 KTV
1.0 05/30/02 14:21 KTV
1.0 05/30/02 14:21 KTV
1.0 05/30/02 14:21 KTV
1.0 05/30/02 14:21 KTV
1.0 05/30/02 14:21 KTV
1.0 05/30/02 14:21 KTV
1.0 05/30/02 14:21 KTV
71.43.2
108·86·1
74.97.5
75-27-4
75-25-2
74-83·9
104-51·8
135·98·8
98-06-6
56-23-5
108·90·7
75-00·3
67-66·3
05/22/02 09:28
05/23/02 16: 10
~ RegLmt
Page: 24
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REPORT OF LABORATORY ANALYSIS Laboratory Certification IDs I
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,~ <eco,, ,K~~ ~nelac1t
LA Wastewater 04034
FL NELAP E87627
VA Drinking Water 213 1
I
I
I
I
ace Analytical™
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
www.pacelabs.com Phone: [phone]
Fax: [phone]
I
I
Lab Sample No: 922282710
Client Sample ID: MW-41
Parameters
Chlorornethane
2-Chlorotoluene
/
1,2·Dibromo·3·chloropropane
0ibromoch1 orom'eth~ne
1.2-Dibromo~i:h';ne (EDB)
4-Chlorotoluene
Di brarnorii'ethi:lne
1. 2 'Di d,i orobenzene ,•· •"C
I /l,3"·Dichlorobenzene
./,:·.> ·J , 4 • Di ch 1 orobenzene
d . · · Di chlorodi fl uoromethane
v,• 1,1-Dichloroethane
I 1,2-Dichloroethane
1.1-Dichloroethene
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cis-1.2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1.3-Dichloropropane
2,2-Dichloropropane
1,l·Dichloropropene
cis-1.3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethyl benzene
Hexachloro-1,3-butadiene
Isopropylbenzene (Cumene)
p-Isopropyltoluene
Methylene chloride
Methyl-tert·butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1.1.2.2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3·Trichlorobenzene
1,2.4-Trichlorobenzene
1.1,l·Trichloroethane
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
,,.
Lab Project Number: 9233015
Client Project ID: NCSU Lot 86/2246
< ·: . .--: :-. Project Sample Number: 9233015-010
Matrix: Water
Oate Collected: 05/22/02 09:28
Date Received: 05/23/02 16:10
Results Units
ND ug/7
ReQQrt Limit ..QL Anal ~zed B~
2.0 1.0 05/30/02 14:21 KTV
ND ug/7 0.50 1.0 05/30/02 14:21 KTV
ND ug/7 0.50 1.0 05/30/02 14:21 KTV
ND ug/7 2.0 1.0 05/30/02 14:21 KTV
ND ug/7 0.50 1.0 05/30/02 14:21 KTV
ND ug/7 0.50 1.0 05/30/02 14:21 KTV
ND ug/l 0.50 1.0 05/30/02 14:21 KTV
ND ug/7 1.0 1.0 05/30/02 14:21 KTV
ND ug/7 1.0 1.0 05/30/02 14:21 KTV
ND ug/7 -1.0 1.0 05/30/02 14:21 KTV
ND ug/7 0.50 1.0 05/30/02 14:21 KTV
ND ug/7 0.50 1.0 05/30/02 14:21 KTV
ND ug/7 0.50 1.0 05/30/02 14:21 KTV
ND ug/7 0.50 1.0 05/30/02 14:21 KTV
ND ug/7 0.50 1.0 05/30/02 14:21 KTV
ND ug/7 0.50 1.0 05/30/02 14:21 KTV
ND ug/7 0.50 1.0 05/30/02 14:21 KTV
ND ug/7 0.50 1.0 05/30/02 14:21 KTV
ND ug/7 0.50 1.0 05/30/02 14:21 KTV
ND ug/1 0.50 1.0 05/30/02 14:21 KTV
ND ug/7 0.5D 1.0 05/30/02 14:21 KTV
ND ug/7 0.50 1.0 05/30/02 14:21 KTV
ND ug/7 D.50 1.0 05/30/02 14:21 KTV
ND ug/7 0.50 1.0 05/30/02 14:21 KTV
ND ug/7 2.0 1.0 05/30/02 14:21 KTV
ND ug/7 0.50 1.0 05/30/02 14:21 KTV
ND ug/7 1.0 1.0 05/30/02 14:21 KTV
ND ug/7 2.0 1.0 05/30/02 14:21 KTV
ND ug/1 0.50 1.0 05/30/02 14:21 KTV
ND ug/7 2.0 1.0 05/30/02 14:21 KTV
ND ug/7 0.50 1.0 05/30/02 14:21 KTV
ND ug/7 0.50 1.0 05/30/02 14:21 KTV
ND ug/7 0.50 1.0 05/30/02 14:21 KTV
ND ug/1 0.50 1.0 05/30/02 14:21 KTV
ND ug/7 0.50 1.0 05/30/D2 14:21 KTV
ND ug/7 0.50 1.0 05/30/02 14:21 KTV
ND ug/7 2.0 1.0 05/30/02 14:21 KTV
ND ug/7 2.0 1.0 05/30/02 14:21 KTV
ND ug/7 0.50 1.0 05/30/02 14:21 KTV
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
~/_t _ 1'1.. ""'{.-,, .. ~
0
cco'10~+"
'1ne c, " -. \,
CAS No. ili!tl.. RegLmt
74-87-3
95·49-B
106-43-4
96·12-B
124-48-1
106-93·4
74.95.3
95·50·1
541-73·1
106-46·7
75·71·8
75.34.3
107-06·2
75.35.4
156-59·2
156-60-5
78·87·5
142-28·9
594-20·7
563-58·6
10061-01·5
10061·02·6
108-20·3
100-41-4
87·68·3
98·82·8
99-87-6
75-09·2
1634-04·4
91·20·3
103-65·1
100-42-5
630-20-6
79.34.5
127-18-4
108-88-3
87·61·6
120-82·1
71-55-6
Page: 25
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
ace Analytical™
www.pacelabs.com
Lab'Sample No: 922282710
Client Sample ID: MW-41
Parameters
l,I.2-Trichloroethane
Trichloroethene . ~ '..>
Tri ch1 orofl uoromethane 1
1, 2, 3· Tri chloropropan~
1.2,4-Trimethyib~~zene
1,3, 5-Trimethyi'benzene
Vinyl chloride
m&p-Xyle~e
/ . ,..-:g;-Xylene
Results Units
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
Lab Project Number: 9233015
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-010
Matrix: Water
Date Collected: 05/22/02.09:28
Date Received: 05/23/02 16:10
Reoort L 1 mi t ...ill;_ Analyzed By CAS No. !l!!tl_ RegLmt
0.50 1.0 05/30/02 14:21 KTV 79-00-5
0,50 1.0 05/30/02 14:21 KTV 79-01-6
0.50 1.0 05/30/02 14:21 KTV 75-69-4
0.50 1.0 05/30/02 14:21 KTV 96-18-4
0,50 1.0 05/30/02 14:21 KTV 95-63-6
0.50 1.0 05/30/02 14:21 KTV 108-67-8
0.50 1.0 05/30/02 14:21 KTV 75-01-4
0.50 1.0 05/30/02 14:21 KTV
0,50 1.0 05/30/02 14:21 KTV 95-47-6 ,.<,/ l-Chloro-3-fluorobenzene (S) ~/ .. '
ND
ND
ND
ND
ND
ND
ND
ND
ND
100 t 1.0 05/30/02 14:21 KTV 625-98-9
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
_.,.(,,•·· i.;,. .....
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Page; 26
Laboratory Certification IDs I
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627 I
I
I
I
I
I
I
ace Analytical™
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone] www.pacelabs.com Lab Project Number: 9233015
Lab Sample No: 922282728
Client Sample ID: MW-411
Parameters
Metals
Metals by Trace JCP
Arsenic
Barium
Cadmium
Chromium .
Lead · , , ~ ,_,,.,
Manganese
I ,/.~f1e~ium
/{,.-~Silver .r ,,
.f'. .Ji-_,,, Date Digested
r
I
I
I
I
I
I
I
I
I
I
I
Mercury. CVMS, in Water
Mercury
Wet Chemistry
Ion Chromatography
Chloride
Nitrate
Sulfate
Alkalinity. Total
Alkalinity. Total
GC Volatiles
GC voes in Water
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butyl benzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chl oroethane
Chloroform
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
Client Project JD: NCSU Lot 86/2246
Project Sample Number: 9233015-011
Matrix: Water
Date Collected: 05/22/02 09:53
Date Received: 05/23/02 16:10
Results Units Report Limit Jlf___ Analyzed By CAS No. Q!!tl_ RegLmt
Prep/Method:
ND
0.029
0.0010
0.041
ND
0.072
ND
ND
EPA 3010 / EPA 6010
mg/l 0.0050
mg/l 0.0050
mg/1 0. 0010
mg/l 0.0020
mg/1 0.0050
mg/l 0.0050
mg/l 0.0050
mg/1 0.0020
Method: EPA 7470
1.0 06/05/02 01:08 DJR 7440·38·2
1. 0 06/28/02 DJR 7440-39-3
1.0 06/05/02 01:08 DJR 7440-43-9
1.0 06/05/02 01:08 DJR 7440-47-3
1.0 06/05/02 01:08 DJR 7439-92-1
1.0 06/05/02 01:08 DJR 7439-96-5
1.0 06/05/02 01:08 DJR 7782·49-2
1.0 06/05/02 01:08 DJR 7440-22-4
05/30/02
ND mg/1 D.D0020 1.0 06/03/02 LBG 7439-97-6 -
Method: EPA 300.0
2.4 mg/l
0.29 mg/1
1.0
0.10
1.0
1.0 05/24/02
1. 0 05/24/02
1.0 05/24/02
CBJ 16887-00-6
CBJ
1.4 mg/1 CBJ
Method: EPA 310.1
15. mg/l 1.0 1. 0 05/31/02 HEH
Me_thod: SM 6230D
ND ug/1 0.50 1.0 05/30/02 15:08 KTV
ND ug/l 0.50 1.0 05/30/02 15:08 KTV
ND ug/1 0.50 1. 0 05/30/02 15: OB KTV
ND ug/l 0.50 1.0 05/30/02 15:08 KTV
ND ug/l 0.50 1.0 05/30/02 15:08 KTV
ND ug/l 0.50 1.0 05/30/02 15:08 KTV
ND ug/1 1.0 1.0 05/30/02 15:08 KTV
ND ug/1 0.50 1.0 05/30/02 15:08 KTV
ND ug/l 0.50 1.0 05/30/02 15:08 KTV
ND ug/l 0.50 1.0 05/30/02 15:08 KTV
ND ug/l 0.50 1.0 05/30/02 15:08 KTV
ND ug/l 0.50 1.0 05/30/02 15:08 KTV
ND ug/l 0.50 1.0 05/30/02 15:08 KTV
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,~ ~cea~
/?'CJ~, IiO~aC\t
71-43-2
108-86-1
74-97-5
75-27-4
75-25-2
74-83·9
104-51-8
135-98-8
98-06-6
56-23-5
108-90-7
75-00-3
67-66-3
Page: 27
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
ace Analytical™
www.pacelabs.com
Lab Sample No: 922282728
Client Sample ID: MW-411
Parameters
Chloromethane
2-Chlorotol uene
4-Chlorotoluene ,,i ., ·
1,2-Dibromo-3-chloropropane
Dibromochloro~thane
1. 2-Di bromoeth~ne (EDB)
Di bromorilettlane
1, 2 ~ Di Chi orobenzene
,r.(3 :~oi chl orobenzene · /,,,.-,,.,<_;:-' 1,4-0i chlorobenzene
Results
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Lab Project Number: 9233015
Client Project ID: NCSU Lot 86/2246
Phone: [phone]
Fax: [phone]
Project Sample Number: 9233015-011
Matrix: Water
Date Collected: 05/22/02 09:53
Date Received: 05/23/02 16:10
Reoort Limit ....QE__ Analyzed By
2.0 1.0 05/30/02 15:08 KTV
0.50 1.0 05/30/02 15:08 KTV
~C~AS~N~o~. _ lli@L ReqLmt
74-87-3
95-49-8
0.50 1.0 05/30/02 15:08 KTV 106-43-4
2.0 1.0 05/30/02 15:08 KTV 96-12·8
0.50 1.0 05/30/02 15:08 KTV 124-48-1
0.50 1.0 05/30/02 15:08 KTV 106-93-4
0.50 1.0 05/30/02 15:08 KTV 74-95-3
1.0 1.0 05/30/02.15:0B.KTV-95·:5oc1
1.0 1.0 05/30/02 15:08 KTV 541-73-1
,,,,:::,.. · Di chl orodi fl uoromethane .-.,
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Units
ug/l
ug/l
ug/1
ug/l
ug/l
ug/l
ug/l
ug/l
ug/1
ug/l
ug/l
ug/l
ug/1
ug/l
ug/l
ug/l
ug/1
ug/l
ug/l
ug/1
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
1.0 1.0 05/30/02 15:08 KTV 106-46-7
0.50 1.0 05/30/02 15:08 KTV 75-71•8
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
1,l·Dichloroethane
1.2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1.3-Dichloropropane
2,2-Dichloropropane
1.1-Dichloropropene
cis-1.3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethyl benzene
Hexachloro-1,3-butadiene
lsopropylbenzene (Cumene)
p-lsopropyltoluene
Methylene chloride
Hethyl-tert-butyl ether
Naphthalene
n-Propyl benzene
Styrene
1.1,1,2-Tetrachloroethane
1.1.2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1.2.3-Trichlorobenzene
1.2.4-Trichlorobenzene
1,1,1-Trichloroethane
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0,50
2.0
0.50
1.0
2.0
0.50
2.0
0.50
0.50
0.50
0.50
0,50
'-0. 50
2.0
2.0
0.50
1.0 05/30/02 15:08 KTV 75-34-3
1.0 05/30/02 15:08 KTV 107-06-2
1.0 05/30/02 15:08 KTV 75-35-4
1.0 05/30/02 15:08 KTV 156-59-2
1.0 05/30/02 15:08 KTV 156-60-5
1.0 05/30/02 15:08 KTV 78-87-5
1.0 05/30/02 15:08 KTV 142-28·9
1.0 05/30/02 15:08 KTV 594-20-7
1.0 05/30/02 15:08 KTV 563-58-6
1.0 05/30/02 15:08 KTV 10061-01-5
1.0 05/30/02 15:08 KTV 10061-02-6
1.0 05/30/02 15:08 KTV 108-20-3
1.0 05/30/02 15:08 KTV 100-41-4
1.0 05/30/02 15:08 KTV 87-68-3
1.0 05/30/02 15:08 KTV 98-82-8
1.0 05/30/02 15:08 KTV 99-87-6
1.0 05/30/02 15:08 KTV 75-09-2
1.0 05/30/02 15:08 KTV 1634-04-4
1.0 05/30/02 15:08 KTV 91-20-3
1.0 05/30/02 15:08 KTV 103-65•1
1.0 05/30/02 15:08 KTV 100-42-5
1.0 05/30/02 15:08 KTV 630-20-6
1.0 05/30/02 15:08 KTV 79.3·4.5
1.0 05/30/02 15:08 KTV 127-18-4
1.0 05/30/02 15:08 KTV 108-88-3
1.0 05/30/02 15:08 KTV 87-61-6
1.0 05/30/02 15:08 KTV 120-82-1
1.0 05/30/02 15:08 KTV 71-55·6
Page: 2B
REPORT OF LABORATORY ANALYSIS Laboratory Certification IDs I
LA Wastewater 04034 This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc. VA Drinking Water 213
FL NELAP E87627 I
I
:1
I
I
I
I
ace Analytical'"
www.pacelabs.com
Lab Sample No: 922282728
Client Sample ID: MW-411
Parameters
1.1.2-Trichloroethane
Trichloroethene
Tri chl orofl uorornethane·'
1. 2. 3-Tri chl oroprop~ne
1,2,4-Trimethylbenzene
1,3,5-Trimethyi'benzene ,. ,,,
Vinyl chloride
/ F m&p'Xylene
. '!'
Results
ND
ND
ND
ND
ND
ND
ND
ND
Units
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Lab Project Number: 9233015
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-011 Date Collected: 05/22/02 09:53
Date Received: 05/23/02 16:10 Matrix: Water
Re12ort Limit ...QL Analyzed By CAS No, ~ Reglmt
0.50 1.0 05/30/02 15:08 KTV 79-00-5
0.50 1.0 05/30/02 15:08 KTV 79-01-6
0.50 1.0 05/30/02 15:08 KTV 75-69-4
0.50 1.0 05/30/02 15:0B KTV 96-18-4
0.50 1.0 05/30/02 15:08 KTV 95-63-6
0.50 1.0 05/30/02 15:08 KTV 10B-67-8
0.50 1.0 05/30/02 15:08 KTV 75-01-4
0.50 1.0 05/30/02 15:08 KTV
,r'. ( xii ene I ,.,.-;:;,-''1-Chloro-3-fluorobenzene (Sl
·-~" :?'•,
ND ug/1
107 t
0.50 1.0 05/30/02 15:08 KTV 95-47-6
1.0 05/30/02 15:08 KTV 625-98-9
I
I
I
I
I
I
I
I
I
I
I
I
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
\M He~~
,.11~~ .. .!>'/ l_:f". y,.. ?Z□t:1aC1t
Page: 29
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
ace Analytical™
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
www.pacelabs.com
Lab Project Number: 9233015
Lab Sample No: 922282785
Client Sample ID: MW-421
Parameters
Metals
Metals by Trace ICP
Arsenic
Barium
Cadmium
Chromium _.. , .
Lead (,\>
ManganeS"e <'."_;,-_.•Selenium
~ , . .,,-
,,r' :1-· Silver
.,,._:-[~/,. Date Digested
~/"
Mercury. CVMS. in Water
Mercury
Wet Chemistry
Ion Chromatography
Chloride
Nitrate
Sulfate
Alkalinity. Total
Alkalinity. Total
GC Volatiles
GC voes in Water
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butyl benzene
sec-Butyl benzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
0ate: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
/
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015·012
Matrix: Water
Date Collected: 05/22/02 10:23
Date Received: 05/23/02 16:10
Results Units Report Limit _QE__ Analyzed By CAS No. 9@!_ RegLmt
Prep/Method: EPA 3010 / EPA 6010
ND mg/1 0.0050 1.0 06/05/02 01:13 DJR
0.048 mg/1 0.0050 1. 0 06/28/02 DJR
0.0035 mg/1 0.0010 1.0 06/05/02 01:13 DJR
0.052 mg/1 0.0020 1.0 06/05/02 01:13 DJR
ND mg/1 0.0050 1.0 06/05/02 01:13 DJR
0.43 mg/1 0.0050 1.0 06/05/02 01:13 DJR
ND mg/1 0.0050 1.0 06/05/02 01:13 DJR
ND mg/1 0.0020 1.0 06/05/02 01:13 DJR
05/30/02
Method: EPA 7470
ND mg/1 0.00020 1. 0 06/03/02 LBG
Method: EPA 300.0
2.2 mg/1 1.0 1.0 05/24/02 CBJ
0.16 mg/1 0.10 1. 0 05/24/02 CBJ
3.2 mg/1 1.0 1.0 05/24/02 CBJ
Method: EPA 310.1
65. mg/1 1.0 1. 0 05/31/02 HEH
Method: SH 62300
ND ug/1 0.50 1.0 05/30/02 16:41 KTV
ND ug/1 0.50 1.0 05/30/02 16:41 KTV
ND ug/1 0.50 1.0 05/30/02 16:41 KTV
ND ug/1 0.50 1.0 05/30/02 16:41 KTV
ND ug/1 0.50 1.0 05/30/02 16:41 KTV
ND ug/1 0.50 1.0 05/30/02 16:41 KTV
ND ug/1 1.0 1.0 05/30/02 16:41 KTV
ND ug/1 0.50 1.0 05/30/02 16:41 KTV
ND ug/1 0.50 1.0 05/30/02 16:41 KTV
ND ug/1 0.50 1.0 05/30/02 16:41 KTV
ND ug/1 0.50 1.0 05/30/02 16:41 KTV
ND ug/1 0.50 1.0 05/30/02 16:41 KTV
0.91 ug/1 0.50 1.0 05/30/02 16:41 KTV
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,,. •cc.,~ ~ lnelaat
7440-38·2
7440-39-3
7440-43-9
7440-47-3
7439-92-1
7439-96-5
7782-49-2
7440-22-4
7439-97-6
16887-00-6
71-43-2
108-86-1
74.97.5
75-27-4
75-25-2
74-83-9
104-51-8
135-98-8
98-06·6
56-23-5
108-90-7
75-00·3
67-66-3
Page: 30
Laboratory Certification IDs I
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627 I
I
.I
I
I
ace Ana/yticar·
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax. [phone] www.pacelabs,com
Lab Sample No: 9222B2785
Client Sample ID: MW-421
Lab Project Number: 9233015
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-012
Matrix: Water
Date Collected: 05/22/02 10:23
Date Received: 05/23/02 16:10
Parameters Results Units
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
Report Limit ..ill_ Analyzed By CAS No.
I
I
Chloromethane
2 ·Chl oroto l uene
4-Chl orotol uene
1.2-Dibromo-3-chforopropane
Dibromochloramethane
,,f ,,
1,2-Dibrooo~thane (EDB)
Dibromolllethane
1. 2 -oi~·hl orobenzene ,••,·,,.
I _.rl;3-Dich1orobenzene
,.-<' ~r"l·. 4 ·Di Chl orobenzene
,,1),,.: ' Di chl orod1fl uoromethane
I
I
I
I
I
I
I
I
I
I
I
I
1,1-Dichloroethane
1.2-Dichloroethane
1.1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1.3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1.3-0ichloroprope~e
Diisopropyl ether
Ethyl benzene
Hexachloro-1.3-butadiene
lsopropylbenzene (Cumene)
p-Isopropyltoluene
Methylene chloride
Methyl-tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
D11te: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
NO
ND
NO
ND
ND
2.0 1.0 05/30/02 16:41 KTV 74-87-3
0.50 1.0 05/30/02 16:41 KTV 95-49-8
0.50 1.0 05/30/02 16:41 KTV 106-43-4
2.0 1.0 05/30/02 16:41 KTV 96-12-8
0,50 1.0 05/30/02 16:41 KTV 124-48-1
0.50 1.0 05/30/02 16:41 KTV 106-93-4
0.50 1.0 05/30/02 16:41 KTV 74-95-3
1,0 1.0 05/30/02 16:41 KTV 95-50-1
1.0 1,0 05/30/02 16:41 KTV 541-73-1
1,0 1.0 05/30/02 16:41 KTV 106-46-7
0.50 1.0 05/30/02 16:41 KTV 75-71-8
0.50 1.0 05/30/02 16:41 KTV 75-34-3
0.50 1.0 05/30/02 16:41 KTV 107-06-2
0.50 1.0 05/30/02 16:41 KTV 75,35.4
0,50 1.0 05/30/02 16:41 KTV 156-59-2
0,50 1.0 05/30/02 16:41 KTV 156-60-5
0.50 1.0 05/30/02 16:41 KTV 78-87-5
0.50 1,0 05/30/02 16:41 KTV 142-28-9
0.50 1.0 05/30/02 16:41 KTV 594-20-7
0.50 1.0 05/30/02 16:41 KTV 563-58-6
0.50 1.0 05/30/02 16:41 KTV 10061-01-5
0,50 1.0 05/30/02 16:41 KTV 10061-02-6
0.50 1.0 05/30/02 16:41 KTV 108-20-3
0.50 1.0 05/30/02 16:41 KTV 100-41-4
2.0 1.0 05/30/02 16:41 KTV 87-68-3
0.50 1.0 05/30/02 16:41 KTV 98-82-8
1.0 1.0 05/30/02 16:41 KTV 99-B7-6
2.0 1.0 05/30/02 16:41 KTV 75-09-2
0.50 1.0 05/30/02 16:41 KTV 1634-04-4
2.0 1.0 05/30/02 16:41 KTV 91-20-3
0.50 1.0 05/30/02 16:41 KTV 103-65-1
0,50 1.0 05/30/02 16:41 KTV 100-42-5
0.50 1.0 05/30/02 16:41 KTV 630-20-6
0.50 1.0 05/30/02 16:41 KTV 79-34-5
0,50 1.0 05/30/02 16:41 KTV 127-18-4
0.50 1.0 05/30/02 16:41 KTV 108-88-3
2.0 1.0 05/30/02 16:41 KTV 87-61-6
2,0 1.0 05/30/02 16:41 KTV 120-82-1
0.50 1.0 05/30/02 16:41 KTV 71-55-6
Page: 31
REPORT OF LABORATORY ANALYSIS Laboratory Certification IDs
LA Wastewater 04034
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,~ •cco~
a'7)(~ i1ne@c~
VA Drinking Water 213
FL NELAP E87627
ace Analytical™ .
www.pacelabs.com
Lab Sample No: 922282785
Client Sample ID: MW-421
Parameters Results
1.1.2-Trichloroethane ND
Trichloroethene NO
Trichlorofluorometha~e· ND
1.2.3-Trichloropfopa';e ND
1.2.4-Trimethylb.enzene ND
1.3.5-Trimethyibenzene ND
Vinyl. ch]o~ide ND
m&p'8ylene ND
Lab Project Number: 9233015
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015·012
Matrix: Water
Date Collected: 05/22/02 10:23
Date Received: 05/23/02 16:10
Re11Qrt Limit ...QL Analyzed Bi CAS No. ~ RegLmt
0.50 1.0 05/30/02 16:41 KTV 79-00-5
0.50 1.0 05/30/02 16:41 KTV 79-01-6
0.50 1.0 05/30/02 16:41 KTV 75-69-4
0.50 1.0 05/30/02 16:41 KTV 96-1B-4
0.50 1.0 05/30/02 16:41 KTV 95-63-6
0.50 1.0 05/30/02 16:41 KTV 108-67·8
0.50 1.0 05/30/02 16:41 KTV 75-01-4
0.50 1.0 05/30/02 16:41 KTV
95-47-6 ,✓6,Xylene ND
_,,:,'.'.>"i·-Chloro-3-fluorobenzene (S) 105
~:-.:->"°'
Units
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
k
0.50 1.0 05/30/02 16:41 KTV
1.0 05/30/02 16:41 KTV 625-9B-9
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,-
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
~,~~~
t1n~aC\t
Page: 32
Laboratory Certification IDs I
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627 I
I
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I
ace Analytical™
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone] www.pacelabs.com
I
Lab Sample No: 922282793
Client Sample ID: MW-43
Parameters
Metals
Metals by Trace ICP
Arsenic , --. -1 ,/
Barium
Cadmium
Chromium
Lead .. ,-:_,,
MJ~9.~nese
I ("'Selenium
/· ~/ ,:r·~Silver , ,
,,/-· Date Digested
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Mercury, CVMS, in Water
Mercury
Wet Chemistry
Ion Chromatography
Chloride
Nitrate
Sulfate
Alkalinity, Total
Alkalinity, Total
GC Volatiles
GC voes in Water
Benzene
Bro100benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromornethane
n-Butylbenzene
sec-Butyl benzene
tert-Butylbenzene
Carbon tetrachloride
Chl orobenzene
Chloroethane
Chloroform
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
Lab Project Number: 9233015
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-013
Matrix: Water
Date Collected: 05/22/02 07:41
Date Received: 05/23/02 16:10
Results Units Report Limit ..QE.__ Anal yzed By CAS No. _ !l!!tl_ RegLmt
Prep/Method: EPA 3010 / EPA 6010
0.0058 mg/1 0.0050 1.0 06/05/02 01:17 DJR 7440-38-2
0 .050 m9/l 0.0050 1.0 06/28/02 DJR 7440-39-3
ND mg/l 0.0010 1.0 06/05/02 01:17 DJR 7440-43-9
O .049 mg/1 0.0020 1.0 06/05/02 01:17 DJR 7440-47-3
0. 0062 mg/l 0.0050 1.0 06/05/02 01:17 DJR 7439-92-1
0.28 mg/l 0.0050 1.0 06/05/02 01:17 DJR 7439-96-5
ND mg/l 0.0050 1.0 06/05/02 01:17 DJR 7782-49-2
ND mg/l 0.0020 1.0 06/05/02 01:17 DJR 7440-22-4
05/30/02
Method: EPA 7470
ND mg/l 0.00020 I. 0 06/03/02 L8G 7439-97-6
Method: EPA 300.0
2.7 mg/l
0.15 mg/1
1.0
0.10
1.0
1.0 05/24/02
1.0 05/24/02
I. 0 05/24/02
C8J 16887-00-6
C8J
1.3 mg/l
Method: EPA 310.1
15. mg/l
Method: SM 62300
ND u9/l
ND ug/1
ND ug/l
ND u9/l
ND ug/l
ND ug/l
ND ug/1
ND ug/l
ND ug/l
ND ug/l
ND ug/l
ND ug/l
8.1 ug/1
CBJ
1.0 I. 0 05/31/02 HEH
0.50 1.0 06/02/02 14:47 KTV
0.50 1.0 06/02/02 14:47 KTV
0.50 1.0 06/02/02 14:47 KTV
0.50 1.0 06/02/02 14:47 KTV
0.50 1.0 06/02/02 14:47 KTV
0.50 1.0 06/02/02 14:47 KTV
1.0 1.0 06/02/02 14:47 KTV
0.50 1.0 06/02/02 14:47 KTV
0.50 1.0 06/02/02 14:47 KTV
0.50 1.0 06/02/02 14:47 KTV
0.50 1.0 06/02/02 14:47 KTV
0.50 1.0 06/02/02 14:47 KTV
0.50 1.0 06/02/02 14:47 KTV
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,~ ~tea~ _,1/it,~-?i□eac11
71-43-2
108-86-1
74-97-5
75-27-4
75-25-2
74-83-9
104-51-8
135-98-8
98-06-6
56-23-5
108-90-7
75-00-3
67-66-3
Page: 33
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
ace Analytical™
www.pacelabs.com
Lab Sample No: 922282793
Client Sample ID: HW-43
~P~ar~a~me~t~e~r~s _______ .·-'-''-'\_:,,·_ --"R,,,_es,,,u,.,_lects'---Units
Chloromethane ND ug/1
2-Chlorotoluene ND ug/1
4-Chlorotoluene ND ug/l
l.2-Dibromo-3-chloropropane ND ug/l
Dibromochloromethine ND ug/1
1.2-Dibromcetliane (EDB) ND ug/l
Di bromcmeti,~ne ND ug/l
1,:2_-9.ichlorobenzene ND ug/l
/;·.3'Dichlorobenzene ND ug/1
/;,' '1,4-Dichlorobenzene ND ug/1
.<' > Di chl orodi fl uoromethane ND ug/1
;> 1. 1-Dichloroethane ND ug/1
1,2-Dichloroethane
1.1-Dichloroethene
cis-1.2-Dichloroethene
trans-1.2-Dichloroethene
1,2-Dichloropropane
1.3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1.3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethyl benzene
Hexachloro-1.3-butadiene
Isopropylbenzene (Cumene)
p-Isopropyltoluene
Methylene chloride
Methyl-tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1.1.2,2·Tetrachloroethane
Tetrachloroethene
Toluene
1.2,3-Trichlorobenzene
1,2.4-Trichlorobenzene
1.1.1-Trichloroethane
Date: 06/29/02
ND ug/1
ND ug/l
ND ug/1
ND ug/l
ND ug/1
ND ug/1
ND ug/l
ND ug/l
ND ug/l
ND ug/l
ND ug/l
ND ug/l
ND ug/l
ND ug/l
ND ug/1
ND ug/l
ND ug/1
ND ug/1
ND ug/1
ND ug/l
ND ug/1
ND ug/1
ND ug/l
ND ug/1
ND ug/l
ND ug/l
ND ug/l
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100 .
Huntersville, NC 28018
Lab Project Number: 9233015
Client Project ID: NCSU Lot 86/2246
Phone: [phone]
Fax: [phone]
Project Sample Number: 9233015-013
Matrix: Water
Date Collected: 05/22/02 07:41
Date Received: 05/23/02 16:10
Report Limit __QE__ Analyzed By CAS No.
2.0 1.0 06/02/02 14:47 KTV 74-87-3
0.50 1.0 06/02/02 14:47 KTV 95-49-8
0.50 1.0 06/02/02 14:47 KTV 106-43-4
2.0 1.0 06/02/02 14:47 KTV 96-12·8
0.50 1.0 06/02/02 14:47 KTV 124-48-1
0.50 1.0 06/02/02 14:47 KTV 106-93-4
0.50 1.0 06/02/02 14:47 KTV 74-95·3
1.0
1.0
1.0
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
2.0
0.50
1.0
2.0
0.50
2.0
0.50
0.50
0.50
0.50
0.50
0.50
2.0
2.0
0.50
1.0 06/02/02 14:47 KTV 95-50-1
1.0 06/02/02 14:47 KTV 541-73-1
1.0 06/02/02 14:47 KTV 106-46-7
1.0 06/02/02 14:47 KTV 75-71-8
1.0 06/02/02 14:47 KTV 75-34-3
1.0 06/02/02 14:47 KTV 107-06-2
1.0 06/02/02 14:47 KTV 75-35-4
1.0 06/02/02 14:47 KTV 156-59-2
1.0 06/02/02 14:47 KTV 156·60-5
1.0 06/02/02 14:47 KTV 78-87-5
1.0 06/02/02 14:47 KTV 142-28·9
1.0 06/02/02 14:47 KTV 594-20-7
1.0 06/02/02 14:47 KTV 563-58-6
1.0 06/02/02 14:47 KTV 10061-01-5
1.0 06/02/02 14:47 KTV 10061-02-6
1.0 06/02/02 14:47 KTV 108-20-3
1.0 06/02/02 14:47 KTV 100-41-4
1.0 06/02/02 14:47 KTV 87-68-3
1.0 06/02/02 14:47 KTV 98-82-8
1.0 06/02/02 14:47 KTV 99-87-6
1.0 06/02/02 14:47 KTV 75-09-2
1.0 06/02/02 14:47 KTV 1634-04-4
1.0 06/02/02 14:47 KTV 91-20-3
1.0 06/02/02 14:47 KTV 103-65-1
1.0 06/02/02 14:47 KTV 100·42-5
1.0 06/02/02 14:47 KTV 630-20-6
1.0 06/02/02 14:47 KTV 79-34·5
1.0 06/02/02 14:47 KTV 127-18-4
1.0 06/02/02 14:47 KTV 108-88-3
1.0 06/02/02 14:47 KTV 87-61·6
1.0 06/02/02 14:47 KTV 120-82-1
1.0 06/02/02 14:47 KTV 71-55-6
Page; 34
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Laboratory Certification IDs
NC Wastewater 12 REPORT OF LABORATORY ANALYSIS Laboratory Certification IDs I
LA Wastewater 04034
NC Drinking Water 37706
SC 99006
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,~ Ht~~ ~ lnelaai
VA Drinking Water 213
FL NELAP E87627 I
I
ace Analytical™
www.pacetabs.com
Lab Sample No: 922282793
Client Sample ID: MW-43 ; . '
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Lab Project Number: 9233015
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-013
Matrix: Water
Date Collected: 05/22/02 07:41
Date Received:. 05/23/02 16: 10
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Parameters Results Units Reoort Limit ___Q[_ Analyzed By CAS No. ~ RegLmt
1.1.2-Trichloroethane
Trichloroethene .·'-·
Tri chl orofl uoromethan.✓ , -; 1.2.3-Trichlorgpropane
1,2,4-Trimethylbenzene
I 1,3.5-Trimethyfbenzene
Vinyl .chloride
m&p,Jiyi'e~e
I /o,Xyl ene
!'_,:;;.-' 1-Chloro-3-fluorobenzene (S)
.,:.,,,•' :.•'
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Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
ND ug/l 0.50 1.0 06/02/02 14:47 KTV
ND ug/l 0.50 1.0 06/02/02 14:47 KTV
ND ug/l 0.50 1.0 06/02/02 14:47 KTV
ND ug/1 0.50 1.0 06/02/02 14:47 KTV
ND ug/l 0.50 1.0 06/02/02 14:47 KTV
ND ug/l 0.50 1.0 06/02/02 14:47 KTV
ND ug/l 0.50 1.0 06/02/02 14:47 KTV
ND ug/l 0.50 1.0 06/02/02 14:47 KTV
ND ug/l 0.50 1.0 06/02/02 14:47 KTV
99 X 1.0 06/02/02 14:47 KTV
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,~ •cco,. '~~ ~nelac\t
79-00-5
79·01-6
75-69·4
96-18-4
95-63-6
108-67•8
75-01-4
95-47-6
625-98-9
Page: 35
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
ace Analytical™
www.pacelabs.com
Lab Sample No: 922282801
Client Sample ID: MW·45
Parameters .t
Metals
Metals by Trace ICP ,... ,.
Arsenic
Barium
Cadmium
Chromium
Lead/:·.·
Maniane'se
&S~l{niurn ~-
.. I • . -'
Results
Prep/Method:
0,049
0.17
ND
0.062
0.020
1.2
ND
Units
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Lab Project Number: 9233015
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015·014
Matrix: Water
Date Collected: 05/22/02 08:21
Date Received: 05/23/02 16:10
Report Limit _QL_ _ _,,A,,,na.,l..,y:,ze.,d'---"B.,_y -.,C,cA:,:S_.N,,.os., _ !l!!tl_ RegLmt
EPA 3010 / EPA 6010
mg/1 0.0050 !,O 06/05/02 01:37 DJR 7440,38,2
mg/1 0,0050 I. 0 06/28/02 OJR 7440,39,3
mg/1 0 .0010 1.0 06/05/02 01:37 DJR 7440,43.9
mg/1 0.0020 1.0 06/05/02 01:37 DJR 7440,47-3
mg/1 0.0050 1.0 06/05/02 01:37 DJR 7439,92,1
mg/1 0.0050 1.0 06/05/02 01:37 DJR 7439,96,5
mg/1 0.0050 1.0 06/05/02 01:37 OJR 7782,49,2
, .,.1Y Si.1 ver
.,.-1_:f,.,~;-' Date Digested
'/
ND mg/1 0.0020 1.0 06/05/02 01:37 DJR 7440,22,4
05/30/02
Mercury. CVAAS, in Water
Mercury
Wet Chemistry
Ion Chromatography
Chloride
Nitrate
Sulfate
Alkalinity, Total
Alkalinity, Total
GC Volatiles
GC voes in Water
Benzene
Brmoobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butyl benzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
Method: EPA 7470
ND mg/1
Method: EPA 300.0
2,8 mg/1
0,88 mg/1
ND mg/1
Method: EPA 310.1
20, mg/1
Method: SM 6230D
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
0.00020 1.0 06/03/02 LBG 7439,97 ,6
1.0
0,10
1.0
1.0
0.50
0,50
0,50
0.50
0.50
0.50
1.0
a.so
0,50
0,50
0,50
0,50
0.50
1.0 05/24/02
I. 0 05/24/02
1.0 05/24/02
CBJ 16887,00-6
CBJ
C8J
I. 0 06/04/02 HEH
1.0 05/31/02 03:42 KTV 71-43•2
1.0 05/31/02 03:42 KTV 108-86·1
J.0 05/31/02 03:42 KTV 74-97-5
1.0 05/31/02 03:42 KTV 75-27-4
1.0 05/31/02 03:42 KTV 75·25·2
1.0 05/31/02 03:42 KTV 74·83·9
1.0 05/31/02 03:42 KTV 104-51·8
1.0 05/31/02 03:42 KTV 135-98-8
1.0 05/31/02 03:42 KTV 98-06·6
1.0 05/31/02 03:42 KTV 56·23·5
1.0 05/31/02 03:42 KTV 108-90-7
1.0 05/31/02 03:42 KTV 75·00-3
1.0 05/31/02 03:42 KTV 67-66-3
Page: 36
REPORT OF LABORATORY ANALYSIS Laboratory Certification IDs
LA Wastewater 04034 This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,~ HCq~
t~-f/Ot::kiC\l
VA Drinking Water 213
FL NELAP E87627
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ace Analytical™
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone] www.pacelabs.com
Lab Sample No: 922282801
Client Sample ID: MW-45
Lab Project Number: 9233015
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-014
Matrix: Water
Date Collected: 05/22/02 08:21
Date Received: 05/23/02 16:10
Parameters Results Units Reoort Limit ...Q[_ Anal lZed Bl CAS No. !ll!fil._ RegLmt
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Chloromethane
2-Chlorotoluene
4 ·Chl oroto l uene
1.2·Dibromo-3·chloropropane
Dibromochlorolllethane
' l ·~·-1. 2 •Di br~m(fothane (EDB)
Di bro1001Tlettiane
1 :,,2 ~ 9:i thl orobenzene
I /--~· 3·:o; chlorobenzene
/;> 1,4-Dichlorobenzene
J.,-Dichlorodifluoromethane
; J· .. · l. l·Dichloroethane
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1.2-Dichloroethane
1.1-Dichloroethene
cis-1,2-Dichloroethene
trans-1.2-Dichloroethene
1,2-Dichloropropane
1.3-Dichloropropane
2.2-Dichloropropane
1,l·Dichloropropene
cis-1,3-0ichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethyl benzene
Hexachloro-1,3-butadiene
Isopropylbenzene (Cumene)
p·Isopropyltoluene
Methylene chloride
Methyl-tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1.1.2-Tetrachloroethane
1,1,2.2-Tetrachloroethane
Tetrachloroethene
Toluene
1.2,3-Trichlorobenzene
1.2.4-Trichlorobenzene
1.1.l·Trichloroethane
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
ND ug/1 2.0 1.0 05/31/02 03:42 KTV 74-87-3
ND ug/1 0.50 1.0 05/31/02 03:42 KTV 95-49-8
ND ug/1 0.50 1.0 05/31/02 03:42 KTV 106-43-4
ND ug/1 2.0 1.0 05/31/02 03:42 KTV 96-12-8
ND ug/1 0.50 1.0 05/31/02 03:42 KTV 124·48-l
ND ug/1 0.50 1.0 05/31/02 03:42 KTV 106-93-4
ND ug/1 0.50 1.0 05/31/02 03:42 KTV 74.95.3
ND ug/1 1.0 1.0 05/31/02 03:42 KTV 95-50-1
ND ug/1 1.0 1.0 05/31/02 03:42 KTV 541-73-1
ND ug/1 1.0 1.0 05/31/02 03:42 KTV 106-46-7
ND ug/1 0.50 1.0 05/31/02 03:42 KTV 75-71-8
ND ug/1 0.50 1.0 05/31/02 03:42 KTV 75.34.3
ND ug/1 0.50 1.0 05/31/02 03:42 KTV 107-06-2
ND ug/1 0.50 1.0 05/31/02 03:42 KTV 75.35.4
ND ug/1 0.50 1.0 05/31/02 03:42 KTV 156-59-2
ND ug/1 0.50 1.0 05/31/02 03:42 KTV 156-60-5
ND ug/1 0.50 1.0 05/31/02 03:42 KTV 78-87-5
ND ug/1 0.50 1.0 05/31/02 03:42 KTV 142-28-9
ND ug/1 0.50 1.0 05/31/02 03:42 KTV 594-20-7
ND ug/1 0.50 1.0 05/31/02 03:42 KTV 563-58-6
ND ug/1 0.50 1.0 05/31/02 03:42 KTV 10061-01-5
ND ug/1 0.50 1.0 05/31/02 03:42 KTV 10061-02·6
ND ug/1 0.50 1.0 05/31/02 03:42 KTV 108-20-3
ND ug/1 0.50 1.0 05/31/02 03:42 KTV 100-41-4
ND ug/1 2.0 1.0 05/31/02 03:42 KTV 87-68-3
ND ug/1 0.50 1.0 05/31/02 03:42 KTV 98-82-8
ND ug/1 1.0 1.0 05/31/02 03:42 KTV 99-87-6
ND ug/1 2.0 1.0 05/31/02 03:42 KTV 75-09-2
ND ug/1 0.50 1.0 05/31/02 03:42 KTV 1634-04-4
ND ug/1 2.0 1.0 05/31/02 03:42 KTV 91-20-3
ND ug/1 0.50 1.0 05/31/02 03:42 KTV 103-65-1
ND ug/1 0.50 1.0 05/31/02 03:42 KTV 100-42-5
ND ug/1 0.50 1.0 05/31/02 03:42 KTV 630-20-6
ND ug/1 0.50 1.0 05/31/02 03:42 KTV 79.34.5
ND ug/1 0.50 1.0 05/31/02 03:42 KTV 127-18-4
ND ug/1 0.50 1.0 05/31/02 03:42 KTV 108-88-3
ND ug/1 2.0 1.0 05/31/02 03:42 KTV 87-61-6
ND ug/1 2.0 1.0 05/31/02 03:42 KTV 120-82-1
ND ug/1 0.50 1.0 05/31/02 03:42 KTV 71-55-6
Page: 37
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
l~eia• •cco.,., ".-~In C\< :n -J~
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
ace Analytical™
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
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www.pace/abs.com
Lab Sample No: 922282801
Client Sample ID: MW-45
Parameters
l.1.2·Trichloroethane '
Trichloroethene
Tri chl orofl uorornethane:
1. 2. 3 · Tri chloropriJpan~
;' '~ 1,2,4-Trimethylbenzene
~ .. ,,,
1.3.5-Trimethylbenzene . ,
Vinyl ,chloride
m&p•Xyle"ne /c•:,-• .-
/,-;O;Xylene , /' /./ l·Chloro-3-fluorobenzene (S) ,~-</ .. ;-.;,-
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
Lab Project Number: 9233015
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-014
Matrix: Water
Date Collected: 05/22/02 08:21
Date Received: 05/23/02 16:10
Results Units Reoort Limit ..QE._ Analyzed By
ND ug/1 0.50 1.0 05/31/02 03:42 KTV
ND ug/1 0.50 1.0 05/31/02 03:42 KTV
ND ug/1 0.50 1.0 05/31/02 03:42 KTV
ND ug/1 0.50 1.0 05/31/02 03:42 KTV
ND ug/1 0.50 1.0 05/31/02 03:42 KTV
ND ug/1 0.50 1.0 05/31/02 03:42 KTV
NO ug/1 0.50 1.0 05/31/02 03:42 KTV
ND ug/1 0.50 1.0 05/31/02 03:42 KTV
ND ug/1 0.50 1.0 05/31/02 03:42 KTV
102 t 1.0 05/31/02 03:42 KTV
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
CAS No. !l!@l. RegLmt
79-00·5
79·01·6
75-69·4
96·18·4
95-63-6
108-67·8
75-01·4
95-47-6
625·98·9
Page: 38
Laboratory Certification IDs I
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627 I
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ace Analytical™
www.pacelabs.com
Lab Sample No: 922282819
Client Sample ID: MW-46
Parameters
Metals
Metals by Trace ICP
Arsenic
Barium
Cadmium
Chromium
Lead . ·.
Mangi1nese , ~
.-Selenium
·1''
. ~-~'./ .r
Results
Prep/Method:
0.0059
0.15
ND
0.051
0.016
1.4
ND
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Lab Project Number: 9233015
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-015
Matrix: Water
Date Collected: 05/22/02 07:59
Date Received: 05/23/02 16:10
Units Report Limit J!E..... Analyzed By CAS No.
EPA 3010 / EPA 6010
mg/l 0.0050 1.0 06/05/02 01:41 DJR 7440-3B-2
mg/l 0.0050 1. 0 06/2B/02 DJR 7440-39-3
mg/l 0.0010 1.0 06/05/02 01:41 DJR 7440-43-9
mg/l 0.0020 1.0 06/05/02 01:41 DJR 7440-47-3
mg/l 0.0050 1.0 06/05/02 01:41 DJR 7439-92-1
mg/l 0.0050 1.0 06/05/02 01:41 DJR 7439·96-5
mg/l 0.0050 1.0 06/05/02 01:41 DJR 77B2-49-2 .· ,,.
I /.;. ·_..,Si 1 ver
.~··· Date Digested
ND mg/l 0.0020 1.0 06/05/02 01:41 DJR 7440-22-4
05/30/02 ..
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Mercury. CVAAS. in Water
Mercury
Wet Chemistry
Ion Chromatography
Chloride
Nitrate
Sulfate
Alkalinity. Total
Alkalinity. Total
GC Volatiles
GC voes in Water
Benzene
Bromobenzene
Bromochloromethane
Bromcidichloromethane
Bromoforrn
Bromomethane
n-Butylbenzene
sec-Butyl benzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
Methcd: EPA 7470
ND mg/1
Method: EPA 300.0
5.8 mg/l
1.2 ·mg/l
ND mg/1
Method: EPA 310.1
5.0 mg/l
Method: SM 6230D
ND ug/l
ND ug/l
ND ug/l
ND ug/l
ND ug/l
NO ug/l
NO ug/l
ND ug/l
ND ug/1
ND ug/l
ND ug/l
ND ug/1
ND ug/l
0.00020 1.0 06/03/02 LBG 7439-97-6
1.0
0.10
1.0
1.0
0.50
0.50
0.50
0.50
0.50
0.50
1.0
0.50
0.50
0.50
0.50
0.50
0.50
1.0 05/24/02
1.0 05/24/02
1. 0 05/24/02
CBJ 16887-00-6
CBJ
CBJ
1.0 06/04/02 HEH
1.0 05/31/02 06:02 KTV 71-43-2
1.0 05/31/02 06:02 KTV 108-86-1
1.0 05/31/02 06:02 KTV 74-97-5
1.0 05/31/02 06:02 KTV 75-27-4
1.0 05/31/02 06:02 KTV 75-25-2
1.0 05/31/02 06:02 KTV 74-83-9
1.0 05/31/02 06:02 KTV 104-51-8
1.0 05/31/02 06:02 KTV 135-98-8
1.0 05/31/02 06:02 KTV 98-06-6
1.0 05/31/02 06:02 KTV 56-23-5
1.0 05/31/02 06:02 KTV 10B-90-7
1.0 05/31/02 06:02 KTV 75-00-3
1.0 05/31/02 06:02 KTV 67-66-3
Page: 39
REPORT OF LABORATORY ANALYSIS Laboratory Certification IDs
LA Wastewater 04034 This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,• •cco,. .-J'fc,.~-f/0€1c1.C\t
VA Drinking Water 213
FL NELAP E87627
ace Analytical~
Pace Analytical Services, Inc.
9800 Kincey Avenue. Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone] www.pacelabs.com
Lab Sample No: 922282819
Client Sample ID: MW-46
Lab Project Number: 9233015
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015·015
Matrix: Water
Date Collected: 05/22/02 07:59
Date Received: 05/23/02 16:10
Parameters Results Units
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
Report Limit ..QL Analyzed By CAS No. !l!illl_ Reglmt Chloromethane
2·Chlorotoluene
4-Chlorotoluene
1,2-0ibromo-3-chloroPropane
DibrOITK)ChloroIDethane
l.2·Dibromo~thane (EDS)
Di bromom;th;ne
1. 2-.oi~hl orobenzene
/ '~· /:il-.'3'=0ichlorobenzene ·
.r,..; .--·1,4-Dichlorobenzene __ , ,J
, ,r,_.', _,/ Di chl orodi fl uoramethane
-"' l.l·Dichloroethane
1.2-Dichloroethane
1.l·Dichloroethene
cis-1.2-Dichloroethene
trans-1.2-Dichloroethene
1.2-Dichloropropane
1.3-Dichl oropropane
2.2·Dichloropropane
l.l·Dichloropropene
cis·l.3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethyl benzene
Hexachloro-1.3-butadiene
Isopropylbenzene (Cumene)
p-Isopropyltoluene
Methylene chloride
Hethyl-tert-butyl ether
Naphtha 1 ene
n-Propylbenzene
Styrene
1.1.1.2-Tetrachloroethane
1.1.2.2-Tetrachloroethane
Tetrachloroethene
Toluene
1.2.3-Trichlorobenzene
1,2.4-Trichlorobenzene
1.1.l·Trichloroethane
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2.0 1.0 05/31/02 06:02 KTV 74·87-3
0.50 1.0 05/31/02 06:02 KTV 95-49·8
0.50 1.0 05/31/02 06:02 KTV 106·43·4
2.0 1.0 05/31/02 06:02 KTV 96·12·8
0.50 1.0 05/31/02 06:02 KTV 124·48·1
0.50 1.0 05/31/02 06:02 KTV 106-93·4
0.50 1.0 05/31/02 06:02 KTV 74.95.3
1.0 1.0 05/31/02 06:02 KTV 95-50-1
1.0 1.0 05/31/02 06:02 KTV 541-73·1
1.0 1.0 05/31/02 06:02 KTV 106-46-7
0.50 1.0 05/31/02 06:02 KTV 75-71-8
0.50 1.0 05/31/02 06:02 KTV 75.34.3
0.50 1.0 05/31/02 06:02 KTV 107-06-2
0.50 1.0 05/31/02 06:02 KTV 75.35.4
0.50 1.0 05/31/02 06:02 KTV 156-59·2
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
2.0
0.50
1.0
2.0
0.50
2.0
0.50
0.50
0.50
0.50
0.50
0.50
2.0
2.0
0.50
1.0 05/31/02 06:02 KTV 156-60·5
1.0 05/31/02 06:02 KTV 78-87-5
1.0 05/31/02 06:02 KTV 142·28·9
1.0 05/31/02 06:02 KTV 594-20-7
1.0 05/31/02 06:02 KTV 563-58·6
1.0 05/31/02 06:02 KTV 10061-01-5
1.0 05/31/02 06:02 KTV 10061-02-6
1.0 05/31/02 06:02 KTV 108·20·3
1.0 05/31/02 06:02 KTV 100·41·4
1.0 05/31/02 06:02 KTV 87-68-3
1.0 05/31/02 06:02 KTV 98·82-8
1.0 05/31/02 06:02 KTV 99-87-6
1.0 05/31/02 06:02 KTV 75-09·2
1.0 05/31/02 06:02 KTV 1634-04-4
1.0 05/31/02 06:02 KTV 91·20-3
1.0 05/31/02 06:02 KTV 103-65-1
1.0 05/31/02 06:02 KTV 100·42·5
1.0 05/31/02 06:02 KTV 630-20-6
1.0 05/31/02 06:02 KTV 79.34.5
1.0 05/31/02 06:02 KTV 127·18·4
1.0 05/31/02 06:02 KTV 108-88-3
1.0 05/31/02 06:02 KTV 87-61-6
1.0 05/31/02 06:02 KTV 120·82·1
1.0 05/31/02 06:02 KTV 71-55-6
Page: 40
REPORT OF LABORATORY ANALYSIS Laboratory Certification IDs
LA Wastewater 04034 This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc. VA Drinking Water 213
FL NELAP E87627
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ace Analytical™
www.pacelabs.com
Lab Sample No: 922282819
Client Sample ID: MW-46
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Lab Project Number: 9233015
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-015
Matrix: Water
0ate Collected: 05/22/02 07:59
Date Received: 05/23/02 16:10
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I Parameters Results Units Reoort Limit _!)f_ Analyzed Sy CAS No. ~ ReqLmt
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1.1,2-Trichloroethane
Trichloroethene
Tri chlorofl uoromethane•, ,._ "/ 1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1. 3. 5-Trime'thyl'i,enzene
Vinyl chloride .,-· .. --
m&p-Xylene
.•'
I . o)ylene ,;< \-chloro-3-fluorobenzene (S)
(~,../
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Oate: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
ND ug/1 0.50 1.0 05/31/02 06:02 KTV
ND ug/1 0.50 1.0 05/31/02 06:02 KTV
ND ug/1 0.50 1.0 05/31/02 06:02 KTV
ND ug/1 0.50 1.0 05/31/02 06:02 KTV
ND ug/1 0.50 1.0 05/31/02 06:02 KTV
ND ug/1 0.50 1.0 05/31/02 06:02 KTV
ND ug/1 0.50 1.0 05/31/02 06:02 KTV
ND ug/1 0.50 1.0 05/31/02 06:02 KTV
ND ug/1 0.50 1.0 05/31/02 06:02 KTV
104 t 1.0 05/31/02 06:02 KTV
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,,. •ccu~
,1~.
?10ek:1.C1\
79-00-5
79-01-6
75-69-4
96-18-4
95-63-6
108-67-8
75-01·4
95-47-6
625-98-9
Page: 41
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
ace Analytical™
www.pacelabs.com
Lab Sample No: 922282827 / .·'·
Client Sample ID: MW·l3 DISSDLyED•_·:.,··
~Pa=r~am=e~t~er~s------~,:,-'✓ Results Metals .:c·
Units
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Lab Project Number: 9233015
Phone: [phone]
Fax: [phone]
Client Project JD: NCSU Lot 86/2246
Project Sample Number: 9233015-016
Hatri x: Water
Date Collected: 05/22/02 10:51
Date Received: 05/23/02 16:10
Report Limit ..QL Analyzed By Cl>S No. !l!!tl._ Reglmt
Dissolved Metals. Trace_JCP
Iron. Dissolved
Prep/Method: EPA 3010 / EPA 6010
Date Digested
C ,J ·,. ,.y,.; .. --<' .,,.,v
Date: 06/29/02
ND mg/1 0.050 1. 0 06/04/02
05/29/02
DJR 7439-89-6
Page: 42
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Laboratory Certification IDs REPORT OF LABORATORY ANALYSIS Laboratory Certification IDs I
LA Wastewater 04034 NC Wastewater 12
NC Drinking Water 37706
SC 99006
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,• •cco~ ~ ~nelaci
VA Drinking Water 213
FL NELAP E87627 I
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ace Analytical™
www.pacelabs.com
Lab Sample No: 922282835
Client Sample ID: HW-27 DISSOLVED,· ,-
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Lab Project Number: 9233015
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Project Sampfe Number: 9233015-017
Matrix: Water
Date Collected: 05/22/02 12:43
Date Received: 05/23/02 16:10
Parameters Results Units Report Limit ..QL -~A~n~a~ly~z~ed~~8~y CAS No. Metals
Dissolved Metals, Trace ICP
Iron, Dissolved
Date Digested
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
Prep/Method: EPA 3010 / EPA 6010
ND mg/l 0.050 1.0 06/04/02
05/29/02
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,,. •t~o~
~,~,. 11nelac1\
DJR 7439-89·6
Page: 43
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
ace Analytical™
www.pacelabs.com
Lab Sample No: 922282843
Client Sample ID: MW-35S DISSOLVED
Parameters Results Metals
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Lab Project Number: 9233015
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-018
Matrix: Water
Date Collected: 05/22/02 12:23
Date Received: 05/23/02 16:10
Units Report Limit ....Q.E__ Analyzed By CAS No.
Dissolved Metals. Trace ICP
Iron, Dissolved
Prep/Method: EPA 3010 I EPA 6010
ND mg/1 0.050
Date Digested
Date: 06/29/02
1. 0 06/04/02
05/29/02
DJR 7439-B9·6
Page: 44
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Laboratory Certification IDs
NC Wastewater 12 REPORT OF LABORATORY ANALYSIS Laboratory Certification IDs I
LA Wastewater 04034 NC Drinking Water 37706
SC 99006
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc. ----~~+. oL I~[;;,. "' fflOeld.C~
VA Drinking Water 213
FL NELAP EB7627 I
I
I
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I
ace Analytical™
www.pacelabs.com
Lab Sample No: 922282850 .,
; Client Sample ID: MW-36D DISSOLVED>,·
Parameters Results
Metals
Pace Analytical Services. Inc.
9800 Kincey Avenue. Suite 100
Huntersville. NC 28078
Lab Project Number: 9233015
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-019
Matrix: Water
Date Collected: 05/22/02 11:51
Date Received: 05/23/02 16:10
Units Report Limit .JlL Analyzed By CAS No. !l!!tl_ RegLmt
Dissolved Metals. Trase·JCP
Iron. Dissolved
Prep/Method: EPA 3010 / EPA 6010
ND mg/1 0.050
Date Digested .· ·
1.0 06/04/02
05/29/02
DJR 7439-89-6
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1,1:;: , .
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Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,~ Hco_, ~~--ffi□elaC1\
Page: 45
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
ace Analytical™
www.pacelabs.com
Lab Sample No: 922282868
Client Sample ID: MW-40 DISSOLVED',:·
Pace Analytical Services, Inc.
9800 Kincey Avenue. Suite 100
Huntersville. NC 28078
Lab Project Number: 9233015
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-020
Matrix: Water
Date Collected: 05/22/02 11:31
Date Received: 05/23/02 16:10
Parameters Results Uni ts Report Limit .Jlf_ Analyzed By CAS No. lli!tl._ RegLmt
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Metals
Dissolved Metals. Trace· I_CP
Ir-on. Dissolved , :_
Date Digested
Oate: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drink·,ng Water 37706
SC 99D06
Prep/Method: EPA 3010 / EPA 6010
0.084 mg/1 0.050 1. 0 06/04/02
05/29/02
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
~1·~e1" •~,,~ ...... tin aci\
DJR 7439-89-6
Page: 46
Laboratory Certification IDs I
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627 I
'
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~ ..
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ace Analytical™
www.pacelabs.com
Lab Sample No: 922282876 ,'
Client Sample ID: MW-41 DISSOLVED.
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Lab Project Number: 9233015
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-021
Matrix: Water
Date Collected: 05/22/02 09:28
Date Received: 05/23/02 16:10
Parameters Results Units Report Limit....![__ Analyzed By CAS No. Q!!tl._ Reglmt Metals
Dissolved Metals. Trace ICP
Iron. Dissolved
Date Digested
/
,/
,,/)·
Date: 06/29/02
laboratory Certification IDs
NC Wastewater · 12
NC Drinking Water 37706
SC 99006
Prep/Method: EPA 3010 / EPA 6010
0.17 mg/1 0.050 I. 0 06/04/02
05/29/02
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,. >tco• .. :•<:,~~+. ,·'/ 1_1'--.,,
JilJt:1aC11
DJR 7439-89-6
Page: 47
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
Fl NELAP E87627
.
, ,
· ace Analytical™
www.pacelabs.com
Lab Sample No: 922282900
Client Sample ID: MW-411 DISSOLVED
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Lab Project Number: 9233015
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015•022
Matrix: Water
Date Collected: 05/22/02 09:53
Date Received: 05/23/02 16:10
Parameters Results Units Report Limit JlL Analyzed By CAS No. Q!i,tl_ RegLmt
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I
I
I
Metals
Dissolved Metals. Trace ICP
Iron. Dissolved
Date Digested
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
Prep/Method: EPA 3010 / EPA 6010
0.12 mg/1 0.050 1. 0 06/04/02
05/29/02
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,. •tea_, ~'~~~ ?1nelac11
DJR 7439·89·6
Page: 48
Laboratory Certification IDs I LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627 I
I
I
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,!!;Ice Analyticar
www.pacelabs.com
Lab Sample No: 922282918 ,".-·
Client Sample ID: MW-421 DISSOLVED.
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Lab Project Number: 9233015
Phone.· 704.875.9092
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-023
Matrix: Water
Date Collected: 05/22/02 10:23
Date Received: 05/23/02 16:10
,_Pae.,r_,.a,,,mee.,tcs.er,_,s,.._ _____ ~· =·-:, : Results Units Report Limit JlL Analyzed By CAS No. Metals
Dissolved Metals, Trace ICP , .'
Iron. Dissolved
Date Digested ,
/,. ,,
Prep/Method: EPA 3010 / EPA 6010
0.18 mg/1 0.050 1.0 06/04/02
05/29/02
DJR 7439-89·6
.,/< . >• ,/
' ,,
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Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services. Inc.
1~ lCG~~ ..... ~~ •. lnelac\1
Page: 49
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP EB7627
ace Analyticar
www.pacelabs.com
Lab Sample No: 922282926 ,-.:
Client Sample ID: MW-43 DISSOLVED.
I' ..
Pace Analytical Services, Inc.
9800 Kincey Avenue. Suite 100
Huntersville, NC 28078
Lab Project Number: 9233015
Phone: [phone]
Fax: [phone]
I
I
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-024
Matrix: Water
Date Collected: 05/22/02 07:41 I
Date Received: 05/23/02 16:10
Parameters Results Units Report Limit ...QE__ Analyzed By CAS No. lli@J_ RegLmt I
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I
Metals
Dissolved Metals. Trace -ICP
Iron, Dissolved
Date Digested .. ·.,
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
Prep/Method: EPA 3010 / EPA 6010
0.092 mg/1 0.050 1.0 06/04/02
05/29/02
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.
.l>t~~ ?iO~C1t
DJR 7439-89-6
Page: 50
I
Laboratory Certification IDs I
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
ace Analytical™
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone] www.pacelabs.com 1 • Lab Project Number: 9233015
Client Project JD: NCSU Lot 86/2246
Lab Sample No: 922282934
Client Sample ID: MW-45 DISSOLVED" .. .'
Project Sample Number: 9233015-025
Matrix: Water
Date Collected: 05/22/02 08:21
Date Received: 05/23/02 16:10
Parameters
Metals
Oi sso l ved Metals. Trace ICP.
Iron. Dissolved
Date Digested
Date: 06/29/02
I
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
Results Units Report Limit JlL __ A"'n"'a~l y~z~ed~~B~y CAS No. lli@L RegLmt
Prep/Method: EPA 3010 / EPA 6010
ND mg/1 0.050 1. 0 06/04/02
05/29/02
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
DJR 7439-89-6
Page: 51
Laboratory Certification IDs
LA Wastewater 0403f
VA Drinking Water 213
FL NELAP EB7627
i~--------E111P.11If'1~--------------
ace Analytical™
www.pacelabs.com
Lab Sample No: 922282942 /!'>'
Client Sample ID: MW-46 DISSOLVED
'·
Parameters Results Units Metals
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Lab Project Number: 9233015
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015·026
Matrix: Water
Date Collected: 05/22/02 07:59
Date Received: 05/23/02 16:10
Report Limit JlL Analyzed By CAS No. lli!.tl_ ReqLmt
Dissolved Metals. Trace ICP i' < •• Prep/Method: EPA 3010 / EPA 6010
Iron. Dissolved 1 NO mg/1 0.050
Date Digested
Date: 06/29/02
1. 0 06/04/02
05/29/02
OJR 7439·89·6
Page: 52
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Laboratory Certification IDs REPORT OF LABORATORY ANALYSIS Laboratory Certification IDs I NC Wastewater 12
NC Drinking Water 37706
SC 99006
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,~ •cc0~0
,, 0 i a,
LA Wastewater 04034
VA Drinking Water 213 1 FL NELAP EB7627
ace Analytical'"
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone] www.pacelabs.com
Lab Sample No: 922282959
Client Sample ID: F8-l
Lab Project Number: 9233015
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-027
Matrix: Water
Date Collected: 05/22/02 11:51
Date Received: 05/23/02 16:10
I
I
I
Parameters · ··. :_ ,,, Results ===-=-------~--'-"' Units Report Limit ....QE_ __ A'-"n,,,a.,_ly,.,z"'-ed,__..,,8c.,_y __,C"-'AS'--"'No,..,._ 9!!tl._ RegLmt
I
Metals
Metals by Trace ICP
Arsenic
Barium
Cadmium ' . ';
Chromium .. · ... ,
Lead.· ·•··
Mang(1ne~Se
I /S~le~ium
.,/: /$nver
• ' · Date Digested
I
I
I
I
I
I
I
I
I
I
I
I
Mercury. CVAAS, in Water
Mercury
Wet Chemistry
Ion Chromatography
Chloride
Nitrate
Sulfate
Alkalinity. Total
Alkalinity. Total
GC Volatiles
GC voes in Water
Benzene
Bromobenzene
BroTOOchloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butyl benzene
tert-8utylbenzene
Carbon tetrachloride
Chlorobenzene
Chl oroethane
Chloroform
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
Prep/Method: EPA 3010 / EPA 6010
ND
ND
ND
ND
ND
ND
ND
ND
Method:
mg/l
mg/l
mg/l
mg/l
mg/1
mg/l
mg/l
mg/l
EPA 7470
0.0050
0.0050
0.0010
0.0020
0.0050
0.0050
0.0050
0.0020
1.0 05/30/02 19:55 DJR 7440-38-2
1.0 05/30/02 19:55 DJR 7440-39-3
1.0 05/30/02 19:55 DJR 7440-43-9
1.0 05/30/02 19:55 DJR 7440-47-3
1.0 05/30/02 19:55 DJR 7439-92-1
1.0 05/30/02 19:55 DJR 7439-96-5
1.0 05/30/02 19:55 DJR 7782-49-2
1.0 05/30/02 19:55 DJR 7440-22-4
05/30/02
ND mg/l 0,00020 1.0 06/03/02 L8G 7439-97-6
Method: EPA 300.0
ND mg/l
ND mg/l
1.0 1.0 05/24/02
0.10 1.0 05/24/02
CBJ 16887-00-6
C8J
ND mg/l 1.0 1.0 05/24/02 CBJ
Method: EPA 310.1
5.0 mg/1 1.0 1.0 06/04/02 HEH
Method: SM 6230D
ND ug/l 0.50 1.0 05/31/02 06:49 KTV
ND ug/l 0.50 1.0 05/31/02 06:49 KTV
ND ug/l 0.50 1.0 05/31/02 06:49 KTV
ND ug/l 0.50 1.0 05/31/02 06:49 KTV
ND ug/l 0.50 1.0 05/31/02 06:49 KTV
ND ug/l 0.50 1.0 05/31/02 06:49 KTV
ND ug/1 1.0 1.0 05/31/02 06:49 KTV
ND ug/l 0.50 1.0 05/31/02 06:49 KTV
ND ug/l 0.50 1.0 05/31/02 06:49 KTV
ND ug/l 0.50 1.0 05/31/02 06:49 KTV
ND ug/l 0.50 1.0 05/31/02 06:49 KTV
ND ug/l 0.50 1.0 05/31/02 06:49 KTV
19. ug/l 0.50 1.0 05/31/02 06:49 KTV
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,~ HCo4 .-1~-ff/Ot:1aC1~
71-43-2
108-86-1
74.97.5
75-27-4
75-25-2
74-83-9
104-51-8
135-98·8
98-06-6
56-23-5
108-90-7
75-00-3
67-66-3
Page: 53
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
ace Analytical™
www.pacelabs.com
Lab Sample No: 922282959
Client Sample ID: F8·1
0P~ar~a~m~et~e~r~'------,,...-,=':"' Results
Chloromethane ND
2-Chlorotoluene ND
4·Chlorotoluene ,,. .. ND
l.2·Dibromc-3-chloropropane
Di bromcchl oronieth:ne
l.2·Dibromci'eth~~e (EDB)
Di bromonietiicl.ne
1, 2 ~Dithl orobenzene •'' ,,,.,.
./i.~; 3'· Di chl orobenzene
,.,•: \>'-1. 4 · Di chl orobenzene
Dichlorodifluoromethane
1.1-Dichloroethane
1.2-Dichloroethane
1.l·Dichloroethene
cis-l,2·Dichloroethene
trans-1,2-Dichloroethene
1.2-0ichloropropane
1.3-Dichloropropane
2.2·Dichloropropane
l.l·Dichloropropene
cis·l.3·Dichloropropene
trans·l.3-Dichloropropene
Diisopropyl ether
Ethyl benzene
Hexachloro-1.3-butadiene
lsopropylbenzene (Cumene)
p-Isopropyltoluene
Methylene chloride
Methyl-tert-butyl ether
Naphthalene
n-Propyl benzene
Styrene
l.l.l.2·Tetrachloroethane
1.1.2.2-Tetrachloroethane
Tetrachloroethene
Toluene
1.2.3-Trichlorobenzene
1.2.4-Trichlorobenzene
1.1.l·Trichloroethane
Date: 06/29/02
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Units
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
Lab Project Number: 9233015
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015·027
Matrix: Water
Date Collected: 05/22/02 11:51
Date Received: 05/23/02 16:10
Reoort Limit J!L Analyzed By CAS No.
2.0 1.0 05/31/02 06:49 KTV 74·87-3
0.50
0.50
2.0
0.50
0.50
0.50
1.0
1.0
1.0
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
2.0
0.50
1.0
2.0
0.50
2.0
0.50
0.50
0.50
0.50
0.50
0.50
2.0
2.0
0.50
1.0 05/31/02 06:49 KTV 95-49·8
1.0 05/31/02 06:49 KTV 106·43·4
1.0 05/31/02 06:49 KTV 96·12·8
1.0 05/31/02 06:49 KTV 124'48·1
1.0 05/31/02 06:49 KTV 106·93·4
1.0 05/31/02 06:49 KTV 74.95.3
1.0 05/31/02 06:49 KTV 95-50-1
1.0 05/31/02 06:49 KTV 541·73·1
1.0 05/31/02 06:49 KTV 106·46·7
1.0 05/31/02 06:49 KTV 75·71•8
1.0 05/31/02 06:49 KTV 75.34.3
1.0 05/31/02 06:49 KTV 107-06·2
1.0 05/31/02 06:49 KTV 75.35.4
1.0 05/31/02 06:49 KTV 156-59·2
1.0 05/31/02 06:49 KTV 156·60·5
1.0 05/31/02 06:49 KTV 78-87·5
1.0 05/31/02 06:49 KTV 142·28·9
1.0 05/31/02 06:49 KTV 594•20•7
1.0 05/31/02 06:49 KTV 563-58·6
1.0 05/31/02 06:49 KTV 10061·01·5
1.0 05/31/02 06:49 KTV 10061·02·6
1.0 05/31/02 06:49 KTV 108·20·3
1.0 05/31/02 06:49 KTV 100-41-4
1.0 05/31/02 06:49 KTV 87·68·3
1.0 05/31/02 06:49 KTV 98-82·8
1.0 05/31/02 06:49 KTV 99-87-6
1.0 05/31/02 06:49 KTV 75-09-2
1.0 05/31/02 06:49 KTV 1634-04·4
1.0 05/31/02 06:49 KTV 91-20-3
1.0 05/31/02 06:49 KTV 103-65-1
1.0 05/31/02 06:49 KTV 100-42-5
1.0 05/31/02 06:49 KTV 630·20·6
1.0 05/31/02 06:49 KTV 79.34.5
1.0 05/31/02 06:49 KTV 127·18-4
1.0 05/31/02 06:49 KTV 108·88·3
1.0 05/31/02 06:49 KTV 87-61·6
1.0 05/31/02 06:49 KTV 120-82·1
1.0 05/31/02 06:49 KTV 71-55-6
Q!w_ RegLmt
Page: 54
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Laboratory Certification IDs
NC Wastewater 12 REPORT OF LABORATORY ANALYSIS Laboratory Certification IDs I
LA Wastewater 04034
NC Drinking Water 37706
SC 99006
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc. FL NELAP E87627
VA Drinking Water 213
1
ace Analytical™
www.pacelabs.com
I Lab Sample No: 922282959
Client Sample IO: FB-1
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Lab Project Number: 9233015
Phone: [phone]
Fax: [phone]
Client Project 10: NCSU Lot 86/2246
Project Sample Number: 9233015-027
Matrix: Water
Date Collected: 05/22/02 11:51
Date Received: 05/23/02 16:10
I
I
Parameters Results Units Reoort Limit ...!lL Anal lZed Bl CAS No. Q!!tl_ RegLmt
I
1.1,2-Trichloroethane ,:
Trichloroethene
Tri chl orofluoromet~arfe ·
1,2,3-Trichloropropane
1. 2. 4-Tri methyl benzene
1.3.5-Trimethylbenzene
Vinyl chl ori.de
m&p,Xyle~e ,.,. ;<...-1 /O;Xylene
/ ✓ A /l·Chloro-3-fluorobenzene (S)
//1··.
'/
I
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I
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I
I
I
I
I
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
NO ug/1 0.50 1.0 05/31/02 06:49 KTV
NO ug/1 0.50 1.0 05/31/02 06:49 KTV
NO ug/1 0.50 1.0 05/31/02 06:49 KTV
NO ug/1 0.50 1.0 05/31/02 06:49 KTV
NO ug/1 0.50 1.0 05/31/02 06:49 KTV
NO ug/1 0.50 1.0 05/31/02 06:49 KTV
NO ug/1 0.50 1.0 05/31/02 06:49 KTV
NO ug/1 0.50 1.0 05/31/02 06:49 KTV
NO ug/1 0.50 1.0 05/31/02 06:49 KTV
105 t 1.0 05/31/02 06:49 KTV
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,, ~eeo, ~~~~~~ fi□elac\t
79·00-5
79-01·6
75-69·4
96-18-4
95-63·6
108-67-8
75-01·4
95-47-6
625-98·9
Page: 55
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
ace Analytical™
www.pacelabs.com
Lab Sample No: 922283007
Client Sample ID: 36D-DUP
Parameters Results Units Metals
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Lab Project Number: 9233015
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015·028
Matrix: Water
Date Collected: 05/22/02 11:51
Date Received: 05/23/02 16:10
Report Limit _.QL_ --"'Ane,accl"yz"'e"'d---"-By"-_...,C"'AS"-"N"'o~. _ !ll!tl_ RegLmt
Metals by Trace ICP · '' Prep/Method: EPA 3010 / EPA 6010
Arsenic 0, 036 mg/l 0.0050 1,0 05/30/02 20:00 DJR 7440·38·2 Barium ND mg/l 0,0050 1.0 05/30/02 20:00 DJR 7440·39·3 Cadmium ND mg/l 0,0010 1.0 05/30/02 20:00 DJR 7440·43-9 Chromium .~ ·_ O. 0081 mg/l 0.0020 1.0 05/30/02 20:00 DJR 7440-47·3 1 Lead· /_;\__.: · . . / Manganese
/-~~i{nium
ND mg/l
0.0096 mg/l
ND mg/1
0.0050 1.0 05/30/02 20:00 DJR 7439·92·1
0,0050 1.0 05/30/02 20:00 DJR 7439·96·5
0.0050 1.0 05/30/02 20:00 DJR 7782-49·2 /:.,-~-Silver 0.0020 1.0 05/30/02 20:00 DJR 7440·22·4 .-,,(:':'.•. Date Digested
NO mg/l
05/30/02
I
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I
I
I
I
I
I
,.·
Mercury, CVMS. in Water
Mercury
Wet Chemistry
Ion Chromatography
Chloride
Nitrate
Sulfate
Alkalinity, Total
Alkalinity, Total
GC Volatiles
GC voes in Water
Benzene
B romobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butyl benzene
tert·Butylbenzene
Carbon .tetrachloride
Chl orobenzene
Chloroethane
Chloroform
Oate: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
Method: EPA 7470
ND mg/l 0,00020 1.0 06/03/02 LBG 7439·97·6
Method: EPA 300.0
2.0 mg/l
NO mg/l
1.0
0.10
1.0
I. 0 05/24/02
1.0 05/24/02
1.0 05/24/02
CBJ 16887-00-6
CBJ
3.0 mg/l CBJ
Method: EPA 310.1
70, mg/l 1.0 1. 0 06/04/02 HEH
Method: SH 62300
ND ug/l 25. 50,0 05/31/02 07:35 KTV
ND ug/l 25. 50.0 05/31/02 07:35 KTV
ND ug/l 25, 50.0 05/31/02 07:35 KTV
ND ug/1 25, 50.0 05/31/02 07:35 KTV
ND ug/l 25, 50.0 05/31/02 07:35 KTV
ND ug/l 25, 50.0 05/31/02 07:35 KTV
ND ug/l 50, 50.0 05/31/02 07:35 KTV
ND ug/1 25, 50.0 05/31/02 07:35 KTV
ND ug/1 25. 50.0 05/31/02 07:35 KTV
61. ug/l 25. 50.0 05/31/02 07:35 KTV
ND ug/l 25, 50.0 05/31/02 07:35 KTV
ND ug/l 25, 50.0 05/31/02 07:35 KTV
1100 ug/l 25. 50.0 05/31/02 07:35 KTV
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
71-43·2
108·86-l
74.97.5
75-27-4
75-25·2
74-83·9
104-51-8
135·98·8
98-06·6
56-23-5
108·90·7
75-00·3
67-66-3
Page: 56
Laboratory Certification IDs I
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627 I
I
ace Analytical™
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
www.pacelabs.com
Lab Sample No: 922283007
Client Sample ID: 36D·DUP ' .
Lab Project Number: 9233015
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015·028
Hatri x: Water
Date Collected: 05/22/02 11:51
Date Received: 05/23/02 16:10
I
I Parameters Results Units Reoort Limit ..QL Anal ~zed B~ CAS No. !l!!tl_ RegLmt
I
I
Chloromethane
2-Chlorotoluene
4 ·Chloroto l uene
1.2-Dibromo-3-chloropropane
Di bromochl orpniethane
1.2-Dibroioo,e,thane (EDB}
Dibromolllethane
1. 2 ·Di chi orobenzene
I /'}~;3:[);chlorobenzene
. ,<'.·' l.4-Dichlorobenzene
<!/,,.. ,, Di chlorodi fl uoromethane
'.··· l. l·Dichloroethane
1,2-Dichloroethane
l.l·Dichloroethene
cis-1.2-Dichloroethene
I
I
I
I
I
I
I
n
I
I
I
trans·l,2-Dichloroethene
1.2-Dichloropropane
1,3-Dichloropropane
2.2·Dichloropropane
l.l·Dichloropropene
cis-1,3-Dichloropropene
trans-1.3-Dichloropropene
Diisopropyl ether
Ethyl benzene
Hexachloro·l,3-butadiene
Isopropylbenzene (Cumene}
p-Isopropyltoluene
Methylene chloride
Methyl-tert·butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1.2-Tetrachloroethane
1.1.2.2-Tetrachloroethane
Tetrachloroethene·
Toluene
1.2.3-Trichlorobenzene
1.2,4-Trichlorobenzene
1,1,1-Trichloroethane
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
ND ug/l 100 50.0 05/31/02 07:35 KTV
ND ug/l 25. 50.0 05/31/02 07:35 KTV
ND ug/l 25. 50.0 05/31/02 07:35 KTV
ND ug/l 100 50.0 05/31/02 07:35 KTV
ND ug/1 25. 50.0 05/31/02 07:35 KTV
ND ug/l 25. 50.0 05/31/02 07:35 KTV
ND ug/l 25. 50.0 05/31/02 07:35 KTV
ND ug/l 50. 50.0 05/31/02 07:35 KTV
ND ug/l 50 . 50.0 05/31/02 07:35 KTV
ND ug/l 50. 50.0 05/31/02 07:35 KTV
ND ug/1 25. 50.0 05/31/02 07:35 KTV
ND ug/l 25. 50.0 05/31/02 07:35 KTV
ND ug/l 25. 50.0 05/31/02 07:35 KTV
ND ug/1 25. 50.0 05/31/02 07:35 KTV
ND ug/l 25. 50.0 05/31/02 07:35 KTV
ND ug/1 25. 50.0 05/31/02 07:35 KTV
ND ug/1 25. 50.0 05/31/02 07:35 KTV
ND ug/1 25. 50.0 05/31/02 07:35 KTV
ND ug/1 25. 50.0 05/31/02 07:35 KTV
ND ug/1 25. 50.0 05/31/02 07:35 KTV
ND ug/1 25. 50.0 05/31/02 07:35 KTV
ND ug/1 25. 50.0 05/31/02 07:35 KTV
ND ug/1 25. 50.0 05/31/02 07:35 KTV-
ND ug/1 25. 50.0 05/31/02 07:35 KTV
ND ug/1 100 50.0 05/31/02 07:35 KTV
ND ug/1 25. 50.0 05/31/02 07:35 KTV
ND ug/1 50. 50.0 05/31/02 07:35 KTV
NO ug/1 100 50.0 05/31/02 07:35 KTV
ND ug/l 25. 50.0 05/31/02 07:35 KTV
ND ug/1 100 50.0 05/31/02 07:35 KTV
ND ug/1 25. 50.0 05/31/02 07:35 KTV
ND ug/1 25. 50.0 05/31/02 07:35 KTV
ND ug/1 25. 50.0 05/31/02 07:35 KTV
ND ug/1 25. 50.0 05/31/02 07:35 KTV
ND ug/1 25. 50.0 05/31/02 07:35 KTV
ND ug/1 25. 50.0 05/31/02 07:35 KTV
ND ug/1 100 50.0 05/31/02 07:35 KTV
ND ug/1 100 50.0 05/31/02 07:35 KTV
ND ug/1 25. 50.0 05/31/02 07:35 KTV
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
1• •cco4 -·~-fiOt:taC\~
74-87-3
95-49·8
106-43-4
96-12·8
124-48-1
106-93-4
74-95-3
95-50-1
541-73-1
106-46-7
75-71-8
75-34-3
107-06-2
75-35-4
156-59-2
156-60·5
78-87-5
142-28-9
594-20-7
563-58-6
10061-01-5
10061-02-6
108-20-3
100-41-4
87-68-3
98·82-8
99-87-6
75·09·2
1634-04·4
91-20-3
103-65·1
100-42-5
630-20-6
79.34.5
127-18-4
108-88-3
87-61-6
120-82-1
71-55-6
Page: 57
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
/
}o" .
ace Analytical™
www.pacelabs.com
Lab Sample No: 922283007
Client Sample ID: 360-DUP
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Lab Project Number: 9233015
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015·028 Date Collected: 05/22/02 11:51
Matrix: Water Date Received: 05/23/02 16:10
Parameters Results Units Re[1Qrt'Limit _QE_ Analyzed By CAS No. !l!!tl_ RegLmt
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
1.1.2-Trichloroethane .··.
Trichloroethene
Tri chl orofl uoromettiaiie/
1,2,3-Trichloropropan~
1,2,4-TrimethYlbenzene
1, 3, 5-Trimet_hylbenzene
Vinyl .cnloride ,' ... .,, ir&p-Xylene
/~fXYlene
.,.--,;; ~l-Chloro-3-fluorobenzene (SJ
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
ND ug/1 25. 50.0 05/31/02 07:35 KTV
ND ug/1 25, 50.0 05/31/02 07:35 KTV
ND ug/1 25, 50.0 05/31/02 07:35 KTV
ND ug/1 25. 50.0 05/31/02 07:35 KTV
ND ug/1 25. 50.0 05/31/02 07:35 KTV
ND ug/1 25, 50.0 05/31/02 07:35 KTV
ND ug/1 25. 50.0 05/31/02 07:35 KTV
ND ug/1 25. 50,0 05/31/02 07:35 KTV
ND ug/1 25. 50.0 05/31/02 07:35 KTV
104 t 1.0 05/31/02 07:35 KTV
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
.?~J~~,~o.,.,.~,.,. ;1n'~l:i'.it\,.
79·00·5
79-01·6
75·69·4
96-18·4
95-63·6
108·67·8
75-01·4
95-47·6
625·9B-9
Page: 58
Laboratory Certification IDs I
LA Wastewater 04034
VA Drinking Water 213 1 FL NELAP E87627
ace Analytical™
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone] www.pacelabs.com
I
I
Lab Sample No: 922283015
Client Sample IO: HW-29
Parameters
Metals
Metals by Trace ICP
Arsenic
Barium
Cadmium
I Chromium,
Lead / _.·
Manga~ese
I ,.,,,,1~1e~ium
,<_,··s;iver
.,,,(,-··' Date Digested ,·
I
I
I
I
I
I
I
I
I
,I
I
I
Mercury, CVAAf,_ in Water
Mercury
Wet Chemistry
Ion Chromatography
Chloride
Nitrate
Sulfate
Alkalinity, Total
Alkalinity, Total
GC Volatiles
GC voes in Water
Benzene
Bromobenzene
Bromochloromethane
Bro100dichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butyl benzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
Results Units
Lab Project Number: 9233015
Client Project IO: NCSU Lot 86/2246
Project Sample Number: 9233015-029
Matrix: Water
Date Collected: 05/22/02 11:11
Date Received: 05/23/02 16:10
Report Limit ..QL_ Analyzed By CAS No.
Prep/Method: EPA 3010 / EPA 6010
NO mg/l 0.0050 1.0 05/30/02 20:05 OJR 7440-38-2
0.020 mg/1 0.0050 1.0 05/30/02 20:05 OJR 7440-39-3
NO mg/l 0.0010 1.0 05/30/02 20:05 OJR 7440-43-9
0.0050 mg/l 0.0020 1.0 05/30/02 20:05 OJR 7440-47-3 1
NO mg/l 0.0050 1.0 05/30/02 20:05 OJR 7439-92-1
0.017 mg/l 0.0050 1.0 05/30/02 20:05 OJR 7439-96-5
NO mg/l 0.0050 1.0 05/30/02 20:05 OJR 7782-49-2
NO mg/l 0.0020 1.0 05/30/02 20:05 OJR 7440-22-4
05/30/02
Method: EPA 7470
NO mg/l 0. 00020 1.0 06/03/02 LBG 7439-97-6
Method: EPA 300.0
1. 9 mg/l
NO mg/1
1.0
0.10
1.0
1.0 05/24/02
1.0 05/24/02
1. 0 05/24/02
CBJ 16887-00-6
CBJ
1.2 mg/l CBJ
Method: EPA 310.1
18. mg/l 1.0 1. 0 06/04/02 HEH
Method: SM 62300
NO ug/l 0.50 1.0 06/02/02 16:21 KTV
NO ug/l 0.50 1.0 06/02/02 16:21 KTV
NO ug/l 0.50 1.0 06/02/02 16:21 KTV
NO ug/l 0.50 1.0 06/02/02 16:21 KTV
ND ug/l 0.50 1.0 06/02/02 16:21 KTV
NO ug/l 0.50 1.0 06/02/02 16:21 KTV
NO ug/l 1.0 1.0 06/02/02 16:21 KTV
ND ug/l 0.50 1.0 06/02/02 16:21 KTV
NO ug/1 0.50 1.0 06/02/02 16:21 KTV
NO ug/l 0.50 1.0 06/02/02 16:21 KTV
NO ug/l 0.50 1.0 06/02/02 16:21 KTV
NO ug/1 0.50 1.0 06/02/02 16:21 KTV
NO ug/l 0.50 1.0 06/02/02 16:21 KTV
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,11 •cca4 ~'~~ fiOt::!R:I.C\t
71-43-2
108-86-1
74.97.5
75-27-4
75-25-2
74-83-9
104-51-8
135-98-8
98-06-6
56-23-5
108-90-7
75-00-3
67-66-3
Page; 59
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
ace Analytical'"
www.pacelabs.com
Lab Sample No: 922283015
Client Sample ID: MW-29
Parameters
Chloromethane
2-Chl oroto luene
4-Chlorotoluene / .. ,-.
1. 2 · Di bromo· 3-chl oropropane
Di bromochloronieth~~e
l.2·Dibromci~th~ne (EDB)
Di brorooffi~t~;ne ,f. .•.• ~,.,
1 .,2,:~i chlorobenzene
.A. 3: Di ch l orobenzene
Results
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Lab Project Number: 9233015
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015·029
Matrix: Water
Date Collected: 05/22/02 11:11
Date Received: 05/23/02 16:10
Reoort Limit _QE._ Analyzed By CAS No.
2.0 1.0 06/02/02 16:21 KTV 74-87-3
_/_·; "i. 4 • Di chl orobenzene
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Units
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
0.50
0.50
2.0
0.50
0.50
0.50
1.0
1.0
1.0
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
2.0
0.50
1.0
2.0
0.50
2.0
0.50
0.50
0.50
0.50
0.50
0.50
2.0
2.0
0.50
1.0 06/02/02 16:21 KTV 95-49-8
1.0 06/02/02 16:21 KTV 106-43-4
1.0 06/02/02 16:21 KTV 96·12·8
1.0 06/02/02 16:21 KTV 124•48-l
1.0 06/02/02 16:21 KTV 106-93-4
1.0 06/02/02 16:21 KTV 74·95·3
1.0 06/02/02 16:21 KTV 95-50-1
1.0 06/02/02 16:21 KTV 541-73•1
1.0 06/02/02 16:21 KTV 106-46-7
1.0 06/02/02 16:21 KTV 75-71-8
1.0 06/02/02 16:21 KTV 75-34-3
1.0 06/02/02 16:21 KTV 107-06-2
1.0 06/02/02 16:21 KTV 75-35·4
1.0 06/02/02 16:21 KTV 156-59·2
1.0 06/02/02 16:21 KTV 156-60-5
1.0 06/02/02 16:21 KTV 78-87•5
1.0 06/02/02 16:21 KTV 142-28·9
1.0 06/02/02 16:21 KTV 594-20-7
1.0 06/02/02 16:21 KTV 563-58-6
1.0 06/02/02 16:21 KTV 10061-01-5
1.0 06/02/02 16:21 KTV 10061·02-6
1.0 06/02/02 16:21 KTV 108-20-3
1.0 06/02/02 16:21 KTV 100·41·4
1.0 06/02/02 16:21 KTV 87·68-3
1.0 06/02/02 16:21 KTV 98-82-8
1.0 06/02/02 16:21 KTV 99·87-6
1.0 06/02/02 16:21 KTV 75-09-2
1.0 06/02/02 16:21 KTV 1634-04·4
1.0 06/02/02 16:21 KTV 91-20-3
1.0 06/02/02 16:21 KTV 103-65·1
1.0 06/02/02 16:21 KTV 100-42·5
1.0 06/02/02 16:21 KTV 630-20·6
1.0 06/02/02 16:21 KTV 79-34-5
1.0 06/02/02 16:21 KTV 127-18-4
1.0 06/02/02 16:21 KTV 108-88·3
1.0 06/02/02 16:21 KTV 87-61-6
1.0 06/02/02 16:21 KTV 120-82-1
1.0 06/02/02 16:21 KTV 71·55-6
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
.. ?r;v.•"
C:! Dichlorodifluoromethane
1.1-Dichloroethane
l.2·Dichloroethane
l.l·Dichloroethene
cis-1.2-Dichloroethene
trans-1.2-Dichloroethene
1.2-Dichloropropane
1,3-Dichloroprapane
2.2·Dichloropropane
1.1-Dichloropropene
cis-1.3-Dichloropropene
trans-1,3-0ichloropropene
Diisopropyl ether
Ethyl benzene
Hexachloro·l.3-butadiene
Jsopropylbenzene (Cumene)
p·Isopropyltoluene
Methylene chloride
Methyl-tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1.1.1.2-Tetrachloroethane
1.1.2.2-Tetrachloroethane
Tetrachloroethene
Toluene
l.2.3·Trichlorobenzene
1.2.4-Trichlorobenzene
1.1.l·Trichloroethane
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
-ug/l
ug/l
ug/l
ug/l
ug/1
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/1
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services. Inc.
Page: 60
Laboratory Certification IDs I
LA Wastewater 04034
VA Drinking Water 213 1 FL NELAP E87627
ace Analytical™
www.pacelabs.com
Lab Sample No: 922283015 . i, :,..,
~: Client Sample 10: HW-29
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Lab Project Number: 9233015
Phone: [phone]
Fax: [phone]
Client Project IO: NCSU Lot 86/2246
Project Sample Number: 9233015-029
Matrix: Water
Date Collected: 05/22/02 11:11
Date Received: 05/23/02 16:10
I
I
I
Parameters Results Units Reoort Limit _Q[_ Anal lZed Bl CAS No. 9!!tl_ RegLmt
I
1.1.2-Trichloroethane
Trichloroethene
Tri chl orofl uoromettlane:'
1.2,3-Trichlor9proP~n'e
1,2.4-Trimethylbenzene
1,3,5-Trimethy,-benzene
Vinyl .chloride
..•.. c '!' m&p0~ylene
I _,,o,.Xyl ene
_,,✓:'::.:~,1-chl oro -3-fl uorobenzene (S)
.-1.:·/
I
I
I
I
I
I
I
I
I
I
I
I
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
NO ug/l 0.50 1.0 06/02/02 16:21 KTV
NO ug/l 0.50 1.0 06/02/02 16:21 KTV
NO ug/l 0.50 1.0 06/02/02 16:21 KTV
NO ug/l 0.50 1.0 06/02/02 16:21 KTV
NO ug/l 0.50 1.0 06/02/02 16:21 KTV
NO ug/l 0.50 1.0 06/02/02 16:21 KTV
NO ug/l 0.50 1.0 06/02/02 16:21 KTV
NO ug/l 0.50 1.0 06/02/02 16:21 KTV
NO ug/1 0.50 1.0 06/02/02 16:21 KTV
100 X 1.0 06/02/02 16:21 KTV
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,, •ceo~
//'~,
ffiOt:1aC1t
79-00-5
79-01·6
75-69-4
96-18-4
95·63·6
108-67-8
75-01-4
95-47-6
625-98-9
Page: 61
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
ace Analytical™
www.pacelabs.com
Lab Sample No: 922283023
Client Sample IO: TRIP BLANK I :.
'
Parameters Results Units
GC Volatiles
GC VOCs in Water
Benzene
Bromobenzene
Bromochlorometh~ne
Brmoodi ch]_Of_omE!thane
Bromofof'ITI,•·
_✓..·,, ,r Bromomethane -~ ,,,-
_,:-<:D;BUtyl benzene
,..-';,.J· ,. sec-Butyl benzene
Method: SH 62300
NO ug/1
NO ug/1
NO ug/1
NO ug/1
NO ug/1
NO ug/1
NO ug/1
NO ug/1
Lab Project Number: 9233015
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Client Project IO: NCSU Lot 86/2246
Project Sample Number: 9233015-030
Matrix: Water
Date Collected: 05/22/02 00:00
Date Received: 05/23/02 16:10
Report Limit ...QE._ -~Aneo•~l~yz~e~d'-~B x~ CAS No.
0.50 1.0 05/31/02 08:22 KTV 71-43·2
0.50 1.0 05/31/02 08:22 KTV 108-86·1
0.50 1.0 05/31/02 08:22 KTV 74.97.5
0.50 1.0 05/31/02 08:22 KTV 75-27·4
0.50 1.0 05/31/02 08:22 KTV 75-25-2
0.50 1.0 05/31/02 08:22 KTV 74-83-9
1.0 1.0 05/31/02 08:22 KTV 104-51·8
0.50 1.0 05/31/02 08:22 KTV / " .-1;t'>' tert-Butylbenzene
135-98-8
NO ug/1 0.50 1.0 05/31/02 08:22 KTV 98-06-6 ·., Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1.2-Dibromo-3-chloropropane
Dibromochloromethane
l,2·0ibromoethane (EDB)
Di bromomethane
1.2-0ichlorobenzene
1,3-0ichlorobenzene
1.4-0ichlorobenzene
Dichlorodifluoromethane
l,l·Oichloroethane
1,2-0ichloroethane
1,1-0ichloroethene
cis·l,2·Dichloroethene
trans-1.2-0ichloroethene
1,2·Dichloropropane
1,3-0ichloropropane
2,2-0ichloropropane
l,l·Oichloropropene
cis-1,3-0ichloropropene
trans-1.3-Dichloropropene
Oiisopropyl ether
Ethyl benzene
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
NO ug/1 0.50 1.0 05/31/02 08:22 KTV
ND ug/1 0.50 1.0 05/31/02 08:22 KTV
ND ug/1 0.50 1.0 05/31/02 08:22 KTV
ND ug/1 0.50 1.0 05/31/02 08:22 KTV
ND ug/1 2.0 1.0 05/31/02 08:22 KTV
ND ug/l 0.50 1.0 05/31/02 08:22 KTV
ND ug/l 0.50 1.0 05/31/02 08:22 KTV
ND ug/l 2.0 1.0 05/31/02 08:22 KTV
ND ug/1 0.50 1.0 05/31/02 08:22 KTV
ND ug/1 0.50 1.0 05/31/02 08:22 KTV
ND ug/1 0.50 1.0 05/31/02 08:22 KTV
ND ug/1 1.0 1.0 05/31/02 08:22 KTV
ND ug/1 1.0 1.0 05/31/02 08:22 KTV
ND ug/1 1.0 1.0 05/31/02 08:22 KTV
ND ug/1 0.50 1.0 05/31/02 08:22 KTV
ND ug/1 0.50 1.0 05/31/02 08:22 KTV
ND ug/1 0.50 1.0 05/31/02 08:22 KTV
NO ug/1 0.50 1.0 05/31/02 08:22 KTV
ND ug/1 0.50 1.0 05/31/02 08:22 KTV
ND ug/1 0.50 1.0 05/31/02 08:22 KTV
ND ug/1 0.50 1.0 05/31/02 08:22 KTV
NO ug/1 0.50 1.0 05/31/02 08:22 KTV
ND ug/1 0.50 1.0 05/31/02 08:22 KTV
ND ug/l 0.50 1.0 05/31/02 08:22 KTV
ND ug/1 0.50 1.0 05/31/02 08:22 KTV
ND ug/1 0.50 1.0 05/31/02 08:22 KTV
ND ug/1 0.50 1.0 05/31/02 08:22 KTV
ND ug/1 0.50 1.0 05/31/02 08:22 KTV
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
56·23-5
108-90·7
75-00-3
67-66·3
74.37.3
95.49.3
106-43·4
96-12-8
124·48-l
106-93·4
74.95.3
95-50·1
541-73•1
106-46-7
75.71.3
75.34.3
107-06-2
75.35.4
156-59·2
156-60-5
78-87-5
142·28·9
594-20·7
563-58·6
10061-01·5
10061-02-6
108-20·3
100-41·4
Page: 62
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
I
I
I
I
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ace Analytical™
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone] www.pacelabs.com Lab Project Number,: 9233015
Client Project ID: NCSU Lot 86/2246
Lab Sample No: 922283023 Project Sample Number: 9233015-030 Date Collected: 05/22/02 00:00
Client Sample ID: TRIP BLANK Matrix: Water Date Received: 05/23/02 16: 10 I Parameters Results Units Reoort Limit J1L Analyzed By CAS No. !l!!.tl._ RegLmt
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Hexachloro-1,3-butadiene
Isopropylbenzene (Cumene)'
p-lsopropyltoluene< · ·
Methylene chlorid~ /.,. . a Methyl-tert-butyl ether
Naphthalene . .'/
n. Propyl beiizene
Styrene" I ,<(1.i,2-Tetrachloroethane
-~~ ... >_..., 1.1. 2, 2 · Tetrachl oroethane
,·ji~:,, Tetrachloroethene
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Toluene
1.2.3-Trichlorobenzene
1.2,4-Trichlorobenzene
1,1,l·Trichloroethane
1.1,2-Trichloroethane
Tri chl oroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1.3.5-Trimethylbenzene
Vinyl chloride
m&p-Xylene
a-Xylene
l-Chloro-3·fluorobenzene (S)
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
ND ug/1 2.0 1.0 05/31/02 08:22 KTV
ND ug/1 0.50 1.0 05/31/02 08:22 KTV
ND ug/1 1.0 1.0 05/31/02 08:22 KTV
ND ug/1 2.0 1.0 05/31/02 08:22 KTV
ND ug/1 0.50 1.0 05/31/02 08:22 KTV
ND ug/l 2.0 1.0 05/31/02 08:22 KTV
ND ug/1 0.50 1.0 05/31/02 08:22 KTV
ND ug/l 0.50 1.0 05/31/02 08:22 KTV
ND ug/l 0.50 1.0 05/31/02 08:22 KTV
ND ug/l 0.50 1.0 05/31/02 08:22 KTV
ND ug/l 0.50 1.0 05/31/02 08:22 KTV
ND ug/l 0.50 1.0 05/31/02 08:22 KTV
ND ug/l 2.0 1.0 05/31/02 08:22 KTV
ND ug/l 2.0 1.0 05/31/02 08:22 KTV
ND ug/l 0.50 1.0 05/31/02 08:22 KTV
ND ug/l 0.50 1.0 05/31/02 08:22 KTV
ND ug/l 0.50 1.0 05/31/02 08:22 KTV
ND ug/l 0.50 1.0 05/31/02 08:22 KTV
ND ug/l 0.50 1.0 05/31/02 08:22 KTV
ND ug/l 0.50 1.0 05/31/02 08:22 KTV
ND ug/l 0.50 1.0 05/31/02 08:22 KTV
ND ug/l 0.50 1.0 05/31/02 08:22 KTV
ND ug/l 0.50 1.0 05/31/02 08:22 KTV
ND ug/l 0.50 1.0 05/31/02 08:22 KTV
104 t 1.0 05/31/02 08:22 KTV
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
~'~el" •~o~.,"..-trn 1ac1~
87-68-3
98-82-8
99-87-6'
75-09·2
1634-04-4
91-20-3
103-65-1
100-42·5
630-20-6
79.34.5
127-18-4
108-88·3
87-61-6
120-82-1
71-55-6
79-00-5
79-01-6
75-69·4
96-18-4
95-63-6
108-67-8
75-01-4
95-47-6
625-98-9
Page: 63
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
ace Analytical™
www.pacelabs.com .
Lab Sample No: 922283031
Client Sample ID: FB-1 DISSOLVED'• .. ,
Parameters Results Units Metals
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Lab Project Number: 9233015
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-031
Matrix: Water
Date Collected: 05/22/02 11:51
Date Received: 05/23/02 16:10
Report Limit _I[__ _...,Ac,,n,,,a~ly'-'z"'ed,___,,B.,_y CAS No. !l!illL RegLmt
Dissolved Metals. Tra.ce ICP Prep/Method: EPA 3010 / EPA 6010
Iron. Dissolved ' ND mg/l 0.050
Date Digested
Date: 06/29/02
1. 0 06/04/02
05/29/02
DJR 7439·89·6
Page: 64
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Laboratory Certification IDs REPORT OF LABORATORY ANALYSIS Laboratory Certification IDs I
NC Wastewater 12
NC Drinking Water 37706
SC 99006
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
LA Wastewater 04034
VA Drinking Water 213 1 FL NELAP E87627
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ace Analytical™
www.pacelabs.com
Lab Sample No: 922283049
Client Sample ID: 36D-DUP DISSOLVED,·
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Lab Project Number: 9233015
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-032
Matrix: Water
Date Collected: 05/22/02 11:51
Date Received: 05/23/02 16:10
Parameters Results Units Report Limit ...!!E..._ Analyzed By CAS No.
Metals
Dissolved Metals. Trace I_CP
Iron. Dissolved
Date Digested
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater. 12
NC Drinking Water 37706
SC 99006
Prep/Method: EPA 3010 / EPA 6010
ND mg/1 0.050 1. 0 06/04/02
05/29/02
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Q,1b1~~ tineac\t
DJR 7439-89·6
Page: 65
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
ace Analytical™
www.pacelabs.com
Lab Sample No: 922283056
Client Sample ID: MW-29 DISSOLVrn·:,_
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Lab Project Number: 9233015
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-033
· Hatrix: Water
Date Collected: 05/22/02 11:11
Date Received: 05/23/02 16:10
Parameters Results Units Report Limit ...QL_ Analyzed By CAS No. !h@l. RegLmt
·1
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Metals
Di sso 1 ved Metals, Tr~c·e l.CP
Iron. Dissolved /; ·· __ -_:.,
Date Digested '
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
Prep/Method: EPA 3010 / EPA 6010
NO mg/1 0.050 1. 0 06/04/02
05/29/02
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
'" •eco,, K1R."' l1.•n1-':;,c"~~
"'--~ h
OJR 7439-89·6
Page: 66
Laboratory Certification IDs I
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627 I
I
i
I
ace Analytical™
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone] www.pacelabs.com Lab Project Number: 9233015
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Lab Sample No: 922285176
Client Sample ID: MW·ll
Parameters
Metals
Metals by Trace ICP
Arsenic
Barium
Cadmium
Chromium / _ .
Lead . ,· .. ·:· •
Mang·anese
I /<,~ele"~ium
.• ,,,.: ·· Silver ,f'. / Date Digested
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Mercury, CVAAS. in Water
Mercury
Wet Chemistry
Ion Chromatography
Chloride
Nitrate
Sulfate
Alkalinity, Total
Alkalinity, Total
GC Volatiles
GC voes in Water
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
8romomethane
n-Butylbenzene
sec-Butyl benzene
tert·Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
Results Units
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-034
Matrix: Water
Date Collected: 05/23/02 11:30
Date Received: 05/24/02 13:55
Report Limit _Qf__ Analyzed By CAS No.
Prep/Method: EPA 3010 / EPA 6010
ND mg/1 0.0050 1.0 05/30/02 20:09 DJR 7440-38-2
0. 039 mg/1 0.0050 1.0 05/30/02 20:09 DJR 7440-39-3
ND mg/1 0.0010 1.0 05/30/02 20:09 DJR 7440-43-9
0. 0043 mg/1 0.0020 1.0 05/30/02 20:09 DJR 7440-47·3 1
ND mg/1 0.0050 1.0 05/30/02 20:09 DJR 7439-92-1
2.1 mg/1 0.0050 1.0 05/30/02 20:09 DJR 7439-96-5
ND mg/1 0.0050 1.0 05/30/02.20:09 DJR 7782-49-2
ND mg/1 0.0020 1.0 05/30/02 20:09 DJR 7440-22-4
05/30/02
Method: EPA 7470
ND mg/1 0.00020 1.0 06/03/02 L8G 7439-97-6
Method: EPA 300.0
4.5 mg/1
0.17
14.
mg/1
mg/1
1.0
0.10
1.0
1. 0 05/24/02
1.0 05/24/02
1.0 05/24/02
C8J 16887-00-6
CBJ
C8J
Method: EPA 310.1
28. mg/1 1.0 1. 0 06/04/02 HEH
Method: SH 62300
ND ug/1 100 200 05/31/02 09:09 KTV
ND ug/1 100 200 05/31/02 09:09 KTV
ND ug/1 100 200 05/31/02 09:09 KTV
ND ug/1 100 200 05/31/02 09:09 KTV
ND ug/1 100 200 05/31/02 09:09 KTV
ND ug/1 100 200 05/31/02 09:09 KTV
ND ug/1 200 200 05/31/02 09:09 KTV
ND ug/1 100 200 05/31/02 09:09 KTV
ND ug/1 100 200 05/31/02 09:09 KTV
ND ug/1 100 200 05/31/02 09:09 KTV
ND ug/1 100 200 05/31/02 09:09 KTV
ND ug/1 100 200 05/31/02 09:09 KTV
7600 ug/1 100 200 05/31/02 09:09 KTV
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services,_lnc.
,, ~cco~ ._,.,<:>~.,f,
-•'1/ 1..:1~ '(, ff/Ot!ld.C\\
71-43-2
108-86-1
74.97.5
75•27-4
75-25-2
74-83-9
104-51-8
135-98-8
98-06-6
56-23-5
108-90-7
75-00-3
67-66-3
Page: 67
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
ace Analytical™
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
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www.pacelabs.com
Lab Sample No: 922285176
Client Sample ID: MW·ll
Lab Project Number: 9233015
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-034
Matrix: Water
Date Collected: 05/23/02 11:30
Date Received: 05/24/02 13:55
Parameters Results Units
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
Report Limit J!L Analyzed By CAS No. Chl oromethane
2-Chlorotoluene .... ,., ..
4-Chlorotoluene _,,; :_.:,,
1.2-Dibromo-3-chloropropane 1• ,,, ,, Dibromochloromethane
1.2-Dibromo~th~ne (ED8)
Di bromofflet:h;ne
1, 2;D.i Chi orobenzene
/(3: 0; chl orobenzene
/..,..:. -·}. 4-Di chlorobenzene
Dichlorodifluoromethane
1.1-Dichloroethane
1.2-Dichloroethane
1.1-Dichloroethene
cis-1.2-Dichloroethene
trans-1.2-Dichloroethene
1,2-Dichloropropane
1.3-Dichloropropane
2.2-Dichloropropane
l.l·Dichloropropene
cis-1,3-0ichloropropene
trans-1, 3-01 chl oropropene
Diisopropyl ether
Ethyl benzene
Hexachloro-1.3-butadiene
Isopropylbenzene (Cumene)
p-lsopropyltoluene
Methylene chloride
Methyl-tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1.1.1.2-Tetrachloroethane
1.1.2.2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1.2.4-Trichlorobenzene
1.1.1-Trichloroethane
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
ND
ND
ND.
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
400 200 05/31/02 09:09 KTV 74-87-3
100 200 05/31/02 09:09 KTV 95-49-8
100 200 05/31/02 09:09 KTV 106-43·4
400 200 05/31/02 09:09 KTV 96-12-8
100 200 05/31/02 09:09 KTV 124-48·1
100 200 05/31/02 09:09 KTV 106-93-4
100 200 05/31/02 09:09 KTV 74-95-3
200 200 05/31/02 09:09 KTV 95-50-1
200 200 05/31/02 09:09 KTV 541·73·1
200 200 05/31/02 09:09 KTV 106-46-7
100 200 05/31/02 09:09 KTV 75-71-8
100 200 05/31/02 09:09 KTV 75.34.3
100 200 05/31/02 09:09 KTV 107-06-2
100 200 05/31/02 09:09 KTV 75.35.4
100 200 05/31/02 09:09 KTV 156-59·2
100 200 05/31/02 09:09 KTV 156-60·5
100 200 05/31/02 09:09 KTV 78-87-5
100 200 05/31/02 09:09 KTV 142·28·9
· 100 200 05/31/02 09:09 KTV 594-20·7
100 200 05/31/02 09:09 KTV 563-58·6
100
100
100
100
400
100
200
400
100
400
100
100
100
100
100
100
400
400
100
200 05/31/02 09:09 KTV 10061-01-5
200 05/31/02 09:09 KTV 10061-02-6
200 05/31/02 09:09 KTV 108-20-3
200 05/31/02 09:09 KTV 100-41·4
200 05/31/02 09:09 KTV 87-68-3
200 05/31/02 09:09 KTV 98-82-8
200 05/31/02 09:09 KTV 99-87-6
200 05/31/02 09:09 KTV 75-09-2
200 05/31/02 09:09 KTV 1634-04-4
200 05/31/02 09:09 KTV 91-20-3
200 05/31/02 09:09 KTV 103-65-1
200 05/31/02 09:09 KTV 100-42-5
200 05/31/02 09:09 KTV 630-20-6
200 05/31/02 09:09 KTV 79-34-5
200 05/31/02 09:09 KTV 127-18-4
200 05/31/02 09:09 KTV 108-88·3
200 05/31/02 09:09 KTV 87-61·6
200 05/31/02 09:09 KTV 120-82-1
200 05/31/02 09:09 KTV 71-55-6
Page: 68
REPORT OF LABORATORY ANALYSIS Laboratory Certification IDs I
LA Wastewater 04034 This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc. VA Drinking Water 213 1 FL NELAP E87627
I
ace Analytical™
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone] www.pacelabs.com · . Lab Project Number: 9233015
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Lab Sample No: 922285176
Client Sample ID: HW-11
Parameters
1.1,2-Trichloroethane
Trichloroethene
Tri chl orof1 uorome~t'lane-·
1,2,3-Trichloroptapa~e
1.2.4-Trimethylbenzene I 1.3.5-Trimeihyibenzene
Vinyl c~lor'i de
m&p,:,:yiene
I ,,(fXiiene
_/,,. l·Chloro·3·fluorobenzene (S)
_.,f;·~•··
~ "-1'
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Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-034
Matrix: Water
Date Collected: 05/23/02 11:30
Date Received: 05/24/02 13:55
Results Units Re~rt Limit JL.. Anal ized Bi CAS No. Q!!tl_ RegLmt
ND ug/1 100 200 05/31/02 09:09 KTV
ND ug/1 100 200 05/31/02 09:09 KTV
ND ug/1 100 200 05/31/02 09:09 KTV
ND ug/1 100 200 05/31/02 09:09 KTV
ND ug/1 100 200 05/31/02 09:09 KTV
ND ug/1 100 200 05/31/02 09:09 KTV
ND ug/1 100 200 05/31/02 09:09 KTV
ND ug/1 100 200 05/31/02 09:09 KTV
ND ug/1 100 200 05/31/02 09:09 KTV
108 t 1.0 05/31/02 09:09 KTV
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,• •cto~
.-1~-?tneiaC\\
79-00·5
79-01-6
75-69-4
96-18-4
95-63·6
108-67·8
75·01·4
95-47·6
625-98-9
Page: 69
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
ace Analytical'"
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
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www.pacelabs.com Lab Project Number: 9233015
Lab Sample No: 922285184
Client Sample ID: MW-Ill
Parameters
Metals
Metals by Trace ICP
Arsenic
Barium
Cadmium
Chromium.
Lead .· :.". •
MangtlneSe
, •·S~l 11'~; um / ;_,,• ,,. ·Silver ,{-,.-;>··· Date Digested
' . a,• -
. : ·.~-.~,...
Mercury, CVMS. in Water
Mercury
Wet Chemistry
Ion Chromatography
Chloride
Nitrate
Sulfate
Alkalinity. Total
Alkalinity. Total
GC Volatiles
GC VOCs in Water
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
BrolTK)methane
n-Butylbenzene
sec-Butyl benzene
tert-Butylbenzene
Carbon tetrachloride
Chl orobenzene
Chloroethane
Chloroform
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
"/
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-035 Date Collected: 05/23/02 10:40
Matrix: Water Date Received: 05/24/02 13: 55
Results Units Report Limit JL Analyzed By CAS No. !l!!tl_ RegLmt
Prep/Method: EPA 3010 I EPA 6010
0.013 mg/1
0.092 mg/1
ND mg/1
0.013 mg/1
ND mg/1
2.0 mg/1
ND mg/1
ND mg/1
Method: EPA 7470
ND mg/1
Method: EPA 300.0
3,3 mg/1
ND mg/1
2.7 mg/1
Method: EPA 310.1
75. mg/1
Method: SH 6230D
NO ug/1
NO ug/1
NO ug/1
NO ug/1
ND ug/1
ND ug/1
NO ug/1
ND ug/1
ND ug/1
II. ug/1
ND ug/1
NO ug/1
450 ug/1
0.0050 1.0 05/30/02 20:14 OJR 7440-38-2
0.0050 1.0 05/30/02 20:14 OJR 7440-39-3
0.0010 1.0 05/30/02 20:14 DJR 7440-43-9
0.0020 1.0 05/30/02 20:14 OJR 7440-47-3
0.0050 1.0 05/30/02 20:14 OJR 7439-92-1
0.0050 1.0 05/30/02 20:14 DJR 7439·96·5
0,0050 1.0 05/30/02 20:14 OJR 7782-49-2
0.0020 1.0 05/30/02 20:14 DJR 7440-22-4
05/30/02
0.00020 1.0 06/03/02 LBG 7439-97-6
1.0
0.10
1.0
1,0
10.
10.
10.
10.
10.
10.
20.
10.
10.
10.
10.
10.
10.
1.0 05/24/02
1.0 05/24/02
1. 0 05/24/02
I. 0 06/04/02
20.0 06/02/02
20.0 06/02/02
20.0 06/02/02
20.0 06/02/02
20.0 06/02/02
20.0 06/02/02
20.0 06/02/02
20.0 06/02/02
20.0 06/02/02
20.0 06/02/02
20.0 06/02/02
20.0 06/02/02
20.0 06/02/02
CBJ 16887-00-6
CBJ
CBJ
HEH
KTV 71-43-2
KTV 108-86-1
KTV 74.97.5
KTV 75-27-4
KTV 75-25-2
KTV 74-83-9
KTV 104-51-8
KTV 135-98-8
KTV 98-06-6
KTV 56-23-5
KTV 108-90-7
KTV 75-00-3
KTV 67-66-3
I
Page: 70
REPORT OF LABORATORY ANALYSIS Laboratory Certification IDs I
LA Wastewater 04034 This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc. VA Drinking Water 213
FL NELAP E87627 I
ace Analytical™
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suile 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone] www.pacelabs.com
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Lab Sample No: 922285184
Client Sample lD: MW-111
Parameters
Chloromethane
2-Chlorotoluene
4-Chlorotoluene .. : /
1, 2-Di bromo-3-chloropropane
Di bromoch l orom~J ha-ne
1,2-Dibromoethane (EDB}
Di bromoffietll;ne /"' ~r
1,/ -~~i chl orobenzene
I .<<!-,3~Dichlorobenzene
/;·,:.-
11, 4 -Di chl orobenzene.
,--::if:_.,.,· Di chl orodi fl uoromethane ,1,, 1, l·Dichloroethane
1.2-Dichloroethane
1.1-Dichloroethene
cis-1,2-Dichloroethene
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trans-1.2-Dichloroethene
1.2-Dichloropropane
1,3-Dichloropropane
2.2-Dichloropropane
1.1-Dichloropropene
cis-1,3-Dichloropropene
trans-1.3-Dichloropropene
Diisopropyl ether
Ethyl benzene
Hexachloro-1.3-butadiene
Jsopropylbenzene (Cumene)
p·lsopropyltoluene
Methylene chloride
Methyl-tert-butyl ether
Naphthalene
n· Propyl benzene
Styrene
1.1.1,2-Tetrachloroethane
1,1.2.2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1.2.4-Trichlorobenzene
1.1.1-Trichloroethane
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
Lab Project Number: 9233015
I. Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-035
Matrix: Water
Results Units Re~ort Limit ..!lL.. Anal ~zed
ND ug/l 40. 20.0 06/02/02
ND ug/l 10. 20. 0 06/02/02
NO ug/l 10. 20.0 06/02/02
NO ug/l 40. 20.0 06/02/02
NO ug/l 10. 20.0 06/02/02
NO ug/l 10. 20. 0 06/02/02
NO ug/l 10. 20.0 06/02/02
ND ug/l 20. 20.0 06/02/02
NO ug/l 20. 20.0 06/02/02
NO ug/l 20. 20.0 06/02/02
ND ug/l 10. 20.0 06/02/02
NO ug/l 10. 20.0 06/02/02
ND ug/l 10. 20. 0 .06/02/02
ND ug/l 10. 20. 0 06/02/02
NO ug/1 10. 20.0 06/02/02
NO ug/l 10. 20.0 06/02/02
NO ug/l 10. 20.0 06/02/02
NO ug/1 10. 20.0 06/02/02
NO ug/l 10. 20.0 06/02/02
NO ug/l 10. 20.0 06/02/02
NO ug/l 10. 20. 0 06/02/02
NO ug/l 10. 20.0 06/02/02
ND ug/1 10. 20.0 06/02/02
ND ug/l 10. 20.0 06/02/02
NO ug/l 40. 20.0 06/02/02
ND ug/l 10. 20. 0 06/02/02
NO ug/l 20. 20.0 06/02/02
ND ug/l 40. 20.0 06/02/02
ND ug/l 10. 20. 0 06/02/02
ND ug/l 40. 20.0 06/02/02
ND ug/l 10. 20.0 06/02/02
ND ug/l 10. 20.0 06/02/02
ND ug/l 10. 20.0 06/02/02
ND ug/l 10. 20.0 06/02/02
NO ug/l 10. 20. 0 06/02/02
470 ug/l 10. 20.0 06/02/02
NO ug/l 40. 20,0 06/02/02
NO ug/1 40. 20.0 06/02/02
10. ug/l 10. 20.0 06/02/02
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consen_t of Pace Analytical Services, Inc.
,.,~~4+ ,·>'.1_,~t-
fflnt:1aC\1
Date Collected: 05/23/02 10:40
Date Received: 05/24/02 13:55
B~ CAS No. !l!§l._ RegLmt
KTV 74-87-3
KTV 95-49-8
KTV 106-43·4
KTV 96-12·8
KTV 124-48-1
KTV 106-93-4
KTV 74.95.3
KTV 95·50-1
KTV 541-73·1
KTV 106-46-7
KTV 75-71-8
KTV 75.34.3
KTV 107-06-2
KTV 75.35.4
KTV 156-59·2
KTV 156-60-5
KTV 78-87-5
KTV 142-28·9
KTV 594-20-7
KTV 563-58-6
KTV 10061·01-5
KTV 10061-02-6
KTV 108-20·3
KTV 100-41·4
KTV 87-68-3
KTV 98-82-8
KTV 99·87•6
KTV 75-09-2
KTV 1634-04-4
KTV 91-20-3
KTV 103-65-1
KTV 100-42·5
KTV 630-20·6
KTV 79.34.5
KTV 127-18·4
KTV 108-88-3
KTV 87-61-6
KTV 120-82·1
KTV 71-55-6
Page: 71
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
ace Analytical™
www.pacelabs.com
Lab Sample No: 922285184
Client Sample ID: MW·lll
Parameters Results Units
1.1.2-Trichloroethane NO ug/l
Tri chl oroethene / NO ug/l
Tri chl orof1 uoromethalle··-NO ug/l
1.2.3-Trichloropropane NO ug/l
1.2.4-Trimethylbenzene NO . ug/l
1. 3, 5-Tri methyl benzene NO ug/l /., .. -
Vi nyl.,,~h,lori de NO ug/l
m&p'Xylene ND ug/1 / ; .. _.,,~_9.: Xylene NO ug/l
Lab Project Number: 9233015
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-035 Date Co 11 ected: 05/23/02 10: 40
Matrix: Water Date Received: 05/24/02 13:55
Reoort Limit ...QL_ Analyzed Bl CAS No. 9!!tl_ Reglmt
10. 20.0 06/02/02 KTV 79-00-5
10. 20.0 06/02/02 KTV 79-01-6
10. 20.0 06/02/02 KTV 75-69-4
10. 20. 0 06/02/02 KTV 96-18-4
10. 20.0 06/02/02 KTV 95-63-6
10. 20.0 06/02/02 KTV 108-67-8
10. 20.0 06/02/02 KTV 75-01-4
10. 20.0 06/02/02 KTV
10. 20.0 06/02/02 KTV 95-47-6
/'.·· 1-Chloro-3-fluorobenzene (SJ 103 X / . I. 0 06/02/02 KTV 625-98-9
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/.,' ~«•.-,,
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,• •cco., ,,_,;,~~ .. l'/·1 ·t=::. "{ .. :iin~mc1~
Page: 72
Laboratory Certification IDs I
LA Wastewater 04034
FL NELAP E87627
VA Drinking Water 213 1
'
I
,,
I ace Analytical™
Pace Analytical Services, Inc,
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone] www,pacelabs,com
I
I
I
I
Lab Sample No: 922285192
Client Sample ID: MW-121
Parameters
Metals
Metals by Trace ICP
Arsenic
Barium
Cadmium
Chromium
Lead ,. · .. '
Mang-aneSe .,,. ,,,·
I. /.,~elenium
/··Silver
,.-a.,,. Date Digested ' :,
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Mercury, CVA/>S, in Water
Mercury
Wet Chemistry
Ion Chromatography
Chloride
Nitrate
Sulfate
Alkalinity, Total
Alkalinity, Total
GC Volatiles
GC VOCs in Water
Benzene
Bromobenzene
Bromochloromethane
Broroodichloromethane
Bromoform
Brornomethane
n•Butylbenzene
sec-Butyl benzene
tert-8utylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Oate: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
Lab Project Number: 9233015
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-036
Matrix: Water
Date Collected: 05/23/02 09:40
Date Received: 05/24/02 13:55
Results Units Report Limit _Qf__ Analyzed By CAS No. ~ RegLmt
Prep/Method: EPA 3010 / EPA 6010
0.024 mg/1 0.0050 1.0 05/30/02 20:19 DJR 7440-38·2
0 .090 mg/1 0.0050 1.0 05/30/02 20:19 DJR 7440-39-3
0.0013 mg/1 0.0010 1.0 05/30/02 20:19 OJR 7440-43-9
0.0040 mg/1 0.0020 1.0 05/30/02 20:19 DJR 7440-47-3 1
O .0062 mg/1 0.0050 1.0 05/30/02 20:19 OJR 7439·92·1
0.25 mg/1 0.0050 1.0 05/30/02 20:19 DJR 7439-96-5
ND mg/1 0.0050 1.0 05/30/02 20:19 DJR 77B2•49·2
ND mg/1 0.0020 1.0 05/30/02 20:19 OJR 7440-22·4
05/30/02
Method: .EPA 7470
ND mg/1 0.00020 1.0 06/03/02 LBG 7439-97-6
Method: EPA 300.0
2.3 mg/1
0.43 mg/1
1.0
0.10
1.0
1. 0 05/24/02
1. 0 05/24/02
1. 0 05/24/02
CBJ 16887-00·6
CBJ
2.0 mg/1
Method: EPA 310 .1
25. mg/1 1.0 1.0 06/04/02
Method: SM 6230D
ND ug/1 5.0 10.0 06/03/02
ND ug/1 5.0 10.0 06/03/02
ND ug/1 5,0 10.0 06/03/02
ND ug/1 5.0 10.0 06/03/02
ND ug/1 5.0 10.0 06/03/02
ND ug/1 5.0 10.0 06/03/02
ND ug/1 10. 10.0 06/03/02
ND ug/1 5.0 10.0 06/03/02
ND ug/1 5.0 10.0 06/03/02
170 ug/1 5.0 10. 0 06/03/02
ND ug/1 5.0 10.0 06/03/02
ND ug/1 5.0 10.0 06/03/02
1600 ug/1 50. 100 06/03/02
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
..... ~ .. .,
//, 1:::, "'' ?1De1<:1.C\1
CBJ
HEH
KTV 71-43·2
KTV lOB-86-1
KTV 74.97.5
KTV 75-27·4
KTV 75-25-2
KTV 74-B3·9
KTV 104-51-8
KTV 135-9B-8
KTV 98-06-6
KTV 56-23-5
KTV 10B-90-7
KTV 75-00-3
KTV 67-66-3
Page: 73
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP . E87627
ace Analytical™
www.pacelabs.com
Lab Sample No: 922285192
Client Sample IO: MW·12I
~Pa~r~a""me'"t"'e"-r"-s ______ ""-·~''--Results
Chloromethane NO
2-Chlorotoluene NO
4-Chlorotoluene .:.· '· ·
1.2-Dibromo-3-chloropropane ,·: > Oibromochloromethane
1. 2-0i bromoet·h,.ne (EDB)
Di bromo:e;i;ne
1. 2 i(}i-~hl orobenzene .,.
/'l ·, 3'-0i chl orobenzene _.,c("• i .4-Dichlorobenzene
NO
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Lab Project Number: 9233015
Phone: [phone]
Fax: [phone]
Client Project IO: NCSU Lot 86/2246
Project Sample Number: 9233015-036
Matrix: Water
Reoort Limit J1L Analyzed
20. 10.0 06/03/02
5.0 10.0 06/03/02
5.0 10.0 06/03/02
Date Collected: 05/23/02 09:40
Date Received: 05/24/02 13:55
By CAS No. lli@L RegLmt
__ ,,{:·, Di chl orodi fl uoromethane ... _ ...
NO
NO
16.
ND
ND
ND
ND
13.
NO
NO
NO
NO
NO
34.
NO
NO
ND
ND
NO
NO
NO
NO
NO
ND
NO
NO
ND
NO
ND
ND
ND
130
NO
Units
ug/1
ug/l
ug/l
ug/l
ug/1
ug/1
ug/1
ug/1
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/1
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/1
ug/1
ug/1
ug/1
ug/l
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/l
ug/l
20.
5.0
5.0
5.0
10.
10.
10.
5.0
10.0 06/03/02
10.0 06/03/02
10.0 06/03/02
10. 0 06/03/02
10. 0 06/03/02
10.0 06/03/02
10.0 06/03/02
10. 0 06/03/02
10.0 06/03/02
10. 0 06/03/02
10.0 06/03/02
10.0 06/03/02
10. 0 06/03/02
10.0 06/03i02
10.0 06/03/02
10.0 06/03/02
10.0 06/03/02
10.0 06/03/02
10.0 06/03/02
10.0 06/03/02
10.0 06/03/02
10. 0 06/03/02
10.0 06/03/02
10.0 06/03/02
10.0 06/03/02
10. 0 06/03/02
10.0 06/03/02
10.0 06/03/02
10.0 06/03/02
10.0 06/03/02
10. 0 06/03/02
10.0 06/03/02
10.0 06/03/02
10. 0 06/03/02
10.0 06/03/02
10.0 06/03/02
KTV 74-87 ·3
KTV 95·49·8
KTV 106-43-4
KTV 96· 12·8
KTV 124·48· l
KTV 106-93·4
KTV 74·95-3
KTV 95·50·1
KTV 541-73•1
KTV 106-46· 7
KTV 75·71-8
KTV 75.34.3
KTV 107·06·2
KTV 75.35.4
KTV 156-59·2
KTV 156·60·5
KTV 78-87-5
KTV 142·28-9
KTV 594·20-7
KTV 563-58-6
KTV 10061·01-5
KTV 10061·02·6
KTV 108·20·3
KTV 100·41·4
KTV 87-68·3
KTV 98-82-8
KTV 99·87·6
KTV 75·09·2
KTV 1634-04-4
KTV 91·20·3
KTV 103·65-l
KTV 100·42·5
KTV 630-20·6
KTV 79-34·5
KTV 127 · 18·4
KTV 108·88·3
KTV 87-61·6
KTV 120·82·1
KTV 71·55-6
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l.l·Dichloroethane
1.2-Dichloroethane
1.1-Dichloroethene
cis-1.2-0ichloroethene
trans-1.2-0ichloroethene
1.2-Dichloropropane
1.3-Dichloropropane
2.2-Dichloropropane
1.1-Dichloropropene
cis-1.3-0ichloropropene
trans-1.3-Dichloropropene
Diisopropyl ether
Ethyl benzene
Hexachloro-1,3-butadiene
Isopropylbenzene (Cumene)
p·Isopropyltoluene
Methylene chloride
Methyl-tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,l,1,2-Tetrachloroethane
1.1.2.2-Tetrachloroethane
Tetrachloroethene
Toluene
1.2.3-Trichlorobenzene
1.2.4-Trichlorobenzene
1.1.1-Trichloroethane
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
ND
ND
ND
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
20.
5.0
10.
20.
5.0
20.
5.0
5.0
5.0
5.0
5.0
5.0
20.
20.
5.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Page: 74
Laboratory Certification IDs I
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627 I
ace Analytical™
www.pacelabs.com
Lab Sample No: 922285192
Client Sample ID: MW-121
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Lab Project Number: 9233015
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-036 Date Collected: 05/23/02 09: 40
Matrix: Water Date Received: 05/24/02 13:55
I
I Parameters Results Units ReQort Limit _QE._ Anal ized Bi CAS No. ~ RegLmt
I
I
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane ·
1.2,3-Trichloropropane
1. 2, 4 · Tri methyi°b~nzene
1.3,5-Trimethy{benzene
Vinyl chl~ride
m&p0 X~l ~~e
I /r§; xylene
_,,/-' l-Chloro-3-fluorobenzene CS) --~:-'
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Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
28. ug/1 5.0 10.0 06/03/02
110 ug/1 5.0 10.0 06/03/02
ND ug/1 5.0 10.0 06/03/02
ND ug/1 5.0 10.0 06/03/02
ND ug/1 5.0 10. 0 06/03/02
ND ug/1 5.0 10.0 06/03/02
ND ug/1 5.0 10.0 06/03/02
ND ug/1 5.0 10.0 06/03/02
ND ug/1 5.0 10.0 06/03/02
105 ~ 1. 0 06/03/02
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,• >Ceo,. ~~~~ t1nelac\\
KTV 79-00-5
KTV 79-01-6
KTV 75-69-4
KTV 96-18-4
KTV 95-63-6
KTV 108-67-8
KTV 75-01-4
KTV
KTV 95-47-6
KTV 625-98-9
Page: 75
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
ace Analytical™
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
I
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I
www.pacelabs.com
Lab Project Number: 9233015
Lab Sample No: 922285200
Client Sample JD: MW-161
Parameters
Metals
Metals by Trace ICP • ·
Arsenic
Barium
Cadmium
Chrorni um , ..... ·
Lead .·• / .. h ,_,.-
Manganese
,,-/ ,,/
/~~elenium
_,,(_/Silver / ., . .<;.: -· Date Digested
Mercury. CVMS. in Water
Mercury
Wet Chemistry
Jon Chromatography
Chloride
Nitrate
Sulfate
Alkalinity. Total
Alkalinity, Total
GC Volatiles
GC voes in Water
Benzene
Brornobenzene
Bromochloromethane
Brornodichloromethane
Bromoform
Broroomethane
n-Butylbenzene
sec-Butyl benzene
tert·8utylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Oate: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
.. J •
Units
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-037
Matrix: Water
Date Collected: 05/23/02 08:30
Date Received: 05/24/02 13:55
Report Limit __Q[_ --'-'An"'a~l~yz~e~d-~8y~ CAS No. llifil_ RegLmt
Prep/Method: EPA 3010 / EPA 6010
ND
0. 14
ND
0.060
0.0050
0.34
ND
NO
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
Method: EPA 7470
NO mg/1
Method: EPA 300.0
2.0 mg/1
0.35
2.1
mg/1
mg/1
Method: EPA 310.1
85. mg/1
Method: SM 62300
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
160 ug/1
0.0050 1.0 05/30/02 20:24 OJR 7440·38·2
0.0050 1.0 05/30/02 20:24 DJR 7440-39-3
0.0010 1.0 05/30/02 20:24 DJR 7440-43-9
0.0020 1.0 05/30/02 20:24 OJR 7440-47-3
0.0050 1.0 05/30/02 20:24 DJR 7439-92-1
0.0050 1.0 05/30/02 20:24 DJR 7439-96-5
0.0050 1.0 05/30/02 20:24 DJR 7782-49-2
0.0020 1.0 05/30/02 20:24 DJR 7440-22-4
05/30/02
0.00020 1.0 06/03/02 L8G 7439-97-6
1.0 1.0 05/24/02
0.10
1.0
1.0
0.50
0.50
0.50
0.50
0.50
0.50
1.0
0.50
0.50
0.50
0.50
0.50
2.5
1. 0 05/24/02
1. 0 05/24/02
1. 0 06/05/02
1. 0 06/02/02
1. 0 06/02/02
1.0 06/02/02
1.0 06/02/02
1.0 06/02/02
1.0 06/02/02
1. 0 06/02/02
1.0 06/02/02
1.0 06/02/02
1. 0 06/02/02
1. 0 06/02/02
1. 0 06/02/02
5.0 06/02/02
C8J 16887-00-6
C8J
C8J
HEH
KTV 71-43-2
KTV 108-86-1
KTV 74-97-5
KTV 75-27-4
KTV 75-25-2
KTV 74-83-9
KTV 104-51-8
KTV 135-98-8
KTV 98-06-6
KTV 56-23-5
KTV 108-90-7
KTV 75-00-3
KTV 67-66-3
1
Page: 76
REPORT OF LABORATORY ANALYSIS Laboratory Certification IDs I
LA Wastewater 04034 This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
~ J1nelaat
VA Drinking Water 213
FL NELAP E87627 I
ace Analytical™
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
I
I
I
I
www.pacelabs.com Lab Project Number: 9233015
Phone: [phone]
Fax: [phone]
I
I
Lab Sample No: 922285200
Client Sample ID: MW-161
Parameters
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1, 2 ·Di bromo-3· chl_orop~opane
Dibromochlorometh~ne , •/ 1.2-Dibromcethane (ED8)
DibromolTI~tti;ne ,-~,; r 1,2-Dichlorobenzene
I _,,,-f:ic□ichlorobenzene
/'_:/ 1,4-Dichlorobenzene .. <:1J-,;,~ Di chl orodifl uoromethane
I
I
I
I
I
D
I
I
I
I
I
l.l·Dichloroethane
1,2-Dichloroethane
1.1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1.2-Dichloropropane
1,3-0ichloropropane
2.2-Dichloropropane
1,1-Dichloropropene
cis-1,3-0ichloropropene
trans·l,3-Dichloropropene
Diisopropyl ether
Ethyl benzene
Hexachloro·l.3-butadiene
Isopropylbenzene (Cumene)
· p-lsopropyltoluene
Methylene chloride
Methyl-tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1.1.1.2-Tetrachloroethane
1,1.2.2·Tetrachloroethane
Tetrachloroethene
Toluene
1.2.3-Trichlorobenzene
1,2.4-Trichlorobenzene
1.1.l·Trichloroethane
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
/
Client Project ID: NCSU Lot 86/2246
< '/,, J Project Sample Number: 9233015-037
. ';• Matrix: Water 'I
Results Units ReQQrt Limit .JlL Anal l'.Zed
NO ug/1 2.0 1.0 06/02/02
ND ug/1 0.50 1. 0 06/02/02
ND ug/1 0.50 1.0 06/02/02
ND ug/1 2.0 !. 0 06/02/02
ND ug/1 0.50 1.0 06/02/02
ND ug/1 0.50 1. 0 06/02/02
ND ug/1 0.50 1.0 06/02/02
ND ug/1 1.0 !. 0 06/02/02
ND ug/1 1.0 1.0 06/02/02
ND ug/1 1.0 1. 0 06/02/02
ND ug/1 0.50 1.0 06/02/02
ND ug/1 0.50 !. 0 06/02/02
ND u9/l 0.50 1.0 06/02/02
ND ug/1 0.50 1.0 06/02/02
NO ug/1 0.50 1.0 06/02/02
ND ug/1 0.50 1.0 06/02/02
1.9 ug/1 0.50 1.0 06/02/02
ND ug/1 0.50 1.0 06/02/02
NO ug/1 0.50 1.0 06/02/02
NO ug/1 0.50 1.0 06/02/02
ND ug/1 0,50 1.0 06/02/02
NO ug/1 0.50 1.0 06/02/02
NO ug/1 0.50 1. 0 06/02/02
NO ug/1 0.50 1. 0 06/02/02
NO ug/1 2.0 1. 0 06/02/02
ND ug/1 0.50 1.0 06/02/02
NO ug/1 1.0 1. 0 06/02/02
ND ug/1 2.0 1.0 06/02/02
NO ug/1 0.50 1. 0 06/02/02
NO ug/1 2.0 1.0 06/02/02
ND ug/1 0.50 1. 0 06/02/02
NO ug/1 0.50 1. 0 06/02/02
ND ug/1 0.50 !. 0 06/02/02
NO ug/1 0.50 !. 0 06/02/02
1.2 ug/1 0.50 1.0 06/02/02
NO u9/l 0.50 1. 0 06/02/02
NO ug/1 2.0 1.0 06/02/02
NO u9/l 2.0 1. 0 06/02/02
NO ug/1 0.50 1.0 06/02/02
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,~ ""o~ ,·~-ff/Ot:U:t.C\\
Date Collected: 05/23/02 08:30
Date Received: 05/24/02 13:55
8~ CAS No. lli!ll_ RegLmt
KTV 74-87·3
KTV 95-49·8
KTV 106-43·4
KTV 96· 12·8
KTV 124·48·1
KTV 106-93·4
KTV 74.95.3
KTV 95-50·1
KTV 541·73·1
KTV 106-46·7
KTV 75·71·8
KTV 75.34.3
KTV 107•06·2
KTV 75.35.4
KTV 156-59·2
KTV 156-60·5
KTV 78-87·5
KTV 142-28-9
KTV 594-20·7
KTV 563-58-6
KTV 10061-01·5
KTV 10061·02·6
KTV 108-20·3
KTV 100-41·4
KTV 87-68·3
KTV 98-82-8
KTV 99-87-6
KTV 75-09·2
KTV 1634-04-4
KTV 91·20·3
KTV 103-65·1
KTV 100-42-5
KTV 630·20·6
KTV 79.34.5
KTV 127-18·4
KTV 108-88·3
KTV 87-61·6
KTV 120·82·1
KTV 71-55·6
Page: 77
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
ace Analytical™
www.pacelabs.com
Lab Sample No: 922285200
Client Sample ID: MW-16!
Parameters
1.1.2-Trichloroethane
Trichloroethene
Trichlorofluoramethane··
1, 2, 3 · Tri chl oropropah~
1.2 ,4· Trimethylbenzene
1. 3. 5 · Tri me_thyfoenzene
Vinyl_ctiloride
"/ m&p 0Xylene ,-:,·-'.,. ....
.' Results Units
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Lab Project Number: 9233015
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015·037 Date Collected: 05/23/02 08:30
Matrix: Water Date Received: 05/24/02 13:55
Ret22rt Limit ..QE_ Anal :z::zed B~ CAS No. !l!!2l_ RegLmt
0,50 1. 0 06/02/02 KTV 79-00-5
0.50 1. 0 06/02/02 KTV 79-01-6
o.5o· 1.0 06/02/02 KTV 75-69-4
0.50 1. 0 06/02/02 KTV 96·18•4
0.50 1.0 06/02/02 KTV 95-63-6
0.50 1.0 06/02/02 KTV 108-67·8
0.50 1.0 06/02/02 KTV 75·01•4
0.50 . 1.0 06/02/02 KTV
0.50 1.0 06/02/02 KTV 95-47-6 ,..,.;9)Xylene
,/',:' / ·1 ·Chl oro-3-fl uorobenzene CS) ,,_.,,,,,,,
ND
ND
ND
ND
ND
ND
ND
ND
ND
93 t 1.0 06/02/02 KTV 625-98·9
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,-•cca~0~
l '¾'..-fl _ C11
Page: 78
Laboratory Certification IDs I
LA Wqstewater 04034
VA Drinking Water 213
FL NELAP E87627 I
I
I
I
I
I
ace Analytical™
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone] www.pacelabs.com Lab Project Number: 9233015
I
Lab Sample No: 922285218
Client Sample ID: MW-171
Parameters
Metals
Metals by Trace ICP
Arsenic
Barium
Cadmium
Chromium
Lead ,": Jl,·" /~-. ,,,
ManganeSe ,... ,.,·
I ✓,,~elenium
/.• Silver
,,r,,_r/ • ..--. . Date Digested ,,,.,
,;"
I
I
I
I
I.
I
I
I
I
I
I
I
Mercury, CVAAS. in Water
Mercury
Wet Chemistry
Ion Chromatography
Chloride
Nitrate
Sulfate
Alkalinity, Total
Alkalinity, Total
GC Volatiles
GC voes in Water
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n•Butylbenzene
sec-8utylbenzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
· NC Drinking Water 37706
SC 99006
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-038
Matrix: Water
Date Collected: 05/23/02 10:10
Date Received: 05/24/02 13:55
Results Units Report Limit _QL Analyzed By CAS No.
Prep/Method: EPA 3010 / EPA 6010
NO
0.019
ND
0.012
ND
0.22
ND
ND
mg/1
. mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
Method: EPA 7470
0.0050
0,0050
0.0010
0.0020
0.0050
0.0050
0.0050
0.0020
1.0 05/30/02 20:48 DJR 7440-38-2
1.0 05/30/02 20:48 DJR 7440-39-3
1.0 05/30/02 20:48 DJR 7440-43-9
1.0 05/30/02 20:48 DJR 7440-47-3 l
1.0 05/30/02 20:48 DJR 7439-92-1
1.0 05/30/02 20:48 OJR 7439-96-5
1.0 05/30/02 20:48 DJR 7782-49-2
1.0 05/30/02 20:48 OJR 7440-22-4
05/30/02
ND mg/1 0.00020 1.0 06/03/02 LBG 7439-97-6
Method: EPA 300.0
2.5 mg/1
0.22
NO
mg/1
mg/1
Method: EPA 310.1
7.5 mg/1
Method: SH 62300
340 ug/1
NO ug/1
NO ug/1
ND ug/1
ND ug/1
NO ug/1
NO ug/1
ND ug/1
ND ug/1
16. ug/1
ND ug/1
NO ug/1
230 ug/1
1.0
0.10
1.0
1.0
10,
0.50
0.50
0.50
0.50
0.50
1.0
0.50
0.50
0.50
0.50
0.50
10.
1.0 05/24/02
1.0 05/24/02
1. 0 05/24/02
1. 0 06/05/02
20. 0 06/02/02
1.0 06/02/02
1.0 06/02/02
1.0 06/02/02
1.0 06/02/02
1.0 06/02/02
1. 0 06/02/02
1.0 06/02/02
1.0 06/02/02
1. 0 06/02/02
1.0 06/02/02
1.0 06/02/02
20. 0 06/02/02
REPOIRT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
._<>'°'/ 1_1 +.,,. ,,~'" •Ceo""~
fin~-Cl\
CBJ 16887-00-6
CBJ
CBJ
HEH
KTV 71-43-2
KTV 108-86-1
KTV 74.97.5
KTV 75-27-4
KTV 75-25-2
KTV 74-83-9
KTV 104-51·8
KTV 135-98-8
KTV 98-06-6
KTV 56-23-5
KTV 108-90-7
KTV 75-00-3
KTV 67-66-3
Page: 79
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
ace Analytical'"
www.pacelabs.com
Lab Sample No: 922285218
Client Sample ID: MW-171
Parameters
Chloromethane
2-Chlorotoluene
4-Chlorotoluene /' ; ... . ,,
1,2-Dibromo-3-chioropropane ·.","'1",. Di bromochl o:,o~thane
1.2-0ibromoetti"ane (EDS)
Dibromofnitti~ne / f 1. 2:=D.i Chlorobenzene
/1 }i'~Di chl orobenzene ,,. ~«:'1· -1.4-0ichlorobenzene
Results
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Lab Project Number: 9233015
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-038
Matrix: Water
Reoort Limit ..m:__ Analyzed
2.0 1.0 06/02/02
Date Collected: 05/23/02 10:10
Date Received: 05/24/02 13:55
By CAS No. !lJ!tl_ RegLmt
.,.,. ;.fo
/; :--Di chlorodi fl uoromethane
ND
ND
NO
ND
NO
10.
ND
ND
ND
ND
ND
ND
2.1
Units
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
0.50
0.50
2.0
0.50
0.50
0.50
1.0
1.0
1.0
0.50
0.50
0.50
0.50
0.50
0.50
10.
0.50
1.0 06/02/02
1.0 06/02/02
1.0 06/02/02
1. 0 06/02/02
1.0 06/02/02
1. 0 06/02/02
1. 0 06/02/02
1. 0 06/02/02
1. 0 06/02/02
1.0 06/02/02
1. 0 06/02/02
1. 0 06/02/02
1.0 06/02/02
1.0 06/02/02
1. 0 06/02/02
20.0 06/02/02
KTV 74-87-3
KTV 95-49-8
KTV 106-43-4
KTV 96-12-8
KTV 124-48-1
KTV 106-93-4
KTV 74.95.3
KTV 95-50-1
KTV 541-73-1
KTV 106-46-7
KTV 75-71-8
KTV 75-34-3
KTV 107-06-2
KTV ·75-35-4
KTV 156-59-2
KTV 156-60-5
KTV 78-87-5
KTV 142-28-9
KTV 594-20-7
KTV 563-58-6
KTV 10061-01-5
KTV 10061-02-6
KTV 108-20·3
KTV 100-41·4
KTV 87-68-3
KTV 98-82-8
KTV 99-87-6
KTV 75-09-2
KTV 1634·04·4
KTV 91-20-3
KTV 103-65-1
KTV 100-42-5
KTV 630-20-6
KTV 79.34.5
KTV 127-18-4
KTV 108-88-3
KTV 87-61-6
KTV 120-82-1
KTV 71-55-6
I
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I
:~. 1,1-Dichloroethane
1,2-0ichloroethane
1.1-Dichloroethene
cis-1,2-Dichloroethene
trans-1.2-Dichloroethene
1,2-Dichloropropane
1.3-0ichloropropane
2,2-0ichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1.3-Dichloropropene
Oiisopropyl ether
Ethyl benzene
Hexachloro-1,3-butadiene
Isopropylbenzene (Cumene)
p-Isopropyltoluene
Methylene chloride
Methyl-tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1.1.1,2-Tetrachloroethane
1,1,2.2-Tetrachloroethane
Tetrachloroethene
Toluene
1.2.3-Trichlorobenzene
1,2.4-Trichlorobenzene
1.1.1_-Trichloroethane
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
ND
NO
ND
130
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
20.
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
0.50
0.50
0.50
0.50
0.50
0.50
2.0
0.50
1.0
2.0
0.50
2.0
0.50
0.50
0.50
0.50
0.50
0.50
2.0
2.0
0.50
1.0 06/02/02
1.0 06/02/02
1.0 06/02/02
1. 0 06/02/02
1.0 06/02/02
1. 0 06/02/02
1. 0 06/02/02
1. 0 06/02/02
1. 0 06/02/02
1.0 06/02/02
1.0 06/02/02
1.0 06/02/02
1.0 06/02/02
1.0 06/02/02
1.0 06/02/02
1.0 06/02/02
1.0 06/02/02
1.0 06/02/02
1. 0 06/02/02
1. 0 06/02/02
1. 0 06/02/02
1.0 06/02/02
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Page: 80
Laboratory Certification IDs I
LA Wastewater 04034
FL NELAP E87627
VA Drinking Water 213 1
I
ace Analytical™
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
www.pacelabs.com
Lab Project Number: 9233015
Phone: [phone]
Fax: [phone]
I
I
I
I
Lab Sample No: 922285218
Client Sample ID: MW-171
Parameters
1,1.2-Trichloroethane J
Trichloroethene
Trichlorofluorometnan~·
1.2,3-Trichloropropane
1, 2. 4-Trimethyi,benzene
1,3.5-Trimethylbenzene
Vinyl _chl~T'-ide
/ _.,/
I ,,,,it~;~:ne
,/'·.,: '1 -Chl oro-3-fl uorobenzene (SJ
,1/",~.,.
,• .,,'
I
I
I
I
I
I
I
I
I
I
I
I
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
,.f.
,,:!.
Client Project ID: NCSU Lot 86/2246
', Project Sample Number: 9233015-038 ··•: Matrix: Water
Results Units Re122rt Limit .J)f_ Anal ized
I. 7 ug/l 0,50 I. 0 06/02/02
13, ug/l 0.50 1. 0 06/02/02
ND u9/l 0.50 1.0 06/02/02
3,6 ug/l 0,50 1. 0 06/02/02
ND ug/1 0.50 1.0 06/02/02
ND ug/l 0,50 I. 0 06/02/02
ND ug/l 0.50 1. 0 06/02/02
ND ug/l 0.50 1.0 06/02/02
ND ug/l 0.50 I. 0 06/02/02
102 t 1.0 06/02/02
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,~ ACco., ........ ~~+.
o'i'l-l'>-'§ {/J)t:::1aC\1
Date Collected: 05/23/02 10: 10
Date Received: 05/24/02 13:55
8t CAS No. Q!!tl_ RegLmt
KTV 79-00-5
KTV 79-01-6
KTV 75-69-4
KTV 96-18-4
KTV 95-63-6
KTV 108-67-8
KTV 75-01-4
KTV
KTV 95-47-6
KTV 625-98·9
Page: 81
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
ace Analytical™
www.pacelabs.com
Lab Sample No: 922285226
Client Sample ID: MW-38
Parameters Results Units Metals
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Lab Project Number: 9233015
Phone: [phone]
Fax: [phone]
Client Project IO: NCSU Lot 86/2246
Project Sample Number: 9233015-039
Matrix: Water
Date Collected: 05/23/02 09:10
Date Received: 05/24/02 13:55
Report Limit ..fil_ _ __,:,A,,,na,_,l..,_y,,,ze,,d,_---"B,_y ~C~A~S~N~o~·-!l!!tl.._ RegLmt
Metals by Trace !CP
Arsenic
Prep/Method: EPA 3010 / EPA 6010
Barium '· ,r-
Cadmium
Chromium_ ,
Lead ," /,{· MangarieSe
/.~~ienium
.. /1·/ Silver
"' Date Digested
Mercury, CVMS. in Water
Mercury
Wet Chemistry
Ion Chromatography
Chloride
Nitrate
Sulfate
Alkalinity, Total
Alkalinity, Total
GC Volatiles
GC VOCs in Water
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromornethane
n-Buty1benzene
sec-Butyl benzene
tert-Butylbenzene
Carbon tetrachloride
Chl orobenzene
Chloroethane
Chloroform
Date: 06/29/02
ND mg/l
0.016 mg/l
NO mg/l
0 .003B mg/1
NO mg/l
0.031 mg/l
NO mg/l
ND mg/l
Method: EPA 7470
NO mg/l
Method: EPA 300.0
1.9 mg/l
NO mg/l
3.5 mg/l
Method: EPA 310.1
120 mg/l
Method: SM 6230D
ND ug/l
ND ug/l
NO ug/l
NO ug/l
ND ug/l
ND ug/l
ND ug/l
ND ug/l
ND ug/1
ND ug/l
NO ug/l
NO ug/l
NO ug/l
0.0050
0.0050
0.0010
0.0020
0.0050
0.0050
0.0050
0.0020
0.00020
1.0
0.10
1.0
1.0
0.50
0.50
0.50
0.50
0.50
0.50
1.0
0.50
0.50
0.50
0.50
0.50
0.50
1.0 05/30/02 20:53 OJR 7440-38-2
1.0 05/30/02 20:53 DJR 7440-39-3
1.0 05/30/02 20:53 DJR 7440-43-9
1.0 05/30/02 20:53 DJR 7440-47-3
1.0 05/30/02 20:53 DJR 7439-92·1
1.0 05/30/02 20:53 DJR 7439-96-5
1.0 05/30/02 20:53 OJR 7782-49·2
1.0 05/30/02 20:53 DJR 7440-22·4
05/30/02
1. 0 06/03/02 LBG 7439-97-6
1. 0 05/24/02
1.0 05/24/02
1.0 05/24/02
CBJ 16887-00·6
CBJ
CBJ
1. 0 06/05/02 HEH
1.0 06/02/02 14:00 KTV 71-43·2
1.0 06/02/02 14:00 KTV 108-86·1
1.0 06/02/02 14:00 KTV 74-97-5
1.0 06/02/02 14:00 KTV 75-27-4
1.0 06/02/02 14:00 KTV 75-25·2
1.0 06/02/02 14:00 KTV 74-83-9
1.0 06/02/02 14:00 KTV 104-51-8
1.0 06/02/02 14:00 KTV 135-98-8
1.0 06/02/02 14:00 KTV 98-06-6
1.0 06/02/02 14:00 KTV 56-23-5
1.0 06/02/02 14:00 KTV 108-90·7
1.0 06/02/02 14:00 KTV 75-00-3
1.0 06/02/02 14:00 KTV 67-66-3
1
Page: 82
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Laboratory Certification IDs
NC Wastewater 12 REPORT OF LABORATORY ANALYSIS Laboratory Certification IDs I
LA Wastewater 04034
NC Drinking Water 37706
SC 99006
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc. VA Drinking Water 213
FL NELAP E87627 I
I
ace Analytical™
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone] www.pacelabs.com
Lab Sample No: 9222~5226
Client Sample ID: HW-38
Lab Project Number: 9233015
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-039
Matrix: Water
Date Collected: 05/23/02 09:10
Date Received: 05/24/02 13:55
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Parameters Results Units
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
Ug/l
ug/l
ug/l
Reoort Limit _QE_ Analyzed By ~C~A~S~N~o~. _ 9!!tl_ RegLmt
74-87-3
I
Chl oromethane
2-Chlorotoluene
4-Chl orotol uene
1,2-Dibromo-3-chioropropane
Di bromochl or:oni'ethiine
l.2-Dibr9moe_thane (EDB)
Di bromorileth'ane
_,. "' I
1,2-Dichlorobenzene
I /1,3'.[)ichlorobenzene
_/~~~· ·:°i.4-Dichlorobenzene
/a}:-1· Dichlorodifluoromethane
·• 1.1-Dichloroethane
1.2-Dichloroethane
1,1-Dichloroethene
I
I
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I
I
I
I
I
I
I.
I
ci s · 1, 2 -Di chl oroethene
trans-1,2-0ichloroethene
1.2-Dichloropropane
1,3-Dichloropropane
2.2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1.3-Dichloropropene
Diisopropyl ether
Ethyl benzene
Hexachloro-1,3-butadiene
Isopropylbenzene (Cumene)
p-Isopropyltoluene
Methylene chloride
Methyl-tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1.2-Tetrachloroethane
1,1,2.2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
I, 1, 1 · Trichloroethane
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
. ug/l
Ug/l
Ug/l
ug/l
ug/l
ug/l
ug/l
2.0 1.0 06/02/02 14:00 KTV
0.50 1.0 06/02/02 14:00 KTV 95-49-8
0.50 1.0 06/02/02 14:00 KTV 106-43-4
2.0 1.0 06/02/02 14:00 KTV 96-12-8
0.50 1.0 06/02/02 14:00 KTV 124-48-1
0.50 1.0 06/02/02 14:00 KTV 106-93-4
0.50 1.0 06/02/02 14:00 KTV 74-95-3
1.0 1.0 06/02/02 14:00 KTV 95-50-1
1.0 1.0 06/02/02 14:00 KTV 541-73-1
1.0 1.0 06/02/02 14:00 KTV 106-46-7
0.50 1.0 06/02/02 14:00 KTV 75-71-8
0.50 1.0 06/02/02 14:00 KTV 75-34-3
0.50 1.0 06/02/02 14:00 KTV 107-06-2
0.50 1.0 06/02/02 14:00 KTV 75.35.4
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
2.0
0.50
1.0
2.0
0.50
2. 0
0.50
0.50
0.50
0.50
0.50
0.50
2.0
2.0
0.50
1.0 06/02/02 14:00 KTV 156-59-2
1.0 06/02/02 14:00 KTV 156-60-5
1.0 06102102·14,oo KTV 78-87-5
1.0 06/02/02 14:00 KTV 142-28-9
1.0 06/02/02 14:00 KTV 594·20-7
1.0 06/02/02 14:00 KTV 563-58-6
1.0 06/02/02 14:00 KTV 10061-01-5
1.0 06/02/02 14:00 KTV 10061-02-6
1.0 06/02/02 14:00 KTV 108-20-3
1.0 06/02/02 14:00 KTV 100-41-4
1.0 06/02/02 14:00 KTV 87-68-3
1.0 06/02/02 14:00 KTV 98-82-8
1.0 06/02/02 14:00 KTV 99-87-6
1.0 06/02/02 14:00 KTV 75-09-2
1.0 06/02/02 14:00 KTV 1634-04-4
1.0 06/02/02 14:00 KTV 91-20-3
1.0 06/02/02 14:00 KTV 103-65-1
1.0 06/02/02 14:00 KTV 100-42-5
1.0 06/02/02 14:00 KTV 630-20-6
1.0 06/02/02 14:00 KTV 79-34-5
1.0 06/02/02 14:00 KTV 127-18-4
1.0 06/02/02 14:00 KTV 108-88-3
1.0 06/02/02 14:00 KTV 87-61-6
1.0 06/02/02 14:00 KTV 120-82-1
1.0 06/02/02 14:00 KTV 71-55-6
Page: 83
REPORT OF LABORATORY ANALYSIS Laboratory Certification IDs
LA Wastewater 04034 This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,~ Hta~
§?~,
I1n~ac11
VA Drinking Water 213
FL NELAP E87627
ace Analytical™
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
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www.pacelabs.com
Lab Sample No: 922285226
Client Sample ID: MW-38
Parameters
1.1,2-Trichloroethane
Trichloroethene
Tri chl orofl uorometti'an~·
1, 2. 3-Tri chl oropropa'ne
1. 2. 4 · Tri methyH,;;n,ene
1,3,5-Trimethylbenzene
• ,· -1., Vinyl .. chloride
m&p'XYl;~e .. ,
,....,O~X,Ylene
,/_;-i-Chloro-3-fluorobenzene (S)
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
Results Units
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
101 t
Lab Project Number: 9233015
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-039
Matrix: Water
Date Collected: 05/23/02 09:10
Date Received: 05/24/02 13:55
Re~rt Limit ~ Analized Bi CAS No. ~ RegLmt
0.50 1.0 06/02/02 14:00 KTV 79-00-5
0.50 1.0 06/02/02 14:00 KTV 79-01-6
0.50 1.0 06/02/02 14:00 KTV 75-69-4
0.50 1.0 06/02/02 14:00 KTV 96-18-4
0.50 1.0 06/02/02 14:00 KTV 95-63-6
0.50 1.0 06/02/02 14:00 KTV 108-67-8
0.50 1.0 06/02/02 14:00 KTV 75-01-4
0.50 1.0 06/02/02 14:00 KTV
0.50 1.0 06/02/02 14:00 KTV 95-47-6
1.0 06/02/02 14:00 KTV 625-98-9
Page: 84
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REPORT OF LABORATORY ANALYSIS Laboratory Certification IDs I
LA Wastewater 04034 This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
1• •CCD-'I
_.-x7Z'¾1r:::·• ... I1neac11
VA Drinking Water 213
FL NELAP E87627 I
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ace Analytical™
www.pacelabs.com
Lab Sample No: 922285234
Client Sample JD: MW-11 DISSOLVE□''
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Lab Project Number: 9233015
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-040
Matrix: Water
Date Collected: 05/23/02 11:30
Date Received: 05/24/02 13:55
Parameters Results Units Report Limit JlL_ Analyzed By CAS No. Qi!tl_ RegLmt Metals
Dissolved Metals. Trace ICP
Iron, Dissolved /
Date Digested
,, ',
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
Prep/Method: EPA 3010 / EPA 6010
0.34 mg/1 0.050 1.0 06/04/02
05/29/02
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc. n~ ttdelaa\
DJR 7439-89-6
Page: 85
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
ace Analytical™
Lab Sample No:
www.pacelabs.com
922285242 , . ',. Client Sample ID: MW-llI DISSOLVED
/ .~
. , Pace Analytical Services, Inc .
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Lab Project Number: 9233015
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015·041
Matrix: Water
Date Collected: 05/23/02 10:40
Date Received: 05/24/02 13:55
Parameters Results Units Report Limit _Qf_ _ _,Aocn,sa,.;ly,..zce,ed,_-"B,_y CAS No. Q!!tl_ RegLmt Metals I I •.• ·.• Dissolved Metals,'Trace ICP .-~. ' Iron, Dissolved _/·
Date Digested ...
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
Prep/Method: EPA 3010 / EPA 6010
0.68 mg/1 0.050 1. 0 06/04/02
05/29/02
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
~?;~~ AK"~+,..,
Iin ac11
DJR 7439·89·6
Page: B6
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
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ace Analytical™
www.pacelabs.com
Lab Sample No: 922285259 •'
Client Sample ID: MW-121 DISSOLVE~ ~/ .·
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Lab Project Number: 9233015
Phone: [phone]
Fax: [phone]
Client Project.ID: NCSU Lot 86/2246
Project Sample Number: 9233015-042
Matrix: Water
Date Collected: 05/23/02 09:40
Date Received: 05/24/02 13:55
Parameters Results Units Report Limit JlL Analyzed By CAS No. ili!tl_ RegLmt Metals
Dissolved Metals, Trace ICP
Iron, Dissolved ,.,.•
Date Digested .
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
Prep/Method: EPA 3010 / EPA 6010
0.17 mg/1 0.050 I. 0 06/04/02
05/29/02 ·
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
i• Hto~
.,,~ .. ?1nelac\t
DJR 7439-89-6
Page: 87
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
ace Analytical™
www.pacelabs.com
Lab Sample No: 922285267 ;
Client Sample IO: MW-16I DISSOLVED
Parameters
Metals Results
Lab Project Number: 9233015
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Client Project IO: NCSU Lot 86/2246
Project Sample Number: 9233015-043
Matrix: Water
Date Collected: 05/23/02 08:30
Date Received: 05/24/02 13:55
Units Report Limit ....!lf..._ Analyzed By CAS No. !l!!tl_ RegLmt
Dissolved Metals. Trace ICP '·,. Prep/Method: EPA 3010 / EPA 6010
Iron, Dissolved . ,-!,.,.,> 1.3 mg/1 0.050
Date Digested •. ·_.
Date: 06/29/02
1. 0 06/04/02
05/29/02
OJR 7439-89-6
Page: 88
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Laboratory Certification IDs
NC Wastewater 12 REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Laboratory Certification IDs I
LA Wastewater 04034
NC Drinking Water 37706
SC 99006 ,~ .e,o~ ~ ldelaat
VA Drinking Water 213
FL NELAP E87627 I
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ace Analytical™
www.pacelabs.com
Lab Sample No: 922285275
Client Sample ID: MW-171 DISSOLVED .. /'
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Lab Project Number: 9233015
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-044
Matrix: Water
Date Collected: 05/23/02 10:10
Date Received: 05/24/02 13:55
Parameters Results Units Report Limit _QE__ Analyzed By CAS No. Q!!tl_ RegLmt Metals
Dissolved Metals. Trace ICP
Iron, Dissolved
Date Digested /
Oate: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
Prep/Method: EPA 3010 / EPA 6010
ND mg/1 0.050 1. 0 06/04/02
05/29/02
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
l~~~ ff/O~C\t
DJR 7439-89·6
Page: B9
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
ace Analytical™
www.pacelabs.com
Lab Sample No: 922285291
Client Sample ID: MW-38 DISSOL~~Di .. ,
Parameters Results Metals
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Lab Project Number: 9233015
Phone. [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-045
Matrix: Water
Date Collected: 05/23/02 09:10
Date Received: 05/24/02 13:55
Units Report Limit ...QL Analyzed By CAS No. 9!!tl._ RegLmt
Dissolved Metals. Trace ICP Prep/Method: EPA 3010 / EPA 6010
Iron, Dissolved
Date Digested
Date: 06/29/02
,. '
/ ND mg/1 0.050 1. 0 06/04/02
05/29/02
DJR 7439-89-6
Page: 90
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Laboratory Certification IDs
NC Wastewater 12 REPORT OF LABORATORY ANALYSIS Laboratory Certification IDs I
LA Wastewater 04034 NC Drinking Water 37706
SC 99006
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
<)~ .... • 71_,S {,c,
ffi0t::k1C\1
VA Drinking Water 213
FL NELAP E87627 I
I
ace Analytical™
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone] .www.pacelabs.com Lab Project Number: 9233015
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Lab Sample No: 922293188
Client Sample ID: MW-2
Parameters
Metals
Metals by Trace ICP
Arsenic
Barium
Cadmium
Chromium ,, ·
Lead/,.,..,,.,
Manganese ,-, . r
I ,r:s;;1 enium
/;"Silver
,.. 'J , ,., Date Digested
,,,l
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Mercury, CVAAS, in Water
Mercury
Wet Chemistry
Ion Chromatography
Chloride
Nitrate
Sulfate
Alkalinity, Total
Alkalinity, Total
GC Volatiles
GC VOCs in Water
Benzene
Bromobenzene
Bromochlorornethane
BroJOOdichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butyl benzene
tert-Butylbenzene
Carbon tetrachloride
Chl orobenzene
Chloroethane
Chloroform
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
/
"/
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-046
Matrix: Water
Date Collected: 05/30/02 10:00
Date Received: 05/30/02 16:15
Results Units Report Limit ...QL Analyzed By CAS No, lli!tl._ RegLmt
Prep/Method: EPA 3010 / EPA 6010
0,0090
1.3
0,0019
0,011
0,013
50,
0.035
0,0062
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
Method: EPA 7470
0.060 mg/1
Method: EPA 300.0
0.0050
0.0050
0.0010
0,0020
0.0050
0.0050
0,0050
0.0020
0.0020
1.0 06/11/02 18:43 DJR 7440-38-2
1.0 06/11/02 18:43 DJR 7440-39-3
1,0 06/11/02 18:43 DJR 7440-43-9
1.0 06/11/02 18:43 DJR 7440-47-3
1.0 06/11/02 18:43 DJR 7439-92-1
1.0 06/11/02 18:43 DJR 7439-96·5
1,0 06/11/02 18:43 DJR 7782-49-2
1.0 06/11/02 18:43 DJR 7440-22·4
06/04/02
10.0 06/03/02 LBG 7439-97-6
210 mg/1
6.6 mg/1
5.0
0.10
1.0
5,0 05/31/02
1. 0 05/31/02
1. 0 05/31/02
COE 16887-00-6
COE
2,8 mg/1 COE
Method: EPA310.l
65. mg/1 1.0 1. 0 06/05/02 HEH
Method: SM 6230D
5300 ug/1 1000 2000 06/04/02 01:54 KTV
ND ug/1 1000 2000 06/04/02 01:54 KTV
ND ug/1 1000 2000 06/04/02 01:54 KTV
ND ug/1 1000 2000 06/04/02 01:54 KTV
ND ug/1 1000 2000 06/04/02 01:54 KTV
ND ug/1 1000 2000 06/04/02 01:54 KTV
ND ug/1 2000 2000 06/04/02 01:54 KTV
ND ug/1 1000 2000 06/04/02 01:54 KTV
ND ug/1 1000 2000 06/04/02 01:54 KTV
2900 ug/1 1000 2000 06/04/02 01:54 KTV
ND ug/1 1000 2000 06/04/02 01:54 KTV
ND ug/1 1000 2000 06/04/02 01:54 KTV
38000 ug/1 1000 2000 06/04/02 01:54 KTV
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,,. •Cco4 ,-?~-
?iOt:1aCit
71-43-2
108-86-1
74.97.5
75-27-4
75-25·2
74-83-9
104-51-8
135-98-8
98-06-6
56-23-5
108-90-7
75-00·3
67-66-3
Page: 91
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
ace Analytical™
www.pacelabs.com
Lab Sample No: 922293188
Client Sample ID: MW-2-
Parameters
Chloromethane
2-Chlorotoluene
4-Chloroto1uene
1,2-Dibromo-3-chloropropane
Oibromochlorom'~tha~e
1.2-Dibrom<i~th~-ne (EDB)
Di brorno~thane
1, 2;:0i chl orobenzene
✓,,·(3 :Di chl orobenzene
/.<_".;..· '1.4-Dichlorobenzene
_/ ,,r-· Di chlorodi fl uoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1.1-Dichloroethene
cis-1.2-Dichloroethene
trans•l,2-Dichloroethene
1.2-Dichloropropane
1.3-Dichloropropane
2.2-Dichloropropane
1.l·Dichloropropene
cis-1,3-Dichloropropene
trans-1.3-Dichloropropene
Diisopropyl ether
Ethyl benzene
Hexachloro-1,3-butadiene
Isopropylbenzene (Cumene)
p-Isopropyltoluene
Methylene chloride
Methyl-tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1.1.1,2-Tetrachloroethane
1.1.2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2.3-Trichlorobenzene
1,2,4-Trichlorobenzene
1, I. I· Tri chl or_oethane
Date: 06/29/02
I' ..
Results
ND
ND
ND
ND
ND
67000
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
18000
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
6100
ND
ND
ND
Units
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
Lab Project Number: 9233015
Pace Analytical Services. Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-046
Matrix: Water
Date Collected: 05/30/02 10:00
Date Received: 05/30/02 16:15
Report Limit J!E..._ Analyzed By CAS No.
4000 2000 06/04/02 01:54 KTV 74-87-3
1000
1000
4000
1000
1000
1000
2000
2000
2000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
4000
1000
2000
4000
1000
4000
1000
1000
1000
1000
1000
1000
4000
4000
1000
2000 06/04/02 01:54 KTV 95-49-B
2000 06/04/02 01:54 KTV 106-43-4
2000 06/04/02 01:54 KTV 96-12·8
2000 06/04/02 01:54 KTV 124-48·1
2000 06/04/02 01:54 KTV 106-93-4
2000 06/04/02 01:54 KTV 74-95·3
2000 06/04/02 01:54 KTV 95-50-1
2000 06/04/02 01:54 KTV 541-73-1
2000 06/04/02 01:54 KTV 106-46·7
2000 06/04/02 01:54 KTV 75-71·8
2000 06/04/02 01:54 KTV 75-34-3
2000 06/04/02 01:54 KTV 107·06·2
2000 06/04/02 01:54 KTV 75-35·4
2000 06/04/02 01:54 KTV 156-59•2
2000 06/04/02 01:54 KTV 156-60·5
2000 06/04/02 01:54 KTV 78-87•5
2000 06/04/02 01:54 KTV 142·28·9
2000 06/04/02 01:54 KTV 594·20·7
2000 06/04/02 01:54 KTV 563-58·6
2000 06/04/02 01:54 KTV 10061-01·5
2000 06/04/02 01:54 KTV 10061-02·6
2000 06/04/02 01:54 KTV 108-20·3
2000 06/04/02 01:54 KTV 100-41·4
2000 06/04/02 01:54 KTV 87-68-3
2000 06/04/02 01:54 KTV 98-82·8
2000 06/04/02 01:54 KTV 99-87·6
2000 06/04/02 01:54 KTV 75-09-2
2000 06/04/02 01:54 KTV 1634·04·4
2000 06/04/02 01:54 KTV 91-20-3
2000 06/04/02 01:54 KTV 103-65·1
2000 06/04/02 01:54 KTV 100-42-5
2000 06/04/02 01:54 KTV 630-20·6
2000 06/04/02 01:54 KTV 79-34-5
2000 06/04/02 01:54 KTV 127-18·4
2000 06/04/02 01:54 KTV 108-88·3
2000 06/04/02 01:54 KTV 87-61-6
2000 -06/04/02 01:54 KTV 120-82-1
2000 06/04/02 01:54 KTV 71-55-6
ll!w_ RegLmt
Page: 92
Laboratory Certification IDs
NC Wastewater 12 REPORT OF LABORATORY ANALYSIS Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
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NC Drinking Water 37706
SC 99006
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
1M •cca., ~ ~nelaa\
FL NELAP EB7627 I
ace Analytical™
www.pacelabs.com
Lab Sample No: 922293188
Client Sample ID: MW-2
Pace Analytical Services, Inc.
9800 Kincey Avenue. Suite 100
Huntersville. NC 28078
Lab Project Number: 9233015
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-046
Matrix: Water
Date Collected: 05/30/02 10:00
Date Received: 05/30/02 16:15
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Parameters Results Units Re~ort Limit _I[_ Anal~zed B~ CAS No. 9!@L RegLmt
I
1.1.2-Trichloroethane
Trichloroethene
Tri chlorofl uoromethane
1.2.3-Trichlorg~ropane
1.2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl,chlo~ide
m&p'Xylene ,r ,,,.
I /O;Xylene
,/,, ·i-Chloro-3-fluorobenzene (S)
,,',"' .-
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Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
ND ug/l 1000 2000 06/04/02 01:54 KTV
ND ug/l 1000 2000 06/04/02 01:54 KTV
ND ug/l 1000 2000 06/04/02 01:54 KTV
ND ug/l 1000 2000 06/04/02 01:54 KTV
ND ug/l 1000 2000 06/04/02 01:54 KTV
ND ug/l 1000 2000 06/04/02 01:54 KTV
ND ug/l 1000 2000 06/04/02 01:54 KTV
ND ug/l 1000 2000 06/04/02 01:54 KTV
ND ug/l 1000 2000 06/04/02 01:54 KTV
102 t 1.0 06/04/02 01:54 KTV
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
~ lnelaa1
79-00-5
79-01-6
75-69-4
96-18-4
95-63-6
108-67-8
75-01-4
95-47-6
625-98-9
Page: 93
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
ace Analytical™
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
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www.pacelabs.com
Lab Project Number: 9233015
Lab Sample No: 922293204
Client Sample ID: MW-3
Parameters
Metals
Metals by Trace !CP
Arsenic
Barium
Cadmium
Chromium
Lead --,,,.'
Mangane'Se L ,·
/1~.~e1enium
/'/Silver
;<;( .,. ' Date Digested
Mercury, CVAAS. in Water
Mercury
Wet Chemistry
Ion Chromatography
Chloride
Nitrate
Sulfate
Alkalinity. Total
Alkalinity. Total
GC Volatiles
GC voes in Water
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butyl benzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-047
Matrix: Water
Date Collected: 05/30/02 10:20
Oate Received: 05/30/02 16:15
Results Units Report Limit J1L Analyzed By CAS No.
Prep/Method: EPA 3010 / EPA 6010
0.013 mg/1
0.57 mg/1
ND mg/1
o. 0024 mg/l
0.0091 mg/l
13.
0.010
ND
mg/1
mg/l
mg/l
Method: EPA 7470
ND mg/l
Method: EPA 300.0
7.8 mg/l
ND mg/l
2.2 mg/l
Method: EPA 310.1
70. mg/l
Method: SH 6230D
8500 ug/l
ND ug/l
ND ug/l
ND ug/l
ND ug/l
ND ug/1
ND ug/1
ND ug/1
ND ug/l
2800 ug/l
ND ug/1
ND ug/1
40000 ug/l
0.0050
0.0050
0.0010
0.0020
0.0050
0.0050
0.0050
0.0020
0.00020
1.0
0.10
1.0
1.0
1000
1000
1000
1000
1000
1000
2000
1000
1000
1000
1000
1000
1000
1.0 06/11/02 18:52 DJR 7440-38-2
1.0 06/11/02 18:52 OJR 7440-39-3
1.0 06/11/02 18:52 DJR 7440-43-9
1.0 06/11/02 18:52 DJR 7440-47-3
1.0 06/11/02 18:52 DJR 7439-92-1
1.0 06/11/02 18:52 DJR 7439-96-5
1.0 06/11/02 18:52 DJR 7782-49-2
1.0 06/11/02 18:52 DJR 7440-22-4
06/04/02
1. 0 06/03/02 LBG 7439-97-6
1.0 05/31/02
1.0 05/31/02
1.0 05/31/02
CDE 16887-00-6
CDE
CDE
1.0 06/05/02 HEH
2000 06/04/02 02:41 KTV 71-43-2
2000 06/04/02 02:41 KTV 108-86-1
2000 06/04/02 02:41 KTV 74-97-5
2000 06/04/02 02:41 KTV 75-27-4
2000 06/04/02 02:41 KTV 75-25-2
2000 06/04/02 02:41 KTV 74-83-9
2000 06/04/02 02:41 KTV 104-51-8
2000 06/04/02 02:41 KTV 135-98-8
2000 06/04/02 02:41 KTV 98-06-6
2000 06/04/02 02:41 KTV 56-23-5
2000 06/04/02 02:41 KTV 108-90-7
2000 06/04/02 02:41 KTV 75-00-3
2000 06/04/02 02:41 KTV 67-66-3
Page: 94
I
REPORT OF LABORATORY ANALYSIS Laboratory Certification IDs I
LA Wastewater 04034 This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
~ lneiaci
VA Drinking Water 213
FL NELAP E87627 I
I
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I
ace Analytical™
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersvi/fe, NC 28078
www.pacelabs.com Phone: [phone]
Fax: [phone]
Lab Sample No: 922293204
Client Sample ID: MW-3
Parameters
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromet~ane
4 1.2-Dibromoethane (EDBJ
Dibromollleth~ne
1. 2:q'i chl orobenzene
,,..1. 3: Di chl orobenzene
l,..,::::::··i .4 -Di ch l orobenzene
.!"' Dichlorodifluoromethane ( .-
" 1.1-0ichloroethane
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1,2-0ichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1.2-Dichloroethene
1.2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1.1-0ichloropropene
cis-1,3-0ichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethyl benzene
Hexachloro-1,3-butadiene
lsopropylbenzene (Cumene)
p-lsopropyltoluene
Methylene chloride
Methyl-tert-butyl ether
Naphthalene
n -Propyl benzene
Styrene
1.1,1.2-Tetrachloroethane
1.1.2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1.1-Trichloroethane
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
Results
NO
ND
NO
ND
ND
2200
ND
NO
ND
NO
NO
NO
NO
ND
ND
NO
6200
NO
ND
NO
NO
NO
NO
ND
ND
ND
NO
9200
ND
ND
ND
ND
NO
NO
NO
2700
NO
NO
NO
Units
ug/l
ug/1
ug/l
ug/l
ug/l
ug/l
ug/1
ug/1
ug/l
u9/l
ug/l
ug/l
ug/1
ug/l
ug/l
ug/l
u9/l
ug/1
ug/1
ug/l
ug/l
ug/l
ug/l
ug/l
Ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/1
ug/1
ug/l
ug/l
ug/l
ug/1
Lab Project Number: 9233015
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-047
Matrix: Water
Date Collected: 05/30/02 10:20
Date Received: 05/30/02 16:15
Report Limit _J[__ Analyzed By CAS No.
4000 2000 06/04/02 02:41 KTV 74-87-3
1000
1000
4000
1000
1000
1000
2000
2000
2000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
iooo
4000
1000
2000
4000
1000
4000
1000
1000
1000
1000
1000
1000
4000
4000
1000
2000 06/04/02 02:41 KTV 95-49-8
2000 06/04/02 02:41 KTV 106-43-4
2000 06/04/02 02:41 KTV 96-12-8
2000 06/04/02 02:41 KTV 124-48-1
2000 06/04/02 02:41 KTV 106-93-4
2000 06/04/02 02:41 KTV 74-95-3
2000 06/04/02 02:41 KTV 95-50-1
2000 06/04/02 02:41 KTV 541-73-1
2000 06/04/02 02:41 KTV 106-46-7
2000 06/04/02 02:41 KTV 75-71-8
2000 06/04/02 02:41 KTV 75-34-3
2000 06/04/02 02:41 KTV 107-06-2
2000 06/04/02 02:41 KTV 75-35-4
2000 06/04/02 02:41 KTV 156-59-2
2000 06/04/02 02:41 KTV 156-60-5
2000 06/04/02 02:41 KTV 78-87-5
2000 06/04/02 02:41 KTV 142-28-9
2000 06/04/02 02:41 KTV 594-20-7
2000 06/04/02 02:41 KTV 563-58-6
2000 06/04/02 02:41 KTV 10061-01-5
2000 06/04/02 02:41 KTV 10061-02-6
2000 06/04/02 02:41 KTV 108-20·3
2000 06/04/02 02:41 KTV 100-41-4
2000 06/04/02 02:41 KTV 87-68-3
2000 06/04/02 02:41 KTV 98-82·8
2000 06/04/02 02:41 KTV 99-87-6
2000 06/04/02 02:41 KTV 75-09-2
2000 06/04/02 02:41 KTV 1634-04-4
2000 06/04/02 02:41 KTV 91-20-3
2000 06/04/02 02:41 KTV 103-65-1
2000 06/04/02 02:41 KTV 100-42-5
2000 06/04/02 02:41 KTV 630-20-6
2000 06/04/02 02:41 KTV 79-34-5
2000 06/04/02 02:41 KTV 127-18·4
2000 06/04/02 02:41 KTV 108-88-3
2000 06/04/02 02:41 KTV 87-61-6
2000 06/04/02 02:41 KTV 120-82-1
2000 06/04/02 02:41 KTV 71-55-6
!l!!tl._ RegLmt
Page: 95
REPORT OF LABORATORY ANALYSIS Laboratory Certification IDs
LA Wastewater 04034 This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
~ lnelaa1
VA Drinking Water 213
FL NELAP E87627
.. f•' •
ace Analyticar·
www.pacelabs.com
Lab Sample No: 922293204 ' Client Sample ID: MW-3
Parameters Results Units
1.1.2-Trichloroethane .~,--~;;r ND ug/l
Trichloroethene 3400 ug/l
Trichlorofluoromethane ND ug/1
1.2 .3· Trichloropr'bpa~~ ND ug/1
1,2.4-TrimethyibJhzene ... J ND ug/1
1. 3. 5-TriAe.t_hyl benzene ND ug/1
Vinyl chl6ride ND ug/1 ,•,. y
m&p-Xylene ND ug/1 .... ,~ /~_,Xylene ND ug/1
/,"'./1-Chloro-3-fluorobenzene (S) 99 X
Date: 06/29/02
Pace Analytical Services, Inc.
9800 Kincey Avenue. Suite 100
Huntersville. NC 28078
Lab Project Number: 9233015
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015·047 Date Collected: 05/30/02 10:20
Matrix: Water Date Received: 05/30/02 16:15
ReQQrt Limit ..QL Anal~zed 8~ CAS No. ~ RegLmt
1000 2000 06/04/02 02:41 KTV 79-00·5
1000 2000 06/04/02 02:41 KTV 79-01-6
1000 2000 06/04/02 02:41 KTV 75-69-4
1000 2000 06/04/02 02:41 KTV 96-18·4
1000 2000 06/04/02 02:41 KTV 95-63·6
1000 2000 06/04/02 02:41 KTV 108-67-8
1000 2000 06/04/02 02:41 KTV 75-01•4
1000 2000 06/04/02 02:41 KTV
1000 2000 06/04/02 02:41 KTV 95-47-6
1.0 06/04/02 02:41 KTV 625-98-9
Page: 96
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Laboratory Certification IDs
NC Wastewater · 12 REPORT OF LABORATORY ANALYSIS Laboratory Certification IDs I
LA Wastewater 04034 NC Drinking Water 37706
SC 990D6
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
.-~e1· ·~'••,,
ff/0 aC\l
VA Drinking Water 213
FL NELAP E87627 I
I ,,
I
I ace Analytical™
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone] www.pacelabs.com •
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Lab Sample No: 922293220
Client Sample ID: MW-6
Parameters
Metals
Metals by Trace ICP
Arsenic
Barium
Cadmium
· • Chromium Lead . ·
Mangane'Se . .. ,~selenium
I / --:,,,.. Sn ver
,. ~.,:, Oa.te Digested ,,.
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Mercury. CVAAS. in Water
Mercury
Wet Chemistry
Ion Chromatography
Chloride
Nitrate
Sulfate
Alkalinity. Total
Alkalinity. Total
GC Volatiles
GC voes in Water
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butyl benzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
Lab Project Number: 9233015
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-048
Matrix: Water
Date Collected: 05/29/02 17:15
Date Received: 05/30/02 16:15·
Results Units Report Limit _QL Analyzed By CAS No. lli!tl._ RegLmt
Prep/Method: EPA 3010 / EPA 6010
ND
0.52
ND
0.055
0.0079
7 .9
0.0056
ND
mg/l
mg/l
mg/l
mg/l
mg/l
mg/l
mg/l
mg/l
Method: EPA 7470
0.00054 mg/l
Method: EPA 300.0
48. mg/l
0.20 mg/l
1.2 mg/l
Method: EPA 310.1
20. mg/l
Method: SM 6230D
770 ug/l
ND u9/l
ND ug/l
ND ug/l
ND ug/l
ND ug/l
ND ug/l
ND ug/l
ND ug/l
1600 ug/l
ND ug/l
ND ug/l
17000 ug/l
0.0050
0.0050
0.0010
0.0020
0.0050
0.0050
0.0050
0.0020
0.00020
1.0
0.10
1.0
1.0
500
500
500
500
500
500
1000
500
500
500
500
500
500
1.0 06/11/02 18:20 DJR
1.0 06/11/02 18:20 DJR
1.0 06/11/02 18:20 DJR
1.0 06/11/02 18:20 DJR
1.0 06/11/02 18:20 DJR
1.0 06/11/02 18:20 DJR
1.0 06/11/02 18:20 DJR
1.0 06/11/02 18:20 OJR
06/04/02
1. 0 06/03/02 LBG
1. 0 05/31/02 CDE
1. 0 05/31/02 CDE
1.0 05/31/02 CDE
1. 0 06/05/02 HEH
1000 06/03/02 22:00 KTV
1000 06/03/02 22:00 KTV
1000 06/03/02 22:00 KTV
1000 06/03/02 22:00 KTV
1000 06/03/02 22:00 KTV
1000 06/03/02 22:00 KTV
1000 06/03/02 22:00 KTV
1000 06/03/02 22:00 KTV
1000 06/03/02 22:00 KTV
1000 06/03/02 22:00 KTV
1000 06/03/02 22:00 KTV
1000 06/03/02 22:00 KTV
1000 06/03/02 22:00 KTV
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
'" ~Cto4 ~~ ?1□elac\\
7440-38-2
7440-39-3
7440-43-9
7440-47-3
7439-92-1
7439-96-5
7782-49-2
7440-22-4
7439-97-6
16887-00-6
71-43-2
108-86-1
74.97.5
75-27-4
75-25-2
74-83-9
104-51-8
135-98-8
98-06-6
56-23-5
108-90-7
75-00-3
67-66-3
Page: 97
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
ace Analytical™
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
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www.pacelabs.com
Lab Sample No: 922293220
Client Sample ID: MW-6
Parameters
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1. 2-Di bromo · 3 · chl or~~",opane j ••• Dibromochloromethane
1.2-Dibromo~thane (EDB)
Di bromomethane
I. 2. p_1 chlorobenzene
/:;: 3·:o; chl orobenzene
,,;_' / 1.4-Dichlorobenzene
,_ .. ;;.---~~ · Di chl orodifl uoromethane
1.1-Dichloroethane
1.2-Dichloroethane
l.l·Dichloroethene
cis-1.2-Dichloroethene
trans-1.2-Dichloroethene
1.2-Dichloropropane
1,3-Dichloropropane
2.2-Dichloropropane
1.1-Dichloropropene
cis-1.3-Dichloropropene
.trans -1, 3-Di chl oropropene
Diisopropyl ether
Ethyl benzene
Hexachloro-1.3-butadiene
Isopropylbenzene (Cumene)
p-Isopropyltoluene
Methylene chloride
Methyl-tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1.1.1.2-Tetrachloroethane
1.1.2.2-Tetrachloroethane
Tetrachloroethene
Toluene
1.2.3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
Results
ND
ND
ND
ND
ND
1200
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2600
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Units
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/1
ug/1
ug/1
ug/l
ug/1
ug/l
ug/1
ug/1
ug/1
ug/l
ug/l
ug/1
ug/l
ug/l
ug/l
ug/1
ug/l
ug/1
ug/1
ug/1
ug/1
ug/1
ug/l
ug/l
ug/l
ug/l
ug/l
Lab Project Number: 9233015
Client Project IO: NCSU Lot 86/2246
Project Sample Number: 9233015-048
Matrix: Water
Date Collected: 05/29/02 17:15
Date Received: 05/30/02 16:15
Report Limit ....!2[__
2000 1000
Analyzed By
06/03/02 22:00 KTV
06/03/02 22:00 KTV
__,C""AS~N~o~. _ !l\!tl_ RegLmt
74-87-3
500 1000 95-49-8
500 1000 06/03/02 22:00 KTV 106-43-4
2000 1000 06/03/02 22:00 KTV 96-12-8
500 1000 06/03/02 22:00 KTV 124-48-1
500 1000 06/03/02 22:00 KTV 106-93-4
500 1000 06/03/02 22:00 KTV 74-95-3
1000 1000 06/03/02 22:00 KTV 95-50-1
1000 1000 06/03/02 22:00 KTV 541-73-1
1000 1000 06/03/02 22:00 KTV 106-46-7
500 1000 06/03/02 22:00 KTV 75-71-B
500 1000 06/03/02 22:00 KTV 75-34-3
500 1000 06/03/02 22:00 KTV 107-06-2
500 1000 06/03/02 22:00 KTV 75-35-4
500
500
500
500
500
500
500
500
500
500
2000
500
1000
2000
500
2000
500
500
500
500
500
500
2000
2000
500
1000 06/03/02 22:00 KTV 156-59-2
1000 06/03/02 22:00 KTV 156-60-5
1000 06/03/02 22:00 KTV 78-87-5
1000 06/03/02 22:00 KTV 142-28-9
1000 06/03/02 22:00 KTV 594-20-7-
1000 06/03/02 22:00 KTV 563-58-6
1000 06/03/02 22:00 KTV 10061-01·5
1000 06/03/02 22:00 KTV 10061-02·6
1000 06/03/02 22:00 KTV 108-20-3
1000 06/03/02 22:00 KTV 100-41-4
1000 06/03/02 22:00 KTV 87-68-3
1000 06/03/02 22:00 KTV 98-82·8
1000 06/03/02 22:00 KTV 99-87-6
1000 06/03/02 22:00 KTV 75-09-2
1000 06/03/02 22:00 KTV 1634-04-4
1000 06/03/02 22:00 KTV 91-20-3
1000 06/03/02 22:00 KTV 103·65-l
1000 06/03/02 22:00 KTV 100-42·5
1000 06/03/02 22:00 KTV 630-20-6
1000 06/03/02 22:00 KTV 79-34-5
1000 06/03/02 22:00 KTV 127-18-4
1000 06/03/02 22:00 KTV 108-88-3
1000 06/03/02 22:00 KTV 87-61·6
1000 06/03/02 22:00 KTV 120-82-1
1000 06/03/02 22:00 KTV 71-55-6
Page: 98
REPORT OF LABORATORY ANALYSIS Laboratory Certification IDs I
LA Wastewater 04034 This report shall not be reproduced. except in full,
without the written consent of Pace Analytical Services, Inc.
ff/~\
VA Drinking Water 213
FL NELAP E87627 I
ace Analytical™
www.pacelabs.com
Lab Sample No: 922293220
Client Sample ID: MW-6
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Lab Project Number: 9233015
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-048
Matrix: Water
Date Collected: 05/29/02 17:15
Date Received: 05/30/02 16:15
I
I
I
Parameters Results Units ReQQrt Limit _Qf_ Anal lZed Bl CAS No. lli@l.. RegLmt
I
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropfopari~
1. 2. 4 -Trimethyl_penzene
1.3.5-Trimethylbenzene
Vinyl,.chloride
m&p-Xylene
,o-Xyi ene I /.t·tchloro-3-fluorobenzene (SJ .,,c,,, ,., ... . . ',
I
I
I
I
I
I
I
I
I
I
I
I
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
ND ug/1 500 1000 06/03/02 22:00 KTV
630 ug/1 500 1000 06/03/02 22:00 KTV
ND ug/1 500 1000 06/03/02 22:00 KTV
ND ug/1 500 1000 06/03/02 22:00 KTV
ND ug/1 500 1000 06/03/02 22:00 KTV
ND ug/1 500 1000 06/03/02 22:00 KTV
ND ug/1 500 1000 06/03/02 22:00 KTV
ND ug/1 500 1000 06/03/02 22:00 KTV
ND ug/1 500 1000 06/03/02 22:00 KTV
103 X 1.0 06/03/02 22:00 KTV
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,~ ACCo~ il5~~ 11nelac11
79-00-5
79-01-6
75-69-4
96-18-4
95-63-6
108-67-8
75-01-4
95-47-6
625-98-9
Page: 99
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
ace Analytical™
www.pacelabs.com
Lab Sample No: 922293261
Client Sample ID: MW·8
,_P,,,ar_,,a~me~t~e~rs"------~~'"...,.) Results
Metals
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Lab Project Number: 9233015
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-049
Matrix: Water
Date Collected: 05/29/02 16:50
Date Received: 05/30/02 16:15
Uni ts Report Limit .JlL.. _ _,_,An,,,a.,l.,_yz.,e.,.d'---"-8y,_ CAS No.
Metals by Trace ICP
Arsenic
Prep/Method: EPA 3010 / EPA 6010
Barium
Cadmium
Chromium , -
Lead_,,.,(:.,.>
Mang"arieSe ' /
4 ,Jelenium
/.c·· Silver
ND mg/1 0.0050
0.023
ND
0.015
ND
0.082
ND
/,<.'..-,.' Date Digested (.!:-/
ND
mg/l
mg/l
mg/l
mg/l
mg/l
mg/l
mg/1
0.0050
0.0010
0. 0020
0.0050
0.0050
0.0050
0.0020
1.0 06/11/02 18:28 DJR 7440-38-2
1.0 06/11/02 18:28 DJR 7440·39·3
1.0 06/11/02 18:28 DJR 7440·43·9
1.0 06/11/02 18:28 DJR 7440-47•3
1.0 06/11/02 18:28 DJR 7439·92·1
1.0 06/11/02 18:28 DJR 7439-96·5
1.0 06/11/02 18:28 DJR 7782·49-2
1.0 06/11/02 18:28 DJR 7440·22·4
06/04/02
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Mercury, CVMS, in Water
Mercury
Wet Chemistry
Ion Chromatography
Chloride
Nitrate
Sulfate
Alkalinity, Total
Alkalinity. Total
GC Volatiles
GC voes in Water
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butyl benzene
sec-Butyl benzene
tert-Butylb~nzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
Method: EPA 7470
ND mg/l
Method: EPA 300.0
4.7 mg/l
0.64 mg/l
I.I mg/l
Method: EPA 310.1
12. mg/l
Method: SM 62300
ND ug/l
ND ug/l
ND ug/l
ND ug/l
ND ug/l
ND ug/l
ND
ND
ND
590
ND
ND
11000
ug/l
ug/l
ug/1
ug/l
ug/l
ug/l
ug/1
0.00020 1.0 06/03/02
1.0 1.0 05/31/02
0.10 1.0 05/31/02
1.0 1.0 05/31/02
1.0 1.0 06/05/02
250
250
250
250
250
250
500
250
250
250
250
250
250
500 06/03/02
500 06/03/02
500 06/03/02
500 06/03/02
500 06/03/02
500 06/03/02
500 06/03/02
500 06/03/02
500 06/03/02
500 06/03/02
500 06/03/02
500 06/03/02
500 06/03/02
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
LBG 7439-97•6
COE 16887-00-6
COE
COE
HEH
KTV 71·43·2
KTV 108-86·1
KTV 74.97.5
KTV 75-27•4
KTV 75-25·2
KTV 74·83·9
KTV 104·51·8
KTV 135•98·8
KTV 98-06-6
'KTV 56·23·5
KTV 108-90· 7
KTV 75-00·3
KTV 67·66·3
Page: 100
Laboratory Certification IDs I
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627 I
I
I
I
I
I
ace Analytical™
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone] www.pacelabs.com Lab Project Number: 9233015
I
Lab Sample No: 922293261
Client Sample ID: MW-8
Parameters
Chloromethane
2-Chl oroto 1 uene
4-Chlorotoluene
1.2-Dibromo-3-chloropropane
Dibromochloromethane
' 1.2-Dibromoethane (ED8)
Di bromofnettiane ,, ,'
1.2-Dichlorobenzene
/1 f, 3'~ Oi ch 1 orobenzene 1/2~,.Ji ,4-Di chlorobenzene
.... :f;.-/ Di chl orodi fl uoromethane
_...,. 1.1-Dichloroethane·
I 1.2-Dichloroethane
1,1-Dichloroethene
I
I
I
I
I
I
I
I
I
I
cis-1.2-Dichloroethene
trans-1,2-Dichloroethene
1,2-0ichloropropane
1.3-Dichloropropane
2,2-Dichloropropane
1.1-Dichloropropene
cis-1.3-0ichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethyl benzene
Hexachloro-1,3-butadiene
Isopropylbenzene (Cumene)
p-Isopropyltoluene
Methylene chloride
Methyl-tert-butyl ether
Naphtha 1 ene
n-Propylbenzene
Styrene
1.1.1.2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1.2,3-Trichlorobenzene
1,2.4-Trichlorobenzene
1,1,1-Trichloroethane
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
Results
ND
ND
ND
ND
ND
470
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Units
ug/l
ug/l
ug/l
ug/1
ug/l
ug/1
ug/l
ug/1
ug/l
ug/1
ug/l
ug/l
ug/l
ug/1
ug/l
ug/l
ug/l
ug/1
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/1
ug/l
ug/1
ug/l
ug/1
ug/l
ug/1
ug/l
ug/l
ug/l
ug/1
ug/l
ug/l
ug/l
ug/l
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-049
Matrix: Water
Date Collected: 05/29/02 16:50
Date Received: 05/30/02 16:15
Report Limit JlE_ -~An~a~l~yz~e~d~~By~ CAS No. lli!tl._ RegLmt
1000 500 06/03/02 KTV 74-87-3
250 500 06/03/02 KTV 95-49-8
250 500 06/03/02 KTV-106-43-4---------
1000 500 06/03/02 KTV 96-12-8
250 500 06/03/02 KTV 124-48-1
250 500 06/03/02 KTV 106-93-4
250 500 06/03/02 KTV 74-95-3
500 500 06/03/02 KTV 95-50-1
500 500 06/03/02 KTV 541-73-1
500 500 06/03/02 KTV 106-46-7
250 500 06/03/02 KTV 75-71-8
250 500 06/03/02 KTV 75-34-3
250 500 06/03/02 KTV 107-06-2
250 500 06/03/02 KTV 75-35-4
250 500 06/03/02 KTV 156-59-2
250 500 06/03/02 KTV 156-60-5
250 500 06/03/02 KTV 78-87-5
250 500 06/03/02 KTV 142-28-9
250 500 06/03/02 KTV 594-20-7
250 500 06/03/02 KTV· 563-58-6
250 500 06/03/02 KTV 10061-01-5
250 500 06/03/02 KTV 10061-02-6
250
250
1000
250
500
1000
250
1000
250
250
250
250
250
250
1000
1000
250
500 06/03/02
500 06/03/02
500 06/03/02
500 06/03/02
500 06/03/02
500 06/03/02
500 06/03/02
500 06/03/02
500 06/03/02
500 06/03/02
500 06/03/02
500 06/03/02
500 06/03/02
500 06/03/02
500 06/03/02
500 06/03/02
500 06/03/02
KTV 108-20-3
KTV 100-41-4
KTV 87-68-3
KTV 98-82-8
KTV 99-87-6
KTV 75-09·2
KTV 1634-04-4
KTV 91-20-3
KTV 103-65-1
KTV 100-42-5
KTV 630-20-6
KTV 79-34-5
KTV 127-18-4
KTV 108-88-3
KTV 87-61-6
KTV 120-82-1
KTV 71-55-6
Page: 101
REPORT OF LABORATORY ANALYSIS Laboratory Certification IDs
LA Wastewater 04034 This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,~ •H11~
.?'~~
ff10eldC\\
VA Drinking Water 213
FL NELAP E87627
ace Analytical™
www.pacelabs.com
Lab Sample No: 922293261
Client Sample ID: MW-8
Parameters Results Units
1.1.2-Trichloroethane , ND ug/1
Trichloroethene
' ND ug/1
Tri chlorofl uorometh;:lhe ,· ND ug/1
I. 2. 3-Tri chl oropr,opane ND ug/1
I. 2. 4-Trimet,hyl )'enzene ND ug/1
1.3,5-Trimethylbenzene ND ug/1
Vinyl chloride ND ug/1
m&p-Xyl;ne ND ug/1 ,,. ,•
ND ug/1
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Lab Project Number: 9233015
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-049 Date Co 11 ected: 05/29/02 16:50
Matrix: Water Date Received: 05/30/02 16:15
Regort Limit J!L Analyzed By CAS No. !l!!tl._ RegLmt
250 500 06/03/02 KTV 79-00-5
250 500 06/03/02 KTV 79-01-6
250 500 06/03/02 KTV 75-69-4
250 500 06/03/02 KTV 96-18-4
250 500 06/03/02 KTV 95-63-6
250 500 06/03/02 KTV 108-67-8
250 500 06/03/02 KTV 75-01-4
250 500 06/03/02 KTV
250 500 06/03/02 KTV 95-47-6 __.,,:~;Xylene
/~~>/1 -Chl oro-3 -fl uorobenzene (S) 104 t ... ,,:,/ I. 0 06/03/02 KTV 625-98-9
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
....... -
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,~ •eco~
.~, ·e, "ne~-c,, " . . a: ,,
Page: 102
Laboratory Certification IDs I
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627 I
I
I
I
I
I
ace Analytical™
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone] www.pacelabs.com
I
Lab Sample No: 922293279
Client Sample ID: MW-8 DUP
Parameters
Metals
Metals by Trace ICP
Arsenic
Barium
Cadmium
Chrorni um
Lead ., ... ,.
Manefcine'se .,,. •. ~
I / Selenium
,/·! .,j$; 1 ver . ,, .
.. ,;,.,....,.. Date Digested . ,.
I
I
I
I
I
I
I
I
I
I
I
I
Mercury, CVAAS, in Water
Mercury
Wet Chemistry
Ion Chromatography
Chloride
Nitrate
Sulfate
Al<alinity, Total
Alkalinity. Total
GC Volatiles
GC VOCs in Water
Benzene
Bromobenzene
Bromochlorornethane
Bromodichloromethane
Bromoform
Bromomethane
n• Butyl benzene
sec-Butyl benzene
tert·Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
Results Units
Lab Project Number: 9233015
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-050
Matrix: Water
Date Collected: 05/29/02 17:00
Date Received: 05/30/02 16:15
Report Limit _QE._ _ __,,,An,,,aw..l Vz.,Zoseds._......eBCL...y CAS No.
Prep/Method: EPA 3010 / EPA 6010
ND mg/1 0.0050 1.0 06/11/02 18:33 DJR 7440-38-2
0. 02B mg/1 0.0050 1.0 06/11/02 18:33 DJR 7440-39-3
ND mg/1 0.0010 1.0 06/11/02 18:33 DJR 7440-43-9
0. 0058 mg/1 0.0020 1.0 06/11/02 18:33 DJR 7440-47-3
ND mg/1 0.0050 1.0 06/11/02 18:33 DJR 7439-92-1
0. 093 mg/1 0.0050 1.0 06/11/02 18:33 DJR 7439-96-5
ND mg/1 0 .0050 1.0 06/11/02 18:33 DJR 77B2·49-2
ND mg/1 0.0020 1.0 06/11/02 18:33 DJR 7440-22-4
06/04/02
Method: EPA 7470
ND mg/1 0.00020 1.0 06/03/02 LBG 7439-97-6
Method: EPA 300.0
4.7 mg/1
0.62 mg/1
1.0
0.10
1.0
1.0 05/31/02
1.0 05/31/02
1. 0 05/31/02
COE 16B87-00-6
COE
1.1 mg/1
Method: EPA 310.1
10. mg/1 1.0 1.0 06/05/02
Method: SM 6230D
ND ug/1 250 500 06/03/02
ND ug/1 250 500 06/03/02
ND ug/1 250 500 06/03/02
ND ug/1 250 500 06/03/02
ND ug/1 250 500 06/03/02
ND ug/1 250 500 06/03/02
ND ug/1 500 500 06/03/02
ND ug/1 250 500 06/03/02
ND ug/1 250 500 06/03/02
650 ug/1 250 500 06/03/02
ND ug/1 250 500 06/03/02
ND ug/1 250 500 06/03/02
12000 ug/1 250 500 06/03/02
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,11 Hco_, ._<:I~~.
§/) ·1·-,_ ".,. 11neac\1
COE
HEH
KTV 71·43·2
KTV 108-86-1
KTV 74.97.5
KTV 75-27-4
KTV 75-25-2
KTV 74-83-9
KTV 104-51-8
KTV 135-98-8
KTV 98-06-6
KTV 56-23-5
KTV 108-90-7
KTV 75-00-3
KTV 67-66-3
Page: 103
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
ace Analytical™ .
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone] www.pacelabs.com
Lab Sample No: 922293279
Client Sample ID: MW-8 DUP
Parameters
Chloromethane
2-Chlorotoluene
4 ·Chl oroto 1 uene
1,2-Dibromo-3-chloropropane
Dibromochloromethane ,
1,2-Dibromoetnane (EDB) ·-].,
Di bromo~ttiane
1. 2 ~o; chlorobenzene
,,,,..{3·:[); chl orobenzene
.,,--;:;.-" i, 4-Di chl orobenzene
.-✓:;")/ Di chl orodi fl uoromethane
1.l·Dichloroethane
1,2-Dichloroethane
1.1-Dichloroethene
cis-1,2-Dichloroethene
trans-1.2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2.2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethyl benzene
Hexachloro-1,3-butadiene
lsopropylbenzene (Cumene)
p·Isopropyltoluene
Methylene chloride
Hethyl-tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,l.l.2·Tetrachloroethane
1,1,2.2-Tetrachloroethane
Tetrachloroethene
Toluene
1.2,3-Trichlorobenzene
1,2.4-Trichlorobenzene
1,1,1-Trichloroethane
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
Results
ND
ND
ND
ND
ND
500
ND.
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
NO
ND
NO
ND
NO
ND
ND
ND
ND
ND
NO
ND
ND
NO
NO
ND
Units
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
Lab Project.Number: 9233015
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-050
Matrix: Water
Date Collected: 05/29/02 17:00
Date Received: 05/30/02 16:15
Report Limit ...QL. __ A~n~a~l~yz~e~d __ B~Y~ -~C~A~S~N~o~. _ lli!tl._ ReqLmt
1000 500 06/03/02 KTV 74-87-3
250 500 06/03/02
250
1000
250
250
250
500
500
500
250
250
250
250
250
250
250
250
250
250
250
250
250
250
1000
250
500
1000
250
1000
250
250
250
250
250
250
1000
1000
250
500 06/03/02
500 06/03/02
500 06/03/02
500 06/03/02
500 06/03/02
500 06/03/02
500 06/03/02
500 06/03/02
500 06/03/02
500 06/03/02
500 06/03/02
500 06/03/02
500 06/03/02
500 06/03/02
500 06/03/02
500 06/03/02
500 06/03/02
500 06/03/02
500 06/03/02
500 06/03/02
500 06/03/02
500 06/03/02
500 06/03/02
500 06/03/02
500 06/03/02
500 06/03/02
500 06/03/02
500 06/03/02
500 06/03/02
500 06/03/02
500 06/03/02
500 06/03/02
500 06/03/02
500 06/03/02
500 06/03/02
500 06/03/02
500 06/03/02
KTV 95-49·8
KTV 106-43·4
KTV 96-12·8
KTV 124-48·1
KTV 106-93·4
KTV 74.95.3
KTV 95-50-1
KTV 541-73-1
KTV 106-46-7
KTV 75-71-8
KTV 75-34-3
KTV 107-06·2
KTV 75.35.4
KTV 156-59·2
KTV 156-60·5
KTV 78-87-5
KTV 142-28·9
KTV 594·20·7
KTV 563-58-6
KTV 10061·01-5
KTV 10061-02-6
KTV 108-20-3
KTV 100-41-4
KTV 87-68-3
KTV 98-82·8
KTV 99-87-6
KTV 75-09·2
KTV 1634-04·4
KTV 91·20·3
KTV 103-65-1
KTV 100-42-5
KTV 630-20-6
KTV 79.34.5
KTV 127-18-4
KTV 108-88·3
KTV 87·61·6
KTV 120-82-1
KTV 71-55·6
Page: 104
REPORT OF LABORATORY ANALYSIS Laboratory Certification IDs
LA Wastewater 04034 This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
.-~-!iOetaC\l
VA Drinking Water 213
FL NELAP E87627
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ace Analytical™
www.pacelabs.com
Lab Sample No: 922293279 \ .. ·,r:,,
Client Sample ID: MW-8 OUP
f
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Lab Project Number: 9233015
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-050 Date Collected: 05/29/02 17:00
Matrix: Water Date Received: 05/30/02 16:15
I Parameters Results Units Re~ort Limit _Qf_ Anal ~zed 8~ CAS No. 9!!tl_ RegLmt
I
1. 1.2-Trichloroethane /~ _ (
Trichloroethene
Tri chl orofl uorornetti'an~--·
1,2,3-Trichlor9propane
1. 2. 4 · Trimethyl_benzene
I 1,3,5-Trimethylbenzene
Vinyl ,,chloride
m&p-,Xyl ene
/'·,'_
I ~-·'~:Xylene
,-,~.'-·' 1-Chloro-3-fluorobenzene (SJ
_.')i;,.,
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Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
NO ug/1 250 500 06/03/02
NO ug/1 250 500 06/03/02
ND ug/1 250 500 06/03/02
NO ug/1 250 500 06/03/02
ND ug/l 250 500 06/03/02
NO ug/l 250 500 06/03/02
ND ug/l 250 500 06/03/02
ND ug/1 250 500 06/03/02
NO ug/1 250 500 06/03/02
104 X 1. 0 06/03/02
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,~ .cco • . ,v-=. o'/' 1..:r-'(, fLOt:::taC\l
KTV 79·00·5
KTV 79-01·6
KTV 75-69·4
KTV 96·18·4
KTV 95-63-6
KTV 108-67-8
KTV 75-01-4
KTV
KTV 95-47·6
KTV 625·98·9
Page: 105
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
ace Analytical™
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone] www.pacelabs.com Lab Project Number: 9233015
Lab Sample No: 922293287
Client Sample ID: MW•I2
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015·051
Matrix: Water
Date Collected: 05/30/02 12:00
Date Received: 05/30/02 16:15
~Pa=r=am=e~te=r~s-----~~~}. '_~R=es=u~lt=s~_ Units Report Limit ...QL -~A~n=a~ly=z~ed~~6~y CAS No. Metals
Metals by Trace ICP
Arsenic
Barium
Cadmium ,\ /
Chromium .. ·.
Lead ,i' •
Manga_fleSe , ,
/se1e"nium .,,_.r-/~ .. -;>5'; 1 ver
? Date Digested
Mercury, CVMS, in Water
Mercury
Wet Chemistry
Jon Chromatography
Chloride
Nitrate
Sulfate
Alkalinity. Total
Alkalinity. Total
GC Volatiles
GC VOCs in Water
Benzene
Bromobenzene
Bromochloramethane
Bromodichloromethane
Bromoforrn
Bromomethane
n-Butyl benzene
sec-Butyl benzene
tert·6utylbenzene
Carbon tetrachloride
Chl orobenzene
Chloroethane
Chloroform
Oate: 06/29/02
Prep/Method: EPA 3010 / EPA 6010
ND mg/1 0.0050
0.37 mg/1 0.0050
0.0044 mg/1 0.0010
ND
ND
mg/1
mg/1
13. mg/1
0. 010 mg/1
ND mg/1
Method: EPA 7470
0. 00027 mg/1
Method: EPA 300.0
55. mg/1
0.32 mg/1
ND mg/1
Method: EPA 310.1
2.5 mg/1
Method: SM 6230D
13000 ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
6900 ug/1
ND ug/1
ND ug/1
100000 ug/1
0.0020
0.0050
D.0050
0.0050
0.0020
0.00020
1.0
0.10
1.0
1.0
1000
1000
1000
1000
1000
1000
2000
1000
1000
1000
1000
1000
2500
1.0 06/11/02 18:57 DJR 7440·36·2
1.0 06/11/02 18:57 DJR 7440·39·3
1.0 06/11/02 18:57 DJR 7440·43·9
1.0 06/11/02 18:57 DJR 7440·47·3
1.0 06/11/02 18:57 DJR 7439·92·1
1.0 06/11/02 18:57 DJR 7439·96·5
1.0 06/11/02 18:57 DJR 7782·49·2
1.0 06/11/02 18:57 DJR 7440·22·4
06/04/02
1. 0 06/03/02
1. 0 05/31/02
1. 0 05/31/D2
1.0 05/31/02
1.0 06/05/02
2000 06/04/02
2000 D6/04/02
2000 06/04/02
2000 06/04/02
2000 06/04/02
2000 06/04/02
2000 06/04/02
2000 06/04/02
2000 06/04/02
2000 06/04/02
2000 06/04/02
20D0 06/04/02
5000 06/04/02
L6G 7439·97•6
COE 16887·00·6
COE
COE
HEH
KTV 71-43•2
KTV 108·86·1
KTV 74.97.5
KTV 75-27·4
KTV 75-25·2
KTV 74-83·9
KTV 104·51·8
KTV 135·98·8
KTV 98-06·6
KTV 56-23·5
KTV 106·90·7
KTV 75-00·3
KTV 67·66·3
Page: 106
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Laboratory Certification IDs REPORT OF LABORATORY ANALYSIS Laboratory Certification IDs I
LA Wastewater 04034 NC Wastewater 12
NC Drinking Water 37706
SC 99006
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
fi~l
VA Drinking Water 213
FL NELAP E87627 I
I Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100 ace Analytical™ Huntersville, NC 28078
I Phone: [phone]
www.pacelabs.com
Lab Project Number: 9233015 Fax: [phone]
Client Project ID: NCSU Lot 86/2246
I Lab Sample No: 922293287 Project Sample Number: 9233015-051 Date Collected: 05/30/02 12:00
Client Sample ID: MW-12 , .. ,
Matrix: Water Date Received: 05/30/02 16:15 . '
I Parameters Results Units ReQQrt Limit .J?.L Analyzed By CAS No. Q!!tl_ RegLmt
Chloromethane ND ug/1 4000 2000 06/04/02 KTV 74-87·3
2-Chlorotoluene ND ug/l 1000 2000 06/04/02 KTV 95-49·8 I 4-Chl orotol uene ND ug/1 1000 2000 06/04/02 KTV 106-43·4
1,2-Dibromo-3-chloropropane ND ug/l 4000 2000 06/04/02 KTV 96-12·8
Oi bromoch1 oi:9m~fhane ND ug/1 1000 2000 06/04/02 KTV 124·48·1
I 1.2-Dibromoethane (EDB) 6900 ug/1 1000 2000 06/04/02 KTV 106-93·4 ;
Oibroroolnettiane ND ug/1 1000 2000 06/04/02 KTV 74.95.3 .• ',,
1, 2 -D.i chlorobenzene ND ug/1 2000 2000 06/04/02 KTV 95-50·1 •'
1 ,,-(3-Dichlorobenzene ND ug/1 2000 2000 06/04/02 KTV 541·73·1 / )'
106-46-7 /,";.·' 1,4-Dichlorobenzene ND ug/1 2000 2000 06/04/02 KTV
./--_..,. Dichlorodifluoromethane ND ug/1 . 1000 2000 06/04/02 KTV 75-71·8 •. .
1,1-Dichloroethane ND ug/1 1000 2000 06/04/02 KTV 75.34.3
I 1.2-Dichloroethane ND ug/1 1000 2000 06/04/02 KTV 107-06·2
l,l•Dichloroethene ND ug/1 1000 2000 06/04/02 KTV 75.35.4
cis-1.2-Dichloroethene ND ug/1 1000 2000 06/04/02 KTV 156-59-2
I trans-1,2-Dichloroethene ND ug/1 1000 2000 06/04/02 KTV 156-60·5
1.2-Dichloropropane 23000 ug/1 1000 2000 06/04/02 KTV 78-87-5
1.3-Dichloropropane ND ug/1 1000 2000 06/04/02 KTV 142-28·9
I 2.2-Dichloropropane ND ug/l 1000 2000 06/04/02 KTV 594-20-7
1, 1-Dichloropropene ND ug/1 1000 2000 06/04/02 KTV 563-58·6
ci s-1. 3 ·Di chl oropropene ND ug/1 1000 2000 06/04/02 KTV 10061·01-5
trans-1,3-Dichloropropene ND ug/1 1000 2000 06/04/02 KTV 10061·02-6
I Diisopropyl ether ND ug/l 1000 2000 06/04/02 KTV 108·20·3
Ethyl benzene ND ug/1 1000 2000 06/04/02 KTV 100-41·4
Hexachloro-1.3-butadiene ND ug/1 4000 2000 06/04/02 KTV 87-68·3
I Isopropylbenzene (Cumene) ND ug/l 1000 2000 06/04/02 KTV 98·82·8
p-lsopropyltoluene ND ug/1 2000 2000 06/04/02 KTV 99-87·6
Methylene chloride 19000 ug/1 4000 2000 06/04/02 KTV 75-09-2
Methyl•tert-butyl ether ND ug/1 1000 2000 06/04/02 KTV 1634-04-4 I Naphthalene ND ug/1 4000 2000 06/04/02 KTV 91-20-3
n-Propyl benzene ND ug/1 1000 2000 06/04/02 KTV 103-65·1
Styrene ND ug/1 1000 2000 06/04/02 KTV 100·42·5
I 1.l.l.2·Tetrachloroethane ND ug/1 1000 2000 06/04/02 KTV 630-20·6
l,l,2,2·Tetrachloroethane ND ug/1 1000 2000 06/04/02 KTV 79.34.5
Tetrachloroethene ND ug/1 1000 2000 06/04/02 KTV 127·18·4
I Toluene 9600 ug/l 1000 2000 06/04/02 KTV 108-88·3
1.2.3-Trichlorobenzene ND ug/l 4000 2000 06/04/02 KTV 87-61·6
1.2,4-Trichlorobenzene ND ug/1 4000 2000 06/04/02 KTV 120·82·1
1,1,1-Trichloroethane ND ug/l 1000 2000 06/04/02 KTV 71-55·6 I
Date: 06/29/02
I
Page: 107
I Laboratory Certification IDs REPORT OF LABORATORY ANALYSIS Labgratgry Certification IDs
NC Wastewater 12 LA Wastewater 04034
NC Drinking Water 37706 This report shall not be reproduced, except in full, VA Drinking Water 213
I SC 99006 without the written consent of Pace Analytical Services, Inc. FL NELAP E87627 ,. '-Cto~ ~ lnelaci
.-; .. ·.• ,
ace Analytical™
www.pacelabs.com
Lab Samp l e No: 922293287
Client Sample ID: MW-12
Parameters Results Units
1,1,2-Trichloroethane ND ug/l
Trichloroethene ND ug/l
Tri chl orofl uoromettfa'rie ,,· ND ug/l
1,2,3-Trichlorqp~oP~n~ ND ug/l
1,2.4-Trimethylbenzene ND ug/l
1.3.5-Trimethyibenzene ND ug/l
Vinyl .. c1{icl~ide ND ug/l
,pJyle~e 1900 ug/1
,,...(,_9; Xy 1 ene ND ug/l
./y,,.· l·Chloro-3-fluorobenzene (S) 97 t
Date: 06/29/02
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Lab Project Number: 9233015
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-051 Date Co 11 ected: 05/30/02 12:00
Matrix: Water Date Received: 05/30/02 16:15
ReRort Limit ....!lL Analtzed St CAS No. lli@l.. RegLmt
1000 2000 06/04/02 KTV 79-00·5
1000 2000 06/04/02 KTV 79-01·6
1000 2000 06/04/02 KTV 75-69·4
1000 2000 06/04/02 KTV 96-18·4
1000 2000 06/04/02 KTV 95-63·6
1000 2000 06/04/02 KTV 108-67-8
1000 2000 06/04/02 KTV 75-01·4
1000 2000 06/04/02 KTV
1000 2000 06/04/02 KTV 95-47-6
I. 0 06/04/02 KTV 625·98-9
Page: 108
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Laboratory Certification IDs I
LA Wastewater 04034
Laboratory Certification IDs
NC Wastewater 12 REPORT OF LABORATORY ANALYSIS
NC Drinking Water 37706
SC 99006
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,._<; ,~ AC~o,t0~ .~
1
s,. •c, t1neac1t
VA Drinking Water 213
FL NELAP E87627 I
I
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ace Analytical™
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone] www.pacelabs.com Lab Project Number: 9233015
I
Lab Sample No: 922293295
Client Sample ID: MW-16
Parameters
Metals
Metals by Trace ICP
Arsenic
Barium
Cadmium · ,;.y
Chromium, •
Lead/,)/
Manganese ,,-_,.-
I ./~§:1enium
,.,,-(,·. · Silver
<P·'· -Date Digested
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Mercury, CVAAS, in Water
Mercury
Wet Chemistry
Ion Chromatography
Chloride
Nitrate
Sulfate
Alkalinity, Total
Alkalinity, Total
GC Volatiles
GC voes in Water
Benzene
Bromobenzene
Bromochloromethane
8romodichloromethane
Bro100form
Bromomethane
n-8utylbenzene
sec-Butyl benzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chl oroethane
Chloroform
Date: 06/29/02
Laboratory Certification IDs .
NC Wastewater 12
NC Drinking Water 37706
SC 99006
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-052
Matrix: Water
Date Collected: 05/30/02 08:30
Date Received: 05/30/02 16:15
Results Units Report Limit .JlL -~An~a~l~yz~e~d~~8y~ CAS No. ~ RegLmt
Prep/Method:
ND
0.13
ND
ND
ND
16.
0,010
ND
EPA 3010 I EPA 6010
mg/1 0.0050
mg/1 0.0050
mg/1 0.0010
mg/1 0.0020
mg/1 0.0050
mg/1 0.0050
mg/1 0.0050
mg/1 0.0020
1.0 06/11/02 19:02 DJR 7440-38·2
1.0 06/11/02 19:02 DJR 7440-39-3
1.0 06/11/02 19:02 DJR 7440-43-9
1.0 06/11/02 19:02 DJR 7440-47-3
1.0 06/11/02 19:02 DJR 7439-92·1
1.0 06/11/02 19:02 DJR 7439-96-5
1.0 06/11/02 19:02 DJR 7782-49·2
1.0 06/11/02 19:02 DJR 7440-22-4
06/04/02
Method: EPA 7470
0.00079 mg/1 0,00020 1.0 06/03/02 L8G 7439-97-6
Method: EPA 300.0
6,3 mg/1
ND mg/1
1.0
0.10
1.0
1. 0 05/31/02
1. 0 05/31/02
1. 0 05/31/02
COE 16887-00·6
COE
4.0 mg/1 COE
Method: EPA 310.1
52. mg/1 1.0 1.0 06/05/02 HEH
Method: SM 6230D
2900 · ug/1 500 1000 06/04/02 03:28 KTV
ND ug/1 500 1000 06/04/02 03:28 KTV
ND ug/1 500 1000 06/04/02 03:28 KTV
ND ug/1 500 1000 06/04/02 03:28 KTV
ND ug/1 500 1000 06/04/02 03:28 KTV
ND ug/1 500 1000 06/04/02 03:28 KTV
ND ug/1 1000 1000 06/04/02 03:28 KTV
ND ug/1 500 1000 06/04/02 03:28 KTV
ND ug/1 500 1000 06/04/02 03:28 KTV
1900 ug/1 500 1000 06/04/02 03:28 KTV
ND ug/1 500 1000 06/04/02 03:28 KTV
ND ug/1 500 1000 06/04/02 03:28 KTV
35000 . ug/1 500 1000 06/04/02 03:28 KTV
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
~~~ ?i□~aCit
71-43·2
108-86·1
74.97.5
75-27-4
75-25-2
74-83·9
104-51·8
135-98·8 ·
98-06·6
56-23-5
108-90-7
75-00·3
67-66·3
Page: 109
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
(
ace Analyticar·
www.pacelabs.com
Lab Samp 1 e No: 922293295
Client Sample ID: MW-16
~Pa~r~a~me~t~e~r'~-----.,.-~··_,,· ·~·· -~R~es~u~lt~''---Units
Chloromethane ' ND ug/1
2-Chlorotoluene ,, ND ug/1
4-Chlorotoluene ND ug/1
1. 2 · Di bromo-3 • chi'oropropane
Di bro100chl oroni~ih~ne
1.2-Dibromo;tha'ne (ED8l
Di brooo~thine
1. 2;P.i Chi orobenzene
,,,,,f. 31:'"o; chl orobenzene .fr~~· /.·<~ ... -1, 4-Di chl orobenzene
~:··· ·,;: Y Diehl orodi fl uoromethane
'· 1.1-Dichloroethane
1,2-Dichloroethane
1.1-Dichloroethene
cis-1.2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1.3-Dichloropropane
2,2-Dichloropropane
1.1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethyl benzene
Hexachloro-1.3-butadiene
Isopropylbenzene (Cumene)
p-Isopropyltoluene
Methylene chloride
Methyl-tert-butyl ether
Naphtha 1 ene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1.2.2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1.2.4-Trichlorobenzene
1,1,1-Trichloroethane
Date: 06/29/02
ND ug/1
ND ug/1
8900 ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
5400 ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
1500 ug/1
5000 ug/1
ND ug/1
ND ug/1
ND ug/1
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Lab Project Number: 9233015
Client Project ID: NCSU Lot 86/2246
Phone: [phone]
Fax: [phone]
Project Sample Number: 9233015-052
Matrix: Water
Date Collected: 05/30/02 08:30
Date Received: 05/30/02 16:15
Report Limit ..QE__
2000 1000
Analyzed By
06/04/02 03:28 KTV
06/04/02 03:28 KTV
~C~A~S~N~o~. _ lli!tl._ ReqLmt
74-87-3
500 1000 95-49-8
500 1000 06/04/02 03:28 KTV 106-43-4
2000 1000 06/04/02 03:28 KTV 96-12-8
500 1000 06/04/02 03:28 KTV 124-48-1
500 1000 06/04/02 03:28 KTV 106-93-4
500 1000 06/04/02 03:28 KTV 74-95-3
1000 1000 06/04/02 03:28 KTV 95-50-1
1000 1000 06/04/02 03:28 KTV 541-73-1
1000 1000 06/04/02 03:28 KTV 106-46-7
500 1000 06/04/02 03:28 KTV 75-71-8
500 1000 06/04/02 03:28 KTV 75-34-3
500 1000 06/04/02 03:28 KTV 107-06-2
500 1000 06/04/02 03:28 KTV 75-35-4
500
500
500
500
500
500
500
500
500
500
2000
500
1000
2000
500
2000
500
500
500
500
500
500
2000
2000
500
1000 06/04/02 03:28 KTV 156-59-2
1000 06/04/02 03:28 KTV 156-60-5
1000 06/04/02 03:28 KTV 78-87-5
1000 06/04/02 03:28 KTV 142-28-9
1000 06/04/02 03:28 KTV 594-20-7
1000 06/04/02 03:28 KTV 563-58-6
1000 06/04/02 03:28 KTV 10061-01·5
1000 06/04/02 03:28 KTV 10061-02-6
1000 06/04/02 03:28 KTV 108-20-3
1000 06/04/02 03:28 KTV 100-41-4
1000 06/04/02 03:28 KTV 87-68-3.
1000 06/04/02 03:28 KTV 98-82-8
1000 06/04/02 03:28 KTV 99-87-6
1000 06/04/02 03:28 KTV 75-09-2
iooo 06104102 03:28 KTV 1634-04-4
1000 06/04/02 03:28 KTV 91-20-3
1000 06/04/02 03:28 KTV 103-65-1
1000 06/04/02 03:28 KTV 100-42-5
1000 06/04/02 03:28 KTV 630-20-6
1000 06/04/02 03:28 KTV 79-34-5
1000 06/04/02 03:28 KTV 127-18-4
1000 06/04/02 03:28 KTV 108-88-3
1000 06/04/02 03:28 KTV 87-61-6
1000 06/04/02 03:28 KTV 120-82-1
1000 06/04/02 03:28 KTV 71-55-6
Page; 110
Laboratory Certification IDs
NC Wastewater 12 REPORT OF LABORATORY ANALYSIS Laboratory Certification IDs
LA Wastewater 04034
NC Drinking Water 37706
SC 99006
This report shall not be reproduced, except in full,
without the written consent of Pace AnalY1ical Services, Inc.
i• •Cto., --~-!in~aC1\
VA Drinking Water 213
FL NELAP E87627
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"
I ace Analytical™
www.pacelabs.com
I Lab Sample No: 922293295
Client Sample ID: MW-16 '
,,
·•., . ; ..
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Lab Project Number: 9233015
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-052
Matrix: Water
Date Collected: 05/30/02 08:30
Date Received: 05/30/02 16:15
I Parameters Results Units Re~ort Limit _Qf_ Analyzed By CAS No. Q!ltl_ RegLmt
I
1.1.2· Trichloroethane.
Trichloroethene / . Trichlorofluoromet~ane· ',' / 1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
I 1,3,5-Trimethyibenzene
Vinyl chloride
m&p-Xyle~e
I ,ci~Xylene / ..-,.~;>,, l-Chloro-3-fluorobenzene (S}
.-',J;/
V
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Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
ND ug/l 500 1000 06/04/02 03:28 KTV
2700 ug/l 500 1000 06/04/02 03:28 KTV
ND ug/l 500 1000 06/04/02 03:28 KTV
ND ug/l 500 1000 06/04/02 03:28 KTV
ND ug/l 500 1000 06/04/02 03:28 KTV
ND ug/l 500 1000 06/04/02 03:28 KTV
ND ug/l 500 1000 06/04/02 03:28 KTV
ND ug/l 500 1000 06/04/02 03:28 KTV
510 ug/l 500 1000 06/04/02 03:28 KTV
99 X 1.0 06/04/02 03:28 KTV
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,,. >tea.,
.o/~, !l□~C\1
79-00·5
79-01-6
75-69·4
96-18•4
95-63·6
108-67·8
75-01·4
95.47.5
625-98·9
Page: Ill
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
ace Analytical™
www.pacelabs.com
Lab Sample No: 922293303
Client Sample JD: MW-36S
~P~ar..,a""me"'t~e~rs,_ _____ ~··c.c··-'·"'-'>. -~R=es=u=lt~s~_ Units Metals
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Lab Project Number: 9233015
Phone: [phone]
Fax: [phone]
Client Project JD: NCSU Lot 86/2246
Project Sample Number: 9233015-053
Matrix: Water
Date Collected: 05/30/02 09:30
Date Received: 05/30/02 16:15
Report Limit J!E_ __ A~n~a=l=yz=e~d __ 8=Y~ -~C~A=S~N=o=·-~ RegLmt
Metals by Trace ICP
Arsenic
Prep/Method: EPA 3010 / EPA 6010
Barium
Cadmium •..f,,,
Chromium
Lead /1,,/
Manganese
,,r·S~lE!~ium .,.,,J/ -~;;· · Silver
.. <'. Date Digested
Mercury, CVAAS. in Water
Mercury
Wet Chemistry
Ion Chromatography
Chloride
Nitrate
Sulfate
Alkalinity. Total
Alkalinity. Total
GC Volatiles
GC voes in water
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butyl benzene
tert-Butylbenzene
Carbon tetrachloride
Chl orobenzene
Chloroethane
Chloroform
Date: 06/29/02
ND mg/1 0,0050 LO 06/11/02 19:07 DJR 7440-38-2
1.0 06/11/02 19:07 DJR 7440-39-3
1.0 06/11/02 19:07 DJR 7440-43-9
1.0 06/11/02 19:07 DJR 7440-47-3
1.0 06/11/02 19:07 DJR 7439-92-1
1.0 06/11/02 19:07 DJR 7439-96-5
1.0 06/11/02 19:07 DJR 7782-49-2
1.0 06/11/02 19:07 DJR 7440·22-4
0.35
0.0029
0.037
0.010
15.
0.011
ND
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
Method: EPA 7470
0.0029 mg/1
Method: EPA 300.0
39. mg/1
ND mg/1
1.5 mg/1
Method: EPA 310.1
18. mg/1
Method: SM 62300
5200 ug/1
ND
ND
3300
ND
ND
ND
ND
ND
2900
NO
NO
34000
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
0.0050
0.0010
0.0020
0.0050
0.0050
0.0050
0.0020
06/04/02
0.00020 1.0 06/03/02 L8G 7439-97-6
1.0 1.0 05/30/02 COE 16887-00-6
COE 0.10 1.0 05/30/02
1,0 1.0 05/30/02 COE
1.0 1.0 06/05/02 HEH
500
500
500
500
500
500
1000
500
500
500
500
500
500
1000 06/04/02 04:14 KTV 71-43-2
1000 06/04/02 04:14 KTV 108-86-1
1000 06/04/02 04:14 KTV 74-97-5
1000 06/04/02 04:14 KTV 75-27-4
1000 06/04/02 04:14 KTV 75-25-2
1000 06/04/02 04:14 KTV 74-83-9
1000 06/04/02 04:14 KTV 104-51-8
1000 06/04/02 04:14 KTV 135-98-8
1000 06/04/02 04:14 KTV 98-06-6
1000 06/04/02 04:14 KTV 56-23-5
1000 06/04/02 04:14 KTV 108-90-7
1000 06/04/02 04:14 KTV 75-00·3
1000 06/04/02 04:14 KTV 67-66-3
Page: 112
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Laboratory Certification IDs REPORT OF LABORATORY ANALYSIS Laboratory Certification IDs I NC Wastewater 12
NC Drinking Water 37706
SC 99006
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,~ ACCQ~ /~~~ ,1n~r\t
LA Wastewater 04034
VA Drinking Water 213 1 FL NELAP E87627
I
I
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I
ace Analytical™
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: 704:875.9091 www.pacelabs.com
I
I
Lab Sample No: 922293303
Client Sample ID: MW-36S
Parameters
Chloromethane
2·Chlorotoluene
4-Chlorotoluene
l,2·Dibromo-3-chloropropane
Di bromochl oronie_th~ne
1,2-Dibromoethane (EDB)
Oibromomethane
1,2:Dichlorobenzene
I /,{:3:[);chlorobenzene
_/,-_:~.-i.4-Dichlorobenzene
_ .. --,· ::-·· Di chlorodi fl uoromethane
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1,1-Dichloroethane
1.2-Dichloroethane
1.1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloraethene
I. 2-Di chl oropropane
1.3-Dichloropropane
2,2-0ichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans·l,3-Dichloropropene
Diisopropyl ether
Ethyl benzene
Hexachloro-1.3-butadiene
lsopropylbenzene (Cumene)
p-Isopropyltoluene
Methylene chloride
Methyl-tert·butyl ether
Naphthalene
n-Propylbenzene
Styrene
l,l,1,2·Tetrachloroethane
1.1.2.2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2.3-Trichlorobenzene
1.2.4-Trichlorobenzene
1.1.1-Trichloroethane
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC □_rinking Water 37706
SC 99006
' . :. ' . '
Results
ND
ND
ND
ND
ND
19000
ND
ND
ND
ND
ND
ND
1400
ND
ND
ND
2100
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
5100
ND
ND
ND
ND
ND
ND
ND
690
ND
ND
ND
Units
ug/1
ug/l
ug/l
ug/l
ug/l
ug/1
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/1
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/1
ug/l
ug/1
ug/l
ug/l
ug/l
ug/l
ug/1
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/1
ug/l
ug/1
ug/l
ug/l
Lab Project Number: 9233015
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015·053
Matrix: Water
Date Collected: 05/30/02 09:30
Date Received: 05/30/02 16:15
Report Limit ....QE_ Analyzed By CAS No.
2000 1000 06/04/02 04:14 KTV 74-87·3
500 1000 06/04/02 04:14 KTV 95-49-8
500 . 1000 06/04/02 04:14 KTV 106-43•4
2000 1000 06/04/02 04:14 KTV 96·12·8
500 1000 06/04/02 04:14 KTV 124-48·1
500 1000 06/04/02 04:14 KTV 106·93·4
500 1000 06/04/02 04:14 KTV 74.95.3
1000 1000 06/04/02 04:14 KTV 95-50·1
1000 1000 06/04/02 04:14 KTV 541-73-1
1000 1000 06/04/02 04:14 KTV 106-46·7
500 1000 06/04/02 04:14 KTV 75-71-8
500 1000 06/04/02 04:14 KTV 75.34.3
500 1000 06/04/02 04:14 KTV 107-06-2
500 1000 06/04/02 04:14 KTV 75.35.4
500 1000 06/04/02 04:14 KTV 156-59-2
500
500
500
500
500
500
500
500
500
2000
500
1000
2000
500
2000
500
500
500
500
500
500
2000
2000
500
1000 06/04/02 04:14 KTV 156-60-5
1000 06/04/02 04:14 KTV 78-87·5
1000 06/04/02 04:14 KTV 142-28-9
1000 06/04/02 04:14 KTV 594·20·7
1000 06/04/02 04:14 KTV 563-58-6
1000 06/04/02 04:14 KTV 10061-01-5
1000 06/04/02 04:14 KTV 10061-02-6
1000 06/04/02 04:14 KTV 108·20·3
1000 06/04/02 04:14 KTV 100-41·4
1000 06/04/02 04:14 KTV 87·68·3
1000 06/04/02 04:14 KTV 98-82-8
1000 06/04/02 04:14 KTV 99-87·6
1000 06/04/02 04:14 KTV 75-09-2
1000 06/04/02 04:14 KTV 1634-04-4
1000 06/04/02 04:14 KTV 91·20·3
1000 06/04/02 04:14 KTV 103·65-l
1000 06/04/02 04:14 KTV 100·42·5
1000 06/04/02 04:14 KTV 630·20·6
1000 06/04/02 04:14 KTV 79.34.5
1000 06/04/02 04:14 KTV 127-18-4
1000 06/04/02 04:14 KTV 108-88-3
1000 06/04/02 04:14 KTV 87-61·6
1000 06/04/02 04:14 KTV 120·82-l
1000 06/04/02 04:14 KTV 71-55·6
Page: 113
REPORT OF LABORATORY ANALYSIS Laboratory Certification IDs
LA Wastewater 04034 This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc. VA Drinking Water 213
FL NELAP E87627
ace Analytical™
www.pacelabs.com
Lab Sample No: 922293303
Client Sample ID: MW-36S
Parameters .... Results Units
1.1.2-Trichloroethane ., · · ND ug/1
Trichloroethene 1800 ug/1
Trichlorofluoromethane ND ug/1
1.2.3-Trichloropropane ND ug/1
1,2 ,4· Tri methyl benzene ND ug/1
1. 3, 5-Tri methibenzene ND ug/1
Vinyl .ch1ciHde ND ug/1
m&p7Xylene ND ug/1 /.,• /' ~
ug/1 ND
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Lab Project Number: 9233015
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-053 Date Collected: 05/30/02 09:30
Matrix: Water Date Received: 05/30/02 16: 15
Re~ort Limit ...Q[_ Analyzed Bi CAS No. ~ RegLmt
500 1000 06/04/02 04:14 KTV 79-00-5
500 1000 06/04/02 04:14 KTV 79-01-6
500 1000 06/04/02 04:14 KTV 75-69-4
500 1000 06/04/02 04:14 KTV 96-18-4
500 1000 06/04/02 04:14 KTV 95-63-6
500 1000 06/04/02 04:14 KTV 108-67-8
500 1000 06/04/02 04:14 KTV 75-01-4
500 1000 06/04/02 04:14 KTV
500 1000 06/04/02 04:14 KTV 95-47-6 _,,✓.,o,Xylene .,.
/'.:/ 1-Chloro-3-fluorobenzene (Sl 103
,,,,/'•::, t 1.0 06/04/02 04:14 KTV 625-98-9
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Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
~ Jnelac\
Page: 114
Laboratory Certification IDs I
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627 I
I
I
I
ace Analytical™
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28018
Phone: [phone]
Fax: [phone] www.pacelabs.com Lab Project Number: 9233015
I
I
I
Lab Sample No: 922293329
Client Sample ID: MW-37
Parameters
Metals
Metals by Trace ICP
Arsenic
Barium
Cadmi urn
Chromium
Lead ~-:1,· _,.
M~ng·~nese
I ✓-;(;f-e1enium
./ / Silver
· · Date Digested
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Mercury, CVAAS, in Water
Mercury
Wet Chemistry
Ion Chromatography
Chloride
Nitrate
Sulfate
Alkalinity, Total
Alkalinity, Total
GC Volatiles
GC voes in Water
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butyl benzene
sec-Butyl benzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-054 Date Collected: 05/30/02 09:00
Matrix: Water Date Received: 05/30/02 16: 15
Results Units Report Limit ...QL Analyzed By CAS No. ~ RegLmt
Prep/Method: EPA 3010 / EPA 6010
ND mg/l
0.43 mg/l
ND mg/l
0.030 mg/l
0.011 mg/l
4.0 mg/l
ND mg/l
ND mg/l
Method: EPA 7470
0 .0012 mg/1
Method: EPA 300.0
24. mg/l
0.13 mg/l
1.4 mg/l
Method: EPA 310.1
60. mg/l
Method: SM 6230D
3600 ug/l
ND ug/l
ND ug/l
ND ug/l
ND ug/1
ND ug/l
ND ug/l
ND ug/1
ND ug/l
4200 ug/1
ND ug/l
ND ug/l
55000 ug/l
0.0050 1.0 06/11/02 19:31 DJR 7440-38-2
0.0050 1.0 06/11/02 19:31 DJR 7440-39-3
0.0010 1.0 06/11/02 19:31 DJR 7440-43-9
0.0020 1.0 06/11/02 19:31 DJR 7440·47-3
0.0050 1.0 06/11/02 19:31 DJR 7439-92-1
0.0050 1.0 06/11/02 19:31 DJR 7439-96-5
0.0050 1.0 06/11/02 19:31 DJR 7782-49-2
0.0020 1.0 06/11/02 19:31 DJR 7440-22-4
06/04/02
0.00020 1.0 06/03/02 LBG 7439-97-6
1.0
0.10
1.0
1.0
500
500
500
500
500
500
1000
500
500
500
500
500
1000
1. 0 05/30/02
1.0 05/30/02
1.0 05/30/02
1. 0 06/07 /02
1000 06/04/02
1000 06/04/02
1000 06/04/02
1000 06/04/02
1000 06/04/02
1000 06/04/02
1000 06/04/02
1000 06/04/02
1000 06/04/02
·1000 06/04/02
1000 06/04/02
1000 06/04/02
2000 06/04/02
CDE 16887-00-6
CDE
CDE
HEH
KTV 71-43-2
KTV 108-86·1
KTV 74.97.5
KTV 75-27-4
KTV 75-25-2
KTV 74-83-9
KTV 104-51-8
KTV 135·98·8
KTV 98·06-6
KTV 56-23-5
KTV 108-90-7
KTV 75-00-3
KTV 67-66-3
Page: 115
REPORT OF LABORATORY ANALYSIS Laboratory Certification IDs
LA Wastewater 04034 This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,. •eco~ ,-}Cr,.~-
ffLnt::taC\\
VA Drinking Water 213
FL NELAP E87627
Pace Analytical Services, Inc. I
ace Analytical™ 9800 Kincey Avenue, Suite 100
Huntersville, NC 28078 I Phone.· 104.815.9092 www.pacelabs.com
Lab Project Number: 9233015 Fax.· 704.815.9091
Client Project ID: NCSU Lot 86/2246 I Lab Sample No: 922293329 Project Sample Number: 9233015-054 Date Co 11 ected: 05/30/02 09:00 Client Sample ID: MW·37 Matrix: Water Date Received: 05/30/02 16: 15
Parameters Results Units Re~ort Limit __QE__ Analyzed By CAS No. !l!!ru_ RegLmt I Chloromethane ND ug/1 2000 1000 06/04/02 KTV 74·87·3 2·Chlorotoluene ND ug/1 500 1000 06/04/02 KTV 95·49·8 I 4-Chlorotoluene ND ug/1 500 1000 06/04/02 KTV 106-43·4 l,2·Dibromo•3·~hloropropane ND ug/1 2000 1000 06/04/02 KTV 96·12·8 Di bromochloromethane ND ug/1 500 1000 06/04/02 KTV 124·48·1 I l,2·Dibromoetha~e (EDB) ND ug/l 500 1000 06/04/02 KTV 106-93·4 Di bromot1lethc;ne ND ug/1 500 1000 06/04/02 KTV 74.95.3 ,,-~-/ 1.2-Dichlorobenzene .... . ~· ND ug/1 1000 1000 06/04/02 KTV 95-50·1
I .,,:r: 3'-Dichlorobenzene ND ug/1 1000 1000 06/04/02 KTV 541·73•1 ./'~> •i, 4-Di ch 1 orobenzene ND ug/1 1000 1000 06/04/02 KTV 106·46·7 .,-•'. ;-,.,, · Di chl orodi fl uoromethane ND ug/1 500 1000 06/04/02 KTV 75•71·8 l.l·Dichloroethane ND ug/1 500 1000 06/04/02 KTV 75.34.3 I 1,2-Dichloroethane 700 ug/1 500 1000 06/04/02 KTV 107·06·2 1,l·Dichloroethene ND ug/1 500 1000 06/04/02 KTV 75.35.4
cis-1,2-Dichloroethene ND ug/1 500 1000 06/04/02 . KTV 156·59·2 trans-1,2-Dichloroethene ND ug/1 500 1000 06/04/02 KTV 156·60·5 I l.2·Dichloropropane ND ug/1 500 1000 06/04/02 KTV 78-87·5 l,3·Dichloropropane ND ug/1 500 1000 06/04/02 KTV 142·28·9 2,2·Dichloropropane ND ug/1 500 1000 06/04/02 KTV 594·20·7 I l.l·Dichloropropene ND ug/1 500 1000 06/04/02 KTV 563-58·6 cis-1,3-Dichloropropene ND ug/l 500 1000 06/04/02 KTV 10061-01·5 trans-1,3-Dichloropropene ND ug/l 500 1000 06/04/02 KTV 10061·02·6 I Diisopropyl ether ND ug/1 500 1000 06/04/02 KTV 108-20·3 Ethyl benzene ND ug/1 500 1000 06/04/02 KTV 100-41·4 Hexachloro-1,3-butadiene ND ug/l 2000 1000 06/04/02 KTV 87·68·3 Isopropylbenzene (Cumene) ND ug/1 500 1000 06/04/02 KTV 98·82·8 I p·Isopropyltoluene ND ug/1 1000 1000 06/04/02 KTV 99-87·6 Methylene chloride 8200 ug/l 2000 1000 06/04/02 KTV 75·09·2 Methyl-tert·butyl ether ND ug/1 500 1000 06/04/02 KTV 1634-04·4 I Naphthalene ND ug/l 2000 1000 06/04/02 KTV 91·20·3 n·Propylbenzene ND ug/1 500 1000 06/04/02 KTV 103-65·1 Styrene ND ug/1 500 1000 06/04/02 KTV 100-42-5
l,l,l,2·Tetrachloroethane ND ug/1 500 1000 06/04/02 KTV 630-20·6 I l,l,2,2·Tetrachloroethane ND ug/1 500 1000 06/04/02 KTV 79.34.5
Tetrachloroethene ND ug/1 500 1000 06/04/02 KTV 127-18·4
Toluene ND ug/1 500 1000 06/04/02 KTV 108·88·3 I 1.2,3-Trichlorobenzene ND ug/1 2000 1000 06/04/02 KTV 87·61·6 1,2,4-Trichlorobenzene ND ug/1 2000 1000 06/04/02 KTV 120-82·1 1,1,l•Trichloroethane ND ug/1 500 1000 06/04/02 _KTV 71.55.5 I
Date: 06/29/02 Page; 116
I
Laboratort Certification IDs REPORT OF LABORATORY ANALYSIS Laboratory Certification IDs I NC Wastewater 12 LA Wastewater 04034
NC Drinking Water 37706 This report shall not be reproduced, except in full, VA Drinking Water 213
SC 99006 without the written consent of Pace Analytical Services, Inc. FL NELAP E87627 I ~ loel· 01
I
ace Analyticar·
www.pacelabs.com
Lab Sample No: 922293329
Client Sample ID: MW-37
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Lab Project Number: 9233015
Phone: [phone]
Fax: [phone]
Client Project JD: NCSU Lot 86/2246
Project Sample Number: 9233015-054 Date Collected: 05/30/02 09:00
Hatri x: Water Date Received: 05/30/02 _16: 15
••
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I
Parameters Results Units ReQort Limit _QE._ Analyzed By CAS No. Q!§L RegLmt
I
1,1.2-Trichloroethane
Tri chl oroethene
Trichlorofluorometh~ne
1.2,3-Trichloropropane
✓ ,', ' 1, 2. 4 · Tri methyl.benzene
1, 3. 5. Trjme):.hyl benzene
Vinyl _chloride , • ✓
rn&p-Xylene
I /<{;xylene
,:;1.-"'i-Chl oro-3-fl uorobenzene (S)
I'; ..
)'
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I
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
ND ug/1 500 1000 06/04/02
1200 ug/1 500 1000 06/04/02
ND ug/1 500 1000 06/04/02
ND ug/1 500 1000 06/04/02
ND ug/1 500 1000 06/04/02
ND ug/1 500 1000 06/04/02
ND ug/1 500 1000 06/04/02
ND ug/1 500 1000 06/04/02
ND ug/1 500 1000 06/04/02
98 t 1. 0 06/04/02
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,~ AC~o~ -~ ?iOt!!a61
KTV 79-00-5'
KTV 79-01·6
. KTV 75-69·4
KTV 96· 18·4
KTV 95-63·6
KTV 108-67-8
KTV 75-01·4
KTV
KTV 95-47·6
KTV 625-98·9
Page: 117
Laboratory Certification IDs
LA Wastewater 04D34
VA Drinking Water 213
FL NELAP E87627
ace Analytical™
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone] www.pacelabs.com
Lab Project Number: 9233015
_Lab Sample No: 922293337
Client Sample ID: F8-2
Parameters
Metals
Metals by Trace ICP
Arsenic
Barium
Cadmium
Chromium
Lead ✓~:' ;. ,, ',.
Results
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-055
Matrix: Water
Date Collected: 05/29/02 16:00
Date Received: 05/30/02 16:15
Units Report Limit ..QE.._ ----"'An,,,a,_,l,1..VZe,ea,adc.___e.8yL. _ _,C"'A"-S_:_N,,,o~. _ Q!!tl_ RegLmt
Prep/Method: EPA 3010 / EPA 6010
ND mg/1 0.0050
ND
ND
ND
ND
ND
ND
ND
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
0.0050
0.0010
0.0020
0.0050
0.0050
0.0050
0.0020
1.0 06/11/02 18:38 DJR 7440-38-2
1.0 06/11/02 18:38 DJR 7440-39-3
1.0 06/11/02 18:38 DJR 7440-43-9
1.0 06/11/02 18:38 DJR 7440-47-3
1.0 06/11/02 18:38 DJR 7439-92-1
1.0 06/11/02 18:38 DJR 7439-96-5
1.0 06/11/02 18:38 DJR 7782-49-2
1.0 06/11/02 18:38 DJR 7440-22-4
Manganese
/,s-~ie·~ium
,,,,:,;.,.:,,:"§"; l ver ,,;_;:> Date Digested 06/04/02
I
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.,
Mercury. CVMS. in Water
Mercury
Wet Chemistry
Ion Chromatography
Chloride
Nitrate
Sulfate
Alkalinity. Total
Alkalinity. Total
GC Volatiles
GC voes in Water
Benzene
Bromobenzene
8romochloromethane
Broroodi ch_l oromethane
Bromoform
Bromomethane
n-Butyl benzene
sec-Butyl benzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
Method: EPA 7470
ND mg/1
Method: EPA 300.0
ND mg/1
ND mg/1
ND mg/1
Method: EPA 310.1
5.0 mg/1
Method: SM 6230D
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
0.00020 1.0 06/03/02 LBG 7439-97-6
1.0
0.10
1.0
1.0
0.50
0.50
0.50
0.50
0.50
0.50
1.0
0.50
0.50
0.50
0.50
0.50
0.50
1.0 05/31/02
1.0 05/31/02
1.0. 05/31/02
1.0 06/05/02
CDE 16887-00-6
CDE
CDE
HEH
1.0 06/05/02 00:18 KTV 71-43-2
1.0 06/05/02 00:18 KTV 108-86-1
1.0 06/05/02 00:18 KTV 74-97-5
1.0 06/05/02 00:18 KTV 75-27-4
1.0 06/05/02 00:18 KTV 75-25-2
1.0 06/05/02 00:18 KTV 74-83-9
1.0 06/05/02 00:18 KTV 104-51-8
1.0 06/05/02 00:18 KTV 135-98-8
1.0 06/05/02 00:18 KTV 98-06-6
1.0 06/05/02 00:18 KTV 56-23-5
1.0 06/05/02 00:18 KTV 108-90-7
1.0 06/05/02 00:18 KTV 75-00-3
1.0 06/05/02 00:18 KTV 67-66-3
Page: 118
REPORT OF LABORATORY ANALYSIS Laboratory Certification IDs I
LA Wastewater 04034 This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc. VA Drinking Water 213
FL NELAP E87627 I
I
I
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I
ace Analytical™
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28018
Phone: [phone]
Fax: [phone] www.pacelabs.com
Lab Sample No: 922293337
Client Sample ID: FB-2
Lab Project Number: 9233015
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-055
Matrix: Water
Date Collected: 05/29/02 16:00
Date Received: 05/30/02 16:15
Parameters Results Units
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
Reoort Limit _lli:...._ Analyzed By CAS No.
I
I
Chl oromethane
2-Chlorotoluene
4-Chlorotoluene
1.2-Dibromo-3-chloropropane
Di bromochl oroniethii.ne
1.2-Dibromci~th~~e (EDS)
Di bromo!ll~.tn;ne
1,2-Dichlorobenzene / . .it:/ ,,,-1; 3 -Di chl orobenzene I /✓;-····l.4-Dichlorobenzene ,· /
., ,.,. _.,P Dichlorodifluoromethane
~-·· 1. 1-Dichloroethane
1.2-Dichloroethane I
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1.1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1.3-Dichloropropene
trans-1.3-Dichloropropene
Diisopropyl ether
Ethyl benzene
Hexachloro-1,3-butadiene
lsopropylbenzene (Cumene)
p-lsopropyltoluene
Methylene chloride
Methyl-tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1.1.1,2-Tetrachloroethane
1.1.2.2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
.l,2,4-Trichlorobenzene
1.1,1-Trichloroethane
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2.0 1.0 06/05/02 00:18 KTV 74-87-3
0.50 1.0 06/05/02 00:18 KTV 95-49·8
0.50 1.0 06/05/02 00:18 KTV 106-43-4
2.0 1.0 06/05/02 00:18 KTV 96-12·8
0.50 1.0 06/05/02 00:18 KTV 124-48-1
0.50 1.0 06/05/02 00:18 KTV 106-93-4
0.50 1.0 06/05/02 00:18 KTV 74-95-3
1.0 1.0 06/05/02 00:18 KTV 95-50-1
1.0 1.0 06/05/02 00:18 KTV 541-73-1
1.0 1.0 06/05/02 00:18 KTV 106-46-7
0.50 1.0 06/05/02 00:18 KTV 75-71-8
0.50 1.0 06/05/02 00:18 KTV 75-34-3
0.50 1.0 06/05/02 00:18 KTV 107-06·2
0.50 1.0 06/05/02 00:18 KTV 75-35-4
0.50 1.0 06/05/02 00:18 KTV 156-59-2
0.50 1.0 06/05/02 00:18 KTV 156-60-5
0.50 1.0 06/05/02 00:18 KTV 78-87-5
0.50 1.0 06/05/02 00:18 KTV 142-28-9
0.50 1.0 06/05/02 00:18 KTV 594-20-7
0.50 1.0 06/05/02 00:18 KTV 563-58-6
0.50 1.0 06/05/02 00:18 KTV 10061-01-5
0.50 1.0 06/05/02 00:18 KTV 10061-02-6
0.50 1.0 06/05/02 00:18 KTV 108-20-3
0.50 1.0 06/05/02 00:18 KTV 100-41·4
2.0 1.0 06/05/02 00:18 KTV 87-68-3
0.50 1.0 06/05/02 00:18 KTV 98-82-8
1.0 1.0 06/05/02 00:18 KTV 99-87-6
2.0 1.0 06/05/02 00:18 KTV 75-09-2
0.50 1.0 06/05/02 00:18 KTV 1634-04-4
2.0
0.50
0.50
0.50
0.50
0.50
0.50
2.0
2.0
0.50
1.0 06/05/02 00:18 KTV 91-20-3
1.0 06/05/02 00:18 KTV 103-65-1
1.0 06/05/02 00:18 KTV 100-42-5
1.0 06/05/02 00:18 KTV 630-20-6
1.0 06/05/02 00:18 KTV 79-34-5
1.0 06/05/02 00:18 KTV 127-18-4
1.0 06/05/02 00:18 KTV 108-88-3
1.0 06/05/02 00:18 KTV 87-61-6
1.0 06/05/02 00:18 KTV 120-82-1
1.0 06/05/02 00:18 KTV 71-55-6
P11ge: 119
REPORT OF LABORATORY ANALYSIS Laboratory Certification IDs
LA Wastewater 04034 This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,11 "ceo,.
{?'Cf_ K.°'¾-, !int:1aC1l
VA Drinking Water 213
FL NELAP EB7627
ace Analytical™
www.pacelabs.com
Lab Sample No: 922293337
Client Sample ID: FB-2
~Pa~r,,,am,,,e"'te~r~s--------c'~--"'-'-'Res,so,u-"lt""s'---Units 1.1.2-Trichloroethane. · ND ug/1
Trichloroethene ND ug/1
Trichlorofluoromettiarie · ND ug/1
1.2,3-Trichloropropane ND ug/1
1.2,4-Trimethylb~~zene ND ug/1
1,3,5-Trimethyibenzene ND ug/1
Vinyl.chloride ND ug/1
m&p-Xyl.;-ne ND ug/1
""'Xylene ND ug/1
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Lab Project Number: 9233015 ,
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-055
Matrix: Water
Date Collected: 05/29/02 16:00
Date Received: 05/30/02 16:15
ReQQrt Limit ....!1L Anal lZed B~ CAS No. !l!!ll.. RegLmt
0,50 1.0 06/05/02 00:18 KTV 79-00-5
0.50 1.0 06/05/02 00:18 KTV 79-01-6
0.50 1.0 06/05/02 00:1B KTV 75-69-4
0.50 1.0 06/05/02 00:18 KTV 96-1B-4
0,50 1.0 06/05/02 00:1B KTV 95-63-6
0.50 1.0 06/05/02 00:18 KTV 108-67-8
0.50 1.0 06/05/02 00:18 KTV 75-01-4
0.50 1.0 06/05/02 00:18 KTV
0.50 1.0 06/05/02 00:18 KTV 95-47-6 ,✓ .,., _,,,"_:;··· 1-Chloro-3-fluorobenzene (S) 101 X 1.0 06/05/02 00:18 KTV 625-98-9
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;.,.Y
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
\J ACco4 --~-?/IJ~C\\
Page: 120
Laboratory Certification IDs I
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627 I
I Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100 ace Analytical™ Huntersville, NC 28078
I Phone: [phone] www.pacelabs.com
Lab Project Number: 9233015 Fax: [phone]
Client Project ID: NCSU Lot 86/2246
I Lab Sample No: 922293345 Project Sample Number: 9233015-056 Date Collected: 05/29/02 00:00 ·'°i ¼' Client Sample ID: TRIP BLANK 05/29 Matrix: Water Date Received: 05/30/02 16:15 ..
I Parameters ; / Results Units ReQQrt Limit Jlf_ Anal }'.Zed B~ CAS No. g!!tl._ Reglmt
GC Volatiles
GC VOCs in Water Method: SM 62300 I Benzene NO ug/1 0.50 I. 0 06/04/02 KTV 71-43-2
Bromobenzene NO ug/1 0.50 I. 0 06/04/02 KTV 108·86-l ' Brmoochl oromethane NO ug/1 0.50 I. 0 06/04/02 KTV 74.97.5
I Bronodi ch lrirolTlethane NO ug/1 0.50 1.0 06/04/02 KTV 75-27-4
Broioofor~. ,.--NO ug/1 0.50 I. 0 06/04/02 KTV 75-25-2
Bromolllethane ND ug/1 0.50 I. 0 06/04/02 KTV 74-83-9 _,·. ,-
1.0 1.0 06/04/02 An;Butyl benzene ND ug/1 KTV 104-51-8 I . ..C:::· -'sec-Butyl benzene NO ug/1 0.50 1.0 06/04/02 KTV 135-98-8
.· .. / tert-Butylbenzene ND ug/1 0.50 I. 0 06/04/02 KTV 98-06-6
[:,· Carbon tetrachloride ND ug/1 0.50 I. 0 06/04/02 KTV 56-23-5 I Chlorobenzene NO ug/1 0.50 . J. 0 06/04/02 KTV 108-90-7
Chloroethane NO ug/1 0.50 I. 0 06/04/02 KTV 75-00-3
Chloroform ND ug/1 0.50 I. 0 06/04/02 KTV 67-66-3
I Chloromethane NO ug/1 2.0 1.0 06/04/02 KTV 74-87-3
2-Chlorotoluene ND ug/1 0.50 I. 0 06/04/02 KTV 95-49-8
4-Chlorotoluene NO ug/1 0.50 I. 0 06/04/02 KTV 106-43-4
1.2-0ibromo-3-chloropropane ND ug/1 2.0 1.0 06/04/02 KTV 96-12-8 I Dibromochlorornethane ND ug/1 0.50 I. 0 06/04/02 KTV 124-48-1
1.2-Dibromoethane (EDB) ND ug/1 0.50 1.0 06/04/02 KTV 106-93-4
Di bromomethane NO ug/1 0.50 I. 0 06/04/02 KTV 74.95.3
I 1,2-Dichlorobenzene ND ug/1 1.0 I. 0 06/04/02 KTV 95-50-1
1,3-Dichlorobenzene NO ug/1 1.0 I. 0 06/04/02 KTV 541-73-1
1.4-Dichlorobenzene NO ug/1 1.0 I. 0 06/04/02 KTV 106·46·7
I Dichlorodifluoromethane ND ug/1 0.50 I. 0 06/04/02 KTV 75-71-8
1.1-Dichloroethane NO ug/1 0.50 I. 0 06/04/02 KTV 75.34.3
1.2-Dichloroethane NO ug/1 0.50 I. 0 06/04/02 KTV 107-06-2
1,l·Dichloroethene ND ug/1 0.50 I. 0 06/04/02 KTV 75.35.4
I cis-1.2-0ichloroethene ND ug/1 0.50 1.0 06/04/02 KTV 156-59-2
trans-1.2-0ichloroethene NO ug/1 0.50 I. 0 06/04/02 KTV 156-60-5
1.2-0ichloropropane ND ug/1 0.50 1.0 06/04/02 KTV 78-87-5
I 1.3-Dichloropropane NO ug/1 0.50 1.0 06/04/02 KTV 142-28-9
2.2-0ichloropropane NO ug/1 0.50 1.0 06/04/02 KTV 594-20-7
l,l·Oichloropropene NO ug/1 0.50 1.0 06/04/02 KTV 563·58-6
cis-1.3-0ichloropropene ND ug/1 0.50 I. 0 06/04/02 KTV !0061-01-5 I trans-I. 3-Di chl oropropene NO ug/1 0.50 1.0 06/04/02 KTV 10061-02-6
Diisopropyl ether ND ug/1 0.50 1.0 06/04/02 KTV 108-20-3
Ethyl benzene ND ug/1 0.50 I. 0 06/04/02 KTV 100-41-4
I
Date: 06/29/02
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Page: 121
I LabQratQry CertificatiQn ID, REPORT OF LABORATORY ANALYSIS Laboratory Certification IDs
NC Wastewater 12 LA Wastewater 04034
NC Drinking Water 37706 This report shall not be reproduced, except in full, VA Drinking Water 213
SC 99006 without the written consent of Pace Analytical Services, Inc. FL NELAP E87627 I 111 HC04 ~ •')la" fine· 01
Pace Analytical Services, Inc.
ace Analytical™ 9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone] www.pacelabs.com
Lab Project Number: 9233015 Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Lab Sample No: 922293345 ·-' , .. :, ~. Project Sample Number: 9233015-056 Date Collected: 05/29/02 00: 00 Client Sample ID: TRIP BLANK 05/29 -:-· Matrix: Water Date Received: 05/30/02 16: 15
Parameters Results Units Renart Limit .JlL Analyzed By CAS No. 9l!il_ RegLmt Hexachloro-1,3-butadiene· ND u~/1 ,· 1 sopropy 1 benzene ( Cu_mene_) ND ug/1
2.0 1.0 06/04/02 KTV 87-68-3
0,50 1.0 06/04/02 KTV 98-82-8
p-lsopropyltoluene _ ,, ND ug/1 1.0 1.0 06/04/02 KTV 99-87-6
Methylene chlocide ND ug/1 2.0 1.0 06/04/02 KTV 75-09-2
Methyl -tert-btityl' ether ND ug/1 0.50 1.0 06/04/02 KTV 1634-04-4
Naphthalene _ _-,-ND ug/1 2.0 1.0 06/04/02 KTV 91-20-3
n-Propyl.beiiZene ND ug/1 0.50 1.0 06/04/02 KTV 103-65-1
Styrene ND ug/1
,,()'; 1'.i, 2-Tetrachl oroethane ND ug/1
0.50 1.0 06/04/02 KTV 100-42-5
0.50 1.0 06/04/02 KTV 630-20-6 1 :.r h' 1, 1, 2 .2-Tetrachloroethane ND ug/1 0.50 I. 0 06/04/02 KTV 79-34-5 -,,✓ ·<··· Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1.1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1.2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
m&p-Xylene
o-Xylene
1-Chloro-3-fluorobenzene (S)
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
ND ug/1 0.50 I. 0 06/04/02
ND ug/1 0.50 1.0 06/04/02
ND ug/1 2.0 I. 0 06/04/02
ND ug/1 2.0 I. 0 06/04/02
ND ug/1 0.50 I. 0 06/04/02
ND ug/1 0.50 I. 0 06/04/02
ND ug/1 0.50 I. 0 06/04/02
ND ug/1 0.50 I. 0 06/04/02
ND ug/1 0.50 I. 0 06/04/02
ND ug/1 0,50 I. 0 06/04/02
ND ug/1 0.50 I. 0 06/04/02
ND ug/1 0.50 I. 0 06/04/02
ND ug/1 0.50 I. 0 06/04/02
ND ug/1 0,50 1.0 06/04/02
96 t 1.0 06/04/02
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,. •cco'1 '~~ fine1:;::-C\s .. L _ let ·"
KTV 127-18-4
KTV 108-88-3
KTV 87-61-6
KTV 120-82-1
KTV 71-55-6
KTV 79-00-5
KTV 79-01-6
KTV 75-69-4
KTV 96-18-4
KTV 95-63-6
KTV 108-67-8
KTV 75-01-4
KTV
KTV 95-47-6
KTV 625-98-9
Page: 122
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking W_ater 213
FL NELAP E87627
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ace Analytical™
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone] www.pacelabs.com Lab Project Number: 9233015
I
Lab Sample No: 922293386
Client Sample ID, MW-17
Parameters
Metals
Metals by Trace ICP
Arsenic
Barium
Cadmium
Chromium ,'
Lead ·:/
Mangai,eie . ,
I /.~e leni um
,,./ ./Silver
. _'.·./ Date Digested
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Mercury, CVMS, in Water
Mercury
Wet Chemistry
Ion Chromatography
Chloride
Nitrate
Sulfate
Alkalinity. Total
Alkalinity, Total
GC Volatiles
GC VOCs in Water
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n•Butylbenzene
sec-Butyl benzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-057
Matrix: Water
Date Collected: 05/30/02 08:45
Date Received: 05/30/02 16:15
Results Units Report Limit ..QE__ Analyzed By CAS No.
Prep/Method: EPA 3010 / EPA 6010
0.0079 mg/1
0 .13 mg/1
ND mg/1
0.022 mg/1
0.022 mg/l
1.2 mg/1
ND mg/l
ND mg/l
Method: EPA 7470
0.00027 mg/1
Method: EPA 300.0
0.0050
0.0050
0.0010
0.0020
0.0050
0.0050
0.0050
0.0020
0.00020
1.0 06/11/02 19:35 DJR 7440•38·2
1.0 06/11/02 19:35 DJR 7440·39·3
1.0 06/11/02 19:35 DJR 7440·43·9
1.0 06/11/02 19:35 DJR 7440·47·3
1.0 06/11/02 19:35 DJR 7439·92·1
1.0 06/11/02 19:35 DJR 7439·96·5
1.0 06/11/02 19:35 DJR 7782·49·2
1.0 06/11/02 19:35 DJR 7440·22·4
06/04/02
1. 0 06/03/02 LBG 7439·97·6
3.7 mg/1
0.39 mg/1
1.0
0.10
1.0
1.0 05/30/02
I. 0 05/30/02
I. 0 05/30/02
COE 16887-00·6
COE
1.0 mg/1
Method: EPA 310.1
5.0 mg/1 1.0 I. 0 06/07 /02
Method: SM 62300
7400 ug/1 100 200 06/04/02
ND ug/l 10. 20. 0 06/04/02
ND ug/1 10. 20.0 06/04/02
ND ug/1 10. 20.0 06/04/02
ND ug/1 10. 20. 0 06/04/02
ND ug/1 10. 20.0 06/04/02
ND ug/l 20. 20.0 06/04/02
ND ug/l 10. 20.0 06/04/02
ND ug/1 10. 20.0 06/04/02
28. ug/l 10. 20. 0 06/04/02
ND ug/1 10. 20.0 06/04/02
ND ug/1 10. 20.0 06/04/02
190 ug/l 10. 20.0 06/04/02
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,J •Ceo,,
,s~-f/Ot::1<1C\'a
COE
HEH
KTV 71.43.2
KTV 108·86·1
KTV 74.97.5
KTV 75·27•4
KTV 75-25·2
KTV 74-83·9
KTV 104·51·8
KTV 135·98·8
KTV 98·06·6
KTV 56-23·5
KTV 108·90·7
KTV 75-00·3
KTV 67·66·3
Page: 123
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
ace Analyticar·
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone] www.pacelabs.com
Lab Sample No: 922293386
Client Sample ID: HW-17
Lab Project Number: 9233015
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-057
Matrix: Water
Date Collected: 05/30/02 08:45
Date Received: 05/30/02 16:15
Parameters Results Units
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
Report Limit ...QE_ Analyzed By CAS No. ~ RegLmt Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1.2-Dibromo-3-chloropropane
Di bromochl oram'kU,ane
I. 2-Di brO,l!IO.ith;ne (EDS)
Di bromolnettiane . ~ ,.
1;., 2 ~,9.fch l orobenzene
/1.3:Dichlorobenzene
, .. ;-'
,./;/ 1.4-Dichlorobenzene /f ,../ Di chl orodi fl uorornethane
..,-l.l·Dichloroethane
1.2-Dichloroethane
1.1-Dichloroethene
cis-1.2-~ichloroethene
trans-1.2-Dichloroethene
1.2-Dichloropropane
1.3-Dichloropropane
2.2-Dichloropropane
1.l·Dichloropropene
cis-1.3-Dichloropropene
trans-1,3-0ichloropropene
Diisopropyl ether
Ethyl benzene
Hexachloro-1,3-butadiene
Isopropylbenzene (Cumene)
p-Isopropyltoluene
Methylene chloride
Methyl-tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1.l.1.2·Tetrachloroethane
1.1.2.2-Tetrachloroethane
Tetrachloroethene
Toluene
1.2.3-Trichlorobenzene
1,2.4-Trichlorobenzene
1.1.l·Trichloroethane
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
ND
ND
ND
ND
ND
28.
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
31.
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
68.
ND
ND
ND
ND
ND
ND
ND
19.
ND
ND
ND
40. 20.0 06/04/02
10.
10.
40.
JO.
10.
JO .
20.
20.
20.
JO.
JO.
10.
JO.
JO.
10.
JO.
10.
10.
10.
10.
10·.
10.
JO.
40.
10.
20.
40.
JO.
40.
10.
JO.
10.
10.
10.
10.
40.
40.
JO.
20.0 06/04/02
20.0 06/04/02
20.0 06/04/02
20.0 06/04/02
20.0 06/04/02
20.0 06/04/02
20.0 06/04/02
20.0 06/04/02
20.0 06/04/02
20.0 06/04/02
20.0 06/04/02
20. 0 06/04/02
20.0 06/04/02
20.0 06/04/02
20.0 06/04/02
20.0 06/04/02
20.0 06/04/02
20.0 06/04/02
20.0 06/04/02
20.0 06/04/02
20.0 06/04/02
20.0 06/04/02
20.0 06/04/02
20.0 06/04/02
20.0 06/04/02
20.0 06/04/02
20.0 06/04/02
20.0 06/04/02
20. 0 06/04/02
20.0 06/04/02
20.0 06/04/02
20.0 06/04/02
20.0 06/04/02
20.0 06/04/02
20.0 06/04/02
20. 0 06/04/02
20.0 06/04/02
20.0 06/04/02
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
~,;~fj~r
ffiO~C\\
KTV 74-87-3
KTV 95-49-8
KTV 106-43-4
KTV 96-12-8
KTV 124-48-1
KTV 106-93-4
KTV 74-95-3
KTV 95-50-1
KTV 541-73-1
KTV 106-46-7
KTV 75-71-8
KTV 75-34-3
KTV 107-06-2
KTV 75-35-4
KTV 156-59-2
KTV 156-60-5
KTV 78-87-5
KTV 142-28-9
KTV 594-20-7
KTV 563-58-6
KTV 10061-01·5
KTV 10061-02-6
KTV 108-20·3
KTV 100-41-4
KTV 87-68-3
KTV 98-82-8
KTV 99-87-6
KTV 75-09-2
KTV 1634-04-4
KTV 91-20-3
KTV 103-65-1
KTV 100-42-5
KTV 630-20·6
KTV 79-34-5
KTV 127-18-4
KTV 108-88-3
KTV 87-61-6
KTV 120-82·1
KTV 71-55-6
Page: 124
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
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ace Analytical'"
www.pacelabs.com
Lab Sample No: 922293386
Client Sample ID: MW-17
Parameters Results
1,1.2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichlorgpropane
1.2.4-Trimethylbenzene
1.3.5-Trimethylbenzene
Vinyl .chloride
m&p0Xyl~ne
ND
57.
ND
ND
ND
ND
ND
23.
Units
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Lab Project Number: 9233015
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-057 Date Collected: 05/30/02 08:45
Matrix: Water Date Received: 05/30/02 16:15
ReQQrt Limit ...QL Anal }'.Zed 8~ CAS No. ~ Reglmt
10. 20.0 06/04/02 KTV 79·00·5
10. 20.0 06/04/02 KTV 79-01-6
10. 20.0 06/04/02 KTV 75-69·4
10. 20.0 06/04/02 KTV 96-18-4
10. 20.0 06/04/02 KTV 95-63-6
10. 20.0 06/04/02 KTV 108-67-8
10. 20. 0 06/04/02 KTV 75-01•4
10. 20.0 06/04/02 KTV
/0:X.Ylene 1-::<> 1-Chloro-3-fluorobenzene (S)
ND ug/1 10. 20.0 06/04/02 KTV 95-47-6
102 t 1.0 06/04/02 KTV 625-98-9
I· ... . .
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: I
I
Date: 06/29/02
Laboratory Certification IDs
· NC Wastewater 12
NC Drinking Water 37706
SC 99006
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,,. •Ceo,.
~-~,
?1ne1c:1.c11
Page: 125
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
ace Analytical™
www.pacetabs.com
Lab Sample No: 922293394
Client Sample ID: MW-2 DISSOLVED.
Pace Analytical Services, Inc.
9800 Kincey Avenue. Suite 100
Huntersville. NC 28078
Lab Project Number: 9233015
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015·058
Matrix: Water
Date Collected: 05/30/02 10:00
Date Received: 05/30/02 16:15
Parameters Results Units Report Limit _QE__ Analyzed By CAS No. Metals
Dissolved Metals, Tra~e-lCP
Iron, Dissolved •.·
Date Digested __ · ·; ,
'
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
Prep/Method: EPA 3010 / EPA 6010
ND mg/1 0.050 1.0 06/16/02 13:25 DJR 7439-89-6
06/10/02
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
... 1/~~~ t/·1~,~ """ fiO~Clt
Page: 126
Laboratory Certification IDs
LA Wastewater D4034
VA Drinking Water 213
FL NELAP EB7627
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ace Analytical™
www.pacelabs.com
Lab Sample No: 922293402
Client Sample ID: MW-3 DISSOLVED.' ·._.
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Lab Project Number: 9233015
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-059
Matrix: Water
Date Collected: 05/30/02 10:20
Date Received: 05/30/02 16:15
Parameters Results Units Report Limit ...QL Analyzed By CAS No. Metals
Dissolved Metals, Trace ICP
Iron, Dissolved
Date Digested .
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
Prep/Method: EPA 3010 / EPA 6010
3.7 mg/1 0.050 1.0 06/16/02 13:29 DJR 7439-89·6
06/10/02
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,,. •cco•
<~, il□~C\\
Page: 127
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
ace Analytical™
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28018
Phone: [phone]
Fax: [phone]
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www.pacelabs.com
Lab Sample No: 922293410
Client Sampl'e ID: MW-6 DISSOLVED.
Parameters
Metals
Dissolved Metals, Trace ICP
Iron. Dissolved
Date Digested
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
Lab Project Number: 9233015
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015·060
Matrix: Water
Date Collected: 05/29/02 17:15
Date Received: 05/30/02 16:15
Results Units Report Limit _l)f__ Analyzed By CAS No. 9!!tl_ RegLmt
Prep/Method: EPA 3010 / EPA 6010
ND mg/1 0.050 1.0 06/16/02 13:34 DJR 7439-89-6
06/10/02
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,~ •cc0~
,,'/~&~ • ... f/l \I,, 'f,-
f/0 · C\1
Page: 128
Laboratory Certification IDs I
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627 I
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ace Analytical™
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone] www.pacelabs.com Lab Project Number: 9233015
Lab Sample No: 922293428
Client Sample ID: MW-8 DISSOLVED.
Parameters
Metals
Dissolved Metals. Trace l,CP
Iron. Dissolved
Date Digested
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
/ .
Results
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015·061
Matrix: Water
Date Collected: 05/29/02 16:50
Date Received: 05/30/02 16:15
Units Report Limit .JlL Analyzed By CAS No.
Prep/Method: EPA 3010 / EPA 6010
ND mg/1 0.050 1.0 06/16/02 13:05 DJR 7439-89·6
06/10/02
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,.,._ ACCq~ i~~~ I1oelaci1
Page: 129
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
ace Analytical™
www.pacelabs.com
Lab Sample No: 922293436
Client Sample ID: MW•8 DUP DISSOLVED.-·
Parameters Results Metals
Pace Analytical Services. Inc.
9800 Kincey Avenue. Suite 100
Huntersville. NC 28078
Lab Project Number: 9233015
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-062
Matrix: Water
Date Collected: 05/29/02 17:00
Date Received: 05/30/02 16:15
Units Report Limit _Q[__ Analyzed By CAS No.
Dissolved Metals, Trace ICP
Iron, Dissolved
Prep/Method: EPA 3010 / EPA 6010
ND mg/1 0.050
Date Digested
1.0 06/16/02 13:10 DJR 7439-89-6
06/10/02
<;:-:~(>
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f
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,~ •Ceo~ .-~-ff/l)t!laCr,
Page: 130
I
Laboratory Certification IDs I
LA Wastewater 04034
VA Drinking Water 213
FL NELAP EB7627 I
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ace Analytical™
www.pacelabs.com
Lab Sample No: 922293444 1). ;
Client Sample ID: MW-12 DISSOLVED
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Lab Project Number: 9233015
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-063
Matrix: Water
Date Collected: 05/30/02 12:00
Date Received: 05/30/02 16:15
Parameters Results Units Report Limit Jl.E...... Analyzed By CAS No. Metals
Dissolved Metals, Trace !CP
Iron. Dissolved
Date Digested
. ,·
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
Prep/Method: EPA 3010 I EPA 6010
NO mg/1 0.050 1.0 06/16/02 13:39 DJR 7439-89·6
06/10/02
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
~,o/~~
ff!D~C\\
Page: 131
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
/.
ace Analytical™
www.pacelabs.com
Lab Sample No: 922293451 /
Client Sample ID: MW-16 DISSOLVED_· ..
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Lab Project Number: 9233015
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-064
Matrix: Water
Date Collected: 05/30/02 08:30
Date Received: 05/30/02 16:15
Parameters Results Units Report Limit ..QL_ Analyzed By CAS No. Metals r-
Dissolved Metals. Trace ICP
Iron, Dissolved ,_::
Date Digested
,/
/<)·,,.,·
,,.:{)"
/_I,./
-( .. ,..-
./'
Prep/Method: EPA 3010 / EPA 6010
0.72 mg/1 0.050 1.0 06/16/02 13:44 DJR 7439-89-6
06/10/02
,,
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Oate: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
-~~•~•"•••••r, ,,n \' ~L -;'.
Page: 132
Laboratory Certification IDs I
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627 I
I
I
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I
ace Analytical™
www.pacelabs.com
Lab Sample No: 922293469
Client Sample ID: HW-17 DISSOLVED
\"
Parameters Results
Metals
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Lab Project Number: 9233015
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-065
Matrix: Water
Date Collected: 05/30/02 08:45
Date Received: 05/30/02 16:15
Units Report Limit JlL Analyzed By CAS No.
Dissolved Metals. Trace ·1cp
Iron. Dissolved
Prep/Method: EPA 3010 / EPA 6010
ND mg/1 0.050
Date Digested
1.0 06/16/02 14:03 DJR 7439-89-6
06/10/02
1::-::-·
P': •
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Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,~ ~cea-t
~-./~-ff1n~aC1\
Page: 133
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
ace Analytical™
www.pacelabs.com
Lab Sample No: 922293477
Client Sample ID: MW-36S DISSO~VED:
Parameters Results Metals
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Lab Project Number: 9233015
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-066
Matrix: Water
Date Collected: 05/30/02 09:30
Date Received: 05/30/02 16:15
Units Report Limit ..Qf_ Analyzed By CAS No.
Dissolved Metals. Trace 'ICP
I ran, Dissolved
Prep/Method: EPA 3010 / EPA 6010
ND mg/1 0.050
Date Digested
Date: 06/29/02
1.0 06/16/02 14:08 DJR 7439-89-6
06/10/02
Page: 134
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Laboratory Certification IDs
NC Wastewater 12 REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Laboratory Certification IDs I
LA Wastewater 04034 NC Drinking Water 37706
SC 99006
,~ •ce0• .... ~~ ... <'/1 ·1·">,· ', •cc f/neaC\\
VA Drinking Water 213
FL NELAP E87627 I
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ace Analytical™
www.pacelabs.com
Lab Sample No: 922293485
Client Sample ID: MW-37 DISSOLVED
/; :','
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Lab Project Number: 9233015
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-067
Matrix: Water
Date Collected: 05/30/02 09:00
Date Received: 05/30/02 16:15
Parameters Results Units. Report Limit .JlL_ -~An=•~l~yz~e~d-~B~y CAS No. Metals
Dissolved Metals. Trace I_CP
Iron, Dissolved
Date Digested
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
Prep/Method: EPA 3010 / EPA 6010
ND mg/1 0.050 1.0 06/16/02 14:13 DJR 7439-89-6
06/10/02
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
i" •Ho~ ,~~ 11nelaci
Page; 135
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
ace Analytical™
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
I
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www.pacelabs.com
Lab Project Number: 9233015
Lab Sample No: 922293493
Client Sample ID: FB-2 DISSOLVED. I.
Parameters
Metals
Dissolved Metals. Trace ICP
Iron. Dissolved
Date Digested.
Oate: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC D(1nking Water 37706
SC 99006
Client Project ID: NCSU Lot 86/2246
Project Sample Number: 9233015-068
Matrix: Water
Date C9llected: 05/29/02 16:00
Date Received: 05/30/02 16:15
Results Units Report Limit .J![_ Analyzed By CAS No.
Prep/Method: EPA 3010 / EPA 6010
ND mg/1 0.050 1.0 06/16/02 13:15 DJR 7439-89-6
06/10/02
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,~ •Ceo.,
.,,~,.. .. t1nelaci\
Page: 136
Laboratory Certification IDs I
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627 I
'
I
I
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I
ace Analyticar
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone] www.pacelabs.com Lab Project Number: 9233015
Client Project ID: NCSU Lot 86/2246
PARAMETER FOOTNOTES
·,./
Dilution factor .shown represents the factor applied to the reported result and reporting limit due to changes ;
in sample prep~rat~on, dilution of the extract. or moisture content
ND ·Not detected at or above adjusted reporting limit
NC Not Calculable
J
MDL
(Sl
' .r Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit
Adj~stia'd Method Detection Limit ·
"/ . ~-~,urrogate
[l) . ✓Analyte is found in the associated blank as well as in the sample (CLP B·Flag).
•. <>· ./ ,.
.•·
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Oate: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
. without the written consent of Pace Analytical Services, Inc.
,~ •ee.,~
,-1~-?iO~aC\t
Page: 137
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
I
I ace Analyticat
wmv.pacelabs.com
I
I Lab Sample No: 922276217
Client Sample ID: MW-34S I Parameters
Wet Chemistry
Results
Pac• Analytlcal SBtvlCBl, Inc.
54 RavenSCIOff Drive
Asheville, NC 28801
Phone: [phone]
Fax: [phone]
Lab Project Number: 9329483
Client Project ID: PIEDMONT GEOLOGIC -9233015
Project Sample Number: 9329483-001
Matrix: Water
Units Report Limit Analyzed By
Date Collected: 05/20/02 17:30
Date Received: 05/21/02 14:10
_,CA.,,,,_s_.N,,,oc.-_ 2l!tl_ ~
Total Organic Carbon I Total Organic Carbon
Method: SM 5310C
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Date: 06/11/02
l aboratorv Certification IDs
NC Wastewater 40
NC Drinkino Water 37712
5.4 mg/1 0.50 05/29/02 EWS 7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Page: 1
Laboratory Certification ms
TN Drinklno Water 02980
SC Environmental 99030
aceAnalyticar
www:pacelabs.com
Lab Sample No: 922276225
Client Sample ID: MW-34D
Parameters Results
Wet Chemistry
Pac• Analytics/ SBrviCBI, Inc.
54 /laK!flSCIOII Drive
Asheville, NC 2880.1
Phon6: 828.254.7116
Fax: [phone]
Lab Project Number: 9329483
Client Project ID: PIEDMONT GEOLOGIC -9233015
Project Sample Number: 9329483-002
Matrix: Water
Date Collected: 05/20/02 17:00
Date Received: 05/21/02 14:10
Units Report Limit _ _.An.,a.,l..,y,eze.,d,____.By'-'--_ __,CA"""S__,N,,,o,.. _ ~ ReqLmt
Total Organic Carbon
Total Organic Carbon
Method: SM S310C
Date: 06/11/02
Laboratory Certification IDs
NC Wastewater 40
NC Drinking Water 37712
2.1 mg/1 0.50 05/29/02 EWS 7440-U·0
Page1 2
REPORT OF LABORATORY ANALYSIS Laboratory Certification IDs
TN Drinking Water 02980 This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc. SC Environmental 99030
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I ace Analyticar
wvM.pacefabs.com
I
I Lab Sample No: 922282611
Client Sample ID: MW-13
I Parameters
Wet Chemistry
Results
Pac, Analytlcal Ssrvlces, Inc.
54 Ravooscroff DrilO
Asheville, NC 28801
Phone: [phone]
Fax: [phone]
Lab Project Nulllher: 9329183
Client Project ID: PIEDMONT GEOLOGIC -9233015
Project Sample Nulllher: 9329183-003
Matrix: Water
Date Collected: 05/22/02 10:51
Date Received: 05/23/02 16:10
Units Report Limit -~An=•~lY~•~e~d-~By~ ~CAS=~N=o~. _ ~ ReqLmt
Total Organic Carbon Method: SM 5310C
I Total Organic Carbon
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I Date: 06/11/02
l aboratorv Certification ms
NC Wastewater 40
NC Drinking Water 37712
I
3.0 mg/1 0.50 06/03/02 EWS 7110-11-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytlcal Services, Inc.
Pago: 3
Laboratory Certification IDs
TN Drinking Water 02980
SC Environmental 99030
www:pacelobS'.com
Lab Sample No: 9.2282629
Client Sample ID: MW-27
Parameters Results
Wet Chemistry
Pace Analytical SsrrlCBS, Inc.
54 Ravenscroft Ori"'
Ashen/le, NC 28801
Phone: [phone]
Fax: [phone]
Lab Project Number: 9329483
Client Project ID: PIEDMONT GEOLOGIC -9233015
Project Sample Number: 9329483-004
Matrix: Water
Date Collected: 05/22/02 12:43
Date Received: 05/23/02 16:10
Units Report Limit _ _.,,Ana,..,l""y"'ze.,d,___.By,.,_ _ _,CA.,,,,_s..,N,.,o~. _ ~ Reqtmt
Total Organic Carbon
Total Organic Carbon
Method: SM S310C
D.at111 06/11/02
Laboratory Certification ms
NC Wastewater 40
NC Drinking Water 37712
2,2 mg/1 0.50 06/03/02 EWS 7440-14-0
Page: &
REPORT OF LABORATORY ANALYSIS Laboratory Certification IDs
TN Drinking Water 02980 This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc. SC Environmental 99030
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aceAnalyticar
www.pacelabs.com
922282637
Client Sample ID: MW-35S
I Parameters
Wet Chemistry
Results
Pac• Analytical Ssrv/cos,. Inc.
54 Ra-..nscron Dri-..
Ashevill~ NC 28801
Phone: 828.254]116
Fax: 828,252.4618
Lab Project Number: 9329483
Client Project ID: PIEDMONT GEOLOGIC -9233015
Project Sample Number: 9329483-005
Matrix: Water
Date Collected: 05/22/02 12:23
Date Received: 05/23/02 16:10
units Renort Limit -~An-•"'-lv;..._.ed,,___.Bv"-~CA.,._s~N~oL. _ ~ ~
Total Organic carbon
Total Organic Carbon
Method: SM 5310C
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Date: 06/11102
Laboratory Certification IDs
NC Wastewater 40
NC Drinking Water 37712
1. 0 mg/1 0.50 06/03/02 EWS 7410-41-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
P11.;111 5
Laboratory Certification IDs
TN Drinking Water 02980
SC Environmental 99030
WlV\v.pacelabs.com
Lab Sample No: 9222a2G,s
Client Sample ID: MW-36D
Parameters Results
Wet Chemistry
Pac• Analytical Ssrvlcas,Jn,.
54 P.awscroll.Ori,o
Asheville, NC 28801
Phone: [phone]
Fax: [phone]
Lab Project Number: 9329483
Client Project ID: PIEDMONT GEOLOGIC -9233015
Project Sample Number: 9329483-006
Matrix: Water
Date Collected: 05/22/02 11:51
Date Received: 05/23/02 16:10
Units Report Limit _ _,,;Ane,ae,.lv,.,z~•~d_JBy~ ~CA=SJN~O~--~ ReqLmt
Total Organic Carbon
Total Organic Carbon
Method: SM 5310C
Datei: 06/11/02
Laboratory CertHkation IDs
NC Wastewater 40
NC Drinking Water 37712
ND mg/1 0.50 06/03/02 EWS 74'0-U-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Page: 6
Laboratory Certification ms
TN Drinking Water 02980
SC Environmental 99030
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I ace Anatyticar
WVIW. pace/abs. com
I
I Lab Sample No: 922282652
Client Sample ID: MW-40 I Parameters
Wet Chemistry
Results
Pac• Analytical S•tY1ca1,./nc.
541/Jvenscrott o,;.,
Asheville, NC 2880_1
Phone: [phone]
Fax: [phone]
Lab Project NUmber: 9329483
Client Project ID: PIEDMONT GEOLOGIC -9233015
Project Sample Number: 9329483-007
Matrix: Water
Date Collected: 05/22/02 11:ll
Date Received: 05/23/02 16:10
Units Report Limit -~An=•~lv;=•~d-~Bv~ ~CAS=~N~o~·-~ ~
I Total Organic Carbon
Total Organic Carbon
Method: SM 5310C
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Date: 06/11/02
l aboratorv Certification IDs
NC Wastewater 40
NC Drinking Water 37712
0.50 mg/1 0.50 06/0l/02 EWS 7440-'4-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full.
without the written consent of Pace Analytical Services, Inc.
,Page: 7
Laboratory Certification IDs
TN Drinking Water 02980
SC Environmental 99030
wvAv.paceiabs.com
Lab Sample No: 922282710
Client Sample ID: MW-41
Parameters
Wet Chemistry
Total Organic Carbon
Total Organic Carbon
Dato: 06/11/0l
laboratory Certification IDs
NC Wastewater 40
NC Drinking Water 37712
Pace Analytical SerYlces,.lnc.
54 Rawscron Dri'tfl
Asheville, NC 28801
Phone: [phone]
Fax: 828.252AS18
Lab Project Number: 9329483
Client Project ID: PIEDMONT GEOLOGIC -9233015
Project Sample Numher: 9329483-008
Matrix: Water
Date Collected: 05122/02 09:28
Date Received: 05/23/02 16:10
Results Units Report Lim.it -~An~•~l~v~•e~d~~By~ -~CA=S~N~o~, _ 2Y!l_ RegLmt
Method: SM 5310C
0,74 mg/1 0.50 06/03/02 EWS 7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Anatytlcal Services, Inc.
Page: 8
I aboratorv Certmcation ms
TN Drinking Water 02980
SC Environmen1al 99030
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aceAnatyticar
~Y.pacelabs.com
922282728
Client Sample ID: MW-411
I Parameters
Wet Chemistry
Results
Pac, Analytical S81Ylco1, Inc.
54 Ravensc,o// Drive
Asheville, NC 28801
Phone: [phone]
Fax: [phone]
Lab Project Number: 9329(83
Client Project ID: PIEDMONT GEOLOGIC -9233015
Project Sample Number: 9329483-009
Matrix: Water
Date Collected: 05/22/02 09:53
Date Received: 05/23/02 16:10
Units Report Limit _ _,,,An.,a,.lv,.,,,.,e,,.d_-'Bv"-'--~""=" ~•-9-, _ .Q:laL ReqLmt
I Total Organic Carbon
Total Organic carbon
Method: SM 5310C
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Date: 06/11/02
I aboratorv Certification IDs
NC Wastewater 40
NC Drinking Water 37712
0.82 mg/l 0.50 06/03/02 EWS 7140-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Pago1 9
Laboratory Certification IDs
TN Drinking Water 02980
SC Environmental 99030
-aceAnalyticar
www.J)8cetabs.com
Lab Sample No: 922282785
Client Sample ID: MW-421
Parameters Results
Wet Chemistry
Pacs Analytical Ssr,lcs1,./nc.
54 Ravenscroll Dri,s
Asheville, NC 28801
Phone: [phone]
Fax: 828.252:4618
Lab Project Number: 9329483
Client Project ID: PIEDMONT GEOLOGIC -9233015
Project Sample Number: 9329483-010
Matrix: Water
Date Collected: 05/22/02 10:23
Date Received: 05/23/02 16:10
Units Report Limit _ _,,,An.,a,.ly>'.Jze,ee.d _ _,B,_,y __ _,CA,,,,,S_,N,,,oc,_._ .QBtl.. RegLmt
Total Organic Carbon
Total Organic Carbon
Method: SM Sll0C
Date: 06111/0l
Laboratory Certification IDs
NC Wastewater 40
NC Drinking Water 37712
0.60 mg/1 o.so 06/03/02 EWS 7410-41-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Page: 10
Laboratory Certification ms
TN Drinking Water 02980
SC Environmental 99030
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ace Analytical"
WW\v.pacelabs.com
Lab Sample No: 922282793
Client Sample ID: MW-'3
Parallletera Result&
Wet Chemistry
Pac• Ana/ytlcsl Ssrv/cs1,.ln•.
54 RavenSCIOll Dri,o
A<;heiille, NC 28801
Phons: 828.254.7176
Fax: [phone]!18
· Lab Project Number:. 9329483
Client Project ID: PIEDMONT GEOLOGIC -9233015
Project Sample Number: 9329483-011
Matrix: water
Date Collected: 05/22/02 07:41
Date Received: 05/23/02 16:10
Unite Report Limit _ __,.An.,a .. 1y.,z,.e,cd _ _,By,,_ ~CA=S~N~o~, _ 2Y.li_ ~
Total Organic Carbon Method: SM 5310C
Total Organic Carbon
Date: 06/11/0:.1
l aboratorv Cerlification IDs
NC Wastewater 40
NC Drinking Water 37712
O.63 mg/1 0.50 06/03/02 EWS 7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Page: 11
laboratory Certification 10s
TN Drinking Water 02980
SC Environmental 99030
www.paceJabs.com
Lab Sample No: 922282801
Client Sample ID: MW-45
Parameters Results
Wet Chemistry
Pac, Analytic,/ s,rvtc,1, In•.
54 /lavenscrort Drive
Asheville. NC 281!()1
Phone: [phone]
Fax: [phone]S18
Lab Project Number: 9329483
Client Project ID: PIEDMONT GEOLOGIC -9233015
Project Sample Number: 9329483-012
Matrix: Water
Date collected: 05/22/02 08:21
Date Received: 05/23/02 16:10
Units Report Limit __ An=•~ly~•~•~d-~By~ ~CAS=~"°=·-.QyAL ReqLmt
Total Organic Carbon
Total Organic Carbon
Method: SM 5310C
Date: 06/11/02
L aboratorv Certification IDs
NC Wastewater 40
NC Drinking Water 37712
ND mg/1 0.50 06/03/02 EWS 7140-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except In full,
without the written conserit of Pace Analytical Services, Inc.
I aboratorv CertiUcation ms
TN Drinking Water 02980
SC Environmental 99030
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www.pacelabs.com
Lab Sample No: 922282819
Client Sample ID: MW-46
Parameters
Wet Chemistry
Total Organic Carbon
Total Organic Carbon
Date: 06/~l/O:Z
laboratory Certtlication IDs
NC Wastewater 40
NC Drinking Water 37712
Pac, Analytical Senlfcs,,./nc.
54 Ravenscroft Drive
Asheville, NC 28801
Phone: [phone]
Fix: 828.252:,1818
Lab Project Number: 9329483
Client Project ID: PIEDMONT GEOLOGIC -9233015
Results
Method: SM 5310C
Project Sample Number: 9329483-013
Matrix: Water
Qni tB Report Limit Ana,lyzed By
Date collected: 05/22/02 07:59
Date Received: 05/23/02 16:10
__,,CAS..,_-'N.,o~. _ lll!ll_ ReqLmt
0.64 mg/l 0.50 06/03/02 EWS 700-U-O
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Page: 13
laboratory Certification IDs
TN Drinking Water 02980
SC Environmental 99030
aceAnalyticar
m•1w:pace/abs.com
Lab Sample No: 922282959
Client Sample ID: FBMl
Parameters Results
Wet Chemistry
Paco Analytical Sorvlco• .. In,.
54 Ra>enscroft o,;,.
Asheville, NC 28801
Phone: [phone]
Fix: 828.252.4618
Lab Project Number: 9329483
Client Project ID: Pim!ON'l' GEOIDGIC M9233015
Project Sample Number: 9329483~014
Matrix: Water
Date Collected: 05/22/02 11:51
Date Received: 05/23/02 16:10
Units Report Limit _ _,,,An.,a .. ly.,,z~e~d-~By~ ~CA=S~N~o~, _ 21!!!_ ReqLmt
Total Organic Carbon
Total Organic Carbon
Method: SM 5310C
Date: 06/11/02
l aboratorv Certltication IDs
NC Wastewater 40
NC Drinking Water 37712
ND mg/1 0.50 06/03/02 EWS 7410·14-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Page1 U
I ahoratorv Certification 10s
TN Drinking Water 02980
SC Environmental 99030
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I wv,w.pacetabs.com
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I Lab Sample No: 922283007
Client Sample ID: 36D-DUP I Parameters
Wet Chemistry
I Total Organic Carbon
Total Organic carbon
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Date1 06/11/02
Laboratory Certification IDs
NC Wastewater 40
NC Drinking Water 37712
Pacs Analytical Ssmcss,,/nc.
54 Rawsaon Drive
Asheville, NC 28801
Phone: 828,2541176
Fax: 828,252,4618
Lab Project Number: 9329483
Client Project ID: PIEDMONT GEOLOGIC -9233015
Project Sample Number: 9329483-015
Matrix: Water
Date collected: 05/22/02 11:51
Date Received: 05/23/02 16:10
Results Qnits Report Limit __ An=•=lv~z=•=d-~By~ _;CA,,,._s_.,N"'o~. _ 2llAl_ Rear.mt
Method: SM 5310C
ND mg/1 0.50 06/03/02 EWS 7410-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Pagei 15
Laboratory Certification IDs
TN Drinking Water 02980
SC Environmental 99030
ace Analyticar
WMv.pacel.lbs.com
Lab Sample No: 922283015
Client Sample ID: MW-29
Parameters Results
Wet Chemistry
Pac, Analytlcal Serv/c,1,,/n,.
54 Ra""1SC!Oll Drive
Ashevill~ NC 28801
Phone: 828,2541176
Fax: 828,252,4618
Lab Project Number: 9329483
Client Project ID: PIEDMONT GEOLOGIC -9233015
Project Sample Number: 9329483-016
Matrix: Water
Date Collected: 05/22/02 11:11
Date Received: 05/23/02 16:10
Units Report Limit __ An,,.,,a~lv;,_._,,e,.d _ _.By,,__ _,,CA,,,,,_S .,,,Noco~. _ ~ ReqLmt
Total Organic Carbon
Total Organic Carbon
Method: SM 5310C
Date: 06/11/02
I aboratorv Certmcation IDs
NC Wastewater 40
NC Drinking Water 37712
ND mg/1 0.50 06/03/02 EWS 7140-14-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Page: 16
Laboratory Certification ms
TN Drinking Water 02980
SC Environmental 99030
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I Lab Sample No: 922285176
Client Sample ID: MW-11 I Parameters
Wet Chemistry
Total Organic Carbon I Total Organic Carbon
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I Date1 06/11/02
I t aboratorv Certification \Ps
NC Wastewater 40
NC Drinking Water 37712
I
Pac• Analytical Set¥/ce,, In<.
54 Ra""scron o,;..,
AsheWlle, NC 28801
Phone: [phone]
Fax: [phone]!18
Lab Project Number: 9329483
Client Project ID: PIEDMONT GEOLOGIC -9233015
Project Sample Number: 9329483-017
Matrix: Water
Date Collected: 05/23/02 11:30
Date Received: 05/24/02 13:55
Results Units Report Limit -~An!!!!!!a,o;lY>'.l•C!!•l!.4 _ _,By!L _,CA=S ~N~oL, _ 2l!!!_ ~
Method: SM 5310C
19. mg/1 o.so 06/03/02 EWS 7440-U-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Seivices, Inc.
Page: 11
Laboratory Certification IDs
TN Drinking Water 02980
SC Environmental 99030
c1ceAna/yticar
www.pacelaos.com
Lab Sample No: 922285184
Client Sample ID: MW-llI
Parameters Results
Wet Chemistry
Pac, Analytlr:a/ S1rvlc,1, lnr.
54 Ravenscroff Oriv,
AsheWlle, NC 28801
Phone: [phone]
Fax: [phone]
Lab Project Number: 9329483
Client Project ID: PIEDMONT GEOLOGIC -9233015
Project Sample Number: 9329483-018
Matrix: Water
Date Collected: 05/23/02 10:40
Date Received: 05/24/02 13:55
Units Report Limit _ __.An,.ao,lc,v..:ze.,d.__.s.,_y -...,CA.,,._S_JN,i;o,_. _ QJ.JAL RegLmt
Total Organic Carbon
Total Organic Carbon
Method: SM 5310C
Date: 06/11/02
Laboratory Certltication IDs
NC Wastewater 40
NC Drinking Water 37712
4.2 mg/1 0.50 06/03/02 EWS 7440-44-0
Page: 18
REPORT OF LABORATORY ANALYSIS Laboratory Certification IDs
TN Drinking Water 02980 This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc. SC Environmental 99030
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aceAnatyticar
www;pacelabs.com
Lab Sample No: 922285192
Client Sample ID: MW-121
parameters Results
Wet Chemistry
Paco Analytlcal Ssrrlcos,.fn<.
54 RavenscroMDrive
Asheville, NC 2811()1
Phone: [phone]
Fax: [phone]
Lab Project Number: 9329483
Client Project ID: PIEDMONT GEOLOGIC -9233015
Project Sample Number: 9329483-019
Matrix: Water
Units Report Limit Analyzed By
Date Collected: 05/23/02 09:40
Date Received: 05/24/02 13:55
_,CA""'-S _.,N""o~, _ QuL ReqLffit
Total Organic Carbon
Total Organic Carbon
Method: SM SJlOC
Date: 06/11/02
l aboratorv Certification IDs
NC Wastewater 40
NC Drinking Water 37712
l. l mg/1 0.50 06/03/02 EWS 7440-41-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Page: 19
Laboratory CertiUcation IDs
TN Drinking Water 02980
SC Environmental 99030
ww,v.pacelabs.rom
Lab Sample No: 922285200
Client Sample ID: MW-161
Parameters Results
Wet Chemistry
Pac• Analytlcal SBrflC8$, Inc.
54 Ravenscroff o,;.,.
Ashewlle, NC 28801
Phone: [phone]
Fax: [phone]
Lab Project Nwnber: 9329483
Client Project ID: PIEDMONT GEOLOGIC -9233015
Project Sample Number: 9329483-020
Matrix: Water
Date Collected: 05/23/02 08:30
Date Received: 05/24/02 13:55
Units Report Limit -~An...,,a,,_ly,..z.,.ed,.____.By"--~CA=S~N~o~. _ 2l:!!L RegLmt
Total Organic Carbon
Total Organic Carbon
Method: SM 5310C
Date: 06/11/02
Laboratory Certification IDs
NC Wastewater 40
NC Drinking Water 37712
ND mg/1 0.50 06/03/02 EWS 74'0·'4·0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Anatytical Services, Inc.
Pege: 20
t aboratocv Certilication ms
TN Drinking Water 02980
SC Environmental 99030
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I aceAnalyticar
wv,w.pacelabs.com
I
1· Lab Sample No: 922285218
Client Sample ID: MW-171
I Parameters
Wet Chemistry
Results
Pacs Analytical Ssrvlcss, Inc.
54 Flavenscroll o,; ..
Asheville, NC 28801
Phone: [phone]
Fax: [phone]
Lab Project Number: 9329483
Client Project ID: PIEDMONT GEOLOGIC -9233015
Project Sample Number: 9329483-021
Matrix: Water
Date Collected: 05/23/02 10:10
Date Received: 05/24/02 13:55
Units Report Lim.it -~An=•=lv~•~•=d-~»~v--~™=~N=o~, _ 2Y.!L ~
Total Organic Carbon
Total Organic Carbon
Method: SM 5310c I
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Date: 06/11/0l
I aboratorv Certification ms
NC Wastewater 40
NC Drinking Water 37712
0.86 mg/1 0.50 06/03/02 EWS 7440-U-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Page; ll
Laboratory Certification IDs
TN Drinking Water 02980
SC Environmental 99030
aceAnalyticar
www;pacetabs.com
Lab Sample No: 922285226
Client Sample ID: MW-38
parameters Results
Wet Chemistry
Pac, Analytical SBrvfCBJ,.lnc.
54 llii•111Scroll o,;,.
Asheville, NC 28801
Phone: [phone]
Fax: 828.252 . ./otB
Lab Project Number: 9329483
Client Project ID: PIEDMONT GEOLOGIC -9233015
Project Sample Number: 9329(83-022
Matrix: Water
Date Collected.: 05/23/02 09:10
Date Received: 05/24/02 13:55
Units Report Limit -~An~•~l~y•~e~d._~By,_ -~CA=S~N~oL, _ ~ ReqLmt
Total Organic Carbon
Total Organic Carbon
Method: SM 5310C
Date: 06/11/02
Laboratory Certification IDs
NC Wastewater 40
NC Drinking Water 37712
0.83 mg/1 0.50 06/03/02 EWS 7U0-U-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in lull,
without the written consent of Pace Analytical Services, Inc.
I aboratorv Certification ms
TN Drinking Water 02980
SC Environmental 99030
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I Lah Sample No: 922293188
Client Sample ID: MW-2 I Parameters
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Wet Chemistry
Total Organic carbon
Total Organic Carbon
Date: 06/11/02
Laboratory Certification IDs
NC Wastewater 40
NC Drinking Water 37712
Pac• Analytlcal Serrlcas, Inc. 54 RaW!f/SC/Oll DrilO
Asheville, NC 28801
Pf1one: 828.254.7176
Fax: [phone]"18
Lab Project Number: 9329483
Client Project ID: PIEDMONT GEOLOGIC -9233015
Project Sample Number: 9329(83-023
Matrix: Water
Date Collected: 05/30/02 10:00
Date Received: 05/30/02 16:15
Results Units Report Limit __ An,,,,,a"'-ly,.,,,..e,..d _ _,s.,v_ -~CA=S~N=o~, _ ~ ~
Method: SM SllOC
99. mg/1· 0.50 06/07/02 EWS 7140•14•0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Page: 23
Laboratory Certification ms
TN Drinking Water 02980
SC Environmental 99030
c1ceAnalyticar
www.pacetabs.com
Lab S-1• No: 922293204
Client Sample ID: MW-3
parameters Results
Wet Chemistry
Pac• Analytical SBIYICB1,tn,.
541/J..nscron Olive
Asheville, NC 28801
Phone: 828,254.7176
Fax: [phone]
Lab Project Number: 9329(83
Client Project ID: PIEDMONT GEOLOGIC -9233015
Project S-1• Number: 9329483-024
Matrix: Water
Date Collected: 05/30/02 10:20
Date Received: 05/30/02 16:15
Units Report Limit _ _.,An_,a,,l,iy.,ze,,d,_....eBv"-_ _,CA""'-S--'N"'o~, _ 2Y.!!_ ReqLmt
Total Organic Carbon
Total Organic Carbon
Method: SM 5310C
Date: 06/11/02
t aboratorv Certttication \Os
NC Wastewater 40
NC Drinking Water 37712
56. mg/1 0.50 06/07/02 EWS 7440-U-0
P1.ge1 2f.
REPORT OF LABORATORY ANALYSIS I aboratorv Certification J□s
TN Drinking Water 02980 This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc. SC Environmental 99030
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www.paceJabs.com
I
I Lab Sample No, 922293220
Client Sample ID: MW-6
I Parameters
Wet Chemistry
Results
Pacs Analytical Ssrvlcas,.lnc.
54 RalelJSC/0ll Ori-..
Asheville, NC 28801
Phone: [phone]
Fax: [phone]
Lab Project Number: 9329(83
Client Project ID: PIEDMONT GEOLOGIC -9233015
Project Sample Number: 9329(83-025
H&trix: Water
Date Collected: OS/29/02 17:15
Date Received: 05/30/02 16:15
Units Report Limit -~An...,a,clvuz,2ed,.__,s,,v __ ...,CA_s_.N,,.,oL, _ 2l!AL l!el!lfil
I Total Organic Carbon
Total Organic Carbon
Method: SM 5310C
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I Date: 06/11/02
I \ aboratorv Certification ms
NC Wastewater 40
NC Drinking Water 37712
I
u. mg/1 0.50 06/07/02 EWS 7'40-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Page1 25
I aboratorv Certification ms
TN Drinking Water 02980
SC Environmental 99030
www;pacetabs.eom
Lab Sample No: 922293261
Client Sample ID: MW-8
parameters Results
Wet Chemistry
PBCB Analytical ServlCB$,./nc.
54 Ravensaoff Drive
Asheville, NC 28801
Phone: [phone]
Fax: 828.252:.tiilB
Lab Project Number: 9329483
Client Project ID: PIEDMONT GEOLOGIC -9233015
Project Sample Number: 9329483-026
Matrix: Water
Date Collected.: 05/29/02 16:50
Date Received: 05/30/02 16:15
Units Report LWt _ _,,,An..,a,.l"yz~•~d-~•~•--~CA=s~•~o~·-Ql!Al_ ~
Total Organic Carbon
Total Organic Carbon
Method: SM 5310C
Date: 06/11/02
Laboratory Certification IDs
NC Wastewater 40
NC Drinking Water 37712
(.2 mg/l 0.50 06/07/02 EWS 7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Pa11e: 26
I aboratorv Certification ms
TN Drinking Water 02980
SC Environmental 99030
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c1ceAnalyticar
www.pacelabs.com
Lab Sample No: 922293279
Client Sample ID: MW-8 DUP
Parameters Results
Wet Chemistry
Pacs Analytical Ssrvlcss,.lnc.
54 Ravenscroff Dtivs
Asheville, NC 28801
Phone: [phone]
Fax: [phone]
Lab Project Number: 9329483
Client Project ID: PIEDMONT GEOLOGIC -9233015
Project Sample Number: 9329483-027
Matrix: Water
Date Collected: 05/29/02 17:00
Date Received: 05/30/02 16:15
Units Report Limit -~An .... a,.lv;u..sed.__,sv,,_ ~CA=S~N=o~, _ !2Y..IL ~
Total Organic Carbon Method: SM Sll0C
Total Organic carbon
Date: 06/ll/02
\ aboratorv Certification \Os
NC Wastewater 40
NC Drinking Water 37712
2.8 mg/1 0.50 06/07/02 EWS 7U0·U·0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Seivices, Inc.
Pago: 27
I aboratorv Certification IDs
TN Drinking Water 02980
SC Environmental 99030
wvAv.paceiabs.oom
Lab Sample No: 922293287
Client Sample ID: MW-12
Parameters Results
Wet Chemistry
Pac• Analytlcal Servtcss, Inc.
54 Ravenscroft Ori,e
Asheville, NC 28801
Phone: [phone]
Fax: [phone]$18
Lab·Project Number: 9329483
Client Project ID: PIEDMONT GEOLOGIC -9233015
Project S-le NUmber: 9329483-028
Matrix: Water
Date Collected: 05/30/02 12:00
Date Received: 05/30/02 16:15
tJnits Report Limit _ _,,,An,,as.lv:z,_..e,,_d _ _,B,,y __ _,CA"""S_,N,,.o,.. _ gy_.tl_ ~ ·
Total Organic Carbon
Total Organic Carbon
Method: SM 5310C
Pate: 06/ll!OJ
Laboratory Certification ms
NC Wastewater 40
NC Drinking Water 37712
80. mg/1 0.50 06/07/02 EWS 7440-U-0
Page: :ZB
REPORT OF LABORATORY ANALYSIS l aboratorv Certification IDs
TN Drinking Water 02980 This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc. SC Environmental 99030
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I Lab Sample No: 922293295
Client Sample ID: MW-16 I Parameters
Wet Chemistry
I Total Organic Carbon
Total Organic Carbon
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Date: 06/11/02
\ ahora1orv Certification 10s
NC Wastewater 40
NC Drinking Water 37712
Pac• Analytlcal S•rvlcaa,./nc.
54 Ravenscrofl Drive
Asheville, NC 288()1
Phone: [phone]
Fax: [phone]fi18
Lab Project Number: 9329,83
Client Project ID: PIEDMONT GEOLOGIC -9233015
Project Sample Number: 9329483-029
Matrix: Water
Date collected: 05/30/02 08:30
Date Received: 05/30/02 16:15
Regµlts Units Report Limit -~An°""a""lvuz"'ed,.__,sv!L ~™=~•~o~·-!mL -
Method: SM 5310C
54. mg/1 0.50 06/07/02 EWS 7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services. Inc.
Page: 29
I aboratorv Certification ms
TN Drinking Water 02980
SC Environmental 99030
aceAnalyticar
wv.w.pacelabs.com
Lab Sample No: 922293303
Client Sample ID: MW-36S
Parameters Results
Wet Chemistry
Pace Analytl,:a/ Services, Inc.
54 P.awscron Dri,e
AsheWlle, NC 28801
Phone: [phone]
Fax: 828.252:4618
Lab Project Number: 9329483
Client Project ID; PIEDMONT GEOLOGIC -9233015
Project Sample Number: 9329483-030
Matrix: Water
Date Collected: 05/30/02 09:30
Date Received: 05/30/02 16:15
Units Report Limit -~An=a,.ly,_,z,.e,._d _ _.B.,y __ _,CAS""'--'N"'o~-_ ~ RegLmt
Total Organic Carbon
Total Organic Carbon
Method: SM 5310C
Dato: 06/11/02
Laboratory Certification IDs
NC Wastewater 40
NC Drinking Water 37712
75. mg/1 0.50 06/07/02 EWS 7440-U-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
I aboratorv Certification IDs
TN Drinking Water 02980
SC Environmental 99030
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I Lab Sample No: 922293329
Client Sample ID: MW-37
I Parameten
Wet Chemistry
I Total Organic Carbon
Total Organic Carbon
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I Date: 06/11/02
I I aboratorv Certuicatioo IDs
NC Wastewater 40
NC Drinking Water 37712
I
Pac• Anatyttcal SBrvlcas,. Inc.
54 Ra-..,,scrall Drive
Asheville, NC 28801
Phone: [phone]
Fax: [phone]S18
Lab Project Number: 9329483
Client Project ID: PIEDMONT GEOLOGIC •9233015
Project Sample Number: 9329483-031
Matrix: Water
Date Collected: 05/30/02 09:00
Date Received: 05/30/02 16:15
Results Units Report Limit __ An=•=lv~•=•=d-~By~ ~CAS=~N=o~-_ QnL ~
Method: SM 5310C
22. mg/1 0.50 06/07/02 EWS 7440-41-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Page: 31
I aboratorv Certilication IDs
TN Drinking Water 02980
SC Environmental 99030
wi.'l'l~pacetabs,com
Lab Sample No: 922293337
Client Sample ID: FB-2
Parameters Results
Wet Chemistry
Pace Analytical Ssrvlces, Inc.
54 Flavenscroll Drive
Mheiille, NC 288/JI
Phofl6: 828.254.7116
Fax: [phone]
Lab Project Number: 9329483
Client Project ID: PIEDMONT GEOLOGIC -9233015
Project Sample Number: 9329483-032
Matrix: Water
Date Collected: 05/29/02 16:00
Date Received.: 05/30/02 16:15
Units Report Limit _ _.,An..,a,-lLY•~• .. 4--Bv.,_ _,CA""'-S_,N.,oL. _ 2YM_ ~
Total Organic Carbon
Total Organic Carbon
Method: SM 5310C
Date: 0li/11/02
l aboratorv Certification IDs
NC Wastewater 40
NC Drinking Water 37712
2.2 mg/1 0.50 06/07/02 EWS 7'40-41-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Page: 32
Laboratory Certification ms
TN Drinking Water 02980
SC Environmental 99030
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aceAnalyticar
wvAv.pacelabs.com
Lab Sample No: 922293386
Client Sample ID: MW-17
Parameters Results
Wet Chemistry
Paco Analyttcal Sortlcos,.ln•.
54 Ra""1scron Drive
Asheville, NC 28801
Phone: 828,254.7176
Fax: [phone]
Lah Project Number: 9329483
Client Project ID: PIEDMONT GEOLOGIC -9233015
Project Sample Number: 9329(83-033
Matrix: Water
Date Collected: 05/30/02 oa,,s
Date Received: 05/30/02 16:15
unit@ Report Limit -~An~•~l~yz~e~d~~B~y ~CA=S~N~o~, _ ~ ReqLmt
Total Organic Carbon Method: SM 5310C
Total Organic Carbon
Do.tel 06/11/02
t aboratorv Certification IDs
NC Wastewater 40
NC Drinking Water 37712
5.6 mg/1 o.so 06/07/02 EWS 7440-U-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Paqa: 33
Laboratory Certification IDs
TN Drinking Water 02980
SC Environmental 99030
aceAnalyticar
ww,v.pacetabs.com
Pac• Analytical S1rvlcas, Inc.
54 Ravenscroff Drive
Asheville, NC 28801
Phone: [phone]
Fax: [phone]
Lab Project Number: 9329,83
Client Project ID: PIEDMONT GEOLOGIC -9233015
PARAMETER FOOTNOTES
Not detected at or above adjusted reporting limit
Not Calculable
ND
NC
J
MDL
Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit
Adjusted Method Detection Limit
Date: 06/11/02
l aboratorv Certification IDs
NC Wastewater 40
NC Drin~ng Water 37712
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in lull,
without the written consent of Pace Analytical Services, Inc.
Page: 3',
I aboratorv Certification ms
TN Drinking Water 02980
SC Environmental 99030
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aceAnalyticar
M'm.pacelabs.com
Lab Sample No: 922276217
Client Sample ID: MW-34S
parameters
Air
Headspace Analysis
Methane
Ethane
Ethane
Lab Sample No: 922276225
Client Sample ID: MW-34D
Parameters
Air
Headspace Analysis
Methane
Ethane
Ethane
Lah Sample No: 922282611
Client Sample ID: MW-13
Parameters
Air
Headspace Analysis
Methane
Ethane
Ethane
Lab Sample No: 922282629
Client Sample ID: MW-27
Parameters
Air
Readspace Analysis
Methane
Date: 06/ll/Ol
Pace Ana/yt/cal Services, Inc.
1700 Elm Street, Suite 20/J
Minneapolis, MN 55414
Phone: [phone]
Fax: [phone]
Lab Project Number: 1057877
Client Project ID: 9233015 PIEDMONT GEOLOGIC
Project Sample Number: 1057877-002
Matrix: water
Dato Collected: 05/20/02 17:30
Date Received: 05/21/02 14:10
Results Units Report Limit -~An=•l~Y~•~e~d-~B~Y--~CA_S~No=, _ 2YAl_ ~
Method: EPA 3810 Modified
22. uo/1
ND ug/1
ND uo/1
10.
20.
20.
05/29/02
05/29/02
05/29/02
MTG 71-82-8
MTG 74-84-0
MTG 74-85-1
Project Sample Number: 1057877-003
Matrix: Water
Dato Collected: 05/20/02 17:00
Dato Received: 05/21/02 14:10
Results Units Report Limit _ _,,An,.a.,1.,v~•~•,.d-~By,_ _CA=S~N~o~. _ ~ RegLmt
Method: EPA 3810 Modified
21. uo/1 10.
ND
ND
uo/l
uo/l
20.
20.
05/29102
05/29/02
05129/02
MTG 74-82-8
MTG 74-84-0
MTG 71-85-1
Project S-1• Number: 1057877-004
Matrix: Water
Dato Collected: 05/22/02 10:51
Date Received: 05/23/02 16:10
Results Units Report Limit -~An-al,.vu•~•~d-~By._ ~CA=S~No=, _ ~ ReqLmt
Method: EPA 3810 Modified
ND
ND
ND
ug/1
ug/l
ug/l
10.
20.
20.
06/03/02
06/03/02
06/03/02
MTG 74-82-8
MTG 74-84-0
MTG 7'-85-1
Project Sample Number: 1057877-005
Matrix: Water
Dato Collected: 05/22/02 12:43
Date Received: 05/23/02 16:10
Results Units Report Limit -~An-a._ly-z....,o~d-~B,.,y_ -~CA=S~N~o~. _ 2Y.tl_ ~
Method: EPA 3810 Modified
ND ug/1 10. 06/03/02
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
MTG 74-82-8
Page: l
aceAnalyticar
www:pacelabs.com
Lab Sample No: 922282629
Client Sample ID: MW-27
Parameters
Ethane
Ethene
Lab S-le No: 922282637
Client Sample ID: MW-35S
Parameters
Air
Headspace Analysis
Methane
Ethane
Ethane
Lab Sample No: 922282645
Client Sample ID: MW-36D
Parameters
Air
Headspace Analysis
Methane
Ethane
Ethene
Lab Sample No: 922282652
Client Sample ID: MW-40
Parameters
Air
Beadspace Analysis
Methane
Ethane
Ethene
Date: 06/11/02
0 ,, scco••
e ~ ~ ~
0 -~L i
Regµlts
ND
ND
Results
Units
ug/1
ug/1
Pace Ana/ytlcal Ssrvlcss, Inc.
1700 Elm Street, Suite 200
Minneapc/is, MN 55414
Phone: [phone]
Fax: [phone]
Lab Project Number: 1057877
Client Project ID: 9233015 PIEDMONT GEOLOGIC
Project Sample Number: 1057877-005
Matrix: Water
Date Collected: 05/22/02 12:,3
Date Received: 05/23/02 16:10
Renart Limit _ __,_An.,,.a,.lvuzsse,ed~_,By"-CAS No,
20. 06/03/02 MTG 74-84-0
20. 06/03/02 MTG 74-85-1
Project Sample Number: 1057877-006
Matrix: Water
Date Collected: 05/22/02 12:23
Date Received: 05/23/02 16:10
Units Report Limit -~An=•l~y~•~e~d-~By~ ~CA=S~N~o~•~-~ ReqLmt
Method: EPA 3810 Modified
ND
ND
ND
ug/1
ug/1
ug/1
10.
20.
20.
06/03/02
06/03/02
06/03/02
MTG 74-82-8
MTG 7'-84-0
MTG 74-85-1
Project •-le Number: 1057877-007
Matrix: Water
Date Collected: 05/22/02 11:51
Date Received: 05/23/02 16:10
Results Units Report Limit _ __,An,,,.,acslv,.z,,,ee,dc___,Byu._ -~CA~S~N~o~, _ ~ ReqLmt
Method: EPA 3810 Modified
ND ug/1
ND ug/1
ND ug/1
10.
20.
20.
06/03/02
06/03/02
06/03/02
MTG 74-82-8
MTG 74-84-0
MTG 7'-85-1
Project Sample Number: 1057877-008
Matrix: Water
Date Collected: 05/22/02 11:31
Date Received: 05/23/02 16:10
Results units Report Limit -~An-•l~y~z~e~d-~B~y_ -~CA=S~No~-~-~ ReqLmt
Method: EPA 3810 Modified
ND ug/1
ND ug/1
ND ug/l
10.
20.
20.
06/04/02
06/04/02
06/04/02
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
MTG 74-82-8
MTG 71-84-0
MTG 7'-85-1
Page= 2
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ace Analytical"
wiw1.pacetabs.com
Lah Sample No: 922282710
Client Sample ID: MW-41
Parameters
Air
Headspace Analysis
Methane
Ethane
Ethane
Lab Sample No: 922282728
Client Sample ID: MW-411
Parameters
Air
Headspace Analysis
Methane
Ethane
Etbene
Lab Sample No: 922282785
Client Sample ID: MW-421
parameters
Air
Headspace Analysis
Methane
Ethane
Ethane
Lab Sample No: 922282793
Client Sample ID: MW-43
Parameters
Air
Headspace Analysis
Methane
Date: 06/11/02
Paco Ana/yt/ca/ S•rvfc,s, Inc.
1100 Elm Street, Suite 200
Minneapo/i~ MN 55414
Phone: [phone]
Fax: [phone]
Lab Project Nllmber: 1057877
Client Project ID: 9233015 PIEDMONT GEOLOGIC
Project Sample NIIIDber: 1057877-009
Matrix: Water
Date Collected: 05/22/02 09:28
Date Received: 05/23/02 16:10
Results Upits Report Limit __ An=•l~•~•~e-d~-IIY-_,CAS.,,.u,No,,_._, _ ~ ReqLmt
Method: EPA 3810 Modified
ND ug/l
ND ug/1
ND ug/l
10.
20,
20.
06/0,/02
06/0'102
06/0'102
MTG 74-82·8
MTG 74-84·0
MTG 74-85-l
Project S-le Number: 1057877-010
Matrix: Water
Date Collected: 05/22102 09:53
Date Received: 05/23/02 16:10
Results Units Report Limit -~Ana=l~•~•~•~d-~By~ -™=~N~o~, _ 21!§.L Rear.mt
Method: EPA 3810 Modified
ND u~l ~.
ND
ND
ug/1
ug/l
20.
20.
06/04/02
06/0(/02
06/04/02
MTG 74-82-8
MTG 74-84·0
MTG 74-85-l
Project Sample Number: 1057877-011
Matrix: Water
Date Collected: 05/22/02 10:23
Date Received: 05/23/02 16:10
Results Units Report Limit -~An=al~v;=e~d~~Bv,_ _,CAS=~No~-_ 2llL ~
Method: EPA 3810 Modified
ND
ND
ND
ug/l
ug/l
ug/l
10.
20,
20.
06/0,102
06/0'102
06/04/02
MTG 74-82-8
MTG 1,-a,-o
MTG 74-85-l
Project Sample NUmher: 10S7877-012
Matrix: Water
Date Collected: 05/22/02 07:41
Date Received: 05/23/02 16:10
Results Units Report Limit -~An~•~l~y;=ed~-~By~ -~CA-s~u~oL, -~ ~
Method: EPA 3810 Modified'
ND ug/l 10. 06/04/02
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
MTG 74-82-8
Page: J
aceAnalyticar
wv11,v.pacetabs.com
Lab Sample No: 922282793
Client Sample ID: MW-43
Parameters
Ethane
Ethane
Lab Sample No: 922282801
Client Sample ID: MW-45
Parameters
Air
Headspace Analysis
Methane
Ethane
Ethane
Lab Sample No: 922282819
Client Sample ID: MW-46
Parameters
Air
Headspace Analysis
Methane
Ethane
Ethene
Lab Sample No: 922285176
Client Sample ID: MW-11
Parameters
Air
Headspace Analysis
Methane
Ethane
Ethene
Date: 06/11/02
Results
ND
ND
Results
units
ug/1
ug/1
Pace Anafyt/ca/ Services, Inc.
1700 Elm Street, Suite 200
Minneapc/is. MN 55414
Phone: 612.61J7.1700
Fax: 612.61J7.6444
Lab Project Number: 1057877
Client Project ID: 9233015 PIEDMONT GEOLOGIC
Project Sample Number: 1057877-012
Matrix: Water
Date Collected: 05/22/02 07:41
Date Received: 05/23/02 16:10
Report Limit _ _,An=•~lyLz~e~d~_,By~ CAS No.
20. 06/0(102 MTG 74-84-0
20. 06/0(/02 MTG 74-85-1
Project Sample Number: 1057877-013
Matrix: Water
Date Collected: 05/22/02 OB:21
Date Received: 05/23/02 16:10
Units Report Limit _ __,,An=•l~Yl'=•~d-~By~ -~CA=S~N~o~. _ 2Y!!._ ~
Method: EPA 3810 Modified
ND
ND
ND
ug/1
ug/1
ug/1
10.
20.
20.
06/0(/02
06/0(102
06/0(/02
MTG 74-82-8
MTG 74-84-0
MTG 74-85-1
Project Sample Number: 1057877-014
Matrix: Water
Date Collected: OS/22/02 07:S9
Date Received: 0S/23/02 16:10
Results Units Report Limit -~AD=•~lY~•~•~d~~B~y ___ CAS=~N~o~. _ QyJ,L RegLmt
Method: EPA 3810 Modified
ND ug/1
ND ug/1
ND ug/1
10,
20.
20.
06/0(/02
06/0(/02
06/0(102
MTG 74-82-8
MTG 74-84-0
MTG 7'-85-1
Project Sample Number: 10S7877-01S
Matrix: Water
Date Collected: OS/23/02 11:30
Date Received: OS/24/02 13:S5
Results Units Report Limit -~AD,..,,a,.lv,.,ze,e,sdc__,By,.,_ _CA=S~N~o~, _ 2llL ReqLmt
Method: EPA 3810 Modified
ND ug/1
ND
ND
ug/1
ug/1
10.
20.
20.
06/0(102
06/04/02
06/0(/02
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
MTG 74-82-8
MTG 74-84-0
MTG 71-85-1
P&ge: '
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ace Analytical'"
ww\v.pacelabs.com
Lab Sample No: 922285184
Client Sample ID: MW-111
Parameters
Air
Headspace Analysis
Methane
Ethane
· Ethane
Lab Sample No: 922285192
Client Sample ID: MW-121
parameters
Air
Headspace Analysis
Methane
Ethane
Ethane
Lab Sample No: 922285200
Client Sample ID: MW-16I
Parameters
Air
Headspace Analysis
Methane
Ethane
Ethene
Lab Sample No: 922285218
Client Sample ID: MW-17I
Parameters
Air
Headspace Analysis
Methane
Date: 06/11/02
o '" >eco•o
,o "'
'< " 0 -~L .~
Result&
Pace Analytical Ssrvlc••• Inc.
1700 Elm Street, Suite 200
Minneapolis, MN 55414
Phone: [phone]
Fax: [phone]
Lab Project Number: 1057877
Client Project ID: 9233015 PIEDMONT GEOLOGIC
Project Sample Number: 10S7877-016
Matrix: Water
Date Collected: 05/23/02 10:40
Date Received: 05/24/02 13:55
tJnits Report Limit -~M=•l~Y-•-•~d-~Bv~ _CA-S~N~o~. _ 2DL ~
Method: EPA 3810 Modified
23. ug/1
ND ug/1
ND ug/1
10.
20.
20.
06/04/02
06/04/02
06/01/02
MTG 7'-82-8
MTG 7'-84-0
MTG 7'-85-1
Project Sample Number: 1057877-017
Matrix: Water
Date Collected: 05/23/02 09:40
Date Received: 05/24/02 13:55
Results Unite Report Limit -~An-•l~vz=e~d-~By~ ~CAS-~No~. _ Q:iaL ReqLmt
Method: EPA 3810 Modified
ND
ND
ND
ug/1
ug/1
ug/1
10.
20.
20.
06/04/02
06/01/02
06/01/02
MTG 7'-82-8
MTG 7'-84-0
MTG 7'-85-1
Project Sample Number: 1057877-018
Matrix: Water
Date Collected: 05/23/02 08:30
Date Received: 05/24/02 13:55
Reaults Units Report Limit -~An-•l~v~•~•~d-~Bv,._ -~CAS-~N~oL, _ ~ ~
Method: EPA 3810 Modified
ND
ND
ND
ug/1
ug/1
ug/1
10.
20.
20.
06/01/02
06/04/02
06/04/02
MTG 7'-82-8
MTG 74-84-0
MTG 74-85-1
Project Sample Number: 1057877-019
Matrix: Water
Date Collected: 05/23/02 10:10
Date Received: 05/24/02 13:55
Unite Report Limit -~M-•l~v~•~•~d-~Bv~ ~CA=S~No~-~-_Qyli__ ~
Method: EPA 3810 Modified
ND ug/1 10. 06/01/02
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
MTG 7'-82-8
Page: 5
wvAv.pace"'bs.com
Lab S-le No: 922285218
Client Sample ID: MW-171
parameters
Ethane
Ethane
Lab Sample No: 922285226
Client Sample ID: MW-38
Parameters
Air
Beadspace Analysis
Methane
Ethane
Ethane
Lab Sample No: 922282959
Client Sample ID: FB-1
Parameters
Air
Headspace Analy~is
Methane
Ethane
Ethane
Lab Sample No: 922283007
Client Sample ID: MW-36DUP
Parameters
Air
Beadspace Analysis
Methane
Ethane
Ethane
Date: 06/11/02
Results
ND
ND
Results
Units
ug/1
ug/1
Pace Analytical Ssrv/ces, Inc.
17/JO Elm Slreet, Suite 2/JO
Minneapolis, MN 55414
Phone: 612.6/Jl.17/JO
Fax: [phone]
Lab Project Number: 1057877
Client Project ID: 9233015 PIEDMONT GEOLOGIC
Project Sample Number: 1057877-019
Matrix: Water
Date Collected: 05/23/02 10:10
Date Received: 05/24/02 13:55
Reno rt Limit _ _,l\Jl,-al;;Vr.,Z,ses,d~_.Bv"--__ CA,_.s.__.N,,o~, -2YAL RegLm.t
20, 06/04/02 M'rG 7'-84-0
20. 06/04/02 M'rG 7'-85-1
Project Sample Number: 1057877-020
Matrix: Water
Date Collected: 05/23/02 09:10
Date Received: 05/24/02 13:55
Units Report Limit _ _,An,,..a,,,lvz:i:a,e,sdc__,B.,,vc. _..cCA..,..s._.,N,,o~. _ ~ ReqLmt
Method: EPA 3810 Modified
ND ug/1 10,
ND
ND
ug/1
ug/1
20.
20.
06/04/02
06/04/02
06/04/02
M'rG 74-82-8
>rrG 74-84-0
M'rG 7'-85-1
Project Sample Number: 1057877-021
Matrix: Water
Date Collected: 05/22/02 11:51
Date Received: 05/24/02 13:55
Results Onita Report Limit _ _,,An""'al.,vz"'-"ed"'----"Bv'-_..cCA,.,,Sw,N,,_o~. _ Qy_y_ ReqLmt
Method: EPA 3810 Modified
ND ug/l
ND ug/1
ND ug/1
10.
20.
20.
06/04/02
06/04/02
06/04/02
M'rG 74-82-8
M'rG 7'-84-0
MTG 7'-85-1
Project Sample Number: 1057877-022
Matrix: Water
Date Collected: 05/22/02 11:51
Date Received: 05/24/02 13:55
Results Units Report Limit Analyzed By
Method: EPA 3810 Modified
ND ug/1
ND ug/1
ND ug/1
10.
20.
20.
06/04/02
06/04/02
06/04/02
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
M'rG 74-82-8
M'rG 7'-84-0
M'rG 7'-85-1
Page: 6
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www.pacelabs.com
Lab Sample No: 922283015
Client Sample ID: MW-29
parameters
Air
Headspace Analysis
Methane
Ethane
Ethane
Lab Sample No: 922293188
Client Sample ID: MW-2
Parameters
Air
Headspace Analysis
Methane
Ethane
Ethane
Lab Sample No: 922293204
Client Sample ID: MW-3
Parameters
Air
Headspace Analysis
Methane
Ethane
Ethane
Lab Sample No: 922293220
Client Sample ID: MW-6
parameters
Air
Headspace Analysis
Methane
Date: 0G/11/0.1
Results
Pace Analytical SsrvltflS, Inc.
1700 Elm Streel, Suite 200
Minneapolis, MN 55414
Phone: [phone]
Fax: [phone]
Lab Project Number: 1057877
Client Project ID: 9233015 PIEDMONT GEOLOGIC
Project Sample Number: 1057877-023
Matrix: Water
Date Collected: 05/22/02 11:11
Date Received: 0512,102 13:55
Units Report Limit _ _,An,.,.a,,_lv~•~e.,d,__.B,..y __ _cCAS,.,,.,._.,N.,o~, _ mL ReqLmt
Method: EPA 3810 Modified
ND
ND
ND
ug/1
ug/1
ug/1
10,
20,
20,
06/01/02
06/04/02
06/0'102
MTG 71-82-8
MTG 74-84-0
MTG 74-85-1
Project Sample Number: 1057877-024
Matrix: Water
Date Collected: 05/30/02 10:00
Date Received: 05/30/02 16:15
Results Units Report Limit Analyzed By _CA,.,.s.__.N,,o~-_ 2Yf..L ReqLmt
Method: EPA 3810 Modified
ND ug/1
ND ug/1
ND ug/1
10,
20,
20,
06/10/02
06/10/02
06/10/02
MTG 74-82-8
MTG 74-81-0
MTG 74-85-1
Project Sample Number: 1057877-025
Matrix: Water
Date Collected: 05/30/02 10:20
Date Received: 05/30/02 16:15
Results Unite Report Limit _ _,An .... a,,;ly>'.lz.,e.,d~_,sy.,__ ~CAS-~No~. _ !!!!&_ -
Method; EPA 3810 Modified
ND ug/1 10,
ND ug/1 20,
ND ug/1 20,
06/10/02
06/10/02
06/10/02
MTG 7'-82-8
MTG 74-84-0
MTG 74-85-1
Project Sample Number: 1057877-026
Matrix: Water
Date Collected: 05/29/02 17:15
Date Received: 05/30/02 16:15
Results Units Report Limit _ _,An .... a,.lv,cz.,e.,,dc__,sv.,__ __:CAS,.,,.u,N.11.0~, _ 2YAL ~
Method: EPA 3810 Modified
ND ug/1 10, 06/10/02
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
MTG 7'-82-8
Page: 7
WVM.pacelabs.com
Lab S-le No: 922293220
Client Sample ID: MW-6
parameters
Ethane
Ethane
Lab S-le No: 922293261
Client Sample ID: MW-8
Parameters
Air
Headspace Analysis
Methane
Ethane
Ethane
Lab Sample No: 922293279
Client Sample ID: MW-8 DUP
Parameters
Air
Headspace Analysis
Methane
Ethane
Ethene
Lab Sample No: 922293287
Client Sample ID: MW-12
Parameters
Air
Headspace Analysis
Methane
Ethane
Ethane
Date: 06/11/02
ND
ND
Units
ug/1
ug/1
Pace Analytical Service,, Inc.
1700 Elm Street. Suite 200
Minneapc/i~ MN 5S414
Phone: [phone]
Fax: [phone]
Lab Project Number: 1057877
Client Project ID: 9233015 PIEDMONT GEOLOGIC
Project Sample Number: 1057877-026
Matrix: Water
Date Collected: 05/29/02 17:15
Date Received: 05/30/02 16:15
Report Limit _ _,An,...a.,,l,.yz.,e.,dc__,B,,vc... __ CA,.,.S....,,Nc,OL, -~ ~
20. 06/10/02
20, 06/10/02
MTG 71·8'-0
MTG 7'·85-1
Project S-le Number: 1057877-027
Matrix: Water
Date Collected: 05/29/02 16:50
Date Received: 05/30/02 16:15
Results Units Report Limit _ _,,An,,a,.1,,y,._.z,.e,,d _ __eBy,_ __ CA-S~No=· _ ~ ReqLmt
Method: EPA 3810 Modified
ND
ND
ND
ug/1
ug/1
ug/1
10.
20.
20.
06/10/02
06/10/02
06/10/02
MTG 74-82·8
MTG 7'·84-0
MTG 74-85-1
Project S-le Number: 1057877-028
Matrix: Water
Date Collected: 05/29/02 17:00
Date Received: 05/30/02 16:15
Results Units Report Limit _ _,An,,,.a,.ly,,z.,e,,,dc____,Sy.,__ _CA-S~N~o~·-
Method: EPA 3810 Modified
ND
ND
ND
ug/1
ug/1
ug/1
10.
20.
20,
06/10/02
06/10/02
06/10/02
MTG 74-82·8
MTG 74-8'-0
MTG 7'·85·1
lll!tl, RegLmt
Project S-le Number: 1057877-029
Matrix: Water
Date Collected: 05/30/02 12:00
Date Received: 05/30/02 16:15
Results Units Report Limit _ _,An,,,.a..,,lv,,,.,e,,,dc____,B,,y ___ CA-S~No=. -2Y.AL ReqLmt
Method: EPA 3810 Modified
ND ug/1
ND ug/1
ND ug/1
10.
20.
20.
06/10/02
06/10/02
06/10/02
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
MTG 7'·82·8
MTG 74-84-0
MTG 74-85-1
Page: B
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ace Analytical'"
ww.v.pacelabs.com
Lab Sample No: 922293295
Client Sample ID: MW-16
parameters
Air
Beadspace Analysis
Methane
Ethane
Ethene
Lab Sample No: 922293303
Client Sample ID: MW-36S
parameters
Air
Beadspace Analysis
Methane
Ethane
Ethene
Lab Sample No: 922293329
Client Sample ID: MW-37
Parameters
Air
Headspace Analysis
Methane
Ethane
Ethene
Lab Sample No: 922293337
Client Sample ID: FB-2
parameters
Air
Headspace Analysis
Methane
Date: 06/11/02
0 ,• ,cco•o
~ "<I'
?L --. \\
Pace Ana/yt/ca/ SBrvlc••• Inc.
1700 Elm S/reet. Suite 200
Minneapoli~ MN 55414
Phone: [phone]
Fax: [phone]
Lab Project Number: 1057877
Client Project ID: 9233015 PIEDMONT GEOLOGIC
Project Sample Number: 1057877-030
Matrix: Water
Date Collected: 05/30/02 08:30
Date Received: 05/30/02 16:15
Results units Report Limit _ _,Ane!l!•.clv,;z.,e,,,d~-'By!:£... _,CA.,,.Su,Noo.,~-~ ~
Method: EPA 3810 Modified
ND ug/1
ND ug/1
ND ug/1
10.
20.
20.
06/10/02
06/10/02
06/10/02
MTG 74-82-8
MTG 74-84-0
MTG 74-85-1
Project Sample Number: 1057877-031
Matrix: Water
Date Collected: 05/30/02 09:30
Date Received: 05/30/02 16:15
Results Units Report Limit _ _,An!!!!!a,.ly,cze,e"'d'------'By"-_;CAS""''-"""o~·-
Method: EPA 3810 Modified
ND ug/1 10.
ND
50.
ug/1
ug/1
20.
20.
06/10/02
06/10/02
06/10/02
MTG 74-82-8
MTG 7'-84-0
MTG 74-85-1
~ ReqLmt
Project Sample Number: 1057877-032
Matrix: Water
Date Collected: 05/30/02 09:00
Date Received: 05/30/02 16:15
Results units Report Limit _ __,An...,a,elv...,z.,eo,d~_,ey!:L. _,CAS.,,.l...!!Nos,..~_ Ql!lL ~
Method: EPA 3810 Modified
ND ug/1 10.
ND
ND
ug/1
ug/l
20.
20.
06/10/02
06/10/02
06/10/02
MTG 74-82-8
MTG 74-84-0
MTG 7'-85-1
Project Sample Number: 1057877-033
Matrix: Water
Date Collected: 05/29/02 16:00
Date Received: 05/30/02 16:15
Results Units Report Limit _ _,An_a,_ly..,z.,e,,,dc___.B,.,y __ _,CAS.,,.l...!!N,,o~. _ QML RegLmt
Method: EPA 3810 Modified
ND ug/1 10. 06/10/02
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the wrttten ~onsent of Pace Analytlcal Services, Inc.
MTG H-82-8
Page: 9
www.pacelabs.com
Lab Sample No: 922293337
Client Sample ID: FB-2
Parameters
Ethane
Ethene
Lab Sample No: 922293386
Client Sample ID: MW-17
Parameters
Air
Headspace Analysis
Methane
Ethane
Ethane
Date: 06/11/0l
0 ,. ,cco•o
0 .,, ~
~ ,.
0 -~L ~
Results
ND
ND
Units
ug/l
ug/l
Paco Analytical Sorvlc .. , Inc.
1700 Elm Streel. Suite 200
Minneap-0/i~ MN 55414
Phone: [phone]
Fax: [phone]
Lah Project Number: 1057877
Client Project ID: 9233015 PIEDMONT GEOLOGIC
Project Sample Number: 1057877-033
Matrix: Water
Date Collected: 05/29/02 16:00
Date Received: 05/30/02 16:15
Report Limit __ An...,a..,lYJu.2ed,.___,Bvu._ CAS No,
20. 06/10/02 MTG 74-8'·0
20. 06/10/02 MTG 74-85-1
Project Sample Number: 1057877-034
Matrix: Water
Date Collected: 05/30/02 08:,5
Date Received: 05/30/02 16:15
Results Units Report Limit _ _,,.Ane,as,,ly"z"'e,.d _ _cBvei_ _,CA.,,,,s..,N,,oc,,,_ 2Ja.L ReqLmt
Method: EPA 3810 Modified
ND ug/l
ND ug/1
ND ug/l
10.
20.
20.
06/10/02
06/10/02
06/10/02
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Service~. Inc.
MTG 74-82-8
MTG 74-84-0
MTG 74-85-1
Page: 10
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ww,,v;pacelabs.com
Lab Project Number: 1057877
Pace Analytlcal Sarvlces, Inc.
1700 Elm Street. Suite 200
Minneapolis, MN 55414
Phone· 612.61J7.1700
Fax: 612.61Jl.6444
Client Project ID: 9233015 PIEDMONT GEOLOGIC
PARAMETER FOOTNOTES
Not detected at or above adjusted reporting limit
Not Calculable
ND
NC
J
MDL
Estimated concentration above the adjusted method detection limit and below the adjusted reporting lWt
Adjusted Method Detection Limit
Date: 06/11/02
0 ,. ACCo•o
,:: c>~
ii_ _ _ . \1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
wtthout the written consent of Pace Analytical Services, Inc.
Page: 11
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ace Analytical™
www.pacelabs.com
QC Batch: 57971
QUALITY CONTROL DATA
Lab Project Number: 9233015
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Analysis Method: SH 62300
Analysis Description: GC voes in Water QC Batch Method: SM 62300
Associated Lab Samples: _· 922276217
922282645
922276225 922282611 922282629
922282652 922282710 922282728
922282637
922282785
METHOD BLANK: . 922289384
Associated Lab,. Samples:
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n·Butylbenzene
sec-Butyl benzene
tert-Butylbenzene
Carbon tetrachloride
Chl orobenzene
Chloroethane
Chloroform
Chloromethane
2·Chlorotoluene
4·Chlorotoluene
1.2-DibrolTK)-3-chloropropane
Dibromochloromethane
l.2·Dibromoethane (EDB)
Dibromomethane
l.2·Dichlorobenzene
1,3-Dichlorobenzene
1,4-0ichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1.2-0ichloroethane
l,l·Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
922276217
922282710
Units
ug/l
ug/l
ug/l
ug/1
ug/l
ug/l
ug/1
ug/l
ug/1
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
922276225 922282611 922282629 922282637
922282728 922282785
Blank Reporting
Result Limit Footnotes
ND 0.50
ND 0,50
NO 0.50
ND 0.50
ND 0.50
ND 0.50
ND 1.0
ND 0.50
ND 0.50
ND 0.50
ND 0,50
ND 0.50
ND 0.50
ND 2.0
ND 0.50
ND 0.50
ND 2.0
ND 0.50
ND 0.50
ND 0.50
ND 1.0
ND 1.0
ND 1.0
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,-ACc0• .-~-?iOt:iaC\t
922282645 922282652
Page: 138
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP EB7627
ace Analytical™
www.pacelabs.com
METHOD BLANK: 922289384
Associated Lab Samples: , 922?76217
Parameter
1.2-Dichloropropane
1,3-Dichloroprapane
t' ,J 2, 2-Di chl or_opropane
1.1-0,JC~lo~opropene
ci (1' .'3-Di chl oropropene
,,t'. ./ • /.~trans-1,3-D1chloropropene
.,,~(,-·' Di i sopropyl ether
Ethyl benzene
Hexachloro-1.3-butadiene
Isopropylbenzene (Cumene)
p·lsopropyltoluene
Methylene chloride
Methyl-tert-butyl ether
Naphthalene
922282710
Units
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
n-Prapyl benzene ug/1
Styrene ug/1
1.1.1.2-Tetrachloroethane ug/1
1.1.2.2-Tetrachloroethane ug/1
Tetrachloroethene ug/1
Toluene ug/1
1,2.3-Trichlorobenzene ug/1
1.2.4-Trichlorobenzene ug/1
1,1.l·Trichloroethane ug/1
1.1,2-Trichloroethane ug/1
Trichloroethene ug/1
Trichlorofluoromethane ug/1
1,2.3-Trichloropropane ug/1
1.2.4-Trimethylbenzene ug/1
1.3.5-Trimethylbenzene ug/1
Vinyl chloride ug/1
m&p•Xylene ug/1
o-Xylene ug/1
l·Chloro·3·fluorobenzene (S) t
Date: 06/29/02
... QUALITY CONTROL DATA
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Lab Project Number: 9233015
Client Project ID: NCSU Lot 86/2246
922276225 922282611 922282629
922282728 922282785
Blank
Result
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
106
Reporting
Limit Footnotes
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
2.0
0.50
1.0
2.0
0.50
2.0
0.50
0.50
0.50
0.50
0.50
0.50
2.0
2.0
0.50
0.50
0.50 -
0.50
0.50
0.50
0.50
0.50
0.50
0.50
922282637 922282645 922282652
Page: 139
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Laboratory Certification IDs
NC Wastewater 12 REPORT OF LABORATORY ANALYSIS Laboratory Certification IDs I
LA Wastewater 04034
NC Drinking Water 37706
SC 99006
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
1M •cco~ .-~~-f/Ot:ld.C\\
VA Drinking Water 213
FL NELAP E87627 I
I Pace Analytical Services, Inc.
ace Analytical™ 9800 Kincey Avenue, Suite 100 ,, Huntersville, NC 28078 I _,'QUALITY CONTROL DATA Phone: [phone] www.pacelabs.com Fax: [phone]
I Lab Project Number: 9233015
Client Project ID: NCSU Lot 86/2246
I LABORATORY CONTROL SAMPLE & LCSD:: ,922289392 922289400
Spike LCS LCSD LCS LCSD
I Parameter -· •·.' Units Cone. Result Result X Rec X Rec RPO Footnotes
Benzene ug/1 20.00 20.61 20.57 103 103 0
Bromobenzene ug/1 20.00 21.69 21.58 108 108 0
Bromochl oromethane.· ug/1 20.00 21.60 21.15 108 106 2 I Bro100dichlorcimethane ug/1 20.00 21.95 22.29 110 111 2
Bromofoqn ug/1 20.00 21.49 21.88 107 109 2
Bro~."1ethane ug/1 20.00 23.39 23.48 117 117 0 I n-8utylbenzene ug/1 20.00 20.41 21.09 102 105 3 ,~ -(.:se~ · Butyl benzene ug/1 20.00 20.29 21.09 101 105 4
1
•(_)·,. tert-Butyl benzene ug/1 20.00 21.44 22.08 107 110 3
I Carbon tetrachloride ug/1 20.00 20.99 21.31 105 107 2
Chlorobenzene ug/1 20.00 21.97 21.91 110 110 0
Chloroethane ug/1 20.00 21. 75 22.21 109 111 2
Chloroform ug/1 20.00 21.45 21.24 107 106 1
I Chloromethane ug/1 20.00 22.06 22.53 110 113 2
2-Chlorotoluene ug/1 20.00 20. 71 20.91 104 105 1
4-Chlorotoluene ug/1 20.00 20.93 21.28 105 106 2
I 1.2-Dibromo-3-chloropropane ug/1 20.00 21.97 20.88 110 104 5
Oibromochloromethane ug/1 20.00 21.51 21. 70 108 108 1
1,2-Dibromoethane (EDB) ug/1 20.00 21.15 21.05 106 105 0
Di bromomethane ug/1 20.00 21.00 21.60 105 108 3 I 1,2-Dichlorobenzene ug/1 20.00 21.95 21.93 110 110 0
l,3·Dichlorobenzene ug/1 20.00 22.15 22.45 111 112 1
1,4-Dichlorobenzene ug/1 20.00 21.49 21.73 107 109 1
I Dichlorodifluoromethane ug/1 20.00 17 .04 19.01 85 95 11
l,l·Dichloroethane ug/1 20.00 22.16 22.06 111 110 0
1.2-Dichloroethane ug/1 20.00 21.11 20.79 106 104 2
I l.l·Dichloroethene ug/1 20.00 21.03 21.23 105 106 1
cis-1.2-Dichloroethene ug/1 20.00 22.10 21.58 110 108 2
trans-1.2-Dichloroethene ug/1 20.00 22.63 22.80 113 114 1
1,2-Dichloropropane ug/1 20.00 21.84 22.54 109 113 3
I 1,3-Dichloropropane ug/1 20.00 21.93 21.99 110 110 0
2.2·Dichloropropane ug/1 20.00 20.45 20.06 102 100 2
1.l·Dichloropropene ug/1 20.00 21.07 22.03 105 110 4
I cis-1.3-0ichloropropene ug/1 20.00 21.37 21. 73 107 109 2
trans•l.3·Dichloropropene ug/1 20.00 21.65 21.91 108 110 1
Diisopropyl ether ug/l 20.00 19.83 20.01 99 100 1
H
Ethyl benzene ug/1 20.00 22,81 23.11 114 116 1
Date: 06/29/02 Page: 140
I
I LaboratQry Certification IDs REPORT OF LABORATORY ANALYSIS Laborato[)' Qertifi~atiQn ID,
NC Wastewater 12 LA Wastewater 04034
NC Drinking Water 37706 This report shall not be reproduced, except in full, VA Drinking Water 213
I SC 99006 without the written consent of Pace Analytical Services, Inc. FL NELAP E87627 ,~ AHo~ ~ ,, lei ,,
?ID aC\\
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078 ace Analytical™
www.pacelabs.com QUALITY CONTROL DATA Phone: [phone]
Fax: [phone]
LABORATORY CONTROL SAMPLE & LCSD:, 922289392 922289400
Parameter
Hexachl oro-1, 3 -butadi ~n,e
Isopropyl benzene (Cuine~e)
p·lsopropyltoluene' .. /'
Methylene chloride
Methyl ·teff'.'butyl ether
Nap~th?l ihe
n,Propylbenzene
r:-tst:Yrene ' .
Spike
Units S2!1f..:__
ug/1 20.00
ug/1 20.00
ug/1 20.00
ug/1 20.00
ug/1 20.00
ug/1 20.00
ug/1 20.00
ug/1 20.00
LCS
Result
22.48
20.89
20.08
21.45
20.03
21.55
20.47
21.10
Lab Project Number: 9233015
Client Project ID: NCSU Lot 86/2246
LCSD LCS LCSD
Result t Rec t Rec RPO Footnotes
22.54 112 113 0
21.48 104 107 3
20.98 100 105 4
21.49 107 107 0
19.95 100 100 0
21.31 108 107 I
21.18 102 106 3
21.47 106 107 2 . ~.>--· 1.1.1. 2-Tetrachloroethane ,,·· ug/1 20.00 21. 78 21.53 109 108 1
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1.l.2.2·Tetrachloroethane
Tetrachloroethene
Toluene
1.2.3-Trichlorobenzene
1,2,4-Trichlorobenzene
1.1.l·Trichloroethane
l.l.2·Trichloroethane
Tri ch l oroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1.2.4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
m&p•Xylene
a-Xylene
l·Chloro-3-fluorobenzene (S)
SAMPLE DUPLICATE: 922289426
Parameter
Benzene
B rmoobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Brornomethane
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
ug/1 20.00 22.32 22.30 112 112
ug/1 20.00 20.74 21.46 104 107
ug/1 20.00 19.90 19.72 100 99
ug/1 20.00 22.60 22.64 113 113
ug/1 20.00 21.53 21.63 108 108
ug/1 20.00 21.48 21.44 107 107
ug/1 20.00 22.12 22.21 Ill Ill
ug/1 20.00 21.09 21.33 105 107
ug/1 20.00 18.02 18.17 90 91
ug/1 20.00 22.58 22.37 113 112
ug/1 20.00 20.10 20.62 101 103
ug/1 20.00 20.62 20.97 103 105
ug/1 20.00 21. 74 21. 90 109 109
u9/l 40.00 44.27 45.04 Ill 113
ug/1 20.00 21.20 21.47 106 107
108 105
922282728 DUP
Units Result Result RPO Footnotes
ug/1 ND ND NC
u9/l ND ND NC
ug/1 ND ND NC
ug/1 ND ND NC
ug/1 ND ND NC
ug/1 ND ND NC
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
1M ACCo,9
._ .. <)~ ?i□elaa\
0
3
I
0
0
0
0
1
1
1
3
2
I
2
I
Page: 141
Laboratory Certification IDs I
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627 I
I
ace Analytical'"
www.pacelabs.com
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SAMPLE DUPLICATE: 922289426
Parameter
n-Butylbenzene
sec-Butyl benzene
tert-Butylbenzerie ·~
Carbon tetrachloride
Chlorobenzene' •'
Chloroethane /
/ . I Chloroform
•. /:,'Chl oromethane
· '\;.,--· 2-Chlorotoluene .,,,.• 4-Ch l oroto l uene I 1.2-0ibromo-3-chloropropane
Dibromochloromethane
1.2-Dibromoethane (EDB)
I Dibromomethane
1,2-Dichlorobenzene
1.3-Dichlorobenzene
I 1.4-Dichlorobenzene
Oichlorodifluoromethane
1.1-Dichloroethane
1.2-Dichloroethane I 1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
I 1.2-Dichloropropane
1.3-Dichloropropane
2.2-Dichloropropane
I l.l·Dichloropropene
cis-1,3-Dichloropropene
trans-1.3-0ichloropropene
Diisopropyl ether
I Ethyl benzene
Hexachlo.ro·l,3-butadiene
lsopropylbenzene (Cumene)
I p•lsopropyltoluene
Methylene chloride
Methyl-tert-butyl ether
I Naphthalene
Date: 06/29/02
I
I La!)Qri!tQrt C~rtificatiQn IDs
NC Wastewater 12
NC Drinking Water 37706
I SC 99DD6
Units
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/l
ug/l
ug/1
ug/l
ug/1
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/1
ug/l
ug/l
ug/l
ug/1
ug/l
ug/l
ug/l
ug/1
ug/l
ug/l
ug/l
'.QUALITY CONTROL DATA
Lab Project Number: 9233015
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
922282728 DUP
Result Result RPD Footnotes
ND ND NC
ND ND NC
ND ND NC
ND ND NC
ND ND NC
ND ND NC
ND ND NC
ND ND NC
ND ND NC
ND ND NC
ND ND NC
ND ND NC
ND ND NC
ND ND NC
ND ND NC
ND ND NC
ND ND NC
ND ND NC
ND ND NC
ND ND NC
ND ND NC
ND ND NC
ND ND NC
ND ND NC
ND ND NC
ND ND NC
ND ND NC
ND ND NC
ND ND NC
ND ND NC
ND ND NC
ND ND NC
ND ND NC
ND ND NC
ND ND NC
ND ND NC
ND ND NC
Page: 142
REPORT OF LABORATORY ANALYSIS Li!!lQrato[Y CertificatiQn IDs
LA Wastewater 04034 This report shall not be reproduced, except in full. VA Drinking Water 213 without the written consent of Pace Analytical Services, Inc. FL NELAP E87627 ,,. •Ceo• ~ / lei ,, 110 ac11
ace Analytical™
www.pacelabs.com
SAMPLE DUPLICATE: 922289426
Parameter Units
n-Propylbenzene ug/1
Styrene ,, ug/1
l.l.1,2-Tetrachloroethane ug/1
1,1,2.2-Tetrachloroethane ug/1 ,,
Tetrachl oi"o"ethene ug/1
Toluene./,,, ug/1 / ·,;:,-
L2·,3-Trichlorobenzene. ug/1 ,., .. .,,
...,,1,,..1~ 2. 4-Tri chlorobenzene ug/1 < ,,{/ 1.1,1-Trichloroethane ug/1 ,. 1,1,2-Trichloroethane ug/1
Trichloroethene ug/1
Trichlorofluoromethane ug/1
1.2,3-Trichloropropane ug/1
1.2,4-Trimethylbenzene ug/1
1.3,5-Trimethylbenzene ug/1
Vinyl chloride ug/1
m&p-Xylene ug/1
a-Xylene ug/1
l·Chloro-3-fluorobenzene (S) t
Date: 06/29/02
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
'QUALITY CONTROL DATA Phone: [phone]
Fax: [phone]
Lab Project Number: 9233015
Client Project ID: NCSU Lot 86/2246
922282728 DUP
Result Result RPD Footnotes
ND ND NC
ND ND NC
ND ND NC
ND ND NC
ND ND NC
ND ND NC
ND ND NC
ND ND NC
ND ND NC
ND ND NC
ND ND NC
ND ND NC
ND ND NC
ND ND NC
ND ND NC
ND ND NC
ND ND NC
ND ND NC
107 ll0
Page: 143
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Laboratory Certification IDs
NC Wastewater 12 REPORT OF LABORATORY ANALYSIS Laboratory Certification IDs I
LA Wastewater 04034
NC Drinking Water 37706
SC 99006
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,~ •~ca~
<>'~,. finelac\1
VA Drinking Water 213
FL NELAP E87627 I
ace Analytical™
www.pacelabs.com
QC Batch: 58071
QUALITY CONTROL DATA
Lab Project Number: 9233015
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Analysis Method: SM 62300
Analysis Description: GC voes in Water
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QC Batch Method: SM 62300
Associated Lab Samples: 922282801
922285176
922282819 922282959 922283007 922283023
922285184
METHOD BLANK: 922293824
Associated,,La9 Samples:
..,.,-,,·.,
I . P.~ramete~
.,/. Benzene
.· ~),.; · Bromobenzene
Bromochloromethane I
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Bromodichloromethane
Bromoform
Bromornethane
n-Butylbenzene
sec-Butyl benzene
tert·Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2 ·Chl oroto l uene
4-Chlorotoluene
1,2·Dibromo·3·chloropropane
Dibromochloromethane
1.2·Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-0ichlorobenzene
1.4-Dichlorobenzene
Dichlorodifluoromethane
1.l·Oichloroethane
1,2-Dichloroethane
1,l·Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1.2-Dichloropropane
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
922282B01
Units
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
922282819 922282959 922283007 922283023
Blank Reporting
Result Limit Footnotes
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 1.0
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 2.0
ND 0.50
ND 0.50
ND 2.0
ND 0.50
ND 0.50
ND 0.50
ND 1.0
ND 1.0
ND 1.0
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
1M ~C~Q~ .-~-~n~C\t
922285176 922285184
Page: 144
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
ace Analytical™ QUALITY CONTROL DATA
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
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www.pacelabs.com
METHOD BLANK: 922293824
Associated Lab Samples:
Parameter
1.3-Dichloropropane
2, 2-Di chl oropropaiu,·
1.1-Di chl or,opropene
cis-1.~:D~~hloropropene
trans:1. 3·.o; chl oropropene
Dii;ot~opyl ether
..,-;:' Ethyl benzene .<:;',',, Hexachloro-1.3-butadiene
Jsopropylbenzene (Cumene)
p-lsopropyltoluene
Methylene chloride
Methyl-tert-butyl ether
Naphthalene
n-Propyl benzene
Styrene
1.1.1.2-Tetrachloroethane
1.1.2.2-Tetrachloroethane
Tetrachloroethene
Toluene
1.2.3-Trichlorobenzene
1,2.4-Trichlorobenzene
1.1.l·Trichloroethane
1,1.2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1.2.3-Trichloropropane
1.2.4-Trimethylbenzene
1.3.5-Trimethylbenzene
Vinyl chloride
m&p-Xylene
o-Xylene
l-Chloro-3-fluorobenzene
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
· 9_22282801
Units
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
(S) t
Lab Project Number: 9233015
Client Project ID: NCSU Lot 86/2246
922282819 922282959 922283007 922283023
Blank Reporting
Result Limit Footnotes
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 2.0
ND 0.50
ND 1.0
ND 2.0
ND 0.50
ND 2.0
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 2.0
ND 2.0
ND 0.50
ND 0.50
ND 0.50
NO 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
104
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
922285176 922285184
Page: 145
Laboratory Certification IDs I
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627 I
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ace Analytical™
www.pace/abs.com , QUALITY CONTROL DATA
Lab Project Number:
Client Project JD:
LABORATORY CONTROL SAMPLE: 922293832
Spike LCS LCS
Parameter Units Cone. Result t Rec Footnotes
Benzene ug/l 20.00 19.99 100
Bromobenzene ug/l 20.00 20.38 102
Brornochl oromethan,e· ug/l 20.00 19.21 96
BrOIOOdi chl o_rOR)ethane ug/l 20.00 20.30 102
Bromoform->, ug/l 20.00 20.89 104
Bromolllethane ug/l 20.00 19.69 98
n-Butylbenzene ug/l 20.00 20.80 104 ,. '.,
· fSec-Butylbenzene ug/l 20.00 20.75 104
tert-Butylbenzene ug/l 20.00 21.39 107
Carbon tetrachloride Ug/l 20.00 19.29 96
Chlorobenzene ug/l 20.00 20.68 103
Chloroethane ug/l 20.00 19. 73 99
Chloroform ug/l 20.00 18.94 95
Chloromethane ug/l 20.00 20.64 103
2-Chlorotoluene ug/l 20.00 19.60 98
4-Chloroto luene ug/l 20.00 20.09 100
1.2-Dibromo-3-chloropropane ug/l 20.00 22.20 111
Dibromochloromethane ug/l 20.00 19.95 100
1.2-Dibromoethane (EDS) ug/l 20.00 19.88 99
Di bro100methane ug/l 20.00 19.58 98
1.2-Dichlorobenzene ug/l 20.00 21.21 106
1,3-Dichlorobenzene ug/l 20.00 20.82 104
1.4-0ichlorobenzene ug/l 20.00 20.61 103
Dichlorodifluoromethane ug/l 20.00 20.65 103
1,1-Dichloroethane ug/l 20.00 19.98 100
1,2-0ichloroethane ug/l 20.00 19.03 95
1.1-Dichloroethene ug/l 20.00 19.56 98
cis-1,2-Dichloroethene Ug/l 20.00 19.38 97
trans-1.2-0ichloroethene ug/l 20.00 20.41 102
. 1, 2-Di chl oropropane ug/l 20.00 19.95 100
1.3-Dichloropropane ug/l 20.00 20.27 101
2.2-Dichloropropane ug/l 20.00 20.70 104
1.1-Dichloropropene ug/l 20.00 19.98 100
cis-1.3-Dichloropropene ug/l 20.00 20.67 103
trans-1,3-Dichloropropene Ug/l 20.00 21.23 106
Diisopropyl ether ug/l 20.00 20.51 103
Ethyl benzene ug/l 20.00 22.42 112
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12 REPORT OF LABORATORY ANALYSIS
NC Drinking Water 37706
SC 99006
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
... .,~,,~ §,'1_,~~'
flO~aC\\
9233015
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
NCSU Lot 86/2246
Page: 146
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
ace Analytical™
www.pacelabs.com
LABORATORY CONTROL SAMPLE: 9~22938":i2
Parameter Units
Hexachl oro-1. 3 · butadiene-· ug/1
Isopropylbenzene_ (C~mene) ug/1
p-lsopropyltoluene• ug/1 ,,. ,-, Methylene chloride ug/1
Hethyl-te_r.t.-butyl ether ug/1
Naphthafone ug/l
n~PrOpY1benzene ug/l
,/;jt;rene ug/l
~;J,,.. 1.1.1.2-Tetrachloroethane ug/l
1.1.2.2-Tetrachloroethane ug/l
Tetrachl oroethene ug/l
Toluene ug/1
1,2.3-Trichlorobenzene ug/1
1.2.4-Trichlorobenzene ug/1
1.1,1-Trichloroethane ug/1
1.1.2-Trichloroethane ug/1
Trichloroethene ug/l
Trichlorofluorornethane ug/l
1.2,3-Trichloropropane ug/l
1.2.4-Trimethylbenzene ug/l
1.3,5-Trimethylbenzene ug/l
Vinyl chloride ug/1
m&p-Xylene ug/l
a-Xylene ug/1
1-Chloro-3-fluorobenzene (S)
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
Parameter Units
Benzene ug/1
Broroobenzene ug/1
Bromochloromethane ug/1
Bromodichloromethane ug/l
Bromoform ug/1
Bromomethane ug/1
Date: 06/29/02
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
·QUALITY CONTROL DATA Phone: [phone]
Fax: [phone]
Lab Project Number: 9233015
Client Project ID: NCSU Lot 86/2246
Spike LCS LCS
Cone. Result X Rec Footnotes
20.00 21.32 107
20.00 20.86 104
20.00 20.48 102
20.00 19.08 95
20.00 20.11 101
20.00 19.27 96
20.00 20.73 104
20.00 20.88 104
20.00 20.17 101
20.00 21.37 107
20.00 19.62 98
20.00 19.96 100
20.00 21.06 105
20.00 20.90 105
20.00 19.14 96
20.00 20.91 105
20.00 18.86 94
20.00 18.24 91
20.00 21. 14 106
20.00 20.11 101
20.00 20.43 102
20.00 19.80 99
40.00 43.95 110
20.00 20.88 104
102
922293899 922293907
922282801 Spike HS HSD HS HSD
Result Cone. Result Result t Rec t Rec RPD Footnotes
0 20.00 19.41 19.17 97 96 1
0 20.00 20.55 20.83 103 104 1
0 20.00 19.41 20.04 97 100 3
0 20.00 20.43 21. 78 102 109 6
0 20.00 20.23 21.98 101 110 8
0 20.00 18.86 21.45 94 107 13
Page: 147
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Laboratory Certification IDs
NC Wastewater 12 REPORT OF LABORATORY ANALYSIS Laboratory Certification IDs I
LA Wastewater 04034
NC Drinking Water 37706
SC 99006
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc. VA Drinking Water 213
FL NELAP E87627 I
I Pace Analytical Services, Inc.
ace Analytical™ 9800 Kincey Avenue, Suite 100
,•i Huntersville, NC 28078 I , QUALITY CONTROL DATA Phone: [phone] www.pacelabs.com Fax: 704.875.909t
I Lab Project Number: 9233015
Client Project ID: NCSU Lot 86/2246
I MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 922293899 922293907
922282801 Spike MS MSD MS MSD
I Parameter Units Result Cone. Result Result t Rec t Rec RPD Footnotes
n-Butylbenzene ug/1 0 20.00 20.19 20.07 101 100 1
sec-Butyl benzene.• ug/1 0 20.00 20.18 20.15 101 101 0
tert-Butyl ben~el1~/ ug/1 0 20.00 21.14 20.68 106 103 2 I Carbon tetrachloride ug/1 0 20.00 20.07 ·21.31 100 106 6 .! •.. , ug/1 4 Chlorob~nzene 0 20.00 20.18 21.09 101 105
Chloroethane ug/1 0 20.00 20.36 21.96 102 110 8 I Chl~riiform ug/1 0 20.00 18.93 20.09 95 100 6
/chloromethane ug/1 0 20.00 21.65 22.17 108 111 2 -~>/ 2-Chlorotoluene ug/1 0 20.00 19.33 20.01 97 100 3
I 4-Chlorotoluene ug/1 0 20.00 19.75 20.02 99 100 1
1.2-0ibromo-3-chloropropane ug/1 0 20.00 21.93 21.61 110 108 1
Oibromochloromethane ug/1 0 20.00 19.57 20.36 98 102 4
1.2-0ibromoethane (EDB) ug/1 0 20.00 19.25 19.88 96 99 3
I Dibromomethane ug/1 0 20.00 19.44 20.62 97 103 6
1.2-0ichlorobenzene ug/1 0 20.00 21.10 20.62 106 103 2
1,3-0ichlorobenzene ug/1 0 · 20.00 19. 73 20.32 99 102 3
I 1,4-0ichlorobenzene u9/1 0 20.00 19.42 19.97 97 100 3
Dichlorodifluorornethane ug/1 0 20.00 20.12 23.48 · 101 117 15
1.1-Dichloroethane ug/1 0 20.00 20.53 21.47 103 107 4
1.2-0ichloroethane ug/1 0 20.00 19.21 19.97 96 100 4 I l.l·Oichloroethene ug/1 0 20.00 20.11 21.49 100 107 7
cis-1,2-Dichloroethene ug/1 0 20.00 19.70 20.55 98 103 4
trans-1,2-Dichloroethene ug/1 0 20.00 21.03 22.17 105 111 5
I 1.2-0ichloropropane ug/1 0 20.00 19.98 21.15 100 106 6
1.3-0ichloropropane ug/1 0 20.00 20.02 20.55 100 103 3
2.2-Dichloropropane ug/1 0 20.00 18.58 19.19 93 96 3
I 1.1-~ichloropropene ug/1 0 20.00 20.62 21. 78 103 109 5
cis-1.3-Dichloropropene ug/1 0 20.00 17.64 18.40 88 92 4
trans-1.3-Dichloropropene ug/1 0 20.00 19. 99 20.39 100 102 2
Diisopropyl ether ug/1 0 20.00 19.17 18.65 96 93 3 I Ethyl benzene ug/1 0 20.00 21.57 22.31 108 112 3
Hexachloro-1.3-butadiene ug/1 0 20.00 22.23 22.65 111 113 2
lsopropylbenzene (Cumene) ug/1 0 20.00 20.07 20.34 100 102 1
I p-lsopropyltoluene ug/1 0 20.00 19.71 19.69 99 98 0
Methylene chloride ug/1 0 20.00 19.16 19.99 96 100 4
Methyl-tert-butyl ether ug/1 0 20.00 19.11 18.79 96 94 2
I Naphthalene ug/1 0 20.00 21.22 20.25 106 101 5
Date: 06/29/02 Page: 148
I
I Laboratory Certifi,atiQn IDs REPORT OF LABORATORY ANALYSIS LabQratory Certifi,atiQn ID~
NC Wastewater 12 LA Wastewater 04034
NC Drinking Water 37706 This report shall not be reproduced, except in full, VA Drinking Water 213
I SC 99006 without the written consent of Pace Analytical Services, Inc. FL NELAP E87627 ~ •''] re, iineac11
Pace Analytical Services, Inc. I
ace Analytical™ 9800 Kincey Avenue, Suite 100
Huntersville, NC 28078 I QUALITY CONTROL DATA Phone: [phone] www.pacelabs.com Fax: [phone]
Lab Project Number: 9233015 I Client Project ID: NCSU Lot 86/2246
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 922293899 922293907 I
922282801 Spike MS MSD MS MSD
Parameter Units Result Cone. Result Result t Rec t Rec RPO Footnotes I n-Propylbenzene ug/1 0 20.00 19.91 19.93 100 100 0
Styrene ug/1 0 20.00 19.35 19.42 97 97 0
1. 1, 1. 2 • Tetra,hlo_roethane ug/1 0 20.00 19.49 20.70 98 104 6 I 1.1. 2, 2-Tetrachloroethane ug/1 0 20.00 21.82 21.99 109 110 1
T et rach l of9~"thene ug/1 0 20.00 19.67 20.48 98 102 4 Toluene,:✓ ug/1 0 20.00 19.43 19.14 97 96 1
1,{3. Trichlorobenzene ug/1 0 20.00 22.34 21.56 112 108 4 I _,,.,~;1j.,4. Trichlorobenzene ug/1 0 20.00 21.27 20.09 106 100 6 ,, ,-~ 1,1,l•Trichloroethane ug/1 0 20.00 19.74 20.89 99 104 6 ,0.:..:y
/ 1,1,2-Trichloroethane ug/1 0 20.00 20.25 21.12 101 106 4
Trichloroethene ug/1 0 20.00 19.09 20.16 95 101 5 I Trichlorofluorornethane ug/1 0 20.00 18.05 20.04 90 100 10
1.2.3-Trichloropropane ug/1 0 20.00 21.02 21.52 105 108 2
1,2.4-Trimethylbenzene ug/1 0 20.00 19.31 18.84 96 94 2 I 1,3,5-Trimethylbenzene ug/1 0 20.00 19.35 19.10 97 96 1
Vinyl chloride ug/1 0 20.00 21.52 23.38 108 117 8
m&p-Xylene ug/1 0 40.00 41.35 42.51 103 106 3 I o-Xyl ene ug/1 0 20.00 19.85 20.16 99 101 2
l·Chloro-3-fluorobenzene (S) 102 107
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Date: 06/29/02 Page: 149
I
Laboratoey C~rtification IDs REPORT OF LABORATORY ANALYSIS LabQratoey Qertification IDs I NC Wastewater 12 LA Wastewater 04034
NC Drinking Water 37706 This report shall not be reproduced, except in full, VA Drinking Water 213
SC 99006 without the written consent of Pace Analytical Services, Inc. FL NELAP E87627 I ,~ Acco.., ,«eir-·1n c· '!, . . \,
I
e
I ace Analytical™ QUALITY CONTROL DATA
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone] www.pacelabs.com
I
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I
I
QC Batch: 58142
QC Batch Method: SM 62300
Associated Lab Samples: 1,
METHOD BLANK: ,922297049
Associated Lab. i;"~~P l es:
I /:. ,;.;'~:~ter
I'' ,' ... ,.:j:·· ,. Benzene . ,·
I Bromobenzene
Bromochloromethane
Bromodichlorornethane
Bromoform
I Bromomethane
n-Butylbenzene
sec-Butyl benzene
I tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane I Chloroform
Chl oromethane
2·Chlorotoluene
I 4-Chlorotoluene
1.2-0ibromo-3-chloropropane
Oibromochloromethane
I 1.2-Dibromoethane (EDB)
Dibromomethane
1.2-Dichlorobenzene
1.3-Dichlorobenzene
I 1.4-0ichlorobenzene
Dichlorodifluoromethane
l.l·Dichloroethane
I 1.2-Dichloroethane
1.1-Dichloroethene
cis-1.2-Dichloroethene
I trans-1.2-0ichloroethene
Date: 06/29/02
I
I LabQratQ[ll CertifiCiltiOn ID,
NC Wastewater 12
NC Drinking Water 37706
I SC 99006
Lab Project Number: 9233015
Client Project ID: NCSU Lot 86/2246
922282793
922285226
Analysis Method: SM 62300
Analysis Description: GC voes in Water
922283015 922285192 922285200 922285218
922293261 922293279
922282793' 922283015 922285192 922285200 922285218
922293279
Blank Reporting
Units Result Limit Footnotes
ug/l ND 0.50
ug/l ND 0.50
ug/l ND 0.50
ug/l ND 0.50
ug/l ND 0.50
ug/l ND 0.50
ug/1 ND 1.0
ug/l ND 0.50
ug/l ND 0.50
ug/l ND 0.50
ug/l ND 0.50
ug/l ND 0.50
ug/1 ND 0.50
ug/l ND 2.0
ug/l ND 0.50
ug/1 ND 0.50
ug/l ND 2.0
ug/l ND 0.50
ug/1 ND 0.50
ug/l ND 0.50
ug/l ND 1.0
ug/l ND 1.0
ug/l ND 1.0
ug/l ND 0.50
ug/l ND 0.50
ug/l ND 0.50
ug/l ND 0.50
ug/1 ND 0.50
ug/l ND 0.50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
1M ~cco., ..,.-:.~ ___../1el •e,
I/0 aC\\
922285226 922293261
Page: 150
LagQratQ[ll CertificatiQn ID,
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
.,
, ,
ace Analytical™
www.pacelabs.com
METHOD BLANK:· 922297049
Associated Lab Samples: '922282793
:· 922293279
Parameter Units
1. 2 · Di chl oroprop.ane' ug/l
1, 3 ·Di chlorol)rop~ne ug/l
2.2·Dichlo~opropane ug/l
1, 1 :.Di.§hl ~ropropene ug/l
Ci S~-r. 3-Di chl oropropene ug/l <' ~-
.. /_):rans-!. 3-Di chl oropropene ug/l _, , .. , piisopropyl ether ug/1
Ethyl benzene ug/1
Hexachloro·l.3·butadiene ug/1
Isopropylbenzene (Cumene) ug/l
p-lsopropyltoluene ug/1
Methylene chloride ug/l
Methyl•tert-butyl ether ug/l
Naphtha] ene ug/1
n-Propylbenzene ug/1
Styrene ug/1
l.l.l,2·Tetrachloroethane ug/l
1.1.2,2-Tetrachloroethane ug/1
Tetrachloroethene ug/l
Toluene ug/1
1,2,3-Trichlorobenzene ug/1
1,2.4-Trichlorobenzene ug/1
1.1.1-Trichloroethane ug/1
1,1.2-Trichloroethane ug/1
Trichloroethene ug/l
Trichlorofluoromethane ug/1
1,2.3-Trichloropropane ug/l
1.2.4-Trimethylbenzene ug/l
1,3,5-Trimethylbenzene ug/1
Vinyl chloride ug/1
m&p-Xylene ug/1
o-Xyl ene ug/l
l·Chloro-3-fluorobenzene (S) X
Date: 06/29/02
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
'QUALITY CONTROL DATA Phone: [phone]
Fax: [phone]
Lab Project Number: 9233015
Client Project ID: NCSU Lot 86/2246
922283015 922285192 922285200 922285218 922285226 922293261
Blank Reporting
Result Limit Footnotes
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 2.0
ND 0.50
.ND 1.0
ND 2.0
ND 0.50
ND 2.0
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 2.0
ND 2.0
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
104
Page: 151
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Laboratory Certification IDs
NC Wastewater 12 REPORT OF LABORATORY ANALYSIS Laboratory Certification IDs I
LA Wastewater 04034
NC Drinking Water 37706
SC 99006
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,,. Hco~
0•fC~-?11J~C1\
VA Drinking Water 213
FL NELAP E87627 I
I
ace Analytical™
www.pace/abs.com
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LABORATORY CONTROL SAMPLE: 9222970.56
I
Parameter
Benzene
Bromobenzene
Bromochloromethane,
Brornodichloromethane
Bromoform /
Bromomethane
/ .• I n,7Bu'tyi' benzene
_.., ~,;-·se'c·Butylbenzene
,,-:_,,..-, tert-Butylbenzene
! .,.. Carbon tetrachloride
I Chlorobenzene
Chloroethane
Chloroform
Chloromethane'
2-Chlorotoluene
4-Chloroto luene
1.2-Dibromo-3-chloropropane
Oibromochloromethane
1.2-Dibromoethane (ED8)
Oibromomethane
1,2-Dichlorobenzene
1.3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
l,l·Dichloroethene
cis-1.2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1.3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethyl benzene
Date: 06/29/02
Units
u9/l
ug/l
ug/l
ug/1
ug/l
ug/1
ug/1-
ug/l
ug/1
Ug/l
Ug/1
ug/l
u9/l
ug/l
Ug/l
Ug/l
ug/l
u9/l
ug/l
ug/l
ug/1
ug/l
ug/1
ug/l
ug/l
ug/1
ug/l
ug/l
ug/l
ug/l
ug/1
ug/l
ug/1
ug/l
ug/l
ug/l
ug/l
Pace Analytical Services. Inc.
9800 Kincey Avenue. Suite 100
Huntersville. NC 28078
QUALITY CONTROL DATA Phone: [phone]
Fax: [phone]
Lab Project Number: 9233015
Client Project ID: NCSU Lot 86/2246
Spike LCS LCS
Cone. Result t Rec Footnotes
20.00 19.48 97
20.00 19.93 100
20.00 19.37 97
20.00 20.25 101
20.00 21.29 106
20,00 18.19 91
20.00 20,22 101
20.00 20.01 100
20.00 20.84 104
20,00 18.90 94
20.00 21.14 106
20,00 18.47 92
20.00 19.10 96
20.00 19.01 95
20,00 18.87 94
20.00 19.62 98
20,00 23.14 116
20.00 20.51 103
20.00 20.45 102
20.00 19,07 95
20.00 21.36 107
20.00 20.60 103
20.00 20,20 101
20.00 17,72 89
20.00 19.88 99
20.00 18,91 95
20.00 17.85 89
20,00 19.56 98
20.00 19.85 99
20.00 19,61 98
20.00 20.82 104
20.00 20.42 102
20.00 19.85 99
20.00 21.07 105
20.00 20.97 105
20.00 20.32 102
20.00 22.18 111
Page; 152
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Laboratory Certification IDs
NC Wastewater 12 REPORT OF LABORATORY ANALYSIS Laboratory Certification IDs
LA Wastewater 04034
· NC Drinking Water 377D6
SC 99006
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc. VA Drinking Water 213
FL NELAP E87627
ace Analytical™
www.pacelabs.com
LABORATORY CONTROL SAMPLE: 922297956
Parameter
Hexachloro-1.3-buta,dfen~'°
lsopropylbenzene (Cumene)
p-Isopropyltoluene·
Methylene chloride
Methyl-tert-butyl ether
Naphthalen~
Units
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1 n · p·;opyl benzene
. / ::,·s~i.Yrene
.. ~;_.:.:~ · ~ 1.1.1, 2-Tetrachloroethane
ug/1
ug/1 + 1.1.2.2-Tetrachloroethane
Tetrachloroethene
Toluene
1.2,3-Trichlorobenzene
1.2.4-Trichlorobenzene
1,1,l·Trichloroethane
1.l,2·Trichloroethane
Trichloroethene
Trichlorofluoromethane
1.2.3-Trichloropropane
1.2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
m&p-Xylene
o-Xylene
l·Chloro-3-fluorobenzene (S)
SAMPLE DUPLICATE: 922297064
Parameter
Benzene
Bromobenzene
Bromochloromethane
Bromodichlorornethane
Bromoform
Bromomethane
Date: 06/29/02
ug/1
ug/l
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
Units
ug/1
ug/1
ug/1
ug/1
ug/1
ug/l
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
· .. QUALITY CONTROL DATA Phone: [phone]
Fax: [phone]
Lab Project Number: 9233015
Client Project ID: NCSU Lot 86/2246
Spike LCS LCS
Cone. Result X Rec Footnotes
20.00 20.94 105
20.00 20.17 101·
20.00 19.93 100
20.00 19.14 96
20.00 20.16 101
20.00 20.84 104
20.00 20.18 101
20.00 20.65 103
20.00 20.53 103
20.00 21.55 108
20,00 19.36 97
20.00 19.03 95
20.00 21.34 107
20,00 22.21 111
20.00 18.96 95
20.00 21.24 106
20.00 18.04 90
20.00 15.88 79
20.00 21.28 106
20.00 19.65 98
20.00 19.78 99
20.00 18.59 93
40.00 42.46 106
20.00 20.39 102
106
922285200 DUP
Result Result RPO Footnotes
ND NO NC
ND ND NC
ND ND NC
ND ND NC
ND ND NC
ND ND NC
Page: 153
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Laboratory Certification IDs
NC Wastewater 12 REPORT OF LABORATORY ANALYSIS Laboratory Certification IDs · 1
LA Wastewater 04034
NC Drinking Water 37706
SC 99006
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc. VA Drinking Water 213
FL NELAP E87627 I
ace Analytical™
www.pacelabs.com
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SAMPLE DUPLICATE: 922297064
Parameter
n-Butylbenzene
sec-Butylbenzene •
tert-Butyl benzene',,. I carbon tetraChloride
ChlorobenZE!ne'
~ ;,
Chloroethane
I Chi'oroform
. /'.ctiloromethane
-.:i ,.. 2-Chlorotoluelle
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4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1.2-Dibromoethane (EDB)
Di bromomethane
1,2-Dichlorobenzene
1.3-Dichlorobenzene
1,4-0ichlorobenzene
Dichlorodifluoromethane
1.1-Dichloroethane
1,2-0ichloroethane
1.1-0ichloroethene
cis-1.2-Dichloroethene
trans-1.2-0ichloroethene
1.2-0ichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1.3-Dichloropropene
trans-1,3-0ichloropropene
Diisopropyl ether
Ethyl benzene
Hexachloro-1.3-butadiene
lsopropylbenzene (Cumene)
p-lsopropyltoluene
Methylene chloride
Methyl-tert-butyl ether
Naphthalene
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
Units
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/1
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/1
ug/l
ug/l
ug/l
ug/1
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/1
ug/l
ug/l
ug/l
ug/l
ug/l
ug/1
ug/l
ug/l
ug/l
ug/l
QUALITY CONTROL DATA
Lab Project Number: 9233015
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
· Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
922285200 DUP
Result Result RPO Footnotes
NO NO NC
NO ND NC
ND ND NC
ND NO NC
ND ND NC
NO NO NC
160.0 140,0 16
NO ND NC
ND ND NC
ND NO NC
ND ND NC
ND ND NC
ND ND NC
ND ND NC
ND ND NC
ND ND NC
ND ND NC
NO NO NC
NO ND NC
ND NO NC
ND ND NC
ND ND NC
ND ND NC
1.900 2.000 7
ND ND NC
ND ND NC
ND ND NC
ND ND NC
ND ND NC
ND ND NC
ND ND NC
ND ND NC
ND ND NC
ND ND NC
ND ND NC
ND ND NC
ND NO NC
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,_ HCo~
:'~~ .. ?1nelac11
Page: 154
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
ace Analytical™
ll)UALITY CONTROL DATA www.pacelabs.com
SAMPLE DUPLICATE: 922297064
I
Parameter ,• _,,
n-Propylbenzene
Styrene ~/,,, '
1.1.1.2-Tetra,hloro·ethane
1.1. 2. 2-Tetrachl.oroethane
/ Tetrachl or~ethene ··: r Toluerie·-•'
1{2 ;i·"Tri chl orobenzene
/<,T:2 .4· Trichlorobenzene
A:.,;:;,' 1.1.1-Trichloroethane
1.1.2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1.2,3-Trichloropropane
1.2.4-Trimethylbenzene
1.3.5-Trimethylbenzene
Vinyl chloride
rr&p-Xylene
o-Xylene
1-Chloro-3-fluorobenzene (S)
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
,•.:,,,.;
/
Units
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
l
Lab Project Number:
Client Project ID:
922285200 DUP
Result Result RPD Footnotes
ND ND NC
ND ND NC
ND ND NC
ND ND NC
1.200 ND NC
ND ND NC
ND ND NC
ND ND NC
ND ND NC
ND ND NC ·
ND ND NC
ND ND. NC
ND ND NC
ND ND NC
ND ND NC
ND ND NC
ND ND NC
ND ND NC
93 99
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,. •tea~ t(S_~~ t1nelac\t
9233015
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suile 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
NCSU Lot 86/2246
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Page: 155
Laboratory Certification IDs I
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627 I
I
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I
ace Analytical™ . ,QUALITY CONTROL DATA
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville. NC 28078
Phone: [phone]
Fax: [phone] www.pacelabs.com
QC Batch: 58187
QC Batch Method: SM 62300
Associated Lab Samples:
METHOO BLANK:. 92.2299110
Associated lab Samples:
(.-;. .
l_,,:·;;;:.~eter
/ 1·· •• Benzene . ,
I Bromobenzene
Bro100chloromethane
Bromodichloromethane
Bromoform
I Bromomethane
n ·Butyl benzene
sec-Butyl benzene
I tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
I Chloroform
Chloromethane
2-Chlorotoluene
I 4-Chlorotoluene
l,2-Dibrorna-3-chloropropane
Oibromochloromethane
I 1,2-Dibromoethane (EDB)
Di bromomethane
1,2-Dichlorobenzene
1.3-Dichlorobenzene
I 1,4-0ichlorobenzene
Dichlorodifluoromethane
1.1-Dichloroethane
I 1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
I
Date: 06/29/02
I
I Laboratory CertificatiQn IDs
NC Wastewater 12
NC Drinking Water 37706
I SC 99006
Lab Project Number: 9233015
Client Project ID: NCSU Lot 86/2246
Analysis Method: SM 62300
Analysis Description: GC VOCs in Water
. 922293188
922293303
922293204 922293220 922293287 922293295
922293329 922293345 922293386
922293188 922293204 922293220 922293287 922293295
922293345 922293386
Units
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
Blank Reporting
Result Limit Footnotes
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 1.0
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 2.0
ND 0.50
ND 0.50
ND 2.0
ND 0.50
ND 0.50
ND 0.50
ND 1.0
ND 1.0
ND 1.0
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
.,.,~~ .. •'°0-1". y, ?iD~aC%
922293303 922293329
Page: 156
LabQratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
ace Analytical™
www.pacelabs.com
,• ,1;: -. ,
QUALITY CONTROL DATA
Lab Project Number: 9233015
Pace Analytical Services, Inc.
9800 Kincey Avenue. Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
METHOD BLANK: 922299110
Associated Lab Samples: 922293188 922293204 922293220 922293287 922293295 922293303 922293329
_922293345 922293386
Blank Reporting
Parameter Units Result Limit Footnotes
1.2-Dichloropr.opane' ug/1 ND 0.50
1, 3 · Di chl or:oJ)r_opane ug/1
2.2·Dichl0rop~opane ug/1 , '
ND 0.50
ND 0.50
1. 1-.Dfi:hl bropropene ug/1
.. ci _t-_1:.:~3 · Di chl oropropene ug/1
ND 0.50
ND 0.50
.,...A-')itfans-1. 3-0i chl oropropene ug/1 ND 0.50
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.--( .. ··'
;•~-... Di i sopropyl ether
Ethyl benzene
Hexachloro-1,3-butadiene
Isopropylbenzene (Cumene)
p-Isopropyltoluene
Methylene chloride
Methyl-tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1.1.2-Tetrachloroethane
1,1,2.2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1.2.4-Trichlorobenzene
1,1,1-Trichloroethane
1.1.2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1.2.3-Trichloropropane
1.2.4-Trimethylbenzene
1.3.5-Trimethylbenzene
Vinyl chloride
m&p-Xylene
a-Xylene
l-Chloro-3-fluorobenzene (S)
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
\
ND 0.50
ND 0.50
ND 2.0
ND 0.50
ND 1.0
ND 2.0
ND 0.50
ND 2.0
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 2.0
ND 2.0
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
97
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Page: 157
Laboratory Certification IDs I
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627 I
I
ace Analytical"'
www.pacelabs.com
I
· QUALITY CONTROL DATA
Lab Project Number: 9233015
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot B6/2246
I LABORATORY CONTROL SAMPLE: 922299128
I Parameter
Benzene
Bromobenzene
Bromochloromethan'e ·
I BromodichlgrOmethane
Bromoform· ,·
Bro~nfe\hane I n,Butylbenzene •' / ,('<:,,.sec-Butyl benzene
_: ~,.:,--tert-Butylbenzene
I Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
I Chloromethane
2-Chlorotoluene
4-Chlorotoluene
I 1.2-Dibromo-3-chloropropane
Dibromochloromethane
1.2-Dibromoethane (EDB)
Dibromomethane I 1.2-Dichlorobenzene
1.3-Dichlorobenzene
1,4-Dichlorobenzene
I Oichlorodifluoromethane
l,l·Dichloroethane
1.2-Dichloroethane
I l,l·Dichloroethene
cis·l.2-Dichloroethene
trans-1,2-Dichloroethene
1.2-Dichloropropane
I 1.3-Dichloropropane
2.2-Dichloropropane
1.l·Dichloropropene
I cis-1.3-Dichloropropene
trans-1.3-Dichloropropene
Diisopropyl ether
I Ethyl benzene
Date: 06/29/D2
I
I Labor~tO[ll Q~rtification !Os
NC Wastewater 12
NC Drinking Water 37706
I SC 99006
Spike LCS LCS
Units Cone. Result t Rec Footnotes
ug/1 20.00 19.13 96
ug/1 20.00 19.9B 100
ug/1 20.00 19.23 96
ug/1 20.00 20.64 103
ug/1 20.00 21.54 108
Ug/1 20.00 18.43 92
ug/1 20.00 20.01 100
ug/1 20.00 19. 77 99
ug/1 20.00 20.46 102
ug/1 20.00 18.92 95
ug/1 20.00 20. 76 104
ug/1 20.00 19.12 96
ug/1 20.00 1B.91 95
ug/1 20.00 18.47 92
ug/1 20.00 19.05 95
ug/1 20.00 19.6B 9B
ug/1 20.00 22.49 112
ug/1 20.00 19.97 100
ug/1 20.00 20.19 101
ug/1 20.00 19.39 97
ug/1 20.00 21.07 105
ug/1 20.00 20.12 101
ug/l 20.00 19.93 100
ug/1 20.00 18.14 91
ug/1 20.00 20.21 101
ug/1 20.00 1B. 75 94
ug/1 20.00 18.74 94
ug/l 20.00 19.37 97
ug/1 20.00 20.36 102
ug/1 20.00 20.06 100
ug/1 20.00 20.51 103
ug/1 20.00 20.19 101
ug/1 20.00 19.60 9B
ug/l 20.00 20.89 104
ug/1 20.00 20.70 103
ug/1 20.00 19.95 100
ug/1 20.00 21.83 109
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,-Hee~ ~ ~nelaat
Page: 158
Laborato[ll Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
:~'
ace Analytical™
www.pacelabs.com
LABORATORY CONTROL SAMPLE: 922299128
Parameter Units
Hexachloro-1,3-butadiene ug/1
I sopropyl benzene (Cum~~e) ug/1
p· Isopropyl tol ue~e>. u9/l
Methylene ~hlqride u9/l
Methyl -ter_t-butyl ether ug/1
Naphtha 1 e~e ug/1 ,--,., n-Propylbenzene ug/1 •• r'"
, .,r:t?:styrene u9/l ,,. 1.1.1.2-Tetrachloroethane u9/l
1,1,2,2-Tetrachloroethane ug/1
Tetrachloroethene ug/1
Toluene u9/l
1,2,3-Trichlorobenzene ug/1
1,2,4-Trichlorobenzene ug/1
1.1,1-Trichloroethane ug/1
1.1,2-Trichloroethane ug/1
Tri chl oroethene ug/1
Trichlorofluorornethane ug/1
1.2,3-Trichloropropane ug/1
1,2.4-Trimethylbenzene ug/1
1,3,5-Trimethylbenzene ug/1
Vinyl chloride ug/1
m&p-Xylene ug/1
a-Xylene ug/1
l-Chloro-3-fluorobenzene (S)
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
Parameter
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
Oate: 06/29/02
Units
ug/1
ug/1
ug/1
ug/1
u9/l
ug/1
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
'QUALITY CONTROL DATA Phone: [phone]
Fax: [phone]
Lab Project Number: 9233015
Client Project ID: NCSU Lot 86/2246
Spike LCS LCS
Cone. Result X Rec Footnotes
20.00 21.92 110
20.00 20.31 102
20.00 19.71 99
20.00 18.68 93
20.00 19.54 98
20.00 19.69 98
20.00 20.22 101
20.00 20.45 102
20.00 20.08 100
20.00 21.68 108
20.00 18.98 95
20.00 19.49 97
20.00 21.24 106
20.00 21.48 107
20.00 18.91 94
20.00 20.68 103
20.00 18.74 94
20.00 17 .59 88
20.00 21.57 108
20.00 19.30 96
20.00 19.63 98
20.00 19.29 96
40.00 42.59 106
20.00 20.17 101
104
922299136 922299144
922293220 Spike MS HSD MS MSD
Result Cone. Result Result X Rec X Rec RPD Footnotes
773.2 20.00 19320 19740 9274094840 2 1,1
0 20.00 19, 78 19.50 99 98 1
0 20.00 18.71 19.05 94 95 2
0 20.00 21.67 22.30 108 112 3
0 20.00 21.19 21.42 106 107 1
0 20.00 19.46 20.86 97 104 7
Page: 159
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Laboratory Certification IDs
NC Wastewater 12 REPORT OF LABORATORY ANALYSIS Laboratory Certification IDs I
LA Wastewater 04034
NC Drinking Water 37706
SC 99006
This report shall not be reproduced, except in full,
without the written consent of Pace Analylical Services, Inc.
1M •cca~ ~~~ i1nelaa1
VA Drinking Water 213
FL NELAP E87627 I
I Pace Analytical Services, Inc.
ace Analytical™ , 9800 Kincey Avenue, Suite 100
1: Huntersville, NC 28078
QUALITY CONTROL DATA Phone: [phone] www.pacelabs.com Fax: [phone]
I Lab Project Number: 9233015
Client Project ID: NCSU Lot 86/2246
I MATRIX SPIKE & MATRIX SPIKE DUPl!CATE: 922299136 922299144
922293220 Spike MS MSD MS MSD
I Parameter Units Result Cone. Result Result X Rec X Rec RPO Footnotes
n-Butylbenzene ug/l 0 20.00 18.80 18.16 94 91 4
sec-8utylbenzene ug/l 0 20.00 19.31 18.84 96 94 2
tert·Butylbenzene ug/l 0 20.00 20.50 19.90 102 100 3
I Carbon tetrac~loride ug/l 1575 20.00 20410 21070 9416097460 3
Chl orobeniene ug/l 0 20.00 20.47 19.84 102 99 3
Ch l oroetha ne ug/l 0 20.00 20.53 20.92 103 105 2 I Chi'oroform ug/l 17300 20.00 33580 37630 81390101600 11 ✓/ chforomethane ug/l 0 20.00 19.26 19.34 96 97 0
, --~' , 2-Chlorotoluene ug/l 0 20.00 17 .97 18.30 90 92 2 l." 4-Chl oroto l uene ug/l 0 20.00 18.25 18.57 91 93 2 I 1,2-Dibromo-3-chloropropane ug/l 0 20.00 22.61 23.13 113 116 2
Dibromochloromethane ug/l 0 20.00 20.14 20.53 101 103 2
1.2-Dibromoethane (ED8) ug/l 1186 20.00 20310 20830 9561098210 3
I Di bromomethane ug/l 0 20.00 19.54 19.97 98 100 2
1.2-Dichlorobenzene ug/l 0 20.00 21.62 21.12 108 106 2
1,3·Dichlorobenzene ug/l 0 20.00 19.47 19.43 97 97 0
I 1.4-0ichlorobenzene ug/l 0 20.00 19.38 19.28 97 96 I
Dichlorodifluoromethane ug/l 0 20.00 21.01 21.89 105 109 4
1.1-Dichloroethane ug/l 0 20.00 20.35 21. 13 102 106 4
1,2-Dichloroethane ug/l 0 20.00 19.30 19. 71 96 98 2 I 1,1-Dichloroethene ug/l .0 20.00 20.06 21.14 100 106 5
cis-1,2-Dichloroethene ug/l 0 20.00 19. 78 20.12 99 101 2
trans-1,2-Dichloroethene ug/l 0 20.00 21.13 20.80 106 104 2
I 1,2-Dichloropropane ug/l 2560 20.00 22980 24160 102100108000 5
1.3-Dichloropropane ug/l 0 20.00 20.21 20.71 101 104 2
2.2-Dichloropropane ug/l 0 20.00 12.01 12.07 60 60 I
I 1,1-Dichloropropene ug/l 0 20.00 20.62 20.91 103 104 I
cis-1,3-Dichloropropene ug/l 0 20.00 17 .94 17.98 90 90 0
trans-1,3-0ichloropropene ug/l 0 20.00 18.69 19.27 94 96 3
Diisopropyl ether ug/l 0 20.00 20.09 19.32 100 97 4
I Ethyl benzene ug/l 0 20.00 21.46 21.09 107 106 2
Hexachloro-1,3-butadiene ug/l 0 20.00 20.10 19.87 100 99 I
Isopropylbenzene (Cumene) ug/l 0 20.00 20.12 19.32 IOI 97 4
I p-Isopropyltoluene ug/l 0 20.00 18.93 18.39 95 92 3
Methylene chloride ug/l 922.9 20.00 20140 20460 9610097700 2
Methyl-tert-butyl ether ug/l 0 20.00 20. 10 19.45 100 97 3
I
Naphthalene ug/l 0 20.00 21.08 20.09 105 100 5
Oate: 06/29/02 Page: 160
I
I LabQratQ[Y CertificatiQn IDs REPORT OF LABORATORY ANALYSIS LaboratQrt C~rtification IDs
NC Wastewater 12 LA Wastewater 04034
NC Drinking Water 37706 This report shall not be reproduced, except in full, VA Drinking Water 213
I SC 99006 without the written consent of Pace Analytical Services, Inc. FL NELAP E87627 ,• >.cco• ~'I~~ _.-"'/)ela ~-ff/0 · C\1
Pace Analytical Services, Inc. I
ace Analytical'" 9800 Kincey Avenue, Suite 100 ., Huntersville, NC 28078 I ✓ ••
. ··QUALITY CONTROL DATA Phone: [phone] www.pacelabs.com Fax: [phone]
Lab Project Number: 9233015 I Client Project ID: NCSU Lot 86/2246
MATRIX SPIKE & MATRIX SPIKE DUPLiCATE: 922299136 922299144 I
922293220 Spike MS MSD MS MSD
Parameter Units Result Cone. Result Result t Rec t Rec RPD Footnotes I n-Propylbenzene ug/1 0 20.00 19.37 18.77 97 94 3
Styrene ug/1 0 20.00 19.58 19.53 98 98 0
1.l.l.2·Tetrachltiroethane ug/1 0 20.00 19.64 19.83 98 99 1 I 1.1, 2, 2-Tet,ashloroethane ug/1 0 20.00 21.45 22.01 107 110 3
Tetrachloroethene ug/1 0 20.00 18.96 19.09 95 95 1 Toluerie} '." ug/1 0 20.00 19.20 19.75 96 99 3 ,· .. ;,-
I 1 ~2, 3'-Tri chl orobenzene ug/1 0 20.00 22.11 21.09 110 105 5 .,....-<fz, 4· Tri chl orobenzene ug/1 0 20.00 21.31 20.37 107 102 5 / •' p~·,., 1.1,1-Trichloroethane ug/1 0 20.00 20.04 20.45 100 102 2
l,1,2·Trichloroethane ug/1 0 20.00 20.62 20.96 103 105 2 I Trichloroethene ug/1 625.5 20.00 19560 19750 9466095640 1
Trichlorofluoromethane ug/1 0 20.00 18.27 19.16 91 96 5
1,2.3-Trichloropropane ug/1 0 20.00 20. 77 21.29 104 106 2
1,2,4-Trimethylbenzene ug/1 0 20.00 19.02 18.37 95 92 4 I 1,3,5-Trimethylbenzene ug/1 0 20.00 19.16 18.48 96 92 4
Vinyl chloride ug/1 0 20.00 21. 71 22.20 108 111 2
m&p-Xylene ug/1 0 40.00 41.61 39.90 104 100 4 I a-Xylene ug/1 0 20.00 19.65 19.27 98 96 2
l·Chloro-3-fluorobenzene (S) 100 102
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Date: 06/29/02 Page: 161
I
Laboratort Certification IDs REPORT OF LABORATORY ANALYSIS Laborato[l' Certifi,ation IDs I NC Wastewater 12 LA Wastewater 04034
NC Drinking Water 37706 This report shall not be reproduced, except in full, VA Drinking Water 213
SC 99006 without the written consent of Pace Analytical Services, Inc. FL NELAP E87627 I ,• •-cu• ~~~ J/Jel •c,
110 ac11
ace Analytical™
www.pacelabs.com .QUALITY CONTROL DATA
Lab Project Number: 9233015
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
I
I
I
I
I
I
Client Project ID: NCSU Lot 86/2246
QC Batch: 58259
QC Batch Method: SM 62300
Associated Lab Samples:
METHOD BLANK: 92230~197
Associated Lab.Sa~ples:
J Parameter ,,,, '~·
I Benzene ,. 'Y
. ,-~.Bromobenz_ene
,:·\,.f,,, Bromochloromethane
r Bromodichloromethane I Bromoform
Bromomethane
n • Butyl benzene
I sec-Butyl benzene
tert-Butylbenzene
Carbon tetrachloride
I Chlorobenzene
Chloroethane
Chloroform
• Chloromethane
I 2-Chl oroto l uene
4-Chlorotoluene
1.2-Dibromo-3-chloropropane
I Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
I 1,2-Dichlorobenzene
1,3-Dichlorobenzene
1.4-0ichlorobenzene
Dichloradifluoromethane
I 1.1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
I cis-1.2-Dichloroethene
trans-1.2-Dichloroethene
1.2-Dichloropropane
I
1,3-0ichloropropane
Date: 06/29/02
I
I La!lQrato[)' C~rtificatiQn IDs
NC Wastewater 12
NC Drinking Water 37706
I SC 99006
Analysis Method: SM 62300
Analysis Description: GC voes in Water
922293337
922293337
Units
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
ug/l
Blank Reporting
Result Limit Footnotes
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 1.0
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 2.0
ND 0.50
ND 0.50
ND 2.0
ND 0.50
ND 0.50
ND 0.50
ND 1.0
ND 1.0
ND 1.0
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,~ >.ccc,. ~ .. ,,.,-~ ..... o'"/ •-f"-',", ?11J'~ac1~
Pllge: 162
Laborato[Y Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
ace Analytical~
·:QUALITY CONTROL DATA
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: 704.8~5.9091
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www.pacelabs.com
METHOD BLANK: 922301197
Associated Lab Samples:
Parameter
2.2·Dichloropropa~e · · .
1. 1-Di chl oroproperie
ci s -1. 3-Di_~~~ir~~ropene
trans -1, J'-Di Chl oropropene
Di; soprcipyl ether
Eth;lb;n,ene _r•,•
,,,:(.:Hexachloro· 1,3·butadiene
,,,,,:;,,-' ..., ... Isopropylbenzene (Cumene)
p·Isopropyltoluene
Methylene chloride
Methyl-tert•butyl ether
Naphthalene
n·Propylbenzene
Styrene
1,1.1,2-Tetrachloroethane
l,1,2,2·Tetrachloroethane
Tetrachloroethene
Toluene
1,2.3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,l·Trichloroethane
1,1,2·Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3·Trichloropropane
1,2,4•Trimethylbenzene
1.3.5·Trimethylbenzene
Vinyl chloride
m&p-Xylene
o-Xylene
1-Chloro-3-fluorobenzene
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
._,;.
·922293337
Units
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
(S) t
/ Lab Project Number: 9233015
Client Project ID: NCSU Lot 86/2246
Blank Reporting
Result Limit Footnotes
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 2.0
ND 0.50
ND 1.0
ND 2.0
ND 0.50
ND 2.0
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 2.0
ND 2.0
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0.50
ND 0,50
ND 0,50
104
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,~ •cco~ ,-1~-
ff/Ot:lclC\t
Page: 163
Laboratory Certification IDs I
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627 I
I Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100. ace Analytical™ Huntersville, NC 28078
I' QUALITY CONTROL DATA Phone: [phone] www.pacelabs.com Fax: [phone]
I Lab Project Number: 9233015
Client Project ID: NCSU Lot 86/2246
I LABORATORY CONTROL SAMPLE: 922301205
Spike LCS LCS
I Parameter Units ~ Result t Rec Footnotes
Benzene ug/1 20.00 20.18 101
Bromobenzene ug/1 20.00 20.34 102
Brmoochl oromethan.e·· ug/1 20.00 18.92 95
I Bromodichloromethane ug/1 20.00 20.97 105
Bromoform•_· ;,:.., ug/1 20.00 22.83 114
Bromomelhane ug/1 20.00 20.04 100 / ,· I n•Butylbenzene ug/1 20.00 20.37 102
,/,:;~;-Butyl benzene ug/1 20.00 20.37 102
. _, .. :•}·· tert · Butyl benzene ug/1 20.00 20.86 104
Carbon tetrachloride ug/1 20.00 18.17 91 I Chl orobenzene ug/1 20.00 21.66 108
Chloroethane ug/1 20.00 19.35 97
Chloroform ug/1 20.00 19.06 95
I Chloromethane ug/1 20.00 19.59 98
2-Chlorotoluene ug/1 20.00 19.44 97
4· Chl oroto 1 uene ug/1 20.00 20.19 101
I 1,2-Dibromo-3-chloropropane ug/1 20.00 24.61 123
Dibromochloromethane ug/1 20.00 20.53 103
1.2·Dibromoethane (EDS) ug/1 20.00 21.65 108
Dibromomethane ug/1 20.00 20.01 100
I 1.2-0ichlorobenzene ug/1 20.00 22.54 113
1,3-Dichlorobenzene ug/1 20.00 20.40 102
1.4-Dichlorobenzene ug/1 20.00 20.72 104
I Dichlorodifluoromethane ug/l 20.00 23.08 115
1.1-Dichloroethane ug/1 20.00 19.62 98
1.2-0ichloroethane ug/l 20.00 18.96 95
I 1.l·Dichloroethene ug/1 20.00 18.37 92
ci s-1. 2· Di chl oroethene ug/1 20.00 19.55 98
trans-1,2-Dichloroethene ug/l 20.00 19.17 96
1.2·Dichloropropane ug/1 20.00 20.49 102
I 1.3·Dichloropropane ug/l 20.00 20.90 105
2.2·Dichloropropane ug/l 20.00 19.50 98
l.l·Dichloropropene ug/1 20.00 24.87 124
I cis-1.3-Dichloropropene ug/l 20.00 21.42 107
trans·l.3·Dichloropropene ug/l 20.00 20. 90 105
Diisopropyl ether ug/1 20.00 28.52 143 2
Ethyl benzene
I
ug/1 20.00 22.78 114
Date: 06/29/02 Page: 164
I
I LabQratorl Certification IDs REPORT OF LABORATORY ANALYSIS Laborato[Y Certifi~~tion ID~
NC Wastewater 12 LA Wastewater 04034
NC Drinking Water 37706 This report shall not be reproduced, except in full, VA Drinking Water 213
I SC 99006 without the written consent of Pace Analytical Services, Inc. FL NELAP E87627
'" >.Cto.f ~·· _.,, lei "{,
?1n ac\1
,, ,
/;·f'•··
ace Analytical™ .·
www.pacelabs.com .. , ; QUALITY CONTROL DATA
Lab Project Number: 9233015
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
LABORATORY CONTROL SAMPLE: 92230,1205
Spike LCS LCS
Parameter Units Cone. Result t Rec Footnotes Hexach l oro-1, 3-butadiene ·, ,.., ug/l 20.00 24.26 121
Isopropylbenzene (Cumene) ug/l 20.00 20.23 101
p-Isopropyl toluen~/ ug/1 20.00 19,97 100 ~ : ,, Methylene chloride ug/1 20.00 18.47 92 ./ ,-,· Methyl -,te~t-butyl ether ug/1 20,00 25,88 129
Naphthalene -· y ug/1 20.00 21.84 109
!1: ~~opyl benzene ug/1 20.00 20.23 101
'.';\;'tyrene ug/l 20,00 19.96 100
1.1,1,2-Tetrachloroethane ug/l 20.00 19.95 100 1,1,2,2-Tetrachloroethane ug/l 20.00 23.02 115
Tetrachloroethene ug/l 20,00 18.05 90
Toluene ug/l 20,00 19.07 95
1,2,3-Trichlorobenzene ug/l 20,00 23.81 119
1.2,4-Trichlorobenzene ug/l 20.00 21.85 109 1,1,1-Trichloroethane ug/1 20.00 18.25 91
1.1,2-Trichloroethane ug/l 20.00 21.90 110
Trichloroethene ug/l 20.00 18.00 90
Trichlorofluoromethane ug/l 20.00 17-40 87
1,2,3-Trichloropropane ug/1 20.00 22.96 115
1,2,4-Trimethylbenzene ug/l 20.00 19. 78 99
1,3.5-Trimethylbenzene ug/1 20.00 20.18 101
Vinyl chloride ug/1 20.00 19. 78 99
m&p-Xylene ug/1 40.00 44.27 111
a-Xylene ug/l 20.00 20.76 104
1-Chloro-3-fluorobenzene (S) 101
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 922301213 922301221
922293337 Spike MS MSD MS MSD
Parameter Units Result Cone. Result Result t Rec t Rec Benzene ug/l 0 20.00 19.53 19.55 98 98
Bromobenzene ug/1 0 20.00 20.21 20.55 101 103 Bromochloromethane ug/l 0 20·.oo 20 .40 19 .94 102 100 Bromodichloromethane ug/1 0 20.00 21.94 21.55 110 108 Bromoform ug/l 0 20.00 22.56 22,60 113 113 Bromomethane ug/l 0 20 .00 21.40 21.90 107 110
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12 REPORT OF LABORATORY ANALYSIS
NC Drinking Water 37706
SC 99006
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
RPO Footnotes
0
2
2
2
0
2
Page: 165
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
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I Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100 ace Analytical™ Huntersville, NC 28078
I QUALITY CONTROL DATA Phone: [phone] www.pacelabs.com Fax: [phone]
/
I Lab Project Number: 9233015
Client Project ID: NCSU Lot 86/2246
I MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 922301213 922301221
922293337 Spike MS MSD MS MSD
Parameter Units Result Cone. Result Result t Rec t Rec RPD Footnotes I n-Butylbenzene ug/1 0 20.00 21.06 20.67 105 103 2
sec-Butyl benzene ug/1 0 20.00 20.93 20.67 105 103 1
tert-8utyl benzene_. · ug/1 0 20.00 21.15 20.87 106 104 1
I Carbon tetrachloride ug/1 0 20.00 21.06 20.30 105 102 4
Ch l orobenf~rie ,· ug/1 0 20.00 21.21 21.02 106 105 1
Chlaroethane ug/1 0 20.00 21.53 20.78 108 104 4 C •,r
Chloroform ug/1 0 20.00 20.64 19.95 103 100 3 I , / ,,,1~.Chloromethane ug/1 0 20.00 20. 71 20.03 104 100 3
.,-~.,,..:;. · 2-Chlorotoluene ug/1 0 20.00 19.58 19. 74 98 99 1
4-Chlorotoluene ug/1 0 20.00 19.87 19.93 99 100 0
I 1,2-Dibromo-3-chloropropane ug/1 0 20.00 24.22 23.89 121 119 1
Dibromochloromethane ug/1 0 20.00 20.65 20. 71 103 104 0
1.2-Dibromoethane (ED8) ug/1 0 20.00 21.53 21.40 108 107 1
I Dibromomethane ug/1 0 20.00 20.69 20.93 103 105' 1
1.2-0ichlorobenzene ug/1 0 20.00 22.27 22.37 111 112 0
1,3-Dichlorobenzene ug/1 0 20.00 20.79 20.64 104 103 1
1,4-Dichlorobenzene ug/1 0 20.00 20.64 20.36 103 102 1 I Dichlorodifluoromethane ug/1 0 20.00 25.83 25.81 129 129 0
1.1-Dichloroethane ug/1 0 20.00 21.66 20.79 108 104 4
1,2-Dichloroethane ug/1 0 20.00 19.86 19.66 99 98 1
I 1.1-Dichloroethene ug/1 0 20.00 21.18 20.81 106 104 2
cis-1,2-Dichloroethene ug/1 0 20,00 21.54 20.99 108 105 3
trans-1,2-Dichloroethene ug/1 0 20.00 21.19 20,87 106 104 1
I 1,2-Dichloropropane ug/1 0 20,00 21.67 21.53 108 108 1
1,3-Dichloropropane ug/1 0 20.00 20.79 21.00 104 105 1
2,2-Dichloropropane ug/1 0 20,00 20.99 19.80 105 99 6
1.1-Dichloropropene ug/1 0 20,00 27 .96 27,51 140 138 2 I cis-1,3-Dichloropropene ug/1 0 20,00 18.98 18.40 95 92 3
trans-1,3-Dichloropropene ug/1 0 20,00 20.69 21.06 104 105 2
Diisopropyl ether ug/1 0 20.00 26,31 28.09 132 140 7
I Ethyl benzene ug/1 0 20.00 22.24 22,11 111 110 1
Hexachloro-1.3-butadiene ug/1 0 20.00 25.75 24.46 129 122 5
Isopropylbenzene (Cumene) ug/1 0 20,00 20,66 20.38 103 102 1
I p-Isopropyltoluene ug/1 0 20.00 20,36 19.98 102 100 2
Methylene chloride ug/1 0 20.00 19.12 19,07 96 95 0
Methyl-tert-butyl ether ug/1 0 20.00 24.43 25.04 122 125 2
Naphthalene ug/1 0 20.00 20,09 23.10 100 116 14
!I
Date: 06/29/02 Page: 166
I
I LaboratQry Certification IDs REPORT OF LABORATORY ANALYSIS L~boratoc,, Certification IDs
NC Wastewater 12 LA Wastewater 04034
NC Drinking Water 37706 This report shall not be reproduced, except in full, VA Drinking Water 213
I SC 99006 without the written consent of Pace Analytical Services, Inc. FL NELAP E87627 ,,. Aec0~ ,,~ ,,'/ lela '",
I ffiO · C\1
Pace Analytical Services, Inc. I
ace Analytical™ 9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
QUALITY CONTROL DATA Phone: [phone] I www.pacelabs.com Fax: [phone]
Lab Project Number: 9233015 I Client Project ID: NCSU Lot 86/2246
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 922301213 922301221 I 922293337 Spike MS MSD MS MSD Parameter Units Result Cone. Result Result X Rec X Rec RPO Footnotes I n-Propy1benzene ug/1 0 20.00 20.32 20.09 102 100 1
Styrene
; '1/ ug/1 0 20.00 18.93 19.18 95 96 1 1.1,l,2·Tetrachloroethane ug/1 0 20.00 19.98 19.57 100 98 2
1, 1, 2, 2-Te!,ra~h 1 oroethane ug/1 0 20.00 22.23 23.10 111 116 4 I Tetrachloroethene ug/1 0 20.00 19,68 19.27 98 96 2 Toluene;.' ug/1 0 20.00 19.90 19.70 100 98 1
1:2, 3:Tri chl orobenzene ug/1 0 20.00 21.97 24.15 110 121 9 I /'··'' ..,..6(~~1:2.4-Trichlorobenzene ug/1 0 20.00 20.44 22.06 102 110 8 -~-.-· 1.1.l•Trichloroethane ug/1 0 20.00 20.90 20.09 104 100 4 (..,,,.,· .,, 1,1,2-Trichloroethane ug/1 0 20.00 21.94 22.02 110 110 0 Trichloroethene ug/1 0 20.00 19.93 19.32 100 97 3 I Trichlorofluoromethane ug/1 0 20.00 20.32 19.31 102 96 5
1.2.3-Trichloropropane ug/1 0 20.00 21. 78 22,49 109 112 3
1.2.4-Trimethylbenzene ug/1 0 20.00 19.31 19.23 96 96 0 I 1.3,5-Trimethylbenzene ug/1 0 20.00 19,87 19.71 99 99 1
Vinyl chloride ug/1 0 20.00 23.28 22.69 116 113 3 m&p-Xylene ug/1 0 40.00 42.13 41.81 105 104 1 I a-Xylene ug/1 0 20.00 20,30 20.26 102 101 0 1-Chloro-3-fluorobenzene (S) 105 103
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I Date: 06/29/02 Page: 167
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Laborato[Y Certification ID, REPORT OF LABORATORY ANALYSIS Laborato[Y Certific,tion IDs I NC Wastewater 12 LA Wastewater 04034
NC Drinking Water 37706 This report shall not be reproduced, except in full, VA Drinking Water 213
SC 99006 without the written consent of Pace Analytical Services, Inc. FL NELAP E87627 I }F.~ •' lei ", fin aci1
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ace Analytical™
www.pacelabs.com , . ---•QUALITY CONTROL DATA
Lab Project Number: 9233015
Pace Analytical Services, Inc.
9800 Kincey Avenue. Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
QC 8atch: 58151
QC Batch Method: EPA 7470
Associated Lab Samples:
METHOD BLANK: 922297304
Analysis Method: EPA 7470
Analysis Description: Mercury, CVMS, in Water
922276217 922276225 922282611 922282629 922282637
922282645 922282652 922282710 922282728 922282785
922282793 922282801
Associateij'.'tab Samples: 922276217 922276225 922282611 922282629 922282637 922282645 922282652
r 922282710
Units
mg/1
LA80RATORY CONTROL SAMPLE: 922297346
Parameter
Mercury
Uni ts
mg/1
922282728 922282785 922282793 922282801
Blank Reporting
Result Limit Footnotes
ND 0.0002
Spike
Cone.
0.0050
LCS
Result
0.0049
LCS
t Rec Footnotes
97
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 922297312 922297320
Parameter
Mercury
SAMPLE DUPLICATE: 922297338
Parameter
Mercury
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
Units
mg/1
Units
mg/1
922276217
Result
0.00009
922276225
Result
ND
Spike
Cone.
0.0050
DUP
Result
ND
MSD MS MSD MS
Result
0.0047
Result t Rec t Rec RPO Footnotes
0.0045 92 88 3
RPO Footnotes
NC
Page: 168
REPORT OF LABORATORY ANALYSIS Laboratory Certification IDs
LA Wastewater 04034 This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,• •cco-
.,,~,. t1nelaci1
VA Drinking Water 213
FL NELAP E87627
ace Analytical™
www.pacelabs.com
QC Batch: 58152
QC Batch Method: EPA 7470
Associated Lab Samples: 922282819
922285184
922293188
922293287
. QUALITY CONTROL DATA
Lab Project Number: 9233015
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Client Project IO: NCSU Lot 86/2246
Analysis Method: EPA 7470
Analysis Description: Mercury, CVMS, in Water
922282959 922283007 922283015 922285176
922285192 922285200 922285218 922285226
922293204 922293220 922293261 922293279
922293295 922293303 922293329 922293337
METHOD 81'.ANK.': 922297353
Ass.~cfated Lab Samples: 922282819 922282959 922283007 922283015 922285176 922285184 922285192
,.,..::,~';:f-)/' 922285200 922285218 · 922285226
922293279 922293287 922293295
922293188 922293204
922293303 922293329
922293220 922293261
922293337
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,,,~.,.,•'
Parameter Units
Mercury mg/1
LABORATORY CONTROL SAMPLE: 922297395
Parameter
Mercury
Units
mg/l
Blank Reporting
Result Limit Footnotes
NO 0.0002
Spike LCS LCS
Cone. Result X Rec Footnotes
0.0050 0.0050 100
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 922297486 922297494
Parameter
Mercury
SAMPLE DUPLICATE: 922297387
Parameter
Mercury
Date: 06/29/02
· Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
Units
mg/l
Units
mg/l
922293220
Result
0.00054
922282959
Result
NO
Spike
Cone.
0.0050
OUP
Result
NO
MSO MS MSO MS
Result
0.0052
Result X Rec X Rec RPO Footnotes
0.0053 93 94 1
RPO Footnotes
NC
Page: 169
I
REPORT OF LABORATORY ANALYSIS Laboratory Certification IDs I
LA Wastewater 04034 This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
~~\\
VA Drinking Water 213
FL NELAP E87627 I
I
' ace Analytical™
www.pacelabs.com
QC Batch: 5Bl53
·QUALITY CONTROL DATA
Lab Project Number: 9233015
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite too
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Analysis Method: EPA 7470
Analysis Description: Mercury. CVAAS, in Water
I
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I
QC Batch Method: EPA 7470
Associated Lab Samples: 9222933B6
METHOD BLANK: 922297403.
Associated Lab: s·ainpi es: 922293386
,., ..
.' .
Parameter/
MefC:ury ~~··•·:,,
Units
mg/1
' ·.!I,·.
Blank
Result
ND
Reporting
Limit Footnotes
0.0002
I /.
.• -LA-B-ORA---,-T.,-OR_Y_C_O_NT_R_O_L_S_AM_P_L_E:-92-2-29_7_4_11 _______________________________ _
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Parameter
Mercury
Units
mg/1
Spike
Cone.
0.0050
LCS
Result
0.0051
LCS
t Rec Footnotes
102
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 922297429 922297437
Parameter
Mercury
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
Units
mg/1
MSD MS MSD 922293386
Result
0.00027
Spike
Cone.
0.0050
MS
Result
0.0054
Result t Rec t Rec RPO Footnotes
0.0055 103 105 2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
1• ACto.f ,?~~---\ .. 11nelacii
Page: 170
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
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ace Analytical™ :_ · · ·ouAuTv coNTRoL oATA
www.pacelabs.com 1
Lab Project Number: 9233015
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Analysis Method: EPA 6010 QC Batch: 57702
QC Batch Method: EPA 3010
Associated Lab Samples: 922276258
Analysis Description: Dissolved Metals, Trace ICP
922276266
METHOD BLANK: 922277611
Associated La? s·~,mples:
Parameter,·
922276258
Units
mg/1
LABORATORY CONTROL SAMPLE: 922277645
Parameter
Iron. Dissolved
Units
mg/1
922276266
Blank
Result
ND
Spike
Cone.
10.00
Reporting
Limit Footnotes
LCS
Result
10.70
0.050
LCS
X Rec Footnotes
107
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 922277629 922277637
Parameter
Iron, Dissolved
Date; 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
Units
mg/1
922276258 Spike MS MSD MS MSD
Result Cone. Result Result t Rec t Rec RPO Footnotes
0.03310 10.00 10.60 10.60 106 106 0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Page: 171
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
ace Analytical™
www.pacelabs.com · QUALITY CONTROL DATA
Lab Project Number: 9233015
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
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QC Batch: 57713
QC Batch Method: EPA 3010
Associated Lab Samples:
METHOD BLANK: 9?2~78072
Associated Lab Samples:
Paramet~-~ '
Ade.ni'c
Analysis Method: EPA 6010
Analysis Description: Metals by Trace ICP
922276217 922276225
922276217 922276225
Blank Reporting
Units Result Limit Footnotes
mg/1 ND 0.0050 _,.n-:"Ba~; um mg/1 ND 0.0050 . , .-'.,~::r Cadmium , mg/1 ND 0.0010
Chromium mg/1 ND 0.0020
Lead mg/1 ND 0.0050
Manganese mg/1 ND 0.0050
Selenium mg/1 ND 0.0050
Silver mg/1 ND 0.0020
LABORATORY CONTROL SAMPLE: 922278106
Spike LCS LCS
Parameter Units Cone. Result t Rec Footnotes
Arsenic mg/1 0.2500 0.2570 103
Barium mg/1 0.2500 0.2910 116
Cadmium mg/1 0.2500 0.2570 103
Chromium mg/1 0.2500 0.2570 103
Lead mg/1 0,2500 0.2480 99
Manganese mg/1 0.2500 0.2600 104
Selenium mg/1 0.2500 0.2570 103
Silver mg/1 0.2500 0.2610 104
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 922278080 922278098
922276217 Spike MS MSD
Parameter Units Result Cone. Result Result
Arsenic mg/1 0.00025 0.2500 0.2640 0.2560
Barium mg/1 0.03720 0.2500 0.3220 0.3210
Cadmium mg/1 0 0.2500 0.2590 0.2510
Date: 06/29/02
MS MSD
t Rec t Rec
106 102
114 114
104 100
Laboratory Certification IDs
NC Wastewater 12 REPORT OF LABORATORY ANALYSIS
NC Drinking Water 37706
SC 99006
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
RPO Footnotes
3
0
3
Page: 172
Laboratory Certification IDs · I
LA Wastewater 04034
VA Drinking Water 213 1 FL NELAP E87627
I
ace Analytical™ . '. QUALITY CONTROL DATA
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
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I
www.pacelabs.com
,."./
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
J
Parameter Units
Chromium :" _,,, mg/l
Lead mg/1
Manganese mg/l
Selenium mg/1
Si 1 ver ' , mg/1
I/~//; .. •·
/.k (•
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Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
Lab Project Number: 9233015
Client Project ID: NCSU Lot 86/2246
922278080 922278098
922276217 Spike MS MSD MS MSD
Result Cone. Result Result X Rec X Rec
0 0.2500 0.2570 0.2490 103
0.00282 0.2500 0.2490 0.2410 98
0.00887 0.2500 0 .2680 0.2610 104
0 0.2500 0.2600 0.2550 104
0.00004 0.2500 0.2590 0.2540 104
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,~ •cco,.
'~ flnelaa\
100
95 .
101
102
102
RPO Footnotes
3
3
3
2
2
Page: 173
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
ace Analytical™
www.pacelabs.com
QC Batch: 57967
QC Batch Method: EPA 3010
Associated Lab Samples: 922282827
922282876
922282942
922285242
922282827
QUALITY CONTROL DATA
Lab Project Number: 9233015
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Analysis Method: EPA 6010
Analysis·oescription: Dissolved Metals. Trace ICP
922282835 922282843 922282850 922282868
922282900
922283031
922285259
922282918
922283049
922285267
922282926
922283056
922285275
922282934
922285234
922285291
METHOD BLANK·: 922289160
Assocfate<l Lab Samples:
/:
,,f>-··'
\/ ?
/ .. f;: ,:,
922282918
922285234
922282835 922282843
922282926 922282934
922285242 922285259
922282850 922282868
922282942 922283031
922285267 922285275
922282876
922283049
922285291
922282900
922283056
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Parameter Units
Iron. Dissolved mg/1
LABORATORY CONTROL SAMPLE: 922289202
Parameter
Iron, Dissolved
Units
mg/1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
Parameter Units
Iron, Dissolved mg/1
SAMPLE DUPLICATE: 922289194
Parameter Units
Iron. Dissolved mg/1
Date: 06/29/02
Blank Reporting
Result Limit Footnotes
ND 0.050
Spike LCS
Cone. Result
10.00 10.40
922289178 922289186
922282827 Spike
Result Cone.
0.02100 10.00
922282835 DUP
LCS
t Rec Footnotes
104
MS MSD
Result Result
10.50 10.20
Result Result RPO Footnotes
ND ND NC
MS MSD
t Rec t Rec
105 102
Laboratory Certification IDs
NC Wastewater 12 REPORT OF LABORATORY ANALYSIS
NC Drinking Water 37706
SC 99006
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
RPO Footnotes
3
Page: 174
Laboratory Certification IDs I
LA Wastewater 04034
VA Drinking Water 213 1 FL NELAP E87627
ace Analytical™
www.pacelabs.com . QUALITY CONTROL DATA
Lab Project Number: 9233015
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
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I
Client Project ID: NCSU Lot 86/2246
I
QC Batch: 57969
QC Batch Method: EPA 3010
Associated Lab Samples: .·
' '
METHOD BLANK: 922289269
Associated Lab Samples:
•-~<:<:-
. ,}'"
.r1 • Parameter
••• Arsenic
Barium
Cadmium
Chromium
Lead
Manganese
Selenium
Silver
Analysis Method: EPA 6010
Analysis Description: Metals by Trace ICP
922282611 922282629 922282637 922282645 922282652
922282710 922282728 922282785 922282793 922282801
922282819
922282611 922282629 922282637 922282645 922282652 922282710
922282785 922282793 922282801 922282819
Blan< Reporting
Units Result Limit Footnotes
mg/l ND 0.0050
mg/l ND 0.0050
mg/l ND 0.0010
mg/l ND 0.0020
mg/l ND 0.0050
mg/l ND 0.0050
mg/1 ND 0.0050
mg/l ND 0.0020
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LABORATORY CONTROL SAMPLE: 922289277
Parameter
Arsenic
Barium
Cadmium
Chromium
Lead
Manganese
Selenium
Silver
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
Units
mg/l
mg/l
mg/l
mg/1
mg/l
mg/1
mg/l
mg/l
Spi<e LCS LCS
Cone. Result t Rec Footnotes
0.2500 0.2530 101
0.2500 0.2740 110
0.2500 0.2500 100
0.2500 0.2530 101
0.2500 0.2430 97
0.2500 0.2520 101
0.2500 0.2480 99
0.2500 0.2410 96
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,~ •eco~
//'W:r~-ffln~C\1
922282728
Page: 175
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
ace Analytical™
www.pacelabs.com
j.
SAMPLE DUPLICATE: 922289301
Parameter Units
Arsenic mg/l
Barium ;/ mg/l
Cadmium mg/l
Chromium mg/l
Lead . .--~ ',•" mg/l
HangalleS~, mg/l se1in1·~m mg/l / ..
,.,.(,,. Silver mg/l ,•',;,'
~,. _r
~
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
'QUALITY CONTROL DATA
Lab Project Number: 9233015
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28018
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
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922282629 DUP
Result Result RPO Footnotes
ND ND NC ·
0.05300 0.06400 19
ND ND NC
0.00550 0.00520 6
0.00580 0.00620 7
0.4500 0.4400 3
ND ND NC
ND ND NC
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
\M ~~Ca~ ,Kr\.~~ inPl:::1r\t
Page: 176 I
Laboratory Certification IDs I
LA Wastewater 04034
VA Drinking Water 213 1 FL NELAP E87627
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ace Analytical™
www.pacelabs.com
QC Batch: 57970
QC Batch Method: EPA 3010
Associated Lab Samples:
. '
922282959
922285192
·QUALITY CONTROL DATA
Lab Project Number: 9233015
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Analysis Method: EPA 6010
Analysis Description: Metals by Trace ICP
922283007 9222B3015 922285176 922285184
922285200 922285218 922285226
METHOD BLANK: .9222B9319
Associated Lab Samples: 922282959 922283007 922283015 9222B5176 9222B5184 922285192 922285200
9222B521B 922285226
I , .,;: ...
/.~!Pa~ameter
, ,,;) -Arsenic
Uni ts
Blank
Result
Reporting
Limit Footnotes
. ,'
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Barium
Cadmium
Chromium
Lead
Manganese
Selenium
Silver
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
LABORATORY CONTROL SAMPLE: 922289350
Parameter Units
Arsenic mg/1
Barium mg/1
Cadmium mg/1
Chromium mg/1
Lead mg/1
Manganese mg/1
Selenium mg/1
Silver mg/1
ND 0.0050
ND 0.0050
ND 0.0010
0.0041 0,0020
ND 0,0050
NO 0.0050
ND 0.0050
ND 0.0020
Spike LCS LCS
Cone. Result X Rec Footnotes
0.2500 0.2610 104
0.2500 0.2500 100
0.2500 0.2600 104
0.2500 0.2600 104
0.2500 0.2570 103
0.2500 0.2600 104
0.2500 0.2620 105
0.2500 0.2510 100
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 922289327 922289335
Parameter
Arsenic
Date: 06/29/D2
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
Units
mg/1
MSD MS MSD 922270327
Result
Spike
Cone.
0.2500
MS
Result
0.2630
Result X Rec X Rec RPD Footnotes
0 0.2570 105 103 2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,M •cco., ~ lnelaa1
Page: 177
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
ace Analytical'"
www.pacelabs.com
MATRIX SPIKE & MATRIX SPIKE DUPUCATE:
;_"
.(
Parameter Units
Barium ·' mg/l
Cadmium mg/l
Chromium mg/l
Lead mg/l
Mangane~e.,_, mg/l
SeleniUm· mg/l ,· .,,
,,...,,,SJ_!.ver mg/l
,,,-:_.;-;·/
:,f.>'J'
SAMPLE DUPLICATE: 922289343
Parameter Units
Arsenic mg/l
Barium mg/l
Cadmium mg/l
Chromium mg/l
Lead mg/l
Manganese mg/l
Selenium mg/l
Silver mg/l
Date: 06/29/02
QUALITY CONTROL DATA
Lab Project Number: 9233015
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
922289327 922289335
922270327 Spike MS MSD MS MSD
Result Cone. Result Result % Rec% Rec RPO Footnotes
0.2600 0.2500 0.5040 0.5040 98 98 0
0 0.2500 0.2560 0.2460 102 98 4
0.1940 0.2500 0.3060 0.2820 45 35 8 3.3
0.00323 0.2500 0.2540 0.2460 100 97 3
1.900 0.2500 2.100 2.050 80 60 2 3
0.00247 0.2500 0.2650 0.2590 105 103 2
0 0.2500 0.2480 0.2450 99 98 1
922278429 DUP
Result Result RPD Footnotes
ND ND NC
0.09700 0.09300 3
ND ND NC
ND ND NC 4
ND ND NC
0.8700 0.8400 4
ND ND NC
ND ND NC
Page: 178
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Laboratory Certification IDs
NC Wastewater 12 REPORT OF LABORATORY ANALYSIS Laboratory Certification IDs I
LA Wastewater 04034
NC Drinking Water 37706
SC 99006
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc. FL NELAP E87627
VA Drinking Water 213 1
I
ace Analytical™
www.pacelabs.com
QC Batch: 58158
QUALITY CONTROL DATA
Lab Project Number: 9233015
. Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Analysis Method: EPA 6010
Analysis Description: Metals by Trace ICP
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QC Batch Method: EPA 3010
Associated Lab Samples: 922293188 922293204 922293220 922293261 922293279
922293287 922293295 922293303 922293329 922293337
METHOD BLANK: 922297668
Assod~ted_~ab Samples:
,.· ./.
I ,.,<>
// ·"·.,_,,/ --.<,H· Parameter
• •• Ji.,.. Arsenic
I
I
Barium
Cadmium
Chromi urn
Lead
Manganese
Selenium
Silver
922293386
922293188 922293204
922293303 922293329
Blank
Units Result
mg/1 ND
mg/1 ND
mg/1 ND
mg/1 ND
mg/1 ND
mg/1 ND
mg/1 ND
mg/1 ND
LABORATORY CONTROL SAMPLE: 922297700
Spike
Parameter Units Cone.
Arsenic mg/1 0.2500
Barium mg/1 0.2500
Cadmium mg/1 0.2500
Chromium mg/1 0.2500
Lead mg/1 0.2500
Manganese mg/1 0.2500
Selenium mg/1 0.2500
Silver mg/1 0.2500
922293220 922293261 922293279
922293337 922293386
Reporting
Limit Footnotes
0.0050
0.0050
0.0010
0.0020
0.0050
0.0050
0.0050
0.0020
LCS LCS
Result X Rec Footnotes
0.2490 100
0.2330 93
0.2500 100
0.2490 100
0.2500 100
0.2470 99
0.2530 101
0.2500 100
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 922297676 922297684
Spike MS MSD
922293287
MS MSD
922293295
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Parameter Units
922293204
Result Cone. Result Result X Rec X Rec RPO Footnotes
Oate: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
REPORT OF LABORATORY ANALYSIS·
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,~ HCq~ §~~~ 11nelac1t
Page: 179
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
aceAnalytica/™ .,, -ouAun coNTRoL oATA
www.pacelabs.com
Lab Project Number: 9233015
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
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MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 922297676 922297684
922293204 Spike HS HSD HS HSD
Parameter Units Result Cone. Result Result X Rec X Rec
Arsenic mg/l 0.01290 0.2500 0.2610 0.2580 99 98
Barium mg/l 0.5700 0.2500 0.7930 0 .7860 89 86
Cadmium mg/1 0.00030 0.2500 0.2490 0.2460 100 98
Chromium mg/1 0.00236 0.2500 0.2510 0.2500 100 99
Lead /. mg/1 0.00909 0.2500 0.2540 0.2520 98 97
Manga_neSe mg/1 12. 70 0.2500 12.50 12.30 0 0 sei'e'ni~m mg/l 0.01000 0.2500 0.2600 0.2590 100 100 ~ .. .,,,,
.,../;::.Silver mg/l 0.00125 0.2500 0.2530 0.2510 101 100 .. ,(<~:;,·
>·
SAMPLE DUPLICATE: 922297692
922293287 DUP
Parameter Units Result Result RPD Footnotes
Arsenic mg/l ND ND NC
Barium mg/l 0.3700 0.3400 9
Cadmium mg/l 0.00440 0.00440 1
Chromium mg/l ND ND NC
Lead mg/l ND ND NC
Manganese mg/1 13.00 13.00 2
Selenium mg/1 0.01000 0.01000 1
Silver mg/l ND ND NC
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12 REPORT OF LABORATORY ANALYSIS
NC Drinking Water 37706
SC 99006
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
RPD Footnotes
1
1
1
0
1
2 3.3
0
1
Page: 180
Laboratory Certification IDs I
LA Wastewater 04034
FL NELAP E87627
VA Drinking Water 213 1
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ace Analytical'" . QUALITY CONTROL DATA
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone] www.pacelabs.com
QC 8atch: 58537
QC 8atch Method: EPA 3010
Associated Lab Samples: :
METHOD 8LA,NK_:., 922313614
Associated.tab Samples:
Iron. Dissolved
Lab Project Number: 9233015
Client Project ID: NCSU Lot 86/2246
Analysis Method: EPA 6010
Analysis Description: Dissolved Metals. Trace ICP
922293394 922293402 922293410 922293428 922293436
922293444 922293451 922293469 922293477 922293485
922293493
922293394 922293402 922293410 922293428 922293436 922293444 922293451
922293469
. Units
mg/l
922293477
Blank
Result
ND
922293485 922293493
Reporting
Limit Footnotes
0.050
LABORATORY CONTROL SAMPLE: 922313655
Parameter
I ran. Dissolved
Units
mg/1
Spike LCS LCS
Cone. Result X Rec Footnotes
10.00 10.10 101
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 922313846 922313853
Parameter
Iron. Dissolved
SAMPLE DUPLICATE: 922313648
Parameter
Iron. Dissolved
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
Units
mg/l
Units
mg/l
922293410 Spike MS MSD.
Result
0.03550
Cone.
10.00
MS
Result
10.50
MSD
Result
9.840
X Rec X Rec RPD Footnotes
922293436
Result
ND
DUP
Result
ND
RPD Footnotes
NC
105 98 6
Page: 181
REPORT OF LABORATORY ANALYSIS Laboratory Certification IDs
LA Wastewater 04034 This report shall not be reproduced, except in full.
without the written consent of Pace Analytical Services, Inc.
ff'~ fl□elaat
VA Drinking Water 213
FL NELAP EB7627
ace Analytical™
www.pacelahs.com ,QUALITY CONTROL DATA
Lab Project Number: 9233015
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Client Project JD: NCSU Lot 86/2246
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QC Batch: 57537 Analysis Method: EPA 310.1
QC Batch Method: EPA 310.1 · ·, Analysis Description: Alkalinity. Total
Associated Lab Samples: · 922276217 922276225
SAMPLE DUPLICATE, ·92J271291
Alkali'nity, Total
<".1·,,,.'
Units
mg/1
922266887 DUP
Result Result
400.0 400.0
RPO Footnotes
0
.,--:;:_· ___________________________________________ _
,-_>·· SAMPLE DUPLICATE: 922271309
Parameter
Alkalinity, Total
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
Units
mg/1
922270699 DUP
Result Result RPO Footnotes
260.0 250.0 2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,~ He~~
,,--~ .. ,1nPEiC"1~
Page: 182
Laboratory Certification IDs I
LA Wastewater 04034
VA Drinking Water 213 1 FL NELAP E87627
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ace Analytical™
www.pacelabs.com QUALITY CONTROL DATA
Lab Project Number: 9233015
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Client Project JD: NCSU Lot 86/2246
QC Batch: 58112
QC Batch Method: EPA 310.1
Associated Lab Samples:
SAMPLE DUPLICATE: 922295274
Paramefer '
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
Analysis Method: EPA 310.1
Analysis Description: Alkalinity. Total
922282611 922282629 922282637 922282645 922282652
922282710 922282728 922282785 922282793
Units
mg/l
922282520
Result
70.00
DUP
Result
75.00
RPO Footnotes
7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,~ Hto,.
,-'?'~,
?iO~aC\1
P11ge: 183
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
ace Analytical™.
www.pacelabs.com : QUALITY CONTROL DATA
Lab Project Number: 9233015
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite too
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
QC Batch: 5B232
QC Batch Method: EPA 310.1
Associated Lab Samples:. ·
· SAMPLE DUPLICATE:, 922300124
,
Parameter
Allcalinity. Total / ..
,/./,+ /4,,:'•;c,
;) , SAMPLE DUPLICATE: 922300132
Parameter
Alkalinity. Total
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
Analysis Method: EPA 310.1
Analysis Description: Alkalinity. Total
922282801 922282819 922282959 922283007 922283015
922285176 922285184 922285192
Units
mg/1
Units
mg/1
922282801 DUP
Result Result RPD Footnotes
20.00 18.00 13
922283635 DUP
Result Result RPD Footnotes
160.0 160.0 2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
~ ff1n~ci
Page: 184
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
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ace Analytical™
www.pacelabs.com · , QUALITY CONTROL DATA
Lab Project Number: 9233015
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
QC Batch: 58326
QC Batch Method: EPA 310.1
Associated Lab Samples: .
SAMPLE DUPLIC~TE: 922304456
SAMPLE DUPLICATE: 922304464
Parameter
Alkalinity, Total
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
Analysis Method: EPA 310.1
Analysis Description: Alkalinity. Total
9222B5200 9222B5218 9222B5226 922293188 922293204
922293220 922293261 922293279 922293287 922293295
922293303 922293337
Units
mg/l
Units
mg/l
9222B5200
Result
85,00
DUP
Result
82.00
922295084 DUP
RPD Footnotes
3
Result Result RPO Footnotes
5.000 5.000 0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,._ H,o,. .,,tr~~~~ finelacra
Page; 185
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
ace Analytical™
www.pacelabs.com
QC Batch: 58476
. , 'QUALITY CONTROL DATA
Lab Project Number: 9233015
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Analysis Method: EPA 310.l
Analysis Description: Alkalinity, Total QC Batch Method: EPA 310.1
Associated Lab Samples: 922293329 922293386
SAMPLE DUPLICATE:•9223il014
/ Parameter.·'·~
, ·•.· ./ . :'
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
Units
mg/1
922293329
Result
60 .00
DUP
Result
55.00
RPO Footnotes
9
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
lzy<~ f1n~ac1~
Page: 186
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
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ace Analytical™
www.pacelabs.com
. , . •QUALITY CONTROL DATA
Lab Project Number: 9233015
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
QC 8atch: 57671 I
I
I
QC Batch Method: EPA 300. 0 ... ·
Associated Lab Samples:
METHOD BLANK: 922276498
Associated Lab·S'i~pi~s:
,•
Parameter
I Chlor{de , ,,
1,_,.p1<:.Nitrate
, .... f,_ · Sulfate ~· ..... ~ .,
.· 922276217
922276217
Units
mg/1
mg/l
mg/l
I LABORATORY CONTROL SAMPLE: 922276506
I
I
Parameter
Chloride
Nitrate
Sulfate
Units
mg/l
mg/l
mg/l
Analysis Method: EPA 300.0
Analysis Description: Ion Chromatography
922276225
922276225
Blank Reporting
Result Limit Footnotes
ND 1.0
ND 0.10
ND 1.0
Spike LCS LCS
Cone. Result X Rec Footnotes
100.00 96.42 96
10.00 9.360 94
JOO.OD 93.44 93
I MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 922276514 922276522
922276217 Spike MS MSD MS HSD
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Parameter Units Result Cone. Result Result X Rec X Rec
Chloride
Nitrate
Sulfate
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
mg/1
mg/l
mg/1
18.25 JOO.DO 118.1 118.5 JOO
0.2500 10.00 9.600 9.640 94
17. 72 100.00 116. I 116.8 98
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,,. Hc0., ~~~ I1nelac1\
JOO
94
99
RPO Footnotes
0
0
I
Page: 187
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
aceAnalytica/'"
/QUALITY CONTROL DATA
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone] www.pacelabs.com
QC Batch: 57B23
QC Batch Method: EPA 300.~
Associated Lab Samples:
METHOD BLANK: : 922283296
Associated· c~·b Samp 1 es:
./··>/
Lab Project Number: 9233015
Client Project ID: NCSU Lot 86/2246
Analysis Method: EPA 300.0
Analysis Description: Ion Chromatography
922282611 922282629 922282637 922282645 922282652
922282710 922282728 9222827B5 922282793 922282801
922282819 922282959 922283007 922283015
922282611 9222B2629' 922282637 922282645 922282652 • 922282710 ' 922282785 922282793 922282801 922282819 922282959 922283007
922282728
922283015
./~:,'<):.--
,,,.,::',> -Parameter ..... ~
Blank
Units Result
Reporting
Limit Footnotes
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Chloride
Nitrate
Sul fate
mg/1
mg/1
mg/1
LABORATORY CONTROL SAMPLE: 922283304
Parameter Units
Chloride mg/1
Nitrate mg/1
Sulfate mg/1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
Parameter Units
Chloride mg/1
Nitrate mg/1
Sulfate mg/1
SAMPLE DUPLICATE: 922283338
Parameter Units
Chloride mg/1
Date: 06/29/02
ND 1.0
ND 0.10
ND 1.0
Spike LCS LCS
Cone. Result t Rec Footnotes
100.00 97.56 98
10.00 9.460 95
100.00 94.86 95
922283312 922283320
922282611 Spike MS MSD MS MSD
Result Cone. Result Result t Rec t Rec
5.560 100.00 105.6 105.8 100 100
4.440 10.00 14.60 14.64 102 102
0 100.00 96.26 96.32 96 96
922283015 _DUP
Result Result RPD Footnotes
1.900 1.800 4
Laboratory Certification IDs
NC Wastewater 12 REPORT OF LABORATORY ANALYSIS
NC Drinking Water 37706
SC 99006
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
~ ~neiaci
RPD Footnotes
0
0
0
Page: 188
Laboratory Certification IDs I
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627 I
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ace Analytical™
www.pacelabs.com
SAMPLE DUPLICATE: 922283338
Parameter ,'.t,. /
Nitrate
Sulfate /
--
. ,
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
.'
Units
mg/1
mg/1
'QUALITY CONTROL DATA
Lab Project Number: 9233015
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
922283015 DUP
Result Result RPD Footnotes
ND ND NC
1.200 1.200 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc. ~'~l'co_,o ".-
f/Oe aC\1
Page: 189
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
ace Analytical™
www.pacelabs.com >QUALITY CONTROL DATA
Lab Project Number: 9233015
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone. [phone]
Fax: [phone]
Cl _i ent Project ID: NCSU Lot 86/2246
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QC Batch: 57857 Analysis Method: EPA 300.0 QC Batch Method: EPA 300.0 •:· './ Analysis Description: Ion Chromatography Associated Lab Samples: · , 922285176 922285184 922285192 922285200 922285218
922285226
METHOD BLANK: 922285309
Associated Lab s:mples: 922285176 922285184 922285192 922285200 922285218 922285226
Blank Reporting
Units Result Limit Footnotes .,,~~<[,Gtii?ride
.,it· / Nitrate
mg/l ND 1.0
mg/l ND 0.10 · :• Sul fate mg/l ND 1.0
LABORATORY CONTROL SAMPLE: 922285317
Spike LCS LCS Parameter Units Cone. Result X Rec Footnotes Chloride mg/l 100.00 96.20 96
Nitrate mg/l 10 .00 9.340 93 Sulfate mg/l 100.00 93.50 94
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 922285325 922285333
922285176 Spike MS HSD HS HSD Parameter Units Result ~ Result Result X Rec X Rec RPD Footnotes Chloride
Nitrate
Sulfate
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
mg/l
mg/l
mg/l
4.540 100.00 101.6 101.7
0.1700 10.00 9.520 9.460
13.78 100.00 110.7 110.3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,~ ~cc0~ ~ lnelac~
97 97 0
94 93 1
97 96 0
Page: 190
Laboratory Certification IDs I
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627 I
I
!' ace Analytical™
www.pacelabs.com ·QUALITY CONTROL DATA
Lab Project Number: 9233015
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone] I
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Client Project ID: NCSU Lot 86/2246
QC Batch: 58058 :.·, •'·: ' Analysis Method: EPA 300.0
QC Batch Method: EPA 300.0 · Analysis Description: Ion Chromatography
Associated Lab Samples: · . 922293188 922293204 922293220 922293261 922293279
922293287 922293295 922293337
METHOD BLANK: 922293543
Associated . Lab:. samp1 es: . :_,.. 922293188 922293204 922293220 922293261 922293279 922293287 922293295
922293337 . ,,r. -~-,.,. I _,,(/ / 1 Parameter Units f . mg/1 _..,..,.,.✓ Chloride
·,,, Nitrate mg/1
I Sulfate mg/1
LABORATORY CONTROL SAMPLE: 922293550
Parameter Units
Chloride mg/1
Nitrate mg/1
Sulfate mg/1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
Parameter Units
Chloride mg/1
Nitrate mg/1
Sulfate mg/1
SAMPLE DUPLICATE: 922293584
Parameter Units
Chloride mg/1
Nitrate mg/1
Oate; 06/29/02
Blank Reporting
Result Limit Footnotes
ND 1.0
ND 0.10
ND 1.0
Spike LCS LCS
Cone. Result X Rec Footnotes
100.00 108.8 109
10.00 10.42 104
100.00 97 .42 97
922293634 922293642
922293220 Spike MS MSD
Result Cone. Result Result
48.05 100.00 148.6 149.1
0.2000 10.00 9.440 9.540
1.250 100.00 94.52 95.32
922293295 DUP
Result Result RPD Footnotes
6.300 6.400 3
ND ND NC
MS MSD
X Rec X Rec
100 101
92 93
93 94
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Laboratory Certification IDs
NC Wastewater 12 REPORT OF LABORATORY ANALYSIS
NC Drinking Water 37706
SC 99006
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
., ... 11~~,J ,·n1/· 1_1" .,, ?1 _ ~aci1
RPO Footnotes
0
1
1
Page: 191
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
ace Analytical™
www.pacelabs.com
SAMPLE DUPLICATE: 922293584 i
Parameter
Sulfate
./ ,~·
•' ' ,,r
.,(/ ., .. ·
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
Units
mg/1
. 'QUALITY CONTROL DATA
Lab Project Number: 9233015
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
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922293295 DUP
Result Result RPD Footnotes
4.000 4.000 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
~tt.~~ i/Llt:ld.C\\
Page: 192
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Laboratory Certification IDs I
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627 I
I
ace Analytical"'
www.pacelabs.com
QC Batch: 58059
✓
. QUALITY CONTROL DATA
Lab Project Number: 9233015
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Client Project ID: NCSU Lot 86/2246
Analysis Method: EPA 300.0
Analysis Description: Jon Chromatography
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QC Batch Method: EPA 300.0.
Associated Lab Samples: / ;, 922293303 922293329 922293386
METHOD BLANK: 92229}592
Associated Lab Samples: 922293303 922293329 922293386 r' I _,,/ ._,,.. Blank Reporting
Parameter Units Result Limit Footnotes
Chloride mg/1 ND 1.0 I " , ,.-✓:', Ni tr ate mg/1 ND 0. 10
:)/ Sulfate mg/1 ND 1.0 '/
LABORATORY CONTROL SAMPLE: 922293600
Spike LCS LCS
Parameter Units Cone. Result t Rec Footnotes
Chloride mg/1 100.00 108.8 109
Nitrate mg/1 10.00 10.42 104
Sulfate mg/1 100.00 97 .42 97
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MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 922293618 922293626
Parameter
Chloride
Nitrate
Sulfate
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 990D6
Units
mg/1
mg/1
mg/1
922293303 Spike MS MSD MS MSD
Result Cone. Result Result t Rec t Rec RPO Footnotes
39.29 100.00 140.1 140.8 101 102 0
0 10.00 9.460 9.480 95 95 0
1.480 100.00 95.96 96.04 94 95 0
Page: 193
REPORT OF LABORATORY ANALYSIS Laboratory Certification IDs
LA Wastewater D4034 This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,• ~cc0~ .~~. fiOt:::ld.Ct
VA Drinking Water 213
FL NELAP E87627
ace Analytical™
www.pacelabs.com
Lab Project Number: 9233015
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Client. Project ID: NCSU Lot 86/2246
QUALITY CONTROL DATA PARAMETER·FOOTNOTES
Consistent with EPA guidelines:-urir6unded concentrations are displayed and have been used to calculate t Rec and RPO values. . , .. '/
LCS(D) Laboratory Cont~oi Sample (Duplicate) ' ' , MS (D) Matrix Spi_ke:.(Dup l i cate)
DUP Sample,.Oupl icate
ND Not .det¢cfed at or above adjusted reporting limit
NC Not·caiculable
J E_stfmated concentration above the adjusted method detection limit and below the adjusted reporting limit MDL :··,.'Adjusted Method Detection Limit
,RPO,..,.. Relative Percent Difference ~-. ,., , ... •(S) Surrogate · .(.::)>' [1] Due to high analyte concentration the matrix spike and/or matrix spike duplicate do not provide reliable t rj/•··' Recovery and RPO values. Sample results for this QC batch were accepted based on LCS/LCSD t Recovery and/or RPD values.
[2] The LCS recovery was outside of the acceptance range.
[3] The spike recovery was outside acceptance limits for the MS and /or MSD due to matrix interference. The LCS and/or LCSD were within acceptance limits showing that the laboratory is in control and the data is acceptable.
[4] Reanalyzed 6-06-02
Date: 06/29/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
,~ •cco~ ~ !i'nelaa1
Page: 194
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
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M'Av.pacelabs.com
QC Batch: 27179
QUALITY CONTROL DATA
Lab Project Number: 9329483
Pac• Analytlcal Ssrr/ce,,./nc.
54 RaVliflSCIOft Dtiva
Asheville. NC 28801
Phone: [phone]
Fax: 828.252..tS/8
Client Project ID: PIEDMONT GEOLOGIC -9233015
Analysis Method: SM 5310C
Analysis Description: Total Organic Carbon I. QC Batch Method: SM 53108
. Associated Lab Samples: 922276217 922276225
I: METHOD BLANK: 931227987
, Associated Lab Samples: 922276217 922276225
I Parameter
Total Organic Carbon
unite
mg/1
I LABORATORY CONTROL SAMPLE: 931228027
I Parameter
Total Organic Carbon
Units
mg/1
Blank
Result
ND
Spike
~
30.00
Reporting
Limit Footnotes
LCS
Result
28.80
0.50
LCS
~ Footnotes
96
I MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 931227995 931228001
I Parameter
Total Organic Carbon
I SAMPLE DUPLICATE: 931228019
I Parameter
Total Organic Carbon
I
I
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Da.te1 06/ll/02
I
Units
mg/1
units
mg/1
931224646
Result
0.6000
Spike
~
20.00
931224653 DOP
Result Result
0.8000 4.100
MS
Result
6.600
MSD
Result
5.500
~ Footnotes
135
MS MSD
%~%Rec RPD Footnotes
30 24 18 1,1
Page: 35
LabtmHO['.l Gerlitir.atioa IOs
NC Wastewater 40 REPORT OF LABORATORY ANALYSIS Laboratory Certmcation IDs
I NC Drinking Water 37712
I
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Seivices, Inc.
TN Drinking Water 02980
SC Environmenlal 99030
aceAnalyticar
Vt'VIW:p.9celab$.COm
QC Batch: 27277
QUALITY CONTROL DATA
Lab Project Number: 9329483
Pace Ana/yllcet s,rrtce,, tn,.
54 Ravenscron Drive
Asheville. NC 28801
Phone: [phone]
Fax: [phone](!18
Client Project ID: PIEDMONT GEOLOGIC -9233015
Analysis Method: SM 5310C
Analysis Descrip~ion: Total Organic Carbon QC Batch Method: SM 5310B
Associated Lab Samples: 922282611
922282710
922282819
9'228518'
922282629 922282637 922282645 922282652
922282728
922282959
922285192
922282785
922283007
922285200
922282793
922283015
922285218
922282801
922285176
922285226
METHOD BLANK: 931231252
Associated Lab Samples: 922282611
922282785
922285176
Parameter units
Total Organic carbon mg/1
LABORATORY CONTROL SAMPLE: 931231294
Parameter Units
Total Organic Carbon mg/1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
faram§!t!:!:r Jlnits
Total Organic Carbon mg/1
SAMPLE DUPLICATE: 931231286
Parameter Un!!,;g
Total Organic Carbon mg/1
Dete: 06/11/02
I aboratorv Certification IDs
NC Wastewater 40
NC Drin~ng Water 37712
922282629 922282637 922282645 922282652
922282793 922282801 922282819 922282959
92228518' 922285192 922285200 922285218
Blank Reporting
Result Limit Footnotes
ND
Spike LCS
~ Result
30.00 29.70
931231260 931231278
922282611 Spike
0.50
LCS
% Rec Footnotes
99
MS MSD MS
922282710 922282728
922283007 922283015
922285226
MSD
R§!l!y,lt; ~ Bgsylt B!i!BUl!;, %---R!£ %~ !!fill FQQtnotH
2.970 30.00 33.51 32.95
922282629 DUP
R1sylt Bgsylt 1W [ootngte!I:
2.200 2.500 13
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
102 100 2
Page: 36
Laboratory Certification IDs
TN Drinking Water 02980
SC Environmental 99030
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I aceAnalyticar
wvl\v.pacefabs.oom
I QUALITY CONTROL DATA
Pacs Analytics/ Ssrv/cs1,.lnc.
54 Ravenscroff Drive
Asheville, NC 28801
Phone: [phone]
Fax: 828.252:4618
Lab Project Nwnber: 9329483 I Client Project ID: PIEWONT GEOLOGIC -9233015
------------QC Batch: 27315
I QC Batch Method: SM 5310B
Associated Lab San;:,les:
I
METHOD BLANK: 931233316 I Associated Lab Samples:
I , parameter
Total Organic Carbon
922293188
922293287
922293386
Analysis Method: SM 5310C
Analysis Description: Total Organic Carbon
922293204 922293220 922293261 922293279
922293295 922293303 922293329 922293337
922293188 922293204 922293220 922293261 922293279 922293287
922293303 922293329 922293337 922293386
Blank Reporting
Units RH~lt !,imit [02tnotes
mg/1 ND 0.50
922293295
I LABORATORY CONTROL SAMPLE: 931233357
I Parameter
Total Organic Carbon
Units
mg/1
Spike
~
30.00
LCS
Result
29.70
LCS
~ Footnotes
99
I MATRIX SPIKE• MATRIX SPIKE DUPLICATE: 931233324 931233332
I Parameter
Total Organic Carbon
Units
mg/1
I SAMPLE DUPLICATE: 931233340
Parameter
I Total Organic Carbon
Units
mg/1
I
I
Date: 06/11/02
I
l abtnatO[!i Cer::tlfi~tio□ IDs
I NC Wastewater 40
NC Drinking Water 37712
I
931223143
Result
2.100
Spike
~
30.00
922293220 DUP
Result Result
1'.00 14.00
MS
Result
36.10
MSD
Result
36.(0
RPD footnotes
3
MS MSD
%.J'&Q % Rec ~ Footnotes
113 114 l
REPORT OF LABORATORY ANALYSIS Laboratory Certification 10s
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
TN Drinking Waler 02980
SC Environmental 99030
aceAnalyticar·
www;pacelabs.com
Pac• Analytical Ssmcas,.lnc.
54 lla""1SCfOll Ori'" Ashen/le, NC 288()/
Phone: [phone]
Fax: [phone]
Lab Project Number: 9329483
Client Project ID: PIEDMONT GEOLOGIC -9233015
QUALITY CONTROL DATA PARAMETER FOOTNOTES
Consistent with EPA guidelines, unround.ed concentrations are displayed and. have been used to calculate% Rec and RPD values.
LCS(D) Laboratory Control Sample (Duplicate)
MS(D) Matrix Spike (Duplicate)
DtJP Sample Duplicate
ND Not detected at or above adjusted reporting limit
NC Not Calculable
J Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit Adjusted Method Detection Limit
Relative Percent Difference
MDL
RPD
[1] Due to matrix interference the matrix spike and/or matrix spike duplicate do not provide reliable values. Sample results for this QC batch accepted baaed on LCS and/or LCSD % Recovery and/or RPD values.
Date: 06/11/02
laboratory Certification IDs
NC Wastewater 40
NC Drinking Water 37712
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.
Pa;e: 38
Laboratory Certification 10s
TN Drinking Water 02980
SC Environmen1al 99030
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WW\"1.pacelat:is.c.om
QUALITY CONTROL DATA
Pace Ana/ytltJ!I Services, Inc.
1100 Elm Street, Suite 200
Minneapolis, MN 55414
Phone: 612.6/Jl.1700
Fax: [phone]
Lab Project Number: 1057877
Client Project ID: 9233015 PIEDMONT GEOLOGIC
QC Batch: 74106
QC Batch Method: EPA 3810 Modified
Associated Lab Samples: 922276217
METHOD BLANK: 103582151
Associated Lab Samples: 922276217
P~i:ameter Units
Methane ug/1
Ethane ug/1
Ethane ug/1
Analysis Method: EPA 3810 Modified
Analysis Description: Headspace Analysis
922276225
922276225
Blank Reporting
Resylt Limit [QQtnoteg
ND lO.
ND 20.
ND 20.
LABORATORY CONTROL SAMPLE• LCSD: 103582169 103582177
Spike LCS LCSD LCS LCSD
Param~ter
Methane
Ethane
Ethane
Date: 06/ll/O1
O ,. ACCo•o
,.,_Q ('I<"
?L \t
Units Cone. Result Result % Rec
ug/1 60.60 51.30 '7 .19 85
ug/1 lH.00 98.66 89.'9 86
ug/1 106.00 90.90 82.85 86
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
% Rec
78
78
78
RPD Footnotes
8
lO
9
Page1 12
www:pacelabs.com
QUALITY CONTROL DATA
Pac, Analytical s,rvlcos, Inc.
1700 Elm Street, Suite 2/XJ Minneapo/i~ MN 55414
Phone: [phone]
Fax: [phone]
Lab Project Number: 1057877
Client Project ID: 9233015 PIEDMONT GEOLOGIC
QC Batch: 74332
QC Batch Method; EPA 3810 Modified
Analysis Method: EPA 3810 Modified
Analysis Description: Headspace Analysis Associated Lab Samples: 922282611 922282629 922282637 922282645
METHOD BLANK: 103594800
Associated Lab Samples: 922282611 922282629 922282637 922282645
Blank Reporting farameter units RHult Limit [Qotnotes Methane ug/1 ND 10. Ethane ug/1 ND 20. Ethane ug/1 ND 20.
LABORATORY CONTROL SAMPLE & LCSD: 103594818 103594826
Parameter
Methane
Ethane
Ethene
Da.te: 06/11/02
0 ,• <cco,0
0 ,:;, ~ ~ ~
0 -~L --. -:;;_
Spike LCS LCSD LCS
units Cone, Result Result % Rec
ug/1 60.60 H.49 53.53 73
ug/1 114.00 80.65 102.0 71
ug/1 106.00 75.28 94.23 71
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc,
LCSD
% Rec
BB
90
89
RPD Footnotes
18
23
22
Page: 13
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aceAnalyticar
www.pacelabs.com
QUALITY CONTROL DATA
Pace Analytfcal Services, Inc.
170/J Elm Street, Suite 2/J/J
MinneJpD/i~ MN 55414
Phone: [phone]/J
Fax: 612.61J7.6#1
Lab Project Number: 1057877
Client Project ID: 9233015 PIEDMONT GEOLOGIC
QC Batch: 74407
QC Batch Method: EPA 3810 Modified 1
Associated Lab Samples: 9222826S2
METHOD BLANK: 103597191
922282801
922285176
922285226
Analysis Method: EPA 3810 Modified
Analysis Description: Headspace Analysis
922282710 922282728 922282785 922282793
922282819 922282959 922283007 922283015
922285184 922285192 922285200 922285218
Associated Lab Samples: 922282652 922282710 922282728 922282785 922282793 922282801
922282959 922283007 922283015 922285176 922285184
922285218 922285226
Blank Reporting
Parameter units Result Limit P'ootnotgs
Methane ug/1 ND 10.
Ethane ug/1 ND 20.
Ethane ug/1 ND 20.
LABORATORY CONTROL SAMPLE• LCSD: 103597209 103597217
P!!tam~t,er
Methane
Ethane
Ethane
Date: 06/11/0:l
Spike LCS LCSD LCS
Units ~ Result Resylt ~
ug/1 60.60 67,65 69, 71 112
ug/1 114.00 138.0 135,6 121
ug/1 106,00 126,5 125,0 119
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytlcal Services, Inc.
LCSD
\ Rec
115
119
118
922285192
U!! Fo2~notes
3
2
1
922282819
922285200
Page1 U
ace Analyticar·
www:pacelabs.com
QUALITY CONTROL DATA
Lab Project Number: 1057B77
Pace Analytical Ssrvlcs1, Inc. 1700 Elm Street. Suite 200
Minneapolis, MN 55414
PhOna· 612.61)7.1700
Fax: [phone]
Client Project ID: 9233015 Pizm.toNT GEOLOGIC
QC Batch: 71623
QC Batch Method: EPA 3810 Modified
Associated Lab Samples: 922293188
922293287
922293386
Analysis Method: EPA 3810 Modified
Analysis Description: Headspace Analysis
922293204 922293220 922293261 922293279
922293295 922293303 922293329 922293337
METHOD BLANK: 103609335
Associated Lab Samples: 922293188
922293303
922293204
922293329
922293220
922293337
922293261
922293386
922293279 922293287
Blank Reporting Parameter units Result Limit FQQtn2te1 Methane ug/1 ND 10. Ethane ug/1 ND 20. Ethane ug/1 ND 20.
LABORATORY CONTROL SAMPLE, LCSD: 103609343 103609350
Spike LCS LCSD LCS LCSD Parmt~r Units ~ Regult Resylt !!..Ml, % Rec mi FQQtnQt!i!S Methane ug/1 60.60 47.19 '9.34 78 81 4 Ethane ug/1 11'.00 89.'9 93.6' 78 82 5 Ethane ug/1 106.00 82.85 86.66 78 82 '
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 103609368 103609376
922293220 Spike MS MSD MS MSD Parmter units R!;!:sylt ~ Result Regylt %~ %...B!Q m Methane
Ethane
Ethane
Date: 06/11/02
0 ,. ACCo•o
,_,,t;J (II"
ffL . \\
ug/1 0 U.80 80.52 93.57 ug/1 0 84 .JO 168.2 197 .8
ug/1 0 78.30 157 .2 184.1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full, wtthout the written consent of Pace Analytical Services, Inc.
180 257 15
200 289 16
201 290 16
922293295
footnotes
1,1,2,3
1,1,3,4
1,1,3,5
Page: 15
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c1ceAnalyticar·
Pace Analytlcal S•rvlc••· Inc. 17/XJ Elm Street. Suite 2/XJ
Minneapolis. MN 55414
Phone: [phone]/XJ
Fax: [phone] wl'lw,pace/abs.com
Lab Project Number: 1057877
Client Project ID: 9233015 PIEDMONT GEOLOGIC
QUALITY CONTROL DATA PARAMETER FOOTNOTES
Consistent with EPA guidelines, unrounded concentrations are displayed and have been used to calculate% Rec and RPD values,
LCS(D)
MS(D)
DUP
ND
NC
J
MDL
RPD
Ill
[2]
[3]
[4]
[5]
Laboratory Control Sample (Duplicate)
Matrix Spike (Duplicate)
Sample Duplicate
Not detected at or above adjusted reporting limit
Not Calculable
Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit
Adjusted Method Detection Limit
Relative Percent Difference
The spike recovery was outside of acceptance limits,
RPD is 35.
The calculated RPD was outside QC acceptance limits.
RPD is 37.
RPD is 36.
D11.te: 06/11/02 Pll.ge: 16
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
wtthout the wrltten consent of Pace Analytical Services. Inc.
www.pacetabs.com
Lab Sample No
Identifier
--------------
922276217
922276225
922282611
922282629
922282637
922282645
922282652
922282710
922282728
92l282785
922282793
922282801
922282819
922282959
922283007
922283015
922285176
922285181
922285192
922285200
922285218
922285226
922293188
922293201
922293220
922293261
922293279
922293287
922293295
922293303
922293329
922293337
Data: 06/ll/02
1tl -'CCo
C <;
C " . -, ..... ~ .. _)~
QUALITY CONTROL DATA
CROSS REFERENCE TABLE
Lab Project Number:
Client Project ID:
Client Sample QC Batch QC Batch Identifier Method Identifier ---------------------------------------
MW-348 EPA 3810 Modified 74106
MW-34D EPA 3810 Modified 74106
MW-13 EPA 3810 Modified 74332
MW-27 EPA 3810 Modified 74332 MW-35S EPA 3810 Modified 74332 MW-36D EPA 3810 Modified 74332
MW-40 EPA 3810 Modified 71107 MW-41 EPA 3810 Modified 71107 MW-41I EPA 3810 Modified 71107
MW-12I EPA 3810 Modified 71107 MW-13 EPA 3810 Modified 71107 MW-IS EPA 3810 Modified 71107
MW-16 EPA 3810 Modified 71107 FB-1 EPA 3810 Modified 71107 MW-36DtlP EPA 3810 Modified 74407 MW-29 EPA 3810 Modified 71107 MW-11 EPA 3810 Modified 71107
MW-llI EPA 3810 Modified 74407 MW-12I EPA 3810 Modified 71107 MW-16I EPA 3810 Modified 71107
MW-17I EPA 3810 Modified 74407 MW-38 EPA 3810 Modified 71107
MW-2 EPA 3810 Modified 71623 MW-3 EPA 3810 Modified 71623 MW-6 EPA 3810 Modified 74623 MW-8 EPA 3810 Modified 71623 MW-8 DUP EPA 3810 Modified 71623 MW-12 EPA 3810 Modified 71623 MW-16 EPA 3810 Modified 71623 MW-36S EPA 3810 Modified 74623 MW-37 EPA 3810 Modified 71623
FB-2 EPA 3810 Modified 74623
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
1057877
Pace Analytical Ssrvlcss, Inc.
170/J Elm Street, Suire 200
Minneapolis, MN 55414
Phone: 612.6/JT.1700
Fax: [phone]
9233015 PIEDMONT GEOLOGIC
Analytical
Analytical Batch
Method Identifier
-------------------------
Page: 17
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Lab Sample No
Identifier
922293386
Dat111 06/11102
Client Sample
Identifier
QC Batch
Method
QC Batch
Identifier
MW-17 EPA 3810 Modified 1,623
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
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Pace Analytlcal Sorvlcos, Inc.
1700 Elm Street. Suite 200
Minneapolis, MN 55414
Analytical
Method
Phone· 612.6/J7.1700
Fax: [phone]
Analytical
Batch
Identifier
Page: 18
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One character per box.
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__,/, ace Analytical®
www.pacelabs.com
October 28. 2002
Mr. Pete Dressel
Piedmont Geologic
6003 Chapel Hill Road
Suite 113
Raleigh. NC 27607
RE: Lab Project Number: 9234596
. Client Project ID: Lot 86/2246
Dear Hr. Dressel:
Pace Analytical Services, Inc. 9800 Kincey Avenue, Suite 100 Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
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Enclosed are the analytical results for sample(s) received by the laboratory on July 16. 2002. Results reported herein conform to the most current NELAC standards. where applicable. unless otherwise narrated in the body of the report.
If you have any questions concerning this report please feel free to contact me.
I
Kristi Tart
[e-mail]
Project Manager
Enclosures
I Laboratory Certification IDs NC Wastewater 12
NC Drinking Water 37706 I SC 99006
REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.
Laboratory Certification IDs LA Wastewater 04034
VA Drinking Water 213 FL NELAP E87627
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ace Analytical®
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Lab Sample No: 922391362
Client Sample ID: F8·3
Pace Analytical Services, Inc. 9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Lab Project Number: 9234596
Client Project ID: Lot 86/2246
Phone: [phone]
Fax: [phone]
Project Sample Number: 9234596-001
Matrix: Water
Date Collected: 07/16/02 10:20
Date Received: 07/16/02 16:30
Parameters Results Units Report Limit JlE_ -~An~•~l~yz~e~d~~8~y ~C~A~S~N~o~·-lli!tl_ RegLmt GC Volatiles
GC VOCs in Water
Benzene
Bromobenzene
Bromochloromethane
8romodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butyl benzene
tert-8utylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2·Chlorotoluene
4·Chlorotoluene
l.2•Dibromo·3·chloropropane
Oibromochloromethane
1.2-Dibromoethane (ED8)
Dibromomethane
1.2-Dichlorobenzene
1.3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1.1-Dichloroethane
1,2-Dichloroethane
1,l·Dichloroethene
cis-1.2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1.3-Dichloropropane
2.2-Dichloropropane
l.l·Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethyl benzene
Date; 10/28/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
Method: SM 6230D
ND ug/1_
ND ug/l
ND ug/l
ND ug/l
ND ug/l
ND ug/l
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ug/l
ug/l
ug/1
ug/1
ug/l
ug/l
ug/l
ug/l
ug/l
ug/1
ug/l
ug/1
ug/l
ug/l
ug/1
ug/l
ug/l
ug/l
ug/l
ug/l
ug/1
ug/l
ug/l
ug/l
ug/1
ug/l
ug/l
ug/1
ug/1
ug/l
ug/1
0.50
0.50
0.50
0.50
0.50
0.50
1.0
0.50
0.50
0.50
0.50
0.50
0.50
2.0
0.50
0.50
2.0
0.50
0.50
0.50
1.0
1.0
1.0
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0,50
0.50
0.50
0.50
0,50
1.0 07/17/02 16:41 STC 71•43·2
1.0 07/17/02 16:41 STC 108·86·1
1.0 07/17/02 16:41 STC 74.97.5
1.0 07/17/02 16:41 STC 75-27·4
1.0 07/17/02 16:41 STC 75•25·2
1.0 07/17/02 16:41 STC 74·83·9
1.0 07/17/02 16:41 STC 104-51•8
1.0 07/17/02 16:41 STC 135-98·8
1.0 07/17/02 16:41 STC 98·06·6
1.0 07/17/02 16:41 STC 56-23·5
1.0 07/17/02 16:41 STC 108·90·7
1.0 07/17/02 16:41 STC 75-00·3
1.0 07/17/02 16:41 STC 67-66·3
1.0 07/17/02 16:41 STC 74-87•3
1.0 07/17/02 16:41 STC 95·49·8
1.0 07/17/02 16:41 STC 106·43·4
1.0 07/17/02 16:41 STC 96-12·8
1.0 07/17/02 16:41 STC 124·48·1
1.0 07/17/02 16:41 STC 106·93·4
1.0 07/17/02 16:41 STC 74.95.3
1.0 07/17/02 16:41 STC 95-50•1
1.0 07/17/02 16:41 STC 541·73-l
1.0 07/17/02 16:41 STC 106·46•7
1.0 07/17/02 16:41 STC 75-71·8
1.0 07/17/02 16:41 STC 75.34.3
1.0 07/17/02 16:41 STC 107·06·2
1.0 07/17/02 16:41 STC 75.35.4
1.0 07/17/02 16:41 STC 156·59·2
1.0 07/17/02 16:41 STC 156-60·5
1.0 07/17/02 16:41 STC 78-87·5
1.0 07/17/02 16:41 STC 142·28-9
1.0 07/17/02 16:41 STC 594-20-7
1.0 07/17/02 16:41 STC 563·58-6
1.0 07/17/02 16:41 STC 10061-01·5
1.0 07/17/02 16:41 STC 10061·02·6
1.0 07/17/02 16:41 STC 108·20·3
1.0 07/17/02 16:41 STC 100·41·4
Page: 1 of 16
REPORT OF LABORATORY ANALYSIS Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213 I SC 99006
This report shall not be reproduced. except in full, without the written consent of Pace Analytical Services, Inc. FL NELAP E87627
Pace Analytical Services, Inc. I
ace Analytical® 9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone] I www.pacelabs.com
Lab Sample No: 922391362
Client Sample ID: FB·3
Parameters
Hexachloro-1.3-butadiene
Isopropylbenzene (Cumene)
p-lsopropyltoluene
Methylene chloride
Methyl-tert·butyl ether
Naphthalene
n-Propylbenzene
Styrene
-· 1. 1. 1.2· Tetrachloroethane
1.1.2.2-Tetrachloroethane
Tetrachloroethene
Toluene
1.2.3-Trichlorobenzene
1.2.4-Trichlorobenzene
1.1.l·Trichloroethane
1.1.2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1.2.4-Trimethylbenzene
1.3.5-Trimethylbenzene
Vinyl chloride
m&p•Xylene
o-Xylene
l·Chloro-3-fluorobenzene
Date: 10/28/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
(S)
Results Units
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
97 X
Lab Project Number: 9234596 Fax: [phone]
Client Project ID: Lot 86/2246
Project Sample Number: 9234596·001 Date Collected: 07/16/02 10:20
Matrix: Water Date Received: 07/16/02 16:30
Re~ort Limit _QL Analyzed By CAS No. llifil__ RegLmt
2.0 1.0 07/17/02 16:41 STC 87-68·3
0.50 1.0 07/17/02 16:41 STC 98·82·8
1.0 1.0 07/17/02 16:41 STC 99-87·6
2.0 1.0 07/17/02 16:41 STC 75-09·2
0.50 1.0 07/17/02 16:41 STC 1634-04-4
2.0 1.0 07/17/02 16:41 STC 91-20-3
0.50 1.0 07/17/02 16:41 STC 103-65·1
0.50 1.0 07/17/02 16:41 STC 100-42·5
0.50 1.0 07/17/02 16:41 STC 630-20·6
0.50 1.0 07/17/02 16:41 STC 79.34.5
0.50 1.0 07/17/02 16:41 STC 127·18·4
0.50 1.0 07/17/02 16:41 STC 108-88-3
2.0 1.0 07/17/02 16:41 STC 87-61·6
2.0 1.0 07/17/02 16:41 STC 120·82-l
0.50 1.0 07/17/02 16:41 STC 71-55·6
0.50 1.0 07/17/02 16:41 STC 79-00·5
0.50 1.0 07/17/02 16:41 STC 79-01·6
0.50 1.0 07/17/02 16:41 STC 75·69-4
0.50 1.0 07/17/02 16:41 STC 96-18-4
0.50 1.0 07/17/02 16:41 STC 95-63·6
0.50 1.0 07/17/02 16:41 STC 108-67-8
0.50 1.0 07/17/02 16:41 STC 75-01-4
0.50 1.0 07/17/02 16:41 STC
0.50 1.0 07/17/02 16:41 STC 95-47·6
.1.0 07/17/02 16:41 STC 625·98-9
Page: 2 of 16
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REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Laboratory Certification IDs I
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627 I
I
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ace Analytical®
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
www.pacelabs.com
Lab Sample No: 922391396
Client Sample ID: MW-43
Parameters Results GC Volatiles Units
Lab Project Number: 9234596
Client Project ID: Lot 86/2246
Phone: [phone]
Fax: [phone]
Project Sample Number: 9234596-002
Matrix: Water
Date Collected: 07/16/02 10:30
Date Received: 07/16/02 16:30
Report Limit _Qf_ -~A=na~l-yz=e~d~~B~Y ~C~AS~N=o~·-!l!@L RegLmt
GC voes in Water Method: SM 6230D
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butyl benzene
sec-Butyl benzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2·Chlorotoluene
4-Chl orotol uene
1.2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1.2-Dichlorabenzene
1.3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
l.2·Dichloroethane
l,l·Dichloroethene
cis-1.2-Dichloroethene
trans-1.2-Dichloroethene
1.2-Dichloropropane
1,3-Dichloropropane
2.2-Dichloropropane
1,1-Dichloropropene
cis-1.3-Dichloropropene
trans-1.3-Dichloropropene
Diisopropyl ether
Ethyl benzene
D11te: 10/28/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
ND ug/l 0.50 1.0 07/17/02 18:04 STC ND ug/1 0.50 1.0 07/17/02 18:04 STC ND ug/1 0.50 1.0 07/17/02 18:04 STC ND ug/l 0.50 1.0 07/17/02 18:04 STC ND ug/l 0.50 1.0 07/17/02 18:04 STC ND ug/l 0.50 1.0 07/17/02 18:04 STC ND ug/l 1.0 1.0 07/17/02 18:04 STC ND ug/l 0.50 1.0 07/17/02 18:04 STC ND ug/1 0.50 1.0 07/17/02 18:04 STC ND ug/1 0.50 1.0 07/17/02 18:04 STC ND ug/1 0.50 1.0 07/17/02 18:04 STC ND ug/1 0.50 1.0 07/17/02 18:04 STC 10. ug/1 0.50 1.0 07/17/02 18:04 STC ND ug/1 2.0 1.0 07/17/02 18:04 STC ND ugf.l 0.50 1.0 07/17/02 18:04 STC ND ug/1 0.50 1.0 07/17/02 18:04 STC ND ug/l 2.0 1.0 07/17/02 18:04 STC ND ug/l 0.50 1.0 07/17/02 18:04 STC ND ug/l 0.50 1.0 07/17/02 18:04 STC ND ug/1 0.50 1.0 07/17/02 18:04 STC ND ug/1 1.0 1.0 07/17/02 18:04 STC ND ug/1 1.0 1.0 07/17/02 18:04 STC ND ug/l 1.0 1.0 07/17/02 18:04 STC ND ug/1 0.50 1.0 07/17/02 18:04 STC ND ug/l 0.50 1.0 07/17/02 18:04 STC ND ug/1 0.50 1.0 07/17/02 18:04 STC ND ug/1 0.50 1.0 07/17/02 18:04 STC ND Ug/1 0.50 1.0 07/17/02 18:04 STC ND ug/1 0.50 1.0 07/17/02 18:04 STC ND ug/1 0.50 1.0 07/17/02 18:04 STC ND ug/1 0.50 1.0 07/17/02 18:04 STC ND ug/1 0.50 1.0 07/17/02 18:04 STC ND ug/1 0.50 1.0 07/17/02 18:04 STC ND ug/1 0.50 1.0 07/17/02 18:04 STC ND ug/1 0.50 1.0 07/17/02 18:04 STC ND ug/1 0.50 1.0 07/17/02 18:04 STC ND ug/1 0.50 1.0 07/17/02 18:04 STC
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
71-43-2
108·86·1
74.97.5
75-27-4
75-25-2
74-83-9
104-51-8
135·98·8
98-06-6
56-23·5
108-90-7
75-00-3
67-66-3
74-87-3
95-49-8
106·43·4
96-12-8
124·48·1
106·93·4
74.95.3
95-50-1
541-73-1
106-46-7
75-71-8
75.34.3
107·06·2
75.35.4
156-59·2
156-60-5
78-87-5
142-28-9
594-20-7
563·58·6
10061-01-5
10061-02-6
108-20-3
100·41·4
Page: 3 of 16
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
ace Analytical®
www.pacelabs.com
Lab Sample No: 922391396
Client Sample ID: MW-43
I Pace Analytical Services, Inc. 9800 Kincey Avenue, Suite 100 I Huntersville, NC 28018
Phone.· 104.815.9092
Lab Project Number: 9234596
Client Project ID: Lot 86/2246
Fax: [phone]
I Project Sample Number: 9234596-002
Matrix: Water
Date Collected: 07/16/02 10:30
Date Received: 07/16/02 16:30 I Parameters Results Units ReQQrt Limit JL Anallzed Bl CAS No. Q!§L RegLmt Hexachloro-1,3-butadiene
lsopropylbenzene (Cumene)
p-lsopropyltoluene
Methylene chloride
Methyl-tert-butyl ether
Naphthalene
n-Propylbenzene
,Styrene
. 1, I. 1. 2-Tetrachloroethane
1,1,2,2·Tetrachloroethane
Tetrachloroethene
Toluene
1,2.3-Trichlorobenzene
1,2,4-Trichlorobenzene
1.1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1.2,3-Trichloropropane
1.2,4-Trimethylbenzene
1.3.5-Trimethylbenzene
Vinyl.chloride
m&p-Xylene
a-Xylene
l·Chloro-3·fluorobenzene (S)
Date: 10/28/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
ND ug/1 2,0 1.0 07/17/02 1B:04 STC ND ug/1 0.50 1.0 07/17/02 18:04 STC ND ug/1 1.0 1.0 07/17/02 18:04 STC ND ug/1 2,0 1.0 07/17/02 18:04 STC ND ug/1 0.50 1.0 07/17/02 18:04 STC ND ug/1 2.0 1.0 07/17/02 18:04 STC ND ug/1 0,50 1.0 07/17/02 18:04 STC ND ug/1 0.50 1.0 07/17/02 18:04 STC ND ug/1 0.50 1.0 07/17/02 18:04 STC ND ug/1 0.50 1.0 07/17/02 18:04 STC ND ug/1 0.50 1.0 07/17/02 18:04 STC ND ug/1 0.50 1.0 07/17/02 18:04 STC ND ug/1 2.0 1.0 07/17/02 18:04 STC ND ug/1 2.0 1.0 07/17/02 18:04 STC ND ug/1 0.50 1.0 07/17/02 18:04 STC ND ug/1 0.50 1.0 07/17/02 18:04 STC ND ug/1 0.50 1.0 07/17/02 18:04 STC ND ug/1 0.50 1.0 07/17/02 18:04 STC ND ug/1 0.50 1.0 07/17/02 18:04 STC ND ug/1 0.50 1.0 07/17/02 18:04 STC ND ug/1 0.50 1.0 07/17/02 18:04 STC ND ug/1 0.50 1.0 07/17/02 18:04 STC ND ug/1 0.50 1.0 07/17/02 18:04 STC ND ug/1 0.50 1.0 07/17/02 18:04 STC 103 t 1.0 07/17/02 18:04 STC
REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.
87-68·3
98-82-8
99-87-6
75-09·2
1634-04-4
91-20-3
103-65-1
100-42-5
630-20·6
79.34.5
127-18·4
108-88-3
87-61·6
120-82·1
71-55-6
79-00-5
79-01-6
75-69-4
96-18-4
95-63-6
108-67·8
75-01-4
95-47-6
625-98·9
Page: 4 of 16
Laboratory Certification IDs LA Wastewater 04034 VA Drinking Water 213 FL NELAP E87627
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I Pace Analytical Services, Inc. ace Analytical® 9800 Kincey Avenue, Suite 100 Huntersville, NC 28078 I Phone: [phone] www.pacelabs.com
Fax: [phone] Lab Project Number: 9234596
Client Project ID: Lot 86/2246 I Lab Sample No: 922391446 Project Sample Number: 9234596-004 Date Collected: 07/16/02 00:00 Client Sample ID: TRIP BLANK Matrix: Water Date Received: 07 /16/02 16:30 :I Parameters Results Units Re(2ort Limit __QE_ Anal ~zed 8~ CAS No. lli@l... RegLmt I GC Volatiles
GC voes in Water Method: SM 62300 I Benzene ND ug/1 0.50 1.0 07/17/02 15:59 STC 71-43-2 Bromobenzene ND ug/1 0.50 1.0 07/17/02 15:59 STC 108-86-1 Bromochloromethane ND ug/1 0.50 1.0 07/17/02 15:59 STC 74-97-5 I Bromodichloromethane ND ug/1 0.50 1.0 07/17/02 15:59 STC 75-27-4 Br'omoform ND ug/1 0.50 1.0 07/17/02 15:59 STC 75-25-2 Bromomethane ND ug/1 0.50 1.0 07/17/02 15:59 STC 74-83-9 n-Butylbenzene ND ug/1 1.0 1.0 07/17/02 15:59 STC 104-51-8 1-sec-Butyl benzene ND ug/1 0.50 1.0 07/17/02 15:59 STC 135-98-8 tert-Butylbenzene ND ug/1 0.50 1.0 07/17/02 15:59 STC 98-06-6 Carbon tetrachloride ND. ug/1 0.50 1.0 07/17/02 15:59 STC 56-23-5 I Chl orobenzene ND ug/1 0.50 1.0 07/17/02 15:59 STC 108-90-7 Chloroethane ND ug/1 0.50 1.0 07117/02 15:59 STC 75-00-3 Chloroform ND ug/1 0.50 1.0 07/17/02 15:59 STC 67-66-3 I Chloromethane ND ug/1 2.0 1.0 07/17/02 15:59 STC 74-87-3 2-Chlorotoluene ND ug/1 0.50 1.0 07/17/02 15:59 STC 95-49-8 4-Chl orotol uene ND ug/1 0.50 1.0 07/17/02 15:59 STC 106-43-4 1,2-Dibromo-3-chloropropane ND ug/1 2.0 1.0 07/17/02 15:59 STC 96-12·8 I Dibromochloromethane ND ug/1 0.50 1.0 07/17/02 15:59 STC 124-48-1 1,2-Dibromoethane (EDS) ND ug/1 0.50 1.0 07/17/02 15:59 STC 106-93-4 Di bromomethane ND ug/l 0.50 1.0 07/17/02 15:59 STC 74-95-3 I 1,2-Dichlorobenzene ND ug/1 1.0 1.0 07/17/02 15:59 STC 95-50-1 1,3-Dichlorobenzene ND ug/1 1.0 1.0 07/17/02 15:59 STC 541-73-1 1,4-Dichlorobenzene ND ug/1 1.0 1.0 07/17/02 15:59 STC 106-46-7 Dichlorodifluoromethane ND ug/1 0,50 1.0 07/17/02 15:59 STC 75-71-8 I 1.1-Dichloroethane ND ug/1 0,50 1.0 07/17/02 15:59 STC 75-34-3 1.2-Dichloroethane ND ug/1 0,50 1.0 07/17/02 15:59 STC 107-06-2 1.1-Dichloroethene ND ug/1 0.50 1.0 07/17/02 15:59 STC 75-35-4 I cis-1.2-Dichloroethene ND ug/1 0.50 1.0 07/17/02 15:59 STC 156-59-2 trans-1.2-Dichloroethene ND ug/1 0.50 1.0 07/17/02 15:59 STC 156-60-5 1,2-Dichloropropane ND ug/1 0,50 1.0 07/17/02 15:59 STC 78-87-5 I 1,3-Dichloropropane ND ug/1 0,50 1.0 07/17/02 15:59 STC 142-28·9 2,2-Dichloropropane ND ug/1 0,50 1.0 07/17/02 15:59 STC 594-20-7 1.1-Dichloropropene ND ug/1 0.50 1.0 07/17/02 15:59 STC 563-58-6 cis-1,3-Dichloropropene ND ug/1 0.50 1.0 07/17/02 15:59 STC 10061-01-5 I trans-1,3-Dichloropropene ND ug/1 0.50 1.0 07/17/02 15:59 STC 10061-02-6 Diisopropyl ether ND ug/1 0.50 1.0 07/17/02 15:59 STC 108-20-3 Ethyl benzene ND ug/1 0.50 1.0 07/17/02 15:59 STC 100-41-4 I
Date: 10120102
Page: 5 of 16 I
I Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.
Laboratory Certification !Ds LA Wastewater 04034 VA Drinking Water 213
FL NELAP E87627 I ,~ •c;ca• t~£ti,
I ace Analytical® Pace Analytical Services, Inc. 9800 Kincey Avenue, Suite 100 I Huntersville, NC 28078
www.pacelabs.com
Phone: [phone]
Lab Sample No: 922391446 Client Sample ID: TRIP BLANK
Parameters
Hexachloro-1.3-butadiene
Isopropylbenzene (Cumene) p·lsopropyltoluene
Methylene chloride
Methyl-tert•butyl ether
Naphthalene
n-Propylbenzene
Styrene
1.1.1.2-Tetrachloroethane
l.l.2.2·Tetrachloroethane
Tetrachloroethene
Toluene
l.2.3·Trichlorobenzene
1.2.4-Trichlorobenzene
1.1.l·Trichloroethane
1.1.2· Trichloroethane
Tri ch loroethene
Trichlorofluoromethane
1.2.3-Trichloropropane
1.2.4-Trimethylbenzene
1.3.5-Trimethylbenzene
Vinyl chloride
m&p-Xylene
O·Xylene
l·Chloro•3·fluorobenzene (S)
Date: 10/28/02
Laboratory Certification IDs NC Wastewater 12
NC Drinking Water 37706 SC 99006
Lab Project Number: 9234596
Client Project ID: Lot 86/2246
Fax: [phone]
I
Results Units
Project Sample Number: 9234596-004
Matrix: Water
ReQQrt Limit J[___ Anal tzed
Date Collected: 07/16/02 00:00
Date Received: 07/16/02 16:30 I ND ug/l 2. 0 Bl CAS No. !l!@l_ Reglmt 1.0 07/17/02 15:59 STC ND Ug/.l 0.50 1.0 07/17/02 15:59 STC ND ug/l 1.0 1.0 07/17/02 15:59 STC ND ug/l 2.0 1.0 07/17/02 15:59 STC ND Ug/l 0.50 1.0 07/17/02 15:59 STC ND ug/l 2.0 1.0 07/17/02 15:59 STC ND ug/l 0.50 1.0 07/17/02 15:59 STC ND ug/l 0.50 1.0 07/17/02 15:59 STC ND Ug/l 0.50 1.0 07/17/02 15:59 STC ND ug/l 0.50 1.0 07/17/02 15:59 STC ND ug/l 0.50 1.0 07/17/02 15:59 STC ND ug/1 0.50 1.0 07/17/02 15:59 STC ND Ug/l 2. 0 1.0 07/17/02 15:59 STC ND ug/1 2.0 1.0 07/17/02 15:59 STC ND ug/l 0.50 1.0 07/17/02 15:59 STC ND Ug/1 0.50 1.0 07/17/02 15:59 STC ND ug/1 0.50 1.0 07/17/02 15:59 STC ND Ug/l 0.50 1.0 07/17/02 15:59 STC ND ug/l 0.50 1.0 07/17/02 15:59 STC ND Ug/l 0.50 1.0 07/17/02 15:59 STC ND ug/l 0.50 1.0 07/17/02 15:59 STC ND ug/l 0.50 1.0 07/17/02 15:59 STC ND ug/l 0.50 1.0 07/17/02 15:59 STC ND ug/1 0.50 1.0 07/17/02 15:59 STC 101 t
1.0 07/17/02 15:59 STC
REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.
87·68-3
98·82·8
99·87-6
75•09·2
1634·04·4
91-20·3
103-65-1
100-42-5
630-20-6
79.34.5
127·18-4
108·88-3
87-61·6
120·82·1
71.55.5
79•00-5
79•01 ·6
75.59.4
96·18·4
95·63·6
108-67•8
75•01 ·4
95.47.5
625-98·9
Page: 6 of 16
Laboratory Certification 10, LA Wastewater 04034 VA Drinking Water 213 FL NELAP E87627
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ace Analytical"
www.pacelabs.com
PARAMETER FOOTNOTES
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Lab Project Number: 9234596
Client Project ID: Lot 86/2246
Phone: [phone]
Fax: [phone]
Dilution factor shown represents the factor applied to the reported result and reporting limit due to changes
in sample preparation, dilution of the extract. or moisture content
Not detected at or above adjusted reporting limit
Not Calculable
ND
NC
J
MDL
(S)
Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit
Adjusted Method Detection Limit
Surrogate
Date: 10/2B/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Page: 7 of 16
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
ace Analyticar
www.pacelabs.com
QC Batch: 60279
QUALITY CONTROL DATA
I
Pace Analytical Services, Inc. 9800 Kincey Avenue, Suite 100 I Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Lab Project Number: 9234596
Client Project ID: Lot 86/2246
I
I Analysis Method: SM 62300 Analys·is Description: GC voes in Water
QC Batch Method: SM 62300 Associated Lab Samples: 922391362 922391396 922391446
I METHOD BLANK: 922392352
Associated Lab Samples:
Paranieter
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butyl benzene
tert-Butylbenzene
Carbon tetrachloride
Ch l orobenzene.
Chloroethane
Chloroform
Chloromethane
2 ·Chl orotol uene
4·Chlorotoluene
l.2·Dibromo·3·chloropropane
Dibromochloromethane
!,2·Dibromoethane (EDS)
Dibromomethane
!,2·Dichlorobenzene
l.3·Dichlorobenzene
1.4-Dichlorobenzene
Dichlorodifluoromethane
1.1-Dichloroethane
l,2·Dichloroethane
l.l·Dichloroethene
cis-1,2-Dichloroethene
trans·l.2·Dichloroethene
!,2·Dichloropropane
I. 3·Di chl oropropane
Date: 10/28/02
laboratory Certification IDs NC Wastewater 12 NC Drinking Water 37706 SC 99006
922391362 922391396 922391446
Blank Reporting Units Result limit Footnotes ug/l ND 0.50 ug/l ND 0.50 ug/l ND 0.50 ug/l ND 0.50 ug/l ND 0.50 ug/l ND 0.50 ug/l ND 1.0 ug/l ND 0.50 ug/l ND 0.50 ug/l ND 0.50 ug/l ND 0.50 ug/l ND 0.50 ug/l ND 0.50 ug/l ND 2.0 ug/l ND 0.50 ug/l ND 0.50 ug/l ND 2.0 ug/l ND 0.50 ug/l ND 0.50 ug/l ND 0.50 ug/l ND 1.0 ug/l ND 1.0 ug/l ND 1.0 ug/l ND 0.50 ug/l ND 0.50 ug/l ND 0.50 ug/1 ND 0.50 ug/l ND 0.50 ug/l ND 0.50 ug/l ND 0.50 ug/1 ND 0.50
REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.
Page: 8 of 16
laboratory Certification IDs LA Wastewater 04034 VA Drinking Water 213 Fl NELAP E87627
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ace Analytical"
www.pacelabs.com
METHOD BLANK: 922392352
Associated Lab Samples:
Parameter
2.2·Dichloropropane
l.l·Dichloropropene
cis·l,3-Dichloropropene
trans-1.~-Dichloropropene
Diisopropyl ether
Ethyl benzene
Hexachloro·l.3-butadiene
lsopropylbenzene (Cumene)
p-Isopropyltoluene
Methylene chloride
Methyl -tert-butyl ether
Naphthalene
n-Propyl benzene
Styrene
1,1,1,2-Tetrachloroethane
1.1.2.2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2.3-Trichlorobenzene
1.2.4-Trichlorobenzene
1,1,1-Trichloroethane
1.1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
l.2,4·Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
m&p•Xylene
a-Xylene
l·Chloro-3-fluorobenzene
Date: 10/28/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
922391362
Units
ug/l
ug/1
ug/l
ug/1
ug/l
ug/l .
ug/1
ug/l
ug/1
ug/l
ug/l
ug/l
ug/l
ug/1
ug/l
ug/l
ug/l
ug/l
ug/l
ug/1
ug/l
ug/l
ug/l
ug/1
ug/1
ug/l
ug/1
ug/l
ug/l
ug/l
(SJ t
QUALITY CONTROL DATA
Lab Project Number:
Client Project IO:
922391396 922391446
Blank Reporting
Result Limit Footnotes
NO 0.50
NO 0.50
ND 0.50
NO 0.50
ND 0.50
NO 0.50
NO 2.0
ND 0.50
NO 1.0
ND 2.0
ND 0.50
NO 2.0
ND 0.50
NO 0.50
ND 0.50
ND 0.50
NO 0.50
NO 0.50
NO 2.0
NO 2.0
ND 0.50
ND 0.50
ND 0.50
ND 0.50
NO 0.50
ND 0.50
NO 0.50
NO 0.50
ND 0.50
NO 0.50
111
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
9234596
Pace Analytical Services. Inc.
9800 Kincey Avenue. Suite 100
Huntersville. NC 28078
Phone: [phone]
Fax: [phone]
Lot 86/2246
Page: 9 of 16
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
ace Analytical®
www.pacelabs.com QUALITY CONTROL DATA
Lab Project Number:
Client Project ID:
LABORATORY CONTROL SAMPLE: 922392360
Spike LCS LCS Parameter Units Cone. Result X Rec Footnotes Benzene ug/1 20.00 19.57 98 Bromobenzene ug/1 20.00 25.75 129 Bromochloromethane ug/1 20.00 22.60 113 BrolOOdichloromethane ug/1 20.00 23.21 116 Bromoform ug/1 20.00 23.22 116 Bromomethane ug/1 20.00 21.31 107 n°Butylbenzene ug/1 20.00 21.05 105 sec-Butyl benzene ug/1 20.00 21.65 108 tert-Butylbenzene ug/1 20.00 21.89 109 Carbon tetrachloride ug/1 20.00 25.16 126 Chlorobenzene ug/1 20.00 22.49 112 Chl oroethane ug/1 20.00 21.84 109 Chloroform ug/1 20.00 23.21 116 Chloromethane ug/1 20.00 21.14 106 2 · Chl oroto 1 uene ug/1 20.00 25.95 130 4·Chlorotoluene ug/1 20.00 25. 71 129 l.2·Dibromo-3•chloropropane ug/1 20.00 24.44 122 DibrollXlchloromethane ug/1 20.00 24.24 121 1.2-Dibromoethane (EDB) ug/1 20.00 24.91 125 Di bromomethane ug/1 20.00 23.08 115 1.2-Dichlorobenzene ug/1 20.00 23.58 118 1,3-Dichlorobenzene ug/1 20.00 24. 18 121 1.4-Dichlorobenzene ug/1 20.00 25.17 126 Dichlorodifluoromethane ug/1 20.00 20.31 102 1.1-Dichloroethane ug/1 20.00 22.56 113 l.2·Dichloroethane ug/1 20.00 21.16 106 1.1-Dichloroethene ug/1 20.00 22.33 112 cis-1.2-Dichloroethene ug/1 20.00 23.17 116 trans•l,2·Dichloroethene ug/1 20.00 21.99 110 l,2·Dichloropropane ug/1 20.00 22.95 115 l.3·Dichloropropane ug/1 20.00 23.80 119 2,2-Dichloropropane ug/1 20.00 25.41 127 1,1-Dichloropropene ug/1 20.00 25.08 125 cis-1,3-Dichloropropene ug/1 20.00 21.31 107 trans-1,3-Dichloropropene ug/1 20.00 22.28 111 Diisopropyl ether ug/1 20.00 29.86 149 Ethyl benzene ug/1 20.00 21.09 105
Date: 10/28/02
Laboratory Certification IDs
NC Wastewater 12 REPORT OF LABORATORY ANALYSIS
NC Drinking Water 37706
SC 99006
This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.
9234596
Pace Analytical Services. Inc. 9800 Kincey Avenue. Suite 100
Huntersville. NC 28078
Phone: [phone]
Fax: [phone]
Lot 86/2246
Page: 10 of 16
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
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ace Analytical"
www.pacelabs.com
LABORATORY CONTROL SAMPLE: 922392360
Parameter Units
Hexachloro-1.3-butadiene ug/1
Isopropylbenzene (Cumene) ug/1
p-lsopropyltoluene ug/l
Methylene chloride ug/1
Methyl-tert•butyl ether ug/1
Naphthalene ug/l
n·Propylbenzene ug/1
Styrene ug/1
1,1.1,2-Tetrachloroethane ug/1
1.1.2.2-Tetrachloroethane ug/1
Tetrachloroethene ug/l
Toluene ug/1
1.2.3-Trichlorobenzene ug/1
1,2,4-Trichlorobenzene ug/1
1.1.l·Trichloroethane ug/l
1.1.2-Trichloroethane ug/1
Trichloroethene ug/1
Trichlorofluoromethane ug/1
1.2.3-Trichloropropane ug/1
1.2.4-Trimethylbenzene ug/1
1.3.5-Trimethylbenzene ug/l
Vinyl chloride ug/1
m&p-Xylene ug/1
o-Xylene ug/1
l·Chloro-3-fluorobenzene (S)
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
QUALITY CONTROL DATA
Lab Project Number:
Client Project ID:
Spike LCS LCS
Cone. Result X Rec Footnotes
20.00 21.44 107
20.00 20.97 105
20.00 20.53 103
20.00 21. 77 109
20.00 19.51 98
20.00 19.95 100
20.00 21.28 106
20.00 20.24 101
20.00 21.56 108
20.00 23.13 116
20.00 22.74 114
20.00 20.57 103
20.00 24.24 121
20.00 20.80 104
20.00 25.07 125
20.00 23.84 119
20.00 21. 95 110
20.00 22.92 115
20.00 20.76 104
20.00 20.90 104
20.00 20.87 104
20.00 22.43 112
40.00 45.62 114
20.00 20.91 105
110
922392386 922392394
922391396 Spike MS MSD
9234596
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Lot 86/2246
MS MSD
Parameter Units Result Cone. Result Result X Rec X Rec RPO Footnotes
Benzene
Brmoobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
Date: 10/28/02
Laboratory Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
ug/1
ug/l
ug/1
ug/1
ug/1
ug/1
0 20.00 18.32 18.41
0 20.00 22.90 22.48
0 20.00 20.81 19.08
0 20.00 22.35 20.27
0 20.00 19.41 19.86
0 20.00 16.12 16.88
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced. except in full,
without the written consent of Pace Analytical Services, Inc.
,~ -~~Co~ ii:l1eil~11
92 92 1
114 112 2
104 95 9
112 101 10
97 99 2
81 84 5
Page: 11 of 16
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
Pace Analytical Services, Inc. I ace Analytical® 9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
QUALITY CONTROL DATA Phone: [phone] I www.pacelabs.com Fax. [phone]
Lab Project Number: 9234596 I Client Project ID: Lot 86/2246
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 922392386 922392394 I 922391396 Spike MS MSD MS MSD Parameter Units Result Cone. Result Result t Rec t Rec RPD Footnotes I n-8utylbenzene ug/1 0 20.00 19.04 19.01 95 95 0 sec-Butyl benzene ug/1 0 20.00 19.67 19.57 98 98 1 tert-Butylbenzene ug/1 0 20.00 20.11 20.07 100 100 0 Carbon tetrachloride ug/1 0 20.00 21. 70 19.62 108 98 10 I Ch 1 orobenzene ug/1 0 20.00 21.00 20.52 105 103 2 Chloroethane ug/1 0 20.00 19.03 17 .77 95 89 7 Chloroform ug/1 10.35 20.00 28.01 25.39 88 75 10 I Chl oromethane ug/1 0 20.00 18.20 16.19 91 81 12 2-Chlorotoluene ug/1 0 20.00 23.31 21.64 117 108 7 4-Chlorotoluene ug/1 0 20.00 23.49 21.68 117 108 8 1.2-Dibromo-3-chloropropane ug/1 0 20.00 21.42 24.56 107 123 14 I Dibromochloromethane ug/1 0 20.00 22.07 20.96 110 105 5 1.2-Dibromoethane (EDB) ug/1 0 20.00 22.57 21. 76 113 109 4 Di bromomethane -ug/1 0 20.00 21.02 19.55 105 98 7 I 1.2-Dichlorobenzene ug/1 0 20.00 21.22 20.13 106 101 5
1.3-Dichlorobenzene ug/1 0 20.00 22.34 20.57 112 103 8 1,4-Dichlorobenzene ug/1 0 20.00 23.18 21.60 116 108 7 I Dichlorodifluoromethane ug/1 0 20.00 15.79 13.42 79 67 16 1.1-Dichloroethane ug/1 0 20.00 20.83 19.04 104 95 9 1.2-Dichloroethane ug/1 . 0 20.00 19. 77 18.06 99 90 9 1.1-Dichloroethene ug/1 0 20.00 20.01 17.83 100 89 12 I cis-1,2-Dichloroethene ug/1 0 20.00 21.59 19.41 108 97 11 trans-1.2-Dichloroethene ug/1 0 20.00 20.41 18.26 102 91 11 1.2-Dichloropropane ug/1 0 20.00 21.36 19.54 107 98 9 I 1,3-Dichloropropane ug/1 0 20.00 21.32 20.40 107 102 4 2.2-Dichloropropane ug/1 0 20.00 22.21 20.37 111 102 9
1.1-Dichloropropene ug/1 . 0 20.00 23.72 21.17 119 106 11
cis-1,3-0ichloropropene ug/1 0 20.00 19.57 17.90 98 90 9 I trans-1.3-DiChloropropene ug/1 0 20.00 20.06 18.87 100 94 6 Diisopropyl ether ug/1 0 20.00 28.76 29.19 144 146 1 Ethyl benzene ug/1 0 20.00 19.54 19.61 98 98 0 I Hexachloro-1.3-butadiene ug/1 0 20.00 19.55 18.23 98 91 7 Isopropylbenzene (Cumene) ug/1 0 20.00 19.37 19.33 97 97 0 p-Isopropyltoluene ug/1 0 20.00 18.78 18. 72 94 94 0 I Methylene chloride ug/1 0 20.00 18.80 16, 94 94 85 10 Methyl-tert-butyl ether ug/1 0 20.00 19.06 19.00 95 95 0 Naphthalene ug/1 0 20.00 17.64 .19.35 88 97 9
Date: 10/28/02 Page: 12 of 16
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LabQratori Ce[!ifi,ation IDs REPORT OF LABORATORY ANALYSIS La!lQratQ[)' Certifi,atiQD IDi; I NC Wastewater 12 LA Wastewater 04034 NC Drinking Water 37706 This report shall not be reproduced, except in full, VA Drinking Water 213 SC 99006 without the written consent of Pace Analytical Services, Inc. FL NELAP E87627 I 1/:.~,,-~.~~--!f~f,
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~e Analytical"
Pace Analytical Services, Inc,
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
QUALITY CONTROL DATA Phone: [phone] www.pacelabs.com Fax: [phone]
Lab Project Number: 9234596
Client Project ID: Lot 86/2246
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 922392386 922392394
922391396 Spike HS HSD HS HSD
Parameter Units Result Cone. Result Result t Rec t Rec RPD Footnotes
n-Propylbenzene ug/1 0 20.00 19.50 19.46 98 97 0 Styrene ug/1 0 20.00 17.70 18.22 88 91 3
l.l.l.2·Tetrachloroethane ug/1 0 20.00 19.45 17 .86 97 89 8
l.l.2.2·Tetrachloroethane ug/1 0 20.00 21.61 21.07 108 105 2 Tetrachloroethene ug/1 0 20.00 20.98 19.82 105 99 6 Toluene ug/1 0 20.00 19.29 19.66 96 98 2
l.2.3·Trichlorobenzene ug/1 0 20.00 20.90 21.33 104 107 2
1.2.4-Trichlorobenzene ug/1 0 20.00 18.93 18.32 95 92 3
1.1.1-Trichloroethane ug/1 0 20.00 23.20 20.96 116 105 10
1.1.2-Trichloroethane ug/1 0 20.00 22.22 20.88 111 104 6 Trichloroethene ug/1 0 20.00 21.31 19.27 107 96 10
Trichlorofluoromethane ug/1 0 20.00 20.57 18.64 103 93 10
l.2.3·Trichloropropane ug/1 0 20.00 18.22 19.21 91 96 5
1.2.4-Trimethylbenzene ug/1 0 20.00 19.28 19.45 96 97 1
1.3.5-Trimethylbenzene ug/1 0 20.00 19.17 19.31 96 97 1
Vinyl chloride ug/1 0 20.00 19.35 17.06 97 85 13
m&p-Xylene ug/1 0 40.00 42.36 42.31 106 106 0
a-Xylene ug/1 0 20.00 19. 71 19.55 99 98 1
l-Chloro-3-fluorobenzene (SJ 101 100
SAMPLE DUPLICATE: 922429964
922391289 DUP
Parameter Units Result Result RPD Footnotes
Benzene ug/1 49.00 52.00 5
Bromobenzene ug/1 ND ND NC
Bromochloromethane ug/1 ND ND NC
Bromodichloromethane ug/1 ND ND NC
Bromoform ug/1 ND ND NC
Bromomethane ug/1 ND ND NC
n-Butylbenzene ug/1 3.400 3.800 10
sec-Butyl benzene ug/1 ND 0.5600 0
tert-8utylbenzene ug/1 ND ND NC
Carbon tetrachloride ug/1 ND ND NC
Chlorobenzene ug/1 ND ND NC
Chloroethane ug/1 ND ND NC
Date: 10/28/02 Page: 13 of 16
Laboratory Certification IDs
NC Wastewater 12 REPORT OF LABORATORY ANALYSIS Laboratory Certification IDs
LA Wastewater 04034 NC Drinking Water 37706
SC 99006
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc. VA Drinking Water 213
FL NELAP E87627
ae Analytical'
www.pacelabs.com QUALITY CONTROL DATA
Lab Project Number:
Client Project ID:
SAMPLE DUPLICATE: 922429964
922391289 DUP
Parameter Units Result Result RPO Footnotes
Chloroform ug/1 ND ND NC Chloromethane ug/1 ND ND NC 2-Chlorotoluene ug/1 ND ND NC 4-Chlorotoluene ug/1 ND ND NC 1.2-Dibromo-3-chloropropane ug/1 ND ND NC Dibromoch1oromethane ug/1 ND ND NC 1:2-0ibromoethane (ED8) ug/1 ND ND NC
Dibromomethane ug/1 ND ND NC 1,2-Dichlorobenzene ug/1. ND ND NC 1,3-Dichlorobenzene ug/1 ND ND NC 1,4-0ichlorobenzene ug/1 ND ND NC Dichlorodifluoromethane ug/1 ND ND NC 1,1-Dichloroethane ug/1 ND ND NC
1,2-Dichloroethane ug/1 ND ND NC
1,1-Dichloroethene ug/1 ND ND NC
cis-1,2-Dichloroethene ug/1 ND ND NC
trans-1.2-Dichloroethene ug/1 ND ND NC 1,2-Dichloropropane ug/1 ND ND NC 1.3-0ichloropropane ug/1 ND ND NC 2.2-Dichloropropane ug/1 ND ND NC 1,l·Dichloropropene ug/1 ND ND NC
cis-1,3-0ichloropropene ug/1 ND ND NC
trans-1,3-Dichloropropene ug/1 ND ND NC Diisopropyl ether ug/1 6.000 5.700 5 Ethyl benzene ug/1 13.00 14.00 4 Hexachloro-1.3-butadiene ug/1 ND ND NC
Jsopropylbenzene (Cumene) ug/1 . 0.7000 0.8100 14 p-Isopropyltoluene ug/1 ND ND NC Methylene chloride ug/1 ND ND NC Methyl-tert-butyl ether ug/1 770.0 780.0 1 Naphthalene ug/1 28.00 31.00 10
n-Propylbenzene ug/1 1.300 1.500 10 Styrene ug/1 ND ND NC
1.1.i.2-Tetrachloroethane ug/1 ND ND NC
1.1,2,2-Tetrachloroethane ug/1 ND ND NC Tetrachloroethene ug/1 ND ND NC
Toluene ug/1 47 .00 49.00 4
Date: 10/28/02
Laboratory Certification IDs
NC Wastewater 12 REPORT OF LABORATORY ANALYSIS
NC Drinking Water 37706
SC 99006
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
9234596
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Lot 86/2246
Page: 14 of 16
Laborato[Y Certifi,ation ID,
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
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ace Analytical®
www.pacelabs.com QUALITY CONTROL DATA
· Lab Project Number:
Client Project ID:
SAMPLE DUPLICATE: 922429964
922391289 DUP
Parameter Units Result Result RPO Footnotes
1.2.3-Trichlorobenzene ug/1 ND ND NC
1.2.4-Trichlorobenzene ug/1 ND ND NC
1.1,l·Trichloroethane ug/1 ND ND NC
1.1.2-Trichloroethane ug/1 ND ND NC
Tri ch l oroethene ug/1 ND ND NC
Trichlorofluoromethane ug/1 ND ND NC
1.2.3-Trichloropropane ug/1 ND ND NC
1,2,4-Trimethylbenzene ug/1 36.00 38.00 5
1,3,5-Trimethylbenzene ug/1 8.200 8. 700 6
Vinyl chloride ug/1 ND ND NC
m&p-Xylene ug/1 79.00 83.00 4
a-Xylene ug/1 29.00 30.00 4
l·Chloro-3-fluorobenzene (S) ¼ 98 96
Date: 10/28/02
Laboratory Certification IDs
NC Wastewater 12 REPORT OF LABORATORY ANALYSIS
NC Drinking Water 37706
SC 99006
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
9234596
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Lot 86/2246
Page: 15 of 16
Laboratory Certification IDs
LA Wastewater 04034
VA Drinking Water 213
FL NELAP E87627
~e Analytical"
www.pacelabs.com
QUALITY CONTROL DATA PARAMETER FOOTNOTES
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Lab Project Number: 9234596
Client Project ID: Lot 86/2246
Phone: [phone]
Fax: [phone]
Consistent with EPA guidelines. unrounded concentrations are displayed and have been used to calculate X Rec and·RPD values.
LCS(D)
MS(DJ
DUP
ND
NC
J
MDL
RPO
(SJ
Laboratory Control Sample (Duplicate)
Matrix Spike (Duplicate)
Sample Duplicate
Not detected at or above adjusted reporting limit
Not Calculable
Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit Adjusted Method Detection Limit
Relative Percent Difference
Surrogate
Date: 10/28/02 Page: 16 of 16
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Laboratory Certificar,on IDs
NC Wastewater 12 REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Laboratory Certification IDs I
LA Wastewater 04034 NC Drinking Water 37706
SC 99006
VA Drinking Water 213
FL NELAP E87627 I
l'AKAUlliJVI ANALYTICAL LAISUKAIUKrn:S, INC.
I Results for Volatiles
byGC6230D
I Client Sample ID: 2391420/MW-43 DUP Analyzed By: EKR
Client Project ID: 34596 Date Collected: 7/16/02
Lab Sample ID: 49028 Date Received: 7/19/02 I Lab Project ID: G150-313. Matrix: Water
I Compound Date Quantitation Result
Analyzed Dilution Limit (ug/L) (ug/L)
I Benzene 7/22/02 0.5 BQL
Bromobenzene 7/22/02 1 0.5 BQL
Bromochloromethane 7/22/02 1 0.5 BQL I Bromodichloromethane 7/22/02 1 0.5 BQL
Bromoform 7/22/02 1 0.5 BQL
Bromomethane 7/22/02 1 0.5 BQL I n-Butylbenzene 7/22/02 0.5 BQL
sec-Butylbenzene 7/22/02 1 0.5 BQL
tert-Butylbenzene 7/22/02 1 0.5 BQL
I Carbon tetrachloride 7/22/02 0.5 BQL
Chlorobenzene 7/22/02 . 1 0.5 BQL
Chloroethane 7/22/02 1 0.5 BQL
I Chloroform 7/22/02 1 0.5 10
Chloromethane 7/22/02 1 0.5 BQL
2-Chlorotoluene 7/22/02 1 0.5 BQL
I 4-Chlorotoluene 7/22/02 1 0.5 BQL
Dibromochloromethane 7/22/02 1 0.5 BQL
1,2-Dibromo-3-chloropropane 7/22/02 1 0.5 BQL
I 1,2-Dibromoethane (EDB) 7/22/02 0.5 BQL
Dibromomethane 7/22/02 1 0.5 BQL
1,2-Dichlorobenzene 7/22/02 1 0.5 · BQL
I 1,3-Dichlorobenzene 7/22/02 0.5 BQL
1 ,4-Dichlorobenzene 7/22/02 1 0.5 BQL
Dichlorodifluoromethane 7/22/02 1 0.5 BQL
I 1 , 1-Dichloroethane 7/22/02 0.5 BQL
1,2-Dichloroethane 7/22/02 1 0.5 BQL
1, 1-Dichloroethene 7/22/02 1 0.5 BQL
D cis-1,2-Dichloroethene 7/22/02 0.5 BQL
trans-1,2-Dichloroethene 7/22/02 1 0.5 BQL
1,2-Dichloropropane 7/22/02 1 0.5 BQL
I 2,2-Dichloropropane 7/22/02 1 0.5 . BQL
cis-1,3-Dichloropropene 7/22/02 1 0.5 BQL
trans-1,3-Dichloropropene 7/22/02 1 0.5 BQL
I Diisopropyl ether (DIPE) 7/22/02 1 0.5 BQL
Ethylbenzene 7/22/02 1 0.5 BQL
Hexachlorobutadiene 7/22/02 1 0.5 BQL
I lsopropylbenzene 7/22/02 0.5 BQL
p-lsopropyltoluene 7/22/02 0.5 BQL
Methyl-tert butyl ether (MTBE) 7/22/02 1 0.5 BQL
I Methylene Chloride 7/22/02 1 5 BQL
Flags:
I BQL = Below Quantitation t>lr:@. Certification #481 S.C. Certification #99029
Page 1 of 2
PARADIGM ANALYTICAL LABORATORIES, INC.
Results for Volatiles
byGC 6230D
Client Sample ID: 2391420/MW-43 DUP
Client Project ID: 34596
------------------. -)i.nalyzed By: EKR
Lab Sample ID: 49028
Lab Project ID: G150,313
Compound
Naphthalene
n-Propylbenzene
Styrene
1, 1, 1,2-Tertrachloroethane
1, 1,2,2-Tertrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1, 1, 1-Trichloroethane
1, 1,2-Trichloroethane-
Trichloroethene
Trichlorofluromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl Chloride
m/p-Xylene
a-Xylene
Surrogate Spike Recoveries ·
1,4-Dichlorobutane
T rifluorotoluene
Comments:
All values corrected for dilution.
Flags:
Date
Analyzed
7/22/02
7/22/02
7/22/02
7/22/02
7/22/02
7/22/02
7/22/02
7/22/02
7/22/02
7/22/02
7/22/02
7/22/02
7/22/02
7/22/02
7/22/02
7/22/02
7/22/02
7/22/02
7/22/02
Dilution
1
1
1
1
1
1
1
1
1
1
1
1
1
Spike
Added
(ug/L)
40
40
Date Collected: 7/16/02
Date Received: 7/19/02
Matrix: Water
Quantitation ·
Limit (ug/L)
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
Spike
Result
(ug/L)
42
41
Result
(ug/L)
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BOL
BQL
BQL
BQL
BQL
BOL
BQL
BQL
BOL
BQL
BQL
Amount
Recovered
(¾)
105
102
Reviewed By: g#
BOL = Below Ouantitation ~-Certification #481 S.C. Certification #99029
Page 2 of 2
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