HomeMy WebLinkAboutNCD980557656_19870101_NC State University (Lot 86 Farm Unit 1)_FRCBERCLA FS_Draft Field Operations Pkan Remedial Investigation and Feasibility Study-OCRI
I
I
I
I
I
I
I
I
I
I
11
I
I
I
I
I
I
EPA WJRK ASSIGNMENT NO. 64-46G7
UNDER
EPA OJNTRACT NO. 68-01-7250
EBi'ISO'.J SERVICES Il/0'.JRroRATED
DRAFT FIEID OPERATIONS PIAN
REMEDIAL INVESTIGA'I'IOO
AND
FFASIBILITY S'IUDY
NORIB CAroLINA STATE UNIVERSITY
l.01' 86 SITE
RAI.EIGH, NORIH CAroLINA
JANUARY 1987
NOI'ICE
'lhe infonnation in this document has been fumed by the united states
Envirornrental Protection Agercy (U.S. EPA) urrler REM III Contract
No. 68-01-7250 to Ebasco Services, loo. (Ebasco). '!his document is a
draft am. has not been fonnally released by eitlJ.er Ebasco or the U.S.
EPA. As a draft, this document sha.ud not be cited or quoted, am. is
bei.nJ ci=ll.ated for cormnent only.
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
,1
I: I
. ---" . , . . .
APPENDIX A
DRAFT FIELD OPERATIONS Pr.AN
I
RDlEDIAL !NVES'l'IGATION AND
I FEASIBILITY SIUDY Kr
NORlli 1CAROLINA STATE UNIVERSITY SITE
RAIEIGH, NORIH CAROLINA
.JANUliRy 1987
1-
1
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I -
I
APPENDIX A
SECTION I
DRAFT FIEID SAMPLING AND ANALYSIS PIAN r
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
USEPA mRK ASSIGNMENI' NUMBER: 64-46G7
USEPA CXlNffiACT NUMBER: 68-01-7250
EBA.Sa:> SERVICES INO'.lRFORATED
lEAFT FIEID SAMPLING AND ANALYSIS PIAN
RillEDIAL INVESTIGATICN
AND
FFASIBTI..ITY S'IUDY
Kr
NORlli CAROLrnA STATE UNIVERSITY IDr 86 SITE
RAIEIGH, NORlli CAROLrnA
JANUARY 1987
PREPARED BY:
CAROLYN F. FOPPEIL
SITE MANAGER
ENv.rnDNMENrAL SCIENCE AND ENGINEERING, INC,
Apprcve:l. by:
<; d?:. Mill jj G ·A Russell H. Boyd, Jr., P.E:
Regional Manager, Region rv
Ebasco Services Incorporated
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Section
1.0
2.0
3.0
4.0
5.0
6.0
C-RDlNCSU2/FSAPIOC.1
01/11/87
TABLE OF CXlNTENI'S
INI'ROCUCTION
SUMMARY OF SITE REOJNNAISSANCE/PRELIMJNARY
CHARACTERIZATION/SAMPLING ACTIVITIES
GENERAL FIELD OPERATIONS
3. 1 PROJECT MOBILIZATION ACTIVITIES
3 .2 FIELD SAMPLING AND ANALYSIS PIAN
3 • 3 SAMPLE CDNrAINER REC{JTREMENTS AND HOIDING TIME'S
3 • 4 SAMPLE PACKAGING AND SHIPPING
3.5 IXlCUMENI'ATION
3. 6 DATA ~ OBJECTIVES
3.6.1 Stage One-Definition of Program Objectives
3.6.2 Stage 'I'Wo-Establishment of Analytical Data
Quality
3.6.3 Stage Three-Selection of Analytical and
Sampling Options
INITIAL FIEID ACTIVITIES
4 .1 Bi'.CKGROOND RECDRCS SEARClI
4. 2 GEOFHYSICAL SURVEYS
MONI'IORING WELL INSTALIATION
5.1 STATIONS
5. 2 MONI'IORING WELL CDNSTRUCTION PROCEIXJRES
5.2.1 Construction of Saprolite Monitoring Wells
5.2.2 Construction of Bedrock Monitoring Wells
5.2.3 Protective Casing and Cement Pad
5. 3 HANDLING OF DRILL aJITINGS AND FIJJII:S
5. 4 SITE SURVEY
SAMPLING PROCEIURES
6.1 SURFACE SOIL SAMPLING
6.1.1 Stations
6 .1. 2 Parameters
i
1
2
3
3
4
5
5
6
6
7
7
8
9
9
9
11
11
11
11
15
16
17
17
18
18
18
18
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I -
I
I
I
I
Section
7.0
TAB1E OF CONTENTS
(Continue:l., Page 2 of 2)
6.1.3 Sampling Methods
6.1.4 Sample Treatment
6.1.5 P,rplicate Samples
6.2 SUBSURFACE SAMPIES
6.2.l Stations
6.2.2 Parameters
6.2.3 Sampling Methods
6.2.4 · Sample Treatment
6.2.5 P,rplicate Samples
6.3 GRCXJND WATER SAMPIES
6.3.l Stations
6.3.2 Parameters
6.3.3 Sampling Methods
6.3.4 Sample Treatment
6.3.5 P,rplicate Samples
6.4 EWilMEN1' DECONTAMINATION
OOALITY' ASSURANCE AND OOALITY' CONIK>L
C-REl1NC:SU2/FSAPI'OC. 2
12/30/86
Page
18
22
22
27
. 27
27
28
28
29
29
29
29
33
33
33
. 34
36
7.1 FIEI.D INSTRLlMENT CALIBRATION AND PREVENTIVE
MAINTENANCE 36
7.2 FIEI.D BI.ANFS AND SPIKES 36
7.3 IXXlJMENTATION 36
7.4 AIJDI'IS 38
ii
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Section
5-1
6-1
6-2
6-3
7-1
Section
5-1
5-2
6-1
C-REMNCSU2/FSAPI.DTF. 1
01/11/87
LIST OF TABLES · ·
Monitorin:;J Well Construction, NCSU, I.ot 86 13
Sanplin:;J Matrix, NCSU, I.ot 86 20
Summary of Analytical Methcrls, Preservation Techniques,
Holding T:imes, ard Method Detection Limits, NCSU,
Fann Site I.ot 86 23
Summary of Analytical Methcxl.s, Preservation Techniques,
Holding T:imes, ard Method Detection Limits, NCSU,
Fann Site I.ot 86 30
RI/FS Sanplin:;J ard Analytical Summary, NCSU, I.ot 86 37
LIST OF FIGURES
Proposed Monitorin:;J Well ard SUbsurface Soil Sample
Locations, NCSU, I.ot 86
Typical Monitorin:;J Well Construction
Proposed Surface ·Soil Sample Locations, NCSU, I.ot 86 .
iii
12
14
19
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
1. 0 INI'ROCUCTION
C-REMNCSU2/FSAP-l.l
12/27/86
'!he Field Saropl:in; and Analysis Plan (FSAP) is an integral part of the
:Remedial InvestigationjFeasibility Study· (RI/FS) Work Plan for the North
carolina state University (NCSU) Lot 86 site. '!he field activities to be
perfonned in the :Remedial Investigation (RI) are descr-ibed in detail in
this document. Infonnation on the specific field activities, sample
locations, and sarnpl:in; proceduies is included in this descr-iption.
1
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
C-RlliNCSU2/FSAP-2.l
1.2/29/86
2. 0 SUMMARY OF SITE R:EenlNAISSANCE/PRELIMINARY CHARACTERIZATION/SAMPLING
ACTIVITIES
Field activities planned for the NCSU I.Dt 86 site inclooe site
re::x:nJ11ai s.sance, preli:minacy characterization, an:i sal!lpl:irq activities to
determine contaminant cx:irx:.entrations an:i migration in groom water a.rd
soil. 'D1ese RI activities are designed to provide data sufficient to
delineate source areas; contaminant types, distrililtion, an:i levels;
hydrogeologic _an:i geologic characteristics relevant to contaminant
transport; an:i actual or potential receptors.
If an evaluation of the data gathered in the RI irrlicates that additional
data are require.:i to define fully the extent of contamination an:i to
determine appropriate ·rerre:liaJ alternatives, the rationale an:i
docurrentation for proposed additional activities will be submitted to the
U.S. Environmental Protection h:Jenc::t (USEPA) in the fonn of a Technical
Direction Merroran:lum (TtM) before additional field activities are
initiated. 'Ihe proposed approach to the NCSU RI/F'S involves only a
s:irqle i:nase of sal!lpl:irq an:i analysis.
2
I
I
I
I
I
I
I
I
'I
I
I
I
I
I
·I
I
I
I
I
C-REMNCSU2jFSAP-3.l
. 01/11/87
3.0 GENERAL FIEID OPERATIONS
3 .1 PROJECT IDBILIZATICN ACTIVITIES
Follc,,ring awrc,val of the Draft Work Plan and F~eld Operations Plan (FOP)
by USEPA Region rv, the field operations team will camnence l!Obilization
activities for the RI. Mobilization activities will include
establishment of a project CXJTVDaro p:,st at the site, camnitJnent and
testin:Jjcalibration of all required field equipment, securinJ of all
necessary pennits and site access agreements, and initiation of arran:,e-
ments for Contract I.ab::lratory P:tcgram (CLP) and Rm m laboratory
services.
Arran,Jerrents will be made for leasinJ a m:ibile office trailer that can be
deployed to the NCSU Lot 86 site area. A security perimeter will be
constructed arourxi the trailer. 'lhis trailer will serve as a a::munaJYi
p:,st and storage facility for perfomance of field samplinJ and surveyinJ
activities. Present schedulinJ requires the trailer to be deployed and
fully operational in advance of the cammencement of excavation and
drillinJ activities requirinJ the use of the trailer. '!he =nan:i p:,st
.will be maintained through the ccmpletion of all major RI field
activities.
Concurrent with the establishment of the =nan:i p:,st, all required field
samplinJ and analytical equipment will be obtained and tested or
calibrated as necessary to ensure that the equipment is in sourxi workinJ
order. 'lhis equipment will be deployed to the site on an as-needed basis
for perfo:rmance of the respective field activities.
'!he Site Manager and Field Operations Tea:ri, Ieader will work to secure all
necessary state and local permits that will be required durinJ the RI
(e.g.,. water well drillin:J/installation pennits). 'Ihe Site Manager will
work with USEPA Region rv to cbtain site access agreements with NCSU. It
is un::lerstood that the securinJ of site access agreements is the
,responsibility of USEPA Region rv.
3
I
I
I
I
I
I
I
I
I
I
I
I
I
I
ii
I
I
I
I
C-RillNCSU2jFSAP-3. 2
01/11/87
Immediately upon aw=vaJ. of the FSAP by USEPA Region N, the Site
Manager will cantact the :REM m Regional I.aboratocy ~ .Coordinator
(RISC) to initiate the necessary requests for CLP services am bidclin:,
procedures for :REM m laboratocy services. Base:i an the present
schedule, analytical services for samples collected at NCSU I.ot 86 site
. will be requinrl by April 13, 1987.
• other general field operations elements that will be addressed durin,
=bilizatian will :uci.ude arran;iements for harxllin, of wastes generated
by the field operations team durin, the RI. Contaminated wastes will be
drummed am stored in a temporary onsite facility am disposed in a
USEPA-approved larrlfill at the conclusion of the field samplin,
activities, or for a maxi= of 90 days, 'Whichever comes first. All
contaminated wastes will be stored am disposed a=rdinJ to Resource
Conservation am Recovery Act (RCRA) requirements. USEPA assistance will
be requinrl in ~ the appropriate permits am manifests for
disposal of wastes generated durin, the RI.
'l1le o.Jrrel'lt schedule provides for construction of a concrete decontam-
ination pad am drum storage facility onsite prior to initiation of soil
excavation am drillin, activities. An interim decontamination area :will
be establishe:i for use durin, initial field (norx:irillin,) activities
(i.e., geoi::hysical smveys am surface soil sampl.in;J).
3. 2 FIELD SAMPLING AND ANALYSIS PIAN
'l1le FSAP cies=ibes data quality objectives (D;;Ps) samplin, design,
samplin, am laboratocy materials am iret:hods, decontamination, am
Quality Assurance/Quality Control (QA/QC) procedures for the NCSU I.ot 86
site RI. 'l1le follc:M.in;J Field Technical Guidelines (FrG), develope:i for
the REM III Program, are applicable to the RI:
4
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
II
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
C-RfflNCSU2jFSAP-3.3
0l/ll/87
FT--4.02
FI'-4.05
· Resistivity arxi Electranagnetic Irrluetion surveys,
Groon:i-J?enetrat:in;, Radar (Gffi) surveys,
FT--6.01
FT--6.02
FT--6.03
FT--6.06
FT--6.07
FT--6.09
FT--7.01
FT--7.02
FT--7.03
FT--7.05
FT--7.06
FT--7.07
FT--7.10
FT--12.01
FT--13.03
Soil arxi Rock Borin;s,
Borehole arxi Sanple I.o39".inJ,
Decantamination of DrillinJ Rig arxi SanplinJ F.quipnent,
In Situ Hydraulic Col'Xiuctivity Testin:J,
Pi~c:aootri..: Head Measurement arxi Groon:i Water contour
MappinJ,
Vertical arxi Horizontal Movement of Groon:i Water,
Groon:i Water McnitorinJ Well Installation,
Groon:i Water Sample Acquisition,
Soil arxi Rock Sanple Acquistion,
Sanple Identification arxi Olain~f-oistooy,
Sanple Presetvation,
SanplinJ Paclc:mJ arxi ShippinJ,
Onsite Water Q.lality Testin:J,
Decont.a:mination of Oie:mical SanplinJ arxi Field
Analytical F.quiµoont., arxi
Site Leg Book.
'Ihese guidelines are on file with the USEPA Deq:uty Project Officer arxi
with USEPA' s I.aborato:cy Evaluation arxi Q.lality Assurance section Qu.ef in
Athens, Georgia.
3. 3 SAMPIE a:iNrAINER ~ AND HOIDING TIMES
Sample container requirements arxi holdinJ ti:rres are specified in REM III
Guideline FT--7.06. 'Ilus information is also in::luded in Tables 6-2 arxi
6-3 (refer to section 6 of this FSAP) for soil arxi grcxmi water san,ples,
respectively.
3. 4 SAMPLE PACKAGING AND SHIPPING
Sanples will be packaged arxi shipped a=:rdin;J to FT--7. 07. When san,ple
shiprents are sent to the REM m or CLP laooratories, the REM m
5
I
I
I
I
I
I
I
I
I
I
I
I
I
I
11
I
I
I
I
C-RillNCSU2jFSAP-3.4
Ol/ll/87
lal::oratory coordinator or USEPA Sanple Management Office (SM::l),
respectively, will be teler:;ooned that day or the follehli.rg momfrq an:i
given the appropriate infonnation about the types of sanples, rnIJDbPr of
sanples, an:i airl:lill rumbers.
3 • 5 IXXXJMENI'ATION
'Ihe field team will maintain a bam:i, weathel:proof notebook. '!his
notebook will be filled rut at each sanplin;J station and will contain
sample particulars, measurements, and observations. 'Ihe field operations
leader or his designee will record infonnatian in this notebook at each
samplin;J station.
A site logbook will be maintained by the field operations leader. '!his
book will contain a =ry of the day'_s activities and will reference
the sanple team's notebooks. Irxiividual field notebooks (e.g.,
geologists' notebooks) will also be referenced. 'Ihe requirements of the
site logbook are ootlined in REM III Guideline FT-13.03.
A sample logbook will be maintained in the field office. '!his book will
contain a separate sheet for each sample. Pertinent infonnation (e.g.,
date and time sampled, in situ water quality measurements, or other
observations) will be placed on these fonns from infonnation recorded in
the field notebooks.
3.6 D.1.TA Q'.JALITY OBJEC!'IVE.S (D;;Ps)
CQ:ls for the NCSU I.Dt 86 site were defined on the basis of the Work
Assignment oojectives, as un:lerstood by Envi=imental Science and
En;Jineerin;J, Inc. (ESE); basic statistical an:i lal::oratory principles;
USEPA's D:x:nrrent No. 93.0-7A entitled "Data Q.lality c:tijectives for the
RI/FS Process;" a review of possible Applicable or Relevant and
Appropriate Requirerrents (ARARs); an:i. the RI/FS Scop:in:y'D;;p ll'Petin;J held
on November 12, 1986.
6
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
3.6.1 stage One-Definition of Program Objectives
C-RillNCSU2jFSAP-3.5
01/ll/87
'lllis stage of the CQ) pi:cx:ess is covered in FOP Sections 1.2 an:l. 1.5.
3. 6. 2 stage Two-Establishrrent of Analytical Data Q.lality
'Ille basic ~ for the RI/F'S is that data collecta:l. be of known
quality. Criteria used for definin;J data quality are:
o Precision-a measure of the rep:ccxfudbility of analyses under a
given set of can:litions,
o A=racy-a measure of the bias that exists in a measurement:
system,
o :Representativeness-the degree to which sanple data a=rrately
an:l. precisely represent selecta:l. characteristics,
o Cgmpleteness-a measure of the amount of valid data obtained
f:ran a measurement system corrq:iared to the amount that was
eJ4)E!Cted to be obtained under nornal can:litions, aro.
o Comparability-an expression of the confidence with which one
data set can be corrq:iared to another.
Precision aro. a=rracy are statistical concepts related to sairpl.in::,
design, methcxis, am materials. Precision is measure::i by collect.in::,
duplicate sanples am replicated analyses in order to define the sanplin;,
variance (or error) attrib.rt:able to environmental heterogeneity an:ljor
the sairplin;, am sanple preparation process. A=racy, in terms of
statistically estimat.in::, the field concentrations, is a function of the
number of sanples. laboratory a=rracy is a function of the method
detection limits (MDI.s) am percent reo::Nery. A=racy is checked
throogh use of ·blanks am matrix spikes am assured by proper instrument
calibration/certification.
'Ille a=rracy arxi precision of sanpl.in::, data taken in this study will·be
adequate to =npare data against ARARs to-be chosen for risk assessirent
arxi feasibility studies. Potential ARARs for the RI/F'S include:
7
I
I
I
I
I
I
C-RfflNCSU2jFSAP-3. 6
01/11/87
o Federal Safe Drinkin;J Water Act (SI:W\.) Pri:l!lacy Drinkirg Water
standards,
0 Clean Water Act (OIA) Water QUality Criteria,
O P.tqosed Maximum o:intaminant I.el/els (M:16) and Maximum
o:intaminant Level Goals (M:LGs) , and
o state of North carolina water quality stan:lards ai;:.plicable to I groom water (Title 15, Subchapter 2L).
I
I
I
I
I
I
I
I I ·•
I
I
I
I
'Ille ARARs for the NCSU IDt 86 site will be disa1ssed in greater detail in
the RI/FS reports. Representativeness of sampling is also extrerely
~rtant for this assignnent. 'Ille proposed sampling plan for the NCSU
IDt 86 site is clesigne:i to ensure that sampling locations are appropriate
and that a sufficient rumiber of samples are collected to meet the
objectives of the RI/FS. 'Ille rationale for selection of sampling
locations and rumiber of sa:nples is provided in the Work Plan for the
RI/FS. Proposed sampling techniques to ensure representativeness are
described in detail in the Work Plan and in this FS1IP. ~leteness will
be assured by maJdn;J every effort to collect and analyze all samples that
are proposed to be collected.
3. 6. 3 stage 'Three-Selection of Analytical and Sampling Options
'Ille analytical options chosen for the site investigation include CQ:)
Levels I, m, DI, and v. 'Ille specific level or analytical option chosen
is based on the CQ:) level for the specific type of sanple and data
"lee:led. CQ:) Level I work consists of field screening for the selection
of sampling location, for a preliminary estilllation of contaminant concen-
tration, and for health and safety precautions. For samples that need a
high level of data quality bJ.t are not required for potential litigation,
CQ:) Level m will be used. Rigoroos QA/QC protocols and documentation
are required for samples that may be used for confirmational water ·
quality; Level DI will be used for these samples. Sanples requirin:J
special analytical services (SAS) will be analyzed at CQ:) Level v.
8
I
I
I
I
I
I
I
I
I
;I
:I
I
I
I
I
I
I
I
I
4. O INITIAL FIEID ACI'IVITIES
C-REMNC!SU2jFSAP-4.l
01/ll/87
Initial field activities planned for the NCSU RI include a backgrcmxl.
records search an:l geqilysical surveys.
4 .1 ~ REOJR!l3 SEARa1
'Ihe backgrcmxl. records search to be perfOl'.llBi as part of the initial
field activities includes d:lta:in:l.rq an:l reviewin;;: (1) waste disposal
records for the tl«l disposal areas; (2) available environmental
m:mitorin;J data from NCSU; an:l (3) info:cmaticn en nearby water supply
wells, surface water uses, an:l sensitive or endan;ered species in the
vicinity of the site.
Disposal records an:l envircnmental m:mitorin;J data are available from
NCSU. 'Ihe review of waste disposal records will include documentation of
chemical/radioactive waste types, quantities, an:l disposal locations.
Info:cmaticn will be summarized into data tables for use in the RI/FS.
Nearby water Sl.Jl:PlY wells, includin;J clanestic, c:cmmerc:ial, agricultural,
an:l industrial wells, will be located by reviewin;J records maintained by
the North carolina Deparbnent of Environmental Management, G:rot1nd Water
Section, in Raleigh. Types of info:cmaticn that will be sought include
location, use, depth, poµl].aticn served, an:l canstnicticn details.
Limited :reconnaissaIX: of thE' i:rmrediat-.e area will also be performed to
identify any additional wells an:l to confirm the locations of wells
identified through the recx:n:cb search.
Uses of nearby surface waters an:l the presence of ~ered or sensitive
terrestrial an:l aquatic species will be detennined by ccntactin;J local
environmental an:l natural resource agencies.
4. 2 GEOFHYSICAL SURVEYS
Geophysical techniques [electranagnetic (EM)-31 an:l GFR S\llVeysJ will be
used to detennine the lateral extent of trenches in both the chemical
waste burial area an:l the l0v1-level radioactive waste disposal area. 'Ihe
9
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
C-RD!NCSU2jFSAP-4.2
0l/ll/87
geq:hysical sw:vey will be performed by Tedmos, In::. as an initial site
activity. A grid pattern for the S\llVeys will be established by stakin;
10-foot (ft) :i.ntervals across the width an:i len;tii of both areas. 'Ihe EM
an:i GPR SlllVeys will be =rllJCted =ntinucusly alOJ'X1 these transects.
'Ihe approxilllate area to be covered during the sw:vey in each area is
130 ft by 180 ft (10,000 total linear feet) in the chemical waste area
an:i 50 ft by 200 ft (4,500 total linear feet) in the low-level
radioactive waste area. E:ach metho::l. relies an response to differin;J
physical an:i chemical characteristics between the uniisturbed, original
soil an:i the soil-waste mix in the trenches.
10
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
5. 0 MJNITOroNG WELL INSTAL!.ATIOO
5.1 STATIOOS
C-R™NCSU2/FSAP-5,l
01/11/87
New m::mitorin3' wells will be installed at the locations shown in
Figure 5-1. 'll1e NCSU Work Plan disoJSSP$ the rationale f= the locations
of the new wells. 'll1e 29 exist.in3' m::mitorin3' wells were installed by
NCSU arxi rrumbered =secutively fran 1 to 20 arxi then 27, 27A, arxi 29.
'll1e new m::mit=in3' wells will be numbered 30 thrrugh 36. Cluster wells
(adjacent wells screened in different intervals) are designated by
letters (A = B) foll""1in;J the well rnTJDbp..r. 'll1e existin3' arxi proposed
m::mitorin3' well construc:tian data are presented in Table 5-1.
'll1e locations of MW-35 arxi MW-36 are tentative arxi will be finalized
foll""'1n;J detailed examination of the subsurface lithology usin3' three
borin3's (CS-D, ns-E, an:i ns-F). 'nlese wells will be screened alon;i-the
san-e beddin;r planes or litholcgic contacts (if possible) down::lradient of
the site, one in the l= saprolite an:i the other in the upper bedr=k.
'll1e other well locations are approximate an:i may depen:i an the actual
field conditions (i.e., roads, trees, etc.) for their final locations.
5. 2 MJNITORING WELL a:NS1'RUCTION PROCEIXJRES
'll1e m::mitorin3' wells will be constructed in a=rdance with REM m
Guideline Fl'-7. 01 an:i state of North Carolina regulations. 'll1e
locations, depths, an:i construc:tian are summarized in Table 5-1. ArrJ
TJeeessacy canstructian pennits required by the state of North Carolina
will be obtained. Monitorin3' well canstructian is depicted in
Figure 5-2.
5.2.1 Construction of Saprolite Monitoring Wells
'll1e boreholes for the saprolite m::mitorin3' wells will be produced usinJ
5-inch inside diameter (I.D.) hollow-stem augers to the desired depth.
'll1e methods for the borinJs will be in a=rdance with REM m
Guideline Fl'-6.01. 'll1e augers (with a bottom plug) will be advanced to
11
I
I
I
I
I
I
I
I
:I
I
I
I
I
I
I
I
I
I
I
REM/// HCSU 1197A
e1s e 13
•10
DS-F t:,.
es • e12
•
•
t:,.
• 32
38 t:,.
27 e
27A e
LEGEND .29
EXISTING MONITORING WELL
LOCATION
FENCE
PROPOSED MONITORING
WELL LOCATION (SUBSURFACE
SOIL SAMPLE LOCATION)
SUBSURFACE SOIL SAMPLE
LOCATION (BORING ONLY)
Figure 5-1
PROPOSED MONITORING WELL AND
SUBSURFACE SOIL SAMPLE LOCATIONS,
NORTH CAROLINA STATE UNIVERSITY,
LOT 86
SOURCES: COM, 1988; ESE. 1987.
12
-;,, • ..
14
• 30
FORMER CHEMICAL
ST~AOE O~ER AREA
\ 300 TO 500 FEET
a
31 • .. ""' ------ac.t.u 1■ nn
ENVIRONMENTAL SCIENCE
AND ENGINEERING, INC.
--- - ----- - - - ------
Tab I e 5-1. '1onitorlng Well Construction, NCSU Lot 86
Well 1.0. Oete of Total To~ of Top of Top of Cesinf Glued •• Top of Stickup '1P above NP •BOY£
lnstal latloo 0cith SC [EN Sand Benton i te Boreho e Cesin1 Natural (fT) Oah.n "$\.
( T) (fT) Pack Seal Diometer (C Backfill (fT) (fT)
--------------------[xistlng '1onitoring Wei Is 37.2 34.5 3/B I. 96 -12. 92 437 .08 I 8/82 SO.JO 35.0 • 23.0
IA 5/85 46.00 40.7 • 39.0 10.0 2/B 1.02 -13.53 436.47
1B 5/85 56.00 50.5 49.0 10.0 2/B 0.96 -13.89 436.11
2 B/82 50.10 42.7 35.0 34.0 3/B • 22.0 I. 78 -6.98 443.02
3 B/82 37.40 32.4 31.0 30.0 3/B • 20.5 I. 98 -7.00 4-43.00
JA 10/86 64.00 60.0 57.0 53.0 2/B • I. 31 -9.43 4-40.57
JB 10/86 76.SO 71.0 68.0 65.0 2/B • 2.00 -B.61 441.39
4 B/82 61.80 47.0 45.0 44.0 3/B • 21.0 2.05 2.05 452.05
5 12/83 50.00 39.0 39.0 38.0 3/B • 20.0 2.32 -10.88 439. 11
SA 5/85 55.00 46.0 • -40.0 10.0 2/B 0.92 -12.65 437.35
SB 5/85 62.00 56.0 • 55.0 10.0 2/B 0.83 -12.19 4 37. 71
6 12/83 40.50 33.5 29.0 28.5 3/6 • 19.0 2.64 -13. 71 436.29
7 12/Bl 48.20 38.5 38.5 37.5 3/B • 20.0 2.H -10.21 439. 79
B 12/83 SJ.JO 48.0 46.0 45.0 3/8 • 15.0 2.37 -4 .29 445. 71
9 5/84 45.60 39.0 37.5 36.5 4/B 17.0 2.70 -9.84 440. 16
10 5/84 44.20 37.0 36.5 35.S 4/B 16.0 2.97 -14.11 435. 89
II 12/84 37.10 24.0 23. 5 23:0 4/8 20.0 0.83 -22 .21 427.79
12 12/84 -42.50 29.0 28.0 27.0 4/B 20.0 I. 17 -25.21 424.79
13 12/84 42.60 29.0 29.0 26.5 4/8 19.0 0,63 -28.46 421. 54
14 12/84 47.40 37 .0 36.0 35.0 4/8 14 .0 3.00 2.91 452. 91
15 12/84 55.00 34 .0 • 33.5 32.5 4/B 21.0 I. 25 -19.90 430. 10 .... 16 5/85 35.00 28.0 28.0 10.0 3/8 I. 28 -24.06 425. 94
w 17 5/85 32.00 26.0 24.0 10.0 2/B I. 65 -27.33 422.67
18 5/85 34 .00 28.0 • 28.0 10.0 2/8 0.00 -30. 3 I 419.69
19 5/85 34.00 26.0 26.0 10.0 2/8 -0.20 -26.52 423.48
20 5/85 30.00 25.0 • 25.0 10.0 2/B 0.00 -23.49 426.51
27 10/86 45.00 40.0 • 33.0 10.0 2/8 I. 46 -3. 91 446.09
27A 10/86 60.00 54 .5 54 .S 52.5 2/8 I. 44 -3.82 446. 18
29 10/86 55.50 50.5 48.5 46.5 2/8 1.99 -4 .BO 445.20
Proposed '1onitorlng Wells Sand Pack Thickness of Casinf Total Screen
Wei I 1.0. Depth Len~th Above Screen Bentonite Boreho e
(ft) ( t) (ft) Seal (ft} Diameter
JO 50-60 10 2 2 2/10
31 100-120 10 2 2 2/10
32 60-70 10 2 2 2/10
33 62 5 2 2 2/IO
34 54 5 2 2 2/10
JS 70-80 10 2 2 2/B
36 105-115 10 2 2 2/B
Notes: • Natural l'leter iel Caving During Construction.
•• Natural backfill was used as a backfi I I in the early monitoring wel Is.
Auger Refusal At ~0.5 rT in M~-6.
MP• ~easuring point
Source: ESE. 1987.
I
I
I
I
I
I
I
I
I
:I
I
I
I
REM/II NCSU 11!1A
i ... -----.... -HINGED CAP
f
2.5'
VARIABLE
GROUND LEVEL i
T7777?)j:,7m
Figure 5-2
-PROTECTIVE STEEL CASING
~=::::::::,---1-~ VENTED CAP
1/
~,1---NO. 316 STAINLESS-STEEL
;; CASING (2" DIAMETER) ,, ,, ,, ,, ,,
;;.;; ----GROUT , ,, ,, ,, ,, ,, ,, , ,,
i---BENTONITE SEAL (2 FEET)
-'"t',..,..--NO. 316 STAINLESS-STEEL WELL SCREEN .t-----,. (0.010" SLOTS)
TYPICAL MONITORING WELL CONSTRUCTION ENVIRONMENTAL SCIENCE
AND ENGINEERING, INC.
SOURCE: ESE. 1987.
14
1-·
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
C-REl1NCSU2;'FSAP-5. 2
01/11/87
the samplm;r depth and the plug renoved to allow soil samples to be ·
collect,ej fran inside the auger. stan:lard Penetration Tests (SPI') will
be performed at the surface and at :intervals of 5 ft, excludin:J the top
10 ft which will be saJ!llled =rtinualsly. 'Ihe depth of re,; shallow wells
will be based an the depth to the water table which will be determined
fran water content of the split-spoon saJ!llles and frcm water level
, neasureirents in nearlJy m:utlt=ing 1tlells.
When the desired depth of the well is reached, the inside of the auger
will be cleane:i. A 10-ft section (MW-34 and MW-35 will have 5-ft
sections) of 2-inch-I.D., flush-jointed, threadsd type-316 stainless-
steel wire-wrappe:1 screen with 0.010-inch slots will be placed into the
hole and 5UDID.l11tai with ena.igh 2-inch-I.D. threaded solid type-316,
Schedule 5 stainless-steel casm;r to allow a 2.5-ft stickup. 'Ihe screen
will be surrounded, usm;r the tremie pipe method with a san:lpack
consistm;r of 20 to 40 mesh, silica sand to a depth of 2 ft above the
screen. A 2-ft seal of bentonite pellets will be placed above the
san:lpack. 'Ihe ~ annulus will be grouted to approximately 3 ft
from the surface with 5 percent bentonite, 95 percent Type I Portland
=t grout mixture, by usm;r the tremie pipe methcd while slowly
remcvm;r the auger. 'Ihe grout will be all~ to set for at least
24 hours prior to any additional work an the well (i.e., installation of
the protective casm;r and the ceme¢ collar or well developrent) • A
stainless-steel cap will be placed an the riser and will be vented to
allow water levels to equilibrate to a'boospheric pressure.
s.2.2 Construction of Bedrock Monitorinq Wells
Borm;rs for the two bedrock m:utltorm;r weils (MW-35 and MW-36) will be
produced usm;r 4-inch I.D. (8-inch ruter diameter (O.D.)] hollow-stem
augers. to the top of the bedrock. Two Shelby tube samples will be
collect,ej from the borm;r for MW-36 at depths of 20 and 40 ft. Once the
bedrock is reached, the augers will be renoved and a 6-inch-diameter
steel casm;r will be driven to the top of the bedrock and cleaned in.
15
I
I
I
I
I
I
I ,,
I
I
I
I
I
I
I
I
I
I
I
C-RlllNCSU2jFSAP-5.3
01/11/87
a=rclance with REM III Guideline FT-6.01. 'lhe casin3' will be gr=ted
for stability an:l alla,,,ed to set for 24 hrurs prior to clrillin3' into the
bedrock. Fifteen feet of the bedrock will be cored usin3' an NX core
barrel for lithologic des=iption an:l confinnation of the depth to
bedrock. 'lhe =e-i..:ile will be reamed to a diameter of 6 inches usin3'
lll!Jd-rotary clrillin3' with an inert, inorganic clrillin3' additive.
'lhe bedrock m:mitorin3' wells will be constructed in the same manner as
the saprolite m:mitorin3' well disoissed above. In addition, a stainless-
steel centralizer will be placed on the base of the screen to keep the
screen in the center of the hole while the well is constructed. All
m:mitorin3' wells will be develc:p=d by i;:urpin3' (submersible or blaclder
i;:urp) or by bailin3', depen::tin; on well yield.
5.2.3 Protective casing an:l Cement Pad
A 5-ft, hin:,ed, lockin;, steel, protective 6-inch casin3' will be placed
over the riser of each new well. 'lhe protective casin3's will be painted
fluorescent orange with weather-resistant rustproof spray paint prior to
installation. Miltional grait will be added to the annulus to
campensate for settlin3' an:l to set in the protective casin3'. 'Ibis last
grait will be added to the hole before settin3' the protective casin3' in
the annulus an:l while the grait is still fluid. Gra.lt will be added to
the inside of the protective casin3' to a level of approxilnately 0.5 ft
above ground surface. A 0.25-inch drain-hole will be drilled
approxilnately 1 inch above the level of grait inside the steel casin3'.
A 4-ft-diameter concrete pad will be placed aroon:i all wells after the
grait has set .. 'lhe collar will be slc:p=d a;,;ay frail the well to permit
drainage. 'lhe cement collar surrcundin:J MW-6 was observed to be broken
durin3' the site reconnaissance. 'lhe collar will be replaced durin3' well
construction activities to prevent dc,..mward migration of contamination
frail the ground surface.
16
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
11
I
5. 3 HANDLING OF mnL ClJITING.5 AND FIIJIOO .
C-REMNCSU2jFSAP-5.4
Ol/ll/87
Drill ~ am fluids frc!n all offsite borin;Js except ~33 an:1 MW-34
will be place:l in an tmlined pit ansite which will be covered with clean
fill -when drillin;J is ccmplete. Because of high levels of contaminants
documented in ~5 am ~B, drill~ an:1 fluids frc!n ~33 an:1
~34 will be carrt:.ainerized in drums, temporarily stored ansite, am
transported am disposed in a=:rtlance with USEPA's regulations. 'Ihe
waste frc!n ansite borin;Js am the developoorrt/i;m:ge water frc!n MW-lA,
MW-IB, MW-3, MW-3B, MW-SA, l-M-SB, MW-8, :r-M-12, an:1 ~16 will be disposed
in the same manner as the waste frc!n I-M-33 am I-M-34.
5.4 SI'IE SURVEY
On ccmpletion of the m::initorin;J well installation task, a detailed site
survey will be perfo:oned by a subcontracted, registered sw:veyor. 'Ihe
survey will include ansite structural features such as fences, gates, am
markers an:1 ansite am offsite m::initorin;J wells. Mcnitorin;J wells will
be surveyed for horizontal an:1 vertical coordinates in a=rdance with
the REM Ill Guideline FT 3.03, Ari onsite top::gra~c SULVey will also be
perfo:oned at a 1-ft contour interval to cletennine drainage patterns
ansite. An offsite top::gral,hic survey of the area has already been
prepared by the City of Raleigh an:1 is therefore not included under this
scope of work.
' '
17
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
6.0 SAMPLING PROCEr::URES
6 .1 SURThCE SOIL SAMPLING
6. 1. l stations
C-RDlNCSU2/FSAP-6 .1
01/11/87
SUrface soil samplin3' stations are shown in Figure 6-1. '.Ihe stations are
prefixed with the letters SS for the type of sample (surface soil) arxi
with a letter A, B, c, D, E, or F to designate different samplin3' areas.
'.Ihe sample number designation foll= the samplin3' area letter. A
permanent record of samplin3' locations will be made by~ arxi
photo;,raphin:J eac.h point or location. '.Ihe location of eac.h sampl:ir:g
point will also be indicated an the site map prc:x:luced by the contracte::l
surveyors.
6 .1. 2 Parameters
Soil samples will be screened initially with the HNU for health arxi
safety purposes arxi for the selection of samplin3' location in one area
(SS-C) • All samples will be analyzed at the ~ Level m for Hazaroous
Substance List (HSL) organics arxi inorganics. '!be samplin3' depth arxi
analytical parameters for eac.h samplin3' location are presented in
Table 6-1.
6.1.3 Sampling Methods
SUrface soil samples will be cxillecte::l a=rdin3' to REM m
Guideline Fl'-7. 03. Sanples from areas SS-A, SS-B, SS-D, arxi SS-F will be
irx:l.ividual samples. '!be two samples cxillecte::l in area SS-C will be
mup::.slted frcm depths of O to 6 inc:hes frcm three locations arxi frcm
depths of 6 to 12 inches from the same three locations. Fac.h of the
six samples frcm area SS-E will consist of a CUtlfX)Site of eight locations
frcm depths of 4 to 10 inc:hes.
A stainless-steel trowel or a stainless-steel harxi auger will be used to
cxillect the surface soil samples. Semple locations will be staked arxi
located an a sketch of the site in the field logbook prior to cxillectin3'
the sample arxi later located an the site map produce'.i frcm the site
18
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
-1
I
••
. 1
REM/I/ NCSU 12/86A
• •
LEGEND
e 13
* SS-D1
MONITORING WELL
LOCATION
• If FENCE
* SS-D2
3Ae
3Be•3
*OR <i3:> SOIL SAMPLE LOCATION
Figure 6·1
PROPOSED SURFACE SOIL SAMPLE
LOCATIONS, NORTH CAROLINA STATE
UNIVERSITY, LOT 86
SOURCES: COM, 1985: ESE. 1987.
19
• .. ::
14 * SS-F
FORM~ CHEMICAL
ST~AOE D~ER AREA
0 IO ------auu 1• nn
ENVIRONMENTAL SCIENCE
AND ENGINEERING, INC .
1--. . ··• --. . -·~ ··-•'-·•·-···-.... . -····· ·-
I
Table 6-1. Sarrpling Matrix, NCSU Lot 86
I Surface Soils Depths PH1 PH2 PH3 'I«: HSL3 HSIA GRa&b
SS-A1 0-6 (in) 1
I SS-A2 0-6 1
SS-A3 0-6 1
SS-A4 0-6 1
SS-AS 0-6 1
I SS-A6 0-6 1
SS-A7 0-6 1
I SS-B1 0-6 1
SS-B2 0-6 1
SS-B3 0-6 df-1
I SS-<::1 0-6
SS-C2 6-12
I SS-D1 0-6
SS-D2 0-6
SS-D3 0-6
I SS-El 4-10
SS-E2 4-10
SS-E3 4~1~
I SS-E4 4-10
SS-ES 4-10
SS-E6 4-10
I SS-F1 0-6
Subsurface soils
DS-Al 10-12 1
I DS-A2 24-26 1
DS-A3 38-40 1
I DS-B1 10-12 df-1
DS-B2 24-26 1
DS-B3 38-40 1
I DS-Cl 10-12 d-1 1
DS-C2 24-26 1 1
DS-c3 38-40 1 1
I DS-El 10 d-1
DS-E2 50 1 df-1
DS-E3 90 d-1 d-1
I 00-{;1 10
DS-G2 50 d-1
·I DS-G3 90 d-1
'IWALS 7 5 10 9 35 0 0
I
I
20
I' ---.. , ..
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Table 6-1. Sarrpling Matrix, NCSU Lot 86 (Continued, Page 2 of 2)
Ground Water
Sarrples
MW-lA
MW-lB
Depth
(ft) Pill
40.7-45.7
50.5-55.5
32.4-37.4
71-76
PH2 PH3 'IIX HSL3 HSIA GRa&b
1
MW-3
MW-3B
MW-4
MW-SA
MW-SB
MW-8
MW-9
MW-12
MW-13
MW-14
MW-15
MW-17
MW-18
MW-19
MW-20
MW-27A
MW-30
MW-31
MW-32
MW-33
MW-34
MW-35
MW-36
47-52
46-51
56-61
48-53
39-44
29-34
29-34
37-42
34-39
26-31
28-33
29-34
25-30
54.5-59.S
50-60
100-120
60-70
56-61
48-53
70-80
105-115
1
1
1 1
1 d-1
1
df-1
1 df-1
1
1
1
1 d-1
1
1
1
1
1
1
1
1
1
1
1
1
df-1
d-1
Medlin Residence df-1
'l'Ol'ALS 0 0 0 0 29 3 10
NOI'ES: PHl~ain size analysis of 5a!T\)les only if the
depth to bedrock is less than 150 ft.
PH2-Physical pararreters: porosity, Atterberg ·limits, viscosity,
penreability, arrl filter press.
PH3-Physical pararreters: rroisture arrl B1'U content.
'IIX--Total organic carbon content.
HSL3-DQ'J Level III HSL organics arrl inorganics.
HSL4-DQ'J Level IV HSL organics arrl inorganics. ·
GRa&~oss alpha arrl beta radiation.
d-Duplicate 5a!T\)le.
f--Field blank collected prior to 5a!T\)le.
Source: ESE, 1986.
21
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
C-RillNCSU2jFSAP--6. 2
Ol/ll/87
survey. Fractions to be analyzed as a Dil[c>Site for volatile organics
will be packed in iooividual containers an1 n Htp~ited in the laboratory
prior to analysis.
6. l. 4 Sample Treatment
o Preservation-,q:plicable sample presexvation guidelines,
presented in REM m Guideline FT-7,06, will be followed,
o IabeJJ i..n;f-Sanple labellin,, guidelines are presented in REM III
Guideline FT-7.05. All labels will be prepared prior to sample
collection and will contain information on site name, sample
number, name of collector, date and til!le of collection; place of
collection, type of sample, sample volume, analysis :req.tlre:i,
and presexvation technique.
o Pacldrg, Shippin,,, and Transportation-Sanples will be packaged,
shipped, and transported in a=rclance with REM m
Guideline FT-7,07. When sample shipients are to be made, the
receivin,, laborato:cy will be teleplCl'led on that day or the
follCll<lin;J m:im:in;J in order to notify the laborato:cy of shiprrent,
aixbill number, and number/type of samples bein,, shipped.
Table 6-2 presents the analytical methods, types of containers, holding
til!les, and MDis for the soil samples to be collected.
6.1.5 l)Jplicate Samples
D.Jplicate samples are used to measure field samplin,, variation. The
number of duplicates and their samplin,, locations for soils are included
in Table 6-1.
22
- -N w - -- - - -- - - -- - -C·REMNCSU2/FSAPH62.1 01/11/87 Tabla 6·2. Su:.nary of Analytical Method1, Preservation Techniques, Holding Times, and Method Detection Ll~lta, NCSU, Far• Site Lot 86 Surflchl and Subsurhce Soll Sll!E!lH Method Preservotlon Mui-ParHU:!ter Method• Technique Reference Sample Container Required Holding Tf111e MDL HSL Organics Volatiles EPA 8240 GCMS • 2 x 4·oz wldemouth Cool to ,•c 10 d1y1 1.6 to 6.9 ug/l amber glass Jars w/ ( In utract) Teflon•·tlned cap '" Eii:tractables EPA 8250/8270 GCMS • 8-oz wldemouth cool to 1i•c 10 days 10 to 50 ug/L gins Jar w/ e11tractlon ( In extract) Teflon•·tlned cap 40 daya after u:tractlon Pesticides and PCBa EPA 8080 GC/EC • 8-01. wt demouth Cool to 4•c 10 daya 0,01 to 5.0 ug/l glau Jar w/ eKtractlon {ln utrect) Teflon•-1tned cap 40 days after extraction Total Phenolic, EPA '20.1 Colorimetric ' 8·01 wldemouth Cool to 4•c . 0.3 111g/g glus Jar W/ Teflon•• t lned cep KSL I norgeni Cl Cyanide EPA 9010 Colorimetric • 8-oz wldemouth Cool to 4•c • 5 ug/g glass J11r w/ Teflon•·tlned cap Met11ls Mercury (Hg) EPA 7471 CVAA 6 8·01 widemouth Cool to 4•c • 0.40 mg/kg glass jor w/ Teflon•·llned cap - - --;
- ---- - - - - -- -- --- -
N ,,.
C·REMNCSU2/FSAPH62.2
12/30/86
Table 6·2. Surrrnary of Analytical Methods, Preservation Techniques, Holding Times, an~ Method Detection Limits, NCSU, Farm Site Lot 86
(Continued, Page 2 of 4)
Surf fetal and
Subsurface Soll Sem~les Method Preservation Maximum
Parameter Method* Technique Reference Sample Container Required Holding Time MOL
Arsenl c (As) EPA 7060 GFAAs 6 8-oz wfdemouth Cool to 4°c + 0.50 mg/kg
glass jar w/
Teflon -lined cap
Selenium (Se) EPA 7740 GFAAs 6 8-oz wfdemouth Cool to 4°c + 0.24 mg/kg
glass jar w/
Teflon -lined c~p
Thallium (Tl) EPA 7841 GFAAs 6 8-oz wfdemouth Cool to 4°C + 0.32 mg/kg
glass jar w/
Teflon ·lined cop
A 11 Others** EPA 6010 ICP 6 8-oz wfdemouth Cool to 4°c + 1 to 10 mg/kg
glass jar w/
Teflon ·lined cap
Moisture Gravimetric 8 8-oz widemouth Cool to 4°C + 0.5 mg/g
glass jar w/
Teflon ·lined cap
Total Organic
Carbon EPA 415.1,2 Combustion 4,8 8-oz wfdemouth Cool to 4°c + 0.4 mg/g
glass jar w/
Teflon ·lined cap
Porosity EM 1110·2· Gravimetric 9 Shelby-tube or un· None required NA NA
1906· I I disturbed sampling
tube
- -
-- -- - - - - - -- - ---- -
C·REMNCSU2/FSAPH62.3
01/11/87
Table 6-2. SUfflnary of Analytical Methods, Preservatfon Techniques, Holding Times, and Method Oetect;on Limits, NCSU, Farm Site Lot 86
(Continued, Page 3 of 4)
Parameter
Btu Content
Graf n S lze
Surffcial and
Subsurface Soft Samples
Method* Technique
02015 Combustion
ASTM D44 Sf eve
Method
Reference
I ASTM
ASTM
Sample Container
8-oz wfdemouth
glass jar w/
Teflon ·lined cap
8-oz widemouth
glass jar w/
Preservation
Required
None required
None required
Maximum
Holding Time
NA
NA
MDL
NA
NA
N Teflon •lined cap V,
*OQO Level 11 is a screening technique; although certain methods are cited, the quality control samples used at thf1 level will be less
than that specified In the method.
•EPA has not established maximum holding times for these parameters in solid matrices. The maximum holding times for a water matrix
should be used as a goal In these instances.
••All other metals include: antimony (Sb), beryllium (Be), cadmium (Cd), chromium (Cr), copper (Cu), lead (Pb), nickel (NI), silver
(Ag), and zinc (Zn).
NA z Not applicable.
EPA= Environmental Protection Agency.
BNA = Base/neutral end acid extractable
Polychlorfnated bfphenyls.
organic compounds.
PCBs
GCMS = Gas chromatography/mass spectrometry.
GC/EC = Gas chromatography/electron capture detector.
-Btu British thermal unft.
CVAAs Cold vapor atomic absorption spectroscopy.
GFAAs
ICP
mg/g
mg/L
ug/L
mg/kg
ug/g
• Graphite furnace atomic absorption spectroscopy.
= Inductively coupled plasma.
= milligrams per gram.
= milligrams per liter.
= micrograms per liter.
ml l l fgrams per kilogram.
= micrograms per gram.
- -
-- -- - - - ---- -- - - - -
C·REMNCSU2/FSAPH62.4
01/11/87
Table 6-2. Summary of Analytical Methods, Preservation Techniques, Holding Times, and Method Detection Limits, NCSU, Farm Site Lot 86
(Continued, Page 4 of 4)
References:
1. Guidelines Establishing Test Procedures for Analysis of Pollutants under the Clean Water Act, Federal Register Vol. 49 (209),
October 26, 1984, P43234,
2. Organics--Contrect Laboratory Program (CLP), Information for Bidders (IFB), Statement of Work (SOW), July 1985.
3. lnorganfcs··Contract Laboratory Program, Information ,for Bidders, Statement of Work, September 1985.
4. Methods for the Che~ical Analysts of Water and Wastewater, EPA 600/4-79-20, revised March 1983, USEPA·EMSL, Cincinnati, Ohio.
5. Prescribed Procedures for Measurement of Radioactfvfty fn Drinking Weter, EPA 600/4·8·032 (1980 Update), August 1980, USEPA,
Cincinnati, Ohio.
6. Test Methods for Evaluating Solid Wastes, EPA·SW-846, July 1982, 2nd Edition, USEPA, Office of Solid Waste and Emergency Response,
\.lashfngton, DC.
7. Procedures for Handling and Chemical Analysts of Sediment and \.later Samples, Technical Report, EPA/CE-81·1, USEPA/Corps of Engineers
Technical Committee. NTIS No, AD/A103 788, May 1981.
8. laboratory Soila Testing, EH1110·2·1906, Department of the Army, OCE, November 30, 1970.
~ Source: ESE, 1987.
- -
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
'I
I
I
I
6. 2 SUB5URF.ACE SAMPIES
6.2.l stations
C-RD!NCSU2,IFSAP-6.3
01/11/87
Subsurface soil samplirx:J locations are shcMn in Figure 5-1. 'Ihe stations
(i.e., J:6-Al) are designated by the prefix r:s for the type of samples
(Deep soil) an:l. with a letter A, B, C, D, E, F, or G to designate the
samplirx:J area. 'Ihe sample rnJJDber foll= the samplirx:J area designation.
A pei:manent record of the samplirx:J sites will be made by stakin; an:l.
photographin;J each location. · In acxlition, the locations will be
designated on the -site map produced by the C011Ltacted sw:veyors.
6.2.2 Parameters
All soil samples will be screened with the HNU for health an:l. safety
purp:,ses an:l. for qualitative volatile organic concentrations in the
sample. Foor urxlisturbed (Shelby tube) samples will be collected from
borirx:Js J:6-D an:l. J:6-E to detel:mine the dip of lithologic contacts an:l.
bedding planes for use in locatirx:J MW-35 an:l. MW-36. 'Ihe sample depths
an:l. paraireters to be analyzed are given in Table 6-1. Samples from areas
J:6-A, J:6-B, an:l. J:6-C will be collected adjacent to the chemical waste
disposal trenches. 'lhese samples will be analyzed for the follc:Min;
parameters.
o l'H3-:Riysical soil parameters, incll.ldin:J nr,isture content an:l.
Btu =tent, will be analyzed as SAS, rQO Level v, by a REM III
team laboratory.
o HSL3--HSL inorganics analyzed at rQO Level III by a REM III
laboratory.
Samples collected fram the deep borirx:J used to detel:mine the lithology of
the saprolite an:l. upper bedrock will be analyzed for the follc:Min;
parameters:
o Hll--<kain-size analyses will be perfornai on samples from
borirx:Js J:6-E an:l. J:6-G at depths of 10, 50, an:l. 40 ft. Since
27
I
I
I
I
I
I
I
I
I
I
I
I
. I
I
I
I
I
I
I
C-RrnNCSU2jFSAP-6.4
0l/ll/87
these data are required to detennine the feasibility of a slurry
wall, the sanples will be analyzed only if the depth to the
bedrock is less than 150 ft, the practical limit of slurry wall
feasibility.
o m2-Blysical parameters inclUCill'l3' :r;orosity, am Atterberg
limits will be detenni.ned an the soil sanples. Permeability,
filter press, am viscosity tests will be nm an a mixture of
the soil sanple, bentonite, am the native ground water. 'lbese
parameters will be analyzed by a REM III team laboratory as a
SAS. Sanples will be collected at the approximate depths given
in Table 6-1.
o 'IOC-'IOC will be analyzed fran fOllr sanples collected foi:m.
bor:in;Js rs-E am rs-c.
6. 2. 3 Samplin:r Methcrls
SUbsurface soil sanples will be collected in a=rdance with REM III
Guideline FT-7. o.3 for split-spoon am umisturl:,ed (Shelby tube) samples.
All soil sanples will be collected in boreholes durin; SPI' thra.Jgh a
hollow-stem auger. Sanpling equiptent will be decontaminated in
a=rdance with REM III Guideline FI'-12.01 prior to collection of samples
for chemical analysis •
6.2.4 ,Sample Treabrent
o Preservatian-J.wlicable sample preservation guidelines, as.
presented in REM III Guideline FI'-7. 06, will be followed.
0 Iabelling-Sanple labelling guidelines are presented in REM III
Guideline FI'-7. 05. All labels will be prepared prior to sample
collection am will contain information an site name, sample
number, name of collector, date am til!le of collection, place of
collection, type of 5a1Tple, sample volume, analysis required,
am preservation technique.
o Pac.kin;r, Shiwing, am Transportation-Sanples will be packaged,
shipped, am transported in a=rdance with REM III
28
I
I
I
I
I
I
I
.I
I
I
I
I
I
I
I
I
I
C-RrnNCSU2jFSAP-6.5
01/11/87
Guideline FT-7. 07. When sample shipments are to be made, the
receiving laboratory will be telephoned on that day or the
follc:M:i.ng 11Crnin3' in order to notify the laboratory of shipment,
airbill rrumber, an:i rrumber/type of samples being shipped.
Table 6-2 presents the analytical methods, types of containers, holding
times, an:i MDI.s for subsurface soil samples.
6.2.5 D,.mlicate Samples
'Ihe rrumber an:i locations of duplicate samples are given in Table 6-1.
6. 3 GRaJND WATER SAMPIES
6.3.l stations
'Ihe g:rourxi water sampling locations are given in Table 6-1 (see
Figure 5-1). 'Ihe 11¥:Jl'litor:i.ng wells are rumberEd consecutively from l to
20 an:i fram 29 throogh 35 with one or more wells at a location designate:i
with a letter (i.e., A or B). MW-30 throogh MW-36 will be installe:l.
during the RI. 'Ihe details of 11¥:Jl'litoring well construction are given in
Table 5-1.
6.3.2 Parameters
Ground water samples will be collected from 18 of the 29 existing wells
an:i frcm all 7 new wells. Eleven of the existing mnitoring wells were
exclude:l. frcm the g:rourxi water sampling prc:gram because they are not
expected to provide significant new data useful in pltnne delineation.
Wells to be sample:l. were selected based on the appropriateness of their
locations an:i depths for des=ibing the horizontal an:i vertical extent of
contamination •. One well, MW-6, was eliminate:i frc:m sampling because of
faulty construction that could potentially =,promise sample integrity.
Ground water samples will be analyze:l. for HSL organics an:i inorganics,
including gross ali;i1a an:i beta radiation for MW-3B, MW-4, MW-8, MW-14,
an:i MW-30 samples. Table 6-3 presents analytical methods, preservation
techniques, holding times, an:i MDI.s for the groorxl. water sampling
29
"' 0
- --- - - - -- - - ---- - -
C·REHNCSU2/FSAPH63.1
01/11/87
Table 6-3. Surrmary of Analytical Methods, Preservation Techniques, Holding Times, and Method Detection limits (MDL), NCSU, Farm Site
Lot 86 Ground ~ater Samples
Method* Method Ref· MDL
CDOO 11, Analytical erence (DQO Preservation Maximum (D00 Ill/
Parameter 111/IV) Technique II, 111/IV) Sample Container Required Holding Time IV)
HSL Organics
Vol at i Les EPA 624/
624-CLP·H GCHS 1/2 3 x 40, 60·ml amber Cool to 4•c 7 days 1.6 to 6.9 Ug/L/
glass vials w/Teflon~ (0.008 percent CRDL
lined septum Na 2s2o3)+
BNA EPA 625/
Extractables 625·CLP·H GCHS 1/2 2 x 2-l amber glass Cool to 4•c 7 days to 1 O to 50 ug/L/
jars with Teflon~ (0.008 percent extract+ CRDL
l fned caps Ne2Sz03)+ 40 days after
extraction
Pesticides EPA 608
end PCBs 608-CLP·H GC/EC 1/2 Z x 2-l amber glass Cool to 4 °C 7 days to 0.01 to 5.0 ug/L
jars W/Teflon~ (0.008 percent extract+a CRDL
lined caps Na2s 2o3>+ 40 days after
(adjust pH to extraction
5 to 9)
Total Phenolics EPA 420.1/
CLP Colorimetric 4/3 1-L glass bottle H2so4 to pH <2, 28 days 0.01 mg/L/CROL
w/Teflon~lfned cap cool to 4°C
HSL lnorgenics •
Cyanide EPA 335.3/
CLP Colorimetric 4/3 1-L polyethylene NaOH to pH >12, 14 days** 5.0 ug/L/CRDL
bottle/cubitainer chill to 4°C
{0.6 g ascorbic
acid)**
-
I·
\,J ,_.
--- -- - - - - -- - ---- -
C·REMNCSU2/FSAPH63.2
01/11/87
Table 6·3. Summary of Analytical Methods, Preservation Techniques, Holding Times, and Method Detection Limits (MDL), NCSU, Farm Site
lot 86 Ground ~ater Samples (Page 2 of 3)
Method* Method Ref-MDL
(DQO 11, Analytical erence (DQO Preservation Maximum (DQO 111 /
Parameter 111/IV) Technique 11 , III/IV) Sample Container Required Holding Time IV)
Metals
Mercury (Hg) EPA 245.2/
CLP CVAA 4/3 1-L polyethylene HN03 to pH <2 28 daya 0.2 ug/L/CRDL
bottle/cubitainer
Arsenic (As) EPA 206.2/
CLP GFAA 4/3 1-L polyethylene HN03 to pH <2 6 months 10 ug/L/CRDL
bottle/cubftainer
Selenium (Se) EPA 270.2/
CLP GFAA 4/3 1-L polyethylene HN03 to pH <2 6 months 5 ug/L/CRDL
bottle/cubitainer
Thallium (Tl) EPA 279.2/
CLP GFAA 4/3 1-l polyethylene HN03 to pH <2 6 months 10 ug/L/CRDL
bottle/cubitainer
All others++ EPA 200.7/
CLP ICP 4/3 1 · L polyethyene HN03 to pH <2 6 months 5 to 50 ug/L/
bottle/cubitainer CRDL
Gross Alpha
and Beta EPA 900.0 PC 5 4-L polyethylene HN03 to pH <2 6 months 1.0 ptcocurie/l
bottle/cubitainer
Temperature EPA 170 .1 Thermometric 4 NA None required Field analysis o. 1 ·c
pH EPA 150. 1 Electrometric 4 NA None required Field analysis 0.1 pH uni ts
Specific
Conductance EPA 120. 1 Electrometric 4 NA None required Field analysis 1 umhos/cm
- -
!
!·
w N
--- - - --- - -- - - - ---
C·REMNCSU2/FSAPH63.3
12/30/86
Table 6-3. Surrvnary of Analytical Methods, Preservation Techniques, Holding Times, and Method Detection Limits (MOL), NCSU, Farm Site
lot 86 Ground ~ater Samples (Page 3 of 3)
*DOD Level 11 is a screening technique; although certain methods are cited, the quality control samples used et this well will be less
than that specified in the method.
+CLP maximum holding time fa 5 days to extraction plus 40 days after extraction.
**Added in the presence of residual chlorine.
++All other metals include: Antimony (sb), Beryllium (Be), Cadmium (Cd), Chromium (Cr), Copper (Cu), Leed (Pb), Nickel (Ni), Silver
(Ag), Zinc (Zn).
Note: 1. 000 level 11 is a screening technique, although certain methods are cited, the quality control samples used at this level
wilt be less than that specified in the method.
CLP Contract Lab Program. PCB Potychlorinated biphenyls.
EPA = Environmental Protection Agency. NA= Not applicable.
GC/EC = gas chromatography/electron capture detector. HN03 s Nitric acid.
CVAA = cold vapor atomic absorption spectroscopy. cm= centimeter.
GFAA = graphite furnace atomic absorption spectroscopy. H2so4 = sulfuric acid.
ICP = inductively coupled plasma. NaOH: sodium hydroxide.
PC = proportional counter. Na2s2o3 = sodium thiosulfate.
GC/MS = gas chromatography-mass spectrometry. ug/L = micrograms per liter.
HSL = Hazardous Substance List. mg/L = milligram per liter.
BNA = Base/neutral and acid extractable organics.
References:
1. Guidelines Establishing Test Procedures for Analysis of Pollutants under the Clean Uater Act, Federal Register Vol. 49 (209),
October 26, 1984, P43234.
2. Organics··Contract Laboratory program (CLP), Information for Bidders (IFB), Statement of Uork (SOU), July 1985.
3. lnorgenics··Contract Laboratory Program, Information for Bidders, Statement of Work, September 1985.
4. Methods for the Chemical Analysis of Water and Wastewater, EPA 600/4·79·20, revised March 1983, USEPA·EHSL, Cincinnati, Ohio.
5. Prescribed Procedures for Measurement of Radioactivity in Drinking water, EPA 600/4·8·032 (1980 Update), August 1980, USEPA,
Cincinnati, Ohio.
6. Test Methods for Evaluating Solid_Wastes, __ EPA·SW-846, July, 1982 2nd Edition, USEPA, Office of Solid Waste and Emergency Response,
Washington, DC.
7. Hazardous Waste Management System; Identification and Listing of Notification Requirement, Reportable Quality Adjustment Proposed
Rule, Hazardous Waste, Federal Register, Vol. S1 (114) June 13, 1986, P26648.
8. Procedures for Handling and Chemical Analysis of Sediment and Uater Samples, Technical Report, EPA/CE-81·1, USEPA/Corps of Engineers
Technical Co~mittee. NTIS No. AD/A103 788, May 1981.
Source: ESE, 1986.
--
' I .
' .
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
C-REMNCSU2/FSAP-6,6
01/11/87
pl.o,JLdlll, Sanlplin:J depths arxi analytical parameters for each well sample
are presented in Table 6-1.
6 • 3 • 3 Sampl i,rn Methcxls
Groun:i water samples will be collected in a=I"dan::e with the
REM III Guideline FI'-7. 02. Prior to the inp.rt of aey article (i.e. ,
measurin:] tape, p.llllp, bailer, line, etc.) into the well, the article will
be decontaminated in a=I"dan::e with REM III Guideline FI'-12.01.
Monitorin:] wells will be purged usin:J dedicated Teflone ballers or
bladder-type p.ll1lpS with dedicated Teflone tubin:J prior to collection of
the sanq;,le for water quality analysis. 'lllree to five well volumes will
be purged; h=er, if the wells are purged dry with less than 3 well
volumes renoved, then the water level will be all~ to = to at
least 70 percent of static level prior to sample collection. Field
neasureirent.s of :fii, temrerature, an:i specific conductivity will be taken
at the beg:l.nn:iD], middle, arxi en:l of purgin;J arxi recorded in the field
logbook.
6.3.4 Sanple Treatment
o Preservation-sample preservation guidelines are presented in
REM III Guideline FI'-7.06.
0 I.abellin:]-Saniple labellin:J guidelines are presented in REM III
Guideline FI'-7.05.
o Packagin:J, Shippin:J, arxi Transportation-Sanlples will be shipped
arxi transported in a=I"dan::e with REM III Guideline FI'-7. 07.
A summary of analytical methods, preservation techniques, holdin:] times,
arxi .MDis for grourxl. water samples is presented in Table 6-3.
6.3.5 D,Iplicate Sanples
'Ihe l1llI!lber arxi location of duplicate samples are given in Table 6-1.
33
I
I
I
I
I
I
I
' I
I
I
I
I
I
I
I
I
·I
I
... •--··· ................ .
6.4 D:.PIR-1EN'X JJEO:m71MINATIOO
C-REMNCSU2,IFSAP-6.7
01/11/87
All equipnent used f= collect.in;J samples f= d'lemical analysis will be
clecontaminated pri= to sample collection, between samples, and at the
en:i of sampl.ina, F.quipnent to be decontaminated includes the folla.in;J:
stainless-steel. hand augers, ~, spatulas, :blckets, and split-spoon
samplers used in soil sampl.ina and bail.ina cord, ballers, p.l!TpS, tubirg,
steel tapes, and electric water-level indicators for grc:,.m:i water
sampl.ina. 'lbe decontamination pr, ce::b:rres are as follows:
o Potable water rinse,
o Al=icx = liquinox rinse,
o Potable water rinse,
o Distilled/deionized water rinse,
o Isopropyl alcohol (pesticide grade) rinse,
o Distilled/deionized water rinse,
0 Air dcyirg, and
o Wrap with aluminum foil for storage= transport to field,
All of the equipment used in test borin3's, =itorirg well installation,
and soil rellOVal will be decontaminated CNe:r a decontamination pad
onsite. 'lbe decontamination pad will be constructed pri= to the
drillirg of any bor~ and will be constructed to allow collection of
the rinse water. 'lbe rinse water will be collected and disposed of in
unlined pits onsite, excluclirg the rinse water from decontamination of
equipnent used for the onsite subsurface soil bo~ and the bo~ for
MW-34 and MW-35. Rinse water pra:iuced from decontamination of equipment
used for these bor~ will be contained in dnms, stored onsite, and
later disposed -in a=rdance with USEPA regulations. 'Ihis equiprrent will
include the folla.in;J: drill rig, backhoes, frorrt-eni loaders, augers,
and drill rods, bits, and core barrels. 'lbe equipment will be
decontaminated as follows:
34
I
I
I
I
I
I
I
1·
I
I
I
I
I
I
I
I
I
I
ii
... ,-. -•-·-··-.... -··-· ----.~ .:..·_ .... .., ............. ____ :
C-REMNCSU2,IFSAP-6. 8
Ol/ll/87
o steam cl~ or liquinox or al=nox wash with b:rushin:;,,
o Potable water rinse, arxi
0 Air chy.
35
I
I
I
I
I
I
I
I
I
I
I
I
I
I
11
7. 0 CQALITY ASSURANCE AND CQALITY CX>NI'ROL (ONOC:l
C-RrnNCSU2jFSAP-7.l
01/11/87
7 .1 FIEID INS'lR1MENl' CALIBRAT.IOO' AND PREVENI'IVE MAJNI'ENANCE
D.lrir)3' l!Ol1itorin;J well ~ an:l. samplir)3', samples will be field tested
for pH, ternfer'lture, an:l. specific o::ioouctivity. '.Ille cali.braticm arrl use
of these inst:nma1ts will be in a=rdance with REM m Guideline
FT-7.10.
7. 2 FIEID BIANKS AND SPIKES
Blank samples are used to check the a=micy of a samplir)3' method an:l. to
determine if there is int:rocructicm of errors durin;J the measureirent
process. Trip blanks are samples of analyte-free deicmized water poured
into sample containers an:l. sealed prior to the samplir)3' event arrl which
acconpany the samples taken in the field throogh storage, pack:in3", arrl
shippir)3' to the laboratory. 'Ihese blanks will be prepared on a daily
basis durir)3' gramd water samplir)3'. Protocx,ls for trip blanks for soil
samples have oot been established.
Field blanks or decontaminaticm blanks ·are a check cm the equipment
decontaminaticm process. '.Ille preparaticm of field blanks =isists of
collecticm of analyte-free deicmized water after it has been poured
throogh the decontaminated samplir)3' equipment. '.Ille field blanks are •then
packed, shipped, an:l. analyzed with the samples. One field blank will be
collected for every 20 samples, by parameter.
'.Ille proposed number of samples, duplicates, an:l. blanks, by medium, is
sumnarized in Table 7-1.
7 • 3 IXXllMENTATIOl I Docurnentaticm of all activities will include a site lcgbook, field
notebooks, labels, custody seals, cha.in-of-custody fonns, corrective · I
I
I
acticms fonns, approvals, an:l. field instrument cali.braticm fonns.
REM m Guideline FT-13.03 describes ESE's REM m Site Lcgbook
procedures. '.Ille samplir)3' team will keep waterproof field notebook!;
36
I
I
I
I
I
I
I
I
I
I
I
I
I
••
I
I
I
I
I
C-RlliNCSU2/FSAP'n 1 . 1
01/11/87
Table 7-1. RI/F'S Salrplin;J and Analytical summary NC:SU I.ot 86
NUrnber of Anal vses
Media Salrples A B C D E F G H Total
Water 26 25 1 5 0 0 0 0 31
Field
D.Iplicates 5 2 1 4 0 0 0 0 7 Trip Blanks* 8 7 1 1 0 0 0 0 9 Field Blanks 3 2 1 1 0 0 0 0 4
Subtotal 42 36 4 ll 0 0 0 0 51
SUrface and SUb-
surface Soils 41 31 0 0 9 4 4 6 35 89
Field
D.Iplicates 8 2 0 0 ·1 4 1 1 8 17 Field Blanks 3 2 0 0 0 1 0 0 0 3
Subtotal 52 35 o· 0 10 9 6 7 43 109
Total 94 71 4 ll 10 9 5 7 43 160
Note: laboratory spikes will be analyzed as specified in the starrlard Operating Proce::lure of the REM .III Teal!l laboratory.
*Trip blanks will be subnitte:l. at a rate of one per day. 'Ibe numbers of san,ples listed are based an estimated field samplin;J t:im:s.
A = HSL organics and inorganics Level III •
B = HSL organics and inorganics Level 'IV.
C = Gross Alpha and Beta.
D = Btu content.
E = 'ICC
F = Atterberg limits, viscosity, filter press, porosity, pe=ability. G = Grain size.
H = Moisture cantent.
Source: ESE, 1987.
37
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
C-RlliNCSU2jFSAP-7.2
01/11/87
cx:irrtainiD3' information on sample rrumber, sample rollectian, tine, sample
location, sample description, samplirq methods, weather, in situ
measurements, am other pertinent information. Olain-of-custody fems,
labels, custody seals arrl other sample documents will be maintaine:i as
specified in REM Ill Guideline FT-7. 05.
7.4 AUDITS
A minimum of one QA performance audit will be perfonned by a designated
QA scientist durin;J con::luct of soil arrl grc,..irxi water samplirq. 'lhis
audit will include checks an adhereooe to all samplirq prot=ls from
station positianirq thrc:u3h samplirq, sample han:ilirq, arrl documentation.
If it becomes necessary to m:dify a program, the Field Operations Ieader
will be required to notify the site Manager of anticipated arxljor
:i.J:mrediately niaroated charges. 'lhis action is followed by USEPA
notification arrl written authorizatiorv~ notice documentation. '!he
significance of actions taken in the field will be evaluated arrl
documented in writirq by the Site Manager.
38
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
·I
I
APPENDIX A
SECTIOO II
DRAFT SITE MANAGEMENr PI.AN
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
••
I
I
WORK ASSIGNMENI': 64-46G7
CONI:RACT NUMBER: 68-01-7250
EBASO) SERVICES INmRroRATED
rnAFT SITE MANAGEMENl' PIAN RE1'1EDIAL INVESTIGATION AND FEASIBILITY S'IUDY
NOR'.lH CAROLINA STATE UNIVERSITY I.or 86 SITE RAI.EIGH, NORIH CAROLINA
JANUARY 1987
NOrICE
The inforrr,ation in this docun-ent has been fun:ied by the United States Environmental Protection Agercy (USEPA) un::ier REM III contract No. 68-01-7250 to Ebas= Services Incorporated (Ebasco). 'lhis Draft Site Management Plan is a draft an::i has not been forrr,ally released by either Ebasco or the USEPA. As a draft, this docun-ent should not be cited or quoted and is bein;J circulated for camrne:nt only •
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
w:JRK ASSIGNMEITT': 64-46G7
<XlNI'RACT NUMBER: 68-01-7250
EBASC:O SERVICES INCORroRATED
DRAFr SITE MANAGD!ENl' PI.AN
!ID!EDIAL INVESTIGATION AND FEASIBILITY SIUDY
NORIH CAROLINA STATE UNIVERSITY I.Or 86 SITE
RAIEIGH, NORIH CAROLINA
JANl.lARY 1987
PREPARED BY:
CAROLYN F. roPPELL
SITE MANAGER
ENVIRONMENrAL SCIENCE AND ENGINEERING, INC.
Approve:! by:
Russell H. Boyd, Jr., P.E.
Regional Manager, Region N
Ebasco SeJ:vices In=rporated
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
;I I
11
Section
1.0
2.0
TABI.E OF a::mnm,
SITE O)NTROL
1. 1 SITE 1\0':FSS
1. 2 • SITE SEa.lRITY/CXJNrnoL
1. 3 FIEr:D OFFICE/CXMWID R:ST
SITE OPERATIONS
2 .1 ~ZATICN
2. 2 RESFONSIBILITIES OF KEY PERS0NNEt 2.3 Scm:r:tJIE
•
i
C-RIBNCSU2/SMPIOC .1
12/31/86
1
1
1
1
3
3
6
7
I
I C-RDINCSU2/SMPIOF. 1
I
12/31/B6
LIST OF FIGURES
I Figure Page
I 2-1 NCSU Site RI/FS Project Organization 4
2-2 NCSU Site RI Field Operations Team 5
I
I
I
I
I
I
I
I
I
I
I
I
I
I ii
I
I
I
I
I
I
I
I
I
I
I
I
:I
I
I
I
I
I
I
l. 0 SITE OONTROL
l. l SITE l\CX:FSS
C-Rll!NCSU2/SMP-l.l
01/12/87
'1be North carolina state University (NCSU) Lot 86 site is accessible by
IXJblic roads, althoogh the site itself is secured by a chain-link .fence
with barbed wire ani a locked gate. Keys to the gate are kept by the
NCSU Department of Public Safety. '1be REM III Site Manager will arran;re,
through the :Regional Project Manager (Rm) , to obtain access to the site
from NCSU. No REM III team mernbPr will enter the site until:
(1) written or verbal authorization is received fram the Site Manager or
designee, (2) at least 24--hct.lr notice is given to the appropriate NCSU
authorities before initiation of field activities, ani (3) each field
team member has personal identification in the fonn of a driver's
license, ccmpany identification card, or a suitable 51.lbstitute approved
by the Field Operations Ieader (FOL) • A list of persons authorized to
enter the site will be provided to the NCSU Department of Public Safety
by the Site Manager or the FOL. '1be list, which is interrled to prevent
unauthorized persons from gaining site access, will be updated, as
necessary, by the Site Manager or her designee. In gaining site access,
no REM m teain nember will sign or ackncMledge any con::litional
acceptance offered by NCSU unless approved by the Site Manager.
1.2 SITE SEaJRITY/ccmroL
All rem:ivable equiprent will be returned to the cammartl post ani secured
at the errl of the work day. Nrf equii;:ment left onsite will be secured to
the extent possible to prevent unauthorized reroval or vanialism. Nrf
unfinished wells will be covered or capped in such a manner as to prevent
tampering. Finished wells will be locked.
l. 3 FIELD OFFICE/a:M!AND :ro5T
A field office will be established near the site in a small, m:ibile,
office trailer. Based on discussions between the Site Manager ani the
NCSU Deparbrent of Public Safety, the field adjacent to the site is not
an acceptable long-tenn location for the trailer, since the field is used
1
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
C-RlliNCSU2/SMP-l. 2
01/12/87
for overflow parking during stadium events an::l. cannot be secured.
Therefore, during m:ibilization activities, a suitable location for the
trailer will be found, an::l. the area will be enclosa:l. with a chain-link
security fence. nie trailer will be utiliza:1. as a cammarxi storage point
f= safety an::l. sampling equipnent, a staging area for sampling teams, an::l.
a sample shi:r;:ping point. D.le to the distance of the site from telephone
lines, tele;:ticne service will not be available in the trailer. Public
telephones are available, however, at carter-Finley stadium,
approximately 0.25 mile fran the site.
2
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
2. 0 SITE OPERATIONS
C-RrnNCSU2/SMP-2. l
01/12/87
'Ille foll~ subsections ootline the organization of the field team for the NCSU Rerredial Investigation (RI) field w:irk, responsibilities of key personnel, arrl the schedule for performance of the RI field w:irk.
2. l ORGANIZATICN
'Ille overall project o~ation arrl responsibilities of key '!!'8Ilagement
personnel are disa1ssed in Section 6.0 of the 'RerediaJ tnvestigation/
Feasibility study (RI/FS) Work Plan. 'Ille organizational chart presented in Sect.ion 6.0 is reproduced as Figure 2-1 for quick reference.
Field w:irk will be performed by a sin;,'le team, un::ler the dixection of the FOL. As shown in the figure, the FOL 1epm:ts directly to the RI Task
Manager. For the NCSU Site RI/FS, the Site Manager will also serve as RI Task Manager. Figure 2-2 shc:,,/s the field q,eratians organization in greater detail. 'Il1e FOL will be responsible for coordinatin:J arn overseein;J all field activities arn will interface with the Health and Safety Officer (HSO) in plannim am performing the RI tasks. F.ach of the Field Team Ieaderc; (FTis) designated for the site RI activities will report to the FOL on a day-to-day basis. FrI£; have been designated for backgroun:i SU1Veys, geophysical surveys, -11 installation am soil
borings, groun:l. water am soil samplin;J, am excavation activities.
'Ille FOL will serve as the F1'L for backgrourxi surveys, wnich include site SUIVeys and records searches. Geophysical surveys will be performed by Technos, Inc., with oversight by the FOL. Well installation, soil borings, arn all Scllli)lin;,' activities will be managed by a geologist
designated as FrL. Oversight of subcontracted soil excavation activities will be provided by another Fl'L. In aexx>rdance with the Health am Safety Plan (HASP), the HSO, or his designee, will interact with the field team durin;,' perfonnance of their tasks.
3
---- - - - - - --- - - --- --·
04/NCSU.1-P
BEMJll ESE DESIGNAIED LEAD
EeA DeQ REGIQNAL MANAGER ... ,,,. ........... D. Bruderly ,,,,,,,.,,,,~
J. Orban R.H. Boyd I
I I I I I I I
EPA RPM SIIE MANAGER 1,, ... ,,, ......... , ...... ,, .... ~ ....... ,, .... C. Poppell CQMeANY HEALIH AND SAFEIY sueERVISQR D. Puffer I,, ..................
C. Haury
HEALIH I!. SAEEIY QEEICER
D. Endicott
I ' I
GEQPHYSICS {IECHNQSl LABQRAIQRY SERVICES SUElCQNIRACIQRS ~ CQQRDINAIQB R. Benson L. Bare Drilling
I Surveys/Mapping
I General Services . j
CONTRACT I REM Ill LAB I TransporVDisposal
LABORATORY Excavation
PROGRAM (CLP)
I I
Bl IASIS MANAGER FIELD QeERAIIQNS ES IASIS MANAGER i--LEADER C. Poppell W. Quarles L. Carter
I I I
RI PROJECT TEAM FIELD TEAM FS PROJECT TEAM
Figure 2-1
NCSU SITE RI/FS PROJECT ORGANIZATION ENVIRONMENTAL SCIENCE
AND ENGINEERING, INC.
SOURCE: ESE. 1987.
-------------------
D4/NCSU.2 1187 k
FIELD OPERATIONS HEALTH AND
LEADER +·········----· SAFETY OFFICER
' W. Quarles D. Endicott
' ' +
BAO<GOOl1'JD GEOPHYSICAL WELL INSTALLATION GROUNDWATER AND
SURVEYS SURVEYS AND SOIL BORINGS SOIL SAMPLING EXCAVATION
FIELD TEAM LEADER FIELD TEAM LEADER FIELD TEAM LEADER FILED TEAM LEADER FIELD TEAM LEADER
W. Quarles Technos, Inc. J. Griffin J. Griffin L. Carter
V,
FIELD TEAM
GEOLOGISTS, ENGINEERS, TECHINICIANS
Figure 2-2
· NCSU SITE RI FIELD OPERATIONS TEAM ENVIRONMENTAL SCIENCE
AND ENGINEERING, INC.
SOURCE: ESE 1987.
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
m
C-RD!NCSU2/SMP-2.2
01/12/87
D.le to the duration of the field pro,iram, the RI Task Manager will fill
in for the roL in the field, as needed, to ensure continuity arrl to meet
project schedules.
2. 2 RESroIBIBILITIES OF KEY PERSOONEL
Fey personnel for field operations are identified in Figures 2-1 arrl 2-2.
'Iheir specific responsihilities are disa1ssed below.
o Field Operations "Leader croLl • 'Ihe roL is responsihle for all
day-~y aspects of the NCSU RI field work. 'Ihe responsi:-
bilities of the roL inclooe:
-:Assurin;J that all field team nembers are familiar with th~
Field Samplin;J arrl Analysis Plan (FSAP) arrl HASP,
-:Assurin;J that all field team IJV"fflbers have completed health arrl
safety trainirg,
-Reportin;J to the RI Task Manager on a regular basis regarding
the status of all field work arrl any problems encountered,
~letin;J Field Olan3'e Orders, as necessary, for approval
by the Site Manager, arrl
--COOrdinatin;J the activities of all field teams.
0 Field Team Leader (FI'L). 'Ihe FI'L reports directly to the roL
arrl has the followin;J responsihilities:
-Prcvidin;J team nembers with daily assignments,
-:Assurin;J that team IJV"fflbers comply with the procedures
ootlined in the FSAP,
--COOrdinatin;J with the roL to ensure sample shippin;J schedules
are met, arxi
-Reportin;J on a daily basis to the roL an the progress of the
team.
o Site Health arxi Safety Officer (HSO). 'Ihe HSO reports to the
Company Health arxi Safety SUpervisor (CRSS) arxi in::lirectl to y .
6
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I ,., ,.
I
I
I
C-REMNCSU2/SMP-2.3
01/12/87
the FOL an:l. Site Manager. Details of the HSO's responsibilities
are presented in the HASP an:l. in:::lude:
~ntrolling specific health an:l. safety related field
operations such as personnel decontamination, m::initoring of
=rker heat or cold stress, distribution of safety equiprent,
etc.;
~nformance of field team personnel with all procedures
established by the HASP;
-Identifying of Assistant HSOs or HSO designees; an:l.
-Terminating =rk if an i=inent safety hazard, e:rrergency
situation, or other potentially dangerous situation is
encountered.
2.3 SalEIXJIE
The schedule for the NCSU RI field activities is presented alon::, with the.
overall schedule for the NCSU Project in section 6.3 of the Work Plan.
Key target dates are:
Activity ~ Final
Background records search 03/16/87 04/03/87 Geophysical survey 03/30/87 04/07/87 Mobilize site team 03/30/87 04/10/87 Collect surface soil sarnples 04/13/87 04/15/87 Excavate soil to define trenches* 06/22/87 06/26/87 Waste characterization 06/29/87 07/03/87 Drill wells/soil borings 06/22/87 07/29/87 Land survey 07/30/87 08/19/87 Well sampling 08/13/87 08/21/87 Pump test 08/24/87 08/26/87
*Optional task.
7
I
I
I
I
I
I
I
I
I APPENDIX A •
SECTION III
I DRAFT HEALTH AND SAFETY PI.AN
I
I
I
.I
I -
I
m
n
D
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
SITE-SPECIFIC HEALTH AND SAFETY PLAN FOR REM III
HAZARDOUS WASTE SITE ACTIVITIES
SITE: North Carolina State University, Lot 86
LOCATION: Raleigh, North Carolina
DATE PREPARED: 12/11/86
PREPARED BY: Dan Endicott, Environmental Science and
Engineering, Inc. (ESE)
REVISION: ______ _
I
I
I
I
I
I
I
I
I
I
I
I
I
I I
I
I
I
Section
1.0
2.0
3.0
4.0
5.0
6.0
7.0
8.0
C-REMNCSU.1/HASP.
12/31/86
C-REMNCSU.1/HASP
12/31/86.
TABLE OF CONTENTS
GENERAL
HEALTH AND SAFETY PERSONNEL
2.1 .HEALTH AND SAFETY PERSONNEL DESIGNATIONS
2.2 COMPANY HEALTH AND SAFETY SUPERVISOR
2.3 SITE HEALTH AND SAFETY OFFICER
SITE HISTORY AND PHYSICAL DESCRIPTION
3.1 LOCATION
3.2 DESCRIPTION
3.3 HISTORY
SITE-RELATED INCIDENTS, COMPLAINTS, AND ACTIONS
WASTE DESCRIPTION/CHARACTERIZATION
5.1 HAZARD INFORMATION
5.2 WASTE TYPES
5.3 CHARACTERISTICS
5.4 CONTAINMENT
HAZARD ASSESSMENT
TRAINING
7.1 BASIC TRAINING REQUIRED
7.2 SITE-SPECIFIC TRAINING
7.3 SAFETY BRIEFINGS
7.4 FIRST AID AND CPR
ZONES, PROTECTION. AND COMMUNICATION
8.1 SITE ZONES
8.2 PERSONAL PROTECTION
i
Page
1
2
2
2
2
3
3
3
3
8
8
8
8
8
8
8
15,
15
15
15
15
16
16
16
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Section
9.0
10.0
11.0
12.0
13.0
14.0
15.0
C-REMNCSU.1/HASP
. 01/09/87
TABLE OF CONTENTS
(Continued, Page 2 of 3)
8.2.1 General
8.2.2 Safety Equipment
8.3 COMMUNICATIONS
MONITORING PROCEDURES
9.1 MONITORING DURING SITE OPERATIONS
9.2
9.1.1
9.1.2
9. 1. 3
Drilling Operations
Excavation Operations
Other Operations
MEDICAL SURVEILLANCE PROCEDURES FOR
EVIDENCE OF PERSONAL EXPOSURE
SAFETY CONSIDERATIONS FOR SITE OPERATIONS
10.1 GENERAL
DECONTAMINATION PROCEDURES
11.1 LEVEL BAND C DECONTAMINATION
DISPOSAL PROCEDURES
EMERGENCY PLAN
13.1 EVACUATION
13.2 POTENTIAL OR ACTUAL FIRE OR EXPLOSION
13.3 ENVIRONMENTAL INCIDENT
13.4 PERSONNEL INJURY
13.5 OVERT PERSONNEL EXPOSURE
13.6 ADVERSE WEATHER CONDITIONS
AUTHORIZATIONS
MEDICAL DATA SHEET
ii
Page
16
18
18
19
19
19
19
19
19
20
20
21
21
26
27
.27
27
28
28
28
30
31
32
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
0
D
Section
16.0
17.0
TABLE OF CONTENTS
(Continued, Page 3 of 3)
FIELD TEAM REVIEW
APPROVALS
iii
C-REMNCSU.1/HASP.
12/31/86
C-REMNCSU.1/HASP
12/31/86
35
36
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Table
5-1
Figure.
3-1
3-2
8-1
13-1
C-REMNCSU.1/HASP
12/31/86
LIST OF TABLES
Representative List of Chemicals Included in
Waste Burials
LIST OF FIGURES
Site Location Map
Monitoring Well Locations and Waste Disposal
Areas
Site Work Zones
Hospital Route Map
iv
Page
9
4
5
17
29
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
D
I
1.0 GENERAL
C-REMNCSU.1/HASP.l
12/31/86
This plan has been prepared in.conformance with the Ebasco
Services Incorporated (Ebasco) REM III Health and Safety Plan
(HASP). It addresses all those activities associated with soil
and ground water sampling at the North Carolina State University
(NCSU) site, Lot 86, Raleigh, North Carolina, and will be
implemented by the Health and Safety Officer (HSO) during site
work. Compliance with this HASP is required of all persons and
third parties who enter this site. Assistance in implementing
this Plan can be obtained from the REM III Health and Safety
Manager (HSM), and/or Charles c. Haury, CIH, the Environmental
Science and Engineering, Inc. (ESE) Company Health and Safety
Supervisor (CHSS). The information contained in this HASP is
made available to health and safety (H&S) personnel who are
responsible for monitoring results or changes in the technical
scope of work. Any changes proposed must be reviewed by H&S
staff and are subject to approval of the ESE CHSS and the HSM. A
copy of this plan will be provided to all onsite personnel.
Emergency phone numbers will be displayed at the site command
post.
SITE: NCSU SITE NO.: Lot #86
PLAN DATE: 12/23/86
SCOPE OF WORK: Collect soil and ground water samples to
determine the type and extent of contamination. Planned
activities include soil boring, well installation, and limited
excavation of topsoil. · ·
NAME
WORK PHONE
EMERGENCY PHONE
Raleigh, NC
Raleigh, NC
SITE MANAGER
Carolyn F. Poppell
· (904) 332-3318
NUMBERS
HEALTH AND SAFETY OFFICER
Dan D. Endicott
(904) 332-3318.
911
911 Rex Hospital
Raleigh Community
Police Dept.
Fire Dept.
Hospital
Back-up Hospital
(919) 755-3100
(919) 872-4800 Hospital
Durham, NC
C.C. Haury, CIH
R.H. Boyd, Jr.
W.A. Quarles
National Response Center
Poison Control Center
CHSS
REM III Regional Manager
Field Operations Leader
REM III HSM (G. Smith or
J. Janous)
1
(804) 424-8802
1-800-672-1697
(904) 332-3318
(404) 662-2378
(904) 332-3318
(703) 558-7506
I
I
I
I
I
I
I
I
I
I
I
I
ii
I
D
D
2.0 HEALTH AND SAFETY PERSONNEL
2.1 HEALTH AND SAFETY PERSONNEL DESIGNATIONS
C-REMNCSU.1/HASP.2
12/31/86
The following briefly describes the H&S designations and general
responsibilities which will employed for the NCSU Project.
These titles are herein identified, and the responsibilities are
consistent with analogous titles and responsibilities in the REM
III Program. The titles have been established to accommodate
the site needs and requirements in order to ensure the safe
conduct of onsite work. The number and type of H&S personnel
for the NCSU site is based on the project size and scope and the
particular health and safety training requirements relative to
the proposed site activities or operations. The NCSU site
investigation will require one full-time HSO based on review of
available site information.
2.2 COMPANY HEALTH AND SAFETY SUPERVISOR (CHSS)
The CHSS has overall responsibility for development and
implementation of this HASP. He also shall approve any changes
to this plan, modification of any procedures .as required, or any
new activities proposed. ·
The CHSS is responsible for the development of any new company
safety protocols and procedures necessary for field operations
and is also responsible for the resolution of any outstanding
safety issues which arise during the site work. All health and
safety-related duties and responsibilities will be assigned only
to qualified i_ndividuals by Charles C. Haury, CIH, the ESE
CHSS. Authorization for personnel to perform work onsite (i.e.,
relative to medical exams and training) must be cleared by the
CHSS.
2.3 SITE HEALTH AND SAFETY OFFICER (HSO)
The HSO will be present onsite during all NCSU field operations
at Level C or higher. The HSO will be responsible for all H&S
activities. Where the site is identified as modified Level D,
the HSO will direct the site H&S efforts through an H&S designee
approved by the CHSS. He may direct or participate in downrange
activities as appropriate when this does not interfere with his
primary HSO responsibility. The HSO has stop-work authorization
which he will execute upon his determination of an imminent
safety h'azard, emergency situation, or any other potentially
dangerous situations (e.g., weather conditions,) where this
action is appropriate. Authorization to proceed with work will
be issued by the CHSS after such action. The HSO will initiate
and execute all contact with support facilities and personnel
when this action is appropriate.
2
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
n
B
I
m
3.0 SITE HISTORY AND PHYSICAL DESCRIPTION
3.1 LOCATION
C-REMNCSU.1/HASP.3
12/31/86
The NCSU site is located on Lot 86, west of Raleigh near
Carter-Finley Stadium in Wake County. Entrance to the site is
approximately 100 feet (ft) south of the southern right~of-way
of Wade Avenue Extension (Figure 3-1).
3.2 DESCRIPTION
The site covers an area of approximately 1.5 acres and was used
for burial of radioactive and hazardous laboratory chemicals
from 1969 to 1980.
Topography is gently rolling with broad, flat, interstream
areas. Surface drainage is to the northwest toward the
extension and stadium parking lot, north to the highway, and to
the east.
Radioactive waste was buried in the eastern half of the site,
and laboratory chemicals were buried on the west side
(Figure 3-2).
The site is overgrown with grass, and shrubs
and east sides. The site is surrounded by a
with a locked gate at the southwest corner.
waste burial area is separated from the rest
wire fence and locked gate.
exist on the north
chain-link fence
The radioactive
of the site by a
An unnamed tributary to Richland Creek runs 400 ft east of the
site, and a small pond lies about 1,600 ft west of the site.
The dirt road leading to the site is used as a jogging path by
university students and area residents.
The nearest water supply well is located about 2,000 ft
southeast of the site fence at the Medlin residence. Figure 3-2
shows burial areas, monitoring well locations, and site
proximity to the Wade Avenue extension.
3.3 HISTORY
NCSU educational and research laboratories generated hazardous
chemical and low-level radioactive wastes that were buried on
Lot 86 of Farm Unit No. 1 from 1969 to 1980. The site was
divided into two separate areas, as shown in Figure 3-2. The
western half received the chemical waste, and the eastern half
received the low-level radioactive waste in the form of animal
carcasses.
Site activities are primarily concerned with the hazardous
chemical waste burial area. NCSU has installed 24 monitoring
wells at the site since 1982 (Figure 3-2).
3
1!!!!!1. 111111 lliilill 1iiiiiiiii iiiiii --------------
~)~\l,~~v~~~~~~~~~~=~~~~~' ~. ~~.--~~?~\~l_,%~(~r=:(~I \::::;,.,?.:~~~~~~~~;;;;i') I
• l~:;;\:' \ . c'<"•~''"·~./p(. C
~
-0 .,__ .. a
Figure 3-1
SITE LOCATION MAP
NORTH CAROLINA STATE UNIVERSITY, LOT 86
SOURCE: USGS, 1981.
· I • ~ --•\; i ! , ::_. 0, '\) ,s---.•
-~,,.-· \ \
ENVIRONMENTAL SCIENCE
AND ENGINEERING, INC.
I
I
I
I
I
I
I
I
I
I
I
I
I
m
u
D
I
I
REM/// NCSU 1187A
e1s 013
e9
LEGEND
e MONITORING WELL
LOCATION
-----FENCE
Figure 3·2
21• 27A.
es e1A 1• e1e er
N~2 ea i ~ FOFII.IEFI OFIUI.I
~ f I :«...._ STORAGE AREA ~ < , I ""-.
::,
0 Q
Cl: ~ I /-~ ·r~ _ _J If< ..
4 / ~ ; C <
I ~ i ~ C ... ::, .., . I ~
'-----+•-.i·:_J
\_ FOFllol~ CHEI.IICAL • ;., STORAGE O~TEFI AFIEA
• ..
• .. .,. ------
14
NORTH CAROLINA STATE UNIVERSITY, LOT 86
MONITORING WELL LOCATIONS AND ENVIRONMENTAL SCIENCE
AND ENGINEERING, INC. WASTE DISPOSAL AREAS
SOURCE: COM. 1985.
5
I
I
I
I
I
I
I
I
I
I
I
I
I
g
D
I
m
I
I
C-REMNCSU.1/HASP.4
12/31/86
The university maintains a listing o~ the types and ~antity of
materials buried at the site. From these records a list of
typical chemicals reported in the burials was compiled and is
presented in Table 5-1 (see Section 5.0 of this HASP). The
chemicals listed include so,lvents, pesticides, heavy metals,
acids, and bases.
The chemical wastes were placed in trenches located in the
northwest portion of the site. The trenches were approximately
10 ft deep and 50 to 150 ft long. After filling, about 2 ft of
cover material excavated from the trenches was used to close the
trenches. Later, the disturbed area was seeded with grass.
NCSU estimates that approximately 22 trenches totaling less than
2,000 linear feet were used. Although some of the liquid
chemicals disposed during the initial site operations were
poured into the trenches, both liquid and solid chemicals were
generally buried in metal, glass, or plastic containers. NCSU
estimates3the volume of buries hazardous waste at 890 cubic
yards (yd ) .
The low-level radioactive waste disposal area is regulated at
the Federal level by the Nuclear Regulatory Commission and at
the State level by the North Carolina Department of Human
Resources, Division of Facility Services, Radiation Protection
Section. There is also a NCSU Radiation Protection Commission.
According to Mr. D.W. Morgan of NCSU Radiation Protection
Office, radiological wastes were buried in trenches
approximately 6 ft deep with 4 ft of cover material. The
trenches have been mapped and waste disposal records are
available. Most of the waste is in a solid form, primarily
animal carcasses. These range in size from rats to whole sheep.
The carcasses were frozen when buried and were not ·
containerized. The most abundant radionuclide in the buried
material is tritium which has a half-life of 12.26 years. For
this half-life, after 5 years, 75 percent of the original
radioactivity remains. After 10 years, 57 percent remains.
Other radionuclides include carbon-14, iron-59, phosphorus-JO,
and phosphorus-32. These four isotopes have half-lives of
5,730 years, 45.1 days, 2.5 minutes, and 14 days, respectively.
Of all these isotopes, the ones of greatest concern are tritium
and carbon-14 because of their longer half-lives. No fission
products were buried at the site •.
In September 1984, NCSU acquired the capability of performing
volatile organic analyses on a routine basis using the purge and
trap method. Monitoring Wells (MW) 1, 2, 6, 7, 8, and 12 show
the greatest number of contaminants. Contaminant concentrations
are highest in Wells 1 and 6. There also appears to be a
pattern of increasing contaminant concentrations in these two
wells over the 6-month period from October 1984 to March 1985.
6
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
C-REMNCSU.1/HASP.5
12/31/86
The most frequently detected compounds include benzene, carbon
tetrachloride, chloroform, 1,2-dibromoethane, dichloromethane,
1,2-dichloropropane, diethylether, ethylbenzene,
4-methyl-2-pentanone, toluene, 1,1,1-trichloroethane,
trichloroethene, and xylene.
The Medlin residence well and the 208 Marsh Avenue well were
sampled for volatile organics analyses on November 29, .1984.
Tetrachloroethene and xylene were detected in both wells at a
level of 10 micrograms per liter (ug/L). NCSU researchers
believe the presence of these compounds is the result of
laboratory contamination. These same compounds were al'so
detected in the blank run with the samples. Without knowing
more details regarding well construction and use at these
locations, it is difficult to correlate the analytical results
with results obtained at the site. Furthermore, these wells are
topographically upgradient from the site. ·
7
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
D
C-REMNCSU.1/HASP.6
12/31/86
4.0 SITE-RELATED INCIDENTS. COMPLAINTS. AND ACTIONS
None recorded.
5.0 WASTE DESCRIPTION/CHARACTERIZATION
The following information is presented in order to identify the types of materials that may be encountered at the NCSU site. The information on these materials was obtained from the American Conference of Governmental Industrial Hygienist (ACGIH) Guidelines.
5.1 HAZARD INFORMATION
See Table 5-1.
5.2 WASTE TYPES: Liquid
Sludge
X Solid X
Semi-solid
Gas _x_
Other
5.3
5.4
CHARACTERISTICS: Corrosive X
Explo!aive
Radioactive X
Other
CONTAINMENT: Pit X _ _,_.,_ __ Pond
Process
Vessel
---
Flammable
Volatile
Inert
X
X
Lagoon
Tank-==== Tank car
Lake
Piping
Lab Pack Drum ---
6.0 HAZARD ASSESSMENT
The potential for exposure to site personnel at the NCSU.site is dependent on the particular task involved. Tasks include excavation and waste characterization, geophysics, soil sampling, soil boring, monitoring well installation, and ground water sampling.
The excavation activity task is the most hazardous task planned. In this task, a backhoe will be used to carefully reveal the contents of the buried waste. Potential exists for exposure to metals, alcohols, ketones, aldehydes, acids, phenolics, pesticides, amines, polynuclear aromatic hydrocarbons (PNAs), halogenated solvents, and other miscellaneous organic compounds.· Some of those chemicals are known carcinogens (i.e., benzidene), extremely flammable (i.e., ethyl ether), or extremely toxic (i.e., cyanide compounds). The excavation task will be subcontracted to a firm specializing in this type of
8
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
QA.7/REM-VTBS!A.l
12/31/86
Table 5-1. Representative List of Chemicals Included in Waste Burials
Chemical
Aliphatic Alcohols
1-butanol
2-chloroethanol
ethanol
dihydroxypropane
ehtylene glycol
isopropanol (propyl alcohol)
methanol
2-methyl-1-propanol (propyl alcohol)
pentanol
2-pentanol
propanol (propyl alcohol)
2-propanol (propyl alcohol)
Misceilaneous Solvents
ethyl benzene
acetonitrile
benzene
cyclohexane
1,4-dioxane
ether
ethyl. acetate
ethyl ether
heptane
hexane
iso-octane (octane)
nitrobenzene
pentarie
pyridine
tetrahydrofuran (THF)
toluene
p-xylene
Inorganics
aluminum
antimony
arsenic
boron
bromine (bromide)
cadmium
chloride (chlorine)
cobalt
copper
chromium
cyanide
fluoride
9
Threshhold Limit
Value (TLV)
mg/m3
305.0
3.0
1,900.0
250.0
24.0 soo.o
260.0 soo.o
500.0
soo.o
435.0
70.0
30.0
1,050.0
1,400.0
1,200.0
1,600.0
180 .o
1,450.0
5.0
1,800.0
15 .o
590.0
375.0
435.0
10.0
0.5
0.2
3.0
0.7
0.05
3.0
0. 1
1.0 o.s
0.5
2.5
I
I
I
I
I
I
I
I
,I
'
·1
I
I
I
I
I
:I
I
I
QA.7/REM-VTB51A.2
'12/31/86
Table 5-1. Representative List of Chemicals Included in Waste Burials
(Continued, Page 2 of 5)
Chemical
Inorganics
iodine (iodide)
iron
lead
lithium (hydride)
magnesium (oxide)
manganese
mercury
molybdenum
nickel
phosphorus
potassium
selenium
silver
sodium
strontium
sulfur
thallium
tin
titanium
zinc
Ketones
acetone
2-butanone
methyl ethyl ketone
4-methyl 2-pentanone
2-pentanone
Aldehydes
ace taldehyde
benzaldehyde
formaldehyde
Bases
potassium.hydroxide
sodium hydroxide
Oxidants
benzoyl peroxide
hydrogen peroxide
potassium permanganate
Threshhold Limit
. Value (TLV)
mg/m3
1.0
1.0 o. 15
0.025
10.0
5.0
0. l
5.0
0. 1
0.1
2.0
0.2
0.01
0.1
2.0
15 .o
5.0
1,780.0
590.0
590.0
700.0
180.0
1.s
2.0
2.0
s.o 1.s
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
QA.7/REM-VTB51A.3
12/31/86
Table 5-1. Representative List of Chemicals Included in Waste Burials
(Continued, Page 3 of 5)
Chemical
Miscellaneous Organics
acenapthene
acrolein
acrylonitrile
2-chloroethyl ether
di-n-butylphthalate
2--methylbutane
4--methylpent-1-ene
nitromethane
nitrotoluene
styrene
p-toluidine
trioxymethylene
diethyl ether
Acids
acetic acid
benzoic acid
boric acid
chloroacetic acid
chromic acid
2-5-dinitrobenzoic acid
formic acid
hydrochloric acid
hydrofluoric acid
mercaptoacetic acid
mercaptoproprionic acid
nitric acid
osmic acid
perchloric acid
phosphoric acid
picric acid
proprionic acid
s uc cinic acid
sulfuric acid
thioacetic acid
thioproprionic acid
tribromoacetic acid
trichloroacetic acid
trifluoroacetic acid
Phenols
p-chlorophenol
2,4-dinitrophenol
p-n!°trophenol
phenol
phenolphthalein 11
Threshhold Limit
Value (TLV)
mg/m3
0.25
4.5
250.0
11.0
215.0
1,200.0
25.0
0. l
9.0
7.0
2.5
5.0
l .0
0. l
30.0
1.0
7 .o
1.0
1.0
1.0
19.0
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
QA.7/REM-VTB51A.4
12/31/86
Table 5-1. Representative List of Chemicals Included in Waste Burials
(Continued, Page 4 of 5)
Chemical
Pesticides/Herbicides/Fungicides
atrazine
carbofuran
2,4-D
DDE
DDT
endrin
ethylene dibromide
malathion
methoxychlor
parathion
sevin
toxaphene
Amines
bisacrylamide
aniline
N-butylamine
dibutylamine
diethylamine
N,N-dimethyl formamide (DMF)
diphenylamine
N,N-diphenyl-p-phenylene-diamine
dipropylamine
ethylenediamine
N-propylamine
tetraethylene diamine
tributylamine
triethylamine
trimethylamine
Halogenated Hydrocarbons
bromobenzene
bromoethane
carbon tetrachloride
chlorobenzene
2-chloro-2-methylpropane
chloroform
1,2-dibromoethane
1,2-dichloroethane
dichloroethane
2,4-dinitrochlorobenzene
ethylene bromide
methylene chloride
perchloroethylene
12
Threshhold Limit
Value (TLV)
mg/u,3
5.0
0. 1
10.0
1.0
1.0
0.1
0. 1
10.0
10.0
0.1
5.0
0.5
0.3
10.0
15.0
14 .o
30.0
30.0
10 .o
0.1
5.0
25.0
5.0
1.0
15.0
40.0
24.0
5.0
5.0
30.0
350.0
10.0
50.0
14.0
790.0
810 .o
1.0
890.0
350.0
335.0
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
QA.7/REM-VTB51A.5
12/31/86
Table 5-1. Representative List of Chemicals Included in Waste Burials
(Continued, Page 5 of 5)
Chemical
Halogenated Hydrocarbons
tetrachloroethane
tetrachloroethylene
trichlorobenzene
trichloroethylene
dichloromethane--1,2-dichloro-
propane
1,1,1-trichlorethane (methyl
chloroform)
PAHS (polycyclicaromatic hydrocarbons)
benzidine
biphenyl
bromonapthalene
chloronaphthalene
chrysene
napthalene
phenanthrene
Note: mg/m3 • milligrams per cubic meter.
• not available.
Source: ESE, 1986.
13
Threshhold Limit
Value (TLV)
mg/m3
335.0
7.0
40.0
270 .o
40.0
1,900.0
1.5
1.0
10.0
10.0
5.0
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
C-REMNCSU.1/HASP.7
12/31/86
activity. Included in the excavation task is limited character-
ization of the types and integrity of waste containers .. This
activity will be performed by the subcontractor. The subcon-
tractor will submit a separate safety plan the excavation and
characterization activites to be reviewed by ESE and the Ebasco
Zone Project Management Office (ZPMO). Activities will require
the use of, as a minimum, full Level c personal protection.
Level B capabilities will be available should monitoring
indicate the necessity to upgrade.
Other activities present hazards from the same group of
compounds, but to a lesser degree based on less disturbance of
buried materials. Splashing of contaminated ground water
directly on skin or breathing volatilized organic compounds are
two sources of exposure.
The overall hazard for the site is moderate, with the excavation
activity ranging from moderate to high. The potential for
chemical burns (corrosives) and fire (flammables) is also
present, especially during excavation activities.
14
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
7.0 TRAINING
7.1 BASIC TRAINING REQUIRED
C-REMNCSU.1/HASP.8
12/31/86
Completion of the fundamental REM III Hazardous Waste Training
Program is required for all employees who will perform work at
the NCSU site. Requirements of the latest training regulations
for hazardous waste site activities will be implemented.
7.2 SITE-SPECIFIC TRAINING
Training will be provided that will specifically address the
activities, procedures, monitoring, and equipment for the site
operations. It will include site and facility layout, hazards,
and emergency services at the site, and will detail all
provisions contained within this HASP. This training will also
allow field workers to clarify anything they do not understand
and to reinforce their responsibilities regarding safety and
operations for their particular activity.
7.3 SAFETY BRIEFINGS
Project personnel will be given briefings by the HSO or designee
on a daily or as-needed basis to further assist site personnel
in conducting their activities safely. It will be provided when
new operations are to be conducted, changes in work practices
must be implemented due to new information made available, or if
site or environmental conditions change. Briefings will also be
given to facilitate conformance with prescribed safety
practices, when conformance with these practices is not being
followed, or if deficiencies are identified during safety
audits.
7.4 FIRST AID AND CARDIO-PULMONARY RESUSCITATION (CPR)
The CHSS will identify those
in order to ensure emergency
activities. At least one of
first-aid and CPR training.
with the requirements of the
individuals requiring this training
treatment is available at field
the field team members will have
These courses will be consistent
American Red Cross Association.
15
I
I
I
I
I
I
I
I
I
I
I
D
n
I
I
I
I
I
I
8.0 ZONES, PROTECTION, AND COMMUNICATION
8.1 SITE ZONES (see Figure 8-1)
C-REMNCSU.1/HASP.9
12/31/86
The site is surrounded by a chain-link fence with a gate located
near the southwest corner. The fence, a good physical barrier,
will serve as the location of the hot line, except in the gate
area immediately adjacent to the fence which will serve as a
decontamination zone. The gate is the controlled access point
through which field personnel will pass during site entry and
exit.
8.2 PERSONAL PROTECTION
8.2,l General
Level B protection will consist of hooded Saranex® coveralls,
chemical-resistant steel toe boots and latex boot covers,
chemical-resistant outer Solvex® gloves and inner latex gloves,
and a full-face pressure demand air supplying respirator. The
joints between the coveralls and boots and gloves will be sealed
with duct tape. In addition, hard hats will be worn in the
vicinity of all drilling operations.
Level C protection will consist of Saranex® coveralls,
chemical-resistant boots and latex boot covers,
chemical-resistant outer gloves (Solvex®) and latex inner
gloves, and a full-face air purifying respirator (APR) with
organic vapor and high-efficiency particulate absolute (HEPA)
cartridges. The joints between the coveralls and boots and
gloves will be sealed with duct tape. In addition, hard hats
will be worn in the vicinity of all drilling operations.
If breathing zone measurements with the HNU PID consistently
indicate concentrations greater than 5 parts per million (ppm),
field team members .. must upgrade to Level B or. further define the
organic vapor.constituents with detector tubes or other
methods. HCN concentrations above 10 ppm also warrant upgrading
to Level Bas measured by the Monotox® HCN detector.
Combustible gas concentrations greater than or equal to
25 percent of the lower explosive limit will warrant site
evacuation until the source can be located and eliminated.
Task Level of Protection
Geophysical Survey
Excavations--onsite
Soil Sampling--onsite
Soil Sampling--offsite
Soil Borings--onsite
Soil Borings--offsite
Wells--offsite
16
*modified
Level C/B
Level C
*modified
Level C/B
*modified
•modified
Level D
Level D
Level D
Level D
.....
-..J
- - - - - - --I!!!!!!!! 1!!111 -liiiii iiiii - - ' - - - -
HOT LINE
FORMER 55 GAL.
DRUM STORAGE
SUPPORT ZONE
Figure 8-1
SITE WORK ZONES
SOURCE: ESE, 1986.
/
1-40 (WADE AVENUE EXTENSION)
290'
• \
RIGHT OF WAY
1· STONE
,-
\.
\.
\.
/
/
/
/
COMMAND
POST~
\.
\.
'\
/
/
KEY:
CRC CONTAMINATION REDUCTION CORRIDOR
FOR DECONTAMINATION PROCEDURES
FORMER CHEMICAL
STORAGE DUMPSTER
NOT
TO
SCALE
ENVIRONMENTAL SCIENCE
AND ENGINEERING, INC.
I
I
I
I
I
I
I
R
I
I
I
I
I
I
I
I
I
I
C-REMNCSU.l/HASP.10
. 12/31/86
Waste characterization after excavation
Ground Water Sampling--offsite
Level C/B
•modified Level D
•Includes chemical-resistant clothing
(Tyvek®), chemical-resistant gloves and
boots, eye/head protection for
drillings, and full-face APR available
for emergency.
8.2.2 Safety Equipment
Basic emergency and first-aid equipment will be available at the
onsite trailer (command post). This will include portable
radios, first-aid kit, emergency eyewash, a.nd fire
extinguishers. The command post will be manned during all
Level C (or higher) activities. When teams are downrange during
these activities, communications will be maintained, and
personnel will be available to assist in decontamination
procedures for personnel and equipment.
A wind sock or other wind direction instrument will be available
in the event ·emergency evacuation becomes necessary.
Air monitoring equipment includes use and calibration of an HNU
No. 101 photoionizati6n detector (PID) for organic vapors, a
Monotox® HCN detector, a Monitor 4® radiation alert meter, and
an MSA® combustible-gas indicator.
8.3 COMMUNICATIONS
0
0
0
Portable Radios--Hand-held units will be utilized as
much as possible by field teams for communication
between downrange operations and the command post base
station.
Telephones--Due ,to the distance to the nearest phone
line, a phone will not be available in the command
post. However, a public phone is located at
Carter-Finley Stadium, approximately 0.25-mile from the
site.
Hand signals--Hand signals will be employed by
downrange field teams along with utilizing the buddy
system. These signals are also very important when
working with heavy equipment. The signals shall be
known by the entire field team before operations
commence and will be covered during site-specific
training.
Weather reports will be ob'served each morning and periodically
during the day to anticipate inclimate weather and the resulting
precautions to be taken.
18
I
I
I
I
I
I
I
n
D
I
I
I
I
I
I
I
I
I
9.0 MONITORING PROCEDURES
9.1 MONITORING DURING SITE OPERATIONS
9.1.1 Drilling Operations
C-REMNCSU.l/HASP.11
12/31/86
Monitoring will be performed continuously by the HSO during the
conduct of work. A PID will be utilized to monitor the
breathing zone, the borehole, and all geological samples upon
their retrieval. Drill cuttings will also be monitored. A
combustible-gas indicator with an oxygen alarm will be used to
monitor the borehole for the presence of combustible gases.
Similar monitoring of any fluids produced during well
development will also be conducted.
9.1.2 Excavation Operations
Monitoring will be performed continuously during all excavation
and sampling operations. A PID will be utilized to monitor the
breathing zone, the excavated area, and any material taken from
an excavation. The excavation will be monitored with a CGI and
oxygen meter.
9.1.3 Other Operations
Soil and well sampling will include continuous monitoring at.
breathing -zone height and at the well head upon opening.
9.2 MEDICAL SURVEILLANCE PROCEDURES FOR EVIDENCE OF PERSONAL
EXPOSURE
All REM III personnel and subcontractors who will be performing
field work at the NCSU site will be required to have passed a
REM III medical surveillance examination or the equivalent. A
release for work will be confirmed by the ESE CHSS before an
employee can begin hazardous site activities. The exam will be
conducted annually (at a minimum) and upon termination of REM
III work. Additional medical testing may be required by the ESE
CHSS in consultation with the company physician and the HSO if
an overt exposure or accident occurs or if other site conditions
warrant further medical surveillance.
19
I
I
I
I
I
I
I
I
n
D
I
m
I
I
I
I
I
I
I
C-REMNCSU.l/HASP.12
12/31/86
10.0 SAFETY CONSIDERATIONS FOR SITE OPERATIONS
10.l GENERAL
All field sampling will be performed under the level of·
protection described in Section 8.0.
All onsite activities shall be limited to daylight hours and
normal weather conditions. Inclimate weather includes extremes
in temperature, wind, rain, and lightning. Wind direction will
be observed periodically. In the event emergency evacuation is
necessary, site personnel will exit the site.
Personnel entering the site shall observe the buddy system at
·all times and enter through the access control point. No
smoking, eating, or drinking will be allowed onsite or before
personal decontamination. Personnel will keep hands, tools,
samples, and equipment away from face and exposed skin.
Team members will maintain visual contact with one another and
will be familiar with hand signals.
20
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
11.0 DECONTAMINATION PROCEDURES
C-REMNCSU.l/HASP.13
. 12/31/86
All personnel and equipment exiting the exclusion zone shall be
thoroughly decontaminated.
11.1 LEVEL BAND C DECONTAMINATION (MODIFIED LEVEL D--OMIT
STATION 15)
Equipment Worn
The full decontamination procedure outlined is for workers
wearing Level Band C protection (with taped joints between
gloves, boots, and suit). Such protection consists of:
1. One-piece, hooded, chemical-resistant splash suit,
2. Full-face supplied air respirator,
3. Hard hat (drilling operations),
4. Chemical-resistant boots with steel toe and shank,
5. Boot covers, and
6. Inner and outer gloves •
•
Procedure for Full Decontamination
Station 1: Segregated Equipment Drop
Deposit equipment used on the site (tools, sampling devices and
containers, monitoring instruments, radios, clipboards, etc.)
on plastic drop cloths or in different containers with plastic
liners. Each will be contaminated to a different degree.
Segregation at the drop reduces the probability of
cross-contamination.
Equipment necessary is:
1. Containers of various sizes,
2. Plastic liners, and
3. Plastic drops cloths.
Station 2: Boot Cover and Glove Wash
Sc:r:ub outer boot covers and gloves with detergent/water
solution.
Equipment necessary is:
1. Container (20 to 30 gal),
2. Detergent/water solution,
3. Two or three long-handle,
brushes.
21
and
soft-bristle scrub
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Station 3: Boot Cover and Glove Rinse
C-REMNCSU, 1/HASP. 14
12/31/86
Rinse off detergent water solution from Station 2 using copious
amounts of water.
Equipment necessary is:
l. Container (30
2. High-pressure
3. Water, and
4. Two or three
brushes.
Station 4: Tape Removal
to 50 gal),
spray unit,
long-handle, soft-bristle scrub
Remove tape around boots and gloves and deposit in container
with plastic liner.
Equipment necessary is:
1.
2.
Container (20 to 30 gal), and
Plastic liners.
Station 5: Boot Cover Removal
Remov~ boot covers and deposit in container with plastic liner.·
Equipment necessary is:
1.
2.
3.
Container (30 to 50 gal),
Plastic liners, and
Bench or stool.
Station 6: Outer-Glove Removal
Remove outer gloves and deposit in container with plastic liner.
Equipment necessary is:
l.
2.
Container (20 to 30 gal), and
Plastic liners.
Station 7: Suit/Safety Boot Wash.
Thoroughly wash splash suit and safety boots, respirator, and
regulator assembly. Scrub with long-handle, soft-bristle brush
and copious amount of detergent/water solution. Repeat as many times as necessary.
22
I
I
I
I
I
I
I
I
I
I
11
I
I
I
I
I
I
I
I
Equipment necessary is:
1. Container (30 to 50 gal),
2. Detergent/water solution, and
C-REMNCSU.l/HASP.15
. 12/31/86
3. Two or three long-handle, soft-bristle scrub
brushes.
Station 8: Suit/Safety Boot Rinse
Rinse off detergent/water solution using copious amounts of
water. Repeat as many times as necessary.
Equipment necessary is:
1. Container (30
2. High-pressure
3. Water, and
4. Two or three
brushes.
to 50 gal),
spray unit,
long-handle, soft-bristle scrub
Station 9: Cartridge or Air Change
If workers leave Exclusion Zone to change cartridges (or air
supply), this is the last step in the decontamination
procedure. Worker's cannister is exchanged, new outer glove and
boot covers donned, and joints taped. Worker returns to duty.
Equipment necessary is:
1. Canister (or mask),
2. Tape,
3. Boot covers, and
4. Gloves.
Station 10: Safety Boot Removal
Remove safety boots and deposit in container with plastic. liner.
Equipment necessary is:
1.
2 •.
3.
4.
Container (30 to 50 gal),
Plastic liners,
Bench or stool, and
Boot jack.
Station 11: Splash Suit Removal
With assistance of helper, remove splash suit. Deposit in
container with plastic liner.
23
I
I
.I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
. ··-.. -••·•· -.
Equipment necessary is:
1, Container (30 to 50 gal),
2. Bench or stool, and
3. Plastic liner.
Station 12: Supplied Air Equipment Removal
C-REMNCSU.l/HASP.16
12/31/86
While still wearing facepiece, remove regulator and belt
assembly and place on designated area. Proceed to next station.
Station 13: Inner-Glove Wash
Wash inner gloves with detergent/water solution that will not
harm skin. Repeat as many times as necessary.
Equipment necessary is:
1, Detergent/water solution and
2. Basin or bucket.
Station 14: Inner-Glove Rinse
Rinse inner gloves with water. Repeat as many times as
necessary.
Equipment necessary is:
l. Water,
2, Basin or bucket, and
4. Small table.
Station 15: Facepiece Removal
Remove facepiece. Avoid touching face with gloves.
facepiece in container with plastic liner.
Equipment necessary is:
l.
2.
Container (30 to 50 gal) and
Plastic liners.
Station 16: Inner-Glove Removal
Deposit
Remove inner gloves and deposit in container with plastic liner.
Equipment necessary is:
1. Container (20 to 30 gal) and
2. Plastic liners.
24
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I I
!
Station 17: Inner-Clothing Removal
C-REMNCSU.l/HASP.17
12/31/86
Remove clothing soaked with perspiration. Place in container
with plastic liner. Do not wear inner clothing offsite since
there is a possibility small amounts of contaminants have been
transferred in removing fully encapsulating suit.
Equipment necessary is:
l. Container (30 to 50 gal) and
2. Plastic liners.
Station 18: Field Wash
Shower as soon as possible.
Equipment necessary is:
l. Water,
2. Soap,
3. Tables,
4. Wash basins or buckets, and
5. Field showers.
Station 19: Redress
Put on clean clothes. A dressing trailer is needed in inclement
weather.
Equipment necessary is:
l.
2.
3.
4.
Tables,
Chairs,
Lockers, and
Clothes.
25
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
12.0 DISPOSAL PROCEDURES
C-REMNCSU.l/HASP.18
12/31/86
All discarded materials, waste materials, or other objects shall
be handled in such a way as to preclude the potential for
spreading contamination, creating a sanitary hazard, or causing
litter to be left onsite. All potentially contaminated
materials (e.g., clothing and gloves) will be bagged or drummed
as necessary and segregated for disposal. All contaminated
waste materials shall be disposed of as required by the
provisions included in the contract and consistent with REM III
and regulatory provisions. All noncontaminated materiais shall
be collected and bagged for appropriate disposal as normal
domestic waste.
All wastes produced during decontamination of equipment and
personnel will be contained and drummed onsite until further
arrangements can be made.
26
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
. -.-·-· ; .. -
13.0 EMERGENCY PLAN
C-REMNCSU.l/HASP.19
12/31/86
As a result of the hazards at the site and the conditions under which operations are conducted, the possibility of an emergency situation developing is real.
The Site Emergency Coordinators are:
Field Operations Leader
HSO (Alternate)
Al Quarles
Dan Endicott
The emergency coordinator will implement the plan outlined below whenever conditions at the site warrant such action. The coordinator is responsible for assuring the ev.acuation, emergency treatment, emergency transport of site personnel as necessary, notification of emergency services, and appropriate management staff.
13.1 EVACUATION
In the event of an emergency situation (e.g., fire, explosion, . or significant release of toxic gases), an air horn or other appropriate device will be sounded for approximately 10 seconds, indicating the inititation of evacuation procedures. All personnel in both the restricted and nonrestricted areas will assemble upwind in the support Zone. The location shall be upwind of the site as determined by the wind direction indicator. For efficient and safe site evacuation and . assessment of the emergency situation, the Emergency Coordinator will have authority to initiate proper action if outside services are required. Under no circumstances will incoming personnel or visitors be allowed to proceed into the area once the emergency signal has been given. The HSO or HSO Designee must see that access for emergency equipment is provided and that all sources of ignition have been shut down once the alarm has been sounded. Once the safety of all personnel is established, the Raleigh Fire Department and other emergency response groups will be notified by telephone of the emergency.
13.2 POTENTIAL OR ACTUAL FIRE OR EXPLOSION
In case of potential or actual fire or explosion, all personnel will immediately evacuate the site (air horn will sound for 10-second intervals). Notify loca.l fire and police department and other appropriate emergency response groups if lower explosion level (LEL) values are above 25 percent in the work zone or if an actual fire or explosion has taken place.
Fire Dept. --911
Police Dept .. --911
27
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
C-REMNCSU,l/HASP.20
12/31/86
13.3 ENVIRONMENTAL INCIDENT
I
In the event of an environmental incident, control or stop
spread of contamination if possible. Notify the U.S. Coast
Guard Response Center and local authorities of possible
evacuation of ·immediate area. Notify Site Manager, CHSS
Regional Manager, and USEPA emergency response groups.
13. 4 PERSONNEL INJURY
Emergency first aid shall be performed onsite as deemed
necessary. The individual will be decontaminated and trans-
ported to Rex Hospital, if necessary. The HSO will supply
medical data sheets to appropriate medical personnel and
complete the incident report designated in HS-1.12.
Hospital--(919) 755-3100
Rescue --911
The ambulance/rescue squad shall be contacted for transport as
necessary in an emergency. During the initial reconnaissance, a
primary hospital and backup facility were located. A detailed
route to and from the site is shown in Figure 13-1. The:
hospital route location map shall be conspicuously posted at the
site command post.
Primary Hospital Route:
Take Old Trinity Road East to Blue Ridge Road North. Go north
on Blue Ridge Road approximately 1.5 miles to Rex Hospital at
4420 Lake Boone Trail.
13.5 OVERT PERSONNEL EXPOSURE
SKIN CONTACT:
INHALATION:
INGESTION:
Use copious amounts of soap and water.
Wash/rinse affected area thoroughly, then
provide appropriate medical attention.
Eyewash and emergency shower or drench
system will be provided onsite at the CRZ
and/or Support Zone as appropriate. Eyes
should be rinsed for 15 minutes after
chemical contamination.
Move to fresh.air and/or, if necessary,
decontaminate and transport to hospital.
Decontaminate and transport to emergency
·medical facility
28
I
I
I
I
I
I
I
I
I
I
I
I
I
:I
I
I
I
I
I
REM/I/ NCSU 12AMM
---' . ..J , , ,,
:~ .. . '· ...
Figure 13-1
, .
HOSPITAL ROUTE MAP
SOURCE, ESE. , ....
29
I -.22A
-~ ........ c,m ,::.;.._..,
ENVIRONMENTAL SCIENCE
AND ENGINEERING, INC.
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
··• ..
I
I
I
PUNCTURE WOUND
C-REMNCSU.l/HASP.21
12/31/86
OR LACERATION: Decontaminate and transport to emergency
medical facility. HSO will provide medical
data sheets to medical personnel as
requested (see Section 14.0).
Hospital--(919) 755-3100
Rescue --911
National Poison Control Center--1(800) 822-9761
13.6 ADVERSE WEATHER CONDITIONS
In the event of adverse weather conditions, the HSO will
determine if work can continue without sacrificing the health
and safety of field workers. Some of the items to be considered
prior to determining if work should continue are:
0
0
0
0
0
Potential for heat stress and heat-related injuries,
Potential for cold stress and cold-related injuries,
Treacherous weather-related working conditions,
Limited visibility, and
Potential for electrical storms.
30
I
.I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
14.0 AUTHORIZATIONS
C-REMNCSU.l/HASP.22
12/31/86
Personnel authorized to enter the NCSU site while operations are being conducted must be certified by the ESE CHSS. Authori-zation will involve completion of appropriate training courses, medical examination requirements, and review and sign-off of this HASP. All personnel must utilize the buddy system or trained escort, and check in with the Field Team Leader at the command post.
1. ESE Personnel Authorized to Perform Work onsite:
2.
1. Carolyn Poppell
2. Al Quarles
3. Leonard carter
4. Charles Haury
5. Dan Endicott
6. Kevin Gara
7. Perry Brake
8.
9.
10.
11. _____________ _
12. ______________ _
13 14. _____________ _
15. ______________ _
16 ·--------------17 • _____________ _
18 ·--------------19 , ______________ _
20. --------------
Other Personnel Authorized to Enter Site:
1.
2.
3.
4.
5.
ZPMO Personnel
REM III Regional
Personnel
EPA Personnel
State Environmental
Personnel
Police Fire
Emergency Personnel
31
6. Technos Personnel
7. Drilling Subcontractor
Personnel
8. Excavation Subcontractor
Personnel
9. Site Survey Subcontractor
Personnel
10. Waste Disposal Transport
Personnel
I
I
I
I
I
.1
I
I
I
I
I
I
I
I
I
I
I
I
I
15,0
Medical Data Sheet and Field Team Review
Thia brief Medical Data Sheet will be completed by all ons'ite
personnel and will be kept in the Co!l'U'l\and Post durhiq. , the
conduct of site operations. Completion is required in addition
to compliance with the Medical Surveillance Program requirements
described in the REM III Program Health and Safety Plan. This
. data aheet will accompany any personnel when medical assistance
ia needed or if transport to hospital facilities is required.
Project . fS
Name ...L.."'-1..l/.!.µ.~~-'-:f.R.~L---Home Telephone {9t)L.f-) 37?-776?
Address P ... <., Gr:,',.L,svi1lt,, [L
Aqe ~ 33 Heiqht S 1 t 1' Weiqht _,_-'Lf-0....:;;.,. ____ _
Name of Next of U.n Sil-\. Gr-1,~d f-. .,.;,..i 1i_,,,_,:s (2J'f Z-62.·7W3
Druq or other Allerqies
Particular Sensitivities Nir,,µ ..;:...:.., _________________ _
Do You Wear Contacts? _._~_5 ___________________ _
Provide a Checklist of Previous Illnesses or Exposures to Hazardous Chemicals ~M~~:..;.::::;_ ___________________ _
What medications are you presently using? _M_~ _________ _
Do you have any medical restrictions? ~N.:..;.o _________ ~~-
Name, Address, and Phone Number of personal physician:
f,,Jw,l., t r ,:,.. f-G..,t.. Gi~x-
--------=================================-=--=============-======
I am the individual described above. I have read and understand thith:~
' Date
32
I
I
.1
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Medical Data Sheet and Field Team Review
Thia brief Medical Data Sheet will be completed by all onsite personnel and will be kept in the Command Post during the conduct of site operations. Completion is required in addition to compliance with the Medical Surveillance Program requirl!Il\ents described in the REM III Program Health and Safety Plan.· This data aheet will accompany any personnel when medical assistance i• needed or if transport to hospital facilities is requi-red.
Project 4({'. 5"f,.,1'. k',,, ',,,ere'ly
> Name /1(,'//:,v,, ,4 l~e, f 0"'", /,,.s Home Telephone 9'15-93</3
Address ~:2 1.:.,., Oa. k L,.,,,t! 4~d,,t:, FL 3;;;,618
Age cl 6 Height S' ' 9' ,., Weight _,i.(_-s✓~o ____ _ Name of Next of JU.n zt1a ,y f'a-lnre, 42,,_,., le, {-· +c) > Drug or other Allergies
Particular Sensitivities
Do You Wear Contacts? ___ M'-"-"D _________________ _
Provide a Checklist of Previous Illnesses or Exposure• to Hazardous Chemicals ______________________ _
What medications are you presently using? _M'-'--'o~n~s:;.._.. ______ _
Do you have any medical restrictions? -~o:::._ ________ .:__
Name, Address, and Phone Number of personal physician:
Ed~.,/ fl«ns•'.:;t-er Mt) ?/? , ,
7R,£ S w fJ• d ttv,;
----------=-================-=============--=========-==========
I am the individual described above. thia HASP,
33
I have read and understand
1 Date
II
II
II
I
I
I
I
I
I
I
I
I
I
I
Medical Data Sheet and Field Team Review
Thia brief Medical Data Sheet will be completed by all onsite
personnel and will be kept in the Command Post durinq the
conduct of site operations. Completion is required in addition
to compliance with the Medical Surveillance Program requirements
described in the REM III Program Health and Safety Plan. This
data sheet will accompany any personnel when medical assistance
is needed or if transport to hospital facilities is required.
' I ,,, ,•f . .: // :.i.
1 : ' '. . ._;-<.A_J. vi.,_./ (..o...(,,__, 7,_
Name ""-~;:(/
Address (,,_ io _5:.....: s-1--'-7'f
Age ,2$'" Heiqht S-' /C ,, Weight
Name of Next of !Un __.4.,_t_.q __ .).....,,r-~---"--~. __ ,_""':'""'·( _____________ _
Drug or other Allergies -~j_/~,~-"~-----------------
Particular Sensi ti vi ties /'..,,:-"-t. --'---~-'------------------
Do You Wear Contacts?
Provide a Checklist of Previous Illnesses or Exposures to
Hazardous Chemicals-~/~/~,~,~~~------------------
What medications are you presently using? ,t)f:Cf
Do you have any medical restrictions?
Name, Address, and Phone Number of personal physician:
·;; I /,, __ ..-4-,_ , ,., -
·;, ''( /'{L.., ◊ l.,vl.:QC::r,-{ I ,• : -_.?. .,-;f'.,;._
I ---------==-==-===========================--===-================
I
I
I
I
I am the individual described above. I have read and understand
this HASP.
1.-~ ~1-1 / "/2 (j le:,,,
Signature Date
34
11
I
I
I
I
I
I
I
I
I
I
:1
I
I
·I
I
C-REMNCSU.l/HASP.24
12/31/86
16.0 FIELD TEAM REVIEW
Each field team member shall sign this section after
site-specific training is completed and before being
permitted to work on site.
I have read and understand this site-Specific Health and Safety
Plan. I will comply with the provisions contained therein.
Site/Project:
Name Printed Signature Date
•
35
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
17.0 APPROVALS
C-REMNCSU.l/HASP.25
12/31/86
By their signature, the undersigned certify that this HASP is
approved and will be utilized at the NCSU Lot 86 site.
CC)r hr Oa,. £ .. d,~_,.;f
Health and Safety Officer
Company Health and Saf
Supervisor
Company Designated✓Lead
// --
REM III Health and Safety
Manager
36
Date
Date
Date
Date