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HomeMy WebLinkAboutNCD980557656_19861216_NC State University (Lot 86 Farm Unit 1)_FRCBERCLA RI_Draft Work Plan Remedial Investigation and Feasibility Study-OCRI·- I I I I I I I 11 I I I I I I I I I :I EPA l'QU{ ASSIGNMENl' NO. 64-46G7 UNDER EPA CXNffiACl' NO. 68-01-7250 EBASCD SERVICES INCDRroRATED DRAFT l'QU{ PIAN RDIEDIAL INVESTIGATICN AND FFASIBILI'IY S'lUDll NORIH CAROLINA STATE UNIVERSI'IY Im 86 SITE :AAIEIGH, NORIH CAROLINA JANUARY 1987 NOI'ICE 'Ihe infonnation in this doa.mlent has been fun:led by the United states Enviroranental Protection Agercy (U.S. EPA) urrler RFl'1 III Contract No. 68-01-7250 to El:lasoo Services, Inc. (Ebasoo). '!his document is a draft an1 has not been fonnally released by either Ebasoo or the U.S. EPA. As a draft, this doa.mlent shoold not be cited or quoted, an:i is bein; circulated for OCll1ll'eJ1t only. , ' I I I I I I I I I I I I I I ,, I I I I I WORK ASSIGNMENT: 64-46G7 OJNTAACT NUMBER: 68-01-7250 EBASCO SERVICES IlfCORroRATED DRAFT WORK PIAN IDlEDIAL INVESTIGATION AND FEASIBILITY SIUDY NORIH CAROIJNA STATE UNIVERSITY rm 86 SITE RAIEIGH, NClRIH CAROIJNA JANUARY 1987 P.REPARED BY: CARDIJ:lN F. l'DPPELL SITE MANAGER ENVIR:lNMENTAL SCIENCE AND ENGINEERrnG, me. Approved by: ' L . u".!lc e, :A Russell H. Boyd, Jr., P.E. Regional Manager, Region IV Ebasco Services Incorporated I· I I I I I I I I I I I I I I I I I I . -••'••· --. USEPA w::lRK ASSIGNMENT: 64-46G7 USEPA CDNTRACT NUMBER: 68-01-7250 EPl;S(l) SERVICE.S llio::mroRATED Draft Work Plan Rerre:lial Investigation arrl Feasibility Study North caro1ina State University I.ct 86 Site Raleigh, North carolina January 1987 I I I I I I I :I I I I I I I I I I I TABlE OF Cl:lNI'ENIS Section C-Rffl'ICSU2,IWP.IDC.1 12/16/86 EXEOJI'IVE SUMMARY Page vi 1.0 2.0 3.0 4.0 JNl'ROCUCTIOO SUMMARY OF EXISTING D.ATA 2 • 1 SITE HISroRY 2.1.1 Site status 2. 2 SITE DESCRIPI'ICN 2.2.1 Toµ,.Jtaphy, SUrface Water. and Drainage 2.2.2 Hydrcgeolc:gy and Soils 2.2.3 Climate 2.2.4 Population and Environmental Resources 2.2.5 Clemical Characterization of Site SCOPlliG OF RI/F'S 3. l RI/FS OBJECITVES 3.1.l Preliminary Risk Assessment 3. 1. 2 Risk Assessment Data Gaps 3.1.3 Scopioo of Remedial Alternatives 3. 2 IDENI'IFICATICN. OF D.ATA ~ 1 4 4 10 11 11 11 14 17 25 25 28 33 34 39 3.2.1 Determination of ARAR 39 3.2.2 CQO Determination 43 3.3 SO'.)PING OF NCSU IJJr 86 SITE REMEDIAL INVESTIGATICN 47 3.3.l SUbsurface Soils 48 3.3.2 SUrface Soils 49 3.3.3 Ground Water 49 3.3.4 other Tasks 50 TASK PIAN FOR REMEDIAL INVESTIGATION 52 4. 1 PROJECT PlllNNING (TASK 1) 52 4.2 C01MlJNITY RELATIONS (TASK 2) 54 4. 3 FIEID INVESTIGATIONS (TASK 3) 54 i I I I I I I I I I I I I I I I I I ·1 I Section 5.0 C-REl1NCSU2jWPIOC. 2 1.2/22/86 TABI.E OF a::Nl'ENI'S (Continued, Page 2 of 3) 4.3.1 Preparation of Bid Specifications an::l Subcontractor Pr=urement (SUbtask 3-ll 4.3.2 Site SUrvey (SUbtask 3-2) 4.3.3 Records Search (SUbtask 3-3} 4.3.4 DiSPOSal Trench Delineation an::l Waste Oiaracterization (SUbtask 3-4) 4.3.5 Soil Investigation (SUbtask 3-5) 4.3.6 Ground Water Investigation (SUbtask 3-6) 4. 4 SAMPIE ANAUiSIS AND D,"\TA VALffil\TICN (TASK 4) 4.4.1 Monitoring Well Sample Analysis 4.4.2 Residential Well Sample Analysis 4.4.3 Surficial Soil Sample Analysis 4.4.4 SUbsurface Soil Sample Analysis 4.4.5 Data Validation 4 • 5 D,"\TA EVlilllATICN (TASK 5) 4. 6 ENDANGERMENT ASSESSMENT (TASK 6) 4. 7 TREATABILITY S'IUDY/Pn.ar TESTING (TASK 7) 4.8 REMEDIAL INVESI'IGATION REroRI' (TASK 8) 54 57 57 58 61 70 76 76 77 77 77 78 79 80 82 83 TASK PI.AN FOR 'THE FEASIBILITY SIUDY 84 5.1. REMEDIAL AlJI'ERNATIVE SCREENING (TASK 9) 84 5.1.1 Development of Remedial Response Objectives 84 5.1.2 Identification of Applicable Technolcpies and Assembly of Alternatives 85 5 .1. 3 Screening of Remedial Technolcpies/ Alternatives 85 5.2 REMEDIAL AilI'ERNATIVES EVlilllATICN (TASK 10) 5.2.1 Technical Evaluation 5.2.2 Risk Assessment 5.2.3 Cost Evaluation 5.2.4 Environmental Assessment 5.2.5 Institutional Requirements 5. 3 FEASIBILITY S'IUDY REroRr (TASK 11) 5.4 :EUST-RI/FS SUProRr (TASK 1.2) ii 86 86 87 88 89 89 90 90 I I I I I I I I I I I I I I I I I Section 6.0 REFERENCES TAfilE OF CXJm'ENIS (Continued, Page 3 of 3) PROJECT' MANAGEMENT' APPRQArn 6 .1 ORGANIZATION AND APrnOACli 6. 2 ~ ASSURANCE AND IYITA MANAGEMENI' 6.3 PROJECT' SClIEDJIE 6.4 DErAIIED COST ESTIMATE C-RD1NCSU2jWPIOC. 3 12/16/86 Page 91 91 93 94 94 APPENDIX A-DRAFT FIEID OPERATICNS PIAN SECI'ION I -DRAFT FIEI.D SAMPLING AND ANALYSIS PIAN SECI'ION II-DRAFT SITE MANAGEMENI' PIAN SECITON III-DRAFT HEAllIH AND SAFEI'Y PIAN iii I I I I ~ I 2-1 I 2-2 I 2-3 I 2-4 I 2-5 I 3-1 3-2 I 3-3 4-1 I 6-1 I I ,. I I I I C-REMNCSU2jWPIDI'F .1 01/08/87 LIST OF TABlES Page Representative List of Chemicals Included in Waste B.Jrials . 7 Nonnal Monthly and Annual Average Te!rperature and Precipitation at NC:SU, Raleigh, North carolina 16 SUmrnary of Q.Jantified Organic Contaminant Concentrations Based on Grourrl Water Sanpling, June 1983 to July 1986 18 SUmrnary of Inorganic Contaminant Concentrations Based on Groun:i Water Sanpling, June 1983 to July 1986 20 Peak O:>ncentrations of Tetrachloroethene, Chlorofonn, and cai:ban Tetrachloride in Grourrl Water 22 Scope of Work for NC:SU RI/FS 26 Relevant and Appropriate Requirerents 42 SUmrnary of Sanple Analyses and Data Quality aJjectives 45 SUbsurface Soil Sanplin3' Locations and Depths 68 RI/FS Tasks and Activities 96 iv I I I I I Figure I 2-1 2-2 :1 2-3 2-4 I 2-5 I 4-1 4-2 I 4-3 I 4-4 6-1 I 6-2 I I I :1 I I I LIST OF FIGURES C-Ril-!NCSU2jWPIDI'F.2 12/22/86 Site I.=ation Map-NCSU Lot 86 5 Monitor:in;, Well I.=ations aro. Waste Disposal Areas 6 General Drainage Patterns in Vicinity of NCSU Lot 86 Site 12 Potentiometric SUrface 15 Plume of Peak Concentrations in Groun::l. Water of Tetrachloroethene, Cltl.oroform, aro. carbon Tetrachloride 23 I.=ation of Geophysical SUl:veys 60 Proposed SUrface Soil Sa:rrple I.=ations 63 Proposed Monitor:in;, Well aro. SUbsurface Soil Sa:rrple I.=ations · 67 'fypical Monitorirg Well Construction 74 Project Organization 92 Project Schedule 95 V I I I I I I I I I I I I I .I I I I I I EXECUI'IVE SUMMARY C-REMNCSU2jEXSUM.l 01/08/87 'Ille :Remedial Investigation/Feasibility sttrly (RI/FS) for the North carolina state University (NCSU) lDt 86 site includes the preparation of project planning reports, subccu1LLa<-tin;J procurement, site investigation, data evaluation arrl risk assessment, arrl evaluation of potential remedial alternatives. 'Ille NCSU lDt 86 site served as a disposal site for chemical arrl low-level radioactive wastes generated in educational arrl research laboratories at NCSU. 'Ille U.S. Environmental Protection Agency (USEPA) Region N has identified NCSU as the sole responsible party. Previous investigations of the site comucted by NCSU identified offsite migration of =ntaminants in ground water. 'Ille results of these investigations indicate the need for additional information =ncernin:J the types arrl volume of waste material buried onsite, levels of =ntamination in ground water arrl soil, arrl current arrl future public health an::l environmental hazards posed by the site. 'Ille proposed RI is designed to evaluate potential health arrl environmental risks arrl to provide the infonnation required to evaluate arrl select renmial alternatives to mitigate such risks. 'Ille RI includes sampling of ground water from existing nonitoring wells arrl one nearby residential well; installation arrl sampling of seven new monitoring wells; geological arrl hydrogeological testing; deep borings to define depth to bedr=lc; definition of waste trerx::hes using geophysical techniques arrl limited excavation; surficial arrl subsurface soil sampling onsite arrl offsite; arrl identification an::l mapping of potential leachate seeps. Records searches will be comucted to determine the types arrl volume of waste disposed onsite arrl the locations arrl =nstruction details of nearby private wells. vi I I I I I I I I I I I I I I I I I I I C-REl1NCSU2jEXSUM. 2 01/08/87 'lhe detaile:i cost SUlI1!l'al'.Y is presented under separate ccver. If tile work is initiated in March 1987 arrl prcgresses as schedule:i, tile RI/FS ca.lld be completed by May 1988 if no Riase II investigation is needed. vii I I I I I I I I I I I :I I I :I :1 'I ,1 •. I 1.0 INTROIUCITON C-Rll!NCSU2/WP1 .1 12/22/86 Envirornrental Science arrl En;Jineerirg, Inc. (ESE), as part of the El:lasco Services Incorporate:i REM III team, is submittirg this Work Plan to the U.S. Envirornrental Protection kJerc:! (USEPA) in response to Work Assigrnnent Number 64-46G7 un:ier Contract Number 68-01-7250. Preparation of this Work Plan was accamplished p.u:suant to the Work Plan Memorarrlum (WH-1) for the North carolina state University (NCSU) IDt: 86 site date:i October 10, 1986, arrl approved by USEPA Region IV on November 5, 1986. Canp Dresser arrl McKee, Inc. (CI:M) prepared a Forward Plannirg Study (FPS) for the NCSU lot 86 site un:ler the USEPA REM II contract (Work Assigrnnent 70-4LG5). ,'Ihe report, date:i August 26, 1985, included a description of the site arrl vicinity, a SUl!U10rY of the history of site operations, arrl a review of the data collected durirg previous site investigations. 'Ihe FPS also identified information deficiencies arrl data gaps as a b3.sis for development of subsequent rerredial investigation (RI) activities. In addition, the study presente:i a preliminary evaluation of rerredial alternatives for the site. 'Ihe FPS has been used as the basis for this Work Plan, supplemented by data obtained recently from NCSU arrl from the site visit perfo:rmed by ESE in October 1986. '.Ille purpose of this Work Plan is.to describe the work that will be perfonned to collect the data needed to define present arrl future health arrl envirornrental risks arrl to evaluate potential rerredial alternatives. '.Ibis Work Plan describes the technical S=!)e arrl presents an estimate:i cost, level of effort (IDE) hours, arrl schedule for the COI1pletion of the RI arrl feasibility study (FS) . '.Ille primary objectives of the NCSU lot 86 site investigation are to: o Locate arrl characterize the wastes disposed onsite to evaluate contaminant migration potential arrl to assess remedial alternatives/technologies relevant to source control. 1 I I I I I I I I I I I I I I I I I I C-RlliNCSU2jWPl.2 12/22/86 o Investigate the nature an:l. extent of groun::l water contaminant migration offsite to determine actual or potential contamination of private water supply wells an:l. surface waters. '.Ihi.s information will be used to evaluate p.iblic health an:l. envirornrental risks arx:l the feasibility of rena:l i aJ alternatives/technologies a:i:med at management of plume migration. o Determine the degree of surficial an:l. subsurface soil contamination onsite an:l. offsite for use in evaluating potential health an:l. envirornrental risks an:l. in evaluating the feasibility of reroodial alternatives/technologies. o Olaracterize geological an:l. hydrogeological parameters for assessment of contaminant fate an:l. transport an:l. evaluation of reroodial technologies. 'Ihe RI is designed to collect data to supplement infonnation previously collected in other investigations an:l. to meet the objectives stated above. Evaluation of reroodial alternatives will be based up:m both new an:l. existing data. 'llle proposed RI will be performed in a single phase, although a limited second-phase investigation may be required if groun::l water an::ljor soil contamination are more widespread than anticipated; however, this Work Plan does not include cost estimates for additional sampling an:l. analysis activities. 'Ihe RI addresses the low-level radioactive disposal area in a limited fashion due to difficulties in accessing NCSU records an:l. data for this area. It is anticipated that these recorqs will be available for examination in the early stages of the RI, at which time the need for additional investigation will be determined. Proposed activities related to the low-level radioactive disposal area include a detailed review of disposal records an:l. 11Pnitoring data (to be provided by NCSU), limited 2 I I I I I I I I I I I I I I I I I I C-RillNC3U2/WPl.3 1.2/22/86 analyses of grourrl water samples for radioactivity, arrl geophysical surveys to delineate the waste disposal trenches. 'lhe prinary focus of the proposed RI/FS is the chemical waste b.Jrial area at the site. Waste disposal trenches will be defined usin;J geophysical techniques with lilnited excavation to determine the disposition of wastes in the trenches. Subsurface soil samples will be =llected adjacent to the trenches to define the depth of soil =ntamination. Groun::l. water samples will be =llected fran existing arrl new oonitorin;J wells on-arrl offsite to define the extent of =ntaminant plume migration arrl potential for =ntamination of offsite private wells. Geological arrl hydrogeological testirg is proposed to describe the potential for contaminant migration (as a basis for the fate an:i transport analysis of the risk assessment) arrl for evaluatin;J the feasibility of remedial alternatives ailned at managenent of =ntaminant migration. Samplin;J arrl analysis of surficial soils onsite arrl offsite is proposed in the Work Plan to determine the extent of =ntamination arrl the potential for =ntaminant migration to potential htman arrl environmental. receptors. 'lhis Work Plan was prepared in a=rdance with USEPA arrl REM III guidelines. 'lhe plan =nsists of six sections, including this Introduction (Section 1.0). Section 2.0 is a surmnary of existing data, including a brief site history arrl site description. Section 3.0 presents the scopin;J of the RI/FS, includin;J the project objectives, a prelilninary risk assessment, prelilninary scopin;J of remedial alternatives, determination of applicable or relevant arrl appropriate requirements (ARAR.s) arrl data quality objectives (D';Ps), arrl scopin;J of the RI. Sections 4.0 arrl 5.0 contain the detailed task plans for the RI arrl FS, respectively, includin;J the rationale arrl basic requirements for the study arrl procedures for evaluation of remedial alternatives. Section 6.0 summarizes the estilnated schedule arrl budget for performance of the Work Assignment. 3 I : , -- 1 I I I I I I I I I I I I I I I I I .... · ··---·· .. 3.0 SOJPING OF 'IHE RI/FS C-REMNCSU2/WP3 .1 01/08/87 ESE has developed, consistent with recent USEPA guidan::e am policy, a technical approach to perfoi:min;J RI/FS studies under the REM III contract. 'lhis approach includes a f'oc1sed investigation in each stage of the RI/FS process to ensure that the field investigation ex>llects the data nee:led for the Endan;ennent Asses~ (EA) am for the evaluation am selection of the most awropriate 'l"E!IIEdiaJ alternative(s). 'lhis approach is interxled to produce data appropriate for their interxled use am to avoid generation of data not "leCessa:cy for valid site characterization or evaluation of 'l"E!IIEdial alternatives. 'lhis approach also ensures that analytical am evaluative activities are perfo:cmed in a tirrely am CX>St-effective manner. 'lhe following subsections identify the oojectives of the RI (Section 3.1), provide a disa1ssi1J11 of ARAR am I:Q:ls (Section 3.2), am des=i.be the scope of the investigation (Section 3.3). 'llle details of RI implementation are presented in Section 4.0, am the Task Plan for the F'S is presented in Section 5.0. 'lhe task stnJcture used in this Work Plan is based on the 12 staroard RI/F'S tasks described in the menoramum fran USEPA's HazardaJs Site Control Division (Jl.ll'le 12, 1986). 'lhis task stnJcture includes all elements of the tasks outlined in the USEPA Region IV Statement of Work dated September 15, 1986. 'llle staroard tasks, as used in this Work Plan, am the tasks in the USEPA Statement of Work are cross-referenced in Table 3-1. 3 .1 RI/FS OBJECI'IVES 'llle overall objectives of the RI/FS investigation for the NCSU Lot 86 site are to define risks to plblic health am the envi=unent, identify the need for Expedited Response Action (ERA), am ex>llect data required to evaluate potential remedial alternatives. 'llle specific objectives are as follows: 25 I I I I I I I I I I I I I I I I I I Table 3-1. Scope of Work for NCSU RI/FS C-RlllNCSU2/V3l. l 12/19/86 NCSU RI/FS Tasks USEPA Region r:v statement of Work Task 1-Project Plannin] RI Task 1-Description of OJrrent Situation RI Task 2-Investigation SUpport RI Task 4-Preliminacy Rerre:lial Technologies RI Task 8-Additional Reql.lireirents Task 2--cammunity Relations RI Task 7--cammunity Relations SUpport Task 3-Field Investigation RI Task 3-Site Investigation Task 4-Sanq:,le Analysis/Validation RI Task 3-Site Investigation Task s-rata Evaluation RI Task s-site Investigation Analysis Task 6-Risk Asse.ssrent F'S Task 1-Endangennent Assessment Task 7-'I'reatability Study/Pilot TestinJ F'S Task 5-I.aboratoi:y studies Task 8-RI Report RI .Task 6-Final Report Task 9-Remedial Alternatives Screening FS Ta&< 2-Description of Proposed Responses FS Task 3-Developrnent of Alternatives F'S Task 4-Initial Screen:in:J of Alternatives Task 10-Remedial Alternatives FS Task 6-Evaluation of the Evaluation Alternatives Task 11-FS Report F'S Task 7--conceptual Design F'S Task 8-Final Report Task 12-Post-RI/FS SUpport F'S Task 9-Mditional Reql.lireirents Source: ESE, 1987. 26 I I I I I I I I I I I I I I I I I I C-RlllNCSU2/WP3.2 01/08/87 o I.Dcate am craracterize the chemical am radioactive wastes disposed onsite to evaluate contaminant migration potential am to assess remerljal alternativesjtechnologies relevant to source co11Ltol. o Investigate the nature am extent of ground water contaminant migration offsite to detennine actual or potential contamination of private water suwly wells am surface waters. 'lhis infonnation will be used to evaluate plblic health am environmental risks am the feasibility of remedial alternatives/technologies aimed at management of plume migration. o Detennine the degree of surficial am subsurface soil contamination onsite am offsite for use in evaluating potential health am environmental risks am in evaluating feasibility of remedial alternatives/technologies. o Cllaracterize geological am hytlrcgeological parameters for assessment of contaminant fate arxl. transport arxl. evaluation of remedial technologies. Relevant to these objectives, several specific questions were considered in developing the scope arxl. tQOs for the NCSU I.at 86 site RI/FS. F.ac:h of the follow-ing questions is addressed in more detail in later sections of this scoping dc:x::urnern:. o What are the potential public health arxl. environmental risks associated with soil arxl. ground water contamination in the vicinity of the site? What is the potential for these contaminants to reach water supplies or neru:by surface waters? o What types arxl. quantities of chemical arxl. radioactive wastes are present at the site? What are the bouooaries of the waste disposal areas arxl. to what degree are the wastes containerized? o Are any expedited response actions required to protect the health of neru:by residents or to prevent further offsite migration of contaminants via ground water or surface runoff? 27 1-· I I I I I I I I I I I I I I I I I I C-Rll!NCSU2/WP3. 3 01/08/87 o Which remedial alternatives may be app1.op1:iate for the site to eliminate sam::e areas amjor to manage offsite migration of contamination? What data are T'JeE'dei_to evaluate these alternatives? o What action levels established by ARAR are necessacy, or appropriate, to minimize or eliminate potential adverse :inq:,acts an health or the environment? o What~ level is appropriate for infonnatian to support_risk assessrne..+-. an:i remedial alternative evaluation? o How can the appropriate quality ani quantity of data be 1IDSt efficiently collectei an:i evaluatei in the RI? Previoos investigations of the site conducted by NCSU have not adequately defined the sam::e volume an:i characteristics or extent of offsite contamination, either in groond water or soils, an:i available info:cnatian suggests that groond water sanplin;J an:i analysis did not canfOl:111 to USEPA stan::1ards for quality assurance/quality control (QA/QC) applied to data used in an RI/FS. Available data are useful in definin;J the scope of the RI by in:licatin;J a general plume configuration, but the data do not appear adequate for canfit:min,l' the presence or absence of contamination at low concentrations or for definin;J the vertical extent of aquifer contamination. P\Jrther ilwestigatian is required to define m:,re ccmpletely the horizontal an:i vertical extent of groond water contamination offsite, to determine the extent of soils contamination onsite an:i offsite, an:i to describe the types an:i disposition of onsite chemical waste material. 3.1.l Prel:i:minary Risk Assessrrent A preliminary risk ar:sessrnert was perfcmned to address the potential public health an:i enviromental risks associatei with the NCSU Lot 86 site. 'Ihe assessment is based an previoos studies comucted by NCSU an:i surmnaries provided in the c:M FPS as well as infonnaticn gathered durin;J the recent site reconnaissance performed by ESE. Sources of 28 I I I I . I I I I I I I I I I I I I I I C-REMNCSU2/WP3. 4 01/08/87 contamination, migration pathways, an::l potential receptors are desc:rilled in this preli:mina:ry analysis • 3.1.1.1 Ground Water Pathway-PreviOJS investigations have established that gram:!. water beneath the site is contaminated with a nurnbPr of : organic an::l inorganic waste constituents an::l that ocntaminated gram:!. · water has migrated at least 100 ft :beyon:1 the site bomdazy (based on 1985 data indicatin;J contamination in MW-12). Grom water sanples collected by USEPA an::l North carolina lllS have not been analyzed for the presence of radioactive isotopes. Water-level measurements fran mnitorin]' -wells indicate that the main gI'Ol.lll:l. water flow direction in the saprolite is westward fran the highest elevation of the site. 'lllere are, ~, localized variations in the general gram:!. water f1C7,1 pattem. 'lllere is only qualitative infomation on the vertical hydraulic gradient that indicates ~ IICllelDeJ'Tt of gram:!. water. QJartz lenses have been obsel:ved in the saprolite at shallow depths, an::l these lenses may serve as con:fu.its for contaminated gram:!. water migration to deeper zones of the aquifer. 'Ihe aquifer, consistin;J of saprolite an::l bedrock, is unconfined which may result in eventual contamination of the bedrock 'Which is used by local residents for water supply -wells. 'Ihe nearest private residence, the Medlin property (Figure 2-1), is located approximately 2,000 ft sa.itheast of the site, 'Which is hydraulically upgradient of the source of contamination. 'Ihe Medlin water suwly -well, analyzed in July 1984 by ll!S, showed no detectable contamination by organics. Analyses of the well in N0\1e!\\ber 1984 revealed trace levels of xylene an::l tetrachloroethene, althc:PJgh. these resu1 ts are believed to be due to laboratory contamination since these ccrnpoun:ls were also detected in laboratory blanks. 'lhls -well will be resairq,led an::l analyzed durin]' the RI for confinnation of the water quality. 29 •· I I I I I I I I :1 I I I I I I I I I C-REl-lNCSU2jWP3.5 01/08/87 'Ihree residences have been identified within a distance of apprcxilllately 3, ooo to 4, ooo ft to the 'WeSt-southwest of the site. 'nlese are the Fads residence, the Hendricks residence, and the Hooper residence, all located on Old Trinity :Road (Figure 2-1), 'nlese residences are not connected to water 61.lpplies of the City of Raleigh bit are served by private wells. Based on available data irxlicatin;J gram:i water flow to the west in the · · vicinity of the site, these residences are not dixectly dclwn:3radient bit may be illlpacted evenblally by the edge of a contaminant plume as the plume disperses laterally. 'nlese wells have not been sanpled previ01.1Sly but will be sanpled if contamination is detected in the proposed new bedrock wells or in MW-27A. '.the irrigation 'Well at carter-Finley stadium, awroximately 1,600 ft southwest of the site, was analyzed for extractable cx:mipoun3s by !ES in July 1984, with no detectable contamination. '.the 'Well has not, however, been analyzed for the volatile organic ccmpoun::1s foun:i at theNCSU site. '.the well is no lO!XJer used for irrigation due to the use of city water. HcMever, the well will be sanpled and analyzed if contamination is detected in the bedr=k or in MW-27A. 3 .1.1. 2 SUrface water Pathway--'.rhe potential for gram:i water un:ierflowin;J the site to discharge to neart:,y surface waters has not been evaluated, based on a review of available infor.mation. '.the nearest surface water is a small intermittent tril:lutary to Richland Creek located approximately 400 ft east of the site. Because the stream is upgradient of the site, the potential for illlpact by contaminated gram:i water from the site is low. A sinall pond, feedirq another unnamad trib.ltary to Richland Creek, lies approximately 2,000 ft west of the site. '.the potential for contaminated gram:i water frcm the site to discharge into the pond or the triJ::JUtazy is unknoWn at this time. '.the potential exists for leachate seeps to fonn a=md the site in wet weather, particularly alon;J the steep northern portion of the site borderin; I-40. kr:f such seeps may result in contamination of surface waters since the tributary 30 I I I I I I I I I I I ·1 I I I I I I I ...... C-REMNCSU2/WP3. 6 01/08/87 flowin:] into the porn west of the site is believed to originate in the drainage ditch locatai downslope an:i north of the site adjacent to Wade Avenue Extension. 'Ille uses of neart,y surface waters will be investigatai during the RI. 3.1.1.3 Soil Pathway--'lhe extent of soil contamination at the site has not been detennined. Because wastes disposed of at the site ~ ocvere:i with fill, contamination of onsite surface soils is not expected to be significant. However, during the site recornldissance, a survey of surficial soils (top 3 to 4 inches) inlicatai detectable volatile organics in several locations as measured by the HNU meter. 'lllese observations occurrecl. IICSt frequently in areas near the !CM-lying northwest =rner of the site, where surficial soils have ercded. Further investigation is required to determine whether this erosion is exposing waste material resulting in offsite migration of =ntaminatai soil during stonn events. As previously statai, the drainage ditch downslope of this erosional area may" feed into neart,y surface water bodies. Additional surface soil contamination may have occurred in two localized areas onsite. Available information inticates that three drums of transfo:aoor oil potentially contaminatai with polychlorinatai bii:nenyls (FCBs) may have been stored onsite prior to offsite disposal. 'lhis storage area is believed to be alO!l:l' the northenl boundary of the site within the chemical waste turial area. Illring site reconnaissance, a 55--gallon drum lid was foon:i in the approximate vicinity of the storage area. 'lhe area is also locatai in an erosional area, described previously. If spills or leaks occurred during drum storage or transport in the area, a pathway exists for =ntaminants to be washed offsite in storm runoff, potentially contaminating neart,y surface waters. A secon:l onsite area of potential soil contamination is the fo:aoor chemical storage dl.mpster area. No evidence was foon:i during the site reconnaissance to inticate soil contamination in this area (by visual inspection or by HNU organic vapor survey of shallow soils). Potential 31 1 ·····-····-·--· I I I I I I I I I I I I C-m!NCSU2/WP3. 7 01/08/87 survey of shallow soils). Potential soil o:mtamination in this area will be. investigated further, due to the potential for surface runoff to lower lyin;J areas offsite. D.lring JxCOJ»lc'issanoe c:utside the site fenoeline, organic vapors at a mu::enLiation of 15 ppn were detec:ta:i in one area on the northeast side · of the site, in a drainageway ~tely 20 to 30 ft fran the low-level radioactive b.lria1 area. 'Iha localized nature of the o:mtamination an::l b.lried, broken glass in::licate a possible spill, I.Jut further investigation is warranted to detennine the extent of o:mtamination in this area. HUman exposure to mntaminants in this area may ooc:ur by direct mntact with soils, inhalation of organic vapors, or .in:lirectl.y by migration of o:mtaminated runoff into surface waters near the site. Ambient measurements of radioactivity were taken durin;J the site reccuu,,,Jssance both onsite an::l offsite. 'nlese measurements did not in::licate the presence of radioactivity above backgrourxl levels in the vicinity of the site. D.lring RI activities, measurements will be taken c:x:mtinu=ly. 3.1.1.4 Air Pathway--'nie potential for chemical contaminant release into the air is considered minimal if the site remains undisturtled. Ambient I air measurements with the HNlJ arourn the site shC1iled no o:mtamination above backgrourxl for volatile organics. 'Iha only detectable releases I I I I I were near disturl:>ed soils at the locations des=ibe::l. previously. 'Iha potential for introduction of contaminant-laden dusts into the air awears low since l!0St of the site is vegetated. In summary, the preliminary risk assessme?"': has identified the follcwin;J potential exposure pathways: o 'Iha unmnfined, shallow aquifer is the predominant pathway for offsite migration of mntaminants, 32 I I I I I I I I I I I I I I I I I I C-REMNCSU2/WP3.8 01/08/87 o 'llle existence of private -wells to the "1e5t-southviest of the site iniicates the presence of poterrtia1 rea,ptors, o SUrficial soil ocntamination is a poterrtia1 source of ocntamination for neart,y surface waters, ani o SUrficial soil cantaminants may pose a poterrtia1 hazard to plblic health by inhalation of organic vapors or direct skin contact. 3. 1. 2 Risk Assessment Data Gaps Based on a review of available data ani identification of poterrtia1 exposure pathways, the follo.TinJ data gaps for dlaracterizin;J plblic health ani environmental risks are identified. Grourd Water o Identify all waste constituents, includin:J gross alpha ani beta radiation, ani their concentrations in groun::l water offsite. o Define horizontal ani vertical extent of ocntamination offsite. o Define direction of groun::l water flew in the vicinity,· particularly east ani sait:h of site. o Determine lcx:ations of private -wells (residential, agricultural, canrnercial, imustrial, nn.micipal), within a 1-mile radius of site, ani respective water uses. o Identify depths of water withdrawal for private wells ani plll[Q?ID;J rates for imustrial ani ccmnercial wells in vicinity. o Determine vertical ani horizontal groun::l water flew rates. o Determine relationship beb;een saprolite ani bedr=k. o Define the hydrcgeological ani structural characteristics of the bedr=k to determine poterrtia1 migration pathways. o Determine presence of leachate seeps in vicinity of site ani, if seeps are present, characterize chemical quality. 33 I I I I I I I I I I I I I I I I I I Surface Wc>ter C-REMNCSU2/WP3. 9 01/08/87 o . Identify surface water drainage patterns in vicinity of the site arxl praxiJnity to nearby surface water bodies. o DeteJ:mine hydraulic gradients between the site arxl nearby surface waters to detennine potential for ground water discharge. o Define uses of nearby surface waters. o Identify presence of any sensitive or eooanqered aquatic species. o DeteJ:mine extent of surficial soil contamination onsite by · organics arxl inorganics, .i.nclu::iin;J former drum storage area arxl chemical d!.mpster area. o Map erosional areas onsite arxl offsite, arxl sanple for =ntaminant deposition. o DeteJ:mine retardation potential of surficial arxl subsurface soils by measur.in; organic camon content. o Detennine vertical extent of soil contamination beneath waste material arxl potential for leachate generation. General o Select indicator chemicals based on ll'Obility, toxicity, arxl =ntaminant concentration. 3.1.3 Scoping of Remedial Alternatives 3.1.3.1 Expedited Response Action Based on available info:cmation, there is not sufficient justification for an e>cpedited response action at the site: o 'Ihere is limited potential for human exposure to wastes because the trenches are covered, the site is rem::ite, arxl access is restricted by fenc.in;. o Surficial soil contamination is limited to small localized areas on arxl nearby the site. 34 I I I I I I I I I I I I I I I I I C-REl-lNCSU2/WP3 .10 01/08/87 o '!here is no evidence that an imminent fire or e>cplosion hazard exists at the site. 3.1.3.2 Can:liclate Remedial Technolcxrles-Site problems that have been identified are contaminated waste dep:lsits, soils, am groon:l water. General response actions to address site problems include treatment, c:orrtainment, am :rem::,vaJ./disposal. Can:liclate remedial. technologies that will be assembled into remedial. altematives are disa1ssed below. Treatment of contaminated media is the preferred rerrediaJ action plrSUal1t to Title I, Section 121 of the SUperfurxl. Amen:lments am Reauthorization Act (SARA) of 1986. Excavation am i.rx:ineration of waste dep:lsits am contaminated soils am c:orrtainment, p.mping, am treatment of contaminated groon:l water will be considered as permanent solutions that will result in no hazardoos substaD:es remaining at the site. Potential technologies to fonn the TeroediaJ action altematives include excavation, incineration, transportable themal treatment units, in situ vitrification, soil-bentonite slun:y walls, extraction wells, air stripping, cartion treatment, ion-exchange, offsite disposal, fixation, lan:l.filling, am capping. Altematives involving partial treatment of contaminants with contairment of residuals will also be considered. 'llti.s Teroedial action may include ccanbinations of the technologies diso1ssed previously with solidifi- cation/stabilization of contaminated soils am capping. Because hazartlous substances remain at the site, the partial treatrrent/ containment altemative will require review of the site £Nery 5 years pursuant to Section 121 of SARA. Offsite transport am disposal of contaminated materials, which is the least favored remedial action, am the no-action altemative will also be considered. 35 I I I I I I I I I I I I I I I I I I I C-REMNCSU2/WP3. ll 01/08/87 3._1.3.3 SCRlrce Control Measures-Salro=: O.Jll.Ltol measures are likely to be required at the NCSO chemical waste dispo.sal area. '!he folla.rin] is a summacy of the infm:matian necessary to screen remedial technologies, establish design criteria, and estimate oosts. Historical data will be used, as appropriate, to limit the number of samples required: o Identification of the trench locations, drum storage area, dump.ster area, and definition of the areal and vertical extent of c:ontaminate:i soil for 1•ernecliaJ alternative evaluation, which will include excavation and treatment of waste deposits and c:ontaminate:i soils, ansite and offsite dispo.sal, ccnta:inrnent, in situ treatment, and the no-action alternative; o Definition of soil characteristics to evaluate the suitability of subsurface barriers, .m situ vitrification, and grcuro. water extraction; o A topographic survey of the site to evaluate oollectian and diversion of surface runon and runoff; and o '!he anount of =ver over the. waste areas and inplicatians concemin; the ventin:, of volatile organics into the air. To inplement source oontrol measures, the sources of contamination DDJSt be locate:i precisely. A pieyra.n of geophysical surveys and limite:i trench excavation is planned for the RI/FS to define the horizontal l:x:lumaries of the chemical waste dispo.sal trenches. SUspected trench bourxlaries have been marked by university E!llployees familiar with the operation of the site. However, exact trench bourxlaries DDJSt be determined to evaluate the use of in situ treatment tedmiques, establish design criteria for remedial alternatives, and estimate CXlSts of the alternatives within the ran;;e required for cletailed alternative analysis. '!he limite:i trench excavation will provide infollllatian an disposition of wastes within the trenches, includirq the degree of containerization. '!he degree of containerization will affect treatment and disposal 36 I I I I I I I I I I I I I I I ! I I I I C-IID!NCSU2/WP3 .12 01/08/87 cptions, partiallarly waste characteristics required for disposal or incineration. 'Ihe amount of soil within the waste trerx::hes will affect the applicability of in filJ;Y vitrification. Because of the large quantities of waste lan:lfilled at the site, it is anticipated that soil cxmtamination beneath .the waste exterxis into the water table. A limited number of soil borin:,Js is planned to estilllate the voli.nne of cxmtaminated soil beneath the site an:i to describe the soil characteristics relevant to rernediaJ alternative evaluation. 3.1.3.4 Management of Migration Measures-'Ihe areal am vertical extent of groum water cxmtamination, contaminant concentrations, an:i infonnation ~ to the strati~ an:i geology of the site are required to evaluate the suitability of subsurface containment, groun:i water ~ll'XJ, an:i groun:i water trea'bnent. 'Ihe contaminant pli.nne will be defined by the RI data collection effort. To evaluate slurry wall feasibility, two soil borin;r-; to bedrock will be conpleted dc:Mngradient of the waste disposal area an:i near MW-11. Continuous splir.--spGlOl'l samples will be collected for soil classification, an:i m,ifOSlte soil samples from three depths will be analyzed for grain-size distribution, total organic carllon ('IOC), an:i Attemexg limits to evaluate the suitability of subsurface barriers. Sanples of cxmtaminated groun:i water, bentonite, an:i soils will be tested for penteability, viscosity, an:i filter press values •. 'Ihese Fhysical tests will be performed if the depth to bedrock is less than 150 ft (limit of depth of slurry wall feasibility) • 'Ihe relationship J::ci:ween the saprolite an:i bedrock will be evaluated fran lithologic descriptions of samples· from the transition zone. 'Ihe top 15 ft of the bedrock will be cored at each boriixJ to detennine if fractures cxx:ur. Slug tests will be performed on the two proposed bedrock \¥ells to detennine the hydraulic con:iuctivity of the uwer bedrock. 37 1-:- 1 I I I I I I I I I I I I I I I ....... ·-· ...... ·•---··· C-REMNCSU2/WP3 .13 01/08/87 AU groun:i water and hydrologic data neoessaiy to evaluate c::ontairment by groun:l. water pumpin;J will be provided by the RI. Gromd water contaminants quantified durin;J the RI will define the scope of treatability studies required to design a cost-effective treatment system, if necessary. Candidate technologies for groun:i water treatment include air strippin;J, carhori/resin adsozpt.ian, and ion exc:harge. 3. 1. 3. 5 'Ihe · No-Action Alternative-Based an the remote location of the NCSU Lot 86 site, the no-action alternative may be appropriate. Available info:onation in::licates that the nearest ~ent residents are more than a mile fran the site; ho.lever, three residents an private wells are located 3H?:rcximately 3,000 ft to the soutmiest of the site and may be potentially affected by the lateral spread of a =ntaminant plume. 'Ihe potential :inp!ct of site contaminants an these residential wells will be evaluated by groun:l. water transport analyses to be ccmpleted in the FA. 'Ihere is, to date, no info:onatian con:::emin;J possible eooan;ennent to neamy surface waters by site contaminants. If the prcp:lSed investigation and FA determine that present risk is low and future risk is not expected, then the no-action alternative may be considered. FUture land use will be considered in evaluatin;J the no-action alternative. 3.1.3.6 SUmmazy of Scoping of Remedial Alternatives-In general, the existinJ d<-tabase is sufficient to describe the overall site problems and provide a prel.i.minacy assesSJDE!l'i': of enviranmental inq:iact and p.iblic health risk. However, the data are not sufficient to pemit the formulation of detailed n>rre:'liaJ alternatives or accx:arplish a detailed risk or environmental inq:iact assessment. A summary of the prel.i.minacy scopin;J of remedial alternatives based an existinJ data for NCSU follows: o Existin;J data on contaminants and waste deposits in::licate that expedited response action is not justified. 38 I I I I I I I I I I I I I I I 1. I. •- I_ . . . . ·-•· --· _, -... ·········-. C-REMNCSU2/WP3 .14 01/08/87 o "Rene:llaJ altema.tives involvin;J scm:oe, m1Ltol are lilllited by data gaps pertainin;J to source lcx:ation an:i dlarac:teristic:s. To provide a reasonable ~ to source O.lllUOl, the REN m team will cx,llect data to aid in lcx:atin; an:i ident.ifyin;; the =areas. o A ground water data cx,llection effort is required to assess the need for management of migration measures, -which will include ground water COlll:ainment, cx,llection, an:i treatment. o '!he can::U.date rernedlaJ altema.tives will include permanent remedies, which are to be perfomed p.u:suant to Section 121 of SARA. o '!he no-action altema.tive will also be considered. 3.2 IDENI'IFICATICN OF or.TA~ 3. 2 .1 Detennination of ARAR Section 300.68(c) (1) of the NCP requixes the detennination of the extent to which Federal or State p.iblic heal th an:i environmental stamards are applicable or relevant an:i appropriate. In addition, other Federal or state advisories, criteria, an:i guidance ll'4.ISt be examined to determine if they are relevant or appropriate in developirq a TPmf'diaJ ':l.ction at the site. Un:ler SARA, the requirement to attain ARARs applies to arrt promulgated state requirement that is =re strirqent than arrt Federal requirement. 'Ihis section provides a preliminary assessment of ARARs for the site. 3. 2. 1.1 Applicable Reguire:rrents--'lbe CERCIA Ccnpliance Menxlran:ium defines applicable stamards as those Federal stamards that woold be triggered by the circumstances at the site if a response were not beirq undertaken p.u:suant to CERCIA Sections 104 or 106. 'lllree Federal requirements are considered to be applicable to perfo:cnance of the RI. o 0cx::irn+:iona1 Safety am Health Administration COSHAl Reguire:rrents-All ocaipational safety an:i health requirements 39 I ---- I I I I I I I I I I I I I I I I I I ..... '- C-RrnNCSU2/WP3 .15 01/08/87 are cq:plicable far -workers c:x:n:iuct.in:; the RI/FS. Many OSHA requirements are specific far dennal contact, breathirg zone cancentrations, etc. ani m.ist be applied accmdin;ly. o RCRA/U.S. Pf'I?r,xt:11ei1t of TranspOrtaticn (rorl Regl.ille:nei1ts-Both RCRA ani ror regulate transport of hazardous wastes materials. RCRA requirements in::lude trackin;J of ~ shipnents via cx:mpleticn of manifests. ror requirements in::lude packa.gin;, shipper equipnent, ani placardin;. Both RCRA ani ror regulations are considered cq:plicable to any wastes shipped offsite far l.aboratoxy analysis, treatment, or disposal. o Nuclear Regulatory Commission (NRCl Requlaticns--Manage:ment ani disposal of lc:M-level radioactive wastes, such as those disposed en the NCSO site, are regulated by the NRC. 'Ihese regulatiOns, with state of North Carolina regulations far radioactive waste, are considered cq:plicable to the site. J.2.1.2 Relevant am Appropriate Requirements-Relevant ani appropriate requirements, as defined by the~ Compliance Memorandum, are those stamarcls designed to apply to circumstances similar to those enootmtered at CERC!A sites, even though they are not legally cq:plicable. 'Ibey include each of the follc:iwin;J. RCRA Grourxl Water Protection stan::lart:ls RCRA grourn water protection starx3ards are not applicable because the facility closed prior to enacbnent of the RCRA regulations, ani the facility was, therefore, never licensed to acce:pt RCRA wastes. HcMe:ver, the RCRA grourn water protection stardards are relevant ani approp1:idte because sane of the hazardous constituents detect:ai in the grourn water are contained in the 40 CFR 261 Appeniix VIII list of substances, ani the hazardous constituents are present in the grourn water above bacl<grc,.Jrxi [in contrast to the 40 CFR 264.94(a)(l) requirements]. 40 •••••• I I I I I I I I I I I I I I I I I I ··------··-·-----··--·----------~---· . • -•• •oL ..... -~~-• •-• -• •-•• •--•-• C-REMNCSU2/WP3.l6 01/08/87 safe Drinking Water h;t CSOO\ Prilmy Drinkim Water stama;ms 'lbe NCSU I.ct 86 site involves potential contamination of dri.nkirg water. SrMA Maximum OJntaminant Levels oas> am Maximum OJntaminant level Goals (MCI.Gs) are set at levels which wcw.d result in no kn:::Jwn or anticipated adverse health effects. M:J:.s are enforceable stan:lards, \otlereas MCLGs are nan-enforceable health goals. Both are cx:insidered relevant am appropriate in the p:twalt situation am are listed in Table 3-2. Sµ,,A Secortjazy Drinking Water starpards 'Ihe National Sec:cn:3ary Drinkin;J Water standards CXJ11Ltol =taminants in dri.nkirg water that primarily affect its aesthetic qualities. 'lbe regulations are not federally enforceable, but are inten:le:i to serve as guidelines. Clean Water l\ct {CWAl Water Q.Jality Criteri'! 'Ihe water quality criteria developed urr:ler a-IA delineate pollutant concentrations which, when not evr::eedecl, reasonably protect human health am aquatic life. Althrugh they are not legally enforceable, they are considered relevant am ~riate am are therefore listed in Table 3-2. Note that the criteria in Table 3-2 have been adjusted for dri.nkirg water only, as taken fran the SUperfund l'Ublic Health Evaluation Manual. USEPA Drinking Water HeaJt.h Mvisories The Superfund l'Ublic Health Evaluation Manual states that USEPA cx:insiclers health advisories to be relevant for risk assessment p.irposes am provides a list of USEPA health advisories. Table 3:-2 lists the USEPA health advisories which are relevant am ~riate with regard to kncwn concentrations of =taminants in grwnd water at the NCSU I.ct 86 site. 41 --- - - - - - - - - - - - --· - -·-· C-REMNCS,l/SCOPEV32.l Table 3-2, Relevant and Appropriate Requirements North Carolina state University, Lot 86 Site Contaminant Chloroform carbon Tetrachloride 1,1,1-Trichloroethane 1,1,2-Trichloroethane ~ 1,1,2-Trichloroethylene Benzene Chlorobenzene Ethyl benzene Tetrachloroethylene Toluene Xylene (Isomer A) Xylene (Isomer B) Barium Zinc Mercury Phenol Lead Proposed MCLs (mg/L) 0,2 0.005 0.005 1.0 0.002 0,05 MCI.Gs (mg/L) 0,2 o.o o.o 0,06** 0.68** 2,0** 0,44** (total) 0,44** (total) CWA Water Quality Criteria (mg/L) 0.0002* 0.0004* 19 0.0006* 0.003* 0.0007* 0,488 2,4 0.0009* 15 5 0.01 3.5 0,05 01/09/87 Lifetime USEPA Maximum Drinking Observed water Ground Water Health Concentration Advisories Offsite (mg/L) (mg/L) 391.5 2.7 17.2 8.9 24,1 128.5 3.15 0.37 3.4 3.9 0,28 10.1 16,9 2.2 (total) 10.2 2.2 (total) 5.4 1.8 0.1 0.04 0,0055 0,0003 0.081 0.02 mg/day 0.055 *Representing a 10-6 increased risk for carcinogens, adjusted for drinking water only. **Proposed MCI.Gs. Note: mg/L = milligrams per liter. mg/day= milligrams per day. Source: ESE, 1987, I I . ' : :· ' ' ' ' : . i. : I I I I I I I I I I I I I I I I I I I state Water Q.Jality starrlards C-REMNCSU2/WP3 .17 01/08/87 Section 121 of SARA requires that aey pramllgated state stamard that is :nme strin;Jent than Federal requixements DDJSt be attained in onsite cleamip actions. 'lhe state of North carolina Departllent of Natural Resources ani 0:mnuni.ty Developnent, Enviranmerrt:a1 Management Division, has pramllgated water quality stan:3ards 8-R)licable to groom water (Title 15, SUbchapter 2L). 'lbese state stan:3ards are, for the mst part, the same as those pramllgated urx:!er the Federal SJ:MA. other Reguil;ement:. other Fe::ieral ani state regulations may be ~icable or relevant ani appropriate base:l en the final results of the investigation ani chosen remedial alternative. 3.2.2 OCQ Detennination ~ are base:? en the o:,nc:ept that different data uses may require different data quality. Data quality is defined as the degree of 1ll'lCertainty with respect to precision, accuracy, reproducibility, carparability, ani caipleteness of a data set. 'lhe three broad categories of data quality are: o SCreenin;J (field screenin; ani [Q:) Level I)-Prollides the lowest data quality but the mst rapid results ani is used for p.JrJ:Cses of site health ani safety llD!'litorin;J, prel:i.minaxy ccmparison to ARAR, initial site characterization to define areas for further st:ooy, ani en;rineerin;J screenin; of alternatives (bench-scale tests). SCreenin;J includes onsite measurements of air quality [e.g., HNU, radiation suxvey meter, ani Monotaxe for cyanide (rn)] ani groom water (t:fi, temperature, an:l specific conductivity). o ED:Jineerin;J ([Q:> levels II, III, an:l V)-Prollides an intermediate level of data quality an:l is used for site dlaracterizaticn ani risk assessment. In addition, these levels 43 I I I I I I I I I I I I I I I I I I I ....... ·-. ·--.... ·· ..... ---··---···· .. ··----····-···-- C-REMNCSU2/WP3.l8 01/08/87 of data . are considered en;pneerin; quality far use in design and cx,st-:reocvery doolmentatian. tQO I.evel V cx:msists of methods requirll'q Contract I.al:x:lratory P.t031am (CLP)-spec:ial Analytical Services (SAS) • o Ccnfimatianal (tQO I.evel IV)-Provides the highest level of data quality an:i doamentatian. 'lhls level of ocnfimatianal analysis far the NCSU Iot 86 site will be used in the deteminatian of HSL organics and ioorganics of gramd water sarnples flan the upgradient Medlin residential well. 'Ihe preliminary review of 'l"'f'It'Edi aJ alternatives (Section 3. l. 3) mlicates that alternatives to be cx:msidered far the NCSU Iot 86 site ocul.d be = a:n,Ltol, migration management, or :no-action rernec'liaJ alternatives. 'Ihe &all'Ce a:ntl.tvl alternatives require the vertical and horizontal extent of the sc:urce be identified. Geo!;ttysical methods will be used to identify the trench lxAlrx3arles, with limited relll:Nal of surficial soils to define waste disposition. Etx;Jineerin;-level data will be used in the analysis of gramd water and soils far design of management of migration remediation. Table 3-3 identifies the D:20s and types of analyses far each media includin;J the following: 0 Air Screeninl Analyses Air screenin;J will be performed using the HNU meter, radiation survey meters, and M:motax8 as health an:i safety mlicatots durin;J field activities .i.nvol~ drilling, excavation, and soil and gramd water sampling. o Ground Water Eng5neerjro Analyses Ground water samples will be collected flan 18 of the 29 existing wells an:i flan all 7 new mcnitorin;J wells. Eleven of the existing monitoring wells were exclllded fran the gramd water sarnpling pl.OJiam because they were not expected to contril::ute significantly to the characterization of the oantami.nant plume. 'Ihe wells to be sarnpled were selected an the basis of their areal coverage of the site and representativeness 44 -- - -- - - - - Table 3·3. St111111ary of Sa111ple Analyse■ and Data Duality Objectives NUlllber of Field Field ODO Media Sa11ple1 Oupllcatea Bianka (1) Level Ground Waiter Existing well1 18 1• 1• 111 4 3* 1• y New well ■ 7 1• 1• 111 1 1• • y Medlin private well 1 IV ~ All wells 36 2 I Ill 1D 1 Surffclal Solla Onsfte: contfnuou■ Chemical dUD!pster area 6 • • 111 NW erosional area 7 • • 111 Offalte: NW erosional area 3 1• 1• 111 I ·40 drafnageway 3 • • 111 East drafnageway 2 • • 111 Background • • 111 --·- HSL Laboratory Anal yala Gron Alpha & HSL Gross Alpha & HSL HSL HSL HSL HSL HSL HSL Beta Beta ---- - C·RENNCSU2/H33.1 12/22/86 pH, pH, pH, pH, pH, Field Analyah (2) conductivity, temperature conductivity, teq,erature conductfvtty, temperature conductivity, temperature conductivity, temperature Gradients, water level• Horizontal hydraulic conductivity EN survey, magnetometer, ground· penetrating radar, visual HNU screening, radiation acreenfng HNU screening, radiation screening HNU screening, radiation screening HNU screening, radiation ecreenlng HNU screening, radiation screening HNU screening, radiation screening - - :i ' :1 ., ,. !.' -------------·--- - .,. "' Table 3·3. Sunaary of Sainpte Analyses and Data Quality Objectives (Continued, Page 2 of 2) Nedi ■ Subsurface soils Onafte: Trench borings Off site: New well and test borings Teat borings NUlllber of Field Field OQO Sample• Duplicates Blanks (1) Level 9 1• 1• 111 • y 4 4 1 y 4 V 6 1 V HSL Laboratory Analysts Btu, 1n0fature TDC Porosity, Atterberg lf■fta, vlacoatty, filter pre11, per.eabt l I ty Grain ahe Field Analysts <2> HNU screening ffNU ■creenfng HNU acreenfnt *Blanks and duplicate• are baaed on total number of-analyses/matrix and availability of precf1fon and accuracy data. C·REMNCSU2/H33.2 12/22/86 Duplicates and blanks will be used to aeet the quality control (QC) requirements for eamplee fr011 other location■ for the aaae ■atrfx and parameter. HNU ■ Photofonlzatlon detector. EN ■ Electromagnetic. TDC• Total organic carbon content. Note: (1) Field blank• or equipment decont••lnatton blank• do not Include trip blanks. Trip blanks will be ahtpped at• rat■ of 1 per day (eattuted) during the field water sampling effort. A total of 8 trip blanks will be Included for this project cost estimate. (2) All field analysis DQO Level I. Source: ESE, 1987. - \1 : ci I L :1 ·' " , I :i i. I I I I I I I I I I I I I I I I I I I C-RE»ICSU2/WP3,l9 01/08/87 vertical plume oanfiguration. Ml'l-6 was el:IJDinated frail the &alli)ling p1.c::y1am lJecause tru, caent oollar surrcun:iln; the well was broken, muplanlsing the integrity of aey water quality data that 'WCUld be c:btained frail the Well. Samples will be analyzed by a REM m labotatory (DQO IsveJ. mi far HSL organics am inorganics, inc:J.u:iing CN, 'Ille anaiytical data frail ~ water &alli)ling will be used to define the horizcntal am vertical extent of contamination, to dlaracterize pathways of CX>!1taminant migration (e.g., alcn; foliation planes, fractures, !!Ind throJgh saprolite) , am far the rislr assesnnert .. o Grcmxi Water Ccnfinnaticnal Analyses 'Ille Me::Uin :residential well, located srutheast of the site, will be &alli)led am analyzed far HSL organics am inorganics at the DQO Isvel 'IV at a CIP facility. o Soils Ersineerim Analyses All soil &alli)les will be analyzed at DQO Isvel m for HSL organics am inorganics. Soil sc:reenin3' with an HNU meter will be perfomed to detel1nine &alli)ling locations alcn; the drainageway east of the site. 'lhese data will be used in the FA to evaluate the pc,tential far offsite migration, ~ water contamination, am direct amtact. Subsurface soils oollected adjacent to the waste trenches will be analyzed at DQO IsveJ. m for HSL inorganics am organics. 'Ille data will be used far source CX>11Lrol remedial alternative selection, cost analysis, an:i in the risk assesr:,nen+-far the no-action alternative. 3,3 SCDPlNG OF 'fflE NCSU Im 86 SITE ROIEDIAL INVESTIGM'IC!l 'Ihis subsection OJtlines the rationale far am major ccmp::ments of the RI at the NCSU lot 86 site. 'Ille data generated during the RI will be used to detennine the nature an:i extent of plblic heal th an:i envircrmental 47 I I I I I I I I I I I I I I I I I I ·. -..... -~ ·-·-.. -. C-RrnNcstl2/WP3. 20 01/08/87 hazards posed by site cantaminants arr:i to evaluate the feasibility of remedial altematives for risk marage11e11t: In partic::ular, ESE anticipates the follcr.rin;J rernecUaJ neasures will be considered: o PuttpinJ arr:i treatnent of groom water, irx:J.ixiln;J possible . installation of a slurry wall am a water treatnent system; o 1D situ vitrification of contarninated subsurface soils; O Excavation, incineration, or treatnent of soils; o Excavation arr:i disposal of contarninated soils offsite; o Fixation of soils; o Ian::lfillinJ of waste dep::>sits arr:i contarninated soils; o Cappin:J of OCll'ltaminant som::es; and o No action. '1be follcr.rin;J subsections provide a brief snrnrnary of the prcposed scope of work for the field investigation, a=rdin; to envirormental nedium. 3.3.1 Subsurface Soils '1be RI will determine the lateral boorrlaries of the trenches, estimate the vertical extent of soil contamination adjacent to waste trenches, aIXi delineate the trenches in order to determine the feasibility of excavation, ..iD §it!! treatnent, arr:i slurry wall altematives. Geq:hysical [electranagnetic (EM) arr:i groom-penetrat.irg radar (GPR)] surveys will be used to determine trench geanetry. C1emical analysis arr:i HNU screenirg of borehole sanples collected adjacent to the trenches will provide a profile of soil contal!lination in the vicinity of the chemical waste rurial area am will provide calibration data for the geq:oysical suzveys. Borehole sanples will also be collected on.site arxi offsite to define piysical arr:i chemical properties of the subsurface soils am lithology for purposes of evaluatinJ rerediaJ altematives (i.e., pmpinJ an:i treatnent of groom water, slurry wall altematives, arr:i ,.iD situ 48 I I I I I I I I I I I I I I I I C-REMNCSU2/WP3.21 01/08/87 treatment) am describin; contaminant migration in the fate am transport analysis of the EA. 3.3.2 Surface Soils IJmita:i sanplin; of surface soils ansite am offsite will be cxmduc:tai to evaluate actual or potential. offsite contaminant migration. Onsite soil · sanples will be cx,Uected in the area previrusly ooc:upied by the chemical waste storage dunp;ter and in the. northwest cx,mer of the site where erosion of surface soils is apparent. 'Ihis nort:hWest area includes the location previaisly used to store drums of transformer oil potentially contaminata:i with PCBs. Offsite surficial soil saI!i)les will be cx,Uected from a drainageway on the northern slope beti.een the site and I-40, a drainageway adjacent to I-40, am a low-lyin; area east of the site where volatile organics were detected durin;J the site reaJipiaissanc:e. 3.3.3 Gmmd W~ter 'llle RI will inclooe an investigation of the site hydrogeology am groun:l water quality for the i;urpose of evaluatin; actual am potential. risks to public health am the environment am for evaluation of the reme·liaJ alternatives. Eighteen of the twenty-nine exis:tin; :acnitorin; 'Wells will be sanpled am analyzed to detennine the extent of groun:l water contamination. All :acnitorin; 'tlells will be used to detennine the direction am rate of groun:l water flow. Seven new :acnitor wells will be installed and sanpled to further define the vertical am horizontal · extent of contamination and backgroorr:i water quality and to cnrpare water quality data fran polyvinyl-chloride (PVC) 'tlells with data fran stainless-steel :acnitorin; 'tlells. lbysical tests of the subsurface · material am field hydraulic con:luctivity tests will be perfomed durin;J the RI to detennine the feasibility of the p.mpirg/treatment alternative am to detennine groun:l water flow rates for fate am transport analysis I of the EA. I I 49 •• I I I I I I I I I I I I I I I I 11 I C-REl-!Ncstl2/WP3 • 22 01/08/87 'D«> of the seven new man.itorirg wells are required by USEPA REgian IV for cxmparability of water quality data fran stainless-steel wells versus PITC wells. 'D«> shallow saprolite 'Wells will be located east am west of the site to further define the horizontal extent of groom water contamination am to detemine groom water flow east of the site. 'lhe background water quality of the bedrock will be man.itored with a well screened in the uwer bedrock (tq, s to 15 ft of the bedrock) sart:heast of the site. 'D«> additional wells will be installe:i to deteDnine the vertical extent of cantaminatian dowrgradient of the site. 'Ihese wells will be screened alon:J the same strucblral bedding plane (if possible), one in the saprolite am the other in the uwer bedrock. Prior to installation of these wells, three soil borin3s will be perfOD!Ed to detemine the hydrogeological, strucblral, am chemical (by HNU screenin;) characteristics of the saprolite. 'lhe groom water investigation also inc:lmesanalysis of a water s.mq:,le from the Medlin residental well located southwest (upgradient) of the NCSU site. 'lbree additional residential 'Wells, located southwest of the site, am the carter-Finley stadium irrigation 'Well will also be sanple:i if cxintamination is observe:i in the bedrock aquifer or in the saprolite southwest of the site (MW-27A). 'Ihis sanplin;J am analysis, hawever, is not include:i in the prcpo.sed scope of 'WOrk. J. J. 4 other Tasks D.lrin;J the RI, the slq,es west am north of the site will be inspected for the occurrence of leachate seeps. If seeps exist, sanples will be cxillected am analyze:i to detemine if ilmninent hazards exist that warrant immediate respouse. Sa!tplin;J am analysis of leachate sanples is not include:i in this Work Plan. 'lhe site am all monitorin;J wells will be suzveye:i (for accurate horizontal am vertical cxio:rdinates) to detemine drainage pattems so II II -. I I I I I I I I I I I I I I ii I C-REMNCSU2/WP3.23 01/08/87 aisite an:l. gram:i water flow dixections. Horizontal cx,ordinates of the trenches will be sw:veyed after they are staked. Groom water an:i surface water uses an:l. potential l:nman an:l. enviraranental receptors will be identified durin;J the RI for use in the risk assessment. 'Ihe details of each task an:l. the rationale for sanple CX>llection are presented in Section 4.0, Task Plan for the RI. 51 I I I I I I I I I I I I I I I I , I I I 4. 0 psK PIAN FOR RO!EDIAL INVESTIGATICN · C-:tm-lNCSTJ2/WP4 .1 12/22/86 '1bis sect.ion presents a description of each task to be perfonned durllx] the RI stlJ:iy at the NCSO I.at 86 site. 'nle RI CC111Sists of the 12 staroard RI/FS tasks descril:,e.d in the June 12, 1986 IDE!IDOramJJlll fran USEPA's HazardcR.ls Site 0.JirLtol Divisicm. 'nle followin; are the sta1Dardized RI tasks used in this Work Plan: Task 1-Project Planriin;J Task 2--0::m!nmity :Relations Task 3-Field Investigation Task 4-5alrple .Analysis/Validation Task s-i:ata EValuatian Task 6-Eroargennent Asses::ment. (FA) Task 7--Treatability studyjPilot Test.in; Task 8-RI Reports '1bis sect.ion descrilies each of the eight tasks cx:mprisin;J the RI. Section s.o describes the remainin;J three FS tasks and one post-RI/FS support task 'Which together cx:mprise the overall :,,,n:gxam for the NCSU I.at 86 site. 4.1 m::iJECl' PIMlNING (TA.SK 1) Task 1 includes the cx:mpletion of those activities as approved in the Work Plan Menorandllm (Wm) as Tasks 1 and 2. 'lhese activities include: o Initiation of Project Work Assi91D1e11t o Preparation of Wl'M o D:!.ta Collection and Review o Investigation of Available Aerial ~ o Development of Interim Health and Safety Plan o Site Reconnaissance 0 Project Kick-Off Meetin;J o Preparation of Project Work Plan (WP) o Preparation of Field Sallplin;J and .Analysis Plan (FSAP) 52 1-'· --·. -... I I I I I I I I I I I I I I I I ;I I o Preparaticn of Health an:i Safety Plan (HASP) o Preparaticn of Site Management Plan (SMP) C-RE1'1NCSU2/WP4. 2 12/22/86 o 0:mpilaticn of Project Plans into Field Operations Plan o Evaluaticn of ARARs o Project llernediaJ Alternative Scopin; Meet.in; o Evaluaticn of CQOs 'llle project plans prepared in Task 1 inclu:le two major plans: o Work Plan, the pt sent doo:nnerl'I", '"'1ich presents the scx:,pe, oost, an:i schedule for the NCSU Lot 86 site RijFS; an:i 0 Field Operations Plan (FOP) 'Which is Clill[osed of three plans: Field Samplin; an:i Analysis Plan (FSAP)-inclu:les the • details of samplin; an:i analytical cbjec..tives; the number, locaticn, an:i rationale for each medium sampled; the site-- specific quality assurance requirements; detailed samplin; an:i analysi.b p,:, cedures; decorrtaminaticn of samplin; equipnent procedures; am data management elements. --Health an:i Safety Plan (HASP)-inclu:les site specific health an:i safety infomaticn, a hazard asses5JDPT't, ~ requirements, health an:i safety =nitorin; ptO::edJ'JTl"S, personnel deccntaminaticn procedures, disposal pre ce'1U"PS, am aey other procedures in accordance with the REM III HASP. 'llle HASP will be updated an a subtask-specific basis as needed. -Site Management Plan (SMP)-inclu:les a brief site descripticn, an q:,eraticns plan o.rt:J.inin; the site project organizaticn am responsibilities, am the field q:,eraticns schedule. 'llle plan also addresses site security an:i aooess. Task 1 will be CCl!i)leted with the awrovaJ. of the WP am FOP. 53 I I I I I I I I I I I I I I I I I I 4.2 ca-lMilN1Ti REtAT.Icm ('l71SK 2) C-RE2-!NCSU2/WP4 • 3 12/22/86 In a=rdance with the USEPA statement of Work, a cammmity Relations Plan is net required as part of this 1o'Otk asslgilllElrt: b.rt: will be tasked as a separate 1o'Otk as1,.l.91mE11L at a later date. 4. 3 FIEtD INVESTIGATicm ('l7ISK 3 l 'lbe Field Investigation task (Task 3) of the RI consists of the follc:,wixq six subtasks: o Preparation of Bid Specifications arxi SUbc:antractor Procurement (SUbtask 3-l), o Site SUrvey (SUbtask 3-2), o Records Search (SUbtask 3-3), o Disposal Trerd1 Delineation arn waste aiaracterizatian (SUbtask 3-4), o Soils Investigation (SUbtask" 3-5), arn o Grall"Xi Water Investigation (SUbtask 3-6) • 'D1ese subtasks are descrilled in detail in the follc:,wixq sections. 4.3.1 Preparation of Bid Specifications arn SUbcontractor Proc1.U.eme11t CSUbtask 3-ll tJrrler this subtask, bid specifications will be prepared arn suboon- tractors will be procured for specific RI activities. SUlx:ontractors will be selected an the basis of bid arxi qualifications. 'Ihe five required sulxxJntra ... ts identified at this tillle are: o surface soil remcval.; o Site lq:xxjtain!c survey, monitorin;J well coordinate survey, trencll.-marker coordinates, arn site map preparation; 54 I I I I I I I I I I I I I I I I I I Ii I .... -···· ··-~· •. C-m-lNCSU2/WP4.4 12/22/86 o SUbsurface soil borin;, =nitorin; well drill:in;J/installation and develq:11ent, and CXll'lStruction of decontamination pad and dr.lm storage pad; o Transport and disposal of contaminated solids and liquids generated durln;J field activities; and o General suwcrt services, irx:ludinJ sett.in:] up a field commarxl. center (trailer, security fence, etc.). 'lhe types of activities cove.red l:ly each of these sulx:ontracts are discnssed below. o If site ccrrlitians prevent successful delineation of the trenches usin;J geofilysical techniques, surface soils will be partially :reDX:M!d to visually map the trenches. 'Ihis renx,vaJ. will be perfo:cmed only in the c:he:mical waste J:uri.a1 area. A subcontractor will be required to perfOlJD limited excavation of soils, only to the extent required to define the trench bourxlaries in the disposal area. o Subsequent and in addition to the trenc:h delineation activities described above, limited soil excavation will be required to eJqlOSe waste :material and characterize wastes in several lcx:atians. A sin;Jle sul:x::ontractor will be procured for all excavation activities. A IIK)I'8 cletailea disrnssian of these proposed excavations is presented uooer SUbtask 3-4, o~ Trerdl Delineation and Waste Oiaracterizatian. o A subcontractor will be required to o:m::hlct a tq:xigraphic ~ of the site and to survey new and existin;J =nitorin; wells and bourxlaries of the waste trenches in both disposal areas. An offsite toJAjrafilic survey of the site vicinity has been prepared l:ly the City of Raleigh and will net be required~ 55 I I I I I I I I I I I I I . -.... ___ ... ,-...·.;:····--· ....... ·--------. ····--------.. ·----···-· .. C-m!NCSU2/WP4. 5 12/22/86 this procurement. 'll'le survey ani map preparation will be ccn:iucted followin;J monitorin; well installation, soil samplin;, ani trench delineation activities. o A sul:xxlntract= will be procured to perfom monitorin; well drillfn;, installation, ani devel.OfiiSllt ani shallc:w ani deep lx>rln;Js for collect.ion of soil samples ani litholcgic dlaracteri.zation. Bid specifications will be prepared for these activities under this subtask in the initial stages of the RI. It will also be ne::essa:ry to construct a decontamination pad ani a separate bermei area for temporazy storage of drummed waste material (e.g., cuttin;is fran well drillin:;J ani waste solvent rinses fran decontamination of sanplin; equipment) prior to offsite disposal. Construction of the decontamination pad ani drum storage area will be included under the drillin; sutcoub.&.."t. o A sul:xxlntract= will be procured to transport contaminated wastes generated durin; the field prcgtam to a USEPA-approved hazartlals waste disposal facility. USEPA assistance will be solicited by the REM m team in identifyirg an appropriate facility ani arrarqin;J for disposal of the waste material. Highly contaminated solid ani liquid wastes generated durin; soil samplin; ani well drillin; activities will be containerized ani stored in a tempora:ry drum storage area prior to offsite disposal or treat:Jnent. wastes not detennined to have significant o:incentratians of oontaminants will be disposed ansite. o A subcantra.ct= will be procured to establish the site cx:,nman:i post, ocnsistin;J of an office ttailer, security f=, air cxinditicnin;vheatin;, ani sanitation facilities (portajc:tln). 56 I I I I I I I I C-R™NCSU2/WP4. 6 12/22/86 'Ihe CX"JDJDaM post will be established prior to initiation of the drillirg pxo;Jtam. 4.3.2 Site Survey (SUbtask 3-2} A detailed survey of the NCSU I.at 86 site, includin; oosite structural • features (i.e., fences, gates, wells, and ror right-of-way markers) and t.qx:x;Jiai;i-i.r (at 1-ft cxmtaJr intel:vals), will be 0Cll:iucted to deteJ:mil'le drainage patteins onsite. E>d.stin; and newly installed mcnitorin; wlls will be surveyed for horizontal and vertical coordinates. 'lhe ems of the trenches will be staked wnen identified and surveyed for horizcntal CXlOrdinates. An offsite topographic survey has been prepared by the City 1 · of Raleigh for the aiea includin; the NCSCJ I.at 86 site; therefore, an offsite survey will not be required under this scope of work. 'lhe survey I I I I I I I 'I I ~ was perfODDed an a scale of 1 inch to 200 ft, usirg 2-ft cxmtaJr intervals. 'Ihis map will be useful in identifyirg local drainage patterns and their iel.atian to the site. 4.3.3 Records Seaml. [SUbtask 3-3} Im'irg the initial·~ of the RI, a seaLdl will be oon:1ucte:i to d:Jtain and review records not previoosly acquired in the develcpnent of the WP. 'lhe required info=tian inclooes: o Disposal iecoLds for the chemical waste and the low-level radioactive waste bJrial. areas; o Envirorinental. mcnitorirg data available for both aieas; o I.ocatians, ccnstructian details, and pmpirg iates of danestic, o:mnercial, and industrial wells in the vicinity of the site; o SUrface water uses; and o Presence of sensitive or ~ terrestrial or aquatic species. 57 I I I I I I I I I I I . 1 I I I I I· I ~ C-REMNCSU2/WP4. 7 12/22/86 Disposal re.:xu:ds and enviranmental. m::initorin;J data are available fran NCSU. 'Ihis infomation will be used for waste characterization; refinement of the field investigation: evaluation, design, and oostin;J of the :remedial 'llternatives; and selection of indicator chemicals for the ri.sl!' assesS!NfflP. 'lbe review of waste disposal n..:mch. will identify, . 'Where possible, the dates, methods, and locations of waste disposal as -well as the types and quantities of wastes. Nearby water ~ly wells (danest.i.c, CXEJmemiaJ., agricultural, municipal, and irxlustrlal) will be identified t:hrcugh a rerutv1oissarre of the area and a review of n:o:,1&. available fran the North carolina Deparbnent of Environmental Management, Grc:m1dwater Section, in Raleigh. Required infomation for the risk assesSll)Effl+: inclu:ies the location, use, depth, pcp.l].atian served, and construction details for any such wells. Uses of nearby surface waters and presence of sensitive or endan;Jered species in the site vicinity will be identified by contactin;J local (City of Raleigh and Wake 0:lunty) enviranmental. and natural resam::es agencies • 'lhis information will be used in the EA for the oo-act.i.on alternative and in evaluatin;r potential environmental and ?,lblic health risks associated with in'plementation of various remedial alternatives. 4.3.4 DiSPOSal Trench Delineation and Waste Cllaracterization (SUbtask 3-4) Identification of onsite waste disposal areas and characterization of the types, quantities, and disposition of waste material are essential for detailed evaluation of :remedial alternatives, developuent of a proper health and safety pro;iram for onsite work, and the EA. Geqilysical methods will be used to determine the lateral extent of trenches in both the chemical waste b.Jrial area and the low-level radioactive waste disposal area. Both an :Dl-31 and GPR will be conducted 58 I I I I I I I I I I I I I I I I I I 1:1 C-R™NCS02/WP4. 8 12/22/86 in the areas designated in Figure 4-l. A grid pattern will be established for the gec:ptySical surveys by drawilx;J transects at lO-ft intervals across the width and len;ith of beth areas. 'Ihe EM and GPR surveys will be cxmuct:ed oc:intiiruaJsl.y alcn;J the transects and will result in total linear footage suzveyed of 8,800 ani 4,500 ft for the · chemical waste J:iurlal. area and the radioactive waste disposal area, respectively, 'Ihe differe1.::e. in soil prqierties (i.e., density, electrical resistivity, porosity, ani moisture com:ent} ani waste characteristics between the trenches and the un:listurlied soil will be defined us:in; EM-31 and GPR surveys. Dle to the uncertainty of soil corxlitians and waste characteristics, these surveys used together will yield the optimJm results and may yield infODDatian not possible if used iniividuaJJy. '!be vertical extent of the trenches can be deteimined us:in; GPR, l::Ait the acan:ac:y is depement an clay and moisture com:ent of the soil. As the soil, clay, and moisture ocntents increase, the depth of radar penetration decreases. 'Ihe minimum depth of radar penetration, given ""°rst possible field corxlitians (i.e., high moisture C0J'ltent and high clay com:ent) , is ellp8Cted to be apprcximately 8 ft, allowing the lateral extent of the trenches to be aefined. If g~ical techniques are unsuccessful in delineat:in; trench bamdarles in the chemical waste l:iurial area, surface soils will be tenporarlly rmcved fran parallel transects across the site, perperxlicular to the ellp8Cted orientation of the trenches (north-south) • 'Ihe general orientation of the trenches will be detemined by four test transects. Once the orientation has been detexmined, 2-ft-wide transects will be made at 20-ft intervals in c:anbinatian with 5-to lO-ft intervals, as req.tlre::i, to locate the ems of the trenches. For c:cstin; purp:ses, it ii' assumed that four test transects a:i;proxiJllately 20 ft lcn;J and nine full transects ~roxiJllately 180 ft lcn;J will be req.tlre::i to define b:e1ch bamdarles, No waste will be rencved fran the trenches 59 I I I I I I I I I I I I I I I I I I I I REM/II NCSU ,_,A LEGEND e MONITORING WELL LOCATION • • FENCE 1,,,,,,j AREA OF GEOPHYSICAL SURVEYS Figure 4-1 f:: C ft! ..... I Jt . Io . -t~ • FORM8' CHEMICAL • STORACJE ~ER AREA • 0 IO ... ------IICAI.I .. PUT NORTH CAROLINA STATE UNIVERSITY, LOT 86 LOCATION OF GEOPHYSICAL SURVEYS ENVIRONMENTAL SCIENCE AND ENGINEERING, INC. SOURCE: COM, 1H5. ~ 60 ....... -.... ..... : . ,. .. "-"---· ···-. . ··•··· . . ~---. I I I I I I I I I I I I I I I I I I I C-REMNCSU2/WP4. 9 12/22/86 durin:;J this tenp:,rary remcval.. On canpletion of the trench delineation, excavated transects will be backfilled, CCl!picted, and resr:4=:i, If geophysical tedlniq.lE!S, in canbination with rec:o.c&. review, are not suooessful. in definill3 thi. tuu.di bomdaries for the lc:M-level radioactive disposal area, the Site Manager will corrluct a meetin;J with the USEPA Region r:v Project Manager to detel'llline the ca.m;e of action. 'l1lis Worlc Plan does not include remcval. of surface soils in the lc:M-level radioactive waste disposal area. Waste characterization for the disposal sites will be aCXX111plishe:l in part by a detailed review of disposal r..c:ozds, wch will detel'llline types, quantities, a:nd dispositian of waste material, as described un:ler SUbtask 3-3. For the p.ixposes of eval.uatm; 'l"f'1DE'diaJ '9.lternatives for the chenical waste disposal area, it will also be necessary to determine the present oondition of the waste material (i.e., the degree of waste containerization followin] disposal a:nd soil cxmq;,action, and, if possible, the ratio of soil to waste in the trel'lcl'les). To a:,tain this information it will be necessary to cx:induc:t a limited soil rem::,val at a mini= of five locations selected 1n· ramcm trerciles identified in the disposal area. Soil = will be reiu:,veci in each area to expose the waste in a 2-ft by 3-ft area, to a depth of approxil!lately 3 ft. waste contairiers will be exaJnined by hand as necess3J'"j to detel'llline whether they are intact and oantain waste material. 'lbe information provided by this r;rurvey will be used to detennine the viability of alternatives such as incineration, ..in situ vitrification, and offsite waste disposal. No excavation is planned for the lc:M-level radioactive waste disposal area. 4.3.5 Soils Investigation (SUbtask 3-Sl Soil investigations at the NCSU Lot 86 site will include surface and subsurface soil sanplin; and analyses for risk assessment and evaluation of remedial alternatives. SUrface soils will be sampled alarg 61 I I I I I I I I I I I I I I I I I I I c-REMNCST.l2/WP4 .10 12/22/86 drainageways, in the f0I1Der dumpster and drum storage areas, and SOlth of the site (bac:kgrcuni sample) , primarily for risk assessment. SllbsUrface soil samples will be collected fran borin;s to detemine P1Y5ical and geodlemical soil c::haracteristic:s in the area and to detemine the extent of soil ccntami.natian adjacent to the trendles in the dlemical waste disposal area. 4.3.5,1 SUrface Soil samplirp-6hallcw soil sanples will be collected fran several localized areas onsite and offsite to a depth of up to 1 ft. 'Ihe potential for offsite migration of a:antaminants and for gro.m:i water ccntami.nation fran these areas will be evaluated. 'Ihe locations and designations of the different areas are depict:e:i in Figure 4-2. Specific locations are shown if JmJwn; if not, the general area to be investigated is shown and specific sanpling locations will be determined in the field at the tiJDe of sanpling (at locations shewing organic coricentrations with HNtJ screening) • I=ations are designated as surface Soil Sanq,le A (SS-A) , meaning surface soil sanple location A. Where =re than one sanple is collected, the sanples will be lat>eled SS-Al, SS-A2, etc. 'Ihe potential for offsite migration of a:antaminants by runoff will be investigated by sanpling surface soils in the drainageways (see Figure 2-3) in the northwest area of the site (SS-A, SS-B) east of the radioactive waste disposal area (SS-C), and alO!XJ the I-40 extension ' (Wade Avenue) drainageway (SS-0) • Alc:n;J the northern and wstezn fenceline in the northwest section of the site, . erosional channels (up to 1 ft in depth) have fonned. 'Ihe channels merge and leave the site at this northwest corner. n.ie to erosian in these dlannels, the depth to the waste rray be nrliia!d and the possibility exists for the elCpOSure of waste if a trendl urrlerlies one of these channels. Drums of PCFrcontaminated transfonner oil were stored at the surface alO!XJ the northern fenceline. 'Ihe potential for PCB contamination of soils and contaminant migration offsite will be evaluated fran soil samples 62 ·••,•·-• ·-··. I I I I I I I I . I I I I I I I I I AEJl/tl NCSU 1,nA .,o LEGEND e MONITORING WELL LOCATION • 1t FENCE *OR<::::::;::) SOIL SAMPLE LOCATION Figure 4-2 PROPOSED SURFACE SOIL SAMPLE LOCATIONS, NORTH CAROLINA STATE UNIVERSITY, LOT 86 SOURCES: CDM, 1H5: ESE. 1U7. 63 -.. • 14 * SS-F FORM~ CHEMICAL ST~AQE D~El'I Al'IEA 0 • ""' ------1c.&u 1•nn ENVIRONMENTAL SCIENCE AND ENGINEERING, INC. • I I I I I I I I I I I I I I I I I I I C-:RF.fflCSU2,IWP4 .11 12/22/86 collected alcrg-the drainageway. seven surface soil &allples (SS-Al through SSA-7) will be collected alcrg-the ansite drainageways as depicted in Figure 4-2. P.tq;csed samplirg locations are= closely spaced in the vicinity of the fomer drum storage area to ensure that patential ccmtaminaticn Jn this area is identified. 'l1'le remaining saJl'i)l.es to be collected in the mrthwest aimer of the site are spaced at apprcod.mately 20-to 25-ft intervals to detexmine whether waste material is elCp06ed near the surface, thus inc:reasirg the pc,tentia1 for contaminated surface runJff. 'l1'le channels are fairly wll defined arxi unifo:cn in slope so the prc:p:,sed samplirg pattern will aid in evaluatirg the pc,tentia1 for da.mslope arxi offsite migration of contamiJ'lants. 'l1'le sanples will be screened with the HNU prior to transmittal to a REM Ill laboratory for the analysis of HSL organics arxi imrganics at IlQO teve1·m. Offsite and damslope of the channels desc:ril:led al:lolle, surface soil samples (SS-Bl through ss-BJ) will be collected at three locations :fran o to 6 inches in depth to in:lic:ate Whether offsi te migration of contamiJ'lants has ocx=red. 'l1'le analytical methods and parameters will be the same as these stated previously. Dlrirg the site r...::cuv1c:dssaooe, HNU screenin;J of surface soils in:lic:ated levels of volatiles up to l.5 a:zn in the drainageway located approidlnately 20 to 30 ft east of the lC"1-level :radioactive waste disposal area. 5ani>les will be collected at S-ft intervals alcrg-approximately 50 ft arxi screened with the HNU for volatile organic content. Soil sanples will be collected for laboratory analysis :fran the three locations shcMirg the highest con:::entraticns of volatile organics in the screenin;J. 5ani>les will be • 111psited into two sanq;,les (SS-Cl arxi SS-<2) • One O itpsite will be :fran a depth of o to 6 inches, arxi the other CXJUf£.X.6lte will be :fran a depth of 6 to 12 inches. 5ani>les will be analyzed for HSL organics an:i imrganics at DQO I.sveJ. m at a REM m laboratory. Based 64 ...... --•·-··· ····•···· ··•·····-··-·-·• ..... _., ·-..... I I I I I I I I I I I I I I :I I I I I C-REMNcstl2/WP4 .12 12/22/86 at the results of these analyses, sul:lsequent saq,lirr;r arxi analysis may be required to further define the extent of oontaminatian in this area, alt:hcu\lh the costs far these aail.ticnal activities have l'lClt been incl.med in this Wc%k Plan. . To further evaluate the p:,tential far offsite migration by surface xunoff far the FA, three samples will be oollected alarg the I-40 extension drainage ditc:n north of the site. one sample (SS-03) will be oollected upslope of the influence of site IUl'lOff as a background soil quality sample. 'Ihe ether two samples (SS-Dl arxi SS-02) will be oollected srutheast of ~17 arxi ~13. Samples will be oollected fran o to 6 inches arxi analyzed far HSL organics arxi inorganics at a REM III laboratory at IX2() Ievel III. In the fo:cmer c:he:mi.cal storage d\inp;t.er area (Figure 2-2), possible soil oontamination frail liquids that may have leaked frail the d\inp;t.er will be evaluated. Shallow soil samples (SS-El thrcu;h SS-E6) will be oollected at depths of 4 to 10 indles at the centers of the grid depicted in Figure 4-2. sinoe the c:he:mi.cal dulip.ter area is. the site of possible c:he:mi.cal spills in the past, a samplirr;r depth of 4 to 10 indles was selected to detect p:,tentially higher contaminant ooncentra.tions in deep,r soils that have l'lClt been elql0Sed to erosion arxi degradation processes oc:o=irr;r at the soil surface (e.g., :i;:tiotodegradation). Soil .fran eight locations will be CXiiifX-ISlted into each sample, resultirr;r in a total of six samples far c:he:mi.cal analysis. 'Ihe soil WlllfX-ISlte samples will be analyzed far HSL organics arxi inorganics at IX2() I.e\1el III. One sample (SS-F) will be oollected fran a depth of 0 to 6 indles approxil!lately 150 ft south of the site to represent background soil quality. 'Ihe background soil samples will be analyzed far level III HSL organics arxi inorganics at a REM III laboratory. 65 r· I I I I I I I I I I I I ·I I I I I I C-RD!NCSU2/WP4 .13 12/22/86 4.3.5.2 SUbsurface Soil Sanplirp--subsurface soil sanq:,les will be collected fran 14 onsite and offsite borin:;s for use in the EA and for evaluatin3' rerneclial altematives (Figure 4-3). Sllbsurface soil sanq:,lin; locations and depths an, pi s □!t:.,d in Table 4-l. SUl:lsurface soil . sanq:,11n;i fran three borin:;s adjacent to trenches in the d1emic:al waste · disposal area will be performed to detemine the depth of soil contamination beneath the trenches and to c:harac:terize d1emic:al-p1y5ic:al properties of the soil relevant to evaluation of 'r'f'IDE'diaJ technologies and to the fate and transport analysis of the EA. Eleven offsite soil 1:>orin;s (bcrin3s m-o, m-E, m-F, IS-G, and the seven prcposed mcnitorin; wells) will be analyzed to describe lithology, hydraulic corxructivity and plys:l.cal-d1emic:al properties. Onsite subsurface soil sanq:,les will be collected frail three :borin;s (IS-A, m-B, and IS-<) located adjacent to trenches in the chemical waste disposal area. 'l\10 of the :borin;s will be located in the dcwn;radient area between one old and one newer ti ... -dl, if trench age can be detennined frail disposal lcGOids. 'Ihis ~ch is intended to detennine differences in depth and degree of soil contamination relative to the age of the trerv:::h. If_ the age of trenches cannot be estimated based an available records, the two dcwn;radient :borin;s will be made between trenches alOl'Y:J the westernmost edge of the disposal area. 'lhe thiJ:d onsite soil :borin; will be located between two uwrafilent trenches in the · d1emic:al disposal area. If drillin; between trenches is not feasible, the :borin;s will be adjacent to the trenches al0l'Y;1 the periphery of the tienc:h area. 'Ihe drillin; qieraticn for all 1:>orin;s will be supeIVised by a field geologist who will log all sanples. Sanples will be obtained durin; SPl' and usin; Shel.by tube sanq:,lers. 66 I I I I I I I I I I I I I I I I I I I fflllHI NCSU 1/11A • • • • /;. e1s • 32 LEGEND e10 DS-F 6 .29 EXISTING MONITORING WELL LOCATION FENCE PROPOSED MONITORING WELL LOCATION (SUBSURFACE SOIL SAMPLE LOCATION) SUBSURFACE SOIL SAMPLE LOCATION (BORING ONLY) Figure 4-3 PROPOSED MONITORING WELL AND SUBSURFACE SOIL SAMPLE LOCATIONS, NORTH CAROLINA STATE UNIVERSITY, LOT 86 SOURCES: COM, 1"8: ESE. 11117. 67 -.. • 14 •--.. • 30 FORMEI' CHEMICAL ST~AQE 0..-sTER AIIEA \ 300 TO SOD FEET ll. 31 0 .. 00 e • KAU ia,ur ENVIRONMENTAL SCIENCE AND ENGINEERING, INC. --------·-----c--·--------.·.--:-:-·: -.::·_ ... -. _. -·-"·---·-·· · ........... ___ ----------·-.. -... .. •.. -· ., ....... , ..• ,·s .. -···• ....... ·-· ·--·-'"· I I I I I I I I I I I I I I I I I I C-REMNCSU2,'WP-Vl'B41. l 12/22/86 Table 4-1. SUbsurfaoe Soil 8allplin; tocaticns am Depths Iocatian Total Depth (ft) Shelby 'l'llbe 8allplin; Depth (ft) Split--spoon Sa:mplim Depth (ftl Blysical Olemical Parameters ParalDeters Bori,rns Completed as · Monitor Wells MW-30* 50-60 MW-31** 100-120 MW-32* 60-70 MW-33* 56-61 MW-34* 48-53 MW-35* 70-80 MW-36** 105-115 20,40 10,50,90 Test Borims I:6-A I:6-B [6-C I:6-D I:6-E CS-F [6-G 40 40 40 100 100 100 100-110 20,40 20,40 20,40 10,50,90 l0-12,24-26, 38-40 10-12,24-26, 38-40 10-12,24-26,. 38-40 Notes: Shell,y TUbe 8allples: StnJctural am lithological c:haracterizaticns cmly. Split-spoon Sa!Iples (for laboratocy tests-not lithologic descripticns): (a) Rlysical paraneters-'Viscosity, filter press, perireability of soiljbentonite mixture, 'IOC, grain size, Atterl:lerg limits, ani porosity. (b) Olemical paraneters-HSL organics ani iix:>Iganics, British thermal unit (Btu) content, ani !IDisture content. *Saprolite wells. **Bedrock 1'lells. SOlrce: :ESE, 1987. 68 I I I I I I I I I I I I I I I I I I I C-REMNCS02/WP4, 14 12/22/86 Split-spoan samples will be oollected at S-ft intervals for HNU sc:reenin:J an::l. lithologic description. Additional samples will be oollected at ~te depths of 10 to 12 ft, 24 to 26 ft, an:l. 38 to 40 ft for analysis of HSL organics an:l. inorganics, moisture a:ntent, an:l. Btu content. '1hese depths were chosen to sample soils near the base of the . trendies (10 ft), the top of the water table (40 ft), an:l. at mid-depth between the base of the trendies an:l. the water table. 'lhe f~ offsite borirJ3s (I:6-D, ts-E, ll:l-F, an:l. 1:6-G) not carplete:I as manitorin;r wells will be drilled usin; a 4-i.nch hollC71ol-Stem auger and will be grouted to the surface 1'o'hen CC111plete. Borin;s ll:l-D, 1:6-E, an:l. ll:l-F will be perfo:aned as an initial field task to aid in the location of MW-35 (saprclite "'811) an:l. MW-36 (bedrock "'811) , determine the structure and lithology of the saprclite by ccntinua.is SPr samplin;, determine the hydrologic oonnection between the saprclite an:l. the bedrock, an:l. descrilie the structure and lithology of the top of the bedrock (corin; 15 ft into the bedrock in each borin;) • Two Shell:1j tube sanples will · be cx,llected fran each borin; at approximate depths of 20 an:l. 40 ft to determine the dip of the beddiJYJ planes. Borin;J ll:l-G will be ccntinua.isly sanpled in the top 10 ft an:1 at 5-ft intervals. Information fran this borirg will be used for the analysis of soil characteristics and to determine the depth to bedrock north of the site. 'Ihis information is critical for the screenin; arxi evaluation of remedial alteznatives an:l. for remedial. design. 'lhe top 15 ft of the bedrock will be cx,red to confil:m the depth to bedrock an:l. to determine the lithologic characteristics of the bedrock (i.e., fractures). 'lhe borin;s for the saprolite 'Wells (MW-30, MW-32, MW-33, MW-34, an:l. MW-35) will be sampled ccntinua.isly in the top 10 ft an::l. at 5-ft inte.xvals to the desired depth arxi at 5-ft intervals to the desired depth for lithologic characterization. 'lhe borin;s for the bedrock wells MW-31 69 ·--------I I I I I I I I I I I I I I I I I I I C-:REMNCSU2/WP4. lS 12/22/86 c::antirD.lwsly in the top 10 ft and at 5-ft-intel:vals to the top of the bedrock followed by oori1q in the top l5 ft of the bedrock. All samples collected fran soil borings will be screened with the HNU upon c:panin; the split--5pOO!l sampler or the Shelby tu1,e and fran the head space of sample jars when the borin;J is oanpletei. Six samples (three fran each borin;J) will be collected fran lxlrin;;s MW-36 and I:6-G at ~te depths of 10, so, an:1 90 ft an:1 analyzed for grain size. 5alllples will also be collected fran these lxlrin;s for laboratory analyses of porosity, Attert>el:g limits, an:1 'IOC of the soil am analyses of viscosity, permeability, llrd filter-press values for a soil...gro.md-water-!:ler'ltanite mix. 'lhese analytical results will aid in evaluatin; feasibility of a slUrIY wall for management of migration. 'lhese tests will be perfoi:mei if the depth of bedrock is less than lSO ft, '<lhidl is the limit of SllJrIY wall feasibility. Field (slug) tests will be perfonned on the two beclroc:k wells to detemine the hydraulic cooouctivity of the upper La:l:toc:k.. 4.3.6 Groom Water Investigation CSUbtask 3::§l 'l1le gram:i water investigation is designed to provide information on contaminant concentrations an:1 distribution offsite and gram:i water flew patterns in the saprolite an:i beclroc:k zones relevant to contaminant transport. 'lhis information is required for evaluatin; existing or future ?J):>lic health and ernrironmental. risks resultin;J fran offsite contaminant migration in gromd water and for evaluatin; the feasibility of gromd water '""IJW>diat-.ion tedmologies. 'l1le gram:i water investigation consists of the follCMin; activities: o Installation of seven new monitoring wells, o Sanpling an:i chemical analysis of 18 existing i.ells and all 7 new wells, and 70 ~-------------:------,--·· ------·--·· ---1 I I I I I I I I I I I I I I I I I 'I C-REMNCSU2/WP4 .16 12/22/86 o Hydrological testin;J of 10 manitorin;J wells to determine grcux:l. water flew patterns. Also incl.med in the· grcux:l. water investigaticn is the identification am description of danestic, cxmrercial, m.micipal, am industrial. wells in the vicinity of the site. '!his infonnaticn will be c::otained by recam,aissance of the area am t=ds seart:hes, as described umer SUbtask 3-3 (section 4,3.3). Infonnation cn such wells, in canbination with the results of the grcux:l. water field investigation, will be critical in the assesSTDP:nt of lniman health risks related to site CXll'ltamination. 'lhe follcwin; subsections dlsa1ss t-Jie three field elements listed aballe. 4.3.6.1 Monitorim Well Installaticn CSUbtask 3.6al-tllr:irq the RI, seven nEM manitorin;J wells (refer to Figure 4-3) will be installed. 'lhe nEM wells will be constructed of stainless steel in a=rdance with guidance received fran USEPA Region r:v. Because the existin;J wells are constructed of PJC, blO stainless-steel manitorin;J wells (MW-33 am ffi-34) will be installed adjacent to existin;J PJC Wells ffi-SB am ffi-8 for evaluating c:axq:>arability am reliability of the water quality data from the existirg "'1'E!l.ls. MW-33 am ffi-34 will be constructed a=rdin:;J to the same specifications (to the fill.lest extent possible) as their adjacent PJC wells. ffi-SB am ffi-8 were chosen as the blO PJC wells to be evaluated for c:axq:>arability ani reliability because of their constructicn am water quality. 'Ihese wells have a doaimented san:l. pack .interval. of 7 ft ani were installed at the base of the l.:lor:irq. '!his allows the nEM wells to be constructed in the same zone as the PJC wells am the water quality data fran the PJC am stainless-steel wells to be o::mpared. Contaminant ocncentraticns for ffi-SB ani ffi-8 have been 400 ani 2,530 micrograms per liter (ug,tL) c:nlorof=, respectively. 71 --··· --------·-···---------·'.-· ___ ; -·-·-.. .!---·---··--··· · .. · · ......... ••-·---·--1 I I I I I I I I I I I I I I I I I I C-IID1NCSU2/WP4 .17 12/22/86 One shallow stainless-steel m:nti:torin;J 'Well (MW-30) will be installed east of the radioactive waste clisp:,sal area to detennine groorxi water quality and flow directions east of the site. MW-30 will be installed approximately 15 · ft below the water table at a depth of approximately SO to 60 ft (a depth c:arq:>aXable to most existin;J shallow 'Wells). 'lbe location of this 'Well is prcp:isa:i to be alx:Alt so ft east of the eastern fenceline of the site and so ft sooth of the I-40 extension fenceline. A backgrourd. m:initorin;J well (m-31) will be installed into the top of the bErlrock aquifer ui:gradient of the site, approximately 300 to 500 ft southeast of MW-4. 'lhis well will be approximately 100 to 120 ft deep and ext.era into the top 15 ft of the bedrock. 'lhe well will be screened from s to 15 ft into the bedrock. Private wells in the area are screened fran the top of the bErlrock to as llllCh as 400 ft into the bedrock. An intermediate saprolite m:initorin;J well (MW-32) will be installed d~ent of MW-3, MW-JA, and MW-3B to deteDnine the lateral extent of groorxi water contaI!linatian in that zone. MW-32 will be installed at a depth of approximately 60 to 70 ft (alx:Alt 25 ft below the water table) to m:initor the 6¥18 relative elevation as MW-3A and MW-SB. 'l'Wo 1ronitorin;J wells (m-35 and M-1-36) will be installed d~dient of the site. 'lhe location of these we1ls will be further defined from the results of the lithologic borin;Js (1:6-0, 1:6-E, and 1:6-F) (SUbtask 3-5) • 'lhese wells will further define the vertical extent of groorxi water contamination offsite. 'lhe lithologic borin;Js will be used to generate detailed geologic cross sections to identify beddirg planes. Samples fran each l:xlrin;J will be screened usin;J the HNO to describe contaminant concentrations in soil with depth. Based an the geologic cross sections and the HNO screenirq, t\.'o m:initorin;J wells will be installed to determine if the groorxi water in the saprolite 011erlyirg the bedrock is contaI!linated and if contaI!linatian has migrated into the bedrock. 'lhe bedrock well will be screened frail awroximately 5 to 15 ft into the 72 1·. I I I I I I I I I I I I I I I I I I :_::·-;-;~::·.~::··:;:!'"':"".'-:,~!..~~~--.~-' C-REl-lNCSU2/WP4 .18 12/22/86 bedrock. 'lhese wells will be ..w:eened alcn:J the same beddinJ planes by projecting the beddlnJ planes identified in the saprolite into the lledxuclc. 'lhe distance fran the site to the bedrock well is anticipated to be less than 300 ft with the saprolite well located ~ the bedrock well am the site. For CXlStinJ p.irposes, the wells are estimated · to be 80 an:i ll5 ft in depth. 'lhe borm;is fo:c all saprolite ioonitorin3' wells will be drilled with 6-inch inner diameter (I.D.) hollow-stem augers to allcw the installation of 2-inch-diaJieter stainless-steel ioonitorin3' wells. Wells will be constructed of 2-inch-diaJieter, threade:i, flush-joint No. 316 stainless- steel casin3s an:i 5-or 10-ft le?'l3ths of wire wrap (0.010-inch slots) screen (Figure 4-4). MW-33 am MW-34 will have ~ft screens, am the remainin;J wells will have 10-ft screens. A filter pack will be placed arourx1 the screen to a depth 2 ft above the top of the screen. A 2-ft bentonite seal will be installed aver the pack, am the remainder of the annulus will be grouted to the surface. F.ach well will be oc:mpleted with a protective steel casirg an:i lockirg cap. All drill cuttings an:i fluids will be collected an:i disposed of in a=rdan::e with USEPA direction. 'lwo bedrock wells (MW-31 an:i MW-36) will be installed to ioonitor the bedrock aquifer water quality. 'lhe borm;is for these wells will be advanced to the bedrock by augerirg (4-inch m, hollow-stem), with continuoos SPl' borirg in the top 10 ft followed by SPl' sairples at 5-ft intervals until refusal. At oc:mpetent rock or auger refusal, the auger will be removed f:ran the borehole am a 6-inch-diaJieter steel casirg will be driven to the bedrock an:i grouted. 'lhe bedrock will be cored (usirg an NX core barrel) 15 ft for lithologic sanplin;J an:i description. 'lhe hole will be reamed to a diameter of 6 inches usin;J the Im.Id-rotary drillin;J method (with an inert, inorganic drillin;J additive) , an::l the well will be constructed in the same manner as the shallcw an::l intemediate wells. 'lhe bentanite seal will be placed belcw the top of 73 I I I I I I I I I I I I I I I I I I I REM/I/ HCSU JAr7A i t 2.5' ... -----r-HINGED CAP -PROTECTIVE STEEL CASING (IC.:=::::::.,-¼---VENTED CAP -DRAINNENT HOLE VARIABLE GROUND LEVEL i ,,..,.,..7T,'?7777":'71: 1/ Figure 4-4 '",----NO. 316 STAINLESS,STEEL ;; CASING (2" DIAMETER) " " " " :;r,i p---GROUT ' " ' ,, ,, " ,, ,,, ~-BENTONITE SEAL (2 FEET) -t';'o,i---NO. 316 STAINLESS-STEEL WELL SCREEN •.•• r------, (0.010" SLOTS) :•.~----,·· • • • • • "1----~'.•~•;r---SAND PACK ••• • • • • •• • •• · .... ,----...... • ... •• •• ·:. . .. ••• •• • • •• ·:. . ... : : :.· .. .----....... •• • .. . .. •• • • •: :-: . .. • • • • -~-=:;:=:::~·· . ..... . . .. ... ..... .. . .. ..... , ....... •···•·•··· ...... •:.•,:·.····. ~·-······ ····· .... TYPICAL MONITORING WELL CONSTRUCTION ENVIRONMENTAL SCIENCE AND ENGINEERING, INC. SOURCE, ESE. 1187. 74 I I I I I I I I I I I I I I I I I I I ·--·---------. · ... __ : ·····--··~····•'-·-····-··-·--...... ---•-·--.. C-~cstl2/WP4 .19 12/22/86 the bedrock to prevent samplin;r the water fran the overlyin;r saprt>lite. All wells will be develope:i by iµpin;r or bailin;r, depen:tirg upon yield. ExistirxJ and newly installed monitor wells will be surveyed ac: diso•ssed in section 4.3.2. 4.3.6.2 Groom Water sanplin;J am Well Testing ISUbtask 3-6bl-Dlrin3' previws investigatic:ns by NCSt1, oantamination has been detect:ei in the deepest mcnitorin;r wells (saprolite) at the site: ~lB (56 ft) and MW-SB (62 ft). 'lbe lateral and vertical extent of oantaminatian has not been delineated with the existing network of mcnitorin;r wells. As described in section 4.3.6.1, five new mcnitorin;r wells will be installed to further define the oontam:iJlant plume and to characterize bac:kgra.md water quality. 'l\io additional wells will be installed adjacent to existing mcnitorin;r wells for c:aiparability an::i reliability of water quality data fran the existing P'JC mcnitorin;r wells. Upon c:anpletian of the =itorin;r well installation and developnent field effort, the newly installed wells and a select ru.m,l:)er of existing monitorin;r wells (Figure 4-3) wi1_l be sampled. Ground water samples will be collected fran 18 of the 29 existin;r wells and fran all 7 new monitorin;r wells. Eleven of the existing monitorin;r wells were excluded fran the groom water samplin;r program, because they were not expected to oontril::ute significantly to the characterization of the oontam:iJlant plume. 'lbe wells to be sampled were selected an the basis of their areal coverage of the site and representativeness of their screen depths for the PJIP05e of characterizin;r the· vertical plume configuration. ~ was eliminated fran the sairplin;r program because the cement collar SllrTCl.lndin:J the well was broken, c:anpranisin;r the integrity of any water quality data that ~d be ootained fran the well. Prior to sairplin;r, the wells will be purged usin;r a dedicated Teflon• bailer or a cleoontanrinated bladder plllp and dedicated Teflon" tub~ 75 ,•-.......... _ -"''-•-·· ··---·· .. -··· .,-·a~~.·.--,-.•.-·-·~--~· .... -. •~--.. •-.·a I I I I I I I I I I I I I I I I I I C-REMNCSU2/WP4. 20 12/22/86 deperxilrg an -11 yield. 'lhe mcn.itorin;J wells will be sanpled usin;J dedicated an:i previously decontaminated Teflane ballers. All grom:i water sanples will be analyzed for l5L organics an:i ioorganics, an:i grass ali;:tia an:i beta analyses will be perfonned an sanples fran MW-3B, MW-4, MW-8, MW-14, an:i MW-30. Water levels measured fran all mcn.itorin;J wells alcnJ with the -11 survey data will be used to construct water level or potenticmeLti.:: surface maps. ~ water flew rates an:i directions will be estil!lated fran these maps an:i the hydraulic parameters of the aquifer (i.e., . porosity an:i hydraulic conductivity) • • Hydraulic conductivity tests will be corxiucted in four newly installed mcn.itorin;J wells (MW-30, MW-31, MW-35, an:i MW-36) an:i in 6 existirg mcn.itorin;J wells (MW-4, MW-SB, MW-14, MW-15, MW-18, an:i MW-20). Slu;J tests will be carrlucted by displacin;J water in a -11 with a solid mass (slug) , measurin;J the water level recovery, then re=vin;J the mass an:i measurin;J the water .level rise. · Water levels will be recorded with a pressure transducer an:i data logger. 4.4 SAMPIE ANADiSIS AND DM:21. VALIDM'ICN ('m.SK 4) Sanple analyses are SUimarized in Table 3-3, \m..ich incll¥3es field screenin;J an:i Rn-I m an:i CLP laboratory analysis. ~ for the sanples to be collected are diso1ssed in Sectian 3.0 of the WP. 4.4.1 Monitorim Well Sample Analysis All grom:i water sanples will be analyzed for l5L organics an:i ioorganics. Seven new wells will be installed an:i analyzed at DQO Level m for l5L organics an:i ioorganics. Of the existirg wells, 18 will be analyzed for l5L organics an:i ioorganics at DQO Ievel m. Additionally, one new well an:i four existirg wells will be analyzed for grass al!ba an:i gross beta contamination (Level V) • 76 a I I I I I I I I I I I I I I I I I . . -· .. ·. . .. ·--.... ·-·. :-- c-REMNCS02/WP4. 21 12/22/86 All analyses will be perfOI'lllEd by a REM m laboratory rather than a c:tP laboratory sin::le the results will be used for en;Jineerin;J p.tipc:ses and no dc:Jwrgradient receptors have been identified. Horizontal hydraulic conductivity will be perfoi:med in the field on 10 of the new-and existin;J wells. 4.4.2 Residential Well Sanple N',alysis 'lhe upgradient Medlin residential well will be analyzed for the HSL organics an::l inorganics at rQO Level 'IV by a c:tP laboratory. Data collected to date for this well have been determined to be inccnclusive. 4.4.3 Sµrficial Soil Sanple N',alysis Six saIIples to be collected in the dlemical dul!p;ter area will be analyzed for HSL organics an::l inorganics (Level Ill) • Sanples from the northWest erosional area, whidl includes the drum storage area, will be analyzed for rQO Level m HSL organics an::l inorganics. Offsite surficial soil saIIples collected in the northWest erosion area, I-40 drainageway, an::l east dra:inageway area an::l a backgrc:A.m:i saIIple will also be analyzed for rQO Level III HSL organics an::l inorganics. All surficial soils will be IOOnitored durin;J saIIplirg for volatile organics with an HNU meter, for cyanide usirg a Monotcx* meter, an::l for radioactivity with a radiation meter. In addition, backgrc:A.m:i radiation measurements will be taken in the field. 4.4.4 SUbsurface Soil Sanple Analysis Soil sanples fran borings will be collected onsite adjacent to the waste 77 --·~---~·-· __ .,_. I ·------ 1 I I I I I I I I I I I I I I I I I C-RDINCSU2/WP4. 22 12/22/86 trendies. samples f:ran the borin,1s will be analyzed far HSL organics and inorganics at DJ) level III and far Btu content. Offsite soil borfn3s will be perfomed in s>.JI¥)rt of en;rineerin;J design. samples will be analyzed far '!OC, Atterl:lerg lJmits, perrneabi.lity, . porosity, and grain size. 'lhese samples will be oollected durin;J new well installation and f:ran test borfn3s. All soil sa111?les (split-spoon or Shell,y tube) will be mtltored durin;J sa111?le oollec:tian far volatile organics, radiation, and cyanide. A REM III laboratory will analyze all subsurface soil sa111?les rather than a CLP laboratory, siooe the data will be generated prilllarily in sui.:p:,rt of en;rineerin;J. 4.4.5 D:lta Validation REM III personnel will validate data received fran the CLP laboratories in a=rclanc:e with USEPA F\lnct.ional Guidelines far evaluatin;J organic, inorganic, and pesticide/PCB analysis. Factors to be considered i.nclooe sample holdirg times, instrument tbne and perfo:r:mm::e, instrument calibration, blanks, SUlL03ate recoveries, matrix spikes/duplicates, plus other quality contzol parameters. 'llle specifications provided in the guidelines an:1/or ac:ceptar.::e criteria given by the USEPA Region "IV :Regional sample a:mtrol Center (RSCX::) will be followed wnen perfoz:min;J the validation. 'Ihe data f:ran the REM III laboratory at I.evel III and level V will ~ have as DUCh quality assurarx:e (~) infOLmatian with it as the CLP data. ~, it will be reviewed based an the~ data available, again usin;J the USEPA F\lnct.ional Qlidelines far evaluatin;J analytical data. 'Ihe stan:1ards specified in the USEPA guidelines will be intE!Il)l'eted in consultation with the Region "IV Envixcnmental SeLvices Division siooe the data will be• used far en;rineerin;J pw:poses. Precision and ao::uracy data 78 . . . ~-------·--........ ~--~--~---~----I I I I I I I I I I I I I I I I I I I • C-REMNCSU2jWP4.2J 12/22/86 will be detennined fran the replicates, spikes, and blanks analyzed for methods \1lhere no historical data are available. Fach type of validation listed will require the judgment of a skilled analytical chemist as well as sane exp3rience with the validation proces.s. 'lhe em use of the data will affect the degree of quality required and will be explained to the validator. 4. 5 DM'A EVAIIJATIOO (TA.SK 5) Data evaluation will be catq)leted IJIXlll receipt of data fran the field investigation (Task J). Data will be ~ to project objectives and sununarized into a usable format for data mani~ation. Tables will be created to exhibit data, rontaminant levels will be plotted on site maps, and groum water cxmtour maps and geologic cross sections will be clevelq:,ed. Contaminant receptors will be identified, contaminant migrcition pathways refined, etc. 'lhe results of this task will be used in the risk assessment and in the evaluation of remedial alternatives. 'lhis task will also include an assessment of 'tmether additional investigation is requried for the risk assessment and evaluation of remedial alternatives. Follc,..,in;J a prel:iminary assessment of the field investigation fin'.iings, a meetin;J will be held between USEPA Region J:V, the :REM m team, and, if appropriate, the State of North Carolina to evaluate the need for additional investigation. If it is deteDnined that Blase II site investigation or laboratoryjbench-scale studies are required, a Memoran:lum for Technical Direction (MID) will be prepared. 'lhe MID will be used to document catq)letion of the first i:rase of the RI and will provide a mechanism for changin;J the authorized ceilin;J with respect to the obligated furdin;J level for the 'l;OZ"k assignment (if necessary) • A=Jrpanyin;J the MID will be a revision to the Work Plan documentin;J the scopin;J, schedulin;J, and l:oogetin;J requirements of the proposed subsequent i:rase, if required. 79 • ·-.... -...... --.. --,-------,--,-· .•. :.c.-_. -...•........• -. . .. . I I I I I I I I I •• I I I I I ,. I I 4.6 ENlY\NGERMENl' ASSESSMENl' (TA.SK 6) C-REMNCSU2jWP4.24 12/22/86 FollowinJ the data evaluatim, an EA will be perfonned usin;J methods described in the USEPA Endan;erment Assessment Han:lbook (August 1985) am the USEPA SUperfun:i Public Health Evaluatia'l Manual (SFHEM, Dece11! er 1985) • 'Ihe objective of the EA is to characterize the cuuent am potential ?-]blic heal th an:i environmental risks that would exist under the no-action alternative. 'Ihe EA will be an evaluation of available de.r..:.ytalJhic, geograi;:ru.c, i;:tiysical, chemical, and biological factors that describe the .i.npacts of hazardCAJS waste releases frcm the site. 'Ihe EA will evaluate the types and concentratia,s of hazardcus chemicals present at the site, migration potential of oontaminants thrcu;Jh varicus media, their taximlogy, and the degree of exposure to the em,i.tonneut and ?-]blic health. 'Ihe results of the exposure assessment will be coupled with the taximlogical evaluation to detennine the degree of errlan:]ement posed by exposure • 'Ihe EA process inclooes the followinJ basic steps: o Selection of :in:ilcator chemicals, o Estimation of exposure point mncentratia,s, o Estimation of chemical intakes, o Toxicity assessnent, an:i o Risk characterization. Based on the prel:ilninazy risk assessment an:i review of available data, fa.Jr chemical classes are of corx::em at the site: o Volatile Ol13lUUC carp:,.ImS, o Semivolatile organic ~. o Pesticides an:i PCBs, o Inorganic ~- 80 I I I I I I I I I I I I :I I I I I I I --•-·· -·-----~----··---•·--··· ~----.... C-REMNCSU2/WP4. 25 12/22/86 Indicator c:hemicals will be selected to represent these c:hemical classes in the EA. A maxill'l.lm of 15 .in::ti.cator chemicals will be selected. · Exposure-point corcentrations of the .in::ti.cator chemicals will be . estil!lated by i.dentifyllq all relevant exposure pathways an:i estiJna~ chemical concentrations at p:itential. receptors by a fate an:i transport analysis. 'llle exposure pathway of prilllary can::iern at the NCSU Iot 86 site is migration of wastes into grrun:i water that may p:itential.ly serve as water supply for nearlJy residents. 'llle p:itential. for human an:i environmental receptors to be exi;csed to contaminated grrun:i water, surface water, an:i soil offsite will be examined in detail. 'llle projected concentrations of indicator chemicals in enviionmental media at exposure points will be estimated fran the database USID3' semiquantitative environmental. fate an:i transport analyses. 'llle use of so.:rusticated grrun:i water transport DYXleJs i.s net anticipated due to the limited nature of proposed sairplll'l3'. Predicted contaminant concentrations will be cx:aipared to a list of ARARs, refined to reflect the contaminants of can::iern. Where contaminant concentrations exceed or awroach stan:iards, additional risk analyses will be performed to confirm that the pollutant transport analyses adequately represent conditions at the site an:i cletennine ~ additional data may be needed to fully characterize risks. For these critical contaminants 'Which have no Federal or State stan:iards, acceptable concentrations in environmental media will be estimated based on acceptable daily intake (ADI) values (for noncarcinogens) an:i cancer potency ~actors (for carcinogens). 'llle primary source of toxicological data used in the analysis will be~ C of the SHiEM, USEPA's Health Effects Assessnent (HEA) documents, an:i the USEPA Ambient Water Q.Jality 81 I I I I I I I I I I I I I I I I I I I c-REMNCSU2/WP4.26 12/22/86 Criteria documents. Target risk levels ·will be determined for carcinogens in consultation with USEPA Region IV. Information frcm previoos steps will be integrated in the risk characterization step to detennine the degree of erx:lan]erment posed by site conta:minants under the no-action alternative. 4. 7 'mEATABIL1T'i S'lUDYjPll.Ol' T.ESl"ll-«> (TA.SK 7) Based on an initial review of data, it ~ that subsurface containment, pm1pill3", an:i treatment of grcurxi water llBY be a carp:,r.ent of a nanagement of migration alternative. To screen the grcurxi water treatment c::cmponent of this type of alternative, treatability studies will need to be ~envmted. If grcurxi water characteristics defined by the collected data in:licate that treatment is feasible, then a WP will be developed for the requ:iied study, clearly definill3" the specific objectives and scope of work. For costin;J p.JrpOSes, the hours requ:iied to develop a study scope, prepare a.WP, procure a laboratory subcontractor, and evaluate and use the generated data are included in this task. If soiljwaste characteristics defined by the collecta:i data in:licate that ..in situ vitrification is feasible as a srurce cont:ro) :rreasure, then a WP will be developed for a bendl-scale laboratory study, clearly definill3" the specific objectives and scope of work. 'lbe cost of this study has been estilllated by includin:J the hours requ:iied to develop a study scope, prepare a WP, procure a laboratory subcontractor, an:l. evaluate and use the generated data. 'lbe costs associated with performance of treatability studies an:l. pilot testing are not included in the cost sumnary for this scope of work. 82 I I I I I I I I I I I I I I I ,, 1· I I 4.8 R&!EDIAL mvESI'IGATICN REl-OR1' ('D\SK 8) C-REMNCS02/WP4. 27 12/22/86 A draft RI report will be prepared at canpletion of the site investigation arxi evaluation of data. 'Ihe report will summarize the results of the field investigation arxi record seardles arxi px sent the data arxi conc:lusians in a clear, oanc:ise zecotd. 'Ihe RI report will also present the results of the data evaluation arxi EA. 'Ihis task is caiplete upon review arxi cx::mrent on the draft RI report ooannent:. 'Ihe report will be finalized am carbined with the FS doonrent (Task 11) ~ a sirqle RI/FS. report. 83 .,~---·-• I I I I I I I I I I I I I I I I I -------·---------······~-··~·,.,;;----·: ·-;'-.-,~:•·---·---·· ···-·· . ········--~·, ., -... : :-,-:-:--:-~.-.. ~ ---. ···-· 5. O TASK PIAN FOR 'lliE FFASIBILl'IY S'IUDX C-m!NCS02/WP5.l 12/22/86 In accordaroe with the stamaJ:d USEPA RI/FS tasks, the FS for the NCSO Lot 86 site will ccnsist of four tasks whicn will be conducted based an the results of the RI. 'lllese tasks are as follows: Task 9-:RernediaJ Alternative Screenin;J, Task lO-~ial Alternative EValuatian, Task ll-Feasi.bility Stu:iy Bep:n.t, and Task 12-Post-RI/FS Sufplr:t. 5.l REMEDIAL AlllmOO'IVE SCREENIN::; (TA&{ 9) 'llie first step in the FS process is conducted sil!lultaneously with the EA (Task 6) and the Data validation, :Reducl:icn, and EValuatian effort (Tasks 4 and 5). 'llie objective of this task is to refine the ran;re of response actions developed durin; the scopin:J p:cocss... 'lhls task will employ the data cx,llected in the Site Investigation (Task 3) and the results of the EA (Task 6). 'llie 61.lbtasks carprisin:J Task 9 will accomplish the foll~ objectives: o Developrrent of remedial response objectives, o Identification of aa,licable technologies and assemb1.y of alternatives, and o SCreenin:J of rernedfoJ technologies/alternatives. 5.1.1 Ilevelopment of Remedial Response Objectives Based on the data cx,llection in the RI and the contaminant migration pathways defined in the EA, the remedial response objectives will be developed. Site specific response objectives will be developed usin:J a risk-'based methodology to define cleanup levels that would eliminate or minimize risks to plblic health and the environment. :EotentiaJ. contaminant migration pathways and el!pOSllr8 pathways, identified in the EA, will be examined fUrther as a basis for estil!latin:J acceptable residual 84 • . -. -. . • ....--c-.,--,ccc:",. ''-:.cc=,7_ . .:,::-;--. , .. ·-··-........ ,-....... ·---. -....... -----·--·. I I I I I I I I I I I- I I I I I I I C-REMNCSU2jWP5.2 12/22/86 o:mtamination levels onsite. Acceptal:>le exposure levels for potential receptors will be identified (fran the EA) . and ansite clearrup l:.-M!ls will then be estbnated by extrapolatinJ fran reoept:or points back to so.iroe areas, along critical migration pathways. Devel01,i121xt of response a,jectives will also inclme :ref:inenelxt of ARARs specific to the NCSO site. 5.1.2 Identification of Applicable Tec:hnolcxdes and Assembly of Alternatives Based on the rerredlal response objectives, a list of applicable technologies will be identified. 'Ihls list will contain technologies previously diso•ssed in Section 3.0. After potential remedial technologies have been aiosen, operable units will be defined for eadl site condition requirin;J remediation. Each operable unit should meet at least one response a,jective. After these operable units have been compiled, any ~te i;tiasin;J of them will _be cansidered. Depel'ldin; on site conditions and the adequacy of RI results, a i;tiased approach may be desirable. After operable units have been defined, reJTEdi al alternatives will be identified. Each remedial alternative will be an cwerall site remedy. 'lhe no-action alternative will be cansidered as a :baseline against wch the other alternatives can be evaluated. Alternatives wch can be classified in each of the classes of alternatives required by the NCI? will be identified. 5.1.3 Screening of Remedial Technologies/Alternatives 'lhe lists of technologies and alternatives discussed previously will be screened. 'lhe a,jective of this effort is to eliminate frail further cansideration any technologies and alternatives that have uroesirable results regardirg cost, acoeptable engineering practices, and 85 -,.. -I I I 1· I I I I I I I I I I I I I I I C-~CSU2,IWP5. 3 12/22/86 effectiveness as described in the NCP Sectian 300.68(g). 'nlese elimination criteria are as follows: o Alternatives/technologies which have significant adverse envircnmental er health illlpact durin;1 illlplementatian, o Alternatives/technologies whic:h do not adequately protect the environment am pmllc health acocrding to the risk asssessrnent am ARAlls, o Alternatives/technologies far whic:h technical feasibility is either difficult er not proven, am o Alternatives/technologies whic:h have CXlSts an order of magnim:ie greater than other alternatives b.It do not provide greater environmental er ?Jblic health benefits er reliability. :Reasons far elimination of aey alternatives at this stage will be documented in the FS LefOL t. 5.2 RE2-lEDIAL AI:raRNATIVES EVAlllATIOO' ('l7\SK 10) 'lhe I'el!l9dial alternatives whic:h pass the initial ~ PL™ (see Task 9, SUl:isectian 5.1) will be further evaluated am oc:mq,ared as req.lixed in the NCP, Sec:tian 300.68(h), SUbpart F. 'lhis evaluation will be based an five factors includirg technical aspects, ?Jblic health protection, cost, environmental illlpact, am institutional requirements. Also, an evaluation of 1o'hether recycle/reuse, waste miniJnizatian, er destruc:tian of wastes is awiop1.iate to reliably miniJnize pzwurt: er future threats to ?Jblic health, welfare, er the envi.rcnment will be made. Preference will be given to alternatives which result in a pez:manent solution, pursuant to Section 121 of SARA. 5.2.1 Technical Evaluation Fac:h alternative will be evaluated for perfo=, reliability, implementability, am safety. Perfo= will be evaluated in terms of effectiveness am useful life. OJnsistent with SARA, alternatives lfflic:h 86 'I. -- 1 I I I I I I I I I I I I I I I I I ·-------. _...:. ... ·----··--·-······•· ----•······--·-···· c-REMNCSU2/WP5.4 12/22/86 may regµire lc:in:rterm management arx1,/ar im:mitoring are ocnsidered less effective than altematives wch eliminate this need. Reliability will be evaluated based en cperatien am maintenance reqµirements am the de:mcnstrated perfomance of the remedial technologies involved. Iq>lementability will be evaluated with respect to ocnstructability am time. ~ the analysis of oanst%uctability, 0C!Xlitions onsite am extemal to the site will be ocnsidered. Time analysis will include an estimate of the time required to in;;ilement the altemative as well as the time required to achieve beneficial results. Safety evaluations will include both the short-tent am larg-tent threats to the safety of neamy comnumities, envitam,ents, am 1olOikers onsite. In aclditicn, each altemative will be defined with emi;rasis en use of establishe::l. technologies. 5. 2. 2 Risk Assessment An FA will be c::oooucted as part of Task 6-~ AssesSIIJeT'lt. 'lhi.s baseline assessment, wch is an evaluatien of the site without further rerrediaJ actien, is also a detaile:l evaluatien of the oo-actien altemative. 'Ihe renainin;J altematives IILISt be evaluated in tlo.'O ways. One is the developnent of target chemical concentrations. 'lliese target concentraticns represent numerical criteria to judge oonfomance with certain ARARs wch do net define such criteria. 'lliese target concentraticns ar actien levels help to define design goals far the rerrediaJ actien am are used as points of c:aqiariscn to the baseline evaluatien. In the selectien of target chemical concentrations, the steps will include selectien of in:licator chemicals, identificatien of exposure pathways, am the selectien of the target concentraticns. Additional selectien of target concentrations will be based en ARARs if they are available or calo.tlated usin;J toxicity arxi chemical intake data developed durin;J the baseline asses5Jllel'i:. 'lliese target chemical concentraticns, in ocnjunctien with envi.rormeltal fate am transIXJrt analyses, will then be used to calo.tlate allowable release rates of chemicals at exposure points ard actien levels far removal ox mxtxol. 87 I I I I I I I I I 11 I I I I I I I I I C-m1NCSU2/WP5. 5 12/22/86 'lhe seooI¥i type of evaluation is the •ssessment arxl canparlson of the risks to public health arxl the environment fran ead!. alternative, after the alternative has been fully defined. steps edmiJar to these diso1ssed far the baseline '!ssessreM: will be used in these evaluations. 5.2.3 Cost Evaluation · A detailed cost analysis will be perfOllDE!d far each alternative arxl will consist of the follcwin:;J steps: o EstiJDate capital arxl operation arxl ma.intenaooe 006ts, o calollate anrrual costs and pt w UJL 'Wtlrth, o Evaluate the sensitivity of cost estimates to d'larXJeS in key parameters such !11'1 discrunt rates, arxl o SU!m!larize data used in the alternative analysis. For ead!. alternative the cost will be estimated within a ran;re of -30 to +50 percent. 'lhe cost analysis will incl.we separate evaluation of capital and operation arxl ma.intenaooe costs. capital costs will consist of short-terJD ~latian costs such as ~design fees, materials arxl equipient, canstructian, arxl offsite trea'bnent er cilsposa.l. Operation arxl ma.intenaooe costs will consist of lan;-terJD costs associated with operatirg arxl mcnitorin; the rernecUaJ actions arxl the ~ re-evaluation of alternatives were hazardc:Als constituents ~ ansite are n:rt: .i!mnobilized er rendered nonhazamc,.is. For lan;- term remedial alternatives, annual operation arxl ma.intenaooe costs will be based an a time of 30 years far cc:mparison of alternatives wc:h may reqJire substantially lan;er design times. A di so::unt rate of 10 percent will be assumed far all present-wrth calollatians. Cost estimates will be prepared using data fran the REM m Project team files, the current USEPA ~al Action Ccstim Procedures Marnia], USEPA technical Xi:fCU.U, arxl quotations fran equipient 88 I I I I I I I I I I I I I I I I ,. I I C-Im!NCSU2/WP5.6 12/22/86 vemors. F.quipnent replacement costs will be inc:lujed imen the reqJ.il:ed perfcmnance period EWCeeis equipnent design life. 5. 2. 4 Envlf 01 mm ,1 aJ AssesSlllF'!Tt 'Ihe environmental. evaluatiai will fOOJS cm the site pra:,lems arxi pathways of contaminatien acblally addressed by the alternative. 'lhiJ: essessrner+: · will deteDlline to what degree the alternative will protect arxi ilrprcve the environment. Adverse environmental. illpl.c:ts of implementatien of the alternatives will be fully described. I<hcwn environmental. problems not addressed by the alternative will be described. 'Ihe level of detail in the environmental assessmeM: will deperxi en the degree of acb.lal or potential da1nage to ~ environment beirg evaluated. A detailec:1 2'ssessme..+-will be perfomed for the no-actien alternative. 'Ihis 2'Sses~ will deteDlline the value of o.irrently or pc,tentially contaminated areas, identify possible environmental impacts, arxi assess the significan::e of such impacts. other alternatives will be assessed in detail if adverse effects en the environment are expected to occur as a result of the response actien. 5.2.5 Institutional ~elteJrts As discussed in SUl:sectien 3.2.1, l\RARs m.JSt be COJ'lSidered durin; the detailed evaluatien of alternatives. Prior to the ARAR confo:cnaooe evaluatien, site specific and alternative specific ARARs will have been defined. For site specific ARAR evaluatiai, actien levels developed will be set to provide specific numerical criteria. turin; the detailed analysis step, each alternative JmJSt be evaluated to the extent for i.duch it attains or evreeds l\Rl\Rs. other Federal criteria and advisories will also be ccnsidered, as ~rlate. In aclditien to an analysis of CXITPliance with ARARs, cx,ordinatien with other affected Federal and North Carolina agercles will be implemented as required for specific alternatives. 89 ir ··" I I I I I I I I I 11 I I ii I I I I I ..•. --.-, __ ·-·"·-"·• ... ·a , .• ~.:,;-,--:-:-:","a:-=c, :,---.-.. -.. c--'.-. -__ -.. --.:·-::-:·c-···· ---· 5.3 FFASIBILI'lY S'll.lI7.t REKJRI· (USK ll) Task ll will can.sist of the followirq subtasks: C-mlNCStl2/WPS. 7 12/22/86 o SUl!lmarlze eadl alternative in tems of detailed tedlnolcgy, reliability, :!nplenentability, pJ!:>lic health, envh011111=11t, institutional requirements, arxl oost evaluation; o CmpaT"<! the rerrs'li al alternatives; and o Prepare the PS lep.11. t. 'nle PS tep.u:t will inc1ucle an executive S\llml'alY, an introduction, a description of the screenirq an:l. evaluatior, p:ti:,xoses, an:i the teO.illllleroation of a selected alternative. 'nle RI/PS report will inc1ucle a Slllml'alY of the detailed technical an:l oost evaluations an:l a oc:mpatative evaluation of the ren..-HaJ alternatives. 'Ihis Slllml'alY will · be presented as table matrices. Backup .info:rmation and calo.ll.aticns will be included as appen:lices. 'nle PS lE!fX».t will be in::otpotat..:d into an overall RI/PS 1eport. 'Jhis overall teµ,it will inc1ucle the revised draft RI report arxl the FA, inc:otporatin; USEPA Oiiiii~S. 'Ihis report will be produced in draft arxl final foll!IS. · If Task l2 is requested as a oc:mtxinent of the RI/PS, the final PS will inc1ucle a responsiveness Sl.ll!lllalY arxl the selected temedy. 5.4 FOS'I'-RI/PS SUPRJRI· (TASK 12) nie REM m teall! will ptOYide suwcrt to USEPA for aey requested assistance in activities wru.dl occur after NcstJ site RI/PS is completed • . 'nle scope arxl J::uiget for this effort, if 118ede:J. will be detetmined in meetin;s the USEPA after the RI/PS :i:ep.u:t is~ arxl ~ ac:tivities identified. SUppott <XlUld includP cornrnnrdty relations, BOD assistance, Responsiveness SUmmal:y suwart, an:1/or assistance to the U.S. Arnrj Cm:ps of Ergineers or others involved in the T'P!QE!rliaJ design/rerredi aJ ac:ticn. 90 r7•-c-.-,-__ .. _-,-_____ --,-___ .... , ...... =::-. ___ :-:-. __ -=,-____ ..,,_ ___ ~~--.-c=..... .. . -.. . I I I I I I I I I 11 I I I I I I I I 6. 0 ffiOJECI' MANAGEMEN1' APProACl;I 6 .1 ~00 AND ~ C-RE2'lNCSU2/WP6 .1 12/22/86 'lhe proposed project organization is shown in Figure 6-1. 'lhe REM III Regional Manager ~, Mr. PusseJJ H. Boyd, Jr., P.E., is responsible for the quality of all 1"'0rk perform.cl in Region rl. Mr. Boyd is suw iLled by a technical review staff at the REM III Zone Project Management Office (ZFM:>) in ArlirxJtcn, Virginia. He monitors the pl.Cyte&. of each WoJ:x Assignment to ensure adequate resaJrCeS are available and that major problems are anticipated and prevented or minimized. 'lhe RM's review concentrates on the technical quality, sdleclule, and cost for the Work As:.lgnaeut. 'lhe Site Manager (SM) , Ms. Carolyn ~J J , has primary responsibility and authority for ilrplementing and exeo.Iting the RI/FS for the site. SUpporting the SM are the Field Operations leader (FOL), FS Task Manager, and other technical support staff. 'llle FOL is responsible for the onsite management of activities for the duration of the site investigation. 'lhe FS leader is responsible for the ilrpleirentation and preparation of the FS tepcu:L. 'llle task numbering system used follows USEPA starrlard approach. 'lhe tasks to be perfotmed during the RI/FS process at the NCSU lot 86 site investigation are as follows: Task 1-Ptoject Planning Task 3-Field Investigation Task 4-Sa!!ple Analysis/Validation Task 5-~ta Evaluation Task 6-Risk Assessuert Task a-Remedial Investigation Report Task 9-Remedial Alternatives Screening Task 10-Remedial Alternatives Evaluation Task 11-Feasibility study Report 91 "' N ----- - -·-- - - - - - -·-· ·- D4/NCSU. 1 .p I ESE DESIGNATED LEAP I BfM.lll EPA OPQ REGIONAL MANAGER ............ ... ,,,, ••• ,.. D. Bruderty J. Orban ; . R.H. Boyd , , • , , • , , EPA RPM SIIE MANAGER ~ ............................ ~ ............ D. Pulfer C. Poppell .............. COMPANY HEALIH ANO SAFEIY Sl/PEBYISOR C. Haurv HEALIH & SAFEIY OFFICER D. Endicott I I I GEQPHYSICS lIECHNOSl LA!;!QRAIOBY SEBVICES SUBCONIRACIQRS A. Benson !.OOBDINAIQR Drilling L. Bare Surveys/Mapping , ' General Services I CONTRACT I REM Ill LAB I Transport/Disposal LABORATORY Excavation PROGRAM (CLP) I I Bl !AS~ MANAGER FIELO QPERAIIONS FS !AS~ MANAGER -LEADER C. Poppell W. Quarles L. Carter I I I RI PROJECTTEAM FIELD TEAM FS PROJECT TEAM Figure 6-1 NCSU SITE RI/FS PROJECT ORGANIZATION ENVIRONMENTAL SCIENCE AND ENGINEERING, INC. SOURCE: ESE, 1987. --,---·---·. --·-···-·· '-··· ... . , __ ·-•·· .· .. ,_: ·.-_. _, .. ·····•··-·-.. ·•···. I I I I I I I I I I I I I I I I I I C-REl!NCSU2/WP6. 2 12/22/86 'lhe followin:J st:ardaJ:d tasks are not inclooed in this Work Plan: Task 2---ccmmmity Relatiais Task 7--'l'reatability study/Pilot Testin;J Task 12-Post-RI/FS SUfp.,rt 'lbe RI/FS tasks inclooed in this WP, in addition to a schedule and 1::mget, cc.mprise the baseline plans 'lotlich fODD an integrata:i management infonnation system again.st 'lotlich Work Assignment progress can be measured. 'Ille baseline plans are a precise cles=iptian of hew the 'WOrk assignment will be executed in tenns of scqie, schedule, and l::u:lget. 'Ille project schedule and detailed exist estimate are presented in Sectians 6.3 and 6.4, :tespectively. F.ach RI/FS task will be scheduled, J::ujgeted, and tracked separately throughait the duration of the investigation. Monthly p:i:cgre5$ reports will be prepared and subnitted to Region r:v. Regularly scheduled progress relTi.ew neetirgs will be held to evaluate project status, disa1ss current items of interest, and review project staffing. Regularly scheduled telephone meetings will be held, ~iaJJy during site activities, between the SM and the USEPA MM. 6.2 ~ ASSURANCE AND lY\V. ~ '!he site specific quality assuJ:'CIIre requirements will be in accordance with the Q.Jality Assurance Project Plan for the REM m prcg1am, as approved by USEPA. Cata nanagement aspects of the prcg:i:am pertain to controlling and filing documents. Eba= Savices Incorporata:i (Eba=) has developed _a REM m prcg:i:am filing system (klministrative Guideline NUmber PA-5) that conforms to the requixements of the USEPA and the REM m iJicgtam to ensure that the integrity of the documents is safegua:i:ded. '!his 93 I I I I I I I I I I I 1 11 I I I I I I I ----··~-• ... ·-·-···----·~ -. •· . ..: .. c-JID,!NCSU2jWP6.3 12/22/86 guideline will !:le ini>lemented tu o::ail.tol and file all doc:unents associated with the NCSU RifiS. 'Ihe system includes dr.nDIJPnt receipt o:111b.ol procedures, a file review ard inspection system, ard security measures to !:le follawed.. · 6.3 :ER'.lJECl' SOlEllJIE 'Ihe project schedule (Figure 6-2) shows the tasks am activities for the RifiS. 'Ihe schedule for the field investigation is l:lased an no site acness restrictions am USEPA awrovaJ. to prooee:l with the work pr, lfased in the WP by March 16, 1987. If the -work is performed a=rdirg to the schedule shown in Figure 6-2, the project CX>Ul.d !:le c:aipleted by May 1988, as51.111Un;J no Erase II work is required. 6. 4 DETAIUD crsr ESTlMAn: 'Ihe esti=ted costs for the NCSU Site RifiS are presented urx:ler separate cover in the OF-60. Table 6-1 presents the IDE ha.Rs by grade level ani project task. CU> costs and data validation for CU> analyses are not included in the m-t m total c:cst. Costs for potential additional investigations, such as berdy'pilot studies, are not included in the esti=tes for this WP. 'lhe c:cst estiltate is l:lased on the assurrption that health and safety personnel protection equipnent requirements are Level D, except durinJ excavation of the surface soils in the c:hemic:al waste ~ area, lmen Ievel. C is assumed. In a=rclance with the site specific !IMP, Level B safety equiiffii!nt will !:le available, if needed, durlrr; excavation activities. Costs associated with this requirement are inclu:led in the c:cst esti=te. 94 --- - JANUARY 13, 1987 Figure 6-2 TASK f1A PROJECT PLANS ORIGINAL OVERSIGHT EFFORT DEVELOP WORK PLAN MEMORANDUM EVALUATE EXISTING DATA - 1986 Sep Oct 15 13 A=====. A======= ••• ... - Nov Dec 10 8 - - - - -- - NC STATE RI/FS TOTAL WORK PLAN SCHEDULE 1987 Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov 22 12 9 9 6 4 29 27 17 31 28 19 2 EPA APPROVE WP MEMORANDUM INTERIM HEALTH & SAFETY PLAN KICKOFF MEETING & SITE VISIT DRAFT SITE CHARACTERIZATION DEVELOP RI/FS LOGIC A A A A A •• FIELD SAMPLING & ANALYSIS PLAN A COMPLETE DRAFT WORK PLAN A SITE HEALTH & SAFETY PLAN A SITE MANAGEMENT PLAN A QC REVIEW SAMPLING/ANAL PLAN A QC REVIEW SITE MANAGEMENT PLAN A QC REVIEW HEALTH & SAFETY PLAN A QC REVIEW DRAFT WORK PLAN A ISSUE DRAFT FIELD OPER PLAN C ISSUE DRAFT WORK PLAN C EPA REVIEW DRAFT FIELD OP PLAN C EPA REVIEW DRAFT WORK PLAN C INCORP COMMENT ISSUE FINAL FOP C INCORP COMMENTS ISSUE FINAL WP C EPA APPROVE WORK PLAN C OBTAIN SITE ACCESS OBTAIN DISPOSAL PERMIT TASK f1B REMEDIAL ALTERNATIVES DRAFT DATA QUALITY OBJECTIVES D REMEDIAL ALTERNATIVE SCREENING D DQO WORKING SESSION D A= COMPLETE C = CRITICAL PATH •= .======. == =• .• =====. ====== ====== == •• •= == .CCC .CCC cccc cccc CCC CCC .cccccc .=== ====== - --- --· L I 1988 Dec Jan Feb Mar Apr May Jun 30 14 11 25 22 21 18 16 13 --- -- - - - - - -- - -- - - Figure 6-2 NC STATE RI/FS TOTAL WORK PLAN SCHEDULE 1986 TASK #3 SITE INVESTIGATION BACKGROUND RECORDS SEARCH GEOPHYSICAL SURVEY MOBILIZE SITE TEAM INTERPRET GEOPHYS DATA COLLECT SURFACE SOIL SAMPLES DRILL MOB/CONSRT OECON FACILIT C UNCOVER TRENCHES . ORILL WELLS/SUBSURF SAMPLING C LOCATE SOIL BORINGS PROBE 5 LOCATIONS IN TRENCHES DEVELOP WELLS PERFORM LANO SURVEY SAMPLE RESIDENTAL WELL COLLECT WELL SAMPLES PUMP TEST DEVELOP DRUM TRANSPORT SPEC PREPARE SURVEY SPEC DEVELOP GENERAL SERVICE SPEC PREPARE DRILLING SPEC PREPARE EXCAVATION SPEC QC REVW/ISSUE SURVEY INQUIRY QC REVW/ISSUE DRUM TRANSP INQ QC REVW/ISSUE GEN SERV INQUIRY QC REVW/ISSUE EXCAVATE INQUIRY C C C QC REVW/ISSUE DRILLING INQUIRY C GENL SERVICE SPEC BID PERIOD SURVEY BID PERIOD DRUM TRANSPORT BID PERIOD EXCAVATION BID PERIOD DRILLING BIO PERIOD C EVALUATE/AWARD GENERAL SERVICE EVALUATE/AWARD SURVEY EVALUATE/AWARD DRUM TRANSP EVALUATE/AWARD EXCAVATION EVALUATE/AWARD DRILLING C Sep Oct 15 13 1987 Nov Dec Jan 1D 8 22 12 Feb 9 Mar 9 Apr 6 .====. ==== .. May 4 Jun Jul Aug Sep Oct Nov 29 27 17 31 28 19 2 .CCC == . cccccccc = == .CCC. .===== • cc .=== .=== .cccc. ==== ==== ==== === CCC =====. .====== .====== cccccc =====. .====. .====. ====== . ccccc 1988 Dec Jan Feb Mar Apr May 3D 14 11 25 22 21 18 16 - Jun 13 'D ...., -- -- - --- -- - - ---- - Figure 6-2 NC STATE RI/FS TOTAL WORK PLAN SCHEDULE 1986 Sep Oct 15 13 TASK 14 SAMPLE ANALYSIS/DATA VALIDATION LAB ANALYSIS SURFACE SOIL SAMP DATA VALIDATION SURFACE SOILS LAB ANALYSIS SUBSURF SOILS DATA VALIDATION·SUBSURF SOILS CLP SAMPLE ANALYSIS REMIII LAB ANALYSIS DATA VALIDATE GW SAMPLES TASK 15 DATA EVALUATION DATA EVALUATE-SURFACE SOILS EVALUATE PUMP TEST DATA DATA EVALUATE·SUBSURF SOILS EVALUATE GW CHEM DATA INTERPRET/CONSOLIDATE DATA INTERIM STATUS MEETING w/EPA TASK 16 RISK ASSESSMENT CONTAMINATION ASSESSMENT RISK ASSESSMENT (CHEM SELECT) C C C C C C C RISK ASSESSMENT (FATE & TRANS) RISK ASSESSMENT (EXPOSE ASSESS) C RISK ASSESSMENT (TOXICITY) RISK CHARACTERIZATION TASK 17 TREATABILITY STUDY TREATABILITY·SPEC/IN·SITU TREATABI/ISSUE INQUIRY/IN-SITU TREATABLTY·BID PERIOD/IN-SITU TREATIBILITY·EVAL BID/IN·SITU TREATABILITY·AWARD IN·SITU PERFORM TREAT STUDY·IN·SITU C C 1987 Nov Dec Jan 10 8 22 12 Feb 9 Mar 9 Apr May 6 4 Jun 1 --i:z-----. ===== Jul Aug Sep Oct Nov 29 27 17 31 28 19 2 • === ====== ccccccc. CCC 1988 Dec Jan Feb Mar Apr Nay 30 14 11 25 22 21 18 16 ==. === .==== .===. ===== cc CCC C ccccc. cc cccccc cccccc • CCC ====. === ■ ----=-----==. - Jun 13 --- - - - - - - -- - Figure 6-2 NC STATE RI/FS TOTAL YORK PLAN SCHEDULE TASK 17 TREATABILITY STUDY (cont) TREATABILITY·GRND YATER•SPEC TREATABILITY·INQRY·GRND YATER TREATABILITY·BID PERIOD·GRD YT TREAT-EVALUATE BIDS·GRND YATER TREAT·AYARD GROUND YTR TREAT PERFORM GRND YATER TREAT STUDT TASK 18 REMEDIAL INVESTIGATION COMPLETE DRAFT RI REPORT QC REVY/ISSUE DRAFT RI EPA REVIEW DRAFT RI REPORT REVISE DRAFT RI TO DRFT FINAL QC REW /ISSUE DRFT FINAL RI EPA REVY DRAFT FINAL RI REVISE RI TO FINAL 1986 C C C C Sep Oct 15 13 TASK 19 REMEDIAL ALTERNATIVE SCREENING REM ALT-SCREEN TECHNOLOGIES REM ALT-DEVELOP RESPONSE OBJT TASK 110 REMEDIAL ALTERNATIVE EVALUATION REM ALTERNATIVE EVALUATION REM ALT-PUBLIC HEALTH EVALUATE 1987 Nov Dec Jan 10 8 22 12 TASK 111 REMEDIAL INVESTIGATION/FEASIBILITY STUDT REPORTS PREL DRAFT FS REPORT COMPLETE PRELIMINARY FS REPORT C QC REVY/ISSUE DRAFT FS REPORT C EPA REVY DRAFT FS REPORT C REVISE FS REPORT TO FINAL C ISSUE FINAL RI/FS REPORT C Feb 9 Mar 9 Apr May Jun 6 4 Jul Aug Sep Oct Nov 29 27 17 31 28 19 2 ======== ==== - - - - 1988 Dec Jan Feb Mar Apr Mey 30 14 11 25 22 21 18 16 • zi::a:::s:1ui:11ca:■ • cccc CCC ccccc .ccccc .••····· •••• =========== cc .CCC cccc ccccc .c - Jun 13 _ .. I j ' \0 \0 -- -- JANUARY 13, 1987 Figure 6-2 -- - ---- - - NC STATE RI/FS TOTAL WORK PLAN SCHEDULE Early Early Late ·ACTIVITY Durst ion Start F ;ntsh Start - - - late Finish ······························ ........... ................. ···-··········--· ·-··············· TASK #1 PROJECT PLANS ORIGINAL OVERSIGHT EFFORT 4D days DEVELOP WORK PLAN MEMORANDUM 20· days EVALUATE EXISTING DATA 26 days EPA APPROVE WP MEMORANDUM 10 days INTERIM HEALTH & SAFETY PLAN 5 days KICKOFF MEETING & SITE VISIT 5 days DRAFT SITE CHARACTERIZATION 8 days DEVELOP RI/FS LOGIC 5 days FIELD SAMPLING & ANALYSIS PLAN 23 days COMPLETE DRAFT WORK PLAN 18 days SITE HEALTH & SAFETY PLAN 18 days SITE MANAGEMENT PLAN 18 days QC REVIEW. SAMPLING/ANAL PLAN 5 days QC REVIEW SITE MANAGEMENT PLAN QC REVIEW HEALTH & SAFETY PLAN QC REVIEW DRAFT WORK PLAN ISSUE DRAFT FIELD OPER PLAN ISSUE DRAFT WORK PLAN EPA REVIEW DRAFT WORK PLAN EPA REVIEW DRAFT FIELD OP PLAN INCORP COMMENT ISSUE FINAL FOP INCORP COMMENTS ISSUE FINAL WP EPA APPROVE WORK PLAN OBTAIN SITE ACCESS OBTAIN DISPOSAL PERMIT TASK 118 REMEDIAL ALTERNATIVES 4 days 4 days 4 days 11 days 11 days 15 days 15 days 10 days 10 days 15 days 10 days 30 days DRAFT DATA QUALITY OBJECTIVES 8 days REMEDIAL ALTERNATIVE SCREENING 8 days DQO WORKING SESSION 1 day 2-Jun-86 15-Sep-86 15-Sep-86 13-0ct-86 21-0ct-86 28·0ct·86 4-Nov-86 14·Nov-86 17-Nov-86 21-Nov-86 25·Nov·86 25-Nov-86 22·Dec·86 23·Dec·86 23-Dec-86 23-Dec-86 2-Jan-87 2-Jan-87 19-Jan-87 19-Jan-87 9·Feb·87 9-Feb-87 23·Feb·87 16-Mar-87 30-Mar-87 4·Nov'86 4-Nov-86 14-Nov-86 28-Jul-86 10-0ct-86 20-0ct-86 24-0ct·86 27-0ct-86 3-Nov-86 )3-Nov-86 20-Nov-86 19-Dec-86 18-Dec-86 22-Dec-86 22-Dec-86 30-Dec-86 30-Dec-86 30-Dec-86 30·Dec·86 16-Jan-87 16·Jan·87 6·Feb·87 6-Feb-87 20·Feb·87 20-Feb·87 13-Mar-87 27-Mar-87 8-May-87 13-Nov-86 13·Nov·86 14-Nov-86 1 ·Apr-88 24·Sep·86 16·Sep·86 13-May-88 22-0ct-86 29·0ct·86 6-Nov-86 18-Nov-86 18-Nov-86 25-Nov-86 26-Nov-86 26-Nov-86 23-Dec-86 24-Dec-86 24-Dec-86 24·Dec-86 2·Jan-87 2·Jan·87 19·Jan-87 19-Jan-87 9·Feb·87 9-Feb-87 23·Feb·87 13-Apr-87 27-Apr-87 5-Nov-86 17-May-88 17-Nov-86 26-May-88 21-0ct-86 21-0ct-86 26-May-88 28-0ct-86 4-Nov-86 17-Nov-86 24-Nov-86 22-Dec-86 22-Dec-86 23-Dec-86 23-Dec-86 31-Dec-86 31-Dec-86 31-Dec-86 31-Dec-86 16-Jan-87 16-Jan-87 6-Feb-87 6-Feb-87 20-Feb-87 20-Feb-87 13-Mar-87 24-Apr-87 5-Jun-87 14-Nov-86 26·May-88 17-Nov-86 . -- .... 0 0 --- - ---- -- - -- - - NC STATE RI/FS TOTAL WORK PLAN SCHEDULE Figure 6-2 Early Early Late late ACTIVITY Duration Start Finish Start Ftnfah TASK #3 SITE INVESTIGATION BACKGROUND RECORDS SEARCH 15 days GEOPHYSICAL SURVEY 7 days MOBILIZE SITE TEAM 10 days INTERPRET GEOPHYS DATA 15 days COLLECT SURFACE SOIL SAMPLES 3 days DRILL MOB/CONSRT DECON FACILIT 10 days UNCOVER TRENCHES 5 days DRILL WELLS 27 days SUBSURFACE SOILS INVESTIGATION 27 days LOCATE SOIL BORINGS 1 day PROBE 5.LOCATIONS IN TRENCHES 5 days DEVELOP WELLS 10 days PERFORM LAND SURVEY 15 days SAMPLE RESIDENTAL WELL 1 day COLLECT MONITOR WELL SAMPLES 7 days PUMP TEST DEVELOP DRUM TRANSPORT SPEC PREPARE SURVEY SPEC DEVELOP GENERAL SERVICE SPEC PREPARE DRILLING SPEC PREPARE EXCAVATION SPEC QC REVW/ISSUE DRUM TRANSP INQ QC REVW/ISSUE SURVEY INQUIRY QC REVW/ISSUE GEN SERV INQUIRY QC REVW/ISSUE EXCAVATE INQUIRY QC REVW/ISSUE DRILLING INQUIRY GENL SERVICE SPEC BID PERIOD SURVEY BID PERIOD DRUM TRANSPORT BID PERIOD EXCAVATION BID PERIOD DRILLING BID PERIOD EVALUATE/AWARD GENERAL SERVICE EVALUATE/AWARD SURVEY EVALUATE/AWARD DRUM TRANSP EVALUATE/AWARD EXCAVATION EVALUATE/AWARD DRILLING 3 days 10 days 10 days 10 days 15 days 15 days 10 days 10 days 5 days 10 days 10 days 20 days 20 days 20 days 20 days 20 days 10 days 10 days 10 days 20 days 15 days 16·Mar·B7 3D·Mar·87 30-Mar-87 8·Apr·87 13·Apr·87 8-Jun-87 22·Jun·87 22-Jun-87 22·Jun·87 29·Jun·87 29-Jun-87 30·Jul·87 30·Jul·87 13·Aug-87 13·Aug•87 24·Aug·87 16-Mar-87 16·Mar·87 16•Mar·87 16·Mar·87 16·Mar·87 30-Mar-87 30-Mar-87 30-Mar-87 6·Apr·87 6·Apr·87 6·Apr·87 13·Apr·87 13·Apr·87 20·Apr·87 20·Apr·87 4·May-87 11 ·May-87 11·May·87 18· May-87 18·May-87 3·Apr·87 7·Apr·87 10·Apr·87 28·Apr·87 15·Apr·87 19·Jun·87 26·Jun·87 29-Jul-87 29· Jul ·87 29·Jun·87 3·Jul·87 12·Aug•87 19-Aug-87 13·Aug·87 21 ·Aug•87 26-Aug-87 27·Mar·87 27·Mar·87 27-Mar-87 3·Apr·87 3·Apr·87 10·Apr·87 10-Apr-87 3·Apr·87 17·Apr·87 17·Apr·87 1 ·May-87 8-May-87 8·May-87 15-May-87 15·May·87 15-May-87 22-May-87 22·May·87 12-Jun-87 5·Jun·87 6·May-88 26·Apr·88 25 ·May-87 5-May-88 30·Jul·87 8-Jun-87 13·Aug·87 22-Jun-87 10-Jul ·87 26·May·88 20-Aug-87 30·Jul·87 30·Dec·87 24-Aug-87 13·Aug•87 25·Sep·87 3-Jun-87 16·0ct·87 6-Apr-87 16-Mar-87 13-May-87 17-Jun-87 30-0ct-87 20·Apr·87 3-Jun-87 6·Apr·87 27·Apr·87 13-Nov-87 1·Jul·87 17-Jun-87 20·Apr·87 25 ·May-87 15-Dec-87 30·Jul·87 16· Jul ·87 18-May-87 26·May·88 4·May•88 5-Jun-87 25·May•88 3·Aug-87 19-Jun-87 19·Aug·87 29•Jul·87 17·Aug•87 26·May-88 26·Aug•87 12·Aug•87 20•Jan·88 24·Aug•87 21 ·Aug-87 29·Sep·87 16·Jun·87 29·0ct·87 17·Apr·87 3·Apr·87 2-Jun-87 30·Jun·87 12-Nov-87 24·Apr·87 16-Jun-87 17·Apr·87 22·May•87 14-Dec-87 29·Jul·87 15·Jul·87 15-May-87 5-Jun-87 29-Dec-87 12·Aug·87 12-Aug-87 5-Jun-87 -- - ,_. 0 ,_. ----- --- - -- -- - - - NC STATE RI/FS TOTAL WORK PLAN SCHEDULE Figure 6-2 Early Early Late Late ACTIVITY Duration Start Finish Start Ftnfsh TASK #4 SAMPLE ANALYSIS/DATA VALIDATION LAB ANALYSIS SURFACE SOIL SAMP 30 days DATA VALIDATION SURFACE SOILS 15 days LAB ANALYSIS SUBSURF SOILS 20 days DATA VALIDATION·SUBSURF SOILS 10 days CLP SAMPLE ANALYSIS 20 days REMIII LAB ANALYSIS 27 days DATA VALIDATE GW SAMPLES 10 days TASK #5 DATA EVALUATION DATA EVALUATE-SURFACE SOILS EVALUATE PUMP TEST DATA DATA EVALUATE·SUBSURF SOILS EVALUATE GW CHEM DATA INTERPRET/CONSOLIDATE DATA INTERIM STATUS MEETING w/EPA TASK t6 RISK ASSESSMENT 5 days 10 days 10 days 5 days 11 days 1 day CONTAMINATION ASSESSMENT 20 days RISK ASSESSMENT (CHEM SELECT) 5 days RISK ASSESSMENT (FATE & TRANS) 15 days RISK ASSESSMENT (EXPOSE ASSESS 20 days RISK ASSESS~ENT (TOXICITY) 20 days RISK CHARACTERIZATION 10 days TASK 17 TREATABILITT STUDT TREATABILITT·SPEC/IN·SITU 15 days TREATABI/ISSUE INQUIRT/IN·SITU 10 days TREATABLTT·BID PERIOD/IN-SITU 15 days TREATIBILITT·EVAL BID/IN-SITU 15 days TREATABILITT·AWARD IN·SITU 10 days PERFORM TREAT STUDT·IN·SITU 45 days 16·Apr·87 28·May·87 30·Jul·87 27·Aug·87 14·Aug·87 14·Aug·87 23-Sep-87 18·Jun·87 27·Aug·87 11·Sep·87 7·0ct·87 14-0ct-87 29·0ct·87 30-0ct-87 1·Dec·87 8-Dec-87 8·Dec·87 8·Dec·87 7-Jan-88 7·Jul·87 28·Jul·87 11 ·Aug-87 1·Sep·87 23·Sep·87 7·0ct·87 27-May-87 17-Jun-87 26·Aug•87 10-Sep-87 11·Sep·87 22-Sep-87 6·0ct·87 24-Jun-87 10·Sep·87 24·Sep·87 13·0ct·87 28·0ct·87 29-0ct-87 30·Nov·87 7-Dec-87 29·Dec·87 6-Jan-88 6·Jan·88 20·Jan·88 27-Jul ·87 10·Aug·87 31·Aug•87 22·Sep·87 6·0ct·87 10·Dec·87 4·Aug·87 16·Sep·87 18·Aug·87 16-Sep-87 25·Aug·87 14·Aug·87 23·Sep·87 7-0ct-87 30·Sep·87 30·Sep·87 7-0ct-87 14-0ct-87 29·0ct·87 30-0ct-87 1 ·Dec-87 15-Dec-87 8·Dec·87 8·Dec·87 7-Jan-88 27·Aug•87 18·Sep·87 2-0ct-87 23-0ct-87 13-Nov-87 1 •Dec·87 15·Sep·87 6-0ct-87 15·Sep·87 29-Sep-87 22·Sep•87 22·Sep·87 6-0ct-87 13-0ct-87 13·0ct·87 13-0ct-87 13-0ct-87 28-0ct-87 29·0ct·87 30-Nov-87 7-Dec-87 6-Jan-88 6·Jan·88 6·Jan·88 20·Jan·88 17-Sep-87 1-0ct-87 22-0ct-87 12-Nov-87 30-Nov-87 3·Feb·88 -- .... 0 N - --- - ---- - - -- - - - Figure 6-2 NC STATE RI/FS TOTAL WORK PLAN SCHEDULE Early Early Late Late ACTIVITY Duration Start Finish Start Ffntah TASK #7 TREATABILITT STUDT (cont) TREATABILITT·GRND WATER-SPEC 20 days TREATABILITT·INQRT·GRND WATER 10 days TREATABILITT·BID PERIOD·GRD WT 20 days TREAT·EVALUATE BIDS·GRND WATER 15 days TREAT-AWARD GROUND WTR TREAT 10 days PERFORM GRND WATER TREAT STUDT 45 days TASK #8 REMEDIAL INVESTIGATION COMPLETE DRAFT RI REPORT QC REVW/ISSUE DRAFT RI EPA REVIEW DRAFT RI REPORT REVISE DRAFT RI TO DRFT FINAL QC REVW /ISSUE DRFT FINAL RI EPA REVW DRAFT FINAL RI REVISE RI TO FINAL 10 days 10 days 15 days 15 days 10 days 15 days 10 days TASK #19 REMEDIAL ALTERNATIVE SCREENING REM ALT·SCREEN TECHNOLOGIES REM ALT-DEVELOP RESPONSE OBJT 15 days 15 days TASK #10 REMEDIAL ALTERNATIVE EVALUATION REM ALTERNATIVE EVALUATION 25 days REM ALT·PUBLIC HEALTH EVALUATE 15 days TASK #11 RI/FS REPORT PREL DRAFT FS REPORT 40 days COMPLETE PRELIMINARY FS REPORT 5 days QC REVW/ISSUE DRAFT FS REPORT 10 days EPA REVW DRAFT FS REPORT 15 days REVISE FS REPORT TO FINAL 10 days ISSUE FINAL RI/FS REPORT 1 day 23·Sep·87 21·0ct·87 4·Nov·87 4·Dec·87 28·Dec·87 12·Jan·88 21·Jan·88 4·Feb·88 18·Feb·88 10·Nar·88 31 ·Nar·88 14·Apr·88 5·Nay•88 14·0ct·87 21·Jan·88 11·Feb·88 25·Feb·88 21·Jan·88 31 ·Nar-88 7·Apr·88 21 ·Apr·88 12·Nay-88 26·Nay·88 20·0ct·87 3·Nov·87 3·Dec·87 24·Dec·B7 11·Jan·88 14·Nar·B8 3·Feb·88 17· Feb-88 9·Nar·88 30·Nar·88 13·Apr·88 4·Nay•88 18·Nay-88 3·Nov·87 10·Feb·88 16·Nar·88 16·Mar·88 16·Nar·88 6·Apr·88 20·Apr·88 11 ·May·88 25 ·Nay-88 26·Nay·88 9·0ct·87 6·Nov·87 20·Nov·87 22·Dec·87 14·Jan·88 28·Jan·88 21·Jan·88 4·Feb·88 18·Feb·88 10·Nar·88 7·Apr·88 21 ·Apr·88 12·Nay·88 14·Jan·88 4·Feb·88 25·Feb·88 10·Nar·88 4·Feb·88 31 ·Nar·88 7·Apr·88 21·Apr·88 12·May·88 26-May-88 5·Nov·87 19·Nov·87 21 ·Dec-87 13·Jan·88 27·Jan·88 30·Mar·88 3·Feb·88 17·Feb·88 9·Nar·88 30·Nar·88 20·Apr·88 11·Nay·88 25·May•88 3·Feb·88 24·Feb·88 30·Nar·88 30·Mar·88 30·Mar·88 6·Apr·88 20·Apr·88 11·Nay·88 25·May·88 26·May-88 -- ,. i: I I ' I - --- - - - ---- -- - - --- DATE: 01/15/87 PAGE: 1 1/Af 64 • 46G7 . NC STATE UNIVERSITY AMENDMENT# 001 Table 6-1 LABOR IIORKHOUR BREAKDOIIM TABLES ----. -. -.. ---.. -----. -. --...... --------.......... ---. ------... --............ -.. -...... -... -........... P4 P3 P2 P1 T2 T1 TOTAL CLER TASK/ DESCRIPTION HOURS HOURS HOURS HOURS HOURS HOURS LOE HOURS -.... -... -.. -. -. ----............ -. ---. -------. --------------············--·····---- 01A PROJECT PLANS 39 418 198 655 170 01B EVALUATION OF REMEDIAL ALTERNATIVES 4 70 18 92 20 TASK TOTAL ···> 43 488 216 747 190 03A BACKGROUNDS RECORDS RESEARCH 44 n n 22 210 25 03B GEOPHYSICAL SURVEY 14 10 308 104 436 24 03C MOBILIZATION/ INITIAL INVESTIGATION 66 106 76 128 16 392 16 030 SUBSURFACE INVESTIGATION 203 473 160 425 8 1269 13 03E SUBCONTRACTING SPECIFICATIONS 25 192 310 62 40 629 125 TASK TOTAL ···> 39 515 1269 298 729 86 2936 203 ... 0 04 SAMPLE ANALYSIS/DATA VALIDATION 82 105 50 237 5 w TASK TOTAL ···> 82 105 50 237 5 05 DATA EVALUATION 30 134 95 105 42 26 432 TASK TOTAL ···> 30 134 95 105 42 26 432 06 RISK ASSESSMENT 45 234 210 84 70 643 190 ! TASK TOTAL ···> 45 234 210 84 70 643 190 07 TREATABILITY STUDY 16 125 32 173 60 TASK TOTAL ···> 16 125 32 173 60 08 REMEDIAL INVESTIGATION 36 138 68 52 76 370 90 TASK TOTAL •. ·> 36 138 68 52 76 370 90 09 REMEDIAL ALTERNATIVE SCREENING 12 92 84 16 204 12 TASK TOTAL ···> 12 92 84 16 204 12 10 REMEDIAL ALTERNATIVE EVALUATION 20 116 102 16 254 6 TASK TOTAL ···> 20 116 102 16 254 6 ---------------------------································-----------------------················-· CONTINUED ON NEXT PAGE ••••• CONFIDENTIAL INFORMATION· DO NOT QUOTE, CITE, OR DUPLICATE ..... 0 .... - -- - - - - - Table 6-1 - -- - - WAI 64·46G7 · N C STATE UNIVERSITY AMENDMENT# 001 LABOR IIORKHClJR BREAKDO\IN TABLES - - DATE: Dl/15/87 PAGE: 2 -·····················································---···································----------P4 Pl P2 P1 T2 T1 TOTAL CLER TASK/ DESCRIPTION HClJRS HClJRS HClJRS HClJRS HClJRS HClJRS LOE HClJRS 11 REMEDIAL INVEST/FEASIBILITY STUDY REPORT 24 210 120 59 413 109 TASK TOTAL • -·> 24 210 120 59 413 109 70 ORIGINAL OVERSIGHT EXPENDITURE 54 22 15 3 94 44 TASK TOTAL -·-> 54 22 15 3 94 44 ············-·-··--·-·-------------------------..............................•..... TOTAL 319 2156 2316 683 n1 25B 6503 909 CONFIDENTIAL INFORMATION· DO NOT QUOTE, CITE, OR DUPLICATE - - .... 0 V, ----- - - - - -- Table 6,-1 MA# 64·46G7 · NC STATE UNIVERSITY AMENDMENT# 001 DETAILED COST ESTIMATE BREAKllOIIH -- ----- DATE: 01/15/87 PAGE: 1 -----------------------·········--------------···············································································-······························· TOTAL *··· 0 THE R D I R E C T COSTS···• TOTAL SUBCONTRACT LAB GRAND TASK/ DESCRIPTION LABOR TRAVEL MATL&SUPL COMPUTER REPORTS MISC ooc•s POOL ANAL TS IS TOTAL ·············------·············------------··· .. ------.... ... ----------······· ........... -. ······-·. ---. .. ----------.. --... -. . . -.. -.. -.. .... ----.... 01A PROJECT PLANS 36,587 2,669 504 3,753 6,927 43,514 018 EVALUATION OF REMEDIAL ALTERNATIVES 5,054 2,208 2,208 7,262 TASK TOTAL ···> 41,641 4,8TT 504 3,753 9,135 50,TT6 03A BACKGROUNDS RECORDS RESEARCH 8,163 4,050 141 471 4,662 12,825 038 GEOPHYSICAL SURVEY 18,279 3,236 3,710 1,797 117 385 9,245 3,15D 30,674 03C MOBILIZATION/ INITIAL INVESTIGATION 14,120 5,469 3,545 2,106 11,119 12,198 37,437 03D SUBSURFACE INVESTIGATION 48,374 26,476 27,424 238 4,366 58,504 106,219 213,097 03E SUBCONTRACTING SPECIFICATIONS 33,527 2,534 59 88 518 1,485 4,684 38,211 TASK TOTAL ···> 122,463 41,764 34,737 2,123 m 8,812 88,214 121,567 332,244 04 SAMPLE ANALYSIS/DATA VALIDATION 11,246 178 119 297 70,790 82,333 TASK TOTAL ·•·> 11,246 178 119 297 70,790 82,333 05 DATA EVALUATION 18,719 1,701 359 580 2,640 21,359 TASK TOTAL···> 18,719 1,701 359 580 2,640 21,359 06 RISK ASSESSMENT 34,595 243 1,650 878 2,770 37,365 TASK TOTAL···> 34,595 243 1,650 878 2,770 37,365 07 TREATABILITT STUDT 10,908 90 181 271 11,179 TASK TOTAL -• -► 10,908 90 181 271 11,179 08 REMEDIAL I NVESTI GA Tl ON 19,148 246 909 1,836 2,991 22,139 TASK TOTAL •••► 19,148 246 909 1,836 2,991 22,139 09 REMEDIAL ALTERNATIVE SCREENING 10,489 10,489 TASK TOTAL •• -► 10,489 10,489 ·········------···············································--------------------------------------------------------------------------------------------- TOTAL COSTS INCLUDE DIRECT SALARY, OVERHEAD, G&A, and ALL FEES OTHER DIRECT COSTS (ODC's) INCLUDE G&A, and ALL FEES CONFIDENTIAL INFORMATION· DO NOT QUOTE, CITE, OR DUPLICATE CONTINUED ON NEXT PAGE ••••• ' ------ Table 6-1 --- - -- WA# 64·46G7 · NC STATE UNIVERSITY AMENDMENT# 001 DETAILED COST ESTIMATE BREAKDOWN - ---- DATE: 01/15/87 PAGE: 2 TOTAL *··· 0 T ff ER DIRECT COSTS···* TOTAL SUBCONTRACT LAB GRAND TASK/ DESCRIPTION LABOR TRAVEL MATL&SUPL COMPUTER REPORTS MISC ooc•s POOL ANALYSIS TOTAL ··············································-............ ------······································· ------------·········· ---------------········ 10 11 70 REMEDIAL ALTERNATIVE EVALUATION TASK TOTAL ••• > 13,185 306 13,185 306 306 306 REMEDIAL INVEST/FEASIBILITY STUDY REPO T 23,797 246 1,623 1,870 1,870 787 787 TASK TOTAL ···> ORIGINAL OVERSIGHT EXPENDITURE TASK TOTAL ... ·> TOTAL 23,797 246 1,623 7,364 401 386 7,364 401 386 313,556 48,342 34,737 3,898 3,827 18,475 109,280 TOTAL COSTS INCLUOE DIRECT SALARY, OVERHEAD, G&A, and ALL FEES OTHER DIRECT COSTS (ODC's) INCLlllE G&A, and ALL FEES CONFIDENTIAL INFORMATION· DO NOT Q\JOTE, CITE, OR DUPLICATE 121,567 70,790 13,491 13,491 25,667 25,667 8,151 8,151 615,193 _, I I R I I I I I I I I I I I I I I I I I I C-:REMt<CSU2/WP6.4 12/22/86 Excavation to identify trench boundaries is considered an optional· task, to be inplemented only if geophysical sw:veys are not effective in definil'J3' waste boundaries. 'lhe cost asscx::iated with this excavation activity is not irx:looed in the total, tut is estilllated at about $79,000. .107 I I I I I I I I I I I I I I I I I . ------------------.. , _ ... :; __ . ···-..... . REFERENCES C-REMNCS.1/SC0PEREF.l 01/13/87 Camp, Dresser & McKee, Inc. (CDM). 1985. Forward Planning Study, N.C. State University, Lot 86 Site. Final Report. Prepared for u.s. Environmental Protection Agency. Atlanta, Georgia. Heater Well Drilling. November 20, 1986. to William A. Quarles, Environmental Engineering, Inc. Re: Geology. Personal communication Science and Liddle, s. 1984. Trace Element Analysis of the Groundwater at a Hazardous Waste Landfill in the Piedmont of North Carolina. M.S. Thesis, Department of Marine, Earth, and Atmospheric Sciences, North Carolina state University. Raleigh, North Carolina. McDade, J.A.1 Won, I.J.1 and Welby, c.w. 1984. Application of Surface Geophysical Methods to the Hydrogeological Evaluation of Waste Disposal sites in North Carolina. Final Report. Prepared for North Carolina Board of Science and Technology. Parker, J.M., III. 1979. Geology and Mineral Resources of Wake County. North Carolina Department of Natural Resources and Community Development. Division of Land Resources, Geological survey Sect~on. Raleigh, North Carolina. i -------··· -- 1 I I I I I I I I I I I I I ·1 I I I EPA mRI< ASSIGNMENI' NO. 64-46G7 UNDER EPA a::m:'RACI' NO. 68-01-7250 EBASCX> SERVICES INCX>RroRATED DRAFT FIElD OPERATICNS PIAN :REMEDIAL JNVESTIGATIOO' AND FFASmILlTl( S'lUDY NORlH CAROLillA STATE UNIVERSIT'll' I!1r 86 SITE :RAI.EIGH, NORIH CAROLillA JANUARY 1987 NOl'ICE 'Ihe infonnation in this document has been furrle:l. by the United states Environmental Protection "/v:Jerct (U.S. EPA) un:ier Rm III Contract No. 68-01-7250 to Ebasco Services, Inc. (Ebasco). 'lhis document is a draft an:i has not been fonnally released by either Ebasco or the U.S. EPA. As a draft, this document should not be cited or quote:i, an:i is bein;J ci=l.ated for oamment only. I I D I I I I I I I I I I I I I I I APPE?IDIX A mAFT FlEID OPERATIONS PIAN REMEDIAL lNVESTIGATION AND FFASIBIU'lY S'lUDY KX NORlli CAROLINA S'I1ITE tlNIVERSITY SITE RALEIGH, NORni CAROLINA JANU1iR'i 1987 ·•-·. • .. I I I I I I I I I I I I I I I I .1 . . . . ·-· . ---•.-~ •.·•·-••. ------. . _. __ . -· -., ... . . -. --- APPENDIX A SECl'ION I DRAFT FIEID SAMPLING AND ANALYSIS PIAN 1·: I I I I I I I I I I I I 11 I I I I I • USEPA WJRI< ASSIGNMENT NUMBER: 64-46G7 tlSEPA cnmlACI' NUMBER: 68-01-7250 EB.?I.SCD SERVICES lliCXlR!/ORATEO I:llAFT FIEID SAMPLING AND ANALYSIS PIAN :REMEDIAL lNVESTIGATIO. AND FFASIBILI'IY S'IUDY AT NORlli CAROLINA STATE UNIVERSITY Im 86 SITE :RAIEIGH, NORlli CAROLINA JANUARY 1987 PREPARED BY: CAROLYN F. FOPPEIL SITE MAN1'GER ENVIRONMENTAL SCIENCE AND ENGINEERING, me. Approved by: s; i:1 fr'/J!!J:#~E'.A Regional Manager, Region IV rllasco Seivices Inco:tp0rated I I I I I I I I I I I I I I I I I I Section 1.0 2.0 3.0 4.0 5.0 6.0 C-:REMNCSU2/FSAPI'OC .1 01/11/87 'l7<BI.E OF CDNTENTS INI'ROruCTION SUMMARY OF SITE RECONNAISSANCE/PRELIMINARY OlARACTERIZATION/Sl\MPLING ACI'IVITIE.S GENERAL FIE1D OPERATIONS 3 .1 PROJECT IDBILIZATION ACI'IVITIES 3. 2 FIElD SAMPLING AND ANALYSIS PIAN 3. 3 SAMPIE CONTAINER REQUIREl-lEN'IS AND HOIDING TIME'S 3. 4 SAMPLE PACKAGING AND SHIPPING 3. 5 IXXllMENrATION 3. 6 mTA ~ OBJECTIVES 3.6.1 Stage One-Definition of Program Objectives 3 .6.2 Stage 'Iwo-Establishment of Analytical ta.ta Quality 3.6.3 Stage 'Ihree-Selection of Analytical and Sampling Options INITIAL FIElD ACI'IVITIE.S 4 .1 MCKGROOND RECORI:s SEARCH 4. 2 GEOFHYSICAL SURVEYS MONITORING WEIL INSTALIATION 5.1 STATIONS 5. 2 MJNI'IORING WEIL CONSTRUCTION PROCEruRES 5.2.1 Construction of Saprolite Monitoring Wells 5.2.2 Construction of Bedrock Monitoring Wells 5.2.3 Protective casing and Cement Pad 5. 3 HANDLING OF DRILL ClJITINGS AND FI.tJICS 5.4 SITE SURVEY SAMPLING PROCEruRES 6.1 SURFACE SOIL SAMPLING 6. 1.1 Stations 6.1.2 Parameters i 1 2 3 3 4 5 5 6 6 7 7 8 9 9 9 11 11 11 11 15 16 17 17 18 18 18 18 I I I I I I I I I I I I I I I II I I Section 7.0 6.2 6.3 6.4 6.1.3 6.1.4 6.1.5 TABIE OF CDNI'ENIS (Ccntinued, Page 2_of 2) Sampling Methods Sample Treatment D.mlicate Samples SlJBSURF1'CE SAMPIES 6.2.1 stations 6.2.2 Parameters 6.2.3 Sampling Methods 6.2.4 · Sample Treatment 6.2.5 P,mlicate Samples GR:XJND WATER SAMPIES 6.3.1 Stations 6.3.2 Parameters 6.3.3 Sampling Methods 6.3.4 Sample Treatment 6.3.5 D.mlicate Samples D;;.UIR-!ENI' DEO:lNrAMINATION OOALI'lY ASSURANCE AND OOALI'lY CONI'ROL C-REMNCSU2,IFSAPTOC.2 12/30/86 Page 18 22 22 27 27 27 28 28 29 29 29 29 33 33 33 34 36 7.1 FIEID INS'rnIJMENT CALIBRATION AND PREVENTIVE MAINI'ENANCE 36 7.2 FIEID BLANKS AND SPIRE'S 36 7.3 IXXllMENTATION 36 7.4 AtJDI'IS 38 ii • I"·-··•··· .. I I I I I I I I I I I I I I I I 'I I Section 5-1 6-1 6-2 6-3 7-1 Section 5-1 5-2 6-1 C-REMNCSU2/FSAPIDl'F.l 01/11/87 LIST OF TABliS Page Monitoring Well Construction, NCSO, Lot 86 13 Sal!plin;J Matrix, NCSU, Lot 86 20 Summary of Analytical Methods, Preseivation Techniques, Holdin;J Times, and Method Detection Limits, NCSU, Fann Site Lot 86 23 Summary of Analytical Methods, Preseivation Techniques, Holdin;J Times, and Met.hod Detection Limits, NCSU, Fann Site Lot 86 30 RI/FS Sal!plin;J and Analytical SU!m'llal:y, NCSU, Lot 86 37 LIST OF FIGURES Proposed Monitorin;J Well and SUbsurface Soil Sample Locations, NCSU, Lot 86 12 'fypical Monitorin;J Well Construction 14 Proposed SUrface ·Soil Sample Locations, NCSU, Lot 86 19 iii 1 ··· I I I I I I I I I I I I I I I I I I 1.0 INI'ROIXJCTION C-RD-INCSU2/FSAP-l.l 12/27/86 'Ihe Field Samplin;J ard Analysis Plan (FSAP) is an integral part of the 'Remedial Investigation/Feasibility study (RI/F'S) Work Plan for the North carolina state University (NCS!J) Lot 86 site. 'Ihe field activities to be perfonned in the 'Remedial Investigation (RI) are described in detail in this document. Information on the specific field activities, s.anple · locations, ard s.anplin;J proceduies is included in this description. 1 ' ---•-•-••--• -••-•-•• •--•-•••• •---------•---..__. _______ R,_ ~-• __ .............. _ -•-•----•• I I I I I I I I I I I I I ' I I I I I I C-Rn!NCSU2jFSAP-2.l 12/29/86 2. 0 SUMMARY OF SITE RECDNNAISSANCEIPRELIMINARY CHARACTERIZATION/SAMPLING ACl'IVITIE5 Field activities planned for the NCSU Lot 86 site include site i:e:::cnuiajssanoe, preliJDinary characterization, an:i sanplin; activities to detennine contaminant 0.J1.::.e11t.Iations an:i migration in grc,.md water an:i soil. 'Ihese RI activities are designed to provide data sufficient to delineate sa.u:ce areas; contaminant types, distribution, an:i levels: hydrcgeologic an:i geologic characteristics relevant to contaminant transport: an:i actual or potential receptors. If an evaluation of the data gathered in the RI indicates that additional data are required to define fully the extent of o:mtamination an:i to determine appropriate remedial alternatives, the rationale an:i documentation for prcpose::l additional activities will be submitted to the U.S. Environmental. Protection '/v:Jercj (USEPA) in the form of a Technical Direction Meiroramum (Tr.M) before additional field activities are initiate:i. 'Ihe prcpose::l approach to the NCSU RI/FS · involves only a sin;le phase of sanplin; an:i analysis. 2 I .. I I I I I I I I I I I I I I I I I I 3. 0 GENERAL FIElD OPERATIOOS 3 .1 PROJECr M:>BILIZATICN AcrIVITIE.S C-REMNCSU2,IFSAP-3 .1 01/11/87 Followin;J ~ of the Draft Work Plan and Field Operations Plan (FOP) by USEPA Region IV, the field ~tions team will ™ mobilization activities for the RI. Mobilization activities will inc:lude establishment of a project CXJDDJaM post at the site, ccmmitment and testin;i/calibration of all required field equipnent, sec:urinJ of all necessary permits and site aroess agreements, and initiation of arran:Je- merits for Contract I.aboratoJ:y PLo.;iram (CLP) and REM m laboratoJ:y services. ~ements will be made for leas.in;J a mobile office trailer that can be deployed to the NCSU Lot 86 site area. A security perimeter will be ccnstructed around the trailer. 'Ihis trailer will serve as ;, mmmard post and· storage facility for performance of field sanpl.in;J and survey.in;J activities. Present schedul.in;J requires the trailer to be deployed and fully operational in advance of the cx:smnencement of excavation and drill.in;J activities requir.in;J the use of the trailer. 'nle =unand post will be maintained thlough the oarq;,letion of all major RI field activities. Concurrent with the establishment of the c:omman:i post, all required field . sanpl.in;J and analytical equipnent will be obtained and tested or calibrated as ¥CeSsazy to ensure that the equipinent is in sourxl. 'WOrk.in;J order. 'Ihis equipnent will be deployed to the site on an as-TJeeded basis for perfoi,nance of the respective field activities. 'nle Site Manager and Field Operations Team reader will "Werk to secure all necessary state and local permits that will be required dur.in;J the RI (e.g., lrater well drillinJ,/installation permits). 'nle Site Manager will "Werk with USEPA Region IV to obtain site access agreements with NCSU. It is urderstood that the sec:urinJ of site access agreements is the responsibility of USEPA Region IV. 3 ' ' ···-·-··----··----I . .. " -. -.... --. --- 1 I I I I I I I I I I I I C-REMNcstJ2jFSAP-3.2 01/11/87 Drnrediat-.ely upon awroval of the FSAP by USEPA Region IV, the Site Manager will contact the REM III Regional Iaboratory SUppJt L Coordinator (RISC) to initiate the necessaey requests for CLP services am bicldin; pr, ce'bu-...; for REM III laboratory services. Based on th.. pr sent schedule, analytical services for samples CXlllec:ted at NCSU Lot 86 site . will be required by April 13, 1987. • other general field operations elements that will be addressed durirq l!Cbilization will include ~ for han:ll.irq of wastes generated by the field operations team durirq the RI. Contaminated wastes will be drummed am stored in a temporacy onsite facility am disposed in a USEPA-approved lamfill at the corx:J.usion of the field samplirq activities, or for a mav:lnnnn of 90 days, whichever comes first. All contaminated wastes will be stored am disposed a=rciin] to :RescRJrce Conservation am ReaNery Act ·(RCRA) requirements. USEPA assistance will be required in obtainirq the a~ropriate permits am manifests for disposal of wastes generated durirq the RI. 'llle current schedule provides for constJ:Uc:Lion of a concrete decontam- ination pad am drum storage facility onsite prior to initiation of soil excavation am drillirq activities. An interim decontamination area will be established for use durirq initial field (ncmrillirq) activities (i.e., geophysical surveys am surface soil samplirq). ~. 3. 2 FIEID SAMPLING AND ANALYSIS PIAN 'llle FSAP describes data quality objectives (t'QOs) samplirq design, samplirq am laboratory materials am nethods, decontamination, am Quality Assurance/Quality Control (WQC) procedures for the NCSU Lot 86 site RI. 'llle followin;J Field Technical Guidelines (FIG), developed for the REM llI Program, are applicable to the RI: I I I I 4 I I I I I I I I I I I I I I I I I I I C-REMNCSU2(EBAP-3.3 01/11/87 o FT-4.02 Resistivity am EJ.ectranagnetic Irouctian SUrveys, o FT-4.05 Grouni-Penetratin;J Radar (GPR) SUrveys, o Fr-6.01 Soil am Rock Borirgs, o Fr-6.02 Borehole am sample IDggirr;, o Fr-6.03 Deccntaminatian of Drillirr; Rig am samplirr;J Equipment, o Fr-6.06 In~ Hydraulic Cbnductivity Testirr;, o Fr-6.07 Piezweb:ic Head Measurement am Grouni Water Contour MaWirr;, o Fr-6.09 Vertical am Horizontal Movement of Grouni Water, o FT-7. 01 Grouni Water Monitorirr; Well Installation, o FT-7.02 Grouni Water sample Acquisition, o FT-7. 03 Soil an::l. Rock sample Acquistion, o FT-7.05 sample Identification am ~-aurt:ody, o FT-7.06 sample PreseJ:vatian, o FT-7. 07 samplirr; Packin;r am Shippirr;, o FT-7 .10 Onsite Water Q.]ality Testirr;, o FT-12.01 Deccntaminatian of Chemical samplirr; am Field Analytical Equipnent, am o FT-13.03 Site Log Book. 'Ibese guidelines are an file with the USEPA De?.tty Project Officer am with USEPA's Iaboratocy Evaluation am Q.lality Assurance Section Otlef in Athens, Geo?:gia. 3.3 SAMP!E cx:itm.INER ~ AND HOIDING TlMES sample container requirements am holdirg times are specified in Rm III Guideline FT-7. 06. '!his info:anatian is also included in Tables 6-2 an::l. 6-3 (refer to Section 6 of this FSAP) for soil an::l. grcund water samples, respectively. 3. 4 SAMP!E PACK11GING AND SHIPPING samples will . be packaged an::l. shipped a=rding to FT-7. 07. When sample shipments are sent to the Rm m or c:u> laboratories, the Rm m 5 I I I I I I I I I I I I I I I I :1 I I C-REl-lNCSU2/FSAP-3. 4 -01/11/87 laboratoey coordinat= or USEPA Sanq:>le Management Office (SM:>) ' respectively, will be telE!fboned that day or the followin;J momin;J an:l. given the appropriate info:cmation about the types of sanples, mll!lber of sanples, an:l. aimill numbers. J.5 IXXllMENrATICIN · 'lbe field team will maintain a boom, -weatherproof notebook. 'lhis notebook will be filled cut at each sanplin;J station an:l. will cantain sample particulars, measurements, an:l. observcltions. 'lbe field operations leader or his designee will record info:cmation in this notebook at each samplin;J station. A site logbook will be maintained by the field operations leader. 'lhis book will cantain a summary of the day's activities an:l. will reference the sample team's notebooks. Individual field notebooks (e.g., geologists' notebooks) will also be refE:l.etl03d. 'lbe requirements of the site logbook are c:utlined in REM m Guideline FT-13.0J. A sample logbook will be maintained in the field office. 'lhis book will .contain a separate sheet for each sample. Pertinent info:cmation (e.g., date an:l. time sampled, in situ water quality measurements, or other observcitions) will be placed on these fo= :from info:cmation recorded in the field notebooks. 3.6 D.'ITA ~ OBJECTIVES (020s) D;Os for the NCSU Lot 86 site were defined on the basis of the Work Assigrnrent objectives, as urderstood by Environmental Science an:l. En;Jineerin;J, Inc. (ESE); basic statistical an:l. laboratoey principles; USEPA'i= D:x:uu:er,+-. No. 93.0-7A entitled "I:ata ~ity Cbjectives for the RI/PS Process; II a review of possible Applicable or Relevant' am Appropriate Requirements (ARARs) ; an:l. the RI/PS Sa,pin;J/I:QO meetin;J held on November 12, 1986. 6 ·, -----. -·-__ -_ ·••' . . . ... -. ------· ·--· -----. . .. --... ···-·-· ·-· ···----•·••·'-····•··-· ... ,. -. ---.. -----.. I I I I I I I I I I I I I I I I I I 3.6.l stage One-Definition of P:n.gram Objectives C-REMNCSU2/FSAP-3 .5 01/11/87 'lhis stage of the ~ process is oavexed in FOP Sections 1.2 and 1.5. 3.6.2 stage ~Establishment of Analytical Data 9,lality 'lhe basic :requirement for the RI/FS is that data collected be of known quality. Criteria used for definin;J data quality are: o Precision-a measure of the repr, ,!ucibi.lity of analyses uroer a given set of conditions, o Accuracy-a measure of the bias that exists in a measurement system, o :Representativeness-the degree to which saJ!l)le data accurately and precisely reprwent selected c:haraCU!ristics, o Completeness-a measure of the amount of valid data obtained fran a measurement system o:mq;,ared to the amcunt that was expecte:l. to be obtained uroer normal conditions, and o Comparability-an expression of the confidence with which one data set can be o:mq;,ared to another. Precision and accuracy are statistical ccncepts related to sampl.irq design, methods,_ and materials. Precision is ireasured by collecting duplicate saJ!llles and replicated analyses in order to define the sampl.irq variance (or error) attrib.ttahle to environmental heterogeneity an:l,lor the sampl.irq and sample preparation process. Accuracy, in tenns of statistically estimat.irq the field concentrations, is a function of the number of saJ!l)les. laboratory accuracy is a function of the method detection limits (MDis) and percent reccvery. · Ar:oJr:ac-f is checked thraJgh use of blanks and matrix spikes and assured by proper instnnnerrt: calibration/certification. 'lhe accuracy and precision of sampl.irq data taken in this study will be adequate tr> mmpare data against ms to be chosen for risk assessment and feasibility studies. Potential ms for the RI/FS include: 7 -----------I ---,_ 7 ---- 1 I I I I I I I I ,I I I I I I I I I C-:REMNCSU2jFSAP-3.6 01/11/87 o Federal Safe Drink.in;J Water Act (SI:W!.) Primary Drink.in;J Water stan:uu:tls, o Clean Water Act (~) Water ~ity criteria, 0 Prcp:lsed Maximum contaminant Levels (M:!s) and Maximum contaminant Level Goals (M::!.Gs) , and o state of North carolina water quality stan::lards awlicable to grourxl water (Title 15, SUbchapter 2L). 'llle ARARs for the NC:SU Lot 86 site will be diSC!JSSed in greater detail in the RI/F'S LE4X)rts. Representativeness of sanplinJ is also extremely important for this =lgnnent. 'llle prcposed sanplinJ plan for the NC:SU Lot 86 site is designed to ensure that sanplinJ locations are appl.opl...i.ate and that a sufficient number of sanples are collected to neet the objectives of the RI/F'S. 'llle rationale for selection of samplinJ locations and number of sanples is provided in the Work Plan for the RI/F'S. Prcp:lsed samplinJ techniques to ensure representativeness are described in detail in the Work Plan and in this FSAP. C'alpleteness will be assured by making f!NBrY effort to collect and analyze all samples that are proposed to be collected. 3.6.3 stage 'lllree-Selection of Analytical and Sa:rrpling Options 'llle analytical options chosen for the site investigation include IQO Levels I, III, 'IV, and v. 'llle specific level or analytical option chosen is based on the IQO level for the specific type of sanple and data needed-IQO Level I "10I'k consists of field screening for the selection of sanplinJ location, for a preliminary estiJDation of contaminant concen- tration, and for health and safety precautions. For Baltples that need a high level of data quality but are not required for potential litigation, IQO Level III will be used. Rigoro.is WQC protocols and doc:=entation are required for sanples that may be used for confiLmatianal water quality; Level 'IV will be used for these samples. San'q;>les LeqUirinJ special analytical SBLVices (SAS) will be analyzed at IQO Ievel v. 8 I I I I I I I I I I I I I I I I I I I 4.0 lNITIAL FIEID ACl'tYA1ii$ C-REMNCSU2JISAP-4.l 01/11/87 Initial field activities planned for the NCSU :RI include a bacJ<grrund records searcn am geq:cysical surveys. 4.1 ~ RECXlRtS SFA'ROi 'llle backgrt:mxi n.cmds. seardl to be perfoi:med as part of the initial field activities includes cirt:ainin;J am revi~: (1) waste di.spJsal records for the two di.spJsal areas; (2) available environmental. m:mitorin:J data frcm NCSU; am (3) information on neart,y water supply wells, surface water uses, am sensitive or eman;iered species in the vicinity of the site. Disposal recmds. am environmental mnitorin] data are available frcm Naro. 'llle reviEM of waste di.spJsal rec=ds will include documentation of chemical/radioactive waste types, quantities, am di.spJsal locations. Info:cmation will be mmanarized into data tables for use in the :RI/FS. Neart,y water SUWlY wells, including danestic, cxmnercial., agricultural, am irxlustrial wells, will be located by revi~ records maintained by the North carolina Deparbnent of Enviranmental Management, Gramd water Section, in Raleigh. Types of information that will be sought include location, use, depth, pcp.il.ation served, am const:cuction details. Limited reconnaissance of the immediate area will also be perfo:aned to identify any additional wells am to confinn the locations of wells identified thrc,.igh the records seardl. Uses of neart,y surface waters am the presence of en::lan;Jered or sensitive terrestrial am aquatic species will be determined by contactirg local environmental am natural resource agencies. 4. 2 GEX:>mYSICAL SURVEYS Geophysical techniques [elecLtauagnetic (EM)-31 am GPR =eysJ will be used to deterllline the lateral extent of trenches :in l:xJth the chemical waste b.Jrial area am the low-level radioactive waste disposal area. 'llle 9 I I I I I I I I I I I I I I I I I I I C-REMNCSU2,'FSAP-4.2 01/11/87 geqnysical survey will be perfODIEd by Tec:hncs, Inc. as an initial site activity. A grid pattem for the surveys will be established by stakirg 10-foot (ft) intervals across the width am len;ith of l:xJth areas. 'lhe EM am GPR surveys will be oorwcted o:intiruously alon; these transects. 'lhe appl"Cldlllate area to be oavered durin;J the survey in each area is 130 ft by 180 ft (10,000 total linear feet) in the chemical waste area am 50 ft by 200 ft (4,500 total linear feet) in the low-level radioactive waste area. Fach method relies on response to differin;J :r;:hysical am chemical characteristics between the urdisturbed, original soil am the soil-waste mix in the trenches. 10 .- 1 I I I I I I I I I I I I I I I I I -------•-·--' .. ,.. ..... ·--· 5.0 M;lNI'I'ORING WEJ::r, TNSTAL!ATION 5.1 STATIC!lS ....... _ ---~---. ··--.·.- C-REl-!NCSU2jFSAP-5.l 01/11/87 New monit=in.J wells will be installed at the locations shewn in Figure 5-1. 'lhe NCSU Wene Plan dlSC'JSses the rationale for the locaticns of the new wells. 'lhe 29 existin,1 monitorin; wells were installed by NCSU am I1l.llllbered conserutively fran l to 20 am then 27, 27A, am 29. · 'lhe new monitorin; wells will be numbered 30 thrt:A.lgh 36. Cluster wells (adjacent wells screened in different inte%vals) are designated by letters (A or B) follOiorlrg the 'Well l'DJ!!lber. 'lhe existin,1 am proposed monitorin; 'Well construction data are presented in Table 5-1. 'lhe locaticns of MW-35 am MW-36 are tentative am will be finalized follOiorlrg detailed exa:rniMtian of the subsurface lithology usin.J three borin.Js (I:6-D, I:6-E, am I:6-F) • 'n1ese wells will be screened alon; the same 1:'P<:lcJirq planes or lithologic contacts (if possil:>le) ~ent of the site, one in the lower saprolite am the-other in the upper bedrock. 'lhe other well locaticns are apprcxjlna.te am may depeni an the actual field conditions (i.e. , roads, trees, etc.) for their final locaticns. 5.2 MJNl'roRING WELL cx:NS'IRJCI'ION PROCmlRES 'lhe monitorin.J wells will be constnicted in accordance with REM m Guideline FT-7.0l am state of North carolina regulations. 'lhe locaticns, depths, am construction are summarized in Table 5-1. Acy necessary construction pemits required by the state of North carolina will be obtaine:i. Monitorin.J 'Well construction is depicted in Figure 5-2. 5.2.l construction of Saprolite Monitorinq Wells 'lhe boreholes for the saprolite monitorin.J wells will be produced usin.J 5-inch inside diallleter (I.D.) hoilow-stem augers to the desired depth. 'Ihe methods for the borin.Js will be in accordance with REM m Guideline Fl'-6.01. 'lhe augers (with a bottom plug) will be advanced to 11 I I I I I I I. I I I I I I I I I I I AElllfl NCSU U81A e1s • 32 e 13 e10 21• 27Ae .___-+:•- • LEGEND EXISTING MONITORING WELL LOCATION ... ,.___..,.._FENCE PROPOSED MONITORING WELL LOCATION (SUBSURFACE SOIL SAMPLE LOCATION) t> SUBSURFACE SOIL SAMPLE LOCA·TION (BORING ONLY) Figure 5•1 PROPOSED MONITORING WELL AND SUBSURFACE SOIL SAMPLE LOCATIONS, NORTH CAROLINA STATE UNIVERSITY, LOT 86 SOURCES: COM, 1886; ESE. 1917. 12 • .. : 14 • 30 FORMER CHEMICAL STORAGE 0...-sTER AREA \ 300 TO 500 FEET ll. 31 0 "' ,00 ------.. ENVIRONMENTAL SCIENCE AND ENGINEERING, INC. ---- -- -- - -- - ---1!!1111 !!1111 Table 5-1. ftonltorlng Wei I Construction. NCSU Lot 86 Wei I 1.0. Oete of Total T~ of Top of Top of Casinfe Clued .. Top of Stick~ tlP Dbove II' A80'I[ lnstel lat ion Oe~th SC HN Sand Bentonite Boreho e Casin~ Nature I (rT) Dat1.n IISL ( T) (fl) Pack Seal Diameter (G Backri 11 (fl) (rT) E~istlng nonltoring Wells I 8/82 50.30 37.2 35.0 34.5 3/8 + 23.0 1.96 -12.92 437.08 IA 5/85 46.00 40.7 • 39.0 10.0 2/8 1.02 -13.53 436.47 I 18 5/85 56.00 50.5 49.0 10.0 2/8 0.96 -13.89 436.11 ' 2 8/82 50.10 42.7 35.0 34.0 3/8 + 22.0 I. 78 -6.98 443.02 .. i . ' 3 8/82 37.40 32.4 31.0 30.0 3/8 + 20.5 1.98 -7.00 443.00 I 3A 10/86 64.00 60.0 57.0 53.0 2/8 + 1.31 -9.43 440. 57 38 10/86 76.50 71.0 68.0 65.0 2/8 + 2.00 -8.61 441. 39 4 8/82 61.80 47.0 45.0 44.0 3/8 + 21.0 2.05 2.05 452.05 5 12/83 50.00 39.0 39.0 38.0 3/8 + 20.0 2.32 -10.88 439.12 5A 5/85 55.00 46.0 • 40.0 10.0 2/8 0.92 -12.65 437.35 58 5/85 62.00 56.0 • 55.0 10.0 2/8 0.83 -12.29 437. 71 6 12/83 40.50 33.5 29.0 28.5 3/8 + 19.0 2.64 -13. 71 436.29 7 12/83 48.20 38.5 38.5 37 .5 3/8 + 20.0 2.43 -10.21 439.79 8 12/83 53.30 48.0 46.0 45.0 3/8 + 15.0 2.37 -4.29 445. 71 9 5/84 45.60 39.0 37.5 36.5 4/8 17.0 2.70 -9.84 440. 16 10 5/84 44.20 37.0 36.5 35.5 4/8 16.0 2.97 -14.11 435.89 II 12/84 37.20 24.0 23.5 23.0 4/8 20.0 0.83 -22.21 427.79 12 12/84 42.50 29.0 28.0 27.0 4/8 20.0 I. 17 -25.21 424. 79 13 12/84 42.60 29.0 29.0 26.5 4/8 19.0 0.63 -28.46 421.54 14 12/84 47.40 37.0 36.0 35.0 4/8 14.0 3.00 2.91 452.91 15 12/84 55.00 34.0 • 33.5 32.5 4/8 21.0 I. 25 -19.90 430. 10 .... 16 5/85 35.00 28.0 28.0 10.0 3/8 I. 28 -24.06 425.94 l.J 17 5/85 32.00 26.0 24.0 10.0 2/8 1.65 -27.33 422.67 18 5/85 34.00 28.0 • 28.0 10.0 2/8 0.00 -30.31 419.69 19 5/85 34.00 26.0 26.0 10.0 2/8 -0.20 -26.52 423.48 20 5/85 30.00 25.0 • 25.0 10,0 2/8 0.00 -23.49 426.51 27 10/86 45.00 40.0 • 33.0 10.0 2/8 1.46 -3.91 446.09 27A 10/86 60.00 54.5 54.5 52.5 2/8 1.44 -3.82 446.18 29 10/86 55.50 50.5 48.5 46.5 2/8 I. 99 -4.80 445.20 ., ··t Proposed "onitoring Wells I Total Screen Sand Pack Thickness of Casinfe ' Wei I 1.0. Depth Len?th Above Screen Bentonite Boreho e (ft) ( t) (ft) Seal (ft) Dimneter 30 50-60 10 2 2 2/10 31 100-120 10 2 2 2/10 32 60-70 10 2 2 2/10 33 62 5 2 2 2/10 34 54 5 2 2 2/10 35 70-80 10 2 2 2/8 36 105-115 10 2 2 2/8 Notes: • Natural neterial Caving During Construction. •• Natural backfill was used as a backfill in the early monitoring wel Is. Auger Refusal At 40.5 rT in t1.W-6. KP• Neasuring point Source: ESE. 1987. I I I I I I I I I I I I I I I I I I REMl/f NCSU 1111A t ... -----... -HINGED CAP -r 2.5' -PROTECTIVE STEEL CASING ,,c_::::::::::.,--1-~ VENTED CAP VARIABLE GROUND LEVEL ! ... ,.!..,..,..,~777:'71 1/ // Figure 5-2 ~,*--NO. 316 STAINLESS-STEEL ;; CASING (2" DIAMETER) ,, ,, ,, ,, ;,;' .---GROUT , , ,, ,, ,, ,, ,, ,, , ,, . . .. ·=· .. . . . . -:· ·:. t--BENTONITE SEAL (2 FEET) •• ',I----"'\,·.· • .'.' · -~•...,..--NO. 316 STAINLESS-STEEL WELL SCREEN ., (0.010" SLOTS) •• ·.• 1----; •• • • • • • • ·•l-----i••· •• • • • • • • . -~----,..•, . .. . . . . • •• • • • •• ·:·• •: ........... . . ....... ·•······•· ······==· .. ~·.····. -~·-· ............ . TYPICAL MONITORING WELL CONSTRUCTION ENVIRONMENTAL SCIENCE AND ENGINEERING, INC. SOURCE: ESE. 1987. 14 I I I I I I I I I I I I I I I I I I C-RrnNCSU2,'FSAP-5. 2 01/11/87 the sanq:ilinJ clept:h am the plug removed to allow soil sanq:iles to be collected fran inside the auger. standaJ:d Penetration Tests (SPl') will be perfonoed at the surface ani at intervals of 5 ft, excludln;J the top 10 ft lfflich will be saqiled o:int.inuoosly. '!be clept:h of new shallow wells will be based on the clept:h to the water table lfflich will be deteDl1ined fran water cxmtent of the split-spoon sanq:iles ani fran water level . measurements in neaJ:by mcnitorinJ wells. When the desired clept:h of the well is reached, the inside of the auger will be cleane:i. A 10-ft section (MW-34 an:1 MW-35 will have 5-ft sections) of 2-inch-I.O., flush-jointed, threaded type-316 stainless- steel wire-wrapped screen with 0.010-inch slots will be placed into the hole an:1 sunoounted with en::,ugh 2-inch-I.D. threaded solid type-316, SChedule 5 stainless-steel casinJ to allow a 2.5-ft sticlOJp. 'lbe screen will be surra.m:led, usin; the tremie pipe method with a san:!pa.ck consistinJ of 20 to 40 mesh, silica san:1 to a clept:h of 2 ft above the screen. A 2-ft seal of bentonite pellets will be placed above the san:!pa.ck. 'lbe remain:i.rg annulus will be grouted to approxil!lately 3 ft from the surface with 5 percent bentonite, 95 percent Type I Portlan:1 cement grout mixture, by usinJ the tremie pipe method while slowly renx:,vinJ the auger. '!be grout will be allowed to set for at least 24 h= prior to any additional \¥Ork on the well (i.e., installation of the protective casinJ ani the cement collar or well developnent). A stainless-steel cap will be placed on the riser an:1 will be vented to allow water levels to equilibrate to atm::,spheric pressure. 5.2.2 Construction of Bedrock Monitorim Wells Bori.nJs for the two bedrock mcnitorinJ wells (MW-35 an:1 MW-36) will be produced usinJ 4-inch I.D. [8-inch cuter diameter (0,0.)] hollow-stem augers to the top of the bedrock. Two Shelby tube sanq:iles will be collected fran the borinJ for MW-36 at clept:hs of 20 an:1 40 ft. Once the bedrock is reached, the augers will be reD¥JVed ani a 6-inch-diameter steel casinJ will be driven to the top of the bedrock an:1 cleaned in 15 ~· ---_..... ~--·· --.... ,..--·1·:.:-::-:-.:: ;_:-:'.':-::-::: .. ; . . . .. -· .. , ....... ,.. .. . .. . . . .. -· .. . ... ·-·-· ····· I I I I I I I I I I I I I I I I I I C-REl-lNCSU2jFSAP-5. 3 01/11/87 aocorclanoe with REM m Guideline PT-6.01. _'!be casin;J will be grcmed fer stability an:l allowed to set fer 24 boors prier to drillin;J into the bedrock. Fifteen feet of the bedrock will be cored usin;J an NX core barrel fer lithologic description an:l conf:izmation of the depth to bedrock. '!be C01.e-hole will be reamed to a diameter of 6 inches usin;J mud-rotaey drillin;J with an inert, inorganic: clrillin;J additive. • '!be bedrock ncnitorin;J -wells will be oanstructed in the same manner as the saprolite ncnitorin;J welJ diso1ssed above. In addition, a stainless- steel centralizer will be placed on the base of the screen to keep the screen in the center of the hole while the well is oanstructed. All ncnitorin;J -wells will be developed by pumpin;J (sul:mle.rsible er bladder pump) er by bailin;J, clepencli.n; on well yield. 5.2.3 Protective Casi.rs an:l Cement Pad A 5-ft, hin;Jed, lockin;J, steel, protective 6-inch casin;J will be placed over the riser of each new well. '!be protective casin;Js will be painted fluorescent oran::i-e with weather-resistant rustproof spray paint prior to installation. Additional grait will be added to the annulus to ~te for settlin;J an:l to set in the protective casin;J. 'lhis last grait will be added to the hole before settin:} the protective casin;J in the annulus an:l while the grait is still fluid. Grout will be added to the inside of the protective casin;J to a level of approxilllately o.s ft above grourxl surface. A 0.25-inch drain-hole will be drilled approxilllately 1 inch above the level of grait inside the steel casin;J. A 4-ft-diameter concrete pad will be placed aroun:l all wells after the grait has set. '!be collar will be sloped aMaY fran the well to pemit drainage. '!be cenvant collar~ MW-6 was abserled to be broken dJJrin;J the site reconnaissance. '!be collar will be replaced dJJrin;J well construction activities to prevent downward migration of contamination fran the grourxl surface. 16 f · . . .. ----::-;-::--.:-:: -=.-." I I I I I ~1 I I I I I I I I I I I I 5. 3 ~ OF !:BILL ClJITIOOS AND FIIlit8 C-REMNCSU2/FSAP-5. 4 01/11/87 Drill cutt.in;is and fluids frcm all offsite l:lorin;s except MW-33 and MW-34 will be plac:Ed in an unlined pit onsite 'Which will be covered with clean fill ...nen drillin;J is ccmplete. Because of high levels of ocntaminants doc::umented in MW-5 am MW-a, drill o.rt:tin;is and fluids frcm MW-JJ and MW-34 will be cantainerized in drums, temporarily stored onsite, and transported and disposed in accordance with USEPA's regulations. 'Ihe waste fran onsite l:lorin;s and the developnerrt:/pw:ge water from MW-lA, MW-lB, MW-3, MW-JB, MW-5A, K-l-5B, MW-8, MW-12, and MW-16 will be disposed in the same manner as the waste fran MW-33 and MW-34. 5.4 SITE SURVEY On carrpletion of the mcnitorin;J well installation task, a detailed site survey will be perfOJ:llled by a subcontracted, registered surveyor. 'Ihe FrorVey will include onsite structural features such as fences, gates, and markers and onsite and offsite mcnitorin;J wells. Monitorirg wells will be surveyed for horizontal and vertical coordinates in acoordance with the REM m Guideline FT J. OJ. An onsite ~c survey will also be perfo:cmed at a 1-ft contour interval to detel:lnine drainage pattexns onsite. An offsite ~ survey of the area has already been prepared by the City of Raleigh and is therefore not included un:ler this scope of work. 17 I I I I I I I I !I ' I I I I I I I I I 6,0 SAMPLING PRJCElXJRES 6.1 SURFACE SOIL SAMPLnC 6.1.l stations C-REMNCSU2jFSAP-6 .1 01/11/87 SUrface soil samplin;J stations are sha.ln in Figure 6-1. 'lbe stations are prefixed with the letters s.s for the type of sample {surface soil) an:i with a letter A, B, c, D, E, or F to designate different samplin;J areas. 'lbe sanple rrumber designation follows the sanplin;J area letter. A pennanent Le::xJid vf samplin;J locations will be made by stakin;J an:i phot.ographin;J each point or location. 'lbe location of each samplin;J point will also be indicated on the site map produced by the ccntracted surveyors. 6 .1. 2 Parameters Soil samples will be screened initially with the HNU for health an:i safety ?JrPOSeS an:i for the selection of samplin;J location in one area (S.S--C). All samples will be analyzed at the IXlQ level m for Hazardous Substance List (HSL) organics an:i inorganics. 'lbe samplin;J depth an:i analytical parameters for each samplin;J location are presented in Table 6-1. 6.1.J Sampling Methods SUrface soil samples will be collected accordin;J to REM m Guideline FT-7 .OJ. 5an'ples frail areas S.S-A, S.S-B, S.S-D, an:i SS-F will be individual samples. 'lbe two samples collected in area s.s-c will be mup:slted frail depths of o to 6 in::hes frail three locations an:i frail depths of 6 to 12 in::hes frail the sane three locations. Each of the six samples :Eran area ss-E will consist of a COUip..\Slte of eight locations frail depths of 4 to 10 in::hes. A stainless-steel trowel or a stainless-steel harxi auger will be used to collect the surface soil samples. 5alrple locations will be staked am located on a sketch of the site in the field logbook prior to collectin;J the sample an:i later located on the site map produced from the site 18 I I I I I I I I I I I I I I I I I I I .. -:. REM/II NCSU 12/Bf$A • e1s e13 * SS•D1 e10 es LEGEND e MONITORING WELL LOCATION • • FENCE *OR~ SOIL SAMPLE LOCATION Figure 6-1 PROPOSED SURFACE SOIL SAMPLE LOCATIONS, NORTH CAROLINA STATE UNIVERSITY, LOT 86 SOURCES: COM, 1985: ESE. 1987. 012 19 • "' • • 14 * SS.F FORM~ CHEMICAL ST~AOE 0...-sTER AREA 0 IO -------ICAU: 1■nn ENVIRONMENTAL SCIENCE AND ENGINEERING, INC. ,---"·-----.•·-•---·-·~-... ·-. --·---·· -------... ·-.. ·--..... ·.--.. . . .. . . -···---. -·-· -····'"~--··-·---'• .. ·-------··---.... .. ··-.. --· - I I Table 6-1. Sarrpling Matrix, NCSU Lot 86 Surface Soils Depths PH1 PH2 PH3 WC HSL3 HSIA GRa&b SS-Al 0-6 (in) 1 I SS-A2 0-6 1 SS-A3 0-6 1 SS-A4 0-6 1 SS-AS 0-6 1 I SS-A6 0-6 1 SS-A7 0-6 1 I SS-Bl 0-6 1 SS-B2 0-6 1 SS-B3' 0-6 df-1 I SS-C1 0-6 1 SS-C2 6-12 1 I SS-D1 0-6 SS-D2 0-6 SS-D3 0-6 I SS-E1 4-10 1 SS-E2 4-10 1 SS-E3 4-1 () 1 SS-E4 4-10 1 I SS-ES 4-10 1 SS-E6 4-10 1 I SS-Fl 0-6 Subsurface soils DS-Al 10-12 1 I DS-A2 24-26 1 DS-A3 38-40 1 I DS-B1 10-12 df-1 DS-B2 24-26 1 DS-B3 38-40 1 I DS-Cl 10-12 d-1 DS-C2 24-26 1 OS-C3 38-40 1 I DS-E1 10 d-1 DS-E2 so 1 1 df-1 DS-E3 90 1 d-1 d-1 I ~1 10 1 DS-G2 50 1 d-1 ~3 90 1 d-1 I 'rol'ALS 7 5 10 9 35 0 0 I I 20 I I I I I I I I I I I I I I I I I I Table 6-1 • Sanpling Matrix, NCSU Lot 86 ( Continua:i, Page 2 of 2) Grourrl Water Depth Sanples MW-lA MW-lB MW-3 MW-3B MW-4 MW-SA MW-SB MW-8 (ft) PHl 40.7-45.7 so.s-ss.s 32.4-37.4 71-76 PH2 PH3 'IOC HSL3 HSIA GRa&b 1 MW-9 MW-12 MW-13 MW-14 MW-15 MW-17 MW-18 MW-19 MW-20 MW-27A MW-30 MW-31 MW-32 MW-33 MW-34 MW-35 MW-36 47-52 46-51 56-61 48-53 39-44 29-34 29-34 37-42 34-39 26-31 28-33 29-34 25-30 54.5-59.S 50-60 100-120 60-70 56-61 48-53 70-80 105-115 1 1 1 1 1 d-1 1 df-1 1 df-1 1 1 1 1 d-1 1 1 1 1 1 1 1 1 1 1 1 1 df-1 d-1 Medlin Residence df-1 0 0 0 0 29 NOI'ES: PHl---{.rain size analysis of saJll)les only if the depth to bedrock is less than 150 ft. 3 10 PH2-Physical paran-eters: porosity, Atterberg limits, viscosity, penneability, and filter press. PH3-Physical paran-eters: noisture and BTU content. 'IOC-Total organic carbon content. HSL3-DQO Level III HSL organics and inorganics. HSIA-DQO Level IV HSL organics·and inorganics. GRa&b---{.ross alpha and beta radiation. d-Duplicate saJll)le. f-Field blank collecta:i prior to sanple. Source: ESE, 1986. 21 j-----··-· I I I I I I I I I I I I I I I I I I C-~CSU2jFSAP-6.2 01/ll/87 SJrlle'f. Fractions to be analyzed as a o 111p:site for volatile organics will be packed in in:iividual containers and ., 11qcsited in the laboratocy prior to analysis. 6.1.4 Sample Treatment o Presel:vation-Applicable sample preservation guidelines, presented in REM m Guiclel.ine FT-7.06, will be follcr.ied. 0 label) in;J-5anple labellin;J guidelines are presented in REM m Guiclel.ine FT-7. 05. All l abeJ s will be prepared prior to sanple . collection and will contain infODJBtian an site name, sample number, name of collector, date and ti:me of collection, place of collection, type of sample, sample volume, analysis required, and preservation technique. o Pacld.n;J, Shippin;J, and Transportatian-sanples will be packaged, shit:Ped, and transported in ao::ordance with REM m Guideline FT-7. 07. When sample shipnents are to be made, the receivin;J laboratoi:y will be telephoned an that day or the follCJloTl.l'J;J llDmirq in order to notify the laboratocy of shipment, ai:r:blll number, and number/type of samples bein;J shipped. Table 6-2 presents the analytical methods, types of containers, holclin;J ti:mes, and MOls for the soil samples to be collected. 6.1.5 p.tplicate Samples l)Jplicate sanples are used to measure field samplin;J variation. 'lhe IlUlllber of duplicates and their samplin;J locations for soils are included in Table 6-1, 22 --"' w --- - ----- - - --C·REMNCSU2/fS.PH62.1 01/11/87 Table 6·2. SlmDl!ry of Analytical Methods, Preservation hchnlques, Holding Tl•ea, artd Method Detection ll■ltl, NCSU, fer■ Sita Lot 86 Para-ter HSL Organfcs VohtflH ••• Surflctet and Subsurface Soft Samples Method• rechnlque EPA 8240 GCNS Extractablea EPA 8250/8270 GCMS Pesticides and PCBs EPA 8080 Total Phenol lea EPA 420. t HSL jnorganlca Cyanide Metals Mercury (Hg) EPA 9010 EPA 7471 GC/EC Colorimetric Colorl.etrlc CVAA Method Reference • • • 4 • 6 Saaiple container 2 Jt 4·oz wldemouth amber glass jers M/ Teflo,,e·llned cap 8·oz -.fde110uth glen Jar w/ Teflon•·llned cap 8-ot wlde11outh 9h11 Jar W/ Teflon•-I lned cap 8-ot widemouth gla11 Jar w/ Tttfl on•· 11 ned cap 8·ot wfdeiaouth glaa■ Ju w/ Teflon•·lined esp 8·ot wldemouth glass jar w/ Teflon•·tined cap Preservation Requl red Coot to ,•c Cool to 4•c cool to 4•c Cool to 4•c cool to 4•c Cool to 4•c MHI-Holdlng TIN 10 days 10 deys extraction 40 days after utrectfon 10 days extraction 40 days after extraction • • • MDL 1.6 to 6.9 ut/l (In extract) 10 to 50 ug/L (In extract) 0.01 to 5.0 ug/L (In extract) 0.3 1119/g 5 ug/g 0.40 mg/kg ---- ---------------- N ~ C·RENNCSU2/FSAPH62.2 12/30/86 Table 6·2. Summary of Analytical Methods, Preservation Techniques, Holding Times, an~ Method Detection Limits, NCSU, Farm Site Lot 86 (Continued, Page 2 of 4) Surficlal and Subsurface So! l Sam(!les Method Preservation Maximum Parameter Method* Technique Reference Sample Container Required Holding Time MDL Arsenic (As) EPA 7060 GFAAs 6 8•oz wfdemouth cool to 4•c + D.50 mg/kg glass jar w/ Teflon ·lined cap Selenium (Se) EPA 774D GFAAB 6 8-oz wfdemouth Cool to 4•c + 0.24 mg/kg glass jar w/ Teflon ·lined c~p Thall tum (Tl) EPA 7841 GFAAB 6 8-oz wtdemouth Cool to 4•c + 0.32 mg/kg glass jar w/ Teflon ·lined cap All Others•• EPA 6010 ICP 6 8-oz wfdemouth cool to 4°C + 1 to 10 mg/kg glass jar w/ Teflon -lined cap Moisture Gravimetric 8 8-oz widemouth cool to 4°C + 0.5 mg/g glass jar w/ Teflon ·lined cap Total Organic Carbon EPA 415.1,2 Combustion 4,8 8•oz wfdemouth cool to 4 •c + 0.4 mg/g glass jar w/ Teflon ·lined cep Porosity EN 1110·2· Gravimetric 9 Shelby-tube or un· None required NA NA 1906·11 disturbed sampling tube -' . ' . ' . ' '' ' i• --------- -- - -- - - - N ..,, C·REMNCSUZ/FSAPH6Z.3 01/11/87 Table 6·2. Summary of Analytical Methods, Preservation Techniques, Holding Times, and Method Detection Limits, NCSU, Farm Sfte Lot 86 (Continued, Page 3 of 4) Parameter Btu Content Grain She Surflciat and Subsurface Soll Samples Method* Technique D2015 Combustion ASTM 044 Sieve Method Reference 'ASTM ASTM Sample Container 8-oz wldemouth glass jar w/ Teflon •lined cap 8·oz widemouth glass jar w/ Teflon •lined cap Preservation Required None required None required Maximum Holding Time NA NA MDL NA NA *DQO Level JI fa a screening technique; although certain methods are cited, the quality control samples used at thl1 level wf,ll be less than that specified In the method. +EPA has not established maximum holding times for these parameters In solid ~atrlces. The maximum holding times for a water matrix should be used as a goat In these instances. •*All other metals include: antimony (Sb), beryllium (Be), cadmium (Cd), chromium (Cr), copper (Cu), lead (Pb), nickel (NI), sflver (Ag), and zinc (Zn). NA a Not applicable. GFAAs • Graphite furnace atomic absorption spectroscopy. EPA= Environmental Protection Agency. ICP = Inductively coupled plasma. BNA • Base/neutral and acid extractable organic compounds. 119/g • mtl Ugrams per gram. PCBs = Polychlorfnated bfphenyls. mg/L • mi t l lgrams per l fter. GCMS = Gas chromatography/~ass spectrometry. ug/L • micrograms per liter. GC/EC = Gas chromatography/electron capture detector. mg/kg • milligrams per kilogram. Btu= British thermal unit. ug/g = micrograms per gram. CVAAs = Cold.vapor atomic absorption spectroscopy. -- ----- - --- -- ------C·REHNCSU2/FSAPH62.4 01/11/87 Table 6·2. Sunnary of Analytical Methods, Preservation Techniques, Holding Times, and Method Detection limits·, ~CSU, Farm Site' Lot 86 (Continued, Page 4 of 4) References: 1. Guidelines Establishing Teat Procedures for Analysts of Pol'lutants under the Clean Yater Act, Federal Register Vol. 49 (209), October·26, 1984, P43234. 2. Organics·-Contract Laboratory Program (CLP), Information for Bidders (IFB), Statement of Work (SOW), July 1985. 3. lnorganfca•·Contract Laboratory Program, Information ,for Bidders, Statement of Work, September 1985. 4. Methods for the Chemical Analysts of Yater and Wastewater, EPA 600/4-79·20, revised March 1983, USEPA·EMSL, Cln~lnnatf, Ohio. 5. Prescribed Procedures for Measurement of Radioactivity fn Drinking Water, EPA 600/4·8-032 (1980 Update), August 1980, USEPA, Cincinnati, Ohio. 6. Test Methods for Evaluating Solid Wastes, EPA·SW-846, July 1982, 2nd Edftfon, USEPA, Office of Solid Waste and Emergency Response, Washington, DC. 7. Procedures for Handling and Chemical Analysts of Sediment and Water Samples, Technical Report, EPA/CE-81·1, USEPA/Corps of Engineers Technical Corm,ittee. NTIS No. AD/A103 788, Hay 1981. 8. Laboratory Soila Testing, EM1110·2·1906, Department of the Army, OCE, November 30, 1970. N Source: ESE, 1987. "' - - I I I I I I I I I I I I I I I I I I I 6.2 SUBSURF7\CE SAMPIES 6.2.l stations ···-···:"" ···-··-·· ·-----·-·--·--. C-mlNCSl.l2jFSAP-6. 3 01/11/87 SUbsurface soil sampl:in;r locations are sher.In in Figure S-1. 'Ihe stations (i.e., IS-Al) are designated by the prefix IS for the type of samples (Deep soil) an:l with a letter A, B, c, D, E, F, or G to designate the sampl:in;r area. 'Ihe sample number follows the samplin;J area designation. A pennanent record of the samplin;J sites will be made by stakin;J an:l i:tiotographin;J each location. In addition, the locations will be designated on the -site map produced by tru, canl.racted surveyors. 6.2.2 Paralreters All soil samples will be screened with the HNU for health an:l safety :?,IIpOSeS an:l for qualitative volatile organic concentrations in the sample. FaJr undisturl:>ed (Shelby tube) samples will be collected from 1:x:,rin;s IS-D an:l IS-E to detemine the clip of lithologic contacts an:l beddirg planes for use in locatin;J ffi-35 an:1 MW-36. 'Ihe sample depths an:l paran-eters to be analyze::l. are given in Table 6-1. Sang;>les from areas IS-A, IS-B, an:l IS-C will be collected adjacent to the chemical waste disposal trenches. 'lbese samples will be analyze::l. for the followin;J paran-eters. o Pf0-8lysical soil parameters, includirg misture content an:l Btu content, will be analyze::l. as SAS, I:QO Level V, by a REM III team laborato:cy. 0 HSL'.3--ESL inorganic:s analyzed at J:Q0 Level III by a REM III laborato:cy. Sang;>les collected from the deep 1:x:,rin;J used to detennine the lithology of the saprolite an:l upper bedrock will be analyzed for the followin;J paran-eters: o PHl-Grain-size analyses will be performed on samples from l:x:,rin;s IS-E an:l IS-G at depths of 10, so, an:l 40 ft. Since 27 I I I I I I I I I I I I I I I I I I I C-REMNCS02jFSAP-6.4 01/11/87 these data are required to detemine the feasibility of a slurry wall, the samples will be analyzed only if the depth to the bedrock is less than 150 ft, the practical lilllit of slurry wall feasibility. o m2-:Rlysical parameters includin;J ~ity, an:! Attemerg limits will be detexmined en the soil samples. Pel:1Deability, filter press, an:! viscosity tests will be run en a mixture of the soil sample, bentcnite, an:! the native grc:und water. 'Ihese parameters will be analyzed by a Rm III team laboratm:y as a SAS. Sanples will be collected at the approximate depths given in Table 6-1. o ~ will be analyzed from foor samples collected f= borin;Js ts-E an:! 00-G. 6. 2. 3 Samplilp Methods SUbsurface soil samples will be collected in a=rclance with Rm III Guideline FT-7 .03 for split-spoon an:! un:list1lJ:bed (Shelby tube) samples. All soil samples will be collected in boreholes during SPl' through a holla.-stem auger. Sa!rq:,ling equipnent will be decontaminated in accordance with Rm III Guideline FT-12.0l prior to collection of sairples for chemical analysis. 6.2.4 Sample Trea'brent o Preservaticn-AI:Plicable sairple presavaticn guidelines, as presented in Rm III Guideline FT-7. 06, will be follc:Med. o Labelling-Salrq:>le labelling guidelines are presented in Rm III Guideline FT-7. OS. All labels will be prepared prior to sairple collection an:! will contain info:anaticn en site name, sairple number, name of collector, date an:! til!le of collection, place of collection, type of sairple, sairple volume, analysis required, an:! preservation technique. o PackiJXJ, Shipping, an:! Transportaticn-Salrq:>les will be packaged, shipped, an:! transported in accordance with Rm III 28 I I I I I I I I I I I I I I I I I I I , ... ···-... ----. .. -· ·-, . . . -... C-R™NCSU2/FSAP-6. 5 01/11/87 Guideline Fr-7.07. When sample shipments are to be made, the receivirq laboratozy will be telephoned on that day or the follc:Min;J =min;J in order to notify the laboratozy of shipment, airl>ill number, an:i number/type of samples beirq shipped. Table 6-2 :i;:=es:.,t:.. the analytical methods, types of ccntainers, holdin;J times, an:i Mms far subsurface soil samples. 6.2.5 Duplicate samples 'Ihe number an:i lcx:ations of duplicate samples are given in Table 6-1. 6. 3 GRl:X.lND WATER SAMPIES 6.3.1 stations 'Ihe grourn water samplirq lcx:ations are given in Table 6-1 (see Figure 5-1). 'Ihe mcnitoring wells are numbered consecutively from l to 20 an:i from 29 through 35 with one or more wells at a lcx:ation designated with a letter (i.e., A or B). MW-30 through MW-36 will be installed durirq the RI. 'Ihe details of mcnitoring well construction are given in Table 5-1. 6.3.2 Parameters Groum water samples will be collected from 18 of the 29 existirq wells an:i from all 7 new wells. Eleven of the existirq mcnitoring wells were excluded from the grourn water samplirq program because they are not expected to provide significant new data useful in plllll'e delineation. Wells to be sampled were selected based on the appropriateness of their lcx:ations an:i depths for describirq the horizontal an:i vertical extent of o:mtamination. One well, K-1-6, was eliminated from samplirq because of faulty construction that cxw.d potentially ccmpramise sanple integrity. Groum water sanples will be analyzed for HSL organics an:i inorganics, includin; gross ali;:ha an:i beta radiation for Ki-3B, MW-4, K-1-8, MW-14, an:i MW-30 sanples. Table 6-3 presents analytical methods, preservation techniques, holdin;J times, an:i Mms for the grourn water samplirq 29 w 0 -- --------- --- ---C·REHNCSU2/FSAPH63.1 01/11/87 Table 6·3. Summary of Analytical Methods, Preservation Techniques, Holding Times, and Method Detection Lfmfts (MDL), NCSU, Farm Sfte lot 86 Gr~und Water Samples Method* Method Ref· MDL (DQO II, Analytical erence (OQO Preservation Maximum (DQD 111/ Parameter 111/IV) Technique II, Ill/IV) Sample Container Required Holding Time IV) HSL Organics Volatiles EPA 624/ 624·CLP·N GCNS 1/2 3 x 40, 60-ml amber Cool to 4•c 7 day• 1.6 to 6.9 ug/L/ glass vials w/TeflonG! (0.008 percent CRDL line.d septum Na2S203)+ 8NA EPA 625/ Extractables 625·CLP·N GCNS 1/2 2 x 2-L amber glass Cool to 4•c 7 days to 10 to 50 ug/L/ jars with Teflon~ (0.008 percent extract+ CRDL l lned caps Na2s 2o3J+ 40 days after extraction Pesticides EPA 608 and PCBs 608·CLP·N GC/EC 1/2 2 x 2-L amber glass Cool to 4°C 7 days to 0.01 to 5.0 ug/L jars w/Teflonel!. (0.008 percent extract.,. CRDL l tned caps Na2s2o3J+ 40 days after (adjust pH to extraction 5 to 9) Total Phenolfcs EPA 420.1/ CLP Colorimetric 4/3 1·L glass bottle H2s04 to pH <2, 28 days 0.01 mg/L/CRDL w/Teflon~l ined cap cool to 4°C HSL lnorgantcs • Cyanide EPA 335.3/ CLP Colorimetric 4/3 1-L polyethylene NaOH to pH >12, 14 days** 5.0 ug/L/CRDL bottle/cubitainer chi 11 to 4°C (0.6 g ascorbic acid)** - ,. '. w ... ----·---·-- ---- - --- C·REMNCSU2/FSAPH63.2 01/11/87 Table 6-3. Summary of Analytical Methods, Preservation Techniques, Holding Times, and Method Detection Limits (MDL), NCSU, Farm Site Lot 86 Ground Mater Samples (Page 2 of 3) Method* Method Ref· MDL (DQO II, Analytical erence (DQO Preservation Maximum (DQO 111/ Parameter 111/IY) Technique I I , 111/IY) Sample Container Required Holding Time IV) Metals Mercury (Hg) EPA 245.2/ CLP CYAA 4/3 1·L polyethylene HN03 to pH <2 28 daya 0.2 ug/L/CRDL bottle/cubitainer Arsenic (As) EPA 206.2/ CLP GFAA 4/3 1·L polyethylene HN03 to pH <2 6 months 10 ug/L/CRDL bottle/cubttafner Selenium (Se) EPA 270.2/ CLP GFAA 4/3 1·L polyethylene HNo3 to pH <2 6 months 5 ug/L/CRDL bottle/cubitainer Thallium (Tl) EPA 279.2/ CLP GFAA 4/3 1-L polyethylene HN03 to pH <2 6 months 10 ug/L/CRDL bottle/cubitainer Alt others++ EPA 200.7/ CLP ICP 4/3 1·L polyethyene HN03 to pH <2 6 months 5 to 50 ug/L/ bottle/cubitainer CRDL Gross Alpha and Beta EPA 900.0 PC 5 4-L polyethylene HN03 to pH <2 6 months 1.0 plcocurie/L bottle/cubitainer Temperature EPA 170.1 Thermometric 4 NA None required Field analysis 0.1°c pH EPA 150.1 Electrometdc 4 NA None required Field analysis 0.1 pH units Sped f i c Conductance EPA 120 .1 Electrometric 4 NA None required Field analysis 1 umhos/cm - f I. ' I I . ' i t .. , -- --- - --- - - -- - - - - w "' C·REMNCSU2/FSAPH63.3 1Z,30/86 Table 6-3. Summary of Analytical Methods, Preservation Techn;ques, Holding Times, and Method Detection Limits (MDL), NCSU, Farm Site Lot 86 Ground Water Samples (Page 3 of 3) *Dao Level 11 is a screening technique; although certain methods are cited, the quality control samples used at this well will be less than that specified in the method. +CLP maximum holding time is 5 days to extraction plus 40 days after extraction. **Added in the presence of residual chlorine. ++All other metals include: Antimony (sb), Beryllium (Be), Cadmium (Cd), Chromium (Cr), Copper (Cu), Lead (Pb), Nickel (Ni), Silver (Ag), Zfnc (Zn). Note: 1. DQO Level II is a screening technique, although certain methods are cited, the quality control samples used at thfs level will be less than that specified fn the method. CLP= Contract Lab Program. EPA= Environmental Protection Agency. GC/EC = gas chromatography/electron capture detector. CVAA = cold vapor atomic absorption spectroscopy. GFAA a graphite furnace atomic absorption spectroscopy. ICP a inductively coupled plasma. PC= proportional counter. GC/MS = gas chromatography-mass spectrometry. HSL = Hazardous Substance lfst. BNA = ease/neutral and acid extractable organics. References: PCB a Polychlorinated blphenyls. NA• Not applicable. HN03 a Nitric acid. cm• centimeter. H2so4 a sulfuric acfd. NaOH • sodium hydroxide. Na2S203 = sodium thtosulfate. ug/l = micrograms per liter. mg/l = milligram per liter. 1. Guidelines Establishing Test Procedures for Analysis of Pollutants under the Clean Water Act, Federal Register Vol. 49 (209), October 26, 1984, P43234. 2. Organics--Contract Laboratory program (CLP), Information for Bidders (IFB), Statement of Work (SOW), July 1985. 3. Jnorganics--Contract laboratory Program, Information for Bidders, Statement of Work, September 1985. 4. Methods for the Chemical Analysis of Water and Wastewater, EPA 600/4·79-20, revised March 1983, USEPA-EMSL, Cincinnati, Ohio. 5. Prescribed Procedures for Measurement of Radioactfvitr in Drinking Water, EPA 600/4·8·032 (1980 Update), August 1980, USEPA, Cincinnati, Ohio. 6. Test Methods for Evaluating Solid Wastes, EPA·SW-846, July, 1982 2nd Edition, USEPA, Office of Solid Waste and Emergency Response, Washington, DC. 7. Hazardous Waste Management System; Identification and Listing of Notification Requirement, Reportable Quality Adjustment Proposed Rule, Hazardous Waste, Federal Register, Vol. 51 (114) June 13, 1986, P26648. 8. Procedures for Handling and Chemical Analysis of Sediment and Water Samples, Technical Report, EPA/CE-81·1, USEPA/Corps of Engineers Technical Co~mittee. NTJS No. AD/At03 788, May 1981. Source: ESE, 1986. - ' I. ' I i i I I'. J J ! I I ' . ' ' ' . .. •••••••• I I I I I I I I I I ! I I I I I I I I C-lID!NCSU2/FSAP-6, 6 01/ll/87 p:ttXJldlll. Samplin;J depths an::l analytical parameters for each -well 6aJ!i)le are presented in Table 6-1. 6.3.3 Samplirxr Methods Grourd water 6aJ!i>les will. be collecta:i in ac:cordan::e with the REM m Guideline Fl'-7. 02. Prior to the input of any article (i.e. , measurin;J tape, pump, bailer, line, etc.) into the -well, the article will be decontaminated in ac:cordan::e with REM m Guideline Fl'-12.0l. Monitorin;J wells will be purged usin;J dedicated Teflone ballers or bladder-type pulli)S with dedicated Teflone tubin;J prior to collection of the san;,le for water quality analysis. 'lbree to five -well volumes will be purged: ha.lever, if the wells are purged dry with less than 3 -well wlumes rencved, then the water level will be allCMed to rec:aver to at least 70 percent of static level prior to san;,le. collection. Field measurements of ~. tenp>rature, an::l specific conductivity will be taken at the beginning, middle, an::l end of ?,Irgin;J an::l reoorde:i in the field logbook. 6.3.4 Sample Treatment o Preservation-Sample preservation guidelines are presented in REM m Guideline Fl'-7. 06. 0 I.abellin;J-Sample lal:Jellin;J guidelines are presented in REM III Guideline Fl'-7.05. o Packagin;J, Shippin;J, an::l Transportation-Samples will be shipped an::l transported in accordance with REM m Guideline Fr-7. 07. A sumnary of analytical methods, preservation techniques, holdin;J tilres, an::l MDis for groun:l water san;,les is presented in Table 6-3. 6.3.5 D.lplicate Samples 'lbe number an::l location of duplicate san;,les are given in Table 6-l. 33 I I I I I I I I I I I I I ,. I I I I I 6. 4 ~ ~CN C-REMNCSU2jFSAP-6.7 01/11/87 All equipment use:i for oollectin;J san-ples for dlemical analysis will be deccntaminated prior to sample oollection, between sang;iles, and at the en:i of sang;ilinJ. F.quipment to be decantaminated .includes the followin;J: stainless-steel ham augers, trowels, spatulas, J:uckets, and split-spoon sang;ilers use:i in soil san-plinJ and bailinJ cord, ballers, pllllPS, tubinJ, steel tapes, and electric water-level in:ilcators for grc,.mi water samplinJ. 'lhe decantamination ptt.retlJ"'P.S are as follows: o Potable water rinse, o Al=nax or l~ rinse, o Potable water rinse, o Distilled/deionized water rinse, o Isoprt:pyl alcohol (pesticide grade) rinse, o Distilled/deionized water rinse, 0 Air dcyinJ, and o Wrap with alumirn.Im foil for storage or transport to field. All of the equipment use:i in test borin;is, m:mitorinJ well installation, and soil =al will be decantaminated i:Ne.r a decantamination pad onsite. 'lhe decantamination pad will be constructed prior to the drillirxJ of any borings and will be constructed to allow oollection of the rinse water. 'lhe rinse water will be oollected and disp:lSed of in unlined pits onsite, excludin;r the rinse water from decontamination of equipment used for the onsite subsurface soil borin;is and the borin;is for MW-34 and MW-JS. Rinse water prcx:iuced from deoontamination of equipment used for these borin;is will be contained in drums, stored onsite, and later disp:lSed in a=rcance with USEPA regulations. 'Ihis equipment will .incll.lde the followin;J: drill rig, backhoes, front-end loaders, augers, and drill rods, bits, and core barrels. 'lhe equipment will be decantaminated as follows: 34 .-...... _,, .. I I I I I I •• I I I I I I I I I I I I . -.-· ... ----.~_;__· ., ............. -............. _.-_ ... . . . . --·------·--------.". ·-•:·-····•-· --·-··-·-··· ~--------J-••·-···'-••··· C-REMNCSU2/F5AP-6. 8 01/11/87 o steam cleanin.J or liquiJ,ccc or alconox wash with brushin:J, o Pl:ltable water rinse, an:i 0 Air dry. 35 I I I I I I I I I I I I I I I I I I I 7. 0 OOAIJ:'lY ASSURANCE AND OOAIJ:'lY amROL (OA/OCl C-m-lNCSU2jFSAP-7,l 01/11/87 7, l FIEID INS'IRlMENT CALIBRATION AND J:m.VENl'IVE M1uNI'El'UINCE D.Jrin; llClnitoril'J;r well p.irgin;J and samplin;J, samples will be field tested for pH, teup!>:ature, and specific conductivity, 'Ihe calibration and use of these instruments will be in a=-clance with REM III Guideline FT-7 .10. 7 ,2 FIEID B!AmS AND SPmES . Blank samples are used to chec::k the accuracy of a samplin;J method and to detennine if there is introductian of errors durin;J the ~ process. Trip blanks are samples of analyte-free deionized water poured into sample containers and sealed prior to the samplin;J event and -ru.c:h a=ipany the samples taken in the field through storage, packin;J, and shippin;J to the laboratory. 'Ihese blanks will be prepared an a daily basis durin;J groom water samplin;J. Protocols for trip blanks for soil samples have not been established. Field blanks or decantamina.tian blanks ·are a chec::k an the equipment decantamina.tian process. 'Ihe preparation of field blanks consists of collection of analyte-free deionized water after it has been poured through the decontaminated samplin;J equipment, 'Ihe field blanks are then packed, shipped, and analyzed with the samples. One field blank will be collected for every 20 samples, by parameter. 'Ihe prcix,sed number of samples, duplicates, and blanks, by medium, is sunmarized in Table 7-1. 7. 3 JXX:llMEN'lX['IQN Documentation of all activities will include a site logbook, field notebooks, labels, OlStody seals, chain-of-custody forms, COJ.te..."tive actions forms, approvals, .and field instrument calibration forms. REM III Guideline FT-13.03 describes E.SE's REM III Site I..ogtx:,ok prrx:elrnYs. 'Ihe samplin;J team will keep watetprcof field notebooks 36 I I I I I I I I I I I I I I :1 I I I I C-m!NCSU2jFSAPV71.1 01/11/87 Table 7-1. RI/F'S Sampling and Analytical Sumrnacy NCSU Iot 86 Number of Anal vses Media Samples A B C D E F G H Total Water 26 25 1 5 0 0 0 0 31 Field Illplicates 5 2 1 4 0 0 0 0 7 Trip Blanks* 8 7 1 1 0 0 0 0 9 Field Blanks 3 2 1 1 0 0 0 0 4 SUbtot:al 42 36 4 ll 0 0 0 0 51 surface and SI.lb- surface Soils 41 31 0 0 9 4 4 6 35 89 Field Illplicates 8 2 0 0 ·1 4 1 1 8 17 Field Blanks 3 2 0 0 0 1 0 0 0 3 SUbtot:al 52 35 o· 0 10 9 6 7 43 109 Total 94 71 4 ll 10 9 5 7 43 160 Note: Laboratory spikes will be analyzed as specified in the standard Operating Proce:tn'."P. of the REM m Team laboratory. · *Trip blanks will be subnitted at a rate of one per day. 'llle numbers of samples listed are based on estimated field sampling times. A= HSL organics and inorganics Level m. B = HSL organics and inorganics Level J:v. C = Gross Ali;xia and Beta. D = Bb.l ccnterrt. E = 'lt>C F = Atterberg limits, viscosity, filter press, porosity, permeability. G = Grain size. H .. Moisture content. 5oorce: ESE, 1987. 37 ··-·-·--·-'"'· .... -.,--~.,.--~-""'-·---··· , _ _:_ .. --. -·••·--·· .. :· ... ,. --··' C-RElmCSU2jPSAP-7.2 01/11/87 CXllT1:ainil'q infODDatian an sample rrumber, sample ex>llectian, time, sample location, sample des=iptian, samplin; methods, weather, in situ -measurements, an:i other pertinent infODDatian. Ola.in-of-custody fOD!IS, labels, custody seals an:i other sample doo.I!rents will be maintained as specified in REM III Guideline Fl'-7.05. 7.4 AIJDITS A minimum of one QA perfo= audit will be perfonned by a designated QA scientist c:h.lrinJ ccrxiuct of soil an:i groJl'Xi water samplin;. 'lhis audit will include checks an adherence to all samplin; protocols from station positianin; throogh samplin;, BaJiple han:llin;, an:i documentation. If it be'xmles "PCeSsa,:y to m:xlify a pxc:gtam, the Field Operation."' leader will be required to notify the Site Manager of anticipated an:1/or immediately marxlated c:hanJes. 'lhis action is followed by USEPA notification an:i written authorizatiO!Vchan;ie notice documentation. 'Ihe significance of actions taken in the field will be evaluated an:i documented in writin; by the Site Manager. 38 I I I I I I I I I I I I I I I I I I I APPENDIX A SECI'IOO II DRAFT SITE Ml\N1IGDlENr PIAN !·,------------------. --------... ------... --·····. ------ I I I I I I I I I I I I I I I I I I w:>RK ASSIGNMENT: 64-46G7 CDNTRACI' NUMBER: 68-01-7250 EBA.Sa:> SERVICES ma:>RFORATED mAFl' SITE MANAGEMENl' PIAN REMEDIAL INVESTIGATION AND FEASIBILITY S'IUDY NORIH Cl\ROLlNA STATE UNIVERSITY IJJr 86 SITE RAIEIGH, NORIH Cl\ROLlNA JANUARY 1987 NOI'ICE The infonration in this document has been funded by the United states Environmental Protection Agercy (USEPA) umer REM Ill Contract No. 68-01-7250 to Ebasco Ser.rices Incoxporated (D:>asco), 'Ibis Draft Site Management Plan is a draft and has not been fonrally released by either Ebasco or the USEPA. As a draft, this dcx:iwent should not be cited or quoted and is bein;J circulated for a:imment only. I I I I I I I I I I I I I I I I I I I WJRK ASSIGNMEITT: 64-46G7 CXJNIRACI' NUMBER: 68~1-7250 EBASCD SERVICES DICXlRPORATED DRAFT SITE MANi\GEMENl' PI1IN REMEDIAL INVFSI'IGATION AND FEASIBILrI"i S'IUDY NORIH CAROL1NA STATE UNIVERSI'IY IDr 86 SITE RAIEIGH, NORIH CAROLINA JANUARY 1987 PREPARED BY: CAROLYN F. FOPPEU.. SITE MANAGER ENVIRONMENTAL SCIENCE AND ENGINEERING, me. Approved by: RusseJl H. Boyd, Jr., P.E. Re:]ianal Manager, Re:]ion IV Ebasco services Incorporated I I I I I I I I I I I I I I I I I I I I Section 1.0 2.0 --------.-.. -.... TABIE OF a:Nl'Em'S SITE a::m'ROL 1.1 SITE llCX"fSS 1.2 • SITE SEaJRI'IY/CXlN'rR'.)L 1.3 FIEID OFFICE/a:M!AND EOST SITE OPERATIONS 2 .1 ~00' 2,2 RESPONSIBILITIES OF REY~ 2.3 SamIXJIE • 1 C-RE2'1NCSU2/SMPI'OC.l 12/31/86 ~ 1 1 1 1 3 3 6 7 I I I I I I I I I I I I I I I I I I I Figure 2-1 2-2 LIST OF FIGURES NCSU Site RI/FS Project OJ:ganization NCSU Site RI Field Operations Team ii C-REMNCS02/SMPIDF, l 12/31/86 5 I I I I I I I I I I I I I I I I I I I 1.0 SITE CON'IRlL 1.1 SITE llCCE'SS C-Rn!NCSU2/SMP-l.l 01/12/87 '1be North <:a=lina state University (NCStJ) lot 86 site is accessible by pmlic roads, although the site itself is secured by a dlain-link fence with bamed wire and a locked gate. :Keys to the gate are kept by the NCStJ Department of l?Ublic Safety. '1be REM m site Manager will arran;e, through the Regional Project Manager (mM), to obtain ac:oess to the site from NCStJ. No REM m team IDE!JJJbP.r will enter the site rmtil: (1) written or verbal authorization is receiva:l from the Site Manager or designee, (2) at least 24-hoor notice is given to the appropriate NCStJ authorities before initiation of field activities, and (3) each field teaJ!1 mernbP...r has personal identification in the fo:r:m of a driver's license, CXJDF!T'Y identification card, or a suitable substitute approved by the Field operations Leader (FOL) • A list of pexsons authorized to enter the site will be provided to the NCStJ Department of l?Ublic Safety by the Site Manager or the FOL. 'llle list, which is interced to prevent tmauthorized pexsons from gainirg site access, will be updated, as necessary, by the Site Mariager or her designee. In gainirg site access, no REM m team membP.r will sign or acknc:Mledge any con:litional acceptance offered by NCStJ unless approved by the Site Manager. 1. 2 SITE SEOJR!Ti/cctnroL All rencvable equipment will be returned to the CXlDDTlan:i post and secured at the en:i of the work day. Any equipment left onsite will be secured to the extent p::iss:il::,le to prevent tmauthorized rem:,val. or van:ialism. Any unfinished wells will be COITered or capped in such a mnner as to prevent taroperin]. Finished wells will be locked. 1. 3 FIEID OFFICE/ca-iMAND K6T A field office will be established near the site in a small, l!Dbile, office trailer. Based on diso1ssions between the Site Manager and the NCStJ Department of l?Ublic Safety, the field adjacent to the site is not an acceptable long-tenn location for the trailer, since the field is used 1 I I I I I I I I I I I I I I I I I I I C-:REMNCSU2/SMP-l, 2 01/12/87 for overflow park:in;J durin;J stadium events arxi carmot be secured. 'lllerefore, durin;J m:ibilization activities, a suitable location for the trailer will be fam:l, arxi the area will be enclosa:l with a chain-link security fence. 'Ihe trailer will be utiliza:i as II o,mmand storage point for safety am ~in;J equipnent, a stagin;J area for Bal!plm;J teams, arxi a Bal!ple shippin;J point. D.le to the distance of the site from telephone lines, telephone service will not be available in the trailer. Public telephones are available, however, at carter-Finley stadium, approxil!lately 0.25 mile fran the site. 2 I I I I I I I I I I I I I I I I I I I 2.0 SITE OPERATIONS C-REMNCSU2/SMP-2.l 01/12/87 'Ihe followin:J subsections ootline the organization of the field team for the NC5!.1 ~iaJ 'tnVestigaticn (RI) field work, responsibilities of key personnel, am the schedule for performance of the RI field work. 2 .1 ORGANIZATION · 'Ihe CITerall project organization am responsibilities of key management personnel an> diso1ssed in Section 6.0 of the IWDediaJ tnvestigatiOIV Feasibility study (RI/FS) Work Plan. 'Ihe organizational chart presented in Section 6.0 is :reprc:rll103d as Figure 2-1 for quick :reference. Field work will be perfol:1DE!d by a s.in;Jle team, uroer the direction of the roL. As shown in the figure, the roL !E!fX)tL::, directly to the RI Task Manager. For the NC5!.1 Site RI/FS, the Site Manager will also serve as RI Task Manager. Figure 2-2 shcMs the field operations organization in greater detail. 'Ihe roL will be respousible for CXlO:ro.inatin; am oversee.in;J all fieid activities am will interface with the Health am Safety Officer (HSO) in planni.rq am perfoi:min;i the RI tasks. Each of the Field Team readers (FT!s) designated for the site RI activities will report to the roL en a day-to-day basis. rns have been designated for backgrouni surveys, geophysical surveys, well installation am soil borin;Js, groum water am soil sampl.in;J, am excavation activities. 'Ihe roL will serve as the PTL for backgroun::l surveys, which include site surveys am records searches. Geophysical surveys will be perfotmed by Technos, Inc., with oversight by the roL. Well installation, soil borin;Js, am all sampl.in;J activities will be managed by a geologist designated as PTL. oversight of subcontracted soil excavation activities will be provided by another rn... In acco:rdance with the Heal th am Safety Plan (HASP), the HSO, or his designee, will interact with the field team durin;J perfomance of their tasks. 3 - ---------- ---- - - 04/NCSU. 1-P .BEMJll ESE [lESIGNAIED 1.EA[l Eet'I oeo REGIQNt'IL Mt'\Nt'IGEB .. , ...... D. Bruderly ,..,,,,,,.,,,..,,,.,,,,, J. Orban R.H. Boyd • , • , • • • , Eet'IBPM $!IE Mt'INt'IGER 1,,,,.,,,,.,,,,,,,,,,,,.,.,,.,,..,J ,,, ,.. .. .,,., .. ,. . D. Puffer C. Poppell ........ .,,,,,,,,,,,,,, CQMet'INY HEt'ILIH t'IN[l St'\FEIY sueEBYISQR C. Haury HEt'ILIH & 5t'IEEIY QEEICER D. Endicott I ' I I GEQPHYSICS CTECHNQS) Lt'IBQRAIQRY SERVICES SUBCQNIBt'ICIQRS ~ R. Benson CQQRDINAIQB Drilling L. Bare ' Surveys/Mapping , , General Services . I CONTRACT I REM Ill LAB I Transport/Disposal LABORATORY Excavation PROGRAM (CLP) I I 81 It'l$1S Mt'\Nt'IGER EIELO QeEBt'IIIQNS ES It'1$1S Mt'INt'IGER -LEt'IOEB C. Poppell W. Quarles L. Carter I I I RI PROJECT TEAM FIELD TEAM FS PROJECT TEAM Figure 2-1 NCSU SITE RI/FS PROJECT ORGANIZATION ENVIRONMENTAL SCIENCE AND ENGINEERING, INC. SOURCE: ESE, 1987. - - - - - - - - - - - - --- - - --·-· D4/NCSU.2 1187 k FIELD OPERATIONS HEALTH AND LEADER i...-------------- SAFETY OFRCER W. Quarles D. Endicott ' ' ~ B<\O<GRJLND GEOPHYSICAL WELL INSTALLATION GROUND WATER AND SURVEYS SURVEYS AND SOIL BORINGS SOIL SAMPLING EXCAVATION RELD TEAM LEADER FIELD TEAM LEADER RELD TEAM LEADER FILED TEAM LEADER RELD TEAM LEADER W. Quarles Technos, Inc. J. Griffin J. Griffin L. Carter V, FIELD TEAM GEOLOGISTS, ENGINEERS, TECHINICIANS Figure 2-2 NCSU SITE RI FIELD OPERATIONS TEAM ENVIRONMENTAL SCIENCE AND ENGINEERING, INC. SOURCE· ESE 1987. I I I I I I I I I I I I I I I ii I I I C-m!NCSU:2/SMP-2. 2 01/12/87 Ille to the duration of the field pi:o;iram, the RI Task Manager will fill in for the FOL in the field, as nee:led, to ensure CXll'ltinuity an:l. to meet project schedules. 2.2 RESroNSIBILITllS OF KEY~ Fey personnel for field q,eratians are identified in Figures 2-1 an:l. 2-2. · 'lheir specific responsibilities arP disa1ssed beJ.cr,,,. o Field Operations "leader /FOL) • 'lhe FOL is responsible for all day-to-day aspects of the NCSU RI field wrk. 'lhe responsi- bilities of the FOL include: . -Assuring that all field team lllPIJlN>:r:s are familiar with the Field Sampling an:l. Analysis Plan (FSAP) an:l. HASP, -Assur:in;r that all field team lllPIJlN>:r:s have cx:mpleted heal th an:l. safety train:in;r, -Report:in;r to the RI Task Manager an a regular basis regardin:; the status of all field wrk an:l. any problems en=untered, -complet:in;r Field Olange Orders, as "lPCPSsary, for appL'C\Tal by the Site Manager, an:l. -coordinat:in;r the activities of all field teams. o Field Team Leader IFI'Ll • 'lhe FTL reports directly to the FOL an:l. has the followin;J responsibilities: -PL'ovid:in;r team members with daily assignments, -Assur:in;r that team meml:)p".'9 CXll!ply with the procedures outlined in the FSAP, -COOrdinat:in;r with the FOL to ensure sang;:,le shipping schedules are met, an:l. -Report:in;r an a daily basis to the FOL an the pio;JLeS"' of the team. 0 Site Health an:J. Safety Officer (HSOJ. 'lhe HS0 reports to the Cr:Jq,any Health an:l. Safety SUpervisor (CHSS) an:l. irnirectl.y to 6 I I ' I I I I I I I I I I I I I I I I C-RnlNCSU2/SMP-2 • 3 01/12/87 the FOL am. Site Manager. Details of the HSO's responsibilities are presented in the HASP am. in::lude: -controllirg specific health aoo. safety related field operations such as personnel deccntamination, naritorin;r of worker heat or cold stress, distri.J:ution of safety equipment, etc.; -COnfo:anance of field team personnel with all pro :edJJJ:PCl established by the HMP; -Identifyi.rg of Assistant HSOs or HSO designees; am. -Terminatirg work if an imninent safety hazard, emergency situation, or other potentially dan;Jerous situation is encountered. 2 • 3 SCHEIXJIE 'Ihe schedule for the NCSU :RI.field activities is presented along with the overall schedule for the NCSU Project in Section 6.3 of the Work Plan. Key target dates are: Activity ~ Final Background records search 03/16/87 04/03/87 Geophysical survey 03/30/87 04/07/87 Mobilize site team 03/30/87 04/10/87 Collect surface soil sairples 04/13/87 04/15/87 Excavate soil to define trenches* 06/22/87 06/26/87 waste characterization 06/29/87 07/03/87 Drill wells/soil borirgs 06/22/87 07/29/87 Land survey 07/30/87 08/19/87 Well sairplirg 08/13/87 08/21/87 Pump test 08/24/87 08/26/87 *Optional task. 7 I I I I I I I I I APPENDIX A • SECTION III I DRAFT HEALTH AND SAFETY Pl.AN I I I I I I I I I I I I I I I I I I I I I I I I I I I I I SITE-SPECIFIC HEALTH AND SAFETY PLAN FOR REM III HAZARDOUS WASTE SITE ACTIVITIES SITE: North Carolina State University, Lot 86 LOCATION: Raleigh, North Carolina DATE PREPARED: 12/11/86 PREPARED BY: Dan Endicott, Environmental Science and Engineering, Inc. (ESE) REVISION: ______ _ I I I I I I .I I I I I I I I I I I I I Section 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.o C-REMNCSU.1/HASP. 12/31/86 C-REMNCSU.1/HASP 12/31/86 TABLE OF CONTENTS GENERAL HEALTH AND SAFETY PERSONNEL 2.1 HEALTH AND SAFETY PERSONNEL DESIGNATIONS 2.2 COMPANY HEALTH AND SAFETY SUPERVISOR 2.3 SITE HEALTH AND SAFETY OFFICER SITE HISTORY AND PHYSICAL DESCRIPTION 3.1 LOCATION 3.2 DESCRIPTION 3.3 HISTORY SITE-RELATED INCIDENTS, COMPLAINTS. AND ACTIONS WASTE DESCRIPTION/CHARACTERIZATION 5.1 HAZARD INFORMATION 5.2 WASTE TYPES 5.3 CHARACTERISTICS 5.4 CONTAINMENT HAZARD ASSESSMENT TRAINING 7,1 BASIC TRAINING REQUIRED 7,2 SITE-SPECIFIC TRAINING 7,3 SAFETY BRIEFINGS 7.4 FIRST AID AND CPR ZONES. PROTECTION, AND COMMUNICATION 8,1 SITE ZONES 8,2 PERSONAL PROTECTION i l 2 2 2 2 3 3 3 3 8 8 8 8 8 8 8 15 15 15 15 15 16 16 16 I I I I I I I I I I I I I I I I I I I • Section 9.0 10.0 ll.0 12.0 13.0 14.0 15.0 C-REMNCSU.l/HASP . 01/09/87 TABLE OF CONTENTS {Continued, Page 2 of 3) 8.2.l General e.2.2 Safety Equipment 8.3 COMMUNICATIONS MONITORING PROCEDURES 9.l MONITORING DURING SITE OPERATIONS 9.2 9.1.l 9. l.2 9.l.3 Drilling Operations Excavation Operations Other Operations MEDICAL SURVEILLANCE PROCEDURES FOR EVIDENCE OF PERSONAL EXPOSURE SAFETY CONSIDERATIONS FOR SITE OPERATIONS 10.l GENERAL DECONTAMINATION PROCEDURES ll.l LEVEL BAND C DECONTAMINATION DISPOSAL PROCEDURES EMERGENCY PLAN 13.l EVACUATION 13.2 POTENTIAL OR ACTUAL FIRE OR EXPLOSION 13.3 ENVIRONMENTAL INCIDENT 13.4 PERSONNEL INJURY 13.5 OVERT PERSONNEL EXPOSURE 13.6 ADVERSE WEATHER CONDITIONS AUTHORIZATIONS MEDICAL DATA SHEET ii 16 18 18 19 19 19 19 19 19 20 20 21 21 26 27 27 27 28 28 28 30 31 32 I I I I I I I I I I I I I I I I I I I Section 16.0 17.0 TABLE OF CONTENTS (Continued, Page 3 of 3) FIELD TEAM REVIEW APPROVALS iii C-REMNCSU.1/HASP. 12/31/86 C-REMNCSU.1/HASP 12/31/86 Page 35 36 I I I I I I I I I I I I I I I I I I I Table 5-1 Figure 3-1 3-2 8-1 13-1 C-REMNCSU.1/HASP 12/31/86 LIST OF TABLES Representative List of Chemicals Included in Waste Burials LIST OF FIGURES Site Location Map Monitoring Well Locations and Waste Disposal Areas Site Work Zones Hospital Route Map iv Page 9 4 5 17 29 I I I I I I I I I I I I I I I I I 1. 0 GENERAL .... -: ...... ' ................ ,;. - C-REMNCSU.1/HASP.l 12/31/86 This plan has been prepared in.conformance with the Ebasco Services Incorporated (Ebasco) REM·III Health and Safety Plan (HASP). It addresses all those activities associated with soil and ground water sampling at the North Carolina State University (NCSU) site, Lot 86, Raleigh, North Carolina, and will be implemented by the Health and Safety Officer (HSO) during site work. Compliance with this HASP is required of all persons and third parties who enter this site. Assistance in implementing this Plan can be obtained from the REM III Health and Safety Manager (HSM), and/or Charles C. Haury, CIH, the Environmental Science and Engineering, Inc. (ESE) Company Health and Safety Supervisor (CHSS). The information contained in this HASP is made available to health and safety (H&S) personnel who are responsible for monitoring results or changes in the technical scope of work. Any changes proposed must be reviewed by H&S staff and are subject to approval of the ESE CHSS and the HSM. A copy of this plan will be provided to all onsite personnel. Emergency phone numbers will be displayed at the site command post. SITE: NCSU SITE NO.: Lot #86 PLAN DATE: 12/23/86 SCOPE OF WORK: Collect soil and ground water samples to determine the type and extent of contamination. Planned activities include soil boring, well installation, and limited excavation of topsoil. NAME WORK PHONE EMERGENCY PHONE Raleigh, NC Raleigh, NC SITE MANAGER Carolyn F. Poppell (904) 332-3318 NUMBERS HEALTH AND SAFETY OFFICER Dan D. Endicott (904) 332-3318 911 911 Rex Hospital Raleigh Community Police Dept. Fire Dept. Hospital Back-up Hospital (919) 755-3100 (919) 872-4800 Hospital Durham, NC C.C. Haury, CIH R.H. Boyd, Jr. W.A. Quarles National Response Center Poison Control Center CHSS REM III Regional Manager Field Operations Leader REM III HSM (G. Smith or J. Janous) 1 (804) 424-8802 1-800-672-1697 (904) 332-3318 (404) 662-2378 (904) 332-3318 (703) 558-7506 --· I I I I I I I I I I I I I I I I I I I 2.0 HEALTH AND SAFETY PERSONNEL 2.1 HEALTH AND SAFETY PERSONNEL DESIGNATIONS C-REMNCSU.1/HASP.2 12/31/86 The following briefly describes the H&S designations and general responsibilities which will employed for the NCSU Project. These titles are herein identified, and the responsibilities are consistent with analogous titles and responsibilities in the REM III Program. The titles have been established to accommodate the site needs and requirements in order to ensure the safe conduct of onsite work. The number and type of H&S personnel for the NCSU site is based on the project size and scope and the particular health and safety training requirements relative to the proposed site activities or operations. The NCSU site investigation will require one full-time HSO based on review of available site information. 2;2 COMPANY HEALTH AND SAFETY SUPERVISOR (CHSS) The CHSS has overall responsibility for development and implementation of this HASP. He also shall approve any changes to this plan, modification of any procedures as required, or any new activities proposed. · The CHSS is responsible for the development of any new company safety protocols and procedures necessary for field operations and is also responsible for the resolution of any outstanding safety issues which arise during the site work. All health and safety-related duties and responsibilities will be assigned only to qualified individuals by Charles C. Haury, CIH, the ESE CHSS. Authorization for personnel to perform work onsite (i.e., relative to medical exams and training) must be cleared by the CHSS. 2.3 SITE HEALTH AND SAFETY OFFICER (HSO) The HSO will be present onsite during all NCSU field operations at Level C or higher. The HSO will be responsible for all H&S activities. Where the site is identified as modified Level D, the HSO will direct the site H&S efforts through an H&S designee approved by the CHSS. He may direct or participate in downrange activities as appropriate when this does not interfere with his primary HSO responsibility. The HSO has stop-work authorization which he will execute upon his determination of an imminent safety hazard, emergency situation, or any other potentially dangerous situations (e.g., weather conditions,) where this action is appropriate. Authorization to proceed with work will be issued by the CHSS after such action. The HSO will initiate and execute all contact with support facilities and personnel when this action is appropriate. 2 I I I I I I I I I I I I I I I I I 3.0 SITE HISTORY AND PHYSICAL DESCRIPTION 3.1 LOCATION C-REMNCSU.1/HASP.3 12/31/86 The NCSU site is located on Lot 86; west of Raleigh near carter-Finley Stadium in Wake County. Entrance to the site is approximately 100 feet (ft) south of the southern right-of-way of Wade Avenue Extension (Figure 3-1). 3.2 DESCRIPTION The site covers an area of approximately 1.5 acres and was used for burial of radioactive and hazardous laboratory chemicals from 1969 to 1980. Topography is gently rolling with broad, flat, interstream areas. surface drainage is to the northwest toward the extension and stadium parking lot, north to the highway, and to the east. Radioactive waste was buried in the eastern half of the site, and laboratory chemicals were buried on the west side (Figure 3-2). The site is overgrown with grass, and shrubs and east sides. The site is surrounded by a with a locked gate at the southwest corner. waste burial area is separated from the rest wire fence and locked gate. exist on the north chain-link fence The. radioactive of the site by a An unnamed tributary to Richland Creek runs 400 ft east of the site, and a small pond lies about 1,600 ft west of the site. The dirt road leading to the site is used as a jogging path by university students and area residents. The nearest water supply well is loc_ated about 2, ooo ft southeast of the site fence at the Medlin residence. Figure 3-2 shows burial areas, monitoring well locations, and site proximity to the Wade Avenue extension. 3.3 HISTORY NCSU educational and research laboratories generated hazardous chemical and low-level radioactive wastes that were buried on Lot 86 of Farm Unit No. 1 from 1969 to 1980. The site was divided into two separate areas, as shown in Figure 3-2. The western half received the chemical waste, and the eastern half received the low-level radioactive waste in the form of animal carcasses. Site activities are primarily concerned with the hazardous chemical waste burial area. NCSU has installed 24 monitoring wells at the site since 1982 (Figure 3-2). 3 lrJ~\l,~~~~~~~lc;;-~~~~~~~~~~~~~~~, .~\~.,~!~ .. ~:.·,~.~~~\--~~~(r~,-~(1~ .. =~~~~~=~=====il ! <~_:\·! \ -, •. . ... ; ~ ~ , Figure 3-1 SITE LOCATION MAP NORTH CAROLINA STATE UNIVERSITY, LOT 86 SOURCE: USOS, 1881. ,_ . .' . . ·-, i I · · ·11 (~;; ' \ . ENVIRONMENTAL SCIENCE AND ENGINEERING, INC. -------------~----- I I I I I I I I I I I I I I I REAi/ii NCSU 1131A e1s e13 LEGEND e MONITORING WELL LOCATION _..----1,_ FENCE Figure 3-2 21e 27A • .,2 14 NORTH CAROLINA STATE UNIVERSITY, LOT 86 MONITORING WELL LOCATIONS AND WASTE DISPOSAL AREAS SOURCE: COM, 1915. 5 0 IO IOO ------ ENVIRONMENTAL SCIENCE AND ENGINEERING, INC. I I I I I I I I I I I I I I I I 1, I I C-REMNCSU.1/HASP.4 12/31/86 The university maintains a listing of the types and ~antity of materials buried at the site. From these records a list of typical chemicals reported in the burials was compiled and is presented in Table 5-1 (see Section 5.0 of this HASP). The chemicals listed include solvents, pesticides, heavy metals, acids, and bases. The chemical wastes were placed in trenches located in the northwest portion of the site. The trenches were approximately 10 ft deep and 50 to 150 ft long. After filling, about 2 ft of cover material excavated from the trenches was used to close the trenches. Later, the disturbed area was seeded with grass. NCSU estimates that approximately 22 trenches totaling less than 2,000 linear feet were used. Although some of the liquid chemicals disposed during the initial site operations were poured into the trenches, both liquid and solid chemicals were generally buried in metal, glass, or plastic containers. NCSU estimates3the volume of buries hazardous waste at 890 cubic yards (yd). The low-level radioactive waste disposal area is regulated at the Federal level by the Nuclear Regulatory Commission and at the State level by the North Carolina Department of Human Resources, Division of Facility Services, Radiation Protection Section. There is also a NCSU Radiation Protection Commission. According to Mr. D.W. Morgan of NCSU Radiation Protection Office, radiological wastes were buried in trenches approximately 6 ft deep with 4 ft of cover material. The trenches have been mapped and waste disposal records are available. Most of the waste is in a solid form, primarily animal carcasses. These range in size from rats to whole sheep. The carcasses were frozen when buried and were not · containerized. The most abundant radionuclide in the buried material is tritium which has a half-life of 12.26 years. For this half-life, after 5 years, 75 percent of the original radioactivity remains. After 10 years, 57 percent remains. Other radionuclides include carbon-14, iron-59, phosphorus-30, and phosphorus-32. These four isotopes have half-lives of 5,730 years, 45.1 days, 2.5 minutes, and 14 days, respectively. Of all these isotopes, the ones of greatest concern are tritium and carbon-14 because of their longer half-lives. No fission products were buried at the site. In September 1984, NCSU acquired the capability of performing volatile organic analyses on a routine basis using the purge and trap method. Monitoring Wells (MW) 1, 2, 6, 7, 8, and 12 show the greatest number of contaminants. Contaminant concentrations are highest in Wells 1 and 6. There also appears to be a pattern of increasing contaminant concentrations in these two wells over the 6-month period from October 1984 to March 1985. 6 I I I I I I I I I I I I- I I I I I I I --~-~.: ·----~.--.. --.-. -.. , .... ---,.· ......... · C-REMNCSU.l/HASP.5 12/31/86 The most frequently detected compounds include benzene, carbon tetrachloride, chloroform, 1,2-dibromoethane, dichloromethane, 1,2-dichloropropane, diethylether, ethylbenzene, 4-methyl-2-pentanone, toluene, 1,1,1-trichloroethane, trichloroethene, and xylene. · The Medlin residence well and the 208 Marsh Avenue well were sampled for volatile organics analyses on November 29, 1984. Tetrachloroethene and xylene were detected in both wells at a level of .10 micrograms per liter (ug/L). NCSU researchers believe the presence of these compounds is the result of laboratory contamination. These same compounds were also detected in the blank run with the samples. Without knowing more details regarding well construction and use at these locations, it is difficult to correlate the analytical results with results obtained at the site. Furthermore, these wells are topographically upgradient from the site. 7 I I I I I I I I I I I I I I I I I I ------------__ -_ ---------- C-REMNCSU.1/HASP.6 12/31/86 4.0 SITE-RELATED INCIDENTS. COMPLAINTS. AND ACTIONS None recorded. 5.0 WASTE DESCRIPTION/CHARACTERIZATION The following information is presented in order to identify the types of materials that may be encountered at the NCSU site. The information on these materials was obtained from the American conference of Governmental Industrial Hygienist (ACGIH) Guidelines. 5.1 HAZARD INFORMATION See Table 5-1. 5.2 WASTE TYPES: Liquid -=X ....... Sludge Solid X Semi-solid Gas _x_ Other 5.3 5.4 CHARACTERISTICS: Corrosive X Exploaive Radioacti v-e--=x Other CONTAINMENT: Pit X --"'----Pond Process Vessel Lake Flammable X Volatile X Inert Lagoon Tank-==== Tank Car Piping Lab Pack ---Drum 6.0 HAZARD ASSESSMENT The potential for exposure to site personnel at the NCSU site is dependent on the particular task involved. Tasks include excavation and waste characterization, geophysics, soil sampling, soil boring, monitoring well installation, and ground water sampling. The excavation activity task is the most hazardous task planned. In this task, a backhoe will be used to carefully reveal the contents of the buried waste. Potential exists for exposure to metals, alcohols, ketones, aldehydes, acids, phenolics, pesticides, amines, polynuclear aromatic hydrocarbons (PNAs), halogenated solvents, and other miscellaneous organic compounds. Some of those chemicals are known carcinogens (i.e., benzidene), extremely flammable (i.e., ethyl ether), or extremely toxic (i.e., cyanide compounds). The excavation task will be subcontracted to a firm specializing in this type of 8 I I •• I I I I I I I I I I I I I I I I QA.7/REM-VTB51A.I 12/31/86 Table 5-1. Representative Ust of Chemicals Included in Waste Burials Chemical Aliphatic Alcohols 1-butanol 2-chloroethanol ethanol dihydroxypropane ehtylene glycol isopropanol (propyl alcohol) methanol . 2-methyl-1-propanol (propyl alcohol) pentanol · 2-pentanol propanol (propyl alcohol) 2-propanol (propyl alcohol) Misceilaneous Solvents ethyl benzene acetonitrile benzene cyclohexane 1,4-dioxane ether ethyl acetate ethyl ether heptane hexane iso-octane (octane) nitrobenzene pentarie pyridine tetrahydrofuran (THF) toluene p-xylene Inorganics aluminum antimony arsenic boron bromine (bromide) cadmium chloride (chlorine) cobalt copper chromium cyanide fluoride 9 Threshhold Limit Value (TLV) mg/m3 305.0 3.0 1,900.0 250.0 24.0 500.0 260.0 500.0 500.0 500.0 435.0 70.0 30.0 1,050.0 1,400.0 1,200.0 1,600.0 180.0 1,450 .o 5.0 1,800.0 15 .o 590.0 375.0 435.0 10.0 0.5 0.2 3.0 0.7 0.05 3.0 O. I 1,0 0.5 0.5 2.5 I I I I I I I I I I I I I I I I QA.7/REM-VTBSIA.2 12/31/86 Table 5-1. Representative List of Chemicals Included in Waste Burials (Continued, Page 2 of 5) Chemical Inorganics iodine (iodide) iron lead lithium (hydride) magnesium (oxide) manganese mercury molybdenum nickel phosphorus potassium selenium silver sodium strontium sulfur thallium tin titanium zinc Ketones acetone 2-butanone methyl ethyl ketone 4-methyl 2-pentanone 2-pentanone Aldehydes acetaldehyde benzaldehyde formaldehyde Bases potassium hydroxide sodium hydroxide Oxidants benzoyl peroxide hydrogen peroxide potassium permanganate 10 Threshhold Limit Value (TLV) mg/.,J 1.0 1.0 0. 15 0.025 10.0 5.0 O. l s.o o. 1 0.1 2.0 0.2 0.01 0.1 2.0 15.0 5.0 1,780.0 590.0 590.0 700.0 180.0 l .5 2.0 2.0 5.0 1.5 I I I I I I I I I I I I I I I I I I I QA.7/REM-VTB51A.3 12/31/86 Table 5-1. Representative List of Chemicals Included in Waste Burials (Continued, Page 3 of 5) Chemical Miscellaneous Organics acenapthene acrolein acrylonitrile 2-chloroethyl ether di-n-butylphthalate 2-methylbutane 4-methylpent-l-ene nitromethane nitrotoluene styrene p-toluidine trioxymethylene diethyl ether Acids acetic acid benzoic acid boric acid chloroacetic acid chromic acid 2-5-dinitrobenzoic acid formic acid hydrochloric acid hydrofluoric acid mercaptoacetic acid mercaptoproprionic acid nitric acid osmic acid perchloric acid phosphoric acid picric acid proprionic acid succinic acid sulfuric acid t hioacetic acid thioproprionic acid tribromoacetic acid trichloroacetic acid trifluoroacetic acid Phenols p-chlorophenol 2,4-dinitrophenol p-nitrophenol phenol phenolphthalein 11 Threshhold Limit Value (TLV) mg/m3 0.25 4.5 250.0 11.0 215.0 1,200.0 25.0 0.1 9.0 7.0 2,5 s.o 1,0 0, 1 30.0 1,0 7 .o 1,0 1,0 1,0 19,0 I I I I I I I I I I I I I I I I I I I QA.7/REH-VTB51A.4 12/31/86 Table 5-1. Representative List of Chemicals Included in Waste Burials (Continued, Page 4 of 5) Chemical Pesticides/Herbicides/Fungicides atrazine carbofuran 2,4-D DDE DDT endrin ethylene dibromide malathion methoxychlor parathion sevin toxaphene Amines bisacrylamide aniline N-butylamine dibutylamine diethylamine N,N-dimethyl formamide (DMF) diphenylamine N,N-diphenyl-p-phenylene-diamine dipropylamine ethylenediamine N-propylamine tetraethylene diamine tributylamine triethylamine trimethylamine Halogenated Hydrocarbons bromobeilzene bromoethane carbon tetrachloride chlorobenzene 2-chloro-2-methylpropane chloroform 1,2-dibromoethane .1,2-dichloroethane dichloroethane 2,4-dinitrochlorobenzene ethylene bromide methylene chloride perchloroethylene 12 Threshhold Limit Value (TLV) mg/m-3 5.0 0.1 10.0 1.0 1.0 0.1 O. 1 10.0 10.0 0,1 5.0 0.5 0.3 10.0 15 .o 14 .o 30.0 30.0 10.0 0.1 5.0 25.0 5.0 1.0 15.0 40.0 24.0 5.0 5,0 30,0 350.0 10.0 50,0 14.0 790.0 810,0 1.0 890,0 350.0 335,0 I I I I I I I I I I I I I I I I I I I QA.7/REM-VTB51A.5 12/31/86 Table 5-1. Representative List of Chemicals Included in Waste Burials (Continued, Page 5 of 5) Chemical Halogenated Hydrocarbons tetrachloroethane tetrachloroethylene trichlorobenzene trichloroethylene dichloromethane-1,2-dichloro- propane 1,1,1-trichlorethane (methyl chloroform) PAHS (polycyclicaromatic hydrocarbons) benzidine biphenyl bromonapthalene chloronaphthalene chrysene napthalene phenanthrene Note: mg/m3 • milligrams per cubic meter. • not available. Source: ESE, 1986. 13 Threshhold Limit Value (TLV) mg/m3 335.0 7.0 40.0 270.0 · 40.0 1,900.0 1.5 1.0 10.0 10.0 5.0 I I I I I I I I I I I I I I I I I I I C-REMNCSU.l/HASP.7 12/31/86 activity. Included in the excavation task is limited character- ization of the types and integrity of waste containers. This activity wi~l be performed by the subcontractor. The subcon- tractor will submit a separate safety plan the excavation and characterization activites to be reviewed by ESE and the Ebasco Zone Project Management Office (ZPMO). Activities will require the use of, as a minimum, full Level c personal protection. Level B capabilities will be available should monitoring indicate the necessity to upgrade. Other activities present hazards from the same group of compounds, but to a lesser degree based on less disturbance of buried materials. Splashing of contaminated ground water directly on skin or breathing volatilized organic compounds are two sources of exposure. The overall hazard for the site is moderate, with the excavation activity ranging from moderate to high. The potential for chemical burns (corrosives) and fire (flammables) is also present, especially during excavation activities. 14 I I I I I I I I I I I I I I 7.0 TRAINING 7.1 BASIC TRAINING REQUIRED C-REMNCSU.1/HASP.8 12/31/86 Completion of the fundamental REM III Hazardous Waste Training Program is required for all employees who will perform work at the NCSU site. Requirements of the latest training regulations for hazardous waste site activities will be implemented. 7.2 SITE-SPECIFIC TRAINING Training will be provided that will specifically address the activities, procedures, monitoring, and equipment for the site operations. It will include site and facility layout, hazards, and emergency services at the site, and will detail all provisions contained within this HASP. This training will also allow field workers to clarify anything they do not understand and to reinforce their responsibilities regarding safety and operations for their particular activity. 7.3 SAFETY BRIEFINGS Project personnel will be given briefings by the HSO or designee on a daily or as-needed basis to further assist site personnel in conducting their activities safely. It will be provided when new operations are to be conducted, changes in work practices must be implemented due to new information made available, or if site or environmental conditions change. Briefings will also be given to facilitate conformance with prescribed safety practices, when conformance with these practices is not being followed, or if deficiencies are identified during safety audits. 7.4 FIRST AID AND CARDIO-PULMONARY RESUSCITATION (CPR) The CHSS will identify those in order to ensure emergency activities. At least one of first-aid and CPR training. with the requirements of the individuals requiring this training treatment is available at field the field team members will have These courses will be consistent American Red Cross Association. 15 I I I I I I I I I I I I I I I I I I I 8.0 ZONES. PROTECTION. AND COMMUNICATION 8.1 SITE ZONES (see Figure 8-1) C-REMNCSU.1/HASP.9 . 12/31/86 The site is surrounded by a chain-link fence with a gate located near the southwest corner. The fence, a good physical barrier, will serve as the location of the hot line, except in the gate area immediately adjacent to the fence which will serve as a decontamination zone. The gate is the controlled access point through which field personnel will pass during site entry and exit. 8.2 PERSONAL PROTECTION 0.2.1 General Level B protection will consist of hooded Saranexe coveralls, chemical-resistant steel toe boots and latex boot covers, chemical-resistant outer Solvexe gloves and inner latex gloves, and a full-face pressure demand air supplying respirator. The joints between the coveralls and boots and gloves will be sealed with duct tape. In addition, hard hats will be worn in the vicinity of all drilling operations. Level C protection will consist of Saranexe coveralls, chemical-resistant boots and latex boot covers, chemical-resistant outer gloves (Solvexe) and latex inner gloves, and a full-face air purifying respirator (APR) with organic vapor and high-efficiency particulate absolute (HEPA) cartridges. The joints between the coveralls and boots and gloves will be sealed with duct tape. In addition, hard hats will be worn in the vicinity of all drilling operations. If breathing zone measurements with the HNU PIO consistently indicate concentrations greater than 5 parts per million (ppm), field team members must upgrade to Level B or further define the organic vapor constituents with detector tubes.or other methods. HCN concentrations above 10 ppm also warrant upgrading to Level Bas measured by the Monotoxe HCN detector. Combustible gas concentrations greater than or equal to 25 percent of the lower explosive limit will warrant site evacuation until the source can be located and eliminated. Task Level of Protection Geophysical survey Excavations--onsite Soil Sampling--onsite Soil Sampling--offsite Soil Borings--onsite Soil Borings--offsite Wells--offsite 16 *modified Level C/B Level C •modified Level C/B *modified *modified Level D Level D Level D Level D ..... ..... -------- - HOT LINE FORMER 55 GAL. DRUM STORAGE SUPPORT ZONE Figure 8-1 SITE WORK ZONES SOURCE: ESE, 1888. / 1-40 (WADE AVENUE EXTENSION) 290' • ' RIGHT OF WAY STONE EQUIPMENT DECON. PAD ~5 ----- -- ·KEY: CRC CONTAMINATION REDUCTION CORRIDOR FOR DECONTAMINATION PROCEDURES FORMER CHEMICAL STORAGE DUMPSTER NOT TO SCALE ENVIRONMENTAL SCIENCE AND ENGINEERING, INC. •.. I I I I I I I I I I I I I I I I I I I C-REMNCSU.l/HASP.10 . 12/31/86 Waste characterization after excavation Ground Water Sampling--offsite Level C/B •modified Level D *Includes chemical-resistant clothing (Tyvek®), chemical-resistant gloves and boots, eye/head protection for drillings, and full-face APR available for emergency. 8.2.2 Safety Equipment Basic emergency and first-aid equipment will be available at the onsite trailer (command post). This will include portable radios, first-aid kit, emergency eyewash, and fire extinguishers. The command post will be manned during all Level C (or higher) activities. When teams are downrange during these activities, communications will be maintained, and personnel will be available to assist in decontamination procedures for personnel and equipment. A wind sock or other wind direction instrument will be available in the event ·emergency evacuation becomes necessary. Air monitoring equipment includes use and calibration of an HNU No. 101 photoionizati6n detector (PID) for organic vapors, a Monotox® HCN detector, a Monitor 4® radiation alert meter, and an MSA® combustible-gas indicator. 8.3 COMMUNICATIONS 0 0 0 Portable Radios--Hand-held units will be utilized as much as possible by field teams for communication between downrange operations and the command post base station. Telephones--Due to the distance to the nearest phone line, a phone will not be available in the command post. However, a public phone is located at Carter-Finley Stadium, approximately 0.25-mile from the site. Hand signals--Hand signals will be employed by downrange field teams along with utilizing the buddy system. These signals are also very important when working with heavy equipment. The signals shall be known by the entire field team before operations commence and will be covered during site-specific training. Weather reports will be observed each morning and periodically during the day to anticipate inclimate weather and the resulting precautions to be taken. 18 • I I I I I I I I I I I I I I I I I I 9.0 MONITORING PROCEDURES 9.1 MONITORING DURING SITE OPERATIONS 9.1.1 Drilling Operations C-REMNCSU.l/HASP.11 12/31/86 Monitoring will be performed continuously by the HSO during the conduct of work. A PID will be utilized to monitor the breathing zone, the borehole, and all geological samples upon their retrieval. Drill cuttings will also be monitored. A combustible-gas indicator with an oxygen alarm will be used to monitor the borehole for the presence of combustible gases. Similar monitoring of any fluids produced during well development will also be conducted. 9.1.2 Excavation Operations Monitoring will be performed continuously during all excavation and sampling operations. A PID will be utilized to monitor the breathing zone, the excavated area, and any material taken from an excavation. The excavation will be monitored with a CGI and oxygen meter. 9.1.3 Other Operations Soil and well sampling will include continuous monitoring at. breathing zone height and at the well head upon opening. 9.2 MEDICAL SURVEILLANCE PROCEDURES FOR EVIDENCE OF PERSONAL EXPOSURE All REM III personnel and subcontractors who will be performing field work at the NCSU site will be required to have passed a REM III medical surveillance examination or the equivalent. A release for work will be confirmed by the ESE CHSS before an employee can begin hazardous site activities. The exam will be conducted annually (at a minimum) and upon termination of REM III work. Additional medical testing may be required by the ESE CHSS in consultation with the company physician and the HSO if an overt exposure or accident occurs or if other site conditions warrant further medical surveillance. 19 I I I I I I I I I I I I I I I I I I I ... .: · •.. :. .. .. ·-· .. ·-.... C-REMNCSU.l/HASP.12 12/31/86 10.0 SAFETY CONSIDERATIONS FOR SITE OPERATIONS 10.l GENERAL All field sampling will be performed under the level of protection described in Section 8.0. All onsite activities shall be limited to daylight hours and normal weather conditions. Inclimate weather includes extremes in temperature, wind, rain, and lightning. Wind direction will be observed periodically. In the event emergency evacuation is necessary, site personnel will exit the site. Personnel entering the site shall observe the buddy system at · all times and enter through the access control point. No smoking, eating, or drinking will be allowed onsite or before personal decontamination. Personnel will keep hands, tools, samples, and equipment away from face and exposed skin. Team members will maintain visual contact with one another and will be familiar with hand signals. 20 I I I I I I I I I I I I I I I . I I I I 11.0 DECONTAMINATION PROCEDURES C-REMNCSU.l/HASP.13 . 12/31/86 All personnel and equipment exiting the exclusion zone shall be thoroughly decontaminated. 11.1 LEVEL BAND C DECONTAMINATION (MODIFIED LEVEL D--OMIT STATION 15) Equipment Worn The full decontamination procedure outlined is for workers wearing Level Band c protection (with taped joints between gloves, boots, and suit). such protection consists of: 1. One-piece, hooded, chemical-resistant splash suit, 2. Full-face supplied air respirator, 3. Hard hat (drilling operations), 4. Chemical-resistant boots with steel toe and shank, 5. Boot covers, and 6. Inner and outer gloves. • Procedure for Full Decontamination Station 1: Segregated Equipment Drop Deposit equipment used on the site (tools, sampling devices and containers, monitoring instruments, radios, clipboards, etc.) on plastic drop cloths or in different containers with plastic liners. Each will be contaminated to a different degree. Segregation at the drop reduces the probability of cross-contamination. Equipment necessary is: 1. Containers of various sizes, 2. Plastic liners, and 3. Plastic drops cloths. Station 2: Boot Cover and Glove Wash Scrub outer boot covers and gloves with detergent/water solution. Equipment necessary is: 1. Container (20 to 30 gal), 2. Detergent/water solution, and 3. Two or three long-handle, soft-bristle scrub brushes. 21 I I I I I I I I I I I I •• I I I I I I Station 3: Boot Cover and Glove Rinse C-REMNCSU.l/HASP.14 12/31/86 Rinse off detergent water solution from Station 2 using copious amounts of water. Equipment necessary is: 1. Container (30 to 50 gal), 2. High-pressure spray unit, 3. Water, and 4. Two or three long-handle, soft-bristle scrub brushes. Station 4: Tape Removal Remove tape around boots and gloves and deposit in container with plastic liner. Equipment necessary is: 1. Container (20 to 30 gal), and 2. Plastic liners. Station 5: Boot Cover Removal Remov~ boot covers and deposit in container with plastic liner.· Equipment necessary is: 1. Container (30 to 50 gal), 2. Plastic liners, and 3. Bench or stool • Station 6: outer-Glove Removal Remove outer gloves and deposit in container with plastic liner. Equipment necessary is: 1. Container (20 to 30 gal), and 2. Plastic liners. Station 7: Suit/Safety Boot Wash Thoroughly wash splash suit and safety boots, respirator, and regulator assembly. Scrub wi_th long-handle, soft-bristle brush and copious amount of detergent/water solution. Repeat as many times as necessary. 22 I I I I I I I I I I I I I I I I I I I Equipment necessary is: 1. Container (30 to 50 gal), 2. Detergent/water solution, and C-REMNCSU.l/HASP.15 . 12/31/86 3. Two or three long-handle, soft-bristle scrub brushes. station 8: Suit/Safety Boot Rinse Rinse off detergent/water solution using copious amounts of water. Repeat as many times as necessary. Equipment necessary is: 1. Container (30 to 50 gal), 2. High-pressure spray unit, 3. Water, and 4. Two or three long-handle, soft-bristle scrub brushes. station 9: Cartridge or Air Change If workers leave Exclusion Zone to change cartridges (or air supply), this is the last step in the decontamination procedure. Worker's cannister is exchanged, new outer glove and boot covers donned, and joints taped. Worker returns to duty. Equipment necessary is: 1. canister (or mask), 2. Tape, 3. Boot covers, and 4. Gloves. station 10: Safety Boot Removal Remove safety boots and deposit in container with plastic liner. Equipment necessary is: 1. Container (30 to 50 gal), 2.· Plastic liners, 3. Bench or stool, and 4. Boot jack. Station 11:· Splash Suit Removal With assistance of helper, remove splash suit. Deposit in container with plastic liner. 23 I I I I I I I I I I I I I I I I I I I . ··-· ·:_ .. ·-··-·· Equipment necessary is: 1. Container (30 to 50 gal), 2. Bench or stool, and 3. Plastic liner. Station 12: Supplied Air Equipment Removal C-REMNCSU.l/HASP.16 . 12/31/86 While still wearing facepiece, remove regulator and belt assembly and place on designated area. Proceed to next station. Station 13: Inner-Glove Wash ·Wash inner gloves with detergent/water solution that will not harm skin. Repeat as many times as necessary. Equipment necessary is: 1. Detergent/water solution and 2. Basin or bucket. Station 14: Inner-Glove Rinse Rinse inner gloves with water. Repeat as many times as necessary. Equipment necessary is: 1. Water, 2. Basin or bucket, and 4. Small table. Station 15: Facepiece Removal Remove facepiece. Avoid touching face with gloves. facepiece in container with plastic liner. Equipment necessary is: 1. Container (30 to 50 gal) and 2. Plastic liners. Station 16: Inner-Glove Removal Deposit Remove inner gloves and deposit in container with plastic liner. Equipment necessary is: 1. 2. Container (20 to 30 gal) and Plastic liners. 24 I I I I I I I I I I I I I I I I I I I Station 17: Inner-Clothing Removal C-REMNCSU.l/HASP.17 12/31/86 Remove clothing soaked with perspiration. Place in container with plastic liner. Do not wear inner clothing offsite since there is a possibility small amounts of contaminants have been transferred in removing fully encapsulating suit. Equipment necessary is: l. Container (30 to so gal) and 2. Plastic liners. Station 18: Field Wash Shower as soon as possible. Equipment necessary is: l. Water, 2. Soap, 3. Tables, 4. Wash basins or buckets, and 5. Field showers. Station 19: Redress Put on clean clothes. A dressing trailer is needed in inclement weather. ;~ ,/ Equipment necessary is: l. Tables, 2. Chairs, 3. Lockers, and 4. Clothes. 25 I I I I I I I I I I I I I I I I I I C-REMNCSU.l/HASP.18 . 12/31/86 12.0 DISPOSAL PROCEDURES All discarded materials, waste materials, or other objects shall be handled in such a way as to preclude the potential for spreading contamination, creating a sanitary hazard, or causing litter to be left onsite. All potentially contaminated materials (e.g., clothing and gloves) will be bagged or drummed as necessary and segregated for disposal. All contaminated waste materials shall be ·disposed of as required by the provisions included in the contract and consistent with REM III and regulatory provisions. All noncontaminated materials shall be collected and bagged for appropriate disposal as normal domestic waste. All wastes produced during decontamination of equipment and personnel will be contained and drummed onsite until further arrangements can be made. 26 I I I I I I I I I I I I I I I I I I . -·-.... ; .. -.. ·-. .-.. ·• : .... , .. ······-· 13.0 EMERGENCY PLAN C-REMNCSU.l/HASP.19 12/31/86 As a result of the hazards at the site and the conditions under which operations are conducted, the possibility of an emergency situation developing is real. · The Site Emergency Coordinators are: Field Operations Leader HSO (Alternate) Al Quarles Dan Endicott The emergency coordinator will implement the plan outlined below whenever conditions at the site warrant such action. The coordinator is responsible for assuring the evacuation, emergency treatment, emergency transport of site personnel as necessary, notification of emergency services, and appropriate management staff. 13.l EVACUATION In the event of an emergency situation (e.g., fire, explosion, . or significant release of toxic gases), an air horn or other appropriate device will be sounded for approximately 10 seconds, indicating the inititation of evacuation procedures. All personnel in both the restricted and nonrestricted areas will assemble upwind in the Support zone. The location shall be upwind of the site as determined by the wind direction indicator. For efficient and safe site evacuation and . assessment of the emergency situation, the Emergency Coordinator will have authority to initiate proper action if outside services are required. Under no circumstances will incoming personnel or visitors be allowed to proceed into the area once the emergency signal has been given. The HSO or HSO Designee must see that access for emergency equipment is provided and that all sources of ignition have been shut down once the alarm has been sounded. Once the safety of all personnel is established, the Raleigh Fire Department and other emergency response groups will be notified by telephone of the emergency. 13.2 POTENTIAL OR ACTUAL FIRE OR EXPLOSION In case of potential or actual fire or explosion, all personnel will immediately evacuate the site (air horn will sound for lo-second intervals). Notify local fire and police department and other appropriate emergency response groups if lower explosion level (LEL) values are above 25 percent in the work zone or if an actual fire or explosion has taken place. Fire Dept. --911 Police Dept. --911 27 I I I I I I I I I I I I I I I I I I I C-REMNCSU.l/HASP.20 12/31/86 13.3 ENVIRONMENTAL INCIDENT In the event of an environmental incident, control or stop spread of contamination if possible. Notify the U.S. Coast Guard Response Center and local authorities of possible evacuation of ·immediate area. Notify Site Manager, CHSS Regional Manager, and USEPA emergency response groups. 13 • 4 PERSONNEL INJURY Emergency first aid shall be performed onsite as deemed necessary. The individual will be decontaminated and trans- ported to Rex Hospital, if necessary. The HSO will supply medical data sheets to appropriate medical personnel and complete the incident report designated in HS-1.12. Hospital--(919) 755-3100 Rescue --911 · The ambulance/rescue squad shall be contacted for transport as necessary in an emergency. During the initial reconnaissance, a primary hospital and backup facility were located. A detailed route to and from the site is shown in Figure 13-1. The hospital route location map shall be conspicuously posted at the site command post. Primary Hospital Route: Take Old Trinity Road East to Blue Ridge Road North. Go north on Blue Ridge Road approximately 1.5 miles to Rex Hospital at 4420 Lake Boone Trail. 13.5 OVERT PERSONNEL EXPOSURE SKIN CONTACT: INHALATION: INGESTION: Use copious amounts of soap and water. Wash/rinse affected area thoroughly, then provide appropriate medical attention. Eyewash and emergency shower or drench system will be provided onsite at the CRZ and/or Support Zone as appropriate. Eyes should be rinsed for 15 minutes after chemical contamination. Move to fresh air and/or, if necessary, decontaminate and transport to hospital. Decontaminate and transport to emergency medical facility 28 I I I I I I I I I I I I I I I I I I I ffEM/11 HCSV r2m1,1 --' . ..J Figure 13-1 HOSPITAL ROUTE MAP SOURCE: ESE, 1988. 29 ENVIRONMENTAL SCIENCE AND ENGINEERING, INC. I I I I I I I I I I I I I I I I I I I . --••' ····-·-·-·-·--' .... : ··-·. -··--.... ··., .... ·.· -·······•·--· ...... . PUNCTURE WOUND C-REMNCSU.l/HASP.21 12/31/86 OR LACERATION: Decontaminate and transport to emergency medical facility. HSO will provide medical data sheets to medical personnel as requested (see Section 14.0). Hospital--(919) 755-3100 Rescue --911 National Poison Control Center--1(800) 822-9761 13.6 ADVERSE WEATHER CONDITIONS In the event of adverse weather conditions, the HSO will determine if work can continue without sacrificing the health and safety of field workers. Some of the items to be considered prior to determining if work should continue are: 0 0 0 0 0 Potential for heat stress and heat-related injuries, Potential for cold stress and cold-related injuries, Treacherous weather-related working conditions, Limited visibility, and · Potential for electrical storms. 30 I I I I I I I I I I I I I I I I I I I -----· --. 14.0 AUTHORIZATIONS C-REMNCSU.l/HASP.22 12/31/86 Personnel authorized to enter the NCSU site while operations are being conducted must be certified by the ESE CHSS. Authori-zation will involve completion of appropriate training courses, medical examination requirements, and review and sign-off of this HASP. All personnel must utilize the buddy system or trained escort, and check in with the Field Team Leader at the command post. 1. ESE Personnel Authorized to Perform Work Onsite: 1. Carolyn Poi;mell 11. 2. Al Quarles 12. 3. Leonard Carter 13 4. Charles Hau:!;:]: 14. 5. Dan Endicott 15. 6. Kevin Gara 16. 7. Pera !;!rake 17. 8. 18. 9. 19. 10. 20. Other Personnel Authorized to Enter Site: 1. 2. 3. 4. 5. ZPMO Personnel REM III Regional Personnel EPA Personnel State Environmental Personnel Police. Fire. Emergency Personnel 31 6. Technos Personnel 7. Drilling Subcontractor Personnel 8. Excavation Subcontractor Personnel 9. Site Survey Subcontractor Personnel 10. Waste Disposal Transport Personnel I I I I I I I I I I I I I I 15,0 Medical Data Sheet and Field Team Review Thi• brief Medical Data Sheet will be completed by all oniite personnel and ·will be kept in the Command Post durihq., the conduct of site operations. Completion is required in addition to compliance with the Medical Surveillance Program :i:equirements described in the REM III Proqram Health and Safety Plan. This . data sheet will accompany any personnel when medical assistance 1• needed or if transport to hospital facilities is required. I fS Name l Home Telephone {9<'Jl{-) 37 P-776? Addre f..4,,.-t.. Ga,i,uv,'ll., L Aqe 3 Heiqht S'; t 1' Weiqht _.__'f() ______ _ Name of Next of ltin ,,.,.,,),, ll~d° ~;"' GrarJ f-. ;,..i-JF,-x,;s (2-''f U,2,,-71/"?, Druq or other Aller;ies -~------------------Particular Sensitivities N,rr~ ---------------------:00 You Wear contacts? _,__es;;.... _________________ _ Provide a Checklist of Previous Illnesses or Exposures to Hazardous Chemicals~#,~""""-'=------------------- What medications are you presently usinq? _M_6"",;...;....a; ________ _ Do you have any medical restrictions? _N_D _________ _.. __ :!fame, Address, and Phone Number of personal physici&n1 A r,,Jiv~ & '1J_'~ +-G.,-l-&,..+,.,,,..., I ==--===========-====-======-=====-=-=====---=====-==-========= I I I I I am the individual described above. this HASP. ~;fiid(. 32 I have read and understand ' Date I I I I I I I I I I I I I I I I I I I Medical Data Sheet and Field Team Review Thi• brief Medical Data Sheet will be completed by all onsite persoMel and will be kept in the Command Post during the conduct of site operations. Completion is required in addition to compliance with the Medical Surveillance Program requirements described in the REM III Program Health and Safety Plan. This data sheet will accompany any personnel when medical assistance is needed or if transport to hospital facilities ia required. Project J'(>f,.1'. 4',,.,;.-,,.1 ,vr Name W,'//4',f,,, /1/b.,,f o.,,_,,, i,,.s Address a_;)_ 1,:,,,, <2a k L,.,.,, Home Telephone "(f5-93"13 Age .'26 Height --=~'--'J.9_" ____ Weight _,1.(_"'t'-'-!:;o:,._ ___ _ Drug or other Allergies Particular Sensitivities Do You Wear Contacts? ___ M....,.o _________________ _ Provide a Checklist of Previous Illnesses or Exposures to Hazardous Chemicals _____________________ _ What medications are you presently using? __,,½..._.o_n~e"'-------- Do you have any medical restrictions? _...:;..o::;... _________ _ Name, Address, and Phone Number of personal physician: Ed ...,A ~I I(« ,. .r, :;t :s , Ml) ;, ,4 ' $ =======-=------=--------------------------=------=------=--== :r am the individual described above. ·this HASP. 33 I have read and understand I I I I I I I I I I I I· I I I I I I I Medical Data Sheet and Field Team Review Thi• brief Medical Data Sheet will be completed by all onsite personnel and will· be kept in the Command Post during the conduct of site operations. Completion is required in. addition to compliance with the Medical Surveillance Program requirements described in the REM III Program Health and Safety Plan. This data sheet will accompany any personnel when medical assistance i• needed or if transport to hospital facilities is required. ' ' i ,, ,:-•·.1 . .: /I 1 .' , ·. . _,-<'A..., • ~ . .! .l'-<--<-7t~ Name IA-~;:,:/ 'iiome Telephone fo £/ • 332 -ZI./"'. _c;; Address (; ·io S:,.,: 8.µ.. 7.R Age .2~ Height S-' /C ,, Name of Next of Jtin _..4 .. 1_~ v..._.l...,r...,.~---~--_~_":'"_·( _____________ _ Drug or other Allergies --~-/~,-•c~•---------------- Particular Sensi ti vi ties fv' ,:. ,._t. .....:.__,...;.;;.;.... _______________ _ Do You Wear Contacts? Provide a Checklist of Previous Illnesses or Exposures to Hazardous Chemicals _..:;.;.l~-~~":a:... _________________ _ What medications are you presently using? -~M ...... f:N ...... _______ _ Do you have any medical restrictions? Name, Address, and Phone Number of personal physician: -'/I _I, l, •.. ~ .• -f '1· •. F. .· / /( ,-Ll-4l C:: L,M..QK!"':: • .,• ~ ·.~~-...--~-. --==--=======-=======-========-=========-=-==-===-==========-= I am the individual described above. I have read and understand this HASP. t,di_ ~ti / '-/2 t/ lf~ Signature Date 34 I I I I I I I I I I I I I I I I I I I C-REMNCSU.l/HASP.24 12/31/86 16.0 FIELD TEAM REVIEW Each field team member shall sign this section after site-specific training is completed and before being permitted to work on site. I have read and understand this Site-Specific Health and Safety Plan. I will comply with the provisions contained therein. Site/Project: Name Printed Signature Date • 35 I I I I I I I I I I I I I I I I I I I 17.O APPROVALS C-REMNCSU,l/HASP,25 12/31/86 By their signature, the undersigned certify that this HASP is approved and will be utilized at the NCSU Lot 86 site. CC/:r /;r o~,. £,.d,~.,;, Health and Safety Officer Company Health and Saf Supervisor Company Designate~✓Lead // -- y REM III Health and Safety Manager 36 Date Date Date Date Date ;; ;< IN :!! .l~ ;;; i~ N N ia :() = :id lil ;< ¥ a :;i ;< 1 N ~ 8~ ;;; ~ ;< w ;; ~ :~ 1\1 ~ l- ~ = ~- :,! ~ ~~ 1\1 .l ~ ::i . ~ • z ~ N :!~ ~ N :e. ~ ~ a ~ ~ ~ w i .!_ .. = ♦ ♦ .. • .. =· :· = e .. I 1. I I ! i 11-------------------------------•• •• u u u u u u u ~ u u u u :;:_ u ~ 'IL'-' u u u u u u u u u u u u u u u u u I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I UNITED STATES ENVIRONMENTAL PROTECTION AGENCY REGION IV · JAN 2 7 1987 4WD-ER Lee Crosby 345 COURTLAND STREET ATLANTA, GEORGIA 30365 North Carolina Waste Management Branch N'.)rth Carolina D=partrrent of Human Resources P.O. Box 2091 Raleigh, North Carolina 27602 D=ar Ms. Crosby: 1-"ea 4 1887 Cfqc l 4 NAGf.~ We are sending you a copy of the N'.:lrth Carolina State university LOt #86 Draft RI/FS W'.:>rk Plan for review and canment. It is requested that any comments _you may have be provided to us by February 9, 1987. If you have any questions, or need additional information, please contact Drew Puffer at (404) 347-2234. Sincerely, ~t-~ Jon Johnston Unit Chief Investigations and Canpliance Section Schedule ·Name: NC STATE RI/FS CRITICAL PATH SCHEDULE Project Manager: R. H. BOYD, Jr/C. POPPELL As of date: 13·Jan·87 Early Early Late Late Task How Long Start End Start End . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -.......... . -....... . .... ---.. . --. -... -------···-- ISSUE DRAFT FIELD OPER PLAN 11 days 2·Jan·87 16·Jan·87 2·Jan·87 16·Jan·87 ISSUE DRAFT WORK PLAN 11 days 2-Jan-87 16·Jan·87 2-Jan-87 16-Jan-87 EPA REVIEW DRAFT FIELD OP PL~~-15 days 19·Jan·87 6-Feb-87 19-Jan-87 6-Feb-87 EPA REVIEW DRAFT WORK PLAN 15 days 19·Jan·87 6-Feb-87 19·Jan·87 6-Feb-87 INCOl!P COMMENT ISSUE FINAL FOP 10 days 9-Feb-87 20-Feb-87 9·Feb·87 20·Feb·87 INCOl!P COMMENTS ISSUE FINAL WP 10 days 9-Feb-87 2D·Feb·87 9-Feb-87 20·Feb·87 EPA APPROVE WORK PLAN 15 days 23·Feb·87 13·Mar·87 23-Feb-87 13·Mar·87 PREPARE DRILLING SPEC 15 days 16-Mar-87 ·3-Apr-87 16-Mar-87 3-Apr-87 QC REW/ISSUE DRILLING INQUIRY 1o·days 6·Apr·87 17·Apr·87 6·Apr·87 17·Apr·87 DRILLING BID PERICX> 20 days 20·Apr·87 15-May-87 20·Apr-87 15·May·87 EVALUATE/AWARD DRILLING 15 days 18·May·87 5-Ji.n-87 18·May·87 5-Ji.n-87 DRILL 1108/CONSRT DECON FACILIT 10 days 8-Ji.n-87 19-Ji.n-87 8-Ji.n-87 19-Ji.n-87 DRILL WELLS 27 days 22-Ji.n-87 29·Ju1·87 22-Ji.n-87 29·Jul-87 DEVELOP WELLS 10 days 30-Jul-87 12•Aug•87 30-Jul ·87 12-Aug-87 COLLECT IIOIIITOI! WELL SAMPLES 7 days 13•Aug·87 21 ·Aug-87 13·Aug•87 21 ·Aug-87 REMIII LAB ANALYSIS 27 days 14•Aug•87 22-Sep-87 14•Aug•87 22·Sep·87 DATA VALIDATE GW SAMPLES 10 days 23·Sep·87 6-0ct-87 23·Sep·87" 6·0ct·87 EVALUATE GW CHEM DATA 5 days 7-0ct-87 13-0ct-87 7-0ct-87 13-0ct-87 INTERPRET/CONSOLIDATE DATA 11 days 14-0ct-87 28-0ct-87 14-0ct-87 28-0ct-87 INTERIM STATUS MEETING w/EPA 1 day 29-0ct-87 29-0ct-87 29-0ct-87 29-0ct-87 CON1AMINATIOII ASSESSMENT 20 days 30-0ct-87 30·.Nov-87 30-0ct-87 30-Nov-87 RISK ASSESSMENT (CHEM SELECT) 5 days 1·Dec·87 7·Dec·87 1 ·Dec-87 7·Dec·87 RISI( ASSESSMENT (EXPOSE ASSESS 20 days 8-Dec-87 6-Jan-88 8-Dec-87 6-Jan-88 RISI( ASSESSMENT (TOXICITY) 20 days 8-Dec-87 6-Jan-88 8-Dec-87 6-Jan-88 RISK CHARACTERIZATION 10 days 7·Jan·88 20·Jan·88 7·Jan·88 20·Jan·88 COMPLETE DRAFT RI REPORT 10 days 21 ·Jan-88 3·Feb·88 21-Jan-88 3-Feb-88 QC REW/ISSUE DRAFT RI 10 days 4·Feb·88 17·Feb·88 4·Feb·88 17-Feb-88 EPA REVIEW DRAFT RI REPORT 15 days 18· Feb-88 9•Mar·88 18-Feb-88 9-Mer-88 REVISE DRAFT RI TO DRFT FINAL 15 days 10-Mar-88 30-Mar-88 10-Mar-88 30-Mar-88 COMPLETE PRELIMINARY FS REPORT 5 days 31 ·Mar-88 6-Apr-88 31 ·Mar-88 6-Apr-88 QC REW/ISSUE DRAFT FS REPORT 10 days 7·Apr·88 20-Apr-88 7·Apr·88 20-Apr-88 EPA REW DRAFT FS REPORT 15 days 21·Apr·88 11·May·88 21 ·Apr-88 11-May-88 REVISE FS REPORT TO FINAL 10 days 12-May-88 25-May-88 12-May-88 25-May-88 ISSUE FINAL RI/FS REPORT 1 day 26-May-88 26·May·88 26-May-88 26·May·88 -- --- - - - ---- - - -- --.. -