NCD122263825_20060811_JFD Electronics - Channel Master_FRBCERCLA SPD_Industrial Users Reports 2005 - 2006-OCR

•
ENSR Consulting and Engineering (NC), Inc.
7041 Old Wake Forest Road. Suite 103. Raleigh, North Carolina 27616
T 919 872 6600 F 919 872 7996 www.ensr.aecom .. com
August11,2006
Mr. Larry Thomas
City Engineer
City of Oxford
P.O. Box 1307
Oxford, North Carolina 27565
RE: Industrial Users Report for July 2006
JFD Electronics/Channel Master NPL Site, Oxford, North Carolina.
Dear Mr. Thomas:
ENSR AECOM
On behalf of The Unimax Corporation and Avnet, Inc., ENSR Consulting and Engineering (NC), Inc. is
submitting the Quarterly Industrial User Pennit report for the months of May, June, and July 2006. This
report is prepared in accordance with pennit requirements for the discharge of treated groundwater at
the above referenced site.
If you have any questions, please contact us at [phone].
Sincerely,
ENSR Consulting and Engineering (NC), Inc.
Gerald Y. Homad
Project Engineer
Enclosure
Senior Program Manager
cc: Brian Kempner, The Unimax Corporation (w/o lab attachment)·
S. Alan Lazar, Avnet, Inc. (w/o lab attachment)
Steve Earp, Smith Helms Muliss & Moore (w/o lab attachment)
David Mattison, NCDENR Superfund
Ken Lucas, USEPA Superfund
Nanjun Shelly, P.E., ENSR
File
S:\PUBS\PROJECT\C\Channe1Master\Quarter1y tUReports\2006\Aug 2006\tUR Letter Aug 2006.doc
•
•
•
INDUSTRIAL USER REPORTING FORM
I.U. PERMIT NO: G001 DISCHARGE NO: ___ _,,_00"-1,...._ ____ _
MONTIIS: May, June. and July -YEAR: 2006
I.U. NAME: JFD Electronics/Channel Master CLASS: COUNTY: Granville
OPERATOR IN RESPONSIBLE CHARGE (ORC): ENSR Consulting & Engineering /NC). Inc.
LABORATORY PERFORMING ANALYSIS: STL-Savannah Laboratories
PERSON(S) COLLECTING SAMPLES: Gerald Hornaday, P.E. {ENSRl. Joe Ladd (ENSR)
CHECK BLOCK IF ORC HAS CHANGED 0
SEND REPORT TO: City Engineer
City of Oxford
P.O. Box 1307
Oxford, NC 27565
Facility Status: (Please check one of the following)
All monthly averages and/or other limitations do meet permit monitoring requirements . [gJ
(Compliant)
All monthly averages and/or other limitations do not meet permit monitoring requirements. D
(Noncompliant)
If the facility is noncompliant, please comment on corrective actions being taken in respect to
equipment, operation, maintenance, etc. and a time table for improvements to be made.
(Attach additional sheets if necessary)
I certify that this Report is accurate and
complete to the best o my knowledge:
Signature of Permittee Representative
William H. Doucette, Jr., Ph.D.
Date:
• TABLE 1. GROUNDWATER REMEDIATION SYSTEM DISCHARGE MONITORING REPORT, CITY OF OXFORD, NORTH CAROLINA
. '
•
•
1.U. PERMIT NO:
DISCHARGE NO:
MONTHS:
YEAR:
1.U. NAME:
COUNTY:
OPERATOR IN RESPONSIBLE CHARGE (ORC):
LABORATORY PERFORMING ANALYSIS:
PERSON($) COLLECTING SAMPLES:
PARAMETER
Dally Average Flow (MGO)
Tetrachloroethylene
1,1-0lchloroethane
cls-1,2 Dlchloroethene
Chlorobenzene
Toluene
1, 1..0lchloroethylene
trans-1,2 Olchloroethylene
Trtchloroethene
Vlnyl Chloride
Cyanide (total)
pH
Temperature
Monitoring requirement only.
MGD MIiiion Gallons per day.
µg/L Micrograms per liter.
mg/L Milligrams per liter.
SU Standard Units.
°C Degrees Centigrade.
G001
001
May, June, and July
2006
JFD Electronics/Channel Master NPL Site
Granville
ENSR Consulting & Engineering (NC), Inc.
STL Savannah Laboratories
Gerald Hornaday, P.E. (ENSR); Joe Ladd (ENSR)
PERMIT LIMITS UNITS SAMPLE
Dally Maximum TYPE
0.040 MGD Meter
µg/L Grab
µg/L Grab
µg/L Grab
µg/L Grab
µg/\. Grab
µg/\. Grab
µg/L Grab
µg/L Grab
µg/\. Grab
0.05 mg/L Grab
5.0to 10.0 SU Grab
40 "C Grab
< Compound was not detected above the quantitation limit .
G:'cnvl..lFDCHANNWC0202.170',Clty of Oxford\lURTable Aug 2006\Tab!~ 1\8110/2006
LAB M(?NTHLY MEASUREMENT
METHOD OATES
05/12/06 06127106 07/28/06
Field 0.020 0.020 0.022
8260 <1.0 <1.0 <1.0
8260 <1.0 <1.0 <1,0
8260 <1.0 <1,0 <1.0
8260 <1.0 <1,0 <1.0
8260 <1.0 <1.0 <1.0
8260 <1.0 <1.0 <1.0
8260 <1.0 <1.0 <1.0
8260 <1.0 <1.0 <1,0
8260 <1.0 <1.0 <1.0
335.2 0.0068 0.0064 0.0057
Field 8.28 8.42 8.39
Field 20.9 20.6 20.7
•
May 2006 Analytical Data
•
•
•
•
Project Manager: Kathryn Smith
SEVERN
. TRENT
ANALYTICAL REPORT
Job Number: 680-16671-1
Job Description: Channel Master
For:
ENSR International
7041 Old Wake Forrest Road
Raleigh, NC 27616.
Attention: Mr. Gerald Hornaday
Kathryn Smith
Project Manager I
[e-mail]
05/26/2006
The test results in this report meet all NELAP requirements for parameters for which accreditation is required or available. Any
exceptions to NELAP requirements are noted in this report. Pursuant to NELAP, this report may not be reproduced, except in full,
without the written approval of the laboratory. All questions regarding this test report should be directed to the STL Project Manager
who signed this test report. ·
Severn Trent Laboratories, Inc.
STL Savannah 5102 LaRoche Avenue, Savannah, GA 31404
Tel [phone] Fax [phone] www.stl-inc.com
Page 1 of 14
• METHOD SUMMARY
•
•
Client: ENSR International
Description
Matrix: Water
Volatile Organic Compounds by GC/MS
Purge-and-Trap
Cyan_ide,Total (Semi-Automated Colorimetry)
Distillation/Cyanide
LAB REFERENCES:
STL_-SAV = STL-Savannah
METHOD REFERENCES:
Lab Location Method
STL-SAV
STL-SAV
STL-SAV
STL-SAV
SW846 8260B
MCAWW 335.4
Job Number: 680-16671~1
Preparation. Method
SW846 5030B
Distillation
MCAWW-"Methods For Chemical Analysis Of Water And Wastes", EPA-600/4-79-020, March 1983 And
Subsequent Revisions .
SW846 -"Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November. l986
And Its Updates .
STL Savannah
Page 2 of 14
•
•
Client: ENSR International
Lab Sample ID
680-16671-1
6B0-16671-2TB
STL Savannah
Client Sample ID
Effluent
Trip Blank
SAMPLE SUMM~RY
Client Matrix
Water
Water
Page 3 of 14
Date/Time
Sampled
05/12/2006 .1200
05/12/2006 0000
Job Number: 680-16671-1
Date/Time·
Received
05/16/2006 0920
05/16/2006 0920
-li~nt: ENSR International
Client Sample ID: Effluent
Lab Sample ID:
Client Matrix:
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
680-16671-1
Water
8260B
5030B
1.0
8260B Volatile Organic Compounds by GC/MS
Analysis Batch: 68~5638
05/25/2006 2135
05/25/2006 2135
Analytical Data
Job Number: 680-16671-1
Date Sampled: 05/12/2006 1200
Date Received: 05/16/2006 0920
Instrument ID: GC/MS Volatiles. 0
Lab File ID: 02134.d
Initial WeighWolume: 5 ml
Final WeighWolume: 5 ml
Analyte Result (ug/L) Qualifier RL
• Chloromethane
Bromomethane
Vinyl chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1, 1-Dichloroethene
. 1, 1-Dichloroethane
•
·s,1 ,2-Dichloroethene
ans-1,2-Dichloroethene
Chloroform
1,2-Dichloroethane
Methyl Ethyl Ketone
1, 1, 1-Trichloroethane
Carbon tetrachloride
Dichlorobromomethane
1, 1,2,2-Tetrachloroethane
1,2-Dichloropropane
irans-1, 3-Dichloropropene
Trichloroethene
Chlorodibromomethane
1, 1,2-Trichloroethane
Benzene
cis-1, 3-Dichloropropene
Bromoform
2-Hexanone
methyl isobutyl ketone
T etrachloroethene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Xylenes, Total
Surrogate
Toluene-dB
4-Bromofluorobenzene
• Dibromofluoromethane
STL Savannah
1.0 u 1.0.
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0.
5.0 u 5.0
25 u 25
2.0 u 2.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
10 u 10
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
10 u 10
10 u 10
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
2.0 u 2.0
%Rec Acceptance Limits
93 79 • 122
98 77 • 120
101 75 • 123
Page 4 of 14
-lient:. ENSR International
Client Sample ID: Trip Blank
. Lab Sample ID:
Client Matrix:
Method:
Preparation:
Dilution:
Date Analyzed:
. Date Prepared:
6B0-16671-2TB
Water
8260B
5030B
1.0
8260B Volatile Organic Compounds by GC/MS
Analysis Batch: 68~5723
05/26/2006 0841
05/26/2006 0841
Analytical Data
Job Number: 680-16671-.1
Date Sampled: 05/12/2006 0000
Date Received: 05/16/2006 · 0920
Instrument ID: _GC/MS Volatiles -O
Lab File ID: 02161.d
Initial WeighWolume: 5 ml
Final WeighWolume: 5 ml
Analyte Result (ug/l) Qualifier RL
• Chloromethane
Bromomethane
Vinyl chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1, 1-Dichloroethene
1, 1-Dichloroethane
·. Ms-1,2-Dichloroethene
~ns-1,2:Dichloroethene
Chloroform
1,2-Dichloroethane
Methyl Ethyl Ketone
1, 1, 1-Trichloroethane
Carbon tetrachloride
Dichlorobromomethane
. 1,1,2,2-Tetrachloroethane
1,2-Dichloropropane
trans-1,3-Dichloropropene
Trichloroethene
Chlorodibromomethane
1, 1,2-Trichloroethane
_Benzene
cis-1, 3-Dichloropropene
Bromoform
2-Hexanone
methyl isobutyl ketone
T etrachloroethene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Xylenes, Total
Surrogate
Toluene-<lB
4-Bromofluorobenzene
• Dibromofluoromethane
STL Savannah
1.0
1.0
1.0
1.0
5.0
25
2.0
1.0
1.0
1.0
1.0
1.0
1.0
10
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
10
1.0
1.0
1.0
1.0
1.0
2.0
%Rec
94
96
92
Page 5 of 14
u· 1.0
u 1.0
u· 1.0
u 1.0
u 5.0
u 25
u 2.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 10
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u· 10
u 10
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 2.0
Acceptance Limits
79 -122
77 -120
75 -123
-lient ENSR International
Client Sample ID:
Lab Sample ID:
Client Matrix:
Analyte
Cyanide, Total
•
STL Savannah
Effluent
680-16671-1
Water
Result
0.0068
Anly Batch: 680-44924
Prep Batch: 680-44851
General Chemistry
Qual Units
mg/L
Date Analyzed 0511712006 1230
Date Prepared: 05117/2006 0730
Page 6 of 14
Analytical Data
Job Number: 680-16671-1.
Date Sampled:
Date Received:
RL
0.0050
05112/2006 1200
05/16/2006 0920
Dil Method
1.0 335.4
•
Client: ENSR International
' '
• Lab Section Qualifier
GC/MSVOA
u
•
General Chemistry
u
•
STL Savannah
DATA REPORTING QUALIFIERS
Job Number: 680-16671-1
Description
Analyte was nof detected at or above the rep·orting limit.
LCS, LCSD, MS, MSD, MD, or Surrogate exceeds the control
limits
Analyte was not detected at or above the reporting limit.
Page 7 of 14
• Quality Control Results .
Client: ENSR International Job Number: 680-16671-1
Surrogate Recovery Report
82608 Volatile Organic Compounds by GC/MS
Client Matrix: Water
Lab Sam11le I!;! Client Sample (BFB) (DBFM) (TOL)
(%Rec) (%Rec) (%Rec)
LCS 680-45638/4 102 100 88
LCS 680-45723/2 111 91 86
MB 680-45638/6 98 103 92
MB 680-45723/5 97 96 94
680-16671-1 Effluent 98 . 101 93
· 680-16671-2TB Trip Blank 96 92 94
Surrogate Acceptance Limits
(BFB) 4-Bromofluorobenzene 77 -120
.DBFM) Dibromofluoromethane · 75 -123
TOL) Toluene-dB 79 -122
•
STL Savannah Page 8 of 14
Client: ENSR International
Method Blank -Batch: 680-45638
Lab Sample ID: MB 680-45638/6
Client Matrix: Water
Dilution: 1.0
Date Analyzed: 05/25/2006 1252
Date Prepa_red: 05125/2006 1252
Analyte
Chloromethane
Bromomethane
Vinyl chloride
Chloroethane
. Methylene Chloride
Acetone
Carbon disulfide
1; 1:Dichloroethene
1, 1-Dichloroethane
•
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Chloroform
1,2-Dichloroethane
•
Methyl Ethyl Ketone
1, 1, 1-Trichloroethane_
Carbon tetrachloride
Dichlorobromomethane
1, 1,2,2-Tetrachloroethane
1,2-Dichloropropane
trans-1, 3-Dichloropropene
Trichloroethene
Chlorodibromomethane
1, 1,2-Trichloroethane
Benzene
cis-1, 3-_Dichloropropene
Bromoform
2-Hexanone
methyl iscibutyl ketone
Tetrachloroethene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Xylenes, Total
Surrogate
Toluene-dB
4-Bromofluorobenzene
Dibromofluoromethane
Analysis Batch: 680-45638
Prep Batch: NIA
Units: ug/L
Result
1.0
1.0
1.0
1.0
5.0
25
2.0
1.0
1.0
1.0
1.0
1.0
1.0
10
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
10
1.0
1.0
1.0
1.0
1.0
2.0
%Rec
92
98
103
Qua!
u
u u
u
u
u
u u
u
u u
u
u u
u u
u u
u
u
u u
u
u
u
u u ·u
u
u
u
u
u u
Calculations are performed before rounding to avoid round-off errors in calculated results.
STL Savannah Page 9 of 14
Quality Control Results
Job Number:_ 680-16671-1
Method: 8260B
Preparation: 5030B
Instrument ID: GC/MS Volatiles -0
Lab File ID: oq612.d
Initial WeighWolume: 5 ml
Final WeighWolume: 5 ml
RL
1.0
1.0
1.0
1.0
5.0
25
2.0
1.0
1.0
1.0
1.0
1.0
1.0
10
1.0
1.0
1.0
1.0
1.0
1.0.
1.0
1.0
1.0
1.0
1.0
1.0
10
10
1.0
1.0
1.0
1.0
1.0
2.0
Acceptance Limits
79 -122
77 -120
75 -123
• Client: ENSR International
Laboratory Control Sample -Batch: 680-45638
Lab Sample ID: LCS 680-45638/4
Client Matrix: Water
Dilution: 1. O
Date Analyzed: 05/25/2006 1140
Date Prepared: 05/25/2006 1140
Analyte
. Chloromethane
Bromomethane
Vinyl _chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1, 1-Dichloroethene
· 1,1-Dichloroethane
· cis-1,2-Dichloroethene
•
rans-1,2-Dichloroethene
Chloroform
1,2-Dichloroethane
•
Methyl Ethyl Ketone
1, 1, 1-Trichloroethane
Carbon tetrachloride
Dich\orobromomethane
1, 1,2,2-Tetrachloroethane
1,2-Dichloropropane
trans-1,3-Dichloropropene
T richloroethene
Chlorodibromomethane
1, 1,2-Trichloroethane
Benzene
cis-1,3-Dichloropropene
Bromoform
2-Hexanone
methyl isobutyl ketone
Tetrachloroethene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Xylenes, Total
Analysis Batch: 680-45638
Prep Batch: NIA
Units: ug/L
Spike Amount Result
50.0 . 25.9
50.0 31.4
50.0 31.3
50.0 31.5
50.0 44.3
100 183
50.0 43.5
50.0 44.0
50.0 43.7
50.0 46.7
50.0 46.2
50.0 48.6
50.0 43.0
100 141
50.0 46.4
50.0 48.0
50.0 46.3
50.0 54.3
50.0 409
50.0 . 50.7
50.0 45.6
50.0 57.5
50.0 44.9
50.0 43:4
50.0 49.2
50.0 62.9
100 136
100 94.5
50.0 56.4
50.0 45.8
50.0 52.1
50.0 51.3
50.0 52.4
150 . 154
Quality Control Results
Job Number: 680-16671-1
Method: 8260B
Preparation: 5030B
Instrument ID: GC/MS Volatiles: 0
Lab File ID: oq608.d
Initial WeighWolume: 5 ml
Final WeighWolume: 5 ml
%Rec. Limit Qua!
52 51 -133
63 21 -176
63 59-136
63 40 -171
89 67 -128
183 20 -183
87 60-130
88 64 -132
87 70-127
93 69 -126
92 67 -130
97 74-124
86 68-130
141 51 -142
93 70-132
96 64 -137
93 74 -128
109 71 -127
''
82 74 -123
101 75 -126
91 75.-122
115 75 -126
90 75 -122
87 74 -122
98 76-126
126 64 -132
136 58 -139
94 62 -130
113 70 -133
92 75 -122
104 75 -123
103 77 -123
105 75 -125
103 77 -121
Calculations are performed before rounding to avoid round-off errors in calculated results.
STL Savannah Page.10 of 14
• Client: · ENSR International
Method Blank -Batch: 680-45723
Lab Sample ID: MB 680-45723/5
Client Matrix: Water
Dilution: 1.0
Date Analyzed: 05/26/2006 0107
Date Prepa_red: 05/26/2006 0107
Analyte
Chloromethane
· Bromomethane
Vinyl chloride
Chloroethane
Methylene Chloride·
Acetone
Carbon disulfide
1, 1-Dichloroethene
1, 1-Dichloroethane
cis-1,2-Dichloroethene
· .rans-1,2-Dichloroethene ·
Chloroform .
1,2-Dichloroethane
Methyl Ethyl Ketone
1, 1, 1-Trichloroethane_
Carbon tetrachloride
Dichlorobromomethane
1, 1,2,2-Tetrachloroethane
_1,2-Dichloropropane
trans-1,3-Dichloropropene
Trichloroethene
Chlorodibromomethane
1, 1,2-Trichloroethane
Benzene
cis-1,3-_Dichloropropene
Bromoform
2-Hexanone
methyl isobutyl ketone
Tetrachloroethene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Xylenes, Total
Surrogate
Toluene-dB
4-Bromofluorobenzene
• Dibromofluoromethane
Analysis Batch: 680-45723
Prep Batch: NIA
Units: ug/L
Result
1.0
1.0
1.0
1.0
5.0
25
2.0
. 1.0
1.0
1.0
1.0
1.0
1.0
10
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
10
1.0
1.0
1.0
1.0
1.0
2.0
% Rec
94
97
96
Qual
u
u
u
u
u
u
u
u
u
u
u.
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
Calculations are performed before rounding to avoid round-off errors in calculated results.
STL Savannah Page 11 of 14
Quality Control Results
Job Number: 680-16671"1
Method: 82608
Preparation: 50308
Instrument ID: GC/MS Volatiles -0
Lab File ID: . oq621.d
Initial WeighWolume: 5 ml
Final WeighWolume: 5 . ml
RL
1.0
1.0
1.0
1.0 ·
5.0
25
2.0
1.0
1.0
1.0
1.0
1.0
1.0
10
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
10
1.0
1.0
1.0
1.0
1.0.
2.0
Acceptance Limits
79-122
77 -120
75 -123
• Client: ENSR International
Laboratory-Control Sample. Batch: 680-45723.
Lab Sample ID: LCS 680-45723/2
Client Matrix: Water
Dilution: 1.0
Date Analyzed: 05/25/2006 2319
Date Prepared: 05/25/2006 2319
Analyte
Chloromethane
Bromomethane
Vinyl chloride
Chloroethane
. Methylene Chloride·
Acetone
Carbon disulfide
1, 1-Dichloroethene
1, 1-Dichloroethane
· cis-1,2-Dichloroethene
· .rans-1,2-Dichloroethene
Chloroform
1,2-Dichloroethane
Methyl Ethyl Ketone
1, 1, 1-Trichloroethane
Carbon tetrachloride
Dichlorobromomethane
1, 1,2,2-Tetrachloroethane
1,2-Dichloropropane
trans-1,3-Dichloropropene
Trichloroethane
Chlorodibromomethane
1, 1,2-Trichloroethane
Benzene
cis-1,3-Dichloropropene
Bromoform
2-Hexanone
methyl isobutyl ketone
T etrachloroethene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Xylenes, Total
•
Analysis Batch: 680-45723
Prep Batch: N/A
Units: ug/L
Spike Amount Result
50.0 -24
50.0 30
50.0 26
50.0 39
50.0 39
100 150
50.0 40
50.0 38
50.0 40
50.0 40
50.0 41
50.0 45
50.0 44
100 140
50.0 46
50.0 47
50.0 50
50.0 62
50.0 45
50.0 56
50.0 46
50.0 63
50.0 51
50.0 43
50.0 53
50.0 58
100 160
100 120
50.0 55
50.0 46
50.0 54
50.0 53
50.0 55
150 160
Quality Control Results
Job Number: 680-16671-1
Method: 8260B
Preparation: 5030B
Instrument 10: GC/MS Volatiles -O
_ Lab File ID: · . oq615.d
Initial Weightivolume: 5 ml
Final Weight/Volume: 5 ml
% Rec. Limit Qual
48 51 -133 •
59 21 -176
52 59-136 •
77 40 -171
78 67 -128
150 .20-183
81 60-130
77 64-132
79 70-127
81 69 -126
82 67 -130
90 74 -124
87 68-130
136 51 • 142
92 70 -132
95 64-137
100 74 -128
125 71 • 127
89 74-123
112 75 -126
93 75-122
125 75-126
102 75 -122
87 74-122
107 76 -126
115 64-132
158 58 -139
119 62 -130
109 70-133
91 75 -122
109 75-123
107 77 -123
110 75 -125
106 77 -121
Calculations are performed before rounding to avoid round-off errors in calculated results,
STl Savannah Page 12 of 14
• Client: ENSR International
Method Blank -Batch: 680-44851
' '
Lab Sample ID: MB 680-44851/1-A
Client Matrix: Water
Dilution: 1.0
Date Analyzed: 05/17/2006 1224
Date Prepared: 05/17/2006 0730
Analyte
Cyanide, Total
Laboratory Control/
Analysis Batch: 680-44924
Prep Batch: 680-44851
Units: mg/L
Result
0.0050
Laboratory Control Duplicate Recovery Report -Batch: 680-44851
LCS Lab Sample ID: LCS 680-44851/2-A
Client Matrix: Water
Dilution: 1.0
a1:_ate Analyzed:
w-'ate Prepared:
05/17/2006 1225
05/17/2006 0730
LCSD Lab Sample ID: LCSD 680-44851/3-A
Client Matrix: Water
Dilution: 1.0
Date Analyzed: 05/17/2006 1225
Date Prepared: 05/17/2006 0730
Analyte
Cyanide, Total
•
Analysis Batch: 680-44924
Prep Batch: 680-44851
Units: mg/L
Analysis Batch: 680-44924
Prep Batch: 680-44851
Units:mg/L
%Rec.
LCS LCSD Limit
95 94 90 • 110
Qual
u
Quality Control Results
Job Number: 680-16671-1
Method: 335.4
Preparation: Distillation
Instrument ID: No Equipment Assigned
Lab File ID: N/A
Initial WeighWolume: 50 mL
Final WeighWolume: 50 mL
RL
0.0050
Method: 335.4
Preparation: Distillation
Instrument ID: No Equipment Assigned
Lab File ID: NIA
Initial WeighWolume: 50 ml
Final WeighWolume: · 50 mL
Instrument ID: No Equipment Assigned
Lab File ID: N/A
Initial WeighWolume: 50 mL
Final WeighWolume: 50 mL
RPO RPO Limit LCS Qual LCSD Qual
1 20
Calculations are performed before rounding to avoid round-off errors in calculated results.
STL Savannah Page 13 of 14
SEVERN
TRENT
ANALYSIS REQUEST AND CHAIN OF CUSTODY RECORD
STL
SAMPLE IDENTIFICATION
PROJECT LOJ:)ITION
!STATE) /JL
COI-ITRACTNO.
MATRIX ·. TYPE
Serial Number 9 0 5 6 6
STL Savannah
5102 LaRoche Avenue
Savannah, GA 31404
C) Alternate LaboratOry Name/location
REQUIRED ANALYSIS
NUMBER OF CONTAINERS SUBMITTED
Website: www.stl-inc.com
Phone: [phone]
Fax: 19121352-0165
Phone:
Fax:
PAGE
STANDARD REPORT
DELIVERY 9iQ
DATE DUE_-,-__ _
EXPEDITED REPORT
DELIVERY 0
!SURCHARGE)
DATE DUE
NUMBER OF COOLERS SUBMITTED
PER SHIPMENT: I
REMARKS
~<t---,--;-----;---------,-------~-----+;--+-H-+--t--+-;---+--l--f----1--t--+--t---------'-ti
i 1----+-----t---------------+-+--+-+-+--+-+---+--+----+-l---t----il---t-----t-+------~-tCL. t -l----+-----+--~----l-+-+--l-+--l----+---f--+---+-----l----+----+----+----+--+------1
L .. i----t-----,-----------------l-l-+-+-+-1--+---+--+--+---1--+---+--+--1---1---------+ L
V· 1-----+----t-------------------+-HH-+-+--+--+--+--+--+--+--+--+--+--+-----------l
RELINQUISHED BY: l~GNATUREl DATE TIME RELINQUISHED BY: l~T\JREJ DATE TIME RELINQUISHED BY: l~GNATUREI DATE TIME
RECEIVED · TIME. RECEIVED BY: ISIGNATUREI DATE TIME
;: t!'
0-680 (12/02)
•
June 2006 Analytical Data
•
•
•
Project Manager: Kathryn Smith
SEVERN
TRENT
ANALYTICAL REPORT
Job Number: 680-18021-1
Job Description: Channel Master
For:
ENSR International
7041 Old Wake Forrest Road
Raleigh, NC 27616
Attention: Mr. Gerald Hornaday
Kathryn Smith
Project Manager I
[e-mail]
07/10/2006
The test results in this report meet all NELAP requirements for parameters for which accreditation is required or available. Any
exceptions to NELAP requirements are noted in this report. Pursuant to NELAP, this report may not be reproduced, except in full,
without the written approval of the laboratory. All questions regarding this test report should be directed to the STL Project Manager
who signed this test report. ·
Severn Trent Laboratories, Inc.
STL Savannah 5102 LaRoche Avenue, Savannah, GA 31404
Tel [phone] Fax [phone] www.stl~nc.com
Page 1 of 12
• Client: ENSR International
I I
Description.
Matrix: Water
Volatile Organic Compounds by GC/MS
Purge-and-Trap
Cyanide, Total (Semi-Automated Colorimetry)
Distillation/Cyanide
LAB REFERENCES:
STL-SAV = STL-Savannah
METHOD REFERENCES:
METHOD SUMMARY
Job Number:· 680-18021~1
Lab Location Method · Preparation Method
STL-SAV
STL-SAV
. STL-SAV
STL-SAV
SW846 8260B
MCAWN 335.4
SW846 5030B
Distillation
MCAWN-"Methods For Chemical Analysis Of Water And Wastes", EPA-600/4-79-020, March 1983 And
. Subsequent Revisions. . .
· • SW846 -"Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November.1986
And Its Updates .
•
STL Savannah·
Page 2 of 12
Client: ENSR International
· Lab Sample ID
•
680-18021-1
680-18021-ZTB
STL Savannah
Client Sample ID
Effluent
Trip Blank
SAMPLE SUMMARY
Client Matrix
Water
Water
Page 3 of 12
DatefTime
Sampled·
06/2712006 1245
06/27/2006 0000
Job Number: 680-18021-1
DatefTlme
Received
06/28/2006 0900
06/28/2006 0900
~lien!: ENSR International
Client Sample ID:
Lab Sample ID:
Client Matrix:
'
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
Effluent
680-18021-1
Water
82608
50308
1.0
82608 Volatile _Organic Compounds by GC/MS
Analysis Batch: 680-48943
06/30/2006 1540
06/30/2006 1540
Analytical Data .
Job Number: 680-18021-1
Date Sampled: 06/27/2006 1245 ·
Date Received: 06/28/2006 0900
Instrument ID:
Lab File ID:
GC/MS Volatiles -

A

a371.d
Initial WeighWolume: 5 mL
5 mL Final WeighWolume:
Analyte Result (ug/L) Qualifier Rl
· Chloromethane
Bromomethane
Vinyl chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1, 1-Dichloroethene
1, 1-Dichloroethane
•
is-1,2-Dichloroethene
ans-1,2-Dichloroethene
Chloroform
· 1,2-Dichloroethane
Methyl Ethyl Ketone
1, 1, 1-Trichloroethane
Carbon tetrachloride
Dichlorobromomethane
1, 1,2,2-Tetrachloroethane
1,2-Dichloropropane
trans-1,3-Dichloropropene
Trichloroethane
Chlorodibromomethane
1, 1,2-Trichloroethane
Benzene
cis-1, 3-Dichloropropene
8romoform
2-Hexanone
methyl isobutyl ketone
Tetrachloroethene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Xylenes, Total
Surrogate
Toluene-dB
4-8romofluorobenzene
• Dibromofluoromethane
STL Savannah
1.0
1.0
1.0
1.0
5.0
25
2.0
1.0
1.0
1.0
1.0
1.0
1.0
10
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
10
1.0
1.0
1.0
1.0
1.0
2.0
%Rec
104
108
102
Page 4 of 12
u 1.0
u 1.0
u 1.0
u 1.0 ..
u 5.0
u 25
u 2.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 10
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 10
u 10
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 2.0
Acceptance Limits
79 -122
77 -120
75 -123
tlnent: ENSR International
Client Sample ID: Trip Blank
. Lab Sample ID:
Client Matrix:
.Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
680-18021-2TB
Water
8260B
5030B
1.0
8260B Volatile Organic Compounds by GC/MS
Analysis Batch: 68048943
06/30/2006 1511
06/30/2006 1511
Analytical Data
Job Number: 680-18021-1
Date Sampled: 06/27/2006 0000
Date Received: 06/28/2006 · 0900
Instrument ID:
Lab File ID:
GC/MS Volatiles -A
a369.d
Initial WeighWolume: 5 mL
5 mL Final WeighWolume:
Analyte Result (ug/L) Qualifier RL
Chloromethane
Bromomethane
· Vinyl chloride
· Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1, 1-Dichloroethene
1, 1-Dichloroethane
· • · cis-1,2-Dichloroethene
-ans-1,2,Dichloroethene
~hloroform
1,2-Dichloroethane
Methyl Ethyl Ketone
1, 1, 1-Trichloroethane ·
Carbon tetrachloride
Dichlorobromomethane
1, 1,2,2-Tetrachloroethane
1,2-Dichloropropane
trans-1,3-Dichloropropene
Trichloroethene
Chlorodibromomethane
1, 1,2-Trichloroethane
Benzene
cis-1,3-Dichloropropene
Bromoform
2-Hexanone
methyl isobutyl ketone
T etrachloroethene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Xylenes, Total
Surrogate
Toluene-dB
4-Bromofluorobenzene
• Dibromofluoromethane
STL Savannah
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
5.0 u 5.0
25 u 25
2.0 u 2.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
10 u 10
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
10 u 10
10 u 10
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
2.0 u 2.0
%Rec Acceptance Limits
103 79. 122
107 77 • 120
104 75 • 123
Page 5 of 12
•• Client: ENSR International
Client Sample ID:
Lab Sample ID:
Client Matrix:
Analyte
Cyanide, Total
•
•
STL Savannah
Effluent
680-18021-1
Water
Result
0.0064
Anly Batch: 680-48850
Prep Batch: 680-48848
General Chemistry
Qual Units
mg/L
Date Analyzed 06/29/2006 1415
Date Prepared: 06/29/2006 0800
Page 6 of 12
Analytical Data .
Job Number: 680-18021-1
Date Sampled: 06/27/20061245
Date Received: 06/2812006 0900
RL Dil.. Method
0.0050 1.0 335.4
• DATA REPORTING QUALIFIERS
Client: ENSR International Job Number: 680-18021-1
' '
Lab Section Qualifier Description
GC/MSVOA
u Indicates the analyte was analyzed for but not detect.ed.
General Chemistry
u Indicates the analyte was analyzed for but not detected.
•
•
STL Savannah
Page 7 of 12
lent: . ENSR International ·
Surrogate Recovery Report
8260B Volatile Organic Compounds by GC/MS
Client Matrix: Water
Lab Sample ID
LCS 680-48943/2
MB 680-48943/3
680-18021-1
680-18021-2TB
Surrogate
Client Sample
Effluent
Trip Blank
(BFB)
(DBFM)
(TOL)
4-Bromofluorobenzene
Dibromofluoromethane
Toluene-dB
•
•
STL Savannah
Quality Control Results.
Job Number: 680-18021-1
(BFB) (DBFM) (TOL)
(%Rec) (%Rec) (%Rec)
108 . 101 98
106 104 104
108 102 104
107 104 103
Acceptance Limits
77 -120
75 -123
79 -122
Page 8 of 12
Client: ENSR International
Method Blank -Batch: 680-48943
Lab Sample ID: MB 680-48943/3
Client Matrix: Water
Dilution: 1.0
Date Analyzed: 06130/2006 1149
Date Prepared: 06/30/2006 1149
Analyte
. Chloromethane
Bromomethane
Vinyl chloride
Chloroethane
Methylene Chloride . ..
Acetone
Carbon disulfide
1; 1-Dichloroethene
1, 1-Dichloroethane
.• cis-1, 2-Dichloroethene
rans-1,2-Dichloroethene ·
Chloroform ·
1,2-Dichloroethane
Methyl Ethyl Ketone
1, 1, 1-Trichloroethane_
Carbon tetrachloride
Dichlorobromomethane
1, 1,2,2-Tetrachloroethane
1,2-Dichloropropane
trans-1,3-Dichloropropene
Trichloroethene
Chlorodibromomethane
1, 1,2-Trichloroethane
Benzene
cis-1, 3-Dichloropropene
Bromoform
2-Hexanone
methyl isobutyl ketone
Tetrachloroethene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Xylenes, Total
Surrogate
Toluene-dB
4-Bromofluorobenzene
• Dibromofluoromethane
Analysis Batch: 680-48943
Prep Batch: NIA
Units: ug/L
Result
1.0
1.0
1.0
1.0
5.0
25
2.0
1.0
1.0
1.0
1.0
1.0
1.0
10
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
10
1.0
1.0
1.0
1.0
1.0
2.0
%Rec
104
106
104
Qual
u
u
u
u u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u ·u
u
u
u
u
u
u
Calculations are performed before rounding to avoid round-off errors in calculated results.
STL Savannah Page 9 of 12
Quality Control Results
Job Number: 680-18021-1
Method: 8260B
Preparation: 5030B
Instrument ID: GCIMS Volatiles. A
Lab File ID: aq715.d
Initial WeighWolume: 5 ml
Final WeighWolume: 5 ml .
RL
1.0
1.0
1.0
1.0
5.0
25
2.0
1.0
1.0
1.0
1.0
1.0
1.0
10
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
10
1.0
1.0
1.0
1.0
1.0
2.0
Acceptance Limits
79 • 122
77 -120
75 • 123
• Client: ENSR International
Laboratory Control Sample -Batch: 680-48943
Lab Sample ID: LCS 680-48943/2
Client Matrix: Water
Dilution: 1.0
Date Analyzed: 06/30/2006 1051
Date Prepared: 06/30/2006 1051
Analyte
Chloromethane
Bromomethane
Vinyl chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1, 1-Dichloroethene
1, 1-Dichloroethane
· cis-1,2-Dichloroethene
• trans-1,2-Dichloroethene
Chloroform
1,2-Dichloroethane
Methyl Ethyl Ketone
1, 1, 1-Trichloroethane
Carbon tetrachloride
Dichlorobromomethane
1, 1,2,2-T etrachloroethane
1,2-Dichloropropane
trans-1,3-Dichloropropene
Trichloroethane
Chlorodibromomethane
1, 1,2-Trichloroethane
Benzene
cis-1,3-Dichloropropene
Bromoform
2-Hexanone
methyl isobutyl ketone
Tetrachloroethene ·
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Xylenes, Total
•
Analysis Batch: 680-48943
Prep Batch: N/A
Units: ug/L
Spike Amount Result
20.0 11.9
20.0 16.1
20.0 · 19.3
20.0 13.1
20.0 21.6
40.0 50.8
20.0 20.0
20.0 19.4
20.0 19.7
20.0 19.5
20.0 19.2
20.0 20.3
20.0 17.7
40.0 45.7
20.0 18.6
20.0 19.1
20.0 19.7
20.0 22.0
20.0 19.1
20.0 20.0
20.0 19.8
20.0 19.0
20.0 18.6
20.0 18: 1
20.0 19.7
20.0 22.1
40.0 50.8
40.0 42.4
20.0 18.1
20.0 19.5
20.0 18.4
20.0 19.9
20.0 21.6
60.0 62.2
Quality Control Results
Job Number: 680-18021-1
Method: 8260B
Preparation: 5030B
Instrument ID: GC/MS Volatiles: A
Lab File ID: . aq711.d
Initial WeighWolume: 5 ml
Final WeighWolume: 5 ml
%Rec. Limit Oual
59 51 -133
80, 21 -176
97 59 -136
66 40-171
108 67 -128
127 ,,20-183
100 60-130
97 64 -132 .
98 70-127
97 69 -126
96 67 -130
102 74 -12:4
89 68 -130
114 51 -142
93 70 -132
96 64 -137
99 74 -128
110 71 -127
95 74 -123
100 75 -126
99 75-.122
95 75 -126
93 75-122
91 74 -122
98 76 -126
111 64 -132
127 58-139
106 62 -130
91 70 -133
98 75 -122
92 75 -123
99 77 -123
108 75-125
104 77 -.121
Calculations are performed before rounding to avoid round-off errors in calculated results.
STL Savannah Page 10 of 12
Client: ENSR International
Method Blank· Batch: 680-48848
' ' '
Lab Sample ID: MB 680-48848/1-A
Client Matrix: Water .
Dilution: 1. 0 ·
Date Analyzed: 06/29/2006 1400
Date Preparnd: 06/29/2006 0800
Analyte
, Cyanide, Total
Laboratory Control/
Analysis Batch: 680-48850
Prep Batch: 680-48848
Units: mg/L
Result
0.0050
Laboratory Control Duplicate Recovery Report• Batch: 680-48848
LCS Lab Sample ID: LCS 680-48848/2-A
Client Matrix:
Dilution:
· .ate Analyzed:
ate Prepared:
. Water
1.0
06/29/2006 1401
06/29/2006 0800
LCSD Lab Sample ID: LCSD 680-48848/3-A
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
Analyte
Cyanide, Total
•
Water
1.0
06/29/2006 1402
06/29/2006 0800
Analysis Batch: 680-48850
Prep Batch: 680-48848
Units: mg/L
Analysis Batch: 680-48850
· Prep Batch: 680-48848
Units: mg/L
%Rec.
LCS LCSD Limit
92 95 90-110
Qual
u
Quality Control Results
Job Number: 680-18021-1
Method: 335.4
Prep a ration: Distillation
Instrument ID: No Equipment Assigned
. Lab File ID: N/A
Initial WeighWolume: 50 mL
Final WeighWolume: 50 mL
RL
0.0050
Method: 335.4
Preparation: Distillation
Instrument ID: No EquipmentAssigned
Lab File ID:. NIA
Initial WeighWolume: 50 mL
Final WeighWolume: · 50 mL
Instrument ID: No Equ.ipment Assigned
Lab File ID: N/A
Initial WeighWolume: 50 ml
Final WeighWolume: 50 mL
RPO RPO Limit LCS Qual LCSD Qual
3 20
Calculations are performed before rounding to avoid round-off errors in calculated results.
STL Savannah Page 11 of 12
SEVERN
TRENT
RELINQUISHED BY: <SIGNATUR£1
ANALYSIS REQUEST.AND CHAIN OF CUSTODY RECORD
STL
PROJECT.LOCATION •: MATRIX.
'u.;11011,u11111c1 ..JUV f J.,
STL Savarlnah· ·:
5102 LaRoche 'Avenue
Savannah,;GA 31404 .. ·
:o· Alte~att~.~r•w1~afe/l.oc~ti,,n · · ·; ,-. : :~·:~;~}f~t:ii~.1~.--· ·; i
Website: www.stl-inc.com
Phone: [phone]
Fax: [phone]
Phone:
Fax:
. (STATE) A) e,_ . · .. TYPE . PAGE • Of
SAMPLE IDENTIFICATION
I
.• \..
DATE Tlt.lE RELINQU/SHED IJY: <SIGNATURE/
· .:RECEIVED BY: <SGNATUREI
STANDARD REPORT
DELIVERY $2t)
DATE.QUE~-~--
EXPEDITED REPORT
DELIVERY 0 (SURGHARGE)
DATE DUE
DATE TIME
DATE TIME
July 2006 Analytical Data
•
•
SEVERN
TRENT
ANALYTICAL REPORT
Job Number: 680-18872-1
Job Description: Channel Master
.For:
ENSR International
7041 Old Wake Forrest Road
Raleigh, NC 27616
Attention: Mr. Gerald Hornaday
•
•
Project Manager: Kathryn Smith
Kathryn Smith
Project Manager I
[e-mail]
08/03/2006
The test results in this report meet all NE LAP requirements for parameters for which accredit.ation is required or available. Any
exceptions to NELAP requirements are noted in this report. Pursuant to NELAP, this report may not be reproduced, except in full,
without the written approval of the laboratory. All questions regarding this test report should be directed to the STL Project Manager
who signed this test report.
Severn Trent Laboratories, Inc.
STL Savannah 5102 LaRoche Avenue, Savannah, GA 31404
Tel [phone] Fax [phone] www.stl-inc.com
Page 1 of 12
• Client: ENSR International
' ' ' . Description
Matrix: Water
Volatile Organic Compounds by GC/MS
Purge-and-Trap
. Cyanide, Total (Semi-Automated Colorimetry)
Distillation/Cyanide
LAB REFERENCES:
STL-SAV = STL-Savannah
METHOD REFERENCES:
METHOD SUMMARY
Job Number' 680-18872-1
Lab Location Method Preparation Method
STL-SA V SW846 8260B
STL-SAV SW846 5030B
STL-SAV MCAWN 335.4
STL-SA V Distillation
MCAWN -"Methods For Chemical Analysis Of Water And Wastes", EPA-600/4-79-020,.March 1983 And
Subsequent Revisions.
· .• SW846-"Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986
And Its Updates .
•
STL Savannah
Page 2 of 12
• Client: ENSR International
•
Lab Sample ID
680-18872~1
680-18872-2TB
STL Savannah
Client Sample ID
07-06 EFFLUENT
TRIP BLANK
SAMPLE SUMMARY
Client Matrix
Water
Water
Page 3 of 12
DatefTime
Sampled
07 /2812006 1300
07/28/2006 0000
Job Number: 680-18872-1
Date/Time
Received
07/31/2006 0933
07/31/2006 0933
-li~nt: ENSR International
Client Sample ID: 07-06 EFFLUENT
Lab Sample ID:
Client Matrix:
Method:
Preparation:
Dilution:
Date Analyzed:
. Date Prepared: .
680-18872-1
Water
8260B
5030B
1.0
8260B Volatile Organic Compounds by GC/MS
Analysis Batch: 680-51361
08/02/2006 1431
08/0212006 1431
Analytical Data
Job Number. 680-18872-.1
Date Sampled: 07/28/2006 ·1300
Date Received: 07/31/2006 · 0933.
Instrument ID:
Lab File ID:
GC/MS Volatiles -A
a120.d
Initial WeighWolume:
Final WeighWolume:
5 ml
5 ml
Analyte Result (ug/L) Qualifier .RL
Chloromethane
Bromomethane
Vinyl chloride
· · . Chloroethane
Methylene Chloride
Acetone
Cart>on disulfide
1, 1-Dichloroethene
. 1, 1-Dichloroethane
· . cis-1,2-Dichloroethene
. . .rans-1,2-Dichloroethene
. Chloroform
1,2-Dichloroethane
Methyl Ethyl Ketone
1, 1, 1-Trichloroethane
Cart>on tetrachloride
Dichlorobromomethane
1, 1,2,2-Tetrachloroethane
· 1,2-Dichloropropane
trans-1,3-Dichloropropene
Trichloroethene
Chlorodibromomethane
1, 1,2-Trichloroelhane
Benzene
cis-1, 3-Dichloropropene
Bromoform
2-Hexanone
methyl isobutyl ketone
T etrachloroethene
Toluene
Chlorobenzene
Ethyl benzene
Styrene
Xylenes, Total
Surrogate
Toluene-dB
4-Bromofluorobenzene
• Dibromofluoromethane
STL Savannah
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
5.0 u 5.0
25 u 25
2.0 u 2.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
10 u 10
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1:0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
10 u 10
10 u. 10
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
2.0 u 2.0
%Rec Acceptance Limits
86 79 -122
95 77 • 120
98 75 -123
Page 4 of 12
-lient ENSR International
Client Sample ID: TRIP BLANK
Lab Sample ID:
Client Matrix:
680-18872-2TB
Water
Analytical Data .
Job Number: 680-18872-1
Date Sampled: 07/28/2006 0000 ·
Date Received: 07/31/2006 0933
8260B Volatile Organic Compounds by GC/MS
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
Analyte
Chloromethane
Bromomethane
Vinyl chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1, 1-Dichloroethene
8260B
5030B
1.0
08/02/2006
08/02/2006
. 1,1-Dichloroethane .
· cis-1,2-Dichloroethene
•
ans-1,2-Dichloroethene
hlorofonm
1,2-Dichloroethane
Methyl Ethyl Ketone
1, 1, 1-Trichloroethane
Carbon tetrachloride
Dichlorobromomethane
1, 1,2,2-Tetrachloroethane
1,2-Dichloropropane
trans-1, 3-Dichloropropene
T richloroethene
Chiorodibromomethane
1, 1,2-Trichlorciethane
Benzene
cis-1,3-Dichloropropene
Bromofonm
2-Hexanone
methyl isobutyl ketone
Tetrachloroethene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Xylenes, Total
Surrogate
Toluene-dB
4-Bromofluorobenzene
• Dibromofluoromethane
STL Savannah
1404
1404
Analysis Batch: 680-51361
Result (ug/L) ·
1.0
1.0
, 1.0
1.0
5.0
25
2.0
1.0
1.0
1.0
1.0
1.0
1.0
10
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
10
1.0
1.0
1.0
1.0
1.0
2.0
%Rec
91
96
101
Page 5 of 12
Instrument ID: . GC/MS Volatiles -A
Lab File ID: a118.d
Initial WeighWolume:
Final WeightiVolume:
5 ml
5 ml
Qualifier RL
u 1.0:
u 1.0
u 1.0
u 1.0
u 5.0
u 25
u 2.0
u 1.0
u to
u 1.0
u 1.0
u 1.0
u 1.0
u 10
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 10
u· 10
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 2.0
Acceptance Limits
79 -122
77 -120
75 -123
.. tllient: ENSR International
Client Sample ID:
'
Lab Sample ID:
Client Matrix:
Analyte
. Cyanide, Total .
•
STL Savannah
07-06 EFFLUENT
680-18872-1
Water
Result
0.0057
Anly Batch: 680-51269
Prep Batch: 680-51264
General Chemistry
Qual Units
mg/L
Date Analyzed 08/01/2006 1230
Date Prepared: 08/01/2006 0730
Page 6 of 12
Analytical Data
Job Number: 680-18872-1
Date Sampled: 07/28/2006 1300
Date Received: 07/31/2006 0933
RL Dil Method
0.0050 1.0 335.4
•
Client: ENSR International
Lab Section Qualifier
GC/MSVOA
u
•
General Chemistry
u
•
•
STL Savannah
DATA REPORTING QUALIFIERS
Job Number: 680-18872-1
Description
Indicates the analyte was analyzed for but not detected.
LCS or LCSD exceeds the control limits
Indicates the analyte was analyzed for but not detected.
Page 7 of 12
. · tent: ENSR International
Surrogate Recovery Report
8260B Volatile Organic Compounds by GC/MS
' ' '
Client Matrix: Water
Lab Sample ID
LCS 680-51361/2
MB 680-51361/13
680-18872-1
680-18872-2TB
Surrogate
Client Sample·
· 07-06 EFFLUENT
TRIP BLANK
. (BFB)
(DBFM)
(TOL)
4-Bromofluorobenzene
Dibromofluoromethane
Toluene-dB
•
STL Savannah
(BFB) (DBFM) . (TOL)
(%Rec) (%Rec) (%Rec)
110 104 94
91 101 91
95 98 86
96 101 91
Acceptance Limits
77 -120
· 75 -123
79 -122
Page 8 of 12
Quality C.ontrol Results
Job Number: 680-18872-1
• Client: ENSR International
Method Blank -Batch: 680-51361
Lab Sample ID: MB 680-51361/13
Client Matrix: Water
Dilution: 1.0
Date Analyzed: 08/02/2006 1306
Date Prepared: 08/02/2006 1306
Analyte
Chloromethane
Bromomethane
Vinyl chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1, 1-Dichloroethene
· 1, 1-Dichloroethane
cis-1,2-Dichloroethene
.rans-1,2-Dichloroethene
Chloroform
1,2-Dichloroethane
Methyl Ethyl Ketone
1, 1, 1-Trichloroethane
Carbon tetrachloride
Dichlorobromomethane
1, 1,2,2-Tetrachlornethane
1,2-Dichloropropane
trans-1,3-0ichloropropene
Trichloroethene
Chlorodibromomethane
1, 1,2-Trichloroethane
Benzene
cis-1,3-Dichloropropene
Bromoform
2-Hexanone
methyl isobutyl ketone
Tetrachloroethene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Xylenes, Total
Surrogate
Toluene-d8
4-Bromofluorobenzene
• Dibromofluoromethane
Analysis Batch: 680-51361
Prep Batch: NIA
Units: ug/L
Result
1.0
1.0.
1.0
.. ' 1.0
5.0
25
2.0
1.0
1.0
1.0
1.0
1.0
1.0
10
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
10
1.0
1.0
1.0
1.0
1.0
2.0
%Rec
91
91
101
Qual
u
u
u
u u u
u u u u
u u
u
u
u u
u
u
u u
u
u u u
u
u
u
u
u u u
u u
u
Calculations are performed before rounding to avoid round-off errors in calculated results.
STL Savannah Page 9 of 12
Quality Control Results
Job Number: 680-18872-1
Method: 82608
Preparation: 50308
Instrument ID: GC/MS Volatiles ~A
Lab File ID: .. aq238.d
Initial WeighWolume: 5 ml
Final WeighWolume: 5 ml
RL
1.0
1.0
1.0
1.0
5:o
25
2.0
1.0
1.0
1.0
1.0
1.0
1.0
10
1.0
1.0
1.0
1.0 ·
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
10
1.0
1.0
1.0
1.0
1.0
2.0
Acceptance Limits
79 • 122
77 • 120
75 • 123
Client: ENSR International
Laboratory Co_ntrol Sample -Batch: 680-51361
Lab Sample ID: LCS 680-51361/2
Client Matrix: Water
Dilution: 1.0
Date Analyzed: 08/02/2006 1141
Date Prepared: 08/02/2006 1141
Analyte
Chloromethane
Bromomethane
Vinyl chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1, 1-Dichloroethene
1, 1-Dichloroethane
: · cis-f,2-Dichloroethene
· .ans-1,2-Dichloroethene
hloroform
1,2-Dichloroethane
Methyl Ethyl Ketone
1, 1, 1-T richloroethane
Carbon tetrachloride
Dichlorobromomethane
1, 1,2,2-Tetrachloroethane
1,2-Dichloropropane
trans-1,3-Dichloropropene
T richloroethene
Chlorodibromomethane
1, 1, 2-Trichloroethane
Benzene
cis-1,3-Dichloropropene
Bromoform
2-Hexanone
methyl isobutyl ketone
T etrachloroethene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Xylenes, Total
•
Analysis Batch: 680-51361
Prep Batch: N/A
Units: ug/L
Spike Amount Result
50.0 37
50.0 73
50.0 44
50.0 47
50.0 47
100 75
50.0 53
50.0 52
50.0 46
50.0 47
50.0 50
50.0 50
50.0 53
100 60
50.0 64
50.0 63
50.0 50
50.0 40
50.0 41
50.0 48
50.0 50
50.0 52
50.0 39
50.0 46 ·
50.0 46
50.0 52
100 67
100 60
50.0 52
50.0 45
50.0 49
50.0 51
50.0 54
150 160
Quality Control Results
Job Number: 680-18872-1
Method: 8260B
Preparation: 5030B
Instrument ID: GC/MS Volatiles -A
. Lab File ID: aq232.d
Initial WeighWolume: 5 ml
. Final WeighWolume: 5 ml
%Rec. Limit Qual
74 51 -133
145 21 -176
87 59 -136
93 40 -171
95 67 -128
75 20 -183
105 60-130
105 64 -132
92 70 -127
93 · 69-126.
101 67 -130
100 74 -124
106 68-130
60 51 • 142
128 70-132
126 64 -137
101 74 -128
BO 71 • 127
82 74 -123
97 75 -126
100 75, 122
103 75 -126
79 75 -122
92 74-122
92 76 -126
105 64-132
67 58 -139
60 62-130
104 70 -133
91 75 -122
98 75-123
103 77 -123
108 75 ° 125
105 77 -121
Calculations are performed before rounding to avoid round-off errors in calculated results.
STL Savannah Page 10 of 12
• Client: ENSR International
Method Blank -Batch: 680-51264
Lab Sample ID: MB 680-51264/1-A
• Client Matrix: Water
Dilution: 1.0
Date Analyzed: 08/01/2006 1213
Date Prepared: 08/01/2006 0730
Analyte
Cyanide, Total
Laboratory Control/
Analysis Batch: 680-51269
Prep Batch: 680-51264
Units: mg/L
Result
0.0050
Qual
.u
Laboratory Control Duplicate Recovery Report -Batch: 680-51264
LCS Lab Sample ID: LCS 680-51264/2-A
Client Matrix: water
Dilution: 1.0
•
Date Analyzed:
Date Prepared:
08/01/2006 1214
08/01/2006 0730
LCSD Lab Sample ID: LCSD 680-51264/3-A
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
Water
1.0
08/01/2006 1215
08/01/2006 0730
Analysis Batch: 680-51269
Prep Batch: 680-51264
Units: mg/L
Analysis Batch: 680-51269
Prep Batch: 680-51264
Units:mg/L
%Rec.
Quality Control Results . .
Job Number: 680-18872-1
Method: 335.4
Preparation:· Distillation
Instrument ID: No Equipment Assigned
Lab File ID: . · N/A
Initial WeighWolume: 50 ml
Final WeighWolume: 50 ml
RL
0.0050
Method: 335.4
Preparation: Distillation
Instrument ID: No Equipment Assigned
Lab File ID: NIA
Initial WeighWolume:
Final WeighWolume:
50 ml
50 ml
Instrument ID: No Equipment Assigned
Lab File ID: N/A
Initial WeighWolume: 50 ml
Final WeighWolume: .50 ml
Analyte LCS LCSD Limit RPD RPD Limit LCS Qual LCSD Qual
Cyanide, Total 98 97 90 -110 20
•
Calculations are performed before rounding to a·void round--off errors ·in calculated results.
STl Savannah Page 11 of 12
ANALYSIS REQUEST AND CHAIN OF CUSTODY RECORD
SEVERN
TRENT STL
Serial Number 9'015 6 8
C) STL Savannah
5102 LaRoche Avenue
Savannah, GA 31404
C) Alternate Laboratory Name;t.ocation
Website: www.stl-inc.com
Phone: [phone]
Fax: [phone] -
Phone:
Fax:
REMARKS
rF:L=-t'-'"--=--=--1r---==:e.:t.L=!,!'._-'====ZLL __ _:_ ___ ~::+..:.i-:+~~--1---1---1--1--1--+--1--+--1-----------1,.
t-~-~-t+"'-"'-'----t-----.,,,,-'-'---~----------f:+++++-+-''-----+--+-+--+---l--1--+--+---t-------------1 ~
N
.t-~~~-1------t-------------'~-------+-+-+-I-Hl--+--+--+-+--+---!--l--+--+---t-------------1 ~ .,
f:"?t-~~-c-11------t--------,---'~---~-----'----¥+-I-I-Hl--l--+--+-+--+---!--l--+--+---t-------------1 l
•
RELINQUISl:l,ED BY: ISIGNATUREI DATE DATE TIME RELINQUISHED BY: !SIGNATURE) DATE TIME
RECEIVED_BY: tS!GNAniRO DATE TIME ,·; ·,
iJ}~t DATE TIME RECEIVED BY;:~~f~TUREI
~-
DATE
0-680 112/02)
•
•
•
ENSR Consulting and Engineering (NC), Inc. ~ @, I
7041 Old Wake Forest Road. Suite 103, Raleigh, North Carolina 276 @, @ @, ~ ~
T 919 872 6600 F 919 872 7996 www.ensr.aecom.com ~ ~ \\N Wlfi.~ 1 1 1\)1)\l
May 10, 2006 ti~~ sc.C1\0~
su?£\\t
Mr. Larry Thomas
City Engineer
City of Oxford
P.O. Box 1307
Oxford, North Carolina 27565
RE: Industrial Users Report for April 2006 ..
JFD Electronics/Channel Master NPL Site, Oxford, North Carolina.
Dear Mr. Thomas:
ENSR AECOM
On behalf of The Unimax Corporation and Avnet, Inc., ENSR Consulting and Engineering (NC), Inc. is
submitting the Quarterly Industrial User Permit report for the months of February, March and April
2006. This report is prepared in accordance with permit requirements for the discharge of treated
groundwater at the above referenced site.
If you have any questions, please contact us at [phone].
Sincerely,
ENSR Consulting and Engineering (NC), Inc.
Project Engineer
Enclosure
William H. Doucette, Jr., Ph.D.
Senior Program Manager
cc: Brian Kempner, The Unimax Corporation (w/o lab attachment)
S. Alan Lazar, Avnet, Inc. (w/o lab attachment)
Steve Earp, Smith Helms Muliss & Moore (w/o lab attachment)
David Mattison, NCDENR Superfund
Ken Lucas, USEPA Superfund
Nanjun Shetty, P.E., ENSR
File
S:\PUBS\PROJECT\C\ChannelMaster\Ouarterly IUReports\2006\May 2006\IUR Letter May 2006.doc
•
•
•
INDUSTRIAL USER REPORTING FORM
LU. PERMIT NO:_--=G=0=01.,__ ___ ~DISCHARGE NO: ___ """0.,,_01.__ ____ _
MONTI-IS: February, March and April YEAR: · 2006
LU. NAME: JFD Electronics/Channel Master CLASS: COUNTY: Granville
OPERA TOR IN RESPONSIBLE CHARGE (ORC): ENSR Consulting & Engineering (NCI, Inc.
LABO RA TORY PERFORMING ANALYSIS: STL-Savannah Laboratories
PERSON(S) COLLECTING SAMPLES: Gerald Hornaday, P.E. (ENSR), Amel Keskar (ENSR)
CHECK BLOCK IF ORC HAS CHANGED 0
SEND REPORT TO: City Engineer
City of Oxford
P.O. Box 1307
Oxford, NC 27565
Facility Status: (Please check one of the following)
All monthly averages and/or other limitations do meet permit monitoring requirements . ~
(Compliant)
All monthly averages and/or other limitations do not meet permit monitoring requirements. 0
(Noncompliant)
If the facility is noncompliant, please comment on corrective actions being taken in respect to
equipment, operation, maintenance, etc. and a time table for improvements to be made.
(Attach additional sheets if necessary)
I certify that this Report is accurate and
complete to the best of my knowledge:
½JJJ..P=u h,,~
Signature of Permittee Representativ
William H. Doucette, Jr., Ph.D.
Date:
•
February 2006 Analytical Data
•
•
•
•
•
ANALYTICAL REPORT
Job Number: 680-13749-1
Job Description: Channel Master
For:
ENSR International
7041 Old Wake Forrest Road
Raleigh, NC 27616
Attention: Mr. Gerald Hornaday
Kathryn Smith
Project Manager I
[e-mail]
03/06/2006
The test results in this report meet all NELAP requirements for parameters for which accreditation is required or available. Any
exceptions to NELAP requirements are noted in this report. Pursuant to NELAP, this report may not be reproduced, except in full,
without the written approval of the laboratory. All questions regarding this test report should be directed to the STL Project Manager
who sianed this test renort .
Severn Trent Laboratories, Inc.
STL Savannah 5102 LaRoche Avenue .. Savannah. GA 31404
Tel [phone] Fax [phone] www.stl-inc.com
Page 1 of 13
•
•
•
Client: ENSR International
Description
Matrix: Water
Volatile Organic Compounds by GC/MS .
Purge-and, Trap
Cyanide, Total (Semi-Automated Colorimetry)
Distillation/Cyanide
LAB REFERENCES:
STL-SAV = STL-Savannah
METHOD REFERENCES:
METHOD SUMMARY
Job Number: 680-13749-1
Lab Location Method Preparation Method
STL-SAV SW846 8260B
STL-SAV SW846 5030B
STL-SAV MCAWW 335.4
STL-SAV Distillation
MCAWW -"Methods For Chemical Analysis Of Water And Wastes", EPA-600/4-79-020, March 1983 And
Subsequ_ent Revisions .
SW846 >rest Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986
And Its Updates .
STL Savannah
Page 2 of 13
•
•
•
Client: ENSR International
Lab Sample ID
680-137 49-1
680-13749-2TB
STL Savannah
Client Sample ID
Effluent
Trip Blank
SAMPLE SUMMARY
Client Matrix
Water
Water
Page 3 of 13
DatefTime
Sampled
02/17/2006 1430
02/17/2006 0000
Job Number: 680-137 49-1
DatefTime
Received
02/20/2006 1025
02/20/2006 1025
•
•
•
Client: ENSR International
Client Sample ID:
Lab Sample ID:
Client Matrix:
Method:
Preparation;
Dilution:
Date Analyzed:
Date Prepared:
Effluent
680-13749-1
Water
82608
50308
1.0
8260B Volatile Organic Compounds by GC/MS
Analysis Batch: 680-37765
03/02/2006 034 7
03/02/2006 034 7
Analytical Data
Job Number: 680-137 49-1
Date Sampled: 02/17/2006 1430
Date Received: 02/20/2006 1025
Instrument ID: GC/MS Volatiles - P
Lab File ID: p3167.d
Initial WeighWolume: 5 ml
Final WeighWolume: 5 ml
. Analyte
Chloromethane
Bromomethane
Vinyl chloride
Chloroethane
Methylene Chloride
Acetone
Result (ug/L) Qualifier RL
Carbon disulfide
1, 1-Dichloroethene
1, 1-Dichloroethane
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Chlorofom,
1,2-Dichloroethane
Methyl Ethyl Ketone
1, 1, 1-Trichloroethane
Carbon tetrachloride
Dichlorobromomethane
1, 1,2,2-Tetrachloroethane
1,2-Dichloropropane
trans-1,3-Dichloropropene
Trichloroethene
Chlorodibromomethane
1, 1,2-Trichloroethane
Benzene
cis-1,3-Dichloropropene
Bromoform
2-Hexanone
methyl isobutyl ketone
Tetrachloroethene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Xylenes, Total
Surrogate
Toluene-d8
4-Bromofluorobenzene
Dibromofluoromethane
STL Savannah
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
5.0 u 5.0
25 u 25
1.0 u· 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u · 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
10 u 10
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u· 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u· 1.0
1.0 u 1.0
10 u 10
10 u 10
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
2.0 u 2.0
%Rec Acceptance Limits
104 79-122
97 77 -120
104 75 -123
Page 4 of 13
•
•
•
Client: ENSR International
Client Sample ID:
Lab Sample ID'
Client Matrix:
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
Trip Blank
680-13749-2TB
Water
8260B
5030B
1.0
8260B Volatile Organic Compounds by GC/MS
Analysis Batch: 680-37765
03/02/2006 0319
03/02/2006 0319
Analytical Data
Job Number: 680-13749-1
Date Sampled: 0211712006 0000
Date Received: 02/2012006 1025
Instrument ID: GC/MS Volatiles - P
Lab File ID: p3165.d
Initial WeighWolume: 5 ml
Final WeighWolume: 5 ml
:"-~~'Y.te Result (ug/L) Qualifier RL -····--·--·
Chloromethane 1.0 u 1.0
Bromomethane 1.0 u 1.0
Vinyl chloride
Chloroethane ·
1.0 u 1.0
1.0 u 1.0
Methylene Chloride
Acetorie
5.0 u 5.0
25 u 25
Carbon disulfide 1.0 u· 1.0
1, 1-Dichloroethene 1.0 u 1.0
1, 1-Dichloroethane 1.0 u 1.0
cis-1,2-Dichloroethene 1.0 u · 1.0
trans-1,2-Dichloroethene 1.0 u 1.0
Chlorofonn 1.0 u 1.0
1,2-Dichloroethane 1.0 u 1.0
Methyl Ethyl Ketone
1, 1, 1-Trichloroethane
10 u 10
1.0 u 1.0
Carbon tetrachloride 1.0 u 1.0
Dichlorobromomethane 1.0 u 1.0
1, 1,2,2-Tetrachloroethane 1.0 u 1.0
1,2-Dichloropropane
trans-1,3-Dichloropropene
Trichloroethane
1.0 u 1.0
1.0 u· 1.0
1.0 u 1.0
Chlorodibromomethane 1.0 u 1.0
1, 1,2-Trichloroethane 1.0 u 1.0
Benzene 1.0 u 1.0
cis-1,3-Dichloropropene 1.0 u· 1.0
Bromoform 1.0 u 1.0
2-Hexanone 10 u 10
methyl isobutyl ketone 10 u 10
Tetrachloroethene 1.0 u 1.0
Toluene 1.0 u 1.0
Chlorobenzene 1.0 u 1.0
Ethylbenzene
Styrene
Xylenes, Total
1.0 u 1.0
8.2 1.0
2.0 u 2.0
~~rrogate
· Toluene-dB
%Rec Acceptance Limits ...... . --··
107 79 -122
4-Bromofluorobenzene 95 77 -120
Dibromofluoromethane 109 75 -123
STL Savannah Page 5 of 13
•
•
•
Client: ENSR International
Client Sample ID:
Lab Sample ID:
Client Matrix:
Analyte
Cyanide, Total
STL Savannah
Effluent
680-13749-1
Water
Result
0.0056
Anly Batch: 680-36983
Prep Batch: 680-36981
General Chemistry
Qual Units
mgll
Date Analyzed 02/2112006 1603
Date Prepared: 02/2112006 0800
Page 6 of 13
Analytical Data
Job Number: 680-137 49-1
Date Sampled:
Date Received:
RL
0.0050
02/17/2006 1430
02/20/2006 1025
Oil Method
1.0 335.4
•
Client: ENSR International
Lab Section Qualifier
GC/MS VOA
u
•
General Chemistry
u
•
•
STL Savannah
DATA REPORTING QUALIFIERS
Job Number: 680-13749-1
Description
Analyte was not detected at or above the reporting limit.
LCS, LCSD, MS, MSD, MD, or Surrogate exceeds the control
limits
Analyte was not detected at or above the reporting limit.
Page 7 of 13
•
•
Client: ENSR International
Surrogate Recovery Report
. 8260B Volatile Organic Compounds by GC/MS
Client Matrix: Water
Lab Sample ID Client Sample
LCS 680-37765/21 LCS
LCSD 680-37765/24 LCSD
MB 680-37765/23 MB
680-13749-1 Effluent
680-137 49-2TB Trip Blank
Surrogate
(BFB)
(DBFM)
(TOL)
4-Bromofluorobenzene
Dibromofluoromethane
Toluene-dB
STL Savannah
(BFB)
(%Rec)
100
101
99
97
95
(DBFM) (TOL)
(%Rec) . (%Rec)
105 102
101 103
108 109
104 104
109 107
Acceptance Limits
77 -120
75 · 123
79 -122
Page 8 of 13
Quality Control Results
Job Number: 680-13749-1
• Client:. ENSR International
Method Blank -Batch: 680-37765
Lab Sample ID: MB 680-37765/23 Analysis Batch: 680-37765
Client Matrix: Water Prep Batch: NIA
Dilution: 1.0 Units: ug/L
Date Analyzed: 03/02/2006 0154
Date Prepared: 03/02/2006 0154
Analyte Result Qual
Chloromethane 1.0 u
Bromomethane 1.0 u
Vinyl chloride 1.0 u
Chloroethane 1.0 u
Methylene Chloride 5.0 u
Acetone 25 u
Carbon disulfide 1.0 u
. 1, 1-Dichloroethene 1.0 u
1, 1-Dichloroethane 1.0 u
cis-1,2-Dichloroethene 1.0 u • trans-1,2-Dichloroethene 1.0 u
Chloroform 1.0 u
1,2-Dichloroethane 1.0 u
Methyl Ethyl Ketone 10 u
1, 1, 1-Trichloroethane 1.0 u
Carbon tetrachloride 1.0 u
Dichlorobromomethane 1.0 u
1, 1 ,2,2-Tetrachloroethane 1.0 u
1,2-Dichloropropane 1.0 u
trans-1,3-Dichloropropene 1.0 u
Trichloroethene 1.0 u
Chlorodibromomethane 1.0 u
1, 1,2-Trichloroethane 1 .0 u
Benzene 1.0 u
cis-1,3-Dichloropropene 1.0 u
Bromoform 1.0 u
2-Hexanone 10 u
methyl isobutyl ketone 10 u
T etrachloroethene 1.0 u
Toluene 1.0 u
Chlorobenzene 1.0 u
Ethylbenzene 1 .0 u
Styrene 1.0 u
Xylenes, Total 2.0 u
Surrogate %Rec
Toluene-dB 109
4-Bromofluorobenzene 99 • Dibromofluoromethane 108
Calculations are performed before rounding to avoid round-off errors·in calculated results.
STL Savannah Page 9 of 13
Quality Control Results
Job Number: 680-13749-1
Method: 8260B
Preparation: 5030B
Instrument ID: GC/MS Volatiles - P
Lab File ID: pq319.d
Initial WeighWolume: 5 ml
Final WeighWolume: 5 ml
RL
1.0
1.0
1.0
1.0
5.0
25
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
10
1.0
1.0
1.0
1.0
1.0
2.0
Acceptance Limits
79 -122
77 -120
75 -123
•
•
•
Client: ENSR International
_ l,.aboratory _Control/
Laboratory Control Duplicate Recovery Report -Batch: 680-37765
LCS Lab Sample ID: LCS 680-37765/21
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
Water
1.0
03/01/2006 2340
03/01/2006 2340
LCSD Lab Sample ID: LCSD 680-37765/24
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
Analyte
Chloromethane
Bromomethane
Vinyl chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1, 1-Dichloroethene
Water
1.0
03/02/2006 0008
03/02/2006 0008
1, 1-Dichloroethane
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Chloroform
1,2-Dichloroethane
Methyl Ethyl Ketone
1, 1, 1-Trichloroethane
Carbon tetrachloride
Dichlorobromomethane
1, 1,2,2-Tetrachloroethane
1,2-Dichloropropane
trans-1,3-0ichloro·propene
Trichloroethene
Chlorodibromomethane
1, 1,2-Trichloroethane
Benzene
cis-1,3-Dichloropropene
Bromoform
2-Hexanone
methyl isobutyl ketone
Tetrachloroethene
Toluene
Chlorobenzene
Ethylbenzene
Analysis Batch: 680-37765
Prep Batch: N/A
Units: ug/L
Analysis Batch: . 680-37765
Prep Batch: NIA
Units: ug/L
%Rec.
LCS LCSD
66
84
78
94
96
127
52
102
98
100
93
100
96
122
96
100
99
93
103
55
102
102
96
96
58
99
110
101
98
93
93
95
62
74
72
82
93
111
52
101
99
99
94
98
91
110
90
93
96
92
100
53
99
101
92
93
55
99
106
99
103
94
99
100
Limit
51 -133
21 -176
59 -136
40 -171
67 -128
20 -183
60 -130
64 -132
70 -127
69 -126
67 -130
74 -124
68 -130
51 -142
70 -132
64 -137
74 -128
71 -127
74 -123
75 -126
75 -122
75 -126
75 -122
74 -122
76 -126
64 -132
58 -139
62 -130
70 -133
75 -122
75 -123
77 -123
Quality Control Results
Job Number: 680-13749-1
Method: 8260B
Preparation: 5030B
Instrument ID: GC/MS Volatiles -

P

Lab File ID: pq313.d
Initial WeighWolume: 5 ml
Final WeighWolume: · 5 ml
Instrument ID: GC/MS Volatiles -

P

Lab File ID: pq315.d
Initial WeighWolume: 5 · ml
Final WeighWolume: 5 ml
RPO
6·
13
RPO Limtt LCS Qual LCSD Qual
8
14
3
13
1
1
1
2
5
11
6
6
3
1
3
4
2
1
4
3
5
0
3
2
6
6
5
50
50
50
50
30
50
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
•
Calculations are performed before rounding to avoid round-off errors in calculated results.
STL Savannah Page10of13
•
•
•
Client: ENSR International
Laboratory Control/ _
Laboratory Control Duplicate Recovery Report -Batch: 680-37765
LCS Lab Sample ID: LCS 680-37765/21
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
. Water
1.0
03/01/2006 2340
03/01/2006 2340
LCSD Lab Sample ID: LCSD 680-37765/24
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
Analyte
Styrene
Xylenes, Total
Water
1.0
03/02/2006 0008
03/02/2006 0008
Analysis Batch: 680-37765
Prep Batch: N/A
Units: ug/L
Analysis Batch: 680-37765
Prep Batch: N/A
Units: ug/L
%Rec.
LCS LCSD Limit
102 104 75 -125
96 99 77 -121
RPD
2
3
Calculations are performed before rounding to avoid round-off errors in calculated results.
STL Savannah Page 11 of 13
Quality Control Results
Job Number: 680-13749-1
Method: 8260B
Preparation: 5030B
Instrument ID: GC/MS Volatiles -P
Lab File ID: pq313.d
Initial WeighWolume: 5 ml
Final WeighWolume: 5 ml
Instrument ID: GC/MS Volatiles -P
Lab File ID: pq315.d
Initial WeighWolume: 5 ml
Final WeighWolume: 5 ml
RPD Limit LCS Qual
30
30
LCSD Qual
•
•
•
Client: ENSR International
Method Blank -Batch: 680-36981
Lab Sample ID: MB 680-36981/1-A
Client Matrix: Water
Dilution: 1.0
Date Analyzed: 02/21/2006 1549
Date Prepared: 02/21/2006 0800
Analyte
Cyanide, Total
Laboratory Control/
Analysis Batch: 680-36983
Prep Batch: 680-36981
Units: mg/L
Result
0.0050
Laboratory·Control Duplicate Recovery Report -Batch: 680-36981
LCS Lab Sample ID: LCS 680-36981/2-A
Client Matrix: Water
Dilution: 1.0
Date Analyzed: 02/21/2006 1550
• Date Prepared: 02/21/2006 0800
LCSD Lab Sample ID: LCSD 680-36981/3-A
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
Analyte
Cyanide, Total
Water
1.0
02/21/2006 1550
02/21/2006 0800
Analysis Batch: 680-36983
Prep Batch: 680-36981
Units: mg/L
Analysis Batch: 680-36983
Prep.Balch: 680-36981
Units:mg/L
%Rec
LCS LCSD Limit
97 98 90 -110
Qual
u
RPD
Calculations are performed before rounding to avoid round-off errors in calculated results.
STL Savannah Page 12 of 13
Quality Control Results
Job Number: 680-13749-1
Method: 335.4
Preparation: Distillation.
Instrument ID: No Equipment Assigned
Lab File ID: NIA
Initial WeighWolume: 50 ml
Final WeighWolume: 50 ml
RL
0.0050
Method: 335.4
Preparation: Distillation
Instrument ID: No Equipment As.signed
Lab File ID: N/A
Initial WeighWolume: 50 ml
Final WeighWolume: 50 ml
Instrument ID: No Equipment Assigned
Lab File ID: N/A
Initial WeighWolume: 50 ml
Final WeighWolume: 50 ml
RPD Limit LCS Qual LCSD Qual
20
ANALYSIS REQUEST AND CHAIN OF CUSTODY RECORD
SEVERN
TRENT
RELINQUISHED BY: !SIGNATURE)
STL
DATE TIME
MATRIX
TYPE
Serial Number' 6 2 7 9 0
M STL Savannah
"f'<-5102 LaRoche Avenue
Savannah, GA 31404
0 Alternate Laboratory Name/location
REQUIRED ANALYSIS
NUMBER OF CONTAINERS SUBMITTED
Website: www.stl-inc.com
Phone: [phone]
Fax: [phone]
Phone:
Fax:
PAGE
STANDARD REPORT
OF
DELIVERY 9Q
DATE DUE ____ _
EXPEDITED REPORT
DELIVERY 0 (SURCHARGE!
DATE DUE
NUMBER OF COOLERS SUBMITTED
PER SHIPMENT:
REMARKS
IU
TIME
/8f00
RELINQUISHED BY: (SIGNATURE) DATE TIME
TIME RECEIVED BY: (SIGNATURE) DATE TIME
l824Q-680 (12/02)
• TABLE 1. GROUNDWATER REMEDIATION SYSTEM DISCHARGE MONITORING RE~RT, CITY OF OXFORD, NORTH CAROLINA
•
•
I.U. PERMIT NO;
DISCHARGE NO:
MONTHS:
YEAR:
I.LI.NAME:
-~COUNTY: -
OPERATOR IN RESPONSIBLE CHARGE (ORC):
LABORATORY PERFORMING ANALYSIS:
G001
001
February, Marcil, and April
2006
JFD Electronics/ChaMel MaS1er NPL Site
Granville
ENSR Consulting & Engineering (NC), Inc.
STL Savannah Laboratories
PERSON(S) COLLECTING SAMPLES: Gerald Hornaday, P .E. (ENSR); Amol Keskar (ENSR)
PARAMETER
Dally Average Flow (MGD)
Tetrachloroethylene
1, 1-0lch\oroethane
cls-1,2 Dlchloroethene
Chlorobenzene
Toluene
1, 1-0lchloroethylene
trans-1,2 Dlchloroethylene
Trichloroathene
Vinyl Chloride
Cyanide (total)
pH
Temperature
Monitoring requirement only.
MGD MIiiion Gallons per day.
µgfl Micrograms per liter.
mg/L Milligrams per liter.
SU Standard Units.
°C Degrees Centigrade.
PERMIT LIMITS
Dally Maximum
0.040
0.05
5.oto 10.0
40
< Compound was not detected above the quantitation limit.
G:'EnVUFOCI-W-lN\NC0202.170\City of ChdonNURTable May 2006\Table 1\Sl9J2006
UNJTS
MGD
"glL
"g/L
"g/L
"glL
"g/L
"g/L .
"g/L
µgfl
"g/L
mg/L
SU
"C
SAMPLE
TYPE
Meter
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
LAB
METHOD
Field
8260
8260
8260
8260
8260
8260
8260
8260
8260
335.2
Field
Field
MONTHLY MEASUREMENT
DATES
02/17/06 03/23/08 04/0.UOS
0.022 0.021 0.022
<1.0 <1.0 <1.0
<1.0 <1.0 <1.0
<1.0 <1.0 <1.0
<1.0 <1.0 <1.0
<1.0 <1.0 <1.0
<1.0 <1.0 <1.0
<1.0 <1,0 <1.0
<1.0 <1.0 <1.0
<1.0 <1.0 <1.0
0.0056 0.0055 0.0058
8.34 8.1 8.47
20.7 19.4 15.8
•
March 2006 Analytical Data
•
•
•
•
•
Project Manage.r: Kathryn Smith
SEVERN
'
· TRENT
ANALYTICAL REPORT
Job Number: 680-14947-1
Job Description: Channel Master
For:
ENSR International
7041 Old Wake Forrest Road
Raleigh, NC 27616
Attention: Mr. Gerald Hornaday
Kathryn Smith
Project Manager I
[e-mail]
04/05/2006
STL
The test results in this report meet all NELAP requirements for parameters for which accreditation is required or available. Any
exceptions to NE LAP requirements are noted in this report. Pursuant to NE LAP, this report may not be reproduced, except in full,
without the written approval of the laboratory. All questions regarding this test report should be directed to the STL Project Manager
who signed this test report .
Severn Trent Laboratories, Inc.
STL Savannah 5102 LaRoche Avenue, Savannah, GA 31404
Tel [phone] Fax [phone] www.sll-inc.com
Page 1 of 16
•
•
•
Client: ENSR International
Description
Matrix: Water
Volatile Organic Compounds by GC/MS
Purge-and-Trap
Cyanide, Total (Semi-Automated Colorimetry)
Distillation/Cyanide
LAB REFERENCES:
STL-SAV = STL-Savannah
METHOD REFERENCES:
METHOD SUMMARY
Lab Location Method
STL-SAV
STL-SAV
STL-SAV
STL-SAV
SW846 8260B
MCAWW 335.4
Job Number: 680-14947-1
Preparation Method
SW846 5030B
Distillation
MCAWW -"Methods For Chemical Analysis Of Water And Wastes", EPA-600/4-79-020, March 1983 And
Subsequent Revisions .
SW846 -"Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986
And Its Updates .
STL Savannah
Page 2 of 16
•
•
•
SAMPLE SUMMARY
Client: ENSR International
Lab Sample ID
680-14947-1
680-14947-2TB
STL Savannah
Client Sample ID Client Matrix
Effluent Discharge Sample Water
TRIP BLANK Water
Page 3 of 16
Date/Time
Sampled
03/23/2006 1600
03/23/2006 0000
Job Number: 680-14947-1
Date/Time
Received
03/2412006 0930
03/24/2006 0930
•
•
•
Client: ENSR International
Client Sample ID:
Lab Sample ID:
, Client Matrix:
Effluent Discharge Sample
680-14947-1
Water
Analytical Data
Job Number: 680-14947-1
Date Sampled:
Date Received:
03/23/2006 1600
03/24/2006 0930
8260B Volatile Organic Compounds by GC/MS
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
Analyte
Chloromethane
Bromomethane
Vinyl _chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1, 1-Dichloroethene
8260B
5030B
1.0
04/03/2006
04/03/2006
1 ;1-Dichloroethane
cis-1,2-Dichloroethene
tra ns-1, 2-Dichloroethene
Chloroform
1,2-0ichloroethane
Methyl Ethyl Ketone
1, 1,1-Trichloroethane
Carbon tetrachloride
Oichlorobromomethane
1, 1,2,2-Tetrachloroethane
1,2-Dichloropropane
trans-1,3-Dichloropropene
Trichloroethene
Chlorodibromomethane .
1, 1,2-Trichloroethane
Benzene
cis-1, 3-Dichloropropene
Bromoform
2-Hexanone
methyl isobutyl ketone
Tetrachloroethene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Xylenes, Total
-~~r~?9.~-~~ ...
Toluene-dB
4-Bromofluorobenzene
Dibromofluoromethane
STL Savannah
Analysis Batch: 680-40698
1217
1217
Result(ug/L)
1.0
1.0
1.0
1.0
5.0
25
2.0
1.0
1.0
1.0
1.0
1.0
1.0
10
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
10
1.0
1.0
1.0
1.0
1.0
2.0
%Rec
95
101
91
Page 4 of 16
Instrument ID: GC/MS Volatiles -

P

Lab File ID: p0657.d
Initial WeighWolume: 5 · ml
Final WeighWolume: 5 ml
Qualifier RL
u. 1.0
u 1.0
u· 1.0
u 1.0
u 5.0
u 25
u 2.0
u -1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 10
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 10
u 10
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 2.0
Acceptance Limits
79 -122
77 -120
75 -123
•
•
•
Client: ENSR International
Client Sample ID:
Lab Sample ID:
Client Matrix:
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
TRIP BLANK
680-14947-2TB
Water
82608
50308
1.0
8260B Volatile Organic Compounds by GC/MS
Analysis Batch: 680-40650
04/03/2006 0259
04/03/2006 0259
Analytical Data
Job Number: 680-14947-1
Date Sampled: 03/23/2006 0000
Date Received: 03/24/2006 0930
Instrument ID: GC/MS Volatiles -

P

Lab File ID: p0613.d
Initial WeighWolume: 5 ml
Final WeighWolume: 5 ml
Analyte Result (ug/L) Qualifier RL
Chioromethane 1.0 u· 1.0
Bromomethane 1.0 u 1.0
Vinyl chloride 1.0 u· 1.0
Chloroethane 1.0 u 1.0
Methylene Chloride 5.0 u 5.0
Acetone 25 u 25
Carbon_ disulfide 2.0 u 2.0
1, 1-Dichloroethene 1.0 u 1.0
1, 1-Dichloroethane 1.0 u 1.0
cis-1,2-Dichloroethene 1.0 u 1.0
trans-1,2-Dichloroethene 1.0 u 1.0
Chloroform 1.0 u 1.0
1,2-Dichloroethane 1.0 u 1.0
Methyl Ethyl Ketone 10 u 10
1, 1, 1-Trichloroethane 1.0 u 1.0
Carbon tetrachloride 1.0 u 1.0
Dichlorobromomethane 1.0 u 1.0
1, 1,2,2-Tetrachloroethane 1.0 u 1.0
1,2-Dichloropropane 1.0 u 1.0
trans-1,3-Dichloropropene 1.0 u 1.0
Trich\oroethene 1.0 u 1.0
Chlorodibromomethane 1.0 u 1.0
1, 1,2-Trichloroethane 1.0 u 1.0
Benzene 1.0 u 1.0
cis-1,3-Dichloropropene 1.0 u 1.0
Bromofonn 1.0 u 1.0
2-Hexanone 10 u 10
methyl isobutyl ketone 10 u 10
Tetrachloroethene 1.0 u 1.0
Toluene 1.0 u 1.0
Chiaro benzene 1.0 u 1.0
Ethylbenzene 1.0 u 1.0
Styrene 1.0 u 1.0
Xylenes, Total 2.0 u 2.0
~.~rr~~.ate %Rec Acceptance Limits -· .. -
Toluene-dB 93 79 • 122
4-Bromofluorobenzene 102 77 -120
Dibromofluoromethane 89 75 • 123
STL Savannah Page 5 of 16
•
•
•
Client ENSR International
General Chemistry
'Client Sample ID: .
Lab Sample ID:
Effluent Discharge Sample
Client Matrix:
Analyte
Cyanide, Total
STL Savannah
680-14947-1
Water
Result
0.0055
Anly Batch: 680-40046
Prep Batch: 680-40044
Qual Units
mg/L
Date Analyzed 03/2712006 1329
Date Prepared: 03/27/2006 0700
Page 6 of 16
Analytical Data
Job Number: 680-1494 7 -1
Date Sampled:
Date Received:
RL
0.0050
03/23/2006 1600
03/24/2006 0930
Oil Method
1.0 335.4
•
Client: ENSR International
Lab Section Qualifier
GC/MSVOA
u
•
General Chemistry
u
•
•
STL Savannah
DATA REPORTING QUALIFIERS
Job Number: 680-14947-1
Description
Analyte was not detected at or above the reporting limit.
LCS, LCSD, MS, MSD, MD, or Surrogate exceeds the control
limits
Ana.lyte was not detected at or above the reporting limit.
Page 7 of 16
• Client: ENSR International
Surrogate Recovery Report
8260B Volatile Organic Compounds by GC/MS
Client Matrix: Water
Lab Sam~le ID Client Sam~le
LCS 680-40650/2 LCS
LCS 680-40698/3 LCS
LCSD 680-40650/3 LCSD
MB 680-40650/6 MB
MB 680-40698/6 MB
680-14947-1 Effluent Discharge
680-14947-2TB TRIP BLANK
Surrogate-• (BFB) 4-Bromofluorobenzene
(DBFM) Dibromofluoromethane
(TOL) Toluene-dB
•
STL Savannah
(BFB) (DBFM) (TOL)
(%Rec) (%Rec) (%Rec)
101 95 92
105 92 96
109 93 98
97 93 95
106 89 94
101 91 95
102 89 93
Acceptance Limits
77 -120
75 -123
79 -122
Page 8 of 16
Quality Control Results
Job Number: 680-14947-1
•
•
•
Client: ENSR International
Method Blank -Batch: 680-40650
Lab Sample ID: MB 680-40650/6
Client Matrix: Water
Dilution: 1.0
Date Analyzed: 04/02/2006 2313
Date Prepared: 04/02/2006 ·2313
Analyte
Chloromethane
Bromomethane
Vinyl chloride
Chloroethane
Methylene Chloride
Acetone-
Carbon disulfide
1, 1-Dichloroethene
1, 1-Dichloroethane
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Chloroform
1,2-Dichloroethane
Methyl Ethyl Ketone
1, 1, 1-Trichloroethane
Carbon tetrachloride
Dichlorobromomethane
1, 1,2,2-Tetrachloroethane
1,2-Dichloropropane
trans-1,3-Dichloropropene
Trichloroethane
Chlorodibromomethane
1, 1,2-Trichloroethane
Benzene
cis-1,3-Dichloropropene
Bromoform
2-Hexanone
methyl isobutyl ketone
Tetrachloroethene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Xylenes, Total
~~rrogate_
Toluene-dB
4-Bromofluorobenzene
Dibromofluoromethane
Analysis Batch: 680-40650
Prep Batch: N/A
Units: ug/L
Result
1.0
1.0
1.0
1.0
5.0
25
2.0
1.0
1.0
1.0
1.0
1.0
1.0
10
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
10
1.0
1.0
1.0
1.0
1.0
2.0
%Rec
95
97
93
Qual
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
Calculations are performed before rounding to avoid round-off errors in calculated results.
STL Savannah Page 9 of 16
Quality Control Results
Job Number: 680-14947-1
Method: 8260B
Preparation: 5030B
Instrument ID: GC/MS Volatiles -

P

Lab File ID: pq279.d
Initial WeighWolume: 5 ml
Final WeighWolume: 5 ml
RL
1.0
1.0
1.0
1.0
5.0
25
2.0
1.0
1.0
1.0
1.0
1.0
1.0
10
1.0
1,0
1.0
1,0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
10
1.0
1.0
1.0
1.0
1.0
2.0
Acceptance Limits
79-122
77 -120
75 -123
•
•
Client: ENSR International
Laboratory Control/
Laboratory Control Duplicate Recovery Report -Batch: 680-40650
LCS Lab Sample ID: LCS 680-40650/2 Analysis Batch: 680-40650
Client Matrix: Water Prep Batch: N/A
Dilution: 1.0 Units: ug/L
Date Analyzed: 04/02/2006 2112
Date Prepared: 04/0212006 2112
LCSD Lab Sample ID: LCSD 680-40650/3 Analysis Batch: 680-40650
Client Matrix: Water Prep Batch: N/A
Dilution: 1.0 Units: ug/L
Date Analyzed: 04/02/2006 2140
Date Prepared: 04/02/2006 2140
% Rec .
Analyte LCS . LCSD Limit
Chloromethane 46 44 51 -133
Bromomethane 62 66 21 -176
Vinyl chloride 56 53 59-136
Chloroethane 65 59 40 • 171
Methylene Chloride 79 79 67 -128
Acetone 90 87 20 -183
Carbon disulfide 74 72 60 -130
1, 1-Dichloro~thene 71 77 64-132
1, 1-0ichloroethane 87 85 70 -127
cis-1,2-Dichloroethene 86 82 69 -126
trans-1,2-Dichloroethene 81 82 67 -130
Chloroform 93 91 74 -124
1,2-Dichloroethane 99 103 68 -130
Methyl Ethyl Ketone 84 86 51 • 142
1, 1, 1-Trichloroethane 102 102 70 • 132
Carbon tetrachloride 110 108 64 • 137
Dichlorobromomethane 99 101 74 -128
1, 1,2,2-Tetrachloroethane 88 95 71 -127
1,2-Dichloropropane 94 99 74-123
trans-1,3-0ichloropropene 104 108 75 • 126
Trichloroethene 96 101 75 • 122
Chlorodibromomethane 97 99 75 -126
1, 1,2-T richloroethane 85 89 75 -122
Benzene 90 94 74 -122
cis-1,3-Dichloropropene 106 110 76 -126
Bromofonn 103 106 64 -132
2-Hexanone 102 104 58 -139
methyl isobutyl ketone 88 93 62 -130
Tetrachloroethene 101 100 70-133
Toluene 89 94 75 • 122
Chlorobenzene 96 98 75 -123
Ethylbenzene 97 98 77 • 123
Quality Control Results
Job Number: 680-14947-1
Method: 8260B
Preparation: 5030B
Instrument ID: GC/MS Volatiles -

P

Lab File ID: pq271.d
Initial WeighWolume: 5 ml
Final WeighWolume: 5 ml
Instrument ID: GC/MS Volatiles· P
Lab File ID: pq273.d
Initial WeighWolume: 5 ml
Final WeighWolume: 5 ml
RPD RPD Limit LCS Qual LCSD Qual
3 50
7 50
5 50
10 50
0 30
4 so
3 30
7 30
2 30
4 30
2 30
2 30
4. 30
3 30
0 30
1 30
3 30
7 30
5 30
4 30
6 30
2 30
4 30
4 30
4 30
3 30
2 30
5 30
1 30
6 30
3 30
2 30
Calculations are performed before rounding to avoid round-off errors in calculated·results.
STL Savannah Page 10 of 16
•
•
•
Client: ENSR International
Laboratory Con_trol/
Laboratory Control Duplicate Recovery Report -Batch: 680-40650
LCS Lab Sample ID: LCS 680-40650/2
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
Water
1.0
04/02/2006 2112
04/02/2006 2112
LCSD Lab Sample ID: LCS□. 680-40650/3
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
Analyte
Styrene
Xylenes, Total
Water
1.0
04/02/2006 2140
04/02/2006 2140
Analysis Batch: 680-40650
Prep Batch: N/A
Units: ug/L
Analysis Batch: 680-40650
Prep Batch: N/A
Units:ug/L
%Rec.
LCS LCSD Limit
104 104 75 -125
100 102 77 -121
Quality Control Results
Job Number: 680-14947-1
Method: 8260B
·Preparation: 5030B
Instrument ID: GC/MS Volatiles - P
Lab File ID: pq271.d
Initial WeighWolume: 5 ml
Final WeighWolume: 5 ml
Instrument ID: GC/MS Volatiles - P
Lab File ID: pq273.d
Initial WeighWolume: 5 ml
Final WeighWolume: 5 ml
RPO RPO Limit LCS Qua! LCSD Qua!
1 30
2 30
Calculations ~re performed before rounding to avoid round-off errors in calculated results.
STL Savannah Page 11 of 16
• Client: ENSR International
Method Blank -Batch: 680-40698
Lab Sample ID: MB 680-40698/6 Analysis Batch: 680-40698
Client Matrix: Water Prep Batch: NIA
Dilution: 1.0 Units: ug/L
Date Analyzed: 04/03/2006 1149
Date Prepared: 04/03/2006 1149
Analyte Result Oual
Chloromethane 1.0 u
Bromomethane 1.0 u
Vinyfchloride 1.0 u
Chloroethane 1.0 u
Methylene Chloride 5.0 u
Acetone 25 u
Carbon disulfide 2.0 u
1, 1-Dichloroethene 1.0 u
1, 1-Dichloroethane 1.0 u • cis-1,2-Dichloroethene 1.0 u
trans-1,2-Dichloroethene 1.0 u
Chloroform 1.0 u
1,2-0ichloroethane 1.0 u
Methyl Ethyl Ketone 10 u
1, 1, 1-Trichloroethane 1.0 u
Carbon tetrachloride 1.0 u
Dichlorobromomethane 1.0 u
1, 1,2,2-Tetrachloroethane 1.0_ u
1,2-Dichloropropane 1.0 u
trans-1,3-0ichloropropene 1.0 u
Trichloroethene 1.0 u
Chlorodibromomethane 1.0 u
1, 1,2-Trichloroethane 1.0 u
· Benzene 1.0 u
cis-1,3-Dichloropropene 1.0 u
Bromoform 1.0 u
2-Hexanone 10 u
methyl isobutyl ketone 10 u
Tetrachloroethene 1.0 u
Toluene 1.0 u
Chlorobenzene 1.0 u
Ethylbenzene 1.0 u
Styrene 1.0 u
Xylenes, Total 2.0 u
Surrogate %Rec
Toluene-dB 94
4-Bromofluorobenzene 106 • Dibromofluornmethane 89
Calculations are performed before rounding to avoid round-off errors in calculated results.
STL Savannah Page 12 of 16
Quality Control Results
Job Number: 680-14947-1
Method: 8260B
Preparation: 5030B
Instrument ID: GC/MS Volatiles - P
Lab File ID: pq289.d
Initial WeighWolume: 5 ml
Final WeighWolume: 5 ml
RL
1.0
1.0
1.0
1.0
5.0
25
2.0
1.0
1.0
1.0
1.0
1.0
1.0
10
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
10
1.0
1.0
1.0
1.0
1.0
2.0
A?ceptan~. Limits
79 -122
77 -120
75 -123
•
•
•
Client: ENSR International
Laboratory Control Sample• Batch: 680-40698
Lab Sample ID: LCS 680-40698/3 Analysis Batch:
Client Matrix: Water Prep Batch: N/A
Dilution: 1.0 Units: ug/L
Date Analyzed: 04/03/2006 1052
Date Prepared: 04/03/2006 1052
Analyte Spike Amount
-· Chloromethane 50.0
Bromomethane 50.0
Vinyl chloride 50.0
Chloroethane 50.0
Methylene Chloride 50.0
Acetone 100
Carbon disulfide 50.0
. 1, 1-Dichloroethene 50.0
1, 1-Dichloroethane 50.0
cis-1,2-0ichloroethene 50.0
trans-1,2-Dichloroethene 50.0
Chloroform 50.0
1,2-Dichloroethane 50.0
Methyl Ethyl Ketone 100
1, 1, 1-Trichloroethane 50.0
Carbon tetrachloride 50.0
Dichlorobromomethane 50.0
1, 1,2,2-Tetrachloroethane 50.0
1,2-Dichloropropane 50.0
trans-1,3-Dichloropropene 50.0
Trichloroethene 50.0
Chlorodibromomethane 50.0
1, 1,2-Trichloroethane 50.0
Benzene 50.0
cis-1,3-Dichloropropene 50.0
Bromoform 50.0
2-Hexanone 100
methyl isobutyl ketone 100
Tetrachloroethene 50.0
Toluene 50.0
Chlorobenzene 50.0
Ethylbenzene 50.0
Styrene 50.0
Xylenes, Total 150
680-40698
Result
21
33
26
29
41
100
37
38
46
45
41
45
48
94
49
51
50
49
48
53
48
48
46
45
53
53
110
99
49
46
47
48
50
150
Quality Control Results
Job Number: 680-14947-1
Method: 8260B
Preparation: 5030B
Instrument ID: GC/MS Volatiles. P
Lab File ID: pq285.d
Initial WeighWolume: 5 ml
Final WeighWolume: 5 ml
% Rec. Limit Qual
..
42 51 -133
66 21 • 176
52 59 -136
57 40 • 171
82 67 -128
102 20 -183
75 60 -130
76 64 -132
92 70 • 127
90 69 -126
82 67 • 130
91 74 -124
96 68 -130
94 51 -142
98 70 -132
101 64 -137
100 74 • 128
98 71 • 127
96 74 • 123
106 75-126
96 75 • 122
96 75 • 126
92 75 • 122
90 74 • 122
106 76 • 126
107 64 -132
115 58 -139
99 62 -130
98 70 -133
91 75 • 122
95 75 • 123
96 77 • 123
101 75 • 125
98 77 -121
Calculations are performed before rounding to avoid round-off errors in calculated results.
STl Savannah Page13of16
•
•
Client: ENSR International
Method Blank -Batch: 680-40044
Lab Sample ID: MB 680-40044/1-A
Client Matrix: Water
Dilution: 1.0
Date Analyzed: 03/27/2006 1314
Date Prepared: 03/27/2006 0700
Analyte
Cyanide, Total
Laboratory Control/
Analysis Batch: 680-40046
Prep Batch: 680-40044
Units: mg/L
Result
0.0050
Laboratory Control Duplicate Recovery Report -Batch: 680-40044
LCS Lab Sample ID: LCS 680-40044/2-A
Client Matrix: Water
Dilution: 1.0
Date Analyzed: 03/27/2006 1315
Date Prepared: 03/27/2006 0700
LCSD Lab Sample ID: LCSD 680-40044/3-A
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
Analyte
Cyanide, Total
Water
1.0
03/27/2006 1315
03/27/2006 0700
Analysis Batch: 680-40046
Prep Batch: 680-40044
Units: mg/L
Analysis Batch: 680-40046
Prep Batch: 680-40044
Units:mg/L
%Rec.
LCS LCSD Limit
100 98 90-110
Qual
u
Quality Control Results
Job Number: 680-14947-1
Method: 335A
Preparation: Distillation
Instrument ID: No Equipment Assigned
Lab File ID: N/A
Initial WeighWolume: 50 ml
Final WeighWolume: 50 ml
RL
0.0050
Method: 335.4
Preparation: Distillation
Instrument ID: No Equipment Assigned
Lab File ID: N/A
. Initial WeighWolume: 50 ml
Final WeighWolume: 50 ml
Instrument ID: No Equipment Assigned
Lab File ID: N/A
Initial WeighWolume: 50 ml
Final WeighWolume: 50 ml
RPD
2
RPD Limit LCS Qual LCSD Qual
20
Calculations are performed before rounding to avoid round-off errors in calculated results.
STL Savannah Page 14 of 16
•
•
•
Client: ENSR International
-Matrix Duplicate -Batch: 680-40044
Lab Sample ID: 680-14947-1
Client Matrix: Water
Dilution: 1.0
Date Analyzed: 03/27/2006 1331
Date Prepared: 03/27/2006 0700
Analyte
Cyanide, Total
Analysis Batch: 680-40046
Prep Batch: 680-40044
Units: mg/L
Sample Result/Qual
0.0055
Result
0.0053
Calculations are performed before rounding to avoid round-off errors in calculated results.
STL Savannah Page 15 of 16
Quality Control Results
Job Number: 680-14947-1
-Method: 335.4
Preparation: Distillation_
Instrument ID: No Equipment Assigned
Lab File ID: N/A
ln~ial WeighWolume: 50 ml
Final WeighWolume: 50 ml
RPD
3
Limit
20
Qual
SEVERN
TRENT
~~:,:1: ., . :-;:•. :.1:<r-!?:~~~:
ANALYSIS REQUEST AND CHAIN OF CUSTODY RECORD
STL
PROJECT NO.
DI o · 19
TIME u,J9-'
TIME
PROJECT LOCATION
(STATE) f\JC,
CONTRACT NO.
MATRIX
TYPE
✓
RELINQUISHED BY: !SIGNATURE!
RECEIVED BY: fSIGNATUREJ
0 sn Savannah
5102 LaRoche Avenue
Savannah, GA 31404
Serial Number 9 0 5 6 7
website: www.stl-inc.com
Phone: [phone]
Fax: [phone]
0 Alternate laboratory NameAocatlon
Phone:
Fax:
REQUIRED ANALYSIS PAGE
lt
DATE TIME RELINQUISHED BY: ISIGNATUREI DATE
DATE TIME RECEIVED BY: !SIGNATUREI DATE
OF
REMARKS
TIME
TIME
STL8240--680 U2,,1)21 •
•
April 2006 Analytical Data
•
•
•
•
Project Manager: Kathryn Smith
SEVERN
TRENT
ANALYTICAL REPORT
Job Number: 680-15321-1
Job Description: Channel Master
For:
ENSR International
7041 Old Wake Forrest Road
Raleigh, NC 27616
Attention: Mr. Gerald Hornaday
Kathryn Smith
Project Manager I
[e-mail]
04/14/2006
STL
The test results in this report meet all NELAP requirements for parameters for which accreditation· is required or available. Any
exceptions to NE LAP requirements are noted in this report. Pursuant to NE LAP, this report may not be reproduced, except in full,
without the written approval of the laboratory. All questions regarding this test report should be directed to the STL Project Manager
who signed this test report .
Severn Trent Laboraiories, Inc.
STL Savannah 5102 LaRoche Avenue, Savannah, GA 31404
Tel [phone] Fax [phone] www.sll-inc.com
Page 1 of 14
•
•
•
Client: ENSR International
Description
Matrix: Water
Volatile Organic Compounds by GC/MS
Purge-and-Trap
Cyanide, Total (Semi-Automated Colorimetry)
Distillation/Cyanide
LAB REFERENCES:
STL-SAV = STL-Savannah
METHOD REFERENCES:
METHOD SUMMARY
Job Number: 680-15321-1
Lab Location Method Preparation Method
STL-SAV
STL-SAV
STL-SAV
STL-SAV
SW846 . 82608
MCAWW 335.4
SW846 50308
Distillation
MCAWW -"Methods For Chemical Analysis Of Water And Wastes", EPA-600/4-79-020, March 1983 And
Subsequent Revisions. ·
SW846 -"Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986
And Its Updates .
STL Savannah
Page 2 of 14
•
•
•
Client: ENSR International
Lab Sample ID
680-15321-1
680-15321-2
STL Savannah
Client Sample ID
EFFLUENT
Trip Blank
SAMPLE SUMMARY
Client Matrix
Water
Water
Page 3 of 14
Date/Time
Sampled
04/04/2006 1435
04/04/2006 0000
Job Number: 680-15321-1
Date/Time
Received
04/05/2006 0912
04/05/2006 0912
•
•
•
Client: ENSR International
Client Sample ID:
Lab Sample ID:
Client Matrix:
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
EFFLUENT
680-15321-1
Water
82606
50306
1.0
82608 Volatile Organic Compounds by GC/MS
Analysis Batch: 680-41698
04/12/2006 1453
04/12/2006 1453
Analytical Data
Job Number: 680-15321-1
Date Sampled: 04/04/2006 1435
Date Received: 04/05/2006 0912
Instrument ID:
Lab File ID:
GC/MS Volatiles -0
00923.d
Initial WeighWolume: 5 ml
5 ml Final WeighWolume:
Analyte
Chloromethane
Bromomethane
Vinyl chloride
Chloroethane
Methylene Chloride
Acetone
Result (ug/L) Qualifier RL
Carbon disulfide
1, 1-Dichloroethene
1, 1-Dichloroethane
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Chloroform
1,2-Dichloroethane
Methyl Ethyl Ketone
1, 1, 1-Trichloroethane
Carbon tetrachloride
Dichlorobromomethane
1, 1,2,2-Tetrachloroethane
1,2-Dichloropropane
trans-1, 3-Dichloropropene
Trichloroethane
Chlorodibromomethane
1, 1,2-Trichloroethane
Benzene
cis-1,3-Dichloropropene
Bromoform
2-Hexanone
methyl isobutyl ketone
T etrachloroethen~
Toluene
Chlorobenzene
Ethyl benzene
Styrene
Xylenes, Total
Surr_o~ate
Toluene-dB
4-Bromofluorobenzene
Dibromofluoromethane
STL Savannah
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
5.0 u 5.0
25 u 25
2.0 u 2.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
10 u 10
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
10 u 10
10 u 10
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
2.0 u 2.0
%Rec Acceptance Limits
"•· -.-. --...
101 79 -122
106 77 -120
103 75 -123
Page 4 of 14
•
•
•
Client: ENSR International
Client Sample ID:
Lab Sample ID:
Client Matrix:
Trip Blank
680-15321-2
Water
Analytical Data
Job Number: 680-15321-1
Date Sampled: 04/04/2006 0000
Date Received: 04/05/2006 0912
8260B Volatile Organic Compounds by GC/MS
Method: 8260B Analysis Batch: 680-41264 Instrument ID: GC/MS Volatiles -0
Preparation: 5030B Lab File ID: 00833.d
Dilution: 1.0 Initial WeighWolume: 5 ml
Date Analyzed: 04/0712006 1937 Final WeighWolume: 5 ml
Date Prepared: 0410712006 1937
Analyte Result (ug/L) Qualifier . RL
Chloromethane 1.0 u· 1.0
Bromomethane 1.0 u 1.0
Vinyl chloride. 1.0 u· 1.0
Chloroethane 1.0 u 1.0
Methylene Chloride 5.0 u 5.0
Acetone· 25 u 25
Carbon disulfide 2.0 u 2.0
1, 1-Dichloroethene 1.0 u 1.0
1, 1-Dichloroethane 1.0 u 1.0
cis-1,2-Dichloroethene 1.0 u 1.0
trans-1,2-Dichloroethene 1.0 u 1.0
Chloroform 1.0 u 1.0
1,2-Dichloroethane 1.0 u 1.0
Methyl Ethyl Ketone 10 u 10
1, 1, 1-Trichloroethane 1.0 u 1.0
Carbon tetrachloride 1.0 u 1.0
Dichlorobromomethane 1.0 u 1.0
1, 1,2 ,2-T etrachloroethane 1.0 u 1.0
1,2-Dichloropropane 1.0 u 1.0
trans-1,3-Dichloropropene 1.0 u 1.0
Trichloroethene 1.0 u 1.0
Chlorodibromomethane 1.0 u 1.0
1, 1,2-Trichloroethane 1.0 u 1.0
Benzene 1.0 u 1.0
cis-1,3-Dichloropropene 1.0 u 1.0
Bromoform 1.0 u 1.0
2-Hexanone 10 u 10
methyl isobutyl ketone 10 u 10
Tetrachloroethene 1.0 u 1.0
Toluene 1.0 u 1.0
Chlorobenzene 1.0 u 1.0
Ethylbenzene 1.0 u 1.0
Styrene 1.0 u 1.0
Xylenes, Total 2.0 u 2.0
Surrogate %Rec Acceptance Limits
Toluene-dB 103 79 -122
4-Bromofluorobenzene 103 77 -120
Dibromofluoromethane 106 75 -123
STL Savannah Page 5 of 14
•
•
•
Client: ENSR International
· Client Sample ID: EFFLUENT
Lab Sample ID: 680-15321-1
Client Matrix: -Water
Analyte
Cyanide, Total
STL Savannah
Result
0.0058
Anly Batch: 680-41319
Prep Batch: 680-41316
General Chemistry
Qual Units
mg/L
Date Analyzed 04/07/2006 1406
Date Prepared: 04/07/2006 0800
Page 6 of 14
Analytical Data
Job Number: 680-15321-1
Date Sampled: 04/04/2006 1435
Date Received: 04/05/2006 0912
RL Dil Method
0.0050 1.0 335.4
•
Client: ENSR International
Lab Section Qualifier
GC/MSVOA
u
•
General Chemistry
u
•
• STL Savannah
DATA REPORTING QUALIFIERS
Job Number: 680715321-1
Description
Analyte was not detected at or above the reporting limit.
LCS, LCSD, MS, MSD, MD, or Surrogate exceeds the control
limits
Analyte was not detected at or above the reporting limit.
Page 7 of 14
• Client: ENSR International
Surrogate Recovery Report
8260B Volatile Organic Compounds by GC/MS
Client Matrix: Water
Lab Samele ID Client Samele
LCS 680-41264/3
LCS 680-41698/1
MB 680-41264/5
MB 680-41698/3
680-15321-1 EFFLUENT
680-15321-2 Trip Blank
Surrogate
(BFB) 4-Brornofluorobenzene • (DBFM) Oibromofluoromethane
(TOL) Toluene-dB
•
STL Savannah
(BFB) (DBFM) (TOL)
(%Rec) (%Rec) (%Rec)
98 93 97
97 100 104
101 99 102
102 106 103
106 103 101
103 106 103
Acceptance Limits
77 -120
75 -123
79 -122
Page 8 of 14
Quality Control Results
Job Number: 680-15321-1
• Client: ENSR International
Method Blank· Batch: 680-41264
Lab Sample ID: MB 680-41264/5 Analysis Batch: 680-41264
Client Matrix: Water Prep Batch: N/A
Dilution: 1.0 Units: ug/L
Date Analyzed: 04/07/2006 1158
Date Prepared: 04/07/2006 1158
Analyte Result Qual
Chloromethane 1.0 u
Brome methane 1.0 u
Vinyl chloride 1.0 u
Chloroethane 1.0 u
Methylene Chloride 5.0 u
Acetone 25 u
Carbon disulfide 2.0 u
1, 1-Dichloroethene 1.0 u
1, 1-Dichloroethane 1.0 u
cis-1,2-Dichloroethene 1.0 u • trans-1,2-Dichloroethene 1.0 u
Chloroform 1.0 u
1,2-Dichloroethane 1.0 u
Methyl Ethyl Ketone 10 u
1, 1, 1-Trichloroethane 1.0 u
Carbon tetrachloride 1.0 u
Dichlorobromomethane 1.0 u
1, 1,2,2-Tetrachloroethane 1.0 u
1,2-Dichloropropane 1.0 u
trans-1,3-Dichloropropene 1.0 u
Trichloroethane 1.0 u
Chlorodibromomethane 1.0 u
1, 1,2-Trichloroethane 1.0 u
Benzene 1.0 u
cis-1,3-Dichloropropene 1.0 u
Bromoform 1.0 u
2-Hexanone 10 u
methyl isobutyl ketone 10 u
Tetrachloroethene 1.0 u
Toluene 1.0 u
Chlorobenzene 1.0 u
Ethyl benzene 1.0 u
Styrene 1.0 u
Xylenes, Total 2.0 u
Surrogate % Rec
Toluene-d8 102
4-Bromofluorobenzene 101
Dibromofluoromethane 99 • Calculations are performed before rounding to avoid round-off errors in calculated results.
STL Savannah Page 9 of 14
Quality Control Results
Job Number: 680-15321-1
Method: 8260B
Preparation: 5030B
Instrument ID: GC/MS Volatiles -0
Lab File ID: oq533.d
Initial WeighWolume: 5 ml
Final WeighWolume: 5 ml
RL
1.0
1.0
1.0
1.0
5.0
25
2.0
1.0
1.0
1.0
1.0
1.0
1.0
10
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
10
1.0
1.0
1.0
1.0
1.0
2.0
Acceptance Limits
79 -122
77 -120
75 -123
•
•
•
Client: ENSR International
Laboratory Control Sample -Batch: 680-41264
Lab Sample ID: LCS 680-41264/3 Analysis Batch:
Client Matrix: Water Prep Batch: N/A
Dilution: 1.0 Units:ug/L
Date Analyzed: 04/07/2006 1053
Date Prepared: 04/07/2006 1053
Analyte Spike Amount
... ....... ,
Chloromethane 50.0
Bromomethane 50.0
Vinyl chloride 50.0
Chloroethane 50.0
Methylene Chloride 50.0
Acetone 100
Carbon disulfide 50.0
1, 1-Dichloroethene 50.0
1, 1-Dichloroethane 50.0
cis-1,2-Dichloroethene 50.0
trans-1,2-Dichloroethene 50.0
Chlorofonn 50.0
1,2-Dichloroethane 50.0
Methyl Ethyl Ketone 100
1, 1, 1-Trichloroethane 50.0
Carbon tetrachloride 50.0
Dichlorobromomethane 50.0
1, 1,2,2-Tetrachloroethane 50.0
1,2-Dichloropropane 50.0
trans-1,3-Dichloropropene 50.0
Trichloroethane 50.0
Chlorodibromomethane 50.0
1, 1,2-Trichloroethane 50.0
Benzene 50.0
cis-1,~-Dichloropropene 50.0
Bromoform 50.0
2-Hexanone 100
methyl isobutyl ketone 100
Tetrachloroethene 50.0
Toluene 50.0
Chiaro benzene 50.0
Ethylbenzene 50.0
Styrene 50.0
Xylenes, Total 150
680-41264
Result
22
34
29
39
42
86
37
42
46
46
46
47
53
96
53
55
53
48
51
52
49
53
50
49
51
53
100
100
49
49
49
50
50
150
Quality Control Results
Job Number: 680-15321-1
Method: 8260B
Preparation: 5030B
Instrument ID: GC/MS Volatiles -0
Lab File ID: oq529.d
Initial WeighWolume: 5 ml
Final WeighWolume: 5 ml
% Rec . Limit Qual
.
43 51 -133
67 21 -176
57 59 -136 •
78 40 -171
85 67 -128
86 20 -183
75 60 -130
83 64 -132
92 70 -127
91 69 -126
91 67 -130
94 74·_ 124
105 68-130
96 51 -142
106 70 -132
109 64 -137
107 74 -128
96 71 -127
102 74 -123
104 75 -126
99 75 -122
105 75 -126
100 75 -122
99 74-122
102 76-126
105 64 -132
104 58 -139
105 62 -130
99 70 -133
98 75 -122
97 75 -123
100 77 -123
101 75 -125
100 77 -121
Calculations are performed before rounding to avoid round-off errors in calculated results.
STL Savannah Page 10 of 14
•
•
•
Client: ENSR International
Method Blank -Batch: 68041698
Lab Sample ID: MB 68()-41698/3
Client Matrix: Water
Dilution: 1.0
Date Analyzed: 04/12/2006 1158
Date Prepared: 04/12/2006 1158
Analyte
Chloromethane
Bromomethane
Vinyl chloride
Chloroethane
Methylene Chloride
Acetone.
Carbon disulfide
1, 1-Dichloroethene
1, 1-Dichloroethane
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Chlorofonm
1,2-Dichloroethane
Methyl Ethyl Ketone
1, 1, 1-Trichloroethane
Carbon tetrachloride
Oichlorobromomethane
1, 1,2,2-Tetrachloroethane
1,2-Dichloropropane
trans-1,3-0ichloropropene
Trichloroethene
Chlorodibromomethane
1, 1,2-Trichloroethane
Benzene
cis-1,3-Dichloropropene
Bromoform
2-Hexanone
methyl isobutyl ketone
Tetrachloroethene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Xylenes, Total
Surrogate
Toluene-dB
4-Bromofluorobenzene
Dibromofluoromethane
Analysis Batch: 680-41698
Prep Batch: N/A
Units: ug/L
Result
1.0
1.0
1.0
1.0
5.0
25
2.0
1.0
1.0
1.0
1.0
1.0
1.0
10
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
10
1.0
1.0
1.0
1.0
1.0
2.0
%Rec
103
102
106
Qual
u
u
Li
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
Calculations are performed before rounding to avoid round-off errors in calculated results.
STL Savannah Page 11 of 14
Quality Control Results
Job Number: 680-15321-1
Method: 8260B
Preparation: 5030B
Instrument ID: GC/MS Volatiles -0
Lab File ID: oq573.d
Initial WeighWolume: 5 ml
Final WeighWolume: 5 ml
Rl
1.0
1.0
1.0
1.0
5.0
25
2.0
1.0
1.0
1.0
1.0
1.0
1.0
10
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
10
1.0
1.0
1.0
1.0
1.0
2.0
Acceptance Limits
79 -122
77 -120
75 -123
•
•
•
Client: ENSR International
Laboratory Control Sample -Batch: 680-41698
Lab Sample ID: LCS 680-41698/1 Analysis Batch:
Client Matrix: Water Prep Batch: NIA
Dilution: 1.0 Units: ug/L
Date Analyzed: 04/12/2006 1053
Date Prepared: 04/12/2006 1053
Analyte Spike Amount
Chloromethane 50.0
Bromomethane 50.0
Vinyl chloride 50.0
Chloroethane 50.0
Methylene Chloride 50.0
· Acetone 100
Carbon disulfide 50.0
1, 1-Dichloroethene 50.0
1, 1-0ichloroethane 50.0
• cis-1,2-Dichloroethene 50.0
trans-1,2-Dichloroethene 50.0
Chloroform 50.0
1,2-Dichloroethane 50.0
Methyl Ethyl Ketone 100
1, 1, 1-Trichloroethane 50.0
Carbon tetrachloride 50.0
Dichlorobromomethane 50.0
1, 1,2,2-Tetrachloroethane 50.0
1,2-Dichloropropane 50.0
trans-1,3-Dichloropropene 50.0
Trichloroethane 50.0
Chlorodibromomethane 50.0
1, 1,2-T richloroethane 50.0
Benzene 50.0
cis-1,3-Dichloropropene 50.0
Bromoform 50.0
2-Hexanone 100
methyl isobutyl ketone 100
Tetrachloroethene 50.0
Toluene 50.0
Chlorobenzene 50.0
Ethylbenzene 50.0
Styrene 50.0
Xylenes, Total 150
680-41698
Result
46
49
49
46
41
100
54
45
43
42
44
43
42
100
47
50
43
40
42
45
43
42
41
43
46
45
100
99
45
43
42
43
42
120
Quality Control Results
Job Number: 680-15321-1
Method: 8260B
Preparation: 5030B
Instrument ID: GC/MS Volatiles • 0
Lab File ID: oq569.d
Initial WeighWolume: 5 ml
Final WeighWolume: 5 ml
% Rec. Limit Qua!
....
92 51 -133
99 21 -176
98 59 -136
92 40 -171
83 67 -128
100 20 -183
109 60 -130
90 64 -132
86 70 -127
83 69-126 .
88 67 -130
87 74 -124
85 68-130
101 51 -142
94 70-132
99 64 • 137
86 74 -128
81 71 -127
85 74 -123
90 75-126
87 75 -122
83 75 • 126
82 75 • 122
86 74 -122
93 76 -126
89 64 -132
101 58 -139
99 62 -130
89 70 -133
86 75 -122
84 75 • 123
86 77 -123
84 75 • 125
83 77 -121
Calculations are performed before rounding to avoid round-off errors in calculated results.
STL Savannah Page 12 of 14
•
•
•
Client: ENSR International
Method Blank·• Batch: 680-41316
Lab Sample ID: MB 680-41316/1-A
Client Matrix: Water
Dilution: 1.0
Date Analyzed: 04/07/2006 1354
Date Prepared: 04/07/2006 0800
Analyte
Cyanide, Total
Laboratory Control/
Analysis Batch: 680-41319
Prep Batch: 680-41316
Units: mg/L
Result
0.0050
Laboratory Control Duplicate Recovery Report -Batch: 680-41316
LCS Lab Sample ID: LCS 680-41316/2-A
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
Water
1.0
04/07/2006 1355
04/07/2006 0800
LCSD Lab Sample IO:LCSD 680-41316/3-A
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
Analyte
Cyanide, Total
Water
1.0
04/07/2006 1356
04/07/2006 0800
Analysis Batch: 680-41319
Prep Batch: 680-41316
Units: mg/L
Analysis Batch: 680-41319
Prep Batch: 680-41316
Units:mg/L
%Rec.
LCS LCSD Limit
105 101 90 -110
Qual
u
RPO
4
Calculations are performed before rounding to avoid round-off errors in calculated results.
STL Savannah Page 13 of 14
Quality Control Results
Job Number: 680-15321-1
Method: 335.4
Preparation: Distillation
Instrument ID: No Equipment Assigned
Lab File ID: N/A
Initial WeighWolume: 50 ml
Final WeighWolume: 50 ml
Method: 335.4
RL
0.0050
Preparation: Distillation
Instrument ID: No Equipment ASsigned
Lab File ID: N/A
Initial WeighWolume: 50 ml
Final WeighWolume: 50 ml
Instrument ID: No Equipment Assigned
Lab File ID: N/A
Initial WeighWolume: 50 ml
Final WeighWolume: 50 ml
RPO Limit LCS Qual LCSD Qual
20
ANALYSIS REQUEST AND CHAIN OF CUSTODY RECORD
SEVERN
TRENT
DATE TIME
ti ol. 11/tS~
RELINQUISHED BY: !SIGNATURE>
STL
PROJECT NO.
P.O. NUMBER
DATE TIME
TIME
/3!:30
PROJECT LOCATION
(STATE) ,(/f_
CONTRACT NO.
MATRIX
TYPE
•
~ STL Savannah
5102 laRoche Avenue
Savannah, GA 31404
Serial Number 9 0 5 6 9
Website: www.stl-inc.com
Phone: [phone]
Fax: [phone]
0 Alternate laboratory Name/location
Phone:
Fax:
REQUIRED ANALYSIS PAGE
I
RELINQUISHED BY: !SIGNATURE> DATE
RECEIVED BY: ISGNATUR£J DATE
OF
TIME
TIME
0
(I)
C)
D..
.Tl824(>,;80 ll 2/1l21
•
•
•
ENSR Corporation
7041 Old Wake Forest Road, Suite 103, Raleigh, North Carolina 27616
T 919 872 6600 F 919 872 7996 www.ensr.aecom.com
February 13, 2006
Mr. Larry Thomas
City Engineer
City of Oxford
P.O. Box 1307
Oxford, North Carolina 27565
RE: Industrial Users Report for January 2006
JFD Electronics/Channel Master NPL Site, Oxford, North Carolina.
Dear Mr. Thomas:
ENSR AECOM
On behalf of The Unimax Corporation and Avnet, Inc., ENSR Consulting and Engineering (NC), Inc. is
submitting the Quarterly Industrial User Permit report for the months of November, December 2005
and January 2006. This report is prepared in accordance with permit requirements for the discharge of
treated groundwater at the above referenced site.
If you have any questions, please contact us at [phone].
Sincerely,
ENSR Consulting and Engineering (NC), Inc.
Gerald Y. Horn ay, P.E.
Project Enginee~
Enclosure
William H. Doucette, Jr., Ph.D.
Senior Program Manager
cc: Brian Kempner, The Unimax Corporation (w/o lab attachment)
S. Alan Lazar, Avnet, Inc. (w/o lab attachment)
Steve Earp, Smith Helms Muliss & Moore (w/o lab attachment)
David Mattison, NCDENR Supertund
Ken Lucas, USEPA Superfund
Nanjun Shetty, P.E., ENSR
File
S:\PUBS\PROJECnC\ChannelMaster\Ouarter1y lUReports\2006\Feb 2006\IUR Letter Feb 2006.doc
•
•
INDUSTRIAL USER REPORTING FORM
J.U. PERMIT NO: _ _,,G=0"-01'-----DISCHARGE NO: ___ _,c00"-1'------
MONTHS: November. December 2005 and January 2006 YEAR: 2005 and 2006
J.U. NAME: JFD Electronics/Channel Master CLASS: COUNTY: Granville
OPERATOR IN RESPONSIBLE CHARGE (ORC): ENSR Consulting & Engineering {NC}. Inc.
LABORATORY PERFORMING ANALYSIS: STL-Savannah Laboratories
PERSON(S) COLLECTING SAMPLES: Gerald Hornaday. P.E. {ENSR). Seth Ryan {ENSR)
CHECK BLOCK IF ORC HAS CHANGED 0
SEND REPORT TO: City Engineer
City of Oxford
P.O. Box 1307
Oxford, NC 27565
Facility Status: (Please check one of the following)
All monthly averages and/or other limitations do meet permit monitoring requirements. [81
(Compliant)
All monthly averages and/or other limitations do not meet permit monitoring requirements. D
(Noncompliant)
If the facility is noncompliant, please comment on corrective actions being taken in respect to
equipment, operation, maintenance, etc. and a time table for improvements to be made.
(Attach additional sheets ifnecessary)
I certify that this Report is accurate and
complete to the best of my knowledge:
~ HG
Signature of Permittee Representative
William H. Doucette, Jr., Ph.D.
Date:
•
•
•
TABLE 1. GROUNDWATER REMEDIATION SYSTEM DISCHARGE MONITORING REPORT, CITY OF OXFORD, NORTH CAROLINA
I.U. PERMIT NO:
DISCHARGE NO:
MONTIIS:
YEAR:
1.U. NAME:
COUNTY:
OPERATOR IN RESPONSIBLE CHARGE (ORC):
LABORATORY PERFORMING ANALYSIS:
PERSON($) COLLECTING SAMPLES:
PARAMETER
Dally Average Flow (MGD)
Tetrachloroethylene
1, 1-0lchloroethane
cis-1,2 Oichloroethene
Chlorobenzene
Toluene
1,1-0ichloroethylene
trans•1.2 Dlchloroethylene
Trichloroethene
Vinyl Chloride
Cyanide (total)
pH
Temperature
Monitoring requirement only.
MGD Milllon Gallons per day.
µg/L Micrograms per liter.
mg/L Milligrams per liter.
SU Standard Units.
°C Degrees Centigrade.
G001
001
November, December and January
2005 and 2006
JFD Electronics/Channel Master NPL Site
Granville
ENSR Consulting & Engineering (NC), Inc.
STL Savannah Laboratories
Gerald Hornaday, P.E. (ENSR); Seth Ryan (ENSR)
PERMIT LIMITS UNITS SAMPLE
Dally Maximum TYPE
0.040 MGD Meter
µg/L Grab
µg/L Grab
µg/L Grab
µg/L Grab
µg/L Grab
µg/L Grab
µg/L Grab
µg/L Grab
µg/L Grab
0.05 mg/L Grab
5.0to 10.0 SU Grab
40 •c Grab
< Compound was not detected above the quantitation limit.
G:1Env\JFOCHANN'\NC0202.170\0ty of O~lord\lURTable Feb 2006\Teble 11211312006
LAB MONTHLY MEASUREMENT
METHOD DATES
11128/05 12/19/05 01/27/08
Field 0.028 0.016 0.022
8260 <1.0 <1.0 <1.0
8260 <1.0 <1.0 <1.0
8260 <1.0 <1.0 <1.0
8260 <1.0 <1.0 <1.0
8260 <1.0 <1.0 <1.0
8260 <1.0 <1.0 <1.0
8260 <1.0 <1.0 <1.0
8260 <1.0 <1.0 <1.0
8260 <1.0 <1.0 <1.0
335.2 0.0060 0.0070 0.0058
Field 7.41 7.78 7.83
Field 17.8 16.9 22.6
•
•
November 2005 Analytical Data
•
•
•
•
• Severn Trent Laboratories, Inc.
ANALYTICAL REPORT
Job Number: 680-11010-1
Job Description: Channel Master
For:
ENSR International
7041 Old Wake Forrest Road
Raleigh, NC 27616
Attention: Mr. Gerald Hornaday
Kathryn Smith
Project Manager I
[e-mail]
12/12/2005
STL Savannah 5102 LaRoche Avenue, Savannah, GA 31404
Tel [phone] Fax [phone] www.stl-inc.com
Page 1 of 12
•
•
•
Client: ENSR International
Description
Matrix: Water
Volatile Organic Compounds by GC/MS
Purge-and-Trap
Cyanide, Total (Semi-Automated Colorimetry)
Distillation/Cyanide
LAB REFERENCES:
STL-SAV = STL-Savannah
METHOD REFERENCES:
METHOD SUMMARY
Lab Location Method
STL-SAV
STL-SAV
STL-SAV
STL-SAV
SW846 8260B
MCAWW 335.4
Job Number: 680-11010-1
Preparation Method
SW846 5030B
Distillation
MCAWW-"Methods For Chemical Analysis Of Water And Wastes", EPA-600/4-79-020, March 1983 And
Subsequent Revisions .
SW846 -"Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986
And Its Updates .
STL Savannah
Page 2 of 12
•
•
•
Client: ENSR International
Lab Sample ID
680-11010-1
680-11010-2
STL Savannah
Client Sample ID
Effluent
Trip Blank
SAMPLE SUMMARY
Client Matrix
Water
Water
Page 3 of 12
Date/Time
Sampled
11/28/2005 1600
11/28/2005 0000
Job Number: 680-11010-1 •
Date/Time
Received
11/30/2005 1020
11/30/2005 1020
•
•
•
Client: ENSR International
Client Sample ID: Effluent
Lab Sample ID:
Client Matrix:
680-11010-1
Water
Analytical Data
Job Number: 680-11010-1
Date Sampled:
Date Received:
11/28/2005 1600
11/30/2005 1020
Method: 82608
5030B
1.0
8260B Volatile Organic Compounds by GC/MS
Analysis Batch: 680-30354 Instrument ID: GC/MS Volatiles -O
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
12/07/2005 1254
12/07/2005 1254
Analyte ----·-··--··-··
Chloromethane
Bromomethane
Vinyl chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1, 1-Dichloroethene
1, 1-Dichloroethane
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Chloroform
1, 2-Dichloroethane
Methyl Ethyl Ketone
1, 1, 1-Trichloroethane
Carbon tetrachloride
Dichlorobromomethane
1, 1,2,2-Tetrachloroethane
1,2-Dichloropropane
trans-1,3-Dichloropropene
Trichloroethane
Chlorodibromomethane
1, 1,2-Trichloroethane
Benzene
cis-1,3-Dichloropropene
Bromoform
2-Hexanone
methyl isobutyl ketone
T etrachloroethene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Xylenes, Total
Toluene-<18
4-Bromofluorobenzene
Dibromofluoromethane
STL Savannah
Lab File ID: 02633.d
Initial WeighWolume: 5 ml
Final WeighWolume: 5 ml
-·-· Result _(ug/l) _______ Qualifier RL
. -----·----· -·-------··
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
5.0 u 5.0
25 u 25
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
10 u 10
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
10 u 10
10 u 10
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
2.0 u 2.0
%Re~-----·-----··-----------·~------A?C8ptance Limits
104
92
100
Page 4 of 12
79 -122
77 -120
75 -123
•
•
•
Client: ENSR International
Client Sample ID: Trip Blank
Lab Sample ID:
Client Matrix:
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
680-11010-2
Water
8260B
5030B
1.0
82608 Volatile Organic Compounds by GC/MS
Analysis Batch: 680-30354
12107 /2005 1223
1210712005 1223
Analytical Data
Job Number. 680-11010-1
Date Sampled: 11/28/2005 0000
Date Received: 11/30/2005 1020
Instrument ID:
Lab File ID:
GC/MS Volatiles -0
02631.d
Initial WeighWolume: 5 ml
Final WeighWolume: 5 ml
~~-~-:~yt_e --
Chloromethane
Bromomethane
.... _ ·---······----·· .•• ________ Result (ug/L) ·----~"..'.'!i~e'. _____________________ ....•. fl:~-------····· ... ,..
Vinyl chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1, 1-Dichloroethene
1, 1-Dichloroethane
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Chlorofonn
1, 2-Dichloroethane
Methyl Ethyl Ketone
1, 1, 1-Trichloroethane
Carbon tetrachloride
D\chlorobromomethane
1, 1,2,2-Tetrachloroethane
1,2-Dichloropropane
trans-1 ,3-Dichloropropene
Trichloroethane
Chlorodibromomethane
1, 1,2-Trichloroethane
Benzene
cis-1,3-Dichloropropene
Bromoform
2-Hexanone
methyl isobutyl ketone
Tetrachloroethene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Xylenes, Total
1.0 U
1.0 U
1.0 U
1.0 U
5.0 U
25 U
1.0 U
1.0 U
1.0 U
1.0 U
1.0 U
1.0 U
1.0 U
10 U
1.0 U
1.0 U
1.0 U
1.0 U
1.0 U
1.0 U
1.0 U
1.0 U
1.0 U
1.0 U
1.0 U
1.0 U
10 U
10 U
1.0 U
1.0 U
1.0 U
1.0 U
3.8
2.0 U
1.0
1.0
1.0
1.0
5.0
25
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
10
1.0
1.0
1.0
1.0
1.0
2.0
rS.~r'!.'?..Q~t: ____ .. ,. .. ····--------·-· _ ··--·-·------·· ·--------· __ . _ ....... ______ .. -~~~~_? ___ , ... --•-····-·----------------·--·--·--·-··---_Acceptance Limits ___ ----·----·-·
Toluene--08
4-Bromofluorobenzene
Oibromofluoromethane
STLSavannah
102
93
101
Page 5 of 12
79-122
77 -120
75 -123
•
•
•
Client: ENSR International
Client Sample ID:
Lab Sample ID:
Client Matrix:
Analyte
Cyanide, Total
STL Savannah
Effluent
680-11010-1
Water
Result
0.0060
Anly Batch: 680-29914
Prep Batch: 680-29911
General Chemistry
Qual Units
mg/L
Date Analyzed 12/05/2005 0634
Date Prepared: 12/02/2005 0600
Page 6 of 12
Analytical Data
Job Number: 680-11010-1
Date Sampled: 11/28/2005 1600
Date Received: 11/30/2005 1020
RL Dil Method
0.0050 1.0 335.4
• DATA REPORTING QUALIFIERS
Client: ENSR International Job Number. 680-11010-1
Lab Section Qualifier Description
GC/MSVOA
u Analyte was not detected at or above the reporting limit.
General Chemistry
u Analyte was not detected at or above the reporting limit.
•
• STL Savannah
Page 7 of 12
•
•
Client: ENSR International
Surrogate Recovery Report
8260B Volatile Organic Compounds by GC/MS
Client Matrix: Water
Lab Sample ID
LCS 680-30354/4
MB 680-30354/5
680-11010-1
680-11010-2
Surrogate
Client Sample
LCS
MB
Effluent
Trip Blank
(BFB)
(DBFM)
(TOL)
4-Bromofluorobenzene
Dibromofluoromethane
Toluene-d8
STL Savannah
(BFB) (DBFM) (TOL)
(¾Rec) (¾Rec) (%Rec)
96 95 97
92 100 104
92 100 104
93 101 102
Acceptance Limits
77 -120
75-123
79 -122
Page 8 of 12
Quality Control Results
Job Number: 680-11010-1
•
•
•
Client: ENSR International
Method Blank -Batch: 680-30354
Lab Sample ID: MB 680-30354/5
Client Matrix: Water
Dilution: 1.0
Date Analyzed: 12/07/2005 1152
Date Prepared: 12/0712005 1152
Analyte
Chloromethane
Bromomethane
Vinyl chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1, 1-Dichloroethene
1, 1-Dichloroethane
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Chloroform
1,2-Dichloroethane
Methyl Ethyl Ketone
1, 1, 1-Trichloroethane
Carbon tetrachloride
Dichlorobromomethane
1, 1,2,2-T etrachloroethane
1,2-Dichloropropane
trans-1,3-Dichloropropene
T richloroethene
Chlorodibromomethane
1, 1,2-Trichloroethane
Benzene
cis-1,3-Dichloropropene
Bromoform
2-Hexanone
methyl isobutyl ketone
Tetrachloroethene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Xylenes, Total
Analysis Batch: 680-30354
Prep Batch: N/A
Units: ug/L
Result Oual
. 1.0 U
1.0 u
1.0 u
1.0 u
5.0 u
25 u
1.0 u
1.0 u
1.0 u
1.0 u
1.0 u
1.0 u
1.0 u
10 u
1.0 u
1.0 u
1.0 u
1.0 u
1.0 u
1.0 u
1.0 u
1.0 u
1.0 u
1.0 u
1.0 u
1.0 u
10 u
10 u
1.0 u
1.0 u
1.0 u
1.0 u
1.0 u
2.0 u
Quality Control Results
Job Number: 680-11010-1
Method: 8260B
Preparation: 5030B
Instrument ID: GC/MS Volatiles -

0

Lab File ID: oq1775.d
Initial WeighWolume: 5 ml
Final WeighWolume: 5 ml
RL
1.0
1.0
1.0
1.0
5.0
25
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
10
1.0
1.0
1.0
1.0
1.0
2.0
~-~r:!"-~ga_te _________________________ ---·-··--------~···-·-"·-· ........... __ %_R_e_c ________ ~·· .... --............... _____ Accepta~_ce Limits
Toluene-dB 104 79 -122
4-Bromofluorobenzene 92 77 -120
Dibromofluoromethane 100 75-123
Calculations are performed before rounding to avoid round-off errors in calculated results.
STL Savannah Page 9 of 12
•
•
Client: ENSR International
Laboratory Control Sample -Batch: 680-30354
Lab Sample ID: LCS 680-30354/4
Client Matrix: Water
Dilution: 1.0
Dale Analyzed: 12/0712005 1020
Date Prepared: 12/07/2005 1020
Analyte
Chloromethane
Bromomethane
Vinyl chloride
Chloroelhane
Methylene Chloride
Acetone
Carbon disulfide
1, 1-Dichloroethene
1, 1-Dichloroelhane
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Chloroform
1,2-Dichloroethane
Methyl Ethyl Ketone
1, 1, 1-Trichloroethane
Carbon tetrachloride
Dichlorobromomethane
1, 1,2,2-Tetrachloroelhane
1,2-Dichloropropane
trans-1,3-Dichloropropene
Trichloroethane
Chlorodibromomethane
1, 1,2-Trichloroethane
Benzene
cis-1,3-Dichloropropene
Bromoform
2-Hexanone
methyl isobutyl ketone
Tetrachloroethene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Xylenes, Total
Analysis Balch: 680-30354
Prep Balch: N/A
Units:ug/L
Spike Amount Result
---· ·---··---·-------. ·-----·-·· ········-·--·····--
50.0 38
50.0 60
50.0 41
50.0 43
50.0 44
100 80
50.0 39
50.0 43
50.0 45
50.0 50
50.0 47
50.0 49
50.0 48
100 89
50.0 50
50.0 52
50.0 48
50.0 50
50.0 48
50.0 48
50.0 47
50.0 50
50.0 47
50.0 46
50.0 49
50.0 48
100 100
100 90
50.0 53
50.0 48
50.0 52
50.0 52
50.0 49
150 150
Quality Control Results
Job Number: 680-11010-1
Method: 82608
Preparation: 50308
Instrument ID: GC/MS Volatiles -O
Lab File ID: oq1769.d
Initial WeighWolume: 5 ml
Final WeighWolume: 5 ml
%Rec. Limit Qual
·-·----··. ---·--·-,._. ...... _., _____ -·----------···--··~----·
76 5~ -i.3,3
120 21 -176
82 59 -136
86 40 -171
88 67 -128
80 20 -183
78 60 -130
86 64 -132
90 70 -127
99 69 -126
94 67 -130
99 74 -124
96 68 -130
89 51 -142
100 70 -132
104 64 -137
95 74 -128
100 71 -127
96 74 -123
97 75 -126
94 75 -122
101 75 -126
94 75 -122
92 74 -122
98 76 -126
96 64 -132
100 58 -139
90 62 -130
107 70-133
95 75 -122
104 75 -123
104 77 -123
98 75 -125
103 77 -121
Calculations are perfonned before rounding to avoid round-off errors in calculated results.
STL Savannah Page 10 of 12
•
•
•
Client: ENSR International
Method Blank • Batch: 680-29911
Lab Sample ID: MB 680-2991111-A
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
Water
1.0
1210512005 0624
12/02/2005 0600
Analysis Batch: 680-29914
Prep Batch: 680-29911
Units: mgll
Result aual
Quality Control Results
Job Number: 680-11010-1
Method: 335.4
Preparation: Distillation
Instrument ID: No Equipment Assigned
Lab File ID: NIA
Initial WeighWolume: 50 ml
Final WeighWolume: 50 ml
RL Analyte
Cyanide. Total
. '"" ··--·-·-·-· ....... ---•---"----·····-----·-•·· -----·-·-------------.. --.---·--·--·•·-···~·······--~-~--. .---•-··--···-·---·----.---·-0.0050 iJ
Laboratory Control/
Laboratory Control Duplicate Recovery Report -Batch: 680-29911
LCS Lab Sample ID: LCS 680-2991112-B
Client Matrix: Water
Dilution: 1.0
Date Analyzed: 1210512005 0625
Date Prepared: 12102/2005 0600
LCSD Lab Sample ID: LCSD 680-29911/3-A
Client Matrix: Water
Dilution: 1.0
Date Analyzed: 12/0512005 0626
Date Prepared: 12/02/2005 0600
Analyte
Cyanide, Total
Analysis Batch: 680-29914
Prep Batch: 680-29911
Units: mg/L
Analysis Batch: 680-29914
Prep Batch: 680-29911
Units:mgll
%Rec.
LCS LCSD Limit
103 101 90 -110
Method: 335.4
Preparation: Distillation
Instrument ID: No Equipment Assigned
Lab File ID: NIA
Initial WeighWolume:
Final WeighWolume:
50 ml
50 ml
Instrument ID: No Equipment Assigned
Lab File ID: NIA
Initial WeighWolume: 50 ml
Final WeighWolume: 50 ml
RPO RPO Limit LCS Qual LCSD Qual
2 20
Calculations are performed before rounding to avoid round-off errors in calculated results.
STL Savannah Page 11 of 12
•
TIME
/t.,_OC>
.....
• ANALYSIS REQUEST AND CHAIN OF CUSTODY RECORD 0 STLSavannah
5102 LaRoche Avenue
Savannah, GA 31404
Serial Number 6 2 7 91
Website: www.stl-inc.com
Phone: [phone]
Fax: (912! 352-0165 STL 0 Alternate Laboratory Name/location
Phone:
Fa11.:
•
PROJECT NO.
/ON<J-· 1
PROJECT LOCATION
!STATE) _!JC..
MATRIX
T'IPE
PAGE OF REQU!REO ANALYSIS
CONTRACT NO.
SAMPLE IDENTIFICATION NUMBER OF COtlTAINERS SUBMITTED
\
RELINQUISHED BY: !SIGNATURE! DATE TIME RELINQUISHED BY: ISIGNATUREI
RECEIVED BY: ISIGNATUREI DATE TIME RECEIVED BY: ISIGNATUREI
--LABORATORY USE ONLY°
CUSTODY. INTACT .
·,YES :0
-No:::c:,
CUSTODY . . STL SAVANNAH . LABORATORY. REMARKS SEAL NO. LOG NO; ·
301iol0 •
DATE TIME
DATE TIME
Sll8240-6801l2/021
•
December 2005 Analytical Data
•
•
•
•
ANALYTICAL REPORT
Job Number: 680-11871-1
Job Description: Channel Master
For:
ENSR International
70.i 1 Old Wake i=orrest Road
Raleigh, NC 27616
Attention: Mr. Gerald Hornaday
Kathryn Smith
Project Manager I
[e-mail]
01/04/2006
The test results in this report meet all NELAP requirements for parameters for which accreditation is required or available. Any
, exceptions to NELAP requirements are noted in this report. Pursuant to NELAP, this report may not be reproduced, except in full,
· without the written approval of the laboratory. All questions regarding this test report should be directed to the STL Project Manager
who sianed this test reoort .
• Severn Trent Laboratories, Inc.
STL Savannah 5102 LaRoche Avenue, Savannah, GA 31404
Tel [phone] Fax [phone] www.stl-inc.com
Page 1 of 12
• Client: ENSR International
Description
Matrix: Water
Volatile Organic Compounds by GC/MS
Purge-and-Trap
Cyanide, Total (Semi-Automated Colorimetry)
Distillation/Cyanide
LAB REFERENCES:
STL-SAV = STL-Savannah
METHOD REFERENCES:
METHOD SUMMARY
Lab Location Method
STL-SAV
STL-SAV
STL-SAV
STL-SAV
SW846 82606
MCAWVV 335.4
Job Number: 680-11871-1
Preparation Method
SW846 5030B
Distillation
MCAWW-"Methods For Chemical Analysis Of Water And Wastes", EPA-600/4-79-020, March 1983 And
Subsequent Revisions .
•
SW846 -"Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986
And Its Updates .
•
STL Savannah
Page 2 of 12
• Client: ENSR International
•
Lab Sample ID
680-11871-1
680-11871-2TB
STL Savannah
Client Sample ID
Effluent
Trip Blank
SAMPLE SUMMARY
Client Matrix
Water
Water
Page 3 of 12
Date/Time
Sampled
12/19/2005 1235
12/19/2005 0000
Job Number: 680-11871-1
Date/Time
Received
12/20/2005 0949
12/20/2005 0949
.Client: ENSR International
Client Sample ID: Effluent
Lab Sample ID:
Client Matrix:
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
680-11871-1
Water
8260B
5030B
1.0
8260B Volatile Organic Compounds by GC/MS
Analysis Batch: 680-32563
12/29/2005 1636
12/29/2005 1636
Analytical Data
Job Number: 680-11871-1
Date Sampled: 12/19/2005 1235
Date Received: 12/20/2005 0949
Instrument ID: GC/MS Volatiles -O
Lab File ID: 03285.d
Initial WeighWol ume: 5 ml
Final WeighWolume: 5 ml
Analyte ___ Result (ug/L) __ Qualifier RL
Chloromethane
Bromomethane
Vinyl chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1, 1-Dichloroethene
1, 1-Dichloroethane
cis-1,2-Dichloroethene
•rans-1,2-Dichloroethene
Chloroform
1,2-Dichloroethane
Methyl Ethyl Ketone
1, 1, 1-Trichloroethane
Carbon tetrachloride
Dichlorobromomethane
1, 1,2,2-T etrachloroethane
1,2-Dichloropropane
trans-1,3-Dichloropropene
Trichloroethene
Chlorodibrornomethane
1, 1,2-Trichloroethane
Benzene
cis-1, 3-Dichloropropene
Bromofonm
2-Hexanone
methyl isobutyl ketone
Tetrachloroethene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Xylenes, Total
Surrogate
Toluene-<l8
4-Bromofluorobenzene
• Dibromofluoromethane
STL Savannah
-·-··--··· 1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
5.0 u 5.0
25 u 25
1.0 u 1.0
1.0 u . 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
10 u 10
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
10 u 10
10 u 10
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
2.0 u 2.0
%Rec Acceptance Limits
99 79 -122
90 77 -120
96 75 -123
Page 4 of 12
• Client: ENSR International
Client Sample ID: Trip Blank
Lab Sample ID:
Client Matrix:
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
680-11871-2TB
Water
82608
5030B
1.0
82608 Volatile Organic Compounds by GC/MS
Analysis Batch: 680-32563
12/2912005 1605
12/2912005 1605
Analytical Data
Job Number: 680-11871-1
Date Sampled: 12/19/2005 0000
Date Received: 12/20/2005 0949
Instrument ID: GC/MS Volatiles -O
Lab File ID: 03283.d
Initial WeighWolume: 5 ml
Final WeighWolume: 5 ml
Analyte Result lug/L) Qualifier RL
Chloromethane
Bromomethane
Vinyl chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1, 1-Dichloroethene
1, 1-Dichloroethane
•
is-1,2-Dichloroethene
rans-1, 2-Dichloroethene
Chloroform
1,2-Dichloroethane
Methyl Ethyl Ketone
1, 1, 1-Trichloroethane
Carbon tetrachloride
Dichlorobromomethane
1, 1, 2, 2-T etrachloroethane
1,2-Dichloropropane
trans-1,3-Dichloropropene
T richloroethene
Chlorodibromomethane
1, 1,2-Trichloroethane
Benzene
cis-1,:,-Dichloropropene
Bromoform
2-Hexanone
methyl isobutyl ketone
Tetrachloroethene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Xylenes, Total
Surrogate
Toluene-dB
4-Bromofluorobenzene
• Dibromofluoromethane
STL Savannah
1.0
1.0
1.0
1.0
5.0
25
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
10
1.0
1.0
1.0
1.0
4.0
2.0
%Rec
103
95
96
Page 5 of 12
u 1.0
u 1.0
u 1.0
u 1.0
u 5.0
u 25
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 10
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 10
u 10
u 1.0
u 1.0
u 1.0
u 1.0
1.0
u 2.0
Acceptance Limits
79 -122
77 -120
75 -123
• Client: ENSR International
Client Sample ID:
Lab Sample ID:
Client Matrix:
Analyte
Cyanide, Total
•
•
STL Savannah
Effluent
680-11871-1
Water
General Chemistry
Result Qual Units
0.0070 mg/L
Anly Batch: 680-32013 Date Analyzed 12/23/2005 0626
Prep Batch: 680-32010 Date Prepared: 12/22/2005 0500
Page 6 of 12
Analytical Data
Job Number: 680-11871-1
Date Sampled:
Date Received:
RL
0.0050
12/19/2005 1235
12/20/2005 0949
Oil Method
1.0 335.4
•
• DATA REPORTING QUALIFIERS
Client: ENSR International Job Number: 680-11871-1
Lab Section Qualifier Description
GC/MSVOA
u Analyte was not detected at or above the reporting limit.
• LCS, LCSD, MS, MSD, MD, or Surrogate exceeds the control
limits ·
General Chemistry
u Analyte was not detected at or above the reporting limit.
•
•
STL Savannah
Page 7 of 12
.lient: ENSR International
Surrogate Recovery Report
82608 Volatile Organic Compounds by GC/MS
Client Matrix: Water
Lab Sample ID
LCS 680-32563/3
MB 680-32563/4
680-11871-1
680-11871-2TB
Surrogate
Client Sample
LCS
MB
Effluent
Trip Blank
(BFB)
(DBFM)
(TOL)
4-Bromofluorobenzene
Dibromofluoromethane
Toluene-dB
STL Savannah
(BFB) (DBFM) (TOL)
(%Rec) (%Rec) (%Rec)
95 90 97
92 89 101
90 96 99
95 96 103
Acceptance Limits
77 -120
75 -123
79 -122
Page 8 of 12
Quality Control Results
Job Number: 680-11871-1
• Client: ENSR International
Method Blank -Batch: 680-32563
Lab Sample ID: MB 680-32563/4
Client Matrix: Water
Dilution: 1.0
Date Analyzed: 12/29/2005 1213
Date Prepared: 12/2912005 1213
Analyte
Chloromethane
Bromomethane
Vinyl chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1, 1-Dichloroethene
1, 1-Dichloroethane
cis-1,2-Dichloroethene
•
trans-1,2-Dichloroethene
Chloroform
1,2-Dichloroethane
Methyl Ethyl Ketone
•
1, 1, 1-Trichloroethane
Carbon tetrachloride
Dichlorobromomethane
1, 1,2,2-Tetrachloroethane
1,2-Dichloropropane
trans-1,3-Dichloropropene
Trichloroethene
Chlorodibromomethane
1, 1,2-Trichloroethane
Benzene
cis-1,3-Dichloropropene
Bromoform
2-Hexanone
methyl isobutyl ketone
Tetrachloroethene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Xylenes, Total
Surrogate
Toluene-<l8
4-Bromofluorobenzene
Dibromofluoromethane
Analysis Batch: 680-32563
Prep Batch: N/A
Units: ug/L
Result
1.0
1.0
1.0
1.0
5.0
25
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
10
1.0
1.0
1.0
1.0
1.0
2.0
%Rec
101
92
89
Oual
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
Calculations are pertormed before rounding to avoid round-off errors in calculated results.
STL Savannah Page 9 of 12
Quality Control Results
Job Number: 680-11871-1
Method: 8260B
Preparation: 5030B
Instrument ID: GC/MS Volatiles -0
Lab File ID: oq011.d
Initial WeighWolume: 5 ml
Final WeighWolume: 5 ml
RL
1.0
1.0
1.0
1.0
5.0
25
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
10
1.0
1.0
1.0
1.0
1.0
2.0
Acceptance Limits
79 -122
77 -120
75 -123
• Client: ENSR International
Laboratory Control Sample -Batch: 680-32563
Lab Sample ID: LCS 680-32563/3 Analysis Batch:
Client Matrix: Water Prep Batch: N/A
Dilution: 1.0 Units: ug/L
Date Analyzed: 12/29/2005 1040
Date Prepared: 12/29/2005 1040
Analyte Spike Amount
Chloromethane 50.0
Bromomethane 50.0
Vinyl chloride 50.0
Chloroethane 50.0
Methylene Chloride 50.0
Acetone 100
Carbon disulfide 50.0
1, 1-Dichloroethene 50.0
1, 1-Dichloroethane 50.0
cis-1,2-Dichloroethene 50.0
• trans-1,2-Dichloroethene 50.0
Chloroform 50.0
1,2-Dichloroethane 50.0
Methyl Ethyl Ketone 100
1, 1, 1-Trichloroethane 50.0
Carbon tetrachloride 50.0
Dichlorobromomethane 50.0
1, 1,2,2-Tetrachloroethane 50.0
1,2-Dichloropropane 50.0
tra ns-1, 3-0ichloropropene 50.0
Trichloroethene 50.0
Chlorodibromomethane 50.0
1, 1,2-Trichloroethane 50.0
Benzene 50.0
cis-1,3-Dichloropropene 50.0
Bromoform 50.0
2-Hexanone 100
methyl isobutyl ketone 100
Tetrachloroethene 50.0
Toluene 50.0
Chlorobenzene 50.0
Ethylbenzene 50.0
Styrene 50.0
Xylenes, Total 150
•
680-32563
Result
36
12
39
45
43
91
43
44
44
42
42
44
58
100
55
55
58
59
53
59
50
60
58
51
54
60
110
130
45
47
45
47
55
140
Quality Control Results
Job Number: 680-11871-1
Method: 82608
Preparatio11: 50308
Instrument ID: GC/MS Volatiles -

O

Lab File ID: oq005.d
Initial Weight/Volume: 5 ml
Final Weight/Volume: 5 ml
% Rec. Limit Oual
76 51 -133
24 21 -176
77 59 -136
90 40 -171
86 67 -128
91 20 -183
85 60 -130
88 64 -132
88 70 -127
84 69 -126
84 67 -130
87 74 -124
115 68 -130
100 51 -142
109 70 -132
110 64 -137
116 74 -128
119 71 -127
106 74 -123
119 75 -126
100 75 -122
121 75 -126
117 75 -122
102 74 -122
, 108 76 -126
120 64 -132
109 58 -139
131 62 -130 •
90 70-133
94 75 -122
91 75 -123
94 77 -123
109 75 -125
95 77 -121
Calculations are performed before rounding to avoid round-off errors in calculated results.
STL Savannah Page 10 of 12
• Client: ENSR International
Method Blank -Batch: 680-32010
Lab Sample ID: MB 680-32010I1-A
Client Matrix: Water
Dilution: 1.0
Date Analyzed: 1212312005 0611
Date Prepared: 1212212005 0500
Analyte
Cyanide, Total
Laboratory Control/
Analysis Batch: 680-32013
Prep Batch: 680-32010
Units: mg/L
Result
0.0050
Laboratory Control Duplicate Recovery Report -Batch: 680-32010
LCS Lab Sample ID: LCS 680-3201012-A
Client Matrix:
Dilution:
Water
1.0
•
Date Analyzed:
Date Prepared:
12/2312005 0612
1212212005 0500
•
LCSD Lab Sample ID: LCSD 680-32010/3-A
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
Analyte
Cyanide, Total
Water
1.0
12/2312005 0613
1212212005 0500
Analysis Batch: 680-32013
Prep Batch: 680-32010
Units: mg/L
Analysis Batch: 680-32013
Prep Batch: 680-32010
Units: mg/L
% Rec.
LCS LCSD Limit
105 103 90-110
Qual
u
Quality Control Results
Job Number: 680-11871-1
Method: 335.4
Preparation: Distillation
Instrument ID: No Equipment Assigned
Lab File ID: NIA
Initial WeighWolume: 50 ml
Final WeighWolume: 50 ml
RL
0.0050
Method: 335.4
Preparation: Distillation
Instrument ID: No Equipment Assigned
Lab File ID: NIA
Initial Weight/Volume:
Final Weight/Volume:
Instrument ID:
50 ml
50 ml
Lab File ID:
No Equipment Assigned
NIA
RPD
3
Initial Weight/Volume: 50 ml
Final Weight/Volume: 50 ml
RPD Limit LCS Qual LCSD Qual
20
Calculations are performed before rounding to avoid round-off errors in calculated results.
STL Savannah Page 11 of 12
SEVERN
TRENT
DATE
RELINQUISHED BY: fSIGNATUREl
ANALYSIS REQUEST AND CHAIN OF CUSTODY RECORD
STL
DATE TIME
PROJECT LOCATION
{STATE) _A)[_
CONTRACT NO.
MATRIX
T'iPE
RELINQUISHED BY: fSIGNATIJREl
Serial Number -6 2 7 9 2
~ STL Savannah
5102 LaRoche Avenue
Savannah, GA 31404
0 Alter_nate Laboratory Name/location
REQU:RED ANALYSIS
NUMBER OF CONTAINERS SUBMITTED
Website: www.stl-inc.com
Phone: [phone]
Fax: [phone]
Phone:
FaX:
PAGE OF
STANDARD REPORT
DELIVERY (JD
DATE DUE ____ _
EXPEDITED REPORT
DELIVERY 0
{SURCHARGE)
DATE DUE
NUMBER OF COOLERS SUBMITTED
PER SHIPMENT:.
REMARKS
DATE TIME RELINQUISHED BY: fSIGNATUREI DATE TIME
RECEIVED BY: fSIGNATUREl DATE TIME
Sll8240-680 fl2/02l
•
January 2006 Analytical Data
•
•
•
•
ANALYTICAL REPORT
Job Number: 680-13046-1
Job Description: Channel Master
For:
ENSR International
7041 Old Wake Forrest Road
Ral,.igh, NC 27G16
Attention: Mr. Gerald Hornaday
Kathryn Smith
Project Manager I
[e-mail]
02/13/2006
The test results in this report meet all NE LAP requirements for parameters for which accreditation is required or available. Any
exceptions to NELAP requirements are noted in this report. Pursuant to NELAP, this report may not be reproduced, except in full,
without the written approval of the laboratory. All questions regarding this test report should be directed to the STL Project Manager
who sianed this test reoort .
•
Severn Trent Laboratories, Inc.
STL Savannah 5102 LaRoche Avenue, Savannah, GA 31404
Tel [phone] Fax [phone] www.stl-inc.com
Page 1 of 12
'ient: ENSR International
Description
Matrix: Water
Volatile Organic Compounds by GC/MS
Purge-and-Trap
Cyanide, Total (Semi-Automated Colorimetry)
Distillation/Cyanide
LAB R:CFERENCES:
STL-SAV = STL-Savannah
METHOD REFERENCES:
METHOD SUMMARY
Lab Location Method
STL-SAV
STL-SAV
SW846 8260B
Job Number: 680-13046-1
Preparation Method
SW846 5030B
STL-SAV
STL-SAV
MCAWN 335.4
Distillation
MCAWN -"Methods For Chemical Analysis Of Water And Wastes", EPA-600/4-79-020, March 1983 And
Subsequent Revisions .
•
W846 -''Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986
nd Its Updates. .
•
STL Savannah
Page 2 of 12
tlient: ENSR International
Lab Sample ID
680-13046-1
680-13046-2TB
•
STL Savannah
Client Sample ID
EFF-1
Trip Blank
SAMPLE SUMMARY
Client Matrix
Water
Water
Page 3 of 12
Date/Time
Sampled
01/27/2006 1300
01/27/2006 0000
Job Number: 680-13046-1
Date/Time
Received
01/28/2006 0920
01/28/2006 0920
.ient: ENSR International
Client Sample ID: EFF-1
Lab Sample ID:
Client Matrix:
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
680-13046-1
Water
8260B
5030B
1.0
82608 Volatile Organic Compounds by GC/MS
Analysis Batch: 680-35905
02/03/2006 1545
02/03/2006 1545
Analytical Data
Job Number: 680-13046-1
Date Sampled: 01/27/2006 1300
Date Received: 01/28/2006 0920
Instrument ID: GC/MS Volatiles -

P

Lab File ID: p6452.d
Initial WeighWolume: 5 ml
Final WeighWolume: 5 ml
Analyte Result (ug/L) Qualifier RL
Chloromethane
Bromomethane
Vinyl chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1, 1-Dichloroethene
1, 1-Dichloroethane
cis-1,2-Dichloroethene
Ans-1,2-Dichloroethene
~loroform
1,2-Dichloroethane
Methyl Ethyl Ketone
1, 1, 1-Trichloroethane
Carbon tetrachloride
Dichlorobromomethane
1, 1,2,2-T etrachloroethane
1,2-Dichloropropane
trans-1,3-Dichloropropene
T richloroethene
Chlorodibromomethane
1, 1 ,2-Trichloroethane
Benzene
cis-1,3-Dichloropropene
Bromoform
2-Hexanone
methyl isobutyl ketone
T etrachloroethene
· Toluene
Chlorobenzene
Ethylbenzene
Styrene
Xylenes, Total
Surrogate
Toluene-dB
~-Bromoflu<:>robenzene
9)ibromofiuoromethane
STL Savannah
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
5.0 u 5.0
25 u 25
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
10 u 10
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
10 u 10
10 u 10
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
2.0 u 2.0
%Rec Acceptance Limits
105 79 -122
98 77 -120
100 75 -123
Page 4 of 12
.lient: ENSR International
Client Sample ID: Trip Blank
Lab Sample ID:
Client Matrix:
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
680-13046-2TB
Water
82608
50308
1.0
82608 Volatile Organic Compounds by GC/MS
Analysis Batch: 680-35905
02/03/2006 1613
02/0312006 1613
Analytical Data
Job Number: 680-13046-1
Date Sampled: 01/2712006 0000
Date Received: 01/2812006 0920
Instrument ID: GC/MS Volatiles - P
Lab File ID: p6454.d
Initial WeighWolume: 5 ml
Final WeighWolume: 5 ml
Analyte Result (ug/L) Qualifier RL
Chloromethane
Bromomethane
Vinyl chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1, 1-Dichloroethene
1, 1-Dichloroethane
·s-1,2-Dichloroethene
ns-1,2-Dichloroethene
hloroform
1,2-Dichloroethane
Methyl Ethyl Ketone
1, 1, 1-Trichloroethane
Carbon tetrachloride
Dichlorobromomethane
1, 1,2,2-T etrachloroethane
1,2-Dichloropropane
trans-1,3-Dichloropropene
Trichloroethene
Chlorodibromomethane
1, 1,2-Trichloroethane
Benzene
cis-1,3-Dichloropropene
Bromoform
2-Hexanone
methyl isobutyl ketone
T etrachloroethene
Toluene
Chlorobenzene
Ethyl benzene
Styrene
Xylenes, Total
Surrogate
Toluene-dB
•
-Bromofluorobenzene
ibromofluoromethane
STL Savannah
,.o
1.0
1.0
1.0
5.0
25
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
10
1.0
1.0
1.0
1.0
5.5
2.0
%Rec
102
95
101
Page 5 of 12
u 1.0
u 1.0
u 1.0
u 1.0
u 5.0
u 25
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 10
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 10
u 10
u 1.0
u 1.0
u 1.0
u 1.0
1.0
u 2.0
Acceptance Limits
79-122
77 -120
75 -123
.ient: ENSR International
Client Sample ID: EFF-1
Lab Sample ID:
Client Matrix:
Analyte
Cyanide, Total
•
•
STL Savannah
680-13046-1
Water
Result
0.0058
Anly Batch: 680-35034
Prep Batch: 680-35032
General Chemistry
Qual Units
mg/L
Date Analyzed 01/31/2006 1218
Date Prepared: 01/31/2006 0700
Page 6 of 12
Analytical Data
Job Number: 680-13046-1
Date Sampled: 01/27/2006 1300
Date Received: 01/28/2006 0920
RL Dil Method
0.0050 1.0 335.4
• DATA REPORTING QUALIFIERS
Client: ENSR International Job Number: 680-13046-1
Lab Section Qualifier Description
GC/MSVOA
u Analyte was not detected at or above the reporting limit.
General Chemistry
u Analyte was not detected at or above the reporting limit.
•
STL Savannah
Page 7 of 12
.nt: ENSR International
Surrogate Recovery Report
82608 Volatile Organic Compounds by GC/MS
Client Matrix: Water
Lab Sample ID
LCS 680-35905110
MB 680-35905/11
680-13046-1
680-13046-2TB
Surrogate
Client Sample
LCS
MB
EFF-1
Trip Blank
(BFB)
(DBFM)
(TOL)
4-Bromofluorobenzene
Dibromofluoromethane
Toluene-dB
•
•
STL Savannah
(BFB) (DBFM) (TOL)
(%Rec) (%Rec) (%Rec)
100 107 106
98 104 101
98 100 105
95 101 102
Acceptance Limits
77 -120
75 -123
79 -122
Page 8 of 12
Quality Control Results
Job Number: 680-13046-1
.lient: ENSR International
Method Blank -Batch: 680-35905
Lab Sample ID: MB 680-35905/11
Client Matrix: Water
Dilution: 1.0
Date Analyzed: 02/03/2006 1311
Date Prepared: 02/03/2006 1311
Analyte
GhloromP.thBne
Bromomethane
Vinyl chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1, 1-Dichloroethene
1, 1-Dichloroethane
cis-1,2-Dichloroethene
~ns-1,2-Dichloroethene
lorolorm
,2-Dichloroethane
Methyl Ethyl Ketone
1, 1, 1-Trichloroethane
Carbon tetrachloride
Dichlorobromomethane
1, 1,2,2-T etrachloroethane
1,2-Dichloropropane
trans-1,3-Dichloropropene
Trichloroethane
Chlorodibromomethane
1, 1,2-Trichloroethane
Benzene
cis-1,3-Dichloropropene
Bromolorm
2-Hexanone
methyl isobutyl ketone
T etrachloroethene
Toluene
Chlorobenzene
Ethyl benzene
Styrene
Xylenes, Total
Surrogate
Toluene-dB
.-Bromofluorobenzene
ibromofluoromethane
Analysis Batch: 680-35905
Prep Batch: NIA
Units: ug/L
Result
1.0
1.0
1.0
1.0
5.0
25
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
10
1.0
1.0
1.0
1.0
1.0
2.0
%Rec
101
98
104
Qual
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
Calculations are performed before rounding to avoid round-off errors in calculated results.
STL Savannah Page 9 of 12
Quality Control Results
Job Number: 680-13046-1
Method: 8260B
Preparation: 5030B
Instrument ID: GC/MS Volatiles - P
Lab File ID: pq696.d
Initial WeighWolume: 5 ml
Final WeighWolume: 5 ml
RL
1.0
1.0
1.0
1.0
5.0
25
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
10
1.0
1.0
1.0
1.0
1.0
2.0
Acceptance Limits
79 -122
77 -120
75 -123
.lient: ENSR International
Laboratory Control Sample -Batch: 680-35905
Lab Sample ID: LCS 680-35905/10
Client Matrix: Water
Dilution: 1.0
Date Analyzed: 02/0312006 1118
Date Prepared: 02/0312006 1118
Analyte
ColcmmethBae
Bromomethane
Vinyl chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1, 1-Dichloroethene
1, 1-Dichloroethane
cis-1,2-Dichloroethene
-ans-1,2-Dichloroethene
hloroform
,2-Dichloroethane
Methyl Ethyl Ketone
1, 1, 1-Trichloroethane
Carbon tetrachloride
Dichlorobromomethane
1, 1,2,2-T etrachloroethane
1,2-Dichloropropane
trans-1,3-Dichloropropene
Trichloroethene
Chlorodibromomethane
1, 1,2-Trichloroethane
Benzene
cis-1,3-Dichloropropene
Bromoform
2-Hexanone
methyl isobutyl ketone
T etrachloroethene
Toluene
Chlorobenzene
Ethyl benzene
Styrene
Xylenes, Total
•
Analysis Batch: 680-35905
Prep Batch: NIA
Units: ugll
Spike Amount Result
50.0 63
50.0 69
50.0 55
50.0 59
50.0 52
100 80
50.0 57
50.0 53
50.0 56
50.0 53
50.0 54
50.0 55
50.0 50
100 100
50.0 56
50.0 53
50.0 50
50.0 48
50.0 51
50.0 52
50.0 50
50.0 44
50.0 52
50.0 51
50.0 51
50.0 48
100 95
100 100
50.0 50
50.0 53
50.0 48
50.0 51
50.0 50
150 150
Quality Control Results
Job Number: 680-13046-1
Method: 8260B
Preparation: 5030B
Instrument ID: GC/MS Volatiles - P
Lab File ID: pq688.d
Initial WeighWolume: 5 ml
Final WeighWolume: 5 ml
% Rec. Limit Qual
"!25 51 -133
138 21 -176
111 59-136
119 40 -171
104 67 -128
80 20 -183
113 60-130
105 64-132
113 70 -127
107 69 -126
107 67 -130
109 74 -124
101 68 -130
100 51 -142
112 70-132
106 64 -137
101 74-128
96 71 -127
102 74 -123
104 75 -126
100 75 -122
87 75 -126
104 75 -122
101 74 -122
102 76-126
95 64 -132
95 58 -139
100 62 -130
101 70 -133
106 75 -122
96 75 -123
101 77 -123
100 75 -125
101 77 -121
Calculations are performed before rounding to avoid round-off errors in calculated results.
STL Savannah Page 10 of 12
.ent: ENSR International
Method Blank -Batch: 680-35032
Lab Sample ID: MB 680-35032/1-A
Client Matrix: Water
Dilution: 1.0
Date Analyzed: 01/31/2006 1206
Date Prepared: 01/31/2006 0700
Analyte
Cyanide, Total
Laboratory Control/
Analysis Batch: 680-35034
Prep Batch: 680-35032
Units: mg/L
Result
Laboratory Control Duplicate Recovery Report -Batch: 680-35032
LCS Lab Sample ID: LCS 680-35032/2-A
Client Matrix:
Dilution:
~ate Analyzed: W'te Prepared:
Water
1.0
01/31/2006 1207
01/31/2006 0700
LCSD Lab Sample ID: LCSD 680-35032/3-A
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
Analyte
Cyanide, Total
•
Water
1.0
01/31/2006 1208
01/31/2006 0700
Analysis Batch: 680-35034
Prep Batch: 680-35032
Units: mg/L
Analysis Batch: 680-35034
Prep Batch: 680-35032
Units:mg/L
% Rec.
LCS LCSD Limit
96 96 90 -110
Qual
u
RPO
Calculations are performed before rounding to avoid round-off errors in calculated results.
STL Savannah Page 11 of 12
Quality Control Results
Job Number: 680-13046-1
Method: 335.4
Preparation: Distillation
Instrument ID: No Equipment Assigned
Lab File ID: N/A
Initial WeighWolume: 50 ml
Final WeighWolume: 50 ml
RL
0.0050
Method: 335.4
Preparation: Distillation
Instrument ID: No Equipment Assigned
Lab File ID: N/A
Initial WeighWolume: 50 ml
Final WeighWolume: 50 ml
Instrument ID:
Lab File ID:
No Equipment Assigned
N/A
Initial WeighWolume: 50 ml
Final WeighWolume: 50 ml
RPO Limit LCS Oual LCSD Qual
20
SEVERN
TRENT
ANALYSIS REQUEST AND CHAIN OF CUSTODY REC
STL
-I
TIME
'30')
TIME
MATRIX
TYPE
RELINQUISHED BY: ISIGNATLllEI
RECEIVED BY: !SIGNATURE!
0 STL Savannah
5102 LaRoche Avenue
Savannah, GA 31404
Serial Number" 6 2 7 9 4 ■
Website: www.stl-inc.c~.-------
Phone: [phone]
Fax: [phone]
0 Alternate Laboratory Name/location
Phone:
Fax:
REQUIRED ANALYSIS PAGE
NUMBER OF CONTAINERS SUBMITTED
\
DATE TIME RELINQUISHED BY: !SIGNATURE!
DATE TIME RECENED BY: !SIGNATURE!
OF
REMARKS
DATE TIME
DATE TIME
N -
N
Q)
ro a..
•
•
•
ENSR International
7041 Old Wake Forest Road, Suite 103
Raleigh, NC 27616-3013
[phone]
FAX [phone]
www.ensr.com
November 7, 2005
Mr. Larry Thomas
City Engineer
City of Oxford
P.O. Box 1307
Oxford, North Carolina 27565
{D)~©liOWrn~
ITTl NOV 0, 9 2005 \1ll
SUPERFUND SECTION
RE: Industrial Users Report for October 2005
JFD Electronics/Channel Master NPL Site, Oxford, North Carolina.
Dear Mr. Thomas:
On behalf of The Unimax Corporation and Avnet, Inc., ENSR Consulting and Engineering (NC), Inc.
is submitting the Quarterly Industrial User Permit report for the months of August, September and
October 2005. This report is prepared in accordance with permit requirements for the discharge of
treated groundwater at the above referenced site .
If you have any questions, please contact us at [phone].
Sincerely,
ENSR Consulting and Engineering (NC), Inc.
/4~·~ Gerald Y.Hornadati £.
Project Engineer
Enclosure
William H. Doucette, Jr., Ph.D.
Senior Program Manager
cc: Brian Kempner, The Unimax Corporation (w/o lab attachment)
S. Alan Lazar, Avnet, Inc. (w/o lab attachment)
Steve Earp, Smith Helms Muliss & Moore (w/o lab attachment)
David Mattison, NCDENR Superfund
Ken Lucas, USEPA Superfund
Nanjun Shelly, P.E., ENSR
File
Celebrating 30 Years of Excellence in Environmental SeNices
•
•
INDUSTRIAL USER REPORTING FORM
I.U. PERMIT NO: _ _,,G""0"'-01,...._ ____ DISCHARGE NO: ___ -"'00"""1'-------
MONTHS: August. September, and October YEAR: 2005
I.U. NAME: JFD Electronics/Channel Master CLASS: COUNTY: Granville
OPERA TOR IN RESPONSIBLE CHARGE (ORC): ENSR Consulting & Engineering (NC). Inc.
LABORATORY PERFORMING ANALYSIS: STL-Savannah Laboratories
PERSON(S) COLLECTING SAMPLES: Gerald Hornaday, P.E. (ENSR). Seth Ryan (ENSR)
CHECK BLOCK IF ORC HAS CHANGED 0
SEND REPORT TO: City Engineer
City of Oxford
P.O. Box 1307
Oxford, NC 27565
Facility Status: (Please check one of the following)
All monthly averages and/or other limitations do meet permit monitoring requirements. ~
(Compliant)
All monthly averages and/or other limitations do not meet permit monitoring requirements. 0
(Noncompliant)
If the facility is noncompliant, please comment on corrective actions being taken in respect to
equipment, operation, maintenance, etc. and a time table for improvements to be made.
(Attach additional sheets if necessary)
I certify that this Report is accurate and
complete to the best ofmy knowledge:
\J~tl~)fi.1-
Signature of Permittee Representative
William H. Doucette, Jr., Ph.D.
Date:
•
•
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TABLE 1. GROUNDWATER REMEDIATION SYSTEM DISCHARGE MONITORING REPORT, CITY OF OXFORD, NORTH CAROLINA
1.U. PERMIT NO:
DISCHARGE NO:
MONTHS:
YEAR:
I.U. NAME:
COUNTY:
OPERATOR IN RESPONSIBLE CHARGE {ORC):
LABORATORY PERFORMING ANALYSIS:
PERSON($) COLLECTING SAMPLES:
PARAMETER
Dally Average Flow (MGO)
Tetrachloroethylene
1, 1-Dlchloroethane
cls-1,2 Olchloroethene
Chlorobenzene
Toluene
1,1-Dlchloroethylene
trans-1,2 Dlchloroethylene
Trichloroethene
Vlnyl Chloride
Cyanide (total)
pH
Temperature
Monitoring requirement only.
MGD Million Gallons per day.
µg/L Mia-ograms per Iller.
mg/l Milligrams per liter.
SU Standard Units.
oC Degrees Centigrade.
G001
001
August, September, and October
2005
JFD Electronics/Channel Master NPL Sile
Granville
ENSR Consulting & Engineering (NC), Inc.
STL Savannah Laboratories
Gerald Hornaday, P.E. (ENSR); Seth Ryan (ENSR)
PERMIT LIMITS UNITS SAMPLE
Oalty Maximum TYPE
0.040 MGD Meter
µg/L Grab
µg/L Grab
µg/L Grab
µg/L Grab
µg/L Grab
µg/L Grab
µg/L Grab
µg/L Grab
µg/L Grab
0.05 mg/L Grab
5.0to 10.0 SU Grab
40 •c Grab
< Compound was not detected above the quantitation limit .
G:\Env\JFOCHANNINC0202.170\Clty ol O:dord\lURT1ble Nov 2005\Table 1\11ll/2005
LAB MONTHLY MEASUREMENT
METHOD DATES
08/18/05 09121/05 10120/05
Field 0.023 0.023 0.021
8260 <1.0 <1.0 <1.0
8260 <1.0 <1.0 <1.0
8260 <1,0 <1.0 <1.0
8260 <1.0 <1.0 <1.0
8260 <1.0 <1.0 <1.0
8260 <1.0 <1.0 <1.0
8260 <1,0 <1.0 <1.0
8260 <1,0 <1.0 <1.0
8260 <1.0 <1.0 <1.0
335.2 0.0064 0,0066 <0.0050
Field 8.33 7.33 7.90
Field 22.6 24.7 20.3
•
•
• Severn Trent Laboratories, Inc.
ANALYTICAL REPORT
Job Number: 680-7231-1
Job Description: Channel Master
For:
ENSR International
7041 Old Wake Forrest Road
Raleigh, NC 27616
Attention: Mr. Gerald Hornaday
Kathryn Smith
Project Manager I
08/25/2005
STL Savannah 5102 LaRoche Avenue, Savannah, GA 31404
Tel [phone] Fax [phone] www.stl-inc.com
Page 1 of 10
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Client: ENSR International
Description
Matrix: Water
Volatile Organic Compounds by GC/MS
Purge-and-Trap
Cyanide, Total (Sem~Automated Colorimetry)
Distillation/Cyanide
LAB REFERENCES:
STL-SAV = STL-Savannah
METHOD REFERENCES:
METHOD SUMMARY
Lab Location Method
STL-SAV
STL-SAV
STL-SAV
STL-SAV
SW846 8260B
MCAWN 335.4
Job Number. 680-7231-1
Preparation Method
SW846 5030B
Distillation
MCAWN. "Methods For Chemical Analysis Of Water And Wastes", EPA-600/4-79-020, March 1983 And
Subsequent Revisions. ,
SW846. "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986
And Its Updates .
STL Savannah
Page 2 of 10
• Client: ENSR International
Lab Sample ID Client Sample ID
680-7231-1 Effluent
•
• STL Savannah
SAMPLE SUMMARY
Client Matrix
Water
Page 3 of 10
Date/Time
Sampled
08/18/2005 1615
Job Number: 680-7231-1
Date/Time
Received
08/19/2005 0908
•
•
•
Client: ENSR International
Client Sample ID:
. Lab Sample ID:
Client Matrix:
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
Effluent
680-7231-1
Water
82608 Volatile Organic Compounds by GC/MS
8260B
5030B
1.0
08/24/2005 0414
08/24/2005 0414
Analysis Batch: 680-20022
Analytical Data
Job Number: 680-7231-1
Date Sampled: 08/18/2005 1615
Date Received: 08/19/2005 0908
Instrument ID: GC/MS Volatiles -A
Lab File ID: a 7850.d
Initial WeighWolume: 5 ml
Final WeighWolume: 5 ml
A-"n-'a'-lyt'-'e"-----------------'-R:.:;e.;:.su;;..l.:..,t (ug/L) -···-· Qualifier
1.0
1.0
1.0
1.0
5.0
25
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
10
1.0
1.0
1.0
1.0
1.0
2.0
Chloromethane
Bromomethane
Vinyl chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1, 1-Dichloroethene
1, 1-Dichloroethane
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Chloroform
1,2-Dichloroethane
Methyl Ethyl Ketone
1, 1, 1-Trichloroethane
Carbon tetrachloride
Dichlorobromomethane
1, 1,2,2-Tetrachloroethane
1,2-Dichloropropane
trans-1,3-Dichloropropene
Trichloroethene
Chlorodibromomethane
1, 1,2-Trichloroethane
Benzene
cis-1,3-Dichloropropene
Bromoform
2-Hexanone
methyl isobutyl ketone
T etrachloroethene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Xylenes, Total
>
1.0 U
1.0 U
1.0 U
1.0 U
5.0 U
25 U
1.0 U
1.0 U
1.0 U
1.0 U
1.0 U
1.0 U
1.0 U
10 U
1.0 U
1.0 U
1.0 U
1.0 U
1.0 U
1.0 U
1.0 U
1.0 U
1.0 U
1.0 U
1.0 U
1.0 U
10 U
10 U
1.0 U
1.0 U
1.0 U
1.0 U
1.0 U
2.0 U
Surrog=at;;:e _________________ .:.'¾;;..,R_e:.;cc,._ ________ _
Toluene-dB 98
4-Bromofluorobenzene 95
Dibromofluoromethane 101
STL Savannah Page 4 of 10
Acceptance Limits
79 -122
77 • 120
75 • 123
--.. ~··-··-·-·---
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•
•
Client: ENSR International
Client Sample ID:
Lab Sample ID:
Client Matrix:
Analyte
Cyanide, Total
STL Savannah
Effluent
68().7231-1
Water
Result
0.0064
Anly Batch: 680.19816
Prep Batch: 680-19814
General Chemistry
Qual Units
mg/L
Date Analyzed 08123/2005 0914
Date Prepared: 0812212005 1200
Page 5 of 10
Analytical Data
Job Number. 680-7231-1
Date Sampled: 08/1812005 1615
Date Received: 08/1912005 0908
RL Oil Method
0.0050 1.0 335.4
• DATA REPORTING QUALIFIERS
Client: ENSR International Job Number: 680-7231-1
Lab Section Qualifier Description
GC/MSVOA
u Analyte was not detected at or above the reporting limit.
General Chemistry
u Analyte was not detected at or above the reporting limit.
•
• STL Savannah
Page 6 of 10
• Client: ENSR International
•
•
Surrogate Recovery Report
8260B Volatile Organic Compounds by GC/MS
Client Matrix: Water
Lab Sample ID Client Sample
680-7231-1 Effluent
LCS 680-20022/1
MB 680-20022/2
LCS
MB
Surrogate
(BFB)
(DBFM)
(TOL)
4-Bromofluorobenzene
Dibromofluoromethane
Toluene-dB
STL Savannah
(BFB)
(%Rec)
95
106
96
(DBFM)
(%Rec)
101
104
96
(TOL)
(¾Rec)
98
112
106
Acceptance Limits
77 -120
75 -123
79 -122
Page 7 of 10
Quality Control Results
Job Number: 680-7231-1
•
•
•
Client: ENSR International
Method Blank· Batch: 680-20022
Lab Sample ID: MB 680-20022/2
Client Matrix: Water
Dilution: 1.0
Date Analyzed: 08/23/2005 1947
Date Prepared: 08/23/2005 1947
Analyte
···---···-· Chloromethane
Bromomethane
Vinyl chloride
Chloroethane
Methylene Chlortde
Acetone
Carbon disulfide
1, 1-Dichloroethene
1, 1-Dichloroethane
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Chlorofonm
1,2-Dichloroethane
Methyl Ethyl Ketone
1, 1, 1-Trichloroethane
Carbon tetrachloride
Dichlorobromomethane
1, 1,2,2-T etrachloroethane
1,2-Dichloropropane
trans-1,3--Dichloropropene
Trtchloroethene
Chlorodibromomethane
1, 1,2-Trtchloroethane
Benzene
cls-1,3-Dichloropropene
Bromoform
2-Hexanone
methyl isobutyl ketone
T etrachloroethene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Xylenes, Total
Analysis Batch: 680-20022
Prep Batch: NIA
Units: ug/L
Result
1.0··
1.0
1.0
1.0
5.0
25
1.0
1.0
1.0
1.0
1.0
1.0
1.0 ,o ,.o
1.0
1.0 ,.o
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
10
1.0
1.0
1.0
1.0
1.0
2.0
Qual
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
surrogate .... u•• ·-····--·=-~-·-~-·---·-·-··· -~-~-~·~~ .... •-<>·•~·•-
%Rec -·-.. ,,. ,,.·--~·-··--·-·~---·-··-.
Toluene-dB 106
4-Bromofluorobenzene 96
Dibromofluoromethane 96
Quality Control Results
Job Number: 680-7231-1
Method: 8260B
Preparation: 5030B
Instrument ID: GC/MS Volatiles· A
Lab File ID: aq671.d
Initial WeighWolume: 5 ml
Final WeighWolume: 5 ml
RL ----·--·-·•-····---1.0
1.0
1.0
1.0
5.0
25
1.0
1.0
1.0
1.0
1.0
1.0
1.0 ,o
1.0 ,.o
1.0 ,.o
1.0 ,.o ,.o
1.0 ,.o ,.o
1.0 ,.o ,o
10
1.0 ,.o ,.o
1.0
1.0
2.0
"',,,,, Acceptan?9. Limi_t~ _, .... '•<S ~-.,a',"•'M•~" • •••'•'''•''" ••
79 -122
77 -120
75 -123
Calculations are perlormed before rounding to avoid round-off errors in calculated results.
STL Savannah Page 8 of 10
• Quality Control Results
Client: ENSR International Job Number: 680-7231-1
Laboratory Control Sample -Batch: 680-20022 Method: 82608'
Preparation: 50308
Lab Sample ID: LCS 680-20022/1 Analysis Batch: 680-20022 Instrument ID: GC/MS Volatiles -A
Client Matrix: Water Prep Batch: N/A Lab File ID: aq668,d
Dilution: 1,0 Units: ug/L lnrtial WeighWolume: 5 ml
Date Analyzed: 08/23/2005 1833 Final WeighWolume: 5 ml
Date Prepared: 08123/2005 1833
Analyte Spike Amount Result %Rec. Limit Oual ~----~---~------
Chloromethane 50,0 47 94 51 -133
Bromomethane 50.0 49 98 21 -176
Vinyl chloride 50,0 49 97 59 -136
Chloroethane 50,0 61 121 40 -171
Methylene Chloride 50,0 62 124 67 -128
Acetone ,oo 110 105 20 -183
Carbon disulfide 50.0 42 83 60-130
1, 1-Dichloroethene 50.0 44 89 64 -132
1, 1-Dichloroethane 50,0 57 114 70 -127
cis-1,2-Dichloroethene 50,0 54 108 69 -126
trans-1,2-Dichloroethene 50,0 34 68 67 -130 • Chloroform 50,0 52 105 74 -124
1,2-Dichloroethane 50,0 49 97 68 -130
Methyl Ethyl Ketone ,oo 110 111 51 -142
1, 1, 1-Trichloroethane 50.0 45 91 70 -132
Carbon tetrachloride 50,0 45 90 64 -137
Dichlorobromomethane 50,0 52 105 74 -128
1, 1,2,2-Tetrachloroethane 50,0 49 97 71 -127
1,2-Dichloropropane 50,0 55 109 74 -123
trans-1, 3-Dichloropropene 50.0 49 98 75 -126
Trichloroethene 50.0 46 92 75 -122
Chlorodibromomethane 50.0 50 99 75 -126
1, 1,2-Trichloroethane 50,0 50 100 75 -122
Benzene 50,0 55 110 74 -122
cis-1,3-Dichloropropene 50,0 54 108 76 -126
Bromoform 50,0 51 102 64 -132
2-Hexanone 100 100 103 58-139
methyl isobutyl ketone ,oo 110 110 62 -130
Tetrachloroethene 50.0 42 84 70-133
Toluene 50,0 50 101 75 -122
Chlorobenzene 50,0 52 104 75 -123
Ethylbenzene 50,0 43 87 77 -123
Styrene 50.0 47 95 75 -125
Xylenes, Total ,so 130 89 77 -121
• Calculations are perfomied before rounding to avoid round-off errors in calculated results.
STL Savannah Page 9 of 10
•
•
•
Client: ENSR International
Method Blank -Batch: 680-19814
Lab Sample ID: MB 680-19814/1-A
Clien1 Matrix: Water
Dilution: 1.0
Date Analyzed: 08/23/2005 0907
Date Prepared: 08/22/2005 1200
Analysis Batch: 680· 19816
Prep Batch: . 680-19814
Units: mg/L
Result Qual
Quality Control Results
Job Number: 680-7231-1
Method: 335.4
Preparation: Distillation
Instrument ID: No Equipment Assigned
Lab File ID: N/A
Initial WeighWolume: 50 ml
Final WeighWolume: 50 ml
RL Analyte
Cyanide. Total ·····-····--------·--········--,------o.0050 u 0.0050
Laboratory Control Sample -Batch: 680·19814
Lab Sample ID: LCS 680·19814/2·A
Client Matrix: Water
Dilution: 1.0
Date Analyzed: 08/23/2005 0908
Date Prepared: 08/22/2005 1200
Analyte
Analysis Batch: 680·19816
Prep Batch: 680-19814
Units:mg/L
Spike Amount Result
-----·---------
Cyanide. Total 0.0300 0.029
Method: 335.4
Preparation: Distillation
Instrument ID: No .Equipment Assigned
Lab File ID: N/A
Initial WeighWolume: 50 ml
Final WeighWolume: 50 ml
%Rec. Limit
97 90 • 110
Qual
Calculations are perfonned before rounding to avoid round-off errors in calculated results.
STL Savannah Page 10 of 10
PROJECT REFERENCE
ANALYSIS REQUEST AND CHAIN OF CUSTODY RECORD
STL
PROJECT LOCATION
//. J;);)... {STATE I A,) c.,_,,
CONTRACT NO.
MATRIX
TYPE
Serial Number 519 9 5
STL Savannah
5102 LaRoche Avenue
Savannah, GA 31404
0 Alternate Laboratory Name/Location
REQUIRED ANALYSIS
,h -n ~, ~ ..,,,_
<' hi. I•"-:
§ ,~l1; :--.,_,J
Website: www.st~inc.com
Phone: [phone]
Fax: 19121352-0165
Phone:
Fax:
,-
PAGE OF
STANDARD REPORT
DELIVERY 9{;)
DATE DUE ____ _
EXPEDITED REPORT
DELIVERY 0
{SURCHARGE}
DATE DUE
NUMBER OF COOLERS SUBMITTED
PER SHIPMENT: ::, T' ,
r--~S~A~M~PL~E~---------------------~~~§ i-~-=·-~-~-~-~-~-~-~-~-~---------~
DATE TIME SAMPLE IOENTIFICATION 8 < ~ ~ ~ NUMBER Of CONTAINERS SUBMITTED REMARKS
RELINQUISHED BY: !S!GNATUR£1 DATE TIME
TIME
/'3:C)O
DATE TIME.
11os-jrll
CUSTODY INTACT
YES C)· -
NO ·o
I
__ LABORATORY USE ONLY : -_ ·
CUSTODY
SEAL.NO.
RELINQUISHED BY: <SIGNATURE! DATE TIME
RECEIVED BY: ISIGNA~I DATE TIME
LABORATORY REMARKS·
STL8240-680 112/021 j}
•
September 2005 Analytical Data
•
•
•
• Severn Trent Laboratories, Inc.
ANALYTICAL REPORT
Job Number: 680-8543-1
Job Description: Channel Master
For:
ENSR International
7041 Old Wake Forrest Road
Raleigh, NC 27616
Attention: Mr. Gerald Hornaday
Kathryn Smith
Project Manager I
[e-mail]
10/06/2005
STL Savannah 5102 LaRoche Avenue, Savannah, GA 31404
Tel [phone] Fax [phone] www.stl-inc.com
Page 1 of 13
•
•
Client: ENSR International
Description
Matrix: Water
Volatile Organic Compounds by GC/MS
Purge-and-Trap
Cyanide, Total (Semi-Automated Colorimetry)
Distillation/Cyanide
LAB REFERENCES:
STL-SAV = STL-Savannah
METHOD REFERENCES:
METHOD SUMMARY
Lab Location Method
STL-SAV
STL-SAV
SW846 8260B
Job Number: 680-8543-1
Preparation Method
SW846 5030B
STL-SAV
STL-SAV
MCAWW 335.4
Distillation
MCAWW -"Methods For Chemical Analysis Of Water And Wastes", EPA-600/4-79-020, March 1983 And
Subsequent Revisions .
SW846 -"Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Ed~ion, November 1986
And Its Updates.
STL Savannah
Page 2 of 13
•
•
•
Client: ENSR International
Lab Sample ID
680-8543-1
680-8543-2
STL Savannah
Client Sample ID
Effluent
Trip Blank
SAMPLE SUMMARY
Client Matrix
Water
Water
Page 3 of 13
Date/Time
Sampled
09/21/2005 1330
09/21/2005 0000
Job Number. 680-8543-1
Date/Time
Received
09/22/2005 1000
09/22/2005 1000
•
•
Client: ENSR International
Client Sample ID: Effluent
Lab Sample ID:
Client Matrix:
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
680-8543-1
Water
8260B
5030B
1.0
8260B Volatile Organic Compounds by GC/MS
Analysis Batch: 680-24077
10/04/2005 1648
10104/2005 1648
Analytical Data
Job Number: 680-8543-1
Date Sampled: 09/21/2005 1330
Date Received: 09/22/2005 1000
Instrument ID: GC/MS Volatiles - P
Lab File ID: p0210.d
lnttial WeighWolume: 5 ml
Final WeighWolume: 5 ml
Analyte Result (ug/L) Qualifier RL
Chloromethane
Bromomethane
Vinyl chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1, 1-Dichloroethene
1, 1-Dichloroethane
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Chloroform
1,2-Dichloroethane
Methyl Ethyl Ketone
1, 1, 1-Trichloroethane
Carbon tetrachloride
Dichlorobromomethane
1, 1,2,2-Tetrachloroethane
1,2-Dichloropropane
trans-1,3-Dichloropropene
Trichloroethene
Chlorodibromomethane
1, 1,2-Trichloroethane
Benzene
cis-1,3-Dichloropropene
Bromoform
2-Hexanone
methyl isobutyl ketone
Tetrachloroethene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Xylenes, Total
Surrogate
Toluene-<l8
4-Bromofluorobenzene
Dibromofluoromethane
STL Savannah
5.0
1.0
1.0
1.0
5.0
25
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
10
1.0
1.0
1.0
1.0
1.0
2.0
%Rec
94
95
110
Page 4 of 13
1.0
u 1.0
u 1.0
u 1.0
u 5.0
u 25
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 10
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 10
u 10
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 2.0
Acceptance Limtts
79 -122
77 -120
75 -123
•
•
•
Client: ENSR International
Client Sample ID: Trip Blank
Lab Sample ID:
Client Matrix:
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
680-8543-2
Water
8260B
5030B
1.0
8260B Volatile Organic Compounds by GC/MS
Analysis Batch: 680-23986
10/04/2005 0556
10/04/2005 0556
Analytical Data
Job Number. 680-8543-1
Date Sampled: 09/21/2005 0000
Date Received: 09/22/2005 1000
Instrument ID: GC/MS Volatiles -

P

Lab File ID: p0178.d
Initial WeighWolume: 5 ml
Final WeighWolume: 5 ml
Analyte Result (ug/L) Qualifier RL
Chloromethane
Bromomethane
Vinyl chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1, 1-Dichloroethene
1, 1-Dichloroethane
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Chloroform
1,2-Dichloroethane
Methyl Ethyl Ketone
1, 1, 1-Trichloroethane
Carbon tetrachloride
Oichlorobromomethane
1, 1,2,2-Tetrachloroethane
1,2-Dichloropropane
trans-1,3-Dichloropropene
Trichloroethene
Chlorodibromomethane
1, 1,2-Trichloroethane
Benzene
cis-1,3-0ichloropropene
Bromoform
2-Hexanone
methyl isobutyl ketone
T etrachloroethene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Xylenes, Total
Surrogate
T oluene-<l8
4-Bromofluorobenzene
Dibromofluoromethane
STL Savannah
4.6
1.0
1.0
1.0
5.0
25
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
10
1.0
1.0
1.0
1.0
1.0
2.0
%Rec
95
97
106
Page 5 of 13
1.0
u 1.0
u 1.0
u 1.0
u 5.0
u 25
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 10
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 10
u 10
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 2.0
Acceptance Limits
79 -122
77 -120
75 -123
•
•
•
Client: ENSR International
Client Sample ID:
Lab Sample ID:
Client Matrix:
Analyte
Cyanide, Total
STL Savannah
Effluent
680-8543-1
Water
Result
0.0066
Anly Batch: 680-23039
Prep Batch: 680-23037
General Chemlst,y
Qual Units
mg/L
Date Analyzed 09/24/2005 1415
Date Prepared: 09/23/2005 0600
Page 6 of 13
Analytical Data
Job Number: 680-8543-1
Date Sampled: 09/21/2005 1330
Date Received: 09/22/2005 1000
RL Dil Method
0.0050 1.0 335.4
• DATA REPORTING QUALIFIERS
Client: ENSR International Job Number. 680-8543-1
Lab Section Qualifier Description
GC/MSVOA
u Analyte was not detected at or above the reporting limlt.
General Chemistry
u Analyte was not detected at or above the reporting limit.
•
STL Savannah
Page 7 of 13
• Client: ENSR International
Surrogate Recovery Report
82608 Volatile Organic Compounds by GC/MS
Client Matrix: Water
Lab Sample ID Client Samele
680-8543-1 Effluent
680-8543-2 Trip Blank
LCS 680-23986/8 LCS
LCS 680-24077/1 LCS
MB 680-23986/9 MB
MB 680-24077 /3 MB
Surrogate
(BFB) 4-Bromofluorobenzene
(DBFM) Dibromofluoromethane • (TOL) Toluene-dB
•
STL Savannah
(BFB) (DBFM) (TOL)
(%Rec) (%Rec) (%Rec)
95 110 94
97 106 95
93 96 86
96 106 91
97 104 97
95 108 95
Acceptance Limits
77 -120
75 -123
79 -122
Page 8 of 13
Quality Control Results
Job Number: 680-8543-1
•
•
•
Client: ENSR International
Method Blank -Batch: 680-23986
Lab Sample ID: MB 680-23986/9
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
Analyte
Water
1.0
10/04/2005 0029
10/04/2005 0029
Chloromethane
Bromomethane
Vinyl chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1, 1-Dichloroethene
1, 1-0ichloroethane
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Chloroform
1,2-Dichloroethane
Methyl Ethyl Ketone
1, 1, 1-Trichloroethane
Carbon tetrachloride
Dichlorobromomethane
1, 1,2,2-Tetrachloroethane
1,2-Dichloropropane
trans-1,3-Dichloropropene
Trichloroethene
Chlorodibromomethane
1, 1,2-Trichloroethane
Benzene
cis-1,3-0ichloropropene
Bromoform
2-Hexanone
methyl isobutyl ketone
T etrachloroethene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Xylenes, Total
Surrogate
Toluene-<l8
4-Bromofluorobenzene
Dibromofluoromethane
Analysis Batch: 680-23986
Prep Batch: NIA
Units: ug/L
Result
1.0
1.0
1.0
1.0
5.0
25
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
10
1.0
1.0
1.0
1.0
1.0
2.0
%Rec
97
97
104
Qual
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
Calculations are performed before rounding to avoid round-off errors in calculated results.
STL Savannah Page 9 of 13
Quality Control Results
Job Number: 680-8543-1
Method: 8260B
Preparation: 5030B
Instrument ID: GCIMS Volatiles -P
Lab File ID: pq136.d
lnttial WeighWolume: 5 mL
Final WeighWolume: 5 ml
RL
1.0
1.0
1.0
1.0
5.0
25
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
10
1.0
1.0
1.0
1.0
1.0
2.0
Acceptanc:.e Limits
79 • 122
77 -120
75 • 123
• Quality Control Results
Client: ENSR International Job Number. 680-8543-1
Laboratory Control Sample -Batch: 680-23986 Method: 82608
Preparation: 50308
Lab Sample ID: LCS 680-2398618 Analysis Batch: 680-23986 Instrument ID: GC/MS Volatiles - P
Client Matrix: Water Prep Batch: N/A Lab File ID: pq130.d
Dilution: 1.0 Units: ug/L Initial WeighWolume: 5 ml
Date Analyzed: 10/03/2005 2257 Final WeighWolume: 5 ml
Date Prepared: 10/03/2005 2257
Analyte Spike Amount Result %Rec. Limit Qual
Chloromethane 50.0 39 77 51 -133
Bromomethane 50.0 56 112 21 • 176
Vinyl chloride 50.0 39 79 59 -136
Chloroethane 50.0 52 103 40 -171
Methylene Chloride 50.0 50 100 67 -128
Acetone 100 120 118 20 • 183
Carbon disulfide 50.0 45 89 60 -130
1, 1-Dichloroelhene 50.0 44 88 64 -132
1, 1-Dichloroethane 50.0 46 92 70 -127
cis-1,2-Dichloroelhene 50.0 49 99 69 -126
trans-1,2-Dichloroethene 50.0 46 92 67 -130 • Chloroform 50.0 46 92 74 -124
1,2-Dichloroethane 50.0 44 88 6B • 130
Methyl Ethyl Ketone 100 110 106 51 -142
1, 1, 1-Trichloroethane 50.0 41 81 70-132
Carbon tetrachloride 50.0 39 79 64 -137
Oichlorobromomethane 50.0 44 87 74 -128
1, 1,2,2-Tetrachloroethane 50.0 45 91 71 • 127
1,2-Dichloropropane 50.0 45 91 74 • 123
trans-1,3-Dichloropropene 50.0 47 93 75 -126
Trichloroethene 50.0 44 87 75 -122
Chlorodibromomethane 50.0 46 91 75 -126
1, 1,2-Trichloroelhane 50.0 46 91 75-122
Benzene 50.0 42 84 74 -122
cis-1,3-Dichloropropene 50.0 45 91 76 -126
Bromoform 50.0 46 92 64 -132
2-Hexanone 100 92 92 5B -139
methyl isobutyl ketone 100 84 84 62 -130
Tetrachloroethene 50.0 44 88 70 -133
Toluene 50.0 43 86 75 -122
Chlorobenzene 50.0 47 94 75 • 123
Ethylbenzene 50.0 44 88 77 -123
Styrene 50.0 46 93 75 -125
Xylenes, Total 150 140 90 77 -121
• Calculations are performed before rounding to avoid round-off errors in calculated results.
STL Savannah Page 10 of 13
•
•
•
Client: ENSR International
Method Blank -Batch: 680-24077
Lab Sample ID: MB 680-24077/3
Client Matrix: Water
Dilution: 1.0
Date Analyzed: 10/04/2005 1538
Date Prepared: 10/04/2005 1538
Analyte
Chloromethane
Bromomethane
Vinyl chloride
Chloroelhane
Methylene Chloride
Acetone
Carbon disulfide
1, 1-Dichloroethene
1, 1-Dichloroethane
cis-1,2-0ichloroethene
trans-1,2-Dichloroethene -
Chloroform
1,2-Dichloroethane
Methyl Ethyl Ketone
1, 1, 1-Trichloroethane
Carbon tetrachloride
Dichlorobromomethane
1, 1,2,2-Tetrachloroethane
1,2-Dichloropropane
trans-1,3-Dichloropropene
T richloroethene
Chlorodibromomethane
1, 1,2-Trichloroethane
Benzene
cis-1,3-Dichloropropene
Bromoform
2-Hexanone
methyl isobutyl ketone
Tetrachloroethene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
X ylenes, Total
Surrogate .•
Toluene-dB
4-Bromofluorobenzene
Dibromofluoromethane
Analysis Batch: 680-24077
Prep Batch: NIA
Units: ug/L
Result
1.0
1.0
1.0
1.0
5.0
25
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
1.0
1.0
1.0
1.0
10
10
1.0
1.0
1.0
1.0
1.0
2.0
%Rec
95
95
108
Qual
u
u
u
u
u u
u
u
u
u
u
u u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
Calculations are performed before rounding to avoid round-off errors in calculated results.
STL Savannah Page 11 of 13
Quality Control Results
Job Number: 680-8543-1
Method: 8260B
Preparation: 5030B
Instrument ID: GC/MS Volatiles -P
Lab File ID: pq148.d
Initial WeighWolume: 5 ml
Final WeighWolume: 5 ml
RL
1.0
1.0
1.0
1.0
5.0
25
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
10
1.0
1.0
1.0
1.0
1.0
2.0
Acce_ptance Limits
79-122
77 -120
75 -123
• Quality Control Results
Client: ENSR International Job Number: 680-8543-1
Laboratory Control Sample -Batch: 680-24077 Method: 82608
Preparation: 5030B
Lab Sample ID: LCS 680-24077/1 Analysis Batch: 680-24077 Instrument ID: GC/MS Volatiles - P
Client Matrix: Water Prep Batch: N/A Lab File ID: pq142.d
Dilution: 1.0 Units: ug/L Initial WeighWolume: 5 ml
Date Analyzed: 10/04/2005 1414 Final WeighWolume: 5 ml
Date Prepared: 10/04/2005 1414
Analyte Spike Amount Result %Rec. Limtt Qual
Chloromethane 50.0 46 93 51 • 133
Bromomethane 50.0 62 124 21 • 176
Vinyl chloride 50.0 50 100 59-136
Chloroethane 50.0 55 109 40 • 171
Methylene Chloride 50.0 55 109 67 -128
Acetone 100 130 128 20 • 183
Carbon disulfide 50.0 52 104 60-130
1, 1-Dichloroelhene 50.0 53 105 64 -132
1, 1-0ichloroethane 50.0 51 101 70-127
cis-1,2-Dichloroethene 50.0 55 109 69 -126
trans-1,2-Dichloroethene 50.0 53 106 67 -130 • Chloroform 50.0 51 102 74 • 124
1,2-Dichloroethane 50.0 42 85 6B-130
Methyl Ethyl Ketone 100 110 115 51 -142
1, 1, 1-Trichloroelhane 50.0 44 68 70-132
Carbon tetrachloride 50.0 43 85 64 -137
Dichlorobromomethane 50.0 45 89 74 • 128
1, 1,2,2-T etrachloroelhane 50.0 48 95 71 • 127
1,2-Dichloropropane 50.0 45 89 74 -123
trans-1,3-Dichloropropene 50.0 45 90 75 • 126
Trichloroethene 50.0 47 93 75 -122
Chlorodibromomethane 50.0 48 96 75 -126
1, 1,2-Trichloroethane 50.0 45 89 75-122
Benzene 50.0 45 90 74-122
cis-1,3-Dichloropropene 50.0 45 90 76 -126
Bromoform 50.0 49 97 64 • 132
2-Hexanone 100 96 96 58 -139
methyl isobutyl ketone 100 83 83 62-130
Tetrachloroethene 50.0 53 106 70-133
Toluene 50.0 46 93 75 -122
Chlorobenzene 50.0 50 100 75 -123
Ethylbenzene 50.0 49 97 77 -123
Styrene 50.0 50 100 75 • 125
Xylenes, Total 150 150 100 77 • 121
Calculations are performed before rounding to avoid round-off errors in calculated results.
STL Savannah Page 12 of 13
•
•
•
Client: ENSR International
Method Blank -Batch: 680-23037
Lab Sample ID: MB 680-2303711-A
Client Matrix: Water
Dilution: 1.0
Date Analyzed: 09/24/2005 1415
Date Prepared: 09/23/2005 0600
Analyte
Cyanide, Total
Laboratory Control/
Analysis Batch: 680-23039
Prep Batch: 680-23037
Units: mg/L
Result
0.0050
Laboratory Control Duplicate Recovery Report -Batch: 680-23037
LCS Lab Sample ID: LCS 680-23037/2-A
Client Matrix: Water
Dilution: 1.0
Date Analyzed:
Date Prepared:
09/24/2005 1415
09123/2005 0600
LCSD Lab Sample ID: LCSD 680-23037I3-A
Client Matrix: Water
Dilution: 1.0
Date Analyzed: 09124/2005 1415
Date Prepared: 09123/2005 0600
Analyte
Cyanide, Total
Analysis Batch: 680-23039
Prep Batch: 680-23037
Units: mg/L
Analysis Batch: 680-23039
Prep Batch: 680-23037
Units:mg/L
%Rec1
LCS LCSD Limit
103 107 90 -110
Qual
u
Quality Control Results
Job Number. 680-8543-1
Method: 335.4
Preparation: Distillation
. Instrument ID: No Equipment Assigned
Lab File ID: NIA
Initial WeighWolume: 50 ml
Final WeighWolume: 50 ml
RL
0.0050
Method: 335.4
Preparation: Distillation
Instrument ID: No Equipment Assigned
Lab File ID: NIA
Initial WeighWolume: 50 ml
Final WeighWolume: 50 ml
Instrument ID: No Equipment Assigned
Lab File ID: NIA
Initial WeighWolume: 50 ml
Final WeighWolume: 50 ml
RPD RPD Limit LCS Qual LCSD Qual
3 20
Calculations are performed before rounding to avoid round-off errors in calculated results.
STL Savannah Page 13 of 13
ANALYSIS REQUEST AND CHAIN OF CUSTODY RECORD
RELINQUISHED BY: !SIGNATURE)
STL
PROJECT NO. PROJECT LOCATION
/01 SLCI · 0/(,, ~ 163 (STATE) .U l--
DATE
SAMPLE IDENTIFICATION
TIME
TIME
/'3:jO
TIME CUSTODY INTACT
YES 0
NO 0
MATRIX
TYPE
CUSTODY
SEAL NO ..
.... ,
Serial Number · 519 9B
9?) Sll Savannah
5102 LaRoche Avenue
Savannah, GA 31404
C) Alternate Laboratory Name/location
REQUIRED ANALYSIS
.-I I_
NUMBER OF CONTAINERS SUBMITTED
Website: www.stl-inc.com
Phone: [phone]
Fax: 19121352-0165
Phone:
Fax:
..-
.l
PAGE / OF /
STANDARD REPORT
DELIVERY <)[)
DATE DUE ____ _
EXPEDITED REPORT
DELIVERY 0
(SURCHARGE!
DATE DUE
NUMBER OF COOLERS SUBMITTED
PER SHIPMENT:
REMARKS
·"·~-~-~--~~--.
'
DAT TIME RELINQUISHED BY: l~GNAT\IREI DATE TIME
9-r;J; os· /?;Jo
DATE TIME RECEIVED BY: l~lllREI DATE TIME
LABORATORY REMARKS
STL824Q.680112/021
•
October 2005 Analytical Data
•
•
•
•
• Severn Trent Laboratories, Inc.
ANALYTICAL REPORT
Job Number: 680-9679-1
Job Description: Channel Master
For:
ENSR International
7041 Old Wake Forrest Road
Raleigh, NC 27616
Attention: Mr. Gerald Hornaday
Kathryn Smith
Project Manager I
[e-mail]
11/06/2005
STL Savannah 5102 LaRoche Avenue, Savannah, GA 31404
Tel [phone] Fax [phone] www.stl-inc.com
Page 1 of 11
•
•
•
Client: ENSR International
Description
Matrix: Water
Volatile Organic Compounds. by GC/MS
Purge-and-Trap
Cyanide, Total (Semi-Automated Colorimetry)
Distillation/Cyanide
LAB REFERENCES:
STL-SAV = STL-Savannah
METHOD REFERENCES:
METHOD SUMMARY
Lab Location Method
STL-SAV
STL-SAV
SW846 8260B
Job Number: 680-9679-1
Preparation Method
SW846 5030B
STL-SAV
STL-SAV
MCAVWV 335.4
Distillation
MCAVWV-"Methods For Chemical Analysis Of Water And Wastes", EPA-600/4-79-020, March 1983 And
Subsequent Revisions .
SW846 -"Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986
And Its Updates .
STL Savannah
Page 2 of 11
•
•
•
Client: ENSR International
Lab Sample ID
680-9679-1
680-9679-2
STL Savannah
Client Sample ID
Elf
Trip Blank
SAMPLE SUMMARY
Client Matrix
Water
Water
Page 3 of 11
Date/Time
Sampled
10/20/2005 1300
10/20/2005 0000
Job Number: 680-9679-1
Date/Time
Received
10/21/2005 0905
10/21/2005 0905
•
•
•
Client: ENSR International
Client Sample ID: Eff
Lab Sample ID:
Client Matrix:
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
680-9679-1
Water
82608
50308
1.0
82608 Volatile Organic Compounds by GC/MS
Analysis Batch: 680-26726
10/28/2005 1545
10/28/2005 1545
Analytical Data
Job Number: 680-9679-1
Date Sampled: 10/20/2005 1300
Date Received: 10/21/2005 0905
Instrument ID: GC/MS Volatiles - P
Lab File ID: p0767.d
Initial WeighWolume: 5 ml
Final WeighWolume: 5 ml
Analyte Result (ug/L) Qualifier RL
Chloromethane 1.0 u 1.0
Bromomethane 1.0 u 1.0
Vinyl chloride 1.0 u 1.0
Chloroethane 1.0 u 1.0
Methylene Chloride 5.0 u 5.0
Acetone 25 u 25
Carbon disulfide 1.0 u 1.0
1, 1-Dichloroethene 1.0 u 1.0
1, 1-Dichloroethane 1.0 u 1.0
cis-1,2-Dichloroethene 1.0 u 1.0
trans-1,2-Dichloroethene 1.0 u 1.0
Chloroform 1.0 u 1.0
1,2-Dichloroethane 1.0 u 1.0
Methyl Ethyl Ketone 10 u 10
1, 1, 1-Trichloroethane 1.0 u 1.0
Carbon tetrachloride 1.0 u 1.0
Dichlorobromomethane 1.0 u 1.0
1, 1,2,2-Tetrachloroethane 1.0 u 1.0
1,2-Dichloropropane 1.0 u 1.0
trans-1,3-Dichloropropene 1.0 u 1.0
Trichloroethene 1.0 u 1.0
Chlorodibromomethane 1.0 u 1.0
1, 1,2-Trichloroethane 1.0 u 1.0
Benzene 1.0 u 1.0
cis-1,3-Dichloropropene 1.0 u 1.0
Bromoform 1.0 u 1.0
2-Hexanone 10 u 10
methyl isobutyl ketone 10 u 10
Tetrachloroethene 1.0 u 1.0
Toluene 1.0 u 1.0
Chlorobenzene 1.0 u 1.0
Ethylbenzene 1.0 u 1.0
Styrene 1.0 u 1.0
Xylenes, Total 2.0 u 2.0
Surrogate %Rec Acceptance Limits
Toluene-dB 96 79 -122
4-Bromofluorobenzene 102 77 -120
Dibromofluoromethane 101 75 -123
STL Savannah Page 4 of 11
•
•
•
Client: ENSR International
Client Sample ID: Trip Blank
Lab Sample ID:
Client Matrix:
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
680-9679-2
Water
8260B
5030B
1.0
8260B Volatile Organic Compounds by GC/MS
Analysis Batch: 680-26726
10/28/2005 1421
10/28/2005 1421
Analytical Data
Job Number: 680-9679-1
Date Sampled: 10/20/2005 0000
Date Received: 10/21/2005 0905
Instrument 10: GC/MS Volatiles - P
Lab File ID: p0761.d
Initial WeighWolume: 5 ml
Final WeighWolume: 5 ml
Analyte Result (ug/L) Qualifier RL
Chloromethane
Bromomethane
Vinyl chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1, 1-Dichloroethene
1, 1-Dichloroethane
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Chloroform
1,2-Dichloroethane
Methyl Ethyl Ketone
1, 1, 1-Trichloroethane
Carbon tetrachloride
Dichlorobromomethane
1, 1,2,2-Tetrachloroethane
1,2-Dichloropropane
trans-1,3-Dichloropropene
Trichloroethene
Chlorodibromomethane
1, 1,2-Trichloroethane
Benzene
cis-1,3-Dichloropropene
Bromoform
2-Hexanone
methyl isobutyl ketone
T etrachloroethene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Xylenes, Total
Surrogate
Toluene-dB
4-Bromofluorobenzene
Dibromofluoromethane
STL Savannah
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
5.0 u 5.0
25 u 25
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
10 u 10
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
10 u 10
10 u 10
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.3 1.0
2.0 u 2.0
%Rec Acceptance Limits
97 79 -122
104 77 -120
103 75 -123
Page 5 of 11
• Client: ENSR International
•
•
Client Sample ID: Eff
Lab Sample·ID:
Client Matrix:
Analyte
Cyanide, Total
STL Savannah
680-9679-1
Water
Result
0.0050
Anly Batch: 680-26264
Prep Batch: 680-26261
General Chemistry
Qual Units
U mg/L
Date Analyzed 10/25/2005 0800
Date Prepared: 10/24/2005 0600
Page 6 of 11
Analytical Data
Job Number: 680-9679-1
Date Sampled:
Date Received:
RL
0.0050
10/20/2005 1300
10121/2005 0905
Dil Method
1.0 335.4
• DATA REPORTING QUALIFIERS
Client: ENSR International Job Number: 680-9679-1
Lab Section Qualifier Description
GC/MSVOA
u Analyte was not detected at or above the reporting limtt.
General Chemistry
u Analyte was not detected at or above the reporting limit.
•
• STL Savannah
Page 7 of 11
• Client: ENSR International
•
•
Surrogate Recovery Report
8260B Volatile Organic Compounds by GC/MS
Client Matrix: Water
Lab Sample ID
680-9679-1
680-9679-2
LCS 680-26726/5
MB 680-26726/6
Surrogate
Client Sample
Elf
Trip Blank
LCS
MB
(BFB)
(DBFM)
(TOL)
4-Bromofluorobenzene
Dibromofluoromethane
Toluene-dB
STL Savannah
(BFB) (DBFM) (TOL)
(%Rec) (%Rec) (%Rec)
102 101 96
104 103 97
108 105 100
103 104 98
Acceptance Limits
77 -120
75 -123
79 -122
Page 8 of 11
Quality Control Results
Job Number: 680-9679-1
•
•
•
Client: ENSR International
Method Blank -Batch: 680-26726
Lab Sample ID: MB 680-26726/6
Client Matrix: Water
Dilution: 1.0
Date Analyzed: 10/28/2005 1325
Date Prepared: 10/28/2005 1325
Analyte
.Chloromethane
Bromomethane
Vinyl chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1, 1-Dichloroethene
1, 1-Dichloroethane
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Chloroform
1,2-Dichloroethane
Methyl Ethyl Ketone
1, 1, 1-Trichloroethane
Carbon tetrachloride
Dichlorobromomethane
1, 1,2,2-Tetrachloroethane
1,2-Dichloropropane
trans-1,3-Dichloropropene
Trichloroethene
Chlorodibromomethane
1, 1,2-Trichloroethane
Benzene
cis-1,3-Dichloropropene
Bromoform
2-Hexanone
methyl isobutyl ketone
T etrachloroethene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Xylenes, Total
Surrogate
Toluene-dB
4-Bromofluorobenzene
Dibromofluoromethane
Analysis Batch: 680-26726
Prep Batch: NIA
Units: ug/L
Result
1.0
1.0
1.0
1.0
5.0
25
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
10
1.0
1.0
1.0
1.0
1.0
2.0
% Rec
98
103
104
Oual
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
Calculations are performed before rounding to avoid round-off errors in calculated results.
STL Savannah Page 9 of 11
Quality Control Results
Job Number: 680-9679-1
Method: 8260B
Preparation: 5030B
Instrument ID: GC/MS Volatiles - P
Lab File ID: pq463.d
Initial WeighWolume: 5 . ml
Final WeighWolume: 5 ml
RL
1.0
1.0
1.0
1.0
5.0
25
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
10
1.0
1.0
1.0
1.0
1.0
2.0
Acceptance Limits
79-122
77 -120
75 -123
•
•
•
Client: ENSR International
Laboratory Control Sample -Batch: 680-26726
Lab Sample ID: LCS 680-26726/5 Analysis Batch:
Client Matrix: Water Prep Batch: N/A
Dilution: 1.0 Units: ug/L
Date Analyzed: 10/28/2005 1204
Date Prepared: 10/28/2005 1204
Analyte Spike Amount
Chloromethane 50.0
Bromomethane 50.0
Vinyl chloride 50.0
Chloroethane 50.0
Methylene Chloride 50.0
Acetone 100
Carbon disulfide 50.0
1, 1-Dichloroethene 50.0
1, 1-Dichloroethane 50.0
cis-1,2-Dichloroethene 50.0
trans-1,2-Dichloroethene 50.0
Chloroform 50.0
1,2-Dichloroethane 50.0
Methyl Ethyl Ketone 100
1, 1, 1-Trichloroethane 50.0
Carbon tetrachloride 50.0
Dichlorobromomethane 50.0
1, 1,2,2-Tetrachloroethane 50.0
1,2-Dichloropropane 50.0
trans-1,3-Dichloropropene 50.0
Trichloroethene 50.0
Chlorodibromomethane 50.0
1, 1,2-Trichloroethane 50.0
Benzene 50.0
cis-1,3-Dichloropropene 50.0
Bromoform 50.0
2~Hexanone 100
methyl isobutyl ketone 100
T etrachloroethene 50.0
Toluene 50.0
Chlorobenzene 50.0
Ethyl benzene 50.0
Styrene 50.0
Xylenes, Total 150
680-26726
Result
73
74
66
60
57
82
60
56
55
55
54
52
44
95
50
49
48
50
50
51
81
50
49
49
53
53
97
95
54
49
53
52
52
160
Quality Control Results
Job Number: 680-9679-1
Method: 8260B
Preparation: 5030B
Instrument ID: GC/MS Volatiles - P
Lab File ID: pq459.d
Initial WeighWolume: 5 ml
Final WeighWolume: 5 ml
%Rec. Limit Qual
146 51 -133
147 21 -176
132 59 -136
120 40 -171
113 67 -128
82 20 -183
119 60-130
113 64 -132
111 70 -127
109 69 -126
107 67 -130
103 74 -124
89 68 -130
95 51 -142
100 70 -132
98 64 -137
96 74 -128
101 71 -127
101 74 -123
102 75 -126
163 75 -122
100 75 -126
98 75 -122
97 74 -122
106 76 -126
107 64 -132
97 58 -139
95 62 -130
107 70 -133
98 75 -122
105 75 -123
104 77 -123
104 75 -125
108 77 -121
Calculations are performed before rounding to avoid round-off errors in calculated results.
STL Savannah Page10of11
•
•
•
Client: ENSR International
Method Blank • Batch: 680-26261
Lab Sample ID: MB 680-26261/1-A
Client Matrix: Water
Dilution: 1.0
Date Analyzed: 10/25/2005 0659
Date Prepared: 10/24/2005 0600
Analyte
Cyanide, Total
Analysis Batch: 680-26264
Prep Batch: 680-26261
Units: mg/L
Result
0.0050
Laboratory Control Sample -Batch: 680-26261
Lab Sample ID: LCS 680-26261/2-A
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
Analyte
Cyanide, Total
Water
1.0
10/25/2005 0659
10/24/2005 0600
Analysis Batch: 680-26264
Prep Batch: 680-26261
Units:mg/L
Spike Amount Result
0.0300 0.031
Qual
u
Quality Control Results
Job Number: 680-9679-1
Method: 335.4
Preparation: Distillation
Instrument ID: No Equipment Assigned
Lab File ID: NIA
Initial WeighWolume: 50 ml
Final WeighWolume: 50 ml
RL
0.0050
Method: 335.4
Preparation: Distillation
Instrument ID: No Equipment Assigned
Lab File ID: NIA
Initial WeighWolume: 50 ml
Final WeighWolume: 50 ml
%Rec. Limit Oual
104 90 • 110
Calculations are performed before rounding to avoid round-off errors in calculated results.
STL Savannah Page 11 of 11
August 5, 2005
Mr. Larry Thomas
City Engineer
City of Oxford
P.O. Box 1307
Oxford, North Carolina 27565
RE: Industrial Users Report for July 2005
ENSR International
7041 Old Wake Forest Road, Suite 103
Raleigh, NC 27616-3013
[phone]
FAX [phone]
www.ensr.com
JFD Electronics/Channel Master NPL Site, Oxford, North Carolina.
Dear Mr. Thomas:
On behalf of The Unimax Corporation and Avnet, Inc., ENSR. Consulting and Engineering (NC), Inc.
is submitting the Quarterly Industrial User Permit report for the months of May, June and July 2005.
This report is prepared in accordance with permit requirements for the discharge of treated
• groundwater at the above referenced site.
•
If you have any questions, please contact us at [phone].
Sincerely,
ENSR Consulting and Engineering (NC), Inc.
Gerald Y. Hornada , P.E.
Project Engineer
Enclosure
William H. Doucette, Jr., Ph.D.
Senior Program Manager
cc: Brian Kempner, The Unimax Corporation (w/o lab attachment)
S. Alan Lazar, Avnet, Inc. (w/o lab attachment)
Steve Earp, Smith Helms Muliss & Moore (w/o lab attachment)
David Mattison, NCDENR Superfund
Ken Lucas, USEPA Superfund
Nanjun Shetty, P.E., ENSR
File
Celebrating 30 Years of Excellence in Environmental Services
•
•
•
INDUSTRIAL USER REPORTING FORM
I.U. PERMIT NO: _ _,G""'0"'-01.,__ ____ DISCHARGE NO: ___ .:e.00,,_1,____ ____ _
MONTHS: _ _,.,M""a,_..y'"". J~u"'n""e_,,a""'nd"'"""Ju,,,_ly,___ ___ YEAR: -------~2,,c00,,,5"-------
I.U. NAME: JFD Electronics/Channel Master CLASS: COUNTY: Granville
OPERATOR IN RESPONSIBLE CHARGE (ORC): ENSR Consulting & Engineering {NC). Inc.
LABORATORY PERFORMING ANALYSIS: STL-Savannah Laboratories
PERSON(S) COLLECTING SAMPLES: Gerald Hornaday. P.E. {ENSR)
CHECK BLOCK IF ORC HAS CHANGED 0
SEND REPORT TO: City Engineer
City of Oxford
P.O. Box 1307
Oxford, NC 27565
Facility Status: (Please check one of the following)
All monthly averages and/or other limitations do meet permit monitoring requirements . ~
(Compliant)
All monthly averages and/or other limitations do not meet permit monitoring requirements. D
(Noncompliant)
Jfthe facility is noncompliant, please comment on corrective actions being taken in respect to
equipment, operation, maintenance, etc. and a time table for improvements to be made.
(Attach additional sheets if necessary)
I certify that this Report is accurate and
complete to the best of my knowledge: ~~~i~ R&;f;;!if9
William H. Doucette, Jr., Ph.D.
Date:
•
•
•
TABLE 1. GROUNDWATER REMEDIATION SYSTEM DISCHARGE MONITORING REPORT, CITY OF OXFORD, NORTH CAROLINA
I.U. PERMIT NO:
DISCHARGE NO:
MONTHS:
YEAR:
1.U. NAME:
COUNTY:
OPERATOR IN RESPONSIBLE CHARGE (ORC):
LABO RA TORY PERFORMING ANALYSIS:
PERSON(S) COLLECTING SAMPLES:
PARAMETER
Daily Average Flow (MGD)
Tetrachloroethylene
1, 1-0ichloroethane
cis-1,2 Dlchloroethene
Chlorobenzene
Toluene
1, 1-Dichloroethylene
trans-1,2 Dichloroethylene
Trichloroethene
Vinyl Chloride
Cyanide (total)
pH
Temperature
Monitoring requirement only.
MGD Million Gallons per day.
µg/L Micrograms per liter.
mg/L Milligrams per liter.
SU Standard Units.
°C Degrees Centigrade.
G001
001
May, June and July
2005
JFD Electronics/Channel Master NPL Site
Granville
ENSR Consulting & Engineering (NC), Inc.
STL Savannah Laboratories
Gerald Hornaday, P.E. (ENSR)
PERMIT LIMITS UNITS SAMPLE
Daily Maximum TYPE
0.040 MGO Meter
µg/L Grab
µg/L Grab
µg/l Grab
µg/L Grab
µg/L Grab
µgll Grab.
µg/L Grab
µg/L Grab
µg/L Grab
0.05 m9tL Grab
5.0 to 10.0 SU Grab
40 •c Grab
< Compound was not detected above the quantitation limit.
G:1Env\JFOCHANN\NC0202.170\City or Oxfonl\lURTable Aug 2005\Table 1\814/2005
LAB MONTHLY MEASUREMENT
METHOD DATES
05126105 06/15/05 07/20/05
Field 0.025 ci.015 0.025
8260 <1.0 <1.0 <1.0
8260 <1.0 <1.0 <1.0
8260 <1.0 <1.0 <1.0
8260 <1.0 <1.0 <1.0
8260 <1.0 <1.0 <1.0
8260 <1.0 <1.0 <1.0
8260 <1.0 <1.0 <1.0
8260 <1.0 <1.0 <1.0
8260 <1.0 <1.0 <1.0
335.2 <0.0050 <0.0050 0.0066
Field 8.49 7.77 7.80
Field 21.1 24.6 26.4
•
May 2005 Analytical Data
•
•
•
•
• Severn Trent Laboratories, Inc.
ANALYTICAL REPORT
Job Number: 680-4210.1
Job Description: Channel Master
For:
ENSR International
7041 Old Wake Forrest Road
Raleigh, NC 27616
Attention: Mr. Gerald Hornaday
Angie Weimerskirk
Project Manager I
[e-mail]
06/16/2005
STL Savannah 5102 LaRoche Avenue, Savannah, GA 31404
Tel [phone] Fax [phone] www.stl-inc.com
Page 1 of 10
•
Client: . ENSR International
Description
Matrix: Water
Volatile Organic Compounds by GCIMS
. Purge-and-Trap
Cyanide, Total (Semi-Automated Colorimetry)
Distillation/Cyanide
REFERENCES
METHOD SUMMARY
Job Number. 680-4210.1
Method Preparation Method
SW846 8260B
SW846 5030B
MCAVWV 335.4
Distillation .
MCAVWV • "Methods For Chemical Analysis Of Water And Wastes", EPA-60014-79-020, March 1983 And
Subsequent Revisions.
SW846 -''Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986
And Its Updates .
STL Savannah
Page 2 of 10
•
Client: ENSR International
Lab Sample ID Client Sample ID
680-4210-1 Effluent
•
•
STL Savannah
SAMPLE SUMMARY
Client Matrix
Water
Page 3 of 10
Date/Time
Sampled
05/26/2005 1513
Job Number. 680-4210.1
Date/Time
Received
05/2712005 0842
•
•
Client: ENSR International
Client Sample ID:
Lab Sample ID:
Client Matrix:
Effluent
680-421G-1
Water
Analytical Data
Job Number. 680-4210.1
Date Sampled: 05/26/2005 1513
Date Received: 05/27/2005 0842
8260B Volatile Organic Compounds by GCIMS
Method: 82608 Analysis Batch: 680-12072 Instrument ID: GC/MS Volatiles -0
Preparation: 50308 Lab File ID: 07797.d
Dilution: 1.0 Initial WeighWolume: 5 ml
Date Analyzed: 06/01/2005 1837 Final WeighWolume: 5 ml
Date Prepared: 06/01/2005 1837
Analyte Result (ug/L) Qualifier RL
Chlotomethane 1.0 u 1.0
Bromomethane 1.0 u 1.0
Vinyl chloride 1.0 u 1.0
Chloroethane 1.0 u 1.0
Methylene Chloride 1.0 u 1.0
Acetone 25 u 25
Carbon disulfide 1.0 u 1.0
1, 1-Dichloroethene 1.0 u 1.0
1, 1-Dichloroethane 1.0 u 1.0
cis-1,2-Dichloroethene 1.0 u 1.0
trans-1,2-Dichloroethene 1.0 u 1.0
Chloroform 1.0 u 1.0
1,2-Dichloroethane 1.0 u 1.0
Methyl Ethyl Ketone 10 u 10
1, 1, 1-Trichloroethane 1.0 u 1.0
Carbon tetrachloride 1.0 u 1.0
Dichlorobromomethane 1.0 u 1.0
1, 1,2,2-Tetrachloroethane 1.0 u 1.0
1,2-Dichloropropane 1.0 u 1.0
trans-1,3-Dichloropropene 1.0 u 1.0
Trichloroethane 1.0 u 1.0
Chlorodibromomethane 1.0 u 1.0
1, 1,2-Trichloroethane 1.0 u 1.0
Benzene 1.0 u 1.0
cis-1,3-Dichloropropene 1.0 ·u 1.0
Bromofonn 1.0 u 1.0
2-Hexanone 10 u 10
methyl isobutyl ketone 10 u 10
T etrachloroethene 1.0 u· 1.0
Toluene 1.0 u 1.0
Chlorobenzene 1.0 u 1.0
Ethylbenzene 1.0 u 1.0
Styrene 1.0 u 1.0
Xylenes, Total 2.0 u 2.0
Surrogate %Rec Acceptance Limits ·----·--------·---.. -·------
Toluene-dB 95 79 -122
4-Bromofluorobenzene 97 77 -120
Dibromofluoromethane 102 75 -123
STL Savannah
Page 4 of 10
•
•
•
Client: ENSR International
Client Sample ID:
Lab Sample ID:
Client Matrix:
Analyte
Cyanide, Total
STL Savannah
Effluent
680-4210-1
Water
Result
0.0050
Anly Batch: 680-11880
Prep Batch: 680-11878
General Chemistry
Qual Units
U mg/L
Date Analyzed 06/01/2005 1124
Date Prepared: 06/01/2005 0600
Page 5 of 10
Analytical Data
Job Number. 680-4210.1
Date Sampled:
Date Received:
RL
0.0050
05/26/2005 1513
05/27/2005 0842
Oil Method
1.0 335.4
•
•
Client: ENSR International
Lab Section
GC/MSVOA
General Chemistry
STL Savannah
Qualifier
u
•
u
N
DATA REPORTING QUALIFIERS
Job Number. 680-4210.1
Description
Analyte was not detected at or above the reporting limit.
LCS, LCSD, MS, MSD, MD, or Surrogate exceeds the control
limits
Analyte was not detected at or above the reporting limit.
MS, MSD: Spike recovery exceeds upper or lower control
limits .
Page 6 of 10
• Client: ENSR International
Surrogate Recovery Report
82608 Volatile Organic Compounds by GC/MS
Client Matrix: Water
Lab Sample ID
680-4210-1
LCS 680-1207211
MB 680-12072/2
Surrogate
Client Sample ID
Effluent
LCS
MB
(BFB)
(DBFM)
(TOL)
4-Bromofluorobenzene
Dibromofluoromethane
Toluene-dB
STL Savannah
(BFB) (DBFM) · (TOL)
(%Rec) (%Rec) (%Rec)
97
109
97
102
114
101
95
104
93
Acceptance Limits
77 -120
75 -123
79 -122
Page 7 of 10
Quality Control Results
Job Number. 680-4210.1
Client: ENSR International
8260B Volatile Organic Compounds by GC/MS
Method Blank -Batch: 680-12072
Lab ID: MB 680-12072/2 Date Analyzed: 06101/2005 1210
Matrix: Water Units: ug/L
Analyte Result Qualifier
Chloromethane 1.0 u
Bromomethane 1.0 u
Vinyl chloride 1.0 u
Chloroethane 1.0 u
Methylene Chloride 1.0 u
Acetone . 25 u
Carbon disulfide 1.0 u
1, 1-Dichloroethene 1.0 u
1, 1-Dichloroethane 1.0 u
cis-1,2-Dichloroethene 1.0 u
trans-1,2-Dichloroethene 1.0 u
Chloroform 1.0 u • 1,2-Dichloroethane 1.0 u
Methyl Ethyl Ketone 10 u
1, 1, 1-Trichloroethane 1.0 u
Carbon tetrachloride 1.0 u
Dichlorobromometharle 1.0 u
1, 1,2,2-Tetrachloroethane 1.0 u
1,2-Dichloropropane 1.0 u
trans-1,3-Dichloropropene 1.0 u
Trichloroethene 1.0 u
Chlorodibromomethane 1.0 u
1, 1,2-Trichloroethane 1.0 u
Benzene 1.0 u
cis-1,3-Dichloropropene 1.0 u
Bromoform 1.0 u
2-Hexanone 10 u
methyl isobutyl ketone 10 u
Tetrachloroethene 1.0 u
Toluene 1.0 u
Chlorobenzene 1.0 u
Ethylbenzene 1.0 u
Styrene 1.0 u
Xylenes, Total 2.0 u
Calculations are performed-before rounding to avoid round-off errors in calculated results.
STL Savannah
Page 8 of 10
Quality Control Results
Job Number. 680-4210.1
Dilution: 1.0
RL
1.0
1.0
1.0
1.0
1.0
25
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
10
1.0
1.0
1.0
1.0
1.0
2.0
• Quality Control Results
Client: ENSR International Job Number: 680-4210.1
82608 Volatile Organic Compounds by GC/MS
Laboratory Control Sample -Batch: 680-12072
lab ID: LCS 680-12072/1 Date Analyzed: 0610112005 1041 Dilution: 1.0
Matrix: Water Units: ug/L
Analyte Spike Result %Rec. Recovery Qualifier
Amount Limits
Chloromethane 20.0 19 93 51 -133
Bromomethane 20.0 19 93 21 -176
Vinyl chloride 20.0 22 111 59-136
Chloroethane 20.0 21 107 40-171
Methylene Chloride 20.0 21 104 67 -128
Acetone 40.0 36 89 20-183
Carbon disulfide 20.0 20 101 60-130
1, 1-Dichloroethene 20.0 22 112 64 -132
1, 1-Dichloroethane 20.0 21 103 70-127
cis-1,2-Dichloroethene 20.0 22 108 69 -126
trans-1,2-Dichloroethene 20.0 22 112 67 -130 • Chloroform 20.0 22 110 74 -124
1,2-Dichloroethane 20.0 20 98 68-130
Methyl Ethyl Ketone 40.0 33 84 51 -142
1, 1, 1-Trichloroethane 20.0 22 108 70 -132
Carbon tetrachloride 20.0 22 110 64 -137
Dichlorobromomethane 20.0 19 97 74 -128
1, 1,2,2-Tetrachloroethane 20.0 20 100 71 -127
1,2-Dichloropropane 20.0 18 90 74 -123
trans-1,3-Dichloropropene 20.0 18 92 75 -126
Trichloroethane 20.0 23 113 75 -.122
Chlorodibromomethane 20.0 23 117 75 -126
1, 1,2-Trichloroethane 20.0 19 93 75 -122
Benzene 20.0 19 95 74 -122
cis-1,3-Dichloropropene 20.0 18 92 76 -126
Bromoform 20.0 24 120 64-132
2-Hexanone 40.0 33 82 58-139
methyl isobutyl ketone 40.0 30 75 62 -130
T etrachloroethene 20.0 27 134 70-133
Toluene 20.0 20 101 75-122
Chlorobenzene 20.0 23 113 75 -123
Ethylbenzene 20.0 22 108 77 -123
Styrene 20.0 22 · 110 75-125
Xylenes, Total 60.0 69 114 77 -121
• Calculations are performed before rounding to avoid round-off errors in calculated results.
STL Savannah
Page 9 of 10
· Client: ENSR International
335.4 Cyanide, Total (Semi-Automated Colorimetry)
Method Blank -Batch: 680-11878
Lab ID: MB 680-11878/1-A Date Analyzed: 06/01/2005 1121
Matrix: Water Unrts: mg/L
Analyte Result Qualifier
Cyanide, Total 0.0050 u
Laboratory Control Sample/ Control Duplicate -Batch: 680-11878
LCS Lab ID: LCS 680-11878/2-A Date Analyzed: 06/01/2005 1121
LCSD Lab ID: LCSD 680-11878/3-A Date Analyzed: 06/01/2005 1122
Matrix: Water
% Recovery Recovery
Analyte LCS LCSD Limits • Cyanide, Total 91 92 90 -110
Matrix Spike/Spike Duplicate -Batch: 680-11878
MS Lab ID: 680-4210-E-1-A MS Date Analyzed: 06/01/2005 1124
MSD Lab ID: 680-4210-E-1-A MSD Date Analyzed: 06/01/2005 1125
Matrix: Water
% Recovery Recovery
Analyte MS MSD Limits
Cyanide, Total 115 109 90-110
• Calculations are performed before rounding to avoid round-off errors in calculated results.
STL Savannah
Page 10 of 10
Quality Control Results
Job Number. . 680-4210.1
Dilution: 1.0
RL
0.0050
Dilution: 1.0
Dilution: 1.0
RPO Qualifier RPO Limit
20
Dilution: 1.0
Dilution: · 1.0
RPO RPO Limit Qualifier
5 20 N
•
June 2005 Analytical Data
•
•
• Severn Trent Laboratories, Inc.
ANALYTICAL REPORT
Job Number: 680-4984-1
Job Description: Channel Master
For:
ENSR International
7041 Old Wake Forrest Road
Raleigh, NC 27616
Attention: Mr. Gerald Hornaday
Angie Weimerskirk
Project Manager I
[e-mail]
06/29/2005
STl Savannah 5102 LaRoche Avenue, Savannah, GA 31404
Tel [phone] Fax [phone] www.st~inc.com
Page 1 of 10
•
•
•
Client: ENSR International
Description
Matrix: Water
Volatile Organic Compounds by GC/MS
Purge-and-Trap
Cyanide, Total (Semi-Automated Colorimetry)
Distillation/Cyanide·
REFERENCES
METHOD SUMMARY
Job Number: 680-4984-1
Method Preparation Method
SW846 8260B
SW846 5030B
MCAWN 335.4
Distillation
MCAWN -"Methods For Chemical Analysis Of Water And Wastes", EPA-600/4-79-020, March 1983 And
Subsequent Revisions.
SW846. "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986
And Its Updates .
STL Savannah
Page 2 of 10
Client:. ENSR International
Lab Sample ID . Client Sample ID
6~984-1 Effluent
•
• STL Savannah
SAMPLE SUMMARY
Client Matrix
Water
Page 3 of 10
DatefTime
Sampled
06/1512005 1720
Job Number. 680-4984C1
DatefTime
Received
06/1712005 0910
•
•
•
Client: ENSR International
Client Sample ID:
Lab Sample ID:
Client Matrix:
Effluent
680-4984-1
Water
Analytical Data
Job Number: 680-4984-1
Date Sampled: 0611512005 1720
Date Received: 0611712005 0910
82608 Volatile Organic Compounds by GCIMS
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
82608
50308
1.0
06/2412005 1745
06/24/2005 17 45
Analyt~----
Chloromethane
Bromomethane
Vinyl chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1, 1-Dichloroethene
1, 1-Dichloroethane
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Chloroform
1,2-Dichloroethane
Methyl Ethyl Ketone.
1, 1, 1-Trichloroethane
Carbon tetrachloride
Dichlorobromomethane
1, 1,2,2-Tetrachloroethane
1,2-Dichloropropane
trans-1,3-Dichloropropene
Trichloroethene
Chlorodibromomethane
1, 1,2-Trichloroethane
Benzene
cis-1,3-Dichloropropene
Bromoform
2-Hexanone
methyl isobutyl ketone
T etrachloroethene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Xylenes, Total
Analysis Batch: 680-14548
Result (u.~._/L-'-) __
1.0
1.0
1.0
1.0
5.0
25
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
10
1.0
1.0
1.0
1.0
1.0
2.0
Instrument ID: GC/MS Volatiles -P
Lab File ID: p7247.d
Initial WeighWolume: 5 ml
Final WeighWolume: 5 ml
Qualifier
u
RL -=--.. -··--·-·. 1.0
u
u
u
u
u
u
u
u u
u
u
u u
u
u
u
u
u
u
u
u
u
u u
u
u
u
u
u u u
u
u
1.0
1.0
1.0
5.0
25
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
10
1.0
1.0
1.0
1.0
1.0
2.0
Surrogate %Rec Acceptance Limi1s --··--·--·-·--·---·---······ ··-·-·-----··--··--···•· -····-··········---------·•···-········-=:.:....:=c::c.-----T oluene-d8 94 79 -122
4-Bromofluorobenzene 94 77 -120
Dibromofluoromethane 92 75 -123
STL Savannah
Page 4 of 10
•
•
Client: ENSR International
Client Sample ID:
Lab Sample ID:
Client Matrix:
Analyte
.Cyanide, Total
STL Savannah
Effluent
68~984-1.
Water
Result
0.0050
Anly Batch: 680-13796
Prep Batch: 680-13756
General Chemistry
Qual · Units
U mg/L
Date Analyzed 06/21/2005 0453
Date Prepared: 06/20/2005 0700
Page 5 of 10
Analytical Data
Job Number: 680-4984-1
Date Sampled: 06/15/2005 1720
Date Received: 06/17/2005 0910
RL Dil Method
0.0050 1.0 335.4
•
•
•
Client: ENSR International
Lab Section
GC/MSVOA
General Chemistry
STL Savannah
Qualifier
u
u
N
DATA REPORTING QUALIFIERS
Job Number. 680-4984-1
Description
Analyte was not detected at or above the reporting limtt.
Analyte was not detected at or above the reporting limtt.
MS, MSD: Spike recovery exceeds upper or lower control
limits .
Page 6 of 10
•
Client: ENSR International
Surrogate Recovery Report
8260B Volatile Organic Compounds by GC/MS
Client Matrix: Water·
Lab Sample 10 Client Sample
680-4984-1
LCS 680-14548/7
MB 680-14548/8
Effluent
LCS
MB
Surrogate
(BFB)
(DBFM)
(TOL)
4-Bromofluorobenzene
Dibromofluoromethane
ToluenM8
STL Savannah
(BFB)
(%Rec)
94
91
91
(DBFM)
(%Rec)
92
92
96
(TOL)
(%Rec)
94
88
96
Acceptance Limits
77 · 120 .
75 -123
79 -122
Page 7 of 10
Quality Control Results
Job Number: 68(µ984-1
• Client: ENSR International
82608 Volatile Organic Compounds by GC/MS
Method Blank -Batch: 680-14548
Lab ID: MB 680-14548/8 Date Analyzed: 06/24/2005 1140
Matrix: Water Units: ug/L
Analyte Result Qualifier
Chloromethane 1.0 u
Bromomethane 1.0 u
Vinyl chloride . 1.0 u
Chloroethane 1.0 u
Methylene Chloride 5.0 u
Acetone 25 u
Carbon disulfide 1.0 u
1, 1-Dichloroethene 1.0 u
1, 1-Dichloroethane 1.0 u
cis-1,2-Dichloroethene 1.0 u
trans-1,2-Dichloroethene 1.0 u
Chloroform 1.0 u
1,2-Dichloroethane 1.0 u • Methyl Ethyl Ketone 10 u
1, 1, 1-Trichloroethane 1.0 u
Carbon tetrachloride 1.0 u
Dichlorobromomethane 1.0 u
1, 1,2,2-T etrachloroethane 1.0 u
1,2-Dichloropropane 1.0 u
trans-1,3-Dichloropropene 1.0 u
Trichloroethene 1.0 u
Chlorodibromomethane 1.0 u
1, 1,2-Trichloroethane 1.0 u
Benzene 1.0 u
cis-1,3-Dichloropropene 1.0 u
Bromoform 1.0 u
2-Hexanone 10 u
methyl isobutyl ketone 10 u
Tetrachloroethene 1.0 u
Toluene 1.0 u
Chlorobenzene 1.0 u
Ethylbenzene 1.0 u
Styrene 1.0 u
Xylenes, Total 2.0 u
• Calculations are performed before rounding to avoid round-off errors in calculated results.
STL Savannah
Page 8 of 10
Quality Control Results
Job Number. 680-4984-1
Dilution: 1.0
RL
1.0
1.0
1.0
1.0
5.0
25
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
10
1.0
1.0
1.0
1.0
1.0
2.0
• Quality Control Results
Client: ENSR International Job Number. 680-4984-1
82608 Volatile Organic Compounds by GC/MS
Laboratory Control Sample • Batch: 680-14548
Lab ID: LCS 680-14548/7 Date Analyzed: 06/24/2005 1044 Dilution: 1.0
Matrix: Water Units: ug/L
Analyte Spike Result %Rec. Recovery Qualifier
Amount Limits
Chloromethane 50.0 43 86 51 -133
Bromomethane 50.0 47 95 21 -176
Vinyl chloride 50.0 48 96 59 -136
Chloroethane 50.0 48 95 40 -171
Methylene Chloride 50.0 46 93 67 -128
Acetone 100 70 70 20 -183
Carbon disulfide 50.0 48 95 60 -130
. 1, 1-Dichloroethene · 50.0 46 91 64 -132
1, 1-Dichloroethane 50.0 47 94 70 -127
cis-1,2-Dichloroethene 50.0 47 93 69 • 126
trans-1,2-Dichloroethene 50.0 44 88 67 -130 • Chlorofonn 50.0 46 92 74 • 124
1,2-Dichloroethane 50.0 46 91 68 -130
Methyl Ethyl Ketone 100 82 82 51 • 142
1, 1, 1-Trichloroethane 50.0 45 91 70-132
Carbon tetrachloride 50.0 47 93 64 -137
Dichlorobromomethane 50.0 45 91 74 -128
1, 1,2,2-Tetrachloroethane 50.0 49 99 71 -127
1,2-Dichloropropane 50.0 45 90 74 • 123
trans-1,3-Dichloropropene 50.0 47 94 75 -126
Trichloroethene 50.0 47 93 75 -122
Chlorodibromomethane 50.0 50 100 75 -126
1, 1,2-Trichloroethane 50.0 46 91 75 -122
Benzene · 50.0 45 91 74 -122
cis-1,3-Dichloropropene 50.0 46 92 76 -126
Bromofonn 50.0 50 101 64 -132
2-Hexanone 100 92 92 58 -139
methyl isobutyl ketone 100 90 90 62 -130
Tetrachloroethene 50.0 50 100 70 -133
Toluene 50.0 44 89 75. 122
Chlorobenzene 50.0 48 95 75 -123
Ethylbenzene 50.0 47 94 77 -123
Styrene 50.0 48 96 75 -125
Xylenes, Total 150 140 96 77 • 121
• Calculations are performed before rounding to avoid round-off errors in calculated results.
STL Savannah
Page 9 of 10
• Client: ENSR International
335.4 Cyanide, Total (Semi-Automated Colorimetry)
Method Blank -Batch: 680-13756
Lab ID: MB 680-13756/1-A Date Analyzed: 06/21/2005 0448
Matrix: Water Units: mg/L
Analyte Result Qualifier
Cyanide. Total 0.0050 u
Laboratory Control Sample/ Control Duplicate -Batch: 680-13756
LCS Lab ID: LCS 680-13756/2-A Date Analyzed: 06/21/2005 0448
LCSD Lab ID: LCSD 680-13756/3-A Date Analyzed: 06/21/2005 0451
Matrix: Water
% Recovery Recovery
Analyte LCS LCSD Limits • Cyanide, Total 91 92 90 -110
Matrix Spike/Spike Duplicate -Batch: 680-13756
MS Lab ID: 680-4984-E-1-A MS Date Analyzed: 06/21/2005 0453
MSD Lab ID: 680-4984-E-1-A MSD Date Analyzed: 06/21/2005 0453
Matrix: Water
% Recovery Recovery
Analyte MS MSD Limits
Cyanide, Total 111 112 90 -110
• Calculations are performed before rounding to avoid round-off errors in calculated results.
STL Savannah
Page 10 of 10
Quality Control Results
Job Number. 680-4984-1
Dilution:· 1.0
RL
0.0050
Dilution: . 1.0
Dilution: 1.0
RPD Qualifier RPD Lim~
20
Dilution: 1.0
Dilution: 1.0
RPD RPD Limit Qualifier
20 N N
ANALYSIS REQUEST AND CHAIN OF CUSTODY RECORD
SEVERN
TRENT
PROJECT REFERENCE
/O/'f(J-o;'f. -IO lo
RELINQUISHED BY: !SIGNATURE)
STL
PROJECT NO. PROJECT LOCATION
(STATE) c_ MATRIX
TYPE
P.O. NUMBER CONTRACT NO.
DATE TIME RELINQUISHED BY: tSIGNATUREJ
Serial Number 519 9 6
STL Savannah
5102 LaRoche Avenue
Savannah, GA 31404
0 Alternate Laboratory Name/Location
REQUIREO ANALYSIS
Website: www.stl-inc.com
Phone: [phone]
Fax: [phone]
Phone:
Fax:
PAGE / OF /
NUMBER OF CONTAINERS SUBMITTED REMARKS
TIME
t)f:So
TIME
RELINQUISHED BY: tSIGNATUREJ
RECEIVED BY: (SIGNATURE)
OATE TIME
OATE TtME
Tl8240-680 (12/02)
•
July 2005 Analytical Data
•
•
•
•
Severn Trent Laboratories, Inc.
ANALYTICAL REPORT
Job Number: 680-6208-1
Job Description: Channel Master
For:
ENSR International
7041 Old Wake Forrest Road
Raleigh, NC 27616
Attention: Mr. Gerald Hornaday
Kathryn Smith
Project Manager I
08/04/2005
STL Savannah 5102 LaRoche Avenue, Savannah, GA 31404
Tel [phone] Fax [phone] www.stl-inc.com
Page 1 of 10
•
•
• Client: . ENSR International
Description
Matrix: Water
Volatile Organic Compounds by GCIMS
Purge-and-Trap
Cyanide, Total (Semi-Automated Colorimetry)
Distillation/Cyanide
LAB REFERENCES:
STL-SAV = STL-Savannah
METHOD REFERENCES:
METHOD SUMMARY
Lab Location Method
STL-SAV
STL-SAV
STL-SAV
STL-SAV
SW846 8260B
MCAWW 335.4
Job Number: 680-6208-1
Preparation Method
SW846 5030B
Distillation
MCAWW -"Methods For Chemical Analysis Of Water And Wastes", EPA-60014-79-020, March 1983 And
Subsequent Revisions .
SW846 -'Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986
And Its Updates .
STL Savannah
Page 2 of 10
Client: ENSR International
Lab Sample ID . Client Sample ID
680-6208-1 Effluent
•
• STL Savannah
SAMPLE SUMMARY
Client Matrix
Water
Page 3 of 10
Date/Time
Sampled
07/20/2005 1625
Job Number: 680-6208-1
Date/Time
Received
07/22/2005 1028
•
•
Client: ENSR International
Client Sample ID:
Lab Sample ID:
Client Matrix:
Effluent
680-6208-1
Water
Analytical Data
Job Number: 68~208-1
Date Sampled: 07/20/2005 1625
Date Received: 07 /2212005 1028
. 8260B Volatile Organic Compounds by GC/MS
Method: 8260B
5030B
1.0
Analysis Batch: 680-17706 Instrument ID: GC/MS Volatiles -

P

Preparation:
Dilution:
Date Analyzed:
Date Prepared:
07/30/2005 2216
07/30/2005 2216
lln_alyt~----·-------·-·-._.,.
Chloromethane
Bromomethane
Vinyl chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1, 1-Dichloroethene
1, 1-Dichloroethane
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Chloroform
1,2-Dichloroethane
Methyl Ethyl Ketone
1, 1, 1-Trichloroethane
Carbon tetrachloride
Dichlorobrcimomethane
1, 1,2,2-Tetrachloroethane
1,2-Dichloropropane
trans-1,3-Dichloropropene
Trichloroethene
Chlorodibromomethane
1, 1,2-Trichloroethane
Benzene
cis-1,3-Dichloropropene
Bromoform
2-Hexanone
methyl isobutyl ketone
T etrachloroethene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Xylenes, Total
Surrogate----·--··-·-... ----·····•-·--··-···---·-··
Toluene-dB
4-Bromofluorobenzene
Dibromofluoromethane
STL Savannah
Lab File ID: p8102.d
Initial WeighWolume: 5 ml
Final WeighWolume: 5 · ml
___ Result (ug/L) __ ---· Qualifier RL "-·--·--------····-··· ···-····--···•-""•-·····-, .......... ,.. ., ... ------··-··---
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
5.0 u 5.0
25 u 25
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
10 u 10
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
10 u 10
10 u 10
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
1.0 u 1.0
2.0 u 2.0
%Rec _ ---•·--_ ·-----··---·-------------Acceptance Limits _____ ----·•--.•--·-·-·--··--··· 89 79-122
90 77 -120
97 75 -123
Page 4 of 10
•
•
Client: ENSR International
Client Sample ID:
Lab Sample ID:
Client Matrix:
Analyte
Cyanide, Total
STL Savannah
Effluent
680-6208-1
Water
Result
0.0066
Anly Batch: 68CJ..17073
Prep Batch: 680-17071
General Chemistry
Qual Units
mgll
Date Analyzed 07/2612005 0904
Date Prepared: 07/25/2005 0730
Page 5 of 10
Analytical Data
Job Number: 680-6208-1
Date Sampled: 07/20/2005 1625
Date Received: 0712212005 1028
RL Oil Method
0.0050 1.0 335.4
•
DATA REPORTING QUALIFIERS
Client ENSR International Job Number: 680-6208-1
Lab Section Qualifier Description
GC/MSVOA
u Analyte was not detected at or above the reporting limit.
General Chemistry
u Analyte was not detected at or above the reporting limlt.
•
STL Savannah
Page 6 of 10
•
•
•
Client: ENSR International
Surrogate Recovery Report
82608 Volatile Organic Compounds by GC/MS
Client Matrix: Water
Lab Sample ID Client Sample
680-6208-1
LCS 680-17706/3
MB 680-17706/4
Effluent
LCS
MB
Surrogate
(BFB)
(DBFM)
(TOL)
4-Bromofluorobenzene
Dibromofluoromethane
Toluene-dB
STL Savannah
(BFB)
(%Rec)
90
100
93
(DBFM)
(%Rec)
97
99
100
(TOL)
(%Rec)
89
92
91
Acceptance Limits
77 • 120
75 • 123
79 · 122
Page 7 of 10
Quality Control Results
Job Number: 680-6208-1
•
•
Client: ENSR International
Method Blank -Batch: 680-17706
Lab Sample ID: MB 680-17706/4
Client Matrix: Water
Dilution: 1.0
Date Analyzed: 07/30/2005 1420
Date Prepared: 07/30/2005 1420
Analyte
Chloromethane
Bromomethane
Vinyl chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1, 1 -Dichloroethene
1, 1-Dichloroethane
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Chloroform
1,2-Dichloroethane
Methyl Ethyl Ketone
1, 1, 1-Trlchloroethane
Carbon tetrachloride
Dichlorobromomethane
1, 1,2,2-Tetrachloroethane
1,2-Dichloropropane
trans-1, 3-0ichloropropene
T richloroethene
Chlorodibromomethane
1, 1,2-Trichloroethane
Benzene
cis-1,3-Dichloropropene
Bromoform
2-Hexanone
methyl isobutyl ketone
T etrachloroethene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Xylenes, Total
~~rr?.~~t: ..
Toluene-dB
4-Bromofluorobenzene
Dibromofluoromethane
Analysis Batch: 680'17706
Prep Batch: N/A
Units: ug/L
Result
1.0
1.0
1.0
1.0
5.0
25
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
·1.0
1.0
1.0
1.0
1,0
1.0
1.0
1.0
1,0
1.0
1,0
1.0
10
10
1.0
1.0
1,0
1.0
1.0
2.0
% Rec
91
93
100
Qual u ...
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
u
Calculations are performed before rounding to avoid round-off errors in calculated results.
STL Savannah Page 8 of 10
Quality Control Results
Job Number: 680-6208.-1
Method: 8260B
Preparation: 5030B
Instrument ID: GC/MS Volatiles • P
Lab File ID: pq281.d.
Initial WeighWolume: 5 ml
Final WeighWolume: 5 ml
RL
•••"•-• •••"' '" "" -•• • . s.••• _, -••• • M • • ·• "••--•~•-••••-•• ••••-•••-
' flcceptan~ LilTli_ts .
79 -122
77 -120
75 -123
1, 0
1.0
1.0
1.0
5,0
25
.1.Q
1.0
1.0
1.0
1.0
1.0
1.0
10
1,0
1.0
1.0.
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
10
1.0
1.0
1.0
. 1.0
1.0
2.0
•
•
•
Client: ENSR International
Laboratory Control Sample -Batch: 680-17706
Lab Sample ID: LCS 680-17706/3
Client Matrix: Water
Dilution: 1.0
Date Analyzed: 07/30/2005 1332
Date Prepared: 07/30/2005 1332
Analyte
···--"" ....... -"'"'•·"·--·-··-·--··
Chloromethane
Bromomethane
Vinyl chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1, 1-Dichloroethene
1, 1-Dichloroethane
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene.
Chlorofonm
1,2-Dichloroethane
Methyl Ethyl Ketone
1, 1, 1-Trichloroethane
Carbon tetrachloride
Dichlorobromomethane
1, 1,2,2-Tetrachloroethane
1,2-Dichloropropane
trans-1,3-Dichloropropene
Trichloroethene
Chlorodibromomethane
1, 1,2-Trichloroethane
Benzene
cis-1,3-Dichloropropene
Bromoform
2-Hexanone
methyl isobutyl ketone
T etrachloroethene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Xylenes, Total
Analysis Batch: 680-17706
Prep Batch: NIA
Units: ug/L
Spike Amount Result
50.0 45
50.0 57
50.0 45
50.0 47
50.0 48
100 76
50.0 47
50.0 45
50.0 46
50.0 48
50.0 44
50.0 47
50.0 46
100 80
50.0 49
50.0 47
50.0 46
50.0 53
50.0 45
50.0 52
50.0 47
50.0 54
50.0 45
50.0 45
50.0 45
so.a 55
100 92
100 86
50.0 56
50.0 46
50.0 53
50.0 52
50.0 52
150 160
Quality Control Results
Job Number. 68~208-1
Method: 8260B
Preparation: 5030B
Instrument ID: GC/MS Volatiles -P
Lab File ID: pq279.d
Initial WeightNolume: 5 ml
Final WeightNolume: 5 ml
% Rec. Limit Qual
·-... , . ······---····-···
90 51 • 133
113 21 -176
90 59-136
93 40 • 171
96 67 -128
76 20 -183
95 60 -130
90 64 • 132
92 70 • 127
97 69 • 126
89 67 -130
94 74 • 124
93 68 -130
80 51 -142
98 70 -132
94 64 -137
93 74 -128
106 71 • 127
89 74 -123
104 75 • 126
94 75 • 122
108 75 • 126
90 75 -122
91 74 -122
90 76-126
110 64 -132
92 58 -139
86 62 -130
112 70 -133
92 75 • 122
107 75 -123
104 77 -123
103 75 • 125
104 77 • 121
Calculations are performed before rounding to avoid round-off errors in calculated results.
STL Savannah Page 9 of 10
•
•
Client: ENSR International
Method Blank -Batch: 680-17071
Lab Sample ID: MB 680-17071/1-A
Client Matrix: Water
Dilution: 1.0
Date Analyzed: 07/26/2005 0854
Date Prepared: 07/25/2005 0730
Analyte
Cyanide, Total
Analysis Batch: 680-17073
Prep Batch: 680-17071
Units: mg/L
Result
Laboratory Control Sample -Batch: 680-17071
. Lab Sample ID: LCS 680-17071/2-A
Client Matrix: Water
Dilution: 1.0
Date Analyzed: 07126/2005 0854
Dale Prepared: 07/25/2005 0730
Analyte
Cyanide, Total
Analysis Batch: 680-17073
Prep Batch: 680-17071
Units:mg/L
Spike Amount
0.0300
Result
··-· 0.032
Qual
Quality Control Results
Job Number: 680-6208-1
Method: 335.4
Preparation: Distillation
Instrument ID: Lachet Ouickchem -LT
lab File ID: N/A
Initial WeighWolume: 50 ml
Final WeighWolume: 50 ml
RL
Method: 335.4
Preparation: Distillation
Instrument ID: lachet Ouickchem -LT
Lab File ID: NIA
Initial WeighWolume: 50 ml
Final WeighWolume: 50 ml
% Rec.
106
Limit
···•··
90 -110
Qual
Calculations are periormed before rounding to avoid round-off errors in calculated results.
STL Savannah Page 10 of 10
• ANALYSIS REQUEST AND CHAIN OF CUSTODY RECORD
STL
PROJECT NO. PROJECT LO ATION
(STATE) L MATRIX
TYPE
L-..J.~~~~:_ _____ L~~~~~~~1:.a>~~U,4.Jl-~~::.~-:'J=i g -~ CLIENT ADDRE~J .J
70'1-1 o~IAJ~~
COMPANY CONTRACTING THIS WORK (if applicable) ?,. 7L,
"' 0 w "' ... "
. Serial Nuniber 519 9 7
STL Savannah
5102 LaROche Avenue
Savannah, GA 31404
0 Alternate Laboratory Name;1._ocation
REQUIRED ANALYSIS
Website: www.stHnc.com
· Phone: [phone]
Fax: [phone]
Phone:
Fax:
PAGE
,·
J OF I
SAMPLE SAMPLE IDENTIFICATION NUMBER OF CONTAINERS SUBMITTED REMARKS
RELINQUISHED BY: iSK;NATUREI DATE TIME DATE TIME. RELINQUISHED BY: i~GNATUREI DATE TIME
OtYo
RECEIVED BY: !SIGNATURE! RECEIVED BY: (SIGNATURE! DATE TIME
···::LABORATORY USE ONLY:.:
RECEIVED FOR LABORATORY BY: ·
(SIGNATURE)
.CUSTODY INTACT . CUSTODY : · YES : C) SEAL NO •.
NO ··o·
STl8240-680 u;
•
•
ENSR International
7041 Old Wake Forest Road, Suite 103
Raleigh, NC 27616-3013
[phone]
FAX [phone]
www.ensr.com
May 12, 2005
Mr. Larry Thomas
City Engineer
City of Oxford
P.O. Box 1307
Oxford, North Carolina 27565
RE: Industrial Users Report for April 2005
suPERfU\\\0 SEC110N
JFD Electronics/Channel Master NPL Site, Oxford, North Carolina.
Dear Mr. Thomas:
On behalf of The Unimax Corporation and Avnet, Inc., ENSR Consulting and Engineering (NC), Inc.
is submitting the Quarterly Industrial User Permit report for the months of February, March and April
2005. This report is prepared in accordance with permit requirements for the discharge of treated
groundwater at the above referenced site.
If you have any questions, please contact us at [phone].
Sincerely,
ENSR Consulting and Engineering (NC), Inc.
Gerald Y. Hornad
Project Engineer
Enclosure
William H. Doucette, Jr., Ph.D.
Senior Program Manager
cc: Brian Kempner, The Unimax Corporation (w/o lab attachment)
S. Alan Lazar, Avnet, Inc. (w/o lab attachment)
Steve Earp, Smith Helms Muliss & Moore (w/o lab attachment)
David Mattison, NCDENR Superfund
Ken Lucas, USEPA Superfund
Nanjun Shetty, P.E., ENSR
File
Celebrating 30 Years of Excellence in Environmental Services
•
•
INDUSTRIAL USER REPORTING FORM
I.U. PERMIT NO: G001 DISCHARGE NO: ___ """'00=-1,_ ____ _
MONTHS: February, March, and April YEAR: 2005
LU. NAME: JFD Electronics/Channel Master CLASS: COUNTY: Granville
OPERA TOR IN RESPONSIBLE CHARGE (ORC): ENSR Consulting & Engineering (NC), Inc.
LABORATORY PERFORMING ANALYSIS: STL-Savannah Laboratories
PERSON(S) COLLECTING SAMPLES: Gerald Hornaday, P.E. /ENSR)
CHECK BLOCK IF ORC HAS CHANGED 0
SEND REPORT TO: City Engineer
City of Oxford
P.O. Box 1307
Oxford, NC 27565
Facility Status: (Please check one of the following)
All monthly averages and/or other limitations do meet permit monitoring requirements. ~
(Compliant)
All monthly averages and/or other limitations do not meet permit monitoring requirements. D
(Noncompliant)
If the facility is noncompliant, please comment on corrective actions being taken in respect to
equipment, operation, maintenance, etc. and a time table for improvements to be made.
(Attach additional sheets if necessary)
I certify that this Report is accurate and
complete to the best of my knowledge:
\~~-H &~
Signature of Permittee Representative
William H. Doucette, Jr., Ph.D.
Date:
•
•
•
TABLE 1. GROUNDWATER REMEDIATION SYSTEM DISCHARGE MONITORING REPORT, CITY OF OXFORD, NORTH CAROLINA
I.U. PERMIT NO:
DISCHARGE NO:
MONTHS:
YEAR:
1.U. NAME:
COUNTY:
OPERATOR IN RESPONSIBLE CHARGE (ORC):
LABORATORY PERFORMING ANALYSIS:
PERSON($) COLLECTING SAMPLES:
PARAMETER
Dally Average Flow (MGD)
Tetrachloroethylene
1, 1-Dichloroethane
cla-1,2 Olchloroethene
Chlorobenzene
Toluene
1, 1•Dlchloroethylene
trans•1,2 Dlchloroethylene
Trichloroethane
Vinyl Chloride
Cyanide (total)
pH
Temperature
Monitoring requlrement only.
MGD Million Gallons per day.
µg/L Micrograms per liter.
mg/L Milligrams per titer.
SU Standard Units.
"C Degrees Centigrade.
G001
001
February, March and April
2005
JFD Electronics/Channel Master NPL Site
Granville
ENSR Consulting & Engineering (NC), Inc.
STL Savannah Laboratories
Gerald Hornaday, P.E. (ENSR)
PERMIT LIMITS UNITS SAMPLE
Dally Maximum TYPE
0.040 MGO Meter
µg/L Grab
µg/L Grab
µg/L Grab
µg/l Grab
µg/L Grab
µg/L Grab
µg/L Grab
µg/L Grab
µg/L Grab
0.05 mg/l Grab
5.0 to 10.0 SU Grab
40 'C Grab
< Compound was not detected above the quantitation limit.
G:\EnvUF0CHANN\NC0202.170\Cily of Ox1ord\lURTabla May 2005\Tabla 1\5/12/2005
LAB MONTHLY MEASUREMENT
METHOD OATES
02/22/05 03/24105 04118/05
Field 0.024 0.029 0.026
6260 <1.0 <1.0 <1.0
8260 <1.0 <1.0 <1.0
8260 <1.0 <1.0 <1.0
8260 <1.0 <1.0 <1.0
8260 <1.0 <1.0 <1.0
8260 <1.0 <1.0 <1.0
8260 <1.0 <1.0 <1.0
8260 <1.0 <1.0 <1.0
8260 <1.0 <1.0 <1.0
335.2 <0.0050 0.0070 0.0058
Field 7.60 7.79 7.2
Field 18.3 18.4 20.6
•
February 2005 Analytical Data
•
•
•
Severn Trent Laboratories, Inc.
ANALYTICAL REPORT
Job Number: 680-685.1
Job Description: Channel Master
For:
ENSR International
7041 Old Wake Forrest Road
Raleigh, NC 27616
Attention: Mr. Gerald Hornaday
Project Manager I
[e-mail]
03/11/2005
STL Savannah 5102 LaRoche Avenue, Savannah, GA 31404
Tel [phone] Fax [phone] www stl-inc com
Page 1 of 17
•
•
•
Client: ENSR International
Description
Matrix: Water
Volatile Organic Compounds by GC/MS
Purge-and-Trap
Cyanide, Total (Semi-Automated Colorimetry)
Distillation/Cyanide
REFERENCES
METHOD SUMMARY
Job Number: 680-685.1
Job Description: Channel Master
Method Preparation Method
SW846 8260B
SW846 5030B
MCAWW 3354
NONE Distillation
MCAWW-"Methods For Chemical Analysis Of Water And Wastes", EPA-600/4-79-020, March 1983 And Subsequent
Revisions.
SW846 -"Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And
Its Updates .
STL Savannah
Page 2 of 17
Client: ENSR International
Lab Sample ID Client Sample ID .·
680-685-1 Effluent
680-685-2 Trip Blank
•
• STL Savannah
SAMPLE SUMMARY
Client Matrix
Water
Water
Page 3 of 17
Date/Time
Sampled
02/22/2005 1530
02122/2005 0000
Job Number: 680-685.1
Job Description: Channel Master
Date/Time
Received
02123/2005 0911
02/23/2005 0911
SAMPLE RESULTS
•
STL Savannah
Page 4 of 17
•
•
•
Client: ENSR International
Client Sample ID:
Lab Sample ID:
Client Matrix:
Effluent
680-685-1
Waler
Analytical Data
Job Number: 680-685.1
Dale Sampled: 02122/2005 1530
Date Received: 02123/2005 0911
8260B Volatile Organic Compounds by GC/MS
Method: 82608 Analysis Batch: 680-2104
Preparation:
Dilution:
Dale Analyzed:
Date Prepared:
50308
1.0
03/01/2005 1256
NIA
Analyte
Chloromethane
Bromomethane
Vinyl chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1, 1-Dichloroelhene
1, 1-Dichloroelhane
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Chloroform
1,2-Dichloroethane
Methyl Ethyl Ketone
1, 1, 1-Trichloroethane
Carbon tetrachloride
Dichlorobromomethane
1, 1,2,2-Tetrachloroelhane
1,2-Dichloropropane
trans-1,3-Dichloropropene
Trichloroethene
Chlorodibromomethane
1, 1,2-Trichloroethane
Benzene
cis-1,3-Dichloropropene
Bromoform
2-Hexanone
methyl isobutyl ketone
Telrachloroethene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Xylenes, Total
Surrogate
Result (ug/L)
1.0
1.0
1.0
1.0
1.0
25
1.0
1.0
1 0
1.0
1.0
1 0
1 0
10
1.0
10
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1 0
10
10
1.0
1.0
1.0
1.0
1.0
2.0
%Rec
Instrument ID: GC/MS Volatiles -P
Lab File ID: p4463 d
lnttial WeighWolume: 5 ml
Final WeighWolume: 5 ml
Qualifier RL
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 25
u 1 0
u 1.0
u 1.0
u 1.0
u 1.0 u 1.0
u 1.0 u 10
u 1.0
u 1.0
u 1.0 u 1.0
u 1.0
u LO u 1 0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0 u 10
u 10
u 1.0 u 1.0
u 1.0
u 1.0
u 1.0 u 2.0
Qualifier Acceptance Limits
... -·-··"··-··-.. •• •~••" ••••" ·••-••n••• •• ••• . ·······--······-·-----·--···-·-··-.. ··-·· ----. -----...... ---·-···. ·-·---·--···········--··-··------··
STL Savannah
Page 5 of 17
•
•
Client: ENSR International
Client Sample ID:
Lab Sample ID:
Client Matrix:
Effluent
680-685-1
Water
Analytical Data
Job Number: 680-685 1
Date Sampled: 02/22/2005 1530
Date Received: 02/23/2005 0911
8260B Volatile Organic Compounds by GC/MS (Continued)
Method: 8260B Analysis Batch: 680-2104
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
50308
1.0
03/01/2005 1256
N/A
Toluene-dB
4-Bromofluorobenzene
Dibromofluoromethane
STL Savannah
108
92
104
Page 6 of 17
Instrument ID: GC/MS Volatiles • P
Lab File ID: p4463 .d
Initial WeighWolume: 5 ml
Final WeighWolume: 5 ml
79 -122
77 -120
75 -123
•
•
•
Client: ENSR International
Client Sample ID:
Lab Sample ID:
Client Matrix:
Trip Blank
680-685-2
Water
Analytical Data
Job Number: 680-685.1
Date Sampled: 02/22/2005 0000
Date Received: 02/23/2005 0911
8260B Volatile Organic Compounds by GC/MS
Method: 82608 Analysis Batch: 680-1989 Instrument ID: GC/MS Volatiles -P
Preparalion:
Dilution:
Date Analyzed:
Dale Prepared:
Analyte
50308
1.0
02/28/2005 1351
N/A
Chloromethane
Bromomethane
Vinyl chloride
Chloroethane
Methylene Chloride
Acetone
Carbon disulfide
1, 1-Dichloroethene
1, 1-Dichloroethane
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Chloroform
1,2-Dichloroethane
Methyl Ethyl Ketone
1,1, 1-Trichloroethane
Carbon tetrachloride
Dichlorobromomethane
1, 1,2,2-Tetrachloroethane
1,2-Dichloropropane
trans-1,3-Dichloropropene
Trichloroethene
Chlorodibromomethane
1, 1,2-T richloroethane
Benzene
cis-1,3-Dichloropropene
Bromoform
2-Hexanone
methyl isobutyl ketone
Tetrachloroethene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Xylenes, Total
Surrogate
STL Savannah
Result (ug/L)
1.0
10
10
1.0
1.0
25
1 0
1.0
1.0
1.0
1.0
10
1 0
10
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1 0
1.0
1.0
1.0
1.0
10
10
1.0
1.0
1.0
1.0
10
2.0
%Rec
Lab File ID: p4424 d
Initial WeighWolume: 5 ml
Final WeighWolume: 5 ml
Qualifier RL
-··--·-------u 1 0
u 1 0
u 1.0
u 1.0
u 1.0
u 25
u 1 0
u 1.0
u 10
u 1.0
u 1.0
u 1 0
u 1.0
u 10
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 1 0
u 1 0
u 1.0
u 1.0
u 1.0
u 1.0
u 10
u 10
u 1.0
u 1.0
u 1.0
u 1.0
u 1.0
u 2.0
Qualifier Acceptance Limits
···--···-·-····-··-···········--.. ,, ......... _, _________ --·---....... --· ·-·-····-.' . ·-··· .... -. ---......
Page 7 of 17
•
•
Client: ENSR International
Client Sample ID:
Lab Sample ID:
Client Matrix:
Trip Blank
680-685-2
Water
Analytical Data
Job Number: 680-685.1
Date Sampled: 02/22/2005 0000
Date Received: 02/23/2005 0911
82608 Volatile Organic Compounds by GC/MS (Continued)
Method: 82608 Analysis Batch: 680-1989 Instrument ID: GC/MS Volatiles • P
Preparation: 50308 Lab File ID: p4424.d
Dilution: 1.0 Initial WeighWolume: 5 ml
Date Analyzed: 02/2812005 1351 Final WeighWolume: 5 ml
Date Prepared: N/A
Toluene-dB 107 79 -122
4-Bromofiuorobenzene 98 77 -120
Dibromofiuoromethane 100 75 -123
STL Savannah
Page 8 of 17
Client: ENSR International
Client Sample ID: Effluent
Lab Sample ID: 680-685-1
Client Matrix: Water
Analyte Result Qual Units
Cyanide, Total 0.0050 U mg/L
•
• STL Savannah
General Chemistry
RL Dil
0.0050 10
Page 9 of 17
Analytical Data
Job Number: 680-685.1
Date Sampled: 02/22/2005 1530
Date Received: 02/23/2005 0911
Method
3354
Analysis Date Analyzed
Batch Date Prepared
680-1657 02/25/2005 0715
02/24/2005 1000
DATA REPORTING QUALIFIERS
Client: ENSR International Job Number: 680-685.1
Lab Section Qualifier Description
GC/MSVOA
u Analyte was not detected at or above the reporting limit.
General Chemistry
u Analyte was not detected at or above the reporting limit.
•
• STL Savannah
Page 10 of 17
•
QUALITY CONTROL RESULTS
•
• STL Savannah
Page 11 of 17
•
Client: ENSR International
QC Association Summary
Lab Sample ID Client Sample ID
GC/MSVOA ····-···················---
Analysis Batch:680-19B9
LCS 680-1989/14 Lab Control Spike
MB 680-1989/15 Method Blank
680-685-A-2 Trip Blank
Analysis Batch:6B0-2104
LCS 680-2104/17 Lab Control Spike
MB 680-2104/18 Method Blank
680-685-8-1 Effluent
General Chemistry
Quality Control Results
Job Number: 680-685 .1
Job Description: Channel Master
Client Matrix Method Prep Batch
Water .
Water
Water
Water
Water
Water
82608
82608
82608
82608
82608
82608
··--· , •• , ................. " .............. --··----• -----------·-----·· .. ······--·--· ··-···-····-----·· ·------------➔-·--··--·-· .... ····-------•·•····· ·········-··•-'<••-----····•"'•""
Prep Batch: 680-1603
LCS 680-1603/2-A Lab Control Spike Water Distillation • LCSD 680-1603/3-A Lab Control Spike Duplicate Water Distillation
MB 680-1603/1-A Method Blank Water Distillation
680-685-E-1-B Effluent Waler Distillation
Analysis Batch:680-1657
LCS 680-1603/2-A Lab Control Spike Water 335.4 680-1603
LCSD 680-1603/3-A Lab Control Spike Duplicate Water 335.4 680-1603
MB 680-1603/1-A Method Blank Water 335.4 680-1603
680-685-E-1-B Effluent Water 335.4 . 680-1603
• STL Savannah
Page 12 of 17
•
•
•
Quality Control Results
Client: ENSR International Job Number: 680-685.1
8260B Volatile Organic Compounds by GC/MS
Method Blank -Batch: 680-1989
Lab ID: MB 680-1989/15 Date Analyzed: 02/28/2005 1220 Dilution: 1.0
Matrix: Water Units: ug/L
Analz'.!e Result Qualifier
Chloromethane 1.0 u
Bromomethane 1.0 u
Vinyl chloride 1.0 u
Chloroethane 1.0 u
Methylene Chloride 1.0 u
Acetone 25 u
Carbon disulfide 1.0 u
1, 1-Dichloroethene 1.0 u
1, 1-Dichloroethane 1.0 u
cis-1,2-Dichloroethene 1.0 u
trans-1,2-Dichloroethene 1.0 u
Chloroform 1.0 u
1,2-Dichloroethane 1.0 u
Methyl Ethyl Ketone 10 u
1, 1, 1-Trichloroethane 1.0 u
Carbon tetrachloride 1.0 u
Dichlorobromomethane 1.0 u
1, 1,2,2-Tetrachloroethane 1.0 u
1,2-Dichloropropane 1.0 u
trans-1,3-Dichloropropene 1.0 u
Trichloroethene 1.0 u
Chlorodibromomethane 1 0 u
I, 1,2-Trichloroethane 1.0 u
Benzene 1.0 u
cis-1,3-Dichloropropene 1.0 u
Bromoform 1 0 u
2-Hexanone 10 u
methyl isobutyl ketone 10 u
Tetrachloroethene 1 0 u
Toluene 10 u
Chlorobenzene 1.0 u
Ethylbenzene 1.0 u
Styrene 1.0 u
Xylenes, Total 2.0 u
Calculations are performed before rounding to avoid round-off errors in calculated results
STL Savannah
Page 13 of 17
RL
1.0
1.0
1 0
10
1.0
25
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
10
10
1.0
10
1.0
1.0
1.0
2.0
• Quality Control Results
Client: ENSR International Job Number. 680-685.1
82608 Volatile Organic Compounds by GC/MS
Laboratory Control Sample -Batch: 680-1989
Lab ID: LCS 680-1989/14 Date Analyzed: 02/28/2005 1055 Dilution: 1.0
Matrix: Water Units: ug/L
Spike Recovery
Analyle Amount Result % Rec. Limits Qualifier
Chloromethane 50.0 43 87 51 -133
Bromomethane 50.0 45 90 21 -176
Vinyl chloride 50.0 47 93 59 -136
Chloroethane 50.0 42 85 40 -171
Methylene Chloride 50.0 47 95 67 -128
Acetone 100 79 79 20 -183
Carbon disulfide 50.0 48 96 60-130
1, 1-Dichloroethene 50.0 47 94 64 -132
1, 1-Dichloroethane 50.0 49 98 70 -127
cis-1,2-Dichloroethene 50 0 50 101 69 -126
trans-1,2-Dichloroethene 50.0 46 93 67 -130
Chloroform 50.0 50 100 74 -124
1,2-Dichloroelhane 50.0 53 106 68 -130
Methyl Ethyl Ketone 100 91 91 51 -142 • 1, 1, 1-Trichloroethane 500 54 107 70 -132
Carbon tetrachloride 50.0 53 106 64 -137
Dlchlorobromomethane 50.0 54 109 74 -128
1, 1,2,2-Tetrachloroethane 500 49 99 71 -127
1,2-Dichloropropane 50.0 50 100 74-123
trans-1, 3-Dichloropropene 500 56 111 75 -126
Trichloroethene 50.0 51 102 75 -122
Chlorodibromomethane 50.0 53 106 75 -126
1, 1,2-Trichloroethane 50.0 52 104 75 -122
Benzene 50.0 50 101 74 -122
cis-1,3-Dichloropropene 50.0 53 105 76 -126
Bromoform 50.0 47 94 64 • 132
2-Hexanone 100 94 94 58-139
methyl isobutyl ketone 100 100 101 62-130
Tetrachloroethene 50.0 50 101 70 -133
Toluene 50.0 51 101 75 -122
Chlorobenzene 50.0 49 98 75 -123
Ethy !benzene 50.0 51 101 77 -123
Styrene 50.0 52 103 75 -125
Xylenes, Total 150 150 100 77 -121
• Calculations are perfom1ed before rounding to avoid round-off errors in calculated results
STL Savannah
Page 14 of 17
• Quality Control Results
Client: ENSR International Job Number: 680-685.1
8260B Volatile Organic Compounds by GC/MS
Method Blank -Batch: 680-2104
Lab ID: MB 680-2104/18 Date Analyzed: 0310112005 1229 Dilution: 1 0
Matrix: Water Units: ug/L
Anal)'.!e Result Qualifier RL
Chloromethane 1.0 u 1 0
Bromomethane 1.0 u 1.0
Vinyl chloride 10 u 1.0
Chloroethane 1.0 u 1.0
Melhylene Chloride 10 u 1.0
Acetone 25 u 25
Carbon disulfide LO u 10
1, 1-Dichloroethene 1.0 u 1.0
1, 1-Dichloroethane 1 0 u 1.0
cis-1,2-Dichloroethene 1.0 u 1.0
trans-1,2-Dichloroethene 1.0 u 1 0
Chloroform 1.0 u 1 0
1,2-Dichloroethane LO u 1.0
Methyl Ethyl Ketone 10 u 10 • 1, 1, 1-Trichloroethane 1 0 u 1.0
Carbon tetrachloride 1 0 u 1.0
Dichlorobromomethane 10 u 1.0
1, 1,2,2-Tetrachloroethane 1.0 u 1.0
1,2-Dichloropropane 1.0 u 10
trans-1,3-Dichloropropene 1.0 u 1.0
Trichloroethene .1.0 u 10
Chlorodibromomethane 1 0 u 1.0
1, 1,2-Trichloroethane 1 0 u 1.0
Benzene 1.0 u 1 0
cis-1,3-Dichloropropene 10 u 1 0
Bromoform 1 0 u 1.0
2-Hexanone 10 u 10
methyl isobutyl ketone 10 u 10
Tetrachloroethene 1.0 u 1.0
Toluene 1 0 u 1.0
Chlorobenzene 1.0 u 1.0
Ethylbenzene 10 u 1 0
Styrene 1.0 u 10
Xylenes, Total 2.0 u 2.0
• Calculations are performed before rounding to avoid round-off errors in calculated results
STL Savannah
Page 15 of 17
• Quality Control Results
Client: ENSR International Job Number: 680-685.1
8260B Volatile Organic Compounds by GC/MS
Laboratory Control Sample -Batch: 680-2104
Lab ID: LCS 680-2104/17 Date Analyzed: 03/01/2005 1114 Dilution: 1.0
Matrix: Water Units: ug/L
Spike Recovery
Analyte Amount Result %Rec. Limits Qualifier
Chloromethane 50.0 47 93 51 -133
Bromomethane 50.0 46 92 21 -176
Vinyl chloride 50.0 49 97 59 -136
Chloroethane 50.0 47 93 40 -171
Methylene Chloride 500 50 100 67 -128
Acetone 100 79 79 20 -183
Carbon disulfide 50.0 50 99 60-130
1, 1-Dichloroethene 50.0 51 102 64 -132
1, 1-Dichloroethane 50.0 51 103 70 -127
cis-1,2-Dichloroethene 50.0 52 104 69 -126
trans-1,2-Dichloroethene 50.0 50 100 67 -130
Chloroform 50.0 53 105' 74 -124
1,2-Dichloroethane 50.0 55 109 68 -130
Methyl Ethyl Ketone 100 94 94 51 -142 • 1, 1, 1-Trichloroethane 50.0 57 114 70-132
Carbon tetrachloride 50.0 55 109 64 -137
Dlchlorobromomethane 50.0 56 113 74 -128
1, 1,2,2-Tetrachloroethane 50.0 50 100 71 -127
1,2-Dichloropropane 50.0 53 105 74 -123
trans-1,3-Dichloropropene 50.0 57 114 75 -126
Trichloroethene 50.0 53 106 75-122
Chlorodibromomelhane 50.0 54 108 75 -126
1, 1,2-Trichloroethane 500 52 104 75 -122
Benzene 500 53 106 74 -122
cis-1,3-Dichloropropene 50.0 56 111 76 -126
Bromoform 50.0 51 101 64-132
2-Hexanone 100 98 98 58 -139
methyl isobutyl ketone 100 110 105 62-130
Tetrachloroethene 50.0 54 108 70-133
Toluene 50.0 53 106 75 -122
Chlorobenzene 50.0 53 105 75 · 123
Ethylbenzene 50.0 53 106 77 -123
Styrene 50.0 54 108 75 -125
Xylenes, Total 150 160 104 77 -121
• Calculations are performed before rounding to avo_id round~off errors in calculated results
STL Savannah
Page 16 of 17
•
•
•
Client: ENSR International
335.4 Cyanide, Total (Semi-Automated Colorimetry)
Quality Control Results
Job Number: 6B0-6B5.1
Method Blank -Batch: 680-1603
Lab ID: MB 680-1603/1-A Date Analyzed: 02/25/2005 0700 Dilution: 1 .0
Matrix: Water Units: mg/L
Analyte Result Qualifier
Cyanide, Total 0.0050 ·u
Laboratory Control Sample/ Control Duplicate -Batch: 680-1603
LCS Lab ID: LCS 680-1603/2-A Date Analyzed: 02/25/2005 0701
LCSD Lab ID: LCSD 680-1603/3-A Date Analyzed: 02/25/2005 0702
Matrix: Water Units: mg/L
Analyte % Recovery
LCS LCSD
Cyanide, Total 99 99
Recover
y Limils
90-110
Calculations are performed before rounding to avoid round-off errors in calculated results
STL Savannah
Page 17 of 17
RPP
0
RL
0.0050
Dilution: 1.0
Dilution: 1.0
RPD
Limit
20
Qualifier
PROJECT REFERENCE
ANALYSIS REQUEST AND CHAIN OF CUSTODY RECORD
STL
PROJECT NO.
/,t} ,I-P-o/2.
PROJECT LOCATION
!STATE) t/ C..-
MATRIX
TYPE
Serial Number 3 8 8 2 7
CS2f'STL Savannah
........--~ 102 LaRoche Avenue
Savannah, GA 31404
0 Alternate Laboratory Name/location
REQUIRED ANALYSIS
Website: www.stl-inc.com
Phone: [phone]
Fax: [phone]
Phone:
Fax:
PAGE OF
ST ILABI PROJECT MANAGER p_Q_ NUMBER CONTRACT NO. ~ -1 STANDARD REPORT ~ ,.-'-7· " }-"' ' I • DELIVERY ~ ~=~§'C!,=-<=='---:::"':c:'l'C-:::...:_:lrC-=._:'--=------l-----~---1-------!;, 15 :,0 ~ ,r-" CLIENT PHONE CLIENT FAX ~ -l (1 DATE QUE ____ _
q;, .,fZ/Jtt'bll-'f 'l;'ili'?"2--/,tov <i87'Z 7'f1-6 ~ ~-ti .. _,
1
~
CLIENT E-MAIL sc! "It-~ JI EXPEDITED REPORT / a:, =' n \\1 DELIVERY O•
'-' 5 N ~ ~ f:J/iorntl.(l'll'f@ e__nSr. C,,C,>v; ?ii 0_ ~ :ti >l n~"J !SURCHARGE)
CLIENT ADDRESS z.7,:,/ "' ii' 5 o Cl.. DATE DUE '<P 1--1 tft--lJ WAl4E-f=Dll-b~'T f!--D -.57;_~ tJ. Pd.11611,tlc g j ~ i1~6o~--+'-----
0
,..J_--l---1----1----l---1----1----l---l-NU-M-.'.'.B'.'.'.ER::_o:::F'.'.:co-=o=LE=Rs=s=u=BM=rrr=E'----lD
COMPANY CONTRACTING THIS WORK lif applicable) ~ ~ ~ § f/cl,-~l). PER SHIPMENT: /
r--~=~--~-------------------~89 ~'~-~-~-~-~-~-~-~-~-~-~--------~ SAMPLE :E :::, -' z
RELINQUISHED BY: <SIC;NATUREI
RE IVED BY: !SIGNATURE
'
DATE
DATE
SAMPLE IDENTIFICATION o o o ~ o U-.l'.(l)C::Z
TIME RELINQUISHED BY: <SI
.d__
MEI
~
TIME RECEIVED.JV'. ISIGNATUREI
"/ '7 tJ</ /:J:S:O
DATE TIME
CJ I I
CUSTODY INTACT
YES 0
NO C)
LABORATORY USE ONLY
NUMBER Of CONTAINERS SUBMITTED REMARKS
TIME RELINQUISHED BY: tSIGNATUREJ DATE TIME
/7t?0
DATE TIME RECEIVED BY: !SIGNATUREJ DATE TIME
LABORATORY REMARKS
L8240-680 !12/021
•
March 2005 Analytical Data
•
•
• Severn Trent Laboratories, Inc .
ANALYTICAL REPORT
Job Number: 680-1889. 1
Job Description: Channel Master
For:
ENSR International
7041 Old Wake Forrest Road
Raleigh, NC 27616
Attention: Mr. Gerald Hornaday
Angie Weimerskirk
Project Manager I
aweimerskirk@stl-inc .. com
04/09/2005
STL Savannah 5102 LaRoche Avenue, Savannah, GA 31404
Tel [phone] Fax [phone] www.sU-inc.com
Page 1 of 13
•
•
•
Client: ENSR International
Description
Matrix: Water
Volatile Organic Compounds by GC/MS
Purge-and-Trap
Cyanide, Total (Semi-Automated Colorimetry)
DisUllalion/Cyanide
REFERENCES
METHOD SUMMARY
Job Number: 680-1889.1
Method Preparation Method
SW846 82608
SW846 50308
MCAWW 335.4
NONE Distillation
MCAWW -"Methods For Chemical Analysis Of Water And Wastes", EPA-600/4-79-020, March t 983 And
Subsequent Revisions
SW846-"Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third EdiLion, November 1986
And Its Updates .
STL Savannah
Page 2 of 13
•
Client ENSR International
lab Sample ID Client Sample ID
680-1889-1 Effluent
•
• STL Savannah
SAMPLE SUMMARY
Client Matrix
Water
Page 3 of 13
Date/Time
Sampled
03/24/2005 1405
Job Number: 680-1889.1
DatefTime
Received
03/25/2005 0915
SAMPLE RESULTS
•
• Sn Savannah
Page 4 of 13
•
•
Client: ENSR International
Client Sample ID:
Lab Sample ID:
Client Matrix:
Effluent
680-18B9-1
Water
Analytical Data
Job Number: 680-1889.1
Date Sampled:
Date Received:
03/24/2005 1405
03/25/2005 0915
8260B Volatile Organic Compounds by GC/MS
Method: B260B Analysis Batch: 680-5604
Preparation:
Dilution:
Dale Analyzed:
Date Prepared:
Analyte .
Chloromethane
Bromomethane
Vinyl chloride
Chloroethane
Melhylene Chloride
Acetone
Camon disulfide
1, 1-Dichloroethene
1, 1-Dichloraethane
5030B
1.0
03/29/2005 1603
N/A
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Chloroform
1,2-Dichloroethane
Methyl Ethyl Ketone
1, 1, 1-Trichloroelhane
Carbon tetrachloride
Oichlorobromomethane
1, 1,2,2-Tetrachloroethane
1 ,2-Dichloropropane
trans-1,3-0ichloropropene
Trichloroethene
Chlorodibromomethane
1, 1,2-Trichloroethane
Benzene
cis-1,3-Dichloraprapene
Bromofonn
2-Hexanone
methyl isobutyl ketone
T etrachloroethene
Toluene
Chlorobenzene
Ethylbenzene
Styrene
Xylenes, Total
Surrogate
Toluene-<JB
4-Bromofluorobenzene
STL Savannah
Res.ult (ug/L)
1.0
1.0
1.0
1.0
1.0
25
1.0
1 0
1.0
1.0
1 0
1.0
1.0
10
1.0
1.0
1.0
10
1.0
1.0
1.0
1.0
1 0
1.0
1.0
1.0
10
10
1.0
1 0
1.0
1.0
10
2.0
%Rec
98
92
Page 5 of 13
Instrument ID: GC/MS Volatiles• P
Lab File ID: p5032 d
Initial WeighWolume: 5 mL
Final WeighWolume: 5 mL
Qualifier RL
u 1.0
u 1.0
u 10
u 1 0
u 1 0
u 25
u 1 0
u 1.0
u I 0
u 1.0
u 1.0
u 1.0
lJ 1.0
u 10
u 1.0
u 10
u 1.0
u 1 0
u 1.0
u 1.0
u 1.0
u 1.0
u 10
u 1.0
u 1.0
u 1.0
u 10
u to
u 1.0
u 1 0
u 1.0
u 1.0
u 10
u 2.0
Acceptance Limits
79-122
77 -120
•
•
•
Client: ENSR International
Client Sample ID:
Lab Sample ID:
Client Matrix:
Effluent
680-1889-1
Water
Analytical Data
Job Number: 680-1889.1
Date Sampled:
Date Received:
03/24/2005 1405
03/2512005 0915
8260B Volatile Organic Compounds by GC/MS (Continued)
Method: 8260B Analysis Batch: 680-5604
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
5030B
1.0
03/2912005 1603
N/A
s.~"!o.~a~~
Dibromofluoromethane
STL Savannah
%Rec
103
Page 6 of 13
Instrument ID: GC/MS Volatiles -P
Lab File ID: p5032.d
Initial WelghWolume: 5 ml
Final WeighWolume: 5 ml
Acceptance Limits
75-123
• Client: ENSR International
Client Sample ID: Effluent
Lab Sample ID: 680-1889-1
Client Matrix: Water ,
Analyte Result Qual Unlls
Cyanide, Total 0 .. 0070 mg/L
•
• STL Savannah
General Chemistry
Analytical Data
Job Number: 6B0-1889 .1
Dale Sampled: 03/24/2005 1405
Date Received: 03/25/2005 0915
RL Oil Method Anly Batch . Date Analyzed
0.0050 1.0 335.4 680-5355 03/28/2005 1226
Prep Batch: 680-5353 Date Prepared: 03/28/2005 0700
Page 7 of 13
• DATA REPORTING QUALIFIERS
Client ENSR International Job Number. 680-1889.1
Lab Section Qualifier Description
GC/MSVOA
u Analyte was not detected at or above the reporting limit.
General Chemistry
u Analyte was not detected at or above the reporting limit.
•
• STL Savannah
Page 8 of 13
•
QUALITY CONTROL RESUL TSH ·
•
• STL Savannah
Page 9 of 13
• Client: ENSR International
Surrogate Recovery Report
8260B Volatile Organic Compounds by GC/MS
Client Matrix: Water
Lab Sample ID
680-1889-1
LCS 680-5604/1 LCS
MB 680-5604/2MB
Surrogate
Client Sample ID
Effluent
LCS
MB
(BFB)
(DBFM)
(TOL)
4-Bromofluorobenzene
Dibromofluoromethane
Toluene-dB
• STL Savannah
(BFB) (DBFM) (TOL)
(¾Rec) (¾Rec) (¾Rec)
92 103 98
98 106 104
92 97 96
Acceptance Limits
77 -120
75 -123
79 -122
Page 10 of 13
Quality Control Results
Job Number: 680-1889.1
• Quality Control Results
Client: ENSR International Job Number: 680-1889_1
82606 Volatile Organic Compounds by GC/MS
Method Blank -Batch: 680-5604
Lab ID: MB 6B0-5604/2 Dale Analyzed: 03/29/2005 1145 Dilution: . 1 .0
Matrix: Water Units: ug/L
Analyte Result Qualifier RL
Chloromethane 1-0 u 1.0
Bromomethane 1-0 u 1.0
Vinyl chloride 1-0 u 1.0
Chloroethane 1.0 u 1 0
Methylene Chloride 1.0 u 1.0
Acetone 25 u 25
Carbon disulfide 1.0 u 10
1, 1-0ichloroethene 1.0 u 1..0
1, 1-Dichloroethane 1.0 u 1.0
cis-1,2-Dichloroethene 10 u 1.0
trans-1,2-0ichloroethene 1.0 u 1.0
Chloroform 1 0 u 1.0
1,2-Dichloroethane 1.0 u 1.0
Methyl Ethyl Ketone 10 u 10 • 1, 1, 1-Trichloroelhane 1..0 u 1.0
Carbon tetrachloride 1.0 u 1 0
Dichlorobromomethane 1.0 IJ 1.0
1, 1,2,2-Tetrachloroethane 1 .o u 10
1,2-Dichloropropane 1-0 u 1.0
trans-1,3-Dlchloropropene 1-0 u 1.0
Trichloroe1hene 1.0 u 1.0
Chlorodibromomethane 1.0 u 1 0
1, 1,2-Trichloroethane 1.0 lJ 10
Benzene 10 u 1..0
cis-1,3-Dichloropropene 10 u 10
Bromoform 1 .. 0 lJ 1 0
2-Hexanone 10 u 10
methyl isobu1yl ketone 10 IJ 10
Tetrachloroethene 1-0 u , .0
Toluene 1.0 u 1.0
Chlorobenzene 1.0 u 1.0
Elhylbenzene 1 0 u 1.0
Styrene 1.0 u 1.0
Xylenes, Total 2.0 u 2.0
• Calcutalions are performed before rounding to avoid round-off errors In calculated re.Suits.
STL Savannah
Page 11 of 13
• Quality Control Results
Client: ENSR International Job Number. 680-1889.1
8260B Volatile Organic Compounds by GC/MS
Laboratory Control Sample -Batch: 680-5604
Lab ID: LCS 680-560411 Date Analyzed: 0312912005 1022 Dilution: 1.0
Matrix: Water Units: ug/L
Analyte Spike Result %Rec Recovery Qualifier
Amount Limits
Chloromethane 50.0 50 100 51-133
Bromomethane 50.0 54 108 21 -176
Vinyl chloride 50.0 52 105 59 -136
Chloroethane 50.0 57 115 40-171
Methylene Chloride 50.0 52 103 67 -128
Acetone 100 110 114 20 -183
Carbon disulfide 50.0 51 102 60 -130
1, 1-Dlchloroethene 50.0 50 101 64 -132
1, 1-Dichloroethane 500 53 105 70-127
cis-1.2-Dichloroethene 50.0 54 107 69 -126
trans-1,2-Dichloroethene 50.0 52 104 67 • 130
Chloroform 50.0 54 10B 74 -124
1,2-0ichloroethane 50.0 52 104 68 -130 • Methyl Ethyl Ketone 100 99 99 51 -142
1, 1, 1-Trichlo,oethane 50.0 53 107 70 • 132
Carbon tetrachloride 50.0 55 110 64 • 137
Oichlorobromomethane 50.0 54 107 74 -128
1, 1,2,2-Tetrachloroelhane 50.0 49 98 71 • 127
1,2-Dichloropropane 500 50 100 74 -123
trans-1,3-0ichloropropene 50.0 55 110 75 -126
Trichloroethene 50.0 52 104 75.·122
Chlorodibromomethane 50.0 56 112 75 • 126
1, 1,2-Trichloroethane 500 53 106 75 -122
Benzene 50.0 51 103 74 -122
cls-1,3-Dichloropropene 50.0 54 109 76 -126
Bromofonn 500 56 113 64 -132
2-Hexanone 100 110 109 58 -139
methyl isobu1yl ketone 100 100 102 62 -130
Tetrachloroethene 50.0 52 104 70 -133
Toluene 500 51 103 75 -122
Chlorobenzene 50.0 51 101 75 -123
Ethylbenzene 50 .. 0 52 104 77 -123
Styrene 50.0 52 104 75 • 125
Xylenes, Total 150 160 104 77. 121
• Calculations are perfonned before rounding to avoid round-off errors in calculated results.
STL Savannah
Page 12 of 13
•
Client: ENSR International
335.4 Cyanide, Total (Semi-Automated Colorimetry)
Method Blank • Batch: 680-5353
Lab ID: MB 680-5353/1-A Date Analyzed: 03/28/2005 1219
Matrix: Water Units: mg/L
Analyte Result Qualifier
Cyanide, Tolal 0.0050 u
Laboratory Control Sample/ Control Duplicate -Batch: 680-5353
LCS Lab ID: LCS 680-5353/2-A Date Analyzed: 03/26/2005 1220
LCSD Lab ID: LCSD 680-5353/3-A Date Analyzed: 03/28/2005 1221
Matrix: Water
Analyte
Cyanide, Total
% Recovery
LCS LCSD
96 97
Recovery
Limits
90 • 110
• Calculations are performed before rounding to avoid round-off errors in calculated results.
STL Savannah
Page 13 of 13
Quality .Control Results
RPO
2
Job Number: 680-1889.1
Dilution: IO
RL
0.0050
DIiution: 1 0
Dilution: 1.0
RPO
Limit
20
Qualifier
•
April 2005 Analytical Data
•
•
•
•
• Severn Trent Laboratories, Inc.
ANALYTICAL REPORT
Job Number: 680-2719.1
Job Description: Channel Master
For:
ENSR International
7041 Old Wake Forrest Road
Raleigh, NC 27616
Attention: Mr. Gerald Hornaday
Angie Weimerskirk
Project Manager I
[e-mail]
05/08/2005
STL Savannah 5102 LaRoche Avenue, Savannah, GA 31404
Tel [phone] Fax [phone] www.stl-inc.com
Page 1 of 9
•
•
•
Client: ENSR International
Description
Matrix: Water
Volatile Organic Compounds by GC/MS
Purge-and-Trap
Cyanide, Total (Semi-Automated Colorimetry)
Distillation/Cyanide
REFERENCES
METHOD SUMMARY
Job Number. 680-2719.1
Method Preparation Method
SW846 8260B
SW846 5030B
MCAWW 335.4
Distillation
MCAWW -"Methods For Chemical Analysis Of Water And Wastes", EPA-60014-79-020, March 1983 And
Subsequent Revisions.
SW846 -''Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986
And Its Updates .
STL Savannah
Page 2 of 9
•
Client: ENSR International
Lab Sample ID Client Sample ID
680-2719-1 Effluent
•
• STL Savannah
SAMPLE SUMMARY
Client Matrix
Water
Page 3 of 9
DatefTime
Sampled
04/1812005 1445
Job Number 680-2719.1
Date/Time
Received
04/1912005 0918
•
•
•
Client: ENSR International
Client Sample ID:
Lab Sample ID:
Client Matrix:
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
Effluent
680-2719-1
Water
8260B Volatile Organic Compounds by GC/MS
8260B Analysis Batch: 680-8946
1.0
04/28/2005 1838
04/28/2005 1838
Analytical Data
Job Number. 680-2719.1
Date Sampled: 04/1812005 1445
Date Received: · 04/19/2005 0918
Instrument ID: GC/MS Volatiles - P
Lab File ID: p5749.d
Initial WeighWolume: 5 ml
Final WeighWolume: 5 ml
Analyte Result (ug/L) Qualifier RL -·-···-·-··-----
Chloromethane 1.0 u 1.0
Brome methane 1.0 u 1.0
Vinyl chloride 1.0 u 1.0
Chloroethane 1.0 u 1.0
Methylene Chloride 1.0 u 1.0
Acetone 25 u 25
Carbon disulfide 1.0 u 1.0
1, 1-Dichloroethene 1.0 u 1.0
1, 1-Dichloroethane 1.0 u 1.0
cis-1,2-Dichloroethene 1.0 u 1.0
trans-1,2-Dichloroethene 1.0 u 1.0
Chloroform 1.0 u 1.0
1,2-Dichloroethane 1.0 u 1.0
Methyl Ethyl Ketone 10 u 10
1, 1, 1-Trichloroethane 1.0 u 1.0
Carbon tetrachloride 1.0 u 1.0
Dichlorobromomethane 1.0 u 1.0
1, 1,2,2-Tetrachloroethane 1.0 u 1.0
1,2-Dichloropropane 1.0 u 1.0
trans-1,3-Dichloropropene 1.0 u 1.0
T richloroethene 1.0 u 1.0
Chlorodibromomethane 1.0 u 1.0
1, 1,2-Trichloroethane 1.0 u 1.0
Benzene 1.0 u 1.0
cis-1,3-Dichloropropene 1.0 u 1.0
Bromofonn 1.0 u 1.0
2-Hexanone 10 u 10
methyl isobutyl ketone 10 u 10
T etrachloroethene 1.0 u 1.0
Toluene 1.0 u 1.0
Chlorobenzene 1.0 u 1.0
Ethylbenzene 1.0 u 1.0
Styrene 1.0 u 1.0
Xylenes, Total 2.0 u 2.0
Sur~?~.~te %Rec Acceptance Limits
-··-------··· .. -··---·----·-· ······-··------····· ... ---·---------·-----·--··----·----··---· .. ·-· ....... -·--··---·-..
Toluene-dB 96 79 -122
· 4-Bromofluorobenzene 116 77 -120
Dibromofluoromethane 93 75 -123
STL Savannah
Page 4 of 9
•
Client: ENSR International
Client Sample ID:
Lab Sample ID:
Client Matrix:
Analyte
Cyanide, Total
STL Savannah
Effluent
680-2719-1
Water
Result Qual
0.0058
Units
mg/L
General Chemistry
Analytical Data
Job Number. 680-2719.1
Date Sampled: 04/18/2005 1445
Date Received: 04/19/2005 0918
RL Oil Method Anly Batch Date Analyzed
0.0050 1.0 335.4 680-7922 04/2112005 1455
Prep Batch: 680-7920 Date Prepared: 04/21/2005 0700
Page 5 of 9
• DATA REPORTING QUALIFIERS
Client: ENSR International Job Number. 680-2719.1
Lab Section Qualifier Description
GC/MSVOA
u Analyte was not detected at or above the reporting limn.
General Chemistry
u Analyte was not detected at or above the reporting limn.
•
• STL Savannah
Page 6 of 9
•
•
Client: ENSR International
Surrogate Recovery Report
8260B Volatile Organic Compounds by GC/MS
Client Matrix: Water
Lab Sample ID Client Sample ID
680-2719-1
LCS 680-8946/1 LCS
Effluent
LCS
Surrogate
(BFB)
(DBFM)
(TOL)
STL Savannah
4-Bromofluorobenzene
Dibromofluoromethane
Toluene-dB
(BFB)
(¾Rec)
116
106
(DBFM)
(¾Rec)
93
93
(TOL)
(¾Rec)
96
90
Acceptance Limits
77 -120
75 -123
79 -122
Page 7 of 9
Quality Control Results
Job Number. 680-2719.1
• Quality Control Results
Client: ENSR International Job Number. 680-2719.1
8260B Volatile Organic Compounds by GC/MS
Laboratory Control Sample • Batch: 680-8946
Lab ID: LCS 680-8946/1 Date Analyzed: 04/28/2005 1326 Dilution: 1.0
Matrix: Water Units: ug/L
Analyte Spike Result % Rec. Recovery Qualifier
Amount Limits
Chloromethane 50.0 51 103 51 -133
Bromomethane 50.0 59 119 21 -176
Vinyl chloride 50.0 49 99 59 -136
Chloroethane 50.0 52 104 40 -171
Methylene Chloride 50.0 50 99 67 -128
Acetone 100 120 121 20 -183
.Carbon disulfide 50.0 45 89 60 -130
1, 1-Dichloroethene 50.0 46 93 64 -132
1, 1-Dichloroethane 50.0 48 96 70 -127
cis-1,2-Dichloroethene 50.0 46 92 69 -126
trans-1,2-Dichloroethene 50.0 46 92 67 -130
Chloroform 50.0 48 96 74 -124 • 1,2-Dichloroethane 50.0 53 106 68 -130
Methyl Ethyl Ketone 100 110 111 51 -142
1, 1, 1-Trichloroethane 50.0 54 107 70 -132
Carbon tetrachloride 50.0 55 109 64 -137
Dichlorobromomethane 50.0 52 104 74 -128
1, 1,2,2-Tetrachloroethane 50.0 54 107 71 -127
1,2-Dichloropropane 50.0 49 97 74 -123
trans-1,3-Dichloropropene 50.0 50 100 75 -126
Trichloroethane 50.0 50 101 75 -122
Chlorodibromomethane 50.0 54 108 75 -126
1, 1,2-Trichloroethane 50.0 48 96 75 -122
Benzene 50.0 49 97 74 -122
cis-1,3-Dichloropropene 50.0 51 102 76 -126
Bromoform 50.0 53 107 64 -132
2-Hexanone 100 100 105 58 -139
methyl isobutyl ketone 100 88 88 62 -130
Tetrachloroethene 50.0 48 97 70 -133
Toluene 50.0 44 88 75 -122
Chlorobenzene 50.0 46 92 75 -123
Ethylbenzene 50.0 47 94 77 -123
Styrene 50.0 52 104 75 -125
Xylenes, Total 150 150 100 77 -121
• Calculations are performed before rounding to avoid round-off errors in calculatecj results.
STL Savannah
Page 8 of 9
•
•
Client: ENSR International
335.4 Cyanide, Total (Semi-Automated Colorimetry)
Method Blank -Batch: 680-7920
Lab ID: MB 680-7920/1-A Date Analyzed: 04/21/2005 1446
Matrix: Water Units: mg/L
Analyte Result
Cyanide, Total 0.0050
Laboratory Control Sample/ Control Duplicate -Batch: 680-7920
LCS Lab ID: LCS 680-792012-A Date Analyzed:
LCSD Lab ID: LCSD 680-7920/3-A Date Analyzed:
Matrix: Water
% Recovery
Analyte LCS LCSD
Cyanide, Total 104 106
Qualifier
u
04/2112005 1447
04/2112005 1447
Recovery
Limits
90-110
Calculations are performed before rounding to avoid round-off errors in calculated results ..
STL Savannah
Page 9 of 9
Quality Control Results
Job Number: 680-2719.1
RPD
Dilution: 1.0
RL
0.0050
Dilution:
Dilution:
RPD
Limo
20
1.0
1.0
Qualifier
PROJECT REFERENCE
RELINQUISHED BY: !SIGNATURE!
R:£EIVED BY:;s,,,.TURE)
~
Serial Number · 3 8 8 2 4
ANALYSIS REQUEST AND CHAIN OF CUSTODY RECORD STL Savannah Website: www.stl-inc.com
Phone: [phone]
Fax: [phone] STL
PROJECT NO. PROJECT Lot;ATION
/o;~Q-0/~ ·I0:5 ISTATEI ,VL
DATE TIME
DATE TIME RECEIVED BY·
3'/6 o">· /S:OlJ
DATE · TIME-.---CUSTODY INTACT
r/N.'C
YES C).
t7f1, NO C)
MATRIX
TYPE
5102 LaRoche Avenue
Savannah, GA 31404
0 Alternate Laboratory Name/location
REQUIRED ANALYSIS
NUMBER OF CONTAINERS SUBMITTED
i
Phone:
Fax:
TIME RELINQUISHED BY: (SIGNATURE}
ll!jlo
TIME RECEIVED BY: 1S!GNATUREI
LABORATORY USE ONLY
CUSTODY STL SAVANNAH LABORATORY REMARKS
SEAL NO. LOG NO.
lo50-c911
PAGE / OF /
STANDARD REPORT Al-.
DELIVERY 'A'
DATE DUE ____ _
EXPEDITED REPORT
DELIVERY 0
!SURCHARGE)
DATE DUE
REMARKS
DATE TIME
DATE TIME
•
•
'/NTERNATIONAL{.1
February 1, 2005
Mr. Larry Thomas
City Engineer
City of Oxford
P.O. Box 1307
Oxford, North Carolina 27565
RE: Industrial Users Report for January 2005
ENSR International
7041 Old Wake Forest Road, Suite 103
Raleigh, NC 27616-3013
[phone]
FAX [phone]
www.ensr.com
JFD Electronics/Channel Master NPL Site, Oxford, North Carolina.
Dear Mr. Thomas:
On behalf of The Unimax Corporation and Avnet, Inc., ENSR Consulting and Engineering (NC), Inc.
is submitting the Quarterly Industrial User Permit report for the months of November and December
2004, and January 2005. This report is prepared in accordance with permit requirements for the
discharge of treated groundwater at the above referenced site.
If you have any questions, please contact us at [phone].
Sincerely,
ENSR Consulting and Engineering (NC), Inc.
Gerald Y. Hornaci{iy, P.E.
Project Engineer
Enclosure
~J ffic~ t/ 'Jichu-~
William H. Doucette, Jr., Ph.D.
Senior Program Manager
cc: Brian Kempner, The Unimax Corporation (w/o lab attachment)
S. Alan Lazar, Avnet, Inc. (w/o lab attachment)
Steve Earp, Smith Helms Muliss & Moore (w/o lab attachment)
David Mattison, NCDENR Superfund
Ken Lucas, USEPA Superfund
Nanjun Shelly, P.E., ENSR
File
Celebrating 30 Years of Excellence in Environmental Services
•
•
INDUSTRIAL USER REPORTING FORM
LU. PERMIT NO: G001 DISCHARGE NO: ___ ..ec0,,_01,..._ ____ _
MONTHS: November. December. and January YEAR: 2004 and 2005
LU. NAME: JFD Electronics/Channel Master CLASS: COUNTY: Granville
OPERATOR IN RESPONSIBLE CHARGE (ORC): ENSR Consulting & Engineering (NC). Inc.
LABORATORY PERFORMING ANALYSIS: STL-Savannah Laboratories
PERSON(S) COLLECTING SAMPLES: Gerald Hornaday. P.E. (ENSR): Tom Gray (ENSR)
CHECK BLOCK IF ORC HAS CHANGED 0
SEND REPORT TO: City Engineer
City of Oxford
P.O. Box 1307
Oxford, NC 27565
Facility Status: (Please check one of the following)
All monthly averages and/or other limitations do meet permit monitoring requirements. [gj
(Compliant)
All monthly averages and/or other limitations do not meet permit monitoring requirements. D
(Noncompliant)
If the facility is noncompliant, please comment on corrective actions being taken in respect to
equipment, operation, maintenance, etc. and a time table for improvements to be made.
(Attach additional sheets if necessary)
I certify that this Report is accurate and
complete to the best of my knowledge:
Signature of Permittee Representative
William H. Doucette, Jr., Ph.D.
1 -51-os-
Date:
•
•
•
TABLE 1. GROUNDWATER REMEDIATION SYSTEM DISCHARGE MONITORING REPORT, CITY OF OXFORD, NORTH CAROLINA
I.U. PERMIT NO:
DISCHARGE NO:
MONTHS:
YEAR:
I.U. NAME:
COUNTY:
OPERATOR IN RESPONSIBLE CHARGE (ORC):
LABORATORY PERFORMING ANALYSIS:
PERSON($) COLLECTING SAMPLES:
PARAMETER
Dally Average Flow (MGD)
Tetrachloroethylene
1, 1-Dlchloroethane
cis-1,2 Dichloroet.hene
Chlorobenzene
Toluene
1, 1-Dichloroethylene
trans-1,2 Dlchloroethylene
Trlchloroethene
Vinyl Chloride
Cyanide (total)
pH
Temperature
Monitoring requirement only.
MGD Million Gallons per day.
µg/L Micrograms per liter.
mg/L Milligrams per liter.
SU Standard Units.
°C Degrees Centigrade.
G001
001
November, December and January
2004 and 2005
JFD Electronics/Channel Master NPL Site
GranviUe
ENSR Consulting & Engineering (NC), Inc.
STL Savannah laboratories
Gerald Hornaday, P.E. (ENSR); Tom Gray (ENSR)
PERMIT LIMITS UNITS SAMPLE
Daily Maximum TYPE
0.040 MGD Meter
µgil Grab
µgil Grab
µg/L Grab
µgil Grab
µg/L Grab
µgil Grab
µg/L Grab
µgil Grab
µg/L Grab
0.05 mg/L Grab
5.0 to 10.0 SU Grab
40 oc Grab
< Compound was not detected above the quantitation limit.
G:\eri-NFOCHANN\NC0202.170\City of Oxlon:NURT11ble Feb 2005\Table 11112712005
LAB MONTHLY MEASUREMENT
METHOD DATES
11111/04 12/16/04 01/18/05
Field 0.025 0.025 0,026
8260 <1.0 <1.0 <1.0
8260 <1.0 <1.0 <1.0
8260 <1.0 <1.0 <1.0
8260 <1.0 <1.0 <1.0
8260 <1.0 <1.0 <1.0
8260 <1.0 <1.0 <1.0
8260 <1.0 <1.0 <1.0
8260 <1.0 <1.0 <1.0
8260 <1.0 <1.0 <1.0
335.2 <0.0050 <0.0050 0.0052
Field 7.39 6.78 8.06
Field 16.6 17.1 6.3
•
November 2005 Analytical Data
•
•
•
Client
Report to:
STL Log#
Client Project #
Project Description
Report Date
Mr. Gerald Hornaday ENSR Consulting & Engineering
7041 Old Wake Forrest Rd Raleigh, NC 27616
5451082
10140-003
Channel Master 11-29-04
r ~e"rski rk,ojectManager
STL Savannah
5102 LaRoche Ave Savannah, Ga 31404
Page 1 of 12
-ISTL
• u:,.·a STL
S1'L Savannah Client I ENSR Consulting & Engineering
Work Order XD Channel Master
Laborato.:cy ID S451082*1
Sample J:D Effluent
Matrix LI Sampled : 11-11-2004
Percent Solids Received: 11-13-2004
RESt1L1'S SUMMARY REPORT
Paramter -Batch Prep Analysis Analyst Result Qual !hits DF RI. ll)L.
Date Date
O,loranetllane 8260 1Dll19 11-19-()4 11-19-04 RI. 1.0 < ug/1. 1 1.0 0.39
Bra,o,ethane (Methyl bronide) 8260 101119 11-19-04 11-19-()4 RL 1.0 < ug/1 1 1.0 0.62
Vinyl chloride 8260 l01ll9 11-19-()4 11-19-04 RL LO < ug/1 1 1.0 0.56
Chloroethane 8260 1Dll19 11-19-()4 11-19-()4 RI. 1.0 < ug/1 1 1.0 0.78
..-ethylene chloride
(Dichloranethane) 8260 1Dll19 11-19-()4 11-19-04 RL 5 .. 0 < ug/1 1 5.0 0.64
Acetone 8260 1Dll19 11-19-()4 11-19-()4 RI. 25 < ug/1 1 25 5 .. 0
Carboo disulfide 8260 101119 11-19-()4 11-19-()4 RI. 1..0 < ug/1 1 1.0 0.66
1, 1-Dic.hloroethene 8260 101119 11-19-()4 11-19-()4 RL 1.0 < ug/1 1 LO 0.36
1,1-Dichloroethane 8260 101119 11-19-04 11-19-04 RI. 1.0 < ug/1 1 1.0 0 .. 36
ci s-1,2-Di chloroethene 8260 101119 i1-19-o4 11-19-04 RL LO ug/1 1 1.0 ---0.38 • <
tri!ns-1, 2-Di chloroethene 8260 1Dll19 11-19-()4 11-19-()4 RI. 1.0 < ug/1 1 1.0 0.40
Olloroform 8260 101119 11-19-()4 11-19-()4 RL 1.0 < ug/1 1 1.0 0 .. 37
1, 2-Di chloroethane 8260 1Dll19 11-19-()4 11-19-04 RI. 1..0 < ug/1 1 1.0 0.26
2-Butanone (1-EK) 8260 101119 11-19-04 11-19-()4 RI. 10 < ug/1 1 10 1..3
1,1,1-Trichloroethane 8260 1Dll19 11-19-04 11-19-04 RL LO < ug/1 1 1.0 0.32
Carbon tetrachloride 8260 1Dll19 11-19-()4 11-19-()4 RI. 1.0 < ug/l 1 1.0 0.31
Bromodichloromethane 8260 1Dll19 11-19-04 11-19-()4 RI. 1.0 < ug/1 1 1..0 0 .. 14
1,1,2,2-Tetrachloroethane 8260 1Dll19 11-19-()4 11-19-04 RI. LO < ug/1 1 1.0 0.18
1, 2-Di chloropropane 8260 101119 11-19-()4 11-19-()4 RI. 1.0 < ug/1 1 1..0 0.33
trans-1,3-Dichloropropene 8260 1Dll19 11-19-04 11-19-04 RI. 1.0 < ug/1 1 1.0 0.26
Trichloroethene 8260 101119 11-19-()4 11-19-04 RI. 1.0 < ug/1 1 1.0 0.37
Dibraioch lomnethane 8260 101119 11-19-04 11-19-()4 RL 1.0 < ug/1 1 10 0.50
1, 1, 2-Tr i ch lorocthane 8260 101119 11-19-()4 11-19-04 RI. LO < ug/1 1 1.0 0.22
Benzene 8260 1Dll19 11-19-()4 11-19-()4 RI. 1.0 < ug/1 1 1.0 0.36
ci s-1, 3-0i chloropropene 8260 1Dll19 11-19-04 ll-19-04 RL 1.0 < ug/1 l 1.0 0.23
Branoform 8260 10lll9 11-19-()4 11-19-04 RL 1 .. 0 < ug/1 1 1.0 0.33
2-Hexanone 8260 101119 11-19-04 11-19-()4 RL 10 < ug/1 1 10 0.93
4-Methyl-2-pentanone (MIBK) 8260 101119 11-19-()4 11-19-04 RI. 10 < ug/1 1 10 0,65
Tetrachloroethene 8260 1Dll19 11-19-()4 ll-19-04 RL 1.0 < ug/1 1 1.0 0.35
Toluene. 8260 101119 11-19-04 11-19-()4 RL 1.0 < ug/1 l 1.0 0,54
0, lorobenzene 8260 101119 11-19-()4 11-19-04 RL 1.0 < ug/1 1 1.0 0 .. 34
Ethyl benzene 8260 101119 11-19-()4 11-19-04 RL 1.0 < ug/1 1 l.O 0,34
Styr-er,e 8260 101119 11-19-()4 11-19-()4 RL 1.0 < ug/1 1 1.0 0.25
Xylenes, Total 8260 1Dll19 11-19--04 11-19-04 RL 2.0 < ug/1 1 20 1.3
Surrogate -To1uene-d8 * 8260 1{)1119 11-19-04 11-19-04 RL 96 % 1
Surrogat:e -
4-BraTIOfJuorobenzene • 8260 101119 11-19--04 11-19-04 RL 92 % 1 •
Page 2 of 12
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Client
Work Order I:D
Laboratory :CD
Sall<Ple ZD
Matrix
I ENSR Consul ting
1 Channel Master
I S451082*1
I Effluent
• LI
iiiii;l~M Mlili§IM STL
S'l'L Sava.nnah
& Engineering
Percent Solids :
Sampled 1 11-11-2004
Received: 11-13-2004
Paraueter
Surrogate -
IJ-ibrarvf7uoronethane ,..
Cyanide.
llethxl Batch
RESULTS SUMMARY REPORT
Prep
Date
Analysis Analyst Result
Date
8260 . 101119 11-19-/)4 11-19-04
335.2 1l17S 11-17--04 11-17--04
RL
LR
98
0.0050
Page 3 crf 12
[p:JI llilts
<
%
mg/l
OF RL llll
1
1 0 010 0.0050
•
ltlllllHI STL 111;11■■
S'l'LSa-va.nnah Client • ENSR Consulting & Engineering
Work Order ID ' Channel Master
Laboratory ID ' S451082*2
Sample :ID Trip Blank
Matrix LI S~led ' 11-11-2004
Percent Solids ' Received; 11-13-2004
RESULTS SUMMARY REPORT
Panmeter llethod Batch Prep Analysis Analyst Result Qual !nits DF RI. Ill.
Date Date
O,lorunethane 8260 J.Oll19 11-19-04 11-19--04 RL 1,0 < ug/1 1 1.0 0.39
Broo:methane (Methyl bromide) 8260 J.Oll19 11-19--04 11-19--04 RL 1.0 < ug/1 1 1..0 0.62
Vinyl chloride 8260 J.Oll19 11-19--04 11-19-04 RL LO < ug/1 1 1 .. 0 0.56
Chloroethane 8260 J.Oll19 11-19--04 11-19-04 RL 1.0 < ug/1 1 1.0 Q.78
Methylene chloride
(Di ch loranethane) 8260 101119 11-19-04 11-19-04 RL 5.0 < ug/1 1 5 .. 0 0.64
Acetone 8260 J.Oll19 11-19--04 11-19--04 RL 25 < ug/1 1 25 5.0
Cartxm disulfide 8260 J.Oll19 11-19--04 11-19--04 RL 1.0 < ug/1 1 1.0 0.66
1, 1-Dich loroethene 8260 J.Oll19 11-19-04 11-19--04 RL LO < ug/1 1 1..0 0.36
1,1-Dichloroethane 8260 J.Oll19 11-19--04 11-19--04 RL 1.0 < ug/1 1 1.0 0.36 • cis-1, 2-Dichloroetl'lene 8260 101119 11-19--04 11-19--04 RL 1.0 < ug/1 1 1.0 0.38
trans-1,2-Dichloroethene 8260 J.Oll19 11-19--04 11-19-04 RL LO < ug/1 1 1.0 0.40
Oilorofonn 8260 J.Oll19 11-19--04 11-19--04 RL 1.0 < ug/1 1 1.0 0.37
1,2-Dichloroettiane 8260 J.Oll19 11-19--04 11-19--04 RL 1.0 < ug/1 1 1..0 0.26
2-Butanone (MEI() 8260 J.Oll19 11-19--04 11-19--04 RL 10 < ug/1 1 10 1.3
1,1,1-Trichloroethane 8260 101119 11-19--04 11-19--04 RL 1.0 < ug/1 1 1,0 0.32
Carbon tetrachloride 8260 10lll9 11-19-04 11-19--04 RL 1.0 < ug/1 1 1..0 0.31
Bromodichloranethane 8260 101119 11-19--04 11-19--04 RL 1.0 < ug/1 1 LO 0.14
1,1,2,2-Tetrachloroethane 8260 101119 11-19--04 . 11-19-04 RL 1.0 < ug/1 1 1.0 0.18
1,2-Di chloropr'Opane 8260 J.Oll19 11-19-04 11-19--04 RL 1.0 < ug/1 1 1.0 0.33
trans-1,3-0ichloropropene 8260 101119 11-19--04 11-19--04 RL 1.0 < ug/1 1 LO 0.26
Trichloroet:hene 8260 J.Oll19 11-19--04 11-19-04 RL 1.0 < ug/1 1 1.0 0.37
Di bromoch l oranethane 8260 J.Oll19 11-19--04 11-19--04 RL LO < ug/1 1 1.0 0.50
1,1, 2-Tr ich loroethane 8260 J.Oll19 11-19--04 ll·l!>--04 RL 1.0 < ug/1 1 1.0 0.22
Benzene 8260 J.Oll19 11-19-04 11-19-04 RL 1.0 < ug/1 1 1.0 0.36
cis-1, 3-0i chloropropene 8260 101119 11-19--04 11-19--04 RL 1.0 < ug/1 1 1.0 0.23
Brorofonn 8260 10lll9 11-19--04 11-19--04 RL 1.0 < ug/1 1 1.0 0.33
2-Hexanone 8260 J.Oll19 11-19-04 11-19-04 RL 10 < ug/1 1 10 0.93
4-..,thyl-2-pemanone (MIBK) 8260 1011l9 11-19--04 11-19--04 RL 10 < ug/1 1 10 0.65
Tetrachloroethene 8260 J.Oll19 11-19--04 11-19-04 RI. 1.0 < ug/1 1 1.0 0.35
Toluene 8260 J.Oll19 11-19--04 11-19--04 RL 1.0 < ug/1 1 1.0 0.54
Ch 1 orobenzene 8260 101119 11-19--04 11-19--04 RL 1.0 < ug/1 1 1.0 0.34
Ethyl benzene 8260 J.Oll19 11-19-04 11-19--04 RL 1.0 < ug/1 1 1.0 0,34
Styrene 8260 101119 11-19--04 11-19--04 RL 1,0 < ug/1 1 1.0 0.25
Xylenes, Total 8260 J.Oll19 11-19--04 11-19--04 RL 2.0 < ug/1 1 2 .. 0 1,3
Svrrogate -To1uene-d8 • 8260 1Dlll9 11-19-1>1 11-19-04 RL 98 % 1
Surrogate -
4-Bn:tnof1uorobenzene * 8260 201119 11-19-04 11-19-1>1 RL 94 % 1 •
Page 4 of 12
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•
C1ient
Work Order ID
Laboratory .ID
Sample ID
Matrix
Percent Solids
Parameter
Svr rogate ~-
Dibrcxnorluorome.thane •
CX~,11 STL
i ENSR Consulting
: Channel Master
S451082*2
1 Trip Blank
LI Sampled , 11-11-2004
Received: 11-13-2004
RESULTS SUMMARY REPORT
STL Savannah
llethod Batch Prep
Date
Analysis Analyst Result
Date
()Ja I Iii I ts DF RI.
826() 1f)l1J9 11-19-04 11-19-04 RL 94 1
Page 5 of 12
llll.
• --STL
S'l'L Savannah
Client ENSR Consulting & Engineering
Work Order :rn Channel Master
Laboratory 7D S451082•3
Sample :ID Method Blank
Matrix LI Sampled :
-Pm:·cent Solids Received:
REGULTS SUMMARY REPORT .. ,.,,.,..,. Method Batth Prep Analysis Analyst Re:iult ().ml lhits DF RI. llll.
Date Date
0,1ornnethane 8260 10ll19 ll-19-04 11-19-04 R1. 1.0 < ug/1 1 1.0 0.39
Bran:m!thane (Methyl branide) 8260 10ll19 11-19-04 11-19-04 R1. 1.0 < ug/1 1 1.0 0.62
Vinyl chloride 8260 lOlll.9 11-19-04 11-19-04 R1. 1.0 < ug/1 1 1.0 0.56
O,loroethane 8260 10ll19 11-19--04 11-19-04 R1. 1.0 < ug/1 1 1.0 0.78
Methylene chloride
(Di chloromethane) 8260 10ll19 11-19-04 11-19-04 R1. 5.0 < ug/1 1 5.0 0.64
Acetone 8260 10ll19 11-19--04 11-19-04 RI. 10 < ug/1 1 25 5 .0
Carbon disulfide 8260 10ll19 11-19-04 11-19-04 RI. 1.0 < ug/1 1 LO 0 .. 66
1,1-Di chloroethene 8260 !Olll.9 11-19-04 ll-19-04 RI. 1.0 < ug/1 1 1.0 0.36
1, 1-Di ch loroethane 8260 10ll19 11-19-04 11-19-04 RI. 1.0 < ug/1 1 1.0 0.36 • ci s-1,2-Di chloroethene 8260 10ll19 11-19--04 11-19-04 RI. 1.0 < ug/1 1 1..0 0 .. 38
trans-1,2-Dichloroethene 8260 10ll19 11-19--04 ll-19-04 R1. 1.0 < ug/1 1 1.0 0.40
O!lorofonn 8260 10ll19 11-19--04 11-19--04 RI. 1.0 < ug/1 1 1.0 0.37
1, 2-Di ch loroethane 8260 10ll19 11-19--04 11-19-04 RI. 1.0 < ug/1 1 1.0 0.26
2-Butanone Q,EK) 8260 10ll19 11-19--04 11-19-04 RI. ID < ug/1 1 10 1.3
1,1,1-Ttichlor-oethane 8260 10ll19 11-19-04 11-19-04 RI. 1.0 < ug/1 1 1.0 0.32
Carbon tetrachloride 8260 10l11.9 11-19--04 11-19-04 RI. 1.0 < ug/1 1 1.0 0.31
Branodichloranethane 8260 10ll19 11-19--04 11-19-04 RI. 1.0 < ug/1 1 1.0 0.14
1,1, 2, 2-Tetr ach loroethane 8260 10ll19 11-19--04 11-19-04 RI. 1.0 < ug/1 1 LO 0.!B
1, 2-Di ch loropropane 8260 10ll19 11-19--04 11-19-04 RI. 1.0 < ug/1 1 1.0 0.33
tr ans-1, 3-Di ch loropropene 8260 10ll19 11-19-04 11-19-04 RI. 1.0 < ug/1 1 1.0 0.26
Trichloroethene 8260 !Olll.9 11-19--04 11-19-04 RI. 1.0 < ug/1 1 1..0 0.37
Di brom:x:hloranethane 8260 10ll19 11-19--04 11-19--04 R1. 1.0 < ug/1 1 1.0 o.so
1, 1,2-Trichloroethane 8260 10ll19 11-19-04 11-19--04 RI. 1.0 < ug/1 1 1.0 0.22
Benzene B260 10ll19 11-19-04 11-19-04 RI. 1.0 < ug/1 1 1.0 0.36
cis-1, 3-Di ch. loropropene 8260 lOlll.9 11-19--04 11-19-04 R1. 1.0 < ug/1 1 1-0 0 .23
Brarofunn 8260 10ll19 11-19--04 11-19--04 R1. 1.0 < ug/1 1 1.0 0.33
2-Hexanone 8260 IDlll.9 11-19-04 11-19-04 RI. 10 < ug/1 1 10 0.93
4-/>lethyl-2-pentanone (MIBK) 8260 10ll19 11-19-04 11-19-04 RI. 10 < ug/1 1 10 0.65
Tetrachloroethene 8260 10ll19 11-19--04 11-19-04 RI. 1.0 < ug/1 1 1.0 0.35
Toluene · 8260 !Olll.9 11-19--04 11-19-04 RI. 1.0 < ug/1 1 1.0 0.54
0, lorobenzene 8260 10ll19 11-19-04 11-19--04 R1. 1.0 < ug/1 1 1.0 0.34
Ethylbenzene 8260 10ll19 11-19--04 ll-19-04 R1. 1.0 < ug/1 1 1.0 0 .. 34
Styrene 8260 10ll19 11-19--04 11-19-04 RI. 1.0 < ug/1 1 1.0 0.25
Xylenes, Total 8260 10ll19 11-19-04 11-19--04 R1. 2.0 < ug/1 1 2.0 1.3
Surrogate -Toluene-dB• 8260 UJlll9 11-19-04 11-19-04 RL 98 % 1
Surrogate -
4-8r011Jf1uorobenzene • 8160 lD1119 11-19-04 11-19-04 RL 94 % l •
Page 6 of 12
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•
Client ENSR Consulting
Channel Master
& Engineering
work Order ID
Laboratory ID
Sample Dl
Matrix
t S451082*3
Percent Solids :
Paraneter
Surrogate -
Dibrcmofl1.x:m:meth.3ne ,..
Cyanide
Method Blank
LI Smnpled:
Received:
RESULTS SUMMARY REPORT
Method Batch Prep
Date
Analysis Analyst. Result
Date
8260 · 101119 11.-19-04 11-19-04
335.2 lll7S ll-17-04 11-17-04
Pag@ 7 of 11
RL
LR
96
0.0050
iidi;ihi Mi@i§IM STL
STL Savannah
~I lhits Of RI.
<
,.
og/l
1
1 0.010 0.0050
•
11l!llilMI hi;ii§IM STL
STL Savannah Client ' ENSR consulting & Engineering
work Order ID ' Channel Master
Laboratory ID S451082*14
Sample ID ' Method Blank
Matrix ' LI Sompled ' Percent Solidi, Received.1
RESULTS SUMMARY REPORT
Parameter -Batch Prep Analysis Analyst Result <u,I lrlits DF RL llll.
Date Date
a, loronethane 8260 10ll20 11-20-04 11-20-04 RI. 1.0 < ug/1 1 1.0 0.39
Bronomethane (Methyl bramde) 8260 . lOll20 11-20--04 ll-20--04 RL 1.0 < ug/1 1 1.0 0 .. 62
Vinyl chloride 8260 10ll20 11-20--04 11-20-04 RI. LO < ug/1 1 1.0 0.56
0, l oroethane 8260 10ll20 11-20-04 11-20-04 RI. 1.0 < ug/1 1 1.0 0.78
Methylene chloride
(Dichlorarethane) 8260 10ll20 11-20-04 11-20-04 RI. 5 .. 0 < ug/1 1 5.0 0.64
Acetone 8260 101120 11-20-04 11-20-04 RI. 25 < ug/1 1 25 5 .0
Carbon disulfide 8260 10ll20 11-20--04 11-20-04 RI. 1.0 < ug/1 1 1.0 0.66
1, 1-Dich loroethene 8260 101120 11-20-04 11-20-04 RI. 1.0 < ug/1 1 1.0 0.36
1,1-Dichloroethane 8260 10ll20 11-20-04 11-20-04 RI. 1.0 < ug/1 1 1.0 0 .. 36 • ci s-1,2-Di ch loroethene 8260 lOll20 11-20-04 11-20-04 RI. 1.0 < ug/1 1 1 .. 0 0.38
tr ans-1, 2-Di ch loroethene 8260 lOll20 11-20--04 11-20-04 RI. 1.0 < ug/1 1 1.0 0.40
Chloroform 8260 lOll20 11-20-04 11-20-04 RI. 1.0 < ug/1 1 1.0 0 .. 37
1, 2-Di ch loroethane 8260 101120 11-20--04 11-20-04 RI. 1.0 < ug/1 1 1.0 0.26
2-Butanone (/oEIO 8260 10ll20 11-20-04 11-20-04 RI. 10 < ug/1 1 10 1.3
1,1,1-Trichloroethane 8260 10ll20 11-20-04 11-20-04 RI. 1.0 < ug/1 1 1.0 0.32
Carbon teer ach 1 or i de 8260 10ll20 11-20--04 11-20-04 RI. 1 .. 0 < ug/1 1 1.0 0.31
Bromodichloromethane 8260 10ll20 ll-20--04 ll-20-04 RI. 1.0 < ug/1 1 1.0 0.14
1,1,2,2-Tetrachloroethane 8260 10ll20 11-20-04 11-20-04 RI. 1.0 < ug/1 1 1 .. 0 O.JB
1, 2-Di ch loropropane 8260 lOll20 ll-Z0-04 11-20-04 RI. 1.0 < ug/1 1 1.0 0.33
trans-1,3-Dichloropropene 8260 lOll20 ll-20-01 11-20-04 RI. 1.0 < ug/1 1 1.0 0.26
Tr i ch 1 oroethene 8260 101120 11-20--04 11-20-04 RI. 1.0 < ug(l 1 1.0 0.37
Dibrarnch 1 orunethane 8260 lOll20 11-20--04 11-20--04 RI. 1.0 < ug/1 1 1.0 0.50
1,1,2-Trichloroethane 8260 10ll20 11-20-04 11-20-04 RL 1.0 < ug/1 1 1.0 0.22
Benzene 8260 101120 ll-20--04 ll-20-04 RI. 1.0 < ug/1 1 1.0 0.36
cis-1, 3-Di ch loropropene 8260 Wll20 11-20-04 11-20-04 RI. 1.0 < ug/1 1 1.0 0 .. 23
Branofonn 8260 10ll20 11-20--04 11-20-04 RI. 1.0 < ug/1 1 1.0 0.33
2-Hexarone 8260 10ll20 11-20-04 11-20-04 RL 10 < ug/1 1 10 0.93
4-Nethyl-2-pent:anone (MIBK) 8260 101120 11-20-04 11-20-04 RI. 10 < ug/1 1 10 0 .. 65
Tetrachloroethene 8260 101120 11-20--04 11-20-04 RL 1.0 < ug/1 1 1.0 0.35
Toluene 8260 10ll20 11-20-04 11-20-04 RL 1..0 < ug/1 1 1.0 0.54
OJ l orobenzene 8260 10ll20 11-20-04 11-20-04 RI. 1.0 < ug/1 1 1.0 0.34
Ethyl benzene 8260 10ll20 11-20--04 11-20-04 RI. 1.0 < ug/1 1 1.0 0.34
Styrene 8260 10ll20 11-20-04 11-20-04 RI. 1..0 < ug/1 1 1.0 0.25
Xylenes, Total 8260 ·101120 11-20-04 11-20-04 RI. 2.0 < ug/1 1 2.0 1.3
Surrogate -Toluene-dB·• 8260 101120 11-2/J-04 11-20-04 RL 98 % 1
Surrogate -
4-Brarof1uorobenzene * 8260 ll11120 11-2/J-04 11-20-04 RL 98 % 1 •
Page 8 of 12
•
•
Client
Work Order :ID
Le.boratory ro
Sample ::t:D
Matrix
ENSR Consulting
: Channel Master
I S451082*14
: Method Blank
LI
& Engineering
So,npled :
Percent Solids 1 Received:
Paraneter
Surrogate -
flibranofTuorcmethane .t
Method Batdl
RESULTS SUMMARY REPORT
Prep
Date
Analysis Analyst Result
Date
8260 1011.20 11. -2()-()4 ll -20--04 RL 92
Page 9 of 12
Sit== STL
STL Savannah
Q.sa I \kl its DF RI. ID.
1
•
Uttilt STL
STL Savannah
Client ENSR Consulting & Engineering
Work Order ro ' Channel Mast.er
Laboratory :ro • S451082*5
Sample J:D Lab Control Standard Result
Matrix LI Sampled i
Pa.:i::·cent Sol.ids Received,
LCS RESOLTS SUMMARY REPORT
P81"aieter -8atd1 Spike Elqlected Units Spike~ Accuracy
Result Value _,, limit
1,1-Dichloroethene 8260 = 49 50 ug/1 98 53-144
Trichloroethene 8260 = 50 50 ug/1 100 70-123
Benzene 8260 = 50 so ug/1 100 69-128
Toluene 8260 = 52 so ug/1 1D4 71-129
Chlorobenzene 8260 = so so ug/1 100 n-126
Surrogate -Toluene-dB* 8260 JD1119 Sl so ug/1 102 74-122
Surrogate -
4-Brorofluorcbenzene * 8260 = so so ug/1 100 70-119
Surrogate -
Dibrooofl uorunethane • 8260 101119 49 so ug/1 98 68-129 • Cyanide 33S 2 11175 0 .. 0293 0 .. 0300 mg/1 98 85-115
•
Page JD of 12
•
liUi;I◄ STL Nii£ii§IM ,
S'rL Savannah
Client ENSlt Consulting &: Engineering
Work Order ID Channel Master
Laboratory ZD S451082•16
Sample :ID Lab Control Standard· Result
Matrix ' LI Sampled 1
Percent solide Received.:
LCS RESULTS SUMMARY REPORT
Panmeter -Batch Spike Expected lkllts Spike I Pa:uracy
Result Value Recovery LIDll't
1,1-Dichloroethene 8260 101120 47 so ug/l 94 53-144
Tri ch l oroethene 8260 lOll20 52 so ug/1 104 70-123
Benzene 8260 lOll20 50 50 ug/1 100 69-128
Toluene 8260 lOll20 54 50 ug/1 108 71-129
Qi l orobenzene 8260 101120 52 50 ug/1 104 72-126
surrogate -Toluene-dB • 8260 101120 53 50 ug/l 106 74-122
surrogate -
4-Bronofl uorobenzene • 8160 101120 53 50 ug/l 106 70-119
Surrogate -
Dibrarof1 uoranethane • 8260 101120 49 so ug/l 98 68-129 •
•
Page 11 of 12
•
111111■ STL 11111~1■
STL Savannah
Client ENSR Consulting & Engineering
Work Order :tD ' Channel Master
Laboratory :tD S451082*7
Sample ID Matrix Spike Result (Batch)
Matrix LI Sampled r
Percent Sol.ids Receivedr
MS/MSD RESULTS SUMMARY REPORT
Panneter -Batch Parent Spike E,q,ected lt!lts Spike" Spike " Aco.Jrt!JfCY Precision
Result Result Val"' Recowry RFD Limit Limit
1, 1-0i ch 1oroethene 8260 lDll20 48 50 ug/1 96 11 53-144 30
8260 . 101120 43 50 ug/1 86
Trichloroethene 8260 lDll20 47 50 ug/1 94 11 70-123 30
8260 101120 42 50 ug/1 84
Benzene 8260 lDll20 47 50 ug/1 94 11 69-128 30
8260 101120 42 50 ug/1 84
Toluene 8260 101120 49 50 ug/1 98 11 71-129 30
8260 101120 44 50 ug/1 88
0, 1 orobenzene 8260 101120 46 so ug/1 92 11 72-126 30
8260 101120 41 so ug/1 82 • Surrogate -Toluene-dB* 8260 lDll20 48 so u9/l 96 74-122
8260 lDll20 43 so ug/1 86
Surrogate -
4-Braaofl uorobenzene • 8260 101120 47 so ug/1 94 70-119
8260 lDll20 42 so ug/1 84
Surrogate -
Di brmofl uoromethane • 8260 lDll20 47 50 ug/1 94 68-129
8260 lDll20 43 so ug/1 86
Cyanide 335.2 1117S 0.0307 0.0300 mg/1 102 0.33 85-115 20
335.2 1117S 0 .. 0308 0.0300 mg/1 103
•
Page 12 of 12
•
•
•
STL SAVANNAH
B
E
N s u
<
w
•
B
D
--F33
E
J
p
u
<
'F53
"F54
'F36
Xl
X
y
*F61
'F65
"F73
'F82
Data Qualifiers
Inorganic Data
The reported result is an estimated concentration that is less than the PQL, but greater than or
equal to the MDL
The reported value is an estimated because of the presence of matrix interference
The matrix spike recovery is not within control limits. See case ruurative
The result was determined by Method of Standard Addition (MSA).
The compound was analyzed for, but was not detected at or above the MDI./PQL
The compound was analyzed for, but was not detected at or above the PQL .
The post-digestion spike for furnace AA analysis was out of control limits, while sample
absorbance was Jess than 50% of spike absorbance.
Duplicate analysis is not within control limits .
Or·ganic Data
The analyte was found in the associated method blank.
The reported 1esult is from a secondary dilution
Control limits are established only for smrogate concentration levels specified by EPA methods.
Because the sample was diluted pdor to analysis, surrogate recoveries are not repmted.
The repoited resuh exceeded the cal.Jbration range of the instrument
The repmted result is an estimated concentration that is Jess than the PQL, but greater than or
equal to the MDL
The GC or HPLC confirmation criteria was exceeded. The relative percent difference is greater
than 40% between the two GC cohnnns or HPLC detectm.
The compound was analyzed for, but was not detected at 01 above the MDL/PQL..
The compound was analyzed for but was not detected at or above the PQL.
Because smrogate recovedes were outside established limits the sample was re-extracted and/or
1eanalyzed Comparable results were obtamed.
Because surrogate recoveries were outside established limits, the sample was re-extracted and/or
reanalyzed. Both sets of data me provided.
Surrogate recovery was outside of established limits due to a coeluting matrix interference present
in the sample.
Internal standards recovered outside ofadvisory limits.
Surrogate recovery was outside of advisory limits.
Spike recovery was outside of advisory limits ..
Universal
The recoveries of the matrix spikes are outside advisory limits due to the abundance oftbe target
analyte in the sample.
Elevated detection limits were reported due to smnple matrix interfmence which required sample
or extract dilution
Matrix spike recoveries were outside advisory limits due to matrix inteiference present in the
sample.
Insufficient sample volmne was available to perform batch specific matrix spikes.
The test results in this report meet all NELAP requirements for parameteI, for which accreditation is
required or available. Any exceptions to NELA1' requiiements me noted in this repmt. Pursuant to NEIAP,
this ieport may not be reproduced, except in full, without the written approval of the laboratory .
•
December 2004 Analytical Data
•
•
•
•
•
Client
Report to:
STL Log #
Cl lent Project# Project Descrlption Report Date
STL Savannah 5102 LaRoche Ave Savannah, Ga 31404
Mr. Gerald Hornaday ENSR Consulting & Engineering 7041 Old Wake Forrest Rd
Raleigh, NC 27616
5452405
10140-003 Channel Master 12-29-04
Page l of 9
►iiiiilkl fllili§iii STL
• IJlllrl~I STL lllill~ill
STL Savannah
Client ENSR Consulting ti: Engineering
Work Order 7D • Channel Master
Laboratory XD • S452405*1
Sample :ID • Effluent
MatriK LI Sampled ' 12-16-2004
Percent Solids Received: 12-18-2004
RESULTS SUMMARY REPORT
Parameter !'ethod Batch Pn,p Analysis Analyst Result Qual Lill ts DF RL llll.
Date Date
Ch lorcmethane 8260 2Pl228Q 12-28-04 12-28-04 PC 1.0 < ug/1 l 1.0 0.39
Brooonethane (Methyl bromide) 8260 2Pl228Q 12-28-04 12-28-04 PC 1.0 < ug/1 1 1.0 0.62
Vinyl chloride 8260 2Pl228Q 12-28-04 12-28-04 PC 1.0 < ug/1 1 1.0 0.56
Ch 1 oroethane 8260 2Pl2280. 12-28-04 12-28-04 PC 1.0 < ug/1 l 1.0 0.78
~thylene chloride
(Oichloranethane) 8260 2Pl228Q 12-28-04 12-28-04 PC s.o < ug/1 l 5.0 0.64
Acetone 8260 2Pl2280. 12-28-04 12-28-04 PC 25 < ug/1 l 25 s.o
Carbon disulfide 8260 2Pl228Q 12-28-04 12-28-04 PC LO < ug/1 l 1.0 0.66
1,1-Dichloroethene 8260 2Pl228Q 12-28-04 12-28-04 PC 1.0 < ug/1 l l..O 0.36
1, 1-Di ch lo roe thane 8260 2Pl228Q 12-28-04 12-28-04 PC 1.0 < ug/1 1 1.0 0.36
ci s-1, 2-Di chloroethene 8260 2Pl2280. 12-28-04 12-28-04 PC 1.0 < ug/1 l 1.0 0.38 • trans-1,2-0ichloroethene 8260 2Pl2280. 12-28-04 12-28-04 PC 1.0 < ug/1 l 1.0 0.40
Chlorofonn 8260 2Pl2280. 12-28-04 12-28-04 PC 1.0 < ug/1 l 1.0 0.37
1, 2-Di chloroethane 8260 2Pl228Q 12-28-04 12-28-04 PC 1.0 < ug/1 l 1.0 0.26
2-Butanone (MEI() 8260 2Pl2280. 12-28-04 12-28-04 PC 10 < u9/l l 10 1.3
1,1,1-Trichloroethane 8260 2Pl2280. 12-28-04 12-28-04 PC 1.0 < ug/1 l 1.0 0.32
Carbon tetrachloride 8260 2Pl228Q 12-28-04 12-28-04 PC 1.0 < u9/l l 1.0 0.31
Braoodich loro:nethane 8260 2Pl228Q 12-28-04 12-28-04 PC 1.0 < ug/1 l 1.0 0.14
1,1, 2, 2-Tetrachloroethane 8260 2Pl2280. 12-28-04 12-28-04 PC 1.0 < ug/1 l LO 0.18
1, 2-Di ch loropropane 8260 2Pl2280. 12-28-04 12-28-04 PC l..O < ug/1 l l..O 0.33
trans-1,3-Dichloropropene 8260 2Pl228Q 12-28-04 12-28-04 PC 1.0 < ug/1 1 1.0 0.26
Tdchloroethellt! 8260 2Pl228Q 12-28-04 12-28-04 PC 1.0 < ug/1 1 1,0 0.37
Dibranochloromethane 8260 2Pl228Q 12-28-04 12-28-04 PC 1.0 < ug/1 1 1.0 a.so
1,1, 2.:.Tri chloroethane 8260 2Pl228Q 12-28-04 12-28-04 PC 1.0 < ug/1 l 1.0 0.22
Benzene 8260 2Pl228Q 12-28-04 12-28-04 PC 1.0 < ug/1 l 1.0 0.36
ci s-1, 3-Di chloropropene 8260 2Pl228C112-28-04 12-28-04 PC 1.0 < ug/1 1 1.0 0.23
Bromofonn 8260 2Pl228Q 12-28-04 12-28-04 PC 1.0 < ug/1 l 1.0 0.33
2-Hexanone 8260 2Pl228Q 12-28-04 12-28-04 PC 10 < ug/1 l 10 0,93
4-Methyl-2-pentanone (MIBK) 8260 2Pl228Q 12-28-04 12-28-04 PC 10 < ug/1 l 10 0.65
Tetrachloroethene 8260 2Pl2280. 12-28-04 12-28-04 PC 1.0 < ug/1 1 1.0 0.35
Toluene 8260 2Pl2280. 12-28-04 12-28-04 PC 1.0 < ug/1 1 1.0 0.54
Ch lorobenzene 8260 2Pl2280. 12-28-04 12-28-04 PC 1.0 < ug/1 1 1.0 0.34
Ethyl benzene 8260 2Pl2280. 12-28-04 12-28-04 PC 1.0 < ug/1 1 1.0 0.34
Styrene 8260 2Pl228Q 12-28-04 12-28-04 PC 1.0 < ug/1 l 1.0 0.25
Xylenes, Total 8260 2Pl2280. 12-28-04 12-28-04 PC 2.0 < ug/1 1 2.0 1.3
Surrogate -To7uene-d8 • 8260 2Pl228Cl 12-28·0-I 12-28-04 PC 100 ~ l
Surrogate -
4-Bromof1uorobenzene • 8260 2Pl228Q 12-18-04 12-28-04 PC 92 ~ 1 •
Page 2 of 9
•
•
•
Client ENSR Consulting & Engineering
Channel Master
S452405*1
Effluent
iiiii;lkl iill;♦i§iii STL
STL Savmmah
Work Order I:D
Laboratory :ID
Sample ID
Matrix : LI Sampled : 12-16-2004
Percent Solids 1
Panmeter
Surrogate -
Dibrcrnof7uoromerhane *
Cyanide
Received1 12-18-2004
RESOL'l'S SUMMARY REPOR'l'
Method Batch Prep
Date
Analysis Analyst Result
Date
8260
llS.2
2PlZ28Q 12-28-04 12-28-04
122]5 12-21-04 12-22-04
Page 3 of 9
PC
LR
104
0.0050
Qual lhlts
< " mg/1
DF Rl lllll.
I
1 0.010 0.0050
•
lti!llil!I STL Elill~III
S'l'L Savannah
Client ENSR Consulting Ii Engineering
Work Order ID ' Channel Master
Laboratory ID ' S452405*2
Sample ID Trip Blank
Matrix LI Sampled ' 12-16-2004
Percent Solids Received: 12-18-2004
RESULTS SUMMARY REPORT
Parameter Method Batdl Pn,p Analysis Analyst Result ~, lhlts DF RL !!ll.
Date Date
01 loronethane 8260 2PI228Q 12-28-04 12-28-04 PC l.O < ug/1 l 1.0 0.39
Braronethane (Methyl bromde) 8260 2P1228Q 12-28-04 12-28-04 PC l.O < ug/1 1 1.0 0.62
Vinyl chloride 8260 2P122BQ 12-28-04 12-28-04 PC 1.0 < ug/1 l 1.0 0.56
Olloroethane 8260 2Pl22BQ 12-28-04 12-28-04 PC l.O < ug/1 l 1.0 0.78
Methylene chloride
(Di ch 1 oronethane) 8260 2Pl2280 12-28-04 l2-28-D4 PC s.o < ug/1 1 5.0 0.64
Acetone 8260 2Pl22BQ 12-28-04 12-28-04 PC 25 < ug/1 1 25 5.0
carbon disulfide 8260 2Pl22BQ 12-28-04 12-28-04 PC 1.0 < ug/1 1 1.0 0.66
1,1-Dichloroethene 8260 2P122BQ 12-28-04 12-28-04 PC l.O < ug/1 1 1.0 0.36
1,1-Dichloroethane B260 2P122BQ 12-28-04 12-28-04 PC l.O < ug/1 1 1.0 0.36
cis-1,2-Dichloroethene 8260 2P122BQ 12-28-04 12-28-04 PC 1.0 < ug/1 1 1.0 0.38 • trans-1,2-Dichloroethene 8260 2PI22BQ 12-28-04 12-28-04 PC 1.D < ug/1 1 1.0 0.40
Chlorofonn 8260 2PI22BQ 12-28-04 12-28-04 PC 1.0 < ug/1 1 1.0 0.37
1,2-Dichloroethane 8260 2P1228Q 12-28-04 12-28-04 PC 1.0 < ug/1 1 1.0 0.26
2-Butanone (MEK) 8260 2P1228Q 12-28-04 12-28-04 PC 10 < ug/1 1 10 1.3
1,1,1-Trichloroethane 8260 2P1228Q 12-28-04 12-28-04 PC 1.0 < ug/1 1 1.0 0.32
carbon tetrachloride 8260 2P1228Q 12·28-04 12-28-04 PC 1.0 < ug/1 1 1.0 0.31
Brom::idichlorcmethane 8260 2P122BQ 12-28-04 12-28-04 PC 1.0 < ug/1 1 1.0 0.14
1,1,2,2-Tetrachloroethane 8260 2Pl2280 12-28-04 12-28-04 PC 1.0 < ug/1 1 1.0 0.18
1,2-Di chloropropane 8260 2P1228Q 12·28-04 12-28-04 PC 1.0 < ug/1 1 1.0 0.33
trans-1, 3-Dichloropropene 8260 2P1228Q 12-28-04 12-28-04 PC LD < ug/1 1 1.0 0.26
Trichloroethene 8260 2P122BQ 12-28-04 12-28-04 PC LO < ug/1 1 1.0 0.37
Oibromoch1oromethane 8260 2P1228Q 12-28-04 12-28-04 PC 1.0 < ug/1 1 1.0 o.so
1,1,2-Trichloroethane 8260 2P1228Q 12-28-04 12-28-04 PC 1.0 < ug/1 1 1.0 0.22
Benzene 8260 2P1228Q 12-28-04 12-28-04 PC 1.0 < ug/1 1 1.0 0.36
cis-1,3-Dichloropropene 8260 2P1228Q 12-28-04 12-28-04 PC 1.0 < ug/1 1 1.0 0.23
Bromofonn 8260 2P122BQ 12-28-04 12-28-04 PC 1.0 < ug/1 1 1.0 0.33
2-Hexanone 8260 2P122BQ 12-28-04 12-28-04 PC 10 < ug/1 1 10 0.93
4-Methy 1-2-pentanone (MIBX) 8260 2Pl2280 12-28-04 12-28-04 PC 10 < ug/1 1 10 0.65
Tetrachloroethene 8260 2P1228Q 12-28-04 12-28-04 PC 1.0 < ug/1 1 1.0 0.35
,:o1uene 8260 2Pl22BQ 12-28-04 12-28-04 PC 1.0 < ug/1 1 1.0 0-54
Ollorobenzene 8260 2P122BQ 12-28-04 12-28-04 PC 1 .. 0 < ug/1 1 1.0 0.34
Ethyl benzene 8260 2P122BQ 12-28-04 12-28-04 PC 1.0 < ug/1 1 1.0 0.34
Styrene 8260 2P122BQ 12-28-()4 12-28-04 PC 1.0 < ug/1 1 1.0 0.25
Xylenes, Total 8260 2Pl22BQ 12-28-()4 12-28-04 PC 2.0 < ug/1 1 2.0 l.l
Surrogate -Toluene-dB~ 8260 2Pl228Q 12-28-04 12-28-04 PC 100 ~ 1
Surrogate -
4-Bn:mof1uorobenzene • 8250 2Pl228Q 12-28-04 12-28.a.4 PC 92 •. ,, l •
Page 4 of 9
•
•
•
Client
Work Order ID
Laboratory ID
Sample :rn
Matrix
Percent Solids
Paraneter
Surrogate -
D'ibra11of1uoranethc1ne ,.
iiiii;lki
Miiiiii§lii STL
ENSR Consulting
Channel Master
S452405*2
I Trip Blank
• LI
& Engineering
Sampled , 12-16-2004
Received: 12-18-2004
RESULTS SUMMARY REPORT
S'l'L Savannah
Method Batth Prep
Date
Analysis Analyst Result
Date
Qual lkllts DF RL
8250 . JP1128Q 12-28-04 12-28-04 PC 104 l
Page s of 9
. lllL
•
llillil~I STL llilill~l 11
STL Savannah
client ENSR Consulting & Engineering
Work Order ID ' Channel Master
Laboratory ID S452405*3
Sample :ID Method Blank
Matrix LI Sampled :
Percent Solids Received:
RESULTS SOMMARY REPORT
Panmeter Method Batch Prep Analysis Analyst Result Qual I.hits OF RL !Ill
Date Date
Chloromethane 8260 21'12280 12-28-04 12-28-04 PC 1.0 < ug/1 1 1.0 0.39
Brooonethane (Methyl brani de) 8260 21'12280 12-28-04 12-28-04 PC 1.0 < ug/1 1 1.0 0.62
Vinyl chloride 8260 21'12280 12-28--04 12-28-04 PC 1.0 < ug/1 1 1.0 0.56
Chloroethane 8260 21'12280 12-28--04 12-28-04 PC 1.0 < ug/1 1 1.0 0.78
»:!thylene chloride
(Dichloromethane) 8260 21'12280 12-28-04 12-28-04 PC 5.0 < ug/1 1 5.0 0.64
Acetone 8260 21'12280 12-28--04 12-28-04 PC 25 < ug/1 1 25 5.0
Carbon di sulfide 8260 21'12280 12-28-04 12-28-04 PC 1..0 < ug/1 1 1.0 0.66
1,1-Dichloroethene 8260 21'12280 12-28--04 12-28-04 PC 1..0 < ug/1 1 1.0 0.36
1,1-Di ch loroethane 8260 21'12280 12-28-04 12-28-04 PC 1..0 < ug/1 1 1.0 0.36
cis-1,2-0i chloroethene 8260 2Pl2280 12-28--04 12-28--04 PC 1.0 < ug/1 1 1.0 0.38 • trans-1,2-Dichloroethene 8260 21'12280 12-28--04 12-28-04 PC 1.0 < ug/1 1 1.0 0-40
Chloroform 8260 21'12280 12-28--04 12-28-04 PC 1.0 < ug/1 1 1.0 0.37
1,2-Dichloroethane 8260 2Pl2280 12-28--04 12-28-04 PC 1.0 < ug/1 1 1.0 Q.26
2-Butanone (MEK) 8260 21'12280 12-28--04 12-28--04 PC 10 < ug/1 1 10 1.3
1,1,1-Trichloroethane 8260 21'12280 12-28-04 12-28--04 PC 1..0 < ug/1 1 1.0 0.32
Carbon tetrachloride 8260 21'12280 12-28-04 12-28-04 PC 1.0 < ug/1 1 1..0 0.31
Broroodichloromethane 8260 21'12280 12-28-04 12-28-04 PC 1.0 < ug/1 1 1.0 0.14
1,1,2,2-Tetrachloroethane 8260 21'12280 12-28-04 12-28-04 PC 1.0 < ug/1 1 1.0 0.18
1,2-Dichloropropane 8260 2P12280 12-28--04 12-28-04 PC 1.0 < ug/1 1 1.0 0.33
trans-1,3-Dichloropropene 8260 2P12280 12-28-04 12-28-04 PC 1.0 < ug/1 1 1.0 0.26
Trichloroethene 8260 21'12280 12-28-04 12-28-04 PC 1.0 < ug/1 1 1.0 0.37
Dibraoochlorome.thane 8260 2Pl2280 12-28-04 12-28-04 PC 1.0 < ug/1 1 1.0 a.so
1,1,2-Trichloroethane 8260 21'12280 12-28-04 12-28-04 PC 1.0 < ug/1 1 1.0 0.22
Benzene 8260 21'12280 12-28-04 12-28-04 PC 1.0 < ug/1 1 1.0 0.36
cis-1,3-Dichloropropene 8260 21'12280 12-28-04 12-28-04 PC 1.0 < ug/1 1 1.0 0.23
Brarofonn 8260 21'12280 12-28-04 12-28-04 PC 1.0 < ug/1 1 1.0 0.33
2-Hexanone 8260 21'12280 12-28-04 12-28-04 PC 10 < ug/1 1 10 0.93
4-Methyl-2-pentanone (MIBK) 8260 21'12280 12-28--04 12-28-04 PC 10 < ug/1 1 10 0.65
Tetrachloroetkene 8260 21'1228012-28--04 12-28-04 PC 1.0 < ug/1 1 1.0 0.35
Toluene 8260 2Pl2280 12-28--04 12-28·04 PC 1..0 < ug/1 1 1.0 0.54
Oflorobenzene 8260 2Pl2280 12-28--04 12-28-04 PC 1.0 < ug/1 1 1.0 0.34
Ethylbenzene 8260 21'12280 12-28-04 12-28-04 PC 1.0 < ug/1 1 1.0 0.34
Styrene 8260 21'12280 12-28-04 12-28-04 PC 1.0 < ug/1 1 1.0 0.25
Xylenes, Total 8260 21'12280 12-28-04 12-28-04 PC 2.0 < ug/1 1 2.0 1.3
Surrogate -To1uene-d8 -8260 2P11280 12-28-04 12-Z8-(J,( PC 100 ~ 1
Surrogate -
4-Brononuorobenzene * 8260 2Pl2280 12-28-04 12-18-04 PC !l4 .. • 1 •
Page 6 of 9
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•
Client
Work Order ID
Laboratory ID
Sample :CD
MatriK
Percent Solids
Parameter
Surrogate -
D'ibrai10f1uoronerh;me ,..
Cyanide
ENSR Consulting
1 Channel Master
t S452405*3
r Method Blank
I LI
&. Engineering
Sampled:
Received:
RESULTS SUMMARY REPORT
Method Batch Prep
Date
Analysis Analyst Result
Date
8260 2Pl2280 12-28-04 12-28-04
335.2 12215 12·21--04 12·22·04
Page 7 of 9
PC
LR
104
0.DD50 <
►iiii;iki iii;§i§i@ STL
STL Sav8llllah
n,g/1
OF Rl l1ll.
1
1 0.010 0.DD50
•
•
Client
Work Order ID
Laboratoey ID
Sample ID
Matrix
Percent Solids
Pa,..,.,..r
1, 1-Di ch loroethene
Trichloroethene
Benzene
To1uene
0, 1 orobenzene
Surrogate -Toluene-dB •
Surrogate -
4-Branofluorobenzene '*
Surrogate -
Di branof1 uoromethane •
Cyanide
'
ENSR Consulting &: Engineering
Channel Master
S452405*5
Lab Control Standard Result
LI Sampled:
Received;
LCS RESUt.TS SUMMARY REPORT
Method Batch Spike upected lhlts
Result Value
8260 2?12280. 58 50 ug/1
8260 2?12280. 55 50 ug/1
8260 2?12280. 54 50 ug/1
8260 2Pl228Cl 51 50 ug/1
8260 2P1228Cl 52 50 ug/1
8260 2Pl228Q 51 50 ug/1
8260 2P1228Cl 48 50 ug/1
8260 2P1228Cl 54 50 ug/1
335.2 12215 0.0288 0.0300 mg/1
Page 8 of 9
IJlllil~I STL 11111§111
STL Savannab
Spike. Accuracy.
Recovery Limit
116 53-144
110 70-123
108 69-128
102 71-129
104 72-126
102 74-122
96 70-119
108 68-129
96 BS-ill
•
11lllilMI STL lilill~liil
STL Savannah
Client ' ENSR Consulting & Engineering
Work Order ID ' Channel Master
Laboratory ID S452405*7
Sample ID Matrix Spike Result (Batch!
Matrix LI Sampled,
Percent Solids Received,
MS /IISD RESOLTS SUMMARY REPORT
Paraneter MetJ-od llat,:h Parent Spike Expected lhlts Spike. Spike • Accuracy Precision
Result Result Value Recovery RPO Limit Limit
1,1-0ichloroethene 8260 2P1228Cl 64 50 ug/1 128 13 53-144 30
8260 2P1228Cl 56 so ug/1 112
Trichloroethene 8260 2P1228Cl 55 50 ug/1 110 5-6 70-123 30
8260 2P1228Cl 52 so ug/1 104
Benzene 8260 2P1228Cl 54 so ug/1 108 3.8 69-128 30
8260 2P1228Cl 52 so ug/1 104
Toluene 8260 2P1228Cl 55 so ug/1 110 7.5 71-129 30
8260 2P1228Cl 51 so ug/1 102
Oilorobenzene 8260 2P1228Cl 51 so ug/1 102 2.0 n-126 30
8260 2P1228Cl so 50 ug/1 100
· Surrogate -Toluene-dB * 8260 2P1228Cl 55 so ug/1 110 74-122 • 8260 2P1228Cl 51 so ug/1 102
Surrogate -
4-Brcm:ifl uorobenzene * 8260 2P1228Cl 47 50 ug/1 94 70-119
8260 2P1228Cl 44 50 ug/1 88
Surrogate -
Dibromofluoromethane * 8260 2P1228Cl 58 50 ug/1 116 68-129
8260 2P1228Cl 52 50 ug/1 104
Cyanide 335.2 12215 0.0288 0.0300 mg/1 96 6.1 85-115 20
335.2 12215 0.0306 0.0300 mg/1 102
•
Page 9 of 9
•
•
STL SAVANNAH
B
E
N s u
<
w
•
B
D
•F33
E
J
p
u
<
*F53
*F54
•F36
XI
X
y
•F61
*F65
*F73
•F82
Data Qualifiers
Inore:anic Data
Toe reported result is an estimated concentration that is less than the PQL, but greater than or
equal to the MDL. .
Toe reported value is an estimated because of the presence of matrix interference.
Toe matrix spike recovery is not "ithin control limits. See case narrative.
Toe result was determined by Method of Standard Addition (MSA).
Toe compotmd was analyzed for, but was not detected at or above the MDL/PQL.
Toe compound was analyzed for, but was not detected at or above the PQL.
Toe post-digestion spike for furnace AA analysis was out of control limits, while sample
absorbance was less than 50% of spil:e absorbance.
Duplicate analysis is not mthin control limits .
Organic Data
Toe analyte was fotmd in the associated method blank.
Toe reported result is from a secondary dilution
Control limits are established only for SlllTOgate concentration levels specified by EPA methods.
Because the sample was diluted prior to analysis, surrogate recoveries are not reported.
Toe reported result exceeded the calibration range of the instrument.
The reported result is an estimated concentration that is less than the PQL, but greater than or
equal to the MDL
Toe GC or HPLC confirmation criteria was exceeded. The relative percent difference is greater
than 40% between the two GC columns or HPLC detectors
The COIDJ>Otmd was analyzed for, but was not detected at or above the MDL/PQL.
The compound was analyzed for but was not detected at or above the PQL.
Because surrogate recoveries were outside established limits the sample was re-extracted and/or
reanalyzed. Comparable results were obtained. ·
Because surrogate recoveries were outside established limits, the sample was re-extracted and/or
reanalyzed. Both sets of data are prov:ided.
Surrogate recovery was outside of established limits due to a coeluting matrix interference present
in the sample.
Internal standards recovered outside of adv:isory limits.
Surrogate recovery was outside of adv:isory limits.
Spike recovery was outside of adv:isory limits-
Unh•ersal
The recoveries of the matrix spikes are outside adv:isory limits due to the abundance oftbe target
analyte in the sample.
Elevated detection limits were reported due to sample matrix interference which required sample
or extraet dilution.
Matrix spike recoveries were outside advisory limits due to matriJ< interference present in the
sample.
Insufficient sample volume was available to perform batch specific matrix spikes.
Toe test results in this report meet all NELAP requirements for parameters for which accreditation is
required or available. Any exceptions to NELAP requirements are noted in this report. Pursuant to NELAP,
this report may not be reproduced, except in full, without the written approval of the laboratory .
Serial Number · 3 8 8 3 2
ANALYSIS REQUEST AND CHAIN OF CUSTODY RECORD (17) STL Savaooah 7C-5102 laRoche Avenue
Savannah, GA 31404
Website: www.sll-inc.com
Phone: [phone]
Fax: 19121352-0165
. -. . ·,TR E N_;r.:· STL
PROJECT REFERENCE PROJECT NO.
/tJ/'f(j -t,l:J.-!;~:).
P.O. NUMBER
RELINQUISHED BY: lStGNATllfiEI DATE TIME
•
TIME
/°3' tJj
PROJECT LOCATION
{STATE! ,'l.)C..
CONTRACT NO.
MATRIX
TYPE
0 Alternate Laboratory NameAocation
Phone:
Fa"x:
REQUIRED ANALYSIS
NUMBER OF CONTAINERS SUBMITTED
RE~NQUISHEO BY: ,,NA.TURD • ~I ·. DATE TIME RELINQUISHED BY: ISIGNAT\JR£J
~ ~~ I :n ti'} /a :/5
RECEIVED BY: tSlGNATURD TE TIME RECEIVED BY: !SIGNATUR[J
LABORATORY USE ONLY
CUSTODY INTACT
YES 0
NO 0
CUSTODY
SEAL NO.
•
STL SAVANNAH LABORATORY REMARKS
~VJ
PAGE I OF I
REMARKS
DATE TIME
DATE TIME
STL8240-680112/021 •
January 2005 Analytical Data
•
•
•
•
•
Client
Report to:
STL Log # Cl lent Project #
Project Description Report Date
STL Savannah
5102 LaRoche Ave Savannah, Ga 31404
Mr. Gerald Hornaday
ENSR Consulting & Engineering 7041 Old Wake Forrest Rd Raleigh, NC 27616
5540488
10140-003 Channel Master 01-24-05
Page 1 of 9
iiU#:1§1
@@;§@§iii STL
•
1-tDlhl§I STL tliili~III
STL Savannah
Client ENSR Consulting &. Engineering
Work Order ID Channel Master
Laboratory ID S540488*1
Sample ID Effluent
Matrix I LI Sampled : 01-1a-200s
Percent Solids Received1 01-19-2005
RESULTS SUMMARY REPORT
Parameter l!etl1od Batch Prep Analysis J\nalyst Result (),al Units DF Rt. !Ill
Date Date
Ol1oromethane 8260 1A0120 01-20-05 01-20-05 S5 1.0 < ug/1 l 1.0 0.39
Broroomethane (Methyl bronride) 8260 lA0120 01-20-05 01-20-05 55 1.0 < ug/1 l 1.0 0.62
Vinyl chloride 8260 lA0120 01-20-05 01-20-05 S5 1.0 < ug/1 l 1.0 0.56
Chloroethane 8260 1A0120 01-20-05 01-20-05 ss 1.0 < ug/1 1 1.0 o. 78
Methylene chloride
(Oichloromethane) 8260 lA0120 01-20-05 01-20-05 ss 5.0 < ug/1 1 5.0 0.64
Acetone 8260 lA0120 01-20-05 01-20-0s ss 2S < ug/1 l 2S s.o
Carbon disulfide 8260 1A0120 01-20-05 01-20-05 ss 1.0 < ug/1 1 1.0 0.66
1, 1-Dichloroethene 8260 lA0120 01-20-05 01-20-05 ss 1.0 < ug/1 1 1.0 0.36
l, 1-0ich loroethane 8260 lA0120 01-20-05 01-20-05 ss 1.0 < ug/7 1 1.0 0.36 • cis-1,2-Dichloroethene 8260 lA0120 01-20-05 01-20-05 ss LO < ug/1 1 1.0 0.38
trans-1,2-Dichloroethene 8260 1A0120 01-20-05 01-20-0s ss 1.0 < ug/1 1 1.0 0.40
Chlorofonn 8260 lA0120 01-20-05 01-20-05 ss 1.0 < ug/1 l 1.0 0.37
1,2-Di chloroethane 8260 lA0120 01-20-05 01-20-05 ss 1.0 < ug/1 1 1..0 0 .. 26
2-Butanone (MEK) 8260 1A0120 01-20-05 01-20-05 ss 10 < ug/1 1 10 1.3
1,1, 1-Trichloroethane 8260 lA0120 01-20-05 01-20-05 ss 1.0 < ug/1 1 1.0 0.32
Carbon tetrachloride 8260 lA0120 01-20-05 01-20-05 ss 1.0 < ug/1 l 1.0 o.31
Bromodichloranethane 8260 lA0120 01-20-05 01-20-05 ss 1.0 < ug/1 1 1.0 0.14
1,1,2,2-Tetrachloroethane 8260 lA0120 01-20-05 01-20-05 ss 1.0 < ug/1 l 1.0 0.18
l, 2-0i ch loropropane 8260 1A0120 01-20-05 01-20-05 ss 1.0 < ug/1 l 1.0 0.33
trans-1, 3-0i ch loropropene 8260 1A0120 01-20-05 01-20-05 ss 1.0 < ug/1 l LO 0 26
Tr ich 1 oroethene 8260 lA0120 01-20-05 01-20-05 ss 1.0 < ug/1 l 1.0 0.37
Dibromochlorcmethane 8260 lA0120 01-20-05 01-20-05 ss 1.0 < ug/1 1 1.0 0 50
1,1,2-Trichloroethane 8260 1A0120 01-20-05 01-20-05 ss l.O < ug/1 1 1.0 0,22
Benzene 8260 lA0120 01-20-05 01-20-05 ss 1.0 < ug/1 1 1.0 0.36
cis-1, 3-Di ch loropropene 8260 JA0120 01-20-05 01-20-05 ss 1.0 < ug/1 1 l.O 0.23
Brcrnofonn 8260 lA0120 01-20-05 01-20-05 ss 1.0 < ug/1 l l.O 0.33
2-Hexanone 8260 lA0120 01-20-05 01-20-05 ss 10 < ug/1 l 10 0.93
4-Methyl-Z-pentanone (MIBI() 8260 lA0120 01-20-05 01-20-05 ss 10 < ug/1 l 10 0.65
Tetrachloroethene 8260 lA0120 01-20-0s 01-20-05 ss l.O < ug/1 1 1.0 0.35
Toluene 8260 lA0120 01-20-05 01-20-05 ss LO < ug/1 l LO 0.54
Ch lorobenzene 8260 lA0120 Ol-20-05 01-20-05 ss 1.0 < ug/1 l LO 0.34
Ethyl benzene 8260 lA0120 01-20-05 01-20-05 ss 1.0 < ug/1 l LO 0.34
Styrene 8260 lA0120 01-20-05 01-20-05 ss 1.0 < ug/1 l 1.0 0.21
Xylenes, Total 8260 lA0120 01-20-05 01-20-05 ss 2.0 < ug/1 l 2.0 l.l
S11rrog,1re -To1uenc-d8 ,,. BZ60 JA0ll0 01-Z0-05 01-20-05 ss 98 ~ l
Surrogate ·
,1-nroocf111orobem:ene ~ 8160 JA0l/0 01-Z0-05 01-Z0-05 ss 10:? ~ 1 •
Page 2 of 9
•
•
Client
Work Order ID
Laboratory ID
Sample ID
Matrix
Percent Solids
Paraneter
Surrog,,re -
Di/Jromof1u01ometh,1ne *
Cyanide
BNSR Consulting
1 Channel Master
1 S540488*1
Effluent
&. Engineering
iiUHhi§I
@§h§:§§66 STL
STL Savannah
LI Sampled : 01-18-2005
Received: 01-19-2005
Method Batdl
RESULTS SUMMARY REPORT
Prep
Date
Analysis 111\alyst Result
Date
8260 1A0120 01-20-05 01-20-05
335.2 01205 01-20-05 01-21-05
ss
LR
10,,
o. 0052
Page 3 of 9
Qual Units OF Rl. llll.
1
mg/I 0.010 0.0050
•
1-111!1 !llil§I STL IIIBiti~ffiifll
STL Savannah
Client ENSR Consulting &; Engineering
Wo:ck Orde:c ID channel Master
Laboratory ID S54048B*2
Sample ID Trip Blank
Matrix LI Sampled ' 01-18-2005
Percent Solids Received: 01-19-2005
RESULTS SUMMARY REPORT
Paraneter Method Batch !'rap Analysis Analyst Result Qual Units OF RI. WL
Date Date
Chloromethane 8260 JA0120 01-20-05 01-20-05 ss 1.0 < ug/1 l 1.0 0 39
Braronethane (Methyl bromide) 8260 JA0120 01-20-05 01-20-05 ss 1.0 < ug/1 l 1.0 0.61
Vinyl chloride 8260 JA0120 01-20-05 01-20-os ss 1.0 < ug/1 l LO o. 56
Chloroethane 8260 JA0120 01-20-05 01-20-05 ss 1.0 < ug/1 1 1.0 0.78
Methylene chloride
(Di chloromethane) 8260 JA0120 01-20-05 01-20-05 ss 5.0 < ug/1 l 5.0 0,64
Acetone 8260 JA0120 01-10-05 01-20-05 5S 15 < ug/1 1 15 5 .o
Cartx:m di sulfide 8160 JA0120 01-10-05 01-10-os S5 1.0 < ug/1 l 1.0 0.66
l, 1-0i ch loroethene 8260 JA0120 01-10-05 01-20-05 ss LO < ug/1 l 1-0 0.36
l, 1-Di chl ornethane 8160 1A0120 01-10-05 01-20-0s 5S 1.0 < ug/1 l 1.0 0.36 • ti s-1, 2-Dich loroethene 8160 1A0120 01-10-05 01-10-05 ss LO < ug/1 1 1.0 o. 38
trans-1, 2-0ich loroethene 8160 1A0120 01-10-05 01-10-05 ss 1.0 < ug/1 1 1.0 0,40
Chloroform 8160 1A0120 01-20-05 01-10-05 5S 1.0 < ug/1 1 LO 0.37
1,2-0ichloroethane 8260 1A0120 01-20-05 01-20-05 5S LO < ug/1 1 1.0 0.16
2-Butanone (f'EK) 8260 lA0120 01-20-05 01-20-05 ss 10 < ug/1 1 10 1.3
1,1,1-Trlchloroethane 8260 1A0120 01-10-05 01-20-05 ss 1.0 < ug/1 1 1.0 o. 31
Carbon tetrachloride 8260 1A0110 01-20-05 01-20-os ss 1.0 < ug/1 1 1.0 0.31
Bromodi ch 1 o rooiethane 8160 1A0120 01-20-05 01-20-05 5S 1.0 < ug/1 1 1.0 0.14
1,1,2,2-Tetrachloroethane 8160 1A0120 01-20-05 01-20-05 ss 1.0 < ug/1 1 1.0 0.18
1,2-Dichloropropane 8160 1A0120 01-20-05 01-20-0s 5S 1-0 < ug/1 l 1-0 0.33
tr ans-1, 3-0i ch 1 oropropene 8260 1A0120 01-20-05 01-20-os ss 1.0 < ug/1 1 1.0 0.16
Trichloroethene 8260 JA0120 01-20-05 01-20-05 ss 1.0 < ug/1 l 1.0 0.37
Dibrornochloranethane 8260 JA0120 01-20-05 01-20-05 5S 1.0 < ug/1 1 1.0 a.so
1, 1, 2-Trich lo roe thane 8260 1A0120 01-20-01 01-20-05 ss 1.0 < ug/1 1 1.0 0.22
Benzene 8260 1A0120 01-10-05 01-20-05 5S 1.0 < ug/1 1 1.0 0.36
cis-1,3-Dichloropropene 8260 1A0120 01-10-05 01-20-05 S5 1.0 < ug/1 1 1.0 0.23
Braooform 8260 1A0120 01-10-05 01-20-05 ss 1.0 < ug/1 l 1-0 0.33
2-Hexanone 8260 1A0120 01-20-05 01-20-05 ss 10 < ug/1 1 10 0.93
4-Methyl-2-pentanone (MIBK) 8260 JA0120 01-20-05 01-20-os ss 10 < ug/1 1 10 0.65
Tetrachloroethvle 8260 JA0120 01-20-05 01-20-05 S5 1.0 < ug/1 1 10 0.35
Toluene 8260 1A0120 01-20-05 01-20-05 ss LO < ug/1 1 10 0.54
0, lorobenzene 8260 JA0120 01-20-05 01-10-05 5S 1.0 < ug/1 1 1.0 o. 34
Ethyl benzene 8160 1A0120 01-20-05 01-20-05 ss 1.0 < ug/1 1 1.0 o.34
Styrene 8260 1A0120 01-20-05 01-20-05 5S 1.0 < ug/1 1 LO 0.25
Xylenes, Total 8260 JA0120 01-20-os 01-10-05 ss 2 .o < ug/1 1 2.0 1 3
S1wr09ate -To1u~ne-d8 &260 JAOl/0 01-20-05 01-20-05 55 9G ·" 1
Surrog,,te · • ,1-8rm.l:)f1uoro/Jen.::ene ' 8260 1A0120 01-20-05 01-20-05 55 ss -· ·"
Page 4 of 9
•
•
Client
Work Order ID
Laboratory ID
Sample ID
Matrix
Percent Sol.ids
Parameter
Su, rngate -
Dibromof1uoronieth<1ne "
iiiii:i§i
iii;i@§iii STL
ENSR Consulting
Channel Master
S540488*2
Trip Blank
LI
&: Engineering
Sampled ; Ol-1B-2005
Received: Ol-19-2005
RESULTS SUMMARY REPORT
STL Savannah
Method Batch Prep
Date_
Analysis Analyst Result
Date
Qual lklits DF Rt
6260 JA0120 01-20-0S 01-20-05 55
Page 5 of 9
10·1 •· , . 1
!Ill
•
lll!llrl■ STL lilill~III
Client ENSR Consulting
STL Savannah
& Engineering
Work Order ID Channel Master
Laboratory ID SS404BB•3
Sample ID Method Blank
Matrix LI Sampled ' Percent Solids Received:
RESULTS SUMMARY REPORT
Parameter Method Batch Prep Analysis Ana I yst Resu It Qual Units OF RL lllL
Date Date
Chloromethane 8260 lADllO Ol-20-05 01-20-05 5S LO < ug/1 1
Brcmomethane (Methyl bromide) B260 lADllO 01-20-05 01-20-05 ss l.O < ug/1 l
Vinyl chloride 8260 lADllO Ol-20-0S 01-20-0S ss 1 .. 0 < ug/1 l
Oiloroethane 8260 lADllO 01-20-05 01-20-05 ss 1.0 < ug/1 l
Methylene chloride
(Dichlorocnethane) 8260 1A0120 01-20-0S 01-20-05 ss s.o < ug/1 l
Acetone 8260 1A0120 01-20-05 01-20-05 S5 25 < ug/1 l
Carbon disulfide 8260 1A0120 01-20-05 D1·20•05 ss 1.0 < ug/1 l
1,1-Dichloroethene 8260 1A0120 01-20-05 01-20-05 S5 LO < ug/1 l
1, 1-Di chlor oethane 8260 lADllO 01-20-05 01-20-05 55 1.0 < ug/1 l • ci s-1, 2-0ichloroethene 8260 lADllO 01-20-05 01-20-05 55 1.0 < ug/1 1
trans-1,2-0ichloroethene 8260 lADllO 01-20-05 01-20-05 ss 1.0 < ug/1 1
O,lorofonn 8260 lADllO 01-20-05 01-20-05 5S l.O < ug/1 1
1, 2-Di ch 1 oroethane 8260 1AD120 01-20-05 01-20-05 S5 1.0 < ug/1 1
2-Butanone (t,'{K_) 8260 lADllO 01-20-05 01-20-05 ss 10 < ug/1 1
1,1,1-Trichloroethane 8260 lADllO 01-20-05 01-20-05 ss 1.0 < ug/1 l
Carbon tetrachloride 8260 lADllO 01-20-05 01-20--05 S5 1.0 < ug/1 l
Branodichloromethane 8260 lAOllO 01-20-05 01-20-05 ss 1.0 < ug/1 1
l, l, 2,2-Tetrachloroetha.ne 8260 1A0120 01-20-05 01-20-05 ss 1.0 < ug/1 1
1,2-Dichloropropane 8260 lADllO 01-20-05 01-20-05 ss 1.0 < ug/1 1
trans-1,3-Dichloropropene 6260 lADllO 01-20-05 01-20-05 5S 1.0 < ug/1 1
Trichloroethene 8260 lADllO 01-20-05 01-20-05 ss 1.0 < ug/1 1
Dibrorochlon::rnethane 8260 IAOllO 01-20-05 01-20-05 ss 1.0 < ug/1 1
1,1,2-Trichloroethane 8260 lADllO 01-20-05 01-20-05 ss 1.0 < ug/1 1
Benzene 8260 1A0120 01-20-05 01-20-05 ss 1.0 < ug/1 1
cis-1,3-0ichloropropene 8260 lADllO 01-20-05 01-20-05 55 1.0 < ug/1 1
Brcmofonn 8260 1A0120 01-20-05 01-20-05 ss 1.0 < ug/1 l
2-Hexanone 8260 lADllO 01-20-05 01-20--05 5S 10 < ug/1 1
4-Methyl-2-pentanone CMmKJ 8260 1A0120 01-20-05 01-20-05 ss 10 < ug/1 1
Tetrachloroethene 8260 lADllO 01-20-05 01-20--05 ss 1.0 < ug/1 1
Toluene 8260 lADllO 01-20-05 01-20-05 ss 1.0 < ug/1 1
O,lorobenzene 8260 lADllO 01-20-05 01-20-05 ss 1.0 < ug/1 1
Ethyl benzene 8260 IAOllO 01-20-05 01-20-05 ss 1.0 < ug/1 1
Styrene 8260 IA0120 Ol-20-05 01-20-05 ss 1.0 < ug/1 1
Xylenes, Total 8260 lADllO 01-20-05 01-20-05 ss 2.0 < ug/1 1
Stwrog,1tc -To1uenc-r!S ·· 6260 1A01Z0 01-20-05 0l-W-05 55 96 ..
Sur rogare -
,1-nro111of1uorobenume S260 JA0ll0 01·Z0·05 01-20-05 55 92 •
Page 6 of 9
•
•
Client
Work Order ID
Laboratory ID
Sample ID
Matrix
Percent Solids
Parmeter
Surrog,,re -
Dibron,of1uarometh,1m2
Cyanide
ENSR Consulting
Channel .Master
S540488*3
Method Blank
LI
& Engineering
Sampled :
Received:
RESULTS SUMMARY REPORT
Method Batch Prep Analysis Analyst Result
Date Date
S260 JAOJW Dl-Z0-05 01-Z0-05 55 106
335.2 0120S 01-20-05 01-21-05 LR o.ooso
Page 7 of 9
iii'ii;♦§i
hi@i§iii STL
STL Savannah
~I Units DF RL "'L
:i; .1
< mg/1 1 0.010 0.0050
•
•
•
Client
Work Order ID
Laboratory ID
Sample ID
Matrix
Percent Solids
Paraneter
1, 1-Dichloroethene
Trichloroethene
Benzene
Toluene
a, lorobenzene
Surrogate -Toluene-dB "'
Surrogate -
4-Bromofluorobenzene "'
Surrogate -
Dibrooof1uoromethane "'
Cyanide
ENSR Consulting & Engineering
Channel Master
S540488*5
1 Lab Control Standard Result
LI Sampled :
Method BaU:h
8260 lAOl20
8260 1A0120
8260 lAOl20
8260 lAOl20
8260 lAOl20
8260 lAOl20
8260 lAOl20
8260 lAOl20
335.2 0120S
Received:
LCS RESULTS SUMMARY REPORT
SpH<e
Result
54
51
48
53
50
52
53
50
0.0308
Expected
Value
50
50
50
50
50
50
50
50
0.0300
Page 8 of 9
Units
ug/7
ug/7
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
mg/1
iiU#l;i§i
iUiitii§iii STL
Spike%
Recovery
108
102
96
106
100
104
106
100
103
STL savannah
Accuracy
Limit
41-158
70-123
69-128
71-129
72-126
74-122
70-119
68-129
85-115
•
liDlil~I STL N~m~m■
STL Savannah
Client ENSR Consulting &. Engineering
Work Order ID channel Master
Laboratory ID S540488*7
Sample ID Matrix Spike Result (Batch)
Matrix LI Sampled :
Percent Solids Received:
MS/MSD RESULTS Smn4ARY REPORT
Parameter Method Batch Parent Spike Expected Units Spike% Spike% Accuracy Precision
Result Result Value Recovery RPO Limit Limit
1,1-0ichloroethene 8260 lAOI20 48 so ug/1 96 9.9 Sl-1« 30
8260 lAOI20 Sl 50 ug/1 106
Trichloroethene 8260 JA0120 so 50 ug/1 100 2.0 70-I2l 30
8260 lAOI20 51 50 ug/1 102
Benzene 8260 lAOI20 46 50 ug/1 92 . 4.2 69-I28 30
8260 lAOI20 48 50 ug/1 96
Toluene 8260 JAOI20 so so ug/1 100 2.0 71-I29 30
8260 lAOI20 51 so ug/1 102
0, 1 orobenzene 8260 lA0120 49 50 ug/1 98 2.0 n-I26 30
8260 lAOI20 so so ug/1 100 • Surrogate -Toluene-dB "" 8260 lAOI20 47 so ug/1 94 74-122
8260 lAOI20 49 so ug/1 98
Surrogate -
4-Bror.ofluorobenzene • 8260 lAOI20 52 so ug/1 10◄ 70-ll9
8260 lAOI20 52 so ug/1 10◄
Surrogate -
Dibromofluoromethane • 8260 lAOI20 46 so ug/1 92 68-I29
8260 lAOI20 49 50 ug/1 98
Cyan1de 335.2 0120S 0.0327 0.0300 mg/1 109 8.6 85-llS 20
33S.2 0120S 0.0300 0.0300 mg/1 100
•
Page 9 of 9
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STL SAVANNAH-STL Log# S540488
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Data Qualifiers
Inorganic Data
ll1e reported result is an estimated concentration that is less than the PQL., but greater than or
equal to tl1e MDL ..
The reported value is an estimated because of the presence of matrix inte1ference.
The matrix spike recovery is not within control limits. See case nanative.
The result was determined by Method of Standard Addition (MSA).
The compound was analyzed for, but was not detected at or above the MDUPQL.
The compound was analyzed for, but was not detected at or above the PQL.
The post-digestion spike for furnace AA analysis was out of control limits, while sample
· absorbnnce was less than 50% of spike absorbance.
Duplicate analysis is not within control limits .
Organic Data
The analyte was found in the associated method blank.
The reported result is from a secondary dilution
Control limits a1e established only for surrogate concentration levels specified by EPA methods
Because the sample was diluted prior to analysis, surrogate recoveries·are not reportC:d.
The reported result exceeded the calibration range of the instrument.
The repmted result is an estimated concentration that is less than the PQL, but greater than or
equal to the MDL .
The GC or HPLC confirmation criteria was exceeded. The relative percent difference is greater
than 40% between the two GC columns or HPLC detectors
The compound was analyzed for, but was not detected at or above the MDUPQL.
The compound was analyzed for but was not detected at or above the PQL
Because surrogate recoveries were outside established limits the sample was re-extracted and/01
reanalyzed. Comparable results were obtained.
Because sunogate iecoveries were outside established limits, the sample was re-extracted and/or
reanalyzed. Both sets of data are provided
Surrogate recove1y was outside of established limits due to a coeluting matrix interference present
in the sample.
Internal standards recovered outside of advisory limits
Surrogate recovery was outside of advisory limits
Spike recovery was outside of advisory limits.
Universal
The 1ecovelies of the mab'ix spikes are outside advisory limits due to the abundance of the target
analyte in the sample
Elevated detection limits were reported due to sample matrix interference which required sample
or extract dilution.
Matrix spike 1ecoveries we1e outside advisory limits due to matrix interference present in the
sample
Insufficient sample volume was availoble to perfonn batch specific matrix spikes.
The analytical results for tl1e above roferenced STL Log# have been reported to the reporting limit (RL).
The test results in this report meet all NELAP requirements for parameters for which accreditation is
required or available. Any exceptions to NELAP requirements are noted in this report. Pursuant to NELAP,
this report may not be reproduced, except in full, without the written approval of the laboratory .
• • Serial Number 3 8 8 3 0
ANALYSIS REQUEST AND CHAIN OF CUSTODY RECORD ~ STL Savannah Website: www.stl-inc.com
Phone: [phone]
Fax: [phone]
PROJECT REFERENCE
TIM£
132!>
RELINQUISHED BY: ISIGNAnmEt
STL
PROJECT NO. PROJECT LOCATION
/0/4-o · 01:2 -S; (STAT£! /JC.
DATE
SAMPLE IDENTIFICATION
TIME
J'/:.1<>
CONTRACT NO.
TIME CUSTODY INTACT
YES 0
S /02,0 NO 0
MATRIX
lYPE
5102 LaRoche Avenue
Savannah, GA 31404
0 Alternate Laboratory Name/location
REQUIRED ANALYSIS
NUMBER OF CONTAINERS SUBMITTED
.1
, ··r·~-... ..:. :: ,.. . . ,i ~ .... q1. ~-
Phone:
Fax:
DATE TIME RELINQUISHED BY: ISlGNATUREI
01 '/¢,,s-I b-:h>
DATE .TIME RECEIVED BY: !SGNATUREI
LABORATORY USE ONLY
. CUSTODY STL SAVANNAH LABORATORY REMARKS
. SEAL ND, LOG NO.
scs oY B
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STANDARD REPORT k,(
DELIVERY ~
DATE DUE ____ _
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SR8240-680112/021