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HomeMy WebLinkAboutNCD122263825_19901001_JFD Electronics - Channel Master_FRBCERCLA RI_Work Plan for the Remedial Investion - Feasibility Study-OCRI I I I I I I I I I I I I I I I I I I Bechtel Oak Ridge Corporate Center 151 Lafayette Drive P.O. Box350 Oak Ridge, Tennessee 37831-0350 Facsimile: (615) 220-2100 Mr. Jack Butler Superfund Section North Carolina Division of SW Management Suite 150, 401 Oberlin Road Raleigh, NC 27605 August 29, 1991 SUBJECT: Contract Number 68-W9 0058, Bechtel Job No. 20385-003 ARCS IV Program, Channel Master Site PHASE I RI/FS WORK PLAN & FOP Subject Code: 0020 Dear Mr. Butler: Mr. McKenzie Mallary (USEPA, Region IV, RPM -Channel Master Site) requested me that I transmit the following documents to you: 1. Work Plan -Final (Phase I) 2. Field Operations Plan -Final (Phase I) Please call me at (615) 220-2375 if you have any questions. Enclosure: As stated Very truly yours, ~~ G. Ganapathi Project Manager cc: McKenzie Mallary, EPA Region IV (w/o) bee: A. Yazdi (w/o) Tl31 ~ Bechtel Environmental I I I I I I I I I I I I I I I I I I I ARCS IV CONTRACT NUMBER 68-W9-0058 WORK ASSIGNMENT NUMBER 03-41..31 IFJINAIL ________ WORK PLAN------- FOR THE Remedial Investigation/Feasibility Study at the JFD Electronics/Channel Master Site PREPARED FOR UNITED STA TES ENVIRONMENTAL PROTECTION AGENCY _________ BY ________ _ BECHTEL ENVIRONMENTAL, INC. October 1990 Cl005 I I I I I I I I I I I I I I I I I I I - WORX PLAN FOR Contract Number 6B-W9-0058 FINAL THE REMEDIAL INVESTIGATION/FEASIBILITY STUDY AT THE JFD ELECTRONICS/CHANNEL MASTER SITE PREPARED FOR THE U.S. ENVIRONMENTAL PROTECTION AGENCY BY BECHTEL ENVIRONMENTAL, INC. OCTOBER 1990 I I I I I I I I I I I I I I I I I I I - 1.0 1.1 1.2 1.3 INTRODUCTION ••••• overview ..... . RI/FS Objectives Project Organization CONTENTS • • • • 1 1 5 5 2.0 SITE BACKGROUND, PHYSICAL SETTING, AND EXISTING CONDITIONS 7 2.1 General Site Background 7 2 . 1 . 1 Lagoon • • • • • . • . • • • 7 2.1.2 voe contamination. • • • • • • • • 8 2.1.3 Sludge Drying Beds • • • • 11 2.1.4 Chronology of Channel Master Site 11 2.2 Physical Setting • • • • • • • • • 15 2.2.1 Regional Geology/Hydrogeology • 15 2.2.2 Site Geology/Hydrogeology 16 2.2.3 Meteorology. • • 16 2.2.4 Land Use • . • 18 2.3 Existing Condition 18 3.0 INITIAL EVALUATION. 3.1 Site Model . . . . . ...... . 3.1.1 Nature and Extent of Contamination 3.1.2 Migration Pathways ••••••.• 3.1.3 Exposure Pathways ••••••••••••• 3.2 Preliminary Health and Environmental Assessment 3.2.1 Identification of Chemicals of Concern 3.2.2 Exposure Assessment •••••••• 3.2.3 Toxicity Assessment •••••••• 3.2.4 Human Health Risk Characterization 22 22 22 27 31 34 34 34 36 39 40 3.2.5 Ecological Assessment ••••••• 3.3 Remedial Response ARARs and Preliminary Objectives • • • • • • • Remedial Response 40 4. 0 WORK PLAN RATIONALE • • • 4. 1 Scope of Remedial Action • • • • • • • • • • 4.2 Preliminary Assessment of Remedial Technologies. 4.2.1 No Action •••• 4.2.2 Soil ............. . 4.2.3 Water •............. 4.3 Treatability studies •••••••• 4.3.1 Summary of Waste Characteristics 4.3.2 Potential Treatability Studies ••• 4.4 Data Requirements/Data Quality Objectives 4.4.1 Characterization Data •••••••• 4.4.2 Geotechnical/Hydrogeologic Data 4.4.3 Feasibility Study Data 4.4.4 Health and Safety Data 4.4.5 Quality Assurance ••• i • • • • 41 41 41 42 42 46 48 49 49 49 50 51 51 51 52 I I I I I I I I I I I I I I I I I I I - CONTENTS (cont'd) 5.0 RI/FS TASKS ....•••.. 5.1 Task 1: Project Planning •• 5.2 Task 2: Community Relations 5.3 Task 3: Field Investigations • 5.3.1 Surveying and Mapping of the Site 5.3.2 Waste Characterization •••••• 5.3.3 Hydrogeologic Investigation ••• • 5.3.4 Soils Investigation. • • • • • • • • • 5.3.5 Surface Water and Sediment Investigation • 5.3.6 Air Investigation ••••••••• 5.4 Task 4: Sample Analysis and Validation 5.5 Task 5: Data Evaluation ••• 5.6 Task 6: Risk Assessment ••• 5.6.1 Contaminant Identification 5.6.2 Exposure Assessment ••• 5.6.3 Toxicity Assessment ••• 5.6.4 Risk Characterization •• 5.7 Task 7: Treatability Studies • • 5.8 Task 8: RI Report . . . . . . . . . .. • • • • • 5.9 Task 9: Remedial Alternatives Development and Screening 5.9.1 Establish Remedial Action Objectives and General Response Actions ........... . 5.9.2 Identify and Screen Technologies •••• 5.9.3 Configure and Screen Alternatives •••• 5.10 Task 10: Detailed Analysis of Alternatives 5.11 Task 11: FS Report 6.0 HEALTH AND SAFETY 7.0 SCHEDULE. REFERENCES • • • ii • • 53 53 53 53 60 60 61 62 62 65 65 66 67 67 67 68 68 69 70 70 71 71 72 72 72 74 75 76 I I I I I I I I I I I I I I I I I I I - Figure 1-1 1-2 1-3 1-4 2-1 2-2 2-3 2-4 2-5 2-6 3-1 5-1 5-2 5-3 5-4 5-5 No. LIST OP FIGURES Title Location of Channel Master Site PreClean-up Site Map Channel Master Existing Site Plan Project Organization Monitoring Wells Installed by Channel Master Soil Boring Locations at the Sludge Drying Area Total Volatile Organics Concentrations Isopleth Map Well construction Record for MW-5 Installed by Channel Master Blow-count Details for MW-5 Installed by Channel Master Channel Master Site Model Channel Master Site-Conceptual Model Channel Master Site Hydrocone Sample Locations for Preliminary Onsite Screening Channel Master Site Surface Water, Sediment and Offsite Hydrocone Sample Locations Channel Master Site Monitoring Well Locations Channel Master Borehole Locations Relationship of Screening Criteria to the Nine Evaluation Criteria iii 2 3 4 6 9 10 12 17 19 21 23 58 59 63 64 73 I I I I I I I I I I I I I I I I I I I Table No. 3-1 3-2 3-3 3-4 3-5 3-6 3-7 5-1 LIST OP TABLES Title Maximum Concentrations of Detectable Groundwater Contaminants Maximum Concentrations of Detectable Volatile Organic Compounds in the Soil and Waste Oil Tank Sediment Contamination Summary Summary of Analytical Results for Inorganic Contaminants from Composite Sludge Sample Maximum Concentrations of Detectable Inorganic Contaminants in Existing Sludge Drying Beds Media, Continuation Concerns and Potential Migration Pathway Preliminary Identification of Contaminants and contaminant-Specific ARARS for the Channel Master Site Sampling and Analysis Details iv 24 26 28 29 30 32 35 54 I I I I I I I I I I I I I I I ,I I ARAR ATSDR ACRONYMS applicable or relevant and appropriate requirements Agency for Toxic Substances and Disease Registry CEC cation exchange capacity CERCLA CFR CLP CRP DCA DCE DQO Comprehensive Environmentai Response Compensations and Liability Act of 1980 Code of Federal Regulations contract laboratory program Community Relations Plan dichloroethane dichloroethene data quality objective EP Extraction Procedure EPA ESB FFS HSP U.S. Environmental Protection Agency Engineering Support Branch of EPA Region IV focused feasibility study health and safety plan JFD JFD Electronics MCL Maximum Contaminant Level NCDHR -North Carolina Department of Human Resources - CERCLA CERCLA Unit NCP National Contingency Plan OSWER Office of Solid Wastes and Emergency Response PCE tetrachloroethene POTW QA publicly owned treatment works quality assurance V I I I I I I I I I I I I I I I I I I I - QA/QC QAPP QC RCRA RI RI/FS RPM SARA SHSP S&ME SOPQAM sow quality quality quality Resource remedial ACRONYMS (cont'd) assurance/quality control assurance project plan control Conservation and Recovery Act investigation remedial investigation/feasibility study remedial project manager (EPA) Superfund Amendments and Reauthorization Act site health and safety plan Soil and Materials Engineers Standard Operating Procedures Quality Assurance Manual statement of work TAT technical assistance team TCA trichloroethane TCE trichloroethene TCL TCLP TOC USGS voe Target Compound List Toxicity Characteristics Leaching Procedures total organic carbon United States Geological Survey volatile organic compound vi I I ABBREVIATIONS I ft feet I ft2 square feet gal gallon I in inches kg kilograms I L liter I mi miles ppb parts per billion I ppm parts per million RfD reference dose I yd yards I yd3 cubic. yards ug micrograms I I I I I I I I vii I I I I I I I I I I I I I I I I I I I I 1.0 INTRODUCTION The U.S. Environmental Protection Agency (EPA), Region IV, under Work Assignment No. 03-4L3L, has retained Bechtel Environmental Inc., (Bechtel) to perform a remedial investigation/feasibility study (RI/FS) at the JFD Electronics/Channel Master (Channel Master) site, Oxford, North Carolina. The purpose of this Work Plan is to define the scope of services, level of effort, costs, and schedule associated with performing the tasks required to complete the RI/FS for this site. The following is an overview of the scope of work, RI/FS objectives, and the project organization. 1.1 overview The Channel Master site is located on Industrial Drive, Oxford, North Carolina in central Granville Countr (Figure 1-1). The coordinates of the site are: latitude 36 17' 59 11 and longitude 78° 36' 23". Electroplating operations were conducted at the Channel Master site (shown in Figures 1-1 and 1-2) from 1968 to 1979 by JFD Electronics (JFD). These operations resulted in the generation of electroplating wastes, including metal-contaminated sludge and wastewater. A lagoon covering approximately 23,400 ft2 was used to dispose of the sludge. In 1980, Channel Master bought the site from JFD and started manufacturing indoor antennas and satellite dishes. Some organic solvents such as trichloroethane (TCA) were used onsite for cleaning. Volatile organic compounds (VOCs), which reportedly originated from a concrete waste oil tank and chemical storage area, were also released at the site during these operations. Based on the evaluations of a limited soil and groundwater investigation conducted by Channel Master, certain clean-up actions were conducted, including removal of sludge, sludge mixed with soil, and subsoil from the containment lagoon, and removal of two fuel oil tanks and one concrete waste oil tank from the south side of the main building (Figure 1-2). This cleanup was carried out by Channel Master in cooperation with the North Carolina Department of Human Resources, CERCLA Unit (NCDHR- CERCLA) during 1987 and 1988. Areas affected by these efforts are south of the main building. The lagoon area was excavated as shown in Figure 1-3, and the excavated material was disposed of at a permitted waste facility. voe-contaminated soil around the areas of the removed tanks was excavated and treated onsite. Prior to being treated through an onsite rotary dryer, these soils were stored in the pile areas identified on Figure 1-3. 1 I I I I I I I I I I I I I I I I I I .3.7/1406.1 SCALE 1:24 000 0 \\ QUADRANGLE LOCATION I ,,,,.-:-,.. ,-..... \ 1oooea::::s::Ea:o ===':;ooo:isea==ei23oooc::::==='oooE====•ooos:::::=:::::5000::E==eaei6000s::::::::=~7000. FEET FIGURE 1-1 CHANNEL MASTER SITE-LOCATION MAP 2 ·------------------- w 0 200 I' = 200' 20J8'j F JG29.0GN 400 600 RGROUNO V[NIS ERGROUNO fll[L 01 FIGURE 1-2 PRECLEAN-UP SITE MAP CHANNEL MASTER SITE ' SHALLOW DEPRESS!~ LOCATED ON f' AERIAL'PHOIO)-. '"', RAILROAD OITOl ~ Q SHALLOW NJNJTCIII~ WUS rm II Sl ll>C( PITS BACUILL[O PMT!c,t <J" LAGOON Sl.Rr &CE ORAINA(;t ·------------------- I I ';:!I 0 200 I' = 200' 20185-f IG28.DGN 400 600 UNDERGROUND I ANK VENTS FORMER run Oil TANK AREAS F I CURE 1 -3 CHANNEL MASTER EXISTING SITE PLAN ' SHALLOW DEPRESS!~ LOCATED ON f AERIAL PHOTO"""\. '"", -RllLROlD DITCH ~ 0 UISllNG IOflTOAJNG W.Ll Pill Of' VOC·C<JfTANJN.UED SOIL PRIil' JO lRCATtUH I I I I I I I I I I I I I I I I I I I These treated soils were then returned as fill material to the excavated areas. Site visits were conducted by representatives of The Agency for Toxic Substances and Disease Registry (ATSDR) in March 1989 and later by EPA in September 1989. Based on these inspections, both agencies concluded that residual contamination from Channel Master's clean-up efforts may remain at the site. 1.2 RI/FS Objectives The overall objectives of the Channel Master RI/FS are to: • Determine the nature and extent of contamination at the Channel Master site • Assess the environmental and public health risks associated with the contamination • Develop and evaluate potential remedial alternatives, consistent with the National Contingency Plan, that will effectively clean up and/or prevent further migration of the contamination found in the soil and groundwater so that any threat to public health and environment is reduced or eliminated 1.3 Project Organization The Bechtel project organization for the Channel Master RI/FS is shown in Figure 1-4. The organization provides for direct access by the EPA remedial project manager (RPM) to the Bechtel Project Manager,which ensures prompt response to questions and availability for guidance. Specific details of responsibilities are included in the quality assurance project plan (QAPP). 5 I I I I I I I I I I I I I I I I I I 120 1342.2 I EPA REMEDIAL PROJECT MAHAGER McKenzie Mallary ARCS IV PROGRAM MAHAGER QUALITY PROJECT MANAGER ASSURANCE ... ••• Dean Wolfe Gomes Gananathl ON-SITE H&S OFFICER ON-SITE GEOLOGIST Joe Duncan Steve Kautz Figure 1-4 PROJECT ORGANIZATION Phll Crotwell HEALTH & SAFID Merv Atwood RISK ASSESSMENT ICF I I I I I I I I I I I I I I I I I I I - 2.0 SITE BACKGROUND, PHYSICAL SETTING, AND EXISTING CONDITIONS 2.1 General Site Background The Channel Master site was vacant prior to being purchased by JFD Electronics. JFD Electronics, which became a subsidiary of Unimax Corporation in 1968, manufactured and electroplated television antennas until 1979. Sludge generated from the chromate conversion and electroplating processes rinse waters was collected in an onsite lagoon. The site was leased in 1979 by Ventura Electronics Corporation, who continued manufacturing television antennas but sent them offsite to be electroplated. Plastic bases for the antennas were also produced using an injection molding process. The chrome conversion process may still have been operating at this time. In 1980, Ventura Electronics Corporation (later named as Channel Master Satellite systems, Inc. and known as Channel Master, a division of Avnet, Inc.) bought the site from JFD Electronics. In 1986, Channel Master began to manufacture satellite receiver dishes and systems using a resin transfer molding process. Solvents, including methylene chloride and 1,1,l-TCA were purchased and used by Channel Master for cleaning purposes. In 1984, Channel Master transferred all of its manufacturing operations from the site to Smithfield, North Carolina. The two buildings onsite are presently being leased by Channel Master (Figure 1-3). A portion of the main building (approximately 100 ft by 800 ft) has been leased by Time Electronics since 1987, for the distribution of electronic components. The other building (approximately 180 ft by 323 ft) on a 3.94-acre portion of the site has been leased by Bandag, Inc., since 1975 as a storage facility. 2.1.1 Lagoon The lagoon was originally 240 ft long and 75 ft wide at the east end and 120 ft wide at the west end, with the sides sloping to a 12-ft depth at its center. Based on the NCDHR site visit report, the lagoon was unlined and held between 800,000 and 1,000,000 gal. of sludge prior to being excavated (Ref. 1). JFD Electronics operated a chromate conversion process and copper/nickel electroplating process onsite from 1968 through 1979. The rinse water from these processes was gravity fed through two lines running from the main building to a series of concrete treatment tanks located adjacent to the lagoon. These treatment tanks were used for reducing hexavalent chromium to trivalent chromium. The treated rinse water was then pumped into the lagoon and allowed to settle. The supernatant was decanted from the surface of the lagoon through a pipe located on its east end and discharged to the city sewer system (Ref. 2). Electroplating operations ceased in 1979 when the site was 7 I I I I I I I I I I I I I I I I I I I subleased to Ventura Electronics Corp., although it is not certain when the chromate conversion operations ceased. Channel Master manufactured satellite receiver dishes and systems using a different process from those employed previously at the facility. In the summer of 1983, permission was granted by the City of Oxford to decant wastewater from the sludge lagoon and discharge it into the sanitary sewer system. The west half of the lagoon was then backfilled by Channel Master and used as a truck parking area. A permit was issued in 1985 by NCDHR to dispose of the lagoon sludge by land application. This permit was withdrawn, also in 1985, before any land application of the sludge occurred. Therefore, Channel Master contracted Soil and Material Engineers (S&ME) to conduct a soil and groundwater investigation of the site in 1986 (Ref. 3). Based on the results of this Phase I Groundwater Evaluation showing heavy metal contamination in the sludge lagoon, Channel Master submitted a draft clean-up plan to NCDHR-CERCLA and EPA, Region IV, in 1987 (Ref. 4). NCDHR approved the clean-up plan in 1987. Clean-up of the lagoon involved combining sludge in the unfilled portion of the lagoon with water in the old concrete treatment tanks, pumping the slurry through a filter, and collecting the filtrate material (Ref. 2). The city issued a temporary discharge permit (6/24/87 to 10/31/89) to allow this filtrate to be discharged to the city sewer system (Ref. 2). Excavation of the lagoon area involved hauling 17,000 yd3 of sludge, sludge mixed with soil, and subsoil to the GSX hazardous waste landfill in Pinewood South Carolina. The excavated lagoon area was regraded with clean fill materials. No post-removal sampling of the areas surrounding the lagoon has been conducted to date. 2.1.2 voe contlllllination voe contamination was discovered at the Channel Master site based on sampling results of 11 temporary wells installed by Channel Master between June and August 1986 and 5 permanent wells installed during 1985-1986 (Figure 2-1). Based on an isopleth map showing concentration levels of sampling results, the contamination plume extends from the scrap metal trailer parking area and in-ground concrete waste oil tank, toward the lagoon, as shown in Figure 2-2 (Ref. 5). An in-depth soil study was conducted by S&ME in September 1986 to better define the areas of contamination. Based on the results of an organic vapor site survey, soil samples were collected from the scrap metal parking area, concrete waste oil tank area, chemical storage area, and in a ditch beneath an eight inch 8 1------------------ 1 I I I I I I I I I I I I I I I ., :,. '" ,_, D Cl >, ... ., "' ::, "O C .... Main Building Railroad ::; '-· '.) 4 0 N LEGEND: • Permanent Monitor Well ■ Temporary Shallow Monitor Well 4 Temporary Deep Monitor Well SOURCE:Soil&Materia/Engineers,lnc.,Nov.1986 Q Proposed Additional Well • .,____ ____________ _ PROJECT I - Channel Master Oxford, N.C. FIGURE 2-1 Monitoring Wells Installed by Channel Master I - ,_. 0 -- - - - ~: -coooc:r .. t••TIOOIII .. 9'1\ - - -- - - - t N ~ - -- - - •• ., .... If ~ . ..----~--.,,,.,. . -------. ---~ .....__ ,._.,..~ /' ;.------------ Source: Son & M■tertal EnglnNra, Inc., Nov 1988 FIGURE2-2 Total Volatile Organics · Concentration Isopleth - I I I I I I I I I I I I I I I I I I I - discharge pipe. Results from this sampling showed the primary area of contamination to be the scrap metal trailer parking area and waste oil tank area. A second area of contamination immediately downgradient of the concrete chemical pad (Figure 1- 2) was also noted (Ref. 5). According to the site inspection report by NCDHR including interviews with Channel Master personnel, equipment drippings, equipment washdown, overflow of the waste oil storage tank, and other small losses may have contributed to volatile organic contamination in the scrap metal trailer parking area (Ref. 1). A cleanup plan for the Channel Master site developed by S&ME in July 1987 estimated the volume of the contaminated soil to be 100 ft by 120 ft by 3.5 ft. During June/July 1988, Channel Master removed two No. 2 fuel oil underground tanks and the in- ground concrete waste oil tank (Ref. 6). These tanks were disposed of at the GSX landfill in Pinewood, South Carolina. Approximately 2,000 yd3 of voe-contaminated soil was also excavated south of the main building. The excavated soil was stockpiled (Figure 1-3) prior to being run through a rotary dryer to drive off the volatiles. Chemical analysis of the cleaned soil showed greatly reduced voe contamination. In November 1988, after receiving information from ATSDR through NeDHR, this soil was used to backfill the excavated areas south of the main building (Ref. 7). 2.1.3 Sludge Drying Beds Eleven rectangular areas were identified south of the Bandag Warehouse in a 1965 aerial photograph of the Channel Master site (Figure 1-2). Some of the former JFD employees have stated that several sludge drying beds were located in this area of the site (Ref. 8). Westinghouse Environmental Services (formerly S&ME) collected five soil samples in this area in October 1988 (Figure 2-3). Four of the five samples were collected in the former sludge drying bed area and a fifth sample was collected in a shallow depression beneath the present Bandag Warehouse that had been identified in the 1965 aerial photo. A moist blue/green sludge was discovered in all of the samples collected in the former sludge drying area (Ref. 9). Analyses of these samples indicated the presence of chromium, copper, nickel and cyanide (Ref. 8). 2.1.4 Chronology of Channel Master Site Prior to 1961 1961-1979 Site vacant. Site operated by JFD Electronics and the Unimax Corporation for the manufacture of television antennas. Activities included electroplating and aluminum/chrome conversion. 11 I ..... "' - PCPLANAJIQN: - - • SOil IOAING LOCATIONS - - ----- -- --- --- -·· ,.,----...... ,.--'\ ( ----·· ' t FOIIIMEft UGOOH t I SOIL BORING LOCATION MAP FIGURE 2-3 Soll Boring Locations at the Sludge Drying Area ......... SMALi.OU DP.PIIIIIOII WCATtD ON AHIAJ. -~--"' // \I ~ / ' / eNA•S ) 0VERl'\.0W / / ( ,_ ....... ... ..... 0 !IO 100 100 SCALE SOURCE: Westtnghouse, Aug.1988 - I I I Oct. 1979 - July 1980 I I Oct. 1979 - Spring 1980 I Fall 1980 I July 1980 I Spring 1981 I I Summer 1983 I 1983 I 1984 I I 1984-1985 I Fall 1985 I 1986-1987 I I I - Operations conducted by Channel Master included manufacture of indoor antennas, which were sent offsite for electroplating. Some solvents, such as trichlorethylene (TCE) were used onsite for cleaning. An injection molding process generated waste plastic, which was sent to the municipal landfill. Channel Master used up inventory left over by JFD by continuing the manufacture of outdoor antennas. All manufacturing processes generating electroplating and aluminum/chrome conversion wastes discontinued. Site purchased by Channel Master from JFD. Channel Master began production of satellite receiver dishes and systems. Approximately 85 drums of solvents were purchased for cleaning purposes, including methylene chloride and 1,1,1-TCA. After receiving permission from the City of Oxford, Channel Master decanted wastewater from the sludge lagoon and discharged this wastewater into the municipal sanitary sewer system. Half of the sludge lagoon was backfilled for use as a truck parking area. All manufacturing operations were discontinued at the site and transferred to Smithfield, North Carolina. Channel Master requested permit from the State of North Carolina to dispose of lagoon sludge at an offsite disposal facility. Permit granted, then withdrawn in April 1985. Channel Master conducted initial soil and groundwater investigations at the site. Site leased to Roses Department Store. 13 I I I I I I I I I I I I I I I I I I I Fall 1986 Jan. 1987 May 1987 June 1987 Dec. 1987 May 1988 June 24,1988 July 1988 July 1988 - Nov. 1988 June 21, 1988 Sept. 25, 1989 Sept. 25, 1989 Nov. 14, 1989 Phase I soil and groundwater evaluation reports issued by S&ME/Westinghouse Environmental Services. Channel Master submitted draft cleanup plan to the NCDHR-CERCLA and to EPA, Region IV. NCDHR-CERCLA completed site inspection report. State approved Channel Master's subject to minor modification. cleanup activities took place. Site leased to Time Electronics. cleanup plan, Lagoon area Site leased to Hamilton/Avnet Electronics. Site proposed for placement on National Priorities List. Westinghouse Environmental Services completed hand auger borings in the scrap metal trailer parking area and the outfall of the discharge line at the drainage ditch. Excavation, treatment, and replacement of voe-contaminated soil in area adjacent to main building. ATSDR indicated in a letter to NCDHR-CERCLA that no further cleanup of the sludge lagoon was necessary to protect public health. EPA issued work assignment to Bechtel to perform RI/FS. EPA issued work assignment to Bechtel to perform RI/FS. EPA performed a removal program inspection of Channel Master site. EPA's Technical Assistance Team (TAT) contractor collected one composite soil sample from around the inground concrete tanks and one composite water sample from the tanks at the Channel Master site. Preliminary analytic results of soil samples revealed 42.9 ppm total chromium, 12.1 ppm hexavalent-chromium, 145 ppm arsenic and 21.1 ppm lead. 14 I I I I I I I I I I I I I I I I I I I - 2.2 Physical Setting 2.2.1 Regional Geology/Bydrogeology The Channel Master site is located near the city of Oxford, in Granville County, North Carolina, which lies within the Piedmont physiographic province. Formations underlying the Piedmont mountains (Piedmont) consist of soil, saprolite and bedrock. Saprolite (or residuum) is the weathered rock underlying the land surface. The saprolite in this region forms a layer from l to 100 ft thick. The regional bedrock which weathered to produce the saprolite is mainly metavolcanic and granodioritic rocks (Ref. 10). The metavolcanic sequence is composed primarily of slightly metamorphosed rocks of volcanic origin, interspersed with some minor sedimentary beds. The volcanic rocks in this sequence include felsic and mafic tuffs, breccia, a few rhyolite flows and basalts. The tuffs predominate. The felsic to intermediate tuffs range in composition from fine-grained rocks composed of volcanic ash to lithic tuffs that contain fragments of feldspar and quartz set in a fine-grained matrix. Mafic tuffs are interbedded with the felsic tuffs at several places. The tuffaceous rocks have a well-developed cleavage at most places that strikes north to northeast. Massive basalt and rhyolite are also minor rock types in the sequence (Ref. 11). The interbedded sedimentary rocks include a few beds of conglomerate and at least one bed of quartzite (Ref. 10). In this central portion of Granville County, granodiorite rocks are exposed and surrounded by metavolcanic rocks or bordered by the younger sediments of Triassic age. These granodiorite rocks are gray to pinkish-gray crystalline rocks mainly composed of feldspars, quartz, and micas. Inclusion of rocks of the metavolcanic unit is common in the granodiorite, but the inclusions do not contain metamorphic minerals indicative of intense dynamic and thermal metamorphism. Around the edges of the bodies, rocks of the metavolcanic unit and granodiorite are interlayered (Ref. 11). Most of the water in these rocks is contained in secondary interstices that were formed after the rock was lithified. There is no evidence of confining layers in this region, indicating that there may be only one aquifer in this region. The aquifer of concern at the Channel Master site is known as the Carolina Slate Aquifer (Ref. 11). Groundwater in the Piedmont is recharged by precipitation on interstream areas. The precipitation infiltrates through the unsaturated zone to the water table, normally located within the saprolite zone. The groundwater moves laterally downward through the saprolite zone to seep out as springs on the hillsides and to 15 I I I I I I I I I I I I I I I I I I I recharge streams in adjacent valleys (Ref. 10). "Some of the water in the saprolite also moves downward into the bedrock and thereafter through the fractures to adjacent valleys"(Ref. 10). 2.2.2 Site Geology/Hydrogeology Knowledge of the geology of the Channel Master site is based on the MW-5, well construction record (Figure 2-4). This well was installed through the eastern abandoned portion of the sludge lagoon by S&ME in March 1986 (Ref. 3). This monitoring well was drilled to a depth of 58 ft into weathered granitic rock (Figure 2-4). The upper 20 ft of material was labeled as "fill". A hard orange-tan silt with dark brown laminations was identified as saprolite from 20 to 28 ft. Coarse sand with lenses of metamorphosed granite was also identified as saprolite from 28 to 58 ft. No bedrock was identified within this 58 ft boring. The test boring record showing blow counts is shown in Figure 2-5. Site surface drainage is to a ditch along the southwestern edge of the property (Ref. 12). Water flows about 1,300 ft in the ditch to the east of an unnamed, intermittent stream, which is about 0.5 mi from an unnamed tributary. The unnamed tributary flows about 2.25 mi to Fishing Creek. Fishing Creek flows to the Tar River and is used for recreational fishing (Ref. 12). Groundwater flow at the site remains to be confirmed. Channel Master conducted a minimal onsite groundwater study by installing a series of temporary wells. Water levels from these temporary wells and five permanent wells (one upgradient and four in close proximity to the lagoon) installed by Channel Master indicated groundwater flowing in a south/southeasterly direction (Ref. 3). All of these monitoring wells, except the upstream well (CM-1), were destroyed during the site clean-up. 2.2.3 Meteorology Oxford, North Carolina lies within the northeastern section of the Piedmont Mountains. The climate is relatively moderate with mild winters and hot, humid summers in this region. Seasonal temperatures average between 42 to 44°F in January and 78 to 8cl°F in July. Yearly rainfall across this region of the Piedmont averages between 44 to 48 in. (Ref. 13). The greatest amount of precipitation occurs in the summer months, with the least amount occurring in the fall (Ref. 13). In the winter, snowfall averages between 6 to 8 in. per year (Ref. 13). The average wind speed throughout the Piedmont is 9 mi. per hour. Winds blow most frequently from a south/southwesterly direction. Seasonally, the winter months show the greatest wind speeds due to the greater temperature contrasts. Summer months have the lowest wind speeds (Ref. 13) . 16 I NORTH ~ DEPAATIEHT OF N4 'IUW. AESQ.l'ICES ANO C()O,N.MTY DEVB.0P'E><T 0M$K)H OF E'HYIAOf,A,,ENT AL ..,...,. aE>-ENT -QAOI.N)WATel SECTION FOR OFFICE USE ONL y P.O. BOX 27887 -AAl.BQf-f,,H.C. 27111. PHONE (818) 7~150a3 ' 0 I ' Ouad. No, " ·J ., Lat. Minor Basin _______ Serial No. ___ _ _______ Long. ____ Pc __ WELL CONSTRUCTION RECORD MW-5 Basin Code I DRILLING CONTRACTOR ___ s_&_ME __ D_r_i_l_li_n_g_C_o_m_p_a_n_y __ RILLER REGISTRATION NUMBER __ _,_#4:,..1:..:2~----- i WELL LOCATION: (Show sketch of lhe loca1ion below) Oxford Neares1 Town: -,,--,------,-------------- :I. " J. ... ,. -\.,, 'l l) ,: "' <.. I (Road. Communily, or Subdivision and Lot No.) OWNER __ C_h_a_n_n_e_l_Ma_s_t_e_r __ s_a_t_e_l_l_i_t_e_S_y_s_t_e_m_s_, _I_n_c_._ ADDRESS_~P_.~0~._B_o~x_14~16.,._.-~--,-,,------ I (Streer or Route N.l).) Smithfield N.c. 27577 City or Town Staie Zip Code DATE DRILLEfi/3/86-3/4/86 USE OF WELL Monitor I TOT AL DEPTH 58. 0' CUTTINGS COLLECTED ~ Yes O No . DOES WELL REPLACE EXISTING WELL? 0 Yes la No I STATIC WATER LEVEL:----FT. D aoo,e TOP OF CASING, D below TOP OF CASING IS 5' FT. ABOVE LAND SURFACE Yi~Lu {gom) ______ METHOD OF TEST ______ _ 1,·,aT:'R ZONES {oeoth): ----------------- ICl-!:.QRIN.~ TIOif C ~ 5:,,G• Tyoe ·-----Amouni Wat! Thickness Deoth D•ar:ieter or We1ght/F1. Material Header Ent. ------GW-1 Ent, __ _ STATE WELL CONSTRUCTION PERMIT NUMBER: ___________ _ Granville Coun1y; Depth DRILLING LOG From o.o 0.5 5.5 14.5 17.0 20.0 28,Q To o.5' 5.5' 14.5' 17.0' 20.0' 28.0' 56,Q' F orm~lion J)e~riotion Gray Silty ~andy ~ravel (Fill Orange-Brown Gravelly Slight] Sandy clayey SILT (Fill) Tan Brown Clayey Slightly Sa" STLT {Fill) Dark Gray-Green Very Wet Sligt Sandy Silty CLAY to Clayey Sil Orange-Brown Clayey Silty tbt to Very Cparse SAND (Fill) Hard Orange-Tan SILT with Dar Bro\.'n Lamination (Saproli:e) Verv Dense Da.r)<. Bro1.-n Sil:v Coarse to Very Coarse s;,::J ~i JPnses of Meramor2hosed G:ani H aooi1iona1 stRccks 6~0Jl;it::e~k O'. rc,~rn- I ,,om -1~--5~_ To 45.1 Ft.l.:.L-0. 71//ft. PVC Sch LOC~TIOfJ SKETCH fs~ow c1rec1ion and distance from a, least 1wc Srate Roa:s. or other m.;::, reference 0:>1n:sJ From ____ To ___ Fr. ___ _ I From ----To F't.---- GRQUT Oeolh Ma1er1a1 Memoc I r'rom 0.0 To 39.5 Fr !.!I Portland Tremmie rrom 39 5 To 42 B Fr. 1,,.11 Bentoni te Pellets lsc~;c::r,. Oeolh Q,.;~e,er S101 S,ze t.1Jtcriat : rorn t, 5. l To 55. I Ft 2.0 ,r. 0. 0l0 ,n PVC Sch I .-,JM ____ To ___ Ft =rom ____ To ___ Fr. ____ on ___ on. IGR~ ... El PACK =furn 42.8 Oeo1h IO 54. 0 Ft Sizt: Sand t.1a1e,1ar Quartz W-4 40 SOURCE: Soil & Material Engineers, Inc., Nov. 1986 I t:orn ____ To ___ Ft R:":!:.,:.f,~S -----------------·-·-----------.------------------- I 17 - FIGURE 2-4 Well Construction Record for MW-5 Installed by Channel Master I I I I I I I I I I I I I I I I I ] J 2,2,4 Land Use Land use within a 1-mi radius of the Channel Master site is as follows: the City of Oxford, which is residential, lies approximately 0.6 mi east/northeast of the site. There is also a sparsely populated area located 0.5 mi southeast of the site. West/northwest of the site are assumed to be recreational areas including the Thorndale Country Club (0.5 mi northwest of the site). Lake Devin is located 0.5 mi west of the site. An agricultural experiment station is located at about 0.3 mi northwest of the site. Immediately southwest of the site, within 0.25 mi, is an industrial park area. 2,2,5 Population and Water Supply The population of the City of Oxford is 6,978 which is the most populated area near the site (Ref, 10). Residents of Oxford draw municipal water from Kerr Lake, which is approximately 10 mi northeast of the city. Lake Devin, about 0.7 mi west of the site, is the emergency water source for the city (Ref. 1). Both of these surface water sources are upgradient. The Channel Master site, other facilities in the industrial park, and residences in the area are also served by municipal water. Wells supplying potable water are reportedly situated in a single continuous aquifer system. "A house count on the USGS map of the area within 3 mi of the Channel Master site excluding areas served by the City of Oxford, reveals 656 houses. Assuming 3.8 residents per house yields 2,493 residents utilizing groundwater" (Ref. 1). Groundwater usage in the vicinity of the site needs to be verified. 2,3 Existing Condition Channel Master's remediation efforts to date have included excavation/removal of the former sludge lagoon and excavation/treatment of voe-contaminated soils associated with leaking tanks. Records do not indicate that Channel Master resampled the areas south of the main building after remediation efforts were completed, Contamination remaining onsite is associated with contaminants that have migrated from the Channel Master remediated areas or from the former sludge drying area, Contaminants detected in a composite sample collected from the lagoon before the clean-up was performed included hexavalent and trivalent chromium (99,000 ppm total chromium), lead (320 ppm), arsenic (52 ppm), selenium (13 ppm), and cyanide (31.9 ppm) (Ref. 2). Soil sampling from the lagoon area showed the presence of 1,2-dichloroethane (DCA). Tetrachloroethane and TCE were detected in the sludge. voe contaminants detected in the soil outside of the lagoon included toluene, xylene, TCE, tetrachloroethene (PCE), and trans-1,2-dichloroethene (DCE) (Ref. 2). The primary area of voe contamination has been 18 I DEPTH FT. DESCRIPTION . _ ·, ~ 4 l' ELEV. ePEt£TRATION-BLONS PER FT. I 0.0 0.5 Orange-Brown Gravelly Slightly Sandy Clayey SILT (Fill) I 5.5 Tan-Brown Plastic Clayey Slightly Sandy SILT (Fill) (ML) I 14.5 I 17.0 20.0 Uark (;ray-Green very wet :,ugnuy -Sane r,11 -• "IV ~ f'l ,.,."'T' ,,..,:11\ ~--,, Orange-Brown Clayey Silty Coarse to Verv Coarse SAND <Fi 11) -(SM) I Hard Orange-Tan SILT with Dark Brown Lamination (Saproli te) I 28.0 Very Dense Dark Brown Silty Coarse I I I I I I I I I to Very Coarse SAND with Lenses of Metamorphosed Granitic Rock (Saproli te 58.0 Boring Terminated at 58.0 feet in SAND with Lenses of Metacorphosed Granitic Rock (Saprolite) BORING ANO SAl.<PL/NG MEETS ASTM 0·1586 CORE DRILLING '-<EETS AST'-< 0-2113 } I I PENETRATION IS THE NLMBC1 OF BLCM"S OF 140 LB HAl.<MER FALLING 30 IN. REQUIRED TO ORIVE 14 IN. I 0. SAl.<PLER I FT. I -L.NOISTURBEO SAMPLE !xi 0/o ROCK CORE REcoYE RY ◄ LOSS OF OR/LL/NG Wl>TER -=-WATE.R TAEl..E-24HR_ --=--WATER TABi..E·IHR. 19 :5 /..J, 0 IO 20 30 40 60 80 100 • 3 4 I 9 - 4 -8 SOURCE: Soil l Material Engineefl, Inc .. Nov. 1966 > 100 78 100+ 100 JOO+ FIGURE 2•5 Blow-Count details for MW-5 Installed by Channel Master I I I I I I I I I I I I I I I I I I I - TABLE 3-1 MAXIMUM CONCENTRATIONS OF DETECTABLE GROUNDWATER CONTAMINANTS CONTAMINANT Metals1 Chromium Nickel Copper Volatile organics Tetrachloroethene2 Toluene1 Trichlorethene2 Ref. 3 Ref. 12 CONCENTRATION 0.08 mg/1 0.28 mg/1 0.05 mg/1 39,000 ug/1 JO ug/1 190,000 ug/1 1 2 3 Maximum contaminant level ARARS 0.05 mg/L3 0.015 mg/L4 1.0 mg/L 0.88 ug/1 15,000 ug/1 2.8 ug/1 ' Water quality criteria adjusted for drinking water 24 I I I I I I I I I I I I I I I I I I I surface water No surface water sampling has been performed at the Channel Master site. The current RI will include an evaluation of on- and offsite contamination of surface water. The surface water investigation will include a determination of whether groundwater discharges to surface water occur and the locations of these interfaces. Locations of runoff discharges into surface water bodies will also be identified. Soils Soil samples were collected by Channel Master from the scrap trailer loading area and the waste oil tank area (Ref. 5). The samples were analyzed for priority pollutants and oil and grease. voes, primarily in the form of halogenated hydrocarbons, and oil and grease were found at significant concentrations. A summary of the maximum voe concentration levels found is provided in Table 3-2. Two base neutral extractables, bis(2-ethylexyl) phthalate and diethyl phthalate, were detected at concentrations of 1000 ug/kg and 1300 ug/kg, respectively (Ref. 5). Acid extractables, PCBs, and pesticides were not detected. Samples were not analyzed for metals. The primary areas of contamination were found to be the scrap metal trailer parking area and the waste oil tank drainage area, with contamination extending to a depth of 7 ft. A secondary area of voe contamination was found in the chemical pad area to a depth of 3 ft (Ref. 5). The subsequent groundwater evaluation, conducted by Channel Master, included the analysis of well boring soils from MW-5. Soil samples were collected from 19 to 50 ft. Only 1,2-dichloroethane was found at detectable concentrations (30 ug/kg) at a depth of 23.5 to 24.8 ft. Residual soil contamination may exist to the south of the main Channel Master building, including the lagoon area, the scrap metal trailer parking area, and the chemical pad area. Sediment Drainage ditch sediment samples were collected in July 1988, by Channel Master's contractor. The samples were collected from along the southwestern edge of the property and showed some voe contamination. The maximum values are given in Table 3-3. No samples were analyzed for inorganic contamination of sediments. 25 I I I I I I I I I I I I I I TABLE 3-2 MAXIMUM CONCENTRATIONS OF DETECTABLE VOLATILE ORGANIC COMPOUNDS IN THE SOIL AND WASTE OIL TANK CONTAMINANT Soils 1,1-dichloroethane 1,2-dichloroethane 1,1-dichloroethene trans-1,2-dichloroethene methylene chloride 1,1,1-trichloroethane trichloroethene xylene tetrachloroethene vinyl chloride acetone waste Oil Tank trichloroethene 1,1,1 trichloroethane CONCENTRATION 70 ug/kg 26 ug/kg 670 ug/kg 170 ug/kg 290 ug/kg 6,500 ug/kg 670 ug/kg 210 ug/kg 5,400 ug/kg 210 ug/kg 290 ug/kg 83,000 ug/kg 16,000 ug/kg I source: Ref. 3 I I I I - 26 I I I I I I I I I I I I I I I I I I I One offsite sample was taken downstream from the site in a drainage ditch at a depth near the water table. voe contamination was detected. Results are presented in Table 3-3. Sludge In 1986, sampling and analysis of the sludge and the lagoon area was conducted by Channel Master to determine the volume of material to be removed and the limits of remediation. Samples were collected from the soil above and below the sludge and a composite sample of the sludge was taken from the lagoon. Soil samples were analyzed for total chromium and the composite sample was analyzed for metals, EP toxicity metals and voes, and cyanide. No chromium contamination was found in the fill material or in the soil. Table 3-4 summarizes the inorganic contamination found in the composite sludge sample taken from the lagoon. Tetrachloroethene at a concentration of 13.4 ug/kg was the only voe detected (Ref. 3). The lagoon area underwent remediation in 1987. Existing concentrations of residual contamination are not known. An investigation of the sludge drying area discussed in Section 2.1.3 was performed by Channel Master in 1989. Samples were analyzed for metals, EP toxicity metals, and cyanide. A summary of the maximum concentrations found in these samples is presented in Table 3-5. Air No ambient air sampling data were available for evaluation. other Units During a site visit by the EPA RPM and Bechtel personnel (December 18, 1989), a concrete treatment tank near the lagoon was noted. 3.1.2 Migration Pathways Based on the existing information from the Channel Master site, a generalized site conceptual model depicting potential migration pathways for contamination transport was developed and is presented in Figure 3-1. Additionally, Table 3-6 identifies the Channel Master site media, possible contamination concerns, and potential migration pathways. Figure 3-1 and Table 3-6 will be revised as additional data become available during the course of the RI. 27 I I I I I I I I I I I I I I I I I I I TABLE 3-3 SEDIMENT CONTAMINATION SUMMARY (SEPTEMBER 1986) CONTAMINANT onsite: trans 1,2-dichloroethene tetrachloroethene trichloroethene Offsite: trans 1,2-dichloroethene tetrachloroethene trichloroethene · vinyl chloride Source: Ref. 12 28 MAXIMUM CONCENTRATION (mg/kg) 18 34 <5 110 5,400 670 210 I I I I I I I I I I I I I I I I I I I TABLE 3-4 SUMMARY OP ANALYTICAL RESULTS POR INORGANIC CONTAMINANTS PROM COMPOSITE SLUDGE SAMPLE PROM LAGOON AREAS (1986) CONTAMINANT CONCENTRATION1 Total Arsenic 52 mg/kg Total Barium 800 mg/kg Total Cadmium 20 mg/kg Total Chromium 99,000 mg/kg Total Lead 320 mg/kg Total Mercury < 0.02 mg/kg Total Selenium 13 mg/kg Total Silver < 2.5 mg/kg Cyanide (total) 31.9 mg/kg EP-TOX Arsenic < 0.005 mg/1 EP-TOX Barium < 0.2 mg/1 EP-TOX Cadmium < 0.01 mg/1 EP-TOX Chromium 0.05 mg/1 EP-TOX Lead < 0.005 mg/1 EP-TOX Mercury < 0.002 mg/1 EP-TOX Selenium 0.012 mg/1 EP-TOX Silver < 0.05 mg/1 1 Results for total metals are reported Sources: Ref. 1, Ref. 5, Ref. 3 29 EP-TOX MCLs 5.0 100.0 mg/1 mg/1 1.0 mg/1 5.0 mg/1 5.0 mg/1 0.2 mg/1 1.0 mg/1 5.0 mg/1 on a dry weight basis. I I I I I I I I I I I I I I I I I I I TABLE 3-5 MAXIMUM CONCENTRATIONS OF DETECTABLE INORGANIC CONTAMINANTS IN EXISTING SLUDGE DRYING BEDS (1989) CONTAMINANT ChromiWII Total (mg/kg) EP-TOX (mg/1) Copper Total (mg/kg) EP-TOX (mg/1) Nickel Total (mg/kg) EP-TOX (mg/1) Total cyanide (mg/kg) Free cyanide (mg/kg) Source: Ref. 8 30 CONCENTRATION 35,000 0.29 2,700 0.08 14,000 6.2 1,200 120 J J ] I I I I I I I I I I I I I I I I To accurately identify migration pathways and predict contamination fate and transport at the Channel Master site, additional data regarding the current state of the site are necessary. Post-remediation data are needed to identify and/or verify existing contamination source areas and to determine the exact nature of the existing contamination. Additionally, a detailed hydrogeologic investigation is required to verify groundwater flow direction (reported to be to the southeast), determine water table depth, and identify groundwater/surface water interfaces. Details regarding the chemical, geochemical, and hydrogeologic data requirements are provided in Section 4.4. 3.1.3 Exposure Pathways Figure 3-1 depicts the potential exposure pathways at the Channel Master site. Remediation efforts, conducted in 1987 by Channel Master, have reduced the potential for exposure of humans to the soil contaminants from the Channel Master site; however, the possible presence of residual contamination, and the presence of contaminated sludge drying areas and groundwater pose a potential threat of exposure. A preliminary evaluation of potential human exposure pathways was performed by ATSDR during their preliminary health assessment conducted in 1989. Inorganics Although the lagoon and the backfilled truck parking lot (west half of the original lagoon) were excavated and backfilled with uncontaminated soil, residual contamination may exist. Therefore, the potential for human exposure to inorganic toxicants through this medium will be evaluated. Groundwater data from monitoring wells did not indicate any significant contamination by inorganics, with the exception of chromium (0.08 mg/L) and nickel (0.28 mg/L), which exceeded the EPA drinking water standards of 0.05 mg/Land 0.015 mg/L respectively. There were no air, surface water, or sediment data available, therefore, no conclusions were drawn regarding human exposure to inorganics contamination from these media. Although sediment data for chromium were not found in the reviewed materials, potential for bioaccumulation in aquatic animals is not high. organics The majority of the voe contamination was reported near the vicinity of the in-ground concrete waste oil tank. The tank has been removed and the contaminated soils around the tank have been cleaned and/or excavated and backfilled with soil acceptable to NCDHR-CERCLA. Human exposure pathways relating to soil media 31 I I I I I I I I I I I I I I I I I I I TABLE 3-6 MEDIA, CONTAMINATION CONCERNS, AND POTENTIAL MIGRATION PATHWAY MEDitJM Groundwater Soil/dust PRIMARY CONTAMINATION CONCERN Chromium and voes voes, semi-volatiles, oil and grease voes Sludges Heavy metals, (Ba, Cd, Cr, Cu, Ni, Pb, Se), cyanide, arsenic Surface water Unknown and sediments Onsite . treatment tank Unknown 32 MIGRATION PATHWAY Natural movement of groundwater (flow direction believed to be to the southeast) Infiltration/ percolation to groundwater Transmission by surface water runoff Transmission by wind Volatilization into air Infiltration/ Percolation to soil and groundwater Storm water runoff Food chain bioaccumulation and transport through mobile organisms Spills or leaks from tank Volatilization of voes if present I I I I I I I I I I I I I I I I I I I - have been limited since the soils contaminated with voes were removed. No air sampling has been conducted for voes, however, with the bulk of the contaminated soil removed, voes are not expected to be a problem with respect to human exposure via inhalation. There were no surface water data regarding voes, therefore, human exposure pathways via surface water cannot be evaluated until the RI has been completed. Groundwater and sediments were found to be contaminated with voes as noted in Section 3.1.1. However, as noted above, these data are not current since they were.obtained before removal of voe- contaminated soils and may not represent present conditions. Assuming that concentrations of contaminants listed in Table 3-1 represent current conditions for onsite groundwater, the potential human exposure pathways for voes present in groundwater are ingestion, inhalation, and dermal contact/absorption from activities such as showering, cooking, washing, and eating. Remedial workers may also be exposed during site remediation of the groundwater. Currently, there do not appear to be any onsite human exposure pathways because municipal water is used at the Channel Master site and is available to residents in this area. Site groundwater flow is reported to be generally toward the southeast; however, groundwater flow direction at the site needs to be confirmed. The nearest private drinking water well, located 2,000 ft. southeast of the site, was sampled in 1987 and did not indicate contamination. Assuming that concentrations of contaminants listed in Table 3-3 represent current conditions for on-and offsite voe sediment contamination, the potential human pathways are inadvertent ingestion, pica and dermal contact. Onsite sediment contamination is not expected to be a problem since voe concentrations are low and the site is restricted. voes, as a class, do not bioaccumulate appreciably. Therefore, ingestion of fish is not expected to be a pathway of concern. Exposure Potential Because access to the Channel Master site is restricted by a fence, exposure to the general public is limited to migration paths that transport the contaminants offsite or to onsite personnel that come in direct contact with seepage or sludge. The treatment tank is fenced and is not accessible to workers or the public. 33 I I I I I I I I I I I I I I I I I I - 3,2 Preliminary Health and Environmental Assessment 3,2,1 Identification of Chemicals of Concern A list of chemicals that are suspected or known to be present at the Channel Master site is given in Table 3-7. This list is based on the pre-remediation data presented in the Phase I Groundwater Quality Evaluation (Ref. 3) and the Report on the Soil Quality (Ref. 5) as well as the results of the analyses of samples collected from the currently:existing sludge drying areas in 1989. The presence or absence of these chemicals and the concentrations of chemicals existing at the site will be determined during the course of the RI. Once this information is obtained, indicator chemicals will be selected, for the purposes of performing the health assessment, in accordance with the US EPA Superfund Public Health Evaluation Manual (Ref. 15). 3,2,2 Exposure Assessment Inorganics Chromium, cadmium, lead, barium, selenium, arsenic, cyanide, nickel, and copper were the inorganics detected at the Channel Master site. Past remediation efforts involving excavation of sludges and sludge/soils from the lagoon and lagoon vicinity should have limited human exposure pathways relating to soil media for these metals. surface water and sediment data for chromium were not available, however, bioaccumulation of chromium in aquatic animals with subsequent human ingestion is not expected to be a pathway· of concern. While the inorganics at this site probably do not pose a public health concern, post- remediation sampling of the lagoon soils, groundwater and the sludge drying area south of the warehouse will be conducted. organics voes in the onsite groundwater are of potential public health concern if the concentrations indicated in Table 3-1 are currently valid and use of the onsite groundwater occurs. Presently, onsite groundwater is not being utilized. The highest concentrations of voes were found in the groundwater near the in- ground concrete waste oil storage tank. Samples collected in 1987 from monitoring wells located near the site boundary showed some voe contamination, indicating the existence of a contamination plume which may be escaping offsite. These wells were destroyed during excavation of the lagoon area. The locations of these former wells are shown in Figure 2-1. Although the nearest offsite well did not show site-related contamination 34 I I I I I I I I I I I I I I I I I I _I TABLE 3-7 PRELIMINARY IDENTIFICATION OF CONTAMINANTS AND CONTAMINANT-SPECIFIC ARARS FOR.THE CHANNEL KASTER SITE IIAXIIUI EPA AIEIEIIT IDITAIIIIWIT 1111 TER IIIAI. I TT IDITAIIIIWIT LEVEL CRITERIA Of IDICERII 1111/L Soll 111;/q (1 > Jnorganic: Araenfc 50 0,002 Barii.n 1000 tactn;a.n 10 10 Chromhn 50 170,000 Lead 50 50 Seleniua 10 10 Cyanide 200 Nick.el 15,4 Copper 1,000 Organic: 1,1·dichloroethane (1,1·DCA) 1,2-dichloroethane 5 0.94 (1,2·DCA) 1,1•dichloroethene 7 0.033 (1,1·DC£) *trens-1,2-dichloroethene 100 (trans·1,2·DCEl *tetrachloroethene 5 0.88 (PCE) 1,1,1-trichloroethane 200 19.0 (1,1,1·TCA) *Trichloroethene 5 2,8 (TCE) •vinyl Chloride 2 2.0 *Xylene 10000 Methylene chloride Toluene 15,000 (1) Adjusted for drinking water • Ref. 3 35 I I I I I I I I I I I I I I I I I I I in 1987, offsite users of the groundwater may be affected in the future if the contamination plume continues to spread. Conclusions regarding the extent of voe migration offsite can only be drawn after additional sampling and analysis of groundwater and soils both on and offsite. voes in the offsite drainage ditch sediment and surface water may be of potential health concern to children playing in these areas. The exposure pathways (inadvertent ingestion and dermal contact) associated with this scenario are believed to be of less consequence with respect to voe toxicity than that of deliberate ingestion (pica) because of the frequency of occurrence and the mode of exposure. Although surface waters were not sampled, the groundwater is thought to have contaminated the offsite sediment and the surface water because of the high water table in some areas. It is not known how far the groundwater/surface water/sediment contamination extends downstream of the ditch. 3.2.3 Toxicity Assessment The toxicological characteristics of the inorganic and organic compounds which have been found at the Channel Master site are discussed below. Based on the existing information, it is not known whether contamination concentrations are present at levels which would manifest any of the toxicological effects described. • Inorganics Inorganic contaminants found at detectable concentrations at the Channel Master site include chromium, cadmium, lead, arsenic, barium, selenium, cyanide, nickel and copper. Chromic acid and its salts have a corrosive action on the skin and mucous membranes. The lesions are confined to the exposed parts, affecting chiefly the skin of the hands and forearms and the mucous membranes of the nasal septum. The characteristic lesion is a deep, penetrating ulcer, which, for the most part, does not tend to suppurate, and which is slow in healing. Small ulcers, about the size of a matchhead or end of a lead pencil may be found, chiefly around the base of the nails, on the knuckles, dorsum of the hands and forearms. These ulcers tend to be clean, and progress slowly. They are frequently painless, even though quite deep. They heal slowly and leave scars. On the mucous · membrane of the nasal septum the ulcers are usually accompanied by purulent discharge and crusting. If exposure continues, perforation of the nasal septum may result, but produces no deformity of the nose. Hexavalent compounds are said to be more toxic than the trivalent. Eczematous dermatitis due to trivalent chromium compounds has been reported. 36 I I I I I I I I I I I I I I I I I I I The inhalation of fumes or dusts of cadmium primarily affects the. respiratory tract; the kidneys may also be affected. Even brief exposure to high concentrations may result in pulmonary edema and death. Usually the edema is not massive, with little pleural effusion. In fatal cases, fatty degeneration of the liver and acute inflammatory changes in the kidneys have been noted. Ingestion of cadmium results in a gastrointestinal type of poisoning resembling food poisoning in its symptoms. Inhalation of dust or fumes may cause dryness of the throat, cough, headache, a sense of constriction in the chest, shortness of breath (dyspnea) and vomiting. More severe exposure results in marked lung changes, with persistent cough, pain in the chest, severe dyspnea and prostration which may terminate fatally. X- ray changes are usually similar to those seen in bronchi- pneumonia. The urine is frequently dark. These symptoms are usually delayed for some hours after exposure and a fatal concentration may be breathed without sufficient discomfort to warn the workman to leave the exposure. Ingestion of cadmium results-in sudden nausea, salivation, vomiting, diarrhea and abdominal pain and discomfort. Symptoms begin almost immediately after ingestion. A yellow discoloration of the teeth has been reported in exposed workers. The presence of lead compounds at the site will not result in eXJ?osure unless lead is in such form, and so distributed, as to gain access into the body or tissues in measurable quantity. Mode of entry into the body can be through inhalation of dusts, ingestion, or through the skin. Absorption through the skin is of special importance in the case of organic compounds of lead, which are absorbed rapidly through the skin and lungs and selectively absorbed by the central nervous system. In the case of inorganic forms of lead, this route is of no practical importance. When lead is ingested, much of it passes through the body unabsorbed and is eliminated in the feces. the greater portion of the lead that is absorbed is caught by the liver and excreted, in part, in the bile. For this reason, larger amounts of lead are necessary to cause poisoning if absorption is by this route and a longer period of exposure is usually necessary to produce symptoms. On the other hand, upon inhalation, absorption takes place easily from the respiratory tract and symptoms tend to develop more quickly. From the point of view of industrial poisoning, inhalation of lead is much more important than is ingestion. Lead is a cumulative poison. Increasing amounts build up in the body and eventually a point is reached where symptoms and disability occur. In mild cases of short duration, there may be symptoms of headache, dizziness and insomnia. Poisoning from arsenic compounds may be acute or chronic. Acute poisoning usually results from swallowing arsenic compounds; chronic poisoning from either swallowing or inhalation. Acute allergic reactions to arsenic compounds used in medical therapy have been fairly common; the type and severity of reaction 37 I I I I I I I I I I I I I I I I I I I depending upon the compound of arsenic. Inorganic arsenical are more toxic than organics. Trivalent is more toxic than pentavalent. Acute arsenic poisoning (from ingestion) results in marked irritation of the stomach and intestines with nausea, vomiting and diarrhea. In severe cases, the vomitus and stools are bloody and the patient goes into collapse and shock with weak, rapid pulse, cold sweats, coma and death. Chronic arsenic poisoning, whether through ingestion or inhalation, may manifest itself in many different ways. There may be disturbances of the digestive system such as loss of appetite, cramps, nausea, constipation or diarrhea. Liver damage may occur, resulting in jaundice. Disturbances of the blood, kidneys and nervous system are not infrequent. Arsenic can cause a variety of skin abnormalities including itching, pigmentation and cancerous changes. Barium, in the form of soluble barium salts, are poisonous if ingested. Symptoms of exposure include severe abdominal pain, vomiting, dyspnea, rapid pulse, paralysis of the arm and leg, and eventually cyanosis and death. Elemental Selenium has low acute systemic toxicity, but dust or fumes can cause serious irritation of the respiratory tract. Some organic selenium compounds have the high toxicity of other organic metal. Inorganic selenium compounds can cause dermatitis. Garlic odor of breath is a common symptom. Chronic exposure can produce symptoms such as pallor, nervousness, depression, and digestive disturbances. Cyanide and hydrocyanic acid are protoplasmic poisons. Exposure to concentrations of 100-200 ppm for periods of 30-60 minutes can cause death. In cases of acute cyanide poisoning, death is extremely rapid. In less acute cases, there is cyanosis, headache, dizziness, unsteadiness of gait, a feeling of suffocation, and nausea. Where the patient recovers, there is rarely any disability. Nickel and many of its compounds are poisons and carcinogens. Some are human carcinogens by inhalation. All airborne nickel contaminating dusts are regarded as carcinogenic by inhalation. Ingestion of large doses of nickel compounds (1-3 mg/kg) has been shown to cause intestinal disorders, convulsions, and asphyxia. Hypersensitivity to nickel is common and can cause allergic contact dermatitis, pulmonary asthma, conjunctivitis, and inflammatory reactions around nickel-containing medical implants and prostheses. The most common effect resulting from exposure to nickel compounds is the development of "nickel itch". It occurs primarily in persons doing nickel-plating and is most frequent under conditions of high temperature and humidity, when the skin is moist, and mainly affects the hands and arms. There is marked variation in individual susceptibility to the dermatitis. 38 I I I I I I I I I I I I I I I I I I I Copper chloride and sulfate have been reported as causing irritation of the skin and conjunctivae which may be on an allergic basis. cuprous oxide is irritating to the eyes and upper respiratory tract. Discoloration of the skin is often seen in persons handling copper, but this does not indicate any actual injury. The ingestion of a large quantity of copper sulfate has caused vomiting, gastric pain, dizziness, exhaustion, anemia, cramps, convulsions, shock, coma and death. Toxicity information for inorganics was taken from Dangerous Properties of Industrial Material. Sixth Edition, 1984. Organics Generally, voes may cause eye irritation and repeated skin contact to high concentrations of the chemicals may result in dry, scaly dermatitis. voes tend to defat the skin. When inhaled at high concentrations, voes act as a narcotic and a central nervous system depressant. Acute narcotic and a central nervous system depressant. Acute exposures via inhalation and/or ingestion may cause dizziness, lack of coordination, drowsiness, slowing of mental ability, fatigue, unconsciousness, respiratory and circulatory failure, and possible death. Long-term or chronic ingestion exposures would have serious health effects. Chronic exposure to voes by inhalation or ingestion have been associated with hepatic damage, immune system disturbances, and kidney function impairment. In addition, a number of the voes found at the site. However, long-term or chronic ingestion exposures at these levels would have serious health effects. Chronic exposures to voes via inhalation or ingestion have been associated with hepatic damage, immune system disturbances, and kidney function impairment. In addition, a number of the voes found in the onsite groundwater are classed as possible (1,1- DCE), probable (1,2-DCA, PCE, TCE, chloroform), and known (vinyl chloride) human carcinogens by EPA and the International Agency for Research on Cancer. Additional information regarding toxicity of the individual voes and chromium may be obtained from toxicological profiles developed by ATSDR (ATSDR, 1989). The toxological profiles for voes have not been published by ATSDR. 3.2.4 Human Health Risk Characterization The human health risk characterization is a quantitative · assessment and is performed by utilizing information from the exposure assessment and toxicity assessment. Because data regarding existing site conditions is limited, even a quantitative preliminary health risk characterization is not possible at this time. Data collected during the RI will be used to perform a risk characterization as described in section 5.6.4. The human health risk presented by the inorganic contaminants at 39 .I I I I I I I I I I I I I I I I I I I the Channel Master site is relatively low since the exposure opportunities are limited and contamination concentrations are not believed to be extremely high. Concentrations of voes in the onsite groundwater could be fairly high; however, the human health risk is believed to be fairly low as the exposure potential to the surrounding population is limited. The greatest current health risk is to onsite employees with access to the fenced areas, and site remediation workers. 3.2.5 Ecological Assessment As with the human health risk assessment, the ecological assessment is performed by utilizing information from the exposure assessment and toxicity assessment. Data regarding existing site conditions is limited. No surface water or biological media data exist and sediment data is limited. Therefore, even preliminary ecological assessment is not possible at this time. Data collected during the RI will be used to perform an ecological assessment as described in section 5.6.4. 3.3 Remedial Response ARARs and Preliminary Remedial Response Objectives In accordance with the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA), as amended by the Superfund Amendments and Reauthorization Act (SARA), site- specific applicable or relevant and appropriate requirements (ARARs) must be identified and primary consideration given to those remedial alternatives that meet or exceed all ARARs. The Remedial Response Objective is to meet or exceed ARARs for the contaminants of concern as given in Table 3-7. A preliminary assessment of remedial technologies which may be employed to attain remedial response objectives are given in Section 4-2. 40 I I I I I 4.0 WORK PLAN RATIONALE 4.1 Scopa of Remedial Action For the Channel Master site, the general goals of the remedial action as detailed in 40 CFR 300.68 (j), are to "mitigate and minimize damage to and provide adequate protection of public health, welfare, or the environment." Remediation of Channel Master may encompass groundwater, sediments, soil and sludge. An assessment of remedial technologies is presented in this section followed by descriptions of potential treatability studies used to evaluate these alternatives. I 4.2 Preliminary Assessment of Remedial Technologies I I I I I I I I I I I I I Previous remedial efforts at Channel Master have focused on removal of contaminant sources including the sludge from the lagoon that resulted from the plating wastewater treatment, and two oil tanks and voe-contaminated soil adjacent to the tanks. Remedial technologies presented here address: l) containment and/or removal of any remaining voe contamination in both the soil and groundwater; and 2) removal of contaminants from the sludge drying area where eleven sludge pits were identified in a 1965 aerial photo of the site. Once field sampling efforts identify the extent of contamination, the remedial technologies presented here will be more closely scrutinized to select the technology which meets clean-up objectives in the most cost effective manner. Treatability studies will be recommended at that time if required. Remedial technologies presented here include: •No Action •Soil •Water Offsite RCRA disposal Low permeability clay cap Low temperature thermal treatment Incineration Insitu biological treatment Soil washing/extraction Solidification/stabilization Vitrification vacuum extraction of voes Discharge to publicly owned treatment works Air stripping Carbon adsorption/ion exchange Biological treatment Chemical precipitation Reverse osmosis 41 I I I I I I I I I I I I I I I I I I I - 4.2.1 No Action Description. In this case, "no action" means "no further remedial action. " Instead, institutional measures are taken to isolate the public from the contaminated media, specifically the soil and the groundwater. This can be accomplished through deed restrictions, installation of a perimeter fence and warning signs to keep people offsite, and restricted use of the groundwater. Groundwater monitoring can help to determine if contaminants are leaching from the soil, or if contaminant concentration is decreasing due to natural soil flushing. Applicability. "No action" establishes a baseline by which to compare other remedial alternatives, both for soil and water. It is required under the NCP. 4.2.2 Boil The following is a discussion of remedial technologies for contaminated soil and their applicability to the Channel Master site. OffSite RCRA Disposal Description. excavating the disposal. Offsite disposal in a RCRA vault involves soil and transporting it to a RCRA facility for Applicability. The applicability of RCRA disposal depends on the contaminants present in the soil, volume of the soil to be handled, the distance to the nearest approved facility, and unit hauling and disposal costs. Land-ban restrictions now prohibit land disposal of soil contaminated with chlorinated solvent wastes without first removing or destroying the solvent. If testing reveals that the soil contains no listed land-ban solvent waste then land-ban restrictions would not apply to the waste. LOW-Permeability Cap Description. This alternative involves reducing surface water drainage onto the site and capping the site with a low permeability clay on top of a synthetic liner. Storm water that drains from the roofs and parking lots would be diverted away • from contaminated areas. The cap would prevent rainwater from percolating through the soil and then into the groundwater. While contaminants would not be removed from the soil, their tendency to migrate into the groundwater and then offsite would be reduced. 42 I I I I I I I I I I I I I I I I I I I Applicability. The Channel Master site is generally flat, making the construction of a cap relatively easy. A suitable clay and synthetic liner would probably be required for the cap. While the tendency of the contaminants to migrate offsite would be reduced, deed restrictions affecting site use and long term monitoring of the cap integrity would be required. Low Temperature Thermal Treatment Description. Low temperature thermal treatment is a process whereby volatile organics are removed from the soil through evaporation. The soil is screened and then heated to approximately 200° c. During the heating process the soil is mixed and agitated, thus allowing moisture and volatiles to vaporize and escape. The volatiles can be destroyed by use of an afterburner, recovered by a condenser and carbon adsorption system, or released directly into the atmosphere. This treatment technology is also referred to as enhanced volatilization. Applicability. The system is capable of processing various types of soil and would be an effective means of removing volatile organics contamination. The heating temperatures are low relative to incineration, thus it is cheaper than incineration. If semi-volatiles are detected in significant quantities, this treatment will not be able to treat them. This method could only be used as preliminary treatment for any soil/sludge that is also contaminated with chromium. The processed soil may then be suitable for a soil washing or solidification/stabilization process to remove any remaining contaminants. Incineration Description. Incineration units can take the form of multiple hearth furnaces, rotary kilns, infrared incineration, and fluidized beds. Soils are subjected to temperatures of 800 - 1100° C, which will evaporate moisture, destroy organic matter and vaporize volatiles. In commercial chromium production the ore (chromite, Fe(Cr02)2] is processed by heating it with sodium carbonate and nitrate to form sodium chromate, Na2cro4 which.is then extracted in water. Many chromium compounds are then derived from sodium chromate. Sodium chromate technology may also be applicable to extract chromium (99,000 ppm), from the soils and sludges at the Channel Master site. The chromium could . then be reconcentrated if necessary by evaporation, precipitation, or ion exchange. Applicability. Incinerators may be used to process both the soil and sludge at the site. Incineration alone is ineffective on heavy metals, unless they are volatile at high temperatures. Therefore, this process would probably precede chromium treatment (removal or stabilization). The cost of equipment and heating fuel are critically important considerations. The chromium may 43 I I I I I I I I I I I I I I I I I I I be in a reduced form at present, incineration might oxidize the chromium to the more toxic hexavalent form. If lead is present it could vaporize at high temperatures. Xnsitu Biological Treatment Description. Insitu biological treatment is the process of stimulating microorganisms to degrade waste material. Microbial activity is enhanced by the introduction of oxygen and nutrients into the soil. If the waste material is not a suitable carbon source, the bacteria will require another carbon source which it will degrade through co-metabolism. If indigenous bacteria are not present, or are unable to degrade the waste, genetically engineered organisms may be used to degrade the material. Applicability. For insitu biological treatment, the soil and contaminants would have to be assessed with regard to contaminant types and concentration and soil characteristics. This method would have no effect on fixing or removing chromium, which might be toxic to the micro-organisms that ~egrade chlorinated solvents. It is not known if indigenous bacteria are present. soil washing/Extraction Description. Soil washing is a process that removes fine particles such as clay and organics from the rest of the soil. It can be performed on excavated soil or insitu (termed soil flushing). Soil is screened, an appropriate cleansing agent (i.e. solvent, surfactant) is introduced, and wash water separates clays and organics from coarser soil. The result is a significant volume reduction of contaminated material. Applicability. This procedure is a separation process. Thus, residuals would require further treatment or disposal. This process might be appropriate for the chromium-contaminated sludge/soil. However, the chromium sludge was the precipitate from a reducing process and is already concentrated. Metal precipitates might be extracted from the sludge/soil and dissolved into the wash solution if the pH is adjusted by the addition of acid or base. Washing might serve only to dilute the chrome, making a larger volume of waste. Organic contamination could be removed from soil through washing, however, the wash would then require additional treatment to remove the organic contamination. If metal-contaminated sludge is confined to discrete areas such as the sludge drying area of lagoon site, it would probably be more feasible to excavate and treat the contaminated material rather than attempt insitu metals removal, Insitu treatment would require the installation of injection and extraction wells. 44 I I I I I I I I I I I I I I I I I I I Solidification/Stabilization Description. The contaminated soil/sludge is excavated to the limit of contamination and then mixed with a stabilizing agent, such as cement and water to fix the contaminants in a matrix that reduces the potential for leaching. The mixture is returned to the pit from which the soil/sludge was excavated and capped with clean soil. Applicability. This process would require no dewatering since the moisture in soil would be used in the pozzolanic reaction that occurs when water is added to cement. The chemicals originally used to treat the electroplating wastes might affect the cement. Bench testing would be required to determine the appropriate stabilizing agent and mix ratio for the process. Organics present in the sludge/soil would also affect the type of cement selected and the mixture used. Land-ban restrictions may apply to this waste. Vitrification Description. Vitrification is a thermal treatment process which immobilizes contaminants in a vitreous mass and can be performed on excavated soil or insitu. For excavated material, the metals- contaminated sludge/soil would be excavated and charged to a vitrifying unit either on a batch or continuous basis. Organics would be destroyed by the extremely high temperature developed with this electric furnace and the metals would be contained in a non-leaching glass-like product. Insitu treatment requires the installation of electrodes in the ground and applying a large electrical current to these electrodes. Glass frit and carbon are placed on the ground surface between the electrodes. Electrical resistance of the soil generates heat. Applicability. Cost is a primary consideration for this option. The soil/sludge would have to be evaluated to see if vitrification would work. Bench tests would have to be conducted to see that the vitrified mass passes the extraction procedure toxicity test for chromium. The process requires high electrical energy input. Vitrification has been tried on a limited basis in the field. Some of the information reviewed for the Channel Master site indicated that groundwater may be contaminated with chromium. This would have a negative impact on insitu vitrification. Electrical power requirements would be greatly · increased by the presence of water. vacuUIII Extraction of voes Description. This process is used to extract voes from soils. When performed insitu the basic components are production wells, monitoring well, and high-vacuum pumps. Production wells are drilled to just above the water table when groundwater is not 45 I I I I I I I I I I I I I I I I I I I contaminated. If groundwater contamination is present and the water table is shallow, the production wells are drilled directly into the water table. Placement of production wells would be determined from field testing. A manifold connects vacuum pumps to the production wells and the vacuum pumps draw voe- contaminated air through the soil to the production well. Fresh air from the surface is drawn through, and essentially flushes, voes from the soil. voe-contaminated air drawn from production wells is either vented to the atmosphere or treated to concentrate or destroy the voes. carbon adsorption or incineration are two possible treatment methods for voe laden air. Applicability. The Phase I Groundwater Evaluation Report indicates a very shallow groundwater depth of 8 to 12 ft. Drilling data provided indicates that the water table is typically 10 ft. below the surface. Additional field tests would have to be conducted to see if the soil is suitable for this treatment technology. With the water table close to the surface, shallow (and therefore less expensive) wells could be installed. This technology would not address any contamination from metals. A treatability study would be required to evaluate this option. ,.2.3 Water The following describes remedial technologies for water and discussed their applicability to the Channel Master site. Pump and Discharge to a Publicly owned Treatment Works (POTW) Description. This remedial activity would involve pumping voe- contaminated groundwater from extraction wells and discharging it to a POTW at an acceptable flow rate. Wells are placed down gradient, and peripheral to, site contamination and serve as interceptors, preventing the migration of contaminants offsite. Applicability. Discharging voe-contaminated water to the POTW would require the approval of regulators and local authorities, however, this alternative would be relatively easy to implement. The Channel Master site has sanitary sewer service which discharges to a POTW. In a typical activated sludge system, voes would probably be biodegraded or air-stripped from the waste water during treatment. A treatability study may be necessary to determine if this treatment method would remove voes from the · contaminated groundwater. Air Stripping Description. Air stripping of contaminated water consists of the transfer of the contaminant from the water phase to the gas phase. The gas (usually air) is contacted with the water either by bubbling air through the water, by intense mechanical 46 I I I I I I I I I I I I I I I I I I I - agitation of the water, by spraying the water into the air, or by water flowing through packed towers. Removal of the contaminant will occur as long as the water is kept in contact with the air, and the air has a lesser concentration of contaminant. Applicability. Air stripping has been proven effective in removing voes in both groundwater and surface water. It would be applicable as a pump and treat method for groundwater treatment and might be considered as a preliminary treatment step for the water that is removed from chromium contaminated soil/sludge. carbon Adsorption/Ion Exchange Description. Carbon adsorption and ion exchange are water treatment processes where contaminants are removed from solution and adsorbed to surface of finely divided granular media. The electrostatic forces which attract the adsorbate (contaminant) to the adsorbent (activated carbon or ion exchange media) must be great enough to overcome the adsorbate-solvent bonds. Carbon adsorption is used to remove non-polar organics while ion exchange is effective means of removing select dissolved metal ions. Applicability. Carbon adsorption can remove organics at low levels. The adsorbativity of compounds is influenced by solubility, molecular size and polarity. Chlorinated solvents found in the soil and groundwater at this site are readily adsorbed by activated carbon. Ion-exchange media specifically designed to remove dissolved metals are available. Batch or column tests can be performed to predict removal efficiency for carbon adsorption and ion exchange. Biological Treatment Description. Biological treatment is a process in which bacteria degrade organic wastes. This can be done either under aerobic or anaerobic conditions. In aerobic treatment systems, organics and oxygen are broken down into carbon dioxide and water. In anaerobic treatment systems, organics are broken down into methane and carbon dioxide. Aerobic degradation is usually more rapid and complete, but anaerobic degradation is preferred when there are volatile organics present. Applicability. The applicability of biological treatment of the groundwater is dependent upon the degradability of the constituents. Genetically engineered bacteria can be developed to degrade specific hazardous wastes. If halogenated volatile organics are present, anaerobic degradation is preferred. Strict anaerobic conditions must be maintained, such as would be provided by an airtight reactor. Anaerobic degradation technology has not yet been applied to contaminated groundwater. 47 I I I I I I I I I I I I I I I I I I I Chemical Precipitation Description. This treatment process requires the addition of a suitable coagulant such as lime, alum, or polymer to contaminated water. The coagulant forms charged complexes which bind to dissolved metal ions. Flocculation causes these particles to agglomerate. Gravity then causes these particles to precipitate. The metals are concentrated in the precipitate which is removed as a sludge. Applicability. This process may be an effective means of removing metal ions or metal ion complexes from contaminated groundwater, although it is typically most cost-effective with concentrated solutions. This proces is also suitable for removal of organics if powdered activated carbon is added with the coagulant. A treatability test may be appropriate for this option. Reverse Osmosis Description. Reverse osmosis is a membrane separation process which results in a smaller volume of a more highly contaminated solution. Pure water flows from the contaminated solution through a semipermeable membrane. The concentration of contaminant in the remaining solution becomes more concentrated. External pressure is applied in order to overcome osmotic pressure. Applicability. Reverse osmosis is used in the desalination of seawater and can be used to remove organics from solution. Because of the high pressure involved, this process is prohibitively expensive for large scale operations and therefore may not be appropriate technology for concentrating voes or metals from groundwater. 4.3 Treatability Studies To achieve clean-up goals in the most cost effective manner many of the remedial alternatives presented here would have to be· tested. These treatability studies would involve field and laboratory work. The goal of these studies would be to demonstrate the technology on a site-specific basis and develop an estimated unit cost for each of the remedial alternatives. More data is needed to determine the extent of organic and inorganic contamination at the Channel Master site. Once the extent of contamination has been established, the treatment technologies presented here should be reconsidered. Treatability studies should identify the most appropriate mix of technologies for treating Channel Master wastes. 48 I I I I I I I I I I I I I I I I I I I 4.3.1 summary of Waste Characteristics For the Channel Master site, matrices requiring treatment may include soil/sludge and groundwater. The following observations will be considered in selecting suitable treatability studies: • The organic contamination present reportedly consists of volatile components most of which are halogenated. • voe contamination was reportedly found in the soil and groundwater south of the main building. • voes have been reported at concentrations up to 9000 ppm. Tetrachloroethene, trichloroethene, 1,1,1 trichloroethane, methylene chloride, toluene, and acetone are the voes reported to be present at Channel Master. • Chromium is the predominant heavy metal that was found in sludges from the lagoon and sludge drying area at the Channel Master site. Other inorganics present in these sludges include cyanide, cadmium, arsenic, copper, and nickel. • If the present chromium is probably in the trivalent (reduced) form and exists as a relatively insoluble precipitate from the treatment process. 4.3.2 Potential Treatability studies Treatability studies may be required to identify the appropriate mix and sequence of treatment technologies. For soils contaminated with voes alone a low temperature thermal treatment process may be appropriate. However, for soils that are also contaminated with heavy metals additional treatment to remove or fix the metals may be investigated. If field screening sample and analysis reveals the presence of heavy metals, then a treatment technology for metals removal should be considered. Vacuum extraction, carbon adsorption~ air stripping, and biodegradation should be investigated for voe removal. If discharging voe-contaminated groundwater to the POTW is an acceptable option a bench scale bioreactor simulating unit operations, such as activated sludge or trickling filter, employed at the local POTW may be an appropriate treatability study. The details of treatability studies will be better defined once additional field sampling data are available. 4.4 Data Requirements/Data Quality Objectives Data requirements for both the RI and FS were evaluated after review of existing and available information. Data needs were determined by first examining what decisions needed to be made for the site and what additional information was required to make those decisions. DQOs are presented in the QAPP. DQOs were based on the intended 49 I I I I I I I I I I I I I I I I I I I use of the data and were selected in accordance with EPA's Data Quality Objectives for Remediation Response Activities, OSWER Directive 9335.0-7B, and recommendations given in Guidance for Conducting Remedial Investigations and Feasibility Studies under CERCLA. ,.,.1 Characterization Data Sampling and analysis of soil, sediment, surface water, and groundwater is needed to characterize the site. These data are needed to define contamination boundary lines, verify existing data, verify the existence and extent of the sludge drying area, identify contaminants of concern, and define volume projections for site remediation activities. Contamination boundary lines need to be defined because the existing information is not adequate to accurately delineate the extent of contamination. The information available is inadequate because: (1) existing data do not conform to technical and quality assurance requirements, (2) not enough sample data are available for peripheral areas of the site, (3) previous investigations of the sludge drying area are inadequate, and (4) records do not indicate that any sampling was done after the Channel Master clean-up. Review of existing data indicates that gaps exist in defining the nature and extent of contamination present at the site. Analysis is necessary for potential contaminants of concern such as hexavalent chromium, voes and cyanide, which may be present in surface water, soil, sediment, and groundwater. Additionally, the target compound list of organic and inorganic analities will be analyzed for in accordance with EPA Contract Laboratory Program protocol. The RI effort will produce a comprehensive set of data of known quality. For the Channel Master site, samples will be collected and analyzed in accordance with established DQOs and using EPA- approved sampling protocols presented in the EPA Region IV ESB SOPQAM. Data needs, DQO level and analytical requirements, sampling locations, and number of samples for each medium are discussed in detail in Section 5.3 under Field Investigations. Finally, an accurate determination of the nature and extent of contamination at the site is necessary to provide reliable volume · estimates. These volume estimates are essential in the selection of an appropriate remediation alternative and developing realistic cost estimates. 50 I I 4.4.2 Geotechnical/Hydrogeologic Data I I I I I I I I I I I I I I I I I Additional hydrogeologic data are needed to verify the accuracy of existing data, and to understand potential migration pathways and mechanisms for contaminants. Specific data requirements for geotechnical and hydrogeologic data are presented in Section 5.3. The groundwater flow direction and gradient data will be confirmed to determine potential migration pathways and rates. Groundwater levels will be measured over a period of time to determine if the gradient and flow direction of the aquifer is affected by factors such as surface recharge, and seasonal precipitation patterns. To obtain this data, monitoring wells will be installed to obtain the necessary information. Local, offsite, private wells will be used to make water level measurements if installation details can be verified and access agreements secured. Additional data are needed to understand the geochemistry of the soils and their response to the contaminants. Tests such as cation exchange capacity and distribution ratio (partitioning coefficient) will determine the soil's potential to fix metal contaminants. The partitioning ratio will determine a similar soil capacity for the organic compounds. 4.4.3 Feasibility Study Data Additional remediation options and technologies will be explored so that the best remediation alternative for the site can be selected. 4.4.4 Health and Safety Data The Health and Safety Plan (HSP) for the Channel Master Site is designed to protect project personnel involved in site activities and the surrounding community. The plan addresses applicable regulatory requirements contained in: • 29 CFR 1910.120(i)(2) Occupational Health and Safety Administration, Hazardous Waste Operations and Emergency Response, Final Rule, March 6, 1989; • US EPA Order 1440.2 -Health and Safety Requirements for Employees Engaged in Field Activities: US EPA Order 1440.3 - Respiratory Protection; • US EPA Occupational Health and Safety Manual; and • US EPA Interim Standard Operating Procedures (September, 1982). 51 I I I I I I I I I I I I I I I I I I - The plan provides a site background discussion and describes personnel responsibilities, protective equipment, health and safety training, and the types and extent of medical surveillance. The plan identifies problems and hazards that may be encountered and how they will be addressed. Procedures for protecting third parties, such as visitors and the surrounding community, are also provided. ,.,.s Quality Assurance Bechtel's Quality Assurance Project Plan (QAPP) for the Channel Master site QC presents the policies, organization, objectives, functional activities, and specific QA activities designed to achieve the data quality goals. The QA/QC plan covers the 14 elements of QA as outlined by EPA's Guideline For Conducting Remedial Investigation and Feasibility Studies Under CERCLA, Interim Final OSWER Directive 9355.3-01 (EPA, 1988). 52 I I I I I I I I I I I I I I 5.0 RI/FS TASKS Tasks 1 through 11 are detailed in the following subsections. 5.1 Task 1: Project Planning Task 1, Project Planning, is comprised of this Work Plan, the Field Operations Plan (FOP), QAPP and HSP. 5.2 Task 2: Community Relations The existing community relations plan (CRP) will be modified to include the remedial action phase of the project and will reflect an assessment of the successes and failures of the community relations program to date. The plan will be modified to provide guidelines for encouraging community participation in remedial planning activities at the site and the decision-making process regarding clean-up; the plan will also highlight any possible approaches to determine public awareness and information needs including conducting personal interviews with members of the community. 5.3 Task 3: Field Investigations Site investigations will be conducted to characterize the site and its actual and/or potential hazard to public health and the environment. The investigations will allow development of preliminary remedial alternatives and will support the detailed evaluation of alternatives in the feasibility study. This section outlines the data needs, the medium to be sampled, number of samples in each category, the rationale for sampling from the specified locations, the analytical requirements, and use for data. The logistics of the field investigations including sample types, sample methods, sample code, preparatory activities, field equipment, personal protective equipment, responsibilities of the field team, and health and safety guidelines are presented in the FOP for the Channel Master site. During the RI, the historical development of the site area will be reviewed to identify occasions when quantities of contaminated soils or other materials may have been disturbed or carried from the site. Aerial photographs, maps, and other historical documents will be examined to identify events that may have · resulted in the disturbance of soils or structures. If available, utility maps and building permits will be examined to determine dates of construction activities. For the purpose of performing the site investigation described in this work plan, EPA will obtain permission to enter the properties from which samples will be collected and buildings on the site. 53 I I I I I I I I I I I I I I I I I I I TABLE 5-1 SAMPLING AND ANALYSIS DETAILS A. Field Screening of Groundwater Brief Description Rationale for S~ling S~le Locations Rationale for Sarrple Locations On-site/CLP Lab (OQD Level) Analyte(s) Rationale for Analysis Detection Level B. Surface soil •Initial site screening will involve obtaining grOISldwater s~les using hydrocone technique. •Analyzing saq,les on-she using a portable GC. •Delineate areal extent of VOC·contamination using preliminary screening. •Aid in finalizing locations for boreholes and monitoring wells. •See Figures 5·1 and 5-2. •Approximately 40 grOIA"dwater &arlfjles. •Two backgrOl.nd &Bffl)les are labeled HC-1 and HC·2. •The remaining s~l ing locations were chosen based on: Previous waste related activities. -Previous sarq:,ling results. • Downgradient of Chal'Ylel Master remediated areas. •On-site (Level II); approximately 20X of the &Bn1Jles to CLP lab for calibration purposes (Level JV). •Volatile organic contaminants including: TCE, PCE. 1,1,1-TCA, 1,1·DCE. •The above mentioned contaminants were identified during previous sarrpl ing investigations conducted at the Channel Master site (Ref. 3 and 5). •Less than 1 ppn. Brief Description •Obtain surface soil aarrple from an approximate 5 in depth. Rationale for SSltlJling •To delineate the surficial extent of soil contamination. Saq:,le Locations •S~ Figure 5-4. NUTi:>er of Saq:,les •12 surface soil aaaples a 1 S8111Jle per borehole location. Rationale for S""l'l• On-site/CLP lab (DQD Level) Analyte(s) Rationale for Analysis Detection Level •One backgrOU'ld •""l'le labeled BH-1. •Four downgradient • ...,les labeled BH·Z, BH-3, BH-4 & BH-5. •The remaining saq,le locations were chosen based on previous waste activities, and are labeled BH·6 thru BH·1Z. •All surface_,toil l""l'les will be analyzed thru the CLP lab (Level IV). TCLP and Cr (Level Y). •TCL, Cr◄-6, TCLP and dissociable cyanide. •Th~TCL includes the entire suite of contaminants of concern. •Cr and dissociable cyanide were identified durh'l9 previous aanpl ing investigations. •The TCLP procedure has replaced EP-Tox. TCLP procedure also provides toxicity characteristics for 39 contaminants, including those that have been detected at the Channel Master site. • CLP requirements. 54 I I I I I I I I I I I I I I I I I I I - TABLE 5-1 (continued) SAMPLING AND ANALYSIS DETAILS c. Subsurface Soil samples Brief Description •Obtain split-spoon soil aanples every 5 ft from each borehole. Rationale for SM1)ling •To define the nature and extent of subsurface soft contamination. N"1D<r of S-les Rationale for Sanple On-she/CLP Lab (DQO Level) Analyte(sl Rationale for Analysis Detection Level A total of 75 subsurface soil &Bn1Jles: •35 saq:,lu; seven boreholes at 5 SM1)les per borehole. •40 sanplu; five 1110nitoril"IQ wells at 8 spl ftspoon sanples per well. •one backgrOU'ld location •-le labeled BH-1. •Four downgredient locations labeled 8H·2, BH·3, BH·4 & BH-5. •The remaining SM1)le locations were chosen based on previous waste activities, and are labeled BH·6 thru BH·12. •All subsurf.!&e soil sa~les will be analyzed thru the CLP lab (Level IV). TCLP and Cr (Level V). •TCL, Cr+6, TCLP and dissociable cyanide. •The above mentioned contaminants were identified during previous sa~ling investigations conducted at the Charnel Master site (Ref. 3 and 5). •CLP requirements. D. Groundwater S11111ples Brief Description •Bechtel will install and develop 5 MW1s. •Obtain grOl..ndwater sarrples from these 5 IIN's. Rationale for S811'pling •To define the nature and extent of grOU'ldwater contamination. S~le Locations N"1D<r of S-les Rationale for Sa,rple Locations On-site/CLP Lab (DQO Level) Analyte(sl Rationale for Analysis Detection Level A total of 6 grOl.l"ldwater sarrples: •5 sa,rples; five MW at 1 sarrple per well. •1 •-le; existing Cherne! Nester well et •-le. •Two backgrOU'ld •-le labeled NW·1 & CM-1. •The remaining san-ple locations, MW-2, MW-3, MW-4 & MW-5 were chosen based on: Previous waste related activities. Contamination was identified fn Charnel Master wells. • Downgradient of Charnel Master remediated areas. •On-site sanples will be analyzed for pH, terrperature and conductivity. •All groundwater •-les will be analyzed thru the CLP lab (Level IV). •TCL, Cr-Hi and dissociable cyanide. •Th~TCL includes the entire suite of contaminants of concern. • Cr and dissociable cyanide were identified during previous saq:,l fng investigations. •CLP requirements. 55 I I I I I I I I I I I I I I I I I I I TABLE 5-1 (continued) SAMPLING AND ANALYSIS DETAILS E. surface Water samples Brief Description Rationale for San:pling S~le Locations Niirber of Saq,les Rationale for Saq>le On-site/CLP Lab (DQO Levell Analyte(sl Rationale for Analysis Detection Level •Obtain surface water saq>les from the creek rlZW'ling through the site and the pond located south of the site; backgrOU'ld sarq:,le frcrn the creek in the north. •To define the nature and extent of surface water contamination. •To delineate pathways of contaminant migration off-site. •See Figure 5-2. •One upgradient saq,le labeled S\J-4. •Three downgradient s~les labeled: SW-1, S\J-2, and SW-3. •On-site saq,les will be analyzed for pH, teq>erature and conductivity. •All surface water s~les will be analyzed thru the CLP lab: TCL (Level IV) cr•e and dissociated cyanide (Level V). •TCL, cr•e and dissociable cyanide. •The TCL includes the entire suite of contaminants of concern. •er•" end dissociable cyanide were identified during previous saq,ling investigations. • CLP requirements. F. sediment samples Brief Description •Obtain sediment sanples frcxn the creek rU'Yling through the site and the pond located south of the aite. Rationale for Sarl1)ling •To define the nature and extent of surface water contamination. •To delineate pathways of contaminant migration off-site. S~le Locations •See Figures 5-2. NLIJDer of .S&ffl)les •4 senples. Rationale-for Sanple •One upgradient S8ff1)le labeled SD-4. On-site/CLP Lab (DQO Levell Analyte(sl Rationale for Analysis Detection Level •Three downgrl!ldient saq,les labeled: SD-1, S0-2, end so-3. •All sediment 1""'1les will be analyzed thru the CLP lab: • TCL (Level IV) -er•" end dissociated cyanide (Level V). •Tel, er•" end dissociable cyanide. •The TCL includes the entire suite of contaminants of concern. •er•" and dissociable cyanide were identified during previous saq,l ing investigations. • CLP requirements. 56 I I I I I I I I I I I I I I I I I I I TABLE 5-1 (continued) SAMPLING AND ANALYSIS DETAILS G. Residential/Municipal Wells Brief Description •Obtain grOU'ldwater saq,les from local ruidentfal and n.nicipal wells. Rationale for Sanplif'ISI •To define the nature and extent of grtu'Glater contamination. •To delineate off-site migration of gro.rdwater contamination. Se,rple Locations •The closest private well fs ahown on figure 5·2. Other residential/fflllicipal well On-site/CLP Lab (DQD Level) Analyte(s) Rationale for Anelysis Detection Level aanple locations will be decided while on-site. •One private well located south of the site labeled P~-1. •Remaining wells to be •11111'led will be Identified and labeled PW (residential wells) or MN (nuiicipal wells). All wells are downgracHent. •On·site s~les will be analyzed for pH, tefl1)erature and corductfvity. •All residential/nu,icipal water saq,les will be analyzed thru the CLP lab: TC~(Level IV) Cr and dissociated cyanide (Level V). •TCL, Cr+6 and dissociable cyanide. •Th~TCL includes the entire suite of contaminants of concern. •Cr and dissociable cyanide were identified during previous sarrpl ing investigations. •CLP requirements. 57 Lil ex, 0 2018~ f IG21.DGN 200 400 I'= 200' 600 FIGURE 5-1 CHANNEL MASTER SITE HYOROCONE SAMPLE LOCATIONS FOR PRELIMINARY ON-SITE SCREENING 0 HC-2 ' SHALLOW OEPRESSIO~ LOCATED ON f AERIAL PHOTO 1. . ""' PR<ffRTY 8(Ur()ARY trJSTINC f[NC[ -RAILROAD DITCH PROPOSE.D HYDROCON[ SDl'l.[ LOCI 111'.JfS ""' 0 0 EXfjTING CHAll("L NASTEA 0 TOOING llll I I I I I I I I I I I I I I I I I I I - 2 0 0 300 mas V!CSITE.OGN VloflCS.2 FIGURE 5-2 CHANNEL MASTER SITE SURFACE WATER, SEDIMENT AND OFF-SITE HYDROCONE SAMPLING LOCATIONS 0 ., HC-40 J---···· 0--··· . .. • C-39 O l) ~ 0 a c::::::, H C -3 7 t:::::J t:::J c::J .........,_,_._ - ~···- * 0 r///;'l. 0 LEGEND BUILDING RAILROAD CREEK ROAD DITCH 0 0 a 0 PROPOSED SURFACE WATER ANO SEDIMENT SAMPLING LOCATIONS PROPSEO OFF-SITE HYOROCONE SAMPLING LOCATIONS PROPERTY BOUNDARY PRIVATE WELL I I I I I I I I I I I I I I I I I I I - 5.3.1 surveying and Mapping of the Site The existing topographic survey map for the Channel Master site was developed in April 1980. Remediation activities conducted by Channel Master may have caused significant changes in the topography at the site. A visual survey of the site will be conducted and the map of the site will be updated as needed. A licensed surveyor will be contracted to conduct a field survey to develop a planimetric map that includes topographic information and physical features and vicinity properties. One concrete monument for use as a permanent bench mark based on USGS Datum, 1929 general adjustment, will be established for the site. Aerial photographs will be used when available, along with information gathered during the preliminary site visit to identify physical features of the area. 5.3.2 Waste Characterization Table 5-1 summarizes the data needs required to supplement the existing data, DQO level, rationale for sampling, proposed number and type of samples, and the analytical requirement for each matrix. A field screening program will be conducted to define the areal extent of organic contamination in groundwater (Table 5-lA and Figure 5-1). Groundwater samples will be collected using a hydrocone-type groundwater sampling technique. Hydrocone sample locations have been selected downgradient of: the excavated in- ground concrete waste oil tank and in-ground No. 2 fuel tank areas, the former lagoon area and in/around the sludge drying area (Figures 5-1 and 5-2) including two upstream locations. The locations identified in this work plan for hydrocone-type groundwater sampling are only tentative. They will be modified, if required, depending on the site conditions. Approximately 40 hydrocone groundwater samples will be collected and analyzed for TCE, TCA, PCE, and trans-1,2 DCE using a portable HNU gas chromatograph. Survey contour maps will be developed based on analytical results and used to qualitatively define the geometry of the source area(s), which will then be used to delineate the plume •. Existing lithographic information indicates potential difficulties in utilizing the hydrocone technology. The depth of the required sampling combined with the hardness of the overburden (100 blowcounts) could make direct penetration of the hydrocone difficult. Insitu Technology, the developer of the hydrocone technology, believes that inserting a "piezocone" to obtain additional lithographic information will unconsolidate the soils sufficiently to allow the hydrocone to be inserted. If this approach is unsuccessful, the driller should auger a small diameter hole. The driller will attempt to drill the hole and extract the drill bit without surfacing spoils. The soils would 60 I I I I I I I I I I I I I I I I I I I be sufficiently loosened to allow for the insertion of the hydrocone sampler. 5.3.3 Bydrogeologic rnvestigation A hydrogeologic investigation will be conducted at the Channel Master Site to determine the present and potential extent of groundwater contamination. Permanent monitoring wells will be installed to carry out the initial characterization of the hydrogeologic conditions at the site. Groundwater-level measurements will be taken to establish site groundwater gradient and flow direction, and most importantly, the rate at which these characteristics may change as a function of factors such as precipitation and recharge of the aquifer. Field permeability tests will be conducted during drilling operations to confirm and clarify the hydraulic conductivity at the site. Hydraulic conductivity will be determined using a slug test. This test involves dropping a weighted object of known volume into the bottom of the well. The amount of time it takes for the top of the water column to return to its original height is recorded. The results of the preliminary screening program will verify the proposed monitoring well locations (Figure 5-3). One background 15 ft. deep monitoring well (CM-1) installed by S&ME still exists onsite. This well is located in the NW corner of the property. Five permanent monitoring wells will be installed. The results of the preliminary screening program will verify the proposed monitoring well locations (Figure 5-3). Any property owners will be identified and permission to install offsite wells will be obtained. All monitoring wells will be surveyed for location and elevation. The data will include elevations of the ground surface at each well and the top of the inner casing elevations with the cap removed. Regional aquifers will be identified, characterized, and classified according to EPA Groundwater Protection Strategy (Ref. 1). Existing information will be used to the extent possible. Following the development of new wells, groundwater samples will be collected in accordance with the EPA Region rv, ESB SOPQAM (April 1986) for laboratory analysis. The objective of the groundwater sampling analysis is to determine the degree and extent of groundwater contamination from detectable chemical concentrations. Groundwater sample locations are shown in Figures 5-2 (offsite private well) and 5-3 (proposed monitoring wells). The analytical parameters for the groundwater samples are shown in Table 5-1. The survey will address the degree of hazard and mobility of the contaminants present, the 61 I I I I I I I I I I I attenuation capacity and characteristics of the soil, possible additional sources of contamination, and background contaminant levels. Field measurements on the groundwater samples will include temperature, pH, and specific conductivity. 5.3.4 Soils Investigation Surface and subsurface soil samples will be collected from locations shown in Figures 5-3 and 5-4. It is proposed to install five monitoring wells (Figure 5-3) and seven boreholes (Figure 5-4). Surface soil samples will be collected from all twelve locations. BH-1 will serve as a background sample and the remaining boreholes are located downgradient of this. Subsurface soil samples will be collected from the soil boreholes at 5 ft. intervals to a depth of 25 ft. and from the monitoring well boreholes at 5 ft. intervals to a depth of 40 ft. Four geologic borehole samples will be collected for geotechnical tests such as permeability, dry density, percent moisture, centrifuge moisture equivalent, soil classification, and grain size distribution. Additionally, two soil samples will be analyzed for cation exchange capacity (CEC) and the distribution coefficient (Kd). These tests will provide information regarding the ability of soils to fix or mobilize contaminants. This data is necessary to determine aquifer characteristics such as effective porosity and other parameters important to transport modeling and remedial design. All surface and subsurface samples will be shipped to CLP lab and analyzed for TCL, total cyanide, dissociable cyanide, TCLP and hexavalent chromium known to have been used during site operations. I 5.3.5 surface Water and Sediment Investigation I I I I I I I A program will be developed and conducted to determine the location and extent of surface water and sediment contamination. This investigation will include sampling of all local surface waters, lake sediments, and sediments from ditches. Drainage patterns within the study area will be identified to determine potential routes of contaminant migration resulting from surface water runoff and to identify locations where sediments from this runoff may accumulate. A historical evaluation of the changes in drainage patterns will also be completed to determine where past sediment accumulation may have occurred. Surface water and sediment samples from areas of runoff will be collected from the locations shown in Figure 5-2 and analyzed for the parameters listed in Table 5-1. Analytical results will be 62 ·------------------- a-w 0 20385 r JG26.()(,H 200 400 I'= 200' 500 FIGURE 5-3 CHANNEL MASTER SITE MONITORING WELL LOCATIONS -•n-- () 0 @ • DITCH PRCf'OS(O BOREM!lE I r.R(UN()WU[R S.ut>t.ES _______. EXISTING CMANlll MASTER KHI TOA ING 11[.ll CMANNEL MASTER KJtlfORING IIELLS IOCSlROTtOI ·------------------- 0 200 400 I' = 200' 20385 f Hi 25. OtN 600 FIGURE 5-4 CHANNEL MASTER SITE BOREHOLE LOCATIONS • () 0 DITCH PIHl'OYD BMEIO.E SAlf'lES PROPOSED BfJUQ.E AM) r.ROI.H)•A T[R SilWl[S EXJSTINC OWIU NAS1£R MONITORING llllll I I I I I I I I I I I I I I I I I I I used to determine the potential for contaminants to be carried from the site dissolved in storm water runoff. Temperature, pH, and specific conductivity of surface water will be measured onsite and the samples will be analyzed for conventional water quality parameters in addition to the contaminants of concern. Drainage patterns will be identified from U.S. Geological Survey quadrangle maps. Additional data on rainfall and soil characteristics will be collected to predict the likelihood of future soil erosion. This data will be used in assessing the potential for future offsite migration of contaminants. Data on sewer systems layout will be obtained from as-built drawings, municipal records, and previous system studies to determine the layouts, elevations, capacities, and ages of the storm and sanitary sewer systems carrying drainage and sewage. If such data is not available, it will be obtained by onsite inspection of the systems. Areas where contaminants from the site may have accumulated will be identified for investigation during the RI. S.3.6 Air Investigation Atmospheric conditions at the site will be monitored to determine the need for a formal air investigation. During drilling and sampling operations, air monitoring will be performed to evaluate the potential for contaminants to be carried offsite. If the need for air investigation exists for the protection of the public in excess of that specifies in the health and safety plans, a plan will be submitted to the RPM and approval will be obtained prior to implementation. An organic vapor monitor (HNU or OVA) will be utilized to monitor the breathing zone during drilling and sampling operations for health and safety reasons. If the monitor detects levels greater than l ppm, the worker personal protection will be upgraded. s., Task 4: Sample Analysis and Validation Bechtel will summarize the results of all site investigations and present these in the RI report. The objective of this task will be to ensure that this data is sufficient to support the FS. A data management system will be developed including field logs, sample management and tracking procedures, and document control and inventory procedures for both laboratory data and field measurements (see the QAPP). Analytic data will be reviewed to ensure that the data is accurate, precise, and suitable for use in the evaluation of remedial alternatives. Quality control (QC) checking of the analytical data will be conducted, and data validation will be performed at the appropriate field or laboratory QC level 65 I I determine whether it is appropriate for its intended use. For CLP analyses, EPA will validate the data. I s.s Tasks: Data Evaluation I I I I I I I I I I I I I I I I - All site investigations will be analyzed and a summary will be prepared of the type and extent of contamination at the site. The data from the source, characterizations of the site, and investigations at the vicinity properties will be organized and presented so that the relationships among data collected for each medium in each phase of the investigation are apparent. The data will be evaluated to ensure that they are sufficient in quality and quantity to: • • • • Ascertain QA/QC procedures Define surface and subsurface hydrology, flow patterns, soils, and geology, as well as environmental, public health, and ecological consequences Identify and characterize contaminants, pathways, receptors of concern; delineate the type and extent of air, surface water, groundwater and soil/sediment contamination Conduct risk assessment, modeling studies, (if necessary), and develop remedial measures to be considered for evaluation • Evaluate the need for additional remedial investigations The evaluation will include all significant pathways of contamination and an exposure assessment. Contaminant pathways are pathways that may result in an actual or potential threat to public health, welfare, or the environment. Contaminant pathways from source material identified during the field investigation will be identified. An exposure pathway is identified by four elements: (1) a source and mechanism of release to the environment, (2) an environmental transport medium for the released material, (3) a point of potential contact of humans with the contaminated medium, and (4) an exposure route (e.g., drinking water ingestion). Estimating environmental concentrations at potential receptors will involve quantification of the amounts of contaminant that will be released to the environment over time by the various sources identified in the exposure pathway analysis, prediction of the environmental transport and fate of each indicator substance in the identified medium of the exposure pathway, and derivation of time-dependent (both short-and long-term) environment concentrations at the point of exposure. It is 66 I I I I I I I I I I I I I I I I I I I - expected that simple analytical models will be sufficient for this evaluation. If it is found that more complex numerical models are needed, an expanded scope of work will be prepared. 5.6 Task 6: Risk Assessment A baseline risk assessment will be conducted to establish the extent to which contamination present at the site is released from the site and the extent to which it presents an imminent and substantial danger to public health, welfare, or the environment. The potential effects of chronic exposures will also be addressed. This risk assessment will evaluate conditions at the site in the absence of any further remedial actions, which in essence constitutes an assessment of the no-action remedial alternative. The assessment will be in accordance with procedures developed by EPA, and will utilize the Risk Assessment Guidance for Superfund (Ref. 27). Other reference documents will include the Exposure Factors Handbook (Ref. 23), the Superfund Exposure Assessment Manual (Ref. 24), and the Integrated Risk Information System, as well as specific ATSDR toxicological profiles. The risk assessment will involve four components: contaminant identification, exposure assessment, toxicity assessment, and risk characterization. These components are discussed in the subsections below. 5.6.1 Contaminant Identification Contaminants of potential concern are those for which data are of sufficient quality to use in a quantitative risk assessment. Selection will be based on intrinsic toxicological properties, quantities present, and potential and actual migration into critical exposure pathways. 5.6.2 Exposure Assessment Exposure assessment is the determination or estimation (qualitative or quantitative) of the magnitude, frequency, duration, and route of exposure. The numerous variables used to quantify exposure include the following: • Estimation of exposure point concentration. Methods include direct use of environmental media monitoring data and use of environmental fate and transport models to predict contaminant release and migration. • Estimation of contaminant intake/exposure. Human chemical intake is estimated from the concentration of contaminant at exchange boundaries available for absorption, normalized for exposure frequency/duration and body weight. 67 I I I I I I I I I I I I I I I I I I I - • Quantification of pathway-specific exposures. Specific chemical intakes can be calculated for several different exposure scenarios such as ingestion of/dermal contact with contaminants in drinking water, ingestion of/dermal contact with contaminants in soil, or inhalation of airborne contaminants. 5.6.3 Toxicity Assessmentt Toxicity assessment is the determination of the potential for adverse effects resulting from human and biota exposure to contaminants. It may also be used to provide an estimate of the relationship between the extent of exposure to a contaminant and the incidence of disease. To evaluate human exposure to noncarcinogenic contaminants at the Channel Master site, an RfD, when available, will be the toxicity value used. Variables affecting RfDs include exposure route (ingestion, inhalation, or dermal contact), critical effect, and length of exposure (chronic, subchronic, or single event). A slope factor with accompanying weight-of-evidence determination, if available, will comprise the toxicity data used to evaluate potential human chemical carcinogenic risks. The slope factor represents a toxicity value that quantitatively defines the relationship between dose and response. The weight- of-evidence determination is used to determine the likelihood that the agent is a human carcinogen. The slope factor is used to estimate an upper bound probability of an individual developing cancer as a result of a lifetime of exposure to a particular level of a potential carcinogen. 5.6.4 Risk Characterization Risk characterization utilizes information from the exposure assessment and toxicity assessment to assess risks to human health and biota from contaminants at a site. Estimate of risk to biota will be qualitative and quantitative, where possible. Components of the human health risk characterization include the following: • Reviews of toxicity and exposure assessments • Quantification of chemical risks from noncarcinogenic substances. This potential is evaluated by comparing an exposure level over a specified time period with an RFD derived for a similar exposure period. The ratio of exposure to toxicity will generate a hazard quotient that can be used to determine the level of concern. Additional calculations will be made to estimate chemical risks from multiple noncarcinogenic substances. 68 I I I I I I I I I I I I I I I I I I I • Quantification of chemical risks from carcinogenic substances. This is determined from the incremental probability of an individual developing cancer over a lifetime as a result of exposure to the potential carcinogen. Separate risk calculations will be made for low and high estimated probabilities. Additional calculations will be made to estimate chemical risks from multiple carcinogenic substances. • Combining risks across pathways. The need for combining risks will be determined by considering (1) the identification of reasonable exposure pathway combinations and (2) the likelihood that the same individuals would consistently face the reasonable maximum exposure by more than one pathway. If it is reasonable to combine risks across pathways, the cancer risks and the noncancer risks will be combined separately. 5.7 Task 7: Treatability studies Bechtel may recommend certain treatability studies. If these are approved by EPA and funding is provided, bench and/or pilot studies will be conducted to determine the suitability of remedial technologies to site conditions and problems. Technologies that may be suitable to the site will be identified as early as possible to determine whether there is a need to conduct treatability studies to better estimate costs and performance capabilities. If treatability studies are approved, a testing plan identifying the types and goals of the studies, the level of effort needed, a schedule for completion, and the data management guidelines will be submitted to EPA for review and approval. Upon EPA approval, a test facility and any necessary equipment, vendors, and analytical services will be procured. Laboratory and bench-scale treatability studies will be conducted as required to evaluate the effectiveness of remedial technologies and establish engineering criteria (e.g., leachate treatment, recovery techniques, groundwater treatment, compatibility of waste/leachate with site barrier walls, cover and other materials proposed for use in the remedy). A literature survey will be conducted to identify applicable treatability data and collect additional field data, as appropriate, to refine and further assess remedial alternatives. Upon completion of the testing, the results will be evaluated to assess the technologies with respect to the goals identified in the test plan. A report summarizing the testing program and its results will be prepared and presented in the final RI/FS report. 69 I I I 5.8 Task 8: RI Report Monthly reports will be prepared to financial progress of the project. the following items: describe the technical and Status reports will include I • Status of work and the progress to date I I I I I I I I I I I I I I I • Percentage of work completed and the status of the schedule • Difficulties encountered during the month and corrective actions to be taken • Activities in progress • Activities planned for the following month • Any changes in key project personnel • Expenditures (including fee) and direct labor hours expended for the month • CUmulative expenditures (including fee) and cumulative direct hours expended to date, as well as the percent expended of total amounts dedicated for each • Projection of expenditures to project completion, including an explanation of any significant variation from the project budget. Monthly reports will be submitted to EPA as specified in the contract. In addition, the activities conducted and the conclusions drawn during the RI (Tasks 3 through 7) will be documented in an RI report with supporting data and information included in the appendices. A draft RI report will be submitted to EPA for review, and comments received will be incorporated into the final RI report. 5.9 Task 9: Remedial Alternatives Development and screening To provide adequate protection of human health and the environment, a range of distinct hazardous waste management alternatives will be developed to remediate or control any contaminated media (i.e., soil, surface water, groundwater, sediments) remaining at the site, as deemed necessary in the RI. The potential alternatives will encompass, as appropriate, a range of alternatives in which treatment is used to reduce the toxicity, mobility, or volume of wastes but vary in the degree to which long-term management of residuals or untreated waste is required. The potential alternatives will also include one or more alternatives involving containment with little or no treatment as well as a no-action alternative. Alternatives that 70 I I I I I I I I I I I I I I I I I I I involve minimal efforts to reduce potential exposures (e.g., site fencing, deed restrictions) will be presented as "limited action" alternatives. The steps to be conducted in determining the appropriate range of alternatives are described in the subsections below. 5.9.1 Establish Remedial Action Objectives and General Response Actions Based on existing information, site-specific remedial action objectives to protect human health and the environment will be developed. The objectives will specify the contaminant(s) and media of concern, the exposure route(s) and receptor(s), and an acceptable contaminant level or range of levels for each exposure route. Preliminary remediation goals will be established based on readily available information (e.g., RfDs, maximum concentration levels). Bechtel will meet with EPA to discuss the remedial action objectives for the site. As more information is collected during the RI, the remedial action objectives will be refined as appropriate. General response actions will be developed for each medium of interest defining containment, treatment, excavation, pumping, or other actions, singly or in combination to satisfy remedial action objectives. Volumes or areas of media to which general response actions may apply will be identified, taking into account requirements for protectiveness as identified in the remedial action objectives and the chemical and physical characteristics of the site. 5.9.2 Identify and Screen Technologies Based on the developed general response actions, hazardous waste treatment technologies will be identified and screened to ensure that only those technologies applicable to the contaminants present, their physical matrix, and other site characteristics will be considered. This screening will be based primarily on a technology's ability to effectively address the contaminants at the site, but will also take into account a technology's implementability and cost. Representative process options will be selected as appropriate to carry forward into alternative development. The need for treatability testing (as described under Task 7) will be identified for those technologies that are probable candidates for consideration during the detailed analysis. 71 I I I I I I I I I I I I I I I I I I I 5.9.3 Configure and Screen Alternatives The potential technologies and process options will be combined into media-specific or site-wide alternatives. The developed alternatives will be defined with respect to size and configuration of the representative process options: time for remediation: rates of flow or treatment: spatial requirements: distances for disposal: and required permits, imposed limitations, and other factors necessary to evaluate the alternatives. If many distinct, viable options are available and developed, a screening of alternatives will be conducted to limit the number of alternatives that undergo the detailed analysis and to provide consideration of the most promising process options. The alternatives will be screened on a general basis with respect to their effectiveness, implementability, and cost. BEI will meet with EPA to discuss which alternatives will be evaluated in the detailed analysis and to facilitate the identification of action-specific ARARs. s.10 Task 10: Detailed Analysis of Alternatives As outlined by the EPA (Ref. 18), a detailed analysis of alternatives will be conducted which will consist of an individual analysis of each alternative against short-and long- term aspects of three broad criteria: effectiveness, implementability, and cost. All the alternatives shall be evaluated relative to a set of nine criteria. This evaluation strategy is presented in Figure 5-5. Each individual alternative analysis will include: (1) a technical description of the alternative that outlines the waste management strategy involved and identifies the key ARARs associated with the alternative: and (2) a discussion that profiles the performance of that alternative with respect to each of the evaluation criteria. A table will be prepared that summarizes the results of each analysis. After completion of the individual analyses, the alternatives will be compared and contrasted to one another with respect to each of the evaluation criteria. s.11 Task 11: FS Report The results of Tasks 9 and 10 will be presented in a FS report. Supporting data, information, and calculations will be included in appendices to the report. A draft FS report will be submitted to EPA for review, and comments received will be incorporated into the final FS report. Copies of the final report will be distributed to those individuals identified by EPA. 72 ·------------------- _, w 121151U SCREENING .CRITERIA EFFECTIVENESS NINE EVALUATION CRITERIA Overall Protection of Human Health and Environment Compliance with ARARs Long-term Effectiveness and Permanence Reductions In Toxicity, Mobility, and Volume through Treatment Short-term Effectiveness I IMPLEMENTABILITY t-1---•-~I lmplementablllty I COST .. , Cffl SOURCE: OuldancttorCon4JC:lngAlirnlldal ... c Sg 5 • Ind FN!dbaty Stucln Unc11r CERC1.A. U.S. C:1,1io.w1aal Pn:nctlon .-,C,, EP~. Octat,.,.1888. I State Acceptance I Community Acceptance Figure 5-5 ROLE OF CRITERIA DURING REMEDY SELECTION "THRESHOLO-FACTORS "PRIMARY BALANCING• FACTORS "MODIFYING" CONSIDERATIONS RELATIONSHIP OF SCREENING CRITERIA TO THE NINE EVALUATION CRITERIA I I I I I I I I I I I I I I I I I I I - 6.0 HEALTH AND SAFETY Bechtel will develop a Health and Safety Plan (HSP) on the basis of site conditions to protect personnel involved in site activities and the surrounding community. The HSP will include requirements by the Occupational Safety and Health Administration including those found in 29 CFR 1910.120, "Hazardous Waste Operations and Emergency Response". The HSP will also include requirements in EPA Order 1440.2, "Health and Safety Requirements for Employees Engaged in Field Activities"; EPA Order 1440.3, "Respiratory Protection"; EPA's Occupational Health and Safety Manual; and the EPA Standard Operating Safety Guides (Ref. 21). Whenever there is a conflict in regulatory requirements, the stricter standard will be used. The HSP will describe site background and history, medical and training requirements, personal protective equipment, air ~onitoring protocols, decontamination procedures, emergency response, visitors requirements, and standard operating procedures for monitoring worker safety. 74 I I I I I I I I I I I I I I I I I I I .... 7.0 SCHEDULE The schedule for the Channel Master RI/FS is shown in Figure 7-1. EPA review periods were included; however, duration may require adjustment based on EPA workload. No time is included for natural disasters or adverse weather conditions that might affect the field work or for potential responsible parties/ public delays. To ensure that the RI/FS is performed to EPA's satisfaction, BEI recommends scheduling at least five interface meetings with the RPM at the following stages of work: • During the third week of field screening to agree on the locations (of how to determine the locations) for the remaining boreholes and wells. The necessity of budget or schedule revisions would also be determined. If revisions are required, BEI will request a work plan revision. If budget/schedule revisions are not necessary BEI will request a technical directive memo will be requested. • Prior to screening of remedial alternatives, during which BEI will propose a limited list of alternatives for EPA approval. • Halfway through the development of the public health evaluation to reach agreement on appropriate routes of exposure and assumptions for the baseline risk assessment. • At completion of the draft RI report to describe its contents and indicate specific sections and issues that require EPA direction. • At completion of the draft FS report, also to describe its contents and indicate specific sections and issues that require EPA direction. 75 90 90 91 91 92 NBS Start Date Finish Date 1kt Nov Dec Jcin Feb Mar wr Mai .iJll .lJI Auo Sec Oct Nov Dec Jan Feb Mar Allr Mai .lln .lJI Au( Se[ Oct Nov Dec Jan Feb Mar I NIH( ASSIOOT AllIPTANCE 10/11/89 10/11/09 D 2 3 NIH( PUN JI.ENIIIWffil 10 II 09 10 2'.i 89 C 4 NIH( PUN MAil 10 to 89 1 9 90 I I 5 EPA IEVIEV MAil N111( IUN 1 I, 90 4 2'.i 90 .. 6 FINAL NIH( IUN IIDIJlAIIIJi 6 18 90 10 19 90 I 7 PHOJ:CT Pl.Alfl!N6 1.0 11 18 89 10 19 90 I 8 COll!UlITY 111A TIIWS IUIHOOill 1989 2.0 to to 89 10 10 09 D 9 to FIELD INVEST PllllLUOOIT/MOOILIZAIIIJi 3.0 917/90 II 30 90 I II SlllVEY AHO SITE MAP 3.1 11 3/90 12 5 90 12 NASTE CHAil/RES NEllS m m !cl!IIIBIT 3.2 11 4/90 12 7, 90 13 6EO 00 HY0006EO INVEST !Nil HYimlJE 3.3 l1 7 90 I II 91 =] 14 500.f ANALYSIS / VALIDATIIJi 4.0 I 14 91 430 91 15 DATA EVALUATI0/1 5.0 3 18 91 5 28 91 I 16 RI~ ASSESH .. 6.0 5 I 91 7 9 91 I 17 EPA IEETIN6 -RI~ ASffOOT 6 I, 91 6 I 91 D 18 TIEATABILIIY STIDIES 7.0 5 I 91 7 9/91 I 19 RI REPORT o.o 11 10 90 7 29 91 20 EPA IEVIEV MAil RI IOOlT 730 91 0/28 91 -- 2i IEV!i DRAFT RI REPORT 8/29/91 9 27 91 --22 EPA REVIEW FINAL RI IEPDRT 9/30/91 10 29 91 - 23 EPA IEETIN6 RI BRIEFIN6 7/31 91 7/31/91 i 24 FEASIBILITY STlllY 9.10.11 5/29 91 12 4/91 I 25 EPA IEETIN6 -FS BRIEFIN6 12/ 5 91 12 5/91 26 EPA REVIEW lllWl FS 12/ 5 91 I 3 92 - 27 REVI1 MAil FS REPORT I/ 6 92 2 4 92 ~J 2B PROJ:CT COMPI.ETillll 2/ 4 92 2 4 92 ] ARCS IV CHANNEL MASTER SITE RI/FS Proiect: ARCWA3SF Date: 10-18-90 FINAL WORK PLAN SCHEDULE -------------------· I I REFERENCES I I I I I I I I I I I I I I I I I 1. Site inspection report prepared by: Jack Butler, NC Solid and Hazardous Waste Management Branch, 18 May 1987. 2. Clean-up Plan for Channel Master, Division of Avnet, Inc., prepared by Channel Master, 7 July 1987. 3. Phase I Groundwater Quality Evaluation, Channel Master, Division of Avnet, Inc., prepared by Solid and Material Engineers, Inc., November 1986. 4. Draft Clean-up Plan for Channel Master, Division of Avnet, Inc., prepared by Channel Master, January 1987. 5. Report on the Soil Quality, Channel Master, Division of Avnet, Inc., prepared by Soil and Material Engineers, Inc., 16 September 1986. 6. Response to CERCLA and RCRA Information Request, 10 February 1989. 7. Letter from: ATSDR Department of Health and Human Services, to: Mr. Jack Butler, NCDHR, 4 November 1988. 8. Letter from: Coffield, Ungaretti, Harris and Slavin, to: Mr. Bruce Clemens, Bechtel, 26 December 1989. 9. Letter from: Smith, Helms, Mulliss and Moore, to: Mr. Bruce Clemens, Bechtel Environmental, Inc., 22 January 1990. 10. Basic Elements of Ground Water Hydrology with Reference to Conditions in North Carolina. U.S. Geological Survey Water Resources Investigations Open-File Report 80-44. 11. Geology and Groundwater Resources in the Raleigh Area, NC, Groundwater Bulletin No. 15, 1968. 12. ATSDR (Agency for Toxic Substances and Disease Registry), 1989. Channel Master/JFD Electronics {Channel Master) Proposed National Priorities List Site, Oxford, Granville County, North Carolina. ATSDR, CERCLIS No. NCD122263825. 13. North Carolina Atlas, Edited by James w. Clay, Douglas M, Orr, Jr., and Alfred W. Stuart. University of North Carolina Press, Chapel Hill, NC, 1975, 14. Installation of Ground Water Monitor Wells Channel Master Satellite Systems, Inc., prepared by Soil & Material Engineers, Inc., October 7, 1985. 76 I I I I I I I I I I I I I I I I I I I REFERENCES (Cont'd) 15. EPA Superfund Public Health Evaluation Manual, (OSWER Directive 9285.4-1) 16. Dangerous Properties of Industrial Material, Sixth Edition, 1984. 17. EPA Data Quality Objectives for Remediation Response Activities, OSWER Directive 9335.0-713. 18. EPA, 1988. Guidance for Conducting Remedial Investigations and Feasibility Studies Under CERCLA. EPA/G-89/004. 19. EPA (U.S. Environmental Protection Agency), 1986. Engineering Support Branch Standard Operating Procedures and Quality Assurance Manual. Region IV, Environmental Services Division. 20. EPA occupational Health and Safety Manual. 21. EPA Standard Operating Safety Guides (July 1988). 22. EPA, 1989. Risk Assessment Guidance for Superfund, EPA/540/1-89/001. 23. EPA, 1989. Exposure Factors Handbook. EPA/600/8-89/043. 24. EPA, 1988. Superfund Exposure Assessment Manual, EPA/540/1-88/001. 77 I I I I I I I I I I I I I I I I I I I - identified as the area extending south from the former scrap metal trailer parking area, including the area that surrounded the leaking concrete waste oil tank, and the adjacent drainage ditch (Figure 1-1). This information is based on the data collected during the Channel Master groundwater evaluation. TCE, PCE and trans-1,2-DCE were detected in temporary shallow monitoring wells installed on the site. A model of the Channel Master site is provided in (Figure 2-6). 20 ·------------------- "-' ,_. Plllltlll IS CWlwlullN-+ 1 21 1509 ~-.!! _._ ~1•111'!! II of . I Figure 2-6 CHANNEL MASTER SITE MODEL I I I I I I I I I I I I I I I I I I I - 3.0 INITIAL EVALUATION 3.1 site Model A conceptual model for the Channel Master site is provided in Figure 3-1. This model identifies potential sources, release mechanisms, pathways, exposure routes, and receptors for contaminants originating from the Channel Master site. 3.1.1 Nature and Extent of contamination The present nature and extent of contamination at the Channel Master site is not well defined by the existing data. Data collected from the site prior to remediation efforts can be used to determine the types of wastes that may exist at the site; however, the present nature and extent of contamination cannot be established without further investigation. Groundwater Groundwater samples were collected in June, 1986, by Channel Master (Ref. 3). The samples were analyzed for EPA drinking water parameters, water quality parameters, and priority pollutants. voes, primarily in the form of halogenated hydrocarbons, were found to be present in the onsite groundwater at significant concentrations. A summary of the maximum concentration levels of voes found is provided in Table 3-1. Metals were not found to be present at levels of concern, with the exception of chromium (0.08 mg/L) and nickel (0.28 mg/L). Semivolatiles and pesticides were all below detectable levels. The highest concentrations of voe contamination were found in the lagoon area and at surface water discharge points and drainage areas along the southern boundary of the site. The groundwater contamination extends from the scrap trailer loading area towards the former lagoon area and probably moves off the property. The nearest private drinking water well is approximately 2,000 ft southeast of the site (Ref. 12). This well was sampled on February 23, 1987 and no significant organic or inorganic contamination was reported. The current status of groundwater contamination is unknown, however, any existing groundwater contamination would most likely occur in the area of the main building and extend southward toward the lagoon area. 22 I - - - - - --· - - - - - - - - - - - - "' w PRIMARY SOURCES FORMER ON-SITE .... LAGOON A SLUDGE Pml- OII-SITE I CONTIGUOUS PROPERTY PRIMARY RELEASE MECHANISM Percolation lnffltntlon Percolatlon SECONDARY SOURCE SOIL - ~ SECONDARY RELEASE MECHANISM tttt lnffllratlon .. Percolation ~:Jill! ➔ Sloloim11m,1w'81atterer '----------I►~~ POTENTIAL RECEPTOR HUMAN BIOTA EXPOSURE PATHWAY ROUTE Araa Sita Terrestrial Aquatic (Activity) Rnldente Vl11tore INGESTION • • • DERMAL CONTACT • • • INGESTION • • INHALATION • Groun--DERMAL CONTACT • • INGESTION • • • • surtace INHALATION Water Sedlmenta DERMAL • CONTACT • • • INGESTION INHALATION • • • I WIND I I DERMAL CONTACT m~!:":NT ·o·II·· ~ ___________________ E_-_•l_o•-•--------1 .. .Jl-;~;;;;;;;~;;;;;;:CT;:-~-ON:r_;;:_T_..;:;....-11--.--i-----il Figure 3-1 CHANNEL MASTER SITE -CONCEPTUAL MODEL 1 21 1509.2