NCD003200383_20040809_Koppers Co. Inc._FRBCERCLA RA_Remedial Action Monthly Progress Reports 2004-OCR

• August 9, 2004
Ms. Beverly Hudson
Remedial Project Manager
U.S. EPA -Region IV, I Ith Floor
North Site Management Branch
61 Forsyth Street, SW
Atlanta, GA 30303
RE: Monthly Progress Report #135
Remedial Action
Koppers Site -Morrisville, North Carolina
Dear Ms. Hudson:
The RETEC Group, Inc.
3040 William Pitt Way
Pittsburgh, PA 15238-1359
RETEC
[phone] Phone
[phone] Fax
\6),@@ @fi'ivi@ ~
l\ru /'>.UG 1 1 2004 \\LlJ
SUPERfUND SECi\ON
In accordance with the Unilateral Order, and on behalf of Beazer East, Inc. (Beazer), please find
attached four (4) copies of the July 2004 Monthly Progress Report for Remedial Action at the
Koppers Superfund Site in Morrisville, North Carolina. No exceedences occurred during this
event.
• Should you need additional information regarding this progress report, please call Mike Helbling
at [phone] or me at [phone].
•
Sincerely,
The RETEC Group, Inc.
Rita Bauer
Project Geologist
Enclosure
cc: D. Mattison -NC Superfund (2 copies)
J. Garrett -NC Division of Water Quality
M. Matthews -NC Division of Water Quality
P. Kilchenstein -RETEC
H:\Beaz-Ralci\07M-04.doc
L. Faulconer -Wake County
G. Caskey -Enwood Structures
M. Helbling -Beazer
•
•
•
MONTHLY PROGRESS REPORT #135
REMEDIAL ACTION
SITE NAME: Koppers Superfund Site
Beazer East, Inc.
Morrisville, NC
USEPA DOCKET NUMBERS: 93-09-C
PERIOD ENDING: July 31, 2004
1. PROGRESS MADE THIS MONTH
Remedial Action (RA) -HABITAT MITIGATION. No activities were conducted this month.
Remedial Action (RA) -GROUNDWATER TREATMENT. The treatment system operated
without fail from June 23'" to July 22 nd, 2004. On July 27th, when the operator returned for his
routine visit, he noticed that a fuse failed in the main disconnect panel. The operator replaced this
fuse and restarted the system. By comparing the effluent meter reading to the typical flow, the
operator determined that the system was down for approximately 120 hours. System
perfomiance was monitored on a biweekly basis. Approximately 45,270 gallons of groundwater
were extracted, treated in the treatment plant, and discharged between June 23, 2004 and July 27,
2004. System water samples were collected on July 2 and July 13, 2004 in accordance with the
sampling schedule in the O&M manual. Samples were submitted to Severn Trent Laboratories,
Inc. for laboratory analysis. The operations and sampling programs are summarized on the
attached Table I.
2.
3.
4.
5.
6.
7.
Remedial Action (RA) -EFFECTIVENESS MONITORING PROGRAM. No activities
were conducted this month.
Remedial Action (RA) -CORRESPONDENCE. None.
PROBLEMS RESOLVED None.
PROBLEMS ANTICH' A TED None.
UPCOMING EVENTS Continue System O&M.
PERSONNEL CHANGES None.
SUBCONTRACTORS None.
ANALYTICAL DATA Analytical data from system influent and effluent
sampling received during this period are enclosed and are summarized on Table 2 .
1-1:\Bcaz-Ralci\07M-04.doc
Date Systems Cumulative SV-101 SV-101
Check Effluent Flow Sample Sample
(yes/no) (Gallons) (yes/no) Parameters
Penta, 2,4-Dichloro, Phenol,
01106/04 yes 4,321,380 yes Dioxin
01/19/04 Yes 4,342,740 no
02/03/04 Yes 4,368,380 no
02/17/04 ves 4,392,180 no
03/05/04 yes 4,424,090 no
03/25/04 yes 4,463,830 no
04/10/04 yes 4,475,980 no
04/23/04 . ves 4,510,660 no
04/27/04 yes 4,519,420 no
05/03/04 ves 4,532,280 yes Penta,.2,4-Dichloro, Phenol
05/18/04 ves 4,561,880 no
06/02/04 yes 4,589,370 no ' -
06/14/04 yes 4,613,800 no
07/02/04 yes 4,639,860 no
07/13/04 ves 4,656,750 no
Noles:
Sampling point SV-101 is located before the Carbon Units (pretreatment)
Sampling point SV-304 is located between the Carbon Units
Sampling point SV-305 is loctated after the Carbons Units (post-treatment)
OatOS/'2004
F:\PROJECTs.ol62•1Reports\Monlhly\200(11l7M-04 Table bl$ •
Table 1
Groundwater Treatment Operations and
Sampling Program Summary
Koppers Superfund Site
Morrisville, North Carolina
July 2004
Associated SV-304 SV-304
Group Sample Sample
(yes/no) Parameters
Penta, 2,4-Dichloro,
1,2 Yes Phenol
no
no
no
no
no
no
no
no
1 yes Phenol
no
no
no
Associated SV-305 SV-305
Grollp Sample Sample
(yes/no} Parameters
Penta, 2,4-Dichloro, Phenol,
1 yes Dioxin, Chronic Tax
yes Penta, 2,4-Dichloro, Phenol
yes Penta, 2,4-Dichloro, Phenol
yes Penta, 2,4-Dichloro, Phenol
yes Penta, 2,4-Dichloro, Phenol
yes Penta, 2,4-Dichloro, Phenol
yes Penta, 2,4-Dichloro, Phenol
.yes Penta, 2,4-Dichloro, Phenol
yes Chronic Tax
1 · ves Penta, 2,4-Dichloro, Phenol, Dioxin
yes Penta, 2,4-Dichloro, Phenol
yes Penta, 2,4-Dichloro, Phenol
,yes Penta, 2,4-Dichloro, Phenol
no yes , Penta, 2,4-Dichloro, Phenol
no yes
Associated Groups:
SV-101 -Group 1 is penta, phenol, and 2,4-dichlorophenol; Group 2 is dioxin
SV-304 -Group 1 is penta, phenol, and 2.4-dichlorophenol
Penta, 2,4-Dichloro, Phenol
SV-305 -Group 1 is penta. phenol, and 2,4-dichlorophenol; Group 2 is dioxin and Group 3 is chronic toxicity
• •
Associated
Group
1, 2, 3
1
1
1
1
1
1
1
3
1, 2
1
1
1
1 '
1
•
•
•
Table 2
Groundwater Treatment Analytical Data Summary
Koppers Superfund Site -Morrisville, North Carolina
July, 2004
Parameter Date
Sample
Collected
Pentachlorophenol 01/06/04
01/19/04
02/03/04
02/17/04
03/05/04
03/25/04
04/10/04
04/23/04
05/03/04
05/18/04
06/02/04
06/14/04
07/02/04
07/13/04
2.4-Dichlorophenol 01/06/04
01/19/04
02/03/04
02/17/04
03/05/04
03/25/04
04/10/04
04/23/04
05/03/04
05/18/04
06/02/04
06/14/04
07/02/04
07/13/04
Phenol 01/06/04
01/19/04
02/03/04
02/17/04
03/05/04
03/25/04
04/10/04
04/23/04
05/03/04
05/18/04 ·
06/02/04
06/14/04
07/02/04
07/13/04
Chronic T oxicitv 01/06/04
04/27/04
Dioxin (2,3,7,8-TCDDl 01/06/04
05/03/04
Analytical
Sample
Location
SV-101
33
20
<0.60
<0.58
<0.60
<0.58
<2.7
Notes: All results are in micrograms per liter (µg/L) eXCf:lP,I ~.i.oxin. Dioxin data,is in picograms per liter (pg/L) .
SV-101 -Before Carbon Units
*SV-304 -Between Carbon Units
0 SV-305 -After Carbon Units
H:\Projects\03624\Reports\Monthly\07M-04
Sample Sample
Location Location
SV-304• SV-305 ..
<0.99 <1.0
<0.99
<1.0
<0.99
<1.0
<1.0
<1.0
<0.99
<0.97 <0.96
<0.98
<1.0
<1.0
<1.0
<1.0
<0.20 <0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.19 <0.19
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20 <0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.19 <0.19
<0.20
<0.20
<0.20
<0.20
<0.20
Pass
Pass
<2.7
<2.7
•
•
•
ANALYTICAL REPORT
Raleigh, Biweekly NPDES
Lot#, C4G030126
Rita Bauer
The RETEC Group Inc
SEVERN TRENT LABORATORIES, INC.
Veronica Bortot
Project Manager
July 9, 2004
SEVERN
STL Pittsburgh
450 William Pitt Way
Pittsburgh, PA 15238
STL
Tel, 412 820 8380 Fax, 412 820 2080
www.stl-inc.~om
Severn Trent Laboratories, Inc.
STL
NELAC REPORTING:
The format and content of the attached report meets N ELAC standards and guidelines except as
noted in the narrative. The table below presents a summary of the certifications held by STL
Pittsburgh. Our primary accreditation authority for the Nori-potable water and Solid & Hazardous
waste programs is New York State DOH. A more detailed parameter list is available upon request.
Please ask your project manager for this information when required.
The codes utilized for program types are described below:
'rlN Hazardous Waste certification
WV\/ Non-potable Water and/or Wastewater certification
X Laboratory has some fonn of certification under the specific program. Many states certify laboratories for specific parameters or
tests within a category. The information in the table indicates the !ab is certified in a general category of testing. Please contact
the laboratory if parameter specific certificaiion infonnation is required.
•
•
•
•
•
Sample Receiving:
CASE NARRATIVE
THE RETEC GROUP
Raleigh, Biweekly NP0ES
STL Lot# C4G030126
STL Pittsburgh, PA received one sample on July 3, 2004. The cooler was received
within the proper temperature range.
If project specific QC was not required for samples contained in this report and batch QC
was completed on these samples, anomalous results will be discussed below.
GC/MS Semivolatiles SIM:
Since insufficient sample volume was received to perform a matrix spike and matrix
spike duplicate, a Laboratory Control Sample (LCS) and Laboratory Control Duplicate
(LCD) were perfonned. All recoveries were within QC limits .
MEIBODSSUMMARY
C4G030126
ANALYTICAL PREPARATION
PARAMETER METHOD ~M=E~T~H~O~D'---------
8270C (SIM) SW846 8270C SIM SW846 3520C
References:
SW846 11 Test Methods for Evaluating Solid Waste, Physical/Chemical
Methods", Third Edition, November 1986 and its updates.
•
•
•
•
•
•
SAMPLE SUMMARY
C4G030l26
~ SAMPLE# CLIENT SAMPLE ID
GKHVL 001 EFF/SV-305
NOTE{S),
• The analytical results of the samples listed above arc presented on the following pages.
-All calculations are performed before rounding to avoid round-off errors in calculated results.
• Results noted as "ND" were uot detected at or above the slated limit.
• This report must 1101 be reproduced, except in full, without the written approval of 1hc laboratory.
-Results for chc following parameters arc never reported on a dry weight basis: color, corrosivity, density, nashpoim, ignilability, layer.~. odor,
paint filler lest, pH, porosity pn:ssure, reactivity, redox potential, specific gravity, spot tests, solids, solubility, temperature, viscosity, and weight.
SAMPLED
DATE
SAMP
TIME
07/02/04 10,05
STL Pittsburgh
SEVERN
TRENT STL Chain of
Custody Record Severn Trent Laboratories, Inc.
450 William Pitt Way, Bldg. 6
Pittsburgh, PA 15238
STL-4124 (0901)
Project Man.'.~ger p _ ___ P.:~
Telephone Number (Area COde)/Fax Number 97:t ;-J1 (-( '{2-');
Site Contact Lab Contact
-P_r_cy_•_c;L~_aJm;•~:~n~d~L~:~c~•~tio•~riw~~ralp_,J,su.~~~~::::-'1i:h.~--~(~'~/\.)~~C...-.:::·J) ___ j_c_a_r_rie-rT,W-ay_b_"_'_N_um-be_r--~----------~~ J
.C\ ' Contract/Purchase Order/Quote No. : Containers & '-....., v i I) (:iA,;-7.., 7--O> (,,:}., 'f-cJ1 (:, Matrix Preservatives v -~-_,,,_ __ -_____ _,--,------,---t-r-.--.---,---+---,--.----.--,-r--,--\~ -~
! Sample /.0. No.'and Description Date Time ; ! @ "" 5 "bi§ ""u.
(Contafners for each sample fTlay be cOmbined on one fine) ~ t ~ · ~ .::; :: ~ ~ ~ ~ ~ ~
Possible Hazard Identification
0 Non-Hazard D Flammable D Skin Irritant D Poison B I
Sample Disposal .
[L(unknown D Return To Client
Turn Around Time Reqwred
D 24 Hours O 48 Hours D 7Days 0 14 Days D 21 Days ~
Time
(7/)J
2. Relinquished By Time
3. Relinquished By
1
Time
Comments
DISTRIBUTION: WHITE· Returned to Client with Report; CANARY -Stays with rhe Sample; PINK -Field Copy
D Archive For
_,. QC Reqwrements (Specify)
2. Received By
3. Received By
Lab Nflmber
Analysis (Attach list if
more s:,ace is needed)
Chain of Custodv Number
Page
190326
I of \
Special Instructions/
Conditions of Receipt
(A fee may be assessed if samples are retained
Months longer than 1 month)
Date Time
Date Time
Date Time ,-~ 7-oJ •,:, l \ I o 't: 3)
•
•
•
THE RETEC GROUP INC
Client Sample ID: EFF/SV-305
GC/MS Semivolatiles
Lot-Sample# ... : C4G030126-001 Work Order# ... : GKHVLlAA
Date Received .. : 07/03/04
Analysis Date .. : 07/08/04
Analysis Time .. : 13:01
Matrix ......... : WATER
Date Sampled ... : 07/02/04 MS Run# ....... :
Prep Date ...... : 07/06/04
Prep Batch# ... : 4188307
Dilution Factor: 1
Method ......... : SW846 8270C SIM
REPORTING
PARAMETER RESULT LIMIT UNITS
2,4-Dichlorophenol ND 0.20 ug/L
Pentachlorophenol ND 1.0 ug/L
Phenol ND 0.20 ug/L
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Nitrobenzene-dS 65 (28 -ll5)
Terphenyl-dl4 88 (10 -ll5)
2-Fluorobiphenyl 72 (34 -ll5)
2-Fluorophenol 61 (24 -ll5)
Phenol-d5 64 (25 -ll5)
2,4,6-Tribromophenol 105 (33 -ll5)
Client Lot# ... , C4G030126
MB Lot-Sample#, C4G060000-307
Analysis Date .. , 07/08/04
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribrornophenol
NOTE(S),
METHOD BLANK REPORT
GC/MS Semivolatiles
Work Order# ... , GKJ2MlAA
Prep Date ...... , 07/06/04
Prep Batch# ... , 4188307
REPORTING
RESULT LIMIT UNITS
ND 0.20 ug/L
ND 1.0 ug/L
ND 0.20 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
71 (28 -115)
84 (10 -115)
79 ( 34 -115)
73 (24 -115)
64 (25 -115)
91 (33 -ll5)
Calculations arc performed before rounding to avoid round-off errors in calculated results.
•
Matrix ......... : WATER
Analysis Time .. : 11:36
METHOD
SW846 8270C SIM
SW846 8270C SIM
SW846 8270C SIM
•
•
•
•
LABORATORY CONTROL SAMPLE EVALUATION REPORT
GC/MS Semivolatiles
Client Lot# ... , C4G030126 Work Order# ... , GKJ2M1AC-LCS
GKJ2M1AD-LCSD
Analysis Date .. , 07/08/04
Analysis Time .. : 12:04
Matrix ......... : WATER
LCS Lot-Sample#, C4G060000-307
Prep Date ...... , 07/06/04
Prep Batch# ... , 4188307
Dilution Factor: l
PERCENT RECOVERY RPO
PARAMETER RECOVERY LIMITS RPO LIMITS METHOD
Phenol 66 I 10 -131) SW846 8270C SIM
53 (10 -131) 23 I 0-43) SW846 8270C SIM
Pentachlorophenol 90 (10 -140) SW846 8270C SIM
73 (10 -140) 21 (0-56) SW846 8270C SIM
2,4-Dichlorophenol 78 (42 -115) SW846 8270C SIM
71 (42 -115) 9.4 (0-44) SW846 8270C SIM
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Nitrobenzene-dS 65 (28 -115)
59 (28 -115)
Terphenyl-d14 82 (10 -115)
72 (10 -115)
2-Fluorobiphenyl 74 (34 -115)
65 (34 -115)
2-Fluorophenol 64 (24 -115)
60 (24 -115)
Phenol-d5 57 I 25 -115)
57 I 25 -115)
2,4,6-Tribromophenol 93 (33 -115)
80 (33 -115)
NOTE(S),
Calculations are performed before rounding to avoid round-off errors in calculated results .
•
ANALYTICAL REPORT
Raleigh, Biweekly NPDES
Lot#: C4G140374
• Rita Bauer
The RETEC Group Inc
SEVERN TRENT LABORATORIES, INC.
~ Veronica Bortot
Project Manager
July 19, 2004
SE VE'RN
STL Pittsburgh
450 William Pitt Way
Pittsburgh, PA 15238
STL
Tel, 412 820 8380 Fax, 412 820 2080
www.stl-inc.com
Severn Trent Laboratories, Inc.
Sample Receiving:
CASE NARRATIVE
THE RETEC GROUP
Raleigh, Biweekly NPDES
STL Lot# C4Gl40374
STL Pittsburgh, PA received one sample on July 14, 2004. The cooler was received
within the proper temperature range.
If project specific QC was not required for samples contained in this report and batch QC
was completed on these samples, anomalous results will be discussed below.
GC/MS Semivolatiles SIM:
Since insufficient sample volume was received to perform a matrix spike and matrix
spike duplicate, a Laboratory Control Sample (LCS) and Laboratory Control Duplicate
(LCD) were performed. All recoveries were within QC limits.
•
•
•
•
•
METHODS SUMMARY
C4G140374
ANALYTICAL PREPARATION
PARAMETER METHOD ~M~E~T~H~O~Dc._ ___ _
8270C (SIM) SW846 8270C SIM SW846 3520C
References:
SW846 11 Test Methods for Evaluating Solid Wastei. Physical/Chemical
Methods", Third Edition, November 1986 and its updates .
SAMPLE SUMMARY
C4Gl40374
WO# SAMPLE# CLIENT SAMPLE ID
GK34X 001 EFF/SV-305
NOTE (S) :
-The analytical results of the samples listed above are presented on the following pages.
-All calculations are performed before rounding to avoid round-off errors in calculated results.
-Results noted as "ND" were not detected at or above the staled limit.
-This report must not be reproduced, except in full, witJiout the written approval of the laboratory.
-Results for the following parame1ers are ne..,er reported on a dry weight basis: color, corrosivity, density, nashpoinl, ignitability, layers, odor,
paint filter test, pH, porosity pressure, reactivity, redox potential, specific gravity, spot tests, solids, solubility, temperature, viscosi1y, and weight.
•
SAMPLED SAMP
DATE TIME
07/13/04 11:10
•
•
MM -@-◄¥ Chain of
i
KMAi '
Custody Record
STL..,,124 {09011
Chon/ I) O r;~·
Addrcns
R~r A✓(.,, \Oo
C,ty . rel CCV\,co· ~,Z¢=-
(9 f1 '-l:l.
Projott Nama and L~r (SJa
1
ti I ' ;z,..n~ v..r l)_ .. ..A. (/\JGJ
ContmcVPurctwso Order/Ovate No, ' ! B(kz.7-. 03 r.,;:> <-/ -o'i ~
I Sample I.D. No. and Description I. Date (COf!Ipmors fOf oach SRmp/o may t>o combmod on orw !trio)
£FF/fol-loS-?h-s/'-1
Possipio Hazard laonMicatiOII
□ No,,.HJw,rrJ 0 Ftammablo 0 Skin lmtant 0 Poison B , rvm Aroumf limo Raqu1roo
0 24 Hours O 48 Hours 0 14 0.1ys D 21 O.JY,
t. Rofinqv,snod By
• STL • STL Pittsburgh
Severn Trent Laboratories, Inc. 450 William Pitt Way, Bldg. 6
Pittsburgh, PA 15238
Pm;ec1~~r Dal?' ( 's I '-{ Ctw,i1 oi Cuswav N,HlliJiY
1 qo1::>.i;
Tolephono N11moer (Area Codo)(Fa~· Numbor Lab Number' ?16 'J?/-1 "{)).. Page I 01 I
Site Contact Lab C0111DCJ Analysis (Altitch fist ,r
more $""'CV is not;dedj f•t-1 Carrior;WayOill Number . '-. \fl Soecial Instructions/
Containers & is Cbnditions of Rece1j;r Matrix Praservatives N:. ' j ! ,3 § is ~" Q; Time l ! " G ~ ~ £! " " ~ ,J
11,0 ' )( \( x
'
I Sample Disposal
KDISpDSlll By uw
(A :ae muv tJiJ ilSSt/SS(t(i d .',i,lnlf)ies i.lW ff!fdlflC:d
' nlmown O Return To Chen: 0 Arcniva F0t A-lonrns tw4e1 mar, : mon:n; ,, OC Roqut1amon,s (Specify/
0/SfRIBUTION: WHITE· Rtuwned :o Ctiam with Aepotl; CANARY, Stays •'11th tha Sample.-PINK· Fie/a CoD:,'
..
TIIE RETEC GROUP INC
Client Sample ID: EFF/SV-305
GC/MS Semivolatiles
Lot-Sample# ... : C4Gl40374-001 Work Order# ... : GK34XlAA
Date Received .. : 07/14/04
Analysis Date .. : 07/17/04
Analysis Time .. : 18:43
Matrix ......... : WATER
Date Sampled ... : 07/13/04 MS Run# ....... :
Prep Date ...... : 07/16/04
Prep Batch# ... : 4198228
Dilution Factor: 1
Method ......... : SW846 8270C SIM
REPORTING
PARAMETER RESULT LIMIT UNITS
2,4-Dichlorophenol ND 0.20 ug/L
Pentachlorophenol ND 1. 0 ug/L
Phenol ND 0.20 ug/L
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Nitrobenzene-dS 77 (28 -115)
Terphenyl-dl4 105 (10 -115)
2-Fluorobiphenyl 83 (34 -115)
2-Fluorophenol 75 ( 24. -115)
Phenol-d5 68 (25 -115)
2,4,6-Tribrornophenol 113 (33 -115)
•
•
•
• METIIOD BLANK REPORT
GC/MS Semivolatiles
Client Lot# ... : C4Gl40374 Work Order# ... : GKSFFlAA
MB Lot-Sample#: C4Gl60000-228
Analysis Date .. : 07/17/04
Dilution Factor: 1
PARAMETER
Pentachlorophenol
2,4-Dichlorophenol
Phenol
SURROGATE
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
Prep Date ...... : 07/16/04
Prep Batch# ... : 4198228
REPORTING
RESULT LIMIT
ND 1.0
ND 0.20
ND 0.20
PERCENT RECOVERY
RECOVERY LIMITS
.so (28 -ll5)
86 (10 -ll5)
78 (34 -ll5)
74 (24 -ll5)
65 (25 -ll5)
95 (33 -ll5)
•
NOTE{S):
Calcula1ions are perfonned before rounding to avoid round-off errors in calculated results .
•
Matrix ......... : WATER
Analysis Time .. : 16:22
UNITS METHOD
ug/L SW846 8270C SIM
ug/L SW846 8270C SIM
ug/L SW846 8270C SIM
LABORATORY CONTROL SAMPLE EVALUATION REPORT
GC/MS Semivolatiles
Client Lot# ... : C4G140374 Work Order# ... : GK8FF1AC-LCS
GK8FF'1AD-LCSD
Analysis Date .. : 07/17/04
Analysis Time .. : 16:50
Matrix ......... : WATER
LCS Lot-Sample#: C4Gl60000-228
Prep Date ...... : 07/16/04
Prep Batch# ... : 4198228
Dilution Factor: 1
PERCENT RECOVERY RPD
PARAMETER RECOVERY LIMITS RPD LIMITS METHOD
Phenol 71 (10 -131) SW846 8270C SIM
63 (10 .-131) 12 ( 0-43) SW846 8270C SIM
Pentachlorophenol 37 (10 -140) SW846 8270C SIM
30 (10 -140) 22 (0°56) SW846 8270C SIM
2,4-Dichlorophenol 82 (42 -115) SW846 8270C SIM
75 (42 -115) 9.0 (0-44) SW846 8270C SIM
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Nitrobenzene-d5 72 (28 -115)
68 (28 -115)
Terphenyl-d14 93 (10 -115)
85 (10 -115)
2-Fluorobiphenyl 77 (34 -115)
72 (34 -115)
2-Fluorophenol 76 (24 -115)
66 (24 -115)
Phenol-d5 64 (25 -115)
61 (25 -115)
2,4,6-Tribromophenol 90 (33 -115)
83 (33 -115)
NOTE(S):
Cala.Jlations are performed before rounding to avoid round-off errors in calculated results.
•
•
•
•
•
... i
August 10, 2004
Ms. Beverly Hudson
Remedial Project Manager
U.S. EPA -Region IV, I Ith Floor
North Site Management Branch
61 Forsyth Street, SW
Atlanta, GA 30303
RE: Monthly Progress Report #134 (Revised)
Remedial Action
Koppers Site -Morrisville, North Carolina
Dear Ms. Hudson:
The RETEC Group, Inc.
3040 William Pitt Way
Pittsburgh, PA 15238-1359
[phone] Phone
[phone] Fax
www.retec.com
In accordance with the Unilateral Order, and on behalf of Beazer East, Inc. (Beazer), please find
attached four (4) copies of the revised June 2004 Monthly Progress Report for Remedial Action
al the Koppers Superfund Site in Morrisville, North Carolina. This report is being reissued as per
Dave Mattison's comments that the laboratory analytical results were inadvertently omitted from
the Monthly Progress Report # 134. Please accept our apology for any inconvenience this may
have caused.
Should you need additional information regarding this progress report, please call Mike Helbling
at [phone] or me at [phone].
Sincerely,
The RETEC Group, Inc.
q~~
Rita Bauer
Project Geologist
Enclosure
cc: D. Mattison -NC Superfund (2 co;1ies)
J. Garrett -NC Division of Water Quality
M. Matthews -NC Division of Water Quality
P. Kilchenstein -RETEC
H:\Beaz-Ralei\06M-04rev,doc
L. Faulconer -Wake County
G. Caskey -Enwood Structures
M. Helbling -Beazer
•
SITE NAME:
MONTHLY PROGRESS REPORT #134(Revised)
REMEDIAL ACTION
Koppers Superfund Site
Beazer East, Inc.
Morrisville, NC
USEPA DOCKET NUMBERS: 93-09-C
PERIOD ENDING: June 30, 2004
I. PROGRESS MADE THIS MONTH
Remedial Action (RA) -HABITAT MITIGATION. No activities were conducted this month.
Remedial Action (RA)-GROUNDWATER TREATMENT. The treatment system operated
throughout the month without upset. System performance was monitored on a biweekly basis.
Approximately 44,630 gallons of groundwater were extracted, treated in the treatment plant, and
discharged between May 28, 2004 and June 23, 2004. System water samples were collected on
June 2 and June 14, 2004 in accordance with the sampling schedule in the O&M manual.
Samples were submitted to Severn Trent Laboratories, Inc. for laboratory analysis. The
• operations and sampling programs are summarized on the attached Table 1.
Remedial Action (RA) -EFFECTIVENESS MONITORING PROGRAM. No activities
were conducted this month.
Remedial Action (RA) -CORRESPONDENCE. None.
2. PROBLEMS RESOLVED . None.
3. PROBLEMS ANTICIPATED . None.
4. UPCOMING EVENTS Continue System O&M.
5. PERSONNEL CHANGES None.
6. SUBCONTRACTORS None.
7. ANALYTICAL DATA Analytical data from system influent and effluent
sampling received during this period are enclosed and are summarized on Table 2.
H:\Beaz-Ralei\06M-04rev.doc
Doto Systems Cumulative SV-101 SV-101
Check Effluent Aow Sample Sample
(yes/no) (Gallons) (yes/no) Parameters
01/06/04 ves 4,321,380 ves Penta. 2 4-Dichloro, Phenol, Dioxin
01/19/04 ves 4,342,740 no
02/03/04 ves 4,368 380 no
02/17/04 ves 4,392,180 no
03/05/04 ves 4,424,090 no
03/25/04 ves 4.463,830 no
04/10/04 ves 4,475,980 no
04/23/04 ves 4,510,660 no
04/27/04 ves 4,519,420 no
05103/04 ves 4,532,280 ves Penta, 2,4-Dichloro Phenol
05118/04 ves 4,561,880 no
06/02/04 ves 4,589,370 no
06/14/04 ves 4,613,800 no
Notes:
Sampling point SV-101 is located before the Carbon Units (pretreatment)
Sampling point SV-304 is located between the Carbon Units
Sampling point SV-305 is loctated after the Carbons· Units (post-treatment)
"'"''''"' F:\PROJECTS'D36241ReportrMonlty"2004'1)6M-04 Tab'8 1.xll
•
Table 1
Groundwater Treatment Operations and
Sampling Program Summary
Koppers Superfund Site
Morrisville, North Carolina
June 2004
Associated SV-304 SV-304
Group Sample Sample
(yes/no) Parameters
1,2 ves Penta, 2,4-Dichloro, Phenol
no
no
no
no
no
no
no
no
1 yes Penta, 2,4-0ichloro, Phenol
no
no
no
Associated Groups:
Associated SV-305
Group Sample
(yes/no)
1 ves
yes
yes
ves
ves
yes
yes
ves
yes
1 ves
ves
ves
ves
SV-101 -Group 1 is penta, phenol, and 2,4-dich!orophenol; Group 2 is dioxin
SV-304 -Group 1 is penta, phenol, and 2,4-dichtorophenol
•
SV-305
Sample
Parameters
Penta, 2,4-Dichloro, Phenol, Dioxin,
Chronic Tax
Penta, 2,4-Dichloro, Phenol
Penta, 2,4-Dichloro, Phenol
Penta, 2 4-Dichloro, Phenol
Penta, 2,4-Dichtoro, Phenol
Penta, 2,4-Dichloro, Phenol
Penta, 2,4-Dichtoro, Phenol
Penta, 2,4-Dichloro, Phenol
Chronic Tox
Penta, 2,4-Dichloro, Phenol, Dioxin
Penta, 2,4-Oichloro, Phenol
Penta, 2,4-0ich!oro, Phenol
Penta, 2,4-Dichtoro, Phenol
SV-305 -Group 1 is penta, phenol, and 2,4-dichlorophenol; Group 2 is dioxin and Group 3 is chronic toxicity
Associated
Group
1, 2, 3
1
1
1
1
1
1
1
3
1, 2
1
1
1
1 ol 2
•
•
Table 2 •-RETEC
Groundwater Treatment Analytical Data Summary
Koppers Superfund Site -Morrisville, North Carolina
June 2004
Analytical
Parameter Date Sample
Sample Location
Collected SV-101
Pentachloroohenol 01/06/04 33
01/19/04
02/03/04
02/17/04
03/05/04
03/25/04
04/10/04
04/23/04
05/03/04 20
05/18/04
06/02/04
06/14/04
2.4-Dichlorophenol 01/06/04 <0.60
01/19/04
02/03/04
02/17/04
03/05/04
03/25/04
04/10/04
04/23/04
05/03/04 <0.58
05/18/04
06/02/04
06/14/04
Phenol 01/06/04 <0.60
01/19/04
02/03/04
02/17/04
03/05/04
03/25/04
04/10/04
04/23/04
05/03/04 <0.58
05/18/04
06/02/04
06/14/04
Chronic Toxicity 01/06/04
04/27/04
Dioxin (2,3,7,8-TCDD) 01/06/04 <2.7
05/03/04
Notes: All results are In micrograms per liter (µg/L) except dioxin. Dioxin data is in picograms per liter (pg/L).
SV-101 • Before Carbon Units
•sV-304 -Between Carbon Units
**SV-305 -After Carbon Units
08/10/2004
F:\PROJECTSI03624\Reports\Monthly\2004\06M-04 Table 2.xls
Sample
Location
SV-304'
<0.99
<0.97
<0.20
<0.19
<0.20
<0.19
Sample
Location
SV-305"
<1.0
<0.99
<1.0
<0.99
<1.0
<1.0
<1.0
<0.99
<0.96
<0.98
<1.0
<1.0
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.19
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.19
<0.20
<0.20
<0.20
Pass
Pass
<2.7
<2.7
1 of 1
•
•
ANALYTICAL REPORT
Raleigh, Biweekly NPDES
Lot#, C4F030224
Rita Bauer
The RETEC Group Inc
SEVERN TRENT LABORATORIES, INC.
Veronica Bortot
Project Manager
June 9, 2004.
SEVERN
STL Pittsburgh
450 William Pitt Way
Pittsburgh, PA 15238
STL
Tel, 412 820 8380 Fax, 412 820 2080
www.stl-inc.com
Severn Trent Laboratories, Inc.
Sample Receiving:
CASE NARRATIVE
THE RETEC GROUP
Raleigh, Biweekely NPDES
STL Lot # C4F030224
STL Pittsburgh, PA received one sample on June 3, 2004. The cooler was received
within the proper temperature range.
If project specific QC was not required for samples contained in this report and batch QC
was completed on these samples, anomalous results will be discussed below.
GC/MS Semivolatiles SIM:
Since insufficient sample volume was received to perform a matrix spike and matrix
spike duplicate, a Laboratory Control Sample (LCS) and Laboratory Control Duplicate
(LCD) were performed. All recoveries were within QC limits.
The reporting limits were adjusted according to the amount of sample extracted.
•
•
•
•
•
METHODSSUMMARY
C4F030224
ANALYTICAL PREPARATION
~P~AR=AM=ET~E~R'-'-----------------------METHOD ~M=E;T~H~O~D ____ _
8270C (SIM) SWB46 B270C SIM SWB46 3520C
References:
SWB46 "Test Methods for Evaluating Solid Waste, Physical/Chemical
Methods 11 , Third Edition, N.ovember 1986 and its updates .
SAMPLE SUMMARY
C4F030224
WO# SAMPLE# CLIENT SAMPLE ID
GHJHS 001 EFF/SV305
NOTE (S):
-The analy1ical results of the samples listed above are presented on the following pages.
-All calculations are performed before rounding to avoid round-off errors in calculated results.
• Results noted as "ND" were not detected at or above the stated limit.
-This report must not be reproduced, except in full, without 1he wriuen approval of the laboratory.
-Results for the following parameters are never reported on a dry weight basis: color, corrosivity, density, flashpoint, ignitability, layers, odor,
paint filter test. pH, porosity pressure, reactivity, redox potential, specific gravity, spot teslS, solids, solubility, 1emperature, viscosity, and weight.
SAMPLED
DATE
•
SAMP
TIME
06/02/04 10:20
•
•
• Chain of • · S E·V ~RN·
. TRENT STL • STL Pittsburgh
Custody Record Severn Trent Laboratories, Inc. 450 William Pitt Way, Bldg. 6
Pittsburgh, PA 15238
STL-412-4 (0901)
Client R,-~ Project Mi"1ger Datr f Chain of Custodv Number -~ C,j -;),j ✓ 1qnr'P d :,,..) ;-<. .,;+..,..__. ·-' .I./ .. Address Eo-lw Avl
. Telephone Number (Area Code}/Fax Number Lab'Nurrlber ( 3uo q"1"1-~11-lll~}. Page of L
City ~c.o(IJ I State I Zip Code Site Contact Lab Contact Analysis {Attach fist if ~~ .,;{'7'{;) more space is needed)
Project Name and Location (State} /;Jc Carrier/Waybill Number ~ ',I. 'Rt;~<.. 1---ol&;)t.f 'O'i~ } Special Instructions/ Contract/Purchase Order/Quote No. , ,::; J Conditions of Rer.eipt Containers & ...__, Matrix Preservatives V
Sample I.D. No. and Description l l g X ;,x ~
Date Time ,; ~ i G 0 ,o ~ (Containers for each sample may bo combined on one line) .• • • ~ i ~~ ' < '" X
tl!-P I ~ \J --:,,:t:; (p\~1../ I 0;2,0 i t f-l , ' .
Possible Hazard Identification I Sample Disposal
~sp~sal By Lab
(A fee may be assessed if samples are retained D Non-Hazard D Flammable D Skin Irritant D PoisonB mnknown O Return To Client D Archive For Months longer than I month)
Tum Around TTme Requ!red
5-rfl ,~C Re(Juirements (Specify)
□·24 Hours 0 48Hours 0 7Days □ 14 Day~ D 21 Days !)(other
1. Relinquished By I\ A \L .-\ ~ ltT,\c.\ I 1:;D-0 I. Rec~lBy (,f
1
Date
1
Time
2. Relinquished By I Dar• I
1
Time 2. RBCf!iVed By
1
Date
1
T1111e
. n
3. Relinquished By
1
Date
1
Time 3.Red~ /!J-j Date
1
Timr
-·----Oi··t:•3 ··o L/ OY c( }
Comments I
DISTRIBUTION: WHITE -Returned to Client with Report: CANARY -Stays with the Sample; PINK -Field Coiw
Lot-Sample# ... : C4F030224-001
Date Sampled ... : 06/02/04
Prep Date ...... : 06/04/04
Prep Batch# ... : 4156201
Dilution Factor: 1.02
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-dS
Terphenyl-d14
2-Fluorobiphenyl
2-Fluorophenol
Phenol-dS
2,4,6-Tribromophenol
THE RETEC GROUP INC
Client.Sample ID: EFF/SV305
GC/MS Semivolatiles
Work O.rder # ... : GHJH51AA
Date Received .. : 06/03/04
Analysis Date .. : 06/08/04
Analysis Time .. : 12,16
Matrix ......... : WATER
MS Run# ....... :
Method ......... : SW846 8270C SIM
REPORTING
RESULT LIMIT UNITS
ND 0.20 ug/L
ND 1. 0 ug/L
ND 0.20 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
78 (28 -115)
82 (10 -115)
75 (34 -115)
70 (24 -115)
83 (25 -115)
92 (33 -115)
•
•
•
•
Client Lot# ... : C4F030224
MB Lot-Sample#: C4F040000-201
Analysis Date .. : 06/08/04
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
METHOD BLANK REPORT
GC/MS Semivolatiles
Work Order# ... : GHLENlAA
Prep Date ...... : 06/04/04
Prep Batch# ... : 4156201
REPORTING
RESULT LIMIT
ND 0.20
ND 1.0
ND 0.20
PERCENT RECOVERY
RECOVERY LIMITS
76 (28 -115)
86 (10 -115)
73 (34 -115)
67 (24 -115)
77 (25 -115)
96 (33 -115)
•
NOTE(S):
Calculations are performed before rounding to avoid round-off errors in calculated results .
•
Matrix ......... : WATER
Analysis Time .. : 10:51
UNITS METHOD
ug/L SW846 8270C SIM
ug/L SW846 8270C SIM
ug/L SW846 8270C SIM
LABORATORY CONTROL SAMPLE EVALUATION REPORT
GC/MS Semivolatiles
Client Lot# ... : C4F030224 Work Order# ... : GHLENlAC-LCS
GHLENlAD-LCSD
Analysis Date .. : 06/08/04
Analysis Time .. : 11:19
Matrix ......... : WATER
LCS Lot-Sample#: C4F040000-201
Prep Date ...... : 06/04/04
Prep Batch# ... : 4156201
Dilution Factor: 1
PARAMETER
Phenol
Pentachlorophenol
2,4-Dichlorophenol
SURROGATE
Nitrobenzene-d5
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
NOTE(S):
PERCENT
RECOVERY
84
83
123
121
77
76
RECOVERY
LIMITS
(10 -131)
(10 -131)
(10 -140)
(10 -140)
(42 -115)
(42 -115)
PERCENT
RECOVERY
73
73
77
74
65
67
66
66
80
80
90
88
Calculations arc performed before rounding co avoid round-off errors in calculated results.
RPD
RPD LIMITS METHOD
SW846 8270C SIM
1. 7 (0-43) SW846 8270C SIM
SW846 8270C SIM
1. 8 (0-56) SW846 8270C SIM
SW846 8270C SIM
1. 7 (0-44) SW846 8270C SIM
RECOVERY
LIMITS
(28 -115)
(28 -115)
(10 -115)
(10 -115)
(34 -115)
(34 -115)
(24 -115)
(24 -115)
(25 -115)
(25 -115)
(33 -115)
(33 -115)
•
•
•
•
ANALYTICAL REPORT
Raleigh, Biweekly NPDES
Lot#: C4Fl70199
• Rita Bauer
The RETEC Group Inc
SEVERN TRENT LABORATORIES, INC.
~. Veronica Bertot
Project Manager
• June 23, 2004
• ' •'-I, ':. • I f " ' •• ~ ' ,r•• • • , leaders in Envirorlmental;Testing'1.ill\.} '-~•. < 1~. '<( • ....... ,,,.,.,,,_
SE V E•R N
STL Pittsburgh
450 William Pitt Way
Pittsburgh, PA 15238
STL
Tel, 412 820 8380 Fax, 412 820 2080
www.stl-inc.com
Severn Trent Laboratories, Inc.
Sample Receiving:
CASE NARRATIVE
THE RETEC GROUP
Raleigh, Biweekely NPDES
STL Lot# C4Fl 70199
STL Pittsburgh, PA received one sample on June 17, 2004. The cooler was received
within the proper temperature range.
If project specific QC was not required for samples contained in this report and batch QC
was completed on these samples, anomalous results will be discussed below.
GC/MS Semivolatiles SIM:
Since insufficient sample volume was received to perform a matrix spike and matrix
spike duplicate, a Laboratory Control Sample (LCS) and Laboratory Control Duplicate
(LCD) were performed. All recoveries were within QC limits.
The reporting limits were adjusted according to the amount of sample extracted.
,
•
•
•
•
•
•
· METHODS SUMMARY
C4F170199
ANALYTICAL PREPARATION
·~P~ARAM==E~T~E~R~---~-----------------METHOD ~M~E~T~H~O~D ____ _
8270C (SIM) SW846 8270C SIM SW846 3520C
References:
SW846 "Test Methods for Evaluating Solid Waste, Physical/Chemical
Methods", Third Edition,_November 1986 and its updates .
SAMPLE SUMMARY
C4F170199
WO# SAMPLE# CLIENT SAMPLE ID
GJGT2 001 EFF.SV-305
NOTE(S)
-The analytical results of the samples listed above arc presented on the following pages.
• All calculations are perfonned before rounding to avoid round-off errors in calculated results.
-Results nolcd as "ND" were not detected at or above the stated limit.
· . • This repon must not be reproduced, except in full, wiUmut the written approval of the laboratory.
-Results for the following parameters are never reported on a dry weight basis: color, corrosivity; density, flashpoint, ignitability, layers, odor,
paint filler test, pH, porosity pressure, reactivity, redox potential, specific gravity, spot tests, solids, solubility, temperature, viscosity, and weight.
SAMPLED
DATE
• SAMP
TIME
06/14/04 15:00
•
•
RELINQUISHED BY: JSIGNATUREJ
EMPT'{ CONT6_iN!:RS
RECEIVED BY: JSIGNA1UREI
ANALYSIS REQUEST AND CHAIN OF CUSTODY RECORD
STL
PROJECT NO.
P.O. NUMBER
DATE TIME
DATE TIME
PROJECT LOCATION
(STATE) (V
CONTRACT NO.
MATRIX
TYPE
RELINQUISHED BY: !SIGNATURE)
Serial Number 2 7 7 71
0 STL Savannah
5102 laRoche Avenue
Savannah, GA 31404 ¥ Alternate Laboratory Name/Location
REQUIRED ANALYSIS
NUMBER OF CONTAINERS SUBMITTED
Website: www.stl-inc.com
Phone: [phone]
Fax: [phone]
Phone:
Fax:
PAGE I
DAT TIME RELINQUISHED BY: JSIGNATUREI DATE
ll'JO
DATE TIME DATE
1 OF
i
REMARKS
TIME
TIME " ot-0-a~ 09: i,[lj
~TIP'JA(lt;Ofltl'lffl'H
THE RETEC GROUP INC
Client Sample·ID: EFF.SV-305
GC/MS Semivolatiles
.Lot-Sample# ... : C4Fl70199-001 Work Order# ... : GJGT21AA
Date Received .. : 06/17/04
Analysis Date .. : 06/22/04
Analysis Time .. : 13:03
Matrix ......... : WATER
Date Sampled ... : 06/14/04 MS Run# ....... :
Prep Date ...... : 06/18/04
Prep Batch# ... : 4170147
Dilution Factor: 1.02
Method ......... : SW846 8270C SIM
REPORTING
PARAMETER RESULT LIMIT UNITS
2,4-Dichlorophenol ND 0.20 ug/L
Pentachlorophenol ND 1.0 ug/L
Phenol ND 0.20 ug/L
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Nitrobenzene-dS 77 (28 -115)
Terphenyl-dl4 91 (10 -115)
2-Fluorobiphenyl 76 (34 -115)
2-Fluorophenol 73 (24 -115)
Phenol-dS 83 (25 -115)
2,4,6-Tribromophenol 97 (33 -115)
•
•
•
Client Lot# ... : C4Fl70199
MB Lot-Sample#: C4Fl80000-147
Analysis Date .. : 06/22/04
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
METHOD BLANK REPORT
GC/MS Semivolatiles
Work Order# ... : GJJ7NlAA
Prep Date ...... :. 06/18/04
Prep Batch# ... : 4170147
REPORTING
RESULT LIMIT
ND 0.20
ND 1.0
ND 0.20
PERCENT RECOVERY
RECOVERY LIMITS
80 (28 -115)
89 (10 -115)
79 (34 -115)
70 (24 -115)
86 (25 -115)
104 (33 -ll5)
NOTE (S) :
• Calculations are performed before rounding to avoid round-off errors in calculated rcsul.15.
Matrix ......... : WATER
Analysis Time .. : 09:44
UNITS METHOD
ug/L SW846 8270C SIM
ug/L SW846 8270C SIM
ug/L SW846 8270C SIM
LABORATORY CONTROL SAMPLE EVALUATION REPORT
GC/MS Semivolatiles
Client Lot# ... : C4Fl70199 Work Order# ... : GJJ7NlAC-LCS
GJJ7NlAD-LCSD
Analysis Date .. : 06/22/04
Analysis Time .. : 10:13
Matrix ......... : WATER
LCS Lot-Sample#: C4Fl80000-147
Prep Date ...... : 06/18/04
Prep Batch# ... : 4170147
Dilution Factor: 1
PARAMETER
Phenol
Pentachlorophenol
2,4-Dichlorophenol
SURROGATE
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
NOTE (S) :
PERCENT RECOVERY
RECOVERY LIMITS
75 (10 -131)
77 (10 -131)
58 (10 -140)
58 (10 -140)
76 (42 -115)
74 (42 -115)
PERCENT
RECOVERY
75
76
85
Bl
77
73
74
68
77
74
102
95
Calculations are perfonned b_efore ro\lnding to avoid round-off errors in calculated results.
RPD
RPD LIMITS METHOD
SW846 8270C SIM
3.6 ( 0-43) SWB46 8270C SIM
SW846 8270C SIM
0.030 ( 0-56) SW846 8270C SIM
SW846 8270C SIM
3.3 (0-44) SWB46 8270C SIM
RECOVERY
LIMITS
(28 -115)
(28 -115)
(10 -115)
(10 -115)
(34 -115)
(34 -115)
(24 -115)
(24 -115)
(25 -115)
(25 -115)
(33 -115)
(33 -115)
•
•
•
•
&irA
NCDENR
l~orth Carolina Department of Environment and l~atural Resources
Division of Waste Management
August 2, 2004
Ms. Beverly Hudson
Remedial Project Manager/Superfund Branch
Waste Management Division
US EPA Region JV
61 Forsyth Street, 11 th Floor
Atlanta, Georgia 30303
RE: Monthly Progress Report # 134
Remedial Action-] une 2004
Former Koppers Industries, Inc. l\'PL Site
Morrisville, Wake County, North Carolina
Dear Ms. Hudson:
Mi:hcJel r= t:r~sl:~y. Grwerno;
WilliaiTi 1:;. ?-0:.s Jr . Se::r~i~i·y
The Superfund Section of the North Carolina Department of Environment and Natural Resources
(NC DENR) has received and reviewed the Monthly Progress Report #134 -June 2004 for the
Former Koppers Industries, Inc. National Priority List (]\'PL) Site. The Superfund Section offers
the following comment.
Monthly Progress Report #134 (June 2004)
Former Koppers Industries, Inc. NPL Site
1. The laboratory analytical results were inadvertently omitted from Monthly Progress
Report #134 (June 2004). Please correct this oversight.
The Superfund Section of the NC DEl\1R appreciates the opportunity to comment on this
document. If you have any questions or comments, please feel free to contact me at (919) 733-
2801, extension 349.
~erely,
;)_J£ ;/~H~~
David B. Mattison, CHMM
Environmental Engineer
NC Superfund Section
Attachment
cc: Matt Matthews -NC Div. of Water Quality
Judy Garrett -i;~s9-,/~ii g~~lJ~5e~~t1~?.~ieigh l✓ort:, CarDlina 27,3?9-1643
l
•
•
•
(
July 8, 2004
Ms. Beverly Hudson
Remedial Project Manager
U.S. EPA-Region IV, I Ith Floor
Nm1h Site Management Branch
61 Forsyth Street, SW
Atlanta, GA 30303
RE: Monthly Progress Report #134
Remedial Action
Koppers Site -Morrisville, North Carolina
Dear Ms. Hudson:
In accordance with the Unilateral Order, and on behalf of Beazer East, Inc. (Beazer), please find
attached four ( 4) copies of the June 2004 Monthly Progress Report for Remedial Action at_ the
Koppers Supcrfund Site in Morrisville, North Carolina. No exceedcnces occurred during this
event .
Should you need additional information.regarding this progress report, please call Mike Helbling
at [phone] or me at [phone].
Sincerely,
The RETEC Group, Inc.
~~4or
Rita Bauer
Project Geologist
Enclosure
cc: D. Mattison -NC Supcrfund (2 copies)
J. Garrett -NC Division of Water Quality
M. Matthews -NC Division of Water Quality
I'. Kilchenstcin -RETEC
C:\IX>CU ME~ I \K GA LLl-1 \LOCALS~ I \Tcmp\nowsU I E074\06M-04.doc
L. Faulconer -Wake County
G. Caskey -Enwood Structures
M. Helbling-Beazer
•
•
MONTHLY PROGRESS REPORT #134
REMEDIAL ACTION
SITE NAME: Koppers Supcrfund Site
Beazer East, Inc.
Morrisville, NC
USEPA DOCKET NUMBERS: 93-09-C
PERIOD ENDING: June 30, 2004
I. PROGRESS MADE THIS MONTH
Remedial Action (RA) -HABITAT MITIGATION. No activities were conducted this month.
Remedial Action (RA) -GROUNDWATER TREATMENT. The treatment system operated
throughout the month without upset. System perfomrnnce was monitored on a biweekly basis.
Approximately 44,630 gallons of groundwater were extracted, treated in the treatment plant, and
discharged between May 28, 2004 and June 23, 2004. System water samples were collected on
June 2 and June 14, 2004 in accordance with the sampling schedule in the O&M manual.
Samples were submitted to Severn Trent Laboratories, Inc. for laboratory analysis. The
operations and sampling programs arc summarized on the attached Table I.
2.
3.
4.
5.
6.
Remedial Action (RA) -EFFECTIVENESS MONITORING PROGRAM. No activities
were conducted this month.
Remedial Action (RA) -CORRESPONDENCE. None.
PROBLEMS RESOLVED
PROBLEMS ANTICIPATED
UPCOMING EVENTS
PERSONNEL CHANGES
SUBCONTRACTORS
None.
None.
Continue System O&M.
None.
None.
7. ANALYTICAL DATA Analytical data from system influent and effluent
sampling received during this period arc enclosed and are summarized on Table 2.
C:\DOCU ME~ I \KGA LLl-1 \LOCALS~ I \Tcmp\notcsB I E074\06M-04.doc
,'
•
•
MONTHLY PROGRESS REPORT #134
REMEDIAL ACTION
SITE NAME: Koppers Supcrfund Site
Beazer East, Inc.
Morrisville, NC
USEPA DOCKET NUMBERS: 93-09-C
PERIOD l~NDING: June 30, 2004
I. PROGRESS MADE TIIIS MONTH
Remedial Action (RA) -/JAB/TAT MITIGATION. No activities were conducted this month.
Remedial Action (RA) -GROUNDWATER TREATMENT The treatment system operated
throughout the month without upset. System performance was monitored on a biweekly basis.
Approximately 44,630 gallons of groundwater were extracted, treated in the treatment plant, and
discharged between May 28, 2004 and June 23, 2004. System water samples were collected on
June 2 and June 14, 2004 in accordance with the sampling schedule in the O&M manual.
Samples were submitted to Severn Trent Laboratories, Inc. for laboratory analysis. The
operations and sampling programs arc summarized on the attached Table I.
2.
3.
4.
s.
6.
Rcmcdial Action (RA) -EFFECTIVENESS MONITORING PROGRAM. No activitics
were conducted this month.
Remedial Action (RA) -CORRESPONDENCE. None.
PROBLEMS RESOLVED
PROBLEMS ANTICIPATED
UPCOMING EVENTS
PERSONNEL CHANGES
SUBCONTRACl'ORS
None.
None.
Continue System O&M.
None.
None.
7. ANALYTICAL DATA Analytical data from system influent and effluent
sampling received during this period arc enclosed and arc summarized on Table 2.
Date Systems Cumulative SV-101 sv-101
Check EHluent Flow Sample Sample
Ives/no' tGallons1 lues/nol Parameters
01/06/04 ves 4 321,380 ves Penta 2 4-Dichloro Phenol Dioxin
01/19/04 ,es 4,342.740 no
02/03/04 ves 4.368.380 no
02/17/04 ves 4.392.180 no
03105/04 ves 4,424.090 no
03/25/04 <es 4.463.830 no
04/10/04 ves 4 475 980 no
04/23/04 ves 4 510 660 no
04127/04 ves 4 519.420 no
05/03/04 ves 4.532 280 ves Penta. 2 4•Dichlorc. Phenol
05/18/04 ves 4561.880 no
06/02/04 ves 4 589 370 no
06/14/04 ves 4613.800 no
1191200-:
F.•P:.QJECTS\0362~\R•pc~o\Montt,P),'..200~\0~M-C4 T•ble \ ,Is
•
Table 1
Groundwater Treatment Operations and
Sampling Program Summary
Koppers Superfund Site
Morrisville, North Carolina
June 2004
Associated SV-l04 SV-304
Group Sample Sample
Ives/no) Parameters
1.2 ves Penta 2.4-Dichloro. Phenol
co
no
no
no
no
no
no
no
1 ves Penta. 2.4•Dich!oro. Phenol
no
no
no
Associated
Group
1
1
•
.RETEC
SV-305 SV-305 Associ.ited
Sample Sample Group
fveslnol Parameters
Penta. 2,4-Dichloro, Phenol, Dioxin,
ves Chronic Tex 1. 2 3
ves Penta 2 4-Dichloro Phenol 1
ves Penta 2 4-Dichloro Phenol 1
ves Penta. 2 4-Dichloro Phenol 1
ves Penta. 2 4.Qichloro Phenol 1
ves Penta. 2 4•Dichloro. Phenol 1
ves Penta 2 4•Dichloro Phenol 1
ves Penta 2 4•Dichloro Phenol 1
,es Chronic Tex 3
ves Penta. 2 4-Dichloro Phenol Dioxin 1 2
,es Penta. 2.4-Dichloro Phenol 1
,es Penta. 2 4-Oichloro Phenol 1
ves Penta 2 4•Dichloro Phenol 1
1 of 1
•
•
•
Table 2
Groundwater Treatment Analytical Data Summary
Koppers Superfund Site -Morrisville, North Carolina
June 2004
Analytical
Parameter Date Sample Sample
Sample Location Location
Collected SV-101 SV-304•
Pentachlorophenol 01/06/04 33 <0.99
01/19/04
02/03/04
02/17/04
03/05/04
03/25/04
04/10/04
04/23/04
05/03/04 20 <0.97
05/18/04
06/02/04
06/14/04
2.4-Dichlorophenol 01/06/04 <0.60 <0.20
01/19/04
02/03/04
02/17/04
03/05/04
03/25/04
04/10/04
04/23/04
. 05/03/04 <0.58 <0.19
05118/04
06/02/04
06/14/04
Phenol 01106/04 <0.60 <0.20
01/19/04
02/03/04
02/17/04
03/05/04
03/25/04
04/10/04
04/23/04
05/03/04 <0.58 <0.19
05/18/04
06/02/04
06/14/04
Chronic Toxicity 01/06/04
04/27/04
Dioxin (2,3,7,8-TCDD) 01/06/04 <2.7
05/03/04
Notes: All results are in micrograms per liter (pg/L) except dioxin. Dioxin dala is in picograms per liter (pg/L).
SV-101 • Before Carbon Units
'SV-304 • Between Carbon Units
"'SV-305 -After Carbon Units
7/9/2004
F:\PROJECTS\03624\Reporls\Monlh1y\2004\04M-04 Table 2.xls
Sample
Location
SV-305 ..
<1.0
<0.99
<1.0
<0.99
<1.0
<1.0
<1.0
<0.99
<0.96
<0.98
<1.0
<1.0
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20 . -;
<0.20
<0.20
<0.19
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.19
<0.20
<0.20
<0.20
Pass
Pass
<2.7
<2.7
1 of 1
•
•
0
June I 0, 2004
The RETEC Group, Inc.
300 Baker Avenue, Suite 302
Concord, MA 01742
6RETE(
[phone] Phone
[phone] Fax
www.retec.com
Ms. Beverly Hudson
Remedial Project Manager
U.S. EPA -Region IV, I Ith Floor
North Site Management Branch
6 I Forsyth Street, SW
Atlanta, GA 30303 ~[J~~:~!]~
SUPERFUND SECTION RE: Monthly Progress Report #133
Remedial Action
Koppers Site -Morrisville, North Carolina
Dear Ms. Hudson:
In accordance with the Unilateral Order, and on behalf of Beazer East, Inc. (Beazer), please find
attached four (4) copies of the May 2004 Monthly Progress Report for Remedial Action at the
Koppers Superfund Site in Morrisville, North Carolina. No exceedences occurred during this
event.
Should you need additional information regarding this progress report, please call Mike Helbling
at [phone] or me at [phone].
Sincerely,
The RETEC Group, Inc.
Rita Bauer
Project Geologist
Enclosure
cc: D. Mattison -NC Superfund (2 copies)
J. Garrett -NC Division of Water Quality
M. Matthews -NC Division of Water Quality
P. Kilchenstein -RETEC
F :\PR OJ E CTS\O 3 624 \Reports\M onth ly\2 004 \0 5 M •04. doc
L. Faulconer -Wake County
G. Caskey -Enwood Structures
M. Helbling -Beazer ·
•
•
MONTHLY PROGRESS REPORT #133
REMEDIAL ACTION
SITE NAME: Koppers Superfund Site
Beazer East, Inc.
Morrisville, NC
USEPA DOCKET NUMBERS: 93-09-C
PERIOD ENDING: May 31, 2004
1. PROGRESS MADE THIS MONTH
Remedial Action (RA) -HABITAT MITIGATION. No activities were conducted this month.
Remedial Action (RA) -GROUNDWATER TREATMENT. The treatment system operated
throughout the month without upset. System performance was monitored on a biweekly basis.
Approximately 61,220 gallons of groundwater were extracted, treated in the treatment plant, and
discharged between May 1, 2004 and May 31, 2004. System water samples were collected on
May 3 and May 18, 2004 in accordance with the sampling schedule in the O&M manual.
Samples were submitted to Severn Trent Laboratories, Inc. for laboratory analysis. The
operations and sampling programs are summarized on the attached Table 1.
2.
3.
4.
5.
6.
Remedial Action (RA) -EFFECTIVENESS MONITORING PROGRAM. No activities
were conducted this month.
Remedial Action (RA) -CORRESPONDENCE. None.
PROBLEMS RESOLVED
PROBLEMS ANTICIPATED
UPCOMING EVENTS
PERSONNEL CHANGES
SUBCONTRACTORS
None.
None.
Continue System O&M.
None.
None.
7. ANALYTICAL DATA Analytical data from system influent and effluent
sampling received during this period are enclosed and are summarized on Table 2.
F :\PR OJ ECTS\O 3 62 4\R epons\Mon th ly\2004 \05 M-04 .doc
•
Date Systems Cumulative SV-101 SV-101
Check Effluent Flow Sample Sample
(yesJnol 1Gallonsl fyes/noi Parameters
01/06/04 ves 4 321 380 ves Penta 2,4-0ichloro Phenol
01/19/04 ves 4 342 740 no
02/03/04 ves 4 368 380 no
02/17/04 ves 4 392 180 no
03/05/04 ves 4 424 090 no
03/25/04 ves 4 463 830 no
04110104 ves 4 475 980 no
04/23/04 ves 4 510 660 no
04/27/04 ves 4519420 no
05/03/04 ves 4 532 280 ves Penta 2 4-Dichloro Phenol
05/18/04 ves 4 561 880 no
Notes:
Sampling point SV-101 is located before the Carbon Units (pretreatment)
Sampling point SV-304 is located between the Carbon Units
Sampling point SV-305 is loctated after the Carbons Units (post-treatment)
"'"""" F.'PROJECT5'03624\Rep0<ts\Monlhly\2004\0SM-04 T atile 1.xls
Dioxin
Table 1
Groundwater Treatment Operations and
Sampling Program Summary
Koppers Superfund Site
Morrisville, North Carolina
May 2004
Associated SV-304 SV-304
Group Sample Sample
1vesJno) Parameters
1 2 •es Penta 2 4-Dichloro Phenol
no
no
no
no
no
no
no
no
1 ves Penta 2 4-Dichloro Phenol
no
Associated Groups:
Associated
Group
. 1
1
•
.RETEC
SV-305 SV-305 Associated
Sample Sample Group
(yes/no) Parameters
Penta, 2,4-Dichloro, Phenol, Dioxin,
ves Chronic Tox 1, 2 3
ves Penta 2.4-Dichloro Phenol 1
ves Penta 2,4-Dlchloro, Phenol 1
ves Penta 2.4-Dichloro, Phenol 1
ves Penta 2,4-Dichloro, Phenol 1
ves Penta, 2,4-0ichloro, Phenol 1
ves Penta 2 4-Dichtoro, Phenol 1
ves Penta 2 4-Dichloro, Phenol 1
ves ChronicTox 3
ves Penta 2,4-Dichloro Phenol Dioxin 1 2
ves Penta 2 4-Dichloro, Phenol 1
SV-101 -Group 1 is penta, phenol, and 2,4-dichlorophenol; Group 2 is dioxin
SV-304 -Group 1 is penta, phenol, and 2,4-dichlorophenot
SV-305 -Group 1 is penta, phenol, and 2,4-dichlorophenol; Group 2 is dioxin and Group 3 is chronic toxicity
1 of 1
.
•
•
Table 2
Groundwater Treatment Analytical Data Summary
Koppers Superfund Site -Morrisville, North Carolina
May 2004
Analytical
Parameter Date Sample Sample
Sample Location Location
Collected SV-101
Pentachloronhenol 01/06/04 33
01/19/04
02/03/04
02/17/04
03/05/04
03/25/04
04/10/04
04/23/04
05/03/04 20
05/18/04
2.4-Dichloronhenol 01/06/04 <0.60
01/19/04
02/03/04
02/17/04
03/05/04
03/25/04
04/10/04
04/23/04
05/03/04 <0.58
05/18/04
Phenol 01/06/04 <0.60
01/19/04
02/03/04
02/17/04
03/05/04
03/25/04
04/10/04
04/23/04
05/03/04 <0.58
05/18/04
Chronic Toxicitv 01/06/04
04/27/04
Dioxin (2,3,7,8-TCDD) 01/06/04 <2.7
05/03/04
Notes: All results are tn micrograms per hter (µg/L) except dioxin. Dioxin data is in picograms per liter (pg/L).
SV-101 -Before Carbon Units
*SV-304 -Between Carbon Units
**SV-305 -After Carbon Units
6/10/2004
F:\PROJECTS\03624\Reports\Monthly\2004\0SM-04 Table 2.xls
SV-304'
<0.99
<0.97
<0.20
<0.19
<0.20
<0.19
Sample
Location
SV-305"
<1.0
<0.99
<1.0
<0.99
<1.0
<1.0
<1.0
<0.99
<0.96
<0.98
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.19
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.19
<0.20
Pass
Pass
<2.7
<2.7
1 of 1
•
•
I ' ' ' Leaders in Environmental Testing I
' ' '
ANALYTICAL REPORT
Raleigh, Biweekly NPDES
Lat#: C4E040318
Rita Bauer
The RETEC Group Inc
SEVERN TRENT LABORATORIES, INC.
SEVERN
TRENT
STL Pittsburgh
450 William Pitt Way
Pittsburgh, PA 15238
STL
Tel, 412 820 8380 Fax, ·412 820 2080
www.stl~inc.com
~~
Veronica Bortot
Project Manager
May l.2, 2004
Severn Trent Laboratories, Inc.
CASE NARRATIVE
THE RETEC GROUP
Raleigh, Biweekely NPDES
STLLot # C4E040318
Sample Receiving:
STL Pittsburgh, PA received samples on May 3, 2004. The cooler was received within
the proper temperature range.
STL West Sacramento outside of the proper temperature range received the samples.
If project specific QC was not required for samples contained in this report and batch QC
was completed on these samples, anomalous results will be discussed below.
GC/MS Semivolatiles SIM:
Since insufficient sample volume was received to perform a matrix spike and matrix
spike duplicate, a Laboratory Control Sample (LCS) and Laboratory Control Duplicate
(LCD) were performed. All recoveries were within QC limits.
The reporting limits were adjusted according to the amount of sample extracted.
•
Due to the concentration of target compounds detected, sample SV-10 I was analyzed at a •
dilution;
Dioxins:
STL West Sacramento, CA performed the dioxin analysis. All results are included in the
report.
There were no problems associated with the analysis.
•
•
•
•
METHODS SUMMARY
C4E040318
ANALYTICAL PREPARATION
~P~ARAME==-=~TE=R"-----------------------METHOD ~ME=TH=O~D;_ ___ _
Dibenzodioxins and Dibenzofurans, HRGC/HRMS
8270C {SIM)
References:
SW846 8290 SW846 8290
SW846 8270C SIM SW846 3520C
SW846 11Test Methods for Evaluating Solid waste, Physical/Chemical
Methods11 , Third Edition, November 1986 and its updates .
WO# SAMPLE# CLIENT SAMPLE ID
GFGBL
GFGBR
GFGBT
NOTE(S)
001
002
003
SV-305
SV-304
SV-101
SAMPLE SUMMARY
C4E040318
• The analytical results of lhe samples listed above are presented on the following pages.
-All calculations are performed before rounding to avoid round-off errors in calculated rcru1ts.
• Results noted as "ND" were not detected at or above the stated limit.
-This report must not be reprOduccd, except in full, without the written app~val of the laboratory.
-Results for the following parameters arc never repol'ted on a dry weigh! basis: color, corrosivity, density, flashpoint. ignitability, layers, odor,
paint filter test, pH, porosity pressure, reactivity, rcdox potential, specific gravity, spot tests, solids, solubility, tcmperawre, viscoSity, and weight.
•
SAMPLED SAMP
DATE ]:!!§._
05/03/04 J-6:40
05/03/04 :L 7: 00
05/03/04 :L7:18
•
•
SEVERN
TR.ENT -
PROJECT REFEREN E;? J
ll>'lA-r' ~
STl (LAB) PROJEC MANAGER
RELINQUISHED BY: {SIGNATURE!
F.MPTY corrrnmi::ns
RECEIVED BY: (SIGNATURE)
• Serial Number· -18179 •
ANALYSIS REQUEST AND CHAIN OF CUSTODY RECOllD
ST L p ',-1-\5 k.~ ,1 \.,., 0 Alternate Laboratory Name/Location
Website: www.st~inc.com
Phone: [phone]
Fax: 19121352-0165
Phone:
OATE TIME
OATE TIME
PROJECT LOCATION
(STATE) IJ<-
CONTRACT NO.
MATRIX
TYPE
RE l~REl
RE E)
Fax:
REQUIRED ANALYSIS PAGE OF
I
RELINQUISHED BY: !SIGNATURE! · DATE TIME
RECEIVED BY: !S!Gt'lATURE) OATE TIME
STL824Q.680 112/02)
Lot-Sample# ... : C4E040318·001
Date Sampled ... : 05/03/04
Prep Date ...... : 05/10/04
Prep Batch# ... : 4131206
Dilution Factor: 0.96
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-dS
Terphenyl-d14
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
THE RETEC GROUP INC
Client Sample ID: SV-305
CK:/MS Semivolatiles
Work Order# ... : GFG8LlAA
Date Received .. : 05/04/04
Analysis Date .. : 05/12/04
Analysis Time .. : 10:29
Matrix ......... : WATER
MS Run# ....... :
Method ......... : SW846 8270C SIM
REPORTING
RESULT LIMIT UNITS
ND 0.19 ug/L
ND 0.96 ug/L
ND 0.19 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
92 (28 -115)
87 (10 -115)
78 (34 -115)
57 (24 . 115)
58 (25 -115)
76 (33 . ll5)
•
•
•
•
•
•
THE RETEC GROUP INC
Client Sample ID: SV-305
Trace Level Organic Compounds
Lot-Sample# ... : C4E0403l8-00l
Date Sampled ... : 05/03/04
Prep Date ...... : 05/05/04
Prep Batch# ... : 4126255
Dilution Factor: 1
PARAMETER
2,3,7,8-TCDD
INTERNAL STANDARDS
l3C-2,3,7,8-TCDD
Work Order# ... : GFGSLlAC
Date Received .. : 05/04/04
Analysis Date .. : 05/06/04
Analysis Time .. : 13:25
DETECTION
RESULT LIMIT
ND 2.7
PERCENT RECOVERY
RECOVERY LIMITS
89 (40 -135)
Matrix ......... : WATER
MS Run.# ....... :
UNITS METHOD
pg/L SW846 8290
Lot-sample# ... : C4E040318-002
Date Sampled ... : 05/03/04
Prep Date ...... : 05/10/04
Prep Batch# ... : 4131206
Dilution Factor: 0.97
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-ds
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
THE RETEC GROUP INC
Client sample ID: SV-3O4
GC/MS Semivolatiles
Work Order# ... : GFG8Rl.AA
Date Received .. : 05/04/04
Analysis Date .. : 05/12/04
Analysis Time .. : 10:54
Matrix ......... : WATER
MS Run# ....... :
Method ......... : SW846 8270C SIM
REPORTING
RESULT LIMIT UNITS
ND 0.19 ug/L
ND 0.97 ug/L
ND 0.19 ug/L
PERCENT RECOVERY
RECOVERY· LIMITS
87 (28 115)
80 (10 -115)
75 (34 -115)
53 (24 -115)
52 (25 -ll5)
76 (33 -ll5)
•
•
•
•
•
•
Lot-Sample# ..• : C4E040318-003
Date Sampled ... : 05/03/04
Prep Date ...•.. : 05/10/04
Prep Batch# •.. : 4131206
Dilution Factor: 2.88
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-ds
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
THE RETRC GROUP INC
Client Sample ID: SV-101
GC/MS semivolatiles
Work Order# ... : GFG8Tl.AA
Date Received .. : 05/04/04
Analysis Date .. : 05/12/04
Analysis Time .. : 11:20
Matrix ......... : WATER
MS Run# •...... :
Method ......... : SW846 8270C SIM
REPORTING
RESULT LIMIT UNITS
ND 0.58 ug/L
20 2.9 ug/L
ND 0.58 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
93 (28 -115)
85 (10 -115)
82 (34 -115)
59 (24 -115)
53 (25 -115)
80 (33 -115)
Client Lot# ... : C4E040318
MB Lot-Sample#: C4El00000-206
Analysis Date .. : 05/12/04
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-ds
Terphenyl-d14
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
NOTE(S):
METHOD BLANK REPORT
GC/MS Semivolatiles
Work order # ••• : GFWXGlAA
Prep Date ...•.. : 05/10/04
Prep Batch# ... : 4131206
REPORTING
RESULT LIMIT UNITS
ND 0.20 · ug/L
ND 1.0 ug/L
ND 0.20 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
68 (28 · 115)
93 (10 · 115)
58 (34 • 115)
44 (24 · 115)
44 (25 · 115)
64 (33 · 115)
Calculations arc performed before rounding co avoid round-off errors in calculated results.
•
Matrix ......... : WATER
Analysis Time .. : 09:04
METHOD
SW846 8270C SIM
SW846 8270C SIM
SW846 8270C SIM
•
•
•
•
METHOD BLANK REPORT
Trace Level organic Compounds
Client Lot# .•. : C4E040318
MB Lot-Sample#: G4E050000-255
Analysis Date .. : 05/06/04
Dilution Factor: 1
PARAMETER
2,3,7,8-TCDD
INTERNAL STANDARDS
13C-2,3,7,8-TCDD
NOTR(S):
Work Order# ... : GFKFll.AA
Prep Date ...... : 05/05/04
Prep Batch# ... : 4126255
DETECTION
RESULT LIMIT UNITS
ND 3.2 pg/L
PERCENT RECOVERY
RECOVERY LIMITS
81 (40 -135)
Calculations are performed before rounding 10 avoid round-off errors in calculated results .
Matrix ......... : WATER
Analysis Time .. : 12:02
METHOD
SW846 8290
LABORATORY CONTROL SAMPLE EVALUATION REPORT
GC/MS Semivolatiles
Client Lot# ••. : C4E040318 Work order# •.. : GFWXGlAC-LCS
GFWXGlAD-LCSD
Analysis Date .. : 05/12/04
Analysis Time .. : 09:33
Matrix ......... : WATER
LCS Lot-Sample#: C4El00000-206
Prep Date .•..•. : 05/10/04
Prep Batch# .•. : 4131206
Dilution Factor: 1
PERCENT
PARAMETER RECOVERY
Phenol
Pentachlorophenol
2,4-Dichlorophenol
SURROGATE
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorobiphenyl
· 2=F1uoropheno'I:
Phenol-d5
2,4,6-Tribromophenol
NOTE (S):
70
66
104
111
101
100
RECOVERY
LIMITS
(10 -131)
(10 -131)
(10 -140)
(10 -140)
(42 -115)
(42 -115)
PERCENT
RECOVERY
89
88
81
75
80
76
61
57
63
53
82
79
Calculations are perfonncd before rounding to avoid round-off errors in calculated results.
RPD
RPD LIMITS METHOD
SW846 827DC SIM
5.4 (0-43) SW846 8270C SIM
SW846 8270C SIM
6.5 (0-56) SW846 8270C SIM
SW846 8270C SIM
1.2 (0-44) SW846 8270C SIM
RECOVERY
LIMITS
(28 115)
(28 -115)
(10 115)
(10 -115)
(34 -115)
(34 -115)
(:M -H5)
(24 -115)
(25 -115)
(25 -115)
(33 -115)
(33 -115)
•
•
•
•
•
•
LABORATORY CONTROL SAMPLE EVALUATION REPORT
Trace Level Organic compounds
Client Lot ll ••• : C4E040318 Work Order# ... : GFKFllAC
LCS Lot-Sample#: G4E050000-255
Prep Date •..... : 05/05/04 Analysis Date .. : 05/06/04
Prep Batch # ... : 4126255 Analysis Time .. : 12:43
Dilution Factor: 1
PERCENT RECOVERY
PARAMETER RECOVERY LIMITS
2,3,7,8-TCDD 91. (72 -l.37)
PERCENT
INTERNAL STANDARD RECOVERY
iJC-2,3,7,8-TCDD 90
NOTE (S) :
Calculations are performed before rounding to avoid round.-off errors in calculated results.
Bold print dcno1cs control parame1ers
Matrix ......... : WATER
METHOD
SWB46 8290
RECOVERY
LIMITS
(40 -135)
•
•
• Leader~ in EnvironmentalTestmg I
ANALYTICAL REPORT
Raleigh, Biweekly NPDES
Lot#: C4E200255
Rita Bauer
The RETEC Group Inc
SEVERN TRENT LABORATORIES, INC.
Veronica Bertot
Project Manager
May 26, 2004
SEVERN
STL Pittsburgh
450 William Pitt Way
Pittsburgh, PA 15238
STL
Tei, 412 820 8380 Fax, 412 820 2080
www.stl-inc.com
Severn Trent Laboratories, Inc.
Sample Receiving:
CASE NARRATIVE
THE RETEC GROUP
Raleigh, Biweekely NPDES
STL Lot# C4E200255
STL Pittsburgh, PA received one sample on May 20, 2004. The cooler was received
within the proper temperature range.
If project specific QC was not required for samples contained in this report and batch QC
was completed on these samples, anomalous results will be discussed below.
GC/MS Semivolatiles SIM:
Since insufficient sample volume was received to perform a matrix spike and matrix
spike duplicate, a Laboratory Control Sample (LCS) and Laboratory Control Duplicate
(LCD) were performed. All recoveries were within QC limits.
The reporting limits were adjusted according to the amount of sample extracted.
•
•
•
•
•
•
MEffiODSSUMMARY
C4E200255
ANALYTICAL PREPARATION
~P~ARAME==~TE=R"------'--------~---------METHOD ~ME=TH=~OD=-----
8270C (SIM) SW846 8270C SIM SW846 3520C
References:
SW846 "Test Methods for Evaluating solid Waste, Physical/Chemical
Methods", Third Edition, November 1986 and its updateS .
SAMPLE SUMMARY
C4E200255
WO# SAMPLE# CLIENT SAMPLE ID
GGl'IJK 001 EFF/SV-305
NOTE(S):
-The analytical result~ or the samples listed above arc presented on the following pages.
-All calailations arc performed before rounding to avoid round-off errors in calculated results..
-R.esultll noted as "ND" were not detected at or above the smced limit.
-This ttpa·n must nOI be reproduced, cxcq>t in full, wilbout the written approval of the laboratory.
-Results for the following parameters are never reported on a dI)' weight basis: color, amos.ivity, density, flashpoint, ignitability, layers, odor,
paint filter tcSt, pH, porosity pressure, reaaivity. rcdox potential, specific gravity, S!)Ot tt:sts, solids, solubility, tcmperanue, viscosity, and wci.gh.t.
SAMPLED
DATE
•
SAMP
TIME
05/18/04 10:20
•
•
• • • Serial Number O O 3 8 6
ANALYSIS REQUEST AND CHAIN OF CUSTODY RECORD
SEVERN STL
C)~ah e Avenue
3I404·····
Website: www.stHnc.com
~l:G!~l:µ;l54-7858 FaX' 1§\,1 352-0165
TRENT ,
PROJECT REFERENCE
' •<>1">--1-o'l
STL,!_LABI PROJECT MANAGER
PROJECT NO,
P,O, NUMBER
PROJECT LOQATION
(STATE! /JV
11' I!'
t,C;;;l-;;I =r,-;(S°'IT"'E'"'I P;;-:M,__;---------f--,Cccll::c:EN:::T:-:PccHccO:::N~:----+Cc-LcclE""NT"'F"AX,,------li
CONTRACT NO,
"'-\-o.. ~.,..,.Lr qr(-n<-1'f),,., "'
MATRIX
TYPE
~C;;;l-;;IEc;;;tjl ~';;;;::;EE:-=c.::._-'-----------f--:'C','ll;:'EN:::T:cE:--:-MA=1L=---J__------i§
~ g g
0 Alternate Laboratory Name/location
REQUIRED ANALYSIS
t,C;;;L~IE~N~T7~~D~R~ES;;;S:---l----~---------------~~5
'-;-;:;~~Do~~~~~r~L¥~l-~Gc,.,.,,=.~"'-'-'"--c-'--'--'--'--'~+--"O~l1--'----'--'Yi=------~G~~ ~
Phone:
Fax:
PAGE I / OF
STANDARD REPORT
DELIVERY 0
DATE DUE ____ _
EXPEDITED REPORT
DELIVERY 0
(SURCHARGE)
DATE DUE
NUMBER OF COOLERS SUBMITTED
PER SHIPMENT:
1 ~OMPANY CONTRACTING THIS WORK (if applicable) ~ ~ ~ 6 {
en ~ ~ ~
r--,S~~"P°'LcE---~---------------------1~~§ i~-~-~-~-~-~-~-~-~-~~r--------7
=PLE IDENTIFICATION 8 5? ~ ~ jia! NUMBER OF CONTAINERS SUBMITTED REMARKS TIME
RELINQUISHED BY: !SIGNATURE)
EMPTY CU!lff!\!NE!\S
RECEIVED BY: !SIGNATIJRfl
DATE
DATE
{
TIME
TIME
RELINQUISHED BY: IS!GNATURO DATE TIME
RECEIVED BY: (SIGNATURE) DATE TIME
Sll8240-680 0 2/02)
THE RBTEC GROUP INC
C1ient Samp1e ID: EFF/SV-305
GC/MS Sem.ivo1ati1es
Lot-Samp1e # ... : C4E200255-001 Work order# ... : GGNJKlAA Matr:u< ••.•..•.• : WATER
Date Sampled .•• : 05/18/04 Date Received-. : 05/20/04 MS Run# ....... :
P:rep Date •..... : 05/24/04 J\nal.ysis Date .. : 05/26/04
P:rep Batch # ... : 4145064 Analysis Time .. : 13:50
Dilution Factor: 0.98
Method ••..• ' ... : SW846 B270C SIM
REPORTING
PARAMETER RESULT LIMIT UNITS
2,4-Dichlorophenol ND 0.20 ug/L
Pentachlorophenol ND 0.98 ug/L
Phenol ND 0 .20 ug/L
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Nitrobenzene-d5 99 (28 -115)
Terphenyl-dl4 94 (10 -115)
2-Fluorobiphenyl 77 (34 -115)
2-Fluorophenol 49 (24 -115)
Phenol-d5 47 (25 -115)
2,4,6-Tribromophenol 84 (33 -115)
•
•
•
•
•
•
Client Lot# •.. : C4E200255
MB Lot-Sample#: C4E240000-064
Analysis Date •• : 05/26/04
Dilution Factor: l
PARAMETER
2,4-Dichlorophenol
Pentachlarophenol
Phenol
SURROGATE
Nitrobenzene-ds
Terphenyl-dJ.4
2-Fluorobiphenyl
2 -Fl uorophenol
Phenol-d5 .
2,4,6-Tribromophenol
NOTS (SJ :
METHOD BLANK REPORT
GC/MS Semi.volatiles
Work Order ff ••• : GGW5HlAA
Prep Date ...... : 05/24/04
Prep Batch# ... : 4145064
REPORTING
RESULT LIMIT UNITS
ND 0.20 ug/L
ND 1.0 ug/L
ND 0.20 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
J.06 (28 -1.15)
102 (10 -115)
80 (34 -1.15)
53 (24 -1.15)
50 (25 -1.15)
86 (33 1.15)
Calculations arc performed before roundlog to avoid round-off errors in c.alculated results .
Matrix ...•.•... : WATER
Analysis Time .. : 12: 25
METHOD
SW846 8270C SIM
SW846 8270C SIM
SW846 8270C SIM
LABORATORY CONTROL SllMPLE KVALlJllTION REPORT
GC/MS Semivolatiles
Client Lot i ..• : C4E200255
LCS Lot-Sample#: C4E240000-064
Prep Date .••••. : 05/24/04
Work order #.'.: GGW5H1AC-LCS
GGW5H1AD-LCSD
Analysis Date .• : 05/26/04
Analysis Time •. : 12:53
Matrix ......... : WATER
Prep Batch i ... : 4145064
Dilution Factor: 1
PARAMETER
Phenol
Pentachlorophenol
2,4-Dichlorophenol
SURROGATE
Nitrobenzene-ds
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
NOTE(S):
PERCENT
RECOVERY
65
67
91
103
103
104
RECOVERY
LIMITS
(10 -131)
(10 -131)
(10 -140)
(10 -140)
(42 -J.15)
(42 -115)
PERCENT
RECOVERY
99
104
101
J.00
84
83
57
55
57
53
87
88
Calcitlatlons are perfonned before roundin&: to avoid round-off errors in calculaied remits.
RPD
~ LIMITS METHOD
SW846 8270C SIM
2.4 (0-43) SW846 8270C SIM
SW846 8270C SIM
12 (0-56) SW846 8270C SIM
'SWB46 8270C SIM
0.58 ( 0-44) SW846 8270C SIM
RECOVERY
LIMITS
(28 -115)
(28 -115)
(10 -115)
(10 -115)
(34 -115)
(34 -115)
(24 -115)
(24 115)
(25 -115)
(25 -115)
(33 -115)
(33 -115)
•
•
•
•
•
•
Environmental Testing Solutions, Inc.
PO Box 7565
Asheville, NC 28802
May 14, 2004
Ms. Liz Sims
Tritest, Inc.
PO Box 33190
Raleigh, NC 27636
RE: ETS PROJECT NUMBER: 1205
Dear Ms. Sims:
Phone: [phone]
Fax: [phone]
E-mail: [e-mail]
Enclosed are toxicity test results for samples from the Retec -Beazer received by
Environmentai'Testing Solutions, Inc. April 28 through May 01 2004.
Parameter Test Procedure
Code
TGP3B
North Carolina Ceriodaphnia Chronic Effluent
Toxicity Procedure -December 1985, Revised:
February 1998
(Ceriodaphnia Pass/Fail Toxicity Test)
EPA Method
Number
EPA-821-R-02-013
Final
Result
PASS
If this test was performed as an NPDES requirement or by Administrative Letter, please
enter a Pon the Effluent Discharge Monitoring Form (MR-I) for the collection date
April 26, 2004 using the parameter code TGP3B.
Additionally, please sign and submit the enclosed DWQ Aquatic Toxicity Form (AT-I)
to the following address. The original AT-I form must be mailed by May 31, 2004.
North Carolina Department of Environment and Natural Resources
DWQ/Environmental Sciences Branch
1621 Mail Service Center
Raleigh, NC 27699-1621
If you have any questions concerning these results, please feel free to_contact me.
Sincerely, cr1~
Jim Sumner
Laboratory Director
North Carolina Certificate Numbers: Biological Analyses: 37, Drinking Water: 37786, Wastewater: 600
South Carolina Certificate Number: Clean Water Act: 99053-001
Environmental Testing Solutions, Inc.
Shipping address:
351 Depot Street
Asheville, NC 28801
Phone: [phone]
Fax: [phone]
Whole Effluent Toxicity Chain-of-Custody Form •
Facility: Tritest, Inc,
Retec -Beazer
NPDES#: .M~
Purchase order:
Pipe#: £:!2}_ County: _W_a_k_e ____ _
Species: Ceriodaphnia dubia Effluent dilution: 90%
Test type: Pass/Fail Chronic Parameter code: TGP3B
Sample information: (to be completed by sample collector)
Composite sample: · ~ Sample location: £Fr° -· .Jl::(,?°OJ
Start,fale: 'f~i, _i}'! Time: JS-OD__ Volumecollecledforlesting: _:.;,l_c:..':..,,.,w=;.zc,s;,..,.., ~--'---
End date: 4 {n y Time: j ~(JO Number qf containers filled for testing: i
Number of samples per hour: L Total residual chlorine (mg/L):
Chilled during collection? );f-: r. Te!Ilperature at time of collection (°C):
1---=If=c:hil:' :le:d:, :sp~e:c:ify.:_:le:m.::p•:ra:::ture:::: _ __:==========~ Method of transport to laboratory: Ll:'4vLl""'--/)L--=0,0.=·-="'-'' l..:"-'::s:"'?a""""''I;;~?~'
Grab snmplc: Comments:
Date: Time:
N()le: DO NO f collect samples before 8:00 AM. Triple rmse sample contamer With sample before fillmg. Completely fill
the sample container with no atr space. Pack the container completely in ice. The sample 1ID..1st be received at< 4,0°C.
I Sample custody: (to be completed by sample collector and facility personnel)
Sllmple c-olle1·ted b~•:
[~ l:r£.~~~~~ ~6d 't/t1 /o'f ,Jo
Dale ,.ldl.Iro>e
Relinqoi<Jhed by: Rereived by:
l:r;-;r' ~0~L~-d f/4Lot i'-?QI
~'""'\.r..i
1s y
f'rillt IJ:llll!UU 1r.,,t,, >111dtime g Rclinqoisl1cd h)': Rct·eived by: t pt~4i;t' ~ F-Q7-oq1 I :~ ::; OPS ' }: 1,:00
Dateilndlir,,c -"-·
L/-~7-0•□✓ I
lo-30 'i
Dare,.L<llill!e :;
Sample receipt information: (to be completed by ETS personnel)
Custodyseulsintact'?: LJ LJ LJ Sample temperature upon receipt at ETS ('C):
Yos No Not used
Samples received in good condition?: LJ LJ
Yes No Project number: \205 Sample number: Q.!0426-O2.
ConnnenL\':
•
•
@,1-0 t/-0/-7~}
Environmental Testing Solutions, Inc.
Shipping address:
351 Depot ~treet
Asheville, NC 28801
Phone: [phone]
Fax: [phone]
Whole Effluent Toxicity Chain-of-Custody Form
Facility: Tritest, Inc. NPDES#: .:.· ____ _ Pipe#: _.__ County: _W:.:..::a::.k::ec_ __ _
Retec -Beazer Purchase order:
Species: Ceriodaphnia dubia Effluent dilution: 90%
Test l)1le: Pass/Fail Chronic Parnmeter code: TGP3B
Composite sample:. f Sample location: SY~ F::r=i=-
Start date: '-I~ ::l Cl y Time: c.lJ.!1 o o_. _ Volume collecled for testing: iO
End ,bte ~}i o/':j_ Time: D JOQ Number of containefS filled for testing: I
Number of samples per hour: t Total residual cli~orine (mg/L):
Chilled during collection? \ Temperature at time of collection (°C): ~&r,. If chilled, specify temperature: -<:. '-j •<. Method of trnnsport lo laboratory: 1.--.--ckli-,v
Grub sample: Comments:
Date: Time: --· -·
.. ..
Sample ~eccipt information: (to be completed hy ETS personnel)
Date and time
Custodysealsintuct?: D D W
Yes N<> NotllS<d
Sample temperature upon receipt at ETS ("C): {). 5·1..,,
Samples received in good condition?: r;::J D
Yes No Projectnumber: IZ0'5 Samplenumber: ~DiC6C/,O/
Conunenl,;:
0 ·o
¥~□TEST
3909 Beryl Road
Raleigh, NC 27607
Page 1 of 1
Telephone: [phone]
Fax: [phone]
NC/WW Cert #: 067
NC/DW Cert.#: 37731 •
Laboratory Report
---Prepared for ---
RAY STEPINSKY
THE RETEC GROUP
3040 WILLIAM PITT WAY
PITTSBURGH, PA 15238
Project No.: 01
Project ID: Chronic Pass/Fail
No. Sample ID
001 EFF -SU305
Test Performed
Bioassay, Chronic Pass/Fail
Date Sampled
4/27/2004
Method
NC Pass/Fail
Time Sampled
15:00
Report Date: 5/20/2004
Date Received: 4/27/2004
Work Order#: 0404-01751
Cust. Code: RE1422
Gust. P.O.#:
Matrix
WW
Sample Type
Composite
Results Analyzed
PASS# 5/14/04
#ANALYZED BY ENVIRONMENTAL TESTING SOLUTIONS, INC., ASHEVILLE, NC
(NC BIOLOGICAL CERT. #37).
Reviewed by:
for Tritest, Inc.
Condition
4 +/-2 deg C
Qualifier
•
•
•
•
Environmental Testing Solutions, Inc.
PO Box 7565
Asheville, NC 28802
Phone: [phone]
Fax: [phone]
E-mail: [e-mail]
Eflluent Toxicity Report J,onn -Chronic Pass/Fail and Acute LC50 Dale: May 14, 2004
Facility: Tritest, Inc. NPDES #: NC-Letter Pipe#: 001 County: Wake· --Rctcc -Beazer
Laboratory Performing Test: Environmental Testing Solutions, Inc. Comments: Q'-irJ..t-01151
Signature of Operator in Responsible Charge:
Signature of Laboratory Supervisor: (!)-~= · Proj~ct: 1205
l SalJ1)1cS: 040428.02, 040501.01
Mail Original To: North Carolina Department of Environment and Natural Resources Chronic Test Result-.
DWQ/ Environmental Sciences Branch Calculated t: -2.811
1621 Mail Service Center Tabular t: 2.508
Raleigh, NC 27699-1621 % Reduction: -6.4
North Cnrolinu Ceriodaplmia Chronic Puss/Foil Reproduction Toxicity Test Percent Average
Morality Reproduction
Control On•unisms 1 2 3 4 5 6 7 8 9 10 11 12 Control Control
Number of Youne Produced 34 35 38 36 36 35 33 33 35 35 36 36 0.0 35.2
Adult Survival: (L)ive, (D)ead L L L L L L L L L L L L Treatrrcnt 2 Treatn~nt 2
0.0 37.4
Efllucnt Pcrccn!Jtgc I 90% I Control CV
Treatment 2 Or~unisms 1 2 3 4 5 6 7 8 9 10 11 12 4.0 Puss Fuil
Number of Y ouni! Produced 38 39 38 38 35 35 41
Adult Survival: (L)ive, (D)ead L L L L L L L
pH (S.U.) 1st Sam le 1st Sam le 2nd Sam le
Control 7.57 7.77 7.63 8.01 7.75 7.50
Treatmerit 2 7.64 8.65 7.98 8.73 8.11 8.55
§' .,, § .,, § 1! " JI "' "' "' "' UJ
D.O. (mg/L) 1st Sam le 1st Sam le
Control 8.0 7.7 7.7 8.3.
Treatment 2 8.8 7.6 7.8 8.4 s.r
LC5ofAcute Toxicity Test
(Mortality expressed as%, combining replicates.)
Concentration ( % )
Mortality(%)
LC50= ____ _
95% Confidence Limits
____ to ___ _
Method of Detennination
40 38 35 39 33 '!l, conlrol orionian~
p,oducffi83!dhrood X L L L L L 100 .
Test Start Date: -'0'--4-'-2"'8'---0.c..4-'---------
Collection (Start) Date:
Sample I 04-26-04 Sample 2 04-29-04
Sample Type/Duration
Grab COtl'.{I, Duratic.i
Smple 'if-__ · +l-yx'-+1-:-:-
Sanple 2 L--~---~· __
Alkalinity (mg CaCO3'L)
Hardness (mg CaCO/L)
Conductivity (µrrhosr'cm)
Total Residual Chlorine (rrg/L)
Sanple Terrtl. at Receipt (0C)
1 "'
N
1 "'
§Trimmed Spearman Karber
Probit
Other: ________ _ I I I
Orguni-m1 Tested: Ceriodaphnia dubia Duration: 6-days pH (S.U.) DO (mg/L)
DWQform AT-I (3/87) rev. 11195
•
•
•
• I
May 10, 2004
Ms. Beverly Hudson
Remedial Project Manager
U.S. EPA-Region IV, I Ith Floor
North Site Management Branch
61 Forsyth Street, SW
Atlanta, GA 30303
RE: Monthly Progress Report #132
Remedial Action
Koppers Site -Morrisville, North Carolina
Dear Ms. Hudson:
• The RETEC Group, Inc.
3040 William Pitt Way
Pittsburgh, PA 15238-1359
RETIE(
[phone] Phone
[phone] Fax
www.retec.com
In accordance with the Unilateral Order, and on behalf of Beazer East, Inc. (Beazer), please find
attached four (4) copies of the April 2004 Monthly Progress Report for Remedial Action at the
Koppers Superfund Site in Morrisville, North Carolina. No exceedences occurred during this
event.
Should you need additional information regarding this progress report, please call Mike Helbling
at [phone] or me at [phone].
Sincerely,
The RETEC Group, Inc.
~cr,.J,1~..;L-
Rita Bauer {{,,-~--0
Project Geologist
Enclosure
cc: ~ttison -NC Superfund (2 co~
~ett -NC Division of Water Quality
M. Matthews -NC Division of Water Quality
P. Kilchenstein -RETEC
H:\Beaz-Ralei\04M-04.doc
L. Faulconer -Wake County
G. Caskey -Enwood Structures
M. Helbling -Beazer
•
•
• •
MONTI-IL Y PROGRESS REPORT #132
REMEDIAL ACTION
SITE NAME: Koppers Superfund Site
Beazer East, Inc.
Morrisville, NC
USEPA DOCKET NUMBERS: 93-09-C
PERIOD ENDING: April 30, 2004
1. PROGRESS MADE THIS MONTH
Remedial Action (RA) -HABITAT MITIGATION. No activities were conducted this month.
Remedial Action (RA) -GROUNDWATER TREATMENT. The treatment system operated
throughout the month without upset. System performance was monitored on a biweekly basis.
Approximately 59,530 gallons of groundwater were extracted, treated in the treatment plant, and
discharged between April 1, 2004 and April 30, 2004. System water samples were collected on
April 10 and April 23, 2004 in accordance with the sampling schedule in the O&M manual.
Samples were submitted to Severn Trent Laboratories, Inc. for laboratory analysis. The chronic
toxicity samples were collected on April 27, 2004. The operations and sampling programs are
summarized on the attached Table 1.
2.
3.
4.
5.
6.
Remedial Action (RA) -EFFECTIVENESS MONITORING PROGRAM. No activities
were conducted this month.
Remedial Action (RA) -CORRESPONDENCE. None.
PROBLEMS RESOLVED
PROBLEMS ANTICIPATED
UPCOMING EVENTS
PERSONNEL CHANGES
SUBCONTRACTORS
None.
None.
Continue System O&M.
None.
None.
7. ANALYTICAL DATA Analytical data from system influent and effluent
sampling received during this period are enclosed and are summarized on Table 2.
H:\Beaz-Ralei\04M-04.doc
•
Dato Systoms Cumulative SV-101 SV-101
Check Effluent Flow Sample Sample
(yes/no) (Gallons) (yes/no) Parameters
01/06/04 ves 4 321,380 ves Penta, 2,4-Dichloro, Phenol
01/19/04 ves 4.342,740 no
02/03/04 ves 4,368,380 no
02/17/04 ves 4,392,180 no
03/05104 yes 4.424,090 no
03/25/04 ves 4 463,830 no
04/10/04 ves 4,475,980 no
04/23/04 ves 4 510,660 no
04/27/04 ves 4,519,420 no
Notes:
Sampling point SV-101 is located before the Carbon Units (pretreatment)
Sampling point SV-304 is located between the Carbon Units
Sampling point SV-305 is loctated after the Carbons Units (post-treatment)
''""""" F:\PAOJECTS\036:24\Reports\M:lntlyYl2004\04M-04 Table 1.xia
Dioxin
Table 1
Groundwater Treatment Operations and
Sampling Program Summary
Koppers Superfund Site
Morrisville, North Carolina
Aprll 2004
Associated SV-304 SV-304
Group Sample Sample
(yes/no) Parameters
1,2 ves Penta, 2,4-Dichloro, Phenol
no
no
no
no
no
no
no
no
Associated Groups:
Associated SV-305
Group Sample
(yes/no)
1 ves
ves
ves
ves
ves
ves
ves
ves
ves
SV-101 • Group 1 is penta, phenol, and 2,4-dlchlorophenol; Group 2 is dioxin
SV-304 -Group 1 is penta, phenol, and 2,4-dichtorophenol
•
.RETEC
SV-305 Associated
Sample Group
Parameters
Penta, 2,4-Dich!oro, Phenol, Dioxin, Chronic
Tox 1, 2, 3
Penta, 2,4-0ichloro, Phenol 1 • Penta, 2,4-Dichloro, Phenol 1
Penta, 2,4-0ichloro, Phenol 1
Penta, 2,4-0ichloro, Phenol 1
Penta, 2,4-0ich!oro, Phenol 1
Penta, 2,4-Dichloro, Phenol 1
Penta, 2,4-Dich!oro, Phenol 1
Chronic Tox 3
•
SV-305 -Group 1 is penta, phenol, and 2,4-dichtorophenol; Group 2 is dioxin and Group 3 is chronic toxicity
•
•
• •
Table 2
Groundwater Treatment Analytical Data Summary
Koppers Superfund Site -Morrisville, North Carolina
April 2004
Analytical
Parameter Date Sample
Sample Location
Collected SV-101
Pentachlorophenol 01/06/04 33
01/19/04
02/03/04
02/17/04
03/05/04
03/25/04
04/10/04
04/23/04
2.4-Dichlorophenol 01/06/04 <0.60
01/19/04
02/03/04
02/17/04
03/05/04
03/25/04
04/10/04
04/23/04
Phenol 01/06/04 <0.60
01/19/04
02/03/04
02/17/04
03/05/04
03/25/04
04/10/04
04/23/04
Chronic Toxicity 01/06/04
04/27/04
Dioxin (2,3,7,8-TCDD) 01/06/04 <2.7
Notes: All results are In micrograms per hter (µg/L) except d1oxm. 01oxm data Is m pIcograms per liter (pg/L}.
SV-101 -Before Carbon Units
•sv-304 -Between Carbon Units
--sv-305 -After Carbon Units
05/10/2004
F:IPROJECTS\03624\Reports\Monthly\2004\04M-04 Table 2.xls
Sample
Location
SV-304•
<0.99
<0.20
<0.20
Sample
Location
SV-305 ..
<1.0
<0.99
<1.0
<0.99
<1.0
<1.0
<1.0
<0.99
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
Pass
Pass
<2.7
1 of 1
•
•
•
-Leaders in Envfr01lme'llfa11esffng---:
'
ANALYTICAL REPORT
Raleigh, Biweekly NPDES
Lot#, C4D130150
Rita Bauer
The RETEC Group Inc
•
SEVERN
TRENT
STL Pittsburgh
450 William Pitt Way
Pittsburgh, PA 15238
STL
Tei, 412 820 8380 Fax, 412 820 2080
www.stl-inc.com
SEVERN TRENT LABORATORIES, INC.
Veronica Bortot
Project Manager
April 1.6, 2004
Sevem Trent Laboratories. Inc.
• •
STL
NELAC REPORTING:
The fonDat end content of the attached report meets NELAC standards and guidelines except as noted in the narrative. Toe table below
presents a summary of the cert;ifications held by Sn. Pittsburgh. Our primary accreditation authority for the Non-potable water and Solid
& Hazardous waste programs is NeW York State DOH. A more detailed parameter list is available upon request Please ask your project
manager for this information when required.
The codes utilized for program types are desaibed belov-r.
HW Haz.ardousWastccenIBcation
WW Non-potable Water and/or Wamwtter certification
X
X
= i}:~· X: ::.="" ·:~:-~.' --~ ... ~~~:: r x~: ij~ /-~~~f~~,
X Laboratory has some form of certification under the sped fie program. Many states certify laboratories for specific parameters or
tests within a categoty. The Information In the table Indicates the lab is certified in a genera! category of testing. Please contact
the laboratory If parameter specific certification Information Is required.
-
•
•
•
Sample Receiving:
CASE NARRATIVE
THE RETEC GROUP
Raleigh, Biweekely NPDES
STL Lot# C4Dl30150
•
STL Pittsburgh, PA received one sample on April 13, 2004. The cooler was received
within the proper temperature range.
If project specific QC was not required for samples contained in this report and batch QC
was completed on these samples, anomalous results will be discussed below.
GC/MS Semivolatiles SIM:
Since insufficient sample volume was received to perform a matrix spike and matrix
spike duplicate, a Laboratory Control Sample (LCS) and Laboratory Control Duplicate
(LCD) were performed. All recoveries were within QC limits.
The reporting limits were adjusted according to the amount of sample extracted .
• •
METHODSSUMMARY •
C4D130150
ANALYTICAL PREPARATION
~PARAME==~T~E~R"---------------------METHOD ~M=E~T~H=O=D ____ _
8270C (SIM) SW846 8270C SIM SW846 3520C
References:
SWB46 11Test Methods for Evaluating Solid Waste, Physical/Chemical
Methods 11 1 Third Edition, November 1986 and its updates.
•
•
• •
• SAMPLE SUMMARY
C4D130150
SAMPLED SAMP
WO# SAMPLE# CLIENT SAMPLE ID
GD2V9 001 EFF./SV-305
04/10/04 12:00
NOTE(S),
• The analytical results of the samples listed above arc presented on the following pages.
• All calculaJ.ions arc perfonned before rounding to avoid round-off errors In calculated results.
• Results noted as "ND" were not detected at or above the stated limit.
-This report must not be reproduced, except in full, without the written approval of \he laboratory.
-Results for lhe following parameters are never reported on a dry weight basis: color, corrosivity, denslcy, flaShpolnt, ignltability. layers. odor,
paint filter test, pH, porosity pressure, reactivity. rcdox potential, specific gravity, spot tests, solids, solubility, temperature, viscosity, and weight .
•
•
S'E VERN
TRENT
RELINQUISHED BY: !SIGNATIJREI
RECH/ED BY: !SGNATUR£l
ANALYSIS REQUEST AND CHAIN OF CUSTODY RECORD
!
STL
PROJECT NO.
DATE
DATE
TIME
TIME
PROJECT LOCATION
(STATE) (I/ C,, MATRIX i TYPE
Serial Number 25636
O STtSavannah
5102 LaRoche.Avenue
Savannah, GA·.31404
<:f<,. Alternate laboratory, Name/location
REQUIRED ANALYSIS
NUMBER OF CONTAINERS SUBMITTED
Website: www.stJ..inc.com
Phone: [phone]
Fax: [phone]
Phone:
Fax:
PAGE
REtMRKS
RELINQUISHED BY: !SIGNATIJREI DATE
•
•
TIME
I
•
•
• •
THE RBTEC GROUP INC
Client Sample ID: BFF./SV-305
Lot-Sample# .•. : C4Dl30150-001
Date Sampled .•. : 04/10/04
Prep Date .•.... : 04/14/04
Prep Batch# ... : 4105184
Dilution Factor: 1.01
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-dS
Terphenyl-d14
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
GC/MS Semivolatiles
Work Order# ... : GD2V91AA
Date Received .. : 04/13/04
Analysis Date .. : 04/15/04
Analysis Time .. : 13:34
Matrix ......... : WATER
MS Run # ....... :
Method ......... : SW846 8270C SIM
REPORTING
RESULT LIMIT UNITS
ND 0.20 ug/L
ND 1.0 ug/L
ND 0.20 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
99 (28 -115)
86 (10 -115)
74 (34 -115)
64 (24 -115)
61 (25 -115)
76 (33 -115)
•
Client Lot# ... : C4Dl30150
MB Lot-Sample#: C4Dl40000-184
Analysis Date .. : 04/15/04
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-d5
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
NOTE(S):
•
METHOD BLl\NK REPORT
GC/MS Semivolatiles
Work Order# ... : GD4E41AA
Prep Date ...••. : 04/14/04
Prep Batch# ... : 4105184
REPORTING
RESULT LIMIT UNITS
ND 0.20 ug/L
ND 1.0 ug/L
ND 0.20 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
92 (28 -115)
82 (10 -115)
71 (34 -115)
59 (24 -115)
68 (25 -115)
70 (33 -115)
Calculations are pcrfonned before rounding to avoid round-off errors in calculated results.
•
Matrix ......... : WATER
Analysis Time .. : 12:09
METHOD
SW846 8270C SIM
SW846 8270C SIM
SW846 8270C SIM
•
•
•
•
•
• •
LABORATORY CONTROL SAMPLE EVALUATION REPORT
GC/MS Semivolatiles
Client Lot# ... : C4D130150
LCS Lot-Sample#: C4D140000-184
Work Order# ... : GD4E41AC-LCS
GD4E41AD-LCSD
Analysis Date .. : 04/15/04
Analysis Time .. : 12,37
Matrix ......... : WATER
Prep Date ...... : 04/14/04
Prep Batch# ... : 4105184
Dilution Factor: 1
PERCENT RECOVERY RPO
PARAMETER RECOVERY LIMITS RPO LIMITS METHOD
Phenol 75 (10 -131) SW846 8270C SIM
81 (10 -131) 7.6 (0-43) SW846 8270C SIM
Pentachlorophenol 136 (10 -140) SW846 8270C SIM
131 (10 -140) 4.0 (0-56) SW846 8270C SIM
2,4-Dichlorophenol 81 (42 -115) SW846 8270C SIM
81 (42 -115) 0.27 (0-44) SW846 8270C SIM
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Nitrobenzene-dS 95 (28 115)
93 (28 -115)
Terphenyl-dl4 83 (10 -115)
80 (10 -115)
2-Fluorobiphenyl 76 (34 -115)
74 (34 -115)
2-Fluorophenol 62 (24 -115)
64 (24 -115)
Phenol-d5 73 (25 -115)
71 (25 -115)
2,4,6-Tribromophenol 78 (33 -115)
76 (33 -115)
NOTB(SJ:
Calculations arc perfonned before rounding to avoid round-off errors in calculated results .
•
•
•
Leaders inJEnvironmentalTestmg · J
ANALYTICAL REPORT
Raleigh, Biweekly NPDES
Lot#: C4D240130
Rita Baller
Tlie RETEC Group Inc
•
STL Pittsburgh
450 William Pitt Way
Pittsburgh, PA 15238
STL
Tel, 412 820 8380 Fax, 412 820 2080
W-Nw.stl~lnc.com
SEVERN TRENT LABORATORIES, INC.
Veronica Bortot
Project Manager
llpril 30, 2004
Sevem Trent laboratories, Inc.
• CASE NARRATIVE
THE RETEC GROUP
Raleigh, Biweekely NPDES
STL Lot# C4D240130
•
Sample Receiving:
STL Pittsburgh, PA received one sample on April 24, 2004. The cooler was received
within the proper temperature range.
If project specific QC was not required for samples contained in this report and batch QC
was completed on these samples, anomalous results will be discussed below.
GC/MS Semivolatiles SIM:
Since insufficient sample volume was received to perform a matrix spike and matrix
spike duplicate, a Laboratory Control Sample (LCS) and Laboratory Control Duplicate
(LCD) were performed. All recoveries were within QC limits.
The reporting limits were adjusted according to the amount of sample extracted.
•
•
•
•
•
•
• •
METHODS SUMMARY
C4D240l.30
ANALYTICAL PREPARATION
PARAMETER METHOD ~ME=TH=O~D~----
8270C (SIM) SW846 8270C SIM SW846 3520C
References:
SW846 11 Test Methods for Evaluatin9 Solid Waste, Physical/Chemical
Methods", Third Edition, November 1986 and its updates .
• •
SAMPLE SUMMARY
C4D240130
WO # SAMPLE# CLIENT SAMPLE ID
GEV82 001 EFF/SV-305
NOTE(S)
• The analytical results of the samples listerl above are presented on the following pages.
• All cakuladons are performed before rounding to avoid round-off errors in calculated results.
-Results noted as "ND" were not dclected at or above the stated limit.
-This repon muse not be reproduced, except in full, without the written approval of the laboratory.
• Results for the following parameters are never reported on a dry weight basis: color, ·corrosivity, density, flashpoint, ignitability, layers, odor,
palm filu:r test, pH. porosity pressure, reactivity, rcdox potential, sped.fie gravity, spot tests, solids, solubility, temperarure, viscosity, and weight.
•
SAMPLED SAMP
DATE TIME
04/23/04 09:15
•
•
• Serial Number 3 3 4 3 6 • ANALYSIS REQUEST AND CHAIN OF CUSTODY REC◊RD C)~h nue
Savanna , GA 404
0 Alternate Laboratory Name/Location
Phone:
Fax:
PROJECT NO. PROJECT LOCATION
(STATE) (; REQUIRED ANALYSIS
P.O. NUMBER CONTRACT NO.
NUMBER OF CONTAINERS SUBMITTED REMARKS
REI.INQUISHED BY: JSIGNATUREI DATE TIME RELINQUISHED BY: ISIGNATUREI DATE TIME
RECEIVED BY: ISIGNATUREI DATE TIME RECEIVED BY: (SIGNATURE) DATE TIME
STLB240-680 (12/02)
•
THE RETEC GROUP INC
Client Sample ID: EFF/SV-305
GC/MS Sernivolatiles
•
Lot-Sample# ... : C4D240130-001 Work Order# ... : GEVB21AA
Date Received .. : 04/24/04
Analysis Date .. : 04/29/04
Analysis Time .. : 13:41
Matrix ......... : WATER
Date Sampled ... : 04/23/04 MS Run# ....... :
Prep Date ...... : 04/27/04
Prep Batch# ... : 4118299
Dilution Factor: 0.99
Method ......... : SW846 8270C SIM
REPORTING
PARAMETER RESULT LIMIT UNITS
2,4-Dichlorophenol ND 0.20 ug/L
Pentachlorophenol ND 0.99 ug/L
Phenol ND 0.20 ug/L
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Nitrobenzene-dS 81 (28 -115)
Terphenyl-dl4 92 (10 -115)
2-Fluorobiphenyl 64 (34 115)
2-Fluorophenol 54 (24 -115)
Phenol-d5 53 (25 -115)
2,4,6-Tribromophenol 64 (33 115)
•
•
•
•
•
•
Client Lot# ... : C4D240l30
MB Lot-Sample#: C4D270000-299
Analysis Date .. : 04/29/04
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-dS
Terphenyl-d14
2-Fluorohiphenyl
2-FluorophenOl
Phenol-d5
2,4,6-Tribromophenol
NOTE (S) :
•
METHOD BLANK REPORT
GC/MS Semivolatiles
Work Order# ... : GElE0lAA
Prep Date ...... : 04/27 /04_
Prep Batch# ... : 4118299
REPORTING
RESULT LIMIT UNITS
ND 0.20 ug/L
ND 1.0 ug/L
ND 0.20 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
100 (28 -115)
93 (10 115)
74 (34 -115)
63 (24 -115)
64 (25 -115)
72 ( 3 3 -115)
Calculations arc performed before rounding to avoid round-off errors in calculated results.
Matrix ......... : WATER
Analysis Time .. : 12: 05
METHOD
SW846 8270C SIM
SW846 8270C SIM
SW846 8270C SIM
• •
LABORATORY CONTROL SAMPLE EVALUATION REPORT
GC/MS Semivolatiles
Client Lot# ... , C4D240130 Work Order# ... , GElE0lAC-LCS Matrix ......... , WATER
LCS Lot-Sample#, C4D270000-299 GElE0lAD-LCSD
Prep Date ...... , 04/27/04 Analysis Date .. , 04/29/04
Prep Batch# ... , 4118299 Analysis Time .. , 12,44
Dilution Factor: l
PARAMETER
Phenol
Pentachlorophenol
2,4-Dichlorophenol
SURROGATE
Nitrobenzene-ds
Terphenyl-d14
2-Fluorobiphenyl
Phenol-d5
2,4,6-Tribromophenol
NOTE(S),
PERCENT
RECOVERY
66
69
74
72
77
76
RECOVERY
LIMITS
(10 -131)
(10 -131)
(10 -140)
(10 -140)
(42 -115)
(42 -115)
PERCENT
RECOVERY
100
98
82
Bl
77
75
70
68
54
51
73
75
Calculations are performed before rounding to avoid round-off errors in calculated results,
RPD
RPD LIMITS
3.9 (0-43)
3.0 (0-56)
2.0 ( 0-44)
RECOVERY
LIMITS
(28 -115)
(28 -115)
(10 -115)
(10 -115)
(34 -115)
(34 -115)
(24 -115)
(2~ -11si
(25 -115)
(25 -115)
(33 -115)
(33 -115)
METHOD
SW846 8270C SIM
SW846 B270C SIM
SW846 8270C SIM
SW846 8270C SIM
SW846 B270C SIM
SW846 8270C SIM
•
•
•
•
•
0
05-10-' 04 09: 51 FROM. LLC · 8283509368 • T-723
~vironmental Testing Solutio!ls, Inc.
P03/03 U-338
PO Box 7565
Asheville, NC 28802
Phone: [phone]
Fax: [phone]
E-mail: Jim.Sumne,@aol.com
Eflluent Toxiciti· Report Fonn -Chronic Pass/Fail and Acute LC,0 Date: May 14, 2004
Facility: Tritest, Inc. NPDES #: NC-Letter Pipe#:~ COUllty: Wake
Retec a Btazer
Laboratory Performing Test: Environmental Testing Solutions, Jnc. Comments:
Signature. of Operator in Responsible Charge:
Signature of Laboratory Super'/lsor: eF~ Project: 120,
Sa~lcs: 04()J28.02. 040501.01
Moil Origi!UII To: North Carolina Department of Environment and Natural Rosourcos Chronic Test Results
DWQ/ Environmenlill Sciences Branch Calculated I: -2.811
1621 Mail Service Center Tabular t: 2.508
Raleigh, NC 27699-1621 % Reduction: -6.4
North Co:rolina Ctriodaphnia Chronic Pius/Fail Reproduction Toxicity Test Perc-ent A,·.rag@
Morality RrprodncU011
Control Ore:nnisrns I 2 3 4 5 6 7 8 9 10 11 12 Control Coutro1
Numbei· of Young Produced I 34 I 35 I 38 I 36 I 36 I 35 I 33 I 33 I 35 I 35 I 36 I 36 I 0.0 35.2
Adult SurvivA!: (L)ive, (D)ead I L I L I L I L I L I L I L I L I L I L I L I L I Trca~\12 Ttt::ll~n1 2
0.0 37.4
Effluent Percentage I 90% I Comrul CV
T:reatment 2 Org1nll!ms I 2 3 4 5 6 7 8 9 to 11 12 4.0 Pass Foil
Number of Youn• Produced I 38 I 39 I 38 I 38 I 35 I 35 I 41 I 40 I 38 I 35 I 39 I 33 I r,tfdl'1.1or,.,.= xi pro~!<dllroed
Adult Survival: (L)ive, (D)ead I L I L I L I L I L I L I L I L I L I L I L I L I 100 .
pH (S.U.) 1st Sam le 1st Sam I" 2nd Sam Test Start Dote: 04-28-04 ------------Control 7.57 7.77 7.63 8.01 7.75 7.
Treatment 2 7,64 8.65 7.98 8.73 8.11 8, Collection (Slilrt) Date:
B ~ ~ ~ ll l tll ill Sample 1 04-26-04 Sample 2 04-29-04
"' "' "'
D.O. (me/L) 1st S 2nd Sam le Sample Type/Duration
Control 8.0 7.9 8.0
Treatment 2 8,8 8.1 7.9
LC,ofAcutc Toxicity Test
(Mortality expressed as%, combining replicates:.)
C-On.centl'llltlon ( % )
M ott"lity ( % )
LC50= -----95% Confidence Limits
~---to ---
Method of Determination
§Trimmed Speannan Karber
Probit
Other: _______ _
Organism Tested: Ceriodaphnia dub/a Durotion: 6-days
Dll'Qform AT-I (3/87) rev. 11/95
Alkalinity (mg C~C0,11..)
Hudu~u (fll;: CaCO,fL)
Conductivity (µnf10t/cnQ
Tota] Resid1111l Chlorine (D'(;/L)
Sarq>le Ttrrp. at Receipt {'CJ
~ l "'
I I I Coritrol
H;shCono.
pH (S.U.)
0.5
~ 1l
"' Ul
I I I
DO (mg/L)
05-10-' 04 10: 09 FROM-Ejji.LLC 8283509368 I T-724
E1-onmental Testing Solutio , Inc.
P02/03 U-341
I...,. t ,__..., f -
Shipping address:
351 Depot Street
Asheville, NC 28801
· Phone: [phone],i
Fax: [phone]_68
,Vhole Effluent Toxicity Chain-of-Custody Form
F,ciliry: Tritest, Inc.
· Retec -Beazer
Species: Ceriodaphnia dubia
Test type: Pass/Fail Chronic
NPDES#: .M~
Purcluse order:
Effluent dilnti.on: 90%
Panmctt.r code: TGP3B
Pipe#: Cl!!J County: _W:..;.:::a;.:k.:ce ___ _
~"'--~;~;~,yA~,C"""\)l'~.,.,,,.A.,.A--,:,,Y,..~~=W,l.),l<"'=.,t=~•~
i Sample lnlormatiom (to be c-0mplered by stmple collecoor)
I I I I !
Compo,il• mnple; • ~ Sample location: JZff -Sr/J<DJ
Tune: (.>CQ Volllmo colkcted for testing: 1 . C,-,;,r4;;_ . so,rtdare: 'f~6 oY
T'ime: ,roo Numb<, of contain.,. filkd for ks ting: I End date: y/ '(
Number of &Am.pies per hour:
~[
Total :residual chhrin.e (mg/L):
Chilled dnrlng collection? Tempenture at time of collection (°C):
If chilled, Specify lcmpcrature: Method of transport to laboratory: lfti,o @1VP~
Grab i.·amph!: Comments:
Date: Time:
Note: DO NOT (Ollcct sarrq>les before 8t00 AM. Tr1plt rmse sample container with sample before fIUiug. Compltttl_y fill the! ~Rfllllle cont~inet ~ith no air 5pnce. Pack tbe container completely in ict. The san11)lt must be rtctii!td at< 4,0GC. i S•mplc custody: (robe completed by ,ample collector and facility p<rsonnen
! ! I I
I
Samph!-coUttttJ b}':
Rdinqul.d~d by:
b-zli"'"' (filva ~4._,__[ ~~Y.,_@!
LhV F,f}?.8ql :Rt«i.vtd )y: I QPS
""' .............. ............ ,., .,,., .... ,, .
I _ Ill',;'!.':?' JI
., . ., ................ ,i,J
S,mplc receipt information: (to b• completed by ETS pcn;onn,J)
Custody seals intuct'l: D r7 r.::-i
'" '--lr.-' ~ Sample temperature upon receipt at ETS (°C):
Snmr,IC!S recetv-ed In good co1UUUon?: (3 D
y,. N• Project numbe,: 1205° Samplrnumben {)f O 4 ze. 0 2,.
Coh'lln,nts:
•
•
•
•
0
05-10-'04 10:09 FROM-LLC . 8283509368 A T-724 P03/03 U-341
Shipping address:
351 Depot StJ·eet
Asheville, NC 28801
~ronmental Testing Soluti1Wls, Inc.
Whole Effluent Toxicity Chain-of-Custody Form
Phone: [phone]
Fax: [phone]
Facility: Tritest, Inc. Nl'DBS #: -'-' _____ Pipe#: _. _ County: _W.=akcc·e'----
Retec .. Beazer PurcJuu;e order: ----------------
Species, Ceriodaphnia dubia Effluent dilution: 90 % --------Te" ~'P•: Pass/Fail Chronic P=ter code: TGP3B -------
fo~e<,~Yl'f~Vff•-"""A"J,&(;/.,,,,/v,..,,,..•,.,.,-N,,M;.'•>ff-,J,WH,//,"2<.,,'(,1,'1'---,/f•'"'".l',Y,d/Y~J/l?-,L:<,...,."1'C/?•----
i S•mplc infocm.tion: (to be completed by s,mple collector)
I I
Composite samplel
1
Sample location: s '.]'.) er=~
Swt cLlte: Lj ~ C\ c/ Time: QlJ.00 Vohunc co&cted for testing: ,o
End date: ~[ of':/_ Time: CJ':'loa Nwnber of containers filled for testing: I
Number of samples per hour: I Tol:II residud chlorine (mg/L):
Chilled during collection? r Temperature al time of collection (°C): <:j&~
If ch.illed, specify temperature: .::. '1 o,:, Method of transport to laboratory: ....... ~-c,U,{,rv·t,,
Grab sample: COITllllents:
Date: Time: ----
Nole: DO NOT collect samples before 8:00 AM. Triple ~1;e sample C'ODfainer with sample before filling, Coll1pletely fill
the salT{lle contaiut"r Y\ith no air ii,pa<'e, Pack the container completcly in ice. The sa~,le Irllst be receiYtd at < 4.o•c .
Sample r-t:ctiFt inforrnatio~,: (to be completed by EI'S personnel)
Cus-tody§:tnkinl1ld7: D r7 tS:J
'" L,r,--1 '"~"
Samples received in good condition?: W D
y.,. 11~
. Cormnents:
Sarrqile kmperature upon rtctipl at ETS (°C):
O.f-Ul·O'/ /01[
pw.,.-,,;,,,.
os(.,
Pro.led numlm: I zo:r Sample number: ~ 01 C6Q ,0 /
•
•
April 9, 2004
Ms. Beverly Hudson
Remedial Project Manager
U.S. EPA -Region IV, 11th Floor
North Site Management Branch
61 Forsyth Street, SW
Atlanta, GA 30303
RE: Monthly Progress Report #131
Remedial Action
Koppers Site -Morrisville, North Carolina
Dear Ms. Hudson:
• The RETEC Group, Inc.
3040 William Pill Way
Pittsburgh, PA 15238-1359
[phone] Phone
[phone] Fax
www.retec.com
In accordance with the Unilateral Order, and on behalf of Beazer East, Inc. (Beazer), please find
attached four (4) copies of the March 2004 Monthly Progress Report for Remedial Action at the
Koppers Superfund Site in Morrisville, North Carolina. No exceedences occurred during this
event.
• Should you need additional information regarding this progress report, please call Mike Helbling
at ( 412) 208-8858 or me at [phone].
•
Sincerely,
The RETEC Group, Inc.
~r~~~~
Rita Bauer
Project Geologist
Enclosure
cc: D. Mattison -NC Superfund (2 copies)
J. Garrett -NC Division of Water Quality
M. Matthews -NC Division of Water Quality
P. Kilchenstein -RETEC
H:\Beaz-Ralei\03M-04.doc
L. Faulconer -Wake County
G. Caskey -Enwood Structures
M. Helbling -Beazer
•
•
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MONTHLY PROGRESS REPORT #131
REMEDIAL ACTION
SITE NAME: Koppers Superfund Site
Beazer East, Inc.
Morrisville, NC
USEPA DOCKET NUMBERS: 93-09-C
PERIOD ENDING: March 31, 2004
1. PROGRESS MADE THIS MONTH
Remedial Action (RA) -HABITAT MITIGATION. No activities were conducted this month.
Remedial Action (RA)-GROUNDWATER TREATMENT. The treatment system operated
throughout the month without upset. System performance was monitored on a biweekly basis.
Approximately 50,720 gallons of groundwater were extracted, treated in the treatment plant, and
discharged between March I, 2004 and March 31, 2004. System water samples were collected
on March 5 and March 25, 2004 in accordance with the sampling schedule in the O&M manual.
Samples were submitted to Severn Trent Laboratories, Inc. for laboratory analysis. Note that due
to unusual circumstances, the samples collected on March 5th were not shipped until March 11 th
and thus received on March 12th . This late arrival of the samples caused the semivolatiles to be extracted outside the hold time and therefore, the results should be considered as estimates. The
operations and sampling programs are summarized on the attached Table I.
2.
3.
4.
5.
6.
7.
Remedial Action (RA) -EFFECTIVENESS MONITORING PROGRAM. No activities
were conducted this month.
Remedial Action (RA) -CORRESPONDENCE. None.
PROBLEMS RESOLVED
PROBLEMS ANTICIPATED
UPCOMING EVENTS
PERSONNEL CHANGES
SUBCONTRACTORS
None.
None.
Continue System O&M.
.None.
None.
ANALYTICAL DATA Analytical data from system influent and effluent
sampling received during this period are enclosed and are summarized on Table 2 .
H:\Beaz-Ralci\03M-04.doc
Date Systems Cumulative SV-101 SV-101
Check Effluent Flow Sample Sample
Cves/nol {Gallons) (vesfno) Paramete~
01/06/04 ves 4 321 380 ves Penta 2 4-Dichloro Phenol
01/19/04 ves 4 342 740 no
02/03/04 ves 4 368 380 no
02/17/04 ves 4 392 180 no
03/05/04 ves 4 424 090 no
03/25/04 ves 4,463,830 no
Notes:
Sampling point SV-101 is located before the Carbon Units (pretreatment)
Sampling point SV-304 is located between the Carbon Units
Sampling point SV-305 is lactated after the Carbons Units (post-treatment)
0,4/0912004
F:\PROJECTSIO:l.624\Reports\MonlNy\200,4\0lM-O( Table l.xts
Dioxin
•
Table 1
Groundwater Treatment Operations and
Sampling Program Summary
Koppers Superfund Site
Morrisville, North Carolina
March 2004
Associated SV-304 SV-304
Group Sample Sample
Ives/no I Parameters
1 2 yes Penta 2.4-Dichloro Phenol
no
no
no
no
no
Associated Groups:
Associated SV-305
Group Sample
(ves/no)
1 ves
ves
ves
ves
ves
ves
SV-101 -Group 1 is penta, phenol, and 2,4-dichlorophenol; Group 2 is dioxin
SV-304 -Group 1 is penta, phenol, and 2,4-dichlorophenol
•
G,RETEC
SV-305 Associated
Sample Group
Parameters
Penta, 2,4-Dichloro, Phenol, Dioxin, Chronic
Tox 1 2, 3
Penta, 2.4-Dichloro Phenol • Penta. 2,4-Dichloro Phenol 1
Penta 2.4-Dichloro, Phenol 1
Penta. 2 4-Dichloro Phenol 1
Penta 2,4-Dichloro Phenol 1
•
SV-305 -Group 1 is penta, phenol, and 2,4-dichlorophenol; Group 2 is dioxin and Group 3 is chronic toxicity
1 oft
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Table 2 .RETEC
Groundwater Treatment Analytical Data Summary
Koppers Superfund Site -Morrisville, North Carolina
March 2004
Analytical
Parameter Date Sample Sample
Sample Location Location
Collected SV-101
Pentachlorophenol 01/06/04 33
01/19/04
02/03/04
02/17/04
03/05/04
03/25/04
2.4-Dichlorophenol 01/06/04 <0.60
01/19/04
02/03/04
. 02/17/04
03/05/04
03/25/04
Phenol 01/06/04 <0.60
01/19/04
02/03/04
02/17/04
03/05/04
03/25/04
Chronic Toxicity 01/06/04
Dioxin (2,3,7,8-TCDD) 01/06/04 <2.7
Notes: AU results are in micrograms per liter (µg/L) except dioxin. Dioxin data is in picograms per liter (pg/L).
SV-101 -Before Carbon Units
•sV-304 -Between Carbon Units
0 SV-305 -After Carbon Units
04/09/2004
F:\PROJECTS\03624\Reports\Monthly\2004\03M-04 Table 2.xls
SV-304'
<0.99
<0.20
<0.20
Sample
Location
SV-305"
<1.0
<0.99
<1.0
<0.99
<1.0
<1.0
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
Pass
<2.7
1 of 1
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Leaders in EnvirbnmentalTesting '
ANALYTICAL REPORT
Raleigh, Biweekl.y NPDES
Lot#: C4C120295
Rita Bauer
The RETEC Group Inc
• SEVERN
TREN'.['
STL Pittsburgh
450 William Pitt Way
Pittsburgh, PA 15238
STL
Tel; 412 820 8380 Fax, 412 820 2080
www.stl-inc.com
SEVERN TRKNT LABORATORIES, INC.
Veronica Bortot
Project Manager
March 17, 2004
Severn Trent Laboratories, Inc.
•
Sample Receiving:
CASE NARRATIVE
THE RETEC GROUP
Raleigh, Biweekely NPDES
STL Lot# C4Cl20295
•
STL Pittsburgh, PA received one sample on March 12, 2004. The cooler was received
within the proper temperature range. The sample was received in the laboratory 7 days
after the sample was collected.
If project specific QC was not required for samples contained in this report and batch QC
was completed on these samples, anomalous results will be discussed below.
GC/MS Semivolatiles SIM:
The sample was extracted three days outside the recommended extraction holding time.
Since insufficient sample volume was received to perform a matrix spike and matrix
spike duplicate, a Laboratory Control Sample (LCS) and Laboratory Control Duplicate
(LCD) were performed. All recoveries were within QC limits.
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•
•
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METHODS SUMMARY
C4Cl.20295
ANALYTICAL PREPARATION
PARAMETER METHOD ME=~TH=O=D ____ _
8270C (SIM) SW846 8270C SIM SW846 3520C
References:
SW846 11Test Methods for Ev.3.luating Solid Waste, Physical/Chemical
Methods", Third Edition, November 1986 and its updates .
• •
SAMPLE SUMMARY
C4C120295
WO# SAMPLE# CLIENT SAMPLE ID
GA62P 001 EFF .SV-305
NOTE (SJ :
-The analytical results of lhe wnples listed above are presented on the following pages .
• All calculations are performed before rounding to avoid round-off errors in calculated results.
• Results noted as •ND" were not detected at or above the stated limit.
-This report must not be rcproduc.ed, except in full, without lhe written approval of the laboratory.
-Results for the following panmeters are never reported on a dry weight basis: color, corrosivity, density, flashpoint, ignirability, layers. odor,
paint filter test, pH, porosity pressure, reactivity, redox potential.. specific gravicy, spot tests, solids, solubility, temperature, viscosity, and weigh!.
-
•
SAMPLED SAMP
DATE TIME
03/05/04 14 :00
•
•
•
SEVERN
PROJECT REFERENCE
B 2tV'
STL {LAB) PROJECT MANAGER
RELINQUISHED BY: ISIGNATUREl
\"iMFTY CIJNT/\!Nl:RS
RECEIVED BY: (SIGNATURE)
CMPY ' -· ' 1
ANALYSIS REQUEST AND CHAIN OF CUSTODY RECORD
STL
PROJECT NO.
P.O. NUMBER
DATE
DATE
TIME
TIME
PROJECT LOCATION
[STATE) /V'C-
CONTRACT NO.
MATRIX
TYPE
Serial Number· • 2 5 6 3 S • 0 STl Savannah
5102 LaRoche Avenue
Savannah, GA31404
~ Alternate Laboratory Name/location
l,;{fau-R-6
()
REQUIRED ANALYSIS
NUMBER OF CONTAINERS SUBMITTED
Website: www.st~inc.com
Phone: [phone]
Fax: {912)352-0165
Phone:
Fax:
PAGE. OF
STANDARD REPORT
DELIVERY 0
DATE DUE ____ _
EXPEDITED REPORT
DELIVERY 0
{SURCHARGE)
DATE DUE
NUMBER Of COOLERS SUBMITTED
PER SHIPMENT:
REMARKS
TIME RELINQUISHED BY: ISIGNATUREl DATE TIME
1no
DATE TIME
STL8240-680 (12/02}
•
THE RETEC GROUP INC
Client Sample ID: EFF.SV-305
GC/MS Semivolatiles
•
Lot-Sample# ... : C4Cl20295-001 Work Order# ... : GA62PlAA
Date Received .. : 03/12/04
Analysis Date .. : ·03/16/04
Analysis Time .. : 11:40
Matrix ......... : WATER
Date Sampled ... : 03/05/04 MS Run# ....... :
Prep Date ...... : 03/15/04
Prep Batch# ... : 4075230
Dilution Factor: 1
Method ......... : SW846 8270C SIM
REPOR_TING
PARAMETER RESULT LIMIT UNITS
2,4-Dichlorophenol ND 0.20 ug/L
Pentachlorophenol ND 1.0 ug/L
Phenol ND 0.20 ug/L
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Nitrobenzene-ds 83 (28 -115)
Terphenyl-dl.4 78 (10 -115)
2-Fluorobiphenyl 69 (34 -115)
2-Fluorophenol 55 (24 -115)
Phenol-dS 66 (25 -115)
2,4,6-Tribromophenol 66 (33 -115)
•
•
•
•
•
•
Client Lot# ... : C4Cl20295
MB Lot-Sample#: C4Cl50000-230
Analysis Date .. : 03/16/04
Dilution Factor: l
PARAMETER
2,4-Dichlorophenol
Penta~hlorophenol
Phenol
SURROGATE
Nitrobenzene-ds
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
NOTE (S) :
METHOD BLANK REPORT
GC/MS Semivolatiles
Work Order# .•. : GA6221AA
Prep Date .....• : 03/15/04
Prep Batch# ... : 4075230
REPORTING
RESULT LIMIT
ND Q.20
ND 1.0
ND 0.20
PERCENT RECOVERY
RECOVERY LIMITS
87 (28 -115)
79 (10 -115)
73 (34 -115)
65 (24 115)
79 (25 -115)
69 (33 -115)
Calculations are performed before rounding to avoid round-off errors in calculated results .
•
Matrix ....••... : WATER
Analysis Time .. : 10,13
UNITS METHOD
ug/L SW646 6270C SIM
ug/L SWB46 B270C SIM
ug/L SW646 6270C SIM
• •
LABORATORY CONTROL SAMPLE EVALUATION REPORT
GC/MS semivolatiles
Client Lot # ... -: C4C120295 Work Order# ... : GA8221AC-LCS
GA8221AD-LCSD
Analysis Date .. : 03/16/04
Analysis Time,.: 10:42
Matrix ......... : WATER
LCS Lot-Sample#: C4Cl50000-230
Prep Date ...... : 03/15/04
Prep Batch# ... : 4075230
Dilution Factor: 1
PERCENT RECOVERY RPD
PARAMETER RECOVERY LIMITS RPD LIMITS METHOD
Phenol 84 (10 -131) SW846 8270C SIM
81 (10 -131) 3.5 (0C43) SW846 8270C SIM
Pentachlorophenol 81 (10 -140) SW846 8270C SIM
74 (10 -140) 8.6 (0-56) SW846 8270C SIM
2,4-Dichlorophenol 83 (42 -115) SW846 8270C SIM
80 (42 -115) 3.0 (0-44) SW846 8270C SIM
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Nitrobenzene-dS 85 (28 -115)
85 (28 -115)
Terphenyl-d14 80 (10 -115)
77 (10 -115)
2-Fluorobiphenyl 73 (34 -115)
70 (34 -115)
2-Fluorophenol 64 (24 -115)
60 (24 -115)
Phenol-d5 69 (25 -115)
67 (25 -115)
2,4,6-Tribromophenol 67 (33 -115)
67 (33 -115)
NOTE (S):
Calculations arc performed before rounding to avoid round-<iff errors in calculated results,
•
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•
Leaders in EnJironmental Testing
I
ANALYTICAL REPORT
Raleigh, Biweekly NPDES
Lot#: C4C260206
Rita Bauer
The RETEC Group Inc
•
SEVERN TRENT LABORATORIES, INC.
Veronica Bertot
Project Manager
April 2, 2004
STL Pittsburgh
450 William Pitt Way
Pittsburgh, PA 15238
STL
Tek 412 820 8380 Fax, 412 820 2080
www.st1•inc.com
Severn Trent laboratories, Inc.
STL
NELAC REPORTING:
The foIIIlat and content of the attached report meets NELAC standards and guidelines except as noted in the narrative. The table below
Presents a summary of the certifications held by STI, Pittsburgh, bur primary 8.ccreditation wp:iority;for the Non-potable water and Solid
& Hazardous waste programs is NeW York State DOH. A more detailed parameter list is available upon request. Please ask your project
manager for this information when required.
,,., .. X ~·~ ·.';':.~;_1 ;.'-i}\t i) ;j~i·.~:tj~ft':~'
The codes utll\Zed for program types ai-e described below:
HW Hazardous Waste certification
WW Non-potable Wau:r and/or Wastewater certification .
X Laboratory has some form of certification under the specific program. Many states certify laboratories for specific parameters or
tests within a category. The Information in the table Indicates the lab is certified ln a general category.of testing. Please contact
the laboratciry ff parameter specific certification Information is required.
•
•
•
Sample Receiving:
CASE NARRATIVE
THE RETEC GROUP
Raleigh, Biweekely NPDES
STL Lot# C4C260206
•
STL Pittsburgh, PA received one sample on March 26, 2004. The cooler was received
within the proper temperature range.
If project specific QC was not required for samples contained in this report and batch QC
was completed on these samples, anomalous results will be discussed below.
GC/MS Semivolatiles SIM:
There were no problems associated with the analysis .
• •
METHODSSUMMARY
C4C260206
ANALYTICAL PREPARATION
=P~ARAM==E~T~E~R~-------------------METHOD ~M~E~T~H~O~D ____ _
8270C (SIM) SW846 8270C SIM SW846 3520C
References:
SW846 11Test Methods for Evaluating Solid Waste, Physical/Chemical
Methodsn, Third Edition, November 1986 and its updates.
•
•
•
•
•
•
•
SAMPLE SUMMARY
C4C260206
WO# SAMPLE# CLIENT SAMPLE ID
GClMP 001 SV-305
NOTE(S)
• The analyt!cal results of the samples listed above are presented on the following pages.
• All calculations arc performed before rounding to avoid round-off errors in calculated results.
-Results noted as "ND" were not detected at or above the stated limit.
-This repon must not be reproduced, except in full, without the written approval of the laboratory.
•
-Results for the following parameters are never reported on a dry weight basis: color, corrosivity, density, flashpoint, ignitab!lity, layers, odor,
paint filter rest, pH, poros.ity pressure, reactivity, redox potential, specific gravity, spot tests, solids, solubility, temperature, viscosity, and weight .
SAMPLED SAMP
DATE TIME
03/25/04 14,10
SEVERN
TRENT STL Chain of
Custody Record Severn Trent Laboratories, Inc.
STL 4124 (0901)
Client Project Manager Date Cham of Custody Number
\2el-«--, Qi~ 'L30-,\UY 3!26lo+ , 127622
Address Telephone Number (Area Code)/Fax Number Lab Number I l
l0Z'2-2"· Ne_ 54, Sw+e--1 oo t\1-0. '31-l l 4'22.. .Page of
City ls~,~1~2> Site Contact Lab Contact Analysis (Attach list if
nw+v.u-vi A,i+ill more s ace is needed
Project Name and Location {Slate) Carrier/Waybill Number .... µ
13~~-Wi ,( i Special Instructions/
Contract/Purchase Order/QuotrNJo. S~e,\e..v\;1 Containers & ~ Conditions of Receipt
13B,t\-<'l:;-::/--os'l52t..1--oq ,~ Matrix '-..;
c:::," = ~1.-e.. Preservatives 4.
Sample I.D. No. and Description Date Time l ! ~ l i 8 ~ ~ l/a ~ (Containers for each sample may be combined on one line) ~ ~ ~ ~ ~~
<,v-?oS-,t>.<'P--1 l4tQ 'K 'X 'r-{..
.
Possible Hazard Identification l Sample Disposal
~sposa/ By L.ab.
(A fee may be assessed 11 samples are retained
D Non-Hazard D Flammable D Skin Irritant D Poison B ~nknown O Return To Client 0 Archive-For Months longer than 1 month)
Turn Around Time Required ' ex; Reqwrements (SpeC1fy)
D 24 Hours D 4Bt:ours □ 7 Days □ 14 Days D 21 Days ·~ther ~
,. Relinquished By ( -0--"\\_-Q(} 1;r ,,;\ (me '3 ::.. o4 ·'": , 1. Rece,c8:d (;,e
j Date
1
Time
2. Relinquished By /Dafe
1
Time 2. Received By '
1
~ate
1
Time
3. Relinqwshed By j Date ) Time 3. Receiv/.,A. _J A IS'~ z.c.--0--r I Ti7a u o ,,y y.___ ;
Commenis
-/4,/
HITE -Returned to Client with Report; CANARY -Stays wilh the Sample; PINK -Field Copy •
•
•
•
•
Lot-Sample# ... , C4C260206-001
Date Sampled ... : 03/25/04
Prep Date ...... : 03/31/04
Prep Batch# ... , 4091195
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-dS
Terphenyl-d14
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol •
•
•
TIIB RETEC GROUP INC
Client Sample ID, SV-305
GC/MS Semivolatiles
Work Order# ... , GClMPlAA
Date Received .. , 03/26/04
Analysis Date .. , 04/01/04
Analysis Time .. , 17,33
Matrix ......... : WATER
MS Run # ....... ,
Method ......... , SW846 8270C SIM
REPORTING
RESULT LIMIT UNITS
ND 0.20 ug/L
ND 1. 0 ug/L
ND 0.20 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
80 (28 -115)
Bl (10 -115)
68 (34 -115)
53 (24 -115)
55 (25 -115)
71 (33 -115)
• •
METHOD BLANK REPORT
GC/MS Semivolatiles
Client Lot # ... : C4C260206 Work Order # ... : GC8MJ1AA Matrix ......... , WATER
MB Lot-Sample#, C4C310000-195
Prep Date ...... : 03/31/04
Analysis Date .. , 04/01/04 Prep Batch# ... , 4091195
Dilution Factor: 1
PARAMETER
Phenol
2,4-Dichlorophenol
Pentachlorophenol
SURROGATE
Nitr9benzene-dS
Terphenyl-d14
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
NOTE(S ,
RESULT
ND
ND
ND
PERCENT
RECOVERY
82
77
69
63
62
61
Galculatiom are performed before rounding 10 avoid round-off errors in calculated results.
REPORTING
LIMIT
0.20
0.20
1.0
RECOVERY
LIMITS
(28 -115)
(10 -115)
(34 -115)
(24 -115)
(25 -115)
(33 -115)
Analysis Time .. : 09: 05
UNITS METHOD
ug/L SW846 8270C SIM
ug/L SW846 8270C SIM
ug/L SW846 8270C SIM
•
•
• •
• LABORATORY CONTROL SAMPLE EVALUATION REPORT
Client Lot ff ... : C4C260206
LCS Lot-Sample#: C4C310000-195
Prep Date ...... : 03/31/04
Prep Batch# ... : 4091195
Dilution Factor: 1
PARAMETER
Phenol
Pentachlorophenol
2,4-Dichlorophenol
SURROGATE
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
GC/MS Semivolatiles
Work Order# ... : GCBMJlAC
Analysis Date .. : 04/01/04
Analysis Time .. : 09 :33
PERCENT RECOVERY
RECOVERY LIMITS
63 (10 -131)
95 (10 140)
60 (42 115)
PERCENT
RECOVERY
71
64
60
52
51
55
NOTB(S):
• Calculations are performed before rounding to avoid round-off errors in calculated results .
•
Matrix ......... : WATER
METHOD
SW846 8270C SIM
SW846 8270C SIM
SW846 8270C SIM
RECOVERY
LIMITS
(28 -115)
(10 -115)
(34 -115)
(24 -115)
(25 -115)
(33 -115)
• •
MATRIX SPIKE SAMPLE EVALUATION REPORT
GC/MS Semivolatiles
Client Lot# ... : C4C260206 Work Order# ... : GClPLlAC-MS Matrix ......... : WATER
MS Lot-Sample#: C4C260212-007
Date Sampled ... : 03/25/04
GClPLlAD-MSD
Date Received .. : 03/26/04
Analysis Date .. : 04/01/04
Analysis Time .. : 14,15
MS Run# ....... : 4091065
Prep Date ...... : 03/31/04
Prep Batch# ... : 4091195
Diluticin Factrir: O. 97
PERCENT RECOVERY
PARAMETER RECOVERY LIMITS
Phenol 61 (10 -131)
69 (10 -131)
Pentachlorophenol 142 a (10 -140)
169 a (10 -140)
74 p (42 -llS)
PERCENT
SURROGATE RECOVERY
Nitrobenzene-d5 80
85
Terphenyl-d14 71
73
2-Fluorobiphenyl 66
69
2-Fluorophenol so
52
Phenol-d5 57
53
2,4,6-Tribromophenol 72
73
NOTE(S):
Ca1culatlons arc performed before rounding 10 avoid round-off errors in caJculated results.
a Spiked analytc recovery Is outalde stated control limits.
p Relative percent difference (RPD) is out.side stated control limits.
RPD
RPD LIMITS METHOD
SW846 B270C SIM
12 (0-43) SW846 8270C SIM
SW846 8270C SIM
3.3 ( 0-56) SW846 8270C SIM
200 (0-44) SW846 8270C SIM
RECOVERY
LIMITS
(28 -ll5)
(28 -llS)
(10 -llS)
(10 -115)
(34 -115)
(34 -115)
(24 -ll5)
(24 -115)
(25 -115)
(25 -115)
(33 -ll5)
(33 -115)
•
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•
March I 0, 2004
Ms. Beverly Hudson
Remedial Project Manager
U.S. EPA -Region IV, I Ith Floor
No1th Site Management Branch
61 Forsyth Street, SW
Atlanta, GA 30303
RE: Monthly Progress Report #130
Remedial Action
• The RETEC Group, Inc.
3040 William Pitt Way
Pittsburgh, PA 15238-1359
[phone] Phone
li=~i=::~:;:-~--;:~~=.;,14~12;:,I ;;826-3409 Fax
~(.~, ~ :,::.~ D ,_
SUPERFUIVNffi101~
Koppers Site -Morrisville, North Carolina
Dear Ms. Hudson:
In accordance with the Unilateral Order, and on behalf of Beazer East, Inc. (Beazer), please find
attached four ( 4) copies of the February 2004 Monthly Progress Report for Remedial Action at
the Koppers Superfund Site in Morrisville, North Carolina. No exceedences occurred during this
event.
• Should you need additional information regarding this progress report, please call Mike 1-lclbling
at [phone] or me at [phone].
Sincerely,
The RETEC Group, Inc.
'1kur1ee,'4_/JJ,/!/(➔
Rita Bauer ·
Project Geologist
/
Enclosure
cc: D. Mattison -NC Superfund (2 copies)
J. Garrett -NC Division of Water Quality
M. Matthews -NC Division of Water Quality
P. Kilchenstein -RETEC
1-1:\Bcaz-Ralci\02M-04.doc
L. Faulconer -Wake County
G. Caskey -Enwood Structures
M. 1-lelbling -Beazer
•
• •
MONTHLY PROGRESS REPORT #130
REMEDIAL ACTION
SITE NAME: Koppers Superfund Site
Beazer East, Inc.
Morrisville, NC
USEPA DOCKET NUMBERS: 93-09-C
PERIOD ENDING: February 29, 2004
I. PROGRESS MADE THIS MONTH
Remedial Action (RA) -HABITAT MITIGATION. No activities were conducted this month.
Remedial Action (RA)-GROUNDWATER TREATMENT. The treatment system operated
throughout the month without upset. System performance was monitored on a biweekly basis.
Approximately 54,640 gallons of groundwater were extracted, treated in the treatment plant, and
discharged between February I, 2004 and February 29, 2004. System water samples were
collected on February 3 and February 17, 2004 in accordance with the sampling schedule in the
O&M manual. Samples were submitted to Severn Trent Laboratories, Inc. for laboratory
• analysis. The operations and sampling programs are summarized on the attached Table I.
•
2.
3.
4.
5.
6.
Remedial Action (RA) -EFFECTIVENESS MONITORING PROGRAM. No activities
were conducted this month.
Remedial Action (RA) -CORRESPONDENCE. None.
PROBLEMS RESOLVED
PROBLEMS ANTICIPATED
UPCOMING EVENTS
PERSONNEL CHANGES
SUBCONTRACTORS
None.
None.
Continue System O&M.
None.
None.
7. ANALYTICAL DAT A Analytical data from system influent and effluent
sampling received during this period are enclosed and are summarized on Table 2 .
H:\Bcaz-Ralci\02M-04.doc
Date Systems Cumulative SV-101 SV-101
Check Effluent Flow Sample Sample
(yes/no) {Gallons) (yes/no) Parameters
01/06/04 ves 4 321 380 ves Penta. 2.4-Dichloro, Phenol
01/19/04 ves 4,342 740 no
02/03/04 ves 4 368,380 no
17/04 ses 4 392 180 no
•
Notes:
Sampling point SV-101 is located before the Carbon Units (pretreatment)
Sampling point SV-304 is located between the Carbon Units
Sampling point SV-305 is lactated after the Carbons Units (post-treatment)
03110/2004
F:\PROJECTS\03624\RepGttSIMonthly\2004\02M--O-I Table 1 .xis •
Dioxin
Table 1
Groundwater Treatment Operations and
Sampling Program Summary
Koppers Superfund Site
Morrisville, North Carolina
February 2004
Associated SV-304 SV-304
Group Sample Sample
(yes/no) Parameters
1 2 ves Penta 2 4-Dichloro Phenol
no
no
no
Associated Groups:
Associated SV-305
Group Sample
(yes/no)
1 ves
ves
"es
ves
SV-101 -Group 1 is penta, phenol, and 2,4-dichlorophenol; Group 2 is dioxin
SV-304 -Group 1 is penta, phenol, and 2,4-dichlorophenol
.RETEC
SV-305 Associated
Sample Group
Parameters
Penta, 2,4-Dichtoro, Phenol, Dioxin, Chronic
Tox 1. 2 3
Penta, 2 4-Dichloro Phenol 1
Penta 2 4-0ichloro Phenol 1
Penta 2 4-0ichloro Phenol 1
SV-305 -Group 1 is penta, phenol, and 2,4-dichlorophenol; Group 2 is dioxin and Group 3 is chronic toxicity
1 cl 1 • •
•
•
•
• •
Table 2 ♦RETEC
Groundwater Treatment Analytical Data Summary
Koppers Superfund Site -Morrisville, North Carolina
February 2004
Analytical
Parameter Date Sample
Sample Location
Collected SV-101
Pentachlorophenol 01/06/04 33
01/19/04
02/03/04
02/17/04
2.4-Dichloroohenol 01/06/04 <0.60
01/19/04
02/03/04
02/17/04
Phenol 01/06/04 <0.60
01/19/04
02/03/04
02/17/04
Chronic Toxicity 01/06/04
Dioxin (2,3,7,8-TCDD) 01/06/04 <2.7
Notes: All results are in micrograms per hter (pg/L) except dmxm. Dioxin data 1s in picograms per hter {pg/L) .
SV-101 -Before Carbon Units
*SV-304 -Between Carbon Units
**SV-305 -After Carbon Units
03/10/2004
F:\PROJECTS\03624\Reports\Monthly\2004\02M-04 Table 2.xls
Sample
Location
SV-304'
<0.99
<0.20
<0.20
Sample
Location
SV-305"
<1.0
<0.99
<1.0
<0.99
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
Pass
<2.7
1 of 1
•
•
•
•
. •leaders in E~-Vironhiental Testing ;. -,, '
• , I , • ~~' ,• • ,. •• :i
•
ANALYTICAL REPORT
Raleigh, Biweekly NPDES
Lot#: C4B040123
Rita Bauer
The RETEC Group Inc
SEVERN TRENT LABORATORIES, INC.
Veronica Bortot
Project Manager
February 9, 2004
. ~ ' ' SEVERN
STL Pittsburgh
450 William Pitt Way
Pittsburgh, PA 15238
STL
Tel, 412 820 8380 Fax, 412 820 2080
www.stl-inc.com
Severn Trent Laboratories, Inc.
STL
NELAC REPORTING:
The fol'Il1at and content of the attached report meets NELAC standards and guidelines except as noted in the narrative. The table below
presents a summary of the certifications held by STL Pittsburgh. Our primary accreditation authority for the Non~potable water and Solid
& Hazardous waste programs is NeW York State DOH. A more detailed parameter list is available upon request. Please ask your project
manager for this information when required.
The codes utiliZ:ed for program types are described below:
HW Hazardous Waste cenification
WW Non•potable Water and/or Wastewater certification
X Laboratory has some form of certification under the specific program. Many states certify laboratories for specific parameters or
tests within a category. The information in the table indicates the lab is certified in a genera! category of testing. Please contact
the laboratory if parameter specific certification infonnation is required.
•
•
•
•
Sample Receiving:
CASE NARRATIVE
THE RETEC GROUP
Raleigh, Biweekely NPDES
STL Lot# C4B040123
•
STL Pittsburgh, PA received samples on February 4, 2004. The cooler was received
within the proper temperature range.
If project specific QC was not required for samples contained in this report and batch QC
was completed on these samples, anomalous results will be discussed below.
GC/MS Semivolatiles SIM:
Since insufficient sample volume was received to perform a matrix spike and matrix
spike duplicate, a Laboratory Control Sample (LCS) and Laboratory Control Duplicate
(LCD) were performed. All recoveries were within QC limits .
------------------------------------------------• •
METHODSSUMMARY
C4B040123
ANALYTICAL PREPARATION
PARAMETER METHOD METHOD --------
8270C (SIM) SW846 8270C SIM SW846 3520C
References:
SW846 "Test Methods for Evaluating Solid Waste, Physical/Chemical
Methods 11
1 Third Edition, November 1986 and its updates.
•
•
•
•
• •
SAMPLE SUMMARY
C4B040123
WO# SAMPLE# CLIENT SAMPLE ID
FBlBX 001 EFF/SV-305
NOTE (S) :
• The analytical results of the samples listed above are presented on the following pages.
-All calculations are performed before rounding to avoid round-off errors in calculated results.
• Results noted as "ND" were not detected at or above the stated limi1.
• This report must not be reproduced, except in full, without the written approval of the laboratory.
• Results for the following parameters are never reported on a dry weight basis: color, corrosivity, density, flashpoint, ignitability, layers, odor,
paint filter test, pH, porosity pressure, reactivity, redox polential, specific gravity, spot tests, solids, solubility, temperature, viscosity, and weight.
•
•
SAMPLED
DATE
SAMP
TIME
02/03/04 08 :50
Chain of
Custody Record
STL 4124 (0901) .
Che"OIJ Jl,?__, I~-,:,,.,.-/'--'·-"]~
Address golt.,,v A-v-e. .?~o c,rv~c,,,af l,,;4-j2@17f~
Project Name and Location (State)
'R..e.a--z.7 -03<oJ.'-f -o9 f,
ContracVPurchase Order/Quote fl!o.
Sample 1.0. No. and Description Date (Containers for each sample may be combined on one fine)
EF-Y/ ,SV-:sc:25 _,__ <,'-f
Possible Hazard Identification
D Non-Hazard D Rammable D Skin Irritant D Poison a
Tum Around Time Required I
SEVERN
TRENT STL STL Pittsburgh
Severn Trent Laboratories, Inc.
450 William Pitt Way, Bldg. 6
Pittsburgh, PA 15238
. ..
Project~.£~ D~~r ,</ Chain of Custody Number 184217
Telephone Number (Area Code)/Fax Number LE.b Number l I 97'1 -'!71-l'-/'),::J Page of
Site Contact Lab Contact Analysis (f:\ttach list if
more s ace is needed
Cf;f ar;mber . J i Special Instructions/
Containers & Conditions of Receipt Matrix Preservatives \;;
' ~ • " , "' ~ Time i J ~ "-i.l i G 0 ~o s § ~ ~ ~~ ~ ' ,
.--9.Co f, )( :+. .
.
· I Sample Disposal (A fee may be assessed if samples are retained
ifunknown D Rerum To Client ~isposal By Lab D Archive For Months longer than 1 month)
QC Requirements (Specify)
D 24 Hours D 14 Days D 21 Days ~ther j7:{)
do
2. Relinquished By
3. Relinquished By
1
Date
1
Time
Comments
•
DISTRIBUTION -E Relumed lo Cl,enl w,lh Repon CANARY -Stays with the Sample; PINK -Field Copy •-------•<----I
•
•
•
THE RETEC GROUP INC
Client Sample ID: EFF/SV-305
GC/MS Semivolatiles
•
Lot-Sample# ... : C4B040123-001 Work Order# ... : F818X1AA
Date Received .. : 02/04/04
Analysis Date .. : 02/06/04
Analysis Time .. : 13:57
Matrix ......... : WATER
Date Sampled ... : 02/03/04 MS Run# ....... :
Prep Date ...... : 02/05/04
Prep Batch# ... : 4036323
Dilution Factor: 1
Method ......... : SW846 8270C SIM
REPORTING
PARAMETER RESULT LIMIT UNITS
2,4-Dichlorophenol ND 0.20 ug/L
Pentachlorophenol ND 1.0 ug/L
Phenol ND 0.20 ug/L
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Nitrobenzene-ds 72 ( 28 -115)
Terphenyl-dl4 83 (10 -115)
2-Fluorobiphenyl 76 (34 -115)
2-Fluorophenol 59 (24 -115)
Phenol-d5 63 (25 -115)
2,4,6-Tribromophenol 74 (33 -115)
•
Client Lot# ... : C4B040123
MB Lot-Sample#: C4B050000-323
Analysis Date .. : 02/06/04
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-d5
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phen.ol-d5
2,4,6-Tribromophenol
NOTE(S):
•
METIIOD BLANK REPORT
GC/MS Semivolatiles
Work Order# ... : F84RX1AA
Prep Date ...... : 02/05/04
Prep Batch# ... : 4036323
REPORTING
RESULT LIMIT UNITS
ND• 0.20 ug/L
ND 1.0 ug/L
ND 0.20 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
70 (28 -115)
77 (10 -115)
74 (34 -115)
57 (24 -115)
61 (25 -115)
70 (33 -115)
Calculations are perfonned before rounding co avoid round-off errors in calculated results.
•
Matrix ......... : WATER
Analysis Time .. : 12:28
METHOD
SW846 8270C SIM
SW846 8270C SIM
SW846 8270C SIM
•
•
•
• •
LABORATORY CONTROL SAMPLE EVALUATION REPORT
GC/MS Semivolatiles
Client Lot# ... : C4B040123 Work Order# ... : F84RX1AC-LCS
F84RX1AD-LCSD
Analysis Date .. : 02/06/04
Analysis Time .. : 12:58
Matrix ......... : WATER
LCS Lot-Sample#: C4B050000-323
Prep Date ...... : 02/05/04
Prep Batch# ... : 4036323
Dilution Factor: 1
PERCENT RECOVERY RPD
PARAMETER RECOVERY LIMITS RPD LIMITS METHOD
Phenol 70 (10 -131) SW846 8270C SIM
69 (10 -131) 1.4 (0-43) SW846 8270C SIM
Pentachlorophenol 86 (10 -140) SW846 8270C SIM
91 (10 -140) 5.3 (0-56) SW846 8270C SIM
2,4-Dichlorophenol 73 (42 -115) SW846 8270C SIM
76 (42 -115) 3.6 (0-44) SW846 8270C SIM
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Nitrobenzene-dS 68 (28 -115)
68 (28 -115)
Terphenyl-dl4 72 (10 -115)
76 (10 -ll5)
2-Fluorobiphenyl 68 (34 -115)
70 (34 -ll5)
2-Fluorophenol 51 (24 -115)
53 (24 -115)
Phenol-d5 52 (25 -115)
57 (25 -115)
2,4,6-Tribromophenol 68 (33 -115)
71 (33 -115)
NOTE(S):
Calculations are performed before rounding to avoid round-off errors in calculated results.
•
•
•
, Leaders ,in En_VirOnmentaliTesting'f,~· •• . ' ' . . . ' ~ .
•
ANALYTICAL REPORT
Raleigh, Biweekly NPDES
Lot#: C4B180232
Rita Bauer
The RETEC Group Inc
SEVERN TRENT LABORATORIES, INC.
Veronica Bertot
Project Manager
February 24, 2004
SEVERN
STL Pittsburgh
450 William Pitt Way
Pittsburgh, PA 15238
STL
Tel, 412 820 8380 Fax, 412 820 2080
www.stl-inc.com
Severn Trent Laboratories, Inc.
STL
NELAC REPORTING:
The foTJDat and content of the attached report meets NELAC standards and guidelines except as noted in the narrative. The table below
presents a summary of the certifications held by STL Pittsburgh. Our primary accreditation authority for the Non-potable water and Solid
& Hazardous waste programs is NeW York State DOH. A more detailed parameter list is available upon request. Please ask your project
manager for this information when required.
The codes utilii:ed for program types are described below:
H'W Hazardous Waste certification
v.;rw Non-potable Water and/or Waste~ater certification
X Laboratory has some form of certification under the specific program. Many states certify laboratories for specific parameters or
tests within a category. The information in the table indicates the lab is certified in a general category of testing. Please contact
the laboratory if parameter specific c~rtification information is required.
•
•
• CASE NARRATIVE
THE RETEC GROUP
Raleigh, Biweekely NPDES
STL Lot# C4B 180232
•
Sample Receiving:
STL Pittsburgh, PA received one sample on February 18, 2004. The cooler was received
within the proper temperature range.
If project specific QC was not required for samples contained in this report and batch QC
was completed on these samples, anomalous results will be discussed below.
GC/MS Semivolatiles SIM:
The reporting limits were adjusted due to the amount of sample used in the extraction
procedure.
Since insufficient sample volume was received to perform a matrix spike and matrix
spike duplicate, a Laboratory Control Sample (LCS) and Laboratory Control Duplicate
(LCD) were performed. All recoveries were within QC limits .
--------------------------------------------------• •
METHODS SUMMARY
C4BJ.80232
ANALYTICAL PREPARATION
~P~ARAM==E~T~E~R,_ _____________________ METHOD _M_E_T_H~O_D ____ _
. 8270C (SIM) SW846 8270C SIM SW846 3520C
References:
SW846 "Test Methods for Evaluating Solid Waste, Physical/Chemical
Methods", Third Edition, November 1986 and its updates.
•
•
•
•
• • SAMPLE SUMMARY
C4Bl80232
!'.!Q_JL SAMPLE# CLIENT SAMPLE ID
F9Q82 001 EFF/SV-305
NOTE(S):
• Tiie analytic.al results of the samples listed above are presented on U1c following pages.
-All calculations are performed before rounding to avoid round-off errors in calculated results,
• Results noted as "ND" were not detected al or above the stated limit.
• This repon must not be reproduced, e,.cept in full, without the written approval of the laboratory.
• Results for the following parameters are never reponcd on a dry weight basis: color, corrosivity, density, flashpoint, ignit.ability, layers, odor,
paint filter test, pH, porosity pressure, reactivity, redox potential, specific gravity, spot t~sts, solids, solubility, temperature, viscosity, and weight.
SAMPLED
DATE
SAMP
TIME
02/17/04 09:50
SEVERN
TRENT STL STL Pittsburgh Chain of
Custody Record Severn Trent Laboratories, Inc.
450 William Pitt Way, Bldg. 6
Pittsburgh, PA 15238
:;11.,1124 (0901)
Project MJ1'ager D . . ~ ~ r> ""-'t.,K,,..,.-
TelephOne Number (Area Code)/Fax Number
q,7~ .-? 7 /-f ;:;iJ-
Site Conract Lab Contact
-Project Name and Location (State) Carrier/Vvaybi/1 Num~er ~w
--~T <',_·. v'.,:c,1='-'-i4-"'17c.c,__,_____ 7---"()'-"JC...:6::..,· )'---/'--·· _--_,,O:..,'}c_:b_· ------'---~---------------l·~'?;
Cnntract/Purctwse Order/Quote No. Containers & ~ ~
Matrix Preservatives ~ ~
-----------------,------,----+--r-r--r--r-r-r--r-.--r--,--r-1.,._ ! ~ 8 -f5 lfs I~
-
Sample I. D. No. and Description
1(:nn/iliners for each sample may be combined on one line)
£ i£ ,c )<, tJ -l v ,;-
···-{
('11ss1ble Hazard ldenlificalion
D Non•Hazard D Flammable 0 Skin Irritant
rwn A1ound Time Required
Date Time j ~ ~ . s • . < "'
:1. I, 1 I o'-1 l>'19J i
' .
I Sample Disposal
0 Poison B '\61 Unknown D Return To Client
D 24 Hours D 48Hours D 7 Days D 14 Days D 21 Days /her Jt/)
I. Relinquished By
2 nelinquiSl,ed By Time
3. Relinquished By l Date I Time
C01111nents
UISTR/BUTJON: /TE -Returned to Client with Report: CANARY· Stays with the Sample; PINK -Field Copy
_. _,_ ~ ~ i ~~ IV-
~osa/ByLab 0 Archive For
J QC Reqwremenrs (Specify)
J
Date
::i
Lab t(.umber
Analysis (Attach /isl if
more soace is neededl
Page L of I
Special Instructions/
~onditions of Receipt
(A fee may be assessed if samples are.rerained
Monrhs longer than I month)
I
•
•
•
THE RETEC GROUP INC
Client Sample ID: EFF/SV-305
GC/MS Semivolatiles
•
Lot-Sample# ... : C4Bl80232-001 Work Order# ... : F9Q821AA
Date Received .. : 02/18/04
Analysis Date .. : 02/20/04
Analysis Time .. : 10:21
Matrix ......... : WATER
Date Sampled ... : 02/17/04 MS Run# ....... :
Prep Date ...... : 02/19/04
Prep Batch# ... : 4051096
Dilution Factor: 0.99
Method ......... : SW846 8270C SIM
REPORTING
PARAMETER RESULT LIMIT UNITS
2,4-Dichlorophenol ND 0.20 ug/L
Pentachlorophenol ND 0.99 ug/L
Phenol ND_ 0.20 ug/L
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Nitrobenzene-dS 69 (28 -115)
Terphenyl-dl4. . 86 (10 -115)
2-Fluorobiphenyl 70 (34 -115)
2-Fluorophenol 56 (24 -115)
Phenol-d5 60 (25 -115)
2,4,6-Tribrornophenol 72 (33 -115)
----:---------------------------------------------------•
Client Lot# ... , C4Bl80232
MB Lot-Sample#, C4B200000-096
Analysis Date .. , 02/20/04
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-dS
Terphenyl-d14
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
NOTE (S) :
METIIOD BLANK REPORT
GC/MS Semivolatiles
Work Order # .•. : F'9WCW1AA
Prep Date ...... : 02/19/04
Prep Batch # ••• ,. 4051096
REPORTING
RESULT LIMIT
ND 0.20
ND 1.0
ND 0.20
PERCENT RECOVERY
RECOVERY LIMITS
75 (28 -115)
86 (10 -115)
74 (34 -115)
61 (24 -115)
65 (25 -115)
73 (33 -115)
Calculations are performed before rounding to avoid round•off errors in calculated. results.
•
•
Matrix ......... : WATER
Analysis Time .. , 09:51
UNITS METHOD
ug/L SW846 8270C SIM
ug/L SW846 8270C SIM
ug/L SW846 8270C SIM
•
••
•
• •
LABORATORY CONTROL SAMPLE EVALUATION REPORT
GC/MS Semivolatiles
Client Lot# ... : C4Bl80232 Work Order# ... : F9WCW1AC-LCS
F9WCW1AD-LCSD
Analysis Date .. : 02/20/04
Analysis Time .. : 08:52
Matrix ......... : WATER
LCS Lot-Sample#: C4B200000-096
Prep Date ...... : 02/19/04
Prep Batch# ... : 4051096
Dilution Factor: l
PARAMETER
Phenol
Pentachlorophenol
2,4-Dichlorophenol
SURROGATE
Nitrobenzene-ds
Terphenyl-d14
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
NOTE (S) :
PERCENT
RECOVERY
75
82
74
82
82
91
RECOVERY
LIMITS
(10 -131)
(10 -131)
(10 -140)
(10 -140)
(42 -115)
(42 -115)
PERCENT
RECOVERY
71
80
81
87
74
80
59
61
62
68
73
81
Ca\rulations are performed before rounding to avoid round-off errors in calculated results.
RPD
RPD LIMITS METHOD
SW846 8270C SIM
8.2 (0-43) SW846 8270C SIM
SW846 8270C SIM
9.4 ( 0-56) SW846 8270C SIM
SW846 8270C SIM
10 (0-44) SW846 8270C SIM
RECOVERY
LIMITS
(28 -115)
(28 -115)
(10 -115)
(10 -115)
(34 -115)
(34 -115)
(24 -115)
(24 -115)
(25 -115)
(25 -115)
(33 -115)
(33 -115)
•
•
•
February 9, 2004
Ms. Beverly Hudson
Remedial Project Manager
U.S. EPA-Region IV, I Ith Floor
North Site Management Branch
61 Forsyth Street, SW
Atlanta, GA 30303
RE: Monthly Progress Report #129
Remedial Action
•
\OJ,~@IJ~·\}~1
l\f\l JAN l 6 2004 I~
SUPERfUNO SEC1\0N
The RETEC Group, Inc.
300 Baker Avenue, Suite 302
Concord, MA 01742
RETE(
[phone] Phone
[phone] Fax
www.retec.com
Koppers Site -Morrisville, North Carolina
Dear Ms. Hudson:
In accordance with the Unilateral Order, and on behalf of Beazer East, Inc. (Beazer), please find
attached four (4) copies of the January 2004 Monthly Progress Report for Remedial Action at the
Koppers Superfund Site in Morrisville, North Carolina. No exceedences occurred during this
event.
Should you need additional information regarding this progress report, please call Mike Helbling
at [phone] or me at [phone].
Sincerely,
The RETEC Group, Inc.
/4/4~
Rita efauer
Project Geologist
Enclosure
cc: D. Mattison -NC Superfund (2 copies)
L. Faulconer -Wake County
G. Caskey -Enwood Structures
M. Helbling -Beazer
F:\I' ROJ ECTS\03624\Rcports\Monthly\2004\0 I M-04.doc
D. Hails -EAP Industries, Inc.
J. Garrett -NC Division of Water Quality
M. Matthews -NC Division of Water Quality
P. Kilchenstein -RETEC
•
•
•
• •
MONTHLY PROGRESS REPORT #129
REMEDIAL ACTION
SITE NAME: Koppers Superfund Site
Beazer East, Inc.
Morrisville, NC
USEPA DOCKET NUMBERS: 93-09-C
PERIOD ENDING: January 31, 2004
1. PROGRESS MADE THIS MONTH
Remedial Action (RA) -HABITAT MITIGATION. No activities were conducted this
month.
Remedial Action (RA) -GROUNDWATER TREATMENT. The treatment system operated
throughout the month without upset. System performance was monitored on a biweekly basis.
Approximately 45,530 gallons of groundwater were extracted, treated in the treatment plant, and
discharged between January 1, 2004 and January 31, 2004. System water samples were
collected on January 6 and January 19, 2004 in accordance with the sampling schedule in the
O&M manual. Samples were submitted to Severn Trent Laboratories, Inc. for laboratory
analysis. The chronic toxicity samples were collected the week of January 5, 2004. The
operations and sampling programs are summarized on the attached Table I.
2.
3.
4.
5.
6.
7.
Remedial Action (RA) -EFFECTIVENESS MONITORING PROGRAM. No activities
were conducted this month.
Remedial Action (RA) -CORRESPONDENCE. None.
PROBLEMS RESOLVED
PROBLEMS ANTICIPATED
UPCOMING EVENTS
PERSONNEL CHANGES
SUBCONTRACTORS
None.
None.
Continue System O&M.
None.
None.
ANALYTICAL DATA Analytical data from system influent and effluent
sampling received during this period are enclosed and are summarized on Table 2 .
F:\PROJ ECTS\03624\Rcports\Monlh ly\2004\0 I M-04 .doc
•
Date Systems Cumulative SV-101 SV-101
Check Effluent Flow Sample Sample
· (';c~fnoJ (Gallons) (yes/no) Parameters
01/06/0,: ves 4 321,380 ves Penta 2 4-Dichloro. Phenol
~-i/i9/04 ves 4 342,740 no
Notes:
· Sampling point SV-101 is located before the Carbon Units (pretreatment)
Sampling point SV-304 is located between the Carbon Units
Sampling point SV-305 is lactated after the Carbons Units {post-treatment)
211012004
F.IPROJECTSl03624\Reports\Monlhl)"-200-tl01M-04 Table bis
Dioxin
•
Table 1
Groundwater Treatment Operations and
Sampling Program Summary
Koppers Superfund Site
Morrisville, North Carolina
January 2004
Associated SV-304 SV-304
Group Sample Sample
(ves/no) Parameters
1 2 ves Penta, 2,4-Dichloro Phenol
no
Associated Groups:
Associated SV-305
Group Sample
(yes/no)
1 ves
ves
SV-101 -Group 1 is penta, phenol, and 2,4-dichlorophenol; Group 2 is dioxin
SV-304 -Group 1 is penta, phenol, and 2,4-dichlorophenol
•
.RETEC
SV-305 Associated
Sample Group
Parameters
Penta, 2,4-Dichloro, Phenol, Dioxin, Chronic
Tex 1. 2. 3
Penta 2,4-Dichloro, Phenol 1
•
SV-305 -Group 1 is penta, phenol, and 2,4-dichlorophenot: Group 2 is dioxin and Group 3 is chronic toxicity
1 of 1
•
•
•
• •
Table 2
Groundwater Treatment Analytical Data Summary
Koppers Superfund Site -Morrisville, North Carolina
January 2004
Analytical
Parameter Date Sample
Sample Location
Collected SV-101
Pentachlorophenol 01/06/04 33
01/19/04
2.4-Dichlorophenol 01/06/04 <0.60
01/19/04
Phenol 01/06/04 <0.60
01/19/04
Chronic Toxicity 01/06/04
Dioxin (2,3,7,8-TCDD) 01/06/04 <2.7
Notes: All results are m micrograms per IJter (µg/L) except dioxin. Dmxin data is in p1cograms per liter (pg/L).
SV-101 • Before Carbon Units
"SV-304 -Between Carbon Units
··sV-305 -After Carbon Units
. 2/10/2004
F:\PROJ ECTS\03624\Reports\Monthly\2004\01 M-04 Table 2.xls
Sample
Location
SV-304•
<0.99
<0.20
<0.20
Sample
Location
SV-305 ..
<1.0
<0.99
<0.20
<0.20
<0.20
<0.20
Pass
<2.7
1 of 1
•
•
•
0
ANALYTICAL REPORT
Raleigh, Biweekly NPDES
Lot i, C4A070229
Rita Bauer
The RETEC Group Inc
•
Sn. Pittsburgh
450 William Pitt Way
Pittsburgh, PA 15238
STL
Tel, 412 820 8380 Fax, 412 820 2080
www.sU~inc.com
SEVERN TRENT LABORATORIES, INC.
Veronica Bortot
Project Manager
January 19, 2004
Severn Trent Laboratories, Inc.
• CASE NARRATIVE
THE RETEC GROUP
Raleigh, Biweekely NPDES
STL Lot# C4A070229
•
Sample Receiving:
STL Pittsburgh, PA received samples on January 7, 2004. The cooler was received
within the proper temperature range.
STL West Sacramento, CA received samples on January 7, 2004. The cooler was
received outside of the proper temperature range.
If project specific QC was not required for samples contained in this report and batch QC
was completed on these samples, anomalous results will be discussed below.
GC/MS Semivolatiles SIM:
The reporting limits were adjusted according to the amount of sample extracted.
Due to the concentration of target compounds detected, sample SV-101 was analyzed at a
dilution.
Since insufficient sample volume was received to perform a matrix spike and matrix
spike duplicate, a Laboratory Control Sample (LCS) and Laboratory Control Duplicate
(LCD) were performed. All recoveries were within QC limits.
Dioxins:
STL West Sacramento, CA performed the dioxin analysis. All results are included in the
report.
The method blank had 2,3, 7,8-TCDD detected between the MDL and the reporting limit.
The result was flagged with a 'T' qualifier. This compound was not detected in any of
the samples.
•
•
•
•
•
• •
METHODS SUMMARY
C4A070229
PARAMETER
Dibenzodi6xins and Diberizofurans, HRGC/HRMS
8270C (SIM)
References:
ANALYTIC.'\L PREPARATION
METHOD ~M~E~T~H~O=D ____ _
SW846 8290 SW846 8290
SW846 8270C SIM SW846 3520C
SW846 nTest Methods for Evaluating Solid Waste, Physical/Chemical
Met:lods 11 , Third Edition, November 1986 and its updates .
•
WO# SAMPLE# CLIENT SAMPLE ID
F7MTO
F7MT7
F7MT8
NOTE(S),
001
002
003
SV-305
SV-304
SV-101
SAMPLE SUMMARY
C4A070229
-The analytical results of the samples listed above an~ presented on the following pages
• All calculations are performed before rounding ro avoid round-off errors in calculaied ren:Jts.
-Results noted as "ND" we.re not detected at or above !he stated limit.
-This report must not be reproduced, except in full, without the written approval of the laboratory.
•
-Results for the following p:uameters are never reporred on a dry weight basis: color, corrosivtty, density, flashpoint, ignitability, layers, odor,
p:iint filter test, pH, porosity pressure, reactivity, redox potential. specific gravity, spot testS, solids, solubility, temperature, viscosity, and weight.
•
SAMPLED S;-.MP
DATE TIME
01/06/04 o,,oo
01/06/04 0,,10
01/06/04 0.9,20
•
•
• • • Serial Number . 14 518
ANALYSIS REQUEST AND CHAIN OF CUSTODY RECORD
Fax:
•
l---+---.--------l-l-----l-+-+-1---t-+--+-----l----+----+------t----,f----r----t-----l.
RELINQUISHED BY: ISGNATUREJ DATE TIME TIME REUN~JS,D BY: (SlGNAlURO
Hit._/['
DATE TIME
RECEIVED BY: !SIGNATUI![) DATE TIME RECEIVED BY: I IGNATUREI DATE TIME
ANALYSIS REQUEST AND CHAIN DF CUSTODY RECORD
STL
MATRIX
n'PE
Serial Number . 14 519
Phone:
Fax:
REQUIRED ANALYSIS PAGE
1----t----l-l--+----t&IHl~--tOOl'l--l----l---++-+-~-H-'-----1f-------+----+---+---'+-+-h_t''.-t--t---t------7
llELINQUISUEO llY: ISK'.:NAlUIIE) DATE TIME RELIN UISHE IGNATURE) DA1E TIME
Fi\~r·:-{ ,.:,.1:tr1.111,J;·r~~1
HlC[IVED BY: !SIGNATUI!EI DATE TIME. DATE TIME
j,Mi''(Y C()11m~lNEitH
• •
, .
•
I
•
•
Lot-Sample# ... : C4A070229-001
Date Sampled ... : 01/06/04
Prep Date ...... : 01/08/04
Prep Batch# ... : 4008287
Dilution Factor: 1.02
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrob6nzene-d5
Terphenyl-d14
2-Fluorobiphenyl
2-Fl uorophenol
Phenol-d5 • 2,4,6-Tribromophenol ·
•
•
THE RETEC GROUP INC
Client Sample ID: SV-305
GC/MS Semivolatiles
Work Order # ... : F7MT01AA
Date Received .. : 01/07/04
Analysis Date .. : 01/12/04
Analysis Time .. : 09:09
Matrix ......... , WATER
MS Run # ....... :
Method ......... : SW846 8270C SIM
REPORTING
RESULT LIMIT UNITS
ND 0.20 ug/L
ND 1. 0 ug/L
ND 0. 2 0 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
59 (30 -121)
67 (11 119)
60 (39 -115)
50 (37 -115)
60 (41 115)
53 (40 -115)
•
THE RBTEC GROUP INC
Client Sample ID, SV-305
Trace Level Organic Compounds
Lot-Sample# ... , C4A070229-001
Date Sampled ... , 01/06/04
Prep Date ...... , 01/09/04
Prep Batch# ... , 4009392
Dilution Factor: 1
PARAMETER
2,3,7,8-TCDD
INTERNAL STANDARDS
13C-2,3,7,8-TCDD
Work Order# ... , F7MT01AC
Date Received .. , 01/07/04
Analysis Date .. , 01/13/04
Analysis Time .. : 15: 17
DETECTION
RESULT LIMIT
ND 2.7
PERCENT RECOVERY
RECOVERY LIMITS
68 (40 -135)
•
•
Matrix ......... , WATER
MS Run# ....... ,
UNITS METHOD
pg/L SW846 8290
•
•
•
Lot-Sample# ... , C4A070229-002
Date Sampled ... , 01/06/04
Prep Date ...... , 01/08/04
Prep Batch# ... , 4008287
Dilution Factor: 0.99
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5 • 2,4,6-Tribromophenol
•
•
THE RETEC GROUP INC
Client Sample ID, SV-304
GC/MS Semivolatiles
Work Order# ... , F7MT71AA
Date Received .. , 01/07/04
Analysis Date .. , 01/12/04
Analysis Time .. : 09:36
Matrix ......... : WATER
MS Run# ....... ,
Method ......... , SW846 8270C SIM
REPORTING
RESULT LIMIT UNITS
ND 0.20 ug/L
ND 0.99 ug/L
ND 0.20 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
58 (3 0 -121)
71 (11 -119)
61 (3 9 -115)
57 (3 7 -115)
64 (41 -115)
57 (40 -115)
•
Lot-Sample# ... , C4A070229-003
Dat'e Sampled.-., 01/06/04
Prep Date ...... , 01/08/04
Prep Batch# ... , 4008287
Dilution Factor: 3
PARAMETER
21 4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
1,4,6-Tribromophenol
THE RETEC GROUP INC
Client Sample ID, SV-101
GC/MS Semivolatiles
Work Order# ... , F7MT81AA
Date Received .. , 01/07/04
Analysis Date.·., 01/12/04
Analysis Time .. : 10:03
•
Matrix ......... : WATER
MS Run # ....... ,
Method ......... , SW846 8270C SIM
REPORTING
RESULT LIMIT UNITS
ND 0.60 ug/L
33 3.0 ug/L
ND 0.60 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
64 (30 -121)
73 (11 -119)
66 (39 -115)
52 (37 -115)
59 (41 -115)
56 (40 -115)
•
•
•
•
•
• •
TEE RETEC GROUP INC
Client Sample ID: SV-101
Trace Level Organic Compounds
Lot-Sample# ... : C4A070229-003
Date Sampled ... : 01/06/04
Prep Date ...... : 01/09/04
Prep Batch# ... : 4009392
Dilution Factor: l
PARAMETER
2,3,7,8-TCDD
INTERNAL STANDARDS
13C-2,3,7,8-TCDD
Work Order# ... : F7MT81AC
Date Received .. , 01/07/04
Analysis Date .. , 01/13/04
Aoalysis Time .. , 15:59
DETECTION
RESULT LIMIT
ND 2.7
PERCENT RECOVERY
RECOVERY LIMITS
59 (40 -135)
Matrix ....•.... : WATER
MS Run JI .•..••• :
UNITS METHOD
pg/L SW846 8290
•
Client Lot# ... , C4A070229
,MB Lot-Sample#, C4A080000-287
Analysis Date .. , 01/12/04
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-dS
2,4,6-Tribromophenol
METHOD BLANK REPORT
GC/MS Semivolatiles
Work Order# ... , F7NWV1AA
Prep Date ...... , 01/08/04
Prep Batch# ... , 4008287
RESULT
ND
ND
ND
PERCENT
RECOVERY
63
68
62
57
66
54
REPORTING
LIMIT
0.20
1.0
0.20
RECOVERY
LIMITS
(30 121)
(11 -119)
(39 -115)
(37 -. 115)
(41 -115)
(40 -·115)
UNITS
ug/L
ug/L
ug/L
•
•
Matrix ......... : WATER
Analysis Time .. : 07:47
METHOD
SW846 8270C SIM
SW846 8270C SIM
SW846 8270C SIM
~NOTE~~($~)~,---------------------------------------.
Calculations arc performed before rounding to avoid round-off errors in calculated result.1.
•
•
•
•
• •
METHOD BLANK REPORT
Trace Level Organic Compounds
Client Lot# ... : C4A070229 Work Order# ... : F7RVF1AA
MB Lot-Sample#, G4A090000-392
Analysis Date .. , 01/13/04
Dilution Factor: 1
PARAMETER
2,3,7,8-TCDD
INTERNAL STANDARDS
13C-2,3,7,8-TCDD
NOTE (S) :
Prep Date ...... : 01/09/04
Prep Batch# ... : 4009392
DETECTION
RESULT LIMIT
5.8 J
PERCENT RECOVERY
RECOVERY LIMITS
78 (40 -135)
Calculations are performed before rounding to avoid round-off errors in calculated results
J Esdmated result. Result is lt:ss lhan the reporting limit .
UNITS
pg/L
Matrix ......... : WATER
Analysis Time .. : 14:36
METHOD
SW846 8290
• •
LABORATORY CONTROL SAMPLE EVALUATION REPORT
~/MS Semivolatiles
Client Lot# ... : C4A070229
LCS Lot-Sample#, C4AOB0000-287
Work Order# ... , F7NWV1AC-LCS
F7NWV1AD-LCSD
Analysis Date .. , 01/12/04
Analysis Time .. , 08, 14
Matrix ......... , WATER
Prep Date ...... : Ol/08/04
Prep Batch# ... : 4008287
Dilution Factor: 1
PERCENT RECOVERY RPD
PARAMETER RECOVERY LIMITS RPD LIMITS METHOD
Phenol 66 (10 -131) SW846 8270C SIM
73 (10 -131) 11 (0-43) SW846 8270C SIM
Pentachlorophenol 75 (10 -140) SW846 8270C SIM
81 (10 -140) 7.4 (0-56) SW846 8270C SIM
2,4-Dichlorophenol 61 (42 -115) SW846 8270C SIM
66 (42 -115) 7.7 (0-44) SW846 8270C SIM
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Nitrobenzene-dS 63 (30 -121)
66 (30 -121)
Terphenyl-d14 72 (11 -119)
76 (11 -119)
2-Fluorobiphenyl 61 (39 -115)
67 (39 -115)
2-Fluorophenol 55 (37 -115)
54 (37 -115)
Phenol-dS 63 (41 -115)
71 (41 -115)
2r4,6-Tribromophenol 60 (40 -llS)
63 (40 -115)
NOTE(S}:
Calculations are performed before rounding to avoid round-off errors In calculated resulls.
•
•
•
•
•
•
LABORATORY CONTROL SAMPLE EVALUATION REPORT
Trace Level Organic Compounds
Client Lot i ... : C4A070229
LCS Lot-Samplei: G4A090000-392
Prep Date ...... : 01/09/04
Prep Batch i ... : 4009392
Dilution Factor: 1
PARAMETER
2,3,7,8-TCDD
INTERNAL STANDARD
13C-2,3,7,8-TCDD
NOTE (S):
Work Order i ... : F7RVF1AC
Analysis Date .. : 01/13/04
Analysis Time .. : 13:54
PERCENT RECOVERY
RECOVERY LIMITS
75 (72 -l.37)
PERCENT
RECOVERY
67
C:i.lculaCions are performed bcfort·rounding to avoid round•Clfferrors in calculated results.
Bold print denotes control par.unecers
Matrix ......... : WATER
METHOD
SW846 8290
RECOVERY
LIMITS
(40 -135)
•
•
•
•
ANALYTICAL REPORT
Raleigh, Biweekly NPDES
Lot#, C4A200239
Rita Bauer
T'he RETEC Group Inc
•
SEVERN TRENT LABORATORIES, INC.
Veronica Bortot
Project Manage,r
January 27, 2004
STL Pittsburgh
450 William Pitt Way
Pittsburgh, PA 15238
STL
Tel, 412 820 8380 Fax, 412 820 2080
www.stl-inc.com
Severn Trent Laboratories, Inc.
•
Sample Receiving:
CASE NARRATIVE
THE RETEC GROUP
E.aleigh, Biweekely NPDES
STL Lot# C4A200239
•
SIL Pittsburgh, PA received samples on January 20, 2004. The cooler was received
within the proper temperature range.
If project specific QC was not required for samples contained in this report and batch QC
was completed on these samples, anomalous results will be discussed b~low.
GC/MS Semivolatiles SIM:
The reporting limits were adjusted according to the an1ount of sample extracted.
Since insufficient sample volume was received to perform a matrix spike and matrix
spike duplicate, a Laboratory Control Sample (LCS) and Laboratory Control Duplicate
(LCD) were performed. All recoveries were with.in QC limits.
•
•
•
•
•
•
• •
METIIODS SUMMARY
C4A200239
ANALYTICAL PREPARATION
PARAMETER METHOD ~ME=T~H~O=D ____ _
9270C (SIM) SWB46 9270C SIM SW845 3520C
References:
SWB46 "Test Methods for Evaluating Solid Waste, Physical/Chemical
Methods11 , Third Edition, November 1986 and its updates .
• •
SAMPLE SUMMARY
C4A200239
WO # SAMPLE~ CLIENT SAMPLE ID
F788T 001 EFF/SV-305
NOTE(S}:
-The malytic.al results of the samples fisted lbovc are prcsc:.ntcd on the following pages.
-All calculations arc performed before rounding to avoid round-off errors in calculated resultS,
-Results noto:l as ~ND" wcrC not detected at or above Li.c stated limit.
-This report must not be reproduced, except in full, without the written approval of the laboratory.
-Results for the following parameters arc: never reported on a dry weight basis: color, comisivity, density, flashpoint, lgnitability, Ja:yers, odor,
SAMPLED
DATE
•
SAMP
TIME
Ol/19/04 :Ll: 20
-----;,ainHil.tt.r-mst'f"i)H-,-porooily-pressur-.t'Cllct.ivityTffiiox---potential,specific•gmvity-;-51'CHestl!;-1IOl~l1:1biley;--t~ll!ttr-Yiscesity;-aftd-wei,Jv~-----'-----------
•
ANALYSIS REQUEST AND CHAIN OF CUSTODY RECORD
t!:11 STL
RELINQUISHED BY:!(SIGNATUREI
l: ;;;;,·,,
HECEIVEO BY: !SlG,'lATUREI
-11"<:i!i":\ ·~
l
DATE
DATE
TIME RELINQ
TIME RECE
•
0 venue
404
Se al Number -19 2 7 9
Website: www.stl-inc.com
Phone: 19121354-7858
Fax: [phone]
•
0 Alternate laboratory Name/1..ocatio
Phone:
Fax:
NUMBER OF CONTi'JNE S SUBMITTED
RE INQU!SHED BY: (SIGNATURE)
RE EIVED BY: (SIGNATURE}
DATE DUE
NUMBER OF COOLERS SUBMITTED
PER SHIPMENT:
REMARKS
DATE TIME
. DATE TIME
•
•
•
THE RRTEC GROUP INC
Client Sample ID, EFF/SV"305
GC/MS Semivolatiles
Lot-Sample# ..• , C4A200239°001
Date Sampled ... : 01/19/04
Work Order# .•. : F788TlAA
Date Received •. , 01/20/04
Analysis Date •. , 01/23/04
Analysis Time-.: 10:37
Prep Date •..... : Ol/22/04
Prep Batch# ... : 4022326
Dilution Factor: 0.99
•
Matrix ......... : WATER
MS Run# ....... ,
Method ......... : SW846 8270C SIM
REPORTING
PARAMETER RESULT LIMIT UNITS
2,4-Dichlorophenol ND 0.20 ug/L
PentachloJ::O
Phenol ND 0.20 ug/L
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Nitrobenzene-dS 70 (3 0 -121)
Terphenyl0 d14 87 (11 -119)
2-Fluorobiphenyl 72 (39 -115)
2~Fluorophenol 67 (3 7 -115)
Pheriol-dS 67 (41 -115)
2,4,6-Tribromophenol 68 (40 -llS)
•
•
•
•
•
•
•
Client Lot U.-.: C4A200239
MB Lot-Sample#: C4A220000-326
Analysis.Date_., 01/23/04
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribrornophenol
NOTE (S):
METHOD BL1\NK REPORT
GC/MS Semivolatiles
Work Order*-··' FBDWPl.AA
Prep Date •... _., 01/22/04
Prep Batch#.-.: 4022326
REPORTING
•
RESULT LIMIT UNITS
ND 0 .2 0 ug/L
ND 1.0 ug/L
ND Q 20 ·ug/I
PERCENT RECOVERY
RECOVERY LIMITS
79 (30 -121)
91 (11 -119)
75 (39 -115)
79 (37 -115)
77 (41 -115)
67 (40 -115)
Calo.tlations are performed before rowuiing to avoid round-off errors in calculated results .
Matrix ......... : WATER
1\nalysis Time._ i 09, 16
METHOD
SW846 8270C SIM
SW846 8270C SIM
SW~G-s;;;
• •
LABORATORY CONTROL SAMPLE EVALUATION REPORT
GC/MS Semivolatiles
Client Lot# ..• : C4A200239 Work Order*···' F8DWP1AC-LCS
F8DWP1AD-LCSD
Analysis Date .. : 0l/23/04
Analysis Time .. : 09:43
Matrix ... _ ..... : WATER
LCS Lot-Sample#: C4A220000-326
Prep Date ______ , 01/22/04
Prep Batch# ... : 4022326
Dilution Factor: 1
PARAMETER
Phenol
2,4-Dichiarophenol
SURROGATE
Nitrobenzene-ds
Terphenyl-dl4
2 -Fl uorobiphenyl
2 -Fli.toroj;,henol
Phenol-dS
2,4,6-Tribromophenol
NOTE (SJ,
PERCENT
RECOVERY
82
82
87
85
72
73
RECOVERY
LIMITS
(10 -131)
(10 -131)
{10 14-0
(10 -140)
(42 -115)
(42 -115)
PERCENT
RECOVERY
73
74
75
75
73
7'f
69.
69
B2
81
67
67
Calculations 11Ie performed before rounding to avoid round-off errors in ca.la.dated results.
RPD
RPD LIMITS METHOD
SW846 8270C SIM
0.48 (0-43) SW846 8270C SIM
6 B2JOC SIM
2.0 (0-56) SW846 8270C SIM
SW846 8270C SIM
0.64 (0-44) SW846 8270C SIM
RECOVERY
LIMITS
(30 -J.21)
(30 121)
(11 -119 ).
(11 -119)
(39 -115).
(39 -115)
(37 -115)
(37 -115)
(41 -115)
(41 -115)
(40 -115)
(40 -115)
•
•
•
FEB-09-04 MON 17 ', 29 • • P, 02
•
Pace Analytical Seri,·ices, Inc,
2225 Riv6r$ide Drive
l\shevil/c, NC 28804 ace Analytical®
!-'none: 828.254.7176 www.pa~oroToxicity Report AT-1 Form Chronic Pass/Fail and Acute LC50 Fax: [phone] Date 1 \ 18\04
.C.:\cilitv: Rett,c NPPES#NC Lener Pipe# Eff
County Wake Laboratory Performing Test PACE Anajytica! Services, Inc.
C.:nrnmcnts
QL-\Q i -QQ;;-;::-1;;,, Si~~J ~r Oooratcr1.~. RQ$PQnsi~I~ .. {h;:irgtl I ,, , i(t:t:.<ct1 ~ I':: 1.,,, ( u .QL) :>1nna_111rf,1f 1 ~""'11tri'V r~JO"l,'Vl<i,ir. ~'7J Samples Ne! A<,f"il{8d Unless OthoMbG }/0\QO'
Environmsnbl Science:<. Branch Chronic Test Results -MAIL ORIGINAL TO: Div. of Water au~Jity
Calculated t 0.879 N.C, DENR
1621 M~il Service Center
Tabular t 2.508 Rc1leigh, North c.,roliM 27699-1621 .. f:i..t?rth Car□li1v,90riod.'7phni~...£hronic PassJF~il R.eproductiop IP.:~dcity lest % Reduction 8.4 CONTROL ORGANISMS: 1 2 3 4 5 6 7 8 g 10 11 12
%:,t.or1;i,lily Avg. fi.o;;rod. # Your1q Produced 17 26 27 28 30 36 24 28 28 25 25 23 ContMI Control
Adult (L)'1ve (D)ead L L L L L L L L L L L L 0.00 26.3
Treatment 2 Tre.=:itmem 2 Effluent% I 90 I 8.3 ?.4.1
;-.,-,,u,,..J r:v TREATMENT 2 ORGANISMS 1 2 3 4 5 6 7 R g 10 11 12 I 17 I FA~.:"; FAIL
;.:. YOunq Produced 22 30 20 22 27 38 31 27 6 31 17 28 "¼CQl"ltrol or1;1.inl!::rru: X I flf-'~~ ~,:1 broo.:i Adult (L)ive (P)ead L L L L L L L L D L L L I 91.7 I Chee!<; one
!comelete This For Either Te~t I T<'>:<::•!-:-ncite: 1st 1st 2nd 1, 7\n4
pH Control ~ ~ 7,2 7.1 Collec11cn st;irl Q3ltJ~
Tream1ent 7.4 7.4 8.1 s.o Sample 1 115\04 S;;:,mple2 1\8\04 9
S I E s I E S I E Samo&I Tvoe/Dura1I01·1 I I I ;t ~N 0 0 0 ;y E 3 d a d a d "'"' Comp. 01.Jr.i~on --< ~d ' ' ' Sample 1 ffi8 ~ "' 0 ~ ~(// . ·"" E' " ii 0 • Sample 2 _ X :wi, '2. 1st 1st 2nd -• D.O ~ ~1111 Control-~ 8.0 8.3 Hardnass (rn::,1) .¥!,, i1i\ ~ : . ~ Treatment 7.8 7.6 8.6 6.3 So<a:c. cond. /•;mhos 1 136 '" =o:; 4
I ChloriM (m!}/1) ; <0.1 <0.1 ;
Sc1mole term,. -ll receiot /Cl ' l.C:5Q!~_!:;ute-To'<·,c·,1y T.2fil
1.9 2.0 ., .. IM0ni'll!IV ~xore;~!'l~d ,'\~ % . r:0mt,int110 r1;:JJ!ic;;it~11-\
% % •• % % % ¾ % % ,,.
Concentration No\a: Pleasa . -cornp1~!1) 1 n1:; % o/o % % % % % % % Soc.ti(;l11 dl:.u Mortality
LC5O= % Method of Determination start.lend star1/end 95% Confidence Moving Avg. Probit n ES Centro! EE -% ,,
r,tgl'I . " Sr:,aarman Other
Coric
On;;i::.im,:;:m Y,u~tQd: CeriodapJmia dubia Te~t Ourt1tia[1 (Hours);
REPORT OF LABORATORY ANALYSIS Asheville Ce11ifi_catio.o..lQQ This report shall not be reproduced, except in full. without the written consent of Pace Analytical Services, Inc.
Gha(IQJJe CertiticatiQDJDs NC Wasiewater 40
i/C Drinking Water 37712
SC tnvironmcntal :~9030
FL NELAP c8764S /n~;~:,~
MC Was1ewater 1 z'
NC Drinking Water 37706
SC .00006
fl MELAP
AQUAJ'1c ·uJXICOLOG'I/ LAJIOl<A'l'UKY l'ACic ANALYTICAL S!iltVlCES, JNC.
CHAIN-OF-CUSTODY AND FIELD ANALYSIS.FORM
[c..c"-·1..cc.ll-=•:"'N'-=f{C.CF'-'A~(-=;1c..L~i'~fl-'_N_A.:~'.-=IH~::=J2j~· ~· .cc __ u-=· -"-:C·C--· ______ · -'--'P'-'U'-l{"'C'-''ICCIACCCSCCI.C.c '-'O-=llccDc..E_R-'/1"': -'--'-----~ B .tl..e-\. -e-cf· ---~L,l_ _____ r::::c:c-::::c:---.-:-c-------------i
COIINTY:. _ 1/'.J,l\.\(_Q'. _ STA'l'll: C
Nl'HES Pl::l:MIT //: A.A_vv--A"--La:,t'? OUTl•AU,/1'1 PEI/:-£(=!= __ _
INFORMA'rl0N ON TIIIS l•0Rl\l IS RE(►lllllEfJ UY STATE ANll F~:OKRAL AGENcms.
·n:ST REQlliR.E:NlEN'TS (please chock the opproprialc test type and species required.)
_1'~! ]_if!!:_
Acute, circle lhc appropriritc test· ilur:1tion: 24 48
__ )':::_ Ci1i-!111ir1 7-d~l)'S
P;:ss/F;1il, dilution rt>quired: _____________ _
Full H~mge DcfiniliYe, dilutions required: ________ _
\:.filer) specify: __________________ _
SAHPLETYPE
Composite sample
S1ecies
Ceriod11pf111i,r d11hia (Water Ilea)
Piuuphales promelas (Fathrnil minnow)
,1/ysi,lopsis b(Jft/(1 (1\tysid shrimp)
,Henidi,, bel))lllntJ (fn!aml sil\·crsidc)
Samnle intormatiou
· 2225 IUHRSIDEDP.IVE
ASHEVfLLE, NC 2S:J(J,l
Pl:IONE: (828) 2S•i.7176
F.\X: (on) 252.4r,1 s
s,a_,·t ~f';f/ ol Start time: Sample location: (af~:~rin~p,rn, at weir, effluent onlfoll, etr.) o~tv
Ent! datji c,/ 0 ~ End time: Approximate ,·olumc co,Jec'ted for testing:~ _{) o'J?'fO
Samples per hour: I Numher of containers filled for tesHng: ::J
Chilled llurine: coUtdion?: V Total residual chlorine (m~/L):
II chilled, specify lemµeraturn: .t:. <-f.D"c:, Teniue1·ature at tinle of collection ( °C)
Method of tranmort to PACE: --· Grnl.J sample
Dale: ~ Time: -Note: Rinse containers with the sample before fillir,g. Pack .samples .in loose ice.
Samples must be received al PACE al or below 4'C. Samples should not be frozen.
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-RE-,-~-1-A_R_K_S _____________________________________________________ OL\
,,. LJ· -sY.
SAiIPLE Cf!STODY
S,J:J:p!r tv!l.-rlffi bx: FOR Off/CE USE ONl:'r l'ROIECI' tltA~S74 :?'O
I . A-b\YG),1 0: I_I -'--ll~t~r+,,,=,,J.,__1 ___.,!~1/2/4~~(-:~ol.;:;--'?u I
l'IUNr S!o..,IIATii?_-..: D,\rc...-.,IOT[\.li
-~~ ,, ; ,,_ 1\, c--·"" ~==◊ .·. "'V-=:=J / -/, o'I lo: ]v f
;_) l'~Dtf ~lC'(,\lLl(C Jl\Tl' .\N:)111.'.l:. (t,y1
Ruti:.-·d iJ1 fACF. l:r: ("_,i .
I
· • · AQtJATrc ToxrcoLocv LAuonAToa
• CHAJN-OF-CIJST<JDY AND FJELD ANALYSI~OR!VI i-r.1.n>n=:1i',\CJUTY N/IJIE--;-7<3T'.._, · PliRCHASf£ ORl)Jm/;: c. y5-"<' -,_c..l:1.J',~_,\,."-------------+------,-,-0---------------j lco[l:~TY: wA:1<:.11: ~--\STA11<:: µc _ NPl)lcS PlcltMIT ii: i'.\:;yb.b ___ 53%'.y' ---·-· OUTFALL/Pim#: . ·ilJ-------~ lNFOHMATION ON TIIIS FORM lS HK0llll(F,J) BY STATE ANO FEllElUJ. AGENCll'.S.
-CL.\ o 1 -oo~ct~o;i..
J'AClc A:-iALYTIC,\1. S~'.\l VJCI-C.
2225 RIVERSIDE DRlVE
ASH E\/fU.E, NC 28,•M
PIIONF: (S28) 25<1-7176
f,\X: (S28) 252-•16l8
TEST llRQIJffiEMliNTS (please check tl1e appropriate £est type a11d species required.) Test J..}J!.£__ . · SP.!_cics ~ Acute, rirclc the appropriate test duration: 24 48 96 ~I Cei-iotlnpl:nia ,/11hia (Water !le:i)
. -·---·P:1ss/Fail, dilution rtfJuiictl: ______________ . Mysiclopsis buhi« (i\1ysid shri11111)
-:-d]. Chronic, 7-days
J Pimep!wles promclas (J1'athr:ul minnow)
_ Full Range DclinHive, <liiutions rctJHiretl:__________ J 1l1e11hlia berylli,w {Inl:iull s_ilrcrsidc) __ Othcr;_,pccify: _______ c.· ___________
_
SMvf rLE TYPE
Composite sample
Sl,r( ~"!JI O if Start time;
{/fro
lend <la / ' { 1 End Umc: I ~ 0'/ (') q JO Samorc.i oer hour: r
Chi!!ed dm·ing collection?: I-ff c-hiJled, soecifv• femnerat_urc:
Grab sam11le
narc: .......,
llE~HRKS
SAHI'LE CUSTODY
S r..:nJ-k. n,/!fc#d l,y-: l &~+kt\
IRlc\~f
P>-tla,;1li1hi'd irF I A~w,..,,., &,'1 I I . · ntifff
Rcli11q-'d1h:.·d h n~JCE I!]·:
Time:
I a;aJI
SIGNAa!r.E
Sample information
Sample location: (after cI1lorinpJn, ~~:Zrveir, Cfflucnt outfaJl, etc.)
--·-Approximate volume collcclcd~·ur le,ti11g: ) . ;;i.
Number of confaincn filled for testing; 0 Total residual cl1lorit1e (m!(/L):
Tem2:erafure at time of collection! °C}
----Method of transoort lo PACK:
Note: Rinse containers \\ith the sample before fillirg. Pack samples in loose ic~-
0 Samples must he received al PACE at or below 4 C. Samples should not be frozen.
I t/Jkt-/)flil I n_,na nr,;n 11,\rn
li/011-
FOR OFFICE USF. ONLY
R,wimll_7:
l'RrlT
R..-,d:-wl d P.-':lCE VJ'.'
_ MltJ"f
PltO!ECT~,'76)5 lt//f!J
Sl,MPLE, !lq;:J_-jf /(p!:f(/7
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