NCD003200383_20040108_Koppers Co. Inc._FRBCERCLA RA_Remedial Action Monthly Progress Reports 2003-OCR

• January 8, 2004
Ms. Beverly Hudson
Remedial Project Manager
U.S. EPA -Region IV, 11th Floor
North Site Management Branch
6 I Forsyth Street, SW
Atlanta, GA 30303
RE: Monthly Progress Report# 128
Remedial Action
Koppers Site -Morrisville, North Carolina
Dear Ms. Hudson:
The RETEC Group, Inc.
300 Baker Avenue, Suite 302
Concord, MA 01742
RETEC
[phone] Phone
[phone] Fax
www.retec.com
In accordance with the Unilateral Order, and on behalf of Beazer East, Inc. (Beazer), please find
attachetl four (4) copies of the December 2003 Monthly Progress Report for Remedial Action at
the Koppers Superfund Site in Morrisville, North Carolina. No exceedences occurred during this
event.
Should you need additional information regarding this progress report, please call Mike Helbling
at ( 412) 208-8858 or me at (978) 3 71-1422.
Sincerely,
The RETEC Group. Inc.
Rita Bauer
Project Geologist
Enclosure
cc: D. Mattison -NC Superfund (2 copies)
L. Faulconer -Wake County
G. Caskey -Enwood Structures
Mike Helbling -Beazer
F:\l 'RO.J ECTS\03 (,24\Repons\Monthly\2003\ 12M-03.doc
D. Hails -EAP Industries, Inc.
J. Garrett -NC Division of Water Quality
M. Matthews -NC Division of Water Quality
P. Kilchenstein -RETEC
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MONTHLY PROGRESS REPORT #128
REMEDfAL ACTION
SfTE NAME: Koppers Superfund Site
Beazer East, Inc.
Morrisville, NC
USEPA DOCKET NUMBERS: 93-09-C
PERIOD ENDING: December 31, 2003
l. PROGRESS MADE THIS MONTH
Remedial Action (RA) -HABITAT MITIGATION. No activities were conducted this
month.
Remedial Action (RA) -GROUNDWATER TREATMENT. The treatment system operated
throughout the month without upset. System performance was monitored on a biweekly basis.
Approximately 55,270 gallons of groundwater were extracted, treated in the treatment plant, and
discharged between December I, 2003 and December 31, 2003. System water samples were
collected on December 5 and December 15, 2003 in accordance with the sampling schedule in
the O&M manual. Samples were submitted to Severn Trent Laboratories, Inc. for laboratory
analysis. The operations and sampling programs are summarized on the attached Table 1.
2.
3.
4.
5.
6.
7.
Remedial Action (RA) -EFFECTIVENESS MONITORING PROGRAM. No activities
were conducted this month.
Remedial Action (RA) -CORRESPONDENCE. None.
PROBLEMS RESOLVED
PROBLEMS ANTICIPATED
UPCOMING EVENTS
PERSONNEL CHANGES
SUBCONTRACTORS
None.
None.
Continue System O&M.
None.
None.
ANALYTICAL DATA Analytical data from system influent and effluent
sampling received during this period are enclosed and are summarized on Table 2 .
• •
Table 1
Groundwater Treatment Operations and Sampling Program Summary
Kopper~ Superfund Site
Date Systems Cumulative SV-101 SV-101
Check Effluent Flow Sample Sample
{yes/no) (Gallons) (yesfno) Parameters
01/15/03 yes 3,715,610 ves Penta, 2.4-Dichloro Phenol,
01/28/03 yes 3,733,790 no
02/11/03 ves 3 753 160 no
02/28/03 ves 3,779,540 no
03/14/03 ves 3,800 330 no
03/24103 ves 3,818,300 no
04/09/03 no
04/11/03 ves 3,850 120 ves Penta, 2,4-Dichloro, Phenol
04/21/03 ves 3,869,820 no
05/05/03 ves 3,894,370 no
05/19/03 ves 3,907 850 no
06/02/03 ves 3,944,990 no
06/16/03 yes 3,971,250 no
07/01/03 ves 3,999,940 ves Penta. 2,4-Dichloro, Phenol
07/17/03 ves 4 029,840 no
08/07103 ves 4,067,970 no
08/21/03 ves 4 094 260 no
09/09/03 ves 4,129,380 no
09/25/03 ves 4 158,630 no
10/14/03 ves 4,191 300 ves Penta, 2,4-Dichloro Phenol
10/28/03 ves 4,212,360 no
11/04/03 ves 4,224,230 no
12/05/03 ves 4 270,590 no
12/15/03 ves 4 286,620 no
Notes:
Sampling point SV-101 is located before the Carbon Units (pretreatment)
Sampling point SV-304 is located between the Carbon Units
Dioxin
Morrisville, North Carolina
December 2003
Associated SV-304 SV-304 Associated SV-305
Group Sample Sample Group Sample
(yes/no) Parameters (yes/no)
1,2 ves Penta 2,4-Dichloro, Phenol 1 ves
no ves
no ves
no ves
no yes
no ves
no ves
1 ves Penta 2 4-Oichloro Phenol 1 ves
no ves
no yes
no yes
no ves
no ves
1 ves Penta 2 4-Dichloro Phenol 1 ves
no yes
no ves
no ves
no ves
no yes
1 yes Penta, 2,4-Dichloro, Phenol , ves
no ves
no ves
no ves
no yes
Associated Groups:
SV-101 -Group 1 is penta. phenol, and 2,4-dich!orophenol; Group 2 is dioxin
SV-304 -Group 1 is penta, phenol, and 2,4-dichlorophenol
e
.RETE(
SV-305 Associated
Sample Group
Parameters
Penta 2.4-Dichloro, Phenol. Dioxin 1,2
Penta 2.4-Dichloro Phenol, Chronic Tox 1,3
Penta 2,4-Dichloro, Phenol 1
Penta 2,4-Dichloro Phenol 1
Penta. 2,4-Oichloro Phenol 1
Penta 2,4-Dichloro, Phenol 1
Chronic Tox 3
Penta 2,4-Dichloro Phenol. Dioxin 1,2
Penta 2 4-Dichloro Phenol ,
Penta, 2,4-Dichloro Phenol 1
Penta, 2,4-Dichloro, Phenol 1
Penta, 2 4-Dichloro Phenol ,
Penta 2 4-Dichloro Phenol 1
Penta 2 4-Dichloro Phenol. Dioxin , 2
Penta, 2 4-Dichloro Phenol 1
Penta, 2,4-Dichloro Phenol 1
Penta, 2,4-Dichloro Phenol 1
Penta, 2.4-Dichloro Phenol, Chronic Tox 1,3
Penta 2,4-Dichloro Phenol 1
Penta, 2 4-Dichloro Phenol, Dioxin 1,2
Penta, 2,4-Dichloro, Phenol 1
Penta. 2 4-Dichloro Phenol. Chronic Tox 1,3
Penta. 2,4-Dichloro Phenol 1
Penta, 2,4-Dichloro Phenol 1
Sampling point SV-305 is lactated after the Carbons Units (post-treatment) SV-305 -Group 1 is penta, phenol, and 2,4-dichlorophenol; Group 2 is dioxin and Group 3 is chronic toxicity
11712004
F:\PROJECTS\03624\R~p<>rall.!Ollthlyl2003112M-03 Table 1 ds 1 ofl
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Table 2 .RETEC
117/2004
Groundwater Treatment Analytical Data Summary
Koppers Superfund Site -Morrisville, North Carolina
December 2003
Analytical
Parameter Date Sample Sample
Sample Location Location
Collected SV-101 sv.304•
Pentachlorophenol 01/15/03 17 <1.0
01/28/03
02/11/03
02/28/03
03/14/03
03/24/03
04/11/03 21 <0.96
04/21/03
05/05/03
05/19/03
06/02/03
06/16/03
07/01/03 20 <0.97
07/17/03
08/07/03
08/21/03
09/09/03
09/25/03
10/14/03 22 <0.95
10/28/03
11 /04/03
11/21/03
12/05/03
12/15/03
2.4-0ichlorophenol 01 /15/03 <0.19 <0.20
01/28/03
02/11/03
02/28/03
03/14/03
03/24/03
04/11 /03 <0.81 <0.19
04/21/03
05/05/03
05/19/03
06/02/03
06/16/03
07 /01 /03 <0.78 <0.19
07/17/03
08/07/03
08/21/03
09/09/03
09/25/03
10/14/03 <0.59 <0.19
10/28/03
11/04/03
11/21/03
12/05/03
12/15/03
F:\PROJ ECTS\03624\Reports\Monthly\2003\ 12M-03 Table 2.x!s
Sample
Location
SV-305 ..
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.1
<1.0
<1.0
<0.98
<0.98
<0.98
<0.99
<0.97
<1.0
<1.0
<0.99
<0.97
<1.0
<0.98
<1.0
<1.0
<1.0
<1.0
<0.21
<0.20
<0.20
<0.20
<0.20
<0.20
<0.21
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.19
<0.20
<0.20
<0.20
<0.19
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
1 of 2
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Table 2 .RETEC
ln/2004
Groundwater Treatment Analytical Data Summary
Koppers Superfund Site -Morrisville, North Carolina
December 2003
Analytical
Parameter Date Sample
Sample Location
Collected SV-101
Phenol 01/15/03 <0.19
01/28/03
02/11/03
02/28/03
03/14/03
03/24/03
04/11/03 <0.81
04/21/03
05/05/03
05/19/03
06/02/03
06/16/03
07/01/03 <0.78
07/17/03
08/07/03
08/21/03
09/09/03
09/25/03
10/14/03 <0.59
10/28/03
11/04/03
11/21/03
12/05/03
12/15/03
Chronic Toxicity 01/28/03
04/09/03
09/09/03
11/04/03
Dioxin (2,3,7,8-TCDD) 01/15/03 <0.22
04/11/03
07/01/03
10/14/03
Notes. AU results are 1n micrograms per liter (ftQIL) except dioxin. D1oxm data 1s in p1cograms per liter (pg/L).
SV-101 -Before Carbon Units
•sV-304 -Between Carbon Units
.. SV-305 -After Carbon Units
Sample
Location
sv.304•
<0.20
<0.19
<0.19
<0.19
F:\PROJECTS\03624\Reports\Monthly\2003\ 12M-03 Table 2.xls
Sample
Location
sv.Jos··
<0.21
<0.20
<0.20
<0.20
<0.20
<0.20
<0.21
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.19
<0.20
<0.20
<0.20
<0.19
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
Pass
Pass
Pass
Pass
<0.28
<0.27
<1.90
<1.10
2 of 2
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. ANALYTICAL REPORT
Raleigh. Biweekly NPDES
'Lot ff: C3L080142,
Rita Bauer
The RETEC Group Inc .
SEVERN TRENT LABORATORIES, INC.
~
vercinica Bertot
··Pr6ject Manager
December l.5, 2003
STL Pittsburgh
450 William Pitt Wey
Pittsburgh, PA 15238
STL
Tel; 412 820 8380 Fax, 412 820 2080
www.stt-inc.com
Severn Trent laboratories., Inc.
. '
Sample Receiving:
CASE NARRATIVE
THE RETEC GROUP
Raleigh, Biweekly NPDES
STL Lot# C3L080142
STL Pittsburgh, PA received one sample on December 8, 2003 in good condition. The
cooler was received within the proper t=perature range.
If project specific QC was not required for samples contained in this report and batch QC
was completed on these samples, anomalous results will be discussed below.
GC/MS Semivolatiles SIM:
Since insufficient sample volume was received to perform a matrix spike and matrix
spike duplicate, a Laboratory Control Sample (LCS) and Laboratory Control Duplicate
(LCD) were performed. All recoveries were within QC limits.
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METHODS SUMMARY
C3L080l.42
l\NALYTICAL PREPARA.TION
=P~ARAME===T=ER='------------------~--METHOD ~ME=TH=O~D ____ _
8270C (SIM) SW846 8270C SIM SW846 3520C
References:
SW846 11 Test Methods for Evaluating Solid waste, Physical/Chemical
Methods", Third Edition, November 1.986 and its updates .
SAMPLE SUMMARY
C3Lq80142
WO# SAMPLE# CLIENT SAMPLE ID
FS?VL 001 EFF/SV-305
NOTE(S):
-The analytial i-esults of !he samples llsted above are presented on the following pagi::s.
-All calculations are performed before roundini to avoid round-off e~rs in calculated. rczul.1:5.
-Results noted u "ND• Wttc riot (I~ at or above the stated limit.
-Trus report mnst not be reproduc.cd, except in full, withouL the written approval of the laboratory,
-R=lts for tlle following p3m0eren are never reponcd on a dry weight bW: color, oor:rosivity, density, flashpoint, ignitability. laym, odor,
paint filler test. pH, porosity pressure, mictivity, redo,; pottnrial, specific gmvity, spot ~. solids, solubility, u:mpenturc, visro.<tity, and weight.
•
SAMPLED SAMP
DATE TIME
12/05/0'.; 14: so
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MN I • STL e
STl Pittsburgh , Chain of
Custody Record Severn,Trent Laboratories,. Inc. 450-William Pitt Way, Bldg. 6
Pittsburgh, PA 15238
STL-4124 (0901)
Cli,;m/ Pro1ect Manager Da:"z/s-b~ Chau, o/Custr 8f!°8 9 4 ~iz,7£<::__. ~i77T tfA-C/r,;:;,
Address .i Te/ephona Number {Area Code)/Fax Number Lab Number
I :'.l, c::o n A IE,? 6V.Q:.... • iu,720-Jo'L "n'd' -::nt I l/2--"2._ Page I of CJ/y . 1:: I lip Code Sile Contact Lab Contact Analysis (Attach list if eo,.,co,{h O/'?'('L more soace ;s needed so:;;;;;d1;;u;~;~71-Cam"er/WaybiJ/ Number
I~ g; tVC.., f!1£1J.$''/G s s.77 t, n7'ila3.s-Special Instructions/ ContracVPurchade Order/Quote No. c;, ~ Conditions of Receipt Contafners & J 1?1ffe'12-7 -oJ(..;,.,.y-CJ7 (. Matrl>< Preservatives
Sample I. D. No. and Description § " .~ i a (la & Date Time 't ~ i i3 q (Containers for eac/J sample may bo combined on one line) ~ f. "' 5 ~ ' :! ~~ c~,... J .ru ]O,) 1i./s;lo:( /$'Jo Y-1'1 X .,.
f '
;:
-
'
.
.
Jssrbfe Hazard lden/ifica!ion I Sample Disposal (A lea may bo assessed if samples are retained Non-Hazard O F/ammeb/9 0 Skin Irritant D PoisonB D Unknown D Ratum To Client -D Disposal By Lab D Archive For Months longer than 1 month) _, Tvrn 'Around Tima Raqwred
D 21 l-lot1rs D 48 Hours D 7 Days D 14 Days D 21 Days
QC Rsqulrements (Speetfy)
I. Relinquished By Time
2. Re/in IJ'S'O
Time Time
3. Relinquished By Time Dou
Time
Comments
DISTRfBUTION: WHITE· Re/umsd to Cl,emt "1th Report; CANARY-Stays with fhe-Se~o: PINK. Fiski Copy
THE RBTEC GROUP INC
Client sample ID: EFF/SV-305
GC/MS Semivo1ati1es
Lot-Sample# .•• : C3L080142-001
Date Sampled .•. : 12/05/03
Work Order # ••• : P57VLlAA
Date Received .. : 12/08/D3
Analysis Date .. : 12/11/03
Analysis Time .. : ll,48
Prep Date ...•.• : 12/10/03
Prep Batch# •.• : 3344344
Dilution Factor: 1
Matrix •••.••••• : WATER
MS Run # •...•• "
Method ..•.•.... : SW846 8270C SIM
REPORTING
PARAMETER RESULT LIMIT UNITS
2,4-Dichlorophenol ND 0.20 ug/L
Pen~achlorophenol ND 1.0 ug/L
Phenol ND 0.2D ug/L
PER£ENT RECOVERY·
SURROGATE RECOVERY LIMITS.
Nitrobenzene-dS 57 (30 -121)
Terphenyl-dl~ 70 (11 -119)
2-Fluorobiphenyl 57 (39 115)
2-Fl1:1orophenol 49 (37 -115)
Phenol-d5 59 (41 -1.15)
2,4,6-Tribrom?phenol 53 (40 -HSI
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Client Lot# ... : C3L080142
MB Lot-Sample#: C3Ll00000-344
1\nalysis Date .. : 12/11/03
Dilution Factor: 1
PARAMETER
2 ,· 4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-d5
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol ·
Phenol-d5
2,4,6-Tribromophenol
NOTE (S) :
METHOD BLANK REPORT
GC/MS Semivolatiles
Work Order # ••• : F6DARlAA
Prep Date ..... ,·: 12/10/03
Prep Batch # .•• : 3344344
REPORTING
RESULT LIMIT
ND 0.20
ND 1.0
ND 0.20
PERCENT RECOVERY
RECOVERY LIMITS
67 (30 -121)
76 (11 -119)
65 (39 -115)
61 (37 -i15)
68 (41 -115)
62 (40 -115)
Calatlalions are pedonned before rounding tO avoid rouwl-o~ errors in calcula.tcd rcrults .
Matrix ......... : WATER
AnaJ.ysis Time .. : 10:27
UNITS MiTHOD
ug/L SW846 8270C SIM
ug/L SW846 8270°C SIM
ug/L SW846 8270C SIM
Ll\BORA:I'ORY CONTROL SAMPLE EVALUATION REPORT
GC/MS Semivolatiles
Client Lot# ... : C3L080142 Work Order# ..• , F6DAR1AC-LCS
F6DAR1AD-LCSD
Analysis Date •. , 12/11/03
Analysis Time •. , 10:54
Matrix ..••... a., WATER
LCS Lot-Sample#: C3Ll00000-344
Prep Date .•.•.. : 12/10/03
Prep Batch# •.. : 3344344
Dilution Factor: 1
PARAMETER
Phenol
Pentachlorophenol
2,4-Dichlorophenol
SURROGATE
Nitrobenzene-ds
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
NOTE{S):
PERCENT
RECOVERY
62
73
80
90
61
70
RECOVERY
LIMITS
(l.O -131)
(10 -1.31)
( l.O -l..40 l
( 10 -140)
(42 -115)
(42 -115)
PERCENT
RECOVERY
60
69
68
75
61
68
49
55
60
62
60
66
Calculations are p~rformcd before rounding to avoid ro~ff errors in calcula.ted results.
RPD
~ LIMITS METHOD
SW846 8270C SIM
17 (0°43) SW846 8270C SIM
SW846 8270C SIM
12 (0-56) SWB46 B270C SIM
SW846 8270C SIM
14 (0-44) SW846 8270C SIM
· RECOVERY
LIMITS
(30 -121)
(30 -l.21)
(11 -119)
(11 -119)
(39 -115)
(39 -115)
(37. -115)
(37 -i15)
(41 -115)
(41 -J.J.5)
(40 -115)
(40 -115)
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ANALYTICAL REPORT
' ,'_
Raleigh, Biweekly NPDES ·.
Lot: ll: C3L160J.92
Rita Bauer
The RETEc Group Inc
sEVERN TRENT LABORATORIES, me.
Veronica Bortot
Project Manager
December 22, 2003
STL Pittsburgh
450 William Pitt Way
Pittsburgh, PA 15238
STL
Tel, 412 820 8380 Fax, 412 820 2080
www.stl-inc.com
Severn Trent Laboratories, Inc.
STL
NELAC REPORTING:
The formal. and content of the attachCd report meets NELAC standards and guidelinCs except as noted in the narratiVe. Tue table beloW
presents a. summary of the certifications held by SU.. Pittsburgh. Our primary accreditation authority foI' the Non-potable water and Solid
& Hazardous waste programs is NeW York State DOH. A more detailed parameter list is available uPon rcqu.cs1:. Please ask your pro} cct
manager for this information when !eg_uired..
South C.arolina (#89014001)
HW X
The codes utilii:ed for program types are described below:
HW Hazardous Waste cenification
WW Non-potable Water and/or Wastewatc:rcertincation
X Laboratory has some form of certification under the specific program. Many states certify laboratories for specific pararnet,~rs or
tests witbin a category. The information In the table Indicates the lab is certified in a general category of testing. Please contact
the laboratory if parameter specific certification information is required.
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Sample Receiving:
CASE NARRATIVE
THE RETEC GROUP
Raleigh, Biweekly NPDES
STL Lot# C3L160192
STL Pittsburgh, PA received one sample on December 16, 2003 in good condition. The
cooler was received within the proper temperature range.
If project specific QC was not required for samples contained in this report and batch QC
was completed on these samples, anomalous results will be discussed below.
. .
CC/MS Semivolatiles SIM:
Since i_nsufficient sample volume was received to perform a matrix spike and matrix
spike duplicate, a Laboratory Control Sample (LCS) and L~boratory Control Duplicate
(LCD) were performed. All recoveries were within QC l\11'lits.
-'
MEIBODSSUMMARY
C3L160192
ANALYTICAL PREPARATION
PARAMETER METHOD ~M~E~T~H~O~D:__ ___ _
8270C (SIM) SW846 8270C SIM SW846 3520C
References:
SW846 11 Test Methods for.Evaluating solid waste, Physical/Chemical
Methods", Third Edition, November 1986.and its Updates.
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SAMPLE SUMMARY
C3Ll.60l.92
WO# SAMPLE# CLIENT SAMPLE ID
F6Q6L 001 EFF/SV-305
NOTE(S)
• The an:alytic:il results of the ~pies lisied abOYe are presented on the following pages.
-All calculations are pcrforma! before rounding to avoid round-off Cmirs In calculated results •.
-Results noled as •ND" were nor detected al or above the Slated limit.
~ 'ibis report mu.'>! not be reproduc.ed, except in full. Without the wrlri.en approval of the laboratory.
-Results for lhc following parameters a.re never reponed on a dry wt:ii:;lil basis: color, corro:.h·ity, density, flashpoint, i&nitibility, la yen, odor,
paint filter test, pH, porosity pressure, reactivity, redo~ potential, specific gravity, spot tests, solids, solubility, temperature, viscosity; and weight .
SAMPLED SAMP
DATE
12/15/03 15 ,28
STL Sll Pittsburgh Chain of
Custody Record Severn Trent Laboratories, Inc.
450 William Pitt Way, Bldg. 6
Pittsburgh, PA 15238
$Tl 4124 (COOi)
CJienl ~ Projecl Mana~ Date Chain of C~s/r 85~. 7 ~1 '..l;-e--~(Nv-,/ .•. ..,_, __ i, . .,
Address Telephone Number (Area.Code}/Fax Number Lab Number I 300'8~ {;.,✓q_, C\.1i-]11~ 1'1'.L-':1. Page of l
C//y ~LO'<'~ I Sta/a I Zip Code Site Cantact Lab Contac;t Analysis {Attach fist if
11\A O l'1-'i -:t.. more s ace is needed ...,
Project Name and Local/on (Sia/a)
(,/'Je,)
Carr/eoWaybi/1 Number . ? ) -~. ,,.=l)o On-'~ <r. '13 '3 '5":,"r B 5s '-f > Special Instructions/
Controcl/Purchase Order/Quote No. . Containers & s ! Conditions of Receipt
-.~ (,_;l>(l 1---01(o;)~ -o''ifn Matrix Preservatives '
Sample J.D. No. and Oescnption Date TimB I ! i i ~ i~ ~ ii. ~-~ Q (Cont:imers tor each sample may be combined on one linef ~-t. "' ~ "''
~-~i: / S✓-3oS \:;J.-1<;;'·0} \S-;i.l'-. I~ \ f..
, ---:
Possible Hazard Identification I Samp/1:1 Disposs.J (A tee may be assess9d If samples are retamed
D Non•H.izard D Flammable 0 Skin lrritanl D PolsonB ~nknmvn O Return To Client ~/sposal By LBb 0 ArchNeFor Months longer tflNI 1 monlh}
Tum Around rime RegwrP.d
0 24 Hours D 48 Hours D 7 Days D f4 Days D 21 Days {;i[o1her
DC Requ1remenrs (Speedy)
, . ReJinQUIShed By Tlma
2. Relinqu1slied By Dalo Time Tims··
1
Dale l TTmo
~Com~-m.-n~,,------------------L------"-----'---~-------------------'------
3. Relinquished By . Time
D/STRl[Jl \VHITE -Returned lo CJ/en/ with Roport: CANARY· Stays with the Sample: PINK· Reid Copy
8
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THE RETEC GROUP INC
Client Sample ID, EFF/SV-305
GC/MS semivolatiles
Lot-Sample# ... : C3Ll60192-001 Work Order# ..• : F6Q6LlAA
Date Received .. : 12/16/03
Analysis Date .• : 12/19/03
Analysis -Time .. , 06:10
Matrix ......•.. : WATER
Date Sampied ... : 12/15/03
Prep Date ...... : 12/17/03
Prep Batch# •.. : 3351292
Dilution Factor: 1.01
PARAMETER
2,4-Dichlorophenol
Pentachlorbpheriol
Phenol
SURROGATE
Nitrobenzene-ds
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenoi
Plienol-dS
2, 4; 6-Tr.ibromophenol
MS Run# ....... :
Method ......... : SW846 8270C SIM
REPORTING
RESULT LIMIT UNITS
ND 0.20 ug/L
ND i.o ug/L
ND 0.20 ug/L
PERCENT RECOVEll.Y
RECOVERY LIMI-T1J,'
61 (30 -· ~21)
67 (11 -il9)
64 (39 -liS)
55 (37 -l.15)
64 (41 -115)
56 (40 -115)
Client Lat# •.. : C3Ll60l.92
MB Lot~sample #: C3Ll70000·292
.Analysis Date .. : 12/19/03
Dilution Factor: i
PARAMETER
2,4...:DichlorOphenOl
P_entachlorophenol
Phenol
SURROGATE
Nitrobenzene-d5
Terphenyl-dl.4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
NOTE (S) : .
METHOD BLANK REPORT
GC/MS Semivolatiles
Work Order # ••• : F6VTll.AA
Prep Date .•.... : 12/17/03
Prep Batcl:t # •.• : 3351292
REPORTING
Matrix ...•..... : WATER
.Analysis Time .. : 01:48
RESULT LIMIT UNITS ==---'---' :cME=TccH~O"D'------
ND
ND
ND
PERCENT
RECOVERY
66
66
68
64
67
59
0.20
1.0
0.20
RECOVERY
LIMITS
(30 -, 1'21\)1
(J.l -i1'9)
(39 . 115)
(37 . 115)
(41 . 115)
(40. -115)
ug/L
ug/L
ug/L
SW846 827DC SIM
SW846 827DC SIM
SWB46 8270C SIM
Calculuions are performed before rounding ro avoid round-off errors in C!.lculatal results.
•
•
•
•
Ll\BORATDRY CONTROL SAMPLE EVALUATION REPORT
GC/MS Semivolatiles
Client LOt # ... , C3Ll60192 Work Order# •.• , F6VT1J_AC-LCS
F6VT11AD-LCSD
Analysis Date .. , 12'/19/03
Analysis Time .• , 05,16
Matrix ....•...• , WATER
LCS Lot-Sample#, C3Ll70000-292
Prep Date ....... , 12/17 /03
Prep Batch# ... , 3351292
Dilution Factor: 1
PERCENT RECOVERY RPD
PARAMETER RECOVERY LIMITS RPD LIMITS METHOD
Phenol 71 (10 -131) SW846 8270C SIM
74 (10 -131) 4.0 (0-43) SW846 8270C SIM
Pentachlorophenol 88 (10 -140) SW846 8270C SIM
109 (10 -140) 21 (0-56) SW846 8270C SIM
2,4-Dichlorophenol 57 (42 -115) SW846 8270C SIM
60 (42· -115) ., .1 (0-44) SW846 8270C SIM
' \
PERCENT •'RECOVERY
SURROGATE RECOVERY LIMITS
Nitrobenzene-dS 63 (30 -121):
67 (30 -121)
Terpheny1-d14 59 (11 -119)
60 (11 -119)
2-Fluorobiphenyl 65 (39 115)
69 (39 -115)
2-Fluorophenol 60 (37 -115)
62 (37 -115)
Phenol-d5 6l (41 -115)
66 (41 -115)
2,4,6-Tribromophenbl 57 (40 -115)
59 (40 -115)
NOTE (S) ,
Calculatiom ore performed before founding to avoid round-off errors in calrulated resulu .
•
•
December 8, 2003
Ms. Beverly Hudson
Remedial Project Manager
U.S. EPA -Region IV, 11th Floor
North Site Management Branch
6 I Forsy1h S1reet, SW
Atlanta, GA 30303
RE:. Monthly Progress Report #127
Remedial Action
Koppers Site -Morrisville, North Carolina
Dear Ms. Hudson:
The RETEC Group, Inc.
3040 William Pill Way
Pittsburgh, PA 15238-1359
.RETEC
. ~
RECEIVED \
'CJEc 2003 •
SUPERFUND I
SECTION ~
In accordance with the Unilateral Order, and on behalf of Beazer East, Inc. (Beazer), please find attached
four (4) copies of the November 2003 Monthly Progress Report for Remedial Action al the Koppers
Superfund Site in Morrisville, No11h Carolina. No exceedences occurred during this event. The
November chronic toxicity testing produced a passing result; therefore, the next chronic toxicity sample
will be collected in the first qua11er of 2004.
Should you need additional information regarding this progress report, please call Mike Helbling at
[phone] or me at [phone].
Sincerely,
The RETEC Group, Inc.
/4~11~
Rita Bauer
Project Geologist
Enclosure·
cc: D. Mattison -NC Snperfund (2 copies)
L. Faulconer -Wake County
G. Caskey -Enwood Structures
M. Helbling -Beazer
11:\Bcaz-Ra lei\ 11 M-03.doc
D. Hails -EAP Industries, Inc.
J. Garret1 -NC Division of Water Quality
M. Matthews -NC Division of Water Quality
P. Ki lchenstein -RETEC
•
•
MONTHLY PROGRESS REPORT #127
REMEDIAL ACTION
SITE NAME: Koppers Superfund Site
Beazer East, Inc.
Morrisville, NC
USEPA DOCKET NUMBERS: 93-09-C
PERIOD ENDING: November 30, 2003
I. PROGRESS MADE THIS MONTH
2.
3.
4.
5.
6.
7.
Remedial Action (RA) -HABITAT MITIGATION. No activities were conducted this
month.
Remedial Action (RA) -GROUNDWATER TREATMENT. The treatment system
operated throughout the month without upset. System performance was monitored on a
biweekly basis. Approximately 41,370 gallons of groundwater were extracted, treated in
the treatment plant, and discharged between November 1, 2003 and November 30, 2003.
System water samples were collected on November 4 and November 21, 2003 in
accordance with the sampling schedule in the O&M manual. Samples were submitted to
Severn Trent Laboratories, Inc. for laboratory analysis. The chronic toxicity samples
were collected the week of November 4, 2003. The operations and sampling programs
are summarized on the attached Table I.
Remedial Action (RA) -EFFECTIVENESS MONITORING PROGRAM. No activities
were conducted this month.
Remedial Action (RA) -CORRESPONDENCE. None.
PROBLEMS RESOLVED
PROBLEMS ANTICIPATED
UPCOMING EVENTS
PERSONNEL CHANGES
SUBCONTRACTORS
None.
None.
Continue System O&M.
None.
None.
ANALYTICAL DA TA Analytical data from system influent and effluent
sampling received during this period are enclosed and are summarized on Table 2 .
11:\Beaz-Ralci\l IM-03.doc
Table 1
Groundwater Treatment Operations and Sampling Program Summary
Koppers Superfund Site
Date Systems Cumulative SV-101 SV-101
Check Effluent Flow Sample Sample
(yes/no) {Gallons) {yes/no) Parameters
01/15/03 ves 3,715,610 ves Penta. 2.4-Dichloro, Phenol.
01/28/03 ves 3,733,790 no
02/11/03 ves 3,753,160 no
02/28/03 ves 3,779,540 no
03/14/03 ves 3 800,330 no
03/24/03 · ves 3,818,300 no
04/09/03 no
04/11/03 ves 3,850,120 ves Penta, 2.4-Dichloro, Phenol
04/21/03 ves 3,869,820 no
05/05/03 ves 3,894,370 no
05/19/03 ves 3,907.850 no
06/02/03 ves 3,944,990 no
06/16/03 ves 3,971,250 no
07/01/03 ves 3,999,940 ves Penta. 2.4-Dichloro, Phenol
07/17/03 ves 4,029,840 no
08/07/03 ves 4,067,970 no
08/21/03 ves 4,094,260 no
09/09/03 ves 4.129,380 no
09/25/03 ves 4,158,630 no
10/14/03 ves 4,191,300 ves Penta. 2.4-Dichloro. Phenol
10/28/03 ves 4,212.360 no
11/04/03 ves 4,224,230 no
11/21/03 ves 4.248,830 no
Notes:
Sampling point SV-101 is located before the Carbon Units (pretreatment)
Sampling point SV-304 is located between the Carbon Units
Dioxin
Morrisville, North Carolina
November 2003
Associated SV-304 SV-304 Associated SV-305
Group Sample Sample Group Sample
(yes/no) Parameters (~es/no)
1,2 ues Penta. 2,4-Dich!oro, Phenol 1 ues
no ues
no ues
no ves
no ves
no ves
no ues
1 ves Penta, 2.4-Dichloro, Phenol 1 ves
no "es
no ves
no ves
no ves
no ves
1 ves Penta. 2.4-Dichloro, Phenol 1 ves
no "es
no "es
no ues
no ves
no ves
1 ves Penta. 2.4-Dichloro, Phenol 1 "es
no ues
no ves
no ves
Associated Groups:
SV-101 -Group 1 is penta, phenol, and 2,4-dichlorophenol; Group 2 is dioxin
SV-304 -Group 1 is penta. phenol, and 2,4-dichlorophenol
SV-305
Sample
Parameters
Penta 2 4-Dichloro Phenol Dioxin
Penta, 2,4-Dichloro. Phenol, Chronic Tox
Penta, 2,4-Dichloro. Phenol
Penta, 2,4-Dichloro Phenol
Penta. 2 4-Dichloro. Phenol
Penta. 2.4-Dichloro, Phenol
Chronic Tax
Penta, 2,4-0ich!oro Phenol, Dioxin
Penta, 2 4-Dichloro Phenol
Penta. 2 4-Dichloro. Phenol
Penta, 2 4-Dichloro. Phenol
Penta, 2,4-Dichloro. Phenol
Penta, 2,4-Dichloro Phenol
Penta, 2.4-Dichloro. Phenol Dioxin
Penta. 2.4-Dichloro, Phenol
Penta. 2.4-Dichloro. Phenol
Penta 2,4-Dichloro Phenol
Penta. 2.4-Dichloro. Phenol Chronic Tox
Penta, 2,4-Dichloro. Phenol
Penta, 2.4-Dichloro. Phenol. Dioxin
Penta. 2.4-Dichloro, Phenol
Penta, 2.4-Dichloro, Phenol, Chronic Tax
Penta, 2.4-Dichloro. Phenol
Sampling point SV-305 is loctated after the Carbons Units (post-treatment) SV-305 -Group 1 is penta, phenol, and 2,4-dichlorophenol; Group 2 is dioxin and Group 3 is chronic toxicity
H:\Prc,jec1>,\03624\Rep<>rts\Mcnlhly\ 1 OM--Ol •
Associated
Group
1,2
1,3
1
1
1
1
3
1 2
1
1
1
1
1
1.2
1
1
1
1,3
1
1,2
1
1,3
1
•
•
H·\Projecto\0362~\Reports\Mon!hlv\ 11 M-03
Table 2
Groundwater Treatment Analytical Data Summary
Koppers Superiund Site• Morrisville, North Carolina
November 2003
Analytical
Parameter Date Sample Sample
Sample Location Location
Collected SV-101
Pentachloroohanol 01/15/03 17
01/28/03
02/11/03
02/28/03
03/14103
03/24103
04111103 21
04/21103
05/05103
05/19103
06/02/03
06/16/03
07/01/03 20
07/17/03
08/07103
08/21103
09/09/03
09/25/03
10/14/03 22
10/28/03
11/04/03
11/21/03
2.4-0Ichloronhenol 01/15/03 <0.19
01/28/03
02/11/03
02/28/03
03/14/03
03/24/03
04/11/03 <0.81
04/21/03
05/05/03
05/19/03
06J02103
06J16103
07101103 <0.78
07117103
08107/03
08121/03
09/09103
09/25/03
10114/03 <0.59
10128103
11104103
11/21103
Phenol 01115/03 <0.19
01128/03
02111103
02128,03
03/14/03
03/24I03
04111/03 <0.81
04/21/03
05/05103
05/19/03
06102/03
06J16/03
07/01103 <0.78
07117/03
08107103
08121/03
09/09103
09125/03
10114103 <0.59
10128103
11/04/03
11/21/03
Chronic Toxic1tv 01128103
04109103
09109103
11104103
Dioxin 12 3 7 8-TCDD 01115/03 <0.22
04/11103
07/01103
10114103
Note•. An re,ults are m rnccrogr•me pet hter (1g/L) e•cept ,!;o.,n. Dlo"n d~ta Ls ,n p,cogram• per l11er (py/lj .
SV-101 -Belote Ca,bon Un,11
'SV-304 -Between Carbon Un,11
"SV-305. After Caibon Unit1
SV-304'
<1.0
<0.96
<0.97
<0,95
<0,20
<0.19
<0,19
<0.19
<0,20
<0.19
<0.19
<0,19
Sample
Location
SV-305"'
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.1
<1.0
<1.0
<0.98
<0,98
<0,98
<0.99
<0.97
<1.0
<1.0
<0.99
<0.97
<1,0
<0.98
<1.0
<1,0
<0 21
<0.20
<0.20
<020
<0,20
<0.20
<0.21
<0.20
<0.20
<0.20
<0.20
<020
<0.20
<0.19
<0.20
<0.20
<0.20
<0.19
<0.20
<0.20
<0.20
<0.20
<0.21
<0.20
<0.20
<0.20
<0.20
<0.20
<0.21
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.19
<0.20
<0.20
<0.20
<0.19
<0.20
<0.20
<0.20
<0,20
Pass
Pass
Pass
Pass
<0.28
<0,27
<1.90
<1.10
•
• t •I • •'' •
i Leaders in Environmental Testing ', ' ' .
ANALYTICAL REPORT
Raleigh,.Biweekly NPDES
Lot#: C3KOS0212
Rita Bauer
The RETEC Group Inc
SEVERN TRENT Ll\BORATORIES; lNC.
Veronica Bertot
Project Manager
November 12. 2003
STL Pittsburgh
450 William Pitt Way
Pittsburgh, PA 15238
STL
Tel, 412 820 8380 Fax, 412 820 2080
www.stl~inc.com
Severn Trent Laboratories, Inc.
STL
NELAC REPORTING:
The foITilat and content of the attached report meets NELAC standards and guidelines except as noted in the narrative. The table below
presetits a summary of the certi:5.Cations held by STL Pittsburgh. Our primary acCremte.tion authority for the Non-potable water and Solid
& Hazardous waste programs is New York State DOH. A i:nore detailed parameter list iS available upon req\leSt. Pk.ase ask your project
manager for this information when rcqlllred.
The codes utiliZed for program types are described below;
HW Hazardous Waste certification
WW Non-potable Water ancj.Jor WastewateJ"certification
X laboratory has some form of certification under the specific program. Many states certify laboratories for specific parameters or
tests within a category. The information in the table indicates the lab is certified in a general category of testing. Pleas,e contact
the laboratory if parameter Specific certification information Is required.
•
•
•
•
Sample Receiving:
CASE NARRATIVE
THE RETEC GROUP
Raleigh, Biweekly NPDES
STL Lot# C3K050212
STL Pittsburgh, PA received one sample on November 5, 2003 in good condition. The
cooler was received within the proper temperature range.
If project specific QC was not reqnired for samples contained in this report and batch QC
was completed on these samples, anomalons results will be discussed below.
GC/MS Semivolatiles SIM:
The reporting limits were adjusted according to the amount of sample extracted.
Since insufficient sample volume was received to perform a matrix spike and matrix
spike duplicate, a Laboratory Control Sample (LCS) and Laboratory Control Duplicate
(LCD) were perfom1ed. All recoveries were within QC limits .
METHODS SUMMARY
C3K0502l2
ANALYTICAL PREPARATION
PARAMETER METHOD ~M~E~T~H~O~D~----
8270C (SIM) SW846 8270C SIM SW846 3520C
References:
SW846 11 Test Methods for Evaluating Solid Waste, Physical/Chemical
Methods", Third Edition, November 1986 and its updates.
•
•
•
•
•
•
SAMPLE SUMMARY
C3K050212
WO# SAMPLE# CLIENT SAMPLE ID
F36R4 001 EFF/SV-305
NOTE (S) ,
• Toe analytical results of the samples listed above arc presented on the following pages.
• All c.alcu!ations arc pcrfonned before rounding to avoid round-off errors in calculated results.
-Results noted as "ND" were not detec!ed at or above the stated limit,
• l11is report must not be reproduced, except in full, without the written approval of the laboratory.
• Results for the following parameters are never reported on 'a dry weight basis; color, COrrosivity, density, flashpoint, ignitabi!ity, Jay en, odor,
paint filter test, pH, porosity pressure, reactivity, rcr.lox potential, sPecilic gravity, spot tests, solids, ~olubi!ily, tempcrnturc, viscosity, and weight.
SAMPLED
DATE
SAMP
TIME
11/05/03 09, 15
SEVERN
TRENT STL S11. Pittsburgh Chain of
Custody Record Seve~n Trent Laboratories, Inc. 450 William Pitt Way, Bldg. 6
Pittsburgh,.PA 15238
STL-4124 (0901)
Client {)_jw Project Mam-tu.... rs-~
Address ~.,1..v-Av~ _Qphone Number (Area Code)/Fax Number
'300 ~-0 5-Jf..: t '-I~ :>... Cily 4'v'-~ I MA--1 "P ~·1+2 Site Contact Lab Contact
ProJect Name and ~ration o~:~) (Ne..) ea;;,N:,ac;umbef t{ 7</?oSJ:J'i]
,.___ Iv. 'B .J>A"Z-if I I) -'\,. ~ Cont~t~·2°1":"o:iG.2 4 -0'1 ~ Containers & ' -Matrix Preservatives ~ "
Sample I.D. No. and Description Date i I Q " , b> ~ Time . -! ~ ~ Q ~-~ ~~ ~ (Containers for each sample may be combined on one line) -S < .. < i <
[.PF/ !,,J~"Jt)'5 111.J/03 Ml< ."\I '{ I)<
'
Possible Hazard /denrification I Sample Disposal
~sposal By Lab D Non-Hazard D Flammable· D Skin Irritant D PoisonB ~ lnknown D Return To Client 0 Archive For
Turn Around Time Requ,red
D 24 Hours
' QC Requirements (Specify)
14 Days D 21 Dnys Other fS'[D
2. Relinquished
3. Relinquished By
1
Date
Comments
WHITE. Returned to Client with Report:-CANARY. Slays with the Sample: PINK. Field Copy
.
Date { I/ Chain of Custoo'v Number
/( L) OJ. 184395
Lab Number I l Page of
Analysis (Attach .list if
more snace is needed
Special Instructions/
Conditions of Receipt
.
(A fee may be assessed if samples are retained
Months longer than 1 month)
Date Time
Date Time
Date It i-;:, > Time I oz.·)-~----
• I
0
TilB RETEC GROUP INC
Client Sample ID, EFF/SV-305
GC/MS semivolatiles
Lot-Sample# ... , C3K050212-001 Work Order# ... : F36R41AA
Date Received .. , 11/05/03
Analysis Date .. , 11/10/03
Analysis Time .. : 13:39
Matrix ......... : WATER
Date Sampled ... , 11/05/03 MS Run ll .....•. ,
Prep Date ...... , 11/07/03
Prep Batch# ... , 3311398
Dilution Factor: 1.01
Method ......... , SW846 8270C SIM
REPORTING
PARAMETER RESULT LIMIT UNITS
2,4-Dichlorophenol ND 0.20 ug/L
Pentachlorophenol Nb 1. 0 ug/L
Phenol ND 0.20 ug/L
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Nitrobenzene-d5 57 (30 -121)
Terphenyl-dl4 62 (11 -119)
2-Fluorobiphenyl 51 (39 -115)
2-Fluorophenol 48 (37 -115)
Phenol-d5 49 (41 -115)"
2,4,6-Tribromophenol 74 (40 -ll5)
Client Lot# ... : C3K050212
MB Lot-Sample#: C3K070000-398
Analysis Date .. : 11/10/03
Dillltion Factor: 1
PARAMETER
2,4-Dichloropheriol
Pentachlorophenol
Phenol
SURROGATE
Niti-obenzene-dS
Terphenyl-d14
2-Fluorobiphenyl
2-Fl\lorophenol
Phenol-d5
2,4,6-Tribromophenol
NOTE (S) :
METHOD BLANK REPORT
'GC./MS Semivolatiles
Work Order# ... : F4DF21AA
Prep Date ...... : 11/07/03
Prep Batch # .•• : 3311398
REPORTING
RESULT LIMIT
ND 0. 20
ND l. 0
ND 0.20
PERCENT RECOVERY
RECOVERY LIMITS
63 (30 -121)
72 (11 -119)
65 (39 115)
57 (37 115)
62 (41 -115)
85 (40 115)
Calculations are perfonned before rounding to avu)d round-off errors in calculated results.
•
Matrix ......... : WATER
Analysis Time .. : 12:16
UNITS METHOD
ug/L SW846 8270C SIM
ug/L SW846 8270C SIM
ug/L SW846 8270C SIM
•
•
0
•
LABORATORY CONTROL SAMPLE EVALUATION REPORT
GC/MS Semivolatiles
Client Lot# ... , C3K050212 Work Order# ... , F4DF21AC-LCS
F4DF21AD-LCSD
Analysis Date .. , 11/10/03
Analysis Time .. : 12:44
Matrix ......... : WATER
LCS Lot-Sample#, C3K070000-398
Prep Date ...... , 11/07/03
Prep Batch# ... , 3311398
Dilution Factor: 1
PARAMETER
Phenol
Pentachlorophenol
2,4-Dichlorophenol
SURROGATE
Nitrobenzene-dS
Terphenyl-d14
2-FlUorobiphenyl
2-Fluorophenol
Phenol-dS
2,4,6-Tribromophenol
NOTE(S),
PERCENT
RECOVERY
57
62
119
133
91
97
RECOVERY RPD
LIMITS RPD LIMITS
(10 -131)
(10 -131) 9.0 (0-43)
(10 -140)
(10 -140) 11 (0-56)
(42 -115) •
(42 115) 6.2 (0-44)
PERCENT RECOVERY
RECOVERY LIMITS
58 (30 -121)
61 (30 -121)
62 (11 119)
66 (11 -119)
61 (39 -115)
65 (39 -115)
53 (37 -115)
63 (37 -115)
55 (41 -115)
56 (41 -115)
86 (40 -115)
92 (40 115)
Calculations are performed before rounding to ~void round-off errors in calculated result.s .
METHOD
SW846 8270C SIM
SW846 8270C SIM
SW846 8270C SIM
SW846 8270C SIM
SW846 8270C SIM
SW846 8270C SIM
0
• ' Leaders in EnvirOnmental Testing.
ANALYTICAL REPORT
Raleigh, BiWeekly NPDES
Lot#, C3K220163
Rita Bauer
The RETEC Group Inc
SEVERN TRENT LABORATORIES, JNC.
eronica Bertot
Project Manager
December 2, 2003
,s EVE RN
STL Pittsburgh
450 William Pitt Way
Pittsburgh, PA 15238
STL
Tel, 412 820 8380 Fax, 412 820 2080
www.stl-inc.com
Severn Trent Laboratories, Inc.
Sample Receiving:
CASE NARRATIVE
THE RETEC GROUP
Raleigh, Biweekly NPDES
STL Lot# C3K220163
STL Pillsburgb, PA received one sample on November 22, 2003 in good condition. The
cooler was received within the proper temperature range.
If project specific QC was not required for samples contained in this report and batch QC
was completed on these samples, anomalous results will be discussed below.
GC/MS Semivolatilcs SIM:
The reporting limits were adjusted according to the amount of sample extracted.
Since insufficient sample volume was received to perfom1 a matrix spike and matrix
spike duplicate, a Laboratory Control Sample (LCS) and Laboratory Control Duplicate
(LCD) were performed. All recoveries were within QC limits.
•
•
•
•
METHODS SUMMARY
C3K220163
ANALYTICAL PREPARATION
PARAMETER METHOD "M"'E"'T~HccOccDc__ ___ _
8270C (SIM) SW846 8270C SIM SW846 3520C
References:
SW846 "Test Methods for Evaluating Solid waste, Physical/Chemical
MethodS 11 , Third Edition, November 1986 and its updates .
SAMPLE SUMMARY
C3K220163
WO# SAMPLE# CLIENT SAMPLE ID
FSGLH 001 EFF/SV-305
NOTE (S):
-The analytical results of Lhc samples listed above are presented on the following pages.
• All c:ikulations are performed before rounding to avoid round-off errors in calculated results.
-Results noted as "ND" were not detected at or above the stated limit.
• This repon must not be reproduced, exc.cpt in full; withoUt the written approval of the laboratory.
-Results for the following parameters arc never reported on a dry weight basis: color, conosivi1y, density, nashpoint, ignitability, layers, odor,
paint filter test, pH, poro~ity pressure, rcactivily, redox potential, specific graviiy, spot lests, so!idS, so!ubilitY, temperature, viscosity, and weight,
SAMPLED
DATE
•
SAMP
TIME
11/21/03 08,17
•
•
• • •
'"SE V:E RN:: STL STL Pittsburgh Chain of
Custody Record Severn Trent Laboratories, Inc.
450 William Pitt Way, Bldg. 6
Pittsburgh, PA 15238
STL -1124 (OclDq CflentQ~
·.~!UtJ
Pro1ect unager
;--k-,.. \5~ Date.\ J l \ ::.., (3
Cham of Gust! 84e2 2 a
Address ¼ -Av-0 I 9ephone Number (Area Coda)/Fa"x Number Lab Nun'lber I I c7 . l<"<'s-Jt-rc/)-:i. '300 pc,, 'f Page of
c;,y C ,~ /m;;_ lz;;;~w.Q Site Contact Lab Contact Analysis (Attach fist if
0"'1..n v7· mores ace is needed
Pro1ect Nam~ Location (State) p,,O"J71h 9i J 6
Carrier/Waybill Number s::I.J c lc~-zvr f'e,lr.:.y S-i 17• Ju':,5 )Sc, _P;r · Special /hstructions/
Corwact'Purchase Order/Quote N . I I Containers & ":, x Conditions of Receipt
'1?..rc.,A-Z,1--03(.,--:,, oq l:, Matrix Preservatives -iQ '-'\
Sample f.O. No. and Description ' ~ Q ' X sx Date Time ,.
~ ~ " " 0 G 0 ~~ ~ (Contamers for each sample may be combined on one line) ;; • § ' l' i . ' X X
£-f:.P I <:,v /1 {J ,,--1,I 1AI \J} 0'31"1 ; ' 'f..
'
Possible Hazard /dent1fica110n I Sample Disposal
~isposal By Lab D Non-Hazard D Flammable D Skin lmtant D Poison B '0"'unknown D Return To Client D Archive For
(A fee may be ;:issessed if samples are retained
Months longer tniJn I month)
Turn A-ound Time Ra wr ' ' QC Reqwremen,s (Spec ry)
D 24 Hours D 14 Days O 21 Days
2. Relinou[she Time·
3. Relinquished By Time Time
Comments
J/STR/BUT/ON: WHITE -Returned to Client with Report: CANARY -Stays with the Sample: PINK -Field Copy
TIIE.RETEC GROUP INC
Client Sample ID, EFF/SV-305
GC/MS Semivoiatiles
Lot-Sample# ... , C3K220163-001 Work Order# ... : FSGLHlAA
Date Received .. : 11/22/03
Analysis Date .. , 11/26/03
Analysis Time .. : 12:08
Matri"x ......... : WATER
Date Sampled ... , 11/21/03
Prep Date ...... , 11/23/03
P±eP aatch #--·= 3330353
Dilution Factor: 1.01
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-dS
Terphenyl-d14
2-Fluorobiphenyl
2-Fluorophenol
Phenol-dS
2,4,6-Tribromophenol
MS Run# ....... ,.
Method ......... , SWB46 8270C SIM
REPORTING
RESULT LIMIT UNITS
ND 0.20 ug/L
ND 1.0 ug/L
ND 0.20 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
64 (30 -121)
72 (11 -119)
61 (39 -115)
54 (3 7 -115)
57 (41 -115)
59 (40 -115)
•
•
•
0
•
METHOD BLANK REPORT
GC/MS Semivolatiles
Client Lot# ... : C3K220163 Work Order# ... : F5NFX1M
MB Lot-Sample#: C3K260000-353
Prep Date ...... : 11/23/03
Arialysis Date .. : 11/26/03 Prep Batch# ... : 3330353
Dilution Factor~ 1
PARAMETER
2,4-Dichlorophenol
PentachlOrophenol
Phenol
SURROGATE
Nitrobenzene-dS
Terphenyl -dH
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
NOTE(S),
RESULT
ND
ND
ND
PERCENT
RECOVERY
63
80
65
60
63
58
Calculations are performed before rounding to avoid round-off errors in calculated rcSUlis .
REPORTING
LIMIT
0.20
1.0
0. 20
RECOVERY
LIMITS
(30 -121)
(11 -119)
(39 -115)
(37 -115)
(41 -115)
(40 -115)
Matrix ......... : WATER
Analysis Time .. : 08:29
UNITS METHOD
ug/L SW846 8270C SIM
ug/L SW846 8270C SIM
ug/L SWB46 8270C SIM
LABORATORY CONTROL SAMPLE EVALUATION REPORT
GC/MS ·semivolatiles
Client Lot# ... : C3K220163 Work Order# ... : FSNFXlAC-LCS
F5NFX1AD·LCSD
1\nalysis Date .. : 11/26/03
Analysis Time .. : 08:56
Matrix ......... : WATER
LCS Lot-Sample#: C3K260000·353
Prep Date ...... : 11/23/03
Prep Batch# ... , 3330353
Dilution Factor: 1
PERCENT RECOVERY RPD
PARAMETER RECOVERY LIMITS RPD LIMITS METHOD
Phenol 68 (10 131) SW846 8270C SIM
65 (10 131) 5.0 ( 0-43) SW846 8270C SIM
Pentachlorophenol 60 (10 . 140) SW846 8270C SIM
60 (10 140) 0.72 (0-56) SW846 8270C SIM
2,4-Dichlorophenol 65 (42 115) SW846 8270C SIM
66 (42 . 115) l. 7 (0-44) SW846 8270C SIM
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Nitrobenzene-dS 67 (30 . 121)
68 (30 121)
Terphenyl-dl4 8.1 (11 -119)
88 (11 . 119)
2-Fluorobiphenyl 67 (39 . 115)
70 (39 -115)
2.:...Fluorophenol 64 (37 . 115)
57 (37 . 115)
Phenol-d5 63 (41 -115)
63 . (41 . 115)
2;4,6-Tribromophenol 70 (40 . 115)
73 (40 . 115)
NOTE (S) ,
Calculations arc pctfonned bcfoie rounding to avoid round-off errors in calculated results,
•
•
•
•-· Prepared for ---
RAY STEPINSKY
THE RETEC GROUP
3040 WILLIAM PITT WAY
PITTSBURGH, PA 15238
Project ID: 01
Project ID: BIOASSAY
No. Sample ID
001 EFF. OUTFALL
Test Performed
Bloassay, Chronic Pass/Fail
TRITEST, INC.
3909 Beryl Road
Raleigh, NC 27607
Telephone: [phone]
Fax: [phone]
NC/WW Cert.#: 067
NC/DW Cert.#: 37731
Laboratory Report
1 of 1
Report Date: 11/24/2003
Date Received: 11/4/2003
Work Order#: 0311-00072
Gust. Code: RE1422
Gust. P.O.#: NEEDS REPORT BY 10TH
Date Sample, Time Sample, Matrix
11/4/2003 09:30 WW
Method Results
NC Pass/Fail SEE ATTACHED#
Analyzed
11/18/03
Condition
4n2o,C
Qualifier
#ANALYZED BY PACE ANALYTICAL SERVICES, INC., ASHEVILLE, NC.
0
• Report Certified by:
for Tritest, Inc.
Pace Analytical Services, Inc.
A I , / ® 2225 Riverside Drive ace na yf tca Asheville, NC 28804
www.pa~b.!@111bToxicity Report AT-1 Form Chronic Pass/Fail and Acute LC5cf"~~! ~~~~~;:;~;~
Date 11118103 •
Facility: Retec NPDES#NC Pipe# Eff.
County Wake
Laboratory Performing Test PACE Analytical Services Inc.
Comments
03jl -ooo l?-,
Signcture·o;~~:~ator in Res~onsibln✓,,._, I ,-c· ,,<,',, / , "-1
Sianatu(.e ~ (aboratorv Su~rviiOr // Samples Not Aerated Unless Otherwise Noted
~ -Environmental Sciences Branch Chronic Test Results --MAIL ORIGINAL TO: Div. of Water Quality Calculated t -1.548 N.C. DENR
1621 Mail Service Center
Raleigh, North Carolina 27699-1621 Tabular t 2.508
North Carolina CeriodaQ.hnia Chronic Pass/Fail Re~roduction Toxicitt Test % Reduction 0
CONTROL ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 12
% Mortality Avg. Reprod.
# Younq Produced 25 26 31 30 28 28 31 34 28 29 27 30 Control Control
Adult (L)ive (D)ead L L L L L L L L L L L L 0.00 28.90
Treatment 2 Treatment 2
Effluent% I 90 I 0.0 30.80
r.nntrnl r.v
TREATMENT 2 ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 12 I 8.5 I PASS FAIL
# Youna Produced 29 30 31 29 28 36 32 35 31 34 30 24 %control organisms xi producing 3rd brood
Adult (L)ive (D)ead L L L L L L L L L L L L I 100.0 I Check One
lcomE!lete This For Either Test I Test Start Date:
1st 1st 2nd 1115\03
pH Control ~ ~ ~ Collection Start Date
Treatment 7.9 8.0 Sample 1 1113103 Sample 2 1116103 1 0
s E s E s E Samoel TvoeJDuration
I I I " -~ " " " .,,,
' a Grab Comp. Duration . ~
d d a d ~ l! ci
' ' ' 0
Sample 1 X ~:;, I I I X 24hr 0 u, ~ • o• 3 " 3 Sample 2 0 u :$ ]-1st 1st 2nd X 24hr " ..
0.0 Control ~ ~ ~ Hardness (mg/I) 46
Treatment 8.6 8.5 Soec. Cond. (umhosl 149 7 4 912 889
Chlor!ne (mg/I)
1<01 <0.1
LC~QlAcute Io11i£ity Test Samele temo. at receiot /Cl 0.5 2.0
(Mortalitv exoressed as % . combinino reolicatesl &
% % % % % % % % %
Concentration Note: Please
Complete This
% % % % % % % % % Section also Mortality
LC50= % Method of Determination start/end start/end
95% Confidence Moving Avg. Probil 7 -
% -% Spearman Other
Organism Tested: Ceriodaohnia dubia Test Duration (Hours):
Asheville Certification IDs
NC Wastewater 40
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
EE Control ~ High
Cone
Charlotte Certification IDs
NC Wastewater 12
•
•
NC Drinking Water 37712
SC Environmental 99030
FL NELAP E87648
NC Drinking Water 37706
SC 99006
FL NELAP E87627
• e
AQUATIC TOXICOLOGY LABORATORY
CHAIN-OF-CUSTODY AND FIELD ANALYSIS FORM
Environmental Testing Solutions, LLC
351 DepotStreet
AsheviBe, NC 28801
Phone: [phone]
Fax: [phone]
CJ'1~! I FACl~Y NAME·,/) {)
rJ --./.(;._"Z,1.,r r ... -k
COUNTY: v--\<..,..\
NPDES PERMIT#: :,.r,..I,~✓
PURCHASE ORDER#:
STATE: /\If
OUTFALL/ PIPE#:
i;-""'
INFORMATION ON THIS FORM IS REQUIRED
BY STATE AND FEDERAL AGENCIES.
TEST REQUIREMENTS (Please check the appropriate test type and species required.) '"'19:__,~_ .. ___ " · · ~. Chronic, 7-days
Pass I Fail, dilution required:
Full Range Definitive, dilutions required·
Other, specify: _________________ _
SAMPLE TYPE
Com 1pos1te samp e
Start date: 11/Jlo, !Start time: 0'-'l)O
End date: td<-1\o") I End time: v-tJO
Samples per hour. I
Chilled during collection?: 7
If chilled, specify temperature: L, ......
Grab sample
loate: -)rime: -
REMARKS
SAMPLE CUSTODY
Sample collected by: I ,4.-vv, jftil
PRIN[
RJnb~(\ \I Uc:\\J~
. PR!NT SIGNA.AAE
Relinquished to ETS by:
I I OATENOTu.E
Species
Ceriodaphnia dubia (Water flea)
Pimephales prome/as (Fathead minnow)
Daphnia pu/ex
Gyprinodon variegatus (Sheepshead minnow)
Menidia berylfina (Inland silverside)
Mysidopsis bahia (Mysid shrimp)
Other, specify: --------------
Sam I · t, p e tn ormation
Sample location: (after chlorinalion, above :;tat weir, e~u~rt o~ao, etc.)
Approximate volume collected for testing: V I 1 1/
Number of containers filled for testing: a
Total residual chlorine {mg/I..);
Temperature at time of collection rq:
Method of transport to ETS:
Note; Rinse containers with the sample before filling. Pack sample in loose ice.
Samples must be received at ETS at or below4•c. Sample should not be frozen.
FOR OFFICE USE ONLY PROJECT#
CLIENT ID#; SAMPLE#:
Received b
llA.TENOTII.£
/o: '-{ 0
I • • • AQUATIC TOXICOLOGY LABORATORY
CHAIN-OF-CUSTODY AND FIELD ANALYSIS FORM
Environmental Testing Solutions, LLC
351 DepotStreet
AsheviUe, NC 28801
Phone: [phone]
Fax: [phone] L PURCHASE ORDER#:
STATE:
OUTFALL/ PIPE#: INFORMATION ON THIS FORM IS REQUIRED
BY STATE AND FEDERAL AGENCIES.
TEST REQUIREMENTS (Please check the appropriate test type and species required.)
Test type
24. 48 96 hours
Chronic, 7-days
Acute, circle th. e appropria. te test duration:
Pass/ Fail, dilution required: ___________ _
F:ull Range Definitive, dilutions required:
Other, specify: _________________ _
SAMPLE TYPE
Co mposite sample ,
Start date: itfr,tn
End date: 11/,/c')
Samples per hour.
Chilled during collection?:
!f chilled, specify temperature:
Grab sample
Joate:
REMARKS
I Start time:
I End time:
l
y .,e:....., 0(..
/Time:
SAMPLE CUSTODY
Sample collected by:
IA~4r1I lc4J.QJ
PRINT SIGW!.TLR€
PRINl S!GNA,~E
"'"'" .,,, 0
DATEN-OTl!,,E
Species
Ceriodaphnia dubia (Water flea)
Pimephafes promefas (Fathead minnow)
Oaphnia pu/ex
Cyprinodon variegatus (Sheepshead minnow)
Menidia beryllina (Inland silverside)
Mysidopsis bahia (Mysid shrimp)
Other, specify: ----------------~-
Sample information
Sample location: {after chlorination, above outfal, at weir, effluent outfaD, etc.)
Approximate volume collected for testing: _\ fl
Number of containers filled for testing; ~
Total residual chlorine (mgll):
Temperature at time of collection (0C):
Method of transport to ETS:
Note: Rinse containers wlth the sample before filling. Pack sample in loose ice.
Samples must be received at ETS at or below 4•c. Sample should not bo frozen.
FOR OFFICE USE ONLY
CLIENT ID#;
PROJECT#: 4 -~ _/ , ~\{/;tj
SAMPLE#: { r:J .--1~ -.Jur j ><
DATE NO Tit.£
on receipt at ETS (° CJ: I J-0
•
•
November 5, 2003
Ms. Beverly Hudson
Remedial Project Manager
U.S. EPA -Region IV, 11th Floor
North Site Management Branch
61 Forsyth Street, SW
Atlanta. GA 30303
RE: Monthly Progress Report #126
Remedial Action
Koppers Site -Morrisville, North Carolina
Dear Ms. Hudson:
The RETEC Group, Inc,
3040 William Pitt Way
Pittsburgh, PA 15238-1359
[phone] Phone
[phone] Fax
www.retec.com
In accordance with the Unilateral Order, and on behalf of Beazer East, Inc. (Beazer), please find altached
four (4) copies of the October 2003 Monthly Progress Report for Remedial Action al the Koppers
Supcrfund Sile in Morrisville, North Carolina. No cxcccdences occurred during this event.
Should you need additional information regarding this progress report, please call Mike Helbling at
[phone] or me al [phone] .
Sincerely,
The RETEC Group, Inc.
~//1~ t-t~E o
Rita Bauer
Project Geologist
Enclosure
cc: D. Mattison -NC Superfund (2 copies)
L. Faulconer -Wake County
G. Caskey -Enwood Structures
M. Helbling -Beazer
H:\Bcaz-Ralci\101\1-03.doc
D. Hails -EAP Industries, Inc.
J. Garrett-NC Division of Water Quality
M. Matlhews -NC Division of Water Quality
P. Kilehenslein -RETEC
•
•
MONTHLY PROGRESS REPORT #126
REMEDIAL ACTION
SITE NAME: Koppers Superfund Site
Beazer East, Inc.
Morrisville, NC
USEPA DOCKET NUMBERS: 93-09-C
PERIOD ENDING: October 31, 2003
I. PROGRESS MAD~: THIS MONTH
2.
3.
4.
5.
6.
Remedial Action (RA) -HABITAT MITIGATION. No activities were conducted this
month.
Remedial Action (RA) -GROUNDWATER TREATMENT. The treatment system
operated throughout the month without upset. System performance was monitored on a
biweekly basis. Approximately 53,730 gallons of groundwater were extracted, treated in
the treatment plant, and discharged between October I, 2003 and October 31, 2003.
System water samples were collected on October 14 and October 28, 2003 in accordance
with the sampling schedule in the O&M manual. Samples were submitted to Severn
Trent Laboratories, Inc. for laboratory analysis. The operations and sampling programs
are summarized on the attached Table I.
Remedial Action (RA) -EFFECTIVENESS MONITORING PROGRAM. No activities
were conducted this month.
Remedial Action (RA) -CORRESPONDENCE. None.
PROBLEMS RESOLVED
PROBLEMS ANTICIPATED
UPCOMING EVENTS
PERSONNEL CHANGES
SUBCONTRACTORS
None.
None.
Continue System O&M.
None.
. None.
7. ANALYTICAL DATA Analytical data from system influent and effluent
sampling received during this period are enclosed and are summarized on Table 2 .
1-1:\lkaz-Ralci\l0M-03.doc
• •
Table 1
Groundwater Treatment Operations and Sampling Program Summary
Koppers Superfund Site
Date Systems Cumulative SV-101 SV-101
Check Effluent Flow Sample Sample
(yes/no) (Gallons) (yes/no) Parameters
01/15/03 yes 3,715,610 yes Penta, 2,4-Dichloro Phenol, Dioxin
01/28/03 yes 3,733,790 no
02/11/03 ves 3,753 160 no
02/28/03 ves 3,779 540 no
03/14/03 yes 3.800.330 no
03/24/03 Yes 3,818,300 no
04/09/03 no
04/11/03 ves 3 850 120 ves Penta. 2,4-Dichloro Phenol
04/21/03 yes 3 869,820 no
05/05/03 yes 3,894 370 no
05/19/03 ves 3,907.850 no
06/02/03 ves 3,944,990 no
06/16/03 yes 3.971,250 no
07/01/03 yes 3.999.940 yes Penta 2.4-Dichloro. Phenol
07/17/03 Yes 4 029.840 no
08/07/03 ves 4,067,970 no
08/21/03 ves 4,094,260 no
09/09/03 yes 4,129,380 no
09/25/03 ves 4,158,630 no
10/14/03 ves 4,191,300 ves Penta, 2.4-Dichloro Phenol
10/28/03 ves 4.212,360 no
Notes:
Sampling point SV-101 is located before the Carbon Units (pretreatment)
Sampling point SV-304 is located between the Carbon Units
Morrisville, North Carolina
October 2003
Associated SV-304 SV-304 Associated SV-305
Group Sample Sample Group Sample
(yes/no) Parameters (yes/no)
1,2 yes Penta. 2,4-Dichloro, Phenol 1 ves
no ves
no yes
no ves
no ves
no yes
no yes
1 ves Penta 2 4-Dichloro Phenol 1 ves
no ves
no ves
no yes
no Yes
no ves
1 ves Penta. 2.4-Dichloro. Phenol 1 ves
no ves
no yes
no Yes
no ves
no ves
1 ves Penta. 2.4-Dichloro. Phenol 1 Yes
no yes
Associated Groups:
SV-101 -Group 1 is penta, phenol, and 2,4-dichlorophenol; Group 2 is dioxin
SV-304 -Group 1 is penta, phenol, and 2.4-dichlorophenol
SV-305
Sample
Parameters
Penta. 2.4-Dichloro. Phenol. Dioxin
Penta. 2,4-Dichloro, Phenol. Chronic Tox
Penta. 2.4-Dichloro. Phenol
Penta. 2,4-Dichloro, Phenol
Penta. 2.4-Dichtoro, Phenol
Penta. 2,4-Dichloro. Phenol
Chronic Tax
Penta. 2.4-Dichloro, Phenol, Dioxin
Penta, 2,4-Dichloro, Phenol
Penta, 2,4-Dichloro, Phenol
Penta. 2.4-Dichloro, Phenol
Penta. 2.4-Dichloro. Phenol
Penta, 2,4-Dich!oro Phenol
Penta. 2,4-Dichloro Phenol, Dioxin
Penta. 2,4-Dichloro, Phenol
Penta, 2,4-Dichloro, Phenol
Penta. 2,4-Dichloro, Phenol
Penta, 2.4-Dichloro. Phenol, Chronic Tax
Penta. 2,4-Dich!oro Phenol
Penta 2 4-Dichloro Phenol, Dioxin
Penta. 2 4-Dichloro. Phenol
Sampling point SV-305 is lactated after the Carbons Units (post-treatment) SV-305 -Group 1 is penta, phenol. and 2,4-dichlorophenol; Group 2 is dioxin and Group 3 is chronic toxicity
H:\Projects\03624\Repoits\Monthly\ 1 0M--03
Associated
Group
1,2
1,3
1
1
1
1
3
1.2
1
1
1
1
1
1,2
1
1
1
1,3
1
1,2
1
•
•
Table 2
Groundwater Troatment Analytical Data Summary
Koppers Superfund Site -Morrisville, North Carolina
October 2003
Analytical
Parameter Date Sample
Sample Location
Collected SV-101
Pentachloroohenol 01/15/03 17
01/28/03
02/11/03
02/28/03
03/14/03
03/24/03
04111/03 21
04121/03
05105/03
05/19/03
06102/03
06116/03
07/01/03 20
07/17/03
08/07/03
08121103
09/09/03
09/25/03
10/14/03 22
10128/03
2.4-Dichloroohenol 01/15/03 <0.19
01/28/03
02/11/03
02/28/03
03/14/03
03124/03
04111/03 <0.81
04121103
05/05103
05119/03
06102/03
06/16103
07/01/03 <0.78
07/17/03
OB/07103
08/21103
09/09103
09/25103
10/14103 <0.59
10/2B103
Phenol 01115103 <0.19
01/2B/03
02/11103
02/28103
03/14103
03/24/03
04/11103 <0.81
04121103
05/05/03
05/19/03
06/02103
06/16103
07/01/03 <0.78
07/17/03
08107/03
OB/21/03
09/09103
09/25/03
10/14103 <0.59
1012B/03
Chronic Toxicity 01/28/03
04/09/03
09/09/03
Dioxin (2,3,7,8-TCDD) 01/15/03 <0.22
04/11/03
07/01/03
10/14/03
Notes. All results era rn micrograms par hter ~,~L) excep1 d1o)()n. DKl)()n data Is in p1cograms per Iller (pgll)
SV-101 -Before Carbon Units
"SV-304 -Between Carbon Units
"'SV-305 -Aller Carbon Units
H. \Projects\03824\Repons\Monthlyl 1 0M-03
Sample
Location
SV-304•
<1,0
<0.96
<0.97
<0.95
<0.20
<0.19
<0.19
<0.19
<0.20
<0.19
<0.19
<0.19
Sample
Location
SV-305**
<1.0
<:1.0
<1.0
<1.0
<1.0
<1.0
<1.1
<1.0
<1.0
<0.98
<0.98
<0.98
<0.99
<0.97
<1.0
<1,0
<0.99
<0.97
<1.0
<0.98
<0.21
<0.20
<0.20
<0.20
<0.20
<0.20
<0.21
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.19
<0.20
<0.20
<0.20
<0.19
<0.20
<0.20
<0.21
<0.20
<0.20
<0.20
<0.20
<0.20
<0.21
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.19
<0.20
<0.20
<0.20
<0.19
<0.20
<0.20
Pass
Pass
Pass
<0.28
<0.27
<1.90
<1.10
• ~eaders in Environmental Testing· ''
ANALYTICAL REPORT
Raleigh, Biweekly NPDES
Lot#, C3J150169
Rita Bauer
The RETEC Group Inc
SEVERN TRENT LABORATORIES, INC.
.S.EVERN
STL Pittsburgh
450 Wil!iam Pitt Way
Pittsburgh, PA 15238
STL
Tel, 412 820 8380 Fax, 412 820 2080
www.stl-inc.com
~
Veronica Bortot
Project Manager
October 29, 2003
Severn Trent Laboratories, Jnc.
STL
NELAC REPORTING:
The fol'IIlat and content of the attached report meets NELAC standardS and guidcHnes _exCept as noted ill the narrative .. The ta"qle below
pre:Sents a summary of the certifications held by STL Pittsburgh. Our primary accreditation authority for the Non-potable water and S0lid
& Hazardous waste programs is NeW York State DOH. A more detailed parameter 1.iSt is available upon request. Plca5e ask your Project
manager for this information when required.
The codes utilized for progr8m types are described below:
HW Hazardous Waste certifica.tion
WW Non-potabl.e Water and/or Wastewater certification . .
X Laboratoty has some form of certification under the specific program. Many states certify laboratories for specific parameters or
tests within a category. The information in the table Indicates the lab ls certified In a general category of testing. Please contact
the laboratory if parameter specific certificatiori Information is required.
•
•
•
•
•
Sample Receiving:
CASE NARRATIVE
THE RETEC GROUP
Raleigh; Biweekly NPDES
STL Lot# CJ.Tl 50169
STL Pittsburgh, PA received samples on October 14, 2003 in good condition. The cooler
was received within the proper temperature range.
If project specific QC was not required for samples contained in this report and batch QC
was completed on these samples, anomalous results will be discussed below.
GC/MS Semivolatiles SIM:
The reporting limits were adjusted according to the amount of sample extracted.
Due to the concentration ofpentachlorophenol detected, SV-101 was analyzed at a
dilution.
Since insufficient sample volume was received to perfotm a mattix spike and matrix
spike duplicate, a Laboratory Control Sample (LCS) and Laboratory Control Duplicate
(LCD) were performed. All recoveries were within QC limits.
Dioxins:
The STL Sacramento, CA laboratory analyzed the dioxins.
The sample was received at 0°C .
MEffiODSSUMMARY
C3J150169
PARAMETER
Dibenzodioxins and Dibenzofurans, HRGC/HRMS
8270C (SIM)
References:
ANALYTICAL PREPARATION
METHOD 0M~E~T~H~O~D~----
SW846 8290 SW846 8290
SW846 8270C SIM SW846 3520C
SWB46 "Test Methods for Evaluating Solid Waste, Physical/Chemical
Methods 11 , Third Edition, November 1986 and its updates.
•
•
•
•
•
•
WO # SAMPLE# CLIENT SAMPLE ID
F2KG4
F2KG6
F2KGB
NOTE(S):
001
002
003
SV-305
SV-304
SV-101
SAMPLE SUMMARY
C3J150l.69
-The analytical results of the samples listed above arc presented on the following pages.
-All calculations arc performed before rounding to avoid round-off errors in calculated results.
-Results noted as "ND" were not detected a\ or above the rutted limit.
• This report ltlust not be reproduced, except in full, without the wrincn approval of the laboratory .
• Results for the following parameters arc never rcponcd on a dry weight basis: color, corrosivity, density, flaW.point, igriitability, layers, odor,
paint filter test, pH, porosity pressure, reactivity, red.ox potential, specific gravity, spot tests, solids, sclubi!ity, temperature, viscosity, and weigh!.
SAMPLED SAMP
DATE TIME
10/14/03 14, 45
10/14/03 15,00
10/14/03 15, 20
ANALYSIS REQUEST AND CHAIN OF CUSTODY RECORD
SEVERN
TRENT
PROJECT REFERENCE PROJECT NO. PROJECT LOCATION
C\<'.A-Z-7--0-:} (;,).4-0 q" (STATE) N
s v-/o/
REUNQUISHEO BY: (SIGNATURE) DATE TIME
·-· ~>r~ :.·,;;t .:::; z.--,
RECH/ED SY: !SIGNATIJRE) DATE TIME
::_.~:,::t~•·: : _-! '.c,f(;:M:tr~:-3
MATRIX
TYPE
a
Serial Number -14 51 7
Phone:
Fax:
REQUIRED ANALYSIS PAGE OF
NUMBER OF CONTAINERS SUBMITTED REMARKS
DATE TIME RELINQUISHED BY: ISIGNATlJREl DATE TIME
[O 1..\01 /boil
DAE TIME RECEIVED BY: (SIGNAnJRE) DATE TIME
Lat-Sample# ... , C3Jl50169-001
Date sampled ... , 10/14/03
Prep Date ...... , 10/21/03
Prep Batch# ... , 3294337
Dilution Factor: 1.01
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-d5
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-TribromophenOl •
•
THE RETEC GROUP INC
ciient Sample ID, SV-305
GC/MS Semivolatiles
Work Order# ... , F2KG41AA
Date Received .. , 10/15/03
Arialysis Date .. , 10/23/03
Analysis Time .. : 12:12
Matrix ......... : WATER
MS Run# ....... ,
Method ......... , SW846 8270C SIM
REPORTING
RESULT LIMIT UNITS
ND 0.20 ug/L
ND 1.0 ug/L
ND 0.20 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
51 (30 -121)
59 (11 -119)
45 (39 115)
40 (37 -115)
45 (41 -115)
57 (40 115)
TIIB RETEC GROUP INC
Client Sample ID: SV-305
Trace Level Organic Compounds
Lot-Sample# ... , C3Jl50169-001
Date Sampled ... , 10/14/03
Prep Date ...... : 10/21/03
Prep Batch# ... : 3294639
Dilution Factor: 1
PARAMETER
2,3 1 7 1 8-TCDD
INTERNAL STANDARDS
13C-2,3,7,8-TCDD
Work Order # •.• : F2KG41AC
Date Received .. : 10/15/03
Analysis Date .. : 10/23/03
Analysis Time .. : 10:59
DETECTION
RESULT LIMIT
ND 1.1
PERCENT RECOVERY
RECOVERY LIMITS
87 (40 -135)
•
Matrix ......... : WATER
MS Run# ....... :
UNITS METHOD
pg/L SW846 8290
•
•
•
Lat-Sample# ... : C3Jl50169-002
Date Sampled ... : 10/14/03
Prep Date ...... : 10/21/03
Prep Batch# ... : 3294337
Dilution Factor: 0.95
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol •
•
THE RETEC GROUP INC
Client Sample ID: SV-304
GC/MS SemivolatileS
Work Order# ... : F2KG61AA
Date Received .. : 10/15/03
Analysis Date .. : 10/23/03
Analysis Time .. : 12:39
Matrix ......... : WATER
MS Run# ....... ,
Method ......... : SW846 8270C SIM
REPORTING
RESULT LIMIT UNITS
ND 0.19 ug'/L
ND 0.95 ug/L
ND 0.19 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
43 (30 121)
55 (11 119)
39 (39 115)
37 (37 -115)
41 (41 115)
53 (40 115)
Lot-Sample # ••• : C3J150169-003
Date Sampled ... : 10/14/03
Prep Date ...... : 10/21/03
Prep Batch# ... : 3294337
Dilution Factor: 2.94
PARAMETER
2,4-Dichlorciphenol
Pentachloropbenol
Phenol
SURROGATE
Nitrobenzene-dS
Terphenyl-d14
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromopheriol
THE RETEC GROUP INC
Client Sample ID: SV-101
GC/MS Sernivolatiles
Work Order# ... : F2KG81AA
Date Received .. : 10/15/03
Analysis Date .. : 10/23/03
Analysis Time .. : 13:06
Matrix ......... : WATER
MS Run# ....... :
Method ......... : SW846 8270C SIM
REPORTING
RESULT LIMIT UNITS
ND 0.59 ug/L
22 · 2.9 ug/L
ND 0.59 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
45 (30 121)
57 (11 -119)
46 ( 39 -115)
40 (37 -115)
41 (41 -115)
59 (40 -115)
•
•
•
•
•
Client Lot# ... , C3J150169
MB Lot-Sample#, C3J210000·337
l\nalysis Date .. , 10/23/03
Dilution Factor: l
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorobiphenyl
2.:.Fluorophenol
Phenol-dS
2,4,6-Tribromophenol
NOTE (S),
METHOD BLANK REPORT
GC/MS Semivolatiles
Work Order# ... , F22881AA
Prep Date ...... , 10/21/03
Prep Batch# ... , 3294337
REPORTING
RESULT LIMIT
ND 0.20
ND 1. 0
ND 0.20
PERCENT RECOVERY
RECOVERY LIMITS
66 (30 . 121)
71 (11 . 119)
59 (39 . 115)
60 (37 · 115)
62 (41 . 115)
73 (40 . 115)
Calculations are performed before rounding to avoid round-off errors in calculated results .
Matrix ......... : WATER
Analysis Time .. : 10:49
UNITS METHOD
ug/L SW846 8270C SIM
ug/L SW846 8270C SIM
ug/L SW846 8270C SIM
Client Lot# ... , C3Jl50169
MB Lot-Sample#, G3J210000·639
Analysis Date .. , 10/23/03
Dilution Factor: l
PARAMETER
2,3,7,B-TCDD
INTERNAL STANDARDS
13C-2,3,7,8-TCDD
NOTE(S),
METHOD BLANK REPORT
Trace Level Organic Compounds
Work Order# ... , F24M71AA
Prep Date ...... , 10/21/03
Prep Batch# ... , 3294639
DETECTION
RESULT LIMIT UNITS
ND 1.1 pg/L
PERCENT RECOVERY
RECOVERY LIMITS
88 (40 -135)
Calculations are performed before rounding to avoid round-off errors in calculated results.
•
Matrix ......... : WATER
Analysis Time .. : 10: 17
METHOD
SW846 8290
•
•
•
•
LABORATORY CONTROL SAMPLE EVALUATION REPORT
GC/MS Semivolatiles
Client Lot tt ... , C3Jl50169 Work Order# ... , F22881AC-LCS
F22881AD-LCSD
Analysis Date .. , 10/23/03
Analysis Time .. : 11:16
Matrix ......... : WATER
I.CS Lot-Sample#, C3J210000-337
Prep Date ...... , 10/21/03
Prep Batch# ... , 3294337
Dilution Factor: 1
PERCENT RECOVERY RPD
PARAMETER RECOVERY LIMITS RPD LIMITS METHOD
Phenol 65 (10 131) S_W846 B27DC SIM
64 (10 131) a.so (0-43) SWB46 B270C SIM
Pentachlorophenol 122 (10 140) SW846 B270C SIM
127 (10 140) 4.5 ( 0-56) SW846 8270C SIM
2,4-Dichlorophenol 89 (42 -115) SW846 827DC SIM
90 (42 115) 0.43 ( 0-44) SWB46 827DC SIM
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Nitrobenzene-ds 68 (30 121)
66 130 -121)
Terphenyl-dl4 66 Ill -119)
65 Ill -119)
2-Fluorobiphenyl 63 139 115)
66 139 -115)
2-Fluorophenol 65 (3 7 -115)
60 (37 -115)
Phenol-dS 58 141 -115)
61 (41 -1i5)
2,4,6-Tribromophenol 86 (40 -115)
8B 140 -115)
NOTE (S) ,
Calculations ue pcrfonned before rounding 10 avoid l"Ound-off errors in calculated results .
LJ\BORATORY CONTROL SAMPLE EVALUATION REPORT
Trace Level Organic Comp~unds
Client Lot# ... , C3Jl50169
LCS Lot-Sample#, G3J2l0000-639
Prep Date ...... , 10/21/03
Prep Batch# ... , 3294639
D'ilution Factor: 1
PARAMETER
2,3,7,8-TCDD
INTERNAL STANDARD
13C-2,3,7,8-TCDD
NOTE (S) ,
work Order# ... : F24M71AC
Analysis Date .. , 10/23/03
Analysis Time .. : 09:36
PERCENT RECOVERY
RECOVERY LIMITS
103 (70 -130)
PERCENT
RECOVERY
79
Calculationi; are performed before rounding to avoid round-off errors in calculated results.
Bold print denotes control parameters
Matrix ......... , WATER
METHOD
SWB46 8290
RECOVERY
LIMITS
(40 -135)
•
•
•
•
• '( Leaders in Environmental Testing
ANALYTICAL REPORT
Raleigh, Biweekly NPDES
Lot#, C3J290l80
Rita Bauer
The RETEC Group Inc
SEVERN TRENT LABORATORIES, INC.
Veron..ica Bort:ot
Project Manager
November 4, 2003
STL Pittsburgh
450 William Pitt Way
Pittsburgh, PA 15238
STL
Tel, 412 820 8380 Fax, 412 820 2080
www.stl-inc.com
Severn Trent Laboratories, tnc.
Sample Receiving:
CASE NARRATIVE
THE RETEC GROUP
Raleigh, Biweekly NPDES
STL Lot# C3J290180
STL Pittsburgh, PA received samples on October 29, 2003 in good condition. The cooler
was received within the proper temperature range.
If project specific QC was not required for samples contained in this report and batch QC
was completed on these samples, anomalous results will be discussed below.
GC/MS Scmivolatilcs SIM:
The reporting limits were adjusted according to the amount of sample extracted.
Since insufficient sample volume was received to perfonn a matrix spike and matrix
spike duplicate, a Laboratory Control Sample (LCS) and Laboratory Control Duplicate
(LCD) were performed. All recoveries were within QC limits.
•
•
•
RELINQUISHED BY: {SIGNATURE)
:7il~!·'!'t': GtJ,;L'.\/fiE!~S
RECEIVED BY: (SIGNATURE)
ANALYSIS REQUEST AND CHAIN OF CUSTODY RECORD
STL p.-t+s.
PROJECT NO.
'i-A?. 7--o ;Jo ,f-c
DATE TIME
DATE TIME
RELINQ
REC
MATRIX
TYPE
Serial Number . 14 515
0 iri.Savannah
5102 LaRoche
Savannah, GA 3
REQUIRED ANALYSIS
Phone:
Fax:
NUMBER OF CONTAINERS SUBMITTED
I
RELINQUISHED BY: (SIGNATURE)
~~
RECEIVED BY: (SIGNATURE)
PAGE OF
L
STANDARD REPORT
DELIVERY • ~
DATEDUE 5 TY)
EXPEDrTED REPORT
DELIVERY 0
!SURCHARGE)
DATE DUE
NUMBER OF COOLERS SUBMITTED
PER SHIPMENT:
REMARKS
DATE TIME
DATE TIME
MEfflODS SUMMARY
C3J290180
ANALYTICAL PREPARATION
PARAMETER METHOD ~M~E~T~H~O~D~----
8270C (SIM) SW846 8270C SIM SW846 3520C
References:
SW846 11 Test Methods for Evaluating Solid Waste, Physical/Chemical
Methods", Third Edition, November 1986 and its updittes.
•
•
•
SAMPLE SUMMARY
C3J2901BO
WO# SAMPLE# CLIENT SAMPLE ID
F3M3D OOl EFF/SV-305
NOTE(S),
-The analytical results of the samples listed above are prese!rued on the following pages.
• AU calculations arc performed before rowiding to avoid round-off errors in calculated results.
-Results noted as "ND" were not detected at or above the Stated limiL
-This repon must not be reproduced, except in full, without the wrincn approval of !lie \aborarnry.
-Results for the following par:11ne1ers arc never reported on a dry weight basis: color, corrosivily, density, flashpoint, ir;nitabiliiy, layers, odor,
paim filter test, pH, porosity pressure, re.activity, red.ox potential. specific gravity, spot tests, solids, solubility, temperature, viscosity, and weight.
•
•
SAMPLED
DATE
SAMP
TIME
l0/28/03 09,20
THE RETEC GROUP INC
Client Sample ID, EFF/SV-305
Lot-Sample# ... , C3J290180-001
GC/MS Semivolatiles
Work Order# ... : F3M3DlAA
Date Received .. : 10/29/03
Analysis Date .. , 11/01/03
Analysis Time .. : 07:32
Matrix ......... : WATER Date Sampled ... , 10/28/03 MS Run# ....... : Prep Date ...... , 10/31/03
Prep Batch# ... , 3304350
Dilution Factor: 0.98
Method ......... : SW846 8270C SIM
REPORTING
PARAMETER RESULT LIMIT UNITS 2,4-Dichlorophenol ND 0.20 ug/L Pentachlorophenol ND 0.98 ug/L Phenol ND 0.20 ug/L
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Nitrobenzene-dS 54 (30 -121)
Terphenyl-dl4 72 (11 -119)
2-Fluorobiphenyl 53 I 39 -115)
2-Fluorophenol 44 (37 -115)
Phenol-dS 44 (41 -115)
2,4,6-Tribromophenol 75 (40 -115)
•
•
•
•
•
Client Lot# ... : C3J290180
MB Lot-Sample#, C3J3l0000-350
Analysis Date .. , ll/04/03
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-d5
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
NOTE (S),
METHOD BLANK REPORT
GC/MS Semivolatiles
Work Order# ... : F3V271AA
Prep Date ...... , 10/31/03
Prep Batch# ... , 3304350
REPORTING
RESULT LIMIT
ND 0.20
ND l.0
ND 0.20
PERCENT RECOVERY
RECOVERY LIMITS
68 (30 -121)
79 (11 -119)
65 (39 -115)
61 (37 -115)
60 (41 -115)
73 (40 -115)
Calculations are performed before rowuiiog to avoid round-off errors in calculated rcsuhs .
Matrix ... _ ..... : WATER
Analysis Time .. : 06:10
UNITS METHOD
ug/L SW846 8270C SIM
ug/L SW846 8270C SIM
ug/L SW846 8270C SIM
LABORATORY CONTROL SAMPLE EVALUATION REPORT
GC/MS Semivolatiles
Client Lot# ... : C3J290180 Work Order JI ... : F3V271AC-LCS
F3V271AD-LCSD
Analysis Date .. : 11/04/03
Analysis Time .. : 06:37
Matrix ......... ! WATER
LCS Lot-Sample#: C3J310000-350
Prep Date ...... : 10/31/03
Prep Batch# ... : 3304350
Dilution Factor: l
PARAMETER
Phenol
Pentachlorophenol
2,4-Dichlorophenol
SURROGATE
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-dS
2,4,6-Tribromophenol
NOTE(S):
PERCENT
RECOVERY
66
64
116
125
103
105
Calculations are perfonned before rounding to avoid rOUOO-off errors in calculated results.
RECOVERY
LIMITS
(10 -131)
(10 -131)
(10 -140)
(10 140)
(42 -115)
(42 -115)
PERCENT
RECOVERY
65
65
75
75
67
66
65
61
58
60
92
94
RPD
RPD LIMITS METHOD
SW846 8270C SIM
3.0 (0-43) SW846 8270C SIM
SW846 8270C SIM
7.5 (0-56) SW846 8270C SIM
SW846 8270C SIM
1.6 (0-44) SW846 8270C SIM
RECOVERY
LIMITS
(30 121)
(30 121)
(11 -119)
(11 -119)
(39 115)
(39 115)
(37 115)
(37 -115)
(41 -115)
(41 -115)
(40 -115)
(40 115)
•
•
•
•
•
•
October 7, 2003
Ms. Beverly Hudson
Remedial Project Manager
U.S. EPA -Region IV, I Ith Floor
North Site Management Branch
61 Forsyth Street, SW
Atlanta, GA 30303
RE: Monthly Progress Report #125
Remedial Action
Koppers Site -Morrisville, North Carolina
Dear Ms. Hudson:
• The RETEC Group, Inc.
3040 William Pitt Way
Pittsburgh, PA 15238-1359
In accordance with the Unilateral Order, and on behalf of Beazer East, Inc. (Beazer), please find attached
four (4) copies of the September 2003 Monthly Progress Report for Remedial Action at the Koppers
Supcrfund Site in Morrisville, North Carolina. No cxceedences occurred during this event. The
September chronic toxicity test produced a passing result; therefore, the next chronic toxicity sample will
be collected in the forth quai1er of 2003.
Should you need ·additional information regarding this progress report, please call Mike Helbling at
( 412) 208-8858 or me at (978) 3 71-1422.
Sincerely,
The RETEC Group, Inc.
~~~
Rita Bauer 1l/3
Project Geologist
Enclosure
cc: D. Mattison -NC Supcrl'und (2 copies)
L. Faulconer -Wake County
G. Caskey -En wood Structures
M. Helbling -Beazer
1-1:\Bcaz-Ralci\091\1-03.doc
D. Hails -EAP Industries, Inc.
.I. Garrett -NC Division of Water Quality
M. Matthews -NC Division of Water Quality
P. Kilchenstein -RETEC
•
•
•
• •
MONTHLY PROGRESS REPORT #125
REMEDIAL ACTION
SITE NAME: Koppers Superfund Site
Beazer East, Inc.
Morrisville, NC
USEPA DOCKET NUMBERS: 93-09-C
\
PERIOD ENDING: ' September 30, 2003
I. PROGRESS MADE THIS MONTH
2.
3.
4.
5.
6.
7.
Remedial Action (RA) -HABITAT MITIGATION. No activities were conducted this
month.
Remedial Action (RA) -GROUNDWATER TREATMENT. The treatment system
operated throughout the month without upset. System performance was monitored on a
biweekly basis. Approximately 57,160 gallons of groundwater were extracted, treated in
the treatment plant, and discharged between September I, 2003 and September 30, 2003.
System water samples were collected on September 9 and September 25, 2003 in
accordance with the sampling schedule in the O&M manual. Samples were submitted to
Severn Trent Laboratories, Inc. for laboratory analysis. The chronic toxicity sample was
collected on September 9, 2003. The operations and sampling programs are summarized
on the attached Table I.
Remedial Action (RA) -EFFECTIVENESS MONITORING PROGRAM. No activities
were conducted this month.
Remedial Action (RA) -CORRESPONDENCE. None.
PROBLEMS RESOLVED
PROBLEMS ANTICIPATED
UPCOMING EVENTS
PERSONNEL CHANGES
SUBCONTRACTORS
None.
None.
Continue System O&M.
None.
None.
ANALYTICAL DATA Analytical data from system influent and effluent
sampling received during this period are enclosed and are summarized on Table 2 .
1-1:\Bcaz-Ralci\09M-03.doc
Table 1
Groundwater Treatment Operations and Sampling Program Summary
Koppers Superfund Site
Date Systems Cumulative SV-101 SV-101
Check Effluent Flow Sample Sample
(yes/no) (Gallons) (yes/no) Parameters
01/15/03 ves 3,715,610 ves Penta, 2 4-Dichloro, Phenol, Dioxin
01/28/03 ves 3,733 790 no
2/11/03 ves 3 753,160 no
28/03 ves 3 779 540 no
03/14/03 ves 3,800,330 no
03/24/03 ves 3 818,300 no
04/09/03 no
04/11/03 ves 3,850,120 ves Penta, 2.4 Dichiaro, Phenol
04/21/03 ves 3 869 820 no
05/05/03 ves 3,894 370 no
05/19/03 ,es 3,907,850 no
06/02/03 ves 3.944,990 no
06/16/03 ,es 3,971,250 no
07/01/03 ves 3,999,940 ves Penta. 2,4-Dichloro. Phenol
./17/03 ves 4,029,840 no
8/07/03 ves 4,067 970 no
08/21/03 ves 4,094.260 no
09/09/03 ves 4,129,380 no
09/25/03 ves 4.158,630 no
Notes:
Sampling point SV-101 is located before the Carbon Units (pretreatment)
Sampling point SV-304 is located between the Carbon Units
Morrisville, North Carolina
September 2003
Associated SV-304 SV-304 Associated SV-305
Group Sample Sample Group Sample
(yes/no) Parameters (•es/no)
1,2 ves Penta, 2,4-Dichloro, Phenol 1 ves
no ves
no ves
no ves
no ves
no "es
no ves
1 ves Penta. 2,4-Dichloro. Phenol 1 "eS
no ves
no ves
no ves
no ves
no ves
1 ves Penta 2.4-Dichloro, Phenol 1 ,es
no "eS
no ves
no "OS
no ves
no ves
Associated Groups:
SV-101 -Group 1 is penta, phenol, and 2,4-dichlorophenol; Group 2 is dioxin
SV-304 -Group 1 Ls penta, phenol, and 2,4-dichlorophenol
SV-305
Sample
Parameters
Penta 2,4-Dichloro Phenol, Dioxin
Penta. 2.4-Dichloro, Phenol. Chronic Tox
Penta, 24-Dichloro Phenol
Penta. 2 4 Dichtoro, Phenol
Penta 2,4-Dichloro, Phenol
Penta 2.4-Dichloro Phenol
Chronic Tax
Penta, 2,4-Dichloro, Phenol. Dioxin
Penta, 2,4-Dichloro. Phenol
Penta, 2,4-Dichloro, Phenol
Penta, 2.4-Dichloro, Phenol
Penta. 2,4-Dichloro, Phenol
Penta. 2,4-Dichloro Phenol
Penta, 2,4-Dich!oro Phenol, Dioxin
Penta, 2.4-Dichloro. Phenol
Penta, 2 4-Dichloro, Phenol
Penta 2.4-Dichloro, Phenol
Penta, 2.4-Dichloro. Phenol. Chronic Tax
Penta, 2,4-Dichloro Phenol
Sampling point SV-305 is lactated after the Carbons Units (post-treatment) SV-305 -Group 1 Ls penta, phenol. and 2,4-dichlorophenol; Group 2 is dioxin and Group 3 is chronic toxicity
H~Prc,je<:ts.\Reports\Monlh/y\09M·03 Tatlle I.xis • •
Associated
Group
1,2
1,3
1
1
1
1
3
1,2
1
1
1
1
1
1,2
1
1
1
1,3
1
•
•
• Table 2 • Groundwater Treatment Analytical Data Summary
Koppers Superfund Site -Morrisville, North Carolina
September 2003
Analytical
Parameter Date Sample Sample
Sample Location Location
Collected SV-101 SV-304*
Pentachloroohenol 01/15/03 17 <1.0
01/28/03
02/11/03
02/28/03
03/14/03
03/24/03
04/11/03 21 <0.96
04/21/03
05/05/03
05/19/03
06/02/03
06/16/03
07/01/03 20 <0.97
07/17/03
08/07/03
08/21/03
09/09/03
09/25/03
2.4-Dichloroohenol 01/15/03 <0.19 <0.20
01/28/03
02/11/03
02/28/03
03/14/03
03/24/03
04/11/03 <0.81 <0.19
04/21103
05/05/03
05/19/03
06/02/03
06/16/03
07/01/03 <0.78 <0.19
07/17/03
08/07/03
08/21/03
09/09/03
09/25/03
Phenol 01/15/03 <0.19 <0.20
01/28/03
02/11/03
02/28/03
03/14/03
03/24/03
04/11/03 <0.81 <0.19
04/21/03
05/05/03
05/19/03
06/02/03
06/16/03
07/01/03 <:0,78 <0.19
07/17/03
08/07/03
08/21/03
09/09/03
09/25/03
Chronic Toxicitv 01/28/03
04/09/03
09/09/03
Dioxin 12,3,7,8-TCDO) 01/15/03 <0.22
04/11/03
07/01/03
Notes. All results ere m rrncrograms per liter (I-OIL) except d1oxm. D1ox1n data 1s m p1cograms per liter (pg/L)
SV-101 -Before Carbon Units
"SV-304 -Between Carbon Units
'"SV-305-Afler Carbon Units
H:\Projocts\03624\Reports\Monthly\08M-03
Sample
Location
SV-305**
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.1
<1.0
<1.0
<0.98
<0.98
<0.98
<0.99
<0.97
<1.0
<1.0
<0.99
<0.97
<0.21
<0.20
<0.20
<0.20
<0.20
<0.20
<0.21
<0.20
<0,20
<0.20
<0.20
<0.20
<0.20
<0.19
<0.20
<0.20
<0.20
<0.19
<0.21
<0.20
<0.20
<0.20
<0.20
<0.20
<0.21
<0.20
<0.20
<0.20.
<0.20
<0.20
<0.20
<0.19
<0.20
<0.20
<:0.20
<0.19
Pass
Pass
Pass
<0.28
<0.27
<1.90
•
•
• Leaders in Environmental Testing
ANALYTICAL REPORT
Raleigh, Biweekly NPDES
Lot#, C3Il00309
Rita Bauer
The RETEC Group Inc
• STL
STL Pittsburgh
450Wiltiam Pitt Way
Pittsburgh, PA 15238
Tel:[phone] Fax: [phone]
www.stl-inc.com
SEVERN TRENT LABORATORIES, INC.
September 16, 2003
• CASE NARRATIVE
THE RETEC GROUP
Raleigh, Biweekly NPDES
STL Lot # C3Il 00309
•
Sample Receiving:
STL Pittsburgh, PA received one sample on September 10, 2003 in good condition. The
cooler was received within the proper temperature range.
If project specific QC was not required for samples contained in this report and batch QC
was completed on these samples, anomalous results will be discussed below.
GC/MS Semivolatiles SIM:
The reporting limits were adjusted according to the amount of sample extracted.
Since insufficient sample volume was received to perform a matrix spike and matrix
spike duplicate, a Laboratory Control Sample (LCS) and Laboratory Control Duplicate
(LCD) were performed. All recoveries were within QC limits.
•
•
•
•
•
• •
MEIBODSSUMMARY
C3Il00309
ANALYTICAL PREPARATION
~P~ARAl=~1=E".T~E~R~-----~------------~--METHOD '-'ME=T.cHccOccDc._ ___ _
8270C (SIM) SW846 8270C SIM SWB46 3520C
References:
SW846 "Test Methods for Evaluating Solid waste, Physical/Chemical
Methods", Third Edition, November 1986 and its updates .
• •
SAMPLE SUMMARY
C3Il00309
1:l.Q_JL SAMPLE# CLIENT SAMPLE ID
FX2ES 001 EFF/SV-305
NOTE (S) ,
-Tiie analytical results of the samples listed above are presented on the following pages.
• All calculations ue performed before rounding to avoid round-off errors in calculated result~.
-Results noted as "ND" were not deiected at or above the stated limit.
-This repon must not be reproduced, except in full, without the written approval of the laboratory.
• Results for the following parameters are ne"Ver rcponed on a dry weight basis: color, corrosivity, density, flashpoint, ignitability, layers, odor,
paint filter test, pH, porosity pressure, reactivity, red ox pmential, specific gravity, spot tests, solids, solubility, temp
0
erarure, vi~sity, and weight.
SAMPLED
DATE
•
SAMP
TIME
09/09/03 09,50
•
•
• e
STL STL Pittsburgh Chain of
Custody Record Severn Trent Laboratories, Inc.
450 William Pitt Way, Bldg. 6
Pittsburgh, PA 15238
STL 4124 {0901)
GIi~
Pro/ect Manager
f) 7-\-o-~
Address YS,:k A.J-0
Telephone Number (Ai-ea Code)/FaK Number
,,...,00 q11, -s,f-I </2. "). -!
City__ d\ 1;·~ 12
~~;~ ~ Sile Contact Lab Contacr
LCJ\N:.□,
Projecr Name and Location (SI.ate)
-01"
Carrier/Waybill Number
~.J 12,(4-z, 1--034,·,i'-{ ,.-."
Contracl/Purchase Order/Ouote No. Containers & ~~
Matrix Preservatives \J ~
Sample /.0. No. and Description l ~ i 8 ~ ~~ It:;
(Containers for each sample may be combined on one line) Date Time • ~ % § ! (3 ~ ti ~ < ' ~ ~ " {f:.Cf'-/ $\/-]'<)) 9/ctl ~ \ l9f5-D f, 7 ~
Possible Hazard lden/ification I Sample Disposal
iJ.. Disposal By Lab 0 Non•Hawrd 0 Flammable 0 Skin Irritant 0 Po1sonB r/vnknown D Return To Client [j Archive For
Tum Around Tune Reqwred
0 24 Hours O 48 Hours
QC Reqwements (Specit;,)
I. Re/inqwshe~
2. Relinquished By
3. Relinquished By
Commenis
D 7 Days D 14 Days D 21 Days
Time
400
Time
Tiine
DISTRIBUTION: WHITE. Returned to Clien/ with Report: CANARY. Slays w1/h the Sample; PINK, Field Copy
Date C\ ~ D)
Chain of Custody Number · 1P421ri .. .) -· "-
LabNumfJer \ of \ Page
Analysis {Attach fist if
more s ace is needed
Special Instructions/
Conditions of Receipt
. (A fee may be assessed if samples are re!ained
MonNiS lor,ger than T month)
•
•
THE RETEC GROUP INC
Client Sample ID, EFF/SV-305
GC/MS Semivolatiles
•
Lot-Sample# ... , C3Il00309-001 Work Order# ... , FX2E51AA
Date Received .. : 09/10/03
Analysis Date .. , 09/15/03
Ana~ysis Time._: ll: 01
Matrix ......... : WATER
Date Sampled ... , 09/09/03 MS Run # .....•. :
Prep Date ...... , 09/11/03
Prep Batch# ... , 3254162
Dilution Factor: 0.99
Method ......... , SW846 8270C SIM
REPORTING
PARAMETER RESULT LIMIT illHTS
2,4-Dichlorophenol ND 0. 20 ug/L
Pentachlorophenol ND 0.99 ug/L
Phenol ND 0.20 ug/L
PERCENT RECOVERY
SURROGATE .RECOVERY LIMITS
Nitroben?-ene-dS 64 I 30 121)
Terphen;'l·dl4 76 ·111 119)
2-Fluorobiphenyl 61 I 39 115)
2-Fluorophenol 59 (3 7 115)
Phenol-d5 67 (41 115)
2,4,6-Tribromophenol 75 (40 115)
•
•
•
•
•
•
•
Client Lat# ... , C3I100309
MB Lot-Sample#, C3Ill0000-162
Analysis Date .. , 09/15/03
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-dS
Terphenyl-d14
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
NOTE (S) ,
METHOD BLANK REPORT
GC/MS Semivolatiles
Work Order# ... : FX3KH1AA
Prep Date ...... , 09/11/03
Prep Batch lt ... , 3254162
REPORTING
RESULT LIMIT
ND 0.20
ND 1.0
ND 0.20
PERCENT RECOVERY
RECOVERY LIMITS
72 (30 121)
86 (11 -119)
69 (39 '115)
63 (37 -115)
77 (41 -115)
84 (40 115)
Calculations are performed before rounding to avoid round-off errors in calculated results .
•
Matrix ......... : WATER
Analysis Time .. : o 9: 3 9
IBUTS METHOD
ug/L SW846 8270C SIM
ug/L SW846 8270C SIM
ug/L SW846 8270C SIM
• •
LABORATORY CONTROL SAMPLE EVALUATION REPORT
GC/MS Semivolatiles
Client Lot# ... : C3Il00309 Work Order# ... , FX3KHlAC-LCS
FX3KH1AD-LCSD
Analysis Date .. , D9/lS/03
Analysis Time .. : 10:06
Matrix ......... : WATER
LCS Lot-Sample#: C3Ill0000-l62
Prep Date ...... : D9/ll/03
Prep Batch# ... , 3254l62
Dilution Factor: 1
PARAMETER
Phenol
Pentachlorophenol
2,4-Dichlorophenol
SURROGATE.
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
NOTE (S),
PERCENT RECOVERY
RECOVERY LIMITS
76 (l0 -l3l)
75 (l0 -l3l)
ll2 (l0 l40)
ll8 ( 10 l40)
l0B (42 -ll5)
lll (42 ll5)
PERCENT
RECOVERY'
78
80
90
91
78
80
71
66
73
76
l08
lll
Calculations are performed before rounding to avoid round-off errors in calculated results.
RPD
RPD LIMITS METHOD
SW846 8270C SIM
1.4 (0-43) SW846 8270C SIM
SW846 8270C SIM
5.3 (D-56 I SW846 8270C SIM
SW846 8270C SIM
2.5 (0-44) SW846 8270C SIM
RECOVERY
LIMITS
(30 l2l)
(30 -l2l)
(ll -ll9)
(ll -ll9)
(39 -ll5)
(39 -ll5)
(37 -ll5)
(37 -ll5)
(41 ll5)
(4l -115)
(40 ll5)
(40 115)
•
•
•
•
•
•
• Leaders in Environmental Testing
ANALYTICAL REPORT
Raleigh, Biweekly NPDES
Lot#: C3I260148
Rita Bauer
The RETEC Group Inc
•
$TL Pittsburgh
450William Pitt Way
Pittsburgh, PA 15238
STL
Tel:[phone] Fax: [phone]
www.stl-inc.com
SEVERN TRENT LABORATORIES, INC.
Veronica Bortot
Project Manager
October 3, 2003
•
Sample Receiving:
CASE NARRATIVE
THE RETEC GROUP
Raleigh, Biweekly NPDES
STL Lot# C3I260148
•
STL Pittsburgh, PA received one sample on September 26, 2003 in good condition. The
cooler was received within the proper temperature range.
If project specific QC was not required for samples contained in this report and batch QC
was completed on these samples, anomalous results will be discussed below.
GC/MS Semivolatiles SIM:
The reporting limits were adjusted according to the amount of sample extracted.
•
•
•
•
•
• •
MEIBODSSUMMARY
C3I26Dl48
ANALYTICAL PREPARATION
PARAMETER METHOD ~M=E=T~H=O=D;_ ___ _
8270C (SIM) SW846 8270C SIM SW846 3520C
References:
SW846 11 Test Methods for Evaluating Solid waste, Physical/Chemical
·Methods 11, Third Edition, November 1986 and its updates .
• •
SAMPLE SUMMARY
C3I260l48
!'!Q_L SAMPLE# CLIENT SAMPLE ID
FOBAL 001 EFF/SV-305
NOTE(S)
-The analytical results of the sampk.s listed above are presented on the f~llowing pages.
-All ca\culatioils are performed before rounding 10 avoid round-off errors in calculated tcsulis.
-Results noted as "ND" were not detected at or above the Sl3ted limit.
-This repon must not bC reproduced, except iri full, without the written approval of the laboratory.
• Results for the folloWing parameiers are never reponcd on a dry weight basis: color, cOrrosivicy, densfty, nashpoint, ignitabilicy, layers, odor,
paint filter test, pH, pOrosity pressure, reactivity, redox potential, speCific gravity, spot tests, solids, solubility, temperature, viscosity, and weight.
SAMPLED
DATE
•
SAMP
TIME
09/25/03 09,20
•
•
• e • SEVERN
-TRENT STL STL Pittsburgh Chain of
Custody Record Sever~Trent l~boratories, Inc.
450 William Pitt Way, Bldg. 6
Pittsburgh, PA 15238
ST\..:.4124 (0901)
C/ienl f<.ntr, Ptct Manager ?, Dat91~s-1d;J Chain of Cusrodv Number
~ ~--184216
A3,oo~~A~t Telephone Number'{Area Code)/Fax Number Lab Number ( -r q'n-?71-( '{')._).,. Page of
~l,o,J IMA l2;p;i·1L{:1 · Site Contact Lab Contact Analysis (Attach list if ·
more s□ace is needed
Project Name and Location (Slate) i t/-Carrier/,Naybi/f Number 'i ✓.
'\?. f, A-z_:f, 03 6 1 -o<q (o F<..l ~ "j( $1-.:29 }-:l ~ 0 ,-,,;, '(';;. 7 l Special Instructions/ ...__
Contract/Purchase Order/Quote No. Containers & ~ Conditions of Receipt
Matrix• Preservatives g Samp/e I.D. No. and'Descrfption · I ~ Q § " "i§ Date Ti1J1e li ~ ! ~ G Q
(Containers tor each sample may be COf:!bfned on one line) • ~ ~ t~
' < ~ " "
CZFF( sv✓3cJ5 CJ/;;i~/03 (J'f )D ) y y
'
' .,
I
Possible Hazard Identification I Sample Di~posa/.
~Disposal-By Lab
(A fee may 0e assessed if samples are_ reramed
0 Non-Hazard D Rammable D Skin Irritant · D Po,son B ~Unknown D Rerurn To Client D Archive For Months longer than I-month)
Tum Around Time Re uired q , ' QC Re wrements S eci q I P ryJ
D 24 ,1../ours O 48 Hours D 7 Days O 14 Days --□ 21 Days
1. Relinqu1Shed By
2. Relinquished By
3. Refinquislied·By
Comments
DISTRIBUTION: WHITE -Returned lo Client with Report:· CANARY -Stays with the Sample: PINK--Field Copy
•
•
•
THE RETEC GROUP INC
Client Sample ro, EFF/SV-305
GC/MS Semivoltitiles
•
Lot-Sample# ... , C3I260148-001 Work Order# •.. , F0SALlAA
Date Received .. , 09/26/03
Analysis Date .. , 10/02/03
Analysis Time .. : 09:25
Matrix ......... : WATER
Date Sampled ... , 09/25/03 MS Run # .....•• , 3272193 ·
Prep Date ...... , 09/29/03
Prep Batch# ... , 3272397
Dilution Factor: 0.97
Method ......... , SW846 8270C SIM
REPORTING
PARAMETER RESULT LIMIT UNITS
2,4-Dichlorophenol ND 0.19 ug/L
Pent.achlorophenol ND 0.97 ug/L
Phenol ND 0.19 ug/L
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Nitrobenzene-dS 58 (30 -121)
Terphenyl-dl4 66 (11 119)
2-Fluorobiphenyl 55 (39 -115)
2-Flilorophenol 50 (37 -115)
Phenol-as 53 (41 115)
2,4,6-TribromOphenol 76 (40 115)
•
•
•
•
•
•
METHOD BLANK REPORT
GC/MS SemiVolatiles
Client Lot# ... , C3I260148 Work Order# ... , FlDCRlAA
MB Lot-Sample#, C3I290000-397
Analysis Date;., 10/02/03
Dilution Factor: l
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene..:.ds
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribrornophenol
NOTE (S) ,
_ Prep Date; ..... , 09/29/03
Prep Batch# ... , 3272397
REPORTING
RESULT LIMIT -
ND 0,20
ND LO
ND 0.20
PERCENT RECOVERY
RECOVERY LIMITS
65 (30 -121)
76 (11 -119)
62 (39 -115)
60 (37 -115)
64 (41 115)
79 (40 115)
Calculations are performed before rounding to avi>id rciu~d-off errors in c.alculated resullS .
•
Matrix ......... : WATER
Analysis Time .. : 06:39
UNITS METHOD
ug/L SW846 8270C SIM
ug/L SW846 8270C SIM
ug/L SW846 8270C SIM
• •
LABORATORY CONTROL SAMPLE EVALUATION REPORT
Client Lot# ... : C3I260148
LCS Lot-Sample#: C3I290000-397
Prep Date ...... : 09/29/03
Prep Batch# ... : 3272397
·Dilution Factor: l
PARAMETER
2,4-Dichlorophenol
Phenol
Pentachlorophenol.
SURROGATE
Ni troberi.z·ene-d5
Terphenyl-d14
2-Fluorobiphenyl
2-Fluorophenol
Phenol-dS
2,4,6..:Tl:'ibromophenOl
NOTE (S) :
GC/MS Semiv6latiles
Work Order #., .. : FlDCRlAC
Analysis Date .. : 10/02/03
Analysis Times:.: 07: 06
PERCENT RECOVERY
RECOVERY LIMITS
86 (42 -ll5)
60 (10 -131)
90· (10 -140)
PERCENT
RECOVERY
59
64
56
55
57
78
Calculations are performed before n:iunding to avoid iound-off errors in calculated resulis.
Matrix ......... : WATER
METHOD
SW846 8270C SIM
SW846 8270C SIM
SW846 8270C SIM
RECOVERY
LIMITS
(30 -121)
(ll 119)
(39 -115)
(37 -115)
(41 115)
(40 115)
•
•
•
•
•
•
MATRIX SPIKE SAMPLE EVALUATION REPORT
Lot-Sample# ... , C3I260148
GC/MS SernivolatileS
Work Order # ... , F03WN1AC _
MS Lot-Sample#, C3I240303-008
Date Sampled ... , 09/24/03
Prep Date ...... , 09/29/03
Prep Batch# ... , 3272397
Dillltion Factor: 1
PARAMETER
PentaChlorophenol_
2,4-DichlOrophenol
SURROGATE
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorciphe'nol
Phenol-d5
2, 4, ·6-Tribromophenol
NOTE(S),
Date ReCeived .. : 09/24/03
Analysis Date .. , 10/02/03
MS Run# ....... , 3272193
PERCENT RECOVERY
RECOVERY LIMITS
66 (10 140)
73 (42 -115)
PERCENT
RECOVERY
51
49
51
49
51
65
Calculations arc performed before rciunding to avoid round-off errors in calculated results.
MatX'ix ......... : WATER
METHOD
SW846 8270C SIM
SW846 8270C SIM
RECOVERY
LIMITS
(30 121)
(11 119)
(39 ll5)
(37 -115)
(41 -ll5)
(40 -115)
• • Pace Analytical Services, Inc.
2225 Riverside Drive ace AnalyJ_icaf ® Asheville, NC 28804
www.pa~l!t!ilill, Toxicity Report AT-1 Form Chronic Pass/Fail and Acute LC5cfh~~! ~~~~~~;~;~
Date 9123103
Facilitv: Retec NPDES#NC _______ Pipe #c..._.cE_ff~--
County Wake
Laboratory Performing Test PACE Analytical Services. Inc.
Comments oso01-ooc{li1o
Signal re of Op. erator In Resp~le Charge
( "", , .. -/.r,' ( \,,.,: 'L> I (_.__ -
~! of L.:ihnffitl'W l',11oorvisor 7 J Samples Not Aerated Unless Otherwise Noted
Environmental Sciences Branch
Div. of Water Quality
Chronic Test Results I--
MAIL ORIGINAL TO: N.C. DENR Calculated t -0.065
1621 Mail Service Center
Raleigh, North Carolina 27699-1621
North Carolina Ceriodaphnia Chronic Pass/Fail Reproduction Toxicity Test
Tabular t
% Reduction
CONTROL ORGANISMS
# Youna Produced
Adult IL,ive /Olead
Effluent% 1 90
TREATMENT 2 ORGANISMS
# Youna Produced
2 3 4 5 6 7 8 9 10 11 12
1 % Mortality
31 24 28 31 20 28 29 24 28 27 27 29 Control
L L L L D L L L L L L L 8.30
1 2 3 4 5
28 31 27 25 31
Treatment 2
0.0
r:rmtml r:v
6 7 8 9 10 11 12 1 11.7 1
28 32 22 26 27 23 27 ¾control organisms
producing 3rd brood
2.508
0
Avg. Reprod
Control
27.20
Treatment 2
27.30
PASS FAIL
xi
• c.A.::d:.=u:.:.lt -"(L:cli:.:.ve::....,_:(D:.,).:::ea:::d:____J L L L L L L L L L L L L 1 100.0 Check One
Test Start Date: r
1st 1st 2nd I complete This For Either Test 9110\03
pH Collection Start Date Control ~
Treatment 7.8 7.8 · ~ ~ Sample 1 918103 Sample 2 9111103
s E
t " a d
' t
1st
0.0 Control ~
Treatment 7.8 7.7
LC50fAcute Toxicity Test
fMortalltv exoressed as% comblnina reolicatesl
LC50= ___ %
95% Confidence
%-% • Organism Tested: Cerioda hnia dubia
s E s E
t " t " a d a d
' ' t t
1st 2nd
~ ~
Method of Determination
Moving Avg.
S earman
Probit
Other
Test Duration Hours :
Samoel Tvoe/Duration
Grab C~ Duration
Sample 1 ffiEj . 24hr
Sample 2 . X 24hr
Hardness (mg/I)
Soec. Cond. /umhosl 147 924 886
Chlorine (mQ/11 00 0.00 0.00
Samele temo. at recelot /Cl m 1.1 2.0
Note: Please
Complete Thls
Section also
start/end start/end
EE Control ffi
High
Cone
p ..
REPORT OF LABORATORY ANALYSIS
Asheville Certi/ication IDs
NC Wastewater 40
NC Drinking Water 37712
SC Environmental 99030
FL NELAP E87648
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
tn~i~?t
Charlotte Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
FL NELAP E87627
•
•
•
• AQUATIC TOXICOLOGY LABORATORY
CHAIN-OF-CUSTODY AND FIELD ANALYSIS FORM
Environmental Testing Solutions, LLC
351 Depot street
Ashevile, N~ 28801
Phone: [phone]
Fax: [phone]
Cit.ENT I FACILITY NAME: -/ {J V:, PURCHASE ORDER#: 1:..-E.C..-13, .. C,'t,L< " ,-., \...
COUNTY: ! h..J • ...,...,.:..\!. STATE: ~'-
NPDES PERMIT#: A~V\,,<\,~ i .. lU./ OUTFALL I PIPE#: ~;=.,= INFORMATION ON THIS FORM IS REQUIRED
BY ST ATE AND FEDERAL AGENCIES.
TEST REQUIREMENTS (Please check the appropriate test type and species required.)
TeS(i:cute. circle \he.appropria. le lest duration: 24. 48 96 hours
Chronic, 7-days
Pass/ Fail, dikrtionreq.lired: ___________ _
Full Range Definitive, dilutions reqlired:
Other, specify: _________________ _
SAMPLE TYPE
Co mpos,te sample
Start date: °\\'>10\
End date: "\ \"I-\ o.._,
Samples per hour: \
Chilled during collection?:
If chilled, specify temperature:
Grab sample
(oate:
REMARKS
lstarttime: o '{ o<:,
!End time: ti"\V:l
J
,:, "-J,.-~-
jTime:
SAMPLE CUSTODY
Sample collected by: lfu;_,.-~ 1~:,\ I lk't\fl
PRINT SJGNAIWE
Relinquished by:
I
PRINT SlGNA.11.RE
Relinquished to ETS by:
DAlEAICITU,E
MTE.Al-OTII-JE
Species
Ceriodaphnia dubia (Water flea)
Pimepha/es prome/as (Fathead minnow)
Daphnia pu/ex
Cy{Xinodon variegatus (Sheepshead minnow)
Menidia beryl!ina (Inland silverside)
Mysidopsis bahia {Mysid shrimp)
Other, spedry: _________________ _
San·1·t 1pJ em onnation
Sample location: (after chlortna.~. {~al, at weir. effuent outral, etc.) (£:F-F O .
Approximate volume collected for testing: ..., V
Mumber of containers filled for testing: ~
rota! residual chlorine (mgll):
Temperature at time of collection rq:
Method of transport to ETS:
Nate: Rinse containers with the sample before filling. Pack sample in loose Ice.
Samples must be received at ETS at or below4"C. Sample should not be frozen.
FOR OFFICE USE ONLY
CLIENT ID#:
Received by:
n',,_~
"'""'
.__I -==-_____._I ~~__.__~,,........,I
PRINT SIGN,11,TtRE DATE IWfJ TMC
Received at ETS by:
I "'""' OATEHOTII,£
sample temperature upon receipt at ETS (° CJ: I I
lb:,,5 -luM1,1u,1~ q/10/t/6_/ ___ /~C --r··--o----z, . o'ioa
•
•
•
AQUATIC TOXICOLOGY LABORATORY
CHAIN-OF-CUSTODY AND FIELD ANALYSIS FORM
Environmental Testing Solutions, LLC
351 Depot Street
Asheville, NC 28801
Phone: [phone]
Fax: [phone]
PURCHASE ORDER#:
STATE:
OUTFALL/ PIPE#: INFORMATION ON THIS FORM IS REQUIRED
BY ST ATE AND FEDERAL AGENCIES.
TEST REQUIREMENTS (Please check the appropriate test type and species required.)
24. 48 96 hours
Chronic, 7-days
Tesi:cute, cirde lhe appropriate test duration:
Pass/ Fail, diution required: ___________ _
Full Range Definitive, dilutions required:
Other, specify: _________________ _
SAMPLE TYPE
Co moosite sample
Start date:
End date:
aI,,103
<rl,:,./oJ
Samples per hour:
Chilled during collection?:
If chilled, speciry temperature:
Grab sample
joate:
REMARKS
SAMPLE CUSTODY
I Start time: O'l3o
I End time: 0'1'JO
I
i
"'-0-'f 'C
!Time: C
Salp/A:::•:~1•// I fL µ.Jj
PRINT SIONA.~
Relinquished by:
I
PRINT SIGNATU<E
Relinquished to ETS by:
I I ''"'" ~--
DATEHOTM:
DATEl'J'VTWE
Species
Ceriodaphnia dubia (Water flea)
Pimephales prome/as (Fathead minnow)
Daphnia pulex
Cyprinodon variegatus (Sheepshead minnow)
Menidia beryllina (Inland silverside)
Mysidopsis bahia {Mysid shrimp)
Other, specify: _________________ _
Sample infonnation
Sample location: . (~ ffrina~n~~ at weir, effluent outfaD, etc.)
Approximate volume collected for testing: -:..,_ p
Number of containers filled for testing: .,
Total residual chlorine {mg/l):
Temperature at time of collection ('C):
Method of transport to ETS:
Note: Rinse containers with the sample before filling. Pack sample in loose Ice.
Samples must be received at ETS at or be/ow4•c. Sample should not be frozen.
FOR OFFICE USE ONLY
CLIENT ID#:
-/').·o3
"'"'" Received at ETS b
e
l'Rffi
2:,"
•
0044 fo
10:5_:5
I.I ·c
•
0
•
September 9, 2003
Ms. Beverly Hudson
Remedial Project Manager
U.S. EPA -Region IV, I Ith Floor
North Site Management Branch
61 Forsyth Street, SW
Atlanta, GA 30303
RE: Monthly Progress Report #124
Remedial Action
The RETEC Group, Inc.
3040 William Pitt Way
• Pittsburgh, PA 15238-1359
Mi'.;.
r;· ' :\:~iJ>-· ~TRETE(
'\ \.) ' ?..ll'i::i~ \ \.:'.'J \
\\\~-'.'-\:, St.'i' \ \i ,. \ \ [phone] Phone
\ ...... --\, \ \ [phone] Fax , .------= 'I \ \ \J 1
' .• www.retec.com I .. ....--\C'\ (' C C, , _ ...
L--• r U \\ v _J L:-_ .• ----
\ s~?t..\\ .... ---·
Koppers Site --Morrisville, North Carolina
Dear Ms. Hudson:
In accordance with the Unilateral Order, and on behalf of Beazer East, Inc. (Beazer), please find attached
four (4) copies of the August 2003 Monthly Progress Report for Remedial Action at the Koppers
Superfund Site in Morrisville, North Carolina. No cxceedcnces occurred during this event.
Should you need additional information regarding this progress report, please call Mike Helbling at
[phone] or me at (978) 371--1422.
Sincerely,
The RETEC Group, Inc.
,4r~~~
Rita Bauer
Project Geologist
Enclosure
cc: D. Mattison --NC Superfund (2 copies)
L. Faulconer --Wake County
G. Caskey --Enwood Structures
M. Helbling --Beazer
1-1:\Bcaz-Ralci\0SM-03.doc
D. Hails -EAP Industries, Inc.
J. Garrett-NC Division of Water Quality
M. Matthews --NC Division of Water Quality
P. Kilchenstein -RETEC
•
MONTHLY PROGRESS REPORT #124
REMEDIAL ACTION
SITE NAME: Koppers Superfund Site
Beazer East, Inc.
Morrisville, NC
USEPA DOCKET NUMBERS: 93-09-C
PERIOD ENDING: August 31, 2003
1. PROGRESS MADE THIS MONTH
2.
3.
4.
5.
6.
Remedial Action (RA) -HABITAT MITIGATION. No activities were conducted this
month.
Remedial Action (RA) -GROUNDWATER TREATMENT. The treatment system
operated throughout the month without upset. System performance was monitored on a
biweekly basis. Approximately 49,550 gallons of groundwater were extracted, treated in
the treatment plant, and discharged between August 1, 2003 and August 31, 2003.
System water samples were collected on August 7 and August 21, 2003 in accordance
with the sampling schedule in the O&M manual. Samples were submitted to Severn
Trent Laboratories, Inc. for laboratory analysis. The operations and sampling programs
are summarized on the attached Table I.
Remedial Action (RA) -EFFECTIVENESS MONITORING PROGRAM. No activities
were conducted this month.
Remedial Action (RA) -CORRESPONDENCE. None.
PROBLEMS RESOLVED
PROBLEMS ANTICIPATED
UPCOMING EVENTS
PERSONNEL CHANGES
SUBCONTRACTORS
None.
None.
Continue System O&M.
None.
None.
7. ANALYTICAL DATA Analytical data from system influent and effluent
sampling received during this period are enclosed and are summarized on Table 2 .
H:\Bcaz-Ralei\0SM-03.doc
Table 1
Groundwater Treatment Operations and Sampling Program Summary
Koppers Superfund Site
Date Systems Cumulative SV-101 SV-101
Check Effluent Flow Sample Sample
{yes/no} (Gallons) (yes/no) Parameters
01/15/03 ves 3,715,610 ves Penta, 2 4-Dichloro. Phenol, Dioxin
01/28/03 yes 3 733 790 no
02/11/03 ves 3 753,160 no
02/28/03 yes 3.779 540 no
03/14/03 ves 3 800 330 no
03/24/03 yes 3 818 300 no
04/09/03 no
04/11/03 ves 3 850 120 ves Penta, 2.4-Dichloro Phenol
04/21/03 yes 3 869 820 no
05/05/03 ves 3,894 370 no
05/19/03 yes 3,907 850 no
06/02/03 ves 3,944,990 no
06/16/03 yes 3,971.250 no
07/01/03 ves 3 999 940 yes Penta 2,4-Dichloro Phenol
07/17/03 ves 4,029 840 no
08/07/03 Yes 4,067.970 no
06/21/03 ves 4,094,260 no
Notes:
Sampling point SV-101 is located before the Carbon Units (pretreatment)
Sampling point SV-304 is located between the Carbon Units
Morrisville, North Carolina
August 2003
Associated SV-304 SV-304 Associated SV-305
Group Sample Sample Group Sample
(yes/no) Parameters {yes/no)
1 2 yes Penta 2.4-Dichloro. Phenol 1 yes
no ves
no yes
no ves
no Yes
no ves
no yes
1 Yes Penta, 2 4-Dichtoro, Phenol 1 ves
no ves
no ves
no ves
no ves
no ves
1 yes Penta, 2 4-Dichloro, Phenol 1 ves
no ves
no YBS
no ves
AssoClated Groups:
SV-101 -Group 1 is penta, phenol, and 2,4-dichlorophenol; Group 2 is dioxin
SV-304 -Group 1 is penta, phenol, and 2,4-dichlorophenol
SV-305
Sample
Parameters
Penta 2.4-Dich!oro, Phenol, Dioxin
Penta. 2 4-Dichloro Phenol. Chronic T ox
Penta 2 4-Dichloro Phenol
Penta 2 4-Dichloro Phenol
Penta 2 4-Dichloro, Phenol
Penta 2 4-Dichloro Phenol
Chronic Tex
Penta 2 4-Dichloro, Phenol, Dioxin
Penta 2,4-Dichloro Phenol
Penta, 2,4-Dichloro Phenol
Penta 2.4-Dichloro, Phenol
Penta 2 4-Dichloro Phenol
Penta 2,4-Dichloro Phenol
Penta 2.4-Dlchloro, Phenol, Dioxin
Penta 2.4-Dichloro Phenol
Penta 2,4-Dichloro Phenol
Penta, 2,4-Dichloro, Phenol
Sampling point SV-305 is lactated after the Carbons Units (post-treatment) SV-305 -Group 1 is penta, phenol, and 2,4-dichlorophenol; Group 2 is dioxin and Group 3 ls chronic toxicity
HV'rojeds\O:l,624\Rcpofts\Monlhly\OeM-Ol Table 1.•ls • • •
Associated
Group
1 2
1,3
1
1
1
1
3
1,2
1
1
1
1
1
1,2
1
1
1
•
•
Table 2
Groundwater Treatment Analytical Data Summary
Koppers Superfund Site -Morrisville, North Carolina
August 2003
Analytical
Parameter Date Sample
Sample Location
Collected SV-101
Pentachloroohenol 01115103 17
01128103
02111103
02128103
03114103
03124103
04111103 21
04121103
05105103
05119103
06102103
06/16103
07101103 20
07117103
08107103
08121103
2.4-Dichloroohenol 01115103 <0.19
01128103
02111103
02128103
03114103
03124103
04111103 <0.81
04121103
05105103
05119103
06102103
06116103
07101103 <0.78
07117103
08107103
08121103
Phenol 01115103 <0.19
01128103
02111103
02128103
03114/03
03124/03
04111103 <0.81
04121103
05105103
05119103
06102/03
06/16/03
07/01103 <0.78
07/17/03
08/07/03
08/21103
Chronic Toxlcitv 01128/03
04/09/03
Dioxin 12,3,7,8-TCDD) 01/15/03 <0.22
04/11 /03
07/01103
Notes. All results are m micrograms per liter ( µg/l) except dioxin. Dioxin data ,s m p1cograms per liter (pg/l),
SV-101 -Before Carbon Units
•sV-304 -Between Carbon Units
.. SV-305 -After Carbon Units
H:\Projects\03624\Reports\Monthly\OBM-03
Sample
Location
sv.304•
<1.0
<0.96
<0.97
<0.20
<0.19
<0.19
<0.20
<0.19
<0.19
Sample
location
SV-305**
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.1
<1.0
<1.0
<0.98
<0.98
<0.98
<0.99
<0.97
<1.0
<1.0
<0.21
<0.20
<0.20
<0.20
<0.20
<0.20
<0.21
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.19
<0.20
<0.20
<0.21
<0.20
<0.20
<0.20
<0.20
<0.20
<0.21
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.19
<0.20
<0.20
Pass
Pass
<0.28
<0.27
<1.90
0
•
•
ANALYTICAL REPORT
Raleigh, Biweekly.NPDES
Lot#, C3H080224
Rita Bauer
The RETEC Group Inc
SEVERN TRENT LABORATORIES, INC.
Veronica Bortot
Project Manager
August l.9, 2003
SEVERN STL
STL Pittsburgh
450 William Pitt Way, Building 6
Pittsburgh, PA i"5238
Tel:[phone] Fax: [phone]
www.stl-inc.com
\\'I ACCo/i ~~~2~
. '.i'i11$k ~ :: · ....
u ·;;';;a
NELAC. REPORTING: ·< : .
The format and content of the attached report meets NELAC standards and guidelines except as
noted in the narrative. The table below presents a summary of the certifications held by STL
Pittsburgh. Our primary accreditation authority for the Non-potable water and Solid & Hazardous
waste programs is New York State DOH. A more detailed parameter list is available upon
request Please ask your project manager for this information when required.
Table -Certifications/Accreditation
West Virginia (#142)
The codes utilized for program types are described below:
HW Hazardous Waste certification
WW Non-potable Water and/or Wastewater certification
WW
HW
X
X
X Laboratory has some form of certification under the specific program. Many states certify
laboratories for specific parameters or tests within a category. The information in the
table indicates the lab is certified in a general category of testing. Please contact the
laboratory if parameter specific certification information is required.
0
•
•
METHODS SUMMARY
C3H080224
ANALYTICAL PREPARATION
PARAMETER METHOD ~M=E~T~H~O~Dc_ ___ _
8270C (SIM) SW846 8270C SIM SW846 3520C
References:
SW846 11 Test Methods for Evaluating Solid W~ste, PhyGical/Chemical
Methods11 , Third Edition, November 1986 and its updates .
SAMPLE SUMMARY
C3H080224
WO# SAMPLE# CLIENT SAMPLE ID
FVXM5 OOl EFF/SV-305
NOTE (S) ,
-The analytical results of tl1e samples liste.tl above arc presented on the folloWing pages.
-All calculations are performed before rounding to avoid round-off errors in calculated results.
-Results noted as "ND" were not detected at or above the stated limit.
• This report must not be reproduced, except in full, without the written approval of the laboratory.
-Results for the following parameters are never reported on a dry weight basis: color, corrosivity, density, flashpoint, ignitahility, layers, odor,
paint filler test, pH, porosity pressure, reactivity, rcdox potential, specific gravity, spot tests, solids, solubility, temperature, vi~cosity, and weight.
SAMPLED
DATE
•
SAMP
TIME ----
08/07/03 l0:20
•
•
•
SEVERN
TRENT
PROJECT REFERENCE
STL (LAB) PROJECT MANAGER
RELINQUISHED BY: iSIGNATUREJ
RECEIVED BY: (S!GNATUREJ
.... , .. '.(~
ANALYSIS REQUEST AND CHAIN OF CUSTODY RECORD
STL
P.O. NUMBER
DATE TIME
DATE TIME
PROJECT LOCATION
-o'/, (STATE) Al '
CONTRACT NO.
RECEIVED
. MATRIX
TYPE
• Serial Number -14 514
G Sfl SawaiiiFBh
518£ taRod1e A~enue
.Sa••a~nah 6° 31191
0 Alternate Laboratory Name/Location
REQUIRED ANALYSIS
Website: www.stl-inc.com
Phone: [phone]
Fax: [phone]
Phone:
Fax:
PAGE
•
NUMBER OF CONTAINERS SUBMITTED REMARKS
TIME RELIN~ BY: {SIGNATURE! DATE
t,Jt) r-,, 1£✓
TIME RECEIVED BY: (SIGNATURE) DATE
OF
TIME
TIME
THE RETEC GROUP INC
Client Sample ID, EFF/SV-305
GC/MS Semivolatiles
Lot-Sample# ... , C3H080224-001 Work Order# ... , FVXMSlAA
Date Received .. , 08/08/03
Analysis Date .. , 08/18/03
Analysis Time .. , 08:21
Matrix ......... , WATER
Date Sampled ... , 08/07/03 MS Run# ....... ,
Prep Date ...... , 08/ll/03
Prep Batch# ... , 3223294
Dilution Factor: 1.02
Method ......... , SW846 8270C SIM
REPORTING
PARAMETER RESULT LIMIT UNITS
2,4-Dichlorophenol ND 0.20 ug/L
Pentachlorophenol ND 1.0 ug/L
Phenol ND 0.20 ug/L
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Nitrobenzene-dS 70 (30 -121)
Terphenyl-d14 75 (ll -ll9)
2-Fluorobiphenyl 67 I 3 9 -llS)
2-Fluorophenol 62 (37 -llS)
Phenol-d5 74 (41 -llS)
2,4,6-Tribromophenol 74 (40 -llS)
•
•
•
Client Lot# ... , C3H080224
MB Lot-Sample#, C3Hll0000-294
Analysis Date .. , 08/18/03
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-ds
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
METHOD BLANK REPORT
GC/MS Semivolatiles
Work Order# ... , FV2VP1AA
Prep Date ...... , 08/11/03
Prep Batch# ... , 3223294
REPORTING.
RESULT LIMIT
ND 0.20
ND 1.0
ND 0.20
PERCENT RECOVERY
RECOVERY LIMITS
67 (30 -121)
70 (11 -119)
63 ( 39 -115)
61 (37 -115)
71 I 41 -115)
75 (4 0 -115)
•
OTE(S),
alculations are performed before rounding to avoid round-off errors in calculated results .
•
Matrix ......... : WATER
Analysis Time .. , 06:57
UNITS METHOD
ug/L SW846 8270C SIM
ug/L SW846 8270C SIM
ug/L SW846 8270C SIM
LABORATORY CONTROL SAMPLE EVALUATION REPORT
GC/MS Semivolatiles
Client Lot# ... : C3H080224 Work Order# ... : FV2VP1AC-LCS
FV2VP1AD-LCSD
Analysis Date .. : 08/18/03
Analysis Time .. : 08:21
Matrix ......... : WATER
LCS Lot-Sample#: C3Hll0000-294
Prep Date ...... : 08/11/03
Prep Batch# ... : 3223294
Dilution Factor: 1
PERCENT RECOVERY RPD
PARAMETER RECOVERY LIMITS RPD LIMITS METHOD
Phenol 68 (10 -131) SW846 8270C SIM
75 (10 -131) 8.8 (0-43) SW846 8270C SIM
Pentachlorophenol 54 (10 140) SW846 8270C SIM
60 (10 -140) 10 (0-56) SW846 8270C SIM
2,4-Dichlorophenol 79 (42 -115) SW846 8270C SIM
87 (42 -115) 9.0 (0-44) SW846 8270C SIM
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Nitrobenzene-dS 73 (30 -121)
79 (3 0 -121)
Terphenyl-dl4 73 (11 -119)
79 (11 -119)
2-Fluorobiphenyl 68 (39 -115)
74 (39 -115)
2-Fluorophenol 65 (37 -115)
68 (37 -115)
Phenol-dS 76 (41 -115)
82 (41 -115)
2,4,6-Tribromophenol 87 (40 -115)
95 (40 -115)
NOTE(S):
Calculations are performed before rounding to avoid round-off errors in calculated resulls.
•
•
•
•
•
ANALYTICAL REPORT
Raleigh, Biweekly NPDES
Lot#, C3H220146
Rita Bauer
The RETEC Group Inc
SEVERN TRENT LABORATORIES, INC.
}it,
Veronica Bortot
Project Manager
August 29, 2003
SEVE~N-
STL Pittsburgh
450 William Pitt Way
Pittsburgh, PA 15238
STL
Tel: [phone] Fax: [phone]
www.stl-inc.com
----------------------------------------------
Sample Receiving:
CASE NARRATIVE
THE RETEC GROUP
Raleigh, Biweekly NPDES
STL Lot# C3H220146
STL Pittsburgh, PA received one sample on August 22, 2003 in good condition. The
cooler was received within the proper temperature range.
If project specific QC was not required for samples contained in this report and batch QC
was completed on these samples, anomalous results will be discussed below.
GC/MS Semivolatiles SIM:
The reporting limits were adjusted according to the amount of sample extracted.
The laboratory control duplicate recovered outside of the control limits for 2,4-
dichlorophenol. This compound was not detected in the samples. Slight positive bias is
not believed to have impacted data quality. All data was reported.
Since insufficient sample volume was received to perform a matrix spike and matrix
spike duplicate, a Laboratory Control Sample (LCS) and Laboratory Control Duplicate
(LCD) were performed. All recoveries were within QC limits.
•
•
•
•
•
•
MEfflODSSUMMARY
C3H220146
ANALYTICAL PREPARATION
~P~ARAM==E~T~E~R,_ _____________________ METHOD ~M~E~T~H~O~Dc.__ ___ _
8270C (SIM) SW846 8270C SIM SW846 3520C
References:
SW846 "Test Methods for Evaluating Solid Waste, Physical/Chemical
Methods", Third Edition, November 1986 and its updates .
SAMPLE SUMMARY
C3H220146
WO# SAMPLE# CLIENT SAMPLE ID
FWRFF 001 EFF/SV-305
NOTE(S)
-The analytical results of lhe samples listed above are prescmcd on the following pages.
• Ail calculacions are performed before rounding to avoid round-off errors in calculated results.
• Results noted as "ND" were noc detected at or above the stated limit.
• This report must not be reproduced, except in full, without the written approval of the laboratory.
-Results for the following parameters are never reported on a dry weight basis: color, corrosivity, density, flashpoint, ignitabi!ity, layers. odor,
paint filter test, pH, porosity pressure, reactivity, rcdox potential, specific gravity, spot 1csts. solids, solubility, temperature, viscosity, and weight.
SAMPLED
DATE
•
SAMP
TIME
08/21/03 11:18
•
•
• • SEVERN·
:·.TRENT STL STL Pittsburgh • Chain of
Custody Record Severn Trent Laboratories, Inc.
450 William Pitt Way, Bldg. 6
Pittsburgh, PA 15238
STL 4124 (0901)
Client ~ Project Manager
12..rt-.... ~
Address
:i?~ .Av.e...
Telephone Number (Area Code)/Fax Number Joo '17f -]7/-/'(}.)_
c~,d I iii4 !
2;;/;</J-A-c~r\, Lab Contact
1-l Project Name and Location (State) 6Tc;JNu~~C, J~inc,6S7}8 BDf z "::J--m~2 ✓-{Y/1.. '? y
ContracVPurchase Order/Quote No. Containers & V\ Matrix Preservatives -..) "' "
Sample I.D. No. and Description-I ~ 0 8 ~ "~ R
Date Time ~ "g " V, ~ D ,o ~ (Containers tor each. sample may be combined on one line) s i 5 ',I ~ ~ ~~ ' V, V, ~
f!-t= F--/ 5 V -1. otr 'f ),2. I/ 6') l I I"• I~ IX )<
Possible Hazard Identification ~-I Sample Disposal
0 Non~Hazard D Flammable D Skin Irritant D Poison B Unknown D Return To Client ~sposal By Lab D Archive For
Turn Around Time Reqwred
0 24 HC!urs D 48 Hours
' QC Reqwements (Specify)
D 7Days D 14 Days D 21 Days
1. Relinquished ii:. Time
/Goo
2. Relinquished By Time
3. Relinquished By Time
Comments
DISTRIBUTION: WHITE -Returned to Client with Report: CANARY -Stays with th"e Sample; PINK -Field Copy
Oat~/ ~l Chain of Custody Number
OJ 1 RF;Ll7q
Lab Number l I
Page of
Analysis (Attach list if
more soace is needed
Special Instructions/
Conditions of Receipt
(A fee may be assessed if samples are retained
Months longer than 1 month)
Date Time
Dale
1, -z.40 3
Time
/OSQ
Date Time
TilE RETEC GROUP INC
Client Sample ID: EFF/SV-305 • GC/MS Semivolatiles
Lot-Sample # ... : C3H220146-001 Work Order # ... : FWRFFlAA Matrix ......... : WATER
Date Sampled ... : 08/21/03 Date Received .. : 08/22/03 MS Run # ....... :
Prep Date ...... : 08/25/03 Analysis Date .. : 08/27/03
Prep Batch # ... : 3238111 Analysis Time .. : 09: 39
Dilution Factor: 1.01
Method ......... : SW846 8270C SIM
REPORTING
PARAMETER RESULT LIMIT UNITS
2,4-Dichlorophenol ND 0.20 ug/L
Pentachlorophenol ND 1.0 ug/L
Phenol ND 0.20 ug/L
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Nitrobenzene-d5 80 (30 -121)
Terphenyl-dl4 85 (11 -119)
2-Fluorobiphenyl 81 (39 -115)
2-Fluorophenol 72 (37 -115)
Phenol-d5 83 (41 -115)
2,4,6-Tribromophenol 78 (40 -115) •
•
• METHOD BLANK REPORT
GC/MS Semivolatiles
Client Lot# ... : C3H220146 Work Order# ... : FWlANlAA
MB Lot-Sample#: C3H260000-111
Prep Date ...... : 08/25/03
Analysis Date .. : 08/27/03 Prep Batch# ... : 3238111
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-dS
Terphenyl-d14
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
RESULT
ND
ND
ND
PERCENT
RECOVERY
81
93
82
69
86
90
• >TE(S):
Calculations are performed before rounding to avoid round-off errors in calculated results .
•
REPORTING
LIMIT
0.20
1.0
0.20
RECOVERY
LIMITS
(30 -121)
(11 -119)
(39 -115)
(37 -115)
(41 -115)
(40 -115)
Matrix ......... : WATER
Analysis Time .. : 07:41
UNITS METHOD
ug/L SW846 8270C SIM
ug/L SW846 8270C SIM
ug/L SW846 8270C SIM
LABORATORY CONTROL SAMPLE EVALUATION REPORT
GC/MS Semivolatiles
Client Lot# ... : C3H220146 Work Order# ... : FWlANlAC-LCS
FWlANlAD-LCSD
Analysis Date .. : 08/27/03
Analysis Time .. : 08:14
Matrix ......... : WATER
LCS Lot-Sample#: C3H260000-111
Prep Date ...... : 08/25/03
Prep Batch# ... : 3238111
Dilution Factor: 1
PERCENT RECOVERY
PARAMETER RECOVERY LIMITS
Phenol 89 (10 -131)
94 (10 -131)
Pentachlorophenol 77 (10 -140)
Bl (10 -140)
2,4-Dichlorophenol 109 (42 -115)
118 a (42 -115)
PERCENT
SURROGATE RECOVERY
Nitrobenzene-d5 88
94
Terphenyl-dl4 95
100
2-Fluorobiphenyl 90
95
2-Fluorophenol 78
83
Phenol-d5 91
96
2,4,6-Tribromophenol 105
107
NOTE (S}:
Calculations are performed before rounding to avoid round-off errors in calculated results.
a Spiked analyte recovery is outside stated control limits.
RPD
RPD LIMITS METHOD
SW846 8270C SIM
6.1 (0-43) SW846 8270C SIM
SW846 8270C SIM
4.4 ( 0-56) SW846 8270C SIM
SW846 8270C SIM
7.3 (0-44) SW846 8270C SIM
RECOVERY
LIMITS
(30 121)
(30 -121)
(11 -119)
(11 -119)
(39 -115)
(39 -115)
(37 -115)
(37 -115)
(41 -115)
(41 -115)
(40 -115)
(40 -115)
•
•
•·
•
August 6, 2003
Ms. l3evcrly Hudson
Remedial Project Manager
U.S. EPA -Region IV, I Ith Floor
North Site Management Branch
61 Forsyth Street, SW
Atlanta, GA 30303
RE: Monthly Progress Report #123
Remedial Action
Koppers Site -Morrisville, North Carolina
Dear Ms. Hudson:
The RETEC Group, Inc.
3040 William Pitt Way
Pittsburgh, PA 15238-1359
[phone] Phone
[phone] Fax
www.retec.com
In accordance with the Unilateral Order, and on behalf of l3eazcr East, Inc. (Beazer), please find attached
four (4) copies of the July Monthly Progress Report for Remedial Action at the Koppers Superfund Site in
Morrisville, North Carolina. No exceedances occurred during this event.
Should you need additional information regarding this progress report, please call Mike Helbling at
( 412) 208-8858 or me at (978) 3 71-1422.
Sincerely,
The RETEC Group, Inc.
~.J!~➔
Rita l3auer 1'-z,
Project Geologist
Enclosure
cc: D. Mattison -NC Superfund (2 copies)
L. Faulconer -Wake County
G. Caskey -Enwood Structures
M. Helbling -Beazer
H:\Beaz-Ralei\07M-03.Joc
D. Hails -EAP Industries, Inc.
J. Garrett -NC Division of Water Quality
M. Matthews -NC Division of Water Quality
P. Kilchenstein -RETEC
•
•
MONTHLY PROGRESS REPORT #123
REMEDIAL ACTION
SITE NAME: Koppers Supcrfund Site
Beazer East, Inc.
Morrisville, NC
USEPA DOCKET NUMBERS: 93-09-C
PERIOD ENDING: July 31, 2003
I. PROGRESS MADE THIS MONTH
2.
3.
4.
5.
6.
Remedial Action (RA) -HABITAT MITIGATION. No activities were conducted this
month.
Remedial Action (RA) -GROUNDWATER TREATME"'NT. The treatment system
operated throughout the month without upset. System performance was monitored on a
biweekly basis. Approximately 64,210 gallons of groundwater were extracted, treated in
the treatment plant, and discharged between July I, 2003 and July 31, 2003. System
water samples were collected on July I and July 17, 2003 in accordance with the
sampling schedule in the O&M manual. Samples were submitted to Severn Trent
Laboratories, Inc. for laboratory analysis. The operations and sampling programs are
summarized on the attached Table I.
Remedial Action (RA) -EFFECTIVENESS MONITORING PROGRAM. No activities
were conducted this month.
Remedial Action (RA) -CORRESPONDENCE. None.
PROBLEMS RESOLVED
PROBLEMS ANTICIPATED
UPCOMING EVENTS
PERSONNEL CHANGES
SUBCONTRACTORS
None.
None.
Continue System O&M.
None.
None.
7. ANALYTICAL DATA Analytical data from system influent and effluent
sampling received during this period are enclosed and are summarized on Table 2 .
11:\Bcoz-Ralei\07M-03.doc
Table 1
Groundwater Treatment Operations and Sampling Program Summary
Koppers Superfund Site
Date Systems Cumulative SV-101 SV-101
Check Effluent Flow Sample Sample
(yes/no) (Gallons) (yes/no) Parameters
01/15/03 ves 3,715 610 ves Penta, 2.4-Dichloro, Phenol
01/28/03 ves 3,733,790 no
02/11/03 ves 3 753,160 no
02/28/03 ves 3,779,540 no
03/14/03 ves 3 800 330 no
03/24/03 ves 3,818,300 no
04/09/03 no
04/11/03 ves 3,850,120 ves Penta, 2,4-Dichloro Phenol
04/21/03 yes 3,869,820 no
05/05/03 ves 3,894,370 no
05/19/03 yes 3,907,850 no
06/02/03 ves 3 944,990 no
06/16/03 yes 3,971,250 no
07/01/03 ves 3,999 940 ves Penta 2,4-Dichloro, Phenol
07/17/03 ves 4,029,840 no
Notes:
Sampling point SV-101 is located before the Carbon Units (pretreatment)
Sampling point SV-304 is located between the Carbon Units
Dioxin
Morrisville, North Carolina
July 2003
Associated SV-304 SV-304 Associated SV-305
Group Sample Sample Group Sample
(veslno) Parameters (yes/no I
1,2 "05 Penta, 2 4-Dichloro Phenol 1 "05
no ves
no "05
no yes
no "05
no yes
no "05
1 ,es Penta. 2.4-Dichloro Phenol 1 ves
no yes
no ves
no ves
no ves
no ves
1 ves Penta 2,4-Dichloro. Phenol 1 ves
no ves
Associated Groups:
SV-101 • Group 1 is penta, phenol, and 2.4..cfichlorophenol; Group 2 is dioxin
SV-304 • Group 1 is penta, phenol, and 2,4..cfichlorophenol
SV-305
Sample
Parameters
Penta. 2 4-Dichloro, Phenol Dioxin
Penta, 2,4-Dichloro, Phenol, Chronic Tax
Penta 2 4-Dichloro, Phenol
Penta, 2,4-Dichloro, Phenol
Penta 2 4-Dichloro Phenol
Penta, 2,4-Dichloro, Phenol
Chronic Tax
Penta, 2 4-Dichloro Phenol Dioxin
Penta, 2,4-Dichloro, Phenol
Penta 2 4-Dichloro Phenol
Penta, 2,4-Dichloro, Phenol
Penta 2,4-Dichloro Phenol
Penta, 2,4-Dichloro, Phenol
Penta 2 4-Dich!oro Phenol Dioxin
Penta, 2,4-Dichloro, Phenol
Sampling point SV-305 is lactated after the Carbons Units (post-treatment) SV-305 • Group 1 is penta, phenol, and 2,4..cfichlorophenol; Group 2 is dioxin and Group 3 is chronic toxicity
H:\Projects\0362~\Re?<)ftl\Monthly\07M·03 T.tile 1.xls • •
Associated
Group
1,2
1,3
1
'
1
'
3
1,2
1
'
1
1
1
1,2
'
•
•
Table 2
Groundwater Treatment Analytical Data Summary
Koppers Superfund Site -Morrisville, North Carolina
July 2003
Analytical
Parameter Date Sample
Sample Location
Collected SV-101
Pentachlorophenol 01/15/03 17
01/28/03
02/11/03
02/28/03
03/14/03
03/24/03
04/11/03 21
04/21/03
05/05/03
05/19/03
06/02/03
06/16/03
07/01/03 20
07/17/03
2.4-Dichlorophenol 01/15/03 <0.19
01/28/03
02/11/03
02/28/03
03/14/03
03/24/03
04/11/03 <0.81
04/21/03
05/05/03
05/19/03
06/02/03
06/16/03
. 07/01/03 <0.78
07/17/03
Phenol 01/15/03 <0.19
01/28/03
02/11/03
02/28/03
03/14/03
03/24/03
04/11/03 <0.81
04/21/03
05/05/03
05/19/03
06/02/03·
06/16/03
07/01/03 <0.78
07/17/03
Chronic Toxicitv 01/28/03
04/09/03
Dioxin (2,3,7,8-TCDD) 01/15/03 <0.22
04/11/03
07/01/03
Notes: All results are m micrograms per liter (µg/l) except d1ox1n. Dioxin data 1s m p1cograms per liter (pg/l).
SV-101 • Before Carbon Units
*SV-304 -Between Carbon Units
**SV-305 -After Carbon Units
H:\Projects\03624\Reports\Monthly\0?M-03
Sample
Location
sv.304•
<1.0
<0.96
<0.97
<0.20
<0.19
<0.19
<0.20
<0.19
<0.19
Sample
Location
SV-305 ..
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.1
<1.0
<1.0
<0.98
<0.98
<0.98
<0.99
<0.97
<0.21
<0.20
<0.20
<0.20
<0.20
<0.20
<0.21
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.19
<0.21
<0.20
<0.20
<0.20
<0.20
<0.20
<0.21
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.19
Pass
Pass
<0.28
<0.27
<1.90
SEVERN
•
• A pa1. d Sevtm Trent pie
STL
ANALYTICAL REPORT
Raleigh, Biweekly NPDES
Lot#, C3G020278
Rita Bauer
The RETEC Group Inc
SEVERN TRENT LABORATORIES. me.
Veronica Bortot
Project Manager
July 17, 2003
Severn Trent Laboratories, Inc.
STL Pittsburgh • 450 William Pitt Way, Pittsburgh, PA 15238
Tel [phone] Fax [phone] • www.stHnc.com
Sample Receiving:
CASE NARRATIVE
THE RETEC GROUP
Raleigh, Biweekly NPDES
STL Lot # C3G020278
STL Pittsburgh, PA received one sample on July 2, 2003 in good condition. The cooler
was received within the proper temperature range
GC/MS Semivolatiles S™:
The reporting limits were adjusted according to the amount of sample extracted.
Due to the concentration of target compounds detected, sample SV-101 was analyzed at a
dilution.
Since insufficient sample volume was received to perform a matrix spike and matrix
spike duplicate, a Laboratory Control Sample (LCS) and Laboratory Control Duplicate
(LCD) were performed. All recoveries were within QC limits.
Dioxins:
STL West Sacramento, CA performed the dioxin analysis.
report.
There were no problems associated with the analysis.
All results are included in the
•
•
•
•
METHODS SUMMARY
C3G020278
PARAMETER
Dibenzodioxins and Dibenzofurans 1 HRGC/HRMS
8270C (SIM)
References:
ANALYTICAL
METHOD
SW846 8290
SW846 8270C SIM
PREPARATION
METHOD
SW846 8290
SW846 3520C
SW846 11 Test Methods for Evaluating Solid Waste, Physical/Chemical
Methods", Third ·Edition, November 1986 and its updates .
WO# SAMPLE# CLIENT SAMPLE ID
FRMSE
FRMSR
FRMS0
NOTE(S)
001
002
003
SV-101
SV-304
SV-305
SAMPLE SUMMARY
C3G020278
-1be analytical results of the &amples listed above are pr~ on the following pages.
• All calculations are performed before rounding to avoid round-off errors in calculated results.
• Results noted as "ND" were not detected at or above the stated limit.
-'This report must not be reproduced, except in full, without the written approval of the laboratory,
• Results for the following parameters are never reported on a dry weight basis: color, corrosivity, density, flashpoint, ignitability, layers, odor,
paint filter test, pH, porosity pressure, reactivity, redox potential, specific gravity, spot tests, solids, rolubility, temperature, viscosity, and weight.
SAMPLED
DATE
•
07/01/03 10,20
07/01/03 10,20
07/01/03 10,50
•
•
I
I
I
I
I
I
I
I
I
I
I
I
I
1.
I
I
I
I
I
I
I
I
I
• • e
SEVERN
· -TRENT' STL STL Pittsburgh Chain of
Custody Record Severn Trent Laboratories, Inc.
450 William Pitt Way, Bldg. 6
Pittsburgh, PA 15238
STL-4124 {0801)
Cflent{;) ,--ff;;-,,
• hj Project ~~:r ' "--~~,,,-Date I ?1 CIJ
Cha;n of Gusti ~4.8 9 3
Addrbss
'E'~ ,{ 1:e_.
Telephone Num_ber (Area Code)/Fax Number Lab Number L 301> lli'1X -11, _ rt./'),).. Page· i of
~ 1;~ l"'P~7;Y:t Sita Contact Lab_ Contact Analysis (Attach list if f2:-v.,,... ~,,._.,J more s ace is needed
Project Name and Loca.tion (Slate) Carrier/Waybill Number r-, ..J TI ~ "4-7.--1-O, t,;:i ..../ -e>"I I,, k,)~£ g ;i. "I]')_ 305"(o)7"l-5 ~ Special Instructions/
ContracVPurchese Order/Quote No. Containers & 0i Conditions of Receipt
Matrix "-' Preservatives V
Sample I.D. No. and DescriP.lion l 1 0 i ~ ,,~ R
(Containers for each sample may be combined an one line} Date Time 1i ~ ~ 2 0 ,o ~ ~ ~ ~ ~ ~ ~l
,",✓-Io I l"'IL l-a"3 /O;,.o 'f, 1' l'i
<v -'Jo 1 •• /07-<' X l< I)(
<.11 -,o'i' \; JoS'iJ x i. y:
Possible Hazard Identification I Sample Disposal (A fee may be assessed if samples are retained D Non-Hazard D Flammable D Skin lmtant 0 PolsonB K}r;inknown D Return To Cfient ~isposal By Lab 0 Archive For Months longer than 1 month)
Turn Around Time R uired eq / OC Re uirements S eci q I P fyJ
D 24 Hours D 48 Hours D 14 Days D 21 Days
t. Relinquished By Time
2. Relinquished By Time
Q3 ,ooo
3. Relinquished By nme
Comments
DtSTRfBUTION: WHITE· Aetumad to Client with Rep011; CANARY -Stays with the Sample; PINK· Reid Copy
Lot-Sample# ... : C3G020278-001
Date Sampled ... : 07/01/03
Prep Date ...... : 07/03/03
Prep Batch# ... : 3184333
Dilution Factor: 3.88
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-ds
Terphenyl-dl4
2-Fl uorobiphenyl
2-Fluorophenol
Phenol-dS
2,4,6-Tribromophenol
THE RETEC GROUP INC
Client Sample ID: SV-101
GC/MS Sernivolatiles
Work Order# ... : FRM8ElAA
Date Received .. : 07/02/03
Analysis Date .. : 07/09/03
Matrix ......... : WATER
MS Run# ....... :
Method ......... : SW846 8270C SIM
REPORTING
RESULT LIMIT UNITS
ND 0.78 ug/L
20 3.9 ug/L
ND 0,78 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
68 (30 -121)
66 (11 -119)
75 (39 -115)
70 (37 -115)
71 (41 115)
78 (40 -115)
•
•
•
•
•
Lot-Sample# ... : C3G020278-002
Date Sampled ... , 07/01/03'
Prep Date ...... : 07/03/03
Prep Batch# ... : 3184333
Dilution Factor: 0.97
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-dS
Terphenyl-dl4
2-Flti.orobiphenyl
2-Fluorophenol
Phenol-dS
2,4,6-Tribromophenol
THE RETEC GROUP INC
Client Sample ID: SV-304
GC/MS Semivolatiles
Work Order# ... : FRM8RlAA
Date Received .. : 07/02/03
Analysis Date .. : 07/09/03
Matrix ......... : WATER
MS Run# ....... :
Method ......... : SW846 8270C SIM
REPORTING
RESULT LIMIT UNITS
ND 0.19 ug/L
ND 0.97 ug/L
ND 0.19 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
61 (30 -121)
59 (11 -119)
65 (39 -115)
64 (37 -115)
66 (41 115)
68 (40 -115)
Lot-Sample# ... : C3G020278-003
Date Sampled ... : 07/01/03
Prep Date ...... : 07/03/03
Prep Batch# ... : 3184333
Dilution Factor: 0.99
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-dS
Terphenyl-d14
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
THE RETEC GROUP INC
Client Sample ID: SV-305
GC/MS Semivolatiles
Work Order# ... : FRM801AA
Date Received .. : 07/02/03
Analysis Date .. : 07/09/03
Matrix ......... : WATER
MS Run# ....... :
Method ......... : SW846 8270C SIM
REPORTING
RESULT LIMIT UNITS
ND 0.20 ug/L
ND 0.99 ug/L
ND 0. 20 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
65 (30 -121)
62 (11 -119)
67 (39 -115)
61 (37 -115)
67 (41 -115)
66 (40 -115)
•
•
•
•
•
•
THE RETEC GROUP INC
Client Sample ID: SV-305
Trace Level Organic Compounds
Lot-Sample j/. .. : C3G020278-003 Work Order# ... : FRMBOlAC
Date Received .. : 07/02/03
Analysis Date .. : 07/11/03
Analysis •rime .. : 07: 21
Date Sampled ... : 07/01/03
Prep Date ...... : 07/08/03
Prep Batch # ... , 3190250
Dilution Factor: 1
DETECTION
PARAMETER RESULT LIMIT
2,3,7,8-TCDD ND 1.9
PERCENT RECOVERY
INTERNAL STANDARDS RECOVERY LIMITS
13C-2,3,7,8-TCDD 85 (40 -135)
Matrix ......... , WATER
MS Run# ....... :
UNITS METHOD
pg/L SW846 8290
Client Lot# ... , C3G020278
MB Lot-Sample#, C3G030000-333
Analysis Date .. , 07/09/03
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-dS
Terphenyl-d14
2-Fluorobiphenyl
2-Fluorophenol
Phenol-dS
2,4,6-Tribromophenol
NOTE (S) ,
METHOD BLANK REPORT
GC/MS Semivolatiles
Work Order# ... , FRP8XlAA
Prep Date ...... , 07/03/03
Prep Batch# ... , 3184333
RESULT
ND
ND
ND
PERCENT
RECOVERY
62
57
68
66
68
73
REPORTING
LIMIT
0.20
1.0
0.20
RECOVERY
LIMITS
(30 -121)
(11 -119)
(39 -115)
(37 -115)
(41 -115)
(40 -115)
UNITS
ug/L
ug/L
ug/L
Calculations are performed before rounding to a"Void round-off errors in calculated results.
•
Matrix ......... , WATER
METHOD
SW846 8270C SIM
SW846 8270C SIM
SW846 8270C SIM
•
•
•
•
METHOD BLANK REPORT
Trace Level Organic Compounds
Client Lot*···' C3G020278 Work Order# ... : FRX00lAA
MB Lot-Sample#: G3G090000-250
Analysis Date .. : 07/11/03
Dilution Factor: l
PARAMETER
2,3,7,8-TCDD
INTERNAL STANDARDS
13C-2,3,7,8-TCDD
NOTE(S):
Prep Date ...... : 07/08/03
Prep Batch it. .. : 3190250
DETECTION
RESULT LIMIT
ND 1.7
PERCENT RECOVERY
RECOVERY LIMITS
91 (40 -135)
Ca\cu\a1ions are performed before rounding to avoid round-off errors in calculated results .
UNITS
pg/L
Matrix ......... : WATER
METHOD
SW846 8290
Ll\BORATORY CONTROL SAMPLE EVALUATION REPORT
GC/MS Sernivolatiles
Client Lot# ... : C3G020278 Work Order# ... : FRPBXlAC-LCS
FRPBXlAD-LCSD
Analysis Date .. : 07/09/03
Matrix ......... : WATER LCS Lot-Sarnplej(: C3G030000-333
Prep Date ...... : 07 /03/03
Prep Batch jf ... : 3184333
Dilution Factor: 1
PERCENT RECOVERY RPD PARAMETER RECOVERY LIMITS g_@__ LIMITS METHOD Phenol 54 (10 -131) SW846 8270C SIM
59 (10 131) 9.3 ( 0-43) SWB46 8270C SIM Peritachlorophenol 66 (10 -140) SW846 8270C SIM
68 (10 -140) 2.6 (0-56) SW846 8270C SIM 2,4-Dichlorophenol 65 (42 -ll.5) SW846 8270C SIM
67 (42 ll.5) 3.6 (0-44) SW846 8270C SIM
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Nitrobenzene-dS 59 (30 -121)
62 (30 -121) Terphenyl-d14 64 (11 -119)
56 (11 -119)
2-Fluorobiphenyl 66 (39 -115)
67 (39 -115)
2-Fluorophenol 59 (37 -115)
59 (37 -115)
Phenol-ds 55 (41 -115)
59 (41 -115)
2,4,6-Tribromophenol 73 (40 -115)
71 (40 -115)
NOTE (S) :
Calailations are performed before roun:ling to avoid rounck:lff errors in calculated results.
•
•
•
•
•
LABORATORY CONTROL SAMPLE EVALUATION REPORT
Trace Level Organic Compounds
Client Lot fl ... : C3G020278 Work Order# ... : FRXOOlAC
LCS Lot-Sarnplejf: G3G090000-250
Prep Date ...... : 07/08/03 Analysis Date .. : 07/11/03
Prep Batch# ... : 3190250
Dilution Factor: 1
PARAMETER
2,3,7,8-TCDD
INTERNAL STANDARD
13C-2,3,7,8-TCDD
NOTE (S) :
PERCENT
RECOVERY
l.l.8
Calc:ulation.s are performed before rounding to avoid round•off errors in ctlculated results.
Bold print denotes control parameters
RECOVERY
LIMITS
(70 -l.30)
PERCENT
RECOVERY
88
Matrix ......... : WATER
METHOD
SW846 8290
RECOVERY
LIMITS
(40 -135)
SEVERN •
•
• A part ol Se~m Trent pie
STL
ANALYTICAL REPORT
Raleigh, Biweekly NPDES
Lot ff, C3G190129
Rita Bauer
The RETEC Group Inc
SEVERN TRENT LABORATORIES, INC.
Veronica Bortot
Project Manager
July 30 1 2003
Severn Trent Laboratories, Inc.
STL Pittsburgh• 450 William Pitt Way, Pittsburgh, PA 15238
Tel [phone] Fax [phone] • www.stl-inc.com
. . . . ' . ····-----·--·-
STL
NELAC REPORTING:
The format and content of the aitached report meets NELAC standards and guidelines except as
noted In the narrative. The table below presents a summary of the certifications held by STL
Pittsburgh. Our primary accreditation authority for the Non-potable water and Solid & Hazardous·
waste programs is New York.State DOH. A more detailed parameter list is available upon
request. Please ask your project manager for this information when required. · ·
. Table· Certificatioris/Accredifr1tion
· · .Certifying : . . Certificate # · · · Program Typ "s · . STL p·ttsburgh· State/Program e • 1
NFESC ·.. . . . . . .. NA'. .. . . . . ... NAVY .. ·.·· , . . , X i:~~~~~~il~~!f i~i;,~:J.~l{,~I i~l:;t~!iil~~~i~~Iiil:~~:;:~~~,~~~~!.t~;
Coriiiectictit (#PH-0688) • WW X
;lilifi~Jl\~J,i~~il~~lim~l\l~~J:l~l~ii!Thfl~f}ifi1;i~fiWft1ii1:;;1tl\i~~ifjl!~iif irf~i/:t
!1~::itg;;;; i~iiiiiii*!ii}i};;;tiiilii~~!ii~l~ti,}1:~:tti!1!~~[~,~tf}1}!}!il~~Ji/.?~iijji.
Louisiana -nelac · (#93200) · WW , X . . . . ~-k ~tti;w~!t~~1f !~?~~~irlt~~, !Ml} . ·· .. ~trtil~IIiJffli~liiri1l~:1?l!!]~i/!;~}!
~~~l1!~1Mtj;:1f.~1l~t~;~iijt(1t.1i~;~i41~:~~!f~,~i~I;~ifi~1-1t\l~~~i~:~1£iti1.i!ijJ1tt~sl!i;~~Z,~;
~~•-f~~~ftj
If.iliirt~}itrni!~:ti~1j~}fi!~liiffj;jf~lt~1fj~~i?i:gfi!{~~i:I!~~i;if~it~~i:~~\::
West Virginia (#142) ·-·-. .. . . WW . X ·------· ..... ······-·····-AW··-•· X
The codes utilized for program typ,es are described below:
HW
WW
X
Hazardous Waste certification
Non-potable Water arid/or Wastewater certification
Laboratory has some form of certification under. the specific program. Many states certify
laboratories for specific parameiers or tests within a category. The information in the
table indicates the lab is certified in a general category of testing. Please contact the
laboratory If parameter specific certification Information is required.
•
•
•
Sample Receiving:
CASE NARRATIVE
THE RETEC GROUP
Raleigh, Biweekly NPDES
STL Lot# C3GI90129
STL Pittsburgh, PA received one sample on July 19, 2003 in good condition. The cooler
was received within the proper temperature range.
If project specific QC was not required for samples contained in this report and batch QC
was completed on these samples, anomalous results will be discussed below.
GC/MS Semivolatiles SIM:
The initial calibratio_n analyzed had compounds outside the 15%RSD criteria. The
average %RSD of all the compounds in the five-point caiibration mix was less than 15%.
Therefore, the average response factor was used for all compounds. See the following
sheets for the compounds and the %RSDs.
The continuing calibration analyzed had compounds outside the ±15%D criteria. The
average %D of all the compounds in the continuing calibration mix was less than 15%.
Therefore, analysis continued and the resnlts for the samples reported. See the following
sheets for the compounds and the %Os.
The reporting limits were adjusted according to the amount of sample extracted .
Data File: \\qpitpa02\d\chem\msd7.i\M061903.b/M0619SC5.D
Report Date: 06/19/2003
INITIAL CALIBRATION REPORT
Injection Date: 19-JUN-2003 09:32
Lab Sample ID: sstd20 • Instrument ID: msd7.i
Lab File ID: M0619SC5.D
Analysis Type: NONE Method File: \ \QPITPA02\D\chem\msd7. i \M061903 .b\sim.m
I
I COMPOUND I IRSD I
1•···································1·······1 12-Fluorophenol I 15.SI
jPhenol-dS I 11.11
J Phenol I 3.11
lbis(2-Chloroethyl)ether I s.,1
11,3-Dichlorobenzene I 5.71
11,4-Dichlorobenzene I i. al
ll,2-Dichlorobenzene I 3 .2j
12,2'-oxybie(l-Chloropropnne) I 3.21
]N-Nitroso-di-n-propylamine I S.Jj
INitrobenzene-dS I 2. 71
INitrobenzene I 11. JI
12,4-Dichlorophenol I 6.7\
I Naphthalene I 8. 91
[Hexachlorobutadiene I 4.8[
12-Methylnaphthalene I 10.J I
11-Methylnaphthalene I 22. 91
/2-Fluorobiphenyl I 10. o I
12-Chloronaphthalene I 10.4) • IAcenaphthylene I 9. J !
!Acenaphthene I 11. oj
I Fluorene I 12. 4 I
f2,4,6-Tribromophenol I 9. 51
IHexachlorobenzene I , . , I
[Pentachlorophenol I 14. 2 I
IPhenanthrene I 10. 9 I
[Anthracene I e., I
ICarbazole I 9.6 I
I Fl uoranth.ene I 9.Sj
IPyrene I 10.11
I Terphenyl-d14 I 13 .1 I
IBenzo(a)Anthracene I 12.01
13,3'-Dichlorobenzidine I 5-31
I Chryeene I 12. s I
IBenzo(b}fluoranthene I 1.21
jBenzo(k)fluoranthene I 13.ol
!Benzo(alpyrene I 10.11
IIndeno(l,2,3-cd)pyrene I 11. o I
IDibenz(a,h)anthracene I 10. 6 I
jBenzo{g,h,i)perylene I 10.31
I
•
•
•
Data File: \\qpitpa02\d\chem\msd7.i\M061903.b/M0619SCS.D
Report Date: 06/19/2003
Instrument ID: msd7.i
Lab File ID: M0619SCS.D
Analysis Type: NONE
I
INITIAL CALIBRATION REPORT
Injection Date: 19-JUN-2003 09:32
Lab Sample ID: sstd20
Method File: \\QPITPA02\D\chem\msd7.i\M061903.
l COMPOUND l \RSD I
1•••••······················•··•·····1•·····•1 1 ______________ 1
The average of all IRSD's in the initial calibration is 9.3
Data File: \\qpitpa02\d\chem\msd7.i\M072803.b/M07288CC.D
Report Date: 07/28/2003
CONTINUING CALIBRATION COMPOUNDS
PERCENT DRIFT REPORT
Injection Date: 28-JUL-2003 07:55
Lab Sample ID: sstd4.0 • Instrument ID: msd7.i
Lab File ID: M07288CC.D
Analysis Type: NONE Method File: \\QPITPA02\D\chem\msd7.i\M0'72803.
EXPECTED I MEASURED I I MAX I
I COMPOUND I CONC. I CONC. I •o I ,o I
1·····-······························1··-·········1···········-1······1······1
185 2-Fluorophenol 4.00001 4.36131 '. 01 100.0(
104 Phenol-dS 4.00001 4.6278/ 15.71 100.01 1 Phenol 4.00001 4 .37401 9,41 1.00.01 11 l,4-Dichlorobenzene-d4 B.0000/ e.00001 0.01 35 01
181 Nitrobenzene-dS 4.00001 3.85761 J .6 I Js.01 1B 2,4-Dichlorophenol 4.00001 3.63571 9-11 100.0j
32 Naphthalene-dB 8.0000[ s.00001 O -O! JS.DI 182 2-Fluorobiphenyl 4.00001 3.9145/ 2. l) 35. 01
52 Acenaphthene-dlO a.00001 a.00001 o. o\ JS.DI 1B6 2,4,6-Tribromophenol 4.0000j J.70931 1. 3 I 100.01
47 Pentachlorophenol 4,0000) 1.54551 s1.4 I 100.01
7B Phenanthrene-dlO a.00001 a.00001 0. 01 JS.OJ 1B3 Terphenyl-d14 4.00001 J.'1173! 14. 6! 35 01
90 Chrysene-d12 8.00001 8.00001 o .o) 35 ol 101 Perylene-d12 8.00001 8.00001 o.o/ 35 01
I •
•
•
•
Data File: \\qpitpa02\d\chem\msd7.i\M072803.b/M0728SCC.D
Report Date: 07/28/2003
Instrument ID: msd7.i
Lab File ID: M0728SCC.D
Analysis Type: NONE
I
CONTINUING CALIBRATION REPORT
Injection Date: 28-JUL-2003 07:55
Lab Sample ID: sstd4.0
Method File: \\QPITPA02\D\chem\msd7.i\M072803.b\sim.m
I COMPOUND I \D I
1·······-····························1·······1
12-Fluorophenol I 9.01
IPhenol-dS I 15.71
I Phenol I 9.4(
\Nitrobenzene-d5 I 3.6)
j2,4-Dichlorophcnol j 9.11
12-Fluorobiphenyl I 2.lj
12,4,6-Tribromophenol 1 7.3J
IPentachlorophenol I 61.41
I Terphcnyl-dl4 I 14.. 6 !
1-------~-----1
The average of tn•s in the continuing calibration is 14.7
MEmons SUMMARY
C3Gl90129
ANALYTICAL PREPARATION
PARAMETER
8270C (SIM) SW846 8270C SIM SW846 3520C
References:
SW846 11Test M~thods for Evaluating Solid Waste, Physical/Chemical
Methods", Third Edition, November 1986 and its updates.
•
•
•
•
•
•
SAMPLE SUMMARY
C3Gl90129
WO# SAMPLE# CLIENT SAMPLE ID
FTM27 001 EFF/SV-305
NOTE(S):
-1bc analytical results of the samples liStcd above are presented on the following pages.
-All calculations are performed before rounding to avoid round•off errors in calculated results.
-Results noted as "ND" were not detected at or above lhe stated limit.
-This report must not be reproduced, except in full, without the wriucn approval of lhe laboratory.
• Results for the following parameters are oever reported on a dry weight basis: color, corrosi,·ity, density, flashpoint, ignitability, layers, odor,
paint filter test, pH, porosity pressure, reactivity, redox potential, specific gravity, spot tests, solids, solubility, temperature, viscosity, and weight .
SAMPLED
DATE
SAMP
TIME
07/17/03 12:50
SEVERN
TRENT Slt Pittsburgh STL Chain of
Custody Record Severn Trent Laboratories, Inc. 450 William Pitt Way, Bldg. 6
Pittsburgh, PA 15238
STL-412◄ (0901)
Cf;ent P,' ·+,;;
"• IDl'l
Project Ma~er "+-~ Ra-vv-U" Oat;f,7 07
Chain of Custody Number 184214
1•~7-i ? o-\Lv-Av-< Telephone Number j'Area Code)/Fax Number Lab Number Cf--n-'31/ -) t.(;;i,J. Page l of I
City J
1 mn-r~i➔'-{ ~ Site Contact Lab Contact Analysis (Attach list if 't-.... ✓~--mores ace is.needed ·
Project Name and Location (State) ct:rz::;;umb721·s~:rDS ~ ~ .J
'IS E".-A-2=7--03b:2 '-f-O't& 1 Special Instructions/ ContracVPurchass Order/Quote No. • Containers & \) Conditions of Receipt Matnx Preservatives ,:, r<.
Sample I.D. No. and Description Dato Time i [ 0 ~ 5 "a ~ ~ ~ ~ ~ {l (Containers for each sample may bo combined on one /Ins) ~ § ~ l ~~ ~ ~ ,:
17.PP / svJ1<>~ 7 h1llt'"? ,~ r t "' '
' -
Possible Hazard ldentif,ca/ion I Sample Disposal
~~sposal By-Lab
(A fee may be assessed if samples are retained• 0 Non-Hazard 0 Flammable D Skin frritanr D Poisons ~Unknown D Retum To Client O· AtchWe.For Months longer than 1 month)
Tum Around Time Required OC Reqwremenrs (SpeCJfy)
0 24 Hours D 48 Hours D ?Days O 14 Days O 21 Days
.1. Relinquished BY,
2. Relinquished By
3. Relinqufshed By
Comments
DJSTRJSl WHITE -Returned to Cfient wtth Report; CANARY -Stays Wfth the $ample; PINK -Field Copy
•
•
•
THE RETEC GROUP INC
Client Sample ID, EFF/SV-305
GC/MS Semivolatilea
Lot-Sample U ... , C3Gl90129-001 Work Order U ... , FTM2 71AA
Date Received .. , 07/19/03
Analysis Date .• , 07/28/03
Analysis Time .. : 16:03
Matrix ......... : WATER
Date Sampled ... , 07/17/03 MSRunU •.•.••. ,
Prep Date ...... , 07/23/03
Prep Batch# ... , 3204448
Dilution Factor: 0.97
Method ......... , SW846 8270C SIM
REPORTING
PARAMETER RESULT LIMIT UNITS
2,4-Dichlorophenol ND 0.19 ug/L
Pentachlorophenol ND 0.97 ug/L
Phenol ND 0.19 ug/L
PERCENT RECOVERY
SURROGATE. RECOVERY .. LIMITS
Nitrobenzene-dS 58 (30 -121)
Terphenyl-dl4 54 (11 119)
2-Fluorobiphenyl 62 (39 -115)
2-Fluorophenol 76 (37 -115)
Phenol-d5 64 (41 -115)
2,4,6-Tribromophenol 56 (40 -115)
Client Lot# ... : C3Gl90129
Mil Lot-Sample#: C3G230000-448
Analysis Date .. : 07/28/03
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene:.:as
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
NOTE(S):
METHOD BLANK REPORT
GC/MS Semivolatiles
Work Order# ... : FTW481AA
Prep Date ...... : 07/23/03
Prep Batch# ... : 3204448
REPORTING
RESULT LIMIT UNITS
ND 0.20 ug/L
ND 1.0 ug/L
ND 0.20 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
55 (30 -121)
51 (11 -119)
62 (39 -115)
64 (37 -115)
67 (41 -115)
62 (40 -115)
Calculations are perfonncd before ro~ing to avoid round-off errors in calculated results.
•
Matrix ......... : WATER
Analysis Time .. : 14:42
METHOD
SW846 8270C SIM
SW846 8270C SIM
SW846 8270C SIM
•
•
•
•
•
July 8, 2003
Ms. Beverly Hudson
Remedial Project Manager
U.S. EPA-Region IV, 11th Floor
North Site Management Branch
61 Forsyth Street, SW
Atlanta, GA 30303
RE: Monthly Progress Report #122
Remedial Action
Koppers Site -Morrisville, North Carolina
Dear Ms. Hudson:
In accordance with the Unilateral Order, and on behalf of Beazer East, Inc. (Beazer), please find attached
four (4) copies of the June Monthly Progress Report for Remedial Action at the Koppers Superfund Site
in Morrisville, North Carolina. No exceedances occurred during this event.
Should you need additional information regarding this progress report, please call Mike Helbling at
[phone] or me at [phone] .
Sincerely,
The RETEC Group, Inc.
'ff~~~
Rita Bauer
Project Geologist
Enclosure
cc: D. Mattison -NC Superfund (2 copies)
L. Faulconer -Wake County
G. Caskey -En wood Structures
M. Helbling -Beazer
H:\Ueaz-Ralei\06M-03.doc
D. Hails -EAP Industries, Inc.
J. Garrett -NC Division of Water Quality
M. Matthews -NC Division of Water Quality
P. Kilchenstein -RETEC
•
•
•
MONTHLY PROGRESS REPORT #122
REMEDIAL ACTION
SITE NAME: Koppers Superfund Site
Beazer East, Inc.
Morrisville, NC
USEP A DOCKET NUMBERS: 93-09-C
PERIOD ENDING: June 30, 2003
1. PROGRESS MADE THIS MONTH
2.
3.
4.
5.
6.
Remedial Action (RA) -HABITAT MITIGATION. No activities were conducted this
month.
Remedial Action (RA) -GROUNDWATER TREATMENT. The treatment system
operated throughout the month without upset. System performance was monitored on a
biweekly basis. Approximately 45,780 gallons of groundwater were extracted, treated in
the treatment plant, and discharged between June I, 2003 and June 30, 2003. System
water samples were collected on June 2 and June I 6, 2003 in accordance with the
sampling schedule in the O&M manual. Samples were submitted to Severn Trent
Laboratories, Inc. for laboratory analysis. The operations and sampling programs are
summarized on the attached Table I.
Remedial Action (RA) -EFFECTIVENESS MONITORING PROGRAM. No activities
were conducted this month.
Remedial Action (RA) -CORRESPONDENCE. None.
PROBLEMS RESOLVED
PROBLEMS ANTICIPATED
UPCOMING EVENTS
PERSONNEL CHANGES
SUBCONTRACTORS
None.
None.
Continue System O&M.
None.
None.
7. ANALYTICAL DATA Analytical data from system influent and effluent
sampling received during this period are enclosed and are summarized on Table 2 .
H:\Bcaz-Ralei\06M-03.doc
Table 1
Groundwater Treatment Operations and Sampling Program Summary
Koppers Superfund Site
Date Systems Cumulative SV-101 sv.101
Check Effluent Flow Sample Sample
(yes/no) {Gallons) (yes/no) Parameters
01/15/03 ves 3 715,610 ves Penta, 2,4-Dichloro Phenol, Dioxin
01/28/03 ves 3,733,790 no
02/11/03 ves 3 753 160 no
02/28/03 ves 3,779,540 no
03/14/03 ves 3,800 330 no
03/24/03 ves 3,818.300 no
04/09/03 no
04/11/03 ves 3 850 120 ves Penta, 2 4-Dichloro Phenol
04/21/03 ves 3,869,820 no
05/05/03 ves 3,894,370 no
05/19/03 ves 3,907,850 no
06/02/03 ves 3 944,990 no
06/16/03 yes 3,971,250 no
Notes:
Sampling point SV-101 is located before the Carbon Units (pretreatment)
Sampling point SV-304 is located between the Carbon Units
Morrisville, North Carolina
June 2003
Associated SV-304 SV-304 Associated SV-305
Group Sample Sample Group Sample
(yes/no) Parameters (yes/no)
1,2 ves Penta 2 4-Dichloro. Phenol 1 ves
no yes
no ves
no ves
no ves
no ves
no ves
1 ves Penta 2 4-Dichloro Phenol 1 ves
no yes
no ves
no yes
no ves
no yes
Associated Groups:
SV-101 -Group 1 is penta, phenol, and 2,4-dichlorophenol; Group 2 is dioxin
SV-304 -Group 1 is penta, phenol, and 2,4-dichlorophenol
SV-305
Sample
Parameters
Penta 2,4-Dichloro, Phenol Dioxin
Penta, 2,4-Dichloro, Phenol, Chronic Tox
Penta, 2,4-Dichloro Phenol
Penta, 2,4-Dichloro, Phenol
Penta 2,4-Dichloro, Phenol
Penta, 2,4-Dichloro, Phenol
Chronic Tox
Penta, 2,4-Dichloro Phenol Dioxin
Penta, 2,4-Dichloro, Phenol
Penta 2,4-Dichloro Phenol
Penta, 2,4-Dichloro, Phenol
Penta, 2.4-Dichloro Phenol
Penta, 2,4-Dichloro, Phenol
Sampling point SV-305 is lactated after the Carbons Units (post-treatment) SV-305 -Group 1 is penta, phenol, and 2,4-dichlorophenol; Group 2 is dioxin and Group 3 is chronic toxicity
H.'1Pfojeds\0362~\Repor1s\Manby\06M.03 Table 1.xls e •
Associated
Group
1 2
1,3
1
1
1
1
3
1 2
1
1
1
1
1
•
•
•
Table 2
Groundwater Treatment Analytical Data Summary
Koppers Superfund Site -Morrisville, North Carolina
June 2003
Analytical
Parameter Date Sample
Sample Location
Collected SV-101
Pentachloronhenol 01/15/03 17
01/28/03
02/11/03
02/28/03
03/14/03
03/24/03
04/11/03 21
04/21/03
05/05/03
05/19/03
06/02/03
06/16/03
2.4-Dichlorophenol 01/15/03 <0.19
01/28/03
02/11/03
02/28/03
03/14/03
03/24/03
04/11/03 <0.81
04/21/03
05/05/03
05/19/03
06/02/03
06/16/03 ....
Phenol 01/15/03 <0.19
01/28/03
02/11/03
02/28/03
03/14/03
03/24/03
04/11/03 <0.81
04/21/03
05/05/03
05/19/03
06/02/03
06/16/03
Chronic Toxicitv 01/28/03
04/09/03 ·
Dioxin /2,3,7,8-TCDDl 01/15/03 <0.22
04/11/03
Notes: All results are in micrograms per liter (µg/L) except dioxin. Dioxin data is in picograms per liter (pg/L).
SV-101 -Before Carbon Units
*SV-304 -Between Carbon Units
.. SV-305 -After Carbon Units
H;\Projects\03624\Reports\Monthly\0SM-03
Sample
Location
SV-304'
<1.0
<0.96
<0.20
<0.19
<0.20
<0.19
Sample
Location
SV-305"
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.1
<1.0
<1.0
<0.98
<0.98
<0.98
<0.21
<0.20
<0.20
<0.20
<0.20
<0.20
<0.21
<0.20
<0.20
<0.20
<0.20
<0.20
<0.21
<0.20
<0.20
<0.20
<0.20
<0.20
<0.21
<0.20
<0.20
<0.20
<0.20
<0.20
Pass
Pass
<0.28
<0.27
SEVERN
•
•
• '-p~11t of~, Trtnt pie
STL Pittsburgh
ANALYTICAL REPORT
Raleigh, Biweekly NPDES
Lot JI, C3F040325
Rita·EaU.er-
The RETEC Group Inc
SEVERN TRENT Ll\BORATORIES, INC.
Veronica Bortot
Project Manager
June 16, 2003
Severn Trent Laboratories, Inc .
r/2
STL Pittsburgh • 450 William Pitt Way, Pittsburgh, PA 15238
Tel [phone] Fax [phone] • www.st/;nc.com
1 of B
Sample Receiving:
CASE NARRATIVE
THE RETEC GROUP
Raleigh, Biweekly NPDES
STL Lot# C3F040325
STL Pittsburgh, PA received one sample on June 4, 2003 in good condition. The cooler
was received within the proper temperature range
GC/MS Semivolatiles SIM:
Since insufficient sample volume was received to perform a matrix spike and matrix
spike duplicate, a Laboratory Control Sample (LCS) and Laboratory Control Duplicate
(LCD) were performed. All recoveries were within QC limits.
STL Pittsburgh 2
•
•
•
of 8
•
•
.MEIBODS SUMMARY
C3F040325
ANALYTICAL PREPARATION
PARAMETER METHOD ~M=ET~H~O~D=------
8270C (SIM) SW846 8270C SIM SW846 3520C
References:
SW846 "Test Methods for Evaluating Solid Waste, Physical/Chemical
Methods11 , Third Edition, November 1986 and its updates .
STL Pittsburgh 3 of B
SAMPLE SUMMARY
C3F040325
WO# SAMPLE# CLIENT SAMPLE ID
FPXWV 001 EFF/SV-305
NOTE(S)
• The analytical results of the samples li~cd above arc presented on the following pajtes,
• All calculations are performed before rounding 10 avoid round-off errors in calculated results.
-Results noted as "ND" were not detected at or above lhe stated limit.
• This report must not be reproduced, except in foll, without lhe written approval of the laboratory.
• Results for the following parameters arc never rcponcd on a dry wei&ht basis: color, corrosivity, density, flashpoint, igoitability, layers, odor,
paint filter test, pH, porosity pressure, reactivity, redox potential, specific gravi1y, S?()l lcsts, solids, solubility, temperature, viscosity, and weigh1.
STL Pittsburgh 4
SAMPLED
DATE
•
SAMP
TIME
06/02/03 10, 48
•
•
of 8
• V1
0 ,.,,
• Chain-of
Custody Record
QUA-4121 0787
c,en0 _--h';
n '-" •
Addmss
'JDO Ui'ht..tr{c A.:vfi.
City C,e:,-AeorJ
Project Name
0?1-J ../-'l\:E'.,lt\---Z 7--
Contract/Purchase 0rder/Ouo!e No.
I °'i'~ I Zip Code ,1/ D 17'1 J..
o'J?
' Sample J.D. No. and Description Date (Containets tor each sample may be combined on one line)
£ r--i= 1-Sv , 3 . .,.,.~ <,,b.l 01
Possible Ha:zarc:J Identification
D· Non-Hazard 0 Aammable 0 Skfn Irritant OPofson8
•
Pro~c/1..rt: R. . -r
Telephone Number (Are.a Code)/Fax Number
0/r? -?7/ J 4J,,)..
Site Contact LabCon1act .
! Garrier/WaybJIJ Number I,-,
!:[J) £-.' <l';)., 1,,-,'JoS-(. Cj]o , ;
;;:
Matrix Containers & I'-PreseNsrives
r.S • ! ~ i 5 '<ti§ ~ Time } ,; .. .,. B ,(;! • S' ~ ~i .,. .,. ~
o</1 IY ·~ If-
l sample Disposal
~Jnknown D Retum To Cfient ~isposal By Lab D Archive For
Tum Around Time Requued
0 24Hours
QC Requirements (SpeafyJ
□ 14 Days □ 21 Days
1. Relinquished By
2. Relinquished By
3. Refinquished By
Comments
DJSTRIBUT10N: WHITE -Stays w,1h Um Sample; CANARY -Returned to Cfienl with Report; PINK· Field Copy
• "j}) ~uanterra
D•,1 :J O:J Cha;n of Custody Numbj l 4 6 9
Lab Number i or I Page
Analysis (Attach Iis"t~~ more snace is neede
Special JnstrucUons/
Conditions of Receipt
{A lee may be assessed if samples .are retained
Months longer than 3 months)
THE RETEC GROUP INC
Client Sample ID, EFF/SV-305
Lot-Sample fl ... , C3F040325-001
Date Sampled ... , 06/02/03
Prep Date ...... , 06/09/03
Prep Batch~ ... , 3160343
Dilution Factor: 0.98
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-ds
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
STL Pittsburgh
GC/MS Semivolatiles
Work Order# ... , FPXWVlAA
Date Received .. , 06/04/03
Analysis Date .. , 06/12/03
Matrix .. -..... -: WATER
MS Run# ....... ,
Method ......... , SW846 8270C SIM
REPORTING
RESULT LIMIT UNITS
ND 0.20 ug/L
ND 0.98 ug/L
ND 0.20 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
75 (30 -121)
55 (11 -119)
58 (39 115)
63 (37 -115)
7l (41 -115)
58 (40 -115)
6
•
•
•
of 8
•
Client Lot: II ... , C3F040325
MB Lot-Sample#, CJF090000-343
Analysis Date .. , 06/12/03
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-ds
Terphenyl-d14
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
NOTE (S) ,
METHOD BLANK REPORT
Ge/MS Semivolatiles
Work Order !I ... , FP7JP1AA
Prep Date ...... , 06/09/03
Prep Batch 11 •.. , 3160343
REPORTING
RESULT LIMIT UNITS
ND 0.20 ug/L
ND 1.0 ug/L
ND 0.20 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
89 (30 121)
65 (11 119)
68 ( 3 9 -115)
77 (37 115)
90 (41 115)
69 (40 115)
• Caltul:ltiom a.re performed before rounding to avoid roun<l•off errors in calculated rcsu!1s .
•
STL Pittsburgh 7
Matrix ......... : WATER
METHOD
SW846 8270C I SIM
SW846 82\0C SIM
SW846 8270C SIM
of 8
LABORATORY CONTROL SAMPLE EVALUATION REPORT
GC/MS Semivolatiles
Client Lot# ... : C3F040325 Work Order# ... : FP7JP1AC-LCS
FP7JP1AD-LCSD
Analysis Date .. : 06/12/03
Matrix ......... : WATER LCS Lot-Sample#: C3F090000-343
Prep Date ....•. : D6/09/03
Prep Batch lt ... : 3160343
Dilution Factor~ 1
PARAMETER
Phenol
Pentachlorophenol
2,4-Dichlorophenol
SURROGATE
Nitrobenzene-ds
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-ds
2,4,6-Tribromophenol
NOTE(S):
PERCENT
RECOVERY
63
64
43
46
59
62
Calculations arc performed before rounding to avoid round-o!C errors in c.alculated rcsu\1s.
STL Pittsburgh
RECOVERY
LIMITS
(10 131)
(10 -131)
(10 -140)
(10 140)
(42 -115)
(42 -115)
PERCENT
RECOVERY
80
82
61
64
63
65
67
7D
77
75
75
76
8
RPD
~ LIMITS METHOD
SW846 8270C SIM
2.0 ( D-4 3) SW846 8270C SIM
SW846 827DC SIM
5.9 (0-56) SW846 8270C SIM
SW846 8270C SIM
5.0 (0-44) SW846 8270C SIM
RECOVERY
LIMITS
(30 -121)
(30 -121)
(11 -119)
(11 -119)
(39 -115)
(39 -115)
(37 -115)
(37 -115)
(41 -115)
(41 -115)
(40 -ll5}
(40 -115)
•
•
•
of 8
•
•
•
SE.VERN
Ni@i§flt STL
A part of Sewm T~nt pie
ANALYTICAL REPORT
RaJ.eigb, Biweekly NPDES
Lot#, C3F170221
Rita Bauer. .·
'l1le RETEc Group Inc
SEVERN TRENT LABORATORIES, rnc.
Veronica Bertot
Project Manager
June 24, 2003
Severn Trent Laboratories, Inc.
STL Pittsburgh• 450 William Pitt Way, Pittsburgh, PA 15238
Tel [phone] Fax [phone] • www.stt-inc.com
Sample Receiving: .
CASE NARRATIVE
THE RETEC GROUP
Raleigh, Biweekly NPDES
STL Lot# C3Fl 70221
STL Pittsburgh, PA received one sample dh June 17, 2003 in good condition. The cooler
was received within the proper temperature range
GC/MS Semivolatiles SIM:
The reporting limits were adjusted according to the amount of sample extracted.
Since insufficient sample volume was received to perform a matrix spike and matrix
spike duplicate, a Laboratory Control Sample (LCS) and Laboratory Control Duplicate
(LCD) were performed. All recoveries were within QC limits.
•
•
•
•
PARAMETER
8270C (SIM)
References:
MEIBODS SUMMARY
C3Fi70221
. ANALYTICAL
METHOD
SW846 8270C SIM
PREPARATION ·. f; METHOD
SW846 "Test Methods for Evaluating Solid Waste, Physical/Chemical
Methods11 , Third Edition, November 1986 and its updates .
SAMPLE SUMMARY
C3Fl-70223-•
SAMPLED SAMP
WO .. # .. SAMPLE# CLIENT SAMPLE ID DATE TIME
FQNJ9 001 EFF/SV-305 06/16/03 13:48
NOTE(S}
-The :analytical results of the samples listed above are presented on the following {'ages.
-All calcut;itions are perfonned before rounding to avoid round-off errors in calculated results.
-Results noted as "ND~ were not detected at or above the ~ted linrit.
-This repon must nol be reproduced, ~ccpt in full, without the wrinen approval of the laboratory.
-Results for thC following parameters are never reported on a dry weight basis: oolor, corrosivity, density, flashpoint, ignitability, layers, odor.
paint filter test, pH, porosity pressure, reactivity, red ox potential, specific gravity, spot tests, solids, solubility, temperature, viscosity, and weight.
•
•
•
Chain of
Custody Record
STL-◄ 124 j0901) m,D,t;.J
Addmss
'¼,o "W\:'r.e:/L Ii.vi£
City ~
LWIL<>-r I 1Xl I z;p ;r;,o.
p~~t'J;/7,"~ ~m;,;;·:r -oq (,,
Conlracl/Purchase Order/Quote No.
Sample I.D. No. and Description Date (Containers for each sample may be combined on oni, fine)
f:FY/Sv-~cK GI I r.lo:r
'
Possible Hazard Identification
D Non-Hazard 0 Rammable D Skin fm'tanl D Po/sonB ,
2. Relinqwshed
J. Relinquished By
Comments
e • SEVERN·
··.TRENT. STL Sll Pittsburgh
Severn Trent Laboratories, Inc.
450 William Pitt Way, Bldg. 6
Pittsburgh, PA 15238
Project Msna9/!2.i.~ [so,.,w..r Dat~l[G 0) Cham of Custodv Number : 185498
Tel(f1{ ~b; ~Ar: ~~):~Number Lab Number . l I
Page of
Site Contact Lab Con/act Analysis (Attach list if
more s ace is needed
Camer/>/tlaybi/1 Number ~ r .~ Special Instructions/
Containers & (. Conditions of Receipt
Matrix Preservatives " V,
' " ii 8 a ~6 ~ Time ' l ~ [ ~ ~ • § ~ 2 ~ N~ ' .,, X
rr·fil 'L X
I Sample Disposal
'N:f" Unknown O Retum To Client fi<{Oisposal By Lab D Archive For
(A fee may be assessed if samples are retained
Months longer than 1 month).
/ QC Reqwrements (Specrfy)
Date Time
Date Time
DISTRIBUTION: WHITE -Returned to Client with Report; CANARY. Stays with the Sample: PINK· Field Copy
THE RETEC GROUP INC
Client Sample ID: EFF/SV-305
GC/MS Semivolatiles
L<?t:~!l"1_l1l'le, ,ll•, · . .'. C3Fl 70221-001 Work Order # ••• : FQNJ91AA
Date Received .. : 06/i 7 )63
Analysis Date .. : 06/20/03
Matrix ......... : WATER
MS Ii.tin# .. : .... : Date Sampled ... : 06/16/03
Prep Date ...... : 06/18/03
Prep Batch # •.• : 3170115
Dilution Factor: 0.98
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-ds
Terphenyl-d14
2-Fluorobiphenyl
2-Flu·orophenol
Phenol-d5
2,4,6-Tribromophenol
Method ......... : SW846 8270C SIM
REPORTING
RESULT LIMIT UNITS
ND 0.20 ug/L
ND 0.98 ug/L
ND 0.20 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
62 (3 0 -121)
60 (11 -119)
58 (39 -115)
57 (37 -115)
66 (41 -115)
65 (40 -115)
•
•
•
•
•
•
, . . ,.: .-.i j f
' '
MRTHOD BLANK REPORT
GC/MS Sernivolatiles
Client Lot If ... , .C3Fl70221 Work Order ti ... : FQR2HlAA
Mil LciE~sainpie Ii,· c:iFi9cicioo-i1s··
Analysis Date .. : 06/20/03
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-dS
2,4,6-Tribromophenol
NOTE (S) ,
Prep Date ...... : 06/18/03
Prep Batch ll ... : 3170115
REPORTING
RESULT LIMIT
ND 0.20
ND 1.0
ND 0.20
PERCENT RECOVERY
RECOVERY LIMITS
66 (30 -121)
61 (11 119)
61 (39 -115)
65 (37 -115)
70 (41 -115)
67 (40 -115)
Calculations are performed before rounding lo avoid round-off errors iu calculated results .
Matrix •........ : WATER
UNITS METHOD
ug/L SW846 8270C SIM ' ug/L SW846 8270C SIM
' ug/L SW846 8270C SIM
Client Lot # ••• : C3Fl 70221
LCS-r.o1:>sariip1<e#: C3-Fl90b 00 c 115
Prep Date ...... : 06/18/03
Prep Batch# ... : 3170115
Dilution Factor: l
PARAMETER
Phenol
Pentachlorophenol
2,4-Dichlorophenol
SURROGATE
Nitrobenzene-ds
Terphenyl -dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribrornophenol
NOTE (S) :
Work Order# ... : FQR2HlAC-LCS
FQR2HlAD-LCSD
Analysis Date .. : 06/20/03
Matrix ......... : WATER
PERCENT RECOVERY RPD
RECOVERY LIMITS RPD LIMITS METHOD
55 (10 -131) SW846 8270C SIM
58 (10 -131) 5.0 (0-43) SW846 8270C SIM
70 (10 -140) SW846 8270C SIM
75 (10 -140) 5.9 (0-56) SW846 8270C SIM
56 (42 -115) SW846 8270C SIM
57 (42 -115) 1. 8 (0-44) SW846 8270C SIM
PERCENT RECOVERY
RECOVERY LIMITS
59 (30 -121)
60 (30 -121)
56 (11 -119)
54 (11 -119)
58 (39 -115)
58 (39 -115)
59 (37 -115)
58 (37 -115)
59 (41 -115)
59 (41 -115)
68 (40 -115)
69 (40 -115)
C.alculations are performed before rounding to avoid round-off errors in calculated results.
•
•
•
•
June 9, 2003
Ms. Beverly Hudson
Remedial Project Manager
U.S. EPA -Region IV, I Ith Floor
No11h Site Management Branch
61 Forsyth Street, SW
Atlanta, GA 30303
RE: Monthly Progress Report #121
Remedial Action
Koppers Site -Morrisville, North Carolina
Dear Ms. Hudson:
( , ..... , ~:1·• t~ -(,-!"i."'
'
In accordance with the Unilateral Order, and on behalf of Beazer East, Inc. (Beazer), please find attached
four (4) copies of the May Monthly Progress Report for Remedial Action at the Koppers Superfund Site
in Morrisville, North Carolina. No exceedances occurred during this event.
Should you need additional information regarding this progress report, please call Mike Helbling at
[phone] or me at [phone] .
Sincerely,
The RETEC Group, Inc.
~~
Rita Bauer
Project Geologist
Enclosure
cc: . D. Mattison -NC Superfund (2 copies)
L. Faulconer -Wake County
G. Caskey -Enwood Structures
M. Helbling -Beazer
1-1:\ncaz-Ralci\0SM-03.doc
D. Hails -EAP Industries, Inc.
J. Garrett-NC Division of Water Quality
M. Matthews -NC Division ofWater1Quality
P. Kilchenstein -RETEC
•
•
•
MONTHLY PROGRESS REPORT #121
REMEDIAL ACTION
SITE NAME: Koppers Superfund Site
Beazer East, Inc.
Morrisville, NC
USEPA DOCKET NUMBERS: 93-09-C
Pl~RIOD ENDING: May 31, 2003
I. PROGRESS MADE THIS MONTH
2.
3.
4.
5.
6.
Remedial Action (RA) -HABITAT MIT/GA TJON. No activities were conducted this
month.
Remedial Action (RA) -GROUNDWATER TREATMENT. The treatment system
operated throughout the month without upset. System performance was mm\itored on a
biweekly basis. Approximately 72,110 gallons of groundwater were extracted, treated in
the treatment plant, and discharged between May I, 2003 and May 31, 2003. System
waler samples were collected ori May 5 and May 19, 2003 in accordande with the
sampling sche.dule in the O&M manual. Samples were submitted to Sdvern Trent
Laboratories, Inc. for laboratory analysis. The operations and sampling prbgrams are
summarized on the attached Table I. I
Remedial Action (RA) -EFFECTIVENESS MONITORING PROGRAM. No activities
were conducted this month.
Remedial Action (RA) -CORRESPONDENCE. None.
PROBLEMS RESOLVED
PROBLEMS ANTICIPATED
UPCOMING EVENTS
PERSONNEL CHANGES
SUBCONTRACTORS
None.
None.
Continue System O&M.
None.
None.
7. ANALYTICAL DATA Analytical data from system influent and effluent
sampling received during this period are enclosed and are summarized on Tab!~ 2 .
1-1:\Bcaz-Ralci\05M-03.doc
Table 1
Groundwater Treatment Operations and Sampling Program Summary
Koppers Superfund Site
Date Systems Cumulative SV-101 SV-101
Check Effluent Flow Sample Sample
(yes/no) (Gallons) (yes/no) Parameters
01/15/03 ves 3,715,610 ves Penta, 2,4-Dichloro, Phenol, Dioxin
01/28/03 yes 3,733,790 no
02/11/03 ves 3,753,160 no
02/28103 yes 3,779,540 no
03/14/03 ves 3,800,330 no
03/24/03 yes 3,818,300 no
04/09/03 no
04/11/03 ves 3,850,120 ves Penta, 2,4-Dich!oro, Phenol
04/21/03 ves 3,869,820 no
05/05/03 ves 3,894,370 no
05/19/03 ves 3,907,850 no
Notes:
Sampling point SV-101 is located before the Carbon Units {pretreatment)
Sampling point SV-304 is located between the Carbon Units
Morrisville, North Carolina
May 2003
Associated SV-304 SV-304 Associated SV-305
Group Sample Sample Group Sample
(yes/no) Parameters (yes/no)
1,2 ves Penta, 2.4-Dichloro, Phenol 1 ves
no yes
no ves
no yes
no ves
no yes
no ves
1 ves Penta, 2,4-Dich!oro, Phenol 1 ves
no ves
no ves
no ves
Associated Groups:
SV-101 -Group 1 is penta, phenol, and 2,4-dichtorophenol; Group 2 is dioxin
SV-304 -Group 1 is penta, phenol, and 2,4-dichlorophenol
SV-305
Sample
Parameters
Penta, 2.4-Dichloro, Phenol, Dioxin
Penta, 2,4-Dichloro, Phenol, Chronic Tax
Penta, 2,4-Dichloro, Phenol
Penta, 2.4-Oichloro, Phenol
Penta, 2,4-0ichloro, Phenol
Penta, 2,4-Dichloro, Phenol
Chronic Tax
Penta, 2,4-Dichloro, Phenol, Dioxin
Penta, 2,4-Dichloro, Phenol
Penta, 2,4-Dichloro, Phenol
Penta, 2,4-Dichloro, Phenol
Sampling point SV-305 is lactated after the Carbons Units {post-treatment) SV-305 -Group 1 is penta, phenol, and 2,4-dichlorophenol; Group 2 is dioxin and Group 3 is chronic toxicity
H·\Projed!NJ3624\Aeports\Mort~ Table 1.Jdl • •
Associated
Group
1,2
1,3
1
1
1
1
3
1,2
1
1
1
•
•
•
Table 2
Groundwater Treatment Analytical Data Summary
Koppers Superfund Site -Morrisville, North Carolina
May 2003
Analytical
Parameter Date Sample Sample
Sample Location Location
Collected SV-101
Pentachlorophenol 01/15/03 17
01/28/03
02/11/03
02/28/03
03/14/03
03/24/03
04/11/03 21
04/21/03
05/05/03
05/19/03
2.4-Dichlorophenol 01 /15/03 <0.19
01/28/03
02/11 /03
02/28/03
03/14/03
03/24/03
04/11/03 <0.81
04/21/03
05/05/03
05/19/03
Phenol 01 /15/03 <0.19
01/28/03
02/11/03
02/28/03
03/14/03
03/24/03
04/11/03 <0.81
04/21/03
05/05/03
05/19/03
Chronic Toxicity 01/28/03
04/09/03
Dioxin (2,3,7,8-TCDD) 01/15/03 <0.22
04/11/03
Notes: All results are 1n micrograms per hter (µg/L) except d1ox1n. D1ox1n data 1s 1n prcograms per hter (pg/L).
SV-101 -Before Carbon Units
"SV-304 -Between Carbon Units
'"SV-305 -After Carbon Units
H:\Projects\03624\Reports\Monthly\0SM-03
SV-304'
<1.0
<0.96
<0.20
<0.19
<0.20
<0.19
Sample
Location
SV-305"
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.1
<1.0
<1.0
<0.98
<0.21
<0.20
<0.20
<0.20
<0.20
<0.20
<0.21
<0.20
<0.20
<0.20
<0.21
<0.20
<0.20
<0.20
<0.20
<0.20
<0.21
<0.20
<0.20
<0.20
Pass
Pass
<0.28
<0.27
SEVERN •
•
• A 1111rt of Severn Trent pie
STL
ANALYTICAL REPORT
Raleigh, Biweekly NPDES
Lot #, C3E06011.0
Rita :,, Bali er i
The RETEC Group Inc
SEVERN TRENT LABORATORIES, INC .
.. . . ,',. ' \··.
veronica
Prc,j ect Manager
May 19, 2003
Severn Trent Laboratories, Inc.
STL Pittsburgh• 450 William Pitt Way, Pittsburgh, PA 15238
Tel [phone] Fax [phone] • www.stJ.inc.com
Sample Receiving:
CASE NARRATIVE
THE RETEC GROUP
Raleigh, Biweekly NPDES
STL Lot# C3E060110
STL Pittsburgh, PA received one sample on May 16, 2003 in good condition. The cooler
was received within the proper temperature range
GC/MS Semivolatiles SIM:
Since insufficient sample volume was received to perform a matrix spike and matrix
spike duplicate, a Laboratory Control Sample (LCS) and Laboratory Control Duplicate
(LCD) were performed. All recoveries were within QC limits.
•
•
•
•
•
•
METIIODS SUMMARY
C3E060110
ANALYTICAL PREPARATION
~P~ARAME==~T~E~R~-------'--------------------METHOD ~ME=TH=O~D~----
8270C (SIM) SW846 8270C SIM SW846 3520C
References:
SW846 nTest Meth6ds foz:: EValuatin9 Solid Waste, Physical/Chemical
Methods11 , Third Edition, November 1986 and its updates .
SAMPLE SUMMARY
C3E060l.1.0
WO# SAMPLE# CLIENT SAMPLE ID
FM6VP 0 01. EFF/SV-305
NOTE(S)
-The analytical results of the samples listed above are presented on lhe following pages.
-All c:alaila1iom are perfonned before rounding io avoid round-off errors in calculated results.
• R~ts noted as "NDft were not d~ at or above Ole stated limit.
• This repon must not be reproduced, except io ful\, without the written approval of the laboratory.
-Results for the following parameteis are never reported on a dry weight basis: ':°\or, corrosivity, densit)', flashpoint; ignitabi!ity, layers, odor,
paint filter test, PH, porosity pressure, reactivity, red ox potential, specific gravily, spot tests, solids, so!Ubility, temperature, viscosity, and weight.
SAMPLED
DATE
SAMP
TIME
05/05,/03 1.0 ,20
•
•
• • • SEVERN
TRENT STL STL Pittsburgh Chain of
Custody Record Severn Trent Laboratories, Inc.
450 William Pitt Way, Bldg. 6
Pittsburgh, PA 15238
-
Client~ Projic'J1'tger ~ Dare -lsi Chsin of Custodv Number
'r+-zu -, _, 5, o3 183817
STL-4124 (0901)
Address lf~ /4.;,e, Telephone Number (Area Code)/Fax Number Lab Number /_ / Too r C/7l-Tll I</)... l--Page of
Clry J I ;4--I ";;, 7-; )' a. Sile Contact l.Eb Contact Analysis (Attach fisl if
more s ace is needed c~
Project Name and Location (State) Ca.rrier/Waybill Number ~~ 1'F-,1-Z:P-&3r;,,1</-r,q~ Pe:}.,!x r.217;;, J 0S6 97 '/ t Special Instructions/
Conrract/Purchase Order/Quote No. Containers & •10: Conditions of Receipt
Matrix PreseNatives \)
Sample J.D. No. and Oescdption ' ~ 0 ~ , .,, R
Date Time [ ~ ~ ! ~ ~ u ~ ~~ ~ (Contam&rs for each sample may be combined on one line) -S ~ < ' ,
(i. F P lsv-~ J v;, ,;-/do-,, IO"' t> ): lC 'K
Possible Hazard Identification I Sample Disposal (A fee may be assessed if samples are retained
D Non-Hazard D Flammable D Skin Irritant D PoisonB Q Unknown D Return Ta Cfient ~Disposal By Lab D Archive For Months longer than f month)
Tum Around Time Required )JO
D 24 Hours D 48 Hours D 7 D;•'!'Y~• _ _i:D:e..c'.'4~DCJ:a:!ys~-'0:::!_2".'__1 0,'.a~ys~...:!'€!-,~~===c=====c...J.7"'=---'--c:------,-----------------c=:-------;,=::-----nme
QC Reqwements (Specsfy)
/G.t:Ju
2. Relinqwshed By Time
3. Relinquished By Time
Comments
DISTRIBUTION: WHITE -Returned ta Client with Report; CANARY. Slays with the Sample: PINK -Ffe/d Copy
THE RETBC GROUP INC
Client Sample ID: EFF/SV-305
Lot-Sample# ... : C3E060110-001
Date Sampled ... : 05/05/03
Prep Date ...... : 05/08/03
Prep Batch# ... : 3129112
Dilution Factor: 1.02
PARAMETER
2,4-DichlOrophenol
Pentachlorophenol
Phenol
SURROGATE
Nitr6behzene-d5
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4;6-Tribromophenol
GC/MS Sernivolatiles
work Order # ... : FM6VP1AA
Date Received .. : 05/06/03
Analysis Date .. : 05/16/03
Matrix .. _ .• ___ .: wii.TER
MS Run It ..•.... :
Method ......... : SW846 8270C SIM
REPORTING
RESULT LIMIT UNITS
ND 0.20 ug/L
ND 1.0 ug/L
ND 0.20 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
59 (30 -121)
55 (11 -119)
54 (39 -115)
59 (3 7 -115)
58 (41 -115)
65 (40 -115)
•
•
•
•
•
•
METHOD BLANK REPORT
GC/MS Semi.volatiles
Client Lot# ... , C3E060110 Work Order# ... , FNEH61AA
MB wt-Sample#, C3E090000-112
Analysis Date .. , 05/16/03
Dilution Factor: l
PARAMETER
2,4~Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-ds
Terphenyl-d14
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
NOTE (S) ,
Prep Date ...... , 05/08/03
Prep Batch# ... , 3129112
REPORTING
RESULT LIMIT
ND 0.20
ND 1.0
ND 0:20
PERCENT RECOVERY
RECOVERY LIMITS
65 (30 121)
57 (11 119)
53 (39 115)
58 (37 -115)
58 (41 115)
63 (40 -115)
Calcula1ions arc performed before rounding to a\·old round~ff errors in calculated results .
Matrix ......... : WATER
UNITS METHOD
ug/L SW846 8270C SIM
ug/L SW846 8270C SIM
ug/L SW846 8270C SIM
LABORATORY CONTROL SAMPLE EVALUATION REPORT
GC/MS Semivolatiles
Client LOt # •.• : C3E060110 work Order# ... : FNEH61AC-LCS
FNEH61AD-LCSD
Analysis Date .. : 05/16/03
Matrix ......... : WATER
LCS Lat-Sample#: C3E090000-112
Prep Date .... ;.: 05/08/03
Prep Batch# ... : 3129112
Dilution Factor: l
PARAMETER
Phenol
Pentachlorophenol
2,4-Dichlorophenol
SURROGATE
Nitrobenzene-ds
Terphenyl-d14
2-Fluorobiphenyl
2-Fluorophenol
Phenol-dS
2,4,6-Tribromophenol
NOTE (S) :
PERCENT
RECOVERY
53
so
52
47
61
56
RECOVERY
LIMITS
(10 131)
(10 -131)
(10 -140)
(10 -140)
(42 "115)
(42 -115)
PERCENT
RECOVERY
65
62
56
51
59
54
56
56
45
44
78
68
Calculations are performe.d before rounding to avoid round-off erron in calculated results.
RPD
RPD LIMITS METHOD
SW846 8270C SIM
6.8 (0-43) SW846 8270C SIM
SW846 8270C SIM
9.4 ( 0-56) SW846 8270C SIM
SW846 8270C SIM
7.5 (0-44) SW846 8270C SIM
RECOVERY
LIMITS
(30 -121)
(30 -121)
(11 -119)
(11 -119)
(39 -115)
(39 -115)
(37 -115)
(37 -115)
(41 -115)
(41 -115)
(40 115)
(40 -115)
•
•
•
SEVERN •
•
• A pa'! of Severn Trent pit
STL
ANALYTICAL REPORT
Raleigh, Biweekly NPDES
Lot#, C3E200247
Rita Bauer
The RETEC Group Inc
SEVERN TRENT LABORATORIES, INC.
~~
Veronica Bortot
Project Manager
May 27, 2003
Severn Trent Laboratories, Inc.
STL Pittsburgh• 450 William Pitt Way, Pittsburgh, PA 15238
Tel [phone] Fax [phone] • www.stl-inc.com
Sample Receiving:
CASE NARRATIVE
THE RETEC GROUP
Raleigh, Biweekly NPDES
STL Lot# C3E0601 I 0
STL Pittsburgh, PA received one sample on May 20, 2003 in good condition. The cooler
was received within the proper temperature range
GC/MS Semivolatiles SIM:
Since insufficient sample volume was received to perform a matrix spike and matrix
spike duplicate, a Laboratory Control Sample (LCS) and Laboratory Control Duplicate
(LCD) were performed. All recoveries were within QC limits.
•
•
•
•
•
•
METHODS SUMMARY
C3E200247
ANALYTICAL PREPARATION
PARAMETER METHOD ~M=E~T=H~O=D ____ _
8270C (SIM) SW846 8270C SIM SW846 3520C
References:
SW846 11Test Methods for Evaluating Solid Waste, Physical/Chemical
Methods 11 1 Third Edition, November 1986 and its updates .
SAMPLE SUMMARY
C3E200247
WO# SAMPLE# CLIENT SAMPLE ID
FN3M4 001 EFF/SV-305
NOTE (S),
-The analytical results of lhe samples listed above are presented on the following pages.
-All calculations are pcrfonned before rounding IO avoid round-off errors in ca\c.u!aled results.
-Results noted as ·ND" were not detected at or above the stated limit.
-This report must not be reproduced, cxcep! in full, without the wriuen approval of the laboratory.
-Results for lhe following parameters are never reponed on a dry weight basis: color, corrosivity, density, flashpoint, ignitability, layers, odor,
paint filter test, pH, porosity pressure, reactivity, redox potential, specific gravity, spot tests, solids, solubility, temperature, viscosity, and weight.
SAMPLED
DATE
•
SAMP
TIME
05/19/03 08,14
•
•
Client: ~
Address: 'Joo \3t-l.'-'I' A,j(t,
Address: 6M<.nrA MA-Ol?f;i,
P,"ffs~~hain-of Custody Record & Analytical Request COC# 15710
Page { of (
Project ID:-~ ~~,/ lJ.ur l-,
P.O. Number: ~~------
Date: 5{Jq (l
Turnaround: __ $7/J~-~---
Job Number: g€kZ1"-o,., 2!/-0 1' C
· Report To: _ _,.~~-------
Contact: {~-n,-.. 8~
Phone: <\?l -3 ,1--1'-{').l-
X
ncHr.UJlll
THE RETEC GROUP INC
Client Sample ID, BFF/SV-305
GC/MS Semivolatiles
Lot-Sample# ... , C3E200247-001 Work Order# ... , FN3M41AA
Date Received .. , 05/20/03
Analysis Date .. , 05/23/03
Matrix ......... : WATER
Date Sampled ... , 05/19/03
Prep Date ...... , 05/21/03
Prep Batch# ... , 3141324
Dilution Factor: 0.98
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
MS Run# ....... ,
Method ......... , SW846 8270C SIM
REPORTING
RESULT LIMIT UNITS
ND 0.20 ug/L
ND 0.98 ug/L
ND 0.20 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
77 (30 -121)
61 (11 -119)
60 (39 115)
70 (37 -115)
72 (41 -115)
75 (40 -115)
•
•
•
•
•
METHOD BLANK REPORT
GC/MS Semivolatiles
Client Lot# ... : C3E200247 Work Order# ... : FN45F1AA
MB Lot-Sample#: C3E210000-324
Analysis Date .. : 05/23/03
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
NOTE(S):
Prep Date ...... : 05/21/03
Prep Batch# ... : 3141324
REPORTING
RESULT LIMIT
ND 0.20
ND 1.0
ND 0.20
PERCENT RECOVERY
RECOVERY LIMITS
84 (30 -121)
63 (11 -119)
65 (39 -115)
71 (37 -115)
78 (41 -115)
84 (40 -115)
Calculations are performed before rounding to avoid round-off errors in calculated results.
Matrix ......... : WATER
UNITS METHOD
ug/L SW846 8270C SIM
ug/L SW846 8270C SIM
ug/L SW846 8270C SIM
LABORATORY CONTROL SAMPLE EVALUATION REPORT
GC/MS Semivolatiles
Client Lot# ... : C3E200247 Work Order# ... : FN45FlAC-LCS
FN45FlAD-LCSD
Analysis Date .. : 05/23/03
Matrix ......... : WATER
LCS Lot-sample#: C3E210000-324
Prep Date ...... : 05/21/03
Prep Batch# ... : 3141324
Dilution Factor: 1
PERCENT RECOVERY RPD
PARAMETER RECOVERY LIMITS RPD LIMITS METHOD
Phenol 68 (10 -131) SW846 8270C SIM
68 (10 -131) 0.040 (0-43) SW846 8270C SIM
Pentachlorophenol 66 (10 -140) SW846 8270C SIM
64 (10 -140) 2.3 (0-56) SW846 8270C SIM
2,4-Dichlorophenol 64 (42 -115) SW846 8270C SIM
63 (42 -115) 2.2 (0-44) SW846 8270C SIM
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Nitrobenzene-dS 75 (30 -121)
74 (30 121)
Terphenyl-dl4 63 (11 -119)
62 (11 -119)
2-Fluorobiphenyl 64 (39 -115)
63 (39 -115)
2-Fluorophenol 67 (37 -115)
66 (37 -115)
Phenol-d5 71 (41 -115)
69 (41 -115)
~,4,6-Tribromophenol 82 (40 -115)
82 (40 -115)
NOTE (S) :
Calculations are performed before rounding to avoid round-off errors in calculated results.
•
•
•
•
•
•
May 8, 2003
Ms. Beverly Hudson
Remedial Project Manager
U.S. EPA -Region IV, I Ith Floor
North Site Management Branch
61 Forsyth Street, SW
Atlanta, GA 30303
RE: Monthly Progress Report #120
Remedial Action
Koppers Site -Morrisville, North Carolina
Dear Ms. Hudson:
In accordance with the Unilateral Order, and on behalf of Beazer East, Inc. (Beazer), please find attached
four (4) copies of the April Monthly Progress Report for Remedial Action at the Koppers Superfund Site
in Morrisville, North Carolina. No exceedances occurred during this event. The April chronic toxicity
sample produced a passing result; therefore, the next chronic toxicity sample will be collected during the
third quarter 2003 ..
Should you need additional information regarding this progress report, please call Mike Helbling at
( 412) 208-8858 or me at [phone].
Sincerely,
The RETEC Group, Inc.
"1r°7J'i4l~ j!,it1pi.n/~
Rita Bauer
Project Geologist
Enclosure
cc: D. Mattison -NC Superfund (2 copies)
L. Faulconer -Wake County
G. Caskey -Enwood Structures
M. Helbling -Beazer
11:\Beaz-Ralci\04M-03.doc
D. Hails -EAP Industries, Inc,
J. Garrett -NC Division of Water Quality
M. Matthews-NC Division of Water Quality
P. Kilchenstein -RETEC
•
•
•
MONTHLY PROGRESS REPORT #120
REMEDIAL ACTION
SITE NAME: Koppers Superfund Site
Beazer East, Inc.
Morrisville, NC
USEPA DOCKET NUMBERS: 93-09-C
PERIOD ENDING: April 30, 2003
I. PROGRESS MADE THIS MONTH
2.
3.
4.
5.
6.
7.
Remedial Action (RA) -HABITAT MITIGATION. No activities were conducted this
month.
Remedial Action (RA) -GROUNDWATER TREATMENT. The treatment system
operated throughout the month without upset. System performance was monitored on a
biweekly basis. Approximately 51,520 gallons of groundwater were extracted, treated in
the treatment plant, and discharged between April I, 2003 and April 30, 2003. System
water samples were collected on April 11 and April 21, 2003 in accordance with the
sampling schedule in the O&M manual. Samples were submitted to Severn Trent
Laboratories, Inc. for laboratory analysis. The operations and sampling programs are
summarized on the attached Table I. Chronic Toxicity samples were collected on April 9,
2003.
Remedial Action (RA) -EFFECTIVENESS MONITORING PROGRAM. No activities
were conducted this month.
Remedial Action (RA) -CORRESPONDENCE. None.
PROBLEMS RESOLVED None.
PROBLEMS ANTICIPATED None.
UPCOMING EVENTS Continue System O&M.
PERSONNEL CHANGES None.
SUBCONTRACTORS None.
ANALYTICAL DATA Analytical data from system influent and effluent
sampling received during this period are enclosed and are summarized on Table 2 .
H;\Beaz-Ralei\04M-03.doc
• •
Table 1
Groundwater Treatment Operations and Sampling Program Summary
Koppers Superfund Site
Date Systems Cumulative SV-101 SV-101
Check Effluent Flow Sample Sample
(yes/no) (Gallons) (yes/no) Parameters
01/15/03 ves 3,715,610 ves Penta, 2,4-0ichforo, Phenol. Dioxin
01/28/03 yes 3,733,790 no
02/11/03 ves 3,753,160 no
02/28/03 yes 3,779,540 no
03/14/03 ves 3,800,330 no
03/24/03 ves 3,818,300 no
04/09/03 no
04/11/03 ves 3,850,120 ves Penta, 2,4-Dichloro, Phenol
04/21/03 ves 3,869,820 no
Notes:
Sampling point SV-101 is located before the Carbon Units (pretreatment)
Sampling point SV-304 is located between the Carbon Units
Morrisville, North Carolina
April2003
Associated SV-304 SV-304 Associated SV-305
Group Sample Sample Group Sample
(yes/no) Parameters (yes/no)
1,2 ves Penta, 2,4-0ichloro, Phenol 1 ves
no yes
no ves
no yes
no ves
no yes
no ves
1 ves Penta, 2,4-Dichloro, Phenol 1 ves
no ves
Associated Groups;
SV-101 -Group 1 is penta, phenol, and 2,4-dichlorophenol; Group 2 is dioxin
SV-304 -Group 1 is penta, phenol, and 2,4-dichlorophenol
•
SV-305
Sample
Parameters
Penta, 2,4-Dichloro, Phenol, Dioxin
Penta, 2,4-Dichloro, Phenol, Chronic Tex
Penta, 2,4-Dichloro, Phenol
Penta, 2,4-0ichloro, Phenol
Penta, 2,4-Dichloro, Phenol
Penta, 2,4-Dichloro, Phenol
Chronic Tax
Penta, 2,4-Dichloro, Phenol, Dioxin
Penta, 2.4-Dichloro, Phenol
Sampling point SV-305 is lactated after the Carbons Units (post-treatment) SV-305 -Group 1 is penta, phenol, and 2,4-dichlorophenol; Group 2 is dioxin and Group 3 is chronic toxicity
F:\Prcjects\03624\RaPOrts\Monlllly\04M-03 Table 1.xls
Associated
Group
1,2
1,3
1
1
1
1
3
1,2
1
''
•
•
•
Table 2
Groundwater Treatment Analytical Data Summary
Koppers Superfund Site -Morrisville, North Carolina
April 2003
Analytical
Parameter Date Sample Sample
Sample Location Location
Collected SV-101 SV-304*
Pentachlorophenol 01/15/03 17 <1.0
01/28/03
02/11/03
02/28/03
03/14/03
03/24/03
04/11/03 21 <0.96
04/21/03
2.4-Dichlorophenol 01/15/03 <0.19 <0.20
01/28/03
02/11/03
02/28/03
03/14/03
03/24/03
04/11/03 <0.81 <0.19
04/21/03
Phenol 01/15/03 <0.19 <0.20
01/28/03
02/11/03
02/28/03
03/14/03
03/24/03
04/11/03 <0.81 <0.19
04/21/03
Chronic Toxicity 01/28/03
04/09/03
Dioxin (2,3,7,8-TCDD) 01/15/03 <0.22
04/11/03
Notes: All results are m micrograms per hter (µg/L) except d1oxrn. Dioxin data 1s 1n p1cograms per hter (pg/L).
SV-101 -Before Carbon Units
"SV-304 -Between Carbon Units
**SV-305 -After Carbon Units
H: \Projects 103624 \Reports \Monthly\04M-03
Sample
Location
SV-305**
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.1
<1.0
<0.21
<0.20
<0.20
<0.20
<0.20
<0.20
<0.21
<0.20
<0.21
<0.20
<0.20
<0.20
<0.20
<0.20
<0.21
<0.20
Pass
Pass
<0.28
<0.27
SEVERN • TRENT
•
• Apzrto!SevemTrentplc
STL
ANALYTICAL REPORT
Raleigh, Biweekly NPDES
Lot#, C3Dl20l2~
Rita BauE!r
The RE'TEC Group Inc
SEVERN TRENT LABORATORIES, INC.
rtf;
Veronica Bortot
Pioject Manager
April 29, 2003
Severn Trent Laboratories, Inc.
STL Pittsburgh• 450 William Pitt Way, Pittsburgh, PA 15238
Tel [phone] Fax [phone] • www.stt<nc.com
Sample Receiving:
CASE NARRATIVE
THE RETEC GROUP
Raleigh, Biweekly NPDES
STL Lot# C3D120124
STL Pittsburgh, PA received samples on April 12, 2003 in good condition. The cooler
was received within the proper temperature range
GC/MS Semivolatiles SIM:
Since insufficient sample volume was received to perform a matrix spike and matrix
spike duplicate, a Laboratory Control Sample (LCS) and Laboratory Control Duplicate
(LCD) were performed. All recoveries were within QC limits.
The reporting limits were adjusted due to the amount of sample used in the extraction
procedure.
Due to the concentration ofpentachlorophenol detected, SV-101 was analyzed at a
dilution.
Dioxins:
The STL Knoxville, TN laboratory analyzed the dioxins.
There were 110 problems associated with the analysis.
r
•
e:
!
l I
J
•
•
•
METHODS SUMMARY
C3D120124
ANALYTICAL PREPARATION
~P~ARAM==E~T~E~R~---------------------METHOD ~M=E~T~H~O;Dc_ ___ _
Dibenzodioxins arid Dibenzofurans, HRGC/HRMS
8270C (SIM)
References:
SW846 8290 SW846 8290
SW846 8270C SIM SW846 3520C
SW846 "Test Methods for Evaluating Solid Waste, Physical/Chemical
Methods 11 , Third Edition, November 1986 and its updates .
I ' I I I-i
I
' !
I I
I
I
WO# SAMPLE# CLIENT SAMPLE ID
FLTRS
FLTR6
FLTR?
NOTE(S)
001
002
003
EFF/SV-305
SV-304
SV-101
SAMPLE SUMMARY
C3D120124
-The analytical results Of the samples liste.d above are presented on the following pag~.
-Al! calculations are performed before rounding to avoid round-off errors in calculated results.
-Results note.cl as "ND• were not detected at or above I.he stated limit.
-Titis repon must not be reproduced, e,;cept in full, withOut the written approval of the laboratory.
-Results for the following parameters are never reported on a dry weight basis: color, corrosivity, density, flashpoint, ignitability. layers, odor,
paint filter test, pH. porosity pressure, reactivity, tt.dox potential, specific gravity, spot tess, solids, solubility, temperature, viscosity, and weight.
•
SAMPL:8D SAMP
DATE TIME
04/11/03 08:30
04/11/03 08,40
04/11/03 08:50
•
• • • SEVERN
TRENT: STL STL Pittsburgh Chain of
Custody Record Severn Trentlaboratories, Inc.
450 William Pitt Way, Bldg. 6
Pittsburgh, PA 15238
STL◄124 (0901)
Client t?,f;;.,
,
Project ;12:,/er TO--R~r
]® /}~/ 4v,<,, Tel(f-hone Number (Area CodeJJFax Number 7'trl7f_;_ /t./lJ......
C;tyCov,u,d lmJ l2
'P~J
Site Contact l .Lab Contact ::",
Project Name and Location (State) Carrier/Wayom Number ~ 13 €:i,f--Z,.J.. 07(,;;J -I-o"tl . 1 ContracVPurchase Order/Ouote No. Containers & Matrix Preservatives ~
" ' l l i\ ~ Sample I.D. No, and Description Date Time " 6 ~1s 1i ~ ~ 0 ~ ' (Containers for each·sample may be combined on one line) ~ 1 t " t~ ~ --,,, ,,, .~
~ /SV-?of' lf /;,/o 3 l}Jfo . --;.
s11;..·•u1 .I. D'tJ'-ID I,
SV-/0 I V or~o
'
Possible Hazard'Jdentifica.fion
D Non.Hazard D Flammable 0 ·skin Irritant D Poison'B
I Sample Disposal ·
r:{' Unknown O Return To Client f.)( Disposal By Lab D Archive For
Turn Around Time Requrred
0 24 Hours D 4B Hours
f. Relinquished B
2. Relinquished
3. Relinquished By
Comments
D 14 Days O 21 Days ~Other 'STlJ.
Oat .Tim
I( il UJ 6W
Da Tune'
Date Time
DISTRIBUTION: WHITE R6tumed to Client wrth Report;· CANARY. Stays Wilh the Sa'mple:. PINK· Field Copy
OC Requtremenls ($peaty)
f,{
2. Recerved By
,
Date Chain of Gus/! a.iii 8 2 <f. JI 6']
Lab Number I I Page of
Analysis (Attach list if
more s ~ace is needed
Special Instructions/
Conditions of Receipt
'
'
,
(A fee may be assessed if samples are retained
Months longer than 1 month)
Date pme
Date-nme
Date Time -f,12-0's () II
THE RETEC . GROUP INC
Client Sample ID: EFP/SV-305
GC/MS Semivolatiles
Let-Sample# ... : C3D120124-001 Work Order# ... , FLTR51AA
Date Received .. : 04/12/03
Analysis Date .. : 04/28/03
Matrix ......... : WATER
Date Sampled ... : 04/11/03
Prep Date ...•.. : 04/16/03
Prep Batch# ... : 3106439
Dilution Factor: 1.06
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Niti:-obenzene-dS
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
MS Run# ....... :
Method ......... : SW846 8270C SIM
REPORTING
RESULT LIMIT UNITS
ND 0.21 ug/L
ND 1.1 ug/L
ND 0 .21 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
79 (30 -121)
63 (11 -119)
65 (39 -115)
73 (37 115)
72 (41 -115)
78 (40 -115)
•
I I ! I
•I
I
I
t I
1
I ~
I
•
•
•
Tl!E RETEC GROUP INC
Client Sample ID: EFF/SV-305
Trace Level Organic Compounds
Lot-Sample# ... : C3Dl20124-001 Work Order# ... : FLTR51AC
Date Received .. : 04/12/03
Analysis Date .. : 04/17/03
Date Sampled ... : 04/11/03
Prep Date ...... : 04/15/03
Prep Batch# ... : 3105613
Dilution Factor: 1
DETECTION
PARAMETER RESULT LIMIT
2,3,7,8-TCDD ND 0.27
PERCENT RECOVERY
INTERNAL STANDARDS RECOVERY LIMITS
13C-2,3,7,8-TCDD 92 . (40 -135)
Matrix ......... : WATER
MS Run # ....•.. :
UNITS METHOD
pg/L SW846 8290
Lot-Sample# ... : C3Dl20124-002
Date Sampled ... : 04/11/03
Prep Date ...... : 04/16/03
Prep Batch# ... : 3106439
Dilution Factor: 0.96
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-dS
Terphenyl-d14
2-Fluorobiphenyl
2-Fluorophenol
Phenol-dS
2,4,6:Tribromophenol
THE RETEC GROUP INC
Client Sample ID: SV-304
GC/MS Semivolatiles
Work Order# ... :· FLTR61AA
Date Received .. : 04/12/03
Analysis Date .. : 04/28/03
Matrix ......... : WATER
MS Run# ....... :
Method ......... : SW846 8270C SIM
REPORTING
RESULT LIMIT UNITS
ND 0.19 ug/L
ND 0.96 ug/L
ND 0.19 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
77 (30 -121)
61 (11 -119)
66 (39 -115)
68 (37 -115)
68 (41 -115)
77 (40 -115)
•
•
I !
,
•
•
•
Lot-Sample# ... , C3Dl20124-003
Date Sampled ... , 04 /11/03
Prep.Date ...... , 04/16/03
Prep Batch# ... , 3106439
Dilution Factor: 4.04
PARAMETER
2,4-Dichloiophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-dS
2,4,6-Tribromophenol
THE RETEC GROUP INC
Client Sample ID, SV-101
GC/MS Semivolatiles
Work Order# ... , FLTR71AA
Date Received,., 04/12/03
Analysis Date .. , 04/28/03
Matrix ........• , WATER
MS Run# ....... ,
Method ......... , SW846 8270C SIM
REPORTING
RESULT LIMIT UNITS
ND 0.81 ug/L
21 4.0 ug/L
ND 0.81 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
71 (30 -121)
62 (11 -119)
60 (39 -115)
70 (37 -115)
67 (41 -115)
79 (40 -115)
METHOD BLANK REPORT
GC/MS Sernivolatiles
Client Lot# ... : C3Dl20124 Work Order# ... : FL29ElAA
MB Lot-Sample ff: C3D160000-439
Analysis Date,.: 04/28/03
Dilution Factor: 1
PARAMETER
2,4~Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-dS
Terphenyl -dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-dS
2,4,6-Tribromophenol
NOTE (S):
Prep Date ...... : 04/16/03
Prep Batch# ... : 3106439
REPORTING
RESULT LIMIT UNITS
ND 0.20 ug/L
ND 1.0 ug/L
ND 0.20 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
82 (30 -121)
62 (11 -119)
64 (39 -115)
74 (37 -115)
74 (41 -115)
85 (40 -115)
Calculations are performed before rounding 10 avoid round-off errors in calculated results.
('
Matrix ......... : WATER
METHOD
SW846 8270C SIM
SW846 8270C SIM
SW846 8270C SIM
•
! I I r I I ' ! ! ; 1 !
I ~ I
I
•
•
•
METHOD BLANK REPORT
Trace.Level organic Compounds
Client Lot# ... : C3Dl20124 Work Order# ... : FL1D21AA
MB Lot-Sample#: G3Dl50000-613
Analysis Date .. , 04/16/03
Dilution Factor: l
PARAMETER
2,3,7,8-TCDD
INTERNAL STANDARDS
13C-2,3,7,8-TCDD
NOTE (S) :
Prep Date ...... : 04/15/03
Prep Batch# ... : 3105613
DETECTION
RESULT LIMIT UNITS
ND 0.27 pg/L
PERCENT RECOVERY
RECOVERY LIMITS
85 (40 -135)
Calculations are performed before rounding to avoid round-off err~rs in calculated results .
\
Matrix ......... : WATER
METHOD
SW846 8290
LABORATORY CONTROL SAMPLE EVALUATION REPORT
GC/MS Semi.volatiles
Client Lot# ... , C3D120124 Work Order# ... , FL29ElAC-LCS
FL29ElAD-LCSD
04/28/03
Matrix ......... , WATER
LCS Lot-Sample#, C3D160000-439
Prep Date ..... ,, 04/16/03 Analysis Date .. ,
Prep Batch# •.. , 3106439
Dilution Factor: 1
PARAMETER
Phenol
Pentachlorophenol
2,4-Dichlorophenol
SURROGATE
Nitrobenzene-d5
Terphenyl-dl4
2~Fluorobiphenyl
2-Fluorophenol
2,4,6-Tribromophenol
NOTE (S) ,
PERCENT
RECOVERY
65
64
65
70
59
65
RECOVERY
LIMITS
(10 131)
(10 131)
(10 -140)
(10 -140)
(42 · · 115)
(42 . 115)
PERCENT
RECOVERY
79
83
56
59
64
67
71
76
71
72
84
87
Calculations are performed before rounding to avoid round-off errors in calculated results.
RPD
RPD LIMITS METHOD
SW846 8270C SIM
1. 7 (0-43 I SW846 8270C SIM
SW846 8270C SIM
6.9 (0-56) SW846 8270C SIM
SW846 8270C SIM
9.2 (0-44) SW846 8270C SIM
RECOVERY
LIMITS
(30 -121)
(30 -121)
(11 . 119)
(11 -119)
(39 -115)
(39 . 115)
(37 -115)
(37 -115)
(41 -115)
(41 -115)
(40 . 115)
(40 -115)
•
•
i e:
•
•
•
LABORATORY CONTROL SAMPLE EVALUATION REPORT
Trace Level Organic Compounds
Client Lot# ... , C3D120124 Work Order# ... , FL1D21AC
LCS Lot-Sample#, G3D150000-613
Prep Date ...... , 04/15/03 Analysis Date .. , 04/16/03
Prep Batch# ... , 3105613
Dilution Factor: 1
PERCENT RECOVERY
PARAMETER RECOVERY LIMITS
2,3,7,8-TCDD 105 (70 -130)
PERCENT
INTERNAL STANDARD ·RECOVERY
13C-2,3,7,8-TCDD 84
NOTE(S),
Calcula~ions are performed before rounding to avoid round-off errors in calculated results.
Bold print denotes control parameters
Matrix ......... , WATER
METHOD
SW846 8290.
RECOVERY
LIMITS
(40 -135)
~ I
I ! I
I
SEVERN •
•
• A part of Severn T~nt pie
STL
ANALYTICAL REPORT
Raleigh, Biweekly NPDES
Lot#, C3D220145
Rita: Bauer
The RETEC Group Inc
SEVERN TRENT ·LABORATORIES, INC.
Veronica Bertot
Project Manager
May 5, 2003
Severn Trent Laboratories, Inc.
STL Pittsburgh • 450 William Pitt Way, Pittsburgh, PA I 5238
Tel [phone] Fax [phone] • www.stJ.inc.com
Sample Receiving:
CASE NARRATIVE
THE RETEC GROUP
Raleigh, Biweekly NPDES
STL Lot# C3Dl20124
STL Pittsburgh, PA received one sample on April 22, 2003 in good condition. The
cooler was received within the proper temperature range
GC/M:S Semivolatiles SIM:
Since insufficient sample volume was received to perform a matrix spike and matrix
spike duplicate, a Laboratory Control Sample (LCS) and Laboratory Control Duplicate
(LCD) were performed. All recoveries were within QC limits.
•
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METHODS SUMMARY
C3D220145
ANALYTICAL PREPARATION
~PARAM==E=•T=E=•Rcc_ ____________________ METHOD ~M=E=T~H=O=D ____ _
8270C (SIM) SW846 8270C SIM ~W846 3520C
References:
SW846 11 Test Methods for Evaluating Solid Waste, .Physical/Chemical
Meth6ds11 , Third Edition, November 1986 and its updates. I I
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WO# SAMPLE# CLIENT SAMPLE ID
FMC29
NOTE(S)
001 EFF/SV-305
SAMPLE SUMMARY
C3D220145
-The analytical ri:sults of the samples listed above are presented on the following pages .
• All ca\Culations are perforined before rounding to avoid round-?ff errors In calculated results.
-Results noted as "ND" WCre not detected at or above the stated limit.
-This rCpon must not be rtproduced, cxc·epc in full, without the wrinen approval of lhe !abo~atory. .
• Results for the following parameters arc never reported on a dry weight basis: coior. corrosivity, density, flashpoint, !gnitabili1y, layers, odor,
paint filter test, pH, porosity pressure, reactiVity, red ox potential, specific gravity, spot tests, solids, rolubllity, temperarure, Viscosity, and weight.
•
•
SAMPLED SAMP
DATE TIME
04/21/03 12,20
•
• • • SEVERN·
.··.TRE.NT°·' STL STL Pittsburgh Chain of
Custody Record Severn Trent Laboratories, Inc. ·
450 William Pitt Way, Bldg. 6
Pittsburgh, PA 15238
STl•412-'• (0901) .
Clisn/ {) O--o;-.U Pro;ect ~ger -~ ls~ oaii;/2 / /o J Chain of Custody Number 183818
Address \ -f\11{, Telephone Number (Area Code)!Fax-Number Lao ivumber. I l '<,oD /50-t'.....r ''.:\'.lb"-37(. Jc':i, .l: Page of
City I Slate I Zip Code Site Contact Lab Contacr Analysis (Attach.fist If
Co----c..o-,--J IMv\ 0l7lfl f more space is needed ·
Project Name and Loc:Jtion (State} CarrierN,!aybi/1 Number. J
'\SE:A:-Z7--01r,,~<J-09 & !l Spedal Instructions/
Contract/Purchase Order/Quote No. Containers & Conditions of Receipt
Matrix Preservatives ~I"'
R.
Sample I. D. No. and Description Date Time I -~ c 8 ' "' &'. ~ i ,,, G 0 ,o
(Contafnem for each sample may bo combined on one tine) I ~ ··• § w ~ ~ ~~ ' ' ,,, ,,, ' ' '
/£,cF /S:.¥-:Jo-. 1(/-.:21/~? /'JU! 7' 1---4 -
"
Possible Hazard Identification f Sample Disposal (A fee may be assessed rrsamples are retained
0 Non-Ha"urd 0Aammable 0 Skin Irritant D Poison_B ~~known □· Returr; To Client tsr;;i;posaf By Lab D Archive For Months longer than I month)
Tum Around Ttme Requ/fed ' QC Reqwemenrs (Specify)
D 24 Hours D 48Hours 0 14-0ays D 21 Days
1. Relinquished By I. Receiv9! By/ . /'.e.,,t.
Dale Time
2. Relinquished By 2. Received By Dale Time
3. Relinquished By Dale Time
'-f Z? O""J lo 3"<J
Comments
DISTR!BUT1ON: WHITE· Returned to Client wfth Report; CANARY· Srays wirh /he Sample; PINK. Reid Copy
Lot-Sample # ... :
Date Sampled ... :
Prep Date ...... :
Prep Batch#.,.:
THE RETEC GROUl' INC
Client Sample ID: EFF/SV-305
GC/MS Sernivolatiles
C3D220145-001
04/21/03
04/25/03
3115312
Work Order# ... : FMC291AA
Date Received .. : 04/22/03
Analysis Date .. : 05/05/03
Matrix ......... : WATER
MS Run# ....... :
Dilution Factor: l Method ......... : SW846 8270C SIM
REPORTING
PARAMETER RESULT LIMIT UNITS
2,4-Dichlorophenol ND. 0. 20 ug/L
Pentachlorophenol ND 1.0 ug/L
Phenol ND 0.20 ug/L
PERCENT RECOVERY
SURROGATE RECOVERY ·LIMITS
Nitrobenzene-dS 71 (30 121)
Terphenyl-dl4 54 (11 -119)
2-FlUorobiphenyl 60 ·. (39 115)
2-Fluorophenol 63 (37 115)
Phenol-d5 65 (41 115)
2,4,6-Tribrom6Phenol 67 (40 -115)
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METHOD BLANK REPORT
GC/MS Semivolatiles
Client Lot jf ... , C3D220145 Work Order # .•. , FMKTDlAA
MB Lot-Sample#, C3D250000-312
Analysis Date .. , 05/05/03
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
PentachloroPhenol
Phenol
SURROGATE.
Nitrobenzene-dS
Terphenyl-dl4
2-FluorobiphenYl
2-Fluorophenol
Phenol-d5
2,4;6-Tribromophenol
NOTE(S),
P·rep Date ...... , 04/25/03
Prep Batch# ... , 3115312
REPORTING
RESULT LIMIT
ND 0.20
ND 1.0
ND 0.20
PERCENT RECOVERY
RECOVERY LIMITS
69 (30 121)
54 Ill 119)
59 (39 115)
63 (37 -ll5)
63 (41 -115)
69 (40 115)
Calculations are performed hefore rounding co avoid round•off errors in ca!culatcd resullS .
UNITS
ug/L
ug/L
ug/L
Matrix ....... · .. , WATER
METHOD
SW846 8270C SIM
SWS46 8270C SIM
SW846 8270C SIM
LABORATORY CQNTROL SAMPLE EVALUATION REPORT
GC/MS Semivolatiles
Client Lot #· ... , C3D220145 Work Order# ... , FMKTDlAC-LCS
FMKTDlAD-LCSD
Analysis Date .. , 05/05/03
Matrix ......... : WATER
LCS Lot-Sample#, C3D250000-312
Prep Date ...... , 04/25/03
Prep Batch# ... , 3115312
Dilution Factor: 1
PARAMETER
Phenol
Pentachlorophenol
2,4-Dichlorophenol
SURROGATE
Nitrobenzene-dS
Terphenyl-dl.4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribrom6phenol
NOTE (S) :
PERCENT
RECOVERY
61
60
56
55
61
61
RECOVERY
LIMITS
(10 -131)
(10 131)
(10 -140)
(10 140)
(42 -115)
(42 115)
PERCENT
RECOVERY
79
78
54
53
66
65
72
68
69
65
83
83
Calculations ~e perfonncd before rounding to avoid iound-off errors in calculated re5u!ts.
RPD
RPD LIMITS METHOD
SW846 8270C SIM
1. 7 (0-43) SW846 8270C SIM
SW846 8270C SIM
0.72 (0-56) SW846 8270C ·srn
SW846 8270C SIM
0.76 ( 0-44) SW846 8270C SIM
RECOVERY
LIMITS
(30 -121)
(30 -121)
(11 -119)
(11 -119)
(39 -115)
(39 -115)
(3 7 -115)
(37 -115)
(41 -115)
(41 -115)
(40 -115)
(40 -115)
•
•
••
•
-
o ?0-1 -ooeeo<~
A 'r.f!)¥:nt To~lty ~~p9.rt AT-1 Form Chro._n_ ic P_ass/Fail and Acute LC50 ace na1y LIC8J .· .... Date 41ZQ@QP3
Pace Analytical Ssrvlcss, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
www.pacslsbs.com Fax: [phone]
aci!lt : Beazer NPll\~$1/NC Admin.Letter Pipe # __ E_ff_
County Wake
Laboratory Performing Test PACE Ana\;hfoa.1 Services, Inc. .• ,<..:. Comme:nl..s:
. Envlrorvnental Sciences Branch
Div. or Water Quality Cb[o□lc Test Besul!s
MA.IL ORIGINAL TO: N.C, DENR Calculated t 0.781
1621 Mall Service Contor
Ralelgh, NC 27699-1621 Tabular t 2.581
No[lb Car~l!iia· Cerioda(].hnia Chronic Pa"ss/Fa!I Rei:i:roductloo Toxicity Test % Reduction 2.4
CON[R0L ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 12
I I I I
#-¥e . d·· :.1-~3-·-s-t--s' ~--30-··29 l-7t, 30·· 1--29 % Mortality ContrOI Avg. Reprod. Centro ,,
Adult /Uive (D)ead L L L L L L L L L L L L 0.00 29.60
Treatment 2 11eatment 2
Effluent% 190.0% I 0.00 26.90
Control CV
TREATMENT 2 ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 12 m PASS FNL
# Youna Produced 29 30 27 32 29 29 28 29
¾central organisms GJ C 29 24 32 ""'"""'~ Check One
Adult (L)lve (D)ead L L L L K L L L L L L L 100.0
TC$l Start Date
1st 1st 2nd Complete This For Either Test 4/9/2003
pH Control ~ ~ ~ Co!J1ctlo[! Start Call
Sample Sa~le
Treatment 7.5 7.4 7 4 I 4/8/2003 2 4/10/2003
' E s E 5 E
' " ' " ' " • ' • ' • ., Grab Comp. Oorauon ' ' ' Sample' ... ·,·-.-~ SI~
I ' ' ' ~-~4. 1 li' I I .
... ·-.. ····-, ... . .
' m &m Sample ,-.. ... ----· i ~i 1st 1st 2nd 2 ' X 2,14 .. ... . ... . -o.e. Oonnol I 0.2 , 7.9 I
a:2 : o:s 7:9
18~+;!1--~-
r---• ,Ao 4:t-·---
Treatment 0.5 8.1 Spoc. Con~. (umhoo 145 '" '"
Chturlno {rno,1J 0.00 0.00
I...C~C~l!le Io~jctl)'. I~sl Sampla li!!mp. ol rece)pt"C 1.2 1.0
(MOit.iil)' expreasea .. 'Mi, ODRID.trmg replleatol} •
l I I I I I I I I I Concentration NOl8: Please Complete
This Sec:llon also
Mortality
LCS0= ___ % Method of Determination
95% Confidence
• %-%
Movtng Avg. Problt
start/and start/end
[ Jbo,:;•certL,t~s
P TN Drinking Water 80
SC Environmental 99030
EB7648
H~l!JHIS.LL!d ~ Sd0N0J J!I.L3li 8tt11L£8L6 YV~ £]:80 £00Z/90/£0
-
<?.t.TEC
P1.ece.'1vr;d
M~1 -· s ·mo3L
<' c·oi· _,.. r~Y.',) .~.._ .. ...,, Prepared for -
Ms. Rita Bauer
TRITEST, INC.
3909 Beryl Road
Raleigh, NC 27607
Telephone: [phone]
Fax: ( 19) 834-6497
borat ry Report•
NC/WW Cert.#: 087
NC/OW Cert.#: 3773'/
1 of 1
THERMORETEC CONSUL TING CORP.
300 Baker Ave.
Report Date: 4/25/2003
ate Recejved: 418/2003
! SUITE 302
CONCORD, MA 01742 ork Order #: 0304-00603
Project ID: 01 RE1422
Project ID: Acute Bloassay NEEDS REPORT BY 10TH
No. Sample ID Date Samplec Time Sample, Matrix Condition
001 Wastewater 4/9/2003 09:00 WW 4ii20C
Test Performed Method Results Analyzed Qualifier
Bloassay, Acute Pass/Fail NC Pass/Fail SEE ATTACHED# 4/20/03
No. Sample ID Date Sample< Time Sample, Matrix Condition
002 Wastewater 4111/2003 09:00 WW 4ii2roC
Test Performed Method Results Analyzed Qualifier
Bloassay, Acute Pass/Fall NC Pass/Fall SEE ATTACHED# 4/20103
#ANAL VZED BY PACE ANALYTICAL SERVICES, INC., ASHEVILLE, NC.
Report Certified by:
~~
for Tritest, Inc.
ZOOll'i H~llflHSJ..Lld ~ SdO!IIO:> :l!LL!lll 8ttTTLC8L6 xv~ t1:so COOZ/90/90
•
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...
C
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Sil
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0 i§ u
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.--; .--;
t---., .,
t---
0,
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0
0 "' ' "' 0
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• •
AQUATIC, OXICOLOGY LABORATORY
CHAIN-OF-CUS ODY AND FIELD ANALYSIS FORM
1 .. -,~ .. ~-,=
351 Dl!potstreet
Asfffile, NC 28801
\ _ PURCHASE ORDER#: Phone; [phone]
r ~~g~+~~:;;m;,=..D.e~£L~"'+--------/;;,c;;";'c,.T,,------------i Fax: [phone]
t~~~P~D~ES~!,p:::,~~IT,~,:--,-----;\..ilW--;;;::-,,--,-------f~a,~i,Aa,Ta'~,i---;L-/"Pa;l~P~E•#":-E,...i,:,
;
:
-
-
-
-
-
-
-
-
j

JFOR1,1ATION ON THIS FORM IS REOUIRED
) BY STATE AND FEDERALAGENOES.
TEST REQUIREMENTS (Please"""'.,. · te test twe. m1d spede5 n,~red.)
@ 48 96 hours Tes;~ cn:ll!D-.e apprtip1111te1est =~~ca,~
Full Range. OuflnltiVG, clluenns -t--,-----------
0\her, ,p,,dr,c -----+---------
SAMPLE TYPE
Gmbsam
Date:
REMARKS
5AMPLE CUSTODY
c:
~'f"""'
Cwicdaphnfu dubia (Water ~ea)
Pimephafes prome/as (Fathead minnow}
Diaphnia pufex · )
Gyprlnodon Variegalus {She~pshead minnow)
Monidia betyflina (Inland sii+raide}
Mysidopsis bahia {Mysid shrJmp)
Other, speclry: -----j-----------~
al, at weir. efTuerrt outfall. etc.)
Number of containers filled for testing:
Total residual chlorine {mg/L):
Temperature at time of collection C):
Method oftransportto ETS:
Nate: Rlns• containers: wtth Iha sample b•lol timryg. Pack r.vnplo In loose Ice.
Smnples mtr.r1 be received .t ETS 111. or ~elow Al"'C. Sample i,houli:I not be fruv!!n.
FOR OFRCE USE ONLY PROJECT#;
CLIENT ID#: SAMPLE#:
Re/In=~ AJJ':if/1 _ _ Received~ ,
.... I ~ ..... ---=""JH_"1
_1 _._~~-.JJ/~__._-..,,.""=""",..._.l 1~;2 I~ 11 I t!ti~,4
Relinquished m ETS by: :r: Received et ETS by: I
I '"" I L ~~~me I e,m i "-~ I o.~aoTI,c I
! sample temperature upon receipt at ETS (0 CJ: LI ____ _,
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April 8, 2003
Ms. IJeverly Hudson
Remedial Project Manager
U.S. EPA -Region IV, I Ith Floor
North Site Management Branch
61 Forsyth Street, SW
Atlanta, GA 30303
RE: Monthly Progress Report # 119
Remedial Action
Koppers Site -Morrisville, North Carolina
Dear Ms. Hudson:
•
In accordance with the Unilateral Order, and on behalf of Beazer East, Inc. (Beazer), please find attached
four (4) copies of the March Monthly Progress Report for Remedial Action at the Koppers Superfund Site
in Morrisville, North Carolina. No exceedances occurred during this event.
Should you need additional information regarding this progress report, please call Mike Helbling at
[phone]w me at [phone].
Sincerdy,
The RETEC Group, Inc.
'fl~~
Rita Bauer
Project Geologist
Enclosure
cc: D. Mattison -NC Superfund (2 copies)
L. Faulconer -Wake County
G. Caskey -En wood Structures
M. Helbling -Beazer
D. Hails-EAP Industries, Inc.
J. Garrett• NC Division of Water Quality
M. Matthews -NC Division of Water Quality
P. Kilchenstein · RETEC
•
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• •
MONTHLY PROGRESS REPORT#l19
REMEDIAL ACTION
SITE NAME: Koppers Superfund Site
Beazer East, Inc.
Morrisville, NC
USEPA DOCKET NUMBERS: 93-09-C
PERIOD ENDING: March 31, 2003
I. PROGRESS MADE THIS MONTH
2.
3.
4.
5.
6.
7.
Remedial Action (RA) -HABITAT MITIGATION. No activities were conducted this
month.
Remedial Action (RA) -GROUNDWATER TREATilfENT. The treatment system
operated throughout the month without upset. System performance was monitored on a
biweekly basis. Approximately 38,760 gallons of groundwater were extracted, treated in
the treatment plant, and discharged between March 1, 2003 and March 31, 2003. System
water samples were collected on March 14 and March 24, 2003 in accordance with the
sampling schedule in the O&M manual. Samples were submitted to Severn Trent
Laboratories, Inc. for laboratory analysis. The operations and sampling programs are
summarized on the attached Table I.
Remedial Action (RA) -EFFECTIVENESS 11-lONITORING PROGRAM. No activities
were conducted this month.
Remedial Action (RA) -CORRESPONDENCE. None.
PROBLEMS RESOLVED None.
PROBLEMS ANTICIPATED None.
UPCOMING EVENTS Continue System O&M.
PERSONNEL CHANGES None.
SUBCONTRACTORS None.
ANALYTICAL DATA Analytical data from system influent and effluent
sampling received during this period are enclosed and arc summarized on Table 2 .
C:\Documcn1s and Settings~anzur\My Documents\Rnys PDl:\March 2003 Progress Reports\0JM-03.doc
•
Date Systems Cumulative SV-101 SV-101
Check Effluent Flow Sample Sample
{yes/no) (Gallons) {yesJno) ·parameters
•
Table 1
Groundwater Treatment Operations and Sampling Program Summary
Koppers Superfund Site
Morrisville, North Carolina
March 2003
Associated SV-304 SV-304 Associated
Group Sample Sample Group
(yes/no) Parameters
•
SV-305 SV-305
Sample Sample
(yes/no) Parameters
01/15/03 ves 3,715,610 ves Penta. 2,4-0ichloro, Phenol, Dioxin 1,2 ves Penta, 2.4-Dichloro, Phenol 1 "eS Penta. 2,4-Dichloro, Phenol, Dioxin
01/28/03 yes 3,733,790 oo
02/11/03 ves 3,753,160 00
02/28/03 ves 3,779,540 no
03/14/03 yes 3,800,330 no
03/24/03 yes 3,818,300 00
Notes:
Sampling point SV-101 is located before the Carbon Units (pretreatment)
Sampling point SV-304 is located between the Carbon Units
Sampling point SV-305 is lactated after the Carbons Units (post-treatment)
F:\Proj&cts\03624\Reports\Monthlyl03M--03 fable 1.xls
no
00
no
no
oo
Associated Groups:
SV-101 . Group 1 is penta and 2,4-dichlorophenol; Group 2 is dioxin
SV-304 • Group 1 is penta and 2,4-dichlorophenol
yes Penta, 2,4-Dichloro, Phenol, Chronic Tax
"eS Penta, 2,4-Dich!oro, Phenol
yes Penta, 2,4-Dichloro, Phenol
ves Penta, 2,4-Dichloro, Phenol
ves Penta, 2,4-Dichloro, Phenol
SV-305 -Group 1 is penta, phenol, and 2,4-dichlorophenol: Group 2 is dioxin and Group 3 is chronic toxicity
Associated
Group
1,2
1,3
1
1
1
1
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•
• Table 2 • Groundwater Treatment Analytical Data Summary
Koppers Superfund Site -Morrisville, North Carolina
March 2003
Analytical
Parameter Date Sample Sample
Sample Location Location
Collected SV-101
Pentachlorophenol 01/15/03 17
01/28/03
02/11/03
02/28/03
03/14/03
03/24/03
2.4-Dichlorophenol 01/15/03 <0.19
01/28/03
02/11/03
02/28/03
03/14/03
03/24/03
Phenol 01/15/03 <0.19
01/28/03
02/11/03
02/28/03
03/14/03
03/24/03
Chronic Toxicity 01/28/03
Dioxin (2,3,7,8-TCDD) 01/15/03 <0.22
Notes: All results are in micrograms per liter (µg/L) except dioxin. Dioxin data is in picograms per liter (pg/L).
SV-101 -Before Carbon Units
*SV-304 -Between Carbon Units
"*SV-305 -After Carbon Units
F:1Projects\03624\Reports\Monthly\03M-03 Table 2.xls
SV-304*
<1.0
<0.20
<0.20
Sample
Location
SV-305**
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<0.21
<0.20
<0.20
<0.20
<0.20
<0.20
<0.21
<0.20
<0.20
<0.20
<0.20
<0.20
Pass
<0.28
SEVERN
•
•
•
A part of Severn Tre11t pie
• STL
ANALYTICAL REPORT
Raleigh, Biweekly NPDES
Lot Jt, C3Cl.50l.42
Rita Bauer
The RETEC Group Inc
•
SEVERN TRENT LABORATORIES, INC.
Veronica Bortot
Project Manager
March 25, 2003
Severn Trent Laboratories, Inc.
STL Pittsburgh • 450 William Pitt Way, Pittsburgh, PA 15238
Tel [phone] Fax [phone] • www.st/;nc.com
• CASE NARRATIVE
THE RETEC GROUP
Raleigh, Biweekly NPDES
SIL Lot# C3C150142
•
Sample Receiving:
SIL Pittsburgh, PA received one sample on March 15, 2003 in good condition.
cooler was received within the proper temperature range
The
GC/MS Semivolatiles SIM:
Since insufficient sample volume was received to perform a matrix spike and matrix
spike duplicate, a Laboratory Control Sample (LCS) and Laboratory Control Duplicate
(LCD) were performed. All recoveries were within QC limits.
•
•
•
•
•
•
• • METHODS SUMMARY
C3C150l.42
ANALYTICAL PREPARATION
PARAMETER METHOD ~M=E~TH=O~D~----
8270C (SIM) SW846 8270C SIM SW846 3520C
References:
SW846 "Test Methods for Evaluating Solid Waste, Physical/Chemical
Methods 11 1 Third Edition, November 1986 and its updates .
• •
SAMPLE SUMMARY
C3C150142
WO# SAMPLE# CLIENT SAMPLE ID
FJBC2 001 EFF/SV-305
NOTE(S):
-The analyticil rcsulis of the samples liSted above are presented on the fo!low!ng pages.
• ~II calculations are performed before rounding to avoid rollnd-off errors in calculated resulls.
-Results noted as "ND" were not detected at or above the stated limit.
-This report must not be reproduced, except in full, without the written approval of the laboratory.
-ResullS for the following parameters are never reported on a dry weight basis: color, corrosivity, density, flashpoint, ignitability, layers, odor,
paint filter test, pH, porosity pressure, reactivity, red ox potential, specific gravity, spot tests, solids, solubility, temperature, viscosity, and weight.
•
SAMPLED SAMP
DATE TIME ----
03/14/03 09: 20
•
•
• • Chain of Custody Record PA 000365 -
Project Name: ·1< ~,. :"? , 'r'J. O,,_ \. Project Number, 'Gf:1\-"'t·f-()3&),f-cf/G
Send Report To: 0 :: +c,... J ~,,.,,,..,.,,,-Sampler (Print Name), J+C,..;{'t:I"'-\J.-•\\
Address, tOD 13,J.l~,.,-.4-J-c Sampler (Print Name): ----
( J'"1V'-LO\/'J N/'1 017'-fl Shipment Method: h,J ()(
Airbill Number, 9"3 <-{ O 3~ !? 'j'{ { (,,q
Phone: 91i-111-1~)a. Laboratory Receiving: 57L ));"~-
Fax:
Field Sample IO Sample Sample Sample Number of
Date Time Matrix Containers
~FF "5v,,os-1\ 1-.I 01 01do tJ Q ,
•
" .;;, ,I s '1'
ThermoRetec Corporation
3040 William Pitt Way• Pittsburgh, PA 15238-1359
[phone] Phone • [phone] Fax
WWW thermoretec.com
,l
"' l~ 4~
~~ !~~
"'
Smart Solutions. Positive Outcomes.
Pag,_[of_j_
Purchase-
Order#·
I Comments, Special Lllb Sample ID
Instructions, etc. (to be completed by lab)
Relinqut ::r natu
V ReceitJ «"~) 1;r;io, Time: Sample Custodian Remarks (Completed By laboratory):
~1 hct> QA/QC level 1urnaround Sample Receipt r<-V
Relinquished by: (Signature) Received by: (Signature) Date: Time: Total# Containers Received?
Level I □ Routine □ COC Seats Present?
Level II □ 24 Hour □ CDC Seals Intact?
Relinquished by: (Signature) Receive:;r: {5_7ru7' Oate: Time: Level II] □ 1 Week □ Received Containers Intact? ···--. 7.,/~-o) !)9]c v-fl_.A Other □ Other __ Temperature?
White: lab Copy Yellow: PM Copy Pink: Field Copy Gold, P1'!'/QA/QC Copy
•
THE RETEC GROUP INC
Client Sample ID: EFF/SV-305
GC/MS Semivolatiles
•
Lot-Sample# ... : C3C150142-001 Work Order# ... : FJ8C21AA
Date Received .. : 03/15/03
Analysis Date .. : 03/21/03
Matrix ......... : WATER
Date Sampled ... : 03/14/03
Prep Date ...... : 03/19/03
Prep Batch# ... : 3078201
Dilution Factor: 1.02
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-d5
Terphenyl-d14
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
MS Run# ....... :
Method ......... : SW846 8270C SIM
REPORTING
RESULT LIMIT UNITS
ND 0.20 ug/L
ND 1.0 ug/L
ND 0.20 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
65 (30 -121)
63 (11 -119)
71 (39 -115)
60 (37 -115)
62 (41 -115)
72 (40 -115)
•
•
•
•
• METHOD BLANK REPORT
GC/MS Semivolatiles
Client Lot# ... : C3C150142 Work Order# ... : FKDHDlAA
MB Lot-Sample#: C3C190000-201
Analysis Date .. : 03/21/03
DilutiOn Factor: 1
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-dS
Terphenyl-d14
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
OTE (S) :
Prep Date ...... : 03/19/03
Prep Batch# ... : 3078201
REPORTING
RESULT LIMIT
ND 0.20
ND 1.0
ND 0.20
PERCENT RECOVERY
RECOVERY LIMITS
72 (30 -121)
77 (11 119)
73 (39 -115)
75 (37 -115)
80 (41 -115)
84 (40 -115)
a\culations are perfonned before rounding to avoid round-off errors in calculated results .
•
•
Matrix ......... : WATER
UNITS METHOD
ug/L SW846 8270C SIM
ug/L SW846 8270C SIM
ug/L SW846 8270C SIM
• •
LABORATORY CONTROL SAMPLE EVALUATION REPORT
GC/MS Semivolatiles
Client Lot# ... : C3Cl50142 Work Order# ... : FKDHDlAC-LCS
FKDHDlAD-LCSD
Analysis Date .. : 03/21/03
Matrix ......... : WATER
LCS Lot-Sample#: C3C190000-201
Prep Date ...... : 03/19/03
Prep Batch# ... : 3078201
Dilution Factor: 1
PARAMETER
Phenol
Pentachlorophenol
2,4-Dichlorophenol
SURROGATE
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-dS
2,4,6-Tribromophenol
NOTE(S):
PERCENT
RECOVERY
57
56
88
92
60
62
RECOVERY
LIMITS
(10 -131)
(10 -131)
(10 -140)
(10 -140)
(42 -115)
( 42 -115)
PERCENT
RECOVERY
62
64
48
so
59
61
54
56
56
so
60
63
Calculations are pi::rformed before rounding to avoid round-off errors in calculated results.
RPD
RPD LIMITS METHOD
SW846 8270C SIM
0.95 (0-43) SW846 8270C SIM
SW846 8270C SIM
4.7 (0-56) SW846 8270C SIM
SW846 8270C SIM
2.8 (0-44) SW846 8270C SIM
RECOVERY
LIMITS
(30 -121)
(30 -121)
(11 -119)
(11 -119)
(39 -115)
(39 -115)
(37 -115)
(37 -115)
(41 -115)
(41 -115)
(40 -115)
(40 -115)
•
•
•
SEVERN
•
•
•
A part of Severo Trent pie
sf1 •
ANALYTICAL REPORT
Raleigh, Biweekly NPDES
Lot#: C3C250225
Rita Bauer
The RETEC Group Inc
SEVERN TRENT LABORATORIES, INC.
Veronica Bortot
Project Manager
April 2, 2003
Severn Trent Laboratories, Inc.
STL Pittsburgh • 450 William Pitt Way, Pittsburgh, PA 15238
Tel [phone] Fax [phone] • www.stl-inc.com
•
Sample Receiving:
CASE NARRATIVE
THE RETEC GROUP
Raleigh, Biweekly NPDES
STL Lot# C3C250225
•
STL Pittsburgh, PA received one sample on March 25, 2003 in good condition.
cooler was received within the proper temperature range
GC/MS Semivolatiles SIM:
The
Since insufficient sample volume was received to perform a matrix spike and matrix
spike duplicate, a Laboratory Control Sample (LCS) and Laboratory Control Duplicate
(LCD) were performed. All recoveries were within QC limits.
The reporting limits were adjusted according to the amount of sample extracted.
•
•
•
•
•
•
• • METHODS SUMMARY
C3C250225
ANALYTICAL PREPARATION
PARAMETER METHOD METHOD ----------------------------------
8270C (SIM) SW846 8270C SIM SW846 3520C
References:
SW846 "Test Methods for Evaluating Solid Waste, Physical/Chemical
Methods,,, Third Edition, November 1986 and its updates .
• •
SAMPLE SUMMARY
C3C250225
WO# SAMPLE# CLIENT SAMPLE ID
FKPMX 001 EFF/SV-305
NOTE{S):
" The analytical results of the samples listed above are presented on the following pages.
-All calculations are performed before rounding to avoid round-off errors in calculated results.
-Results ncitcd as "ND" were not detected at or above the stated limit.
-Tiiis report must not be reproduced, except in full, without the written approval of the laboratory.
-Results for the following parameters are never reported On a dry weight basis: color, corrosivity, density, flashjioint, ignitability, layers, odor,
paint filter ,est, pH, porosity pressure, reactivity, redox potential, specific gravity, spot lests, solids, solubility, temperature, viscosity, and weight.
SAMPLllD
DATE
•
SAMP
TIME
03/24/03 10:20
•
•
~W tNULAND TESTING LABORATORY, INC . 9 Douglas A venue · .
North Providence, RI 02904 • •
CHAIN OF CUSTODY RECORD PHOJ. NO. PROJECT NAME~% ~03G~. '-I -0 '1 & t
CLIENT I NO. jf Y\ffi '&.:z.,UJ ~ I;.,_
OF ,,
j CON• (J
C G TAINERS SAMPLE DATE TIME 0 R STATION LOCATION , REMARKS I.D. M A
'
p 8
i,,l'.:).,b )O)o ' "X. J:ff'!~v-105 ~ " . • '
•
Re~uished ~:]atu,e) 3b vl·~·r I~ ifD
Received by: (Signature) Relinquished by: (Signature) Date/Time Received by: (Signature)
Kr,k;,<. I Relinquished by: (Signature) Date/Time Received bY: (Signature) Relinquished by: (Signature) Date/Time Received by: (Signaturo) I I Relinquished by: (Signature) Dale/Time R:,:z:::J.', for Leborafo~ Date/Time Remarks
\
~s· ,,, -;;( ~J ... /(!}i'>I ~/., ,·.
• •
TIIE RETEC GROUP INC
Client Sample ID: EFF/SV-305
GC/MS Semivolatiles
Lot-Sample# ... : C3C250225-001 Work Order# ... : FKPMXlAA
Date Received .. : 03/25/03
Analysis Date .. : 04/01/03
Matrix ......... : WATER
Date Sampled ... : 03/24/03
Prep Date ...... : 03/27/03
Prep Batch# ... : 3086336
Dilution Factor: 1.01
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-d5
Terphenyl~dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-dS
2,4,6-Tribromophenol
MS Run# ....... :
Method ......... : SW846 8270C SIM
REPORTING
RESULT LIMIT UNITS
ND 0.20 ug/L
ND 1.0 ug/L
ND 0.20 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
58 (30 -121)
68 (11 -119)
64 (39 -115)
57 (37 -115)
62 (41 -115)
78 (40 -115)
•
•
•
• •
• METHOD BLANK REPORT
GC/MS Semivolatiles
Client Lot# ... : C3C250225 Work Order# ... : FKVN71AA
MB Lot-Sample#: C3C270000-336
Analysis Date .. : 04/01/03
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-dS
Terphenyl-d14
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
TE (SJ :
Prep Date ... _._: 03/27 /03
Prep Batch# ... : 3086336
REPORTING
RESULT LIMIT
ND 0.20
ND 1.0
ND 0.20
PERCENT RECOVERY
RECOVERY LIMITS
72 (30 -121)
68 (11 -119)
74 (39 -115)
81 (37 -115)
79 (41 -115)
76 (40 -115)
culalions are performed before rounding to avoid round-off errors in calculated results .
•
UNITS
ug/L
ug/L
ug/L
Matrix ......... : WATER
METHOD
SW846 8270C SIM
SW846 8270C SIM
SW846 8270C SIM
• •
LABORATORY CONTROL SAMPLE EVALUATION REPORT
GC/MS Semivolatiles
Client Lot# ... : C3C250225 Work Order# ... : FKVN71AC-LCS
FKVN71AD-LCSD
Analysis Date .. : 04/01/03
Matrix ......... : WATER
LCS Lot-Sample#: C3C270000-336
Prep Date ...... : 03/27/03
Prep Batch# ... : 3086336
Dilution Factor: 1
PERCENT RECOVERY RPD
PARAMETER RECOVERY LIMITS RPD LIMITS METHOD
Phenol 55 (10 -131) SW846 8270C SIM
55 (10 -131) 0. 56 (0-43) SW846 8270C SIM
Pentachlorophenol 68 (10 -140) SW846 8270C SIM
71 (10 -140) 4.3 (0-56) SW846 8270C SIM
2,4-Dichlorophenol 61 (42 -115) SW846 8270C SIM
63 (42 -115) 2.1 (0-44) SW846 8270C SIM
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Nitrobenzene-dS 52 (30 -121)
55 (30 -121)
Terphenyl-dl4 63 (11 -119)
64 (11 -119)
2-Fluorobiphenyl 67 ( 39 -115)
69 (39 -115)
2-Fluorophenol 61 (37 -115)
61 (37 -115)
Phenol-d5 58 (41 -115)
61 (41 -115)
2,4,6-Tribrornophenol 81 (40 -115)
81 (40 -115)
NOTE (S) :
Calculations are performed before rounding to avoid round-off errors in calculated results.
•
•
•
•
•
•
II. A"...,--1..., 1 f\ '"IAf'\"!: "'"'-''-'" , v, ,:.,,vv_,
Ms. Beverly Hudson
Remedial Project Manager
U.S. EPA -Region fV, 11th Floor
North Site Management Branch
61 Forsyth Street, SW
Atlanta, GA 30303
RE: Monthly Progress Report #118
Remedial Action
Koppers Site -Morrisville, North Carolina
Dear Ms. Hudson:
In accordance with the Unilateral Order, and on behalf of Beazer East, Inc. (Beazer), please find attached
four (4) copies of the Febrnary Monthly Progress Report for Remedial Action at the Koppers Superfund
Site in Morrisville, North Carolina. No exceedances occurred during this event.
We are also enclosing the January 2003 chronic toxicity analytical data, which was not included with the
January 2003 progress report due to severe weather conditions delaying the sampling event and
subsequent laboratory analytical report.
Should you need additional information regarding this progress report, please call Mike Helbling at
( 412) 208-8858 or me at [phone].
Sincerely,
The RETEC Group, Inc. ~. Tu //(, ....... --· \ ( ,, t· /---~/4-1./2 -j,J»_,_y__,A~
. Rita Bauer 1
Project Geologist
CK:pb
Enclosure
cc: 0. Mattison -NC Superfund (2 copies)
L. Faulconer -Wake County
G. Caskey -Enwood Structures
M. Helbling -Beazer
D. Hails -EAP Industries, Inc.
J. Garrett-NC Division of Water Quality
M. Matthews -NC Division of Water Quality
P. Kilchenstein -RETEC
F :\ US E RS\C Karman\ D ca.zcr\ NP DE S\O 3 624-Rn.lci gb \R 1!ports\fvt on thl y\02 M -03 . doc
•
•
•
MONTHLY PROGRESS REPORT #118
REMEDIAL ACTION
SITE NAME: Koppers Superfund Site
Beazer East, Inc.
Morrisville, NC
USEP A DOCKET NUMBERS: 93-09-C
PERIOD ENDING: February 28, 2003
1. PROGRESS MADE THIS MONTH
2.
3.
4.
5.
6.
7.
Remedial Action (RA) -HABITAT MITIGATION. No activities were conducted this
month.
Remedial Action (RA) -GROUNDWATER TREATMENT. The treatment system
operated throughout the month without upset. . System performance was monitored on a
biweekly basis. Approximately 45,750 gallons of groundwater were extracted, treated in
the treatment plant, and discharged between January 28, 2003 and February 28, 2003.
System water samples were collected on February 11 and February 28, 2003 in
accordance with the sampling schedule in the O&M manual. Samples were submitted to
Severn Trent Laboratories, Inc. and Tritest, Inc. for laboratory analysis. The operations ·
and sampling programs are summarized on the attached Table I.
Remedial Action (RA) -EFFECTIVENESS MONITORING PROGRAM. No activities
were conducted this month.
Remedial Action (RA) -CORRESPONDENCE. None.
PROBLEMS }U:SOL VED
PROBLEMS ANTICIPATED
UPCOMING EVENTS
PERSONNEL CHANGES
SUBCONTRACTORS
None.
None.
Continue System O&M.
None.
None.
ANALYTICAL DATA Analytical data from system influent and effluent
sampling received during this period are enclosed and are summarized on Table 2 .
F: \USE RS\C Kannan \Beazer\N PD ES\03 62 4-Rale i gh\Reports\M on thl y\02 M-03 . doc
•
Date Systems Cumulative SV-101 SV-101
Check Effluent Flow Sample Sample
(yes/no) (Gallons} (yes/no) Parameters
•
Table 1
Groundwater Treatment Operations and Sampling Program Summary
Koppers Superfund Site
Morrisville, North Carolina
February 2003
Associated SV-304 SV-304 Associated
Group Sample Sample Group
(yes/no) Parameters
•
SV-305 SV-305
Sample Sample
(yes/no) Parameters
01/15/03 ves 3 715 610 ves Penta, 2.4-Dichtoro, Phenol, Dioxin 1 2 ves Penta, 2,4-Dichloro Phenol 1 ves Penta 2,4-0ichloro. Phenol Oioxir.
01/28/03 ves 3,733,790 no
02/11/03 ves 3 753,160 no
02/28/03 ves 3 779,540 no
Notes:
Sampling point SV-101 is located before the Carbon Units {pretreatment)
Sampling point SV-304 is located between the Carbon Units
Sampling point SV-305 is lactated after the Carbons Units {post-treatment)
F:\Projects\0362,IRepor1$\Monthly\02M-03 Table 1 di
no
no
no
Associated Groups:
SV-101 -Group 1 is penta and 2,4-dich!orophenol; Group 2 is dioxin
SV-304 -Group 1 is penta and 2,4-dichlorophenol
ves
yes
yes
Penta, 2,4-0ichloro, Phenol, Chronic Tax
Penta 2.4-0ichloro Phenol
Penta 2 4-Dichloro, Phenol
SV-305 -Group 1 is penta, phenol, and 2,4-dichlorophenol; Group 2 is dioxin and Group 3 is chronic toxicity
Associated
Group
1,2
1,3
1
1
•
Table 2
Groundwater Treatment Analytical Data Summary
Koppers Superfund Site -Morrisville, North Carolina
February 2003
Analytical
Parameter Date Sample Sample
Sample Location Location
Collected SV-101 SV-304*
Pentachlorophenol 01/15/03 17 <1.0
01/28/03
02/11/03
02/28/03
2.4-Dichlorophenol 01/15/03 <0.19 <0.20
01/28/03
02/11 /03
02/28/03
Phenol 01/15/03 <0.19 <0.20
01/28/03
02/11/03
02/28/03
Chronic Toxicity 01/28/03
Dioxin (2,3,7,8-TCDD) 01/15/03 <0.22
Notes: All results are in micrograms per liter (µg/L) except dioxin. Dioxin data is in picograms per liter (pg/L).
SV-101 -Before Carbon Units
*SV-304 -Between Carbon Units
• ··sV-305 -After Carbon Units
•
F:\Projects\03624\Reports\Monthly\02M-03 Table 2.xls
Sample
Location
SV-305*'
<1.0
<1.0
<1.0
<1.0
<0.21
<0.20
<0.20
<0.20
<0.21
<0.20
<0.20
<0.20
Pass
<0.28
•
•
• A Dart ot Severo !rent Ole
STL
ANALYTICAL REPORT
PROJECT NO. BEAZER
Raleigh, NPDES
Lot~' C3Bi20243
Gregory MalZoile
The RETEC Group IriC
SEVERN TRENT IJ\BOMTORIES, INC.
Veronica BortOt
Project Manager
February 20, 2003
Severn Trent labora.tories, Inc. sn Pittsburgh• 450 William Pitt Way, Pittsburgh, PA 15238
Tel [phone] Fax [phone] • www.stl-inc.com
•
•
•
CASE NARRATIVE
THE RETEC GROUP
Raleigh, Biweekly NPDES
STL Loi # C3B 120243
Sample Receiving:
STL Pittsburgh, PA received. one sample on February 12, 2003 in good condition. The
cooler was within the proper temperature range .
· GC/MS Semivolatiles SIM:
Since insufficient sample volume was received to perform a matrix spike and matrix
spike duplicate, a Laboratory Control Sample (LCS) and Laboratory Control Duplicate
(LCD) were performed. All recoveries were ·within QC limits.
The reportilig limits were adjusted. according to the amount of sample extracted .
•
•
8270C (SIM)
Refereilces:
.METHODS SUMMARY
.,..,-,r,., .,,,.....,, ", "-.;,J.:.1~,<;.V""-.,,_-'
ANJU,YTICAL PREPARATION
SW846 8270C SIM SW846 3520C
SW846 11Tesi:. Methods for Evaluating Solid Waste, Physical/Chemical
Methods11 , _Third Edition, NoVembe:::-1986 and its Updates .
•
•
•
SAMPLE SUMMARY
C3Bl20243
WO # SAMPLE# CLIENT. SAMPLE . ID
FHG38 001 EFF/SV-305
NOTE(S)
-The analytical results of the samples listed above arc presen1ed oD. the follciwing pages.
• All CJ.lcul.acions arC Pcrfomie'i.l before rotJnding to avoid round-off errors in calculated rCSUJts.
• Results iloted as "ND' were not detected at or above" lhc stated limit.
• This repor_! must not be reproduced, c;-1ccp1 in futi, without the written approval ohtu: laboratory;
• Rcsult5 for the following parameters are never reported on a dry weight basis: color, corro&iviiy, density, flashjioint, igTiitability, layers, odor;
paint filter test, pH, porOsitY pmsure; reactivity, rcdox potential, specific gravity, spot tesui, solids, s~lubility, 1Cmperature. vfscosity, and weigh I .
SAMPLED SAMP
DATE TIME
02/11/03 10, 20
I
I
I
I
I
I I
I
I
I
I
I
I
I
I
I
• • • 'STL STL Pittsburgh Chain of
Custody Record Severn Trent Laboratories, Inc.
•450William Pitt Way, Bldg. 6
Pittsburgh, PA l!i238
STL 4124 {0901)
Clienbofo.,.
'
Project ~agar
1"'"C..:. &~
Addrsss
il..u<_'
Telephone Number (Area Code)/Fax Number
3 011 R .. J4..-q7'l. 171--'1<{)-1.
Cl~,,-,/ ~late I Zip Cods _ . Sile Contact l.ab Ccmtacl
4-tJ/7 o./J.. -
Project Name and L~J°n (S~~e) ·carn·eoWaybi/1 Number ( /seo. --z.-<r J/J --,'h.
ConrracVPurchase Order/Quote No .. Containers & . 0•;1.
J?e,+7, r -<13€':J '-i -o'l '-. Matrix Presarvatives J ·•
Sample I.D. No. -and Description ! ' 0 § .. r bi§ g,
(Co,7/a/ners tor each sample may bo combined on on~ fine) Date Time • ~ ~ ~ ~ " 0 ~-~ &I < ' ~ § ~ r r. l!
£Cp l<v/JoS-;;i. I,,\ 03 I 0:1 D · l'I X I/\
I
"
-'
Possible Hazard Jdentilication .
D Non-Hazard 0 Flammab/8 0 Skin lrrilanr D Poison 8
. I Sample, Disposal
,-J(1 Unknaivn D Re;um To Client X' ~ispossl By Lab D Archive For
Turn Around Timo Requlfed .
0 •24 Hours O 48 Hours
QC Requuem,mts (SpaciM
D 7 Days O 14 Days D 21 D-!!rs
, . Re!inquishod By Time ,, o, hot>
2. Relinquished By Time
3. Relinquished By Tii11e
Comments
OISTRISUTJON; WHITE· Returned to Clhml with Reporl:· CANARY. Stays wilh the Samp/8; PINK -Reid Copy·
Date / ,j o.)
Chain of Custodv Ni1mber
~ '180567
Lab Number l ·page I of
Analysis (Attach list if
mores ace is needed
Special Instructions/
Conditions of Recaipt
'
.
r
(A° fee may be assessod if samples are rotained
Manlh3 longor than I month)
Date Time-
Date Tims
oate Time
•
•
THE RETEC GROUP. INC
Client Sum_ple ID: EFF/SV-305
Lot-Sample# ... : C3Bl20243-001
Date Sampled ... : 02/11/03
Prep Date ...... : 02i13/03
Prep Batch# ... : 3044111
Dilution Factor: 1.01'·
PARAMETER.
2,4~Dichlorophenol
Penta~hlorophenol
Phenol
SURROGATE
Nitrobeilzene-'dS ·
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2, 4, 6-TribrOmoPhenol
GC/MS Semivolatiles
Work Order#.,.: FHG381AA
Date Received .. : 02/12/03
Analysis Date .. , 02 /2 iJ / 03
Matrix ......... : WATER
MS Run#., ..... :
Method ......... : SW846 8270C SIM
REPORTING
RESULT LIMIT UNITS.
ND 0.20 ug/L
ND 1.0 ug/L
ND 0.20 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
82 (3 0 -121)
86 (11 -119)
73 (39 -115)
75 (3 7 -115)
76 (41 -115)
93 (40 115)
•
•
Client Lot# ... , C3B120243
MB Lot-Sample#, C3B130000-lll
Analysis Date .. , 02/20/03
Dilutioil Factor: 1
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-dS
Terphenyl-d14
2-Fluorobiphenyl
2-Fltio~ophenol
Phenol-d5
2,4,6-Tribromopheno'l
NOTE (SJ :
M.8'1'..l::i.OD l:SLAftK. .lili.1;-"U.KT
GC/MS SemiVolatiles
Work Order # ... : FHHRGlAE
Prep Date .. c, •. , 02/l3/03
Prep Batch# .•. : 3044111
REPORTING
RESULT LIMIT
ND 0.20
ND 1.0
ND 0.20
PERCENT RECOVERY
RECOVERY LIMITS
56 . (30 -121)
80 (li -119)
59 (39 -ll5)
63 (37 -ll5)
66 (H -115)
75 (40 115)
Calculations an: performed be.fore rounding _10 avoid round-off errors in calcula:cd rcsulU.
Matrix ......... : WATER
UNITS METHOD
ug/L SW846 8270C SIM
ug/L SW846 8270C SIM
ug/L SW846 8270C SIM
• LABORATORY CO.N'.CHOL' SAMPLE .t";VALU.!-\.'i'.Lu.N :REPORT
GC/MS Semivolatiles
Client· Lot #.:. i C3Bl20243 Work Order fl •.• , FHHRGlAC-LCS
FHHRGlAD-LCSD
0?/20/03
Matiix ... ~·····= WATER
LCS Lot-Sample#, C3Bl30000-lll
Prep Date ...... , 02/13/03 Analysis Date .. ,
Prep Batch j/ •• ,, 3044111
Dilution Fae.tor: 1
PARAMETER
PentaChloropheriol
2,4-Dichlorophenol
Phenol
SURROGATE
Nitrobenzene-dS
Terphenyl0 d14
• 2-Fluorobiphenyl
2-Fluorophenol
Phenol-dS
2 , 4 , ·6 -T,ribromophenol
NOTE (S) ,
PERCENT
RECOVERY
105
107
84
86
76
78
RECOVERY
LI'i~ITS
(10 -140)
(10 -140)
(42 -115)
(42 -115)
(10 -131)
(10 -131)
PERCENT
RECOVERY
92.
91
91
90
83
81.
84
84
82
85
1.00
1.01
Calculations arc performed before rounding to avoid rouad--off erron in c:..lculated resuhs .
•
RPD
~ LIMITS METHOD
SW846 8270C SIM
1. 7 (0-56) SW846 8270C SIM
SW846 8270C SIM
2.6 (0-44) SW846 8270C SIM
SW84-6 8270C SIM
3.5 (0-43) SW846 8270C SIM
RECOVERY
LIMITS
(30 -121.) · ..
(30 -1.21.)
(11 -119)
(11 -119)
(39 -1.15)
(39 -1.15)
(37 -1.1.5)
(37 -1.is)
( 41. -11.5)
(4:l -1.i5)
(40 C 1.1.5)
(40 -1.1.5)
•
• A part of Sevem Trent pie
STL
ANALYTICAL REPORT
Raleigh, Biweekly NPDES
Lot#: C3COlOl09
Rita Bauer
The RETEC Group Inc
SEVERN TRENT LABORATORIES, INC.
Project Manager
March 10, 2003
Severn Trent Laboratories, Inc.
STL Pittsburgh• 450 William Pitt Way, Pittsburgh, PA 15238
Tel [phone] Fax [phone] • www.stl,nc.com
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Sample Receiving:
CASE NARRATIVE
THE RETEC GROUP
Raleigh, Biweekly NPDES
STL Lot# C3C010109
STL Pittsburgh, PA received one sample on March 1, 2003 in good condition. The
cooler was received within the proper temperature range
GC/MS Semivolatiles SIM:
Since insufficient sample volume was received to perform a matrix spike and matrix
spike duplicate, a Laboratory Control Sample (LCS) and Laboratory Control Duplicate
(LCD) were performed. All recoveries were within QC liniits .
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METHODS SUMMARY
CSC010l09
k.'1ALYTICAL PREPA."<ATION
PARAMETER METHOD :cMecEc:TccH:.,O:.,D:_ ___ _
8270C (SIM) SW846 8270C SIM SW846 3520C
References:
SW846 11Test Methods for Evaluating Solid Waste, Physical/Chemical
Methods11 , Third Edition, November 1986 and its updates .
• SAMPLE SUMMARY
c3c.01.01.09
SAMPLED SAMP
~ SAMPLE# CLIENT SAMPLE ID DATE TIME
FJFKQ 001 EFF/SV-305 02/28/03 10,20
NOTE(S)
-The analyctcal results of !he samples listed above are prf.">enred on the following pages.
-All calculations are performed before rounding to avoid round-off errors in calculared resulrs.
-Results noted as "ND" were not detected at or above the stated !lmic.
-This report must not be repinduc.cd, except in full, without lhe written approval of the Jab oratory.
-Re.<;'o.1Jt, for the following parameters are never reported on a dry weight basis: color, 1.:orrosivity, density. flashpoint, igniubility, layers, odor,
paint filter test, pH, porosity pressure, reactlvicy, ml.ox potential, spt:cific gravity, spot iests, solids, solubility, temperature, viscosity, and ~ight .
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fLli-
Client: ~
Address: J(}O lo.h Ave,
Address: &eonft?/f-tJn</).
Quote /1:
I I
. .. ------------,---'·.__
Chain-of Custody Record & Analytical Request
CDC# 30366
~n .. Page __ l _ of /
/
Date:_~d<..f--""'-f'-'"""d:=----
Turnaround: --·~ITT~~·---.--
Job Number: f,E/t-Z, ]-03GL{ /J '/ ~-
P.O. Number:
O~· ReportTo:_~l ________ _
Invoice To:
NC' __ SC ___ Other __ _
//00
ORIGINAL
SEE REVERSE FOR
TERMS AND CONDITIONS _J
\
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THE RETEC GROUP INC
Client Sample ID: EFF/SV-305
GC/MS Semivolatiles
Lot-Sample# ... : C3C010109-001 Work Order# ... : FJFKQlAA
Date Received .. : 03/01/03
Analysis Date .. : 03/10/03
Matrix ......... : WATER
Date Sampled ... : 02/28/03
Prep Date ...... : 03/05/03
Prep Batch# ... : 3064260
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-dS
2,4,6-Tribromophenol
MS Run# ....... :
Method ......... : SW846 8270C SIM
REPORTING
RESULT LIMIT UNITS
ND (). 2 0 ug/L
ND 1.0 ug/L
ND 0.20 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
65 (30 -121)
53 (11 -119)
52 (39 -115)
so (37 -115)
57 (41 -115)
59 (40 -115)
•
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Client Lot# ... , C3C010109
MB Lot-Sample#, C3C050000-260
Analysis Date .. , 03/10/03
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
NOTE (SJ ,
METHOD BLANK REPORT
GC/MS Semivolatiles
Work Order # ... : ?JLFRlAA
Prep Date ...... , 03/05/03
Prep Batch# ... , 3064260
REPORTING
RESULT LIMIT
ND 0.20
ND 1.0
ND 0.20
PERCENT RECOVERY
RECOVERY LIMITS
88 (30 121)
68 (11 -119)
69 (39 -115)
71 (37 -115)
59 (41 -115)
77 (40 -115)
Calculations are performed before rounding to avoid round.off errors in calculated results .
Matrix ......... , WATER
UNITS METHOD
ug/L SWB46 B270C SIM
ug/L SWB46 B270C SIM
ug/L SW846 8270C SIM
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LABORATORY CONTROL SAMPLE EVALUATION REPORT
GC/MS Semi.volatiles
Client Lot# ... , C3C010109 Work Order# ... , FJLFRlAC-LCS
FJLFRlAD-LCSD
Analysis Date .. , 03/10/03
Matrix ......... : WATER
LCS Lot-Sample#, C3COS0000-260
Prep Date ...... , 03/05/03
Prep Batch# ... , 3064260
Dilution Factor: 1
PARAMETER
Phenol
Pentachlorophenol
2,4-Dichlorophenol
SURROGATE
Nitrobenzene-dS
Terphenyl-d14
2-Fluorobiphenyl
2-Fluorophenol
Phenol-dS
2,4,6-Tribromophenol
NOTE (S) ,
PERCENT
RECOVERY
60
62
89
87
68
67
RECOVERY
LIMITS
(10 -131)
(10 -131)
(10 -140)
[10 -140)
(42 -115)
(42 -115)
PERCENT
RECOVERY
81
80
61
61
60
60
61
61
62
63
76
77
Calculations are performed before rounding to avo!d roum:1.-off errors in calculaced results .
RPD
RPD LIMITS METHOD
SW846 8270C SIM
1. 8 (0-43) SW846 8270C SIM
SW846 8270C SIM
2.8 (0-56) SW846 8270C SIM
SW846 8270C SIM
2.2 (0-44) SW846 8270C SIM.
RECOVERY
LIMITS
(30 121)
(30 -121)
(11 -119)
(11 -119)
(39 -115)
(39 -115)
(37 -115)
(37 -115)
(41 -115)
(41 -115)
(40 -115)
(40 -115)
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Environmental Testing Solutions, LLC
PO Box 7565
Asheville, NC 28802
Phone: [phone]
Fax: [phone]
E-mail: [e-mail]
Effluent Toxicity Report Form -Chronic Pass/Fail and Acute LC50 Date: Februaiy 17, 2003
Facility: TriTcst, Inc. NPDES #: NC-Pipe#: County: Wake --
Beazer
Laboratory Perfonning Test: Environmental Testing Solutions, LLC Comments:
Signature of Operator in Responsible Charge:
Signature of Laboratory Supervisor: 8~ Project: 582
Samples: 030129.01, 030201.01
Mail Original To: North Carolina Department of Environment and Natural Resources Chronic Test Results
DWQ/ Enviromnental Sciences Branch Calculated t: 0.615
1621 Mail Service Center Tabular t: 2.508
Raleigh, NC 27699-1621 %1 Reduction: 2.3
North C.irolina Ceriodaplrnia Chronic Pass/Fail Reproduction Toxicity Test Percent Average
Control Organisms I 2 3
Number of Yount? Produced 29 27 34
Adult Swvival: (L)ivc, (D)cad L L L
Effluent Percentage 190%1
Treatment 2 Organisms I 2 3
Number of Young Produced 30 29 29
Adult Swvival: (L)ive, (D)cad L L L
pH(S.U.) !st Sam le !st Sam le
Control 7.84 7.93 7.90 8.37
Treatment 2 8.19 8.87 8.43 8.88
t ~ t ~ " " " " ~ '" ~ '"
D.0. (mg/L) 1st Sam le 1st Samnle
Control 7.7 7.9 7.8 8.1
Treatment 2 7.5 7.8 7.6 8.1
LC5ofAcutc Toxicity Test
(Mortality expressed as%, combining replicates.)
Cnnccnlration (%)
ivlortalily (%)
4 5 6 7
34 32 33 32
L L L L
4 5 6 7
33 31 37 28
L L L L
2nd Samnlc
801 8.05
8.34 8.89
t ~ " " ~ '"
2nd Samnle
8.0 8.0
8.0 8.0
LCS0 = Method of Dctenninution
95% Confidence Limits
____ to ___ _ §Trimmed Spcam1un Karbcr
Probit
Other:
Organism Tested: Ceriodaphnia tluhia Duration:
DWQformA1C/ (3/87)rev. 11195
l\foralitv Reproduction
8 9 10 11 12 Control Control
35 37 36 33 33 I 0.0 32.9
L L L L LI Treatment 2 Treatment 2
0.0 32.2
Control CV
8 9 10 11 12 8.4 Pass Fail
37 30 35 35 32 I % <otl!rol 0<5oniam
pro,lucill,\ lrd brood X L L L L LI 100 .
Test Start Date: .;:0c;,1_:-2:.:9c...-0;:;3:_ ________ _
Collection (Start) Date:
Sample I 01-27-03 Sample 2 _c;.0.c..!-"-3"-0--=0.::.3_
Sample Type/Duration
Grab Comp Duration
Sample 1
Sample 2
X
X
Alkalinity (mg CaCO/L)
Hardness (mg CaCOiL)
Conductivity (µmhos/cm)
24-hour
24-ltour
Tota! Residual Chlorine (mg/L)
Sample Temp. at Receipt (0C)
33,
45,
I I I Control
High Cone.
7-days pH (S.U.)
<0.10
0.1
I I I
DO (mg/L)
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TRl'i'EST, INC.
Bioassay Chain ·of Custody Form
· Bio;:i ssavs. are to be samoled after B:30a.m. Dri
P.O.#: ____________ _
Phone# (1T{ ) j'] f-J 'f 2 ::J.
Contact: ,e_,-tz...._ 15,~.,....--County : _ ___,iA)c..' =· .:.:<J.:..v=-=•==-· _____ Outfall/ Pipe#: _____ . N"?~ES Permit#: · /i.,t.,.,-.-. liJt,; %Effluent Dilution : __ __,fe::.· ___ '1..ca...c1,..c."-"-0\o••-z.<;-o"'J . -TestMcthod: {j,r(v, .. it .. To;t( . Sa;nple Site Desc:iption: _._J<_Y.1:.--S,..__.,,e=-!:.F.if_...,.... _____ ....,c _____ _
Srunpie Collector: _Print> _1+.A+-'-"=fc-.=~.....,,_'-"-r~-'--. nJ~'!-·\...,,_\ ____ ----,-__ _ Signature >_-'-L..,i=J.~"'-'-'-''~==+l-'d/=-,1------,-------
Sam;:il: Typ:: Comoosite:
Daw Started: ___ _,l",-;;,:.....,..L,-Cc...<------Time: / tJo·o @ or P~ Date Ended:----+-""'-':..,..;""""'------
Time: /o-zn;; .(@r PM Samples per Hour:-----'-'------·# Hours: :)_ f
Grab:_
Date: _____ _;_ _________ _ T'nne: __ -___ .;.A.VI or P.M
Sample Volume: ---'"'X=--'2-'· "-----,~--Ch_il]ed during Collection? Y
Method ofTraJJsportal:ion to Lab :-'V\o.:.....::=,.J-"",._,,)J<-· =• =-· ·v_t_'-----------------... , ...... ·· .................. . Chilin of Custody R:Jease .............................. !•····· '
•I Ii Relinoul\hed By. I Date Time Received Bv · I I A -::r1..IJ'-J/tlYJ/11 ///J/1 'l . ;-,,. I ,n=. .,.J. . .-,c.-b.2i . r,q""' . ~ r, .
V
.
-ror Laborn1ory Use Only
. Rec,iving Temperature: _...g,~=--------By: ·r 1,)M~ Residua! Chlorine: _ __,f-J-=l:..~:Z .. -i ... ________ Number of Bottles:_,;?--_· ___ _
Address: 3909·Beryl Rd.• Ral=gi,.. NC 27607 Phone(9l9) 834 -4984 FBX (9151) 834-6497 /l '3JI -0 I rt;<J ~do f
"D"'• Time lil,:J,ti/ti:? ;, . ..;_, I/ ~•-?<1-0"-~=-
f 11..cr:rtt--r~ 5£' 2...
51'>'.PLe -if;-OC0\2"1-0t
\e;-\ f' C O ':, ·c.
(
[!fl
. I -
I
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TRITEST, fN.C.
Bioassay Chain ·or'Custody F~rm
Bioassays are to be sampled a,fter B:30a.m. on ~u.e·sday &. Friday.
Faoility :Name· &zi4:zfi" / R4t-@ 2d . I Address: fit::11f::C-P.O.#: ___________
_
Pbond ( Cf 7i ) ':I 71-/<;,'.2. "2.,
c=ty: u1Ak£ OutfalYPi;,; fl: 4'(!; (
Contact: ~ &-(P<.e'
NJ>DESP=tlt;/.: -~✓,V, (4/t'P?£-. %Effluent Dilution : _...,_.,:_ ____ _ TesiMelhod: Gfi4w/C Tit(. · Sample Site Description: __:J:..z,Y.!:., . .:_· -A.,Z..,_',;:¥;",:;;:z..,_. ---------~----
Sompie Collector: .Print> T.¢.-T L4.4v~ ·
Signt.tirrc > ~~ . z5 7ryJ--. Sam?le Type: Como.osite:
DatcStart,.c!: 1/20/Dl Time: ~9eio Date Ended: __ ,._.).,.:r_..d,..,o"-7;;._ _______ Tunc: · O'f ob
@:,r PM
· ~or PM Samples p~ Hour:--~--------
#Hours: if"(
D•tc : ______________
_ Time: -----'-AM or PM Sample Volu.-nc: _,..,Z;:;___,:'-:,.{J.:z:g_.=z:(Z_.,,_.J __ -,-___ Chill=d during Collection? Y4'C
Mi:thod ofTransporllltion to Lab: b?9M2 i1R.Jue.4'P,2 .
• · • • • , ~ • •··. • • • • • • • • • • • • • • • • • · · Chain of c.ustody ~lean. ♦ t ♦ ♦ ♦ if 4 t ♦ ♦ •. ♦ ♦ ♦ t t ♦ ♦ •·. ! ♦ ♦ t • ♦ ~ls'n:A ~" D•t": Tll!l~ R.eccivcdBv . In, IA., If?.<: 1, .-, . I/ c-et--.e:.c '"~i -o~ 2'!,lo <'•.-I< ,,.,,v,./7
..
-rar LabotVOry u~ Only 3(,C,,,
~--/ a
Receiving Tempcntu::: _ __,Q~•~-"--------
By: T /J'lJIZll7':0<. Residual Chlorine: ---+!'f;;,..l,:..,-..:f:'"'7 ______ , Number ofBot!le;: _,,J-___ _
Add=<: 39O9-Boryl Rd.-Rale!gb, NC 27607 Phonc(9l 9) 834 -4984 FB>t (91~) 834-6497 1Jg6 I -tJI Jc:; tJ -ofJ-Z
·p .... Timt I I< in-;; J/7<. 7,; U~]'.11,J,.,-..,::.._ 1 ,.;; la
J.f.h-<-0DI t
. f' 11.~'5~ 1...
,5p,I-IPL€. :ll Q:,020 \ 'C \
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February 7, 2003
Ms. Beverly Hudson
Remedial Project Manager
U.S. EPA -Region IV, I Ith Floor
North Site Management Branch
61 Forsyth Street, SW
Atlanta, GA 30303
RE: Monthly Progress Report #117
Remedial Action
Koppers Site -Morrisville, North Carolina
Dear Ms. Hudson:
FEB 1 7 2003
In accordance with the Unilateral Order, and on behalf of Beazer East, Inc. (Beazer), please find attached
four (4) copies of the January Monthly Progress Report for Remedial Action at the Koppers Superfund
Site in Morrisville, North Carolina. No exceedances occurred during this event. We have received verbal
notification from the lab that the January chronic toxicity sample produced a passing result. However, we
have not yet received the final hard copy of the chronic toxicity report. Therefore, we will forward this
final report with the next Monthly Progress Report. Since we had a passing result, the next chronic
toxicity sample will be collected during the second quarter 2003 .
Should you need additional information regarding this progress report, please call Mike Helbling at
( 412) 208-8858 or me at (978) 3 71-1422.
Sincerely,
The RETEC Group, Inc. ??cu-rt ?yfof,wdtf
Rita Bauer
Project Geologist
CK:pb
Enclosure
cc: D. Mattison -NC Superfund (2 copies)
L. Faulconer -Wake County
G. Caskey -Enwood Structures
M. Helbling -Beazer
H:\Bcaz-Ralei\O I M-03.doc
D. Hails -Ecological Restoration, Inc.
J. Garrett-NC Division of Water Quality
D. Matthews -NC Div. of Waste Management
P. Kilchenstein -RETEC
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MONTHLY PROGRESS REPORT #117
REMEDIAL ACTION
SITE NAME: Koppers Superfund Site
Beazer East, Inc.
Morrisville, NC
USEPA DOCKET NUMBERS: 93-09-C
PERIOD ENDING: January 31, 2003
1. PROGRESS MADE THIS MONTH
2.
3.
4.
5.
6.
7.
Remedial Action (RA) -HABITAT MITIGATION. No activities were conducted this
month.
Remedial Action (RA) -GROUNDWATER TREATMENT. The treatment system
operated throughout the month without upset. System performance was monitored on a
biweekly basis. Approximately 39,790 gallons of groundwater were extracted, treated in
the treatment plant, and discharged between December 31, 2002 and January 28, 2003.
System water samples were collected on January 15 and January 28, 2003 in accordance
with the sampling schedule in the O&M manual. Samples were submitted to Severn
Trent Laboratories, Inc. and Tritest, Inc. for laboratory analysis. The operations and
sampling programs are summarized on the attached Table I.
Remedial Action (RA) -EFFECTIVENESS MONITORING PROGRAM. No activities
were conducted this month.
Remedial Action (RA) -CORRESPONDENCE. None.
PROBLEMS RESOLVED None.
PROBLEMS ANTICIPATED None.
UPCOMING EVENTS Continue System O&M.
PERSONNEL CHANGES None.
SUBCONTRACTORS None.
ANALYTICAL DATA Analytical data from system influent and effluent
sampling received during this period are enclosed and are summarized on Table 2 .
H:\Beuz-Ralei\01 M-03.doc
•
Date Systems Cumulative SV-101 SV-101
Check Effluent Flow Sample Sample
(yes/no) (Gallons) (yes/no) Parameters
•
Table 1
Groundwater Treatment Operations and Sampling Program Summary
Koppers Superfund Site
Morrisville, North Carolina
January ~003
Associated SV--304 SV-304 Associated
Group Sample Sample Group
(yes/no) Parameters
•
SV-305 SV-305
Sample Sample
(yes/no} Parameters
01/15/03 yes 3,715,610 ves Penta, 2.4-Dichloro Phenol, Dioxin 1,2 ves Penta 2.4-Dichloro, Phenol 1 ves Penta 2.4-Dichloro Phenol Dioxin
01/28/03 ves 3 733 790 no
Notes:
Sampling point SV-101 is located before the Carbon Units (pretreatment)
Sampling point SV-304 is located between the Carbon Units
Sampling point SV-305 is loctated after the Carbons Units (post-treatment)
NR -Not recorded
F.\Prcjecls\O:J.624\RepOrts\Monlhly\()IM~3 Table 1.xls
no
Associated Groups:
SV-101 -Group 1 is penta and 2,4--dichlorophenol; Group 2 is dioxin
SV-304 -Group 1 is penta and 2,4-dichtorophenol
ves Penta 2 4-Dichloro, Phenol, Chronic Tax
SV-305 -Group 1 is penta, phenol, and 2,4-dichlorophenol; Group 2 is dioxin and Group 3 is chronic toxicity
Associated
Group
1,2
1 3
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Table 2
Groundwater Treatment Analytical Data Summary
Koppers Superfund Site -Morrisville, North Carolina
January 2003
Analytical
Parameter Date Sample Sample
Sample Location Location
Collected SV-101
Pentachlorophenol 01/15/03 17
01/28/03
2.4-Dichlorophenol 01/15/03 <0.19
01/28/03
Phenol 01/15/03 <0.19
01/28/03
Chronic Toxicitv 01/28/03
Dioxin (2,3,7,8-TCDD\ 01/15/03 <0.22
Notes: All results are in micrograms per liter (µg/L) except dioxin. Dioxin data is in picograms per liter (pg/L).
SV-101 -Before Carbon Units
"SV-304 -Between Carbon Units
**SV-305 -After Carbon Units
F:\Projects\03624\Reports\Monthly\01 M-03 Table 2.xls
SV-304'
<1.0
<0.20
<0.20
Sample
Location
SV-305"
<1.0
<1.0
<0.21
<0.20
<0.21
<0.20
Pass
<0.28
SEVERN
• · T,RENT•
•
•· A part of Sevem Trent pk:
STL
ANALYTICAL REPORT
Raleigh, BiweeklY NPDES
Lot ff: C3A290140
Rita Bauer
The RETEC Group Inc
SEVERN TRENT LABORATORIES, INC.
Veronica Bertot
Project Manager
February 6, 2003
Severn Trent Laboratories, Inc.
STL Pittsburgh• 450 William Pitt Way, Pittsburgh, PA 15238
Tel [phone] Fax [phone] • www.stl-inc.com
Sample Receiving:
CASE NARRATIVE
THE RETEC GROUP
Raleigh, Biweekly NPDES
STL Lot# C3A290140
STL Pittsburgh, PA received samples on January 29, 2003 in good condition. The cooler was within the proper temperature range
GCfMS Semivolatiles SIM:
Since insufficient sample volume was received to perfom1 a matrix spike and matrix spike duplicate, a Laboratory Control Sample (LCS) and Laboratory Control Duplicate (LCD) were performed. All recoveries were within QC limits.
•
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MEfflODSSUMMARY
C3A290140
ANALYTICAL PREPARATION
~PARAM===ET~E=R~-------------------METHOD =M=E~T=H~O=D ____ _
8270C (SIM) SW846 8270C SIM SW846 3520C
Referenceo:
SW846 "Test Methods for Evaluating Solid waste, Physical/Chemical
Methods 11 , Third Edition, November 1986 and its updates .
SAMPLE SUMMARY
C3A290140
WO# SAMPLE# CLIENT SAMPLE ID
FGR79 001 EFF/SV-305
NOTE(SJ
-The analytical resuUs of the samples listed above are presenicd on the following pages.
• All calcillations arc performed before rounding to avoid round-off errors in calculated results.
• Results n·otcd as 'ND" were not detected at or above the stated limit.
• This report must not be reproduced, except in full, without the written approval of the laboratory.
• Ri:stilis for the following parameters are never repo·rtect on a dry wi:ight basis: cO!or, corroslvity, denSity, fl.ishpoint, ignitability, layers, odor,
paint filter test, pH, p~rosity pressure, reacti.Vity, red ox potential, specific Sravlty, spot tests, ~lids, solubility, ccmperarure, viscosity, and weight.
•
SAMPLED SAMP
DATE TIME
01/28/03 OB,55
Chain of :.
Custody Record
SEVERN
TRENT
SERVICES · Severn Trent Laboratories, Inc.
STL-4124 (0901)
Client~ Project ManT!w.--~ ~ 07 I Chain of Custody Number
I Ill' J,. I '"\v 0:J 17LISR4
Address? ./h'C? ff~ fivJ/ Tsfephone Number (Area Code)/Fax Number Lad Number I I 'il1V -77 / -1t.lJ~ Page of
Ci/)'0 A iffii4-I '°P oh✓:2 Site Contact Lab Contact Analysis (Attach list if -, ) more space is needed
. Project ~ar:;: L;,1 (~tato z fa:Jtf Garrier/Wayt:ii/1 Number 1 -01?, Special Instructions/
Contract/Purchase 0rrier/Dubte No. cOntainers &
,, Conditions of Receipt Matrix • Preservatives .S_
"
Sample 1.0. No. and Description ' I 0 8 ~ ~i§ fl
Date Time ! • li ~ G ~ (Containers for ea.ch sample may be combine(! on one line) s ~ • 5 ~ ~ ~ ~~ ' ~ z
G:t=f-f<.v-3o5 ,b~I», (} <;'I;(;_ '/.. Y., -\
' ' II
Possible Hazatd ldentilicatioh ~, ~ Samp/9 'Disposal
'"~posa/ By Lab
(A fee may be assessed ,t samples are retained 0 Non-Hazard . O-.Flammable 0 Skm Irritant -D Poison B Unknown O Return To Client D Atehive For Months lar,ger than I month)
Turn Around nme Required / ~ro ' DC Requirements (Specify)
0 24 Hours 04)1' ours 0 70ays D 14 Days 0 21 Days lSl 0fller
. 1. Relinquished By (, ,I -o /J 1 "a :}JI~ !"mi G 6'Z)
'I. RecefVed By !Date r nme .f}. A /1 r-:.-__P #✓
2. Relinquished By --' , I°''"' . 1"= 2. Rea,fed) ''; ·,lP f/4.,, -~ 1;,~ o,/,,,;, !";~D?) irI
3. Relinquished By ·(ate
1
Time 3. Received By ' I Date ~
1
nme
Comments
DISTRIBUTION: WHITE • Returned to Client with RepoJt; CANARY -Stays with Iha Sample; PINK -Field Copy • • f •
THE RETEC GROUP INC
Client Sample ID: EFF/SV-305
GC/MS semivolatiles
Lot-Sample# ... : C3A290140-001 Work Order# ... : FGR791AA
Date Received .. : 01/29/03
Analysis Date .. : 02/05/03
Matrix ......... : WATER Date Sampled ... : 01/28/03
Prep Date ...... , 01/31/03
Prep Batch# ... : 3031266
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
MS Run # ....•.. :
Method ......... : SW846 8270C SIM
REPORTING
RESULT LIMIT UNITS
ND 0 .20 ug/L
ND 1.0 ug/L
ND 0.20 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
102 (30 -121)
BO (11 -119)
90 (39 -115)
97 (37 115)
107 (41 -115)
86 (40 115)
•
•
•
•
METHOD BLANK REPORT
GC/MS Semivolatiles
Client LOt # ... : C3A290140 Work Order# ... : FGX0HlAA
MB LOt-Sample #: C3A310000-266
Analysis Date .. : 02/05/03
Dilution Factor: 1
PARAMETER
2 , 4 -Di.chlorophenol
PE!ntachlorophenol
Phenol
SURROGATE
Niti:-obenzene-dS
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
NOTE (S) :
Prep Date ... , .. : 01/31/03
Prep Batch# ... : 3031266
REPORTING
RESULT LIMIT
ND 0.20
ND 1.0
ND 0.20
PERCENT RECOVERY
RECOVERY LIMITS
88 (3 0 -121)
67 (11 -119)
72 (39 115)
81 (37 -115)
88 (41 -115)
72 (40 -115)
Calcu!atioru are performed before rounding to avoid round-off errors in calculated results .
UNITS
ug/L
ug/L
ug/L
Matrix ......... : WATER
METHOD
SW.846 8270C SIM
SW846 8270C SIM
SW846 8270C SIM
LABORATORY CONTROL Sl\MPLE EVALUATION REPORT
GC/MS Semivolatiles
Client Lot# ... : C3A290140 Work Order# ... : FGX0HlAC-LCS
FGX0HlAD-LCSD
Analysis Date .. : 02/05/03
Matrix ......... : WATER
LCS Lot-Sample#: C3A310000-266
Prep Date ....•. : 01/31/03
Prep Batch# ... : 3031266
Dilution Factor: 1
PARAMETER
Phenol
Pentachlorophenol
2,4-Dichlorophenol
SURROGATE
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
NOTE (S):
PERCENT
RECOVERY
92
93
99
99
87
90
Calculatiom; are perfonned before rounding to avoid round-off errors In calculated results.
RECOVERY
LIMITS
(10 -131)
(10 -131)
(10 -140)
(10 -140)
(42 -115)
(42 115)
PERCENT
RECOVERY
89
93
72
74
79
79
79
78
82
84
84
82
RPD
RPD LIMITS METHOD
SW846 8270C SIM
0.70 (0-43) SW846 8270C SIM
SW846 8270C SIM
0.31 (0-56) SW846 8270C SIM
SW846 8270C SIM
3.3 (0-44) SW846 8270C SIM
RECOVERY
LIMITS
(30 -121)
(30 -121)
(11 -119)
(11 -119)
(39 -115)
(39 -115)
(37 -115)
(37 -115)
(41 -115)
(41 -115)
(40 -115)
(40 -115)
•
•
SEVERN • TRENT
•
• A. PM of Severn Trent pie
STL
ANALYTICAL REPORT
Raleigh, Biweekly NPDES
Lot#, C3A160226
Rita Bauer
The RETEC Group Inc
SEVERN TRENT LABORATORIES , INC.
~
Veronica Bertot
Project Manager
January 29, 2003
Severn Trent Laboratories, Inc.
STL Pittsburgh• 450 William Pitt Way, Pittsburgh, PA 15238
Tel [phone] Fax [phone] • www.stl,nc.com
Sample Receiving:
CASE NARRATIVE
THE RETEC GROUP
Raleigh, Biweekly NPDES
STL Lot# C3AI60226
STL Pittsburgh, PA received samples on January 16, 2002 in good condition. The cooler
was within the proper temperature range
The dioxin samples were shipped directly to the STL Sacramento, CA laborat01y for
analysis.
GC/MS Semivolatiles SIM:
The reporting limits for the sample were adjusted to reflect the amount of sample used in
the extraction'procedure.
'
Due to the concentration of pentachlorophenol detected, SV-10 l was analyzed undiluted
and at a 5X dilution. Both sets ofresults are reported.
Since insufficient sample volume was received to perform a matrix spike and matrix
spike duplicate, a Laboratory Control Sample (LCS) and Laboratory Control Duplicate
(LCD) were performed. All recoveries were within QC limits.
Dioxins:
There were no problems associated with the analysis.
•
•
•
•
MEfflODSSUMMARY
C3Al60226
Dibenzodioxins and Dibenzofurans, HRGC/HRMS
8270C (SIM)
References:
ANALYTICAL PREPARATION
SW846 8290 SW846 8290
SW846 8270C SIM SW846 3520C
SW846 11Test Methods for Evaluating Solid Waste, Physical/Chemical
Methods11 , Third Edition, November 1986 and its updates .
WO # SAMPLE# CLIENT SAMPLE ID
FF659
FF66C
FF66D
NOTB(S)
001
002
003
EFF/SV-305
SV-304
SV-101
SAMPLE SUMMARY
C3Al60226
-The analytical results of the samples listed above are presented on the followlng pages.
-All calculations arc performed before rounding to avoid round-off errors in calculated results.
-Resull.8 noted as "ND~ were not dc1ec1ed at or above the stated limit.
-This report must noc be reproduced, except in full, without lhe wrinen approval of the laboratory.
• Re.suits for the following parameters are never reported on a dry wei8ht basis: color, corrosivity, density, flashJ)-Oint, ignitability, layers, odor,
paint filter te&t, pH, porosity pressure, reactivily, redox potenlial; specific gravity, spot tests, solids, solubility, temperature, viscosity, and wcight.
•
SAMPLE:D SAMP
DATE TIME
01/15/03 10:20
01/15/03 10:35
01/15/03 10:50
.
Chain of Custody Record PA 000364
Project N,mec Ru;z,.,,,l /2 V. -1 Project N,mber, /Je.A-7 7,.. t) J (,.; '{ -09 C,
Send-Report To: ,{<,;t-,;.. 1Jo-,u o r' Sampler (Print Name): tL ,,JI,-/
Address: '3 {}() '!] \,,r, L,,e,. Sampler (Print Name): -
(? ,. .d M.J4 ~r,</d Shipment·Method: r::.e,d£✓
Airbill Number: ?l::n 0)/,. , "" ,
Phoaec Cf?':j_ ~·?J (-Jc/,2).. Laboratory Receiving: sn_ -Prrrs
Fax:
Field Sampte·ro Sample Sample ·Sample Number of
Date Time Matrix Containers
r:,FF/S'V-7oS-i/,cln1 t,.,_, ,... t.i.J, Kr :i.,
SIi-?o</ ' \ . ;,r,7<" ~
Sv-101 '1/ I 0<:7J ) I d
b 1" " i, ~ ,,,
.}!. ~ ;,
" "i
~
'1-
'/..
i
'
ThermoRetec Co.rporation
3040 William Pitt Wey• Pittsburgh, PA 15238-1359
{412) 825-3340 Phone• [phone] Fax
• www.thermoretec.com
'}I
.
I
0 'fhermoRetec
Smart Solutwns. Positive Outromes..
Page__!.of_f_
Purchase
Order#·
Comments, Special Lab Sample IO
Instructions, etc. (to be completed by lab)
Relm7:r:b~ (Sigaa'?J) Received by:·(Signature) ~·7r\1,,. Time: Sample Custodian Remarks (Completed .BY Laboratoiy):
,C . 7 /',, .1/'&1', QA/OC Level · Turnaround Sample Receipt . I Cj
Relinquished by: (Signature) Received by: (Signiture) Dete:· • Time: Total# Containers Received?
level I .o Routine D COC Seals Present?
level II D 24 Hour D COC Seals Intact? Relinquished by .(Signature) .7:2(7'li .z~£44 Time: level m D 1 Week D .Received Containers Int.ad?
-., . l/,', A /0~~ Other D Other --"Temperature?
__ ,
Yellow: PM Copy Pink: field Copy • •
THE RETEC GROUP me
Client Sample ID: EFF/SV-305
GC/MS Semivolatiles
Lot-Sample# ... : C3A160226-001 Work Order# ... : FF6591AA
Date Received .. : 01/16/03
Analysis Date .. : 01/22/03
Matrix ......... : WATER
Date Sampled ... : 01/15/03
Prep Date .... · .. , 01/20/03
Prep Batch# ... , 3020338
Dilution Factor: 1.04
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-dS
Terphenyl-d14
2-Fluorobiphenyl
2-Fluorophenol
Phenol-dS
2,41 6-Tribromophenol
MS Run# ....... :
Method •........ : SW846 8270C SIM
REPORTING
RESULT LIMIT UNITS
ND 0.21 ug/L
ND 1.0 ug/L
ND 0 .21 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
76 (30 -121)
80 (11 119)
62 (39 -115)
68 (37 -115)
83 (41 115)
60 (40 -115)
•
•
•
•
THE RETEC GROUP INC
Client Sample ID, EFF/SV-305
TraCe Level Organic Compounds
Lot-Sample# ... , C3Al60226-001 Work Order# ... , FF6591AC
Date Received .. , 01/16/03
Analysis Date .. , 01/26/03
Date Sampled ... , 01/15/03
Prep Date ...... , 01/24/03
Prep Batch# ... , 3024502
Dilution Factor: 1
DETECTION
PARAMETER RESULT LIMIT
2,3,7,8-TCDD ND 0. 28
PERCENT RECOVERY
INTERNAL STANDARDS RECOVERY LIMITS
13C-2,3,7,8-TCDD 80 (40 -135)
Matrix ......... : WATER
MS Run# ....... ,
UNITS METHOD
pg/L SW846 8290
Lot-Sample# ... , C3A160226-002
Date Sampled ... : 01/15/03
Prep Date ...... : 01/20/03
Prep Batch# ... , 3020338
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-dS
Terphenyl-d14
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
THE RETllC GROUP INC
Client Sample ID, SV-304
GC/MS Semivolatiles
Work Order# ... : FF66C1AA
Date Received .. : 01/16/03
Analysis Date .. , 01/22/03
Matrix ......... ' WATER
MS Run# ....... :
Method ......... : SW846 8270C SIM
REPORTING
RESULT LIMIT UNITS
ND 0.20 ug/L
ND 1.0 ug/L
ND 0.20 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
60. (30 121)
90 (11 -119)
50 (39 115)
52 (37 115)
63 (41 -115)
56 (40 115)
•
•
•
•
Lot-Sample# ... , C3Al60226-003
Date Sampled ... , 01/15/03
Prep Date ...... , 01/20/03
Prep Batch# ... , 3020338
Dilution Factor: 0.96
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
S!JRROGATE
Nitrobenzene-dS
Terphenyl-di4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
NOTE(S),
THE RETEC GROUP I.NC
Client Sample ID, SV-101
GC/MS Semivolatiles
Work Order# ... , FF66D1AA
Date Received .. , 01/16/03
Analysis Date .. , 01/22/03
Matrix ......... : WATER
MS Run# ....... ,
Method ......... , SW846 8270C SIM
REPORTING
RESULT LIMIT UNITS
ND 0.19 ug/L
21 B 0.96 ug/L
ND 0.19 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
67 (30 121)
83 (11 -119)
55 (39 115)
58 (37 115)
71 (41 -115)
59 (40 -115)
E &timate<l result. Result concemratlon exceeds the calibration range .
Lot-Sample# ... : C3Al60226-003
Date Sampled ... : 01/15/03
Prep Date ...... : 01/20/03
Prep Batch# ... : 3020338
Dilution Factor: 4.8
PAAAMET!fa
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
THE RBTEC GROUP INC
Client Sample ID: SV-101
GC/MS Semivolatiles
Work Order# ... : FF66D2AA
Date Received .. : 01/16/03
Analysis Date .. : 01/22/03
Matrix ......... : WATER
MS Run# ....... :
Method ......... : SW846 8270C SIM
REPORTING
RESULT LIMIT UNITS
ND o. 96 ug/L
17 4.8 ug/L
ND 0.96 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
81 (30 -121)
97 (11 -119)
64 (39 115)
73 (37 -115)
84 (41 115)
67 (40 -115)
•
•
•
•
THE RETEC GROUP INC
Client Sample ID: SV-101
Trace Level organic Compounds
Lot-Sample jl. .. : C3Al60226-003
Date Sampled ... : 01/15/03
Prep Date ...... : 01/24/03
Prep Batch# ... : 3024502
Dilution Factor: 1
PARAMETER
2;3,7,8-TCDD
INTERNAL STANDARDS
13C-2,3,7,8-TCDD
Work Order# ... : FF66DlAC
Date Received .. : 01/16/03
Analysis Date .. : 01/26/03
DETECTION
RESULT LIMIT
ND 0.22
PERCENT RECOVERY
RECOVERY LIMITS
81 (40 -135)
Matrix ......... : WATER
MS Run# ....... :
UNITS METHOD
pg/L SW846 8290
METHOD BLANK REPORT
GC/MS Semi~olatiles
Client Lot# ... : C3Al60226 Work Order# ... : FGCVWlAA
MB Lot-Sample#: C3A200000-338
Analysis Date .. : 01/22/03
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorobiphenyl
2 -Fl uorophenol
Phenol-dS
2,4,6-Tribromophenol
NOTE(S):
Prep Date ...... : 01/20/03
Prep Batch# ... : 3020338
REPORTING
RESULT LIMIT UNITS
ND 0.20 ug/L
ND 1.0 ug/L
ND 0.20 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
80 (30 -121)
74 (11 119)
66 (39 -115)
79 (37 115)
89 (41 -115)
64 (40 115)
Calculations are performed before rounding 10 avoid round-off errors in calculated resuhs.
•
Matrix ......... : WATER
METHOD
SW846 8270C SIM
SW846 8270C SIM
SW846 8270C SIM
•
•
Client Lot# ... , C3Al60226
MB Lot-Sample#, G3A240000-502
Analysis Date .. , 01/26/03
Dilution Fabtor: 1
PARAMETER
2,3,7,8-TCDD
INTERNAL STANDARDS
13C-2,3,7,8-TCDD
NOTE (S),
METHOD BL/INK REPORT
Trace Level Organic Compounds
Work Order# ... , FGMRMlAA
Prep Date ...... , 01/24/03
Prep Batch# ... , 3024502
DETECTION
RESULT LIMIT UNITS
ND 0.23 pg/L
PERCENT RECOVERY
RECOVERY LIMITS
80 (40 -135)
Calculations are perforffied before rounding to avoid round-off errors in calculated results .
Matrix ......... , WATER
METHOD
SW846 8290
LABORATORY CONTROL SAMPLE EVALUATION REPORT
GC/MS Semivolatiles
Client Lot# ... : C3A160226 Work Order# ... : FGCVWlAC-LCS
FGCVWlAD-LCSD
Analysis Date .. , 01/22/03
Matrix ......... : WATlm LCS Lot-Sample#: C3A200000-338
Prep Date ...... : 0l/20/03
Prep Batch# ... : 3020338
Dilution Factor: 1
PERCENT RECOVERY RPD
PARAMETER RECOVERY LIMITS RPD LIMITS METHOD
Phenol 74 (10 -131) SW846 8270C SIM
76 (10 -131) 3. 0 (0-43 I SW846 8270C SIM Pentachlorophenol 74 (10 -140) SW846 8270C SIM
74 (10 -140) 0. 7l (0-56) SW846 8270C SIM
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS Nitrobe!nzene-ds 85 (30 -121)
84 (3 0 -121)
Terphenyl-dl4 78 (ll -.119)
80 (ll -119)
2-Fluorobiphenyl 64 (39 115)
66 (39 -115)
2-Fluorophenol 71 (37 -115)
70 (3 7 -115)
Phenol-d5 76 (41 -115)
78 (41 115)
2,4,6-Tribromophenol 65 (40 115)
66 (40 ll5)
NOTE(S):
Calculations arc perfonned before rounding to avoid round-off errors in calculated results.
•
•
•
•
LABORATORY CONTROL SAMPLE EVALUATION REPORT
Trace Level Organic Compounds
Client Lot# ... : C3Al60226 Work Order# ... : FGMRMlAC
LCS Lot-Sample#: G3A240000-502
Prep Date ...... : 01/24/03 Analysis Date .. : 01/26/03
Prep Batch# ... : 3024502
Dilution Factor: 1
PERCENT RECOVERY
PARAMETER RECOVERY LIMITS
2,3,7,8-TCDD 128 (70 -130)
PERCENT
INTERNAL STANDARD RECOVERY
13C-2,3,7,8-TCDD 83
NOTE (S) :
Calcu\alions arc performed before rounding to avoid round-off errors In calculated results.
Bold print denotes control parameters
Matrix ......... : WATER
METHOD
SW846 8290
RECOVERY
LIMITS
(40 -135)