NCD003200383_20031009_Koppers Co. Inc._FRBCERCLA RA_Second Quarter 2003 Groundwater Monitoring Report-OCR

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October 9, 2003
Ms. Beverly Hudson
Remedial Project Manager
USEPA-Region IV
N011h Superfund Remedial Branch
Waste Management Division
100 Alabama Street
Atlanta, Georgia 30303
RE: Second Quarter 2003 Groundwater Monitoring Report for the
Former Koppers Company Site, Morrisville, North Carolina
RETEC Project No.: BEAZ?-03624-103
Dear Ms. Hudson:
The RETEC Group, Inc.
1822 E. NC Highway 54, Suite 100
Durham, NC 27713
[phone] Phone
[phone] Fax
www.retec.com
RETEC North Carolina, Inc. (RETEC), on behalf of Beazer East, Inc. (Beazer), hereby submits
the results of the second quarter 2003 groundwater monitoring event at the former Koppers
Company Site in Morrisville, North Carolina (Site). This report documents the field and
laboratory results of the groundwater monitoring event performed on June 12, 2003.
Groundwater Monitoring Program-Second Quarter 2003
Based on the Proposed Remedial Action Groundwater Monitoring Program (ThennoRetec,
1999)1 requirements, the second quarter 2003 monitoring event included the:
• Gauging of 50 monitoring wells (Figure I): 35 on-site wells and 15 off-site wells
• Sampling of three on-site wells: C-14A, C-29B, and PW-01
Although well M-04 is usually included in the groundwater sampling program, RETEC found
that the volume of water present in this well was not sufficient to generate a sample.
Groundwater Elevation and Direction of Flow
Groundwater elevations for the A-, B-, and C-zone wells, as measured on June 12, 2003, are
presented in Table I. The groundwater elevations presented in Table I were used to construct
the A-, B-, and C-zonc groundwater potentiometric surface maps shown in Figures 2 through 4.
Historic groundwater elevations for wells C-01 B and C-1 OB differ significantly from the historic
groundwater elevations in the other 8-zone wells. These consistently different groundwater
elevations, in conjunction with the fact that these wells are 30 to 55 feet deeper than the
neighboring 13-zone wells. indicate that wells C-0113·and C-1013 do not communicate with the
rest of the 13-zone aquifer. Because of this lack of communication, wells C-0113 and C-1013 will
1 ThormoRetec, 1999. Proposed Rcmedinf Action Groundwater Monitoring Program. Proparecl lJy ThermoRctcc
Consulting Corporation. August 1999.
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Ms. Beverly Hudson
October 9, 2003
Page 2
continue to be gauged, but will not be included m the dataset used lo .determine the
potentiometric surface for the B-zone (Figure 3).
Figures 2 and 3 show the cone of depression that exists around the pumping well (PW-01) and
indicate that, outside of the zone of influence, groundwater flow is generally to the northeast and
south-southwest. The high variability in the C-zone groundwater elevations indicates that these
wells are screened in isolated fracture zones within the bedrock, as seen on Figure 4.
Phenolic Analytical Results
Each groundwater sample was analyzed for 2,4-dichlorophenol and pentachlorophenol using the
United States Environmental Protection Agency (USEPA) Method 8270C-Select Ion
Monitoring. RETEC personnel validated the groundwater analytical results and applied the
necessary data qualifiers, as summarized in Table 2. A complete copy of the laboratory
analytical results and data evaluation report is provided in Appendix A.
The Record of Decision for this Site requires that groundwater meet the following cleanup
standards:
• 20 micrograms per liter (µ.g/L) for 2,4-dichlorophenol
• I µ.g/L for pentachlorophenol
As shown in Table 2, pentachlorophenol was detected in groundwater sampled from wells C-
14A, C-29B and PW-01. All of these pentachlorophenol detections exceeded the
pentachlorophenol cleanup standard of I µ.g/L; however, 2,4-dichlorophenol was not detected in
any of the samples analyzed during this event.
In accordance with the USEPA-approved Groundwater Monitoring Program, RETEC will
continue to collect quarterly samples from all wells with pentachlorophenol and/or 2,4-
dichlorophenol results above the specified cleanup levels. This sampling will continue until the
concentrations of pentachlorophenol and 2,4-dichlorophenol meet the cleanup levels for four
consecutive sampling events.
Since pentachlorophenol was detected in groundwater sampled from wells C-29B and PW-01
above the cleanup standard, these wells wi II be sampled as part of the third quarter 2003
monitoring event. In addition, an attempt to sample C-14A, which is typically a low-yielding
well and had nol supplied a sufficient sample volume since the third quarter of 2001, will be
made.
/\s part of the third quarter 2003 event, RETEC will attempt lo sample well M-04. M-04 is on
the annual sampling schedule: however, the well was once again dry in the second quarter of
2003 and has not been sampled since the second quarter of 200 I monitoring event.
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Ms. Beverly Hudson
October 9, 2003
Page 3
Dioxin and Furan Analytical Results
Dioxin and furan sampling by USEPA Method 8290 occurs on a semiannual basis in a subset of
wells. The Groundwater Monitoring Program requires dioxin and furan samples be collected
semiannually from wells that had concentrations of pentachlorophenol at or above the specified
cleanup levels during the previous sampling event, or wells with two or more quarterly
pentachlorophenol detections in the previous four quarters. Therefore, the second quarter 2003
semiannual dioxin and furan sampling event included wells Cl4A, C-29B, and PW-01. RETEC
personnel validated the groundwater analytical results and applied the necessary data qualifiers,
as summarized in Table 2. Table 3 shows the detected concentrations of dioxins and furans with
their calculated toxicity equivalent quotient (TEQ) concentration. The TEQ concentration is
calculated by multiplying the concentration of each dioxin or furan by its respective toxicity
equivalent factor. The resulting TEQ concentrations are then summed to determine the total
TEQ.
The Record of Decision for this Site requires that groundwater meet the following cleanup
standards:
• 30 picograms per liter (pg/L) for dioxins and furans
As presented in Tables 2 and 3, the dioxins HPCDD and OCDD, and the furans OCDF and
HPCDF were detected in groundwater sampled from well C-14A. No dioxins or furans were
detected in wells C-29B and PW-01. As shown in Table 3, the C-14A TEQ did not exceed the
associated cleanup standard.
In agreement with the USEPA-approved Groundwater Monitoring Program as described above,
the next dioxin and furan sampling event will occur in the fourth quarter of 2003 when C-29B
and PW-01 will be sampled for dioxins and furans. This list will be reviewed and revised based
on the third quarter 2003 sampling results.
During the fourth qua1ter of 2003, RETEC will also attempt to sample well C-14A for dioxins
and furans. This well is typically dry and has not supplied a sufficient sample volume in the
previous six monitoring events.
Operational Summary
The groundwater extraction system is currently pumping at its optimum. The aquifer's low yield
will not support a pumping rate greater than 2 gallons per minute, nor will the low yield of the
aquifer support the "pulsing" of the system.
Quarterly review of the groundwater analytical results indicates Iha! the concentrations of
C()llstitucnts or interest ;in.: riuctu:1ti11g in groundwater collected from the three rcmaming \veils
iC14J\. C-2913. and PW-01) with groundwater impact. ivlonitoring will continue in mdcr lo
dc1cr1ninc the rate al which the; levels of impact arc rluctuating.
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Ms. Beverly Hudson
October 9, 2003
Page4
If you have any questions regarding these results, please call Michael Helbling of Beazer at (412)
208-8858 or Rita Bauer at [phone].
Sincerely,
RETEC North Carolina, Inc.
Stefanie D. Young
Environmental Scientist
SY:gmd
Enclosures
RETEC North Carolina, Inc.
Rita M. Bauer
Groundwater Sampling Program Manager
cc: D. Mattison-2North Carolina Department of Environment and Natural Resources
M. Helbling-Beazer East, Inc.
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Tables
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Well ID
C-01A
C-02A
C-03A
C-04A
C-05A
C-06A
C-07A
C-08A
C-09A
C-10A
C-11A
C-12A
C-13A
C-14A
C-15A
C-25A
C-26A
C-27A
C-28A
C-30A
C-31A
C-33A
M-04
C-01B
C-02B
C-03B
C-09B
C-10B
C-11 B
C-12B
C-13B
C-14B
C-15B
C-25B
C-26B
C-27B
C-28B
C-29B
C-33B
l!l/'.J/'.;!HU
Table 1
Groundwater Elevations
First Quarter 2003
Former Koppers Company Site
Morrisville, North Carolina
Top of Casing Depth to
Gauging Date Elevation Groundwater
(feet msl) (feet)
12-Jun-03 383.06 21.62
12-Jun-03 380.76 22.52
12-Jun-03 380.21 14.08
12-Jun-03 385.31 14.75
12-Jun-03 386.59 14.13
12-Jun-03 383.90 10.31
12-Jun-03 374.30 7.90
12-Jun-03 376.34 27.82
12-Jun-03 372.98 9.57
12-Jun-03 373.88 19.46
12-Jun-03 363.28 8.93
12-Jun-03 375.00 14.77
12-Jun-03 367.31 7.78
12-Jun-03 371.13 27.59
12-Jun-03 357.08 2.22
12-Jun-03 365.52 16.38
12-Jun-03 382.12 15.64
12-Jun-03 372.10 19.01
12-Jun-03 372.40 12.18
12-Jun-03 379.11 22.82
12-Jun-03 379.98 · 15.63
12-Jun-03 354.37 8.06
12-Jun-03 368.83 13.55
12-Jun-03 383.35 100.24
12-Jun-03 381.72 10.38
12-Jun-03 380.69 17.35
12-Jun-03 374.76 17.23
12-Jun-03 373.58 100.54
12-Jun-03 363.28 9.68
12-Jun-03 375.75 13.53
12-Jun-03 367.02 4.42
12-Jun-03 371.66 26.59
12-Jun-03 357.62 1.78
12-Jun-03 364 85 16.17
12-Jun-03 382.21 26.21
12-Jun-03 372.01 33.72
12-Jun-03 373.07 6 78
12-Jun-03 369.00 30.71
12-Jun-0:J 35L.84 G.96
'l I \I 'I\( J.l 1:c J''.-;\1 k<1:1:r I til1,1,_JI 1\"/ -(J'.',' ;;,.n: ·11(J:1, ,,,,,, ,111 J r J1:,·111, ,r
Groundwater
Elevation
(feet msl)
361.44
358.24
366.13
370.56
372.46
373.59
366.40
348.52
363.41
354.42
354.35
360.23
359.53
343.54
354.86
349.14
366.48
353.09
360.22
356.29
364.35
346.31
355.28
283.11
371.34
363.34
357.53
273.04
353.60
362.22
362.60
345.07
355.84
348.68
356.00
338.29
366 29
3'.18.29
:J.15.88
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Table 1
Groundwater Elevations
First Quarter 2003
Former Koppers Company Site
Morrisville, North Carolina
Top of Casing Depth to
Well ID Gauging Date Elevation Groundwater
(feet msl) (feet)
C-34B 12-Jun-03 376.31 14.65
C-09C 12-Jun-03 374.34 11.64
C-12C 12-Jun-03 376.11 71.15
C-16C 12-Jun-03 368.37 16.82
C-19C 12-Jun-03 365.84 10.91
C-20C 12-Jun-03 378.17 23.52
C-21C 12-Jun-03 361.04 30.45
C-22C 12-Jun-03 355.24 4.66
C-32C 12-Jun-03 368.88 20.78
C-33C 12-Jun-03 353.54 12.67
C-34C 12-Jun-03 376.39 16.60
Note:
msl ::; mean sea level
l(J/'.i/:;(J(J:l
V-.1 \I 'I !0.11:C r~;\I J.::11,:r ! ialr:iql 1\-/-0'.IG'.!,;1:!00'.l\'. ;, :(;, md Oua11i~r
.RETEC
Groundwater
Elevation
(feet msl)
361.66
362.70
304.96
351.55
354.93
354.65
330.59
350.58
348.10
340.87
359.79
I (jj ;>
iiiiil ------------
Table 2
Groundwater Sampling Analytical Results
Second Quarter 2003
Former Koppers Company Site
Morrisville, North Carolina
l~ample Locat1on sample ROD
Date Units Groundwater Standard*
Method 8270C SIM
2,4-0ichlorophenol
Pentachloronhenol
Method 8290
1.2,3,4,6,7,8-HPCDD
1,2,3,4,6,7 ,8-HPCDF
1,2,3,4,7,8,9-HPCDF
1,2,3,4,7,8-HXCDD
1,2,3,4,7,8-HXCDF
1,2,3,6,7,8-HXCDD
1,2,3,6,7,8-HXCDF
1,2,3,7,8,9-HXCDD
1,2,3,7,8,9-HXCDF
1,2,3,7,8-PECDD
1,2,3,7,8-PECDF
2,3.4,6,7,8-HXCDF
2,3,4,7,8-PECDF
2,3,7,8-TCDD
2,3,7,8-TCDF
OCDD
OCDF
Total HPCDD
Total HPCDF
Total HXCDO
Total HXCDF
Total PECDO
Total PECDF
Tota!TCDD
Total TCDF
Notes:
pg/L = picograms per liter
µg/L = micrograms per liter
I ua/L I
I ua/L I
oa/L
00/L
no/L
nn/L
nn/L
on/L
oa/L
on/L
00/L
no/I
na/L
00/L
oa/L
Dail
aa/L
aa/L
aa/L
aa/L
aa/L
aa!L
aa/L
oa/L
oa/L
oa/L
nn/L
Bold values represent detections.
DUP indicates duplicate sample.
D indicates result is from a secondary dilution.
J indicates estimated result.
NA indicates not applicable.
AB indicates Rinse Blank
20
1
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
U indicn1cs compound was analyzed for, but not detected.
"Record ol Decision Groundwater Cleanup Standard
c-1 .. "' G·<OD
06/12/03 06/12/03
0.28 U • 0.2 U
96 D 31 D.
200 8.8 U
26 U 4 U
4.3 u 4.9 U
4.5 U 4.4 u
3.2 U 3.5 u
6.9 U 4.5 u
3.2 u 3.4 U
4.3 U 4.2 u
3.6 U 3.9 U
5.6 U 6.2 U
3.6 U 4.2 u
3.3 U 3.6 U
3.6 U 4.2 U
3.9 U 4.5 U
2.8 U 3.3 U
1200 30 U
84 J 8.8 U
300 , 8.8 U
52 4.9 U
11 U 4.5 u
7.5 U 3.9 U
5.6 U 6.2 u
3.6 U 4.2 u
3.9 u 4.5 u
2.8 U 3.3 U
nv-<J,
06/12/03
. I 0.21 U ·
I 17 D •
6.4 u
4.7 u
4.3 U
4.3 U
3.2 u
4.5 U
3.1 u
4.1 u
3.5 U
6.2 U
3.5 U
3.2 u
3.5 U
3.5 U
2.1 U
16 U
10 U
6,4 u
4.7 u
4.5 U
3.5 U
6.2 U
3.5 u
3.5 U
2.1 U
\\' If'''' )J[C l SIB,•J:.t!I RJlcigt1\i·03624\2003\Second Quarter
---

-

-
-
t'VY-U I • UUt" """"' 06/12/03 06/12/03
I 0.21 U I 0.21 U·
17 D I 1 U •
7.4 u 9.1 u
5.6 u 5.8 U
3.8 u 4.3 U
4.1 u 4.4 u
4.1 u 4.5 u
4.3 U 4.6 U
2.9 U 2.9 u
4 U 4.2 u
3.1 u 3.3 U
5.6 U 5.9 U
3.7 U 4.5 U
3 U 3 U
3.7 U 4.5 U
3.2 U 3.4 U
2.1 U 2.5 U
15 U 14 u
9 U 10 U
7.4 u 9.1 u
5.6 U 5.8 U
4.3 U 4.6 U
4.1 u 4.5 U
5.6 U 5.9 u
3.7 U 4.5 U
3.2 u 3.4 U
2.1 u 2.5 U
1 ol 1
- - - - ----- - -- --
Table 3
Calculation of Toxicity Equivalent Quotients for Dioxins/Fu rans
Second Quarter 2003
Former Koppers Company Site
Morrisville, North Carolina
ROD C-14A C-298
-
PW-01 Analyte TEF Units Groundwater Standard* Result TEO Result TEO Result TEO
1.2,3.4.6.7,8-HPCDD 0.01
1.2.3,4,6,7,8-HPCDF 0.01
1.2.3,4,7,8,9-HPCDF 0.01
1,2.3.4,7,8-HXCDD 0.1
1.2,3,4,7,8-HXCDF 0.1
1,2,3.6,7,8 HXCDD 0.1
1.2.3.6.7,8-HXCDF 0.1
1.2,3.7,8,9-HXCDD 0.1
1.2.3,7,8,9-HXCDF 0.1
1,2.3.7.8-PECDD 0.5
1.2.3.7.8-PECDF 0.05
2.3.4,6.7,8 HXCDF 0.1
2.3.4,7.8-PECDF 0.5
2.3.7,8-TCDD 1
2,3,7,8-TCDF 0.1
OCDD 0.001
OCOF 0.001
Total HPCDD 0
Total HPCDF 0
Total HXCDD 0
Total HXCDF 0
Total PECDD 0
Total PECDF 0
Total TCDD 0
Total TCDF 0
Totals:
Notes:
pg.IL = picograms per liter
TEF = Toxicity Equivalent Factor
TEO= Toxicity Equivalent Quotient
Bold values represent detections.
DUP indicates duplicate sample.
J indicates estimated result.
NA indicates not applicable.
n, L
nc L
n, L
n, L
nn L
nn L
nn/L
nn/L
n, L
n,
n, L
n, L
n, L
n, L
n, L
n, L
nn/L
nnil
nn/L
nn/L
nn/L
nn/L
nrnL
nn/L
nrnl
I
U indicates compound was analyzed for, but not detected.
NA 200
NA 26 U
NA 4.3 U
NA 4.5 U
NA 3.2 U
NA 6.9 U
NA 3.2 U
NA 4.3 U
NA 3.6 U
NA 5.6 U
NA 3.6 U
NA 3.3 U
NA 3.6 U
NA 3.9 U
NA 2.8 U
NA 1200
NA 84 J
NA 300
NA 52
NA 11 U
NA 7.5 U
NA 5.6 U
NA 3.6 U
NA 3.9 U
NA 2.8 U
30
Laboratory results that were Li-qualified were assigned a value of O for this calculation.
·Record of Decision Groundwater Cleanup Standard
\01912003
'.".':\? ROJ::CTS\Seazer Raleigh\7-03624\2003\Second Ouaner
2 8.8 U 0 6.4 U 0
0 4 U 0 4.7 U 0
0 4.9 U 0 4.3 U 0
0 4.4 U 0 4.3 U 0
0 3.5 U 0 3.2 U 0
0 4.5 U 0 4.5 U 0
0 3.4 U 0 3.1 U 0
0 4.2 U 0 4.1 U 0
0 3.9 U 0 3.5 U 0
0 6.2 U 0 6.2 U 0
0 4.2 U 0 3.5 U 0
0 3.6 U 0 3.2 U 0
0 4.2 U 0 3.5 U 0
0 4.5 U 0 3.5 U 0
0 3.3 U 0 2.1 U 0
1.2 30 U 0 16 U 0
0.084 8.8 U 0 10 U 0
0 8.8 U 0 6.4 U 0
0 4.9 U 0 4.7 U 0
0 4.5 U 0 4.5 U 0
0 3.9 U 0 3.5 U 0
0 6.2 U 0 6.2 U 0
0 4.2.U 0 3.5 U 0
0 4.5 U 0 3.5 u 0
0 3.3 U 0 2.1 u 0
I 3.284 I 0 0
-- --
.RETEC
PW-01-DUP
Result TEO
7.4 U 0
5.6 U 0
3.8 U 0
4.1 U 0
4.1 U 0
4.3 U 0
2.9 U 0
4 U 0
3.1 U 0
5.6 U 0
3.7 U 0
3 U 0
3.7 U · 0
3.2 U 0
2.1 U 0
15 U 0
9 U 0
7.4 U 0
5.6.U 0
4.3 U 0
4.1 U 0
5.6 U 0
3.7 U 0
3.2 U 0
2.1 U 0
0
1 of 1
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GROUNDWATER MONITORING PROGRAM
BEAZER EAST, INC.
BEA.Zl-03624-103
DATC 7 / 16/03
/
/ ()
200
LEGEND:
MONITORING WELL
RAILROAD TRACKS
FENCELINE
DRAINAGE/STREAM
PROPERTY BOUNDARY -BEAZER
EAST, INC.
PROPERTY BOUNDARY -UNIT
STRUCT\JRES INC.
PROPERTY BOUNDARY -UNKNOWN
400 ~--SCALE: 1 "=400'
♦C22C
SITE MAP
FORMER KOPPERS COMPANY
MORRISVILLE, NORTH CAROLINA
LA.YOVT SITE ~AP FIGURE: 1
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346.31
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GROUNDWATER MONITORING PROGRAM
BEAZER EAST, INC
BEAZ?-03624-103
[)AT[; 7/17/03 .3624CH02
/
Q
A-ZONE GROUNDWATER CONTOURS
JUNE 12, 2003
FORMER KOPPERS COMPANY
MORRISVILLE, NORTH CAROLINA
L.ATOUT: A-ZONE FIGURE: 2
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345.88
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GROUNDWATER MONITORING PROGRAM
BEAZER EAST, INC .
BEAZl-03624-103
DATE: 7/17/QJ fll(: J62<1CHOJ
/
Q
B-ZONE GROUNDWATER CONTOURS
JUNE 12, 2003
FORMER KOPPERS COMPANY
MORRISVILLE, NORTH CAROLINA
LAYOUT: 8-ZONE FIGURE: 3
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GROUNDWATER MONITORING PROGRAM
BEAZER EAST, INC .
BEAZl-03624-103
OAT[: 7 / 16/0J J624CH0"
/
J5J.7J
LEGEND:
MONITORING WELL
INFERRED GROUNDWATER CONTOUR
GROUNDWATER ELEVATION
AT WELL (FEET MSL)
~
200 0 400
l'""'r-
. SCALE: 1 "=400'
C-ZONE GROUNDWATER CONTOURS
JUNE 12, 2003
FORMER KOPPERS COMPANY
MORRISVILLE, NORTH CAROLINA
LAYOUT: C-ZONE FIGURE: 4
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Appendix A
Second Quarter 2003 Laboratory Analytical Results
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Final Data Evaluation Report
Site: Beazer/Raleigh
Program/Event: CERCLA Groundwater Monitoring/02-03
Laboratory: Severn Trent Laboratories, Inc. -Pittsburgh and
West Sacramento
Laboratory Project Numbers: C3F130255
Analyses: Pentachlorophenol and 2,4-Dichlorophenol by SW-
846 Method 8270C SIM
Dioxins and Furans by SW-846 Method 8290
Evaluator: Gregory A. Malzone
Date: June 30, 2003
The Raleigh Q2-03 data report from Severn Trent Laboratories, Inc. was evaluated using
the USEPA National Functional Guidelines and USEPA method specifications. Each
issue requiring comment and/or data qualification is addressed below.
II
Sample Collection, Receipt, and Log-In
Sample Collection: Well M-04 did not yield sufficient water volume for sample
collection.
Sample Receipt: Samples were received by the laboratory in good condition and
within the optimal temperature range of 2-6° C.
Pentachlorophenol and 2,4-Dichlorophenol by SW-
846 Method 8270C SIM
Dilutions/Reporting Limits: Samples PW-0 I, PW-0 I _DUP I, C-298, and C-I 4A
required analyses at di Jut ions because pcntachlorophenol exceeded the calibration
range. For this reason, the pentachlorophenol results rrnm the original analyses
were qualil'ied "E" by the laboratory. The pcntachlornphenol results rrom the
secondary dilutions were acccptahle and rnusl he used. ;\JI other results must he
Beazer/Raleigh : Cliem Work Product
Private and Confidemial Q2-03
reported from the original analyses
The ten-fold dilution required for C-14A diluted out the surrogates. However, the
surrogate recoveries were acceptable in the original (undiluted) run._ No data
qualifications were required. -·
Reporting limits were adjusted to reflect extraction volume. The 2,4-
dichlorophenol reporting limits for samples C-14A, PW-01, and PW-Ol_DUP I
was slightly elevated after adjusting for the extraction volume. There were no
positive 2,4-dichlorophenol results equal to or greater than 0.20 µ.g/L in the
samples.
Matrix Spike Recoveries: Matrix Spike and Matrix Spike Duplicate (MS/MSD)
analyses were perforrned on sample PW-0 I. The pentachlorophenol spike added
was less than 25% of the original sample result. Validation action was not
required.
Ill Dioxins and Furans by SW-846 Metho_d 8290
Data Reporting: Results reported above the estimated detection limit and below
the lowest calibration standard were qualified "J," as an estimated concentration,
because of the uncertainty below the lowest calibration standard.
IV Field Duplicate Samples
Samples PW-01 and PW-0 l_DUPI were the primary and field duplicate samples
collected for this sampling event. No data qualifications are required based on the
relative percent difference (RPD) of field duplicate sample data alone. However,
the positive results are presented in the table below to evaluate precision and
sample homogeneity. An RPD greater than the advisory limit of 30% is an
indication of sample heterogeneity with respect to that compound, poor field
precision and/or poor laboratory precision. Field and laboratory precision were
acceptable.
Field Duplicate Comparison
Raleigh 02-03
Parameter PW01
Pentachlorophenol 17 µq/L
1:.-11 /,A D-/i./ (, 2 4/IJ11 /(/I!,.,,, llf)IS_ 2 ( I( I.ill/ 1\ _ Q 2 -0 3
2
PW-01 DUP1
17 µ□IL
RPD (%)
0
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SEVERN
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STL
ANALYTICAL REPORT
PROJECT NO. BEAZER
Raleigh, Mo=isville
Lot#, C3F130255
Gregory Malzone
The RETEC Group Inc
SEVERN TRENT LABORATORIES, INC.
Veronica Bortot
Project Manager
June 24., 2003
Severn Trent Laboratories, Inc.
STL Pittsburgh • 450 William Pitt Way, Pittshurgh, P/\ ! 5238
Tel [phone] fax [phone] • 1•.ww.sll-inc.corn
Sample Receiving:
CASE NARRATIVE
THE RETEC GROUP
Raleigh, Morrisville
STL Lot# C3FI 30255
STL Pittsburgh, PA received samples on June 13, 2003 in good condition. The cooler
was within the proper temperature range
GC/MS Semivolatiles SIM:
The reporting limits were adjusted according to the amount of sample extracted.
Due to the concentration of target compounds detected, several samples were analyzed at
a dilution.
The dilution of sample C-14A had the surrogates diluted out.
The matrix spike and matrix spike duplicate recovered outside of the control limits for
pentachlororphenol
Dioxins:
STL West Sacramento, CA performed the dioxin analysis. All results area included in
the report.
There were no problems associated with the analysis.
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METHODSSUMMARY
C3P130255
ANALYTICAL
_P~ARAME==~T~E~R~---------------------~ME~TH_O~D~----
Dibenzodioxins and Dibenzofurans, HRGC/HRMS
8270C (SIM)
References:
SW846 8290
SW846 8270C SIM
PREPARATION
METHOD
SW846 8290
SW846 3520C
SW846 "Test Methods for Evaluating Solid waste, Physical/Chemical
Methods 11 , Third Edition, November 1986 and its updates.
SAMPLE SUMMARY
C3F1302SS
WO# SAMPLE# CLIENT SAMPLE ID
FQH4L 001 RB-01
FQJQJ 002 PW-01
FQJQM 003 PW-01 DUPl
FQJQN 004 C-29B
FQJQQ oos· C-14A
NOTE(S)
• The analytical results of the samples listed iibOYC arc presented on the following pases.
-Al! calc::ulations are performed before rounding to avoid round-off errors in calculated results.
• Results noted as "NDft were not detected at or above the stated limit.
-This report must not be reproduced, except in full, without the wriuen approval of the laboratory.
-Results for lhe following parameters arc never reponed on a dry weight buis: color, corros.ivity. density, flashpoint, ignltability, layers, odor.
paint flit.er test, pH, porosity pressure, reactivity, red ox potential, specific gravity, spot tests, solids, solubility, tempcn.ture, viscosity, aOO weight.
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SAMPLED SAMP
DATE TIME I 06/12/03 11:00
06/12/03 11:30
06/12/03 11'30 I 06/12/03 13:00
06/12/03 13:30
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------Chain of
Custody Record
STL-4124 !0901)
Client & {, /_,:? /
,va,~,~ f?pJ:ev A{_
c11,. Ccu'-C-e,,,,,.../ v;'.0_)'on4z
Pr'6ame and Locat~ate)
. C'av-~lo,i(/,-,, k IC
Conrrac('Purchase Order/Quote No. ,._...
?x__c. z, 7 -=~v,24 -.cCt(
Sample /.0. No. and Descnptfon Oare
(Containers for eacn sample may be combined on one line)
iZ'--6 · ol ro/ fZ,{ .,3
r;,J,;0/
.!pl,J-c> I OvPl
;US I
fl,1~0 I
-----------_SEVERN
TRENT/ STL -Prlf
Severn Trent Laboratories, Inc.
o~ /?A v3 Cham of Custody Number
Proje~ger l00043 --,P-cu&
TelephO~JYj~ (A§~(e)/F/4:'zz_ Lab Nilmber l of _j_ Page
Analysis (Attach list if
S1/8[!,~{C/ A 1 • "' iiCo~" ,/ l more space 1s needed
r,_.,,,.,T /b'J ~ Carrser~i!I N~ Speciaf Instructions/ 1
f\J' Conditions of Receipt
Containers &
Matnx Preservatives •
J ~ 0 i r ~5 C Time • ~ 0 • ~ C -~ • ~~ ~ • ~ 0 r z
/llD X z )G
J.1-:::;o 2-
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{
('_ 'Z-"7r-2, 1300 z ..
e-14A • (2,2,t) -~ .Pl) \/,;nf /, I ), (
' _) •
Poss1!Jfe Hazard /dentdicauon I Sample Disposal (A fae may tie assessed I( samples are reta,ned
tlfunknown D Rerurn To Client • }j Disposal By LaD D Archive For Monrris longer than I month)
D No,1-Hazara D FlammatJ/a 0 Skin Im/ant D Poison B
Turn Around Time Required {
l".J Oth,k ~~ L QC Requirements (Spec1ty)
0 2~ ho~•rs D 48 Hcurs D 7 Days 0 14 Days 0 21 Days ] Date
1
Time
i/WJz/ts I 77<Tb 1. Received /1
~r,quisheO ~ /, ,f '/)~ h, (2"i-ut7 I r,1; 1 c:-<--2 Rec1/Z j ~ ~ /-'' -""·t""(_j () j Date
1
Time
11 'A.1 ~ .1..1./1.
:1 f1,.1,nr1w•,lw<f Ry
1
Date / Time 3. Received By l Oare ('"'
OISTF!13UT/ON: \W-/ITE. Returned /0 Client with Report; CANARY· Slays with /he Sample; PINK· Field Copy
Lot-Sample 11 ... : C3Fl30255-001
Date Sampled ... : 06/12/03
Prep Date ...... : 06/17/03
Prep Batch 11 ... : 3168365
Dilution Factor: 1.03
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
SURROGATE
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
THE RETEC GROUP INC
Client Sample ID: RB-01
GC/MS Semivolatiles
Work Order 11 ... : FQH4LlAA
Date Received .. : 06/13/03
Analysis Date .. : 06/19/03
Matrix ......... : WATER
MS Run II ....... : 3168204
Method ......... : SW846 8270C SIM
REPORTING
RESULT LIMIT UNITS
ND 0.21 ug/L
ND 1.0 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
59 (30 -121)
55 (11 -119)
57 (39 -115)
60 (37 -115)
61 (41 -115)
64 ( 4 0 -115)
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THE RETEC GROUP INC
Client Sample ID, RB-01
Trace Level Organic Compounds
Lot-Sample# ... : C3Fl30255-001 · Work Order # ••. : FQH4LlAC
Date Sampled ... : 06/12/03 Date Received .. , 06/13/03
Prep Date ...... : 06/19/03 Analysis Date .. , 06/19/03
Prep Batch# ... : 3170407
Dilution Factor: 1
DETECTION
PARAMETER RESULT LIMIT
2,3,7,8-TCDD ND 3.4
Total TCDD ND 3.4
1,2,3,7,8-PeCDD ND 5.9
Total PeCDD ND 5.9
1,2,3,4,7,8-HxCDD ND 4.4
1,2,3,6,7,8-HxCDD ND 4.6
1,2,3,7,8,9-HxCDD ND 4.2
Total HxCDD ND 4.6
1,2,3,4,6/7,8-HpCDD ND 9.1
Total HpCDD ND 9.1
OCDD ND 14
2,3,7,8-TCDF ND 2.5
Total TCDF ND 2.5
1,2,3,7,8-PeCDF ND 4.5
2,3,4,7,8-PeCDF ND 4.5
Total PeCDF ND 4.5
1,2,3,4,7,8-HxCDF ND 4.5
1,2,3,6,7,8-HxCDF ND 2.9
2,3,4,6,7,8-HxCDF ND 3.0
1,2,3,7,8,9-HxCDF ND 3.3
Total HxCDF ND 4.5
1,2,3,4,6,7,8-HpCDF ND 5.8
1,2,3,4,7,8,9-HpCOF ND 4.3
Total HpCDF ND 5.8
OCDF ND 10
PERCENT RECOVERY
INTERNAL STANDARDS RECOVERY LIMITS
13C-2,3,7,8-TCDD 67 (40 -l35)
13C-l,2,3,7,8-PeCDD 71 (40 135)
13C-l,2,3,6,7,8-HxCDD 87 (40 135)
13C-l,2,3,4,6,7,8-HpCDD 65 (40 135)
13C-OCDD 58 (40 135)
13C-2,3,7,8-TCDF BO (40 -135)
13C-l,2,3,7,8-PeCDF 73 (40 -135)
13C-l,2,3,4,7,8-HxCDF Bl (40 135)
13C-l,2,3,4,6,7,8-HpCDF 75 (4 0 -135)
Matrix ......... : WATER
MS Run# ....... : 3170162
UNITS METHOD
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L .. SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 82 90
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
Let-Sample# ... , C3Fl30255-002
Date Sampled ... , 06/12/03
Prep Date ...... , 06/17/03
Prep Batch# ... , 3168365
Dilution Factor: 1.04
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
SURROGATE
Nitrobenzene-dS
Terphenyl -d14
2-Fluorobiphenyl
2-Fluorophenol
Phenol-dS
2,4,6-Tribromophenol
NOTE(S},
THE RETEC GROUP INC
Client Sample ID, PW-01
GC/MS Semivolatiles
Work Order# ... : FQJQJ1AA
Date Received .. , 06/13/03
Analysis Date .. , 06/19/03
Matrix ......... , WATER
MS Run# ....... , 3168204
Method ......... , SW846 8270C SIM
REPCRTING
RESULT LIMIT UNI-TS
ND 0. 21 ug/L
19 E LO ug/L
PERCENT RECOVERY
RECOVERY LIMITS
61 (30 -121)
56 (11 -119)
58 I 39 • 115)
62 (37 -115)
62 (41 115)
67 (40 -115)
E Estimated result. Result concentration exceeds the calibration range.
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Lot-Sample# ... : C3Fl30255-002
Date Sampled ... : 06/12/03
Prep Date ...... : 06/17/03
Prep Batch# ... : 3168365
Dilution Factor: 3.12
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
SURROGATE
Nitrobenzene-dS
Terpheny l -dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-dS
2,4,6-Tribromophenol
THE RETEC GROUP DIC
Client Sample ID, PW-01
GC/MS Semivolatiles
work Order II ... : FQJQJ2.AA
Date Received .. , 06/13/03
Analysis Date .. , 06/19/03
Matrix ......... : WATER
MS Run# ....... : 3168204
Method ......... : SW846 8270C SIM
REPORTING
RESULT LIMIT UNITS
ND 0.62 ug/L
17 3. l ug/L
PERCENT RECOVERY
RECOVERY LIMITS
63 (30 -121)
58 (11 -119)
64 I 39 -115)
62 (37 -115)
65 (41 -115)
67 (40 -115)
THE RETEC GROUP INC
Client Sample ID, PW-01
Trace Level Organic Compounds
Lot-Sample# ... , C3F130255-002
Date Sampled ... , 06/12/03
Prep Date ...... , 06/19/03
Prep Batch# ... , 3170407
Dilution Factor: 1
PARAMETER
2,3,7,8-TCDD
Total TCDD
1,2,3,7,8-PeCDD
Total PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
Total HxCDD
1,2,3,4,6,7,8-HpCDD
Total HpCDD
OCDD
2,3,7,8-TCDF
Total TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
Total PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
Total HxCDF
1,2,3,4,6,7,8-HpCDF
1_, 2 , 3 , 4 , 7, 8, 9-HpCDF
Total HpCDF
OCDF
INTERNAL STANDARDS
13C-2,3,7,8-TCDD
13C-l,2,3,7,8-PeCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-1,2,3,7,8-PeCDF
13C-1,2,3,4,7,8-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
Work Order# ... , FQJQJ1AE
Date Received .. , 06/13/03
Analysis Date .. , 06/19/03
DETECTION
RESULT LIMIT
ND 3.5
ND 3.5
ND 6.2
ND 6.2
ND 4.3
ND 4.5
ND 4.1
ND 4.5
ND 6.4
ND 6.4
ND 16
ND 2.1
ND 2.1
ND 3.5
ND 3.5
ND 3.5
ND 3.2
ND 3.1
ND 3.2
ND 3.5
ND 3.5
ND 4.7
ND 4.3
ND 4.7
ND 10
PERCENT RECOVERY
RECOVERY LIMITS
80 (40 -135)
80 (40 -135)
98 (40 -135)
78 (40 -135)
70 (40 -135)
94 (40 135)
87 ( 40 -135)
93 (40 -135)
86 (40 -135)
MatriX ......... : WATER
MS Run# ....... , 3170162
UNITS METHOD
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L .. SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 82 90
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
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THE RETEC GROUP INC
Client Sample ID: PW-01 DOPl
GC/MS Semivolatiles
Lot-Sample# ... : C3Fl30255-003 work Order# ... : FQJQMlAA
Date Received .. : 06/13/03
Analysis Date .. : 06/19/03 Date Sampled ... : 06/12/03
Prep Date ...... : 06/17/03
Prep Batch# ... : 3168365
Matrix ......... : WATER
MS Run# ....... , 3168204
Dilution Factor: 1.04 Method ......... : SW846 8270C SIM
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
SURROGATE
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
NOTE(S):
RESULT
ND
21 E
PERCENT
RECOVERY
56
54
52
52
53
63
E Estimat.ed resuli. ~suit concentration exceeds the calibration range:.
REPORTING
LIMIT UNITS
0.21 ug/L
1.0 ug/L
RECOVERY
LIMITS
(30 -121)
(11 -119)
I 39 -115)
(37 -115)
(41 -115)
(40 -115)
THE R.ETBC GROUP INC
Client Sample ID, PW-01 DIJPl
GC/MS Semivolatiles
Lot-Sample# ... , C3Fl30255-003 Work Order# ... , FQJQM2AA
Date Received .. , 06/13/03
Analysis Date .. , 06/19/03
Matrix ......... , WATER
Date Sampled ... , 06/12/03
Prep Date ...... , 06/17/03
Prep Batch# ... , 3168365
Dilution Factor: 3.12
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
SURROGATE
Nitrobenzene-ds
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
MS Run# ....... , 3168204
Method ......... , SW846 8270C SIM
REPORTING
RESULT LIMIT UNI-TS
ND 0.62 ug/L
17 3.1 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
60 {30 -121)
58 {11 -119)
59 {39 -115)
58 {37 -115)
61 (41 115)
62 { 4 0 -115)
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THE RETEC GROuP INC
Client Sample ID, PW-01 DUPl
Trace Level Organic Compounds
Lot-Sample# ... , C3Fl30255-003 Work Order# ... , FQJQMlAC
Date Received .. , 06/13/03
Analysis Date· .. , 06/19/03
Date Sampled ... , 06/12/03
Prep Date ...... , 06/19/03
Prep Batch# ... , 3170407
Dilution Factor: 1
DETECTION
PARAMETER RESULT LIMIT
2,3,7,8-TCDD ND 3.2
Total TCDD ND 3.2
1,2,3,7,8-PeCDD ND 5.6
Total PeCDD ND 5.6
1,2,3,4,7,8-HxCDD ND 4.1
1,2,3,6,7,8-HxCDD ND 4.3
1,2,3,7,8,9-HxCDD ND 4.0
Total HxCDD ND 4.3
1,2,3,4,6,7,8-HpCDD ND 7.4
Total HpCDD ND 7.4
OCDD ND 15
2,3,7,8-TCDF ND 2.1
Total TCDF ND 2.1
1,2,3,7,8-PeCDF ND 3.7
2,3,4,7,8-PeCDF ND 3.7
Total PeCDF ND 3.7
1,2,3,4,7,8-HxCDF ND 4.1
1,2,3,6,7;8-HxCDF ND 2.9
2,3,4,6,7,8-HxCDF ND 3.0
1,2,3,7,8,9-HxCDF ND 3.1
Total HxCDF ND 4.1
1,2,3,4,6,7,8-HpCDF ND 5.6
1,2,3,4,7,8,9-HpCDF ND 3.8
Total HpCDF ND 5.6
OCDF ND 9.0
PERCENT RECOVERY
INTERNAL STANDARDS RECOVERY LIMITS
13C-2,3,7,8-TCDD 7B (40 -135)
13C-l,2,3,7,B-PeCDD Bl (40 -135)
13C-l,2,3,6,7,B-HxCDD 100 (40 135)
13C-l,2,3,4,6,7,8-HpCDD 7B (40 -135)
13C-OCDD 69 (40 -135)
13C-2,3,7,8-TCDF 94 (4 0 135)
13C-l,2,3,7,B-PeCDF BB (40 -135)
13C-l,2,3,4,7,B-HxCDF 95 (40 135)
13C-l,2,3,4,6,7,B-HpCDF BB (40 -135)
Matrix ......... , WATER
MS Run# ....... , 3170162
UNITS METHOD
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SWB46 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
·pg/L SW846 8290
pg/L SW846 8290
Lot-Sample# ... , C3Fl30255-004
Date Sampled ... , 06/12/03
Prep Date ...... , 06/17/03
Prep Batch# ... , 3168365
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Pentacblorophenol
SURROGATE
Nitrobehzene-ds
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-dS
2,4,6-Tribromophenol
NOTE(S),
THE RETEC GROUP INC
Client Sample ID, C0 29B
GC/MS Sernivolatiles
work Order# ... , FQJQNlAA
Date Received .. , 06/13/03
Analysis Date .. , 06/19/03
Matrix ......... , WATER
MS Run # ....... , 3168204
Method ......... , SW846 8270C SIM
REPORTING
RESULT LIMIT UNITS
ND 0.20 ug/L
41 E LO ug/L
PERCENT RECOVERY
RECOVERY LIMITS
55 (30 -121)
39 (11 -ll.9)
57 (39 -115)
58 (37 -ll.5)
SB (41 -115)
62 (4 0 -115)
E Estimated result. Result concentration exceeds the calibration range.
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Lat-Sample# ... , C3Fl30255-004
Date Sampled ... , 06/12/03
Prep Date ...... , 06/17/03
Prep Batch# ... , 3168365
Dilution Factor: 5
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
SURROGATE
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluoro'phenol
Phenol-d5
2,4,6-Tribromophenol
THE RETEC GROUP INC
Client Sample ID, C-29B
GC/MS Semivolatiles
Work Order# ... , FQJQN2AA
Date Received .. , 06/13/03
Analysis Date .. , 06/19/03
Matrix. __ ...... :
MS Run# ....... ,
Method ......... , SW846 8270C SIM
REPORTING
RESULT LIMIT UNITS
ND 1.0 ug/L
31 5.0 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
57 (30 -121)
39 Ill 119)
59 (39 -115)
62 (3 7 115)
62 (41 115)
56 (40 -115)
WATER
3168204
THE RETEC GROUP INC
Client Sample ID: C-29B
Trace Level organic Colllpounds
·Lot-Sample# ... : C3Fl30255-004 Work Order# ... : FQJQNlAC
Date Received .. : 06/13/03
Analysis Date .. : 06/19/03
Date Sampled ... : 06/12/03
Prep Date ...... : 06/i9/03
Prep Batch# ... : 3170407
Dilution Factor: 1
DETECTION
PARAMETER RESULT LIMIT
2,3,7,8-TCDD ND 4.5
Total TCDD ND 4.5
1,2,3,7,8-PeCDD ND 6.2
Total PeCDD ND 6.2
1,2,3,4,7,8-HxCDD ND 4.4
1,2,3,6,7,8-HxCDD ND 4.5
1,2,3,7,8,9-HxCDD ND 4.2
Total HxCDD ND 4.5
1,2,3,4,6,7,8-HpCDD ND 8.8
Total HpCDD ND 8.8
OCDD ND 30
2,3,7,8-TCDF ND 3.3
Total TCDF ND 3.3
1,2,3,7,8-PeCDF ND 4.2
2,3,4,7,8-PeCDF ND 4.2
Total PeCDF ND 4.2
1,2,3,4,7,8-HxCDF ND 3.5
1,2,3,6,7,~-HxCDF ND 3.4
2,3,4,6,7,8-HxCDF ND 3.6
1,2,3,7,8,9-HxCDF ND 3.9
Total HxCDF ND 3.9
l,2,3,4,6,7,8-HpCDF ND 4.0
1,2,3,4,7,8,9-HpCDF ND 4.9
Total HpCDF ND 4.9
OCDF ND 8.8
PERCENT RECOVERY
INTERNAL STANDARDS RECOVERY LIMITS
13C-2,3,7,8-TCDD 86 (40 135)
13C-l,2,3,7,8-PeCDD 84 (40 -135)
13C-l,2,3,6,7,8-HxCDD 102 (40 -135)
13C-l,2,3,4,6,7,8-HpCDD 84 (40 -135)
13C-OCDD 79 (40 135)
13C-2,3,7,8-TCDF 97 (40 135)
13C-l,2,3,7,8-PeCDF 90 (40 135)
13C-l,2,3,4,7,8-HxCDF 93 (40 135)
13C-l,2,3,4,6,7,8-HpCDF 91 (4 0 135)
Matrix ......... : WATER
MS Run# ....... : 3170162
UNITS METIIOD
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 82 90
pg/L SW846 8290
pg/L sw04·5 8290
pg/L SW846 8290
pg/L. SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
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Let-Sample# •.. : C3Fl30255-005
Date Sampled ... : 06/12/03
Prep Date ...... : 06/17/03
Prep Batch# ... : 3168365
Dilution Factor: 1.39
PARAMETER
2,4-Dichlorophenol
Pelltachlorophenol
SURROGATE
Nitrobenzene-d5
Terphenyl-d14
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
NOTE (S) :
THE RETEC GROUP INC
Client Sample ID: C-l.4A
GC/MS Semivolatiles
Work Order # •.• : FQJQQlAA
Date Received .. : 06/13/03
Analysis Date .. : 06/19/03
Matrix ......... , WATER
MS Run# ....... : 3168204
Method ......... : SW846 8270C SIM
REPORTING
RESULT LIMIT UNI-TS
ND 0.28 ug/L
1.20 E 1..4 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
50 (30 -121)
34 (11 -119)
53 (39 -115)
53 (37 -115)
51 (41 -115)
56 (40 -115)
E Estimated result. Result concentra1ion exceeds the calibration nmgc.
Lat-Sample# ... , C3Fl30255-005
Date Sampled ... , 06/12/03
Prep Date ...... , 06/17/03
Prep Batch# ... , 3168365
Dilution Factor: 13.89
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
SURROGATE
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorobiphenyl
2-Flu?rophenol
Phenol-d5
2,4,6-Tribromophenol
NOTE (S) ,
NC Toe recovery and/or RPO were not calculated.
THE RETEC GROUP INC
Client Sample ID, C-14A
GC/MS Semivolatiles
Work Order# ... , FQJQQ2AA
Date Received .. , 06/13/03
Analysis Date .. , 06/19/03
Matrix ......... : WATER
MS Run # ....... , 3168204
Method ......... , SW846 8270C SIM
REPORTING
RESULT LIMIT UNITS
ND 2.8 ug/L
96 14 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
NC,DIL (30 121)
NC,DIL (11 -119)
NC,DIL (39 115)
NC,DIL (37 -115)
NC,DIL (41 -115)
NC,DIL (40 115)
DIL The concentration is estimated or not reported due to dilution or the presence of intcrferint! ana\ytes.
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THE RETEC GROUP INC
Client Sample ID, C-14A
Trace Level Organic Compounds
Lot-Sample# ... , C3Fl30255-005
Date Sampled ... , 06/12/03
Prep Date ...... , 06/19/03
Prep Batch# ... , 3170407
Dilution FaCtor: 1
PARAMETER
2,3;7,8-TCDD
Total TCDD
1,2,3,7,8-PeCDD
Total PeCDD
1,2,3,4,7,B-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
Total HxCDD
1,2,3,4,6,7,8-HpCDD
Total HpCDD
OCDD
2,3,7,8-TCDF
Total TCDF
1,2,3,7,8"-PeCDF
2,3,4,7,8-PeCDF
Total PeCDF
1,2,3,4,7,B-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCOF
Total HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
Total HpCDF
OCDF
INTERNAL STANDARDS
13C-2,3,7,8-TCDD
13C-l,2,3,7,8-PeCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-0CDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-l,2,3,4,7,B-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
NOTE(S),
J Estimatt:d result. R~sult is kss than 1he rcponlng limit.
Work Order# ... , FQJQQlAC
Date Received .. , 06/13/03
Analysis Date .. , 06/19/03
DETECTION
RESULT LIMIT
ND 3.9
ND 3.9
ND 5.6
ND 5.6
ND 4.5
ND 6.9
ND 4.3
ND 11
200
300
1200
ND 2.8
ND 2.8
ND 3.6
ND 3.6
ND 3.6
ND 3.2
ND 3.2
ND 3.3
ND 3.6
ND 7.5
ND 26
ND 4.3
52
84 J
PERCENT RECOVERY
RECOVERY LIMITS
73 (40 -135)
75 (40 -135)
95 (40 135)
73 (40 135)
65 (4 0 135)
85 (40 135)
79 (40 135)
86 (40 135)
BO (40 135)
Matrix ......... , WATER
MS Run It •••.... , 3170162
UNITS METHOD
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 82 90
pg/L SW846 8290
pg/L SW846 82 90
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
pg/L SW846 8290
METHOD BLANK REPORT
GC/MS Semivolatiles
Client Lot# ... : C3F130255 Work Order# ... : FQM7H1AA
MB Lot-Sample#: C3F170000-365
Analysis Date .. : 06/19/03
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
SURROGATE
Nitrobenzene-d5
Terphenyl-d14
2-Fluorobiphenyl
2-Flu6rophenol
Phenol-d5
2,4,6-Tribromophenol
NOTE(S):
Prep Date ...... : 06/17/03
Prep Batch# ... : 3168365
REPORTING
RESULT LIMIT
ND 0.20
ND 1.0
PERCENT RECOVERY
RECOVERY LIMITS
60 (30 -121)
56 (11 -119)
59 (39 115)
59 (37 -115)
62 (41 -115)
63 (40 115)
Calculations are perfonned before rounding to avoid round--Off errors in calclllated results.
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Matrix ......... : WATER I
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UNITS METHOD
ug/L SWB46 B270C SIM
ug/L SW846 B270C SIM I
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METHOD BLANK REPORT
Trace Leve1 organic Compounds
C1ient Lot# ... , C3Fl30255 work Order# ... , FQT6KlAA
MB Lot-Sample#, G3Fl90000-407
Prep Date ...... , 06/19/03
Analysis Date .. , 06/19/03 Prep Batch # ... , 3170407
Dilution Factor: 1
DETECTION
PARAMETER RESULT LIMIT UNITS
2,3,7,8-TCDD ND 3.6 pg/L
Total TCDD ND 3.6 pg/L
1,2,3,7,8-PeCDD ND 5.6 pg/L
Total PeCDD ND 5.6 pg/L
1,2,3,4,7,8-HxCDD ND 4.4 pg/L
1,2,3,6,7,8-HxCDD ND 4.5 pg/L
1,2,3,7,8,9-HxCDD ND 4.2 pg/L
Total HxCDD ND 4.5 pg/L
1,2,~,4,6,7,8-HpCDD ND 6.6 pg/L
Total HpCDD ND 6.6 pg/L
OCDD ND 12 pg/L
2,3,7,8-TCDF ND 2.2 pg/L
Total TCDF ND 2.2 pg/L
1,2,3,7,8-PeCDF ND 3.6 pg/L
2,3,4,7,8-PeCDF ND 3.6 pg/L
Total PeCDF ND 3.6 pg/L
l,2,3,4,7,8-HxCDF ND 3.0 pg/L
l,2,3,6,7,8-HxCDF ND 3.0 pg/L
2,3,4,6,7,8-HxCDF ND 3.1 pg/L
1,2,3,7,8,9-HxCDF ND 3.4 pg/L
Total HxCDF ND 3.4 pg/L
1,2,3,4,6,7,8-HpCDF ND 4.9 pg/L
1,2,3,4,7,8,9-HpCDF ND 4.1 pg/L
Total HpCDF ND 4.9 pg/L
OCDF ND 7.6 pg/L
PERCENT RECOVERY
INTERNAL STANDARDS RECOVERY LIMITS
13C-2,3,7,8-TCDD 79 (40 -135)
13C-l,2,3,7,8-PeCDD 82 (40 -135)
13C-l,2,3,6,7,8-HxCDD 98 (40 -135)
13C-l,2,3,4,6,7,8-HpCDD 82 (40 -135)
13C-OCDD 74 (4 0 135)
13C-2,3,7,8-TCDF 95 (40 -135)
13C-l,2,3,7,8-PeCDF 86 (40 135)
13C-l,2,3,4,7,8-HxCDF 89 (4 0 -135)
13C-l,2,3,4,6,7,8-HpCDF 88 (40 135)
NOTE (S):
Calcula1ioi1~ arc r,er!onncd tictorc rounding lO avoid round-off crrnrs in calculated results.
Matrix ......... , WATER
METHOD
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
LABORATORY CONTROL SAMPLE EVALUATION REPORT
GC/MS Semivolatiles
Client Lot# ... : C3F13025S Work Order# ... : FQM7H1AC
LCS Lot-Sample#: C3F170000-36S
Prep Date ...... : 06/17/03 Analysis Date .. : 06/19/03
Prep Batch# ... : 3168365
Dilution Factor: 1
PARAMETER
Pentachlorophenol
2,4-Dichlorophenol
SURROGATE
Nitrobenzene-ds
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
NOTE (S) ,
PERCENT
RECOVERY
70
56
RECOVERY
LIMITS
(10 -140)
(42 -115)
PERCENT
RECOVERY
57
54
57
54
60
67
CalculJ.tions arc performed before rounding to avoid round-off errors in calculated results.
Matrix ......... : WATER
METHOD
SW846 8270C SIM
SW846 8270C SIM
RECOVERY
LIMITS.
(30 -1°21)
(11 -119)
(39 -115)
(37 -115)
(41 -llS)
(40 -115)
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LABORATORY CONTROL SAMPLE EVl\LOATION REPORT
Trace Level Organi.c Compounds
Client Lot# ... : C3Fl30255 Work Order# ... : FQT6KlAC
I.CS Lot-Sample#: G3Fl90000-407
Prep Date ...... : 06/19/03 Analysis Date .. : 06/19/03
Prep Batch# ... : 3170407
Dilution Factor: 1
PERCENT RECOVERY
PARAMETER RECOVERY LIMITS
2,3,7,8-TCDD 120 (70 -130)
1,2,3,7,8-PeCDD 112 (77 -129)
1,2,3,4,7,8-HxCDD 94 (57 -149)
i,2,3,6,7,8-HltCDD 109 (73 -137)
1,2,3,7,8,9-HxCDD 101 (69 -152)
1,2,3,4,6,7,8-HpCDD 107 (79 -132)
OCDD 108 (79 -130)
2,3,7;8-TCDF 109 (67 -137)
1,2,3,7,8-PeCDF 112 (77 -133)
2,3,4,7,8-PeCDF 115 (61 -136)
1,2,3,4,7,8-HxCDF 103 (78 -127)
1,2,3,6,7,8-HxCDF 116 (71 -141)
2,3,4,6,7,8-HxCDF 120 (56 -166)
1,2,3,7,8,9-HxCDF 99 (64 -159)
1,2,3,4,6,7,B-HpCDF 104 ( 77 -132)
1,2,3,4,7,8,9-HpCDF 89 (68 -144)
OCDF 103 (68 -138)
PERCENT
INTERNAL STANDARD RECOVERY
13C-2,3,7,8-TCDD 74
13C-l,2,3,7,8-PeCDD 78
13C-l,2,3,6,7,8-HxCDD 91
13C-l,2,3,4,6,7,8-HpCDD 74
13C-OCDD 68
13C-2, 3, 7, 8-TCDF 90
13C-l,2,3,7,8-PeCDF 82
13C-l,2,3,4,7,8-HxCDF 86
13C-l,2,3,4,6,7,B-HpCDF 82
NOTE(S):
Calculacions are performed before rounding lo 3VOid round-off errors in calculaled results.
Bold print denm~ control parameler.;
Matrix ......... : WATER
METHOD--
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
RECOVERY
LIMITS
(40 -135)
(40. -135)
(40 -135)
(40 -135)
(4 0 -135)
(40 -135)
(40 -135)
(40 -135)
(4 0 135)
MATRIX SPIKE SAMPLE EVALUATION REPORT
GC/MS Sernivolatiles
Client Lot# ... , C3Fl30255
MS.Lot-Sample#, C3Fl30255-002
Work Order# ... , FQJQJlAC-MS
FQJQJlAD-MSD
Date Received .. , 06/13/03
Analysis Date •. , 06/19/03
Matrix ......... , WATER
Date Sampled ... , 06/12/03
Prep Date ...... , 06/17/03
Prep Batch#.,., 3168365
Dilution Factor: 1.01
PARAMETER
Pentachloropbenol
2,4-Dichlorophenol
SURROGATE
Nitiobenzene-dS
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2;4,6-Tribr6mophenol
NOTE(S),
PERCENT
RECOVERY
242 a
238 a
63
63
RECOVERY
LIMITS
(10 -140)
(10 -140)
( 42 -115)
(42 -115)
PERCENT
RECOVERY
64
65
61
60
64
64
61
66
68
67
77
75
Calculations are performed before rounding to avoid round-off errors in calculated results.
a Spiked analyte rCCOvery is outside stated control limits.
MS Run # ... · ..... , 3168204
RPD
RPD LIMITS METHOD
SW846 8270C SIM
0.66 ( o-56 I SW846 8270C SIM
SW846 8270C SIM
0.56 ( o-44 I BW846 8270C SIM
RECOVERY
LIMITS··
(3 0 -121)
(30 -121)
(11 -119)
(11 -119)
(39 -ll5)
(39 -115)
(37 -115)
(37 -ll5)
(41 -ll5)
(41 -ll5)
(40 -115)
(4 0 -ll5)
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MATRIX SPIKE SAMPLE EVALUATION REPORT
Trace Level organic COmpounds
Client Lot # ... : C3Fl30255 Work Order #-_ .. : FQJQJlAF-MS Matrix .... _ .... :
MS Lot-Sample#: C3Fl30255-002 FQJQJlAG-MSD
Date Sampled ... : 06/12/03 Date Received. _ : 06/13/03 MS Run#.-.· ..... :
Prep Date ...... : 06/19/03 Analysis Date .. : 06/19/03
Prep Batch# ... : 3170407
Dilution Factor: 1
PERCENT RECOVERY RPD
PARAMETER RECOVERY LIMITS RPD LIMITS METHOD
2,3,7,8-TCDi::> 118 (70 -130) SW846 8290
119 (70 -130) 0.94 (0-25) SW846 8290
1,2,3,7,8-PeCDD 109 (77 -129) SW846 8290
113 (77 -129) 3.8 (0-25) SW846 8290
1,2,3,4,7,8-HxCDD 94 (57 -149) SW846 8290
94 (57 -149) 0.01 (0-25) SW846 8290
1.2.3.6,7,8-HxCDD 105 (73 -137) SW846 8290
110 (73 -137) 4.9 (0-25) SW846 8290
1,2,3,7,8,9-HxCDD 100 (69 -152) SW846 8290
101 (69 -152) 1.2 (0-25) SW846 8290
1,2,3,4,6,1,e-HPcoo 105 (79 -132) SW846 8290
105 (79 -132) 0.84 ( 0-25) SW846 8290
OCDD 103 (79 -130) SW846 8290
107 (79 -130) 4.8 (0-25) SW846 8290
2,3,7,8-TCDF 108 (67 -137) SW846 8290
111 (67 -137) 3.2 (0-25) SW846 8290
1,2,3,7,B-PeCDF 109 (77 -133) SW846 8290
112 (77 -133) 3.2 (0-25) SW846 8290
2,3,4,7,8-PeCDF 109 (61 -136) SW846 8290
115 (61 -136) 5.7 (0-25) SW846 8290
1,2,3,4,7,8-HxCI)F 101 (78 -127) SW846 8290
101 (78 -127) 1.0 (0-25) SW846 8290
1,2,3,6,7,8-HxCDF 115 (71 -141) SW846 8290
117 (71 -141) 2.0 (0-25) SW846 8290
2,3,4,6,7,8-HxCDF 121 (56 -166) SW846 8290
119 (56 -166) 0.90 (0-25) SW846 8290
1,2,3,7,8,9-HxCDF 96 (64 -159) SW846 8290
96 (64 -159) 0.07 (0-25) SW846 8290
1,2,3,4,6,7,8-HpCDF 100 (77 -132) SW846 8290
102 (77 -132) 2.5 (0-25) SW846 8290
1,2,3,4,7,8,9-HpCDF 88 (68 -144) SW846 8290
86 (68 -144_) 1.6 (0-25) SW846 8290
OCDF 97 (68 -138) SW846 8290
101 (68 -138) 4.8 (0-25) SW846 8290
(Continued on next page)
WATER
3170162
MATRIX SPIKE SAMPLE EVALUATION REPORT
Trace Level. Organic compounds
Cl.ient Lot# ... : C3Fl30255 Work Order# ... : FQJQJlAF-MS Matrix ......... : WATER
MS Lot-Sampl.e #: C3Fl30255-002 FQJQJlAG-MSD
PERCENT RECOVERY
INTERNAL STANDARDS RECOVERY
13C-2,3,7,B-TCDD 81
79
13C-l,2,3,7,8-PeCDD 83
81
13C-l,2,3,6,7,8-HxCDD 99
97
13C-l,2,3,4,6,7,B-HpCDD 79
77
l3C"OCDD 73
71
13C-2,3,7,8°TCDF 96
92
13C-l,2,3,7,8-PeCDF 88
85
13C-l,2,3,4,7,B-HxCDF 92
91
13C-1,2,3,4,6,7,8~HpCDF 86
86
NOTE (S) :
CatCUlations arc performed before rounding 10 avoid round-off errors in calculated results.
Bold print denotes control parametns
LIMITS
(40 -135)
(40 -BS)
(4 0 -135)
(40 -135)
(40 -135)
(40 -135)
(40 -135) ·
(40 -135)
(40 -135)
(40 -135)
(40 -135)
(40 -135)
(40 -135)
(40 -135)
(40 -135)
(40 -135)
(40 -135)
(40 -135)
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