NCD003200383_20030114_Koppers Co. Inc._FRBCERCLA RA_Remedial Action Monthly Progress Reports 2002-OCR

North Carolina
Department of Environment and Natural
Resources
• Michael F. Easley, Governor .
•
William G. Ross Jr., Secretary
Dexter R. Matthews, Director January 14, 2003
Ms. Beverly Hudson
Remedial Project Manager
Superfund Branch
Waste Management Division
US EPA Region IV
61 Forsyth Street, 11 th Floor
Atlanta, Georgia 30303
RE: Monthly Progress Report #116
Remedial Action-December 2002
Fonner Koppers Industries, Inc. NPL Site
Morrisville, Wake County, North Carolina
Dear Ms. Hudson:
The Superfund Section of the North Carolina Department of Environment and Natural Resources
(NC DENR) has received and reviewed the Monthly Progress Report #116-December 2002 for
the Fonner Koppers Industries, Inc. National Priority List (NPL) Site. The Superfund Section
offers the following comment.
Monthly Progress Report #116 (December 2002)
Former Koppers Industries, Inc. NPL Site
I. Please correct Table I to indicate that the effluent sample collected from the groundwater
remediation system at sampling point SY-305 was analyzed for pentachlorophenol,
phenol and chronic toxicity, and not dioxin, content on November 5, 2002.
The Superfund Section of the NC DENR appreciates the opportunity to comment on this
document. If you have any questions or comments, please feel free to contact me at (919) 733-
2801, extension 349. · · ·
Sincerely,
1)~JS/l(~C#~4
David B. Mattison, CHMM
Environmental Engineer
NC Superfund Section
Attachment
cc: Matt Matthews -NC Div. Of Water Quality
Judy Garrett -NC Div. Of Water Quality
1646 Mail Service Center, Raleigh, North Carolina 27699-1646
Phone: [phone] \ FAX: [phone] \ Internet: www.enr.state.nc.us
AN EQUAL OPPORTUNITY\ AFFIRMATIVE ACTION EMPLOYER -50% RECYCLED/ 10% POST CONSUMER PAPER
•
•
January 24, 2003
Ms. Beverly Hudson
Remedial Project Manager
U.S. EPA -Region IV, I Ith Floor
North Site Management Branch
6 I Forsyth Street, SW
Atlanta, GA 30303
RE: Resubmission of Monthly Progress Report #116 Table l
Remedial Action
Koppers Site -Morrisville, North Carolina
Dear Ms. Hudson:
JAN 2 8 2003
In response to Mr. David B. Mattison's January I 4, 2003 letter, please find the attached four (4)
copies of Table I that was inadvertently marked as sampled November 5, 2002 for Dioxin
content in the December Monthly Progress Report (# 116) for Remedial Action at the Koppers
Superfund Site in Morrisville, North Carolina. We apologize for this oversight and any
inconveniences that it may have caused .
Should you need additional information regarding this progress report, please call Mike Helbling
at [phone] or me at [phone].
Sincerely,
The RETEC Group, Inc.
'li'~&t-11~
Rita Bauer
Project Geologist
RS
Enclosure
cc: D. Mattison -NC Superfund (2 copies) D. Hails -Ecological Restoration, Inc.
L. Faulconer -Wake County J. Garrett -NC Division of Water Quality
G. Caskey -Enwood Structures M. Helbling -Beazer
D. Matthews -NC Div. of Waste Management
P. Kilchcnstein -RETEC
11:\Ucaz-Ra lei\ l 2M-02corn.:ction.doc
•
Date Systems Cumulative SV-101
Check Effluent Flow· Sample
(yes/no) (Gallons) (yes/no)
01/10/02 ves 3.251,280 no
01/23/02 ves 3,264,850 ves
02/07/02 ves 3,283.240 no
02/19/02 ves 3,300,140 no
03/06/02 ves 3,318,630 no
03/21102 ves 3,338,440 no
04/02/02 ves 3,356,200 ves
04117102 ves 3.378.150 no
05/01/02 ves 3,397,920 no
05/13/02 ves 3.414.970 no
06/12/2002 ves 3,455,530 no
06/24/2002 ves 3,467,110 no
07/10/2002 ves 3 484,130 ves
07/26/2002 ves 3,503,441 no
08/06/2002 ves 3.515.200 no
08/23/2002 ves 3,536.650 no
09/04/2002 ves 3,547.340 no
09/19/2002 ves 3,564.680 no
10/09/2002 ves 3,587,350 ves
10/22/2002 ves 3,603,120 no
11/05/2002 ves 3,619,248 no
11/22/2002 ves 3,638,832 no
12/12/2002 ves 3.670.160 no
12/31/2002 ves 3,694.000 no
Notes:
Table 1
Groundwater Treatment Operations and Sampling Program Summary
Koppers Superfund Site
Morrisville, North Carolina
December 2002
SV-101 Associated SV-304 SV-304 Associated
Sample Group Sample Sample Group
Parameters {yes/no) Parameters
no
Penta, 2,4-Dichloro, Phenol Dioxin 1 2 ves Penta 2,4-0ichloro, Phenol 1
no
no
no
no
Penta 2 4-Dichloro Phenol 1 ves Penta 2,4-Dichloro Phenol 1
no
no
no
no
no
Penta. 2 4-0ichloro, Phenol ' yes Penta 2,4-Dichloro Phenol 1
no
no
no
no
no
Penta. 2 4-0ichloro. Phenol 1 ves Penta, 2,4-Dichloro, Phenol 1
no
no
no
no
no
Associated Groups:
Sampling point SV-101 is located before the Carbon Units (pretreatment)
Sampling point SV-304 is located between the Carbon Units
SV-101 -Group 1 is penta and 2,4-dichlorophenol; Group 2 is dioxin
SV-304 -Group 1 is penta and 2,4-dichlorophenol
•
SV-305 SV-305
Sample Sample
(yes/no) Parameters
ves Penta 2,4-0ichloro Phenol
Penta, 2,4-0ichloro, Phenol, Dioxin, Chronic
ves Tox
yes Penta, 2.4-Dichloro Phenol
yes Penta 2,4-Dichloro Phenol
yes Penta. 2 4-Dichloro Phenol
ves Penta. 2,4-Dichloro Phenol
Penta, 2,4-Dichloro, Phenol. Dioxin, Chronic
ves Tox
yes Penta, 2,4-Dichloro, Phenol
ves Penta 2,4-0ichloro Phenol, Chronic Tex
ves Penta, 2,4-0ichloro Phenol
ves Penta, 2,4-Dichloro Phenol Chronic Tex
ves Penta. 2,4-Dichloro, Phenol
Penta, 2,4-Dichloro, Phenol, Dioxin, Chronic
yes Tox
ves Penta. 2,4-0ich!oro, Phenol
ves Penta 2.4-0ichloro Phenol Chronic Tex
ves Penta, 2,4-0ichloro. Phenol
yes Penta. 2,4-Dichloro Phenol, Chronic Tox
yes Penta, 2 4-Dichloro Phenol
Penta, 2,4-Dichloro, Phenol, Dioxin, Chronic
ves Tox
ves Penta 2,4-Dichloro Phenol
yes Penta 2,4-Dichloro, Phenol Chronic Tax
yes Penta, 2,4-Dichloro, Phenol
yes Penta 2,4-0ich!oro, Phenol
ves Penta, 2,4-0ichloro. Phenol Chronic Tex
Sampling point SV-305 is lactated after the Carbons Units (post-treatment) SV-305 -Group 1 is penta, phenol, and 2,4-dichlorophenol; Group 2 is dioxin and Group 3 is chronic toxicity
NR -Not recorded
F:IProjects\0362•\Reporto\Monlhty\ 12M-02 Table 1.xls
Associated
Group
1
1 2.3
1
1
1
1
1 2,3
1
1,3
1
1 3
1
1 2,3
1
1 3
1
1 3
1
1,2,3
1
1 3
1
1
1,3
• January I 0, 2003
Ms. Beverly Hudson
Remedial Project Manager
U.S. EPA -Region IV, 11th Floor
North Site Management Branch
61 Forsyth Street, SW
Atlanta, GA 30303
RE: Monthly Progress Report #116
Remedial Action
Koppers Site -Morrisville, North Carolina
Dear Ms. Hudson:
In accordance with the Unilateral Order, and on behalf of Beazer East, Inc. (Beazer), please find attached
four ( 4) copies of the December Monthly Progress Report for Remedial Action at the Koppers Superfund
Site in Morrisville, North Carolina. No exceedances occurred during this event. As discussed in the
previous monthly status report (December I 0, 2002), chronic toxicity was sampled for on a monthly basis
due to past chronic toxicity failures. The December sample did produce a passing result, therefore, the
sampling schedule will revert to quarterly sampling because two consecutive passing results were
obtained.
Should you need additional information regarding this progress report, please call Mike Helbling at
( 412) 208-8858 or me at (978) 3 71-1422.
Sincerely,
The RETEC Group, Inc.
CK:pb
Enclosure
cc: D. Mattison -NC Superfund (2 copies)
L. Faulconer -Wake County
G. Caskey -En wood Structures
M. Helbling -Beazer
H:\Bcaz-Rah:i\l 2M-02.Jnc
JAN 1 4 2003
D. Hails -Ecological Restoration, Inc.
.I. Garrett -NC Division of Water Quality
D. Matthews -NC Div. of Waste Management
P. Kilchenstein -RETEC
•
0
MONTHLY PROGRI~SS REPORT #116
REMEDIAL ACTION
SITE NAME: Koppers Superfund Site
Beazer East, Inc.
Morrisville, NC
USEPA DOCKET NUMBERS: 93-09-C
PERIOD ENDING: December 31, 2002
1. PROGRESS MADE THIS MONTH
2.
3.
4.
5.
6.
Remedial Action (RA) -HABITAT MITIGATION. No activities were conducted this
month.
Remedial Action (RA) -GROUNDWATER TREATMENT. The treatment system
operated throughout the month without upset. System performance was monitored on a
biweekly basis. Approximately 45,590 gallons of groundwater were extracted, treated in
the treatment plant, and discharged between November 25, 2002 and December 31, 2002.
System water samples were collected on December 12 and December 31, 2002 in
accordance with the sampling schedule in the O&M manual. Samples were submitted to
Severn Trent Laboratories, Inc. and Tritest, Inc. for laboratory analysis. The operations
and sampling programs are summarized on the attached Table I.
Remedial Action (RA) -EFFECTIVENESS MONITORING PROGRAM. No activities
were conducted this month. '
Remedial Action (RA) -CORRESPONDENCE. None.
PROBLEMS RESOLVED
PROBLEMS ANTICIPATED
UPCOMING EVENTS
PERSONNEL CHANGES
SUBCONTRACTORS
None.
None.
Continue System O&M.
None.
None.
7. ANALYTICAL DATA Analytical data from system influent and effluent
sampling received during this period are enclosed and are summarized on Table 2.
H:\Bcaz-Ralci\12M-02.doc
Date Systems CumulaUve SV-101
Check Effluent Flow Sample
(yes/no) (Gallons) {yes/no}
01/10/02 ves 3,251,280 no
01/23/02 ves 3,264 850 ves
02107/02 ves 3 283,240 no
02119/02 ves . 3,300 140 no
03/06/02 ves 3,318 630 no
03/21/02 ves 3,338 440 no
04/02102 ves 3,356 200 ves
04/17/02 ves 3,378 150 no
05/01/02 ves 3,397 920 no
05/13/02 ves 3414970 no
06/1212002 ves 3,455.530 no
06/24/2002 ves 3,467,110 no
07/10/2002 ves 3,484 130 ves
07/26/2002 ves 3 503 441 no
08/06/2002 ves 3,515 200 no
08/23/2002 ves 3,536 650 no
09/04/2002 ves 3,547 340 no
09119/2002 ves 3,564,680 no
10/09/2002 ves 3,587 350 ves
10/22/2002 ves 3,603 120 no
11/05/2002 ves 3,619,248 no
11/22/2002 ves 3,638 832 no
12/12/2002 ves 3 670 160 no
12/31/2002 ves 3,694,000 no
Notes:
Table 1
Groundwater Treatment Operations and Sampling Program Summary
Koppers Superfund Site
Morrisville, North Carolina
December 2002
SV-101 Associated SV-304 SV-304 Associated
Sample Group Sample Sample Group
Parameters (yes/no) Parameters
no
Penta 2,4-0ichloro, Phenol Dioxin 1 2 yes Penta, 2 4-Dichloro Phenol 1
no
no
no
no
Penta, 2 4-Dichloro Phenol 1 ves Penta 2 4-Dichloro Phenol 1
no
no
no
no
no
Penta 2 4-0ichtoro Phenol 1 ves Penta 2 4-0ichloro, Phenol 1
no
no
no
no
no
Penta 2,4-0ichloro Phenol 1 yes Penta 2 4-Dich!oro, Phenol 1
no
no
no
no
no
Associated Groups.
Sampling point SV-101 is located before the Carbon Units (pretreatment)
Sampling point SV-304 is located between the Carbon Units
SV-101 -Group 1 is penta and 2,4-dichlorophenol; Group 2 is dioxin
SV-304 -Group 1 is penta and 2,4-dichlorophenol
SV-305 SV-305
Sample Sample
(yes/no) Parameters
yes Penta, 2.4-Dichloro. Phenol
Penta, 2,4-Dichloro, Phenol, Dioxin, Chronic
yes Tox
yes Penta, 2 4-0ich!oro, Phenol
yes Penta. 2,4-Dichloro, Phenol
ves Penta, 2 4-Dichloro, Phenol
yes Penta. 2 4-Dichloro. Phenol
Penta, 2,4-Dichloro, Phenol, Dioxin, Chronic
yes Tox
ves Penta, 2,4-0ichloro, Phenol
yes Penta, 2.4-Dichloro. Phenol, Chronic T ox
yes Penta, 2 4-0ichloro, Phenol
yes Penta, 2 4-Dichloro, Phenol Chronic Tox
yes Penta, 2,4-Dichloro. Phenol
Penta, 2,4-0ichloro, Phenol, Dioxin, Chronic
ves Tox
yes Penta, 2.4-0ichloro, Phenol
ves Penta, 2 4-Dichloro, Phenol Chronic Tax
yes Penta. 2,4-0ichloro, Phenol
ves Penta. 2,4-Dichloro. Phenol, Chronic T ox
ves Penta, 2 4-Dichloro. Phenol
Penta, 2,4-Dichloro, Phenol, Dioxin, Chronic
yes Tox
yes Penta, 2,4-Dichloro. Phenol
Penta, 2,4-0ichloro, Phenol, Dioxin, Chronic
ves Tox
ves Penta, 2 4-Dichloro, Phenol
yes Penta. 2,4-Dichloro, Phenol
yes Penta. 2.4-0ichloro. Phenol. Chronic Tox
Sampling point SV-305 is loctated after the Carbons Units (post-treatment) SV-305 -Group 1 is penta, phenol. and 2,4-dichlorophenol; Group 2 is dioxin and Group 3 is chronic toxicity
NR -Not recorded
F:IProjects\0362,\Repcrt!I\Mon!hly\ 12M-02 Table 1.xts
Associated
Group
1
1,2 3
1
1
1
1
1,2,3
1
1,3
1
1 3
1
1.2.3
1
1,3
1
1,3
1
1,2,3
1
1,3
1
1
1,3
•
f.1Projocll\03624\Roporla\Monlhl1112M-02 Tobit 2 ,lo
Table 2
Groundwater Treatment Analytical Data Summary
Koppers Superfund Site. Morrisville, North Carolina
October 2002
Analytical
Parameter Data Sample Sample
Sample Location Location
Collected SV-101
Pen1achloronhenol 01110/02
01123/02 6.2
02107/02
02119/02
OJ/00/02
OJ/21/02
04102/02 24
04117/02
OS/01/02
05113/02
06/12/02
06124/02
07110/02 33
07126/02
09106/02
08123/02
09/04/02
09/19/02
10/09/02 ,,
10/22/02
11/05/02
11122/02
12112/02
\2131/02
2.4-Dichloro~henol 01110/02
0112J/02 <0,20
02/07/02
02119/02
03/00/02
OJ/21/02
04/02/02 <0.20
04/17/02
OS/01/02
05/13/02
06/12/02
06/24/02
07110/02 <0.21
07/28/02
06/06/02
06123/02
09/0◄ /02
09119/02
10/09/02 <0.20
10/22/02
11/05J02
11122/02
12112/02
12131/02
Pheno( 01110/02
01123/02 <0,20
02/07/02
02119102
03/06102
03121/02
04102/02 <0,20
04117/02
05101/02
OSJlJ/02
06/12/02
06/24/02
07110/02 <0.21
07126/02
'"''''" ,.,,,..,
09/04/02
09/19/02
10/09/02 <0.20
10/22/02
11/05/02
11122/02
12112/02
12131/02
Chronic To~icitv 01/23102
04102/02
05/01102
00112102
071101{)2
0811◄/02
09/04/02
10/09/02
11/05/02
12131/02
Dioxin 12 3 7 8-TCDO\ 01123/02 <2.6
04/02/02
07110/02
10/091{)2
NotH· All •••LJ!o o,o on......,,,,.,,.. P"' ,,., (1,g/1.) ••cop! doo>,n Doo,"1 dlla'" in P~m• ,,., Iller (pgfl)
SV•101 -BefoJo Cart>on UM•
"SV--30<1 • Boi-en Cartoon UM&
'"SV·305, Alto< Cart>on u,.to
SV,304"
<1.0
<1.0
<1.1
<0,00
<0.20
<0,20
<0.22
<0.19
<0.20
<0.20
<0.22
<0.19
Sample
Location
SV-305"
<1,0
<1.0
<1.0
<1.0
<t.O
<1,0
<1.0
<\.O
<1.0
<0.96
<1.0
<0.98
<1.0
<1.0
<1.0
<1.0
<0.99
<0.99
<1.0
<1.0
<0.97
<1.0
<1.0
<1.0
<O 20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.19
<0 20
<0,20
<0.21
<O 20
<0,21
<0.20
<0.20
<O 20
<020
<021
<0.19
<0.20
<0.21
<0.20
<O 21
<0.20
<O 20
<0.20
<0.20
<0,20
<0.20
<0.20
<0,20
<0.20
<0.19
<0.20
<O 21
<0.20
<0.21
<020
<0.20
<0.20
<0.20
<O 21
<0.19
<0,20
<0,21
<0,20
Pass
Fail
Fail
Pasa
Fail
Pan
Pan
Fail
Pan
Pan
<1.5
<O 82
<2.4
<3,1
0
' ' SEVERN;
. T·R ENT I STL
ANALYTICAL REPORT
Ralei~h, BiweekJ.y NPDES
Lot#, C2Ll30436.
Rita Bauer
The RRTEC GrOtip InC
SEVERN TRENT LABORATORIES, INC.
Veronica Bertot
Project Manager
January 2, 2003
Severn Tre.nt Laboratories, Inc.
• A part of Severn Trent pk:
STL Pittsburgh• 450 William Pitt Way, Pittsburgh, PA 15238 Tel [phone] Fax [phone] • www.stf.inc.com
Sample Receiving:
CASE NARRATIVE
THE RETEC GROUP
Raleigh, Biweekly NPDES
STL Lot# C2L130436
STL Pittsburgh, PA received one sample on December 13, 2002 in good condition. The cooler was within the proper temperature range
GC/MS Semivoiatiles SIM:
The reporting limits for the sample were adjusted to reflect the amount of sample used in the extraction procedure.
•
• METHODS SUMMARY
C2L130436
ANALYTICAL_ PREPARATION.
_P_ARAME __ ._T_E~·R~---------~------~~---METHOD _ME=T~H~O~D ____ _
8270C (SIM) SW846 8270C SIM SW846 3520C
References:
SW846 "Test Methods foi-Evaluating Solid waste, Phy'sical/chemical
Methods11 , Thira Edition, November 19a6·and its updates.
SAMPLE SUMMARY
C2L130436
WQ_ff .SAMPLE# CLIENT SAMELE ID
FEVFH 001 SYS EFF/SV-305
NOTE(S):
-The analytical results ~f the salllples listed above 3re presented on the following pages.
-All calculations are pf:rfonned before rounding to avoid round-off errors in calCU!ated results.
-Results noted as ~Nn• were ll~t decci:ted at or above the Slated limit
· -This repOrt must not be reproduce;d, except in full, witholl1 the wrlttt:~ appioval of the laboratory.
-Results !Or the-following pruimeters are never reported on a dry weight basis: color, corrosivity, density, flashpoint, ignirabiiity, byers, odor,
paint filter teU, pH, Porosity pressu~e, reactivity, re.dox potential, specific gravity, spot iests, solids, solubility, ~peiature, visCOsity, and weight.
•
SAMPLED SAMP
D/\.TE.__ _ .. TlME __
12/12/02 10,50
I
I
I
silfo;.·
Custody Record
SEVE.RN
'TRENT
Severn Trerit Laboratories, Inc. ,.
STL ◄

1
2
4

(0901)
Client{) :-{r,;:,
ProjeDManager ~ DBt~-r , ~ \ o ;J._
Cha.in of custody Number ·
---·
"~ ~ 144745
a In.,,.)
' .A ' Address· K \b. Tef9phone Number (Area Code)/Fax Number Lab Number \
lno A.vi._ 97/'h-'Jl\~ l'i.la
Page ~ of
City .. d lm~t~t.l Sire Contact Lab Contact Analysis {Attach list if '
.. '(' ,-.. .,.. u, w: :
more space is needed) I
I
Project Name and Location (State) Carrier/Waybill.Number
I * µ I
13 -!'=--A-~ 7 ~ 0 3 (;,.;) 4-0'1 (h
Special Instructions/
Contract/Purchase Order/Quote No.
COntaiilers & V)· 't Conditions of Receipt Matrix Preservatives . J
i t i5 ?! \JI
i
Sample /,D. No. and Description
Date Tifl)e ~ '6 "' 8 ~ ~-!~ •GI
(Containers for each sample may be combined on one line)
-~ { "' ·"> § \'! i -~ , S ';'5 Ei:.P. /s,v-Jo-';' IQ.\"\_ {nS°'O X ii. X
',
' ,·
'
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'
I
I Possible Hazard Identification
\ Sample Disposal-~: -
(A fee may be asse~sed if samples are retained
0 Non-Hazard 0 Aammable .-D Skin 1rn·1ant D Polson a· ,zr ~nknoWrl □-Retum·T~ Client Disposal By Lab. 0 Archive For· Months longer than I monlti)
,. . Tum Around Time Required
0.24 Hours ~8 Hours 14 Days IZ] 21 Days·
OC Requirements (Spea(y)
r. Relinquished .er
2. Relinquished By
DISTRIBUTION: WHITE -Returned to Client with Report; CANARY -Stays with the Sample: PINK -Field Copy
THE RETEC GROUP INC
Client Sample ID, SYS EFF/SV-305
:I&t=Sim!Ple # •.• ,.C2Ll30436-001
Date Sampled .•. , 12/12/02
Prep Date_ ...... , 12/19/02
GC/MS Sernivolatiles
Work.Order.# ... ,. FEVFHlAA-
Date Received .. , 12/13/02
Analysis Date .. , 12/30/02
Matrix ......... , WATER.
MS Run# ....... , 2353120
Prep Batch#, .. , 2353291
Dilution Factor: 1.03 Method ......... , SW846 8270C SIM
REPORTING
PARAMETER RESULT LIMIT UNITS
2,4-Dichlorophenol ND 0 .21 ug/L
PentachlorOphenol ND l.O ug/L
Phenol ND 0 .21 ug/L
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Nitrobenzene;..ds 74 (30 . 121)
Terplienyl -d14 58· (11 119)
2-Fluorobiphenyl 67 (39 115)
2.:..Fluorophen6l 68 (37 . 115)
Phenol-dS 66 (41 . 115)
2,4,6-Trib~omophenol 68 (40 -115)
•
•
•
METHOD BLANK REPORT
GC/MS semivolatiles
CJ.-ient-Lot--1!,.-.•····, .. C2Ll30436-·'-·--Work Order # .. ;, FE53MlAA ..
MB Lot-Sample#, C2Ll90000·291
Analysis Date .. , 12/30/02
Dill.ltion Factor: 1
PARAMETER
2,4-Dichlorophenol
PentaChlorophenol
Phenol
SURROGATE
Nitrobellzene-dS
Terphenyl-dl4
2-Fluorobiphenyl_
2 -Fl uoropheilol
Phenol-d5
2,4;6-Tri,bromoph'enol
NOTE (S) ,
Prep Date .. : ..• , 12/19/02
Prep Batch# ... , 2353291
REPORTING
RESULT LIMIT UNITS
ND 0.20 ug/L
ND l. b ug/L
ND 0:20 ug/L
PERCENT RECOVERY
RECOVERY· LIMITS
76 (30 -121)
55 (11 -119)
66 (39 -115)
73 (37 -115)
73 (41 -115)
69 (40 -115)
Cileulations are performed before rounding to avoid roUDd-off erron in allculated reru.lts .
·Mat.i'ix:;.. _. _ . __ . "': WATER
METHOD
SWB46 8270C SIM
SW846 821-0C SIM
SW846 8270C SIM
LABORATORY CONTROL SAMPLE EVALUATION REPORT • GC/MS Seinivolatiles
__ Client_Lot .. # ... -,_, C2LJ.30436 ...... _ Work Order # ..• : FE53M1AC Matrix_ ... ; .... : WATER LCS Lot-Sample#: C2L190000-291
Prep Date ...... : 12/19/02 Analysis Date .. : 12/30/02 Prep Batch#--'' 2353291
Dilution Factor: l
PERCENT RECOVERY PMAMETER RECOVERY LIMITS METHOD Phenol 79 (10 -131) · SW~46 0210c SIM Pentachlorophenoi 45 (10 -140) SW846 B270C SIM 2,4-Dichloroph~nol 82 (42 -115) SW846 8270C SIM
PERCENT RECOVERY SURROGATE RECOVERY LIMITS -Ni1:rbbenzene-d5 86 (30 -121) Terphenyl-dl4 62 (11 -119) 2-Fluorobiphenyl 70 (39 -115) 2-Fluorophenol 80 (37 115) Phenol-d5 82 (41 -115) 2,4,6-Tribromophenol 79 (40 -1~5)
NOTE (S) :
CalcuJ.atiClns are performed ·before r□Wlding to avoid round-off errors in ?,!OJ.lated results.
•
MATRIX SPIKE SAMPLE EVALUATION REPORT
GC/MS Semivolatiles
ciient. Lot .. # .•• , .. C2L:L30436 Work Order # .•• : FEVCWlAC· MS :. Matrix. ... ~ ...... : WATER
FEVCWlAD·MSD . MS Lot-Sample#: C2Ll30418-oo2·
Date Sampled ... : 12/12/P2 Date Received .. : 12/13/02
Analysis Date .. : 12/30/02.
MS Run # ....... : 2353120 Prep Da_te •..... : 12/19/02
Prep Batch# ... ·: 2353291
DilutiOn Factor: l.~6
PARAMETER-
Phenol
Pentachlorophenol
2,4°Dichlorophenoi
SURROGATE
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorobiphenyl
2..:Fluorophencil
Phenol-d5
2, 4, 6-Tr.ibromophe,nol
NOTE {S):
PERCENT
RECOVERY
67
77
68
117
69.
79
RECOVERY
LIMITS
(10 -131)
(10 -131)
(10 -140)
(10 -140)
(42 -115)
(42 115)
PERCENT
RECOVERY
73
83
55
64
65
73
68
73
72
78
71
80
Calculations are performed befo~c rounding co avoid round-off emirs in e:a.Iciualed results .
RPD
RPO LIMITS METHOD
SW846 8270C SIM·.
13 {0-43) SW846 8270C SIM
SW846 8270C SIM
8.4 {0-56) SW846 8270C SIM
SW846 8270C SIM
13' (0-44) SW846 8270C SIM
RECOVERY
LIMITS
(30 . -121)
(3 0 -121)
(11 -119)
(il -119)
(39 -115)
(39 -115)
(37 -115)
(37 115)
(41 -115)
(41 115)
. (40 115)
(40 -115)
~EVERNI
TRENT\ STL
ANALYTICAL REPORT
Raleigh, BiweekJ.y NPDES
-Lot#: C3A030176
Rita Bauer
The RE'TEC Group Inc
SEVERN TRENT LABORATORIES, INC.
Veron.i.C.i Bortot
Project Manager
January 9, 2003
Severn Trent Laboratories, Inc.
STL Pittsburgh• 450 William Pitt Way, Pittsburgh, PA 15238
Tel [phone] Fax [phone] • www.st"inc.com
Sample Receiving:
CASE NARRATIVE
THE RETEC GROUP
Raleigh, Biweekly.NPDES
STL Lot# C3A030176
STL Pittsburgh, PA received one sample on January 3, 2002 in good condition. The
cooler was within the proper temperature range ·
GC/MS Semivolatiles SIM:
The reporting limits for the sample were adjusted to reflect the amomit of sample used in the extraction procedure.
Since insufficient sample volwne was received to perform a matrix spike a.lid matrix spike duplicate, a Laboratory Control Sample (LCS) and Laboratory Control Duplicate
. (LCD) were performed. All recoveries were within QC limits.
•
•
0
•
METHODS ~y
C3A030176
ANALYTICAL PREPARATION ~P_ARAME __ .~T~E~R ______________________ METHOD _ME~TH~O~D~--~-
8270C (SIM). SW846 8270C SIM SW846 3520C
References:
SW846 11 Test Methods for Evaluating solid waste, Physical/Chemical
Methods 11 , Third Edition, November·19s6 and itS updates.
SAMPLE SUMMARY
C3A030176 •
WO# SAMPLE# CLIE\IT SAMPLE ID
FFL4Q 001 SYS EFF/SV-305
NOTE(S)
• The analytical results of the samples listed above are prCSent.ed on the following pages.
-All calculali.ons are perfornicd befo!e rounding to avoid rotind-off errors in calculated results. -Results noted as ~ND" .were nOt detected at or above the stated limit.
-This report lllust no! be reproduced, except in full, wilhout the wrinen ai,proval of the J.i.boratoty. -Results for the followlllg parameters are never. reported ·on I dry wcii;bt basis: color, corrosivity, density, flashpo~t, ignitabilil)', layers, odor, paint filter test, pH, porosity pressure, reactivity, red ox polentiaJ, iipecific gnvity, Sl)ot tests, solids, g:,lubility, tC'JJll)erature, viscosity, and Weight.
SAMPLED SAMP
_D~A_T_E __ ~
12/31/02 10,05
•
,
c0,;or•··
Custody Record
STL-4124 {0901)
Cf/en{) ot;-; . HJ
Address ~ JOO 'Ro ---fS.vu
c~ j\
1 ra"-l"p t1; ~ J. ,.
Project Name snd ,;e:;y;__stale)
~eo,..7-er _ t JqL
Con/ract/Purchas~ 0rder!QuottJ No.
Sample l.D. No. and Description ·
Date
(Containers for each sample may be combined on one line) S: Y5 £,rr:-(5',;-'Jo-....,-( •:,_/-)i/ Ol.._
,
·_
Possfbte Hazard Jdentillcation
□· Non-Hazard D Flammable 0 Skin Irritant O;PoisonB
ProjFK;t '/jnager
·:+-n-\5(Y..>.V(
Te!epnone Number (Area Code)/FBX Number q'\L-17 i-, '/);}..
Si/eCbn/act Lab Contact
Carrier/Waybill Number
Containers & Matrix
Preservatives
nme-
" i ~ ~ ~-t §
0 8 -~ !~ ~ ~ ~ ~ ~-
/00', ( {
\ Sample Disposal Kf" Unknown D Return Ta _Client csroisposal By Lab
SEVERN.
TRENT
-·SERVICES-\Severn Trent Laboratories, Inc.
Oaie ( ( Chain of Custody Numbw ;.,_ i I o.L-1745h~ lab Number
( Page of J Analysis-(Attach list if more s ace is needed -✓ .... 0.:
Special Instructions/
u .. C ;;;-Conditions of Receipt " <> ~ .
. i.'
.
.
i
!
.
.
(ft fee may be assessed if samples are retained D Arch/Ve F6r Month's longer than 1 month)
-1 um Around nme Requ1red
D 24. Hours· 0 48 Hours· QC ReqU1remenrs (Spac,fy) 0 t40ays O 21 Days I, Re!ir,qurshed By
1. Received By 2, Relinquished By
3. Relinquished By
Comments·
DISTRIBUTION:. WHITE -Returned lo C/fentwlth Report: CANARY -Stays with.the Sample; PINK· Field Copy
THE RETEC GROUP INC
Client Sample ill: SYS EFF/SV-305.
GC/MS Semivolatiles
Lot-Sample#.;.: C3A030l76-001 Work Order# ... : FFL4QlAA
Date Received .. : 01/03/03
Analysis Date .. : 01/08/03
Matrix .......... : WATER Date Sampled ... : 12/31/02
Prep Date ...... : 01/06/03
Prep Batch# ..• : 3006251
Dilution Fact6r: 1.01
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitr6benzene-d5
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluor7'phenol
Phenol-d5
2,4,6-Tribromophenol
MS Run# ....... :
Method ...... , ... : SW846 8270C SIM
RESULT REPORTING
LIMIT UNITS ND 0.20 ug/L ND 1.0 ug/L ND 0 .20 ug/L
PERCENT RECOVERY RECOVERY LIMITS 83 · (30 -121) 68 (H -119) 73 (39 -115) 94 (37 -115) 103 (41 -115) 76 (40 -115)
•
•
•
METHOD BLANK REPORT
GC/MS Semivolatiles
Client Lot # ... : C3A030176 Work Order # ... : FFNDllAA
MB Lot-Sample#: C3A060000-251
Analysis Date .. : 01/08/03
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenbl
SURROGATE
Nitrbbenzene-dS
Terphenyl -d14
2-Fluorobiphenyl
2-Fluoi:-Ophenol
Phenol-d5
2,4,6-Tri~romophenol
NarB (S) :
Prep Date,.· .... : oi/06/03
Prep Batch#.,.: 3006251
REPORTING
RESULT LIMIT UNITS
ND 0.20 ug/L
ND 1.0 ug/L
ND 0. 20 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
.70 (30 -121)
61 (11 -119)
58 (39 -115)
82 (37 -115)
91 (41 -115)
64 (40 -115)
Calculations arc pecifonned before rounding to :aVoid round.off errors in e:aJcub.ted results .
Matrix ......... : WATER
METHOD
SW846 8270C SIM
SW846 8270C SIM
SW846 8270C SIM
LABORATORY CONTROL SAMPLE EVALUATION REPORT
· GC/MS Semivolatiles
Client Lot# ... , C3A030l76 Work Order # ... ' FFNDllAC-LCS
FFNDJ.lAD-LCSD
Analysis Date .. , 0l/0B/03
Matrix ......... : WATER LCS Lot-Sample#, C3A060000-25l
Prep Date ...... , 0l/06/03
Prep Batch# ... , 300625i
Dilution Factor: 1
PERCENT RECOVERY RPD PARAMETER RECOVERY LIMITS RPD LIMITS METHOD Phenol 85 [10 -J.31) SW846 8270C SIM 88 (10 -J.31) 3.0 ( 0"43) SW846 827DC SIM ~entachlorophenol 76 (10 -140) SW846 8270C SIM 78 (10 -140) 1. 9 ( 0-56) SW846 8270C SIM 2,4-Dichlorophenol 63 (42 -115) .SW846 8270C SIM
63 (42 -llS) 0 .2·7 [0-44) SW846 s21oc SIM
PERCENT RECOVERY SllRROGATE RECOVERY LIMITS Nitrobenzene-ds 74. ( 3 0 -121)
75 (30 -121) Terpheriyl-d14 57 (ll -1.19)
SB (11 -119) 2-Fluorobiphenyl 62 (39 -llS)
65 (39 -115) 2-Fluorophenol 78 (37 -115)
82 (37 115) · Phenol-dS 88 (41 -115)
91 [41 -115) 2,4,6-TribromOphenol 70 (40· -11S)
69 [40 -11S)
NOTE(S),
Calculations arc performed berofc rounding to avoid i-owld:-off errors in c.alcuJared results,
•
•
•
•
•
JAN 10 '03 11:55 FR TRITEST 9198345497 TD 14128253409 P.02/02
Effluent Toxicity Report Form -Chronic P&ss/Fail and Acute LCSO Date: 01/10/03
Facility: BEAZER NPOES#: NC Pipe#: County; WAKE
Laboratory Performing Test.? TRITEST, JNC.
/•,
Comments:
X if?J /ll !J'j;a0rnr in Responsiu.i.e Cnarge
X e or Laooracory supervisor * PASSED: 4.52% Reduction •
Work ;t"der: 0212-01545 Environmental Sciences Branch
MAIL ORIGINAL TO: Div. of Water ualit Q y
North Carolina Ceriodaphnia
Chronic Pass/Fail Reproduction Toxicity Test
CONTROL ORGANISMS l 2 3 4 5 6 7 B 9
N.C. DENR
1621 Mail Service Center
Raleigh, No~th Carolina 27699-1621
10 11 12
Chronic Test Results
Calculated t -1.052
Tabular t -2.508
% Reduction -4.52
% Mortality Avg.Reprod.
# Youny Produced 27 26 27 24 23 2B 29 29 26 27 21 23 0.00
Control
25.83
Control
Adult (L)ive (D)ead L L L L L L L L L L L L
Effluent i: 90\
o.oo
Treatment 2
24.67
Treatment 2 ,
TREATMENT 2 ORGANISMS 1 2 3 4 5 6 7 B 9 lCI 11 12 Control CV
9.881% PASS FAIL
# Young ~roduced 29 26 24 29 23 20 26 26 24 26 21 22 % control
producing
brood
orgs
3rd
Check One
Adult (L)ive (D)ead L L L L L L L L L L L L 100\
let. sample
pH
control
Treatment .2 ~
s
t e
a n
r d
t
1st sample
P.O.
Control
Treatment 2 ~
1st sample
~
e
t e
a n
r d
t
1st eample
ffi
LCS0/Acute Toxicity Teet
2nd sample·
~
8
t e
a n
r d
t 2nd sample
~
(Mortali~y eXJ?ressed as %1 combining replicates}
Complete This For Either Test
Tee~ Start Date: 01/01/03
Collection (Start) Date
Sample 1: 12/30/02 Sample 2: 01/02/03
Sample Type/Duration
Grab Comp. Duration
Sample l l---+---+----1 X 24 hrs
Sample 2 X 24 hrs
1st
D
l . s
L /'.
U M
T p
2nd
P/F
s
A
M p
Hardness (mg/1)
1---1----1----,
Spec. Cond. {µmhoe)
t-----1--1-1----1
Chlor.ine(mg/1) :::::::::; <O.l <0.1
217 945 814
t-----+----+-----1
Sample temp. at receipt ( 0 c) ;;;;;;;;;: 1.. 4 o. 4
Concentration
Mortality
start/end
pH
I
Note: Please
complete This
Section Also
start/end
D.O.
Organism Tested: Ceriodaphnia dubia ouracion {hrs) :
Copied from DWQ form AT-1 (3/87) rev. 11/95 (DUBIA ver. 4.41)
** TOTAL PAGE.02 **
•
•
Letter of Transmittal
The RETEC Group, Inc.
1822 East NC Highway 54
Suite 100
Durham, NC 27713
.RETEC
919.484. 2200 Phone
919.484. 8100 Fax
www.retec.com
TO: Beverly Hudson DATE: _12_/_l_l/_0_2 _________ _
Third Quarter 2002 Groundwater Monitoring
RE: Report, Raleigh PROJECT NO: BEAZ7-03624-l03
PLEASE FIND: [8J Allached D Under separate cover via:
0 Copy of Leller
0 Samples
0 Change Order
0 Other:
0 Drawings/Figures O Plans/Specs
Copies Date No.
I 12/11/02
0 For Approval O Approved as Submilled
[8J For Your Use O Approved as Noted
0 As Requested O Returned for Corrections
0 For Review & Comment
Remarks:
Third Quarter
Report, Raleigh
0 Resubmit
0 Submit
0 Return
0 Other:
Description
2002 Groundwater Monitoring
Copies for Approval
Copies for Distribution
Corrected Prints
Atlachcd arc computer-generated groundwater contour maps requested by D. Mattison to be done in conjunction
with the hand drawn maps in the report.
Should you have any questions, please feel free to call me.
Sincerely,
The RETEC Group, Inc.
Stefanie Young
Cc w/ attachments: M. Helbling, R. Baucr;· o:-Mattiscin-:J
DEC 1 2 2002
' -. ---·--·· -· ____ __,
•
December I 0, 2002
Ms. Beverly Hudson
Remedial Project Manager
U.S. EPA -Region IV, 11th Floor
North Site Management Branch
61 Forsyth Street, SW
Atlanta, GA 30303
RE: Monthly Progress Report #115
Remedial Action
Koppers Site -Morrisville, North Carolina
Dear i'vls. Hudson:
The RETEC Group, Inc.
300 Baker Avenue, Suite 302
Concord, MA 01742
RETE(
[phone] Phone
[phone] Fax
www.retec.com
In accordance with the Unilateral Order, and on behalf of Beazer East, Inc. (Beazer), please find attached
four ( 4) copies of the November Monthly Progress Report for Remedial Action at the Koppers Superfund
Site in Morrisville, North Carolina. No exceedences occurred during this event. However, since the
October chronic toxicity test failed, we are colleting on a monthly (rather than quarterly schedule) until
we have passing results for two consecutive months. Because the November chronic toxicity sample
passed, a second monthly chronic toxicity sample will be collected in December.
Should you need additional information regarding this progress report, please call Mike Helbling at
( 412) 208-8858 or me at [phone].
Sincerely,
The RETEC Group, Inc.
~/~~
Rita Bauer
Project Geologist
CK:th
Enclosure
cc: D. Mattison -NC Superfund (2 copies)
L. Faulconer -Wake County
G. Caskey -En wood Structures
M. Helbling -Beazer
F:\\1RO.I ECTS\03624\Rcports\lvlonthly\2002\ 1 I M-02.tloc
D. Hails -Ecological Restoration, Inc.
J. Garrett -NC Division of Water Quality
D. Matthews -NC Div. of Waste Management
P. Kilchenstein -RETEC
MONTHLY PROGRESS REPORT #115
REMEDIAL ACTION
SITE NAME: Koppers Superfund Site
Beazer East, Inc.
Morrisville, NC
USEPA DOCKET NUMBERS: 93-09-C
PERIOD ENDING: November 30, 2002
L PROGRESS MADE THIS MONTH
2.
3.
4.
5.
6.
Remedial Action (RA) -HABITAT 1'v/ITIGATION. No activities were conducted this
month.
Remedial Action (RA) -GROUNDWATER TREAT1'v/ENT. The treatment system
operated throughout the month without upset. System performance was monitored on a
biweekly basis. Approximately 34,560 gallons of groundwater were extracted, treated in
the treatment plant, and discharged between November I, 2002 and November 30, 2002.
System water samples were eollected on November 5, 2002 and November 22, 2002 in
accordance with the sampling schedule in the O&M manual. Samples were submitted to
Severn Trent Laboratories, Inc. and Tritest, Inc. for laboratory analysis. The operations
and sampling programs are summarized on the attached Table l.
Remedial Action (RA) -EFFECTIVENESS 1'v/ONITORING PROGRAM. No activities
were conducted this month.
Remedial Action (RA) -CORRESPONDENCE. None.
PROBLEMS RESOLVED
PROBLmVIS ANTICIPATED
UPCOMING EVENTS
PERSONNEL CHANGES
SUBCONTRACTORS
. None.
None.
Continue System O&M.
None.
None.
7. ANALYTICAL DATA Analytical data from system influent and effluent
sampling received during this period are enclosed and are summarized on Table 2.
1=:\l'ROJ EC'l'S\03624\Rcports\Monthl y\2002\ I I tvt-02.doc
e
Date Systems Cummulatlve SV-101 SV-101
Check Effluent Flow Sample Sample
(ves/no) (Gallons) (yes/no) Parameters
01/10/02 ves 3 251 280 no
Table 1
Groundwater Treatment Operations and Sampling Program Summary
Koppers Superfund Site
Morrisville, North Carolina
November 2002
Associated SV-304 SV-304 Associated
Group Sample Sample Group
{vn.lno) Parameters
no
•
SV-305 SV-305
Sample Sample
(~es/no) Parameters
ves Penta 2 4-Dichloro Phenol
Penta, 2,4-Dichloro, Phenol, Dioxin, Chronic
01/23/02 ves 3 264 850 ,es Penta 2 4-Dichloro Phenol Dioxin 1. 2 ves Penta 2 4-0ichloro Phenol 1 ves Tox
02/07/02 ves 3,283,240 no
02119/02 ves 3 300 140 no
03/06/02 ves 3 318 630 no
03/21/02 ves 3 338 440 no
04/02/02 ves 3 356,200 ves Penta 2 4-Dichloro, Phenol
04/17/02 ves 3 378 150 no
05/01/02 ves 3 397 920 no
05/13/02 ves 3 414 970 no
6/12/2002 ves 3 455 530 no
6/24/2002 ves 3467,110 no
7/10/2002 ves 3 484 130 ves Penta 2 4-Dichloro Phenol
7/26/2002 ves 3 503,441 no
8/6/2002 ves 3 515,200 no
8/23/2002 ves 3 536 650 no
9/4/2002 ves 3,547 340 no
9/19/2002 ves 3 564 680 no
10/9/2002 ves 3 587 350 ves Penta 2 4-Dichloro Phenol
10/22/2002 ves 3 603 120 no
11/5/2002 ves 3619248 no
11/22/2002 ves 3 638 832 no
Notes:
Sampling point SV-101 is located before the Carbon Units (pretreatment)
Sampling point SV-304 is located between the Carbon Units
Sampling point SV-305 is lactated after the Carbons Units (post-treatment)
NR -Not recorded
f:\Prcject&\0l62•1Reports\Mofllhly\l 1M-02 Table Llls
no
no
no
no
1 ves Penta 2,4-Dichloro Phenol 1
no
no
no
no
no
1 ves Penta 2,4-0ichloro Phenol 1
no
no
no
no
no
1 "OS Penta 2 4-Dichloro Phenol 1
no
no
no
Associated Groups:
SV-101 -Group 1 is penta and 2,4-dichlorophenot; Group 2 is dioxin
SV-304 -Group 1 is penta and 2,4-dichlorophenol
ves
•es
"OS
ves
ves
"OS
ves
ves
ves
•es
ves
•es
ves
"OS
"OS
ves
"OS
"OS
ves
ves
Penta 2 4-Dichloro Phenol
Penta 2 4-Dichloro Phenol
Penta, 2 4-Dichloro, Phenol
Penta 2 4-Dichloro, Phenol
Penta, 2,4-Dichloro, Phenol, Dioxin, Chronic
Tox
Penta 2,4-Dichloro Phenol
Penta 2 4-Dichloro Phenol Chronic Tax
Penta 2,4-Dichloro, Phenol
Penta 2 4-Dichloro Phenol Chronic Tex
Penta 2,4-Dichloro, Phenol
Penta, 2,4-Dichloro, Phenol, Dioxin, Chronic
Tox
Penta 2 4-Dichloro Phenol
Penta 2 4-Dichloro Phenol Chronic Tex
Penta 2 4-Dichloro Phenol
Penta, 2 4-Dichloro, Phenol, Chronic Tax
Penta 2 4-Dichloro Phenol
Penta, 2,4-Dichloro, Phenol, Dioxin, Chronic
Tox
Penta, 2,4-0ichloro, Phenol
Penta 2.4-Dichloro Phenol, Chronic Tax
Penta 2 4-Dichloro Phenol
SV-305 -Group 1 is penta, phenol, and 2,4-dichlorophenol; Group 2 is dioxin and Group 3 is chronic toxicity
Associated
Group
1
1 2 3
1
1
1
1
1,2 3
1
1.3
1
1,3
1
1,2 3
1
1,3
1
1 3
1
1,2 3
1
1 3
1
Table 2
Groundwater Treatment Analytlcal Data Summary
Koppers Suporfund Sito -Morrlsvlllo, North Carolina
· November 2002
Analytical
Parameter Date Sample Sample
Sample Location Location
Collected SV-101 SV-304"
Pentachloronhenol 01/10/02
01123102 62 <1.0
02/07102
02/19/02
03106102
03/21102
04/02/02 24 <1.0
04/17102
05/01/02
05/13/02
00112102
06/24/02
07110/02 33 <1.1
07/26102
()8,100/02
08/23/02
09104/02
09J19102
10/09102 15 <0.96
10!22/02
11/05/02
11122102
2. 4-DH:hloronhenol 01/10/02
01(23/02 <0.20 <0.20
02/07/02
02/19/02
03/06/02
03/21/02
04102/02 <0.20 <0.20
04117102
05/01/02
05/13102
06/12/02
00124102
07110/02 <0.21 <0.22
07(26/02
08100/02
08/23/02
09/04/02
09119/02
10/09/02 <0.20 <0.19
10/22/02
11/05102
11/22102
Phenol 01/10/02
01123102 <0.20 <0.20
02/07/02
02/19/02
03108/02
03/21/02
04/02/02 <0.20 <0.20
04117/02
05/01/02
05113/02
08/12/02
08/24/02
07/10/02 <0.21 <0.22
07/26102
08/06102
08/23/02
09/04/02
09119!02
10/09/02 <0,20 <0.19
10122/02
11105/02
11/22102
Chronic To~icitv 01/23102
04/02/02
05/01102
06/1V02
07110/02
06/14102
09104102
10/09/02
11105/02
Dlo)()n 12 3.7 8-TCDDl 01123102 <2.8
04/02/02
07110/02
10109/02
Net••· All r••"tt' aro ,n m,:rcgram, per l<le,,tlL) except dioxin Oic"'n dota ~., p,ccgram, pe, l<ler (pg/L)
sv.101 -Beier• Calbcn units
"SV.:30<1 -B-n Cart>on Un!LI
NSV-305 -After Carr.en Unn
F.IProJa<:lal036241Roport,IMonthly\11M-02 Table 2.~I•
Sample
Location
SV-305""
<1.0
<1 0
<1.0
<1.0
<1,0
<1.0
<1.0
<1.0
<1.0
<0.96
<1.0
<0.98
<1.0
<1.0
<1.0
<1.0
<0.99
<0.99
<1.0
<1.0
<0.97
<1.0
<0.20
<020
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.19
<0,20
<0.20
<0.21
<0.20
<0.21
<0.20
<0.20
<0.20
<0.20
<0,21
<0.19
<0.20
<0.21
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0,20
<0.20
<0.20
<0.19
<0.20
<0,21
<0,20
<O 21
<0.20
<0.20
<0.20
<0.20
<0.21
<0.19
<0.20
Pass
Fail
Fail
Pass
Fail
Pass
Pass
Fail
Pass
<1.5
<0,62
<2.4
<3.1
•
•· . .., ..... , .....
STL
ANALYTICAL REPORT
Raleigh, Biweekly NPDES
Lot#: C2K060332
Rita Bauer
The RETEC Group Ille
SEVERN TRENT LABORATORIES, INC.
erom.ca.
Project Manager
November is, 2002
Severn Trent Laborcltorles, Inc.
STL Pittsburgh• 450 William Pitt Way, Pittsburgh, PA 15238 Tel [phone] Fax [phone] • www.stJ.inc.com
Sample Receiving:
CASE NARRATIVE
THE RETEC GROUP
Raleigh, Biweekly NPDES
STL Lot# C2K060332
STL Pittsburgh, PA received one sample on November 6, 2002 in good condition. The
cooler was within the proper temperature range
GC/MS Semivolatiles SIM:
The reporting limits for the sample were adjusted to reflect the amount of sample used in
the extraction procedure.
Since insufficient sample volume was received to perform a matrix spike and matrix
spike duplicate, a Laboratory Control Sample (LCS) and Laboratory Control Duplicate
(LCD) were performed. All recoveries were within QC limits.
•
•
METHODS SUMMARY
C2K060332
ANALYTICAL PREPARATION
~P:..:ARAME==.o.TE"'R"-_;_ ___________________ METHOD . '-'ME=TH=D.:D ____ _
8270C (SIM) SW846 8270C SIM SW846 3520C
References:
SW846 "Test Methods for Evaluating Solid Waste, Physical/Chemical
Methods", Third Edition, November 1986 and its upda~es .
I
\ I
i
SAMPLE SUMMARY
C2K060332
WO# SAMPLE# CLIENT SAMPLE ID
FCJHG 001 EFF/SV-305
NOTE(S):
-The analytical results of the samples listed above ~ prescmed on die following pages.
-All cak:ulatiom arc performed before rouoding to ,avoid round-off erron in calculated rcsulu.
-Rcsuhs noted as ~ND~ were not detected at or above the staced limit. -This rcpon must not be rcproduca1. except in full, without lhe written approval of the Labomory.
-Results fqr the following parameters are ~ rcponcd on a dry wci&ht basis: color, corrosivity, demity, flashpoint., ignitability, layers, odor, pai:ct. filter test, pH, porosity pressure, reactivity, redox potential, specific ~vity, spot testa, solids, solubility, temperature, viscosity, aIXI weight.
•
SAMPLED SAMP
DATE TIME
11/05/02 0B,20
•
-----------· ----------.... ------.=-. ---------=-~•,________,___
~TL
Chain-of Custody Record & Analytical Request COC# 30365
Page [ of ( -.-. Client: (?.J,{L ,~'?.<r'~"'{\i>rojectID: ____ _ Address: JoD 'B j.i;...; Arv~. Contact: I?;,+,,._ :K~ A.ddress:k<.o,.\ ffiA-, CW11~ Phone: c\:71 ~118'· I i;J.l..
Date: _l_l\-s~(~.,_:l __ _ Report To: ________ ~ -Turnaround: _s_rf.l _____ _
Job Number: /J£11-Z::J--6:J,2<1-o'l(:.
·ncrr..1uA1
' .. ,. -. -.
SEE REVERSE FOR
TERMS AND CONDITIONS
THE RETEC GROUP INC
Client Sample ID: 'BPF/SV-305
GC/MS Semivolatiles
Lot-Sample# ... : C2K060332-001 Work Order # ••• : FCJHGlAA
Date Received .. : 11/06/02
Analysis Date •. : 11/14/02
Matrix ......... : WATER Date Sampled ... : 11/05/02
Prep Date ...•.. : 11/08/02
Prep Batch# ... : 2315091
Dilution Factor: 0.97
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene·d5
Te:cphenyl-dl4
2·Fluorobiphenyl
2·Fluorophenol
Phenol•d5
2,4,6-Tribromophenol
MSRun# •.....• :
Method ..•....•. : SW846 8270C SIM
REPORTING
RESULT LIMIT UNITS
ND 0.19 ug/L
ND 0;97 ug/L
ND 0.19 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
74 (30 -1.21)
61 (11 -119)
77 (39 -115)
72 (37 " 115)
70 (41 -115)
86 (40 -115)
•
•
•
• METHOD BLANK REPORT
GC/MS semivolatiles
Client Lot # •.• : C2K060332 Work order # .•. : FCTHClAA
MB Lot-Sample#: C2Kll0000-091
Analysis Date .. : 11/14/02
Dilution Factor: l.
PARAMETER
Pentachlorophenol
Phenol
2,4-Dichlorophenol
SURROGATE
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-dS
2,4,6-TribromoPhenol
NOTE(S):
Prep Date ...... : 11/08/02
Prep Batch# •.• : 2315091
REPORTING
RESULT. LIMIT UNITS
ND 1.0 ug/L
ND 0;20 ug/L
ND 0.20 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
74 (30 -121)
60 ( J.l -119)
77 (39 -J.15)
74 (37 -J.15)
74 (41 -J.15)
87 (40 -J.15)
Calculations are pcrfonned before rounding to avoid round-off errof'S in calculattd results.
Matrix ......•.• : WATER
METHOD
SW846 8270C SIM
SW846 8270C SIM
SW846 8270C SIM
LABORA'l'ORY CONTROL SAMPLR EVALUATION REPORT
GC/MS Semivolatiles
Client Lot# .•. : C2K060332 Work Order # •.• : FCTHC1AC-LCS
FCTHC1AD-LCSD
Ana.l.ysis Date .. : 11/14/02
Matrix ......... : WATER LCS Lot-Sample#: C2K110000-091
Prep Date •••.•. : 11/08/02
Prep Batch# ... : 2315091
Dilution Factor: 1
PARAMETER
Phenol
Pentachlorophenol
2,4-Dichlorophenol
SURROGATE
Nitrobenzene-d5
Terphenyl-dl.4
2-Fluorobiphenyl
2-Fluoropheilol
Phenol-dS
2,4,6-Tribromophenol
NOTE(S):
PERCENT
RECOVERY
68
70
.95
9B
Bl
BS
Calcularions are pcrfmmcd before rouooing to avoid rour.d-off errors in calculated results.
RECOVERY RPD
LIMITS RPD LIMITS METHOD
(10 -1.31) SWB46 B270C SIM
(10 -1.31) 2.8 (0-4.3) SW846 B270C SIM
(10 -140) SW846 B270C SIM
(10 -140) 3.4 (0-56) SWB46 B270C SIM
(42 -115) SWB46 B270C SIM
(42 -115) 4.6 (0-44) SWB46 8270C SIM
PERCENT RECOVERY
RECOVERY LIMITS
72 (30 -121)
77 (30 -121)
58 (11 -119)
61 (11 -119)
74 (39 -115)
76 (39 -115)
70 (37 -115)
71. (37 -1.1.5)
69 (41. -115)
68 (41. -115)
B1 (40 -115)
83 (40 -115)
•
•
•
• Apa-tolSevemTrentlfc
.STL
ANALYTICAL REPORT
Raleigh, Biweekl.y NPDBS
Lot if: C2K230l.34
Rita Bauer
The RETEC Group Inc
SEV:8RN TRENT LABORATOIUES, INC.
~&U veronica Bortot
Project Manager
December 4, 2002
Severn Trent Laboratories, Inc •
STL Pittsburgh • 450 William Pitt Way, Pittsburgh, PA 15238 Tel [phone] Fax [phone] • wwv1.stJ.inc.com
Sample Receiving:
CASE NARRATIVE
THE RETEC GROUP
Raleigh, Biweekly NPDES
STL Lot# C2K230134
STL Pittsburgh, PA received one sample on Nov=ber 23, 2002 in good condition. The cooler was within the proper temperature range
G:C/MS Semivolatil~ SIM:
The reporting limits for the sample were adjusted to reflect the amount of sample used in the extraction procedure.
Since insufficient sample volume was received to perform a matrix spike and matrix
spike duplicate, a Laboratory Cciritrol Sample (LCS) and Laboratory Control Duplicate (LCD) were performed. All recoveries were within QC limits.
•
•
1.
(I
•
METHODS SUMMARY
C2K230134
ANALYTICAL
PARAMETER METHOD =====----~'-------------'------
PREPARATION
METHOD
B27DC (SIM) SW846 8270C SIM SW846 3520C
References:
SWii46 "'.test Methods for Evaluating Solid' waste, Pnysica'.1/Chemica1
MethodS11 , Third Edition, November 1986 and its updates.
SAMPLE SUMMARY
C2K230J.34 •
WO# SAMPLE# CLIENT SAMPLE ID
FDRKS
NOTE [S):
001 STSEFF/SV-305
-The lll&lytical results. of the samples listed aboYC arc pn:scntcd on the fullowing p&ft:S.
-All calculations aic perfo.r:mcd befoi-c rounding io avoid round-off mon in caJeulatcd results.
-Results DO~ 88 •1m~ were not deucted at of aboVe the stated iimii..
-This report must not be reproduced, except in full. wilhout the written approval of tho labOratory,
-R.cadts: for the followiDg paroneten are neYer reported on a dry weight basis: color, corroslvity, density, flashpoint, ignitability, layen, odor,
paint filter te£t, pH, pomaly pressure., reletivity, redox potential, apecific gmvity, spot r.em, solidi. solubility, tmiperwre., ,.iso:mty, ~ wcigbt.
SAMPLED SAMP
DATE TIME
11/22/02 11:20
•
I
I
I
I
I
I
I
I
I
1 ' I
I l
I
' I
I
I
\
I
aihot
Custody Record
Sll ◄124 (0901)
Cl/rm1~·.
Address
Ea..\6.., IL.it,-'?)00
a,r ~'-"""I rstat\ lZJpCode tll' · ct,<J:i. Prefect~~ and ~ratfJ :s,~e) TI In,:....-~ '\;., Contract/Purchase t)rder/Quot8 Nol , r-t.n=l\,Z·'J: -O~&J{ .... o'it
Sample J.D. No. and Description (Containers for each sample may be coinbined on one line) Date
{;, i ~ (r-p( f;.../-1»~ 11bJ, ...
Possible Hazard /denllticatlon
0 No11-Hazard 0 Flammable 0 Skin /rrltant O·PoisonB
ProjecDanager
rJ,.,... ~~ Tef0phone Number (Araa Code}/Fax Number 9 l&'-111-1 c/.;lJ.. Sito Contact l La~.Con,act
Cani8r/Wayblll Number :
~ Containers & Matrix-' Preservatives "' , ' l " i § <· "'l ~ nme • l ;g J ~ .~ ~ ~~ ·~ "' " 11ao y .,, i.'
..
~ I Sample Disposal
nlmown O Return Td Cfirint £oiSposa/ By Lab 0 Atchlve For
Tum AroLJn? nme Required
D 24 Hours DC Requtroments (Speclfy) 14 Days D 21 Days
2, Relfriqulshed 8 .
J. Re(mqulshad By
Comments-.
DISTRIBUTION: WHITE~ Returned lo CllMI wllh Report; CANARY: Stays with-the Sample; PINK-Fl9fc! Copy
Severn Trent Laboratories, Inc. . oats ~Jo._ Chan otci'447•4 4 .11
L8b ,...,,,,be, -
l l Paga of Analysts fANach fist if more spaQe is needed)
Special Ins/ructions/
Conditions of Receipt
'
(A fee may be assessed If ssmpff1s ar8 retained Months longer than 1 month)
Time
Time
Dalo Tfme ltrl-'J--ck.. o '! «-
Lot-Sample# .. ,:
Date sampled ••. :
Prep Date •.•••. :
Prep Batch # .•• :
TIIE RETEC GROUP INC
Client sample ID: STSEFF/SV-305
GC/MS Semivolatiles·
C2K230134-001
11/22/02
11i25/02
2329317
Work Order # ••• : FDRKBlAA
Date Received •• , 11/23/02
Analysis Date •• : 12/03/02
Matrix ..••....• : WATER
MSRlln# •..•... :
Dilution Factor: 1.01 Method .....••.. : SW846 8270C SIM
REPORTING
PJ\IDll'IETER RESULT LIMIT UNITS
2,4-Dichlorophenol ND o.2ci ug/L
Pentachlorophenol ND 1.0 ug/L
Phenol ND 0 .20 ug/L
PERCENT RECOVERY
SURROGATE. RECOVERY LIMITS
Nitrobenzene-dS 67 (30 . 121)
Terphenyl•d14 74 (il -l:L9)
2-Fluorobiphenyl 67 (39 -115)
2-Fltiorophenol 58 (37 -115)
Phenol-d5 66 (41 -115)
2,4,6-Trihroiriophenol 64 (40 -115)
•
•
•
•
Client Lot # ••• : C2K230l.34
MB Lot-Sample#: C2K250000-3l.7
Analysis ~te •. : l.2/03/02
Dilution Factor: l.
Pentachlorophenol
2,4~Dichlorophenol
Phenol
SURROGATE
Nitrobenzene-dS
Terphenyl,dl.4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-dS
2,4,6-Tribrom6phenol
NOTE(S):
METHOD BLANK REPORT
GC/MS Semivolatiles
Work Order # ••• : FDT3Hl.AA
Prep Date •••••• : l.l/2s/02
Prep Batch # ••• : 23293l. 7
REPORTING
RESULT LIMIT ONITS
ND l..O ug/L
ND 0 .20 ug/L
ND 0.20 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
70 (3 0 -1.2l.)
76 ( l.l. -l.19)
66 (39 -l.15)
62 (3 7 -l.15)
6~ (41 -ll.5)
65 (40 -l.l.S)
Calculations are performed bdore rounding ~-,avoid round-Qff' eiron in alcuhted rc;u!tl.
Matrix ......... : WATER
METHOD.
SW846 8270C SIM
SW846 8270C SIM
SW846 8270C SIM
L!IBORAXORY CON.raOL SAMl?I.B EVAL!JATION REPORT
GC/MS Semi.volatiles
Client Lot# ••• : C2K230134 work order # ••• : FDT3H1AC-LCS
FDT3H1AD-LCSD
Anal.ysis Date •• : 12/03/02
Matrix ......... : WATER LCS Lo;t-sample#:
Prep Date •.•.•. :
Prep Batch # ••. :
C2K250000-317
l.1/25/02
2329317
Dilution Factor: i
PARAMETER
Phenol
Pentachlorophenol
2;4-Dichlorophenol
SURROGATE
Nitrobe:nzene-dS
Terphenyl-dl.4
2-Fiuorobiphenyl
2-Fluorophenol ·
Phenol-d5
2,4,6-Tribromophenol
NOTB(S):
PE;RCENT
RECOVERY
70
73
77
83
6i
65
Calailations ue pt:rfonned before rounding to avoid n:nmd-off erTon in ctk:ul2ted tellllts.
RE;COVERY
LIMITS
Cio 131.)
(10 -131)
(l.O -140)
(10 -140)
(42 -115)
(42 -115)
PE;RCENT
llCOVERY
65
69
61
61.
63
65
57
60
51
55
66
70
RPD
~ LIMITS METHOD
SW846 8270C SIM
.4.4 ( 0-43) SW846 8270C SIM
SW846 8270C SIM
7.7 (0-56) SW846 8270C SIM'
SW846 8270C SIM
5.7 (0-44) SW846 8270C SIM
RECOVERY
LIMITS
(30 -121)
(30 -121)
(11 -119)
(11 -119)
(39 -115)
(39 -115)
(37 -115)
(37 -liS)
(41 -115)
( 4 l. -J.15)
(40 -1i5J
(40 -l.15)
•
•
Effluent Toxicity Report Form -Chronic Pass/Fail and Acute LCSO Date: 11/22/02
Facility: BEAZER NPDES#: NC Pipe#: County: WAKE
aboratory Performing Test: TRITEST, INC.
arge
Supervisor
Work rder: 0211-00123
MAIL ORIGINAL TO:
Comments:
* PASSED: 15.72% Reduction*
Environmental Sciences Branch
Div. of Water Quality
N.C. DENR
1621 Mail Service Center
North Carolina Ceriodaphnia
Chronic Pass/Fail Reproduction
Raleigh, North Carolina 27699-1621
CONTROL ORGANISMS 1 2 3 4
# Young Produced 30 33 28 29
Adult (L) i ve (D)ead L L L L
Effluent%: 90%
TREATMENT 2 ORGANISMS 1 2 3 4
# Young Produced 23 25 27 27
Adult (L)ive (D) ead L L L L
pH
Control
Treatment 2
1st sample
~
1st sample
~
s s
t e t e a n a n r d r d
t t
D.O.
Control
Treatment 2
1st sample
~
1st sample
[8JB3
Toxicity Test Chronic Test Results
5 6 7 8
26 32 30 0
L L L D
5 6 7 8
28 1 24 25
L D L L
2nd sample
~
s
t e
a n
r d
t
2nd sample
~
Calculated t = Tabular t = 9 10 11 12 % Reduction = 15.72
%
29 27 25 29
Mortality Avg.Reprod.
8.33 26.50
Control Control L L L L
8.33 22.33
Treatment 2 Treatment 2
9 10 11 12 Control CV
32. 641% PASS FAIL
22 15 25 26 % control orgs 0C
L
producing 3rd
brood Check One L L L 92%
Complete This For Either Test
Test Start Date: 11/05/02
Collection (Start) Date
Sample 1: 11/04/02 Sample 2: 11/07/02
Sample Type/Duration
Grab Comp. Duration
Sample 1 X 24 hrs l---+----+-------1
Sample 2 X 24 hrs
1st
D
I S
L A
U M
T p
Hardness(mg/1) 44 ......... .
2nd
P/F
s
A
M
p
>---+---+---I
Spec. Cond. (µmhos) 200 924 891 >---+---+---I
<0.1 <0.1
LC50/Acute Toxicity Test
Chlorine(mg/1)
l---+---+----1
Sample temp. at receipt(°C) 1.1 0.7
(Mortality expressed as
LC50 % ----Limits 95% Confidence
% --%
% , combining replicate_s)
Concentration
Mortality
start/end
Method of Determination
Moving Average Probit
Spearman Karber Other
pH
Organism Tested: Ceriodaphnia dubia Duration (hrs) :
Copied from DWQ form AT-1 (3/87) rev. 11/95 (DUBIA ver. 4.41)
Note: Please
Complete This
Section Also
start/end
D.O.
Bioassay Chain 'of Custody Form
. . Bioassays.a,.re to be sampled after 8:30a.m. on •
%Uluont0
D!Jutlon : _4¢""-'-----
. Sample Sit:, Description: --=~'-"-Y_.S,.___.:::£:;..;/:...,_£ _____ __:. ____ _
Samr,le ColJC>etor: .Print> __ ~,_---'-"'.=-'_:..:;..,..__~..:..,,.:,,~\"-'\_. ________ _
SigMture> __ ~.,...-=.,,'"""""'"'-. ."lJ1~JI.,,· ---------
Semple Type: Compoolte ;
Dati,Started: /.j /;.Ao~ 'Ilme: OS::16 @)or l"M
DaieEnded: HI ~10} Tim~:· O'iJo _· (ii;or PM: Samples p;i-Hour: ___ ....... _____ ·#Hours: i?{ ·
~
Date=-----=--=-------T'unc: ---. AM or P-M ' ' Sampl~ V ohuue: ;> · ,.£ Ch!1lcd durlJig Collection? '/
' ' • • • • •" • • • • • • • • • • • • • • • • • • • •· . ChainofC-d:yR=leaso ·········••.•···············
. '· For Laboratory Use Oi,Jy I I ,c-. Rccolvins; T=mpcmu,:: -6'-"6'-'--------By: 1,· Qo ,.S,ltUI:
. . ..
Residw Chlorine: · tJf:l.r Numbe:r ofBottli:s: . ,:2. __.a-_ __ _
A.dlltess: 39O9-Beryl Rd.· Raleigh, NC 27607 Phane(9J9) 834 -4984 Fax (91~) 834-6491 oJ-//-.Oo(;J..3-~01 ( •
•
•
TRITES.T, INC.
Bioassay Chain ·of Custody Form
Bioassays . are to be sampled a,fter on
P.O.#: ___________ _
Phan~# ( C/7,f ) 57/-Jy;) "J.
Contact : /<-{r"-L oC: . County:, __ ""W..,.· w;;:k"-=·-"'·'-----O?tfall/Pipe#:_Cb:c.·=i..(_· __ ·NPDESPermitvi: · /4.k'J.... ~
%Effluent Dilution: -~ff-'-._____ -T~Method :· ~t cTo,:::·
. Sample Site Description: __ 5_, __ . 5:c....,. _C._F~. --/: _____________ _
Sample Collec:t.nr: _Print>_;+~+-.....,Ac,-'-'' °''"""'-~:<:=-u->-,-rrflh". !-'--tiu...r+l/ ______ _
Sigru.ture >_-"bb-~....,_-=---=~J:k,...,_,..:i'J"'-"',Y'--_--~------
Sample Type: Cornoosi-te:
DatS!axted: __ _,_·1.,,,1/:-J4(..;;o=.;i.c...,...--~---Trme: J] if Ger PM.
Date Ended: ----f~'-'li,..~.:.0.,-~~-------Time: · /J ;;).o @ or PM
Samples per Hour: ----4--------# ~o~: d P · . · · ·
Grab~
_D_ate_• -,._· _____ :::::_________ Time:_/ ___ ·--'-AM or PM
Sampl_e Volume: ---'-;)-'-/.,----'i--.,-"-..._'i __ -,--~Chilled during Coll:::tion?_t __ _
Method ofTranspor.ation tow: _,_;,._/_~-'--de..,. ~;,6'.""-'-'l,_.V· ___ --'-------
♦-+ • • • .-• •· ·• • • • • • • • • • • • • • • • • + • . Chain of Cµstody Release
Relinnu"'°"ed B_v. , A Date. Time Rec::ived B~ "Date / -'-,, .,, {)I Y/(.)--':, ') 7 nn .. -,, . . '
..
. .
-ror Laooratory Use Only
· Receiving Temperature: _---"0'--, ...,7 _______ By: .JI_.~
Residual Chlorine: · ~ Number of Bottles:_· _g ___ _
Ad°ilress: 3909·B:ryl Rd.-Ral:igli., NC 27607 Phon:(919)_834 -4984 Fax (9!~) 834-6491 o-i.1t-Do12.J~~ r
Time
ft£?:.
'
•
•
November 8, 2002
Ms. Beverly Hudson
Remedial Project Manager
U.S. EPA -Region IV, I Ith Floor
North Site Management Branch
61 Forsyth Street, SW
Atlanta, GA 30303
RE: Monthly Progress Report #114
Remedial Action
Koppers Site -Morrisville, North Carolina
Dear Ms. Hudson:
The RETEC Group, Inc.
300 Baker Avenue, Suite 302
Concord, MA01742
RETE(
[phone] Phone
[phone] Fax
www.retec.com
1 5 2CC2
In accordance with the Unilateral Order, and on behalf of Beazer East, Inc. (Beazer), please find attached
four (4) copies of the October Monthly Progress Report for Remedial Action at the Koppers Superfund
Site in Morrisville, No11h Carolina. No exceedances occurred during this event. However, the Chronic
Toxicity sample did fail. Based on this failure, we will collect chronic toxicity samples on a monthly
basis until two consecutive monthly tests pass .
Should you need additional information regarding this progress report, please call Mike Helbling at
(4 I 2) 208-8858 or me at [phone].
Sincerely,
Project Geologist
CK:th
Enclosure
cc: ·D. Mattison·-NC:Superfund (2 copies)
L. Faulconer -Wake County
G. Caskey -En wood Structures
M. Helbling -Beazer
F:\I' RO.I ECTS\03 624\Rcports\Monthly\l 0M•02.doc
D. Hails -Ecological Restoration, Inc.
J. Garrett-NC Division of Water Quality
D. Matthews -NC Div. of Waste Management
P. Kilchenstein -RETEC
•
•
MONTHLY PROGRESS REPORT #114
REMEDIAL ACTION
SITE NAME: Koppers Superfund Site
Beazer East, Inc.
Morrisville, NC
USEPA DOCKET NUMBERS: 93-09-C
PERIOD ENDING: October 31, 2002
1. PROGRESS MADE THIS MONTH
2.
3.
4.
5.
6.
Remedial Action (RA) -HABITAT 1\1ITIGATION. No activities were conducted this
month.
Remedial Action (RA) -GROUNDWATER TREATMENT. The treatment system
operated throughout the month without upset. System performance was monitored on a
biweekly basis. Approximately 29,260 gallons of groundwater were extracted, treated in
the treatment plant, and discharged between October I, 2002 and October 31, 2002.
System water samples were collected on October 9, 2002 and October 22, 2002 in
accordance with the sampling schedule in the O&M manual. Samples were submitted to
Severn Trent Laboratories, .Inc. and Tritest, Inc. for laboratory analysis. The operations
and sampling programs are summarized on the attached Table I.
Remedial Action (RA) -EFFECTIVENESS MONITORING PROGRAM. No activities
were conducted this month.
Remedial Action (RA) -CORRESPONDENCE. None.
PROBLEMS RESOLVED
PROBLEMS ANTICil'ATED
UPCOMING EVENTS
PERSONNl~L CHANGES
SUBCONTRACTORS
None.
None.
Continue System O&M.
None.
None.
7. ANALYTICAL DAT A Analytical data from system influent and effluent
sampling received during this period are enclosed and are summarized on Table 2.
F:\PROJ ECTS\03 624\Reports\Monthly\ I 0M-02.doc
e
Date Systems Cummulatlve SV-101
Check Effluent Flow Sample
(yes/no) (Gallons} (yes/no)
01/10/02 ves 3,251 280 no
01/23/02 ves 3 264 850 ves
02107/02 ves 3 283 240 no
02/19/02 ves 3 300 140 no
03/06/02 ves 3 318 630 no
03/21102 ves 3 338 440 no
04/02/02 ves 3 356'200 ves
04/17/02 ves 3 378,150 no
05/01/02 ves 3 397 920 no
05/13/02 ves 3414970 no
6/12/2002 ves 3 455 530 no
6/24/2002 ves 3,467 110 no
7/10/2002 ves 3 484 130 ves
7/26/2002 ves 3 503 441 no
8/6/2002 ves 3515200 no
8/23/2002 ves 3 536 650 no
9/4/2002 ves 3 547 340 no
9/19/2002 ves 3 564 680 no
10/9/2002 ves 3 587 350 ves
10/22/2002 ves 3 603 120 no
Notes.
Table 1
Groundwater Treatment Operations and Sampling Program Summary
Koppers Superfund Site
Morrisville, North Carolina
October 2002
SV-101 Associated SV-304 SV-304 Associated
Sample Group Sample Sample Group
Parameters Ives/no\ Parameters
no
Penta 2 4-Dichloro Phenol Dioxin 1 2 ves Penta 2 4-Dichloro Phenol 1
no
no
no
no
Penta, 2 4-Dichloro, Phenol 1 ves Penta, 2 4-Dichloro Phenol 1
no
no
no
no
no
Penta 2 4-Oichloro Phenol 1 ves Penta 2 4-Dichloro Phenol 1
no
no
no
no
no
Penta 2 4-Oichloro Phenol 1 ves Penta 2.4-Oichloro. Phenol 1
no
AssOC1ated Groups.
Sampling point SV-101 is located before the Carbon Units (pretreatment)
Sampling point SV-304 is located between the Carbon Units
SV-101 -Group 1 is penta and 2,4-dich!orophenol; Group 2 is dioxin
SV-304 -Group 1 is penta and 2,4-dichlorophenol
•
SV-305 SV-305
Sample Sample
(yes/no) Parameters
ves Penta 2,4-Dichloro Phenol
Penta, 2,4-Dichloro, Phenol, Dioxin, Chronic
ves Tox
ves Penta 2 4-Dichloro Phenol
ves Penta 2.4-Dichloro, Phenol
ves Penta 2 4-Dichloro Phenol
yes Penta 2,4-Oichloro Phenol
Penta, 2,4-Dichloro, Phenol, Dioxin, Chronic
ves Tox
ves Penta, 2 4-Dichloro Phenol
ves Penta 2 4-Dichloro Phenol, Chronic Tax
ves Penta 2 4-Dichloro Phenol
ves Penta 2 4-Dichtoro Phenol Chronic Tax
ves Penta, 2 4-Dichloro, Phenol
Penta, 2,4-Dichloro, Phenol, Dioxin, Chronic
ves Tox
ves Penta 2.4-Dichloro, Phenol
ves Penta 2,4-Dichloro Phenol Chronic Tax
ves Penta 2 4-Dichloro, Phenol
ves Penta 2 4-Oichloro Phenol, Chronic Tax
ves Penta 2,4-Oichloro, Phenol
Penta, 2,4-Dichloro, Phenol, Dioxin, Chronic
ves Tox
ves Penta 2 4-Dichloro. Phenol
Sampling point SV-305 is lactated after the Carbons Units (post-treatment) SV-305 -Group 1 is penta, phenol, and 2,4-dichlorophenol; Group 2 is dioxin and Group 3 is chronic toxicity
NR -Not reCOfded
f:\Projecll\Ol624\Reporb\Moolhly\ 1 0M•02 Table 1.xls
Associated
Group
1
1 2,3
1
1
1
1
1 2 3
1
1 3
1
1 3
1
123
1
1 3
1
1 3
1
123
1
•
Table 2
Groundwater Treatment Analytical Data Summary
Koppers Superfund Site -Morrisville, North Cai-olina
October 2002
Analytlcal
Parameter Date Sample
Sample Locallon
Collected SV-101
Pentachloronhenol 01/10/02
01123/02 6.2
02/07/02
02/19/02
03/06/02
03/21102
04102/02 24
04/17/02
05101/02
05/13/02
06/12/02
06/24/02
07110102 33
07126/02
08/06/02
08/23/02
09/04/02
09/19/02
10/09/02 15
10122/02
2.4-Dichloronhenol 01/10/02
01/23/02 <0,20
02/07/02
02/19/02
03/06/02
03121/02
04/02!02 <0.20
04/17102
05/01/02
05113/02
06/12/02
06/24/02
07/10102 <0.21
07126/02
08/06/02
08/23102
09/04/02
09/19/02
10/09/02 <0.20
10/22102
Phenol 01/10/02
01/23/02 <0.20
02/07/02
02119102
03/06J02
03/21/02
04/02/02 <0.20
04117/02
05101/02
05113/02
06/12/02
06/24102
07/10/02 <0.21
07126/02
08106/02
08/23/02
09/04/02
09119/02
10/09102 <0.20
10/22102
Chronic Toxicitv 01/23/02
04/02102
05101/02
06/12/02
07/10/02
08114/02
09104102
10/09/02
Dioxin 12,3.7 8-TCDDI 01/23/02 <2.6
04/02102
07/10/02
10/09/02
Note,,: AJI ,.,.ulls are In microgram• per IJle/ bgll.) ex~pl dio•ln. Dioxin data i• In pic0gram11 per lite, (pg/L).
SV-101 • Belo<e Carbon Units
"SV-304 -BtTWttn C.rbon Un/bi
··sv-305 -A~erCart>on UJllts
F:\Projecta\03624\Reportll\Moolhly\ 10M·02 Table 2.•I•
Sample
location
SV-304"
<1.0
<1.0
<1,1
<0.96
<0.20
<0.20
<0,22
<0.19
<0.20
<0.20
<0.22
<0.19
Sample
Location
SV-305 ..
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<0.96
<1.0
<0.98
<1.0
<1.0
<1.0
<1.0
<0.99
<0.99
<1.0
<1.0
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.19
<0.20
<0.20
<0.21
<0.20
<0.21
<0.20
<0.20
<0.20
<0.20
<0.21
<0.21
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.19
<0.20
<0.21
<0.20
<0,21
<0.20
<0.20
<0.20
<0.20
<0.21
Pass
Fail
Fail
Pass
Fail
Pass
Pass
Fail
<1.5
<0.62
<2.4
<3.1
• STL
ANALYTICAL REPORT
Raleigh, Biweekly NPDES
Lot#, C2J100334
Rita Bauer
The RETEC Group :Inc
SEVERN TRENT LABORATORIES, INC.
Project Manager
October 24, 2002
Severn Trent Laboratories, Inc.
STL Pittsburgh• 450 William Pitt Way, Pittsburgh, fA 15238
Tel [phone] Fax [phone] • www.stl-inc.com
Sample Receiving:
CASE NARRATIVE
THE RETEC GROUP
Raleigh, Biweekly NPDES
STL Lot# C2Jl 00334
STL Pittsburgh, PA received three samples on October 10, 2002 in good condition.
cooler was within the proper temperature range
GC/MS Semivolatiles SIM:
The
Due lb the concentration of compounds detected, SV-101 was analyzed undiluted and at a
5X dilution.
Since insufficient sample volume was received to perform a matrix spike and matrix
spike duplicate, a Laboratory Control Sample (LCS) and Laboratory Control Duplicate
(LCD) were performed. All recoveries were within QC limits.
•
•
•
0
•
MEmODSSUMMARY
C2Jl.00334
PARAMETER
Dibenzodioxins and Dibenzofurans, HRGC/HRMS
8270C (SIM)
References:
ANALYTICAL PREPARATION
METHOD METHOD --------
SW846 8290 SW846 8290
SW846 8270C SIM SW846 3520C
SW846 "Test Methods for EValuating solid Waste, PliySical/Che~iCal
Methods11 , Third Edition, November 1986 and its updates.
WO # SAMPLE# CLIENT SAMPLE ID
·E9Q7G
E9Q7J
E9Q7K
NOTE (SJ:
001
002
003
SV-101
SV-304
SV-305
SAMPLE SUMMARY
C2Jl00334
-The ana.lytical results of the samples listed above are presented on the following pages.
-All calculations are performed bc:fore roiinding to avoid round-off errors in calculated results.
-Results noted as "ND" were not detected at or above~ statl':d limit,
-This repo·n must nm. be reprOduced, except in full, without the written approval of the laboratory,
-Results for lhe following parameters aie never reported on a dry 'weight basis: color, corrosivity, density, flashpoint, ignitability, layers. odor,
paini filter lest, pH. porosity pressure, ieactivity. redox pot.ential, specifiC gravity, spOc tests, solids, solubility, temperature, viscosity, and weight.
•
SAMPLED SAMP
DATE TIME
10/09/02 09:40
10/09/02 10:00
10/09/02 10:30
•
A .ft Chain.of
Custody Record
STl•4124 (0901)
Client -·• ·:::.....1 ,/1,,....,.,.... { , lf-16'
Address
•
Pro/act Man{lger C,,eo u/' ,iZjjl;4 ~,4v.C#.
Telephone Number (Area Code)IFBX Number ,700 /?,4,/Lo/ AvP , .Jv r'1£ 30~ /q 13 I 37 r -f'-12.';L City ,., /] IZ'.41 Zip Code Site'l?)ntacl Lab qontact CO/\f,-on~
Project Name and Locati? (State) W BE.A•/,R' ''L>AJr.d ' c;;;v,::;,;~e'r;:7-~:.?Yi o '/~Cf9 ::J. Contract/Purchase Ordd"/Ouote No.
Containers & Matrix PreseNatives
Sampre f.D. No. and Description Date Time i ~ I i i§ o_~ -(Containers tor each sample may be combined on:one fine) ~ l i ! ~ ~ ~l . < ~
<(I-lo I I ti 'ilo-z-o'/ye, . I' . :i.. ~
Sll ..,Jo'{ jOOC::, ~ FI su -.:res---' I. /0.30 1.:::
'
-
Possible Hazard Identification I Sample Disposal 0 Non-Hazard D Aammable · 0 Skin Irritant 0 Poison a D Unknown ED Return To Chem 0 Disposal By Lab
!.lG 'J .
r-,'i~ ~ ~ '-,
i,
I•
..
D Arehive For
Turn Around Time Reqwred QC ReqUfterr'lents (Specify) 0 24 Hours O 48 Hours D 7 Days D 14 Days O 21 Days
1. Aelmqwshed By 1. Received By
2. Relmquished B
3. Rehnqwshed By
Comments
DISTRIBUTION: WHITE· Returned to Client with Report: CANARY -Stays with the SampJs; PINK· Reid Copy
•
'Severn Trent Laboratories, Inc.
Dara \ I • I r, C\ Q"'l....., Ch~;n of Ci'4' s"ieg 6 Lab Number
\ Page of \
AnaJysis (Attach list if more snace is neededl
Special Instructions/
Conditions of f:1eceipt
(A fee may be assessed if samples are retained
Months longer than 1 month)
Lot-Sample II •.. : C2J100334-001
Date Sampled ••. : 10/09/02
Prep Date .•.•.. : 10/14/02
Prep Batch# ... : 2287310
Dilution Factor: 1
PARAMETER
2,4~Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-d5
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol·d5
2,4,6-Tribromophenol
NOTE (S) :
THE RETEC GROUP INC
Client Sample ID: SV-l.01
GC/MS Semivolatiles
Work Order# ... : E9Q7G1AA
Date Received •• : 10/10/02
Analysis Date •• ; 10/18/02
Matrix ......... : WATER
MS Run # ••••••• :
Method ... , ..... : SW846 8270C SIM
RESULT
ND
26 E
ND
PERCENT
RECOVERY
73
67
63
64
63
78
REPORTING
LIMIT·
0.20
1.0
0.20
RECOVERY
LIMITS
(30 -121)
(11 -119)
(39 -115)
(37 -115)
(41 -115)
(40 -115)
.UNITS
ug/L
ug/L
ug/L
E Estimated result. Result ronccntration ex~s the ca.Iibration range.
•
•
•
•
•
Lat-Sample# ... , C2Jl00334-001
Date Sampled ..• : 10/09/02
Prep Date ...... , 10/14/02
Prep Batch# ... , 2287310
Dilution Factor: 5
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzerie-ds
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophen61
Phenol-dS
2,4,6-Tribromophenol
THE RETEC GROUP IllC
Client Sample ID, SV-101
GC/MS Semivolatiieg
Work Order# •.. , E9Q7G2AA
Date Received .. , 10/:0/02
Analysis Date .• : 10/ia/02_
Matrix •••..•••• : WATER
MSRun# ••••••• :
Method ......... , SW846 8270C SIM
REPORTING
RESULT LIMIT UNITS
ND 1.0 ug/L
15 5.0 ug/L
ND 1.0 ug/L
PERCENT RECOVERY
RECOVERY 'LIMITS
50 (30 -121)
64 (l.1 -119)
64 (39 -115)
63 (37 -115)
61 (41 -115)
52 (40 -115)
Lot-Sample# •.• , C2J100334-002
Date .sampled ... , 10/09/02
Prep Date_ ...•.. , 10/14/02
Prep Batch# .•. , 2287310
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Pe~tachlorophenOl
Phenol
SURROGATE
Nitrobenzene-dS
Terphenyl-d14
2-F.luorcibiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
THE RETRC GROUP INC
Client Sample ID, SV-304
GC/MS Semivolatiles
Work Order # •.. , E9Q7J1AA
Date Received .. , 10/10/02
Analysis Date .. , 10/18/02
Matrix ......... , WATER
MS Run# ....... ,
Method ......... , SW846 8270C SIM
REPORTING
RESULT LIMIT UNITS"
ND 0.19 ug/L
ND 0.96 ug/L
ND · 0 .19 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
72 (30 -121)
60 (11 -119)
63 (39 -115!'
61 (37 -115)
61 (41 -115)
67 (40 -115)
•
•
•
•
0
•
Lot-sample# •.. : C2Jl00334-003
Date Sampled ••• : io/09/02
Prep Date ...... : l0/14/02
Prep Batch# .•• : 22873l0
Dilution Factor: 1
PARAMETER.
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-dS
Terphenyl-dl4
2°Fluorobiphenyl
2-Fluorophenol
Phenol-dS
2;4,6-TribromoPhenol
THE RETEC GROUP INC
Client sample ID: SV-305
GC/MS Semivolatiles
Work Order # ... : E9Q7K1AA
Date Received •• : lO/l0/02
Analysis Date .. : lO/lB/02
Matrix .•••••.•. : WATER
MSRun# ....••. :
Method ..... ; ... : SW846 8270C SIM
REPORTING
RESOLT LIMIT UNITS
ND 0.20 ug/L
ND l.O ug/L
ND 0 .20 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
71 (30 -l2l)
69 (ll -ll9)
69 (39 • llS)
68 (37 -llS)
70 (41 -llS)
70 (40 -115)
THE RETEC GROUP INC
Client Sample ID: SV-305
Trace Level Organic Compounds
Lot-Sample# ... : C2Jl00334-003 Work Order# ... : E9Q7KlAC
Date Received .. : 10/10/02
Jmal.ysis Date .. : 10/18/02
Date sampled ... : 10/09/02
Prep Date ...... : 10/16/02
Prep Batch# ... : 2289161
Dilution Factor: 1
DETECTION PARAl,!ETER RESULT LIMIT 2,3,7,8-TCDD
ND 3.l
PERCENT RECOVERY INTERNAL STANDARDS RECOVERY LIMITS 13C-2,3,7;8-T~OD 80 (40 -135)
Matrix ••..•...• : WATER
MS Run# •••...• :
UNITS METHOD
pg/L SW846 8290
•
•
•
•
•
•
METHOD BLANK REPORT
GC/MS Semivolatiles
ciient 'r.ot ·11 ••• : C2Jl00334 Work order II ..• : E90W31AA
MB Lot-Sample II: C2Jl40000-310
Analysis Date'..: 10/18/02
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-dS
Terphenyl-d14
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
NOTE(S):
Prep Date ••.••• : 10/14/02
Prep Batch 11 ••• : 2287310
REPORTING
RESULT. LIMIT UNITS
ND 0.20 ug/L
ND 1.0 ug/L
ND 0.20 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
61 (30 -12l.)
72 (11 -119)
59 (39 -115)
63 (37 -115)
65 (41 -115)
62 (40 -115)
CaJculatiam a.re perfonned before rounding to avoid I'Ound-off errors in calculated rcsult:i .
Matrix •.....•.• : WATER
METHOD
SW846 8270C SIM
SW846 8270C SIM
SW846 8270C SIM
METHOD BLANK REPORT
Trace Level organic Compounds
Client Lot# •.• : C2J100334 Work order# ..• : E94ER1AA
MB Lot-Sample#: G2J160000-161
Analysis Date .. : 10/18/02
Dilution Factor: l
PARAMETER
2,3,7,8-TCDD
INTERNAL STANDARDS
13C-2,3,7,B-TCDD
NOTE(S):
Prep Date ...... : 10/16/02
Prep Batch# •.. : 2289161
DETECTION
RESULT LIMIT UNITS
ND 2.1 pg/L
PERCENT RECOVERY
RECOVERY LIMITS
74 (40 -135)
Calculations arc perfomicd before rounding lo avoid roWJd-off errors in calcii.laled results,
•
Matrix .•••.•... : WATER
METHOD
SW846 8290
•
•
•
•
•
LABORATORY CONTROL SAMPLE EVALUATION REPORT
GC/MS Semivolatiles
Client Lot # ••• : C2.Jl00334
LCS Lot~Sample#: C2Jl40000·310
Prep Date .•.••• : io/14/02
Work Order# ... : E90W31AC-LCS
E90W31AD-LCSD
Anal.ysis Date .. : 10/18/02
Matrix ......... : WATER
Prep Batch# ..• : 2287310
Dilution FaCtor: 1
PARAMETER
Phenol
Pehtachlorophenol
2,4-Dichlorophenol
SURROGATE
Ni.troberizene-dS
Terphenyl•dl4
2-Fluorobiphenyl
2-Fluorciphenol
Phenol-d5
2,4,6-Tribromophenol
NOTE (S):
PERCENT
RECOVERY
63
53
75
78
70
72
Calculations ai:e performed bd'orc rounding to avoid round--0fJ errors in calculated results .
RECOVERY
LIMITS
(10 · 131)
(10 • 131)
(10 • 140)
(10 · 140)
(42 · 115)
(42 -1.15)
PERCENT
RECOVERY
62
59
62
54
65
66
54
·54
63
~4
80
83
RPD
~ LIMITS METI!OD
SW845 8270C SIM
0.25 (0-43) SWB45 8270C SIM
SW845 8270C SIM
3.9 (0·56) SWB46 8270C SIM
SW845 8270C SIM
3.1 ( 0-44) SW846 8270C SIM
RECOVERY
LIMITS
(30 -121)
(30 -121)
(ll . 119)
(ll • 119)
(39 · 115)
(39 · 115)
(37 · 115)
(37 · 115)
(41 · 115)
(4l -115)
(40 -115)
(40 -115)
LABORATORY CONTROL SAMPLE EVALllATION REPORT
Tl:ace Level Organic Compounds
Client Lot# ... : C2Jl00334 Work Order# ... : E94ER1AC
LCS Lot~Sample#: G2Jl60000-161
Prep Date ...... : 10/16/02 Analysis Date .. : 10/18/02
Prep Batch# ... : 2289161
Dilution Factor: 1
PARAMETER
2,3,7,8-TCDD
INTERNAL STANDARD
13C-2,3,7,B-TCDD
NOTE(S):
PERCENT
RECOVERY
80
RECOVERY
LIMITS
(75 -126)
PERCENT
RECOVERY
83
Calculations are performed before rounding to avoid round-off errors in C2latlate:d results-.
Bold print denotes control parameters
Matrix ......••. : WATER
METHOD
SW846 8290
RECOVERY
LIMITS
(40 -135)
•
•
•
• A part of S!Mrll Trent Ille
STL
ANALYTICAL REPORT
Raleigh, Biweekly NPDES
Lot #: C2J250266
Rita Bauer
The RETEC Group Inc
. SEVERN TRENT LABORATORIES, INC.
1/4
Veronica Bortot
Project Manager
November 4, 2002
Severn Trent Laboratories, Inc.
STL Pittsburgh • 450 William Pitt Way, Pittsburgh, PA 15238
Tel [phone] Fax [phone] • www.stfinc.com
Sample Receiving:
CASE NARRATIVE
THE RETEC GROUP
Raleigh, Biweekly NPDES
STL Lot# C2J250266
STL Pittsburgh, PA received one sample on October 24, 2002 in good condition. The
cooler was within the proper temperature range'
GC/MS Semivolatiles SIM:
The reporting limits for the sample were adjusted to reflect the amount of sample used in
the extraction procedure.
Since insufficient sample volume was received to perform a matrix spike and matrix
spike duplicate, aLaboratory Control Sample (LCS) and Laboratory Control Duplicate
(LCD) were performed. All recoveries were within QC limits.
•
•
•
•
•
•
METHODS SUMMARY
C2J250266
ANALYTICAL PREPARATION
~P~ARAM==E~T=E~R'----------------------METHOD ~ME=T~H~O=D ____ _
8270C (SIM) SW846 8270C SIM SW846 3520C
References:
SW846 11Test Methods for Evaluating Solid Waste,. Physical/Chemical
Methods", Third Edition, November 1986 _and its updates .
SAMPLE SUMMARY
C2J250266
WO# SAMPLE# CLIENT SAMPLE ID
FAR6P 001 EFF/SV-305
NOTE(S):
-The analytical resul1s of the samples listed above are presen1ed on the following pages.
-All c.alculatioru are performed before rounding to avoid rou.nd--off errors in calculated results.
-RC$ullS noted as ·No" were not dc1ectcd a1 or above the staled JimiL
• This report muse not be reproduced, except in full, without the written approval of lhe laboratory.
• Results for the following parameters are never reported on a dry weight basis: color, corrosivity, density, flashpoint, ignitabilily, layers, odor,
paint filter test, pH, porosity pressure, rcac1ivity, rcdox potential, specific gravity, spot tests, solids, ~lubility, temperature, viscosity, and weight.
SAMPLED
DATE
•
SAMP
TIME
10/22/02 16:50
•
Chain of
Custody Record_
STL•4124 (0901)
Client Dn~
3?Jb~1 {we.
ea
c~~ Im~ lz;poi1~
Project Name anr:i Locata.1
\7.., <U'--v<,,r' ; ill~ _f\Jl,,,
Contract/Purehase Order/Quote No. ' '
Sample /.0. No. and DescriJ)tion
(Containers for each sample may be combined on Ol)B line) Date
£(!.pf 5v-?v!'"" \ o\;i._\0l-
Possible Hazard Jdemification
0 Non-Hazard D Flammable D _Skin Irritant D PoisonB
•
Poect Maflagor
I r.:J,-,,. 't;> , .
Telephone Number (Area Code)JFax Number
IC\7f ~37( -1<.{.ia.
S,te comact Lab Contact
Carrier/Waybill Number I ..,J
'1 11 Containers & Matrix-' VI
Preservatives I'--
I ~ I i a ii {i
Time .• ! ~ c§ 2 {;;!. < 2'! N~
\t.$1) ' Iv 11
' .
•
. I Sample Disposal
lQ'unknown D Reh.Im To Gliem ~isposal By Lab t] Atchive For
Tl.Im Around Time Required
0 24 Hours O 48 Hours
, , QC Rcqurrements (SpeCJfy)
7 Days D 14 Days D 21 Oays
1. Relinquishe
2. Relinquish
3, Relinquished By
Comments
DISTRIBUTION: WHITE. Rerumed /0 Client with Report CANARY• Stays with rhe Sample: PINK• Field Copy
•
Severn Trent Laboratories, Inc.
Dat9 Cha;n of Ci'';f 61.9 7 lo a,), ~-;.,,
Lab Number •
Page { of I
Analysis (Attach list if
more snace is needed
Special Instructions/
Conditions of Receipt
(A fee may be assessed if samples are retained
Months longer than 1 month)
Date Time
Date
/J '..?
Date Time
THE RETEC GROIJP INC
Client Sample ID: EFF/SV-305
GC/MS Semivolatiles
Lot-Sample# ... : C2J250266·001 Work Order# ... : FAR6PlAA
Date Received .• : 10/25/02
Analysis Date .. : 11/01/02
Matrix ..•.•.•.• : WATER
MS Run# ••••••• : Date Sampled ... : 10/22/02
Prep Date.· ..... : 10/28/02
Prep Batch# ... : 2301414
Dilution Factor: l.05
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-ds
Terphenyl-d14
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
Method .••.•••.• : SW846 8270C SIM
REPORTING
RESULT LIMIT UNITS
ND 0 .. 21 ug/L
ND 1.0 ug/L
ND 0 .21 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
96 ( 3 0 -121)
76 (11 -119)
85 (39 -115)
·73 (37 -115)
72 (41 -115)
80 (40 -115)
•
•
•
•
•
Client Lot # ... : C2J250266
MB Lot-Sample#: C2J280000-414
Analysis Date .. : 11/01/02
Dilution Factor: l
PARAMETER
Pentachlorophenol
2,4-Dichlorophenol
Phenol
SURROGATE
Nitrobenzene-ds
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
NOTE (SJ:
METHOD BLANK REPORT
GC/MS Semivolatiles
Work Order# .•• : FAXHNlAA
Prep Date ...... : 10/28/02
Prep Batch# ... : 2301414
REPORTING
RESULT LIMIT UNITS
ND 1.0 ug/L
ND 0.20 ug/L
ND 0.20 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
92 (30 -121)
. 75 (11· -119)
84 (39 -115)
80 (37 -115)
79 (41 -115)
75 (40 -115)
calculations arc perfonncd before rounding to avoid round-off errors in calculated results.
Matrix .....•••• : WATER
METHOD
SW846 8270C SIM
SW846 8270C SIM
SW846 8270C SIM
LABORATORY CONTROL SAMPLE EVALUATION REPORT
GC/MS Semivolatiles
Client Lot# ... : C2J250266
LCS Lot-Sample#: C2J280000-414
Prep Date ..•.•. : 10/28/02
Work order# ..• : FAXHNlAC-LCS
FAXHNlAD-LCSD
Anal.ysis Date .. : 11/01/02
Matrix ...•••••. : WATER
Prep Batch# ... : 2301414
Dilution Factor: 1
PARAMETER
Phenol
Pentachlorophenol
2,4-Dichlorophenol
SURROGATE
Nitrobenzene-ds
Terphenyl-d14
2-Fluorobiphenyl
2-Fluorophenol
Phenol-dS
2,4,6-Tribromophenol
NOTE (S) :
PERCENT
RECOVERY
70
75
67
75
83
90
RECOVERY
LIMITS
(10 -131)
(10 -131)
(10 -140)
(10 -140)
(42 -115)
(42 -115)
PERCENT
RECOVERY
87
97
69
75
79
86
68
73
68
73
88
93
Calculatioll$ arc performed before rounding to avoid round-off errors in calculated results.
RPD
RPD LIMITS METHOD
SW846 8270C SIM
7.0 (0-43) SW846 8270C SIM
SW846 8270C SIM
11 (0-56) SW846 8270C SIM
SW846 8270C SIM
7.1 (0-44) SW846 8270C SIM
RECOVERY
LIMITS
(30 -121)
(30 -121)
(11 -119)
.(11 C 119)
(39 -115)
(39 -115)
(37 -115)
(37 -115)
(41 -115)
(41 -115)
(40 -115)
(40 -115)
•
•
•
Effluent Toxicity Report Form -Chronic Pass/Fail and Acute LCS0 Date: 10/22/02
Facility: BEAZER NPDES#: NC Pipe#: County: WAKE
~tiboratory Performing Test: TRITEST, INC.
X.~~-----~-----~~---~-=-------S1gnature of Operator in Responsible Charge
Comments: There was a residual
oil type substance noted in
treatment cup #8.
Work Order: 0210-00811
MAIL ORIGINAL TO:
North Carolina Ceriodaphnia
Chronic Pass/Fail Reproduction Toxicity Test
CONTROL ORGANISMS 1 2 3 4 5 6 7 8 9
# Young Produced 20 32 23 29 27 25 29 29 24
Adult (L) ive (D) ead L L L L L L L L L
Effluent %: 90%
TREATMENT 2 ORGANISMS 1 2 3 4 5 6 7 8 9
10 11
28 29
L L
10 11
** Mann-Whitney U = 26.0 **
Environmental Sciences Branch
Div. of Water Quality
N.C. DENR
1621 Mail Service Center
Raleigh, North Carolina 27699-1621
Chronic Test Results
Calculated t =
Tabular t =
12 % Reduction = 22.39
% Mort?.lity Avg.Reprod.
31
0.00 27.17 Control Control L
8.33 21. 08
Treatment 2 Treatment 2
12 Control CV
12. 927% PASS FAIL
# Young Produced 23 27 23 25 25 14 22 0
dult (L)ive (D) ead L L L L L L L D
pH
Control
Treatment 2
1st sample
tBE]
1st sample
~
2nd sample
~
s s s t e t e t e a n a n a n r d r d r d t t t
D.O.
Control
Treatment 2
1st sample
~
1st sample
~
2nd sample
~
LC50/Acute Toxicity Test
19 20 27 28 % control orgs □~
L
producing 3rd
brood Check One
L L L 100%
Complete This For Either Test
Test Start Date: 10/09/02
Collection {Start) Date
Sample 1: 10/08/02 Sample 2: 10/10/02
Sample Type/Duration
1st
Grab Comp. Duration D
I S
Sample 1 X 24 hrs L A
f----+---+----~ U M
Sample 2 X 24 hrs T P
2nd
P/F
s
A
M p
L_ _ _L __ _j_ ____ r-l----------<
Hardness (mg/1)
Spec. Ccnd. (µmhos)
Chlorine (mg/1)
Sample temp. at receipt(°C)
46 ......... .
207 873
<0.1
1. 9
915
<0.1
3.0
(Mortality expressed as%, combining replicates) I
Concentration
pH
Organism Tested: Ceriodaphnia dubia Duration{hrs): I
Copied from DWQ form AT-1 (3/87) rev. 11/95 (DUBIA ver. 4.41)
Note: Please
Complete This
Section Also
start/end
I Control I
High I Cone. L._-1 __
D.O.
TRITEST, INC.
Bioassay Chain'ofCustody Form
Bio assays . are to be sa..inpled a,fter 8:30a.m. Ori
Tue-sday & Friday.
Facili!y Name: B &4.z.e:-L.. / t€Aiui1(// . . I
Address; -rl-f-lZ /!IZJ?ZG,, . £Ai v' ,fl P.O.#: ___________ _
.19{\ iJA-):;DL. Al/£ ,Jv-ifi,L.,-Joz_ Phone# ( '17S' · ) :17 f -/'("22. ,. (fQtv(,D,/4J , ;r-;A 0/?C(L · Contact: .4?,774 lf'A(.k5;,e' ' .
Co~nty; W ,4-j,::.£... Ou1fall/?ipo#: CC) f" NPDES?ermit;'/: i4;:wJ1N ( 6.. J7?02._
%Effiuent Dilution : ¢·· T~siMet.liod: C-1-hRa,-vzC ·7b)<:,
. Sample Site Description: s ysrv-....--ff1 I €ff I Sample Collector: _Print> 7S£Fr t.6;4~
· Signa.'ure> ## ~ _
Sa'11ple Type: Comnostte.:
Date Started : ___ _:_l .:...o ,_/-"'i,_/o=-=,c=.· -~---Tune : 0 9 O'.C) (!!!Jr ?M
Date Ended: ___ _,/-'o'-'/-"1,.,_1/0=--L..--·· ____ Tim~: · 0 7 OIS . @yr PM
Samples p~ Hour: ___ .,_ _______ ·#Hours: ,2,'/ ·
Grab:_
Date: ______________ _ Time;-----'-AM or ?M
Sampi_e Volume: _,.d-,= __ C_,1'-v:z;,e...,'-'·"""''--~[<---____ Chilled during Collection?
Method of Transportation to Lab: lfA.rJ,{) ,t}LZ?(v~
t • , • + ~ • •··• • + • • + + • + • + • • • + • • •. : Chain of C.US-i..edy Rdeaso
-~ " ,•? ':•'.. if.I . .
+ f • + _•,:~_~}; ♦ • +_ + + ♦ •• f + +,_ ! ~ ♦ ♦ + ♦ .
C: mau1snc IV. R r '. dB D ate 1me ec=1ve IV R · dB I -D ate Time // _,,._,, -7 -/ fl -vr -' /l) ,,;,::::_-;::::-#h·, /I' ... ,I •. _,. /{) --q --6"2.-· 111,'7' .. A
✓ "' u
·-
For Laboratory Use Only
· Recoiving Temperature: _ _..:;_J'._.,_._9_"_c.. ______ By: \ 'Ji /bruJ-1?<...<,{__
Residual Chlorine: ---'"~-{:.cc.-fz,_....__,,-~·-:------Number of Bottles: --'fl=c:,:_ __ _ • A.ddr-..ss: 3909·Beryl Rd.-Ralcigii., NC 27607 Phone[phone] Fax [phone] '/}?✓llJ --oof (/-t>Ol _ (
0
TRITEST, INC.
Bioassay Chain ·of Custody Fo_rm
Bioassays . are to be samoled after B:30a.m. on
P.O.#: ___________ _
Phan~# cqJ,S_ ) '?7( ~ ;<-{J.)._
Contact: 1./-..i."'TT'-½~ · County:. _ _,,@'-. .,.·'-'o_k..,.· 0
2
~Q,.·_<"-·-~-Ou1full/ Pipe# : ,-, . NP~ES Permit# : · ffi;Jj!L,yb--\~
%Effluent Dilution : Rf T~Mcthod: Clt,t6v.c, rc:x:
Sa.'nple Type: Comoosrte ! _/
Date Started: ___ · _/'-'De:+/4.:...i~=i.,..(Jc__)__~ ___ T=c :~ P~
Date Ended: ____ ..._[.,_n.,_,/1-· .,_r'+c(..,o"')..-'-_·. ____ Timc: • c;t:loo_·@ or PM
Samples p~ Hour:-----~-----· ·#Ho,,;..: oJ <f
Grab:_
Date'------------=:........-· ____ -__ _ ·-----Time: · AM or P.M
Sample Volume: ____ .,.;:}),.·-_,,,£-=-...,t __ ,5..,,___-· Cnilled during Collection? _ _,_}/ __
1\,. 7 yr',J<;r_ Method of Transportation to Lab: __ 4(;:±,_,_,.,,=v-/."'----"~==:.............._o _______ _
; • • • + • • ., + + + • + • • • + • • • • • • • • + . . Chain of Cp.Stody Release ·········•• ................... . Rcllnou\,,d 3v. . ~ n.r, ·, Time Receiv~dBv -. D••• . Time (I\ -· , • /j. ,!Ill !(I ri1-t:-;;.,-i:,-\ .,, . II ll _ ,i I -/O//(f!'.TI, pl~ I • ..
-ror Lano)">!()ry Use Only ~ . £7 · Receiving Temperature: _ __cl~f~•ji)~· ________ By, r,j?' ff-{YU/71,,L,d-
Rcsidual Chlorinc: __ _,_M-=?FJ:c..;:+--"'-~~---Numb~ of Bottles: -f~.<----
Address: 3909·Bcryl Rd.-Rcleigli, NC 27607 Phone[phone] Fax [phone] oito -oo#/t-oo-z.. (
North Carolina
Department of Environment and Natural
Resources
0 Michael F. Easley, Governor
William G. Ross Jr., Secretary
Dexter R. Matthews, Director
Ms. Beverly Hudson
Remedial Project Manager
Superfund Branch
Waste Management Division
US EPA Region JV
61 Forsyth Street, 11 th Floor
Atlanta, Georgia 30303
RE: Monthly Progress Report # 113
November 4, 2002
Remedial Action-September 2002
Former Koppers Industries, Inc. NPL Site
Morrisville, Wake County, North Carolina
Dear Ms. Hudson:
MCDENR
The Superfund Section of the North Carolina Department of Environment and Natural Resources
(NC DENR) has received and reviewed the Monthly Progress Report #113 -September 2002 for -
the Former Koppers Industries, Inc. National Priority List (NPL) Site. The Superfund Section
offers the following comment.
Monthly Progress Report #113 (September 2002)
Former Koppers Industries, Inc. NPL Site
1. The laboratory results for the September 4, 2002 sampling event were inadvertently
omitted from the report and the laboratory results for the September 19, 2002 sampling
event were inadvertently duplicated. Please correct this oversight.
The Superfund Section of the NC DENR appreciates the opportunity to comment on this
document. If you have any questions or comments, please feel free to contact me at (919) 733-
2801, extension 349.
Sincerely,
DavuJ 8 fYtoLL,:.s,,,_., /dk
David B. Mattison, CHMM
Environmental Engineer
NC Superfund Section
Attachment
cc: Matt Matthews -NC Div. Of Water Quality
Judy Garret -NC Div. Of Water Quality
1646 Mail Service Center, Raleigh, North Carolina 27699-1646
Phone: [phone] \ FAX: [phone] \ Internet: www.enr.state.nc.us
AN EQUAL OPPORTUNITY\ AFFIRMATIVE ACTION EMPLOYER -50% RECYCLED/ 10% POST CONSUMER PAPER
•
North Carolina
Department of Environment and Natural
Resources
Michael F. Easley, Governor
William G. Ross Jr., Secretary
Dexter R. Matthews, Director
November 4, 2002
Ms. Beverly Hudson
Remedial Project Manager
Supcrfund Branch
Waste Management Division
US EPA Region IV
6 l Forsyth Street, l l th Floor
Atlanta, Georgia 30303
RE: Monthly Progress Report #ll3
Remedial Action-September 2002
Former Koppers Industries, Inc. NPL Site
Morrisville, Wake County, North Carolina
Dear Ms. Hudson:
The Superfund Section of the North Carolina Department of Environment and Natural Resources (NC DENR) has received and reviewed the Monthly Progress Report #113 -September 2002 for the Former Koppers Industries, Inc. National Priority List (NPL) Site. The Superfund Section offers the following comment.
Monthly Progress Report #113 (September 2002)
Former Koppers Industries, Inc. NPL Site
]. The laboratory results for the September 4, 2002 sampling event were inadvertently omitted from the report and the laboratory results for the September 19, 2002 sampling event were inadvertently duplicated. Please correct this oversight.
The Superfund Section of the NC DENR appreciates the opportunity to comment on this document. If you have any questions or comments, please feel free to contact me at [phone], extension 349.
Sincerely,
LX11/1.d 8 n'to..,[;Lis,,,__.. I dJc
David B. Mattison, CHMM
Environmental Engineer
NC Superfund Section
Attachment
cc: Matt Matthews -NC Div. Of Water Qualiry
Judy Garret -NC Div. OfWarer Quality
1646 Mail Service Center, Raleigh, North Carolina 27699-1646
Phone: [phone] \ FAX: [phone] \ Internet: www.enr.state.nc.us
AN EQUAL OPPORTUNin' \ AFFIRMA m'E ACTJO!\: EMPLOYER -50% RECYCLED/ 10% POST CONSUMER PAPER
'·
• November 13, 2002
Ms. Beverly Hudson
Remedial Project Manager
U.S. EPA -Region fV, I Ith Floor
North Site Management Branch
61 Forsyth Street, SW
Atlanta, GA 30303
I r_,;\ ',i
I I : ! ' !l ..,_
I' I'',' i u l' I •
The RETEC Group, Inc.
300 Baker Avenue, Suite 302
Concord, MA01742
RETE(
[phone] Phone
[phone] Fax
www.retec.com
NOV 1 8 2C02
RE:
I
Resubmission of Monthly Progress Report #113 Analytical olta•: : .. -~i
' '
·: :·'
l d, Remedial Action · ··
Koppers Site -Morrisville, NC
Dear Ms. Hudson:
In response to Mr. David B. Mattison's November 4, 2002 letter, please find attached four (4) copies of
the Analytical Data Packet that was inadvertently omitted from the September Monthly Progress Report
for Remedial Action at the Koppers Superfund Site in Morrisville, North Carolina. We apologize for this
oversight and any inconveniences that it may have caused.
Should you need additional information regarding this progress report, please call Mike Helbling at
[phone] or me at [phone].
0 Sincerely,
•
The RETEC Group, Inc.
~~ f61 1Zg
Rita Bauer
Groundwater Monitoring Program Manager
PS:mvc
Enclosure
cc: D. Mattison -NC Superfund (2 copies)
L. Faulconer -Wake County
G. Caskey -Enwood Structures
M. Helbling -Beazer
F:\PROJECTS\03624\Reports\Monthly\9M-02 Data Resubmission.doc
Peter Sullivan
Project Engineer
D. Hails -Ecological Restoration, Inc.
J. Garrett -NC Division of Water Quality
D. Matthews -NC Div. of Waste Management
P. Kilchenstein -RETEC
•
ANALYTICAL REPORT
11aleigh, Biweekly NPDES
Lot#: C2I050325
Rita Bauer·
The RETBC Group Inc
SXVERN TRENT LABORA'l'OlUES, INC.
Sll Pittsburgh
450 William Pitt ~
Pittsburgh, PA 15238-1330
Tel: [phone]
Fax: [phone]
www.stHnc.com
~~
Veronica Bortot
Project Manager
September I6, 2002
STL Pittsburgh is a part of Sewm Trent Laboratories, Inc.
SAMPLE SUMMARY • C2I050325
SAMPLED SAMP WO# SAMPLE# CLIENT SAMPLE ID _D_l'i._TE ___ ~
E7RHO 001 SYS EFF/SV-305 09/04/02 10 :30
NOTB(S):
-The analytical results of the samples listed above are prcscmed on the following pages.
-All c:alatlalions arc pcrfonned before rounding co avoid roWld.-off erron in calculated results.
-Resulu nortd as ~ND" were not deta::tcd at or above the llQled limit.
-This rcpon must not be rq:,roduccd, except in full, without the wrlnen approval or the laboratory.
-Results for.the .following parameters are never i:cportcd on a dry weight basis: color, COrrosivity, density, flashpoint, ignimbility, byen, odor, paint ~ test. ·pH, porosity pressure, reactivity, redox potc:mial, specific gravity, si>ot lcSls, solids, 10hlbility. tempcmturc, viscosity, and weight.
•
· sl • Chain of
CustodyRecord g-,T,RENT.1 " 'S~ve.rn Trent Laboratories,Jnc. STI."4124 {0901)
. C/lef'\ f\ Project M~er 'is~ Oa9. y Chain of ci'4 {ttll· O ..-u.,..1n1t.... ~ 0~ Address no-\lu Lv,e,. qephone Number (Area Cod'1;aJ< Number LsbNuhber
.I 30v · r'3-"J7/-I )'-Page I of ~~ . ,_stats I Zlp Code Sita Contact Lab Con/act Analysis (Attach list if 111,\-0 l7' t.l. -l more s ace. ,s needed Project Nam(! end LJ~ Carrler/Wayb/11 Number
.~ N '\3.eOLV, .· •">i \,,-. ·"~ I Special Instructions/ Con/fact/Purchase Order/Quote No.1 .
Containers & -· Conditions of Receipt Matrix . " PresetVatives R Sample /. D. No. end Description Date 77me I . l '@ a (l· ~ u ~ · (Containers for each 5dtnplfJ may b9 combined Ocl one Jin~) , ·' ~ ! ;§ t 1 ~ SYS £'Ff'. I $V/3os' I'\\ L/\o;i ~ f. 1\1 I'll '
.
.
..
. Possible Hazard ldentificatiOfl · I Sample Disposal
. 'ti'otsposal BY Lab (A fae may be asses,sed If samp(es are retained D Non-Hazard D Flammable D Skin Irritant D Polson B "gf" unknown [J Return To Client 0 Archive For Months longer than· 1 month} Tum Around Time Required ./ QC RequJremtmts (Specify) D 14 Days O 21 Days
·nme
-nine
Tl/Ile
0. /1)01) 3. Relinquished By
Tm,e
Comments
_ DISTRIBUTION~ WHITE -Re_tumed to C/i6fll with Report; CANARY. StayS with the Sa,rple-. PINK· Fie_ki Copy
•
•
METHOD BLANK REPORT
GC/MS Semivolatiles
Client Lot # .•. : C2I050325 Work Order # ••. : E73HR1.AA MB Lot-Sample#: C2Ill0000·346
Analysis Date .. : 09/13/02
Dilution Factor: 1
PARAMETER
.2,4·Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
2 · Fl uorophenol
Phenol·d!i
2,4,6-Tribrofflophenol
NOTK(S):
Prep Date ...... : 09/11/02
Prep Batch# ... : 2254346
REPORTING
·RESULT LIMIT UNITS
ND 0.20 ug/L
ND 1.0 ug/L
ND 0.20 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
78 (37 -·115)
79 (41 -115)
80 (40 • 115)
Cak:u.Jacions are performed befo~ roundin( to avoid round-off~ in calculated results .
Matrix ......... : WATER
METI!OD
SW846. 8270C SIM
SW846 8270C SIM
SW846 8270C SIM
•
•
ANALYTICAL REPORT
Raleigh, Biweekly NPDES
Lot#: C2I200203
Rita Bauer
The RETEC Group Inc
SEVERN TRENT LABORATORIES, INC.
Veronica Bertot
Project Manager
September 27, 2002
STl Pittsburgh is a part of Severn Trent laboratories, Inc.
STL Pittsburgh
450 WIiiiam 11tt Way
Pittsburgh, PA 15238-1330
Tel: [phone]
Fa~ 412 820 2080
www.st~inc.com
•
•
METHODS SUMMARY
C2I200203
ANALYTICAL PREPARATION
=P~ARAME==~TE=R'---------~------------METHOD ~M=E=TH=O=D'------
8270C (SIM) SW846 8270C SIM SW846 3520C
References:
SW846 ~Test Methods for Evaluating Solid Waste, Physical/Chemical
Methods", Third Edition, November 1986 and its updates .
ChJIP. of Custody Record PA 000361 ..
P,oject Name,'R ~---i-,,(\ R.-9 u,, \.. Pmject N,mber, R p'_~ 1,"'1-: ~ O~ C,,il/i • <>'IC Send Report To: 0 · t -'(<.,, ., Sampler (Print Name): A .\\.:\\
Add,m, ~()0 "\< o¥...t,,--.h..v~. Sampler (Print Name): -
,. --A • -_ _\ tf\\b. ri\1<.J.~ Shipment· Method: FJI.S){ ' AirbiU Number: -Phone: laboratory Receivlf19: s-fL·\r.~. Fax:
Field Sam pie ID Sample Sample Sample Number of Date · Time Matrix Containers ~v:.r:rp/ Sv-~oS · l'th~/)), t'31'3 Cw ~
T r:hed by, l~:r ·Received by: (Signature) Date:
p;_,_J..£,<
Relinquished by: (Signature) Received by: (Signature) Date:
Relinquished by: {Signature) Received by: (Signature) Date:
White: lab Copy Yellow:· PM Copy Pink: Field Copy Gold, PM/QA/QC Copy
• ThermoRetec Corporation
3040 William Pitt Way• Pitnbu~h. PA 15238-1359 (412} 826-3340 Phone • [phone] fa~ www.thermoietec.com
" ~ ~~ ;, i1. ,f! . ~
"°S :? '<"
Si
1-f--
• Q. ThermoRetec
Smart Solvtions. Positive Outrom~
Pag,_Lf_j
Purchase
Order#·
I Comments, Special Lab Sample IO Instructions, etc. (to b!! complet~d by l~b)
Time: Samp{e Custodian Remarks ._(Completed By Laboratory):
OA/OC Level Turnaround Sample Receipt
Time: Total ti Containers Receiv~?
level l □ Routine □ CO( Seals Present?
Level Il □ 24 Hour □ COC Seals Intact? Time: Level Ill 0 1 Week □ Received Containers Intact? Other 0 other --Temperature?
•
0
•
Client Lot# ... : C2I200203
MB Lot-Sample#: C2I230000-315
Analysis Date .• : 09/27/02
Dilutioil Factor: 1
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophen6l
NOTE{S):
METHOD BLANK REPORT
GC/MS Semivolatiles
Work Order # ... : EBN2N1AA
Prep Date., . .-... : 09/23/02
Prep Batch# ... : 2266315
REPORTING
RESULT LIMIT UNITS
ND 0.20 ug/L
ND 1.0 ug/L
ND 0.20 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
64 (37 -115)
66 (41 -115)
57 (40 -115)
Calculations are pcrfonncd before rounding to avoid round-off errors in calculated results.
Matrix ......... , WATER
METHOD
SW846 8270C SIM
SW846 8270C SIM
SWB46 B270C SIM
Effluent Toxicity Report Form -Chronic Pass/Fail and Acute LC50 Date, 09/12/02 ~,,,,,, ,,,,~ NPDES#,
boratory Performing Test: TRITEST, INC.
-
Si/ :;e~~ rn Responsrn~e Charge
X
Si'!f<' ~ure ot Laboratory Supervisor
Work Order, 020900075
MAIL ORIGINAL TO,
North Carolina Ceriodaphnia
Chronic Pass/Fail Reproduction Toxicity Test
CONTROL ORGANISMS 1 2 3 4 5 6 7 8 9
# Young Produced 24 24 27 24 28 24 28 25 29
Adult (L) ive (D) ead L L L L L L L L L
Effluent%, 90%
TREATMENT 2 ORGANISMS 1 2 3 4 5 6 7 8 9
NC
10 11
29 30
L L
10 11
Pipe#, County, WAKE
Comments:
* PASSED, 6.90% Reduction
Environmental Sciences Branch
Div. of Water Quality
N.C. DENR
1621 Mail Service Center
*
Raleigh, North Carolina 27699-1621
Chronic Test Results
Calculated t = 1.691
Tabular t = 2.508
12 % Reduction= 6.90
% Mortality Avg. Reprod. 27
0.00 26.58
Control Control
L
0.00 24.75
Treatment 2 Treatment 2
12 Control CV
8.557% PASS FAIL
# Young Produced 24 24 29 26 29 26 26 26 22 25 19 21 % control orgs 0C producing 3rd
brood Check One 8 ult (L)ive (D) ead
pH
Control
Treatment 2
D.O.
Control
Treatment 2
1st sample
~ ~
6
t e
a n
r d
t
1st sample
5
L L L L
1st sample
~ ~
s
t e
a n
r d
t
1st sample
0
L L L L
2nd sample
~ ~
s
t e
a n
r d
t
2nd sample
8
L L L L 100%
Complete This For Either Test
Test Start Date, 09/04/02
Collection (Start) Date
Sample 1, 09/03/02 Sample 2, 09/05/02
Sample Type/Duration
Grab Comp. Duration
Sample 1 X 24 hrs
Sample 2 X 24 hrs
Hardness (mg/1)
Spec. Cond. (µmhos)
D
I
L u
T
1st
s
A
M p
44 ......... .
224 831
2nd
P/F
s
A
M p
936 tBIB ~ ~ Chlorine (mg/1) <0.1 <0.1
LC50/Acute Toxicity Test Sample temp. at receipt(°C) 1.1
(Mortality expressed as%, combining replicates)
Concentration
Mortality
start/end
Note: Please
Complete This
Section Also
start/end
LC50 % Method of Determination
I I lc::::oll
I I
95% Confidence Limits Moving Average Probit % --% Spearman Karber -Other
Cone.
pH D.0.
Organism Tested, Ceriodaphnia dubia Duration(hrs),
Copied from DWQ form.AT-1 (3/87) rev. 11/95 (DUBIA ver. 4.41)
1.3
TRITEST, INC.
Bioassay Chain.·ofCustody Form • Bioassays . are to be samoled a,fter 8:30a.rn. on . .. .· Tue-sday &_ Friday.
Facility Name; Bz;,-~<l< \ P.,,.1~\ \,,..
Address: tL@_.-, P.O.#: ___________ _ 3'00 E&--i<.tv." A,-,,e.
Co~ty: -VJ¼£ . Outfall/ Pipe# :
%Effluent Dilution : ----'{#>'-'-_· __ _
.~ . · Sample Site Description: ---'$ii'-''(~~-"· __ E~F~F._,---,-------------
/1 ~,,\! Sample Collector: _Print> _---'c~--==---,--Yl-i't-----------,-----
Signature > __ _,.Q,.._,,;;;:J..,,.· ==· "-"--'--·__,_ _________ _
Sample Typ~: Composite: \ I
Date Start-..d: ___ C\__,_~ __ c,~-~ ___ Tnne :~or PM.
Date Ended, ____ 9-'-\-1-'G,,_,__\ o_J_-----Time, ~@)or PM
Samples pe; Hour:---~-------.; ~ours: d 1 .
Date'--------'-==------Time: ----'-'----'-AM or PM
Sample V olumc: ___ .,...,?~_-_.{/,._,__,1<,.-"-""--~----Chilled during Collection?_'f-'--"e5"-_
Method of Transportation to Lab: __ kk.,__--"c?'-'-'J---'--')J"-'. "-'";"--'\._,V--_-'---------~
•· • • • • • • •··, • • • • • • • +-+ + • • • • • • +: . Crihln ofC_ustodyR:lease ♦ ♦ ♦ ♦ ♦ ♦ ♦ • ♦ • •. • • • • • ♦ ♦ +. ♦ • ♦ 4 • ♦ •
Reun-ished By. ' r, D,tt,,i Tim~ Rcc:lvedBy -Date Time I ,.,,_ • II 1V I Of:/t./d1-I !(JC:, ' !}./),, ._,.,_ .-"7-IA-,CZ /IA C: I , ' .
' ..
-. ror uooramry Use Only
· Receiving Tempe~: --·~/_._3--_"_c---______ B,c ~ µffl,i1,itt_ .
Residual Chlorine: ___ _._t-/_.,ec..a.Gz...__· _____ Number of Bottles,--'~"------
P-dciress: 3909 Beryl Rd.-Raieigii, NC 27607 Phone(9!9) 834 -4984 Fax (91~) 834-6491 ·• o 2iJ I/ -.o"vD 1 r-:-(J {) 2 (
•
•
October 8, 2002
Ms. Beverly· Hudson
Remedial Project Manager
U.S. EPA -Region IV, 11th Floor
North Site Management Branch
61 Forsyth Street, SW
Atlanta, GA 30303
RE: Monthly Progress Report #113
Remedial Action
Koppers Site -Morrisville, North Carolina
Dear Ms. Hudson:
The RETEC Group, Inc.
300 Baker Avenue, Suite 302
Concord, MA 01742
[phone] Phone
[phone] Fax
www.retec.com
. , -/ ,
I
In accordance with the Unilateral Order, and on behalf of Beazer East, Inc. (Beazer), please find attached
four (4) copies of the September Monthly Progress Report for Remedial Action at the Koppers Superfund
Site in Morrisville, North Carolina. No exceedances occurred during this event. As discussed in the
previous monthly status report (September 10, 2002), chronic toxicity was sampled for on a monthly basis
due to past chronic toxicity failures. The September sample did produce a passing result, therefore, the
sampling schedule will revert to quarterly sampling because two consecutive passing results were
obtained .
Should you need additional information regarding this progress report, please call Mike Helbling at
[phone] or me at [phone].
Sincerely,
Project Geologist
CK:pb
Enclosure
cc: D. Mattison -NC Superfund (2 copies)
L. Faulconer -Wake County
G. Caskey - En wood Structures
M. Helbling -Beazer
F: \PR OJ ECTS\O 3 624 \Reports \Mon th! y\2002\9M -0 2.doc
D. Hails -Ecological Restoration, Inc.
J. Garrett -NC Division of Water Quality
D. Matthews -NC Div. of Waste Management
P. Kilchenstein -RETEC
•
•
MONTHLY PROGRESS REPORT #113
REMEDIAL ACTION
SITE NAME: Koppers Supe1fund Site
Beazer East, Inc.
Monisville, NC
USEPA DOCKET NUMBERS: 93-09-C
PERIOD ENDING: September 30, 2002
1. PROGRESS MADE THIS MONTH
2.
3.
4.
5.
6.
Remedial Action (RA) -HABITAT MITIGATION. No activities were conducted this
month.
Remedial Action (RA) -GROUNDWATER TREATMENT. The treatment system
operated throughout the month without upset. System performance was monitored on a
biweekly basis. Approximately 31,770 gallons of groundwater were extracted, treated in
the treatment plant, and discharged between September 1, 2002 and September 30, 2002.
System water samples were collected on September 4, 2002 and September 19, 2002 in
accordance with the sampling schedule in the O&M manual. Samples were submitted to
Severn Trent Laboratories, Inc. and Tritest, Inc. for laboratory analysis. The operations
and sampling programs are summarized on the attached Table 1.
Remedial Action (RA) -EFFECTIVENESS MONITORING PROGRAM. No activities
were conducted this month.
Remedial Action (RA) -CORRESPONDENCE. None.
PROBLEMS RESOLVED
PROBLEMS ANTICIPATED
UPCOMING EVENTS
PERSONNEL CHANGES
SUBCONTRACTORS
None.
None.
Continue System O&M.
None.
None.
7. ANALYTICAL DATA Analytical data from system influent and effluent
sampling received during this period are enclosed and are summarized on Table 2 .
F: \ PR OJ ECTS\03 6 24 \Reports\M on th l y\2002\9 M-02.doc
Date Systems Cummutative SV-101 SV-101
Check Effluent Flow Sample Sample
(yes/no) (Gallons) (yes/no} Parameters
01/10!02 ves 3.251,280 no
Table 1
Groundwater Treatment Operations and Sampling Program Summary
Koppers Superlund Site
Morrisville, North Carolina
September 2002
Associated SV-304 SV-304 Associated
Group Sample Sample Group
(yes/no) Parameters
no
SV-305 SV-305
Sample Sample
(yes/no) Parameters
"85 Penta, 2.4-Dichloro, Phenol
Penta, 2,4-0ichloro, Phenol. Dioxin, Chronic
01/23/02 ves 3,264 850 ,es Penta, 2,4-Dichloro, Phenol. Dioxin 1, 2 ,es Penta, 2,4-Dichloro. Phenol 1 "85 Tox
02107102 ves 3,283,240 no
02/19/02 ,es 3,300 140 no
03/06/02 ,es 3,318,630 no
03/21/02 ves 3,338,440 no
04/02/02 ,es 3,356.200 ves Penta, 2 4-Dichloro, Phenol
04/17/02 ,es 3,378,150 no
05/01/02 ves 3,397,920 no
05/13/02 ,es 3,414 970 no
6/12/2002 ,es 3,455,530 no
612412002 ,es 3,467 110 no
7/10/2002 ,es 3,484 130 ,es Penta, 2 4-Dichloro
7/26/2002 ,es 3.503,441 no
8/6/2002 ves 3,515.200 no
8/23/2002 ,es 3,536 650 no
9/4/2002 ,es 3,547,340 no
9/19/2002 ves 3,564,680 no
Notes:
Sampling point SV-101 is located before the Carbon Units (pretreatment)
Sampling point SV-304 is located between the Carbon Unlts
Phenol
Sampling point SV-305 is lactated after the Carbons Units (post-treatment)
NR -Not recorded
F.\Projects\03624\Rer,orts\Mont!ty\SM--02 Table his
no
no
no
no
1 ,es Penta, 2,4-Dichloro, Phenol 1
no
no
no
no
no
1 ves. Penta, 2 4-Dichloro. Phenol 1
no: .,
no
no
no
no
Associated Groups:
SV-101 -Group 1 is penta and 2,4-dichlorophenol; Group 2 is dioxin
SV-304 -Group 1 is penta and 2,4-dichlorophenol
,es Penta 2,4-0ichloro, Phenol
"8S Penta, 2,4-Dichloro, Phenol
"8S Penta 2,4-0ichloro, Phenol
,es Penta 2.4-Dichloro, Phenol
Penta, 2,4-0ichloro, Phenol, Dioxin, Chronic
,es Tox
"8S Penta 2.4-Oichloro, Phenol
,es Penta, 2,4-Oichloro, Phenol, Chronic Tax
,es Penta 2,4-Dichloro Phenol
,es Penta 2,4-Oichloro, Phenol, Chronic Tax
"8S Penta 2,4-Dichloro Phenol
Penta, 2,4-Dichloro, Phenol, Dioxin, Chronic
ves · Tox
"85 Penta 2.4-Dichloro, Phenol
"es Penta 2.4-Dichloro, Phenol Chronic Tax
,es Penta, 2,4-Dich!oro Phenol
,es Penta 2,4-Oichloro, Phenol. Chronic Tax
"85 Penta 2,4-Dich!oro, Phenol
SV-305 -Group 1 is penta, phenol, and 2,4-dichlorophenol; Group 2 is dioxin and Group 3 is chronic toxicity
Associated
Group
1
1.2,3
1
1
1
1
1 2,3
1
1,3
1
1,3
1
1 2,3
1
1,3
1
1 3
1
•
Table 2
Groundwater Treatment Analytical Data Summary
Koppers Superfund Site -Morrisville, North Carolina
September 2002
Analytical
Parameter Date Sample Sample
Sample Location Location
Collected SV-101
Pentachloronhenol 01/10102
01123/02 6.2
02/07/02
02119/02
03/06/02
03/21/02
04/02102 24
04/17/02
05/01/02
05/13/02
06/12/02
06/24/02
07/10/02 33
07/26/02
08/06/02
08/23/02
09/04/02
09/19102
2.4-Oichlorochenol 01/10/02
01/23/02 <0.20
02/07/02
02/19/02
03/06102
03/21/02
04/02/02 <0.20
04/17/02
05/01/02
05/13/02
06112102
06124/02
07110/02 <0.21
07126/02
08/06/02
08123/02
09/04/02
09/19/02
Phenol 01/10/02
01123/02 <0.20
02/07/02
02/19/02
03/06/02
03/21/02
04102102 <0.20
04/17/02
05/01/02
05/13/02
06/12/02
06124/02
07/10/02 <0.21
07/26/02
08/06/02
08/23102
09/04/02
09/19/02
Chronic Toxicity 01/23/02
04/02/02
05/01/02
06/12/02
07110/02
08/14/02
09/04/02
Dioxin /2,3,7,8-TCOO) 01123/02 <2.6
04/02102
07/10/02
Noles: All results a,a in micrograms per liter (µglL) except diox;n. Dioxin data is in picograms per liter (pg/L).
SV•1 01 • Before Carbon Units
·sv.304. Between Carbon Units
••sv.305 • After Carbon Units
F:\Projects\03624 \Rep0r1s\Mon1hiy\9M.02 Table 2.xls
sv-304•
<1.0
<1.0
<1.1
<0,20
<0,20
<0.22
<0.20
<0,20
<0.22
Sample
Location
SV-305°
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<0.96
<1.0
<0.98
<1.0
<1.0
<1.0
<1.0
<0.99
<0.99
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0,20
<0.19
<0.20
<0.20
<0.21
<0.20
<0.21
<0.20
<0.20
<0.20
<0.21
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.19
<0.20
<0.21
<0.20
<0.21
<0.20
<0.20
<0.20
Pass
Fail
Fail
Pass
Fail
Pass
Pass
<1.5
<0.62
<2.4
•
0
•
ANALYTICAL REPORT
Raleigh, Biweekly NPDES
Lot#: C2I200203
Rita Bauer
The RETEC Group Inc
SEVERN TRENT LABORATORIES, INC.
Veronica Bertot
Project Manager
September 27, 2002
S11 Pittsburgh is a part of Severn Trent Laboratories, Inc.
STL Pittsburgh
450 William Pitt Way
Pittsburgh, PA 15238-1330
Tel: [phone]
Fax: [phone]
www.stl-lnc.com
•
Sample Receiving:
CASE NARRATIVE
THE RETEC GROUP
Raleigh, Biweekly NPDES
STL Lot # C21200203
STL Pittsburgh, PA received one sample on September 20, 2002 in good conctition. The
cooler was within the proper temperature range.
GC/MS Semivolatiles SIM:
There were no problems associated with the analysis.
Since insufficient sample volume was received to perform a matrix spike and matrix
spike duplicate, a Laboratory Control Sample (LCS) and Laboratory Control Duplicate
(LCD) were performed. All recoveries were within QC limits .
•
•
METHODS SUMMARY
C2I200203
ANALYTICAL PREPARATION
=P~ARAM==E~T~E~R,_ ____________________ METHOD ~M=E=T~H~O=D ____ _
8270C (SIM) SW846 8270C SIM SW846 3520C
References:
SW846 "Test Methods for Evaluating Solid Waste, Physical/Chemical
Methods1', Third Edition, November 1986 all.d its Updates .
•
SAMPLE SUMMARY
C2I200203
WO # SAMPLE# CLIENT SAMPLE ID
EBKNH 001 SYSEFF/SV-305
NOTE(S)
• Tite analytical results of the samples listed above are presented on the following page's.
-All calculations are performed before. rounding to avoid round-off error& in calculaied results.
-Re5Ults noted as "ND' were not detected at or above lhe stated limit.
• This repofl must not be reproduced, except in full, without the written approval or the laboratory.
-Results for the following parameters ari: never rcpotted Qn a dry weight basis: color, corrosivity, density, fla5hpoint, igriiiabi!ity, layers, odor,
paint filter test, pH, porosity pressure, re3ctivity, redox potential, specific graViry, Spot testS, solids, solubility. 1emperarure, viscosity, and weight.
SAMPLED SAMP
DATE TIME
09/19/02 13,18
Chain of Custody Record PA 000361
Project tiame:"K,,,, u(\R,~ Pmject N,mbec, \s ;,-.,1:i:=1--()';, t,,a;'-t" <>1(:
Send Report To: 0 · \. _ '5 ,ll Sampler (Print Name): ~ ,\\:\\
Address: ~OO ~o¥J,,--Lvt, Sampler (Print Name): -~,,,A tr\lJ>.1 n\7L1-::,_ Shipment' Method: FJ-Gx
Airbilt Number: -
Phone: laboratory· Receiving: S'1\, ,();-w;_
Fax:
Sample Sample Sample Number of Field Sampte ID Date · Time Matrix Containers
r:.Y::.f:Ff ( Sv, :,oS l'f\\~o:i. t'Jl'i> Cw ~
rx:hedby (*:r Received by: (Signature) Date:
~J£,<
Reunquished by; (Signature) Received by: (Signature) Date:
Relinquished by: (Signature) Received by: ($ignature) Dab::
White: Lab Copy Yellow:· PM Copy Pink: Field Copy Gold: PM/QA/QC Copy
ThermoReh!c Corporation
3·040 William Pitt Way• Pittsburgh, PA 15238-1359
[phone] Phone • (412) 62!.i-3409 Fax
www.thermoretec.com
tf if-t.: §_
,I;!
·" ~ fS
" 'S::J"' "1:
1--+-
.
-0 ThermoRetec
Smart Solutions. Pajitive Outromi;s.
/ / Page: __ of __
Purchase
Order ~-
I Comments, Special Lab Sample IO
Instructions, etc. (to be completed by lab)
Time: Sample Custodian Remarks :(Completed By Laboratory):
QA/QC level Turnaround Sample Receipt
Time: Total# Containers Received?
Level I D Routine D COC Seals Present?
level u D 24 Hour D CDC Seals Intact? Time: Level m D 1 Week D Received Containers Intact?
Other D Other --Temperature?
•
•
•
THE RETEC GROUP INC
Client Sample ID, SYSEFF/SV-305
GC/MS Semivolatiles
Lot-Sample# ... , C2I200203-001 Work Order# ... , EBYJ'!"tllAA
Date Received .. , 09/20/02
Analysis Date .. , 09/27/02
Matrix ......... : WATER
Date Sampled ... , 09/19/02
Prep Date ...... , 09/23/02
Prep Batch# ... , 2266315
Dilution Factor: 0.99
PARAMETER
2;4-Dichlorophenol
Pentachlorophenol
Pllenol
SURROGATE
2-Fluorophenol
Phenol-dS
2,4,6-Tribromophenol
MS Run jf .....•• ,
Method ......... , SW846 8270C SIM
REPORTING
RESULT LIMIT UNITS
ND 0.20 ug/L
ND 0.99 ug/L
ND 0.20 ug/L
PERCEN'T RECOVERY
RECOVERY LIMITS
58 (37 -115)
58 (41 -115)
66 (40 -115)
•
•
Client Lot# ... , C2I200203
MB Lot-Sample#, C2I230000-315
Analysis Date .. , 09/27/02
Dilutioil Factor: 1
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
2-Fluorophenol
Phenol-d5
2,4,6-TribromophenOl
NOTE(S),
METHOD BLANK REPORT
GC/MS semivolatiles
Work Order# ... , E8N2NlAA
Prep Date., ..... , 09/23/02
Prep Batch# ... , 2266315
REPORTING
RESULT LIMIT UNITS
ND 0.20 ug/L
ND 1.0 ug/L
ND 0.20 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
64 (37 -115)
66 (41 -115)
57 (40 115)
Calculations are performed before rounding to avoid round-off errors in ca!cu!aied results .
Matrix, ........ , WATER
METHOD
SW846 8270C SIM
SW846 B270C SIM
SW846 8270C SIM
LABORATORY CONTROL SAMPLE EVALUATION REPORT
GC/MS SemivOlatiles
Client Lot# ... , C2I200203 Work Order# ... , E8N2NlAC-LCS
E8N2NlAD-LCSD
Analysis Date .. , 09/27/02
Matrix ......... : WATER
LCS Lo·t-Sample#,
Prep D<:-te ...... :
Prep Batch # ... ,
C2I230000-315
09/23/02
2266315
Dilution Factor: 1"
PARAMETER
Phenol
Pen:1:achlorophenol
2,4-Dichlorophenol
SURROGATE
2-FluOrOphenol
Phenol-d5
• 2,4,6-Tribromophenol
NOTE (S) , .. I
PERCENT RECOVERY
RECOVERY LIMITS
65 (10 -131)
63 (10 -l31)
59 (10 • 140)
41 (10 -140)
74 (42 115)
76 (42 -115)
PERCENT
RECOVERY
65
63
66
65
81
81
C;1lculations are performed before rounding to avoid round-off errors in calculated results .
•
RPD
RPD LIMITS METHOD
SW84.6 8270C SIM
3.9 (0-43) SW846 B270C SIM
SW846 8270C SIM
36 (0-56) SW84G 8270C SIM
SW846 B270C SIM
2.2 (0-44) SW846 B270C SIM
RECOVERY
LIMITS
(37 -ll5)
(37 -115)
(41 -115)
(41 -115)
(40 -115)
(40 -115)
•
•
ANALYTICAL REPORT
Raleigh, Biweekly NPDES
Lot#: C2I200203
Rita Bauer
The RETEc Group Inc
SEVERN TRENT LllBOllATORIES, INC.
Veronica Bortot
Project Manager
September 27, 2002
STL Pittsburgh is a part of Sevem rrent laboratories, Inc.
STL Pittsburgh
450 William Pitt Way
Pittsburgh, PA !52311-1330
Tel: 4J2 820 8380
Fax: [phone]
WWv-1,stl-inc.com
I
I
•
•
Sample Receiving:
CASE NARRATIVE
THE RETEC GROUP
Raleigh, Biweekly NPDES
STL Lot # C2I200203
STL Pittsburgh, PA received one sample on September 20, 2002 in good condition. The
cooler was within the proper temperature range.
GC/MS Semivolatiles SIM:
There were no problems associated with the analysis.
Since insufficient sample volume was received to perform a matrix spike and matrix
spike duplicate, a Laboratory Control Sample (LCS) and Laboratory Control Duplicate
(LCD) were performed. All recoveries were within QC limits .
•
•
METHODS SUMMARY
C2I200203
ANALYTICAL PREPARATION
~P~ARAM==E~T=E~R'---------~------------METHOD ~M=E=T=H=O=D ____ _
8270C (SIM) SW846 8270C SIM SW846 3520C
References:
SW846 "Test Methods for Evaluating Solid Waste, Physical/Chemical
Methods 11 , Third Edition, November 1986 and its Updates· .
•
•
•
SAMPLE SUMMARY
C2I200203
WO# SAMPLE# CLIENT SAMPLE ID
ESKNH 001 SYSEFF/SV-305
NOTE(S)
• TI1e analytic:il results of the samples listed above are presented on the following pagiis .
• All calculations are performed before rounding to avoid round-off error~ in calcu!ared results .
• Results noted .as "ND" were not detected at or above the stated limit.
-Thi~ report must not be reproduced, except in full, without the written approval of the laboratory .
• Results for the following parameters are never reported on a dry weight basis: color, corrosivity, density, flaShpoint, igriiiabi!ir:y, layers. odor,
paint filter test. pH, porosity pressure, reactivity, rcdox potential, specific graYity, Spot testS,"so!ids, solubility, temperature, viscosity, and weight.
SAMPLED SAMP
DATE
09/19/02 13,18
Chain of Custody Record PA 000361
Project Name:~"'··:-U,(\ {t-Pu,,i \ Pmject /lumber: R .-Oc 1,"!-_ (')'"";) r,,~ -o1C
Send Report To: 0 · L 1<.. .... ., Sampler (Prir.t Name): A __ ,.,,.... ,\\;\\
Addre<s: ~VO ~o-'.v..t..--},_V~-Sampler (Print Name): -~
,.,_,~1 ,., I. '1 t4 ~ Shipment" Method: FJ Gx
Airbill Number: -Phone: laboratory· Receiving: m ,();-k.
Fax:
Sample Sample Sample Number of Field Sample IO Date · Time Matrix Containers
! <YSr:FP f S-J, :,o:t;; I 't\ \C\\lr~.-t'3l'ii Cw ~ .
..
rJ:h,d by (SJ:r Received by: {Signature) O_ate:
Fi-<1€;:.
Rennquished by: (Signature) Received by: (Signature) Date:
Relin(]Uished by; (Signature) Received by: (Signatur'e) Oat1::
White; Lab Copy Yellow:· PM Copy Pink: Field Copy Gold: PM/QA/QC Copy •
ThermoRetec Corporation
3040 William Pitt Way• Pittsburgh, PA 15238-1359
[phone] Phone • (412} 825-3,09 Fax www.thermoretec.com
t/ 'if-~
&. ,J'!
·" ~ rs
'C
1
1--t-
.
G fhermoRetec
smart Solutions. Positive outaims.s.
1/ / / Page __ of __
I 'I Pmchase Order#·
I Comments, Special lab Sample IO Instructions, etc. (to be complffi!d by lab)
nme: Sample Custodian Remarks "{Completed By Laboratory):
OA/OC Level Turnaround Sample Receipt
Time: Tola! # Containers Received?
level I D Routine D COC Seals Present?
Level II D 24 Hour D CDC Seals Intact? Tirne: level Ill D 1 Week D Received Containers Intact? Other D Other --Temperature? • •
• THE RETEC GROUP INC
Client Sample ID, SYSEFF/SV-305
GC/MS Semivolatiles
Lot-Sample ft ... ' C21200203-001 Work Order # ..• ' E8YJm1AA Matrix ......... : WATER
Date Sampled ... , 09/19/02 Date Received .. : 09/20/02 MS Run ft ..... -. '
Prep Date ...... : 09/23/02 .Analysis Date .. : 09/27/02
Prep Batch It •.• ' 2266315
Dilution Factor: 0.99 Method ......... , SW846 8270C SIM
REPORTING
PARAMETER RESULT LIMIT UNITS
2;4-Dichlorophenol ND 0.20 ug/L
Pentachlorophenol ND 0.99 ug/L
Phenol ND 0.20 ug/L
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
2 -Fluorophenol 58 (37 -115)
Phenol-dS 58 (41 -115)
·2,4,6-Tribromophenol 66 (40 115)
•
•
•
•
•
Client Lot# ... , C2I200203
MB Lot-Sample#, C2I230000-3l5
Analysis Date .. , 09/27/02
Dilutioil Factor: 1
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
2-Fluorophenol
Phenol-d5
2, 4, 6 -Tribromophen·ol
NOTE(S),
METHOD BLANK REPORT
GC/MS Semivolatiles
Work Order# ... , E8N2N1AA
Prep Date ....... , 09/23/02
Prep Batch# ... , 2266315
REPORTING
RESULT LIMIT UNITS
ND 0.20 ug/L
ND 1.0 ug/L
ND 0.20 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
64 (37 -115)
66 (41 -115)
57 (40 -115)
C;i.lcul~rions ar~ _performed before rounding 10 avoid round-off errors in calculated results .
Matrix ......... : WATER
METHOD
SW846 8270C SIM
SW846 8270C SIM
SW846 8270C SIM
• LABORATORY CONTROL SAMPLE EVALUATION REPORT
GC/'MS Semivolatiles
Client.Lot# ... , C2I200203 Work Order# ... , EBN2NlAC-LCS
EBN2NlAD-LCSD
Analysis Date .. , 09/27/02
Matrix ......... , WATER
LCS Lot-Sample#, C2I230000-315
Prep Date ...... , 09/23/02
Prep Batch# ... , 2266315
Dilution Factor: 1
PARAMETER
Phenol
Pentachlorophenol
2,4-Dichlorophenol
SURROGATE
2-FluorOphenol
Phenol-d5
• 2,4,6-Tribromophenol
NOTE (S) ,
PERCENT
RECOVERY
65
63
59
41
74
76
RECOVERY
LIMITS
(10 -131)
(10 -131)
(10 -140)
(10 -140)
(42 llS)
(42 llS)
PERCENT
RECOVERY
65
63
66
65
Bl
81
Calculations are performed before rounding to avoid round-off errors !n calculated results .
•
RPD
RPD LIMITS METHOD
SW846 8270C SIM
3.9 (0-43) SW846 B270C SIM
SW846 8270C SIM
36 (0-56) SW846 B270C SIM
SW846 8270C SIM
2.2 (0-44) SW846 8270C SIM
RECOVERY
LIMITS
(37 -llS)
(37 -ll5)
(41 -llS)
(41 -ll5)
(40 -115)
(40 -llS)
Effluent. Toxicity Report Form -Chronic Pass/Fail and Acute LCSO Date, 09/12/02
J.:acility, BEAZER
.aboratory Performing Test, TRITEST, INC.
NPDES#, NC
Cnarge
Si~r~ure or Laooratory Supervisor
Work Order, 020900075
MAIL ORIGINAL TO,
North Carolina Ceriodaphnia
Chronic Pass/Fail Reproduction Toxicity Test
CC·NTROL ORGANISMS 1 2 3 4 5 6 7 8 9 10
# Young Produced 24 24 27 24 28 24 28 25 29 29
Adult (L)ive (D) ead L L L L L L L L L L
Effluent %, 90%
TREATMENT 2 ORGANISMS 1 2 3 4 5 6 7 8 9 10
11
30
L
11
Pipe#, County, WAKE
Comments:
* PASSED, 6.90% Reduction*
Environmental Sciences Branch
Div. of Water Quality
N.C. DENR
1621 Mail Service Center
Raleigh, North Carolina 27699-1621
Chronic Test Results
Calculated t = 1.691
Tabular t = 2.508
12 % Reduction= 6.90
% Mortality Avg.Reprod.
27
0.00 26.58
Control Control
L
0.00 24.75
Treatment 2 Treatment 2
12 Control CV
8.557% PASS FAIL
# Young Produced 24 24 29 26 29 26 26 26
.dult (L) ive (D) ead L L L L L L L L
1st sample 1st sample 2nd sample
pH
Control
Treatment 2 ~ ~ ~
s s s
t e t e t e
a n a n a n
r d r d r d
t t t
1st sample 1st sample 2nd sample
D.rJ. ~ g [BB] Control
T:c·aatment 2
LC50/Acute Toxicity Test
22 25 19 21 % control orgs 0C
L
producing 3rd
brood Check One
L L L 100%
Complete This For Either Test
Test Start Date, 09/04/02
Collection (Start) Date
Sample 1, 09/03/02 Sample 2, 09/05/02
Sample Type/Duration
Grab Comp. Duration
Sample 1 X 24 hrs
Sample 2 X 24 hrs
Hardness(mg/1)
Spec. Cond. (µmhos)
D
I
L u
T
1st
s
A
M p
44 ::::::::::
224 831
2nd
P/F
s
A
M p
936
Chlorine (mg/1) <0.1 <0.1
Sample temp. at receipt(°C) 1.1 1. 3
(!,!ortality expressed as % , combining replicates) I
Note: Please
Complete This
Section Also
Organism Tested: Ceriodaphnia dubia
Concentration
Mortality
start/end
pH
Duration (hrs) :
Copied from DWQ form AT-1 (3/87) rev. 11/95 (DUBIA ver. 4.41)
start/end
D.O.
•
•
TRITEST, INC.
BioassayChain:ofCustody Form
Bioassays. are to be samnled a,fter 8: 30a .m. on
.· Tue-sday & Friday.
Facillt)' Name: 73.eao?r l ~-k r~
Addr~ss:~. P.O.#: ____________ _
County: . W J4-k-€
%Effiumt Diluticm : ·¢
Outfall/ Pipe # :
. ~ .
Phone# ( q7<? ) ?1/-I <-{;). J.
. Contact: 'P,J'~ R ~-;"' ·
G:!=F-. NP~ES Permit#: A-Jl1'.H::::: / i"Pfr
T~st Method : d~r,,._ ... : .. i'c._ TZ:ll(
· Sampl~SiteDescriptioii: ~~-£,&~
SampleColle~or: Print>~ a~~ }4:¼1\
· S1gnaturo>_...&"-"-"'--''-=-=--__,_rfj...,_:J//=-"----~--------
Sample Typ. e: Composite~:~_;. i·p.?-Ti"me ·. (!) iOO . . Date Stru1:od: --'""1+"1>-'-4<-A -f---~~-
Dat: Encied: t..{ ~ Time: -C)~Ot> --------------
Samples Ji'"nour: l ·#Hours: :.J-{
@or PM .
. ~ _@or PM
Date: _______________ _ Time:.......:===--'-A."1\1 or PM
Sample Volu...-ne: _ __,D...__.=c.£,=·..,_+-"' __ <. _____ Ch_i]led during Collection? i::'.
Method of Transportation to Lab: _.,_1,._.=...J_· ...c..· --'-,)J;"-'="-",v,,/----'--------~
; • • • + .., • • • + • • • • • • • • • • • • + • • • . . Cn8.in of C_ustOdy Release • ♦ • ♦ • ♦ ♦ • • ♦ •. ♦ • ♦ ' •• ♦ +. ♦ • ♦ ♦ ♦ • .
Relinautshed By. ,· . Dai,-, Time. Received Bv ' .. . Date Time I' "
.. ,, I 'i!Lil= I I.,. ;,io .£)/}?}17/J ;,; "J -... J "1 -u--n, i-Z //) I ·-
I ..
I
I
-.
C)C. ror Laboratory Use ~nly ~/ -/)
Receiving Tempera!ure: ----'/'--·-· -'-/ _______ By:~/'yh" ~
Residual Chlorine: ----'M'--"vb-· -"'f--'-. ______ Number of Bottles: _ _.2:::._ __ _
• Address: 3909·Bcr;i Rd.· R.?leigo., NC 27607 Phone[phone] Fex [phone]
•
•
•
TRITEST, INC.
Bioassay Chain :of Custody Form
Bioassays. are to be sampled 2,fter
. . .· Tue-sday &_ Friday.
Facility Name: Bt,.:,_2".1yy_.:. \ flltl.!~1, \_..
8:30a.:m. on
Addr~ss: ~/ . . P.O.#: ____________ _
300 Eo...\<vr A,..,,e.
County : . UV-A),<, L O:.1tfall/ Pipe # :
%Effiucnt Dilution : -----'M-___ _ ./ <:.;_ '-' r=..-F · Sample Site Description·: ---'~,:;.._;;..·1...:""---'"-~,....:c· ______________ _
Sample Collector: _Print>_~Zl:="'°'; ~~~~~-ii....,_,.;_\_! ___________ _
Signature >~C.,.,_.~....,.;;:J~·=....· --'--~--'------,----
Sample Type: Comoosite: \
1 Date Started: ___ · _C\-'-+-~-r-0--'~'-=-~---Twe :~or PM
Date Ended : ____ 9_ ..... \.,;G~\~o_·_J _____ Time, . cP}eo @i)or PM
Samples per Hour: ___ _,__ _______ #Hours: d 1 .
Date'---------"-=-------Time : ---.C....---'-A1v.I or PM ::: !'',~ :-S ~ e<· Sampl_e Volume: ---~~ ...... -~K.. ....... ~="-----C"n_illed during Co!kction?_..c_ t;cc.J __
Method of Transportation to Lab: --~th~c<--V~J~~M'--=. =J~'\_,_V_--''--------
•·• • • • • • ..... • ~ • • • ~ • + + + ••• • • • •-· ·c.a:iunofC_uStociyR.elease ·········••.•······•·.~······ ReiirHM\llsh::d. 3v. '
.., Datei Time Rec:ivedBv · Date Time I ,,,,,,. J '' w I op,:1t11--U/1~ I• 'lfM}yy];;, -; .) .· I "1-/. -,ri.-. il ,If ... I I ' I I I I .. I
-. ror Lahorazory Use Oruy
Receiving Temper&'ure: ----'/_. --'S_"_,,_.. ______ By. ~ Wl:i1-./k_ .
Residw,J Chlorine: ---~t-!~~~~Gz~_· _____ Number ofBot!les: -=-(T ___ _
Address: 3909·:Scryl Rd.-Rcieigi:l. NC 27607 Phone(9!9) 834 -4984 Fax [phone]· 0 2-r} Ii ".{)t[J 1 > ~ o {) 2. (
September I 0, 2002
Ms. Beverly Hudson
Remedial Project Manager
U.S. EPA -Region IV, I Ith Floor
North Site Management Branch
6 I Forsyth Street, SW
Atlanta, GA 30303
RE: Monthly Progress Report #112
Remedial Action
Koppers Site -Morrisville, NC
Dear Ms. Hudson:
The RETEC Group, Inc.
300 Baker Avenue, Suite 302
Concord, MA 01742
RETE(
[phone] Phone
[phone] Fax
www.retec.com
In accordance with the Unilateral Order, and on behalf of Beazer East, Inc. (Beazer), please find attached
four ( 4) copies of the August Monthly Progress Report for Remedial Action at the Koppers Superfund
Site in Morrisville, NC. No exceedances occurred during this event. However, since the July chronic
toxicity test failed, we are colleting on a monthly (rather than quarterly schedule) until we have passing
results for two consecutive months. Because the August chronic toxicity sample passed, a second
monthly chronic toxicity sample will be collected in September.
• Should you need additional information regarding this progress report, please call Mike Helbling at (412)
208-8858 or me at [phone].
•
Sincerely,
C1?f"L
Rita Bauer , [,
Project Geologist
CK:th
Enclosure
cc: D. Mattison--NC Superfund (2 copies)
L. Faulconer -Wake County
G. Caskey -Enwood Structures
M. Helbling -Beazer
F: \PR OJ E CTS\03 624 \Repo rts\M on th I y\20 02\8 M-02. doc
11 U L ,' SEp l l ,I/ ;
; 200'2 ,''/ i i L / I
< ; I,., ;-;;:-:·--. ·-----.· • -;
' _t '• !J' :~ ! n , ----....
' i ; I ., ' 1·1.. ' ., ._u ·...:: I .'C:'.'t; /
D. Hails -Ecological Restoration, In~:--'
J. Garrett -NC Division of Water Quality
D. Matthews -NC Div. of Waste Management
P. Kilchenstein -RETEC
•
•
•
MONTHLY PROGRESS REPORT #112
REMEDIAL ACTION
SITE NAME: Koppers Superfund Site
Beazer East, Inc.
Morrisville, NC
USEPA DOCKET NUMBERS: 93-09-C
PERIOD ENIHNG: August 31, 2002
1. PROGRESS MADE THIS MONTH
2.
3.
4.
5.
6.
7.
Remedial Action (RA) -HABITAT MITIGATION. No activities were conducted this
month.
Remedial Action (RA) -GROUNDWATER TREATMENT. The treatment system
operated throughout the month without upset. System performance was monitored on a biweekly basis. Approximately 38,650 gallons of groundwater were extracted, treated in
the treatment plant, and discharged between August 1, 2002 and August 31, 2002.
System water samples were collected on August 6, 2002 and August 23, 2002 in
accordance with the sampling schedule in the O&M manual. Samples were submitted to Severn Trent and Tritest, Inc. for laboratory analysis. The operations and sampling
programs are summarized on the attached Table I .
Remedial Action (RA) -EFFECTIVENESS MONITORING PROGRAM. No activities
were conducted this month.
Remedial Action (RA) -CORRESPONDENCE. None.
PROBLEMS RESOLVED None.
PROBLEMS ANTICIPATED None.
UPCOMING EVENTS Continue System O&M.
PERSONNEL CHANGES None.
SUBCONTRACTORS None.
ANALYTICAL DATA Analytical data from system influent and effluent sampling received during this period are enclosed and are summarized on Table 2 .
F :\PRO J ECTS\03 62 4\R cports\M onth I y\2 002\8 M-02. doc
•
Date Systems Cummulative SV-101 SV-101
Check Effluent Flow Sample Sample
(yes/no) (Gallons) (yes/no) Parameters
01/10/02 ves 3,251 280 no
•
Table 1
Groundwater Treatment Operations and Sampling Program Summary
Koppers Superfund Site
Morrisville, North Carolina·
August 2002
Associated SV-304 SV-304 Associated
Group Sample Sample Group (yes/no) Parameters
no
•
SV-305 SV-305
Sample Sample
(ves/no) Parameters
ves Penta, 2.4-Dichloro, Phenol
01/23/02 yes 3,264 850 yes Penta 2,4-Oichloro Phenol, Dioxin 1, 2 Penta, 2,4-0ichloro, Phenol, Dioxin, Chronic ves Penta, 2 4-Dichloro, Phenol 1 ves Tox 02/07/02 Yes 3 283 240 no
02/19/02 ves 3 300 140 no
03/06/02 ves 3 318 630 no
03/21/02 ves 3,338,440 no
04/02/02 Yes 3 356,200 ves Penta, 2,4-Dichloro, Phenol
04/17/02 ves 3 378 150 no
05/01/02 ves 3 397 920 no
05/13/02 ves 3 414 970 no
6/12/2002 yes 3 455 530 no
6/24/2002 ves 3467110 no
7/10/2002 ves 3,484 130 yes Penta 2.4-Dichloro Phenol
7/26/2002 yes 3,503,441 no
8/6/2002 ves 3515,200 no
8/23/2002 ves 3 536,650 no
Notes:
Sampling point SV-101 is located before the Carbon Units (pretreatment)
Sampling point SV-304 is located between the Carbon Units
Sampling point SV-305 is lactated after the Carbons Units (post-treatment)
NR • Not recorded
F:\Pfcjeds\0362~\Repofb\Monlhly\aM.02 Table his
no
no
no
no
1 yes Penta, 2,4-0ichloro. Phenol 1
no
no
no
no
no
, Yes Penta 2 4-Dichloro, Phenol 1
no
no
no
Associated Groups:
SV-101 -Group 1 is penta and 2,4-dichloropheno!; Group 2 is dioxin
SV-304 -Group 1 is penta and 2,4-dichlorophenol
Yes Penta, 2,4-Dichloro, Phenol
ves Penta, 2 4-Dich!oro, Phenol
ves Penta, 2 4-Dichloro, Phenol
ves Penta. 2 4-Dichloro, Phenol
Penta, 2,4-Dichloro, Phenol, Dioxin, Chronic
ves Tox
Yes Penta, 2 4-Dichloro, Phenol
ves Penta, 2 4-Dichloro, Phenol Chronic Tax
ves Penta, 2,4-Dichloro, Phenol
ves Penta, 2,4-Dichloro, Phenol Chronic Tax
yes Penta. 2 4-Dichloro, Phenol
Penta, 2,4-Dichloro, Phenol, Dioxin, Chronic
ves Tox
ves Penta, 2 4-Dichloro. Phenol
yes Penta, 2 4-Dichloro, Phenol Chronic Tax
Yes Penta, 2 4-Dich!oro, Phenol
SV-305 -Group 1 is penta, phenol, and 2,4-dichlorophenol; Group 2 is dioxin and Group 3 is chronic toxicity
Associated
Group
1
1 2,3
1
1
1
1
1 2,3
1
1,3
1
1 3
1
1,2,3
1
1,3
1
•
•
•
Table 2
Groundwater Treatment Analytical Data Summary
Koppers Superfund Site -Morrisville, North Carolina
August 2002
Analytical
Parameter Date Sample Sample
Sample Location Location
Collected SV-101 SV-304*
Pentachloronhenol 01/10/02
01/23/02 6.2 <1.0
02/07/02
02/19/02
03/06/02
03/21/02
04/02/02 24 <1.0
04/17/02
05/01/02
05/13/02
06/12/02
06/24/02
07/10/02 33 <1.1
07/26!02
08/06/02
08/23/02
2.4-0ichloroohenol 01/10/02
01/23/02 <0.20 <0.20
02/07/02
02/19/02
03/06/02
03/21/02
04/02/02 <0.20 <0.20
04/17/02
05/01/02
05/13/02
06/12/02
06/24/02
07/10/02 <0.21 <0.22
07/26/02
08/06/02
08/23/02
Phenol 01/10/02
01/23/02 <0.20 <0.20
02/07/02
02/19/02
03/06/02
03/21/02
04/02/02 <0.20 <0.20
04/17/02
05/01/02
05/13/02
06/12/02
06/24/02
07/10/02 <0.21 <0.22
07/26/02
08/06/02
08/23/02
Chronic Toxicitv 01/23/02
04/02/02
05/01/02
06/12/02
07/10/02
08/14/02
Dioxin f2.3.7,8-TCDD\ 01/23/02 <2.6
04/02/02
07/10/02
Notes: All results are in micrograms per literr(gll) except dioxin. Dioxin data is in picograms per liter {pg/L) .
SV-101 -Before Carbon Units
"SV-304 -Between Carbon Units
··sv-305 -After Carbon Units
F:\Projects\036241Reports\Monthly\8M-02 Table 2.xls
Sample
Location
SV-305°
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<0.96
<1.0
<0.98
<1.0
<1.0
<1.0
<1.0
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.19
<0.20
<0.20
<0.21
<0.20
<0.21
<0.20
<0.21
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.19
<0.20
<0.21
<0.20
<0.21
<0.20
Pass
Fail
Fail
Pass
Fail
Pass
<1.5
<0.62
<2.4
Effluent Toxicity Report Form -Chronic Pass/Fail and Acute LC50 Date, 08/26/02
Facility, BEAZER NPDES#, NC
aboratory Performing Test, TRITEST, INC.
Work Order, 0208-00582
MAIL ORIGINAL TO,
North Carolina Ceriodaphnia
Chronic Pass/Fail Reproduction Toxicity Test
CONTROL ORGANISMS l 2 3 4 5 6 7 8 9 10 11
Pipe#, County, WAKE
Comments:
* PASSED, 6.07% Reduction*
Environmental Sciences Branch
Div. of Water Quality
N.C. DENR
1621 Mail Service Center
Raleigh, North Carolina 27699-1621
Chronic Test Results
Calculated t = 1.083
Tabular t = 2.508
12 % Reduction= 6.07
% Mortality Avg.Reprod. # Young Produced 25 20 24 29 27 24 28 27 25 32 21 31
0.00 26. 08
Control Control Adult (L) ive (D) ead L L L L L L L L L L L L
0.00 24.50
Treatment 2 Treatment 2 Effluent %, '90%
TREATMENT 2 ORGANISMS l 2 3 4 5 6 7 8 9 10 11 12 Control CV
14 .011% PASS FAIL
# Young Produced 25 27 20 29 25 26 22 24 24 26 17 29 % control ergs 0C producing 3rd
brood Check One dult (L) ive (D) ead L L L L L L L L L L L L 100%
1st sample 1st sample 2nd sample Complete This For Either Test pH tB3BJ m ffi Test Start Date: 08/14/02 Control Collection (Start) Date
Sample 1, 08/12/02 Sample 2, 08/15/02 Treatment 2 Sample Type/Duration 8 8 8
1st s s s Grab Comp. Duration D t e t e t e I s a n a n a n Sample l X 24 hrs L A r d r d r d u M t t t Sample 2 X 24 hrs T p
1st sample 1st sample 2nd sample D.0. [8IB ~ Hardness(mg/1) so .......... .......... Control g Spec. Cond. (µmhos) 223 947 Treatment 2 8.3 8.1 l 0
Chlorine (mg/1) .......... <0.1 ..........
LC50/Acute Toxicity Test Sample temp. at receipt ( °C) l. 8
(Mortality expressed as %, combining replicates)
% % % % % % % % % %
I I I I I I I I I I I
Concentration
% % % % % % % % % % Mortalit
LCSO ~~--~% 95% Confidence Limits
% %
Method of Determination
Moving Average Probit
Spearman Karber Other
fiOrganism Tested, Ceriodaphnia dubia Duration(hrs):
y
start/end
pH
I
Copied from DWQ form AT-1 (3/87) rev. 11/95 (DUBIA ver. 4.41)
..........
I
Note: Please
Complete This
Section Also
start/end
D.O.
2nd
P/F
s
A
M p
..........
1015
<0.1
l. 7
•
•
T·RITEST, INC ..
Bio assay ChaL.,. of Custody Form
Bioassays. are to be sa.'!Unled a,fter 8:30a.ro. on . Tue-sday &: Friday.
?aciU!)' Name: ·062\z,~.,? /;Jct/._£; f. ti l Addr:ss: 3 OQ f,Ak;.,U.-4: v£-. ,fv ;7.L 3' o ~
Ol7Y2..-
P.O.#: ___________ _ C cc,I (o;:2/) , r'7J4 Phone# (CJ1 S
C,,;,,,ty : /;J ft lf-Outfall/ Pipe# : 0 0 /' NPDES Permit w·: M/111,v , /..§77:<fi'C..-%Efiluent Dilution : _. _,7"-·~··------T~stMethod: · ct1,4;,v1e,;, TD X • . Sample Site Desc:-iption: .Sy S-P.,::,'.Y'.\ g;,qc,
Sample Collector. . l?ri_nt > 'T£Pr L&4V',gzg;._
Signa..'ure> ~~.
·.~.
Sample Type: Comoosite :
Date Started : i [i-z.[ 0 2., Tim:: 010-0 @or PM'. Date Ended: g/n/o-z_
Ti."D.C: 0700 .'@or PM Sa.rnpk-s p~ !iol.lI': ·# E:ours: ;;zy ·
Grab:.
Date:
, Time: AM. or P.M SampJ_e Volume: :2.. (, I -,;;;;;,es . Chilled during Collection? y
J
..
• • 1 • • ~ • • • + • • • • • • + • + • + • • • • • · · Chain of Cµstody Rd.ease • ♦ ♦ • ♦ ♦ + •• • ♦ +. ♦ •.•• f • ♦ •·. ! ♦ ♦ ♦ ♦ ♦ . Relin auished By._ Date Time. Received By · Date Timo
/2',,.,-H. -,
~ 1 ~ ,,_ • i .,; I""-"<'· 1/2 • I~ .,,,__,. !r -/'< -o J . F71,~
i../ {/(./
I
I ..
. For Laboratory Use Only
· Receiving Temperature: --1--/.,,_,...,§.,_~ _______ By,&i/Yrl/7 /H~ Residu.nl Chlorine: __ /),_. -~_,_ ________ Number ofBDtt!:s: :)..
Ad'~ss: 39O9· B:ryl Rd.-Raleigh, NC 27607 Phonc(9 I 9) 834 -4984 Fox (9 !!;') 834-6491
r 0 t.c.,'J,f'> '6b ~ f ,J. -() I.! I
I
•
•
TRITEST, INC.
. I Bioassay Chain ·of Custody Form
Bioassays .are to be sampled a.fter 8:30a.m. ori Tue-sday Si:. Friday.
FaciWy Nam:: istff?:t242:~ J f34?:c:c Gt! I
Address: @£,T;:z.C._, P.O.#: ___________ _
. I . Cor--.1~1'<2 • mA-on y2...... · 7 .
Pb.one # ( '77 '( ) Tl/ -1 'f. 2-<-
Contact: . f;;7,Z'J &4 </RJ2..-
County: LU Af::'.F -0utfall/ Pipe# :CO / NPDES Permit i: ,..M=m:.:.2.1.V'-"-__,?t£[/&1"""==-<--
%E:fflucnt Dilution : ¢' ·. -7+-~-----. -T;si Method :-C/-/-4,vf C .,--o X
I . San1pl~ Site Description: ..:.f~V~,· =o:,,,,,--\:..:.._;~_,.C,...,~-<---=':.......-----------•
Sample Collector: _Print> · :::T~ L.64 kfC"/4'.
~ignature> ~d;.~
Sample Type: Composite :
Date Started : ---"~4-/ .... ; ('-'-f._a_Lc...,.. __ ~ ___ Tim: :~r Pllr°
Date Ended '--~i~l~1 '~6~o~]_..,-~· ------Tim;: ~r PM Samples per Hour: __ __._ ________ #Ho~: 2C/ · · ·
Grab:.
Date: ______________ _ Time:-------'-AM or PM Sampl_e Volume: ;L c..frp:zz. ~ Chilled during Collection? Y
Method of Transportation ta Lab: :&:½(,,;? (2(i:U~
; • • • • • • .,··• • • • • • • • + • • • • • • • • • · · Ch"• ofC_USto·· a·yn .. t...,.,.,.e. • • • • • • • • • + • • • • • • + + • • • • ·
....... L\,,,i;J...,..,;, • . ••• • • Rdin.c,u\,hed.Bv Date Timo. ReceivedBv · Date Time //-.,,,,---;,,,:::-7.,., .. A ✓ ,g (1<./c""L !Ll{O · -&n. , . r-11, --vL-7vro , v· u ' -
..
. For Laboratory Use Only
· Receiving Temperature: _ _,__/_,_7 ........ @_<J.. ______ By:~ ikz?,~
Residlll!l Chlarino: __ ___,_p/~@~~;,:r,___· _____ Number of Bottles: ;}-
Address: 3909-Beryl M.-Raleigh, NC 27607 Phane(9!9) 834 -4984 ?ax (91~) 834-6491 -I) Z,o ff ---cvr;i; ~ -co 2---(
•
•
•
ANALYTICAL REPORT
Raleigh, Biweekly NPDES
Lot JI: C2H070l.6"7
Rita Bauer
The RETEC Group Inc
SEVERN TRENT LABORATORIES, INC.
STL Pittsburgh
450 William Pitt Way
P;ttsburgh, PA 15238-1330
Tel: [phone]
Fa~ 412 820 2080
www.stl-inc.com
u~J~ r~
Veronica Bertot
Project Manager
August 1.4, 2002
STL Pittsburgh is a part of Severn Trent Laboratories, Inc.
~---------------------------------------------
Sample Receiving:
CASE NARRATIVE
THE RETEC GROUP
Raleigh, Biweekly NPDES
STL Lot# C2H070167
STL Pittsburgh, PA received one sample on August 7, 2002 in good conclition. The
cooler was within the proper temperature range.
GC/MS Semivolatiles SIM:
The reporting limits were adjusted according to the amount of sample extracted.
Since insufficient sample volume was received to perform a matrix spike and matrix
spike duplicate, a Laboratory Control Sample (LCS) and Laboratory Control Duplicate
(LCD) were performed. All recoveries were within QC limits.
•
•
•
•
•
•
MEfflODS SUMMARY
C2H070167
ANALYTICAL PREPARATION
PARAMETER METHOD ~M~E~T~H~O~D:_ ___ _
8270C (SIM) SW846 8270C SIM SW846 3520C
References:
SW846 11Test Methods for Evaluating Solid Waste, Physical/Chemical
Methodsn, Third Edition, November 1986 and its updates .
_____________________________________________________________ ,_
SAMPLE SUMMARY
C2H070167 •
WO# SAMPLE# CLIENT SAMPLE ID
E52JC 001 SYS EFF ./SV-305
NOTE(S)
-lbe analytical results of the samples lls:ied above are pres.emed on The following pages.
• All c.tlculations are perfonned before rounding to avoid round-off erron in calculated resul13.,
-Results noted as "ND" wue no1 deu:Cled at or above lhe stated limit.
-This report must not be reproduced, except in full, without the written approval of the laboratory.
• Results for the following parameters are never reported on a dry ~ght basis: color, corrosivity, density, flashpoint, ignitability, layen, odor,
paint filter test, pH, porosity pressure, reactivity, rcdox polcnlial, specific gravity, :spol tests, solids, solubility, tcmperarure, viscosi1y, and weight.
SAMPLED SJIMP
DATE
08/06/02 13:20
•
•
•
Client: ~/
\ddress: 'Jf!::t c¥.i,,; /J.-v <.,
\ddress: G J MA-,onc.f l I
Juote #: ________ _
. . .
•
Chain-.of Custody Record & Analytical Request 30363
[ of_/_ Page
COC#
Report To: _________ _
Invoice To:
NC __ SC __ Other __ _
J.. ({
I
ORIGINAL
SEE REVERSE FOR
TERMS ANDCONDUWNS
---------------------------------------------------
THE RETEC GROUP INC
Client Sample ID: SYS EFF./SV-305
GC/MS Semivolatiles
Lot~.sample # ... : C2H070167-001 Work Order# ... : E52JC1AA
Date Received .. : 08/07/02
Analysis Date .. : 08/13/02
Matrix .•... c ••• : WATER
MS Run # •••••.• : Date Sampled ... : 08/06/02
Prep Date ••.... : 08/09/02
Prep Batch# ..• : 2221283
Dilution Factor: 1.04
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-dS
Terphenyl-dl4
·2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
Method ......... : SW846 8270C SIM
REPORTING
RESULT LIMIT UNITS
ND 0.21 ug/L
ND 1.0 ug/L
ND 0.21 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
76 (30 -121)
64 (11 -119)
73 (39 -115)
70 (37 -115)
71 (41 -115)
65 (40 -115)
•
•
•
•
•
•
METHOD BLANK REPORT
GC/MS Semivolatiles
Client Lot# ... , C2H070167 Work Order# ••• , E57FDlAA
MB Lot-sample#, C2H090000-283
Analysis Date .. : 08/13/02
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-ds
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2, 4, 6-Tr1bromophenol
NOTE(S):
Prep Date .....• , 08/09/02
Prep Batch# •.. , 2221283
REPORTING
RESULT LIMIT
ND 0.20
ND l. 0
ND 0.20
PERCENT RECOVERY
RECOVERY LIMITS
70 (30 -121)
58 (11 -119)
66 (39 -115)
66 (37 -115)
66 (41 -115)
55 (40 -115)
Calculations are pafom:lcd before rounding to .avoid rou~.-off errors in calculated results .
UNITS
ug/L
ug/L
ug/L
Matrix •••.•••.. , WATER
METHOD
SW846 8270C SIM
SW846 8270C SIM
SW846 8270C SIM
---------------------------------------------------
LABORATORY CONTROL SAMPLE EVJ\LUATION REPORT
GC/MS Semivolatiles
Client Lot# ... : C2H070167 Work Order# .•. : E57FD1AC-LCS
E57FD1AD-LCSD
Analysis Date .. : 08/13/02
Matrix. __ ...... : WATER
LCS Lot-Sample#:
Prep Date ...••. :
Prep Batch # ••• :
C2H090000-283
08/09/02
2221283
Dilution Factor: 1
PARAMETER
Phenol
Pentachlorophenol
PERCENT
RECOVERY
67
66
66
66
2,4-Dichlorophenol 70
71
SURROGATE
Nitrobenzene-ds
Terphenyl-d14
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
NOTE(S):
RECOVERY
LIMITS
(10 -131)
(10 -131)
(10 -140)
(10 -140)
(42 -115)
(42 -115)
PERCENT
RECOVERY
73
75
60
60
71
. 72
66
65
63
62
72
72
Calcula1ions are performed before rounding to a ... oid round-off errors in calculated results.
RPD
RPD LIMITS METHOD
SW846 8270C SIM
2.2 (0-43) SW846 8270C SIM
SW846 8270C SIM
0.61 (0-56) SW846 8270C SIM
SW.846 8270C SIM
1.3 .(0-44) SW846 8270C SIM
RECOVERY
LIMITS
(30 -121)
(30 -121)
(11 -119)
(ll -119) ·
(39 -115)
(39 -115)
(37 -115)
(37 -115)
(41 -115)
(41 -115)
(40 -115)
(40 -115)
•
•
•
•
•
•
ANALYTICAL REPORT
Raleigh, Biweekly NPDES
Lot ff: C2H240120
Rita Bauer
The RZTEC Group Inc
SEVERN TRENT LABORATORIES. me.
Veronica Bertot
Project Manager
September 5, 2002
STL Pitlsburgh is a pilrt of Severn Trent Laboratories, lnC.
sn. Pittsburgh
450 William Pitt Way
Plttsbur8'1, PA 15238-1330
Tel: [phone]
Fax: 412 B20 2080
www.stl~nc.com
--------------------------
Sample Receiving:
CASE NARRATIVE
THE RETEC GROUP
Raleigh, Biweekly NPDES
STL Lot# C2H240120
STL Pittsburgh, PA received one sample on August 24, 2002 in good condition. TI:ie cooler was within the proper temperature range.
GC/MS Semivolatiles SIM:
There were no problems associated with the analysis,
Since insufficient sample volume was received to perform a matrix spike and matrix spike duplicate, a Laboratory Control Sample (LCS) and Laboratory Control Duplicate (LCD) were performed. All recoveries were within QC limits.
•
•
• METHODS SUMMARY
C2H24.0120
ANALYTICAL .PREPARATION
;P~ARAME==~T~E~R'--------'--~~----~-'------METHOD ~ME=T~H~O~Dc_ ___ _
8270C. (SIM) SWB{6 8270C SIM S~846 3520C
ReferenceS:
SW846 "TeSt Methods for Evaluating Solid Waste, Physical/Chemical
Methods", Third Edition; November 1986 and its updates.
----------------------------------------------------------
SAMPLE SUMMARY
C2H240120 •
WO # SAMPLE# CLIENT. SAMPLE ID
.SAMPLED SAMP ·
DATE ·TIME -----
E657D 0 OJ. SYS EFF 08/23/02 J.2:30
NOTE (S}:.
-1k analytical results of lbc saaiples listed abO"Ye arc presented on th0 following pages.
-All calculations ate performed before n;imxting to avoid round-off wars iri c.alcitlated results.
• ResuJtll noted as •ND• were not detected at or above the Stated limit.
-This report must npt be rcprcduced, exc:c:pt in full, without the written approval of the laboratory.
-Results for lbc following parameters are never reported on a di-y ~ei~ basis: co!Or. C:Orrosivity' density. fluhpoint, ignitability' la yen, odo'r.
paint filter lest, pH, porosily pressure, .reactivity, rcdox potentiil., specific gravity, spot tests, solids, solubility, tempcr.i.ru:re, viscosity, and weight,
•
•
•
I.
j
I
l
I
I .,
I
I
I ,.
' I
I
I
I I·
I
t
I
I I
I I
~ . : ..
I
I
I
I
I
I . I
I
I
' I
I
1 ·
I '
Chaindf .
Custody Record
STL..,.124 !0901)
Client(< £T.£t".
Address·
.JC() A~~,_,:~_.,, bl/&.. ru c1ZZ,, J"~ z_,
City
,:~ l
21~/1YC CO ... 1 .,.. n:A.
P;oject Name fnd Location_ (State)
fl r.. -F/L-/#f'6.ktff-
· ~ontracf/Purch~se Ortpr/Ouole Np.
Sample l,D. No. and Description.
· (Containeis lor..each sample may'be cpmbined on one line} Date
-S"\rS. tz;,t:r: .. -1 _J,1. " . . '~---,
.
. .
Possible Hazard Identification·
•
Project Manager
£r,,4 t? ./4..i ,¢.
T~;e Number (Area Code)/Fax Number . .) .71, •f'f?,:z . .,
Site Coiitact Lab Contact
Carrier/Waybill Nt1mber
r=-~.cic-
Matrix Contain'ers &·
Preservatives
i n •. 8 ,: "Ii Trme 0 ~ ~ J ~ ~ ·O .•. ~ ~ ~ ~~ ~ .~
}?'.1C'l .'A ~
. I
D NOn-Hazard □·Aammab1e 0 Skin ·Irritant 0 PoisonB
. I Sample Disposal
0 Unki:iown □· Return To Client. 0 Disposal By L,sb
~
. \,
" !
~
X
. .
0 Archive. For _Tum Around Tune Requ,red
D 24 Hours O · 48 Hours
QC Requirements (SpeCJfy)
· 0-7-0ays. □ ·14 Days·· 0-21 Da}'S Oott,er.
f. Relinql,JfShBd By·· 1. Rec8ived"By
2. Ralitiqulshed B ·2. Received By
.3 .. Reflf'1quishad.By Dale
Comments
DISTRIBUTION:· WH(TE • RelumedJ'? Cfienl wit~ Rf1PM; CA_NARY • Stays with-fhe·sample; PINK -Field Copy
•
Severn Trent Laboratories, In<
Date ), g Z1, 0"l.,.. Ch,frlol~i'ts~r41
·Lab Number
Page I ol I
Analysis (Attach list if mores ace·is needed
-Special Instructions/
Conditions of Receipt
-
,
(A fee may be assessed if samples are retained
Months . longer lhan t m~nth)
Da/B nme
O?te nma
}{. nme -2¥-02. IC>
Lot-Sample # ••• : C2H240120-001
Date Sampled.c.: 08/23/02
P:r:ep Date, ..... : 08/28/02
P:r:ep Batch# ... : 2240326
D)_lution Factor: l
PARAMETER
2,4-Dichlorophenol
P,entachlorophenol
Phenol
SURROGATE
Nitrobenz~ne-ds
Terphenyl-di4
2-Fluo:J':Obiphenyl
:=: -Fluorophenol
Phenol-dS
2, 4, 5·-Tribromophenol
THE RE'l'EC GROUP lNC
Client Sample ID: SYS EFF
GC/MS Sem:i;volatiles
Work Order# ... : E657DlAA
Date Received .. : 08/24/02
Analysis Date •• : 09/04/02
Mat:i"i.x ... .; ..... : WATER
MS Run# ....... :
Method ...•..... : SW846 8270C SIM
REPORTING
RESULT LIMIT UNITS
ND 0.20 ug/L
ND 1.0 ug/L
ND 0 .20,, ug/L
PERCENT RECOVERY
RECOVERY LIMITS.
81 (30 -12:J.)
66 (l'i -119)
69 (39 -115)
69 (37 -115)
68 (41 -115)
99 (40 -115)
•
•
•
•
Client Lot# ... : C2H240120
MB Lot-Sample#: C2H280000"326
Analysis Date .. : 09/04/02
DilutiOD. Factor: 1
PARAMETER
2,4-Di-Chlo"rophenol
Pentachlorophenol
Phenol ·
SURROGATE
Nif:.robenzene-dS
Terphenyl-dl4·
2-Fluorobiphenyl
2~Fluoropheno).
Phenol-dS
. 2, 4, 6 -·Tr1biomophenol
NOTE (S):,
METHOD BLANK REPORT
Ge/MS Semivolatiles
Work Order # ... : E7CQFl.AA
Prep Date .•.. c.: 08/28/02
Prep Batch# ... : 2240326
REPORTING
RESULT LIMIT UNITS.
ND 0.20 ug/L
ND 1.0 ug/L
ND 0.20 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
69 (30 -121)
57 Ill -119)
61 (39 -ll5)
64 13'7 -115)
64 (41 -115)
BO (40 -ll5)
• · Cal~fatioltt arc pe:rfornli::d before rounding to ~void rou.'Yl-off erron in calcul;i.ted results.
Matrix ........ ;: WATER
METHOD
SW846 8270C SIM
SW846 8270C SIM
SW846 8270C SIM
LABORATORY CONTROL SAMPLE EVALUATION REPORT
GC/MS Semivolatiles
Client Lot # •.• : C2H240120 work Order # ... : _ E7CQF1AC-LCS Matrix ••••••••• : WATER
LCS Lot-Sample#: C2H28.0000-326 E7CQF1AD"LCSD
Prep Date .•• : •• : 08/2a/02 Analysis Date •• : 09/04/02
Prep.Batch# ••• : 2240326
Dilution FaC:tor: 1
PARAMETER
Phenol
Pentachlorophenol
2 ·, 4-DichlOrophenol
SURROGATE
Nitrobenzene-d5
Terphenyl0 dl4
2~Fluoi-6biphenyl
2-Fluorophenol
Phenol-d5
2,4;6-Tribromopheiloi
NOTB(Sl:
PERCENT
RECOVERY
67
66
86
82
83
83
. Calculatioris arc performed before rounding to avoid roum:.o« crm"S in caladatcd rcnuu.
RECOVERY
LIMITS
(10 131)
(10 • 131)
(10 -140).
(10 -140)
(42 -115)
(42 -115)
PERCENT
RECOVERY
8:L
83
64
63
72
68
73
68
69
67
105
109
RPD
~ LIMITS
2.2 (0-4J)
3.8 (0-56)
0.26 (0-44)
RECOVERY
LIMITS
(30 -121)
(30 -121)
(11 -119)
(11 -119)
(39 -115)
(39 ° 115)
(37 -115)
(37 115)
(41 -115)
(41 -115)
(40 • 115)
(40 -115)
METHOD
Sl'/846 8270C SIM
Sl'/846 8270C SIM
Sl'/846 '8270C SIM
Sl'/846 8270C SIM
SW846 il270C SIM
Sl'/846 8270C SIM
•
•
•
•
•
August 9, 2002
Ms. Beverly Hudson
Remedial Project Manager
U.S. EPA -Region IV, 11th Floor
North Site Management Branch
(i I Forsyth Street, SW
Atlanta, GA 30303
RE: Monthly Progress Report #111
Remedial Action
Koppers Site -Morrisville, NC
Dear Ms. Hudson:
The RETEC Group, Inc.
300 Baker Avenue, Suite 302
Concord, MA 01742
[phone] Phone
[phone] Fax
www.retec.com
!11 accordance with the Unilateral Order, and on behalf of Beazer East, Inc. (Beazer), please find attached
four (4) copies of the July Monthly Progress Report for Remedial Action at the Koppers Superfund Site in
Morrisville, NC. No exceedances occurred during this event. However, the Chronic Toxicity sample did
-fail. Based on this failure, we will collect chronic toxicity samples on a monthly basis until two
consecutive monthly tests pass .
Should you need additional information regarding this progress report, please call Mike Helbling at (412)
208-8858 or me at [phone].
Sincerely,
@A:~~
Rita Bauer , v-JC:l
Project Geologist
CK:th
Enclosure
cc: D.-Mattison -NC Superfund (2 copies)
L. Faulconer -Wake County
G. Caskey -Enwood Structures
M. 1-lelbling -Beazer
F: \PR OJ E CTS\O 3 6 2 4 \ Rcpo rts\M onth I y\2 002 \ 7 M -0 2.doc
D. Hails -Ecological Restoration, Inc.
J. Garrett -NC Division of Water Quality
D. Matthews -NC Div. of Waste Management
P. Kilchenstein -RETEC
•
•
•
MONTHLY PROGRESS REPORT #111
REMEDIAL ACTION
SITE NAME: Koppers Superfund Site
Beazer East, Inc.
Morrisville, NC
USEPA DOCKET NUMBERS: 93-09-C
PERIOD ENDING: July 31, 2002
I. PROGRESS MADE THIS MONTH
2.
3.
4.
5.
6.
7.
Remedial Action (RA) -HABITAT MITIGATION. No activities were conducted this
month.
Remedial Action (RA) -GROUNDWATER TREATMENT. The treatment system
operated throughout the month without upset. System performance was monitored on a
biweekly basis. Approximately 36,330 gallons of groundwater were extracted, treated in
the treatment plant, and discharged between July 1, 2002 and July 31, 2002. System
water samples were collected on July 10, 2002 and July 26, 2002 in accordance with the
sampling schedule in the O&M manual. Samples were submitted to Severn Trent and
Tritest, Inc. for laboratory analysis. The operations and sampling programs are
summarized on the attached Table 1.
Remedial Action (RA) -EFFECTIVENESS MONITORING PROGRA1vf. No activities
were conducted this month.
Remedial Action (RA) -CORRESPONDENCE. None.
PROBLEMS RESOLVED None.
PROBLEMS ANTICIPATED None.
UPCOMING EVENTS Continue System O&M.
PERSONNEL CHANGES None.
SUBCONTRACTORS None.
ANALYTICAL DATA Analytical data from system influent and effluent sampling
received during this period are enclosed and are summarized on Table 2 .
F: \PRO J ECTS\0J 6 2 4\Rcports\M onth I y\2 002\ 7 M-0 2.doc
•
Date Systems Cummulative SV-101 SV-101
Check Effluent Flow Sample Sample
{veslno) (Gallons) (ves/no) Parameters
01/10/02 ves 3 251 280 no
•
Table 1
Groundwater Treatment Operations and Sampling Program Summary
Koppers Superfund Site
Morrisville, North Carolina
July 2002
Associated SV-304 SV-304 Associated
Group Sample Sample Group
{ves/no) Parameters
no
•
SV-305 SV-305
Sample Sample
(ves/no) Parameters
yes Penta, 2 4-Dichloro Phenol
Penta, 2.4-Dichloro, Phenol, Dioxin, Chronic
01/23/02 ves 3 264 850 ves Penta 2 4-Dichloro Phenol Dioxin 1 2 ves Penta 2 4-0ichloro Phenol 1 yes Tox
02/07/02 ves 3 283 240 no
02/19/02 ves 3 300.140 no
03/06/02 ves 3 318 630 no
03121/02 ves 3 338 440 no
04/02/02 ves 3,356 200 ves Penta 2 4-Dichloro Phenol
04/17/02 ves 3378150 no
05/01/02 ves 3 397 920 no
05/13/02 ves 3414970 no
6/12/2002 ves 3 455 530 no
6/24/2002 ves 3467110 no
7/10/2002 ves 3.484 130 ves Penta, 2 4-Dichloro Phenol
7/26/2002 ves 3.503 441 no
Notes:
Sampling point SV-101 is located before the Carbon Units (pretreatment)
Sampling point SV-304 is located between the Carbon Units
Sampling point SV-305 is lactated after the Carbons Units (post-treatment)
NR -Not reCOl"ded
f:\Plojects\Ol62~\Reports\Manlhly\71d---()2 Table 1..>:15
no
no
no
no
1 ves Penta 2 4-Dichloro Phenol 1
no
no
no
no
no
1 yes Penta 2 4-Dichloro Phenol 1
no
Associated Groups:
SV-101 -Group 1 is penta and 2,4-dichlorophenol; Group 2 is dioxin
SV-304 -Group 1 is penta and 2,4-dichlorophenol
yes Penta 2 4-Dichloro Phenol
ves Penta 2 4-Dichloro Phenol
ves Penta 2 4-Dichloro, Phenol
yes Penta, 2 4-Dichloro, Phenol
Penta, 2,4-Dichloro, Phenol, Dioxin, Chronic
ves Tox
ves Penta 2 4-Dichloro, Phenol
yes Penta 2 4-Dichloro Phenol Chronic Tax
yes Penta 2 4-Dichloro Phenol
ves Penta 2 4-Dichloro Phenol Chronic Tox
ves Penta 2 4-Dichloro Phenol
Penta, 2,4-Dichloro, Phenol, Dioxin, Chronic
yes Tox
yes Penta 2 4-Dichloro
SV-305 -Group 1 is penta, phenol, and 2,4-dichlorophenol; Group 2 is dioxin and Group 3 is chronic toxicity
Associated
Group
1
1 2,3
1
1
1
1
1,2 3
1
1 3
1
1 3
1
1 2,3
1
•
•
•
Table 2
Groundwater Treatment Analytical Data Summary
Koppers Superfund Site -Morrisville, North Carolina
July 2002
Analytical
Parameter Date Sample
Sample Location
Collected SV-101
Pentachloroohenol 01/10/02
01/23/02 6.2
02/07/02
02/19/02
03/06/02
03/21 /02
04/02102 24
04/17/02
05/01/02
05/13/02
06/12/02
06/24/02
07/10/02 33
07/26/02
2.4-Dichloroohenol 01/10/02
01/23/02 <0.20
02/07102
02/19/02
03/06/02
03/21/02
04/02/02 <0.20
04/17/02
05/01/02
05/13/02
06/12102
06/24/02
07110/02 <0.21
07/26/02
Phenol 01/10/02
01/23/02 <0.20
02107102
02119/02
03/06/02
03/21/02
04/02/02 <0.20
04/17/02
05/01/02
05/13/02
06/12/02
06/24/02
07/10/02 <0.21
07/26/02
Chronic Toxicitv 01/23/02
04/02/02
05/01/02
06/12/02
07/10/02
Dioxin (2,3,7,8-TCDDl 01/23/02 <2.6
04/02/02
07/10/02
Notes: All results are in micrograms per liter (µg/L) except dioxin. Dioxin data is in piccgrams per liter (pg/L).
SV-101 -Before Carbon Units
"SV-304 -Between Carbon Units
· ··sv-305 -After Carbon Units
F:\Projects\03624\Reports\Monthly17M-02 Table 2.x!s
Sample
Location
SV-304'
<1.0
<1.0
<1.1
<0.20
<0.20
<0.22
<0.20
<0.20
<0.22
Sample
Location
SV-305*"'
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<0.96
<1.0
<0.98
<1.0
<1.0
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.19
<0.20
<0.20
<0.21
<0.20
<0.21
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.19
<0.20
<0.21
<0.20
Pass
Fail
Fail
Pass
Fail
<1.5
<0.62
<2.4
ANALYTICAL REPORT.
Raleigh, Biweekly NPDES
Lot #: C2Gl.l.Ol.23
Rita Bauer
The RETEC Group Inc
SEVERN.TR.ENT LABORATORIES, INC.
Project Manager
• July 30, 2002
STL Pittsburgh is a part of Severn Trent laboratories, Inc.
STL Pittsburgh
450 William Pitt Way
Pittsburgh, PA 15238-1330
Tel: [phone]
Fax: [phone]
www.stl-inc.com
__________________________________________ ,_
· CASE NARRATIVE
THE RETEC GROUP
Raleigh, Biweekly NPDES
STL Lot# C2Gl 10123 •
Sample Receiving:
STL Pittsburgh, PA received samples on July 11, 2002 in good condition. The cooler
was within the proper temperature range.
GC/MS Semivolatiles SIM:
For all samples, the.reporting limits were adjusted according to the amount of sample
extracted.
Sample SV-101 was analyzed at a dilution due to the concentration ofpentachlorophenol
detected.
Dioxins:
STLWest Sacramento performed the dioxin analysis. All results are included in the
report.
•
•
•
•
METHODS SUMMARY
C2Gll0l23
. PARAMETER·
Dibenzodioxins and Dibenzofurans, HRGC/HRMS
8270C (SIM)
References:
ANALYTICAL PREPARATION
METHOD ~M~E~T~H~O~D:.._ ___ _
SW846 .8290 SW846 8290
SW846 8270C SIM SW846 3520C
SW846 "Test Methods for Evaluating Solid Waste, Physical/Chemical
Methods 11
1 Third Edition, November 1986 and its updates .
WO# SAMPLE# CLIENT SAMPLE ID
E4HDH
E4HDJ
E4HDK
NOTE(S):
001
002
003
SV-101
.SV-304
SV-305
SAMPLE SUMMARY
C2Gll0123
-The :malytical results of the samples listed above are Presented on the.following pages.
• All calculations are performed before rounding to avoid round-off errors in calculated results.
-Results noted as MND" were not detected at or above the stated limit.
·• This repon must not be reproduced, except in full, without the'wrinen approval of the laboratory.
• Results for the following parameters are never reponed On a dry weigh I basis: color. corrosiviry, density. flashpoint, ignitability, layers, odor,
paint filter test, pH, porosity pressure, rcactiyiry, redox potential, specific gravity, spot tests, solids, solubility, temperature, visc.osiry, and weight.
SAMPLED
DATE • SAMP
TIME
07/10/02 08:10
07/10/02 OE:20
07/10/02 OE,: 30
•
Chain dr ■1
Custody Record
S::rL 4124 {1200)
Clienr~U
Address
300 Ko,..,~-. .f\-J~
City _1 C~o'f1
I State I Zip Code (Y)i'\ o\'1'{"-
Project Name and Loc~rn (~ ·.•
~-eo-zer Cr-a\-.
Con/racl/Purchase Orddr!Quo/e No I
Sample I. D. No. and Description Date (Containers for each sample may be combined on one fine}
Sv-101 1ho/ :i.
Sv-3o'-/
Sv -Jo,;-\ I/
Possible Hazard Identification
0 Non-Hazard 0 Flammable D Skin Irritant D Poison B
•
Projec~ager -~ -. "er " Telephone Number (Area Code)/Fax Number
97<i;-3'1l-1 '--{~)--.
Sile Contact Lab Can/act
Carrier/Waybill Number
Matrix Containers &
Presetvalives
' • 0 ~ , ~, Time ' ti n ~ 0 G 0 qO
~ a • 11 " ,' " • ~~ s ~ ~ ~ , , "
oi1v -( f.
W)D
nf5v V ✓
.
..
I Sample Disposal
efunknown O Return To Client ~posal By Lab
i Vl
(
Ji
I-
1-x
1-i
• !SEVERN
!TRENT_
j. SERVICES -Severn Trent Laboratories, Inc.
Date
I of J_
Chain of Custody Number
1 103675
Lab Number ( 7 Page of
Analysis (Attach list if
more s 1ace is needed
._J
] Special Instructions/
Conditions of Receipt ~
(A fee may be assessed 1f samples are re/ained D Archive For Months longer than 3 months)
Turn Around Time Required QC Requirements (Specify)
0 24 I-lours O_ 14 Days D 21 Days
1_ Relinquished By _J) Time
2 Relinquished By Time
3. Relinquished By Time
Comments
(}OD
DISTRIBUflON: WHITE -Slays with the Sample; CANARY -Re/urned to Client with Report; PINK -Field Copy
------------------------------------------------------
Lot-Sample# ... : C2Gl10123c001
Date Sampled ... : 07/10/02
Prep· Date ...... : 07 /12/02
Prep Batch# ... : 2193291
Dilution Factor: 1.05
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribrornophenol
NOTE (S):
THE RETEC GROlJP INC
Client Sample ID: SV-101
GC/MS Semivolatiles
Work Order# ... : E4HDH1AA
Date Received .. : 07/11/02
Analysis Date .. : 07/17/02
Matrix ......... : WATER
MS Run# ....... :
Method ......... : SW846 8270C SIM
REPORTING
RESULT ·LIMIT UNITS
ND 0.21 ug/L
63 E. 1.0 ug/L
ND 0.21 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
69 (30 121)
63 (11 -119)
.65 (39 -115)
70 (37 -115)
71 (41 -115)
68 (40 -115)
E Estimated result. Result concentration exceeds the calibration range. •
•
• Lot-Sample# ... : C2Gll0123-001
Date Sampled ... : 07/10/02
Prep Date ...... : 07/12/02
Prep Batch# .... , 2193291
Dilution Factor: 5.25
PARAMETER
2, 4 -Dichloroph.enol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2 .. 4, 6-Tribromophenol
•
TIIE RETEC GROUP INC
Client Sample ID: SV-l0l
GC/MS Semivolatiles
Work Order# ... : E4HDH2AA
Date Received .. : 07/11/02
Analysis Date .. : 07/17/02
Matrix ......... : WATER
MS Run# ....... :
Method ......... : SW846 8270C SIM
REPORTING
RESULT LIMIT UNITS.
ND l.O ug/L ·
33 5.2 ug/L
ND 1.0 ug/L
·PERCENT RECOVERY
RECOVERY LIMITS
68 (30 -121)
58 (ll -ll9)
68 (39 -llS)
71 (37 -llS)
78 (41 ll5)
50 (40 -ll5)
-----------------------------------------------
Lot-Sample# ... : C2G110123-002
Date Sampled ... : 07/10/02
Prep.Date ...... : 07/12/02
Prep Batch# ... : 2193291
Dilution Factor: 1.08
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribrornophenol
THE RErEC GROuP INC
Client Sample ID: SV-304
GC/MS Semivolatiles
Work Order# ... : E4HDJ1AA
Date Received .. : 07/11/02
Analysis Date .. : 07/17/02
Matrix ......... : WATER
MS Run# ....... :
Method ......... : SW846 8270C SIM
REPORTING
RESULT LIMIT UNITS
ND 0.22 ug/L
ND 1.1 ug/L
ND 0.22 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
77 (30 -121)
·75 (11 -119)
79 (39 -115)
65 (37 -115)
72 (41 -115)
76 (40 -115)
•
•
• Lot-Sample# ... : C2Gll0123-003
Date Sampled ... : 07/10/02
Prep Date ...... : 07/12/02
Prep Batch# ... : 2193291
Dilution Factor:· 1.03
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
·Phenol
SURROGATE
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-dS
2,4,6-Tribromophenol
•
•
TIIE R.ETEC GROUP INC·
Client Sample ID: SV-305
GC/MS Semivolatiles
Work Order# ... : E4HDK1AA
Date Received .. : 07/11/02
Analysis Date .. : 07/17/02
Matrix ......... : WATER
MS Run# ....... :
Method ........ ·.: SWB46 8270C SIM
REPORTING
RESULT LIMIT UNITS
ND 0.21 ug/L
ND 1.0 ug/L
ND 0.21 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
84 (30 -121)
89 (11 -119)
·s2 (39 -115)
78 (37 -115)
Bl (41 -115)
83 (40 -115)
THE RE'I'EC GROUP INC
Client Sample ID: SV-305
Trace Level Organic Compounds
Lot-Sample# ... : .C2Gll0123-003
Date Sampled ... : 07/10/02
Prep Date ...... : 07/18/02
Prep Batch# ... : 2200473
Dilution Factor: 1
PARAMETER
2,3,7,8-TCDD
INTERNAL STANDARDS
13C-2,3,7,8-TCDD
Work Order # ... : E4HDK1AC
Date Received .. : 07/11/02
Analysis Date .. : 07/21/02
DETECTION
RESULT LIMIT
ND 2.4
PERCENT RECOVERY
RECOVERY LIMITS
66 (40 -135)
•
.Matrix ......... : WATER
MS Run# ....... :
UNITS METHOD
pg/L SW846 8290
•
•
METIIOD BLANK REPORT • GC/MS Semivolatiles
Client.Lot# ... , C2Gll0123 Work Order# ... , E4LFQ1AA
MB Lot-Sample#, C2Gl20000-291
Analysis Date .. , 07/17/02
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitro;t>enzene-ds
_Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-dS
.2,4,6-Tribromophenol
NOTE (S),
Prep Date ...... , 07 /12/02
Prep Batch# ... , 2193291
REPORTING
RESULT LIMIT
ND 0.20
ND l.O
ND 0.20
PERCENT RECOVERY
RECOVERY LIMITS
66 (30 -121)
74 (11 -119)
72 (39 -115)
63 (37 -115)
64 (41 -115)
61 (40 -115)
Calculations are performed before rounding to avoid round~off errors in calculated r~ults . •
•
Matrix ... · ...... , WATER
UNITS METHOD
ug/L SW846 8270C SIM
ug/L SW846 .8270C SIM
ug/L SW846 8270C SIM
------------------------------------------------------,-
Client Lot# ... : C2G110123
MB Lot-Sample#: G2G190000-473
Analysis Date .. : 07/20/02
Dilution Factor: 1
PARAMETER
2,3,7,8-TCDD
INTERNAL STANDARDS
13C-2,3,7,8-TCDD
NOTE(S):
METHOD BLANK REPORT
Trace ~evel Organic Compounds
Work Order# ... : E42XH1AA
Prep Date ...... : 07/18/02
Prep Batch# ... : 2200473
DETECTION
RESULT LIMIT UNITS
ND 3.4 pg/L
PERCENT RECOVERY
RECOVERY LIMITS·
50 (40 -135)
Calculations are performed before rounding to avoid round-off errors in calculated results.
• Matrix;: ....... : WATER
METHOD
SW846 8290
•
•
LABORATORY CONTROL SAMPLE EVALUATION REPORT • .GC/MS Semivolatiles
Client Lot# ... : C2Gll0123 Work Order# ... : E4LFQ1AC~LCS
E4LFQ1AD-LCSD
Analysis Date .. : 07/17/02
Matrix ......... : WATER
LCS Lot-Sample#: C2Gl20000-291
Prep Date ...... : 07 /12/02
Prep Batch# ... : 2193291
Dilution Factor: 1
PERCENT RECOVERY RPD
PARAMETER RECOVERY LIMITS RPD LIMITS METHOD
Phenol 72 (10 -131) SW846 ·s270C SIM
71 (10 -131) l. 9 (0-43) SWB46 8270C SIM
Pentachlorophenol 11 (10 -140) SW846 8270C SIM
12 (10 -140) 4.7 (0-56) SW846 8270C SIM
2,4-Dichlorophenol 77 (42 -115) SW846 B270C SIM
76 (42 -115) 1.4 (0-44) SW846 8270C SIM
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Nitrobenzene-dS 74 (30 -121)
73 (30 -121)
Terphenyl-dl4 72 (ll -119)
69 (11 -119)
2-Fluorobiphenyl 76 (39 -115)
73 (39 -115)
• 2 -Fl uorophenol 66 (37 -115)
66 (37 -115)
Phenol-dS 68 (41 115)
67 (41. -115)
2,4,6-Tribromophenol 80 (40 115)
76 (40 -115)
NOTE(Sf:
Calculations are performed before rounding to avoid round-off errors in calculated results .
•
------------------------------------------------------
LABORATORY CONTROL SAMPLE EVALUATION REPORT
Trace ·Level Organic Conipounds
Client Lot# ... : C2Gll0123 Work Order # ... : E4 2XH1AC .. Matrix ......... : WATER
LCS Lot-Sample#: G2Gl90000-473
Prep Date .. ; ... : 07/18/02 Analysis Date .. : 07/20/02
Prep Batch# ... : 2200473
Dilution Factor: l
PARAMETER
2,3,7,8-TCDD
INTERNAL STANDARD
13C-2, 3, 7, 8-TCDD
NOTE (S) :
PERCENT RECOVERY
RECOVERY LIMITS
l.l.5 (75 -l.26)
PERCENT
RECOVERY
58
Calculations are performed before rounding to avoid round-off errors in calculated resultS.
Bold Print denotes comrol parameters
METHOD
SW846 8290
RECOVERY
LIMITS
(40 -135)
•
•
•
•
•
•
ANALYTICAL REPORT
Raleigh, Biweekly NPDES
Lot #, C2G2701-42
Rita Bauer
The RETEC Group Inc
SEVERN TRENT LABORATORIES, INC.
Project Manager
August 8, 2002
STL Pittsburgh is a part of Severn Trent Laboratories, Inc.
$TL Pittsburgh
450 William Pitt Way
Pittsburgh, PA 15238-1330
Tel: [phone]
Fax: [phone]
www.stl-inc.com
-------------------------------------------
Sample Receiving:
CASE NARRATIVE
THE RETEC GROUP
Raleigh, Biweekly NPDES
STL Lot# C2G270142
STL Pittsburgh, PA received one sample on July 27, 2002 in good condition. The cooler
was within the proper temperature range.
GC/MS Semivolatiles SIM:
The reporting limits were adjusted according to the amount of sample extracted.
•
•
•
5-r L-r-tt~ la--41-.
Chain-of Custody Record & Analytical Request
Client: -~-----------
Address: ~OJ1~,'¼r-------~~t, ___ _
Project ID: ~~~~~~\,,i
A cl cl ress :G,,...(,orr\ ffi fl: I Ol 1 'Q
Quote#:
Contact: a,,,_J., Turnaround: __ s~tC~-----
Phone/171 / 3'7 ( , 1 '-f). ). Job Number: _______ _
Fax: _______ P.O. Number:
s,ri,,,,; m"i, ll~\l •.:·!_!_;.,_;.' .. •1.m_.;·•·:,:.:.:_.~_;_:.:_.··. ·u_··;,,.(:_.::,'.:_l .•. r._·:.•:~.'._;.i~.• .. _: ..
- -✓• >·,::/. --~/L , . -·:
Ix -'
.Relinquished By , Temperature
COC# 30362
Page ) of __l_
Report To: __________ _
Invoice To:
Comments:
Please specify any special reporting
. . ·• reQuirements
State Certification Requested
, NC __ SC ___ Other __ _
SEE REVERSE FOR
TERMS AND CONDITIONS
---------------------------------------------------
METHODSSUMMARY
C2G270142
ANALYTICAL PREPARATION
PARAMETER METHOD ~M=E~T~H~O~Dc.._ ___ _
8270C (SIM) SW846 8270C SIM SW846 3520C
References:
SW846 11 Test Methods for Evaluating Solid Waste, Physical/Chemical
Methods 11 , Third Edition, November 1986 and its updates.
•
•
•
•
•
•
SAMPLE SUMMARY
C2G270l42
~ SAMPLE# CLIENT SAMPLE ID
ESGJN OOl SYS EFF/SV-305
NOTE(S)
-The analytical results of the samples listed above are presented on the following pages.
-A!l calculations arc performed before rounding to avoid round--off errors in calcu!ated results.
• Results noted as "ND" were not detected at or above the stated limit.
• This repon must not be reproduced, except in full, without the written approval oflhe laboratory.
-Rcsul!s for the following parameters are never reported on a dry weight basis": color, corrosivity, density, flashpoint, ignitabi!ity, layers, odor,
paint filter test, pH, porosity pressure, reactivity, redox potential, specific gravity, spot tests, solids, solubility, 1cmpcra1ure, viscosity, and weight.
SAMPLED
DATE
SAMP
TIME
07/26/02 ll,50
TIIE RETEC GROUP INC
Client Sample ID: SYS EFF/SV-305
GC/MS Semivolatiles
' '
Lot-Sample# ... : C2G270142-001 Work Order# ... : ESGJNlAA
Date Received .. : 07/27/02
Analysis Date .. : 08/07/02
Matrix ......... : WATER
Date Sampled ... : 07/26/02
Prep Date ...... : 08/02/02
Prep Batch# ... : 2217126
Dilution Factor: 1.01
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-ds
Terp;~enyl-dl4
2 -Fl·~orobiphenyl
2-Fluorophenol
Phenol-dS
2,4,6-Tribromophenol
MS Run# ....... :
Method ......... : SW846 8270C SIM
REPORTING
RESULT LIMIT UNITS
ND 0.20 ug/L
ND 1.0 ug/L
ND 0.20 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
74 (30 -121)
65 (ll -119)
68 (39 -115)
64 (37 -115)
62 (41 -115)
69 (40 -115)
•
•
•
•
Client Lot# ... : C2G270142
MB Lot-Sample#: C2H050000-126
Analysis Date .. : 08/07/02
Dilution Factor: l
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-dS
Terphenyl-d14
2-Fluorobiphenyl
2-Fluorophenol
Phenol-dS
2,4,6-Tribromophenol
METHOD BLANK REPORT
GC/MS Semivolatiles
Work Order# ... : ESWVRlAA
Prep Date ...... : 08/02/02
Prep Batch# ... : 2217126
REPORTING
RESULT LIMIT UNITS
ND 0.20 ug/L
ND 1.0 ug/L
ND 0.20 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
67 (30 -121)
57 (11 -119)
60 (39 -115)
59 (37 -115)
57 (41 -115)
62 (40 -115)
•
NOTE(S):
Calculations are performed before rounding to avoid round-off errors in calculated results .
•
Matrix ......... : WATER
METHOD
SW846 8270C SIM
SW846 8270C SIM
SW846 8270C SIM
LABORATORY CONTROL SAMPLE EVALUATION REPORT
GC/MS Semivolatiles
Clien.t Lot# ... : C2G270142 Work Order# ... : E5WVR1AC-LCS
E5WVR1AD-LCSD
Analysis Date .. : 08/07/02
Matrix ......... : WATER
LCS lot-Sample#: C2H050000-126
Prep Date ...... : 08/02/02
Prep Batch# ... : 2217126
Dilution Factor: 1
PARAMETER
Phenol
Pentachlorophenol
2,4-Dichlorophenol
PERCENT
RECOVERY
64
63
63
60
70
RECOVERY
LIMITS
(10 -131)
(10 -131)
(10 -140)
(10 -140)
(42 -ll5)
69 (42 -ll5)
SUREOGATE
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
NOTE (S) :
Calculations are perfomted before rounding 10 avoid round-off errors in caiculated results.
PERCENT
RECOVERY
72
71
57
55
66
63
60
60
52
51
70
72
RPD
RPD LIMITS METHOD
SW846 8270C SIM
1.0 (0-43) SW846 8270C SIM
SW846 8270C SIM
3.9 (0-56) SW846 8270C SIM
SW846 8270C SIM
1. 9 (0-44) SW846 8270C SIM
RECOVERY
LIMITS
(30 -121)
( 3 0 -121)
(11 -119)
(ll -119)
( 39 -115)
(39 · -ll5)
(3 7 -115)
(37 -ll5)
(41 -ll5)
(41 -115)
(40 -ll5)
(40 -115)
•
•
•
Effluent Toxicity Report Form -Chronic Pass/Fail and Acute LCS0 Date: 07/22/02
Facility: BEAZER NPDES#: NC
aboratory Performing Test: TRITEST, INC.
X
Work Oder: 0207-00374
in Responsi
y Supervisor
MAIL ORIGINAL TO:
North Carolina Ceriodaphnia
Chronic Pass/Fail Reproduction Toxicity Test
CONTROL ORGANISMS 1 2 3 4 5 6 7 8 9 10 11
Pipe#: County: WAKE
Comments:
Environmental Sciences Branch
Div. of Water Quality
N.C. DENR
1621 Mail Service Center
Raleigh, North Carolina 27699-1621
Chronic Test Results
Calculated t = Tabular t = 12 % Reduction = 57.58
% Mortality Avg.Reprod. # Young Produced 37 28 34 -31 30 35 31 33 33 28 33 36
0.00 32.42
Control Control Adult (L)ive (D)ead L L L L L L L L L L L L
50.00 13.75
Treatment 2 Treatment 2 Effluent %: 90%
TREATMENT 2 ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 12 Control CV
8.966% PASS FAIL
# Young Produced 6 22 28 5 11 6 23 4 9 17 24 10 % control orgs □~ producing 3rd
Adult (L)ive (D)ead brood Check One D L L D D
1st sample· 1st sample
pH
Control
Treatment·· 2 ~ ~
s s
t e t e a n a n r d r d
t t
D L D D
2nd sample
~
s
t e
a n
r d
t
L L L 100%
Complete This For Either Test
Test Start Date: 07/10/02
Collection (Start) Date
Sample 1: 07/09/02 Sample 2: 07/11/02
Sample Type/Duration
Grab Comp. Duration
Sample 1 X 24 hrs l---+---+-----1
Sample 2 X 24 hrs
D
I
L u
T
1st
s
A
M p
2nd
P/F
s
A
M
p 1st sample
D.O. 1st sample 2nd sample L..__.L_ _ __j_ ___ ,L--~--r----J
Hardness(mg/1) 48 ......... . Control ~ [H]ffi ~ 1----1-----1----1
Spec. Cond. ( µmhos) -214. 866 888 T:!:'eatment 2 l---+----1----1
Chlorine(mg/1) <0.1
LC50/Acute Toxicity Test Sample temp. at receipt(°C) 1.0
(Mortality expressed as%, combining replicates)
~
% 1----,-:......+-% 1---+-% 1---f-% I -+-% I --+-% I -+--%% I %-+--I %%1--%% I· Concentration
% i . % % % % % % I Mortality
· • · · · start/end
Note: Please
Complete This
Section Also
start/end r-----------r---------------LC50
95%
______ %
'confidence Limits
% - -%
Method of Determination
Moving Average Probit
Spearman Karber Other I I I c~;~;ol I I I
pH D.O.
Organism Tested: Ceriodaphnia dubia Duration(hrs):
Copied from DWQ form AT-1 (3/87) rev. 11/95 (DUBIA ver. 4.41)
<0.1
2.0
TWTEST, INC.
·Bioassay Chain ·of Custody F~rm
Bioa"ssays . are to be sampled g,fter 8:30a.m. on •
Pb.onei/(918'. )'3]/-1':f::i.~ •
. Contact : ~ --1:-p,,_ ~-·' Collllty :. __ L-v=-='-·.,_[J;,.,_~.,_<.=-~=~"'----Outfall/ Pipe# : Oo NP~ESP=:mitti: · ~:,,,,,_ l--rifrc
-T~st Method : . CJ'-,, ,,M.' i c:.' Tox
%Effinent. Dilution : --1--..;.·· ____ _
· Sample Site Description: _.......,$'-")'._S...__E:=-·-F_~_..,..... ___________ · _· · .·
-~-~ \\,._\\ Sample Collector: _Print> ~ ~ ""Tfl
Signature> ( . .--. ~_J.j
Sample Type: Composite : \
DD: :~d•d ,' .· ~-f_ \qo) ~ TUile :~or PM -= -:J.!. t <2= T~~: ()fl° b -~r PM Samples per H:oUI: ____ __,_ _____ # E!o~: ;;;J .c{, · ·
Grab:_
Date: ______ -=====-----Trrn:, -----'-AM or P.M 9_ 11 '( : . {_ -...;, Sampi_e Volume: --~;..<1-...c-"--'c.='--~-'-""'-=~C----~ Chilled during Collection? I
M:thod ofT,..,;sp~on to Lab: If~ Ui-v~ . ·.
+' • 1 ~ • "+ •··• • • • + ♦ + • + • • + <f • • • • • · · Che.in ofCµstodylt.ci""-ase
Rec:elvedB ..
O"-' For Laboratory Use Only
· Rcctlvin.g Temp:.riaf..m:: _· __,_/_: [)=--------By: Clf/2.tnr,, ~
Residuti Cn!o:inc: · ~ Number of Bottles: __,d'-----
Adci~a: 3909·B:ryl R.d.-:lWelgb., NC 27607 Phone(9!9) 834-4984 Fax (91,/) 834-649,: OZo7-·tJv ?7r/ ._,tJe:,/ (
•
•
TRITEST, INC.
Bioassay Chain·o{CustodyForm
Eioassays .are to be sa...-uoled a,r:i:er 8:3-0a.m. on "Tue-sday &. Friday.
?acilityName: ef'Aia.< /,4qc;,c;; 6d j
Ad~ss: f!.£,~
P.O.#=-------------'--:300 t.A,J:::,t? A-i.£--.Ju TT£..., .Jo2-' l CorJCc/2{.J , l'J1 0/7'(7-. I
Phone# ('17 li' ) Tl I-/$/ 2-?_ .
Contact: IC rrf{ /l,4V~ Co~ty, Wfr/qZ Outfall/ Pipe# : C>O {
%Effluent Dilution : _ __,p~------
. Sample Site D::sc:-iption: _,,j_1µ/[1L-::._.m=.~~"---------..:...------
Sample Collector: _Print> "3/£r1C" {GA~
· Signature> /4/-(~ ., ·. V '9-i5Y Sample Type: Comoosite: .
Date Started :
7
,_·1_/tk
0
_; Time : 0 ({:ft) @or PM Q]:)@0:¥nded: ---6-~~~c-~-------Tim;: · Q'?J () ·@r PM l ·•. H_ours .• ,_u·. Sa111plesp::rHour, ___________ " v?_
Grab: --.
Date: ______________ _ --Tun: : ------'-AJ\1 or P.M Sampl_e Volume: -=<~--t_,~7,~~=·~~----~Chllled during l;::olle:tion? 'yw
Method of Transportation to Lab : t/trlV'LJ /Jp.1 I/~
+· + • • • • + .. ··• + + + + • • • + + + + • • + + • +. . Ch's.in ofCjistodyRdease
Relinautshe<i,Bv,,, Dab Time. Re::eived Bv · Date /, A ' 7/ h)o'-2..I Ing, · 1:;nr,,,;;;,,, " ~·,t.,...I!__· / ";/ (/
I ..
. For Laboratory Use Only
· Re:,iving Ten\p::ratur:: __;~::__···..::r)_· _,,_c:.. ______ By; ~1)1,-u"J -4,~
Rcsidu.a1 Chlorfo:: _ _,_/{/"'-"/2q"""~-------"'umb::r ofBnttles : _?..,~"----
Addross: 3909·B:ryl R.d.-Re.loig!l, NC 27607 Phon,(919)_834 -4984 ?i,x (91!1) 834-6491 0 'U) 7 '"' 0V ? 7 cf -cJZYL.
7-/2
(
-.:'.1/l...
Turu:
I nC"r>
i
•
•
•
July 9, 2002
Ms. Beverly Hudson
Remedial Project Manager
U.S. EPA -Region IV, 11th Floor
North Site Management Branch
61 Forsyth Street, SW
Atlanta, GA 30303
RE: Monthly Progress Report #110
Remedial Action
Koppers Site -Morrisville, NC
Dear Ms. Hudson:
; p~ r~-~ __ t I -w--~
J l1
' JUL 1 5 2002
I
I_----
The RETEC Group, Inc.
300 Baker Avenue, Suite 302
Concord, MA01742
(978) 371,1422 Phone
[phone] Fax
www.retec.com
In accordance with the Unilateral Order, and on behalf of Beazer East, Inc. (Beazer), please find attached
four (4) copies of the June Monthly Progress Report for Remedial Action at the Koppers Superfund Site
in Morrisville, NC. No exceedances occurred during this event. In addition, the results for the Chronic
Toxicity sample collected in June passed and a second Chronic Toxicity test will be completed in July.
Should you need additional information regarding this progress report, please call Mike Helbling at (412)
208-885 8 or me at (978) 3 71-1422 .
Sincerely,
The RETEC Group, Inc .
. , . / ;/'-/✓ .,,,y ~_,< .. -:..,~..-0-~7
Rita Bauer
Project Geologist
CK:th
Enclosure
cc: D. Mattison -NC Superfund (2 copies)
L. Faulconer -Wake County
G. Caskey -Enwood Structures
M. Helbling -Beazer
F: \PR OJ E CTS \0 3 624 \ Repo rts\M on th I y\6M-02. doc
D. Hails -Ecological Restoration, Inc.
J. Garrett-NC Division of Water Quality
D. Matthews -NC Div. of Waste Management
P. Kilchenstein -RETEC
•
•
•
MONTHLY PROGRESS REPORT #110
REMEDIAL ACTION
SITE NAME: Koppers Superfund Site
Beazer East, Inc.
Morrisville, NC
USEPA DOCKET NUMBERS: 93-09-C
PERIOD ENDING: June 30, 2002
I. PROGRESS MADE THIS MONTH
2.
3.
4.
5.
6.
Remedial Action (RA) -HABI_TAT MITIGATION. No activities were conducted this
month.
Remedial Action (RA) -GROUNDWATER TREATMENT. The treatment system
operated throughout the month without upset. System performance was monitored on a
biweekly basis. Approximately 20,420 gallons of groundwater were extracted, treated in
the treatment plant and discharged between June I, 2002 and June 30, 2002. System
water samples were collected on June 12, 2002 and June 24, 2002 in accordance with the
sampling schedule in the O&M manual. Samples were submitted to Severn Trent for
laboratory analysis. The operations and sampling programs are summarized on the
attached Table I.
Remedial Action (RA) -EFFECTIVENESS MONITORING PROGRAM. No activities
were conducted this month.
Remedial Action (RA) -CORRESPONDENCE. None.
PROBLEMS RESOLVED
PROBLEMS ANTICIPATED
UPCOMING EVENTS
PERSONNEL CHANGES
SUBCONTRACTORS
None.
None.
Continue System O&M.
None.
None.
7. ANALYTICAL DATA Analytical data from system influent and effluent sampling
received during this period are enclosed and are summarized on Table 2 .
F :\PR OJ E CTS \03 6 2 4 \Repo ns\r--.fonth I y\6M ·02. doc
• •
Table 1
Groundwater Treatment Operations and Sampling Program Summary
Koppers Superfund Site
Morrisville, North Carolina
June 2002
Date Systems Cummulative SV-101 SV-101 Associated SV-304 SV-304 Associated SV-305 Check Effluent Flow Sample Sample (ves/no\ lGal!ons\ (veslno\ Parameters
01/10/02 ves 3 251 280 no
01/23/02 ves 3,264,850 ves Penta. 2 4-Dichloro Phenol. Dioxin 02/07/02 ves 3 283 240 no
02/19/02 ves 3 300 140 no
03/06/02 ves 3 318 630 no
03/21/02 ves 3,338 440 no
04/02/02 ves 3 356 200 ves Penta 2 4-Dichloro Phenol Dioxin 04/17/02 ves 3 378 150 no
05/01/02 yes 3 397.920 no
05/13/02 ves 3 414 970 no
6/12/2002 ves 3 455 530 no
6124/2002 ves 3467110 no
Notes:
Sampling point SV-101 is located before the Carbon Units (pretreatment)
Sampling point SV-304 is located between the Carbon Units
Group Sample Sample Group (ves/nol Parameters
no
1 2 ves Penta 2 4-Dichloro Phenol 1
no
no
no
no
1 ves Penta 2 4-Dichloro Phenol 1
no
no
no
no
no
Associated Groups:
SV-101 -Group 1 is penta and 2,4-dichlorophenol; Group 2 is dioxin SV-304 -Group 1 is penta and 2.4-dichlorophenol
Sample
fves/no'
ves
ves
ves
ves
ves
ves
ves
ves
ves
ves
ves
ves
•
SV-305
Sample
Parameters
Penta 2 4-Dichloro Phenol
Penta, 2,4-0ichloro, Phenol, Dioxin, Chronic
Tox
Penta 2 4-Dichloro. Phenol
Penta 2 4-Dichloro Phenol
Penta 2 4-Dichloro, Phenol
Penta 2,4-Dichloro Phenol
Penta, 2.4-Dichloro, Phenol, Dioxin, Chronic
Tox
Penta 2 4-Dichloro Phenol
Penta 2,4-Dichloro, Phenol. Chronic Tax
Penta. 2 4-Dichloro. Phenol
Penta 2.4-Dichloro Phenol Chronic Tax
Penta 2 4-Dich!oro Phenol
Sampling point SV-305 is lactated after the Carbons Units (post-treatment) SV-305 -Group 1 is penta, phenol, and 2,4-dichlorophenol; Group 2 is dioxin and Group 3 is chronic toxicity
NR -Not recorded
F.\Projecis\OJ6241Reports\Monlhly\6M-02 Table 1.Jrlll
Associated
Group
1
1,2 3
1
1
1
1
1 2 3
1
1,3
1
1 3
1
•
•
•
Table 2
Groundwater Treatment Analytical Data Summary
Koppers Superfund Site -Morrisville, North Carolina
June 2002
Analytical
Parameter Date Sample Sample
Sample Location Location
Collected SV-101 SV-304*
Pentachlorophenol 01/10/02
01/23/02 6.2 <1.0
02/07/02
02/19/02
03/06/02
03/21/02
04/02/02 24 <1.0
04/17/02
05/01/02
05/13/02
06/12/02
06/24/02
2.4-Dichlorophenol 01/10/02
01/23/02 <0.20 <0.20
02/07/02
02/19/02
03/06/02
03/21/02
04/02/02 <0.20 <0.20
04/17/02
05/01/02
05/13/02
06/12/02
06/24/02
Phenol 01/10/02
01/23/02 <0.20 <0.20
02/07/02
02/19/02
03/06/02
03/21/02
04/02/02 <0.20 <0.20
04/17/02
05/01/02
05/13/02
06/12/02
06/24/02
Chronic Toxicity 01/23/02
04/02/02
05/01/02
06/12/02
Dioxin (2,3,7,8-TCDD) 01/23/02 <2.6
04/02/02
Notes: All results are in micrograms per Iller {g/L) except dioxin. Dioxin data is in picograms per liter (pg/L).
SV-101 -Before Carbon Units
•sV-304 -Between Carbon Units
*"SV-305 -After Carbon Units
F:\Projects\03624\Reports\Monthly\SM-02 Table 2.xls
Sample
Location
SV-305**
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<0.96
<1.0
<0.98
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.19
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.19
<0.20
<0.20
Pass
Fail
Fail
Pass
<1.5
<0.63
•
•
•
ANALYTICAL REPORT
Raleigh, Biweekly NPDES
Lot#: C2FI3036I
Rita Bauer
The RETEC Group Inc
SEVERN TR.ENT LABORATORIES, INC.
Veronica Bortot
Project Manager
June 19, 2002
STL Pittsburgh is a part of Severn li-ent Laboratories, Inc,
STL Pittsburgh
450 William Pitt Way
Pittsburgh, PA 15238+1330
Tel: [phone]
Fax: [phone]
WW\"1.stl-inc.com
____________________________ ,_
Sample Receiving:
CASE NARRATIVE
THE RETEC GROUP
Raleigh, Biweekly NPDES
SIL Lot# C2Fl303GI
STL Pittsburgh, PA received one sample on June 13, 2002 in good condition.
was within the proper temperature range.
GC/MS Semivolatiles SIM:
There were no problems associated with the analysis.
The cooler
Since insufficient sample volume was received to perfom1 a matrix spike and matrix
spike duplicate, a Laboratory Control Sample (LCS) and Laboratory Control Duplicate (LCD) were performed. All recoveries were within QC limits.
•
•
•
•
•
•
METHODS SUMMARY
C2Fl3036l.
ANALYTICAL PREPARATION
·~P~ARAM==E~T~E~R.,_ _____________________ METHOD ~M=E~T~H~O~Dc_ ___ _
8270C (SIM) SW846 8270C SIM SW846 3520C
References:
SW846 11 Test Methods for Evaluating Solid Waste, Physical/Chemical
Methods 11 , Third Edition, November 1986 and its updates .
______________________________________ ,_
SAMPLE SUMMARY
C2Fl30361
~ SAMPLE# CLIENT SAMPLE ID
E22F0 001 SYS EFF
NOTE (S):
-TI1c analytical results of the samples listed above arc presented on the following pages.
-All calculations arc performed before rounding to avoid round-off errors in calculated results.
• Results noted as "ND" were not detected at or above the stated limit.
-This rcpon must not be reproduced, except in full, without the written approval of the laboratory.
-Results for the following parameters arc never reported on a dry weight basis: color, cor~osivity, density, nashpoim, ignitabiliry, layers, odor,
paint filter test, pH, porosity pressure, reactivity, re.dox potential, specific gravity, spot tests, solids, solubilily, temperature, vi5:eosity, and weight.
SAMPLED
DATE
• SAMl
TIMl
06/12 /02 09: (
•
•
. -~ Chain of · • • Custody Record /'.1;:';:SERVICES_, 7-';,,c ..... ' ,..___.,..._ ~ Severn Trent Laboratories, Inc.
STL-4124 (1200) Cl,Drrn ProjeQ:J+~ '5~,...--Date ,;,J;;z Cha;n of rsodtr l( 5 . '" ' G
Address A.v<-Telephone Number (Area Code)/Fax Number Lab 'Number I l '(()n R,.,k.,r ST.e., 3oJ. C/71-J7/-/ r./2.L Page of
r: rJ I m'A I 20c1~ '{ J
Site Contact Lab Contact Analysis (Attach list if
.r, .... J:,., more s ace is needed
\~=~~q;alk~ ~ CarrierNVaybi/1 Number ~ t ~ Special Instructions/
Contract/Purchase ( rder/Quote No. ' Containers & "' i Conditions of Re_ceipt
Matrix Preservatives -R "'
Sample I.D. No. and Description . 2, "' ~ ~~ Date Time 1 u ~ [ "' 0 i) 0 ~o (Containers for each sample may be combined on one line) ' " C N I ~ ~~ 8a < < "' ~ ~ ~
s ';'\ Cf:-F c;,/1;;,.,/.l c,q S-o X f'. "-.
Possible Hazard Identification I Sample Disposal (A fee may be assessed if samples are retained
D Non-Hazard D Flammable D Skin lm·tant D Poison B ~nknown D Return To Client l[oisposal By Lab D Archive For Months longer than 3 months)
~· Tum Around 1 ,me Reqwred
D 24 Hours D 48 Hours 5W QC Requirements (Specify)
D 14 Days D 21 Days
t. Relinquishe Time Date Time
:),:l. OD
2. Relinquished By Time Time
3. Relinquished By Time Time
Comments
DISTRIBUTION: WHITE -Stays With the Sample; CANARY-Rerurned (0 Client w,rh R:port: PINK.-Field Copy
____________________________ ,_
Lot-Sample# ... : C2Fl30361-001
Date Sampled ... : 06/12/02
Prep Date ...... : 06/14/02
Prep Batch# ... : 2165318
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-dS
Terphenyl-dl4.
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5 ·
2,4,6-Tribromophenol
THE RETEC GROUP INC
Client Sample ID: SYS EFF
GC/MS Semivolatiles
Work Order# ... : E22F01AA
Date Received .. : 06/13/02
Analysis Date .. : 06/19/02
Matrix ......... : WATER
MS Run# ....... :
Method ......... : SW846 8270C SIM
REPORTING
RESULT LIMIT UNITS
ND 0.20 ug/L
ND 1.0 ug/L
ND 0.20 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
51 (32 -112)
61 (10 -144)
65 (30 -110)
59 (13 -110)
65 (10 -113)
50 (21 -122)
•
•
•
•
Client Lot# ... : C2Fl30361
MB Lot-Sample#: C2Fl40000-318
Analysis Date .. : 06/19/02
Dilution Factor: 1
PARAMETER
Pentachlorophenol
Phenol
2,4-Dichlorophenol
SURROGATE
Nitrobenzene-ds
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-dS
2,4,6-Tribromophenol
OTE(S):-
METHOD BLANK REPORT
GC/MS Semivolatiles
Work Order# ... : E22951AA
Prep Date ...... : 06/14/02
Prep Batch# ... : 2165318
REPORTING
RESULT LIMIT UNITS
ND 1.0 ug/L
ND 0.20 ug/L
ND 0.20 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
32 ( 32 -112)
39 (10 -144)
41 (30 -110)
36 (13 -110)
37 (10 -1"13)
36 (21 -122)
Calcul:nions arc pcrfonncd Defore rounding to avoid round-off errors in calculated results .
•
Matrix ..... : ... : WATER
METHOD
SW846 8270C SIM
SW846 8270C SIM
SW846 8270C SIM
_____________________________________________________ ,_
LABORATORY CONTROL SAMPLE EVALUATION REPORT
GC/MS Semivolatiles
Client Lot# ... : C2Fl30361 Work Order# ... : E22951AC-LCS
E22951AD-LCSD
Analysis Date .. : 06/19/02
Matrix ......... : WATER
LCS Lot-Sample#: C2Fl40000-318
Prep Date.; .... : 06/14/02
Prep Batch# ... : 2165318
Dilution Factor: l
PARAMETER
Phenol
Pentachlorophenol
2,4-Dichlorophenol
SURROGATE
Nitrobenzene-ds
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
NOTE (S) :
PERCENT
RECOVERY
63
64
68
60
67
67
RECOVERY
LIMITS
(10 -131)
(10 -131)
(10 -140)
(10 -140)
(42 -115)
(42 -115)
PERCENT
RECOVERY
53
54
61
63
66
68
61
61
67
65
60
60
Calculations arc performed before rounding to avoid round-off errors in calculated results.
RPD
RPD LIMITS METHOD
SW846 8270C SIM
1.1 (0-43) SW846 8270C SIM
SW846 8270C SIM
13 I o-56) SW846 8270C SIM
SW846 8270C SIM
0.59 (0-44) SW846 8270C SIM
RECOVERY
LIMITS
(32 -112)
(32 -112)
(10 -144)
(10 -144)
(30 -110)
(30 -110)
(13 -110)
(13 -110)
(10 -113)
(10 -113)
(21 -122)
(21 -122)
•
•
•
•
•
•
ANALYTICAL REPORT
Raleigh, Biweekly NPDES
Lot#: C2F250255
Rita Bauer
The RETEC Group Inc
SEVERN TRENT LABORATORIES, INC.
~nut~ Veronica Bortot
Project Manager
July l., 2002
STL Pittsburgh Is a part of Severn Trent LaboratorieS, Inc.
STL Pittsburgh
450 William Pitt Way
Pittsburgh, PA 15238-1330
·Tel: [phone]
Fax: [phone]
w1.vw.stt-inc.com
---------------------------------------
Sample Receiving:
CASE NARRATIVE
THE RETEC GROUP
Raleigh, Biweekly NPDES
STL Lot# C2F250255
STL Pittsburgh, PA received-one sample on June 25, 2002 in good condition. was within the proper temperature range.
GC/lvIS Semivolatiles SIM:
The cooler .
The repo1ting limits were adjusted according to the amount of sample extracted.
•
•
•
•
•
•
METHODS SUMMARY
C2F250255
ANALYTICAL PREPARATION
~P~ARAME==-=~T~E~R'---------------------METHOD ~M~E~T~H~O~D ____ _
8270C (SIM) SW846 8270C SIM SW846 3520C
References:
SW846 11Test Methods for Evaluating Solid Waste, Physical/Chemical
Methods 11 , Third Edition, November 1986 a_nd its updates .
------------------------------
SAMPLE SUMMARY
C2F250255
~ SAMPLE# CLIENT SAMPLE ID
E3NFK 001 SYSEFF/SV-305
NOTE(S)
• The: analytical re:sulis of the samples listed above are presented on the following pages.
-All calculations are performed before routld~g· to avoid round-off ~rrors in cilculaled results.
• Results noted as "ND" were not detected at or above the stated limit.
• ~is repoM must not be reproduced, e~cept in fu]l, wilhout the wrincn approval of the !abontory.
· Results for the following parameters are never reported on a dry weight basis: color, corrosivir:y, density, flashpoint, ignitabi!ity, layers, odor,
paint filter test, pH, porosity pressure, reacdvity, redox potential, specific gnvity, spot tests, &elids;solubiliry, temperaniie, viscosity, and weight.
• SAMPLED SAMP
DATE TI!§_
06/24/02 OB :2C
•
•
• Chain of
Custody Record
STL-412<1 (1200)
Client{)~ ---o-o;
Address
Joo K~ Av., r-;-(._ 1o-:i.
c~t-6,J. l~'~lz;"~; <{~ ~~=~::rrtt:leh ~ ~I~
Contract/Purchase Ord,r/Quote No. I
Sample 1.0. No. and Description Date (Containers fOI each sample may be combined on one line)
5:Y&.£F(C' f ~V-'!o'r ~ l.,NIJ_
' '
Possible Hazard Identification
0 Non-Hazard 0 Flammabie D Skin f,rita~I 0 Poison 8
•
Project Manager
Telephone Number (Area Code)IFaX Number
Site Contact Lab Contact
Carrier/Waybill Number
i-Containers & -Matrix ·Preservatives "' .
l t 0 ~ < ~a ~l Time b • ~ 0 G 0 o!' ~ • ~ 5 N ~ ~ 0.
~ < < N~
(}gJo '(. 1 'I--
'
I Sample Disposal ·
~nknown O Return· To Client efo;sposal By Lab 0 An:hive For
Tum Around Time Required
0 24 Hours O 4B Hours
QC Requirements (Speoty)
0 7 Days D 14 Days D 21 Days f:rQ
1. Relinquished~ JD Time
CL nao 1. Rec~ived By
2. Relinquished By ,,me
3. Relinquished By Time
Comments
DISTRIBUTION: WHI l'E -Stays with the Sample; CANARY -Returned to Cli~nt with Report; ~INK -Field Copy
•
Severn Trent Laboratories, Inc.
Date Chain of Custody Number 103674
Lab Number
Page of
Analysis (Attach list if
more s ace is neededl
Special Instructions/
Conditions of Receipt
.
(A fee may be assessed if samples are retained
Months longer than J months}
Time
Time
f,1/J u
Time
THE RETEC GROUP INC
Client Sample ID: SYSEFF/SV-305
GC/MS Semivolatiles
Lot-Sample# ... : C2F250255-001
Date Sampled.·.·: 06/24/02
Prep Date ... _ ... : 06/27/02
Prep Batch# ... : 2179133
Work Order #._ .. : E3NFK1AA
Date Received .. : 06/25/02
Analysis Date.·.: 06/29/02
Matrix ... _ ..... : . WATER
MS Run# .•....• :
Dilution Factor: 0.98 Method ...... _. .. : SW846 8270C SIM
PARAMETER·
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-ds
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4 1 6-Tribromophenol
RESULT
ND
ND
ND
PERCENT
RECOVERY
48
57
60
56
60
52
REPORTING
LIMIT UNITS·
0 .20 ug/L
0.98 ug/L
0.20 ug/L
RECOVERY
LIMITS
(30 " 121)
(11 -119)
(39 -115)
(37 -.115).
(41. -115)
(4 0 -115)
•
•
•
•
Client Lat # c '..: C2F250255
MB Lot-Sample#: C2F280000-133
Analysis Date .. : 06/29/02
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2 , 4 , 6 ~ Tribromophenol·
NOTE(S):
METHOD BLANK REPORT
GC/MS Semivolatiles
Work Order.# ... : E3W4RlAA
Prep Date ...... : 06/27/02
Prep Batch.# ... : 2179133
REPORTING
RESULT LIMIT UNITS
ND 0.20 ug/L
ND 1.0 ug/L
ND 0.20 . ug/L
PERCENT RECOVERY
RECOVERY LIMITS
48 (30 -121)
53 (11 -119)
57 (39 -115)
56 (37 -115)
57 (41 -115)
49 (40. -115)
• Calculations are perfonncd before rounding to avoid round-off errors in c.alculatcd results .
•
Matrix ......... : WATER
METHOD
SW846 827DC SIM
SW846 8270C SIM
SW846 8270C SIM
Ll\BORA'IURY CONTROL SAMPLE EVALUATION.REPORT
GC/MS Semivolatiles
Client Lot# ... , C2F250255 work order# •.. , E3W4R1AC-LCS
E3W4R1AD-LCSD
06/29/02
Matrix ..... · .... : WATER
LCS Lot-Sample#, C2F280000-133
Prep Date ...... : 06/27/02 Analysis Date .. ,
Prep Batch# ... , 2179133
Dilution Factor: 1
PARAMETER
Phenol
Pentachlorophenol
2,4-Dichlorophenol
SURROGATE
Nitrobenzene-ds
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol0 d5
2,4,6-Tribromophenol
NOTE(S):
PERCENT RECOVERY
RECOVERY LIMITS
46 (10 -131)
52 (10 -131)
34 (10 -140)
35 (10 -140)
51 (42 -115)
59 (42 -115)
PERCENT
RECOVERY
39
46
42
48
45
52
4.3
·51
.42
51
43
49
Dkulations arc performed before row1ding to avoid round-off errors ii-1 calculated results.
RFD
~ LIMITS METHOD
SW846 8270C SIM
14 (0-43) SW846 8270C SIM
SW846 8270C SIM
1.5 (0-56) SW846 8270C SIM
SW846 8270C SIM
16 . ( 0-44). SW846 8270C SIM
RECOVERY
LIMITS
(30 -121)
(30 -121)
(ll -119)
(ll -119)
(39 -115)
(39 -115)
(37 -115)
(37 -115)
(41 -115)
(41 -115)
(40 -115)
(40 115)
•
•
•
Effluent Toxicity Report Form -Chronic Pass/Fail and Acute LCSO Date: 06/20/02
.cility: BEAZER NPDES#:
boratory Performing Test: TRITEST, INC.
X -
X
S1/ituf::~~~~1n ~~_9harge
s113na 11.1:0<> g { t~upervisor
Work Ord r: 0206-00550 MAIL ORIGINAL TO:
NC Pipe#: County: WAKE
Comments:
* PASSED: 6.07% Reduction*
Environmental Sciences
Div. of Water Quality
N.C. DENR
Branch
1621 Mail Service Center
Raleigh, North Carolina 27699-1621
North Carolina Ceriodaphnia
Chronic Pass/Fail Reproduction
CONTROL ORGANISMS 1 2 3 4
# Young Produced 23 23 25 34
Adult (L) ive (D) ead L L L L
Effluent %: 90%
TREATMENT 2 ORGANISMS 1 2 3 4
# Young Produced 24 25 26 25
.dult (L)ive (D) ead L L L L
1st sample 1st sample
pH
Control
Treatment 2 ~ ~
s s
t e t e
a n a n
r d r d
t t
1st sample 1st sample
D.O.
Control
Treatment 2 ~ ~
551 £1111 A 3 12RM
LC50/Acute Toxicity Test
Chronic Test Results Toxicity Test
Calculated t = 1.137
Tabular t = 2.508
5 6 7 8 9 10 11 12 % Reduction= 6.07
% Mortality Avg.Reprod.
28 26 28 32 22 20 26 26
0.00 26.08
Control Control
L L L L L L L L
0.00 24.50
Treatment 2 Treatment 2
5 6 7 8 9 10 11 12 Control CV
15.462% PASS FAIL
29 25 23 20 21 27 22 27 % control orgs 0C
L L L L L
2nd sample
~
s
t e
a n
r d
t
2nd sample
[B3Bj
... 6¥¥
producing 3rd
brood Check One
L L L 92%
Complete This For Either Test
Test Start Date: 06/12/02
Collection (Start) Date
Sample l: 06/12/02 Sample 2: 06/14/02
Sample Type/Duration
Grab Comp. Duration
Sample 1 X 24 hrs
Sample 2 X 24 hrs
Hardness (mg/1)
Spec. Cond. (µmhos)
D
I
L u
T
50
1st
s
A
M
p
..........
187 852
2nd
P/F
s
A
M
p
762
Chlorine (mg/1) .......... .......... <0.1 <0.1
Sample temp. at receipt(°C) .......... .......... 1.1 1.4
(Mortality expressed as%, combining replicates) I
Note: Please
Complete This
Section Also
Organism Tested: Ceriodaphnia dubia
Concentration
Mortality
start/end
pH
Duration(hrs):
Copied from DWQ form AT-1 (3/87) rev. 11/95 (DUBIA ver. 4.41)
start/end
D.O.
..
TRITEST, INC.·
Bioassay Chain ·of Custody Form • Bioassays .are to be sampled a,fter 8:30a.m. OJi Tue-sday &:. Friday.
Facility Name: (?(£AZ#--, J&,-1,£16i/ . J Address: ]lclO ff(rlca 1:ve?". '[c.rillC._ ,JO 'L P.O.#: Ru:.~ . . , l {Or{l)/'✓.:J ,( d1t onyL
Phone#('17J' ,, JJ7/-/Y2-Z-,
Contact: k' O::f\ ,6'Av~ County: (Uf+,{V I ''? OutfaJVPipe # ,CJ_O~---NPDESPermlt#': M<WN' uzwY.-%Effluent Dilution:--~</------
. Sample Site Description: _J_·~yJ __ .~£ff:-~~·~--------------
SampleCollector: Print> Ti£-/7.= ~c/~
Signat~re> ~~ ..
Sample 1ype: Comoosite :
Date Started : --~b~l.1.~1.,_./,_0_2-~~---Tnne: o</ 3 C Date Ended: ---~6~A~M~·:,__"L-__ ·. ____ Time: · c1r::? b Samples )i;r Hour:_,__ _________ ·#Hours: :2.. l{
Grab:_
@or PJ\{
· ilfi}or PM
Date: ______________
_ Time : ~ or PM SampJ.eVolume: ;;J-l-(T7£1,Z.J . Chilled during <;:ollection? Ya:::.f
•
=-===========================
=
=
=
=
s
=
=
=
=
=
=
=
=
•
=

============================
=
=
=
=
=
=
=
=
=
=
=

+· • • ◄ • "+ .:·. + • + • ♦ ~ + + • + + + • • + • •· "Chain.ofCµstodyR.eleasc • ♦ ◄ ♦ • ♦ ♦ • ♦ • + ♦ ♦ ♦ ♦ • • • +. • • + • • •· ' . ' Date Time. · Date Time 1--. oL llJe> ·
0 Lb--C?o
For Laboratory Use Only
!·. I .,c.. . ,,, . f) · Receiving Temperature: _ _,__~_,__ _______ By: Q f.JuDu h [Pn~-=-R... ' Residulll Chlorine: _~/J.~c-Z.,=~-------Number
ofBot!les: _ _..,:J_~---
Address: 3909·Beiyl Rd.-R.alelgh, NC 27607 Phone[phone] Fax (91!1) 834-649,: o~h -tfZJs=c:cJ .-'0°1 ( •
•·
TRITEST, INC.
Bio assay Chain ·of° Custody Fo_rm
Bioassays are to be sampled a.fter B:30a.:m. on Tue·sday &. Friday.
Faci!H_yName: '.Biu-ier )R,J.i. 4 l_
Addr~ss: /6,t,:;__,
,::?c:io TI c-..¼.c A--J(L ~ TE" 1 o :l
P.O.#: _______ ..,..... ___ _
Phone#(Cf7'{) "37f-J.r,/-;J,)..
Contact : ~-,-;t., ~ ~ Coun1y: . !..A.) A-\ <E. Outfall/ Pipe# : (')I. -NP~ESPemmti: -~)_, ~ %Effluent Dilution : ___ · -'· ___ if,_ ___ _ -T~si Method : · · ClJr<rr--l G, I er,,<'
D · · · ,.-..;, .-,,.: {:-F · Sample Site esc:r1pt1on: ___ -.:.,._~-'-...::<:..:._ _____________ _
Sample Collector. _Print> --=--·~:----f .-"c'---~...--'-m'-',.· _-_\_( .....;----------
~ignatur~ > ___ J1-~==~===Et-~J/J'.~._-~-------
Sample T)'pe: Composite:
Date Started : -~'"-'-l/~'J /,__::l.~ __ Tm,e:
Date Ended: ---oc.-~-+7_1_'1.,_._/_~ ______ Time:
Samples per Hour: _____ \ ______ ·#, E;ours:
Grab:.
Time~
oaJo @orPM
08'Jo ·@or PM c)t./ .
~ AM or PM
Date: _____ ___, _____ '--_·. _______ _
Sampl.e Volume: -~=-~b=e..-~~'--t'--5----~· Chilled during Collection? __ T __
Method of Transportation to Lah: _Jt\~"--"'-J~-·~J&-=· •~v_V __________ _
i • • i • f • /"+ • ~ • • • • • • • • • • • + • • + • · Chain of C_usiody Rclease •• -••• , ••••• _ ....... + +.♦♦-♦♦♦♦• . . . Re}\oomshed By. nm, Time Receb,edB;, -. Da±e Time
t J ... ~--"H--~11 t./1'1/;;,; t:>900 (I '/Hu ff7v'1 , It/"' . .£/ . .IL i, -i'-/".,O. c1,r;,· I ' '· ... ..
oc. For Laboratory Use Only
· Receiving Temperiiture: __ /_,_$(,__ _______ By: ~ ,/k11/J £-'--..
Resid11al Chlorine: __ · ~t-!~@~9._ ______ Number of Bottles:_" -"J-___ _
Ad'dress: 3909·Boi-yl Rd.-Ra)ejgh, NC 27607 ?honc(919) 834 -4984 Fax [phone]\>
(
• June I 0, 2002
Ms. Beverly Hudson
Remedial Project Manager
U.S. EPA -Region IV, 11th Floor
North Site Management Branch
61 Forsyth Street, SW
Atlanta, GA 30303
RE: Monthly Progress Report #109
Remedial Action
Koppers Site -Morrisville, NC
Dear Ms. Hudson:
Tile RETEC Group, Inc.
300 Baker Avenue, Suite 302
Concord, MA01742
[phone] Phone
[phone] Fax
www.retec.com
In accordance with the Unilateral Order, and on behalf of Beazer East, Inc. (Beazer), please find attached
four (4) copies of the May Monthly Progress Report for Remedial Action at the Koppers Superfund Site in Morrisville, NC. Because our Chronic Toxicity sample failed, we will collect chronic toxicity samples
on a monthly basis until two consecutive monthly tests pass.
Should you need additional information regarding this progress report, please call Mike Helbling at [phone] or me at [phone].
• Sincerely,
•
~E~roup,,
\___,.<&: }11 '(7:iu.-<!_;1_
Rita Bauer ./' j'-
Projcct Geologist
CK:th
Enclosure
cc: D. Mattison -NC Superfund (2 copies)
L. Faulconer -Wake County
G. Caskey -Enwood Structures
M. Helbling -Beazer
F:\PROJECTS\03624\Rcports\tvlonthly\2002\5M-02.doc
D. Hails -Ecological Restoration, Inc.
J. Garrett -NC Division of Water Quality
D. Matthews -NC Div. of Waste Management
P. Kilchenstein -RETEC
•
•
•
MONTHLY PROGRESS REPORT #109
REMEDIAL ACTION
SITE NAME: Koppers Superfund Site
Beazer East, Inc.
Morrisville, NC
USEPA DOCKET NUMBERS: 93-09-C
PERIOD ENDING: May 31, 2002
I. PROGRESS MADE THIS MONTH
2.
3.
4.
5.
6.
Remedial Action (RA) -HABITAT MITIGATION. No activities were conducted this
month.
Remedial Action (RA) -GROUNDWATER TREATMENT. The treatment system
operated throughout the month without upset. System performance was monitored on a
biweekly basis. Approximately 55,831 gallons of groundwater were extracted, treated in
the treatment plant and discharged between May I, 2002 and May 30, 2002. System
water samples were collected on May 1, 2002 and May 13, 2002 in accordance with the
sampling schedule in the O&M manual. Samples were submitted to Severn Trent for
laboratory analysis. The operations and sampling programs are summarized on the
attached Table I.
Remedial Action (RA) -EFFECTIVENESS MONITORING PROGRAM. No activities
were conducted this month.
Remedial Action (RA) -CORRESPONDENCE. None.
PROBLEMS RESOLVED
PROBLEMS ANTICIPATED
UPCOMING EVENTS
PERSONNEL CHANGES
SUBCONTRACTORS
None.
None.
Continue System O&M.
None.
None.
7. ANALYTICAL DATA Analytical data from system influent and effluent sampling
received during this period are enclosed and are summarized on Table 2 .
r:':\PROJECTS\03624\Reports\Monchly\2002\SM-02.doc
• •
Table 1
Groundwater Treatment Operations and Sampling Program Summary
Koppers Superlund Site
Date Systems Cummulative SV-101 SV-101
Check Effluent Flow Sample Sample
(ves/no) (Gallons) (yes/no) Parameters
01/10/02 ves 3,251,280 no
01/23/02 ves 3,264,850 ves Penta, 2 4-Dichloro, Phenol, Dioxin
02107102 ves 3,283,240 no
02/19/02 ves 3,300,140 no
03/06/02 ves 3,318,630 no
03/21/02 ves 3,338,440 no
04/02/02 ves 3,356,200 ves Penta, 2 4-0ichloro, Phenol, Dioxin
04/17/02 ves 3,378,150 no
05/01/02 ves 3,397,920 ao
05/13/02 ves 3,414,970 no
Notes:
Sampling point SV-101 is located before the Carbon Units (pretreatment)
Sampling point SV-304 is located between the Carbon Units
Morrisville, North Carolina
May 2002
Associated SV-304 SV-304 Associated SV-305
Group Sample Sample Group Sample
(ves/no) Parameters (ves/no)
no ves
1, 2 ves Penta, 2 4-Dichloro, Phenol 1 ves
no ves
no ves
no ves
no ves
1 ves Penta. 2,4-Dichloro, Phenol 1 ves
no ves
no ves
no ves
Associated Groups:
SV-101 -Group 1 is penta and 2,4-dichlorophenol; Group 2 is dioxin
SV-304 -Group 1 is penta and 2,4-dichlorophenol
•
SV-305
Sample
Parameters
Penta 2,4-Dichloro Phenol
Penta, 2,4-Dichloro, Phenol, Dioxin, Chronic
Tox
Penta, 2,4-0ichloro Phenol
Penta 2,4-Dichloro Phenol
Penta 2 4-0ichloro Phenol
Penta, 2,4-Dichloro Phenol
Penta, 2,4-Dichloro, Phenol, Dioxin, Chronic
Tox
Penta, 2,4-Dichloro Phenol
Penta, 2,4-Dichloro, Phenol, Dioxin, Chronic
Tox
Penta, 2,4-Dichloro, Phenol
Sampling point SV-305 is lactated after the Carbons Units (post-treatment) SV-305 -Group 1 is penta, phenol, and 2,4-dichlorophenol; Group 2 is dioxin and Group 3 is chronic toxicity
NR -Not recorded
F,\Projecls\03624IR•ports\Moolhl)'\5M--02 Table l xis
Associated
Group
1
1,2 3
1
1
1
1
1,2 3
1
1,3
1
•
•
Table 2
Groundwater Treatment Analytical Data Summary
Koppers Superfund Site -Morrisville, North Carolina
May 2002
Analytical
Parameter Date Sample Sample
Sample Location Location
Collected SV-101
Pentachlorophenol 01/10/02
01/23/02 6.2
02/07/02
02/19/02
03/06/02
03/21/02
04/02/02 24
04/17/02
05/01/02
05/13/02
2.4-Dichlorophenol 01/10/02
01/23/02 <0.20
02/07/02
02/19/02
03/06/02
03/21/02
04/02/02 <0.20
04/17/02
05/01/02
05/13/02
Phenol 01/10/02
01/23/02 <0.20
02/07/02
02/19/02
03/06/02
03/21/02
04/02/02 <0.20
04/17/02
05/01/02
05/13/02
Chronic Toxicity 01/23/02
04/02/02
05/01/02
Dioxin (2,3,7,8-TCDD) 01/23/02 <2.6
04/02/02
Notes: All results are in micrograms per liter (µg/L) except dioxin. Dioxin data is in picograms per liter (pg/L).
SV-101 -Before Carbon Units
*SV-304 -Between Carbon Units
-•sV-305 -After Carbon Units
F:\Projects\03624\Reports\Monthly\SM-02 Table 2.xls
SV-304•
<1.0
<1.0
<0.20
<0.20
<0.20
<0.20
Sample
Location
SV-305"
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<0.96
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.19
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.19
Pass
Fail I
Fail
<1.5
<0.63
•
•
Q
ANALYTICAL REPORT
Raleigh, Biweekly NPDES
Lot#: C2E020227
Rita Bauer
The RETEC Group Inc
SEVERN TRENT LABORATORIES, INC.
Veronica Bortot
Project Manager
May 7, 2002
STL Pittsburgh is a part of Severn Trent laboratories, Inc
MlniD
STL Pittsburgh
450 William Pitt Way
Pittsburgh, PA 15238-1330
Tel: [phone]
Fax: [phone]
www.stl-inc.com
---------------------------------------------
Sample Receiving:
CASE NARRATIVE
THE RETEC GROUP
Raleigh, Biweekly NPDES
STL Lot# C2E020227
STL Pittsburgh, PA received one sample on May 2, 2002 in good condition.
was within the proper temperature range.
GC/MS Semivolatiles SIM:
There were no problems associated with the analysis.
The cooler
Since insufficient sample volume was received to perform a matrix spike and matrix
spike duplicate, a Laboratory Control Sample (LCS) and Laboratory Control Duplicate
(LCD) were performed. All recoveries were within QC limits.
•
•
•
•
•
•
METHODSSUMMARY
C2E020227
ANALYTICAL PREPARATION
PARAMETER METHOD METHOD --------
8270C (SIM) SW846 8270C SIM SW846 3520C
References:
SW846 "Test Methods for Evaluating Solid Waste, Physical/Chemical
Methods", Third Edition, November 1986 and its updates .
,-------------------------------
SAMPLE SUMMARY
C2E020227
WO# SAMPLE# CLIENT SAMPLE ID
E0R31 001 EFF/SV-305
NOTE (S) ,
-The analytical results of the samples listed above are presented on the following pages.
-All calculations are performed before rounding to avoid round-off errors in calculated results.
-Results noted as "ND" were nm detected at or above the stated limit.
-This report must not be reproduced, except in full, without the written approval of the laboratory.
-Results for the following parameters are never reported on a dry weigh! basis: color. corrosivity, density, llashpoim, ignitability, layers. odor,
paint tilter test, pH. porosity pressure, reactivity, redox potential, specific gravity, spot tests, solids, solubility, temperature, viscosity, and weight.
SAMPLED
DATE
•
os/01/02 08:40
•
•
Chain of·
Custody Record
STL-~12,1 (1200)
Clien/)_rrto:r_
'(/,C/
Add!ess
Sh) I<'. oJ.6. < ~~ Ste. 30:.'\
Cit~ I Sflerl I Zip~;; <f ~
Proj~ame and Location IStaM
\ -::i-ecc -Z.J2.,\ '
Contract/Purchase Order1Qbote No.
qlA
Sample I. D. No. and Description Date (Contai11ers for each sample may be combined on one line)
E f2F-/ SJ-3o'.J Lrf1I ;i,
Possible Hazard ldentit1cation
0 Non-Nazard D Flammable 0 Skin lmtant D Poison B
•
Projeo1anager ~
r-\r-. \ OJ...JL-r
Telephone Number (Area Code)/Fa)( Number
q 1i -3'7 f I <f J..:J..,
S1/e Contac/ Lab Contact
Carrier/Waybill Number ~ li:: J Containers & v" ~ Matrix ,. Preservatives -' ~ ... ' ~ 0 ~ , "' r-Time ! ~ a " ~ 0 G 0 qO A " ~ ~ § N 2 • C • t,> , , , 2 N2
l'R,, '-I 0 1'1 V I>< I .
I Sample Disposal
f.J/Unknown D Return To Cliell/ ~ Disposal By Lab D Archive For
Tum Around Tune Reqwred ' QC Reqwrements (Specify)
D 24 I lours 48 Hours 0 7Day 14 Days D 21Days
1. Relinquished
2. Relinquished
3 Relinquished By
Comments
DISTRIBUTION: \\'ff/TE-Slays with ttie Sample; CANARY-Returned to Client with Report; PINK-Field Copy
• Severn Trent Laboratories, Inc.
Date Chain of Custody Number
fijs-i .2_ 1nrir=;s1
Lab Number '
Page i of I
Analysis (Attach list if
more space is needed
Special Instructions/
Conclitions of Receipt
(A fee may be assessed if samples are retamed
Months longer than 3 months)
Date Time
Date Tune
.. ~ d 16!-
Date
------------------------------------------------
THE RETEC GROUP INC
Client Sample ID: EFF/SV-305
GC/MS Semivolatiles
Lot-Sample# ... : C2E020227-001 Work Order# ... : EOR311AA
Date Received .. : 05/02/02
Analysis Date .. : 05/06/02
Matrix ......... : WATER Date Sampled ... : 05/01/02
Prep Date ...... : 05/03/02
Prep Batch# ... : 2123162
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
MS Run# ....... :
Method ......... : SW846 8270C SIM
REPORTING
RESULT LIMIT UNITS
ND 0.20 ug/L
ND 1.0 ug/L
ND 0.20 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
96 (32 -112)
71 (10 -144)
75 ( 3 0 -110)
82 (13 -110)
93 (10 -113)
87 (21 -122)
•
•
•
• METHOD BLANK REPORT
GC/MS Semivolatiles
Client Lot# ... , C2E020227 Work Order# ... , E0VDDlAA
MB Lot-Sample#, C2E030000-162
Analysis Date .. , 05/06/02
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-d5
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribrornophenol
Prep Date ...... , 05/03/02
Prep Batch# ... , 2123162
REPORTING
RESULT LIMIT UNITS
ND 0.20 ug/L
ND 1.0 ug/L
ND 0.20 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
88 (32 -112)
65 (10 -144)
65 (30 -110)
80 (13 -110)
90 (10 -113)
80 (21 -122)
•
NOTE(S),
Calculations are performed before rounding to avoid round-off errors in calculated results .
•
Matrix ......... , WATER
METHOD
SW846 8270C SIM
SW846 8270C SIM
SW846 8270C SIM
__________________________________________________ ,_
LABORATORY CONTROL SAMPLE EVALUATION REPORT
GC/MS Semivolatiles
Client Lot# ... : C2E020227 Work Order# ... : E0VDDlAC-LCS
E0VDDlAD-LCSD
Analysis Date .. : 05/06/02
Matrix ......... : WATER LCS Lot-Sample#: C2E030000-162
Prep Date ...... : 05/03/02
Prep Batch# ... : 2123162
Dilution Factor: 1
PERCENT RECOVERY RPD
PARAMETER RECOVERY LIMITS RPD LIMITS METHOD
Phenol 90 (10 -131) SW846 8270C SIM
91 (10 -131) 1.2 (0-43) SW846 8270C SIM Pentachlorophenol 62 (10 -140) SW846 8270C SIM
61 (10 -140) 2.7 (0-56) SW846 8270C SIM 2,4-Dichlorophenol 99 (42 -115) SW846 8270C SIM
101 (42 -115) 2.0 (0-44) SW846 8270C SIM
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Nitrobenzene-dS 99 (32 -112)
101 (32 -112)
Terphenyl-d14 74 (10 -144)
75 (10 -144)
2-Fluorobiphenyl 81 ( 3 0 -110)
83 (30 -110)
2-Fluorophenol 89 (13 -110)
89 (13 -110)
Phenol-d5 97 (10 -113)
98 (10 -113)
2,4,6-Tribromophenol 95 (21 -122)
97 (21 -122)
NOTE(S):
Calculations are performed before rounding to avoid round-off errors in calculated results.
•
•
•
Effluent Toxicity Report Fonn -Chronic Pass/Fail and Acute LCS0 Date: 05/10/02
Facility: BEAZER NPDES#: NC
boratory Performing Test: TRITEST, INC.
x.~f...-_,~-+~~-----~~---~-=--------in Respons.1.
x.+=i~droW~~~n~LhJ2_..----~·=:,,c··'°· ;c;-;:-------
Work rder: 0205-00012
MAIL ORIGINAL TO:
North Carolina Ceriodaphnia
Chronic Pass/Fail Reproduction Toxicity Test
CONTROL ORGANISMS 1 2 3 4 5 6 7 8 9 10 11
Pipe#: County: WAKE
Comments:
Environmental Sciences Branch
Div. of Water Quality
N.C. DENR
1621 Mail Service Center
Raleigh, North Carolina 27699-1621
Chronic Test Results
Calculated t = 2.656
Tabular t = 2.508
12 % Reduction= 28. 36
% Mortality Avg.Reprod. # Young Produced 36 29 23 14 30 31 30 37 28 24 28 25
0.00 27.92
Control Control Adult (LI ive (DI ead L L L L L L L L L L L L
0.00 20.00
Treatment 2 Treatment 2 Effluent %: 90%
TREATMENT 2 ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 12 Control CV
21.840% PASS FAIL
# Young Produced 22 17 5 29 30 20 22 28 21 4 18 24 % control orgs □~ producing 3rd
dult (LI ive (DI ead brood Check One L L L L L L L L L L L L 100%
1st sample 1st sample 2nd sample Complete This For Either Test pH ~ ~ [E8HJ Test Start Date: 05/01/02 Control Collection (Start) Date
Sample 1: 04/30/02 Sample 2: 05/02/02 Treatment 2 Sample Type/Duration 8 6 9
1st s s s Grab Comp. Duration D t e t e t e I s a n a n a n Sample 1 X 24 hrs L A r d r d r d u M t t t Sample 2 X 24 hrs T p
1st sample 1st sample 2nd sample D.O. ~ ~ ~ Hardness (mg/11 46 .......... Control
Spec. Cond. (µmhosl 217 875 Treatment 2 0 1 4
Chlorine (mg/11 .......... <0.1 ewe I If ii& ifN\55 ,. 1;;;5•3 Si ; F
LC50/Acute Toxicity Test Sample temp. at receipt ( °CI .......... 0.4
(Mortality expressed as %, combining replicates I I
% % % % % % % % % %
% % % % % % % % % % I I I I I I I I I I I
Concentration
Mortalit y
start/end
Note: Please
Complete This
Section Also
start/end
LCSO ~-~--~% Method of Determination I I I Control I 95% Confidence Limits Moving Average Probit • . .
L--====~%:__-_-_:====~%:__L:S~p~e:a:r:m~a~n'..'._~K:a:r:b:e:r'.:_=:_~o:t:h~e:::.:r--===_J j High '----'--~· Cone. '----'---
pH D.O.
Organism Tested: Ceriodaphnia dubia Duration (hrs) :
Copied from DWQ form AT-1 (3/871 rev. 11/95 (DUBIA ver. 4.411
2nd
P/F
s
A
M p
..........
876
<0.1
2.0
TRITEST, INC.
Bio assay Chain ·of Custody Form
Bio assays . are to be sai.-npled after B:30a.m. on ---Tue-sday & Friday.
Fa::ilityNarne: hf,c.,zu/R.a lz<12
Address: Q.;To--, _(j3eu,u..r / /<it:J;: , P.O.#: ___________ _ 300 8~ Av<. :;--re, so::l Phone#(~ J.bi,-1,-
•
Outfall/ Pipe#:
.Contact: ~. -'
0 I NP~ESP~l,.dlg:p
%Effluent Dilution : ------'·-~¢....__ __ _ -TesiMethod: c.Lc-oAJ <---Td ;C
DateS~d: ~Jt>[;)... Tl!De: Obi) @,or PM
Sample Type: Composite '§ j
.. Date Ended: _&~_r...,/~;;:i,_· ________ Time: · Q 7%': @)or PM
Samples per Hour: \ ·#Hours: ;;> f ·
Grab:_
Date: ______ =--""========"---------__ Time:~--or PM Sampl_e Vohrn1e: __ ::,s~'.'.)~_Z=~~ -k.r::.~~~--~Chllled during Co!lection?_I..._-__
Method of Transportation to Lab: ---l~=::...:ci::,..__.,---'d""-'o""Q._·.,_, v~e--=C--'---------~
.... ◄ ♦ ,f ♦ ...... ♦ • ♦ ♦ ♦ • ♦ ♦ • ♦ •• ♦ •••• Chain of C_ustody Rel= ••••• ♦ • ♦ ♦ • • .••••• ♦ ♦ •·. ~ ••• ♦ ♦ Rclinnuished By. r _ ... D.re. · Time. Received Bv { I . J.1-~.,J'J/ ..
For Laboratory Use Only CC-. Receiving Temperature: ___ [)_._Lt _______ By: __ ~_, _lcltl __ ~_o_if'U..F~ __ -
Residual Chlorine: __ ~1-.J=D~µ=l'~ _____ Number of Betties: __ ;}-___ _
Address: 3909-Beryl Rd.-Raleigh, NC 27607 Phone(9!9) 834 -4984 Fax (91~) 834-6497
-Date Time
r
•
•
•
•
TRITEST, INC ..
Bioassay Chain ·of Custody Form
Bioassays .are to be sampled a,fter
Tuesday & Friday.
FadlityName: 8~ /&,$;6f/
8:30a.m. on
. . I I Address: f!.e;;g.,--J!,t[A //Aur4,-. l . P.O.#: ___________ _ J?o {(AJ&i? Av£ · ,Jv,TJZ JcJL . ' Pb.one# (C/7':r )3]l-/'f.ZZ.. cot-!©92 ,t&t ~IJ.'/7.-Contact: t;@ f~ ·
Outfall/Pipe#: _____ N-PDES Pemiit#: W,1AJ. U7J?;;;c_: %E:fi:1uent Dilution : __ ::::· :::_-___ _ r.;.i Method: Cdt4Y1c.-· TO}( · Sample Site Description~ ____________________
_
Sample Collector: hint> T£i'r: ?M~
Signature> z/etff~
Sample Type: Comoosite :
Da:te Started ; s/z/o Z Tiooe :~r PM Da:teEnded:_~r::;,_,_/.,cJk..,,,,e..L-.=·=--------Ti
m
e
:
of0 0 . @)or PM Sa.'llples per Hour: _ _, _________ ·#Hours: ;l Y
Date: ______________ _ Tune:-----'-Ale[ or P.M Sample Volume: dl.. L.;~( Cb.illed during Collection?_,,
1
Y,___ __
Method of Transportation to Lab : /-1>4,A,(} .f}.4Z! vr;z:4Z?
♦-• + • • • • •··• + • • • + • • + • + • • • + • • •. . Che.in ofCµs""..ady Rel:.ase
R er mourshe dB !y D ate Time Rece,ved Bv · Dato 0. /.,, ~ n~lcrz_ I 11-/{, ·-:-I\ A ' ltf-ru.,c:· ·,=, ? / /I 0 I.
I .
d(_ For Laboratory Use Only
· Receiving Temperaturc: _ _.;!J...._~. ,../)~------By: ~ /)o J,Jo/ft4::;
Residual Chlorine: )1,,(J,,<,L-Number of Bottles : _ _..(f __ _
Address: 3909·Beryl Rd.-Raleigh, NC 27607 Phon:(919) 834 -4984 Fax (91~) 834-6497 0 ZoC:--oool 2. -62J·z... (
02-
Time
!Ti7<'
~
--------------------------
ANALYTICAL REPORT
Raleigh, Biweekly NPDES
Lot#: C2El40203
Rita Bauer
The RETEC Group Inc
SEVERN TRENT LABORATORIES, INC.
Veronica Bertot
Project Manager
May 21, 2002
STL Pittsburgh is a part of Severn Trent Laboratories, Inc.
STL Pittsburgh
450 William Pitt Way
Pittsburgh, PA 15238-1330
Tel: [phone]
Fax: [phone]
www.stl-inc.com
•
•
•
•
•
•
Sample Receiving:
CASE NARRATIVE
THE RETEC GROUP
Raleigh, Biweekly NPD ES
STL Lot # C2E 140203
STL Pittsburgh, PA received one sample on May 14, 2002 in good condition. The cooler
was within the proper temperature range.
GC/MS Semivolatiles SIM:
There were no problems associated with the analysis.
Since insufficient sample volume was received to perform a matrix spike and matrix
spike duplicate, a Laboratory Control Sample (LCS) and Laboratory Control Duplicate
(LCD) were perfom1ed. All recoveries were within QC limits .
-----------------------------
METHODS SUMMARY
C2E140203
ANALYTICAL PREPARATION PARAMETER METHOD ~ME=T_H~O~D ____ _
8270C (SIM) SW846 8270C SIM SW846 3520C
References:
SW846 "Test Methods for Evaluating Solid Waste, Physical/Chemical
Methods", Third Edition, November 1986 and its updates.
•
•
•
SAMPLE SUMMARY
• C2El.40203
WO# SAMPLE# CLIENT SAMPLE ID
El.D2F 001 SYS EFF/SV-305
NOTE (S) :
-The analytical results of the samples listed above are presented on the following pages.
-All calculations are performed before rounding to avoid round-off errors in calculated results.
-Results noted as "ND" were not detected at or above the stated limit.
-TI1is report must not be reproduced, except in full, without the written approval of the laboratory.
· Results for the following parameters are never reported on a dry weight basis: color, corrosivity, density, flashpoint, ignirability, layers, odor,
paim filter test, pH, porosity pressure, reactivity, redox potential, specific gravity, spot tests, solids, solubility, temperature, viscosity, and weight.
•
•
SAMPLED
DATE
SAMP
TIME
05/13/02 15,15
Alternate billing information: ~tf:u
'.:Do &~JG-, A--..J-2. sTe 10:i
(GA-. co :-cl /1\ Y-',. e:, \7 'i ,:)_
FAX:
Collected by (signature): D
Cl(X;·,,,v-i-\ JJ
l'ack..:d 011 Ice N (.)
Sample ID
.
mail kr
'"'s'"; /1:l V'ollected . _ _ o---,,,
) CUent Project #: ESC Key:
Site/Facility ID#: P.O.#:
jRush?f ( Lab MUST Be Notified)
__ Same Day. . .... 200%
__ Next Day.. . ... 100%
__ Two Day. . .... 50%
Comp/Grab Matrix• Depth
Date Results Needed:
Email? _No_Yes
FAX? _No_Ye:,
Date Time
'
....,
) v ·-·~
No ~
Ci
of ,.)
Cnlrs "' ,..._
~
'::, i .,J
I
I '
i
!
i
' I I
I
I ' ' ! ;
*Matrix: SS -Soil/Solid GW -Groundwater WW -Wastewater DW -Drinking Water OT -Other ___ _
Remarks:
Relinqui ~~\\,~ Date: Time: Received by: (Signature) 's[ I 3 \<{DD Kj[
Relinquished by: (Signature} Date: Time: Received by: (Signature}
r>-"--··=-l-.-.J l-. ••• (Slgi1aiurt:) Dale: Tirne: 1"\t"lll14Ul.>tlt"U LJy.
Analvsis/Container/Preservative Chain of Custody
Page_ol_
CoCode: (lab use only)
Template/Prelogin
Shipped Via:
Remarks/Contaminant Sample # (lab only)
' .
i I I
i
' I ' l i I
' i
' ;
i
' I I
' !
pH Temp
Flow _____ _ O1hcr
amp es re urne -via: 0 UPS Condition: (tab use only) □ FedEx O Courier □, __ ~
Temp: Bottles Received:
Time: pH C"necked:
Oc)LtJ-I
THE RETEC GROUP INC
Client Sample ID: SYS EFF/SV-305 • GC/MS Semivolatiles
Lot-Sample# ... : C2El40203-001 Work Order # ... : ElD2FlAA Matrix .. _ ...... : WATER Date Sampled ... : 05/13/02 Date Received .. : 05/14/02 MS Run# ....... : Prep Date ...... : 05/15/02 Analysis Date .. : 05/20/02
Prep Batch # ... : 2135272
Dilution Factor: 0.96 Method ......... : SW846 8270C SIM
REPORTING
PARAMETER RESULT LIMIT UNITS
2,4-Dichlorophenol ND 0.19 ug/L Pentachlorophenol ND 0. 96 ug/L Phenol ND 0.19 ug/L
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Nitrobenzene-dS so ( 32 -112)
Terphenyl-dl4 70 (10 -144)
2-Fluorobiphenyl 55 ( 3 0 -110) 2 -Fluorophenol 51 (13 -110) Phenol-dS 58 (10 -113) 2,4,6-Tribromophenol 62 (21 -122)
•
•
------------------------------------------------------
METHOD BLANK REPORT
GC/MS Semivolatiles
Client Lot# ... : C2E140203 Work Order# ... : ElFMAlAA
MB Lot-Sample#: C2E150000-272
Analysis Date .. : 05/20/02
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
NOTE (S) :
Prep Date ...... : 05/15/02
Prep Batch# ... : 2135272
REPORTING
RESULT LIMIT UNITS
ND 0.20 ug/L
ND 1.0 ug/L
ND 0.20 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
56 (32 -112)
70 (10 -144)
58 (30 -110)
62 (13 110)
67 (10 -113)
62 (21 -122)
Calculations are performed before rounding to avoid round-off errors in calculated results.
•
Matrix ......... : WATER
METHOD
SW846 8270C SIM
SW846 8270C SIM
SW846 8270C SIM
•
•
LABORATORY CONTROL SAMPLE EVALUATION REPORT • GC/MS Semivolatiles
Client Lot# ... : C2El40203 Work Order# ... : ElFMAlAC-LCS
ElFMAlAD-LCSD
Analysis Date .. : 05/20/02
Matrix ......... : WATER LCS Lot-Sample#: C2El50000-272
Prep Date ...... : 05/15/02
Prep Batch# ... : 2135272
Dilution Factor: 1
PERCENT RECOVERY RPD
PARAMETER RECOVERY LIMITS RPD LIMITS METHOD
Phenol 69 (10 -131) SW846 8270C SIM
67 (10 -131) 4.2 (0-43) SW846 8270C SIM Pentachlorophenol 91 (10 -140) SW846 8270C SIM
93 (10 -140) 1.8 (0-56) SW846 8270C SIM 2,4-Dichlorophenol 78 (42 -115) SW846 8270C SIM
78 (42 -115) 0.070 (0-44) SW846 8270C SIM
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Nitrobenzene-dS 80 (32 -112)
84 (32 -112)
Terphenyl-dl4 75 (10 -144)
76 (10 -144)
2-Fluorobiphenyl 73 (30 -110)
• 2-Fluorophenol
74 (30 -110)
67 (13 -110)
67 (13 -110)
Phenol-d5 74 (10 -113)
72 (10 -113)
2,4,6-Tribromophenol 78 (21 -122)
82 (21 -122)
NOTE(S}:
Calculations arc performed before rounding to avoid round-off errors in calcula1ed results .
•
•
•
•
May 9, 2002
Ms. Beverly Hudson
Remedial Project Manager
U.S. EPA -Region IV, 11th Floor
North Site Management Branch
6 I Forsyth Street, SW
Atlanta, GA 30303
RE: Monthly Progress Report #108
Remedial Action
Koppers Site -Morrisville, NC
The RETEC Group, Inc.
300 Baker Avenue, Sulte 302
Concord, MA01742
[phone] Phone
[phone] Fax
www.retec.com
0:r;1t 1)----
//;; 1 c, .. /J llf /--.___
/
,,): M,4y -., I ~• /;)
L:: ,.'. .. ,. ~-:---1_3 2002 .~:~/
1, . 11, ---Dear Ms. Hudson: . ~J( ,' : ,. . ~ .
. .. ' '·i_ ',·, •"J .... '• 'I O'
In accordance with the Unilateral Order, and on behalf of Beazer East, Inc. (Beazer), pleas,/fin81 a ached
four (4) copies of the April Monthly Progress Report for Remedial Action at the Koppers Superfund Site
in Morrisville, NC. Because our Chronic Toxicity sample failed, we will collect chronic toxicity samples
on a monthly basis until two consecutive monthly tests pass.
Should you need additional information regarding this progress report, please call Mike Helbling at (412)
208-8858 or me at [phone] .
Sincerely,
The RETEC Group, Inc.
Gt /~1;,6wA-
Rita Bauer l
Project Geologist
RB:th
Enclosure
cc: D. Mattison -NC Superfund (2 copies)
L. Faulconer -·Wake County
G, Caskey -En wood Structures
M. Helbling -Beazer
F: \PR OJ E CTS\O 3 6 2 4\ R epo ns\M on th I y\200 2\4 M -02.doc
Peter Sullivan
Project Engineer
D. Hails -Ecological Restoration, Inc.
J. Garrett-NC Division of Water Quality
D. Matthews -NC Div. of Waste Management
P. Kilchenstein -RETEC
•
•
•
MONTHLY PROGRESS REPORT #108
REMEDIAL ACTION
SITE NAME: Koppers Superfund Site
Beazer East, Inc.
Morrisville, NC
USEPA DOCKET NUMBERS: 93-09-C
PERIOD ENDING: April 30, 2002
1. PROGRESS MADE THIS MONTH
2.
3.
4.
5.
6.
Remedial Action (RA) -HABITAT NllTIGA TION. No activities were conducted this
month.
Remedial Action (RA) -GROUNDWATER TREATMENT. The treatment system
operated throughout the month without upset. System performance was monitored on a
biweekly basis. Approximately 45,510 gallons of groundwater were extracted, treated in
the treatment plant and discharged between April 1, 2002 and April 30, 2002. System
water samples were collected on April 2, 2002 and April 17, 2002 in accordance with the
sampling schedule in the O&M manual. Samples were submitted to Severn Trent for
laboratory analysis. The operations and sampling programs are summarized on the
attached Table 1.
Remedial Action (RA) -EFFECTIVENESS MONITORING PROGRAM. No activities
were conducted this month.
Remedial Action (RA) -CORRESPONDENCE. None.
PROBLEMS RESOLVED
PROBLEMS ANTICIPATED
UPCOMING EVENTS
PERSONNEL CHANGES
SUBCONTRACTORS
None.
None.
Continue System O&M.
None.
None.
7. ANALYTICAL DATA Analytical data from system influent and effluent sampling
received during this period are enclosed and are summarized on Table 2 .
F :\PRO .IE CTS \0 3 624 \Re ports\M on th I y\2 002\4 M ·02. doc
• •
Table 1
Groundwater Treatment Operations and Sampling Program Summary
Koppers Superfund Site
Date Systems Cummulative SV-101 SV-101
Check Effluent Flow Sample Sample (ves/nol (Gallons) (yes/no\ Parameters
01/10/02 ,es 3 251 280 no
01/23/02 ,es 3 264 850 ,es Penta 2 4-Dichloro Phenol Dioxin
02/07/02 ves 3 283 240 no
02/19/02 ,es 3 300 140 no
03/06/02 ,es 3 318 630 no
03/21/02 ,es 3 338 440 no
04/02/02 ves 3 356 200 ves Penta 2 4-Dichloro Phenol Dioxin
04/17/02 ves 3,378 150 no
Notes:
Sampling point SV-101 is located before the Carbon Units (pretreatment}
Sampling point SV-304 is located between the Carbon Units
Morrisville, North Carolina
April 2002
Associated SV-304 SV-304 Associated SV-305
Group Sample Sample Group Sample
Ives/no\ Parameters (yes/no'
no ,es
1 2 ,es Penta 2 4-Dichloro Phenol 1 ,es
no yes
no ves no ves no ves
1 ,es Penta 2 4-Dichloro Phenol 1 yes
no ves
Associated Groups:
SV-101 -Group 1 is penta and 2,4-dichlorophenof; Group 2 is dioxin
SV-304 -Group 1 is penta and 2.4-dichlorophenol
•
SV-305
Sample
Parameters
Penta. 2 4-Dichloro Phenol
Penta, 2,4-Dichloro, Phenol, Dioxin, Chronic
Tox
Penta 2 4-0ichloro Phenol
Penta 2 4-Dichloro Phenol
Penta 2 4-Dichloro Phenol
Penta 2 4-Dichloro Phenol
Penta, 2.4-Dichloro, Phenol, Dioxin, Chronic
Tox
Penta, 2,4-Dichloro, Phenol
Sampling point SV-305 is lactated after the Carbons Units (post-treatment) SV-305 -Group 1 is penta, phenol, and 2,4-dichlorophenol; Group 2 is dioxin and Group 3 is chronic toxicity
NR -Not recorded
f:\Pfojec:II\DJ624\Repofts\Mon1hfy\,1M--.Q2 Tat le 1
Associated
Group
1
1 2 3
1
1
1
1
1 2 3
1
•
•
•
Table 2
Groundwater Treatment Analytical Data Summary
Koppers Superfund Site -Morrisville, North Carolina
April 2002
Analytical
Parameter Date Sample Sample
Sample Location Location
Collected I SV-101
Pentachlorophenol 01/10/02
01/23/02 6.2
02/07/02
02/19/02
03/06/02
03/21/02
04/02/02 24
04/17/02
2.4-Dichlorophenol 01/10/02
01/23/02 <0.20
02/07/02
02/19/02
03/06/02
03/21/02
04/02/02 <0.20
04/17/02
Phenol 01/10/02
01/23/02 <0.20
02107/02
02/19/02
03/06/02
03/21/02
04/02/02 <0.20
04/17/02
Chronic Toxicitv 01/23/02
04/02/02
Dioxin (2,3,7,8-TCDD) 01/23/02 <2.6
04/02/02
Notes: All results are in micrograms per liter (µg/L) except dioxin. Dioxin data is in picograms per liter (pg/L).
SV-101 -Before Carbon Units
*SV-304 -Between Carbon Units
-sv-305 -After Carbon Units
F:\Projects\03624\Reports\Monthly\4M-02 Table 2
SV-304'
<1.0
<1.0
<0.20
<0.20
<0.20
<0.20
Sample
Location
SV-305"
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<0.20
. <0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
Pass
Fail
<1.5
<0.63
•
•
•
ANALYTICAL REPORT
Raleigh, Biweekly NPDES
Lot:#: C2D0301.79
Rita Bauer
The RETEC Group Inc
SEVERN TRENT LABORATORIES, INC.
Veronica Bertot
Project Manager
April 9, 2002
STL Pittsburgh is a part of Severn Trent Laboratories, Inc.
STL Pittsburgh
450 William Pitt Way
Pittsburgh, PA 15238-1330
Tel: [phone]
Fax: [phone]
www.stl-inc.com
---------------------
Sample Receiving:
CASE NARRATIVE
THE RETEC GROUP
Raleigh, Biweekly NPDES
SIL Lot# C2D030179
SIL Pittsburgh, PA received samples on April 3, 2002 in good condition. The cooler was within the proper temperature range.
GC/MS Semivolatiles SIM:
Due to the concentration of target compounds detected, sample INF/SV-101 was analyzed undiluted and at a 6X dilution. Both sets ofresults are reported.
Dioxins:
SIL West Sacramento, CA performed the dioxin analysis. All results are included in the report.
There were no problems associated with the analysis.
•
•
SAMPLE SUMMARY • C2D030l.79
SAMPLED SAMP WO# SAMPLE# CLIENT SAMPLE ID DATE TIME
E.l()\19 001 INF/SV-101 04/02/02 10:05 E.l(A2D 002 B.C./SV-304 04/02/02 10:10 E.l(A2F 003 EFF/SV-305 04/02/02 10:15
NOTE (S) :
-The analytical results of the samples listed above are presented on the following pages.
-All calculations are perfonned before rounding 10 avoid round-off :rrors in calculated results.
-Results noted as "ND" were not detected at or above the stated limit.
-This report must not be reproduced. except in full, without the written approval of the laboratory.
-ResullS for the following parameters arc never reported on a dry weight basis: color, corrosivity, density. flashpoint, ignitability, layers, odor.
p:iim filter test, pH, porosity pressure, reactivity, redox potential, specific gravity, spot tests, solids, solubility, temperature, viscosity, and weight.
•
•
__________________________________________________ ,_
METHODS SUMMARY
C2DD3Dl. 79
PARAMETER
Dibenzodioxins and Dibenzofurans, HRGC/HRMS
8270C (SIM)
References:
ANALYTICAL PREPARATION
METHOD ~ME=T~H~O~D=--------
SW846 8290 SW846 8290
SW846 8270C SIM SW846 3520C
SW846 "Test Methods for Evaluating Solid Waste, Physical/Chemical
Methods", Third Edition, November l.986 and its updates.
•
•
•
~ain of l'"'llllR#ifU
Custody Record
ST 2 200 l•41 4 ( 1 I
Client ~ II .
.JI/Or,
Address
'Joo g,JG..,... A-.vi'. {'.'" < 7/ '1
City j State Zip Code c,,,.,,,. .::~ J11+ I')/ 7</J._.
Proje~me and Location /~le~
t_c,_ Z.GJ 12. ,z., I,. ( tJe,)
Contrac//Purchase Order/Quote No I
Sample J_Q_ No. and Description Date (Containers for each sample may be combined on one line)
X'I\JP/ 5• 1-Joi '-i I.). I)._
3,C... '< V -~D '-I . I'
f:.ff sv _Ji)f.c, 'O
Possible Hazard Identification
D Non-Hazard D Flammable 0 Skin Irritant D PoisonB
•
Project ~ager
,~-\-"'-R c~,.....---
Telephone Number (Area Code)IFax Number q1r--z-11 -I '-t 2.L
Site Contact Lab Contact
Carrier/tNaybill Number
< -Containers & Matrix Preservatives b ~ ! ~ • ~ , ,,, Q Time u ~ ~ ~ Q 0 Q qQ
~ • 0 ~ , ~ 0. • ~ ~ , , , NO
}DO') •-f... I',( 'I.. '/,.
Jo/u j '/.
/Or{ ~ '
)
I Sample Disposal
iZ'J Unknown D Re/um To Client li(oisposal By Lab 0 Archive For
Tum Around Time Required
D 24 Hours D 48 Hours
QC Requ,rements (Specify)
D 7 Days D 2 I Days J'A qther sw
/_ Relinquished By Time 1. Received By
CA 2. Relinquished By Time 2. Received By
3. Relinquished By Time
Comments
DISTRIBUTION: WHITE -Stays with the Sample; CANARY~ Returned to Client with Report; PINK -Field Copy
• Severn Trent Laboratories, Inc. ·
' D')J(J_ J_ Chain of rcr 7N69 0
Lab Numtier ( Page of I
Analysis (Attach list if
more s ace is needed)
Special Ins/ructions/
Conditions of Receipt
'
(A fee may be assessed if samples are retained
Months longer than 3 months)
------------------------------
TIIE RETEC GROUP JNC
Client Sample ID: INF/SV-101
Lot-Sample# ... : C2D030179-001
Date Sampled ... : 04/02/02
Prep Date ...... : 04/04/02
Prep Batch# ... : 2095109
GC/MS Semivolatiles
Work Order# ... : EXA191AA
Date Received .. : 04/03/02
Analysis Date .. : 04/08/02
Matrix. ____ ... __
MS Run# ....... :
Dilution Factor: 1 Method ......... : SW846 8270C SIM
REPORTING
PARAMETER RESULT LIMIT UNITS
2,4-Dichlorophenol ND 0.20 ug/L Pentachlorophenol 24 E l.O ug/L Phenol ND 0.20 ug/L
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Nitrobenzene-dS 75 ( 32 -112) Terphenyl-dl4 70 (10 -144)
2-Fluorobiphenyl 62 (30 -110)
2-Fluorophenol 69 (13 -110)
Phenol-dS 74 (10 -113)
2,4,6-Tribromophenol 70 (21 -122)
NOTE (SJ :
E Estimated result. Result concentration exceeds the calibration range.
•
WATER
•
•
•
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•
THE RETEC GROUP INC
Client Sample ID: INF/SV-101
Lot-Sample# ... : C2D030179-001
Date Sampled ... : 04/02/02.
Prep Date ...... : 04/04/02
Prep Batch# ... : 2095109
Dilution Factor: 6
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribrornophenol
GC/MS Semivolatiles
Work Order# ... : EXA192AA
Date Received .. : 04/03/02
Analysis Date .. : 04/08/02
Matrix ......... : WATER
MS Run# ....... :
Method ......... : SW846 8270C SIM
REPORTING
RESULT LIMIT UNITS
ND 1.2 ug/L
15 6.0 ug/L
ND 1.2 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
61 (32 -112)
69 (10 -144)
66 (30 -110)
60 (13 -110)
61 (10 -113)
56 (21 -122)
-----------------------------
THE RETEC GROUP INC
Client Sample ID: B.C./SV-304
GC/MS Semivolatiles
Lot-Sample# ... , C2D030179-002 Work Order# ... , EXA2D1AA
Date Received .. , 04/03/02
Analysis Date .. , 04/08/02
Matrix ......... , WATER Date Sampled ... , 04/02/02 MS Run# ....... , Prep Date ...... , 04/04/02
Prep Batch# ... , 2095109
Dilution Factor: 1 Method ......... : SW846 8270C SIM
REPORTING PARAMETER RESULT LIMIT UNITS 2,4-Dichlorophenol ND 0.20 ug/L Pentachlorophenol ND 1.0 ug/L Phenol ND 0.20 ug/L
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Nitrobenzene-d5 80 ( 32 -112)
Terphenyl-dl4 81 (10 -144) 2-Fluorobiphenyl 72 ( 3 0 -110)
2-Fluorophenol 73 (13 -110)
Phenol-dS 80 (10 -113)
2,4,6-Tribromophenol 73 ( 21 -122)
•
•
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THE RETEC GROUP INC
Client Sample ID: EFF/SV-305
GC/MS Semivolatiles
Lot-Sample# ... : C2D030179-003 Work Order# ... : EXA2FlAA
Date Received .. : 04/03/02
Analysis Date .. : 04/08/02
Matrix .... .
Date Sampled ... : 04/02/02
Prep Date ...... : 04/04/02
Prep Batch# ... : 2095109
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
MS Run # .. .
Method ......... : SW846 8270C SIM
REPORTING
RESULT LIMIT UNITS
ND 0.20 ug/L
ND 1.0 ug/L
ND 0.20 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
75 (32 -112)
77 (10 -144)
66 (30 -110)
66 (13 -110)
73 (10 -113)
63 (21 -122)
WATER
_________________________________ ,_
THE RETEC GROUP INC
Client Sample ID, EFF/SV-305
Trace Level Organic Compounds
Lot-Sample# ... , C2D030179-003 Work Order# ... , EXA2FlAC
Date Received .. , 04/03/02
Analysis Date .. , 04/06/02
Date Sampled ... , 04/02/02
Prep Date ...... , 04/04/02
Prep Batch# ... , 2094098
Dilution Factor: 1
DETECTION
PARAMETER RESULT LIMIT
2,3,7,8-TCDD ND 0.63
PERCENT RECOVERY
INTERNAL STANDARDS RECOVERY LIMITS
13C-2,3,7,8-TCDD 63 (40 -135).
Matrix.•···-···' WATER
MS Run # ... _ ... ,
UNITS METHOD
pg/L SW846 8290
•
•
•
•
Client Lot# ... : C2D030179
MB Lot-Sample#: C2D050000-109
Analysis Date .. : 04/08/02
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-ds
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-dS
2,4,6-Tribromophenol
.NOTE(S):
METHOD BLANK REPORT
GC/MS Semivolatiles
Work Order# ... : EXE971AA
Prep Date ...... : 04/04/02
Prep Batch# ... : 2095109
REPORTING
RESULT LIMIT UNITS
ND 0.20 ug/L
ND 1.0 ug/L
ND 0.20 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
46 (32 -112)
64 (10 -144)
42 (30 -110)
42 (13 -110)
46 (10 -113)
45 (21 -122)
C::ilculations are performed before rounding co avoid round-off errors in calculated results .
•
Matrix ..... . WATER
METHOD
SW846 8270C SIM
SW846 8270C SIM
SW846 8270C SIM
-----------------------------
Client Lot# ... :
MB Lot-Sample#:
C2D030179
G2D040000-098
Analysis Date .. : 04/05/02
Dilution Factor: 1
PARAMETER
2,3,7,8-TCDD
INTERNAL STANDARDS
13C-2, 3, 7, 8-TCDD
NOTE{S):
METIIOD BLANK REPORT
Trace Level Organic Compounds
Work Order# ... : EXC3AlAA
Prep Date ...... : 04/04/02
Prep Batch# ... : 2094098
DETECTION
RESULT LIMIT UNITS
ND 0. 73 pg/L
PERCENT RECOVERY
RECOVERY LIMITS
58 (40 -135)
Calculations are performed before rounding to avoid round-off errors in calcu!a1ed results.
•
Matrix. -.... WATER
METHOD
SW846 8290
•
•
• LABORATORY CONTROL SAMPLE EVALUATION REPORT
GC/MS Semivolatiles
Client Lot# ... : C2D030179 Work Order# ... : EXE971AC-LCS
EXE971AD-LCSD
Analysis Date .. : 04/08/02
Matrix ..... .
LCS Lot-Sample#: C2D050000-109
Prep Date ...... : 04/04/02
Prep Batch# ... : 2095109
Dilution Factor: 1
PERCENT RECOVERY RPD
PARAMETER RECOVERY LIMITS RPD LIMITS METHOD
Phenol· 68 (10 -131) SW846
72 (10 -131) 5.5 (0-43) SW846
Pentachlorophenol 59 (10 -140) ·SW846
60 (10 -140) 1. 2 (0-56) SW846
2,4-Dichlorophenol 72 (42 -115) SW846
76 (42 -115) 4.3 (0-44) SW846
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Nitrobenzene-ds 69 ( 32 112)
74 ( 32 -112)
• Terphenyl~dl4 68 (10 144)
68 (10 144)
2-Fluorobiphenyl 60 ( 3 0 -110)
65 ( 30 -110)
2-Fluorophenol 61 (13 -110)
66 (13 -110)
Phenol-d5 70 (10 -113)
74 (10 -113)
2,4,6-Tribromophenol 72 (21 -122)
78 (21 -122)
NOTE (S) :
Calculations are performed before rounding to avoid round-off errors in calculated results .
•
WATER
8270C SIM
8270C SIM
8270C SIM
8270C SIM
8270C SIM
8270C SIM
LABORATORY CONTROL SAMPLE EVALUATION REPORT
Trace Level Organic Compounds
Client Lot II ... , C2D030179 Work Order II .... : EXC3AlAC
LCS Lot-Sample#, G2D040000-098
Prep Date ...... , 04/04/02 Analysis Date .. , 04/06/02
Prep Batch# ... : 2094098
Dilution Factor: 1
PERCENT RECOVERY
PARAMETER RECOVERY LIMITS
2,3,7,8-TCDD 110 (75 -126)
PERCENT
INTERNAL STANDARD RECOVERY
13C-2,3,7,8-TCDD 70
NOTE (SJ ,
Calculations are performed before rounding to avoid round-off errors in calculated results.
Bold print denotes control parameters
Matrix ..... _ ... , WATER
METHOD
SW846 8290
RECOVERY
LIMITS
(40 -135)
•
•
•
Effluent Toxicity Report Form -Chronic Pass/Fail and Acute LCSO Date, 04/12/02
Facility, BEAZER NPDES#, NC Pipe#, County, WAKE
aboratory Performing Test, TRITEST, INC.
Comments:
x---;,c=h=-=-±=-=-===,c--,c=---ss-=====c:-;s===-----r in Responsi
x.---;,c±=cJ-dAtk-\-=-,'-4---c\,="""~cA=L<,<P.-c===-=---------Pervisor
Work Order, 0204-00135
MAIL ORIGINAL TO,
North Carolina Ceriodaphnia
Chronic Pass/Fail Reproduction Toxicity Test
CONTROL ORGANISMS 1 2 3 4 5. 6 7 8 9 10 ll
Environmental Sciences Branch Div. of Water Quality
N.C. DENR
1621 Mail Service Center
Raleigh, North Carolina 27699-1621
Chronic Test Results
Calculated t = 4.680
Tabular t = 2.508
12 % Reduction== 29.36
# Young Produced 29 30 30 30 30 31 % Mortality Avg.Reprod.
30 28 26 28 31 21
0.00 28.67
Control Control Adult (L)ive (D) ead L L L L L L L L L L L L
0.00 20.25
Effluent % ' 90% Treatment 2 Treatment 2
TREATMENT 2 ORGANISMS l 2 3 4 5 6 7 8 9 10 11 12 Control CV
9.792% PASS FAIL
# Young Produced 23 19 20 24 21 8 25 14 30 18 22 19 % control ergs □~ producing 3rd
dult (LI ive (D)ead brood Check One L L L L L L L L L L L L 100%
1st sample 1st sample 2nd sample Complete This For Either Test pH ~ ~ ~ Test Start Date, 04/03/02 Control Collection (Start) Date Sample 1, 04/01/02 Sample 2' 04/05/02 Treatment 2 Sample Type/Duration 9 9 8
1st s s s Grab Comp. Duration D t e t e t e I s a n a n a n Sample 1 X 24 hrs L A r d r d r d u M t t t Sample 2 X 24 hrs T p 1st sample 1st sample 2nd sample D.O. t83E8 [EffiB ~ Hardness(mg/11 48 .......... Control
Spec. Cond. (µmhos) 191 857 Treatment 2 l 2 2
Chlorine(mg/1) .......... <0.1
LC50/Jl.cute Toxicity Test Sample temp. at receipt ( °C) 0.9
{Mortality expressed as %, combining replicates)
% %1 % % % % % %1 % % Concentration
% % % % % % % % % % Mortality I I I I I I I I I start/end
LC50 % -----~Limits 95% Conr1ctence
% --% •
Method of Determination
Moving Average Probit
Spearman Karber Other
Organism Tested: Ceriodaphnia dubia Duration(hrs),
Copied from DWQ form AT-1 (3/87) rev. 11/95 (DUBIA ver. 4.41)
pH
I
.. ........
I
Note, Please
Complete This
Section Also
start/end
D.O.
2nd
P/F
s
A
M p
.......... ..........
894
<0.1
0.6
-
..
TRITEST, INC. ii
Bioassay Chai,"1 of Custody Form
Bioassays .are to be sai.upled a,fter 8:30a.m. oii 'Tuesday &: Friday.
FaciWy Name: ~ z~r iQA (Jrq h
Address: 38n ~ Ave St-e, sooe P.O.#: (<'S't'-,L,e d ,fY\A C) 1742 Phone # ( C/7 f ) ~,/-/ "i _).__)._ W1v I
~--Contact: g~
County: L-J A-\::~ O!-JtfalL' Pipe# : -NP~ES Permit# : -fl.,J»vYJ b:/:ky'
%Effluent Dilution : -¢ Test Method : · Cfvo Cl J' C /OJ\ s -r'<;; [-/=+ . . . · Sample Site Description:
Sample Collector: _Print> ~Jj ~ignature >
Sample Type: Comoosite : tt:t)_ Date Started : Time: o~.fo G)orP~
Date Ended: Time: lt/0 -~or PM
Samples per Hour: { ·# E;ours: /)cf
Gr.ab: --.
-~~ Date: -· ~rPM J.une:
S2mple Volume: Chilled during Colle~ '-"' I ?
Method of Transportation to Lab: 4-fe-vJ J..&iv~r
. .. +••························ · Chain of Custody Release • + ♦ •• t + ♦ ♦ • •. + ♦ ♦ ••• ♦ •·. t ♦ ♦ + ♦ • -Reli•"'•tshed By , __ ,1 DRr.e ·, Time Rec::ived Bv · Date Tim
( ,. l"r:-CN --11 c,i .Y &'ii.fr) /. I) ~ /11.,,u-,I -,J. . tn.,, I '-1 l-'•
I .. I
-

I

I
I _.
9 tJC.,
For Laboratory Use Only ZJ~ --~t.u. · Receiving Temperature: By: I
Residual Chlorine: ~ Number ofBottles: J. • ' Address: 3 909-Beryl Rd.-Raleigh, NC 27607 Phone[phone] !'ax [phone]
( tJ/,,IJif--ooi!ti
•
•
•
TRITEST, INC. -
Bioassay Chain of Custody Form
Bioassays .are to be samoled a,fter 8:30a.m. on --Tuesday & Friday.
Facility Na.-ne; ]?&A~ /;PAc.,1£/ £:ii --I -Address: /Zg,T,Z: C P.O.#: ___________ _ ----9' Joo fVr(~
Cor,.JCO/Y) -d'.ff . I .
Phone# ( "f I"/ ) 27 I -7 'z(r-f,
Contact: -S-~ ?,✓-=="cf:V,@;.'
Outfall/ Pipe# : --'0"'/____ NPDES Permit# : /tfen rt</ , /4::z;rpye
%Effluent Dilution : --~-----Test Method: ________ _
· Sample Site Description: §",..C-G /,/' ~
Sample Collector: Print>4'~v£L
-Signature> ,.,;:,,:-=:,,:.,1+-,1',~c,;,==::::....==-,----------_ V --Sample Type: ComoosJte: .
Date Started '----':""A_'-"~1-'~c._a_
1
,,.ccZ-c,._ --~---Time :~r PM.
Date Ended: --~' .... J '-"~"--=-~'--~------Time: DfC! C) ~or PM
Grab:_
Date : ___ iv~/2--'ri-____ _ Time'-----'-AM or PM
SampJ.e Volume: _,;z. ___ L_,r~~¼~-~~~--,--~Chilled during Collection?_
1;..)I __
+' • • • • • • + • • • + • • • • • • • • • • • • • • • · Chain ofC_uStody Release ••• + •••• ♦ • • ... ♦ ♦ •• ♦ • •·. ! • ♦ ♦ ♦ ♦ .
Relinquished By Date Ttm'!. Received Bv -Date Time ,...,.,;,'~ _,,r,J' _ _,, '7//7,, z_ cJ'l~O ,_ ,-, •m t!h,u..R LJ -~ -()2. '72/\ {/" VU -
. I -
-

-
ae.
-Redvl'1g Temper!L'ur:-: _ __,.O'--, ,.;(o,_ _______ By: _ __,_L~-'---'-'72"",-._,m'-"""o-.,.ka.-1 ... ¢ ._p_
For Laboratory Use Only
Residual Chlorine: __ _,,_r""/~~•==-----Number ofHottles: _ ___.2=---
Ad-dress: 3909-Beryl Rd.-Raleigh, NC 27607 Phone(919)_834 -4984 Fa.--: (91~) 834-6497-() z,:;i ~ -oz;/3,;---: cJD~
•
•
I
•
ANALYTICAL REPORT
Raleigh, Biweekly NPDES
Lot 11: C2D190l36
Rita Bauer
The RETEC Group Inc
SEVERN TRENT LABORATORIES, INC.
Veronica Bortot
P!"oject Manager
April 24, 2002
STL Pittsburgh is a part of Severn Trent Laboratories, lnc.
irifiml ■
STL Pittsburgh
450 William Pitt Way
Pittsburgh, PA 15238-1330
Tel: [phone]
Fax: [phone]
www.stl-inc.com
~----------------------------------
Sample Receiving:
CASE NARRATIVE
THE RETEC GROUP
Raleigh, Biweekly NPDES
STL Lot# C2Dl90!36
STL Pittsburgh, PA received one sample on April 19, 2002 in good condition. The
cooler was within the proper temperature range.
GC/MS Semivolatiles SIM:
There were no problems associated with the analysis.
Since insufficient sample volume was received to perform a matrix spike and matrix
spike duplicate, a Laboratory Control Sample (LCS) and Laboratory Control Duplicate
(LCD) were performed. All recoveries were within QC limits.
•
•
•
•
•
•
METHODS SUMMARY
C2D1-901-36
ANALYTICAL PREPARATION
~P~ARAME==~T~E=R-'--------------------------METHOD _M_E_T_H_O_D ____ _
8270C (SIM) SW846 8270C SIM SW846 3520C
References:
SW846 "Test Methods for Evaluating Solid Waste, Physical/Chemical
Methods 11 , Third Edition, November 1986 and its updates .
-----------------------------
SAMPLE SUMMARY
C2Dl.90l.36
!'.!.Q_jL_ SAMPLE# CLIENT SAMPLE ID
EX6FG 001 EFF/SV-305
NOTE{S) :
-The analytical results of the samples listed above are presented on the fo!lowing pages.
-Al! calcufadons are performed before rounding to avoid round-off errors in calculated results.
-Results noted as "ND" were not detected at or above the stated limit.
-This report must not be reproduced, except in full, withom rhe written approval of the laborawry.
-Results for the following parameters are never reported on a dry weight basi,s: color, corrosivity, density. flashpoint, ignitabi!ity, layers, odor,
paint filter test, pH, porosity pressure, reactivity, redo:< potemial. specific gravity, spot tests, solids, solubility, temperature, viscosity, and weight.
SAMPLED
DATE
•
SAMP
TIME
04/17/02 13 :4
•
•
• •
CHAIN OF CUSTODY RECORD PAOJ. UO PROJECT NAME
1// f?~e, RcJ..o..ic1 i,, 01
,._0 '\ CLIENT ' I NO ,, ,:;, Qztiu OF " CON-CJ I,
/~
C G TAINEAS ~ \) 1 SA.UPLE DATE TIME 0 A STATION LOCATION REMARKS ,o M A 4.: p B
•1',1}1 /Jj, )( 'i:...F{:.-/,:,·..J -:,«'=, c; )( -t..' ,c
'
Relj'1 uished by: {Signa/1.1,0) Dale/Time Received by: (Signature) Relinquished by: (Signatu,e) Date/Time Received by: (Signature) ov-.-JtJ ci;, ,/ ~ I !'Tu.:> kA:i,,vv--I Ret-:-r<quishGd by: (Signaturu) ' Date/Time Received by: (Signa/Ure) Relinquished by: (Signature) Dale/Time Received by: (Signarure)
I I Relinquished by: (Signature) Dale/Time Aeceiv.,.e~Horlaboratory by: Dale/Time Remarks
I !Yg~hJ/f/J l 11M / rz' / ,, l/-lf, , / '-'L-
(._/ -' ).''-{)--
_____________________________ ,_
TilE RETEC GROUP INC
Client Sample ID, EFF/SV-305
GC/MS Semivolatiles
Lot-Sample# ... , C2Dl90136-001 Work Order# ... , EX6FG1AA
Date Received .. , 04/19/02
Analysis Date .. , 04/23/02
Matrix ......... , WATER Date Sampled ... , 04/17/02
Prep Date ...... , 04/22/02
Prep Batch# ... , 2112324
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
MS Run# ....... ,
Method ......... , SW846 8270C SIM
REPORTING
RESULT LIMIT UNITS
ND 0.20 ug/L
ND 1.0 ug/L
ND 0.20 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
72 ( 32 -112)
69 (10 -144)
56 ( 3 0 -110)
58 (13 -110)
66 (10 -113)
62 ( 21 -122)
•
•
•
•
Client Lot# ... : C2Dl90136
MB Lot-Sample#: C2D220000-324
Analysis Date .. : 04/23/02
Dilution Factor: 1
PARAMETER
Pentachlorophenol
2,4-Dichlorophenol
Phenol
SURROGATE
Nitrobenzene-d5
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-dS
2,4,6-Tribromophenol
OTE (S) ,
METHOD BLANK REPORT
GC/MS Semivolatiles
Work Order# ... : EX8251AA
Prep Date ...... : 04/22/02
Prep Batch# ... : 2112324
REPORTING
RESULT LIMIT UNITS
ND 1. 0 ug/L
ND. 0.20 ug/L
ND 0.20 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
95 (32 -112)
88 (10 -144)
73 (30 -110)
80 (13 -110)
89 (10 -113)
78 (21 -122)
Calculations are performed before rounding 10 avoid round-off errors in calculated results .
•
Matrix ..... . WATER
METHOD
SW846 82 70C SIM
SW846 82 70C SIM
SW846 8270C SIM
----------------------------------------------~---,-
LABORATORY CONTROL SAMPLE EVALUATION REPORT
GC/MS Semivolatiles
Client Lot # ... : C2Dl90136 Work Order# ... : EXB251AC-LCS
EX8251AD-LCSD
Analysis Date .. : 04/23/02
Matrix ......... : WATER
LCS Lot-Sample#: C2D220000-324
Prep Date ...... : 04/22/02
Prep Batch# ... : 2112324
Dilution Factor: 1
PERCENT RECOVERY RPD
PARAMETER RECOVERY LIMITS RPD LIMITS METHOD
Phenol 88 (10 -131) SW846 8270C SIM
74 (10 -131) 17 (0-43) SW846 8270C SIM
Pentachlorophenol 54 (10 -140) SW846 8270C SIM
47 (10 -140) 13 ( 0-56) SW846 8270C SIM 2,4-Dichlorophenol 93 (42 -115) SW846 8270C SIM
80 ( 4 .2 . -115) . 16 (0-44) SW846 8270C SIM
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Nitrobenzene-ds 101 (32 -112)
87 (32 -112)
Terphenyl-dl4 82 (10 -144)
73 (10 -144)
2-Fluorobiphenyl 79 ( 3 0 -110)
69 (30 -110)
2-Fluorophenol 78 (13 -110)
67 (13 -110)
Phenol-dS 92 (10 -113)
78 (10 -113)
2,4,6-Tribromophenol 92 (21 -122)
Bl (21 -122)
NOTE (S) :
Calculations are performed before rounding to avoid round--off errors in calculated results.
•
•
•
•
•
•
Letter of Transmittal
The RETEC Group, Inc.
300 Baker Avenue, Suite 302
Concord, MA 01742-2851
:~(~RETEC !,!\~
APR 1 5 2002 !<' !J 978.371. 1422 Phone
' 978.371. 1448 Fax
.... 3 www.retec.com
. :Q' N ! I I
TO: D. Mattison, North Carolina Superfund
Koppers Superfund Site Monthly Progress
Report Analytical Data
DATE: ~ALpr~il~l'-'0~, =-20'-'0"'2 _______ _
RE: PROJECT NO: BEAZ7-03624-096
•
PLEASE FIND: ~ Attached D Under separate cover via:
D Copy of Letter
D Samples
D Change Order
D Other:
D Drawings/Figures D Plans/Specs
Copies Date No. Descriotion
2 Aoril I 0, 2002 Monthlv Progress Reoort # I 07
D For Approval
~ For Your Use
D Approved as Submitted
D Approved as Noted
D As Requested O Returned for Corrections
0 For Review & Comment
Remarks:
David
0 Resubmit
0 Submit
0 Return
0 Other:
___ Copies for Approval
___ Copies for Distribution
___ Corrected Prints
Attached, please find your two copies of the Monthly Progress Report #107, for the Koppers Superfund Site in
Morrisville, North Carolina. In recent communications you had requested a full report on the QA/QC data
relevant to the sample analysis performed for the progress reporting. In the March 13, 2002 analytical report,
comments regarding QA/QC perfomed for the March 6, 2002 sample analyses were not included from the Case
Narrative section of the laboratory report because RETEC's sample was not selected for use in running the batch
MS/MSD sample. In the March 27, 2002 report, insufficient sample volume and lack of samples prevented the
laboratory from running an MS/MSD pair_ However, as their note states, they were able to run an LCS/LCSD to
check the laboratory QC. Should you have any further question about the QA/QC data for the enclosed analytical
reports, please contact me at [phone].
Should you have any questions, please feel free to call me.
Sincerely,
The RETEC Group, Inc.
Peter Sullivan, Project Engineer
cc:
• Apri I I 0, 2002
Ms. Beverly Hudson
Remedial Project Manager
U.S. EPA-Region IV, I !th Floor
North Site Management Branch
6 I Forsyth Street, SW
Atlanta, GA 30303
RE: Monthly Progress Report #107
Remedial Action
Koppers Site -Morrisville, NC
Dear Ms. Hudson:
The RETEC Group, Inc,
300 Baker Avenue, Suite 302
Concord, MA01742
.RETE(
.... ,-i ·:·:_ ,---::-=wll 371-1422 Phone le.' I' 111 -, , I ,\ 1-1 · '. ·Ig7 ) 371-1448 Fax [i;", ... ,·1 i -~ ! . "i ' r
· - · -.. · .... 1 1 ! www.retec.com ! : i Jl APR 1 5 2002 1, ·.~/
In accordance with the Unilateral Order, and on behalf of Beazer East, Inc. (Beazer), please find attached
four (4) copies of the March Monthly Progress Report for Remedial Action at the Koppers Superfund Site
in Morrisville, NC. No exceedances occurred during this event.
Should you need additional information regarding this progress report, please call Mike Helbling at (412)
208-8858 or me at [phone].
• Sincerely,
•
Project Geologist
RB:th
Enclosure
cc: D. Mattison -NC Superfund (2 copies)
L. Faulconer -Wake County
G. Caskey -Enwood Structures
M. Helbling -Beazer
D. Hails -Ecological Restoration, Inc.
J. Garrett-NC Division of Water Quality
D. Matthews -NC Div. of Waste Management
P. Kilchenstein -RETEC
F: \ P ROJ ECTS\O 3 62 4\Rcports\M on th ly\2 002\3 M -02. doc
Peter Sullivan
Project Engineer
•
•
•
MONTHLY PROGRESS REPORT #107
REMED[AL ACTION
SlTE NAME: Koppers Superfund Site
Beazer East, Inc.
Morrisville, NC
USEPA DOCKET NUMBERS: 93-09-C
PERlOD ENDlNG: March 31, 2002
1. PROGRESS MADE THIS MONTH
2.
3.
4.
5.
6.
7.
Remedial Action (RA) -HABITAT ll1ITIGATION. No activities were conducted this
month.
Remedial Action (RA) -GROUNDWATER TREATJ'v!ENT. The treatment system
operated throughout the month without upset. System performance was monitored on a
biweekly basis. Approximately 45,210 gallons of groundwater were extracted, treated in
the treatment plant and discharged between March 1, 2002 and March 3 I, 2002. System
water samples were collected on March 6, 2002 and March 21, 2002 in accordance with
the sampling schedule in the O&M manual. Samples were submitted to Severn Trent for
laboratory analysis. The operations and sampling programs are summarized on the
attached Table I.
Remedial Action (RA) -EFFECTIVENESS MONITORING PROGRAM. No activities
were conducted this month.
Remedial Action (RA) -CORRESPONDENCE. None.
PROBLEMS RESOLVED None.
PROBLEMS ANTICIPATED None.
UPCOMING EVENTS Continue System O&M.
PERSONNEL CHANGES None.
SUBCONTRACTORS None.
ANALYTICAL DATA Analytical data from system influent and effluent sampling
received during this period are enclosed and are summarized on Table 2 .
F: \PRO J E CTS\03 624 \Reports\M onth I y\2 002\J M ·02. doc
•
Table 1
Groundwater Treatment Operations and Sampling Program Summary
Koppers Superfund Site
Date Systems Cummulative SV-101 SV-101
Check Effluent Flow Sample Sample
(ves/no) (Gallons) {ves/no\ Parameters
01/10/02 ves 3,251,280 no
01/23/02 ves 3,264,850 ves Penta 2,4-Dichtoro, Phenol. Dioxin
02/07/02 ves 3,283,240 no
02/19/02 ves 3,300,140 no
03/06/02 ves 3,318 630 no
03/21/02 ves 3,338,440 no
Notes:
Sampling point SV-101 is located before the Carbon Units (pretreatment)
Sampling point SV-304 is located between the Carbon Units
Morrisville, North Carolina
March 2002
Associated SV-304 SV-304 Associated SV-305
Group Sample Sample Group Sample
(ves/no) Parameters (yes/no)
no ves
1, 2 ves Penta, 2 4-Dichloro, Phenol 1 ves
no yes
no yes
no ves
no ves
Associated Groups:
SV-101 -Group tis penta and 2,4-dichlorophenol; Group 2 is dioxin
SV-304 -Group 1 is penta and 2,4--dichlorophenol
•
SV-305
Sample
Parameters
Penta, 2 4-Dichloro, Phenol
Penta, 2,4-Dichloro, Phenol. Dioxin, Chronic
Tox
Penta, 2,4-Dichloro Phenol
Penta, 2,4-Dichloro Phenol
Penta 2.4-Dichloro Phenol
Penta, 2,4-Dichloro, Phenol
Sampling point SV-305 is lactated after the Carbons Units (post-treatment) SV-305 -Group 1 is penta, phenol, and 2,4-dichloropheno!; Group 2 is dioxin and Group 3 is chronic toxicity
NR -Nol recorded
F:\Pr0jects\0l624\Reporl5\MOl\lhly\3M-02 Table l . .!1
Associated
Group
1
1,2 3
1
1
1
1
•
•
Parameter
Table 2
Groundwater Treatment
ANALYTICAL DATA SUMMARY
Koppers Superfund Site
Analytical
Date Sample Sample
Sample Location Location
Collected SV-101
Pentachlorophenol 01/10/02
01/23/02 6.2
02/07/02
02/19/02
03/06/02
03/21/02
2.4-0ichlorophenol 01/10/02
01/23/02 <0.20
02/07/02
02/19/02
03/06/02
03/21/02
Phenol 01/10/02
01/23/02 <0.20
02/07/02
02/19/02
03/06/02
03/21/02
Chronic Toxicity 01/23/02
Dioxin (2,3,7,8-TCOO) 01/23/02 <2.6
Notes: All results are in micrograms per liter (µg/L) except dioxin. Dioxin data is in picograms per liter (pg/L).
SV-101 -Before Carbon Units
*SV-304 -Between Carbon Units
*"SV-305 -After Carbon Units
F :\PROJECTS\03624\Reports\Monthl y\2002\3M-02 Table 2.x!s
SV-304'
<1.0
<0.20
<0.20
Sample
Location
SV-305 ..
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
Pass
<1.5
•
•
ANALYTICAL REPORT
Raleigh, Biweekly NPDES
Lot#: C2C0703l.6
Rita Bauer
The RETEC Group Inc
SEVERN TRENT LABORATORIES, INC.
Veronica Bortot
Project Manager
March 1.3, 2002
STL Pittsburgh is a part of Severn Trent laboratories, Inc.
SEVER.N
SERVICES, .
STL Pittsburgh
450 William Pitt Way
Pittsburgh, PA 15238-1330
Tel: [phone]
Fax: [phone]
www.stl-inc.com
.---------------------------------------------
Sample Receiving:
CASE NARRATIVE
THE RETEC GROUP
Raleigh, Biweekly NPDES
SIL Lot# C2C0703 l 6
SIL Pittsburgh, PA received one sample on March 7, 2002 in good condition. The
cooler was within the proper temperature range.
GC/MS Semivolatiles SIM:
There were no prnblems associated with the analysis.
•
•
•
SAMPLE SUMMARY
C2C07031.6
WO # SAMPLE# CLIENT SAMPLE ID
EV4HD 001 EFF/SV-305
NOTE (S) :
-The analytical results of the samples listed above are presented on the following pages.
• All calculations are performed before rounding to avoid round-off errors in calculated results.
• Results noted as "ND" were not detected at or above the stated limit.
-This repon must not be reproduced, except in full, without the written approval of the laboratory.
• Results for the following parameters are never reported on a dry weight basis: color. corrosivity, density, flashpoint, ignitability. layers, odor,
paint filter test, pH, porosity pressure, reactivity, redo,c po1ential, specific gravity, spot tests. solids, solubility, temperature, viscosity, and weight.
SAMPLED
DATE
SAMP
TIME
03/06/02 1.7:05
---------------------------------------------------
METHODS SUMMARY
C2C07031-6 •
ANALYTICAL PREPARATION
PARAMETER METHOD _ME_T_H_O~D~----
8270C (SIM) SW846 8270C SIM SW846 3520C
References:
SW846 "Test Methods for Evaluating Solid Waste, Physical/Chemical
Methods", Third Edition, November 1986 and its updates.
•
•
•
•
METHODS SUMMARY
C2C220256
ANALYTICAL PREPARATION
~P~ARAME==~T~E~R_,__ _____________________ METHOD ~ME=T~H~O~Dc_ ___ _
8270C (SIM). SW846 8270C SIM SW846 3520C
References:
SW846 "Test Methods for Evaluating Solid Waste, Physical/Chemical
Methods", Third Edition, November 1986 and its updates .
__________________________________________________ ,_
SAMPLE SUMMARY
C2C220256
WO# SAMPLE# CLIENT SAMPLE ID
EWT03 001 EFF/SV-305
NOTE(S}:
-The analytical results of the samples listed above are presented on the following pages.
-All calculations are performed before rounding co avoid round-off errors in calculated results.
-Results noted as "ND~ were not detected at or above the stated limit.
-This repon must not be reproduced, except in full, without the written approval of the laboratory.
-Results for the following parameters are never reported on a dry weight basis: color, corrosivicy, density, flashpoint, ignitability, layers, odor,
paim filter test, pH, porosity pressure. reactivity, redox potential, specific gravity, spot tests, solids. solubility, temperarure, viscosily, and weight.
SAMPLED
DATE
•
SAMF
TIME
03/21/02 09:3
•
•
Chain ot•
Custody Record
STL-4124 (1200)
Client~.__;
Address
'<DO go¼.< A...." ~i:e.... <! 0)., cch,'J~ I f\4 ! Zi~~;4 ~
. P~me and Locatir (Sta/ep .
0----z.,..e,r--'/? A 'fj-q\ _
ContracVPurchase Ordef!Quote No. I
Sample I.D. No. and Description Dale
(Containers for each sample may be combined on one line)
Ef-P/ s✓-)o~ 1ld')...
•
Possible Hazard Identification
D Non-Hazard D Flammable D Skin Irritant 0 PoisonB
ProjectM~r
\-c~ \50\..l....c..-l.-
Telephone Number (Area Code)/Fax Number
TI~ ~3, l-1<..I)..:}...
Site Contact Lab Contact
Carrier/Waybill Number
Containers & Matrix PreseNatives
Time i • 0 "' , ~,
li 1l 0 "' 0 G 0 qQ
~ • C ~ i; • ~~ < "' "' ~ , , ~
110 .'.)"' ~ ~
"
I Sample Disposal
C)(u~knawn O Return To Client ~sposa/ By Lab
SEVERN
TRENT • SERVICES' Severn Trent Laboratories, Inc.
. .
Date Chain of Custody Number
3' ? )__ 100845
Lab Number
Page I of\
Analysis (Attach fist if
more snace is needed
Special Ins/rue/ions/
Conditions of Receipt
~
~ ~
I 'i " •
(A fee may be assessed if samples are retained
0 Archive For Months longer than 3 months)
Tum Around Time ReqU1red
D 24 Hours D 48 Hours
' ( QC ReqU1rements (Specify)
D 7 Days 0 14 Days D 21 Days Time
2. Relinquished By 2. Received By Time
3. Relinquished By
Time
-7-oL -.
Comments
DISTRIBUTION WHITE -Stays with the Sample: CANARY -Returned to Client with Repon: PINK -Field Copy
---------------------------------------------------
THE RETEC GROUP INC
Client Sample ID: EFF/SV-305
GC/MS Semivolatiles
•
Lot-Sample# ... : C2C070316-001 Work Order# ... : EV4HD1AA
Date Received .. : 03/07/02
Analysis Date .. : 03/11/02
Matrix ......... : WATER
Date Sampled ... : 03/06/02
Prep Date ...... : 03/08/02
Prep Batch# ... : 2067163
Dilution Factor: l
PARAMETER
2,4·Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-dS
Terphenyl•dl4
2-Fluorobiphenyl
2·Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
MS Run# ....... :
Method ......... : SW846 8270C SIM
REPORTING
RESULT LIMIT UNITS
ND 0.20 ug/L
ND 1.0 ug/L
ND 0.20 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
57 (32 -].].2)
74 (10 -144)
58 (30 -ll0)
62 (].3 -110)
60 (l0 -ll3)
53 (21 -122) •
• METHOD BLANK REPORT
GC/MS Semivolatiles
Client Lot# ... : C2C070316 Work Order# ... : EV4XW1AA
MB Lot-Sample#: C2C080000-163
Analysis Date .. : 03/11/02
Dilution Factor: 1
PARAMETER
2,4·Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-d5
Terphenyl·dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
Prep Date ...... : 03/08/02
Prep Batch# ... : 2067163
REPORTING
RESULT LIMIT UNITS
ND 0.20 ug/L
ND l.O ug/L
ND 0.20 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
59 (32 -112)
73 (10 -144)
62 (30 -110)
69 (13 -110)
66 (10 -113)
59 (21 -122)
.NOTE(S):
Calculations are performed before rounding to avoid round-off errors in calculated results.
Matrix ......... : WATER
METHOD
SW846 8270C SIM
SW846 8270C SIM
SW846 82 70C SIM
LABORATORY CONTROL SAMPLE EVALUATION REPORT
GC/MS Semivolatiles
Client Lot# ... : C2C070316 Work Order# ... : EV4XW1AC-LCS
EV4XW1AD-LCSD
Analysis Date .. : 03/11/02
Matrix ......... : WATER
LCS Lot-Sample#: C2C080000-163
Prep Date ...... : 03/08/02
Prep Batch# ... : 2067163
Dilution Factor: 1
PERCENT RECOVERY RPD
PARAMETER RECOVERY LIMITS RPD LIMITS METHOD
Phenol 63 (10 -131) SW846 8270C SIM
62 (10 -.131) 1.8 ( 0-43) SW846 8270C SIM
Pentachlorophenol 40 (10 -140) SW846 8270C SIM
40 (10 -140) 1.2 ( 0-56) SW846 8270C SIM
2,4-Dichlorophenol 64 (42 -115) SW846 8270C SIM
63 (42 -115) 2.1 (0-44) SW846 8270C SIM
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Nitrobenzene-d5 66 (32 -112)
66 (32 -112)
Terphenyl-dl4 64 (10 -144)
64 (10 -144)
2-Fluorobiphenyl 61 (30 -110)
60 ( 30 -110)
2-Fluorophenol 67 (13 -110)
65 (13 -110)
Phenol-d5 63 (10 -113)
62 (10 -113)
2,4,6-Tribromophenol 67 (21 -122)
65 (21 -122)
NOTE (S) :
Calculations are performed before rounding to avoid round-off errors in calculated results.
•
•
•
•
•
•
ANALYTICAL REPORT
Raleigh, Biweekly NPDE·s
Lot#, C2C220256
Rita Baue.i:
The RETEC Group Inc
SEVERN TRENT LABORATORIES, INC.
Veronica· Bertot
Project Manager
March 27, 2002
STL Pittsburgh is a part of Severn Trent laboratories, Inc.
. .. -~
SEVE~.N
. STL Pittsburgh
450 William Pitt Way
Pittsburgh, PA 15238-1330
Tel: [phone]
Fax: [phone]
www.stl-inc.com
-------------------------------------------
Sample Receiving:
CASE NARRATIVE
THE RETEC GROUP
Raleigh, Biweekly NPDES
STL Lot# C2C220256
STL Pittsburgh, PA received one sample on March 22, 2002 in good condition. The
cooler was within the proper temperature range.
GC/MS Semivolatiles SIM:
Due to insufficient sample volume received and no other samples were in house to batch
this one with an LCS/LCSD were prepared and analyzed.
•
•
•
Chain of
Custody Record
STL-4124 (1200)
Client g .I' 1--"iA. __.I
-Address
3 Oo 12, Af l(t ,2,. Av-f :'.sr--f'. s o..;.t
City . I Slat,1-Zip COde Ca:i1J or, j /r1 fJ /_7 t./).
Project Name and Locr3/io(2$/aJZi
1 ~-1'.'&-Z-e< ,,, '1-,,, /I
Co11tracl/Purchase Or ,er/Quote No. '
Sample I. D. No. and Description Dale (Containers fo_r each sample may be combined on one line) .
EFF I .Sv-"30.1-3/~ ,I,)
Possible HazarrJ lde11/ification
D Non~!-lazard 0 Flammable 0 Skin Irritant D Poison 8
Project Manager . /ln,__.fJ~
Telephone Number (Area Code)/Fax Number
Cf 7 </ , 37 /-I t/:;J.;).
Site Contact Lab Contact
Carrier/Waybill Number
Containers & Matrix · Preserva/ives
i· .; • <n ~ b~ • 0 Time ti ~ "-<n 0 i3 0 ~o ¾ • bl § N ~ • ~~ ; <n ~ ~ ~ ~
{Yf]D )( rx
_ I Sample Disposal '
lslfunlmown D Return T ~ C1ient 1S1'oisposal By Lab
SE V,E It N
't'ltENT:
Sl!ftVICES -• I, Severn Trent Laboratories, Inc.
'
D~I~ ,/
Chain of Cus/ody Number
1 / ,l 106840
Lab Number ( l Page of
Analysis (Attach list if
more s,:;_ace is needed
Special Instructions/
Conditions of Receipt
-~ :] ~
)( ht
-·
(A fee may be assessed if samples are retained 0 Archive For Months longer than 3 months) Tum Around Tune Requued
D 24 Hours D 48 Hours sn QC Requirements (Specify)
14Days D 2/Days
I. Relinquished By
2. Refi11quisl1ed By
Time 1. R~ceived By
~\ {;01:;
Time 2. Received By
Date Time
Date Time
3. Relinquished By Time Date· Time
Comments 7-))-0) /:J.60
DISTRIBUTION: TE -Slays with the Sample; CANARY -Returned to Client with Report: PINK -Field Copy
__________________________________________________ ,_
THE RETEC GROUP INC
Client Sample ID: EFF/SV-305
GC/MS Semivolatiles
Lot-Sample# ... : C2C220256-001 Work Order# ... : EWT031AA
Date Received .. : 03/22/02
Analysis Date .. : 03/27/02
Matrix ......... : WATER
Date Sampled ... : 03/21/02
Prep Date ...... : 03/25/02
Prep Batch# ... : 2084355
Dilution Factor: l
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
MS Run# ....... :
Method ......... : SW846 8270C SIM
REPORTING
RESULT LIMIT UNITS
ND 0.20 ug/L
ND 1.0 ug/L
ND 0.20 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
84 (32 -112)
84 (10 -144)
76 (30 -110)
85 (13 -110)
92 (10 -113)
85 (21 -122)
•
•
•
• METHOD BLANK REPORT
GC/MS Semivolatiles
Client Lot# ... : C2C220256 Work'Order # ... : EWWRHlAA
MB Lot-Sample#: C2C250000-355
Analysis Date .. : 03/27/02
Dilution Factor: 1
PARAMETER
Pentachlorophenol
Phenol
2,4-Dichlorophenol
SURROGATE
Nitrobenzene·dS
--Terphenyl·dl4
2·Fluorobiphenyl
2·Fluorophenol
Phenol-dS
2,4,6·Tribromophenol
Prep Date ...... : 03/25/02
Prep Batch# ... : 2084355
REPORTING
RESULT LIMIT UNITS
ND 1.0 ug/L
ND 0.20 ug/L
ND 0.20 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
82 (32 -112)
84 (10 -144)
74 (30 -110)
83 (13 -110)
89 (10 -113)
84 (21 -122)
.0":E(S):
Calculations are performed before rounding to avoid round-off errors in calculated results.
•·
Matrix ......... : WATER
METHOD
SW846 82 70C SIM
SW846 8270C SIM
SW846 8270C SIM
---------------------------------------------------. .
LABORATORY CONTROL SAMPLE EVALUATION REPORT •
GC/MS Semivolatiles
Client Lot# ... : C2C220256
LCS Lot-Sample#: C2C250000-355
Work Order# ... : EWWRHlAC-LCS
EWWRHlAD-LCSD
Analysis Date .. : 03/27/02
Matrix ......... : WATER
Prep Date ...... : 03/25/02
Prep Batch# ... : 2084355
Dilution Factor: 1
PARAMETER
Phenol
Pentachlorophenol
2,4-Dichlorophenol
SURROGATE
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
NOTE(S):
PERCENT
RECOVERY
74
75
74
75
78
81
RECOVERY
LIMITS
(10 -131)
(10 -131)
(10 -140)
(10 -140)
(42 -115)
(42· -115)
PERCENT
RECOVERY
68
70
69
71
61
65
69
70
75
77
71
75
Ca!culations are perfonned before rounding to avoid round-off errors in calculated results.
RPD
RPD LIMITS METHOD ---SW846 8270C SIM
2.5 (0-43) SW846 8270C SIM
SW846 8270C SIM
2.2 (0-56) SW846 8270C SIM
SW846 8270C SIM
4.0 (0-44) SW846 8270C SIM
RECOVERY
LIMITS
(32 -112)
(32 -112)
(10 -144)
(10 -144) • (30 -110)
(30 -110)
(13 -110)
(13 -110)
(10 -113)
(10 -113)
(21 -122)
(21 -122)
•
••
•
March 7, 2002
Ms. Beverly Hudson
Remedial Project Manager
U.S. EPA -Region IV, 11th Floor
North Site Management Branch
61 Forsyth Street, SW
Atlanta, GA 30303
RE: Monthly Progress Report #106
Remedial Action
Koppers Site -Morrisville, NC
Dear Ms. Hudson:
The RETEC Group, inc.
300 Baker Avenue, Suite 302
Concord, MA01742
RETEC
[phone] Phone
[phone] Fax
www.retec.com
_;,;ON
In accordance with the Unilateral Order, and on behalf of Beazer East, Inc. (Beazer), please find attached
four (4) copies of the January Monthly Progress Report for Remedial Action at the Koppers Superfund
Site in Morrisville, NC. No exceedances occurred during this event.
Should you need additional inforrnation regarding this progress report, please call Mike Helbling at (412)
208-8858 or me at [phone].
Sincerely,
The RETEC Group, Inc.
r/41.Afi--~ ,d..,,{P, (s
~i~a Bauer l ·
Project Geologist
RB:mvc
Enclosure
/
cc: lDc-Mattiso;:-NC.Superfund (2copiesf)
L. Faulconer -Wake County
G. Caskey -Enwood Structures
M. Helbling -Beazer
F:\PROJECTS\03624\Rcports\Monthly\2002\2M-02.doc
Peter Sullivan
Project Engineer
D. Hails -Ecological Restoration, Inc.
J. Garrett -NC Division of Water Quality
D. Matthews -NC Div. of Waste Management
P. Kilchenstein -RETEC
•
•
•
MONTHLY PROGRESS REPORT #106
REMEDIAL ACTION
SITE NAME: Koppers Superfund Site
Beazer East, Inc.
Morrisville, NC
USEPA DOCKET NUMBERS: 93-09-C
PERIOD ENDING: February 28, 2002
1. PROGRESS MADE THIS MONTH
2.
3.
4.
5.
6.
Remedial Action (RA) -HABITAT MITIGATION. No activities were conducted this
month.
Remedial Action (RA) -GROUNDWATER TREATMENT. The treatment system
operated throughout the month without upset. System performance was monitored on a
biweekly basis. Approximately 35,290 gallons of groundwater were extracted, treated in
the treatment plant and discharged between February 1, 2002 and February 28, 2002.
System water samples were collected on February 7, 2002 and February 19, 2002 in
accordance with the sampling schedule in the O&M manual. Samples were submitted to
Severn Trent for laboratory analysis. The operations and sampling programs are
summarized on the attached Table 1.
Remedial Action (RA) -EFFECTIVENESS MONITORING PROGRAM. No activities
were conducted this month.
Remedial Action (RA) -CORRESPONDENCE. None.
PROBLEMS RESOLVED
PROBLEMS ANTICIPATED
UPCOMING EVENTS
PERSONNEL CHANGES
SUBCONTRACTORS
None.
None.
Continue System O&M.
None.
None.
7. ANALYTICAL DATA Analytical data from system influent and effluent sampling
received during this period are enclosed and are summarized on Table 2 .
F:IPROJECTSI03624\Reports\Monthlyl200212M-02.doc
•
•
Parameter
Pentachlorophenol
2.4-Dichlorophenol
Phenol
Chronic Toxicity
Dioxin (2,3,7,8-TCDD)
Table 2
Groundwater Treatment
ANALYTICAL DATA SUMMARY
Koppers Superfund Site
Analytical
Date Sample
Sample Location
Collected SV-101
01/10/02
01/23/02 6.2
02/07/02
02/19/02
01/10/02
01/23/02 <0.20
02/07/02
02/19/02
01/10/02
01/23/02 <0.20
02/07/02
02/19/02
01/23/02
01/23/02 <2.6
Notes: All results are in ug/L except dioxin. Dioxin data is in picograms/L.
SV-101 -Before Carbon Units
•sV-304 -Between Carbon Units
*"SV-305 -After Carbon Units
F:\Projects\03624\Reports\Monthly\2M-02 Table 2
Sample Sample
Location Location
SV-304• SV-305 ..
<1.0
<1.0 <1.0
<1.0
<1.0
<0.20
<0.20 <0.20
<0.20
<0.20
<0.20
<0.20 <0.20
<0.20
<0.20
Pass
<1.5
Date Systems Cummulative SV-101
Check Effluent Flow Sample
(yes/no) (Gallons, tves/no'
01/10/02 ves 3 251 280 no
01/23/02 ves 3 264 850 ves
02107/02 ves 3 283 240 no
02/19/02 ,es 3 300 140 no
Notes:
•
Table 1
Groundwater Treatment Operations and Sampling Program Summary
Koppers Superfund Site
Morrisville, North Carolina
February 2002
SV-101 Associated SV-304 SV-304 Associated
Sample Group Sample Sample Group
Parameters fvesfno) Parameters
no
Penta 2 4-Dichloro. Phenol Dioxin 1 2 ves Penta 2 4-Dichloro Phenol 1
no
no
Associated Groups:
SV-305
Sample
lves/no1
ves
ves
,es
,es
SV-101 -Group 1 is penta and 2,4-dichlorophenol; Group 2 is dioxin
SV-304 -Group 1 is penta and 2,4-dichlorophenol
•
SV-305
Sample
Parameters
Penta 2 4-Dichloro Phenol
Penta, 2,4-Dichloro, Phenol, Dioxin, Chronic
Tox
Penta 2 4-Dichloro Phenol
Penta, 2,4-Dichloro, Phenol
Sampling point SV-101 is located before the Carbon Units (pretreatment)
Sampling point SV-304 is located between the Carbon Units
Sampling point SV-305 is Iodated after the Carbons Units (post-treatment) SV-305 -Group 1 is penta, phenol, and 2,4-dichlorophenol; Group 2 is dioxin and Group 3 is chronic toxicity
NR -Not recorded
f:\Projecta\Ol624\Reports\Monlhfy\2M-02 Tat>le 1
Associated
Group
1
1 2 3
1
1
•
•
ANALYTICAL REPORT
Raleigh, Biweekly NPDES
Lot#, C2B080233
Rita Bauer
ThermoRetec Corp
SEVERN TRENT LABORATORIES, INC.
February 14, 2002
STL Pittsburgh is a part of Severn Trent Laboratories. Inc.
STL Pittsburgh
450 William Pitt Way
Pittsburgh, PA 15238-1330
Tel: [phone]
Fax: [phone]
www.stHnc.com
____________________________________________ ,_
Sample Receiving:
CASE NARRATIVE
THE RETEC GROUP
Raleigh, Biweekly NPDES
STL Lot# C2B080233
STL Pittsburgh, PA received one sample on February 4, 2002 in good condition. The
cooler was within the proper temperature range.
GC/MS Semivolatiles SIM:
There were no problems associated with the analysis.
•
•
•
iffl~•»iliiiliil'alilill
Chain of
Custody Hecord
Sample /.0_ No. and Description Date Time
~!;,;fa, Inc. -Piltsbu,PA Lab
450 William Pill Way
Pittsburgh PA 15238
Sample Type
•
-.J _'-l.,+---+--l-+-+--+--+--+--1-fl· -
--------------------------1-----+---+-----+-----t----+-+-----+--------+-t-+-+--l-----·---·· ····---·---·· ---
-----------------1--1----+----l-----+----+---t--+----+-------+--+--+--l-+--+--+--I-+-+--+--+-
--------.. -·-· -------+----1---+----+----+----+-+------+-------+-t-+-+-+-t-+-+-+-t-+--+--
------·------·------+----t--+----+----+----+-+-----+-------+-t-+-+-+-t-+-+-+~t-+--+--
---------------·---·-----+-----+--+-----+----+----1---'l-----t--------t-+-+-+-+-+--t--t-+-+-+--+--
---·---------··· --·· . ·---·-·----- ------------t------t---t-------t-----+-----t~-t------t---------+--+-+--+-+---+-+---t--+---tt--t---tt--
-----------------·--------t------+---+-------+------tf-----i---+------t---------t--+---+-+--+--+---+---t--+---+-+--+--
····--··-·-------+------+---•------1------+-----+---+-----+----------t--+--!---+-!----l--!---I--+--+-+--+--
Special lnstrt1c/1~11s
Date Time
DISTRIBUTJON: Wf-fl7E · 5tilys 1v1!h Sample; CANARY -Returned to Client with Report; PINK. Field Copy
r------------------------------,-
MEIBODSSUMMARY
C2B080233
ANALYTICAL PREPARATION _P_ARAME __ ~T_E_R ______________________ METHOD _ME_T_H_O_D ____ _
8270C (SIM) SW846 8270C SIM SW846 3520C
References:
SW846 "Test Methods for Evaluating Solid Waste, Physical/chemical
Methods", Third Edition, November 1986 and its updates.
•
•
•
•
•
SAMPLE SUMMARY
C2B080233
WO# SAMPLE# CLIENT SAMPLE ID
ETV4Q 001 SYSEFF/SV-305
NOTE (S) :
-The analytical results of the samples listed above are presented on the following pages.
-All calculations are performed before rounding 10 avoid round-off errors in calculated resulu.
-Ri:.sults noted ;is '':-ID" were nOL detec1et.l :11 or above th~ SLatcxl limit.
• Thi~ report must not be reproduced, e:-:.ce;it in full. without the writ1en approv;i! of the 1:iboratory.
-Result5 for the following parameter. are never reported on a dry weight b~sis: color, corrosiviry, density, flashpoint, ignitability, layers. odor,
paint filter test, pH, porosity pres.sure, reactivity, redox potential, specific gravity. spot testS, solids, solubility, temperature, viscosity. and weight.
SAMPLED
DATE
SAMP
TIME
02/07/02 10:05
~----------------------------------
THE RETEC GROUP INC
Client Sample ID, SYSEFF/SV-305
Lot-Sample# ... , C2B080233-001
Date Sampled ... , 02/07/02
Prep Date ...... , 02/11/02
Prep Batch# ... , 2042291
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-dS
2,4,6-Tribromophenol
GC/MS Semivolatiles
work Order# ... , ETV4QlAA
Date Received .. , 02/08/02
Analysis Date .. , 02/13/02
Matrix ......... : WATER
MS Run# ....... :
Method ......... , SW846 8270C SIM
REPORTING
RESULT LIMIT UNITS
NO 0.20 ug/L
NO l.O ug/L
NO 0.20 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
72 (32 -112)
64 (10 -144)
62 (30 -110)
66 (13 -110)
71 ( 10 -113)
70 (21 -122 I
•
•
•
•
•
•
Client Lot# ... , C2B080233
MB Lot-Sample#, C2B110000-291
Analysis Date .. , 02/13/02
Dilution Factor: l
Pl'.RAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-ds
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
NOTE(S),
METHOD BLANK REPORT
GC/MS Semivolatiles
Work Order # ... ' ETXQTlAA
Prep Date ...... , 02/11/02
Prep Batch# ... , 2042291
REPORTING
RESULT LIMIT UNITS
ND 0.20 ug/L
ND 1.0 ug/L
ND 0.20 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
56 (32 -112)
55 (10 -144)
47 (30 -110)
53 (13 -110)
60 (10 -113)
63 (21 -122)
Calculations are performed before rounding 10 avoid round-off errors in ca!cularcd results .
Matrix ......... : WATER
METHOD
SW846 8270C SIM
SW846 8270C SIM
SW846 8270C SIM
------------------------------------------------------
LABORATORY CONTROL SAMPLE EVALUATION REPORT
GC/MS Semivolatiles
Client Lot# ... : C2B080233 Work Order# ... , ETXQTlAC-LCS
ETXQTlAD-LCSD
Analysis Date .. , 02/13/02
Matrix ......... , WATER
LCS Lot-Sample#, C2Bll0000-291
Prep Date ...... , 02/11/02
Prep Batch# ... , 2042291
Dilution Factor: 1
PERCENT RECOVERY RPO
PARAMETER RECOVERY LIMITS RPD LIMITS METHOD
Phenol 58 (10 -131) SW846 8270C SIM
61 (10 -131) 5.8 ( 0-43) SW846 8270C SIM Pentachlorophenol 98 (10 -140) SW846 8270C SIM
95 (10 -140) 2.4 (0-56) SW846 8270C SIM
2,4-Dichlorophenol 59 (42 -115) SW846 8270C SIM
62 (42 -115) 4.7 (0-44) SW846 8270C SIM
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Nitrobenzene-dS 63 (32 -112)
66 (32 -112)
Terphenyl-d14 58 (10 -144)
59 (10 -144)
2-Fluorobiphenyl 53 (30 -110)
55 (30 -110)
2-Fluorophenol 60 (13 -110)
63 (13 -110)
Phenol-d5 62 (10 113)
64 (10 -113)
2,4,6-Tribromophenol 69 (21 -122)
70 (21 -122)
NOTE(S),
Calculations are performed before rounding to avoid round-off errors in calculated results.
•
•
•
•
•
•
ANALYTICAL REPORT
Raleigh, Biweekly NPDES
Lot#: C2B200214
Rita Bauer
TherrnoRetec Corp
SEVERN TRENT LABORATORIES, INC .
February 26, 2002
STL Pittsburgh Is a part of Severn Trent Laboratories, Inc.
STL Pittsburgh
450 William Pitt Way
Pittsburgh, PA 15238-1330
Tel: [phone]
Fax: [phone]
Wl¥','(.s1Hnc.com
---------------------------------------------
Sample Receiving:
CASE NARRATIVE
THE RETEC GROUP
Raleigh, Biweekly NPDES
STL Lot# C2B200214
STL Pittsburgh, PA received one sample on February 20, 2002 in good conrution. The
cooler was within the proper temperature range.
GC/MS Semivolatiles SIM:
There were no problems associated with the analysis.
•
•
•
•
•
METHODS SUMMARY
C2B20021.4
ANALYTICAL PREPARATION
PARAMETER METHOD ~ME=T~H~O=D ____ _
8270C (SIM) SW846 8270C SIM SW846 3520C
References:
SW846 11 Test Methods for Evaluating Solid waste, Physical/Chemical
Methods11 , Third Edition, November 1986 and its updates .
____________________________ ,_
SAMPLE SUMMARY
C2B200214
WO# SAMPLE# CLIENT SAMPLE ID
EVDNR 001 SYSEFF/SV-305
NOTE (S):
• The analytic:1.I results of the samples listed above are prcsemed on the following pages.
-All calculations are perfonncd before rounding to avoid round-off errors in calculated results.
-Results noted as "ND" were not dctecu:d at or above the stated limit.
• This report must not be reproduced. except in full, without the wriuen approval of the lahor:110~.
• Results for the following parameters arc never reported on a dry weight basis: color, corrosivity. density, flashpoint, ignitability, layers, odor,
paint filter test. pH, porosity pressure, reactivity, redox potential, specifi':_ gravity, spot tests, solids, solubility, temperature, viscosity, and weight.
SAMPLED
DATE
•
02/19/02 13: 50
•
•
.... .-ten•51W,AHI
Chain of
Custody Recorcf
Client () --~·--\'--.!I. Jl.c,
Address \ .. ~ ~ .. ·-)
--Jjo 1=✓,._ "~-• h,,1,1. ~-., 30;;_ c ,\ (".jV'\ cc.rr lmA l'bc~~ '-' ~
~rc,/ccl Name and Lo:-·u\°'Jf /a/el & a<?."'-I ' -i l_ ,11~ k (),_) (_
Contrac.t/Purchese Ome}l.:;tuote fJc,
SJmple UJ. Nci. and Dascrip/ion Date (CG/1/iJmers lo, uacii sampfa ma:,· be combined on one· line)
s c., • I \v ----.• ~£.=,== '..) -":'.i:iS ~, 'O\ \.).
' '
Poss ibid I taz¥d ldentiii::aric,n
D Nan-Hazard D Flammable D $kin Irritant D Poison B
•
Project 2 ger
n-fj. ~ , . n •f
Telephone Number (Area Code)lFax Number
lc'.:\7'"6---s11 -\ <-{ )... "";)_
Site Contact Lab Contact
CarrierNlaybi/1 Number
Containers & 'f2 "; Matrix PreseNatives
; • 0 ~ , ", ~ ~ nma ! ~ @ ~ 0 G 0 sO ~ 1l ~ , ~ ~~ ~
' ~ 0 r r r
/~O (', IA r-11'
.
I Sample Disposal
~nkno~n D Return To Client OOoisposal By Lab D Archive For
Tum Aro11nd Time R<"', :1ir<:;d ' ( C Re uirements S eci
0 24 llours D 7 Days D 14 Days D 21 Days
1. Relinquishe
3. Refmquished By
Commen/s
DISTRIBUTION: W/-fl rE. Suys with me Sample: CANARY. Returned to Client with Report PINK -Field Copy
•
Severn Trent Laboratories, Inc.
Date 10.I ")_ Chain oflso"lt§1o O «.
Lab Nllmber \ ~ Page of
Analysis (Attach list if
more soace is needed)
Special Instructions/
Conditions of Receipt
.
(A fee may be assessed it samples are retained
Months longer than 3 months)
Time
Time
Time
---------------:------------------------------------,-:--
THE RETEC GROuP INC
Client Sample ID: SYSEFF/SV-305
GC/MS semivolatiles
Lot-Sample# ... : C2B200214-001 Work Order # ••• : EVDNRlAA
Date Received .. : 02/20/02
Analysis Date .. : 02/25/02
Matrix ......... : WATER Date Sampled ... : 02/19/02
Prep Date ...... : 02/21/02
Prep Batch# ... : 2052220
Dilution Factor: l
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-d5
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribrornophenol
MS Run # •.•.•.. : 2052100
Method ......... : SW846 8270C SIM
REPORTING
RESULT LIMIT UNITS
ND 0.20 ug/L
ND 1.0 ug/L
ND 0.20 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
58 (32 -112)
64 (10 -144)
57 (30 -110)
53 (13 -110)
61 (10 -113)
74 (21 122)
•
•
•
•
Client Lot# ... : C2B200214
MB Lot-Sample#: C2B210000-220
Analysis Date .. : 02/25/02
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-ds
Terphenyl-d14
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
NOTE (S) :
MllTIIOD BLANK REPORT
GC/MS Semivolatiles
Work Order # ••• : EVEPPlAA
Prep Date ...... : 02/21/02
Prep Batch# ... : 2052220
REPORTING
RESULT LIMIT UNITS
ND 0.20 ug/L
ND 1.0 ug/L
ND 0.20 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
61 (32 -112)
60 (10 -144)
53 (30 -110)
58 (13 -110)
60 (10 -113)
61 (21 -122)
Calculations are performed before rounding to avoid round..off errors in calculated results,
Matrix ......... : WATER
METHOD
SW846 8270C SIM
SW846 8270C SIM
SW846 8270C SIM
-----------------------------------------------------i--
LABORATORY CONTROL SAMPLE EVALUATION REPORT
GC/MS Semivolatiles
Client Lot# ... : C2B200214 Work Order# ... : EVEPPlAC
LCS Lot-Sample#: C2B210000-220
Prep Date ...... : 02/21/02 Analysis Date .• : 02/25/02
Prep Batch# ... : 2052220
Dilution Factor: 1
PARAMETER
Phenol
Pentachlorophenol
2,4-Dichlorophenol
SURROGATE
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
NOT8 (S) :
PERCENT
RECOVERY
56
53
58
RECOVERY
LIMITS
(10 -131)
(10 -140)
(42 -115)
PERCENT
RECOVERY
60
63
55
55
57
67
Calculations are performed before rounding to avoid round-o!T errors in calcula1ed results.
Matrix ......... : WATER
METHOD
SW846 8270C SIM
SW846 8270C SIM
SW846 8270C SIM
RECOVERY
LIMITS
(32 112)
(10 -144)
(30 -110)
(13 -110)
(10 -113)
(21 -122)
•
•
•
•
•
MATRIX SPIKE SAMPLE EVALUATION REPORT
GC/MS Semivolatiles
Client Lot# ... : C2B200214
MS Lot-Sample#: C2B200218-014
Work Order # ..• : EVDQAlAC-MS
EVDQAlAD-MSD
Date Received .. : 02/20/02
Analysis Date .. : 02/26/02
Date Sampled ... : 02/19/02
Prep Date ...... : 02/21/02
Prep Batch# ... : 2052220
Dilution Factor: 1
PERCENT RECOVERY RPD
Matrix ......... , WATER
MS Run# ....... , 2052100
PARAMETER RECOVERY LIMITS RPO LIMITS METHOD
Phenol 53 (10 -131) SW846 8270C SIM
57 (10 -131) 7.7 (0-43) SW846 8270C SIM Pentachlorophenol 130 (10 -140) SW846 8270C SIM
133 (10 -140) 0.88 (0-56) SW846 8270C SIM 2,4-Dichlorophenol 59 (42 -115) SW846 8270C SIM
61 (42 -115) 3.9 (0-44) SW846 8270C SIM
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Nitrobenzene-ds 62 (32 -112)
65 (32 -112)
Terphenyl-dl4 57 (10 -144)
58 (10 -144)
2-Fluorobiphenyl 55 (30 -110)
57 (30 -110)
2-Fluorophenol 57 (13 -110)
61 (13 -110)
Phenol-d5 57 (10 -113)
60 (10 -113)
2,4,6-Tribromophenol 68 (21 -122)
70 (21 -122)
NOTE(S),
Calculations are performed before rounding to avoid round-off errors in calculated results.
Effluent Toxicity Report Form -Chronic Pass/Fail and Acute LCSO Date: 02/08/02
NPDES#: NC Pipe#: County: WAKE
boratory Performing Test: TRITEST, INC.
Comments:
x~,,,,',=itccc=c=---,s=::-±=c-,c=--;s-::====""===-=------1. Respons1.
X
ry Supervisor
0201-01339
MAIL ORIGINAL TO:
* PASSED: 9.77% Reduction*
Environmental Sciences Branch
Div. of Environmental Management
N.C. Dept. of EHNR
4401 Reedy Creek Road
North Carolina Ceriodaphnia Raleigh, North Carolina 27607-6445
Chronic Pass/Fail Reproduction Toxicity Test Chronic Test Results
CONTROL ORGANISMS 1 2 3 4 5 6 7 8
# Young Produced 29 27 30 33 25 30 31 27
Adult (L) ive (D) ead L L L L L L L L
Effluent %: 90%
TREATMENT 2 ORGANISMS 1 2 3 4 5 6 7 8
# Young Produced 25 28 27 27 28 23 24 19
.dult (L)ive (D) ead L L L L L L L L
1st sample 1st sample 2nd sample
pH
Control
Treatment 2 ~ ~ [E8B3
s s s
t e t e t e
a n a n a n
r d r d r d
t t t
1st sample 1st sample 2nd sample
D.O.
Control
Treatment 2 ~ ~ ~
Calculated t = 2.529
Tabular t = 2.508
9 10 11 12 % Reduction= 9. 77
% Mortality Avg.Reprod.
29 29 32 26
0.00 29.00
Control Control
L L L L
0.00 26.17
Treatment 2 Treatment 2
9 10 11 12 Control CV
8.318% PASS FAIL
26 30 29 28 % control orgs ~c
L
producing 3rd
brood Check One
L L L 100%
Complete This For Either Test
Test Start Date: 01/23/02
Collection (Start) Date
Sample 1: 01/22/02 Sample 2: 01/24/02
Sample Type/Duration
1st
Grab Comp. Duration D
I S
Sample 1 X 24 hrs L A
>---1-----4----~ U M
Sample 2 X 24 hrs T P
2nd
P/F
s
A
M p
'---'----'----r-'-----------J
Hardness (mg/1) 50 ........ ..
f---+---+-----J
Spec. Cond. (~mhos) 200 871 846
------+----'---~
Chlorine (mg/1)
>---+---+-----J <0.1 <0.1
LC50/Acute Toxicity Test Sample temp. at receipt('C) 0.9 1.3
(Mortality expressed as%, combining replicates)
LC50 _____ %
95% Confidence Limits
% - -% •
Concentration
Mortality
start/end
Method of Determination
Moving Average Probit
Spearman Karber Other
pH
Organism Tested: Ceriodaphnia dubia Duration(hrs): I
Copied from DEM form AT-1 (3/87) rev. 11/95 (DUBIA ver. 4.32)
I
Note: Please
Complete This
Section Also
start/end
D.O.
-! .,,, ____,, ~~C) 1 -() I 33 o/
.
....
TRITEST, INC. • Bioassay Chain of Custody Form
Bioassays are to be sampled after 8:30a.m. on
Tuesday & Friday.
Facility Name: BG4~ UAv£1 t-1/ I
Address: Joo /}Aµ:£/'~ Aef . .f'v11£ • Jc2-P.O.#:
{o rv Co;?,,!) . /YJA 0171./2-I Phone# ( 'l7 S' ) Jl/-/'/2-7-
, ffU/'11 Q 1!£.r.e:.c.-Contact: !ZITA fl A v,£,.,{:?_
County: lvAfL..c.. Outfall/ Pipe# : -NPDES Permit#: AtJ1"11/\J, t.£7r~
%Effluent Dilution : (1) Test Method : Cl/4.oN IC , To?<, I
Sample Site Description: .S /'.'.ST~ £-Fr.
Sample Collector: . Print> ~,(iJV'-~:\]
Signature> ~J M\=
Sample Type: Composite : \(~._ l ;,_ Date Started : Time: 09ov @or PM
Date Ended: ~?>~ Time : ff'!OV (AM)or PM
Samples per Hour : I #Hours: ,;2.. '/
Grab:
--Date: Time: AM or PM
Sample Volume: .;2.. l..(T,?=,0 ( Chilled during Collection? t.6'
Method of Transportation to Lab : HANO /J£L I ~
♦ ♦ I t ♦ t ♦ ♦ t ♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦ Chain of Custody Release ••••••••••••••••••••••••• .
Relinquished By • Date Time Recei_ved Bv Dat< Time
I ' ' ' ;I J ,111.:,..-,,,\ ':\:. -<1. • . "17 A. /I~;;,: II : 0-:0 •
For Laboratory Use Only
f).o/ oL---_eJ'. . Receiving Temperature: By:~
Residual Chlorine: Number of Bottles: •
Address: 3909Beryl Rd.-Raleigh, NC 27607 Phone(9!9) 834 -4984 Fax [phone]
I
-
•
•
•
TRITEST, INC .
Bioassay Chain of Custody Fonn
Bioassays are to be sampled after 8:30a.m. on
Tuesday & Friday.
FacilityName: B@:z4i4--/£(£;6# I
Address: Joo iJ,4~
(orvCo/4/) , ;YJA
Ave , Iv 11£ • P.O.#'-------'------
. ' 00 1-12-Phone# ( '118 J 7 1-I '(2-7-
Tf/-llcao /!£re::c.-Contact : £ /TA I] .4 v~
County : lv f'1L£, Outfall/Pipe#: _____ NPDESPermit#: A/J1"11/\J, t.,f]T44:--
%Effluent Dilution : (12 Test Method: Cl/fZoNI C , 10;<,
Sample Site Description·: S)'..fT&Y\. /£Fr.
Sample Collector: ,Print> ftoJot1-~(I( Qc,Ar'.'::'. Signature> JP
Sample Type: Composite:
Date Started : /~J 4);~ Time: ~ J-o ®r PM
Qate Ended: i l ., /.-Time: O"l}o (OOor PM '
Samples per Hour : # Hours.: .,,2.y
Grab:
Date: Time: AM or PM
Sample Volume: ,;;;._ t...r,F-,0 ( Chilled during Collection? !'.6
Method of Transportation to Lab : HArvO ti£!, r ~
•••••••••••••••••••••••••• Chain of Custody Release . ••••••••••••••••••••••••••
Re lOQU[S e IV hdB Date Time R eceive d Bv Date Time . "~ .1;1-~ Jll Y 1<1 J 11'100 .1,'f'V• ,,.~ ,/2,,SIO" I /1 •','._
u
For Laboratory Use Only /) "C vf Receiving Temperature: ___ \:.;'c.....:'J _______ By: __ .,_a.J.-f!>'"--------
r/ Residual Chlorine: ___ 11.,_e.::..j'l---·-------Number ofBottles: _..:.."'1-'-----
Address: 3909-Beryl Rd.· Raleigh, NC 27607 Phone[phone] Fax [phone]
• February 7, 2002
Ms. Beverly Hudson
Remedial Project Manager
U.S. EPA-Region IV, 11th Floor
North Site Management Branch
61 Forsyth Street, SW
Atlanta, GA 30303
RE: Monthly Progress Report #105
Remedial Action
Koppers Site -Morrisville, NC
Dear Ms. Hudson:
-\ -ri '( (?-. ,,-t,kr
0 The RETEC Group1 inc.
300 Baker Avenue, Suite 302
Concord, MA01742
[phone] Phone
[phone] Fax
www.retec.com
In accordance with the Unilateral Order, and on behalf of Beazer East, Inc. (Beazer), please find attached
four (4) copies of the January Monthly Progress Report for Remedial Action at the Koppers Superfund
Site in Morrisville, NC. No exceedances occurred during this event.
Should you need additional information regarding this progress report, please call Mike Helbling at
[phone] or me at [phone].
• Sincerely,
•
Tho RETEC5:';, ill,. ~ ·~~
Project Geologist ,
RB:mvc
Enclosure
cc: D. Mattison -NC Superfund (2 copies)
L. Faulconer -Wake County
G. Caskey -Enwood Structures
M. Helbling -Beazer
F :\PR OJ ECI'S\03 6 24 \R cports\M on th I y\2002\ 1 M-02 .doc
Peter Sullivan
Project Engineer
D. Hails -Ecological Restoration, Inc.
J. Garrett -NC Division of Water Quality
D. Matthews -NC Div. of Waste Management
P. Kilchenstein -RETEC
·'
•
•
•
MONTHLY PROGRESS REPORT #105
REMEDIAL ACTION
SITE NAME: Koppers Superfund Site
Beazer East, Inc.
Morrisville, NC
USEPA DOCKET NU!VIBERS: 93-09-C
PERIOD ENDING: January 31, 2002
1. PROGRESS MADE THIS MONTH
2.
3.
4.
5.
6.
Remedial Action (RA) -HABITAT MITIGATION. No activities were conducted this
month.
Remedial Action (RA) -GROUNDWATER TREATMENT. The treatment system
operated throughout the month without upset. System performance was monitored on a
biweekly basis. Approximately 29,630 gallons of groundwater were extracted, treated in
the treatment plant and discharged between January 1, 2002 and January 31, 2002.
System water samples were collected on January 10, 2002 and January 23, 2002 in
accordance with the sampling schedule in the O&M manual. Samples were submitted to
Severn Trent for laboratory analysis. The operations and samp_Iing programs are
summarized on the attached Table 1.
Remedial Action (RA) -EFFECTIVENESS MONITORING PROGRAM. No activities
were conducted this month.
Remedial Action (RA) -CORRESPONDENCE. None.
PROBLEMS RESOLVED
PROBLEMS ANTICIPATED
UPCOMING EVENTS
PERSONNEL CHANGES
SUBCONTRACTORS
None.
None.
Continue System O&M.
None.
None.
7. ANALYTICAL DATA Analytical data from system influent and effluent sampling
received during this period are enclosed and are summarized on Table 2 .
F: \PRO J ECTS\O 3 624 \Repons\Mon th I y\2002\ I M -02 .doc
•
Table 1
Groundwater Treatment Operations and Sampling Program Summary
Koppers Superlund Site
Date Systems vummulat1ve •-.>Y-101 ..... -101
Check Effluent Flow Sample Sample
(yes/no) (Gallons) (yes/no) Parameters
01/10/02 ves 3,251,280 no
01/23/02 ves 3,264,850 ves Penta, 2,4-0ichloro, Phenol, Dioxin
Notes:
Sampling point SV-101 is located before the Carbon Units (pretreatment)
Sampling point SV-304 is located between the Carbon Units
Morrisville, North Carolina
January·2002
n<>SOciatec vv•304 vv-304 Associatea vv-305
Group Sample Sample Group Sample (yes/no) Parameters (yes/no)
no ves
1, 2 ves Penta, 2,4-0ichloro, Phenol 1 ves
Associated Groups:
SV-101 • Group 1 is penta and 2,4-dichlorophenol; Group 2 is dioxin
SV-304 -Group 1 is penta and 2,4-dichloropheno!
;:,v-305
Sample
Parameters
Penta, 2,4-Dichloro, Phenol
Penta, 2,4-Dichloro, Phenol, Dioxin
Sampling point SV-305 is loctated after the Carbons Units (post-treatment) SV-305 -Group 1 is penta, phenol, and 2,4-dichlorophenol; Group 2 is dioxin and Group 3 is chronic toxicity
NA -Not recorded
F;IProjectsVXl6241Reponsl.V,o~hly,1M-02 Table 1
•
Associated
Group
1
1, 2
•
•
•
Parameter
Pentachlorophenol
2.4-Dichlorophenol
Phenol
Chronic Toxicity
Dioxin (2,3,7,8-TCDD)
Table 2
Groundwater Treatment
ANALYTICAL DATA SUMMARY
Koppers Superfund Site
Morrisville, North Carolina
January 2002
· Analytical
Date Sample
Sample Location
Collected SV-101
01/10/02
01/23/02 6.2
01/10/02
01/23/02 <0.20
01/10/02
01/23/02 <0.20
CTS
01/23/02 <2.6
Notes: All results are in ug/L except dioxin. Dioxin data is in picograms/L
SV-101 -Before Carbon Units
"SV-304 -Between Carbon Units
--sv-305 -After Carbon Units
CTS -quarterly Chronic Toxicity Sampling yet to be perfonned
F:\Projects\03624\Reports\Monthly\ 1 M-02 Table 2
Sample Sample
Location Location
SV-304* SV-305**
<1.0
<1.0 <1.0
<0.20
<0.20 <0.20
<0.20
<0.20 <0.20
<1.5
•
•
•
ANALYTICAL REPORT
Raleigh, Biweekly NPDES
Lot~, C2All02ll
Rita Bauer
ThermoRetec Corp
SEVERN TRENT LABORATORIES, INC.
f ///' /:!.
ra1J!//p/!nrblfa6
Veronica Bortot.
Project Manager
January l8, 2002
STL Pittsburgh is a part of Severn Trent Laboratories, Inc.
STL Pittsburgh
450 William Pitt Way
Pittsburgh, PA 15238-1330
Tel [phone]
Fax: [phone]
wvvw,stl-inc.com
---------------------------------------------
Sample Receiving:
CASE NARRATIVE
THE RETEC GROUP
R.aleigh, Biweekly NP DES
STL Lot ii C2AI 10211
STL Pittsburgh, PA received one sample on Janua1·y 11, 2002 in good condition. The
cooler was within the proper temperature range.
GC/MS Semivolatiles SIM:
There were no problems associated with the analysis.
•
• •
•
•
METHODS SUMMARY
C2All02ll
ANALYTICAL PREPP,RATION
PARAMETER ME7!JQD METHOD =~=~----
8270C (SIM) SW846 8270C SIM SW846 3520C
References:
SW846 11 Test Methods for Evaluating Solid Waste, Physical/Chemical
Methods 11 , Third Edition, November 1986 and its updates .
------------------------------------------------------------------,-
SAMPLE SUMMARY
C2A110211
NO # S.il.MPLE# CLIENT SP.J-,'IDL3 ID
ERJJ0 001 SYSEFF/SV-305
NOTE (S) ,
-The :i.nalytic:i! results of the samples lbteJ lbuvc :.ire prescrned on the following pages.
-AH calcubtio11s an.: pert'ormcd bcforc rounding 10 avoiJ round-off errors in c:::dculatcd results.
-Results nmetl :1s "ND" were not Jctt:ctt:d at or above the SIJ.!ed limit.
-This rcpon must not be reproduced. e,'<cept in ful!, wi1hom the wriuen approval of 1he L:tbor::uory.
-Results for the following parameters are nel'er reported on a dry weight basis: color, corrosivity. density, flashpoim, ignitability, IJyer~. odor,
p:iint filter test, pH, porosity pressure, reactivity, rcdox pocential, specific gravity, spot tests, solids, solubility. temper:uure, viscosity, :i.nd weight.
S.:'.:l .. MPLED
DA_TE
•
SFJ·IJP
TIME
01/10/02 15 ,2,
•
•
r,:~1~~1a•1• • • Custody Record
-Severn Trent Laboratories, Inc.
Ghent ') __ Project Manager Date Chain of Custody Nwn/Jer (, <-JJu:.; ~-\: 0--6c].,WJ(' l 10b. C!;1 ·\ '. . ' ' ..·
·' .. i Address Telephone Number (Area Code)/Fax Number Lab Number --1 .,,.) ,-\.I A-"C., ,, ··) 911.--"'"11-\ '-(),~ i or I ~ ,<1,~· 1-.:Lf ':,,,? ... ·,/)2_
Page
C11y ...., ,\ t State I Zip Code Site Contact Lab Contact Analysis (Attach list if Cc:..v\cn:-,-. /'(\ 1\.-0 \ , '-1. A-more s ace is needed)
Prujt:'!.,!!ame and Locatjon (S/al'1{ . Carrier/Waybill Nut.er _ ., -,; ' (_'; '2.,c:-z_"'-r \ [) ,,JQ i-,1\,... A,:,-,\,., 0~ -r1;3 c_:1 o '-Is s-7 'l-J Special Instructions! Contra1://P11rchc1se OH/ei/Ouote No C.-
Matrix Containers & • Comlitions of Receipt Preservatives ?: -·-:,
Sample I.D. No. and Description I " 0 ~ , 0 Date Time .. o> r< ~ -5 ~ 0 G 0 ~o 0: ,IY' (Containers for each sample may be combined on one line) < • § N ~ ~ ~~ ~ ~ , ,
-) rs [f ,~ l <; ,r --i,,,; ,Loh. l.:;:).o I, ·I. V. Ii( h.11-r,n-t.:._":,p~·.:...1•:I, _ ~ -.1 ,f icl..\,.,; :.;J,.,,.,I ; /~ J-..,.J,& I I ' .
Possib1e Nazard Identification I Sample Disposal
(A Ice may be assessed if sDmplos arc ret,1inod 0 Non-Hazard D Flammable D Skin lrrilan/ D Poison B efunknown D Return To Client IVl"Oisposal By Lab D Archive For Months longer than 3 mon/11s)
Turn Around Time Required ' QC Requirements (Specify)
D 2--i Hours D 48 Hours D ? Days 0 14 Days D 21 Days '(,(other .c:;77')
I. Rel,nqui,t,ec/ By CL . ~-~ f) l oate
1
Time 1. Received By
1
Date I Time i°\ ,o\ .:,, \/,70U A.:; r\o" ~ ;,,,r, /-Y"-..-"'----1 -'-I,
2. Relmquishf;c/ By ' '"
1
Date '
1
Time 2.R1/!t!:K·J p)J,n J
1
Date /4
1
fone
"J / ',·,. ~ I hi u,J l/ ,)o_ 3. Relinquisllecl By
1
Dale
1
Time 3. F.feceived By
1
Date
1
Timo
Commems
DISTRIBUTION: Wl--llTE · Stays with liie Sample; CANARY Returned lo Client with Report; PINK. Field Copy
--------------------------------------------------
THE RETEC GROUP INC
Client Sample ID, SYSEFF/SV-305
GC/MS Semivolatiles
Lot-Sample# ... , C2A110211-001 Work Order # ... : ERJJOl.ZVl-. Matrix. -... -... : WF.TER
Date Sampled ... , 01/10/02 Date Received .. , 01/11/02 MS Run# ....... ,
Prep Date ...... , 01/14/02 Analysis Date .. , 01/17/02
Prep Batch# ... , 2014303
Dilution Factor: 1 Method ......... , SW846 8270C SIM
REPORTING
P.l\R.'1·1ETER RESULT LIMIT ill-lITS
2,4-Dichlorophenol ND 0.20 ug/L
Pentachlorophenol ND l.O ug/L
Phenol ND 0.20 ug/L
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Nitrobenzene-d5 51 (32 -112)
Terphenyl-d14 56 (10 -144)
2-Fluorobiphenyl 51 (30 -110)
2-Fluorophenol 55 (13 -110)
Phenol-d5 ·52 (10 -113)
2,4,6-Tribromophenol 51 (21 -122)
•
•
•
•
Client Lot 11 ..• , c2.o.110211
MB Lot-Sample ii, C21:U40000-303
Analysis Date .. , 01/17/02
Dilution Factor: l
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-dS
Terphenyl-d14
2-Fluorobiphenyl
2-Fluorophenol
Phenol-dS
2,4,6-Tribromophenol
OTE(S),
METHOD BLANK REPORT
GC/MS Semivolatiles
Work Order# ... : ERLPHl~P-
Prep Date ...... , 01/14/02
Prep Batch 11 .•• , 2014303
REPORTING
RESULT LIMIT UNITS
ND 0.20 ug/L
ND 1.0 ug/L
ND 0.20 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
53 (32 -112)
57 (10 -144)
51 (30 -110)
54 (13 -110)
60 (10 -113)
53 (21 -122)
'alculations are performed before rounding to avo_id round-off errors in calculated results.
Matrix ..... . WJl..TER
METHOD
SW846 8270C SIM
SW846 8270C SIM
SW846 8270C SIM
------------------------------------------------------
LABORATORY CONTROL SAMPLE EVALUATION REPORT
GC/MS Semivolatiles
Client Lot# ... , C2All02ll Work Order # ... , ERLPHlAC-LCS
ERLPHLZ\IJ-LCSD
Analysis Date .. , 01/17/02
Matrix ..... .
LCS Lot-Sample#, C2Al40000-303
Prep Date ...... , 01/14/02
Prep Batch# ... , 2014303
Dilution Factor: l
P.Z\RAMETER
Phenol
Pentachlorophenol
2,4~Dichlorophenol
SURROGATE
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
NOTE (S) ,
PERCENT
RECOVERY
52
52
96
94
54
54
RECOVERY
LIMITS
(10 -131)
( 10 -131)
(10 -140)
( 10 -140)
(42 -115)
(42 -115)
PERCENT
RECOVERY
50
50
53
53
48
48
49
49
54
54
60
60
Calculmions are performed before rounding to ;ivoid round-off errors in c:i.lculated results.
RPD
RPD LIMITS METHOD
SW846
0.46 (0-43) SW846
SW846
2.0 ( 0 -56) SW846
SW846
0.41 (0-44) "SW846
RECOVERY
LIMITS
(32 -112)
( 3 2 -112)
(10 -144)
(10 -144)
(30 -110)
(30 -110)
(13 -110)
(13 -110)
(10 -113)
(10 -113)
(21 -122)
(21 -122)
•
B270C SIM
8270C SIM
B270C SIM
8270C SIM
s27oc SIM
8270C SIM
•
•
•
•
ANALYTICAL REPORT
Raleigh, Biweekly NPDES
Lot#, C2A240184
Rita Bauer.
ThermoRetec Corp
SEVERN TRENT LABORATORIES, INC.
I;//" //
!f:/7//t:lf/!J der#;/-, ,
Veronica Bortot
Project. Manage!."
January 31, 2002
STL Pittsburgh is a part of Severn Trent Laboratories, Inc.
STL Pittsburgh
450 William Pitt Way
Pittsburgh, PA 15238-1330
Tel: [phone]
Fax: [phone]
www.stl-inc.com
,---------------------------------
Sample Receiving:
CASE NARRATIVE
THE RETEC GROUP
Raleigh, Biweekly NPDES
STL Lot# C2A240184
SIL Pittsburgh, PA received samples on January 24, 2002 in good condition. The cooler
was within the proper temperature range.
GC/MS Scmivolatiles SIM:
Due to the concentration of target compounds detected, sample INF/SV-101 was
analyzed undiluted and at a 2X dilution. Both sets of results are reported.
Dioxins:
SIL West Sacramento, CA performed the dioxin analysis. All results are included in the
report.
There was no Ending Static Resolution due to a brief power outage.
The interruption caused the source conditions to change. This problem occurred more
than eight hours after the Ending Standard, therefore no impact on data.
•
•
•
•
•
METHODS SUML'1ARY
C2A240l84
P.>R.l\.METER
Dibenzodioxins and Dibenzofurans, HRGC/HRMS
8270C (SIM)
References:
ANALYTICAL
METHOD
S1'1846 8290
SW846 8270C SIM
PREPl'RATION
METHOD
S\'1846 8290
SW846 3520C
SW846 11 Test Methods for Evaluating Solid Waste, Physical/Chemical
Methods 1'1 Third Edition, November 1986 and its updates .
\'VO # SllJvfPLE# CLIENT SP.J.IPLP ID
ER57M
ER570
ER576
NOTE(S),
001
002
003
EFF/SV-305
B.C./SV-304
INF/SV-101
SAt'VIPLE SUMMARY
C2A240l84
-The analytical results of the samples listed above arc prescmed on the following pages.
-All calculations arc performed before rounding to avoid round-off errors in calculated results.
-Results noted as "ND" were not detected at or above tl1c stated limit.
-This report must not be reproduced, except in full, without 1he written approval of the laboratory.
-Results for the following parameters are never reported on a dry weight basis: color. corrosivity, density, tlashpolnt, ignitability, layers, odor,
paint filter test, pH. porosity pressure, reactivity, rcdox potential, specific gravity, spot tests, solids, solubility, tcmper:uure, viscosity, and weight.
SMPLED
DA'T'E
\.
•
S_1\MP
TIME
01/23/02 10,00
01/23/02 10,05
01/23/02 10,10
•
~~o'Jlr6/k!¥4fii-M • Custody Record
STL---412~ (07001
Client D Project Manager
'-~:,) t> '"'"l'--~:~r ;,,ddress T~/ephone Number (Area Code)!Fax Number soo ~ 0-. ¼ 1-I, --R s-~t ?,oz_ C\. 7'?. -"37\-I Y.J..-~ Cay _ . ,Jt I z;~c~~ 'I)_
Site Contact ! Lab Contact Gm ,>,i' c\
Projecl ~Jame and Localio\ (State~ l~: Carrier/Way~r --'D,_,, :z..~ < \'L ·~c;\ '\ L-A.., -·-rcs ·lo 4,;l7 / 1 ContracUPurchase Order/Quote No. ' Containers & c,._
Matrix Preservatives -t r:,
l ·~
r-Sample /.0. No. and Description l 0 ~ " "" r-; Date Time tj 'a ~ 0 G 0 ~o (;-< (Containers for each sample may be combined on one fine) . ' > N ., ~ em ' ' ~ ~ " " " NO
E.f-F-<,_\}-""',o'., I I--,.,,( ~ iO<n:, 'I-l'K )( ✓ p· ~ \I , ""\ v•/ , I , I oo'{' ,
X 1'1--:) . {_,,, y..._ J1,,,p s v-;o I ~ 10/0 ,I X X "-
Possible Hazard ldentificalion ·l Sample Disposal
D Non-Hazard D Flammable D Skin lrri/ant 0 PoisonB ~nknown D Return To Client ~i~posa/ By Lab D Archive For
Turn Around Tune Reqwred
0 2--1 Hours O 48 Hours
e uir OCR q em ents S ecif I P Yi
□, ay, .□ 14 Days 0 21 Days
J. Rdinquished By
2 Relinquished By
3. R&linqwshed By
Comments
DISTRIBUTION: WHITE· Stays with /lie Sample; CANARY-Returned to Client with Report PINK -Field Copy
•
Severn Trent Laboratories, Inc.
Date :I \ .-( :n .)___ Chain of Custocl)' N11mht.:1 .. c1 ii :L ).'.' 1-1 ii \ _! ,_, t Lab Number
Page \ of \
Analysis (Attach list if
more soace is needed)
Special Jnstn1ctionsl
Conditions of Receipt
(A Jee may be assessed if samples are retilinecJ Months longer than 3 months)
Date Time
Date Time
i-2{£.-{JJ... i:J.0(:)
Dll/0 Ti(IIIJ
TIIE RETEC GROUP INC
Client Sample ID: EFF/SV-305
GC/MS Semivolatiles
Lot-Sample #---: C2J\_240184-001 Work Order # ___ : ERS 7MlAA Matrix .... __ ... :
Date Sampled ___ , 01/23/02
Prep Date ______ , 01/28/02
Prep Batch j/ ___ , 2028248
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phe-nol
SURROGATE
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-dS
2,4,6-Tribromophenol
Date Received .. : 01/24/02
Analysis Date._, 01/30/02
MS Run#-. __ ... :
Method ..... _ ... : SW846 8270C SIM
REPORTING
RESULT LIMIT UNITS
ND 0.20 ug/L
ND 1. 0 ug/L
ND 0.20 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
66 (32 -112)
60 (10 -144)
62 (30 -110)
64 (13 -110)
68 (10 -113)
60 (21 -122)
•
WATER
•
•
•
•
•
THE RETEC GROUP INC
Client Sample ID, EFF/SV-305
Trace Level Organic Compounds
Lot-Sample# ... , C2A240184-001 Work Order# ... , ER57MlAC
Date Received .. , 01/24/02
Analysis Date .. , 01/28/02
Date Sampled ... , 01/23/02
Prep Date ...... , 01/28/02
Prep Batch# ... , 2028116
Dilution Factor: 1
DETECTION
PARAMETER RESULT LIMIT
2,3,7,8-TCDD ND 1. 5
PERCENT RECOVERY
INTERNAL STANDARDS RECOVERY LIMITS
13C-2, 3, 7, 8-TCDD 94 (40 -135)
Matrix ......... : WP..TER
MS Run # ....... ,
UNITS METHOD
pg/L SW846 8290
,--------------------------------------------------
THE RETEC GROUP INC
Client Sample ID, B.C./SV-304
GC/MS Semivolatiles
·'
Lot-Sample# ... : C2A240184-002 Work Order# ... , ER57011\A
Date Received .. , 01/24/02
Analysis Date .. , 01/30/02
Matrix ..... -... : W.l'\.TER
Date Sampled ... , 01/23/02 MS Run# ....... ,
Prep Date ...... , 01/28/02
Prep Batch# ... , 2028248
Dilution Factor: 1 Method ......... , SW846 8270C SIM
REPORTING
P/\.RAMETER RESULT LIMIT UNITS
2,4-Dichlorophenol ND 0.20 ug/L
Pentachlorophenol ND 1.0 ug/L
Phenol ND 0.20 ug/L
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Nitrobenzene-dS 55 (32 -112)
Terphenyl-dl4 51 (10 -144)
2-Fluorobiphenyl 50 (30 -110)
2-Fluorophenol 54 (13 -110)
Phenol-d5 57 (10 113)
2,4,6-Tribromophenol 50 (21 -122)
•
•
• TilE RETEC GROUP INC
Client Sample ID, INF/SV-101
GC/MS Semivolatiles
Lot-Sample# ... , C2A240184-003 Work Order# ... , ER5761AA
Date Received .. , 01/24/02
Analysis Date .. , 01/30/02
Date Sampled ... ·, 01/23/02
Prep Date ...... , 01/28/02
Prep Batch# ... , 2028248
Matrix ......... , WATER
MS Run# ....... ,
Dilution Factor: l Method ......... , SW846 8270C SIM
PARAMETER
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-dS
2,4,6-Tribromophenol
RESULT
ND
13 E
ND
PERCENT
RECOVERY
60
59
57
60
65
62
•
NOTE(S), ·
~ Estimated result. Result concentration exceeds the calibration range .
•
REPORTING
LIMIT UNITS
0.20 ug/L
1..0 ug/L
0.20 ug/L
RECOVERY
LIMITS
(32 -112)
(10 -144)
(30 -110)
(13 -110)
(10 -113)
(21 -122)
---------------------------------------------------
THE RETEC GROUP INC
Client Sample ID, INF/SV-l0l
GC/MS Semivolatiles
Lot-Sample# ... , C2A240184-003 Work Order# ... , ER5762P~.
Date Received .. , 01/24/02
Analysis Date .. , 01/30/02
Matrix .... ·-. -.: WATER
Date Sampled ... , 01/23/02 MS Run# ....... ,
Prep Date ...... , 01/28/02
Prep Batch!/ ... , 2028248
Dilution Factor: 2 Method ......... , SW846 8270C SIM
REPORTING
PARAMETER RESULT LIMIT UNITS
2,4-Dichlorophenol ND 0.40 ug/L
Pentachlorophenol 6.2 2.0 ug/L
Phenol ND 0.40 ug/L
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Nitrobenzene-dS 49 (32 -112)
Terphenyl-dl4 50 (10 -144)
2-Fluorobiphenyl 48 (30 -110)
2-Fluorophenol 48 (13 -110)
Phenol-d5 55 (l0 -113)
2,4,6-Tribromophenol 49 (21 -122)
•
•
•
THE RETEC GROUP INC • Client Sample ID, INF/SV-lOl
Trace Level Organic Compounds
Lot-Sample# ... , C2A240184-003 Work Order# ... , ER5761AC
Date Received .. , 01/24/02
Analysis Date .. , 01/28/02
Date Sampled ... , 01/23/02
Prep Date ...... , 01/28/02
Prep Batch# ... , 2028116
Dilution Factor: l
DETECTION
PARAMETER RESULT LIMIT
2,3,7,8-TCDD ND 2.6
PERCENT RECOVERY
INTERNAL STANDARDS RECOVERY LIMITS
13C-2,3,7,8-TCDD 90 (40 -135)
•
Matrix ..... . WATER
MS Run# ....... :
UNITS METHOD
pg/L SW846 8290
-----------------------------------------------------
Client Lot lt ... , C2A240184
MB Lot-Sample#, C2A280000-248
Analysis Date .. , 01/30/02
Dilution Factor: 1
2,4-Dichlorophenol
Pentachlorophenol
Phenol
SURROGATE
Nitrobenzene-dS
Terphenyl-d14
2-Fluorobiphenyl
2-Fluorophenol
Phenol-dS
2,4,6-Tribromophenol
NOTE (S),
METHOD BLANK REPORT
GC/MS Semivolatiles
Work Order# ... ' ETAJ81AA
Prep Date ...... , 01/28/02
Prep Batch# ... , 2028248
REPORTING
RESULT LIMIT UNITS
ND 0.20 ug/L
ND 1. 0 ug/L
ND 0.20 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
71 (32 -112)
65 (10 -144)
63 (30 110)
72 (13 -110)
73 (10 -113)
67 (21 -122)
Calculations are performed before rounding to avoid round-off errors in calculated results.
•
METHOD
SW846 8270C SIM
SW846 8270C SIM
SW846 8270C SIM
•
•
Client Lot# ... , C2A240184
MB Lot-Sample#, G2A280000-116
Analysis Date .. , 01/28/02
Dilution Factor: 1
PARAMETER
2,3,7,8-TCDD
INTERNAL STANDARDS
13C-2, 3, 7, 8-TCDD
NOTE (S) ,
METHOD BLANK REPORT
Trace Level Organic Compounds
r-Work Order# ... , ER9801AA
Prep Date ...... , 01/28/02
Prep Batch# ... , 2028116
DETECTION
RESULT LIMIT UNITS
ND 1.5 pg/L
PERCENT RECOVERY
RECOVERY LIMITS
87 (40 -135)
Calcubtions are performed before rounding to avoid round-off errors in calculated results .
•
•
Matrix ..... . WATER
METHOD
SW846 8290
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LABORATORY CONI'ROL SAMPLE EVALUATION REPORT
GC/MS Semivolatiles
Client Lot# ... : C2A240184 Work Order# ... : ETAJ81AC-LCS
ETAJ81AD-LCSD
Analysis Date .. , 01/30/02
Matrix ...... ~ _ . :
LCS Lot-Sample#: C2A280000-248
Prep Date ...... , 01/28/02
Prep Batch# ... , 2028248
Dilution Factor: 1
PARAMETER
Phenol
Pentachlorophenol
2,4-Dichlorophenol
SURROGATE
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorobiphenyl
2-Fluorophenol
Phenol-d5
2,4,6-Tribromophenol
NOTE(S):
PERCENT
RECOVERY
65
66
79
74
67
66
RECOVERY
LIMITS
(10 -131)
(10 -131)
(10 -140)
(10 -140)
(42 -115)
(42 -115)
PERCENT
RECOVERY
73
72
58
SB
63
62
65
69
68
69
73
72
Calculations are performed before rounding to avoid round-off errors in calculatetl results.
RPD
RPD LIMITS METHOD
SW846 B270C
0.33 ( 0-43) SW846 B270C
SW846 B270C
6.0 ( o-56 I SW846 B270C
SW846 B270C
1. 9 (0-44) SW846 8270C
RECOVERY
LIMITS
(32 -112)
· (32 -112)
(10 -144)
(10 -144)
(3 0 -110)
(3 0 -110)
(13 -110)
(13 -110)
(10 -113)
(10 -113)
(21 -122)
(21 -122)
•
WATER
SIM
SIM
SIM
SIM
SIM
SIM
•
•
•
•
•
LABORATORY CONTROL SAMPLE EVALUATION REPORT
Trace Level Organic Compounds
Client Lot# ... , C2A240184 Work Order# ... , ER9801AC
LCS Lot-Sample#, G2A280000-116
Prep Date ...... , 01/28/02 Analysis Date .. , 01/28/02
Prep Batch# ... , 2028116
Dilution Factor: 1
PERCENT RECOVERY
PARAMETER RECOVERY LIMITS
2,3,7,8-TCDD 118 (75 -1.26)
PERCENT
INTERNAL STANDARD RECOVERY
13C-2,3,7,8-TCDD 87
NOTE (S) ,
Calculations are performed before rounding to avoid round-off errors in calcula1ed results.
Bold print denotes control parameters
Matrix ...... _ .. : WATER
METHOD
SW846 8290
RECOVERY
LIMITS
,(40 -135)