NCD003200383_20010108_Koppers Co. Inc._FRBCERCLA RA_Monthly Progress Reports 2000-OCR

• January 8, 2001
Ms. Beverly Hudson
Remedial Project Manager
U.S. EPA -Region IV, 11 th Floor -
North Site Management Branch
61 Forsyth Street, SW
Atlanta, GA 30303
RE: Monthly Progress Report #92
Remedial Action
Koppers Site -Morrisville, NC
Dear Ms. Hudson:
ThermoRetec Corporation
300 Baker Avenue, Suite 302
Concord, MA 01742
Smart Solutions. Positive Outcomes.
{978) 371-1422 Phone
{978) 371-1448 Fax
www.thermoretec.com
SUPERFUND SECTION
In accordance with the Unilateral Order, and on behalf of Beazer East, Inc. (Beazer),
please find attached four ( 4) copies of the December Monthly Progress Report for
Remedial Action at the Koppers Superfund Site in Morrisville, NC.
• Should you need additional information regarding this progress report, please call Mike
Slenska at (4l2) 208-8867 or me at [phone].
•
Sincerely,
ThermoRetec Consulting Corporation
.1 . I ! n<-r; ,n "::. lc.u..,,~ l, /--!,_.'I-,_~
Rita Bauer
Project Geologist
RB:cg
Enclosure
cc: D. Mattison -NC Superfund (2 copies)
D. Hails -Ecological Restoration, Inc.
J. Garrett -NC Division of Water Quality
P. !Glchenstein -ThermoRetec
D. Matthews -NC Division of Water Qua!.
F: IPR OJ ECTS\03624 I Rcports\M onthly\ 12 M-00. wp<l
M. Slenska -Beazer
L. Faulconer -Wake County
.G. Caskey -Enwood Structures
M. Helbling -Beazer
a Thermo Electron company
•
•
•
MONTHLY PROGRESS REPORT #92
REMEDIAL ACTION
SITE NAME: Koppers Superfund Site
Beazer East, Inc.
Morrisville, NC
USEPA DOCKET NUMBERS: 93-09-C
PERIOD ENDING: December 31, 2000
1. PROGRESS MADE THIS MONTH
2.
3.
4.
5.
6.
Remedial Action (RA) -HABITAT MITIGATION. No activities were conducted this
month.
Remedial Action (RA) -GROUNDWATER TREATMENT. The treatment system
operated throughout the month without upset. System performance was monitored
on a biweekly basis. Approximately 34,465 gallons of groundwater were extracted,
treated in the treatment plant and discharged between November 29, and
December 28, 2000. System water samples were collected on December 8, 2000
and December 20, 2000 in accordance with the sampling schedule in the O&M
manual. Samples were submitted to Severn Trent and TriTest for laboratory
analysis. The operations and sampling programs are summarized on the attached
Table 1.
Remedial Action (RA) -EFFECTIVENESS MONITORING PROGRAM. No activities
were conducted this month.
Remedial Action (RA) -CORRESPONDENCE. None.
PROBLEMS RESOLVED
PROBLEMS ANTICIPATED
UPCOMING EVENTS
PERSONNEL CHANGES
SUBCONTRACTORS
None.
None.
Continue System O&M.
None.
None.
7. ANALYTICAL DATA Analytical data from system influent and effluent sampling
received during this period are enclosed and are summarized on Table 2 .
F: \PROJ ECTS\03624\Reports\Monthly\ 12M-OO. wpd
•
Date Systems Cummulative SV-101 SV-101
Check Effiuent Flow Sample Sample
(yes/no) (Gallons) (yes/no) Parameters
01/04/00 "' 2,178,450 00
01/20/00 m 2,201,060 "° 02/01/00 m 2,222,900 "° 02/18100 \'CS 2,250,320 00
03/03/00 ves 2,275,240 00
03/13/00 "' 2,294,030 00
04/12/00 m 2,347,700 00
04/24/00 "' 2,371,150 '" 05/05/00 "' 2.387,750 00
05/15100 \'CS 2,411,760 00
05/31/00 ves 2,441,250 "° 06/14/00 "' 2,462,390 00
06/26/00 "' 2,481,440 00
07/06/00 "' 2,497,950 ao
07/11/00 "' 2.505,210 00
07/17/00 m 2,513,700 "' 2,4-Dichloro. Phenol
08/01/00 "' 2,536,540 00
08/14/00 "' 2,556 590 00
09/05/00 "" 2,591,501 "° 09/27/00 "" 2,635,455 00
10/13/00 "' 2,656,712 00
10/24/00 "' 2,667,340 ves Penta, 2,4.Dichloro, Phenol
11/08/00 vcs 2,688,980 00
11/21/00 "' 2,705,840 00
12/08/00 "' 2,727,160 "' Dioxin
12/20/00 "' 2,740,750 00
Notes:
Sampling point SY-IOI is located before the Carbon Units (pretreatment)
Sampling point SY-304 is located between the Carbon Units
Sampling point SY-305 is lactated after the Carbons Units {post-treatment)
•
Table I
Groundwater Treatment Oper:itions and Sampling Program Summary
Koppers S11perfu11d Site
Morriwille, North Carolina
October 2000
Associated S\'-304 SV-304 Associated
Group Sample Sample Group
(yes/no) Parameters
00
"° 00
"' 2,4-Dichloro, Phenol I
oo
"° 00
ao
00
00
00
00
00
"° "° I "' 2,4-Dichloro, Phenol I
00
00
"° "° 00
I "' Penta, 2,4-Dichloro, Phenol I
00
"° 2 ao
00
Associated Groups:
SY-JOI -Group I is penta and 2,4-dichlorophenol; Group 2 is dioxin
SY-304 -Group I is penta and 2,4-dichlorophenol
SV-305 SV-305
Sample Sample
(yes/no) Parameters
"' Penta, 2,4-Dichloro, Phenol, chronic tox
"" Penta, 2 4-Dichloro, Phenol
"" Penta. 2.4-Dichloro, Phenol, chronic tox
ves Penta, 2,4-Dichloro, Phenol, dioxin
m Penta, 2,4-Dichloro. Phenol
\'CS Penta, 2,4-Dichloro, Phenol
"" Penta, 2,4-Dichloro. Phenol, chronic lox
"' Penta, 2,4-Dichloro, Phenol
"' chronic toxkiiv
"' Penta, 2,4-Dichloro, Phenol
"' Penta, 2 4-Dichloro, Phenol
"' Penta, 2,4-Dichloro, Phenol , dioxin, chronic tox
"' Penta, 2.4-Dichloro, Phenol
"' Penta, 2.4-Dichloro, Phenol
"" chronic 1oxicitv
ves Pema. 2,4-Dichloro, Phenol, diodn
"" Penta, 2,4-Dichloro, Phenol, chronic tox
"" Penta, 2,4-Dichloro, Phenol
"' Penta, 2,4-Dichloro, Phenol, chronic tox
m Penta, 2,4.Dichloro. Phenol
ves Penta, 2,4-Dichloro, Phenol
"" Penta, 2,4-Dichloro, Phenol , dioxin. chronic tax
"" Penta, 2 4-Dichloro, Phenol
vcs Penta, 2,4-Dichloro, Phenol
"' Penta, 2,4.Dichloro, Phenol
m Penta, 2,4-Dichloro, Phenol
SY-305 -Group I is penta, phenol, and 2,4-dichlorophenol; Group 2 is dioxin and Group 3 is chronic toxicity
•
Associated
Group
1.3
I
1.3
1,2
I
I
1,3
I
4
I
I
I, 2, 3
I
I
J
I, 2
1.3
I
1,3
I
I
I, 2, 3
I
I
I
I
•
•
•
Parnmel<r
Pent,cblorooher,11
2.4,D,chlornohenol
!'her,>]
Chtnnie Toxi<lt>
Tahle 2
Gmundw:itl'r 'l'rl':ilmfnl
ANALYTICAL DATA SUM.'HARY
Koppers Superfund Site
Morris\·ille, ~orth Carolina
December 2000
Alllllyc,cal
Dare Sample
Sa,nrl• Lueation
Cull«tod SV-JOI
IJj/1).111•>
Ul/2IJ10)
02111210,
n211x1m
fl.1111,lA<I
<11/llA>I
114/ll/m
114/2411•1
115115/r.l
ns1J1/fl11
\Wl4/IXI
!111121,1m
(17/IIM•I
!J7117/m
ll~All/1!1
IJ&/l-1/!MI
09111$/1!1
(!912711•1
lOJIJll•I
lll124AXI " 11/(Jl!/IMJ
11/llil!I
12/IIX/UI
12110101
Oll!14/l•I
01110/111
(ll/!12/lXI
(llJIMXI
(IJ/()J/11)
11111J1••1
114112/1•)
IJ.lr.l4il!I
MIil/i>!
OV11/I"
()h/14/1.,
()(,/'lf,A•I
!111Hr,1m
117/!7/IIJ <Ill
IIMllll•I
ll~/14/111
tl9/113/UI
IP\1/27/UI
IUIIJl<•I
111/24/1., <Ill
11/IIMXI
11/21/IM)
12/l)Mkl
12J2llll•l
111/114111!
111n111m
112/Ul/UI
i,211~11,1
OJ/113/IXI
()J/IJ/IXI
()4l12~MJ
04/H/lkl
11,11,11xJ
11,iJI/IKJ
llfJJ4/IKJ
llfJ2M••
111/IIM•I
IJ7/\711!! < IO
OX/111101
11~114/111
IP'J/11511•1
119n11,11
111113/fMI
11112-111,, <!II
11111~11•1
111?1/0I
12/llHll,1
12110,rn
'11111411"
IJ2/111/IMI
114112/ral
11:1111,,m
!Wl4/I.,
07111/111
OMJJIOI
mm,,m
IU/2411•1
11/<IX/tal
121<151<•1
D",xin 12,J,7,8,TCDD\ 02/l~Ail
<Wi,11,1
07/11/1.,
1ur.un.,
11n21m
12mxn,1 <2.7
N""" All re,ul" "'" 1n ugJL excer< <J1<1w1. D,u,,n <Jata "rn r""~ram>JL,
SV-]IJI • Def.,,. c., .. ,n Uni"
•sv.J!l4 -Between C4rl>on urn,.
""SV-305. Allor Carhon Uni"
1~~80 M••l>od ""'d
S•rnple Sample
L,x:,1ti<1t1 Luc,uion
SV-3(1-1" sv.1111••
<>
<>
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<> <>
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<> <>
<> <> <> <>
<> <>
<>
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<> <>
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< IO
<111
<Ill
<Ill <Ill
< 111
<l'I
<Ill
< ID
<10
<10
<Ill
<Ill
<Ill
<111 <Ill
<Ill
<IU
<l<l
<10
< 10
< Ill <IU
<JII
<Ill
<Ill
<Ill
<Ill
<Ill
<IU
<Ill < 10
<10
<111
<HJ
<Ill
<Ill
<Ill
<Ill
<Iii
< I()
< 10 <ID
<IO
< ID
< 10
< 10
< 10
<Ill < 10
< 10
<10
<JO
<10 p,.,
Pa"
f'ail p,,.
Fail , ..
Foil
Fail
Fa,I
F•il p,.,
<l.2
<J.'14
<U.~hl
<IJ.fill~•
<II.J71
•
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ANALYTICAL REPORT
PROJECT NO. RALEIGH
Raleigh-Bi-Weekly NPDES
Lot#, C0L090140
Debbi Leuteritz
ThermoRetec
SEVERN TRENT LABORATORIES, INC.
''.::;fSERVIGits:::,:;!'., ~-~--~·-
STL Pittsburgh
450 William Pitt Way
Pittsburgh, PA 15238-1330
Tel: [phone]
Fax: [phone]
www.stl-inc.com
~~d
Veronica Bortot
Projecc Manager
December 18, 2000
STL Pittsburgh is a part of Severn Trent Laboratories, 1nc.
•
•
•
Sample Receiving:
CASE NARRATIVE
THERMORETEC CORPORATION
Raleigh
STL Lot# C0L090140
STL Pittsburgh, PA received samples on December 09, 2000 in good condition. The
cooler was within the proper temperature range.
GC/MS Semivolatiles:
There were no problems associated with the analysis.
GC Phenols:
There were no problems associated with the analysis .
Chain'1J1
Gusto~ Record
QUA 4124 0797
Client
-n,..,_/"i'!1<J D~
Address
300 Bc~~r fJ. ,J{.
City .
(,.A ,•crJ I State \ Zip Code M/1\ Otl'fl-
Project Name ( ~
\'--z,<z-<'. r (L 1\~
ContracVPurchase Order/Quote No. '
Sample /.0. No. and Description Date (Containers tor each sample may be combined on one line)
CFC:-( <; J -Sc:>5-I 2/if~o
Possible Hazard Identification
•
Project M7~~~ r·.-/ c.t,.,..,,., f-cj\A
Telephone Number (Area Code)/Fax Number
CJ 1q. 7, 7 L I'-{ 1/ .. T-·
Site Contact Lab Contact
~."=.. (>c,v,.r
Carrier/Waybill Number
Containers & Matrix Preservatives ~ ----::,-. ' [ 0 "' ~ "6 ~" &!, Time I ti ~ "' ~ G Q b,, • a § ~ ~ ~~ ' "' "' ~ ~
IO Oti X 'A Y. X
[}(Non-Hazard 0 Flammable D Skin Irritant D PoisonB
I Sample Disposal
D Unknown D Return To Client ro Disposal By Lab D Archive For Tum Around Time Requrred
D 24 Hours D 48 Hours
2. Relinquished By
3. Relinquished By
Comments
D 14 Days D 21 Days
DISTRIBUTION: WHITE -Stays with the Sample; CANARY -Returned to Client with Report; PINK -Field Copy
QC Reqwrements (Specify)
1. Recerled BJ .
/1-,,l.,A_..
2. Received By
3. Received B
Date I ( I 'Z. 'i o,e-·
Chain of Custody Numb<f--6 l '-J ,, .. J
Lab Number
Page I of l
Analysis {Attach list if
more s ace is needed
Special Instructions/
Conditions of Receipt
(A lee may be assessed if samples are retained Months longer than 3 months)
Time
Time
Time
2-b''-// I(;
i'
•
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Cooler Receipt Form
STL Pittsburgh
Project: _______ _ Quote 2. 7 I..,, ( c\
Cooler Rec'd & Opened for Temp. Check on: I?...-,·~c:, "
Coolers Opened and Unpacked on: ----~~~~~~~~~~~l~-?--~~:--~c~-~-'----_' ~~~~~~~~~--B-y-: --,'(_'-----___ _
(Signature)
SIL Pittsburgh Lot Number: ____ _,,__0 _(_0_·._1'--· _O--'/---''(_c_; ________________ _
I. Were custody seals on the outside of the cooler? _______________ _
IfYES, how many and where? Quantity ~c.Location ___ (_-:_-v_-_.r-,--_______ _
Were signatures and date correct? ____________________ _
2. Were custody papers included inside the cooler? _______________ _
J. Were custody papers properly filled out (ink, signed, match labels)? _______ _
4. Did you sign the custody papers in the appropriate place? ___________ _
5. Was shippers packing slip attached to this form? _______________ _
6. Were packing materials used? ______________________ _
,,
If YES, what type? --------~)= .. _L~, L_,~(_<-__ ~_c_-..,_'' _________ _
7. Were the samples chilled? (Record temperatures on reverse side.) ________ _
8. Were the samples appropriately preserved? _________________ _
9. Were all bottles sealed in separate plastic bags? _______________ _
10. Did all bottles arrive in good condition (unbroken)? _____________ _
11. Were all bottle labels complete (sample ID, preservatives, etc.)?-----~----
12. Did all bottle labels and/or tags agree with custody papers? ___________ _
IJ. Were correct bottles used .for tests indicated? ________________ _
Yes
.,.,.,,--
No
~-
l4.
15.
Were all VOA vials checked for the presence of air bubbles?___________ ~:.-__
Was a sufficient amount of sample sent in each bottle?_____________ ____..,.-::::::
~ 16. Samples received by: FEDEX UPS . CLIE1'ff DROP-OFF OTHER
Explain any discrepancies:
Cl Level 2 Review~-----------------------------------
Was contacted on ________ bv _______________ to resolve discrepancies.
,',TL PT/Ft:b-o00/96-005/COOL.DOC ' : Pagel of2
•
II
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ThiET DIAET HG
Sample ID PH<: PH<: PH<:!
I
I
I
I
I
Cooler Receipt Form
STL Pittsburgh
0G
NITT(I) CN TPHC PHEN SU1.F
PH<:! PH:21:! PH<:! PH<: ?H<!:l::!
TC<: TOX VOA
PH<: PH<: P.'UP
I
P · P resen,ed
UP: Unpreserved
h«irus
p!-[c::
I
I
I
I
I
I
I
( l) ''NUT' could mclude sample bottles for auunonrn, chemical oxygen dema..'1d, rutrate!rutnte, TIG..'1, or total phosphorus
I
I
Comments:----------------------------------------
Cooler Number Temperature Bottle Type Lot Number*
I . . :z I . I
I
I
I
' I, I I I I .. • Please use an astensk 11 bottle lot number was covered by rhe labe!.
STL PT/F~b-00196-.J05iCOOL.DOC Page2of2
•
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I
I
METHODS SUMMARY
COL090140
ANALYTICAL
=.PceARAM==Ec,Tc=EccR'-------------------------~M~E~T~H~O~D~----
Phenols by GC
Semivolatile Organic Compounds by GC/MS
References:
SW846 8041
SW846 8270C
PREPARATION
METHOD
SW846 3520C
SW846 3520C
SW846 "Test Methods for Evaluating Solid Waste, Physical/Chemical
Methodsn, Third Edition, November 1986 and its updates .
•
•
•
SAMPLE SUMMARY
C0L090140
~ SAMPLE# CLIENT SAMPLE ID
DQ6NM 001 EFF/SV-305
NOTE (S) ,
-The analytical results of the samples listed above arc presented on the fo!lowing pages.
-All calculations are performed before rounding 10 avoid round-off errors in calculated results.
-Results noted as "ND" were not detected at or above the stated limit.
• This report must not be reproduced, except in full, without the written approval of the laborawry.
-Results for the following parnmetcrs arc never reported on a dry weight basis: color, corrosivity, density, nashpolnt. ignitability, layers, odor.
paint filter test. pH, porosity pressure, reac1ivi1y, rctlox potential, specific gravity, spot tes1s, solids, solubility, temperature, viscosity, and weight.
DATE TIME
12/08/00 10,00
•
•
TIIERMORETEC CORP
Client Sample ID, EFF/SV-305
GC/MS Semivolatiles
Lot-Sample # ... ' COL090140-001 Work Order # ... ' DQ6NM1AA Matrix ......... , WATER
Date Sampled ... , 12/08/00
Prep Date ...... , 12/13/00
Prep Batch # ... ' 0349092
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Phenol
SURROGATE
Phenol-d5
2-Fluorobiphenyl
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorophenol
2,4,6-Tribromophenol
Date Received .. :
Analysis Date .. :
Method ......... ,
RESULT
ND
ND
PERCENT
RECOVERY
63
80
74
75
65
84
12/09/00 MS Run# ....... ,
12/16/00
SW846 8270C
REPORTING
LIMIT UNITS
10 ug/L
10 ug/L
RECOVERY
LIMITS
(10 -113)
(3 0 -110)
(32 -112)
(10 -144)
(13 -110)
(21 -122)
THERMORETEC CORP • Client Sample ID, EFF/SV-305
GC Semivolatiles
Lot-Sample # ... ' C0L090140-001 Work Order # ... ' DQ6NM1AC Matrix ......... , WATER
Date Sampled ... , 12/08/00 Date Received .. : 12/09/00 MS Run # ....... ,
Prep Date ...... , 12/11/00 Analysis Date .. : 12/14/00
Prep Batch # ... , 0346432
Dilution Factor: 1 Method ......... , SW846 8041
REPORTING
PARAMETER RESULT LIMIT UNITS
Pentachlorophenol ND 2.0 ug/L
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
2,4-Dibromophenol 81 (31 -134)
•
•
I •
• METIIOD BLANK REPORT
GC/MS Semivolatiles
Client Lot# ... , C0L090140 Work Order# ... , DRDLElAA
MB Lot-Sample#, C0L140000-092
Analysis Date .. , 12/17/00
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Phenol
SURROGATE
Phenol-dS
2-Fluorobiphenyl
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorophenol
2,4,6-Tribromophenol
NOTE {S),
Prep Date ...... , 12/13/00
Prep Batch# ... , 0349092
REPORTING
RESULT LIMIT
ND 10
ND 10
PERCENT RECOVERY
RECOVERY LIMITS
49 ( 10 -113)
59 (30 -110)
57 (32 -112)
80 (10 -144)
47 (13 -110)
78 (21 -122)
.Calculations are performed before rounding to avoid round-off errors in c:ilculated results.
UNITS
ug/L
ug/L
Matrix ......... , WATER
METHOD
SW846 8270C
SW846 8270C
• METHOD BLANK REPORT
GC Sernivolatiles
Client Lot# ... , C0L090140 Work Order# ... , DQ79TlAA
MB Lot-Sample#, C0Lll0000-432
Analysis Date .. , 12/14/00
Dilution Factor: 1
PARAMETER
Pentachlorophenol
SURROGATE
2,4-Dibromophenol
NOTE (S),
Prep Date ...... , 12/11/00
Prep Batch# ... , 0346432
REPORTING
RESULT LIMIT
ND 2.0
PERCENT RECOVERY
RECOVERY LIMITS
65 (31 -134)
Calculations are performed before rounding to avoid round-off errors in calculated results .
•
UNITS
ug/L
Matrix ......... , WATER
METHOD
SW846 8041
•
' .•
•
LABORATORY CONTROL SAMPLE EVALUATION REPORT
GC Semivolatiles
Client Lot# ... : C0L090140 Work Order# ... : DQ79TlAC-LCS
DQ79TlAD-LCSD
12/14/00
Matrix ......... : WATER
LCS Lot-Sample#: C0Lll0000-432
Prep Date ...... : 12/11/00 Analysis Date .. :
Prep Batch# ... : 0346432
Dilution Factor: 1
PERCENT RECOVERY
PARAMETER RECOVERY LIMITS
2-Chlorophenol 80 (50 -1.31)
80 (SO -1.31)
2,4-Dichlorophenol 83 (53 1.34)
83 (53 -1.34)
4-Chloro-3-methylphenol 84 (62 -123)
83 (62 -123)
2,4,6-T~ichloro-81 (54 -143)
phenol
81 (54 -143)
Pentachlorophenol 73 (50 -126)
73 (SO -126)
PERCENT
SURROGATE RECOVERY
2,4-Dibromophenol 86
86
NOTE (S) :
Calculations are performed before rounding to avoid round-off errors in calculated results.
Bold prim denotes comrol parameters
RPD
RPD LIMITS METHOD
SW846 8041
0.22 (0-20) SW846 8041
SW846 8041
0.020 (0-20) SW846 8041
SW846 8041
0.68 (0-20) SW846 8041
SW846 8041
0.11 (0-20) SW846 8041
SW846 8041
0.090 (0-20) SW846 8041
RECOVERY
LIMITS
(31 -1.34)
(31 -134)
•
•
LABORATORY CONTROL SAMPLE EVALUATION REPORT
GC/MS Semivolatiles
Client Lot# ... , C0L090140 Work Order# ... , DRDLElAC
LCS Lot-Sample#, C0L140000-092
Prep Date ...... , 12/13/00 Analysis Date .. , 12/17/00
Prep Batch# ... , 0349092
Dilution Factor: 1
PERCENT RECOVERY
PARAMETER RECOVERY LIMITS
2-Chlorophenol 65 (19 -124)
1,4-Dichlorobenzene 58 (28 -110)
N-Nitrosodi-n-propyl-55 (30 -115)
amine
1,2,4-Trichloro-64 (31 -110)
benzene
4-Chloro-3-methylphenol 58 (29 -124)
Acenaphthene 68 (39 -118)
4-Nitrophenol 62 (19 -144)
2,4-Dinitrotoluene 67 (47 -131)
Pentachlorophenol 82 (10 -140)
Pyrene 81 (46 -130)
Phenol 57 (10 -131)
PERCENT
SURROGATE RECOVERY
Phenol-d5 59
2-Fluorobiphenyl 65
Nitrobenzene-dS 64
Terphenyl-dl4 71
2-Fluorophenol 55
2,4,6-Tribromophenol 81
NOTE (S) ,
Calculations are performed before rounding to avoid round-off errors in calculated results.
Bold print denotes control parameters
Matrix ......... , WATER
METHOD
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
RECOVERY
LIMITS
(10 -113)
(30 110)
(3 2 -112)
(10 -144)
(13 110)
(21 122)
•
•
•
ANALYTICAL REPORT
PROJECT NO. RALEIGH
Raleigh-Bi-Weekly NPDES
Lot~' C0L210197
Debbi Leuteritz
ThermoRetec
SEVERN TRENT LABORATORIES, INC.
~£,~6
Veronica Bortot
Project Manager
January 3, 2001
STL Pittsburgh is a part of Severn Trent Laboratories, Inc.
-~-
STL Pittsburgh
450 William Pitt Way
Pittsburgh, PA 15238-1330
Tel: [phone]
Fax: [phone]
www.stl-inc.com
•
•
•
METHODS SUMMARY
COL210197
PARAMETER
Phenols by GC
Semivolatile Organic Compounds by GC/MS
References:
ANALYTICAL
METHOD
SW846 8041
SW846 8270C
PREPARATION
METHOD
S1'1846 3520C
S1'1846 3520C
SW846 11 Test Methods for Evaluating Solid Waste, Physical/Chemical
Methods 11 , Third Edition, November 1986 and its updates .
• SAMPLE SUMMARY
COL210197
~ SAMPLE# CLIENT SAMPLE ID
DRVDL 001 EFF.SV-305
NOTE(S)
• The analytical results of the samples listed above are presented on the fo!lowing pages.
-All calculations are performed before rounding to avoid round-off errors in calculated results.
-Results noted :is "ND" were not detected at or ahove the stated limit.
-This report must not be reproduced. except in full, without the writ1en approval of the laboratory .
• Results for the following parameters arc never reported on a dry weight basis: color, corrosivity, density, nashpoint, ignitability, byers, odor,
paint filter test, pl!, porosity pressure, reactivity, redox potential. specific gravity, spot tests, solids, solubility, temperature, viscosity, and weight.
•
•
DATE TIME
12/20/00 14, so
•
•
•
Sample Receiving:
CASE NARRATIVE
THERMORETEC CORPORATION
Raleigh
SIL Lot# C0L210197
SIL Pittsburgh, PA received one sample on December 21,2000 in good condition. The
cooler was at proper temperature range.
GC/MS Semivolatiles:
There were no problems associated with the analysis.
GC Phenols:
There were no problems associated with the analysis .
• ■ • ls!EVERN_ • Chain of
Custody Record Severn Trent Laboratories, Inc.
5, L--! \ 4 ' Client Project Manager Date
1
/4 Chain of Custody Num:Je_r
Tl-/-/.£01-Jo L¼✓¼:....G ,e,TA lA~ (2-2,• 0 f"'\ ij 1·11 G> CJ:;:, . -~-. 1.J ...... -
Address 19p;o; f j;, 'AfYc~ra, Numbe,
Lab Number
]00 f:,Atff/L, Ava: S V / T1Z., 3 0 ::2..,. Page I of I
Cl/y IM 1'~~1\.'A Site Conract Lab Contact Analysis (Attach list if
r-: o r-1 CA /JJ more soace is needed)
Prf]~atio/~tiZJ£Jf Carrier/lNaybi/1 Number
f./0 A 1 /ful?lv£ 9]90 'fJ{;,·7'( Special Instructions!
Conlrac//Purchase Orde!iOuote No Containers & Conditions of Receipt
Matrix Preservatives -...... . • ~ g
Sample /.0. No. and Description ' e 0 ~ , ", ~ i-J
Date Time ii ti -a ~ ~ 0 G 0 ,o (),, (Containers for each sample may be combined on one line) ~ ~ § ~ ~ 1 ~~ ' ~ , , ,
2 (0700
17,Cr. __s-v--.JoS-ri,l~lco I '{J'C ' \ 1 Y. .
'
Possible Hazard /denti/1cation I Sample Disposal
0 Non-Hazard D Flammable D Skin Irritant D Poison B D Unknown D Return To Client D Disposal By Labt\ 0 Archive For
(A lee may be assessed if samples are retained
Months longer than 3 months)
Turn Around Time Required QC · \nts (jPecify) /\ . ,: lli1/.t-D 24 Hours D 48 Hours D 7 Days D 14 Days 0 21 Days D Oiher / I I ;
1. Relinquished By ./ .!/_;;(;_
1
Date I ~7-a· 1. Received ffi.,:__ ~{,/ J ' l°ul1~y ~~ JU rz,Jt.,,/oa ~ ' -. // ,.../} / , ~ "" 2. Relinquished ti.I 1/v I Dale [ Time 2. Received By l°·t r 1
Time
r
3, Relinquished By
1
0a/e
1
Time 3. Received By
1
Date j Time _.,..,,:,~·
.
Comments
DISTRIBUTION: WHITE -Stays with the Sample: CANARY -Returned to Client with Report: PINK -Field Copy
•
... ,. ~ '·-
•
,//_d
Cooler Receipt Form
STL Pittsburgh
Client: ---,-r-1~·-c.e-~>--. ~---~&_;{/~·---------_Proj;;tt
Coo I er Rec'd & 0 pen ed far Temp. Cheek on ___ ..ci-e:.~.L-Jf/-= .:7;·7
7· ~cc' '-:::.',----,'--------/''---1--r+--
Coo lers Opened and Unpacked on: ________ /'--_l_,,_/~-~~7,,/2c...c""-"-'~1cek'-L../0""r'-, ___ _ -. / I I (Signature)
,. r> .. l l'J / / L~l, ij SIL Pittsburgh Lot Number: _"-__ '-'_· ·· __ ---'cl'-'-: c....· .::_:l_) _.L.-"-...J~1,--------------------
I. Were custody seals on the outside of the cooler?
IfYES, how many and where? Quantity_ Location
\Vere signatures and date correct? ___________________ _
2. Were custody papers included inside the cooler? ______________ _
' .J .. Were custody papers properly filled out (ink, signed, match labels)? _______ _
4 Did you sign the custody papers in the appropriate place? ___________ _
5.
6 .
Was shippers packing slip attached to this form? ______________ _
:::·:::::;ri•lsosed? c:zfH_l~.
7. Were the samples chilled? (Record temperatures on reverse side.)-------'---
8. Were the samples appropriately preserved? ________________ _
9. \Vere all bottles sealed in separate plastic bags? ______________ _
10. Did all bottles arrive in good condition (unbroken)? _____________ _
11 Were all bottle labels complete (sample ID, preservatives, etc.)?--,---~----
12. Did all bottle labels and/or tags agree with custody papers?· __________ _
13. · Were correct bottles used for tests indicated? _______________ _
14. Were all VOA vials checked for the presence of air bubbles? __________ _
~-
/_
/
_,,/
~-
~ 15. Was a sufficient a~..;;;,,,.,ss's·a.,.., -1° sent in each bottle? ____________ _
16. Samples re7ed /: FEDEX S CLIENT DROP-OFF OTHER A.IRBOR..l"'TE
Explain any di/epancies: '--c==,..L=--------------------~------
• Level 2 Review-::----------------------------------
Was com1cted on· ________ by ______________ to resolve discrepancies.
STL PT,'fcb--,'JC!/96-005/COOL.DOC Page 1 of 2
..
•
I
•
T:,!ET D},!ET HG
Sa.mpk 1D PH-:: PH<: PH<:
I
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1..,001er Kece1pt Form
STL Pittsburgh
CG
NlJT(I) CI TPH'C P!-...:EN SULF
PH<:! PH;c:J'.! PH< PH~ P!-f~I:
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TOC TOX VOA
PH<'2 PH-::: ?:l,"'P
•.•
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P: Preserved
UP: Unprese:-,:ed
hrtlm...
P:-i<.:
I
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I
I ( 1) '~NUT' could rnclude sample bottles for ammorua, chem1cJ.! oxygen demand, rutrate!rutnte, TKN', or total phosphorus
Comments: ----------------------------------------
Cooler Number -Temperature Bottle Type Lot Number* (-;t~-I -I I I I I I I
I I
I
I I I
I ' I
"' Ple:ise use an aste:isk if bottle lot number was covered by the !abel.
STL PT,'Feb-00/96-005/COOL. DOC P1ge2of2
• + 0 • • • • •
•
•
•
• I
• .i ®'2 ! 3 F0dfi l"''"'Y rl"mber 8250319571.
Address '/}c) r-{Ji/f,, dvt /~ ?T. ,;.,r.,.f-11/
lo"IIOlD"a1feObloe>boo,prr1tF..Jbad<Jr .. , 1
Phone C..1/ 2 4a Express Package Service Packages up lo 150/bs. ~ D_,.,. <""'"'"'"'" m:ry .. ..,,., ., """"aoe•• [ FedEx Priority_Overrnght D Fl!dEx Standard Overnight [] ruiJE., First Ovw1iglit Nmbusln,»lll(l<nlllj No'1buY>ess•~.,_ £.,....i..,,1,.,..,.._,,.,.,....g 0 FedEx20ay• secmt_....dav 4b Express Freight Setvice O ~:1~al.;reight" 'Cdlo<Ccnlinnaolin: 5 Packaging D FedEx Envelope/ Letter• D FedEx Express Saver• Hllllbusrlessday □ FedEx 20ay Freight Secondi,wn,,sday 0 FedEx Pak" ~ ... ,_,bu_,. Packages over 150 lbs. ~c""""""'9n1may0Plal.,.,.,.,...,.,, ~Other Pkg. lnt'lides FN(, &;,fedh Tolle, ,rt0ou11on,erpkg 6 Special Handling r--lnctod~fedhadd1essi11Soe1iofll --7 □ SATURDAYDefNCrf □ SUNDAY Delivery □HOlDWcekday □ HOLD Salurday A. r A,Wtilo....,lo<Ft<J<>,l'r..-..,. A,a.ti1eon1y10,fto£.Pno<..,. at FedEx Location at FedEx Lornl1on V ,0 }/,_ 7 ... ?'.J /' . ..._, •-0v<N"l)IU ond fe,JU Wav Ovt!rnighl to S<lm ZIP codes Not ava .. lje WIIJ> Avaial>o <>11'/ lur Foclh Pr Kiri!\' r} c;c,V _). _ • IOS1J1mZIPcOOes F<OExFnt~ QvCffll9'll..-.if1'0h10ay IOsdeCtkw;lllDII!, ( Does lhis shipmen! coritain dar,gerous goods? ,_ ___ Onebu•n,,..tboch.er~oll
D ~.~Yc(~furrnM~--•--'• D Ca1go Aircraft Only
D No D l';!,mctied D ~r"10Kbro1100
Shlppl<',Oodllr...,.. nc1,_td
I 0""'l'OIOUIGood>•-be~OlrodE,padaPIII
' 7 Payment Bill to: D Ol,1ain llccip
W<0o'1notde~r1oPO bo,e,orPO ZIPcOO•'-) . f.Jft EnterfcdbAccl lfo ,,rC•e•J11Caidl/o he.low ·--.-··-1 A~,! N1,
\
1, D Sender ecipient D Third Party O Credit Card O Cash/Check
t .lcclNo.01Soc1D> •
,·~bllbiled. _ • --------------------------~o,~,,,,..=,~.~ .. ,~-.. = '-,.~ '~15
' \_Total Packages TotalWeighl
. ~~,~-l :3 I $ .00
rO:~~ "'ii ~ed le S\00 lness ·;,,u declare a t.gt,~r value. See b.>c~ kn d~h
8 Release Signature S,gnmacd/lo,ilt!<k/NM-...u,o,~01iw,.,19.,g,,,""•
By "'!JOII!) yW tuthoriie us ID deM!r this shipment Wllhoul obt•Hllg a ,,g ... n.e and agreo ra indemn,tv and hold us harmles,; from any resul!o,g clauns
Ouestions7 Visit our Web site at www.fedex.com
or ca~ 1·800-Go•fe<JE,< 1800N63·3JJ9
,q,,,.a,,,1.w-r.,,,,15491s•fN'l1-'-11UJF,,![,,lflill//Oll//$A G8FE taro
CrodilC.,d/lud'I. ~ ·t.: •
136 □1 • I
•
•
•
THERMORETEC CORP
Client Sample ID, EFF.SV-305
GC/MS Semivolatiles
Lot-Sample# ... , C0L210197-001 Work Order# ... , DRVDLlAA
Date Received .. , 12/21/00
Analysis Date .. , 01/02/01
Matrix ......... , WATER
Date Sampled ... , 12/20/00
Prep Date ...... , 12/27/00
Prep Batch# ... , 0362279
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Phenol
SURROGATE
Phenol-d5
2-Fluorobiphenyl
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorophenol
2,4,6-Tribromophenol
MS Run # ....... ,
Method ......... , SW846 8270C
REPORTING
RESULT LIMIT UNITS
ND 10 ug/L
ND 10 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
74 (10 -113)
54 (30 -110)
69 (32 -112)
75 (10 -144)
61 (13 -110)
77 (21 -122)
•
•
•
THERMORETEC CORP
Client Sample ID: EFF.SV-305
Lot-Sample# ... : COL210197-001
Date Sampled ... : 12/20/00
Prep Date ...... : 12/23/00
Prep Batch# ... : 0358129
Dilution Factor: 1
PARAMETER
Pentachlorophenol
SURROGATE
2,4-Dibromophenol
GC Semivolatiles
Work Order# ... : DRVDLlAC
Date Received .. : 12/21/00
Analysis Date .. : 01/02/01
Method ......... : SW846 8041
REPORTING
RESULT LIMIT
ND 2.0
PERCENT RECOVERY
RECOVERY LIMITS
75 (31 -134)
Matrix ......... : WATER
MS Run # .....•. :
UNITS
ug/L
•
•
METIIOD BLANK REPORT
GC Semivolatiles
Client Lot# ... , C0L210197 Work Order# ... , DR0LMlAA
MB Lot-Sample#, C0L230000-129
Analysis Date .. , 01/02/01
Dilution Factor: 1
PARAMETER
Pentachlorophenol
SURROGATE
2,4-Dibromophenol
NOTE (S),
Prep Date ...... , 12/23/00
Prep Batch# ... , 0358129
RESULT
ND
PERCENT
RECOVERY
79
REPORTING
LIMIT
2.0
RECOVERY
LIMITS
(31 -134)
Calcula1ions arc performetl before rounding to avoid round-off errors in calculated results .
UNITS
ug/L
•
Matrix ......... , WATER
METHOD
SW846 8041
• METHOD BLANK REPORT
GC/MS Semivolatiles
Client Lot# ... , C0L210197 Work Order# ... , DR14KlAA
MB Lot-Sample#, C0L270000-279
Analysis Date .. , 01/02/01
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Phenol
SURROGATE
Phenol-d5
2-Fluorobiphenyl
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorophenol
2,4,6-Tribromophenol
NOTE (S),
Prep Date ...... , 12/27/00
Prep Batch# ... , 0362279
REPORTING
RESULT LIMIT
ND 10
ND 10
PERCENT RECOVERY
RECOVERY LIMITS
61 (10 -113)
55 ( 30 -110)
60 ( 32 -112)
78 (10 -144)
51 (13 -110)
78 (21 -122)
• Calculations are performed before rounding to avoid round-off errors in c.ilculatcd results .
•
UNITS
ug/L
ug/L
Matrix ......... : WATER
METHOD
SW846 8270C
SW846 8270C
•
•
•
LABORATORY CONTROL SAMPLE EVALUATION REPORT
GC Semivolatiles
Client Lot# ... , COL210197 Work Order# ... , DROLMlAC-LCS
DROLMlAD-LCSD
Analysis Date .. , 01/02/01
Matrix ......... , WATER
LCS Lot-Sample#, COL230000-129
Prep Date ...... , 12/23/00
Prep Batch# ... , 0358129
Dilution Factor: 1
PERCENT RECOVERY
PARAMETER RECOVERY LIMITS
Pentachlorophenol 77 (50 -1.26)
77 (SO -126)
PERCENT
SURROGATE RECOVERY
2,4-Dibromophenol 80
Bl
NOTE (S) ,
C:ilculmions arc performed before rounding to avoid round-off errors in calculated results.
Bold prim denotes control parameters
RPD
RPD LIMITS METHOD
SW846 8041.
0.69 (0-20) SW846 8041.
RECOVERY
LIMITS
(31 -134)
(31 -134)
• LABORATORY CONTROL SAMPLE EVALUATION REPORT
GC/MS Semivolatiles
Client Lot# ... , COL210197 Work Order JI ... , DR14KlAC-LCS Matrix ......... : WATER
LCS Lot-Sample#, COL270000-279 DR14 KlAD-LCSD
Prep Date ...... : 12/27/00 Analysis Date .. : 01/02/01
Prep Batch# ... , 0362279
Dilution Factor: 1
PERCENT RECOVERY RPD
PARAMETER RECOVERY LIMITS RPD LIMITS METHOD
2-Chlorophenol 54 (19 -124) SW846 8270C
64 (19 -124) 16 (0-43) SW846 8270C
1,4-Dichlorobenzene 48 (28 -110) SW846 8270C
56 (28 -110) 14 (0-36) SW846 8270C
N-Nitrosodi-n-propyl-SB (30 -115) SW846 8270C
amine
64 (30 -115) 10 (0-36) SW846 8270C
1,2,4-Trichloro-53 (31 -110) SW846 8270C
benzene
60 (31 -110) 12 (0-37) SW846 B270C
4-Chloro-3-methylphenol 67 (29 -124) SW846 8270C • 77 (29 -124) 13 (0-55) SW846 8270C
Acenaphthene 62 (39 -118) SW846 8270C
71 (39 -118) 14 (0-35) SW846 8270C
4-Nitrophenol 72 (19 -144) SW846 8270C
82 (19 -144) 13 (0-34) SW846 8270C
2,4-Dinitrotoluene 69 (47 -131) SW846 8270C
78 (47 -131) 12 (0-32) SW846 8270C
Pentachlorophenol 70 (10 -140) SW846 8270C
77 (10 -140) 10 (0-56) SW846 8270C
Pyrene 75 (46 -130) SW846 8270C
87 (46 -130) 15 (0-31) SW846 8270C
Phenol 52 (10 -131) SW846 8270C
61 (10 -131) 15 ( 0-43) SW846 8270C
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Phenol-dS 56 (10 -113)
65 (10 -113)
2-Fluorobiphenyl 48 (30 -110)
55 (3 0 -110)
Nitrobenzene-dS 57 (32 -112)
65 (32 -112)
Terphenyl-dl4 66 (10 -144)
76 (10 -144)
2-Fluorophenol 46 (13 -110) • 54 (13 -110)
2,4,6-Tribromophenol 70 (21 -122)
76 (21 -122)
(Continued on next page)
•
•
•
LABORATORY CONTROL SAMPLE EVALUATION REPORT
GC/MS Semivolatiles
Client Lot# ... , C0L210197 Work Order# ... , DR14KlAC-LCS Matrix ......... , WATER
LCS Lot-Sample#, C0L270000-279 DR14KlAD-LCSD
SURROGATE
NOTE(S),
PERCENT
RECOVERY
Calculations are performed before rounding to avoid round-off errors in calculated results.
Bold print denotes control parameters
RECOVERY
LIMITS
•
Decernber 29. 2000
STL SACRAivIENTO PROJECT NUMBER: G0L 120243
PO/CONTRACT:
Rita Bauer
ThcrrnoRetec
9 Da111011111ill Square
Suite 3A
Concord, iv!A 0 1742-2851
Dear Ms. Bauer,
·----~-------
~SERVICES~ 'Ja<;",~,~-'~·-· .,;r_.,.,,
STL Sacramento
880 Riverside Parkway
West Sacramento, CA 95605-1500
Tel: [phone]
Fax: [phone]
www.stt-inc.com
• This report contains the analytical results for the sarnple received under chain of custody by
STL Sacrarnento on 12/9/00. This sarnplc is associated with your Beazer/Raleigh project.
The case narrative is an integral part oCthis report.
If you have any questions, please feel free to call me at [phone].
Sincerely,
Robert Weidenleld
Project Manager
STL Sacramento is a part of Severn Trent Laboratories, Inc.
• CASE NARRATIVE
STL SACRAMENTO PROJECT NUMBER G0L120243
The sample in this lot was received at 2 degrees C.
There were no anomalies associated with this project.
•
•
STL-Sacramento [phone]
•
•
QC Batcl1
Duplicate Control Sample
(DCS)
Duplicate Sample (DU)
Laboratory Control Sample
(LCS)
Matrix Spike and Matrix Spike
Duplicate (MS/MSD)
Method Blank (MB)
Surrogate Spike
STL Sacramento
Quality Control Definitions
A set of up to 20 field samples plus associated laboratory QC
samples that are similar in composition (matrix) and that are
processed within the same time period with the same reagent
and standard lots.
Consist of a pair of LCSs analyzed within the same QC batch
to monitor precision and accuracy independent of sample
matrix effects. This QC is performed only if required by
client or when insufficient sample is available to perform
MS/MSD.
A second aliquot of an _environmental sample, taken from the
same sample container when possible, that is processed
independently with the first sample aliquot. The results are
used to assess the effect of the sample matrix on the precision
of the analytical process. The precision estimated using this
sample is not necessarily representative of the precision for
other samples in the batch.
A volume of reagent water for aqueous samples or a
contaminant-free solid matrix (Ottawa sand) for soil and
sediment samples which is spiked with known amounts of
representative target analytes and required surrogates. An
LCS is carried through the entire analytical process and is
used to monitor the accuracy of the analytical process
independent of potential matrix effects.
A field sample fortified with known quantities of target
analytes that are also added to the LCS. Matrix spike
duplicate is a second matrix spike sample. MSslMSDs are
. carried through the entire analytical process and are used to
determine sample matrix effect on accuracy of the
measurement system. The accuracy and precision estimated
using MS/MSD is only representative of the precision of the
sample that was spiked.
A sample composed of all the reagents (in the same
quantities) in reagent water carried through the entire
analytical process. The method blank is used to monitor the
level of contamination introduced during sample preparation
steps.
Organic constituents not expected to be detected in
environmental media and are added to every sample and QC
at a known concentration. Surrogates are used to determine
the efficiency of the sample preparation and the analytical
process.
Source: STL Sacramento® Quality Control Program, Policy QA-003, Rev. 0, 8/19/96 . •
STL •Sacramento [phone] 2
•
•
•
WO#
DQ97H
Notes(s):
Sample#
1
Sample Summary
G0L120243
Client Sample ID
lNF/SV-101
Sampling Date
12/8/00 09:30 AM
The analylical results of the samples listed above are presented 011 the following pages.
All cnlcubtions arc performed before rounding to avoid round-off errors in calculated results.
Results noted as ·'ND" were not detected al or above the stated limit
This repon must 110 be reproduced, except in 1h11, without the written approval oftl1e laboratory.
Received Date
12/9/00 11 :55 AM
Rcsul1s for the followiug parameters arc never reponcd on a dry weight ba::.is: color, corrosivily, density, flnshpoint, ignitabiliry,
\ayers, odor. paint litter test. pH. porosity, pressure, reactivity, redox potential, specific gravity, sµot tests, so{ids, solubility,
tcmpcrn.1urc, viscosity, and weigh
STL-Sacramento [phone] 3
Ji ~ i;1Chain o • (f> '/!Custody Record
ID 3 roauA 412-1 0797 C
0 Client fl>o-f-i
,-11.,,_.,r MO ' ' t,,
Project~~-\c: I c.. I,,.~ ~ k.., "'-
Address Telephone Number (Area Code)/Fax Number
3:>o ??ak-"-,-Avt. C(Ti-1-i 1-tii Z,
c;,y I State I Zip Code Site Conrac1 Lab Contact
lov1cc,J 1114 {,I( 7 o.{ l, RAD-1,.,,,,,,--• Project Name { . Carrier;Waybi/1 Number G
'\lee,.,,,., R-0,141-\J
Contract/Purchase OrderiOuote No. Containers & ':;i Matrix PreseNalives :;;-
Sample I.D. No. and Description I ~ ~ ~ es 11a 12 Date Time l 'o " ~ ~ (Containers for each sample may be combined on one lino) ~ § ~ ~ ~~
:J.NF / Sil-iol r2lilo"' o9?o f f.. )',..
<O
E! w
w u,
0,
0
Possible Hazard Identification I Sample Dispose/ tsJ -Non-Hazard O Flammable D Skin Irritant D PoisonB D Unlmolffi O Return To Client ~Disposal 8y Lab D Archive For
Turn Around Time Required
0 24 Hours '5T0 oc_ Reqwrements (Specify)
D 7 Days D 14 Days D 21 Days
Time
)'. o, OD
2. Relinquished By Time
3. Relinquished By Time
Comments
DISTRJ8UT10N: . WHITE· Stays with tho Sample; CANARY· Returned to Client ~·ith Report; PINK· Field Copy ..
Jn~ ' .. ~uanaerra •
Dali'?,,/ g I bD Chain of Custody Number
Lab Number
Page J or
Analysis (Anach list if
more s ace /s needed
L
Special Instructions/
Conditions of Receipt
ai.tiod
(/ AP-(.,_;,::;,..Ac)
'
(A lee may be assessed if samples are retained
Months longer than 3 months)
•
WATER, 8290, Dioxins/Furans,
•
•
STL•Sacramento [phone] 9
• THERMORETEC CORP
Client Sample ID: INF/SV-101
Trace Level Organic Compounds
Lot-Sample# ... : GOL120243-001 Work Order# ... : DQ97HlAA Matrix ......... : WATER
Date Sampled ... : 12/08/00 Date Received .. : 12/09/00
Prep Date ...... : 12/14/00 Analysis Date .. : 12/21/00
Prep Batch # ... : 0349162
Dilution Factor: l
DETECTION
PARAMETER RESULT LIMIT UNITS METHOD
2,3,7,8-TCDD ND 2.7 pg/L SW846 8290
Total TCDD ND 2.7 pg/L SW846 8290
1,2,3,7,8-PeCDD ND 4.4 pg/L SW846 8290
Total PeCDD ND 4.4 pg/L SW846 8290
l,2,3,4,7,8-HxCDD ND 2.6 pg/L SW846 8290
1,2,3,6,7,8-HxCDD ND 2.5 pg/L SWB46 8290
1,2,3,7,8,9-HxCDD ND 2.4 pg/L SW846 8290
Total P.xCDD ND 2.6 pg/L SWB46 8290
1,2,3,4,6,7,8-HpCDD ND 2.3 pg/L SW846 8290
Total HpCDD ND 2.3 pg/L SW846 8290
OCDD ND 15 pg/L Sv/846 8290
2,3,7,8-TCDF ND 3.9 pg/L SW846 8290 • Total TCDF ND 3.9 pg/L SW846 8290
1,2,3,7,B-PeCDF ND 2.4 pg/L SW846 8290
2,3,4,7,8-PeCDF ND 2.4 pg/L SW846 8290
Total PeCDF ND 2.5 pg/L SW846 8290
1,2,3,4,7,8-HxCDF ND 1.6 pg/L SW846 8290
1,2,3,6,7,8-HxCDF ND 1.4 pg/L SW846 8290
2,3,4,6,7,8-HxCDF ND 1.6 pg/L SW846 8290
1,2,3,7,B,9-HxCDF ND 1.8 pg/L SW846 8290
Total HxCDF ND 1.8 pg/L SW846 8290
1,2,3,4,6,7,8-HpCDF ND 1.2 pg/L SW846 8290
1,2,3,4,7,8,9-HpCDF ND 1.6 pg/L SW846 8290
Total HpCDF ND 1.6 pg/L SW846 8290
OCDF ND 2.7 pg/L SW846 8290
PERCENT RECOVERY
INTERNAL STANDARDS RECOVERY LIMITS
13C-2,3,7,8-TCDD 75 (40 135)
13C-1,2,3,7,8-PeCDD 75 (40 -135)
13C-1,2,3,6,7,8-HxCDD 69 (40 -135)
13C-l,2,3,4,6,7,8-HpCDD 93 (40 -135)
13C-OCDD · 100 (40 -135)
13C-2,3,7,8-TCDF 65 (40 -135)
13C-l,2,3,7,8-PeCDF 87 (40 -135)
13C-1,2,3,4,7,8-HxCDF 82 (40 -135)
13C-l,2,3,4,6,7,8-HpCDF 86 (40 -135)
•
$TL-Sacramento [phone] 10
•
SAMPLE#
001
•
•
STL-Sacramento
QC DATA ASSOCIATION SUMMARY
GOL120243
Sample Preparation and Analysis Control Numbers
MATRIX
WATER
ANALYTICAL
METHOD
SW846 8290
LEACH
BATCH#
[phone]
PREP
BATCH#
0349162
MS RUN#
11
' .
• METHOD BLANK REPORT
Trace Level Organic Compounds
Client Lot# ... : G0L120243 Work Order# ... : DRDRDlAA Matrix ......... : WATER
MB Lot-Sample#: GOL140000-162
Prep Date ...... : 12/14/00
Analysis Date .. : 12/20/00 Prep Batch # ... : 0349162
Dilution Factor: 1
DETECTION
PARAMETER RESULT LIMIT UNITS METHOD
2,3,7,8-TCDD ND 2.2 pg/L SW846 8290
Total TCDD ND 2.2 pg/L SW846 8290
1,2,3,7,8-PeCDD ND 4.1 pg/L SW846 8290
Total PeCDD ND 4.6 pg/L SW846 8290
1,2,3,4,7,8-HxCDD ND 3.l pg/L SW846 8290
1,2,3,6,7,8-HxCDD ND 3.2 pg/L SW846 8290
1,2,3,7,8,9-HxCDD ND 2.9 pg/L SW846 8290
Total HxCDD ND 3.2 pg/L SW846 8290
1,2,3,4,6,7,8-HpCDD ND 3.6 pg/L SW846 8290
Total HpCDD ND 3.6 pg/L SW846 8290
OCDD ND 7.4 pg/L SW846 8290
2,3,7,8-TCDF ND 1. 8 pg/L SW846 8290 • Total TCDF ND 1.8 pg/L SW846 8290
1,2,3,7,8-PeCDF ND 1.8 pg/L SW846 8290
2,3,4,7,8-PeCDF ND 1. 7 pg/L SW846 8290
Total PeCDF ND 1.8 pg/L SW846 8290
1,2,3,4,7,8-HxCDF ND 2.3 pg/L Sv1846 8290
1,2,3,6,7,8-HxCDF ND 2.1 pg/L SW846 8290
2,3,4,6,7,8-HxCDF ND 2.3 pg/L SW846 8290
1,2,3,7,8,9-HxCDF ND 2.5 pg/L SW846 8290
Total HxCDF ND 2.5 pg/L SW846 8290
1,2,3,4,6,7,8-HpCDF ND 2.4 pg/L SW846 8290
l,2,3,4,7,8,9-HpCDF ND 3.l pg/L SW846 8290
Total HpCDF ND 3.1 pg/L SW846 8290
OCDF ND 3.7 pg/L SW846 8290
PERCENT RECOVERY
INTERNAL STANDARDS RECOVERY LIMITS
13C-2,3,7,8-TCDD 62 (40 -135)
l3C-l,2,3,7,8-PeCDD 59 (40 -135)
13C-l,2,3,6,7,8-HxCDD 64 (40 -135)
13C-1,2,3,4,6,7,8-HpCDD 77 (40 -135)
13C-OCDD 85 (40 -135)
13C-2,3,7,8-TCDF 50 (40 -135)
13C-l,2,3,7,8-PeCDF 77 (40 -135)
13C-l,2,3,4,7,8-HxCOF 76 (40 -135)
13C-l,2,3,4,6,7,8-HpCDF 79 (40 -135)
NOTE(S):
• Calculalions are performed before rounding 10 avoid round-off errors. in calculated resulis.
STL-Sacramento [phone] 12
• LABORATORY CONTROL SAMPLE DATA REPORT
Trace Level Organic Compounds
Client Lot# ..• , G0L120243 Work Order# ... , DRDRDlAC Matrix ......... : WATER
LCS Lot-Sample#: G0L140000-162
Prep Date ..••.• , 12/14/00 Analysis Date .. , 12/20/00·
Prep Batch# ... , 0349162
Dilution Factor: l
SPIKE MEASURED PERCENT
PARAMETER AMOUNT AMOUNT UNITS RECOVERY METHOD
2,3,7,8-TCDD 200 200 pg/L 100 SW846 8290
1,2,3,7,B-PeCDD 1000 1030 pg/L 103 SW846 8290
1,2,3,4,7,8-Hx.CDD 1000 1080 pg/L 108 SW846 8290
1,2,3,6,7,8-HxCDD 1000 1040 pg/L 104 SW846 8290
1,2,3,7,8,9-HxCDD 1000 980 pg/L 98 SW846 8290
1,2,3,4,6,7,8-HpCDD 1000 960 pg/L 96 SW846 8290
OCDD 2000 1970 pg/L 98 SW846 8290
2,3,7,8-TCDF 200 192 pg/L 96 SW846 8290
1,2,3,7,8-PeCDF 1000 933 pg/L 93 SW846 8290
2,3,4,7,8-PeCDF 1000 570 pg/L 57 SW846 8290
1,2,3,4,7,8-HxCDF 1000 1010 I>9/L 101 SW846 8290
1,2,3,6,7,8-RxCDF 1000 924 w/L 92 SW846 8290 • 2,3,4,6,7,8-HxCDF 1000 679 pg/L 68 SW846 8290
1,2,3,7,8,9-HxCDF 1000 938 I>9/L 94 SW846 8290
1,2,3,4,6,7,8-HpCDF 1000 1040 f)9/L 104 SW846 8290
1,2,3,4,7,8,9-HpCDF 1000 986 I>9/L 99 SW846 8290
OCDF 2000 1900 w/L 95 SW846 8290
PERCENT RECOVERY
INTERNAL STANDARD RECOVERY LIMITS
13C-2,3,7,8-TCDD 62 (40 -135)
13C~1,2,3,7,8-PeCDD 59 (40 -135)
13C-l,2,3,6,7,8-HxCDD 65 (40 -135)
13C-1,2,3,4,6,7,8-HpCDD 75 (40 -135)
13C-OCDD 84 (40 -135)
13C-2,3,7,8-TCDF 46 (40 -135)
13C-l,2,3,7,8-PeCDF 80 (40 -135)
13C-l,2,3,4,7,8-HxCDF 81 (40 -135)
13C-l,2,3,4,6,7,8-HpCDF 83 (40 -135)
NOTE (S) :
Calculations are performed before rounding to avoid round-off errors in ca1culated results.
Bold print denotes conrrol parameters
•
STL-Sacramento (916) 373·5600 13
•
•
•
. '
LABORATORY CONTROL SAMPLE EVALUATION REPORT
Trace Level Organic Compounds
Client Lot# .•. : G0L120243 Work Order# ... : DRDRDlAC
LCS Lot-Sample#: G0L140000-162
Prep Date ...... : 12/14/00 Analysis Date .• : 12/20/00
Prep Batch# ... : 0349162
Dilution Factor: 1
PERCENT RECOVERY
PARAMETER RECOVERY LIMITS
2,3,7,8-TCDD 100 (73 -144)
1,2,3,7,8-PeCDD 103 (85 -131)
1,2,3,4,7,8-BxCDD 108 (58 -146)
1,2,3,6,7,8-HxCDD 104 (80 -131)
1,2,3,7,8,9-Hx.CDD 98 (60 -154)
1,2,3,4,6,7,8-HpCDD 96 (78 -134)
OCDD 98 (73 -144)
2,3,7,8-TCDF 96 (70 -135)
1,2,3,7,8-PeCDF 93 (79 -136)
2,3,4,7,8-PeCDF 57 (56 -154)
1,2,3,4,7,8-HxCDF 101 (77 -124)
1,2,3,6,7,8-HxCDF 92 (69 -135)
2,3,4,6,7,8-BxCDF 68 (SB -140)
1,2,3,7,8,9-HxCDF 94 (58 -141)
1,2,3,4,6,7,8-HpCDF 104 (80 -115)
1,2,3,4,7,8,9-HpC:OF 99 (68 -151)
OCDP 95 (64 -152)
PERCENT
INTERNAL STANDARD RECOVERY
13C-2,3,7,8-TCDD 62
13C-1,2,3,7,8-PeCDD 59
13C-1,2,3,6,7,8-HxCDD 65
13C-1,2,3,4,6,71 8-HpCDD 75
13C-OCDD 84
13C-2,3,7,8-TCDF 46
13C-l,2,3,7,8-PeCDF 80
13C-1,2,3,4,7,8-HxCDF 81
13C-l,2,3,4,6,7,8-HpCDF 83
NOTE(S):
Calculations are pcrfonned before rounding to avoid round-off errors in calculated results.
Bold prim denotes control parameters
Matrix ......... : WATER
METHOD
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
SW846 8290
RECOVERY
LIMITS
(40 -135)
(40 -1.35)
(40 -1.35)
(40 -135)
(40 -135)
(40 -135)
(40 -135)
(40 -135)
(40 -135)
STL-Sacramento (916) 373·5600 14
•
•
•
ThermoRetec Corporation
300 Baker Avenue, Suite 302
Concord, MA 01742
December 14, 2000 ---~-=-=·-· fhermoRetec IE t IE U '¥} \E If\\ Smart Solut,ons. Pos,t,ve Outcomes.
Ms. Beverly Hudson
Remedial Proj cct Manager
DEC 2 l 2000 1\lJJ [phone] Phone
[phone] Fax
www. thermoretec.cam
U.S. EPA -Region IV, 11 th Floor
North Site Management Branch
6 1 Forsyth S tree!, SW
SUPERFUNO SECTION
Atlanta, GA 30303
RE: Monthly Progress Report #91
Remedial Action
Koppers Site -Morrisville, NC
Dear Ms. Hudson:
Enclosed please find four copies of the laboratory report for the Dioxin sampling performed on
November 21, 2000. This data was received after our December 8, 2000 submission of Progress
Report #90. Because this data was not recorded in Report #91, we are including four corrected
copies of the Groundwater Treatment Analytical Data Summary table (Table 2) .
Should you need additional information regarding this progress report, please call Mike Slenska at
[phone] or me at [phone].
Sincerely,
ThermoRctec Consulting Corporation
~ \
Rita BaueP ~" f:-,"JS
Project Geologist
RB:cg
Enclosure
cc: 'l!)-_Mattison -NC Superfund (2 copies) "'i
D. Hails -Ecological Restoration, Inc.
.l. Garrett -NC Division of Water Quality
P. Kilchenstein -ThcrmoRetec
D. Matthews -NC Division of Water Qua!.
F: \PROJ ECTS\03624 \Repons\M onth!y\Huds 1214. wpd
M. Slenska -Beazer
L. Faulconer -Wake County
G. Caskey -En wood Structures
M. Helbling -Beazer
a Thermo Electron company
•
•
•
MONTHLY PROGRESS REPORT #91
REMEDIAL ACTION
SITE NAME: Koppers Superfund Site
Beazer East, Inc.
Morrisville, NC
USEPADOCKETNUMBERS: 9~0~C
PERIOD ENDING: November 30, 2000
1. PROGRESS MADE THIS MONTH
2.
3.
4.
5.
6.
Remedial Action (RA) -HABITAT MITIGATION. No activities were conducted this
month.
Remedial Action (RA) -GROUNDWATER TREATMENT. The treatment system
operated throughout the month without upset. System performance was monitored
on a biweekly basis. Approximately 39,437 gallons of groundwater were extracted,
treated in the treatment plant and discharged between October 31, and November
28, 2000. System water samples were collected on November 8, 2000 and
November 21, 2000 in accordance with the sampling schedule in the O&M manual.
Samples were submitted to Severn Trent and TriTest for laboratory analysis. The
operations and sampling programs are summarized on the attached Table 1 .
Remedial Action (RA) -EFFECTIVENESS MONITORING PROGRAM. No activities
were conducted this month.
Remedial Action (RA) -CORRESPONDENCE. None.
PROBLEMS RESOLVED
PROBLEMS ANTICIPATED
UPCOMING EVENTS
PERSONNEL CHANGES
SUBCONTRACTORS
None.
None.
Continue System O&M.
None.
None.
7. ANALYTICAL DATA Analytical data from system influent and effluent sampling
received during this period are enclosed and are summarized on Table 2 .
F: \PR OJ ECTS\03624 \Reports \M onthl y\H uds 1214. wpd
Date Systems Cummulaiive SV-101 SV-10!
Check Effluent Flow Sample Sample
(vcs/no) (Gallons) (yes/no) Parameters
01/04/00 "' 2.178,450 '" 01/20/00 m 2.201.060 00
02/02/00 ves 2.222.900 00
02/18/00 m 2,250,320 00
03/03100 "' 2,275.240 00
03/13/00 "" 2,294,030 00
04/12/00 yes 2,347,700 '" 04'24/00 m 2,371,150 00
05/05/00 "' 2,387.750 00
0::,/15/00 ves 2,411.760 00
05/31/00 "' 2,441.250 00
06/14/00 ves 2,462,390 00
06/26/00 m 2,481.440 00
07/06/00 "' 2,497.950 00
07/l 1/00 "' 2,505,2IO 00
07/17/00 "' 2,513,700 "" 2,4-Dichloro, Phenol
08/01/00 yes 2,536,540 00
08/14,00 "' 2,556,590 00
09/05/00 "" 2,591,501 00
09/27/00 "' 2,635,455 00
l0/13/00 "' 2,656.712 00
I0/24/00 ves 2,667,340 "' Penta, 2,4-Dichloro, Phenol
11/08/00 ves 2,688,980 00
11/21/00 "' 2.705,8-40 00
Notes:
Sampling point SV-101 is localed before the Carbon Units {pretreatment)
Sampling point SV-304 is located between the Carbon Units
Sampling point SV-305 is loctated after Ilic Carbons Units (post-treatment)
•
Table I
Groundwater Treatment Operations and S:impliog Progrnm Summary
Koppers Superfund Site
l\lorriHillc, North Carolina
Oc1ober 2000
Associated SV-304 SV-304 Associated
Group Sample Sample Group
(yes/no) Parameters
00
00
00
"' 2,4-Dichloro, Phenol I
00
00
00
00
00
00
00
00
00
00
00
I "' 2,4-Dichloro, Phenol I
00
00
no
00
00
I "' Penta, 2,4-Dich!oro, Phenol I
00
00
Associated Groups:
SY-IOI -Group! is penta and 2,4-dichlorophenol; Group 2 is dioxin
SV-304 -Group I is penta and 2,4-dichlorophenol
SV-305 SV-305
Sample Sample
(yes/no) Parameters
ve, Penta, 2,4-Dichloro, Phenol, chronic tox
ves Penta, 2,4-Dichloro, Phenol
ves Pema, 2,4-Dichloro, Phenol, chronic tax
"' Penta, 2,4-Dichloro. Phenol. dioxin
yes Penta, 2,4-Dichloro, Phenol
"' Penta, 2,4-Dichloro, Phenol
m Penta, 2,4-Dichloro. Phenol, chronic 101.
ves Penta, 2,4-Dichloro, Phenol
"' chronic to1.icitv
ves Penta, 2,4-Dich!oro, Phenol
yes Penta, 2,4-Dich!oro, Phenol
ves Penta, 2,4-Dichloro, Phenol , dio1.in, chronic to,;
"' Penta, 2,4-Dichloro, Phenol
"' Penta, 2,4-Dichloro, Phenol
ves chronic toxicity
"' Penta, 2,4-Dichloro, Phenol, dioxin
,·es Penta, 2,4-Dichloro, Phenol, chronic tox
m Penta. 2,4-Dichloro, Phenol
"' Penta, 2,4-Dichloro, Phenol, chronic tox
yes Penta, 2,4-Dichloro, Phenol
ves Penta, 2,4-Dichloro, Phenol
ves Penta, 2.4-Dichloro, Phenol , dioxin, chronic wx
m Penta, 2.4-Diehloro, Phenol
"' Penta, 2,4-Dichloro, l'henol
SV-305 -Group I is pcnta, phenol, and 2,4-dichlorophenol; Group 2 is dioxin and Group 3 is chronic toxicity
•
Associated
Group
1.3
I
1.3
!.2
I
I
I .3
I
4
I
I
I. 2. 3
I
I
3
L 2
I ,3
I
1,3
I
I
I. 2, 3
I
I
•
•
•
Par;in,cter
l'cutadth,ronl,c1~,I
Table 2
Groundwater Treatment
ANALYTICAL DATA SUM~IARY
Koppers Supcrfund Site
;\lorris,·ille, North Carolina
November 2000
A11.1.ly1ic>.l
Date Samplo
Sample UK.-:Ui"n
c.,11rc1"'1 sv.io1
Ol/04100
Oll'Z0/00
02102100
02/18100
OJIOJ/00
0)11)/00
04112100
(l-lf24100
05115100
05131/00
06114100
"'"""' 07/06100
07117/00
08/01100
08/14/00
09105100
09/27/00
10113100
1on4,oo " 11108100
llfWOO
2A-Dichlom heaol 01,'0-!l00
OJn0/00
02/IWOO
02/18100
OJ/Ol/00
0J/IJ/00
04112/00
04r.WOO
0511~/00
05/11/00
06114100
061'26100
07/06100
07117100
08/01/00
08/WOO
09/05/00
09n7/00
I0/13/00
lOr.!4100
!1/(18/00
!l/ll/00
Pl!<:lkll 0l/04/00
01/20/00
02102/00
02/ISIOO
03103100
03113100
04112100
04/'WOO
05115100
05131100
06114/00
06/26100
07/06/00
07/17/00
081(11/00
08114/00
09/05100
09127100
10113/00
10124/00
t !/08/00
ll/21/00
Chmnic T,,.ici•v 0!liJ.1100
0210!100
0-1/\2100
05/05100
06/14/00
07/11/00
08/01/00
0910,100
10n4,oo
JJ/08100
Dioxin (2.l,7,8,TCDD) Oll\S/00
0611~/00
07/17/00
1on.i100
! ll!~/00
Notes. 1111 rcsulis are"' ui/L <>ccpl tl"""'· Dmxm tl•bo" rn ~,,.,~r•uc<IL
SV-101 -Bdoto Cart.m UniL<
•~Y-J().j -Bcmeen CJrl>un Units
••SV-30S -Aller C0<l>on Units
18lS0 Mctl,uJ u«:tl
<IO
<IO
<IO
<IO
Sample S•mple
l.oc:uin11 Lo,::uion
sv.304• SV-305 ..
<l
<'
<l
<l <'
<,
<l
<' <l
<l
<l
<l
<l
<l
<l
<,
<l
<l
<,
<l
<l <l
<l
<l
<IO
<,0
<IO
<IO <'"
<,0
<'"
<W
«o
<"
<'" <,0
<'" <,0
<IO <IO
<IO
<'"
<"
<IO
<IO
<'" <'"
<IO
<'"
<'"
<IO
<IO
<'" «o
<IO
<IO
<IO
<'"
<IO
<IO
<'"
<IO
<IO
<IO <IO
«o
«o
<IO
<IO
<IO
<IO «o
«o
<IO
I'•"'
l'a,;s
Fail p._._,
F•il
Pa.~<
Fail
Fail
Fail
Fail
<U
<),q4
<0.863
<0.001541
<0,377
•
•
AW&i\4¥A
ALTA
December 13, 2000
Alta Batch I.D.: 9487
Ms. Rita Bauer
ThermoRetec Consulting Corporation
300 Baker A venue
Suite 302
Concord, MA 01742
Dear Ms. Bauer,
Enclosed are the results for the one aqueous samples received at Alta Analytical Laboratory on
November 22, 2000. This work was identified as project BEAZER/RALEIGH. This sample was
extracted and analyzed using EPA Method 8290 for 2,3,7,8-TCDD only. A standard turnaround
time was requested for this work.
The following report consists of a Sample Inventory (Section I), Analytical Results (Section ID and
the Appendix. The Appendix contains a copy of the chain-of-custody, a list of data qualifiers and
abbreviations, our current certifications, diskette deliverables, and copies of the raw data.
Alta Analytical Laboratory remains committed to serving you in the most effective manner.
Should you have any questions or need additional information and technical support, please do not
hesitate to contact me. Thank you for choosing Alta as part of your analytical support team.
Sincerely,
c-_·· I
'") . I 1 I I" , .· u..,.Ccu, 'r/1JJ_fl:.},,j':-1 :i --
('Shelly A/Weagraff ,1:r I I}. f_;l't ·,HRMS Services C:oordmator
Alta Analytical Laboratory Inc.
5070 Robert J. Mathews Parkway
El Dorado Hills, CA 95762
FAX [phone]
(916) 933· 1640
IA -ALTA
•
Section I: Sample Inventory Report
Date Received: 11/22/200
Alta Lab. ID Client Samnle ID
9487-00 I SV-101
•
•
•
•
•
TCDD
EPA METHOD 8290
METHOD BLANK
Matrix: , Aqueous
Date Received:
Date Extracted:
NA
12/6/00
Sample Amount: 1.000 L
Com[!ound
2.3.7.8-TCDD
Cone.
ND
Internal Standards %R
13C-2,3,7,8-TCDD 77.6
Clean-u[! Recovery Standard %R
37Cl-2.3.7.8-TCDD 91.1
Date Analyzed
Il..l!.ci:. 12/8/00
Analyst: RS Page I of I
DL
0.508
MDL
0.711
J1a -ALTA
Lab ID: 0-MBOOl
QC Set: l..,l8_0
Units: .MlL
Qualifier
Reviewer:
•
OPRRESULTS
Lab ID: OPR00l
Matrix: Aqueous
Compound
2,3,7,8-TCDD
Internal Standards
13C-2,3,7,8-TCDD
• Clean-up Recovery Standard
37CI-2,3,7,8-TCDD
Date Analyzed
DB-5: 12/8/00
• Analyst: RS.
TCDD
EPA METHOD 8290
Date Received: NA
Date Extracted: 12/6/00
Sample Amount: 1.000 L
Spike
Cone.
10.0
Spike
Cone.
Spike
Cone.
40.0
Page 1 of 1
Amount
Found
10.4
85.2
97.8
IA -ALTA
QC Set: 1 180
Units: ng/mL
OPR Limits
7 -13
OPR Limits
40-135
OPR Limits
40 -135
Reviewer:
•
•
•
TCDD
EPA METHOD 8290
Sample ID:
Project:
SV-101
BEAZER/RALEIGH
Matrix: Aqueous
Sample Amount: 0.974 L
Compound
2,3, 7,8-TCD D
Internal Standards
13C-2,3,7,8-TCDD
Clean-up Recovery Standard
37CI-2,3,7,8-TCDD
Date Analyzed
DB-5: 12/9/00
Analyst: RS
Date Received:
Date Extracted:
Cone.
ND
%R
89.0
%R
98.2
Page I of l
11/22/00
12/6/00
DL
0.377
MDL
0.711
/1.. -ALTA
Lab ID: 9487-001
QC Set: I 180
Units:
Qualifier
Reviewer: <'''. :::•,"-I,')
•
•
•
A
B
C
D
E
F
G
H
I
Cone.
D.L.
NA
SIN
*
ND
MPC
DATA QUALIFIERS & ABBREVIATIONS
The amount detected is below the Method
Calibration Limit. ·
This compound was also detected in the blank.
The amount detected is less than five times the Method
Quantitation Limit.
The amount reported is the maximum possible concentration.
The detection limit was raised above the Method Quantitation
Limit due to chemical interferences.
This result has been confirmed on a DB-225 column.
This result has been confirmed on a SP-2331 column.
The signal-to-noise ratio is greater than 10:1.
Chemical Interference
Concentration
Detection Limit
Not applicable
Signal-to-noise
See Cover Letter
Not Detected
Maximum Possible Concentration
J1a. -ALTA
•
CURRENT CERTIFICATIONS
Bureau of Reclamation-Mid-Pacific Region---(MP-470, Res-I. I 0)
Commonwealth of Kentucky---(Certificate No. 90063)
Commonwealth of Virginia---(Certificate No. 00013)
State of Alaska, Department of Environmental Conservation---(Certificate No. OS-00197)
State of Arkansas, Department of Health---(Approval granted through CA certification)
State of Arkansas, Department of Environmental Quality---
State of California---(Certificate No. 1640)
State of Connecticut---(Certificate No. PH-0182)
State of Florida---(Certificate No. 87456)
State of Louisiana---(Certificate No. 98-33)
State of Mississippi---(Approval granted through CA certification)
State of Nevada---(Certificate No. CA413)
State of New York, Department of Health---(Certificate No. 11411)
• State of North Carolina---(Certificate No. 06700)
State of North Dakota, Department of Health---(Certificate No. R-078)
State of Oregon---
State of Pennsylvania---(Certificate No. 68-490)
State of South Carolina---(Certificate No. 8700200 I)
State of Texas -(Certificate No. TX247-2000A)
State of Tennessee---(Certificate No. 02996)
State of Utah---(Certificate No. E-201)
State of Washington, Department of Ecology---(Certification No. C091)
State of \Visconsin---(Certificate No. 998036160)
State of Wyoming---(Ref: SES-LB)
U.S. Army Corps of Engineers
U.S. 5 EPA Region
• May2000
/11. -ALTA
STANDARD OPERATING PROCEDURE
• Attachment 10. B.1
SAMPLE LOG-IN CHECKLIST
94.'67 ALTA Project No.:--~---'---ClienUProtocol No. ___ ~JV __ /_1t ______ _
I. Date Samples Arrived: i/ / 2..--<-( oo Initials: #c Location: !.,;I(-/
2. Time I Date logged in: If-,,~ 7 -oo !/DO Initials: $.,b Location: !._uJ1--i
' ,
3. Samples Arrived By: (circle) ~ UPS World Courier Other:
4. Shipping Preservation: (circle) ~ Blue Ice / Dry Ice / None Temp °C y
YES NO NA
5. Shipping Container(s) Intact"? If not, describe condition in comment section. ;<-
6. Shipping Container(s) Custody Seals Present? r><'
Intact? If not intact, describe condition in comment section. ~
7. Shipping Documentation Present? (circle) Shipping Label G ;< Tracking Number "i? 2~6 3/ '1 S-< ( ~ 3
8. Sample Custody Seal(s) Present? No. of Seals or Seal No. K • Intact? .Jf not intact, describe condition in comment section. ;<
9. Sample Container Intact? If no. indicate sample condition in comment section. ;x_
10. Chain of Custody (COC) or other Sample Documentation Present? 'x
11. COC/Documentation Acceptable? If no, complete COC Anomaly Form. r--
12. Shipping Container (circle): ALTA~ Retain or~~ or Disposed
13. Container(s) and/or Bottle(s) Requested? /'<
14. Sample Control Check In/Out Log Completed?· (HRMS Only) ),<:
15. Drinking Water Sample? (HRMS Only) If yes, Acceptable Preservation? Y or N
Preservation Info From? (circle) coc or Sample Container or None Noted )<:
16. Number of Samples Received: /v'/✓,1,
Name: ________________ _ Date Samples Reconciled: _____ _
(Signature Required for LCMS Only)
Comments:
• SOP# CH10Br12, Page 4 of 6
Chain of
Custody Record
Client
,1-/£:e;n () &rE_r
Address
~~ A:0£ ,Ju;FZ-:Jo z_
City 1;; Zip Code
COvJ c.o,e/J or7yL
Project Name
8@_2£1/2--r('.Lfuz1tff
Contract/Purchase Orderltlf.Jote No.
Sample f.D. No. and Description Date Time
_,rl{_-/C> / I i/11 /or. ;s:-ax
Specml Instructions
Q, 1m;iten e:, lne. PiHslst-11 gl t PA Lab
420 JWlia:.: Pitt Wa,
RiU I gl Po 1 E??R::ai
Project Manager
_,TA 8Av. _,,,
Telephone Number (Area Code)/Fax Number
fci1?l 311 -1'12.L
I :i1te Contact
Carrier/Waybill Number
Total Containers Sample Type Volume Type No.
L1' 0 2. £,m;L 2
Preservative
/VD/Vb
0 Skin Irritant 0PoisonB □unknown D Return To Client
Project Specific (Specify) QC Level
3. Relinquished By Date Time 3. Received By
Comments
DISTRIBYTION , E · Stays with Sample; CANARY· Returned to Client with Report; PINK· Field Copy
Date 1d21/oo Chain Of Custody Number 67903
Lab Number J L Page of
Analysis
0 .]
.J'
~ 0
Condition on Receipt c:;
f.A.
I
I
D Disposal By Lab 0 Archive For Months
Date
•
•
•
December 8, 2000
Ms. Beverly Hudson
Remedial Project Manager
U.S. EPA -Region IV, 11 '" Floor
North Site Management Branch
61 Forsyth Street, SVV
Atlanta, GA 30303
RE: Monthly Progress Report #91
Remedial Action
Koppers Site -Morrisville, NC
Dear Ms. Hudson:
ThermoRetec Corporation
300 Baker Avenue, Suite 302
Concord, MA 01742
Smart Solutions. Positive Outcomes.
SUPERFUND SECTION
In accordance with the Unilateral Order, and on behalf of Beazer East, Inc. (Beazer), please find
attached four ( 4) copies of the November Monthly Progress Report for Remedial Action at the
Koppers Superfuncl Site in Morrisville, NC.
The dioxin sample was collected on November 22, 2000. Because the sample was collected late
in the month, the Laboratory results the will not be received until December 11, 2000. We will
submit a revised version of Table 2, along with the dioxin laboratory report within 7 clays of
receiving the data.
Should you need additional information regarding this progress report, please call Mike Slenska
at [phone] or me at [phone].
Sincerely,
TherrnoRetec Consulting Corporation
~)]{.~
Project Geologist
RB:cg
Enclosure
cc: D. Mattison -NC Superfund (2 copies)
D. Hails -Ecological Restoration, Inc.
J. Garrett -NC Division of Water Quality
P. Kilchenstein -ThcrmoRetcc
D. Matthews -NC Divisio'n of V\/ater Qua!.
F:\PROJ ECTS\03624\Rcrorts\Monthly\ 11 M-00. wp<l
M. Slenska -Beazer
L. Faulconer -Wake County
G. Caskey -Enwoocl Strucmres
M. Helbling -Beazer
a Thermo Electron company
•
•
•
MONTHLY PROGRESS REPORT #91
REMEDIAL ACTION
SITE NAME: Koppers Superfund Site
Beazer East, Inc.
Morrisville, NC
USEPA DOCKET NUMBERS: 93-09-C
PERIOD ENDING: November 30, 2000
1. PROGRESS MADE THIS MONTH
2.
3.
4.
5.
6.
7.
Remedial Action (RA) -HABITAT MITIGATION. No activities were conducted this
month.
Remedial Action (RA) -GROUNDWATER TREATMENT. The treatment system
operated throughout the month without upset. System performance was monitored
on a biweekly basis. Approximately 39,437 gallons of groundwater were extracted,
treated in the treatment plant and discharged between October 31, and November
28, 2000. System water samples were collected on November 8, 2000 and
November 21, 2000 in accordance with the sampling schedule in the O&M manual.
Samples were submitted to Severn Trent and TriTest for laboratory analysis. The
operations and sampling programs are summarized on the attached Table 1.
Remedial Action (RA) -EFFECTIVENESS MONITORING PROGRAM. No activities
were conducted this month.
Remedial Action (RA) -CORRESPONDENCE. None.
PROBLEMS RESOLVED None.
PROBLEMS ANTICIPATED None.
UPCOMING EVENTS Continue System O&M.
PERSONNEL CHANGES None.
SUBCONTRACTORS None.
ANALYTICAL DAT A Analytical data from system influent and effluent sampling
received during this period are enclosed and are summarized on Table 2 .
F: \I' ROJ ECTS\03624\Rcports\Momhly\ 11 r,..,t-00. wpd
•
Date Systems Cummu!ati\'e SV-IOI SV-101
Check Efnuent Flow Sample Sample
(yes/no) (Gallons) (yes/no) Parameters
01/04/00 ves 2,178.450 ao
01/20/00 m 2,201.060 ''° 02/02(()() ves 2.222.900 ao
02/18/00 \'CS 2.250.320 ao
03/03100 '" 2,275,240 ao
03/13/00 m 2.294,030 ao
04112/00 m 2,347.700 ao
04f2.4/00 \'CS 2.371.150 no
05/05/00 ,·es 2.387.750 ao
05/15/00 ves 2,411,760 ao
05/31/00 \'CS 2.441,250 ao
06/14/00 vcs 2,462,390 ao
06126/00 m 2.481.440 ao
07/06/00 VCS 2.497,950 ao
07/11/00 "' 2,505.2!0 ao
07/17/00 "' 2,513,700 \'CS 2,4-Dichloro, Phenol
08/01/00 "' 2,536.540 "° 08/14/00 "' 2.556.590 "° 09/05/00 "' 2,591,501 "° 09n7/00 \'CS 2,635,455 ao
10/13/00 vcs 2,656,712 "° 10/24/00 yes 2.667,340 ves Pcma, 2,4-Dichloro, Phenol
11/08/00 "' 2,688.980 "o
11(21/00 "' 2,705,840 ao
Notes:
Sampling point SV-101 is located before the Carbon Units (pretreatment)
Sampling poim SY-304 is located between the Carbon Units
Sampling point SY-305 is loctatcd after the Carbons Units (post-treatment)
•
Table I
Groundwater Treatment Operations and Sampling Program Summary
Koppers Superfund Site
l\lorrisville, North Caroliua
October 2000
Associated SV-304 SV-304 Associated
Group Sample Sample Group
(yes/no) Parameters
ao
ao
ao
ves 2.4-Dichloro, Phenol I
ao
,m
"° no
"° ao
ao
ao
ao
"° ao
I ves 2.4-Dichloro, Phenol I
"" "° ao
ao
"° I "' Penta, 2,4-Dichloro, Phenol I
''° ao
Associated Groups:
SV-101 -Group I is pema and 2,4,dichlorophenol; Group 2 is dioxin
SV-304 -Group I is pcnta and 2,4-dichloropheno!
SV-305 SV-305
Sample Sample
(yes/no) Parameters
"CS Pema. 2,4-Dichloro. Phenol. chronic tox
ves Penta. 2,4-Dichloro. Phenol
YCS Penta. 2.4-Dichloro, Phenol, chronic lox
\"CS Pema. 2,4-Dichloro, Phenol, dioxin
,·es Pema. 2.4-Dichloro, Phenol
ves Penta. 2.4-Dichloro. Phenol
"' Penta. 2.4-Dichloro, Phenol. chronic tox
\'CS Penta. 2.4-Dichloro, Phenol
,·cs chronic 1oxici1v
,·es Penta. 2.4-Dichloro, Phenol
"" Penta, 2.4-Dichloro, Phenol
ves Penta, 2.4-Dichloro, Phenol , dioxin, chronic tox
"" Penta. 2.4-Dichloro, Phenol
m Pcma, 2.4-Dichloro, Phenol
VCS chronic toxici1v
m Penta, 2.4-Dichloro, Phenol, dioxin
"' Penta, 2.4-Dichloro, Phenol, chronic tox
"' Penta. 2,4-Dichloro. Phenol
\'CS Penta. 2,4-Dichloro, Phenol, chronic IOX
ves Penta. 2.4-Dichloro, Phenol
"" Penta, 2,4-Dichloro, Phenol
"' Penm, 2,4-Dichloro, Phenol , dioxin, chronic tox
"' Penta, 2.4-Dichloro. Phenol
~·es Penta, 2.4-Dichloro, Phenol
SV-305 -Group I is penta, phenol, and 2,4-dichlorophenol; Group 2 is dioxin and Group 3 iS chronic toxicity
•
,\ssocia1ed
Group
1.3
I
I.]
u
I
I
1,3
I
' I
I
I, 2, 3
I
I
3
I. 2
1,3
I
1,3
I
I
I, 2, 3
I
I
•
•
•
Par.uncl«
Pc,,tadiln«•nhe,,.,/
Tahlc 2
(;roundwatcr Treatment
ASALYTICAL DATA SUi\li\lARY
Koppers Supcrfund Site
Morrisville, i',orlh Carolina
Novcmhcr 2000
AIUl)!ka!
Dale S.;mplc
S..,np!e 1.,.._,.,ina
Col!«.t«l S\'-101
01104/00
01/20100
02/02/00
02118/00
03/0J/OO
OJ/ll/00
().1/12/00
0-1'24/00
05115/00
05111/0()
()(,114/00
06/26/{)()
07/06100
07117100
08/0JIOO
08/HIOO
09/05100
09n7100
10113100
10124/IXJ 33
11108/()()
11121/00
2.4.Dichl,mmJ,c,i~,I 01/04/00
011101(1()
02/02/00
02118/00
OJ/01/00
OJ/11100
0.\112/00
01/Z4100
Mll.~/00
O~Hl/00
06114/00
()(,/'26/00
07106/00
07117/00
08101/00
08/14100
()1)105/00
09127100
10113/00
1or.woo
11108/00
11/21/00
Phcrn,I 01/04100
01120100
0:!102/00
02118/00
OJ/OJ/00
03113/00
(M/12/00
04/'24/00
05115/{)()
05131/00
06/!4IOO
""'""' 07/06/00
07117100
08101100
08/14/{)()
09/m/OO
09127100
10/13/00
10124100
lll{l8/00
llnl/00
Cl,mnic Tu,i,itv OI/0-1100
02/01/1)()
0411211)0
0~/0~100
06114100
07111/00
Oa/01/00
0910~/00
I0/2J,OO
11108/00
p;.,,;,. (~.J.7.8-TrDO\ 0~118100
0(,/1~/l)l)
071\7100
IOt:!4100
llt:!~/00
N<>l<S! All r.-.uhs an: m u~/L e\CC'f'I J111rn1. D111xrn J>t•" 111 r1e"~fJ11"/l.
SV-IOl -lk1nreC.rt..n1 U11i"
•SV-J0-1 -AolWWI r,ohm, llni1.,
••sv-Jo~ -Aller C "''""' Uuiis
18~60 Mcth"Ll U"><Ll
<,0
<W
<"
"'
S•mrlc 5.uu[llc
Uo:~tinn Lation
S\'-J(M• SV-305"'
<e
<e
<'
<e <e
<e
<'
<e
<e
<'
<'
<'
<'
<'
<'
<e
<e
<e
<'
<e
<e <e
<e
<e
<W
<W
<W
<,0 <W
"' < 10
<W
<W
<W
<W
<W
<,0
"" <W "' "' <"
<W
<"
<W
<W <"
<"
<W
"' <W
<"
<W <"
<W
<W
<" <W
<,0
<,0
<,0
<"
<W
"' <W
<W
<W
< 10
<W
"' <W <"
<"
<,0
P~,"'
Pa"
Fail
P:«,
Fail
p .... ,
Fail
F•il
Foil
Fait
< 1.2
<3.'14
<0.863
<0.001541
m;ulh n<1>.lrne
•
•
•
ANALYTICAL REPORT
PROJECT NO. RALEIGH
Raleigh-Bi-Weekly NPDES
Lot#: COKl00237
Debbi Leuteritz
Thermo Re tee
SEVERN TRENT LABORATORIES, INC.
/l f Ut!!f 11s,~i
Project Manager
November 20, 2000
STL Pittsburgh is a part of Severn Trent Laboratories, Inc.
STL Pittsburgh
450 William Pitt Way
Pittsburgh, PA 15233-1330
Tel: [phone]
Fax: [phone]
www.stl-inc.com
•
•
•
Sample Receiving:
CASE NARRATIVE
THERMORETEC CORPORATION
Raleigh
STL Lot# C0Kl00237
STL Pittsburgh, PA received samples on November I 0, 2000 in good condition. The
cooler was within the proper temperature range.
GC/MS Scmivolatilcs:
There were no problems associated with the analysis.
GC Phenols:
There were no problems associated with the analysis .
Chain a
Custol!f' Record
QUA 4 2~ . '
Clien11 R 1 I v4VJ11'.>.liiJ:jj ,
Address
]Ou l)(_~\,.:..,_.,--A-vu
City I State
('o-\l\··· ., ,rJ 0'11A,
Project Name 0 \;> .2.,.,,:, 7 ,,,.-I e,...V_QJ·r, h
ContracVPurchase Order/Q/Jote No. '
Sample 1.0. No. and Description
S~"~ ;,:,,,::c I \)·✓ -]c._5•'
Special lnstruclions
Possible Hazard Identification
I Zip Code
Qi,'-{l
Date Time
11hcl 00 1--)''<' J 0
Ouanterra, Inc. -PiJiliiii'rgh PA Lab
. 450 WilliamW,Vay
Pittsburgh PA 15238
Project Manager, k: \cL..-•"'""'--'\,-..___ '?ct··
Teleph:\ Number {Area Code)/Fax Number
tl'lk "J1( 1...J 7-Z . Site Contact Rr-t-r~ [s' "'-,,,_,JA/
.
' CalrM'aybill Numbe~ ,
!rLu,'vv...-JL 7 l 3L/o·:.f 277~✓
'
Total Containers
Sample Type Preservative Volume I Type No.
{,;,L-v 't,t.,f 'l.icSc,'\ ,,..._ 7 c.lZ
" .
•
Sample Disposal
' Non-Hazard D Flammable D Skin Irritant OPoisonB Ounknown 0 Return To Cfient
Turn .,round Time Required OC Level Project Specific (Specify)
0Rush O,. 011. 0111.
Dal Time 1.
/I r C:(} (;o'tl
2. Relinquished By Date Time 2.
3. Relinquished By Date Time
Comments
DISTRIBUTION: Wf-1/TE -Slays with Sample: CANARY -Returned to Client with Report; PINK -Field Copy
d})' ~uante..,
Chain Of Cusrody Number Date I ·
It 1;:,' 06
r•-----:nt"1, ... ~((;;:),
Lab Number
Page i of I
Analysis
I."--0 r---:i-
"·\ --
Condition on Receipt IC.: \)
X -,(
---
--~
.
I
I
0 Archive For A·Tonths
Time
1
fone /)G
) {1) /()'-
Time
,,.-, Cooler Receipt Form ., j(g~ ST Pil::::,h________ Quote: ~'-+--,£;'--+--fJ
Cooler R/~'d & Opened for Temp. Check on: ___ 1_1_·µ(-=G=-+~----.,..-------+--!+-fi'+l-'--o-1---
Coolers Opened and Unpacked on: ________ ,_, _-1-l-1-1/---1-_µ0"-., +-/-=c=-··_(~_-. __ _
(
, (Signature)
STL Pittsburgh Lot Number: ____ _,,_'_u-==··.'..-, -'\\-Cs,.__· --'-\-"'Ccc:..~(-"'· .. ,'-, ,_;:::.:J"--'-'3"'-~--'------------
1. Were custody seals on the outside of the cooler? ---------,,"--#;1---~-
IfYES, how many and where? Quantity_· Location ____ _,_(~, f'--v:.-'''--~-,_· ___c.f(__:1/f,..,£=··eccL0==-
Were sign;itures and date correct? ___________________ _
2. Were custody papers included inside the cooler? ______________ _
3. Were custody papers properly filled out (ink, signed, match labels)? _______ _
4. Did you sign the custody papers in the appropriate place? ___________ _
5.
6. •
Was shippers packing sjjp attached to this form?---------=------
Were packing materials used? ___ _,,,,:/~-.L-,C/J-1-7-,/:._,c..7""',/~/'-----R~.,,L--?-lt/dc,, __ ,..., ---
If YES, what type? ____ __cJ:)=s'<=c:::._c_--_~-=-{J✓.:........::0:::.-=L==-·-{ __ ' -'.(1--(\....'....J-(-'--</::_ll.-=l.._:oc=•---
7. Were the samples chilled? (Record temperatures on reverse side.) ________ _
8. Were the samples appropriately preserved? ________________ _
9. Were all bottles sealed in separate plastic bags? ______________ _
10. Did all bottles arrive in good condition (unbroken)? _____________ _
11. Were all bottle labels complete (sample ID, preservatives, etc.)?-----~---
12. Did all bottle labels and/or tags agree with custody papers? __________ _
13. · ·Were correct bottles used for tests indicated? _______________ _
/No
L
_L_
/
14. Were all VOA vials checked for the presence of air bubbles?___________ ,~
I 6. Samples received by: FED EX UPS CLIENT DROP-OFF
15. Was a sufficient amount of sample sent in each bottle? _____ -,,,--====~-====·-=-·
~;HELAJRBORNE :s
Explain any discrepancies:
~eve! 2 Review _________________________ -_--_-_--_·_· ______ _
Was contacted on ________ by ______________ to resolve discrepancies.
STL PT/Feb-00/96-005/COOL.DOC Page 1 of2
I
' I
I
I
I
•
TMET rn .. fET HG
Sample ID PH<-"'2 PH<2 PH<.:
~-
Cooler Receipt Form
STL Pittsburgh
0G
}.'l.iT{J) CN TI'HC PHEN SULF
PH<2 PH ~12 PH<2 PH<2 PH<!l2
m: TOX
PH<2 PH<2
VOA
PIUP
P: Preserved
UP: Unpreserved
hnlru.s
PH<Z
(1) ''NUT' could include sample bottles for ammoma, chemical oxygen demand, nitrate/nitrite, TK.}J, or total phosphorus
Comments:--------------------------------------
Cooler Number Temperature Bottle Type Lot Number*
.. ,,....)._ ...
-
* Please use an asterisk if bottle lot number was covered by the label. • STL PT/Feb-00/96-005/COOL.DOC Page 2 of2
•
" l . ,_,
:'•::~ :; ;.;
,:;\·'. J ;_,. f:., L f .:: :,i:_
•
r7Bill ~ Aece!ver
0 91113,d
party .
AIRBORNE
E>CPRESS. ·□◄HAA
□
OTP
•
·7a3 4 □4 2775
•
•
•
PARAMETER
Phenols by GC
METHODS SUMMARY
C0Kl.00237
ANALYTICAL
METHOD
Semivolatile Organic Compounds by GC/MS
SW846 8041
SW846 8270C
References:
PREPARATION
METHOD
SW846 3520C
SW846 3520C
SW846 "Test Methods for Evaluating Solid Waste, Physical/Chemical
Methods", Third Edition, November 1986 and its updates .
•
•
•
SAMPLE SUMMARY
C0Kl00237
~ SAMPLE# CLIENT SAMPLE ID
DPNXE 001 SYSEFF/SV-305
NOTE (S):
• The analytical results of the samples listed :1bove arc presented on the following pages .
• All calculations arc performed before rounding to avoid round-off errors in calculated results.
-Results noted as "ND" were not detccted at or above the stated limit.
-This report must not be reproduced, except in full, without the written approval of the laboratory.
• Results for the following parameters are never reported on a dry weight basis: color, corrosivity, density, flashpoint, ignitabi!ity, !ayers, odor,
paint tilter test, pl!, porosity pressure, reactivity, n:dox potcnti:.d, specific gravity, spot tests, solids, solubility, tempernture, viscosity, and weight .
DATE TIME
11/08/00 08:30
THERMORETEC CORP • Client Sample ID: SYSEFF/SV-305
GC/MS Semivolatiles
Lot-Sample # ... : COK100237-001 Work Order ll. .. : DPNXElAA Matrix ......... : WATER
Date Sampled ... : 11/08/00 Date Received .. : 11/10/00 MS Run # .....•. :
Prep Date ...... : 11/13/00 Analysis Date .. : 11/16/00
Prep Batch # ... : 0319318
Dilution Factor: 1 Method ......... : SW846 8270C
REPORTING
PARAMETER RESULT LIMIT UNITS
2,4-Dichlorophenol ND 10 ug/L
Phenol ND 10 ug/L
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Phenol-dS 60 (10 -113)
2-Fluorobiphenyl 61 (30 -110)
Nitrobenzene-ds 57 (32 -112)
Terphenyl-dl4 91 (10 -144)
2-Fluorophenol 53 (13 -110)
2,4 1 6-Tribromophenol 91 (21 -122)
•
•
•
•
•
THERMORETEC CORP
Client Sample ID: SYSEFF/SV-305
Lot-Sample# ... : C0K100237-001
Date Sampled ... : 11/08/00
Prep Date ...... : 11/14/00
Prep Batch# ... : 0320240
Dilution Factor: 1
PARAMETER
Pentachlorophenol
SURROGATE
2,4-Dibromophenol
GC Semivolatiles
Work Order# ... : DPNXElAC
Date Received .. : 11/10/00
Analysis Date .. : 11/15/00
Method ......... : SW846 8041
REPORTING
RESULT LIMIT
ND 2.0
PERCENT RECOVERY
RECOVERY LIMITS
82 (31 -134 I
Matrix ......... : WATER
MS Run # ....... : 0320113
UNITS
ug/L
• METHOD BLANK REPORT
GC/MS Semivolatiles
Client Lot# ... : C0K100237 work Order# ... : DPTK81AA
MB Lot-Sample#: C0K140000-318
Analysis Date .. : 11/16/00
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Phenol
SURROGATE
Phenol-d5
2-Fluorobiphenyl
Nitrobenzene-d5
Terphenyl-dl4
2-Fluorophenol
2,4,6-Tribromophenol
NOTE (S) :
Prep Date ...... : 11/13/00
Prep Batch# ... : 0319318
REPORTING
RESULT LIMIT UNITS
ND 10 ug/L
ND 10 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
82 (10 -113)
79 (30 -110)
79 (32 -112)
83 (10 -144)
75 (13 -110)
99 (21 -122)
• Calculations are performed before rounding to avoid round•Off errors in c:ilcula1ed results .
•
Matrix ......... : WATER
METHOD
SW846 8270C
SW846 8270C
• METIIOD BLANK REPORT
GC Semivolatiles
Client Lot# ... : C0K100237 Work Order# ... : DPV851AA
MB Lot-Sample#: C0KlS0000-240
Analysis Date .. : 11/16/00
Dilution Factor: 1
PARAMETER
Pentachlorophenol
SURROGATE
2,4-Dibromophenol
NOTE(S):
Prep Date ...... : 11/14/00
Prep Batch# ... : 0320240
REPORTING
RESULT LIMIT
ND 2.0
PERCENT RECOVERY
RECOVERY LIMITS
65 I 31 -134)
Calculations arc performed before rounding to avoid round-off errors in calculated results .
•
•
Matrix ......... : WATER
UNITS METHOD
ug/L SW846 8041
• LABORATORY CONTROL SAMPLE EVALUATION REPORT
GC/MS Semivolatiles
Client Lot # ... , COK100237 Work Order# ... , DPTK81AC-LCS Matrix._ ... _ ... : WATER
LCS Lot-Sample#, COK140000-318 DPTK81AD-LCSD
Prep Date ...... , 11/13/00 Analysis Date .. : 11/16/00
Prep Batch# ... , 0319318
Dilution Factor: 1
PERCENT RECOVERY RPD
PARAMETER RECOVERY LIMITS RPD LIMITS METHOD
2-Chlorophenol 63 (19 -124) SW846 8270C
63 (19 -124) 0.84 (0-43) SW846 8270C
1,4-Dichlorobenzene 59 (28 -110) SW846 8270C
60 (28 -110) 2.0 ( 0-36) SW846 8270C
N-Nitrosodi-n-propyl-55 (30 -115) SW846 8270C
amine
53 (30 -115) 3.7 (0-36) SW846 8270C
1,2,4-Trichloro-65 (31 -110) SW846 8270C
benzene
66 (31 -110) 2.7 (0-37) SW846 8270C
4-Chloro-3-methylphenol 70 (29 -124) SW846 8270C • 71 (29 -124) l.5 ( 0-55) SW846 8270C
Acenaphthene 75 (39 -llB) SW846 8270C
76 (39 -118) l.8 (0-35) SW846 8270C
4-Nitrophenol 80 (19 -144) SW846 8270C
82 (19 -144) l.6 (0-34) SW846 8270C
2,4-Dinitrotoluene 75 (4 7 -131) SW846 8270C
76 (4 7 -131) l.l (0-32) SW846 8270C
Pentachlorophenol 118 (10 -140) SW846 8270C
120 (10 -140) l.3 (0-56) SW846 8270C
Pyrene 95 (46 -130) SW846 8270C
93 (46 -130) 2.3 ( 0-31) SW846 8270C
Phenol 61 (10 -131) SW846 8270C
62 (10 -131) l. 7 (0-43) SW846 8270C
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Phenol-d5 63 (10 -113)
63 (10 113)
2-Fluorobiphenyl 71 (30 110)
71 (30 -110)
Nitrobenzene-ds 61 (32 -112)
62 (32 -112)
Terphenyl-dl4 89 (10 144)
86 (10 -144)
2-Fluorophenol 53 (13 -110) • 53 (13 110)
2,4,6-Tribromophenol 96 (21 -122)
96 (21 -122)
(Continued on next page)
•
•
•
LABORATORY CONTROL SAMPLE EVALUATION REPORT
GC/MS Semivolatiles
Client Lot# ... , C0K100237 Work Order# ... , DPTKBlAC-LCS Matrix ......... , WATER
LCS Lot-Sample#, C0K140000-318 DPTKBlAD-LCSD
SURROGATE
NOTE (S),
PERCENT
RECOVERY
Calculations are performed before rounding to avoid round-off errors in calculated results.
Bold prim denotes control parameters
RECOVERY
LIMITS
•
•
•
LABORATORY CONTROL SAMPLE EVALUATION REPORT
GC Sernivolatiles
Client Lot# ... : C0K100237 Work Order# ... : DPV851AC
LCS Lot-Sample#: C0K150000-240
Prep Date ...... : 11/14/00 Analysis Date .. : 11/16/00
Prep Batch# ... : 0320240
Dilution Factor: 1
PERCENT RECOVERY
PARAMETER RECOVERY LIMITS
Pentachlorophenol 74 (SO -126)
PERCENT
SURROGATE RECOVERY
2,4-Dibromophenol 62
NOTE (S):
Calculations arc performed hclorc rounding 10 avoid round-off errors in calculated results.
Bold prim denotes control parameters
Matrix ......... : WATER
METHOD
SW846 8041
RECOVERY
LIMITS
(31 -134)
•
•
•
MATRIX SPIKE SAMPLE EVALUATION REPORT
GC Semivolatiles
Client Lot# ... : C0K100237
MS Lot-Sample#: C0K110155-004
Work Order# ... : DPPBRlAC-MS
DPPBRlAD-MSD
Date Received .. : 11/11/00
Analysis Date .. : 11/15/00
Date Sampled ... : 11/10/00
Prep Date ...... : 11/14/00
Prep Batch# ... : 0320240
Dilution Factor: 1
PERCENT RECOVERY RPD
PARAMETER RECOVERY LIMITS RPD LIMITS
Pentachlorophenol 61. (54 -133)
70 (54 -1.33) 1.3 (0-20)
Matrix ......... : WATER
MS Run # ....... : 0320113
METHOD
SW846 8041.
SW846 8041.
PERCENT RECOVERY
SURROGATE RECOVERY
2,4-Dibromophenol 56
62
NOTE (S) :
Calculations are performed before rounding to avoid round-off errors in calculated results.
Bold prim denotes cumrol parameters
LIMITS
(31 -134)
( 31 -134)
•
•
ANALYTICAL REPORT
PROJECT NO. RALEIGH
Raleigh-Bi-Weekly NPDES
Lot#: C0K220172
Debbi Leuteritz
ThermoRetec
SEVERN TRENT LABORATORIES, INC.
Veronica Bertot
Project Manager
November 29, 2000
STL Pittsburgh is a part of Severn Trent L.:iboratories, Inc.
,_,
STL Pittsburgh
450 William Pitt Way
Pittsburgh, PA 15238-1330
Tel: [phone]
Fax: [phone]
www.stl-inc.com
•
•
Sample Receiving:
CASE NARRATIV~=
THERMORETEC CORPORATION
Raleigh
STL Lot# C0K220172
STL Pittsburgh, PA received samples on November 22, 2000 in good condition. The
cooler was within the proper temperature range.
GC/MS Semivolatiles:
There were no problems associated with the analysis.
GC Phenols:
There were no problems associated with the analysis .
,-· ·hain of
Custody Record
Client -~ -___ /·_ ~o ~-f_/ ,/_,,
Address
C
Joo 8Ait&4. Av .a .J (, ,'TE-;Jc,z_
City I Sttlte Zip Code
Co .Jq, ,eo il1A Ot1YL
Pre&~~ I RN£,, II
ContractlPurchase Order/Qt.iote No.
Sample 1.0. No. and Description Date Time
tz.Fr. sv-.1os-11/-J.1/~ 1rro
Special Instructions
Possible Hazard Identification
Quant .. Inc. -Pittsburgh PA Lab
450 William Pill Way
Pittsburgh PA 15238
Project Manager
/.?;774 P,A 1/£/2---f);;; N~/(:a;°?rr Number
Site Corftact
CarrierM/aybi/1 Number
Total Containers Sample Type Volume Type No.
~_fl z'. L. L ...,
n-Hazard D Flammable 0 Skin Irritant 0PoisonB 0 Unknown
OC Level
3. Relinquished By Date Time 3. Received By
Comments
DISTRIBUTION: WHITE -Stays with Sample; CANARY -Returned to Client with Report; PINK -Field Copy
Preservative
,~~1vc
"'~\ . "1!!!uanterra
Date
n I z.1 loo Chain Of Cusrody NumtJ ,:
<..
Lab Number
Page I of
Analysis
Q
~ ;.
€. Condition on Receipt °' )( X ' I
.
D Disposal By Lab 0 Archive For Months
Tim
. \r/ Jr~
Cl1e:it: ~ S _,,, Project: ________ _ Cooler Rec'/& Onened for Temo. ,Check on: r (2? o, .
Cooler Receipt Form
STL Pitisburgh
• lers Ope.1ed a~c! Unpacked o.n: 11 / 77 / cc',
I I /) . STL Pittsburgh Lot Number: _____ ___,l=-:::..0:::...._:_}--=:l:::.."'---.::7"-'":::..;2,"'[j""-\-'-/_' LI,_;}.--:::.. ____________ _
1. Were custody seals on the outside of the cooler? _______________ _
IfYES, how many and where~ Quantity·_ .. Location __ ..c...~~---------
Were signatures and date correct? -------.LI.L·h___,z._y-"""':.../_. _· _________ _ I 2. Were cusiody papers included inside the cooler? _______________ _
3. Were custody papers properly f.lJed out (ink, signed, match labels)? ________ _
4. Did you sign the custody papers in the appropriate place? ____________ _
5. Was shippers packing slip attached to this form? ______ -'--''-----------
IfYES, what type? ____ __:c-c::::1-t:::.:.....C'==:'.~c:'....l=:..._--'.._;:.__ _________ _
7.Were the samples chilled? (Record tempera~res on reverse side.) ________ _
8. · Were the samples appropriately preserved?'---~----------------
9. Were all bottles sealed in separate plastic bags? _________ _:__ _____ _
0. Did all bottles arrive in good condition (unbroken)? ______________ _
l. Were all bottle labels complete (sample ID, preservatives, etc.)?'---'-------'-'------
2. Did all bottle labels and/or tags agree with custody papers?· ___________ _
,·.·.Were correct bottles used.(or tests indicated? ________________ _
Were all VOA vials c~presence of air bubbles?
Was a suffi~~un~ampi'~ sd in each bottle? _____________ _
Yes No
/
__.....--::_· -
_L
;;;:r-
~
' , __,../ ~-
Sample€receiv by FEDEX S CL1E1'ff DROP-OFF OTHER AIR.BOR.'-IE
,lain any discre;:,ancie:~. ==:::::::=---------------------~~------
el 2 Review------------------------------------
; .tac:ed a~ _· -'--------by _______________ to resolve discrepancies.
'T;'f eo--00196-D O .5/C 00 L DOC Page l of 2
i
I I
STL Pittsburgh
• CG
TI,CET 01-,,IET HG NUT(l) C" ., T?!--:C P:''.=:;'l SUL? TCC TOX vc;,._
Sample !D ?fr:2 P!-i<: PE<: PE<: PH ;;:I'.! PE<: P~C P:-:1 ~I: PH<: PH<'.! P/u?
I I I I I I I
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I I I I I I
I I I I I I I I I
I I I I I I
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I I I I
I I I I I
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(1) "NUT' could mclude sample bottles tor 3.II'.ID □rua, cne:rucal oxyge:i de::.and, rut...rate/rutnte, T..rCN, or tot.al phosphorus
P: Preser,ed
UP: Unpreser,ed
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PE<:
I I I
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I I I
I I
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Comments:-------------------------------
Coo \er Number Temperature Bottle Type Lot Number*
'-'7" ~ .. --I
I I
I I I
I I I I
I .. I I
. -• "f Ple:ise use 3.n 3.Srensk 1r bottle lot number·\vas covered by the label.
STL PT/F:b.Q0/96-J05/COOL.DOC
Page 2 of1
®
+
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I J_
State/VG ZIP
2 Your Internal Billing Reference
3 To
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Cornoany
Addrnss 1/')£? (.v, 111{\r'i\
To 1-lOI.D" 01 Fedu lo<....,_,,..... Fodb addr,.._
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4a Express Package Service Packages up to 150 lbs. -
Oe!Nfft'•~-be1.>1ero,,...,..,,.,, • -rii, fedh _Priority Overnight I Ne>!lbtuless,..,...,.,.
0 FedEx Standilld Overnight O FedEx first Overnight
tl,>:1b,alessahemo<>:> EM~nt'1buoo"'""""-
dei•""l"''cl"'tk•cano,,,
0 FedEx20ay•
Second ou,i,,ess<lly
0 FedEx _Express Saver~.
lholdt>u>ineud"'I ,, • FedEx t~•~•• Rate no1 av01c,~e M_,,..,v,,~e-po,.ndrote
4b Express Freight Service I ,lf Packages over 150 lbs.
O,n<,11y,_mM11mo1 t>o Joie,"''""'"'''"
D FedEx 20~~ Freight
S.c«od-....11-v
5 • Oe<latod ,aue lml 5'.iOO
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Packaging
FedEx Envelope/
Lener•
·•··•··t~f,
D FedEx Pak" ...Qf ntt,er Pkg. ~ 'rd,,desfedullo>.fd• lube.
•ncl cwome, J>lo
Total Packages
( ' ,00
l()ur iabiity is lin:led to $100 llllles.syoo declare a higher \'i.l.le. See hat\; to, detais
8 Release Signature s'lloto8ulh,..,,Fd,+.,,,,y...mornubl•""'•g.,,,,.....-,_
Bv sig!ling yoc, aut!,orire us ta deliver this sliii,mem Wiltiout oblaning a signattue
and agree to mdemn1fy a1>d hold us harmle" Ir run any ,e,ull01g cta,rns
Questions? Visit our Web site at www.fedex.com
"'i;;-,n l·BOO·Go•fedE>.· !800)-l6J·3339
11c .... n,,emll•r>rlll~Hll•'!:'l!l'Y-71l1Jll..-f[,•l1111HWIIIIISA Gere 10/00
•
•
•
METHODS SUMMARY
COK220l72
PARAMETER
Phenols by GC
Semivolatile Organic Compounds by GC/MS
References:
ANALYTICAL
METHOD
SW846 8041
SW846 8270C
PREPARATION
METHOD
SW846 3520C
SW846 3520C
SW846 "Test Methods for Evaluating Solid Waste, Physical/Chemical
Methods", Third Edition, November 1986 and its updates .
•
•
•
SAMPLE SUMMARY
COK220l. 72
l:!Q_JL_ SAMPLE# CLIENT SAMPLE ID
DQAOL 0 0 l. EFF SV-305
NOTE (S) :
-The analytical results of the samples listed above arc presented on the following pages.
-All cakulJtions are performed before rounding to :ivoid round-off errors in calculated results.
-Results nocc..>d as "ND" were not detected at or above the stated limit.
• This rcpon must not be reproduced, except in full. without the written approval of the laboratory .
• Rcsulls for the following parnmctcrs arc never repmted on a dry weight basis: color. corrosivity. densily, lhshpoim, ignitability, layers, odor,
paint filter test, pH. porosity pressure, reactivity, redox potential, specific gravity, spot tests, solids, solubility, temperature, viscosity, and weight.
DATE TIME
l.l./21/00 15: 50
•
•
•
THERMORETEC CORP
Client Sample ID, EFF SV-305
GC/MS Semivolatiles
Lot-Sample # ... ' COK220172-001 Work Order # ... ' DQAOLlAA Matrix ......... , WATER
Date Sampled ... , 11/21/00 Date Received .. : 11/22/00 MS Run# ....... ,
Prep Date ...... : 11/24/00 Analysis Date .. , 11/28/00
Prep Batch # ... ' 0329098
Dilution Factor: 1 Method ......... , SW846 8270C
REPORTING
PARAMETER RESULT LIMIT UNITS
2,4-Dichlorophenol ND 10 ug/L
Phenol ND 10 ug/L
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Phenol-d5 81 (10 -113)
2-Fluorobiphenyl 71 (30 -110)
Nitrobenzene-dS 77 (32 -112)
Terphenyl -dl4 91 (10 -144)
2-Fluorophenol 68 (13 -110)
2,4,6-Tribromophenol 89 (21 -122)
THERMORETEC CORP • Client Sample ID: EFF SV-305
GC Semivolatiles
Lot-Sample # ... : COK220172-001 Work Order # ... : DQAOLlAC Matrix ......... : WATER
Date Sampled ... : 11/21/00 Date Received .. : 11/22/00 MS Run# ....... :
Prep Date ...... : 11/24/00 Analysis Date .. : 11/27/00
Prep Batch # ... : 0329099
Dilution Factor: 1 Method ......... : SW846 8041
REPORTING
PARAMETER RESULT LIMIT UNITS
Pentachlorophenol ND 2.0 ug/L
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
2,4-Dibromophenol 77 (31 -134)
•
•
• METHOD BLANK REPORT
GC/MS Semivolatiles
Client Lot# ... : C0K220172 Work Order# ... : DQDMSlAA
MB Lot-Sample#: C0K240000-098
Analysis Date .. : 11/28/00
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Phenol
SURROGATE
Phenol-d5
2-Fluorobiphenyl
Nitrobenzene-ds
Terphenyl-dl4
2-Fluorophenol
2,4,6-Tribromophenol
NOTE (S):
Prep Date ...... : 11/24/00
Prep Batch# ... : 0329098
REPORTING
RESULT LIMIT
ND 10
ND 10
PERCENT RECOVERY
RECOVERY LIMITS
74 (10 -113)
66 (30 -110)
69 (32 -112)
95 (10 -144)
61 (13 -110)
86 (21 -122)
.Calculations are performed before rounding to avoid round-off errors in calculated resu!ls .
•
UNITS
ug/L
ug/L
Matrix ......... : WATER
METHOD
SW846 8270C
SW846 8270C
• METI!OD BLANK REPORT
GC Semivolatiles
Client Lot# ... : C0K220172 Work Order# ... : DQDM71AA
MB Lot-Sample#: C0K240000-099
Analysis Date .. : 11/27/00
Dilution Factor: 1
PARAMETER
Pentachlorophenol
SURROGATE
2,4-Dibromophenol
NOTE (S) :
Prep Date ...... : ll/24/00
Prep Batch# ... : 0329099
REPORTING
RESULT LIMIT
ND 2.0
PERCENT RECOVERY
RECOVERY LIMITS
92 (31 -134)
Calculations arc performed before rounding to avoid round-off errors in calculated results .
•
•
Matrix ......... : WATER
UNITS METHOD
ug/L SW846 8041
• LABORATORY CONTROL SAMPLE EVALUATION REPORT
GC/MS Semivolatiles
Client Lot# ... : COK220172 Work Order #. _.: DQDM51AC-LCS Matrix ..... _ ... : WATER
LCS Lot-Sampleit: COK240000-098 DQDM51AD-LCSD
Prep Date ...... : 11/24/00 Analysis Date .. : 11/28/00
Prep Batch# ... : 0329098
Dilution Factor: 1
PERCENT RECOVERY RPD
PARAMETER RECOVERY LIMITS RPD LIMITS METHOD
2-Chlorophenol 78 ( l.9 -l.24) SW846 8270C
83 ( l.9 -l.24) 6.3 (0-43) SW846 8270C
1,4-Dichlorobenzene 71. (28 -].].Q) SW846 8270C
75 (28 -l.l.O) 5.4 (0-36) SW846 8270C
N-Nitrosodi-n-propyl-72 (30 -HS) SW846 8270C
amine
75 (30 -].].5) 4.4 (0-36) SW846 8270C
1,2,4-Trichloro-73 ( 31. -].].Q) SW846 8270C
benzene
77 (3]. -].].0) 5.9 (0-37) SW846 8270C
4-Chloro-3-methylphenol 84 (29 -l.24) SW846 8270C • 89 (29 -l.24) 6.0 (0-55) SW846 8270C
Acenaphthene 76 (39 -l.l.8) SW846 8270C
82 (39 -].].8) 7.8 (0-35) SW846 8270C
4-Nitrophenol 76 (l.9 -l.44) SW846 8270C
81. ( l.9 -l.44) 7. l. (0-34) SW846 8270C
2,4-Dinitrotoluene 74 (4 7 -l.31.) SW846 8270C
80 (4 7 -l.31.) 7.8 (0-32) SW846 8270C
Pentachlorophenol l.08 (].O -l.40) SW846 8270C
].]. 7 ( ].Q -l.40) 7.4 (0-56) SW846 8270C
Pyrene l.04 (46 -l.30) SW846 8270C
l.l.3 (46 -l.30) 8. l. (0-31.) SW846 8270C
Phenol 74 (l.O -l.31.) SW846 8270C
79 ( ].0 -l.31.) 5.9 (0-43) SW846 8270C
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Phenol-d5 79 (10 -113)
83 (10 -113)
2-Fluorobiphenyl 74 (30 -110)
78 ( 3 0 -110)
Nitrobenzene-ds 76 (32 -112)
79 (32 -112)
Terphenyl -d14 93 (10 -144)
99 (10 -144)
2-Fluorophenol 64 (13 -110) • 68 (13 -110)
2,4,6-Tribromophenol 94 (21 -122)
100 (21 -122)
(Continued on next page)
•
•
•
LABORATORY CONTROL SAMPLE EVALUATION REPORT
GC/MS Semivolatiles
Client Lot# ... : C0K220172 Work Order# ... : DQDM51AC-LCS Matrix ......... : WATER
LCS Lot-Sample#: C0K240000-098 DQDM51AD-LCSD
SURROGATE
NOTE (S) :
PERCENT
RECOVERY
Calculations are performed before rounding to avoid round-off errors in calculated results.
Bold print denotes control parame1ers
RECOVERY
LIMITS
•
•
•
LABORATORY CONTROL SAMPLE EVALUATION REPORT
GC Semivolatiles
Client Lot# ... , C0K220172 Work Order# ... , DQDM71AC-LCS
DQDM71AD-LCSD
Analysis Date .. , 11/27/00
Matrix ......... , WATER
LCS Lot-Sample#, C0K240000-099
Prep Date ...... , 11/24/00
Prep Batch# ... , 0329099
Dilution Factor: 1
PERCENT RECOVERY
PARAMETER RECOVERY LIMITS
Pentachlorophenol 84 (50 -126)
85 (50 -1.26)
PERCENT
SURROGATE RECOVERY
2,4-Dibromophenol 87
89
NOTE (S),
Calculations are performed bcfore rounding to avoid round-off errors in calculatL'U results.
Bold print denotes control parameters
RPD
RPD LIMITS METHOD
SW846 8041
1..6 (0-20) SW846 8041.
RECOVERY
LIMITS
(31 -134)
(31 -134)
Effluent Toxicity Report Form -Chronic Pass/Fail and Acute LCS0 Date, 11/22/00
NPDES#, NC
boratory Performing Test: TRITEST, INC.
Work Order, 0011-00241 MAIL ORIGINAL TO,
North Carolina Ceriodaphnia
Chronic Pass/Fail Reproduction Toxicity Test
CONTROL ORGANISMS 1 2 3 4 5 6 7 8 9 10 11
Pipe#, County: WAKE
Comments:
Environmental Sciences Branch
Div. of Environmental Management
N.C. Dept. of EHNR
4401 Reedy Creek Road
Raleigh, North Carolina 27607-6445
Chronic Test Results
Calculated t = 3.413
Tabular t = 2.508
12 % Reduction= 26.09
% Mortaljty Avg.Reprod.
# Young Produced 26 31· 33 27 28 33 34 30 33 25 32 36
0.00 30.67
Control Control
Adult (L)ive (D) ead L L L L L L L L L L L L
0.00 22.67
Treatment 2 Treatment 2
Effluent %: 90%
1 2 3 4 5 6 7 8 9 10 11 12 Control CV TREATMENT 2 ORGANISMS 11.324% PASS FAIL
# Young Produced 28 12 15 24 32 29 15 12 29 28 21 27 % control orgs □ ~ producing 3rd
brood Check One
dult (L)ive (D) ead L L L L L L L L L L L L 100%
1st sample 1st sample 2nd sample Complete This For Either Test
pH ~ ~ ~ Test Start Date: 11/08/00
Control Collection (Start) Date
Sample 1, 11/07/00 Sample 2, 11/09/00
Treatment 2 Sample Type/Duration 8 9 5 1st
s s s Grab Comp. Duration D
t e t e t e I s
a n a n a n Sample 1 X 24 hrs L A
r d r d r d u M
t t t Sample 2 X 24 hrs T p
1st sample 1st sample 2nd sample
D.O. Hardness(mg/1) 45 ..........
HE [83E8 [8IE
.......... ..........
Concrol Spec. Cond. ( µmhos) 170 850
Treatment 2 2 2 0
Chlorine (mg/1) .......... <0.1
LCS0/Acute Toxicity Test Sample temp. at receipt I °C) .......... 0.9
(Mortality expressed as ~ . ' combining replicates) I
%1 %1 %1 % % % % %
% % % % % % % % I I I I I I
% %
% % I I
Concentration
Mortalit y
start/end
Note: Please
Complete This
Section Also
start/end
pH D.O.
Organism Tested: Ceriodaphnia dubia Duration(hrs):
Copied from DEM form AT-1 (3/87) rev. 11/95 (DUBIA ver. 4.32)
2nd
P/F
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850
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• TRITEST, INC.
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Sarnpk r:, p..:: Composite:
Da,, Sun,d: ___ /c__l .;,/_0_:\L_.,>\_o_:o::_ _____ Tim<: O"I JO ~r P'1
Dale End,d: __ -fi--'1--a(f-'.L,.,,c:_1-,l _c_,> ______ Tim<: cc; lo @or P.\I • # Hours : ~ •/ S;1mpks pl.'r Hour : _____ .,,_ ______ _
Grab: /
Dali: : _________ __,/:_________ Timi::--------.,'-
Sampll' \"11lu111,.:: _____ _,/ ________ ChilkJ during Culk · ,.m·.1 ___ _
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I I O O I t I O I O I I I I t I t t I I t I I I I I Chain of Cus10Jy Rck:i:,c t I I I I I I I t t f f t I I I I o t t f I o O I
l{,.:li11u11:.~!i,.:d lh ,., Dat.: T lllh.' Rel.'.C!\1.'.J lh lbt,: !i111,:
I !A,,,;;,,-""~•-j(, I (!JI i1/ 1, /o~ /,
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For Laboratory Usi: Onl~·
R..::-1du.1I l"hl11rin..:: ______________ Sumbi:r of Bou ks: _____ _ • ,.\ddr..:~~: .l9(1lJ B..:r;! RJ .. Rjkigh. NC 27607 Phum.:(919) 834 •498➔ Fax (9l9J 8J-t-6-t97
• TRITEST, INC.
P.O.•:
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cf Test ~k,hoJ: (,,'1,;roi,v.-f. T():,o' c/7
;"i:unpk ~ill." [),::,;,:rirtinn: ____ s"'. '-'y'--"~'--'-·--"<r:c....!.F_,_F ____________ _
S"111plc lnl 1:;~:::,,,,l;~i:_' -'_· ======~1,ILC:L:l,;"-•o,\:~:=:=~==lt:JJi./'-\}=l=· :i~~'-·=============---
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Dab: E11Jl·d: ____ ,_I \...,\,_'c.,_(--'l...,
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Timi::: 11 ¥c) 1.J @or P~I
Time: C~\O @)or p" • Sampks p,:r Hour: ___________ _ # Hours : .) f
:::~t,_' ----~~=---· ___ · ____ _ Time: /:." or P~t ,
••••••••••••••••••••••• ' • t Chain of Cus10Jy Rdr.::.1sc •••••••••••• ♦ ••••••••••••
Timr.:
" '.? Oi)
For Laboratory Usi:: Ont:
•
...
•
•
•
November 22, 2000
Ms. Beverly Hudson
Remedial Project Manager
U.S. EPA -Region IV, I 1th Floor
North Site Management Branch
61 Forsyth Street, SW
Atlanta, GA 30303
RE: Revision to Monthly Progress Report #90
Remedial Action
Koppers Site -Morrisville, NC
Dear Ms. Hudson:
ThermoRetec Corporation
300 Baker Avenue, Suite 302
Concord, MA 01742
ThermoRetec
Smart Solutions. Positive Outcomes.
[phone] Phone
[phone] Fax
www.thermoretec.com
RECEI\/ED
DEC 1 2000
SUPERFUND SECTION
Enclosed please find four copies of the laboratory report for the Dioxin sampling performed on
October 24, 2000. This data was received after our November 10, 2000 submission of Progress
Report #90. Because this data was not recorded in Report #90, we are including four corrected
copies of the Groundwater Treatment Analytical Data Summary table (Table 2). Please note that the
laboratory inadvertently ran Method 8280 instead of the specified Method 8290. Communications
with the lab have taken place to ensure that this does not occur in the future.
Should you need additional information regarding this progress report, please call Mike Slenska at
[phone] or me at [phone].
Sincerely,
ThermoRetec Consulting Corporation
l ·1 ---fYu.---cr--<--C
Rita Bauer C:
Project Geologist
RB:cg
Enclosure
cc: ,_D. Mattison -NC Superfund (2 copies)
D. Hails -Ecological Restoration, Inc.
.I. Garrett -NC Division of Water Quality
P. Kilchenstein -ThermoRetec
D. Matthews -NC Division of Water Qua!.
F:\PROJ ECTS\03624\Rcpons\Momhly\Hu<ls 1122. wp<l
M. Slenska -Beazer
L. Faulconer -Wake County
G. Caskey -Enwood Structures
M. Helbling -Beazer
a Thermo Electron company
L
•
•
MONTHLY PROGRESS REPORT #90
REMEDIAL ACTION
SITE NAME: Koppers Superfund Site
Beazer East, Inc.
Morrisville, NC
USEPA DOCKET NUMBERS: 93-09-C
PERIOD ENDING: October 30, 2000
1. PROGRESS MADE THIS MONTH
2.
3.
4.
5.
6.
Remedial Action (RA) -HABITAT MIT/GA TION. No activities were conducted this
month.
Remedial Action (RA) -GROUNDWATER TREATMENT. The treatment system
operated throughout the month without upset. System performance was monitored
on a biweekly basis. Approximately 41,185 gallons of groundwater were extracted,
treated in the treatment plant and discharged between September 28, and October
30, 2000. System water samples were collected on October 13, 2000 and October
24, 2000 in accordance with the sampling schedule in the O&M manual. Samples
were submitted to Severn Trent and TriTest for laboratory analysis. The operations
and sampling programs are summarized on the attached Table 1.
Remedial Action (RA) -EFFECTIVENESS MONITORING PROGRAM. No activities
were conducted this month.
Remedial Action (RA) -CORRESPONDENCE. None.
PROBLEMS RESOLVED
PROBLEMS ANTICIPATED
UPCOMING EVENTS
PERSONNEL CHANGES
SUBCONTRACTORS
None.
None.
Continue System O&M.
None.
None.
7. ANALYTICAL DATA Analytical data from system influent and effluent sampling
received during this period are enclosed and are summarized on Table 2.
F: \PROJ ECTS\03624\Reports\Monthly\Hmls l l 22. wpd
•
•
Parameter
Pentachlornnhenol
2.-l•Dichloro~herml
Phennl
Chronic Tnxidtv
Table 2
Groundwater Treatment
Ai.'l'ALYT[CAL DATA SlJI\.,L\-tARY
Koppers Superfund Site
l\lorrisvillc, North Carolina
October 2000
Analytkal
O;ue Sample
Sample !.<>1:.11i,m
c.,nec1eJ S\'-101
0li04/00
01120/00
02102/0(1
02/18100
03/03100
03/13100
04/12/00
04/24/()()
05115/00
05131/00
06/!4100
06126100
07/06100
07/17/00
08/01100
08/14100
09105100
09/27/00
10/JJ/[)()
10/24100 33
0!/04/00
0!/20/00
02102./00
02118100
03/03100
03113100
04112100
04/24100
05115/00
05131/00
06/14/()()
06'26/00
07/06/00
07/17100 < 10
08/01100
08/14100
09/05/00
09/27/00
l0/13/00
I0/24100 <IO
01/04100
01/20100
02/02/00
02/18100
03/03100
03/13100
04/12/00
04/24/00
05115100
05131100
06/14100
06126100
07106100
07117100 < lO
08101100
08/14100
O<JM/00
o<Jmmo
10/13100
I0/24100 < 10
01/04100
01/01100
04/12100
OS/05100
06114/00
0711]10()
08/01100
09/05100
I0/24/00
Di.,xin (2.3,7.S•TCDD) 02/18100
06/15100
07/17100
10/241()()
N"ccs: All rcsulcs arc in ug/L cx,:,pl Jinx in. Di,)xin JatJ l.1 in pkngr;.11n.,/L.
SV•\01 -Before Carhnn Units
•SV-30-i -Bctwcrn Carhun Unit,
usV-305 -At'lcr Carhnn UniL,
182!\0 McthuJ use<l
Sampk Sample
Localion Lncatiun
SV-304• SV-305••
<2
<2
<2
<2 <2
<2
<2
<2
<2
<'
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2 <2
<IU
<10
<IO
< lO <IU
<10
<10
<10
<10
<10
< lO
<10
< lO
< lO
< 10 < IO
<10
< lO
<10
< lO
<IO
<10 < lO
<10
<10
< lO
<IO <10
<10
<10
< 10
< 10
<10
< lO
<10
<10
<10
<IO <10
<10
<10
<IO
<IO
<IO
< 10 <10
Pa.,s
Pa.,s
Fail
Pass
Fail
Pass
Fail
Fail
Fail
<U
<3.94
<0.863
<0.00154'
• 4&4-44
ALTA
November 14, 2000
Alta Batch I.D.: 9304
Ms. Rita Bauer
ThermoRetec Consulting Corporation
300 Baker A venue
Suite 302
Concord, MA 01742
Dear Ms. Bauer,
Enclosed are the results for the one aqueous samples received at Alta Analytical Laboratory on
October 25, 2000. This sample was extracted and analyzed using EPA Method 8280 for 2,3,7,8-
TCDD only. A standard turnaround time was requested for this work.
• The following report consists of a Sample Inventory (Section I), Analytical Results (Section II) and
the Appendix. The Appendix contains a copy of the chain-of-custody, a list of data qualifiers and
abbreviations, our current certifications, diskette deliverables, and copies of the raw data.
Alta Analytical Laboratory remains committed to serving you in the most effective manner.
Should you have any questions or need additional information and technical support, please do not
hesitate to contact me. Thank you for choosing Alta as part of your analytical support team.
Sincerely,
\-, (
" .. , · It.· / ru __ ,J)._ . vVi..tz.,, o (<. r
( ShSIIY A.1 f eagr~, //)
-HRMS Services Coordinator ,_.
Alta Analytical Laboratory Inc.
5070 Robert J. Mathews Parkway
El Dorado Hills, CA 95762
FAX [phone]
[phone]
IA -ALTA •
Section I: Sample Inventory Report
Date Received: 10/25/200
Alta Lab. ID Client Samnle ID
9304-001 SV-305
•
•
n
•
•
•
METHOD BLANK
Matrix: Aqueous
Compound
2,3,7,8-TCDD
Internal Standards
I 3C-2,3, 7,8-TCD D
Clean-up Recovcrv Standard
37Cl-2,3,7,8-TCDD
Date Analvzcd
DB-5: 11/11/00
Analyst: RS
TCDD
EPA METHOD 8280
Date Received: NA
Date Extracted: 11/8/00
Sample Amount: 1.000 L
Cone.
ND
'1/.,R
63.4
97.2
DL
0.00313
P:.lge I of I
MDL
0.00226
JA.
J!!!!!!!!!!!>
ALTA
Lab ID: 0-MB00l
QC Set: 1 I 05
Units: nu/L
Qualifier
•
OPR RESULTS
Lah ID: Ol'R00l
Matrix: Aqueous
Compound
2,3,7,8-TCI)I)
Internal Standards
13C-2,3,7,8-TCDD
• Clean-up Recovery Standard
37Cl-2,3, 7,8-TCD D
Date Analyzed
DB-5: 11/11/00
•
Analyst: RS
TCDD
El'A METHOD 8280
Date Received: NA
Date Extracted: 11/8/00
Sample Amount: 1.000 L
Spike
Cone.
Amount
Found
I 0.0
Spike
Cone.
50.0
Spike
Cone.
50.0
9.45
73.0
97.3
P.ige I of l
IA -ALTA
QC Set: 1. 105
Units: ng/mL
OPR Limits
7-13
OPR Limits
25 -150
OPR Limits
25 -150
•
•
•
TCDD
EPA METHOD 8280
Sample ID: SV-305
Project: General Amlytical HRlvlS
Matrix: Aqueous
Sample Amount: 0.967 L
Compound
2,3,7,8-TCDD
Internal Standards
I 3C-2,3, 7,8-TCD D
Clcan-un Rccove1-v Standard
37Cl-2,3,7,8-TCDD
Date Analyzed
DB-5: 11/11/00
Analyst: RS
Date Received:
Date Extracted:
10/75/00
I I /8/00
Cone.
ND
DL
0.00154
MDL
0.00226
%R
91.4
%R
99.1
Page I of I
IA
J!!!!!!!!!!>
ALTA
Lab ID: 9304-001
QC Set 1.105
'½,Solids: 0.110
Units: ng/L
Qualifier
Reviewer: fif;:2""" ....
•
•
A
B
C
D
E
F
G
H
I
Cone.
D.L.
NA
SIN
*
ND
MPC
DATA QUALIFIERS & ABBREVIATIONS
The amount detected is below the Method
Calibration Limit.
This compound was also detected in the blank.
The amount detected is less than five times the Method
Quantitation Limit.
The amount reported is the maximum possible concentration.
The detection limit was raised above the Method Quantitation
Limit due to chemical interferences.
This result has been confirmed on a DB-225 column.
This result has been confirmed on a SP-2331 column.
The signal-to-noise ratio is greater than 10:1.
Chemical Interference
Concentration
Detection Limit
Not applicable
Signal-to-noise
See Cover Letter
Not Detected
Maximum Possible Concentration
/4. -ALTA
•
•
CURRENT CERTIFICATIONS
Bureau of Reclamation-Mid-Pacific Region---(MP-470, Res-I. I 0)
Commonwealth of Kentucky---(Certificate No. 90063)
Commonwealth of Virginia---(Certificate No. 00013)
State of Alaska, Department of Environmental Conservation---(Certificate No. OS-00197)
State of Arkansas, Department of Health---(Approval granted through CA certification)
State of Arkansas, Department of Environmental Quality---
State of California---(Ccrtificate No. 1640)
State of Connecticut---(Certificate No. PH-0182)
State of Florida---(Certificate No. 87456)
State of Louisiana---(Certificate No. 98-33)
State of Mississippi---(Approval granted through CA certification)
State of Nevada---(Certificate No. CA4 I 3)
State of New York, Department of Health---(Certificate No. 11411)
State of North Carolina---(Certificate No. 06700)
State of North Dakota, Department of Health---(Certificate No. R-078)
State of Oregon---
S tate of Pennsylvania---(Certificate No. 68-490)
State of South Carolina---(Certificate No. 87002001)
State of Texas -(Certificate No. TX247-2000A)
State of Tennessee---(Certificate No. 02996)
State of Utah---(Certificate No. E-201)
State of Washington, Department of Ecology---(Certification No. C091)
State of Wisconsin---(Certificate No. 998036160)
State of Wyoming---(Ref: SES-LB)
U.S. Army Corps of Engineers
·U.S. 5 EPA Region
May 2000
J. -ALTA
ALTA • •
CHAIN OF CUSTODY RECORD
Relinquished by: {Signature and Printed Name)
. ... .·, ,. ,--,··:·---. ,·--. -
SHIP TO: Alta Analytical Laboratory
5070 Rohen J. Mathews Parkway
El Dorado Hills, CA 95762
(9 I 6) 933-1640 • Fax (9 I 6) 933-0940
www.ahalab.com
ATTN: -'~ ./2u£<\d'.
Sample ID Date Time
f...;~30'5" / nf ,JI. In<./ 0
'
Special Instructions/Comments:
Container Types: A= 1 Liter Amber, G = Glass Jar
P = PUF, T = MMS Train, 0 = Other ______ _
Time: Receiv: d by: "' Printed Name) Date: Time: Db S'Jo ----i"c ,o o t,,c,3
Time: Date: Time:
Dale: Time: Received by: (Signature and Printed Name) Date: Time:
-~ .. . . ---. ·--~--. --.~--'-.-. . --.. ~ .
M~j o(~pment Circle or Add
Analysis(es) N,c:;; STANDARD TAT= 21 DAYS. Requested 0,, Surcharge may be applied
for less than 21 days. "-7 Shipment IO: 'V 'V TAT (Analytical Turnaround Times): 1 = 7 days, o~ r 2 = 14 days, 3 = 21 days, 4 = 28 days
"''..,,,. ~"' ,i,~' °'"'"' ~ ,1) ~<$'.~ ~-Container(s) --; 'b t-s 'b 4-~ 4-~ '
Sample Description <J"' <J"' ~C, <J"' e,'<-e,'<-<J"' TAT Qty Type Matrix BPT*
GW
SEND
DOCUMENTATION
AND RESULTS TO:
*Bottle Preservative Type: T = Thiosulfate, 0 = Other __________ _
WHITE-ORIGINAL YELLOW · ARCHIVE
IY ,;-, (.) ::, 4
.
Name: p .'+,.,, ,;z ,/
Company: -I /l
Address: ? .,,,.., JS,,._/::..,/ A-v<
City: f-,.r,vv•.rJ State:~ JJ' 0/l'(Z
Phone:flf?Q") <'71-t'llt-Fax:~[ ~'I· 'l[7'j' -· ,
Matrix Types: OW= Drinking Water, EF = Effluent, PP= Pulp/Paper,
SO= Sediment, SL= Sludge, SO= Soil, WW = Wastewater, O = Other _____________ _
PINK-COPY
STANDARD OPERATING PROCEDURE
• Attachment 1 0.B.1
(;, -, l.
AL TA Project No.: -l ,:.2)0 (
SAMPLE LOG-IN CHECKLIST
ClienUProtocol No. -------------/11 t't
I. Date Samples Arrived: ( 0 •' ?, ;--<) , .. ;; Initials: -z___, Location: ·-
2. I I ' ~ --&c::i Initials: --z, Location: t2 --, Time I Date logged in: G ( 7 !O -' s
' ·-
3. Samples Arrived By: (circle) ( FedEj UPS World Courier Other:
4. Shipping Preservation: (circle) @Blue Ice / Dry Ice / None Temp °C -fv
YES NO NA
5. Shipping Container(s) Intact"? If not, describe condition in comment section. X
6. Shipping Container(s) Custody Seals Present? )s-
Intact? If not intact. describe condition in comment section.
'j
7. Shipping Documentation Present? (circle) Shipping Label @rbill) )<z
Tracking Number gr 17-ccz. 6 9 30"16
• 8. Sample Custody Seal(s) Present? No. of Seals or Seal No. X:
Intact? -If not intact, describe condition in comment section. X:
9. Sample Contair:ier Intact? If no, indicate sample condition in comment section. ?\
10. Chain of Custody (COG) or other Sample Documentation Present? X
11. COG/Documentation Acceptable? If no, complete COG Anomaly Form. X
12. Shipping Container (circle): ALTA ( ~) Retain or ( Retu~~ >or Disposed
13. Container(s) and/or Bottle(s) Requested? y
14. Sample Control Check In/Out Log Completed? (HRMS Only) 7'
15. Drinking Water Sample? (HRMS Only) If yes, Acceptable Preservation? Y or N A.
Preservation Info From? (circle) COG or Sample Container or None Noted
16. Number of Samples Received: /1./ <l
Name: ________________ _ Date Samples Reconciled: _____ _
(Signature Required for LCMS Only)
Comments:
•
SOP# CH108r12, Page 4 of 6
•
•
•
November 10, 2000
Ms. Beverly Hudson
Remedial Project Manager
U.S. EPA -Region IV, 11 ,h Floor
North Site Management Branch
61 Forsyth Street, SW
Atlanta, GA 30303
RE: Monthly Progress Report #90
Remedial Action
Koppers Site -Morrisville, NC
Dear Ms. Hudson:
ThermoRetec Corporation
300 Baker Avenue, Suite 302
Concord, MA 01742
~~ ~•ThermoRetec
Smart SOiutions. Positive Outcomes.
[phone] Phone REcr-,.J~) 371-1448 Fax ' .cl\! t::t;,thermoretec.com
NOV 15 2000
SUPERFUNO SECTION
In accordance with the Unilateral Order, and on behalf of Beazer East, Inc. (Beazer), please find
attached four ( 4) copies of the October Monthly Progress Report for Remedial Action at the
Koppers Superfuncl Site in Morrisville, NC.
The dioxin sample was collected on October 24, 2000. Because the sample was collected late
in the month, the Laboratory results the will not be received until November 15, 2000. vVe will
submit a revised version of Table 2, along with the dioxin laboratory report within 7 clays of
receiving the data.
Should you need additional information regarding this progress report, please call Mike Slenska
at [phone] or me at [phone].
Sincerely,
ThermoRetec Consulting Corporation
G~-~
Rita Bauer
Project Geologist
RB:cg
Enclosure
cc: 0. Mattison -NC Superfuncl (2 copies)
0. Hails -Ecological Restoration, Inc.
J. Garrett -NC Division of Water Quality
P. Kilchenstcin -ThermoRetec
D. Matthews -NC Division of Water Qua!.
F: \P ROJ ECTS\03624 \Reports \Monthly\ ! OM-00. wp<l
M. Slenska -Beazer
L. Faulconer -Wake County
G. Caskey -Enwoocl Structures
M. Helbling -Beazer
a Thermo Electron company
e
Date Systems Cummulath•e SV-101 SV-10!
Check Effluent Flow Sample Sample
(yes/no) (Gallons) (yes/no) Parameters
01/04/00 "' 2,178,450 ,o
01/20/00 "' 2,201.060 ,o
02/02/00 "' 2,222,900 ,o
02/18/00 ves 2,250,320 ,o
03/03/00 "' 2,:!75,240 ,o
03/13/00 "' 2,294,030 ,o
04/12/00 "' 2,347,700 ,o
04/24/00 "" 2,371,150 "° 05/05/00 "' 2,387,750 "" 05/15/00 "' 2,411.760 "" 05/31/00 "' 2,441,250 ,o
06/14/00 "' 2,462,390 ,o
06/26/00 yes 2,481,440 ,o
07/06/00 ves 2,497,950 ,o
07/11/00 "' 2,505,2!0 ,o
07/17/00 "' 2,513,700 "' 2,4-Dichloro, Phenol
08/01/00 "' 2,536,540 "" 08/14/00 yes 2,556,590 ,o
09/05/00 '"' 2,591,501 ,o
09(27/00 "' 2,635,455 ,o
10/13/00 "' 2,656.712 ,o
10/24/00 ves 2,667,340 "' Penta, 2,4-Dichloro, Phenol
Notes:
Sampling point SV-IOI is located before the Carbon Units (pretreatment)
Sampling point SV-304 is located between the Carbon Units
Sampling point SV-30S is loctated after the Carbons Units (post-treatment)
•
I Table I
Ground11·ater Treatment Operations and Sampling Program Summary I Koppers Superfund Site
~lorrisville, North Carolina
October :moo
Associated SV-304 SV-304 Associated
Group Sample Sample Group
(yes/no) Parameters
"° ,o
,o
"' 2,4-Dichloro, Phenol I
"° ,o
"° ,o
no
,o
,o
,o
,o
,o
,o
I "' 2,4-Dichloro, Phenol I
,o
"" nn
"° "" I "' Penta, 2,4-Dich.loro, Phenol I
Associated Groups:
SV-101 -Group I is penta and 2,4-dichlorophenol; Group 2 is dioxin
SV-304 -Group I is penta and 2,4-dichlorophenol
SV-305 SV-305
Sample Sample
(yes/no) Parameters
\'CS Pcma. 2,4-Dichloro. Phenol. chronic tox
"' Penta, 2,4-Dichloro, Phenol
"' Penta. 2,4-Dichloro, Phenol, chronic tox
"' Penta. 2,4-Dichloro, Phenol, dioxin
"' Penta. 2,4-Dichloro, Phenol
H'!S Penta, 2,4-Dichloro, l'heno!
\'CS Penta, 2,4-Dichloro, Phenol, chronic tox
"' Penta, 2,4-Dichlom, Phenol
ves chronic toxicity
"' Penta, 2,4-Dich]oro, Phenol
"' Penta, 2,4-Dichloro, Phenol
"' Penta, 2,4-Dichloro, Phenol , dioxin, chronic lox
"' Penta, 2.4-Dichloro, Phenol
"' Penta, 2,4-Dichloro, Phenol
yes chronic toxicity
yes Penta, 2,4-Dichloro, Phenol, dioxin
ves Penta, 2,4-Dichloro, Phenol, chronic tox
ves Penta, 2,4-Dichloro, Phenol
"' Penta, 2,4-Dichloro, Phenol, chronic tox
"" Penta, 2,4-Dichloro. Phenol
"' Penta, 2,4-Dichloro, Phenol
"' Penta, 2,4-Dichloro, Phenol , dioxin, chronic tox
SV-305 -Group I is penta, phenol, and 2,4-dichlorophenol; Group 2 is dioxin and Group 3 is chronic toxicity
•
Associated
Group
1.3
I
1,3
1,2
I
I
1,3
I
4
I
I
I, 2, 3
I
I
3
I, 2
l.l
I
1,3
I
I
I, 2, 3
•
•
•
MONTHLY PROGRESS REPORT #90
REMEDIAL ACTION
SITE NAME: Koppers Superfund Site
Beazer East, Inc.
Morrisville, NC
USEPA DOCKET NUMBERS: 93-09-C
PERIOD ENDING: October 30, 2000
1. PROGRESS MADE THIS MONTH
2.
3.
4.
5.
6.
Remedial Action (RA) -HABITAT MIT/GA TION. No activities were conducted this
month.
Remedial Action (RA) -GROUNDWATER TREATMENT. The treatment system
operated throughout the month without upset. System performance was monitored
on a biweekly basis. Approximately 41,185 gallons of groundwater were extracted,
treated in the treatment plant and discharged between September 28, and October
30, 2000. System water samples were collected on October 13, 2000 and October
24, 2000 in accordance with the sampling schedule in the O&M manual. Samples
were submitted to Severn Trent and TriTest for laboratory analysis. The operations
and sampling programs are summarized on the attached Table 1.
Remedial Action (RA) -EFFECTIVENESS MONITORING PROGRAM. No activities
were conducted this month.
Remedial Action (RA) -CORRESPONDENCE. None.
PROBLEMS RESOLVED
PROBLEMS ANTICIPATED
UPCOMING EVENTS
PERSONNEL CHANGES
SUBCONTRACTORS
None.
None.
Continue System O&M.
None.
None.
7. ANALYTICAL DATA Analytical data from system influent and effluent sampling
received during this period are enclosed and are summarized on Table 2 .
F: \PROJECTS\03624\Reports\Monthly\ lOM-00. wpd
•
•
•
Parnmcu,r
l'~ntachh,ro henol
Table 2
Groundwater Treatment
A.J."lALYTICAL DATA SUl\fl\fARY
Koppers Superrund Site
~lorris"·ille, North Carolina
October 2000
Ana!ycical
Date Sample
Sample Locatinn
Collected sv.101
01/04100
01/20/00
02/02100
02/18100
03/03/00
03/13100
04/12100
04124/()()
05/15/00
05/31/(Ml
06/14100
06/26/(X)
01/06/()()
07117/00
08/0!/00
08114100
09/05100
09/27/00
10/13/00
10124100 33
2.4• Dichlo)nmhcn,,I 01/04100
01/20/00
02/02100
02/18100
03/03100
03/13100
04112100
04/24100
05/15100
05/31/00
06/14/00
0M26/00
07/06/00
07/17100 < IO
08/01/00
08/14100
09/05100
09127100
10113/00
10/24100 <IO
Ph~nol 01/04100
01120100
02102100
02118/00
03/03/00
031!3/00
04/12/00
04/24/00
0S/JS/00
05/31/00
06114/00
06/26100
07106100
07/17/00 <10
08/01100
08/14/00
09/05/00
09/27100
l0/!3/00
10n4100 <IO
Chnmic To~icitv 01104/00
02101/00
04112100
05/05100
06/14100
07111/00
08101100
09105/00
10n4100
Dio~in (2.J.7.ll-TCDD) 02/18/00
06115100
07/17100
10/24100
Notes: All rcsulls. are in u;::IL e~cepl llio~in. Dio~in data i1 in piwi,:rams/L.
SV-1□1 -Ildi,re Carbon Unit,
•SV-304 -Bctwe,:n Carbon Units
.. SV-305 -Attcr Carbon Unils.
Sampl<: Sample
Location Locatitin
5y.304• sv.305••
<2
<2
<2
<2 <2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2 <2
<10
<10
<10
<IO <10
<10
< 10
<10
<10
<10
<10
<10
<10
<10
<10 <10
<10
<10
<10
<IO
<10
<10 <10
<10
<10
<10
<IO <10
< 10
< 10
< 10
< 10
<10
< 10
<10
< IO
<10
<IO <10
<IO
<10
<IO
<10
<IO
<IO <10
Pas.,
Pas!
Fail
Pa.s,
Fail
Pass
fail
Fail
Fail
< 1.2
<3.94
<IJ.8~3
rc.1ul1.1 ncmJin •
Effluent Toxicity Report Fo:r;m -Chronic Pass/Fail and Acute LCSO Date: 11/07 /oo
Facility: BEAZER NPDES#: NC
abo=atory Performing Test: TRITEST, INC.
0010-0l.575
~.AIL ORIGINAL TO:
North Carolina Ce:riodaohnia
Chronic Pass/Fail Reproduction Toxicity Test
CONTROL ORGANISMS l. 2 3 4 5 6 7 B 9 10 11
Pipe#: County: WAKE
Co:nment.S!
Environmental Sciences Branch
Div. of Environmental Management.
N. C. Dept·; of EIINR
4401 Reedy Creek Road
Raleigh, North Carolina 2760'7-6445
Chronic Test Results
Calculated t = 4.566
Tabular t = 2.650
12 t Reduction = 30,4J
% Mortality Avg.Reprod.
# Young Produced 29 27 27 27 27 29 28 24 24 26 24 30
0,00 26.83
Control Control
Adult IL} ive ID}ead L L L L L L ' L L L L L L
0.00 l.8.67
Treatment 2 Treatment 2
Effluent 1;, 9 01;
TREATMENT 2 ORGANISMS l 2 3 4 5 6 7 8 9 10 11 12 Control CV
7.593% PASS PAIL
# Young Produced 15 10 15 23 24 23· 20 8 22 16 21 27 % control orgs, □ c=: producing 3rd
.Adult
brood: Checlc One
IL} ive (D} ead L L L L L L ,, L L L
1st sample 1st sample 2nd sample
pH ~ ~ ~ Control
-..
Treatment 2
s s s
t e . e t '· e -.. a n a n a n
r d r d r d
t t t
l9t sample 1st sample 2nd sample
D.O. ~ G ~ Control
Treatment 2
LC50/Acute Toxicity Test
(Mortality ex.pressed as %, combining replicates)
L L L 100%
Complete This For Either Test
Test Start Date: 10/25/00
Collection (Start) Date
Sample
Sample
Sample
Sample
Sample
1: 10/23/00 Sample 2: 10/26/00
Type/Duration 1st
Grab Comp. Duration D
I s
l JC 24 hrs L A
TJ M
2 X 24 hrs 'l' ,,
Hardnesslmg/1) 45
Spec. cond . ( µmhos} 173 BOO
temp.
Chlorine(mg/1) .......... <0.l
at receipt I •c} .... , ..... 0.5
I
Note: Please
Complete This
Section Also
start/end
LCSO = \ Method of Determination
I I 95"1 Confide.nee Limics Moving Average Probit -¾ " -% Spearman Karber -Other
pH D.O.
Organism Tested: Ceriodaphnia dubia Durationlhrs}:
Copied from DEM form AT-l. 13/87) rev. 11/95 (DUBIA ver. 4.32)
·1NT 1 1c:::::i1 n--11 >-1-' c:vl:).L v1v1, vn rinN
2nd P/F
s
A
M p
·········· ..........
897
<0.1
0.8
•
•
•
ANALYTICAL REPORT
PROJECT NO_ RALEIGH
Raleigh-Bi-Weekly NPDES
Lot i: COJ140162
Debbi Leuteritz
ThermoRetec
SEVERN TRENT LABORATORIES, INC_
Veronica Bertot
Project Manager
October 26, 2000
STL Pittsburgh is a part of Severn Trent Laboratories, Inc.
STL Pittsburgh
450 William Pitt Way
Pittsburgh, PA 15238-1330
Tel: [phone]
Fax: [phone]
www.stl-inc.com
•
•
•
Sample Receiving:
CASE NARRATlV~:
THERMORETEC CORPORATION
Raleigh
STL Lot# C0J!40162
STL Pittsburgh, PA received samples on October 14, 2000 in good condition. The cooler
was within the proper temperature range.
GC/MS Semivolatiles:
There were no problems associated with the analysis.
GC Phenols:
There were no problems associated with the analysis .
•
•
METIIODSSUMMARY
COJl40l62
PARAMETER
Phenols by GC
Semivolatile Organic Compounds by GC/MS
References:
ANALYTICAL
METHOD
SW846 8041
SW846 8270C
PREPARATION
METHOD
SW846 3520C
SW846 3520C
SW846 "Test Methods for Evaluating Solid Waste, Physical/Chemical
Methods", Third Edition, November 1986 and its updates .
SAMPLE SUMMARY
• COJl.40l.62
WO# SAMPLE# CLIENT SAMPLE ID DATE TIME
DM651 001 EFF/SV-305 10/13/00 10:05
NOTE (S) :
• The analytical results of the s;irnples listed above arc prcscn1cd on the following pages.
• All calculations arc performed before rounding to avoid round-off errors in calculated results.
-Results noted as "ND" were not detected at or above the stated limit.
-This report must not be reproduced, except in full, without the written approval of the laboratory.
-Results for the following parameters 3re never reported on a dry weight basis: color, corrosivity, density, nashpoint, ignitability, layers, odor,
paint filter test, pH, porosity pressure, reactivity, redox potential, specific gravity, spot tests, solids, solubility, tcmpcr:i.turc, viscosity, and weight.
•
•
RECffl LabNet D Buffalo CH91N-OF-CUSTODY RECORD PageeL_ of _J_
8300 Westpark D Houston
Houston, TX 77063 •
[phone] -~ Pittsburgh
Project Manager ~~-3C/\l,f..J.,i Company J1&r V\-"l-,0 ~
Project Name v3--::; 1, ~'-"Ila-,; k Add_ress 3ao '.Ec&r' ~yr. Su
Purch'ase Order No. · C,sv'Lt:,:, ;J. Ml+-C, 11 '{ v
Requested
Turn Around Time __ r._1_1) ______ _
Sampler(s) Ao.ScYl }·t,'\ I Phone# 'l1~ 'S'l i-1c/'l-'2..-Fax )1 l ' I Lf Y ~
Mail Report to: __ _,(Z-'-: T"C"--'---~---"-'-'--------
Subcontractor ___________ _
COMMENTS
tJ I Other Analyses I $ /L HNO, 5. NaOH 9> f!> !:?
0 b 2. H2S0, 6. Na,SO, .S:j 0 "" 3. H,3PO, 7. Nooe C::-.,;:
-.!!> ~ 4. HCI 8. Other(s)_£' /!, $ .!]'
if f I Media / ff O t j "' () c:: -§' cJ
..g, o? 0 ¼/4i,' "'~ ~ ~ "' it-~Q.,:;§•-.!.•.fJ-0$! 'rff ~ C, "' ,..__ Q/':J{t,' "-'(l}f?::\"...__ ~ 4 l'" * rf o.."" ~ ,l l o..0 :t ii5 .:!' ~ o'" ;.__§ o·
SAMPLE IDENTITY ;f: REMARKS
f:c::cJ::. / SJ '~ 0 ~ '"' 12\,. cc~ " "I. 'X
'
..
Relint:.:.9Jld ,;;;~ Time Received By: (Signature) Date Time D {[,5:) /+irb~ Delivery Method: In Person
I De ~ommon Carrier Relinquished By: (Signature) 'oate Time Received By: (Signature) Date Time Airbill#
1 ~3·-fo<.f r;; 13 □ Specify
Lab Courier
Relinquished By: (Signature) . Date Time l:z'BK..ature) /, Date lvoo0
'1,, /---c)-(y..,~ □ Other
'-' ,.A. v White -Lab Copy Canary -File Copy Pink -Client Copy
Cooler Receipt Form
STL Pittsburgh
·7 7/.' 0(/1 Quote: -~-~"-'--"U'-.lient: L~cc-~, IZ,, .. f--v'-Project: _______ _
Cooler Rec'd & Opened for Temp. Check on: _____ ;....:· 6_· _•-_t_'-f'--·-v_cJ_· ----------,-----
Coolers Opened and Unpacked on: --------'-(-"o'---....:c_~...,_(_-c:_,--'<'--·, _____ By: -,,( C-
(Signature)
(' ~('{ SIL Pittsburgh Lot Number: -----='--0_·'-:"'---'---'-'C"-i-1.r-'='.·::..·· _. ~~---------------
•
•
1. Were custody seals on the outside of the cooler? ______________ _
If YES, how many and where? Quantity _ [Location ----'-F-'r-~_-_i--_·· ___ _
Were signatures and date correct? ___________________ _
-2. Were custody papers included inside the cooler? ______________ _
3. Were custody papers properly filled out (ink, signed, match labels)? _______ _
4. Did you sign the custody papers in the appropriate place? ___________ _
5. Was shippers packing slip attached to this form? ______________ _
6. Were packing materials used? ____________________ _
If YES, what type? ---------1-"::....::"c..:hc..:~::..(::..'--=--__:c....,=-:.cll::c.~::.._;:,' __________ _
7. Were the samples chilled? (Record temperatures on reverse side.) ________ _
8. Were the samples appropriately preserved? ________________ _
9. Were all bottles sealed in separate plastic.bags? ______________ _
IO. Did all bottles arrive in good condition (unbroken)? _____________ _
11. Were all bottle labels complete (sample ID, preservatives, etc.)? ________ _
12. Did all bottle labels and/or tags agree with custody papers?---------,---
13. Were correct bottles used for tests indicated? ----------------
14. Were all VOA vials checked for the presence of air bubbles? __________ _
15. Was a sufficient amount of sample sent in each bottle?---------~---
Yes No ~-
/
/ ----
/)/I-_
~ ----
/' ----
/ 7-
~
,vfY . ~
16. Samples received by: FEDEX UPS CLIENT DROP-OFF OTHER CAIRBORNE -, ________ _)
Explain any discrepancies: -----------------------~------
Level 2 Review----------------------------------
Was contacted on ________ by ______________ to resolve discrepancies.
STL PT/F,b-00/96-005/COOLOOC Page 1 of2
•
I~
•
ThfET D~lET HG
Sample ID PH<.."": PH<2 PH<Z
Cooler Receipt Form
STL Pittsburgh
0G
!'o'l.IT(l) QI TPHC PHEN Su1.F
PH<2 PH.!12 PH< PH<.: PH<!l:Z
TOC TOX VOA
PH< PH<: P/UP
P: Preserved
UP: Unpreserved
h,dnu
PH<:
I
(1) "NUT" could mclude sample bottles for ammorua, chemical oxygen demand, rutrate/rutnte, TKN, or total phosphorus
Comments:--------------------------------------
Cooler Number Temperature Bottle Type Lot Number*
I ;:,._
'
* Please use an asterisk if bottle lot number was covered by the label.
STL PT/F~b-.00/96-005/COOL.OOC Page2of2
•
t-
I
FROM
11 l~.J..-:-. r ,::,A. \·\ ! \
/; /\
)-<.-· .·• v\. :
TO
' ,, .
• l,-·, --../.i.1 1/J:; /.-'V {._,
7834043873
11
,:-1 / ;, .. , ")
•
Preprint Format No. Origin Alrblll Number
□Bill 3rd Party
D Pa;d In
Advance
B!!l!ng Reference w/J/appearoo ll'lvolce
No. of Pkgs Weight(LBS) Ono box must be checked
1---~-· _,_c_,_·_~'~15~~~--E~-•;_," __ "'_t=J_'"'-!r j,¥ ~~hi] .. _I·;):~_:,:;, {
Special Instructions · ~◄SAT □◄HAA ·iVt,A:iO
□◄LAB □ 783 404 3873
•
,. :
•
•
•
THERMORETEC CORP
Client Sample ID: EFF/SV-305
GC/MS Semivolatiles
Lot-Sample fl ... : COJ140162-001 Work Order fl ... : DM6511AA Matrix ......... : WATER
Date Sampled ... : 10/13/00 Date Received .. : 10/14/00 MS Run fl ....... :
Prep Date ...... : 10/16/00 Analysis Date .. : 10/18/00
Prep Batch ll. .. : 0290392
Dilution Factor: 1 Method ......... : SW846 8270C
REPORTING
PARAMETER RESULT LIMIT UNITS
2,4-Dichlorophenol ND 10 ug/L
Phenol ND 10 ug/L
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Phenol-d5 70 (10 -113)
2-Fluorobiphenyl 56 ( 30 -110)
Nitrobenzene-d5 64 (32 -112)
Terphenyl-dl4 81 (10 -144)
2-Fluorophenol 59 (13 -110)
2,4,6-Tribromophenol 66 ( 21 -122)
•
Lot-Sample # ... :
Date Sampled ... :
Prep Date ...... :
Prep Batch# ... :
Dilution Factor:
PARAMETER
Pentachlorophenol
SURROGATE
2,4-Dibromophenol
•
•
THERMORETEC CORP
Client Sample ID: EFF/SV-305
GC Semivolatiles
COJ140162-001 Work Order# ... : DM6511AC
10/13/00 Date Received .. : 10/14/00
10/16/00 Analysis Date .. : 10/18/00
0290414
1 Method ......... : SW846 8041
REPORTING
RESULT LIMIT
ND 2.0
PERCENT RECOVERY
RECOVERY LIMITS
82 (31 -134)
Matrix ......... : WATER
MS Run# ....... :
UNITS
ug/L
• METHOD BLANK REPORT
GC/MS Semivolatiles
Client·Lot # •.. : COJ140162 Work Order# ... : DM74AlAA
MB Lot-Sample#: COJ160000-392
Analysis Date .. : 10/18/00
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Phenol
SURROGATE
Phenol-d5
2-Fluorobiphenyl
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorophenol
2,4,6-Tribromophenol
NOTE (S) :
Prep Date ...... : 10/16/00
Prep Batch# ... : 0290392
REPORTING
RESULT LIMIT UNITS
ND 10 ug/L
ND 10 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
78 (10 -113)
59 (30 -110)
70 (32 -112)
84 (10 -144)
65 (13 -110)
72 (21 -122)
• Calculacions are performed before rounding 10 avoid round-off errors in calculated results .
•
Matrix ......... : WATER
METHOD
SW846 8270C
SW846 8270C
•
Client Lot# ... : C0J140162
MB Lot-Sample#: C0J160000-414
Analysis Date .. : 10/18/00
Dilution Factor: 1
PARAMETER
Pentachlorophenol
SURROGATE
2,4-Dibromophenol
NOTE (S) :
METIIOD BLANK REPORT
GC Semivolatiles
Work Order# ... : DM75T1AA
Prep Date ...... : 10/16/00
Prep Batch# ... : 0290414
REPORTING
RESULT LIMIT UNITS
ND 2.0 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
82 (31 -134)
Calculations are performed before rounding-to avoid round-off errors in calculated results .
•
•
Matrix ......... : WATER
METHOD
SW846 8041
• LABORATORY CONTROL SAMPLE EVALUATION REPORT
GC/MS Semivolatiles
Client Lot# ... , C0J140162 Work Order# ... , DM74AlAC-LCS Matrix ......... : WATER
LCS Lot-Sample#, C0J160000-392 DM74AlAD·LCSD
Prep Date ...... , 10/16/00 Analysis Date .. , 10/18/00
Prep Batch# ... , 0290392
Dilution Factor: 1
PERCENT RECOVERY RPD
PARAMETER RECOVERY LIMITS RPD LIMITS METHOD
2-Chlorophenol 57 ( 1.9 -1.24) SW846 8270C
65 ( 1.9 -1.24) 1.4 (0-43) SW846 8270C
1,4-Dichlorobenzene 44 (28 -l.1.0) SW846 8270C
51. (28 -l.l.O) 1.5 (0-36) SW846 8270C
N-Nitrosodi-n-propyl-60 (30 -l.l.5) SW846 8270C
amine
69 (30 -l.l.5) 1.4 (0-36) SW846 8270C
1,2,4-Trichloro-48 ( 31. -l.1.0) SW846 8270C
benzene
56 (31. -l.1.0) 1.6 (0-37) SW846 8270C
4-Chloro-3-methylphenol 67 (29 -1.24) SW846 8270C • 78 (29 -1.24) 1.5 (0-55) SW846 8270C
Acenaphthene 62 (39 -l.l.8) SW846 8270C
74 (39 -l.1.8) 1.8 (0-35) SW846 8270C
4-Nitrophenol 62 ( 1.9 -1.44) SW846 8270C
76 ( 1.9 -1.44) 20 (0-34) SW846 8270C
2,4-Dinitrotoluene 73 (4 7 -1.31.) SW846 8270C
88 (4 7 -1.31.) 1.8 (0-32) SW846 8270C
Pentachlorophenol 69 (l.O -1.40) SW846 8270C
81. (l.O -1.40) 1.6 (0-56) SW846 8270C
Pyrene 73 (46 -1.30) SW846 8270C
87 (46 -1.30) 1.7 ( 0-31.) SW846 8270C
Phenol 49 (l.O -1.31.) SW846 8270C
56 ( 1.0 -1.31.) 1.4 (0-43) SW846 8270C
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Phenol-d5 52 (10 -113)
60 (10 -113)
2-Fluorobiphenyl 48 (30 -110)
57 (30 -110)
Nitrobenzene-ds 56 (32 -112)
66 (32 -112)
Terphenyl-dl4 71 (10 -1.44)
84 (10 -144)
2-Fluorophenol 44 (13 -110)
51 (13 -110) • 2,4,6-Tribromophenol 64 (21 -122)
76 (21 -122)
{Continued on next page)
•
•
"
•
LABORATORY CONTROL SAMPLE EVALUATION REPORT
GC/MS Semivolatiles
Client Lot# ... , C0J140162 Work Order# ... , DM74AlAC-LCS Matrix ......... , WATER
LCS Lot-Sample#, C0J160000-392 DM74AlAD-LCSD
SURROGATE
NOTE (S),
PERCENT
RECOVERY
Calculations arc performed before rounding to avoid round-off errors in calculated results.
Bold print denotes control parameters
RECOVERY
LIMITS
•
•
•
LABORATORY CONTROL SAMPLE EVALUATION REPORT
GC semivolatiles
Client Lot# ... , COJ140162 Work Order# ... , DM75T1AC-LCS
DM75T1AD-LCSD
Analysis Date .. , 10/18/00
Matrix ......... , WATER
LCS Lot-Sample#, COJ160000-414
Prep Date ...... , 10/16/00
Prep Batch# ... , 0290414
Dilution Factor: 1
PERCENT RECOVERY
PARAMETER RECOVERY LIMITS
Pentachlorophenol 82 (50 -126)
78 (50 -126)
PERCENT
SURROGATE RECOVERY
2,4-Dibromophenol 77
77
NOTE(S),
Calculations are performed before rounding to avoid round-off errors in calculated results.
Bold print denotes concrol parameters
RPD
RPD LIMITS METHOD
SW846 8041
4.8 (0-20) SW846 8041
RECOVERY
LIMITS
(31 -134)
(31 -134)
•
•
•
ANALYTICAL REPORT
PROJECT NO. RALEIGH
Raleigh-Bi-Weekly NPDES
Lot ft, C0J250205
Debbi Leuteritz
ThermoRetec
SEVERN TRENT LABORATORIES, INC.
~dH;ri&
Veronica Bortot
Project Manager
November 6, 2000
STL Pittsburgh is a part of Severn Trent Laboratories, Inc.
STL Pittsburgh
450 William Pitt Way
Pittsburgh, PA 15238-1330
Tel: [phone]
Fax: [phone]
VN-Jw.stl-inc.com
•
•
•
Sample Receiving:
CASE NARRATIVE
THERMORETEC CORPORATION
Raleigh
SIL Lot# C0J250205
SIL Pittsburgh, PA received samples on October 25, 2000 in good condition. The cooler
was within the proper temperature range.
GC/MS Semivolatilcs:
There were no problems associated with the analysis.
GC Phenols:
For the continuing calibration standard analyzed on the RTX-5 column on October 30,
2000 at 17:58 pentachlorophenol was outside of the +/-15%D criteria. The average of all
of the compounds in the continuing calibration standard was 14.4%. Pentachlorophenol
was reported in sample EFF/SV-102. The sample was confirmed on the RTX-200
column where pentachlorophenol was within the +/-15%D criteria. The result was
reported from the RTX-200 column. All other samples were non detect for this
compound .
•
•
•
PARAMETER
Phenols by GC
METHODS SUMMARY
COJ250205
ANALYTICAL
METHOD
Semivolatile Organic Compounds by GC/MS
SW846 8041
SW846 8270C
References:
PREPARATION
METHOD
SW846 3520C
SW846 3520C
SW846 "Test Methods for Evaluating Solid Waste, Physical/Chemical
Methods", Third Edition, November 1986 and its updates .
•
•
•
~ SAMPLE# CLIENT SAMPLE ID
DNQJH
DNQJJ
DNQJL
NOTE (S):
001
002
003
EFF/SV-305
EFF/SV-102
EFF/SV-304
SAMPLE SUMMARY
C0J250205
-The analytical results of the samples listt.'d above arc presented on the following pages.
-Al! calculations an: performed before rounding to avoid round-off errors in calculated results.
-Results notc..'t! as "ND" were n0t detected at or above the Stated limit.
-This report must not be reproduced, except in full, without the written approval of the laboratory.
-Results for the following parameters are never reported on a dry weight basis: color, corrosiviry, density, flashpoint, ignitability, layers, odor,
paint tilter test, pH, porosity pressure, reactivity, redox potential, specific gravity, spot tests, solids, solubility, temperature, viscosity, and weight.
DATE TIME
10/24/00 10,40
10/24/00 10,50
10/24/00 10,55
Cham of
Custody Record
STL-!124 (0700)
Client
\\,\U'""o O,t.i
Ad~ B..¥w' L(,,,,
C,t~ _
• t • I h'1A I z;~c:~ '1,__
Project Name and Location (State)
Contrac//Purchase Order/Quote No.
Sample /.D_ No. and Description Date (Containers for each sample may be combined on one line) ,
,:;-r=PI r v -1 ~ s--ldtr//(J{)
I >V-I 1"17-
. '
Sv-3o4 ,v
Possible Hazard Identification
~ Non-Hazard 0 Flammable 0 Skin Irritant 0 Poison 8
Turn Around Time Required
•
Project Manager ~ 0 l: r I c.L....,._s+e.·.,.
Telephone Number (Area Code)/Fax Number
·~·]11-!t/Zt
Site Contact Lab Contact
f<fm-'l~ Caz;i::=b~ 7'6J'-/ofJ 770
Containers & C) ~ Matrix Preservatives ....
J . 0 "' , 1l, ~ ~ e Time 0 'a 0 "' 0 0 0 ,o • 0 § N " • C o ' "' "' , , , " N <
/o</o y. f. Ix 1-
loS-0 I I
loS') ~ :, "\I 'ii
I Sample Disposal
D Unknown O Return To Client D Disposal By Lab 0 Archive For
OC Requirements
0 24 Hours 0 18 Hours D 7 Days D 14 Days D 21 Days ~Other ff() ,...,.---,_ Specify) I\
1. Relinquished B~ J+.JI 0j: f pt/i,o I r7.<? 0 1rce~e~By /1 I \
~
u
2. Relinquished By
1
Dace':
1
Time 2~By '
3. Relinquished By l Date
1
Time 3. Received By
Comments
DISTRIBUTION: WHITE· Stays with the Sample: CANARY -Returned to Client with Report: PINK -Field Copy
•
Severn Trent Laboratories, I
Dati di,{ /(!)0 Chain of Custody Number
UU.13
Lab N1Jmbei I
Page l of I
Analysis {Attach list if
more s ace is needed)
Special Instructions;
Conditions of Receip
(A lee may be assessed if samples are retained
Months longer than 3 months)
,
YOP<1?>i1 Time// ~
l1'e/ I Tim~
j Date
1
Time
Cooler Receipt Form
~,., 1 STL Pittsburgh
Client: & Project: ---c-,--------Quote: ____ _
• Cooler Rec'd &
7
Opened for Temp. Check on: ----c-'-1""".0t\l_;cc·;?~,;/,stli-:;l,(rt,:-;it"'(J----=-_L!/41/;}i~,•✓1 /j_~-~/====-
Coolers Opened and Unpacked on: _______ .-'-/---,,...1,-=-t;,,,_f""',2~/--,,½"". 11__,u"""·-' ____ Btk/2 .... &~-+!----
()C. _1 l ~• 1
_i _., 1 _ (Signature) sn Pittsburgh Lot Number: -------'-=--"-) ..,:.l_,./_.'-'-'"-(-"'.'..c·=a::· ·c.c< ... ,--"•,.>:_,,___ ______________ _
Yes Na
1. Were custody seals on the outside of the cooler? ______________ _
IfYES, haw many and where? Quantity_ Location ____________ _
Were signatures and date correct? ___________________ _
2. Were custody papers included inside the cooler? ______________ _ /' -:r---
3. Were custody papers properly filled out (ink, signed, match labels)? _______ _ L-
4. Did you sign the custody papers in the appropriate place? ___________ _ /
5. Was shippe·rs packing slip attached'ta this form? ___ ...:..., __________ _ ./
Were packing materials used? ~ /,,////"=
IfYES, what type? ( G/J,,V~ ---1,/
Were the samples chilled? (Record temperatures on reverse side.) ________ _
6.
• 7.
/,/
8. V.iere the samples appropriately preserved? ________________ _
9. Were all bottles sealed in separate plastic bags? ______________ _
I 0. Did all bottles arrive in good condition (unbroken)? _____________ _
I 1. Were all bottle labels complete (sample ID, preservatives, etc.)? ________ _
l2. Did all bottle labels and/or tags agree with custody papers? __________ _
13. Were correct bottles used for tests indicated? ----------------
l4. Were all VOA vials checked for the presence of air bubbles? __________ _
15.
16.
Was a sufficient amount ofsamole sent in each bottle? _________ ~--==-...,,,,,,,----· ~ ----=--,.,,_ -~ ·· ....... ,
CLIENT DROP-OFF ~~ORl'JE j
/ /
/
Samples received by: FEDEX UPS
Explain any discrepancies:
• Level 2 Review----------------------------------
Was contacted on ________ by ___ _c._ __________ to resolve discrepancies.
STL PT/Fcb-00/96--'J05/COOLDOC Page I of2
• ThiET
PH<:
STL Pittsburgh
0G
O?,,,JET HG ~(I) Qf TI'HC PHEN
PH<: PH<: PH<: PH ::t: PH<: PH<:
P: Preserved
\JP: Unpreserved
Sl.iLF rec TOX VOA WISS
PH c!!: PH<: PH<: P/L'P PH<:
I I l---------l--+---+-----l--1---+--+--+----+--+---+---+--+----1----i____.Jl1
ij
' • I <l--------+---+--+--+----+----+--+---+---+----,--+---+--+--+---1--'I
;11--------+---+--+--+----+----+--+---+---+----,--+-'---+--+---1---1-___Jl1 I
I I I
i'1--~---+---+--t-----il--+---+--+----i--+--+--t--+--+-1---+-----'II I !,1------+-----1---+--t--+---+---+--t-----t----1----1---,1---+---+--+---)II
I I 11-----+---+--+--+--f----+--+--+--+----i-.-+------'i---t-+----i--ljl
I
~1-----1---+I -+---t---+--t---+---+--+--+---+---+--+-+-+-1J
(1) ''NUT' could :.nc!ude sa.-rnpk bottJes for ammorua, cht!rrucal oxygen demand, rutra~rutnte, TKN', or total phosphorus
Comments:-----------------------------------------
Cooler Number Temperature Bottle Type Lot Number*
(2_1 I
J I
I
I I
' I
I
I
I I
I : I I
I
• Ple:ise use an asterisk if bottle lot number was covered by the label. • STL PT/Feb-O0i96-005iCOOL.DOC Page 2 of2
•
+
lU
z
:r:
f--
-~ 'fl. en W'""~"" 1--_, z
0. w
:;;
0..
:r: en
'a:
0 u.
FROM
Bt(i1.; 6 ,~·FD
'·: i: ,;:, ;; ILL t .,:tr•~
Ft
!;' j -T T
7834043770
11111 I 1111
Origin A1 ill Number
Preprint ~orrnat No.
7834043770
Assumed sender unless olhenYise Mted
AIRBORNE
EXPRESS.
BiUing Reference willappea,-co/rnuice
No. ol Pkgs Weigllt(LBS)
Special Instructions
•
□◄SAT
□◄LAB
□◄HAA
0
i ~ .. ' ' _,.,,,,.,.
783 404 3770
; '
•
•
•
THERMORETEC CORP
Client Sample ID, EFF/SV-305
GC/MS Semivolatiles
Lot-Sample lt ... ' COJ250205-001 Work Order lt ... , DNQJHlAA Matrix ......... , WATER
Date Sampled ... , 10/24/00 Date Received .. : 10/25/00 MS Run lt ....... ,
Prep Date._ .... : 10/26/00 Analysis Date .. : 10/30/00
Prep Batch lt ... ' 0302093
Dilution Factor: 1 Method ......... ' SW846 8270C
REPORTING
PARAMETER RESULT LIMIT UNITS
2,4-Dichlorophenol ND 10 ug/L
Phenol ND 10 ug/L
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Phenol-d5 34 (10 -113)
2-Fluorobiphenyl 58 ( 3 0 -110)
Nitrobenzene-ds 65 ( 32 -112)
Terphenyl-d14 80 (10 -144)
2-Fluorophenol 51 (13 -110)
2,4,6-Tribrornophenol 73 (21 -122)
•
•
THERMORETEC CORP
Client Sample ID: EFF/SV-305
Lot-Sample# ... : C0J250205-001
Date Sampled ... : 10/24/00
Prep Date ...... : 10/26/00
Prep Batch# ... : 0302095
Dilution Factor: 1
PARAMETER
Pentachlorophenol
SURROGATE
2,4-Dibromophenol
GC Semivolatiles
Work Order# ... : DNQJHlAC
Date Received .. : 10/25/00
Analysis Date .. : 10/30/00
Method ......... : SW846 8041
REPORTING
RESULT LIMIT
ND 2.0
PERCENT RECOVERY
RECOVERY LIMITS
97 (31 -134)
Matrix ......... : WATER
MS Rllil # ....... :
UNITS
ug/L
THERMORETEC CORP
• Client Sample ID, EFF/SV-102
GC/MS Semivolatiles
Lot-Sample ll ... ' COJ250205-002 Work Order ll ... , DNQJJlAA Matrix ......... , WATER
Date Sampled ... ' 10/24/00 Date Received .. : 10/25/00 MS Run# ....... ,
Prep Date ...... , 10/26/00 Analysis Date .. : 10/30/00
Prep Batch ll ... ' 0302093
Dilution Factor: 1 Method ......... , SW846 8270C
REPORTING
PARAMETER RESULT LIMIT UNITS
2,4-Dichlorophenol ND 10 ug/L
Phenol ND 10 ug/L
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Phenol-d5 75 (10 -113)
2-Fluorobiphenyl 66 ( 30 -110)
Nitrobenzene-dS 76 (32 -112)
Terphenyl-dl4 73 (10 -144)
2-Fluorophenol 62 (13 -110)
2,4,6-Tribromophenol 81 (21 -122)
•
•
•
•
THERMORETEC CORP
Client Sample ID: EFF/SV-102
GC Semivolatiles
Lot-Sample# ... : COJ250205-002 Work Order# ... : DNQJJlAC
Date Received .. : 10/25/00
Analysis Date .. : 10/30/00
Date Sampled ... : 10/24/00
Prep Date ...... : 10/26/00
Prep Batch# ... : 0302095
Dilution Factor: 1 Method ......... : SW846 8041
REPORTING
PARAMETER RESULT LIMIT
Pentachlorophenol 33 2.0
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
2,4-Dibromophenol 86 (31 -134)
Matrix ......... : WATER
MS Run# ....... :
UNITS
ug/L
THERMORETEC CORP
• Client Sample ID: EFF/SV-304
GC/MS Semivolatiles
Lot-Sample # ... : COJ250205-003 Work Order ll ... : DNQJLlAA Matrix ......... : WATER
Date Sampled ... : 10/24/00 Date Received .. : 10/25/00 MS Run# ....... :
Prep Date. _ .... : 10/26/00 Analysis Date .. : 10/30/00
Prep Batch# ... : 0302093
Dilution Factor: 1 Method ......... : SW846 8270C
REPORTING
PARAMETER RESULT LIMIT UNITS
2,4-Dichlorophenol ND 10 ug/L
Phenol ND 10 ug/L
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Phenol-d5 51 (10 -113)
2-Fluorobiphenyl 43 (30 -110)
Nitrobenzene-dS 50 (32 -112)
Terphenyl-dl4 83 (10 -144)
2-Fluorophenol 40 (13 -110)
2,4,6-Tribromophenol 72 (21 -122)
•
•
•
Lot-Sample # ... :
Date Sampled ... :
Prep Date ...... :
Prep Batch # ... :
Dilution Factor:
PARAMETER
Pentachlorophenol
SURROGATE
2,4-Dibromophenol
•
TIIERMORETEC CORP
Client Sample ID: EFF/SV-304
GC Semivolatiles
COJ250205-003 Work Order # ... : DNQJLlAC
10/24/00 Date Received .. : 10/25/00
10/26/00 Analysis Date .. : 10/30/00
0302095
1 Method ......... : SW846 8041
REPORTING
RESULT LIMIT
ND 2.0
PERCENT RECOVERY
RECOVERY LIMITS
104 (31 -134)
Matrix ......... : WATER
MS Run# ....... :
UNITS
ug/L
•
•
METHOD BLANK REPORT
GC/MS Semivolatiles
Client Lot# ... , C0J250205 Work Order# ... , DN06XlAA
MB Lot-Sample#, C0J280000-093
Analysis Date .. , l0/30/00
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Phenol
SURROGATE
Phenol-dS
2-Fluorobiphenyl
Nitrobenzene-ds
Terphenyl-dl4
2-Fluorophenol
2,4,6-Tribromophenol
NOTE (S) ,
Prep Date ...... , l0/26/00
Prep Batch# ... , 0302093
REPORTING
RESULT LIMIT
ND l0
ND l0
PERCENT RECOVERY
RECOVERY LIMITS
73 (l0 -ll3)
70 (30 -ll0)
74 (32 -ll2)
Sl (l0 -l44)
6l (l3 -ll0)
80 (2l -l22)
Calcubtions arc performed before rounding to avoid round-off errors in calculated results .
UNITS
ug/L
ug/L
Matrix ......... , WATER
METHOD
SW846 8270C
SW846 8270C
•
•
Client Lot# ... : COJ250205
MB Lot-Sample#: COJ280000-095
Analysis Date .. : 10/30/00
Dilution Factor: 1
PARAMETER
Pentachlorophenol
SURROGATE
2,4-Dibromophenol
NOTE {S) :
METHOD BLANK REPORT
GC Semivolatiles
Work Order# ... : DN07FlAA
Prep Date ...... : 10/26/00
Prep Batch# ... : 0302095
REPORTING
RESULT LIMIT UNITS
ND 2.0 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
76 ( 31 -134)
Calculations are performed before rounding to avoid round-off errors in calculated results .
Matrix ......... : WATER
METHOD
SW846 8041
• LABORATORY CONTROL SAMPLE EVALUATION REPORT
GC/MS Semivolatiles
Client Lot# ... , COJ250205 Work Order # ... , DN06XlAC·LCS Matrix. _ . _ . _ . _ . : WATER
LCS Lot-Sample#, COJ280000·093 DN06XlAD·LCSD
Prep Date ...... , 10/26/00 Analysis Date .. : 10/30/00
Prep Batch# ... , 0302093
Dilution Factor: 1
PERCENT RECOVERY RPD
PARAMETER RECOVERY LIMITS RPD LIMITS METHOD
2-Chlorophenol 63 (19 -124) SW846 8270C
66 (19 -124) 5.6 ( 0-43) SW846 8270C
1,4-Dichlorobenzene 61 (28 -110) SW846 8270C
64 (28 -110) 4.8 (0-36) SW846 8270C
N-Nitrosodi-n-propyl-56 (30 -115) SW846 8270C
amine
59 (30 -115) 6.2 (0-36) SW846 8270C
1,2,4-Trichloro-67 (31 -110) SW846 8270C
benzene
68 (31 -110) 2.8 (0-37) SW846 8270C
4-Chloro-3-methylphenol 69 (29 -124) SW846 8270C
73 (29 -124) 5.0 (0-55) SW846 8270C • Acenaphthene 69 (39 -118) SW846 8270C
73 (39 -118) 5.8 (0-35) SW846 8270C
4-Nitrophenol 69 (19 -144) SW846 8270C
75 (19 -144) 8.8 (0-34) SW846 8270C
2,4-Dinitrotoluene 74 (4 7 -131) SW846 8270C
80 (4 7 -131) 8.0 (0-32) SW846 8270C
Pentachlorophenol 77 (10 -140) SW846 8270C
82 (10 -140) 6.5 (0-56) SW846 8270C
Pyrene 75 (46 -130) SW846 8270C
79 (46 -130) 5.9 (0-31) SW846 8270C
Phenol 62 (10 -131) SW846 8270C
66 (10 -131) 5.7 (0-43) SW846 8270C
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Phenol-d5 64 (10 . 113)
68 (10 . 113)
2-Fluorobiphenyl 63 (30 . 110)
66 (30 . 110)
Nitrobenzene-dS 66 (32 . 112)
70 (32 . 112)
Terphenyl-dl4 75 (10 . 144)
78 (10 . 144)
2-Fluorophenol 54 (13 . 110)
57 (13 . 110) • 2,4,6-Tribromophenol 74 (21 . 122)
78 (21 . 122)
(Continued on next page)
•
•
LABORATORY CONTROL SAMPLE EVALUATION REPORT
GC/MS Semivolatiles
Client Lot# ... : C0J250205 Work Order# ... : DN06XlAC-LCS Matrix ......... : WATER
LCS Lot-Sample#: C0J280000-093 DN06XlAD-LCSD
SURROGATE
NOTE(S):
PERCENT
RECOVERY
Calculations are performed before rounding to avoid round-off errors in calculated results.
Bold prim denotes control parameters
RECOVERY
LIMITS
11/10/00 10:54 FAX [phone] ALTA ANALYTICAL 141001/017
• /1,.
•
•
ALTA
November 6, 2000
Alta Batch I.D.: 9154
Ms. Rita Bauer
TherrnoRetec Consulting Corporation
300 Baker A venue
Suite 302
Concord, MA 01742
Dear Ms. Bauer,
Enclosed are the results for the five aqueous samples re'ceived at Alta Analytical Laboratory on
September 28, 2000. This work was authorized under HARP ID# 0530-0540-1000. These
samples were extracted and analyzed using EPA Method 8290 for 2,3,7,8-TCDD only. A
standard turnaround time was requested for this work .
The following report consists of a Sample Inventory (Section I), Analytical Results (Section II) and
the Appendix. The Appendix contains a copy of the ch~-of-custody, a list of data qualifiers and
abbreviations, our current certifications, diskette deliverables, and copies of the raw data.
Alta Analytical Laboratory remains committed to serving you in the most effective manner.
Should you have any questions or need additional information and technical support, please do not
hesitate to contact me. Thank you for choosing Alta as part of your analytical support team.
Sincerely,
Alta Analytical Laboratory Inc.
5070 Robert J. Mathews Parkway
El Dorado HUis, CA 95762
FAX [phone]
{916) 9.~~-1640
•
•
•
11/10/00 10:55 FAX [phone] ALT.-\ ANALYTICAL
Section I: Sample Inventory Report
Alta Lab. ID
9154-001
9154-002
9154-003
9154-004
9154-005
Date Received: 9/28/00 ··,
Client SamoJe ID
C-29B
PW-01
C-14A
Equipment Blank
Field Blank
(ii] 002/01 i , .. -ALTA
11/10/00 10:55 FAX [phone] ALTA ANALYTICAL la] 003/017
lit. -ALTA
•
SECTION II .
•
•
•
•
•
11/10/00 10:55 FAX [phone] ALTA ANALYTICAL
METHOD BLAi'IK
Matrix: Aqueous
Compound
2,3,7,8-TCDD
Internal Standards
l3C-2,3,7 ,8-TCDD
Clean-up Recovery Standard
37Cl-2,3, 7,8-TCDD
Date Analyzed
~ 11/4/00
Analyst: RS
TCDD
EPA METHOD 8290
Date Received: NA
Date Extracted: 11/2/00
Sample Amount: 1.000 L
~
ND
.'½R
68.4
.'½R
94.2
Page 1 ofl
DL
2.40
!·
MDL
0.711
14] 004/017
JJt. -ALTA
Lab ID: 0-MB00I
QCSet: LQB.1
Units: ugLL
Qualifier
Reviewer: &.)
•
•
11/10/00 10:56 FAX [phone] ALTA ANALYTICAL
OPRRESULTS
Lab ID:
Matrix:
Compound
OPR00J
Aqueous
2,3,7,8-TCDD
Internal Standards
13C-2,3,7,8-TCDD
Clean-up Recovery Standard
37Cl-2,3, 7,8-TCDD
Date Analyzed
l!B:.5l 11/4/00
Analyst: ES
TCDD
EPA METHOD 8290
Date Received: NA
Date Extracted: j l/2/00
Sample Amount: 1.000 L
Spike
~
10.0
Spike
Q!fil.
100
Spike
~
40.0
Page 1 of 1
Amount
Found
8.96
¾R
64.5
91.8
QC Set: .L0M
Units: ng/mL
QPR Limits
7 -13
QPR Limits
40 -135
QPR Limits
40 -135
Reviewer: &J__.
@] 005/01 i
l1t. -ALTA
•
•
•
11/10/00 10:56 FAX [phone] ALTA ANALYTICAL
TCDD
EPA METHOD 8290
Sample ID:
Project:
C-29B
BEAZER/RALEIGH
Matrix:
Sample Amount:
Compound
2,3,7,8-TCDD
Aqueous
Q,272 L
Internal Standards
13C-2,3,7,8-TCDD
Clean-up Recovery Standard
37Cl-2,3, 7,8-TCDD
Date Analyzed
Illi:S.;. 11/4/00
Analyst: RS
Date Received:
Date Extracted:
Cone,
ND
¾R
93.9
%R
95.7
Page 1 of 1
9/28/00
11/2100
DL
1.21
Mfil.
0.711
i4J 006/017
J., -ALTA
Lab ID: 9!54-001
QC Set: .1.J2a:!
Units:
Qualifier
•
•
11/10/00 10:56 FAX [phone] ALTA ANALYTICAL
TCDD
EPA METHOD 8290
Sample ID:
Project:
PW-OJ
BEAZER/RALEIGH
Matrix:
Sample Amount:
Compound
2,3,7,8-TCDD
AQ.ueous
O 993 L
Internal Standards
13C-2,3, 7,8-TCDD
Clean-up Recoverv Standard
37Cl-2,3, 7,8-TCDD
Date Analyzed
DB-5: 11/4/00
Analyst: RS
Date Received:
Date Extracted:
.Qiru;,
ND
.½R
72.7
%R
92.5
Page 1 of I
9/28/00
j j/2/00
fil
1.24
MDL
0.711
Lab ID:
QC Set:
Units:
[4]007/017
IA -ALTA
9154-002
1 084
Qualifier
Reviewer: &
•
•
•
11/10/00 10: 56 FAX [phone] ALTA ANALYTICAL
TCDD
EPA METHOD 8290
Sample ID:
Project:
C-)4A
BEAZER/RALEIGH
Matrix:
Sample Amount:
Compound
2,3,7,8-TCDD
AmieQu~
0.916 L
Internal Standards
13C-2,3,7,8-TCDD
Clean-up Recovery Standard
37Cl-2,3,7,8-TCDD
Date Analyzed
M=5.:_ 11/4/00
Analyst: RS
Date Received:
Date Extracted:
.Qm£,
ND
½R
72.8
%R
87.4
Page 1 of I
IQL28/QQ
) 1/2/00
ill. MDL
2.13 0.711
i4J 008/0li
IA -ALTA
Lab ID: 9)54-Q03
QC Set: .L.QM
¾Solids: lLl..iQ
Units: ,llZLL
Qualifier
Reviewer: ~
•
•
•
11/10/00 10:57 FAX [phone] ALTA ANALYTICAL
TCDD
EPA METHOD 8290
Sample ID:
Project:
Equipment Blank
BEAZER/RALEIGH
Matrix:
Sample Amount:
Compound
2,3,7,8-TCDD
A(Jl!eous
Q.288L
Internal Standards
13C-2,3,7,8-TCDD
Clean-up Recovery Standard
37Cl-2,3,7,8-TCDD
Date Analyzed
M=5..:. 11/4/00
Analyst; RS.
Date Received:
Date Extracted:
Cone,
ND
¾R
64.8
"/4,R
80.7
Page 1 orl
9128/QQ
I J/2/QQ
DL
1.24
Mill,
0.711
Lab ID:
QC Set:
Units:
141009/0li
IA -ALTA
9154-004
.LD.8.:!'
Qualifier
Reviewer: fil_
•
•
11/10/00 10:57 FAX [phone] ALTA ANALYTICAL
TCDD
EPA METHOD 8290
Sample ID:
Project:
l\1atrix:
Field Blank
BEAZER/RALEIGH
Sample Amount:
Compound
2,3,7,8-TCDD
Aqueous
0.996 L
Internal Standards
13 C-2,3, 7,8-TCDD
Clean-up Recovery Standard
37Cl-2,3, 7,8-TCDD
Date Analyzed
:!:rn=5.; 11/4/00
Analyst: BS
Date Received:
Date Extracted:
CQm;,
ND
%R
71.1
%R
94.7
Page I of I
9/28/00
11/2/00
IlL
1.73
MDL
0.711
Ii/) 010/017
/1.. -ALTA
Lab ID: 9 I 54-005
QC Set: ) 084
Units:
Qualifier
Reviewer: &.
11/10/00 10:57 FAX [phone] ALTA ANAL YT! CAL li1J011/017
J. -ALTA
•
APPENDIX
•
•
•
•
11/10/00 10:58 FAX [phone] ALTA ANALYTICAL
A
B
C
D
E
F
G
H
I
Cone.
D.L.
NA
SIN
*
ND
MPC
DATA QUALIFIERS & ABBREVIATIONS
The amount detected is below the Method
Calibration Limit.
This compound was also detected in the blank.
The amount detected is less than five times the Method
Quantitation Limit.
The amount reported is the maximum possible concentration.
The detection limit was raised above the Method Quantitation
Limit due to chemical interferences.
This result has been confirmed on a DB-225 column.
This result has been confirmed on a SP-2331 column.
The signal-to-noise ratio is greater than 10:1.
Chemical Interference
Concentration
Detection Limit
Not applicable
Signal-to-noise
See Cover Letter
Not Detected
Maximum Possible Concentration
14] 012/017
Ji.. -ALTA
11/10/00 10:58 FAX [phone] ALTA ANALYTICAL
CURRENT CERTIFICATIONS
• Bureau of Reclamation -Mid-Pacific Region -(MP-470, Res-1.10)
Commonwealth of Kentucky -(Certificate No. 90063)
Commonwealth of Virginia
•
•
State of Alaska -(Certificate No. OS-00197)
State of Arkansas Department of Health -(Approval granted through CA certification)
State of Arkansas Department of Pollution Control
State of California--:-(Certificate No. 1640)
State of Connecticut -(Certificate No. PH-0182)
State of Florida -(Certificate No. 87456)
State of Nevada -(Certificate No. CA413)
State of New York Department of Health -(Certificate No. 11411)
State of North Carolina -(Certification No. 06700)
State of North Dakota Department of Health -(Certificate No. R-078)
State of Oregon
State of Pennsylvania -(Certificate No. 68-490)
State of South Carolina -(Certificate No. 87002001)
State of Tennessee -(Certificate No. 02996)
State of Utah -(Certificate No. E-201)
State of Wisconsin -(Certificate No. 998036160)
State of Wyoming -(Ref: SES-LB)
U.S. Army Corps of Engineers
U.S. EPA Region 5
Washington Department of Ecology -(Certification No. C091)
1-17-97
[f1l 013/017
/1,,. -ALTA
• . . \ ) ' .
Chain of
Custody Record
Client
-... P1-t-;,. ProaM•"[; R '11, ~ -....
Address
Ave.., 9u~"i{n't~ ,"vz:z:umber 3,o R,,_\u f
cf' J ~·a. I z;p ;~·, "z. Site Contact Lab Contact . , '. 0 Project Name R.t. 0 n ;,,\,_
Garrier,,Waybl/1 Number
-~ R_ Ort_?,e,{'
Contracr.tPurchass Ords /Quote Na. ' Matm< Containers & '\ Preservatives ·,
l . • 1l ~ li • Sample I.D. No. and Description • 0 --Date Time i ! ~ ~ i] I t.c (Containers far each sample may be combined on one line) , ' "' " ~ ,:
C-f '-/,4 ,,1 t, 1/00 I loo II(; I~ )( .
ef;iblo HBZard Jdenlification
Non-Hazard O Flammable 0 Slcin Irritant D PofsonS
I Sample Disposal
0 Unknown D Return To Client (Yoisposal By Lab D Archive For
Tum Around Time Required OC Requirements (Spedfy)
D 24 Hours O 48 Hours O 7 Days D f 4 DBys D 21 DBys
1. Relinquished By Time
(6&o
Time
Time
Comments
D15ffi/Bl.l110N: WHITE -Sta vs with the Samo le; CANARY -Rerumed ta Client with Reoort: PINK -Field Conv
• • ~
,4LTA-
0•J°o[-i1\ oo Chain of Custody Numbn 7 2 5 4
Lab Nutnber
Psge l of I
Analysis (Attach list if
more s ace is needed
Special Instructions/
Condffions of Receipt
(A fee may be assessed if samples arc rotafned
-Months longer than 3 months)
Time 1/cm
·,,
.... ....
----....
0
----0
0
'TJ ,.
H
"' ....
"'
"' c., c.,
0 "' ...
0
0 .,.
"" 0 M
M
"' "' "" "'
0
...; .·
0
0 -...
0 ...; -... "" ""
www FMFM#i!i◄M
Chain oa
Custody'~ecord
STL-"124 (0700!
Client
,
I • I -,~ /MC) ,eu,; tat-C
Projac/ Manager 12,m (], A _,.
~ --··--. .. r .. ·--· -· ... s ls;"**
••
I I ::; :Is: 8 I
Oare Cf /,;i.,,i/ 0 0 Chain of Custody Numbor
001676 Address m~r;;r'A;i;:~ ~";:; ,-r't ~ t Lab Numbor
300 17,.J.,,r/.J AV£ , .ru rm:,, j'c:,2., Page \ a, I
City /;;_ rp ;0;;V2. S1 a Conlact
CA ,--.IC<!) /?/}
Projec/ Name and Location ($/;1/e) Carn"er/Waybill Number
,, -·-r..# I /Jtt.e16tf .,(Ve. Fm~£ \C
Con/rac//Purchase O(der/Quota No.
Matrix
Sample I.D. No. and Description Date Time l • l (Contaim1rs for each sample may be combined on one line) -~ • ' ~
r -'.l 'l /!. 't / ;,1,1 lai ((SO I\
/Jw--o/ ,s-,o
C-11( A /'(Sb
l:9Jf'Jr-~A-~ ,-AJA 1:..-l~
C,_,,., A /f/At\/K.-\ I /1/CT'J I\
Possible Hazard Identification I Sample Disposal
D Non-Hazard D Flammable □ Skin lrrilant 0 PoisonB D Unknown D Relum To Client
Turn Around T1ma Requ,red
D 24 Hours D 4B Hours D 14 Days D 21 Days 0 Olher
1. Relinquished By
2. Relinquishod By
J. Relinquished By Date
Comments
DISTRIBUTION: WHl!E -Stays with the Sample; CANARY-Retumed to Cliarit with Report PINK -Fiald Copy
Lab Cdntact 11 Analysis (Attach list if
more s ace is needed)
I~ C I ..
I-Special Instructions!
Containers & ' "'-'< -l1 Conditions of Receipt
Preservatives ~I~ .. i 0 ~ ' ~· 0 ~(l :<l 0 G 0 ,o cS ! ~ r!:ii > >
I' r 'l. I ;t
2
'
'" 1, 12-
(A fee may ba a"ssessed if samp/as ara ra/ainad 0 Disposal By Lab 0 Archive For Months longer than 3 month.sJ
QC Reqwroman/s (Spac1fy)
Time
/6@
Tims
J. Received By nm,
11/10/00
•
•
11:00 FAX [phone] ALTA ANALYTICAL
STANDARD OPERATING PROCEDURE
li1I016/017
· Attachment 10.8.1
SAMPLE LOG-IN CHECKLIST
AL TA Project No.: Cf/ s'f Client/Protocol No .. _____ J.J_,_[~,i,_ ____ _
I. Date Samples Arrived: q'-~ Initials: JU~ Location: /..,.;~-(
2. Time I Date logged in: / tJ /:Z-00 /._'J'Oc> .:ir Initials: fj/ ,,/_ Location: Lui?-! ..,
]. Samples Arrived By: (circle) ~UPS World Courier Other:
4. Shipping Preservation: (circle) (§:,' Blue Ice / Dry Ice / None Temp °C ()
YES NO NA
5. Shipping Container(s) Intact"? If not, describe condltlon ... in comment section. ><
6. Shipping Container(s) Custody Seals Present? y
Intact? If not intact. describe condition in comment section. ~
7. Shipping Documentation Present? (circle) Shipping label ~ Tracking Number ?2:2~ ~L/'-"Jj2o c;-_ ><
8. Sample Custody Seal(s) Present? No. of Seals ·-· or Seal No. r: .I ' Intact? -If not intact, describe condition in comment section. v
9. Sample Container Intact? If no, indicate sample condition in comment section. y_
10. Chain of Custody (COC) or other Sample Documentation Present? y
11. COG/Documentation Acceptable? If no. complete COC Anomaly Fann. )C
12. Shipping Container (circle): ALTA e, ~or Return or Disposed
13. Container(s) and/or Bottle(s) Requested? )<
14. Sample Control Check In/Out Log Completed? (HRMS Only) ><
.,
15. Drinking Water Saf!lple? (HRMS Only) If yes. Accep_table Preservation? Y or N )< Preservation Info From? (circle) COG or Sample ~ontainer or None Noted
' w.l~ 16. Number of Samples Received:
Name:-,,---.....,.,---,------,,-,-------
(Signature Required for LCMS Only)
comments:
SOP# CH10Br12, Page 4 of 6
..
Date Samples Reconciled: _____ _
11/10/00 11: 00 FAX [phone] ALTA ANALYTICAL i4J 017 /017
STANDARD OPERATING PROCEDURE
• Attachment 10.B.1
SAMPLE LOG-IN CHECKLIST
ALTA Project No.: _q__._.)'--'-lCf..._ __ Client/Protocol No.,_~/J~. -0~--------
-
/ /J /--,__; (rAJ £/ ,,,,,,
Location: l,.J fZ, ( I. Date Samples Arrived: Initials: '-f •
'
2. Time/ Date logged in: /0/A L~ //;),,) Initials: ~ Location: ~I<,{_ -
3. Samples Arrived By: (circle) ('FedEx) UPS World Courier Other:
4. Shipping Preservation: (circle) (ic9t Blue Ice / Dry Ice / None Temp •c ---z_
YES NO NA
5. Shipping Container(s) Intact"? If not, describe condition in comment section. ·~
6. Shipping Container(s) Custody Seals Present? •. IX
Intact? If not intact, describe condition in comment section. X
7. Shipping Documentation Present? (circle) Shipping Label ®> >< Tracking Number 'i?[ 210, 2/.,.73_Cf 3S
• 8 . Sample Custody Seal(s) Present? No. of Seals or Seal No. "i<-
Intact? .If not intact, describe condition in comment section. '-./
9. Sample Container Intact? If no, indicate sample condition in comment section. 'y
10. Chain of Custody (COC) or other Sample Documentation Present? y
11. CDC/Documentation Acceptable? If no, complete COC A.~omaly Form. '-{-
12. Shipping Container (ciicle): ALT< Clie,V (":Ret;;;;;:__or Return or Disposed
13. Contalner(s} and/or Bottle(s) Requested? )(
14. Sample Control Che_ck In/Out Log Completed? (HRMS Only) ',L,
' ' 15. Drinking Water Sample? (HRMS Only) If yes. Acceptable Prese,vation? Y or N f--Preservation Info From? (circle} coc or . Sample Container or None Noted
16. Number of Samples Received: Al/,1..,
Name: ________________ _ Date Samples Reconciled: _____ _
(Signature Required for LCMS Only}
Comments:
SOP#CH10Br12,Page~of6:
•
•
•
October 5, 2000
Ms. Beverly Hudson
Remedial Project Manager
U.S. EPA-Region lV, 11 th Floor
North Site Management Branch
6 I Forsyth Street, SW
Atlanta, GA 30303
RE: Monthly Progress Report #89
Remedial Action,
Koppers Site -M6rrisville, NC
Dear Ms. Hudson:
ThermoRetec Corporation
300 Baker Avenue, Suite 302
Concord, MA 01742
-OrhermoRetec
Smart Solutions. Positive Outcomes.
[phone] Phone
{978) 371-1448 Fax
www.thermoretec.com
RECEIVED
0CT17 2000
SUPERFUND SECTION
In accordance with the Unilateral Order; and on behalf of Beazer East, Inc. (Beazer),
please find attached four ( 4) copies of the August Monthly Progress Report for Remedial
Action at the Koppers Superfund Site in Morrisville, NC. Please note that the
Cumulative Effluent flow readings presented on Table I, which had been calculated
based on average daily flow, have been corrected to reflect the cumulative flow meter
readings recorded by the field technician.
Should you need additional information regarding this progress report, please call Mike
Slenska at [phone] or me at [phone]
Sincerely,
ThermoRetec Consulting Corporation
y I r
Lf·•-t.A...---.2;;.r..~-.(. t ,. \\
Rita Bauer·
Project Geologist
RB:cg
Enclosure
cc: D. Mattison -NC Superfund (2 copies)
D. Hails -Ecological Restoration, Inc.
). Garrett -NC Division of YVater Quality
P. IGlchenstein -TherrnoRetec
D. Matthews -NC Division of YVater Qua!.
F: \PR OJ E CTS\03624\Reports\M unthly\9 M-00. wpd
M. Slenska -Beazer
L. Faulconer -Wake County
G. Caskey -Enwood Structures
M. Helbling -Beazer
a Thermo Electron company
•
MONTHLY PROGRESS REPORT #89
REMEDIAL ACTION
SITE NAME: Koppers Superfund Site
Beazer East, Inc.
Morrisville, NC
USEPA DOCKET NUMBERS: 93-09-C
PERIOD ENDING: September 30, 2000
1. PROGRESS MADE THIS MONTH
2.
3.
4.
5.
6.
Remedial Action (RA) -HABITAT MIT/GA T/ON. No activities were conducted this
month.
Remedial Action (RA) -GROUNDWATER TREATMENT. The treatment system
operated throughout the month without upset. System performance was monitored
on a biweekly basis. Approximately 55,455 gallons of groundwater were extracted,
treated in the treatment plant and discharged between August 29, and
September 27, 2000. System water samples were collected on September 5, 2000
and September 27, 2000 in accordance with the sampling schedule in the O&M
manual. Samples were submitted to Severn Trent and TriTest for laboratory
analysis. The operations and sampling programs are summarized on the attached
Table 1.
Remedial Action (RA) -EFFECTIVENESS MONITORING PROGRAM. No activities
were conducted this month.
Remedial Action (RA) -CORRESPONDENCE. None.
PROBLEMS RESOLVED
PROBLEMS ANTICIPATED
UPCOMING EVENTS
PERSONNEL CHANGES
SUBCONTRACTORS
None.
None.
Continue System O&M.
None.
None.
7. ANALYTICAL DATA Analytical data from system influent and effluent sampling
received during this period are enclosed and are summarized on Table 2 .
F: \PROJ ECTS\03624 \Repons\Monthly\9M-00. wp<l
•
Dace Systems Check Cummu!acive SV-101 SV-101
(yes/no) Effluent Flow Sample Sample
(Gallons) (yes/no) Parameters
01/(WOO ves 2,178,450 no
01/20/00 "' 2,201.060 no
02/02/00 "' 2,222,900 no
02/18/00 ves 2,150,320 no
03/03/00 ves 2,275,240 no
03113/00 VO, 2,294,030 no
04/12/00 m 2,347,700 no
04/2,HOO VO, 2,371,150 no
05/05/00 "' 2,387,750 no
05/15/00 ves 2,411,760 no
05/31/00 m 2,441,250 no
06/14/00 "' 2,462.390 no
06/26100 VOS 2,481,440 no
07/06/00 vc, 2,497,950 no
07/11/00 m 2,505,210 no
•
Tahle 1
Groundwater Treatment Operations and Sampling Program Summary
Koppers Supcrfund Site
l\1orrisl·ille, North Carolina
September 2000
Associated SV-304 SV-304 Associa1ed SV 305
Group Sample Sample Group Sample
(yes/no) Parameters (yes/no)
no yes
no yes
,m ye,
m 2,4-Dichloro, Phenol I m
no yes
no ye,
no m
no ves
no yes
no yes
no yes
no ves
no yes
no yes
no yes
SV 305
Sample
Parameters
Penta. 2,4-Dichloro, Phenol, chronic toxicity
Penta, 2,4-Dichloro, Phenol
Penta, 2,4-Dichloro, Phenol, chronic toxicity
Penta, 2,4-Dichloro, Phenol, dioxin
Penta, 2,4-Dichloro, Phenol
Penta, 2,4-Dichloro, Phenol
Penta, 2,4-Dichloro, Phenol, chronic toxicity
Penta, 2,4-Dichloro, Phenol
chronic mxiciw
Penta, 2,4-Dich!oro, Phenol
Penta, 2,4-Dichlorn, Phenol
Penta, 2,4-Dichloro, Phenol , dioxin, chronic toxicity
Penta, 2,4-Dich\oro, Phenol
Penta, 2,4-Dichloro, Phenol
chronic toxicity
07/17/00 "' 2,513,700 V,S 2,4-Dichloro, Phenol I \·es 2,4-Dichloro, Phenol I yes Penta, 2,4-Dichloro, Phenol, dioxin
08/01/00 yes 2,536,540 no
08/14/00 yes 2,556,590 no
09/05/00 yes 2,591,501 no
09/27/00 ves 2,635,455 no
Notes:
Sampling point SV-101 is located before the Carbon Units (pretreatment)
Sampling point SV-304 is located between the Carbon Units
Sampling point SV-305 is loctated af1er the Carbons Units (post-treatment)
no ye,
no yes
no \'CS
no ye,
Associated Groups:
SV-101 -Group I is pema and 2,4-dichlorophenol: Group 2 is dioxin
SV-304 -Group I is penta and 2,4-dich!orophenol
Penta, 2,4-Dich!oro, Phenol, chronic toxicity
Penta, 2,4-Dichloro, Phenol
Penta, 2,4-Dichloro, Phenol, chronic toxicity
Penta, 2,4-Dichloro, Phenol
SV-305 -Group I is pema, phenol, and 2,4--dichlorophenol; Group 2 is dioxin and Group 3 is chronic toxicity
e
Associ:itcd
Group
1,3
I
1,3
1.2
I
I
1,3
I
4
I
I
I, 2, 3
I
I
3
1, 2
1,3
I
1,3
I
•
•
Table 2
Groundwater Treatment
ANALYTICAL DATA SUMMARY
Koppers Superfund Site
Morrisville, North Carolina
September 2000
Analytical
Parameter Dale Sampk
Sample Location
Collected SV-101
l'cntachloro )henol 01104/00
01/20/00
02/02/00
02/18100
03/03/00
03/13/()()
04/12/00
04/24/00
05115100
05/31/00
06/14/00
06/261()()
07/06100
07/!7/00
08/01/00
08/14/00
09/05/00
09/27/00
2. 4-Dichloronhenol 01/04/00
Ol/20/00
02/02/00
02/18/00
03/03/00
03/13/00
04/12100
04/24/00
05/!5/00
05/JJ/O()
06/!4100
06/26100
07/06100
07/17100 <JU
08/0J /(IO
08/14/00
09/05100
09127/()()
Pl1enol OJ/04/(Kl
01/20/00
02102100
021111/()()
03103100
03/13/00
04112/00
04124/!Xl
05115/00
05/31/00
06/14/00
06126/00
07/06/00
07/17/00 <10
08/01100
08114/(Kl
09105100
09n7/00
Chronic Toxicitv 01/04100
02101/(Xl
04112100
05/05/00
06114/()()
07/11/00
08101/00
09105/00
Dioxin (2,3,7,11-TCDD) 02118/()()
06115100
07/17/00
Notes: All rc.rnhs are in ug/L except dic1'in. Dioxin data is in picogrn1m/L.
SV-101 -Before Carbon Units
•SV-304 -Between Carbon Units
••SV-305 -After Carbon Units
Sample Sample
Location Location
SV-304• SV-J05u
<2
<2
<2
<2 <2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
< IO
< IO
< 10
< IO < IO
<10
<10
< IO
<10
< IO
<10
<10
<10
<10
< 10 < 10
<10
<10
<10
< IO
< 10
<10
<10
<JU <10
<10
<10
<10
< 10
< 10
<10
<10
<10
<10
<10 < 10
<10
< 10
<10
< 10
Pass
Pass
Fail
P~,
Fail
Pass
Fail
Fail
< 1.2
<3.94
<0.863
•
•
•
ANALYTICAL REPORT
PROJECT NO. RALEIGH
Raleigh-Bi-Weekly NPDES
Lot#, C0I060l78
Debbi Leuteritz
ThermoRetec
SEVERN TRENT LABORATORIES, INC.
~ut{)drnz±
Veronica Bertot
Project Manager
September lB, 2000
STL Pittsburgh is a part of Severn Trent Laboratories, Inc.
STL Pittsburgh
450 William Pitt Way
Pittsburgh, PA 15238-1330
Tel: [phone]
Fax: [phone]
www.stl-inc.com
Sample Receiving:
CASE NARRATIVE
THERMORETEC CORPORATION
Raleigh
STL Lot# C0I060178
STL Pittsburgh, PA received samples on September 6, 2000 in good condition. The
cooler temperature was at 7°C.
GC/MS Scmivolatiles:
There were no problems associated with the analysis.
GC Phenols:
There were no problems associated with the analysis.
•
•
•
PARAMETER
Phenols by GC
METHODS SUMMARY
COI060l78
ANALYTIC/IL
METHOD
Semivolatile Organic Compounds by GC/MS
SW846 8041
SW846 8270C
References:
PREPAR".TION
METHOD
SW846 3520C
SW846 3520C
SW846 "Test Methods for Evaluating Solid Waste, Physical/Chemical
Methods11 1 Third Edition, November 1986 and its updates .
SAMPLE SUMMARY
COI060l.78
l:!Q_JL_ SAMPLE# CLIENT SAMPLE ID TIME
DJXRC 0 0 l. EFF. SV-305 09/05/00 12:15
NOTE (S) :
-The analytica.l results of the samples listed above arc presemed on the following pages.
-All calculations arc performed before rounding to avoid round-off errors in calculated results.
-Results noted as "ND" were not detected at or above the stated limit.
-This report must not be reproduced, except in full. without the written appruv:il of the laboratory.
-Results for the following parameters are never reported on a dry weight basis: color, corrosivity, density, flashpoint, igni1ability, layers, odor,
paint filter tcsl, pH. porosity pressure, reactivity, redox potential, specific gravity, spot tests, solids, solubility, temperature, viscosity. and weight.
1 1ii i Chain of
Custody Record
OUA-4124 0797
Client
11f/£i2.=o /) ,...,£:G
Address
10D [J,411£,L, ,41,&
City ~A C-OrJwf-!J
Project Name
/aCE! Ld 6.,,;-A-~ r,',,J
Contract/Purchase Ord('r!Ouote No,
Sample I.D. No. and Description
lz~~1n-,
(Containers for each sample may be combined on one line) Date
err lrv-'JOS-'-1/S-/:D
Possible Hazard Identification
D Non-Hazard D Flammable 0 Skin Irritant D PoisonB
11J, e ~uanferra
• .c
Project Manager Date"J/s/oo Chain of Custody Numbt) 7 2 5 Rn-A {]AV~
Te<i70Yi ni' (Ar; ::;2z: Number
Lab Number I ) Page of
Site Contact Lab Contact Analysis {Attach list if
more s ace is needed
Carrier/Waybill Num~
A I /4f c,l!Al'tZ;. IC--cJ7..)Y~iY Special Ins/ructions/
Containers & Conditions of Receipt
Matrix Preservatives I~ 0
l ~ o <n ,: <15 ~ fil Time ti ~ § ~ Q u Q • 0 ~ ~ ~~ ' <n <n ,: ,:
ll!S-'I-"'f-_ I'>< IX -'
,.
I Sample Disposal
0 Archive For /J (A lee may be assessed if samples are retained D Unknown D Return To Client D Disposal By Lab .. Months longer than 3 months)
Turn Around Time Required Q~ent Spe Cr// I I D 24 Hours D 48 Hours D 7Days D 14 Days D 21 Days □ Other. I I
1. Relinquished By A .P, _,P
I
0
;;"/ dao 1 ';m;,, oo 1 Received By ~! I I r:f# l,;:r-(7 ;J 0
-I "-,t I I
2. Relinquished {!J:,/ uu
1
Date
1
Time 2. ,o,._ V ~ ' lJa1/
1
Time
J
3. Relinquished By [ Date ] Time 3. Received By
1
Dale
1
Time
Comments
DISTRIBUTION: WHITE -Slays with the Sample; CANARY -Returned to Client with Report; PINK -Field Copy
3
Oient: $(1,
Cooler Receipt Form
STL Pittsburgh
;,
.ler Rec'd & Opened for Temp. Check on: -------,f--7L.J",,L-.C!.;k.'.,-,:__~-----{._....,Ll-,!.4:...__
Coolers Opened and Unpacked on: _________ _!_ __ _.:::,.LJ.C....L.J~'-----
/
STL Pittsburgh Lot Number: ____ _..;.(_7,_0_---_0_u_·_~;_u_· .:....l.:....?...!Y'.._· _· ----------
1. Were custody seals on the outside of the cooler? ___________ ,,__ __ _
If YES, how many and where? Quantity_ Location ------,d'-,l-/4..:..;/::...:..· ____ _
Were signatures and date correct? _____________ __: _____ _
2. Were custody papers included inside the cooler? ---------------
3. Were custody papers properly filled out (ink, signed, match labels)? _______ _
4.
5.
6.
Did you sign the custody papers in the appropriate place? ___________ _
Was shippers packing slip attached to this form? ______________ _
Were packing materials used? ----1""---------=-~L..:7j?j-,-;·-,,91:..,·;(./ _ _LZ__,L.,L--,!./ ____ _
IfYES, what type? ____ ---::-~--,L.-/'-. ce:tL~¼~_5J:::.JL.~-L~_:c-i..!=~~=----
Were the samples chilled? (Record temperatures on reverse side.) ________ _
Yes No
L
/
8. Were the samples appropriately preserved? /
9. Were all bottles sealed in separate plastic bags? '/,-. -
10. Did all bottles arrive in good condition (unbroke_n_)? __ --------------/,--
11. Were all bottle labels complete (sample ID, preservatives, etc.)? /-, -
12. Did all bottle labe_ls and/or tags agree with custody papers? ~
13. Were correct bottles use·d for tests indicated?---------------'----.. / --
'14. Were all VOA vials checked for the presence of air bubbles? _________ _ J;/ ~
15. Was a sufficient amount of sample sent in each bottle?-----========:;;:::;===--...::::;::
16. Samples received by: FEDEX UPS CUEN'T DROP-OFF --OTHE AIRB O Ri'-!E '
Explain any discrepancies: _____________________________
_
Cl Level 2 Review----------------------------------
Was contacted on ________ by ______________ to resolve discrepancies.
STL PT/~\J.y-00196-00:51COOLDOC Page 1 of 2
\,,;Oo1er Heceipt Form
STL Pittsburgh
P: Preserved
UP: Unpreserved
I~ 0G
DMET HG NUT(l) CN TIHC PHEN SULF TOC TOX VOA hronss I
!
I
I
I
Smiplc rD
TMIT
PH<.:? PH<.2 PH<:! PH<2 PH 2'12 PH-::.:?. PH<.2 PH 2:12 PH<.2 ?H<.2 P/UP PH<2
(1) "NUT' could mclude sample bottles tor ammonia, cherrucal oxygen demand, nitrate/nitrite, TK..'\f, or meal pnosphorus
II
O:omments: -----------------------------------------
Cooler Number Temperature Bottle Type Lot Number•
7"' I /
'
I
• Please use an asterisk if bottle lot number was covered by the label.
•
STL PT/May-00196-005,COOLDOC Page2of2
•
THERMORETEC CORP
Client Sample ID, EFF. SV-305
GC/MS Semivolatiles
Lot-Sample # ... ' C0I060178-001 Work Order # ... ' DJXRCl0l Matrix ......... , WATER
Date Sampled ... , 09/05/00 Date Received .. : 09/06/00 MS Run# ....... ,
Prep Date_ .. ___ : 09/09/00 Analysis Date .. , 09/12/00
Prep Batch # ... ' 0255117
Dilution Factor: 1 Method ......... , SW846 8270C
REPORTING
PARAMETER RESULT LIMIT UNITS
2,4-Dichlorophenol ND 10 ug/L
Phenol ND 10 ug/L
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Phenol-dS 59 (10 -113)
2-Fluorobiphenyl 60 (30 -110)
Nitrobenzene-ds 58 (32 -112)
Terphenyl-dl4 74 (10 -144)
2-Fluorophenol 39 (13 -110)
2,4,6-Tribromophenol 68 (21 -122)
TIIERMORETEC CORP
• Client Sample ID: EFF. SV-305
GC Semivolatiles
Lot-Sample # ... : COI060178-001 Work Order # ... : DJXRC102 Matrix ......... : WATER
Date Sampled ... : 09/05/00 Date Received .. : 09/06/00 MS Run# ....... :
Prep Date ...... : 09/09/00 Analysis Date .. : 09/13/00
Prep Batch # ... : 0255129
Dilution Factor: 1 Method ......... : SW846 8041
REPORTING
PARAMETER RESULT LIMIT UNITS
Pentachlorophenol ND 2.0 ug/L
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
2,4-Dibromophenol 99 (31 -134)
0
METHOD BLANK REPORT
GC/MS Semivolatiles
Client Lot# ... : C0I060178 Work Order# ... : DK5FR101
MB Lot-Sample#: C0ill0D00-117
Analysis Date .. : 09/12/00
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Phenol
SURROGATE
Phenol-d5
2-Fluorobiphenyl
Nitrobenzene-ds
Terphenyl-dl4
2-Fluorophenol
2,4,6-Tribromophenol
NOTE (S) :
Prep Date ...... : 09/09/00
Prep Batch# ... : 0255117
REPORTING
RESULT LIMIT
ND 10
ND 10
PERCENT RECOVERY
RECOVERY LIMITS
61 (10 -113)
63 (30 -110)
59 (32 -112)
72 (10 -144)
40 (13 -110)
70 (21 -122)
• Calculations arc performed before rounding to avoid round-off errors in calculated results .
•
Matrix ......... : WATER
UNITS METHOD
ug/L SW846 8270C
ug/L SW846 8270C
•
•
METHOD BLANK REPORT
GC Semivolatiles
Client Lot ft ... : C0I060178 Work Order ft ... : DK5GF101
MB Lot-Sample ft: C0ill0000-129
Analysis Date .. : 09/13/00
Dilution Factor: 1
PARAMETER
Pentachlorophenol
SURROGATE
2,4-Dibromophenol
NOTE (S) :
Prep Date ...... : 09/09/00
Prep Batch ft .•• : 0255129
REPORTING
RESULT LIMIT
ND 2.0
PERCENT RECOVERY
RECOVERY LIMITS
82 (31 -134)
Calculations arc performed before rounding to avoid round-off errors in calculated results .
Matrix ......... : WATER
UNITS METHOD
ug/L SW846 8041
LABORATORY CONTROL SAMPLE EVALUATION REPORT
GC/MS Semivolatiles
Client Lot# ... , C0I060178 Work Order# ... , DK5FR102-LCS Matrix ....... _.: Wl<TER
LCS Lot-Sample#, C0ill0000-117 DK5FR103-LCSD
Prep Date ...... , 09/09/00 Analysis Date._: 09/12/00
Prep Batch# ... , 0255117
Dilution Factor: 1
PERCENT RECOVERY RPD
PARAMETER RECOVERY LIMITS RPD LIMITS METHOD
2-Chlorophenol 68 (19 -124) SW846 8270C
71 (19 -124) 3.0 (0-43) SW846 8270C
l,4-Dichlorobenzene 65 (28 -110) SW846 8270C
68 (28 -110) 3.5 (0-36) SW846 8270C
N-Nitrosodi-n-propyl-69 (30 -115) SW846 8270C
amine
73 (30 -115) 5.9 (0-36) SW846 8270C
1,2,4-Trichloro-65 (31 -110) SW846 8270C
benzene
67 (31 -110) 3.6 (0-37) SW846 8270C
4-Chloro-3-methylphenol 74 (29 -124) SW846 8270C • 77 (29 -124) 3.2 (0-55) SW846 8270C
Acenaphthene 68 (39 -118) SW846 8270C
70 (39 -118) 2.8 (0-35) SW846 8270C
4-Nitrophenol 65 (19 -144) SW846 8270C
65 (19 -144) 0.050 (0-34) SW846 8270C
2,4-Dinitrotoluene 64 (4 7 -131) SW846 8270C
66 (47 -131) 3.4 (0-32) SW846 8270C
Pentachlorophenol 57 (10 -140) SW846 8270C
55 (10 -140) 3.5 (0-56) SW846 8270C
Pyrene 69 (46 -130) SW846 8270C
71 (46 -130) 2.5 (0-31) SW846 8270C
Phenol 70 (lO -131) SW846 8270C
72 (10 -131) 3.8 (0-43) SW846 8270C
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Phenol-d5 70 (10 -113)
72 (10 -113)
2-Fluorobiphenyl 65 (30 -110)
67 (30 -110)
Nitrobenzene-ds 64 (32 -112)
66 ( 32 -112)
Terphenyl-dl4 69 (10 -144)
70 (10 -144)
2-Fluorophenol 46 (13 -110)
47 (13 -110) • 2,4,6-Tribromophenol 71 (21 -122)
72 (21 -122)
(Continued on next page)
•
LABORATORY CONTROL SAMPLE EVALUATION REPORT
GC/MS Semivolatiles
Client Lot# ... : C0I060178 Work Order# ... : DKSFR102-LCS Matrix ......... : WATER
LCS Lot-Sample#: C0ill0000-117 DKSFR103-LCSD
SURROGATE
NOTE (S):
PERCENT
RECOVERY
Calculations are performed before rounding to avoid round-off errors in calculated results.
Bold prim denotes control parameters
RECOVERY
LIMITS
•
•
LABORATORY CONTROL SAMPLE EVALUATION REPORT
GC Semivolatiles
Client Lot# ... : C0I060178 Work Order# ... : DK5GF102-LCS
DK5GF103-LCSD
Analysis Date .. : 09/13/00
Matrix ......... : WATER
LCS Lot-Sample#: C0ill0000-129
Prep Date ...... : 09/09/00
Prep Batch# ... : 0255129
Dilution Factor: 1
PERCENT RECOVERY
PARAMETER RECOVERY LIMITS
Pentachlorophenol 74 (50 -126)
78 (50 -126)
PERCENT
SURROGATE RECOVERY
2,4-Dibromophenol 80
80
NOTE (S):
Calculations :ire performed before rounding to avoid round-off errors in calculated results.
Bold prim denotes control parameters
RPD
RPD LIMITS METHOD
SW846 8041
4.4 (0-20) SW846 8041
RECOVERY
LIMITS
(31 -134)
(31 -134)
•
ANAL ITICAL REPORT
PROJECT NO. RALEIGH
Raleigh-Bi-Weekly NPDES
Lot#, C0I280148
Debbi Leuteritz
TherrnoRetec
SEVERN TRENT LABORATORIES, INC.
Veronica Bertot
Project Manager
October -1, 2000
STL P1!lsburgh is a part of Severn Trent Laboratories, !nc.
-~SERVIC-ES~ ,.
STL Pittsburgh
450 William Pitt Way
Pitt;;burgl1, PA 15238-1330
Tel: [phone]
Fax: [phone]
www.stl-inc.com
•
•
•
Sample Receiving:
CASE NARRA TJVE
THER.t'VIORETEC CORPORATION
Raleigh
STL Lot # COI280 I 48
STL Pittsburgh, PA: receivecl samples on September 28, 2000 in good condition. The
cooler temperature was at 7°C.
GC/MS Semivolatiles:
There were no problems associated with the analysis.
GC Phenols:
There were no problems associated with the analysis .
Chain of
Custody Record
STL 412~ (07001
Client
T f/-r,_,.2,n 6 /?£,7e:-L.,
Address
Project Manager
l?rrA-MC/rL
TeleµJ,011e Number (Area Code)/Fax Number
A-v£ (cqg) Y/1-1'12:z_ Yll -/yyl{
'
Project Name and Locar1un (Stale)
8,£4.,ff..P /R41r.,,,:,,Cf
Cor,tracl/Purchuse O,derlDuo!e No.
Sample f,O. No. and Description Date (Cont;iinr:rs (o.• er,ch sample m'.ly be com!Jined on one line)
r,, r F I .s v JoS--q/1.-1/CXJ
Possible Hazard Identification
D Non-Haza:d [] Flammable D Skm /rritanr D PoisonB
Tum Around Time Reauired
Site Contact
C.Jrrier/Waybi/1 Number
r'G.J ~£-~;
Matrix
Time I ti 1l ' • ~ ~
!too )
!
Sample Disposal
D Unknown D Retum To Client
D 24 Hours 0 48 Hours 0 / Days 0 14 Days D 21 Oats O Other
1_ .'?elinquished By
[
0'1/L1/oo I r;~3 0
2 Relinquished Sy
1
Date ! rime
3 Relinquished By _joa1e
1
Time
Comments
DISTRIBUTION: WHITE -Sta;-s wilh ;,~e Samµle: CANARY-Returned fo Client with Report: PINK· Field Copy
Lab Contact
Containers &
Preservatives
D Disposal By Lab
J_ Received By
'
D Archive For
e
Severn Trent Laboratories, Inc.
Lab Number
Analysis (Attach list if
more soace is needed)
Chain of Cusrody Number
Page I
nr·1 ::;1° .,• _) .l. ' ---.J
of (
Special Instructions/
Conditions of Receipt
(A lee may be assessed if samples are retainea
Months longer than 3 months)
I; Date t I """' I
1
Dale j Tune
•
re)
STL Pittsburgh Lot Number: ------~G:__:CJ:::.._~__;Z=..,_"r...:::;c.:_vl:__' c/.L . .JY,__ ________ _
Yes No
1. Were custody seals on the outside of the cooler? ______________ _ ~
IfYES, how many and where? Quantity_ Location-''--------------
Were signatllres and date ~orrect? ___________________ _ ,,//
2. Were custody papers included inside the cooler? _______ '---------_.L..,
3. Were custody papers properly filled out (ink, signed, match iabeis)? _______ _ ....,L_
4. Did you sign the custody papers in the appropriate place? ----'----------L
5. Was shippers packing slip attached to this form? ______________ _ L
6.
Q
Were packing materials used? . /7 !' h/
IfYES, what type? <:...ti, J:f4
./'
7. Were the samples chilled? (Record temperatures on reverse side.) ________ _
8. Were the samples appropriately preserved? ________________ _
9. Were all bottles s~aled in separate plastic bags? ______________ _
10. Did all bottles arrive in good con_dition (unbroken)? _____________ _
l 1. Were all bottle labels complete (sample ID, preservatives, etc.)? ________ _
12. Did all bottle labels and/or tags agree with custody papers? __________ _
13. Were correct bottles used for tests indicated? _______________ _
14. Were all VOA vials checked for the presence of air bubbles? __________ _
15. Was a sufficien ounkifsampl
/ /'
1 '5. Sarnple,H{ce,v~: FEDEX
, ' . -. . .{ .,_ _,.,. t:xp,am any mscrepanc1e-------==----------------------~------
sent in each bottle? -------------
UPS CLlfNT DROP-OFF OTHER A.IRBOR.t's'E
• Level 2 Review----------------------------------
Was contacted on -------'--by ______________ to resolve discrepancies.
STL PT/Fcb-00/96-D05/COOLDOC Page I of 2
•
STL Pittsburgh
-
ex,
TMET 01',.[ET HG ,nJT(J) CN TPEC PEEN
S-.rnpic ID ?H·<:! PHs.-: PH._'": PH,--z PH~12 PH<.: PH<1
I
"
•. I
SUL~ TOC TOX
PH.::1::: PH<.: PH<.:
..
I
VOA
P/UP
I
I
I
I
P: Preser,ed
UP: Unpreser1ed
"""=
P'H<:
I
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I
-(I) •~1lJT" could Ulclude sample bottles tor ammorna.., chemical oxygen de:!'land. nio-atdniL'1te, TIQ-i, er tot.a! phosphorus
I .,
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I
Comments:---------------------------------------
Cooler Number Temperature Bottle Type Lot Number*
c'!' ,.
~
I
I ' I
I
I ' I
'I I I
I
• ?!ease use an asterisk if bottle lot number was covered by the label.
STI. ?TiFclr00/96-005iCOOL.DOC Page 2 of2
• II'!-_r::;,.,,,,,-rt:,"\)11:'½,~: ·, . .,, r-,.-'.,; O_e~_ _'.j )Zc:?f ci () ,, o, ''"''"' -~ -.c/' / -4•~ Na1nu __ .) t~-t.z-LL!,J' V~-Phooe 'flJ :}_1L:J'fT'£ COfJIQ_d_l:JV~--£ __ /;·L'_:.] ___ _ ----------Adrlrr.s~ _V-o (t __ .. S Cl _.t21"<~L_;<?t rl ~ o,p,1F1,,,,,s.,,l!l..,. ---, /1 ,½,<" 'C ~--J.11_~~_/_ State ;vc__. ZIP ~-5:Q.;z_ 2 \'1wr 4?o,.;;r;.I flit lb,(! r ~!:i1.0:11r.r: 3 T~, Aocipies·s ( _,, ~, .-/) -,-~ , _ / /' y 2_ "'ZO 8"'0""\ Name ___ ~~_'.'.'-1 /l1/"<-.t1:::~ __ _1__5:_k_~·!!fJt'/~ Q Phone . / 0 -..:::,(l1-' Corn~rny (iJi"/6.b:L~~g.tf /aL, ' , ~l. t'"•~;, _ _l;,'5,:,_v.1_,fl1"'1,r1___13_~!,_Y __ ~----T•-~lllI~"'' ... , ........ f'"'!f<rlu•""'" -,I" l'/oc-dMulorO.r.o.r10,f_~Zll'""'" -~ ,'• . -::-,"\-. ----------------,--,•<c_~.'-,:x,-,.-. ---~~-~.~ .. ~..,,,..-,J · . ./ t. ·-_ . ,,._. ,,'!. l1JIJe_u,e6 , .. ,,·f~--1!r__:t§..;t3.""-"'-Y __ • ·-10.lio 0200 Ila 1:xpre'.;S Pilr.lc<l!jP. SP.nrir.~ Packages up rCJ 150 lbs. ~ O<i,"'1'<•"""""""""''"'1<1<'"'0'"'"''1' ~dEx Priority Ovf!might O F~dEx Standard Overnighl O FedEx f-irst Ovemi!)ht <1t,us.,,c,;10-.:""" :.,,,.,~.,..,..,,,,.,,,. E,,,rno,"l'"'"'"""-"·'1 ~"""1"'"""1;, .. ..,, □ ~~~\,~,~rd,, 0 fodEx Express Save1· 10,d••'"'""~• "fo~E,.l"""P•A1n1•""'""'""''•tl'• M_ct,,·1,·0n,-00,,U,,·, llh Elcprr.:;s Frni!lht Sen.rir:e Packages oveT 15() lb.~ O.h""''~"'"'a,l>tl,r01_,,..,-_1,ten O ~~~£:~,aJ.;reight• O fodE~ 2Dav Freight St<:1l'ldt,o,..,ud,v •. Q FedEx 3D ay F1eight Th,OW,..,.,.d,;· ·wa~ 5 _ r.u:tcaniuri 0 !'i!dEx Envelope/ Lcttr.r• Q Fe□fa P~k' ·0«1,.,:1.,m_,...5.'l:ll ,Dther?kg. ooo,~ur,ir,ae, F<rhTue,. tr>! <c•-.< ~l~ 6 Spr.r:inl I I r1mllin11 ,--Jecl .. ~crr,IEc,~.irr<sln.~,,.,.,o~ --D SII.TUflDAY Delivery ,._.....,folfod(.h-a:,y o,..,'"'l"'•"ff"''' 10,i ,,,..i.:1z1,,.,,., D SUNDAY Delivery _., ..... , .. ,...,;:_,"-, U\.,,n,"!hllo,,~clZ/Pt:<H!I, . , CoosthiJshipm<•tconlaln dang&rous ~•••" ~-Ooe~o,mo•1tr.,.l,,.,kc~ -----, 0 No O 1~!.,....... 0 ~.,,o,~ s,wppor<t\o<1>r.-,.. .,.,.,,,.,a ~Goocuu,rabe...,...~"fn(,p,ch'1"!1 o~\0/~~i~[~~~~11n D ~t°F~~l:r~~:trm, "10,.,,.,oJ,,""'! t,,,,1,ol,,10,-htt,P.,>r>I\' lffltroiO..,rqt~ O,-. ....... ord/ot<l,:)» l>,o~Clfx,;oa, □ ~~~C:l.ll'JIM~---~ X ----•-111 0 Ciilgo Aircraft Only 7 Pavmrmt Bi/Ito: norc•-~~:~·u ~ f.,~c,frl£•~r.c, r10 n,r,,,1,,r. ... tr••• ~rim·•. ---l~~r:• , .. ,. 0 t~f~!~s"'"'" , Rncipicm QH1bl Par;y O Credit Card O Cash/Check ~ ----.---·-~---~----1~_j 9 _~WH'OIL~ll'~_,.,.~-'l;.--..IJ'a!Ul,~bto~'J<1.&l>'Sl.ll.ll"~hol Total Pack~ges Talal Weiglrt QS__ s .00 0226.6345119□ 11111111 \ \ . ">:~,, 11 "~_;a I '} 1 --1--~--f-10.., li,bicyislm!t1110 s1fuu111 .. ,voo~cta,, 1 too;r,f<"NM.Sn Oot\foro,~:, flr.kaseSi[Jnaltur: ~ ... .-,,,d..,,"'l·..-.-="""'I"•_.,..•• !!y sig""'~ you 1Litho1u• us to~''"'°' n., ,~<pmoOlwn~ol/1 ~t,ta,n,~ll a ,i,;n.wra ,r><1..,.,u11>0,dernr»1y,nollddu11oa,tr10,slrom,"'frc:"""'9''-'""' n ..••• ,. __ ., r.n 1.onn.r..~.r::~.-lr::-· '""" •~~.n~c• Clodo CIOd ~.;;-l36□1 • +
•
•
METHODS SUMMARY
COI280148
PARAMETER
Phenols by GC
Semivolatile Organic Compounds by GC/MS
References:
ANALYTICAL
METHOD
SW846 8041
SW846 8270C
PREPARATION
METHOD
SW846 3520C
SW846 3520C
SW846 "Test Methods for Evaluating Solid Waste, Physical/Chemical
Methods 11 1 Third Edition, November l986 and its updates .
•
•
SAMPLE SUMMARY
COI280l48
~ SAMPLE# CLIENT SAMPLE ID
DL6PC 001 EFF/SV-305
NOTE (S):
• TI1e analytical results of the samples listed above are presemed on the following pages.
-All calculations arc performed before rounding to avoid round-off errors in calculated rt!Sulls.
-Results noted as "ND" wc~c not detected at or above L.'Jc stated Emit.
• This report must not be reproduced, except in full, without the written approval of the laboratory.
-Results for the followini:: par:imctcrs arc never reported on a dry weight basis: color. corrosivity, density, flashpoint, lgnitability, layers, odor.
paint filrcr !CS!. pH, porosity pressure, rc:ictivity, rcdox potential, specific gr:iviry, spec tCS!S, solids. 5olubility, temperature, viscosity, and weight.
DATE TIME
09/27 /00 11, 00
•
•
THERMORETEC CORP
Client Sample ID, EFF/SV-305
GC/MS Semivolatiles
Lot-Sample# ... , COI280148-001 Work Order# ... , DL6PC101
Date Received .. , 09/28/00
Analysis Date .. , 10/03/00
Matrix ......... : WATER
Date Sampled ... , 09/27/00 MS Run# ....... ,
Prep Date ...... , 09/29/00
Prep Batch# ... , 0274131
Dilution Factor: 1 Method ......... , SW846 8270C
REPORTING
PARAMETER RESULT LIMIT UNITS
2,4-Dichlorophenol ND 10 ug/L
Phenol ND 10 ug/L
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Phenol-dS 71 (10 113)
2-Fluorophenol 63 (13 110)
2,4,6-Tribromophenol 66 (21 122)
THERMORETEC CORP • Client Sample ID, EFF/SV-305
GC Semivolatiles
Lat-Sample # ... ' COI280148-001 Work Order # ... ' DL6PC102 Matrix ......... : WATER
Date Sampled ... , 09/27/00 Date Received .. : 09/28/00 MS Run # ••...•. ,
Prep Date ...... : 09/29/00 Analysis Date .. : 10/03/00
Prep Batch # ... ' 0274129
Dilution Factor: 1 Method ......... , SW846 8041
REPORTING
PARAMETER RESULT LIMIT UNITS
Pentachlorophenol ND 2.0 ug/L
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
2,4-Dibromophenol 95 (31 -134)
•
•
•
•
METHOD BLANK REPORT
GC/MS Semivolatiles
Client Lot# ... : C0I280148 Work Order# ... : DLCXDl0l
MB Lot-Sample#: C0I300000-131
Analysis Date .. : 10/03/00
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Phenol
SURROGATE
Phenol-dS
2-Fluorophenol
2,4,6-Tribromophenol
NOTE (S) :
Prep Date ...... : 09/29/00
Prep Batch# ... : 0274131
REPORTING
RESULT LIMIT UNITS
ND 10 ug/L
ND 10 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
67 (10 -113)
57 (13 -110)
62 (21 122)
Calculations arc performed before rounding to avoid round-off errors in c3lculated results .
Matrix ......... : WATER
METHOD
SW846 8270C
SW846 8270C
•
•
Client Lot# ... , C0I280148
MB Lot-Sample#, C0I300000-129
Analysis Date .. , 10/03/00
Dilution Factor: l
PARAMETER
Pencachlorophenol
SURROGATE
2,4-Dibromophenol
NOTE (S) ,
METHOD BLANK REPORT
GC Semivolatiles
Work Order# ... : DLCXllOl
Prep Date ...... , 09/29/00
Prep Batch# ... , 0274129
REPORTING
RESULT LIMIT
ND 2.0
PERCENT RECOVERY
RECOVERY LIMITS
101 (31 -134)
Calculations an: performed before rounding to avoid round-off errors in calculated results .
Matrix .. ' ....... , WATER
UNITS METHOD
ug/L SW846 8041
•
•
LABORATORY CON'l'ROL SAMPLE EVALUATION REPORT
GC/MS Semivolatiles
Client l.ot # ... , C0I280148 Work Order# ... , DLCXD102-LCS
DLCXD103-LCSD
10/03/00
Matrix ......... : WATER
LCS Lat-Sample#, C0I300000-131
Prep Date ...... , 09/29/00 Analysis Date .. ,
Prep Batch # ••• , 0274131
Dilution Factor: 1
PARAMETER
2-Chlorophenol
4-Chloro-3-rnethylphenol
4-Nitrophenol
Pentachlorophenol
Phenol
SURROGATE
Phenol-d5
2-Fluorophenol
2,4,6-Tribromophenol
NOTE(S) c
PERCENT
RECOVERY
64
65
63
65
75
76
81
81
59
60
RECOVERY
LIMITS
(19 -124)
(19 -124)
(29 -124)
(29 -124)
(19 -144)
(19 -144)
(10 -140)
(10 -140)
(10 -131)
(10 -131)
PERCENT
RECOVERY
63
63
53
53
66
66
Calculations are performed before rounding to avoid round-off errors in calculated results.
Bold print denotes control parameters
RPD
RPD LIMITS METHOD
SW846 8270C
1.0 (0-43) SW846 8270C
SW846 8270C
2.5 (0-55) SW846 8270C
SW846 8270C
1.2 (0-34) SW846 8270C
SW846 8270C
0.0 (0-56) SW846 8270C
SW846 8270C
1.1 (0-43) SW846 8270C
RECOVERY
LIMITS
(10 -113)
(10 -113)
(13 -110)
(13 -110)
(21 -122)
(21 -122)
•
•
•
LABORATORY CONTROL SAMPLE EVALUATION REPORT
GC Semivolatiles
Client Lot lt ... c COI280148 Work Order# ... , DLCX1102-LCS
DLCX1103-LCSD
Analysis Date .. , 10/03/00
Matrix ......... : WATER
LCS Lot-Samplelt, COI300000-129
Prep Date ...... , 09/29/00
Prep Batch U ••• , 0274129
Dilution Factor: l
PARAMETER
Pentachlorophenol
SURROGATE
2,4-Dibromophenol
NOTE (S) c
PERCENT
RECOVERY
84
82
RECOVERY
LIMITS
(50 -126)
(50 -126)
PERCENT
RECOVERY
87
85
Calculations arc performed before rounding to avoid round-off errors in calculated reSlllts.
Bold prim denotes control parameters
RPD
RPO LIMITS METHOD
SW846 8041
2.4 (0-20) SW846 8041
RECOVERY
LIMITS
(3l -134)
(31 -134)
Effluent Toxicity Report Form -Chronic Pass/Fail and Acute LCSO Dat:e, 09/29/00
Facility, BEAZER NPDES#, NC Pipe#, Count:y, WAKE
aboratory Performing Test: TRITEST, INC.
Comments:
X --,,c;-;o;t,=;t-;;,,,.----;,;c,.---,,===t'"'o"'r:c-c:-,c:n"R"'e;-;sc;p"°o""n=sc:-1=--;c:----,,,==-,,--------
X-a+,~~5,,~d.;-[c'--;';Cro---/~==;,;-;c-------S Supervisor
V Work Order, 0009-00168
MAIL ORIGINAL TO,
North Caro ina Cer1odaphn1a
Chronic Pass/Fail Reproduction Toxicity Test
CONTROL ORGANISMS l 2 3 4 5 6 7 8 9 10 11
Environmental Sciences Branch
Div. of Environmental Management
N.C. Dept:. of EHNR
4401 Reedy Creek Road
Raleigh, Nort:h Carolina 27607-6445
Chronic Test Results
Calculated t = 4. 917
Tabular t = 2.508
12 % Reduction= 27.21
% Mortalit:y Avg.Reprod.
# Young Produced 21 24 25 27 21 25 23 28 29 22 22 27
0.00 24.50
Control Control
Adult: (L)ive (D) ead L L L L L L L L L L L L
0.00 17.83
Treatment 2 Treatment 2
Effluent: %: 90%
TREATMENT 2 ORGANISMS l 2 3 4 5 6 7 8 9 10 11 12 Control CV
11.346% PASS FAIL
# Young Produced 16 13 22 19 23 21 16 17 17 20 10 20 % control orgs □~ producing 3rd
brood Check One
dull: (L)ive (D) ead L L L L L L L L L L L L 100%
1st sample 1st sample 2nd sample Complet:e This For Either Test
pH ~ [83H] [ffi8j Test Start Date: 09/06/00 Control Collection (Start) Date
Sample 1, 09/04/00 Sample 2, 09/07/00
Treatment 2 Sample Type/Duration 2nd 7 9 8
1st: P/F
s s s Grab Comp. Duration D
I: e I: e I: e I s s
a n a n a n Sample l X 24 hrs L A A
r d r d r d u M M
t t I: Sample 2 X 24 hrs T p p
1st sample 1st: sample 2nd sample
D.O. ffiili ~ ~ Hardness(mg/1) 47 .......... .......... .......... .......... Control
Spec. Cond. (µmhos) 165 850 825
Treatment 2 0 0 0
Chlorine(mg/1) .......... <0.1 <0.1 ..........
LC50/Acute Toxicity Test Sample temp. at receipt: ( °C) .......... 1.8 1.0 .......... ..........
(Mort:alit:y expressed as %, combining replicates) I
% % % % % % % %
% % % % % % % % I I I I I I I I I
Organism Tested: Ceriodaphnia dubia
%1
%
% Concentration
% Mortalit
Duration(hrs):
y
start/end
pH
I
Copied from DEM form AT-1 (3/87) rev. 11/95 (DUBIA ver. 4.32)
Note: Please
Complete This
Section Also
start/end
D.O.
•
•
TRITEST, INC.
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•
•
•
•
August 31, 2000
Ms. Beverly Hudson
Remedial Project Manager
U.S. EPA -Region IV, I Ith Floor
North Site Management Branch
61 Forsyth Street, SW
Atlanta, GA 30303
RE: Revision to Monthly Progress Report #87
Remedial Action
Koppers Site -Morrisville, NC
Dear Ms. Hudson:
ThermoRetec Corporation
300 Baker Avenue, Suite 302
Concord, MA 01742
• Tlhermo!Retec
Smart Solutions. Positive Outcomes.
[phone] Phone
[phone] fax
www.thermoretec.com
RECEIVED
SEP 05 2000
SUPERFUND SECTION·
Enclosed please find four copies of the Effluent Toxicity Reporting Form for the Chronic
Toxicity Test performed on the July IO thrbugh I 3, 2000 Chronic Toxicity samples. This data
was received after our August 7, 2000 subihittal of Progress Report #87. The passing results of
I this test are the first pass after our June failure. Therefore, we will collect another Chronic
Toxicity sample in August to assure that wJ are meeting our effluent requirements, In addition,
we have contacted the analytical laboratori and requested that they submit their-reports to us
prior to the I 0th of each month .
Because this data was not recorded in Report #87, we are including four corrected copies of the
Groundwater Treatment Operations and Sa)npling Program Summary table (Table I) and the
Groundwater Treatment Analytical Data Summary table (Table 2).
Should you need additional information regLding this revised progress report, please call Mike
I Sien ska at ( 412) 208-8867 or me at (978) 3 7 -1422
Sincerely,
Ge)n.sultin, Corporation
Rita Bauer
Project Geologist
RB:cg
Enclosure
cc: D. Mattison -NC Superfund (2 copies
D. Hails -Ecological Restoration, Inc.
.I. Garrett -NC Division of Water Qua ity
P. Kilchenstein -ThermoRetec
M. Matthews -NC Division of Water Qua!.
F: \ I iroj cc ts\03 62 4 \ R c po rts\Mon t l y\Rcv 7 M .QQ
M. Slenska -Beazer
L. Faulconer -Wake County
G. Caskey -Enwood Struc.
M. Helbling -Beazer
a Thermo Electron company
•
•
•
REVISED MONTHLY PROGRESS REPORT #87
REMEDIAL ACTION
SITE NAME: Koppers Superfund Site
Beazer East, Inc.
Morrisville, NC
USEPA DOCKET NUMBERS: 93-09-C
PERIOD ENDING: July 31, 2000
1. PROGRESS MADE THIS MONTH
2.
3.
4.
5.
6.
7.
Remedial Action (RA) -HABITAT MITIGATION. No activities were conducted
this month.
Remedial Action (RA) -GROUNDWATER TREATMENT. The treatment system
operated throughout the month without upset. System performance was
monitored on a biweekly basis. Approximately 43,665 gallons of groundwater
were extracted, treated in the treatment plant and discharged between June 26
and June 27, 2000. System water samples were collected on July 6, 2000, July
11, 2000 (Chronic Toxicity), and July 17, 2000 in accordance with the sampling
schedule in the O&M manual. Samples were submitted to Tritest, Inc. and
Severn Trent Laboratory for laboratory analysis. The operations and sampling
programs are summarized on the attached Table 1.
Remedial Action (RA) -EFFECTIVENESS MONITORING PROGRAM. No
activities were conducted this month.
Remedial Action (RA) -CORRESPONDENCE. None.
PROBLEMS RESOLVED
PROBLEMS ANTICIPATED
UPCOMING EVENTS
PERSONNEL CHANGES
SUBCONTRACTORS
None.
None.
Continue System O&M.
None.
None.
ANALYTICAL DATA Analytical data from system influent and effluent
sampling received during this period are enclosed and are summarized on Table
2 .
•
Date Systems Check Cummulative SV-101 SV-101
(yes/no) Effluent Flow Sample Sample
(Gallons) (yes/no) Parameters
01/04/00 VOS 2,178,450 no
01/20/00 vcs 2,201.060 no
02/02/00 yes 2,223.670 no
02/18/00 yes 2,243.495 no
03/03100 yes 2,278,733 no
03/13/00 yes 2,313,971 no
04/12/00 VOS 2,382,031 00
04/24/00 "' 2,450,091 no
05/05/00 VOS 2,472,228 00
05/15/00 ,es 2,490,675 no
05/31/00 '" 2,520,191 no
06/14/00 V<S 2.540,286 no
06/26/00 ,es 2,560,381 no
07/06/00 VOS 2,575,437 no
07/11/00 ves 2,582,715 no
Tahle 1
Groundwater Treatment Operations and Sampling Program Summary
Koppers Superfond Site
J\.forrisYillc, North Carolina
July 2000
Associated SV-304 SV-304 Associated SV-305
Group Sample Sample Group Sample
(yes/no) Parameters (yes/no)
"° 'CS
"° VOS
no "' ves 2,4-Dichloro, Phenol 1 VOS
no ves
no V'5
no ses
no ves
no yes
no \'CS
00 '"s
no ves
no ves
no •cs
no ves
•
SV-305 Associated
Sample Group
Parameters
Pema, 2,4-Dichloro, Phenol, chronic toxicity 1,3
Penta, 2,4-Dichloro, Phenol 1
Penta, 2,4-Dichloro, Phenol, chronic toxicity 1,3
Penta, 2,4-Dichloro, Phenol, dioxin 1,2
Penta, 2,4-Dichloro, Phenol 1
Penta, 2,4-Dichloro, Phenol 1
Penta, 2,4 Dichloro, Phenol, chronic toxicity 1,3
Penta, 2,4-Dichloro, Phenol 1
chronic toxicit" 4
Penta, 2,4 Dichloro, Phenol 1
Penta, 2,4-Dichloro, Phenol 1
Penta, 2,4-Dichloro, Phenol , dioxin, chronic toxicitv I, 2, 3
Penta, 2,4-Dichloro, Phenol 1
Penta, 2,4 Dichloro, Phenol 1
chronic toxicitv 3
07/17/00 "' 2,604,046 ,es 2,4 Dichiaro, Phenol 1 V'5 2,4-Dichloro. Phenol 1 V'5 Penta, 2,4-Dichloro, Phenol, dioxin 1, 2
Notes:
Sampling point SV-101 is located before the Carbon Units (pretreatment)
Sampling point SV-304 is located between the Carbon Units
Sampling point SV-305 is loctatcd after the Carbons Units (post-treatment)
Associated Groups:
SV-101 -Group l is penta and 2,4-dichlorophenol; Group 2 is dioxin
SV-304 -Group l is penta and 2,4-dichlorophenol
SV-305 -Group I is pent.a, phenol, and 2,4--dichlorophenol; Group 2 is dioxin and Group 3 is chronic toxicity
•
•
•
Table 2
Groundwater Treatment
ANALYTICAL DATA SUMMARY
Koppers Superfund Site
Morrisville, North Carolina
July 2000
Analytical
Par:imctcr Date Sample
Sample Location
Collected SV-101
Pcntachlorophenol 01/04/00
01/20/00
02/02/00
02/18/00
03/03/00
03/13/00
04/12/00
04/24/00
05115/00
05/31/00
06/14/00
06/26/00
07/06/00
07/17/00
2 .4-Dichlorophenol 01/04/00
01/20/00
02/02/00
02/18/00
03/03/00
03/13/00
04/12/00
04/24/00
05/15/00
05/31/00
06/14/00
06/26/00
07/06/00
07/17/00 <10
Phenol 01/04/00
01/20/00
02/02/00
02/18/00
03/03/00
03/13/00
04/12/00
04/24/00
05/15/00
05/31/00
06/14/00
06/26/00
07/06/00
07/17/00 <10
Chronic Toxicity 01/04/00
02/01/00
04/12/00
05/05/00
06/14/00
07/11/00
Dioxin (2,3,7,8-TCDD) 02/18/00
06/15100
07/17/00
Notes: All results are in ug/L except dioxin. Dioxin data is in picogr:ims/L.
SV-101 -Before Carbon Units
*SV-304 -Between C,ubon Units
**SV-305 -After Carbon Units
Sample Sample
Location Location
SV-304* SV-305°
<2
<2
<2
<2 <2
<2
<2
<2.
<2
<2
<2
<2
<2
<2
<2
< 10
<10
< 10
<10 < IO
< IO
< IO
< IO
< 10
<IO
< IO
<10
<10
<10
< 10 < 10
<10
< 10
< 10
< 10 < 10
< 10
<IO
<10
< 10
< IO
<10
<IO
<10
<IO
< 10 <10
Pass
Pass
Fail
Pass
Fail
Pass
< 1.2
<3.94
<0.863
Effluent Toxicity Report Form -Chronic Pass/Fail and Acute LCS0 Date: 07 /24/00
Facility: BEAZER NPDES#: NC Pipe#: County: WAKE
~aboratory Performing Test: TRITEST, INC.
Comments:
* PASSED: 13.13% Reduction*
Work Or er: 0007-00673
MAIL ORIGINAL TO:
Environmental Sciences Branch
Div. of Environmental Management
N.C. Dept. of EHNR
North Carolina Ceriodaphnia
Chronic Pass/Fail Reproduction
CONTROL ORGANISMS
# Young Produced
Adult (L) ive (DI ead
Effluent % : 90%
TREATMENT 2 ORGANISMS
# Young Produced
Adult (LI ive (D)ead
pH
Control
Treatment 2
D.O.
Control
Treatment 2
1st sample
~ ~
s
t e
a n
r d
t
1st sample
~ 8
1 2 3 4
30 28 30 26
L L L L
1 2 3 4
23 22 29 25
L L L L
1st sample
~ ~
s
t e
a n
r d
t
1st sample
~ 6
LC50/Acute Toxicity Test
4401 Reedy Creek Road
Raleigh, North Carolina 27607-6445
Toxicity Test Chronic Test Results
5 6 7 8
30 25 28 23
L L L L
5 6 7 8
24 24 24 21
L L L L
2nd sample
~ ~
s
t e
a n
r d
t
2nd sample
t8B3
Calculated t = 2.381
Tabular t = 2.508
9 10 11 12 % Reduction= 13 .13
% Mortality Avg.Reprod.
34 22 33 26
0.00 27.92
Control Control
L L L L
0.00 24.25
Treatment 2 Treatment 2
9 10 11 12 Control CV
13. 268% PASS FAIL
27 16 31 25 % control orgs ~c
L
producing 3rd
brood Check One
L L L 100%
Complete This For Either Test
Test Start Date: 07/12/00
Collection (Start) Date
Sample 1: 07/10/00 Sample 2: 07/13/00
Sample Type/Duration
Grab Comp. Duration
Sample 1
>----,---.J.-------<
X 24 hrs
Sample 2 X 24 hrs
D
I
L u
T
1st
s
A
M p
2nd
P/F
s
A
M p
49 Hardness (mg/1)
>---+----l------,
Spec. Cond. (µmhos)
'---+-----l------,
180 850 930
Chlorine (mg/1)
1----+-----1----
<0.1 <0.1
S ample temp. at receipt(°C) 4.0 2.5
(Mortality expressed as%, combining replicates)
Organism Tested: Ceriodaphnia dubia
Concentration
Mortality
start/end
pH
Duration(hrs):
Copied from DEM form AT-1 (3/87) rev. 11/95 (DUBIA ver. 4.32)
Note: Please
Complete This
Section Also
start/end
D.O.
'
.,
,.
"
• ·,
0010 EnJcJ :
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• I
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• TRITEST, INC.
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Ph,""' I Cj 7 5J l J]/ -/ '( ;;:L :2__
c\,nuct: /.2 t,A (Z,4 ua;L---
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: Ill :so
For LJbVr.Ih>': L'si: Onl~
•
TRITEST, INC.
3909 Beryl Road
Raleigh, NC 27607
Telephone: [phone]
Fax: [phone]
NC/WW Cert.#: 067
L a b o r a t o r y R e p o r t
Prepared for
LAURA KELMAR
THERMORETEC CONSULTING CORP.
9 POND LANE
SUITE 3A
CONCORD, MA 01742
Project ID: 01
Project Info: BIOASSAY / BEAZER-RALEIGH
Page 1 of 1
Report Date:
Date Received:
7/27/00
7/11/00
Work Order#: 0007-00673
Cust. Code: RE1422
Cust. P.O.#:
No. Sample ID Date Sampled
7/11/2000
Time Sampled
9:00
Matrix
WW
Condition
See coc 001 SYSTEM EFFLUENT
Test Performed Method Results Tech Analyzed Qual
Bioassay, Chronic Pass/Fail NC Pass/Fail done CAM 7 /11/00
• Report certified by:
for Tritest, Inc.
GA
· ,-NCDENR •·
• JAMES B. HUNT JR.,;
GOVERNOR ~< :,
--,. \
BILL HOLMAN
• SECRETARY
NORTH CAROLINA DEPARTMENT OF
ENVIRONMENT AND NATURAL RESOURCES
DIVISION OF WASTE MANAGEMENT
July 27, 2000
Ms. Beverly Hudson
Remedial Project Manager
Superfund Branch
Waste Management Division
United States Environmental Protection Agency
Region IV
61 Forsyth Street, I I th Floor
Atlanta, GA 30303
Re: Monthly Progress Report #86 (June)
Koppers Company NPL Site
Morrisville, Wake County
Dear Ms. Hudson:
The Superfund Section of the North Carolina Department of Environment and
Natural Resources (NC DENR) has received Monthly Progress Report #86 (June)
for the Koppers Company National Priorities List (NPL) Site. The Superfund
Section has reviewed this document and offers the following comments.
Monthly Progress Report #86 -June 2000
I. Monthly Progress Report #84 (April 2000) was not received by the NC
DENR Superfund Section. Please correct this oversight. Additionally,
please provide responses to the regulatory comments issued July 1999
through June 2000.
2. Table 2 indicates that in April 2000, the facility failed its toxicity test. The
May 2000 toxicity test had complete survival with treatment organism
reproduction essentially the same as the control organisms. Table 2
indicates that the groundwater treatment system effluent passed the
chronic toxicity test. In the body of the report there was no explanation or
response to the toxicity described. Please detail any activiiies that were
undertaken to correct the effluent quality. Please detail whether provisions
stipulated in the Toxicity Reduction Evaluation Work Plan were
implemented.
ii11SU ••·••·• 1646 MAIL SERVICE CENTER, RALEIGH, NORTH CAROLINA 27699·1646
401 OBERLIN ROAO, SUITE 150, RALEIGH, NC 2760S
F'HONE 919-733-4996 FAX 919-715·3605 AN EQUAL OPPORTUNITY/ AFFIRMATIVE ACTION EMPLOYER -50% RECYCLED/IC% POST-CONSUMER PAPER
•
•
Ms. Beverly Hudson
July 27, 2000
Page 2
3. The Case Narrative included in the laboratory documentation for the June 14, 2000
groundwater treatment system samples submitted to Severn Trent Services indicates that the water sample was received at proper temperature. However, the Cooler Receipt Form indicates that the water sample was received at 5° Celsius. This exceeds the Contract
Laboratory Program (CLP) protocol that water samples for 2,4-dichlorophenol, phenol
and dioxin analyses be stored at no greater than 4° Celsius. Beazer East, Inc. (Beazer)
should note in the table that these samples were improperly preserved. Furthermore,
Beazer should detail and implement procedures to prevent the future occurrence of
improper sample handling, including notification by the laboratory and provisions for resampling.
4. The Cooler Receipt Form was inadvertently omitted from the laboratory documentation
for the groundwater treatment system samples collected on June 26, 2000. Please correct
this oversight.
We appreciate the opportunity to comment on this document. If you have any questions, please feel free to call me at [phone], extension 349.
Sincerely,
David B. Mattison, CHMM
Environmental Engineer
Superfund Section
cc: Judy Garrett, NC Div. of Water Quality
Matt Matthews, NC Div. of Water Quality
Mike Slenska, Beazer East, Inc .
•
•
July 11, 2000
Ms. Beverly Hudson
Remedial Project Manager
U.S. EPA -_Region IV, 11th Floor
North Site Management Branch
6 I Forsyth Street, SW
Atlanta, GA 30303
RE: Revisions to Monthly Progress Report #86
Remedial Action
Koppers Site -Morrisville, NC
Dear Ms. Hudson:
ThermoRetec Corporation
300 Baker Avenue, Suite 302
Concord, MA 01742
.lhermoRetec
Smart Solutions. Positive Outcomes.
[phone] Phone
(978) 371-144¾x www.thermoretMECE/VEo
JUL 172000
Sun.,'' ..,,,J SECTION
Enclosed please find a copy of the Effluent Toxicity Reporting Form for the Chronic Toxicity
Test performed on the June 13 through 15, 2000 Chronic Toxicity samples. This data was
inadvertently ommitted from our June 7, 2000 submittal of Progress Report #86. Because of
this ommission, we are herein submitting four ( 4) revised copies of Monthly Progress Report
#86, Table 1, and Table 2.
Please note that the June Chronic Toxicity test was a failure. Therefore, we will co_ntinue to
collect Chronic Toxicity samples on a monthly basis to assure that we are meeting our
effluent requirements.
Should you need additional information regarding this revised progress report, please call
Mike Slenska at [phone] or me at [phone]
Sincerely,
~~fL'"°'
Project Geologist
RB:cg
Enclosure
cc: o: M,tttison -NC Superfund (2 cop\es)
D. Hails -Ecological Restoration, Inc.
J. Garrett -NC Division of Water Quality
P. Kilchenstein -ThermoRetec
F:\Projccts\03624\Rcports\Mont!1ly\H uds07 I I
M. Slenska -Beazer
L. Faulconer -Wake County
G. Caskey -Enwood Struc.
M. Helbling -Beazer
a Thermo Electron company
•
•
•
REVISED MONTHLY PROGRESS REPORT #86
REMEDIAL ACTION
SITE NAME: Koppers Superfund Site
Beazer East, Inc.
Morrisville, NC
USEPA DOCKET NUMBERS: 93-09-C
PERIOD ENDING: June 30, 2000
1. PROGRESS MADE THIS MONTH
2.
3.
4.
5.
6.
Remedial Action (RA) -HABITAT MIT/GA T/ON. No activities were conducted
this month.
Remedial Action (RA) -GROUNDWATER TREATMENT. The treatment system
operated throughout the month without upset. System performance was
monitored on a biweekly basis. Approximately 40,190 gallons of groundwater
were extracted, treated in the treatment plant and discharged between May 30
and June 27, 2000. System water samples were collected on June 13, 2000
(Chronic Toxicity), June 14, 2000, and June 26, 2000 in accordance with the
sampling schedule in the O&M manual. Samples were submitted to Tritest, Inc.
and Severn Trent Laboratory for laboratory analysis. The operations and
sampling programs are summarized on the attached Table 1.
Remedial Action (RA) -EFFECTIVENESS MONITOR/NG PROGRAM. No
activities were conducted this month.
Remedial Action (RA) -CORRESPONDENCE. None.
PROBLEMS RESOLVED
PROBLEMS ANTICIPATED
UPCOMING EVENTS
PERSONNEL CHANGES
SUBCONTRACTORS
None.
None.
Continue System O&M.
None.
None.
7. ANALYTICAL DATA Analytical data from system influent and effluent
sampling received during this period are enclosed and are summarized on Table
2 .
F:\Projects\03624\Reports\l'vlontlily\H lllls071 I
•
Dale Systems Check Cummula1ive
(yes/no) Effluent Flow
(Gallons)
01/04/00 yes 2,178,450
01/20/0() yes 2,201,060
02/02/00 yes 2,223,670
02/18/00 yes 2,243,495
03/03/00 yes 2,278,733
03/13/00 yes 2,313,971
04/12/00 yes 2,382,031
04/24/00 yes 2,450,091
05/05/00 yes 2,472,228
05/15/00 yes 2,490,675
05/31/00 yes 2,520,191
06/14/00 yes 2,540,286
06/26/00 yes 2,560,381
Nmes:
SV-101 -Before Carbon Units (prelreatment)
*SV-304 -Between Carbon Units
**SV-305 -After Carbons Uni,s (pos1-treatment)
SV-101
Sample
(yes/no)
no
no
no
no
no
no
no
no
no
no
no
nn
no
•
Revised Table 1
Groundwater Treatment Operations and Sampling Program Summary
Koppers Superfund Site
SV-l01
Sample
Parameters
Morrisville, North Carolina
June 2000
Associated SV-304* SV-304 Associated SV-305**
Group Sample Sample Group Sample
(yes/no) Parameters (yes/no)
no yes
no yes
nn yes
yes 2,4-Dichloro, Phenol 3 yes
no yes
no yes
no yes
no yes
no yes
no yes
no yes
no yes
nn yes
Associa1ed Groups:
SV-101 -Group I is penta and 2,4--dichlorophenol; Group 2 is dioxins
SV-304 -Group 3 is penta and 2,4--dichlorophenol
SV-305
Sample
Parameters
Penta, 2,4-Dichloro, Phenol, cox
Penta, 2.4-Dichloro, Phenol
Penta, 2,4-Dichloro, Phenol, cox
Penta, 2,4-Dichloro, Phenol, dioxin
Penta, 2,4-Dichloro, Phenol
Penta, 2,4-Dichloro, Phenol
Penta, 2,4-Dichloro, Phenol, cox
Pema, 2.4-Dichloro, Phenol
Tox
Penta, 2,4-Dichloro, Phenol
Penta, 2,4-Dichloro, Phenol
Penta, 2,4-Dich\oro, Phenol , dioxin, rnx
Penta, 2,4-Dichloro, Phenol
SV-305 -Group I is penta and 2,4-dichlorophenol; Group 2 is dioxins and Group 4 is toxicity
Associated
Group
1,4
I
1.4
1.2
I
I
1,4
I
4
I
I
I, 2, 4
I
•
•
Table 2
Groundwater Treatment
REVISED ANALYTICAL DATA SUMMARY
Koppers Superfund Site
Morrisville, North Carolina
June 2000
Analytical
Parameter Date Sample Sample
Sample Location Location
Collected SY-IOI SV-304*
Pemachloror,henol 01104/00
01/20/00
02/02/00
02/18/00 <2
03/03/00
03/13/00
04/12/00
04/24/00
05/15/00
05/31/00
06/14/00
06/26/00
2.4-Dichloroohenol 01/04/00
01/20/00
02/02/00
02/18/00 < 10
03/03/00
03/13/00
04/12/00
04/24/00
05/15/00
05/31/00
06/14/00
06/26100
Phenol 01/04100
01120100
02102100
02/18100 <10
03103100
03/13100
04112100
04124/00
05/15100
05131100
06114100
06126100
Chronic Toxicity 01104/00
02101100
04112100
05105100
06/15100
Dioxin (2,3,7 ,8-TCDD) 02118100
06/15100
Notc.s: All results are in ug/L except dioxin, Dioxin data is in picograms/L.
SY-101 -Before Carbon Units
*SV-304 -Bt!tween Carbon Units
**SY-305 -After Carbon Units
Sample
Location
SV-305"'*
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
< 10
< 10
< 10
<10
<IO
< 10
< 10
< 10
< 10
< 10
< 10
< 10
<IO
<IO
< 10
< 10
<10
< 10
< 10
< 10
< 10
< 10
< 10
< 10
Pass
Pass
Fail
Pass
Fail
< 1.2
<3.94
Effluent Toxicity Report Form -Chronic Pass/Fail and Acute LCSO Date: 06/22/00
Facility: BEAZER NPDES#: NC
Laboratory Performing Test: TRITEST, INC.
Work Ord r: 0006-00572
MAIL ORIGINAL TO:
Nort Caro ina Cerio aphnia
Chronic Pass/Fail Reproduction Toxicity Test
h 1· d
CONTROL ORGANISMS 1 2 3 4 5 6 7 8 9 10 11
Pipe#: County: WAKE
Comments:
Environmental Sciences Branch
Div. of Environmental Management
N.C. Dept. of EHNR
4401 Reedy Creek Road
Raleigh, North Carolina 27607-6445
Chronic Test Results
Calculated t = 4.182
Tabular t = 2.508
12 % Reduction= 28.13
% Mortality Avg.Reprod.
# Young Produced 21 29 33 32 34 15 33 33 29 36 29 28
0.00 29.33
Control Control
l;\dult (L) ive (D) ead L L L L L L L L L L L L
0.00 21.08
Treatment 2 Treatment 2
Effluent %: 90%
TREATMENT 2 ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 12 Control CV
20.316l PASS FAIL . ~ ~ # Young Produced 25 17 20 24 22 15 22 20 22 27 20 19 % control orgs
producing 3rd
brood Check One
Adult (L) ive (DI ead L L L L L L L L L L L L , 100%
1st sample 1st sample 2nd sample Complete This For Either Test
pH ~ tffiE ~ Test Start Date: 06/14/00
Control Collection (Start) Date
Sample 1: 06/13/00 Sample 2: 06/15/00
Treatment 2 Sample Type/Duration 7 8 8
1st
s s s Grab Comp. Duration D
t e t e t e I s
a n a n a n Sample 1 X 24 hrs L A
r d r d r d u M
C t t Sample 2 X 24 hrs T p
1st sample 1st .sample 2nd sample
D.O. ~ [BIB [BIB Hardness (mg /1) 48 ·········· Control
Spec. Cond. (/lmhos) 180 900
Treatment 2 8 6 5
Chlorine (mg/1) .......... <0.1
LC50/Acute Toxicity Test Sample temp. at receipt ( 0 c) .. ........ 0.9
(Mortality expressed as%, combining replicates)
I :1 :1 :1 :1 :1 :1 :1 :1 :1 :1
Concentration
Mortality
start/end
Note: Please
Complete This
Section Also
start/end
pH D.O.
Organism Tested: Ceriodaphnia dubia Duration (hrs) :
Copied from DEM form AT-1 (3/87) rev. 11/95 (DUBIA ver. 4.32)
2nd
P/F
s
A
M p
..........
900
<0.1
0.9
•
TRITEST, INC.
!\111:1:-.~.1~ l.'h.nn 11(\..·u~i1'~~ F1•r:::
C .,;-/, 1 .r £' / .,..:-,/1 · ,-:-,,. Ll _..;.__: ~ --r , a.-,· , , ~ 1-•. ~--• ! C . ,
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:-S.111:rk 1..·,,1L.:..:tcir: Print c-J£~ ~V'~
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>.111,rk r·;r,:: Compo~ile:
il:11,· ,,.,n,J : ____ 6_' µ/4~::1,_,/~o=O~------
ll:11, """'d . ---~6~V~~~~6~~~0~-----
Tim<:
Time:
-.;Jmrl,;_~ ,icr f luur: ____ /_· _______ _ ii H1..1urs ;
r.u. ';;
C>f/10
oSro_
2 'f_
~or P.\I
@)or r,1
Tim<: ______ A.\1 or P'.\1
0 ♦ I O O I O O O O O O O O O O O O t O O O O O O I
TRITEST, INC.
Pth•nc :i I 9 7 5: ) ] ] / -/ i _2 .2_
C,-/S---0c1 Timi:: Qx'fJS A" or P.\I
• &-!(, -c 0 Ca'.:.i) /
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Oat,.:
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• ______________ \umb~r vf Bvuks
•
•
•
I ,,
July 7, 2000
Ms. Beverly Hudson
Remedial Project Manager
U.S. EPA-Region IV, I Ith Floor
North Site Management Branch
61 Forsyth Street, SvV
Atlanta, GA 30303
RE: Monthly Progress Report #86
Remedial Action
Koppers Site -Morrisville, NC
Dear Ms. Hudson:
ThermoRetec Corporation
300 Baker Avenue, Suite 302
Concord, MA 01742
.ThermolRetec
Smart Solutions. Positive Outcomes.
[phone] Phone
(978) 371-141,8 Fax
www.thermoretec.com
RFCEIVEO
JUL 14200Q
SUPERFUND SECTION
In accordance with the Unilateral Order, and on behalf of Beazer East, Inc. (Beazer),
please find attached four ( 4) copies of the June Monthly Progress Report for Remedial
Action at the Koppers Superfund Site in Morrisville, NC.
Should you need additional information regarding this progress report, please call Mike
Slenska at [phone] or me at [phone]
Sincerely,
ThermoRetec Consulting Corporation
~~r~
Rita Bauer
Project Geologist
RB:cg
Enclosure
cc: D. Mattison -NC Superfund (2 copies)
D. Hails -Ecological Restoration, Inc.
J. Garrett -NC Division of Water Quality
P. !Glchenstein -ThermoR.etec
F: \PROJ ECTS\036N\Rcports\Monthly\6m-00. wpd
M. Slenska -Beazer
L. Faulconer -Wake County
G. Caskey -Enwood Structures
M. Helbling -Beazer
a Thermo Electron company
•
•
MONTHLY PROGRESS REPORT #86
REMEDIAL ACTION
SITE NAME: Koppers Superfund Site
Beazer East, Inc.
Morrisville, NC
USEPA DOCKET NUMBERS: 93-09-C
PERIOD ENDING: June 30, 2000
1. PROGRESS MADE THIS MONTH
2.
3.
4.
5.
6.
Remedial Action (RA) -HABITAT MITIGATION. No activities were conducted this
month.
Remedial Action (RA) -GROUNDWATER TREATMENT. The treatment system
operated throughout the month without upset. System performance was monitored
on a biweekly basis. Approximately 40,190 gallons of groundwater were extracted,
treated in the treatment plant and discharged between May 30 and June 27, 2000.
System water samples were collected on June 14, 2000 and June 26, 2000 in
accordance with the sampling schedule in the O&M manual. Samples were
submitted to Severn Trent and Alta Analytical for laboratory analysis. The
operations and sampling programs are summarized on the attached Table 1 .
Remedial Action (RA) -EFFECTIVENESS MONITORING PROGRAM. No activities
were conducted this month.
Remedial Action (RA) -CORRESPONDENCE. None.
PROBLEMS RESOLVED
PROBLEMS ANTICIPATED
UPCOMING EVENTS
PERSONNEL CHANGES
SUBCONTRACTORS
None.
None.
Continue System O&M.
None.
None.
7. ANALYTICAL DATA Analytical data from system influent and effluent sampling
received during this period are enclosed and are summarized on Table 2 .
F: \PROJECTS\03624 \Repons\Montl1ly\6n1-00. wpd
r •
Date Systems Check Cununulative
(yes/no) Effluent Flow
(Gallons)
01/04/00 ves 2_178,450
01/10/00 ves 2.201,060
02/02/00 ves 2,223,670
02/18/00 yes 0,243,495
03/03/00 yes 2,278,733
03/13/00 yes 2,313,971
04/12/00 ves 2,382,031
()4/?4/00 ves 2.450.091
05/05/00 yes 2,472,228
05/15/00 ves 2.490,675
05/31/00 ves 2.520,191
06/14/00 yes 2,540.286
061'6/00 ves 2,560,381
Notes:
SY-101 -Before Carbon Units (pre1reacment)
*SV-304 -Between Carbon Units
SV-101
Sample
(ves/no)
no
no
00
no
no
no
no
no
no
no
00
00
no
**SV-305 -After Carbons U~its (posHreatmenc)
•
Tahle I
Groundwater Treatment Operations and Sampling Program Summary
Koppers Superfund Site
Morrisville, North Carolina
June 2000
SV-101 Associated SV-304* SV-304 Associated
Sample Group Sample Sample Group
Parameters (ves/no) Parameters
no
no
no
yes 2,4-Dichloro, Phenol 3
no
no
no
00
no
no
no
no
00
Associated Groups:
SV-305**
Sample
(ves/no)
ves
yes
ves
ves
ves
yes
ves
Yes
ves
ves
ves
ves
ves
SV-101 -Group l is pema and 2,4-dichlorophenol; Group 2 is dioxins
SV-304 -Group 3 is penta and 2,4-dichlorophenol
SV-305
Sample
Parameters
Penta. 2,4-Dichloro. Phenol. tox
Pema, 2,4-Dichloro, Phenol
Penta, 2.4-Dichloro. Phenol. mx
Penta,? ,4-Dichloro, Phenol, dioxin
Penta. 2.4-Dichloro, Phenol
Penta. ? ,4-Dichloro, Phenol
Penta, 2,4-Dich\oro, Phenol, tox
Penta, 2.4-Dichloro, Phenol
Tox
Penta. 2.4-Dichloro, Phenol
Penta. 2,4-Dichloro, Phenol
Penta, 2.4-Dichloro, Phenol , dioxin
Penta. 2,4-Dichloro, Phenol
SV-305 -Group l is penta and 2,4-dichlorophenol; Group 2 is dioxins and Group 4 is toxicity
e
Associated
Group
1,4
1
1.4
1.?
1
1
1.4
1
4
1
1
I. 2
1
•
•
•
Parameter
Pentachlorophenol
2 .4-Dichloroc henol
Phenol
Chronic Toxicity
Table 2
Groundwater Treatment
ANALYTICAL DATA SUMMARY
Koppers Superfund Site
Morrisville, North Carolina
June 2000
Analytical
Date Sample Sample
Sample Location Location
Collected SV-101 SV-304*
01/04/00
01/20/00
02/02/00
02/18/00 <2
03103/00
03/13/00
04/12/00
04/24/00
05/15/00
05/31/00
06/14/00
06/26/00
01/04/00
01/20/00
02/02/00
02/18/00 < 10
03/03/00
03/13/00
04/12/00
04/24/00
05/15/00
05/31100
06/14/00
06/26100
0 I 104/00
01/20/00
02/02/00
02/18/00 < 10
03/03100
03/13/00
04/12/00
04/24/00
05/15/00
05/31/00
06/14/00
06/26/00
01/04/00
02/01/00
04/12/00
05/05/00
Dioxin (2,3,7,8-TCDD) 02/18/00
06/15/00
Notes: All results are in ug/L except dio.xin, Dioxin data is in picograms/L.
SV-101 -Before Carbon Units
*SV-304 -Between Carbon Units
"'*SV-305 -After Carbon Units
Sample
Location
SV-305"'*
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
< 10
< 10
< 10
< 10
< 10
< 10
< 10
< 10
< 10
< 10
< 10
< 10
< 10
< 10
< 10
< 10
< 10
< 10
<10
< 10
< 10
< 10
< 10
< 10
Pass
Pass
Fail
Pass
< 1.2
<3.94
•
•
•
ANALYTICAL REPORT
PROJECT NO. RALEIGH
Raleigh-Bi-Weekly NPDES
Lot#: COF150137
Debbi Leuteritz
ThermoRetec
SEVERN TRENT LABORATORIES, INC.
Veronica Bortot
Project Manager
June 22, 2000
STL Pittsburgh
450 Wiltiam Pitt Way
Pittsburgh, PA 15238
Tel [phone]
Fax [phone]
www.stl~inc.com
•
•
Sample Receiving:
CASE NARRATIVE
THERJWORETEC CORPORATION
Raleigh
STL Lot#C0Fl50l37
STL Pittsburgh, PA received one sample on June 15, 2000 in good condition and at the
proper temperature.
GC/!WS Semivolatilcs:
There were no problems associated with the analysis.
GC Phenols:
There were no problems associated with the analysis .
•
•
•
MJ~THODS SUMMARY
COF150137
ANALYTICAL
;:.P.:..:A-=cRAM=:.=Ec:T:.:EccR.:.._ _____________________ .:..:MccE..cTccH..cO..cD ____ _
Phenols by GC
Semivolatile Organic Compounds by GC/MS
References:
SW846 8041
SW846 8270C
PREPARATION
METHOD
SW846 3520C
SW846 3520C
SW846 ''Test Methods for Evaluating Solid Waste, Physical/Chemical
Methods", Third Edition, November 1986 and its updates .
•
•
SAMPLE SUMMARY
CDF150137
WO# SAMPLE# CLIENT SAMPLE ID
DEP9D 001 EFF/SV-305
NOTES
• The annlyticnl re.~ullll of the 11wnplea listed ubove arc presenlcd on the following page.~.
-All cnlculntions nre pcrfonne<l before rounding to nvoid round-off erro111 in culculut<!d re.mil~.
-Results noted WI ~ND" were not detected nt or ubovc the stilted limit.
• TI1is report mw1t not be reproduced, except in fu!l, without the written npprovnl of the lnborntory.
• Re.mils for the following pnrnmcte111 nre never reported on n dry weight bn11i11: color, carrosivity, density, flruihpoint, ignilubi!ity, layers, odor,
p:iint filter te.,t. pH, por011ity pressure, rcm;tivity, redox potential. specilic gravity, 11pot te.1L1, 11nliJs. 11olubi!ity, t.empernture, vi11cosity, an<l weight .
DATE TIME
06/14/00 07:50
Chain o~
Custody Record
QUA •112\
Client
(/~1{Jj?g7bC-
Address
,5-00 8A'' ..,,-:-"" Av£
City 1;;;~ Cal'-'~
Zip Code
01_7 ![7--
Ouanterra, Inc. -Pittslh PA Lab
450 William Pitt Way
Pittsburgh PA 15238
Project Manager
£>rr:4 tUv.G-,£_
Telephone Number (Area Code)!Fax Number
(9.1;,-) 311 /Y-,7
Sit~ Contact
Prnje;;~ ~tli c;;;;;:;,;;;; # 7,;3<,61/37(,
ContracVPurc/Jase Order/Quote No
.
Containers Sample 1.0. No. and Description Date Time Sample Type Total Preservative Volume Type No.
_£Ee .ISv-30.S-L'l/~/40 <f].n:, Qf.,11 y{._' C.' (/ -.
Special Instructions
Possible Hazard Identification Sample Disposal
0 Non-Hazard D Flammable D Skin Irritant 0Poison8 □unknown D Return To Client
Tum Around Time Required QC Level Project Specific (Specify)
0 No,ma/ □ Rush □ /. □ II. □ Ill.
1. Relinqu;st,ed By /4 --4(L~
1
D~"/;~ D Hme'JO'O
2. Relinquished~-6'-1 ec...-=...,e=....=~-------"-o~a=,re Time
3. Relinquished By Date Time 3. Received By
Comnwnts
DISTRIBUTION: WHITE -Stays with Sample; CANARY -Returned to Client with Report PINK -Field Copy
1n, 9 ~uanterra
Dale 6/1._v!~_() Chain Of Custody Number i:·,-ons uJ-'¥
Lab Number ·
Page I of J
Analysis
0 ..,,_,,
fJ :~
i Condition on Receipt ~
r)(' " ,
.
0 Disposal By Lab D Archive For /1.·lonths
Date Time -I (, -1 5-oo I /_Jj_'._3 ()
Date Time -
Date Time
Cooler Receipt Form
STL Pittsburgh
Project: _______ _ Quote: 77 (,, °In
.ooler Rec'd & Opened for Temp. Check on: --'1-'--'c _· -'--/--'5'--··w--'·'---------------------
Coolers Opened and Unpacked on: -'-I·"-'--. -''-"j---''°"',·o'---------------By: .)41v . .,,../_rc../L y'./ · (-/-~(__
(Signature)
Yes No
1. Were custody seals on the outside of the cooler? ______________ _ X
If YES, how many and where? Quantity _l Location F>n·:-t" ~-'-'-"0-C....---------
W ere signatures and date correct? ___________________ _
Were custody papers included inside the cooler? ______________ _ 2.
'K
X
Were custody papers properly filled out (ink, signed, match labels)? _______ _
Did you sign the custody papers in the appropriate place? ___________ _
Was shippers packing slip attached to this form? ______________ _
Were packing materials used? ____________________ _
3.
4.
s.
6.
x
::L
>-
L
If YES, what type? I t.2. b•J2..c:s \--,, .,\:;l:,y .. ,,-o.r:::,, _:; ' . \ • 7.
8.
X
X Were the samples chilled? (Record temperatures on reverse side.) ________ _
Were the samples appropriately preserved? ________________ _
9. Were all bottles sealed in separate plastic bags? ______________ _ L
10.
11.
12.
I " X ;:
T I x
Did all bottles arrive in good condition (unbroken)? _____________ _
Were all bottle labels complete (sample ID, preservatives, etc.)? ________ _
Did all bottle labels and/or tags agree with custody papers? __________ _
13. Were correct bottles used for tests indicated? ---------------)( -------v _ ___,. ··--~-----
( AIRBOR.t~ )
' /
\
14. Were all VOA vials checked for the presence of air bubbles? ----------
15. Was a sufficient amount of sample sent in each bottle? ---------7'---
16. Samples received by: FED EX UPS CUENT DROP-OFF OTHER
'· Explain any discrepancies: _____________________________ _
• Level 2 Review ________________________________ _
Was contacted on ________ by ______________ to resolve discrepancies.
Page l of 2
Cooler Re;ceipt Form
STL Pittsburgh
I
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TMET DMET HG NUT(l) C< ~HC PHEN SULF
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P: Preserved
UP: Unpreserved
hn!m,; •
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• (1) .. NUT could include sample bottles for :i.mmonia., -.;herruc::ll oxygfn de:nand. nnrate,mtme, Tl<..'-', or total pnospnorus
Cooler Number Ternperacure
/0 '::>
•
sn PT/May-00196-0051COOLDOC
Bottle Type Lot Number•
I
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11
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I -
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I Page 2 of 2
I
I
I
I
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11
I
•
•
Lot-Sample# ••. :
Date Sampled ... :
Prep Date ....•. :
THERMORETEC =RP
I
Client samJ1e ID: EFF/SV-305 '
GC/MS ISemivolatiles
I Work Order# ... : DEP9D101
Date Redeived .. : 06/15/00
Analysi<i Date .. : 06/19/00
Matrix •........ : WATER
MS Run# ....... :
Prep Batch# ... :
COF150137-001
06/14/00
06/16/00
0168262
Qilution Factor: 1 Method . .I. ...... : SW846 8270C
PARAMETER
2,4-Dichlorophenol
Phenol
SURROGATE
Phenol-dS
2-Fluorobiphenyl
Nitrobenzene-d5
Terphenyl-dl4
2-Fluorophenol
2,4,6-Tribromophenol
I
RESULT I
ND
ND
PERCENT
RECOVERY I
:: I
64 I
91
I 53
67
REPORTING
LIMIT
10
10
RECOVERY
LIMITS
(10 -113)
(30 -110)
(32 -112)
(10 -144)
( 13 -110)
( 21 -122)
UNITS
ug/L
ug/L
•
•
•
THERMORETEC =RP
!
Client Sample ID: EFF/SV-305 I
Lot-Sample# ... : COF150137-001
Date Sampled ... : 06/14/00
Prep Date ...... : 06/16/00
Prep Batch# ... : 0168267
Dilution Factor: 1
PARAMETER
Pentachlorophenol
SURROGATE
2,4-Dibromophenol
' GC Semivolatiles I
Work Ordkr # ••• :
Date Rec~ived .. :
Analysisloate .. :
' Method .. , ...... : I '
RESULT
ND
' PERCENT I
RECOVERY
59
DEP9D102
06/15/00
06/20/00
SW846 8041
REPORTING
LIMIT
2.0
RECOVERY
LIMITS
(31 -134)
Matrix ......... : WATER
MS Run# ....... :
UNITS
ug/L
•
•
•
Client Lot# ... : COF150137
MB Lot-Sample#: COF160000-262
Analysis Date .. : 06/19/00
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Phenol
SURROGATE
Phenol-dS
2-Fluorobiphenyl
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorophenol
2,4,6-Tribromophenol
NOTE S :
I
I
I METHOD BLANK REPORT
I
GC/MSISemivolatiles
I Work Order# ... : DETG8101
Prep
Prep
Date ...... : 06/16/00
BatJh # ••• : 0168262
RESULT
ND
ND
PERCENT
RECOVERY
70
63
69
94
60
71
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I
REPORTING
LIMIT
10
10
RECOVERY
LIMITS
(10
(30
(32
(10
( 13
(21
-113)
110)
112)
144)
110)
122)
UNITS
ug/L
ug/L
Calcul11tion.q are perfonneJ before rounding to 11void round-off error.:i in calculated re;~ulL1 .
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Matrix ......... : WATER
METHOD
SW846 8270C
SW846 8270C
•
•
Client Lot#---' COF150137
MB Lot-Sample#: COF160000-267
Analysis Date--: 06/20/00
Dilution Factor: 1
PARAMETER
Pentachlorophenol
SURROGATE
2,4-Dibromophenol
NOTE S :
I
I METHOD BLANK REPORT
Work
Prep
Prep
I
GC sefilivolatiles
I
I Order 1---' DETH8101
I
Dat~------' 06/16/00
Batch#--·' 0168267
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RESULT
REPORTING
LIMIT UNITS
ND 2-0 ug/L
PERCENT
RECOVERY
98
RECOVERY
LIMITS
(31 -134)
C11kulntion.s nre perfo11ned before rounding to uvoiJ roun<l•off erroni in cnlculntc<l l"isuttll.
i
Matrix .•••.•••. : WATER
METHOD
SW846 8041
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• I LABORATORY CONTROL SAMPLE EVALUATION REPORT
'
GC/HS ii Semi volatiles
Client Lot# ... : C0Fl50137 Work Order# ... : DETG8102-LCS Matrix ...•..... : WATER
' LCS Lot-Sample#: COF160000-262
AnalysislDate .. :
DETG8103-LCSD
Prep Date ...... : 06/16/00 06/19/00
Prep Batch# •.. : 01682 62
Dilution Factor: 1
PERCENT I RECOVERY RPO
PARAMETER RECOVERY I LIMITS RPO LIMITS METHOD
2-Chlorophenol 60 I (19 -124) SW846 8270C
60 I (19 -124) 0.88 (0-43) SW846 8270C
1,4-Dichlorobenzene 58 I (28 -110) SW846 8270C
59 (28 -110) 1.4 (0-36) SW846 8270C
N-Nitrosodi-n-propyl-67 I (30 -115) SW846 8270C
amine I 69 I (30 -115) 3.8 (0-36) SW846 8270C
1,2,4-Trichloro-58 I (31 -110) SW846 8270C
benzene
59 (31 -110) 2.7 (0-37) SW846 8270C
4-Chloro-3-methylphenol 63 (29 -124) SW846 8270C • 66 (29 -124) 4.1 (0-55) SW846 8270C
Acenaphthene 64 (39 -118) SW846 8270C
66 (39 -118) 2.4 (0-35) SW846 8270C
4-Nitrophenol 57 (19 -144) SW846 8270C
58 (19 -144) 1.8 (0-34) SW846 8270C
2,4-Dinitrotoluene 66 (47 -131) SW846 8270C
68 (47 -131) 2.7 (0-32) SW846 8270C
Pentachlorophenol 60 (10 -140) SW846 8270C
62 (10 -140) 2.8 (0-56) SW846 8270C
Pyrene 87 (46 -130) SW846 8270C
89 I (46 -130) 2.0 (0-31) SW846 8270C
Phenol 57 I (10 -131) SW846 8270C
59 (10 -131) 2.3 (0-43) SW846 8270C
I PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Phenol-d5 I 64 (10 113) I -
63 (10 -113)
2-Fluorobiphenyl
I
59 (30 -110)
60 (30 -110)
Nitrobenzene-dS ' 62 (32 -112)
63 (32 -112)
Terphenyl-dl4 86 (10 -144)
88 (10 -144)
2-Fluorophenol 53 ( 13 -110) I 53 ( 13 -110) • 2,4,6-Tribromophenol I 70 ( 21 -122)
I 69 ( 21 -122)
'
(Continued I on next page)
•
•
•
LABORATORY CONTROL SAMPLE EVALUATION REPORT I
I GC/MS Semivolatiles
I
Client Lot# ... : COF150137 Work Order# ... : DETG8102-LCS
LCS Lot-Sample#: COF160000-262 ! DETG8103-LCSD
NOTES:
C11h:ul11tiorl!I nre perfonne<l before rounding to 11Void round-off en-or.; in culculut~ re.~ulL~.
Boid print denotes control p11rnmeters I
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•
•
' LABORATORY =NTROi;, SAMPLE EVALUATION REPORT
Client Lot# ... : COF150137
LCS Lot-Sample#:
Prep Date ...... :
Prep Batch# .•. :
Dilution Factor:
PARAMETER
Pentachlorophenol
SURROGATE
2,4-Dibromophenol
NOTES:
C0Fl60000-267
06/16/00
0168267
1
GC sLivolatiles
' I Work Order# ... : DETH8102-LCS
PERCENT
RECOVERY
108
109
DETH8103-LCSD
06/20/00
RECOVERY RPO
LIMITS RPO LIMITS
(50 -126)
(50 -126) 0.73 (0-20)
PERCENT RECOVERY
RECOVERY LIMITS
90 (31 -134)
88 (31 -134)
CalculaliOllll are pet-formed before rounding to avoid round-off crror.i in calculnted rc.,ulL~.
Bold print denotes control pnrumeters
METHOD
SW846 8041
SW846 8041
•
•
U//IJ//UIJ AL'l'A ANALYTICAL 14]UUl/Ul.l
M
ALTA PJst-it" Fax Note 7671 Date l #-cl ► pages II
Tei . From .
June 5, 2000 C6.!De?t.
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Co.
Phono # Phone#
I
Alta Batch 1.D.: 8642 Far•qJ'l ;:;,11-IWf<' Fax#
Ms. Rita Bauer
ThermoRetcc Consulting Corporation I
300 Baker A venue \
~~3m I
Concord, MA 01742 I
I
Dear Ms. Bauer, I
I
Enclosed is the result for the one effluent sample received at Alta Analytical Laboratory on June
15, 2000. Th.is work was identified as your \Beazer/Raleigh project. This sample was analyzed
using EPA Method 8290 for 2,3,7,8-TCDD. IA standard turnaround time was requested for this
work. I
I
The following report consists of a Sample Inveritory (Section I), Analytical Results (Section II) and
the Appendix. The Appendix cotains a copy of the chain-of-custody, a list of data qualifiers and
abbreviations, our current certifications, diskette deliverables, and copies of the raw data.
i
If you have any questions regarding this report please feel free to contact me.
Sincerely,
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Alta AnalyticL Ll.boratory Inc .
I 5070 Robert J . .\fathtws Parkway
El Dorado I Hills, CA 95762
f,\J{ (916) 933-09•lo
[phone]
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I I Section [: Sample Inventory Report
Date Rec.lived: 6/15/00
Alla Lah. ID
8642-001
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Client Samp!c ID
EFF.SV-305
lf{JlHJ-.:./l!Ll
'"' -ALTA
v,, u,, "" _._., . .,.. f"':\.\ 11.l.O ~J,}.}\J~.14\J
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AL'l'.-1 ANALYTICAL
SECTION II.
I
14Joo:l/OU
1 ... -ALTA
•
•
·· ·· • ••••• •~•.u ,""JU,)U~J-ilJ ALTA ANALYTICAL
METHOD BLANK
Matrix: Aqueous
Compound
2,3,7,8-TCDD
Internal Standards
13C-2,3,7,8-TCDD
Clean-up Recovery Standard
37Cl-2,3,7,8-TCDD
Date Analyzed
DB-5: 7/3/00
Analyst: :ll'J.L
'1 ;rcnn
EPA METHOD 8290 I
Date Rechived:
I Date Extracted:
I
I Sample A.mount:
~ I
ND I
I
'.z'ill
56.3
%.R
67.5
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I Page I ofll
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tlA
6/19100
1,000 L
Ill M.llL
3.80 0.71]
14] 004/011
1~ -ALTA
Lab ID: 0-MBOOI
QC Set: 1.3.fi
Units: Qll.lL.
Qualifier
Revie-wer:
•
•
u I I ll t I ti <I
OPR RESULTS
Lab ID: OPR00l
Matrix: Aqueous
Compound
2,3,7,8-TCDD
Internal Standards
13C-2,3, 7,8-TCDD
Clean-up Recovery Standard
37Cl-2,3,7,8-TCDD
Date Analvzed
DB-5: 7/3/00
Analyst: W.JL
ALT,\ ANALYTICAL
I TCDD
EPA METHOD 8290
I I Date Received: !'{A
I
Date Extracted: 6/19/00
I
Sample Amount: 1.000 L
Spike
Cone.
10.0
Spike
Cone.
100
Spike
Cone.
40.0
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Pago J ~f I
Amount
Found
9.59
43.2
.%.R
62.2
QC Set: lli
Units: ng/mL
QPR Limits
7 -13
QPR Limits
40-135
OPR Limits
40 -135
Reviewer: &)_
[f\) 005/011
1 .. -ALTA
•
•
.'."i.L..J.:l. r,.1,.'1.1~1 I I V.'1.L
I 'l<CDD
I EPA METHOD 8290
I
Sample ID:
Project:
I
I
EFF.SV-305
BEAZER/RALEIGH I Date Received: Matrix: Effluent
Sample Amount: 0.857 L
Compound
2,3,7,8-TCDD
Internal Standards
13C-2,3,7,8-TCDD
Clean-up Recoverv
37Cl-2,3,7,8-TCDD
Date Analvzed
DB-5: 7/3/00
Analyst: WJL
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Date Extr~cted:
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Cone. II
ND
•/4,R
53.5
"/2,R
74.8
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Page19r1
6115100
6/19/00
DL
3.94.
MDL
0.711
~ \/\JU/ \J J. I
Jj,. -ALTA
Lab ID: 8647-0()l
QC Set: lli
¾Solids N6.
Units: ]l.g{L
Qualifier
Reviewer: ~
0
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I APPENDIX
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tgjlJU(/UlL
Jj,_ -ALTA
•
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A
B
C
D
E
F
G
H
I
Cone.
D.L.
NA
SIN
*
ND
MPC
:\LT:-\ .--\1":\LlTll_;:\L
I
DATA QUALIFil):RS & ABBREVIATIONS·
I
I The amount detected is below the Method
Calibration Limit. I
I I This compound was also detected in the blank.
I .
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The amount detected is less than five times the Method
Quantitation Limit. \
The amount reported is the maximum possible concentration.
I
The detection limit was raised above the Method Quantitation ' Limit due to chemical interferences.
I
This result has been cpnfirmcd on a DB-225 column.
I
This result has been confirmed on a SP-2331 column. I
I The signal-to-noise raj:io is greater than 10:1.
I
Chemical lnterferencJ
'
Concentration
Detection Limit
Not applicable
Signal-to-noise
See Cover Letter
Maximum Possible Co'!centration
{gjtltl.S/011 ,. -ALTA
•
•
L" • "U-< • ,.~ _, L V ,, '-' •~" ., --. _,
I
CURRENT CERTIFICATIONS
JJt. -ALTA
I
Bureau of Reclamation-Mid-Pacific Rcgion---(MP-470, Res-1.10)
I
Commonwealth of Kentucky---(Certificatc No. 90063)
Commonwealth of Virginia---(CertifiLte No. 00013)
'
State of Alaska, Department of Envifonmental Conservation---(Certificate No. OS-00197)
State of Arkansas, Department of Hjalth---(Approval granted through CA certification)
State of Arkansas, Department of Enlvironmental Quality---
1
State of California---(Certificate No. 1640)
'
State of Connecticut---(Certificate Nol. PH-0182)
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State of Florida---(Certificate No. 87456)
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State of Louisiana---(Certificate No. 98-33)
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State of Mississippi---(Approval granted through CA certification)
. I
State of Nevada---(Cert,ficate No. CA413)
State of New York, Department of HLlth---(Certificate No. I 1411)
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State of North Carolina---(CertificatelNo. 06700)
State of North Dakota, Department of Health---(Certificate No. R-078)
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State of Oregon---j
State of Pennsylvania---(Certificate No. 68-490)
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State of South Carolina---(Certificate No. 87002001)
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State of Texas -(Certificate No. TX247-2000A)
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State of Tennessee---(Certificate No. 02996)
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State ofUtah---(Certificate No. E-201)
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' State of Washington, Department of fcology---(Certification No. C091)
State of Wisconsin---(Certificate No. 998036160)
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State of \Vyoming---(Ref: SES-LB) f
:
U.S. Army Corps of Engineers
U.S. 5 EPA Region
May 2000
•
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"', "', "" ~\/ I.I// 1/l.l
' STANDARD OPERATING PROCEDURE
I
I
I Attachment 10. 8.1
SAMPLE LOG-IN CHECKLIST
AL TA Project No.: _,@."--t_C/_2 ___ _ I
iC\ienUProtocol No. _____________ _
I. Date Samples Arrived: b r /~ = I Initials: .I?..-Location: fol
I
2. Time/ Date logged in: 0-/S-CJV /~62> Initials: ~ Location: ,I{-/
'
Samples Arrived By: (circle) ('FedEx ) UPS
:
3. forld Courier Other:
' ::;>
4. Shipping Preservation: (circle) @)slue Ice: / Ory Ice / None Temp °C =-
i YES NO NA
5. Shipping Container(s) Intact"? If not, describe co1ndition in comment section. ?'(.
I
6. Shipping Container(s) Custody Seals Present? I 'r:
Intact? \f not intact, describe condition in comme,nt section. --.c::
7. Shipping Documentation Present? (circle) Shibping Label ~ ;(
Tracking Number <g-2o ;;z-i:;;: :;i $=. y(A"i:/
8. Sample Custody Seal(s) Present? No. of Seal~ or Seal No. )<
If not intact, describe condition in com~ent section. Intact? ><
'
9. Sample Container lntact?-lf no, indicate sample dandition in comment section. r<. '
10. Chain of Custody (COG) or other Sample Docurrientation Present? ye
I
11. COG/Documentation Acceptable? If no, complete COG Anomaly Form. '?
I
12. Shipping Container (circle): ALTA zClient} ~or Return or Disposed
13. Container(s) and/or Bottle(s) Requested? I x
14. Sample Control Check In/Out Log Completed? (HRMS Only) y
15. Drinking Water Sample? (HRMS Only) If ye~, Acceptable Preservation? Y or N )<-' PreseNation Info From? (circle) COG or sample Container or None Noted
'
16. Number of Samples Received: I
'
Name: _________________ ~ Date Samol·:s Reco:~ciled:
(Signature Required for LCMS Only)
Comments:
SOP# CH10Br12, Page 4 of6
I
e. •
ALTA
CI-IAIN OF CUSTODY RECORD
Project I.D.: (J£A-7v/ IRA{.tw-W I ~
Date:
G 1).
Rel in Date: Time: Dote: Time:
Relinquished by: (Si1:m1un;: wd !'limed Name) Date: Time: Received by: (Sig~atun: ind Prmiul Name) Date: Time:
-. --····· .. -. -.. ---... -. ·----. ······-, .. ,. ..
SHIP TO: Alta Analytical Laboratory Method of Shipment Circle or Add
5070 Robert J. Mathews Parkway Analysis(cs) STANDARD TAT= 21 DAYS.
El Dorado llills, CA 95762 Requested Surcharge may be applied [phone] • Fax [phone] for less than 21 days. www.alrnlab.com Shipment ID: "' TAT (Analytical Turnaround Times): 1 = 7 days,
ATTN:. o" 2 = 14 day_s, 3 =_21_days,.4 = 28 days---
:,'<' ii'· ""' ~ -0,"' ~-£:'" .. ---
-------.-·-~-------~ ·u' ~ "5.: :\,q:; b,. t-"' o Containcr(s) -
Sample ID Date Time Sample Description
~ 'b ', 'b ~ -ii'. iY1 ~'!,,,. <>"' 'Ce,'<' ,s,,. e,'<' e,'r-~'!-"' TAT Qty Type M,urix Bl'T'
~ .{"v -30-f" I I o-i.r, ~~
Special lnstmctions/Comments:
Container Types: A= 1 Ltlar Amber, G = Glass ,Jar
P = PUF, T = MM5 Train, 0 = Other ______ _
..,,._ .2... A-€r -•
'
-, ,. ,,_.,. ,e,~ :Qa!,!tName: .
SEND , rl.C,L'Ak> ~ --.,c._..
DOCUMENTATION
AND RESULTS TO:
'Bottle Preservative Type: T = Thiosullale,
0 = Other _________ _
WHITE-ORlGINAL YEU,OW -ARCIIIVE
Company:
Address: ;7~ AA ~ A-IA,£;
City: ~oo&:1_ State:L!lA Zip:_af2Q__
Phone:r:j)?}JiC-r Y22... Fa" -------
Malrix Types: DW = Drinking Water, EF = Effluent, PP= Pulp/Paper,
SD= Sedimenl, SL= Sludge, SO= Soil, V✓W::::. Waslewater, 0 =Other _____________ _
PINK-COPY
C
=
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ANALYTICAL REPORT
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!
PROJECT NO. RALRIGH
'
RaleightBi-Weekly NPDES
Lot Ilk COF2701.94
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!
De.blt Leuteritz
I I ThermoRetec
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SEVERN TRENT 1L1\.80RATORIES, INC.
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1:,,1 4
ft/2"/7Uctt,,iJ-c-1,Z:,-:&-
veran.ica Bertot
' I ProJert Manager
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Juli 6, 2000
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STL Pitt~UL!rgh is .'.! p2rt o_t Seve,n Trent Laboratories, !nc.
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: S'E,Y;ERN
STL Pittsburgh
450 William Pitt Way
Pittsburgh, PA 15238-1330
Tel: 412 S20 8380
Fax: [phone]
wwv1.stl-inc.com
•-■! • Chain of
Custody Record
CUA 4124 0797
Client
'1 ~ Project Manager . . ~ I/.· \ Date Chain of Gus.lady Numh~J _7 ,·: q . \ '-:~ /?_, ·(\I() JO i<f ... ·{_,{ \~--. l> .. ,,.,\r._1 __ t ~--..0: \ 'O it.,,_, . ! ,::. (_ ',;-} / ·,.! .. f i\.1U ,-:,,, .\.,. '-
Address Te(ephone Number (Area Cade)!Fax Number Lab Number
.5!"';("' '"17, i\\.:_( ,, '-i\, ,~-~. ( C\7){\ ~-,, \ u\ ?.'7-Page al ' Cit'/. I Slate I Zip Code Silq Com:1c/ Lab Contact Analysis (Attach list if
( .,r, .. -, /,. ' ,Al/\ D\l'-ll-r.. \' . more S'lace is needed) r ~.\ ..._("\'" \ ,,._ \ _,J_ ✓ ' Project Name CarrieoWaybill Number .
1-,, i f \I ' {'\c. /c, ,, I ;,_l_ \ (/Z., 7-;;,::, 1 ·-1 i / ;'-,_, t·,._ -7; ( r!n1."·.,-,\ ., -_';v.: . .J Special Instructions/ Contrac//Purchase Ordtir/Ouofe No. \ Containers & Conditions of Receipt Malrix Preservatives r •, ,, ,,
Sample i.D. No. cind Description I I 0 ~ , "a ,,, ,,\'l Date Time g ] ~ 0 0 !..\ -,, (Containers for each sample may be combined on one fine) ~ , ~ ~~ ' ~ , ,
f-: \.-F--I ,, I .. .. l,-7(..-oo t/·-\<t.) j__ 'y ·, '/.. I '. \ .. -, r,, ,, {\ -
---------
-----------,,. -. ----. ----· ------------•. . ----.,
;
Possible Hazard Identification I Sample Disposal . {A lee may be assessed if samples are retained
[]JJon-Hazard D Flammable D Skin lrrilant D Poison B D. Unknown D Return To Client ~:Vpisposal By Lab D Archive For Months longer than 3 months)
Turn Around Time Required (,1--0 QC Requirements (Specify)
D 24 Hours 0 48 Hours □ 7Days □ 14 Days D 21 Days [J'o1her:
I. Relinquis~_7d!~ u rP l Date ;
1
Time 1. Received By ' ID,Ue
1
Time "/' ! . . . /1.i'f l.~;d;,·~~·:;/ I L-· ·-t--~ ... -__,,,.,,,. .1.X; /r. -l h i~li., -' /-~o ;_) , ' 2. Relinquished Dy l Dale
1
Time 2. Received Dy_; 'tJ , I . l~~t\ I ~r'.?~·-<, .
" I 'r·• -,, i ; .. ,. . .\! •!, i, I I t~ : ,.-I _,,,
3. Relinquished By j Date
1
//me 3. Received By " ' ' .
1
Da/e /
1
r,mc
Commen/s
DISTRIBUTION: WHITE· Stays with /he Sample; CANARY. Returned lo Client with Report; PINK -Field Copy
•
C,~SE NARRATLVE
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I
THERMORETEC CORPORATION
' I Raleigh
STE LtJL # COF270 l 94
' i I
Sa1nple Receiving: I
STL Pittsburgh, PA received o,1e sample on June 27, 2000 in good condition and at the
proper temperature. I
I
GC/MS Semivolatiles: !
There were no problems associated with the analysis.
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GC Phenols: I
There were no problems associated with the analysis.
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PARAMETER
Phenols by GC
'1
METHODS SUMMARY I
COF270l94
1\NALYTIC.AL
METHOD
Semivolatile Organic Compounds by I
Gt;:/~1S
SW846 8041
SW846 8270C
References: I I
i
PREPJ\.Rl\.TION
METHOD
SW846 3520C
SW846 3520C
SW846 11 Test Methods for Evaluating Solid Waste, Physical/Chemical
' Methods 11 , Third Editio'n, November 1986 and its updates. '
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i SAMPLE SUMMARY
':!Q__jL_ SAMPLE~ CLIENT SAMPLE ID
DFCVS 001 EFF/SV-305
Narn (Sl ,
I
\ COF270l94
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-The unulyticu! n:.1ulL, ,if the .,umplc.~ futcd :i.bove :\re prc.3e11tcd on the fo!lowin~ pnges.
' -All cuk:u!ntion., nre performed before rnunding to nvoid rouud-off erron in culculMed resulu.
• Re11u!t,i uuted 11.:1 'ND' were not detec!OO 11t or nbove the ,tnted limit. I
' -Tl1is report mlll!t not bo reproduce,:,!, except in ti.ill, without the written 11pprov11-! of the luborutory.
-RC11ult11 for the following p1111unctcr.1 11.rci never repmtN on n dry weight b1ui.,,: Joler, curro~ivity, density, flll.Shpoint, ignitribiliLy, !nyers, odor,
' puinL filter tr,it, pH, pormity prcssw-c, reactivity, redo;,; potcntfol, specific gruvity, .,pot tesu, soli,b, solubitily, tcmpcruture, vi:,co~ity, 11nd weight.
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D.Z,TE TIME
06/26/00 09 ,so
•
•
I
I TIIERMORIITEC CORP I
I Client S~le ID: EFF/SV-305
Lot-Sample# ... : C0F270194-001
Date Sampled ... : 06/26/00
Prep Date ...... : 07/02/00
Prep Batch# ... : 0185094
Dilution Factor: l
PARAMETER
2,4-Dichlorophenol
Phenol
SURROGATE
Phenol-d5
2·Fluorobiphenyl
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorophenol
2,4,6-Tribrornophenol
I GC/MS Semivolatiles
I
Work Order # ... : ' Date Received .. :
1 I. Ana ysis Date . _ :
i
Method ......... : I
I
' RESULTI
ND
ND
PERCENT
' RECOVERY
56 I
58
I 64
94
43
80 I
I
I
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I
I
i
I
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I
I
DFCV5101
06/27/00
07/03/00
Matrix ......... : WATER
MS Run# ....... :
SW846 8270C
REPORTING
. LIMIT
10
10
RECOVERY
LIMITS
(10 113)
(30 110)
(32 112)
(10 144)
(13 110)
(21 122)
UNITS
ug/L
ug/L
•
•
I
I
I TiffiRMORETEC CORP I
Client seimple ID: EFF/SV-305
I - - .
Lot -Sample # ... ,
Date Sampled. _ . :
Prep Date .. _ ... :
Prep Batch # ... ,
COF270194 -001
06/26/00
07/01/00
0183155
Dilu~ion Factor: l
PARAMETER
Pentachlorophenol
SURROGATE
2,4-Dibromophenol
GC Semivolatiles I I Work Order# ... :
Date Rkceived .. :
Analys~s Date .. :
I Method ......... :
I
RESULT I
ND I PERCENT ' R]'.;'COVERY
79 I
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DFCV5102
06/27 /00
07/03/00
SW846 8041
REPORTING
LIMIT
2.0
RECOVERY
LIMITS
(31 -134)
Matrix ......... : WATER
MS Run# ....... ,
UNITS
ug/L
•
Client Lot# ... : COF270194
MB Lot-Sample#: COGOl0000-155
Analysis Date __ , 07/04/00
Dilution Factor: 1
PARAMETER
Pentachlorophenol
SURROGATE
2,4-Dibromophenol
NarE(S):
METHOD BLANK RRPORT I ' GC 1semivolatiles
I Work Orper # ___ : DFMEFlOl
Prep Date .. _ ... : 07 /01/00
Prep Batch# ... : 0183155
RESULT
ND
PERCENT I
RECOVERY•
91 I
' I
REPORTING
LIMIT UNITS
2.0 ug/L
RECOVERY
LIMITS
(31 -134)
Culculutiorui urc pcrfonnecl before rounding to 11void round-off error., ia culeufoted r~uJL'!.
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Matrix ......... : WATER
METHOD
SWB46 8041
•
Client Lot# ___ , COF270194
MB Lot-Sample#: COG030000-094
Analysis Date __ , 07/03/00
Dilution Factor: l
PARAMETER
2,4-Dichlorophenol
Phenol
SURROGATE
Phenol-d5
2-Fluorobiphenyl
Nitrobenzene-dS
Terphenyl -d14
2-Fluorophenol
2,4,6-Tribromophenol
NOrE(S):
METHOD BLANK REPORT
I
I GC/MS Semi-volatiles
I
Work Ofder #-•.. : DFN9Nl01
I Prep Date ______ , 07/02/00
Prep Batch ff ___ : 0185094
I I
'
RESULT I
ND
ND I
i
PERCENT I
RECOVERY!
58
58
60
99
43
80
I
I
I
I
REPORTING
LIMIT
10
10
RECOVERY
LIMITS
(10 113)
(30 110)
(32 112)
(10
(13
(21
144)
110)
122)
UNITS
ug/L
ug/L
Calcul11tiow are pc:rfornml before rounding to 11.void round-off crron in cnlcula~ re.111!t.1.
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!
Matrix ......... : WATER
METHOD
SW846 8270C
SW846 8270C
•
•
I LABOR.r\.TORY CONTROI, St-'"\HPLE EVALlJATION REI?ORT
Gclsemivolat:iles
Client: Lot: II ... : COF270194 I Work Order # ... : DFHEF102-LCS
DFMEF103-LCSD
07/04/00
Matrix ......... : WATER LCS Lot-Sample#: COGOlOOQQ-155 I
Prep Date ...... : 07/01/00 Analys~s Date .. :
Prep Batch II ... : 01B3155
Dilution Factor: 1
PERCENT I RECOVERY
' PARAMETER RECOVERY, LIMITS
Pentachlorophenol 89 (SO -l.2 6)
92 (SO -l.26)
i PERCENT
SURROGATE I RECOVERY
2,4-Dibromophenol I 91 I 92 I
Nam (S) : I
Colcul11tio!lll = pcrformod before rounding to avoid rourn.l•off crron in calcu!n~ results.
Bold print deootel cootrol po.mmctcn I I I
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RPD
RPD LIMITS METHOD
SW846 8041.
4-0 (0-20) SW846 8041
RECOVERY
LIMITS
(31 134)
(31 -134)
LABORATORY COID:ROI, SAMPLE RVALUATION REPORT
GC/MS Semivolatiles
Client Lot # •.. : COF270194 Work Order# ... : DFN9Nl02 -I.CS Matrix._._ .... _: WATER
I.CS Lot-Sample#, COG030000-0H DFN9Nl03-LCSD
Prep Date .... _.: 07 /02/00 Analysis Date .. : 07/03/00
Prep Batch # _ . _ , 0185094
Diluticm Factor: 1
PERCENT RECOVERY RPD
PARAMETER RECOVERY LIMITS RPD LIMITS METHOD
2-ClIJ.orophenol 61 (19 -124) SW846 8270C
60 (19 -124) 3.0 (0-43) SW846 8270C 1,4-Dichlorobe.nzene 55 (28 -110) SW846 8270C
53 (28 -110) 4.5 (0-36) SW846 8270C
N-Nitrosodi-n-propyl-59 (30 -115) SW846 8270C
amine
58 (30 -115) l.5 (0-36) SW846 8270C
l,2,4-Trichloro-56 (31 -110) SW846 8270C
benzene
56 (31 -110) 0.80 (0-37) SW846 8270C
4-C!Iloro-3-methylphenol 66 (29 -124) SW846 8270C
67 (29 -124) l.5 (0-55) SW846 8270C
Acenaphthene 70 (39 -118) SW846 8270C
70 (39 -118) 0.35 (0-35) SW846 8270C
4-Nitrophenol 65 (19 -144) SW846 8270C
66 (19 -144) l.2 (0-34) SW846 8270C
2,4-Dinitrotoluene 73 (47 -131) SW846 8270C
72 (47 -131) 0.77 (0-32) SW846 8270C Pentachlorophenol 80 (10 -140) SW846 8270C
82 (10 -140) 2.0 (0-56) SW846 8270C
Pyrene 85 (45 -130) SW846 8270C
85 (46 -130) 0.46 (0-31) SW846 8270C
Phenol 51 (10 -131) SW846 8270C
51 (10 -131) 0.55 (0-43) SW846 8270C
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Phenol -d5 57 (10 113)
55 (10 113)
2-Flucrcbiphenyl '" o. (3 0 110)
62 (30 110)
Nitrobenzene-d5 62 (32 112)
63 (32 112)
Terphenyl-dl4 95 (10 144)
92 (10 144)
2-Fluorophenol 41 (13 110)
39 (13 110)
2,4,6-Tribramophenol 83 (2l 1.22)
83 (21 122)
(Continued on next page) •
•
ulli.~RATORY CONTROL SAMPLE: EVALUATION REPOR'I'
GC/MS Semivolatiles
Client: Lot: # ... , COF270194 Werle Order # ... , DFN9N102-LCS Matrix. __ .. _ ... , WATER I.CS Lot-Sample#, COGOJ0000-094 DFN9N103-LCSD
NOTE (S) ,
CQJ,:;ufotion., nre performed before rounding to avoid round-off error, in Clllcu!a.tcd re~ult,.
8t)ld print d,:nolul control pRl"llflJ~teu
RA
flNCDENR
J.-.MES 8. HUNT JR .•
GOVERNOR
BILL HOLMAN
SECRETARY
... ---~-
NORTH CAROLINA DEPARTMENT OF
ENVIRONMENT AND NATURAL RESOURCES
DIVISION OF WASTE MANAGEMENT
June 26, 2000
Ms. Beverly Hudson
Remedial Project Manager
Superfund Branch
Waste Management Division
United States Environmental Protection Agency
Region rv
6 I Forsyth Street, 11 th Floor
Atlanta, GA 30303
Re: Monthly Progress Report #85 (May)
Koppers Company NPL Site
Morrisville, Wake County
Dear Ms. Hudson:
The Superfund Section of the North Carolina Department of Environment and
Natural Resources (NC DENR) has received Monthly Progress Report #85 (May)
for the Koppers Company National Priorities List (NPL) Site. The Superfund
Section has reviewed this document and offers the following comments.
Monthly Progress Report #85 -May 2000
I. Monthly Progress Report #84 (April 2000) was not received by the NC
DENR Superfund Section. Please correct this oversight. Additionally,
please provide responses to the regulatory comments issued July 1999
through April 2000.
2. Table 2 indicates that in April 2000, the facility failed its toxicity test. The
May 2000 toxicity test had complete survival with treatment organism
reproduction essentially the same as the control organisms. Table 2
indicates that the groundwater treatment system effluent passed the
chronic toxicity test. In the body of the report there was no explanation or
response to the toxicity described. Please detail any activities that were
undertaken to correct the effluent quality. Please detail whether provisions
stipulated in the Toxicity Reduction Evaluation Work Plan were
implemented.
wm ►U•MN·IM
1646 MAIL SERVICE CENTER, RALEIGH, NORTH CAROLINA 27699-1646
401 OBERLIN ROAD, SUITE 150, RALEIGH, NC 27605
PHONE 919-733•4996 FAX [phone] AN EQUAL OPPORTUNITY I AFFIRMATIVE ACTION EMPLOYER• 50% RECYCLED/IC% POST•CONSUMER PA.PER
Ms. Beverly Hudson
June 26, 2000
Page 2
We appreciate the opportunity to comment on this document. If you have any questions, please feel free to call me at (919) 733-280 l, extension 349.
Sincerely,
David B. Mattison, CHMM
Environmental Engineer
Superfund Section
cc: Judy Garrett, NC Div. of Water Quality
Matt Matthews, NC Div. of Water Quality
Mike Slenska, Beazer East, Inc.
•
June 8, 2000
Ms. Beverly Hudson
Remedial Project Manager
U.S. EPA-Region IV, 11 th Floor
North Site Management Branch
6 I Forsyth Street, SW
Atlanta, GA 30303
RE: Monthly Progress Report #85
Remedial Action
Koppers Site -Morrisville, NC
Dear Ms. Hudson:
ThermoRetec Corporation
300 Baker Avenue, Suite 302
Concord, MA 01742
Smart Solutions. Positive Outcomes.
[phone] Phone
[phone] Fax
www.thermoretec.com
In accordance with the Unilateral Order, and on behalf of Beazer East, Inc. (Beazer),
please find attached four ( 4) copies of the May Monthly Progress Report for Remedial
Action at the Koppers Superfund Site in Morrisville, NC.
Should you need additional information regarding this progress report, please call Mike
Slenska at [phone] or me at [phone]
Sincerely,
ThennoRetec Consulting Corporation
G~.~
Rita Bauer
Project Geologist
RB:cg
Enclosure
cc: Q-:-Nl;I.tTiso11-c:-N e-S-.!Tp~e-rfmrd:(2:cQpi es )l'
D. Hails -Ecological Restoration, Inc.
J. Garrett -NC Division of Water Quality
P. J(ilchenstein -ThermoRetec
F: \PR OJ ECTS\03 624 \CORR ES\20(Kl\H uJs0606. wpd
RECf-lVF.n
JUN 12·2000
SUPERFUND SEG1 •
M. Slenska -Beazer
L. Faulconer -Wake County
G. Caskey -Enwood Structures
M. Helbling -Beazer
a Thermo Electron company
-
•
•
•
MONTHLY PROGRESS REPORT #85
REMEDIAL ACTION
SITE NAME: Koppers Superfund Site
Beazer East, Inc.
Morrisville, NC
USEPA DOCKET NUMBERS: 93-09-C
PERIOD ENDING: May 31, 2000
1. PROGRESS MADE THIS MONTH
2.
3.
4.
5.
6.
Remedial Action (RA) -HABITAT MIT/GA T/ON. No activities were conducted this
month.
Remedial Action (RA) -GROUNDWATER TREATMENT. The treatment system
operated throughout the month without upset. System performance was monitored
on a biweekly basis. Approximately 70,100 gallons of groundwater were extracted,
treated in the treatment plant and discharged between April 24 and May 31, 2000.
System water samples were collected on May 5, 2000 (Toxicity), May 15, 2000 and
May 31, 2000 in accordance with the sampling schedule in the O&M manual.
Samples were submitted to Severn Trent for laboratory analysis. The operations
and sampling programs are summarized on the attached Table 1 .
Remedial Action (RA) -EFFECTIVENESS MONITORING PROGRAM. No activities
were conducted this month.
Remedial Action (RA) -CORRESPONDENCE. None,
PROBLEMS RESOLVED
PROBLEMS ANTICIPATED
UPCOMING EVENTS
PERSONNEL CHANGES
SUBCONTRACTORS
'
None.
None.
Continue System O&M.
None.
None.
7. ANALYTICAL DA TA Analytical data from system influent and effluent sampling
received during this period are enclosed and are summarized on Table 2 .
F: \PROJECTS\03624\CORRES\2000\Huds0606. wpd
•
Date Systems Check Cummulative
(yes/no) Effluent Flow
(Gallons)
01/04/00 ves 2.178,450
01/20/00 ves ? .201.060
02/02/00 ves 2.223,670
02/18/00 ves 2.243.495
03/03/00 ves 2,278.733
03/13/00 ves 2.313,971
04/12/00 ves 2,382,031
04/24/00 ves 2,450.091
05/05/00 ves 2,472,228
05/15/00 ves 2.490.675
05/31/00 ves 2,520,191
Notes:
SV-101 -Before Carbon Units (pretreatment)
*SV-304 -Between Carbon Units
SV-101
Sample
(ves/no)
nn
no
no
no
no
no
no
no
no
no
no
**SV-305 -Afler Carbons Units (post-treatment)
e
Table I
Groundwater Treatment Operations and Sampling Program Summary
Koppers Superfund Site
Morrisville, North Carolina
April 2000
SV-101 Associated V-304* SV-304 Associated
Sample Group Sample Sample Group
Parameters (ves/no) Parameters
no
no
no
yes 2,4-Dich\oro. Phenol 3
no
no
no
no
no
no
no
Associated Groups:
SV-305**
Sample
(ves/no)
ves
ves
ves
ves
ves
yes
ves
ves
ves
ves
ves
SV-101 -Group I is penta and 2,4-dichlorophenol; Group 2 is dioxins
SV-304 -Group 3 is penta and 2.4-dichlorophenol
SV-305
Sample
Parameters
Penta. 2,4-Dich\oro. Phenol, !OX
Penta. 2,4-Dichloro, Phenol
Penta. 2.4-Dich\oro. Phenol. tox
Penta. 2.4-Dich\oro, Phenol, dioxin
Penta. 2.4-Dichloro, Phenol
Penta, 2,4-Dich\oro, Phenol
Penta, 2.4-Dichloro, Phenol, tax
Penta, 2,4-Dichloro, Phenol
Tox
Penta, 2.4-Dichloro. Phenol
Penta, 2,4-Dichloro, Phenol
SV-305 -Group I is penta and 2,4-dichlorophenol; Group 2 is dioxins and Group 4 is 10xici1y
•
Associated
Group
1.4
1
1.4
1.2
1
1
1.4
1
4
1
1
•
0
•
Parametcr
Pentachlorophenol
2.4-Dich\orophenol
Phenol
Chronic.: Toxicity
Dioxin (2,3,7,8-TCDD)
Table 2
Groundwater Treatment
ANALYTICAL DATA SUMMARY
Koppers Superfund Site
Morrisville, North Carolina
April 2000
Analytical
Datt: Sample
Sample Location
Collected SV-101
01/04/00
01/20/00
02/02/00
02/18/00
03/03/00
03/13/00
04/12/00
04/24/00
05/15/00
05/31/00
01/04/00
01/20/00
02/02/00
02/18/00
03/03/00
03/13/00
04/12/00
04/24/00
05/15/00
05/31/00
01/04/00
01 /20100
02/02/00
02/18/00
03/03/00
03/13/00
04/12/00
04/24/00
05/15/00
05/31/00
01/04/00
02/01/00
04/ 12/00
05/05100
02/18/00
Samplt:
Location
SV-304*
<2
< 10
< 10
Notes: All results are in ug/L except dioxin, Dioxin data is in picograms/L.
SV-101 -Before Carbon Units
*SV-304 -Between Carbon Units
**SV-305 -After Carbon Units
Sample
Location
SV-305**
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
< 10
< 10
< 10
< 10
< 10
< 10
< 10
< 10
<10
< 10·
< 10
< 10
< 10
< 10
< 10
< 10
< 10
<10
< 10
< 10
Pass
Pass
Fail
Pass
< 1.2
Effluent Toxicity Report Form -Chronic Pass/Fail and Acute LCSO Date: 05/11/00
Facility: BEAZER NPDES#: NC Pipe#: County: WAKE
Laboratory Performing Test: TRITEST, INC.
Comments:
x--;acc=2-S-C:c=c--c~~=~~=-,n:c:-::==-=s=-=--c==~----erator in Respons1
Work Order: 0005-00115
MAIL ORIGINAL TO:
North Carolina Ceriodaphnia
Chronic Pass/Fail Reproduction Toxicity Test
CONTROL ORGANISMS 1 2 3 4 5 6 7 8 9
# Young Produced 32 35 32 29 29 32 32 14 16
Adult (L)ive (D)ead L L L L L L L L L
Effluent %: 90%
TREATMENT 2 ORGANISMS 1 2 3 4 5 6 7 8 9
10 11
7 31
L L
10 11
* PASSED: 12.58% Reduction*
Environmental Sciences Branch
Div. of Environmental Management
N.C. Dept. of EHNR
4401 Reedy Creek Road
Raleigh, North Carolina 27607-6445
Chronic Test Results
Calculated t = o. 964
Tabular t = 2.508
12 % Reduction= 12.58
% Mortality Avg.Reprod.
21
0.00 25.83
Control Control
L
0.00 22.58
Treatment 2 Treatment 2
12 Control CV
34. 969% PASS FAIL
# Young Produced 12 15 18 14 26 19 18 33 30 28 26 32 % control orgs 0C producing 3rd
brood Check One
Adult (LI ive (DI ead L L L L L
1st sample 1st sample
pH
Control
Treatment 2 ~ ~
s s
t e t e
a n a n
r d r d
t t
1st sample 1st sample
D.O.
L L L L
2nd sample
~
s
t e
a n
r d
t
2nd sample
L L L 91. 7%
Complete This For Either Test
Test Start Date: 05/03/00
Collection (Start) Date
Sample 1: 05/02/00 Sample 2: 05/04/00
Sample Type/Duration
Grab Comp. Duration
Sample 1
f----+---+-----
X 24 hrs
S ample 2 X 24 hrs
1st
D
I S
L A
U M
T p
Hardness (mg/11 49 ......... .
2nd
P/F
s
A
M p
Control 2 ~ [fBH] f----+---+-----1
Spec. Cond. (µmhos) 190 900 910 Treatment 2 f--__ _,_ __ _, __ __,
Chlorine(mg/1) <0.1
LC50/Acute Toxicity Test Sample temp. at receipt(°C) 2.5
(Mortality expressed as%, combining replicates)
% % % % % % % Concentration
% % % % Mortality L __ c___---1 __ .J.. __ ..1_ __ .L.. __ L-_-1. __ _L __ _1___ start/end
LCSO _____ %
95% Confidence Limits
Method of Determination
Moving Average Probit
% % Spearman Karber Other
pH
Organism Tested: Ceriodaphnia dubia Duration(hrs):
Copied from DEM form AT-1 (3/87) rev. 11/95 (DUBIA ver. 4.32)
Note: Please
Complete This
Section Also
start/end
D.O.
<0.l
3.1
•
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•
•
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0 1? '-I:?,
_w~A~kL.~-------Outfall/ Pipe#:-----
Phund{ 97'J I ,J,]/-/'(;J_.::z.__
Cuntact : ~ 17---,.q /},4 u,;;,;,L-
SPDES P,rmit #: A{)t11rf'(. l£-Tti?Z;C-
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--~! ·.v1· \:
f f t t • t I O t f f f I f I t I t t t I t t t t f -f) -~J: .~~ai~ of~ust_o~y.~~kaJ~;
.) -, _, .• _}... ~-, ,. I ·f> ,.-_~•·······~·:··············
~-Ll v: trc <:..:.:;.J(HJ\:.;' · 1}" ! ; .::J lL
Ri.:i.:.:i \ Ill:.! r .:mpi.:r:Hur.:: -,--'~""'"-'~s'--,---i';1,,,:---__ ,_.t~-· .,,:1:·_r,,,·\)r:·1·_~
'.• -'.,. · . /L :l : "~( · ~,-'!.t ... ,ttg._;1_\l ,.,
fh::-iJu~l l'hllirin.:: ;.t ~iJi ~tU-;: Sumb~rot:Bou'i~~:~, . ,,;-,~,c-,---..,,., -~-.;c~,..::'--,,.,.It"'t"··rimcc~,ril~(0
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:t1dr~~~-J()(J() ·[k·~:FR~.Tkaieii1. ~2!21E1 1·~~~n; 9).rgJ-4 -~~~1 F~f-{;1, 9~!Jj~_6-i91; i:'
·.; .. •:. : ::~; ff{ if· r!j. n ; ·.·.•i • 'fr . ff·:f! •"•? ·., .. Fl
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•
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TRITEST, INC.
Cc r\:'{: ~,cS)
n.-r:.
s:lr:/4o
lbt,.: EnJ,:J S"'/s/o0
I
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0;1h: . _________________ _
. . . . . . . '.' ... ''
p L) :i .
Ph,,nc • i 9 7 'J I J]/ -/ 'f _;]_ 2._
A! , -r-A Ii A v.;,:z:,,L-
Tim~: 0~2-0 @, P\I
Tim~: o~zo @r P~I
1' Huur.;: ;; L.
' ... ' ''.' ... '' ....
______________ \uml:'ic.:r vf Butlk::i
$?''$ ()
•
•
•
ANAL Y""TICAL REPORT
PROJECT NO. RALEIGH
Raleigh-Bi-Weekly NPDES
Lot #: C0E1 70218
Debbi Leuteritz
ThermoRetec
SEVERN TRENT LABORAIDRIES, INC.
Veronica Bortot
Project Manager
May 23, 2000
STL Pittsburgh
450 William Pitt Way
Pittsburgh, PA 15238
Tel [phone]
Fax 412s2:02oao
www.stl-inc.com
•
•
Sample Receiving:
CASE NARRATIVE
THERMORETEC CORPORA TlON
Raleigh
STL Lot# C0El 70218
STL Pittsburgh, PA received one sample on May 17, 2000 in good condition and at the
proper temperature.
GC/MS Semivolatiles:
There were no problems associated with the analysis.
GC Phenols:
There were no problems associated with the analysis .
•
•
METHODS SUMMARY
COE170218
PARAMETER
Phenols by GC
Semivolatile Organic Compounds by GC/MS
References:
ANALYTICAL
METHOD
SW846 8041
SW846 8270C
PREPARATION
METHOD
SW846 3520C
SW846 3520C
SW846 11 Test Methods for Evaluating Solid Waste, Physical/Chemical
Methods", Third Edition, November 1986 and its updates .
SAMPLE SUMMARY
COIU70218
WO# SAMPLE# CLIENT SAMPLE ID DATE
DDASM 001 SYSEFF/SV305 05/15/00 13: 55
NOTE (S):
• The mmlyticul results of lhe samples listed above are presented on the following p11ges.
-All cnlculutions 11re performed before rounding to avoid round-off cno11:1 in calcul11ted results.
-Results noteJ rui "ND" were not detected ot or above the atuted limit.
-This report must not be reprcxluced, except in full, without the wri1ten upprovnl of the laboratory.
-Results for the following pnmmcters nre never reported on u dry weight hll.!lis: color, corrosivity, density, 0!1.'lhpoint, ignit.llbility, lnycrs, odor,
point filter test, pH, porosity pressure, reactivity, redox potenti11J, specific grnvity, spot tests, solids, solubility, tempernturc, viscosity, lllld weight .
•
•
Chain of a,3
Custody Record
QUA 412~ 0797
A
C/ie~"tl-.)...,'(\IV\() ~ qdress
\\-... ,,~ In \\,, (_(j
C,ty -~ Co,v.c,r,·
I
A~
State
Y\t\
Pr~tName \ C<, 0 ,. -, -,,, o .Oa~'--
Contrac'./Purchase Order/Quote No. .
Sample I.D. No. and Description
f'.t,
Zip Code
1')t 1 --i Z-
(Containers tor each sample may be combined on one line) Date
Sy5Ei:r=/Sv -Jor ~i, s-la,,
Possible Hazard Identification
•
'
Project Maker '.
1'f-r,,_ 'r, A IO ~ TektFwn'/~'et:7 Number
Sit&-eontact La.b Contact
' caz/Wati/1::1 \. . 'i
IV' 0 11 Z-7ZJ >!J
Containers & Matrix! Preservatives ,0 ...... ' r--':}. ' l " ~ G ~ X oX ~ Time 1 ti ~} ~ ~ " G ~G • ,, ~ ~~ ' ~ X X
ns-, ·{ ~-X -\
'·
i
'
'
' '
;
0 Non-Hazard 0 Flammable D Skin Irritant 0 PoisonB
I Sample Disposal
0 Unknown D Return To C/it D Disposal By Lab D Archive For
Turn Around Time Required QC Require e s (Specify)
D 24 Hours D 4§.Hours D 70ays □ 14 Days 0 21 Days 0 Other. r-----.. -I I
1. RellflquishedB: ( JI, J-1-. -.jfJ
1ffii ,1....1....___. -A 1°•~7 :(1 5/J; OD 17°</;; r Received ~ j)J L I
\ 'tfV\..,7 "" 2. Relinquished By
1
Dale
1
Time 2. t1eceived By
3. Relinquished By
1
Date
1
TTme 3. Received By
Comments
JISTRIBUTfON: WHITE -Stays with the Sample; CANARY -Returned lo Client with Report; PINK -Field Cc:v
Date
IJ~,· v,euanterra •
c;-,/')~03
Chain of Custody Numbb 7 2 £.1. 6
Lab Number l Page t of ~
Analysis (Attach liS. if
more s ace is neered)
Special Instructions/
Conditions of Receipt
.
·:
Months
(A /ee may be-assessed if samples are retained
linger than 3 months)
/
\ VJ? /4J Ir// V>
,'f'". ( \ Time
I Date
1
Time
.THERMORETEC
Client Sample ID: SYSEFF/SV305
GC/MS Semivolatiles • Lot-Sample # ... : C0E170218-001 Work Order # ... : DDA8M101 Matrix ......... : WATER
Date Sampled ... : 05/15/00 Date Received .. : 05/17/00 MS Run# ....... :
Prep Date ...... : 05/20/00 Analysis Date .. : 05/23/00
Prep Batch # ... : 0141132
Dilution Factor: 1 Method ......... : SW846 8270C
REPORTING
PARAMETER RESULT LIMIT UNITS
2,4·Dichlorophenol ND 10 ug/L
Phenol ND 10 ug/L
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Phenol-d5 62 (10 113)
2·Fluorobiphenyl 54 (30 110)
Nitrobenzene-dS 60 (32 112)
Terphenyl·d14 79 (10 144)
2·Fluorophenol 55 (13 110)
2,4,6-Tribromophenol 64 (21 122)
•
•
•
THERMORHTEC
C1ient Samp1e ID: SYSEFF/SV305
Lot-Samp1e # ... : COE170218-001
Date Samp1ed ... : 05/15/00
Prep Date ...... : 05/18/00
Prep Batch# ... : 0140310
Dilution Factor: 1
PARAMETER
Pentachlorophenol
SURROGATE
2,4-Dibromophenol
GC Semivo1ati1es
Work Order# ... : DDA8M102
Date Received .. : 05/17/00
Ana1ysis Date .. : 05/22/00
Method ...... , .. : SW846 8041
REPORTING
RESULT LIMIT
ND 2.0
PERCENT RECOVERY
RECOVERY LIMITS
76 (31 -134)
Matrix _________ : WATER
MS Run# ....... :
UNITS
ug/L
•
•
METHOD BLANK REPORT
GC/MS Semivolatiles
Client Lot# ... : C0E170218 Work Order# ... : DDGQ3101
MB Lot-Sample#: C0E200000-132
Analysis Date .. : 05/23/00
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Phenol
SURROGATE
Phenol-d5
2-Fluorobiphenyl
Nitrobenzene-dS
Terphenyl -dl4
2-Fluorophenol
2,4,6-Tribromophenol
NOTE (S) :
Prep Date ...... : 05/20/00
Prep Batch# ... : 0141132
REPORTING
RESULT LIMIT
ND 10
ND 10
PERCENT RECOVERY
RECOVERY LIMITS
67 (10 113)
59 (30 110)
66 (32 112)
80 (10 144)
60 (13 110)
68 (21 122)
Calcul11tions ure perfonned before rounding to avoid round-off errors in cnlculo.ted results .
Matrix ......... : WATER
UNITS METHOD
ug/L SW846 8270C
ug/L SW846 8270C
•
•
•
METHOD BLANK REPORT
GC Semivolatiles
Client Lot# ... : C0E170218 Work Order# ... : DDF85101
MB Lot-Sample#: C0E190000-310
Prep Date ...... : 05/18/00
Analysis Date .. : 05/23/00
Dilution Factor: 1
Prep Batch# ... : 0140310
REPORTING
PARAMETER RESULT LIMIT
Pentachlorophenol ND 2.0
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
2,4-Dibromophenol 73 (31 -134)
NOTE (S) :
Cnlculntiol!.ll ure performed before rounding to avoid round-off crroni in calculatod results .
UNITS
ug/L
Matrix ......... : WATER
METHOD
SW846 8041
LABORATORY CONTROL SAMPLE K\11\LOATION REPORT
• GC/MS Semivolatiles
Client Lot# ... : COE170218 Work Order# ... : DDGQ3102-LCS Matrix .. _ ...... : WATER
LCS Lot-Sauq,le#: COE200000-132 DDGQ3103-LCSD
Prep Date ...... : 05/20/00 Analysis Date .. : 05/23/00
Prep Batch# ... : 0141132
Dilution Factor: 1
PERCENT RECOVERY RPD
PARAMETER RECOVERY LIMITS RPD LIMITS METHOD
2-Clllorophenol 65 (19 -124) SW846 8270C
69 (19 -124) 5.8 (0-43) SW846 8270C
1,4-Dichlorobenzene 60 (28 -110) SW846 8270C
64 (28 -110) 5.5 (0-36) SW846 8270C
N-Nitrosodi-n-propyl-71 (30 -115) SW846 8270C
amine
75 (30 -115) 6.0 (0-36) SW846 8270C
1,2,4-Trichlorobenzene 59 (31 -110) SW846 8270C
65 (31 -110) 9.0 (0-37) SW846 8270C
4-Cllloro-3-methylphenol 69 (29 -124) SW846 8270C
74 (29 -124) 8.2 (0-55) SW846 8270C
Acenaphthene 71 (39 -118) SW846 8270C
77 (39 -118) 7.6 (0-35) SW846 8270C
4-Nitrophenol 71 (19 -144) SW846 8270C
79 (19 -144) 10 (0-34) SW846 8270C • 2,4-Dinitrotoluene 77 (47 -131) SW846 8270C
83 (47 -131) 7.5 (0-32) SW846 8270C
Pentachlorophenol 71 (10 -140) SW846 8270C
76 (10 -140) 6.7 (0-56) SW846 8270C
Pyrene 87 (46 -130) SW846 8270C
94 (46 -130) 7.9 (0-31) SW846 8270C
Phenol 61 (10 -131) SW846 8270C
64 (10 -131) 6.2 (0-43) SW846 8270C
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Phenol-as 66 (10 113)
69 (10 113)
2-Fluorobiphenyl 58 (30 110)
61 (30 110)
Nitrobenzene-dS 64 (32 112)
68 (32 112)
TerPhenyl-d14 79 (10 144)
84 (10 144)
2-Fluorophenol 58 (13 110)
61 (13 -110)
2,4,6-Tribromophenol 72 (21 122)
75 (21 122)
NOTB (S) : • Calculations nre perfonned before rounding lo avoid round-off erroni in calculated results .
Bold print denolel! control parameters
•
•
LABORATORY CONTROL SAMPLE EVALUATION REPORT
GC Semivolatiles
Client Lot# ... : C0E170218 Work Order# ... : DDF85102·LCS
DDF85103-LCSD
Analysis Date .. : 05/23/00
Matrix ......... : WATER
LCS Lot-Sample#: C0E190000-310
Prep Date ...... : 05/18/00
Prep Batch# ... : 0140310
Dilution Factor: 1
PERCENT RECOVERY
PARAMETER RECOVERY LIMITS
Pentachlorophenol 80 (50 -126)
80 (50 -126)
PERCENT
SURROGATE RECOVERY
2,4-Dibromophenol 72
71
NOTE (S):
Calculations nre performed before rounding to avoid round•off erron1 in cnlculnted results.
Bold print denotes control p1muneters
RPD
RPD LIMITS METHOD
SW846 8041
0.34 (0-20) SW846 8041
RECOVERY
LIMITS
(31 134)
(31 -134)
•
•
•
ANALYTICAL REPORT
PROJECT NO_ RALRIGH
Raleigh-Bi-Weekly NPDES
Lot#: COF020171
Debbi Leuteritz
ThermoRetec
SEVERN TRENT LIIBORllTORillS, INC.
~
veronica Bortot
Project Manager
June 8, 2000
-'
S~VERN
Sl.tiiSSS "'TJPJT.._
STL Pittsburgh
450 William Pitt Way
Pittsburgh, PA t 5238
Tel [phone]
Fax [phone]
www.stl4 inc.com
•
Sample Receiving:
CASE NARRATIVE
THERMORETEC CORPORATION
Raleigh
STL Lot # C0F020 l 7 l
STL Pittsburgh, PA received one sample on June 2, 2000 in good condition and at the
proper temperature.
GC/MS Semivolatiles:
There were no problems associated with the analysis.
GC Phenols:
There were no problems associated with the analysis.
•
•
•
METHODS SUMMARY
COF020171
PARAMETER
Phenols by GC
Semivolatile Organic Compounds by GC/MS
References:
ANALYTICAL
METHOD
SW846 8041
SW846 8270C
PREPAR.Z.TION
METHOD
SW846 3520C
SW846 3520C
SW846 11Test Methods for Evaluating Solid Waste, Physical/Chemical
Methods", Third Edition, November 1986 and its updates .
•
SAMPLE SUMMARY
COF020171
~ SAMPLEI/ CLIENT SAMPLE ID
DE41R 001 EFF SV-305
NOTR (S) :
• The un11Jyticul results of tho samplea llitod 11bovc nro presented on the following p11g~.
• All cnlculntioll!'I ure performed before rounding to nvoid round-off errors in cnlculnted mul!J: .
• Resu!L, notcJ 11!1 "ND" were not detected nt or above tho stnc.ed !unit,
• Thi, report mwt not bo reproduced, except in full, without the written npprovol of tl1e !aborntory.
• Result.s for the following pcnuncters ore never reported on n dry weight bui.1: color, corrosivity. density, fl!l..ihpoint, ignitability, la.yera, odor,
pnint filter test, pH, porosity pre.uurc, reactivity, rcdox potcntilll. specific gruvity, spot testJ, solids, solubility, temperature, viscosity, o.nd weight.
DATE
05/31/00 18:30
-· Chain of
L!)"\ • "1.feUanterra
Custody Record
UA-4124 ·.•
Client .. Project Managet ' ' Date _ /2 /n r, ~hainof.CuS1.00yNumb5 7 2_4 8 Tf I;_~ -7-, .,,,
·~.
(· •'i'" ,,,,A I? ~,,,b.-? .. >f'. S:, ZI , ' .. ;
a 01s1
Address ..... : !87crhone Number (Area Cor;Je)JFax Number SI'," Lab Number
( 0 0 /? .LJ /.,-£:;?' Ar/C-~';,~rE •',..,, 'J9.} 7..-, I -I' ') 7 . .
;,2.:-Page I of \ .,.
Cfty State J I Zip Code SitilContaCt Lab Contact · Analysis (Attc:ich list if
C_(\A.JCo4LJ /1);q oo<n . more soace is needed
Project Name
. /..-,,;_ 1 £'/(!; LI
Carrier/Naybifl Nv_m~er -~
I< €'A 2.,£,? Ai nn n r.--r 7L' _,,,-, ,,.,, ,ll'_c -Special /nstructionSJ
Cantract!Purchase Order/Quote No. Containeis & .. Conditions of Receipt
Matrix Preseivatives ;..._ { c>-
SafTlpte I.D. No. and Description i l c ~ "' l~ ~ ~ pate Time l " ~ ~ 13 0
(Containers for each sainpfe inay be combined on one line) • 'i' ~ ;.;; < ~ "'
£.-=: n, --,,..... c--5/2,loo l3''10 ) I\ "j \' .
,7 . ' /
. ..
. -~.-
.. '' ..
' . .
"
.
Possible Hazard Identification . l Sampl~ Disposal• I (A lee may be assessed if samples are retained
D Non-Hazard D Flammable 0 Skin Irritant D PoisonB 0 Unknown O Retum To Cfie,nt □ Disposal By Lab D A/chive For Months . longer than 3 months)
Turn AroOnd Time Required ,i . QC Requirem('l.(Spe.cify) . I , '\. . ··,;. □ other '' I D 24Hours D 48Hours □ 7Days □ 14Da}'S □ 21 Days : I ' / ! . .
· 1. Relinquished By _ ,, f (·'i.1._ (;m:70 1. Received ') J\ I ... I ~·t1 / rv ) i77•, l/.!> . · . ./. .,£/-• .,...._ ( r------_ . _;., .r·
2. Relt,JPnshedt!}I .f' . ,Date •
1
Time 2. Receiv';:) '\_ • I°'.· 1
r,,,,.
~
3. Refinquishe~ By . !Date
1
Tfme 3._ Received By . (~le
1
Time
Comments
D/STRIBUTTON: .WHITE -Sta}'$ with the Sample; CANARY -Returned to Client with Repon; PINK -Field C9py
THERl!!ORBTllC CORP
Client Sample ID: EFF SV-305 • GC./r!iS Semivolatiles
Lot-Sample ll ... : COF020171-001 Work Order# ... : DE41Rl01 Matrix ......... : WATER
Date Sampled ... : 05/31/00 Date Received .. : 06/02/00 MS Run It •..•.•• :
Prep Date ...... : 06/05/00 Analysis Date .. : 06/07/00
Prep Batch # ••. : 0157340
Dilution Factor: 1 Method ......... : SW846 8270C
REPORTING
PARAMETER RESULT LIMIT UNITS
2,4-Dichlorophenol ND 10 ug/L
Phenol ND 10 ug/L
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Phenol-dS 58 (10 113)
2·Fluorobiphenyl 57 (30 110)
Nitrobenzene-d5 60 (32 112)
Terphenyl-dl4 84 (10 144)
2-Fluorophenol 52 (13 110)
2,4,6-Tribromophenol 65 (21 122)
THllRMORRTEC CORI'
Client Sample ID: EFF SV-305 • CC Sem1v-olatiles
Lot-Sample # .•. ' COF020171-001 Work Order# ... : DE41Rl02 Matrix ......... : WATER
Date Sampled ... : 05/31/00 Date Received .. : 06/02/00 MS Run# ....... :
Prep Date ...... : 06/05/00 Analysis Date .. : 06/08/00
Prep Batch# ... : 0157356
Dilution Factor: 1 Method ......... : SW846 8041
REPORTING
PARAMETER RESULT LIMIT UNITS
Pentachlorophenol ND 2.0 ug/L
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
2,4-Dibromophenol 87 (31 -134)
•
•
•
METHOD BLANK REPORT
GC/MS Sem.ivolatiles
Client Lot IL .. : COF0201 71 Work Order IL .. : DE6RM101
MB Lot-Sample#: COFOS0000-340
Prep Date ______ : 06/05/00
Aoalysis Date .. : 06/07/00
Dilution Factor: 1
Prep Batch# .•. : 0157340
PARAMETER
2,4-Dichlorophenol
Phenol
SURROGATE
Phenol-d5
2-Fluorobiphenyl
Nitrobenzene-d5
Terphenyl-di4
2-Fluorophenol
2,4,6-Tribromophenol
NarE (S) :
RESULT
ND
ND
PERCENT
RECOVERY
72
63
72
87
64
69
Cnlcuilltioru ttre performed before rounding lo nvoid round-off errors in cnlcu!11ted ruu!t'I .
REPORTING
LIMIT
10
10
RECOVERY
LIMITS
(10 113)
(30 110)
(32 112)
(10 144)
(13 110)
(21 122)
UNITS
ug/L
ug/L
Matrix ......... : WATER
METHOD
SW846 8270C
SW846 8270C
•
•
•
Client Lot# ... , C0F020171
MB Lot-Sample#, C0F0S0000-356
.Analysis Date .. , 06/08/00
Dilution Factor: 1
PARAMETER
Pentachlorophenol
SURROGATE
2,4-Dibromophenol
NOTE (S),
METHOD BLANK REPORT
GC Semivolatiles
work Order# ... , DE6TF101
Prep Date ...... , 06/05/00
Prep Batch# ... , 0157356
REPORTING
RESULT LIMIT
ND 2.0
PERCENT RECOVERY
RECOVERY LIMITS
88 (31 -134)
Cnkulnlions 1ue performed before rounding to nvoid round-off error, in cukulated results .
Matrix ......... : WATER
UNITS METHOD
ug/L SW846 8041
•
•
•
LABORATORY CONTROL SAMPLB ITTIALIJATION REPORT
GC/MS Semivolatiles
Client Lot# ... : COF020171 Work Order# ... : DE6RM102-LCS Matrix ......... : WATER
LCS Lot-Sanq>le#: COF050000-340 DE6RM103-LCSD
Prep Date ...... : 06/05/00 Analysis Date .. : 06/07/00
Prep Batch # ... : 0157340
Di1ution Factor: 1
PERCENT RECOVERY RPD
PARAMETER RECOVERY LIMITS RPO LIMITS
2-Clllorophenol 67 (19 -124)
65 (19 -124) 3.4 (0-43)
1,4-Dichlorobenzene 67 (28 -110)
66 (28 -110) 2.4 (0-36)
N-Nitrosodi-n-prapyl-62 (30 -115)
amine
59 (30 -115) 5.6 (0-36)
1,2,4-Trichlorobenzene 66 (31 110)
66 (31 -110) 0.0 (0-37)
4-Chloro-3-methylphenol 68 (29 -124)
66 (29 -124) 2.6 (0-55)
Acenaphthene 76 (39 -118)
74 (39 -118) 2.4 (0-35)
4-Nitrophenol 76 (19 -144)
72 (19 -144) 5.6 (0-34)
2,4-Dinitrotoluene 81 (47 -131)
79 (47 -131) 3.0 (0-32)
Pentachlorophenol 78 (10 -140)
78 (10 -140) 0.34 (0-56)
Pyreoe 94 (46 -130)
94 (46 -130) 0.42 (0-31)
Phenol 64 (10 -131)
61 (10 -131) 4.7 (0-43)
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Phenol-d5 71 (10 113)
66 (10 113)
2-Fluorobiphenyl 67 (30 llO)
65 (30 110)
Nitrobenzene-dS 71 (32 112)
69 (32 112)
Terphenyl-dl4 94 (10 144)
n (10 H4)
2-Fluorophenol 64 (13 110)
59 (13 110)
2,4,6-Tribromophenol 76 (21 122)
75 (21 122)
NOTE (SJ :
C11lcu\11tioIU ru:c-; performed bcforo rounding to ttvoid round-off errore in ct1kul111cd r=lta.
Bold print d~note5 control panunctc111
METHOD
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
SW846 8270C
•
•
LIIBORATORY CONTROL SAMPLE HVALUATION REPORT
GC Semivolatiles
Client Lot lk .. : C0F020171 Work Order# ... : DE6TF102·LCS
DE6TF103-LCSD
Analysis Date .. : 06/08/00
Matrix ......... : WATER
LCS Lot-Sample#: C0F050000·356
Prep Date ...... : 06/05/00
Prep Batch# ... : 0157356
Dilution Factor: 1
PERCENT RECOVERY
PARAMETER RECOVERY LIMITS
Pentachlorophenol 99 (50 -126)
102 (SO -126)
PERCENT
SURROGATE RECOVERY
2,4-Dibromophenol 78
78
NOTE (S):
Cnlculntioru llJO performed before rounding to nvoid round-off errors Ul ca.[culc,ted resuJtJ.
Bold print denotes conlfol po.nuneter1
RPD
RPD LIMITS METHOD
SW846 8041
3.1 (0-20) SW846 8041
RECOVERY
LIMITS
(31 134)
(31 -134)
JA.MES 8. HUNT JR. •
GOVERNOR
BILL HOLMAN
SECRE::TARY
•.. . .
... -'=· .. ;.J
.•• ·-" ~-.e..'ii.--..,.
NORTH CAROLINA DEPARTMENT OF
ENVIRONMENT AND NATURAL RESOURCES
Ms. Beverly Hudson
Remedial Project Manager
Superfund Branch
Waste Management Division
April 20, 2000
United States Environmental Protection Agency
Region IV
6 I Forsyth Street, l l'h Floor
Atlanta, GA 30303
Re: Monthly Progress Report #83 (March)
Koppers Company NPL Site
Morrisville, Wake County
Dear Ms. Hudson:
DIVISION OF WASTE MANAGEMENT
The Superfund Section of the North Carolina Department of Environment and Natural Resources (NC DENR) has received Monthly Progress Report #83
(March) for the Koppers Company National Priorities List (NPL) Site .. The
Superfund Section has reviewed this document and offers the following
comments.
Monthly Progress Report #83 -March 2000
I. Table I indicates that the water sample collected between the carbon units
on February 18, 2000 was analyzed for 2,4-dichlorophenol and phenol.
However, Table 2 indicates that the water sample collected between the
carbon units on February 18, 2000 was analyzed for pentachlorophenol,
2,4-dichlorophenol and phenol. Please clarify this discrepancy.
Additionally, please revise the notes for Table 1 to indicate that pheriol is
included as Associated Group # I.
2. Please clarify if the Table 2 heading, Analytical Sample Location SV-102,
should actually be Analytical Sample Location SV-101 as reflected in the Table 2 Notes and in Table I.
&JD ••·••·• 1646 MAIL SERVICE CENTER, RALEIGH, NORTH CAROLINA 27699-1646
401 OBERLIN ROAD, SUITE 150, RALEIGH, NC 27605
PHONE 9 I 9•733-4996 FAX [phone] AN EQUAL OPPORTUNITY/ AFFIRMATIVE ACTION EMPLOYER• 50% RECYCLE0/10% POST•CONSUMER PAPER
•
•
•
Ms. Beverly Hudson
April 20, 2000
Page 2
3. In November 1999, the facility significantly failed its toxicity test (complete organism
mortality and no reproduction). The December 1999 and January 2000 toxicity tests had complete survival with treatment organism reproduction essentially the same as the control organisms. Table 2 indicates that the groundwater treatment system effluent
passed the chronic toxicity test. In the body of the report there was no explanation or response to the toxicity described. Please detail any activities that were undertaken to correct the effluent quality. Please detail whether provisions stipulated in the Toxicity
Reduction Evaluation Work Plan were implemented. Additionally, please provide
responses to the regulatory comments issued July 1999 through April 2000.
We appreciate the opportunity to comment on this document. If you have any questions, please feel free to call me at [phone], extension 349.
cc:
Sincerely,
David B. Mattison, CHMM
Environmental Engineer
Superfund Section
Judy Garrett, NC Div. of Water Quality
Matt Matthews, NC Div. of Water Quality
Mike Slenska, Beazer East, Inc .
•
•
•
April 7, 2000
Ms. Beverly Hudson
Remedial Project Manager
U.S. EPA -Region IV, 11 '" Floor
North Site Management Branch
61 Forsyth Street, SW
Atlanta, GA 30303
RE: Monthly Progress Report #83
Remedial Action
Koppers Site -Morrisville, NC
Dear Ms. Hudson:
ThermoRetec Corporation
9 Damonmill Square, Suite 3A
Concord, MA 01742-2851
.ThermoRetec
Smart Solutions. Positive Outcomes.
RECEl¥fi:@1,22 Phone
[phone] Fax
APR 1 0 2odo'mo,eteccom
SUPERFUND SECTION ;
In accordance with the Unilateral Order, and on behalf of Beazer East, Inc. (Beazer), please find
attached four ( 4) copies of the Monthly Progress Report for the period ending March 3 I, 2000
for the Remedial Action for Koppers Superfund Site, Morrisville, NC.
Should you need additional information regarding this progress report, please call Mike Slenska
at [phone] or me at [phone].
Sincerely,
ThermoRetec Consulting Corporation
$L 4-<1;,'!/ /~1;~£,
Rita Bauer
Project Geologist
rb:jrc
Enclosure
,r-......._ -------,
cc: (£). Mattison/ NC Supcrfund (2 copies)
D. Hails -Ecological Restoration, Inc.
). Garrett -NC Division of Water Quality
M. Matthews -NC Division of Water Quality
F :\PRO I ECTS\03 62 4\CO RRES\2000\H uds040 7. wpd
M. Slenska -Beazer
L. Faulconer -Wake County
G. Caskey -Enwood Structures
A subsidiary of Thermo Terra Tech Inc.,
•
•
MONTHLY PROGRESS REPORT #83
REMEDIAL ACTION
SITE NAME: Koppers Superfund Site
Beazer East, Inc.
Morrisville, NC
USEPADOCKETNUMBERS: 9~0~C
PERIOD ENDING: March 31, 2000
1. PROGRESS MADE THIS MONTH
2.
3.
4.
5.
6.
7.
Remedial Action (RA) -HABITAT MIT/GA TION. No activities were conducted this
month.
Remedial Action (RA) -GROUNDWATER TREATMENT. The treatment system
operated throughout the month without upset. System performance was monitored
on a biweekly basis. Approximately 70,476 gallons of groundwater were extracted,
treated in the treatment plant and discharged between March 1 and March 31,
2000. System water samples were collected on March 3, 2000 and March 13, 2000
in accordance with the sampling schedule in the O&M manual. Samples were
submitted to Quanterra Incorporated for laboratory analysis. The operations and
sampling programs are summarized on the attached Table 1.
Remedial Action (RA)-EFFECTIVENESS MONITORING PROGRAM. No activities
were conducted this month.
Remedial Action (RA) -CORRESPONDENCE. None.
PROBLEMS RESOLVED None.
PROBLEMS ANTICIPATED None.
UPCOMING EVENTS Continue System O&M.
PERSONNEL CHANGES None.
SUBCONTRACTORS None.
ANAL YT I CAL DAT A Analytical data from system influent and effluent sampling
received during this period are enclosed and are summarized on Table 2 .
F, IP R OJ ECTSIO 3 62 4 IC O RRES\2 000\H uds040 7. wpd
•
•
MONTHLY PROGRESS REPORT #83
REMEDIAL ACTION
SITE NAME: Koppers Superfund Site
Beazer East, Inc.
Morrisville, NC
USEPA DOCKET NUMBERS: 93-09-C
PERIOD ENDING: March 31, 2000
1. PROGRESS MADE THIS MONTH
2.
3.
4.
5.
6.
7.
Remedial Action (RA) -HABITAT MIT/GA T/ON. No activities were conducted this
month.
Remedial Action (RA) -GROUNDWATER TREATMENT. The treatment system
operated throughout the month without upset. System performance was monitored
on a biweekly basis. Approximately 70,476 gallons of groundwater were extracted,
treated in the treatment plant and discharged between March 1 and March 31, 2000.
System water samples were collected on March 3, 2000 and March 13, 2000 in
accordance with the sampling schedule in the O&M manual. Samples were
submitted to Quanterra Incorporated for laboratory analysis. The operations and
sampling programs are summarized on the attached Table 1.
Remedial Action (RA) -EFFECTIVENESS MONITORING PROGRAM. No activities
were conducted this month.
Remedial Action (RA) -CORRESPONDENCE. None.
PROBLEMS RESOLVED
PROBLEMS ANTICIPATED
UPCOMING EVENTS
PERSONNEL CHANGES
SUBCONTRACTORS
None.
None.
Continue System O&M.
None.
None.
ANALYTICAL DATA Analytical data from system influent and effluent sampling
received during this period are enclosed and are summarized on Table 2 .
F: \ US ERS\NGI I Al\lkazer\Raleigh\momhly _ 83. w1xl
•
Date Systems Check Cummulative
(yes/no) Effluent Flow
(Gallons)
0!/04/00 ves 2.178.450
01/20/00 ves 2.201.060
02102100 ves 2.223.670
02/ I 8/00 ws 2.243 495
0J/03/00 ves 2,278,733
03/13/00 ves 2,313,971
Notes:
S\'-101 -Before Carbon Units (preireacmem)
*SV-304 -Between Carbon Units
SV-101
Sample
(ves/no)
nn
no
no
no
no
no
**SV-:105 -After Carbons Units (post-treatment)
•
Table I
Groundwater Treatment Operations and Sampling Program Summary
Koppers Superfund Site
Morrisville, North Carolina
March 2000
SV-101 Associated :}V-304* SV-304 Associated
Sample Group Sample Sample Group
Parameters (ves/no) Parameters
no
no
no
ves 2,4-Dichloro, Phenol I
no
no
Associated Groups:
SV-305""
Sampl,._.
(ves/no)
ves
ves
ves
ves
yes
ves
SV-JOJ -Group I is penta and 2,4-dichlorophenol: Group 2 is dioxins
SV-304 -Group 3 is penta and 2,4-dichlorophenol
SV-305
Sampk
Parameters
Pema. 2.4-Dichloro. & Phenol, & tox
Penta. 2.4-Dichloro, Phenol
Penta. 2.4-Dichloro. Phenol, & tox
Penta. 2.4-Dich!oro, Phenol.& dio.\in
Penta. 2.4-Dichloro, Phenol
Penta . .2.4-Dichloro, Phenol
SV-305 -Group I is penta and 2,4-dich!orophenol: Group2 is dioxins and Group 4 is toxicity
Associated
Group
1.4
I
1.4
1.2
I
I
•
•
Parameter
Pe1\lach l11rophem>l
2.4-Dichlorophenol
Phenol
Chronic Toxicity
Dioxin (2.3. 7.8-TCDD)
Table 2
Groundwater Treatment
ANALYTICAL DATA SUMMARY
Koppers Superfund Site
Morrisville. Nonh Carolina
March 2000
Ana1yt1c;11
Date Sample
Sample Location
Colkc1ed SV-102
0 [ 10-1/00
0[/20100
02102100
021[ 8100
03103100
031 [ 3100
0110-1/00
01/20100
02/02100
021[ 8100
0:1103100
031 I 3100
0 I 104100
0 I 120100
02/02100
02/ 18100
0:1103100
031[3/00
01104/00
02101100
02/ 18/00
Sample
Location
SV-304*
<2
< 10
< 10
Notes: All results are in ug/L except dioxin. Dioxin data is in picograms/L.
SV-lOJ -Before Carhon Uni1s
*SV-304 -Between Carbon Units
"*SV-305 -After Carhon Units
Sample
Location
SV-305**
<2
<2
<2
<2
<2
<2
< 10
< 10
<IO
<IO
< 10
< 10
< 10
< 10
< lO
<10
< 10
< 10
Pass
Pass
< 1.2
Quanterra
450 iVifliam Pitt \½1v
Pittsburgh, Pe1111syl1N;nia J 5238-1330
4 I 2 820-8380 Telephone
4 I 2 820-2080 Fm
•
•
ANALYTICAL REPORT
PROJECT NO. RALEIGH
Raleigh-Bi-Weekly NPDES
Lot#: C0C040143
Debbi Leuteritz
'I11ermoRetec
QIDINTERRA INCORPORATED
Veronica Bortot
Project Manager
March 10, 2000
(}puanterra
•
•
•
CASE NARRATIVE
THERMORECTEC CORPORATION
SITE:
RALEIGH BI-WEEKLY NPDES
Quantcrra Lot No. COC040143
SHIPMENT:
lfn}\ ~uanlterra
Sample was received at Quantcrra-Pittsburgh, PA on March 4, 2000 in good condition
and at proper temperature. The sample was anal yzcd for the parameters as directed on the
chain of custody and HARP Form.
NOTE:
Except where noted, no problems were observed during the analyses,
SAMPLE SUMMARY
COC040143
!'.!.Q__jL_ SAMPLE# CLIENT SAMPLE ID
D99DQ 001 EFF. SV-305
NOTE (S) :
-The anrdytieul r~1ults of the samples listed ubove nre presented on the following pugcs.
-A!l cnlculntions nre perfonned before rounding to avoid round-off errors in rnlculnted result~.
-Results noted us 'ND" were not dckctOO Ill or above the stated limit.
-1l1i~ repo11 must not be reproduce.:!, except in full, without the wriuen 11pprovnl of the lnborntory.
~}\ ~uanterra
DATE
03/03/00 09:50
-Result~ for the following pnn:uneters are never reported on II d1y weight bllSis: color, corrosivity, density, flnshpoint, ignitnbility, layers, odor,
paint tilter test, pH, porosity pressure, reactivity, red ox potentiul, specific gravity, spot tests, !olids, solubility, tempernture, viscosity, and weight .
•
•
0
•
•
METHODS SUMMARY #}}\ ~uanterra
COC040l43
PARAMETER
Phenols by GC
Semivolatile Organic Compounds by GC/MS
References:
ANALYTICAL
METHOD
SW846 8041
SW846 8270C
PREPARATION
METHOD
SW846 3520C
SW846 3520C
SW846 11 Test Methods for Evaluating Solid Waste, Physical/Chemical
Methods 11 , Third Edition, November 1986 and its updates .
THBRMORIITEC
Client Sample ID: EFF. SV-305
II}}\ ~uanterra
0
Lot-Sample# ... : COC040l43-00l
Date Sampled ... : 03/03/00
Prep Date ...... : 03/06/00
Prep Batch# ... : 0067103
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Phenol
SURROGATE
Phenol·d5
2-Fluorobiphenyl
Nitrobenzene-d5
Terphenyl-dl4
2-Fluorophenol
2,4,6-Tribrorn?phenol
•
•
GC/MS Semivolatiles
Work Order# ... : D99DQ101
Date Received .. : 03/04/00
Analysis Date .. : 03/08/00
Matrix ......... : WATER
MS Run# ....... :
Method ......... : SW84 6 82 70C
REPORTING
RESULT LIMIT UNITS
ND 10 ug/L
ND 10 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
58 (10 113)
53 (30 110)
54 (32 112)
89 (10 144)
43 (13 110)
89 (21 122)
THRRMORETEC
Client Sample ID: EFF. SV-305
Lot-Sample# ... : COC040143-001
Date Sampled ... : 03/03/00
Prep Date ...... : 03/06/00
Prep Batch# ... : 0067102
Dilution Factor: 1
PARAMETER
Pentachlorophenol
SURROGATE
2,4-Dibromophenol
•
•
GC Semivolatiles
Work Order# ... : D99DQ102
Date Received .. : 03/04/00
Analysis Date .. : 03/08/00
Method ... -.. -.. : SW846 8041
REPORTING
RESULT LIMIT
ND 2.0
PERCENT RECOVERY
RECOVERY LIMITS
104 (31 -134)
.,.
lfn~\ ~uanterra
Matrix ......... : WATER
MS Run# ....... :
UNITS
ug/L
METHOD BLANK REPORT • GC/MS Semivolatiles
Client Lot# ... : COC040143 Work Order# ... : D9ADG101
MB Lot-Sample#: COC070000·103
Analysis Date .. : 03/08/00
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Phenol
SURROGATE
Phenol-dS
2-Fluorobiphenyl
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorophenol
2,4,6-Tribromophenol
NOTE (S) :
Prep Date ...... : 03/06/00
Prep Batch# ... : 0067103
REPORTING
RESULT LIMIT
ND 10
ND 10
PERCENT RECOVERY
RECOVERY LIMITS
68 (10 113)
66 (30 110)
64 (32 112)
85 (10 144)
53 (13 110)
85 (21 122)
Cnlculntions nre performed before rounding to ovoid round-off errora in cnlculnted results . •
•
•
UNITS
ug/L
ug/L
4}}\ ~uanterra
Matrix ......... : WATER
METHOD
SW846 8270<;:
SW846 8270C
METHOD BLANK REPORT
GC Semivolatiles
Client Lot# ... : C0C040143 Work Order# ... : D9ADF101
MB Lot-Sample#: C0C070000-102
Analysis Date .. : 03/08/00
Dilution Factor: 1
PARAMETER
Pentachlorophenol
SURROGATE
2,4-Dibrornophenol
NOTE (S) :
Prep Date ...... : 03/06/00
Prep Batch# ... : 0067102
REPORTING
RESULT LIMIT
ND 2.0
PERCENT RECOVERY
RECOVERY LIMITS
105 (31 -134)
Culcul11tions nrc perfonned before rounding to 11void round-off errors in cnlculated results .
•
•
UNITS
ug/L
I})\ ~uanterra
Matrix ......... : WATER
METHOD
SW846 8041;,
•
•
II}~\ ~uanterra
LABORATORY CONTROL SJIMPLR KVALIJATION REPORT
GC Semivolatiles
Client Lot# ... : COC040143 Work Order# ... : D9ADF102·LCS
D9ADF103·LCSD
Analysis Date .. : 03/08/00
Matrix ......... : WATER
LCS Lot-Sample#: COC070000·102
Prep Date ...... : 03/06/00
Prep Batch# ... : 0067102
Dilution Factor: 1
PERCENT RECOVERY
PARAMETER RECOVERY LIMITS
Pentachlorophenol 95 (50 -126)
95 (50 -126)
PERCENT
SURROGATE RECOVERY
2,4-Dibrornophenol 106
106
NOTE {S) :
Culcufation.~ are perfonned before rounding to 11void round-off errors in calculuted re.~ullll.
Bold print <lcnote11 control p11raJneters
RPO
RPO LIMITS METHOD
SW846 80111
0.55 (0-20) SW846 8041
RECOVERY
LIMITS
I 31 134)
(31 . 134)
I}~\ ~uanterra
LABORATORY CTJNTROL SAMPLE EVALUATION REPORT
Client Lot# ... : COC040143
LCS Lot-Sample#: COC070000·103
Prep Date ...... : 03/06/00
Prep Batch# ... : 0067103
Dilution Factor: 1
PARAMETER
2·Chlorophenol
1,4-Dichlorobenzene
N-Nitrosodi-n-propyl-
amine
1,2,4-Trichlorobenzene
4-Chloro-3-methylphenol
Acenaphthene
4-Nitrophenol ••• 2,4-Dinitrotoluene
Pentachlorophenol
Pyrene
Phenol
SURROGATE
Phenol·dS
2·Fluorobiphenyl
Nitrobenzene-dS
Terphenyl·dl4
2 · Fl uorophenol
2,4,6-Tribromophenol
GC/MS Semivolatiles
Work Order# ... : D9ADG102·LCS
D9ADG103·LCSD
Analysis Date .. : 03/08/00
PERCENT RECOVERY
RECOVERY LIMITS RPD
71 (19 -124)
69 (19 -124) 3.7
80 (28 -110)
76 (28 -110) 4.5
79 (30 -115)
77 (30 -115) 2.5
88 (31 -110)
85 (31 -110) 3.4
78 (29 -124)
75 (29 -124) 3.3
94 (39 -118)
89 (39 -118) 5.9
76 (19 -144)
72 (19 -144) 6.1
92 (47 -131)
88 (4 7 -131) 4.9
81 (10 -140)
76 (10 -140) 6.8
89 (46 -130)
85 (46 -130) 4.8
70 (10 -131)
69 (10 -131) 2.0
Matrix ......... : WATER
RPO
LIMITS METHOD
SW846 0270c
(0-43) SW846 8270C
SW846 8270C
(0-36) SW846 8270C
SW846 8270C
(0-36) SW846 8270C
SW846 8270C
(0-37) SW846 8270C
SW846 8270C
(0-55) SW846 8270C
SW846 8270C
(0-35) SW846 8270C
SW846 8270C
(0-34) SW846 8270C
SW846 8270C
(0-32) SW846 8270C
SW846 8270C
(0-56) SW846 8270C
SW846 8270C
(0-31) SW846 8270C
SW846 8270C
(0-43) SW846 8270C
PERCENT RECOVERY
RECOVERY LIMITS
80 (10 113)
77 (10 113)
79 (30 110)
75 (30 110)
73 (32 112)
71 (32 112)
8B (10 144)
B4 (10 144)
62 (13 110)
60 (13 110)
9B (21 122)
95 (21 122)
.NOTE(S):
Culcululions nre performed before !Ounding to avoid round-off crrofl! in cnlculnte<l result~.
Bold print denotes control pnrumcter.i
Chain of
Custody Record
DUA 4124 0797
Client
T7-J,,,-£-vv /) c~-__.. -✓ ') /<.; ;/ -/ ,!-;: .... -c...__ ...
Address
'1 /3 /I A n_/ /i1. I I
City
..
._({7,\_/•t:.:¾-
,,. ,rvVr ,.,P-,,J
I State-I Zip C6de _
mA o;7Y-::J.
Project Name / ~ --I/ &r.ZA;;i.£/4'_ I /'<->'Ji£, I 6, ·
Contract/Purchase Ordef/Ouote No.
f$ample 1.0. No. and Description Date (Containers for each sample may be combined on one line)
;-;;:?: -JV-JO~--,,/,in()
Possible Hazard Identification
Project Manager
l?,r-"\ fl: Au;.-:.-_-, .. ~'/_
Telephone Number (Area Code)/Fax Number tq-c:/ I I . ) 111 --/ if).?..
Sire Contact Lab Contact
Carrier/VVaybi/1 Number ,
'\ ,, 1 ·" r.--ft:--;:. Qq )./ /1, t) Y-;_<,---.r.l,1,.,:,1.,:)_ ... ":::,f'.:L :,, ,-· -,
Containers & ~ Matrix Preservatives i$: ! " ' V, " 0 ' a> & Time ti ~ § V, 0 G 0 ~o I{...'\ • ~ , i ~~ ' ~ , ' r:As-o 'X -x 'I 'X
'
0 Non-Hazard D Flammable 0 Skin lrrilanl D PoisonB
I Sample Disposal
0 Unknown D Return To Client ~isposal By Lab D Archive For
Turn Around Time Reqwred
D 24 Hours O 48 Hours
1. Relinquished By
0 7 Days D 14 Days
2. Relinquished By (./ !/U
3. Relinquished By
Comments
0 21 Days 0 Other
]Date zh/4/) 1
Time
I //:0
1
Date
1
Time
1
Date
1
Time
DISTRIBUT10N !TE -Stays wilh the Sample; CANARY -Returned to Client with Report; PINK -Field Copy
QC Requ,rements (Specify)
1. Received By
2. Received By
I~}" veuanterra
Date I I Chain of Cus/ody Number., _.., 0 Zis//;,7'! I: . ,.. ? -' I...., • .,:
Lab Numb'er
Page { ) of ' Analysis (Attach list if
more soace is needed
Special Instructions/
Conditions of Receipt
(A fee may be assessed if samples are retained
Months longer than 3 months)
1
Date
1
Time
1
Date
1
Time
I~;~~
. ' .. : J 1
Ti7e
8
•
•
---Severn Trent Laboratories
450 William Pitt Way
Pittsburgh, Pennsylvania 15238
Committed to Your Success
Tel: ( 412) 820-8380
Fax: [phone]
ANALYTICAL REPORT
PROJHCT NO_ RALEIGH
Raleigh-Bi-Weekly NPDRS
Lot#: C0C140160
Debbi Leuteritz
ThermoRetec
SRVRRN TRENT LABORATORIES, INC_
Veronica Bortot
Project Manager
March 21, 2000
•
•
•
Sample Receiving:
CASE NARRATIVE
THERMORETEC CORPORATION
Raleigh-Bi-Weekly NPDES
STL Lot# C0CI40160
STL Pittsburgh, PA received samples on March 14, 2000 in good condition and at proper temperature.
GC/MS Semivolatiles:
There were no problems associated with the analysis.
GC Semivolatiles:
There were no problems associated with the analysis .
•
•
METHODS SUMMARY
COC140160
PARAMETER
Phenols by GC
Semivolatile Organic Compounds by GC/MS
References:
ANALYTICAL
METHOD
SW846 8041
SW846 8270C
PREPARATION
METHOD
SW846 3520C
SW846 3520C
SW846 11Test Methods for Evaluating Solid Waste, Physical/Chemical
Methods 11 , Third Edition, November 1986 and its updates .
SAMPLE SUMMARY
COC140160 • WO# SAMPLE# CLIENT SAMPLE ID DATE TIME
D9KVF 001 EFF.SV-305 03/13/00 18:15
NOTE (S):
-TI1e nnalyticul results of the samples listed above n,-e prC8ented on the following pages.
-All culculntio1111 llfC perfonned before rounding to avoid round-off erron in calculated ruults.
-Resultll noted UJl "ND' were not detected at or above the slated limit.
-This report must not be reproduced, except in full, without the written approval of the \aborutory.
-Results for the following parnmeten1 nre never reported on ll dry weight bll!IUI: color, corrosivity, density, flashpoint, ignitnbility, layers, odor,
paint filter test, pH, por03ity pressure, reactivity, redo)( potenti11I, specific gravity, spot tests, solids, solubility, temperature, viscosity, nnd weight .
•
•
Chain of
Custody Record
QUA 4124
Client
T!+_JZ.ma R 01 -z;;c.,,
Address
t21/l10f\) j' m.7Qu4~L City l:;;A z;p c;; </ ;;}_ C"'o,vC-o,,e.,,J Pe~~ IRAt.£1611-
ConrracVPurchase or&er!Ouore No.
Sample I. D. No. and Description Date Time
' ~ sv ?OS--~1/i/C(, /X/J
Soec1a/ lnstruct10ns
Possible Hazard ldentifica/ion
Ouanterra, Inc. -Pittsburgh PA Lab
450 William Pitt Way
Pittsburgh PA 15238
Project Manager
R1rA 6',Avt&e'.-
TA;ot) Nu:/J ;-:a ;;•;,;:_umber
Site Contact
CarrierNvaybi/1 Number #
A-1&o€NC-7gJff) 2. Cj~ 7 /,
Total Containers Sample Type Volume Preserva/Jve Type No.
H20 't t.. " ,,,,,, (/ -
Sample Disposal
0 Non-Hazard O Flammable D Skin lmtant D PoisonB Ounknown 0 Return To Client
Turn Around Time Required DC Level Project Specific (Specify)
□ Normal □ Rush □ I. □ II. □ Ill.
1. Received By
2. Received By
3. Relinquished By Date Time
Comments
DISTRIBUTION: WH, Stays with Sample; CANARY· Re/Urned to Client with Report; PINK· Field Copy
IJ)'\ ~uanterra
't
Date s~s oo
Chain Of Custody Number
Lab Number
Page I
Analysis
Q
i~ " ~ Condition on Receipt ()(
IX y
• I •
0 Disposal By Lab 0 Archive For
Date
Date
Date
J-f -UQ
I
.65 366
of I
!
I
' I
I
I
I
I
I I
I I
_ _I~! __
1
Time
Time
I
I
I
I
I
•
THERMDRKTEC
Client Sample ID: llFF.SV-305
GC/MS Semivolatiles
Lot-Sample# ... : C0C140160·001 Work Order# ... : D9KVF101
Date Received .. : 03/14/00
Analysis Date .. : 03/20/00
Matrix ......... : WATER
Date Sampled ... : 03/13/00 MS Run# ....... :
Prep Date ...... : 03/15/00
Prep Batch# ... : 0076102
Dilution Factor: 1 Method ......... : SW846 8270C
REPORTING
PARAMETER RESULT LIMIT UNITS
2,4-Dichlorophenol ND 10 ug/L
Phenol ND 10 ug/L
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Phenol·dS 80 (10 113)
2-Fluorobiphenyl 72 (30 110)
Nitrobenzene-dS 84 (32 112)
Terphenyl·dl4 92 (10 144)
2-Fluorophenol 73 (13 110)
2,4,6-Tribromophenol 82 (21 122)
•
•
THERMORETEC
C1ient Samp1e ID: EFF.SV-305 • Lot-Samp1e # ... : COC140160·001
Date Samp1ed ... : 03/13/00
Prep Date ...... : 03/15/00
Prep Batch# ... : 0076103
Dilution Factor: 1
PARAMETER
Pentachlorophenol
SURROGATE
2,4-Dibromophenol
•
•
GC Semivolatiles
Work Order# ... : D9KVF102
Date Received .. : 03/14/00
Ana1ysis Date .. : 03/20/00
Method ......... : SW846 8041
REPORTING
RESULT LIMIT
ND 2.0
PERCENT RECOVERY
RECOVERY LIMITS
102 (31 . 134)
Matrix ......... : WATER
MS Run# ....... :
UNITS
ug/L
• MBTHOD BLANK REPORT
GC/Jl!S Semivolatiles
Client Lot# ... : C0C140160 work order# ... : D9NFM101
MB Lot-Sample#: C0C160000·102
Analysis Date .. : 03/20/00
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Phenol
SURROGATE
Phenol·d5
2·Fluorobiphenyl
Nitrobenzene-dS
Terphenyl·dl4
2-Fluorophenol
2,4,6-Tribromophenol
NOTE (S):
Prep Date ...... : 03/15/00
Prep Batch# ... : 0076102
REPORTING
RESULT LIMIT
ND 10
ND 10
PERCENT RECOVERY
RECOVERY LIMITS
93 (10 113)
84 (30 110)
89 (32 112)
103 (10 144)
85 (13 110)
90 (21 122)
Cnlculntiorui are pcrfonnod hefore rounding lo avoid round-off errora i.n calcuh1tcd roiults . •
•
Matrix ......... : WATER
UNITS METHOD
ug/L SW846 8270C •.
ug/L SW846 8270C
MRTHOD BLANK REPORT • GC Semivolatiles
Client Lot# ... : C0C140160 Work Order# ... : D9NFN101
MB Lot-Sample#: C0C160000-103
Analysis Date .. : 03/20/00
Dilution Factor: 1
PARAMETER
Pentachlorophenol
SURROGATE
2,4·Dibromophenol
NOTE (SJ :
Prep Date ...... : 03/15/00
Prep Batch# ... : 0076103
REPORTING
RESULT LIMIT
ND 2.0
PERCENT RECOVERY
RECOVERY LIMITS
89 (31 . 134)
Cnlculntions nre performtd before rounding to avoid round-off errof!I in cnlculnted results .
•
•
Matrix ......... : WATER
UNITS METHOD ,
ug/L SW846 8041;,
LABORATORY CONTROL SAMPLE KIIALOATION REPORT • GC/MS Semivolatiles
Client Lot# ... : COC140160 Work Order # ... : D9NFM102-LCS Matrix. __ .... _.: WATER
LCS Lot-Sample#: COC160000·102 D9NFM103·LCSD
Prep Date ...... : 03/15/00 Analysis Date .. : 03/20/00
Prep Batch# ... : 0076102
Dilution Factor: 1
PERCENT RECOVERY RPD
PARAMETER RECOVERY LIMITS RPD LIMITS METHOD
2-CIIlorophenol 92 (19 -124) SW846 827.0C
93 (19 -124) 0.57 (0-43) SW846 8270C
1.4-Dichlorobenzene 93 (28 -110) SW846 8270C
93 (28 -110) 0.64 (0-36) SW846 8270C
N-Nitrosodi-n-propyl-110 (30 -115) SW846 8270C
amine
111 (30 -115) 0.36 (0-36) SW846 8270C
1,2,4-Trichlorobenzene 103 (31 -110) SW846 8270C
98 (31 -110) 4.4 (0-37) SW846 8270C
4-CIIloro-3-methylphenol 101 (29 -124) SW846 8270C
97 (29 -124) 4.1 (0-55) SW846 8270C Acenaphthene 104 (39 -118) SW846 8270C
100 (39 -118) 3.9 (0-35) SW846 8270C
4-Nitrophenol 96 (19 -144) SW846 8270C
.2,4-Dinitrotoluene
92 (19 -144) 3.8 (0-34) SW846 8270C
106 (47 -131) SW846 8270C
103 (47 -131) 2.7 (0-32) SW846 8270C Pentachlorophenol 100 (10 -140) SW846 8270C
94 (10 -140) 5.8 (0-56) SW846 8270C
Pyrene 114 (46 -130) SW846 8270C
110 (46 -130) 3.6 (0-31) SW846 8270C
Phenol 81 (10 -131) SW846 8270C
81 (10 -131) 0.16 (0-43) SW846 8270C
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Phenol-d5 94 (10 113)
92 (10 113)
2-Fluorobiphenyl 87 (30 110)
84 (30 110)
Nitrobenzene-dS 94 (32 112)
89 (32 112)
Terphenyl-d14 103 (10 144)
98 (10 144)
2-Fluorophenol 86 (13 110)
85 (13 110)
2,4,6-Tribromophenol 91 (21 122)
87 (21 122)
.NOTH(S):
C11lcul11tions 11re performed before rounding to nvoid round-off eTTors in culculated reimlt.s.
Bold print denotes control pnnunctera
LABORATORY CONTROL SAMPLE EVALUATION REPORT • GC Semivolatiles
Client Lot# ... : C0C140160 Work Order# ... : D9NFN102-LCS
D9NFN103-LCSD
Analysis Date .. : 03/20/00
Matrix ......... : WATER
LCS Lot-Sample#: C0C160000-103
Prep Date ...... : 03/15/00
Prep Batch# ... : 0076103
Dilution Factor: 1
PERCENT RECOVERY
PARAMETER RECOVERY LIMITS
Pentachlorophenol 89 (50 -126)
89 (50 -126)
PERCENT
SURROGATE RECOVERY
2,4-Dibrornophenol 81
83
Nm'E (S) :
Clliculations nre perfonned before rounding to avoid round-off error11 in calcul11ted ruu!ts.
Bold print denotea control parameters
•
•
RPD
RPD LIMITS METHOD
SW846 804;1
0.49 (0-20) SW846 8041
RECOVERY
LIMITS
(31 134)
(31 -134)
• JJ...
•
•
ALTA
March 17, 2000
Alta Batch l.D.: 8101
Ms. Rita Bauer
ThermoRetec Consulting Corporation
9 Damon Mill Square
Concord, MA 01742
Dear Ms. Bauer,
Enclosed is the result for the one effluent sample received at Alta Analytical Laboratory on
February 19, 2000. This work was identified as your Beazer/Raleigh Project. This sample was
analyzed using EPA Method 8290 for 2,3,7,8-TCDD. A standard turnaround time was requested
for this work .
The following report consists of a Sample Inventory (Section I), Analytical Results (Section II)
and the Appendix. The Appendix cotains a copy of the chain-of-custody, a list of data qualifiers
and abbreviations, our current certifications, diskette deliverables, and copies of the raw data.
If you have any questions regarding this report please feel free to contact me.
Sincerely,
Alta Analytical I.aboratory Inc.
5070 Robert J. Mathews Parkway
El Dorado Hills, CA 95762
FAX [phone]
[phone]
•
•
•
Sample Inventory Report -Extended
Project Name: General Analytical HRMS
Project No.: 81 O 1
ALTA
Sample ID
810 I 001
2/24/00
Client
Sample I /J
EFF/SV-305
Client Sample
Description
Storage
Sampled Received Lorntion
2/18/00 2/19/00 R-1
Page No.:
smpinvc.x.
1 .. -ALTA
•
•
•
Method Blank
Lah ID: 8101-MB
Matrix: Aqueous
Compound
2,3,7,8-TCDD
Internal Standard:
13C-2,3,7,8-TCDD
Cone.
ND
Clean-up Recovery Standard:
37Cl-2,3,7,8-TCDD
Dates Analyzed:
DB-5: 3/13/00
Analyst: MS
TCDD
EPA METHOD 8290
Date Received: NA
Date Extracted: 3/7/00
Sample Amount: 1.000 L
D.L.
1.2
Ratio
Isotopic Recovery Results
%R
60
68
Page I of I
S/N
Ratio
Ratio
0.76
NA
!CAL 1D: 11613
QC Lot: LC0307 A
Units: l2lill.
Qualifier
Qualifier
J .. -ALTA
•
•
•
LCS RESULTS
Lah ID:
Matrix:
8101-LCS
Aqueous
Compound
2,3,7,8-TCDD
lut,·rnal Standard:
13C-2,3,7,8-TCDD
Clean-up Rccove,y Standard:
37 Cl-2,3, 7,8-TCDD
Dates Analyzed:
DB-5: 3/ 13/00
Analysl: MS
TCDD
EPA METHOD 8290
Date Received: NA
Date l~xtrncted: 3/7/00
Sample Amount: 1.000 L
Spike
Amount
200
LCS
95
Isotopic Recove,y Results
Spike
Amount
2000
800
DH-225: NA
Pal,!l'I of I
LCS
'1/c,R
68
86
ICAL ID: 11613
QC Lot: LC0307A
U11its: NA
Limit
70 -130
1h1 // Rcvicwcr:7
/1.. -ALTA
•
•
•
Sample ID: EFF/SV-305
Lab ID: 8101-0001-SA
Matrix: Aqueous
Compound
2,3,7,8-TCDD
Internal Standard:
13 C-2,3, 7,8-TCD D
Cone.
ND
Clean-up Recovery Standard:
·'7 Cl-2,3,7,8-TCDD
Dates Analyzed:
DB-5: 3/16/00
Analyst: MS
TCDD
EPA METHOD 8290
Date Received: 2/19/00
Date Extracted: 3/7/00
Sample Amount: 0.938 L
D.L.
1.0
Ratio
Isotopic Recovery Results
'¼, R
60
77
Page I of 1
SIN
Ratio
Ratio
0.78
NA
I CAL ID: l.!.filJ_
QC Lot: LC0307A
Units: pg&
Qualifier
Qualifier
JJ.. -ALTA
•
•
•
A
B
C
D
E
F
G
H
Cone.
D.L.
NA
SIN
*
ND
MPC
DATA QUALIFIERS & ABBREVIATIONS
The amount detected is below the Method
Calibration Limit.
This compound was also detected in the blank.
The amount detected is less than five times the Method
Quantitation Limit.
The amount reported is the maximum possible concentration.
The detection limit was raised above the Method Quantitation
Limit due to chemical interferences.
This result has been confirmed on a DB-225 column.
This result has been confirmed on a SP-2331 column.
The signal-to-noise ratio is greater than I 0: I.
Chemical Interference
Concentration
Detection Limit
Not applicable
Signal-to-noise
Sec Cover Letter
Not Detected
Maximum Possible Concentration
1 .. -Al,TA
•
•
•
CURRENT CERTIFICATIONS
Bureau of Reclamation-Mid-Pacific Region---(MP-470, Res-I. I 0)
Commonwealth of Kentucky---(Certificatc No. 90063)
Commonwealth of Virginia---(Ccrtificate No. 00013)
State of Alaska, Department of Environmental Conservation---(Certificate No. OS-00197)
State of Arkansas, Department of Health---(Approval granted through CA certification)
State of Arkansas, Department of Pollution Control---
State of California---(Certificate No. 1640)
State of Connecticut---(Certificatc No. PH-0182)
State of Florida---(Certificate No. 87456)
State of Louisiana---(Certificate No. 98-33)
State of Mississippi---(Approval granted through CA certification)
State of Nevada---(Ccrtificate No. CA4 I 3)
State of New York, Department of Health---(Certificate No. 11411)
State of North Carolina---(Ccrtificatc No. 06700)
State of North Dakota, Department of Health---(Certificate No. R-078)
State of Oregon---
State of Pennsylvania---(Certificate No. 68-490)
State of South Carolina---(Certificatc No. 87002001)
State of Tennessee---(Certificate No. 02996)
State of Utah---(Certificatee No. E-20 I)
State of Washington, Department of Ecology---(Certification No. C09 l)
State of Wisconsin---(Certificate No. 998036160)
State of Wyoming---(Ref: SES-LB)
U.S. Army Corps of Engineers
U.S. 5 EPA Region
11/18/99
1 .. -ALTA
l.i.. FOiiLABORATORY USE ONLY
ALTA 1, iU/ . L:aboratory Project ID: ____ ~-------
CHAIN OF CUSTODY RECORD
-Storage
p _ / Secured:
Storage ID: ---~r-___________ Yes 0 No □
P.O.#:. _________ S.1mpler Tc~ IC41--ZZ:-L
-(l'rintcll Name)
Date: ;Z,-/ '-Di)
Date: Time: I ecei vcd by: (Signature and l'rint~'<.l N,Ullc) D:nc: Time:
Relinquished by: (Si~nalurc and Printed Namd Date: Time: Received by: (Signature and J>rim.:<l N.uncJ Date: Time:
See "Sample Log-in Checklist" for additional sample inf~rmation ..
SHIP TO:
ATTN:
Aha Analytical Laboratory
5070 Robert J. Mathews Parkway
El Dorado Hills, CA 95762
[phone] • Fax [phone]
www.altalab.com
-------------------
Sample ID Date Time
6t,1./ ,
Method of Shipment:
Shipment ID:
Sample Description
Circle or Add
Analysis(es)
Requested
Special Instructions/Comments: ______________________ _
Container Types: A= 1 Liter Amber, G = Glass Jar
P = PUF, T = MMS Train, 0 = Other ______ _
SEND
DOCUMENTATION
AND RESULTS TO:
*Bottle Preservative Type: T = Thiosulfate,
0 =Other _________ _
WHITE~ ORIGINAL YEL•-ARCHlVE
X
STANDARD TAT= 21 DAYS.
Surcharge may be applied
for less than 21 days.
TAT (Analytical Turnaround Times): 1 = 7 days,
2 = 14 days, 3 = 21 days, 4 = 28 days
Con1ainer(s)
Qty Type r-...fatrix BPT*
A !Zr
Name: /4',,,4-v,;Jl/~L
Company: Tdrl;,e,no ~,?L-C-
Address: 9 IJ4Mc,v 1'11,, I JO~¥_£
City: Cc,,-JC{,,R-11 State: /'-1~ Zip: C,i)'(~'J..,
Phone:(9)S )37/-/ Y,;L-~ Fax:('P?/J(;'i -'(L l j
Matrix Types: OW= Drinking Waler, EF = Effluent, PP = Pulp/Paper,
SO= Sediment, SL= Sludge, SO= Soil, WW= Wastewater, 0 = Other _____________ _
PlNK-COPY •
STANDARD OPERATING PROCEDURE
ALTA Analytical Laboratory Project No.: __ g/( __ c)_/ __
Attachment 10.B.1
I Sample log-In Checklist I Yes I No I (!)/IA--2-). "t ·tJ!J y I. Date Samples Arrived: ,,l-( 'f ·QJ Initials: ~
2. Time I Date logged in: i-J. l( "oi) /_?(JZ/ Location R-!_ liiitials: ~ ,
3. Samples Arrived By: (circle one) Airborne Express ~eral~ UPS Emery
Freezer Truck Company Courier World Courier Other
4. Shipping PreseNation: (circle) ~Y Blue Ice / Dry Ice / None Temp °C 2
5. Shinnina Container(s) Intact? If no describe condition below. ;<
6. Shipping Container(s) Custody Seals Present? V
Intact? If not intact, describe condition below.
• 7. Shipping Documentation_ Present? (circ;~ Shipping Label ~ ~ K Tracking Number <1657 0'7 3'> < ,-if 2-J.
•
8. Sample Custody Seal(s) Present X
Intact? If not intact, describe condition below.
No. of Seals or Seal No.
9. Sample Container Intact? If no, indicate sample condition below. 'I.
10. Chain of Custody (COC) or other Sample Documentation Present? </
11. COC/Documentation Acceptable? If no, complete COG Anomaly Form. A...·
12. Shipping Container: (circle) ALTA Retain or Return or Disposed
~ Retain or ~ or Disposed
13. Container(s) and/or Bottle(s) Requested? k
14. •sample Control Check In/Out Log Completed? )<
15. '"'Drinking VVater Sample? If yes, Acceptable Preservation? (circle) Y or N
IY Preservation Info From? (circle) coc or Sample Container or None Noted
•Required for HRMS
Name: __________________ _
(Signature Required for LCMS Only)
Date Samples Reconciled:~ ______ _
• Comments:
SOP# CH10Br11, Page 4 of 6
,,
RA
.NCDEMR
JAMES B. HUNT JR.
GOVCRNOR
BILL HOLMAN
SECRETARY
•
NORTH CAROLINA DEPARTMENT OF
ENVIRONMENT AND NATURAL RESOURCES
DIVISION OF WASTE MANAGEMENT
March 22, 2000
Ms. Beverly Hudson
Remedial Project Manager
Superfund Branch
FILE corv
Waste Management Division
United States Environmental Protection Agency
Region IV
61 Forsyth Street, l I th Floor
Atlanta, GA 30303
Re: Monthly Progress Report #82 (February)
Koppers Company NPL Site
Morrisville, Wake County
Dear Ms. Hudson:
The Superfund Section of the North Carolina Department of Environment and
Natural Resources (NC DENR) has received Monthly Progress Report #82
(February) for the Koppers Company National Priorities List (NPL) Site. The
Superfund Section has reviewed this document and offers the following
comments.
Monthly Progress Report #82 -February 2000
I. The laboratory analytical reports for the groundwater treatment system
effluent samples collected February 2, 2000 and February 18, 2000 were
inadvertently omitted. Please correct this oversight.
2. Table I indicates that the water sample collected between the carbon units
on February 18, 2000 was analyzed for 2,4-dichlorophenol and phenol.
However, Table 2 indicates that the water sample collected between the
carbon units on February 18, 2000 was analyzed for pentachlorophenol,
2,4-dichlorophenol and phenol. Please clarify this discrepancy.
Additionally, the notes for Table I indicate that phenol has been
inadvertently omitted from the associated groups. Please correct this
oversight.
IJlD tiiM·MM·M
1646 MAIL SERVICE CENTER, RALEIGH, NORTH CAROLINA 27699-1646
401 OBERLIN ROAD, SUITE 150, RALEIGH, NC 27605
F'HONE 919-733-4996 FAX [phone] AN EQUAL OPPORTUNITY/ AFFIRMATIVE ACTION EMPLOYER -50% REC:YCLED/10% POST-CONSUMER PAPER
•
•
•
Ms. Beverly Hudson
March 22, 2000
Page 2
3. Please clarify if the Table 2 heading, Analytical Sample Location SV-102, should actually
be Analytical Sample Location SV-101 as reflected in the Table 2 Notes and in Table I.
4. In November I 999, the facility significantly failed its toxicity test (complete organism
mortality and no reproduction). The December 1999 and January 2000 toxicity tests had
complete survival with treatment organism reproduction essentially the same as the
control organisms. Additionally, Table 2 indicates that the groundwater treatment system
effluent passed the chronic toxicity test. In the body of the report there is no explanation
or response to the toxicity described. Please detail any activities that were undertaken to
correct the effluent quality. Please detail whether provisions stipulated in the Toxicity
Reduction Evaluation Work Plan were implemented. Additionally, please provide
responses to the regulatory comments issued July I 999 through March 2000,
We appreciate the opportunity to comment on this document. If you have any questions, please
feel free to call me at [phone], extension 349.
Sincerely,
/J at, ,fd ,8 . /7) o..J:i,l 5 17•-' / d._/(
David B. Mattison, CHMM
Environmental Engineer
Superfund Section
cc: Judy Garrett, NC Div. of Water Quality
Matt Matthews, NC Div. of Water Quality
Mike Slenska, Beazer East, Inc .
•
•
ThermoRetec Corporation
9 Damonmill Square, Suite 3A
Concord, MA 01742-2851
pi:-:~E1v6rherm0Retec
March 8, 2000 MAR 13 2000
Si.., _,,FUND SECTION
Smart Solutions. Positive Outcomes.
[phone] Phone
[phone] fa,
www.thermoretec.com Ms. Beverly Hudson
Remedial Project Manager
U.S. EPA -Region IV, 11 ,h Floor
North Site Management Branch
61 Forsyth Street, SW
Atlanta, GA 30303
RE: Monthly Progress Report #82
Remedial Action
Koppers Site -Morrisville, North Carolina
Dear Ms. Hudson:
ln accordance with the Unilateral Order, and on behalf of Beazer East, Inc. (Beazer), please find
attached four (4) copies of the Monthly Progress Report for the period ending Februa1y 29,
2000 for the Remedial Action for Koppers Supcrfu,id Site, Morrisville, North Carolina .
Should you need additional information regarding this progress report, please call Mike Slenska
at ( 412) 208-886 7 or 111c at (207) 839-5 185.
Sincerely,
Ther1110Retec Consulting Corporation
//-. L C--✓ s_
\___:i-{tt,. /l·f y::::;a,u·--c
I Rita Bauer
Project Geologist
IU3:rm
Enclosure
cc: D. Mattison -NC Superfuncl (2 copies)
D. Hails -Ecological Restoration, lnc.
J. Garrett -NC Division of \>\later Quality
/'v1. Mauhews -NC Division of Water Quality
M. Slenska -Beazer
L. Faulconer -Wake County
G. Caskey -Enwood Structures
A subsidiarv of Thermo Terra Tech Inc..
•
•
•
MONTHLY PROGRESS REPORT #82
REMEDIAL ACTION
SITE NAME: Koppers Superfund Site
Beazer East, Inc.
Morrisville, NC
USEPA DOCKET NUMBERS: 93-09-C
PERIOD ENDING: February 29, 2000
1. PROGRESS MADE THIS MONTH
2.
3.
4.
5.
6.
7.
Remedial Action (RA) -HABITAT MIT/GA T/ON. No activities were conducted this
month.
Remedial Action (RA) -GROUNDWATER TREATMENT. The treatment system
operated throughout the month without upset. System performance was monitored
on a biweekly basis. Approximately 42,435 gallons of groundwater were extracted,
treated in the treatment plant and discharged between February 1 and February 29,
2000. System water samples were collected on February 2, 2000 and February 18,
2000 in accordance with the sampling schedule in the O&M manual. Samples were
submitted to Quanterra Incorporated/Severn Trent Laboratories for laboratory
analysis. The operations and sampling programs are summarized on the attached
Table 1.
Remedial Action (RA) -EFFECTIVENESS MONITORING PROGRAM. No activities
were conducted this month.
Remedial Action (RA) -CORRESPONDENCE. None.
PROBLEMS RESOLVED
PROBLEMS ANTICIPATED
UPCOMING EVENTS
PERSONNEL CHANGES
SUBCONTRACTORS
None.
None.
Continue System O&M.
None.
None.
ANALYTICAL DATA Analytical data from system influent and effluent sampling
received during this period are enclosed and are summarized on Table 2 .
F ,\I' RO I ECJ" S\03 614\CO RRES\1000\H uds0308. wpd
•
Date Systems Check Cummulative
(yes/no) Efnuent Flow
(Gallons)
0!/04/00 ves 2.178.450
Qt{J.Q/00 '" 2 201 060
02/02/uu ves 2,223,010
02/ I 8/00 ves 2,243,495
Notes:
SV-101 -Before Carbon Units (pretreatment)
*SV-304 -Between Carbon Units
SV-101
Sample
(ves/nol
no
no
no
no
HSV-305 -After Carbons Units (post-lreatmem)
•
Table I
Groundwater Treatment Operations and Sampling Program Summary
Koppers Superfund Site
Morrisville, North Carolina
February 2000
SV-101 Associated 'V-304* SV-304 Associated
Sample Group Sample Sample Group
Parameters (ves/no) Parameters
no
no
no
ves 2.4-Dichloro. Phenol I
Associated Groups:
SV-305**
Sample
(ves/no)
m
~es
'" \leS
SV-101 -Group I is pema and 2,4-dichlorophenol; Group 2 is dioxins
SV-304 -Group 3 is penta and 2,4-dich!orophenol
SV-305
Sample
Parameters
Penta, 2,4-Dichloro, & Phenol. & tox
Penta 2 4-Dich]nro Phenol
Penta, 2.4-Dichloro. Phenot, ~ tox
Penta, 2,4-Dichloro. Phenol
SV-305 -G~~~ta and 2.:~~c~!~r~p~e_!!_ol.;_Q!_o_!!p2 is dioxins and Group 4·is·to.,iciiy--------
•
Associated
Group
I .4
I
1,4
I
•
•
Parameter
Pentachlorophenol
2.4-Dichlorophenol
Phenol
Chronic Toxicity
I Table 2 i Groundwater Treatment
ANALYTICAL DATA SUMMARY
I Koppers Superfund Site
Morrisville, North Carolina
I February 2000
I Analytical
I Date Sample I Sample Location i
I Collected SV-102
! 01/04/00
; 01/20/00
! 02/02100
I 02/18/00
I 01/04/QQ
I 01120100
: 02/02/00
I 02/18/QO
: 01 /04/00
iOl/20/00
1,02/02/00
:02/18/00
,01/04/00
02/01/00
Sample
Location
SV-304*
<2
< 10
< 10
Notes: All results are in ug/L except ~lioxin, Dioxin data is in picograms/L.
SY-IOI -Before Carbon Units
*SV-304 -Between Carbon Uni1s
**SV-305 -After Carbon Units
Sample
Location
SV-305**
<2
<2
<2
<2
< 10
< 10
< 10
<IO
< 10
< 10
< 10
< 10
Pass
Pass
BILL HOLMAN
.'· SECRETARY
NORTH CAROLINA DEPARTMENT OF
ENVIRONMENT AND NATURAL RESOURCES
DIVISION OF WASTE MANAGEMENT
February 24, 2000
I Ms. Beverly Hudson
' Remedial Project Manager
Superfund Branch 1
Waste Management Division
United States Environmental Protection Agency
Region IV
61 Forsyth Street, 11 '~ Floor
' Atlanta, GA 30303 '1
Re:
' I Monthly Progress Report #81 (January)
Koppers Company NPL Site
Morrisville, W:ake County
\
Dear Ms. Hudson:
'
The Superfund Sectiori of the North Carolina Department of Environment and
Natural Resources (NC DENR) has received Monthly Progress Report #81 ' (January) for the Koppers Company National Priorities List (NPL) Site. The
Superfund Section has reviewed this document and offers the following ' comments. ·
' Monthly Progress Report #81 -January 2000
1.
2.
'1
The Case Narrat_ive included in the Analytical Reports for the groundwater
remediation syst~m effluent samples collected on January 4, 2000 and
January 20, 2000 indicate that the samples were received at proper ' temperature by Quanterra Environmental Services, Inc. Please include the
actual sample temperature as received by the laboratory in all future
laboratory reports.
I
I Please clarify if the Table 2 heading, Analytical Sample Location SV-102,
' should actually b~ Analytical Sample Location SV-101 as reflected in the
Table 2 Notes and in Table I. I
1646 MAIL SERVICE CENTER, RAt..EIGH, NORTH CAROL,INA 27699•1646
401 OBERLIN ROAD, SUITE I SO, RALEIGH, NC 27605
PHONE 919•733•4996 FAX 919·7 \ 5·3605 AN EQUAi. OPPORTUNITY/ AFFIRMATIVE ACTION E'.MPL.OYER • 50% RECYCI.E0/10% POST•CONSUMER PAPER
' .
•
•
•
Ms. Beverly Hudson
February 24, 2000
Page 2
' 3. In November 1999, the facility significantly failed its toxicity test (complete organism mortality and no reproductibn). The December 1999 and January 2000 toxicity tests had complete survival with treatment organism reproduction essentially the same as the I control organisms. In the body of the report there is no explanation or response to the toxicity described. Please d~tail any activities that were undertaken to correct the effluent quality. Please detail whether provisions stipulated in the Toxicity Reduction Evaluation Work Plan were implement~d. Additionally, please provide responses to the regulatory comments issued July 1999 through December 1999.
I
' We appreciate the opportunity to comment on this document. If you have any questions, please
' feel free to call me at (919) 733-280 I, extension 349.
cc:
I
Sincerely,
David B. Mattison, CHMM
Environmental Engineer
Superfund Section
Judy Garrett, NC Div. of Water Quality
Matt Matthews, NC Div. ofW~ter Quality
Mike Slenska, Beazer East, Inc.' . I
' I
\
I
•
•
Februarv 4, 2000
Ms. Beverlv Hudson ;
Remedial Project Manager
U.S. EPA -Region IV, 11 ,h Floor
North Site Management Branch
61 Forsvth Street, SW
Atlanta, GA 30303
RE: Monthly Progress Report '#81
Remedial Action 1
Koppers Site • Morrisville; NC
Dear Ms. Hudson:
ThermoRetec Corporation
9 Damonmill Square, Suite 3A
Concord, MA 01742-2851
.ThermoRetec
Smart Solutions. Positive Outcomes.
[phone] Phone
[phone] Fax
www.thermoretec.com
FF..1:i \I l 2000
SUPERFUND SECTION
In accordance with the Unilateral Order, and on behalf of Beazer East, Inc. (Beazer), please find
attached four ( 4) copies of the Mont0ly Progress Report for the period ending January 31. 2000
for the Remedial Action for Koppers, Superfund Site, Morrisville, North Carolina.
Should ,·ou need additional information regarding this progress report, please call Mike Slensb
at [phone] or me at [phone].
Sincerelv,
' I
ThermoRetec Consulting Corporation • I ---.· ' .,,,,-,-.·
\ -/·· , _______ , ;,..,. ·~(~_ :1._:_/ /~:: ~ c: •\_
Rita Bauer
Project Geologist
rb:mcv
Enclosure
'
cc: D. Mattison -NC Superfund (2 i:opies)
D. Hails -Ecological Restoration: Inc.
J. Garrett -NC Division of Water Quality
M. Matthews -NC Division of Water Quality
I
F:\PROJECTS\3603\CORRES\2000\Hu<ls0204.wp<l i I
M. Slenska -Beazer
L. Faulconer -Wake County
G. Caskey• Enwood Structures
A subsidiary of Thermo Terra Tech Inc.,
a Thermo Electron company
•
•
I
I
MONTHLY PROGRESS REPORT #81
I REMEDIAL ACTION
I
I
SITE NAME: KopJers Superfund Site
Beazer East, Inc.
Morrisville, North Carolina
!
I
USEPA DOCKET NUMBERS: : 93-09-C
'
PERIOD ENDING: I January 31, 2000
I
1. PROGRESS MADE THIS:MONTH
I
' Remedial Action (RA) -HABITAT MIT/GA T/ON. No activities were conducted this
I month. ,
I
I
Remedial Action (RA) -GROUNDWATER TREATMENT. The treatment system
operated throughout the month without upset. System performance was monitored
on a biweekly basis. Apprdximately 50,130 gallons of groundwater were extracted,
treated in the treatment plant and discharged between January 1 and January 31,
2000. System water samples were collected on January 4, 2000 and January 20,
2000 in accordance with th~ sampling schedule in the O&M manual. Samples were
submitted to Quanterra Incorporated for laboratory analysis. The operations and
sampling programs are surtimarized on the attached Table 1.
Remedial Action (RA)-EFFECTIVENESS MONITORING PROGRAM. No activities
were conducted this month;
I
Remedial Action (RA) -COf?RESPONDENCE. None.
I
2. PROBLEMS RESOLVED , None.
3.
4.
5.
6.
7.
PROBLEMS ANTICIPATED
UPCOMING EVENTS
PERSONNEL CHANGES
SUBCONTRACTORS
ANALYTICAL DAT A
None.
Continue System O&M.
None.
None.
Analytical data from system influent and effluent
sampling received during this period are
enclosed and are summarized on Table 2 .
•
Date Systems Check Cummulative
(yes/no) Effluent Flow
(Gallons)
01/04/00 ves 2.178,450
01/20/00 ves 2,201,060
Notes:
SV-101 -Bdorc Carbon Unit:-. (prctrl!alnh.:nl)
•SV-304 -Between Carbon Units
SV-101
Sample
(ves/no)
no
no
HSY -305 -After Carbons Units (post-1reatment)
•
Tahle 1
Groundwater Treatmem Operations and Sampling Program Summary
Koppers Superfund Site
fvtorrisville, Nonh Carolina
January 2000
SV-IOI Associated SV-304' SV-304 Associated
Sample Group Sample Sample Group
Paramett!rS (ves/no) Paran1cters
no
no
Associated Groups:
SV-305**
Sample
(yes/no)
vcs
yes
SV-101 -{iruup I i:-. pcnta :rnd 2,4•dichloroptwuul; Grnup 2 is dioxins
SV-304 -Group 3 is pe1ita and 2.4-dichlorophem:il
SV-305
Sample
Paranieters
Penta, 2,4-Dichloro, & Phenol. & lox
Penta, 2,4-Dichloro, Phenol
SY-305 -Group I is pema and 2.-1-dichlorophenol; Groupl is dioxins and Group 4 is ioxicity
Associated
Group
1.4
I
•
•
•
Parameter
Pentachlorophenol
2.4-Dichlorophenol
Phenol
Chronic Toxicity
Table 2
Groundwater Treatment
ANALYTICAL DATA SUMMARY
I Koppers Superfund Site
'Morrisville, North Carolina
I I January 2000
' I
' I
' I ! i
!
I
'
I
I
'
Ana1yuca1
Date Sample
Sample Location
Collected SV-102
01/04/00
01/20/00
01/04/00
01/20/00
01/04/00
01/20/00
01/04/00
Sample
Location
SV-304*
Notes: All results are in ug/L except dioxin. Dioxin data is in picograms/L.
SV-101 -Before Carbon Units '
*SV-304 -Between Carbon Units
**SV-305 -After Carbon Units
Sample
Location
SV-305**
<2
<2
< 10
< 10
< 10
< 10
Pass
Qrumterra
• 450 i,Villiam Pitt VVav
Pittsburgh, Penn.syluc;nia I 523 8-1330
412 820-8380 Telephone
412 820-2080 Fax
•
•
ANALYTICAL REPORT
PROJECT NO. RALEIGH
I
Raleigh-Bi-Weekly NPDES
:Lot#: C0A0S0l.46
'nebbi Leuteritz I
I
I I
I
I
ThermoRetec
QOlU!'1'ERRA INCORPORATED
/':/ l//;/t;/ft,t✓J(Jiu.ftj:,
V~ronica Bertot
P~oject Manager
I
January 11, 2000
lj}\ ~uanterra
•
•
•
SHIPMENT:
I I CASE NARRATIVE
THERMORECTEC CORPORATION
!
I
SITE:
RALEIGH Bl-WEEKLY NPDES
I
I
Quahterra Lot No. C0A050 l 46
I
' ' ' I
I
I!}' -,euanterra
Sample was received at Quanterra-Pittsburgh, PA on January 5, 2000 in good condition
and at proper temperature. The sample was analyzed for the parameters as directed on the
' chain of custody and HARP Form,
I I
NOTE: '
Except where noted, no problems ~vere observed during the analyses,
'
SAMPLE SUMMARY I
Q>uanterra
•
•
I COA050146
WO# SAMPLE# CLIENT SAMPLE ID
D73GP 001 SYSEFF/SV-305
NOTE (S) :
• The o.nnlyticnl results of the samples lillled nbove nre presented on the
0
following pnges.
' • All calcu!ations nre perfonncd before rounding to avoid round-off el'T1o~ in calculated results.
-Results noted as "ND" were not detected ut or above thi.i sllltcd limit. !
-This report mu.st not be reproduced, except in full, without the writteri. npprovnl of the toborntory.
• Results for the following parameters are never reported on II dry weig~t bll!lis: color, corrosivity, density, flashpoint, ignitability, \ayer.1, odor,
pnint filter test, pH, porosity pressure. reactivity, rcdox potential, spcc,ific gruvicy, spot tests, solids, solubility, temperature, viscosity, nnd weight .
•
DATE TINE
01/04/00 15:45
•
•
•
METHODS SUMMARY llf!}' ~uanterra
COA050l46
PARAMETER
Phenols by GC 1
Semi volatile Organic Compounds ',by GC/MS
i
' References:
ANALYTICAL
METHOD
SW846 8041
SW846 8270C
PREPARATION
METHOD
SW846 3520C
SW846 3520C
SW846 "Test Methods for Evaluating Solid Waste, Physical/Chemical
Methods 11 , Third EditiOn, November 1986 and its updates.
i
'
THEl!KlRETKC
i {}!Juanterra
Cl.ient Sampl.e ID: SYSEFF/SV-305
• Lot-Sampl.e lL .. : COA050146·001
01/04/00
01/06/00
0006203
Date Sampl.ed ... :
Prep Date ...... :
Prep Batch # ... :
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Phenol
SURROGATE
Nitrobenzene-dS
Terphenyl·dl4
2 ·Fluorophenol
2·Fluorobiphenyl
Phenol-d5
2,4,6-Tribrornophenol
•
•
' I
IGC/MS Semivol.atil.es
I Work Order# ... : D73GP101
Date Received .. : 01/05/00
Analysis Date .. : 01/10/00
I '
'
Matrix ......... : WATER
MS Run# ....... :
Method ......... : SW846 8270C
REPORTING
RESULT LIMIT UNITS
ND\ 10 ug/L
ND I 10 ug/L
' PERCENT RECOVERY
RECOVERY LIMITS
·61 (32 112)
89 (10 144)
52 (13 110)
55 (30 110)
63 (10 113)
71 (21 122)
•
•
•
THERH.JRETEC
Client Sample ID: SYSEFF/SV-305
Lot-Sample# ... : C0A050146·001
Date Sampled ... : 01/04/00
Prep Date ...... : 01/06/00
Prep Batch# ... : 0006218
Dilution Factor: 1
PARAMETER
Pentachlorophenol
SURROGATE
2,4·Dibromophenol
GC Semivolatiles
Work Order # ... : D73GP102
Date Received .. : 01/05/00
I • / Anjtlysis Date .. : 01 07/00
'
Method ......... : SW846 8041
I I
I
RESULT
i PERCENT
' RECOVERY
96
REPORTING
LIMIT
2.0
RECOVERY
LIMITS
(31 -134)
In\ ~uanterra
Matrix ......... : WATER
MS Run# ....... :
UNITS
ug/L
• Client Lot# ... : C0A050146
MB Lot-Sample#: C0A060000-203
Analysis Date .. : 01/10/00
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Phenol
SURROGATE
Nitrobenzene-dS
Terphenyl·dl4
2-Fluorophenol
2-Fluorobiphenyl
Phenol·dS
2,4,6-Tribromophenol
NOTE(S):
I
\METHOD BLlll!IK REPORT
iGC/MS Semivolatiles
i Wo~k Order# ... : D75SQ101
' ' PreP Date ...... : 01/06/00
Prep Batch# ... : 0006203
' REPORTING I RESULT LIMIT
ND 10
ND 10
' ' ' PERCENT RECOVERY
RECOVERY LIMITS
56 (32 112)
91 (10 144)
so (13 110)
48 (30 110)
58 (10 113)
67 (21 122)
Cakulations are performed before rounding to avoid round-off errors in calculntcd results .
•
•
(j!)uanterra
Matrix ......... : WATER
UNITS METHOD
ug/L SW846 8270C
ug/L SW846 8270C
• 'METHOD BLANK REPORT
I
\ GC Semivolatiles
I
Client Lot# ... : C0A050146 Work Order# ... : D758Ql01
MB Lot-Sample#: C0A060000·218
Analysis Date .. : 01/07/00
Dilution Factor: 1
PARAMETER
Pentachlorophenol
SURROGATE
2,4·Dibromophenol
NOTE(SJ:
' Prep Date ...... : 01/06/00
Prep Batch# ... : 0006218
' REPORTING I RESULT LIMIT
ND 2.0
PERCENT RECOVERY
RECOVERY LIMITS
90 (31 . 134)
Calculations nrc performed before rounding to nvoid round-off erron in e;ilculated results .
•
•
UNITS
ug/L
II!!' ~uanterra
Matrix ......... : WATER
METHOD
SW846 8041
Q' 'l/Uanterra
LABORATORY CONTROL SAMPLE KVALOATION REPORT
I • IGC/MS Semivolatiles
I
Client Lot # ... : COA050146 Work Order# ... : D755Q102-LCS Matrix ......... : WATER
LCS Lot-Sample#: COA060000-203 I D755Q103-LCSD
Prep Date ...... : 01/06/00 Aruil.ysis Date .. : 01/10/00
I
Prep Batch# ... : 0006203
Dilution Factor: 1
PERCENT RECOVERY RPD
PARAMETER RECOVERY LIMITS RPD LIHITS METHOD
2-Chlorophenol 57 (19 -124) SW846 8270C
60 (19 -124) 5.1 (0-43) SW846 8270C
1,4-Dichlorobenzene 52 (28 -110) SW846 8270C
55 (28 -110) 6.5 (0-36) SW846 8270C
N-Nitrosodi-n-propyl-60 (30 -115) SW846 8270C
amine
64 (30 -115) 7.6 (0-36) SW846 8270C
1,2,4-Trichlorobenzene 54 (31 -110) SW846 8270C
55 (31 -110) 3.0 (0-38) SW846 8270C
4-Chloro-3-methylphenol 67 (29 -124) SW846 8270C
70 (29 -, ..,A\ _._..,,.,.. I 3.9 {C-55} SW846 8270C
Acenaphthene 73 (39 -118) SW846 8270C
76 (39 -118) 4.3 (0-35) SW846 8270C
4-Nitrophenol 78 (19 -144) SW846 8270C • 81 (19 -144) 3.9 (0-34) SW846 8270C
2,4-Dinitrotoluene 86 (47 -131) SW846 8270C
88 (47 -131) 2.8 (0-32) SW846 8270C
Pentachlorophenol 79 (10 -140) SW846 8270C
86 (10 -140) 7.6 (0-56) SW846 8270C
Pyrene 95 (46 130) SW846 8270C
99 (46 -130) 4.2 (0-31) SW846 8270C
Phenol 54 (10 -131) SW846 8270C
58 (10 -131) 6.3 (0-43) SW846 8270C
PERCENT RECOVERY
SURROGATE RECOVERY LIHITS
Nitrobenzene-dS 61 (32 112)
63 (32 112)
Terphenyl-d14 92 (10 144)
96 (10 14-l)
2-Fluorophenol 51 (13 110)
54 (13 110)
2-Fluorobiphenyl 56 (30 110)
59 ( 30 110)
Phenol-d5 62 (10 113)
66 (10 113)
2,4,6-Tribromophenol 74 (21 1221
77 (21 122)
• NOTE (S) :
Cakulutions nre performed before rounding lo avoid round-off errors in cut6ubted results.
I Bokl print denote~ control purnmctcr.i I
I
I
I
•
•
•
lf!i' -,.euanterra
LABORATORY CONTROL SAMPLE EVALUATION REPORT
Client Lot# ... : C0A050146
LCS Lot-Sample#: C0A060000-218
Prep Date ...... : 01/06/00
Prep Batch# ... : 0006218
Dilution Factor: 1
PARAMETER
Pentachlorophenol
I GC Semivolatiles
I
I Work Order# ... : D758Q102-LCS
i
' Analysis
' '
PERc'ENT ' RECOVERY
88 I
93
D758Q103-LCSD
Date .. : 01/07/00
RECOVERY
LIMITS RPO
(SO -126)
(SO -126) 5.1
Matrix ......... : WATER
RPO
LIMITS METHOD
SW846 8041
(0-20) SW846 8041
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
2,4-Dibromophenol 107 (31 134)
114 (31 -134)
NOTE (S) :
' Cnkulntions arc performed before rounding to nvoid round-,lff errors if!, ,.;11\culnted result!!.
Bold print denotes control parameters
Chain of
Custody Record
QUA 412~
CNenl /\ ['
, \ ~O:J,V•ll '.a A,t(
Address _ . _ '\; _':l' ~ ' ( ,_) ----~~i'~, ,
Citv \ r ( ~,,n /~J/)/\
p;ojec_r. ~~ne f (' ' <. ,'i I:_-,,,.(',_ t e ,-
Con/rac/lPurchase OrdorkJuo/o No.
i/ IL 1,-0c, \\,_
Slate Zip Code
Mr ,"")· ,, lt1'7'l ' ' '
I
0Qjr1\-,
I
Project Manager ' 1 ,, \ r, .>, ~/•' &,I ~/ ·' ,,,
Telephone Number (Area Code)/Fax Number
• • .,1 C• i ' ,) ' ·1 ~ I\:-::
Site Contact
Carrierrayqilf Number JI , -'11·,11/'1 i ;·-~ / r, -\.nr,i/\~ ' -' ii
' Containers
Sample 1.0. No. and Description Total Date Time Sample Type Preservative
:<· 1/::_ r:1·r-1 ',v ·.3-0.5
------
Special Instructions
Possible Hazard Identification
[ZJ !'Jon-Hazard D Flammable
T(Jrn Around Time Required
IS] Nonna/ 0 Rush
I'. Relinquished By , 1 If . ' ' I ,~:/_.ft•.
2. Relinquished By
3. Relinquished By
Comments
Volume
1--· '-f -f' I:, 1 ·~·,J ·t I -{ ••• ) ,.! Q_
,I
'
-~--~ -------------------
D Skin Irritant 0Poison8 □unknown
l
ac Level
Or, Q,r, 0111.
IDa/e L _ '·i !) 'Time
i-~-1:' I I Date
1
Time
jDate
1
Time
., ' 'C ·,
DISTRIBUTION: -Stays with Samofe; CANARY -Returned to Client with Report; PINK -Field Copy
Type No,
:;. \'-,\.,.' '1 \ u / .. Jr:r •,
Sample Disposal
D Return To Client
Project Specific (Specify)
I. Received By
11 \ ''' ,-1: .!
2. Received By i .[. ! i
3. Re_ceived By
IA~" ~uanterra
Date , I -, Chain Of Custody Number
I ~ ,··· r-
.i/ , .. \
" Lab Number
Page of ' Analysis
' -
I" ,,:
-, ,,
Condition on Receipt (:,-<·
'
-------------
' . ------
C:J Disposal ay· Lab 0 Archive For Months
!Date I Time
j ..
1
Date
1
T~me
!Date
1
Time
:·:r r· -
-
Q1wnterni • 450 l.Yilliam Pitt H/c1v
Pittsburgh, Pennsylvania 15238-1330
4 I 2 820-83 80 Teleplwne
412 820-2080 Fax
•
•
ANALYTICAL REPORT
PROJECT NO. RALEIGH
I
Ra)-eigh-Bi-Weekly NPDES
Lot#: COA210188
:
1
Debbi Leuteritz
I
l ThermoRetec
QOANTERRA INCORPORATED
' '1/"
~t1~It_t[!cl1-ir;t-
Veronica Bertot
Project Manager
J~uary 27, 2000
(}puanterra
•
•
SHIPI.YIBNT:
CASE NARRATIVE
THERMORECTEC CORPORATION
SITE:
RALEIGH BI-WEEKLY NPDES
I
\
Quanterra Lot No. COA210l88
I
~!\ ~uanterra
Sample was received at Quantei'ra-Pittsburgh, PA on January 21, 2000 in good condition
and at proper temperature. The lample was analyzed for the parameters as directed on the
chain of custody and HARP FoAn. .
I
NOTE: I
Except where noted, no problems were observed during the analyses,
i
•
•
•
PARAMETER
Phenols by GC
Semivolatile Organic
References:
METHODS SUMMARY lfff~ ~uantterra
CUA210188
I
I Compounds, by GC/MS
' I
ANALYTICAL
METHOD
SW846 8041
SW846 8270C
PREPARATION
METHOD
SW846 3520C
SW846 3520C
SW846 "Test Methods for Evaluating Solid Waste, Physical/Chemical
Methods 11 , Third Edition, November 1986 and its updates.
I
•
•
' 1SAMPLE SUMMARY
COA210188
WO # SAl'lPLE# CLIENT SAMPLE ID
tlf!}"\ ~uanterra
DATE TIME
D7NKX 001 EFF/SV305 01/20/00 11:35
NOTE (S) :
-1lle a.imlyti..:ul 1,:~ulll! <>f the .'lnmpics li.'l=l nhnve nm r~ntcd ('Q the follo•.ving page!.
-All c:ilculations ure performed before rounding to avoid round-off errors in cnlculnted results.
-Rt:.!!ullll noted I.L1I "ND" were not detected nt or nbove the stntcd limit.
I -Thu report must not be reproduced, except in full, without the writtell approval of the lnborntory.
-Resullli for the following pnmmeters are never reported on :i dry weig~t b11sis: color, corrosivity, density, tlruihpoint, ignitability, byer.1, odor,
p11int filter test, pH. porosity prcs.'lllre, reactivity, rcdox potential, sp~ific gravity, spot tests. solids, solubility, temperature, v~osity, Wld weight.
I
I
I
• Lot-Sample# ... : C0A210188-001
Date Sampled ... : 01/20/00
Prep Date ...... : 01/24/00
Prep Batch# ... : 0024296
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Phenol
SURROGATE
Nitrobenzene-dS
Terphenyl·dl4
2·Fluorophenol
2·Fluorobiphenyl
Phenol-dS
2,4,6-Tribromophenol
•
•
~RETEC
Client Sample ID: EFF/SV305
GC/MS Semivolatiles
' ~ork Order# ... : D7NKX101
Date Received .. : 01/21/00
lfualysis Date .. : 01/26/00
I
If!~\ ~uanterra
Matrix ......... : WATER
MS Run# ....... :
l!!ethod ......... : SW846 8270C
l
REPORTING
RESULT LIMIT UNITS
ND 10 ug/L
Nri 10 ug/L :
PERCENT RECOVERY
RECOVERY LIMITS
99 i (32 112)
I 121 (10 144)
' 80 ', (13 110)
96 , (30 110)
91 : (10 113)
97 (21 122)
• Lot-Sample# ... : COA210188·001
Date Sampled ... : 01/20/00
Prep Date ...... : 01/24/00
Prep Batch# ... : 0024292
Dilution Factor: 1
PARAMETER
Pentachlorophenol
SURROGATE
2,4-Dibromophenol
•
•
==c
11. / C ,J.ent Sample ID: EFF SV305
GC Semivolatiles
I
Work Order # ... : D7NKX102 I Date Received .. : 01/21/00
Analysis Date .. : 01/26/00
I
Method ......... : SW846 8041
I
I REPORTING
RESULT LIMIT
ND 2.0
PERCENT RECOVERY
I RECOVERY LIMITS
1i2 (31 . 134)
I
lif!~\ -,euanterra
Matrix ......... : WATER
MS Run# ....... :
UNITS
ug/L
• Lot-Sample# ... : COA210188·001
Date Sampled ... : 01/20/00
Prep Date ...... : 01/24/00
Prep Batch# ... : 0024292
Dilution Factor: 1
PARAMETER
Pentachlorophenol
SURROGATE
2,4-Dibromophenol
•
•
THRRMORETEC
i
Client Sample ID: KFF/SV305 !
GC Semivolatiles
Work Order # ... : D7NKX1 O 2
riate Received .. : 01/21/00
ApaJ.ysis Date .. : 01/26/00
Method ......... : SW846 8041
!
I REPORTING
RESULT LIMIT
ND 2.0
i
PERCENT RECOVERY
RECOVERY LIMITS
112 (31 . 134)
II)~\ ~uanterra
Matrix ......... : WATER
MS Run# ....... :
UNITS
ug/L
•
•
•
Client Lot# ... : COA210188
MB Lot-Sample#: COA240000·292
Analysis Date .. : 01/26/00
Dilution Factor: 1
PARAMETER
Pentachlorophenol
SURROGATE
2,4-Dibromophenol
NOTE (S) :
METHOD BLANK REPORT
GC Semivolatiles
I
w6rk Order# ... : D7R83101
'
Pr~p Date ...... : 01/24/00
Prep Batch# ... : 0024292
REPORTING
RESULT LIMIT
ND I 2.0 I
I PERCENT RECOVERY
' RECOVERY LIMITS
109 (31 -134)
' Calculations nre perfonncJ before rounding 10 avoid round-off errors iri co.lculnted results.
'
UNITS
ug/L
I!~\ ~uanterra
Matrix ......... : WATER
METHOD
SW846 8041
•
•
Client Lot# ... : C0A210188
MB Lot-Sample#: C0A240000-296
Analysis Date_.: 01/26/00
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Phenol
SURROGATE
Nitrobenzene-d5
Terphenyl -dl4
2-Fluorophenol
2-Fluorobiphenyl
Phenol-d5
2,4,6-Tribromophenol
NOTE(S):
METHOD BLANK REPORT
1 GC/MS Semivolatiles
I Work Order# ... : D7R88101
I
P~ep Date ...... : 01/24/00
Prep Batch# ... : 0024296
I
I REPORTING
RESULT LIMIT
ND 10
' ND ' I 10
I
PERCENT RECOVERY
RECOVERY LIMITS
78 (32 112)
115 \ (10 144)
65 (13 110)
73 (30 110)
75 (10 113)
84 (21 122)
Cah.:ulations are perfonned before rounding 10 :ivoid round-off error.I in i:11lculatcd rCllults .
UNITS
ug/L
ug/L
I)}"\ ~11anterra
Matrix ......... : WATER
METHOD
SW846 8270C
SW846 8270C
•
•
•
If!~"\ ~uanterra
LABORATORY\ CONTROL SAMPLE KVALUATION REPORT
GC Semivolatiles
Client Lot# ... : C0A210188
C0A240000·292
01/24/00
Work Order# ... : D7R83102-LCS Matrix ......... : WATER
LCS Lot-Sample#:
Prep Date ______ :
I D7R83103-LCSD
~ysis Date .. : 01/26/00
Prep Batch# ... : 0024292
Dilution Factor: 1
PARAMETER
Pentachlorophenol
SURROGATE
2,4-Dibromophenol
NOTE (S) :
PERC:EtIT
RECOVERY
1031 I
103,
RECOVERY
LIMITS
(50 -126)
(50 -126)
PERCENT
RECOVERY
126
124
Calculations nre perfonned before rounding to avoid round-off errors•~ calculated results.
Bold print denote., control parameters
RPD
RPD LIMITS
0.48 (0-20)
RECOVERY
LIMITS
(31 134)
(31 -134)
METHOD
SW846 8041
SW846 8041
~\ r,uanter:ra
LABORATORY\CONTROL SAMPLE EVALOATION REPORT
• I GC/MS Semivolatiles
I
Client Lot # ... : COA210188 Work Order # ... :
'
D7R88102-LCS Matrix ......... : WATER
LC$ Lot-Sample#: COA240000-296 D7R88103-LCSD
Prep Date ...... : 01/24/00 Analysis ' Date_.: 01/26/00
Prep Batch# .. _: 0024296 I
I Dilution Factor: 1 I
PER~ENT RECOVERY RPD
PARAMETER RECOVERY LIMITS RPD LIMITS METHOD
2-Clllorophenol 87 i (19 -124) SW846 8270C
84 ' (19 -124) 3.2 (0-43) SW846 8270C
1,4-Dichlorobenzene 91 (28 -110) SW846 8270C
89 (28 -110) 2.3 (0-36) SW846 8270C
N-Nitrosodi-n-propyl-109 (30 -115) SW84.6 8270C
amine
109 (30 -115) 0.37 (0-36) SW846 8270C
1,2,4-Trichlorobenzene 94 (31 -110) SW846 8270C
91 (31 -110) 2.8 (0-37) SW846 8270C
4-Cllloro-3-methylphenol 95 (29 -124) SW846 8270C
94 (29 -124) l.2 (0-55) SW846 8270C
Acenaphthene 110 (39 -118) SW846 8270C
108 (39 -118) l.8 (0-35) SW846 8270C
4-Nitrophenol 105 ' (19 -144) SW846 8270C • 98 (19 144) 6.3 (0-34) SW846 8270C
2,4-Dinitrotoluene 120 (47 -131) SW846 8270C
120 (47 -131) 0.28 ( 0-32) SW846 8270C
Pentachlorophenol 105 (10 -140) SW846 8270C
103 (10 -140) l.8 (0-56) SW846 8270C
Pyrene 133 a, (46 130) SW846 8270C
131 al (46 -130) 0.88 (0-31) SW846 8270C
Phenol 81 I (10 -131) SW846 8270C
79 (10 -131) 2.5 (0-43) SW846 8270C
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Nitrobenzene-dS 94 (32 112)
89 (32 112)
Terphenyl-dl4 ' 125 (10 144)
' 126 (10 144)
2-Fluorophenol 75 (13 110)
72 {13 110·}
2·Fluorobiphenyl 86 (30 110)
86 (30 110)
Phenol-as 89 (10 113)
87 (10 113)
2,4,6-T=ibromcphencl 105 (21 122)
100 {21 , ")'}\ .,...,..,_,/
• NOrE(S):
C;.lrnl.:.ti0,1.5 ,ac: pcr/V11111:J l,dUrc rounding h.l avoid rounJ-uff errors in cai.:Jtut.::d re~u!~.
I B,,IJ print .Jcnuce~ ~·unlrnl purameu:r.i
a Spiked unalytc recovcry is ouL~ide Mated control limits.
flJ!!uanteri('a E1n'iI"onn1ental Services No. 65521
CLIENT cooEi\\•.l,"10/'.~tv-· □ 1) QUOTE / SAR NUMBER ____ _
Chain-of Custody Record
PROJ. NO. PROJECT NAME/LOCATION
~..o-U< i f-n.QQ_,j ,,l1
QUANTERRA, INC.
4101 SHUFFLE DA. N.W.
NORTH CANTON, OHIO 44720
PHONE [phone] FAX [phone] _,
'
QUANTERRA, INC. 0 3)
450 WILLIAM PITT WAY
PITTSBURGH. PA 15238
PHONE [phone] FAX [phone]
PARAMETER
QUANTERRA, INC.
5910 BRECKENRIDGE PKWY., STE. H
TAMPA, FL 3361 O
PHONE [phone] FAX [phone]
SAMPLE~S: /Signatur\ -~~ NO.,
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TRITEST, INC .
\ Bioa=y Chain of Cu,,tcdy For.n
lacilit)'Naruc P5Alf,f }&g?f;il/ r,
AJJ:cs,: --rd77e-,, C Rtt:"tg P.O ; : ___________ _
Phond ( ~o1 ) 8'3 ~ -5]lf
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Con1act: J)«{Jl,£ /Jlrr.&,,f!crz_..
NPDES ?eir.,it # : J0,,.,,.,.,;, t,g:7fir!T:/
••;,1:1\1u.:nt IJilution : ---/!~-----Test Mc!hoc: Clf4:t-£i (
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t)ut(! St.J.tkd : __ \:...-_'s..:_-_C_O~· _______ Time:
D -, " l-Y-ooi -at\! t.:-.uc1,;.: --''-----------lune:
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San:pk.s j:i.=: Hcur · ----~' / ______ _ , Hours : -",;;_--'-'3/ __
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Time· _____ .l.'.\1 ur ?:\1
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\kthoJ .:t'Tcon;poruitico to Lab: ~.Q f2'1:Cir(,,f;tP,,f;Z
'
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Rc,iJuol Chlorine: ________ ... lc_ ___ Numbc:r cf Bottle,:---'-----
' ,,cJrcss: 3909 Bc,yl Ri.• Rakigh. NC 2i607\ Phuno(9 \ 9) 334 -4984 :o, (9; 9) sJ,..SJ97
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TRITEST, INC.
' i Bioassay Chain a(Custa:ly Form
Faciliry Name: 9.-ie,c,. ur·I ~ I,,
' i
Addr=: '.:{3 41 JJ., ;./\~ D t". P.O. I: __________ _
Go~c.M .r/1.~ IO<fo 5{
Con!act: _________ _
CDunty : __ W_· _f\._i.-:'._IL_z... __ -'--Outfall/ Pipe I : ____ NPDES P""'1it I :
::' :. %Effiucnc Diluti011 : ---"~-..,.....--Test Method : CL," A.1t .. To)(
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Sample Site Description: __ )<....1,.t.,jc.,.: .....:::C~F-_;_F ___________ _
Sample Colla:tor. Pruit> A o-l.-.~ J-l: \ \
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Sample Ty~: Comomite:
I ... ,: 1,-GO Date Sllw.cd: _ _. ___ ,;,, _______ Tlllle:
Date E!ldc:l: ___ /-_7'---'-t_cJ_O _____ Tm>::
Smnpl .. pc< J,-: --~/ ______ I Haun:
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----oq,) (gt or PM
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Sample Volume: ---✓"--a.cf;=c.,-'_i-<_-_._"'5-"'--Chilled during Collo:'Jon7
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Metl!<xl ofTrmspartatica ID Lab: h io..V',d Mvd
' .......................... Chain oC Custa:ly Rel= ■ I t I • I • t ■ ■ t ■ f I I I ■ • t I ■ ■ f ■ ■
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For Ltboratory Use Only
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Aodr=: 3909 &rt! Rd.-lWcigb,. NC 27607 l'h,:,o,:(919) 83-1 -4984 Fax [phone]
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