NCD003200383_20000807_Koppers Co. Inc._FRBCERCLA RA_Monthly Progress Report 87-OCR

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August 7, 2000
Ms. Beverly Hudson
Remedial Project Manager
U.S. EPA· Region JV, 11 ,1, Floqr
North Site Management Branch
61 Forsyth Street, SW
Atlanta, GA 30303
RE: Monthly Progress Report #87
Remedial Action I
Koppers Site '. Morrisville, NC
Dear Ms. Hudson:
ThermoRetec Corporation
300 Baker Avenue, Suite 302
Concord, MA 01742
,G rhermoRetec
Smart Solutions. Positive Outcomes.
[phone] Phone
[phone] Fax
www.thermoretec.com
RECEIVED
AUG 142000
SUPERFUND SECTION
In accordance with the Unilateral Order, and on behalf of Beazer East, Inc. (Beazer),
please find attached four ( 4) copies of the July Monthly Progress Report for Remedial
Action at the Koppers Superfurld Site in Morrisville, NC.
Should you need additional infol-mation regarding this progress report, please call Mike
Slensk.a at ( 412) 208-886 7 or n{e at (978) 3 7 I• I 422
Sincerely,
ThermoRetec Consulting Corpo ation
Project Geologist
RB:cg
Enclosure
cc: D. Mattison• NC Superfund (2 copies)
D. Hails• Ecological Rest01~ation, Inc.
J. Garrett· NC Division of r,Vater Quality
P. Kilchenstein • ThennoRetec
F:\PROJECTS\0362<!\Rt:ports\Mo1lll11y\7/',l-U0.wptl
M. Slenska • Beazer
L. Faulconer• Wake County
G. Caskey -Enwood Structures
M. Helbling• Beazer
a Thermo Electron company
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MONTHLY PROGRESS REPORT #87
REMEDIAL ACTION
SITE NAME: Koppers Superfund Site
Beazer East, Inc.
Morrisville, NC
USEPA DOCKET NUMBERS: 93-09-C
PERIOD ENDING: July 31, 2000
1. PROGRESS MADE THIS MONTH
2.
3.
4.
5.
6.
7.
Remedial Action (RA) -HABITAT MITIGATION. No activities were conducted this
month.
Remedial Action (RA) -GROUNDWATER TREATMENT. The treatment system
operated throughout the month without upset. System performance was monitored
on a biweekly basis. Approximately 43,665 gallons of groundwater were extracted,
treated in the treatment plant and discharged between June 26 and July 25, 2000.
System water samples were collected on July 6, 2000 and July 17, 2000 in
accordance with the sampling schedule in the O&M manual. Samples were
submitted to Severn Trent and Alta Analytical for laboratory analysis. The
operations and sampling programs are summarized on the attached Table 1.
Remedial Action (RA) -EFFECTIVENESS MONITORING PROGRAM. No activities
were conducted this month.
Remedial Action (RA) -CORRESPONDENCE. None.
PROBLEMS RESOLVED None.
PROBLEMS ANTICIPATED
UPCOMING EVENTS
PERSONNEL CHANGES
SUBCONTRACTORS
None.
Continue System O&M.
None.
None.
ANALYTICAL DATA Analytical data from system influent and effluent sampling
received during this period are enclosed and are summarized on Table 2.
F: \PR OJ ECTS\03(i24 \Re pons \Mo nth I y\ 7 M-00 . w pd
--- - -
Date Systems Check Cummulative SV-101
(yes/no) Effluent Flow Sample
(Gallons) (yes/no)
01/04/00 yes 2.178,450 no
01/20/00 YCS 2,201,060 no
02/02/00 yes 2,223.670 no
02/18/00 yes 2,243,495 no
03/03100 vcs 2,278.733 no
03/13/00 VCS 2,313.971 no
04/12/00 yes 2,382,03 I no
04/24/00 vcs 2,450,091 no
05105/00 yes 2,472.228 no
05/15/00 yes 2,490,675 no
05/3 1/00 yes 2,520,191 no
06/14/00 ves 2,540.286 no
06n6100 yes 2.560,381 no
07/06/00 yes 2,575,437 no
07/17/00 vcs 2,604.046 yes
Notes:
- ----- -
Table I
Groundwater Treatment Operations and Sampling Program Summary
Koppers Supcrfund Sitl'
!\lorl"is\'ille, i\"orth Carolina
Jul:r 2000
SV-IOI Associated SV-304 SV-304 Associated
Sample Group Sample Sample Group
Parameters (yes/no) Parameters
no
no
no
yes 2,4-Dichloro, Phenol I
no
no
no
no
no
no
no
no
no
no
2,4-Dichloro, Phenol I yes 2,4-Dichluro, Phenol I
Associated Groups:
-
SV-305
Sample
(yes/no)
ves
ves
',/CS
yes
VCS
ves
YCS
ves
ves
ves
yes
yes
ves
ves
yes
Sampling point SV-101 is located before the Carbon Units (pretreatment)
Sampling point SV-304 is localed between the Carbon Units
SV-101 -Group I is penta and 2.4-dichlorophenol; Group 2 is dioxin
SV-304 -Group I is penta and 2,4-dichlorophenol
---
SV-305
Sample
Parameters
Penta, 2,4-Dichloro, Phenol. tax
Penta, 2.4-Dichloro, Phenol
Penta. 2.4-0ichloro. Phenol. lox
Penta, 2,4-Dichloro, Phenol. dioxin
Penta. 2,4-Dichloro, Phenol
Penta. 2.4-Dichloro, Phenol
Penta, 2,4-Dichloro. Phenol, tax
Penta, 2,4-Dichloro. Phenol
Tox
Penta, 2,4-Dichloro, Phenol
Penta, 2,4-Dichloro. Phenol
Penta. 2,4-Dichloro, Phenol, dioxin, tox
Penta, 2.4-Diehloro, Phenol
Penta, 2.4-Dichloro, Phenol
Penta. 2.4-Diehloro, Phenol, dioxin
Sampling point SV-305 is loctated after the Carbons Units (post-treatment) SV-305 -Group I is penta, phenol, and 2,4-dichlorophenol; Group 2 is dioxin and Group 3 is chronic toxicity
--
Associated
Group
1.3
I
1.3
1,2
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4
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I, 2. 3
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Table 2
Groundwater Treatment
ANALYTICAL DATA SUMMARY
Koppers Supcrfund Site
Morrisville, North Carolina
July 2000
Parameter Date
Sample
Collected
Pcntachlorophcnol 01/04/00
01120100
02/02/00
02/18/00
03/03/00
03/13/00
04/12/00
04/24/00
05/15/00
05/31/00
06/14/00
06/26/00
07/06/00
071! 7/00
2.4-Dichlorophcno! 01/04/00
01/20/00
02/02/00
02/18/00
03/03/00
03/13/00
04/12/00
04/24/00
05/15/00
05/31/00
06/14/00
06/26100
07/06/00
07/17/00
Phenol 01/04/00
01120/00
02/02/00
02/18/00
03/03/00
03/13/00
04/12/00
04/24/00
05/15/00
05/3 1/00
06/14/00
06/26/00
07/06/00
07/!7/00
Chronic Toxicity 01/0-1/00
02/0 1/00
04/12/00
05/05/00
06/14/00
Dioxin (2.3.7.8-TCDD) 02118/00
06/15/00
07117/00
Notes: All results arc in ug/L except dioxin. Dioxin darn is in picograms/L.
SV-101 -Before Carbon Units
*SV-304 -Between Carbon Units
· **SV-305 -After Carbon Units
Analytical
Sample
Location
SV-101
<ID
<10
Sample Sample
Location Location
SV-304• SV-305°
<2
<2
<2
<2 <2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<2
<10
<10
<10
<10 <10
<10
<10
<10
<10
<10
<10
<10
<10
<ID
<10 <ID
<10
<10
<10
<10 <10
<10
<10
<10
<ID
<10
<10
<10
<10
<10
<10 <10
Pass
!'ass
Fail
!'ass
Pass
<1.2
<3.94
<0.863
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ANALYTICAL REPORT
PROJECT NO. RALEIGH
Raleigh-Bi-Weekly NPDES
Lot#: C0G070251
Debbi Leuteritz
ThermoRetec
SEVERN TRENT LABORATORIES, INC •
yeronica Bortot
Project Manager
July 14, 2000
STL Pittsburgh is a part of Severn Trent Laboratories, Inc.
STL Pittsburgh
450 William Pitt Way
Pittsburgh, PA 15238-1330
Tel: [phone]
Fax: [phone]
www.stl-inc.com
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Sample Receiving:
CASE NARRATIVE
THERNIORETEC CORPORATION
Raleigh
STL Lot# C0G070251
STL Pittsburgh, PA received one sample on July 7, 2000 in good condition and at the
proper temperature.
GC/MS Semivoiatiles:
There were no problems associated with the analysis.
GC Phenols:
There were no problems associated with the analysis.
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1\lETHODS SUl\ll\IARY
COG070251
PARAMETER
Phenols by GC
Semivolatile Organic Compounds by GC/MS
References:
ANALYTICAL
METHOD
SW846 8041
SW846 8270C
PREPARATION
METHOD
SW846 3520C
SW846 3520C
SW846 ''Test Methods for Evaluating Solid Waste, Physical/Chemical
Methods", Third Edition, November 1986 and its updates.
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SAJ\fi>LE SUl\·~fARY
• COG070251
WO# SAMPLE# CLIENT SAMPLE ID
DFVAP 001 EFF/SV-305
NOTES:
• The una!yticul resulL, of the siunpka listed above nre pre11entOO on ll1e following pug cs.
-All cnlcu\::ition!I urc pcrfonnc<l before rounding to ovoid round-off errors in cukulat(:,(! rc..~ults.
-Re.~uh.ll noted ns •ND" were not detected nt or nbove the 61.lllt:<l limit.
-This report must not be reproduced, except i11 full, without the wriU<!n approval of the l:,bor.1101)'.
• Results for the following pnnuneleni nre ncv1:r repu11ctl on II dry weight basis: cu!or, currosivity, dcmily, Otrnhpuint, igniWhility, laye111, odor,
p11i11t filter te:it, pH, poro!'lity prc:murc, Tl!llCtivity, re<lox potential. i.pecific gr.1vi1y, spot lo;L~. 11oli<ls. solubilily, temperature. viscosity. un<l weight.
DATE TIME
07 /06/00 11: 05
Chain of
Custody Record
OUA•4 124 0797
CJ;en'"T\,J R i ,WIV ·, ~th
Address
300 i)"-''¥:.z..-
--
Av€..
City ') \ C:,'V\, (c (( 1 ;~~ I z;p :~·, l/ "'
Project Name I
Deo.ur R,_~)i~
ContracVPurchase OrderlOuote No. '
Sample I.D. No. and Description Date (Containers for each sample may be combined on one line)
~.:~ I <;,1--s 01 7 \iJ ,,n
' '
Possible Hazard Identification
----- ---
Project Manager ~ \<t,f .1 ,,, ~fvn
Date Chain of Custody Numbr:;r..,, 7 r) r::
1b Oil u , i
fn • <-, V
Telep /wne Ni~nber (Area Code)!Fax Number Lab Number I J C(-g T7/_ 147 u Page of
0
SiteC ntact Lab Contact Analysis (Attach fist if
Qrn:'---?.ic;,.. hvv" more s ace is needed
Carrier;Waybilrumber _rf: I (p z. 7·z,J f5o1.., 4,-r Of'.,,.J...:. Special Instructions/
Containers & Condi/ions of Receipt
Matrix PreseNatives ~
l • il .~,) ~ • ~ Ii .,~ :;::, Time li ~ § "' G ~~ ' "' ol 'i' '€ ~ !1
l\ o <" l'l< I)';. I~ Ii
(A lee may be assessed if samples are retained
'.~.~on-Hazard D Flammable D Skin Irritant D PoisonB
I Sample Disposal
0 Unknown D Return To Client D Disposal By Lab 0 Archive For Months longer than 3 months)
' -1 urn Around Time Requ1red
0 24 Hours D 48 Hours
1. Relinquished By
2. Relinquished By
3. Relinquished By
Commencs
D ?Days D 21 Days
Time
1 G Or> Gov
Time
Time
DISTRIBUTION: WHITE -Stays with the Sample; CANARY -Returned to Client with Report; PINK -Field Copy
QC Reqwrements (Specify)
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THERHORETEC CORP
Client Sample ID: EFF/SV-305
Lot-Sample# .•. : COG070251-001
Date Sampled ... : 07/06/00
Prep Date ....•• : 07/10/00
Prep Batch# ... : 0192312
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Phenol
SURROGATE
Phenol-dS
2-Fluorobiphenyl
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorophenol
2,4,6-Tribromophenol
GC/MS semivolatiles
Work Order# ... : DFVAP101
Date Received .. : 07/07/00
Analysis Date .. : 07/12/00
Method ......... : SW846 8270C
REPORTING
RESULT LIMIT
ND 10
ND 10
PERCENT RECOVERY
RECOVERY LIMITS
70 (10 -113)
66 (30 -llO)
71 (32 -ll2)
97 (10 -144)
63 ( 13 -llO)
80 ( 21 -122)
Matrix ......... : WATER
MS Run # ••••••• :
UNITS
ug/L
ug/L
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TIIERMORETEC CORP
Client Sample ID: EFF/SV-305
Lot-Sample# ... : COG070251-001
Date Sampled ... : 07/06/00
Prep Date ...... : 07/10/00
Prep Batch# ... : 0192318
Dilution Factor: 1
PARAMETER
Pentachlorophenol
SURROGATE
2,4-Dibromophenol
GC Semivolatiles
Work Order# ... : DFVAP102
Date Received .. : 07/07/00
Analysis Date •• : 07/13/00
Method .......•• : SW846 8041
REPORTING
RESULT LIMIT
ND 2.0
PERCENT RECOVERY
RECOVERY LIMITS
94 (31 -134)
Matrix .•••••••• : WATER
HS Run# ••..... :
UNITS
ug/L
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Client Lot# ... : C0G070251
MB Lot-Sample#: COGl00000-312
Analysis Date .. : 07/12/00
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Phenol
SURROGATE
Phenol-dS
2-Fluorobiphenyl
Nitrobenzene-dS
Terphenyl-dl4
2-Fluorophenol
2,4,6~Tribromophenol
NOTE S :
METHOD BLANK REPORT
GC/MS Semivolatiles
Work Order# ... : DFXVH101
Prep Date ...... : 07/10/00
Prep Batch# ... : 0192312
REPORTING
RESULT LIMIT
ND 10
ND 10
PERCENT RECOVERY
RECOVERY LIMITS
75 (10 -113)
67 (30 -110)
72 (32 -112)
100 (10 -144)
66 (13 -110)
81 (21 -122)
Cu!cu\otions nrc perfonne<l before rounding to 11voi<l round-off erron1 l.11 c:,lculatcd rcm1l11-.
Matrix •........ : WATER
UNITS METHOD
ug/L SW846 8270C
ug/L SW846 8270C
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Client Lot# ... : COG070251
MB Lot-Sample#: COGl00000-318
Analysis Date .• : 07/13/00
Dilution Factor: 1
PARAMETER
Pentachlorophenol
SURROGATE
2,4-Dibromophenol
NOTES:
METHOD BLANK REPORT
GC Semivolatiles
Work Order# .•. : DFXVR101
Prep Date ...... : 07/10/00
Prep Batch# ... : 0192318
RESULT
ND
PERCENT
RECOVERY
94
REPORTING
LIMIT
2.0
RECOVERY
LIMITS
(31 -134)
Cnkuhition.9 nrc pcrfonna.! before rounding to nvoid round-off ,;:rrot'!I i.n c:ilculah:<l resulL~.
Matrix ......... : WATER
UNITS METHOD
ug/L SW846 8041
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I LABORATORY CONTROL SAHPLE EVALUATION REPORT
I GC/MS Semivolatiles
Client Lot # ••• : COG070251 Work Order# ... : DFXVH102-LCS Matrix .......... : WATER
I LCS Lot-Sample#: COGl00000-312 DFXVH103-LCSD
Prep Date ...... : 07/10/00 Analysis Date .. : 07/12/00
Prep Batch# ... : 0192312
I Dilution Factor: 1
PERCENT RECOVERY RPO
PARAMETER RECOVERY LIMITS RPO LIMITS METHOD I 2-Chlorophenol 69 (19 -124) SW846 8270C
71 (19 -124) 2.1 (0-43) SW846 8270C
1,4-Dichlorobenzene 67 (28 -llO) SW846 8270C
I 68 (28 -llO) 1.5 (0-36) SW846 8270C
N-Nitrosodi-n-propyl-37 (30 -ll5) SW846 8270C
amine
I 39 (30 -ll5) 3.7 (0-36) SW846 8270C
1,2,4-Trichloro-68 (31 -llO) SW846 8270C
benzene
I 68 (31 -llO) 1.2 (0-37) SW846 8270C
4-Chloro-3-methylphenol 69 (29 -124) SW846 8270C
I 68 (29 -124) 1.2 (0-55) SW846 8270C
Acenaphthene 73 (39 -ll8) SW846 8270C
71 (39 -ll8) 1.9 (0-35) SW846 8270C
4-Nitrophenol 73 (19 -144) SW846 8270C I 73 (19 -144) 0.91 (0-34) SW846 8270C
2,4-Dinitrotoluene 76 (47 -131) SW846 8270C
77 (47 -131) 1.0 (0-32) SW846 8270C
I Pentachlorophenol 80 (10 -140) SW846 8270C
81 (10 -140) 0.99 (0-56) SW846 8270C
Pyrene 103 (46 -130) SW846 8270C
I 102 ( 46 -130) 1.8 (0-31) SW846 8270C
Phenol 63 (10 -131) SW846 8270C
63 (10 -131) 0.63 (0-43) SW846 8270C
I PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
Phenol-dS 72 (10 -113 I
I 71 (10 -113)
2-Fluorobiphenyl 71 (30 -110)
68 (30 -110)
I Nitrobenzene-dS 73 (32 -112 I
71 (32 -112 I
Terphenyl-dl4 109 (10 -144)
106 (10 -144) I 2-Fluorophenol 61 ( 13 -110)
61 (13 -110)
2,4,6-Tribromophenol 87 (21 -122)
I 85 (21 -122)
(Continued on next page)
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LABORATORY CONTROL SAMPLE EVALUATION REPORT
GC/MS Semivolatiles
Client Lot# ... : C0G070251 Work Order# ... : DFXVH102-LCS Matrix ......... : WATER
LCS Lot-Sample#: C0Gl00000-312 DFXVH103-LCSD
NOTE S :
Cnku!ntions ure pcrfonned before rounding to iivoi<l rouml•off errors in cakul:,tcd r~·sulL~.
Bo!d print denote.~ control pnrumetcn;
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LABORATORY CONTROL SAMPLE EVALUA'J'ION REPORT
GC Semivolatiles
Cl.ient Lot# ... : COG070251
COGl00000-318
07/10/00
0192318
Work Order# ... : DFXVR102-LCS
DFXVR103-LCSD
Analysis Date •• : 07/13/00
Matrix ••••••.•. : WATER
LCS Lot-Sampl.e#:
Prep Date ...... :
Prep Batch# .•. :
Dilution Factor: 1
PERCENT RECOVERY
PARAMETER RECOVERY LIMITS
Pentachlorophenol 88 (50 -126)
94 (SO -126)
PERCENT
SURROGATE RECOVERY
2,4-Dibrornophenol 88
94
NOTES:
Cnkulntions nre perfonne.d before rounding to nvoi<l round-off crrori; in c:1!cu\:itcd result~.
Dold print denotc.B control pnmmeters
RPO
RPO LIMITS METHOD
SW846 8041
6.2 (0-20) SW846 8041
RECOVERY
LIMITS
(31 -134)
(31 -134)
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ANALITICAL REPORT
PROJECT NO. RALEIGH
Raleigh-Bi-Weekly NPDRS
Lot#: COG18D12D
Debbi Leuteritz
ThermoRetec
SEVERN TRENT LABORATORIES, INC.
Veronica Bertot
Project Manager
July 24, 200D
STL Pittsburgh is a part of Severn Trent Laboratories, Inc.
STL Pittsburgh
450 William Pitt Way
Pittsburgh, PA 15238-1330
Tel: [phone]
Fax: [phone]
www.stl-inc.com
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Sample Receiving:
CASE NARR,\TIVE
THERfv10RETEC CORPORATION
Raleigh
STL Lot# C0Gl 80120
STL Pittsburgh, PA received samples on July 18, 2000 in good condition and at the
proper temperature.
GC/MS Semivolatiles:
There were no problems associated with the analysis.
CC Phenols:
There were no problems associated with the analysis.
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METHODS SUMMARY
COG180120
PARAMETER
Phenols by GC
Semivolatile Organic Compounds by GC/MS
References:
ANALYTICAL
METHOD
SW846 8041
SWB46 B270C
PREPARATION
METHOD
SW846 3520C
SW846 3520C
SWB46 "Test Methods for Evaluating Solid Waste, Physical/Chemical
Methods", Third Edition, November 1986 and its updates.
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SAMPLE SUMMARY
COG180120
WO# SAMPLE# CLIENT SAMPLE ID
DGDSK 001 EFF/SV-305
DGDSL 002 EFF/SV-102
DGDSM 003 EFF/SV-304
NOTE(S:
-The nnulyticul results of the srunple., listed t1bove are presented on the following pagca.
-All cnlcul.o.tiona ore performed before rounding to avoid round-off errors in cn\culnted results.
-Results note.cl ns "ND" were not detected nl or above the el.Bled limit.
-11iia report must not be reproduce.d, except in full, without the written npprovol of the \uborntory.
• Results for the following pnrumctcr.i ure never n::ported on u dry weight bnsis: color, corrosivity, density, nnshpoint, ignitnbility, layers, odor,
paint filter test, pH, porosity pre.~sure, reactivity, redox potential, ~pecific grnvity, spot test~. imlids, solubility, temperature, viscosity, and weight.
DATE TIME
07/17/00 12:40
07/17/00 12:50
07/17/00 12:55
-- - --- --Chain of
Custody Record
OUA•4124 0797
Client ~~ _./) . -£)V\".,, ~· J 4, J
Address
,so,-, R-\t, A,..,, ,
CdCor'\c_erJ MA-I z;;c;; <I l.
ProjeRme • \ ru,.. -z.,, ,. ~~o.;,., Lo
Contract/Purchase Order/Cluo/e No. '
Sample I.D. No. and Description Date (ContairnJrs for each sampfe may be combined on one line)
Project Manage?c 0 le,·\cL. ... sh ,~
Telephone Number (Area Code)/Fax Number
~ 1t -~ 1 I -I <.j Z ~
Site Contact lr?:--n,...~ Lab Contact
Ca;t~;c;:;~ L (p z, 7 zJ c./C, i:c ..,_ .....
Matrix Containers & ~ Preservatives
I ! ~ "' Q cc )>CC Time ti 6 ~ Q i3 Q ~Q • ;,; 11 rq~ "' "' cc
~
o%
Ei=c: (~v-3o~ 1•11-0 o l"'\O f.. i,. 'I-. "I-' Sv-/9-Z.. I IZSo "Is 11' '(.
SI/ -~o<f ~ 17 C.<.-'i. he: ,,(
Possible Hazard Identification I Sample Disposal
i,{ Non-Hazard 0 Flammable 0 Skin Irritant 0 PoisonB 0 Unknown O Return To Client i°'irnisposal By Lab D Archive For
Tum Around Time Reqwred QC Reqwrements (Specify)
D 24 Hours D 14 Days D 21 Days
1. Relinquished By Time oo ''°o 1. Receive ~y \
lY\;,, ,,,.,..t...--
2. Relinquished By Time 2. Received By
3. Relinquished By Time
Comments
DISTRIBUTION: WHITE -Stays with the Sample; CANARY -Returned to Client with Report; PINK -Field Copy
-- -
~ -r/1I1a11terra
Date Chain of Custody Numbf') 7 ') [:"
1-n-oa ~ I ' ,) 1
Lab Number
Pnge l of I
Analysis (Attach list if
more snace is needed
Special Instructions/
Conditions of Receipt
(A lee may be assessed if samples are retained
Months longer than 3 months)
Date Time
Dale Time
Date Time
7LyvJ 'O ~u
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THERMORETEC CORP
Client Sample ID: EFF/SV-305
Lot-Sample# •.. : COG180120-001
Date Sampled •.. : 07 /17 /00
Prep Date .•...• : 07 /19/00
Prep Batch# ••. : 0201261
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Phenol
SURROGATE
2-Fluorobiphenyl
Nitrobenzene-d5
Terphenyl-d14
GC/MS Semivolatiles
Work Order# .•. : DGD5K101
Date Received •. : 07/18/00
Analysis Date .. : 07/24/00
Method ........• : SW846 8270C
REPORTING
RESULT LIMIT
ND 10
ND 10
PERCENT RECOVERY
RECOVERY LIMITS
52 (30 -110)
56 (32 -112)
80 (10 -144)
Matrix ......... : WATER
MS Run# ....... :
UNITS
ug/L
ug/L
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THERMORETEC CORP
Client Sample ID: EFF/SV-3O5
Lot-Sample# ... : COG180120-001
Date Sampled ... : 07/17/00
Prep Date .•••.• : 07 /20/00
Prep Batch# •.. : 0203110
Dilution Factor: 1
PARAMETER
Pentachlorophenol
SURROGATE
2,4-Dibromophenol
GC Semivolatiles
Work Order# ... : DGD5Kl02
Date Received .. : 07/18/00
Analysis Date .. : 07/24/00
Method ......... : SW846 8041
REPORTING
RESULT LIMIT
ND 2.0
PERCENT RECOVERY
RECOVERY LIMITS
93 (31 -134)
Matrix ......... : WATER
MS Run# ....... : 0203017
UNITS
ug/L
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THERMORETEC CORP
Client Sample ID: EFF/SV-1O2
GC/MS Semivolatiles
Lot-Sample # ... : COG180120-002 Work Order # ... : DGD5Ll01
Date Sampled ... : 07/17/00 Date Received .. : 07/18/00
Prep Date ••...... : 07/19/00 Analysis Date .. : 07/24/00
Prep Batch # ..• : 0201261
Dilution Factor: 1 Method ......... : SW846 8270C
REPORTING
PARAMETER RESULT LIMIT
2,4-Dichlorophenol ND 10
Phenol ND 10
PERCENT RECOVERY
SURROGATE RECOVERY LIMITS
2-Fluorobiphenyl 44 (30 -llO)
Nitrobenzene-dS 45 (32 -112)
Terphenyl-dl4 65 (10 -144)
Matrix ................. : WATER
MS Run# ••••.•• :
UNITS
ug/L
ug/L
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THERMORETEC CORP
Client Sample ID: EFF/SV-3O4
Lot-Sample# ... : COG180120-003
Date Sampled ... : 07/17/00
Prep Date ...... : 07/19/00
Prep Batch# ... : 0201261
Dilution Factor: 1
PARAMETER
2,4-Dichlorophenol
Phenol
SURROGATE
2-Fluorobiphenyl
Nitrobenzene-dS
Terphenyl-dl4
GC/HS Semivolatiles
Work Order# ... : DGDSM101
Date Received .. : 07/18/00
Analysis Date .. : 07/24/00
Matrix .• _ ...... : WATER
MS Run# ....... :
Method ......... : SW846 8270C
REPORTING
RESULT LIMIT UNITS
ND 10 ug/L
ND 10 ug/L
PERCENT RECOVERY
RECOVERY LIMITS
67 (30 -llO)
62 (32 -ll2)
77 (10 -144)
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METHOD BLANK REPORT
GC/HS Semivolatiles
Client Lot# ... : COG180120 Work Order# ••. : DGFF8101
MB Lot-Sample#: COG190000-261
Analysis Date •. : 07/24/00
Dilution Factor: 1
PARAMETER
Phenol
2,4-Dichlorophenol
SURROGATE
2-Fluorobiphenyl
Nitrobenzene-d5
Terphenyl-dl4
NOTE S :
Prep Date ...... : 07/19/00
Prep Batch# ... : 0201261
REPORTING
RESULT LIMIT
ND 10
ND 10
PERCENT RECOVERY
RECOVERY LIMITS
49 (30 -110)
48 (32 -112)
82 (10 -144)
Culculutions ure pcrfonned before rounding to uvoid round•off error.I in cnlculuted results.
Matrix ......... : WATER
UNITS METHOD
ug/L SW846 8270C
ug/L SW846 8270C
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METHOD BLANK REPORT
GC Semivolatiles
Client Lot# ... : C0G180120 Work Order# ... : DGK95101
MB Lot-Sample#: COG210000-110
Analysis Date .. : 07/24/00
Dilution Factor: 1
PARAMETER
Pentachlorophenol
SURROGATE
2,4-Dibromophenol
NOTE S :
Prep Date ...... : 07/20/00
Prep Batch# ... : 0203110
REPORTING
RESULT LIMIT
ND 2.0
PERCENT RECOVERY
RECOVERY LIMITS
129 (31 -134)
Cn\culutions nre pcrfonned before rounding to nvoid round-off crrore in cnlculutro results.
UNITS METHOD
ug/L SW846 8041
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LABORATORY =NTROL SAMPLE EVALUATION REPORT
GC/MS Semivolatiles
Client Lot# ... : COG180120 Work Order# •.• : DGFF8102-LCS
DGFF8103-LCSD
Analysis Date •• : 07/24/00
Matrix ......... : WATER
LCS Lot-Sample#: C0Gl90000-261
Prep Date ••.••. : 07/19/00
Prep Batch# ••• : 0201261
Dilution Factor: 1
PARAMETER
2-Chlorophenol
4-Chloro-3-methy1pheno1
4-Nitrophenol
Pentachlorophenol
Phenol
SURROGATE
2-'Fluorobiphenyl
Nitrobenzene-dS
Terphenyl-dl4
NOTES :
PERCENT
RECOVERY
52
55
54
56
51
57
58
62
45
47
RECOVERY
LIMITS
(19 -124)
(19 -124)
(29 -124)
(29 -124)
(19 -144)
(19 -144)
(10 -140)
(10 -140)
(10 -131)
(10 -131)
PERCENT
RECOVERY
56
56
55
55
81
84
Culcul11tions nre perfonned before rounding to nvoid round-off errors in c11lculnte<l results.
Bold print denotes control pnrameteni
RPO
RPD LIMITS METHOD
SW846 8270C
4.8 (0-43) SW846 8270C
SW846 8270C
3.2 (0-55) SW846 8270C
SW846 8270C
9.9 (0-34) SW846 8270C
SW846 8270C
6.9 (0-56) SW846 8270C
SW846 8270C
4.4 (0-43) SW846 8270C
RECOVERY
LIMITS
(30 -110)
(30 -110)
(32 -112)
(32 -112)
(10 -144)
(10 -144)
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LABORATORY CONTROL SAMPLE EVALUATION REPORT
GC Semivolatiles
Client Lot# ... : COG180120 Work Order# •.. : DGK95102
LCS Lot-Sample#: COG210000-110
Prep Date ...... : 07/20/00 Analysis Date .. : 07/24/00
Prep Batch# ... : 0203110
Dilution Factor: 1
PARAMETER
Phenol
Pentachlorophenol
SURROGATE
2,4-Dibrornophenol
NOTES:
PERCENT
RECOVERY
74
84
RECOVERY
LIMITS
(52 135)
(50 -126)
PERCENT
RECOVERY
90
C11lcuh1tio1LS ure perfonned before rounding to uvoid round-off errors in cnlcui::J.ted results.
Bold print denotes control pnrnmctcrs
Matrix ••.....•. : WATER
METHOD
SW846 8041
SW846 8041
RECOVERY
LIMITS
(31 -134)
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-➔-ALTA
August 2, 2000
Alta Batch I.D.: 8801
Ms. Rita Bauer
ThermoRetec Consulting Corporation
300 Baker A venue
Suite 302
Concord, MA 01742
Dear Ms. Bauer,
Enclosed are the results for the one groundwater sample received at Alta Analytical Laboratory on
July 18, 2000. These samples were analyzed using EPA Method 8290 for 2,3,7,8-TCDD. A
standard turnaround time was requested for this work.
The following report consists of a Sample Inventory (Section I), Analytical Results (Section II) and
the Appendix. The Appendix contains a copy of the chain-of-custody, a list of data qualifiers and
abbreviations, our current certifications, diskette deliverables, and copies of the raw data.
Alta Analytical Laboratory remains committed to serving you in the most effective manner.
Should you have any questions or need additional information and technical support, please do not
hesitate to contact me. Thank you for choosing Alta part of your analytical support team.
Sincerely,
,,.. ... --.. , J
'-...,_ ' ' ".'
·'-(,1...,LLl: V' CC~-'--(!....~ I
\ _ ___.Shelly ~~Weagra f ' \/\
HRMSlservicesl oor 1hator
Alta Analytical Laboratory Inc.
5070 Robert J. Mathews Parkway
El Dorado Hills, CA 95762
FAX [phone]
[phone]
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Section I: Sample Inventory Report
Date Received: 7 /18/00
Alta Lab. ID Client Sample ID
8801-001 EFF/SV-305
1 .. -ALTA
I , .. -ALTA
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I SECTION II.
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METHOD BLANK
Matrix: Aqueous
Compound
2,3,7,8-TCDD
Internal Standards
13C-2,3,7,8-TCDD
Clean-up Recoven· Standard
37Cl-2,3,7,8-TCDD
Date Analyzed
DB-5: 7/28/00
Analyst: .IMH
TCDD
EPA METHOD 8290
Date Received: NA
Date Extracted: 7/24/00
Sample Amount: 1.000 L
Cone. UL
NU 0.573
94.5
"/4,R
91.4
Page I of I
MDL
0.711
, .. -ALTA
Lab ID: 0-MB00l
QC Set: 810
Units: pg/L
Qualifier
Reviewer: /;6
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OPRRESULTS
Lab ID: OPR00I
Matrix: Aqueous
Compound
2,3,7,8-TCDD
Internal Standards
BC-2,3,7,8-TCDD
Clean-up Recovery Standard
37Cl-2,3,7,8-TCDD
Date Analyzed
DB-5: 7/28/00
Analyst: .JMI-I
TCDD
EPA METHOD 8290
Date Received: NA
Date Extracted: 7 /24/00
Sample Amount: 1.000 L
Spike
Cone.
Amount
Found
10.0
Spike
Cone.
100
Spike
Cone.
40.0
8.04
93.8
90.0
Page I of I
IA -ALTA
QC Set: 810
Units: ng/mL
OPR Limits
7 -13
OPR Limits
40-135
OPR Limits
40 -135
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TCDD
EPA METHOD 8290
Sample ID:
Project:
EFF/SV-305
BEAZER/RALEIGH
Matrix: Aqueous
Sample Amount: 1.040 L
Compound
2,3,7,8-TCDD
Internal Standards
13C-2,3, 7,8-TCD D
Clean-up Recovcrv Standard
37Cl-2,3,7,8-TCDD
Date Analyzed
DB-5: 7/31/00
Analyst: .IMl·I
Date Received:
Date Extracted:
Cone.
ND
¾R
93.0
¾R
86.7
Page I of I
7/18/00
7/24/00
DL MDL
0.863 0.711
/1,,. -ALTA
Lab ID: 8801-001
QC ~et 810
%Solids -0.260
Units: ~
Qualifier
Reviewer: ~ -~-
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: I
A
B
C
D
E
F
G
H
Cone.
D.L.
NA
SIN
*
ND
MPC
DATA QUALIFIERS & ABBREVIATIONS
The amount detected is below the Method
Calibration Limit.
This compound was also detected in the blank.
The amount detected is less than five times the Method
Quantitation Limit.
The amount reported is the maximum possible concentration.
The detection limit was raised above the Method Quantitation
Limit due to chemical interferences.
This result has been confirmed on a DB-225 column.
This result has been confirmed on a SP-233] column.
The signal-to-noise ratio is greater than 10:1.
Chemical Interference
Concentration
Detection Limit
Not applicable
Signal-to-noise
See Cover Letter
Not Detected
Maximum Possible Concentration
J&.
"""""" ALTA
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CURRENT CERTIFICATIONS
Bureau of Reclamation-Mid-Pacific Region---(MP-470, Res-I. I 0)
Commonwealth of Kentucky---(Ce11ificate No. 90063)
Commonwealth of Virginia---(Certificate No. 00013)
J .. -ALTA
State of Alaska, Department of Environmental Conservation---(Certificate No. OS-00197)
State of Arkansas, Department of Health---(Approval granted through CA certification)
State of Arkansas, Department of Environmental Quality---
State of California---(Certificate No. 1640)
State of Connecticut---(Certificate No. PI-1-0182)
State of Florida---(Certificate No. 87456)
State of Louisiana---(Certificate No. 98-33)
State of Mississippi---(Approval granted through CA certification)
State of Nevada---(Certificate No. CA413)
State of New York, Department of Health---(Certificate No. 1 I 411)
State of North Carolina---(Certificate No. 06700)
State of North Dakota, Department of Health---(Certificate No. R-078)
State of Oregon---
State of Pennsylvania---(Certificate No. 68-490)
State of South Carolina---(Certificate No. 8700200 I)
State of Texas -(Certificate No. TX247-2000A)
State of Tennessee---(Certificate No. 02996)
State of Utah---(Certificate No.E-201)
State of Washington, Department of Ecology---(Certification No. C091)
State of Wisconsin---(Certificate No. 998036160)
State of Wyoming---(Ref: SES-LB)
U.S. Army Corps of Engineers
U.S. 5 EPA Region
May2000
-~'"
J ..
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CHAIN OF CUSTODY RECORD
Relinquished by: (Signa.cun: and Primed Name)
Relinquished by: (Signa1ure and Prin1cd Name)
Sll!P TO:
Alta Analy1ical Laboratory
5070 Robert J. Mathews Parkway, Suite 2
I;\ Dor._do Hills CA 9.5762
\9\1., ! cp;, ·-iG'iO
ATTN: ________________ _
Special Ins1ructions/Comments:
Received by: (Signature and Printed Name)
Shipment JD:
Circle Oi Add
Analysis(es)
Requested
------------------------
/'!. ~\.~-----------------------------------------
; if,·\\, i,_---.A,---------------------------------------
'N
Date:
7--oc,
Date: 7 -... C'<'.)
Date:
Date:
Time:
Time:
imittn:r::x/:g,,;r:Br/MW:~
:.v/m;\:!NW1/.-,,~·
tir:/tt.t'r·:;,;., ,,.,tc:c:,,-_,/·ts:::,,-1:v m,rw.z,,,,~,.,~r:::c,?--/J:':tr1;~\W
<Z:C::%%:W.1/-,,::'''~-'::,c:,:z,,:/N\: ,ii
0·11r.w· /4'if$WAW,r//C:::JHU,fil
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tWFT.P/~W/:}tfHfi
·fa:t}¼&fKtw1/-&::t+%S::C:';l
TAT (Analytical Tum-Around Times) I = 7 days 2 = 14 days 3 = 21 days 4 = 28 days
Container Tyix:s: C = Core Tube T = Train A = I Liter Amber
G ~ Glass Jar P ~ PUF O ~ Other --------------
SEND DOCUMENTATION AND RESULTS TO:
Name: &•'<•~ 6,....,...,,.-
Company: ES $1 -?"R J 1:LV··),M..o k~
Address: ·3;.,o C A-k /!,:'.-A vr,
Phone:~7'i_ ---37 i -I'-! l 't--Fax: ...,K ·-- ---
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STANDARD OPERATING PROCEDURE
Attachment 1 0.B.1
SAMPLE LOG-IN CHECKLIST
AL TA Project No.: ----'~"----....:..._Q,,--+{ __ ClientfProtocol No.,_..c;i_V-'(,~;1 _______ _
I. Date Samples Arrived: .:J.-l'E.;.._CX> Initials: ,lk~ Location: d✓t<--1 7
2. Time I Date logged in: 7-/f-OD l)tp,D Initials: )/f.;:t:' Location: t,.J/,-(__ , .
3. Samples Arrived By: (circle) ('FedEx) UPS World Courier Other:
4. Shipping Preservation: (circle) ~Blue Ice / Dry Ice / None Temp °C (-:)
YES NO NA
5, Shipping Container(s) Intact"? If not, describe condition in comment section. X
6. Shipping Container(s) Custody Seals Present? )(_
Intact? If not intact, describe condition in comment section. ,<
7. Shipping Documentation Present? (circle) Shipping Label e)
Tracking Number ~ ;2.'.253 t:>16 2 C('EJ'f. '<
8. Sample Custody Seal(s) Present? No. of Seals or Seal No. >< Intact? -If not intact, describe condition in comment section. ><--
9. Sample Container Intact? If no, indicate sample condition in comment section. y
10. Chain of Custody (COG) or other Sample Documentation Present? 'f
11. COG/Documentation Acceptable? If no, complete COC Anomaly Form. f
Shipping Container (circle): ~ -(Ret~ 12. Client or Return or Disposed
13. Container(s) and/or Bottle(s) Requested? X
14. Sample Control Check In/Out Log Completed? (HRMS Only) Y-
15. Drinking Water Sample? (HRMS Only) If yes, Acceptable Preservation? Y or N
Preservation Info From? (circle) coc or Sample Container or None Noted ~
16. Number of Samples Received: /{/,4
Name: ___ =-c-----::-----,-c--,--,-,-c-=-------
(Signature Required for LCMS Only)
Date Samples Reconciled: _____ _
Comments:
SOP# CH10Br12, Page 4 of 6