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HomeMy WebLinkAboutNCD003200383_20000512_Koppers Co. Inc._FRBCERCLA RA_One-Year Groundwater Monitoring 1998 - 2000-OCR05/15/2000 02..:_JS F.U 9783~99279 Fax Cover Sheet ---·· ,S"<O"'--.. -----·---·-----··--~ g:\ _l Message'-': __ lei 001 ThcrnioRetec Carµoration Joo B.akt!t Ave., Suite 302 Co1lcorci, MA 01/1,2 ~ThermoRetec Pag~s: Proj. No.: 5r,.art So/uLions, Paritivf! Or.it.comes. (g78) l7J•l,.22 i''loi:i,1~ (978) 31:.-14.:.is r"ax www.t11,•, ,na ret~c.t".1111 .. -·--· ,-, ().. ~) ~3«<.;) 4-/0 Date'. ~o~ 1 u.~er<~ ~o"" M:K( .S lc"!i:'k.r.. ..!J,.,.,.__1,. ~oc.... (}_\ J,_ .f\t() ~ /y__(.f.\W. -1.::.\.-,.t ~ l \ow~"-~ N:JJ ~~J 711.lol< ~ 1v..: e,\l C.c-...\1,. ( ct,g-s1l-/'i~J.) tD t:A..ow yov...'IJ< r~ce~-vt4 JJ.-..,~. Hardcopy to Follow· □ □ Yes No ---,-.. ----·--···-·- A Subsidi:Hy r,t 1 h1wno TPr r.iTi.:cll, lnc .. 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Afu:r,,,.,-d w tTro-.--.,,1 O>'<"<nil',ht. 16:55 C~:u 15:10 CLe.;.r 10:15 Hro,.n 10.00 Clrn;dy \Od5 Eru,,.TI, t.urbid \6:00 Pl•q,,cd dry, 1Uowc-d to HCOVTJ a'>'C::J'Tiight "" rc-c,.>:<y/no iam1>'.c- 1&00 Clear, 1wtet od.o:, umpk h•d o&n \2:!iD Eit11 bro-,o,,-,, w.-bid 15:00 Ught browr, 1000 C~ar • • 0 "' ' ~ "' ' N 0 0 0 0 '-' '-' 0, .,, ,. "' "' ,..., lco '-' "' "' "' N .... "' 1§1 0 0 N . . • • ThermoRetec Corporation 9 Damonmilt Square, Suite 3A Concord, MA 01742·2851 .ThermoRetec March 20, 2000 Ms. Beverly Hudson Remedial Project Manager Superfund Branch Waste Management Division .RECEIVED MAR 21 2000 United States Environmental Protection Agrofl!RFUND SECTION Region IV 61 Forsyth Street, 11 th Floor Atlanta, GA 30303 Smart Solutions. Positive Outcomes. (978) 371-1422 Phone (978) 369-9279 Fax www.thermoretec.com RE: One-Year Groundwater Remedial Action Monitoring Report -Revised Koppers Company NPL Site Morrisville, Wake County EPA #ILD 000 819 946 Dear iv!s. Hudson: On behalf of Beazer East, Inc. (Beazer), ThermoRetec is submitting two copies of the One-Year Groundwater Remedial Action Monitoring Report -Revised for the Koppers Company NPL site in Morrisville, North Carolina. This document has been revised to reflect the comments contained in the North Carolina Department of Environment and Natural Resources's letter of February 14, 2000. The following changes were made in response to the noted comments: Comment I. Table 3 has been revised to indicate that the sampling date for well C-27B was January 23, 1998. / Comment 2. Pages 2 and 3 of Table 6 had been inadvertently omitted during copying and have been inserted in to these complete documents. /Comment 3. Pages 1 and 2 of Table 7 had been inadYertently omitted during copying and have been inserted in to these complete documents. /Comment 4. Page I of the Field Data Sheet in Appendix A for Groundwater Sampling for the January 1998 groundwater sampling event had been inadvertently omitted during copying and has been inserted in to these complete documents. ✓Comment 5. Graphs for 2,,4-dichlorophenol time trends for monitoring wells C-27B, C- 12A, C-11B, C-IOB, C-IOA, C-09B, and C-01B which were omitted during copying have been inserted in to these complete documents. A subsidiary of Thermo Terra Tech inc., a Thermo Electron company Ms. Beverly Hudson March 20, 2000 Page 2 • • .ThermoRetec We apologize for these omissions If you have any questions or require additional information, please feel free to contact me at (978) 371-1422 or Mr. Mike Slenska at (412) 208-8867. Best regards, ThermoRetec Consulting Company Laura A. Kelmar, P.E. Groundwater Monitoring Program Manager LK:mvc Enclosure cc: D. Mattison, NCDENR M. Slenska , Beazer (w/o enc) HP RO J E CTS\0362 4\CORRES'2000\H u<ls03 20. wpd . . . JAMES a: HUNT JR. GOVERNOR BILL HOLMAN SECRETARY • NOR.CAROLINA DEPARTMENT OF ENVIRONMENT. AND NATURAL RESOURCES DIVISION OF WASTE MANAGEMENT Ms. Beverly Hudson Remedial Project Manager Superfund Branch Waste Management Division February 14, 2000 United States Environmental Protection Agency Region IV 6 I Forsyth Street, I I th Floor Atlanta, GA 30303 Re: One-Year Groundwater Remedial Action Monitoring Report -Revised Koppers Company NPL Site Morrisville, Wake County Dear Ms. Hudson: The Superfund Section of the North Carolina Department of Environment and Natural Resources (NC DENR) has received the One-Year Groundwater Remedial Action Monitoring Report -Revised for the Koppers Company National Priorities List (NPL) Site. The Superfund Section has reviewed this document and offers the attached comments. We appreciate the opportunity to comment on this document. If you have any questions, please feel free to call me at (919) 733-2801, extension 349. Sincerely, PJ David B. Mattison, CHMM Environmental Engineer Superfund Section Attachment cc: Mike Slenska, Beazer East, Inc. ljllfjj ••·••·• 1646 MAIL SERVICE CENTER, RALEIGH, NORTH CAROLINA 27699-1646 401 OBERLIN ROAD, SUITE 150, RALEIGH, NC 27605 PHONE 919-733-4996 FAX 919-715-3605 AN EQUAL OPPORTUNITY/ AFFIRMATIVE ACTION EMPLOYER• 50% RECYCLE0/10% POST-CONSUMER PAPER Ms. Beverly Hudson February 14, 2000 Page I • • ONE-YEAR GROUNDWATER REMEDIAL ACTION MONITORING REPORT -REVISED Table 3 Summary of Field Purging and Sampling Parameters I. Table 3 indicates that the sample date for groundwater monitoring well C-27B is January 22, 1998. However, the Field Data Sheet for Groundwater Sampling included in Appendix A indicates that the sampling date for C-27B is January 23, 1998. Please clarify this discrepancy. Table 6 Summary of Equipment Blank Results 2. Page 2 and Page 3 (of three pages) of Table 6 were inadvertently omitted. Please correct this oversight. Table 7 Summary of Field Duplicate Results 3. Page 1 and Page 2 (of three pages) of Table 7 were inadvertently omitted. Please correct this oversight. Appendix A Field Data Sheets and Chain-of-Custody Forms 4. Page 1 ( of two) of the Field Data Sheet for Groundwater Sampling for the January 1998 groundwater-sampling event was inadvertently omitted from Appendix A. Please correct this oversight. Appendix C Pentachlorophenol and 2,4-Dichlorophenol Time Trends 5. The graph of 2,4-dichlorophenol time trends for groundwater monitoring wells C-27B, C- 12A, C-1 IB, C-lOB, C-lOA, C-09B, and C-OlB were inadvertently omitted. Please correct this oversight. • Tanuary 19, 2000 Ms. Beverly Hudson Remedial Project Manager U.S. EPA -Region IV, 11 th Fl~ECEI\/En North Site Management Branch · --- 61 Forsyth Street, SW JAN Z l ZOOO Atlanta, GA 30303 • ThermoRetec Corporation 9 Damonmill Square, Suite 3A Concord, MA 01742-2851 .ThermoRetec Smart Solutions. Positive Outcomes. (978) 371-1422 Phone (978) 369-9279 Fax www.thermoretec.com SUPERFUND SECTION RE: One-Year Groundwater Remedial Action Monitoring Report -Revised Koppers Site -Morrisville, NC Dear Ms. Hudson: Enclosed please find the revised One-Year Groundwater Remedial Action Monitoring Report for the Koppers Superfund Site, Morrisville, NC. This revision incorporates the changes originally submitted to your office by Fluor Daniel-GT! on October 29, 1998. Should you need additional information regarding this report, please call Mike Slenska at (412) 208-8867 or me at (978) 371-1422. Sincerely, ThermoRetec Consulting Corporation ~~L v"' Q CQ~ Laura A. Kelmar, P.E. Groundwater Monitoring Program Manager Enclosure cc: D. Mattison -NC Superfund M. Slenska -Beazer f,lprojects\3624\corres\2000\Hudson_0 119.wpd A subsidiary of Thermo Terra Tech Inc., a Thermo Electron company -' . ;·: --. ' ,, -· -: : •., . ·•··· / .... '.,;.k.,. ''!--). NORTH AROLINA DEPARTMENT OF ENVIRONMENT AND NATURAL RESOURCES DIVISION OF WASTE MANAGEMENT August 11, I 999 Memorandum TO: FROM: RE: Mr. Jay Zimmerman Division of Water Quality David B. Mattison, cHMM@ Environmental Engineer Superfund Section Proposed Remedial Action Groundwater Monitoring Program Koppers Company, Inc. NPL Site Morrisville, Wake County ThermoRetec Consulting Corporation, on behalf of Beazer East, Inc., has completed the Proposed Remedial Action Groundwater Monitoring Program for the Koppers Company, Inc. National Priorities List (NPL) site. The document being reviewed is attached. Please distribute this document to the appropriate personnel and submit any comments to the NC Superfund Section. We would like to have the views and permitting requirements of the Groundwater Section by September I, 1999 in order to transmit any comments to the United States Environmental Protection Agency in an expeditious.manner. If you or your staff have any questions or comments, please feel free to call me at (919) 733-2801, extension 349. Attachment 401 OBERLIN ROAD, SUITE 150, RALEIGH, NC 27605 PHONE 919-733-4996 FAX 919-715-3605 AN EQUAL OPPORTUNITY/ Al'"FIRMAT!VE ACTION EMPLOYER· SO% RECYCLED/10% POST-CONSUMER PAPER 07/29/99 08:33 'B'H2 205 8869 BEAZER EAST INC • BEAZER EAST, INC., ONE OXFORD CENTRE, SUITE 3000, PITTSBURGH, PA 15219 FAX COVER SHEET DATE: TIME: PHONE: TO: ;)"-~ i\A.,;,;tt; ~ o - Nc-.,e.t-17.. FAX: "11 C.., • +Jl · fGf/ FROM M;k (\e,,.._;l,,"" Beazer East, Inc. PHONE· (412) 208-6~} FAX: (412) 208-8869 RE: CC· Number of pages including cover sheet: ..c..i_l _ Message GQ~v-'""'-'\-t ( °'-"--• i e"r GvJ ~r~r+) f M, f., r-eJ ..r Q~ I ~,,,___ ..... ~D 'Y.o'--, Cfkv'.Q,v-J /4 ~~ o.~ €._ ~ ~J-~-="'~"""~r ~--"""'~='--~:..../-"v---'+---,\.-.o 1-...... o r r-o "v ~ g_, ~/ ~ f D"'-.\.-o ,-.--o_r-_f'_O_\A..l--'------ --~--'M4~L~l±~U~~e: ====---· ~001 07/29/99 08:34 'B'412 208 8869 BEAZER EAST INC • Responge to Comments by NCDENR. Former Koopers Suoerlund s·1t@, Morrisville, N::irtti Carolina RESPONSE TO COMMENTS • Page i October 29, 1998 BY NORTH CAROLINA DEPARTMENT OF ENVIRONMENTAL AND NATURAL RESOURCES DATED AUGUST 27, 1998 le'.) 002 ONE-YEAR GROUNDWATER MONITORING REPO FORMER KOPPERS SUPERFUNO SITE MORRISVILLE, NORTH CAROLINA RAFT Executive Summary Comment 1: The third and fourth sentences of the sixth paragraph of this section state that three groundwater samples (collected from groundwater monlton·ng wells C-11B and C-29B, and pumping well PW-1) exceeded the groundwater protection standard for pentachlorophenol. However, the laboratory documentation included in Appendix B indicates that the groundwater sample obtained from groundwater monitoring we// C -14B contained 20 ug/1 pentachlorophenol (in excess of the groundwater protect/on standard for pentachlorophenol). Please clarify this discrepanc;y. Response· The laboratory provided analytical data in two formats, 1) a hard copy (i.e, the contents of Appendix B) and 2) electronic date format (i.e. diskette) Electronic data was transferred into Fluor Daniel GTl's GIS/KEY d.itabase. This database was used to create the analytical data tables The electronic data provideded by the laboratory reported a non detected concentration for pentachlorophenol. Review of the instrument raw data indicates that pentachlorophenol was detected at a concentration of 20 ug/L in the groundwater sample obtained from monitoring well C-14B as provided in Appendix B. The si)(!h paragraph of the Executive Summary has been revised as well as the locations in the report referenced in Comments 6, 7, 9, 18, ·, 9 and 33. Comment 2: The fifth sentence of the sixth paragraph of this section states that the pentach/orophenol conc;entrations have decreased at groundwater monitoring we/ls C-11B and C-29B, and pumping well PW-1. However, monitoring we/I C-29B exhibited a significant increase in pentachlorophenol concentrations during the January 1998 sampling event. Please clarify this discrepancy. Response: The fifth sentence, of the sixth paragraph of this section states: "Compared with the overall historical concentrations at these three wells [C-11 Band C- 29B, and pumping well PW-1 ], the pentachlorophenol concentrations have decreased in each of the wells samples." Beazer recognizes that the concentration of pentachlorophenol in the sample from well M- 29B has increased from the March 1996 sampling event to the January 1998 sampling evenl However, the statement refers to an overall review of the groundwater quality data from 1990 to 1998. The pentachlorophenol concentrations in lhe samples collected during 1990 from well C-29B were 591 ug/L (July 1990) and 968 ug/L (October 1990) compared to the January 1998 concentration of 170 ug/L. Based on this overall 07/29/99 08:34 'B'412 208 S8G9 BEAZER EAST INC • Response to Comments by NCDENR FT ea,., Former Koooers Suoertund Site, Morrisville, North Carolina October 29, 1998 cnrnparison the concentration of pentachlorophenol in the samples collected from monitoring well C-29B has decreased significantly. Table of Contents -Figures Comment 3: The Table of Contents states that the title of Figura 6 is "Penta<:hlorophenol Conc;entration In Monitoring Wells." However, the title of Figure 6 is "Penta<:hlorophenol Concentration -January 1998.'' Please clarify this discrepancy. Response The Table of Contents has been revised to reflect the title of Figure 6 verbatim. Comment 4: Figura 7 was inadvertently omitted. Please corroct this oversight. Response: The revised report includes a copy of Figure 7 showing 2,4-dichlorophenol concentrations for the January 1998 groundwater sampling event Table of Contents -Tables Comment 5: The Table of Contents states that the title of Table 8 is "Comparison of Historical Groundwater Quality Data and Six-Month Groundwater Quality Data." However, the title for Table B is "Historical Groundwater Quality Data for Constituents of Interest." Please clarify this discrepancy. Response: The Table of Contents has been revised to state the title of Table 8 verbatim. Section 4.1 One-Year Groundwater RA Monitoring Analytical Results Comment 6 : The first paragraph of this section states that "pentachlorophcno/ concentrations exceeding the maximum contaminant /eve/ (MCL) of 1 microgram per liter (ugll) were roported from groundwater samples from two monitoring wells (C-11B and C" 29B)." However, the laboratory documentation included in appendix B indicates that, besides groundwater monitoring we/ls C-11 B and C-29B, the groundwater sample obt~ined from groundwater monitoring well C-146 contained 20 ug/1 pentach/orophenol. Please clarify this discrepancy. Response Section 4.1 has been revised to indicate that pentachlorophenol was detected at a concentration of 20 ug/L in the sample collected from groundwater monitoring well C-146. Refer to the response to Comment 1 above. Section 4.2 Comparison of Historical Groundwater Quality Data Comment 7: The seventh sentence of the second paragraph Of this section states that "pentachlorophenol was not detected above the detection limit (1 ug/J) in the samples col/ec;ted from wells C-14A and C-14B during the One-Year groundwater RA monitoring event." However, the laboratory documentation included In Appendix B indicates that the groundwater sample obtained from groundwater ~003 07/29/99 08:35 'B'H2 208 8869 BEAZER EAST INC • Response to Cornrnents by NCDENR D~AFT ._, Fornier Kopper-s Superiu:,d Sile, Morrisville. North CerolinJ October 29, 1998 monitoring well C-14B contained 20 ug/I pantachlorophenol. Please clarify this discrepancy. Response: Section 4 2 has been revised to indicate that pentachlorophenol was detected at a concentration of 20 ug/L in the sample collected from groundwater monitoring well C-14B. Refer to the response to Comment 1 above. Comment 8: The fourth sentence of the fourth paragraph of this section states that "pentachlorophenol concentrations at the extraction well PW-1 and monitoring well C-29B have also shown an overall decreasing trend." However, monitoring well C- 29B exhibited a significant Increase in pentach/orophenol concentrations during the January 1998 sampling event. Please clarify this discrepancy, Response: Beazer recognizes that the pentachlorophenol concentratbn in the sample from well M- 29B has increased from the March 1996 sampling event to the January 1998 sampling event. However, this document provides an overall review of the analytical data from 1990 to 1998. Pentachlorophenal concentrations in samples collected during 1990 from well C-29B were 591 'Jg/L (July 1990) and 968 ug/L (October 1990) compared to the January 1998 concentration of-, 70 ug/L. Based on an overall comparison of the analytical data pentachlorophenol concentrations in the samples collected from monitoring well C-29B have decreased significantly Conclusions and Recommendations Comment 9: The second sentence of the second paragraph of this section states that "pentachlorophenol is below the MCL in all wells except C-11B, C-29B and PW-1 .. . " However, the laboratory documentation included in appendix B indicates that the groundwater sample obtained from groundwater monitoring well C-148 contained 20 ugll pentachlorophenol. Please clarify this discrepancy. Response: Section 5, 0. Conclusions and Recommendations, has been revised to indicate that pentachlorophenol was detected at a concentration of 20 ug/L in the sample collected fncrn groundwater monitoring well C-14B. Please refer to the response to Comment 1 above. Comment 10: The second to last sentence of this section should state " ... Beazer will re- evaluate the groundwater monitoring program ... " Please correct this oversight. Response: The report has been revised. Table 1 Summary of Groundwater Elevations -October 21, 1997 Comment 11: Table 1 indicates that the depth to groundwater was not measured for groundwater pumping well PW-1 and groundwater monitoring wells C-1BC, C-21C, C-23C, C-24C and M-9. Please provide justification for not collecting depth to groundwater measurements at these we/ls. 1//i 004 07/29/99 08:35 'B'412 208 8869 BEAZER EAST INC • ResponS8 to Comrnents by NCDENR Fomier Koooers Superfund Site, Morrisville. North Carolina Response: As stated in the Field Sampling Plan -Pertonmance Standards Verification for tr,e Remedial Action (Remedial Action Work Plan, Volume 2, Cummings Riter, May 1995), water levels ar., to be measured in the on-site and near-offsite monitoring wells, which are shown on Figure 1A of the report. Water level measurements in the on-site and near- offslte monitoring wells are used to assess the influence of pumping at well PW-1, Because the offsite deep monitoring wells (i.e.,C-18C, C-21C, C-23C, C-24C) would not exhibit influence by the groundwater extraction at well PW-1, due to the distances to these wells and anIsotrop1c influences of the bedrock, there is no need to measure water levels at these wells. Monitoring well M-9 was destroyed during the soil remedial action, This monitoring well wil! be removed from the groundwater monitoring table as well as those affsIte deep wells that are not measured. Several attempts were made to obtain a water level measurement at well PW-1 an October 21, 1998. However, the electrical cables and wires associated with the high and low level water sensors in well PW-1 interfered with the collection of the water level measurements Table 2 Summary of Groundwater Elevations -Janua,y_21, 1998 Comment 12: Table 2 indicates that the depth to groundwater was not measured for groundwater monitoring walls C-18C, C-21C, C-23C, C-24C and M-9. Please provide justification for not collecting depth to groundwater measurements at these groundwater monitoring walls. Response: As stated in the Field Sampling Plan -Performance Standards Verification for the Remedial Action (Remedial Action Wark Plan, Volume 2, Cummings Riter, May 1995), water levels are to be measured in the on-site and near-offsite monitoring wells shown on Figure 1A Water level measurements in the on-site and near-offsite monitoring wells are used to assess the influence of pumping at well PW-1. Because the offsite deep monitoring wells are not influenced by the groundwater extraction at well PW-1, due ta distance to these wells and the anisotropic infiuences of the bednock water-bearing zone, there is no need to measure water levels at these wells Monitoring well M-9 was destroyed during the sail remedial action This monitoring well will be removed from the table as well as those offsite deep wells that are not measured for depth to groundwater. Table 3 Summary of Field Purging and Sampling Parameters Comment 13: Table 3 lndic;ates that well depth for groundwater monitoring well C-14B is 65.33 feet (ft), However, the Field Data Sheet for Groundwater Sampling inc;luded in Appendix A indicates that the well depth for C-14B Is 65.93 ft. Please clarify this discrepancy, Response: The well depth for C-148 listed in Table 3 was incorrectly reported. The value listed on the Field Data Sheet is correct. Table 3 has been corrected, Ii!] 005 07/29/99 08:36 '6'412 208 8869 BEAZER EAST INC • Response to Comments !:iy NCDENR Fon'l"ler Koppers Supj,!rfund Site, Morrisvills, North Carolina Comment 14: Table 3 indicates that the depth to water before purging for groundwater monitoring well C-27B is 36.95 ft. However, the Field Data sheet for Groundwater Sampling inc;luded in Appendix A indicates that the depth to water before purging for C-27B Is 34. 95 ft. Please clarify this discrepancy. Response: The depth to water in well C-27B before purging was incorrectly reporte,d Table 3 has been c:orrected. Comment 15: Table 3 Indicates that the sample date for groundwater monitoring well C-27B is January 22, 1998. However, the Field Data Sheet for Groundwater Sampling included In Appendix A lndicatf/s that the sampling date for C-27B is January 23, 1998. Please clarify this discrepancy. Response: Table 3 has been corrected as referenced in the comment Comment 16: Table 3 indicates in the section entitled, Comments, that the groundwater sample for groundwater monitoring well C-11 e was clear and had an odor. However, the Field Data Sheet for groundwater Sampling included in Appendix A that the groundwater sample for C-11 B was cloudy. Please clarify this discrepancy, Response: Table 3 has been corrected to state "Clear. then cloudy at 3 well volumes." Comment 17: Table 3 Indicates in the section entitled, Comments, that the groundwater sample for groundwater pumping well PW-1 was c/e;;ir. However, the Field Data Shoot for Groundwater Sampling included in Appendix A that the groundwater sample for PW-1 was clear and had an odor. Please clarify this discrepancy. Response: The comment is ambiguous about which sampling date is being referenced Table 3 states that on January 22, '1998, tne water from well PW-1 was "Clear" withe "sweet odor". which is what is written on the Field Data Sheet for \his groundwater sampling event. The sample collected on February 11, 1998 had an odor. The information has been added to Table 3. Table 4 Summary of Groundwater Analytical Results for Constituents of Interest Comment 18: Table 4 indicates that the groundwater sample obtained from groundwater monitoring well C-14B contained no detectable concentrations of pentachlorophenol at a laboratory quantltation llmit of 1 ug/I. However, the laboratory document.ation included in Appendix B indicates that the groundwater sample obtilined from groundwater monitoring well C-14B contained 20 ug/I pentachlorophenol. Please clarify this discrepancy. Response: Table 4 has been revised to indicate that pentachlorophenol was detected at a concentration of 20 ug/L in the sample collected from groundwater monitoring well C-14B. Refer to the response to Comment 1 above. li1J 006 07/29/99 08:37 °B'412 20S S869 BEAZER EAST INC • R.esoonse to Comments by NCDENR Former Koppers Superfund Site, Morrisville, North Caro!i,1~ Table B Summary of Historical Groundwater Quality Data for Constituents of Interest Comment 19: Table B indicates that the groundwater sample obtained from groundwater monitoring well C-14B in Janvary 199B contained no detectable com:entrations of pentachlorophenol at a laboratory quantitatlon limit of 1 ug/I. However, the laboratory documentation included in Appendix B indicates thiJt the groundwater sample obtained from groundwater monitoring well C-14B in January 1998 contained 20 ug/I pentach/oropheno/. Please clarify this discrepancy. Response: Table 8 has been revised to indicate that pentachlorophenol was detected at a concentration of 20 ug/L in the groundwater sample collected from monitoring well C-14B. Refer to the response to Comment 1 above. Figure 1 On-Site and Near Off-Site Monitoring Well Locations Comment 20: Figure 1 does not indicate the location of groundwater monitoring wells C-16C, C- 17C, C-18C, C·19C, C-20C, C-21C, C-22C, C-23C, C-24C, and C-32C. Please revise Figure 1 or include an additional figure to depict the locations of all groundwater monitoring wells. Response: The above well locations have been provided on Figure 1 B. Tne text has been revised to include this Figure. The ten deep offsite wells were placed at locations to encircle the site to determine whether constituents of Interest had migrated to these distant offsite locations. These wells will not be influenced by the pumping at well PW-1. Figure 2 Groundwater Elevation Contours. Shallow Wells -October 21. 1997 Comment 21: Figure 2 does not indicate tha location or groundwater elevation of groundwater monitoring we// C-30A. Please revise Figure 2 to depict the location of groundwater monitoring well C-30A. Response Despite the designation of well C-30A as an A-level well, monitoring well C-30A has always been considered an intermediate level monitoring well, as discussed in the Remedial Investigation (RI) Report (Keystone, September 1992). The following is a summary of the explanation as provided in the RI report. The borings drilled at all but three of the 38 on-site and near offsite monitoring well locations (as shown on Figure 2-2 of the RI report, which ts reproduced as Figure 1A of the One-Year Groundwater Remedial Action Dato Summary Report) were completed using air drilling methods. Only the borings for monitoring well locations C-14A, C-27 A. and C-28A were completed using 6 114-inch l.D, hollow stem augers because groundwater was encountered in the weathered bedrock. The total depths of the borings far these three monitoring wells were 28.5 feet bgs, 28 feet bgs and 26 feet bgs, respectively. After encountering auger refusal at monitorir.g weli location C-30A prior to reaching the water table (eventually encountered within a fracture at 30 to 31 feet bgs). and based on anticipated depths to water and information regarding depth to bedrock derived from borings installed prior to the RI, the decision was made to complete all remaining wells using air nctary or air percussion drilling methods lilJ 007 07/29/99 08: 37 'B'412 208 8869 BEAZER EAST INC • Response to Ccrriments by NCDENR Page 7 Cber 29, 1998 f=orrner Ko pers Superfund Site, Morrii;;ville, North Carolina The initial borehole for monitoring well C-30A was advanced to a depth ol 25 feet bgs where augec refusal was en~ountered. No groundwater was observed in the borehole during installation. This borehole remained open for 12 days. Since no groundwater entered the borehole during the period that it was open, the borehole was abandoned. A subsequent borehole was advanced for monitoring well C-30A using air drilling methods, and a water-bearing fracture in competent bedrock was encountered between 30 and 31 feet bgs. Static water levels in this well were measured at depths ranging rrom 1 0 to 13 fee:. Because the static water levels were considerably above the depth at which groundwater was encountered, well C-30A has been considered an intermediate level well. Please refer to Figures 4 and 5 for the location of well C-30A and its gmundwater elevations, which are representative al an intermediate monitoring well. Figure 3 Groundwater Elevation Contours. Shallow Wells -January 21, 1998 Comment 22: Figure 3 indicates th;,t the groundwater elevation for groundwater monitoring well C-BA is 348.92 ft., mean sea /eve/ (ms/). However, Table 2 indicates that the groundwater elevation for C-BA is 348.52 ft., ms/. Please clarify this discrepancy. Response The value listed on Figure 3 has bE!en changed to "348.52" (!Bet msl). This minor difference in groundwater elevation does not affect the groundwater elevation contours in an area where the contours are marked to be inferred. Comment 23: Figure 3 does not indicate the location or groundwater elevation of groundwater monitoring well C-30A. P/e;,se revise Figure 3 to depict the location of groundwater monitoring well C-30A. Response: See response to Comment 21 above. Figure 4 Groundwater Elevation Contours, Intermediate/Deep Wells -October 21, 1997 Comment 24: Figure 4 does not indicate the location or groundwater elevation of groundwater monitoring wells C-1B, C-9C, C-12C, C·17C, C-19G, C0 20C, C-22C, C-33C orC-34G. Please revise Figure 4 or include an additional figure to depict this data. Additionally, please provide justification for the inclusion of groundwater elevation data for one groundwater monitoring well over another in those instances in which groundWater monitoring well clusters have been installed. Response: Please refer to the response to Comment 20 above regarding the deep offsite wells cited 111 this comment. as well as the discussion in the RI report for an understanding of the occunnence of groundwater in several of the listed wells during monitoring well drilling and groundwater monitoring and the temporal changes in groundwater elevation observed in the monitor,ng wells during the pumping test completed in February 1991. In reviewing the RI report, please be cognizant that the C-level wells were required for the purpose al vertical delineation and were found to be unrepresentative in terms of groundwater fiow in the fractured bed.ock (specifically, bedrock that is not an "aquifer"). ~008 07/29/99 08:38 °6'412 208 8869 BEAZER EAST INC • Response to Comment5 oy NCDENR Former Koppers Superfund Site, Morrisville, Nonh Carolina As discussed on page 3-35 of the RI report, water levels ,n wells C-16, C-1 OB and C-12C have always been considerably lower than in the other B and C series wells. At these well locations. no water-bearing fractures were encountered during drilling after the surface casing was set. N; seen from the groundwater elevation data for October 21, 1997, well C-12B had a depth to water of 15.79 feet yielding a groundwater elevation of 359.96 feet ms\, while the adjacent well C-12C had depth to groundwater greater than 100 feet. On January 21, 1998, the depth to water in wells C-12B (15.75 feet) and C-12C ( 123-73 feet) resulted in groundwater elevations of 350 00 feet msl and 252,38 feet msl, respectively, The low yield of groundwater in well C-12C is caused by the groundwater elevation being more than 100 feet lower than the adjacent intermediate level well. Because of this low yield of groundwater, monitoring well C-12C is not used in groundwater elevation contouring. Similarly, the groundwater elevation for monitoring well C-1 OB on October 21, 1997 was greater than 1 DO feet, and this groundwater elevation is not representative of groundwater in the intermediate zone since there were no groundwater fractures encountered at this well. As discussed in the RI report, the pumping test completed in February 1991 revealed that \here was anisotropic groundwater fiow in the water-bearing bedrock underlying the site. The cumulative information collected during the RI indicates that the interval that produced the most water was 30 to 55 feet in depth where fractures were encountered. For example, while well C-9B had 1.37 feet of drawdown observed during the pumping test, monitoring well C-9C had no drawdown observed. In terms of deter.mining the effects of groundwater extraction at well PW-1, well C-9B is used due to the extent of capture demonstrated during the RI pumping test. An example of the disparity in groundwater elevations and unreliability of the groundwater elevation data between the Band C level wells can be seen in comparing the C-33B and C-33C groundwater elevations. The gnoundwater elevations for wells C-33B and C-33C were 347.57 feet msl and 314,80 feet msl, respectively. In comparison to the groundwater elevations for other wells in the area, the elevation for well C-33C is clearly not representative of the intermediate zone and therefore, not used in groundwater elevation contouring. Figure 4 shows a dashed line for the 342-feet ms\ groundwater elevation contour line indicating an inferred groundwater elevation between well C-25B ,ind well C-32C, as the C-32C groundwater elevation is considered less reliable, Comment 25: Groundwater monitoring well C-30A was inadvertently included in Figure 4, Please remove C-30A from Figure 4 and place In Figure 2. Response: Please refer to the response to Comment 21 above. Figure 5 Groundwater Elevation Contours. Intermediate/Deep Wells -January 21. 1998 Comment 26: Figure 5 does not indicate the location or groundwater elevation of groundwater monitoring wells C-1B, C-9C, C-12C, C-17C, C-19C, C-20C, C-22C, C-33C or C-34C. Please revise Figure 5 or include an additional figure to depict this data. Additionally, please provide justification for the inclusion of groundwater elevation i//J 009 07/29/99 08:J8 'B'412 208 8869 • Resconse to Comments by NCOENR Former Koppers Superfund Slt0, Morrisville, North Carolina BEAZER EAST INC ,, ·;;a--• r age 9 October 29, 1998 data for one groundwater monitoring wall aver another in those instances in which groundwater monitoring well clusters have been installed. Response: Please refer to response to Comment 24 above. Comment 27: Groundwater monitoring well C-30A was inadvertently included in Figure 5. Please remove C-30A from Figure 5 and place in Figure 3. Response: Please refer to the response to Comment 21 above. Figure 6 Pentachloropheno/ Concentration -January 21, 1998 Comment 28: Please provide arrows to indicate which groundwater monitoring wells are associated with the corresponding pentachlorophenol concentrations. Response: A line from the data boxes to the individual wells has been added to Figure 6. Comment 29; Figure 6 indicates that the groundwater sample obtained from groundwater monitoring well C-148 contained no detectable concentrations of pentachloropheno/ at a laboratory quantltation limit of 1 ug/1. However, the laboratory documentation included in Appendix 8 indicates that the groundwater sample obtained from groundwater monitoring well C-14/3 contflined 20 ugl/ pentachlorophenol. Please clarify this discrepancy. Response: Please refer to the response to Comment 1 above. Appendix A Field Data Sheets and Chain-of Custody Forms Comment 30: The copy of the field log book pages that include depth to water measurement for the nine-month remedial action monitoring event conducted on Oc;tober 21, 1997 were inadvertently omitted. Please correct this oversight. Response: The depth to water level measurements have been included in Appendix A. Comment 31: The copy of the field log book page that contains the depth to water measurements for the one-year remedial action monitoring event conducted on January 21, 1998 indicates that multiple depth to water measurements were made for groundwater monitoring wells C-11B, C-13A, C-13B, C-14A, C-14B, C-15B, C-27A, C-27B, C-28A, C-28B, C-29B, PW-1 and M-4. Please provide the rationale used In collecting this dat;,, a discussion of the accuracy ;,nd precision of the data collect/on for all of the depth to water measurements, and the rational used in determining which data is included in Table 2. Please amend the appropriate sections of this report to include this inrormation. Response: Because of the low sustainable yield of the fractured Triassic bedroc!<, the pump in well PW-1 is not able to operate continuously. Rather, is it controlled by high and low water !i/1010 07/29/99 08:39 'fi'H2 208 8869 BEAZER EAST INC • h , ,, ::~,;~'; ' Response: to Comments by NCDENR D~P f.·.:.·:i/..7-1""" :L age 10 Former Koppers Superfund Site, Morrisville, North Carolina October 29, 1998 level sensors in well PW-1 that activate and terminate pumping. Once the primary porosity of the fractures is drained, tM secondary porosity of the bedrock does not contribute to the groundwater yield. The effect of limited secondary porosity and permeability causes groundwater extraction to occur in a "pulsed" rnanner. When the pump started on the January 21, 1998 event, multiple water level measurements were collected from wells located within the hydraulic infiuence cf we!! PW-1 to determine the influences pumping operations have on groundwater elevations. Collection of multiple water level measurements while the pump in well PW-1 was operating allowed the determination of groundwater level Ructuation at select monitoring wells in proximity to well PW-1. Since the maximum depth to woter measurement was used in constnuct,ng the groundwater contours for January 22, 1998, these contours depict the likely maximum hydraulic infiuence of well PW" 1 at each monitoring well location. The above discussion was included in Section 2,0 of the report, Comment 32: The Field Data Sheets for Groundwater Sampling are Incomplete. The Field Data Sheets should include the date and start time for purging actlvives, the estimated water volume required for purging i!IS well as the pH, specific conductivity and temperature measurements collected prior to purging and immediately fol/owing the purging of each well volume purged. A portion of this information has been Included in Table 3. However, please provide copies of the field tog boo/< which document the groundwater sampling activities and the collection ot this data. Response· The format of the Field Data Sheet in this report is the same format as presented in the Quality Assurance Project Plan (OAPjP, Chester, June 1993) contair.ed in the Remedial Action Work Plan, (Cummings Riter, May 1995). The water volume required for ourg,ng each well was calculated using the well's water column height in feet multiplied by the volume of water contained in the well casing (gallons per foot) for a specific well diarr,eler Appendix C by a factor of three. · The date, start and end time of purging, lime of sample collection and the pH, specific conductivity and temperature measurements collected during purging are provided on the attached copies of the logbook pages. There are no measurements recorded for groundwater indicator parameters before the initiation of purging, since this water is stagnant and not representative of actual groundwater conditions as indicated by the groundwater quality indicator parameters listed. It is for tnis reason that groundwater is purged from a. monitoring well prior to collection of groundwater samples Furthermore, the collection of field measurements prior to purging listed In this comment do not agree with tl1ose listed in the EPA Region IV Environmental Investigations Standard Operating Procedures and Quality Assurance manual (EISOPQAM, May 1996). Pentachloropheno/ and 2,4-D!chlorophenol Time Trends Comment 33: The graph of pentach/oropheno/ time trends for groundwater monitoring well C- 148 indicates that the groundwater sample obtained from groundwater monitoring ~011 07/29/99 09:30 'B'H2 208 8869 BEAZER EAST INC • • BEAZER EAST, INC, ONE OXFORD CENl?,E, SUITE 30C{), PITTSBURGH, PA 15219 FAX COVER SHEET DATE: TO: }).,,""-M .. +h ~ "~ Nc::,\FiJZ. FROM: M: V..q_, .(\e,,.,,_;V"" Beazer East. Inc. RE: CC: C,, o M r,-;,L ,.,.\ ( ( °'-' 'k • i. e ...._ r I PHONE: FAX: 91 '1--=7J3 · fB# PHONE: (412) 208--0'o(.}- FAX: (412) 208-8859 G ..,_; ~P="' rl-'_j-r---f'f~~--"-f-f .,=r:::S:c.=<d---'.s"---'o"'"'~=:;::____- -+\ .,_,., e.--":?, D , '-( o '--C N v--'. e,vJ j. ~ D!.., (Al ., "'~ -"'J_,,.,____,c...,,v--""r__,.._=~J,:__7 \\& ~'y ~ 1 0-.,.. +.c """' o r f' D '-'-" JUL !±lJ ~ 001 • Re~po~se to Comments by NCDENR DRAFT .. ,.,, Former Koppers Sucerfuna site, M□rTisv1l1e, North Carolina Ociober 29, 1998 Response: well C-148 during the January 1998 sampling event contained no detectable concentrations of pentachlorophenol at a laboratory quantitation limit of 1 ug/1. However, the laboratory documentation included in Appendix B indicates that the groundwater sample obtained from groundwater monitoring well C-148 during the January 1998 sampling event contained 20 ugll pentachlorophenol. Please clarify this discrepancy. The time vs pentachlorophenol concentration trend for well C-14B has been revised to indicate that pentachlorophenol was detected at a concentration of 20 ug/L in the January 1998 sample collected from groundwater monitoring well C-14B. Refer to the response to Comment 1 above. JNI LS\'3 M3Z\/38 oc:50 66/6,llO i,ORT •,SUP E RFU ND iD: JUL 27'99 • • UNITED STATES ENVIFIONMENTAL PROTECTION AGENCY REGION 4 4WD-NSMB Mr. Michael Slenska Beazer Eaet,Inc, ATLANTA FEDERAL CENTER e1 FORSYTH STREET ATLANTA, GEORGIA 30303-8960 July 27, 1999 One Oxford Centre, Suite 3000 Pittsburgh, PA 15219 10:35 No.003 P.02 SUBJ: One-Year Groundwater Remedial Action Monitoring Report and Proposed Remedial Action Groundwater Monitoring Program for the Koppers Superfund Site. Dear Mr. Slenska: The Environmental Protection Agency and the North Carolina Department of Environmental and Natural Resources has conditionally approved the above mentioned documents. Please note the following comment and any previous co1m1ents submitted to you by the State of North Carolina. Also, please accept comments submitted to you by the State of North Carolina regarding the Work Plan for Toxicity Reduction Evaluation dated August 11, 1998. 1) Executive Summary, pg iii. The MCL for 2,3,7,8-TCDD is 0.00003ug/l not 30ug/l. We appreciate the opportunity to review the groundwater reports. If you have any questions, please do not hesitate to contact me at (404) 562-8816 or Dave Madison at (919) 733·2801. cc: Dave Madison, NC S.incerely, r y T. Hudson Management Division lntomot Addroos (URL)• h1lp:/lwww.opa.gov Reoyclod/Recyclal)lt • Ptlnled w~h V&f,16\~IB OIi Based In~ on Aocyciad f'aper (Minimum 2:ig/. f'oSlonsumer) i-JORT'' SUPERFUi,D ID: JUL 27'99 10:36 No .003 P.01 -~ T01 bo.v~ OFFICE: . :. -if~.:..:. : ,:·-..:.'.'I• • •' j·, .. --:• .. . . .~;---~--_ .. r-:,. __ ._.:_ . .· .. .-·;\>:_/:-. . .-._· ... United states Environmental ~ote.ction Agency .W~ M'•nagement Division North Site Management Branch 61 Ponyth Street, SW Atlanta, Ocorp, 30303 · ' DATE: ,iz7/9? ll'f'lad is cf'\ TELEPHONE#: cq l'I) 13 ?i-' .2?0 I . FAX PHONE II: (919)133-4%'11. FROM: 'oc-1 e,~ l+u d.:, o/"I TELEPHONE I: ( ~ C4) 5lc-2 -f~ I(,, OfflCE: Nu,--\h ~ix._ A,\o.~o.j e..m er+-P-,n_,__~ch PAGE 1 OF 2-PAGES INCLUDINO COVU SHBBT ' RETURN FAX II: (404) 562-87ss • BEAZER EAST, INC., ONE OXFORD CENTRE, SUITE 3000, PITTSBURGH, PA 15219-6401 July 22, 1999 Beverly Hudson Remedial Project Manager United States Environmental Protection Agency -Region IV Atlanta Federal Center 61 Forsyth Street, SW Atlanta, Georgia 30303-8909 ✓David Mattison, CHMM Environmental Engineer, Superfund Section North Carolina Department of Environment and Natural Resources Division of Waste Management 401 Oberlin Road, Suite 150 Raliegh, North Carolina 27605 Re: Site Meeting RECEI\/El) JUL 2 21999 SUPERFUND SECTION Former Koppers Company, Inc. Site Morrisville, North Carolina Dear Ms. Hudson and Mr. Mattison: · This letter is written in anticipation of our scheduled July 29, 1999 meeting at the Former Koppers Company, Inc. Superfund Site located in Morrisville, North Carolina. Beazer East, Inc. (Beazer) believes that there are several significant issues to discuss at that upcoming meeting. These issues are briefly summarized below: • One-Year Groundwater Remedial Action Monitoring Report, June 4, 1998, Fluor Daniel GT!, Inc. -This report provides a summary of the groundwater monitoring program activities, and the corresponding findings, conducted from April 1997 through February 1998. The North Carolina Department of Environmental and Natural Resources (NCDENR) provided comments on the report on August 27, 1998. To date Beazer has not received comments from USEPA regarding this report. • . Proposed Remedial Action Groundwater Monitoring Program, July 20, 1998, ThermoRetec -This report described a proposed groundwater monitoring program and recommended a future operation and monitoring plan for the groundwater extraction system. These recommendations were based on the results and ·conclusions of the monitoring activities described in the above-listed report. NCDENR provided Ms. Hudson and Mr. Mlson July 22, 1999 Page 2 • comments on this proposed monitoring program on September I 0, 1998. To date Beazer has not received comments from USEPA. • Work Plan for Toxicity Reduction Evaluation (TRE), August 11, 1998, ThermoRetec -This work plan was prepared to describe the work that Beazer intended to conduct in an attempt to determine the source of periodic toxicity in the Site's groundwater treatment plant effluent. Since the August 11, 1998 work plan submittal, only the January 1999 effluent sample failed the toxicity test. NCDENR provided comments on this proposed TRE work plan on September I 0, 1998 and September 16, 1998. To date Beazer has not received comments from USEPA. • Domestic Well Sampling -Beazer understands that the USEPA has conducted two dioxin sampling events of numerous domestic wells located near the Site. Beazer would like to discuss the locations of these wells, the sample collection methods, the analytical methods used test the well samples, and the subsequent results. Beazer looks forward to meeting with you and representatives from the NCDENR on July 29, 1999 at 12:30 p.m. to discuss the above issues and any other pertinent topics related to the Site. If you should have any questions or require additional information, please contact me at (412) 208-8867. 8;;:ljJLL__ Michael Slenska, P.E. Environmental Manager cc: Ben Genes, ThermoRetec JAMES B. HUNT JR .. GoVERNOR ( '. . •" .. . WAYNE MCDEVITT,.; • ,. ::;,J, SEC:,RETARY ; ~_:,_.;•·;··· ',~ j. ~;;;~,Jtll1 . WILLIA_M L";_ MEYER.'"-:..'1-.·:,<i• . ,, .... -.--,·~~ .... -~ .. •. ;, ·.".'_'•-M. 'c-~~ii-_'r,,a,t. " ,._ DIRECTOR: ~-•-_.r". "i.:2iJ~,;q . . ; ., -v:;t-.. .\;,...l,-Jc,:;,: ... ,, .. ·-: .. ,, ··..:te-i-.~ !;1'!i1.:t,.' ... ,~---~ .....,\· 1,,:,:::~..;.i ,.:;.::: ~ ; ·-··' ~i'"'~ : : ! .,._; {f.f~~ .. ; ~)·},~t f~~ . 1·. Ji: ·,;0 1 .... ~.,_ I I. -· . \ f-. ·-,,;..J ; ·--1 1: . ·:.{ ;~t) _. __ i!JJ;~;~ . ....;-.·" ..... .,. '-t;..i-• :~:-.,.. .""'r~ ... -.pi:~)illi~ :'5111 NORTH !ROLINA DEPARTMENT OF ENVIRONMENT AND NATURAL RESOURCES Ms. Beverly Hudson Remedial Project Manager Superfund Branch Waste Management Division August 27, 1998 United States Environmental Protection Agency Region IV 61 Forsyth Street, 11th Floor Atlanta, GA 30303 Re: One-Year Groundwater Monitoring Report Koppers Company NPL Site Morrisville, Wake County Dear Ms. Hudson: DIVISION OF WASTE MANAGEMENT The Superfund Section of the North Carolina Department of Environment and Natural Resources (NC DENR) has received One-Year Groundwater Monitoring Report for the Koppers Company National Priorities List (NPL) Site. The Superfund Section has reviewed this document and offers the attached comments. We appreciate the opportunity to comment on this document. If you have any questions, please feel free to call me at (919) 733-2801, extension 349. Attachment Sincerely, David B. Mattison, CHMM Environmental Engineer Superfund Section cc: Mike Slenska, Beazer East, Inc. 401 OBERLIN ROAD, SUITE 150, RALEIGH, NC 27605 PHONE 919-733-4996 FAX 919•715-3605 AN EQUAL OPPORTUNITY/ AFFIRMATIVE ACTION EMPLOYER -SO% RECYCLED/I 0% POST-CONSUMER PAPER Ms. Beverly Hudson August 27, 1998 Page 1 • ONE-YEAR GROUNDWATER MONITORING REPORT Executive Summary • 1. The third and fourth sentences of the sixth paragraph of this section state that three groundwater samples (collected from groundwater monitoring wells C-llB and C-29B, and pumping well PW-I) exceeded the groundwater protection standard for pentachlorophenol. However, the laboratory documentation included in Appendix B indicates that the groundwater sample obtained from groundwater monitoring well C- 14B contained 20 µg/1 pentachlorophenol (in excess of the groundwater protection standard for pentachlorophenol). Please clarify this discrepancy. 2. The fifth sentence of the sixth paragraph of this section states that the pentachlorophenol concentrations have decreased at groundwater monitoring wells C- llB and C-29B, and pumping well PW-1. However, monitoring well C-29B exhibited a significant increase in pentachlorophenol concentrations during the January 1998 sampling event. Please clarify this discrepancy. Table of Contents -Figures 3. The Table of Contents states that the title of Figure 6 is "Pentachlorophenol Concentration in Monitoring Wells." However, the title of Figure 6 is "Pentachlorophenol Concentrations -January 1998." Please clarify this discrepancy. 4. Figure 7 was inadvertently omitted. Please correct this oversight. Table of Contents -Tables 5. The Table of Contents states that the title of Table 8 is "Comparison of Historical Groundwater Quality Data and Six-Month Groundwater Quality Data." However, the title for Table 8 is "Historical Groundwater Quality Data for Constituents of Interest." Please clarify this discrepancy. Section 4.1 One-Year Groundwater RA Monitoring Analytical Results 6. The first paragraph of this section states that "pentachlorophenol concentrations exceeding the maximum contaminant level (MCL) of I microgram per liter (µg/1) were reported from groundwater samples from two monitoring wells (C-llB and C-29B)." However, the laboratory documentation included in Appendix B indicates that, besides groundwater monitoring wells C-llB and C-29B, the groundwater sample obtained from groundwater monitoring well C-14B contained 20 µg/1 pentachlorophenol. Please clarify this discrepancy. Ms. Beverly Hudson August 27, 1998 Page 2. • • Section 4.2 Comparison of Historical Groundwater Quality Data 7. The seventh sentence of the second paragraph of this section states that "pentachlorophenol was not detected above the detection limit (1 µg/1) in the samples collected from wells C-14A and C-14B during the One-Year groundwater RA monitoring event." However, the laboratory documentation included in Appendix B indicates that the groundwater sample obtained from groundwater monitoring well C- 14B contained 20 µg/1 pentachlorophenol. Please clarify this discrepancy. 8. The fourth sentence of the fourth paragraph of this section states that "pentachlorophenol concentrations at the extraction well PW-1 and monitoring well C- 29B have also shown an overall decreasing trend." However, monitoring well C-29B exhibited a significant increase in pentachlorophenol concentrations during the January 1998 sampling event. Please clarify this discrepancy. Conclusions and Recommendations 9. The second sentence of the second paragraph of this section states that "pentachlorophenol is below the MCL in all wells except C-l lB, C-29B and PW-I .. . " However, the laboratory documentation included in Appendix B indicates that the groundwater sample obtained from groundwater monitoring well C-14B contained 20 µg/1 pentachlorophenol. Please clarify this discrepancy. 10. The second to last sentence of this section should state " ... Beazer will re-evaluate the groundwater monitoring program ... " Please correct this oversight. Table 1 Summary of Groundwater Elevations -October 21, 1997 11. Table 1 indicates that the depth to groundwater was not measured for groundwater pumping well PW-1 and groundwater monitoring wells C-18C, C-21C, C-23C, C-24C and M-9. Please provide justification for not collecting depth to groundwater measurements at these wells. Table 2 Summary of Groundwater Elevations -January 21, 1998 12. Table 2 indicates that the depth to groundwater was not measured for groundwater monitoring wells C-18C, C-21C, C-23C, C-24C and M-9. Please provide justification for not collecting depth to groundwater measurements at these groundwater monitoring wells. Ms. Beverly Hudson August 27, I 998 Page 3 • • Table 3 Summary of Field Purging and Sampling Parameters 13. Table 3 indicates that well depth for groundwater monitoring well C-14B is 65.33 feet (ft). However, the Field Data Sheet for Groundwater Sampling included in Appendix A indicates that the well depth for C-14B is 65.93 ft. Please clarify this discrepancy. 14. Table 3 indicates that the depth to water before purging for groundwater monitoring well C-27B is 36.95 ft. However, the Field Data Sheet for Groundwater Sampling included in Appendix A indicates that the depth to water before purging for C-27B is 34.95 ft. Please clarify this discrepancy. 15. Table 3 indicates that the sample date for groundwater monitoring well C-27B is January 22, 1998. However, the Field Data Sheet for Groundwater Sampling included in Appendix A indicates that the sampling date for C-27B is January 23, 1998. Please clarify this discrepancy. 16. Table 3 indicates in the section entitled, Comments, that the groundwater sample for groundwater monitoring well C-llB was clear and had an odor. However, the Field Data Sheet for Groundwater Sampling included in Appendix A that the groundwater sample for C-llB was cloudy. Please clarify this discrepancy. 17. Table 3 indicates in the section entitled, Comments, that the groundwater sample for groundwater pumping well PW-I was clear. However, the Field Data Sheet for. Groundwater Sampling included in Appendix A that the groundwater sample for PW-1 was clear and had an odor. Please clarify this discrepancy. Table 4 Summary of Groundwater Analytical Results for Constituents of Interest 18. Table 4 indicates that the groundwater sample obtained from groundwater monitoring well C-14B contained no detectable concentrations of pentachlorophenol at a laboratory quantitation limit of 1 µg/1. However, the laboratory documentation included in Appendix B indicates that the groundwater sample obtained from groundwater monitoring well C-14B contained 20 µg/1 pentachlorophenol. Please clarify this discrepancy. • • Ms. Beverly Hudson August 27, 1998 Page 4 Table 8 Summary of Historical Groundwater Quality Data for Constituents of Interest 19. Table 8 indicates that the groundwater sample obtained from groundwater monitoring well C-14B in January 1998 contained no detectable concentrations of pentachlorophenol at a laboratory quantitation limit of I µg/1. However, the laboratory documentation included in Appendix B indicates that the groundwater sample obtained from groundwater monitoring well C-14B in January 1998 contained 20 µ.g/1 pentachlorophenol. Please clarify this discrepancy. Figure 1 On-Site and Near Off-Site Monitoring Well Locations 20. Figure 1 does not indicate the location of groundwater monitoring wells C-16C, C- 17C, C-18C, C-19C, C-20C, C-21C, C-22C, C-23C, C-24C, and C-32C. Please revise Figure 1 or include an additional figure to depict the locations of all groundwater monitoring wells. Figure 2 Groundwater Elevation Contours, Shallow Wells -October 21, 1997 21. Figure 2 does not indicate the location or groundwater elevation of groundwater monitoring well C-30A. Please revise Figure 2 to depict the location of groundwater monitoring well C-30A. Figure 3 Groundwater Elevation Contours, Shallow Wells -January 21, 1998 22. Figure 3 indicates that the groundwater elevation for groundwater monitoring well C- SA is 348.92 ft, mean sea level (ms!). However, Table 2 indicates that the groundwater elevation for C-8A is 348.52 ft, ms!. Please clarify this discrepancy. 23. Figure 3 does not indicate the location or groundwater elevation of groundwater monitoring well C-30A. Please revise Figure 3 to depict the location of groundwater monitoring well C-30A. • • Ms. Beverly Hudson August 27, 1998 Page 5 Figure 4 Groundwater Elevation Contours, Intermediate/Deep Wells -October 21, 1997 24. Figure 4 does not indicate the location or groundwater elevation of groundwater monitoring wells C-lB, C-9C, C-12C, C-17C, C-19C, C-20C, C-22C, C-33C or C- 34C. Please revise Figure 4 or include an additional figure to depict this data. Additionally, please provide justification for the inclusion of groundwater elevation data for one groundwater monitoring well over another in those instances in which groundwater monitoring well clusters have been installed. 25. Groundwater monitoring well C-30A was inadvertently included in Figure 4. Please remove C-30A from Figure 4 and place in Figure 2. Figure 5 Groundwater Elevation Contours, Intermediate/Deep Wells -January 21, 1998 26. Figure 5 does not indicate the location or groundwater elevation of groundwater monitoring wells C-lB, C-9C, C-12C, C-17C, C-19C, C-20C, C-22C, C-33C or C- 34C. Please revise Figure 5 or include an additional figure to depict this data. Additionally, please provide justification for the inclusion of groundwater elevation data for one groundwater monitoring well over another in those instances in which groundwater monitoring well clusters have been installed. 27. Groundwater monitoring well C-30A was inadvertently included in Figure 5. Please remove C-30A from Figure 5 and place in Figure 3. Figure 6 Pentachlorophenol Concentrations -January 21, 1998 28. Please provide arrows to indicate which groundwater monitoring wells are associated with the corresponding pentachlorophenol concentrations. 29. Figure 6 indicates that the groundwater sample obtained from groundwater monitoring well C-14B contained no detectable concentrations of pentachlorophenol at a laboratory quantitation limit of 1 µg/1. However, the laboratory documentation included in Appendix B indicates that the groundwater sample obtained from groundwater monitoring well C-14B contained 20 µg/1 pentachlorophenol. Please clarify this discrepancy. Ms. Beverly Hudson August 27, 1998 Page 6 • • Appendix A Field Data Sheets and Chain-of-Custody Fonns 30. The copy of the field log book pages that include depth to water measurements for the nine-month remedial action monitoring event conducted on October 21, 1997 were inadvertently omitted. Please correct this oversight. 31. The copy of the field log book page that contains the depth to water measurements for the one-year remedial action monitoring event conducted on January 21, 1998 indicates that multiple depth to water measurements were made for groundwater monitoring wells C-llB, C-13A, C-13B, C-14A, C-14B, C-15B, C-27A, C-27B, C-28A, C-28B, C-29B, PW-I and M-4. Please provide the rational used in collecting this data, a discussion of the accuracy and precision of the data collection for all of the depth to water measurements, and the rational used in determining which data is included in Table 2. Please amend the appropriate sections of this report to include this information. 32. The Field Data Sheets for Groundwater Sampling are incomplete. The Field Data Sheets should include the date and start time for purging activities, the estimated water volume required for purging as well as the pH, specific conductivity and temperature measurements collected prior to purging and immediately following the purging of each well volume purged. A portion of this information has been included in Table 3. However, please provide copies of the field log book which document the groundwater sampling activities and the collection of this data. Appendix C Pentachlorophenol and 2,4-Dichlorophenol Time Trends 33. The graph ofpentachlorophenol time trends for groundwater monitoring well C-14B indicates that the groundwater sample obtained from groundwater monitoring well C- 14B during the January 1998 sampling event contained no detectable concentrations of pentachlorophenol at a laboratory quantitation limit of 1 µg/1. However, the laboratory documentation included in Appendix B indicates that the groundwater sample obtained from groundwater monitoring well C-14B during the January 1998 sampling event contained 20 µg/1 pentachlorophenol. Please clarify this discrepancy. L • • BEAZER EAST, INC, ONE OXFOIU) CENTRE, SUITE 3000, PITTSBURGH, PA 15219-6401 R June 4, I 998 Beverly Hudson Remedial Project Manager United States Environmental Protection Agency -Region IV Atlanta Federal Center JUN O 5 1998 SUPERFUNu ;:itCTION 61 Forsyth Street, SW Atlanta, Georgia 30303-8909 Re: One-Year Groundwater Monitoring Report Former Koppers Company, Inc. Site Morrisville, North Carolina Dear Ms. Hudson: Please find enclosed four copies of the One-Year Groundwater Remedial Action Monitoring Report (Report) for the Former Koppers Company, Inc. site located in Morrisville, North Carolina. Fluor Daniel GT!, Inc. prepared this report on behalf of Beazer East, Inc. (Beazer) in accordance with the requirements of the Unilateral Administrative Order (USEP A Docket 93- 09C) and the USEPA-approved Remedial Action Work Plan prepared pursuant thereto. The enclosed Report provides a summary of the groundwater monitoring program activities, and the corresponding findings, conducted from April I 997 through February I 998. Based on the results and conclusions of these monitoring activities, and in accordance with the USEP A- approved Operations & Maintenance Plan, Beazer will re-evaluate the groundwater monitoring program and propose a recommended future operation and monitoring plan for the groundwater extraction system. Beazer's recommended future operation and monitoring plan will be submitted by July 20, 1998. If you should have any questions or require additional information, please contact me at (412) 208-8867 or Ms. Mary Anna Babish with Fluor Daniel GT!, Inc. at ( 412) 823-5300. s:;;:el' f /1 /; ' :11(2'!:f~;l,,/L----- Michael Slenska, P E Environmental Manager Enclosure cc: Dave Mattison, NCDEH (2 copies) Mary Anna Babish, FOGT! (w/o enclosure)