NCD003200383_19950828_Koppers Co. Inc._FRBCERCLA RD_BCD Treatability Study 1994 - 1995-OCR

August 28, 1995
Memorandum
TO:
FROM:
RE:
File ~V
David J. Lown~~
BCD Technology
Koppers NPL Site
Morrisville, Wake County
Today, James A. Cook, Project Manager for Beazer East, Inc., telephoned to tell me that
since our meeting on August I 0, 1995, some additional information on the BCD process as used
by ETG Environmental, Inc. has come to light. Apparently, BCD was used in a pilot test in
Stockton, California and there was a release of dioxin to the atmosphere. Cook said that
B. Hudson and C. Fehn are reviewing the data.
cc: Jack Butler
• • 0
(2UMMINGS
T<.. ~~l!s~LTANTS, INC.
Mr. Richard Lasater
NC Department of Environment, Health, and Natural Resources
Air Quality Section
P.O. Box 29535
512 N. Salisbury Street
Raleigh, North Carolina 27604
RE: AIR MONITORING DATA FROM SITE DEMONSTRATION
KOPPERS COMPANY INC., SUPERFUND SITE
Dear Mr. Lasater:
Project 93-145
November 9, 1994
On behalf of Beazer East, Cummings/Riter has enclosed air monitoring data from the
SITE demonstration conducted at the Koppers Company Inc. Superfund Site.
Cummings/Riter pursued this data from the contractor who performed the SITE
demonstration so that discussions regarding the air permitting requirements could be
initiated and the schedule for the start of construction could be maintained. We look
forward to working with you and the Air Quality Section.
If you have any questions, or would like to discuss the air pennitting requirements with
regard to the enclosed information, please contact us.
Sincerely yours,
UJ
William C. Smith,
Project Manager
pc: __ Ms .. Beverly._ HudsQn,_USEPA, Regioll JV __ -----;,
f Mr. Davie! Lown, NCDEM, Superfund Branch_ J
Mr. Jirn Cook, Beazer East· . ---·
Enclosures
WCS\AHT\aht
LASATER.DOC. . Oxford Building, Suite 202 • University Office Plaza• Newark, DE I 9702
[phone] • FAX [phone]
• •
TO: A. Preston Howard, Jr. DATE: August 24, 1993
FROM:
RE:
Director
North Carolina Division of
Environmental Management
Michael A. Kelly
Deputy Director
North Carolina Division
of Solid Waste
Terrence W. Lyons
Superfund Innovative Technology
Technology Evaluation (SITE)
Project Manager Risk Reduction
Engineering Laboratory
SUBIECT: Koppers Superfund Site
Demonstration Project
U.S. Environmental Protection Agency
North Carolina Department of Environmental Health and Natural Resources Division of
Environmental Management letter, August 23, 1993.
In response to the referenced letter, we respectively provide the following responses.
1. BCD Technology and SAREX" Therrn-O-Detox'm system is shown in Figure 1 and
discussed in the attached technology description. Soil exiting the MTTD unit will be
treated to a level well below the treatment standard and can be returned to the site.
The SAREX" Therm-O-Detox'm system is designed to minimize air emissions. It is
an indirect electrical heat thermal desorption process therefore there is no
combustion that occurs in the system. The off-gas flow rate will be operated in the
25 -50 CFM range. Organic compounds will be condensed by an oil scrubber, two
(2) water scrubbers, a condenser unit and then further polished by two (2) carbon
adsorption units prior to discharge into the atmosphere. This off gas treatment
system has been permitted as meeting BOAT in several states including California,
Washington, Ohio, New Jersey, Oklahoma, Texas, Louisiana, Kansas, etc. The off
gas will be discharged at a temperature range of 80' -lO0'F from the 4 inch stack
with a height of approximately 18 feet after the carbon adsorption units.
The air emission rates for key parameters will be 3 - 4 orders of magnitude lower
than the maximum emission rates. We expect the PCP, TCDD, HCDF and
particulate concentration will be non-detect in the off-gas discharged from the system.
Based on 40 CFM off-gas flow rate, detection levels, 500 lbs/hr soil processing rate
at 8 hours/run and 6 total runs, the emission rates are estimated as follows:
.. , .... ·.·•·Tcoo>· HCDF Particulate PCP
NC State Max 0.0064 0.00020 0.0051 1.83
Emission Rate Lb/Hr Lb/Day Lb/Yr Lb/Hr
Detection Level 20 0.03 0.016 0.001
µg/dscm ng/dscm ng/dscm Grains/dscf
Air Emission Rate 2.95 X 10.;; 3.56 X 10"12 2.4 X 10"11 2.45 X 104
(0.00000295) Lb/Day Lb/Day (0.000345)
Lb/Hr Lb/Hr
Total Air Emission 1.4 X 104 1.65 X 10"2
During Demo (0.00014) 2.1 X 10"11 1.4 X 10-lO (0.0165)
Lb Lb Lb Lb
2. Respirable Particulate Matter
Respirable PM 10 particulate matter, particles with aerodynamic diameter of less than
10 microns, will be collected using Wedding and Associates, Inc. high-volume PM10
sampling systems. The Wedding samplers are accepted by the EPA as a reference
collection method for PM 10• Components of the sampling system include the
following:
An aluminum housing;
An omni-directional size-selective (10 micron) inlet;
A filter holder;
A critical flow device; and
A blower.
The attached figure presents the sampling system graphically. An 8.5-in by 11-in glass
fiber filter is used to collect the particles for subsequent gravimetric analysis. The
sampling system will be operated at 40 CFM, concurrent with site activities,
approximately 8 hours per day. The filters will be visually inspected to determine
when loading is sufficient and filters should be recovered. A nominal air volume for
three days of sampling would be approximately 60,000 ft.3•
The EPA reference method for PM10 is found in 40 CFR 53, Appendix J.
PM10 particulate filters will be shipped to the Radian laboratory in Austin for
gravimetric determination. Gravimetric determination of the filter is implemented
to ascertain the total particulate matter with an aerodynamic diameter of 10
micrometers or less. The filter is desiccated and allowed to come to a constant
weight ( + /-0.5 mg), and the values are reported to the nearest 0.1 mg.
Four high-volume PM-10 samplers will be located in open areas near the perimeter
of the site, as shown on the attached site map.
3. As presented in Reference # 1, as presented earlier to the state, this demonstration
will not exceed the threshold levels as given in ISA NCAC 2H .0610. Therefore
dispersion computer modeling will not be required.
~ (?..,~rMJ
U _,¥1..{ Cr ~I >.)
Summary of Inlet SemiVOST Sampling Parameters
!Total Sampline:, Time immi
·c-... -rrecte:d BArometric Pressure (in 1-ig) I .
/-bsolute StacK Pr.cs.sure tin Hg)
istack StallC P:-!S~Ufl~ (in H2O)
i
·:\,·ernge Stad: Tempereture l"F)
St,.,ck Are, isq in)
.\i.:~ual \1erer \:(,]um-:.-(cu ft)
!_-\vern~c :--.tet:r Yr~s~'Jre 11n H20)
. .:..v,:r11g.e Meter Tr:npcrature ( ;,~)
l\io1stu1e (t)ileued (g)
iCarbon Dio).\de C".",ncernr:Hion 1 ¼ VJ
I
,1)xygrn Conct:ntrtHion t % V)
Nitrogen C,,nccntrau=:i1: ( 7;, \')
;Dry Gas Meter Factor
· Nozzle Diamtt(SJ ( ir. ',
I ,A,ern~c S,mpling Rate (ds,ftn)
:
IS<Bnci,rJ Metered Volume (dsc:)
·s1andard W.o!:.e1t-d \'olumc 1dscm)
' \1ole t'rac:1or. Dry Stark Gos
Drv Molecular We1oht I , ~
Wet ~1olecular Weight
:s<Bck Gas Vcloc1ty (fpm1
Stack Go~ Velocity (mpm1
'Volurr.etric Flow RAte (acfm1
I
:\'clumetnc Flow Rate (a..:mm)
•\'olu:nt":tr:c f-luw Rote 1J~cfm1
l\'olumerr,c Flow Rote (d,cmm)
:Percent l5okinetic
Run 1 1 Run 2 . Run 4 1
8128193 3129193 l 8131193 I
300 I
29.87
30.02
2. 10
104.70
7.07
112.586
0.39
88.08 i
65, 71
1.0 I
20,0
79,0
1. ()(X) 1
0.210
0,362 I
108.451
3.071
2.78
0.972
28.96
28.66
1636.9
498,9
80.3
Z.3
73,3
2.1 I
100.7 !
240 I
29,11 I
29,79
1. 10
99,56
I ' 7.07 I
' 121.473
i),74
81.23
85.9 I
' 1.0;
20.0
79.0
1.0<Xll I
o.2s8 I
0.4921
117,961 i
I
3.)41 I
3.32 :
0.967
28.96
28.60
,449.9
441.9
71.2
2.0
64.6 I
I
1.8
102,8
.;40
29,82 ·
' 0.10 I
' %.0~;
7,071
' 12L002 I
J. "76 i
00.00
33.9
i. '.)
w.o'
79.0 .
1.0001 1·
O.JlO
' 0,496 i
I
118 990 I
3.370 I
...... .., ' ·'·"-
0,')6a '
28,961
2S.6i j
1023.9 :
312.1 i
50,3 I
1.4.
46,9 ·
1.3
99,1
Run 5 i
,101/93 ;
240 I
29.69 :
29.i4 I
0. 75 i
85.06 ;
I
7 .07 i
U0.2i-4 l
I 0.~~
112.1
I '· .u
20.0
I
79,0 ,
: I)')')! I
a.25s I
D.530 ·
127.2561
I 0-~!
JyY
0,960
28.96
2S.52
155!.: i
' .. ,i:.. <'-, a I
'6 . I ' .l I
i . ., ' -·-I
,0.4 I
' 2.0 i
!Oi.~ I
R,n 6
9i02l93
NO!
29.78 i
09 8' I " . ., I
'J,70 '
I 3~,;51·
: .07
129. i 78 i
I
0.83 ;
i6.07
l.G
~0.0 . I
79.0 I
1..0001 I
o.310 I
0.529
126.9i8
3.5% I
:.93 i
0,971 '
I
.:8.961
.!S.64
1071.S
326,6
52,6 /
u l
48.9 i
1.4 I
101.4 ,
-\ verage ,
29,76
29.84 i
1.07
93,03
i,07 i
:23.1071
il.i j I
S0.66 i
85.~ i
1.0
20.0
79,U
1.0001
0.269
' 0.482 i
119.927 I
' J.396 i
' 3 2S !
o.~os i
I
28.96 i
18.60
1346. 7
410.5 I
66.1 !
' 1.9 I
t-0.8 :
1.7
:01.1
ill.IF. •. -•. -.. -, .: ',1
Summary of Outlet Semi-VOST Sampling Parameters
Run I Run 2 I Run 4 i KUn 5 R~n 6 i Average ! I
S/28/93 3129/93 S/3 I.'~) ' ,;,,,)1193 9102/93
' ' \";otal Sampling Timc: tminl 285 240 I 240 240 240 249
' -
29. 71 ! Cvrrec~.'.!d 3:i.r,JmtHric Pressure (in Hg) 29.i2 29.77 ~? 69 29. 78 29.73 ·
Absoiurc S1ack Pressure (in Hg/ 29.78 29.73 i c9. 78 2,Ul .:9 80 29.76
I
:stack Sllltic Pressure (in H2O) 0.85 0.35 ' :).22 : 0.24 : 0.24 0.18
I I
98.941 '
I
iAverage Stack Temperamre 1 'F) 105.58 I Y5.5f: i JOI .:.S ' 94.25 99.14
I i I I 7.07 I I
;Stack Area tsq ml 7 .07 \ ~ .07 i 7 .07 . 7.071 7.07
Actu;al Meter Vclumc (~u II} 106.799 i 12!.918 · "'4 f ' 1 : :23.398 i22.:9~ I 19.910 I-' , "'• i ' I
A\'erage Merer Pressure 1in H20) 0.43 I 0.77 ' (J.8J ! 0.80 0.79 t r) -2 : .... , !
:Average Meter Temperetur, i'l') 85.641 ~6. 15 i 83 78 I i3.G4 81.101 84.06 i
I
82.2 i i
79.; ! j',101sture Collected lg) 1,.3 l 71.9 , 90,0 ·;(L l !
' I 1.0 !· Carbon Dioxide Concen1rarion \ % V) i.O 1.0 I :.o; 1.0 1.0
I
20.0 I I
Oxyger. Ccnccntrat,on ( % V l 20.0 20.0 i .'.0.0 ~0.0 20.c i . I
Ni1rogen Concentrnt1on (% Vi 79.0 79,0 79.0 0 9,0 I 79.0 79.0 j I . I 1.0024 I [Dry Gas Me,cr Fac10r J .0024 1.0024 1.0024 1.0024 i 1.0024
I I
;Nozzle-Di:imeter (in) 0.2:4 0.258 0.3CJ9 u.258 0.309 0.270' ,-
1-~verage. Sampling Raie (dscfml 0.362 0.490 0.504 0.500 0.497 0.4il '
Standard ~fotere.<l Volume 1dsci) !03.066 117,603 :21.018 i 19.994 l !9.356 l 16.207
iStan,Jnrci :vletered Volume (dscrn.l 2.919 3 331 I }.427 J.398 3.380 3.291
I I 2.92 I · Stack Moi~turo ( % Vl 3.42 3. 19 , ~. 7 2 :~.~2 3. 13
!
Mole Fract:on i')ry Stack Gas 0.966 0.968 i 0.973 C.966 I 0.971 0,969 !
28.96 l I
!Dry Molecular Weight 28.96 2S.9b 28.96 l 28.96 28.96 I I
!Wet Moleculor Wei~hl 28.59 28.61 i 28,66 28.59 28.64 28.62 I . ' I
I.Stack Gas Vcloct!y (fpm) 1646.8 1459,2 i 1046,6 1494,7 !019.1 1333.3 i
' I
,Slack Gas 1/elodty tmpml 501.9 I 444.8 )19,0 ~55.6 310,6 406.4
' so.s i I ,Volumetric Flow Rate (acfm) 71.6 51.4 i3.4 50.0 65.4
I
'Volumetric Flow Ratt. tacmml 2.3 ' 2.0 I 5 1. l 1.4 J".9
I
;votumemc Flow Rate (dscfm) 72.5 65.1 J 7 ,J 66.2 -\6.1 59.4
I I l.i I Volumetm Flow Rate !dscmm) 2.1 1,8 I l .~ 1.9 !.3
I 102.2 i lPercent lsokinetic _ 98.0 101.8 i i00.5 l 01 .S 100,8
• ----•· -----.,:,_,Ii.':. :-=.-::: .. _.:. .• ::-:_·
Summary of Outlet HCI Sampling Pru-ameters
Run l Run 2 'j Run 4 1 Run 5 : Run 6 Average !
, ___ ----------,>-8/_2_8_/9_3-+_8_/2_9_/9_;3;____._81_3_1 ,_'9'-3-'-1 c..9__:!0_:1:..:/9..:3-+i .c.'.c.i0:.:2:::/9:.:3~! ___ _J
jTotal Samplin~ Time <min) 180 ! 135 j 120
1
120, 120
1
.
,Correc<ui Barometric Pressur, !in Hg) '29.72 [ 29.71 ,
1
29.77 I 29.6, I :9.i8
:Absolute Stack P,essure l:n Hg) 29.78 I 29.73 29.73 1 29."/I I 29.80
:stack Sllltic Pressure tin i-120\ 0.85 I 0.351 0.22 : 0.2~ ; 0.24
!Average SUiek Temperorure i°F) 105.251 93.89 ] 89.38 ! 96.25 : ~8.63
iStack Area (sq inl 7.07 j 7.071 •,CJ7 [ "'.17 I 7.07
1Actu.nl Meter Volume (lU rn 67.070 I '70.018 ! 1i3,48S:
1 I I I
!A vern~e Meter Pre,,ute I in fi2O) 0.40 j I). 79 i <'. 36 ' ,:,. 79 I iJ. 8 I i
!Average :>.1etcr Temperature ('F) 85.28 ! n.47 ! 7).36: 80.:5, 78.06 j
!Moisture C,;:lect~d lg) J5.2 31.S : 29.S i 3:.01 39.1 i
I ' i /Carbon Diox.iJe. Concentra1ion r, o/c V) 1.0 i .0 1 ] .C = i .0 1.0 j
135 i I
2'1.73 j
09 '6 I -. , I
0.Ja i
94.68 I
7.07 i
65. !00 i
I 0. 73 I
I
81.06 i
34.5 I
1.0" !~
·Oxygen Concentration (\\Y; 20.0 20.0 .-'.0.0 20.0 20.0 I 20.0 I
Nitrogen Concentration(%\') 79.0 79.0 79.0 79.0 79.0 i 79.0 J
Dry Ges Meter Factor 0.986! 0.9861 0.9861 ; 0.9861 I 0.986! I 0.9861 :
:Nozzle Di,meter <.in) 0.211 0.259, 0.3W ! 0.258 II 0.310 i 0.270 ! -----'-----!--'-=-'-'---, -----,----"--'+-----1,-----=-:._.1
Average Sampling Rate (dscfml 0.354 0.4961 0.510 f '.),S(YJ I 0.502: 0.472 I
St.and.ard \lelere<l \'c,lume /dscfl 63.710, 66.8961 61.I•I 59 943; 60.263 J 62.391 !
'si.,ndad Metered Volume (dscm) i.8041 l.895 i i 0J2; :.6\i8 I 1.707: 1.767'
:s1.ack Motsture ,;',Vi 2.54 J 2.171 2.25 ! ~.83 I 2.971 2.551
l\fole Fraction Dry St.a,k Gas 0.975 I 0.978 0.973 : 0 972 0.'.'i0 i 0.974 I
:Dry Molecular Weight 28.96 ' 28.96 28.96 ! :'.S.96 28.961 28.96 i
I l I :
:wet Mole~ular Wei2ht 28.68 28.72 28.71 ' ~S.65 23.63 '1 28.68 j ! -
:St.ack Gas Velocity /fpm) 1643.6 1455.7 1056.2: !479.; 1024.41 1331.9 I
!stad:Gas Yeiocuy (mpm) 501.0 I 443.7 .121.9 i 451.C:' 312.2: 406.0
1vo!umetric !-'10~1 Rate (acfmc 80.7 71.5 51.8: 72.-5 50.3 I ti5.4
:Volumetric flow ~•t~ 1scmm) 2.3 2.0 1.5: 2.1 i.4 I 1.s·
/Volumetric flow Rate jd-cfm) 73.! : 66.2 I J8.5 i ,;6.5 46.8 60.2
("olumetric flow Rate (d.,cmm) 'l ! I.9 ! :.4 ! 1.9 1.3 :.7
: Percent ls_o:.:k:.:i.::.n•:.:':.:ic ________ c._ _ __;9:_:;.c.: 9=--'-i _ _:'.:.00:.:·.::.4...!J_--'9-'~-.4_: _.:..' O:..:lc... ,'--'--=-: '.:._)O:_·c..6_, __ ~_9 -~8
• • Summary of lnlet CDD/CDF Sampling Parameters
Rwi I Run 2 ; Rwi 4 Run 5
q/28/93 S/29/93 ! 3/3li93 9i0L'93 f-------------------t----i---'
,Total Sampling Time (m11;)
!correc~fd 8.uometric Pre<:sure I in HgJ
IAbsvlute Slllck Pressure (1n ll,01
I
JOO I
~9.87 !
J0.01 !
i Stack St~Hic Prtssure i i:1 H 20) 2. ! 0 j
,Averal{e Slllck Temperature ( '~) 104.80 ' ~ I • jSiack Area (sq m\ 7.07
.Actual Meter Volume (cu it) 109.~'.:6 (
Average \1eter Prnssure {:n H":O) 1).42 1
Average Meter Temperature ( 'f) 38.27 i
,~!oisrure Collected<',:) 59.3 ;
240
29.71
29.79
1.10
101.75 I
I
7.07 :
121.301
0.81
35.39
33.9 i
!.O !
240 l 240 1
29.77 29.C9
29.82 29. /J :
Q,jQi (1.15:
' 87.19 35.J i ;
7.07 '.07 1
120.357 12'.'.010 i
0.81 0.90 i
83.37 32.55
84.J 96. 7 '
l.O l.O · / Carbon Dioxide Concer.1rnt1Qn : ~ V! l .0 !
!oxvi;z!!a CcncentrJl!cn t··.-;, \') 20.0 ! 20.0 : ·20.0 ~0.0 :
Run;.;
24J ;
l9 83
:) . /() :
·!Q. I 9 I
1) !'<0 i ... I
' 11. .!3 i
1i0.ii ;
();
I . . I '
!~itrvgea Cr-,n(:entration: 'e \/\ -:-~.0 79.0 79.0 : 79.0 : ":9.0 !
I I
Dry Gas !,leter Factor I.IX41 l.ll04l 1.0041 ' :.C<J41 ,.l\l41
/Nozzle Diamet,r (in1 0.211 i 0.25? IJ.309 j •) 259 1\)09
f-: A-v-.-,-•g_e_S_a_n_,F_l-in_g_R_a_:_e_1_ -d,-,-:'m-, -----Q-_-J-54'--1-1--0-.4_3_9_1 --◊-. 4-g-8 r---0-. 5-! 5~; --,)-. 5-1-2'
!Standard Mor.r<'d Vc!ume id.«t'1 106.284 117.381 117.!37 '. :23.495 · l2'2.399 !
lsunclard Metered Volume ,·dscrr,l J.010 3.324. 3.317: J.497; ·,.431' I
I Stack Moisture ( %V1 2.56 3.26
1Mole Fraction Dry Suck Gas 0.974 0.967
j Dry Mole~ular Weight 28.961 28.96 ,
·Wet Mole·:ul,,r We1l1ht '.8.68 28.60 I
;Slllck Ga, Velocity (fpm1 i636.4 'I !447.J '
ISta.:k Oas Velocity (mpm1 498.8 441. l [
1Volumetric Flow R.1te !adr.i) 80.3 71.0 /
/vc1umetric flow Rate (a<mm1 2.3 2.0 I
3.28
0.967
28.96 i
' 23.60 i
'
1025.4 I
312.5 j
50.J i
r.4 I
-lli. s
' 0.96-l;
28.96 ;
23.57
1547.& :
471.8 I
I
76.0 !
i
) ·'.' !
-•-I
' 70.5 I !Volumelric Flow R.lte (dscim1 73.4 64.3 ,
/Volumetric Flow Rate (Cscmm) 2.1 ; 1.s·, t.J !.O [
: Pe rcen I lsoki.ce ric _ _i_ __ 9_7 __ . 6::....:.1 _..clc.:0'2=. o:_i_l _ __,;.9;::8 .~3..1_ __ 9:...:..,7. 9 I
----------::-::.:::·-.::·.:.:-.=· -·-
J.1)0 :
I
U.970 I
I
2~. 96
:x.oJ
1071!.4 :
126 3 I
51.5 i
i
I 51
,s. s !
, .• I
i
99.0 ,
.-\ vera ~1..•
:9. 7.i
I
:9 84 :
1.07 :
' 93 85 i
7 .Oi' 1
i20.8&1 I
J. i? !
a4. 17 !
! ''I .) I -~ . l !
. ' l . :i I· '
20.0 I
'9.0 I
Q.472
I 17 4.19
3.326
J.13
I
i 1).969
28.96 :
23.62
IJ45,.; :
' 110. l ;
Cb.QI
l. 9
' l. 7 ;
! 98.9 I
Sun1ma.f Outlet CDD/CDF Samplin.rametcrs
···-·-·-·--·-· ....... ·-·-----
Run i Run 2 Run 4 Run 5 ' R!.!n 0 :\verJ~e i ! ! 8/28/93 8/29/93 8131!93 I 9/01 /93 ').tC·J._;i)) . - j
Tora! Sampling Ti.no (,r,in1 300 i 240 240' '240 : .!-tO '. 2521
Corrected Baromelr'..: r:iress1,;f':' {in ! i~i ,,~ ... ,, 29.71 29. 77 2~ ci'J 2~-78 · _'j, I.., i). 7J i
Absolute Sllld; Pressur~ (in lf~l 2Y.78 29.73 29.78 , )rJ 1 I -~ . , . 29. ~(l : -,o 1 · I -~ .. 0
Stack Static Pressuro lin H20i 0. 85 0.35 U.2~ 0 24 ! n 24 i 0.38
' ) . ' Average St.1ck Temperature , T: 105.85 98.63 95.06 I iXl. 81 ' '4.1.l ! 98,90
I ' Stac~ Arca (sq in) 7.07 7.07 7.07 i.01 I 7 .o: : 7,07
I
Actu.:1I Merer Vc,iume (cu )I) 114.150 . 124.727 129. 11! 1:5.186 : 123.762 ! 123 389
I ' Average Meter Pressure (in H"2U J 0.42 0.79 0.86 0.80 I O.iS \). 73
Average Meter Tempernture (<l F) 8 I. 04 89. 19 86.62 35.18 ; W' ·7 ' 84.92 .... :, I
i ' Moisture Collected (g) 73.0 77.0 68.2 82,5 : 70.3 : 7 -l. J
1Carbon Dioxide Concentracion < % \! i 1.0 1.0 1.0 1.0: 1.0: 1.tl i ! :oxygen Concenrration t ¼VI 20.0 20.0 20.0 20.C : 2:),0 20.0
' 79.0 I I Nitrogen f:on(entrat1on ( ~ V; 79.0 79.0 ''9.0 : 79.G 7:;. i)
I Ory G3s Meter Factor 0.9923 ' 0.9928 i 0 9928 1),9928 : ,u,28 : 0.99'.<!8 I
' IJ '5" ! ' l) 308 ' Nozzle Dismc:ter (in) 0.212 0.257 1 0,308 • ._ I ' 0.268 ---·-··--' 0.494 i o . ..i~i : !Average Sampiiog Rate ~ds.:lm:) 0.367 0.515 0.499 : 0.474 I
119.3(12: 51.lndard Metered Yolun,e 1Jscr1 I 10.019 118.507 , 123.530 119.7-12: 118 222
Standard Metered Volume lJscml J.116 3.356 3.493 }.39 I ' :i.379 : ].]48 i
51.lck Moisture(% V) 3.03 2.97 2.54 J, 15 i ~ : ) 2.88
Mole Fraction Dry St:11.!J.:. G::is 0.970 0.970 0.9i5 0.969 I <J.973 C.971 I
1
ory Mo,ecular Weighl 28.90 28.96 28.96 28.96: 28.96 · 28.961
Wet Molecu!Jr Weight 28.63 28.63 28.68 28.62 ' 23. 6<\ ' 28.64
' Stock Gas Velocity (fpro• 1646.0 1464.i 106!.9 1497.0 ' 101 ~ 8 tJJ7.: i
Stack Ga, V<ioci~; 1mprr.1 501. 7 446_.! 323 7 -156.) .lHU 407.7 i
Volumetric Flow R:ite (acfn11 80.8 71.9 52.1 73.5 . )(l_(! 65.7
Volumetric Flow Rate ,·acrnm~ 2.3 2.0 1.5 2. ! I -1 i i 9 I
Volumetric Flow Rate r.dscfm) 72_g 65.5 I 48. I i 66.5 46.2 . 59.3
I Volumetric Flow Rate {dscmm.1 2.1 1.9 i 1.4 1 l. 9 1 . .:; I. C
' Percent lsokineiio 100.9 102.7 I 101.s I l1J2.'2 10-:.2 1.01.-J I
J
l J
J
]
J
J
J
J
J
J
1
J
1
J
]
]
]
RADIAN • • co ■~ORATION
Table 1-1
Gas Sample Collection Summary
I I.·· .. Run 1 Run 2 Run 4•· · Run 5
Parameter · 8/28 8/29 8/31 9/01
Inlet Carbon Bed
Particulate/HO .[ .[ .[ .[
Semivolatile Organics .[ .[ .[ .[
PCDD/PCDF .[ .[ .[ .[
Volatile Organics .[ .[ .[ .[
Outlet Carbon Bed
Particulate /H Cl .[ .[ .[ .[
Semivolatile Organics .[ .[ .[ .[
PCDD/PCDF .[ .[ .[ .[
Volatile Organics .[ .[ .[ .[
Liquid Reactor
Semivolatile Organics
Volatile Organics .[
Field Blanks
Particulate/HO
Semivolatile Organics
PCDD/PCDF
Volatile Organics
Reagent Blanks
Particulate/HO
Semivolatile Organics
PCDD/PCDF
1-7
.. Run 6 Run 7
. 9/02 9/03
.[ .[
.[ .[
.[ .[
.[ .[
.[ .[
.[ .[
.[ .[
.[ .[
.[
.[
.[
.[
.[
.[
.[
.[
)
)
L_ii LJ LJ LJ L......11 ~ :........1 1..-J 1..-J 1..-J L-1 1....-,j 1....-,j '----' ___.
Table 2-1
Summary of Analysis Results for Semivolatile Organic Compounds in Soil Reactor Off-Gas (µg/dscm)
. :> ·•·:> .... ... . . : <>· .. . .... FoddBlanb Run I Run2 Run4 RunS Run6 ··.. R ·r• :·.. an .·
8-28-93 8-29-93 8-31-93 9-01-93 9-02-93 9-03-93· 9-03-93 • ••
~ . Inlet
lalet Outlet lDlct Oullct lDlct Oullet lolet Oullct Inlet Outlet lDlct Outlet lalet Dup Outlet
1,2-Dichlorobcnzcnc 173 <0.2 247 <0.2 112 <0.2 203 <0.2 253 <0.2 300 <0.2 <0.2 <0.2 <0.2
1,2,4-Trichlorobenzenc 77.2 <0.2 165 <0.2 40.7 <0.2 46.6 <0.2 64 <0.2 109 <0.2 <0.2 <0.2 <0.2
1,3-Dichlorobcnzcne 245 <0.2 542 <0.2 118 <0.2 225 <0.2 277 <0.2 416 <0.2 <0.2 <0.2 <0.2
1,4-Dichlorobcnzenc 44 <0.2 82.6 <0.2 21.8 <0.2 47.4 <0.2 66.7 <0.2 83.1 <0.2 <0.2 <0.2 <0.2
2-Methylnaphthalenc 197 <0.1 143 <0.1 166 <0.1 240 <0.1 231 <0.1 611 <0.1 <0.1 <0.l <0.1
2-Melhylphenol 25.7 <0.1 30.2 <0.01 <9.2 <0.1 <4.3 <0.1 <8.6 <0.1 <1.S <0.1 <0.1 <0.1 <0.1
2,4-Dichlorophcnol <3.7 <0.2 233 <0.2 <17 <0.2 <18 <0.2 <16 <0.2 <14 <0.2 <0.2 <0.2 <0.2
2,4,5-Trichlorophenol <3.3 <0.2 59.9 <0.2 <IS <0.2 <7.1 <0.2 <15 <0.2 <13 <0.1 <0.2 <0.2 <0.2
2,4,6-Trichlorophcnol <3.3 <0.2 95.8 <0.2 <IS <0.2 <7 <0.2 <IS <0.2 <13 <0.1 <0.2 <0.2 <0.2
4-Melhylphenol 32.9F <0.2 33.SF <0.J <14 <0.2 <6.4 <0.1 <13 <0.1 <12 <0.t <0.1 <0.1 <0.1
Accnaphthcnc <1.8 <0.1 9.S <0.1 <8.1 <0.1 3.8 <0.1 <7.6 <0.1 18.8 <0.1 <0.1 <0.1 <0.1
Accnaphthylcnc 98.3 <0.1 45.8 <0.1 <12 <0.1 8.3 <0.1 <12 <0.1 20.S <0.1 <0.1 <0.1 <0.1
Anlhraccnc 4.0 <0.1 4.5 <0.1 <11 <0.1 <5.1 <0.1 < 11 <0.1 20.3 <0.1 <0.1 <0.1 <0.l
Bcnzoic acid 19.ll <13 <231 21 <1145 0.4) <540 0.5) < 1100 0.6 <940 1.3 <12 <12 <12
Bcnzo(b )fluoranthcnc <S.9 0.SF <5.4 <0.3 <27 <2.3 <13 1.2F <26 1.4 <22 <0.3 <0.3 <0.3 <0.3
Bcnzo(t)fluoranthcnc <6.5 0.SF <6 <0.3 <30 <0.3 <14 l.2F <28 1.4 <25 <0.3 <0.3 <0.3 <0.3
Bcnzyl aloohol 18.S <0.2 <3.7 <0.2 <18 · <0.2 <8.5 <0.2 <17 <0.2 <15 <0.2 <0.2 <0.2 <0.2
Benz( a )anthraccnc <2.9 1.0 21 <0.1 <13 <0.1 <6.2 0.9 <13 0.8 <12 1.9 <0.1 <0.1 <0.1
Benz(a)pyrcnc <3.4 0.ll <3.1 <0.2 <16 <0.2 <7.2 0.2 <IS 0.1 <13 <0.1 <0.2 <0.2 <0.2
bis(2-E1hylhc:xyl)phthala1e 6.0 4.6 24.6 <0.2 <18 5l.4E 1.SJ 22.8 <17 63.6 <14 23.7 1.02 1.03 <0.2
•
•
1.....1 .....i 1.....1 1.....1 1.....1
I ~II\.r .·· R.J; 1 -:: ... .. ·. : .
.·. : 8-28-93. Analyic.··
lnlcl Oullet lnlcl . •.
Butylbcnzylphlhalatc 5.8 3.3 25.2
Chrysenc · <3.S I.I 40.2
Dibenzoforan 26.4 <0.2 38.9
Diethylphthalalc 23.8 3.3 <3.1
Dimcthylphalhalatc <2.2 <0.1 1.6.J
N w Di-n-butylphthalalc 4.8 0.6 13.7
Di-n-octylphthalatc <2.3 <0.1 <2.1
Fluoranthcnc 7.8 0.7 51.0
Auorcne 11.3 <0.01 34.2
I lc:x.achlorobcnzcnc <2 <0.1 48.6
bophorone 17.4 <0.2 <3.7
Naphthalene 967 <0.2 748
Pentachlorophenol 495 1.2 6974
Phenanlhrcne 18.4 <0.2 36.5
Phenol 384 <0.3 521
Pyrcnc 5.9 0.7 9.3
Swroptc Rca,wric:a (%)
2-Fluorobiphenyl 89 98 91
2-Fluorophenol 95 96 100
.. .
Rim 2
8-29-93
Oulld
<0.2
<0.2
<0.2
<0.2
<0.1
<0.1
<0.1
<0.1
<0.1
<0.1
<0.2
O.IJ
41.7
<0.1
<0.3
<0.1
94
92
1.....1 1....,1 1.....1
Table 2-1
(Continued)
.·;.:" .. · : ·· .. :'-.-::.· ..
·' Rua S .. Ruu4 •.
.. i 8-31-93' 9-01-93
lnlcl Oullet lnlcl Oullet
<19 0.7 8J 3.7
<16 <0.2 <7.4 1.9
<16 <0.2 7.8 <0.2
<16 0.3 <7.2 O.ll
<10 <0.1 <4.4 <0.1
<10 0.3 <4.S 0.2
<II <0.1 <4.9 0.1
<14 <0.1 6.ll 16.1
<12 <0.1 <5.3 <0.1
<9.3 <0.1 <4.4 <0.1
<19 <0.2 <8.6 <0.2 -
629 0.IJ 730 <0.1
<27 26.9 36.6 16.1
<14 <0.l <6.5 <0.1
229 <0.3 224 <0.3
<13 <0.1 5.9 0.4
NC 92 99 94
NC 90 110 94
1....1 1.....1 1.....1 1.....1 1.....1 1.....1 :......J · ......
9~! > F,R..;;i ,·, ".·/ . . FddBlaab I ':9-0:l-93··· 9-03-93 .
,· -·:. ..
·''Inlet
Inlet Outlet . lnlcl : Ou1lcl lnlcl Dup Outlet
<18 2.0 <16 <0.2 <0.2 <0.2 <0.2
<IS 1.2 <13 2.4 <0.2 <0.2 <0.2
126.J <0.2 30.7 <0.1 <0.2 <0.2 <0.2
<IS 0.2 <32 <0.1 0.207 0.212 <0.2
<9.3 <0.1 <8.1 <0.1 <0.1 <0.1 <0.1
<9 0.3 <7.8 <0.1 <0.1 <0.1 <0.1
<9.8 <0.1 <8.S <0.1 <0.1 <0.1 <0.1
9.5 0.3 24.I 2.2 <0.1 <0.1 <0.1
<II <0.1 15.0 <0.1 <0.1 <0.1 <0.1
<8.7 <0.1 <7.6 <0.1 <0.1 <0.1 <0.1
<18 <0.1 <15 <0.1 <0.2 <0.2 <0.2
843 <0.1 2826 <0.1 <0.1 <0.1 <0.1
160 8.9 3285 24 3.76 3.76 <0.3
9.41 <0.1 59.9 0.1 <0.1 <0.1 <0.1
306 <0.3 493 <0.3 <0.3 <0.3 <0.3
!OJ 0.6 29.2 5.1 <0.1 <0.1 <0.1
NC 93 112 93 93 91 89
NC 88 124 90 93 88 94
\....I \...,I \....I '--I .....,
.. · . •:>: •: :c..,)·<: : ·•·.• .. :-··: ,.-.:•,,:
Run 1 · Run2
S-28-93 g.29-93 Analyle :.: . ..
Inlet Outlet Inlet Oulld Inlet
Nitrobcnzcne-dS JOI 86 107 87 NC
Phcnol-dS 117 95 113 94 NC
Tcrphcnyl-dl4 98 95 103 JOI NC
2,4,6-Tribromophcnol 56 81 76 82 NC
:-J
..... .....
Table 2-1
(Continued)
Run ◄ 1 ::. • \.:.,: · ,. Run S
S-31-93 · 9--01-93
Outlet Inlet Outlet
86 272 88
Q,F
90 97 94
97 95 94
81 59 79
..... ""-ii ....,
itwi, f 1. ff ·• ... · .. > Ruu·7
9-02-93 ·• .. 9--03-93 •
··.:· <::•:
Inlet Outlet Inlet Oullct
NC 83 264 82
Q,F
NC 90 102 89
NC 90 104 87
NC 77 68 81
i_ Note: All < values arc detection limits for analytes not detected. Rcsul1s for analy1es dctccled below detection limils arc reponed and J-Oagged.
Qualifiers:
E -Analytc ronccnlration acceded calibration range.
F -ln1erfcrcncc or coclution suspected.
J • Result is less than stated Dctcclion Limit.
NC · Not calculable.
...., ...., .....
~ ..
'FiddB~
. ·. 9--03-93 .
Inlet
Inlet Dup Oullct • 88 87 83
96 93 93
JOO 98 96
79 76 76
•
1...-J 1-J 1-J L......i L-.1 i-J L....I L....J L....I 1-.J L....J L....t'
Table 2-2
Summary of Analysis Results for Particulate and Anions in Soil Reactor OIT-Gas
.
Run 1 Rua2 Run4 RuoS Run 6· Run 7 Field Bbnl: Analytc Units
lnJct Outlet lnJct Outlet Inlet Oulld lnlcl Oulld lnJct Oulld Inlet Outlet Inlet Outlet
HCI' (mg/dscm) o.i97 0.113 6.027 0.153 0.232 0.067 0.169 0.052 0.400 0.230 5.71 0.47 0.160 0.11
a2• (mg/dscm) 0.094 0.089 0.184 0.406 0.090 0.037 0.10S 0.039 0.109 0.073 0.361 0.0214 0.016 0.005
HF (mg/dscm) NA <0.01 NA <0.01 NA <0.01 NA <0.01 NA <0.01 NA <0.01 NA <0.01
Particulate (gr/dscf) 0.037 0.021 0.040 0.021 0.001 0.0004 0.005 0.005 0.021 0.012 0.049 0.028 NA NA
Particulate (lb/hr) 0.024 0.013 0.022 0.012 0.001 0.0002 0.003 0.003 0.009 0.005 0.023 0.013 NA NA
• = Reported as chloride. ,...,
' lJI NA = Nol analyzed.
•
:a..-1 '--' ......, ......, a...-1 '--I ...... .__ i..... .__,
Table 2-3
Summary of Analysis Results for Volatile Organic Compounds in Soil Reactor Off-Gas (ppbv)
< • ·•···<} > ... .. ·• .
·· <Rao6L/ I . . ..
Rua I Rua2 Run4. RllllS Rllll7 I .
S-28-93 . S-29-93 S-31-93 9-01-93 9-02'}3' 9-03-93 • Trip Field
. Blank Blank
Ana~ 1Dld Outlet 1Dld o,uld lnlcl Oulld 1Dld 1Dld Dup Oulld 1Dld Oulld lnld Ou11ct• S-28-93 S-28-93
1,1,1-Trichloroelhane <8 <0.7 <55 <3.1 <900 <5000 <280 <280 <60 <290 <190 <900 NA <0.S <0.9
1,2-Dichlorobcnzcnc 18 <0.7 <55 <3.1 <900 <5000 <280 <280 <60 <290 <190 <900 NA <0.5 <0.9
1,2,4-Trichlorobcnzenc 18 <0.7 <55 <3.t <900 <5000 <280 <280 <60 410 <190 <900 NA <0.S <0.9
1,2,4-Trimethylbc:nzcnc 64 <0.7 58 <3.1 <900 <5000 3000 3000 <60 <290 <190 <900 NA <0.S <0.9
1,3-Buladiene 740 <0.7 2000 <3.1 62000 <5000 24000 24000 10000 10000 11000 46000 NA <0.S <0.9
1,3-Oichlorobcnzene 28 <0.7 <55 <3.1 <900 <5000 <280 <280 <60 <290 <190 <900 NA <0.5 <0.9
N 1,3,5-Trimethylbcnzcne 22 <0.7 <55 <3.1 <900 <5000 1300 1300 <60 <290 <190 <900 NA <0.S <0.9
' °' Acctonilrile <80 <7 <550 <31 <9000 <50000 36000 36000 2000 9000 <1900 <9000 NA <5 <9
Benzene 1200 <0.7 1600 <3.1 16000 <5000 <280 <280 <60 7400 <190 38000 NA <0.S <0.9
Oromomclhane 160 II 1000 8.9 <900 <5000 1400 1200 <60 <290 <190 <900 NA <0.5 <0.9
Chlorobcnzenc 63 <0.7 130 <3.1 <900 <5000 1500 1500 <60 <290 <190 <900 NA <0.S <0.9
Chlorocthanc 200 <0.7 500 <3.l <900 <5000 <280 <280 <60 <290 <190 <900 NA <0.5 <0.9
Chloromcthanc 910 71 13000E 110 1100 <5000 12000 12000 600 980 500 10000 NA <0.S 1.8
Ethyl benzene 130 0.85 120 <3.1 1100 <5000 6500 6400 <60 820 <190 1600 NA <0.S <0.9
Ethyl toluene 80 <7 <SSO <31 <9000 <50000 3600 3600 <600 440 <1900 <9000 NA <5 <9
Methylene chloride 84 29 310 190 <900 <5000 <280 <280 <60 <290 <190 <900 NA <0.5 <0.9
m,p-Xylcnc 300 2.8 350 <3.1 2500 <5000 14000 14000 <60 1700 <190 3100 NA <0.S <0.9
n-Octane 200 <0.7 210 <3.1 2000 <5000 4000 3900 <60 1200 <190 <900 NA <0.S <0.9
o-Xylenc 150 1.5 170 <3.1 1100 <5000 7300 7200 <60 820 <190 1400 NA <0.S <0.9
Propylene 3800E 2.5 1300 610 350000E 630000 IIOOOOE IIOOOOE 22000E 75000E 31000 220000E NA <0.S 1.9
1-J i,......J L..J L,j j_j
Rua 1 Run2
S-28-9] S-29-93 .
. ··•·Analylc Inlet Outld Inlc:i Outlet
Tc1rachloroc1hcnc <8 1.1 <55 <3.l
Toluene 870 3.3 1100 <3.1
Vinyl chloride <8 <0.7 100 <3.1
Swrogatc Ra:ow:ria (%)
N
-'...i Oc1afluoro1olucnc 100 96 100 99
Tolucnc-d8 100 95 96 94
4-Bromonuorobenzcnc 102 104 93 104
a Run 7 outlet aamplc was Josi due 10 now conlrollcr becoming clogged.
E -Eslimaled value, result exceeds inslrumcnl calibration range.
j_j j_j j_j
Run 4
Table 2-3
(Continued)
S-31-93
.
Inlet . Outlet Inlet
<900 <5000 <28-0
12000 <5000 39000
<900 <5000 <280
99 IOI 102
97 102 102
94 89 96
i__J i.___J i.___J i__J a___J L_ __ ...
Rua S Run6 Run 7
9-01-93 9-02-9] 9-03-9] Trip Field
: _::.-.-.-: -:.". Blank Blank
lnk:t Dup Oullet 1nlel Outlet . 1nlel Oudc:ta S-28-9] S-28-93
<28-0 <60 <290 <190 <900 NA <0.5 <0.9
39000 <60 5300 <190 18000 NA <0.5 I
<28-0 <60 <290 <190 <900 NA <0.5 <0.9
104 101 97 97 97 NA 99 99
104 101 95 98 97 NA 95 94
95 96 97 94 99 NA 106 106
•
....I
/ ' ,· :.,., :•. . ...
//·· .;.;;..1y1c
2,3,7,8-TCDD
2,3,7,8-TCDF
Surroplc RCOOYC!J' (%)
13C-2,3,7.8-TCDD
13C-2,3,7,8-TCDF
Amlylc
Tolal TCDD
1,2,3,7,8-PeCDD
Tolal PeCDD
1,2,3,4,7,8-H,CDD
1,2,3,6,7,8-f!JICDD
1,2,3, 7,8,9-f!JICDD
Total l!JICDD
1,2,3,4,6,7,8-HpCDD
Total llpCDD
OCDD
Total TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
i.....J ......i ...... ....... ....... ;..... t.....
Table 2-4
Summary of Analysis Results for Polychlorinated Dibenzo-dioxins and Dibenzofurans
in Soil Reactor Off-Gas (ng/dscm)
. : ~-. .,.: .. ·.•:•···.·•·· '···. / .. ... :<: .,. ··. )<>,,• ,' ...
•• itwi•··· \: R~/ .:. " \ Rune. ; ,, ··-,·.-:':/:· ::: . .• ithii i Ruo·2. ., }~~< ... •·•··•· 8-28-93 8-29-93 .. . 8-31-93 ':-9-01-93 :•::: .. } 9-02-93 ·.:
.. :· .. -::· .... ............ 1•·)/••_?• · .. ·• r• :, __ .. :··
lnlcl . ·. Oulld . Inlet Oullct 1nlci Oullct Inlet Oullct .. 1nlci .•. .:oUiict lnlci' • Outlcl
140E 78.2E 131E 222E 14.9E 3.23 47.2E 447E 264E 147E 179E 119E
7.36C 3.93C 12.SC,E 30.7C,E l.2C 0.206C 2.94C 29.3E,C 15.6C,E 7.06C 29.SC,E 12.SC,E
57 26 52 49 17 34 SI 27 22 ss 19 41
50 24 47 31 19 34 47 23 20 SI 19 35
3490 B,E 2120B,E 3770B,E 8840B,E 61908,E 1458,E 17208,E IIBOOE 7820E 3880E 7250E SIOOE
5098,E 333B,E 3588,E 6808,E 33.9B,E 12.IB,E 3468,E I750E 734E 472E 487E 306E
5390 B,E 3,6008,E 5710B,E 116008,E 525B,E 1888,E 36508,E 24300E 8650E 5480E BBOOE,Q 5900E
580 B,E 362B,E 409B,E 674B,E 21.9B,E 6.78 4988,E 1060E 506E 333E 402E 29IE
702 B,E 442B,E 403B,E 638B,E 25.BB,E 8.29B 5788,E I260E 563E 370E 263E 157
11508,E 6698,E 885B,E 14308,E 50.7B,E 16.2B 9478,E 2150E 93IE 5970E 690E 572E
12,4008,E 74808,E 87608,E 14,7008,E 5568,E 1958,E 112008,E 28900E 6210E 4020E 4560E 3920
5100B,E 3570B,E 30908,E 51408,E 1638,E 38B,E 38908,E 5640E I070E 776E 636E 474E
10,4008,E 7420B,E 62208,E 10,2008,E 3988,E 99.2B,E 78908,E 11900E 2340E I670E 1550E 12IOE
156008,E 8630B,E 54308,E 141008,E 4088,E 63.SB,E 99308,E 12700E 1720E 1500E 856E 565E
5520B,E,1 316B,E,1,Q 757B,E,l 20208,E,l 85.7E,I 14.71 339E,I 1890E,I l ll0E,l 4531 2140E,I 1240E,I
42.2B,C 24.BB,E,1 33.BB,E,1 53.6B,E 2.528,1 0.8058,1 21.98,C,E,I 1251 57.51 37.41 27.6 18.2
14.4C 8.41C,I 31.6C,E 38.IC,E,1 I.Ill 0.25 7.791 46.9 13.3 9.21 13.3 7.91
'--'
• Field:
. Blank ·, 9-03-93
Oullct
1.31
0.llC
28
28
5838,E
3.73B
810B
3.53B
2.3IB
7.97B
9338,S
17.838,E
503B,E
27.68,E
9.271
0.26,
0.1
-....I L.,.J i......l
' :• . >i" -:•, .. .· _: .
Run 1
. 8-28-93
Analytc lnld Outld
Tolal PcCDF 562 B,E,l,Q 413B,E,1
1,2,3,4,7,8-HxCDF 39.8 29.7E,1
1,2,3,6,7,8-HxCDF 38.7 29.5E,1
2,3,4,6,7,8-HxCDF 4.2 2.88
1,2,3,7,8,9-HxCDF 8.87 5.27
Tola! HxCDF 442B,E,1 607B,E,I
1,2,3,4,6,7,8-llpCDF JOBE 86.8E
1,2,3,4,7,8,9-HpCDF 30.5B 23.5B,E
Total llpCDF 313B,E,1 327B,E
OCDF 502B,E 30IB,E
Surrog;atc R"""""J' ('JI,)
IJC-2,3,7,8-TCDD 56 23
JJC-123,7,8-PcCDD 57 25
J3C-J,2,3,6,7,8-l-lxCDD 58 31
I JC-I ,2,3,4,6,7,8-HpCDD -67 32
JJC-OCDD 25 IO
J3C-2,3,7,8-TCDF ss 22
IJC-1 ,2,3,7,8-PcCDF 56 24
J3C-J,2,3,4,7,8-HxCOF 63 32
IJC-J,2,3,4,6,7,8-HpCDF 64 28
i......l
Rwi2
8-29-93
Inlet Oulk:t
I0IOB,E,I 1720B,E,1,Q
53.8E,1 85.2E,1
35E,1 54.IE,1
4.41 7.8IQ
4.42 7.22
729B,E,1 1150B,E,l,Q
85.9E 132E
18.5 29B,E
2988,E 4808,E,1
25IB,E 7928,E
68 68
72 58
69 65
66 65
14 6.9
71 15
59 57
74 71
61 60
~ i.....J ~
.
Table 2-4
(Continued)
· Rwi4
8-31-93
lnld Oullct
56.9B,E,i 18.38,1
2.181 0.7521
1.891 0.8881
0.249 0.0874
0.313 0.0917
25.6B,1 9.2IB,I
3.98 1.08
0.88B 0.0288
14B 3.54B
5.018 0.09398
64 26
65 29
80 41
88 48
63 32
63 27
64 29
BS 39
80 46
L-J l,_j L...I l,_j L • ....J
·. -·•-···>:_· .... /._(· . . . .. ·(y . . . Fldd
RunS Run6 · Rw,7 · Bia.at
9-01-93 9-02-93 9-9-03-93
lnld Outk::f." lnld Outld Inlet Outld Outk::C
3838,E,I 2430E 11601 7811 1290E,I 8681 10.871
36.4E,1 89.91 38.11 31.81 ◄LIE 30.1 0.41
35.6E,I 86.81 26.4 22.8 31.6E 10.2 0.13
3.73 6.68 3.53 2.72 3.82 2.34 0.528,1
5.BSE 12.8 6.77 5.66 2.58 1.66 0.oJ
4378,E,I 11601 5431 4751 472E,I 3161 5.SB,1,O,S
92.4E 143 71.7 56.6 54.JE 32.5 0.498
19.2B,E 29.2 13.4 l0.6 8.84 S.14 0098
3488,E 5350 277 224 J96E 122 1.7B
7478,E 497E 88.4 89.2 38.7 19.J 0.368,S
57 40 62 69 87 71 29
55 29 71 BS 73 15 41
63 36 60 72 75 62 40
64 43 68 70 86 80 48
s 6.S 28 19 87 64 43
ss 33 67 75 70 62 32
56 33 71 82 88 73 40
75 44 69 69 81 63 38
66 42 63 65 80 62 43
N ' -0
'I_.J
'' R,;fL''·.
S-23-93', ..
··AnaJytc Inlet Outlet
MMS Su,rogatc R"""""Y (\ll\)
JJC-1,2,J,4-TCDf 71 71
Inlet
SB
Ruo2
S-29-93
Oullct ·
52
Note: Field Blank values calcula!cd using a nominal volume or 3 dscm.
Oualificn:
B -Anatytc found is associated Jaboralory method blank.
C -Cocluting isomer present.
E -Estima1c only; a:oceds ins1rumcn1 calibration range.
I -Positive polychlorinaled diphcnyl ether interference.
J .-Estimate only; below inslrumcnt calibration range.
NA -Nol analyzed.
Q -Peak prcscnl outside ion ratio limits.
U -Nol detected at the level reported.
i..... i......l .__,.
Table 2-4
(Continued)
Inlet
72
Ruo4
S-31-93
Outlet
74
Inlet
75
RuoS
9-01-93
......_,
Ou11et
71
......_, ......_,
:.· .
auuo
9-02-93
Inlet Outlet
79 81
'--' .......
Run7:
903-93
Inlet Outlet
76 82
'F-ic1<1
. Diani:
9-03-93
Outk::t
80
•
-,
-,
-,
·,
.,
J
l
l
l
l
7
I _;
..
' i ..
RADIAN • • CO. ~ 0 R A-T IO N
Table 2-5
Summary of Analysis Results for Volatile and Semivolatile Organic
Compounds in Liquid Reactor Off-Gas
LTR Run l
9-1-93
,: .. · .. · , Volatile Organic Compound (ppbv)
1, 1, I-Trichloroethane 8700
1,2-Dichlorobenzene <3500
1,2,4-Trichlorobenze <3500
1,2,4-Trirnethylbenze 14000
1,3-Butadiene <3500
1,3-Dichlorobenzene <3500
1,3,5-Trimethylbenze 6900
Acetonitrile <35000
Benzene <3500
Bromomethane <3500
Chlorobenzene <3500
Chloroethane <3500
Chloromethane <3500
Ethyl benzene 56000
Ethyl toluene 19000
Methylene chloride <3500
rn,p-Xylene 120000
n-Octane 180000
a-Xylene 71000
Propylene ll0OO00E
Tetrachloroethene <3500
Toluene 320000
Vinyl chloride <3500
Surrogate Recoveries (%)
Octafluorotoluene 101
Toluene-dB 103
4-Brornofluorobenzene 86
2-11
.,
J
J
]
J
j
]
]
]
]
]
l
]
]
]
]
]
]
]
]
I
RADIAN • co ■~o ■aT10N
Table 2-5
(Continued)
Semivolatile Organic Compound
1,2-Dichlorobenzene
1,2,4-Trichlorobenze
1,3-Dichlorobenzene
1,4-Dichlorobenzene
2-Methylnapthalene
2-Methylphenol
2,4-Dichlorophenol
2,4-5-Trichlorophenol
2,4,6-Trichlorophenol
4-Methylphenol
Acenaphthylene
Anthracene
Benzoic acid
Benzo(b )fluoranthene
Benzo(k)fluoranthene
Benzel alcohol
Benz( a)anthracene
Benz(a)pyrene
bis(2-Ethylhexyl)phthalate
Butylbenzylphthalate
Chrysene
Dibenzofuran
Diethylphthalate
2-12
•
LTR Run 2
9-3-93
(µg/dscm) ·
<2050
< 1900
<2310
<1900
28035
< 1000
< 1830
< 1650
< 1650
< 1500
<1350
< 1745
< 12400 .
<2920
<3220
< 1970
< 1450
< 1670
< 1870
<2000
< 1750·
< 1750
< 1660
-
-
J
J
J
]
]
]
]
]
]
]
]
]
]
]
RADIAN
CORPORATION
Ir ...
•
Table 2-5
(Continued)
. ·• > .··•
> ... · ........... . ··.·.·.·.. <.·· SVOC Analyte ··
Dimethylphathalate
Di-n-butylphthalate
Di-n-octylphthalate
Fluoranthene
Fluorene
Hexachlorobenzene
Isophorone
Napthalene
Pentachlorophenol
Phenanthrene
Phenol
Pyrene
Surrogate Recoveries (%)
2-Fluorobiphenyl
2-Fluorophenol
Nitrobenzene-d5
Phenol-d5
Terphenyl-d5
2,4,6-Tribromophenol
•
Run2
.9-3-93.
(µg/dscm)
<1080
4451
<1140
13501
3494
< 1010
< 1980
68740
<2860
10830
2840
1952
NC
NC
NC
NC
NC
NC
Note: All < values arc Detection Limits for analytcs not detected. Results for scmivolatile organic anaJytcs detected below detection
limits are J-flaggcd.
Qualifiers:
E -Rcsull cxcccds instNmcnt calibration range.
J -Result is below sample-specific detection l.imiL
NC -Not ca.la.dated due to high dilutions.
2-13