NCD003200383_19901011_Koppers Co. Inc._FRBCERCLA RA_Organic and Physical Chemical Data Validation-OCR

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PGH-90-MKL-407
DATE
TO
FROM
SUBJECT
Overview
October 11, 1990
Mr. Roberts. Markwell
Program Manager -Environmental Services
Beazer Materials and Services, Inc.
436 Seventh Avenue
Pittsburgh, Pennsylvania 15219
Mark K. Lentz
AWD Technologies, Inc.
Organic and Physical/Chemical Data Validation
Keystone Environmental Job #M90-05.40
AWD
TtCHNOLOGIES
The set of samples for Beazer (sampled 5/08/90 and 5/09/90)
contained 20 samples. These included: 18 soil samples and
2 rinsate blank. The sample set also included 2 pairs of field
duplicates. Samples were analyzed for phenols by EPA Method 8040.
Summary
All elements were successfully analyzed in all samples. Areas of
concern with respect to data usability are listed according to the
seriousness of the problem. These include:
Minor Issues
2,4-dimethylphenol and 2-chlorophenol were reported in the QA/QC
Lab blank which accompanied these samples. The samples with
positive results for these compounds are qualified "U" if the
result was less in magnitude than five times that of the blank.
Notes
In addition, magnitudes of results for all samples containing
positive hits for 2,4-dimethylphenol and 2-chlorophenol were
underestimated due to blank subtraction. Blank subtraction is
contrary to U.S. EPA guidelines.
AWD Technologies, Inc. Penn Center West. Building Ill, Suite 400 Pittsburgh Pennsylvania 15276 Telephone [phone] Telecopier 412 788 1316
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AWD Technologies, Inc.
PGH-90-MKL-407
Mr. Roberts. Markwell
Beazer Materials and Services, Inc.
October 11, 1990 -Page 2
Information Regarding Report Content
Attachments:
1.
2.
3 •
4.
Glossary of data qualifier codes.
Data Summary. This includes:
a) All positive results with qualifier codes, if applicable;
b) All unusable detection limits qualified with an "R"; and
c) All estimated detection limits qualified with UJ or UL.
Appendix A -results as reported by the laboratory (no
corrections were made during data validation).
Appendix B -Support Documentation includes details to support
the statement in this report.
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AWD Technologies, Inc.
GLOSSARY OF DATA QUALIFIER CODES (ORGANIC)
CODES RELATING TO IDENTIFICATION
(confidence concerning presence or absence of compounds)
< = Not Detected. The associated number indicates approximate
sample concentration necessary to be detected.
u = Not detected substantially above the level reported in
laboratory or field blanks.
(NO CODE)= Confirmed Identification
R = Unreliable Result. Analyte may or may not be present in the
sample. Supporting data necessary to confirm result.
CODES RELATED TO OUANTITATION
(can be used for positive results and sample quantitation limits):
J =
UJ
Analyte present.
precise.
Reported value may not be accurate or
= Not detected. Quantitation limit may be inaccurate or
imprecise.
OTHER CODES
NA= Not Analyzed
I AWO Technologies, Inc.
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I DATA SUMMARY FORMS
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I I NON CLP om FOIi SAMPLES comc1Eo 1/8/90 BEAZER· RALEIGH !eystone En,ironiental loo. I "90·05.10 I Saiple !lo. I 1-168-EA paqe l of l S·lHA S·lHI 1-ll·EA S·lHA S·lHA ----------------------------------------------------------------------------------------········----------------·········---I COIIPOUHO Uni ts ----------------------------------------------------------------------------------------------------------------------------ISolids at 103 ·c I 61.3 13.l 12.l 71.4 67.1 74.4 I lotal Organic Carbon 11100 lOJOO HR HR 80401 I Phenol ug/!g HR 2-ChlorOl)henol 119/!g HR 2-Ni trOl)henol ug/!g HR HR 732 277 111 107 HR mu 387U 430 U 906 HR < 96. 0 111.0 227 m l,4·0i1ethylphenol ug/lg NR I l,4-0ichlor011henol ug/!g HR 4·Chloro·3·1ethylphenol ug/lg HR HR <96.0 <10.0 <71.0 (67.1 HR 126 U <70.0 <71.0 <67.1 HR <96.0 170. 0 410 112 l, 4, 6· 1 ri chlor011henol ug/!g HR HR (l!l <140 <148 <ll4 12,4-0initrOl)henol 119/lg HR 4-Ni tr011henol ug/lg HR HR <l!l <140 <148 <134 HR <Ill <140 <148 <134 l,3,l,6·1etrachlor011~nol ug/lg HR HR <191 <140 1148 1134 I MethyH,6·dinitr011henol ug/!g HR PentachlorOl)henol ug/lg HR HR <192 <140 <148 < 134 HR 116 <140 <148 <!Ji I I I I I I I I I
I I HOM CLP orn FOR mms COLLECTED 1/1/90 BEAZER -RALEIGH I !eystone En,ironmtal Joli. I "90-01.40 I Saaple No. I CONPOUKO Uni ts 11solids at 103 -c Iota! Organic Carbon I 80401 I Phenol 1-Chlorophenol ug/lg ug/lg Hitrophenol • l,Hiaethylphenol l, 4-0ichlorophenol ug/li ug/li ug/lg 4-Chloro-3-aethy!phenol ug/lg • 1,4,Hrichlorophenol l ,4-0ini trophenol ug/lg ug/lg 4-Mitrophenol ug/lg 11,3,1,Hetrachlorophenol 2-Nethy 1-4 ,6-dini trophenol Pentac h lorophenol ug/lg ug/lg ug/lg I I I I I I I I I pa1e l of 3 S-288-EA 5-lMA 5-30-iA S-31-iA 78.2 11 71.3 19 11.8 <61 71.6 113 163 166 411.0 U mu m m 397.0 301.0 117 U 414 U 463.0 U 478.0 U < 64 121 190. 0 113 .0 146 100 90.7 < 63.1 <118 <130 <140 <127 <128 <130 <140 <127 <128 <130 <140 <127 <118 <130 <140 <127 <118 <130 <140 <127 <128 < 130 118.0 <12)
I I IIOII CLP om FOR SAHPLES COLLECTED 5/8/90 and 5/9/90 BEAZER -RALEIGH I leystone En,iron1ental lob. I H90-0I.IO Sa111le Ho. S-32-IA COHPOUHD Uni ts 5-ll-iA S-34-iA S RINSATE S RIHSATE BLAH! BLAH! page 3 of 3 5-168-EA OUP ----------------------------------------------------------------------------------------------------------------------------\Solids at 103 -c t 18 .1 66. 8 59 .1 NR NR 68. l Iota! Organic Carbon ug/lg HR HR NR HR HR 20000 Total Organic Carbon ug/L NR NR HR Cl.00 NR NR 80401 Phenol ug/lg <6U m 98. 8 HR Ni NR l-Chlorophenol ug/!g Ill WU lOlU HR NR NR , .. Mi trophenol ug/lg 298 80 ., C8U Hi HR NR 2, 4-0i 1eth1 !phenol ug/!g mu 1140 U mu HR KR MR 2,4-Dichlorophtnol ug/!g 90. l 234 (84.5 NR MR NR 4-Chloro-l-iethylphenol ug/lg C 64 m <8U NR MR NR 2,4,6-lrichlorophtnol ug/lg (128 <150 <l49 NR MR MR 2,4-0initrophtnol ug/!g (128 <150 (169 HR MR HR 4-Hitrophenol ug/lg (128 CIIO (169 HR HR HR 2, l, 5, 6-1 et rachlorophenol ug/lg (128 CIIO (169 HR MR HR 2-Kethy 1-4, 6-dini trophenol ug/lg <128 (l50 (169 HR HR MR Pentachlorophenol ug/!g (128 CIIO 229 HR HR MR
I AWD Technologies, Inc.
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I RESULTS AS REPORTED BY THE LABORATORY
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2v-J\.li-l'l'i0
S-iry oi Ar,alytinl Results
D,te rece1veo: 9-IIAY-19'10 Custooer: Beazer -Raleigh
,.eystone IO
Date Sapled
Cust011er 1D
Paraeeters Units
lSolids at 103'C ' Total Organic Carbon mgiKg
8040)
Phenol ugiKg
2-Chlorc,pnenol ugi,.g
i·Nitroptier,ol ug/Kg
2,4-uu,ethylphenol Ug/~g
2 ,4-Dichlorophenol ug/Kg
4-Chloro-3-aetny lpher,ol ug/>.g
2141b-Tr1chlorophenol ug.;Kg
2, 4-Dini tropher,<1l ug/,g
4-Nitrophenol ug/,.g
2,3,5,o-Tetrachloropnenol ug/,g
2-~ethy 1-4,b-drni tropner,ol ug/,g
~ent acr1 loropn1:no l ug/Kg
B:J40X Si.Jh1'ffi1TES
2-Fluorophenol • Recovery
2, 4 ,b-Tr 1brv1op:-,enol 4 ~ecover,.-
40-(,(,4 40-l}Jo
8-Ml-!99'j 6-IIAY-1990
S-loB-EA S-23-EA
b5,3 53.2
:-s100 })30c)
Nf; NR
Nk NR
NR NR
NR NR
NR NR
NR NR
NR Nii
NR rli
NR NR
NR NR
NR NR
~~: ti:
NR NR
i~ NR
40-007
B-l'IAv-1m
S-24-EI!
52.2
NR
732
47~
(9b.1)
:9b,(J
120
(96.0
<J92
(192
<192
<.l 92
<.192
216
64.7
75.9
Job nae: "90-05,4(,
40-008
8-PIAl-19'ro
s-:'j-E/1
71.4
NR
'i.77
387
154
(70,0
<7O.O
570
(140
<.l4v
,140
(14Q
<.140
<.140
52.7
7b,9
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i.~--1.1,-, ~ .......
5-,,..,.f ot Ar,;lyuc,I Results
Date recei,,J: 9·1'1AI ·; 9'10
"£fS t or.e l(i
0,te Saapied
CustOlit?r ID
P.ram,ters
-------------
8040X
Pt1H1Ul
2-C!-i lor0p,·1tr,0l
2-Nitro;iMnol
2, 4-L11.n1eth·,-lpheno l
214-[!ii:nlvrophenol
4-ChiJrl:·3-Hthy lpht:riol
2,4,o·Trichlorophenol
i 14-[1in1 trophenvl
4-Nitropaenol
2, 3, :, , b· T ,tr.en lc;rophF,,,i
2-l'letr,-,. l -4 1b·din1 tr0pncr1c•l
~·1:ntacl'"1k,ropner.ol
8<)4(>l 5UfJ;f.13ATES
2-F luorvpr,rnol
2, 4,6-Tr ibroo1c.pnenc,l
Ur,1 ts
,, •
c~).g
ug/~.g
ug/i.g
ug;'f.g
ug;Kg
ug;!.g
ug/•g
ug.-'1..g
ug;Kg
ug_:i.g
ug/~g
ug/t-.g
4 ~i:co·,cr-,.-
l ReCLt-'P"r"
S»ples
41;-0,)9
8-~Y-1990
S-ib-EA
b?.b
43(0
,;_,;_1
·.:4,,:,
<74.1)
411)
'.148
::_148
:.148
:.148
,.148
;t46
05. 7
40-01::, 4/i·Ol l
8-l'IAY • l 990 8·/IAY-19'10
S-2':-EA S·28·EA
74.4 76.2
:1}7 85.8
9"~~ :.03
~ 4'" '•'
,.o7 ,(; 1c~ ·"
\0 7 ,;) ;_c,.1,1)
11: 14b
'; )4 ,.128 ...... , ;_1:b '. l :,-.
'.134 <i:6
:,134 <12&
•.~34 ,.128 ....... -.1,_, .. , 128
b8.2 64.4
7(1,◊ 78.4
Job nae: l'l'IC-05,40
4(1-(:15 40-(Jlo 40-017
8-l'IAY · 1990 8-/IA!· l 9'/t) 8-l'IAY·l'I',:
5·29-WA S-3<)-WA 5-31 ·WA
77.0 71.3 79.0
<o5.0 n,b 123
:.oo 491 449
319 3'17 301
424 4o3 478
121 190 113
1c,0 9(,. 7 \bJ. ~.
,·13(1 (14;) (:27
<. 1 3(J < 14(1 ;_127
< 130 \141) '127
;_130 \140 ( 1:7
i l j<) (140 <.127
;13(1 158 <127
62.2 53.5 oo.B
72.6 77 .1 ,, C 1/,.J
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,eystor,e II,
D.te S••pied
Custo~er ID
Parameters iJr11ts
4;j-(:l&
8-Jl!I~,-i ~9:)
·:i-::·:-w~
4:>:)l'i !cj-1)~0
f-!\.'.\·,-1991) 8-!'1AY-J991j
S-JJ-~ S-j.4-W..
4';-ii2l 4(,-022 4(1-(iiJ
8-~Al-!990 9-IIAY-19% a-1•111'1-l 9->i
5 ,!N5'i!E s R!NSATE S-lbB-EA
BLANK 8LAI« CU:tlCATE
-------------------------------------------------------------------------------------------------------------------------------
,Solias at lOJ'C ' 78.1 bb.B 59.1 NR NR b8.3 •
Total Orgm1c Caroon •gi>-J r;R NR NR NR MR 20<~)0
Total Organic (arbor, •lj,'L ,ir,. NR Nh U.00 NR MR
80401
Pr,er,ol ug;fg <b4.(: 125 98.8 N/1 MR MR
2-Cn loropher,c,l ug/~g 531 447 202 rf.: MR NR
2-N1 tr-opr1Ht0l ug;~q 298 80.b 184.S MR HR NR
i 14-(11tt1et:-1y lp11er1c.l ug/l.g bk 114') 4~,3 NF< NF< ffi
2,4-Dicnlurophenc-i ug;lq 91), 7 ,34 (84.5 Nfi rll rll
4-Cnlorv-J-a-,t tii'f ljjher1ol ulji<.g <o~.v <75.(1 <84,S Ni< NR MR
2,4 16-fr-1chlvruphcr.ol ug.,lq t.126 '. l ~.() '109 NR NR NR
2, 4-[1 m1 trophenc,l ug;·i.g ::126 ,· 1 S,(; ,:109 Ni( NR Nfi
4-Ni trupncnol ug;·lq ,.12B ;_ 1 :,;) , lb9 rlR ~R NR
2,3 1S,b-Tetracnl0rupninol ug;·i.g ~.1 :-; ,.15(! ;JO~ NR Nfi r;,;·
2-fllctny l -4, 0-oir,1 tr..:,pnti1Vl u911.q ,.1:B \ 15(1 ,.10~· NF NR t.lf'i
~tnt a.er-, lo r opr,cno 1 uq:i.g ;_ 1:; -..l~;J Z29 r.-~-N'< Nfi
8041)) 5Uh1'.DGATES
2-F luoropher,ol ' Ficco--,er:,-e,.5. I!! <= ' 43.J im NR ffi .>J,i..
2, 4, 6-1 r iurcifftvptumo: . Ficcu·.;cr·~· 8:.: &8.1 8j, l rii-: Nfi r;F,
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Keystoru: lD
Date Sa,,plea
Custo,;.r ![,
Paraaeters
8(14(,
Phenol
2-Chloropiienol
2-N1trophc:nol
2, 4· 010etny lpher,ol
2, 4-(11cnl,,ropher,ol
4-Cnloro-j-•ethylpne~ol
2,4,6-Tr1chlorophenol
2, 4-0rnii rophenol
4-Nltropnenol
2,3,516-Tetrachlorophenol
2-"etny 1-4 16-dir,1 trophenol
~·ent achlvrupt"renol
S,)4,) SlJii,1JGATES
2-t luor-,:,pt1enol
2:, 4, b· Tr 1nr .:..F10p:-,c:i10l
tm1ts
ugiL
ug/L
ug/L
ug/L
ug/L
cg;L
ug;L
Ugil
ug;L
ug/L
ug;l
ug/L
• Recv·.,itr·r ., Ri.-:,Jw't:.rl •
Sua-arr of A;,fr,tic.! Rescl ts
4(;-(:::1
8-AAY-19%
S idt6ATE
BLAN!s.
<0.5'))
<(1,SI))
,0.5X•
.;_ (;. :'.(1(;
<0.500
,.(!. 5(,j
<l .1j(;
<1.00
d .(M)
<J .00
< 1. 1)1)
:: 1 • (;(1
73.:,
75.:,
4;)-(,::
9-li\/d· ~ 990
; RirlS/-iE
&LANI'
:. (J. 5:)lj
-;_(;. 51)0
:(l,:°,(r.)
•: (;. :',(11)
;_1j,:".t)0
((J, 50v
;I.l<J
(1.0(:
<l,iX1
:_ ! . (~)
\; .00
:_ l. • (1(;
71).0
oB.a
I AWD Technologies, Inc.
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I SUPPORT DOCUMENTATION
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PHENOLS
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JD: l,-QI\ -\JS,LIC)-~c:) \ ,: 1,0\q 0\ \''<' I ~,,u ,-, DATE INJECTED: 7 , 0 RUN f:, 1 ISOL: 1.Jv·
AMT. EXTRACTEO: ___ ML \0 GM FINAL VOL,: \ ML DIL: j I __.__
toMPOUND _______ IR,T, (MIN.) I_RESPONSE_l_coNc. (UG/kj )_ r~L 1 ____ 1 ____ 1_<_S_o,_o __ _
2-CHLOROPHENOL , ____ 1 _l_S_,_l_--'*~-
~-NITROPHENOL. _____ ----____ ,_<_S_o_,o ___ _
1,4-DIMETHYLPHENOL. ___ I ________ ,_\1_), __ :....;.__
f, 4-DICHLOROPHENOL. ___ I. I _<._5_0_, ti ___ _
,-CHLORO-3-METHYLPHENOL_ I , _...JLt ___ _
2,4,6-TRICHLOROPHENOL, __ , 1_< ....... l~00=-·----
1, 4-DINITROPHENOL '-+------
1-NITROPHENOL _____________ --+-----
,,J,5,6-TETRACHLOROPHENOL_I ____ -----+------
4,6-DINITRO-2-METHYLPHENOLI ________ -+-----
'ENTACHLOROPHENOL_· _____________ \J.L.J ___ _
I
1-FWOROPHENOL(SURR) __________ ,_1_9_.~_..,;/,__ __
i, 4, 6-TRIBROMOPHENOL(SURR) '----' , _s_s_ . ....:..4""'1!
0
).---__
I * 'S lA61'-c-d OlAl"" ~ D/J/'C,U,C,'-(::,0{. c2,,Hd.
0 ~0 ~ :;
0;;J I
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PHENOLS
ID: h'.\C)-()S,4~-~,
AMT. EXTRACTED:
~--"'--_,____DATE INJECTEO:~RUN I:~)] \SOL:~
___ KL \t) GM. FINAL VOL. : I ML OIL: J_
COMPOUND
PHENOL
______ IR-T. (MIN.) I_RESPONSE_I_CONC. (~G/ k,)
. _____ 1 ___ 1 ___ 1 <SO.O
2-CHLOROPHENOL
2-NITROPHENOL ___ 1=====1=====1_l __ _
·-----___ I 7~ I, 1S 2,4-DIMETHYLPHENOL
--___ 1 ___ 1 <So,""b 2,4-0ICHLOROPHENOL
4-CHLOR0-3-KETHYLPHENOL_I __ , __ ,_{, __
2,4,6-TRICHLOROPHENOL <loo.
2,4-DINITROPHENOL
4-NITROPHENOL
2,3,5,6-TETRACHLOROPHENOL_I
4,6-DINITR0-2-METHYLPHENOLI 1 ____ -----
PENTACHLOROPHENOL 1 ______ ,...,..) __ _
2-FLUOROPHENOL(SURR)
l,4,6-TRIBROHOPHENOL(SURR) I
~s~~
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r-.ey:it,:,nt i0
Sampi1rig ;,;.1:1t
Cu=t~•i::.r IL:
45vlias ot 103'C
Tc,t1l Cr;1r,1c CirOC•f;
804(,;.
C·r1er,ol
2-Chlc,r .:·~!1ii1•:• l
.:.-N 1 tr C•~·i1!:i1C· l
: 1 ! -(11.rJetiiy lp•,!:r,..:-~
: 14-D 1c;-,lc,rc,pner1c-l
4-Crilorv-j-,,etii"f lpr,-:.;,c,l
2,4 1b·Tr1cnloroph~n0l
:,4-D:nitr0pnen0l
~-N l tr C•Pi:fi,G l
_i I j I: l t. f £tr ac:-, l,:,r-,:,~,r1€i-,:,i
2-:'I'!-: t:"I";-" l -.! , t··C lr1.i tr0pr-1e.r:C• l
~-:n~i~~1;,0~ni~0l
8;;,.:,:;_1 3:_if-.1\C•;:; iE S
:-F 1~0r::-p:-,ei10l
: 1 ! 1 c,-~ r 1or,:,:;ic·;,:,1:.: .ol
lints
•g/L
ug/i:. ,;
ug/t..g
ug/~ g
ug/l;_g
wg/kg
ug/'-.·~
ug/><g
u-;i,·t,_•;
Li•Jil .'l
1_:,;_iL-~
;_i,;,:1._~
tig:' '·-·~
·~ ~ 2cc,p·1·
l f.,•:t,<'r
4(; •(::) i
~_:;"C
LAB ~LMit(
• C: :. ,".
'.·.I\','.'
c9 ; ___ ,;). ;)
:_':-;(,' (;
·.iO(i
; j1j(:
. !:\:
; ~ ::r,::
;;.: _tl(
~~8 CC:rf:RQ~
~111HE
60. 7 ~ ~cc.
tr.2 ~ ~cc.
NE
NR
NF
77.6 l ~:iC.
r,;h·
i:t:,;
tj:,7·\~~i::.
e-:.i::
8:,''
4:)-(:1:
~;:.-~c
~-:E-tA :~·
78. :.
N!i_
4(,-:Jl]
~A _QC
S-:6-EH MS
Nfi
NR
]',2
4(,.2
tlli
~;R
N/;
61.<)
~i
(~~
':,t,,J
r~;-
r~~-
., • ., .
. , •
: .. ::,. 7 ·,
54.(1
E:t,;;
,ec,
R,c.
Rei:.
,,c.
Rte.
41)-(114
QA_OC
S-:B-t;:; ~S[:
Nk
NR
60.5 k ~~c .
61.5 '% ~:ti:.
NR
tlfi
NR
67.6, Re: .
W'<
NR
'5!.4 Re-:,
·' I
!,
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PGH-90-MKL-408
DATE October 11, 1990
TO Mr. Robert S. Markwell
Program Manager -Environmental Services
Beazer Materials and Services, Inc.
436 Seventh Avenue
Pittsburgh, Pennsylvania 15219
FROM Mark K. Lentz
AWD Technologies, Inc.
SUBJECT Organic and Physical/Chemical Data Validation
Keystone Environmental Job #M90-05.16
overview
AWD
TECHNOLOGIES
The set of samples for Beazer
contained 20 samples. These
1 rinsate blank. Samples were
(sampled
included:
analyzed
5/02/90 and 5/03/90)
19 soil samples and
for phenols by EPA
Method 8040.
summary
All elements were successfully analyzed in all samples. Areas of
concern with respect to data usability are listed according to the
seriousness of the problem. These include:
Minor Issues
2,4-dimethylphenol and phenol were reported in the QA/QC Lab blank
which accompanied these samples. The samples with positive results
for these compounds are qualified ''U'' if the result was less in
magnitude than five times that of the blank.
Notes
In addition, magnitudes of results for all samples containing
positive hits for 2,4-dimethylphenol and phenol were underestimated
due to blank subtraction. Blank subtraction is not contrary to
U.S. EPA guidelines.
AWD Technologies. Inc. Penn Genier West. Building Ill. Suite 400 Pittsburgh Pennsylvania 15276 Teleohone 412 788 2717 Telecooier 412 788 1316
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AWD Technologies, Inc.
PGH-90-MKL-408
Mr. Roberts. Markwell
Beazer Materials and Services, Inc.
October 11, 1990 -Page 2
Information Regarding Report Content
Attachments:
1.
2 •
3.
4.
Glossary of data qualifier codes.
Data Summary. This includes:
a) All positive results with qualifier codes, if applicable;
b) All unusable detection limits qualified with an ''R''; and
c) All estimated detection limits qualified with UJ or UL.
Appendix A -results as reported by the laboratory (no
corrections were made during data validation).
Appendix B -Support Documentation includes details to support
the statement in this report.
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AWD Technologies, Inc.
GLOSSARY OF DATA QUALIFIER CODES (ORGANIC)
CODES RELATING TO IDENTIFICATION
(confidence concerning presence or absence of compounds)
< = Not Detected. The associated number indicates approximate
sample concentration necessary to be detected.
U = Not detected substantially above the level reported in
laboratory or field blanks.
(NO CODE) = Confirmed Identification
R = Unreliable Result. Analyte may or may not be present in the
sample. Supporting data necessary to confirm result.
CODES RELATED TO OUANTITATION
(can be used for positive results and sample quantitation limits):
J = Analyte present.
precise.
Reported value may not be accurate or
UJ = Not detected. Quantitation limit may be inaccurate or
imprecise.
OTHER CODES
NA= Not Analyzed
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NON CLP DATA FOR SAMPLES COLLECTED 5/2/90 THRU 5/3/90
BEAZER· RALEIGH
Keystone Envirorwnental Job.# M90-05.16
Sa~le No.
C~POUNO
%Sol ids at 103 ·c
8040X
Phenol
2-Chlorophenol
2-Nitrophenol
2,4-Dimethylphenol
2,4-Dichlorophenol
4-Chloro-3-methylphenol
2,4,6-Trichlorophenol
2,4-Dinitrophenol . \ 4-Nitrophenol
2,3,S,6-Tetrachlorophenol
2-Methyl-4,6-dinitrophenol
Pentachtorophenol
Units
ug/Kg
ug/Kg
ug/Kg
ug/Kg
ug/Kg
ug/Kg
ug/Kg
ug/Kg
ug/Kg
ug/Kg
ug/l(g
ug/lCg
BENTONITE
91.6
<54.4
<54.4
<54.4
136 U
<54.4
<54.4
<109
<109
<109
<109
<109
<109
SANOPACK CEMENT
98.3 98.6
<51 .0 22300
<51.0 <50.5
<51.0 <50.5
<51 .a 32.8 U
<51.0 <50.5
<51 .0 <50.5
<102 <101
<102 <101
<102 <101
<102 <101
<102 <101
<102 <101
X·30CP
2·4 1
79.4
<63.0
<63.0
<63.0
<63.0
<63.0
<63.0
<126
<126
<126
<126
<126
<126
page 1 of 4
86.3 81.9
<63.0 <61.0
<63.0 <61.0
<63.0 <61.0
<63.0 <61.0
<63.0 <61.0
<63.0 <61 .0
<148 <112
<148 <112
<148 <112
<148 <112
<148 <112
<148 <112
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NCO CLP DATA FOR SAMPLES COLLECTED 5/8/90
BEAZER · RALEIGH
Keystone Envirormental Job. # M90-05.16
Sarrple No. X·33CP
a-10 1
X·40EA
6-81
X·41WA
2-4 1
X·41WA
8-101
page 2 of 4
X·9LF
2·4 1
----------········--··----------···············---------------·······-------------------------------------------------------
CO<POUND Units
----------------------------------------------------------------------------------------------------------------------------
\Sol ids at 103 ·c X 88.2 82.6 80.6 85.7 86.5 74.4
Total Organic Carbon
8040X
Phenol ug/Kg <56.5 <60.S <62.0 <58.5 <58.0 107 U
2-Chlorophenol ug/Kg <56.5 <60.5 <62.0 <58.5 <58.0 906
2-Ni trophenol ug/Kg <56.5 <60.5 <62.0 <58.5 <58.0 389
2,4-0imethylphenol ug/Kg <56.5 202 U <62.0 62.8 U <58.0 <67. 7
2,4-Dichlorophenol ug/Kg <56.5 <60.5 <62.0 <58.5 <58.0 <67. 7
4·Chloro·3·..,thylphenol ug/Kg <56.5 <60.5 <62.0 <58.5 <58.0 112
2,4,6-Trichtorophenol ug/Kg <113 <121 <124 <117 <116 <134
2,4-Dinitrophenol ug/Kg <113 <121 <124 <117 <116 <134
4-Nitrophenol ug/Kg <113 <121 <124 <117 <116 <134
2,3,5,6-Tetrachlorophenol ug/Kg <113 <121 <124 <117 <116 <134
2·Methyl·4,6·dinitrophenol ug/Kg <113 <121 <124 <117 <116 <134
Pentachlorophenol ug/Kg <113 <121 <124 <117 <116 <134
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NON CLP DATA FOR SAMPLES COLLECTED 5/8/90 and 5/9/90
BEAZER · RALEIGH
Keystone Envirormental Job.# M90-05.16
Sa~le No.
CCX<PCXJND
XSol ids et 103 ·c
8040X
Phenol
2-Chlorophenol
2-Nitrophenol
2,4-Dimethylphenol
2,4-Dichlorophenol
4-Chloro·3·methylphenol
2,4,6-Trichlorophenol
2,4-Dinitrophenol
4-Nitrophenol
2,3,5,6-Tetrachtorophenol
2-Methyl-4,6-dinitrophenol
Pentachlorophenol
Units
ug/Kg
ug/Kg
ug/Kg
ug/Xg
ug/Kg
ug/Xg
ug/Kg
ug/Kg
ug/Kg
ug/Kg
ug/Kg
ug/Xg
92. 1
<54.5
<54.5
<54.5
<54.5
<54.5
<54.5
<109
<109
190
<109
<109
<109
X·9LF
12• 14 I
87.9
<57.0
<57.0
<57.0
<57.0
<57.0
<57.0
<114
<114
186
<114
<114
<114
X·42"A
2-4'
79.9
<62.5
<62.5
<62.5
<62.5
<62.5
<62.5
<125
<125
<125
<125
<125
<125
X-42"A
12· 14'
76.1
<65.5
<65.5
<65.S
<65.5
<65.5
<65.5
<131
<131
187
<131
<131
<131
X·42"A
18-20 1
83
<60.0
<60.0
<60.0
<60.0
<60.0
<60.0
<120
<120
223
<120
<120
<120
80.5
<62.0
<62.0
<62.0
<62.0
<62.0
<62.0
<124
<124
<124
<124
<124
<124
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NON CLP CATA FOR SAMPLES COLLECTED 5/8/9D and 5/9/90
BEAZER· RALEIGH
Keystone Envirormental Job.# M90-05.16
Sample No.
COMPOLND
%Solids at 103 ·c
8040X
Phenol
2-Chlorophenol
2-Nitrophenol
2,4-0imethylphenol
2,4-0ichlorophenot
4-Chloro-3-methylphenol
2,4,6-Trichlorophenol
2,4-Dinitrophenol
4-Nitrophenol
2,3,5,6-Tetrachlorophenol
2-Methyl-4,6-dinitrophenol
Pentachlorophenol
8040
Phenol
2-Chlorophenol
2-Nitrophenol
2,4-Dimethylphenol
2,4-Dichlorophenol
4-Chloro-3-methylphenol
2,4,6-Trichlorophenol
2,4-Dinitrophenol
4-Ni trophenol
2,3,5,6-Tetrachlorophenol
2-Methyl-4,6-dinitrophenol
Pentachlorophenol
Units
%
ug/Kg
ug/Kg
ug/Kg
ug/Kg
ug/Kg
ug/Kg
ug/Kg
ug/Kg
ug/Kg
ug/Kg
ug/Kg
ug/Kg
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/l
ug/L
ug/L
ug/L
ug/L
ug/L
X·44~A
8-10'
87.3
<57.5
<57.5
<57.5
<57.5
<57.5
<57.5
<115
<115
127
<115
<115
<115
X RINSATE
( ug/L)
<0.500
<0.500
<0.500
0.5
<0.500
<0.500
<1.00
<1.00
<1.00
<1.00
<1.00
<1.00
I AWO Technologies, Inc.
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I RESULTS AS REPORTED BY THE LABORATORY
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~.e·7s tor11:. I£:
One Saapleo
Customer !~
Paraeters
:Svllds ;t 10J·c
80401
Phrnol
:-Cnlor -:,pne11C• l
2-N l tr l•;i1€i,O 1
2, 4-(111:t thy lp:io.:r1c-l
2, 4-Dic~ilc,rc,pneno l
4-C!,lc.rc,-j•11cthy lp~u:.r,i:i 1
2,~,o-T,1~nl0rop~cno1
2, 4-Dir, i tr ,:,pi11mu l
4-tH tr(,pi1ff1C,l
2,3,51b·fctrac~i0~0pnen~l
2-llleth"f 1-~, o·WHd t rv~i\'!?1Vl
C•erit acr, l~,r ,.:,~:,cr1c,l
81;4,); S!»DGi;TE3
~-F luc,ri::,pru:r,..:,l
: 14 ,b·; r iur v:~0pnu1c,l
Ur,1ts
'
ug/•,g
U(Jif ']
ug;~,g
ug;~g
ug,,i g
ug/~~
ag;i g
ug/~-.g
,.;g/q
ug/~.•~
ug/f,,J
ugh,g
., f:cc0vtr)'" •
' tl.c-:c.-,e.ri
S "'P les
:o-<X3 1,::,-!)(:.!
~-M,;Y-19-?(i :-i'!Ar-I 9'i'(;
BENTGNIH SAtJ-.:·ACK
91.b 9B,j
;,54. :, (:°,l,(l
::A.:. :-51.:)
; 5➔• 5 : :.; .J
L.Jt, ,:,1.0
:i::-., : •.51 I;) '--· .-
,~/ C :.51.:) ........ _.
:.. 1 ;)9 ,_l(;i
:.1 v--;· -:_ 1 (;i
' I V'i ; j1)i
<1li'1 :_11)2
:.1 ;)9 '-l ij2
;,l(i~ ·;.1,:,2
~= C 6:,.(; I·.'•·•'
7tl. (; ,'t,, :,
Joe n••e: "90-<)5, lb
l o-()(J:. 10-0vo 10-1)(;7 16-(.('8
2-i',';1-1990 i-111.AY-199(1 2-ll'tAY-1991) 2-1:AY-I 9'ic:
CEMENi X -J(>CP 2-4' l-30CP 8-10' .:.-3XP 4-6'
98.b 79.2 &,,J 81.9
2~J.\: ',oJ.O (':,8,0 <ol.O
. .: ;. C 'b3,0 {_~.a. (1 ;.bl.(1 '..''.'o.J
· .• -J. -· <,oJ,1) <.58.U (bl,(,
2:.8 \63.(i (58 ,(J •.bl , (i ,_:~:•, :. Cb],0 <58.1) <61.0
c;, <bj,1j <:-8.(} ;_t: ~ ,(j .._ .r,:, _,
:_ i <)l ~.lib (116 t, 122
;_l(ij_ ,:120 t.1 lb ~.12.i . ,.·,, ::126 ~ l lb ; ' ,,, • .•• , J '. >L<l.
;_l(:1 <12o ',l lb ::1:2
:..11:11 d2o I! lb , 122
;_Ll \120 <I lb ::1:.:
}.!,j ~2.7 >< < I ·.Jo.• 07 .3
h·.c b9 ,;· 71.9 , ... -. , .....
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i..: .•. ., ..... ' .
,.__eystor,c Hi
D,t,; Suplcd
Custvliler rn
PHa•eters
l5olios at 103'C
8().\0l
~r,er,ol
i-Chlorophcmol
2-Ni tr(,ptltriol
214-D lJiu:tn f lprit!Ml
i,4-Dichl~roph€nGl
4-Chloro-3-,,eth; lpher,0:
2, 4 ,6-Tr iciilor opt',cnol
2, 4-Dmi tropru:nol
4-Mitropncr,ul
2,3,5,6-TctrachlorophE~0l
;:-"etny 1-4 16-drn1 t r,ipr,,;r,ol
f•entacn lo ropher,o 1
tKI.\Oi SURRQG;;TES
:-F luorophEr,ol
2, 416· Tr ibrooopiii:r,v 1
ugjig
ug,'t.g
ug,lg
ugi, g
ugj•.g
ug,'l\g
ug/1\g
ug,',.g
ug/,.g
ug/,g
ug;,g
ug/i g
~ fii:ClWH'f
~ ~.t.CCIVt!'y'
S.il!,p les
10-(;(rf
2·t4A'r-199(1
)_ -J.3CP 8-1(,·
,So.5
(50. ':,
t.5-6.:,
:::-6.'5
,:~.5
<':to.5
(113
\l 13
d i3
,.113
0.113
<! 13
i,<l, 0
b8.1
Cust01,er: Be,zer -e,le1gn Job r,ioe: ~9<)-(15, lb
l C• ·t) l (J lo-,)11 lo-015 lo-Olo
i-tt.A'f-19';<• 2-r-tAY-19-?1) i-~y-1990 i-MAY-1Y9fi
.• -!1)EA :'.•4' > •41JtA o-8' X-4lloi.i 2-4 1 1-41\11,'; 8-1(,·
8'.c.o 8<,.b 8'5,7 86.5
\0(),5 <o?.O \:.a .. 5 <58.0
·:.,,.:,,5 :..62.(1 ..-c-C ',.,d. ,J <SB.(,
q:ii),5 :.6i.V ,.~.a. 5 1:8.0
.:.·:.:. -;,o2 .0 t2.8 <58.0
\b•:1. 5 .· ., . \0.;.,(J ,5,J,5 <.'5t3. (l
<o(,. S \02,tJ (56.:, <:.a.I)
'121 <1:4 <.117 <116
<121 <124 <.1 l 7 (!lb
-;.121 (124 (117 ( l 16
<.1.~l (124 (117 <.llo
<121 <.124 q17 <116
< l ::1 <124 <117 <.! lo
88.4 88.4 94.0 :,2,4
89. 1 92.4 90.o 70,4
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I ,J. ~•J,• I.
~.cys~or1e :r1
DHe Saapl,d
CustOR1•' J[;
lSohds at lOJ'C
0040X
Phenol
2-Chli:,ropiier,ol
2-Nitropi,<:nul
2, 4-Di•etny ipnenol
214-0icri loropnenol
4-Chloro-3-1,.thy lpheno i
i 14, b-T r 1chlc,r.:,pliinul
21 4-[,initrophenc.l
4-Nitrophenol
2, j 15 ,o-T etr aci1h1rvpt1er1~• l
2-~c thy 1-4 ,0-dmi t ropricnol
P'eritacnlor t:,pheriol
a,w,i StJ-f<w;\ T t S
2-F luoropi,cnvl
2, 4, b-Tr iori:ott10pr1Ciiol
).
U9il.g
ug/~.g
ug;rg
ug/Kg
ug/Kg
ug/,.g
U9iSlj
ug/,.g
ugi>g
ug/~g
•jg;r.g
ug;fg
' Fcc~vc.ry ., RccJ·.-cr-,. •
10-:)15 lo-(•l 9
3-P\A·y· -1 S·S 1J J-IIAY-1990
I -9Lf :-4 ,-9Lf b-8'
84.b 92, l
,59.0 ,.54.5
<:,9 ,(; :.54.:
i59,!) <:"4.5
(5~· .0 <:-4. :,
~59 ,1) (.':,4,5
<:,9.(: (54.5
'118 ,11)9
• ◄ I -\ I J lj ,.tt)<i
, 118 19ti
q 1.j '.109
\11~ \ 11j'f
jo(; \l(G
3&.(; 63.3
o4.8 a1.2
1,,-0::V lo-:)21 lo-1)22 lb-02j
HIAY-1991j J-Mi.-19% J-~AY-l 99li 3-MA~ -1 ~-~
~-9LF 1:-14' J-42W?; 2-4' X-42\IIA 12-14 X-42 1e-:,;
87.9 79,9 76. l 83.0
,57.0 <b2.S <65.5 <.60.0
(57.0 <.b2,5 {65,5 <bO.O
<57.0 <.62,5 <:65.5 (l,O. 1)
(57 ,lj <62.5 (65.5 (l,0,0
,57.0 (62.5 (65.5 <bO.O
,57 ,(, (62.5 (65.5 (l,0,0
<114 q~. < 131 (121)
\ l 14 \125 '131 \12\l
186 <.125 187 223
< 114 : 12'5 (131 1,120
; 114 ;_125 1.131 ~.121)
:.ll4 ~.125 <.131 <120
·-' l!)J •. 60, l 79 ,9 71.o
75.4 79.2 88.: 64.5
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Ketstone ID
Oate Saplea
Custo;,er ID
Para,;eters
------------
lSollas •t 11;J'C
804Ul
i'her,ol
i-Cr1i0r ~,pru:r,01
i-Nitr0piiff1Ul
2, 4-(1 Uit'=tn7· lpncru.:il
2, 4-(iichlorophenol
4-Cnloro· 3-oethy lpt.e0,ol
2 ,4,b· Tr 1ctdc,roptu:nol
2, 4-[1m1 tr~ipneriol
4-Nitropnenol
2, 3, 516· T etrachloropneno l
2-"etnt 1-4,t:·Cir,1 tropher,o 1
~·er1t achloropr11:nol
BtJ401 ~TES
2-F luoropn.nol
21416-Tr 1trCifi10phlfft0l
units
'
ug/l.g
UIJ/~-9
ug;lg
ug;,.g
ug/ig
ug/~g
ug/1.g
ug/,.g
ug/Kg
ug/i.g
ug/Kg
ug;,.g
4 R1:covery
l f<ecov;ry
16•!)~4 lb-02~
Hl.11· 199,j J-'1AT · l 9'10
i-44~!\ 4-o' l·44flA 8-1(1'
8(i. 5
,02,1)
\6? ,(;
•.bi,0
<..bi,(i
' . ,.o"'.v
(02.(i
,:i:4
,L14
'124
q~4
-:t24
,.1:i
79.9
935
87.3
·:..57 -~·
'115
;,115
i.27
<.11 :-
< 115
·.115
78.5
9(;,8
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~.e·1stor,e ID
Oate Sa•pleo
Custoiaer i:U
P-1ras11:ters
lo·(;~~-
2•'1'.A) -1191)
-~ ~-i Nij; T(
-------------------------------------------------------------------------------------------------------------------------------
8(J4(,
Phenol ug;L ;_0. ':,0ij
2-Cnloropr,enol ug/L ,.(1, :.(M;
2-Nitrophenol ug;L ! ,J •. s,::,J
2, 4-Ui1tethy lprier,L• l ug/L 1:1.:.,:,;:1
2,4-Dichloropnenol ug;L :,),$Vi)
4-Cr,loro-j-•etny lpnenoi ug;l ;_tj. 5t;(:
2,4,o-Tr1cnloropnenol ug/L ,1.1)1)
2, 4-[11ni tropn£ncl ug;l •:_ l, Ut)
4-N1tro~neriol ug/l 'l. 0,)
2,3,5,b·Tetrachlorophenol UgJL ( 1. (.1(;
2-Methy 1-4 ,b-aini t rop!'ltr,vi ug;l ,1.01)
~·c.nt 11chlo r opr1eno l ug; l ;_ 1. ;J(;
&14:) Si.JR!i'OGATES
2-F luor.Jpt1tr1ol ' F;eco-..•cr·,-J~ .B
2, 4 1b· Tr 1t,r C•lltOphe.r1L• i • ~.ecc·.cr1 :"-i:::i,,.:.
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KEYSTONE ENVIRONMENTAL RESOURCES, INC.
CASE NARRATIVE
I GENERAL
A. WORK ORDER M90-05.16
B. SAMPLE NUMBERS
C. SHIPPING PROBLEMS
II ANALY~.IS
A. ANALYSIS PROBLEMS
B. COMMENTS
001-025
None -------------------
None _________________ _
All soil results are on a dry weight basis.
All 8040 identifications are from retention
time only. The Lab Control Blank sample for
soil samples contained the components Phenol
and 2,4-dimethylphenol. These values were then
subtracted out of the results for the entire
work order of soil samples. These inter-
ferences come from the extraction procedure
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Keyst.ir,€ ID
sa~pirng Pornt
Custc~,H IL
81)4,n.
~-r,-:r,vl
2 -Cr,k,t ,::.p~erio l
i-r,i 1 tr c,pi1ii1C•l
2, 4-[11~1etny lpher1L• l
2,4-D1cnlor0pneriol
4-C,,iorc,-3-mctriy lpr,er,c,l
2, 4, 6-Tr 1a,loropnu,c l
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\
' ,
PGH-90-TMJ-409
DATE
TO
FROM
SUBJECT
Overview
October 11, 1990
Mr. Roberts. Markwell
Program Manager -Environmental Services
Beazer Materials and Services, Inc.
436 Seventh Avenue
Pittsburgh, Pennsylvania 15219
Thomas M. Jackman
AWD Technologies, Inc.
Organic and Physical/Chemical Data Validation
Keystone Environmental Job #M90-07.53
AWD
TiatNOLOGIES
The set of samples for Beazer (sampled 7/13/90) contained 4 water
samples including 1 pair of field duplicates, 1 field blank and
1 trip blank. Samples were analyzed for Isopropyl Ether, Phenols,
Dissolved Calcium, Dissolved Potassium, Dissolved Magnesium,
Dissolved Sodium, Total Alkalinity, Carbonate Alkalinity,
Bicarbonate Alkalinity, Chloride and Sulfate. Isopropyl ether was
analyzed by EPA Method 602; phenols were analyzed by Method 8040;
pentachlorophenol was also analyzed by Method GC515; metals and
physical/chemical parameters were analyzed by approved EPA methods.
Summary
All compounds were successfully analyzed in all samples. Areas of
concern with respect to data usability are listed according to the
seriousness of the problem.
Major Problems
Surrogate recoveries for the field blank accompanying this package
exhibited significant interferences and a very low recovery in the
analysis of phenols (Method 8040). Because of these interferences,
positive results for the field blank are qualified ''J'', estimated
and detection limits are qualified ''UJ'', estimated. (Appendix B
contains the chromatogram and raw data for the field blank).
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AWD Technologies, Inc.
PGH-90-TMJ-409
Mr. Robert S. Markwell
Beazer Materials and Services, Inc.
October 11, 1990 -Page 2
The field blank contained phenol, 2-ni trophenol, 2, 4-dimethyl-
phenol, 2,4-dichlorophenol, 4-chloro-3-methylphenol, 2,4,6-
trichlorophenol, 4-nitrophenol, 2,3,5,6-tetrachlorophenol,
2-methyl-4,6-dinitrophenol, 2,4-dinitrophenolandpentachlorophenol
(Method 8040) at concentrations exceeding levels in the samples.
Therefore positive samples results of these compounds are qualified
"U".
Minor Problems
Matrix interferences prevented the surrogate recovery of
pentachlorophenol analyzed by Method GC515 in sample C-24-0SE.
Therefore the positive pentachlorophenol result for this sample is
qualified ''J", estimated.
Notes
The positive result for 2-chlorophenol (25.0 ug/L) in sample
C-24-0SE was miscalculated by the laboratory. The corrected value,
29.0 ug/L, is reported in the data summary.
The data package contained no quality control or raw data for
metals. Therefore evaluation of metal results could be performed.
The interferences in the analysis of the field blank, described
above, raise questions regarding the usability of the phenol data,
i.e., is it reliable or not? Although the phenol results were
reviewed in strict accordance with EPA validation guidelines, the
significant interferences, in the opinion of the reviewer, cast
doubt both on the value of blank results and their subsequent
impact on sample results.
The data were reviewed according to the National Functional
Guidelines for Evaluating Organic and Inorganic Analyses. The text
of this report addresses only those problems affecting usability.
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AWD Technologies, Inc.
PGH-90-TMJ-409
Mr. Roberts. Markwell
Beazer Materials and Services, Inc.
October 11, 1990 -Page 3
Information Regarding Report Content
Attachments:
1.
2 .
3 •
4.
Glossary of data qualifier codes.
Data summary. This includes:
a) All positive results with qualifier codes, if applicable;
b) All unusable detection limits qualified with an "R''; and
c) All estimated detection limits qualified with UJ.
Appendix A -results as reported by the laboratory (no
corrections were made during data validation).
Appendix B -Support Documentation includes details to support
the statements in this report.
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AWO Technologies, Inc.
GLOSSARY OF DATA QUALIFIER CODES
CODES RELATING TO IDENTIFICATION
(confidence concerning presence or absence of compounds)
< = Not Detected. The associated number indicates approximate
sample concentration necessary to be detected.
U = Not detected substantially above the level reported in
laboratory or field blanks.
(NO CODE) = Confirmed Identification
R = Unreliable Result. Analyte may or may not be present in the
sample. Supporting data necessary to confirm result.
CODES RELATED TO QUANTITATION
(can be used for positive results and sample quantitation limits):
J = Analyte present.
precise.
Reported value may not be accurate or
UJ = Not detected. Quantitation limit may be inaccurate or
imprecise.
OTHER CODES
NR = Not Analyzed
I AWD Technologies, Inc.
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I DATA SUMMARY FORMS
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DATA SUMMARY
I NON CLP DATA FOR SAMPLES COLLECTED 7/13/90
Keystone Envirormental Job.# M90·07.53
I Salfl)le No. C-24-0SE
I
COMPOUND Units
I Total Alkalinity as CaC03 mg/L 210
Chloride mg/L 157
Carbonate Alkalinity as CaC03 mg/L 40.4
I Bicarbonate Alkalinity as CaC03 mg/L 170
Sul fate mg/L 12.5
Dissolved Calciun ug/L 16200
I Dissolved Potassiun ug/L <5000
Dissolved MangesiLEl ug/L 5670
Dissolved Sodiun ug/L 18200
I Isopropyl Ether ug/L <1.00
Phenol ug/L <O. 500
2-Chlorophenol ug/L 29.0
I 2-Nitrophenol ug/L <0.500
2,4-Dimethylphenol ug/L <0.500
2,4-0ichlorophenot ug/L <0.500
I 4-Chloro-3-methylphenol ug/l <0.500
2,4,6-Trichlorophenol ug/L 2.53 U
2,4-Dinitrophenol ug/L <1.00
4-Nitrophenol ug/l <1.00
I 2,3,5,6-Tetrachlorophenol ug/L 4.9 U
2-Methyl-4,6-dinitrophenol ug/l 1.10 U
Pentachlorophenol ug/l 1.56 U
Pentachlorophenol (GC515) ug/L 0.015 J
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C-24-0SE
DUPLICATE
MR
MR
MR
MR
MR
MR
NR
NR
NR
<1.00
<0.500
24.2
<0.500
<0.500
<0.500
<0.500
<1.00
<1.00
<1.00
4.24
1.65
2.91
0.014
u
u
u
F !ELD
BLANK
MR
MR
MR
MR
MR
MR
NR
MR
MR
<1.00
3.72 J
<0.500 UJ
3.45 J
0.920 J
<0.500 UJ
9.05 J
2.05 J
<1.00 UJ
26.6
86.4 J
6.31 J
1.35 J
<0.010
TRIP
BLANK
MR
MR
MR
MR
MR
MR
NR
MR
NR
<1.00
NR
MR
NR
NR
NR
NR
NR
NR
MR
NR
NR
MR
NR
I AWD Technologies, Inc.
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APPENDIX A
I RESULTS AS REPORTED BY THE LABORATORY
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24-/;UG-19%
Sum11,ary oi Analytical Results
Dlte received: 14-JUL-19% Customer: Beazer -Raleigh Job nae: ~90-07.53
Keystone ID
Date Sampled
Customer ID
Parameters Units
Total Alkalinity as CaC03 mlj/L
Chloride •gil
Carbonate Alkalinity as C,C03 •gJL
Bicarbonate Alkalinity as CaCOJ rng/L
Sulfate mg/L
Dissolved Calcium ug/L
Dissolved i·ohssiU<T, ug;L
Dissolved ~agr,esium ug/L
Dissol';ed Sodium ug/l
GC515
Penhchlorophenol
GC515 SURROGATES
ug/L
Samples
53-003
13-JUL-1990
C-24-0SE
210
157
40.4
170
12.:,
16200
<:,000
5670
182000
0.015
Tr ibrooopnenol ,Recovery M,trix Int.
53-007 53-008
13-JUL-1990 13-JUL-1990
C-24C-OSE DUPLICATE FB
NR Nii
NR NR
NR NR
NR NR
NR Nfi
NR NR
NR NR
"' NR
NR NR
0.014 (0.010
110 69, l
Page
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24-AU;· l 9W
S"""ary of Ana1"1tical Results
t•ne rece1veo: 14-JUL-1990 Custoa;er: 6e1zer -Raleigh
keystone Ifi
Date Sapled
Cust001er ID
Paraoeters Units
802v
Isopropyl Ether ug/L
802\l SURhW.TES
Benzotriiluor1oe l Recovery
8040
~henol ug/L
2-Chlorophenol ug/L
2-Nitrophenol ug/L
2,4-Dimethylphenol ug/L
214-D1chlorophenol ug/L
4-Cnloro-3-oetnylpnenol ug/L
2,4,6-Trichloropnenol ug/L
214-Dirii trophenol ug/L
4-Nitrophenol ug/L
2,3,5,6-Tetrachlorophenol ug/L
2-Methy J -4 ,6-dini trophenol ug/L
Pentac:nloropnt!nol ug/L
8040 SLJRROGMES
2-Fluoropnenol , Recovery
2, 4, 6-T r ibroo,;phenol , Recover(
Sa•pies
53-1)1)3
13-JUL-1990
C-24-0SE
{1.00
106
<0.500
2'5.0
(0.500
(0,50(1
(0.500
<.0.50<)
~.53
<l.O<i
'1.00
4.90
1. 10
1.56
;·o.J
76.0
oJ-007
13-JUL-1990
C-24C-0St DUPLICATE
(1.00
99.2
<0.500
24.2
(0,500
<0.500
<0.500
<0.500
<1.00
< 1. 1)(1
(1.00
4.24
1.65
2.?l
37. 7
68.4
Job na•e: ~90-07.53
53-00E
13-JlJL-l'm
f&
(1.00
93.2
3.72
(0.500
3.45
0.920
(0.500
9.05
2.05
(1.00
2ti.6
86.4
b,31
1.35
14.5
~atrix Int,
53-009
!J-JUL-1990
T6
(1.00
93.2
NR
NR
NR
NR
NR
NR
NR
N~:
NR
NR
NR
Nii
NR
NR
Page 2
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AWD Technologies. Inc.
APPENDIX B
SUPPORT DOCUMENTATION
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