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Home My WebLink AboutNCD003200383_19901008_Koppers Co. Inc._FRBCERCLA RA_Organic and Physical Chemical Data Validation-OCRI I I I I I I I I I I I I I I I I I I AWD TECHNOLOGIES PGH-90-DAL-374 DATE TO FROM SUBJECT overview October 8, 1990 Mr. Robert S. Markwell Program Manager -Environmental Services Beazer Materials and Services, Inc. 436 seventh Avenue Pittsburgh, Pennsylvania 15219 David A. Lang AWD Technologies, Inc. Organic and Physical/Chemical Data Validation Keystone Environmental Work Order No. M90-07.34 The set of samples for Beazer (sampled 7/10/90 -7/11/90) contained 16 samples. These included 12 water samples (one duplicate), 2 trip blanks, and 2 field blanks. Samples were analyzed for total alkalinity, chloride, carbonate alkalinity, bicarbonate alkalinity, sulfate, dissolved calcium, dissolved potassium, dissolved magnesium, dissolved sodium, isopropy 1 ether, and phenols. Isopropyl ether was analyzed by Method 8020 and phenols were analyzed by Method 8040. Pentachlorophenol was analyzed by both Method 804 O and Method GC5 l 5, and phys ica 1 / chemica 1 parameters were analyzed by accepted U.S. EPA methods. summary All elements were successfully analyzed in all samples. Areas of concern with respect to data usability are listed according to the seriousness Qualifiers affected. of the problem. Note that the Summary of Data (Table 1) lists the specific samples which were These include: Minor Issues Phenol, 2-chlorophenol, 2-nitrophenol, 2,4-dichlorophenol, 4-nitrophenol, and pentachlorophenol were detected in laboratory and/or field blanks of levels which required qualification of data. Positive sample results with concentrations less than 5 times the amount present in the blanks are qualified ''U''. The surrogate spike recovery for pentachlorophenol was high for samples C-llB-OSE, C-llB-OSE DUP, and FB (7/11/90). Therefore, the results of these samples have been qualified ''J'', estimated. AWD Technologies. Inc. Penn Center West. Building Ill. Suite 400 Pitlsburgh Pennsylvania 15276 Telephone 412 788 2717 Telecopier 412 788 1316 I I I I I I I I I I I I I I I I I I AWD Technologies, Inc. PGH-90-DAL-374 Mr. Robert S. Markwell Beazer Materials and Services, Inc. October 8, 1990 -Page 2 Notes Matrix interference prevented the recoveries for pentachlorophenol for M-9-CP, and Well C-lB OSN. calculation of surrogate samples C-29B-EA, M-4-EA, Blank contamination concentrations were subtracted out for other sample results. The practice of subtracting out to adjust for blank contamination is not consistent with EPA Methodology. Information Regarding Report Content Table 1 1s a summary of qua 1 if iers added to the laboratory's results during data validation. Attachments: 1. 2. 3 • 4. Glossary of data qualifiers. Data Summary. This includes: a. All positive results with qualifier codes, if applicable. b. All unusable detection limits qualified with an ''R.'' c. All estimated detection limits qualified with ''UJ.'' Appendix A Results as reported by the laboratory (no corrections were made during data validation). Appendix B -Support Documentation includes details to support the statement of this report. I I I I I I I I I I I I I I I I I I I AWD Technologies, Inc. GLOSSARY OF DATA QUALIFIER CODES (ORGANICS) Codes Relating to Identification (confidence concerning presence or absence of compounds) u = Not Detected. The associated number indicates approximate sample concentration necessary to be detected, or not detected substantially above the level reported in laboratory or field blanks. (NO CODE) = Confirmed Identification. R = Unreliable Result. Analyte may or may not be present in the sample. Supporting data necessary to confirm result. Codes Related to ouantitation (can be used for positive results and sample quantitation limits) J = UJ = Analyte present. precise. Reported value may not be accurate or Not detected. imprecise. Quantitation limit may be inaccurate or Other Codes Q = No analytical result. I lum1 SUKXARY OF om QUALIFIERS IEYS!ONE IOR! OiDER 1110·07.34 1 ........................................................................................................................... . Analyte Suplu Aff1cted Positive Ion Bias CoueAts • Results D1tect1 --------------------------------------------······-----······---------------------------······-······---------------------Phenol lell C·ll OSN, lell Ml OSI U HIGH I lell MB OSk, lell MC OSk C·lll·OSE, l·Hl, !·MP ·1·Ch loropheno 1 ·1·iitrophenol .1,Hichloropheno 1 Hi tropheno 1 .Pentach loropheno 1 (GC515) lell C·ll OSI, lell C·lB OSI lell C·9l OSN, lell C·9B OSI lell C·9C OSN, !·9·CP lell C·ll OSk, iell Ml OSI iell MC OSI lell C·ll OSN, iell Ml OSI lell C·98 OSN, iell C·9C OSk lell Ml OSI, lell MC OSN u u u C·11l·OSE, C·98·0SN U C·11B·OSE, C·118·0SE OUP, fB (l/11/90) J HIGH HIGH HIGH HIGH HIGH HIG!I ··························································································································-· • comm 1. Laboratory ind/or field blank contuination. 11. High surrogate spike recovery • • • I I I I I I AWO Technologies, Inc. I I I I I I I I I DATA SUMMARY FORMS I I I I I I I I I I I lsunm 01 CLP DATI FDR SAIPLES COLLECTED l/l0/90·7/ll/!D IER • RALEIGH tone Envirmental Job. I !90·01.34 I OF 3 I Sup le No.ml C-IA OSI WELL C-11 OSN WELL MB OSI WELL HA OSN WELL HI OSI IEll HC OSI ·---------------------------------------------------------··········---------------------------------------------------I JMPOUID Units 1--------------------------------------------------------------------------------------------------------····----·---------------1 Alk1linity as C1C03 19/l 217 NR 314 222 191 ride 19/l 408 IR ll.6 64.1 81.8 1rbon1te Alkalinity II CaC03 19/l 0.000 IR 0.000 0.000 75.4 lrbonate Allalinity as CaC03 19/l 217 NR 314 !22 120 ate 19/l 18.4 IR uo I.lo 21.40 issolved C1lclu1 ug/L 101000 NR moo moo 1480 901ved Potassiua ug/L 5670 NR <1000 <1000 1990 •o lved !19nes iua ug/l 89000 NR 13200 22400 <1000 1ssolved Sodiu1 ug/l 97600 NR 18700 31300 90000 lropyl Ether lol loropheno 1 ·Nltrophenol lo i1ethyl pheno 1 Oichlorophenol ·Chloro-3-aethylphenol t6-T rich loropheno 1 Oinitrophenol tropheno 1 ,3,1,6-Tetrachlorophenol I thy H, Hin ltropheno 1 tachlorophenol (8040) ,ntach loropheno 1 (&Cl 11)) ug/L ug/l ug/L ug/l ug/l ug/L ug/l ug/l ug/L ug/l ug/L ug/L ug/l ug/L 1-·-·····-·--·-·----·-·······-·--···--·--·-I I I I I <1.00 0, 119 U 1.11 U 2, 81 IJ 2, 14 2 ,02 U <0.500 (1.00 <1.00 (1.00 < 1.00 <1.00 <1.00 <0.010 1.28 (1.00 <2.00 IR 3. 12 U KR 134 IR <2.00 IR 31.8 IR 2.88 lR <UO IR 13.I IR 36.2 u 16, 4 u 91. 0 u <UO u o, !11 --------------<1.00 <1.00 <I.Of 2.01 IJ Ui U 0.791 IJ 16.2 U 13.4 U 31. 8 U 1.46 U <0.100 3, 71 U <0.100 <0.500 <0.100 1.08 U 0,731 U 1.61 U <0, 100 (0, 100 <0.100 <1.00 (1.00 <1.00 <1.00 <1.00 <1.00 1.88 U (1.00 U3 U <1.80 <1.00 <1.00 ·<1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <0.010 0.010 IJ Q.101 --------- I I Tl SUKURY --LP om FOR SAMPLES COLLECTED l/10/90-l/l1/IO • R -RALEIGH • one Envircnmtal Job. I !90-0l.H iE 1 OF 3 I Suple lo. Fl lB 7/10/90 C-111-0SE C-118-0SE C-111-0SE DUP C-298-EA ·1----------------------------------------'.'.I0/10 ----------··········---------------------------------:I'.'.~--------------------------~'.'.~'. ____________________________________________________________________________________________ _ 'Alkalinity as CaCOJ 19/l NR 318 216 NR 438 le ride 19/l Ni ,,nate Alkalinity II CaCOJ 19/L IR bcnate Alkalinity as CaC03 19/L IR If ate 19/L II llved Calciu1 ug/L NR hed Pctmi11 ug/L NR 11Ghed la9nesiu1 u9/l IR lhed Scdiu1 u9/L IR ;ticpyl Ether ug/L <I.OD · 1 i~l 1.51 -morophelel u9/L 12.1 ·1rcphe1ol u9/L <0.500 litt~lphencl 19/l <D.500 t-Dlclllorcphenol u9/l 0.651 -,· oro-3-iethylphencl u9/L <0.500 -lrichlcrcphencl u9/l <1.00 -initrophencl ug/L <1.00 iitrcphenol ug/l 1.08 1,6-Tetrachlcrcphencl ug/L <1.00 hy1-4,l-dl1ltrophencl ug/l <1.00 ntachlcrcphencl (8044) ug/L <t.00 -,chlorophencl (6C515)) ug/L <0.010 . --------············-----------------------------I I I I I 799 0.000 398 10.1 113000 1110 113000 335000 (1.00 <1.00 HR 1.64 U NR <0.500 NR <D.500 NR <0. 500 NR <0.500 HR <0. 500 IR <1.00 NR <1.00 NR <1.00 IR <1.00 IR <1.00 IR 3.17 0.014 U ------------------------195 NR 10. 8 0.000 IR 0.000 m NR 41! uo IR <I.OD 11310 NR moo <1000 IR <5000 16300 NR 51700 18700 IR 91900 11.0 81.0 1800 <D.500 <0.500 <D.500 <0.500 <0.500 <0.500 <D.500 <D.500 <0.500 <D.500 <D.500 <0. 100 <0.500 <0. 500 <D.500 <0.500 <0.500 <D.500 <1.00 <1.00 4.11 <1.00 <I.GO <1.00 <I.OD <1.00 <1.00 <1.00 <I.DO 1.98 <t.00 < 1.00 1.!I 1.80 ti.I 511 11.0 J 19.IJ 1110 ----------------- I I -TA SIIPARY J'°P om FOR SAMPLES COLLECTED 7/10/10·7/11/90 : • RALHGH , one En1iromnt1I Job. I MIO·Ol.H -,l OF 3 I Suple No. !·HI !·9-CP TB 7/11/90 C·l1B-OSE OUP C·29B·EI •••••••••••• ·-· •••••••••••••••••••• T / 11 /90 1................ FB ----------------------------------------········----------------------------------------------------------------·······-------------------------------------------------------········-IUID Units A lk1linity IS CaCOl 11/l 175 169 NR lide 19/L 166 28, I NR · ute llkalinity as CaCOl 19/l 0.000 0.000 II bonate Alkalinity as CaCOJ 19/L m 161 AR ,Hate 19/L 6.30 UO IR lhed Calciua ug/l !1800 2!700 AR 101! Potmiu1 ug/L <1000 <1000 II ,110hed 119nuiu1 ug/L moo 10100 NR 'lied Sodiua ug/L mooo moo IR lopy 1 Ether ug/l 1 ug/l 1180 (1.00 <1.00 <1.00 UI U o.m u o.w u NR ·Ch1oropheno1 ug/l <UOO 0, 911 U <0.100 NR ltropheao 1 ug/l Olaethy1pheno1 ug/l <UOO <UDO <0.100 lR <0.100 <0.100 <0.100 lR .4·0lch1oropheno1 ug/l <UDO <UOO <UOO IR '1oro·3·iethylpheno1 ug/l 6·Trich1oropheno1 ug/L . Oinitropheno1 ug/L 2, 79 <UOO <0.100 II l, 11 <I.DO (1.00 IR <1.00 <1.00 <1.00 II ltropheno1 ug/L l,l·Tetr1chlorophe101 ug/l thyH,Hinltrophtool ug/l <1.00 <1.00 (1.00 u (1.00 <1.00 <1.00 II <1.00 <1.00 <1.00 II ,ntachloropheno1 (1044) 1g/l II.I <1.00 <1.00 • Ill 0.101 0.011 J lachloruphenol (6CIII)) ug/l ······················--··--------------------------------------------------------------------I I I I I I AWD Technologies, Inc. I I I I I I I I APPENDIX A I RESULTS AS REPORTED BY THE LABORATORY I I I I I I I I I ' * I I I I I I I I I I I I I -1 I I I ! I I ~~)'t\Q:1"; it: [,n, Si•r It~ Cu-; t i•e r lD Total AIHi1r,11.,-a;; C,CG3 Chlond4 Carbonm All'!l101 ty lS c.COJ 81.: 1rD0;,-l te i!-lh l in 4 t"t ~s C 1COj Sulfat, Dasi:.1lveo Cale.tu/fl t•1uc-J·,ec 1·,nsHuo Ci5sr,!vtJ ~1ijnes1~ J;asol·.ca Si'.'~l~ GC~IS ;-~r-t ~Cl"llJropli,?rtO l GC: i 5 S,J,;~OGI< Tf.~ Tr lbr ,:~-:-~ritr-c i •g.'l •g,'l ••~• l •9/L l1~/L u,!L U\j/L IJg_; i_ :J~ ' ..... --. -.. -. -.. ---........ -. 1:1-JWL•i~~:_1 ;._';-Ji.Jl·J,.1..;.(, 11.1-JUi. l~'.: 1•)-jUL·l9'10 :•£Ll 1: ·~~ 03N .:t~L C lb OS~ ,JhL c-~~ 8Sr~ !lit~ .. C·9b ~/I; ·--~·············-·-------------------- "'r:"" ;,.,.JI Jll i22 4(Jll oJ.6 b•.b ,J 1 (1(1<1 f;. ;))() ,),(1(!0 :::7 )14 222 1a., 4. ••'.• ~-~1; 1:)7(1(\: bJW.l ~(IU;) 56"\1 ; :,(1()1) < 'iu!JO ~-~l\'ll_l .iJ:,:,o 2~40i} "".-t.i:.r.:: t-e·,:.~: J4jl_i(t ; (,/:11: 1). (~.(. J ~1:; J,f, 8-,U;-l '1% ~-e:·, 3 ~Jnc. r L: Dia Su,~lc1 Cu:t(lacr iu Pulllictcrs ~191 : Sua..r'y oi ~r.a!·1t1..:1l k.esults DHt r1Et,,·ea: 11-JlJL·l·)'i:~: ·=·.JS1:oJllllc:-: Beazer -~1lc1gr1 Ji.le na.e: 11%-07 .~ 5aplcs -·····------------------------------------------]4-<)(,B 34-:))'1 j4-::;11 34-01 ~-;:i-JUL-;·'91) 1,)-J\;L-19',,i ; ;-JUL ·1990 : l · JUL-1991) WE,L C-?"C ~ Fi, C-;:A-OSE C-i;l,-OSE units ------------------------------------------------------------------------Totll Alnl !.fll ty as C 1COJ 1g;l l '15 ~ m 2511 chloriae igil 85.8 tf1 m l '15 Carbor1ate Aluliriity 1s ClCQj IQ/L 75.4 Nf< 0.000 o.oov 81caroor,;te Alk,l1r,1ty is CaC03 1g/l t20 NR J'18 256 Sul:,te lg/l 21.4 Ni; 10,b 4.90 01ssvlveo Calc1ua ug/l 5-400 NR ; 13000 :2300 D1ssoh·ea ~-c,ta;s11.a ug;L ml) Nf< ~120 ,_5000 O:i.ssvl·re:d fll1qr1esH.11 ug/L C::50(;0 r'1 1 ::iooo loJOO D1ssolveo So11<J1o Ug/L 9:;(JIJO NR 3350(.1() :87000 ~-1:'. P,m t 1cr1 i (, r -:-pnt:!'IO 1 Ug/l 1), !Ob (i), 1) IV <),014 lo.O Ge~ l:, SlJ:R\..1GA TES r r ior,::.0phi!1V l :r.ei::ovcrf i08 "1i.-? "'1.4 132 I I I I I I I I I I I I I I I I I f.c-,;t0n1: u.· Uau :,~~l~•J Cust~C" ::: :-cinl ;~~·;lir,lt'f Chlvrit:::t: 15 :: s.roc,r,-tti: hl,:si:t,j,\1 C 1CO~ as :: ;.C:Jj tnoroc,r,.rto:: ~lulm1ty lS C 3,:_jJ Sulr:;:c G1s;o1".-ac: C1!G:.m. Ui;si:-l,·t?o :-,;:•ti.551\JJI D1ss11hcc ~igrn:511.A [11;sC\i·•ca SVOliJli lll5l'S Picr1Hi:r: k-rJpne.r.vl GC~,IS S;JRRCiGAit; ir1or-:i1op:it?no! Jr,.i. ts I'll L •'ll L •'Ji L l'JI.L ifl9J" ~ ug/L Jg.,' i. ,g/L ;jg.tl U'J/ L ,RicoJvt?ry JA-,)lb j4-i)l 7 j4-<)l6 34-<j\ 9 34-0~) ll-JUL • l 1'10 l l-JUL ·!'19>> ll·J\JL·l'/90 ll-JUL-1991) ll-JUL-!9'1\i C-11&-,JSE Du=· C·:'9B-EA 111-4-EA ~-9-Ci• FB ~ n,; 6~ lb9 tfi 'fi ,.;.a ibo 28. l Nil Ne. i;.C,.)J v.vw o. (){Ji; "' NR 438 075 1b9 'fl NI, :.1 -•~(1 ,.3') l.llf; If< '1K 422,)0 =~avv =~i(iJ ~ rlf-;_5'~W ,:,vw <~® ,.. ti,: s:-:oo !J",,00 10100 ~ ~ 9']<,,'/; --.-.. ,.:,1,.11,J,,1 '52<.JOO ~ 19,b 1190 1 ?9 l).~-oti 0.012 136 ll!atri:-: Int. "•trix Int. "•tru Int. ,J!, I I I I I I I I I I I I I I I I ~.i?·,;t,)r1C iU [Lltt! S1,1plca Cost.:.,r ID i.JnltS .)4-,,v~ j-4-,:,:..1 :;4-,:,f; j.1-,,,:.o j.\-,ft)] ),1-:))6 l•;·JUL·ioqO l')-JuL-:991) 10·:UL-10% 10·J\Jl·l9'10 IO·JUL·l99<l i•)-JlJL-190<) NELL ,:-:A J:5N ~Ecc C·lB 05/; ~ELL C-::E 05N WELL ,:-9A OSI, •hl C-% ilSII WELL C-'IC [,S,, ------------------------------------------------------------------------------------------------------------------------------- 802(, I sopropy I Etner ug/L < i .Oc) 1.:-a \i.00 (1,(1\) (1.00 '1.00 BO~ ~TES Benzotr1iluor1de • Rccu1it?ry 87.J 9~.J 86.4 105 10-4 96.3 • 804-0 enenol ug/L 0.779 G.00 tfl ~-01 I. 3-4 0.7'15 2-Cnloropnenol ug/L , '" 3. 1: ti< 16.2 13,-4 35.8 , • '.J :-Ni:rvpnenol ug/L :.EA l J-4 rt< 1.% ,0.500 J.71 2,4-[•aetnylpnenol Ug/l :. 14 :,~ ,(11j ff; (0.500 <.0.500 <O.~ i, 4·D1c:-1lor,Jpr,er.ol ug;L :,ij: J'5.a If'< ~ ,;}8 o. 731 1.61 A-Ct1 iorv-3-aethy lpricnvl Ug/l ;';j. Sv(.1 :.BB ~ .0.500 :.0. S,j,,) <:O.SW :, 410-Tr 1ct1lorvpn12rivl 'J~/l :1.W •.4. ((• I.fl ,1.00 ,1.00 '.I.;)) :, 4-Uir11 trvphenol ug,: L ,.1.W 13,5 ti, :.1. I)) :..1. O(• :.1 • i:(1 4·N1tr0pnenol 1Jg/L , t .VI) 3o.: ~ 1.88 <1.00 4 <" • :;,J : 1 j ,.:-10-T e.t r iCi,lor"pner10 l Ulj/L :.1 .. ,:; lo.4 rfi < 1 ,,)0 q J,<j , l ,oj(, 1-.'!t!ttiy l -410-dm1 t ~vpnenc-: ''lji L ,1.00 i'8. 0 If'< ' I. ()I) ,.1.00 LOO 17ier,t ~cnl,:iropnei,,.:il IJg.,' l ;_: 'v,.; '4 .,,:, ~. ,1.0,:, ;:!/,i,,1 '.l.w 804-0 Sl.liRCG,;1ES i-F luoropr,enol • Reco,.ry l S, l .\i.6 ~ ~.B 34.;) :,J.9 • i,4,o-iriori:wiupnenol l ;.eco,·uy ib.'i 32.4 ~ oi; , ., 45.·1 r:,t ., ' .. I I I I I I I I I I I I I I I I ~.,:y;tvr-~ iL jc-rc SilP~•Hl ~.!-,:~ 11> :UL· l 991) " 34-011) j4-1J1 l ,:)-JUL -1991) l!·Jll·,9"0 r& C • 1 IA·OSE 3.\-1)1 ~ 3.\·0lo )4-,:,17 l,-;IJL-19'1\1 ll·JUL-19'11) ll·Jll·19"v C · l :B-OSE C·llB·OSt l)J:• C·.2%-EA --------------------------------------------------------· ---------------------------------------------------------------------- 1(::,:; [si:pr•:•p·ri Ernt:r •Jgil il,00 :.1,00 :J.00 9. ,, ,.v 84.0 280<) ai;2.:, j;,_~h~~TE5 B~riz,:;rr it li.i..:ir ,ac . 1'.cc .. her)" 93,9 9o,3 97,j 113 103 1,): • 3:,4(, ~·t-1iJIV 1 J(j/ l ~.56 If; Lb4 :_:). 500 .0.500 ,:o.5w 2-Cr:~vr0pr10:r,0i =Jg.,· L ' -• Nii :,0.500 ,:). ~00 :0.500 <O.~ !.,;., .. :-~it r opr,1:rn:i 1 IJgil ,_v. ';l:,j ""' ,o. 5(•) 1.0.5(:4) :\),500 \0,500 i, •-:::1::-:ny lpn~r1cl ug.-l ;_:). ':li; Nii : I;. ~N ;1),500 \0,500 ,0.:.00 :, 4-L:~i:ri li:•"-:•p1"lH,ol ug/L 1).oS: Nfi :0,-:.\lt) :.0.500 ,o.s.:io ,o.soo 4 ·Sr:l0re+· 3 ·•ctn.,-~pncr,ul ug;L ,0. SJO rt< :0,5(.,) {0. 500 :_0.500 <O.SW i, .t 1 ;-Tr 1cnlvr0pr;cr,vl ug;L :J.00 r-1< ~ 1. t}V •.1.00 <.1.00 4. 77 : ,-'· ~; ~.r,1 trupncr1vl ug/L ~ ~ .00 Nfi :_i,00 ,_1.00 <.1.00 :. 1, 1i(: 4-N,tr,,pnenol 1Jg/L 1.08 r-1< ,1.00 '· 1. :)(I :1.00 ; 1. (K) .i, 3, ~ ,b· T etr .;,,:tiloropner,ol ug, l <1.00 tf< ,1.00 \l.00 \l,00 7.% ;:-~.,ny 1-4 ,b-a1r,1 t ropner,ol U(j/ l ,1.00 tfl ;J.00 ;1 .00 <1.00 i.28 ~-er,t 1criluropncnol ug;L <.1.00 tf< 3.67 9.00 13. 9 591 004<) m \AJA TES i-F !wrvphinol z Recovery 47.o tfl :.8.8 ;:7.8 43. 1 27.4 :, 41b-T r ibrc.avpru!nol l ~ecovary .ta. 7 N.<: ~.b 40.4 48.9 4., .. •• J I I I I I I I I I I I I . r-.ef:t,:,rit II: Date ;ap~l!O CustJ11cr lL av:,:, lsopri)jlyl Etner 8020 SIJ1,.ffiATES B,nzotr1iluor1de 8(,40 Ph1?r;u1 2-Cnlorophenoi 2-Nitropnenol 2, 4·01.1ctny !phenol 214·L1chloropn,nol 4-Chloro-j-a,tnylpnenol :,4,b·Tr1chlvropheriol 2,4-Dinitrophenoi 4·NHropnenol 2, 315,b· Tetracnloropnenoi 2-llletrty l ·4,b-dir,1 tropner,ul ~,nncniorophenol 8040 ~TES 2-f hioropn.nol 2,4,0-iribroauphenvl ·, UgJ-. ~ Recc.-,er,- ugil •Jg/l ug/l ug/t ug/l ug/L ug;L ug/~ ug/L U!j; l lJQ..iL Ug/L • ~eco¥ery • ~ Recuviry -~-:.~3 ; i -]\.,\. -j 't)"l) 1:.so 100 .:.~ ,:o.sw .1;, 51)) •.DI '300 .0.5(.:1) .i. 79 ~·.12 l.(•) '.l.W ,.1.00 ,1.0<l ·f9.2 J7.4 45.1 }4-,_11 ~ 11-JUL·l..:•~) A-;-C~ . l,i)) 89,;) 0. ;5ti c. 911 «).~ •.◊. 5'XJ ,0.500 -J;. 5(10 =.1.1)() '1.v<i \l.00 ~.1. ;:.(i •.LOO ;I.(;<) ' ' blJ,, 43.o ]-4-i;.:,:: u -;t.;v:m '" il,;JV iOO 0.b47 \0.500 <0.500 (~•.soo <.0.500 ,o.sw <1.00 ;J,(10 d.00 ,1.00 ;J,1),) \l.00 33. 1 '""' , ,:,1 Job r,,ae: l!'ltl-07.J.4 3-!-021 11 · J\Jl · l 99<) TB ; l.(N) 114 If< NI'( ~ ~ 111 ti< 111 ~ tfl Hf< 111 tl< NI'( NI'( I I I I I I I I I I I I I I I I I m m AWD Technologies, Inc. APPENDIX B SUPPORT DOCUMENTATION I I I I I I I I I I I I •• I I I ~-•=--r·;t~nt? rn Dia iu1~le1 Cu::tOIICr rn Toti! Al,;imn7 15 CaC03 Chlur 1de C«rbon.te Alul1r,ity 15 CaC03 B1caroor,;te Alkahr,1 ty 15 CaC03 Sultite 015sulvea C,lciua D1ssol'lea f·cta;s1ua Dlssul"-;ed ll!agnesl!.11 01ssolvea SuOllJI ~l~ Pentlcn 1,:, r,:.prieno 1 GC~l5 S!Jif<t.~TES Tr 1oroaopf14?r1ol 191l •gil •9/ L •g/l 19/ l ugil ug,'L ug;L Ulj/ l ug;L ~l\ecovery r:J-JUL·i?90 I•)-JUL-lQ91) ,,-;\;L·199<l :l·JUL-19'lll WE,L :-?~ OSN ,& C · 1 :a-OSE C-1 ,&-OSE 195 tf< 398 2511 85.8 tf< 79'1 19S 7'5.4 Nf( 0.000 0.000 :iV tf; J'18 25b 21.4 Nf( lU,b 4.90 ~ Nf( :13000 moo 999(; If; 512" ('SOC,Q ,.~,) tfl i 13000 lbllO '1:XM! Nf( 335()(.(i :87000 ,). 106 (1),1)10 0.014 lb,O 108 '1.i.9 -iq .4 E) I I I I I I I I I I I I I I I I I ~ c-;:~ont:: a Date :;in,ple-~ :-onl !;jy;l1r,lt'i Cnlur 1,:;e lS CarbOi,iti: ,., ... : ... ._ ,.,.,, -S.1..;.11.1. ._, CiCO~ as C.sCQj B1nrw,,r1ate ~i•.;lrn1ty as C,wJ Sulh\c ~1s;vl"~·o:?:d C1li:1:.a D 1ss.:-l t"i?.O :-~tHSll.8 D1ssv!'t•ec: ~i.Wr€SH.a [1i;soi·y·ca SJ!Jli.6 G.:51~ c·,erit 1i:rJu·0pner,ol GC':,1 S S;JRR~-:-ts Tr 10 r v11vpt1cnv l Jnlts 1g/i.. •91L tg/l tg/L itig/ ~ ug/l Ugil U(jil •,'lfl ug;L ~Recvvcry n-JUL-1990 11-JUL·l~(; C-11B·OSE DI;'.· C•i'i&•E, ~ na Of; .,;,a Ni, :j.f#J ~ 438 Nii ;_ l .lJ(J "" 4i2tl0 tii <~ 11( ~2700 ~: nw,;, 19.o 1190 6 "•tr1x Int. j4·(Jl6 ll·JUL·l990 ~-4-EA b 7'S loo (J. (J(fJ 075 o.3'i =~800 <5(,(,(J !350<) : "7;:jjJ,.J l~ fllatr1x rrit. Joe ,, .. ,: 11%-07.34 34-(,19 ll·JUL·l99tl "·9-Ci• lb9 ~8.1 o.w:, !bl l.8<; :::7()j <':,(,Qj 10100 52000 1),506 "•tr1x lnt. 34-0:)j ll·JUL·l'm FB I I I I I I I I I I I I I I I I I I k_,ry;tor,~ lli jc-;:: 511pl-::,:J ~..i-({~ l 1)-;liL · l 991) ,& 34-01,) ]4-,)11 IO-JUL·J9'/ll ll·JUL-199<) To C·llA·QSE 34-('1 S ]4-1)10 )4-,:,: 7 1:-;UL · !99(: ll·JUL·:9'11) ll·lUL·i'l'<tl C·11B-05E c·ll&·OSi [).J• C ·::<:-EA ---------------------·--------------------------------------------------------------------------------------------------------- a.;~-(1 lsopropyi t tl'ler ug;l 1.00 ,.1.00 :.1.00 9l .O 84.0 280<) ai)ZiJ SJfi.'hOGATE5 Bi:!r1..:ut r 1 f luvr 11l1:. ' l\ecv·.,ery 93.9 9b.3 97,j 113 103 10:' • 3114() ~ Ph•nol ag;L ~ l.o4 ,.:),:<XI 0.500 (0.500 2-Crilorupncr,c.l :191· L . 4 Nii \0,5(.(l ;JJ,50(; ,.o.soo (0,500 :-N1tropr1t:r1vl ug;l <O.Sii<i "' (0. 'jl)O i0.500 ,o.soo (0.500 2, 4-~1111-:::ny lpn.::r,vl ug.. L ~ tf( ;i), '1,">) :1),500 (0.500 (1), 500 . 2,4-D1c"l0r~p"inol •Jlj/L ' NR <V.~) <0.500 ,o.soo (0.500 L 4-Cril,:iri.:i-j-ee.tn'i lpiierrol ug;L ;_(;. 5-)0 ~ '0. SQ,) <-0.~ ,.o.soo (0.500 :, 4, ,:,-Tr 1cnlvr,:ipt1c.r1vl ugil '.1.00 If; ::1 Ji(} •1.00 '.l.00 4.77 : 14-D 1r,1 t ropncr,vi Jg_,\ ~ ~ d.00 <.1.00 :.1.w ,.1.w . 4-Nitr-:,pnenol •Jgil 08 ~ :1.00 ,:i. ;)() : :.oo q ,i)) 2,3, 516· i etnchloropner,ol ug; L <!.00 ~ ;!,00 \l.00 <!.00 7 ,96 2-~e,hy l ·4 16-oir,1 tropner,ol ug;L ( 1,0,) tfl '1.00 <.1.00 q .oo :.;a ~·er,t ici1lorupneriol ug/l 11.00 ~ 3.67 9,8(1 13. 9 591 ao40 StN<i,illHES i·F luvruphenol % Recovery 47,b tfl 58.8 27.8 43.1 27.4 2, 4 ,b· Tr ibr011opr,enol l Recovery 48.7 ff( 75,b 4-0. 4 48.9 42,3 I I I I I I I I I I I I I I I I I i: cr;t,)r11: :;:: Date 3i1plcc ::us;:.J11cr l~ 802(, !sopropyl Etner 00:10 m1x;1ms Benzotr1tluoride 8040 Ph1?r;o1 2-Chlorophenol 2-Ni tropnenol 2,4-Dil.tnylphenol ;',4-Dichloropn.nol 4-Chloro· 3-oetny Jpnenol 2141b·Tr1chlu,opnenol 2,4-Dinitrvphenol 4-Nitropnenol 2131516-Tetracnloropnenol .":·"ethy 1-4,b-dir,i tropner,ol eentacnloropnenol 8040 ~TES :-F luoropn,nol 2,4,b-irioroaopnenvl ug./~ ~ Rec-:•~·er7· ugjl ug/L ug/L 1~L ug/L ug;, ug;L ug/L ug,L ug/L ug,·L Ug/L : ~ecovery ~ Kecovcry :~-::~3 ~-::1.; ii· JL,L ·: i',·1) : : • Ji.JL • l ~'11; ~-4•~-,ll-:.i:;• 1:w ' .. oo !OU 89.0 i.~ t), i~ .:o.".iJiJ C. 911 ;_1;. 5')) ,.o.ouu .:t). :.(.() •C.5<XI •.O.Si;<) ,o.m i.79 '.IJ, 500 i. 12 '. l ,(~) 'I. (I) ,1.w :.1 .~a.) ,.1.00 ;_l,O(i ,1,,x, ,:i ,1)0 ,.1.00 ·19.: \ I. (.,j 37.4 bl), i 45.1 43.o :4-:;)) li ·JlJL-l9'f(; •B •.1.00 108 @ . .:o.500 ,0.500 <0.500 ,0.500 <1.00 \l.00 ,1.00 ,1.00 d.OV ,l.w 33.1 17. 7 :-l-(1?1 :1-TuL • 1991) TB ,1.,;,) 114 lfl tf< rfl rfl lfl If< lfl !fl lfl If< lfl !fl If< If< I I I I I I I I I I I I u I I D ~-c·ys:-:-~-e :!: 3111p~i.i,~ ;,)li1t -:w::-:.;e i[1 8;);:1i lsopropyl tther 80:1) SU-i<OGATE5 Benzvtr 1 f h1or 1ue 804D Pher..il ?-C~l~ropherioi i·tHtropne.nol 2,4 •I:111etilylpne:nc,l : , 4 -i), :ii lur vpl'lenu l 4-Cr:.1.•Jro-j-1111:thy lpilen01 ::, 4, o-r r 1cr. luroprnmol ~, 4-L11r,1 tropnenol 4-~itropnenol :: 13, :, ,b-T etr 1cr,loropnenvl : -~nhy i -4 16-oir11 tru~neri.Ji ~·er, ucnlu r vptJeno i o,)4,:, Sl.lfij;1J6A TES ~-; luurophcr,ol 2,4,b-;r ioroaopnenul ug/L ;J,,:,; : ~e.cc;•crt r•F ug/l ~ Ug/l ':). 5(11) ug/l (0) ug/L :_:..:. ':,((; ugil ;1). 7))1; ug/L :_(;,50(; ug/L :.i ,!)) ug/L :.1.(1.J ug;L :.l ,00 u~·L ·. ~ .(,0 ug,,L .l,00 ug/L ;_l ,:XJ ~ ~eco1i·ery 74.0 :.: Reco·'l"er'i 74.7 :],:. __ .~ i.;;~ :UNTt\"'JL Salll'LE ~3.: i 101 f-ec. 77.0 : ~.ec. 7b.b l Rec. rfi If: If< s:.e-;: f-ec. rfi II< a':i.5. ,ec. NF; II< F•:)lj ~-~ c·l!A-ilSE -.S 93,? ~ Rec. 96.4 55.8 % Rec. 92.8 l Re.c. lfl rfi 3-1.J % Rec. ff< II< pfi 19,7: Rec, ,f< rfi 8i.6 ~ R-cc. b3,b l Rec. 7:.a 71 .o '/9,6 b8.l :~-)14 ~JC :-11A-OSt ~~: 'l<).0 % Rec, 94.5 81.2 % Rec. 94.7 % Rec. ~ rfi aJ.4 ~ Rec. ffi rf rfi 4o.8 : Rec. If. NF( 89,4 l Rec. 93.S 88.1 I I I I I I I I I I I I I n D D H I D PGH-90-TMJ-380 DATE TO FROM SUBJECT overview October 8, 1990 Mr. Robert S. Markwell Program Manager -Environmental Services Beazer Materials and Services, Inc. 436 Seventh Avenue Pittsburgh, Pennsylvania 15219 Thomas M. Jackman AWD Technologies, Inc. Dioxin/Furan Data Validation Triangle Laboratories Projects #15747 and #16100H AWD TECHNOLOGIES The set of samples of Triangle Laboratories Project# 15747 for Beazer (collected 5/09/90) contained 1 soil sample. The set of samples of Triangle Laboratories Project # 16100H for Beazer (collected 7/01/90) contained 3 soil samples. Two of the samples, X-48-30CP and 5-2 3-0SS were replacements of previous samples. Samples were analyzed for polychlorinated dibenzo-p-dioxins and dibenzofurans by high-resolution gas chromatography/high- resolution mass spectrometry. summary All elements were successfully analyzed in all samples with the exception of compounds with saturated peaks which required reanalysis. Areas of concern with respect to data usability are listed according to the seriousness of the problem. These include: Major Issues Peaks for 123678-HxCDD, 1234678-HpCDD, OCDD, 1234678-HpCDF, OCDF, Total HxCDD, Total HpCDD, Total PeCDF, Total HxCDF and Total HpCDF in sample X-48-CP (Work Order# 15747) were saturated. Positive results for these compounds are qualified "J", estimated and represent minimum values only. AWD Technologies. Inc. Penn Center West. Building Ill. Suite 400 Pitlsburgh Pennsylvania 15276 Telephone 412 788 2717 Telecopier 412 788 1316 I I I I I I I I I I I I I I I I I I AWD Technologies, Inc. PGH-90-TMJ-380 Mr. Robert S. Markwell Beazer Materials and Services October 8, 1990 -Page 2 Notes The TLI soil blank for Work Order #15747 contained 1234678-HpCDD, OCDD, 1234678-HpCDF, OCDF, Total PeCDD, Total HXCDD, Total HPCDD, Total HxCDF and HpCDF at concentrations less than 5% of sample results. No results were qualified on the basis of the blank contamination because sample concentrations were far greater than blank concentrations. According to the Case Narrative, sample S-23-0SS (Work Order #16100H) is the replacement sample for sample X-48-CP (Work Order #15747). The results for both samples were reported on the Data Summary because Sample X-48-CP contained results which were diluted out in the replacement sample. Also, Sample X-48-JOCP is a replacement sample of S-23-EA. Triangle Laboratories adopted a new procedure for calculating analyte specific detection limits. This procedure uses 2 representative noise height determinations which are summed and multiplied by an empirically determined factor before applying the detection limit equations. The effect of this approach is to increase the detection limits of the DB-5 column by a factor of 5 and that of the DB-225 column by 3.5. The laboratory states that the new procedure produces a more accurate estimate of detection limits. The laboratory performed the required 5 point initial calibrations but did not supply raw data and chromatograms for the individual calibrations. Checks of response factors and retention times could, therefore, not be performed. The data were reviewed according to Method 8290 (June 1987), an isotope-dilution high resolution mass spectrometric version of RCRA Method 8280 (SW846), Triangle Laboratories' Data User Manual and the National Functional Guidelines for Evaluating Organic Analyses. The text of this report addresses only those problems affecting usability. I I I I I I I I I I I I I I I I I I AWO Technologies, Inc. PGH-90-TMJ-380 Mr. Robert S. Markwell Beazer Materials and Services October 8, 1990 -Page 3 Information Regarding Report content Attachments: 1. 2 • 3. 4 • Glossary of data qualifier codes. Data Summary. This includes: a) All positive results with qualifier codes, if applicable; b) All unusable detection limits qualified with an ''R''; and c) All estimated detection limits qualified with UJ or UL. Appendix A results as reported by the laboratory (no corrections were made during data validation). Appendix B -Support Documentation includes details to support the statement in this report. I I I I I I I I I I I I I I I I g n AWD Technologies, Inc. GLOSSARY OF DATA QUALIFIER CODES (DIOXINS) CODES RELATING TO IDENTIFICATION (confidence concerning presence or absence of compounds) < = Not Detected. The associated number indicates approximate sample concentration necessary to be detected. (NO CODE) = Confirmed Identification R = Unreliable Result. Analyte may or may not be present in the sample. Supporting data necessary to confirm result. CODES RELATED TO OUANTITATION (can be used for positive results and sample quantitation limits): J = Analyte present. precise. Reported value may not be accurate or I AWO Technologies, Inc. I I I I I I I I I DATA SUMMARY FORMS I I n u D I I I I I I DATA SUMMARY So11 D1ox1n/Furan Results I DATA FOR WATER SAMPLES COLLECTED 5/11/1990 TRIANGLE LABORATORIES PROJECTS •15747 and 116100H I Project I 15747 ------------- I Sample No. X-48-CP I ' ' :COMPOUND UNITS EMPC I ' I 2378-TCDD ppt 175 12378-PeCDD ppt 1510 123478-HxCDD ppt 3260 I 123678-HxCDD ppt 10140 J 123789-HxCDD ppt 8660 1234678-HpCDD ppt 42190 J I OCDD ppt 88730 J 2378-TCDF ppt 163 12378-PeCDF ppt 537 I 23478-PeCDF ppt 440 123478-HxCDF ppt 3630 123678-HxCDF ppt 3510 I 234678-HxCDF ppt 3060 123789-HxCDF ppt 57.0 1234678-HpCDF ppt 16320 J I 1234789-HpCDF ppt 5520 OCDF ppt 55800 J TOTAL TCDD ppt 763 863 I TOTAL PECDD ppt 4440 TOTAL HxCDD ppt 41420 J ,TOTAL HpCDD ppt 71670 J I I I :TOTAL TCDF ppt 2200 2560 :TOTAL PECDF ppt 9420 J 16090 11 :TOTAL HxCDF ppt 13860 J 55110 :TOTAL HpCDF ppt 49760 J 53650 PERCENT MOISTURE Not Reported I EMPC = ESTIMATED MAXIMUM POSSIBLE CONCENTRATION H D D I I DATA S-Y S011 01ox1n/Furan Reault■ I DATA FOR WATER SAMPLES COLLECTED 5/11/1910 TRIANGLE LABORATORIES PROJECTS 115747 and 118100H I Project I 18100H =============---------= I -·· No. S-23-0SS X48-30CP S18B-EA Rerun of Rerun of' X-48-CP 9-23-EA I I :cacpooNo UNITS l!NPC EMPC EMPC :2378-TCDD ppb <0.01 <0.01 0.03 I : 12378-P.COD ppb 0.03 0.01 0.07 : 1234 78-HxCOD ppb 0.05 0.02 0.19 : 1231S 78-HxCOD ppb 0.28 0.1a 0.57 : 123789-HxCDO ppb o. 24 0.05 0.81 I : 1234878-HpCOO ppb 9.0 5.3 18.Z :ocoo ppb 71. 1 so.a 137 I :2378-TCOF ppb <0.008 (0.008 0.01 : 12378-PeCDF ppb <0.02 <0.02 0.02 :23478-PeCOF ppb <0.02 <0.02 0.01 I :123478-HxCOF ppb 0.05 0.02 0.10 :123078-HxCOF ppb 0.05 0.01 0.08 :234878-HxCOF ppb o.oa 0.04 0. 11 : 123789-HxCOF ppb <0.02 <0.02 <0. 01 I : 1234878-HpCOF ppb 1.2 0.89 2. 1 ! 1234789-HpCDF ppb 0.011 0.07 0.17 :ocoF ppb 5.2 7.7 8.8 I :TOTAL TCOO ppb 0.08 0.03 0.51 0.55 !TOTAL PECDD ppb 0.07 0.01 0.03 0.71 1.0 I :TOTAL HxCOO ppb 1. 7 0.48 0.52 4.8 5.0 :TOTAL HpCOO ppb 18.Z 8.4 30.5 :TOTAL TCDF ppb 0.02 <0.008 o.u o. 18 I :roTAL PECOF ppb 0.45 o.oe 0.93 :roTAL HxCDF ppb 1.8 1.2 3.4 3.5 :TOTAL HpCDF ppb a.a 4.1 a.a I PERCENT MOISTURE 11. 9 18.4 21.2 I I I I I AWO Technologies, Inc. I I I I I I I I I APPENDIX A RESULTS AS REPORTED BY THE LABORATORY I I I I I ,I I I I I I I I I I I I I .I I I • I I I I ' I ,~ I FILE NAME .... : CONCAL ....... : ANALYST ...... : SAMPLE SIZE .. : !CAL DATE .... : SPIKE FILE ... : S901879 S901874 HSK 8.43 9 06/11/90 SPX2372K TRIANGLE LABORATORIES, INC. PCDD/PCDF 2378X ANALYSIS (b) CLIENT ID ...• : KEYSTONE SAMPLE ID ...• : X-48-CP ANALYSIS DATE: 06/15/90 SAMPLE MATRIX:·SOIL SAMPLE ORIGIN: MORRISVIL Page 1 of 2 06/28/19 TLI NUMBER .... : 31-94-1 PROJECT NUMBER: DATE RECEIVED. : DATE COLLECTED: SHIPMENT NO ..• : 15747 05/11/90 I I 17928005 ---------------------------------------------------------------------------=== NAME CONC(ppt) NUMBER DL EMPC RATIO RT FLAGS ------------------------------------------------------------------------------2378-TCOD 175 0.78 31: 04 13.... 12378-PeCOD 1510 1. 55 36:28 123478-HxCOO 3260 1. 22 41: 16 123678-HxCOO 10140 1.08 41:25 _s 123789-HxCOD 8660 1. 22 41: 53 1234678-HpCOO 42190 1.00 46: 18 !...-S ocoo 88730 0.91 51: 46 .14~ 2378-TCOF 163 0.69 30: 17 12378-PeCOF 537 1.59 35:02 23478-PeCOF 440 1.58 36:0Q 123478-HxCOF 3630 1. 11 40:08 123678-HxCOF 3510 1. 12 40: 17 234678-HxCDF 3060 1. 12 41: 04 123789-HxCDF EMPC 57.0 1234678-HpCOF 16320 0.89 44:45 ..14.~ 1234789-HpCDF EMPC 5520 OCOF 55800 0.95 51: 57 ~s TOTAL TCOO 763 11 863 0.78 TOTAL PeCOO 4440 11 1.60 TOTAL HxCOO 41420 6 1. 18 ......s. TOTAL HpCOO 71670 2 1.00 .......i TOTAL TCOF 2200 12 2560 o. 70 TOTAL PeCDF 9420 11 16090 1.61 ~ TOTAL HxCDF 13860 7 55110 1. 11 ~ TOTAL HpCDF 49760 3 53650 0.91 .....s.. ------------------------------------------------------------------------------ X237_RPT rev:3.03 I I I I I I I I I I I I I. I I I I ' 1. • I I FILE NAME .... : CONCAL ....... : ANALYST ...... : SAMPLE SIZE .. : !CAL DATE .... : SPIKE FILE ... : T903493 T903488 VC 0.80 9 07/17/90 SPX23710 TRIANGLE LABORATORIES, INC. PCOO/PCOF 2378X ANALYSIS (b) CLIENT ID .... : SAMPLE ID .... : ANALYSIS DATE: SAMPLE MATRIX: SAMPLE ORIGIN: KEYSTONE S-16B-EA 08/07/90 SOIL RNC/BEAZE Page 1 of 2 08/20/90 TLI NUMBER .... : 34-29-3 PROJECT NUMBER: 16100H DATE RECEIVED.: 07/03/90 DATE COLLECTED: 07/03/90 SHIPMENT NO •.. : 17928005 ------------------------------------------------------------------------------NAME 2378-TCDD 12378-PeCDO 123478-HxCDD 123678-HxCOO 123789-HxCOO 1234678-HpCDD OCDD 2378-TCDF 12378-PeCDF 23478-PeCDF 123478-HxCDF 123678-HxCDF 234678-HxCDF 123789-HxCDF 1234678-HpCDF 1234789-HpCDF OCDF TOTAL TCDD TOTAL PeCDO TOTAL HxCDO TOTAL HpCOO TOTAL TCDF TOTAL PeCOF TOTAL HxCDF TOTAL HpCDf CONC(ppb) NUMBER EMPC 0.07 0. 19 0.57 0.61 18.2 137 EMPC 0.02 0.01 0. 10 0.08 o. 11 ND 2. 1 0.17 8.6 0.51 0.79 4.9 30.5 o. 13 0.93 3.4 8.8 5 4 6 2 2 7 8 3 DL 0.01 EMPC 0.03 0.01 0. 55 1.0 5.0 o. 18 3.5 ------------------------Cf RATIO RT 1.46 34:23 1.30 39:10 1.19 39: 19 1.29 39:46 1 .05 44:08 0.85 48:56 1.48 32:55 1.67 33:53 1.29 38:00 1.24 38:09 1. 40 38: 58 0.94 42:37 1.03 44:44 0.89 49:07 0.73 1.48 1.29 1.05 0.83 1.55 1.23 0.97 FLAGS X237_RPT rev:3.03 I I I I I I I I D D I I I I I I I I I FILE NAME .... : CONCAL ....... : ANALYST ...... : SAMPLE SIZE .. : ICAL DATE .... : SPIKE FILE ... : 1903492 1903488 vc 0.89 g 07/17/90 SPX23710 TRIANGLE LABORATORIES, INC. PCOO/PCOF 2378X ANALYSIS (b) CLIENT IO ...• : SAMPLE IO •... : ANALYSIS DATE: SAMPLE MATRIX: SAMPLE ORIGIN: KEYSTONE S-23-0SS 08/07/90 SOIL RNC/BEAZE Page 1 of 2 08/20/90 TLI NUMBER .... : 34-29-2 PROJECT NUMBER: 16100H DATE RECEIVED.: 07/03/90 DATE COLLECTED: 07/03/90 SHIPMENT NO ••• : 17928005 ------------------------------------------------------------------------------NAME 2378-TCOO 12378-PeCOO 123478-HxCOO 123678-HxCOO 123789-HxCOO 1234678-HpCOO ocoo 2378-TCOF 12378-PeCDF 23478-PeCOF 123478-HxCOF 123678-HxCOF 234678-HxCOF 123789-HxCDF 1234678-HpCOF 1234789-HpCOF OCOF TOTAL TCOO TOTAL PeCOD TOTAL HxCOO TOTAL HpCOO TOTAL TCOF TOTAL PeCOF TOTAL HxCOF TOTAL HpCOF CONC(ppb) NUMBER ND EMPC 0.05 0.28 0.24 9.0 71. 7 NO NO NO 0.05 0.05 0.06 NO 1. 2 0.08 5.2 0.08 0.07 , • 7 16.2 0.02 0,45 , • & 3.& 2 3 7 2 1 3 6 3 DL 0.01 0.008 0.02 0.02 0.02 EMPC 0.03 0.09 0.32 0.06 1.6 RATIO RT 1.08 39:10 1.19 39:19 1. 10 39: 46 1.01 44:08 0.86 48:55 1.07 37:59 1.28 38:09 1. 36 38: 58 0.90 42:37 1.11 44:43 0.94 49:07 0.73 1. 56 1.18 1 .04 0,76 1.62 1.18 0.97 FLAGS ----------------------------------CL<J X237_RPT rev:3.03 I I I I m I I D I I I I I I I I I I ' I .• I I FILE NAME .... : CONCAL ....... : ANALYST ...... : SAMPLE SIZE .. : ICAL DATE .... : SPIKE FILE. .. : T903491 T903488 vc 0.88 9 07/17/90 SPX23710 TRIANGLE LABORATORIES, INC. PCDD/PCOF 2378X ANALYSIS (b) CLIENT ID .... : SAMPLE ID .... : ANALYSIS DATE: SAMPLE MATRIX: SAMPLE ORIGIN: KEYSTONE X48-30CP 08/07/90 SOIL RNC/BEAZE Page I of 2 08/21/90 TLI NUMBER .... : 34-29-1 PROJECT NUMBER: 16100H DATE RECEIVED.: 07/03/90 DATE COLLECTED: 07/03/90 SHIPMENT NO ... : 17928005 ------------------------------------------------------------------------------NAME 2378-TCDD 12378-PeCDD 123478-HxCDD 123678-HxCDD 123789-HxCDD 1234678-HpCDD OCDD 2378-TCDF 12378-PeCDF 23478-PeCDF 123478-HxCDF 123678-HxCDF 234678-HxCDF 123789-HxCDF 1234678-HpCDF 1234789-HpCDF OCDF TOTAL TCDD TOTAL PeCDD TOTAL HxCDD TOTAL HpCDD TOTAL TCDF TOTAL PeCDF TOTAL HxCOF TOTAL HpCDF 9c CONC(ppb) NUMBER ND 0.01 EMPC 0. 16 0.05 5.3 50.6 ND ND ND 0.02 0.01 0.04 ND 0.89 0.07 7. 7 0.03 0.01 0.49 8.4 NO EMPC 1. 2 4,8 2 1 4 2 6 3 DL 0.01 0.008 0.02 0.02 0.02 0.008 EMPC 0.02 0.03 0.52 0.06 RATIO 1. 48 1.33 1. 42 1.04 0.84 1.08 1. 30 1. 28 0.98 0.96 0.92 0.86 1.48 1. 33 1, 04 1. 21 0,96 RT 34:23 39: 19 39:47 44:08 48:S6 38:00 38:09 38:58 42:37 44:45 49:07 FLAGS ----------------------------------------- 1:.11:!l'!li. X237_RPT rev:3,03 ) I I I I I I ft I I I I I I I I I I I I AWD Technologies, Inc. APPENDIX B SUPPORT DOCUMENTATION I I I I I B D u I I I I I I I I I I I Pt1C 1f?~? ---One soi 1 sample was received from KEYSTONE ENVIRONMENTAL RE- SOURCES in good condition May 11, 1990 and stored in a refrigera- tor at 4°C. The sample was extracted and analyzed according to procedures described in the Triangle labs User Manual provided with this data package. Any particular difficulties encountered during the sample handling by Triangle labs w, 11 be discussed in the QA/QC remark section below. Quality Assurance/Quality Control Samples A laboratory method blank --identified as the TLI Blank --is prepared along with the sample. QA/QC Remarks The release of this particular set of KEYSTONE ENVIRONMENTAL RESOURCES analytical data by Triangle Labs was authorized by the Quality Assurance Officer who has reviewed each sample data package individual 1y fol lowing a series of inspections/reviews conducted at two other levels of the data production line. When applicable, general deviations from acceptable QA/QC requirements are identified below. Comments on the effect of these devia- tions upon the validity and reliability of the results can be obtained from the User Manual ( Data Quality Objectives; Section 5). Specific QA/QC Problems Associated with this Particular Project are: Sample Preparation Laboratory: None Mass Spectrometry: None Data Review: This soi 1 sample has been scheduled for re-analysis due to the presence of saturated peaks. Enclosed is the initial analysis of this sample. Those isomers flagged ··s·· on the report represent minimum estimate (saturated). Two internal standards, HpCOF and OCDD, fall outside the ion abundance ratio criteria. This is due to contribution from their respective saturated analyte peaks. As the analytes are saturat- ed, they represent only a minimum estimate anyway. The TLI Blank contamination associated with this sample is well below 5.0:i& of that concentration present in the sample. This level of contamination is acceptable under TLI guidelines. Addendum to Section 4.6 of the Data User's Manual Effective December 15, 1989, Triangle Laboratories has adopted a new procedure for calculating the analyte specific detection limits. Under this new policy two representative noise height determinations are summed and multiplied by an empirically deter- mined factor before the detection limit equation given in Section 4.6 of the Data User's Manual is applied. The effect of this 2 I I I I I n D I I I I I I I I I I I I • 'i)cJC, ;;11r11/ -Three soil samples were received from KEYSTONE ENVIRONMENTAL RESOURCES, INC. in good condition July 03, 1990 and stored in a refrigerator at 4°C. The samples were extracted and analyzed according to procedures described in the Triangle Laba user Manual provided with this data package. Any particular difficul- ties encountered during the sample handling by Triangle Laba will be discussed in the QA/QC remark section below. Quality Assurance/Quality Control Samples A laboratory method blank --identified as the TLI Blank prepared along with the batch of samples. is QA/QC Remarks The release of this particular set of KEYSTONE ENVIRONMENTAL RESOURCES, INC. analytical data by Triangle Labs was authorized by the Quality Assurance Officer who has reviewed each sample data package individually following a series of inspections/reviews conducted at two other levels of the data production line. When applicable, general deviations from acceptable QA/QC requirements are identified below. Comments on the effect of these deviations upon the validity and reliability of the results can be obtained from the User Manual (Data Quality Objectives; Section 5). Specific QA/QC Problems Associated with this Particular Project are: Sample Preparation Laboratory: None Mass Spectrometry: None Data Review: Sample X-48-30CP 115747). Sample (Project t15722). is a replacement sample for S-23-EA S-23-0SS is a replacement sample for (Project X-48-CP OCDD was found in the TLI blank at a concentration not greater· than 5X of any sample concentrations. Blank contamination of this magnitude is acceptable under TLI guidelines, as discussed in section 5.1.3.2 of the Data User's Manual. In addition, the blank contains a very out-of-ratio peak that corresponds to 1234678-HpCDF Thie peak will have a negligible effect on the other samples. Addendum to Section 4.6 of the Data User's Manual Effective December 15, 1989, Triangle Laboratories has adopted a new procedure for calculating the analyte specific detection limits. Under this new policy two representative noise height determinations are eunvned and multiplied by an empirically deter- mined factor before the detection limit equation given in Section 4.6 of the Data User's Manual is applied. The effect of this procedure is to increase DB-225 analyses detection limits by a factor of 3.5, and DB-5 analyses detection limits by a factor of 2 ./ I I I I u R I I I I I I I I I I I PGH-90-TMJ-381 DATE TO FROM SUBJECT overview October 8, 1990 Mr. Robert S. Markwell Program Manager -Environmental Services Beazer Materials and Services, Inc. 436 Seventh Avenue Pittsburgh, Pennsylvania 15219 Thomas M. Jackman AWD Technologies, Inc. Dioxin/Furan Data Validation Triangle Laboratories Project #15932 AWD m:HNOLOGIES The set of samples of Triangle Laboratories Project# 15932 for Beazer (collected 6/06/90) contained 10 soil samples. No blanks were included in the data package. Samples were analyzed for polychlorinated dibenzo-p-dioxins and dibenzofurans by high- resolution gas chromatography/high-resolution mass spectrometry. summary All elements were successfully analyzed in all samples with the exception of those qualified as unreliable ''R''. Areas of concern with respect to data usability are listed according to the seriousness of the problem. These include: Major Issues Quantitative interferences were identified in the analyses of 123678-HxCDD, 123789-HxCDD, 234678-HxCDF, 123789-HxCDF, Total PeCDD, Total HxCDD, Total TCDF, Total PeCDF. Quantitative interferences may result in false negatives or estimated concentrations. Most of the affected samples were diluted and reanalyzed because of saturated peaks and the dilutions eliminated the interferences. Therefore, where possible, results for these compounds shown on the data summary are taken from the diluted analyses. In some instances results of the initial analyses were "diluted out" in the reanalyses and compounds detected in the initial run were not detected in the second. In such cases, the positive results of the first run are reported on the data summary and are qualified ''J'', estimated. AWD Technologies. Inc. Penn Center West. Building Ill, Suite 400 Pittsburgh Pennsylvania 15276 Telephone 412 788 2717 Telecopier 412 788 1316 I I I I H I I I I I I I I I I I I I AWD Technologies, Inc. PGH-90-TMJ-381 Mr. Robert S. Markwell Beazer Materials and Services October 8, 1990 -Page 2 OCDD and OCDF were detected in the TLI of 17. 2 and 2. 8 ppt, respectively. (EMPC) in Sample X-94 is qualified results are qualified because they levels detected in the blanks. Minor Issues soil blank at concentrations Therefore, the OCDD result "R", unre 1 iable. No other are substantially above the Matrix Spike (MS) and Matrix Spike Duplicate (MSD) recoveries for 234678-HxCDF were below quality control criteria. In addition, the MS/MSD relative percent differences for 234678-HxCDF, 123678-HxCDD and 123789-HxCDD exceeded criteria. These MS/MSD problems may be related to the quantitative interferences described above. Because of these problems, initial run results for these compounds are qualified ''J'', estimated and detection limits are qualified ''UJ", estimated. Notes The signal to noise ratios (S/N) for internal standards 13 c1 12 1234678-HpCDF and 13 Cl 12 -1234789-HpCDF were slightly below the required 10: 1 ratio in Sample X-50-FL (Dilution). Because the internal standard recoveries for these compounds meet quality control er i ter ia, sample resu 1 ts on the data summary are not qualified because of the low S/N. Triangle Laboratories adopted a new procedure for calculating analyte specific detection limits. This procedure uses 2 representative noise height determinations which are summed and multiplied by an empirically determined factor before applying the detection limit equations. The effect of this approach is to increase the detection limits of the DB-5 column by a factor of 5 and that of the DB-225 column by 3.5. The laboratory states that the new procedure produces a more accurate estimate of detection limits. The laboratory performed the required 5 point initial calibrations but did not supply raw data and chromatograms for the individual calibrations. Checks of response factors and retention times could, therefore, not be performed. The data were reviewed according to Method 8290 (June 1987), an isotope-dilution high resolution mass spectrometric version of RCRA Method 8280 (SW846), Triangle Laboratories' Data User Manual and the National Functional Guidelines for Evaluating Organic Analyses. The text of this report addresses only those problems affecting usability. r: I I I D I I I I I I I I I I I I I I I AWO Technologies, Inc. PGH-90-TMJ-381 Mr. Roberts. Markwell Beazer Materials and Services October 8, 1990 -Page 3 Information Regarding Report Content Attachments: 1. 2 • 3 • 4 • Glossary of data qualifier codes. Data Summary. This includes: a) All positive results with qualifier codes, if applicable; b) All unusable detection limits qualified with an ''R''; and c) All estimated detection limits qualified with UJ or UL. Appendix A results as reported by the laboratory (no corrections were made during data validation). Appendix B -Support Documentation includes details to support the statement in this report. j I I I I D I I I I I I I I I I I I I AWD Technologies, Inc. GLOSSARY OF DATA QUALIFIER CODES (DIOXINS) CODES RELATING TO IDENTIFICATION (confidence concerning presence or absence of compounds) < = Not Detected. The associated number indicates approximate sample concentration necessary to be detected. (NO CODE) = Confirmed Identification R = Unreliable Result. Analyte may or may not be present in the sample. Supporting data necessary to confirm result. CODES RELATED TO OUANTITATION (can be used for positive results and sample quantitation limits): J = Analyte present. precise. Reported value may not be accurate or UJ = Analyte not detected. Detection limits may be inaccurate or imprecise. I AWD Technologies, Inc. I I I I I I I g I DATA SUMMARY FORMS I D R I I E I I I I I DATA SUHMAllY SOIL OIOXIM/lrllllAN RISULTS I DIOXIN DATA roa WATIR SAKPLIS COLL!CTID 8/04/1990 TRIANCLI l.ABOI.ATORIIS PBOJICT 115932 I Sa.aple No, 00021001 S5-1-TP ss-2-TP X-10-TP 0-2" I :coMPOU'MD UlUTS EKPC IKPC EPIPC IPIPC I :2378-TCDD ppt 36.3 0,78 1.3 0.63 :12378-PeCDD ppt 127 4,9 6,8 1.8 I l123478-Hll:CDD ppt 117 • 8,1 21.7 3,3 :123678-Hs.COD ppt 201 • 57.1 • 77.1 • 17 ,9 J :123789-Hs.CDD ppt 994 • 19.5 J 80.2 • 9.0 J I :1234678-HpCDD ppt S370 • 1410 3270 588 :ocoo ppt 147610 • 13570 60930 8250 l2378-TCDP ppt <0.3 1.1 1.2 0.47 I :12378-PeCDP ppt <0.6 1.4 2,4 0,85 :23478-Peeor ppt <0,7 2.6 3.8 1.3 ll23478-HxCDP ppt <4,8 • 9.6 24,2 • 5,1 I :123678-HxCDP ppt <4,5 • 10,7 12,8 4.0 :234678-llxCDP ppt <6.8 ■ 25,4 J 9.5 J 30.7• 10.2 J ;123789-BxCOf ppt <8,9 • <0,4 0.38 J <0.2 I ;1234678-BpCOf ppt <8.3 • 301 • 389 • 113 : 1234789-HpCDF ppt <15.7 • 22.6 33.0 7.9 :ocor ppt <25,6 • 1380 • 2520 433 u :rotAL TCDO ppt 531 8.7 8.4 21.20 23,7 4,1 5.2 lTOTAL PICOO ppt 1290 • 1310• 17,5 J 20,4 46.50 J 48.0 4,4 16.5 :rotAJ. BxCDD ppt 4870 ■ 298 • 497 • 82,1 82.6 D lTOTAL HpCOD ppt 14070 • 2380 • 8440 • 1020 :rorAL rcur ppt <0,3 11.7 12,8 18,30 17,1 5,3 8,0 D :TOTAL PICDP ppt <0,7 85.8 J 88.8 75.9 • 27.8 29,5 :rotAL BxCDr ppt cs.a• 70,4 • 562• 588• 157 :rotAL BpCDf ppt <10,8 ■ 1090 1500 • 397 I PIBCINT NOISTUU 1.25 18.2 18.8 11,7 D IKPC = BSTIMATID IUJ:IKUK POSSIBLI COIICINTIIATIOII • BIBULTS ROPI OILUTID Al!ALYSIB R I I I I DATA SU1'91AB.T SOIL DIOXIN/l'URAII USULTI I DIOXIN DATA roe WATER SAMPLIS COLLICTID 6/04/1990 TBIAJICLI LABOBATOKIIS PBOJICT U5932 I Saaple No, X-10-TP X-10-TP l-49-CP X-50-CP 4-6" 8-10" (Initial) I I ;CONPOU)fD UJUTS IMPC EKPC IMPC IKPC :2378-TCDD Pin <0.5 <0,S 226 o. 59 :12378-PeCDD ppt 0.44 <0.6 2220 4,2 I : 123478-HKCDD ppt 0,92 <0.3 15,6 • :123678-HxCDD ppt 2,9 J <0.2 UJ 227 • :123789-HxCDD ppt 1, 7 J <0,3 UJ 47.3 • I :1234678-HpCDD ppt 155 5.7 9040 • :ocoo ppt 13380 • 522 50790 • I :2378-TCDF ppt <0,3 <0.3 207 0,60 :12378-PeCDF ppt <0,5 <0.6 333 2,0 :23478-Pecor ppt <0,6 <0,7 452 3,8 :123478-BKCDF ppt 0.44 (0.3 41.9 • n :123678-BxCDP ppt 0.37 <0.3 23,3 • l234678-BxCDP ppt 1.5 J 1.2 43.3 • :123789-H:111:CDP ppt <0.3 <0,5 <12.0 • u Jl234678-HpCDP ppt 10.8 17.0• <0,3 1820 ■ : 1234789-HpCDF ppt 1. 2 <0,5 <19.7 • :ocor ppt 53.4 58.4• 3,3 4320 • D :TOTAL TCDD ppt <0.5 <0,5 620 622 1.6 14,6 :TOTAL PICDD ppt 1.2 J 1.9 <0.6 4820 J 10,6 11.6 lTOTAL Hi:CDD ppt 13,0 J 14, 3 <0,3 747 • I !TOTAL BpCDD ppt 281 315• 12,8 14860 • ITOTAL TCDF ppt <0,1 <0,S 1090 1100 8,6 J 9,1 I :TOTAL PICDP ppt 1.0 <0.6 7180 J 7950 123 128• :TOTAL RxCDr ppt 11,4 J 12.4 1.1 2170 • :roTAL BpCDr ppt 43.7 48.6• 1.4 6680 • D PERCENT "°lSTUIIB 16,Z 10.2 15.t E EKPC • ISTIMATBD MAllllllll POSSIBLE CONCBNTBATIOJI • RISIILTS rBOII DILUTID AJIALTSIB I I I I I DATA SmtKAJlY SOIL DIOXIN/"1ll.lll USULTS I DIOXIN DATA roe WATIB SAKPLIS COLLICTID 6/04/1190 TRIANGLE LABORATORIIS PBOJICT 115932 I Sample No. X-94 X-1-0-SN I 1 11 :cOKPOUMD UNITS l!IIPC aU'C :2378-TCDD ppt <0.8 <0.4 :12378-PeCDD ppt <1.2 1.6 I :123478-HxCDD ppt <0.6 3, l :123678-lll<CDD ppt <0.6 UJ 9,1 J :123789-HitCDD ppt <0.7 OJ 8.3 J I :1234678-BpCDD ppt 4.1 293 :ocoo ppt 31.2 a: 8600 I :2378-TCDF ppt <0.6 0,61 :12378-PeCDP ppt <!.l <0,6 :23478-PeCDF ppt <1.3 <0,7 : 123478-Rl<CDP ppt (0,5 I, 9 I :123678-HxCDF ppt <0,5 1,6 :234678-HxCDr ppt 2,2 4,5 :123789-HlCCDP ppt <0.9 <0.6 I :1234678-BpCDP ppt <0,5 39,0 :1234789-HpCDP ppt <1.0 2,3 :ocor ppt <2. 1 121 I :roTAL TCDD ppt <0.9 2,9 :TOTAL PICDD ppt <1.2 14.4 :rorAL Rl<CDD ppt 5,0 73,4 g lTOTAL HpCDD ppt 4,1 558 :tOTil TCDP ppt <0,6 2,1 3,1 n :rorn PICDP ppt <!.2 T,1 9.1 :TOTAL llxCDP ppt z.o 46,4 ITOTAL BpCDP ppt 2,T 115 H PDCINT IIOISTUB.I 6.9 14,3 I D I I I AWO Technologies, Inc. I I I I I I I I I APPENDIX A RESULTS AS REPORTED BY THE LABORATORY I I I I 'I I I I I I I I I TRIANGLE LABORATORIES, INC. Page 1 of 2 PCOO/PCOF 2378X ANALYSIS (b) 09/15/90 I FILE NAME •••• : S902348 CLIENT IO •••• : KEYSTONE TLI NUMBER •••• : 33-11-4 CONCAL (VER).: S902344 SAMPLE IO •••• : X-10-TP (8-10") I PROJECT NUMBER: 15932 !CAL DATE •••• : 06/11/90 ANALYST •••••• : VC ANALYSIS DATE: 07/30/90 SAMPLE SIZE •• : 9.440 g SAMPLE MATRIX: SOIL SAMPLE ORIGIN: BEAZER RI I DATE RECEIVED.: 06/06/90 DATE COLLECTED: 06/06/90 SPIKE FILE ••• : SPX2372K SHIPMENT NO ••• : 17928005 ------------------------------------------------------------------------------------------------------------------------------------------------------------NAME CONC(ppt) NUMBER DL EMPC RATIO RT FLAGS I 2378-TCOO NO 0.5 12378-PeCOO NO 0.8 I 123478-HxCOO ND 0.3 123878-HxCOO ND 0.2 123789-HxCDD NO 0.3 1234678-HpCOO 5.7 1.08 47:11 I OCDO 522 0.87 52:47 ....ll. 2378-TCOF ND 0.3 I 12378-PeCOF ND 0.8 23478-PeCDF ND 0.7 123478-HxCOF ND 0.3 123878-HxCDF ND 0.3 I 234678-HxCDF 1.2 1.28 41 :54 ..I?... 123789-HxCOF ND o.s 1234678-HpCDF NO 0.3 I 1234789-HpCOF ND 0.6 OCDF 3.3 1.00 53:02 ...n. TOTAL TCDO ND 0.6 I TOTAL PeCOD ND 0.8 TOTAL HxCDD ND 0.3 TOTAL HpCOO 12.8 2 1.09 I TOTAL TCOF ND 0.3 TOTAL PeCDF ND 0.8 I TOTAL HxCOF 1.1 1 1.28 TOTAL HpCOF EMPC 1.4 7V .1.1!2.IJE.: X237_RPT rev:3.03 I I I I I I I I I I I I I I I I I I I .I I I I; FILE NAME ••.• : S902349 CONCAL (VER).: S902344 PROJECT NUMBER: 15932 ANALYST ••••.• : KF· SAMPLE SIZE •• : 8.730 9 DATE RECEIVED.: 06/06/90 SPIKE FILE ••• : SPX2372K TRIANGLE LABORATORIES, INC. PCOO/PCDF 2378X ANALYSIS (b) CLIENT ID •••• : KEYSTONE SAMPLE ID •••• : X-49-CP ICAL DATE .••• : 06/27/90 ANALYSIS DATE: 07/30/90 SAMPLE MATRIX: SOIL DATE COLLECTED: 06/06/90 Page 1 of 2 09/12/90 TLI HIMBER •••• : 33-11-7 SAMPLE ORIGIN: BEAZER RI SHIPMENT NO ••• : 179280-5 ==================================================-=========================-- NAME CONC(ppt) NUMBER DL EMPC RATIO RT. FLAGS 2378-TCDD 226 0.79 31:51 12378-PeCDD 2220 1.59 37: 17 2378-TCDF 207 0.76 31:04 12378-PeCDF 333 1.60 35:49 23478-PeCDF 452 1. 59 36:48 TOTAL TCOO 620 12 622 0.78 TOTAL PeCDD 4820 12 1.63 ~ TOTAL TCDF 1090 15 1100 o. 76 TOTAL PeCDF 7930 10 -7950 1 .56 ~q 7V LJ gJ !! : X237_RPT rev:3.03 -' .·-"' -. ·- .• :_"'f,,·:--.. ~ ..... ~' ·---~-;f• . .., ·:.,,.,.: .. /. I I I I I I I I I I I I I I I I I ,, I TRIANGLE LABORATORIES, INC. Page 1 of 2 PCOO/PCOF 2378X ANALYSIS (b) 09/15/90 FILE NAME ••.. : T903644 CLIENT IO .•.• : KEYSTONE TLI NUMBER .•.• : 33-11-3 CONCAL (VER).: 1903639 SAMPLE ID •••. : X-10-TP (4-6") diluted PROJECT NUMBER: 15932 ICAL DATE •••• : 07/17/90 ANALYST ...•.• : JA ANALYSIS DATE: 08/18/90 SAMPLE SIZE .• : 9.140 g SAMPLE MATRIX: SOIL SAMPLE ORIGIN: BEAZER RI DATE RECEIVED.: 06/06/90 DATE COLLECTED: 06/06/90 SPIKE FILE ••. : SPX2372K SHIPMENT NO ••• : 17928005 =============----==============================--============================= NAME CONC(ppt) NUMBER DL EMPC RATIO RT FLAGS ----- 2378-TCOO NO 11.2 12378-PeCOO NO 9. 1 123478-HxCOO NO 13.2 123678-HxCOO NO 12.3 123789-HxCOO NO 15.9 1234678-HpCOO EMPC 149 ocoo 13380 0.84 54:09 _a. 2378-TCOF NO 7.3 12378-PeCOF NO 8.4 23478-PeCOF NO 9.5 123478-HxCOF ND 1.6 123678-HxCOF NO 1.0 234678-HxCOF NO 10.6 123789-HxCOF NO 13.9 1234678-HpCOF EMPC 17 .0 1234789-HpCOF NO 20.1 OCOF EMPC 58.4 .JL TOTAL TCOO NO 11.2 TOTAL PeCOO NO 9. 1 TOTAL HxCOO ND 13.7 TOTAL HpCOO 1811 1 315 0.94 TOTAL TCOF ND 7.3 TOTAL PeCOF ND 8.9 TOTAL HxCOF NO 9.1 TOTAL HpCOF EMPC 48.8 I,,,, LJ0to: X237_RPT rev:3.03 ' I I I I TRIANGLE LABORATORIES, INC. Page 1 of 2 PCDD/PCDF 2378X ANALYSIS (b) 09/15/90 I FILE NAME •••• : S902345 CLIENT ID •••• : KEYSTONE TLI NUMBER •••• : 33-11-3 CONCAL (VER).: S902344 SAMPLE ID •••• : X-10-TP (4-8") I PROJECT NUMBER: 15932 ICAL DATE •••• : 06/27/90 ANALYST •••••• : VC ANALYSIS DATE: 07/30/90 SAMPLE SIZE .. : 9.140 g SAMPLE MATRIX: SOIL SAMPLE ORIGIN: BEAZER RI I DATE RECEIVED.: 06/06/90 DATE COLLECTED: 06/06/90 SPIKE FILE ••• : SPX2372K SHIPMENT NO ••• : 179280-5 ======================================================-=-==----------========= NAME CONC(ppt) NUMBER DL EMPC RATIO RT FLAGS I 2378-TCDD ND 0.5 12378-PeCDD EMPC 0.44 I 123478-HxCDD 0.92 1.37 42:08 123678-HxCDD 2.9 1.29 42:13 ..i,_ 123789-HxCDD 1. 7 1.29 42:42 ,._ Q I 1234678-HpCDD 155 1.02 47: 10 OCDD 14250 0.91 52:48 ~ 2378-TCDF ND 0.3 I 12378-PeCDF ND 0.5 23478-PeCDF ND 0.6 123478-HxCDF 0,44 1.25 40:56 I 123678-HxCDF 0.37 1.20 41:07 234878-HxCDF 1. 5 1.05 41:54 ..JL 123789-HxCDF ND 0.3 1234878-HpCDF 10.8 0.93 45:33 I 1234789-HpCDF 1.2 0.99 47:53 OCOF 53.4 0.90 53:03 .JL. I TOTAL TCDO ND 0.5 TOTAL PeCDD 1.2 2 1. 9 1.52 .lL TOTAL HxCDO 13.0 5 14.3 1.31 ..!... TOTAL HpCOO 281 2 1.03 I TOTAL TCOF NO 0.3 TOTAL PeCOF EMPC 1.0 I TOTAL HxCOF 11.4 5, 12.4 1.14 Ji.. TOTAL HpCOF 43.7 3 -0.98 .,.,, liaJ'i-0: X237_RPT rev:3.03 I I I I .. . . --·~·-:a-·:.-~-·--•·-•••~ I I I I I I I I I I I I I I I I I I I TRIANGLE LABORATORIES, INC. PCOO/PCOF 2378X ANALYSIS (b) Page 1 of 2 09/15/90 FILE NAME •••• : S902341 CONCAL (VER).: S902330 PROJECT NUMBER: 15932 ANALYST •••••• : VC CLIENT 10 ••.• : KEYSTONE TLI NUMBER •.•• : 33-11-2 SAMPLE 10 •.•• : X-10-TP (0-2") ICAL DATE •••• : 06/11/90 ANALYSIS DATE: 07/29/90 SAMPLE SIZE •. : 8.910 g DATE RECEIVED.: 08/06/90 SPIKE FILE ••. : SPX2372K SAMPLE MATRIX: SOIL SAMPLE ORIGIN: BEAZER RI DATE COLLECTED: 08/06/90 SHIPMENT NO ••• : 17928005 ===============================------=======-=-=============================== NAME CONC(ppt) NUMBER DL EMPC RATIO RT FLAGS --------------------------------------------------- 2378-TCDD EMPC 0.83 12378-PeCDD 1. 9 1.38 37: 19 123478-HxCOO 3.3 1. 29 42:08 123678-HxCOO 17.9 1.21 42: 15 123789-HxCOO 9.0 1. 21 42:43 ..f!.. 1234678-HpCOO 589 1.03 47:10 ocoo 8250 0.88 52:48 i\ 2378-TCOF 0.47 0.70 31:05 12378-PeCOF 0.85 1.41 35:52 23478-PeCOF 1.3 1.47 38:48 . 123478-HxCOF 5.1 1.18 40:58 123678-HxCOF 4.0 1.19 41:07 234878-HxCOF 10.2 1.17 41:54 .f!...~ 123789-HxCOF NO 0.2 1234878-HpCOF 113 0.98 45:34 1234789-HpCOF 7.9 0.91 47:53 OCOF 433 0.90 53:03 ..a. TOTAL TCOO 4.1 2 5.2 0.82 TOTAL PeCOO 4., 5 18.5 1.53 TOTAL HxCOO 82.1 7 82.8 1 .24 TOTAL HpCOO 1020 2 1.03 TOTAL TCOF 5.3 8 8.0 o. 77 TOTAL PeCDF 27.8 7 29.5 1. 51 TOTAL HxCOF 157 a 1.17 TOTAL HpCOF 397 3 0.9' ---------------L!!. !.J £!.I!!!.: X237_RPT rev:3.03 I I I I I I I I I I I I I , I I I I I I I TRIANGLE LABORATORIES, INC. PCOO/PCOF 2378X ANALYSIS (b) Page 1 of 2 08/29/90 FILE NAME .... : S902796 CONCAL (VER).: S902790 PROJECT NUMBER: 15932 CLIENT IO .... : KEYSTONE )TLI NUMBER •... : SAMPLE IO •... : SS-2-TP(OI~ ICAL DATE •.•• : 08/04/90 33-11-6 ANALYST ...... : VC SAMPLE SIZE .. : 8.850 g DATE RECEIVED,: 06/06/90 SPIKE FILE •.• : SPX2372K ANALYSIS DATE: 08/24/90 SAMPLE MATRIX: SOIL DATE COLLECTED: 06/06/90 SAMPLE ORIGIN: BEAZER RI SHIPMENT NO ••• : 17928005 -------------------------------------------------------======================= NAME CONC(ppt) NUMBER DL EMPC RATIO RT FLAGS ------------------------------------------------------------------------------2378-TCOO NO 6.0 12378-PeCOO NO 10.4 123478-HxCOO EMPC 31. 1 123678-HxCOO 77.9 1. 23 41:29 123789-HxCOO 80.2 1.28 . 41: 57 1234678-HpCOO 3270 1.04 46:21 ocoo 60930 0.86 51: 44 Jr 2378-TCOF ND 5.6 12378-PeCOF NO 8.0 23478-PeCDF ND 8.7 123478-HxCDF 24,2 1. 39 40: 11 12 36 7 8-HxCDF 12,8 1. 38 40:22 234678-HxCDF EMPC 30.7 123789-HxCOF ND 20.2 1234678-HpCDF 389 0.99 44:48 1234789-HpCDF 33.0 0.97 47:02 OCDF 2520 1.00 51: 58 I TOTAL TCOD EMPC 14.6 TOTAL PeCDD EMPC 17. 0. TOTAL HxCDD 497 4 557 1.29 TOTAL HpCDD 6440 2 1.05 TOTAL TCDF EMPC 8.4 TOTAL PeCOF 75.t 3 1. 51 TOTAL HxCOF 512 5 589 1.27 TOTAL HpCDF 1500 3 0.97 :oo· ~-----------------------------------------------..!/MY. X237_RPT rev:3,03 J I I I I I I I I I I I I I I I I I I I FILE NAME .•.. : S902348 CONCAL (VER).: S902344 PROJECT NUMBER: 15932 ANALYST ••.... : OM SAMPLE SIZE .. : 8.850 9 DATE RECEIVED.: 06/06/90 SPIKE FILE •.. : SPX2372K TRIANGLE LABORATORIES, INC. PCOO/PCOF 2378X ANALYSIS (b) CLIENT IO .... : KEYSTONE SAMPLE ID ..•• : SS-2-TP !CAL DATE .... : 06/27/90 ANALYSIS DATE: 07/30/90 SAMPLE MATRIX: SOIL DATE COLLECTED: 06/06/90 Page 1 of 2 09/12/90 TLI NUMBER .... : 33-11-6 SAMPLE ORIGIN: BEAZER RI SHIPMENT NO .•. : 179280-5 ------------------------------------------------------------------------------NAME CONC(ppt) NUMBER 2378-TCOO EMPC 12378-PeCOO 6.6 123478-HxCOO 21.7 123678-HxCOO 67.9 123789-HxCOO 25.8 1234678-HpCOO 3190 ocoo 40070 2378-TCOF 1. 2 12378-PeCOF 2.4 23478-PeCOF 3.8 123478-HxCOF 20.0 123678-HxCDF 11. 4 234678-HxCOF 9.5 123789-HxCOF 0.36 1234678-HpCOF 334 1234789-HpCDF 27.7 OCDF 1620 TOTAL TCOO 21. 2 7 TOTAL PeCDO 46.5 10 TOTAL HxCOO 401 10 TOTAL HpCDO 6150 2 TOTAL TCOF 16.3 7 TOTAL PeCOF 55.3 10 TOTAL HxCOF 445 14 TOTAL HpCOF 1320 3 DL EMPC 1.3 23.7 48.0 17. 1 55.5 RATIO 1.54 1. 07 1.24 1. 22 1.04 0.92 0.73 1. 62 1. 51 1.22 1. 14 1. 19 1. 13 0.97 0.94 0.92 0.79 1.55 1.21 1.05 0.76 1.54 1.18 0.96 RT 37:25 42:20 42:28 42:53 47:13 52:49 31 : 11 35:56 36: 56 41:10 41:20 42:05 43:12 45:40 47:55 53:05 FLAGS ...Q.. ....Q,. ~ ...Q.. ~ ....G. ----------------------------------------nl .!J!l..lH.: X237_RPT rev:3.03 I I I I I I I I I I I I I I I I ' I- I FILE NAME .... : S902795 CONCAL (VER).: S902790 PROJECT NUMBER: 15932 ANALYST ....•. : VC SAMPLE SIZE .• : 8.850 g DATE RECEIVED.: 06/06/90 SPIKE FILE ..• : SPX2372K TRIANGLE LABORATORIES, INC. PCDD/PCDF 2378X ANALYSIS (b) Page 1 of 2 09/06/90 CLIENT ID .... : KEYSTONE TL! NUMBER ...• : 33-11-5 SAMPLE ID •••• : SS-1-TPLC>•L\ !CAL OATE .... : 08/04/90 ANALYSIS DATE: 08/23/90 SAMPLE MATRIX: SOIL SAMPLE ORIGIN: BEAZER RI DATE COLLECTED: 06/06/90 SHIPMENT NO ..• : 17928005 ---=---------------=====~===------------------------------------------------== NAME CONC(ppt) NUMBER 2378-TCDD NO 12378-PeCOO NO 123478-HxCOO NO 123678-HxCOO 57.1 123789-HxCOO NO 12346 78-HpCOO 1330 ocoo 13570 2378-TCOF NO 12378-PeCOF NO 23478-PeCOF NO 123478-HxCOF NO 123678-HxCOF NO 234678-HxCOF NO 123789-HxCOF NO 1234678-HpCOF 301 1234789-HpCOF NO OCOF 1380 TOTAL TCOD ND TOTAL PeCDO ND TOTAL HxCDO 298 3 TOTAL HpCDD 2320 2 TOTAL TCDF ND TOTAL PeCDF NO TOTAL HxCOF 70.4 1 TOTAL HpCDF 1030 2 dl J...J i.J&t. DL EMPC 12.7 18.9 43.7 50.1 10.6 16.8 18.4 25.4 21.8 32.4 44.7 56.8 12.7 18.9 10.6 17 .6 RATIO RT 1.26 41:29 0.98 46:21 0.83 51:44 1. 01 44: 48 0.86 51:58 1.29 0.97 1. 07 0.98 FLAGS "IL ....l.. X237_RPT rev:3.03 l I I I I I I I I I I I I I I I I I I I FILE NAME .... : S902347 CONCAL (VER).: S902344 PROJECT NUMBER: 15932 ANALYST ...... : OM SAMPLE SIZE .. : 8.850 9 DATE RECEIVED.: 06/06/90 SPIKE FILE ... : SPX2372K TRIANGLE LABORATORIES, INC. PCOD/PCDF 2378X ANALYSIS (b) CLIENT IO ...• : KEYSTONE SAMPLE IO .... : SS-1-TP ICAL DATE ..•• : 06/27/90 ANALYSIS DATE: 07/30/90 SAMPLE MATRIX: SOIL DATE COLLECTED: 06/06/90 Page 1 of 2 09/12/90 TLI NUMBER .... : 33-11-5 SAMPLE ORIGIN: BEAZER RI SHIPMENT NO ..• : 179280-5 =-----======-----======------------------------------------------====--------- NAME CONC(ppt) NUMBER DL EMPC RATIO RT FLAGS ------------------------------------------------------------------------ 2378-TCDD 12378-PeCDD 123478-HxCDD 123678-HxCDD 123789-HxCDD 1234678-HpCDD OCDD 2378-TCDF 12378-PeCDF 23478-PeCDF 123478-HxCDF 123678-HxCDF 234678-HxCDF 123789-HxCDF 1234678-HpCDF 1234789-HpCOF OCDF EMPC 4.9 6. 1 45.1 19.5 1410 13010 1. 1 1.4 2.6 9.8 10.7 25.4 ND 298 22.8 1130 TOTAL TCOO 8,1 TOTAL PeCDIJ .c:. 1r-'1t• TOT AL HxCOO ....... _ 15 -~ TOT AL HpCOO £ 2280 '. ·t:· ~ '""'' . -· ~ TOTAL TCOF -At:. 1f;l·· TOTAL PeCOF 81.8 TOTAL HxCDF 332 TOTAL HpCOF 1090 2 7 8 2 8 7 9 3 0.4 0.78 8.4 20.4 183 12.8 68.9 333 1.49 1.28 1.24 1. 31 1.04 0.91 o. 77 1. 41 1. 52 1. 19 1.09 1. 17 •o. 93 1 .09 0.89 0.80 1.57 1.28 1.04 o. 79 1.50 1. 18 1.00 37: 17 42:05 42:13 42:42 47:09 52:47 31 :04 35:49 36:47 40:58 41:05 41:53 45:33 47:51 53:02 ..L ....Q. :5 ·" .J1.. --------------· -------------------------------------- .1.J .!.ll 1!!.l X237_RPT rav:3.03 ) I I I I I I I I I I I I I • I I I I I I FILE NAME .... : S90236\ CONCAL (VEA).: S9023« PROJECT NUMBER: 15932 ANALYST •..•.. : SB SAMPLE SIZE .. : 9.950 g DATE RECEIVED.: 06/06/90 SPIKE FILE .•• : SPX2372K TRIANGLE LAIIORATORIES, INC, PCDO/PCOf 2378X ANALYSIS (b) CLIENT IO ••.. : KEYSTONE SAMPLE IO ••.. : 00021001 ICAL DATE .... : 06/27/90 ANALYSIS DATE: 07/30/90 SAMPLE MATRIX: SOIL DATE COLLECTED: 06/08/90 Pa911 of 2 Ot/12/90 TLI NUMBER .... : 33-11-10 SAMPLE ORIGIN: BEAZER RI SHIPMENT NO ••• : 179280-5 ===============-=======-=========-====-==-====================-============--- NAME COHC(ppt) NUMBER Dl EMPC RATIO RT FLAGS ---------------------------------- 2378-TCOO 38.3 12378-PeCDD 127 2378-TCDF ND 12378-PeCOF ND 23478-PeCDF ND TOTAL TCDD 531 TOTAL PeCDD 1040 TOTAL TCDF ND TOTAL PeCDF NO ------rv li!:11 'ill 13 11 0.3 o.8 0.7 0.3 o. 7 0.80 31:51 1.57 37:17 0.80 1.81 ·---------------------·---X237_RPT niv:3.03 I I I I I I I I I I I I I I I ~ I I I I I TRIANGLE LABORATORIES, INC. PCOO/PCOF 2378X ANALYSIS (b) Page 1 of 2 08/29/90 FILE NAME .... : T90365' CONCAL (VER).: T903651 PROJECT NUMBER: 15932 CLIENT IO .... : KEYSTONE TLI NUMBER .... : 33-11-10 SAMPLE ID .... : 00021001 Lo•l) ANALYST ...... : MCO !CAL DATE •... : 07/17/90 ANALYSIS DATE: 08/19/90 SAMPLE SIZE .. : 9.950 9 DATE RECEIVED.: 06/06/90 SPIKE FILE ... : SPX2372K SAMPLE MATRIX: SOIL SAMPLE ORIGIN: BEAZER RI DATE COLLECTED: 06/06/90 SHIPMENT NO •.. : 17928005 ============---===--------------------------------------====================== NAME CONC(ppt) NUMBER DL EMPC RATIO RT FLAGS ------------------------------------------------------------------------------2378-TCDD EMPC 36.6 1237B-PeCOD 99.3 1. 36 38:02 123478-HxCDD 117 1. 25 42:5, 123678-HxCDD 201 1.09 43:02 123789-HxCDD 994 1.2, 43:31 1234678-HpCDD 5370 1.00 48:06 OCDD 147610 0.88 5,:o3 I 2378-TCDF ND 3.5 12378-PeCDF ND 5.2 23478-PeCDF ND 5.9 123478-HxCDF ND 4.8 123678-HxCDF ND 4.5 234678-HxCDF ND 6.8 123789-HxCDF ND 8.9 1234678-HpCDF ND 8.3 1234789-HpCDF ND 15.7 OCDF ND 25. 6 TOTAL TCDD 65' 9 743 0.79 TOTAL PeCDD 1290 9 1310 1. 57 TOTAL HxCDO '870 7 1. 21 TOTAL HpCDD 14070 2 1.01 TOTAL TCDF ND 3.5 TOTAL PeCDF ,. ·-5.5 TOTAL HxCDF ,:J;_,· ... 5.8 TOTAL HpCOF·-.0 .. •~.r-10.8 ~--------------------------ii~: X237_RPT rev:3.03 I I I I I I I I I I I I 11 I I I I I I I FILE NAME .•.. : S902358 CONCAL (VER).: S902354 PROJECT NUMBER: 15932 ANALYST .••••• : SB SAMPLE SIZE .• : 9.800 9 DATE RECEIVED.: 08/06/90 SPIKE FILE ••• : SPX2372K TRIANGLE LABORATORIES, INC. PCDO/PCOF 2378X ANALYSIS (b) CLIENT IO ••.• : KEYSTONE SAMPLE IO •••• : X-50-FL ICAL DATE •••• : 06/27/90 ANALYSIS DATE: 07/30/90 SAMPLE MATRIX: SOIL DATE COLLECTED: 08/08/90 Page 1 of 2 09/12/90 TLI HUMBER .••• : 33-11-9 SAMPLE ORIGIN: BEAZER RI SHIPMENT NO ••• : 179280-5 ======================-===========-===============-==-================-·====== NAME CONC(ppt) HUMBER DL EMPC RATIO RT FLAGS ----------------------------------------------------------2378-TCOO EMPC 12378-PeCOO 4.2 2378-TCOF 0.60 12378-PeCOF 2.0 23478-PeCOF 3.8 TOTAL TCDO 1. 8 TOTAL PeCDO 10.8 TOTAL TCOF 8.8 TOTAL PeCOF 123 2 7 7 8 0.59 14.8 11.8 9.1 123 ---------------------------------· !.I~!!:', ,. --• 1.63 0.89 1.38 1.85 0.72 1.60 0.75 1.56 37: 19 31 :08 35:52 36:50 X237_RPT rev:3.03 I I I I I I I I I I I I I I I I I I I I FILE NAME .... : S903020 CONCAL (VER).: S903014 PROJECT NUMBER: 15932 ANALYST ...... : GG SAMPLE SIZE .. : 9.800 g DATE RECEIVED.: 06/06/90 SPIKE FILE •.. : SPX2372K TRIANGLE LABORATORIES, INC. PCOO/PCOF 2378X ANALYSIS (b) Page 1 of 2 09/11/90 CLIENT ID .... : KEYSTONE TLI NUMBER .... : 33-11-9 SAMPLE IO .... : X-50-FL L011..) ICAL DATE .... : 08/04/90 ANALYSIS DATE: 09/07/90 SAMPLE MATRIX: SOIL SAMPLE ORIGIN: BEAZER RI DATE COLLECTED: 06/06/90 SHIPMENT NO ... : 17928005 ------------------------------------------------------------------------------NAME CONC(ppt) NUMBER DL EMPC RATIO RT FLAGS ------------------------------------------------------------------------------2378-TCOO ND 7.6 12378-PeCOO NO 6.8 123478-HxCOO 15.6 1. 36 40:40 123678-HxCOO 227 1. 28 40:48 123789-HxCOO 47.3 1. 34 41:16 1234678-HpCDD 9040 1. 03 45:37 OCDO 50790 0.86 50:45 :B. 2378-TCOF NO 6. 1 12378-PeCOF NO 6.7 23478-PeCOF NO 6.7 123478-HxCOF 41. 9 1. 10 39:31 123678-HxCOF 23.3 1.06 39:40 234678-HxCDF 43.3 1. 23 40:28 123789-HxCOF NO 12. 0 1234678-HpCOF 1820 0.93 44:05 1234789-HpCOF NO 19.7 OCOF 4320 0.93 50:59 TOTAL TCOO NO 7.6 TOTAL PeCOO NO 6.8 TOTAL HxCDD 747 6 1. 26 TOTAL HpCDD 14860 2 1.04 TOTAL TCDF ND 6. 1 TOTAL PeCDF 98.4 1 128 1. 37 TOTAL HxCDF 2170 7 1.13 TOTAL HpCDF 6680 2 0.91 ------------------------------------------------------------------------Cf' _j/.!.!./.!t>: X237_RPT rev:3.03 J • I I I I I I I I I I I I I I I I I I FILE NAME .... : CONCAL ....... : ANALYST ...... : SAMPLE SIZE .. : ICAL DATE .... : SPIKE FILE ... : NAME 2378-TCDD 12378-PeCDD 123478-HxCDD 123678-HxCDD 123789-HxCDD 1234678-HpCDD OCDD 2378-TCDF 12378-PeCDF 23478-PeCOF 123478-HxCOF 123678-HxCOF 234678-HxCDF 123789-HxCDF 1234678-HpCDF 1234789-HpCOF OCDF TOTAL TCOO TOTAL PeCDO TOTAL HxCOD TOTAL HpCDD S902340 S902330 vc 8.94 g 06/11/90 SPX2372K TRIANGLE LABORATORIES, INC. PCDD/PCDF 2378X ANALYSIS (b) CLIENT ID .... : KEYSTONE SAMPLE IO .... : X-1-0-SN ANALYSIS DATE: 07/29/90 SAMPLE MATRIX: SOIL SAMPLE ORIGIN: BEAZER RI CONC(ppt) NUMBER DL 0.4 EMPC ND 1. 6 3. 1 9. 1 8.3 293 8600 0.61 ND NO 1. 9 1. 6 4.5 ND 39.0 2.3 121 EMPC 12.2 73.4 558 5 6 2 0.6 0.7 0.6 2.9 14.4 Page 1 of 2 08/21/90 TL I NUMBER .... : 33-11-1 PROJECT NUMBER: 15932 OAT E RECEIVED. : 06/06/90 DATE COLLECTED: 06/06/90 SHIPMENT NO ... : 17928005 RATIO RT FLAGS 1. 52 37: 17 1. 12 42:05 1. 40 42:13 1. 34 42:42 1. 01 47:09 0.87 52:46 0.66 31:04 1. 09 40:57 1. 12 41:05 1. 22 41:53 0.98 45:33 1.04 47:51 0.94 53:02 1.60 1.25 1.03 TOTAL TCDF 2.1 3 3.6 0.72 TOT AL PeCOF 7. 1 2 9. 1 1. 44 TOTAL HxCOF 46.4 6 1.14 _il. ~OTAL ~ -----C.....v~---3 ________________________ 0.97_~;;;=~~~-;~:~~; I I I I I I I I I I I I I I I I I I I FILE NAME .... : CONCAL ....... : ANALYST ...... : SAMPLE SIZE .. : ICAL DATE .... : SPIKE FILE ... : NAME 2378-TCDD 12378-PeCDD 123478-HxCDD 123678-HxCDD 123789-HxCDD 1234678-HpCDD DCDD 2378-TCDF 12378-PeCDF 23478-PeCDF 123478-HxCDF 123678-HxCDF 234678-HxCDF 123789-HxCDF 1234678-HpCDF 1234789-HpCDF OCDF TOTAL TCDD TOTAL PeCDD TOTAL HxCDD TOTAL HpCDO TOTAL TCDF TOTAL PeCOF TOTAL HxCOF TOTAL HpCOF TRIANGLE LABORATORIES, INC. PCDD/PCDF 2378X ANALYSIS (b) S902605 S902600 HSK 0.99 g 08/04/90 SPX23710 CLIENT IO .... : SAMPLE IO ...• : ANALYSIS DATE: SAMPLE MATRIX: SAMPLE ORIGIN: KEYSTONE X-49-CP 08/13/90 SOIL n/a CONC(ppb) NUMBER DL EMPC 0.05 EMPC 0. 41 0.95 3.7 2.3 80.7 566 0.06 0.08 0.09 0.73 0.30 0.25 ND 10.7 1. 0 81. 1 0.02 0.85 14.3 122 0.33 1. 6 16.1 50.7 1 5 6 2 1 6 9 3 0.04 0. 11 1. 1 14.4 0.37 1. 9 16.2 Page 1 of 2 08/19/90 TU NUMBER .... : 3-11-7 PROJECT NUMBER: 15932R DATE RECEIVED.: 06/06/90 DATE COLLECTED: 06/06/90 SHIPMENT NO ... : 179280-5 RATIO 1.52 1. 24 1. 22 1.17 1. 03 0.87 0.67 1. 44 1. 61 1. 18 1. 12 1. 36 0.94 1.08 0.91 0.72 1.56 1.23 1.03 0.69 1.49 1.16 0.98 RT 36:48 41: 36 41:44 42: 12 46:37 52:05 30:34 35:20 36: 19 40:27 40:36 41:23 45:03 47: 18 52: 19 FLAGS ::::a ------------------------------------------· : 42 !:..;~~ X237_RPT'rev:3.03 l I I I I I I I I I I I I I I I I I I 11 I FILE NAME .... : CONCAL ....... : ANALYST ...... : SAMPLE SIZE .. : !CAL DATE .... : SPIKE FILE ... : S902350 S902344 HSK 9. 77 g 06/11/90 SPX2372K TRIANGLE LABORATORIES, INC. PCDD/PCDF 2378X ANALYSIS (b) CLIENT ID •... : SAMPLE ID .•.• : ANALYSIS DATE: SAMPLE MATRIX: SAMPLE ORIGIN: KEYSTONE X-94 07/30/90 SOIL BEAZER RI Page 1 of 2 08/20/90 TL! NUMBER .... : 33-11-8 PROJECT NUMBER: 15932 DATE RECEIVED.: 06/06/90 DATE COLLECTED: 06/06/90 SHIPMENT NO ... : 17928005 ------------------------------------------------------------------------------NAME CONC(ppt) NUMBER DL EMPC RATIO RT FLAGS ------------------------------------------------------------------------------ 2378-TCDD 12378-PeCDD 123478-HxCDD 123678-HxCDD 123789-HxCDD 1234678-HpCDD OCDD 2378-TCDF 12378-PeCDF 23478-PeCDF 123478-HxCDF 123678-HxCDF 234678-HxCDF 123789-HxCOF 1234678-HpCOF 1234789-HpCDF OCDF TOTAL TCDO TOTAL PeCDD TOTAL HxCDD TOTAL HpCDD TOTAL TCOF TOTAL PeCOF TOTAL HxCOF TOTAL HpCOF ND ND ND ND ND 4. 1 EMPC ND ND ND ND ND EMPC ND ND ND ND 0.9 1.2 0.6 0.6 0. 7 0.6 1 • 1 1. 3 0.5 0.5 0.9 0. 5 1. 0 2. 1 NO 0.9 NO 1.2 31.2 2.2 EMPC 5.0 1.00 47:10 4.1 1 1.00 NO 0.6 NO 1.2 .a_ EMPC 2.0 U.. 2.7 1 0.97 .--------=..;:.~~------------------------------------------- ' I:},\"'\ ::i/~O: X237_RPT rev:3.03 ) I I I I I I I I I I I I I I I I I I II AWD Technologies, Inc. APPENDIX B SUPPORT DOCUMENTATION I I I I I I I I I I I I I I I I I I I FILE NAME. ... : S220801 CON CAL ....... : S902205 ANALYST., .... : VC SAMPLE SIZE..: 10.00 g !CAL DATE .... : 06/11/90 SPIKE FILE ... : SPX2372K TRIANGLE LABORATORIES, INC. PCOO/PCOF 2378X ANALYSIS (b) CLIENT IO .... : KEYSTONE SAMPLE IO .... : TLI BLANK ANALYSIS DATE: 07/14/90 SAMPLE MATRIX: n/a SAMPLE ORIGIN: n/a Page 1 of 2 08/20/90 TLI NUMBER .... : n/a PROJECT NUMBER: 15932 DA TE RECEIVED. : I I DATE COLLECTED: I I SHIPMENT NO ... : n/a ------------------------------------------------------------------------------NAME CONC(ppt) NUMBER DL EMPC RATIO RT FLAGS ------------------------------------------------------------------------------2378-TCDO NO 0.5 12378-PeCOO NO 0.4 123478-HxCDD NO 0.4 123678-HxCDD NO 0.3 123789-HxCDO ND 0.4 1234678-HpCOO NO 0.4 ocoo ~ 0.76 50:52 2378-TCOF NO 0.4 12378-PeCOF ND 0.3 23478-PeCOF ND 0.4 123478-HxCDF NO 0.3 123678-HxCOF NO 0.2 234678-HxCOF NO 0.4 123789-HxCOF ND 0.5 1234678-HpCOF NO 0.3 1234789-HpCOF ~ 0.5 OCDF 0.94 51:07 TOTAL TCOO ND 0.5 TOTAL PeCDD ND 0.4 TOTAL HxCDD ND 0.3 TOTAL HpCOD ND 0.4 TOTAL TCDF ND 0. 4 TOT AL PeCDF ND O. 4 TOT AL HxCDF ND O. 3 TOT AL HpCDF NO O. 3 --------·~--------------------------------------------------------------- : ___ _.__Elt1......__._ '.(_;~ X237_RPT rev:3.03 I I I {)tJG I PROJECT 15932 DATE 8/20/90 TRIANGLE LABORATORIES, INC. I MATRIX SPIKE COMPARISON MATRIX: SOIL I METHOD X2378 SAMPLE X-94 (MS) AND SAMPLE X-94 (MSO) I mass,g. 9. 72 10.21 I ISOMER MS MSD AVERAGE RPO (pg) (pg) (pg) I 2378-TCDD 37. 6 34.5 36. 1 9, 12378-PeCDD 184.0 182.0 183.0 1, I 123478-HxCDD 153.0 108.0 130.5 ~ 123678-HxCDD 189.0 178.0 183.5 I 123789-HxCDD 181.0 125.0 153.0 37 1234678-HpCDD 206.9 187. 9 197.4 10, I OCDD 561.8 525.8 543.8 1, I 2378-TCOF 40.9 39.6 40.3 3, I 12378-PeCDF 238.0 232.0 235.0 3, 23478-PeCOF 255.0 233.0 244.0 9, 123478-HxCDF 187. 0 178.0 182.5 5, I 123678-HxCDF 209.0 200.0 204.5 ~ 234678-HxCDF 370.8 260.8 315.8 123789-HxCDF 228.0 203.0 215.5 I 1234678-HpCDF 227.0 217 .0 222.0 5, 1234789-HpCDF 233.0 223.0 228.0 4, ,. OCDF 502.0 438.0 470.0 14, I I I I [bC PROJECT 15932 I DATE 8/20/90 TRIANGLE LABORATORIES, INC. MATRIX SPIKE RECOVERY I MATRIX: SOIL METHOD X2378 I SAMPLE X-94 AND X-94 (MSD) ISOMER SAMPLE SPIKED OBSERVED RECOVERY (ppt) (ppt) (ppt) ABS t;REC I 2378-TCOO NO 39.2 34.5 34.5 88t; I 12378-PeCOO NO 195.9 182.0 182.0 93t; ~ 123478-HxCOO NO 195.9 108.0 108.0 I 123678-HxCDD NO 195.9 178.0 178.0 123789-HxCOD NO 195.9 125.0 125. 0 64t; I 1234678-HpCOO 4. 1 195.9 192.0 187.9 96t; OCDD 31. 2 391.8 557.0 525.8 134t; I 2378-TCDF NO 39.2 39.6 39.6 101 t; I 12378-PeCDF ND 195.9 232.0 232.0 118t; 23478-PeCDF NO 195.9 233.0 233.0 119t; I 123478-HxCDF ND 195.9 178.0 178.0 91t; 123678-HxCDF NO 195.9 200.0 200.0 102, 234678-HxCDF 2.2 195.9 263.0 260.8 133t; I 123789-HxCDF NO 195.9 203.0 203.0 104t; 1234678-HpCDF ND 195.9 217 .0 217 .0 111 t; I 1234789-HpCOF NO 195.9 223.0 223.0 114t; OCOF ND 391.8 438.0 438.0 112, 11 I I I I I I ()QC PROJECT 15932 I DATE 8/20/90 TRIANGLE LABORATORIES, INC. MATRIX SPIKE RECOVERY I MATRIX: SOIL METHOD X2378 I SAMPLE X-94 AND X-94 (MS) IS~ER SAMPLE SPIKED OBSERVED RECOVERY (ppt) (ppt) (ppt) ABS :1;;REC I 2378-TCDD ND 41. 1 37. 6 37.6 91' I 12378-PeCDD ND 205.5 184.0 184.0 90% ~ 123478-HxCDD ND 205.5 153.0 153.0 I 123678-HxCDD ND 205.5 189.0 189.0 123789-HxCDD ND 205.5 181. 0 181. 0 88% 1234678-HpCOO 4. 1 205.5 211. 0 206.9 101' I ocoo 31. 2 411. 0 593.0 561.8 137% I 2378-TCDF ND 41 • 1 40.9 40.9 100, I 12378-PeCDF NO 205.5 238.0 238.0 116% 23478-PeCOF NO 205.5 255.0 255.0 124% I 123478-HxCOF NO 205.5 187.0 187.0 91% 123678-HxCDF NO 205.5 209.0 209.0 102, 234678-HxCDF 2.2 205.5 373.0 370.8 180% I 123789-HxCDF NO 205.5 228.0 228.0 111' 1234678-HpCOF ND 205.5 227.0 227.0 110, I 1234789-HpCOF NO 205.5 233.0 233.0 113% OCDF ND 411. 0 502.0 502.0 122, I I I I I I I I I I I I I I I I I I I I I I I I I I August 22, 1990 Penny Gardner Keystone Environmental Resources 3000 Tech Center Drive Monroeville, PA 15146 Dear Penny, Enclosed is sample X-94, X-94(MS), X-94(MSD), and X-1-0-SN of TLI Project 15932. Remarks from QUALITY CONTROL are as follows: All DB-5 samples in this project except the TLI Blank present QC ion instabilities as a result of quantitative interferences. Where the interference coincides with an internal standard, the internal standard is flagged "Q"; corresponding 2378-substituted analytes are unaffected, whereas Totals are affected. Percent recoveries of corresponding standards may be artificially high or low. Quantitative interference is described in section 5.1.2.4.1 of the Data User's Manual. Sample X-94(MSD) (TLI# 33-11-8) was reanalyzed due to excessive quantitative interference. Samples X-10-TP DUP (TL!# 33-11-3), SS-1-TP (TLI# 33-11-5), SS-2-TP (TL!# 33-11-6), X-50-FL (TL!# 33-11-9) and 0D021001 (TL!# 33-11-10) are being diluted and reanalyzed due to saturation. Sample X-49-CP (TLI# 33-11-7) is being reextracted due to exces- sive saturation. The results of both columns of these analyses will be sent as soon as they are available. We apologize for the delay. Reported percent recovery of matrix spike additions for the 234678-HxCDF isomers in both MS and MSD analyses have fallen outside QC criteria. Relative percent deviation for these iso- mers, as well as the 123678-HxCDD and 123789-HxCDD isomers, for the MS/MSD comparison has also fallen outside QC criteria. These analysis problems may be due to quantitative interference coin- ciding with these analytes. We apologize for the delay. s~~~~ tnuwW Daphne Newkirk 801-10 Capitola Drive Durham, NC 27713 919-544-5729 Triangle Laboratories, Inc. P.O. Box 13485 Research Triangle Part, NC 27709 Fax I 919•544-5491 I I I I I I I I I I I I I I I I I I I Ten soi 1 samples were received from KEYSTONE ENVIRONMENTAL RE- SOURCES in good condition June 06, 1990 and stored in a refriger- ator at 40c. The samples were extracted and analyzed according to procedures described in the Triangle Labs User Manual provided with this data package. Any particular difficulties encountered during the sample handling by Triangle Labs will be discussed in the QA/QC remark section below. Quality Assurance/Quality Control Samples A laboratory method blank --identified as the TL! Blank --is prepared along with the batch of samples. QA/QC Remarks The release of this particular set of KEYSTONE ENVIRONMENTAL RESOURCES analytical data by Triangle Labs was authorized by the Quality Assurance Officer who has reviewed each sample data package individually fol lowing a series of inspections/reviews conducted at two other levels of the data production line. When applicable, general deviations from acceptable QA/QC requirements are identified below. Comments on the effect of these devia- tions upon the validity and reliability of the results can be obtained f rem the User Manua 1 ( Data Qua 1 i ty Objectives; Section 5). Specific QA/QC Problems Associated with this Particular Project are: Sample Preparation Laboratory: None Mass Spectrometry: None Data Review: Due to sensitivity differences between analyses of samples x-10- TP (TL! 33-11-2) and SS-1-TP more TCDF peaks were detected on the DB-5 analysis than on the DB-225 analysis. Reliable estimates for Total TCDF can be obtained from the DB-5 analysis. Many DB-5 analyses in this project present QC ion instabilities as a result of quantitative interferences. Where the interfer- ence coincides with an internal standard, the internal standard is flagged "Q"; analytes with identical as the internal standard chlorine distribution are unaffected, whereas other isomers may be affected. Percent recoveries of the affected standards may be artificially high or low. Quantitative interference is described in section 5.1.2.4.1 of the Data User's Manual. Samples X-10-TP(4-6") (TL!# 33-11-3), SS-1-TP (TL!# 33-11-5), ss- 2-TP (TL!# 33-11-6), X-50-FL (33-11-9) and DD021001 (TL!# 33-11- 10) have been diluted and reanalyzed due to saturation. Reports for both the initial and the diluted samples analyses are provid- ed. For undiluted samples X-50-FL and DD021001, however, data for Tetra-and Pentachlorinated congeners are presented only. 2 I I I I I I I I I I I I I I I I I I I Sample X-49-CP (TLI# 33-11-7) has been reextracted, :;sing much smaller sample size, due to excessive saturation. The results have been sent in a previous shipment. This shipment contains results for the initial analysis, however, data for Tetra-and Pentachlorinated congeners are included only due to saturation of most of the higher mass analyte peaks. Please note differences in concentration units; ppb and ppt for the previous (File No.S902605) and current (File No.S902349) reports respectively. Please be aware that many analytes may be undetected under dilu- tion, as such analyses are performed for accurate evaluation of compounds showing saturation on the initial run only. This shipment concludes Project 15932. Addendum to Section 4.6 of the Data User's Manual Effective December 15, 1989, Triangle Laboratories has adopted a new procedure for calculating the analyte specific detection limits. Under this new pol icy two representative noise height determinations are summed and multiplied by an empirically deter- mined factor before the detection limit equation given in Section 4.6 of the Data User's Manual is applied. The effect of this procedure is to increase DB-225 analyses detection limits by a factor of 3.5, and DB-5 analyses detection limits by a factor of 5. This procedure will result jn a more accurate estimate of detection limits. The revised formula for DB-225 analyses is: o a -2 2 5 2 . 5 • ( 3. 5 • Ha 1 ) * Qe J Dla1 = ------------------------- AaJ * RRF * W 3 , 5 * Ha 1 = Ano , • • The revised formula for DB-5 analyses is: o a -s 2 • 5 * ( 5 * Ha , ) * Qa J Ola, = ----------------------- Aa J * RRF * W 5 * Ha , = Ano 1 • • The symbols are defined in Section 4,6 of the Data User's Manual. As an example, consider a DB-225 confirmation analysis of a 10 g samp 1 e. The i nterna 1 standard spike is 2000 pg, the 13Cll=. 2,3,7,8-TCDF internal standard area is 12000 area units, the RRF is 1.215 and the noise height is 11 units. The 2,3,7,8-TCDF detection limit is: 3 I I I I I I I I I I I I I I I I I I I PGH-90-TMJ-382 DATE TO FROM SUBJECT overview October 8, 1990 Mr. Robert S. Markwell Program Manager -Environmental Services Beazer Materials and Services, Inc. 436 Seventh Avenue Pittsburgh, Pennsylvania 15219 Thomas M. Jackman AWD Technologies, Inc. Dioxin/Furan Data Validation Triangle Laboratories Project #15882 AWD TECHNOLOGIES The set of samples for Beazer (collected 5/30-31/90) contained 4 soil samples. No field blanks accompanied the data package. Samples were analyzed for polychlorinated dibenzo-p-dioxins and dibenzofurans by high-resolution gas chromatography/high-resolution mass spectrometry. Summary All elements were successfully analyzed in all samples with the exception of those qualified as unreliable, ''R". Areas of concern with respect to data usability are listed according to the seriousness of the problem. These include: Major Issues 12378-PeCDD, 123478-HxCDF, 123678-HxCDD, 123789_HxCDD, 1234678- HpCDD, OCDD, 123478-HxCDF, 123678-HxCDF, 1234678-HpCDF and OCDF was detected in TLI blanks at low levels. Positive results with concentrations comparable to blank concentrations are qualified "R", unreliable. Notes The 123789-HxCDD result in Sample S-22-MP (0-6') was flagged "PR" by the laboratory. "PR" indicates the GC peaks were "poorly resolved". Poorly resolved peaks are an indication of poor instrument performance. Identification of 123789-HxCDD does not appear to be in doubt, as all criteria for compound identification AWD Technologies. Inc. Penn Center West. Building Ill. Suite 400 Pittsburgh Pennsylvania 15276 Telephone 412 788 2717 Telecopier 412 788 1316 I I I I I I I I I I I I I I I I I I I AWD Technologies, Inc. PGH-90-TMJ-382 Mr. Roberts. Markwell Beazer Materials and Services October 8, 1990 -Page 2 were met. There may, however, be some uncertainty in the reported concentration of 123789-HxCDD because of the poorly resolved peaks. Internal standard recoveries for 13 c12 -123789-HxCDF and 13c 12 -OCDD were below quality control criteria. Results are not qualified because there are at present no guidelines for internal standard recoveries and because the signal to noise ratios (S/N) for these compounds are greater than 10:1. Triangle Laboratories adopted a new procedure for calculating analyte specific detection limits. This procedure uses 2 representative noise height determinations which are summed and multiplied by an empirically determined factor before applying the detection limit equations. The effect of this approach is to increase the detection limits of the DB-5 column by a factor of 5 and that of the DB-225 column by J.5. The laboratory states that the new procedure produces a more accurate estimate of detection limits. The laboratory performed the required 5 point initial calibrations but did not supply raw data and chromatograms for the individual calibrations. Checks of response factors and retention times could, therefore, not be performed. The data were reviewed according to Method 8290 (June 1987), an isotope-dilution high resolution mass spectrometric version of RCRA Method 8280 (SW846), Triangle Laboratories' Data User Manual and the National Functional Guidelines for Evaluating Organic Analyses. The text of this report addresses only those problems affecting usability. Information Regarding Report Content Table 1 presents results of the Field Duplicate Analysis. Attachments: 1. Glossary of data qualifier codes. 2. Data Summary. This includes: a) All positive results with qualifier codes, if applicable; b) All unusable detection limits qualified with an "R"; and c) All estimated detection limits qualified with UJ or UL. 3. Appendix A results as reported by the laboratory (no corrections were made during data validation). 4. Appendix B -Support Documentation includes details to support the statement in this report. I I I I I I I I I I I I I I I I I I I AWD Technologies, Inc. GLOSSARY OF DATA QUALIFIER CODES (DIOXINS) CODES RELATING TO IDENTIFICATION (confidence concerning presence or absence of compounds) < = Not Detected. The associated number indicates approximate sample concentration necessary to be detected. (NO CODE) = Confirmed Identification R = Unreliable Result. Analyte may or may not be present in the sample. Supporting data necessary to confirm result. CODES RELATED TO OUANTITATION (can be used for positive results and sample quantitation limits): J = Analyte present. precise. Reported va 1 ue may not be accurate or I AWD Technologies, Inc. I I I I I I I I I DATA SUMMARY FORMS I I I I I I I I I I I DATA SUKKA.IY SOIL DIOXIN/rullAJI BISULTS I DIOXIN DATA ,OB WATIB SAIIPLIS COLLICTID 5/30-31/1990 TRIAMCLI LABORATORIES PllOJICT U5882 I Sample No. S-18-MP S-18-KP S-22-KP S-22-KP 0-6" 2-4" 0-6" 1.5-3.5" I :c011POUND UNITS IKPC IIIPC IIIPC IIIPC I :2378-TCDD ppt 14.8 <0.3 32.1 <2,3 :12378-P.CDD ppt 49.6 <0.3 59.4 <2.9 I :123478-HxCDD ppt 159 <0.3 213 <5.6 :123678-RxCDD ppt HS <0.3 850 <4,4 :123789-HxCDD ppt 454 <0,4 731 <6.2 I : 1234678-HpCDD ppt 18930 21.5 38060 51.5 :ocoo ppt 150980 888 369740 5070 :2378-TCDP ppt 8.1 <0.2 <2.1 <1.8 I :12378-PeCDP ppt 13.3 (0.3 <2.6 <2.5 :23478-PeCDP ppt <l.5 <0,3 <2.8 <2,8 :123478-HllCDF ppt 64.3 <0.2 4Z.3 3.2 B I :123678-HsCDP ppt 72.5 <0.2 54.2 <2.3 : 234678-Hll:CDF ppt 126 <0.3 163 3.3 :123789-HxCDP ppt <3.4 <0.4 <5.8 <4.6 I :1234678-HpCDP ppt 1790 1.6 B 3110 14. 8 a : 1234789-HpCDP ppt 187 <0,4 132 <8,2 :ocor ppt 6800 4.4 B 12260 52.6 B I lTOTAL TCDD ppt 762 823 <0.3 2780 2820 <2.3 lTOTAL PICDD ppt 1500 1640 1.0 B 2.2 B 3920 3970 <2,9 :TOTAL BxCDD ppt 7960 8010 6.5 I 17200 10.6 •: I :TOTAL RpCDD ppt 38070 54.4 I 80990 120 I :TOTAL TCDP ppt 345 370 <0.2 888 964 <1.8 I I TOTAL PICDP ppt 488 520 <0,3 831 951 <2,8 :TOTAL BxCDr ppt 3980 4070 0,89 1.8 5120 5140 5,2 13.3 :TOTAL BpCDP ppt 5540 4,5 8840 18,9 I PIBCIINT IIOISTIIBI 35.8 19,2 49.7 19.5 IIIPC • ISTIIIATID KilllllJK POSSIILI CONCRNTBATIOII I I I I I AWO Technologies, Inc. I I I I I I I I APPENDIX A I RESULTS AS REPORTED BY THE LABORATORY I I I I I I I I I I I I I I I I I I I I I I I I I . -i FILE NAME .... : CONCAL. ...... : ANALYST ...... : SAMPLE SIZE .. : ICALDATE .•.. : SPIKE FILE ..• : S219808 S902197 GG 7. 31 g 06/27-/90 SPX2372K TRIANGLE LABORATORIES, INC. PCOO/PCOF 2378X ANALYSIS (b) Page 1 of 2 08/03/90 CLIENT IO; ... : KEYSTONE TLI NUMBER .•.. : 32-92-9 SAMPLE IO •.•• : S-18-MP 0-6" ANALYSIS DATE: 07/06/90 PROJECT NUMBER: 15882 SAMPLE MATRIX: SOIL DATE RECEIVED.: 06/04/90 SAMeL-E ORIGIN: MORRISVIL DATE COLLECTED: 05/30/90 . SHIPMENT NO ... : 17928004 ========================----===--~===---------===-=====-====================-NAME CONC(ppt) NUMBER DL EMPC RATIO RT FLAGS -------------------------------------~----------------------------------------2378-TCOO 14.8 0.65 30:52 12378-PeCOO 49.6 1. 61 36: 17 i 123478-HxCOO 159 1.39 41 :04 1236 78-HxCOO 448 1.31 41:11 123789-HxCOO 454 1. 31 41 :40 12 346 7 8-HpCOO 18930 1.03 46:03 L ocoo 150980 0.86 51:19 _ii, 2378-TCOF 8.7 0.86 30:05 12378-PeCOF 13.3 1. 42 34:50 23478-PeCOF NO 1.5 123478-HxCOF 64.3 1.28 39:55 ..a. 123678-HxCOF 72.5 1.06 40:03 ..a. 234678-HxCOF 126 1.40 40:52 123789-HxCOF NO 3.4 1234678-HpCDF 1790 1.00 44:31 F 1234789-HpCOF 187 1.09 46:41 OCOF 6800 0.85 51:33 A TOTAL TCOO 762 7 823 0.75 TOTAL PeCOO 1500 8 1640 1.60 TOTAL HxCOO 7960 6 8010 1. 32 TOTAL HpCOO 38070 2 1.04 TOTAL TCOF 345 8 370 o. 76 TOTAL PeCOF 488 8 520 1.50 TOTAL HxCOF 3980 a 4070 1.22 TOTAL HpCOF 5540 3 1.00 .. ------------------------------------11-·,_ ·. d , . Q//<YbJ: X237_RPT rev:3.03 I I I I I I I I I I I I I I I I I I I I I -• FILE NAME .•.. : CONCAL ....... : ANALYST •....• : SAMPLE SIZE .. : !CAL DATE .... : SPIKE FILE ... : 1903419 1903413 SB 8.75 g 07/17/90 SPX2372K TRIANGLE LABORATORIES, INC. PCDD/PCDF 2378X ANALYSIS (b) Page 1 of 2 08/10/90 CLIENT ID •••• : KEYSTONE TL! NUMBER .... : 32-92-8 SAMPLE ID .•.• : S-18-MP-2-4 ANALYSIS DATE: 08/03/90 PROJECT NUMBER: 15882 SAMPLE MATRIX: SOIL DATE RECEIVED.: 06/04/90 SAMPLE ORIGIN: MORRISVIL DATE COLLECTED: 05/30/90 SHIPMENT NO •.• : 17928004 ------------------------------------------------------------------------------ NAME CONC(ppt) NUMBER DL EMPC RATIO RT FLAGS ----·------------------------------- 2378-TCDD 12378-PeCDD 123478-HxCDD 123678-HxCDD 123789-HxCDD 1234678-HpCDD OCDD 2378-TCDF 12378-PeCDF 23478-PeCDF 123478-HxCDF 123678-HxCDF 234678-HxCDF 123789-HxCDF 1234678-HpCDF 1234789-HpCDF OCDF TOTAL TCDD TOTAL PeCDD TOTAL HxCDD TOTAL HpCDD TOTAL TCDF TOTAL PeCDF TOTAL HxCDF TOTAL HpCOF ND ND ND ND ND 21.5 888 NO ND NO NO ND ND NO 1.6 ND 4.4 ND 1.0 6.5 54.4 NO ND 0.89 4,5 , 2 2 , 2 0.3 0.3 0.3 0.3 0.4 0.2 0.3 0.3 0.2 0.2 0.3 0.4 0.4 0.3 0.2 0.3 2.2 1.8 1.17 46:41 ..ff__ 0.84 52:14 .A,_ 1.02 45:06 ~ 0.83 52:29 D 1.56 1.25 1.14 1,13 1 ,02 ------------------------------ !.IJV:1!.: X237_RPT rev:3.03 • I I I I I I I I I I I I I I I I I I I I • FILE NAME •••• : CONCAL. ...... : ANALYST •..... : SAMPLE SIZE .. : !CAL DATE .... _; SPIKE FILE. .. : NAME TRIANGLE LABORATORIES, INC. PCDD/PCDF 2378X ANALYSIS (b) Page 1 of 2 08/03/90 S219803 S902197 HSK 5.82 g 06/07 /90· SPX2372i<" .- CLIENT ID ..•. : KEYSTONE TLI NUMBER ...• : SAMPLE ID .... : S-22-MP 0-6" ANALYSIS DATE: 07/12/90 PROJECT NUMBER: SAMPLE MATRIX: SOIL DATE RECEIVED.: SAMPLE ORIGIN: MORRISVIL DATE COLLECTED: SHIPMENT NO ••• : 32-92-7 15882 06/04/90 05/30/90 1792800' . . ~ J ----. CONC(ppt) NUMBER DL EMPC RATIO RT FLAGS ----------------------------------------------·------------------------------- 2378-TCDD 12378-PeCDD 123478-HxCDD 123678-HxCDO 123789-HxCDD 1234678-HpCOD OCDD 2378-TCDF 12378-PeCDF 23478-PeCOF 123478-HxCDF 123678-HxCDF 234678-HxCDF 123789-HxCDF 12 346 7 8-HpCOF 1234789-HpCDF OCOF TOTAL TCDO TOTAL PeCOO TOTAL HxCDD TOTAL HpCDD TOTAL TCOF TOTAL PeCDf TOTAL fl1(COf TOTAL HpC0F 0 7/l EMPC 59.4 213 650 731 38060 369740 ND ND ND 42.3 54.2 163 ND 3110 132 12260 2780 3920 17200 80990 888 831 5120 8840 8 7 6 2 5 4 8 3 2, 1 2.6 2. 8 5.8 32.9 2820 3970 964 951 5140 1. 33 1. 15 1.27 1. 15 1. 03 0.87 1. 16 1.21 1. 26 0.94 0.89 0.96 o. 77 1.48 1. 21 1.03 0,75 1. 57 1. 17 0.92 36: 17 41 :04 41:11 41:40 46:03 51:19 39:55 40:04 ,o:52 44:31 46:41 51:33 L L -----------------X237_RPT rev:3.03 I I I I I I I I I I I I I I I I I I I FILE NAME .•.• : CONCAL ....... : ANALYST •..••. : SAMPLE SIZE .. : !CAL DATE •.•• : SPIKE FILE ... : T903428 T903427 JA 8.43 g 07 /17 /90 SPX2372K TRIANGLE LABORATORIES, INC. PCOO/PCOF 2378X ANALYSIS (b) Page 1 of 2 08/10/90 CLIENT IO ...• : SM-lPL E ID •••• : ANALYSIS DATE: SAMPLE MATRIX: SAMPLE ORIGIN: KEYSTONE TLI NUMBER ..•• : S-22-MP-1. 5-3. 5 08/04/90 PROJECT NUMBER: SOIL DATE. RECEIVED.: MORRISVIL DATE COLLECTED: SHIPMENT NO .•• : 32-92-6 15882 06/04/90 05/30/90 17928004 ============================================================================== NAME 2378-TCOO 12378-PeCOO 123478-HxCOO 123678-HxCDD 123789-HxCOO 1234678-HpCOO ocoo 2378-TCDF 12378-PeCOF 23478-PeCOF 123478-HxCDF 123678-HxCOF 234678-HxCDF 123789-HxCOF 1234678-HpCOF 1234789-HpCOF OCOF TOTAL TCOO TOTAL PeCOO TOTAL HxCOO TOTAL HpCOO TOTAL TCDF TOTAL PeCOF TOTAL HxCOF TOTAL HpCOF CONC(ppt) ---- NO NO ND NO NO 51.5 5070 NO NO ND EMPC NO 3.3 NO 14.8 NO 52.6 NO ND EMPC 120 ND ND 5.2 18.9 -------'~=v ~V.!!: NUMBER 2 2 1 DL . EMPC 2.3 2.9 5.6 4.4 6.2 1. 8 2.5 2.8 2.3 4.6 8.2 2.3 2.9 1. 8 2.6 3.2 10.6 13.3 RATIO RT . FLAGS 1.05 44:12 0.87 49:01 0.38 1.07 0.93 1. 03 0.85 1.07 e 39:01 42:40 J!. 49:13 ..{L X237_RPT rev:3.03 I I I I I I I I I I I I .I 'I I I I I I AWO Technologies, Inc. APPENDIX B SUPPORT DOCUMENTATION I I I I I I I I I I I I 1· I I I I I I . - FILENAME ..•. : CONCAL., ..... : ANALYST ...•.. : SAMPLE SIZE..: ICAL DATE .... : SPIKE FILE. .. : S213801 S902137 GG 9.00 g 06/27/90 SPX2372K TRIANGLE LABORATORIES, INC. PCOO/PCOF 2378X ANALYSIS (b) CLIENT IO .... : SAMPLE IO .... : ANALYSIS DATE: SAMPLE MATRIX: SAMPLE ORIGIN: KEYSTONE TLI BLANK 07/06/90 n/a n/a Page 1 of 2 08/03/90 TLI HUMBER .... : n/a PROJECT HUMBER: DATE RECEIVED.: DATE COLLECTED: SHIPMENT NO ... : 15882 I I I I n/a =============================-c=================~====================-----==== NAME CONC(ppt) NUMB~R .OL · . EMPC RATIO RT FLAGS ------------------------------------------------------------------------------ 2378-TCOO 12378-PeCOO 123478-HxCOO 123678-HxCOO 123789-HxCOO 1234678-HpCOO ocoo 2378-TCOF 12378-PeCOF 234 78-PeCOF 123478-HxCOF 123678-HxCOF 234678-HxCOF 123789-HxCOF 1234678-HpCOF 1234789-HpCOF OCOF TOTAL TCOO TOTAL PeCOO TOTAL HxCOO TOTAL HpCOO TOTAL TCOF TOTAL PeCOF TOTAL HxCOF TOTAL HpCDF NO GD ~ NO NO (lD ~ ~n NO E~ EMPC NO N 6.iJ ,s.11_/ 3 2 1 1. 3 0.8 0.9 1. 0 1. 0 1. 4 1. 3 1. 3 0.8 0.9 1. 10 1.06 1. 30 1. 22 1.20 1.05 0.82 1. 15 1. 21 1.05 41:21 41: 30 41:58 51:45 40:12 40:23 44:48 51:57 X237_RPT rev:3.03 I D I I I I I I I I I I I 1· 1· I I I I I August 06, 1990 Penny Gardner Keystone Environmental Resources 3000 Tech Center Drive Monroeville, PA 15146 Dear Penny, Enclosed are Samples S-18-MP 0-6" and S-22-MP 0-6" of TLI Project 15882. Remarks from the QC Officer are as follows: Due to sensitivity differences between analyses of sample S-18-MP-0-6 (TLI I 32-29-9), more TCDF peaks was detected on the DB-5 analysis than on the DB-225 analysis. Reliable estimates for Total TCOF can be obtained from the DB-5 analysis Analytes were found in the soil blank at concentrations not greater than one-third the calculated method Quantitation 1 imit (TMQL) for the associated samples except for the OCDD and OCDF concentration. Blank contamination levels of one-third TMQL or less are acceptable under TLI guidelines, as discussed in section 5.1.3.2 of the Data User's Manual. OCDD and OCDF are not consid- ered to be specific isomers so their concentrations are not reQuired to meet this criteria. Samples S-22-MP 1.5-3.5 "(TLI I 32-92-6) and S-18-MP 2-4" (TLI I 32-92-8) have been scheduled for reanalysis on the DB-5 column due to poor sensitivity and resolution. We apologize for the delay. Sincere l,y, ~w~ Lisa Winstead 801·10 Capttoi. Drlw Durham, NC 27713 919-5,U-5131 TrlallQi. I.Jlboratorlu, hw:. P.O. Boll 1:USS Re#arch TrlallQi. Parle, NC 2mJI Fu I 919-5,-5491 ,. I I I I I I I I I I I I I I I I I I I PGH-90-TMJ-392 DATE TO FROM SUBJECT overview October 8, 1990 Mr. Robert S. Markwell Program Manager -Environmental Services Beazer Materials and Services, Inc. 436 Seventh Avenue Pittsburgh, Pennsylvania 15219 Thomas M. Jackman AWD Technologies, Inc. Organic and Physical/Chemical Data Validation Keystone Environmental Job #M90-07.63 AWD TECHNOUJGIES The set of samples for Beazer (sampled 6/6/90) contained 15 water samples including 1 pair of field duplicates, 3 field blanks and 2 trip blanks. Samples were analyzed for Isopropyl Ether, Phenols, Dissolved Calcium, Dissolved Potassium, Dissolved Magnesium, Dissolved Sodium, Total Alkalinity, Carbonate Alkalinity, Bicarbonate Alkalinity, Chloride and Sulfate. Isopropyl ether was analyzed by EPA Method 602; phenols were analyzed by Method 8040; pentachlorophenol was also analyzed by Method GC515; metals and physical/chemical parameters were analyzed by approved EPA methods. summary All compounds were successfully analyzed in all samples. Areas of concern with respect to data usability are listed according to the seriousness of the problem. Major Issues The three field blanks accompanying this data package contained phenol, 2-nitrophenol, 2,4-dimethylphenol, 2,4-dichlorophenol, 4-chloro-3-methylphenol, 2,4,6-trichlorophenol, 4-nitrophenol, 2,3,5,6-tetrachlorophenol, 2-methyl-4,6-dinitrophenol, 2,4- dinitrophenol, and pentachlorophenol (Method 8040). Therefore positive results of these compounds are qualified ''U". AWD Technologies. Inc. Penn Center West. Building 111. Suite 400 Pittsburgh Pennsylvania 15276 Telephone 412 788 2717 Telecooi~· 012 788 1316 I I I I I I I I I I I I I I I I I I I AWO Technologies, Inc. PGH-90-TMJ-392 Mr. Robert S. Markwell Beazer Materials and Services, Inc. October 8, 1990 -Page 2 In addition, chromatograms of the three blanks and a number of samples exhibited significant interferences in the analysis of phenols (Method 8040). (See chromatograms in Appendix B, Support Documentation). The interference also contributed to low surrogate spike recoveries and samples requiring dilution and reanalysis. Because of these interferences, positive results of affected samples are qualified "J", estimated and detection limits are qualified ''UJ'', estimated. Notes The data package contained no quality control or raw data for metals. Therefore evaluation of metal results could be performed. The data were reviewed according to the National Functional Guidelines for Evaluating Organic and Inorganic Analyses. The text of this report addresses only those problems affecting usability. Information Regarding Report Content Attachments: 1. Glossary of data qualifier codes. 2. Data Summary. This includes: a) All positive results with qualifier codes, if applicable; b) All unusable detection limits qualified with an ''R''; and c) All estimated detection limits qualified with UJ. 3. Appendix A results as reported by the laboratory (no corrections were made during data validation). 4. Appendix B -Support Documentation includes details to support the statements in this report. I I I I I I I I I I I I I I I I I I GLOSSARY OF DATA QUALIFIER CODES CODES RELATING TO IDENTIFICATION (confidence concerning presence or absence of compounds) < = Not Detected. The associated number indicates approximate sample concentration necessary to be detected. U = Not detected substantially above the level reported in laboratory or field blanks, (NO CODE)= Confirmed Identification R = Unreliable Result. Analyte may or may not be present in the sample. Supporting data necessary to confirm result. CODES RELATED TO QUANTITATION (can be used for positive results and sample quantitation limits): J = Analyte present. precise. Reported value may not be accurate or UJ = Not detected. Quantitation limit may be inaccurate or imprecise. OTHER CODES NR = Not Analyzed I AWD Technologies, Inc. I I I I I I I I I DATA SUMMARY FORMS I I I I I I I I I I I OAT A SUMMARY NON CLP DATA FOR SAMPLES COLLECTED 7/18-18/90 I Keyatone Environ1Mnta1 Job. I MI0-07.83 I Sample No. C-8A-WA C18C--OSE C23C--OSE C32-08E ,uLD BLANK 7/18/90 I COMPOUND Unit■ I Total Alkalinity a■ C4C03 ■g/L 221 281 223 313 NR Chloride ■g/L 18.7 304 402 131 NR Bicarbonate Alkalinity aa CaC03 ■g/L 221 281 183 313 NR I Carbonate Alkalinity •• CaC03 ■g/L 0.00 0.00 40.4 0.00 NR Sulfate ■g/L 2. 10 25.3 18.4 18. 1 NR Dissolved Potaaait.a ug/L <5000 <5000 <5000 <5000 NR I Dissolved Magesi\a ug/L 28100 42800 10100 45700 NR Dissolved Sodiu■ ug/L 19300 111000 328000 30700 NR Oiaaolved calch.e ug/L 49800 142000 28000 108000 NR I Iaopropyl Ether ug/L <1.00 (1.00 <1.00 <1.00 <1.00 Phenol ug/L 1. 91 U 18.9 U 10.7 U 3.98 U 4.38 J I 2-Chlorophenol ug/L <0.500 UJ <0.500 W <0.500 UJ <0.500 UJ <0.500 w 2-Nitrophenol ug/L <0.500 <0.500 <0.500 <0.500 5.00 J 2,4-Oim■thylphenol ug/L <0.500 <0.500 <0.500 <0.500 0.175 J I 2,4-Oichloraphenol ug/L <0.500 <0.500 <0.500 <0.500 <0. 500 w 4-Chloro-3-Mthylphenol ug/L 2. 79 U <0.500 0. 518 U <0.500 7.48 J 2,,,e-Tricnlorophenol ug/L <1.00 3.55 1. 21 (1.00 1. 48 J 2,4-Oinitrophenol ug/L (1.00 <1.00 (1.00 <1.00 <1,00 UJ I 4-Nitrophenol ug/L <1.00 <1.00 1. 98 <1.00 22.8 J 2,3,5,e-T■trachlorophenol ug/L <1.00 1 .80 u 1. 77 u <1.00 91.2 J 2-Methyl-4,9-dinitrophenol ug/L <1.00 <1.00 <1.00 (1.00 122 J I PentAchlorophenol ug/L <1.00 <1.00 8.24 U <1.00 (1.00 UJ Penta.chloraphenol (GC515) ug/L <0.010 0.018 0.013 <0.010 <0.010 I I I I I I I I DATA SlM4ARY NON CLP DATA FOR SAMPLES COLLECTED 7/18-18/90 I Keystone Environaenta1 Job. I M90-07,93 I 9up1e No. C-18-DSE C-18-0SE C-2DC-OSW c-21c-OSE TRIP DUPLICATE 8LAHK 7/11/90 I COMPOUND Un1ta I Total Alkalinity a■ cacoa ■9/L 97,0 NR 251 83.0 NR Chloride ■g/L 108 NR 33.5 579 NR Bicarbonate Alkalinity•• CaC03 ■g/L 7.00 NR 258 79.0 NR I carbonate Alkalinity aa CaC03 ■g/L 90.0 NR 0.00 ,.oo NR Sulfate ■9/L 37.0 NR ,. ,o 28.2 NR 01esolved Potaaa1\.a ■9/L <5000 HR <5000 <5000 NR I 01aaolved Magesiia ■9/L <5000 NR 25700 19700 NR Oiaeolved Sod1UII ■9/L 108000 NR 27700 353000 NR 01aaolved Calciu. ■g/L 18700 NR 55900 39800 NR I Iaopropy1 Ether ug/L <1.00 <1.00 <1.00 <1.00 <1.00 Phenol ug/L 8.58 U 9,78 U <0.500 UJ <0.500 NR I 2-Ch l oropheno 1 ug/L 20.0 J 21. 5 J <0.500 UJ 1. 85 J NR 2-Hitrophenol ug/L 0.731 u <0.500 <0.500 UJ <0.500 NR 2,4-D1aethylph4tno1 ug/L <0.500 UJ <0.500 <0.500 UJ <0.500 NR I 2,4-D1chlorophenol ug/l 4,75 u 5.48 U <0.500 UJ <0.500 NR 4-Chloro-3-rnthylphenol ug/l 9.55 U 2.50 U <0. 500 UJ 3.00 U HR 2,4,&-Trichloropnenol ug/L 33. 1 J 40.8 <1.00 UJ 9,88 NR 2,4-Dinitrophenol ug/l 1. 54 u 1. 77 U <1.00 UJ <1.00 HR I 4-Hitrophenol ug/l <1.00 UJ <1.00 <1.00 UJ <1.00 HR 2,3,5,8-Tetrachlorophenol ug/l 15.7 U 13. 1 u <1.00 UJ 2.38 U NR 2-Methyl-4,9-dinitrophenol ug/l (1.00 UJ 129 8.05 J <1.00 NR I Pentachlorophenol ug/l <1.00 UJ <1.00 48.7 J (1.00 HR Pentachlorophenol (QC515) ug/L <0.010 <0.010 <0.010 0,020 NR I I I I I I I I DATA Sl.MIARY NON CLP DATA FOR SAMPLE9 COLLECTED 7/18-18/80 I Key■tone Env1roNHnt&1 Job. I MI0-07.63 I Saaple No. C-C22C-08W FIELD C-19C-OSN FIELD TRIP BLANK BLANK BLANK 7/17/10 7/18/90 7/18/90 I COMPOUND Un1ta I Total Alkalinity •• CaC03 ■g/L 189 NR 409 NR NA Chloride ■g/L 45.3 NR 207 NR NR B1carbonata Alkalinity aa caco3 ■g/L 187 NR 408 NR NR I Carbonate Alkalinity ae CaC03 ■g/L 22.0 NR 0.00 NR NR Sulfate ■g/L 1.00 NR 20.7 HR HR 01aaolved Potaaa1ura ■g/L <5000 HR <5000 NR NR I D1aaolved Mage&1UIK ■g/L <5000 NR 50800 HR NR Di IJ801Ved Sod'h.-mg/L 108000 NR 130000 HR NR O1ssolved Cale ha ■g/L <5000 HR 78000 NR NR I Iaopropyl Ether ug/L <1.00 <1.00 <1.00 <1.00 (1.00 Phenol ug/L 3.50 u <0.472 UJ <0.500 <0.472 UJ NR I 2-Chlorophenol ug/L 1. 85 J <0.472 UJ <0.500 UJ <0.472 UJ NR 2-N 1 t rop,-,o 1 ug/L <0.500 UJ 1. 51 J <0.500 1. 28 u NA 2,4-Diaethylphenol ug/L <0.500 UJ <0.472 UJ <0.500 <0. 472 UJ HR I 2,4-Dichlorophenol ug/L 1. 77 u <0.472 UJ <0.500 <0,472 UJ NR 4-Chloro-3-••thylphenol ug/L 1. 39 U 3.30 J 3.29 U 2.84 u HR 2,4,8-Trichlorophenol ug/L 3.83 J <0.9U UJ <1.00 <0.9U UJ NR 2,4-0initrophenol ug/L (1.00 UJ 4.23 J <1.00 <0.944 UJ NR I 4-N;trophenol ug/L <1.00 UJ 14.9 J <1.00 28.5 J NR 2,3,5,6-Tetrachlorop,henol ug/l 1. 20 u 32.5 J <1.00 49.1 J HR 2-Mothyl-4,8-d1n1tropheno1 ug/L (1.00 UJ 11.0 J <1.00 11.5 J NR I Pentachlorophenol U11/L <1.00 UJ <0.IU UJ <1.00 3.14 J NR Pentachlon,phenol (GC515) ug/L <0.010 <0.010 <0.010 <0.010 UJ NR I I I ,I I I I AWD Technologies, Inc. I I I I I I I I APPENDIX A I RESULTS AS REPORTED BY THE LABORATORY I I I I I I I I I I I I I I I I I I I I I I I I I I I I I Kt:lStor11: a· S-itt1~· L.r,g ;.·,: it, t C1.r;:-:.ii1t.r l[: : -.• ~ t r,:,v.~rn:· ~ :·,.: -~: i1;-c :r:~· lpner:~~ ~ :1l-Gic~1:,0µ~0:.n0l 4-:~l0r0•:•ft•2t~i~~~2~01 :,•,~·7r:c~l0r0pr2~~1 :,4-~i~::r0~12~-01 .; .,.. ~ ;:-r,,:;p:-,:.-·,..:: l :,~1 ~1~--t.:riCGi0:~;~:.r,~l :-M1:~~il-~1o·G~~:t·0~~:.~0l ;-Cr:: ~ -: :-, ~ ~-~ -:· ~-:--':.~.::,al. 2-F l;.il"\fQP,,:.,·,.::,~ : 14 1 ti·~' it•' -:,L•,O~:'"•':.:",·:· ~ u~; ~ 1.:g/L =.:~/L :;,-,.: -;,• - '...:~/:.. '.J~/ ;_ ;,;~ii.. u~_,-... -~ :--.:n: ~ ~/"!)C L~O 8u'.;:~,: ! !_'.;. o,,;:~- ,:. ~-' t ~;._.;.: aA _QC C : c-: -QS!ii r.::. : -1 ~·c -G·;..: "1;ri =13 ~ ~ ~-ec. qp;,,--i _; _'_0 67.3 ~-Kc::. ;~ r;;,: •;F,· 4~. 2 ., ,:.:.~ ,·.-,, .. 6S.1 ;Jr", :~;; D I I I I I I I I I I I I I I I I I ~-t:,'St0r,c L.1 Dat..: :aF-~lc,; Customer i~: i0Hl ~}. :~1ri1ty -1: C;~.:-J Cr,lJr lCiC t-1n"b,r,;:e. Alfal1r,1t-, :;_; C;CGJ [;~e,-:,rx;:. Ai~.-1lm1t-, 1: C~(:jJ Sul~ He. D1;s0l~t:: :0tJss1~~ [1:ssc-i·•t·J ~:-jr,es1.:.sn, fl~SS(,~VC.: :.:,Ql:Jiit ~:1s;c,ht.-: ::1iC1u11, .-·e, e J•..,-., ! ,j Pe.rt;c~~0~0p~en0l GC:,1 :. s~:;.:_~ .. :;,:JtS t.1ri1 rs mg; L mg/L 11,g_:L ,r,,~;" L. 111•~< ;..!,~,_-l U·~i '- ;.!•;/l ug/L t,>:J:::~ ~a-JUL·:-~.;,(: --. ' LO.l ,) . :):) :c: l (;(: l S·3(:(; t,j-(,(,, i-J-JGL -191(1 1> ltiC ·OSE 281 oc -.:..• . .:.· ;_:.1:;1);) 42:j(/: oJ-1;::;:. :o-JUL-l 19,j C-23C-G.3E 18. 4 \51)1)1) l(:11)'.:1 Ji6(1(r1) 6j-(;JJt- lo-JuL -! 99(J C-32-0SE 313 131 J1j 0. (I~) 16, l (5(tt>(: 4570(1 j:)7::~:: l (,~::;;:1:_; t.,j-(1/7 lo-JUL -1991) iB I I I I I I I I I I I I I I I I I I I i-.C/:-:1F': IL' [;;t:: S:•::;-l:i: C,J:\C-1l.1C :~: Tc,-::;l ~:•:.:.li,1-::r· -~: l~C,:,:, Cnlunue 81ci~o0~-;::: ~11.al1r,1ty i5 :iC05 Car~0~it~ ~lf.ali~~tf iS (iCO~ :'ul Tate [11;;~,l\,cu ;,:·71~s1U'Y: (11s;0ivt.d ~;gri~SlU!l, [11ssolvea S0a1u1J, [11ssc-l·.-1.::d :;.lc1u11, GC51~ ;·1:r,1: -~Ci1lc,~a:,phtr1L' l &c:,:: su~;;Qij~TES ·4' ;rig/l ~g .... 1,,J.-_.l ~g/ ~ ogil ug.l 1Jg/i. ug_:\ C · 16C-USt c:-, . ' ; • l.J 10E ~-. (;(J :; ,) • (J :~' (i :,(~;(; ;, ::,a(:(;;) t -,.-, •. 1C· 1,_,._, -,.-. -. 10,.:. 03-0~(: ,:--u:i 63-01: l 7-JUL -: ~~·;:, 17-JiJL · iS9t) I 7-j:_:~ <~·9(1 ----· 1.. • l,:,;_ -w·:.!:. Matnx lr:t, ~J.5 ·~:.c. 1,4;:; :_ S(;(11) ~77(11) :,.:.~(1,:· :,~-~- i1. \_: .l, 1)(, '"·• -. .. ,..,;. ;'~)1)0 ~ ~·71)(_1 JSJO(l(; J't~t/1 I I I I I I I I I I I I I I I I I I I ' . . , ··.· k€y: "CJT1t E- DH': Sll'1~•l20 Cu;tclfilo:.· ~[; -------------------------------------------:<·-;/:.: ,::-,:.-1.: tij-(~~· ,:,:.;:.:::1 ; 7 -;:_,I.· l 1% ! ?-JL1~ -; ~S,(; !C-~L1L -; ,-~:_; ;6-JUL-: ·?~(; ~-=~:-u~,~ ,;c, C·19C-8:i:-. ~b ·-------------------------------------·-----·---------------------------------------------------- Total Ah:;lir11t-, .3.:j C;COJ Chl0r1Clt: B1caroc:r11tc Ah:.1li . .f1lt'i" as C.;CQ3 C1rborr1tt: Ai;:.1lrn1:y Swli.1t1: [11:;;sL•h·c.c ;-.:-n,ss1urr, [11;;01".·1:o r,;gri,2s1w1; Dls;1.ilveo S,..1a1um [llSSL•ht:d C1ic1u11, &CS1S Peri tactii,:,:--,.1pii-:no 1 GC:, l :-S1_1~;t,:Q;~;; TES 7 r 1t,r::-rric,v11:i1C,l 35 C.1CCJ 11"1g/~ 1E9 ;r,,~/ L 4~ .. ] Ii:•;/ L l c:-7 lhg/L :~.1) iiig/~ 1, .>,) cg/L :.-~<<::J UIJ/ l <:,(1::i:J ug/L i ,)t,t);_J.j cg,l :_:,,)(.::: " ""./ . ., ....... f :.::~)(; 13(101)() NF, NR NR ------------------------------ I :4·ALG·l990 I I Date rec.ived: ll·JUL-1990 Cust(lller: 8uz.r · Rale19n I ~:eystor,e IO San,ples 6:i·(;(J:i 6J-Gv4 bj•,:>15 o3-<lvo 1,J-(;07 6j-(;(,ii Date Si.pied lo-JUL·i99il lo-JUL·l9% 16-JUL·l9% lo-JUL·l990 lb-JUL-1990 lo· JUL· l 9';,: I Custo,,er ID C-84-lriA C-18C-OS, C-23C·OSE C·32·0,,t FB TB ~,.ar -llru: t e rs I ----------------·······----·---·········-····------------···-·-··-·····-········---------------------------·-········-····-···· 8020 !sopropyl Ether ug/L (1.01) ;1,00 I I I I I I I I I I I I 8-02(1 SURROGATES Benzotrifluoride 8040 Phenol 2-Chlorophenol ~-N 1 t rc,phenol 2, 4· D iRiethf lpht:r1C• l 2, 4-(iich lorophcno 1 4·Chloro·3·•cthy lpr,anc i 2, 4, b· T richloropher,ol 2, 4· [<ir,i t rophenol 4·Nitrophenol 213,5,6-T~trlcnlorophenol 2-Me thy 1-4, 6-a rn1 trophi:r10 l Per1t ;chlurvpner1c. l 81)4:) 3IBliDG.:.Tts 2-F lu,:,rophc:riol 2, 4 ,6-Tr ibr0tiophcr,ol : Rei:overy 83.9 89.J ug/l 1. 91 lb,9 Us/l (1),5(,v <O.~,(M:• ug/L (1),5(1) \0,500 ug/L ~c :.((: (0.5(1(; ug/l \(1, S,)<j <0.500 Ugil 2. 7g {,!), ':,(I(! ug/l d.00 J.55 ug/L \1,0:) ,,1,0(; ugil \l.l~) ,1.00 ug/L \ 1. (J<j 1,8(, ug/L (1.00 'l.W ug/L : 1. (J(, \l .(10 ' hec~y·cry 63.6 70.: ' heco·v·e.ry 7:,,j (6.2 il.00 '1,(,0 <1.00 il.00 84.8 83.9 90.4 107 10. 7 J.98 4.38 ~ <(,.5VO ((1, ':..:)0 (0.500 Nf< ,,),S,iO <(i,500 5.00 NR iO, S,~) i(l.51)) 0.97'5 Nf< (0.500 (0. ~)O <.0.500 NR 0.518 (0.500 7.48 tf- 1.21 <.I.00 1.48 Nf< (I.IX, < 1.(1(; (1.00 Nf< I. 96 < I , 0,) 22.6 NR I. 77 (1 .(,) 91.2 Nf< ,1.00 (l.lJI) 122 Nf;· 6.24 ·;_ i ,1)(, <1 .01) rii li.4 :,4.ti 41), 7 NF; 132.S -,-, -. t:",Hr ix Int. Nf, I lo I I I I I I I I I I I I I I I I I I I I _1·nv1.r.11v Date rece1vea: 17-Jul·l'iW 5.oples Keystor,e ll oJ-(;('9 Date Sa•plec 17-JUL · 1990 Custoa,er ID C·loi:-OSE Parameter; Units 1)1)~ Isopropyl Ether ug/L ;1.00 802(, SIBROG/\TE S Benzotr i iluor 1de ,; Recc,very 9b.8 • 8()40 kner,ol ug/L 8.56 2-Cr,lorophcnol ug,: L 2(1.(1 i·N1tropnenol ug/L o. 7)1 214 · t i..att tr1"t lphenoi ug/L ~ 0. :',t)(.1 i 14·D1cnlorophenol ug/L 4,7S 4-Cnlor o· 3·R,e~ny lpher1c, 1 Uljil ~-. 5.:, :14,t.i~Tr1cnlorophenol ug/l 33,: 21 4-Gin1trophen0l ug/L 1.54 4-Ni tropr,er,ol ug/L -..l •1)0 2,3 15,6-Tetracnloropnenol ug/i.. l 5. i .i·Mfthyl·4 16-d1n1tropnenol ug;l ,1,00 r errt-ich loropheriGl ulj/ L :.1.00 8041) SUf(f;CJGA!ES ~-F luorophenol .. RecLi1rery 18.4 • i,4,6-Tribroroophcnol • F.eco·,·err oJ.3 63-1)1:i l 7-JUL · i 990 C·lbC·OSE ['lJl'.•LI CA TE (1.00 \1)0 9.76 21. '5 (0.5(u) :.(1,.::.i:1t1 :,,48 ... =: L, .• h_l 4).8 l. 77 ::.1.00 13. l 129 '1.00 50.1 61. 9 b3·011 6j•012 63-013 b3·014 l7·JUL·l'i9<) 17-JUL-19'!'0 17-JUL-1990 11-JUL · l'M:· C · 2(,C ·OSW C-2,C·QSE C·22C·OSW FB (1.00 \1.00 (1.00 (1.00 92.b 93.b 101 91.5 ,o.soo (0,51)) 3.50 (0.47: (1),500 1.6:-l.b5 <0.47: <:o.~.\JI) <0.5oo 10,5<)0 1.51 <.0,5(llj :0.50(; ((), 5(n) \(;. '7: <O .5i)(i .:_!). :".i):) 1. 77 ;_1),472 ((J.:'.;)(1 3.:)0 1. J9 ,.:i,,A' ,1.00 9.&, 3.83 ,.o. S4-! < 1. O(i ( l. :)!j {1.00 4,ij ,1.00 <1.W : 1 .,~:: 14.9 '.!.(•> 2.36 1 ·,(, • J..,' 3_;:,~ . 8.05 C:1.1)(1 n.,JO 11. 0 48 ., . ' <.l .((i (_1.(llJ :_(: 5!-4 24,b 41. l 15.0 Dllotea Out 3).0 :-6,j 62.J Diiutec Out I I I I I I I I I I I I I I I I I I I .,..j ·r,~.;. • l 7\,/ Date rec,1vea: 17-JUL-l 991) r-et:itN1C 1[1 [1at, Saopl,a CustOIIIH rn Vu¼ID:etcrs 8(1:;:'0 I sc,propy l E rncr 8')10 SURRtlG,HES Benz ut r i 1 l•.J,:,r ioe 804(, ~·henol 2-Chlc-r~•phHuJl :-N1tr•)pnenol 2, 4-L1.a1e tny lpnenol 214-Di~nlorophenol 4-Crilc,ro-2-•e thy lpheno ~ 2,4,6-Tr1chl0rophe~ol 2, 4-D uii trc,phenc,l 4-N 1 tr opher1L•l 213,5,b-Tetrichlorophenoi :-~cthyl-41b-din1trophenol ~·erit a,::1 lor0p:-um0l &)4(: SW>tlGA TES : -F luL•ropi1i::rn:d i 14 ,6-Tr 1::; r 0wopner,ol Ur11ts ugil ug/l ug/l ug/L ug/l uq;l ug/L ug1l Ug/L uq;L U•f t. ug/l ug/l ~ hecovery • f..ecov·ery eij-!)i5 l7-Jul -111/tj H, Cl.00 90.4 NR NR c,:i-016 id-JUL -i i91J C-19C-QSN :_ l, :),) ;:j,: <,.!) •. :'11)j ,0. :,1.1() ,·1),5(.;) <0.:~jij <1).5\JV 3.29 d ,1)0 '-1 ,i:,, d,00 q ,(;(1 (1.00 1 • (>0 6l.l ~.: .• 4 63-t)i(i 18-JUL -1 ;91) fB q ,(M) 03.t) <U.4 72 <tJ.472 : .::6 <0.472 ,,j,47: 2.64 (0.9~4 (0,<144 2'8.5 49.1 19.S j,94 4o.0 8l.o 6J-(,:1 16-JlJL-:991) TB <t.00 1(;7 Ni; NF, N, ~'R NR ~ NR NF- NR t;F NR If( NR Ni; I I I I I I I I I APPENDIX B I SUPPORT DOCUMENTATION I I I I I I I I I ---'------------. !9'1 _ ---·---------·-=~-~ c,·, ______ ., _____ ---------.... ·-------·· .. ____ _ ONOUlU-9':-t ff!~ =-~-~=:-=:~•-=jf~--~~-::,---~:-~ :~:::' '_~~~- tt·t --=:=__:.-~--~--~---=-------lC'I : .::c:c::=--·:·.=---··---·-· ·-·--•--·-····-···· ------··-----·---- -_jJ: ' _-: -----tr~ ---------·------·------·----------·--- tJJj/ 1j./ l'l"f' ?"~PP°IJ le! : l0llll40 ::d :11111111 ,,.. ----------· --. ·•·-.L .. -·--•·-. ----··• .. ---:-.-::~_-::::.-:-_:-..:~--- I' .. 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' .. : • r :rd :1ciJ·:,~=10:~i:z:: :x~:1 xnc;·:·c: xw;r·o1Moc·;-i1~~z11:tt:,~=:xn~~~ Ctt ·c : ~ gc, :lO)tl>dO ;:d :ntOll)j ~1CX3Bl\tt:tC\XYw~:, :poq111 !5=tl 0£-,~Y-:c ::! ;x:.iJ ·:t)~ :1acotqJ c:C·(~:·:o-~f~ I I 11 I I I - I I I I I I I I I I I :11a1110, I :aopnna :ruJnbJt I :11dns