NCD003200383_19900919_Koppers Co. Inc._FRBCERCLA SAP QAPP_Organic and Physical-Chemical Data Validation-OCR

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AWD
TECHNOLOGIES
PGH-90-MKL-343
DATE
TO
FROM
SUBJECT
overview
September 19, 1990
Mr. Robert S. Markwell
Program Manager -Environmental Services Beazer Materials and Services, Inc.
436 seventh Avenue
Pittsburgh, Pennsylvania 15219
Mark K. Lentz
AWD Technologies, Inc.
Organic and Physical/Chemical Data Validation
Keystone Environmental Job #M90-05.4, #M90-04.87 and #M90-05.105
The first set of samples for Beazer (sampled 5/01/90, #M90-05.4) contained 23 samples. These included: 19 soil samples and 1 rinsate blank. The first sample set also included 3 pairs of field duplicates. The second set of samples for Beazer (sampled 5/29/90, #M90-05. 105) contained 9 samples. These included: 9 soil samples 3 of which were duplicates. These samples sets were analyzed for isopropyl ether, and phenols. Isopropyl ether and phenols were analyzed by Method 8040. Pentachlorophenol was analyzed by EPA Method 8040. The third sample set (sampled 4/23/90, #M90-04.87) included 4 water samples which were also analyzed for isopropyl ether and phenols with the previously described analytical methods; in addition, the third sample set was analyzed by Method GC515 for pentachlorophenol.
summary
All elements
concern with
seriousness
Qualifiers
affected.
were successfully analyzed in all samples. Areas of respect to data usability are listed according to the of the problem. Note that the Summary of Data (Table 1) lists the specific samples which were
AWD Technologies, Inc. Penn Center West. Building Ill. Suite 400 Pittsburgh Pennsylvania 15276 Teleohone 412 788 2717 Telecooier 412 788 1316
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AWD Technologies, Inc.
PGH-90-MKL-343
Mr. Robert S. Markwell
Beazer Materials and Services, Inc.
September 19, 1990 -Page 2
Minor Issues
2,4-Dichlorophenol was
accompanied the #M90-05. 4
less than five times the
reported in the rinsate blank which
set of samples. Therefore, sample results
blank concentrations are qualified "U".
Notes
The #M90-05.4 of samples analyzed in accordance with Method 8040x,
the lab control blank had values reported for 2-chlorophenol and
2,4-dichlorophenol; the second set of samples analyzed in
accordance with Method 8040X had lab blank contamination of phenol,
2,4-dichlorophenol and 2-chlorophenol. Therefore, the samples
results less the five times these blank concentrations are
qualified ''U''. In addition, these were subtracted out of all the
affected samples on this work order based on the assumption that
this interference or contamination was throughout the entire set
of samples.
Control blank contamination subtraction was done by the
laboratory and is not considered proper by EPA guidelines.
Information Regarding Report Content
Table 1 is a summary of qua 1 if iers added to the laboratory's
results during data validation.
Attachments:
1.
2.
3 •
4 •
Glossary of data qualifier codes.
Data Summary. This includes:
a) All positive results with qualifier codes, if applicable;
b) All unusable detection limits qualified with an "R''; and
c) All estimated detection limits qualified with UJ or UL.
Appendix A -results as reported by the laboratory (no
corrections were made during data validation).
Appendix B -Support Documentation includes details to support
the statement in this report.
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AWD Technologies, Inc.
GLOSSARY OF DATA QUALIFIER CODES (ORGANIC)
CODES RELATING TO IDENTIFICATION
(confidence concerning presence or absence of compounds)
< = Not Detected. The associated number indicates approximate
sample concentration necessary to be detected.
U = Not detected substantially above the level reported in
laboratory or field blanks.
(NO CODE) = Confirmed Identification
R = Unreliable Result. Analyte may or may not be present in the
sample. Supporting data necessary to confirm result.
CODES RELATED TO QUANTITATION
(can be used for positive results and sample quantitation limits):
J = Analyte present.
precise.
Reported value may not be accurate or
UJ = Not detected. Quantitation
imprecise.
OTHER CODES
NA= Not Analyzed
limit may be inaccurate or
IM90-05.105 I TAdLE 1
SUMMARY OF DATA QUALIFIERs
SOIL SAMPLE BLANK CONTAMINATION I------------------------------------------------------------
SAMPLES AFFECTED
POSITIVE
RESULTS BIAS I ANALYTE ------------------------------------------------------------
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Phenol
2-Chlororphenol
2,4-Dichlororphenol
(X-5-LF/0-2') u HIGH
(X-5-LF/4-6') u HIGH
(X-5-LF/4-6') DUP u HIGH
(X-5-LF/8-10') u HIGH
(X-8-LF/0-2') u HIGH
(X-8-LF/0-2') DUP u HIGH
(X-8-LF/4-6') u HIGH
(X-8-LF/8-10') u HIGH
(X-5-LF/0-2') u HIGH
(X-5-LF/4-6') u HIGH
(X-5-LF/4-6') DUP u HIGH
(X-5-LF/8-10') u HIGH
(X-8-LF/0-2') DUP u HIGH
(X-8-LF/4-6') u HIGH
(X-8-LF/8-10') u HIGH
(X-5-LF/0-2') u HIGH
(X-5-LF/4-6') u HIGH
( X-8-LF /0-2') u HIGH
I ~MG-::,-,:,:: .. 4
r;.iE,LE l
.SUMMAR) GF DATA ~UAL!FIERs
I-------------------~~~~-~~~~~~-~~~~~-~~~~~~~~~=~~~-----------
FOS!TIVE
,~~~~~~~-------------~~~~~~~-~:~~~=~~----~~~~~=~------~~~~----
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'..:-Chloror ot,enol
(X-2:-LF/()-:' J
( >:-C:-LF/2-4' i
(;<:-t,-LF/0-·2·)
( ><-6-L F / 2--~, ' ·1
( ><-6-LF./5-7'
(\-17-LF/c-8')
IX-17-LF/6-S ) dup
(X-18-LF/2-4')
(X-JS-LF/4-6')
(_\-3-LF/0-2')
(Y-3-LF/2-4')
(X-6-LF/0-2')
(,:-t--LF/3-5')
(><-6-LF/5-7')
(X-18-LF /2-4')
(X-18-LF/4-c')
(X-21-Lr/'.2-4')
(X-21-LF/<l-6 1
)
(>:-::.:6-LF/2-4:)
( :•>26-LF/~-6.)
(Y-3S-CP/2-4.)
IX-35-CP/2-4') dup
( X-35-CP/6-8')
( ;~>~7-CP/2-4')
( A-37-CP/6-E.
(X-48-CP/:.;-4'
( ,:-4E--CP/8-l 0
(X-48-CP/8-10') dup
IJ
u
l!
\'
u
IJ
u
u
u
u ,_,
•_J
u
L,
u
u
u
u
u
l;
u
u
u
u
,_I
u
u
H !C-iH
HIGH
HIGH
HIGH
HIGH
HIGH
HIGH
HIGH
HIGH
HIGH
HIGH
HIGH
HIGH
HIGH
HIGH
HIGH
HIGH
HiGH
HIGH
HIGH
HIGH
HIGH
HIGH
HIGH
HIGH
HIGH
HIGH
H Ir..;;H
I AWO Technologies, Inc.
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I DATA SUMMARY FORMS
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NON CLP DATA FOR SAMPLES COLLECTED •l23/90
BEAZER -RALEIQH
Keyatone Environaental Job. • M90-04.17
Suiple No. STEAM
CLEANER
MUNICIPAL
WATER
RINSATE
BLANK
TB
--------------------------------------------------------------------------------------------------
COMPOUND ltnitll
--------------------------------------------------------------------------------------------------
GC515
Pentachlorophenol
8020
Ieopropyl Ether
eo,o
Phenol
2-Chlorophenol
2-Nitrophenol
2,4-Dimethylphenol
2,4-Dichlorophenol
4-Chloro-3-tnethylphenol
2,4,8-Trichlorophenol
2,4-0initrophenol
4-Nitrophenol
2,3,5,8-Tetrachlorophenol
2-Methyl-4,8-dinitrophenol
Pantachlorophenol
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
0.015
(1.00
<0.500
<0.500
<0.500
<0.500
<0.500
<0.500
<1.00
<1.00
<1.00
<1.00
<1. 00
(1.00
<0.010 NR NR
<1 .00 NR <1.00
(0,500 <0.500 NR
<0.500 <0.500 NR
<0.500 <0.500 NR
(0,500 <0.500 NR
<0.500 <0.500 NR
<0.500 <0.500 NR
< 1.00 <1.00 NR
< 1 .00 <1.00 HR
<1.00 <1.00 NR
<1.00 < 1 .00 HR
<1.00 <1.00 NR
<1.00 <1.00 HR
--------------------------------------------------------------------------------------------------
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NON CLP DATA FOR SAMPLES COLLECTED 5/29/90
BEAZER -RALEIGH
Keyatone Environmental Job. I M90-05.105
Sample No. X-5-LF
0-2·
X-5-LF
4-8'
X-5-LF
4-8' OUP
X-5-LF
8-10·
--------------------------------------------------------------------------------------------------
F1old Duplicates
COMPOUND Units
--------------------------------------------------------------------------------------------------
s9o11da at 103 ~c
8040X
Phenol
2-Chlorophenol
2-Nitrophenol
2,4-0imathylphenol
2,4-0ichlorophenol
4-Chloro-3-methylphenol
2,4,8-Trichlorophenol
2,4-Dinitrophenol
4-Nitrophenol
2,3,5,8-Tetrachlorophenol
2-Methyl-4,8-dinitrophenol
Pentachlorophenol
s
ug/Kg
ug/Kg
ug/Kg
ug/Kg
ug/Kg
ug/Kg
ug/Kg
ug/Kg
ug/Kg
ug/Kg
ug/Kg
ug/Kg
85.3
180 u
313 u
<58.5
154 u
<58.5
<58.5
<117
< 117
< 117
< 117
< 117
< 117
89.3 89.5 95.5
177 u 308 u 184 U
222 u 327 U 243 U
<58 <58 <52.5
140 u <58 <52.5
<58 <58 <52.5
<58 <58 <52.5
<112 < 112 < 105
< 112 <112 < 105
<112 < 112 < 105
<112 <112 < 105
< 112 < 112 < 105
< 112 < 112 < 105
--------------------------------------------------------------------------------------------------
Sa.mp1e No. X-8-LF
4-8'
X-8-LF
8-10'
X-8-LF
0-2·
X-8-LF
0-2'DUP
------------------------------------------------------------------------------------------------
Field Dupl icatea
COMPOUND Unit&
------------------------------------------------------------------------------------------------
SSolida at 103 ·c s 92.8 91. 4 90.1 90.4
8040X
Phenol ug/Kg 282 u 239 u 178 u 138 U
2-Chlorophenol ug/Kg 310 u 152 u <55.5 117 u
2-N1trapheno1 ug/Kg <54 <54.5 <55.5 < 55. 5
2,4-0imethylphenol ug/Kg <54 <54.5 132 U <55.5
2,4-0ichloraphenol ug/Kg <54 <54.5 (55.5 <55.5
4-Chloro-3-methylphenol ug/Kg <54 <54.5 <55.5 <55.5
2,4,G-Tr1chlorophenol ug/Kg < 108 < 109 < 111 < 111
2,4-Dinitrophenol ug/Kg <108 <109 <111 < 111
4-Nitrophenol ug/Kg < 108 < 109 <111 < 111
2,3,5,8-Tetrachlorophenol ug/Kg <108 <109 <111 <111
2-Methyl-4,8-dinitrophenol ug/Kg (108 < 109 <111 < 111
Pentachlorophanol ug/Kg <108 <109 < 111 <111
--------------------------------------------------------------------------------------------------
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I NON CLP DATA FOR SAMPLES COLLECTED 5/01/90
BEAZER -RALEIGH
Keystone Environ1ental Job. I M90-05.l
I
Sample No.
COMPOUND Units
X-3LF
0-2'
X-3LF
2-,·
X ·6LF
0-2'
HLF
3-5'
1-6 LF
5-7'
1·17FL
l-6' I
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sSolids at 103 ·c s 91.7 91.5 93.9 NR 91.1 NR
80201
Isopropyl Ether ug/Kg NR <109 NR NR (109 MR
80401
Pheno I ug/ Kg 66. I < s,. 5 (53.0 (55.0 < 54. 5 (58.0
2-Chlorophenol ug/Kg 1070 U 1830 U 1650 U 486 U l61 U < 58. 0
2-Nitrophenol ug/Kg (54.5 < s,. 5 58.8 (55.0 (54.5 707
2,l-Diiethylphenol ug/Kg (5l.5 <5l.5 < 53. 0 <55.0 <5l.5 <58.0
2,l-Oichlorophenol ug/Kg 80.9 U 600 U 763 U 90, 7 U 525 U <58.0
l-Chloro-3-1ethylphenol ug/Kg (5l.5 (54. 5 < 53. 0 (55.0 <54.5 <58.0
2,,,6-Trichlorophenol ug/Kg 138 115 112 < 110 151 < 116
2.l-Oinitrophenol ug/Kg <109 < I 09 165 <110 (109 < 116
l-Nitrophenol ug/ Kg (109 < 109 (106 < 110 < 109 <116
2,3,5,6-Tetrachlorophenol ug/ Kg (109 < 109 (106 < 110 (109 < 116
2-Methyl-l,6-dinitrophenol ug/ Kg < 109 ( 109 <106 < 110 < 109 < 116
Pentachlorophenol ug/ Kg < I 09 < I 09 <106 ( 110 (109 4880
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NON CLP DATA FOR SAMPLES COLLECTED 5/01/90
BEAZER -RALEIGH
Keystone Environmental Job. I M90·05.4
Suple No. X-17Lf X-17LF OUP H8Lf H8Lf X·21lf Hllf
6-8' 6-6' 2-4' 4-6' 2~4' 4-6'
--------------------------------------------------------------------------------------------
COMPOUND Units --------------------------------------------------------------------------------------------------------------------
sSolids at 103 ·c s 91 90.5 81. 1 81.5 90.4 65.7
8020X
Jsopropyl Ether ug/ Kg < 110 < 111 NR NR NR NR
6040X
Phenol ug/Kg < 5 5. 0 m.o (61.5 < 61 . 5 < 60. 5 <58.5
2-Chlorophenol ug/ Kg 340 U 356 U 1080 U 7 37 U < 60. 5 (58.5
2-Nitrophenol ug/Kg m.o < 55. 0 75.6 (61.5 < 60. 5 (58.5
2,4-0imethylphenol ug/Kg (55.0 < 55. 0 (61.5 <61.5 < 60. 5 (58.5
2,4-0ichlorophenol ug/Kg m.o < 55. 0 1120 1040 U 941 U 500 U
4-Chloro-3-methylphenol ug/Kg m.o m.o < 61 . 5 <61.5 < 60. 5 < 56. 5
2,4,6-Trichlorophenol ug/Kg 111 136 1120 175 186 141
2,4-0initrophenol ug/Kg < 110 < 110 <61.5 (123 (121 < 117
4-Nitrophenol ug/ Kg < 110 <110 152 (123 < 121 < 117
2,3,5,6-Tetrachlorophenol ug/Kg < 110 < 110 (123 (123 < 121 < 117
2-Methyl-4,6-dinitrophenol ug/Kg < 110 < 110 < 113 (123 ( 121 < 117
Pentachlorophenol ug/Kg < 110 < 110 < 113 692 7430 251
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I NON CLP DATA FOR SAMPLES COLLECTED 5/01/90
BEAZER -RALEIGH
1 Keystone Environmental Job. I M90-05.4
Sa~ple No.
I
I COMPOUND Units
I 1s01 ids at 103 ·c I
8010!
Isopropyl Ether ug/Kg
I
8040!
I Phenol u9/lg
2-Chlorophenol ug/!g
1-Nitrophenol ug/!g
I 2,4-Dimethylphenol ug/Kg
2,4-Dichlorophenol ug /Kg
4-Chloro-3-methylphenol ug/!g
2,4,6-Trichlorophenol ug/Kg
I 1,4-0initrophenol ug/Kg
4-Nitrophenol ug/Kg
2,3,5,6-Tetrachlorophenol ug/!g
I 2-Methyl-4,6-dinitrophenol ug/!g
Pentachlorophenol ug/Kg
X-16Lf
2-4'
X-26LF
4-6'
Field Duplicates
NR 87.6
NR NR
< 59. 5 < 51. 0
< 59. 5 (57.0
< 59. 5 (57. 0
(59.5 ( 5 7. 0
398.0 94.7
< 59. 5 < 51. 0
132 ( 114
( 119 ( 114
< 119 ( 1 14
( 11; ( 114
< 119 < 114
248 647
l-35CP X-l5CP dup
H' 2-4'
Field Duplicates
NR NR
NR NR
<62 < 61
<62 (61
< 62 < 61
< 62 ( 61
401 196
< 62 < 61
224 153
( 114 (122
i 124 (112
< 124 (122
(124 < 1 22
2870 907
X-35CP
6-8'
89.6
< 111
< 56
(56
(56
< 56
230
(56
253
<112
< 112
( 112
< 11 2
< 1 11
X-37CP
H'
NR
NR
< 61
< 61
( 61
(61
334
(61
330
(122
(122
< 112
<122
213
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I NON CLP DATA FOR SAMPLES COLLECTED 5/01/90
BEAZER -RALEIGH
I Keystone Environmental Job. I M90-05.4
Suple No. X-37CP X-48CP i-48CP X-48CP X R!NSATE 18
I 6-8' 2-4' 8-10' 8-10'0UP BLANK
----------------------------------------------------------------------------------------------------------------------------
I Fie Id Duplicates Field Duplicates
COMPOUND Units
----------------------------------------------------------------------------------------------------------------------------
I ssolids at 103 ·c s 84 NR 82. I 80.4 NR NR
8020
I Isopropyl Ether ug/ Kg HR HR HR HR (1 < I
8040
I Phenol ug/Kg HR HR HR HR (0.5 NR
2-Ch I oropheno I ug/ Kg HR NR NR NR (0.5 NR
2-Nitrophenol ug/Kg HR NR HR HR (0.5 NR
I 2,4-Dimethylphenol ug/Kg NR NR HR HR (0.5 NR
2,4-Dichlorophenol ug/Kg HR NR NR HR 2.55 HR
4-Chloro-3-aethylphenol ug/Kg HR HR NR NR < 0. 5 NR
2.4,6-Trichlorophenol ug/Kg NR NR HR NR ( 1 NR
I 2,4-0initrophenol ug/Kg HR NR HR HR ( 1 NR
4-Nitrophenol ug/Kg NR NR HR NR < I NR
2,3,5,6-Tetrachlorophenol ug/Kg HR NR HR NR ( 1 NR
I 2-Nethyl-4,6-dinitrophenol ug/Kg HR NR NR NR ( 1 NR
Pentachlorophenol ug/Kg NR NR NR NR (1 NR
I 8020!
Isopropyl Ether ug/Kg 1062 NR NR NR NR NR
I 8040!
Phenol ug/ Kg (59.5 (62.5 < 61 (62 NR NR
I 2-Chlorophenol ug/Kg (59,5 < 62. 5 < 61 < 62 MR NR
2-Nitrophenol ug/Kg <59.5 <62.5 < 61 < 62 NR NR
2,4-0imethylphenol ug/Kg (59.5 (62.5 <6 I (62 NR NR
I 2,4-Dichlorophenol ug/Kg 197 470 306 433 NR NR
4-Chloro-3-methylphenol ug/Kg < 59. 5 < 62. 5 < 61 <62 MR NR
2,4,6-Trichlorophenol ug/Kg 16 7 16 5 140 159 NR NR
I 2,4-Dinitrophenol ug/Kg < 119 (125 (122 (124 NR HR
4-Nitrophenol ug/Kg < 119 <125 (122 (124 HR NR
2,3,5,6-Tetrachlorophenol ug/Kg ( 119 721 < 122 <124 NR NR
2-Methyl-4,6-dinitrophenol ug/Kg < 1 I 9 (125 (122 (124 NR NR
I Pentachlorophenol ug/Kg < 119 191000 779 263 NR NR
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I AWD Technologies, Inc.
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I RESULTS AS REPORTED BY THE LABORATORY
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1£/Ston, lu
D1H Sapi,d
CustOlo.r it,
GCS15
P,1nncnJ,;ropnenol
GCS 1 ~ 51.H,f,;A TE;
T rioruaopheno l
802(;
lsopropyl Etner
8i>2<) ~TES
&enzotr1iluor1ae
00W
Phenol
2-Chloropher,oi
2·Ni trophenol
2, 4-Dillethy lpher,ol
2,4-01chlorophenol
4-Chloro-3-1ethylphert0l
:,4,b·Trichloropnenol
2, 4-0ir,i tropheno I
4·Nitrophenol
2,J,5,6-Tetr1chlorophenol
2-Nethyl-4,6-d1n1trop/lenol
Pent•chlorophenol
8044) 51.RROOATES
:-Fluorophenol
2,4,6-Tribroaophenol ~~-. ~.-~
~ ~· '
!JiJil
:Reco,ery
U(J/L
= ~ecvvery
ug/L
ug,'L
~/L
ug/L
ugil
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Sapl,1s
67-1Jl)j
:J-~·199\)
STEAi! CLEANEF.
v.015
96.5
:.L((I
98.J
o. 5,:,:,
;J;,5')j
,:0,500
,o. ~)
'.0,500
(0.500
< 1.00
(1.00
(1.00
11.00
(1.00
(1.00
1 Recovery • 34.4
1 Recovuy', 56.:
C
f~~~~~:r Ji-·
97.,»4
:J-APR-19'11)
i'IUNICll'AL IIATEF,
·:0.010
1 v5
(1.00
10-4
,0.500
,,).5w
,0,500
10.500
,0.500
(0.500
(1.00
(1 .oo
(1.00
(1.00
(1.00
(1.00
73.4
7'1.5
Job nae: J<!Olj-,)4,87
87-M
:J-A,,i;-I 'I'll)
~!rlSATE &LA/t'.
ff;
tfl
,fl
tf1
:o.soo
(0.500
.0.500
{0.5((,
,0.500
<.0.500
(1.00
d.00
(1.00
(1.00
(1.00
(1.00
60.2
64.~
87-0(Jb
:J-i.;;-1m
T&
tf1
tf1
(1.00
96.,
tfl
tfi
lfi
lfi
tfl
,fl
tfl
lfi
tf1
lfi
tfl
!fl
tf1
tf1
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1··-
1
~-elstor,c ~Ll
One 5,cplea
Cust01i,2r l[:
,Solids at 103'(
80401
Pnenul
2-ChJorophrnol
2-Ni tropnenol
2, 4-Daethy lpher,o!
214-[J1ch!orophenol
4·Ch!oro-3--.thy!pnenol
2,4,o-TricnlDropnenol
214·Drn1 tropher,ol
4-N1trophen0l
2,3,5,6-TEtrachloroµhtnol
2-l'le t~iy l -4 1b-d1r1i t ropneri0l
~·en ta chloroprieno l
&.:µ@ Wf;If! 3e TE 5
2-F ll.ioropnernJl
2, 416-1 r 1or0i11~•µ11€r,0l
'• '
ug;i.g
ug;,.g
ugi~g
ug;~g
ug;Kg
ug/•g
ug;Kg
ug/1\g
ug;Kg
ug/t.g
ugi,.g
ug;Kg
,, ~eco;.·e:r;· • ,, h"c.c,:r•ery .
10:,-i:,,;~ rc:.-;;;A
29-P1A1-1,?"ft) :"1-~Y -19S\:
1-5-LF 0·2· i-5-Lf A-o·
85.3 89,j
lb(I I 77
J1] i22
;58, :. \5ti.(i
l:-4 140 ,.:.a.:. \:,6. (j
<.5-8.~ (:,6.(;
'117 ~ 112
;Jli ( 112
'-.117 \112
\l 17 ;_ 11::
,.1 t 7 di2
,.11? q iL
5e.8 ~9.7
68.1 e9 .r.,
1(1~•(;.;:,,:
:--;·-,1A,-199:)
-~ -5-LF !-6'
DUPLICA,E
8'7.5
J,x,
32i
,~.(1
<::io.(1
<56,t)
\~,(I
(11,:
,.11:
\112
\I le
il 1:
,.11:
,:,J.~
":(1,8
!C':--r}(;o l(r-5-,:;(:7
:-s-r~,-19% ~'9-~r-1~·9t)
A-5-LF 6-10' X-8-LF 0-2'
95.5 90, I
lb4 17b
243 ,i::-r r \,.~J. ,..,
(52,5 00 0 \,J.J,•J
(5~.:. 132
,52.5 \5.5.:.
<52.5 •' C"C' 0 \ .J . .J ,._.
(1('5 ( l l l
<105 <.111
<.105 <.111
\105 (111
<I0.5 <_ 111
<HIJ ;._lil
~~). 1) 38.S
7(:, J 71.(1
1(15-,)(:6
:--;-MA'r-1S"W
,-8-Lf (,-:·
c•UPLiCATE
90.4
138
117
\S.5.5
{55.5
,55.5
<.55.5
(Ill
<111
<111
.:111
dll
<.111
"4.5
62.2
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I
I
I
il•J\Ji-l'!',;·.~
Keysrnr.e I[;
One Saopt,,;
Cust011tcr ![,
Poraaeters 1Jr,1ts
S,aple:
11)5-(11/1
:,-IIAY-199<)
l-8-Lf ~-i,'
Lust<iGler: beazer -~·ale1gn
l (;:, -l:;1 j
29-~A\-l'f',<;
,1.-8-LF 8-i(i'
-------------------------------------------------------------------------------------------------------------------------------
,Solids at l(,3'C
80401
Phenol
2-Cnlor o;>,rnoi
2-r11 tropr-,cru:il
2, 4-Di.nu::t11.,.-lphe11i:• l
2, 4-Dicrilurophenol
4-Chlori:i-j•&ietny lphi:ftC•l
2,4,o-TrtCillorophenol
2, 4-[11r,1 tropt-1enol
4-Ni trophcr,ol
2,3,5,6-T~tricnlor~pnEnGl
~-Me thy 1-4 10-c:1ini tropner1ol
l=i1:.nt1cn ic,r0~ner1ol
8".)40X ~ii~TES
,-Fluoropn,nol
2, 4, b-Tr 1t,rorr1L•~i1€r10l
., •
ug,lg
ug/kg
ug/,g
cg/Kg
ug;Kg
ug;i.g
,9;,g
ug;,.g
,,g;,.g
ug/,.g
ug,sg
ug.-·,.g
l Ri:cu·.-ery
'• Ri:i:O','H.7' •
92,b
:6:
~10
•.54.0
z54.::;
,.54,1:,
;_:'-4.(;
::;oo
;,lOt,
<106
.,.1::;;;
;_ 11)8
'· l t.:0
5.;,:
61.(•
91.4
;_54,~
:::,4 -~·
·, 1<)9
:_ 1 (:;
1.1(19
:JC~
; 11)9
:_ l (;~
45, l
bo.E
- -•· -- -
.. ~ .._:. n· ,__ .,, :--• •,-• ! '
~ l..• ~!.
. .
-·' ,·-..,, .:; ,,. ....
"
(" ,:-
~~ ,f~
oi':-.....
,.
• , r _, t . ~. , .. ; r ·' r.
-
L .. 'Ip . J, 1-.° L.l
-
. ' .,
,-'-' ,-'"-~ I +., ;.• r 1
' . '. i:· ,.,
►. ' .
-
.. , ...
"·
_,
---
o, <C, ., .... <..: ,. ,:. ►,-
~-· .f"-" t I ,: , ..
·' :.◄ ' ~-~: :: ): = ,, . ., '~'-. ~ -· ,,. •,·, ~~ ~t: ,:, . '-;
e> ,i ·1~-, r-n,
:-:, ,, ' "t. r_, r, .-_
T.• ·' ,, .
"'
..
--
<· -~ .,., ,. .-, :-r n, ,.:
,., .. :.,
IT, "T:, ··• _, :.i ,, •
;.~ ~;
:-, ·~:
- --
" '
i,',
' •1•
-
, .
" "
-
t(• •· .. ~;: l-j•
.. . ,
-
,i
..
I
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I
Date received: Z·IIAY-1990
,.e1stone ![:
D.re Sapled
Cust.;aer ID
~'irilin?tUS
XSolids it l•i3'C
80:\JX
!s,ipropyl tth.r
8020l 31.AAOGIITES
Bcrizutr1fluor1dc
8(.:4(,X
Phen,iJ
2-Chlvropher,-:;l
:-N1trophenoi
2,4-Daetnylpr .. moi
:,4-Dichlvropricnvl
4-Chlorc,· 3-aeth)· lpne;,,:;l
2,4,b-Tricnloropnenol
1, 4-Du,1 trophenol
4·N1tropnenol
2,3,5,b·Tetrachlorophenol
2-"ethy l-416-dir.1 tropher,ol
~entachlorophenol
004-01 ~TES
2-F luorophenol
2,4,b·Trior .. ophenol
ur11 ts
ugj•g
l Ri?covery
ug/kg
ug/•g
ug;lg
ug/Kg
ugikg
ug/i.g
ug/kg
ug/•g
ugikg
ug/kg
ug,il\g
ug/kg
: Recovery
l Recovery
4-0(Jj
1-IIAl·l'i'IO
l·3Lf :)-2·
q1, 7
i<,. 1
1070
,54 .. 5
<54.!
8').9
(54.5
138
c,.oq
( 11}9
: l 09
;jl)q
(10'1
58.5
72.1
Cws,.:.,r: Beazer -,,leigh
4-004 4-005
HleY-1990 l ·IIAY-19'1<)
X·3LF 2·4' X·bLF o-2'
10'1
~5-4.:':,
~54.:,
~.54. 5
ll5
<J0'1
'10'1
<IO'i
\109
;Ji)q
59.2
b8.8
93.,
lill
<53.o
lb50
5a.a
,:Sj,(,
;i,J
(~.!)
112
165
;)OI,
(I/JI,
(!Ob
(106
59.1
85.0
J,:;o nue: lflll-ll5,4
4-006
1·11Ai·l9'1<)
X·oLF 3-5'
NR
lill
,55.0
4&
(55.0
155.0
90. 7
(S5.(I
( 110
(110
(110
,110
\ 110
(110
4-4.3
74,0
4-fX,7
l-llAY-1990
X-blf 5· 7'
q1,4
(11)'1
111
,54,5
461
(54.5
<54.S
525
(.54.S
lSI,
(10'1
(10'1
(109
(10'1
(10'1
42,0
b-4.b
4·({J6
l ·IIA!·:i'%
l·17FL 4-b'
t4i
If<
If:
<~-~
<58.C
.. 707
?t_ (56.0
t 158.u
(58.0
(I lb
<llb
( l lb
(llt:
'116
488(;
37.l
b2.2
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1·
I
.· •r ..
0,te rece1vea: :-11Av-1m
~c-;stur,c IL 4-(1;~ 4-(11:J 4-,),1 4-1J1: 4-013 4-:) I 4
Date 5..,pJea 1-111\1-19% ,-AAY-199(; ,-l'IAV·:990 l·l'!Ar·l'190 HIAY· 1990 l ·AAV· ,i'l<i
Custu1oer ID :...-17rL 0·8' .J.-17fL. 1·18fl 2-4 l·l8FL 4-b' 1·2lfl 2·4' X<:1Fl !-0·
DUPLICATE o·8'
~ird.AICtUS UT1i t;
·-----------------------------------------------------------------------------------------------------------------------------
?Solids it 103'C ' l'LI) %" .. ~. 81.5 tf( ~.7
00~1
[sopropyl Ether ugil<.g a:110 \Ill ~ ~ ~ If(
0020X SIM<OGATES
8en2otr1fluor1ae I ~ecovery 105 102 ~ ~ ttl ~
8v4DX
Phenol ug;l<.g ,55,1) :.55.0 (61 .s (61.S (60,5 <58.S
2-Chlorophencl ug!,.,i j4() J5o 1080 737 (60,5 <56.S
2-Nitrophenol ug/1<.g ,55.0 ,55,0 75.b (bl .5 (60,5 (58.5
214-0aethylphenol ug/Kg (55,(; <55.0 <"bl.S {bl.5 (60,5 ;t (58.5
2,4-0ichlcrophenol ugil<.g ,:55,0 \55,0 II~ 1040 941 < 500
4-Chloro-3-1ethylphencl ug/K,i :.55.(1 <~~o ~.bl. 5 <61.5 (60,5 <58.5
21416-Tr1chlorophenol ug/1<.g 111 136 1120 175 186 141
214-0initropnenol ug/1g ,w, '110 <61.S \123 (121 i, J 17
4-N1 trophenol u911<.g ;.110 \110 152 <123 ,121 ( 117
213,S1b-Tetnchloropher,ol ug/1<.g mo q l(; (123 <123 (121 (117
2·"•thyl·41b·d1n1trophenol u911<.g (110 \110 ,123 '123 <121 \117
eer,hcnloropher,ol ug/,.g ,110 <11◊ ,.123 692 7430 = .......
8040X 51.H((JGATES
2-Fluoropnenol % Recovery 37.0 41.b bJ,b 55.8 61.7 b.3.~
2,4,b·Tribro,,ophenol : ~ecovery ~.7 67 ,'j 80.6 68.9 78.2 78.j
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,. . .,. ..
ScMtry of Ar,il1t1c.l Results
>.e/stone ![, 4-,:;l:, 4·1_;lo 4-0P 4·018 4-(:1 q 4-o.:,;
D,te S..-pl,;o l -~1-1 '/91) 1-11\Al'-19~1) l·~Ai-19'10 l -'1A! • l 99t) HIAY-1990 HIAY'l~i
Custu11iH ID A·26FL ~-4· ,·:bf, 4·o' ,·:uP 2·4 i · 3'5CP X·J<~ b·B· X-jiC~· :-!·
:-4 O!J:LICATE
Paraeter; Ur1l t:i
------------------------------------------------------------------------------------------------------------------------------
lSohds it ;03'C l Nh 87.o rfi ti( 8'U, r;f;
80::0X
lsvpropyl Ether ug/~g NR ti( NR NR <l 12 ~
8020X Sl.flf<OGATES
Benzotr1iluvr1de : Recovery Nii NR NR NR 98,0 NR
804-0X
Phenol ugi~g \S9.5 :..57.0 •.b2.0 (61,0 (56.0 (61,0
2-Chlorophenol ug,'Kg (59.5 \57,0 \62.0 (61.0 <56,0 (61.0
;:-Mi trophenol ug/kg ,5~.5 ,Si.I) :6i.O (61.0 <56.0 { (61,0
2,4-Daethylphenol ug,'Kg ,:59,5 (57.0 (62.(; (61,0 <56,0 ,. (61,0
;:,4-0ichlorophenol ugikg 398 94.7 ¼l 1% 2)) 334
4-Chloro·3·1ethylpnenol ug/~.g .:.59.S (5'7,1) :..62.0 <.61.0 ,56.0 <61.:;
2,4,6-Trichlvrophenol ug/kg 1:r. , 114 ~4 153 :;53 J30
2,4-Dmi tropher,ol ug;lg (119 <.114 (124 (1~ < 112 <12:
4·N1trophenol ugikg (l 19 ( l 14 (124 (122 (112 (l:2
2, 3,5,6· T etr;chlorophe;,ol Ug/!.g ,119 '-114 <124 <122 !.112 <122
:-Metnyl·4,6·dinitrophenol ug;Kg '119 '114 , 124 ,.122 <112 d~
Pcr1 tact-rlo r upher1~ 1 u~/i.g 248 o47 ~7:) '1(;7 (112 213
8040 ! su;1lOOA TES I ::-Fluoropnenol l Recovery bl·.i 46,8 54,5 1,8,J 47,8 oJ.J
2,4,6·Tribroaophenol l ~ecovery BO~U b 7 .3 67,J 79. 1 b2.2 87.5
.-
.,
-< C.1 -< I· r
,:,
-- ----
;~• .::,
~ .. n ~-~
~ ~
C C. C. L'. ,· ~~ ~ .::. '° ~ '!.' '('. <f:1 ;•
OIL:. o.C\ ..:.
r.· .. ,
-.>
~-,,., :_;:: r .• ~~ ~.,: r,, f,
- -
-o ·-,!: ;; ,, ..... ' -=· .....
r-C ,-. C:,:.
I, r., t.• t.\
,_,, ·-"
,..
t ·' •
u·
i-:-Cr ►. , .!
..::-
,:, •·
-
...... _ ,.
,.,
-- --- -
a, C f .J l ' I. t-,1 I• J
..;.I' t J :Z ... .._.. ., ....
,., ... ,: T') ~ ' ~ -:: "~ ;, .._,-zr·,,.
• •.l'f .... t-:1 1•· ,.._ .....
.J -<· ...,.. a-.:., -·• •,y r' <r) ~J n, . ,~ ·-... -~ .... ... ~; ": .-; ~; '--' :: ·_;,
i:, ,.
" <• ..,
';:T '" ~ -:, ;:=,
<•
:J ,_.
~
~ .,
C• T•
' "
~ C. ~ ~
C• :,· ,:"I ~ " ~ ~ ,, i;
C ._._ C I'". I: r.'" C <: i.; (; C ' C 'P. ,,:_, "':, ie . .,c of'.~ ~'. ,('I .,,:, -f.' '(J ':!::'
r , ..
C.' "' a,
Q
ff:' • ·' tJI ~ •· =· '' •:•
C
...
C• •J.• .,_, C ,
~fl 1:•
~
-
...
u•
'.
t;,
--
,-, :.:~
~
"
., <..
··I 3 I·.· r-, :i:: ,. ,
(.• ---·
~
t:. , r I-. } .
1:., --<
~ --
1.:" :;"" ~ -~ :~ it:'. ·-< .' ,-. .. , ·" ..
-
0
n,
;.
·>·
r,
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: '-JIJN-; 'f1\j
k.ey;t0r1E ID
S.u,plrng P,nr,t
Customer i[;
Para•eters
lSolias H l(1J~C
81)40X
Pnenol
2-Chlc,ropner,ol
:-Ni trc,pr,,r,,il
::, 4-Di,cthy lprn:r,v l
i, 4-D1chlorc,phmol
4-Cnloro-3-metny lph,n,:,l
2,4 16-fri,:nl,iropncnol
2, 4-Diri1 t rophF,c•l
4-N1 tr,iphar,ol
i, 3, 5,6-T etr a::r1l0rc,pth:i1Gl
i·Pleth;· l -4, o-orn1 t rc,pner,c,l
~e;-it ~ ch l c,r c,pr,er1,:; l
8#)1 SUh'fi-QG.; f E :i
2-F luoropt'1HnJl
i, 416-Tr iorc,mop:1!:1,c,l
'
ug/1.g
ug/f.g
ug;lg
Lig/1.g
ug;~g
u~·,.g
Lliji~g
c-;;,.g
ug/Kg
ug/t.g
ug:',; 9
ug;, g
• ~-=c~•--!:r-;
• F,c,:i;·,·c.r 1-
10':,· ;:,-.;1 ~;;_oc
LAf BLA;i!-.
NR
s· 1 • o
L·O:,
C, , ~.-.,.11), l}
!4i
;,:.;),;)
<5(;,i}
\ l(M)
,:1(1(1
, 1 ,x,
:J(rt)
'.)(J;)
".!(a;
:~). 7
·,.-. '• IV,
l 1/:,-:;{,i
i;A _QC
Li4C-CONTRJi.
5~1'1Vi.E
t~:
48. 1 ., • j4,9 . , •
NR
~;;
NR
82.3 ,
NR
NFi
s:.:: ,, •
Ni:
NE
-:'8, ·> " '
:7.o
6t.."?
10:.-:::1:
QA_QC
1. ·8-LF 4-o' '15[1
9j,4 NR NF;
Rec. NF; 51).2 ' Rec. 58.9 ' R,c .
Rac . ti' 47, 1 ' Rec. 5:'. I ' Rec,
NF; NR NR
tf; NR Nfi
tf; NR Ml
Rec, NF 6').4 i Rec. 71.6 . , Rec . • Nf,:· NR tlR
rfi NR NR Rec, NR 6-5. 7 ., Rac. 7:',, 1 ., R,c. • • NF tlR t1h:
NR NR NR
E2c. ,~ 64.(1' Rae. 73. 7 , R,,:.
NR 48,1) 51.3
N;, o:,, 9 74.6
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~-IIAY-I 9'IO
D.ite received: :-IIAY-1990
keystone ID
Sapling Point
Custoaer lD
80201
lsopropyJ Ether
80201 SIMOGA TES
Ben2otrifluor1de
8(/4/JX
Phenol
2-Chlorophenol
Z-NitrophtnoJ
2,4-Dilethylphenol
2,4-D1chloropllenol
4-Chloro-J-oethylphenol
21411,-Trichlorophenol
2,4-Dinitrophenol
4-Nitropllenol
2,J,S,1,-Tetrichlorophcnol
2-Nethyl-4,6-dinitrophenol
Pentichlorophenol
80401 51.JlROOATES
2-F luorophenol
2,4,b-Tribroaophenol
ugiL
I Recovery
ug/kg
ug/kg
ug,ikg
ug/kg
ug/kg
ug/Kg
ug/kg
ug/kg
ug/Kg
ug/kg
ug/kg
ug/kg
% Recovery
I Recovery
Saples
4-(,()l
ilA_OC
LA& BL.tt
,1.00
Ill
,su.u
511
150.0
<Sv.u
194
(50.0
(100
(100
<100
(100
(100
<100
49,S
57.9
S1Miry ot llA/OC Results
Custoaer: Seizer -Rile1gh
4-002
QA_OC
LA& COOTROL SAIJILE
11)9 I Rec,
100
~-5 I Rec.
bl .0 I Rec.
lfl
tfl
If!
1,7,J I Rec.
lfl
tf(
80.0 % Rec.
lfl
If!
74,b I Rec.
51.7
74.4
Job nae: "90-05.4
4-021
llA_OC
X·J7CP 2-4' 115
lfl
lfl
65,J I Rec.
1>5.8 I Rec.
lfl
If!
lfl
73.9 I Rec.
lfl
If!
80,2 % Rec.
lfl
If!
SJ.I, l Rec,
58.4
80.4
4-022
llA_OC
X-J7CP 2-4' lt'ill
lfl
lfl
68. 7 I Rte.
70.0 I Rec.
If!
lfl ::
If! ~
75.6·% Rec.
lfl
If!
n.1, % Rec.
If'<
If!
78.2 I Rec.
60.1
79.S
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AWD
TtCIINOUlGIES
PGH-90-DAL-350
DATE
TO
FROM
SUBJECT
overview
September 19, 1990
Mr. Robert S. Markwell
Program Manager -Environmental Services
Beazer Materials and Services, Inc.
436 Seventh Avenue
Pittsburgh, Pennsylvania 15219
David A. Lang
AWD Technologies, Inc.
Organic Data Validation
Keystone Environmental Work Order No. M90-06.142
The set of samples for Beazer (sampled 6/28/90) contained four
solid samples. -The samples were analyzed for phenols by U.S. EPA
Method 8040.
summary
All elements were successfully analyzed in all samples. Areas of
concern with respect to data usability are listed according to the
seriousness
Qualifiers
affected.
of the problem. Note that the Summary of Data
(Table 1) 1 ists · the specific samples which were
These include:
Minor Issues
The surrogate spike recovery for pentachlorophenol was low.
Therefore, the results for the associated sample, CEMENT, were
qualified "J", estimated. Similarly, detection limits for the
associated sample, CEMENT, were qualified "UJ", estimated.
Notes
2-Chlorophenol was detected in a laboratory blank. This
concentration was then subtracted out for other sample results.
The practice of subtracting out to adjust for blank contamination
is not consistent with U.S. EPA methodology.
The data were reviewed according to the National Functional
Guidelines for Evaluating Organic Analyses. The text of this
report addresses only those problems affecting usability.
AWD Technologies, Inc. Penn Center West Building Ill. Suite 400 Pittsburgh Pennsylvania 15276 Telephone [phone] Telecopier 412 788 1316
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AWO Technologies, Inc.
PGH-90-DAL-350
Mr. Robert S. Markwell
Beazer Materials and Services, Inc.
September 19, 1990 -Page 2
Information Regarding Report content
Table 1 is a summary of qualifiers added to the laboratory's
results during data validation.
Attachments:
1.
2 •
3.
4 •
Glossary of data qualifiers.
Data Summary. This includes:
a. All positive results with qualifier codes, if applicable.
b. All unusable detection limits qualified with an ''R.''
c. All estimated detection limits qualified with "UJ.''
Appendix A -Results as reported by the laboratory (no
corrections were made during data validation).
Appendix B -Support Documentation includes details to support
the statement of this report.
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AWD Technologies, Inc.
GLOSSARY OF DATA QUALIFIER CODES
(ORGANICS)
Codes Relating to Identification
(confidence concerning presence or absence of compounds)
u = Not Detected. The associated number indicates
approximate sample concentration necessary to be
detected, or not detected substantially above the level
reported in laboratory or field blanks.
(NO CODE) = Confirmed Identification.
R = Unreliable Result. Analyte may or may not be present in
the sample. Supporting data necessary to confirm result.
Codes Related to Ouantitation
(can be used for positive results and sample quantitation limits)
J =
UJ =
Analyte present. Reported value may not be accurate or
precise.
Not detected.
imprecise.
Quantitation limit may be inaccurate or
Other Codes
Q = No analytical result.
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SUNNARY OF DATA QUALIFIERS
'EYSTONE IOR! ORDER 1190·06. 141
lnalyte Saaples lffected Positive Non Bias Cments
Resul,s Detects
-----·----------------·······--------------------------------------------------------------------------------------
Pheno I CEMENT J LOI I
I-ch loropheno I CEMENT UJ LOI
r·Nitrophenol
2, H i1ethy I pheno 1
I ,Hich loropheno 1
Hh 1oro· 3·nethy 1 pheno 1
I, I, 6-1 rich loropheno I
,,Hinitropheno 1
I-Nit ropheno 1
I• 3, I, 6-1 etrach loropheno 1
HethyH,Hinitrooheno 1
' lentachlorcihenol
~ON!ENTS
I· Low surrogate recovery.
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um: UJ LOI
CEMENT UJ LOI
CEMENT UJ LOI
mm UJ LOI
CEMENT UJ LOI
CEMENT UJ LOI
CEMENT UJ LOI
CEMENT UJ LOI
CEMENT UJ LOI
CEMEil UJ LOI
I AWO Technologies, Inc.
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I DATA SUMMARY FORMS
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I IA SU!!IRV NOi CLP om FOR SAMPLES COLLECTED 6/28/90 IZER -RALEIGH stone Environ1ent1I Job, I !90-06.112 I I Smle Ho. POIOEREO 8ENTON!TE SIMO PICK 8ENTON!TE PELLETS CO!POUND Units mm 1-----------------------------------------------------------------------------------------------nol ug/kg <IU <IU <IU IU J 2-Chlorophenol ug/kg 321 931,0 <16,6 <16.6 UJ litrophenol ug/kg 16.9 <IU <IU <IU UJ -Oi1ethylphenol ug/kg <16,6 16.9 <16.6 11€.6 UJ , -Oichlorophenol ug/kg <16.6 <IU <16.6 (16.6 UJ Hhloro·l-lethylphenol ug/kg CIU 11.1 <16.6 <16.6 UJ 1,6-lrichlorophenol ug/kg <33.3 17.l <33.3 <ll.l UJ -Oinitrophenol ug/kg <33.3 <33.3 <ll.l <33.3 OJ i-.arophenol ug/kg <33.3 <ll.l <33.J <33.J UJ 1,1,6-letrachlorophenol ug/kg <33.3 <ll.l <Jl.l <ll.l UJ ethyH,6-dinitrophenol ug/kg 37.6 II. I <Jl.l <JU UJ Pentachlorophenol ug/kg Tl. I 108.0 <l3.3 <33.J UJ ,-----------------------------------------------------------------------------------------------1 I I I I I I I I
I AWD Technologies, Inc.
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APPENDIX A
I RESULTS AS REPORTED BY THE LABORATORY
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AWO Technologies, Inc.
1\PPENDIX B
SUPPORT DOCUMENT1\TION
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