NCD003200383_19900824_Koppers Co. Inc._FRBCERCLA SAP QAPP_Field Sampling Plan 1990 - 1993-OCR

4 October 1993
TO:
FROM:
SUBJECT:
File
Jack Butle/~
Koppers Company, Inc.
NCD003200383
Moorisville, Wake County, NC
Mr. Eric Hess, PRC Environmental (913/281-2277), was contacted on this date
concerning test data that was faxed to our office from Triangle Labs on 1 October 1993.
The data for Samples 047-1126-001 and 047-1126-00lFB indicate that the level of Dioxin
in the Investigation Derived Wastewater (IDW) is below the 10 pg/I (lx10·5 ppb) level
established in our letter to Mr. Hess of 21 September 1993. Mr. Hess reported that this
IDW water has been disposed of in the fire pond on site as previously agreed.
Mr. Hess also noted that the data corresponding to Client Sample: QPR HPLC
Water and TLI Aqueous Blank are part of the QA/QC standards for the lab and not sample
data. Mr. Hess agreed to send a copy of the entire lab data package including all QA/QC
data to our office when it is received from Triangle Laboratories.
JB/dk/3
September 21, 1993
Mr. Jack Butler
SEP ~ 0 ,::i::iJ -
SUPfRFIINl'l SEGrlON
Environmental Engineering Supervisor
CERCLA Special Projects Section
•
North Carolina Department of Environment, Health, and Natural Resources
40 I Oberlin Road
Raleigh, NC 276111 Kopper6
Dear Mr. Butler:
PRC Environmental Management, Inc.
650 Minnesota Avenue
Kansas City, KS 661 O 1
913-281-2277
Fax [phone]
PRC
PRC Environmental Management, Inc_ (PRC), would like to have the treated wastewater, discussed in
your September 21, 1993, letter, analyzed by SW-846 Method 1613A. This method is specific for
the dioxin of concern (2,3, 7,8-tetrachlorodibenzo-p-dioxin) and it will meet, or produce analytical
data below, the 1 x 10-5 /Lg/L level discussed in your September 21, 1993, letter. PRC intends to use
Triangle Labs (801 Capitola Drive, Durham, North Carolina) for the analysis of these samples.
If you have any questions, please call me or Frank Bryant_at [phone].
Sincerely,
t_:_t/fe)
Eric Hess
Project Manager
PRC
TO:
Company
FAX No.
.FKOM:
ADDffiONAL
COMMENTS
• PRC ENVIRO~AL MANAGEMENT, INC . 650 Minnesota Aveoue, 2nd floor Ka= City, Kao= 66101
Telephone: 913/281-'1Z77
FAX No.: 913/281-5383
FAX 'IRANSMITTAL
Date; 9 )a~ /ss
Total Pages: )~
(Including cowr page)
Project Number: 1$42 -~ 112 f..
ly((,,n,.,;,(5
\ I ~ 0&ue.. B \..A'.TI m
(le. 1)&I, oF Et,;)01 l::\ ~A<...:D:l ~wD ' • N P.. W 0. '\ '-K~ <; 0 v,.)l L ,;;-<;
015~ 7~<.,, -~?:i 1 l
F, Ill !7. ~c
(o/13) 2-f-/-2277
Hsi, '\3 u. n m J
~_:')~ &~il~.l;"i;;IA'r1:l'. Yf-:>16 1::10.e Db Ttl.l). ~:arna. 'kl &651,d\4 e, '.D':'.le:\.Y fl£M9:::2&L pf nks('. MI\, TE9,.J ~U. J ~l,ll:l :ID As~11 !l ~ "11k es~ 1111 ao 'L D~: ,.-,(f'-:Pil:: £•ia!..D , lo ix, a lilm a.::.:: -PRC ~CLA.!,,Jlt: C....l f«:: -:rr, a~,~ f..:sl ~nst'2..
::rr'.?:6b'.Cb ►N:t: 0 6,) c, e,:w, a 1?& ::r C '-t l ;i.s 6 J), I 0 ra:>
l~,r '""'tr (l~~' ~::r: ~1-!u ,~ii.a:: 61:S 10~~ &:~ fo5)1b(.O:: • -
~Urgeot
I rK, fJ).,..s
I [. n· -
□ Company Sensitive
'P.s. ~., 1"1<=:<..J;> ~IJ""-'<'lll It v<ttY .,,,-.,1,1t[1_ lt) ~ w -8¥-l f1rrdofJ 8t/, C/p
•'1,;:1illlilll
• •
September 20, 1993
Mr. Jack But! er
Environmental Engineering Supervisor
CERCLA Special Projects Section
North C:amlina Department ~fF.nvironmenr, ffealth, and Natural Re.~urces 401 Oberlin Road
Raleigh, NC 27605
Dear Mr. Butler:
, _,_ .•. ,o.:...:..--( .!.b ;-·, i~\:.'.
PRC Environmemal Management. Inc. 650 Minnesota Avsnul;.)
K;m.e.;i.~ City, KK AA101
91 S-281-2277
Fax [phone]
PRC
During our telephone conversation on Septemtjer 17, 1993, PRC, representing the U.S. Environmental Protection Agency, proposed t9 dispose of approximately I 00 55-gallon drums of contaminated water derived from the Superfund Innovative Technology Evaluation (SITE) demonstration. conducted at the Beazer East, Tnc., site, Morrisville, North Carolina. This SITE demonstration· involved the thermal and catalyt,ic destruction of pentachlorophenol contaminated soil. The S-Oil used in this demonstration also contaired 2,3,7,8-tetrachlorodibenzo-p-dioxin (dioxin) in the 100 l'g/kg concentration range.
The water contained in the drums was produclid when three inches of rain fell on the containment pad, and from the decontamination of the conbinment pad. This water is probably contaminated with dioxin and pentachlorophenol. Both the dioxin and pentachlorophenol contamination of the water is primarily ~aus"'1 by wnt.aminat"'1 stX.!i.Int:11!.,; s~,p~uueu iu llie wale1. TI,i, IJyl"•ll1,:;,is i, bai.ed on the low solubility of the two compounds. PRC es~mates that the maximwn concentration of dioxin in water is less than 0.2 µ,g/L based on the absolute solubility of dioxin in water. ft is possible that ' pentachlorophenol concentrations are in the 2 to 3 mg/L range due to the higher relative S-Olubility of pentachlorophenol, and the higher concentrations of pentachlorophenol in the soils.
Based on an evaluation of Resource Conservaqon and Recovery Act (RCRA) regulations, PRC has assigned the RCRA hazardous waste codes K001 and F032 to this waste stream. KOO I was ' cons•rvativ~ly assigned because the soil was e~cavated from the sand filter area of the site; this was not a wood treatment process area. The RCRA waste code F032 was assigned because the source of the soil contamination and subsequent water contamination was from wood treating operations.
Hazardous waste codes F027 and F028 (dioxin containing wastes) were not assigned because the ' listing required that the waste was derived from discarded, unused formulations of pentachlorophenol. PRC did not have any indication that unused formulation, were disposed of in the sand filter area. PRC feels that this type of waste release would be restricted to the wood treatment process areas.
PROPOSED ACTION
PRC prOJXlSe1: to treat the contaminated water using an activate<l c.arbon filtration system, The system will consist of the following components: '
I._, • •
Mr. Jack Butler
September 20, 1993
Page 2
•
•
•
•
A 3-rnicron pre-filter, replaced as its flow is reduced due to sedimentation. These used filters will be drummed and incinerated off-site.
Three carbon filters operated in series. Each filter is contained in a 55-gallon drum, and contains approximately 165 pounds of activated carbon. Used carbon filters will be incinerated off-site. This filtration system will be outfitted with secondary containment as an added precaution to prevent enviromnental releases of the untreated water.
Containment tanks for effluent. These tanks will store treated water until on-site analysis determines if pentachlorophenol and dioxin concentrations are ,s;; l µ,g!L.
Additional activated carbon filters will be on-site, to use if breakthrough occurs in the first activated carbon filter.
PRC will sample the influent and the effluent from the first activated carbon filter, and the final effii,ent from the tre.atmen! system, prior to discharge into the holding tank. PRC will use a laboratory grade gas chromatograph equipped with an electron capture detector. Low detection levels will be accomplished by sample concentration through the use of a nitrogen evaporation system. PRC intends to treat the waste·,;ater to the on-site analytical detection limit of 1 µ,g/L, When the effluent is verified to meet the 1 µ,g/L action level then the effluent will be spray irrigated on the study area.
I have enclosed descriptions of our on-site anal}1ical methods and descriptions of the carbon filtration units.
If you have any questions, please call me or Frank Bryant at [phone].
Sincerely,
(.;_.~;
Eric Hess
Proja't Manager
EH/ksb
Enclosures
(
,....
,·
GENERAL DESCRIPTION·
o.,,;; Mid t,;,r '-flow ._. lr""111lenl OMA a1ro.1t, p,v-f.bmM ~ f'lollSolr C$il6ai,s .:oncdTi d 'ltl8 ep--amtinf, ·•llll'lti lo,;nd In a ~ ~plM) S)'llqnl. ThlrlieS1Tl811.tlturlC)!IIUJl~hetl 18S--0f1Jl'M'A acU,illGd"81Wn lorlll'Pflll3li0nl ~
•S!J181 .. ., ••• ~ • -~ n,.,.oi:IWik,..
-~ ~llrie lqJQ: •WelfJUl1')klllS
• Pr(,ductp,Hifi<;"6o,,Of~
• Taric.~wator.'11w\Jlll'.li'II
• Billm waler' or prooucttream&nt • Oett,o,,~pllClt~
• Emt!QBIIC)' ~ bil!lln•\\ • Mui 1oomg ""'"Wl8tt lr""..als.;., ......... 'I\
FEATURES
FlowS.:<t>a/lers-,;ffenlt'osancfb,jl;.Alsla~
CQ!r•Aetml and~-~
• $1,/fdy , 8 ~ ~ ~ pt,< 00T
~It,
•Conllnuou!r"81roonfatl'lll")'ingfbwr.stesR
W<WrtlO!k.NiS
• 8iff1l)k', i ISlalallo,1. and ~ • ~ al)Qygoart,on~lnc .. fO,.ltlli<li&ltibu1lon Of ~ • Fle,cjbiftylo 119~;,, ~or~ ope,al!ot, • SuppUed 'M\!l virgin or ~-Blud .,Jbllr, • May~ Ile.~ 1l'iltl IOensatt>, art ol •• ' d:lent "'°""' ' • ~a~oi,tion. •~ wper,1 c:i!ltion~ml!fbc retllmedlOC81go(, Ca,boll lot ssfo cart,o,, readl1ldon . * l.owe0$:lt)Of'Ul'l;tA1WliP8.~tr.;. .. 01tti(.,1Qijl.C:.,,~
FLOWSORS SPECfRCATIONS
Vesset. .............. -..... Open head ltS ~-1 -.181Br ~"'-··········-···-····-·"·...;·· ... -15~{1<11'00T17C ~···-···RemOvable sle9' °"""'· 12 gauget>olll'in;.,.;tt, bul)i rublNo'~ ~I \nt8mal Coaling: .................. -.Heat c:ured ~ pher1olic l:xJemll1 Com!nQ: ...... ___ , ....... _ .... Baked ensm;,I (gray) Ter,,perarure l.il'llit ·-··-··•···· .... · 191>" F ~.a,<::)~ 350" F !176.7" C) ~ tnlc!: ................................... _ ................... _ ... _2" FNPT ~ ........................ :. FNPT; 304 $1em19SS lllefl ~Cf cart)on: ................ -• 11:S poor<!! !)"'nubr ~ ootbo,r. ~ fiW'anb 30Q or reaor;.,<tvd grade strip Wei~: .............. -... -.................. 232 p0tAlS \105 kg) 1,:kmlfficallon: ........ _ •.. ~~tor."-""'
i ..
FLOWSORB DlMENSIOHS
QU"fm,
t"l'fll'T
COOPUIIG
..;;.•r..;.,-.:,_,_,-~:_7 ::,_1 •..:.•:'· ~·:,J. : i"•':.'Wi r·r:.'-!:.I':: 1";:··~;1.:,r,::, '-!: 1 IU SE!'-16-1993 1si 21 FFn1 CR.D:N ~ N. C. 51'4..ES TO 99l32B15363 P.03
I)
TYPICAL FLOWSORB
OPERATING PARAMETERS
Fl!;,w R;ll;:: •.••.. s•-·····•-·"···---···-·•·····-10gi,m (37.81/m)
Conlact rlfll(l: ·•······-··''··'·-'·····-·-.. -··-··········· .. 4.5 mlnules ~~ ._ .............. ,.::11)$i(dvoo-snc:1cartloo.)
()p8raling l>tiJss-.: ......... _ .. __ .. Aecoo ., ... .:i ~ I Ill
~ltum61'!1i9, bUI~~.
~ 10 l2 p!lig, ~-"'111 li!jlll OO'lllr o\olve
FLOWSORB INSTALLATION
Ro~~tll'lloh!pped_dry __ _,;
1he ~ must b9 wett11d-and de.i.mdod~ 10 use. Thu; ~ ~ air from ft,e rnae.n.ai strucbe of Ille ~ gmnule. lh11S ~tlntthe liq,l,dt, t.trNtld;. in cxmtaotwtmlllec:a,t,c:,n llUl1ace. .
Pri<lrlO op,,,tlllor,, each~ ~be lillGd wilt, de:an
..,.11,r. 1111>-~ bl> loirodi,o,,.u,,.,_11,o bol!Drn-
conllliC1ion. 1oounitshcM(l*foo ~ODili!OetJ 48"""'9-
llw ~ mQ!lt (lllht~·• inlelllal~ wbooome
wetl8d, as GhtR;n on~ W¥10r\; IU"<l') tiee:,w,
Alle,-we11inQ, lheotdbol 11)ed131~ I "'-1 brdtainin;i
· lh<, ~ aOli a{laa1 ,11ng ttlO aonl!;iw opflow wllh dean
....-. lhillr,roooclu,vWiR tlllmina!l)an,-air l)OCJlle(s ..iticltmey
h<M, loone,.j bl!!!" "'"" ht i:arbon !JI& In. The Flui,Soib !,, OOH road)' b-QPlrallcn.
~c ch<,uidll<,""'o,, ,o llol,11,y,:J~and pi,>ed
atrocot1'11"'1ododintheiralla~~-Tlm~
cr,r,~ !l!l0IJkl 1l9 llh:hed lb 1he \ll'lt bf UCing .a lk!xill(! ~ as""""' minor defiedb, .A lie llcf may occur-W l)r8SWfe Otiil:la <Mo lofillrm!an or Olt,orfloi,, bl! ~ q !jown. weam.
100
8S
Ii(!
75
WETTING CURVE FOR GAC
Tl"Fl25'C)
0 24 -48 72 96 120
TIME{HOUf!S)
2
•
..,_ ~OOP (
TOAl\Slllltl'lOOClill -
I R.OWSCAB
~
TYPICAL Fl.OWSOFl8 INSTALLATIOH
~Golt! ~•Ot ~ tl'IOlild il1dud!! an el4!\ll!\.o piping IOOPIOa.nlJllil.lhe~,.,.flODdsclwtlh
-llI all flme,i. Irr ar;ld:1iOn 10 Ille· i,;s,iog Imp, 11 ,_, e,,r,11ec!11011 bs ,ea.,,m,Md;d on fl!O ~,as~ ~ flie
:lllo"8dtait...;ie Dflhe unl!l)tiorl0dlo0ol ...eofiur1 Drla1fp0it11f
SilOl®m'-/
A IIU,;it' ~ b!i ~ 11111114 ~ l!le lqlilil ltlbe tree.tea·
ccntalns 9IJbstaolial S1110U!11s af ~ 9011d$.A ~ ca.bl,;pt c,r.,._,fil., ~ pr,Mrt~~p I!', 11N> C8!1x;,r\b&d.
FLOWSORS-OPERATION
Fbll$ort) oa,a11,,,;: ~ be IJII "'~ WIIIOI' ~ -.... 11 boQins.Row,-1011,e ~ !!ho&llc! be !lem'· mnSll~onroqulredc:onhlcl~t>et 11r,lllllliQfaOllfld
lhevaitui~ Irr~ keall1w,lltQPllll(.:aioii1,h
~ oon!Bd lrn9 wi ~$--1 o ~ wittt .a ~ftc,w~~6gpm,c:on.,,tyw,Oa!go,1
CartxJn Techfloal Sl!l,ta RG!Jrl$$dla!h," fer -ad-rioe ~
pr0pffl' o:>nll1Ct tima fcr yolr ujl,.(i B!ioo L
f"luW:SUW <a,, t,,, ~ In ~ PPl"i>k-• lo,
highor~r.iles. For~c,pe,afl,n.lffl>~b9oenbo
piptdl0gelhe,~.asnormalprta1midropmlln<ll
exceed fm tQX)tJAJ)tftta:Jod QJG<&fitlQ ~
The$e ~ .Isle, s hr,.., space tor ll..:I •.pisi"1o!1 <!f1d can
b<l~t.y;d1~9<..kl31"!-orilq.Jidatl!fl!ll""I-
IT\QIOI)' 20-26 gp<r, lo 1he ~ c,rlCI 181,i~ bukll;m -rmtor
from 1he inlet
\ .
(
:u -~-~(5~~~11--"(lb ~.Ub
TO 99132915383 P. 04 • • THEORETICAL FLOVlSOtlB TREATMENT CAPACITY FOR TYPICAL CASeS
C-5
Qsi.ei1. ~
~ppl,}560.000 500Pflll
~· k!lllli. Sialklli.
S ppm } 125000 4 Pl"" •
i'l;wd
TolalSOC
C..8
.!.llW.. ~
10 wm } so,ooo 100 ppm
eeee•
I.mi. ~
100 J)p'R } f0.000 1,000 PP"
Ett<:11..-1ep,esa11&.~01 M1S10 AW .1!wnlllal«riaine1'11>W11ilJlilllllor1doanlPmln8nllllielud. ni. -.,;,nt~, •-lhe.,,. gc,!lona of1htll ~-1halmay be ireil!ed ~ _.,, ... w,,d!IO =1a>~uarits.in~inlhtnslBCl_.ast10llld-~~'\YbmeoonS1PT1,Wlltfl'Ql
7
0
'
f
o
r
"
"
"
'

and 185 ~<>I Mli!aw,t,300. ~ n:>cie kl&slhan 1 ppmexocptphsnolllU6Sa1>ni:iwd.Ccxmm.'\to!>1& reduced lo< 5~. ~ pM<>0! 011:11C lfflletli6 lor !lS"fo~fflduclion.
HOW TO ESTIMATE FLOWSORB LIFE
The U\fflttitMII I.de Qnlhi,; 1"91 k!ll lhe~of _.,. thal Ctlnbe ~ b)' th!>~ for~ u...alau&l!ltio.1 sirualions. ~-most~--i.,,-~.ffl!x.. tin Qf orparrioctw,,, li::Q1 ocJj1tll1lina11ls irduc!lrig comQ ~ ealii ttld!~ ;rt dlllerent ~-<>• l!trr,lgtte. ~ contlllt~ycur~~Teotalied~1w,;.m,,,
lalM,to,mo,-,,~ aboot.,;a,tx,,, tiseg,t-
RETURN OF FLOWSORBS
~ tlhould be me.6-111 the tirnO of~ f¥'1tiM9 Ill~ ~ !<!l\lffi of 011ltl$9(& oontair'>i"I! spent
oart,on, ~ Carb<,n Will~ --on -10 nmple tile Sj)9rl) carbo!1 and am,ngi, for~ aQCIQI>--~-~spoor oa,t,onis r~by(;algon Carllon end~ 11f lM~«l'll1hennat, de,;~ oftd. n.. company will not aweptflJ~ torla!Jrffill, irlcinern-tion or other meani Of disposal.
No FlowSorb.;canbe!-IT!9dlo~Cl>rlx,n,,,,_
th,, carbon~ pmc,edUre hoo i:.e.r, CJl,JlllSIQd. arr JOC!lf)t$>al numberpn,vic:led.and~retumlab41!& (~ with ltie uni1S al th!, time of pu~) are e«a.A1ed.
3
~ muat blll dmk-iod.-Wld ~ ~ iionl:fflUtlt 1)8 ~-J)lfwtorelllmto C,lllgcneiut,on.
SAFETY CONSIDERATIONS
It If) unll~ v..t11·ft<lwWOl.dd be ab!& lo~ eirtflr ll Ao,lt'SO!t,~. / IC~. fie /cllow.11,g lnbma· tl<>n w r,,acaulione epi,1y 1o a ~c'-d ~ 1)1' ~ WIIGfe cart,on ~ ID be l'llfflD'ld lrcml lhe Ol!l,;919, and storoed e.be.rl'\oc1e:.
Wmcr«yaoli~CMX11'!~-
¢:<Nelt frOm ..-. In a0$'ld or~ Cl<l'DOd ~ o-~ may·,u:11 ha.arclouo:....,.._ If~ mtll:f enler II-' COl-""ilQ ca1ion, 14)1)10Pliale ,_.._ prrng .ind WCl1< p,oc,,dun,,, shotrl<l bu fQ!lowll(!lOf ~Y ~ ~ -lncllldir'l!J 1!1t !Mll,;at"" ~ and ~requke11"'1RS.
CALGON CARBON LIQUID PURfflCATION SYSTEMS
~Isa 11nlt 1!l)l!Cilieollfr de, gr~!vra \1Wi!l1y<>l $11811 flvw~Oe.~, ~ Oocp<,r.<llo,1<1ff,,tJ I wklt, rung<> 01 can,oo ~ S)SIOl'fl$ and Sl!tvir:eG let a gres!er ~ of lltM rate,; and i;o,rbo,, ~ to -!l!)OC!flc~ns.
ILi
SEP-16--19'33 1s: 22 ;=R0-1 CAUXls oiRWN N. c. SALES TO 93132815393 P.05 • • WARRANTY FLOWSORB PRESSURE ORC>f'
There lilm flO (!.)I:~~ Of" ~ O'Etftbi~ S QI My "' 14 w wa,,-sntyot ~a!>T,ty orli:ne$$ S'.fo<aµartiwtar~ ....
<t ~will>~ ga1"3 of 1lis PfOOUC!. it 12 ...
LIMfTATION OF LIABILITY 0 10 ! The f'V,-Chlls9f's e;«:JIISive """'1dy lot any ca,r.;e ot 8 aor;c,n 11r13iog wt of ~ and use o1 loo RoWSoro. irn;:lwing but not limited lo broach cl wananty, oog!iger.oe Q. 6 0 a."ldlor indarnnilicati0l.s. is~ ~mllnd lo a mai<irnum ! <>I tt><, P<Jronao!I pncc,olthe ~ unll a. oold. All da\rno 4 ot ~nature Shall bl! deem9d w;ih,ro Im'-~ "' a: In wriling 'lrilliin!Qr.y-li"9 {45}days:o!lh&o=mt>noe{!MnQ ::, 2 "' rl~ lOthe claim. In no e-.-entshall °"'90" Ca,bon Ccrpora-m r.,n for any '""->0 b,, lebl" lu, io<;:ldc,otal .,,-~ 0 damages, damages in 41XC= of the purchase priw ol the ...
~ uni!, k>IIS of profits o< fino,; imposed. by ~ :i 4 a e ,o 12 14
mental~. A..Offl\Att; (;,PM
FQrmxr,,l<J,11181>a.1rotoop,QtJ,,,;t~i,,lhis,.._,,.,,.infomu,llononoltm ~•~~a,rrta<:t~olcur~ -°""""'--"'y,;,,J:
Reolonl
POllox6766
1120~22~
B<icigo,,al,,r. ~ 088(;7
T•1(90Q)-
Fti, (908) ~
""s'= ...
560077<;;!><',~~
6"\ffi200
Coor-. NC ~17
'ie-1 (704} &2'?-:"'90
F"" (7o-i) 523-.3500
R,:,gionl
t-'.O. Box 71'7
Plttsbtngh,PA 1SZJQ-On7
Tet\41Z)n:fJo'700
!,W/4-CARIJON
F "'-{412) 7S7..(;!;7t;
SALES OFFICES
~"' ~1Z15olll!l9CMt<10Rnal
San-,CA9"<1W
TGl 1411i)!Sn-i!111
Fa,c ( 415) S,~
Re,iionVI
19':>1 C;,mino Vida RcCilt!
Sllila Ill? c...-,o.=
Tlll'6W)4:i1·S3>
Fax (ln9)<13Hl1GS
~l.O~
CAlR0((~~1'CJl'II
L.dkJ • :oe.1 ,car, ~1a P1")llle .
P.O. Box 717 ~""·=17 iol 141:n ffl-4019
Fax (<lll'J 787~
~
~e..rtx,,,~,lrc.
·Su!e.'104
l>w,Jl\lrpof1fioad
!$; :i; !Nf9Q.O:nario
C;!r1adG ~V 1 RB
Tol(418)m,71:)7
F,..("1e}~
El,Jl'Opo
ChemYirOn CAtt>Otl
'9o\llevaro <Jo~ woi,,,,,,, GO
8o4e7
s-1~ ~. ~ T"' :i:z 2 Tl1! \lZ 1l
Fax322770$3~
J
J
J
J
J
J
J·
J
J
l -
-
I I_!
•
SUPERFUND INNOVATIVE TECHNOWGY
EVALUATION PROGRAM
FlNAL DEMONSI'RATION PLAN FOR THE
EVALUATION OF
PENT~CHLOROPffENOL
FlELD SCREENING TECHNOLOGIES
Prepared For:
U.S. ENVIRONMENTAL PROTECTION AGENCY
Office of Research and Development
Cincinnati, Ohio 45268
Work As.signment No.
Date Prepared
EPA Contract No.
PRC Project No.
PRC Project Manager
Telephone No.
EPA Project Manager
Telephone No.
()-40
August 20, 1993
68-CC>-004 7
047-4000
Eric Hess
[phone]
Lary Jack
[phone]
• •
4.5.2 General Operating Procedures
The FASP method has the potential to provide quick and accurate results for pentai;ltlorophenol in the
field using a mobile laboratory. This mobile laboratory includes all equipment ne<lded to analyze soil
and groundwater samples for pentachloropheool. Electricity for the mobile laboratory can be
provided by an exten~ion cord connection to an electrical outlet, or if this source is unavailable,
through use of a gasolin~weted generator.
Soil and water samples require extraction before GC analysis. Extraction is performed by adding a
portion of the sample 10 an extraction vial. Sodium sulfate is added to soil sample extract to bind
with water present in the sample. Methyl ten butyl ether (MTBE)' is added to the extraction vial
containing the soil sample. The solvent and soil are then mixed with a vortex mixer for 2 minutes.
The mixture is allowed to separate and an aliquot of the solvent extract is taken and concentrated to I
mL using a nitrogen blowdown apparatus.
A measured amount of water is. acidified with sulfuric acid to a pH of ,s; 2. MTBE is added ro th.,
water sample ~nd mixed using a vortex mixer. The organic phase is removed from the water and
placed into a separate container. The extraction procedure is repeated two more times and the
ori:auic fractions arc combined. The. organic fraction is then concentrated with a nitrogen blowdown
apparatuli.
The water and soil sample extracts are separated on the GC with a DB-5 megabore capillary column
and the pentachlorophenol is identified and quantified u:;ing a flame ionization detector (FID). Toe
sample extracts are compared to standards to determine if pentachlorophenot is present in a sample,
and if so, at what concentration. The FASP method will only provide ppb dett:<.-tion concentrations of
pentachlorophenol in water. The FASP method's detection limits are not below the maximum
contaminant levels (MCL) published by EPA. To achieve the MCL for pentachloropbenol of l ppb,
another extraction and analysis needs to be performed.
To achieve tb" MCL for pentachlorophenol, a water sample is extraeted as described above, Once
extracted, the water sample is esterified with diazornetbane to produce a methyl ester of .
pentaehlorophenol. The sample is then concentrated with the nitrogen blowdown apparatus and
t•.:.,
•
analyzed using a DB-608 megabore capillary column connected to an electron capture detector (ECD).
Calibration standards also are esterified in this manner and are used for sample comparison to
determine the prcsen" and concentration of peotaoblorophenol in the ..:imple. This approach is used
when the detection limits achieved with the none.sterified water sample method do not meet a project's
data quality objectives (DQO) aru! when achieving a dete<.-tiu11 l lmit below the MCL is required.
Esterification of peotacblorophenol only needs to be performed when water sample results using the
' nonesterified method do not detect pentacbloropbenol or to provide confimlation of tbe presence ot'
pentachlorophenol in a water sample.
GC analysis for pentachiorophenol starts with the analysis of calibration standards. lniti.al calibration
of the GC consists of the analysis of three concentrations of pentachlorophenol calibration standards
(low, mid, and high). Retention time windows and calibration factors are determined during the
initial calibration. The initial calibration is then evaluated to ensure that it meets acceptance criteria.
After an acceptable initial calibration has bl!lln performed, sample analysis may hegin.
Sample analysis begins with the analysis of H laburatory reagent blank to evaluate the presence or
absence of laboratory-induced contamination. Samples may then be analyzed for a period as long as
12 hours. Samples may be diluted if a high pentachlorophenol content is expected.· At the l.lllU or 24
hours, a continuing calibration is performed.
A continuing calibration consists of analyzing pentachlorophenol to update retention time windows
and to determine if the initial calibration is still valid. The relative percent difference (RPD) between
the continuing calihration factor and the average calibration factor determined in the initial calibration
must be less than 25 percent. If this RPD is exceeded, initial calibration must be repeated,
Samples are identified as containing pentachlorophenol if a sample peak falls within the retention time
window established during the initial calibration. Sample pe.ik r,:,;ponse is compiU'cd to that of a
pentachlorophenol calibration standard for sample quantitation.
Sample peak responses should fall within the calibration range determined by the initial calibration. If
a sample peak exceeds the response of the high-level pentachlorophenol calibration standard of the
initial calibration, the sample must be diluted and reanalyzed.
4-19
[
[
[
[
r '
[
[
L
[
,· L
\ I -
,·
L
I ►
I
L
L
r
• •
Water samples which show no pentachlorophenol must be re-extracteo and analyzed using the
GC/ECD. GC/ECD analysis requires the same initial and continuing calibration procedures as
uescdbcd above.
4.5.3 Reagents, Equipment, and Instrumentation
The analysis of samples using tbe FASP methoo Is perfurmed using a number of rengeni:s, equipment.
and instruments. Table 4-12 summarizes the reagents, equipment, and instruments required to
perform water and soil sample analyses.
4.5.4 TralninB !llld Maintenance
A minimum .of 6 months experience in using a GC and a minimum of 1 month experience in
analyzing pentaclilorophenol are required to effectively use the FASP method. Some college-level
chemistry courses are recommended before operating the GC. In addition, the user must have the
abfllty to interpret COmPICX chromatograms.
Maintenance of the equipment is essential if It ls to provide quick and accurate results in the field.
Because of the rigors of working in the field, the GC must be on site and operating correctly at le.m
I to 2 days before the start of sample collection. This lead time allows for any neede<l maintenance
prior to sample collection.
Routine maintenance includes carrier gas changes, seprum changes, and column conditioning.
Nonroutine maintenance may include colunm changes or electronic board replacement. Agreements
with equipment suppliers for overnight delivery of replacement parts or in-the-field servicing by
equipment service representatives.
4.5.S Testing T'une and Costs
Initial calibration must be performed before sample analysis can begin. The initial calibration can be
completed in 2 hours and should occur before sampling takes place. After an acceptable initial
calibration is performed, sample analysis can begin. Sample extraction requires 20 minutes per
4-20
TABLE 4-12
REAGENTS, EQUIPMENT, AND INSTRUMENTS FOR FASP METIIOD
EPA Superf\lnd Branch
pentachlorophenol Field Screening Technologies
SITE Demonstration
Field Lab Components
• •
•
•
•
•
•
• • •
• • • •
Gas chromatograph equipped with an electron capture dete.:tor
Autosampler
Data acquisition and integration system
Flow controllers for the carrier gas
Data disks (3.5-inch, 1.44 megabyte)
Vorte,. mixer
Analytical balance (0.01 gram accuracy)
Nitrogen blowdown apparatus
Centrifuge
General field GC instrument size:
Data system size:
General field GC instrument weight:
General field data system weight:
General electrical requirements:
1.5 feet by 2 feet by 2.5 feet
1.5 feet by 2 feet by 2 feet
75 lbs
30 lbs
. 120-Volt AC, 20 amps
Test Kit Cumwnents for Annlyzjng Soil
• • •
0
• • • •
•
•
•
• •
Nitrogen carrier gas (99. 999 percent purity)
Cartier gas filters
Syringes
Printer paper
40,.mL extraction vials
Test tubes with teflon-lined lids
10, 50, 100, 200-µ.L precision pipets
Disposable Pasteur pipets
Prepurified nitrogen gas
Nitrogen carrier gas (99.999 percent purity)
Zero-grade air
Zero-grade hydrogen
MtBE. pesticide-grade
4--34
. .:,, .I .•
ru
•
TABLE 4-U
REAGENTS,'EQUlPMENT, AND INSTRUMENTS FOJt FASP METHOD (Continued)
' • •·' ~' • " '¥"
< ·-
EPA Super:Jund Branch •
pcnr.acllloropbenol Field Screening Technologies
,;, ·SITE oemocstration ....
: -!,> -·· -
Addjtional~Materials Neede.d, bur not Supplieg
•
• • • ..
•
~~
.f
ACS·.;,srade ·sillfuric aCid ;.
Diazomelhan~~derivatization reagents
Peniachlorophenol calibration standards
Petl!Wlent ro¥king pens :
Laboratory tissue -
Liquid waste~container
Paper towm,~ · -
i\ ;i ~;; .. C e· ,..
i •
= -1
' !
}:.,;:_.•_
'\ i. '"' ··'\
~:;·.~. ::* r ·-~.,
~ ....
Sr
4-35(•·
. :' '
P.13
( -
.,...
... ...
"'
...
TL-RTP Project: 25378
Client Sample: QPR HPLC WATER
Client Project: n/a
Sample Matrix: AQUEOUS Date Received:
TI"RTP TD: OPRWATER Date Extracted:
Date Analyzed:
Sample Size: 1.000 L Dilution Factor: Dry Weight: n/a Blank File:
GC Column: DB-5 Analyst:
2.3,7,8-TCDD 179
13C,,-2,3,7,8-TC0D 2390 120
"CZ.-2,3, 7,8-TCDD 234 117
,,c,,. J,2.3,4-TCDD
1613A TCDDfTCDF Analysis (DB-5)
Analysis File: T934609
I I Spike File: SP161F2S
09/29/93 !CAL: TF59033
09/30/93 CONCAL: T934608
n/a % Moisture: n/a
T934610 % Lipid: n/a
SA % Solids: n/a
0.80 29:41
0.80 29:40 Q
29:41
0.81 29:28
Data Reviewer: $....,JJ,.,,aj'+}_/ ____ 00/30/93
¼e loft
Triangle Laboratories of RTP, Inc:.
801 Capttola Drive• Durham, North Carolina 27713
Phone: (919} 544-5729 • Fax: [phone]
IOIF_PSR ~:1.06, I.AA$j.Q9,0!
Printed: 21: 14 09/30/93
l. .!. • .::...... l ..:·;..1.•1..1-,,, l l'\ .1. rl 1, U l..J L l..J rl I.J ~ ..I. .._, ,_,
TL-RTP Project: 25378
Client Sample: TLI AQUEOUS BLANK
Client Project: n/a
Sample Matrix: AQUEOUS Date Received: TLRTPID: TLI BLANK Date Ex tr acted:
Date Analyzed:
Sample Size: 1.000 L Dilution Factor: Dry Weight: n/a Blank File:
GC Column: DB-5 Analyst:
2,3,7,8-TCDD 0.41
1613A TCDDfTCDF Analysis (DB-5)
Analysis File·. T934610
I I Spike File: SP161F2S
09/29/93 ICAL: TF59033
09/30/93 CONCAL: T934608
n/a % Moisture: n/a
T934610 % Lipid: n/a SA. % Solids: n/a .
0.81 29:40
'i~t,~{,~'.~~~i;:'.T0l~t~;;1is:11;t};iggn1t:c1(~If::"Ri}i);fg.~~~~~;;,;;;,\i;{;i';}t.:I:IJi'.~tJg";'.\:iif{I:@i\'\;)'ijf:f £:tI/ itijii~}I?
1360 67.9
"C~-2,3,7,8-TCDD 167 83.6
Dara Reviewer: J!dm>y/ ·
Page I of I
Triangle Laboratories ol RTP, Inc.
801 Capttola Drive• Durham, North Carolina 2n13
Phone: [phone] • Fax: [phone]
0.80 29:39 Q
29:40
09/30/93
l<ilF_PSR v:1.06, u.RS.5.09.01
Printed: 21: 15 09/30/93
1 1 . .::., I .r .. 1v1 r·• l I'-.1 M. l'I \.1 l.J C. i.J M D tJ . .l 1._.I _'-±.
TL-RTP Project: 25378
Client Sample: 047-1126-001
Client Project:
Sample Matrix:
TI.,RTP ID:
Sample Size:
Dry Weight:
GC Column:
2,3,7,8,TCDD
"Cl.·2,3,7 ,8-TCDD
13C,,· l ,2.3.4· TCDD
n/a
AQUEOUS
71-4•1A
1.000 L
nfa
DB-5
ND
2210
249
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor:
Blank File:
Analyst:
1.1
110
125
1613A TCDD/TCDF Analysis (DB-5)
Analysis File: T934612
09/29/93 Spike File: SP161F2S
09/29/93 ICAL: TFS9033
09/30/93 CONCAL: T934608
n/a % Moisture: 100.0 T934610 % Lipid: n/a
SA % Solids: 0.0
0.79 29:39 .q
29:40 Q
0.82 29:26 C.'J
}0 11 n ~ Data Reviewer: -4:f'-~ ... ~~...,,...n..,..... ______ 09/30/93 u
Triangle Laboratories of ATP, Inc.
801 Capitola Drive• Durham, North Carolina 27713
Phone: (919) 544·5729 • Fax: [phone]
Page l of 1 l(i!F_PSR v:J.06.~ 5.!W0I
Printed: 21: 14 09/30/93
.10.c11.S13 l l : 24' .i\JVI *TRIANGLE P05
TL-RTP Project: 25378
Client Sample: 047-1126-00lFB
Client Project: n/a
Sample Matrix: AQUEOUS Date Received: TLRTPID: 7'.1.-4-2A Date Extracted:
Date Analyzed:
Sample Size: 1.000 L Dilution Factor: Dry Weight: n/a Blank File: GCColumn: DB-5 Analyst:
2,3,7,8-TCDD ND 2.9
1613A TCDDtrCDF Analysis (DB-5)
Analysis File: T934613
09/29/93 S pilce File: SP161F2S 09/29/93 ICAL: TF59033
09/30/93 CONCAL: T934608
n/a % Moisture: 100.0
T934610 % Lipid: n/a
SA % Solids: 0.0
'skti'&tJ!!,:~fa~~)fi~fB;yfoii;cj,,:,:o/¥:;,cf@}'•;;;,),;'.;':~-R#<>:vft"ry,,, ;"':;1,:,)£::<,,·::1.~!!~~1e,;;&;;2:<;:Jp':, :,,. "+F\ae\l'~'
"CL-2,3,7,8-TCDD 89.2 44.6 , 29:40 Q
"C12-l,2,3,4-TCDD 0.79 29:26 Q
;WJ . .,..,....~-·
Data Reviewer:~~
Page 1 of I
09/30/93
!CHP .}'SR v:\,06, LARS Hl9.0J
Trl:$1:nl"IIA I nhnro.+nrlat.t ..,.f D~ 1 ......
• _ _.. .__. .I. • ._ •. _, .I. • L.. I _. ._.1.•,.1. J. 1'\.L.rlJ.,ULJ.L. Url.U>J
• •
FAX TRANSMITTAL
DATE: October 1, 1993
COMPANY: PRC Environmental Management, INC,
FROM: Valerie Evans
COMPANY: Triangle Laboratories -Research Triangle Pnrk
# OF PAGES INCLUDING THIS ONE: S
. IF RETRANSMTSSTON TS REQUIRED CALL VALERIE EVANS 919/544-8353
MESSAGES:
TU PROJECT #25328 , CLIENT SAMPLE ID #047-1126-(X) I &
047-1126-00lFB, sample results. The client sample id#
047-1126-00IFB is being reanalyzed due to quantitative
intcrforcnccs which is instrument related. The data is
considered valid.
Tr/angle Laboratories of RTP, Inc,
801 Capito/a Drive P.O. Box 13485
1 1_1 l
Durham, NC 27713 Research Triangle Park, NC 27709
919-544-5729 Fax# [phone]
• • UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
REGION IV
345 COURTLAND STREET. N.E.
ATLANTA. GEORGIA 30365
4WD-SFB
CERTIFIED MAIL
RETURN RECEIPT REQUESTED
September 26, 1990
Shannon Craig
Beazer Materials and Services, Inc.
436 Seventh Avenue
Pittsburgh, PA 15219
RE: Koppers Site
Morrisville, North Carolina
Dear Ms. Craig:
l\tt;t1vED
Der os 7990
SOPBifaNDSEcr,oN.
This letter is written to provide conditional approval of the Round 2
Sampling Plan. Due to the detection of dioxin in the groundwater at
the site, resampling of wells to confirm these results will be
necessary. The following wells will be resampled:
C-30A
C-4A and
Either C-27A or C-28A
The sampling plan submitted for Round 2 stated several times that the
data from Round 1 has not been validated. The Agency requests that
all validation procedures be completed no later than October 31,
1990.
Please contact me if you have any questions concnerning this letter.
We look forward to the Round 2 sampling. Per our conversation, this
effort will begin during the first week of October 1990.
Sinc;:erely,
/( :C(:, \·2·-.. ·~/(,/~)~·-
Barbara H. Benoy
Remedial Project Manger
Waste Management Division
. : /
Pat DeRosa, NCD22NR ✓
Mary Jane Rigatti, Dyna!ne.c
BerD.ie Hayes! Wi,!:J
page 1
Wt(l;rrJ '9 ED •
STONE ENVIRONMENTAL RESOlillirES
ANALYTICAL DIVISION -
REPORT: Sample Status by Job for M90-06.95
Produced on: 5-JUL-1990 By: George R.
SAMPLE SOURCE TEST I DATE SAMPLED
JUL 13 1990
Rusnak 11\1D SECllON
COMPLETED ----------------------------------------------------------------------------
SW RINSATE BLANK (FIL)
SW RINSATE BLANK (UNFIL)
X RINSATE BLANK (UNFIL)
SW-10-FB (FIL)
SW-10-FB (UNFIL)
SW-12-FB (FIL)
SW-12-FB (UNFIL)
SW-12-FB-DUP (FIL)
SW-12-FB-DUP (UNFIL)
X-17-FL
X-17-FL (DIL)
X-18-FL
X-37-CP
DIOX
DIOX
DIOX
DIOX
DIOX
DIOX
DIOX
DIOX
DIOX
DIOXX
DIOXX
DIOXX
DIOXX
l-MAY-1990
l-MAY-1990
l-MAY-1990
l-MAY-1990
l-MAY-1990
l-MAY-1990
l-MAY-1990
l-MAY-1990
l-MAY-1990
l-MAY-1990
l-MAY-1990
l-MAY-1990
l-MAY-1990
27-JUN-1990
27-JUN-1990
27-JUN-1990
27-JUN-1990
27-JUN-1990
27-JUN-1990
27-JUN-1990
27-JUN-1990
27-JUN-1990
27-JUN-1990
27-JUN-1990
27-JUN-1990
27-JUN-1990
==============================================================================
p.,ge 2 l SAMPLE SOURCE l TEST i DA -AMPLE□ I COMPLETED I 1----------------------------------------------------------------------------1 X-27LF 0-2' I SOLCLP I 30-MAY-1990 I 22-JUN-1990 I X-4-LF 0-2' I 8080X I 30-MAY-1990 I 2-JUL-1990 I X-4-LF 0-2' i 8240X I 30-MAY-1990 I 2-JUL-1990 I X-4-LF (>-2' I 8270X I 30·-MAY-1990 I 2·-JUL-19','0 I X-4-LF 0-2' t , I CL.Pl~E_X I 30-MAY-1990 I 22-JUN-·1990 I I X-4-(F 0-2' I CNTCL I 30-MAY-1990 I 11-JUN-1990 I I X-4-LF 0-2' I SOLCLP I 30-MAY~1990 I 22-JUN-1990 I I C25A-WA I 8080 I 31-MAY-1990 I 2-JUL-1990 I I C25A-WA I 8240 I 31-MAY-1990 I 2-JUL-1990 I I C25A-WA I 8270 I 31-MAY-1990 I 2-JUL-1990 I I C25A-WA I CLPME I 31-MAY-1990 I 22-JUN-1990 I I C25A-WA I CLPME_D I 31-MAY-1990 I 27-JUN-1990 I I C25A-WA I CNTCL I 31-MAY-1990 I 11-JUN-1990 I I C-26A-WA I 8080 I 31-MAY-1990 I 2-JUL-1990 I I C-26A-WA I 8240 I 31-MAY-1990 I 2-·JUL-1990 I I C-26A-WA I 8270 I 31-MAY-1990 I 2-JUL-1990 I I C-26A-WA I CLPME I 31-MAY-1990 I 22-JUN-1990 I I C-26A-WA I CLi:-•ME_D I 31-IVIAY-1990 I 22-JUN-1990 I I C-26A-WA I CNTCL. I 31-MAY-1990 I 11-JUN-1990 I I C-30·-LF I 308<) I 31-MAY-1990 I 2-JUL-1990 I I C-30-LF I 8240 I 31-MAY-1990 I 2-JUL-1990 I I C·-30-LF i 8270 I 31-MAY-1990 I 2-JUL-1990 I I C-30-LF I CLPME I 31-MAY-1990 I 22-JUN-1990 I I C·-30-LF I cu:.•ME_[, I 31-MAY-1990 I 27-J"UN-1990 I I C-·30-LF I CNTCL I 31-·MAY-·1990 I 11-JUN-1990 I I S-RINSATE I 8080 I 31-MAY-1990 I 2-JUL-1990 I I S-RINSATE I 8240. I 31-lvlAY-1990 I 2-JUL-1990 I S-RINSATE I 8270 I 31-MAY-1990 I 2-JUL-1990 I S-RINSATE I CLPME I 31-MAY~1990 22-JUN-1990 I S-RINSATE I CNTCL I 31-MAY-1990 11-JUN-1990 I C-50A I 8080 I 29-MAY-1990 2-JUL-1990 I C-50A I 8240 I 29-MAY-1990 2-JUL-1990 I C-50A I G::70 I 29-MAY-1990 2-JUL-1990 I C-50A I CLPME I 29-MAY-1990 22-JUN-1990 I I C-50A I CNTCL I 29-MAY-1990 11-JUN-1990 I I C-55A I CNTCL I 29-MAY-1990 11-JUN-1990 I I C-60A I CLPME I 29-MAY-1990. 22-JUN-1990 I I S-80 I 8080 I 29-MAY-1990; 2-JUL-1990 I I S-80 I 8270 I 29-MAY-1990 2-JUL-1990 I I S-80 I CLPME I 29-MAY-1990 22-JUN-1990 I I C-FB I CLPME I 31-MAY-1990 22-JUN-1990 I I C-FB I CLPl~E_D I 31 ·-MAY-1990 27-JUN-1990 I I C-FB I CNTCL I 31-MAY-1990 11-JUN-1990 I --------------------------------------------------------------------------------------------------------------------------------------------------------------
page 1
.Ja;(STONE El·J'v' l_ROM·'iENTAL R[SOUF,CES
• Al',ALYTICAI_ [1IVISION •
REPORT: Sample Statu5 by Job for rt90-05.110
Produced on: S-JUL-1990 By: George R. Rusnak
I SAl':ll=-'L E SDURCE I TE:ST I DATE SAMPLE Li I COMPLETED I
I----------·-··· ------------------·-------------------------------------------------1
I C4--n:, 8(l8(J I 30-i"IAY-1990 I 2-JUL-19'70 I
I C4-TP 824(1 I 30-MAY-1990 I 2-JUL-1 ';'90 I
I C4-TP 82'7(.i I 30-MAY-1990 I 2-JUL-1990 I
I C4-TP CLPME I 30·-MAY-1990 I 22-JUl\l-1990 I
I C4-TP CLP11[ _[, I 30-MAY·" 19'?0 I 22-JUN--1990 I
I C4-TP CNTCL I 30-·i'lAY-1990 I 11--JUN-1'>'90 I
I C27A··FL 8():J(1 I 30--MAY-l 9'7'0 I 2-JUL·-199(, I
I C27A-FL 8240 I 30-·MAY-1990 I 2-JUL-1990 I
I C27A-FL 827(; I 30-MAY·-1990 I 2-JUL-199(, I
I C27A-FL CL.PME I 30-MAY-· 1990 I 22-JUl~-1990 I
I C27A-FL CLl='!YIE -[I I 30-MA ·.,-· -1 ci''70 I 27-JU:·J-19Li'O I
I C27A-FL CI\ITCL I 30-MAY-1 <)90 I 11-JUN-t 9<;'0 I
I C27-FL DUPLICATE 80t.3G I 30·-MAY-1990 I 2--JUL--1990 I
I C27··FL DUPLICATE 8:24<) I 30-MAY-1990 I 2-JUL-1990 I
I C27-FL DUPLICATE 827(.1 I 30-l':'!AY-1990 I 2-JUL-l.97(, I
I C27-FL DUPLICATE CLP~IE I 30-·MAY-1990 I 22-JUN-1990 I
I C27-FL DUPLICATE CLPl1E [I -I 30-MAY-1990 I 27-JUN-1990 I
I C27··FL DUPLICATE CNTCL I 30-MAY-l 9'10 I 1 l··J'UN-1990 I
I C-28A-CP 8080 I 30-MAY·-1990 I 2-JUL-1990 I
I C-28A-CP 8240 I 30-MAY-1990 I 2-JUL-1990 I
I C-28A-CP 8270 I 30-MAY-1990 I 2-JUL-19C/() I
I C-28A-CP CLPME I 30-MAY..:1990 I 22-JUl~-1990 I
I C-28A-CP CLPME D -I 30-MAY-1990 I 27-JUN-1990 I
I C-28A-CP CNTCL. I 30-MAY-1990 I 11-JUN-1990 I
I RALEIGH CLPME I 30-MAY-l'i'90 I 22-JUN-199<) I
I RALEIGH CNTCL I 30-MAY-1990 I 11-JUN-1990 I
I FB 8080 I 30-MAY-1990 I 2-JUL-1990 I
I FB 8240 I 30-i"IAY-1990 I 2-JUL-1990
I FB 827(1 I 30-MAY-1990 I 2-JUL·-1990
I FB CLPME: I 30-MAY-1990 I 22-JUN-1990
I FB CL\:'Mi:: _D I 30-MAY-l't90 I 27-JUN-1'190
I FB CtHCL I 30 -~iAY-1990 I 11-JUN-1990
I S-18-MP 0·-611 t3(l1J(1 ;;;_ I 30·-MAY-1990 I 2-JUL-1990
I S-18-MP 0--6 11 8240X I '.JO··MAY-1990 I 2-JUL-1990
I S-18-MP (1·-611 8'.2~lOX I 30-MAY-1 '7'10 I ·2-JUL-1990
I S-18·-MP 0-611 CLP~IE X 30-MAY-1990 22-JUN-1990
I S-18·-MP c,-611 CNTCL '.JO··MAY--1990 11-JUN-199(,
I S-18-l"iP 0-611 SOLCLP 30-MAY-1990 22-JUN-1990
I S-18·-MP 2-4' 8080X 3(,-·MAY-1990 2-JUL-19'7'0
I S-18-MP 2-4' 8240X 30-MAY-1990 2-JUL-1990
I S-18-MP 2-4' s::·1ox 30-11AY-1990 2-JUL-1990
I S-18-MP 2-4' CLP~IE ,.-30-MAY-19':IO 22-JUN-1990 ~
I S-18-MP 2-4' CNTCL 30-·MAY-19'?0 ll-JUN-1990
I S-18-·MP 2-4' SOLCLP 30-MAY-1990 22-JUN-1990
I X--2-LF 0-:'.' 80f:3l) X 30-MAY-1990 2-JUL-199(,
I x-2-U" 0-2 I 824UX 30-MAY·-1990 2-JUL-1990
I X-2-LF 0-2' 8::70X 30---MAY--1990 2-JUL-1990
I X-·2-LF 0-·2,. CLPME X -~JO-MAY-1990 22-JUN-1990
I X-2-LF (, .•. ::.:: ; CI\ITCL 30-MAY-1990 11-JUN-1990
page 2
I SAMPLE SOURCE I TEST I DA SAMPLED I COMPLETED I 1----------------------------------------------------------------------------1
I FB I S04 I 30-MAY-1990 I 11-JUN-1990
I TB I 8020 I 30-MAY-1990 I 19-JUN-1990
I C-25A-WA . I 802() I 31-MAY-1990 I 19-JUN-1990
I C-25A-WA • 8040 I 31-MAY-1990 I 18-JUN-1990
I C-2~~-WA ALK I 31-MAY-1990 I 5-JUN-1990
I C-25A-WA CL I 31-MAY-1990 I 5-JUN-1990
I C-25A-WA C03 I 31-MAY-1990 I 5-JUN-1990
I C-25A-WA GC515 I 31-MAY-1990 I 19-JUN-1990
I C-25A-WA HC03 I 31-MAY-1990 I 5-JUN-1990
I C-25A-WA S04 I 31-MAY-1990 I 11-JUN-1990
I C-26A-WA 81)20 I 31-MAY-1990 I . 19-JUN-1990
I C-26A-WA 8040 I 31-MAY-1990 I 18-JUN-1990
I C-26A-WA ALK I 31-MAY-1990 I 5-JUN-1990
I C-26A-WA CL I 31·-MAY-1990 I 5-JUN-1990
I C-26A-WA C03 I 31-~!AY-1990 I 5-JUN-1990
I C-26A-WA GC515 I 31-MAY-1990 I 19-JUN-1990
I C-26A-WA HC03 I 31-·MAY-1990 I 5-JUN-1990
I C-26A-WA S04 I 31·-l~AY-1990 I ll-JUN-1990
I C-30-LF 8(:)20 I 31-MAY-1990 I 19-JUN-1990
I C-30-LF 81)40 I 31-MAY-1990 I 18-JUN-1990
I C-30-LF ALK I 31-MAY-1990 I 5-JUN-1990
I C-30-LF CL I 31-MAY-1990 I 5-JUN-1990
I C-30-LF C03 I 31-MAY-1990 I 5-JUN-1990
I C-30-LF GC515 I 31-MAY-1990 I 19-JUN-1990
I C-30-LF HC03 I 31-MAY-1990 I 5-JUN-1990
I C-30-LF S04 I 31-MAY-1990 I 11-JUN-1990
I S-RINSATE 8040 I 31-MAY-1990 I 19-JUN-1990 I
I ORGANIC FREE WATER GC515 31-MAY71990 I 19-JUN-1990 I
I C-FB 8()2() 31-MAY-1990 I 19-JUN-1990 I
I C-FB 81)40 31-MAY-1990 I 19-JUN-1990 I
I C-FB ALK 31-MAY-1990 I 5-JUN-1990 I
I I C-FB CL 31-MAY-1990 I 5-JUN-1990 I
I C-FB C03 31-MAY-1990 I 5-JUN-1990 I
I C-FB GC515 31-MAY-1990 I 19-JUN-1990 I
I C-FB HC03 31-MAY-1990 I 5-JUN-1990 I
I C-FB 504 31-MAY-1990 I 11-JUN-1990 I
I TB 8020 31-MAY-1990 I 19-JUN-1990 I
I 5-RINSATE BLANK 80~0 l·JUN-1990 I 19-JUN-1990 I
I 5-RINSATE BLAN!( 8040 1-JUN-1990 I 19-JUN-1990 I
I S-RINSATE BLANK TDC 1-JUN~1990 I 11-JUN-1990 I
I X-RINSATE BLANK 8040 1-JUN-1990 I 19-JUN-1990 I
I C-FB ALK 1-JUN-1990 I 5-JUN-1990 I
I C-FB CL 1-JUN-1990 I 5-JUN-1990 I
I C-FB C03 1-JUN-1990 I 5-JUN-1990 I ·1 C-FB HCOJ 1-JUN-1990 I 5-JUN-1990 I
I C-FB, 504 1-JUN-1990 I 11-JUN-1990 I
I TB 802() 1-JUN-1990 I 19-JUN-1990 I ---------------------------------------------------------------------------------------------------------------------------------------------------------------
I
•
YSTONE EhlV H(Cll·ME:HAL f',:E~;n,-;FS
ANALYTICAL DIVISION
REPORT: Sample Status by Jcb fer M?0-05.106
p.,ge 1
Produced or): 5-JUL-1990 By: George R. Rusnak
I SAMPLE SOURCE I ·rEST I DA.rE SAMPLED I COMPLETED I 1----------------------------------------------------------------------------1 RINSATE BLANK (SOIL)
C4-TP
C4-TP
C4-TP
C4··TP
C4-TP
C4-·TP
C4-TP
I C4·TP
I C27A-FL
I C27A··FL
I C27A-FL
I C27A-r-L
I C27A-~L I
I C27A-l:L
I C27A-FL
I C27A-r-L
I C28A-CP
I C28A-C~·
I C28A-CP
I C28A-C~•
I C28A-CP
I C28A-·C~•
I C28A-·CP
I C28A-CP
I S-RINSATE BLANK
I S-RINSATE BLANf<
I X-RINSATE E:LANf<
I X-RINSAT[ BLANK
I FlALE IGH
I RALEIGH
I RALEIGH
I F,ALE IGH
I RALEIGH
I RALEIGH
I RALEIGH
I RALEIGH
I RALEIGH
I RALEIGH
I RALEIGH
I RALEIGH
I RALEIGH
I FB
I FB
I FB
I FB
I FB
I FB
I f-8
8040 29-MAY-1990
8020 30-MAY-1990
804(; 30-MAY-1990
ALI< 30·-MAY-1990
CL 30-MAY-1990
co:: 30-MAY-1?90
GC51~:'. 30·-MAY·· 1990
HCOJ 30-MAY-199<)
EiCJ-4 30-IV!A"r' -1990
£}020 JO-·MAY-1990
l".l(i4(; 30·· l~AY-1990
AU< 30-l"IAY-1990
CL. 3(> -MAY - 1 99(,
C03 30-MAY-1990
f3C::'., 1 ~::. 3(i-ti1AY-199(,
HCOJ 30·-MAY-1990
E;tJ4 30-MAY·-1990
8020 ~W-MAY-1990
8U40 3(,-MHV-1990
AU< 30-·MAY-1990
CL. :x,-MAY-:-1990
C:03 30-MAY-1990
GC~.51 ~~I 3C,-MAY-19'i'O
HC:03 30-MAY-1 'r90
::-31]4 30-MAY--1990
8020 30-iYIAY-1990
81)40 30-MAY-1990 so:.:o 30-MAY-1990
804(, 30-MAY--1990
8020 30-iYIAY-·1990
Ei(i40 30-MAY-1990
AU< 30-MAY-1990
BOD 3(,-MAY-199(,
CL 30-MAY-1990
CCJ3 30·-MAY·-1 (i'-70
COD 30-MAY-1990
CF:6 30··1':tAY-1990
GC51 !:5 30-MAY--1990
HC:03 30--r~AY-1t?90
S04 30-iYIAY-1990
TCJC 30-MAY-1990
TSS 30-r-lAY--1990
l~O:::::(J '.30·-MAY-1990
8040 30-MA'/-1990
AU< 30-MAY-1990
CL 30··1'1AY-19?0
C03 30-MAY-19?(,
GC51ti 30-~IAY-·1?90
HC03 30-·MAY·· 1990
i
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
19-JUN-1 'i'90
19-JUN-1990
19-JUN-1990
5-JUN-1990
5-JUN-1990
5-JUN-1 't90
21-JUN-1990
~;-JUN-1 ??O
11-JUN-1 ','<;'0
19-JUN-1??0
19-JUN-1 ',·90
5-JUN-1990
'c,-JUN-1990
5-JUN-1 '?1YO
1 9 ·· JUN-1-c;c;•(,
:",-·JUN·· J. 990
11 · JUN-l ''i"i·(1
19-·JUN-1990
19-·JUN · 1970
5-JUN-1 't'tO
5-JUN-1990
5-JUN-1990
21-JUN-1990
5-JUN-1990
11-JUN-1990
19-JUN-1990
19-JUN-1990
19-JUN-.1990
19-JUN-1 ','90
19-JUN-1990
19-JUN-1990
5-JUt,-1990
15-JUN-1990
5-JUN-1990
5-JUN-1990
11-JUN-1990
ll-JUN-1990
21-JUN-1990
c5-·JUN-1990
11-JUN-1990
1 l··JUN-1990
5-JUN-1990
19-JUN-1990
19-JUN-1990
:',··JUN-1 ?90
5-JUN-1?90
~;-JUN-19'1'0
21-JUN-1990
~;-JWl-1990
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
. I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
P·"ge 1
•
:YST:JI-.IE Et·NIG:Dl-.ll~El·HAL RESfMCES
ANALYTICAL DIVISION •
REPORT: Sample Status by Job ·for ~190-05.105
Produced on: 5-JUL-1991) By: George R. Rusnak
I SAI1IPU; SOUF(CE I TEST I DAT[ SAMPLED i COMPLETED I 1--------------------··-----------------------------------·--------------------1
x--~•-L.F 0-2'
X--:5-LF I~.; .. -2 1
X--::'.1-LF 4·-b'
X-~i-·LF 4-6'
X-c',-U' 4··6' [tUPLlCATl
X-5-LF 4-6' DUPLICATE
X-5-LF 8·-· l ;) 1
X-5-LF 8-1!)'
X·-8-u: (l·-·2'
X-B-LF 0-2'
X-8-·LF 0·-2 I DUPLICATE
X-8-LF 0·-2' DUPLICATE
X-8-·LF 4-6'
X-8-·LF 4-6·
X-8·-LF 8-1 (l'
X-8· u: 8-10'
8(;4(i:< I
:30L I
80.:'.rOX I
SOL I
8040X I
SOL I
t;(i40>:.
SOL
8040X
SOL
Li04()X
SOL
8040l
SOL
8040l..
[JOL
'.29··1'1AY-l 990
::9-MAY-1 S'90
29-MAY· 1990
29-MAY-1990
29 ·-MAY-1 9<;·(,
29-MAY-199<)
29-MAY--1990
29-i'tiAY-1990
29-r~AY-1990
29-MAY-1990
2C/-MAY-1990
29-·MAY-· 1990
29·-MAY·-199(1
29-MAY-1990
29-MAY-1990
29-·MAY-1990
19-JUN-199<'..1
1 -JUN·· 1 '?90
19·-JUN-l '·N(,
1-JUN-1990
19-JUN-1990
1-JUN-· 19'70
i '7-JUN-l. 990 .
1-JUN·· 1990
19-JUN-1990
1-JUN-1990
19-JUN-1990
l-JUN-1990
19-JUN-1990
1-JUN-199,)
19-JUN·-1990
1-JUN-· 1990 ---------------------------•-·-------------------------------------------------------------------------------------·--------------------------------------------
page 1 aYSTONE El\l',t'lF,CJl,lltlEhlTAL RES01C.ES • ANALYTICAL DIVISION REPORT: Sample Status by Job for M90-05.40 Produced on: 5-JUL-1990 By: George R. Rusnak I SAMPLE SOURCE I TEST I DATE SAMPLED I COMPLETED I 1----------------------------------------------------------------------------1 I S-16A··EA I 8040X I 9·-MAY-1990 I 4<TUN-19'i0 I I S-16A-EA I SUL I 9-MAY-1990 I 15-MAY-1990 I I S-16B-EA I B040fi: I 8-MAY·-1990 I 4-JUN-199(> I I 5-16B-EA I SOL i 8-MAY-1990 I 15-MAY-· 1990 I I S-168-EA I TOC~. I 8-MAY-1990 I 21-MAY-1990 I I S-17-EA I 8041)):'. I 8·-MAY-1990 I 4-JUN-1990 I I S-17-EA I SOL I 8-MAY-19''1(• I 15-l~AY-19'i'O I I S-23-EA I 8l)40X I 8-MAY-1990 I 4-JUN-1990 I I S-23-EA I SOL I 8 .. ·MA r-1 '?90 I 15-MAY-1990 I I S-23-EA I TOCX I 8-MAY-1990 I 21-MAY-·1990 I I S-24-EA i 8040X I 8·-MAY-19'70 I 4-JUN-1990 I I 5-24-EA I SOL I 8-MAY-1990 I 15-MAY-1990 I I 5-25-EA i 8040X I 8-MAY-1990 I 4-JUN-1990 I I S-25-EA I SCIL I 8·-MAY-1990 I 15-MAY-1990 I I 5-26-EA I 804(,X I 8-MAY-1990 I 4-JUN-1990 I I S-26-EA I SOI_ i B···MAY-· 1990 I 15-MAY-1990 I I S-27-EA I 8C•40X I 8-MAY·-1990 I 4-JUN-1990 I I 5-27-EA I SCJL I B··MAY-1990 I 15-MAY-1990 I S-28-·EA I 8040X I 8·-MAY-1990 I 4-JUN-1990 I S-28-EA I SOL I 8-MAY-1990 15·-MAY-1990 I S·-29-WA I 804(>X I 8·-MAY-1990 4-JUN-1990 I S-29-·WA I SOL I 8--t~AY~ 1990 15·-MAY-1990 I G-3(1·-WA I 8(i4(lX I 8-·MAY-1990 4-JUN-1990 I 5-30-WA I SOL I 8-MAY-1990 15-·MAY-1990 I G-31-WA I 804:=,x I B··MAY-1990 4-JUN-1990 I 5-31-WA I SOL I 8-MAY-1990 15-MAY-1990 I S-32·-WA I 8040)( I i3·-MAY-1990 4-JUN-1990 I 5-32-WA I SOL I 8-MAY-1990 1!":,··MAY-1990 I S·-33·-~iJA I 804CiX I 8·-MAY-1990 4·-JUN-1990 I S-33-W;Cl I SOL I fl-MAY-1990 15-iYIAY-1990 I S··34-Wi'l I 8(14(iX. I 8··1'1AY·· 1990 4-JUN·-1990 I S-34··WA I ,30L I 8-IYIAY-l.9'i'O 15-MAY-1990 I S RIN>3ATE f::L./·H~f< i 804(.1 I 8-MAY-1990 4·-JUN-1 'i'90 I S RINSATE 8LAl'!I,: I TOC I B··MAY-1990 17-MAY-1990 I S RH-ISATE E>LANfc: i s,:,40 I 9-MAY-1990 4-JUN-1990 I S-168-EA DUPLICATE I SCJL I 8-·MAY-'"*** I 21-MAY-1990 I S-i68-EA Dlii=-'LlCATE I TOCX I 8·-MAY-*·"'*·"' I 21-MAY-1 '?90 I -------------------------------------------------------------------------------
I
•
YSTOl~I: l:r·N n,m.:ME1--1TAL ,:;;1.:sou,-·Es
ANALYTICAL DIVISION
"REPORT~ Sample Status by Job for M90-05.28
page l
Produced on: 5-JUL-1990 By: George R, Rusnak
SAMPLE SOURCE I TEST I [1AT[: SAMPLED I COMPLETED I 1----------------------------------------------------------------------------1
I SW-18-MP Sllf-(FACE DUPLICATE 8020 7-MAY-1990 I 22--MAY-1 \?90 I
I SW-18-·MP SUF,FACE DUPLICATE GC~~ 15 7-MAY-1990 I 30-MAY-1990 I
I SW-18-Me-' SUF,FACE 802(1 7-MAY·-1990 I 22-MAY-1990 I
I SW-18-MP SURFACE 804() 7-MAY-1990 I 1-J-UN-1990 I
I SW-18-MP SUFffACE GC~;J.~:; 7-MAY-1991) I 30-MAY-1990 I
I SW-18-MP 2/3 DEPTH 8020 7-MAY-l"NO I 22-MAY-1990 I
I SW·-18-MP 2/3 DEPTH 8040 7-MAY -1990 I 1-JUN-1 'l90 I
I SW-18-MP 2/3 DEPTH GC~~ l ~i 7-MAY-1990 I 30-MAY-1990 I
I SW-·2(i·-/YIP SURFACE 002(1 7-MAY-1 '191) I 22-MAY-1991) I
I SW-20-MP SURFACE 81)41) 7-MAY-1990 I 1-JUN-1990 I
I Sl,J-2(1--Mi".' SURFACE DOD 7•-l't!AY-1990 I l 7·-MAY-1990 I I SW--20-MP SUPFACE COD 7-MAY-1990 I 21-MAY-1990 I
I SW-20-l'i'\~1 SL/1-,FACE GC~51~5 7-MAY-l.990 I 30·-·MAY·-1990 I I SW-20--~lP SURr--.:AcE TOC 7-MAY-1990 I 17-MAY-1990 I
I SW-2Ci-r-'li:· sur,FACE -r ,-, , .. ,
I._:,.::;) 7-MAY··· t ·,90 I 17·-MAY-1 '790 I
I SW--20-MP 2/3 [1EPTH 8020 7-MAY-1990 I 22-MAY-19','0 I
I SW--'.~1)-MP 2/3 DE~•Tli 804C, 7-MAY-199(, I 1-JUN-1990 I
I SW-·20-M~• 2/~J DEPTH BUD 7-MAY-1990 I 17-MAY-1990 I
I SW ·-2() ·-· !'\I-=' '":I ,' .. -. ..:...J -~ DEPTH ccm 7--f<IAY-19't1:, I 21-MAY--199(, I
I SW-2<)-MP 2/:J DEPTH GC~11 ~5 7-MAY-1990 i 30-·MA'(-1990 I
I SW--2(1-··Ml=-1 2/3 DEVTH TOC 7--MAY ·•· 1 r:,190 I 17-MAY-1990 I I SW-20-·MP '.2/3 [<EPHI rr-.,-, 7-MAY-1990 I 17-·MAY-1990 I .-::>::.:,
I SW-22-MP SUi~FACE E102c, "?*•IYIA\1 -1990 I 22-MAY-1990 I
I SW-22-·l'l'lP SUF,FACE 8040 i 7-MAY-1990 I 1-JUN-1 '·190 I
I SW-'.22-MP SUF,FACE E<DD I 7·-MAY·-1':;>9(1 I l 7-·MAY-1991:, I
I SW-2:2-·MP :::Ufo0 ACE COD I 7-·MAY-19l110 I 21-MAY-1990 I
I S~JJ-22-MI=-• sur,:FACE GC~ll~'.1 I 7-MAY-l'i"iO I 30--MAY-l 99(, I
I SW-·22·-r:!P SURFACE TOC I 7-MAY-1990 I 17-MAY-1990 I
I SW-22-MP SUF(FACE TSS I 7-MAY-1990 I 17-MAY-1990 I I SW-22-MP 2/3 DEPTH 0020 I 7-MAY-· 1990 I 22-MAY-1990 I I SW-22-l<IP 2/3 Dt:PTH 804() I 7-MAY-1990 I 1-JUN-1990 I
I SW-22-MP 2/3 DEPTH [10[1 I 7-MAY-1990 I 17-~IAY-1990 I I SW-:22·-MP 2/3 DEPTH CDD I 7·-MAY·· 1990 I 21-MAY-1990 I I SW-22-MP 2/3 D!:PTH Ge::; 15 I 7-MAY-1990 I 30-MAY-1990 I I Sl,J·-22--M~• 2/3 DEl".•TH TOC I 7-MAY·-1990 I 17-MAY-1990 I I SW--22-·MP 2/J DEPTH TSS I 7-MAY-1990 I 17-MAY-1990 I I SW F(Il'!SATE BLANf,:: 80:2(, I 7-MAY-1990 I 22-MAY-1990 I
I SIIJ FdNSATE BLANI< 8041) I 7-MAY~1990 I 1-JUN-1990 I
I SW R HlSATE BLAr!f,:: DOD I 7·-MAY-1990 I 17·-MAY·-1 •,'90 I
I SW RINSATE BLANf(: COD I 7-MAY-1990 I 21-MAY-19',0 I
I SW RINSATE BLANK GC~:015 I 7-MAY-1990 I 30--MAY-19'?0 I
I SW RirlSATE BLANf< TOC I 7-MAY-1990 I 17-MAY-1990 I
I SW RINSATE BLANI< TSS I 7-MAY-1990 I 17-MAY-1990 I
I TE< 80:20 I 7-MAY-1 C,'90 I 22-MAY-1990 I ---------------------·-------------------------------------------------------------------------------------------------------------------------------------------
I • YSTiJl•,it: HNlf~IJl111t:NTAL f,E:SIJaCES ANALYTICAL DIVISION • REPORT: Sample Status by Job for M90-05.16 page 1 Produced on: 5-JUL-1990 By: George R. Rusnak SAMPLE SOURCE I TEST I DATE SAMPLED I COMPLETED I 1----------------------------------------------------------.-----------------1 I BENTON I TE I 8O4OX I 2-MAY-1990 I 1-JUN-1990 I I BENTON I TE I SOL I 2-MAY-1990 I B-MAY-1990 I I SANDPACK I 8040X I 2-MAY-1990 I 1-JUN-1990 I I SANDPACK I SOL I 2-MAY-1990 I B-MAY-1990 I I CEMENT I 3040X I 2-MAY-1990 I 1-JUN-1990 I I CEMENT I SIJL I 2-MAY-1990 I 8-MAY-1990 I I X-30CP 2··4' I 8040X I 2-MAY-1990 I 1-JUN-1990 I I X-30CP 2-4' I SOL I 2-MAY-1990 I 8-MAY-1990 I I X-30CP 8-10' I 8040X I 2-MAY-1990 I 1-JUN-1990 I I X-JOCP 8-10' I SOL I 2-MAY-1990 I 8-MAY-1990 I I X-33CP 4-6' I 804OX I 2-MAY-1990 I l-JUN-1990 I I X-33CP 4-6' I SOL I 2-MAY-1990 I 8-MAY-1990 I I X-33CP 8-10' I 8O40X I 2-MAY-1990 I l-JUN-1990 I I X-33CP 8-10• I SOL I 2-MAY-1990 I 8-MAY-1990 I I X-40[A 2-4' I 8O40X I 2··MAY-1990 I 1-JUN-1990 I I X-40EA 2-4' I SOL I 2-MAY-1990 I 8-MAY-1990 I I X-40EA 6-8· I s,:140X I 2-MAY-1990 I 1-JUN-1990 I I X··40EA 6-8' I SOL I 2-MAY-1990 I 8-MAY-1990 I I X-41WA 2-4' I 8O4OX i 2-MAY-1990 I 1-JUN-1990 I I X-41WA 2-4' I SOL I 2-MAY-1990 I 8-MAY-1990 I I X-41WA 8-10' I 8040X I 2-MAY-199O I 1-JUN-1990 I I X-41WA 8-10' I SOL I 2-MAV-1990 I 8-MAY-1990 I I X RINSATE I 8040 I 2-MAY-1990 I 1-JUN-1990 I I X-9LF 2-4' I 8040X I 3-MAY-1990 I 1-JUN-1990 I I X-9LF 2-4' I SOL I 3-MAY-1990 I 8-MAY-1990 I I X-9LF 6-8' I 8040X I 3-MAY-1990 I l-JUN-1990 I I X-9LF o-8' I SOL I 3-MAY-1990 I 8-MAY-1990 I I X-9LF 12-14' 1-804()X I 3-MAY-1990 I 1-JUN-1990 I I X-9LF 12-14' I SOL I 3-MAY-1990 I 8-MAY-1990 I I X-42WA 2-4' I 804()X I 3-MAY-1990 I . 1-JUN-1990 I X-42WA 2-4' I SOL I 3-MAY-1990 I B-MAY-1990 I X-42WA 12-14' I 8040X I 3-MAY-1990 I 1-JUN-1990 I X-42WA 12-14' I SOL I 3-MAY-1990 I 8-MAY-1990 I X-42 18-20' I 8O4OX I 3-MAY-1990 I 1-JUN-1990 I X-42 18-20' I SOL I 3-MAY-1990 I 8-MAY-1990 I X-44WA 4-6' I 8040X I 3-MAY-1990 I 1-JUN-1990 X-44WA 4-6' I SOL I 3-MAY-1990 I B-MAY-1990 X-44WA 8-10' I 8O4OX I 3-MAY-1990 I 1-JUN-1990 X-44WA 8-10' I SOL I 3-MAY-1990 I 8-MAY-1990 -------------------------------------------------------------------------------
page J
I. SAMPLE SOURCE I TEST I DA--AMPLED I COMPLETED I
1----------------------------------------------------------------------------1
X RINSATE BLANK 8080 I 1-MAY-1990 I 31-MAY-1990
X RINSATE BLANK 8240 I 1-MAY-1990 I 31-MAY-1990
X RINSATE BLANK 8270 I 1-MAY-1990 I 31-MAY-1990
TB 8240 I 1-MAY-1990 I 31-MAY-1990 f TB 8240 I 2-MAY-1990 I 5-JUN-1990 ' . ----------------------------------·------------------------------------------------------------------------------------------------------------------------------
page ~ .;_
l f3AMi:•L E SOUf;:CE TE~iT I [I SAMPLED I COMPLETED I !--------·---------.. -·-------··---·-·--------·----·--------·-·----·------------------------------1
I X -_J:;cp 2-.. 4' CNTCL 1-l~AY-1990 I 21-MAY-1990 I
I X-35C~• 2-4' SOLCLP 1-MAY-1990 I 30·-MAY-1990 I
I X-35CP 2-4' DUPLICATE 8080X 1-MAY-1990 I 31-·MAY-1990 I
I X-35CP 2·-4 I 8UPL1CATE 8240X. 1-MAY-1990 . I 81 ·-MAY-1 'i'/0 I
I X-35CP 2-4' 1UPI_ I CATE 8270X 1-MAY-1990 I 31-MAY-1990 I
I X-35CP 2-4' DUPLICATE CLPl'-'IE -X 1-MAY-1990 I 30-MAY·-1 '790 I
I X-35CP 2-·4 I DUPLICATE CNTCL 1-MAY-l 'i90 I 21-MAY-1990 I
I X-35CP 2-4' DUPLICATE I SOLCL.P 1-MAY·-1990 I 30·-MAY--199(, I
I X-37CP 2-4' I 8080X 1-fYlAY-1990 I 31-MAY-1990 I
I X-37CP 2-4' I 824UX 1-MAY-1990 I 31-MAY-1990 I I X-37CP 2-4' I 8270X 1-MAY-1990 I 31-MAY-1990 I ' I X-37U:-' 2•-4 I I CL.PM!:: X 1--MAY-1990 -I 30-MAY-1990 I
I X-37CP 2-4' I C~ITCL 1-MAY-1990 I 21-MAY-1990 I
I X-37CP 2-4' I SOL.CLI=• 1 ·-MAY-1990 I 30-MAY-1990 I
I X-48CP 2-4' 8080X 1-MAY-1990 I 31-MAY-1990 I
I X-48CP 2--4' 8240\ 1-MAY-1990 I 31-MAY-1990 I
I X-48CP 2-4: 827();( 1-MAY-1990 I 31-MAY-1990 I
I X-48CIC' 2-4' CLPME -X 1-MAY-1990 I 30-MAY-1990 I
I X-48CP 2-4' Cr-lTCL. 1-MAY-1990 I 21-MAY-1990 I
I X-48CIC• 2-4' SOLCLP 1-MAY-1990 30·-MAY-1990 I
•I SW-24-· EA 808() 2-MAY-1990 5-·JUN-1990 I
I SliJ-24-EA 8240 2-MAY-·1990 5-JUN-1990 I
I SW-·24-EA 8270 2--MAY-1990 5-·JUN-1990 j
SW-24-EA cu=-1ME ·2-MAY-1990 30·-MAY-1990 I SW-24-EA Cl'HC:.. 2-MAY-1990 21-MAY-1990 I SW·-24-EA DUPLICATE fj(.18(.1 2·· MAY-1990 ':,-JUN-1990 I SW-24-E:A DUPLICATE B241.) I 2-·MAY-199<) 5-JUN-1990 I SW-·24·· f:A DUf'.•L 1.CAH: 827(.1 I 2-MAY-199(, 5·· JIJN-1991) I
SW-24-EA DUPLICATE CL~•r,IL' I 2-·~IAv'-19')0 30-1YIAY-!990 j
SW-24-EA DLJi:•L lC/'.iTE CI\ITCL I '.:;.1-l'l'IAY-199(1 21-·M/'.iY-199(, I SW-26-·EA BOfJ(i I 2·-i"IAY-1990 5--JUN-1990 I SW-26-EA 82-'k• I 2-MA\-1990 i 5-JUN·-1 'i90 I
SW-26-EA s:~ 7•) I 2-MAY-1990 I ;:;--JUN-· 1990 I SW-26·-EA CL.PME I 2 ·MAV·-1990 I 30-MAY-l't90 I SW-·26-·EA ·CNTC:L I 2-MAY-1990 I 21-MAY-1990 I
SW-34-WA 808(, I 2-MAY-1990 I 5-JUN-1990 I SW-34-WA 8240 I 2-MAY-1990 I 5-·JUN-1990 I SW-34-WA 827(, I 2-MAY·-1990 I ::;-J"UN-1 990 I SW-34-·WA CLPME I 2-MAY-1990 I 30-MAY-1990 I Sl~-34-·WA CNTCL I 2-MAY-19')0 I 21-MAY-1 'i'90 I SW RINSATE BLAN!< 8080 I 2-MAY-1990 I 5-JUN-1990 I
SW F'1NSATE i!LAtJf< 8240 I 2-MAY-1990 I 5-JUN-1990 I SW Rlr-lSATE BLANK 8270 I 2-·MAY-1990 I 5-JUN-1990 I SW RU~SATE BLAl\1t:: CLPl~E I 2-MAY-1990 I 30-MAY-1990 I SW F<INSATE BLANfC: CNTCL I 2-MAY-1990 I 21-MAY-1990 I SW-40 808(, I 2·-MAY-1990 I 5-JUN-1990 I SW-40 8240· I 2-MAY-1990 I 5-JUN-1990 I
SW-40 8270 I 2-MAY-1990 I 5-JUN-1990 I
SW-40 CLPME I 2-MAY-1990 I 30-MAY-1990 I SW-4(, CNTCL I 2-l~AY-1990 I 21-MAY-1990 I SW-41 8080 I 1-MAY-1990 I 5-JUN-1990 I
SW-41 8240 I 1-it!AY-1990 I 5-JUN-1990 I t,W-41 fJ270 I 1-~IAY-1990 I 5-JUN-1990 I SW-41 C:LPl~E I 1-MAY-1990 I 30-MAY-199<:;
SW--41 CNTCL I 1-MAY-1990 I 21-MAY-1990 SW-41 ( I CS i CL~1ti'lE I l-Mf'.\Y-199(, I 30-MAY-1 99(,
I
aYSTOl~E ENVIf.:01.!~EI-HAL RESO,CES
-ANALYTICAL DIVISION
REPORT: Sample Status by Job for M90-05,5
page 1
Produced on: 5-JUL-1990 By: George R. Rusnak
SAMPLE SOURCE I TEST I DATE SAMPLED I COMPLETED I 1----------------------------------------------------------------------------1
I SW-12FP 2/3 DEPTH I 801:J(; I 1 ·-MAY-1990 I 31-MAY-1 't90
I SW-12FP 2/3 DEPTH I 8240 I 1-MAY-1990 I 31-MAY-1990
I SW-12FP '"\ I ,-., ..::..1 ..:i DEt:•TH I 8270 I 1 ·-MAY-1990 I 31-MAY-1990
I SW-12FP 2/3 DEPTH I CLPME I 1-MAY-1990 I 30-·MAY-1990
I SW-12FP 2/3 DEPTH I CI-HCL I 1-MAY-1990 I 21-MAY-l.990
I SW-12FP 2/3 DUPLICATE I 8081) I 1 -Ma:\ Y-1 990 I 31-·MAY-1990
I SW-12FP 2/3 DUt:•L ICAT[ I 8240 I l. -MAY ·-199(> I 31-MAY-1 't90
I SW-12FP 2/3 DUPLICATE I 8270 I 1-MAY-1990 I 31-MAY-1990
I SW-12FP 2/3 DUPL. ICAH: I CLi='r-1E I 1-MAY-l.990 I 12-MAY-1990
I SW-12FP 2/3 DUPLICATE I CNTCL I 1-MAY-1990 I 12-MAY-1990
I SW-12Ft:• 2/3 DUPLICATE I DlOX I 1-MAY-1990 I 12·-MAY-1990
I SW F,INSATE BLANI< I 8081) ·1 -l-MAY-1990 I 31-MAY-1990
I SW RINSATE BLANK I (324(i I 1-MAY-1990 I 31-MAY-1990
I SW RINSATE GI_ANI< I 8271) 1-MAY-1990 I 31-!YIAY-1990
I Sl~ HINSATE BLAN~( I CLPME 1 ·-MAY-1990 I 30-MAY-199(, I
I SW RINSATE BLANI( I CNTCL 1-MAY-1990 I 21-MAY-1990 I I X-6LF 3-5' I 808CiX 1-MAY-1990 I 31-MAY-1990 I I X-·6L F 3•~5 I I 8240X 1-MAY-1 'r90 I 31-MAY-1990 I I X-6LF "j C: I ....,-._. I 8270X 1-MAY-1990 I 31-MAY-1990 I
. I X-6LF 3-5' I CLPME -X 1-MAY-1990 I 30-MAY-1990 I I X-6LF 3-5' I CI-HCL 1-MAY-1990 I 21-MAY-1990 I
I X-6LF 3 ~--._1 I SOLCLP 1-MAv°-1990 I 30-MAY-1990 I
I X-17FL 4-6' I 8080X 1-MAY-1990 I 31-MAY-1990 I
I X-17FL 4-6' I 8240X 1-MAY-1990 I 31-MAY-1990 I
I X-17FL 4-6' I 8270X 1-MAY-1990 I, 31-MAY·-1990 I
I X-17FL 4-6' I CLP~IE " 1-MAY-1990 I 30-MAY-1990 I -~
I X-17FL 4-6' I CNTCL 1-MAY-1990 I 21-MAY-1990 I
I X-17FL 4-6' I -SOLCLP 1-MAY-1990 I 30-MAY-1990 I
I X-18FL :2-4 I I 80[i0X 1-MAY-1990 31-MAY-1990 I
I X-18FL 2-4' I 824UX l-i•IAY-1990 31-MAY-1990 I
I X-18FL 2•-4 I I 8'.270X 1-MAY-1990 31-MAY-1990 I
I X-18FL 2-4' I CLPME -X 1-·MAY-1990 30-l~AY-1990 I
I X-18FL 2-4' I CNTCI_ 1 ·-MAY-1 ?90 .21-MAY-1990 I I X-1£lFL :2-4' I SOLCLP 1-MAY-1990 30-MAY-1990 I
I X-21FL 2·-4' I 8080X. 1--MAY-1990 31 ·-MAY-1990 I
I X-21FL 2-4' I 8240X l -MAY-· 1990 '31-MAY-1990 I
I X·-21FL 2-4' I 8270X 1 -MA 'y -1 990 31-MAY-1990 I
I X-2l.FL 2-4' I CLPME _:X 1-MAY-1990 30-MAY-1990
I X-21FL 2-4' I CIHCL 1-MAY·-1990 21-MAY-199(,
I X-21FL 2-4' I SOL.CLP 1-IYIAY-1990 30-MAY-1990
I X-26FL :2-4 I I 8080X 1-MAY-1990 31-MAY-1990
I X-26FL 2-4' I 8240X 1-MAY-1990 31-MAY-1990
I X-26FL 2-4' I 8270X 1 ·-MA'i-1990 31-MAY-1990
I X-26FL 2-4' I CNTCL 1-MAY-1990 21-MAY-1990
I >--26FL 2--4' I SDLCLP 1·-MAY·-1990 31-MAY-1990
I X-35CP 2-4' I 8080X 1-MAY-1990 31-MAY-1990
I X-35CP 2-4' I 824CX 1 ·-MAY·-1990 31-MAY-1990
I X-35CP 2•-4 I I 8270X 1-MAY-1990 31-MAY-1990
I X.-35CP 2-4' I CLPME X -1--MAY-1990 30-MAY-1990
REPORT: Sample Status by Job tor M90-04.91
Produced on: 5-JUL-1990 By: George R. Rusnak
I SAMPLE SOURCE I TEST I DATE SAMPLED' I COMPLETED I
1---------------------------------------------------------------------------1
STEAM CLE_Ar!ER 808(, 23-APR-1990 31-MAY-1990 I
STEAM CLEANER 8240 23-APR-1990 31-MAY-1990 I
STEA~I CLEANER 827(: 23-AIC'R-1990 31-MAY-1990 I
STEAM CLEANER CLPME 23-APR-1990 30-·MAY-1990 I
STEAM CLEANER CIHCL 23-APf-,-1990 4-MAY-1990 I
MUNICIPAL WATER 80:'3() 23-APR-1990 31 -·MAY-1 990 I
I MUN IC I f'.'AL WATER 8'.24(1 23-APR-1990 31 ··MAY-1990
I MUNICIPAL WATEF, 8270 23-APR-1990 31-MAY-1990
I MUN IC I ::•AL l~ATEr, Cl.PMC 23-A~1r-.;: --1 c;·9(i 30-MAY-1 '79(,
I MUNICIPAL WATER CNTCL 23-APF?-1 9'10 4--MAY-1990
I ORGANIC FREE WATER 80lJ(1 23-APR-1990 31-MAY-1990
I ORGANIC FREE WATER 8240 23·-APR-1990 31-~IAY-· 1990
I ORGANIC FREE WATEG: :.327() 23-Ae-•R-1 •790 31-MAY-199(1
I Of\Gf-\NIC FREE WATER CLPiYIE 23-APf,-1990 I 30-MAY-1990
I ORGANIC FREE WATER Cl·HCL 23-APR-1990 I 4-MAY-1990
I X-75A CLPM[ -X 26-·APf~-1990 I 30-MAY-1990
I X-7':•A Cl'JTCL 26-APR-1990 I 4-MAY-1990
I X-75A SOLCLP 26-APR-1990 I 30-MAY-1990
I X-758 i3240X 26-APR-1990 I 31-MAY-1990
.I X-75C 8080X · 26-APF,-1990 I 31-MAY-1990
I X-75C 8270X 26-APR-1990 I 31-MAY-1990
I X-76 8080X 26-APR-1990 I 31-MAY-1990
I X-76 8270X 26-APR-1990 I 31-MAY-1990
I TB 8240 26·-APR·· 1990 I 31-MAY-1990 --------------------------------------------------------------------------------------------------------------------------------------------------------------
.·: . '1,.
f-.... ' ~~
t;;!'..j_t
,\J ,-ti,: \~i; ~~-~ tl·::J;
'~
f. I ' ~ >,lli,;;, ' -l':'f;,.:i::, ..... "';'¼,', .. ,. ~tj~t;?r; ,~~~ti 4.r,:k·Hi ~i:~r;i}~~
• • KEYSTONE
ENVIRONMENTAi. RESOURCES, INC.
Phone: [phone] Tech Center Dr., Monroeville. PA 15146
March 15, 1990
Ms. Barbara Benoy
NC/SC Site Management Unit
Superfund Branch, Waste Mgmt. Div.
US EPA Region IV
345 Courtland Street, NE
Atlanta, GA. 30365
Dear Barbara:
Fax:[phone]
Ref. No.179225-04
fff.Ct:IVEO
MAR 1 6 1990
SUPERFUND SECTION
On behalf of BM&S, enclosed please find five copies of the Field Sampling Plan
final Remedial lnvesti ation and Feasibili Stud at the former Koppers
ompany, Inc., facility in Morrisville, N.C., which has been revised based upon your
letter dated February 23, 1990. As discussed with you during our meeting in Atlanta,
we have attempted to address each comment; however, in your review should you
find this not to be the case, please call Shannon or me to discuss.
By copy of this letter, two copies of this Plan are being submitted to the State of
North Carolina.
/'\"£'C"'ni;,LJ,,,
lnc. Mitsak
Senior Project Manager
JCM/s
attachments (5)
cc: Ms. Lee Crosby -State of N.C.
Ms. Shannon Craig -BM&S
• • UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
REGION IV ·RfCfll!fO
345 COURTLAND STREET. N.E.
MEMORANDUM
ATLANTA. GEORGIA 30365 JAN i 2 1990
SUPERFUND SECTION
DATE:
SUBJECT:
FROM:
TO:
J.A.N 1 7 1990
Draft Field Sampling Plan
Koppers Superfund Site
Morrisville, North Carolina
·Barbara H. Benoy 6--.Je:;
Remedial Project Manager
Addressees
Attached for your review is a copy of the draft Field Sampling Plan
for the Koppers Superfund Site located in Morrisville, North
Carolina. Please return your comments to my attention by February 7,
1990. If you are unable to meet this due date, please inform me as
soon as possible as to when I may expect your comments.
If you have any suggestions or comments concerning this site, please
do not hesitate to contact me. I can be reached at 404/347-7791.
Addressees: Doug Lair, ESD
Elmer Akin, WasteMD
Bernie Hayes, G-WTU
Pat DeRosa, NCSFB
Lee Crosby, NCSFB
memo only * /
memo only*
* North Carolina Superfund Branch Personnel received
copies of the subject plan directly from the PRP as per
the Administrative Order to conduct this RI/Fs. ·