NCD003200383_19870424_Koppers Co. Inc._FRBCERCLA SPD_Application for Change in Classification-OCR

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KEYSTONE
£:-;'\'IRO!\ME;-.;TAL RESOURCES, !SC.
436 Seventh Avenue, Suite 1940, Pittsburgh, PA 15219
Dear Sir:
April 24, 1987
Solid & Hazardous Waste Management Branch
Division of Health Service
P. O. Box 2091
Raleigh, N. C. 27602
Attn:
RE:
w. L. Meyer
Koppers Company
I. D. No. NCO 003200383
Enclosed is an Application for Change in Clissification under RCRA.
As you may know, Koppers has sold the manufacturing portion of this
facility to Unit Structures, Inc. Koppers has assigned the
administration of environmental liability to Keystone Environmental
Resources, Inc.
If you have any questions concerning Koppers' involvement at the
Raleigh site, please contact me at [phone].
MMS/mrw
Enclosure·
cc: J. R. Campbell
M. J. Dvorsky
Pat DeRosa
Sincerely yours,
Martin M. Schlesinger
Assistant Program Manager
Koppers Previously Operated Properties
· wo/ Attach.
"
(NC. OHR)
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Department of Human Resources R .. t.1 c1r::1.1 ~'..A!'-1.T
Division of Health Services
Solid and Hazardous Waste Management Branch
APPLICATION FOR CHANGE IN CLASSIFICATION UNDER RCRA
Date:
Company Name:
Company Address:
EPA ID No: )Je-/) ,103 2-60 3Ef;?
/c/c,# 'fl l-22 ?-2,f;'d''Lf
Mr. William L, Meyer, Head
Solid & Hazardous Waste Management Branch
Division of Health Servic
Post Office Box 2091
Raleigh, N.C. 27602
Dear Mr. Meyer:
Our Company requests the following change in its classification under RCRA
(check all that apply):
Add As Delete As
D Cil Generator
□ [J Transporter
□ □ Treater
D [] Storer
□ _[] Disposer
00 D Small Generator
The reason for this request is:
H -t_.L .foe< A -(-q('A er.-~ 1w ?t v---' "-~ ( "-..._L. ...( ( ....
I /
;7c /J.,.,= ,.o-t<« ./. /~ • ~ cc •• "s /',./ re ✓,j ~J-e "'
NOTES: 1) Be specific. Give all pertinent information. This may he a change
in your process; a change in your handling procedures; new
analyses, or the like.
2) This is not a delisting petition with respect to a listed waste,
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Although Koppers does not currently generate hazardous waste, we wish to
retain our I.D. tlumber. Koppers anticipates the need for an I.D. Number
during possible future remediation actions. The need for these remedial
actions is currently bein~ discussed with the N.C. DHC, Solid & Hazardous
Waste Management Branch.
~;:~ a,~-~;9~~ r Koppers 1
Previously Operated Properties
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...-;:.-sr-:::r;---.., ?:~~~,,~-~ ..... ., ~~t\.
fa ~i1~~ .. l1\ ;v '~_·r : ·•.t _:.J: ; \~ .. -·
North Carolina Department of Human Resources
Division of Health Services
P.O. Box 2091 • Raleigh, North Carolina 27602-2091
James G. Martin, Governor
Phillip J. Kirk, Jr., Secretary
Ronald H. Levine, M.D., M.P.H.
Ms. Denise Smith
EPA NC CERCLA Project Officer
EPA Region IV Waste Division
345 Courtland Street, N.E.
AtlanLa, GA 30365
Dear Ms. Smith:
SUBJECT: Summary Trip Report
22 January 1987
Koppers Co., Inc. NC D003200383
Hwy. 54 West
Morrisville, NC 27 560
Site Investigation, December 17, 1986.
State Health Director
Tne Koppers Co., Inc. site is located on a 53 acre tract on Hwy. 54
West in Morrisville, NC. A company called Unit Structures first produced
glued-laminated wood products on this site around 1955 until 1962. Koppers
purchased the site in 1962 and continued the glue-laminating process. From
1968 to 1975, Koppers used the southeast portion of the site for wood
_treatment with pentachlorophenol (PCP). Wood treatment was discontinued on
site around 1976, however, laminated wood production continued. The plant was
sold in September 1986. Koppers retained 10 acres of the original site
including the areas where PCP contamination was known or likely to have
occurred. The remainder of the site has been sold back to Unit Structures.
Koppers notified as a generator, transporter at this site. However, no Part A
application for interim status was filed and no closure permits have been
issued.
Wastewater lagoons from the PCP treatment process were closed by
Koppers in 1976. The liquid from the lagoons was sprayed over a portion of a
field in the northeast corner of ·the property and the sludges were mixed with
soil surrounding the lagoons. Soil samples collected by Koppers in the spring
and fall of 1980 led to the removal of PCP contaminated soil from the site.
Subsequent studies have been conducted by Koppers and US EPA Region IV. To
date, PCP has been measured in soil, groundwater, and pond sediment on site.
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Ms. Denise Smith
22 January 1987
Page 2
The northern portion of the site drains to a ditch which crosses
under the railroad tracks and Hwy. 54 and flows to the northeast. The rest of
the site drains to Koppers pond. The pond has an outlet to the south which
drains to another pond on residential property across the road. City water is
not.available in the area immediately surrounding the site. Residents and
business are dependent on private wells for water supply.
NC CERCLA Unit personnel Pat DeRosa and Mark Durway initiated a site
inspection of the Koppers site on December 19, 1986. Since an on-site
inspection was postponed awaiting a meeting with Koppers representatives,
off-site well sampling was planned to address contaminant migration and
potential public health concerns. We arrived at the site at approximately
1000 hours. We drove around the perimeter of Koppers property in order to
identify and locate off-site wells previously sampled. Based on previous
sampling, topography, and prior contact with off-site well owners, 6 wells
were selected for sampling.
We began sampling at 1115 at Triangle Materials approximately
.5 miles southeast of the site. This well should serve as a background
groundwater sample. We subsequently sampled the residential wells at the
homes of James Crowe, William Barbee, George Harding, John Medlin, and Louis
Barbee. These wells were purged prior to sampling except where owners
cautioned us against running the well dry. Samples were collected for
volatile and extractable organics, inorganics, and low concentrations of acid
extractable phenolics (i.e. PCP). Samples were preserved accordingly and
submitted to the NC State Laboratory of Public Health for analysis.
On January 7, -1987, we returned to the site to meet with Koppers
representative, Mike Dvorsky, and Jim Campbell and Marty Schlesinger of
Keystone Environmental Resources (KER). KER works under contract with Koppers
to provide laboratory services. We toured Koppers' portion of the site and
obtained background information on the former PCP treatment operations. We
also discussed site sampling and cleanup activities which had been conducted
at the site to date. Additional sampling data and hydrogeologic information
is forthcoming from Koppers and KER.
If you have any questions, please contact me at [phone].
PD/tb/0338b
Sincerely,
~J-e/0t---
Pat DeRosa, Waste Management Specialist
CERCLA Unit
Solid and Hazardous Waste Management Branch
Environmental Health Section
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TO:
FROM:
RE:
File
Pat DeRosa ~
Koppers Co., Inc.
NC D003200383
8 December 1986
I spoke by telephone with Mike Dvorsky, Koppers Co., Inc.,
Pittsburgh, PA [phone], regarding the current status of the subject
site. Mr. Dvorsky confirmed that a cleanup was conducted at the Morrisville
plant in July 1986. Post cleanup samples were collected in September 1986
however sample analysis has not yet been completed. Mr. Dvorsky indicated
that on and off site well sampling had been conducted, however he was not
familiar with the specifics of the sampling or analyses. He said that Jim
Campbell of Keystone Environmental Resources was familiar with the sampling
and analyses of the samples and that he would have Mr. Campbell contact me
with the details. Mr. Dvorsky indicated that if we collected additional
samples at the site, Koppers would like to split samples with us. He will
contact me about arranging an on-site meeting.
PD/tb/0176b
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Dear Pat,
KEYSTONE
ENVIRONMENTAL RESOURCES, INC.
436 Seventh Avenue, Suite 1940, Pittsburgh, PA 15219
January 26, 1987
Solid and Hazardous Waste
Management Branch
North Carolina Department of
Human Resources
P. O. Box 2091
Raleigh, NC 27602-2091
Attention: Pat DeRosa
Waste Management Section
Re: Koppers Morristown Site
Information Request
Enclosed is the information you requested in
letter which we discussed during our visit.
mation is enclosed:
your December, 1986
The following infor-
1. Letter to Mr. Paige, from D.R. Kerschner, dated February 14,
1986 which discusses the soil removal from the area of the
former lagoons.
2. Letter to Mr. R. A. Fisher from R. K. Garner (GSX) dated
July 24, 1986 covering the actions of GSX during the soil
removal.
3. Memo to S. M. Tymiak from R. A. Fisher, dated August 25, 1986
titled "Final Report, Soil Removal Project, Raleigh, NC".
4. Site Maps (2) showing locations of borings, monitoring wells.
5. A short history of the lagoons and their closure.
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Page 2
North Carolina Department of Human Resources
January 26, 1987
6. A letter, addressed to the families which participated in our survey of off-site domestic groundwater quality. As we dis-cussed during our meeting, Koppers will release the results of this investigation upon its completion.
The analysis of the soil samples taken during the soil removal are currently in progress. However, due to the large number of analyses of this type in our laboratory, I do not foresee receiving the results until late February. They will be forwarded to your office when I re-ceive them.
Please feel free to call me at this office if you have any questions regarding this submittal or our activities at the site.
MMS/wl
Enclosures
cc: J. Blunden
J. Campbell
M. Dvorsky c. Beck
C. Cramer
155500
Sincerely yours,
Martin M. Schlesinger
Assistant Program Manager
Previously Operated Properties
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CERTIFIED MAIL
Dear Mr. Paige:
~36 Seventh Avenue. r~1nsbu1gh, J-'A l~Ll':l
Telephone 4 i 2-227•2000
February 14, 1986
Mr. William Paige
Solid and Hazardous Waste
Management Branch
Division of Health Services
P.O. Box 2091
R~leigh, North Carolina 27602
As we discussed in our telephone conversation this afternoon,
Koppers is in the process of evaluating the immediate removal of
pentachlorophenol-containing soil from the former wastewater
lagoon area at our Morrisville (Raleigh) plant. I had contacted
your agency so that the plant could either reactivate its old EPA
ID number or obtain a new number; the plant's former number was
de-activated due to the lack •Of hazardous waste activity.
Pursuant to that, I understand that you will be sending me the
paperwork to obt~in a new ID number. ·
You had also requested that I explain our proposed activity at
the site. We are presently evaluating the removal of K001
materials in che area which contain pentachlorophenol at or above
10 mg/Kg (ppm). ·You can refer to our November, 1984 report to
examine soil quality data from the area. My estimates indicate
that approximately 1100 cubic yards of soil are involved. This
material would be trucked to the GSX landfill in Pinewood, SC,
assuming that full approvals are obtained.
The lack of an EPA ID number is the only thing holding up our
application to place this material in .Pinewood. Upon that
approval, the project must be approved by Koppers management
before contracts can be awarded. Thus, at this ppint, the
project remains in a ''proposed'' status.
You had also indicated that your Agency would have to review our
proposed actions, including our 10 mg/Kg clean-up level. It is
not our intent to have this pioject generate any discussions
concerning clean-up levels which would delay the project.
Koppers feels that the proposed remediation is necessary and
should be pursued without delay.
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WILLIAM PAIGE
PAGE TWO
FEBRUARY 14, 1986
I appreciate your assistance in this matter. If you have any
questions or comments, please call.
DRK/bj.
cc: L.C. Beck (Raleigh)
W. J. Baldwin
Very truly yours,
CJ<v;'{ ,{! ~cL_____
David R. Kerschner
Manager, Environmental
Regulatory Programs
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Hr. Robert A. Fisher
KOPPERS COill'ANY, INC.
436_.Seventh Avenue
Pittsburgh, PA 15219
GSX Services, Inc.
Emergency, Rernedi2/ &
Technical Projecls Gtoup
PO. Box210
t':.~idsville, North Carolina 27320
(919) 3<2-6106
(9i9} 272-2222 (Emergency Response)
July 24, 1986
Re: Contaminated Soil Removal Project; Morrisville, NC
Dear Hr. Fisher:
Please find below a final report of the work that GSX Services, Inc. (GSX)
performed at the Morrisville, NC site.
This information is summarized by day.
July 2.,_ 1986 .::. Monday
GSX mobilized one (1) Project Manager and two (2) Equipment Operators from
its Reidsville, North Carolina facility. The GSX crew arrived on site
and met with you. Upon our arrival you gave us a preliminary site tour
discussing boundaries, waste areas, schedules, etc. All questions and
initial problems were ans·.ered and solved. ·The GSX crew then left the
sit2.·
July~ 1986 .::_ Tuesday
The GSX ere;;, arrived on site at 7:45 a.m. only to find that the excavator
had not arrived. Upon the completion of several phone calls, the excavator
arrived at 8:45 a.m. It was unloaded and excavation of the "one (1) foot
designated area" was begun at 9:20 a.m. All material was stockpiled by our
GSX front-end loader. Hike Hilchuck, our GSX Technical Sales
Representative, arrived for a site visit.
At 5:00 p.m., we decided that approximately 20-25 truckloads of material
was stockpiled and ready for the next day's pick-up. We left the site at
6:00 p.m.
July .2..L. 1986 .::. Wednesday
We arrived on site at 5:35 a.m. Using both pieces of equipment, we began
loading trucks at 6:10 a.m, We loaded seventeen (17) dump trucks. Upon
their completion, the GSX crew continued stockpiling material for the next
day's loading. We left the site at 1:30 p.m.
GENSTAR
A Gi::nstar Ylas1e
Services Company
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Mr. Robert A. Fisher
KOPPERS CO'.·!PANY, INC .
.July 24, 1986
Page -2-
July~ 1986 .:::_ Thursday
We arrived on site at 5:40 a.m. The GSX crew did a preventive maintenance
check on site equipment. Again, using both pieces of equipment, we began
loading trucks at 6: 10 a.m. GSX loaded nineteen (19) trucks. Stockpiling
continued. We left the site at 2:00 p.m.
July·__JJ_,_ 1986 .:::_ Friday
Arrived on site at 5:45 a.m. The GSX crew began loading trucks at 6:10
a.m. CSX loaded eighteen (18) trucks. The CSX crew demobilized to
Reidsville, NC. (1/2 day charge)
July _ll_,_ 1986 .:::_ Sunday
Mobilized Project Manager and one (1) Equipment Operator from Reidsville,
NC.
July .l::_,_ 19S6 .:::_ Monday
Arrived on site at 5:30 a.m. Front-end· loader began loading trucks at 5:50
a.m. Finished loading twenty-one (21) trucks at 9:20 a.m. Equipoent
Operator skimmed areas designated by yourself for the next day's loading.
We left the site at 1:00 p.m.
July _s 1986 .:::_ Tuesday
Arrived on site at 5:45 a.m. At 6: 10 a.m. the Equipment Operator began
loading the first truck. At 7:00 a.m. the front-end loader received a flat
tire. A service call was made and the loader continued at 9:30 a.m. All
trucks were finished loading at 11:20 a.m. We left the site at 11:45 a.m.
(1/2 day charge)
Please note that there will be a change in some of the "Daily Costs"
sheets. Task I (Protective Clothing) is a "per day" charge. This pertains
to whether we worked a full or· partial day. I apologize for any
inconvenience that this might cause.
Final Summary
CSX excavated, stockpiled and loaded eighty-four dump truck loads of
contaminated soil and debris from the Morrisville area. Total work time
was five (5) full eight (8) hour days and two (2) half days.
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Mr. Robert A. Fisher
KOPPERS COXPANY, INC.
July 24, 1986
Page -3-
Should you have any questions conceriing the ~ork performed or the disposal
of the materials, please do not hesitate to contact us. We at CSX look
forward to working. with Koppers in the future.
Sincerely,
#~,;L~-
Randy K. Garner
Project Manager
ERT Group
RKG/dwb
cc: Mike Hilchuck
Robert Stephens
Dave Sprinkle
Larry Davis
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Subject
Interoffice Correspondence
S. M. Tymiak
K/1928
FINAL REPORT
SOIL REMOVAL PROJECT
RALEIGH, NC
From
Location
Date
R. A. Fisher
K/1928
August 25, 1986
:
7, 1986 CSX Services Inc .. mobilized Monday, July
initiating the Raleigh soil removal project.
concentrated. on three (3) specific areas:
The clean-up
Former Lagoon Area
Filter Bed Area, and
The Blowndown Pit Area.
Location of subject areas within the Raleigh Plant Site are
shown on Figure 1. _ .
Excavation and stockpiling of PCP contaminated soil from
the Lagoon Area commenced Tuesday; July 8, 1986. The first cor.-
voy of trucks arrived Wednesday, July 9th. Figure II depicts
graphically the location of old lagoons, extent and depth of ex-
cavation,' and a 200 ft. x 100 ft. grid sampling network. Approx~
imately 110® cu .. yds. of contaminated soil was excavated and re-
moved from the 20, 000 sq. ft. area encompassing the old lagoons.
The filter Bed Area contained about 50 cu. yds. of contaminated
concrete, piping and soil. The Blowndown Pit Area consisted
of approximately 100 cu. yds. of contaminated soil.
All contaminated material,,. totalling 1250 cu. yds. (1552 tons)
was manifested and transported to Pinewood Landfill,
South Carolina.
Upon completion of all excavation and transport activities,
soil surface samples were collected at all three (3) subject
areas; former Lagoon Area (forty-eight (48) samples at designated
locations), Fllter Bed Area (one (1) sample), and Blowdown Pit
(one (1) sample). All samples were shipped to Monroeville
July 15, 1986.
Sheet 1 of 2
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Site restoration commenced July 16, 1986 with the backfilling of
subject areas. Fill dirt consisted of silt and topsoil. Due to
previous excavations, performed in 1980 around the Cellon Treating
Area and Old Lagoons, the req~red volume of fill dirt "as doubled.
All excavated ·areas were restored to grade level and seeded. The
entire soil removal project was finalized and completed July 22,
198 6.
Negotiations with sub.contractors throughout the project ·and. utilization
of cost effective measures resulted in savings of over $60, 000. ;The
attached chart delineates the scope of completed work and final costs.
RAF:m
Enclosures
Copies to:
M. R. Urbassik
M. Dvorsky
D.R. Kerschner
J. R. Campbell
File
R. A. TISHER
Sheet 2 of 2
-------
Area
ill£@ + EXJSTJN(i IIELLS
. -t PflO"{)SEO WELLS
Excavated Material fro•m
·Blowdown Pit, Filter Bed and
Former Lago_on Areas.
----

-
---SOIL REMOVAL PROJECT
RALEIGH, NORTH CAROLINA ..
--
--
----------W-2 +
Filter Bed Area
F'I/1c /U",n
SO.££ (FEET/
I I I
0 7J JStJ
----
ncsi«t.JCE
R. A. Fisher
8-18-86
FIGURE I
..
I '~-RALEIGH, .NORTH CAROLINA
\ FORMER LAGOON AREA
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PIEA A I
EXCAVATED i211 OF SOIL I,--,
t~~GHO~-T INSCRIBED I✓
AIEA B -: 7
EjCCAVATED 36" OF SOIL~-
'Jl{ROUGHOUT INSCRIBED I
AREA. .
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,
10, ... -
. ., -· ·-1 .i-/ ·,
0
LEGEND:
0 .SOIL SURFACE SAMPLES
TAKEN AT EACH.
LOCATION {48 SAMPLES)
1/
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0
o·
. v.,.) ~
0 ~")
0 &'
0
,.0
0 '-~
0 o.
0 0 C
~
OUTLINE OF 01
LAGOON
R.A. FISHER·
8-18-36
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100
-- -- - -- -
11!!!!!!!!1
0
□
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CEHETARY~
FISURE 1
-Jt'Ell
SCALE (FEEn RALE~~;:;~:. MAP 'ISVILl.E. 0 100 200 300
KOPPERS coMP.i.NY • IHC. .,
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100
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SCALE (FEET)
0 100 200 300
- - - -
0
~
CEMETARY~
~
FI6URE e,._
BOA.ING-
LOCATION
RAlEIGH/HORRI;~ll
KOP £, ERS COMi>ANY, INC.
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PROCESS HISTORY
The Koppers' Raleigh plant produced glued-laminated wood products
from 1962 to 1986 when it was sold to Unit Structures.
Production has continued Unit Structures management. The plant
initially used untreated wood and wood preserved with fluor
chrome arsenate phenol (iCAP), Type A. No treating of this
material occurred at the site. In 1968 the CELLON process was
installed at the site to produce treated wood for use as a raw
~aterial. This treatment consisted of pressure injecting
pentachlorophenol (PCP) in a liquified butane isopropyl ether
solution into the wood. After the impregnation was completed,
the butane carrier evaporated, leaving the pentachlorophenol as a
dry, crystalline salt. The CELLON treatment plant was located in
the southeastern portion of the site, near the existing fire
pond. The CELLON treatment process was discontinued in 1975,
after which treated wood was imported from other facilities.
Excess PCP salt was removed from the wood by steaming. The wash
solution was treated to recover PCP after which it was discharged
to the fire pond until the two treatment lagoons were installed
approximately six (6) months after start-up. After the CELLON
process was discontinued, the lagoons were ''closed.'' The closure
process consisted of spraying the residual liquid over a portion
of the field northwest of the steel shop and mixing the remaining
sludges with the soil surrounding the lagoons. Fertilizer was
added in both operations to enhance biodegradation of the
pentachlorophenol.
From the recollection of knowledgeable employees at the facility
and prior written memos, it is evident that the CELLON process
did experience operational problems over the course of its
operation which may have contributed to the escape of PCP to the
environment. Spills of process chemicals may also have led to
soil contamination in storage a~d process plant areas.
Chronology of Environmental Activities
In January of 1971, after a heavy rain, about 200 fingerlings
were found dead in the Medlin Pond. The Medlin Pond is located
downstream of the overflow of the Koppers' fire pond on the
property of a private residence. To avoid a repeat of this
incident, the Koppers' pond overflow was by-passed around the
Medlin Pond until about 1980.
In mid-1975, the CELLON process was shut down and the equipment
was dismantled and sold where possible.
Following the shutdown of the CELLON Process, water samples were
taken from the fire pond in the summer of 1976 to determine if
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the pond water could support fish. PCP levels of less than 1 ppm were recorded with higher levels near the CELLON process effluent lagoons by land treatment. Shortly thereafter the lake was stocked with 500 catfish and 500 bream species.
During the spring and summer of 1977 (April to September), closure of the CELLON effluent waste treatment lagoons occurred. Two large areas on the plant's property were picked to dispose of the lagoon water. The first location was behind the steel shop, and the second area located between the steel shop and the railroad tracks. The two areas were diked, when needed, and plowed. A tank truck drained the lagoons and sprayed the liquid over the two fields. Two applications were made on the fields. After the second application, the fields were plowed and generously fertilized. Dikes were then constructed to prevent any rain run-off from entering the pond in the vicinity of the CELLON effluent lagoons. The sludge on the bottom was removed, mixed, and spread over the lagoons and adjacent areas to dry. Once the area was dry, it was fertilized and seeded.
During the weekend of May 21 and 22, 1977, the plant received a strong rainfall which agitated the lake. At this time, a large number of ''bullfrog'' tadpoles died. It was theorized at the time that either the agitation of the pond bottom or the rain run-off was the cause of this event. No evidence of a fish kill was noted. However, a fish kill was reported in September of 1979 after a heavy rain. This occurrence was attributed to plant run-off contaminated with calcium chloride, which was used as a dust suppressant on the roads.
Investigations were begun in 1980 by Koppers to study the pentachlorophenol contamination of both the plant groundwater and the soils. Investigations included the installation of nine backhoe test pits and the collection of water samples from five of the pits, from seven of the eiisting wells, and from three surface water sources. In addition, soil samples were taken from several areas of the plant on several different occasions. Based on the results of these efforts, approximately 220 cubic yards of soil were removed from the plant on two different dates (April and May, 1980). The soils were removed to a permitted, commercial chemical waste disposal site.
In July, 1980, after the contaminated soils were removed, an in-depth soil sampling and analysis program was initiated in the area of the former effluent waste treatment lagoon, the former CELLON treatment area, and the.former warehouse area. As part of this program, seven monitoring wells (Nos. 9 thru 15) were installed to provide a ring of monitoring points around the plant. The depths of the wells were chosen such that the wells terminated at or above the uppermost confining layer. Groundwater samples were drawn from these wells in August, September and October of 1980. In addition, samples of three private wells and two offsite sediments (Medlin Pond and east discharge ditch) were taken on July 24, 1980 followed by water samples from the pond and soil samples from the pond and selected
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test pits on September 11, 1980*. Based on the results of this
investigation, an additional 240 cubic yards of contamin~ted soil
were removed to a permitted disposal site in November, 1980.
The US-EPA, (Region IV) Surveillance and Analysis Division (SAD),
at the request of the Air and Hazardous Materials Division,
conducted a hazardous waste site investigation (HWSI) which
included the collection and analysis of water, sediment, and fish
for purgeable and extractable organic compounds on
September 24, 1980. Surface water samples were collected from
the Koppers lake, Medlin pond, and the east ditch runoff under
the railroad etracks. Groundwater samples were collected from
three private wells and three wells on Koppers' property.
Sediment samples were collected from the Koppers' fire pond,
Medlin pond, and a ditch draining the land farming area. Fish
samplei were collected from the Koppers' fire pond and Medlin
pond. The samples were divided into fish tissue and fish liver
for analysis. Trace levels of an organic solvent were identified
in a well supplying the laminating plant but it was concluded
that the trace level would not merit health concern with respect
to potable use.
A more detailed follow-up soil investigation was completed in the
area of the former effluent waste treatment lagoons in June,
1981. This investigation indicated that PCP was still present at
certain locations. Koppers conducted another round of
groundwater sampling in June of 1984, including a confirmation of
the soil sampling results of 1981. As a result, soil was again
removed (approximately 1,100 cubic yards) from the lagoon area in
1986.
*The July 24 samples were actually collected by North Carolina
and Federal EPA with all samples split between Koppers and the
Agency.
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Dear Neighbor:
Koppers Company, Inc., Science and Technology
436 Seventh Avenue, Pittsburgh, PA 15219
Telephone [phone]
KOPPERS
January 20, 1987
Thank you for your cooperation in permitting us to draw water samples
from your home. We apologize for any inconvenience we may have
caused.
Koppers' Morrisville plant was recently sold to Unit Structures
Company. To complete the sale we must conduct an environmental study.
This study is being done with the knowledge of the North Carolina
Department of Human Resource Services, Division of Health Services.
The samples from your homes are being used as part of that study.
Whenever drinking water is analyzed, extra precautions must be taken
to ensure accurate and meaningful results. That is why we have taken
three samples from your wells. None of the completed analyses on the
first two samples has shown any reason for concern about the quality
of the groundwater.
The third set of samples is being analyzed at our contractor's
laboratories in Pennsylvania and Texas.
The complete results of this drinking water study will be sent to you
and the N.C. Department of Human Resources as soon as we receive the
laboratory reports. We expect to receive this information by the end
of February. If, during any analysis of your water, there had been
any indication that harmful constituents might be present, you would
have been notified immediately. I want to assure you that our testing
results do not indicate any cause for concern about the quality of
your drinking water.
I want to thank you again for your cooperation and apologize for any
inconvenience we may have caused.
Sincerely yours,
Martin M. Schlesinger, Assistant Manager
Previously Operated Properties
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Dear Pat,
KEYSTONE
ES\'JRONMENTAL RESOURCES, INC.
436 Seventh A\'enue, Suite 1940, Pittsburgh, PA 15219
. January 26, 1987
Solid and Hazardous Waste
Management Branch
North Carolina Department of
Human Resources
P. O. Box 2091
Raleigh, NC 27602-2091
Attention: Pat DeRosa
Waste Management Section
Re: Koppers Morristown Site
Information Request
Enclosed is the information you requested in
letter which we discussed during our visit.
mation is enclosed:
your December, 1986
The following infer-
1. Letter to Mr. Paige, from D. R. Kerschner, dated February 14,
1986 which discusses the soil removal from the area of the
former lagoons.
2. Letter to Mr. R. A. Fisher from R. K. Garner (GSX) dated
July 24, 1986 covering the actions of GSX during the soil
removal.
3. Memo to S. M. Tymiak from R. A. Fisher, dated August 25, 1986
titled "Final Report, Soil Removal Project, Raleigh, NC" ..
4. Site Maps (2) showing locations of borings, monitoring wells.
---)'7 5. A short history of the lagoons and their closure.
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Page 2
North Carolina Department of Human Resources
January 26, 1987
--)➔ 6. A letter, addressed to the families which participated in our survey of off-site domestic groundwater quality. As we dis-cussed during our meeting, Koppers will release the results of this investigation upon its completion.
The analysis of the soil samples taken during the soil removal are currently in progress. However, due to the large number of analyses of this type in our laboratory, I do not foresee receiving the results until late February. They will be forwarded to your office when I re-ceive them.
Please feel free to call me at this office if you have any questions regarding this submittal or our activities at the site.
MMS/wl
Enclosures
cc: J. Blundon
J. Campbell
M. Dvorsky
C. Beck
C. Cramer
155500
Sincerely yours,
Martin M. Schlesinger
Assistant Program Manager
Previously Operated Properties
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PROCESS HISTORY
The Koppers' Raleigh plant produced glued-laminated wood products
from 1962 to 1986 when it was sold to Unit Structures.
Production has continued Unit Structures management. The plant
initially used untreated wood and wood preserved with fluor
chrome arsenate phenol (FCAP), Type A. No treating of this
material occurred at the site .. In 1968 the CELLON process was
installed at the site to produce treated wood for use as a raw
material. This treatment consisted of pressure injecting
pentachlorophenol (PCP) in a liquified butane isopropyl ether
solution into the wood. After the impregnation was completed,
the butane carrier evaporated, leaving the pentachlorophenol as a
dry, crystalline salt. The CELLON treatment plant was located in
the southeastern portion of the site, near the existing fire
pond. The CELLON treatment process was discontinued in 1975,
after which treated wood was imported from other facilities.
excess PCP salt was removed from the wood by steaming. The wash ~~,-'=,f>U.l:$
solution was treated to recover PCP after which it was discharged '-"0~r.-..H
I to the fire pond until the two treatment lagoons were installed f 0~,
arrr0xi~2te!y six (6) months after start-up~ After the CELLON
11'15'process was disc·ontinued, the lagoons were. "closed." The closure
process consisted of spraying the residual liquid over a portion I
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of the field northwest of the steel shop and mixing the remaining
sludges with the'stiil surrounding the lagoons. Fertilizer was
added in both operations to enhance biodegradation of the
pentachlorophenol.
From the recollection of knowledgeable employees at the facility
and prior written memos, it is evident that the CELLON process
did experience operational problems over the course of its
operation which may have contributed to the escape of PCP to the
environment. Spills of process chemicals may also have led to
soil contamination in storage and process plant areas.
Chronology of Environmental Activities
In January of 1971, after a heavy rain, about 200 fingerlings
were found dead in the Medlin Pond. The Medlin Pond is located
downstream of_ the overflow of the Koppers' fire pond on the
property of a private residence. To avoid a repeat of this
incident, the Koppers•-pond overflow was by-passed around the
Medlin Pond until about 1980. ~;,
In mid-1975, the CELLON process was shut down and the equipment
was dismantled and sold where possible.
Following the shutdown of the CELLON Process, water samples were
taken from the fire pond in the summer of 1976 to determine if
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the pond water could support fish. PCP levels of less than 1 ppm were recorded with higher levels near the CELLON process effluent lagoons by land treatment. Shortly thereafter the lake was stocked with 500 catfish and 500 bream species. ---~
During the spring ~nd summer of 1977 (April to September), closure of the CELLON effluent waste treatment lagoons occurred. Two large areas on the plant's property were picked to dispose of the lagoon water. The first location was behind the steel shop,~ and the second area located between the steel shop and the railroad tracks. The two areas were diked, when needed, and plowed. A tank truck drained the lagoons and sprayed the liquid over the two fields. Two applications were made on the fields. After the second application, the fields were plowed and generously fertilized. Dikes were then constructed to prevent any rain run-off from entering the pond in the vicinity of the CELLON effluent lagoons. The sludge on the bottom was removed, mixed, and spread over the lagoons and adjacent areas to dry. Once the area was dry, it was fertilized and seeded.
During the weekend of May 21 and 22, 1977, the plant received a strong rainfall which agitated the lake. At this time, a large number of "bullfrog" tadpoles died. It was theorized at the time that either the agitation of the pond bottom or the rain run-off was the cause of this event. No evidence of a fish kill was noted. However, a fish kill was reported in September of 1979 ~:t"' a \·,cav y tain. This occurrence was attributed to plant run-off contaminated with calciu~ chloride, which was used as a dust suppressant on the roads.
Investigations were begun in 1980 by Koppers to study the pentachlorophenol contamination of both the plant groundwater and the soils. Investigations included the installation of nine backhoe test pits and the collection of water samples from fiv~ of the pits, from seven of the existing wells, and from three surface water sources. In addition, soil samples were taken from several areas of the plant on several different occasions. Based on the results of these efforts, approximately 220 cubic yards of soil were removed from the plant on two different dates (April and May, 1980). The soils were removed to a permitted, commercial chemical waste disposal site.
In July, 1980, after the contaminated soils were removed, an in-depth soil sampling and analysis program was initiated in the area of the former effluent waste treatment lagoon, the former CELLON treatment area, and the former warehouse area. As part of this program, seven monitoring wells (Nos. 9 thru 15) were installed to provide a ring of monitoring points around the plant. The depths of the wells were chosen such that the wells terminated at or above the upp'ermost confining layer. Groundwater samples were drawn from these wells in August, September and Octqber of 1980. In addition, samples of three private wells and two offsite sediments (Medlin Pond and east discharge ditch) were taken on July 24, 1980 followed by water samples from the pond and soil samples from the pond and selected
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test pits on September 11, 1980*. Based on the results of this.
investigation, an additional 240 cubic yards of contaminated soil
were removed· to a permitted disposal site in November, 1980.
The US-EPA, (Region IV) Surveillance and Analysis Division (SAD),
at the request of the Air and Hazardous Materials Division,
conducted a hazardous waste site inve~tigation (HWSI) which
included the collection and analysis of water, sediment, and fish
for purgeable and extractable organic compounds on
September 24, 1980. Surface water samples were collected from
the Koppers lake, Medlin pond, and the east ditch runoff under
the railroad etracks. Groundwater samples were collected from
three private wells and three wells on Koppers• property.
Sediment samples were collected from the Koppers' fire pond,
Medlin pond, and a ditch draining the land farming area. Fish
samples were collected from the Koppers• fire pond and Medlin
pond. The samples were divided into fish tissue and fish liver
for analysis. Trace levels of an organic solvent were identified
in a well supplying the laminating plant but it was concluded
that the trace level would not merit health concern with respect
to potable use.
A more detailed follow-up soil investigation was. completed in the
area of the former effluent waste treatment lagoons in June,
1981. This investigation indicated that PCP was still present at
certain locations. Koppers conducted another round of
groundwater sampling in June of 1984, includirig a confirmation of
the soil sampling results of 1981. As a result, soil. was again
removed (approximately 1,100 cubic yards) from the lagoon area in
1986. .
L ,-c •:p(J.t<-~ k ~k-en, ,t
i . :::, /tf1L-tfh,«-<( ~ I i( .
'--'-) [/c,_&1e.)
*The July 24 samples were actually collected by North Carolina
and Federal EPA with all samples split between Koppers and the
Agency.
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I KEYSTONE
ESVIROS~IENTAL RESOCRCTS, l~C.
l _____ ::---:--:----;:-::--;-;::::::--::=~~------:------
436 Seventh A,·enue, Suite 1940, Pittsburgh, PA 15219
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Dear Pat,
. January 26, 1987
Solid and Hazardous Waste
Management Branch
North Carolina Department of
Hu::ian Resources
P. O. Box 2 0 91
Raleigh, NC 27602-2091
Atte~tion: Pat DeRosa
Waste Management Section
Re: ~oppers Morristown Site
Information Request
~nclosed is the information you requested in
letter which we discussed dur~ng our visit.
~ation is enclosed:
your December, 1986
The following infor-
2.
Letter to Mr. Paige, from D. R. Kerschner, dated February 14,
1986 which discusses the soil removal from the area.of the former lagoons.
Letter to Mr. R. A. Fisher from R. K. Garner (GSX) dated
July 24, 1986 covering the actions of GSX during the soil removal.
Memo to S. M. Tymiak from R. A. Fisher, dated August 25, 1986
titled "Final Report, Soil Removal Project, Raleigh, NC".
Site Maps (2) showing locations of borings, monitoring wells.
A short history of the lagoons and their closure.
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Page 2
North Carolina Department of Human Resources
January 26, 1987
--)➔ 6. A letter, addressed to the families which participated in our survey of off-site domestic groundwater quality. As we dis-cussed during our meeting, Koppers will release the results of this investigation upon its completion.
The analysis of the soil samples taken during the soil removal are currently in progress. However, due to the large number of analyses of this type in our laboratory, I do not foresee receiving the resu~ts until late February. They will be forwarded to your office when Ir~-ceive them.
Please feel free to call me at this office if you have any questions regarding this submittal or our activities at the site.
?·lMS/wl
::nclosures
cc: J. Blunden
J. Campbe 11
M. Dvorsky
C. Beck
C. Cramer
155500
Si~cerely yours,
Martin M. Schlesinger
Assistant Program Manager
Previously Operated Properties
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PROCESS HISTORY
The Koppers' Raleigh plant produced glued-laminated wood products from 1962 to 1986 when it was sold to Unit Structures. Production has continued Unit Structures management. The plant iriitially used untreated wood and wood preserved with fluor chrome arsenate phenol (FCAP), Type A. No treating of this material occurred at the site. In 1968 the CELLON process was installed at the site to produce treated wood for use as a raw material. This treatment consisted of oressure injecting pentachlorophenol (PCP) in a liquified butane isopropyl ether solutio~ into the wood. After the impregnation was completed, the butane carrier evaporated, leaving :he pentachlorophenol as a d,y, crystalline salt. The CELLON treat:nent plant was located in the southeastern portion of the site, near-the existing fire pond. The CELLON treatment process was discontinued in 1975, after which treated wood was imported f~o:n other facilities.
:C:xcess PCP salt was removed from the ,:ocd by steaming. The wash ~I"t,.--_1c,~· .. i:5 solution w_ as treated to recover PCP after _1,;:1ic:1 it was discharged u..!>-:-c";-cl'..-..(--1, to the fire pond until the two treatment lagoons were installed f 0~~ ~nnrr.vim~~01 " ~, V 16\ mo~tl--s ~rt· er st~r;-up.· '·fter the CELLON . ,-r· -••--•-w--J .., ... ,. \ , i.,, 11 •J C: C ...,-• t'. _·::;.:,;process _was d isc·ontinued, the lagoons were "closed." The closure p,ocess consisted of spraying the residual liquid over a portion of the field northwest of the steel shop and mixing the remaining sludge~ with the ioil surrounding the lagoons. Fertilizer was added in both operations to enhance biocegradation of the pentachlorophenol.
From the recollection of knowledgeable employees at the facility and prior written memos, it is evident that the CELLON process did experience operational problems over the course of its operation which may have contributed to the escape of PCP to the environment. Spills of process chemicals may also have led to soil contamination in storage and process plant areas.
Chronology of Environmental Activities
In January of 1971, after a heavy rain, about 200 fingerlings were found dead in the Medlin Pond. The Medlin Pond is located downstream of_ the overflow of th'e Koppers' fire pond on the property of a private residence. To avcid a repeat of this incident, the Koppers' pond overflow was by-passed around the V.edlin Pond until about 1980. ~;:, . .
IA rnid-1975, the CELLON process was shut down and the equipment was dismantled and sold where possible .
Following the shutdown of the CELLON Process, water samples were taken from the fire pond in the summer of 1976 to determine if
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the pond water could support fish. PCP levels of less than 1 ppm were recorded with higher levels near the CELLON process effluent lagoons by land treatment. Shortly thereafter the lake was stocked with 500 catfish and 500 bream species.
During the spring and summer of 1977 (April to September), closure of the CELLON effluent waste treatment lagoons occurred. Two large areas on the plant's property were picked to dispose of the lagoon water. The first location was behind the steel shop, and the second area located between the steel shop and the railroad tracks. The two areas were diked, when needed, and plowed. A tank truck drained the lagoons and sprayed the liquid over the two fields. Two applications were made on the fields. After the second application, the fields were plowed and generously fertilized. Dikes were then constructed to prevent any rain run-off from entering the pond in the vicinity of the CELLON effluent lagoons. The sludge on the bottom was removed, mixed, and spread over the lagoons and 2cjacent areas to dry. Once the area was dry, it 1,as fertilize: and seeded.
During the weekend of l·'.ay 21 and 22, 19 7 7, the plant received a st,on6 rainfall which agitated the lake. ;;:. this time, a large number of "bullfrog" tadpoles died. It ;,·as theorized at the time that either the agitation of the pond tcttom or the rain run-off was the cause of this event. No eviden:e of a fish kill was noted. However, a fish kill w-as reportec in September of 1979 =~~~~ ~ h~~vy r•dir1. This occurrence was attributed to plant run-off contaminated with calcium chloride, which was used as a dust suppressant on the roads.
Investigations were begun in 1980 by Koppers to study the · pentachlorophenol contamination of both the plant groundwater and ~he soils. Investigations included the installation of nine backhoe test pits and the collection of water samples from five cf the pits, from seven of the existing wells, and from three surface water sources. In addition, soil samples were taken from several areas of the plant on several different occasions. Based on the results of these efforts, approximately 220 cubic yards of soil were removed from the plant on two different dates (April and l'iay, 1980). The soils were removed to a permitted, commercial chemical waste disposal site.
In July, 1980, after the contaminated soils were removed, an in-depth soil sampling and analysis program, was initiated in the area of the former effluent wast.e tre2tr:ent lagoon, the former CELLON treatment area, and the former warehouse area. As part of this program, seven monitoring wells (Nos. 9 thru 15) were installed to provide a ring of monitoring points around the plant. The depths of the wells were chosen such that the wells t~rminated at or above the uppermost confining layer. Groundwater samples were drawn from these wells in August, September and Octqber of 1980. In addition, samples of three private wells and two offsite sediments (~edlin Pond and east discharge ditch) were taken on July 24, 1980 followed by water samples from the pond and soil samples from the pond and selected
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test pits on September 11, 1980*. Based on the results of this
investigation, an additional 240 cubic yards of contaminated soil
were removed· to a permitted' disposal site in November, 1980.
The US-EPA, (Region IV) Surveillance and Analysis Division (SAD),
at the request of the Air and Hazardous Materials Division,
conducted a hazardous waste site investigation (HWSI) which
included the collection and analysis of water, sediment, and fish
for purgeable and extractable organic compounds on
September 24, 1980. Surface water samples were collected from
the Koppers lake, Medlin pond, and the east ditch runoff under
the railroad etracks. Groundwater samples were collected from
three private wells and three wells on Koppers' property.
Sediment samples were collected from the Koppers' fire pond,
Medlin pond, and a ditch draining the land farming area. Fish
sam·ples were collected from the Koppers' fire pond and Medlin
pond. The samples were divided into fish tissue and fish liver
for analysis. Trace levels of an organic solvent were identified
in a well supplying the laminating plant but it was concluded
that the trace level would not merit he2lth concern with respect
to potable use.
A more detailed follow-up soil investig2tion was cc~pleted in the
area cf the former effluent waste treat~ent lagoons in June,
1981. This investigation indicated that PCP was still present at
certain locations. Koppers conducted another round of
groundwatRr sampling in June of 1984, including a confirmation of
the soil sampling results of 1981. As a result, soil. was again
removed ( approximately 1,100 cubic yards) from the lagoon area in
198 6.
~The July 24 samples were actually collected by North Carolina
and Federal EPA with all samples split between Koppers and the
Agency.
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KEYSTONE
ENVIRONMENTAi. RESOURCF$, INC.
436 Seventh Avenue, Suite 1940, Pittsburgh, PA 15219
January 26, 1987
Solid and Hazardous Waste Management Branch
North Carolina Department of Human Resources
P. 0. Box 2091
Raleigh, NC 27602-2091
Attention: Pat DeRosa
Waste Management Section
Re: Koppers Morristown Site Information Request
Ref. 2
Dear Pat,
Enclosed is the information you requested in letter which we discussed during our visit. mation is enclosed:
your December, 1986 The following infor-
\
1. Letter to Mr. Paige, from D.R. Kerschner, dated February 14, 1986 which discusses the soil removal from the area of the former lagoons.
2. Letter to Mr. R. A. Fisher from R. K. Garner (GSX) dated July 24, 1986 covering the actions of GSX during the soil removal.
3. Memo to S. M. Tymiak from R. A. Fisher, dated August 25, 1986 titled "Final Report, Soil Removal Project, Raleigh, NC".
4. Site Maps (2) showing locations of borings, monitoring wells. 5. A short history of the lagoons and their closure.
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Page 2 North Carolina Department of Human Resources January 26, 1987
6. A letter, addressed to the families which participated in our survey of off-site domestic groundwater quality. As we dis-cussed during our meeting, Koppers will release the results of this investigation upon its completion.
The analysis of the soil samples taken during the soil removal are currently in progress. However, due to the large number of analyses of this type in our laboratory, I do not foresee receiving the results until late February. They will be forwarded to your office when I re-ceive them.
Please feel free to call me at this office if you have any questions regarding this submittal or our activities at the site.
MMS/wl
Enclosures
cc: J. Blundon
J. Campbell
M. Dvorsky
C. Beck
C. Cramer
155500
Sincerely yours,
Martin M. Schlesinger
Assistant Program Manager
Previously Operated Properties
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CERTIFIED MAIL
Dear Mr. Paige:
Telephone [phone]
February 14, 1986
Mr. William Paige
Solid and Hazardous Waste
Management Branch
Division of Health Services
P .0. Box 2091
Ref. 2, Encl. 1
Raleigh, North Carolina 27602
As we discussed in our telephone conversation this afternoon,
Koppers is in the process of evaluating the immediate removal of
pentachlorophenol-containing soil from the former wastewater
lagoon area at our Morrisville (Raleigh) plant. I had contacted
your agency so that the plant could either reactivate its old EPA
ID number or obta.in a new number; the plant's former number was
de-activated due to the lack .of hazardous waste activity.
Pursuant to that, I understand that you will be sending me the
paperwork to obt~in a new ID number~
You had also requested that I explain our proposed activity at
the site. We are ~resently evaluating the removal of KOOl
materials in ~he area which contain pentachlorophenol at or above
10 mg/Kg (ppm). You can refer to our November, 1984 report to
examine soil quality data from the area. My estimates indicate
that approximately 1100 cubic yards of soil are involved. This
material would be trucked to the GSX landfill in Pinewood, SC,
assuming that full approvals are 6btained.
The lack of an EPA ID number is the only thing holding up our
application to place t~is material in .Pinewood. Upon that
approval, the project must be approved by Koppers management
before contracts can be awarded. Thus, at this ppint, the
project remains in a ''proposed" status.
You had also indicated .that your Agency would have to review our
proposed actions, including our 10 mg/Kg clean-up level. It is
not our intent to have this project generate any discussions
concerning clean-up levels which would delay the project.
Koppers feels that the proposed remediation is necessary and
should be pursued without delay.
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WILLIAM PAIGE
PAGE TWO
FEBRUARY 14, 1986
I appreciate your assistance in this matter. If you have any
questions or comments, please call.
DRK/bj
cc: L.C. Beck (Raleigh)
W .J. Baldwin
Very truly yours,
(;J,,.,;c( f)_ ~'-OC~
David R. Kerschner
Manager, Environmental
Regulatory Programs
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GSX Services, Inc.
Emergency, Remedial &
Technical Projecls Group
PO. Box 210
F.eidsvi//e, North Caolina 27 320
(9J9) 302-6106
(919} 272-2222 (Emergency Response)
Mr. Robert A. Fisher
KOPPERS COMPANY, INC.
436_.Seventh Avenue
Pittsburgh, PA 15219
July 24, 1986
Re: Contaminated Soil R~moval Project; Morrisville, NC
Dear Mr. Fisher:
/.
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'
Ref. 2, Encl. 2
Please find below a final report of the work that GSX Services, Inc. (GSX)
performed at the Morrisville, NC site.
This information is summarized by day.
July }_,._ 1986 .:::. Monday
GSX mobilized one (1) Project Manager and two (2) Equipment Operators from
its Reidsville, North Carolina facility. The CSX crew arrived on site
·and met with you. Upon our arrival you gave us a preliminary site tour
discussing boundaries, waste areas, schedules, etc. All questions and
initial problems were answered and solved. The GSX crew then left the
Si t2 e'
July~ 1986.:::. Tuesday
The GSX crew arrived on site at 7:45 a.m. only to find that the excavator
had not arrived. Upon the completion of several phone calls, the excavator
arrived at 8:45 a.m. It was unloaded and excavation of the "one (1) foot
designated area" was begun at 9:20 a.m. All material was stockpiled by our
GSX front-end loader. Mike Milchuck, our GSX Technical Sales
Representative, arrived for a site visit.
. At 5:00 p.m., we decided that approximately 20-25 truckloads of material
was stockpiled and ready for the next day's pick-up. We left the site at
6:00 p.m.
July ~ 1986 .:::. Wednesday
We arrived on site at 5:35 a.m. Using both pieces of equipment, we began
loading trucks at 6:10 a.m. We loaded seventeen (17) dump trucks. Upon
their completion, the GSX crew continued stockpiling material for the next
day's loading. We left the site at 1:30 p.m.
GENST/.\R
A Genstar Waste
Servic~s Company
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Mr. Robert A. Fisher
KOPPERS COclPANY, INC.
July 24, 1986
Page -2-
July 10, 1986-= Thursday
We arrived on site at 5:40 a.rn. The GSX crew did a preventive m2intenance
check on site equipment. Again, using both pieces of equipment, we began
loading trucks at 6: 10 a.m. GSX loaded nineteen (19) trucks. Stockpiling
continued. We left the site at 2:00 p.m.
July· l!..,_ 1986 -= Friday
Arrived on site at 5:45 a.m. The GSX
a.m. GSX loaded eighteen (18) trucks.
Reidsville, NC. (1/2 day charge)
July ~ 1986 -= Sunday
crew began loading trucks at 6:10
The GSX crew demobilized to
Mobilized Project Manager and one (1) Equipment Operator from Reidsville,
NC.
July ..!.!:_,_ 1986 -= Monday
Arrived on site at 5:30 a.m. Front-end loader began loading trucks at 5:50
a.m. Finished loading twenty-one (21) trucks at 9:20 a.m. Equip □ent
Operator skimmed areas designated by yourself for the next day's loading.
We left the site at 1:00 p.m.
July 12.L 1986 -= Tuesday
Arrived on site at 5:45 a.m. At 6: 10 a.m. the Equipment Operator began
loading the first truck. At 7:00 a.m. the front-end loader received a flat
tire. A service call was made and the loader continued at 9:30 a.m. All
trucks were finished loading at 11:20 a.m. We left the site at 11:45 a.m.
(1/2 day charge)
Please note that there will be a change in some of the "Daily Costs"
sheets. Task I (Protective Clothing) is a "per day" charge. This pertains
to whether we worked a full or-partial day. I apologize for any
inconvenience that this might cause.
Final Summary
GSX excavated, stockpiled and loaded eighty-four dump truck loads of
contaminated soil and debris fiom the Morrisville area. Total work time
was five (5) full eight (8) hour days and two (2) half days.
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Mr. Robert A. Fisher
KOPPERS COXPAh'Y, INC.
July 24, 1986
Page -3-
Should you have any questions conceriing the 0ork performed or the disposal
of the materials, please do not hesitate to contact us. We at GSX look
forward to working with Koppers in the future.
Sincerely,
#~~-Randy K. Garner
Project Manager
ERT Group
RKG/dwb
cc: Mike Hilchuck
Robert Stephens
Dave Sprinkle
Larry Davis
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Interoffice Correspondence
S. M. Tymiak
K/1928
FINAL REPORT
SOIL REMOVAL PROJECT
RALEIGH, NC
From
location
Date
Ref. 2, Encl. 3
R. A. Fisher
K/1928
August 25, 1986
CSX Services Inc .. mobilized. Monday, July 7, 1986
initiating the Raleigh soil removal project. The clean-up
concentrated on three (3) specific areas:
Former Lagoon Area
Filter Bed Area, and
The Blowndown Pit Area.
Location of subject areas within the Raleig·h Plant Site are
shown on Figure I.
Excavation and .stockpiling of PCP contaminated soil from
the Lagoon Area commenced Tuesday, July 8, 1986. The first co,,-
voy of trucks arrived Wednesday, July 9th. Figure II depicts
graphically the location of old lagoons, extent and depth of ex-
cavation, and a 200 ft. x 100 ft. grid sampling network. Approx~
i~tely 1100 cu. yds. of contaminated soil was excavated and re-
moved from the 20, 000 sq. ft. area encompassing the old lagoons.
The filter Bed Area contained a·bout 50 cu. yds. of contaminated
concrete, piping and soil. The Blowndown Pit Area consisted
of approximately 100 cu. yds. of contaminated soil.
All contaminated material,•· totalling 1250 cu. yds. (1552 tons)
was manifested and transported to Pinewood Landfill,
South Carolina.
Upon completion of all excavation and transport activities,
soil surface samples were collected at all three (3) subject
areas; former Lagoon Area (forty-eight (?8) samples at designated
locations), Fllter Bed Area (one (1) sample), and Blowdown Pit
(one (1) sample). All samples were shipped to Monroeville
July 15, 1986.
Sheet I of 2
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Site restor2.tion
subject areas.
commenced July 16, 1986 with the backfilling of
Fill dirt consisted of silt and topsoil. Due to
previous excavations, performed in 1980 around the Cellon Treating
Area and Old Lagoons, the required volume of fill dirt w2.s doubled.
All excavated areas were restored to grade level and seeded. The
entire soil removal project was finalized and completed July 22,
1986.
Negotiations with subcontractors throughout the project ·and utilization
of cost effective measures resulted in savings of over $60, 000. ;The
attached chart delineates the scope of completed work and fin2.l costs.
RAF:m
Enclosures
Copies to:
M. R. Urbassik
M. Dvorsky
D.R. Kerschner
.J. R. Campbell
File
R. A. TISHER
Sheet 2 of 2
lli.s.l!!l
/
/
+ EXJSTJNG llfllS
·<\>, pfl(lD{)SEO k'ELlS
$
RALEIGH, NORTH CAROLINA· ..
--------
PnDf'E fl h' 80lfla,IRY
..
LN6IW)G) >tlXI -· + W•I ◄
f'f/C>"En r r POU\O.J.RY
Blowdown .
Pit Area
tA,U)€0 Y.J.ro
'.
Fil_ter_ ...
F/llc/'<l"'1
----
tO . s£0 SI
p11f c,.O
rr:ru&£ . . . . . . . '0;¼
0 .
· w-a
+
KJ/OC/'K'l"
R. A. Flshel'
8-18-86
FIGURE I
.. RAL:C::IGH, .NORTH CAROLINA
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FORMER LAGOON AREA
IEA B .. 7 EXCAVATED 36" OF SOIL),,.-
r~~GHOUT INSCRIBED
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LEGEND:
Q .SOIL SUR.FACE SAMPLES
TAKEN AT EACH
LOCATION (~8 SAMPLES)
0
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Q, . /4
OUTLINE OF 01
LAGOON
R. A. FISHER·
8-18-36
o ..
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PROPERTY
BOUNDARY
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SCALE (FEET)
0 100 200 300
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l!!!!!!!!!I !!!!!I
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FI61JRE 1
_l.OCATION lt'Ell
RALEIGH/NORRI,::;.LLE.
KOPPERS COMPANY ' INC.
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FIGURE e,_
80AfN c;,.
LOCATION
RALEIGH/NORRI~,::;.LLE.
KOPPERS COMPANY, ' %NC.
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Ref. 2, Encl. 5
PROCESS HISTORY
The Koppers' Raleigh plant produced glued-laminated wood products from 1962 to 1986 when it was sold to Unit Structures. Production has continued Unit Structures management. The plant initially used untreated wood and wood preserved with fluor chrome arsenate phenol (FCAP), Type A. No treating of this material occurred at th,e site. In 1968 the CELLON process was, installed at the site to produce treated wood for use as a raw material. This treatment consisted of pressure injecting pentachlorophenol (PCP) in a liquified butane isopropyl ether solution into the wood. After the impregnation was completed, the butane carrier evaporated, leaving the pentachlorophenol as a dry, crystalline salt. The CELLON treatment plant was located in the southeastern portion of the site, near the existing fire pond. The CELLON treatment process was discontinued in 1975, after which treated wood was imported from other facilities.
Excess PCP salt was removed from the wood by steaming. The wash solution was treated to recover PCP after which it was discharged to the fire pond until the two treatment lagoons were installed approximately six (6) months after start-up. After the CELLON process was discontinued, the lagoons were "closed." The closure process consisted of spraying the residual liquid over a portion of the field northwest of the steel shop and mixing the remaining sludges with the soil surrounding the lagoons. Fertilizer was added in both operations to enhance biodegradation of the pentachlorophenol.
From the recollection of knowledgeable employees at the facility and prior written memos, it is evident that the CELLON process did experience operational problems over the course of its operation which may have contributed to the escape of PCP to the environment. Spills of process chemicals may also have led to soil contamination in storage and process plant areas.
Chronology of Environmental Activities
In January of 1971, after a heavy rain, about 200 fingerlings were found dead in the Medlin Pond. The Medlin Pond is located downstream of the overflow of the Koppers' fire pond on the property of a private residence. To avoid a repeat of this incident, the Koppers' pond overflow was by-passed around the Medlin Pond until about 1980.
In mid-1975, the CELLON process was shut down and the equipment was dismantled and sold where possible.
Following the shutdown of the CELLON Process, water samples were taken from the fire pond in the summer of 1976 to determine if
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the pond water could support fish. PCP levels of less than 1 ppm were recorded with higher levels near the CELLON process effluent lagoons by land treatment. Shortly thereafter the lake was stocked with 500 catfish and 500 bream species.
During the spring and summer of 1977 (April to September), closure of the CELLON effluent waste treatment lagoons occurred. Two large areas on the plant's property were picked to dispose of the lagoon water. The first location was behind the steel shop, and the second area located between the steel shop and the railroad tracks. The two areas were diked, when needed, and plowed. A tank truck drained the lagoons and sprayed the liquid over the two fields. Two applications were made on the fields. After the second application, the fields were plowed and generously fertilized. Dikes were then constructed to prevent any rain run-off from entering the pond in the vicinity of the CELLON effluent lagoons. The sludge on the bottom was removed, mixed, and spread over the lagoons and adjacent areas to dry. Once the area was dry, it was fertilized and seeded.
During the weekend of May 21 and 22, 1977, the plant received a strong rainfall which agitated the lake. At this time, a large number of ~bullfrog'' tadpoles died. It was theorized at the time that either the agitation of the pond bottom or the rain run-off was the cause of this event. No evidence of a fish kill was noted. However, a fish kill was reported in September of 1979 after a heavy rain. This occurrence was attributed to plant run-off contaminated with calcium chloride, which was used as a dust suppressant on the roads.
Investigations w~re begun in 1980 by Koppers to study the pentachlorophenol contamination of both the plant groundwater and the soils. Investigations included the installation of nine backhoe test pits and the collection of water samples from five of the pits, from seven of the existing wells, and from three surface water sources. In addition, soil samples were taken from several areas of the plant on several different occasions. Based on the results of these efforts, approximately 220 cubic yards of soil were removed from the plant on two different dates (April and May, 1980). The soils were removed to a permitted, commercial chemical waste disposal site.
In July, 1980, after the contaminated soils were removed, an in-depth soil sampling and analysis program was initiated in the area of the former effluent waste treatment lagoon, the former CELLON treatment area, and the former warehouse area. As part of this program, seven monitoring wells (Nos. 9 thru 15) were installed to provide a ring of monitoring points around the plant. The depths of the wells were chosen such that the wells terminated at or above the uppermost confining layer. Groundwater samples were drawn from these wells in August, September and October of 1980. In addition, samples of three private wells and two offsite sediments (Medlin Pond and east discharge ditch) were taken on July 24, 1980 followed by water samples from the pond and soil samples from the pond and selected
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test pits on September 11, 1980*. Based on the results of this
investigation, an additional 240 cubic yards of contaminated soil
were removed to a permitted disposal site in November, 1980.
The US-EPA, (Region IV) Surveillance and Analysis Division (SAD),
at the request of the Air and Hazardous Materials Division,
conducted a hazardous waste site investigation (HWSI) which.
included the collection and analysis of water, sediment, and fish
for purgeable and extractable organic compounds on
September 24, 1980. Surface water samples were collected from
the Koppers lake, Medlin pond, and the east ditch runoff under
the railroad etracks. Groundwater samples were collected from
three private wells and three wells on Koppers• property.
Sediment samples were collected from the Koppers' fire pond,
Medlin pond, and a ditch draining the land farming area. Fish
samples were collected from the Koppers• fire pond and Medlin
pond. The samples were divided into fish tissue and fish liver
for analysis. Trace levels of an organic solvent were identified
in a well supplying the laminating plant but it was concluded
that the trace level would not merit health concern with respect
to potable use.
A more detailed follow-up soil investigation was completed in the
area of the former effluent waste treatment lagoons in June,
1981. This investigation indicated that PCP was still present at
certain locations. Koppers conducted another round of
groundwater sampling in June of 1984, including a confirmation of
the soil sampling results of 1981. As a result, soil was again
removed (approximately 1,100 cubic yards) from the lagoon area in
1986.
*The July 24 samples were actually collected by North Carolina
and Federal EPA with all samples split between Koppers and the
Agency.
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Dear Neighbor:
Koppers Company. Inc., Science and Technology
436 Seventh Avenue, Pittsburgh, PA 15219
Telephone [phone]
KOPPERS
January 20, 1987
Ref. 2, Encl. 6
Thank you for your cooperation in permitting us to draw water samples from your home. We apologize for any inconvenience we may have caused.
Koppers' Morrisville plant was recently sold to Unit Structures Company. To complete the sale we must conduct an environmental study. This study is being done with the knowledge of the North Carolina Department of Human Resource Services, Division of Health Services. The samples from your homes are being used as part of that study.
Whenever drinking water is analyzed, extra precautions must be taken to ensure accurate and meaningful results. That is why we have taken three samples from your wells. None of the completed analyses on the first two samples has shown any reason for concern about the quality of the groundwater. ·
The third set of samples is being analyzed at our contractor's laboratories in Pennsylvania and Texas.
The complete results of this drinking water study will be sent to you and the N.C. Department of Human Resources as soon as we receive the laboratory reports. We expect to receive this information by the end of February. If, during any analysis of your water, there had been any indication that harmful constituents might be present, you would have been notified immediately. I want to assure you that our testing results do not indicate any cause for concern about the quality of your drinking water.
I want to thank you again for your cooperation and apologize for any inconvenience we may have caused.
Sincerely yours,
Martin M. Schlesinger, Assistant Manager Previously Operated Properties
l!!!!!I == ----. liiiiiii . iiii --

.

son, REMOVAL PROJECT
RALEIGH, NORTH CAROLINA. -
,-=--,--* -==---------
/
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Llllli!l + EXJSrING I/El.LS
. ·It PR<Y'OSEO Jr'£LLS
/\_ .
/ PflOf'li<TY
/ BOWURY
PROf'cRTY
BOthOAfl Y
w-10
-4>:
Blowdown
Pit Area
Excavated Material from
f'i~;~'?c:i Blowdown Pit, Filter Bed and
Former Lago_on Areas.
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SC'AlE (r££fl
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. O 13 154
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R. A, Fisher
8-18-86
-
FIGCTRE I if
t-h
ICa'f'tnS CC't"'JWf, w
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CERTIFIED HAIL
Koppers Company, Inc .. Forest Pioduc:s G111up
Pittsbur9h. PA 15219, 412-227-~00Q
July 3, 1980
Mr. Joe Young
Environmental Scientist
EPA, Region 4
345 Courtland Street
Atlanta, GA 30365
RE: Koppers Company, Inc.
f I ~J L {) l,(_l,U" , --
-----Ref. 4
Forest Products Grouo
Raleigh, North Carolina Plant
Dear Mr. Young:
The Koppers Company, Forest Products Group has reviewed the area
around the old Cellon operation at the Raleigh, North Carolina
plant for pentachlorophenol contamination and has taken action
to clean this area where required. The following has been done
as part of this effort. ·
1. A physical cleanup of this area was conducted. This
involved removing approximately 220 tons of con-
taminated soil and shipping it to SCA Services, a
secure landfill in South Carolina.
2. Three active wells, an abandoned well and the two
surface storm water discharge, leaving the plant
were. sampled on May 6, · 1978 and analyzed for
pentachlorophenol at the Koppers Company's,
Monroeville Research Laboratory in Monroeville,
Pennsylvania. The results of these tests are as
follows:
Active Hells
Main Office Well /fl
Main Laminating Plant Well 4,12
Truck Leasing Building Hell if3
Inactive Well 1
East of steel shop
Writer's Oi,cct Oi.11 Nt:mbcr _______ _
Penta npm
<0.0004
<0.0004
<0. 0004
· 0 .092
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Surface Storm Water Discharges
·East Discharge
Penta ppm
O.O'J6
0.0013 Lake Discharge
The only well that a meaningful amount of pentachlorophenol
was found in was east of the steel shop; This well ·has
been monitored by Koppers for the past few years and has
shown a significant improvement. The pentachlorophenol
contamination has reduced by a magnitude of 2. As
reference, the Bureau of National Affairs Inc., Environ-
mental Reporter, 2195-2196 reports a recommended ambient
water quality criterion for pentachlorophenol of .140 ppm.
3. Additional testing for pentachlorophenol is currently
being done in the area of the old Cellon operation by
Koppers Company.
4. Mr. Larry Perry of Solid & Hazardous Waste Management
Branch of the State of North Carolina's Environmental
Health Section visited the plant on June 26, 1980. During
this visit he reviewed the site and collected and split
with Koppers four water samples to be tested for penta-
chlorophenol. Koppers plans to work closely with the state
regarding the evaluation of this site. ·
If you have any questions, please contact me at [phone].
RAP:cg
cc: T. A. Marr
P. D. Smith
J. E. Heinz
Sincerely, ~ ~~d.P~
Project Engineer
Environmental Engineering
Forest Products Group
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Koppers Company, Inc.
Pittsburgh, Pennsylvania 15219
l<OPPERS
. Ref. 5
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KOPPERS COMPANY, INC.
HYDROGEOLOGIC INVESTIGATION
OF THE
RALEIGH, NC, PLANT
.·
.,.
"' NOV 26 J0"-1 i-' '~ '~~
,. u-J' """'" '~fl'4_S_T~__!"\\,~/
Prepared by: R. J. Anderson
J. A. Quagliotti
Koppers Company, Inc.
Hydrogeology Group
November 13, 19&4
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TABLE OF CONTENTS
I .0 BACKGROUND AND OBJECTIVES ••••••••••.••..••..•••.•...••••••
2.0 FIELD INVESTIGATIONS •.••••••••.••••.••••••••••..•••..••.•..••••••••
2.1 Preliminary Site Visit •••••••••••..••••••••••••••..••..•..•.••••••
2.2 Borehole Geophysical Investigation ....•••••••••.•.•.•..••••
2.3 Monitoring Wells Installation •••••••..•..••••••••••••••••••••••
2.4. Water Level Measurements ••••••••.••••• ; •••..•••••••..•••••••
2.5 Water Sampling and Analyses .•.••..•.•••••......•.........•••
3.0 GEOLOGIC SETTING •••......•••• · •••......•••••.•.•..........••••••.••.•.
3.1 Geography •••••••••••••••••••••••••••. : ••.••••.•••••.•.•.•••... ; ••••••
3.2 Climate •••••••••••••••••••.•••••••••••••••••••••••••••••••••••••••.••••
3.3 Geology •••••••••••••••••••.•••••••••••••••••••••••••••••.•••••.••••••••
3.4 Ground Water Occurrence ••••••••••••••••••••. : •..•••••••••••••
4.0 SITE HYDROGEOLOGY •••••••••••.••••.••••••••••••.•••••••••••.•••••••
5.0 CHEMICAL QUALITY OF GROUND WATER ...•.••••••.•••••••
5.1 Analytical Procedures .......................................... .
5.2 pH •.••••••••••••••••••••••••••••••••••••••••••••.••••.•••••••••••••••••••
5. 3 Phenols ••••..•••••••••••••••••••.•••..•••••••••......•••.•••••••••••..•
5.4 Formaldehyde •••••.••••••••••.•••••••••••••...•...•.••.•••••..•...••
5. 5 Pentachlorophenol ••..••••••••••••..••••••••..........••••••••••...
6.0 DISCUSSION AND CONCLUSIONS ................................ .
6.1 Potential Sources of Pentachlorophenol.. ............... .
6.2 Influence of the Pond ........................................... .
6.3 Movement of Pentachlorophenol. ........................... .
6.4 Formaldehyde Contamination .•.........................•.....
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TABLE OF CONTENTS (Cont.)
List of Figures
Figure I Plant Map .•.•••••••.•••••••••..••.•••••..•••••••••••••••••••••••..•....
Figure 2 Contour of the Surface of the Uppermost
Confining Layer ••••.••••...••••••••••••••••••••••••••••••••••••••••
Figure 3 Ground Water Contours on I0/18/80 ....................... .
Figure __ ·4 Phenols Distributions ............................................. .
Figure 5 Pentachlorophenol Distribution •••••••••••••••••.••••••••••••••
Table I
Table 2
Table 3
Table 4
Table 5
APPENDIX
List of Tables
Summary of Borehole Geophysical Results ••••••••••••••
Summary of New Monitoring Well Logs ••.••••••••••••••••
Yield of Wells in Triassic Rocks According
to Depth (After May & Thomas 1968) •••••••••••••••••••••••
Monitoring Well Water Levels ...................... , ••••••••• ·
Ground Water Quality ••••••••••••••••••••••••••••.••••••••••••••.
(ii)
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1.0 BACKGROUND AND OBJECTIVES
The Koppers Raleigh plant presently produces glued-laminated wood
products. The plant does not now treat wood with any type of preserva-
tive. During the years 1968-1975, however, a portion of the plant treated
wood by the Cellon process. This treatment consisted of pressure injecting
pentachlorophenol in .a liquefied butane solution into the wood. After the
impregnation was completed, the butane carrier evaporated, leaving the
pentachlorophenol as a dry, crystalline salt. The C~lo_r, treatment plant
was located in the southeastern portion of the site, near the existing pond
(see Figure I).
The effluent treatment system for the Cellon plant included two lagoons.
After the Cellon process was discontinued, those lagoons were "closed."
The closure process consisted of spraying the liquid over a portion of the
field northwest of the steel shop and mixing the remaining sludges with the
soil surrounding the lagoons. Fertilizer was added in both operations, to
enhance biodegradation of the pentachlorophenol.
The plant obtains water from three wells. Well No. 1 supplies the sales
office and Well No. 2 supplies the remainder of the plant. Well No. 3 is
currently used at the building on the plant site occupied by the Florence
Truck Leasing Company. Six other wells have been drilled at the plant and-
are not used for the following reasons:
Well Location Reason for Nonuse
Well No. 4 SW Corner Insufficient Water
Well No. 5 W. of Steel Shop Insufficient Water
Well No. 6 E. of Steel Shop Caved In
\Veil No. 7 E. of Former Lagoons Caved In
\Veil No. 8 Between \V-7 & W-6 Caved In
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W-13
. . .
·--- -..!
W-14
0
OW-4
1-z
<!
.....J a..
(!) z
I-
<! z
:E
<!
.....J
W-15
0
0
W-3
OW-9
.-------, : ______ _: 0 W-11
0
□W-8
FORMER
CELLON AREA
FORMER
L~'bNS
W-7 0 0
W-10
0
W-1
~o
POND
0
Q MONITORING
WELL
FIGURE l -RALEIGH, NC PLANT MAP
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Wells No. 6, 7, and 8 were found to contain pentachlorophenol. At one
time, these wells were connected with Well No. 2 via a header system.
This arrangement may have permitted inter-well flow of contaminated
ground water.
In addition to the problem of ground water contamination, the plant
experienced a fish kill in the plant pond in September, 1979. The cause of
the fish kill was never determined definitely; however, one of the reasons
postuls1ted was that runoff from heavy rains had caused toxic levels of
pentachlorophenol to be washed into the pond.
The fish kill may also be attributed to calcium· chloride, which was spread
on the roads to control dust, and may have been washed into the pond_ by
precipitation runoff. No calcium chloride has been used recently, and
there have been no fish kills since 1980.
In addition to the pentachlorophenol, another possible source of ground
water contamination was noted in th~_ 1980 plant survey -glue wastewater.
The glue wastewater flowed through two buried separators then out of the
larr1inating building, and
the laminating building.
was discharged in the wooded area southwest of
This practice has been discontinued. The glue
wastewater is currently separated from particulate matter and evaporated
in a spray-evaporation unit.
Due to the contamination found in the three supply wells and the possibility
of contamination from the glue wastewater, an initial site visit was ·made
in May, 1980, and the following environmental problem areas were
identified:
I. Pentachlorophenol contamination of surface soils in the
old Cellon area.
2. Former pentachlorophenol lagoons.
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3. ' Existing pond -there was evidence that the pond
bottom sediments were contaminated with pentachloro-
phenol.
4. Pentachlorophenol contamination of ground water.
5. Glue wastewater -formaldehyde contamination of
ground water -(it was later discovered that the results
indicating the presence of formaldehyde in the ground
water were invalid).
4
Investigations were begun by Koppers to study the pentachloropheno}
contamination of the soils at the plant and a hydrogeologic study was
performed to study the ground water problems. The studies indicated that
contaminated soil should be removed from the site of the former Cellon
area and lagoons. These soils were removed in 1980.
The United States Environmental Protection Agency conducted a study of
the site in January of 1981 (Appendix). They found a trace level of an
organic sol vent in a well supplying the laminating plant but concluded that
the trace level would not merit health concern with respect to potable use.
Koppers conducted another round· of ground water sampling in June of
1984. The results of this sampling are included in the report.
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2.0 FIELD INVESTIGATIONS
2.1 Preliminary Site Visit
The preliminary site visit in 1980 included the installation of nine backhoe
test pits at the site. Water samples were collected from five of the pits,
from seven existing wells, and from three surface water sources.
Soil samples were taken from several areas of the plant on several
different occasions to determine pentachlorophenol concentrations in the
plant soils. Based on the results of these samplings, soils were removed
from the plant on two different dates (April and May, 1980). The soils
were removed to a permitted, commercial chemical waste disposal site
(waste removal manifests are included in the Appendix).
After the contaminated soils were removed, an in-depth soil sampling and
analysis program was initiated in the area of the former lagoon, former
Cellon treatment area, and former warehouse area. Based on the results of
this investigation, contaminated soils were removed to a permitted disposal
site in November, 1980 (see Appendix for waste removal manifests).
A more detailed soil investigation was done in the area of the former
lagoon in June, 1981. A map of the lagoon area, sampling points and
depths, and results is included in the Appendix.
2.2 Borehole Geophysical Investigation
Dependable well logs were not available for the eight existing wells at the
plant. Six logs were available, none of which could be matched with a
specific well. These logs indicated well depths of 200-1/00 feet.
A borehole geophysical study was performed by Law Engineering Testing
Company to obtain information from the existing wells (see Appendix for
logs). Information concerning underlying stratigraphy and porosity
differences was the primary goal. This data would identify possible
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aquifers and confining layers. It was also hoped that the logging would be
able to identify separate zones of different qualit{ water flowing into the
well. The following geophysical logs were performed in the wells:
1. Temperature.
2. Long/short normal resistivity.
3. Dual spaced density/porosity.
4. Composite, including:
a. Mechanical caliper,
b. Single point resistance,
c. Natural gamma ray,
d. Neutro'n.
Not all logs were performed at each well.
The geophysical study indicated that all of the wells had caved in and were
much more shallow than when first drilled. Well depths ranged from 73 ft
to 210 ft (compared to original depths of 200 ft to 400 ft). The geophysical
logs indicated numerous zones of high porosity in the wells and also
indicated confining zones in all the wells except Well No. 2. A summary of
these findings is displayed on Table 1. The survey indicated that the
shallowest confining zone occurs at a depth of approximately 50 feet. A
rnap was constructed showing the elevation of the uppermost confining
zone. This map, included as Figure 2, was used to design the depths of the
new monitoring wells.
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Wel_l
No.
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4
5
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·3
TABLE j
SUMMARY OF BOREHOLE GEOPHYSICAL RESULTS
High Porosity Confining
Zone Layer
.
22-32' enlarged hole 60-63'
78-107' high porosity 154-158
Several other high porosity • >,
zones
0-55 enlarged None
30-45 I (enlarged hole) 53-78 (Clayey)
53-78' 78-93 (Very tight)
40-60'
120' (medium porosity) 60-100'
140-155' (very high porosity)
12-] 9 I 58-76 I
"29-34' 82-90'
25-35' 64-67'
73-76'
.15-29' 56-62 I
77~79' (enlarged hole)
7
Total Depth
of Well
189' .
.
73 I.
210".
165'
120
151 I I
·112·
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l\t
0
W-13
W-14
W-4
W-15
1
FIGURE 2 -RALEIGH, NC
-8
,-------. : _______ : OW-II
l~t
'----+-+~(
0
s
0
W-10
100'
Q MONITORING
WELL
CONTOUR OF TIIE SURFACE OF TIIE UPPERMOST CONFINING LAYER
.Based on a Plant Datum of 100 Feet
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2.3 Monitoring Wells Installation
The existing supply wells penetrated a number of different aquifers and
were therefore not adequate for determining the water quality and flow
direction in the uppermost bedrock aquifer. The locations of the new
monitoring wells were chosen to provide a ring of monitoring points around
the plant. The depths of the wells were chosen such that the wells
terminate at or above the uppermost confining layer identified by the
geophysical survey.
Seven new monitoring wells were installed by the air rotary method in
August, I 980. All of the wells were constructed with a 2:J ft length of 6-
1/8 inch diameter steel casing cemented into rock. Below this surface
casing, the well was left open-hole. Table 2 summarizes the depths and
yields of the wells.
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The wells were ·developed using the air compressor on the drill rig. Any
water present in the wells· was blown out of the wells for at least 30
minutes once the well_was completed.
2.4 Water Level Measurements
Upon completion of the drilling, well-head altitudes were determined by
standard surveying techniques. · Elevations were referenced to an arbitrary
benchmark of I 00.0 ft on the concrete slab of the porch of the sales office
building. Six rounds of water level readings were collected during
September and October.
2.5 Water Sampling and Analyses
Ground water samples for the initial investigation were collected in 1980
on August 21, September II, and October 27. The wells were sampled
again on June 2, I 984. During the August 21, I 980 sampling, the wells
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D TABLE 2
SUMMARY OF NH/ MONITORING WELL LOGS
I
JULY, 1980
I Well No.
9
Depth Yield
64 ft Dry
m 10 55 ft 30 gpm--
1··.
11 57 ft 1 gpm ~
I 12 . 62 ft Dry
.
I 13
14
55 ft Dry
53 ft Dry
I 15 50 ft 1 gpm -
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were pumped with a submersible pump until at least three casing volumes
of water had been evacuated from the well. The wells were then sampled
using a stainless steel bailer. (Wells No. I and No. 2 were sampled from an
inside faucet after allowing approximately three casing volumes to flow
out.) The water sample was placed directly into specially prepared sample
bottles which contained the appropriate preservatives. The samples were
then refrigerated until being shipped to the laboratory via overnight air
express.
The September, 1980 sampling was confined primarily to the new monitor-
ing wells. Three casing volumes of water were removed before the samples
were collected; however, this time the evacuation was performed with a
stainless steel bailer instead of a pump. Sample handling was identical to
the August procedure.
The set of samples collected in October, 1980, involved all available wells.
The evacuation procedures were identical to the September sampling
(evacuation by bailers); howeve_r, the sample-handling procedures were
changed because of_ turbidity in the samples.
Most of the water samples collectep at the Raleigh plant were extremely
turbid. Ground water flows at low velocities under laminar flow condi-
tions, and therefore does not transport the sediments often seen in well
samples. Turbidity is thus a function of sampling, not ground water flow.
Because of this, the samples were filtered in the October, 1980," sampling
so the results would not reflect the quality of the sediments which are not
transported by ground water. Filtering was done in a field laboratory at
the site, prior to the addition of the appropriate preservatives, to prevent
any reaction between the preservatives and the sediments. No more than
two hours expired between sampling and filtering. Filtration was per~
formed with a vacuum pump and a Buchner funnel fitted with Wattman 42
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filter paper. The filtrate was then split into individual bottles with the
appropriate preservatives, and sent to the laboratory by overnight air
express.
Sam piing and sample-handling procedures for the June, l 984, sampling
round were identical to the October, 1980, sampling round.
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3.0 GEOLOGIC SETTING
The majority of the information in this section was obtained from "Geology
and Ground-Water Resources in the Raleigh Area, North Carolina," by V. J.
Maj and J. D. Thomas, North Carolina Department of Water and, Air
Resources, 1968.
3.1 Geography
The Koppers Raleigh plant is located just north of Morrisville, Wake
County, North Carolina. The plant is situated in the Piedmont physio-
graphic province, an uplifted and partially dissected peneplain. The
topography is very gently rolling and most interstream areas are broad and
flat. Streams in the province have v-shaped valleys.
The plant site is located in the Neuse drainage basin. Surface drainage
from the site flows toward Crabtree Creek and eventually into the Neuse
River.
3.2 Climate
The average annual temperature is 5.9.5°F, as measured at the nearby
Raleigh-Durham Airport station. Annual rainfall is 43.6 inches; with most
occurring in the months of July, August, and September. The driest months
are October, November, and December.
3.3 Geology
The plant is underlain by a thick sequence.of sedimentary rocks of Triassic
age. These deposits are part of the Triassic Durham basin, a trough
reported to be up to 10,000 feet deep. The Jonesboro fault, approximately
3 miles east of the plant site, forms the eastern contact of the Triassic
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rocks with the older, metamorphic rocks to the east. The strike of the
bedding is to the north-northeast, and the dip is toward the Jonesboro fault
(southeast) at IO to 15 degrees.
Triassic rocks include buff arkosic sandstones, red argillaceous sandstones,
maroon shales and coarse fanglomerate. Black diabase dikes intrude the
Triassic sedimentary rocks at several locations. These dense intrusions
range in thickness from a few inches to several tens of feet.
The bedrock weathers to form a mantle of unconsolidated, residual soil
(saprolite). The sandstones weather to a light brow!) sandy loam soil, while
the shales weather to a dark red to purple clay.
3.4 Ground Water Occurrence
The Triassic rocks. are poor aquifers. The average yield of wells producing
from the Triassic rocks in the Raleigh area is only 6 gpm. (This number is
probably high because many of the yields were determined by short
duration pumping or bailing tests which do not accurately evaluate
sustained yields.) The average yield per foot of well is only 0.04 gpm and I&
percent of all Triassic rock wells yield less than I gpm. Table 3
summarizes the yields of &I/ wells producing from Triassic rocks in the
Ra! ei gh area.
Diabase dikes are very poor aquifers; however, they play an important role
in ground water occurrence in the area. A dike is an intrusive body of rock
which usually creates fractures in the host rock by the heat and force of
the intrusion. These additional fractures can increase the secondary
permeability of the host rock greatly. ~ost of the high yield Triassic wells
in the Raleigh area are probably adjacent to diabase dikes.
Rainfall is the primary source of recharge to the Triassic rocks. It is
estimated that recharge is on the order of l 00,000 gallons per day per
square mile in the Triassic Basin.
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Range in
depth
(feet)
0-100
l 01-150
151-200
201-250
251-300
Greater
than 300
All wells
TABLE 3
YIELD OF WELLS IN TRIASSIC ROCKS ACCORDING TO DEPTH
(AFTER MAY & THOMAS 1968)
Number Average Yield (gem)
· of depth Per foot
wells (feet) · Range Average of well
25 81 0-25 9 0.11
25 124 0-25 7 .06
16 178 .5-15 4 .02
10 221 0-12 4 .02
5 280 .5-5 3 .01
3 419 . 5-7 4 .01
84 153 0-25 6 .04
15
Percent of
wells
yieldjng l gpm
or less
12
12
25
30
20
33
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4.0 SITE HYDROGEOLOGY
The saprolite at the site consists primarily of red silty clay, overlain by a
tan clayey silt layer with traces of sand. These sandier, tan soils are up to
IO feet thick at the upper elevations of the plant (western portion) but'thin
to less than a foot in the lower portion of the site.
The Triassic rocks underlying the plant are composed of thick, maroon to
purple shales interbedded with thin 0-3 feet thick) arkosic sandstones. The
sandstones in this location are composed primarily of quartz, feldspar and
iron oxide.
The shales underlying the plant have very little primary permeability.
Most of the ground water is stored in and moves in secondary features such
as joints and fract.ure planes. Bedding planes are also a source of water to
wells in the area. The sandstones have a higher permeability than the.
shales but the joints and fractures are still a major factor in the storage
and movement of ground water.
The new monitoring wells drilled at the site (with the exception of Well No.
I 0) are indicative of the water supply problems in the area. Four of the
seven wells were described as "drY'' and two yielded only one gallon per
minute. Well No. IO yielded 30 gallons per minute for a short period of",
pumping. This yield ~he presence of a diabase dike in the vicinity >
which would have caused a concentrated network of secondary fractures. '
Six rounds of water level readings were collected during September and
October of 1980. Water levels declined an average of 1.5 feet during this
time period. Ground water elevations measured on October 28, 1980, are
· plotted on Figure 3 with a contour map of the water table. (Only the .
/ elevations taken from the. new wells are used in constructing the water:'
table maps because the older wells may reflect a combination of heads
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70
OW-4
D
0
W-3
W-9
0
W-1
,-------:
' ' ·-------
o Do W-5 W-6
POND
0
Q MONITORING
WELL
FIGURE 3 -RALEIGH, NC
GROUND WATER CONTOURS ON 10/28/80
Based on a Plant Datum of 100 Feet
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from several aquifers.) This representation of the water table is consistent
with maps prepared from earlier measurements.
A seventh round of water level readings was collected in June, I 984. Table
4 gives a summation of the water levels measured on all dates. Levels
increased between October, 1980, and June, 1984. This is probably due to
seasonal fluctuations in the ground water table; levels tend to decrease
through the fall and increase in the spring and early summer. The water
table ·contours from June 2, 1984, indicate that the general flow pattern is
similar to that mapped in Figure 3.
The direction of the horizontal component of ground water flow is
perpendicular to the water table contours. From Figure 3, it can be seen
that a ground water divide runs through the plant roughly·on a line between
the east corner of the. pond and Well No. 12. Ground water flows generally
to the north and south from either side of this divide.
The pond serves as a recharge area for the local ground water. Surface
water flows into the pond and the water seeps out through the pond
. bottom, creating a ground water mound. The hydraulic gradient is 0.06 just
east of the pond and 0.05 just west of the pond. The steep gradients may
be due to lower permeability materials in the vicinity of the pond. It is not
pos_sible to determine the specific discharge area for the ground water
from the limited data available.
- - - - - - - - - - - - - - - - -l!!!!!!!I -
TABLE 4
RALEIGH, NC
MONITORING WELL WATER LEVELS
WELL NO: W-4 W-5 ~ W-8 W-9 ~ W-11
WATER LEVELS
09/10/80 67.25 84.49 86.65 86.64 88.36 86.61 84. 91
09/25/80 66.99 84.40 86.48 86.60 87. 61 86.53 84. 16
10/03/80 66.74 83. 74 85.81 85.93 87.86 85.95 83.99
10/10/80 66.66 83.32 85.65 85.68 88.03 85. 61 83.74
10/17/80 66.41 82.87 85.23 85.35 87.18 85.20 83.30
10/27/80 66:26 82.67 84.98 84.43 87.05 85.08 83.29
06/02/84 72.24 84.65 88.78 88.63 88.41
NOTES: Wells W-1, W-2, W-3, and W-6 are supply wells with spigots.
The casing was broken off of well W-8 sometime before June 2, 1984.
A building was constructed on well W-9 sometime before June 2, 1984.
w-iz W-13 W-14 W-15
89.34 73.18 69.08 69.99
85.17 68.75 69. 41
86.75 72.58 68.50 69.41
86.75 72.51 69.00 69.24
86.17 72.06 68.08 68.86
86.22 71.96 67.95 68.89
91.37 80. 79 73.45 73.26
All weHs are constructed of 20' of 6-5/8" steel casing cemented into place. The monitoring interval is
open-hole.
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5.0 CHEMICAL QUALITY OF GROUND WATER
5.1 Analytical Procedures
The ground water samples were sent to the Koppers Environmer1tal
Analysis Laboratory in Monroeville, Pennsylvania, for analysis. The lab
performed the following tests in accordance with methods outlined in
Standard Methods for the Examination of Water and Wastewater, 14th
edition:
pH
Total Organic Carbon
Biochemical Oxygen Demand
Chemical Oxygen Demand
Phenols
Totaf Dissolved Sol ids
Conductivity
The laboratory analyzed the first two sets of samples in the 1980 sampling
for formaldehyde by a spectrophotometric method which determines
carbonyl. This value was then used to calculate formaldehyde. The
laboratory then developed a polarographic method which is specific for
formaldehyde, and this was used for the final set of samples.
The laboratory analyzed pentachlorophenol using a gas chromatography
method developed by Koppers.
Aliquots of the third set of sam pies in I 9&0 were sent to the independent
laboratory of D'Appolonia Consulting Engineers, Pittsburgh, PA, to
. expedite analysis of specific anions and cations.
The results of the analyses of the I 980 samples are listed on Table 5.
20
-----------------------------l!!!!!!!!!!!I l!!!!!!!!!!!I l!!!!!!!I -bi-1 bi-2 Pll·l ..... bi-S ..... b,-, l>/•8 b,.9 Pll·lO bw-11 bi-12 Pll· ll bw-14 Pll·IS ·-· low-1 low-2 low·l b,.4 ..,.5 <JW•6 .... 7 011-8 011-9 0'1•10 <>I-II ,,1-12 low·ll OW• 14 OW•l5 ood ·• Tl.ILi S CIOUKD VA.TU QOALlff lil.llCB PUl'T T0C --/L M>D ••/L COD --/L e/21/80 9/lt/80 10127'80 712/84 8/2t/80 9/11/80 10'17/80 """ 8/2li60 9ill/80 10/27/80 7/ll84 8'21/80 9111/80 10/27/80 712/V. 7. 7 7.8 7.95 ·4 19 1 10 14 1 70 < 10 1' 7.5 7 .6 7.11 4 4.5 I 7 • 2 so < ID II 7.7 1., 7.8% • 4.5 I 7 10 , I 25 80 14 7.4 7.4 7.84 4 1S 1 • 11-(1 85 < 10 17 7. 7 8.0 8.IJ 4 4.S I 8 6 1 87 < 10 18 1., 7 .4 7.6 7,92 6 4l s 2 6 6.0 14 2 JO JS < ID 16 7.5 7.8 7,S7 6 12.s 2 ' 6 2 25 SI ' 1., 7.6 7.92 6 25 l 6 10 2 45 67 22 7.6 6.9 7.9 6 34 4.S 7 s.o 8 22 85 < ID 7.5 7.2 7.8 7.91 • s, 6.S 2 6 l 4 2 40 (ID < 10 JS 8.2 7.l 7.8 7.88 14 J6 8.S l 6 <I 6 2 27 <ID < 10 12 7.6 7.4 7.6 7.87 10 34 6.S 2 6 (1 l l 25 70 < 10 1l 7.8 7.6 7.9 7.88 14 21 14 2 s 4 8 l 1S (ID < 10 1l 7.4 7 .4 7.6 1.12 12 27 124 2 6 4 141 1 10 (ID lll 12 7 .5 7.J 7.J 7.66 12 20 17 2 s <I 4 2 20 (10 45 1l 6.8 7.4 46 16 <I 2 JS ( 10 Pbenol,. ••/L TDS --/L Cood •• o,/c• roraaldeb•de Peotachloropbenol, ag/L 812\180 911\180 10/27/80 7/2/84 11/21/8[ 9/11180 10127180 712 /84 8/21/80 9111/80 10/27/80 8/21/80 9111180 10127/80 8/21/80 9/11/80 10 127 lg() 1121s < .oos <.005 <.oos 316 322 ]76 479 384 I (.] (.0004 (.0004 • 0021 0.01 (.005 .006 316 271 290 SJO 355 (I <.J (.0004 <.0004· (,001 .008 .0143 <.DOS 25] ,so 257 ]30 390 q (.J .00048 <.0004 (.001 ~ .005 .<.005 (.005 416 461 492 720 610 <I (.] .00052 (.0004 <.DOI .006 <.OOS <.oos 237 206 234 JSJ . 150 (I <.J .ooo, <.0004 (.001 < .oos <.oos <.oos (.005 487 764 574 406 870 800 800 I. <.s <.J .on· .012 .008. .091 .008 <.oos <.oos 468 419 517 810 ••• <I (.J ,91 ~ 1,0 · .042. < .oo.s .0095 <.DOS 495 244 40] 880 179 (I (.J ,OJJ .23 .006l' ,DI <,DOS (,DOS :IOS ZIS 341 481 470 271 <I (,S (,J (,0004 ,00059 .00079 .006 (.005 .0085 (,DOS 487 471 479 524 860 750 700 <I (,S (,] .7 6.2 1,9-2.3 .26 ': .006 <.DOS <.oos (.005 826 457 461 485 1400 780 620 <I (.S (.] .OU ... , ,017 ,00)1. .005 <.oos <.oos (.005 ll9 328 ]16 Jl6 520 450 420 (I <.s (.J ,00068 .00059 (.0004 (.001 < ,005 (.005 (.005 .OU 194 207 207 276 ]20 270 275 (I (.5 <.J .00044 .00069 ,00093 (.001 .OJ <.oos <.oos (.OOS 496 430 ]97 710 600 520 (1 <.s <.J (.O~ .00052 .00085 <.001 ( ,005 coos (.005 <.005 280 268 264 JIO 437 400 ]25 <I .s (.] ,00052 .001 (,0004 (.001 (,005 .DOS Ill llS 145 Ill <.S (.] .00056 (.0004 .0021 N -
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5.2 e!:!_
All of the pH values are within the effective secondary drinking water
criteria of 6.5 to 8.5.
· 5.3 Phenols
The EPA Water Quality Criteria Documents (November, 1980) derived a
criteria level based upon available toxicity data for the protection of
public health of 3.5 mg/liter. The level for controlling undesirable taste
and odor is 0.3 mg/liter.
Several of the wells at the site have phenol concentrations above normal
background levels for the 1980 samplings; however, none of the values
exceed the 0.3 mg/liter criteria (Figure 4).
The phenols concentrations in wells W-3, W-8, and W-10 all dropped to
below detection limits for the June 2, 1981/ sampling. Only two wells
showed any phenols concentrations for the June 2 sampling, and these were
both very near the detection limit of 0.005 mg/I (well W-2 -0.006, well W-
13 -0.015).
5.4 Formaldehyde
The results obtained from the samples collected during the May, I 980
sampling (see Appendix) indicated the presence of formaldehyde in four
wells. The analytical laboratory subsequently reported that the test was
improperly performed and that the results were invalid. _
The August, 1980 samples were analyzed using a spectrophotometric
· method with a limit of detection of I mg/liter (as carbonyl). Wells No. 1
and No. 5 each indicated I mg/liter of formaldehyde.
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II
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.01
<.005
.006
0
W-13
(.005 -
-<.005
(.005
.,..015
.-----; • ____ _!
.03
<.005
<.005
<.005
W-14
0
.005
<.005
<.005,
<.005
W-15
0
(.005
(.005
<.005
<.005
OW-4
<.~05 -----d
<.005
--<.005
0
W-3
OW-9
.01
<.005
<.005
<.005
<.005
<.005
0
W-1
Sampling Dates:
23
-------. I ' ' ' ·-------OW-II\\
0
W-5
.006
0~-6
<.005
<.005
<.005
<.005
.006
<.005
<.005
<.005
<.005
<.005
POND
10/27 /80
07/02/84
0
0
0
<.005
-~095\· <.005
.008
<.005
O :.oos
W-7
0
W-10
.006
<.oo5
.0_()_lf,;,,,
<.oo5
l00°
Q MONITORING
WELL
Results in mg/1
FIGURE 4 -RALEIGH, NC
PHENOLS DISTRIBUTIONS
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The September, 1980 analyses were also performed by the spectrophoto-
metric method, but the lab had refined the limit of detection to 0.5
mg/liter (as carbonyl). Only Well No. 15 had any detectable formaldehyde
( 0. 5 mg/liter as carbonyl).
A polarographic method was used for the October, 1980 samples with a
limit of detection of 0.3 mg/liter. This method measures the formaldehyde
directly (as formaldehyde). None of the samples contained detectable
quantities of formaldehyde in the final sampling.
5.5 Pentachlorophenol
The EPA Water Quality Criteria Documents specify the limit for penta-
chlorophenol for the protection of public health at I.OJ mg/liter. The EPA
has also estimated a level of 30 ug/liter for controlling undesirable taste
and odor qualities of ambient water.
Pentachlorophenol was present in the ground water in the three 1980
samplings at Wells No. 7 and No. 10 at levels ranging from 0.7 to 6.2
mg,iliter (Figure 5). The concentration of pentachlorophenol in the ground
water at Wells No. 6, 8, and No. 11 was from .008mg/liter to 0.046
mg/liter.
Pentachlorophenol was detected in levels above 0.001 mg/I only in the
wells along the eastern boundary of the plant and well W-1. The
concentrations dropped in all but two of these wells from 1980 to 1984.
The concentration in well W-6 rose from 0.008 to 0.091 mg/I, and the
concentration in W-1 increased from less than .0004 to .0026 mg/I.
It can be seen from Figure 5 that pentachlorophenol was found in the
• surface runoff leaving the plant in 1980. The site named "east discharge"
is a small drainage ditch which flows from the plant. Low levels of penta-
chlorophenol were found in the pond. The separate designations following
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<.0004
<.001
0
W-I3
.00044
.00068
.00093
<.001
. . . '
. ~o (
.00068
.00059 0 <.0004
<.001
0
W-3
.00048
< .0004.
<.001
<.0004
.00059
.00079
OW-9
0
W-5
.009
<.0004
<.001
0~-6
.013
.012
.008
.091
::::
Ll
0
25
\\
.012
.046
.017
.0036
1.0
0 .082
W-7
0
W-10
.7
6.2
1. 9-2. 3
.26
<.0004
.00052
.00085
<.001 POND
W-14
0
W-15
0
.00052
.001
<.0004
(.001
<.0004
<.0004
.0026
0
W-I
OW-4
.00~52 ----d
<.0004 Sampling Dates:
08/21/80
09/11/80
10/27/80
07/02/84 _<.001
FIGURE 5 -RALEIGH, NC
PENTACHLOROPIIENOL DISTRIBUTION
0 l00°
Q MONITORING
WELL
Results in mg/1
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26
the word "pond' indicate the location along the bank where the sample was
collected.
Samples have been collected from three private wells near the plant; the
analyses have not detected the presence of pentachlorophenol •.
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6.0 DISCUSSION AND CONCLUSIONS
The results of the present investigation have led to the following conclu-
sions:
6.1 Potential Sources of Pentachlorophenol
Pentachlorophenol concentrations in the ground water have decreased
between 1980 and 1984 in all but two wells. Based on water table contours
and flow directions, the source area for the pentachlorophenol for all of
the wells along the eastern plant boundary appears to'be the former lagoon
area. The trace amounts of pentachlorophenol in well W-1 may be leaching
from the sediments in the bottom of the pond.
The source of pentachlorophenol in wells W-6 and W-11 may also be
attributed to another potential source. The nearby field was used during
the lagoon closure to dispose of the liquid in the former lagoons. This
practice could have allowed pentachlorophenol to enter the ground water,
and reach wells W-6 and W-1 I. The concentration of pentachlorophenol in
well No. 6 has been decreasing steadily since 1977. Use of the well has
been discontinued, which might explain the decline in pentachlorophenol
concentrations. The pumping would have caused a cone of depression
which may have intercepted a plume of contamination. Thus, termination
of the pumping would have reduced the potential of the well drawing water
from the contaminant plume.
A third potential source for the pentachlorophenol found in Well No. 6 is
the former water distribution system. With the wells joined by a common
header system, it is possible that contaminated water pumped from another
·well in the system could have been inadvertently introduced into Well No.
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28
6. This cont_aminated water could have then moved into the aquifer around
Well No. 6. With limited pumping, this contaminated slug of ground water
could exist around the well for a substantial period of time.
6.2 Influnce of the Pond
The ground water contours indicate that the pond serves as a recharge are
for the local ground water. Surface water flows into the pond, and it was
suspected that this runoff might carry pentachlorophenol into the pond.
The highest concentration _ of pentachlorophenol found in the pond was
0.01 I mg/liter and the mean concentration of nine analyses is 0.0032
mg/liter. The sediments found in the deeper portions of the pond in the
19&0 investigation have pentachlorophenol concentrations ranging from
0.031 mg/Kg to 0.42 mg/Kg.
6.3 Movement of Pentachlorophenol
Analysis of water samples from all of the wells along the eastern boundary
of the plant has revealed the presence of pentachlorophenol in· these wells.
The ground water contours indicate that the direction of flow in this area
is to the northeast. Ground water velocities have not been determined,
thus it is difficult to predict the extent of the pentachlorophenol
movement. The Wilkerson well is apparently downgradient of the plant;
however, no pentachlorophenol has been detected in two separate
samplings of this well.
6.4 Formaldehyde Contamination
Using reliable analytical techniques, the presence of formaldehyde was not
· detected in any of the ground water samples analyzed. Thus, formaldehyde
does not appear to be an issue at the Raleigh site.
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APPENDIX
Contaminated Soil Study (enc.lose di)
Pentachlorophenol Concentrations at the Surface
Pentachlorophenol Concentrations at 0.5 Feet
Pentachlorophenol Concentrations at ·1.5 Feet
Pentachlorophenol Concentrations at 3.0 Feet
Pentachlorophenol Concentrations at 6.0 Feet
Soil Sample Results, 5/7/80 ref. JI
Water and Soil Sample Results, 8/26/80 r-C'..f. 'i
Water and Soil Sample Results, 10/29/80 ,c:F. 1 0
Soil Removal Manifests (e"clo.se&.')
US EPA 1981 Study rc:t-C,
"Hazardous Waste Site Investigation, Koppers Company,
Inc., Morrisville, NC, January 27, 1981."
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CONT AMINA TED SOIL INVESTIGATION
Prior to, and concurrent with this hydrogeologic investigation, the Forest
Products Engineering Department has been conducting an investigation of
the contamination of surface soils at the Raleigh plant. Although not a
part of this investigation, the findings of the soil contamination study
relate to the ground water quality. A discussion of the study is therefore
included.
A set of .soil samples was collected in March, 1980, and as a result of that
sampling, contaminated soils were removed to a perrriitted disposal site in
April and May, I 980 (see manifests). A more wide-spread set of soil
samples was collected in June, 1980, resulting in removal of additional
contaminated soils in November, 1980 (see manifests).
Concentrations of pentachlorophenol have been found in the June, 1980 soil
samples at levels as high as 220,000 mg/Kg. This figure may not be truly
indicative of the soil because the sample may have included a crystal(s) of
s~d_ium pentachlorophenate. Pentachlorophenol was found in the June,
. 1980, samples in the following concentrations:
No. of PCP Range PCP Mean
Location Samples mg/Kg mg/Kg
Cellon Treatment Area 14 3.2 -4,700 621
Warehouse Area 8 31.0 -4,000 1,319
Former Lagoon Area 0.81-220,000 20,060
In June, 1981, another in-depth soil survey was conducted in the area of the
old lagoon. A map of the lagoon area, sampling points, and results are
-given in the Appendix.
--------SOLID WASTE \IANAGEMENT DIVISION
Y-P'-" of procru
·hi ch produetd ll'hU'S: -c,-,-,-,..,.,,w,....o_o~dc.,-=-Pcrr~e',-Cs_e.c..cr_v_i_n__,_~_...., __ ~~~=
tLxa~pir ~r~JI p 1tin1, rqu1p~rn~ clrininc, 01 lln&
wastr~atrr ltr3tmrnt, p!cklJnc bat~. ~ctr~:cu,P; rrf!nln;}
"htd. typr or ..,~strs:
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Chuilcal toilrt wHtrs
ll;x.up:,·,; ilyJr-:,chlotlc acic!, Jir-t, cau5tlc soda,
phtnnl1r.,, ,olvrnt, (list), Nlal, llht).
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facil"it,· n:u•rJ ~rlo,.· and "J!, ac,·tj't~J.
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-
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..... {t,;u;J,tT'J 15~rHt) (Citr) •
T<J,phon,. n=bn,(919) 467~6[5[ ,.o. o, Con\r,<l :1o.: 440-OG-2001
<nd" ,10<,d by: Raymond Perr ou .. 4-1-80 '
1.0 .,cid soJ:.,tion
2.0 -1.]b.Jinr sc-lut1on
J,Ql PruiciJ-:-~
!; D Tani. botto11 H"dlttnt
9. 0 Oil
•
4.0 P~int s!-J!;r
S.0 Sohn:t
10. 0 tlrilllnr 11ud
11.ti Ct1nta::1lnatrd !-t"II ~ und
ll. 0 Cannrry,wastr
Cr,:::rcnt>nt ~:
6,0 hturth_d Jra.! sludir
7,0 O:r:dCiil toi 1U wa;<teos
(ll.1Jt1,1:r,: llyJrochlorlc: acid, lfn-t, ra:.11tic soda,
j'~r11c-l10, c<olvrnn lllst), .~ta!, (li,t_l,
ur~~n1c;< (list), cr~nlds)
._P ent_achlo rophenol P !.i.l~lccs_. __
1. -----·------. ··-----
) .
I. -------------·------'·-------------
Cl•r>l;\inrrs:
(hu~
rhplc•l uur: 0 liquid
13. 0 lJtu wute
It, 0 '+Jd , w■tu
IS. 0 BriM
Contf'ntratlon
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- - - --------SOLID WASTE f!.ANAGE!-IENT DIVISICJN ~ - ----____-.
PROO'JC(A, or WASTE (U\Jst be filled b,· proJuCu)
,,..,_ Cprtnt or typ,J: · l<oQ:pe rs Company~ Inc.
"" up ,JJrus:Highway 54 West, Morrisville, NC
(NuNJrr) IStrrct) (Clty)
Td,phon< nuabn:[phone] P.O. or Contml So .. 440~0G-200l
OTdu plHed by: Raymond Perr
Dl:5(11.IPTlcr.; Of W.-.STE (~t..Jst be fillrd ~)' prot!ucH)
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or~•n1n (lisc), cylnlds) ·
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~r:ur llq:.,i~ 1,,ntr h;iulcr', rt'ti~rntici:, .,., ':f .,;,rl1,·.1,1<'): _________ _
Job no.:
Thr ih•,-:ribrd .,Htt vu h.1ultJ by llt to :h .li."j't''11
htllitr n.11trJ tirlow and 'N:IS •t\'tpttd,
I «mf, lo, ,J,rl,rc) uod,r pco,,l!y ~ fi J or pc-rJ.J;.; th.it thr (ort1~01nc ls 11:rc /)· ./
anJ (OIH'~l. -------.• {)_J_j --
Sl\ .•: f l ~ r,:"J J,., •
liisi'OSLR 1..lf '-\S{!-. l~knt he till<'J bY · · ,r: --
0 .,,..,('~
i 'l~f .-i-1
,,_ (pdnl « tn>•J: :.S:C__..!j-'7-,-·····----·
Sil< ,JJr,s;, ____ f~1.tJ..~.QO¥-'-D...L---·---
Tnt: h:.ulc, ;,L-,n: Jcliv«rcd tht' ,lc,-.::rit,,•j ~.n·.~ 1:-:h1, Ji-.r,••;d !-1:II.~• ,·:! 1: -,• .. :-.
1c<f"rt.1blt r:1u·rl1I undrr 1ht' trr111• nr rh,· ,,1:-1 11,•.1c ~.10.l\:.....-1·rit l1i,·1\\,,n', rr,4, .. n•-r"·
St.UC 0c-r.1n1t1c-nt of lle-•llh ,nJ l:nYtror:..-,,i:.; -~ .. 11~1~,1• .. n·,ul3llOT"I'.
~.::!r:tlt)' :-.tH'Jrc-d ~ (if :111rll,•.:,';,!c-)· _!:j~</S_bD._t:.1.itc """ (i:" .,ii~···
Th, Sitt t1r1·ru11r st\:all l1.1hpit :I h"tlhr.-(l'lj'.
Kanaa,•cnt l•1yision,
,•
----~.\.~ . ,_ ' .... ,~ ----· --
•
N!Xl'l..'CU rs •A.S"'l't (1'ttt .. (Ille-cl by p~n)
.._ (prlat or,,,..,, Koppero Company, Inc.
Pld vp .,,,;,..,fighway 54 Weet,. Morrleville, NC
· l.l.111Wr) lSUttt) {ChrJ
T•I~ ,....,.r:(919 j 467-6151 ,.o. or Contu<t '°" 440-0G.;.2001 °'"" ,11,.a •r: Raymond Perr o.u: 4-1-80 ~
rrr o( pronu
rhich pt04i.Ktd wntu: ,vood Pre·serving
tE:lu-pie?. -t.>i phunr, ~u,pe,m-: du.1u111, oll Jrlihn1
vu1rw1ter trutMnl, picllinr b.at~. PfUDJCUII NClnlntJ
>t!-OTPTIOS Of W"'-<"Tl f}lnt bC' ti I lr-d ~r producn}
Tut bottoa udllMftt
Oil
1.0
1.0 ,.ti ,.o
s.□ . ,.o
Add tolut Ion
Alhlln• ,oh,tlDIII
,-utlcido
Paint 1Ju.!tt'
Sol..-.ni
,. 0
,. 0
JO, 0
ll. D
Jl,0
IJ.0 u.o
J~ r:
O,IIIIJII u
Conuatnaud IOU I uad CaftM,r·.,uu·
7.0
0 ,:p,oi'lt'1'1 ti ;
Tttrut~·J had th.kit•
Oiulc.al fOl lt'I WUIU
lJtH trUU
ti.rd ' ..... .,.
lrln•
luaplu: HyJrochloric acid, llw, C&uttlc sodi,
jhrnollrs, MIVl'T'IU (list), wt.alt (list),
~r1.anir1 (Jl11), cyanJJsl
Coouotntloa
i.-r \
Pentachlorophenol Frills 0 60
-------------
. O.:.rua:s
" .. !110lld
-------..
O~Of'l'ffl ..
Ot>uNJ'I .
·1n .-i>·
Ob•1•
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D
D
D
D
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ppa
D
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:,~~::i::,:.:~,, (,v,'/f /VIS TR u£J<7n
l:~.,,llll:Kfl iSth·lt't•
Ttlc,honc •-••( 7{',1 0 ff 7 4
Job no.:_~4..:.:0c..4.=-,2:... ____ ~~-or J,j.1.!1 ;r tup· _ _\_ ____ unit
0 v1:uu■ t ru,·l ":u•c!f, ·-··--
n.. 4ucrlbf-4 wsst• vu haultJ br ~~ to tM' ~1!ro,al
hclllty r.1w'4 Nlow ud 11:1t ac~rruJ.
□ T latt,rJ.
--
.,. : ;,:,3
l!f" .:,thn. jJ_l!'
i ~f•t'; I I
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Slh aJJnu: · Q, ~l ~•-l---,,•~11-------------
Tht h;,uhi-al.,.:,1>• Jdhon:Jj/:~£:W.l~Q .. :,/ :., ~~-,, .:t~p,.,-.;,1·t.J.:1l1t.•· J~,I ,: •o .,·,
tcC'•pubh 11u,rh.J urwf•r th• 1~,11111-nr th,··.•, 1 •otC' ~1.tn,,t""'""' lii•,•1,, ,n•,. "-t111t1·~••":
Stau Dtpartaent of l~•hh 1nJ t.nnron1H'nt>1 :~~r:1:~•l', rr1ul.H1on1' ..
Q'.Unttty ac~surNf ll
k&Adl1n1 wthoJ11):
a ·rsco.,.,,,
CJ nr1tMflt (sJW"CltrJ: · ____ ·-·-·-·.,----. fG::i:-p&u: lr.,nr.u.,,1::r., ~c:;'rJ.! ,t,•it:,•:i. prr.:1r,t:1t1..::,,
C dh;,ou1'(spcdfr): O?""ftJ Osru.i.~::i, □1 Jf:11 0111JC"t~1.l:. 1,,r::
. Uothtr (tP"<'H1l·_ -· __ ··-.. ·-·--· ·-· •.•. ' . ·u.~~•ic u t-•Jd for 41tj'OP.~J •l_s~u ,r,•:1r, !u:1:
"ti II"' .. I d,r •: -~ ,., ('I),_"\_ __
• c1.u,rr tor :,~,3/.•r~o.w. .t t""r, ... rr /lt?bbS
'• 011 OW !orc-s11i111 is U\H' .111d corrttt. •"!'f£,.,.~-----
·•· . • . ~ ,..._: · . · S111ut1onr ol •u n ... ih, ('lrtr■,~r •hall ,uh-it • ,.,11:,i. "•"''i"Y #', f'l~~. ,·t'91"'lrlr,I
._..,...,., Divl&IN,
fRIY.l'JCUl Of IU,STT ('k.ut be filled b:· pro-hJctr)
J-;JrM (pint or trp-t): Kopp~·r?_ Company, Inc.
'"' up ,Jd""' Highway 54 West, Morrisville, NC·
(t,u~rr) IStrn1 J City)
Td,phon• nu•bH:(919; 467-6151 r.o. or Cootnct '•·. 440-OG-2001
OTdrr plHtd br: Raymond Perr """ -4-1-80
Typt of procus
lo'hi..:h proJ•Jctd ... aHr$: \Vood Preserving l Lu -::pi e?: -"'t' tl I -=-p~l ,~,=,~.~,=,...;.,=4=u=, ~p.,.'-n-,-,~1-,-,-.-,-,-,-,-.-, -, _J_r_i_l_l_i~n C
"S51t•ltu trc:;o::z,tr,t, picllin, bath, retrole:wr refinlnt)
Tank bottom Jcdlcent
OiJ
•
I. D
2.D
i. Cl
,.□
s.D ,.□
7.D
.~.:id solution
.l.H.alinr solulion
Pnticid~,
Paint slu.!;:e
~ohcnl
.,. D
9. D
JD, 0
II • Ill
JI. 0
Jl. D u.o
JS. D
Drl11ln1 ■ud
Conuainatcd set I ,_. und
Cannery "Ute
Tttranh~ I JuJ sludse
Chr111iol toilet wHtcs
Lltel vute
\.\J~ , wattt
Brine
D·:-::,.-r (:Oprc:i!y) ----------------------
Cc ~rcn~nt r-:
(tJ.Ll".ylc:s: llydrochloric .acid, li~e, ,:1u1tlc soJa,
pl.irn,;,\in, 'IOlvrnts (11st), Nlah (liHI,
o:►,11.10 (11st), cy,,nldsl
,. ___ PentacHorophenol Pril_l_s __
l. _________ _
s.
•• -------------------
0
Conct'nl ration
Lovirr \
60 0
□ □ 0
□ □
Pr"
□ □ □ □ □ □
i
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TC'IC'rhe>nt' 1nz:-:~rr• , ~t.~~~~~~ "itk t1;-· .!-.. __:_T1r.r:
5f:J1(' liquid .... Ht:' ~:mlt'l' ~ . ';'l:l "lO ~ir :lj'[ll,•,":,?r): ________ _
Job no.: 4043 \o, o( lo.JJJ or 1r1p .. _ _j_ ___ .en;1 "'' '--~
D \'acuu11 t r".Jd, o/,,c,LJ
Tl1t" h;.ulot1· ,-L,,>\I: Jthvt'ri:d ~:-e Jc·.,.iilwJ ... ,.,,l, 1,:1 ti.I> .!1,;,t••,;,d f.1.111~\ ml 1: •I··
ac:c:Pr1;1ble r..llrrhl unJrr !hr trr~• of th, ,.,.liJ ••He .u.\1'1,1,,.• .. nt 11i\1,i,•r>'• rru,.,
State Orp.,n•ent•or lle•lth ar.J l.nnronQtntJi l.c-'.'''~•I'~ '/iul:itic-r.,.
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lfandl1na, m:thoJls}:
1. ,·
------------------

-
-

-
-
----SOLID WASTE l".AfAGEMENT DIVISION -------
,~u or w.a.s:E f~t..,st bt" fl I hd br ;,roduc,r)
MM (punt Dt l,VC): Koppers Company, ln~,c•:.---------
'"' up ,dd,0 .,Highway 54 West, Morrisville, NC
11',ullbtr) · tSt ru11 (CUy)
Td,pl,ou,· ""'°.bu:919; 467-6151 P,O,
0rdu phc•d br: Raymond Perr
or Con:mt :;,,·. • 440-0G-ZQOl
o-,
(t··,.::a•::: • .•
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l.lll ,.o
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S.>hcnt
Trtrartt-.. , l !u:i slud&t
.:'.':-.t:111,;,II tc~l•t "altt'!-
H\,,~\.-t. 11y.!r-·1..:!ilori.: .aciJ, Jicc-, C<OJS~!: sod\,
, .. 'lrn.11:•, 'Ol':f'nl._ 111,~'., Wl.alJ. ~liill,
rir,:.,·,::• ;I.Ht ... ~.,n:J,
Pentachloronhenol Prille
. --····•--···· ·-·-----:...C, ___ ----·•-·-------
--------·•·-·--·· --·--··-
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.). _____________ ...
··-··-----·-'--·-------------
h.i:,r!~u~ i,ruj,~•ni~ ... .:ii '""~!r;
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(II,..•'
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f,nlllli RJL':M'J 1-elo-· and 1ol) •c~·l";,tf'd,
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or r'C!'j.:.:"f th,IC th~ (:ur,:<,i":i It !.::·C'
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hi
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.·•.•;C'IJl,l W;,..;tc ~1.,11:ir_r..,r-nt lllvhlnn
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l'hronr.: (~(1.\J 7511-H,nl .
Nn"'" 1. JI. r"•lr-
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11/\Z/\ltl OllS W/\Sll.i MAfll FEST
A,lclu·;!I J'hnnr-Uumh('t
~~ !!" Z_H _O~l~
Y'""r ~•1r,1fi ~ny
111:i'I ,11rl l'll1" (or f"C""'l'lr-1 lnr.
1hi, l"orn1 011 rt',rtH' ,hie
11:ilr ;>h ii'!''"''
------l numbr r --~-:i-0111:1,:r ) _____ . -···---... l nrcn __ ~oJc_C..._nU111.Jcr L---· y~~g_C'.l.!~t'd
11) l:c-nt'tnl (lt
, ,. Highway 54 West HO I 05 I
____ l\~_p~crs Co . ., lnc, ----·---·-·----· 1'.1.o_i:1j,;y.iU.1:~ .. N_C __ z75.f.,Q __ 3 l.2.L'.l6.1.=_G 151 . yen r ________ 111011 l fi"-: ____ .•. ,1.
I I J lrnn,r(ltler tlo, I 4900 Brom-::o BO I 05 I ., '.
Willms ~frucking Co. N. Charle~lon, SC HO 1/747 -Q2l4 _, t ~ C:-~ fi l Ii"""~= J
-
lrnn~rorter tlo, z I I J.r..nr----111ciiilfi=.-=J
I.\) le!'' nt, 1, B~,f 5~r 803/452-5003
I I
S A Services, Inc. lWP-145 1, 1, P\unn 7q 17 S r c J r . --,.. iiii I ri---.
11) IXIT I' rorc • \!) l>OT
I c, l Gf'ncrntor I t ""' l:oun t Pl 1;,ur: I \ f'PII t:llt'Ck
SlilrplhR l111z.i,rd IS) 11:nn rrlou, lfll!lt, I' I 011•111 I
""'"~ Cl l\!t!I I') C}1innt I I y I 4) 1f1t ~ I" Coile Chnrnclrrl:ttlc(~
hy Ori
Cnntnln('r lype Nuii,\uir CnntnJncr lypf' t-ln111\,, r (rn111,.J
i] Tf.iiTTiili Ir'
·-----·
3 lli:nrn,!llv(' · .:Zh,nY77l''t:;,C DRr!'lctlH ...;,-,~ .z,c·
NOS Poison 20 yd r:11oslc Truck 1
8~l•LfJ ···--··---
r.111 nrile
UCnrrn!I iYf'
au~ni:t he ~,.,.,Jc ISi J ---·
hp11fnlilf' -
0C:nrrr,,1¥t"
0 lhrnc:-t hf! Rr~:1~. '
r..,~r,Rrncy Rl"'~pnn!II"' tnrnr111ntlnn: "· s,,rc 111 I llnnll I' Ill( IIU t rnc l I OIi<:: r.. COllll'llf'll l !1 :
In f"'ft'l1 t or nn ('rilt' 'R ency, rhnnf' tht r:tn~r11tor "':
l 919 ! 467-6151 Pnt Sm ill, /.(,/. CJ ,1'/--v"-y.:-3. 5 0 5 0 CJ,2-(l, 'JI
-
In eV"riitnl n ~l'I 117M5viith I'.• r n I In fl , c fl 11 '"" llr"pn rfri,rnl n l ( 110:'I J 7~11-S~.'1. ~~
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Thi, 1, In «rt I fy •,• r ,hovo-n,mr,I wnt•dnt, ,rr rrnf'rrly clo,slllr,I, ,lc,crlbeJ, pncko,r.1, mnrkrJ onJ lnhel.,I, nn,1 n" In rrnprr cn111ll1lon '"'
trnn,portlllon ... 1:.7.r• ~ nll •rrllc•hl" rrp,ulnllon?' t:tf fh1" U.S. llnT, th1" S,C. r.:; .. r., n111I lhf! S.C. 11,11.1!.C.
, =~ • ,< P. D. SmithJlant Manager 5-28-80
'T--n .,tt hiij;jr,"iiiiit-Tttr-.-1111 ( C
I hrrrhy ccrllfy t hn t I "" nn nol hnr I r.r,I "~l'f":\"nlnl h,• nl
"r u• f Or u 1 t 1,,,:, t C'
1hr lrnn,pntlC"r ,11111 thnt 1hr wn"tf'l!I) ffllll qunnt It y dr"c-rlhr1I In th I !I Hnn Ir""' , .. '" her.11
Jf!l lvC"ry (0)~-ry-!m!Jl,t,.ntJr1rJ1 7hovr.
lrnn~pnrtrr Nn. I : ~. .,, ~ . <·---l'' 1. ..l ....... Willm.~ Trucking Co-5-28-80
r,1 i1"in I rr r ·---. """"'
nn,-.-·
lr,•n!lrort "r No, z:
S l ,;,;;,-;; ----
I hr.rchy c,.rt!JH thflt I 11111 nn othttrlr.1'."•I ""Jltl"'~u•ntnllvro ol lh~ ·1.,;111= ldP"nl Ir lr,1 1hnvr nntl thnl I hr
''"'" -~ •r :~,~~z ,, .. , .... ,n,1/nr '"''""'', ,_;;;Jf_...s;. , -;/,,.µ, /Ee•/ r:1'/i/<,~. ~ .,, .,. . /;/r,"L"i!.J
&1 t,ire· --✓ ·--~ • • Tinint"·oiiil Tltlc -
,
11111:r. I I .. l ,,
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ll:1n lf1'" r
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-:all,..~----.... --
j;~?l"..rh rnrnlin., 1t,·1'·1,lmrnt C'f llrnltl1 11n1I -"!!II -ca 1iiiiil ·-----End rnumrntnl t:nulrnl INTEl{l~I ------~~ os~z8 ~)O"'t
f 51,J lrl W,iclc '1:111;,r.rmrnt Jllvhl"n
. H,1111 flu I I ~trrct, t:olu111ldn, .i;r Z!>Znl
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I I I 1:rnt: r:1t nr
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11 I lrnn~rort~r No. I
Willmn Trucking Co,
lr11n~rorter No .. Z
I)) sl:R" ,. . ... ,erv1ces, l11 C. JW P-1•15
I I) IXIT rrorc, I I) I.IOT
Shlpplh~ ll11tnrJ
Nn111r: Cln~~ PJ !Jurrnllty I 4 I Nn~t" Cn1le
11/IZ/lltlllllS IVMil'I: ~WI I Fi:~,r
.\,Mrr~:,: l'hnnr H11111hcr
lat C'll......CoLlc_L .. numl,cr.L ---·· fTTgl,way-5'1-W eil ______
?l'J I 4 67 -615_!_. Morrisvill£L NC .27 5(,0 ..
4900. n 1·~mc:o 803/747-097.J . N, Char eston, SC
lq. l, llox 55
Pinn•voocl SC 291Z5 . 803/452-5 03
\ (,) Gi:-ner11tor I lrm tounl I 7 I
I ~I ll:11.nrdn•11 ""!'It"
Chnrnctrr 1:oil It{~
~nr· rt1;,ii11,· .i;y-------
l11<1r111:ll•111• fnr Ct1111p)pl\nr.
l Ii I~ 1·111111 001 rrvrr~r title.
lt:\1 r !;hi 1'11r•I
or /\rrrptr1I
80 I 05 I 2
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80 / 0 5 t Zc
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I I ye:;-,--"--;;ii il l ri--tli
vw1: ltt-111 Chcrk
I' I U• .. 111 I·
hy NP" I J
t:n11tnlnrr Typ• Numhf!r Cunt n lnr!r Ty11e Hu,..lir-r \ rn1111rt·
[JTr,iiH,61. . ---·
Ut:nrro, lvr .:zJr/11/ T,t,,c,C.. .33_..:0,,
ycl 3 Unrnrtlv~
NOS Poison 20 t:11 OI I c Truck 1
-s~lstfd ---···-· -·----
Rn1 nTile
UCorro'!'I I Yl'
Oltencthr
~ro, le
-· ~h I fJr,r---RII I ti I t'
u1:orro:,IYt"
URenclivr
H~•~J~., / '
r"'c r1r11cy Re~ tmn ~" Inf O '"'" I I OJI: It. S11rclnl 11:,n, tfnR 111i;tn1c11011~: r,, Com111rnt~:
5oe~1
In event or nn t'mr.r1cncy, rhnnp t ht! r.PnPrrtlnr nl:
! ~If! 467-6151-Pat Smilh ,((/ (} -t/ ~,Y.f
In rYrii ·u~"pl117ii-~Oiilh. f.11rnl ln11, tfll 1 I ftp ~~" llr1•n rfl'IPnt nl I ,n ·' I 11,-ssH.
//
11,t, I• t'o cenlly lh~tli, •l•nve•Hnmr,I ~•r,rlnl• or, prurcrly cln.,lllrd, ,h•<erlhcJ, I'"""'"''• """ rkr,I 1111d I nhf' I r,I, "1111 n" In r¼•r-r ' t Inn '"'
trnn,rnrt11tlon "~:Pv' t-&11 111.rrllt',.hle rrv.nlfftlun, nr tht' 11.s. uor, thr ::;,1:. l',s.c; nrul tht" :;.t:. 11,11.fl,l:. -
(~ / P. D. Smith-Plant Manager 5-28-110 nn {, ill rnniur ~ h:iiiir!riiiuiTTJe -
I lu:rf"l,y cnlily thnt I ""' n11 st11lh{'lrlif'1I ,,.11rp,i:-nlnllv,-nl th,. 1,n11!'q10rlf'r no,I t lln t the-wn~ If' I~ J Ill.IHI qmrntllr ,lf"~crlhr,1 In th I, ,111nH,.~, hnYf' hrr11 ni:t "I', ,.,1
hy IJ~ for II It 1111:, tr. ~le~~~ 1h.£L1~:-~1d~!_!ll/l~1I nhovt', Willm., Trucking Co. 5-28-80
ln,n~portf'r Ho. I : f -~/ £.~ . ..:c.--(_/~C/.U•f•".-1/ --nittiir···--fl;, r r ·-------·----
•• ·1p1n urp
Tr•n~ptHlf!r Un, I : ---lJj IE ·-·-
S 1 i;iiiilii u ·----·---Uiimc -:··
I hrrrhy Ct'rt.lfy thnt I it"' n11 n11thnrlt,.,I ,,.prr,rntnllvr nf th,. -,~111: ldrnl Ir lf',I 1hovr. nn•I t l1n t !..!!L."'"" tr t,) ""'' 1111"' 11 I I I t' dro:crlhr-,1 In I h I~ tl:111 If"" I lt11 y,-
hl'"rn n~~#, mr.11t, ~1orn1p•, ~1111/ur dl•1'0•1tl. ~..J'i;..•0c·<!' .. -/Au-/.,:-;-•.-/ ..:5 ;.:½' £'d
. . G,,-,tr:· 7 4 iy,il:fi.::---·--··----. ---. n --,;;a ·Trn;; · -·--n.H .-;:--. --~-__ e-:,_. .
nmc n 1
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llilf N T--1 --I 1/\Z./\HI OllS W/\Sll' ~Wll Fl:ST
''""'"
(J) ljrnnn1ot hoppers Co,, Inc.
iZ~n,rorlcr Ho. ·'
Willmo Trucking Co.
I • 11. Cr-ii r
lnumbt l..~. !lt't1rcr.J _______ _
------------·----
1r1n~rorter H~. Z
I ..;.:--:~-------+--~-:-:-:-;:----1 Ht, [. llox 5C5
f.., 1•11r
" 1·'5 Pinewood, S
PJ S<'.'.:A Services, Inc. lh P-.,
I IJ
O) Q1111ntlty
l!i} ll:1tnnlm1!' thstt
Chnrncterhtlc(!'
29125
Cnntnlnu lyre
803/4.52.-5003·
\1 J 151!1'
Humlu,r Cnntnlnf!r Type
-
1}•1111111 1, 1
hy ""Ith
(1'011~-~ .. J
.3Jl .. Solb
I k I •nJ JnhC"ltd, nnd 11rr In 11rorrr ro11,lll lr,11 fnr
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1
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0e ~d.~4.'rC,c,J'.. 41_4 7a•,,;/ •
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·~t;; .. ,,1;1 1'1'.i.'-t c P1.i11:1r,r,.,r:nt Ill, Io: l1111
En\·lrnnri,rntnl l'.11111 rnl
.... ,,,.r.n11 flull ~trrct, CoJumhl:1, ~r 292111
,,, l'iu,nr· (AOlJ 7SA-HR1
r'""''" I. II. rrulr ... " .lnumbrL IL~.C111rcc1
111 1:rnrrnlor
_ [<opjlCl'S Co .. Inc.
I l J lrnn~ror-ter Ho. I .
'Wil ms Trucldng_Cn ..
lr11n~rorter Nn. z
I~ I ,~nr
SCA :c;ervices, Inc. IWP-l45
l I I ll\JT rrorer (21 llOT
~hlpplhR ll•tnrd
tl11111c CI•~ !I I l I Qunntlty l 4 I tfrt!lt' Cn1le
NOS Poison 20 yd3
-11/\ZJ\lllll\lS WM;TE ~Wll l'EST -----.._J\..arll 80 _ _/ _OS _ _/ 2_8_/ _____ _
'yr=nr "'"r1tl, .lny
lid! 111r1 h11" fn1· l'timpl,.1 lnr
I hi!-I II r /II "" 11 rrvrr~c , 1 e.
i\,Mrr~~ l'hnnr tl11rnhr r 11:tl r St. I prr1I
01_~·.£S.1•t('J la na.._coJ c_LnuclJc rJ
TTqd,way "S'l-Wcs-r-HO I 05 I •,<
919 / 467-61 ~!_ ___ ,. <
Mnrrisvill_cL.NC_ 27560 . rcRr _____ 1r1011Hi. -· ____ ,1;
... 05 Z!
<!<)00 13 r1mco 803/747-0974
80 I I
N. Char esto11, SC JC ii l---~iiottlri=_-: J;
I I yn-,----111Qi1{li __ -=_~i
Hi. l, Bqx ~5 803/452-5003
I . I
Ptn . C Z'll25 )"C;l r ~ii l rr-""<l.
( 6) Gr11crAlor 11 ""' t:oun t (7) 1!Wf ltl"l'I 1;ht'Ck
I I I ll:11nr1lou, tf 11 !I l t l' I 1)111111 t I
C:hnrnclr.rl:ttlc(~ Hunihtr
hy .. ,
t:nutnlner Trr• Numh"r f.nntnlner Tyre lronnd
UTi:11ifif61ci
--
Ucnrro~lvci · :z:u "I 77' ,-c I(. ,yl, C8(1,1
CJnrnfl ht Truck 1
,,
.6:11 end c
8~istvd R:111 nli,"
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oc., r ro!= I Yt
□fir.net Ive
§lo• Jc · .. _ -1'1 d ------
\,r:n,fnrdr.
Ul:orn,, IYC"
ORrnctlv" Hr 0;l~•
l:111rrar11cy Rc-~pnn~" In lnr1111t lt111: ,,. Sitt'\; Ill 11nnt1f 11111, 111,lt'UCI 1011~: Ii, Comlllt"'ll t ~:
In r. vr.n l nr nn c-mcrl(cncy, rhnne the Gt>nt-r11tnr "1 !
1919M 467-(,151 -Pat Smith wo,,.·1! Cl~ cJ ,<'. r/ ?'-Y~?
In rml. n~p11rTilSITTith C"rnlln11, CII II thP
CJY'~~fo 11,.rn rtrnrnt ., ( 'n .I J Bll-S:,,11,
. _(os
Th I~ I ·• lo Ct>rl lfy I '1n! 1hr 1hovr'•n11111r,I ""' "r In I !I "rr. 11rn1•~rly ~ln~~lrlr1I, c1C'!'Cf 11,('J, 11nc ►.n,.r1I, "'"rk~d 11nd I "ht' I t!d, nn,J . " In 11 rri11r r crrntl It ln11 for
''""'P::••tlon ;p;;_z-;;11 nprl lc111hl r rr.p,uJ nt I on, of t hr U.S. IIIIT, the S. G. r, ~; :c. nn,I lhf' s. l:. 11, 11.1! ,C.
P. D. Smith, Plant 1'.•hu1agcr 5-28-80
~· ""A I .-, r··· tliiiiie nmT'Tltlo fiii l C'
I he rrhy tertlry tl111l I n~nn 1rnthnrlic1I rfr'•";JntntlY" olv:. lrnn"('nrlr.r ,11111 t hn t I hr wn~1e1.•J nml q1111ntlly Jr!'Crlhr-d In l h I !II P\11nlfr,r hnve lir.rn nccf'rtt
by "' for ulllm:ite dtllVt' y t 1'"' r;111:.1ttr11tlr c1I \llhnvi 5-28-80
1 rnn~rorter tlo. I : .,, 'd.t:JJ?_ • Ir . 1 dl£. '._ ':.:J. Willmn Trucking Co.
:,:zzrr / · ,/ niirnl:! · on l l'
1r11n!lporter No, z: . -'/ --n;
~l ii (11
I hrrrhy cert!J.r thnt ,~~'" nn nuthurlte,I ,.,1,rf'~rntntllf' of I hf" 1:m1: hf('tr\ Ir f("',I 1h11vr. nnd thnt th'" ""!'lei!'} nn,1 ,111n111 It y ,lr!lcrlhrll In I hi~ , 1:, n I r'" ~ 1 luuc
h"en "~~~hr·~ t nl:2t, ."tnrn11~, ,unl/nr ,II :o:11n":1 I.
1~~-tYr1--1'c~·-,?.z_.;r. /&;,-/-.:,·~
11-(...... . (.if~ " ~
ltt ,,111re , , 7 -nml' n 1 1 • ' fl~H.~~,;.
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tl111;r: ( I I '\ J ) \)\\ \. \) "·'':, CJ~ • ~.,.1clt,
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., t!:. C:l•• ,: /0 --\'. :,;';-' ,..')
...... C
-r I ii~ l'(,rf'I llll rrvrr:H" _, ' '' i:..,,,,. A,Mr"!'" """''" t1111111'cr 11:, I ,. ~h ipr,••I
llt11"'1" I . II. 01 /w_c_!"_l!.l!_J (num1Jti'1. 'L~tTllrttl larra_c.oJe_~_num~clJ
I I I 1:,-nr rnt nr llif!hw:,y .'i4 W~st 80 I 05 I 21
l<opµcrs Co., ]11c. Morrisville· C 275(,0 'L!.9_/4 &7-6151 ·-.· -·---·;:cnr·.:-=-__ -_::-iiiOi11 ~--~; ·-· ·•-----· --···--···-•" ------1------··· -····-----· (ZJ lrn11!lfnrler NC'I, I 4900 lli:omco __ !)_Q_I _,.P .. !i 1r,:·-' -~l
Willm~ Trucking Co. .N,_Gha.tlr.aton sc: BO '3 /747 -nq--: ,., JClll __ . __ 11011 1 ___ , fl
1 rnn!'r,orlt"r Uo, I I I
J.r.l\r 111~.Hl t h _____ J,
Pl T~ II/: Hi. I, JJ~x ~t I I
SC.t\ Services, Inc. IWP-145 Pm ,npr, 801/,1<;7._r.nn, vr:,-,----;iiiiTr.---J~
I I) !Xll I' r op, 1 l I I IIOT ( r, J Gr11er11tnr l1"111,C~nnt 171 1~111: It""" Cht"ck
ShlpplhR ll11t11rd I~) ll;nn rdnu!l lf1111:t, I 'I IJII 1111 t I I
N11111, Cl R!'!l I l) f}u11ntlly I 4 J ""!II" Cn,1«! C:hnTncttrl:ttlc(!l hy N,.\1
Cnntnlnrr lyre Nu111her t:nnl"lnrr Trr" Nu,.,htr tr(mllll•
Ufr.i1ltri15lc
Ut:nrro!'IVt'! :JJt0y17.l',,c;C 34«0)1, 3 tJnrnct.lve
NOS Poison 20 ye! 01c-xlc Truck l
-~~hlfd · -···-------
,.111 ntilc
Or.orro~ I u• ' Ollr.ncthf'
§Jo,lc Isl d ~~111fnlilr. . ar.ouoslvc
U Ren ct Ive
H~l~d --l:111crRrncy Rr!llrnn~" lnfor11111t Ion: ll. ~il'rc l n 11:'lrH ni l11!'1lr11Cl1Ufl0:! F.. Co'""'rn t !t :
~D ~ In CYCnl or nn CT!lt'fRCncy' phnne the r,,.n,.r1llor II t :
! 919 J 467-6151 --Pat Smith /t/.(} pf 11, 07§0 ~ In c'v'Friru I • ~pltnttSoiith C1rnlln11, C'II II t "" nrrn rt 111en t nl I• n .I 1 7S8-SS~I.
\. £
11<1, 1, lo cr,I lry 't) 1hr ,hovo-n,or,1 •n••dnl, ore rrnrrrly rl•.,Hlrol. ,lo•crlh•d, l'•rt,,r.1, m,rk-.1 ond l•h•lrol, 11n1l ... In 11 rr,pl"I rr1111llt\t111 rnr
trn11.~rorlntlon "~J: P,~11 nprllc"hl,-rrR1tlntlnn!I nl thr-11,S. ltn~, th1• ~.t:. r.s,c. 111111 lh!' li.t:, 11.11,P..C.
n-r5-=-2 8.=.8 Q " ____ ./.. , . , · .1'.:_P'. Sn!.!!_l!,..L!ant Manager ,ilul!\JJ.LU' · h;irnr. nnJ Tille . '
I herrt,y crrt i ry th;, t I •• "" nulhorlu•,I '"l''"~entnt hf' ol I h,-t tnll'.'l''H I r.r ""'' thnt th" wn,tc{!t) ,11111 q1111ntlty 1lt"!'IC r I hrtl lo I h I~ flnnlfl:':tl hnvt ht'!('M nf<'"PI ,.,I
hy ,,. lor ultiffl:ite Jellvtn~o•1th~TSIIF: Jz•}ICl",I rthOVl'. n-r~ZJl.~Jl_n Trnn!'lportt"r No. I:~ '.;;/,· .((!',I Will nm Trucking Co. VJ''" ~. • / I 1Tiiiiie , .
Trnn!!-porter Pio. z: n, • .... SJii11n[u
I h•rehy ~~ lhnt I •• •n ,utho,lt«I r,1or•s,nlntlve ol 1hr ·1~1,r: Mr-ut Ir Ir.ii 1hnvr-nncl l hn t th" Wrt!lll"l:!1) ,111d q1111ntlty d(""crlhr,1 In th I~ Jl:1nlfe~I l111Yt
ht"en 11cct"rl ~~tr , "'"~..;Yt1rn,te, nnd/or dl:!1pt1!11nl, SY_s;--< ,.,i: J.J -/46. /c'cvl • . ._::) =-2 .-,;--,9-J
lJIP'ltJrt.Ure /. ., .. ~, ·-------p:i{e -N:ini;. n;-t~'IUli:
I nm:r. I I
-, ,. 1,, r.-.s&•'Tte••, •••• -----··-·--• •-
r··---~;~i"fT i.>J. , .,_, • ., ,11 • •• , • •• ·i. '·"'
:•-(RC/'J
,681-------, ., '
/:✓
,\ Name: 1.0. Code
a
{I) Generator
I<:oppers Comoanv; Inc. NCD 003200383
(2) Trans(lortcr No. I
Willms Trucking Co, SCD 073709297
Tran.sporter No. 2
(l) TSDF
SCA Services, Inc. SCD 070375985
(I) Gc:ncra1oi Item Count
Number
1
Container Type
Truckload
(Work No,
6524)
(2) DOT Proper Shipping
Name/Hau.rd Class/
DOT Identification Number
Waste Pentachloro-
phenol Sludge-ORM-E.
NA 2020 ·
--

-
-------
Phone Number
Address (area code & number)
()) Total
Quantity
Highway 54 West
Morrisville.· NC 27560
4900 Bromco
/QlQ\467-6151
N, Charleston, SC 29406 [phone]
.Koute l, Box 55
Pinewood. SC 29125
(4) Weigh!
(pound,)
1803)452-5003
(5) Wa,ic Code
40, 020# 003200383-P090-001
Datc:Shippcd -
or Accepted
80 I 11
yur month
80 1 11
yur monlh
I
monlh
I
JUf mon1h
(6) TSDF Item Check
Number Container. Type
1
C Emcr(trnq Rcsnonse Information:
In c:\·rnt or an cmc:r~ncy, phone the Generator al:
D. Special Handling lnSlruclions: E. Comments:
p, ""P 4r.,c.,J.(
£ 919 > 16J-6l5l -Pat Smith
In event of a spill in South Carolina,
call !he Dcparlmcnt .it (80)) 758-SS) I
-
I 24
"
I 24 ,,
I ,,
I . ,,
(7) Qu;i.n1i1y
by Wci~ht
(pounds)
14-· 3
F. Thi.\ is lo certify that the above-named materials arc properly classified, described, packaged, marked and labeled, and are in proper condition for transportation according to all applicable regulalions or the l
D. OT, U.S. EPA, thd.~,:J,''~nd f)e S:k,PHEC. ·
~',ef'_.,,,o<I P, D. Smith, Plant Manager ,,.,,__.l~l ~--2~4~-~6~0 ______ _
~•111uv•f Namr 1nd Titlr 011r
G I hereby certify that I am an authorized representalive of lhc transporlcr and 1hat lhc ·waste(s) and quantity described in this Manifest have been accepted by us for ultimate delivery to lhc TSDF identiried at
Transporter No. I:~~~~
S11n11vrt
Willms Trucking Co, 11-24-80
.Transponer No. 2: ..,.....,.,.---------------~•,1111v1r N,mr 01lr
H I hereby certiry that I am an authoritcd representative or the TSDF identified above and that the wastc(s) and quantity in this Manifest have been accepted by me for treatmenl, storage, and/or dispo~al.
u
DHcC J9RR (l/RO) lnsiructions ror completing this Form on reverse side.
. . -~"'lliill"'"•'f"'lllllllivisic----~---···-· -· .. ···--··-
I· .,tree mb1, 9201 -.. AZ.wlJO-..V A-M-FE-- -- -
~ _--~84-i · 160)) 7l8-l681
Phone Number Date Shipped .
· N,,mc l.D. Code Address (area code & number) or Accepled
ii) Generator Inc. NCD 003200383 Highway 54 West 80 l 11 l 24
Koppers Company, ""o rti sll:ill e NC z:z5t.n /QlQ\467-6151 yor morul'I d,y
\2) Transporter No. I 4900 Bromco 80 l 11 l 24
. vn11-c -r~,r'-'nrr ,..._ c;rn n7,70Q7'17 l\1 ri. ..... , ................ _c;r -,n,1n h 1on,\7,17_nq7,1 ynr monll'I ,.,
Transporter No. 2 I (
yur month doy
(l) TSDF Route l,. Box 55 I I
SCA Services Inc, SCD 070375085 Pinewood. SC 2q125 IR03\ 457.-5003 yur mo,uh doy
(l)·Gcnc:ralor Item Count (2) DOT Proper Shipping (3) Total (4) Weight (l) WaSle Code (6) TSDF Item Check (7) Quan1ity
Name/Haz..ard Class/ by Weight
Number Conlainer Type DOT ldentification·Number Quantity (pounds) Container Type (pounds) Number
Waste Pentachloro-yd3 '{)->.,.,. f T ).'_u cl-( 3c,11,3o lb
1
phenol Sludge-ORM-E. 16 39,820# 003200383-P090-001 I Truckload NA 2020
(Work No, .D
6526)
/k~ _05
iY
'
~· ~ " '
Emericncy Response lnrormation: D. Special Handling Instructions: E. Commenu: uJ .0-~ l,:52,(.,, In §Y§t or an emer~G!JfY•&tonc 1he Gencra10~ at: ! l 4 -51-Pat Snuth
In event or a spill in Soulh Carolina,
call the Department ot (803) 7l8-llll
This is 10 ceniry 1ha1 the :ibove-n.imed materinh arc prOperly classiried, described, packaged, marked and labeled, and arc in proper condition for transportation aecordina to all applicable regulations or the U.S
DOT, U.S. EPA, thY,j=·ff f)d ~')-C. DH. EC.
,,,,.,,, ~ .of__/RJ P. D. Smith, Plant Manager =-c--=-l._l-::..:2e..4._-::..:8e..:O'-------
N,m, 1nd Tllk 0•1f ·"'•"•lurr
I hereby certify lhal I am an authorucd representative of lhe transporter and that the wastc{s) and quantity described in this Manifest hp.ve been accepted by us for ultimale delivery to the TSDF 1den11f1ed abov
Transporter No. I: 01~ ~ Willms Trucking Co. . =_l..,l,c-:..,2><.4;,..:c-.,e8:.,0'--------
s,.,.,~ ~ N,m, ""'
Transrortcr No. 2: ________________ _
!,i n1!11rt
I hereby certify 1hat I am an authorized representative of the TSDF identified above and that the waste(s) and quantity in this Manifest have been accepted by me for treatment, storage, and/or dispo~al.
l>■lr
-

-
-; .':> ·.y-'' JJ8-J68)
, -8 -
: ~-,·' '
-
:>::c Phone Number -Date Shipped
1.D. Code Address •. (area code&. number) or Accepted
(I) Crncralor NCD 003200383 ·
Highway ·54 West 80 l 11 l 24
Koooers Company, Inc. ~•~rrieuill"' NC 27560 1g1g) 467-6151 ;rur month ,.,
{2) Tr:1nspor1cr No. I 4900 Bromco 80 I 11 l 24
\V;ll-i::. 'T'-•r,.,inrr r,.. sr.D 07370Q2Q7 N. Charleston, SC 2g406 [phone] yfl/ month ,.,
TnnsPorlcr No. 2 I I
YfU month ,.,
(l) TSDF Route l, Box 55 I I
SCA Services, Inc. SCD 070375985 Pinewood. SC 29125 (80 3) 452-500 3 yrtr month ,.,
(I) Generator llem Count (2) DOT Proper Shipping (l) Total (4) Wcisht (J) Waste Code (6) TSDF Item Check (7) Quantity
Name/Hazard Cla.ss/ by Weight
Number Container Type DOT ldentiricatioll Number Quantity (pounds) Number Container Type (pounds)
1 Truckload Waste Pentachloro-3 t Cb-.r ,~; phenol Sludge-ORM-l H, yd 36, 100# 003200383-P090-001 t 3;&1!2UI
NA 2020
(Work No, ,J.7
6528)
'
.,050 (10 0 &-
rJu~
~u
Emergency Response Information: D. Special Handling Instructions: E. Comments:
t l)l~ 01 an i'~'1,13/'..''1;f~f~'}Y'.[f~~'flfit: p,., "f> 1¥"' 0,/(
In event or a spill in Soulh Carolina, /)J ,o. ii l,52 B
call 1hc Department at (80)) 7,58-S.HI
This is lo cdtify thal 1hc above.named materials are properly classtned, dCJcribed, packaged, marked and labeled, an4 arc in proper condition ror transporta1ion ac~ording to all applicable regula1ions or the U
DOT, U.S. EPA,~~-DHEC.
P, D. Smith, Plant Manager· 11-24-80
!-,,n1t11•r Name ,nd Tillr Otlf
.:; I nc:rcby certify Iha! 1 am an authorized representative or the transporter and that the wasle(s) and quantity described in this Manifest have been accepled by us for ultimate delivery to the TSOF identified ah,
Tnnsponer No. I: Ld_.~ ~e-~ ~llms Trucking Co. 11-24-80
S111U1u,c N1mc 0,1f
Tr:insroncr No. 2:
~•tnllU'f Name 01lf
rl I hereby cenify lhat I am an authoriied rcprc.sentalive of the TSDF Identified above and that the waJte(s) and quantity In this Manifest have bee"n accepted by me for.treatment, slorage, Ind/or disp0.\:11.
-J,,~/ ~e-8: 5fiftv1c-e.3 l I--Z..C{-B"l>
s,,n11u1r j
Dtlt
NI c tl'd Tille
V
.... , U!r oto•• 11 lel\1 tns1rue1lon1 ror comi,1c-lln■ 1hls Fetrm on reverse side,
•• w 111111 n .. ,n
~-1'''.'1----. : . ~
/ ,.
,,, Phone Number Date Shipped
,"' N.1me 1.0. Code Address (area code & number) or Accepted
/
{I) Grncra1or •, Highway 54 .West so l 11 l 2·
-1.\Qt>pe rs Ga.mp.an" Tnr Mrn nn,?nn,ll,. ', cir.ri..aldll.~ 1'1r ?7~Ln /010\'1/'..7 _ Li c1 7111 mnn1II '
(2) Tran~porlcr No, I 4900 Bromco 80 I 11 /24 Willms Trucking Co. SCD 073709297 I N. Charleston, SC 29406 '18031 747-0974 yuf molllh '
Traosportcr No. 2 ' ' yur monih '
(l) TSDF Route 1, Box 55 [phone] ' J
SCA Services. Inc, SCD 070375q35 TI.'n ' c:r ?0l?~ yur mon1h '
D (1) Generator Item Count (2) DOT Proper Shipping (l) Total (4) Weight (l) Waste Code (6) TSDF li<m Check (7) Ouantit)
Name/Hazard Class/ Quantity (pounds)
by Weit1hl
Number Container Type DOT ldentificacion Number Number Container Type (pounds)
Waste Pentachloro-
yd3 1 Truckload ph'N1ol Sludge-ORM-: 16 38, 950# 00 3 200 383-P090-001 I D:,,..,, "fro-~ 3°/1o?c A 2020
(Work No, I
-~ 6529)
~ ~ w' . _('},. ,<"\ ,..._
~~-'
C Emcriency Response lnrormalion: 0. Special Handling Instructions: E. Comments: l)J .o:-,t (,,52, In ev~ri or an cmg;cnc6l 5honc the G§ncralor at; ! 2 2 J 4 -1-Pat mith
In event of a spill in South Carolina,
call the Department al (803) 758-553 I 00 ,..,.,_ ri-h-v-L--
F. This is to certiry lh~l the above-named mater\als are properly classlned, described, packaged, marked and labeled, and are in proper condilion (or transportation according to all applicable regulations of !he t
DOT, U.S. EPA, '7~.$' DHEC.
P. D. Smith, Plant Manager ll-24-80
~i,n11urr ,..,mt and Tillt D11r
G ' "'"" "'" ', '"" ' ,. '" '"'""""~:• •• '"' "~w•• '"' ••• ~ .... ,., •• '"""" •=•~ '" '"" •••• '" "'" "'" '"'"" •• "' '"' ""'-" '''''"' '" '"' "°' "'"" '"' ••
Transporler No. J: s;,llt_ ¼tr£ Willms Trucking Co. 11-24-80
S11n h,1 ( ,..,mt D11,
Transporter No, 2:
s,,n11urt ,..,mr o,,,
H I hereby cerlify Iha! I am an authorized representative of the TSDF identiried above and that the wastc(s) and quantity in this Manircst have been accepted by me r.or treatment. storage, and/or dispo.~al.
~~~ ,~l".:-~ S0a IJ.c:..G;:::. ~t°f.Sri?-Ll-e .'l..-2:2.
Si,111luff , D,1,
"''"" 1nd 111, -(1/
DHEC 1988 (J/80) Instructions for comple1ln1 this Form on reverse side.
-- -
Phone Number Dale Shipped
,\ Nnrne I.D. Code Address (area code & number) · or Accepted
(I) Genc:rator NCD 003200383
Highway 54.West 80 l 11 l 24
1 I<onnPrs Co .. Inc 1',,1',..,....,~,,..~;11 ... l\lr, 77~(,0 /QlQ\_,1t.7_/'.,] <;1 70• monlh ,,
(2} Tr:insportcr No. I 4900 I! romeo 80 l 11 l 24
Willms T ru ckin" Co. SCD 073709297 N. Charleston, SC 2940 P {803) 747-0974 rur mon1h ,,
Transporter No. 2 I I
rnr monlh ,,
(l) TSDF Route 1, Box 55
{803)452-5003 I I SCA Services Inc. SCD 070375< 85 Pinewood SC 2q125 yur month ,,
(I) Generator Item Count (2) DOT Proper Shipping (3) Total (4) Weight (l) Waste Code (6) TSDF Item Check (7) Quantity
Namt/Haz.ard Class/ by Weigh!
Number Container Type DOT ldcntirication Number Quantity (pounds) Container Type (pounds) Number
Waste Pentachoro-3
1 Truckload phenol NA 2bu2ige-ORM-E 16 yd 38, 110# 00 3 200383-P090-001 J 0,.,. ,..,-L. _v 38/ol0
• (Work No. I:, ,le
6530)
6050 (1 nn ~6r ' () 0 () f) J'(\J..,(y'
' ~
Emergency Response lnformalion: D. Special Handling Instructions: E. Comments: t r/f~t or an i'm4r,l}'::'rJ'tr:.iea~e'g~'l.'t~' !'.) v-f' 1rvc. k
In event or a spill in South Carolina, w.o.ir 1.t,530 call the Department at (B0J) 7'8·SSJ I
This is lo ccrliry lh:it !he above-named ma1erl11ls are properly classlned, described, packaged, marked and labeled, and arc In proper condition for transportation according to all applicable regulations or the U
DOT, U.S. EPA.i;p-;_z;;y-c, DHEC, . .
P. D. Smith, Plant Manager 11-24-80
s,,n1hirf ,
f\11mr 1nd Tillr D11f
I hmby cellify •~at I am an authorize~[ 1he transporter and thal the wastc(s) and quantily described in this Manifest have been accepted by us lor ultimate delivery to the TSDF identified abc ,(tJ/4 A _/·
Transporter No. I: ,,/// J_ Willms Trucking Co. · · 11-24-80
i1n11111rv V f\llffl( 011(
Transporlcr No. 2:
~•rn1turr fll1mt D•lt
L I hereby certify that I am an authoriud representative or the TSDF idenllned above and that the wastc(s) and quantity in this ManHcst have been accepted by me (or treatment, s1oragc, and/or disponl.
~~~~ -S.c...4 ~eR.Vlc:.C"~ ~&n:WLEP IL-z.<J..-oO..
N1mr and T11lr 1>11r
u , . Dl!EC 198A (J/80) Instructions ror complrtin,i: this Form on rrvc"c side. , ,. \ l)
/·""·· · ·~p,1111······· •11 111;·•·•" ~uu L-•·•·•••·• .. • .. .,,-•...• .,,.,,
~./4;i --~~;uW,'~~, ... ,t D----H!!!R•S -'.rE-NIMf ------·• II VU II l~U
i', ')1.;, (80)) 7J8-J681
.., 0 85
,{ . Phone Number · OB le ~hipped
Name I.D. Code Address (area code & number) or Accepled
' (I) Grnerntor .H1gnway :>4 YY est 80 l 11 l 25
Konners Comoanv, Inc, NCD 003200383 Morrisville, N C 27560 (91g/467-6151 7ur rnonlh ,,
(2) Trnnsroner No. I -.'/UV D romeo 80 l 11 l 25
Wi lms Truckine Co, SCD 073709297 N. Charleston, SC 29406 /803) 747-0974 7rar rnon1h d
Transporter No. 2 I I
JUI mon1h • d
(J) TSDF Route 1, Box 55 I I
SCA Services. Inc, SCD 070375985 Pinewood. SC 2g125 "/803) 452-5003 7t1r month '
a "(I) Gcncra1or Item Count (2) DOT Proper Shipping (J) Total (4) Weight (5) Waste Code (6) TSDF llem Check (7) Quanlil)
Namc/Ha:..ard Class/ by Wei~ht
DOT ldentificatiOn Number Quantity (pounds) Number Container Type (pounds)
Number Conlainer Type :
l Truckload Waste Pentachloro-3 00 3 200383-P090-001
0henol Slud~e-13' yd 39,000# 1 ft I½ LJ fr, -L l?:,g 9 .:2 RM-ENA 020. '
(Work No.
. ' I
\~ .1
6531)
50:50 ~ ('! ~o" a a..-.
. ~
I
C Emeqtc·ncy Response lnrormalion: D. Special Handling Instructions: E. Comments: uJ o.:rJ:&53.t t elf~' or ,n J°2f'i?f~'61~n.: tr,£t"l3"z'~Hh A-, '1/° fr/.,t.. it,
In event of n spill in Soulh Carolina,
call the Dcn11r1menl al (80)) 758-5531
F Thi.\ is 10 certify th.i.l the above-n~mcd materials arc properly classified. described, packaged. marked and labeled, and arc in proper condition (or transport.a lion according to all applicable regulations of the 1
DOT, U.S. EPA~p-C, DHEC .
. ~ P. D. Smith, Plant Manager . 11-25-80
:-;,,n11111r Namt ■nd Title D■lt
G I hereby cenify thal I am an authorized representative o( the transporter and that the waste(s) and quantity described in this Mani(cst have been accepted by us for ultimate delivery lo the TSDF idenlined al
-,~ -~ .
Transporler No. I: /_mz~-o a~..-Willms Trucking Co, ll-ZS-80
..,s,,1'il1ult Nam~ D■lt
Transporter No. 2:
S,,n1luH N■mt Datt
H I hereby ceriify that I am an authorized representative or lhc TSOF Identified above and that the wastc(s) and quantity in this Manircsl have been accepled.by me (or trealment, slorage, and/or di.spo.\al.
. o,,,/c:z,_ j) Va,, -. s C t2:. ~ (:_ -;e'Ulc r;;:Y S//;,t1P&.~ L 1-z,5-~ .
. 'i,l111lu•t ./ / Ntmt Ind Tillt 011t
r ~
... 1<s~olu ... C l ..
: ·:/· ,OJ -J6SI ---HJ-.ltD-\~·E ~Jflllll" -----""~ ~5,,-
\i ' ' me
Phone Number . Dale Shipped
1.0. Code Address (area code & number) or Accepled
'!co Ciener:itor Highway :,4 west BO l 11 l 25
/ l\oppers Co., Inc. NCD 003200383 Morrisville. NC 27560 ( 212) 46:Z-f11~1 yur monlh ,,,
(2) Tramfortcr No. I 4900 Bromoco 80 l 11 l 25
Wil ms Trucking Co. SCD 073709297 "' r\... ... ,..1.-.-L--~~ ~94()..(, rno31 747-og74 yur monlh ,,,
-,
Transporter No. 2 I I
yur month d•J
(l) TSDF Route 1, Box 55 I I
SCA Services, Inc, SCD 070375985 Pinewood. SC 2Ql25 [phone] yor 111on1h ,,
J (I) Generator It.em Counl (2) DOT Proper Shipping ()) Total (4) Weight (S) Waste Code (6) TSDF Item Check (7) Quantity
Name/Haz.ard Class/ by Weight
Number Container Type DOT ldentHicalion Number Quantity {pounds) Container Type (pounds) Number
Waste Pentachloro-3
1 Truckload phenol Sludge-ORM-E 13 yd 38,700# 00 3 200 383-P090-001 Y-u11;P .J<J.!,, <J(; NA ?n?n
(Work No. I 4
6532)
. ·~· ~ POon f(\1,_Vl
~ r-. \
::: Emergency Response Information: D, Special Handling lnslructions:
E. c;J.o.-// 05.:iL In ever or an emirt?'Ybtonc the Gencralor at: ! 2 2 l -51-Pat Smith
In evcnl. or a srill in South Carolina.
coll the Department at (80)) 7J8-Jlll .
F This iJ 10 cerlHy 1h01 the above-named materials are properly classlned, described, packaged, marked and labeled, and arc in proper condition for transpor1a1ion according to Rll applicable regulations or the U
DOT, U.S. EPA~;,C. DHEC.
P. D. Smith, Plant Manager· 11-25-80
!-,1n1hlfr N1mt 1nd Tlllt 011r
G
,-.
1 hereby cenlfy Iha! I am an aulhorized rer,resentatlvc or lhe tr~nsporler and that the wastc(s) and quantity described in this Manifest have been accepled by us for ultimate delivery to lhe TSOF identified ab,
Traniporter No. I:~~ < ,V/4,#,~~ Willms Trucking Co. .. 11-25-80
IJ lhHf N1mr 0,1,
, Transpcrier No, 2:
~,•n111.11r N•mr o,,r
H I hmb2.' am d2"vc of the TSDF Identified above and that the waste(•) and quantity in this Manifc,l have been accepted by m; for treatment, siorage, and/or dupo,al.
_ ',t,0-:, · I ~~-..Jlf#.JtfY//',,i:"e,J-_/46". ,/,£c,,,('. j/-;J.5-c9o
--:',••··~··"" ,I / .,,, ·1 Ntmr tftd Tlllt D11t
/ V ,.
. '. -7 •. ~trr·allf 29,_ ---... ' ---------~ 1111!59~ .
. <., ,;-~ I· · 8J '• .. j ,I ~~t ; ;,. . . <\fl-/;/ Phone Number Datt Shipped \fr}:.\ 1.D. Code Address (area code & number) or Accepted
Highway 54··.West 80 l 11 l 25 . · 3/enc-r.:11or .
/, · I<oppers Company, Inc. NCD 003200383 Morrisville. NC 27560 1q1q1 467-6151 )tlr m011lh d•l
(l) Tran$pOrter No. I 4900 Bromco 80 l 11 l 25
Willms Truckin" Co. SCD 0737oq2q7 l\1 f""h.,. ... 1 ....... J.,...n .c;r. ?oAn(., /Qn~\ 747_nq74 yut month ,,,
. \\ llliE ..al II
l
Trarlsportcr No. 2 I I
yur mo"lh ,,,
(l) TSDF Route 1, Box 55 I I SCA Services, Inc. SCD 070375985 Pinewood. SC 2g125 18031 452-5003 yur mo111h d•J
(I} Generator Item Count (2) DOT Proper Shipping (l) Total (4) Weight (5) Waste Code (6) TSDF Item Check (7) Quan1i1y
Name/Hazard Class/ Quantity (pounds) by Wtiy.hl
Number Container Type DOT ldcnlification Number Number Container Type (pounds)
l Truckbad Waste Pentachloro-
13· yd3
phenol-Sludge-ORM-) 39,000# 003200383-P090-001 l ~nL I-" =:.C/1 :3.50, NA 2020 ·
(Work No. I
I 3 · '1 6533)
~~: r--
' fJ.'P
Emcr~cncy Response lnrormation: 0. Special Handling Instructions: E. Comments: vJ·O· d--~s=B In cvcnl or an c:mlr6?CYbfhonc: the Gc:nc:rator at: I 212 l -51-Pat Smith
In event of a ~pill in South Carolina,
c::ill the: Ocpartmc:nl at (80)) UB-~531 P~ -h--u0 I( .
This is to certify that lhc abovc-nnmcd materlnls arc properly classilied, described, packaged, marked and labeled, nnd nre in proper condition for 1rrmspor1,1ion Recording to all ,q,plicAble rcgul~liom or the U.
DOT, U.S. EPA, the~~;c, DHEC,
' P. D. Smith, Plant Manager 11-25-80
~,,1,alur, Name 111d Tille Ollf
I hereby certify that I am an author~cpresen:ativJthe transporter and that the waste(s) and quantity described in this Manifest have been accepted ~y us for ultimate delivery to the TSDF identified ab,
Transporter No. I: ~ .01· , ALL Willms Trucking Co. 11-25-80
S11n~ur -;-Name Q1lf
Transporter No. 2:
S11n11urr Nlfflf lhlf
l. I hereby certify that I am an authorized rcprc:sc:ntatlvc: or the TSDF identified above and that the waste(s) and 11uan1i1y in 1his Manifest have been accepled by me for lrea1mc:n1, storage, and/or dispou1I.
Ci,,J An_,A,Qo, S(;.4-s662V1c & o/9171 OL(-fR.. ll-?J--<TQ
S•1n1tu,c / I Due 1
H1nie and TII e ·
nucr 1aoo nun, I ln11ruc i ., LJ t V U 1lon1 fnr camnldin■ this form on re e e 1 de. . I
I.D. Code
(I) GpJerator 1\.opp er s Company, Inc. NCD 003200383
(2) Transporter No. I
Willms Truckine-Co. SCD 073709297
Tnnsporler No. 2
(l) TSDF
SCA Services, Inc, SCD 070375985
(l),Generalor It.em Count
Number Container Type
1 Truckload
(Work No,
6534)
(2) DOT Proper Shipping
Namc/Haz.ard.Class/
DOT ldcnlificalion Number
Waste Pentachloro-
phenol Sludge-ORM-E
NA 2020 .
Addrcu
Highway 54 West
Ho rris,ville. NC 27 560
4900 Bromco
N. Charleston, SC 2940
Route 1, Box 95
Pinewood. SC 7.917.5
-Phone Number
(area code &. number)
[phone]
[phone]
1803\ 452-5003
(l) WaSle Code
-· Date Shipped
or Acccpled
80 I
80 t
yur
I
yur
I
)'Ur
(6) TSDF hem Check
(3) Total
Quantity
(4) Weight
(pounds) Number Container Type
3
13 yd 37,760# 00 3200 383-P090-001
Emcrp:cncy Response lnrormation:
~n fJYW or an i'46~~'6l~on; ''15~{"g~fil
0. Special Handling Instructions: E. Comments:
In event. or n ~pill in Soulh Carolina,
c;ill \he Dcparlmenl 11 (80)) 758-55)1
11 I 25
month .. ,
11 t 25
monlh .. ,
I
mon1h .. ,
I
monlh .. ,
(7) Quanlily
by Weight
(pounds)
F. This is 10 certify thnl the :ibo~e-named materinls are proi><:rly classiried, described, packaged, marked and labeled, and arc in proper condition for transpOrtalion accordirig to all applicable regulations of lhe U.
DOT, U.S. EPA, '.h!/':Yl~ ff• s.c. DHEC.
~/ft P. D. Smith, Plant Manager :--=11:..:-:..,2c;5:..:-:..,B°"0'--------
'~-.;;'::;""::!':!!'":!."--------------------..!.N::!•!!!m•!..:'::"'::..T!!"~'•---------------------------"""'"'-' ---------:---:-:-:-:-
G. I hereby ccrtiry that J am an authorized representative or the transporter and that the wasle(s) and quantity described in this Manircst have been accepted by us for ultimate delivery to the TSDF 1den1if1ed abo
Transpor1er No. 1: /eut---::> Willms Trucking Company s-::-:-l::.l_-::.2c::.5_-::.8c::.0 ______ _
/,>,.,U,1v1P"4 N1mt D11,
Tramroner No. 2: -.,,---------------!,,.,111v" Namt D••r
H. I hereby certify lhal I •man 1u1h( rized reprmnlative or the TSDF Identified above and that the waste(s) and quantity in this Manifest have b;,n accepled by me for 1r,a1men1, SI or age, and/or diipos>I.
_,G.1~~,..,-· _rJJ,rv-,:re.& swu,e..cs ,5fJ-n11 Pcc'J? 11 -?.S..R/J
~••"''"" I I N1rnt and T<1lt D1U
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,,t D S 14 , .
,,j... ( ,I
;-~ .:, ~ wa § UNITED STATES ENVIRONMENTAL PROTECTION AGENCY '" ,,-... , ';.i, -a,\.(.... REGION IV
February 26, 1981
&:F: 4W-WS
34, COURTLAND STRELT
ATLANTA. CCORCIA 3030:S
Mr. Ray Perr, Project Engineer
Kof,?erS. O;rnpany Incorporated
Forest Products Group
Pittsburgh, PA 15219
Dear Mr. Perr:
As part of a recent investigation of a hazardous waste' site· at the Kor,,?ers Co:1;:,any, _Inc. plant in Morrisville, North Carolina, two of the plants potable water wells were sampled en September 23, 1980. Subsequent results of a..alyses co these samples by the Region 'IV EPA :Surveillance & Analysis or. illl authorized contractor · there of Division or an authorized contractor thereof are the subject matter of this letter. The specific results of analyses performed ·deal with volatile and/or extractable organic para.,eters.
Th: results of these analyses sho.rs the well supplyin,J the main office to be free frcxn any detectable contamination. The well supplying the m:iin laminating plant, h&,,.,ever, showed a trace level (less then 10 Pi)b) of diethyl pht.alate, This agent bas industrial usage as ari organic solvent ard fixative. Tho~·',3h the presence of this organic would oot be considered typical, a trar.e level would r.ot merit health concern with respect to potable . . use.
Should you. have any specific questions or a:i,-iroc,nts concerning these anal::,,ses a:: their irrq;>lications, please feel free to contact this office.
si.!.cerely yours,
C. Hal Ernnett, Acting Chief Drinking Water Section
Water Supply Branch
cc: Charles E. Rundgren, Head Water Supply Branch, (NC)
Mike Carter
RECEIVED
l,
-S~rveillance and Analysis Division (Athens)
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HAZARDOUS WASTE SITE INVESTIGATION
KOPPERS CO., INC.
MORRISVILLE, NC
JANUARY 27, 1981
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INTRODUCTION
HAZARDOUS HASTE SITE INVESTIGATION
KOPPERS CO., INC.
MORRISVILLE, NC
JANUARY 27, 1981
The US-EPA, Region IV,. Surveillance and Analysis Division (SAD), at the request
of the Air and Hazardous·Materials Division, conducted a hazardous waste site
investigation (HWSI) at the Koppers Co., Inc. plant in Morrisville, NC on September
24, 1980. The study was conducted by Messrs. Rod Davis and Charles Till, US-EPA
SAD personnel with the assistance of .Tom Smith, Ecology and Environment, Inc.
(E&E). Mr. Ray Perr, Koppers Co., Inc. Project Engines>r, and Mr. Larry Perry,
representing the North Carolina Department of Natural and Economic Resources, were
present during the investigation.
The Koppers plant in Morrisville, NC produces various types of laminated wood
products. The plant also produced preserved wood products from 1968 to 1975
using a pressure treatment process. Pentachlorophenol (PCP) was the preservative
used in the process. Waste materials such as bark, saw dust and excess PCP were·
·dumped into pits for disposal. Koppers no longer treats wood at this plant;
however, waste piles and the disposal pits are still present. In 1978 some of the
waste was land-farmed on two small areas of Koppers property (see Figure l for
locations).· Koppers is presently in the process of removing the remaining waste
to acceptable landfills in South Carolina.· Since the waste and disposal pits are
still present, there has been concern that the PCP might be entering the ground
water which supplies private wells •in the area. The purpose of this investigation
was to determine if the surface waters and grou..'1d water had been contaminated as
a result of runoff and infiltration from the waste area.
Water, sediment, and fish samples were collected and.analyzed for purgeable and
extractable organic compounds. The fish samples were collected for the US~EPA by
the North Carolina Wildlife Resources Comrr.ission. TJ-.e fish sample:s were divid8d
into fish tissue (fillets) and fish liver for analysis. Surface water samples were
collected from the Koppers lake, Medlin pond, and the east· ditch runoff under the
railroad.tracks •. Ground·water samples were collected from three private wells and
three wells on Koppers property:· Sediment samples were collected· from the Koppers
lake, Medlin pond, and a ditch draining the land farming area #1. Fish samples
were collected from the Koppers lake and Medlin pond (see Table· 1 and Figure l for
sampling locations).
SITE LOCATION AND DESCRIPTION
The site is located approximately two miles northwest of Morrisville, NC on Highway
54. The area is being influenced by urban sprawl from Durham to the north and
Raleigh to the east. There are residential areas, light industry and small business
within a one-half-mile radius of the Koppers facility. There is no community water
supply; water comes from individual wells. Surface drainage appears to be s<>uth to
southeasterly toward Crabtree Creek, which in turn flows into the Neuse River. The
topography of the area is characterized by nearly flat bottomlands to gently sloping
uplands .. soils consist of silty sa,·,ods, silty clays, and clayey silts derived from
claystone, siltstone and sandstone. Colors of the soils range from tan-hrm-ms to
tan-reds to purple. GeoloE,ically the site is located in the Piedmont pl2:•:cau of
North Caroline•, with the rock types being classified as Triassic sedimentary rocks ( 1).
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2
SUHHARY
Pentachlorophenol (PCP) was detected in the sediment sample collected from Koppers
lake at a concentration of 6400 µg/kg. Trace concentrations of nine other organic
compounds were detected in the sediment sample from Koppers lake but were too low
to be quantified. No PCP was detected in the water and fish samples from Koppers
lake. Methylene chloride (8.5 µg/L) was detected in the water sample from the Hedlin
pond (PL-002). PCP was detected(< 2000 µg/kg) in the sediment sample from the
Medlin pond, but It was too low to be quantified. Three other organic compounds
were detected in the sediment from the Medlin pond, two with concentrations too low
to be quantified.and one with an estimated value of 3400 µg/kg. Bis (2-ethylhexyl)
phthalate was detected in the fish sample from the Medlin pond at a concentration of
31 mg/kg. No PCP was detected in the fish sample from the Medlin pond but it did
contain trace concentrations (< 5 mg/kg) of di-n-octyl-phthalate and an unknown
phthalate~ and so~e naturally occurring organic acids. No PCP or other toxic
organic compounds were detected in the fish sample from Koppers lake, but two
naturally occurring fatty acids were detected. The water sample from (KR-001;)
contained bis (2-ethylhexyl) phthalate at a concentration of 26 µg/L and three
organic compounds with concentrations too low to be quantified. No PCP was
detected in (KR-004). The sediment sample from (KR-003) contained a trace concen-
tration of(< 800 µg/kg) and eight other organic compounds with concentrations
too low to be· quantified.
No pentachlorophenol .was detected in the w_ater samples from the private wells or
from the wells on Koppers property. A phthalate was detected(< 10 µg/1) in one
of Koppers wells (KW-020) but at a concentration.too low to be quantified. (See
Appendix A). No pesticides that were analyzed for· were detected in any of the
water, sediment or fish samples_. ·
RESULTS AND-DISCUSSION
Station locations are indicated on Figure 1 and descriptions of sampling locations
and type of samples are listed in Table 1 .. figure 2 gives photographic coverage of
sampling locations and PCP sour~e areas. Tables 2, 3, and 4 give data summaries,
and Appendix A and B contain the analytical data and field data sheets, respectively.
Koppers lake (KL-100) is•approximately three acres in size and located in the
southern portion of the Koppers property immediately downstream from the old waste
disposal pits and land farming area #2 (see Figure 1). The water sample from Koppers
lake did not contain any detectable PCP, but the sediment sample contained 6,400
µg/kg of PCP. The sediment in 1:he lake consisted of silt, clay and organic matter.
Sorption by organic matter play,, a role in the storage and transport of PCP. PCP is
only slightly soluble in water 2:nd tends to be absorbed by the sediment (2). Trace
concentrations of nine other organic compounds were detected in the sediment samples
from Koppers lake but were too low to be quantified (see Appendix A). These were
napthalenc (< 10,000 µg/kg), acenaphthylene (<10,000 µg/kg), phenanthrenc/anthracene
(< 10,000 µg/kg), fluoranthene (<10,000 )Jg/kg), pyrene (< 10,00f) µg/kg), 2,4-
dimethylphenol (< 2000 pg/kg), 2,4,6-trichlorophenol (< 2000 pg/kg), tetrachlorophenol
( 2 isomers) ( < 2000 pg/kr,), and hydroxy-methoxy benzaldehyde ( < 2000 )Jg/kg). No PCP
or other toxic organic compounds were detected in the fish samples fro:n Koppers lake.
Two fatty acids were detected but ,-,ere naturally occurring, possibly related to the
natural L1ts in the fish.
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3
The Medlin pond (PL-002) is located t100-S00 feet dm-mgradient (south) from the
Koppers lake and receives runoff and drainage from Koppers lake. The 1-ledlins had
complained in the past of fish kills which they said were caused by PCP. To avoid
future kills they diverted the drainage from.Koppers lake aroW1d their pond.
However, they have since reestablished the flow back into their pond. The water
saBple collected from the Medlin pond (PL-002) did not contain any detectable PCP
or related compounds. Methylene chloride was detected at a concentration of 8.-5
µg/L. The sediment sample contained PCP at a trace concentration (< 2000 µg/kg)
that was too low to·be quantified. Three other organic compounds, two with trace
concentrations too low to be quantified, namely dimethyloctahydrophenanthrene
. carboxylic acid (< 2000 µg/kg), hydroxy-methoxy-benzaldehyde (< 2000 µg/kg),
. and hexadecanoic acid (estimated 3400 µg/kg) were detected in the l-ledlin pond
sediment sample. The fish samples from the Medlin pond did not contain PCP;
_ho;iever, one of the fatty acids found in the Koppers lake fish sample was ·also
present in the Medlin pond fish sample. Bis (2-ethylhexyl) phthalate-was detected
in the Blue Gill fish tissue (fillets) from the Medlin pond at a concentration of
31 mg/kg. Bis· (2-ethylhexyl) phthalate is commonly used as a plasticizer. · Di-n-
octyl-phthalate and an unknown phthalate were also detected at a trace concentration
(< 5 mg/kg) but too low _to be quantified.
Sample location (KR-003) is located in a drainage ditch on the east side of Koppers
property downgradient from the land farming area #1. Since there was no flow, only
a sediment sample was taken .. Trace concentrations of PCP(< 800 µg/kg) and eight
other organic compounds were detected but were unquantifiable (see Appendix A).
These compoW1ds are: acenaphthylele (< 7000 µg/kg), phenanthrene/anthracene
(< 7000 µg/kg), fluoranthene (< 7000 µg/kg), pyrene (< 7000 µg/kg), 1,2-benzanthracene
(< 7000 µg/kg), indo (1,2,3-cd) pyrene (< 7000 _µg/kg), 1,2,5,6-dibenzanthracene
(< 7000 µg/kg) and 1,12-benzoperylene (< 7000 µg/kg).
A water sample from location (KR-004) was collected in a pool of water under the
railroad tracks where.the east drainage ditch drains off Koppers property. The
sample did not.contain detectable PCP but ·did contain three organic compounds at
concentrations (< 10 µg/L) too low to be quantified. These w·ere acenaphthene,
fluoranthene and pyre.ne. Bis (2-ethylhexyl) phthalate >1as._ also detected at a
concentration of 26 µg/L. Sampling locations (KR-003) and (KR-004) are located
along the railroad rights of way so creosote from the crossties under the tracks
is a possible.source of some of the compounds detected at these two locations.
Three wells on the Koppers property were sampled (K\-1-010, KW-020, and KW-030). Two
of the wells (J,,.'W-010 and KW-020) are used for drinking water (see Table l anr'
Figure 1). Diethyl phthalate was detected in (KW-020) at a trace· concentration
(< 10 µg/L) which was too low to be quantified. Diethyl phthalate is commonly
used as a solvent. None of the samples contained PCP or other organic compounds
at detectable concentrations.
Three private wells were sampled in close proximity to Koppers property (see Table 1
and Figure 1). The Medlin well is located downgradient and south of Koppers. The
Wilkerson Construction Co. well is located east of Koppers, and the Baerbee well is
located upgradient and northwest of Koppers. No PCP or other organic compounds were
detected in any of the private well water samples.·
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4
METHODOLOGY
The water 2nd sediment samples colle<?ted during this investigation 1,.;ere grab
samples. The fish samples were collected by a dip net after "shocking". All
samples collected by US-EPA SAD co:ployees were in accordance with the \·later and
Surveillance Br_'.1nch Standard Operating Procedures and Quality Assura!lce 1-:anual
(WSB-SOPQAl1) (3). All samples were transported to the SAD laboratory in Athens,
Georgia by the investigators while maintaining proper chain-of-custody.
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References
1-Stuckey, Jasper L. and Conrad, Stephen G., "Explanatory Text for
Geologic Hap_ of North Carolina", Bulletin number 71, 1958.
2. Water-Related Environmental Fate of 129 Priority Pollutants,.
Volume II, EPA-440/4-79--0296, 19.79.
3. Water Surveillance Branch Standard Operating Procedures and Quality
Assurance Hanual (Draft), U.S. Environmental Protection Agency,
Region IV, .Surveillance. and Analysis Division, August 29, 1980.
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t Q) u " ro
Baerbee
Residence
Figure 1 .
1 -Locat, Map-Samp ing Stuay Koppers Co. Inc.
· ·11e NC Morr1.sv1 ,
Koppers Property
@ KW-020
Main Laminating
Building
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Building I
Building I
Abandoned
PCP Treating '"""U
Main □ -010 Office□ KW
Koppers
3 Acre
Lake
Not to Scale
"
I M -1-'
" f,l ----JP'~Y~!(Ro'-= ... a~_g_-._-_-_-_-_-~-=-=-=-=;""'~=I ;:w.:~-i~o~o~===~~=========r=
----V 'I I
t
T
I t I I
Medlin Residence
ll. ng. location samp
Mobile Homes
PL-002
I
N
Wilker-
son Con~
Co.
PW-200
'>-
u z
Q)
,-j
,-j
•rl :>
<I)
•rl
M M 0 !2
+
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Station No.
KL-001
PL-002
KR-003
KR-004
KW-010
KW-020
KW-030
PW-100
PW-200
PW-300
W -Water
Table 1
Sampling Locations
Koppers Co. Inc. Study
Morrisville, NC
Sampling Site
Three-acre lake on Koppers Co.· Inc.
property
One-half-acre pond behind Medlin residence
Runoff from land farming area #1
East ditch runoff under railroad tracks
Well #1 (100 feet deep) Koppers Co., Inc.
main office
Well #2 (110 feet ·deep) Koppers Co., Inc.
main laminating plant
Well #6 {60 feet deep) Koppers Co., Inc.
east of steel shop
Private well -Medlin well at mobile home
Private well -Wilkerson Construction Co.
Private well -Lewis Baerbee
S -Soil/Sediment
F -Fish
Sample Collected
W,S,F
W,S,F
s
w
w
w.
w
w
w
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Organic Compounds
Methylene chloride
Napthalene
Fluoranthene
Pyrene
Bis (2-ethylhexyl) phthalate
Diethyl phthalate
Table 2
Data Summary
Water Samples
Kopper Co. Inc. Study
Morrisville, NC
PL-002
(µg/L)
8.5
KR-004
(µg/L)
T<lO
T<lO
T<lO
26
KW-020
(µg/L)
T<lO
T< -(Trace less than) -the number is the min~mum detection limit.
Table 3
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Data Summary
Sediment Samples
Koppers Co. Inc. Study
· Organic Compounds
I Napthalene
Acenaphthylene
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Phenanthrene and/or anthracene·
Fluoranthene
Pyrene
I.. 2, 4-dimethylphenol
2, 4, 6-trichloroph.enol
Pentachlorophenol
Tetrachlorophenol (2 isomers)
Dimethyloctahydrophenanthrene
carboxylic acid
Hydroxy-methoxy-benzaldehyde
H d . . ·a 1/ exa ecanoic aci -
1,2-benzanthracene and/or chrysene
Indo (i,2,3-cd) pyrene
1,2,5,6-dibenzanthracene
1, 12-.benzoperylene
Petroleum type product
. KL-001
. ( µg/¾g)
T< 10,000
T< 10,000
. T< 10,000
T< 10,000
T< 10,000
T< 2,000
T< 2,000
6,400
T< 2,000
T< 2,000
p
PL-002
(µg/kg)
T<2,000
T<2,000
T<2,000
3,l/OOJ
KR-003
(µg/kg)
.T<7,000
T<7,000
T<7,000
T< 800
T<7,000
T<7,000
T<7,000
T<7 ,000
p
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T< -Trace less than -The number is the minimum detection limit
P -Indicates presence
1/ -Tentative identification
J -Estimated value
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Organic Compounds.
Hexadecanoic Acid Y
Bis (2-ethylhexyl) phthlate
Unknown phthalate
Octadecenoic acidy
Di-n-octyl phthalate
J -Estimated value
Table ti
Data Summary
Fish Samples
Koppers Co. Inc. Study
Morrisville, NC
KL-001
(mg/kg)
Fish Fish
fillet liver
6J 360J
160J
1/ -Tentative identification
I I
PL-002
(mg/kg)
Blue Gill Blue Gill
fillet liver
. 200J 290J
31
T< 5
T< 5
T< -Trace less than -The number is the minimum detection•limit
Bass Bass
fillet liver
6.7J 2.SJ
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Figure 2
Koppers Co. Inc. Study
(a) Collecting fish samples in Koppers 3-acre lake. KL-001.
(b) Delta area forming from sediment washed from land farming area f/2 and
waste piles. KL-001.
I Figure 2
1--Koppers Co. Inc. Study
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1----( e) Collecting fish samples in Medlin Pond ( 1/2-acre lake). PL~002.
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1---
I (d) Collecting watec and sediment samples in Medlin Pond (l/2-acrc ·1ake). PL-002.
I
I figure 2
I \ Koppers Co. Inc. Study
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I (e) Land farming area #2 and waste piles above Koppers 3-acre lake.
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I ( f) Waste piles above Koppers 3-acre lake.
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(g)
Figure 2
Study Koppers ·Co. Inc.
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a
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Fi,;urc 2
Koppers Co. Inc. Study
(i) Koppers well cast o.f steel shop. KW-030.
(j) KR-003. Ditch where runoff from land farming area 1/J. ancl upper
portion of Koppers property come together.
liiiiiii liiii iiiil iiiii - ---Figure 2
Koppers Co. Inc. Study
-
(k) Land farming area #2.and waste piles above Koppers 3-acre lake.
-- --- -
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APPENDIX A ·
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fISI! PACE. 3 ox:-.\ :~:::::·c:<·t i::c s::E.a
E~:TR,\CT.\llLE o:tc;,:; IC ,-,::_.\LYS l $
Lr',\, S,\!J, r'.C::J. l \!
Athens, C,\ 4/30
l'iWJi~Cl__l;Qi!_,"1<.:l-~~ Cc:•. Tu~ _________ CHE:l!ST E.. ~ ... Loy, Jr. R?.C'D. Cl-")-RfLCC~PL'n.11-~-so
~~o~·d:.d l lc• ~:c
----2,i;~{.) $,\[) ::o. . f.'.OC
r.i..· uul l"jl;>t:E end
of La~e ne.::ir
$OUF.CE b ST,\TIO:i t;illows .?dj. to
D.:lt. FIS!-
OATf./7_1:!S 9-23-80 @ 1000
Co::ipoun<ls on rm.nc List of Priority Conccnt:-.:it.ion
Pollutants ,..,. tkn
17. his( ch lororne thvl) ether l!i? n SA
61. ~-nit t·.:,sodir,,cthv lamin~ 34!.!;2 NA
2,. l 2-Jichlo:-ohenzene 3-4540 IOU
26. 1.3-rlichlorob~r.~cnc 34570 lOU
27. 1.4-<lichlcrobenzene 3➔575 IOU 18. bis (2-chloroc! thyl) ctb-::.r 30277. lOIJ
12. hex:1chlorocth:me 3:;~00 !Ol:
42. bis(2-chloroisoorooyl) ether \'.287 IOU
63. N-nitrosodi-n-orooylanine _..'..'...'..1.? 20~
56. nitrobenzcne }l.,:. 5L 1ou·
52. he:-:achlorobutodiene 3.:.393 IOU
8. 1.2,4-trichlorob~nzene J!..5'5 IOU
>5. uo!."'ht.h:'llr.ne '.1-'.446 !OU
43. bi.s(2-chloroethoxy) t:1ethune 3.::.202 lOiJ
54. isorihorone 3::.t..12_ 20U
53. hcxachlorocvclooentaclicnc ".'.. t4Q lOU
20. 2-chloronanhthalene 3!..585 1ou
77. .tcenaohthvlene 1!.?0t. lOC
1. ::iccnanhthcne 3!.209 IOU
71. diRethvl ohthalat..:: 1!.J!.5 IOU
35. 2 4-dinitrotolucne 1!.lil ~ lOU
36. 2.6 dinit.rotolucr.c 30630 lo.,
40. 4-chlorophenyl ohenvl ether 1Lf>G"", 1 Q;J
80. ·· fluorene . '4385 ,ou
70. diethvl t>hth.:ibte 3.'..Jl.,J lQH
37. l 2-diohen\•lhvdra:r.inc .=..1 3!.JS0 IOU
62. N-ni t rosodieht?nvl.:i.-:,1ineJ/ 30437 IOU
. 9. hexachloro~Cn7.cne 3!.668 lOU
H. ·4-brOmonh.c-:wl nhcnvl ether )4'J60 lOU
.81. nhenon· • 34~6S .
78. anthraccne.'.!_/ 3.'.i224 lOU
68. di-n-butyl ohthalatc: 34683 IOU
39. flur,r2nthene . 34)80 lOU
6-4. nvrcne 3:ili /J lOC
67. butvl benzvl ohthalate 34296 lOU
5." benzidinc 3➔241 20L'
66. bis(2-ethvlhe:;c\·l) nhthalate · 3':10')9 "!OU
76. chry::;ene: .-:!..' · 34324
72. l.2-b~nzanchr~ccn~ ::..1 3.'..530 lOU
28. 3 3'-dichlorobenzidine 34635 lOU
69. di-n-octyl phthal.,.tc J:.;uUU JOU
74. 3, l1-ben7,ofluor.anthi::-ne ~/ . 1!. '"J 1!
75. 11 12-Lcn~o ~ luor.1n thcneb/ J~"246 IOU
73. 3. l,-bcnzopvrcnc . 3'-1251 IOU
83. indcno (l 2.3-cd) ovrcuc .. 3.'..407 IOU
82. I 2 5 6-d i Lenz.in th r.::iccnc )-'1560 lOU
79. I J 2 .. ln~n7.0[)C ry lcn e Jl1S:!S lOU
21 •. 2-chloro;-,hc:no! )!i:,'-JU l, Ii
57. 2-nitrophcnol 3:,59:, I, II
65:-t. phenol (GG/:'.S) ):,.'.i18 4t,
31,. 2 11-tl ir.11; Lhyl ph~no l y;,.,10 ,,u
31. 2 1,-d i ch loronh,;nn 1. )!,{,()] 4t• 3..~J:.. 6-trich 1 nro:,l,.;nnl )!,(,'..!5 t.i;
22. p:1 r.,ch loro;,-.r: 1.:1 cr,-:~ol ).'i.';J(i 4L'
::,'). 2 l1-0i nit rop!i.:-:-io l J.'.:.,'.'.•J J2L'.
60. I, .6-<liui t1 o-r•-<-:rer;o] 3.·,t,•.iJ 4U
~-•..:nt;idilo_::~::,!,cn0l J'-!Uo!J 41! ,e. l,-11 i.1. rop:1,:r10 J j.·,;J)i..l Sli
'-A -t:ot :-in:ily;:c<l.
J -J:•;t.ir.;.,tctl v:1lu(•.
K -/\ctu.il v,,111<! i:-; l:no:.;n to bl! lC'.!;:; lh.Jn \':1l11c r,ivcn.
L -/,ct1.1:il v.,lui! is kno~n to h...: cr.:-;:itc:-th:rn v:1lt,,! f,i\"..'.!t:. t= ~;:;';;~~~t;~~~~~:~:~~i~~'. hut no, JctcctcJ. Th,• m,,,,cr ic.
I soc 2463
FISH Ll\'ER
Co:1cc:-:cration Conccncc.ation
m':.'../'r~f!. mi:;/kg
~A
~A
8U
BU
SU
SU
an
81!
16ll
.uu sli-
8U au
SU
l6H
SU
.SL:
SU
SU
I SU
BU
au
8U
BU
BU
Bu-
BU
BU
-i;u
SU ·--..
OU
I ou·
SU
"" 16U
. ·.· "" .
.. . ' . . SU --.. -. .. --_ou
bLi
.. ' · .,···au· .. : a ---· . . .su . .
SU
Sll
·_oL' ·-16t: ·-· -16li ·----16!!
l(,t;
](ii:
lOll ----161: ----·-····---i l1C!'! ---bli·---·--1
I jf,[i ----1
I JOL!
~/_ Chr:_;:-t:nc .,n~/or 1,2-h>!n::.,nth-::
[!I -J,l1-hca::uflu,1r;mthcr..:-:md/,l:-.
ll, 12.-1,cn::oi 11:0 r .:i.:1 tl:...:nc.
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D ......... ,._ ..... ,.:..",
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SOIJRCE ' ST.\TlO)l
D:\TF./Tl~IE
CO:-IPOUND
bex_a~d_~~-a'!:'-oic:. acid li
octadecenoic-acid li
.
~·1 S!! IJ,\i,\ }:L:'C:rrt::c ::iili:::ET
[XTh..\CT,\Ul.E O:>.c.~:1c .~:,\LYSIS
.. ' ~L-tll.ll L';.ipcr end
of L,ke near
\>'.illo..,.s. adj. to
delt. FISH
J s-2J-so ~ 1000
Concentration
n~/ke:
6J
lOU
.
.
'
..
:.., :\. :i.\:J. ::-.-..::;. !".'
Alh<!ns • C:,\ t./2,1
co:-:?t. • D .1 r-:>-~
.-
FISH Ll\'ER
Concer.tration Concentr.-?ti::>1
~-=-•t: .. r:.,:;,/k-:
J50J
160J
..
.
. ..
.. .
-
-
llo other or~anic co:npounds detected with ~n c~·::i:,:itcd F.iinir.ium dt!tcction li:.:it of
120
J E=.tim.:itcd v;i.luc.
K Actu=il "'-"11:ce 1::: kno·.::1 to he lc::;s t·h,:m v:il11c ~iv-.?n.
L -;,ctual v.ilcc !::; known to be grc:1.tcr th:m v.::ilu.:: givcu.
U -fUtcrlal v.1.~; .,~1.:ilyzccl for bu~ not. dctccu~d. The nur::bcr i5 the !-li11ir.1ura D.:..:c.-~ct.ion l.i~i.:.
l/_ T~nt;1tive i1!c:nti(ication.
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D
FlSH
!).\';".\ l:i~•:.):-:.Ti::G ~!'.7.i·:T
EXD.,\CT,\!JL£ O?.CA~IC ;,:~..\LYSl'.'.;
.P,\GE 6 r.r'.\, S,\lJ, RG::. 1·:
Athens, G,\ t.{S\J
Koppers Co., lnc. ciic rs E I' L J 1'?.0J:.CT ___________________ :.:I T • ~. oy. r. R.:.c·n. 9-25-BOco~!PL'D.Jl-{,-50
SOi.iRCE & ST.\TlO~
DATE/T[:-tE
CompOlm<ls on ~RDC List of Priority
Pollu:::mts
17. hi!.:(chloro~o?thvl) ether
61. ~!-nitro~::icli1:iethvlaminc
25. l, 2-<l ichlo:-o~enzcne
26. l . 3-,1 i,:hlorobenzcne
27. l,.'.;-clir.:hlorob~n;:ene
~is-( .2-c.hlo:-octh'l.·1) ether
12. he:-::-ic!., lo:-oc th:i.nc
42. l,i5(2-chloroi::;~,!':lro""l) ether
63. ~•-nitro!todi-n-nro!>yl:imine
56. nitr~hcn;.en~
52. hcxachlorobutndienc
8. 1.2.4-trichlorobcnzcne
55. nnohthalcne
43. bis(2-chloroethcxv) rnP.th~nc
53.
20.
77.
l.
71.
35.
36.
· 40.
80.
70.
37.
isoohorone
hcx2.C:hlorocvclo::-f!ntt!.dicne
2-chloronaohthal~ne
acen:iphthvlcne
acem:ohthcnc
dlmethvl oht.halati:!
2.4-dini::rotolucne
2,6-dinitrotolucne
4-chlororih<?nyl phenyl cth.-:r
fluorc-ne
diethvl oht.h:t}.!.t~
1 2-dioh~nvlhvdra7.inc L./
62. N-ni.trosodirohenvl.:ininc.l/
9. hex~chlorobi:?nzcne
41. ·4-bro~o~nvl ohcnyl ether
">!,')"~
34442
345.40
34570
34575
34277
3M.CO
34287
J!..!i"')
1dst.
J!,]93
345~-s
3:,:.46
34'.!82
JL.412.
1!. 100
J!, .-.s,;:
"'.\!£',IA
-.,42il9
J!.345
1f,ii 1 =-,
··14630
1!:64,;:
14385
3434,J
34350
34437
34668
34640
81.· ~.n..thr~~-~--~-:== '''--------'--"" 78. anthraccne.Y
34465
34:!24
68. di-n-butyl rihthalatc
39. fluornnthcrie
67. but.vl benzvl rihtlialo.tc
5.·· bcnz.idinc
66. bis(2-echylhexvl) nhthalace·
76. chrvsenc ~/
2S. 3,J'~dichlorobenzidinc
69. di-n-octvl ohthal:'ttC
74. 3 4 btn7.ofluoranthcnc b/
34f.83
34380
344 7)
342~6
34241
· · 3~09~ .. · 34314
J45JO
3463S -·:r41;,uo
,!,?'"''
-soc 2466
PL-002 Pond be-
hind H<!dlin
horce.
Bl.EE C.1LL
9-23-80 @ 1115
Conccntrati6n
.,.,./kt;_
SA
NA
SU
5U
SU
SU
SU
SU
. IOU
SU __ ,,;,._
SU
SU
SU
SU
. IOU
SU
SU
SU
SU
SU
SU
SU
SU
SU
Stl
SU
SU
SU
SU
, ·su
511
.. -SU
. SU
SU
IOU
31
SU
Jt,'.U,6 75. 11 12-henzofluoranthcncl,/ SU
31,251
3:,407 8). indeno .(1,21 3-cd) .-. ... ·rcne SU
3.'iS60 ~~215 16-dibe:nzanthracenc SU
I
HU.:E GILL U\'ER
Conccnt ration .::...,nccntratio:':.
r.i~/k:; 1:-:~/k~ ·;, ,,
70t:
70LI
70t:
70U
70U
70U"
140U
iOU
70U
70Li
70:; -70U
14011
70U
70t.: ..
70"
70ti
7UU
70U
7('~!
70C
7011
70.U
70ll
70U
70U
70U
1ou •.
70U
70U
70U
70U
140U ... . 70U
. ' -.. .. 70U ..
70U ..
7n•• _., .. . .
--=--!------101..: -. 70l.:
70(;
70C --+-----·19. 1 12-hcnzor,f!rvlcnc '.>LI -'-'-'--"-'-=-=-====='------==-1----"'"----1----"'-"---.---:--.-'-----21,. 2 chloror,hcnol IOU
)!1525
3I.)')0
70ll
2.0U
3:,:,95 S"J. 2-ni trophcno} }OU
").',.',C,S 65n. tihc!nol (t:C/l!S) ]OU
J'l(,10
34(,0)
)t,oLS
3:.:,5.-,
:1:,,·,:!()
:1.',t,1,J
J.HJl1IJ
J.',11:,;J
·:A -l:t.>t ;m.-.ly~•:<l.
J -f.:>tir.i:i.tcd v.,luc.
I( -/•.<.:·ual v.,l.11r.. j:: kuo1.:n to be lc-ss llt:?n \':!luc 1:i.vcn.
I. -,'h·t u.:tl value i::. kt1u~1n ln h•~ i.:rc-.,t<.!r' t.h~1n \·.,111..:: r,iv,:n.
:!OU
20U
.,Ol'.
')'()LI
.~ot:
:cu~!
1 i,di..'
2UU
?UL -1---
:.•JC -i ------
Chry:.t:nc: .,n.J/o:-1,2-hcn~::t=-ith:::
J, /1 -i,.~n ::c, [ h.:u :-;1nr.li..::n,"! nncl / C:'
l l, l'.!-·l>,~n::nf l11or:mth<!ne.
I/ -i-!.~tl";ri.-.1 11-1:; nn:lly;,;<;<I for \,uL uot. dcte.ctc,I. 111<! nu:::hc.r i:; th<! ::i11i~:u~1 lkrcction I.ioit.
-~-Tf-;nt:1tJ.·,11.! ident!.fic:ition. ~ .-· .11~d/or :1zol,c:>n;:~nc. (ov:::i.)
I
I
I
I
I
I
I
•
I
·._-::·~: u
D
I
I
R
I
D
I
I
I
..
SO~lR.C!:: " ST,\TlO~J
UAT~:/Tl~lF.
CO:-ll'OUND
unknown· phth.ilatf!~ ]J
hcxadccanoic acid }j
..
,
rrsn lJ,\T,\ 8E!'l1:-:.r1:;r. Si!l::i.::T
E:-:Tf'..:\CL\~>L[ O~C,\J:IC ,\'.•:,\!.."i!~lS
-' PL-002 l'o:,d behic,1
H~dlin Hor.:e..
BLUE GILL
9-23-80 G 1115 I
Concentration
m~/1:.~
SK
200J
-.
Atb::n5 1 CA 4/SU
co:·IPi.'D. 11-6-:3
V _ .. l >
?,!,_J_;a;-GILL Ll\'F.R
I
Car.cent-ration Conccntration
...,,../'.<,n . t:i~,~~
70U
290J
I ..
.
-
-
..
• so ng/_~s J:o other orr.anic cowpound:; detected .,,:ith an cr,tir.iatcd reinicu:a <l.!te;ction li::iit of
160 og/kg -
J -Estim:itcd value. · GILL I.
1: Actual -..·.-i~ut! i:. knQI.JO to be less th,:rn v;i.luc giver..
L -/,ci:u;:il v:iluc ls kno\.ln to he r,rcatcr than value r,ivcu.
U -i-Lltcr::!.al \.1:1$ :m.:ilyzcd for but not detected. The nu;::!,cr is the !-!ini:au::i. Dct~ction Liait.
l/ Tcnt.,tive iJcnti(ic:ition.
••
I
I
I
•·
I ;
I
I
I
I
I
m
m
I
I;
I
I
n
D
1-'IS!i n.\T.\ 1,:::!•:Jc<.·1 i::c s::c:.c:r
D:T!::,CT,\!.:I.::': o~c.,:;1c ;,;:_\L'iS[:;
--~•!.c:s ,J -
t.., "· .,.\:J, r:.c:-:. !':
,\t~ ... :11::., CA :.j2,,_
,··c~ Co lnc. c111·.·.1•.s·,· E. 1:. Loy; J.r. !'RO_ 1, • --1:a.pµ•=~·--·-•-----------!{:'.:C' D. _2.::_?. 'l-.~o<:O:·!i'L' !) • -1._~
M0 rr i ,.,. i.10l~e~~'~C_. ________ _
-.. ---~.\.lJ :;o. soc 2t,{j6 soc 2466
PL-002 Pond b..:-
SOU~CE: & ST,\TIO:I hind Medlin
horue.
P,t,SS Br\SS LI\'EH n.,n:rr1:1E 9-23-SO @ 1115 --Co::i;'JOunds on 1'!-.DC List of Priority Couccntr.'.lt.ion Conccntratiun Co:ice:-icr~tio:i
Pollut,:mts --,,. tkp o;:;/k~ n~/t~
17. his ( c:h loro:re,thv [) ether .,, ?·,,.., NA NA
61. ~-nit n,sod iocchv l.i::i i.r.~ 34442 NA !\.'.
25. 1. 2-<l ichloro~c-nzcnc 34540. SU 30C I . 26. l. )-,tich loroh~n=~r.~ 34570 SU 30:;
27. l 4-dichloroben~cne 34575 SU I 30l:
18. his ( 2-chl oroech,· l) ether 34277 SU JOU ·12. hcx~chlor~cth.'.ln~ 34li00 SU JOU
42. bis(2-chloroi~ooroDvl) c~hcr 3~287 lOU 60U
63. N-nitrosodi-n-nrooVl~ni~e \!;.liJ? SU JGC
56. nitro~cnzcne ·1:',451. SU 30t
52. hcx.'.lchlorobut.idicn~ 34193 SU )Ol! s. 1. 2, l.-tdchluroLcn::cnt? 3!.5.S"i SU JOU
55. n:1.1hth:tlcnt? 34446 SU JOU
43. bis(2-chloroctho:-:v) r.:cth.:me )!i282 SU JOU
511. isonhorone 34412._ lOU 601..i
· 53. hcx.,chlorocYclo:,cnt.:i.dicn2 l!i'HiQ SU JOU I 20. 2-ch.loronnnhth:ilcne 1(,535 SU JOG
77. :iccnanhthvlcne 1','"'l.. SU JOU
1. :iccn:i:ihthc~ 34209 SU JOU
71. di~ethvl nhth.1:L'!tc 1!13!,5 SU JOU
35. 2.4-dinitroto!ucn~ 1!.f,J ') -= JOU
36. 2 6-dinitrotolucnc 346.30 SU )OU ,,o .. 1.-Chloro:->lwnvl riht?nvl ether ·Vifit,'i SU JOU 80. f h:orcnc <u ·JOU -34385
70. rlicthvl nhthal.itr. 1!, '.\4,J <u JOU
37. r 2-dinhcn-.·lhvdr.u.inc LI 34350 SU JOU I 62. N-ni t. ro:;odinhcny J ;:nain,2.J/ 3'~437 SU JOV
9. hc:•:ach loro!lcnzr.nc 34688 SU )OU
H. 4-bro:nonht>n,·l ohcnvl cth.:!r · 34640 SU JOU
81. '"'~":J .... D th--c:or• ~,, 34465
iB. .t!lth!".:iccn~I 3!,224 ·su ·3oti .. -..
68. di-n-hutvl nhth:i.1.:itc 34683 SU JOU
39. fluor:inthcne 34380 SU 30U I 84. m;rl!ne 34413 SU 30i.l r 67. hutvl hcnzvl ohthalatc 342% SU 30!.J
5.·· benddinc 34241 lOU 60C
66. his(2-cthvlhcx\"l) r,hthalatc . J;oyy SU JOU
76. chavs-::nc :'..! . · 343:!4 . . . . . .. ' 72. 1. 2-t,cn:!.."rnthr.iccnc .c!...I 34!,Jl) ' . -JOU .. .. . . -· ' SU ..
28. 3 3'-dichlorobcn~idine 3-'1635 SU JOU
69. di-n-octvl nhth:llatc J4bUU SU :•. JOU ..
1,. 3 4-b1:n:w(luor.1.nth,::,ne ::::_, . .,, ?1./ ,. ....
75. 11 12-bcn:,;o f luor:rn thc:1c_l!.f 3!, 246 SU .:.···!wU ---..
73. 3. 1,-bcn zonv r~~nc J!i251 · ·su ··-. 30!.J ' 83. indeno (1. 2, 3-cdLJlvrcne 34407 SU JOU
82. I 2 5 G-d ibcn":!.:m th r,,cene )!1560 SU JCll!
79. 1.12-bc•r.7.oocn·lcnc 34525 SU "JOL'
24. 2 ch l c,:-or,hl·nol 3-',590 lU 2t: 57. 2-nitro~lu . .:nol )!1595 J ti 2li
G),i. nk:nol (GC/IIS) .1-',!,()8 JU 2U ~-2 1,-<l i 1~c tl,v 1 phcno l 3-'<610 Ill 2l!
31. 2 1,-<l i ch J.ororiht'.no I 34(,0S -
. l C 2r
21. 2, 4. G-trich loronhcnol Jt,1.>:!.S 2C
--~
. .. -JU
22. p.,r:ich lon•:-:'!t:1 c:-c:.:ol Vi:',Sf, lC 21..: -59. 2 1,-d i :l i. t roohc:10 l '.14t,J.U 8U lb:.'
(,0. t,. (,-din 1 t ro-o-c r.:::.:o 1 :1::.(,(1 J. LU 2L I -·
-~~-?_'--'nt.1ch lo:-<•j•l,,.~nol )'JUllU I JU , .. -----C
.1U. t,--111.t.rophcnol 2U
:A -t:ot :,naly:-:c,I.
J -I-::;cim.J.tcJ v.,llic.
Chry:-..::nP. iln,1/or l, 2-b,~;1:-.:inth-:
J ,1,-h,•n::o ( 11..:0~ .::ntlu:.-r..: .1nd/ c-::-.
K -/,ctu,11 v:1l11c i:-. kno-..rn to he le~:; tkrn \'.1l11c &ivcn. 11,12-i•>.!n::orli::,r.,u::h,--::ii!.
L Actu.:il v.1lu\! i:, kno\ln to hi! 1;l·c.1tcc rh:rn _v.1l11t! r.i'✓i~:\.
~ -i::~tcrl.-11 v.,s ·.1.r.Jlyzcd for but nut d.::tcctc:,I. The nu::!h<:r i:; t.!11.:_ }lj;1i~11::-i Uct..::ct.i,1n Lir.:it.
-~-Tcntatlvc idcntificati{lO.
; .-· :1nd/nr .l.7.r>1H•n:•,·n,·. tn,11.-:1\
I
I
I
I
I
I
I
m
I
g . ····.·•···· .........
D
I
D
D
I.
m
•
I
I
PKUJ?.CT Koppers Co., hie.
"orrisvi 11-. :-::c ... ,.
-~--=
5,\Jl ;;o.
!'"ISi\ lJ:\7,\ P..E:'t;;rre:c $!\EE:r
EXT:'..,\CTA!\l.E o:::cA~llC .~:,\L\'Sl~
C!!!:::HST E. \.!. Lov, Jr.
-~ sue 2!.66
PL-002 rand be-
Ei'.\. S,\J, ;,_:,:;;_ ~-•
Athens, C:.\ 4/i!.O
r.r:C'D. 9-2S-SO
-~.._,_ .. ave 'l.466 I
hind l-!edl i.n home. SOURCE • ST,\TlC~
BASS BASS LIVER
DATE/Tn:t-: 9-23-80 ~ 1115 -
' Concentr.:i:iOn co:1Pour-..-n Concentration Concentration
nr-.Lke> ". . -:-:.z,/'r.z.
h~xadecanoic.. acid }) .6.N j::;y---··
..
.
..
.
.. .
,
-
..
No other organic co:.ipounc!::; detected \.'ith an c!;0tir.1:1tcd r.iini1;ura d~tcction lii:i.i.t of_lO .:-.~/k.s_.=.._l .::_::_:_::_:.::_.::_:ce:::::c:.:....:::::c.::.::..::.::.::..::.:.:.:.::.:::.:_.::c:_..:c:_:::.::.::cc.::..:c:_.=:.:.:.:.::::c..:..:.:.::..::.:.:.:.::...::.:.::..::.:_:.:::_660 '--Sfr!; - I . Ll
,J -Esti~ate<l value.
1: Actunl Y,"ll_ue is kno.,.-n t:o he less than v.:iluc: i;iv.:!n.
I. Actual value is known to he ircatcr th::in v:1l11c f.ivcn .
U Hatci:::i.:il \..",,s 0~1.:i.lyze.d for: but not detected. The nur::.bcr is the Hiriir.iu;J. n,.-t~ctiort Linit.
!/ _ TcntatiYt! ident_ific~ti.011.
I
I
I
I
I
I
I
I
D
I
I
D
u
I
SEDl:-;r.::r
n,\TA kE!'Oi{TJ:,.;G SHEET
EXTRACTAULE ORGA:-;IC ,\~;,\LYSIS
!':lOJ:.c: !.:o!">t•.!rS Co .• Inc.
:•'.:>rri!-vill<c'. XC
Cl!E:·t!ST F.. IL Lov, Jr.
EPA, S.W, RC:,.;. r,·
Athens, GA ~/50
REC'D. 9-25-RO CO:·!PL'D. 11-6-S:
RFSULTS o-.; llRY t-!FJr.!iT £\·\SIS ---~ --~:;,D '.'0. 60C 2t.69
KR-003 Dovnstr~.:i.m
sci.:;.c~ ST . .\TIO:,.; from are.:i. dis-&
char~cd & SO'.JT\
'" •h r:rass. ~,;p·/7I:·!E 9-23-80 Q 1700
Co:.i,.ounds on ~;soc List of Priority <.:onccntx:atioa
Pollut."ints u~/k~
l 7. his ( c!i loro~e thvl) ether 34271 NA 61. :,.;-n i trcsodir:,c th\· Ll~i n~ J ... 1 , ..
2). 1 2-dichlorobcnzenc J➔.'>J9 7 ,ooou 26. 1.3-dic~loro~cn~cnc .,-ob:' 7 ,ooou 27. 1, t,-dichlorobcnzcnc . J.'..iS74 7 ,ooou .18. b ! s ( 2-c_h lorocthv 1) ether 34276 7 ,ooou 12. hexach!o roe~h::mc. 34399 7 ,ooou !.2. bis(2-chloroisopru~vl) ether 3.'.+286 7 ooou 63. N-n i trosodi-n-Pro:,v l.1.r.iine 344 31 14 00011 56. nitrobcnzene 34450 1 noou S2. he:-:-'!ch ln:-obucaclic.n~ 39705 7 noo11 B. l 2.4-t~ichlorobenzcne 34554 7 mu ' 55. nn.ohthalcnc 3·4t.45 7 nr Oil 4). bis(2-ch!oioc.tho~v) T:',eth.=me 14281 7 ooou 54.· iso:,ho-ro:,e 14411 14 ooou 53. hex~chlorocvclo~ent~clien~ 1.41!<.'-I 7 ooou 20. 2-chlo:-onanhthalcnc. '.M584 7 ooou 77. acenao!;c.hvl.:ne ... "1{,?n"l 7 O00K 1. accnnnhthc.ne ~4-,no 7 ooou 71. ciimethvl nhthalatc. ,41t..4 7 ooou 35. 2 14-dinicroco!uenc J'if.11 t, 7 ooou 36. 2.6-dinicrotoluene 34629 7 ooou t,O. 4-chlo-rorhenvl ohenvl ether 34644 , 00011 80. fluorc~"" 3!+384 1 onou 70. liet!ivl ohth.ilate 31,339 7 nnou 37. 1.2-dinhen·,·lh•:drazine .£I 34349 7 ooou 62. t:-ni trosoci i ohenvl.imi:i.e Jr 34!.36, 7 ooou 9. he:-:a~h lor-;:,~~:,z~:,e 39701 7 ,ooou 41. ·4-bro::,o-.:ien,..l nhc.nvl ether 3li6J9 7 .ooou ~ ,...., ... ,,,,.,,.•,/ 34464 7B. anth:-acenc.:/ 34223 7 000K· 66. di-n-bu;:vl 2hthalatc. 39112. 7.000U 39. fluorant~:ie. · .. ·]!1379 .. · .-7.000K 64. ovr<'!:ie ·-··· .. .. 34t.72" 7 000K 67. bucvl benzyl ohthala::.e 34295 7 .ooou 5 .. bcnzidine . 3q121 14.000U 66. bis ( 2-1'.!t:ivlhe;.:•:l) r,h tha la ::e .,0 102 7 ooou 76. chr•:ser.e :,_, 34323 72. 1 22':""benz.anchracene .JI. ... . .. -... ·34529·· . . ,. 7 000K. 28. 3.3'-dich!orobenzidinc 14f,1!i 7 ooou 69. di-n-octvl nhth.ilate 1,45ci9 7 ooou 74. 3.4-bc:-izofluor.::mtbome ::-..1 •42" 75. 11. J 2-henzo ~luo:-:i.nthene~J 1/,'.)t..'l 7 ooou 73. 3. ~-::c,.:.c;}v!'.::r.~ .. . ·-----·•t,7."",•). , . . 7 ·OQUU , .. ·.·,··..; 83. ind..:no ( 1. 2. 3-:cC:) .. o·:r.:-..:.c. ··-}l,I,·(\;.. .• 7 000t: 32. l· 2.5.6-dibenz,:mthrac~ne <!, 'l '--0 • •. 7 O0m:: 79. l 1-12-0o:-nzor•err!ene: .. -. -· 7:.52.L _··-·'_LOOOK 24. 2-r.'.1lo!'o;1hcnol )!;5!-19 soou 5 7. 2-ni t rn:,b,:-.n.,1 )!,594 800!.i 65a. P~l•".:l!'Jl (GC/:·!S) ]l;(,95 8UOLI )4. ' l-<l i :~,:, t!w l ~:1c:101 J!,f,O9 soou 31. ' 1,-d ich In ro;ih~no l )/! 60; 800U 21. 2. I,, 6-tr ic:, !o:-oril,cnnl .V,(12!1 8()UU 22. p."! r .,ctil o :-oi~e t ;i cr~snl ).'.t.~5 t:00U ;.9. 2.',-d i:1i t n:•r,hc111Jl Jfd,}9 fi l1ULlt: &O. l .. r,-di:iitrn-o-,:rc::ol J!,{,60 SODU ~-~·:, t :,,:t~l-n rc-0!•.cr.•1 ! :iSD!'.""11 HllOK ~-· ,,-'.~0-ror,it<:nc-1 )!, ()/, <.l l {,001!
:,\ -::o::: .1:1:11:,-zcd.
J -F.:.tic:.1r<.!j v .. 1luc.
:..;. -:,ct.t:...11 v.:iluc is ~n01.:n to l,c le:;:, th.:w v;iluc r,iven.
I -~--
Co~ct!~tration ~1.Jncent r.;i. tic,:-.
u~/kR ug/".<.~
NA NA ~-. ...
I
.-
,
...
-..
.. .. -
' ·-· .• .. . ..
-·-·
··1·
-•------
Ch r;;s·,:at! ;,n,l/oi-1, ~-Lcn::anth:-.:ic,
J,t.-l:t.:a=ofluc)::_--.1111 h<!IL\! and/or
ll, 12-h.:::n~of h1uc1:1thc:'\...:. L -Actc.11 value is ~-.1101:n to be l:rc·.,tcr rh.1n v.::ilu<.! r,iv,~n. li: :-'...:!t<.!ri.:il 1..1.ls ·.1n.:ily;,.cd for but not <l1.:tcctcd. Tltc n11;--.,bcr is 1.h.::: Mi~i~u::i Dc:tection !..fr:iL. Tc~t:itivc idc:1tificatio:1.
-if .ind/ur .:nol>.:::n:'.0.:11<.!. ~,= --''··--·~-'-... (0\'E:l)
I·
I
I
I
I
I
I
I
I
I
I
I
n.
I
I
I
SEhI::::::-:1
DATA REPO!{TJ:;G SHEET
tXTR,\CTA~I.~ ORG,\;:rc ,-..-;;..LYSlS
~ROJ[CT KOl)"'<!rS Co .• Inc.
~;nrrisvill.:! i\C
CI!F.~!lST E. \..'. Lo::, Jr.
SOURCE & STATIC~
0ATE/Tnl£
Co~pounds o~ ~RDC List o( Priority
Poll11ta,1ts
17. bis(chloro~Pth\"l) ether 34271
25. 1,2-dichlo:-oht?n=:cn.. )4539
27. 1.4-dichlornbcn.zcne 34574
18. bis(2-chlorocthd) echer 34276
12. hcxachloro.:!t!"l:mc 34399
42. bi~(2-chlorci~ooroovl) ether 34286
63. N-:nitrosodi-n-oro~vl:rnine 34L31
56. nitrobcnzene J'!!,SQ
52. hexachlorobu~.:idicne )•.H(JS
8. 1.2,4-trichlorobenzcne 3.!.554
55. naohth.::iknc 34445
43. bis(2-chloroethoxv) methane· 342£1
20. 1-chloron.:rnhthalene 14~$4
77. ac<::n.Jf'hthvlcne 1.4?n-,
I
PL-002 rand be-
hind Medlin
hor::ie.
9-2)-80 • 1115
l:onccntr.,cion
ug/kr.
NA
?l!A
2 ooou
2 .ooou
2.ooou
2 ooou
2;000U
2 ooou
4.000U
2 ooou
2.000U 2 ooou
2 ooou
2 ooou
4 ooou
2 ooou
2 ooou
2 ooou
PAC£ .S
EP /, • S,'.D, P.c:-;. I\"
Athens, CA t,/00
R!:C'D. 9-25-1:iU CCf.iPL'0. 11-6-fJ
Concl'.!:it.ration
Uf'./ki::.
NA
C1Jaccntratio:
uc/k2
1 .. acen~~~h~t~h~e~n~•=.:-:-:-::-::,-------~'~·4~·'~0~'•~;---;;-~~:,------J---'--------+-~------71. dii.lethvl ohthala::c ':1,41!.!: I
2 ooou
2 0000
35. 2.4-dinitrotoluene 1.!:f..ll
36. 2 6-dinitrotoluenc 34629
GO. G-chlorooh!!nvl rihcnvl ether 31;6l.4
SO. fluorene 34384
70. diethvl :,hthalate 3G339
37. 1,2-di:,he.nvlhvdrazinc !:J 34349
62. N-nf t.rosodil:ih<::.:ivlai.linc.:!.' 14l,36
9. he~:;,,_ch loro~.:-;iur.e 39701
-H. ·4-brci~o~henvl ohe:nvl ether 34639
~~c-,"'ntbr·~-..... Y 34464
78. anthr~cen~~/ 34223
84.
67.
65.
)6.
72.
28.
69.
pvrt!ne
butyl benz.vl ohthalate
benz.idinc
bis(2:..ethvlhexvl) phthnlate
chn·scn~ ";)_/
1, 2-bcnz.anthracenc .:!_I
3,3'-dichlorohenzidinc
<li-n-c-ctvl phthalatc
)!,472
3.:.295
391n
39102'
J4J23
14529
34514
3!1599
74. 31 4-benzofluor,1.nthcne ~, )!•231
75. 11112-benzofluur.,nthcnc6/ 34·.U,"•
57. 2-nitro:,hc-nol )!,S~!,.
1 ooni,
? MOu
2 oonu
2.000U
2 ooou
2 ooou
2 ooou
---t-------2.000L! 2 ooou
2.000U 2 ooou 2 ooou 2.GOOU
2 ooou
4 ooou
2 ooou
2 ooou
2 ooou
·2 OOOLI
2 ooou
2 ouoo
2 ooou
--'--'-= 2.000U
2 ooou
2.0fJ0U
2 .uoou
I___LOO0U
6S:i. uhcnol. (GC/:-;s) )!.f,95 ~-.'.-cl i r.:r;:~;.~;1~,,~l:._c:_n_o_l ______ ~3.-,,r~,o~,~,-~~~~---+--------~·--------
2 00011
2 Q(liJL:
c)~l~.~~2~.,~1~,-~d~,~-c~','·-~' ~"~'~o~o~h~e~•,~o~l~~------·3~'~t~,0~4~+---"-""="'-----t---------1---------
21. 2 I, 6-trichlor.£2_hcnol )46~4 I I 2 ouou
1(, ,OOOli
"2~2~--~I~'·'~'~"~c~l~•~l "='~o~i~~c~t~.,~c~c~e~s~o~l~ ______ )~t~.,~',S ,~'-;-~-';-'"""'-'~---+-~--------11-------___ _
S9. 2.t.-dinitro7>~Cnol J.'J,!9
2 ()(J()l: 60. t.,6-Jinitro-r)-cr...:!;(,1 l/,:'J60 ~·--'------~=~------~=~--+-~~~~---+-----------+---------
~en tnch lo ro:lk:n:1 ! _)~'0(, I _--2...Q.,(,.,o~,~------t-----_ ----+--~-------
58. t.-ni tro:1hcnnl ·j:di!,<J t. O!JOO
:,\ -:~ut :111;,Jyzed.
J -Esti:.":.1:--·<l v:ilu'.!.
,\ctu.Jl ·.-.-!luc i5 bw:..·n to b..:: lc:~s ti1.Jn v:1l11c r.iv,~n.
Actu.Jl v:1luc i5 kntn,'11 to be gre.Jtcr th.:.11 \'Jlu..: r,ivcn.
;-Ltt.::ri.11 ·-•.15 a~.'.l.lyzcd for but not <l..::tcctcJ. The nu::i:i..:~·
,--,.,,,.,ri,.,,. 1,1,.~,;f;,..,,,..;,,,._
Chrys~n,:-.,nJ./nr J. 2-b,:r.::.:wth:-.:i...:
3, l1-hc-:1~of lull t· .'lnt ht!nc ;ir-_:\/ o~
11. 12-b..:!n:,;of lu~i t· .,n t Ilene~
i~ the :-lini~u:n Oct..:ctio11 Li::ii.t.
I
I
I
I
I
I
I
I
I
·g'<,·.-•····"~·-.... . ....... ;.;.·-.:
n
D
I
n
I
I
m
I
I
PROJECT Ko:-.!'ers Co. In~.
}'orri~vi l lc NC
S,\0 ;\U.
SOURC'£: • STATION'
DATE/TI~lE
cm-1rou:,..1>
dimethyloctahydrophenanthrene
acid =-'
~roxv-methox,;-benznldc~,·dc
hex:1dec2noi.c acid y
.
<·
,
. '
srn1:-1E:;r
D,\T,\ REPORTI~:G S!lEF.T
EXTR..\CT.-\BLE o;_c,\~IC Al~ALYSIS
EPA, ·st.u. r.c:,;. IV
Atli<.!ns, C,\ /i/'::,0
Cl!L'-:lST~~-1..l:......._ R~C' D. 9_25-80 CO>rPL'D. 11-6-$
RESL!!.1''.i O:i URY l~E.IC!iT !!,\:,!$
soc 24(15 I
PL-002 Pond
beliinc1 l-!e.dlin
hone..
9-23-SO ~ 1115 I
Cone en tr:i c ion Conct:r.tr.Jtion Concentration
ui>/kc u~/k2 . ur-/kr-..
carboxylic
·• .. 2QOOK
1/ ?QO,...., .
3400J
.
No other organic cor.i~)Qunds dctcctc<l with :in e~·tiia.:tt.l.!d minit.1u1:1 dJtcction li:nit of .• 16 ,0DO ug/ks
J -Estimated value.
K -Actual v.:iluc is knm.:n to bc ll.!!::S than v::ilue tivcn.
L -/~c~u~l v::ilue is ki.1u•,1n to lie grc::itcr th:m v::ilu~ tivcu.
U -r'literi::il \,1.1.s .:i:1_:;lyz.::<l for but not detected. The nurr.hcr is th~ Z.li~fr.t::J D.::tection Lir.iit.
i/_ Tentative i<lentific;-itio.i:
••
I
I
I
I
I
I
I
D
n
0
D
D
n
I
?;tOJLCT l:c,·iricr~ Co. Inc.
~br:-isvillc. :,.;c
. ... .
S,\O ~:o.
SOURCE • STATim1
D,\TF./TI~I!::
Compounds on ~RDC List. of Priority
rollutnnts
17. bis f ch loro~~ thv l) Pthcr
61. N-nitrosodi~cchvlaminc
25. 1.2-rlichlorohcnzcnc
26. 1,3-dichloroberizcno!
27. 1,4-dichlorobenzcne
IS. bis ( 2-ch loro~thvl) ethct·
12. hcxachloroeth.'.lne
42. bis(2-chloroi~~oronvl) cthc?:r
63. N-n i t!:"osod i-n-nro:,vlm~inc
56. nitrobenzcnc
52. hex~chlorobut~dier.e
.. 8. 1 2,4-trichlorobenzene
55. naohthalcne
43. ·bis ( 2-ch!or-oetho:~v) t:1ethane
54. isot>lioro:te
53. hcx.'.lchlorocycloncnt.'.ldiene
20. 2-chloronnohthalcn~
11. acenaohchvlenc
. 1. accn.'.lohthenc
71. di:::ethvl nhthal.'.lte
35. 2-4-dinitrotoluene:
36. 2 6~rlinitrotoluenc
'40. 4~chloroohcnvl oh.:!r.vl cth.ar
80. fluorene
10. di,!thYl t>hthaL:i.ce
37. l ~-diohenvlhYdr.'.lzinc ,,
62. N ni trosodio!i~nvlar.iineJJ
9. hcx~chlorc~enzcr.e
41. ·4-brOD']:Q~l nhcnvl
~ ,. ..... i-. ... .,. ... ~,
ether
1B. anthraccn~'
68. di-n-butvl ohthalate
39, !luo_ranthene•
84. evrene-
67. butyl benzvl nhthnlate 5 .. benzidine
66. bis(2-cthvlhexvl) nhthal.'"lte
76. chrvscnc ,.,
72. 1, 2-bcnznnthraccnc JI
28. 3.J'-dichloroben7.idinc
69. di-n octvl ohth:,.lnte
74. 3 4-hcn7.ofluor:mtl:o:!nC. 6/
75. 11,12 bcn:rnf luor.:in th€neL>/
73. 3 l.-bcnl:Oovrcnc
83. inrlcno (I 2 J-cd) ovrf!r.C
S2. 1 12 15 1 6-d i hen7..:int.h r.:i.cc:n.:
79. 1 1 12-henz□Pcrvlenc
24. 2-chloroohf!nol
57. 2-n it rophcno 1
65,'"I. r:hcnol (GC/:•lS)
3t,. 2. l.-J ir.1e thv l nit~nol
31. 2 t,-d ich lorop!1...:n? J
21. 2 ,, 6-tr j Ch lororh<~nol
22. e.:!.r:ichloro~ct;i crc~;ol
59. 2.4-1li:1itro~l1cn1,l
60. l (!..:.~!} n1 tro-o-c rc:::n l
64. r,c:: c :ich lo rn;)hcno l
58. l,-n it. ro:lhf!nO 1
:,\ -!\at :rn.:i.lyzcd.
J -[stii:1.:itcd v~1lu,i.
~r.or:n:::T
DATA f.Ei'Oan:~r. SHEET
EXTR,\CT.\lll.E ORG,\:;1c A~~:\LYSIS
PACE 2
EPA. SAD. RC::. IV
A then~;, CA 4/S0
Cl!Emsr E. IJ. Lo·• Jr. S.EC'D. 9-25 8QC0:1r1.·o. 11-6-8(
P-l"Sl:LTS 0:{ ovy \'1~l(:1!T r. \SIS ' .. . , ... .. " . . -~-soc 2<,62 I I f~L-Uu1.. Upper
cn<l o( Lake near
\Hllows. adj. to
D!!:l t.
'J-2)-80 @ 1015
t.:onccntration Conccrlcr.lt.ion ~...,nccncracion
ur./kg ug/kp, t.t<!_/k~ 34271 NA I':A NA J4uul .. ... . ..
)l..'i.J~ 10 ooou
34'..Jt,:1 10 ooou
3457'! 10 ooou
34276 10 ooou
34399 10 ooou
34286 10 ooou
34431 20 ooou
34l50 10 ooou
39705 10 ooou
Jl1554 1o·ooou ,
34445 10 OOOK1
;3':281 10 ooou
3'-!-_11 20 ooou
J~ ]~CJ 10 00011 ,
J:45~4 1n noon
1.'.a '0
"'4?n<> ,n nnnn
1.4"'' 10 ooou
.., 'r l l, 10 ooou
. 34629 10 ooou
34644 10 ooou
3!i384 10 ooou
34)3<1 10 ooou
34349 10 ooou
34436 10 ooou
39701 10 ooou
34639 10 ooou
34464
34223 · 1o·cooK . ..
~ 39112 10 ooou
30379 ·10 onoK
34472 10 OOOK
3:,295 10 ooon
39121 20 00011
30102 10 00011
34323
14529 ,o 00011 .. .. .. . -·-.. · ..
3li634 10.ooou
31i5q9 10 noon .
11,211 ' 'l!, '>!.,;. ,n nnn •• .. .. . .. C ., ..
1!.2'-n TO nnmr
v,1,nr. ' -1'1.5.5.2-. _l_O. nnn,.
J~ 511 10 ooou
3!.5};9 ·2 .ooou
Jt,S9li 2 ooou
3l.(,95 2 ooou
34(,0') 2 OOOK :_ I
)!; (,()!; 2 -ooou
.1!,(11!, 2 .090K-
141, "-'.; I 2 oooi: -+ 3,_0.2_ _!Q_ J:!QU l! -3:, r,r,n 2 (}(JQLJ ··-+ 1'!01,1 (, ,,,_){). I .. ]!, (,!, 9 ,, OilflU .. .:~--=r·:
!.:. Actu.:'.ll \'.J.luc i!; kn0·,.1n t.o be-lf!:;~ t.h:rn v.:iluc f,ivcn.
Chry:;...:n~ ;11Hi/0r 1, 2-b,;n; .. 11\th:-.l
J,:,-bcn::o( lu,icwth,!n..! .'.lnd/or
ll, 12-henzo[lu.11·;1nthcn<!. L -Actc.:il v,-iluc is kno\Jn to \.)...: grt•.1tcr th.111 value r,iv...:n.
~/-i-Litcd:11 t.•,:i.s an.:ilyzc<l for but not. detected. Tli.:: nu;:1bcr
--Tc,nt.::ith·e idc:1cific:1tion.
2/_~~n,!/ni· ~7nh~~~nn.•
is the :tini:rn::i D...:tcction Li □i.t.
, .... ,. ,..,,
I
I
I
I
I
I
I
I
I
D ----
------------I /
I.
I
I
I
I
I
I
PROJECT
SEDim::,;T
DAT,\ REPORTI::c Sl!EET
D:.TF..,\CTA~Li:: ORC,U.: lC ;1::,:ALYS IS
Kopncrs C.o~~l~n~c~-~------CllE:HST f W Loy. Jr.
t.FA. SAD. RCS'. T''
Athens. GA
REC'D. 9-25-S0
'I • orr10>q, .. ,c r:!':SUI.TS OS' n:::: ~~E!Gl:! !;i\SIS -Boe 2M>2 I S.-\D ~a.
ll-UDl Llpp<!r
STAT!O:-{ end of Lake: near SOURCE I, tJillm.,s, adj. to·
Delt.
DATE/Tl~!£ 9-23-80 Q 1015
COHPQU:,..1) Conccntr:ition ConcenCTation Concentratio:,,
u,;-,/k[' ur::./:u:.. u-./k,.
tetrachlorophenol .. (2..isomers) .. J:L ··---··-·-······ --.Z000K
hydroxy-r.iechoxy -benzalclehyde--.!'--..• 2000!<. -'
• . .
THE CHRO:-tATOGRAN INDICATED THE PRESE.."-:CE
OF t, f~IP,QJ,f:Utl I.Y£E PR~DUCT.
·-•
-
-
, .
No other or~:i.nic compounds dctcct<!d wir.:t an cl.;0tim3tcd minimum d~tection J lmit of .• 20,000
-J -E~ti1nated v,,lue.
K Aclunl va\uc is known to be less th.:1n v.,lu('; given.·
L -;.c;:u:11 v:iluc is known to Le greater th;m vnluc r,iv~u.
U -;,-:..it.t2.r!.al ,,_.as .:i:-:~lyzc<l for but not detected. The m1::1bcr is the !'!inir.iu=i Dclccti,on Lioi::.
!/_ Tentative i<lcntific~tion~
I
I
I
I
I
I
I
I
I
0
I
I
I
I
I
I
11
I
'. -IJ,".lEK
i-::•:"i :::.c·:·:. ::;_:: o:-:•.::,:; i.;.; ; ::A::1·:; i.:.. t.t ;1•..:11:•. c:. ,; / :-
l'i:OJ ::cr_~:_~>1,,,....: rs Cn., lnr:0._-__________ C!!E~!IST E. IJ. Loy, Jr. _y1:c'11._2:_l~~-CG:<:•i.'D. l~-
• }.l_Q.,:ri::vi l11·......._l;'~: ____ _
P;,t··· 1' ----------------~ ---·--------------~-"~=-==·,,---~--==="==~--!~
Co:::?0~111c!!: on i:r:.u:: List.: of l'rio~i ty
I'ol !.1:t:inti;
17. hi~(r,.J!lor0Ae:t!1..-l) ctliCr
(, l. ti-n i. t r,,sod i.::-:-th\' L1~1inc
25. 1, 2-d ic.h lon,Ue:i..-cnc
26. 1.3-,iichlorobem:'cne
27. l.',-dic:hlorol1i!n;:cnc
1S. bis(f--chloroct:l\'l) ether
12. l,C'!x.::i.chloroctb.::ine
47.. b:i~(2-r:hlo:..-oi:.opro:Jyl) cthP.r
63. r:-nit rosodi-n-oropy l.,r.ifoc
56. n i. t rohcnzcne:
52. hcx.?.chlorobutadicnc
8. 1 2.4-trichlorobcnzcnc
55. nn:.!, ch:'Llcnc
43. bi~(Z-chlorocthoxy) 1:1cth::in~ •
54. is0:ihorone
53. hc:-:.'.?.chlorocyclo;-ic117:it.l.ic:ne ·
20. L-chloron;iphth."llcnc
77. ta:~n.:tphthylcnc
1. acc-n.::ihthcnc
71. dir:tthyl ohthal;itc
311268
Jlil,:.iH
3C'!>J6
311566
34571
31,773
311396
)!1283
344:i.8
31,447
39702
3!+5Sl
3116%
1.l127o
141,0r!
1/+ J.S..6....
":If, .. s,
31,zon
1l ?Qi_
K'i:-0J0 S t.':d
Shop.
Couc<:nt:· .1.t ion
u:~/L
r-:A
·-
IOU
IOU
lOU
1011
lUU
lOU
20U'
!OU
JOU
lOU
lOU
1011
20U
_ _:_iou
lOU
J.Ql!
_1(111
lOU
Concc..:ntr::.tio:i.
·u;',/L
I,,\
'~
Co::cc,~tr.'.?.~ic
u::/1.
35. 2, l;-dini t rc-:c.,t~o~l~u~•~n~o~-------,----"'-''-'--'-l-c-"--42'-----1--,-----------l--'-----35. 2 16-dinitrl"ltokr.nc
,_uu_
":II(, 11 lOU
)!,62..5.... .lOU
]/1(,l;}
$0. fluorcne 311 ~:IRl
70. diethyl phthalatc
37. 1 2-diohcnvlhvrlrn:dnc l/
3!,J)6
34J!,6
62. N-nitrosodinhC'n"-'l:u~ine-'f 341,33
J9)00
31,636
311G 61
34220
lOU
I --='---1-----_-,·---
lUU
lOU
lOU
lOU ,-
JOU
lOU
10H
68. di-n-butyl ph th1J_€1ct~c~------~<'"'-"--+---"'-"-------l--------·--_.l---'-----39. fluoranthcne
·:,s9uo IOU
34376 lOU
'----+---'--=-""'------1--'------1------~yrcne ·· ··
61 ... _h_!1t·v1 bcnzyl pht:h<'l];,tc
3li/.!..69 lOU
3!1 29'1 lOU
5. -l,r.nzidine · · 39\20 20U
66. his(2-cthslhr:xvl) phthnln.te
76. chryscne /
39\00 ·1ou
31,:-iJ0 --·-. -
. -110.lii ' !OU·
. 14611 .. ·1uu
69. di-:-n-octyl phtk!_•'~.,~,•~---~'-=-----,---,--~<:c:/.!!_+---ccc---"~'-------,-J-~...,.,----,.,. ---.,...,-,--,·~·-,-·_·+,.,_:·',.,.~---
71,. 3,11-hen:,;o[luor:::1thcne §...~,-----~ ::--:. ____ -__ -· .. · · · ·
1!, ..... (, 100
Jl,J..llL --
'75. l l i..12-hc.nzo!:1 uo-:-.:ii1thcneo_. ·
"/3. 3.1.-b-:-nzopvrcne · · · ·
:,\ f'.-:>t ;}n:1Jyzccl.
.I -E·.ti.1.1.:itl:d v:1lut~.
">{.,,?l?
1'L'iiL
Jfd,QJ
l'1.'.i..'.i6-
-~!,.J.2.l._
J/1)?i(,
:H1~~?.l
. IOU
·1ou ·
-·1ou
· .· · ·10u ------JOU
JOU
10.11
K -J. ;,l!:11 v,,lt1o! i:.; know,, lo l;l'. le..::;;, t:l1:1n v:il,1o: r.iv(:n.
"
Cbq·~;•:n.:-. .111<l/nr l,2-h~•.i:-.. ,:~::
J, !,-f,..::: :~ll f _ll;~, :-.:,: t!,c•:h'. :•.11;.1./ ll
l l, 12-!,.::n:-.o ~ l.11.,c1.:~::!1.::nc..:.
I, -,\ct11:1l '\',1luC j_:; i:nowa to \,c j',r1';1tt:r Lh.111 v:1}.11,· 1:iv<:n. ~--'= i-!.;l'•..:ri."ll, v.:i!. ·:in,1l.Jz.::d for l,ul not ·<lctccl~·1\. '1'!11: nu::i!i.~r j;, th,~ lli11i::1u;.1 iJ,:t..:·c: it•n Li;:;i.t.
Tcnt:iti.vc idc:iti(jc.11.lon.
~~--~lnrl/or :17.0\,<•n;•.1:n,:: (rn·;-,:,, ··•:,:-,~:··.·. ·
I
I
I
I
I
I
I
I
n
··o -------------
D
m
m
I
•• ...... ~ .. -•··· ~
I
I
I
I
.: -WATER :-:·! i'..\C !;,;:t,_~ (l:{l:;,;; :;_: ; .. :;;,;_\·:_; iS
r;~oJZCT 1~01.:_i_H.:1·~ Co., Inc. r.11i-:~!t~·1~_L_l.:._~,> Jr-.
_rJ,:,_uf=-\·i tJ.s..J""----------
1:Ec':L_~-2::,<-;(1 cs:-::·!.':,. 11-':.
!',\GE 15
!:0_::Cc__::2_c_':_":____ __ J _______ ll
1'1-1·-300 rauc-2;t bl!
si<lc of Lewis
Hncrb~e rc5idcnc
----,--------------------+~=------<------~---,..------~1~-c-;_·i:,~~~-~ .. <= ......... w ______ .,,.,-=-==--!=.:2~3-1_;::.o_, ..... =----==--=----===--==-=··-t,,,. ___ =------~~
Co1:1;,.::iund::: on t,;RUC Li!;t of l'riority C~•.to::it.:r:\tiou Conc<.;ntr.1tio:"i I CQ:-:.c-. ..:~tt::,t':.o:!
l'oll1:t:rnt~ u::/L U!:/L l!C"~/~'---
17. hi~(chlon1metl!.}JJ ct·li~r 1:,\ --f-----,....-0•-~-.. ·~'---
,6~1~-c.....-l~i_-~n~i~t~t~·o~s~o~d~,~-~~--c~--~"~•LY~l~.,~m~i~n~o'----~-=~~+--~e'c~----t----'~•~•-------+----'~
)/1268
J•1•1:St:
M
25. l. 2-<l ich loroLcn :-;,:-nc
26. l. 3-ci.ichloroben;:cnc
21. l 4-dlcl1loro!1,:nzcnc
IS. bi.s(~-chloroctiwl} ether
12. hc:.::,,.chlorocth;:i.nc
42. bi.~(2-chlorobooronvl) ct1n~r
63. l!-nitrosodi-n-nrcin','l.:ir:!inc
56. nitroben.:l'nc
52. he>:.ichlnrc•~utadicne
8. l 2, 1,-trichlorcibenzcnc
55. nanltth~lc:nc
43. bi:.(2-chlo:-octhoxy) 1nethanc
54. i sophorone
53. hcx.:i.chloro;::yclo::>E!ntndicne
20. :l-chloronaohth.:ilcnc
77~ accnaohthylcne:
1. acenanh thcne:
71. dir.ie.:hyl ththalatc
35. 2. /1-dini t rotolucnc
36. Z1(,-clinitrotCllucnc
60. fluorcne
70. c!icthyl oht:hal.'.ltc
· 63. di-n-butvl ohthalate
34:>:Sb
34566
34571
Jl,273
311396
)!1283
3411 7.f,
3!,447
39702
34551
:V1696
1/1278
ll1l,Q~.
Jlil'lfL
11158)
J/1200
":lf;?f\<:
141!t.L.
"l/;f,''
J!(t:')t:
311641
Jl11Gl
343)~!._
34:V,6
341,33
·39100
3116%
31+.t.61
· 3/;220
39Jl0
. 311376
3M,69
"' lOU
!OU
!OU
lO!J
101.i
JOU
20U
!OU
}OU
lOU
10:T
1 OU.
20"
'-· lQU
1011 j --
1011 I
100
100
ClOU I --
lOU -
100
lOU
lOll
lOU
lOU
lOU
100
lOU
lOU
100
100
31,7.92 .. 39110 e6~7~·c....._b~u~t~y~lc,'b~c~n~z~lL' l"--'p~_ l~•~tl~-•~n-~l"n~t~"'--~~,---~-""--'-"-"--+~-~~'-------J--,-,------,-,------,,--,-~---,--f -,,----,------5. -bcm:idinc . . r· lOU
20U
(,6. bi!;(2-cthylhexyl) phth.ilat~ .... 3_9_100 . . . .. ], _______ _
76. chrysen<:? 5/ · · Jl,J20 ' ·1ou ..
'n.7,2-bcnz.:mthr,"lccne 5} · · 3{i'j26 . -100 . ' ·1ou
.• JOU ..
-1ou
·100 -
' ·1ou . . ·iou ..
l{HI
}01!
;,\ ..:. 11ot .--,;1:, 1.yu·d.
J -E:ait.1."\lC(! vah1~.
I~ -A-:.tu;1l v.1lu.:: i:; knu-.Jn to l,c le::;:-; 1'11:111 V,"ll11•: i-,iv,:n.
I. -!\~tual V.'.lluC i:; b10\:n to he ;:rP,"lU:r 1.h.111 v.11.l,~ f:i•1c.n.
~ -l·btcd . .'.'11_ va:; ·;:i.r.:ily:i-.e,I for. 1,ut not ·dc1.cctcd. Th,! m::::l,.:r i::
-1
1-Tc:nt.;iti·:•:~ i<lcntjfi.c.,tJon. ~ .-·:..,!"Id/,,,-_-,;-,,1,,.,,.,, .. ,.,, •.
Ch1·y,:~nc .,nJ/oc .1,2-l•a::::=.-::.::::
J, '• -l>!':n::n flc:1 r;1 nt l1a~::.::. .:i.;-.;J / t::"
11, l 2-!,r:1~ ,.a f h:..:,c· .,n ;-_1:-~n.:!.
I
I
I
I
I
I
I
I
I
I
I
I
I
I
-l;,,r::iz
Co;.1,)o,1r.:.!~ on NRDC Li.:;t of Pt"ior:ity
l'ollut:mts
l~hlchlonir:ii!thyl) ct.liCr
61. N-nitro:w<li.::c?thvla:'nin,:
25. 1. 2-dichlorol,en:z.cac
26. 1 1 '.J-tiichlocohem:cnc
27.
J 8.
12.
63.
56.
52.
8.
1,4-dich lorobc:17.cne
his(2-chlorocthyl) ether
hc:-:~Ch lo roe th:10c
bi~ (:!-<::hlo:-oh::..,·1:.'.'0')V l) ct.leer
~ nitrosodi-n-rorou\·l.:u:iinc
nicrobcnzcne
hcx.1chlorohutacliene
l 2. "-trichlnro!,cn:::cnc
n:mhthalcne
-_··".\:·: '' l;::,;:;,:-.:;,,; ;,:;.:,!.;':;;"_.'.
31.~(,fi
J411.H_';
j~J)o
)4566
Jt,571
3!.27)
34396
3!.7.R3
3!.42$
341,47
3970>
J.'i!J5_1,_
J!,6~?
r...1;-020 i'2 !,'ell,
1:1::iin la::iinatin::;
?le..!~. l:it faucet.
Concentration
u~/L
t:A
"·' lOLi
lOU
JUU
li.JU
lOU
lOU
· 2011
lOU
JOU
lOU
10tl
fo\ ,.,
.'; / .-: .
11 • -:
Coac.::;-'.tr~:tio:
ll;:!./L
31,2-;~ , n;1 0. bis(>-chloroe.thosy) T.>ethonc j"
1M•Q3. 20U
VJ~'-___}OH
• .,54,..c----;i_s_oo~h7o7ro_n~•...,,...,---::~,.,.-,---,--==:--t--~~---i--------;l_-----
53. h.:•:--.::1chloroc>•clopcntatlicnc
20. 2·-chloronnpht!vilcne
~ ~ ~l,:t p h th yl en i!
1. i!C<:'mmhthcne
71. di:r::cthyl ohth:11:!te
35. 2 1 i,-dinitrotolut::nc
35. 2,6-dinitrotolucnc
t,(J. 4-chloro2hcnyl phenvl ct!icr ·
80. fluorcnc
1G'ill__
·v,'lnr\
"'""
V1Jf•1
Jt.(,11
3t.,;1i:.
:V16lil
311381
Jl,336-
Jl,J!1(,
3fil,33
3"9700
3H,J6
J/1/161
1011
mu
1011
JOU
1OU
!OU
lOU
lOU
·JOI("•
lUU.
lOU
]OU
lOU
3421.0 lOU
39110 lOU. 68. di-n-butyl ph thalatc ~f--c----;'~,-----t----,-----c-c-+-------
39. fluoranthcne 34))6 ]Ol.!
84. nvrcne J_~.';69 JOU
67 •. butyl hen2.yl phthab::c J/,~92 JOU
5. -ben7.idinc 39110 20ll
66. hi5(2-eth5lhc;..--.·l) nhth:iln.te · .. 19100 ·1ou
'.\/1320
-v.•:."'l(, lOU
76. chryscnc /
72. 1. 2-b~nzanthr,"!.ccnc J/ ·
28. 3,3'-die.hlornbcnzidinr. · '.).illl ··10u
Jt.'l()6 lOU
J.'!2.JJL
J!· ?/1? lCll
1112'1.L_ ·1ou
1!:.!d!J_ ·1ou
1! <: <:l:. ·1011 2.~..1 1 12-h(~nzopcry] cne v),;n ]OU
21 •• ~-chlorophP.1101 Jl1)f:(, l(JU
57. J.-nitrophenol ·~~_!_~1_1 _ ____ 1nu
65,,. t•hcnol (GC/MS) )!.:VJ', }Oll
;,\ 1:0;: :-in:1 ly:•.c:,1.
J -Esti1:i:1tcd v.1luc.
K Actual v:1luc i~ kno·~•n to lie J.1::;s 1'11:,a v:11110: r,ivc:n.
L Ac:tu:il v:1l\1C i~ !;noun to In:: [:l'(:;1t(:!.' Lh.111 \.';-d,l:C !:iv,:;n.
U -iL:in.:ri:.il. 11.1::; ·,1n:tl);,._,.:.i for t,ut no:. ·<.!c.:lc<.tl·<i. Th,: 1H:i:1J,:r j:; 11 ·r · 1• ·r· , -1-_. cnt:.1t:1-vc (.cnl1-1.c.11: on. ~ _..:. ;,r,,.J /nr :,7,,h:•n··,·,.,. ·
• .. -..., _.
~'-Cbry:;(:11'.! :i':l~/t•r: 1, 2-b:.c:--::-.. ::--:t
f!_/ _ J,l,-\,,•;1:-.o{h:,,:·.•.alh....::h~ :-:n,'./~1
ll, 12-1,;:n;:o [ h:0 ~-;1n :...hen,:;.
..... i .
I
I
I
I
I
I
I
I
n
.D-
I
D
I
I
I
I
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I
I
P,\CE 11 ---:=:..~---·· ... ----------------------------= -------··--·----~·------------------
~,.~,,,.:1•_.c,N0:.:_ •• _____________________ +..:"c:"'.::'C:c·="2c::cl'7O ---f---------.;f _____ _
Kl{-UO!, E;1~t
S0l1~:CE l, STATJ.0): ditch run~f'f
from u.idcr RR
tr.:lck.s.
~,1?/TJ~L_-------==--~-.....,_-_9-23-8~3 _171_~.,.-=--==-----·==·~------
Co::i?mrn~s on l.:RDC .Li~t of Priority Concl':at::·.1.cion Com.:-:.::1c,,r::tiou Corn.:{;ntt·.1.tiot
,1~•o~l~l~u=t-~a~n~t~s'--------------------+---"~C~-~/=L'-----+----'°":,--._/_L _________ u_r:L!:.__
17. h b ( r.h lo n-imethvl) c-t·liC r 311 2 6 8:;....+--__ ....:;t:~A'-------+-----~"~A,___ ___ ---1---~•~! t~, __ _
fi·1. ~-ni tn,~o<lir.:t?thyL:tminc )(Go )L"L----+----' •.·-~··------1----C'S:"'
25. 1 1 2-tlic!,lorohcn~.::n~ Jffi1J JOU '-
2(,. 1 3-riic!d<•ro1,~n::cnC' 34565 lllll
21. 1 .l,-<!i.cltl.ircLeu;:cnc 34~71 IOU
Hi. hi~{2-~ilT.lro¢thvl) ct.hf':l" 34273 IOU
l,2. bis(2-chlornisonrn'">vl) t!th<::r 31,/..fi) lOU
63. N-nitro~odi-n-nn;•-·•1.-..mbte Jf142S ZOU
.,5~6~-,___~c~, •~-~t~r~o~b~c~••~'-~c~n~c'-----,-,----------,------'33~4~1,~1,~7:---lf-----·'J~O~U,___ ____ 1 __ .,..... ______ I_ ______ _
52. hc:xachlorobu~.J.dicne 39702 iou
lOU
!OU
JOU
70. diethyl phthalate 3.!!336
3'/. l 2-c~ip!1cnylhydr.-..zi11!: 27 34)!16
62. · ?~-ni.trn~odiohc11vl:'l.min,·J/ 3M;)]
lOU
!OU
1ou·
I
9. hi:~:;,.chloro?>l':n::enr:. ·39·;0:J JOU
lOU
' lOU
/,1. ·l,~h1.·~:l":O:Phcny? phenyl ether J!1&]6
81. nhcn::\.llffirJ.:..."'t!! ~J · · J!!!±L ..
18. :i.nthr;,cc:tH·.Y ~,,4~2~.2~0'---!---~---"'"-"----+---------1-·-·_· ____ ·•_•· ' GB. Li-ri-butvl phth.:!latc 39110 IOU
39. fluoraath~ne ·--·-· · Jl;J76 ··10K.
;A 1:oc :m.tl.}'z.:;1I.
.I l::;tit:,:-itt:<l v:1luc.
K -/1.cLu:.11 v:1lu.:: i:; l:11,1;..,n to l,c ](•.;.;s r.h.,n v:du,: 1:i"cn.
I. -/,Citu:,l v,,luc: i:-; b1m:n 1:0 1,c r.1·<·:1tc:1· tlt:,n \';11.11~ J;i'h"'.n.
Ch;-y::cnc .,1u~/(•l· 1, ~-'.,...::1::.--:1·,.::
) , !, -h.:,:zof 1 t:P r:111t::...::h~ .""11::l/ u{
J.J., 12-t,.-.:n::o~ l.\1<)t";1n:.hc1<...-.
I
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P!~llJ ~Ci !,;0p;,;; n: C". , I ::c.
-l.',\TER t:.;i.-;::.i..: ~·;,~;: o:~c;,:;,: ~ ,-,;:.;~_:;:.: i:..;
C.11£:~lST F .. l:. I.av Jr. __,::.:.,.::.!:.lli~k_._ 1~"~: __________ _ -.------------···----··----------------•-•--= = S'l1 •·1 ~>C 2t,°71 c· "''"-·~·~·•~-~--------------------+"c'c\;-_o
10 :-:.:iin
office well,
faucet in kitc:.liet
9-23-60 i! 1615
PACI:: 12
11,\Tf./T!.:•1~'. :..,...-~--=-=---------=~~---=~~~--==---~-~-=~~--=f=a-,=====··.:--:,-'"'~ .,_,_,....,._-=-~
Co;;i;,o:.,n:..!~ on ::r:.1.>c Li!;t of l'riori_,ty Coaccntr.'.ltion Conccntrati"~\ Conccntr:: _l'~o~l~I~u_,,.'_.o_t_s _________ :-------cco-,:=c-lr----"~~~.f_I_. ____ +---'-'•~'~/~I.-----t---".u:'!.}~ 17. hi~(c:hlor(lr.i~thyl} ctli;'!r Jfi~68 NA ?IA t!A
IOU
l0li 27. 1.4-<lichloroh,"?07.e:nc 34571. · 101.: 13. h!~(2-chloroeth•:1) ether 34273 JOU
lCJC t,2. bis(2-chloroi~o.,ronvl) ctht!r. JG283 IOU
2ou· 56. uitrobcnzcn~ 341,47 101; 52. l,c:rnchlorobut~diene 39702 IOU 8.-1 1 2 ,l,-trichloroh.'.!r.zcne. 34551 JOU
IOU G3. bi:,.(2-chloroctlroxy) -methane 3t1278 JOU
2n~
101! ,au
,n'
IOii
lUU
"lOU
lOU
lOU
lOU
lOtl
lOU
lOU
IOU
lOU
' lOU 68. di-n-hutyl phthalatc 39110 lOU
IOU
·1ou
10!1
:wu
·iou
.. lOU
·1ou
IOU
JOU
·1ou · ..
·1.ou
·iuu
H1tr· --J.OU
10ll
.1011
lOU
;_\ -1),:-,t :1n."Ilyz,~d.
J -E~ti.:::;\lc:d v:d.u,.:..
i:::: l:n(1:..rn to h<'" 11:::~ th:1n v:1111,~ r.iv,:11. " I. to l,o..: i:r1•<1.1..:c.:r tl:.111 v,:]1:c: J~i.v~a. for !,11[ not ·,!t·lcct:.:d. T!,,: n1;:-:1~h·~
·-·
.•
··---
C!try::ent.: :11:t!/nr 1,/.-'.· ;1::,1:,::
J, !1 -1,~~n::o: ll?c' :. 111 th,..;n,--:: .:, 1Hl/ o 11, 12-1,.;n ::n [ l.l:" c.,atl tt:nc.
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-~.',\TEI: :-.·,1. -:·:·;:;,..;:·,\;;;_:: ~;:~<;;,;;~._; ;,;~_-.:_y:.;1:; l\ti1-~:,::. (.;,\ ,,;.'.J l'iUU'.-:CT Koi'\'Cr~ CC>., Inc_.______ Cl!E'.·!I~;-r E. \!. L~~:___liEC'f1. 9-25-RO CO:·li"l.'D.~ _}b ;.:r.!~.ti..!..!i:,S 0~C~----------
P,\GC 9 ·-----~~ ......... r-...........-------_.,_,,_---------;-=----~------------------. ~---··---S,\U ~;;,1_ euc 2tius I l'i,•-~ou l~dl at
Wilkerson
Cnntr~ictinr, Co.
nAn:trrn~ 9 23-S0 iJ 1)45 .=-..:,1 ......... -._-.-,;=.,,,.._,.,._ ___ ----=------=·~·=-=--~·-··-4--···=·~-===~--"'"'===---=-=·-=::.... .... =====~ Co;;ipot1::C$ Oll NRIJ(: List of I'docity Co11ccnt: .... tion l'oll.u::~nts u~/L ·,
17. b:L·:fchlorC':;ieth·;l) er-liC.r
61. ll-nitrc•~odir::::thyl.,:uinc
25. 1. 2-dich lorolit..:11zcne
26. 1. 3-d ich lo1·0J.,en..-:c11c
27. 1 • .:.-dich lorobcn7.c1\c
1S. bis ( 2-chloroct.hv l) cth,·r
12. Jic:..::i.c-hloroct.h.inc
li2. bis(2-chl0roisooroLJ\"l) l:th<!r
63. r-:-nitrosodi-n-prC1pylami~'.!
52. hcJ-:,"'\chlorobut:idicne
3!1268
J<.~:so
34>3u l0U
Jli~66 1ou
)(1571 1ou
]!1273 l0U
343% l0U
3',283 1ou
3!;42S 2ou·-
34447 JOL:
39702 1011
Cor:ccucr.:itio;1
ur:/I.
llh ...
..
Conc;cntr.:i.tio;-:
u;-./J.
.,
---·-
IOU
IOU
34551
1Mi9&
8. l. 2 .t,-crtc~h~l~o~r~o~b~c~n~•~c~o~•~-----7'-';c'o--t---~~~-----t----------+--------55. r:."'!Oh th:~lcne
~~l,-is(2-c:hloro-:?tho:~y) ncthanc. 54: iso;,horons
53. hcxachlorocvclo::ient.i<licne:
20. 2-chloro:i.:!.phthnlcn~
1. ~ccnaohthcne · · 71.. dirr.cthyl ohthalatc K~ l,-dinitrotoluc1~c
36. ?,6-cli.nitrotoluene
-40. -4-chloro!)hcnvJ. uh:::nvl. ct~1-:!'l.." · 80. fluorcnl?
70. · diethyl ohthal:'!.tc
3"/. l 2-dipht:nvlh-.·dr:i.zinc ±1
68. c!i-n-butyl p!1thal:ttc
84. pyrcnc
67 •. hutyl hcnz.yl phth:i1:i.~:c
~-.. bc:i.r.idine
66. hi::;(2-cth511t~>:,.,l) nhth:i.latc' 76. chrysc~'! /
72. I 2-h~nz,mthraccn-.! 51
t!ot .,n:, 1 yz,·d.
J -E:;li::;:1!.YJ 1,·:,lw.!.
..
31~21r. lOt.:
1,f.!,r.'3 2011
1fi1.~0 1011
14",:;1 lClU
J/1..2..QCL 1 011
y,;>n<:. l0U
JfiliL 1ou
3M•'' -iou
1.(,(, -,r:, l0U
JMil,l l0U
31,381 IOU
3!,336 !OU
3!1 31, (, l0U
341,33 lOll
·39700 101.J
J/16% 1ou
'3f+l,6l
.'.\/1220 JOO
39110 JOU
'.V1376 100
311?69 ·1ou.
3',292 !OU
39120 20U
39100 ·1ou
3liJ20 ... -1!,'>?.6 lOU
l!&.JL lOU
•1f1 <:.0(1 lOU
,t17Jn
J!,?/,7
. <l!.]..!,~7
3',/1!"':
K -/,ctu:il v:1lu.:.: i:: bun,n to L,c le:;:; th:,11 v.:I.1:-~ 1:i.vc11. I. Actu:11 Vd~t:•~ is l:11,:iun t:o lw r,r.:-at:c~r t:11:w \•,1l1~1: 1:iv,:11. v,-i:.;1c:ri.:d. 11:1:; -,,n;d.):z,:,l for h:.:.:: n,,t <1cu:.::L....:d. Tl1,: 1w;·1~<'.l 7-1-'fc_:nt:;1ti·.·,:>_ iCc.it:i(ic:,tlon.
,, ~1n.t/r,r .'.lzulic:n:•_,"!n....::
.
.
--
C.h ry::l·n,:'. .111,I/ n r l, =~-. :,c:n:·.:1r: c:~ r.:,
) , !,-1,l~n:c:o [ ll:o r:1nt. li.::11,~ ;int!/ l' ~·
J l, 12-l.•c..:11::of h:or:,n tlicnc:.
Hi.ni;:1111:1 D:..:t:c:cti.011 J.!nii.:::.
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l'?,OJECT K0pp~rs Co., Inc.
_Jj_Q_ l'iS\•il lr. NC:
.
S.\U :,;;l).
SOURCE • ST/,TIO~I
DA TE /T 1:-1 F.:
..
--
. ; ~ ~ :-. -..
u:;:·.\ ~~Z?U;'(!"C.~ ::;!::::::·:
EATi:..\CT,\r;LS O:lG/.:; lC ;,:,;_.;:.,y;:.: LS
S!iE~:rsr F.. u. Le,·. Jr.
. -. .. ·----=-=-:::...._--=-c
HOC 2467
£'>,'-Ulll, \..'dl fro;,
;,:c<l.lin ~!obilc
hone.
9:-23-60 Q 1.315 . --
P,\CE 8
E:•,\, :-;,:1. :-:c::.
At!icns, CA :,/0
REC'D. 9-25-80 CO~'.i'L'D. ll-i
.. -Cornpounc!s on NRDC List of Priority t.:onccntration Conccnc.r.:i.tion Concent::.:itio
Pollutnnts t.:~/L
17. his( chlo:"C\~cth•:11 <-:tliCr 34263 r:A
61. N-n i trosod i.;::~ th·: 1 nm i. r:e J44j;:,i ...
25. l,Z-dichlorobenzene ~~~36 lOU
26. 1.3 ciich.lorobt!r:zcnc 34566 lOU
27. 1. 4-dich lo ro~e:n zi!ne. 34571 lOU
18. bis (2-chloroethvl) ether 34273 JOU
12. hcx.::ichlorocth.:me 34396 lOU
42. bis ( 2-chloroi~o;, i·o•lvl) ether 34283 lOU
63. N-n i tros.odi-n-11::-onv l.:i;:,.i.ne 3442S · 20U
56. ,nit roben::-:;cne 34447 lOU 52. hcxn ch lorobu ::ad i•.~ ne 39702 IOU
6. l 2. 4-trichlorobE:nzene 34551 101)
55. n::irihthalcne . 1./1696 IOU 43. bis! 2-chloroe thoxy) 'met Itani:: ,.,,ns ,ou
54. iso;i:,{1r6ne 1,.41,.rv, 20U 53. hexachlorocvclo~entadien~ "14 .. .,,,, ,nir
20. 2-chlorona:ihthalcnc J4<;!H 1ou 77. acenauhthvlene ·14?/\(' ,011
l. acenaohthene 3G",.,_" ,au
71. dimethyl ohtlrn.latc "l/, ]f,] IOU
35. 2.4-dinitrotolcene ...,t. (,,,, ·10u
36. 2 6-dinitrotolucne v,t....,,,, lOU
40. 4-chloroohe.nvl nhenvl cLher · J/1541 !OU
BO. fluorcne 3!1381. !OU
70. dieth):l {!hthalate _}_!,336 IOU
37. 1 J 2-diohe.nylhfd razine 2/ __ ;i/1]!16 !OU
62. t:-n it rosodiohenv lcn.,ine J] 341133 lOU
9 .. heX.'.!.Ch lo ro!,cn zen~ "39/00 lOU 1,1. ·t.-br~moehenyl ehenyl ether· 34636 IOU
81. nh .. ·o,mtbp•z5'i/ 3"461 I 78. 34220 IOU anthraccne
68. di-n butvl nhth,"ll:ite 39110 lOU
39. flu"or.:mthene ~!i]/6 lOU
64. nvrcne ]446? lOU 67 •. butyl benzvl Ehthalate J/1292 101.; .•. 5.-bcnzitline .. 39120 20(1
66. bis(2-eth?)lhexyl) phthnlat.e · ]9100. ·1ou •-.
. . 76. chrvsene 7 · · · 34320
72. l 2-benzanthracene ::>I · .. .. ~t," ...,t'. lOU
28. 3 1 3'-dichlorobenzidine · J:l16JJ "lOli
69. di-n-octvl nhthalate .. 14'% lUU
74. 3 4-benzoflt.:orn.nthcne E._1 "1!, '> i:r,
11 112-benzo fluo-ranthcn£'2._/ · 75. ]!,?!,? . lOU
73. 3 i 4-b~nzoevrcne 1/1'):1Z. ·1ou ·
83. indeno (1 2.J-cd) rivrcne 1./tfi ...... ·1ou
82 ~ S. 6-d ibenzan th r,,ccne 1./, <;,. ~ 'JOU
79. 1,12-\Jenzoperv](!nc. 1:1.32..L. 1 lOU
21 •• 2-chloroJ:!hcnol JI!'.:% lOU
5 7. 2-nitronhenol Vi5'!J lOU
65.,. ~hcnol (GC/ClS) .)!,f,91, l~l_i.!
]/1. 2 1 l,-<l j !!!<::thy l J:!hcno 1 1-',(,0(, FllJ
~1 1,-c!idtlorophcnol )l,(.OJ !Ol.i 21. 2 I, 6-t ri.ch lon:nhcno 1 3!,_(,'.."l !JJU
.33...:.-1,,"l r:1ch lo rom.:: r:.-: .. <: :·(: ::o 1 ]j:'0? l:iU
59. 2 1,-d in i trorh~·:_:_:d J.',6"!.(, I f;(1:J
1_!,65.LJ __ GO. ,, G-d in i r~·rJ-t:-c r•·::o 1 JOU . .. -------!!.__~._r.'!11"t:1~1l.!,,, .-:,!:,;no! :1'.)(~J]_j IOI!
-. , ' ( " 2Uu
;,\ liOt :1n.1l.y:'.,~d.
J -Esti:::.::itctl \'.'.l.luc.
Actu3l v.1hi.~ is kno·.,n ro be lcs:~ tl•:•:1 \·:1lur: ~iv.:o.
1,ctual v.1lu<! is l:no,~n to l,c 1:rr.;1te::-:~1:011 ·::d.11<~ f,iv,:;n.
it:itcrial. 1,.1,::i~ ·,,n.:"ll.y7.(!d fc,r l,11t 11ot ·<'.~•:<.<.ts:;~. Tl"~ 11u::1l>1:::-is
Tcnt.,tive 1~r:ntiflr:.11:fnn.
. .
-
ur,/L Uf',/L
?::\ t:A, ... '"'--
·----·-
--· .
.. -. ·-·
..... ..
..
.. .. ' ' .. .. •· .. . . . . .
•.• ... .. . .. . ··•,··· . .
. .. ;
' --.
··--·· -
-
···-·1 ··-,--·
-··· .--, ..•.
.J
C!1l·r,:cne .,nJ/ur 1, 2-Lc-.n::.'.!.:1t
J, !, -J,,::n ::u f luu r:1 nl h.::nc :.i:-.J/ ;:-:
11, 12-h:..:u:.:u r l.uor .tn thcnc..
I
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I
I
I
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iJ_\·:·.\ ~:::::·:;;.:::T.1: :.;~;:::::r
E:.;:1;:,\CT,\l:LS OitG,\:-; lC ,\~:ALYS IS
PAGE l.
!-:~ ,\. :~:.:.i, 2c::.
/I.then!., GA 11/S'.J
PROJSCT Kopper~ Co., Inc. CJiellST E. IL Loy. Jr. RF.C'D. 9-25-SQ:o~!i'L'O. 11-6-t
---.::!ncri...:..:..ci.J.lJ,c.--J>i!:_ ________ _
--
SAD ::11. i:-nc: 21.r,4
PL-002 Pond be-
SOURCE [, STATIO~ hind Medlin
home.
~T!:.'71:·IE 9-23 80 Q 1115
Cor.ipounc!s on NitDC List o( Priority ·. Concentration
Pollut.:ints ur,/L
17. bis { ch lorc,meth•:l' echCr 34268 NA
61. N ni tro!-od i::i~thvl.ir.ii nc 144)8 ..
25. l 2-dichlorobcn:::.cm: )453b lOU
26. l 3-dichloro~enzcne 3l.5()(, lOU
27. 1./4-dichlorohen;.cnc 34571 lOU
18. bis { 2.-chlorocthvl) ether 34273 lOU
12. hc::--achloroeth,,ne 3!,396 lOU
42. bis ( 2-ch loroisonroovl) ether 34283 lOU
63. r-:-nitrosorli-n-oroovla!'!1i:i.<:! 34428 20U
56. uitrobcnz.ene 34447 lOU
52. hcxac~loro~ut~dicr.~ 39702 lOU
8. l 2,4-trichlorob<:!nz.cne 34551 lOU
55. nariht.h.:ilcne 34695 ·1ou
43. bisf2-chlorocthoxv' neth:i.ne '4'78 lOU
54: isoohorone j44Q3 20U
53. hcxachloroc,·clooent.:idicne '''"' lOU
20. 2-chloron:i.ohthalcne . ... "i8' 1ou
77. accna~hthvlcne J/1 ---!OU
l. accnanhthcne '''"' ·1ou
71. dimcthvl nhthaiatc 'll,, 'l{,, IOU·
35. 2 14-dinitrotolucne 311. ~ • lOU
36. 2,6-dinitrotoluenc 'l.!.,.'"'?k lOU
40_ li-chloronhcnvl nh<?nvl -ether· 34641 lOU so.-fluorcn<> 34381 1ou
70. Cicthvl Phthalate 311336 lOl!
37. l 2-dinhcnvlhydrazine LI 34346 lOU
62. r:-n it ro!:od i :e hcnv I.1.mine J/ 3M133 lOU
9. he:<::1<;.h Iorohcnzcnc . 39700 lOU
41. ·li-bro.nonhen"l nhen•.11 cth~r· 34636 !OU
81. ' .:-;, '•I 34461
78. anthraccne-_~/ 34220 lOU
68. di-n-butvl. nhthalat.e 39110 lOU
39. fluoranthcne 34376 lOU
84. EYrcne 34469 lOU
67. butvl benzvl nht~.:ilate 34292 lOU -5 ... be'i1zidinc 39120 20U
66. bis (2-cthvlhex•tI) nhtha l:!.te 39100 lOU
76_ chrvsene ':>I 34320 -72. l 2-benzanthr:u:cne ':>I · '\/,<;.2f.. lOU · ..
28. 3 3' -dichlorobenzidine 'l.!,6'11 lOU
69. di-n-octvl eh th.:i Iate j4~96 lOU
74. J ,, h<:nzo flue ran th•.mc l,7 . 'l.[,?..,"
75. llzl2-bcnzofluo-:;-:i.nthcne"1 · 3!, -• --JOU
73. 3 li-bcn7.onvrcn"' • "1./, ?I, 1 ·1ou
83. in<leno (1,2,3-cd) P}'.rcn"" ·1~J-fl'l lOU
82. l 2 5 6-<l i Lcn;::i.nth r.:lcenc '•!<;er, lOU
79. 11 12-henzoncrrlcnc 1!;~ IOU.
24. 2-chiurophcnnl V1S86 lOU
57. 2-nitro•ihr.noI 34S91 lOU
65.i.. ubcnol (CC/MS) 3469!1 1.0U
Jt,. 2, !1-<lir::c:thvl nhcno 1 ]!1(,0IJ JOU
Jl. 2, t,-clic:hl orophcno_l. )!,{,Ol 1.0U -21... 2 ,, G trichloro.--,lic:no 1 )!iG:J:l IOU
1_~---P·ir:u:11 I oro;;ict:t cr0.:;ol )!,!, 'i 2 IOU
~ 4-dini trnpl:r:r-101 3:,e~ _ _t_§_ HOll
60. !, • 6 <linirro 0 \.l'0.SO J _,1_.:,_~~1.7 __ lOU
64. p(:1~t:tch Io ro11h1~nn I _____ )JUl~ JOU
5e. 1,-n it ro..,h.::noI :V,£1!1(, 20i.:
;,\ -1:nc .,n.-:ilyzctl.
J -!::.ci::1.:i.tcd v:i.luc.
K -/,ctu.1.l v.1ll•~ i:. kno'-'n t:o be le:;:; th.,n v:1111._. r,iv~n.
L -l,ctu:11 v.:iluC is kno1J11 to h,~ r;n~.1:,:::: th:111 v:1l11c r,iv.::n:
y_1-_ i-L~teri:il vas ·:111:11j,-.cd for l,11t not J,:tcctcd. Th(: m1r.1~H!r i.~
'!.I_· :~~;::i~~}~cntific.,tioa.
-=-=·-
Conccncratio:1 Conccntra:.iun
up,/L uc./1.
NA NA ., .,
'
--
-..
-
..
.. ' -. --.. .. ~ ... --... ...
..
... ... .. .
. t·· ... .. • •·· . ... .,
-
·-
·-' -·
·--·· ---.
-···
-··--·
···•··--L
Chr:,·:;c:n:• :1nJ/ or 1, 2-!h·TJ ;,;.1.:1 ::'.:
3, l,-h.::'.:· o ( luvr;H'.C.~,:;n,:; .1.n::./ 0 ;-
11, 12-h...:11:·.,1 ( lu.01·:.ia t \i._,:,,:,.
the 1-:inL-:lt::-:i J:.:tcct.ion Lir.1i.t..
••
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PROJECT Koppc.rs Co .• Inc.
Morrisville ~.:c
---
S,\O l\O.
SOURCS & STATION'
D,\TE/TI~!E
Corapour:.ds on trn.nc List of Priority
Pollut:mts
17. bi5{chlor~raethvl) ether
61. N-ni t ro~o<l i ~<? th,· 1:na inc
25. 1 2-dichlorobenzcne
26. 1. 3-ciichlorob~nzcn-~
27. 1.4-dichlorohenzcne
18. bis(2-chloroethvl) ether
12. he:wchloroe thane
lr.2. bis (2-chloroisonro:>vl) ether
63. N-n i tro~od i-n-e ro;r: lm:tine
56. nitrobenz(::nt!
52. hcxachlorobutadicne
6. 1. 2. 4-crichl orobenzene
55. nanhthalcne.
43. bis(2-chlo~oethoxv) metha:ie
54. isoohorone
53. hex~chlorocvclooentadicne
20. 2-chloronanhthalcne
77. acenaphthvien<?
l. acen:mhthene
71. di~ethyl ohthalatc
35. 2 24-dinitrotoluenc
36. 2.6-dinitrotoluene
40. 1.-chloroohcmvl nhenvl ,ethi:!r ..
60. flt!orene
10, diP.thVl ohthalate
37. 1 2-dinhenvlhVdra.zine !J
62. N-ni trosod i2henv I amine J.!
9. hexachlorobenzcn~
/11. ··4-br6monhe0vl nhcnvl ether
81. ub--n;-ntbrc2r4"' 78. anthracene:
68. di-n-butvl phthalate
39. fluoranthene
84. T,"rct\e
67. butvl benzvl nhthnlace·
5." be.i.zidine -.
66. bi.s:(2-ethvlhexvl) ohthalate
76. chrvsene :!...,
72. 1 1 2-benzanthr.:~c.ne .,, ·
28. 3 3'-dichlo~y~~nzi~ine·
69. di-n-octvl t>hthalate
74, 3.11-benzofluornnthene !'I
75. 11 12-benzo ~1 uo-r.,.nchcncb/ ·
73. 3 /i-benzonvrenc
83. incleno (1,2,3 cd) pyrcr.e
82. 1 2,5,6 dibcn z.:m th r:iccne .
79. 1 1 12-benzopcry]cne
24. 2-chloroohenol
57. 2-nitronhcnol
65.:i. r-hcnol (GG/MS)
JI;. 2,l,-dinicthvl~hcnol ·
31. 2 ,. dichloronh~nol
21. 2. 4. 6-t ri c"}i 1 oron!a•no 1
22. o.? r:1ch lorrn::e ta crcsol
59. 2 1,-rl ini. t ronhcno l
60. ,. 6-dinitr~-o-cr<!~Q]
64. nc:11t:ich lo ro'lhc:nn l
58. t.-ni.trnnh<!nol
·;:\ -Kot :\U:ilyzc<l.
J -Estic:itcd value.
llATU~
. DAT.\ R!::rO:<TJ:,;c sm:r:T
l::X.Tt'..,\CT,\!.\LE O!<GA:ac A:;A!..YSIS
C:l!E:1IST r.. \,'. Loy, Jr.
-----60C 2!161
KL-001-upper
end of Lake ne:.ir
,n11ows, adj. co
Delt.
9-2)-80 i! 1015 ·=
p;..cc 1
E:•,\, :~,\:1. :-c.: L'
Ath..::n5, C,\ 1./SJ
REC'D. 9-25-S0cCJ:1P!.'n. 11-5-~
--'" I
-t:onccntr.:i.tion Cor.ce:ntr.'.ltion Co:1-:.c:it.r.:i.tivn
u~/L ur./L t.:i'.:/L
34268 NA t<A NA
J<i-.JO ... ,•~ . . .J,.::iJo •n•
34566 '0"
30571 ,on
3,273 1ou
343::.J,S '0"
34:~83 lOU
34l12o 20U I
J!.447 1ou·
39702 lOU
34551 lOU
346% lOU
14278 ,.ou
1440R 2o·u
it.-,oi:: IOU .-
1[i "" l lOU
''H.')nn 10U
.. it.?tH IOU
):L)Gl lOU
3:{.'-11 ·10u
'l;!,/:,.?~ lOU
Jl,641 lOli
34361 IOU
34336 IOU
343!,6 IOU
34433 lOU
39700 IOU
34636 lOU
J/1461
34220 IOU .. .... •. ·-
39110 lOU
31.376 lOU
34469 IOU
34292 IOU_ . . 3s120 20U .....
39100 ·1ou .. . .
34120 .. .. -.. ' 1!, .. 26 . -IOU· ·--.. ·~ . -·---
145,1 · · ·1ou ....
"Ht;C6 lOU ' 1/,.?.,,., .. . .
lOU =-•• -·· ":II ?I,_'} , . •··. -.. ..
. ,,,., .. ., . · ·10u . .
1!,1 n, .. ·10u
'l.{ <;t: r ·10u
]/1~?1 IOU
J,586 lOU
3!;)91 IOU -3!;69!; IOU • )!, uou JOU
V,&Ol JOU I ---).'.(,21 IUU
3.4!, 52 JOU -).'.(,](, sou -··--3.~(,;J7 lUlJ i ___ .. ,. ···-:v:wn ]Un ·-J ----JI,(,!,(, ✓.OU
K -Actual Villu~ is knoun to be. lc:;s th.in v.,lu._• r.iv.::n.
~/_ Chc;·scnc od/nc 1.2-beocact,,c
f!../ _ J,l1-bcn:::oflt:,,r.1ut:h..::th! a-:iG/or
11.12:-b~n z:.:, [ luor:in ~hen.:-..
L -Actu.ol value is l:r~o1,11 co J,c t1·e.1.ccr r.krn ,_.,,11:t~ f~i·:cn.
~ -iGrcrial u,:i!; ·.1n~lf:-.1:,l for hut not detc:ct<~d. The nu::ihcr
-1
1-Tentative ic!cntific.1.tion. ~ __ · ;"1~•1/n-r ;,,-,n\,,..,,?,.,n"
i5 the Mi.ni:::1; . ., D-.:tr.:ction L.i..iit.
I
~~-2·~~~~;~~2~~~~~~-~~~'.~?~:~~~~
.. ·:_ ~~
\-1.\Tl::i:.
OAT,\ 1:r:L·v .. GC:t; S!i::.:Er
l'UllCE.:\!.S!.E. O'.<.GA.cl[C A<J,iLYSlS
::::-.~-.;_~_J, ~'.~::.
,\"fi!:::~e:;. C.-\
4/80
PROJECT Koppers Co,..,__,_I~•~•c'c-'-.----~CHG'-11$T E.W. Loy, Jr,·
~:orrisvillc. r;c
REC'D. 9-25-80 C0:0-lPLET'D • lO 21-6(
---
SAU 1:0. aor ?4"~ !:lQC 2§6] fiOc 2!..64
KL-:-001 'PJ.-002
SOURCE & STA.TIO:/ Upper End of rand behind ~le< BLANK Lake. Hon:e..
~E/TUIE. 9-22-SOQ 0815 9-2)-80 @ 1015 9-2) BO Q lllS -----
Cor;,2:ound ug/L ug/L ug/L
. 2/-dichlorodi f luoror:iethane-,4,co SU -.. , < ..
methvl chloride~/ 34418 Su .. , SU
methyl bro:,ii.rl~Y )4413 Su SU SU
vinvl chlo'!"iddl )9175 SU 5V SU
ch loroethaneL1 31,:\11 SU SU SU
methvleoe chlorideU 3-'1423 Su SU 8.5
t:richlorofluorow.ethane:.::.t )4483 ,u SU SU
lll-dichlo~oe.thylen~I J!.::.1vl Su SU 5U
1 1-dichloruethane"'l.7 J7411Yb SU · SU . 51.i
1 1 2-crans-dichloroethrlene±/ J4'.)l~b Su SU SU
t:hlorofora 27 j2UHi SU SU SU
1 2-dichloroethane!:.1 JLlU-i SU SU SU
1.1 1-trichloroe:thane _,, O,,<O< SU 5~ <,,
corbon tetr.t!chloride.Y 'l'>l07 Su :--u "'
dichlorobro~om~thane..=:.1 32101 SU 50 ...
1. 2-dichloroorooane.Y. 14,,,1 SU SU -<••
1.) dichloronro""lcne21 )4561 SU SU "G ..
trich loroethvlen"'L' 39180 SU SU .. SU
benzen~/ )40)0 SU su· SU
chlorodibromo:nethane.£7 )4)06 SU -SU SU
1 1· 2-trichloroethane.Y )4511 SU SU SU
2 chlorN:thyl vinvl ether (mixed)L/34576 Su SU SU
bromofo~:n:::.1 )2104 SU .SU 5Ll
l 1 llZ1 2-t~~rachloroethanc.=-/ 3,.s16 . SU SU 5Ll
tc.tr.t!chloro~thvh.::ne.Y )4475 SU SU 5t'.
t:olucne4 ' 34010 Su SU St! --
chlorobenzene.Y · )4)01 SU SU ---5\!.
cthylbenzcne.!=.' · 34)71 ·su -SU SU
acrolcin.Y 34210 1000 1000 1000_ .
ac.rvlonitrilc.!I 34215 1000. · 1000 lOOU ..
.-. .
' ..
.. . . . ..... . .
. .
' .. i. .·, · .
-· . I
. . I
I
-----
----.
------~ --.. ---
.. ., ~-
-· ..
J Estirnated v,1lue.
K Actu.:il value is, kno\.ln to l;c less ·ch:m v.:iluc civ£.!n.
L Actual value is:knovn t:o Le r,rc,1t<:r t:h.1n v.:iluc: r,ivcn.
·U Matcri.'.ll \.la:, ·analyz:£:d _(or: hut not <li:!tcctc<l. The nu.:;,1~er is the l·ilnfr.nun Dl!~·~.:tion l.inil
_NA Not ~naly4ed~
·!/_·Tentative idcncification.
'·?:,,J_.O.i t/RDC List of Priority Pollutants .
. , .:-~-'._.._:~->~-~-
I
•• .•
.. ·' ~ ,·." 1.::\·1·,\ !:t·::·t1~r1:,..c Siii:::::r
l'llllG[A'.jLE O:tG!,~lG /l[gL\'SIS
;;(:::::;:-. C:,\
4/HQ
PROJECT Koppers Co., lnc. E. \L IQY._.u: ___ ,r.cc•n.-2.:_25-S0 __ co:-li"'I.[T'[). · 10-21
Horri~vil le !\C
--·------sor ~; ~ . .., ==-•-•· -
SAD rm. soc 21.;68 r-;uc 24 70
SOURCE ' STATION P\.l-100\~ell rw-200 t-.'cll at KR-00t. E.:lst dit
~lc:dlin Hone. \Jilkcrson Con-u:-idcr RR Tracks
tract Co.
DATE/TIME 9-23-80 ~ 1)15 9-23-80 Q 1345 9-23-60 @ 1715
Compound ug/L ug/~ ug/L . 2/-dichlorodifluoro~ethane-,,,r,s 5U SU 5U
methyl .chloride,?/ Jt.4)8 5U 5U 5U
methvl bro~it.laY 34413 5U 5U 5U
vinvl chlor i<le .. ::J 39175 5U 5U ·5U
chloroeth:rne21 34311 5U 5U 5U
i:,,ethvlcn<! chloride Li J!.423 5U --, 5U
trichl0rof11:ororn~thane.!:..' 34!,88 5U ,,, 5U
l 1-dichloro~thvlcne±J _j!,501 SU .~ .. 5U
1-1-dichloroethan~Z/ J44~o 5U <n 5U
l,2-trans-dichloroethvlcn2~/ . 34)46 5U 5U 5U
t:hlorofonn L./ JHUb SU 5U ' 5U
1 22-dichloroethane=.' 3Ll 5U 5U 5U
1.1 l trichloroeth"ane 7,:.1 i.t.:::nF. 5U SU 5U
carbon tetrachloride=.' ">?~O? SU 5U 5U
dichlorohroreome t!\:me.::/ · 32101 SU SU '" 1 2 2-dich loroprori::me..::.'. s4s41 5U SU "' 113-dichlornproer.J..cnell 34551 SU SU. ...
trichloroeth"lcneZ/ 39180 SU 5t: .-· C:•1
benzene.!/ 340,0 SU 5U < '
chlorodibro~omethan~1 34306 SU SU <q
l l 2-tri!:hl01:o~:::h.'.!.r1c>.!:.' 34511 5U SU I ...
2--chlo""Coethvl vinvl ether (r.tixcd, .. , 34576 5U 5U SU(.
bro..-ororr::L.I .. 32104 SU SU <c
l l 2 2-tetrachlorocthane2., 34516 5U SU SU
te trnch loroeth" 11..:ne..Y 34475 5U SU 5U
toluene<-/ 34010 '" .SU 5U
•· chlorohenzene . .Y · 34301 <n 5U 5U.
ethvlb<mzer:el/ · 34371 ·su ,u· 5U
ncrolcln..=.1 34210 lOOU lOOU lOOU
ac!J:•lonitr.i.J .J.!·.1 34215 lOOU .. 1oou lOOU
. .
' .. -. -
' ..
. . .. ...... . . -
..
..
·--
,'
·J F.~til'1atcd v,1.lne.
K Actual v:ilu'! is. _knoun to be less "th:m value given.
L Act.u..1.l v:ilue is=kno· .. m to 1,c grc.1.tcr tlwn valu.:. r,ivcn.
·.U llatccial \.las ·:malyzcd _for-but not <lctcctc<l. "fhc nu=:~cc is the ::ini::mr:i r:,~t:cction Linit.
.. N,\ Not -:nalyzecl~.
·,.-!/ _ Tcni:,:;tivc idcntUication.
··:~/-On lW.UC Ltst of I'_ciocity Pollutants.
I
I .. ,
,ft~~~~~
. : ":-.:::~-:-: \::, . ..,.. __ ··.--. --_, ..
. . . . . . . . .. -. -_.
1tt~~-;~r~~f~:t-':~~I ·
-·~-:-_· .... -,-:,·• ·:-.:·: ...
:J/~'~--~~-~'~-~----~:~::.
. :•r: ·,/:~:-• , , . •· , • .. ·•,/ •
·1,.,~~i~~~~it~~~i
PP.OJECT Koppers Co., Inc.
-:-1!orr1svn·1 c:., t:c
-
S.1\0 ::o.
SOURCE I, STATION
DATE/TUI!::
Co::ieound
dichlorodifluorooi!thane~/-
meth\•l .chloride21
rnethvl bromide.£!
vinvl chlorid,.Z]
chloroethane2/
raethvlene chloride,:~/ .
t rich loro f luororneth:me~.1
ltl-dichloroethylcnd]
L 1-dichloroethaneZ/
1-2-trans-<lichloroethvlen~/
C::hloroforo LI
1-2-dichloroethane.£1
L l 1-trichlOr:-oethane ~,
ca1:bon tetrnchlorid,?-:1
dichlorobro~omathan~1
1.2-dichloroprooan~.'
1 3-tlichlorooroovlenel/
trichlor-o·ethv lcne 2/
bcnzc:nC..::.'
ch lorodibrorao:ne thanel7
1-l. 2-_trich loro~~hanel'
,:.r,:::::~ o:,:,·,\ t:a·u:-1.T(:-it; :.;!t~ET
1'llltC!::l\ULE Q;{CA~:lC /u'l/1.LYS!S
--BOC 247'
k1J-010 }'..:iin
office ,._,i!ll
faucet in
kitchen.
9-23-80 @ 1615
ug/L
,.,,,n Su
34418 SU
J!+41J SU
39175 SU
J!1Jll SU
3'-23 Su
3!;488 SU
Jt,5ul 511
344~0 SU
3,546 Su
1llua Su
.,_lu.1 SU
'l4c;nt: SU
'"0' SU
32101 SU
,4,,, SU
34561 SU
39180 SU
3li030 SU
34306 5U
34511 SU
2-chloroethvl vinvl ether (mixed)~, 345 76 Su
bro:.toforr:\£1 32104 SU
l 1li21 2-tctrachloroethane.~.' 34516 "' tetrachloroethvl~nd' 3r,4.75 Sn
toluc:nd/ 34010 su
·chlorobenzcneL' 3,301 SU
ethylbenzcn':'.!::..1 34371 ·su
acrolcin±} 3,210 1oou
acrylo!'it"tile.Y 342l5 1oou·. ..
..
..
'
J Estim~tcd value.
}':. Actual value is, kno\.lO to h·c lc.f.s 'th,rn valut:! ci.ven .
.
I. Actual value is kno\,IT\ to l,f:! r.rc,,:::er th:in value r,iven.
RQr .,,_ I?
}G./"~20 C2 \.Tell
main Bldg. Kie
faucet.
9-23-80 @ 1545
I ug/L
. 'U
SU
SU
SU
SU
SU
SU
SU
su·
. SU
5U
SU
SU
SU
SU
SU
5U
SU
su·
. SU·
SU
SU
SU
5U ,,.
<,
'U
·su
lOOU
JOOU
' -· -
' ..
. . . . -
..
. -.
. .
Al'l:t:~;~, C.l.
4/80
CO:--IPLET'D-10 21.
o_oc 2l. 7J
R.:-0J0
Sr.eel Shop.
9-21-80 @ 1500
ug:/L
SU
SU
SU
St:
SC
SU
SU
5U
5Ll ,u
• .. ,
"' °'' ·, ..
SU
SU
SU·
SU
SU
SU
SU
SU
SU
5U
5U
'-•
'"· SU
1001.,'
lOOU
-
..
U I·latl'.!d . .-11 \JaS ·an.,lyzcd _for hut not detected. The nu.-:i~cr i~ th.! Hini.:;ium Dl'.tcc.t.ion l.i::ii.t
_ NA Not: ~n:tlyz:e<l~
·l/_ Tcni:acive idcnti.fication:
?J--on l:T-:llr. Li~t of Pri.od.t.y Pollut.:mts.
I
T~~~~'";~
--~--:~~~~ ~~~·-.-.~_~;::~>f.s~~?~}in~
~----.
SA[) i-:o.
sou::cc ,. STAT IO~
D,\Tf:/TU!~
Cor:,,2ound
. 2/· dich lo rod if luorom~thane-
methvl_chloridc'!--_/
methvl hromide1
vinvl ch loridc.!:.'
chlaroethane2/
methvlcne. c!, lor id~'-'
trich loro fluoromet 11.::me...=.•
1 11-dichloroeth~lc~~~,
1 1-dichloroethine_LI
1.2-trans-dichloroethvlcn~/
c:hlorofonn !:..I
L 2-dichloroethane.Y
1 2 1 21-trichloroeth:me -•
carbon tetrachloric!e.27
dichlorobro:nomethaneJJ
1. 2-dichloronrooandJ.
1.3-dichloropronvlene±_,
trichloroethylcn~/
bcnzene.~.J
chlorodibr0mo~echanP-!:.'
1.].. 2-.crichloroethaw•~'
I
:. r:·:'.: o:\ r.\ 1:i•.,'l'-<. ~· 1:.c :::1 :·:i::·r
l'Ult(;[AllLE ORG,\:ac AS,\LY;,rs
_su..c_.,1 !. 7 t..
Pi.'-300
· F;rncct beside
Bacrbee Residence
9-23-3~ 0 1~20
ug/L
"·"" ,u
311418 SU
34413 SU
39175 '" 34311 5U
3!14Z3 S11
34488 50
Jt,Sl.ll 50
34L.Yb SU
:14540 SU
ouvv SU
JL.lU SU
11,r,n1. 5U
nlf'., SU
3Z.l01 50
'14~41 SU
34561 5U
l91so SU
::S40)0 50
34306 SU
34511 SU
· 2---chloroc.thvl vinvl cth-e:r (mh:.c.d)~1 34576 50
bromr•:!'rm=.1 32104 SU
11 1 1 ~.: Z-tctrachloroeth::ine.!:.1 34516 50
"tritr:>.chlo-roethy__h,ne~• · )!,1t7S SU
toluene.?} )f.010 SU
-chlorobei1zcne.Y · 34301 SU
etflvlbenzenC' 34371 SU
acrolc-ln.Y 34210 lOOU
acrylonit:rilc.:Y 34215 1oou .
..
•..
.
.
-· ·•
--~-
·-··
Esti111atPd v.'lluc.
Actual value is, knovn to b·e less ·t_h:rn v:i.1~1c r;ivi!n.
'
'
. ' ..
J
K
L
u
__ NA
l/_
U-
Actu.:-,1 value i~•koo.m to be r,rc.:i.tcr th.in v.'lluc r,iven.
_Material vas ·analy7.c<l _[or but not <letcctcJ. The 110:n!.icc is
Not ~n., lyzcd.
Tcni::3ti.vc identification."
On tm.oc Li::.t of Priority Pollutants.
.
u&/_L
,.
.
'·
.
. ....
. .
..
..... ,.
;,t::::::::-i:>. c;;,
4/60
.
ug/L
.
'
.,
.
.
..
:
-----
------..
,
th<!. Hini;;iur.i. D2:tection Licit
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rl
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(
DAT.\ ~,:::1..::Ih~~~ ~r.::::::: E?A-~;.\U-;\(;:,.. I'.'
_; l'f:STJ :lf'ES/i'CB'S·. ,\:;t> OTHE!{ C\LOU:~ATL□ cm~ou::ns Athc~s. CA t./E
i"~O . .lECT Koppers Co., Inc. c11::::u::;r E. w. Loy, Jr. ·------------
crn·: Morrisville
r.c::C'D. 9-2S-80 cc::t?L'D. 11-5-
@ 0800
STATE: ~forth Carolin.:i.
S,\D i\O.
SOURCE & STATION'
'
DATE/T 1:-t:.:
.. . cmIPOUND
69. :i.ldrln ZI . 34680
90. dieldrin M 39404
91. chlordane (tech. taixcure &
t:letabolites) 'lJ 34682
n. 4 14 1-DDT !T,. .o'-DDT\fl 39302
93. •. 4,4'-nn:: <e 22'-nn~'Y 3'1322
94. 4,4'-DDD {~.o'-TDE141 3S312
95. a-en:io.salfan-.\loha U 34365
96. b-endo.sulfan-Beta I.I 34360
97. endosulfan sulfate. M 34355
98. endrin M 34'6S5
99. endrin aldehyde 2/ 34)70
100. he2tachlor £/ '""8 7
101. hcnt:achlor eno:x:ide "J;.1 · 346S6
102. a-lrnC-Aloha y J~U14
103. · ·b-Bi-IC-Bet.n '!:_/ 342:iS
104. y-BHC-(lindene)-Gm:u:ia. 'l-./ 3976:>
105. .0.-BHC-Delta "I./ J4:.!bJ
106. PCB-1242 Aroclor 1242)£/ .,, r:nn
107. PCB-1254 Aroclor 1254)fl 1'/,00
103. PCB-1221 Aroclor 1221)~, 1,6,fi(,/, ·
109. PCC-1232 Aroclor 1232)9 34667
110. PCli-1248 (Aroclor 124S).M 34669
111. PCB-1260 ~Aroclol." 1260).M 346 70 ·
112. PCB-1016 (Aroclor 1016)Y 34674
113. Toxaohene "?,_/ 34691
Pronaclor iRarnrod\
Pror::ieton
2 4-0 39734
Silvex
2 ·4 5-T
129. 2 3 7 8-Tetrachlorodi~enzo-
. n-dioxin fTCDO\ ZI. 34679
·-· ..
" -
NA -Kot Analyzed.
.I -Esticatcd value.
BOC 2463 soc 21,6)
KJ.-001 upper KL-001 u_pper
end of lake end of lake
nc:ar \~illo'..'S, nt!ar Willows,
Adj. to Delt. Adj. to Dt!l t.
Cat Fish. Cat Fish Liver
9-23-80 @ 100( 9-23-80 @ 1000
~oncent.ra-Concentra-
tion· ng/kg tion 'mg/kg
0.2U o.osu
0.02U 0.03l'
0.2U 0. c ..
O.OlU O.lU
0.0.lU O.lU
0.0!.U O.lU
0.0'.W U.U)U
O.OlU . O.lU
O.OlU u~2U
0.04U 0.061.i
O.O!U 0.2U
O.OlU o.osu
0.2U o.osu
O.OlU 0.05U
O.O!U o.osu
O.Olll 0.05U
0.0lU a.usu
o.su o.su
0.lU lU
0.5l! o.su
o.su o.su o.su 0 .. 5U
O.lU lU o.su o.su
O.lU lU
NA NA
"NA NA
NA NA
NA NA
NA NA
NA NA
. ..
"
i~ -Actu.:ii ·valu~ i::; knOvn to be lc::;s th:in vai.u<.! r;.ivcn.
-·
Conr.!entr.\-Concent.ra
t.ion J?-J/kg tio:1 q
.
--N• ...
-
-· ·-
·1. .-·Actual value ·i_::; knovn to hc·r,rcar.cr than v.1luc r;i.vcn~.
U -:-.Matcri.'.:ll 1.1.1.; ;n;i:,·~cd for but not. Jc:..cctcd. The nui:;:bcr is the }lirdrnum D.:tcctioa Li::iit..
: ·}~ _:: !·c~-~~ ~~v<·fd~~~i: i~., ~ ~~~. , .. ,. _ ......
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FT'-t: n,\f.\ r.:::p,:,_,r;.:;: .:>r..:..:.~ ~?.\-3,\Ll-.::i.C,:,.;. D
· Es rrcrn::s/rcs' s, .,::o or!!::il c::L;:;~1:-L\7:..:~ cc:-~:>uu:~□ s l,thc:ns, C.-\ 4/SV
i'!W.JECT Koo;iers Co .• Inc.
crn·: Morrisville
Cl!E..:-llST E. t;. 1.o,· Jr. I:::C'll. 9-25-SO CO:-!PL'D. 11-5-eO
STATE: t-:orth Carolir." --
S,\U 1:0. soc 2.'; (,(, !ill.C 2:'..(,6 I ROC
-
2~~~-BOC 24f.()
(>L-002 Pond r-oo·• Pond pL-002 Pon<l pL-002 Po:-id
behind Medlin e.hind ~l~dlin bchin:! Hedlin behind };edl
SOURCE • STATION home. ho~c. hor:ie. home
Bass B.2.ss liver. Blue gill. Blue gill 1
DATE/TH1£ 9-23-80 g 1115 9-23-80 @ 1115 9-23-RO ~ 1115 )-23-80 Q 11
cm1Pomm Concentra-Cc.ncentr:l.-Conceat::;i-(C"nc.:c:.ntra-.. cion tian r:ig/kg tion t.ion r::.;/i:g oil~~& r:.gH
69. :i.l<lr'in 2/ 34Ufi0 0.03:J n , " 0.030 O.lC
90. dieldrin ~/ 394U!, O.Oll: n 1 r: 0.0lli 0.113
91. chlordan~ (tech. mix.cure &
metabolites) ?:I )!i682 0.03U " 1 11 0.03U O.lU
92. 4 " ·" DDT ln.o'-DnT'Y 39311" O.OlU 0.03U 0.0lU 0.031:"
93: 4 14'-DoE· (e 20'-D!J.F;HI 39322 O.OlU O.OJU o.on: O.OJV
94. 4 4'-DDD (-~•-mr:)'n 39312 0.0lLl O.OJU 0.(Jlti 0.0)ti
95. a cndosulfan-Aloha ~' 34365 o.ou: 0.lU 0.0lLJ 0.lU
96. b-endosulfan-Beca ;, 34360 O.OlU 0.0JU O.OlU 0.03,'
97. enc!o!>ulfan sulfate Y 34355 0.01V 0.03U 0.011; 0.03l'
93. et!drin M ]468) 0.02U 0.2U 0.02t: 0.2l.!
99. enJrin aldehvde 2/ )!;370 0.011; 0.03U O.OlU 0.0Jt;
100. heocnchlor LI J4l>87 0.003U O.OlU 0.003U O.Olli
101. hcec.'.!.chlor epoxide "?:./ · 346S6 0.03U 0. lLi 0.03U O.lU
102. a-BHC-Alnha fl J~U,4 0.003U O.OlU 0.003U O.OJIJ
103 • . ·b BHC-Ilec~ 2{ 34Z53 0.003U u.OlU O.OOJi.." O.hlC
104. y--BHC-(lindane)-G:?.c:na L.f 31Jt:i"i 0.003U u.uie 0.003U O.OH;:
105. 6-BHC-Dclta !,./ 34£63 I 0.003U OJ'lJ.L' 0.003ti O.Oi.~=
106. PCil-1242 (kcoclor 12425I7? · ·--o.2r 0.2U o,iu o.·1f·-
107. PCC-12.54 (Aroclor 1254)f/ i4600 O.lU. 0.30 O.lU 0.:;t:
108. PCB-1221 (At:oclor 1221)Zi, 1li~!. 0.2U O. 2U 0.2U 0.2t.:
109. 'PCB-1232 (A-::-oclor 1232g, "\46,,7 0. 2U 0.2U Oa2U 0. 2U
110. PCB-1248 (Aroclor 1246)£134669' o.zu 0.2U 0. 2U 0.2l.I
111. PCB-1260 (Aroclor 1260)ll 34670 · O.lU . 0.JU 0.JU O.Jl:
112. PCB-1016 (Aroclor 1016)-'' 34674 0.20 0.2U o.zu 0.21..;
113. Toxanhcne U )4691 O.lU 0.30 0. ll: 0.3l1
!'ror:aclor 'Ramt.od~ NA },;:~ t-A NA
Pror.:ctO!l. NA NA NA NA
2 1,-D )973!i NA NA ~A NA
Silv?.::-:: NA NA KA KA
2 4 5-T NA NA l\,\ SA
129. 2 3 7 6-Tctrachlorodlbenzo-------
~ dioxin (TCDD--,----;r/-34679 NA NA NA -..... A
·····.
·-·
--
------•··
--·· .
---·
I I J
1.;A.-Kot /,n.,ly7.cd.
J -E~ t ioa r:cd v.1 luc.
I~ -Accu:11 v.iluc i~• knO,.:n to be lc~s ch:1n valU'.: ti.v,~n.
L 'Accual v,1lu~ i5 knO\..'ll lo li<! r,.C~<\tcc th.:rn v.tluc I;ivcn.
U -:-. Matcri:ll u.1:. .1naly;,:ccl for hut 11ot JctcctcJ. Tile nur.1\H~C i:; the }linlnu~.1 D.::t:.::c.Lion Li1:ii.t.
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\ t~AT~K
DATA REPORTING SHEET
PESTICIDES/PCB' S • A.'\D OTHER CHLORINATED CC:1POUNDS
EPA-SAD-RC;~. IV
Athens, GA 4/SO
p1~0-JECT Koppers Co .• Inc.
Moufsvi J Jc NC
CHE.~IST E. ~-Loy, Jr. REC'D. 9/25/80 C0!1PL'D. 10/}0/8
@ 0800
SAD NO. OOM,h] on,-,-,,,hl 80""4""7 Qf'lr'll,kO
KL-001-Upper PL-002 Pond PW-100, \.'ell P\'o'-200 t..'el
End of Lake N .behind from Medlin @ \./ilkersc
SOURCE & STATION Willows, Adj. Medlin Home Mobile Home Contract in
to Delt Company
DATE/Tll1E -9/23/80 @ 101' 0/23/80 @ 1115 9/23/80@ 1315"9/23/80@ 13
cm!POUND Concentra- Concentra-Concencra-Concentra-
tion ug/L tion ug/L tion ug/L tion ug/L
89. aldrin 2.1 39330 0.03U 0.01U 0.03U 0.03U
90. dieldrin M ",no 0,05U 0. QC:11 0.05U o.osu
91. chlordane (tech. mixture &
metabolites) 2./ 39350 0.4U n ,.n 0. t.n n l.t!
92. 4.4'-DDT (o n'-DOT 1ft 39300 . O.lU · 0 m O.lU O m
93. '4 14'-DDE !E:zE:'-oo~ £ 39320 O.lU n 1n O.lU n 1n
94. 4 41-DDD (" o'-TDE ., 39310 0,lU n "' O.lU n m
95. a-endosulfan-Alpha " 34361 0 ""' n '"" o.ocn n
96. b-endosulfan-Beta &. 34356 n rn n rn 0. 111 n rn
97. endosulfan sulfate !:./ 34., .. , n m n "' O , n
n "' 98. endrin U ,o,oo n ••• n ,n O m nm
99. endrin aldehyde ", 34366 n "' n ••• 0.111 . n , 11
100. heptachlor =' 39410 n n,n O n.n 0.0:m o.o,n
101. heotachlor eooxide U 39420 n n"' n ""' 0.01U n. n111
102. a-BHC-Aloha fl 39337 n n, .. n n"' . 0.03U n n<.11
103. · ·b-BHC-Bet.::. fl 39338 n.o«• n ""• 0.03U n n,n
104. y-BHC-(lindane)-Gamma !:.I 39340 n n,n O n.n 0.03U o.o~•
105. A-BHC-Delta 1,.1 34259 n ""' O n,n 0.03n O n,n
106. PCB-1242 (Aroclor 1242)9 39496 n ,., n ,., 0. 311 n "' 107. PCB-1254 CAroclor 1254):, 39504 ,n lU m
108. PCB-1221 (Aroclor 1221H:1 39488 -n n 0. n
109, PCB-1232 (Aroclor 1232)e, 39492 n ,., 0 ,., O.n O ,n
110. PC8-1248 (Aroclor 1248),U 39500 n ,., n ,., 0.3U n ,.,
111. PCB-1260 (Aroclor 1260),V 39508 ... rn 111 ...
112, PCB-1016 (Aroclor 1016):.1 34671 n ... n ,., 0 ,11 " ...
113. Toxanhene 1,./ 39400 "' rn ... rn
Prooaclor (Ramrod) 77729 ... ... MA ...
Prometon ,ao-• ... MA '" ...
2 4-n '""" ... ... NA ...
Silvex <0160 ... "' 2.li .5-T ,s14n ... ... "' ...
129. 2.3 7 8-Tetrachlorodibenzo---- -
n-dioxin fTCDDl £.I 34675 NA NA NA .,.
.......
NA: Not analyzed.
J -Estimated value.
K -Actual value is kno\.ffi to be less than value given.
L -Act.ual value is kno\.ffi to be greater t.han value given .
U -Hate.rial was analyzed for but not Jet.ected. The number
l/_ Tentative identification.
is t.he }Unfmum Detection Limit.
Z/_ On NRDC List of Priority Pollutants.
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l·!ATt::H.
DATA REPORTING SHEET
PESTICIDES/PCB' s I A,.~D OTHER CHLORlNATED co~omms
EPA-SAD-RGN. IV
Athens, GA 4/80
PROJECT Koppers Co. 1 Inc.
Morris:v111e NC
CHEMIST E. Y. Loy, Jr. REC'D. 9/25/80 COMPL'D. 10/30/80
@ 0800
SAD NO. 80C2470 80C2471 80C24 72 80C24 73
KR-004 East 1'.1.J-010 Main KW-22 Well, KW-030 Ste,
Ditch Runoff Office '.Jell, Main Laminatirg Shop
SOURCE & STATION fr. under RR Faucet in Bldg. Kitchen
Tracks Kitchen Faucet
DATE/Till£ -9/23/80 @ 1715 9/23/80 @ 1615 9/23/80@ 1545 9/23/80 @ 151
.
Concentra-Concentra-Concentra-Concentra-Cm-1POUND tion cion tion tion ug/L ug/L ug/L ug/L
89. aldrin Z/ 39330 0.03U 0.02U 0.03U 0.02U
90. dieldrin M 39380 o.osu 0.06U 0.05U 0.06U
91. chlordane (tech. m.ixture & 0.4U 0.5U 0.4U 0.5U
metabolites) Z/ 39350
92. 4.4'-DDT (o n'-DDT ,9 39300 ·o.1u O.lU 0.lU O.lU
93. 414'-DDE !P1E'-oo~ <' 39320 O.lU O.lU O.lU O.lU
94. 4 4'-DDD (n. "'1-TDE) M 39310 O.lU O.lU O.lU O.lU
95. a-endosulfan-Alpha ~, 34361 o.osu 0.06U 0.05U 0.06U
96. b-endosulfan-Beta fa' 34356 O.lU 0.lU O.lU O.lU
97. endosulfan sulfate f/ 14-:ii;;.1 O.lU O.lU O.lU O.lU
98. endrin ~, ,q1qo O.lU O.lU 0.lU O.lU
99. endrin aldeh\•de '-' 34366 O.lU 0.10 O.lU O.lU
100. heptachlor Eat 39410 0.03U. 0.02U 0.03U 0.02U
101. heotachlor eooxide ff• 39420 0.03U 0.02U 0.03U 0.02U
102. a-BHC-Aloha ~, 39337 0.2U 0.02U 0.03U 0.02U
103. · -b-BHC-Bets. LI 39338 0.2U 0.02U 0.03U 0.5U
104. y-BHC-(lindane)-Gam.na !::.' 39340 0.2U 0.02U 0.03U 0.02U
105. 6-BHC-Delta l,.I 34259 0.2U 0.02U 0.01.u 0.02U
106. PCB-1242 Aroclor 1242''' 39496 0. 3U 0.4U 0.3U 0.4U
107. PCB-1254 Aroclor 1254)£/ 39504 lU 2U lU 2U
108. PCB-1221 Aroclor 122llfl 39488 O.JU 0.4U 0.3U 0.40
109. PCB-1232 Aroclor 1232lfl 39492 o. 3U 0.4U o. 3tJ 0.40
110 .. PCB-1248 (Aroclor 1248)f/ 39500 0. 3U 0.4U 0.3U 0.4U
111. PCB-1260 IAroclor 1260)<> 39508 lU 2U lU 2U
112. PCB-1016 <Aroclor 1016l.9 ""\4671 n. <u 0.40 0.3U 0.4U
113. Toxaphene 1,./ ]':1400 lU 2U lU 2U
Prooaclor (Ramrod) 77729 NA NA NA NA
Prometon -:ic O'"'i6 NA NA NA NA
2 4-D ,o,on NA "' "' NA
Sil vex -.n760 N• NA NA NA
2 4 .5-T ,onn NA _,.. J.JA NA NA
129. 2 3.7.8 Tetrachlorodibenzo------o-dioxin <TCDD) U 34675 NA NA "' "'
.....
NA-Not analyzed
J -Estimated value.
K -Actual value is known to be less than value g1ven.
L -Actual value is knoi.m to be greater than value given.
U -Material was analyzed for but not. Jetected .. The number
1/_ Tentative identification.
is the Minimum Detection Limit.
2/ -On NRDC List of Priority Pollutants. _. __ . ........,,_ .. '....
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t,.'ATl::K
DATA REPO!lTI~G SHEET
PESTICIDES/PCB'S1 AND OTHER CHLORINATED COXPOUNDS
EPA-SAD-RGN. I\'
Athens~ GA 4/80
PRciJECT_-"K'°'o.cP.cPcc"~r"s_C"o~. ~• ~I~n~c~·~----CHEMISI E. W. Loy 7 Jr.
Mnrri svi 11 e NC
SAD ~O. 80C2474
PW-300 Fauce
SOURCE & STATION beside
Levis
Bacrbee
Re~idence
DATE/TlME -9/23/80@ 1420
P.EC'D9/25/80
@ 0800
COMPL' D. 10/30/l
C0:-1:POUND Concentra-Concentra-Concentra-Concentra-
tion ug/L tion
89. aldrin 2./ 39330 0.03U
90. dieldrin '-' . 0 0.05U
91. chlordane (tech. mixture & 0.4U
metabolites) 2./ 39350
92. 4 4'-DDT (o "'-DOT)f/ 39300 O.lU
93. ·4,4'-DOE (p,p'-oor; 39320 O.lU
94. 4.4'-DDD (n,p'-TDE)" 39310 O.lU
95. a-endosulfan-Alpha !:.I 34361 0.05U
96. b-endosulfan-Beca 1s.1 34356 O.lU
97. endosulfan sulfate f/ 14·11::1 O.lU
98. endrin ff 0 O.lU
99. endrin aldehvde ~, 34366 O.lU
100. heptachlor £./ 39410 0.03U
101. heotachlor eooxide !,./ 39420 0.03U
102. a-BHC-Aloha f/ 39337 0.20
103. b-BHC-Beta £1 39338 0.2U
104. y-BHC-(lindane)-Gamma ~, 39340 0.2U
105. A-BHC-Delta '-' 34259 0.2U
106. PCB-1242 (Aroclor 1242\!J 39496 0.3U
107. PCB-1254 {Aroclor 1254)~1 39504 lU
108. PCB-1221 (Aroclor 1221)9 39488 O.JU
109. PCB-1232 (Aroclor 1232)fl 39492 0.3U
110. PCB-1248 (Aroclor 1248\"#;_/ 39500 0.3U
111. PCB-1260 (Aroclor 1260)<' 39508 lU
112. PCB-1016 (Aroclor 1016)9 ':!.4671 0.3U
113. Toxaphene f=.t 39400 lU
Prooaclor (Ramrod) 77729 NA
Prometon ,on« NA
2 4-D on,on NA
Silvex 60 NA
2 4.5-T OOH 0 NA
129. 2.3.7.8-Tetrachlorodibenzo-
. o-dioxin (TCDDl ti. 34675 NA
NA-Not analyzed.
J -Estimated value.
K -Actual value is kno\.lT\ to be less than value given.
L -Actual value is known to be greater than value given.
U -Material vas analyzed for but not Jecected. The number
l/_ Tentative identification.
2/ -On NRDC List of Priority Pollutants.
ug/L tion ug/L tion ug/L
.
NA »o
is the Minimum Detection Limit.
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SEDIMENT
PEST1CID£S/PC~'s. AND OTHER Cl!LOilI~IATl::D co~~ou:-.:os
2~.\-s.-.0-r:c::. .:. .-
Athens, CA 4 /t,O
l'l:OJr:CT. _ __!Ke,;o,ip,ip!Je'-'rc,suC.i;o!llrolllPs>Bncyy_·_,.1nucc.... __ __:CllL'IIST E. t.l. 1.oy, Jr. REC'D. 9/25/80
@ 0800·
CO:-".PL • D. 10/)0/ 8(
Morrisville. NC RESULTS m( DRY HEIGHT fiASlS.
~AD XO. •oc2,i2 onr'l4fi'i 80C2469
KL-001 Upper PL-Q_02 .Pond KR-003 dm.-nstr
End of Lake nr behind from Area'.
SOURCE & STATION Willows. adj. Medlin Disced, and
' --to Delt Sown with --. -·-Grass· . .
. •·· .
DATE/TI.:.lE .
9/23i8o @ 1015 9/23/80 @ 9/23/8_0 @ 1700 1115
.. CO~lPOUND Concentra-Conce.ntra-Concentr~-Conce.ntra-
tion ug/kg tion ug/kg cion llg/kg tion ug/kg
89. aldrir.).I 39333 lOOU 1oou. 80u 90. dieldrin L.I 39383 40U 6U 7U
91 •. chlordane.(tech. cLxture & 70U ,uU 40U·
· n:etabolites) 'l../ 39351 ·
92. , 414'-DDT <e1e'-DDT}Y 39301 20U ZOU ZOU 93. 414'-DDE CeiE:1 DD~'l'.V 39321 .. .£uU-.:-. ·. " 20U ZOU 94. 4 41 -DDD (-""1 -TDE':n 39311 LUU 20U 20U 95. a-endosul fan-Alnha I,,/ 34364 am, "' 7U 96. b-endosulfan-Beta Li 34359 """. """ 2ou·
97. endosulfen sulfate-'!:,/ ,4,54 20U '"" ZOU 98. end.rin Z/ ':10"191 ,ou '"" 7U
99. en<lrin aldehvde 2/ 34369 20U 20U ZOU
100. heo tachlo r !... ' 39413 lOOU lOOU sou
101. · hept:.ichlor el)oxide ff· 39423 lOOU--lOOU nuU
102. a-BHC-Aloha !:.1 39076 lOOU lOOU .. 80" 103. · ·b-BHC-Betc ~I 34257 lOOU lOOU BOU 104. Y--BHC-(l.it".dane )-Ganin.a 21 39343 · lOOU lOOU BOU 105. 6-RHC-Delt.a 7 I 34262 lOOU lOOU 8ou 106. PCC-1242 (Aroclor 1242)11 39499 600U ouuU 1-000U
107. PC!l-1254 (:Aroclor 1254)~, 39507. lOOU lOOU 70U
l 00. PCB-1221 (Aroclor 1221)!...' 39491 mu,u 600U l,OOOU·
109. PCB-1232 (Aroclor 1232)17 39495 uuuU .600U ~ nnn ..
110. PCB-1248 (Aroclor l2l18H,I 39503 ouuu 600U .. noon
111. PCB-1260 (Aroclor 1260)~' 39511 1oou lOOU -,on
112. PCB-1016 (Aroclor 1016)Z/ 39514 600U 600U 1 ooou 113. Toxaoh~ne 61 3%03 lOOU lOOU 70U 2,4--D 39731 NA NA. NA
· Silvex ·-39761 NA NA NA
2 4 5-T-':10'741 . NA NA NA
Prooachlor fRa:i:,rod' 6<672• NA NA NA
·Prometon ,.,,,. ..... NA NA NA ,,n 2 3 7.8-Tetrarhlorodib~nzn--
n-dioxin 'TCDD' ,, '4678 u, NA NA NA
-
. -
.,
-.
..
-
NA -Not_ analyzed. .. ,._ . --. ... , ·--• . ------j ·_ Estimated value.
K -Actual ·value is kno\JT\ to he less t:h.1.n value r,iven.
L· ·J\ccu.J.l v.1.Lue i!; knm.Tl to be r,n·,1.Ccr th:rn v.1.luc!· r,iv.:-11.
U ·..:. H.1.t.:!Ci:"!l v,1s :-in~lv1:erl for hor: not: ,kte<:t:<:!d. The nur.1hcr
... ·:. .; ..
;,:·_
is t.h<.! Hini=tum Detection Limir..
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(
APPENDIX B .
I U.S, Et>, KON MENTAL PROTECTIC AGENCY
SURVEILLANCE ANO ANALYSIS DIV!SION
.• REGION Ill: ATHENS ,GEORG/1
SAMPLING STATION NO. !{I...-00 / · I DISCHARGER --:-1"--'-'+-Jµ....,_~....l....c.>L.:.-F='-"'-------1
ADDRESS _ __Jclli::ilcu..!ll..!.l.L,-~~.e_ _____ -3 SAM P Co -'-'~-'---'-.,......-.:L...1. __ _
,.,_,1
SAMPLE AND WASTE FLOW INFORMATION ·-,-----------------------
SAMPLE D MUN, D IND. D INF. D EFF. D ---□---HR. COMP. AT __ ~ MIN. INJERVALS D FLOW PR<
I SAMPLER D EPA D DISCHARGER D MAN. D AUTO. D TYPE uJq-f,,v d-<:ed111R<if: c:S-J.,,.,';t"Ll
FLOW . 0 EPA O DISCHARGER O AVG. 0 INST. 0 EST. 0 EOUIP-----------
COMPUTED FROM
I SAMPLE COLLECTION
I SAD NO.
DATE
COMPOSITE GRA8 SAMPLES 1/ I SAMPLF COD~~
TIME
FLOW-, l L!. I TEMPERATURE 0 c
nH
TOT. Cl2 RES.mg/I
I
I
. ~i) <-"?-¥!;;1
'I/Z, ;/1,,1
. I t)/J
-,c.:.i<..;i;
· <'fiZ <lf;O ,~,.,
1. ~AMPLE CODE t<Ji-rd/ -;,C~o,;,,j
/e<lr, . CYANIDE
SAMPLED BY (Sia) •4-':/.. {l.""(.{t1.::. JJ1-:/?,£Yu~/ -LL:..;Z,,M1i.f
· ·SEALED BY lSial v~u, -.1.-<,...,,.· ._tv.;.-.u.4.,J~
DATE AND TIME r:--:2,-.z, loJn C(·l.J-YO ,()_J.{) ?RE<:f:RVl,D
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L!. Use Avg. Flow for Comoosites and Inst. Flow for Grabs l! Circle or Indicate Anolvsis and Enter th1rn'!!ricol C(lde
SAMPLE CUSTODY AND SHIPPING INFORMATION
SAMPLicS RELicASED TO (SIG) OR SHIPPED VIA DAT6 TIME ND .. CONT. NO CART. RECEIPT NO.
~_/_.,,_ ___ ...-:;:·-,.,." -~ .~ ,-...j ';r-7, fQ/ ),-7.(//J /.J Vr-Y .-J LL
/ , / -,
REMARKS AND SKETCHES
I U.S. ENVIRONMEi\lTAL PROTECT!nN AGENCY
I (
SU'1. ,EILLAr~CE AND .l\.r~ALYSI::, JIVISION
I REGiON = ATHENS ,GEOR•
. D1scHARGER · koppe-r,s I ADDREss f\:~vv1·sv, !k,
CONTACT Po r .s,,,A-k ,
Co, "1°N-~C-~------i
N-C--~<~-----
' I SAMPLE AND WASTE FLOW INFORMATION
I. SAMPLE
SAMPLER
0 MUN. 0 INO. 0 INF. 0 EFF. 0 ___ 0 _ HR, C9MP. AT_-,-MiN. iNT~RVALS O FLOW P
0 EPA O DISCHARGEf.c O MAN. 0 AUTO. 0 TYPE _ll,d::-C,wgf. /-Cc;;fGs/, .
I FLOW
SAO NO.
OATE
0 EPA O DISCHARGER O AVG. 0 INST. 0 EST. 0 -----EDUiP--~-------
COMPUTEO FROM
S/.U,1PLE COLLECTION
COMPOSITE GRAB SAMPLES
I TIME /" /Oc?O CYANIOE
FLOW ( . I I!. I ·METALS
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SAMPLE COOE
SAMPLED BY (Siq)
. SEALED BY (Sial.
DATE· AND TIME
L!. Use Avg. flow for Composi!es ond Inst. Flow 1or Grohs I.! Circle or Indicate Anolys,s and E'nter Num~ricol Code
PRcS~RVED .
SAM-PLE CUSTODY AND SHIPPING INFORMATION
SAMPLES RELEASED TO (sir.) OR SHiPPED Vi A C)ATE1 TiME NO. CONT. NO CART. RECEIPT NO.
< /4: I/ /,t:!:,,.,, .r:::::t..J;? ~, /7•" Y-/~,-,pz, /"Jc-oo /
/ -·,1 /
REMARKS AND SKETCHES
I U.S. ENVIRONMENTAL PROTECTION
SUR( _rLLAI\JCE AND ANALYSIS (,
AGENCY
✓ISION
.REGION :nz:: ATHENS ,GEORGIA
,'.J1scHARGER -~~"'-'---"--~--------SAMPLING STATION No. PL~oo1-~ I AO OR ESS -'-h~\ \r~.:,cc.· -·-=..J'-'0'-'-1,'-'-'---'-','-'--"'-.u..,_-'-----------l SAMPLING LOCATION p., Y\d b,, h vk,c\.
. -be · 1. '15&0 MeJ\;,-, he I CONTACT v..\J:t?V t:A~f ':l~di mu
SAMPLE AND WASTE FLOW INFORMATION
lsAMPLE
SAMPLER
0 MUN. 0 IND. 0 INF. 0 EFF. 0 ___ 0 ___ HR. COMP. AT ___ MIN. INTERVALS O FLOW PRC
0 EPA O DISCHARGER O MAN. 0 AUTO. 0 TYPE __________________ _
_-.FLOW 0 EPA O DISCHARGER O AVG. 0 INST. 0 EST.□-----EDUIP-----------
COMPUTED FROM
FLOW I . I L!. METAi S
SEALED BY ISial
ov9:>u.1cS
J' 1·. fl, ,/:W, .
I DATE AND TIME . . PRF.S~RV"'D
. L!. Use AvQ. Flow ~or Compos it.es. ond Inst. Flow for Grebs L! Circle or lnd1co~e Analysis. c_nd Enter Numerical Cod~
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SAMPLE CUSTODY AND SHIPPING INFORMATION
SAMPLES RELEASED TO ( Sit: I OR SHIPPED VIA. DATE1 TIME NO. CON 1. NO CART. RECEIPT NO.
~":~ . ./::,.~. ~7_L.,,.,,,7~,,,,.T.2? '/ /.· <:r/ .l S l.f'F o s.,,t;o J-1;.. , I ✓
REMARKS AND SKETCHES
I U.S. ENVIRONMENTAL PROTECTION AGEr•JCY
(
SUL .:ILLANCE ANO ANALYSIS !VISION I REGION=
DISCHARGER i)y-ivate LAK€
I ADDRESS OW$, J/.,,0~~1,_,_rf.1-...cl'-'-')·1"r~,.J~. '-'I ;..,_\J _______ -1
£f.v (;,,'!. 11 ~1 ,,15
ATHENS ,GEORGI
SAMPLl~JG STATION NO. PL-{) 07--
SAMPLING LOCATION Po,._,~ \v ~, vt ~
CONTACT _________ _ l-1-1 (.,o
I
I SAMPLE
SAMPLER I FLOW
J
SAMPLE AND WASTE FLOW INFORMATION
0 MUN. 0 IND. 0 INF. 0 EFF. 0 ___ □---HR. COMR AT ___ MIN. INTERV"-LS O FLOW PR
0 EPA O DISCHARGER O MAN. 0 AUTO. 0 TYPE-,-------------------
□ EPA O DISCHARGER O AVG-0 INST. 0 EST. 0 -----
COMPUTED FROM
EQUIP-----------
I SAMPLE COLLECTION
-------...-""'c"'o,...M""""P""'o"'s,...1'"=T'"'E~...-----'----G=--R=-,"'"A""s-s,...A-M'""P"'L..,_E""'s,,__ _______ 1""s_A_i_~~P-LF° coo£ G
SAD NO. B'Ci'--',,l.Yl•'-' f OAr;TF~:~1
DATE I 4 I 2?> 1••✓ J I "<",n <:<;'1 TOC I TIME / -//Ir-"· CYANIDE.
FLow·1 )I!. i Y~TAI"
I SAMPLE CODE
SAMPLED BY (Sin)
SEALED BY t Sia l
. DATE AND TIME
I I L!.. U'j,e Avg. Flow for ComooSites and lnSt. Flow for Grabs
~ P-R~$ERVF.:D
t! Circle or lndicat<? Analysis ond Ent~, Nu:-::~dco! Ced~
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. SAMPLE CUSTODY AND SHIPPING INFORMATION
·SAMPLES RELEASED TO (SIG) OR SHIPPED VIA DATE I TIME NO. CONT. NO CART. _-_,,,,__--~. /~~ "d-?, c-n..2.r/.1"1: /j V-0,:> I
/ / ~
·~----,------L:RuEJ~n~AtillR~K~S AND SKETCHES
"'°bde i-~ ·
RECEIPT NO.
..
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U.S. ENVIRONM.ENTAL PROTECTJnN AGENCY
' SU. ( ,EILLANCE AND ANALYSI:::, .JIVISION
REGION =
ATHENS ,GEORt
DISCHARGER Ko on,?t•S & , T10c.
ADDRESS Mov:,•svd Ir-1-.1,r
SAMPLE
SAMPLER
FLOW
SAD NO,
DATE
,
SAMPLE AND WASTE FLOW INFOR~AATION
0 MUN. 0 IND. 0 fNF. 0 EFF. 0 ___ 0 ___ HR. COMP. AT ___ MIN, INTERVALS O FLOW p 0 EPA O DISCHARGER O MAN. 0 AUTO. 0 TYPE---------------'-'---
□ EPA D DISCHARGER D AVG,□ INST.DEST,□-----EOUIP----------
COMPUTED FROM
SAMPLE COLLECTION
COMPOSITE GRAB SAMPLES SA~PLr:· COOc: ~
I nnn ,..,..,n_ T()r ll I
.TIME / . ·--;,~ -CYANIDE FLOW ( ) L!. · MFTA• "· .
!1
I. SAMPLE CODE
SAMPLED 6Y (SiQ) .
SE ALEO BY ( Sia I
, DATE AND TIME
l!J~v-q_ t .. /1-0
. q,?{-9() /711> PRE!'.EPVf'() I ll Use Avg-Flow for ComoositE:s ond Inst. Flow for Grabs ~ Circle. or Indicate Anol~sis and Entl'!r Norneric11I Cod~
SAMPLE CUSTODY AND SHIPPING INFORMATION
SAMPLES RELEASED TO (SIG) OR SHIPPED VIA QATE, TIME NO, CONT, NO CART.
.. "f--:""-._.,.~-·/.'::,, • ..,...-~~...-i--.~ t,,,;,-;,. .._,,~ _ .... -,_.,r,_·, /J.f"Oi> '· / / / I
I REMARKS AND SKETCHES
--:Z: 4;i.R' /\1 1
9/;T o / i,x.y I . 6-frctJeJ /,-r
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C1,;,/ 11, r r
T;,1,r
$L,m(l-'J
/,i-t'(-l.
RECEIPT· NO.
(.
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U.S. ENVIRON1v1ENTAL PROTECTION AGENCY
SI. VEIL LANCE AND ANALY:f DIVISION 1.
REGION =
ATHENS .GEC
CONTACT ________________________________
· __ u __
SAMPLE AND WASTE FLOW INFORMATION
0 MUN. 0 INO. 0 INF. 0 EFF. 0 ___ 0 ___ HR. COMP. AT __ MIN. INTERVALS O FLOW
SAMPLE
SAMPLER
FLOW
0 EPA O DISCHARGER O MAN. 0 AUTO. 0 TYPE-----------~-----□ EPA O DISCHARGER O AVG. 0 INST. 0 EST.□-----EOUIP---------COMPUTED FROM
SAMPLE COLLECTION
COMPOSITE GRAB SAMPLES SAM?Lt· COOt. l SAD NO. VO,_'"__,, ~'?0 RACTFRl'f DATE I ui,z IN7 ;,on rnn ,or-TIME I ''/'1/.r CYANIDE FLOW I l I!.
MFTA1 c """"'"'' o, -'i,"1!! N p DH "'. ~Jtlf%}~l ORG.08,G PEST TOT. CJz RES,mg/1 . ',~{~i1~1tf PHENOLS
. . . )t' .,,.,, 11.::11 SOLIDS
SAMPLE CODE Cl-'>::.:>,,, f C: ,-SAMPLED BY (Sia} . /_N, ,
SEALED BY (Sjnl ..... ,.v
DATE AND TIME , •-J, ?"!i'O 17.31 I PRESFRVED L! Use Avg. Flow. for Compos1t~s ond Inst. Flow for Grabs -,ll. C1~cle or lr.d,cot~ Analysis ond tn1,;r ~1!mencol Code SAMPLE CUSTODY AND SHIPPING INFORMATION
SAMPLES RELEASED TO (SIG} n,1 SHIPPED VIA Q'ATEr · TIME NO. CONT. NO CART. RECEIPT NO. -,.-_-~ /~~ ,,,.,-~; ., .... --./ ?'/~~/.ft) ,..,v~ _,
/ , , , -
REMARKS -AND SKETCHES
I U.S. Ery· ··RON MENTAL PROTECTIC'"' AGENCY
I . \
SUR\tt:ILLANCE ANO ANALYSIS u1VISION
ATHENS ,GEORGI I
])IV-Joo SAMPLING STATION NO. -,..C...c...c-.:..=....oc.:. ___ _
SAMPLING LOCATION-----------
SAMPLE AND WASTE FLOW INFOR1vlATION
I CONTACT
I SAMPLE
SAMPLER I FLOW
0 MUN. 0 IND. 0 INF. 0 EFF. 0 ___ □---HR. COMP. AT __ MIN. INTERVALS O FLOW Pilt
0 EPA O DISCHARGER O MAN. 0 AUTO.·□ TYPE------------------
□ EPA O DISCHARGER O AVG-0 INST. 0 EST. 0 -----
COMPUTED FROM
EQUIP--------~-
I SAMPLE COLLECTION
· -------.--,C'"'O'"'M""""'P""O""S""IT=E......,-------.,,G°"'R,.,A""8,-,S"°A'-","M-,,P""L""E"'S,---------r.s-iS7A-:-,,,,.,._;--s:--l-;.E:...-,C;<eO"'°D"'"·-t:•--:i.;;""°z-
l
SAO NO. ,"('() <~~~?' lii:..Il'Fdt.1
· DATE / Cl 11-,, I kl) I t1QD C{ln Tor
TIME / . I::: '-' I CYANIDE
FLOW· 1 I I!. ' I META1 "
I ;~:•:.:•::::,~ .llll---'ic.::-.,,.L..,.,,..~-+-----+--~--;------1L~~~;Js~i' P~ST
•. SAMPLE CODE ~ '"· ·< <
SAMPLED BY (Sia} t;.', /"';Y ·
SEALED ev· (Sin I " -'"""'-'A
PRESf.f1VEO I DATE ANO TIME· '1-Z'!·"" /.'1'.}.I'.
L.!. Use Avg. Flo"" for Comoosites ond Inst. Flow for G~obs 8. Circle or lndiccte Analysis ond Ent~r r~~1mericol Cod'!
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SAMPLES
SAMPLE CUSTODY AND SHIPPING INFORMATION
RELEASED TO (SIG} OR SHIPPED VIA_ · 01\TE , :r1ME NO. CONT. NO .CAR_T.
/.7.-/, --~ l\,..,-"7; 0/2S/r< /'JP'OO ~ ..
/.:/ / ,
REMARKS AND SKETCHES
I c~ -/ 40 'deep v:e I I
I
I
RECEIPT NO. ·
<f-. L..
I U.S. ENVIRONMENTAL PROTECTION AGENCY
SUR _IL LANCE AND ANALYSIS! . VISiON I REGION= ATHENS ,GEORGI
SAMPLING STATION NO. K\VOIO DISCHARGER O, I ADDRESS l~\l'VV\' yt'{j ", fJ.<: , S.11.MPLING LOCATION /!.Wm o1f!Ce: lJ€' f /
-ti I ' l'cl/(c{-<{ .s-, bl fie; f.-e..,,, hu, <,-,' 1,
CONTACT _________________ t---"'&~•~~~,~t~,u..LL--------------
1 SAMPLE AND WASTE FLOW INFORMATION
· I SAMPLE
SAMPLER
0 MUN. 0 IND. 0 INF. 0 EFF. 0 ___ □---HR. COMP. AT ___ MIN. INTERVALS O FLOW PR
0 EPA O DISCHARGER O MAN. 0 AUTO. 0 TYPE --,------------------
□ EPA O DISCHARGER O AVG. 0 INST. 0 EST. 0 -----EOUIP-----------
COMPUTEO FROM.
I FLOW
I SAMPLE COLLECTION
-------r--;:C,-;;O"M=P-;:O;-;Sc-;l-,;T-;:E,--.----'------;G,;R','.A;;'.Bo"cs:-;A;-;l-:-'1,.;P-;-LcE.7'S,------.;_-,I S;e-;:A-:-M-:,P"L-:::~· -,c"'0"1u:-;,t..--,.~,,.-•
SAO NO. -,j;J C,,..J-'/7/ I RACTFRl/l!
DATE ANO TIME 1·),.i•W /6 ,,, I PRES!:RVFO I Ll Use Avg. Flow for Composites ond Inst. Flow for Grabs 12 Circle or lndico1e Analvsis ona Ent'dr Nurnericol Code
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. SAMPLE CUSTODY AND SHIPPING INFORMATION
SAMPLES RELEASED TO (SIG) OR SHIP.,PEO V!A DATE 11ME NO. CONT. NO CART.
.-:.z.:::,, ->.,,~,/.-~ r . 'di-? -0"/.J ,/ft /.;}(-'-'&") 3 - -r "/ ,
REMARKS AND SKETCHES
f-uv
RECEIPT NO.
I U.S. ENVIRONMENTAL PROTECTION AGENCY , SUn .ILLANCE AND AI\IALYSIS .VISION
REGION TIC I DISCHARGER Lewis b~Y-bie .. /JJcl I
ATHENS .GEORGI
ADDRESS R\--'v 6ov f/• <,, ,, rMDoVr:-_,, i.)1p !Ii, c,, I CONTACT --, ,
SAMPLING STATION NO. P11V--_3oo
SAMPLING LOCATION. ,f'a_tg<? .. T /y,p.:,,{~ &t!V[F
I SAMPLE AND WASTE FLOW INFO?.MATION -------------
I SAMPLE
SAMPLER
FLOW
0 MUN. 0 INO. 0 INF. 0 EFF. 0 ___ □---HR. COMP. AT ___ MIN. INTERVALS O FLOW PR 0 EPA O OISCHARGER O MAN. 0 AUTO. 0 TYPE __________________ _
0 EPA O OISCHARGER O AVG. 0 INST. 0 EST. 0 -----EOUIP-----------
1 COMPUTEO FROM ___ --,----_____ .,_____ __ _
SAMPLE COLLECTION I COMPOSITE GR~.8 SAMPLES l Sl\MPU:. roof. l3. SAD NO. <YD c✓:i.c,,.~, ~AC-TFw'A' DATE 7 q/z:, /,,11 °,-,n rnr-Tnr'"
~AMPLE CODE uf/.:-j,._,c!," I SAMPLED BY (Sio > ,v,'11,.LMJu',
SEALED BY t Sial ~. U, _.,_,...
PRESFRV!':D Ill Use Avg. ~J'ow for Composites and Inst._ Flow for Grabs L! Circ:e or Indicate Anol:tsis and Enter Numerical CC'>r1e
-SAMPLE CUSTODY AND. SHIPPING INFORMATION
SAMPLES RELEASED TO (SI;.) OR SHIPPED VIA DATE, TIME I --7..,._,.,,,.-sz. ,,= '\...-, , ~:co.:-:
. . 7 --
I
I · 5 M=',,,,f c.. Pw'l.je [
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.1
~7 '>!i"Jl't., 7JPv,t:;
I ,/
REMARKS AND S
D
NO. CONT. NO CART.
._? '
I T
RECEIPT NO.
. I ')
I
REGION =
U.S. Et\"'IRONMENTAL PROTECTION AGENCY
(
SU~. ell LANCE AND ANALYSIS _,!VISION
ATHENS ,GEOR<
CONTACT _________________ +I---------------------
SAMPLE AND WASTE FLOW INFORM.l),TION
!• ~
SAMPLE
SAMPLER
FLOW
0 MUN. 0 IND. Q INF. 0 EFF. 0 ___ □---HR. COMP. AT ___ MIN. INTERVALS O Fi.OW F
0 EPA O DISCHARGER O MAN. 0 AUTO. 0 TYPE __________________ _
I
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I
SAD NO.
DATE
0 EPA O DISCHARGER O AVG. 0 INST. 0 EST. 0 -----
COMPUTED FROM.
SAMPLE COLLECTION
COMPOSITE GRAB SAMPLES
EQUIP----------
SAMPLF CODt:. ~
TIME / f'.64..4 · CYANIOE
FLOW ( I I!. METALS
I !_T~_:_._?:_1:_A_:_:_:_:_g_~-1~~-l-'---L-1~_~~--+----~1------+-----r:~~~~~~~;~~~~~~;-~_£_sT __
I SAMPLE CODE
SAMPLED ·sy (SiQ)
, SEALED BY (Sin1
D~-"~•"\,\C,<;. I
. ))IC//.L-'<.'v;r./ ;
I
~ PRl::SC-Rv;:::o I DATE AND TIME
L!. Use Avg. Flow for Composites ond Inst. Flow for Grabs I.! Circle or lr.dico1e Anolvsis ond Ent~r Num~ricot Code
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SAMPLE CUSTODY AND SHIPPING INFORMATION
SAMPLES.RELEASED TO (SIGJ..QR SHIPPED VIA I MTE, TIME NO. ·coNT. NO CART.
✓~/ ::>J ;,-_::;.t..,------=::""~ _/ r-'~ I Yl ,);,'/1'-V OYOO .:..~-
/-: / ✓
4..(c
Appv-0'1-, ~ {t1c..\-_!.P~\ \
p,Wiuf_ 5 /1l-41 ,
REMARKS AND SKE:CHES / .
2, aei-:a c.5 J Iv { d, 1 f cltJ,S ~ 6i' n1
RECEIPT NO.
9
I
u.::;. ENVIRONMENTAL PROTECTION AGENCY sr 'VEILLANCE AND ANALYS DIVISION REGION IlC
ATHE.NS .GEC DI s CHARGER --~k~r1....,_i--'-'t_-S_C_..o_ ... _s._. '-~-·----• SAMPLING STATION NO. _/(~·lJQ 20
SAMPLING LOCATION -c;,:j .2. Wei/ /ltw},L,s,,".;;Ja±-t IJJ /!,:.;tic!;/[ 1 __,.,. /4.-,c,J ,J
ADDRESS ___ ~1"'-"-.LL~5~·u~~-l~/~f,_:..;tJ~~~C=c~------I
SAMPLE AND WASTE FLOW INFORMATION
SAMPLE 0 MUN. 0 IND: 0 INF. 0 EFF. 0 ___ O ___ HR. COMP.AT ___ MIN.INTERVALS O FLOW I SAMPLER 0 EPA O DISCHARGER O MAN. 0 AUTO. 0 TYPE _________________
_ FLOW 0 EPA O DISCHARGER O AVG. 0 INST. 0 EST.□-----EOUIP----------COMPUTED FROM
I SAMPLE COLLECTION
COMPOSITE !<711 i.✓ ')J.J. / ;!.... GRAB SAMPLES SAMPU: . coot I SAD NO. -112"-.lfl>
RAtTi::-t-pA1
DATE I '· 11,-<1. ... .. ~~ rri" yr,,-TIME I
CYAN•::,E FLOW { J I.!.
MF' Tt-.• s ;:""""""' ocr '} '?
N p 7,~
ORG 08G PEST
TOT. Clz RES.mg/I <;:t.~Ji>'.:"~!ii-]~}J;:::~x:;.:
PHFriOLS . -~~r.~ .. --?_jili~}~li~ SOLIDS SAMP.LE CODE (J W, J..< IC <" ,(, SAMPLED BY (Sio J t<J~A SEALEO BY 'ISiol -· DATE AND TIME . (-2 ~ · W '/?6"0
PR:C:S:F.'lV"D
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L!. Use AvQ. Flow for Compos1t~s ond Inst. flow for Grabs L!. Circle or Indicate Analvs•s and Enter N1mencol Code
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SAMPLE CUSTODY AND SHIPPING INFORMATION SAMPLES RELEASED TO (SIG) OR SHIPPED VIA D-'<TE. TIME NO. CONT. NO CART. , /.Z.. .. , .... ~ ' ----~---7/~',7.f-: ?'Po-, . -,; , ., ..
REMARKS AND SKETCHES
.f.ov
RECEIPT NO.
G
I U.S. E1'1"IRONMENTAL PROTECTIC'"l AGENCY ,. (
SUR v C:1 LLANCE AND ANALYSIS ...,IVISION I REGION=
· DISCHARGER__._k~~~•o~.n&~ii-~~--------~~
l'\,\.'.Jvf\0S,< i\ le . tJ .c.,,
SAMPLING
SAMPLING
ATHENS ,GEORG
STATION NO. /<h}-03()
LOCATION :fr b lilf/J sf.,,e1 sl,,-.,1 I ADDRESS
CONTACT _ __._e~~~t~-~3~i•~A1'--'--'-\--l,,,_ _________ +-------------------
I _________ ___J___ ________ _
SAMPLE AND WASTE FLOW INFORMATION
I SAMPLE
SAMPLER
0 MUN. 0 IND. 0 INF. 0 EFF. 0 ___ □---HR. COMP. AT ___ MIN. INTERVALS O FLOW PF
I FLOW
0 EPA O DISCHARGER O MAN. 0 AUTO. 0 TYPE-------------------
□ EPA O DISCHARGER O AVG. 0 INST. 0 EST.□-----EOUIP-----------
COMPUTED FROM
I SAMPLE COLLECTION
-------...... ..,C,..O,..M..,..,.?""'o-s-1""T"'E--.---------,G,-,R,..A,..a""· ...,,S,..A,..~..,.A"'P.,.L""E"'s--------...S~A""°M'"P""L-F-""'C""'o""'D'"'• E~~-
SAD NO. ~ o (.;?,..,t..i.7.J. ~Af'TS:-RIAI
DATE I TIME
FLOW f
I C1/J,-;r,/f<n ·= ~~-Tnr
/ ' "•-,::,,_, CYANluE
l I!. -METAL<:
· SEALED BY ISinl ,u·.-v--
. DATE AND TIME · 1 ,· J-~ -;,,; 16:J., PRE~EP.V•D It!. U~e Avg. Flow for Comoosite~ o~d. Inst. Flow for Grabs t! Circle or Indicate Analysis and Enter Numericol Code
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_ SAMPLE CUSTODY AND SHIPPING INFORMATION
SAMPLES. RELEASED TO (SIG) OR SHIPPED VIA D,ATE, TIME fJO. CONT. NO CART.
_;...0--✓;.-.,; _/..,_ •J->-> "?'/..?_; ,,,;; 0.(-r.r, -3
✓ 17 -,
REMARKS AND SKETCHES
f~l) ~~-tlo<J fJ.,,M~
S e-e. v.Jo d< f '"·" /vfrvf far .Sl<e-f"<-1--.e..s: •
RECEIPT NO.
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Name of
.System:
Address:
, '
( TE LABORATORY OF PUBLIC HEALTH/
DIVISION OF HEALTH SERVICES
N.C. DEPARTMENT OF HUMAN RESOURCES
P.O. BOX 28047-306 N. WILMINGTON ST., RALEIGH 27611
ORGANIC CHEMICAL ANALYSES ,-PUBLIC WATER SYSTEM
ZIP
Complete All Items Above Heavy Line
{See Instructions on Reverse Side)
. (404-) ,54& -3.30 O
· Be :9"v-'--'Vif1-ff'
Source of Wa~~~: __ ..... ~-•"
( ' ) ···t;;ound •·
_ ( · I Surface
.. ·,
' (
(
Ref. 7
Both
Purchased -----------------------'-L....,.~, l ~ Coun_ty: -----'''---------------------l
IRepi~ To: _ .. L=c-=-c ,_,~--',.-+--..,_,/)'--L....,;'-P.-""'--'r_,__r_,· ''-''---------'--! /.. ,
i! ;j_
/
L..,,,. .... ,. r~ ZIP
teleph<>ne Numbe~----___,_(_..,..._,__) _________ -_-_--_-_--_--_---------1
.. Collected By:· _l ~,.. -.._, /). /J< "r ,--. Jate Collected::..· ---'-7,__~..,)~?'------"'&-___,c,'--__ •..,T.,,im"'e"':'---'3"'--'-;-"3:__;6:::..._ __ '-'-~P-'-'M<'I
:::'
.~ocation Ot Sampling Point: -·····
· ·Address where sample)"as collected) _
. J.u~ f ~ -. ,,-. '"1/, . :;tj.. .1 Rem.irks:: .) ('I. "~/ -c. :· ... -·-' .. ,.-I,,-A,t:-~--l.1 .. 11--/-'h.: .. ·i-~··-·· -5'".zo/·
State Drinking Water Parameters (Required)
< ----
--(CHLORINATED HYDROCARBONS:)
Endrin I lindane
Methoxvchlor
Results·
.. mg/I
mg/l
mg/I
.
5
4
3 I Toxaohene HLOROPHENOXY~~,=,=='------1------,c_+--'-+ mg/I 4
mg/I
I
IHS ~o,m 2G6S 7/79
.!boratory
2,4-D . -·
2 4,5-TP
3
. mg/l 4
I
Source of Sample: __ _ 'c . i Dlstribution Tap
Type of Sample:
( ) Raw (
Type of Treatment:
(-· I · None --(
( · ) -Chlorinated· . (
( ) Fluoridated (
( ) Filtered ( ( I Alum (
Type of Sample:
. ( ) Regular (
( I Check (
)
)
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House Tap
Well Tap
Treated -
Lime··
Soda Ash
Polyphos_phate
Water Softener
Other
·----
Private ..
Special-
WATER SYSTEM 1.D. NUMBER (COPY FROM MAILING LABEL_
o □-00-:000
Optional Parameters (List as nee"ded) ,;..,'
-Results
VcP n. o 7'7 ,-i ,-7,rn ·-·~·~. -
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;.-_
Mildred A. Kerbaugh
Director
I ._ ...
'. ·-· --
E LABORATORY OF PUBLIC HEALTH (
I DIVISION OF HEALTH SERVICES
N.C. DEPARTMENT OF HUMAN RESOURCES
P.O. BOX 28047 -306 N. WILMINGTON ST., RALEIGH 27611
I ORGANIC CHEMICAL ANALYSES -PUBLIC WATER SYSTEM
I
ystem: ' .-. ~✓,er (
'
f-
A_ddress: •'-/ . //4 -· 'I'",-.<' .... • <=
.....
(unfy:
l,.J..,.
e~rtTo: fer~---.. ) • A •-,r-..._ ;\ ,, /
tddress:. p . ;-?;J, J? ,. .. 2 I? -·~ /;~ -
'
. (,,//,/ )YA--...,-. l,.;~, 1 ...
Je;ephone Numbe·r/·/
.. ·-·· . I -
llected By:· L r, . -• - . __ 1) l',-,.-r~ , , ..
ate Collected:· 1 ..:·1 , __ F./, . -~ Time:
loCation of Sampling Point:
Address where sample was collected)
ZIP
ZIP
Complete All Items Above He·avy Line
(See Instructions on Reverse Side)
.
..
Source of Water:
( .. ) .. Ground.,
( ) Surface
S<>urce of Sample:
( ) Distribution Tap
.·. ·-' . ..
Type of Sample:
( ) Raw
Type of Treatment:· ..
( ) None:· .....
( ) Chlorinated ·
( ) Fluoridated
AM ( ) Filtered
"f:oo .PM ( ) Alum
· Type of Sample:
( ) . Regular
( ) Check
·-·. _,,_. . (
. (
. :• .,,. .-,.
(
.. . I-
(
. .. --··-. (
(
(
.(
(
(
(
.
) Both
) Purchased
. .
) House Tap
) . Well Tap
) . Treated
i Lime
) Soda Ash
) Polyphosphate
) Water Softener
) Other
) Private
) ' Special
· _wcf-e~ 5"'-,,,.:.//e . ;:;L_j_
. . ... WATER SYSTEM 1.0. NUMBER (COPY FROM MAILING LABEL) ,•marks: · · · · . /.v e/l ' i·:,· _/1eJ/:~-R..-s . ./,,.,.,.
'. lt~t-~ Drinking Water Parameters (Required)
· Results
(CHLORINATED HYDROCARBONS:)
I · Endrin
Lindane
.
Methoxvchlor
' Toxaohene HLOROPHENOXY::i:/
I
. ,ate Receiv~d
'ate Extracted
lamments:
IHS F:orm 2RBG
L,1boratory
7/79
2,4-0
2.4 5 TP
mg/I 5
mg/I 4
mg/I 3
mg/I 4
mg/I 3
mg/I 4
□□-DD-:-00 □
Optional Parameters (List as needed) ·
Results · rrr~ ·,,, "/...c.
,·
-
o. f'J/0/1I,1m
/I
Mildred A. Ki!r!J'"ugh
Director
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i. 'E LABORATORY OF PUBLIC HEALTH
DIVISION OF HEAL TH SERVICES
N.C. DEPARTMENT OF HUMAN RESOURCES
P.O. BOX 28047 -306 N. WILMINGTON ST., RALEIGH 27611
ORGANIC CHEMICAL ANALYSES -PUBLIC WATER SYSTEM
.. .tame of l(ystem:
:-.
· 'Address:
Ir,,_,,,,,,..,..,,.,, , ,
.1'1c-rr , u, /,/4.
tddress: ir ~ 11:
s,,1, J I /4 . .,'
ZIP
ZIP
Complete All Items Above Heavy Line
(See Instructions on Reverse Side)
Source of Water:
A·· ► :. Ground 0·:
/ ( ) Surface
,
...... ·' ~-·-·. ·, ( -. )
... ( ) ..
Source of Sample: ( I Distribtiticin·T~~., '
,: ·;:_ .. ~ ,:_.;_.. -. ·-
( )
.... c, ... ( ·,, I· ..
Typ~ of Sample:
( · I Raw ( )
Type of Treatment:
· .. ( .· .. ) · .· None· ( )
( ) Chlorinated ( )
( ) Fluoridated ( ) ilected By:· /j ,. ~' ~-,1, /::/. ,.'-,: -
·-., ~to Collected:· :7~-2 ;c J/, Time: t/ ;~b
( ) Filtered
( ) Alum
( )
.. ,. ( ) ,.. .
Type of Sample:
( ) Regular ( )
( ) Check ( )
Both
Purchased
House Tap
Well Tap
Treated
Lime
Soda Ash
. Polyphosphate
Water Softener
Other
Private
Special
·· · , . WATER SYSTEM 1.0. NUMBER (COPY FROM MAILING LABEL)
□□-□□-□□□
-Optional Parameters (List as needed}
-..
. Results
(CHLORINATED HYDROCARBONS:)
.•. Endrin mg/I 5 . (--t p: L L-{:;) .. 0 tu /lf}PJ >-··.-
-"L'"in,_,d,_,a,,.,nece _____ +----'-----1""-'4-='-+------------11---------mg/I 4 -
.... -"M-"e,.,th""o,,,xec:Vc,<Ccch,.,lo,.,r ___ +-______ -"'-'+''-+--------'-------'1---------1 Toxaohene
mg/I 3
HLOROPHENOXY~~,,-,==~-~-+------'"-f-'-+-----------+---------mg/I 4
mg/I 2,4-0
I 2 4 5-TP mg/I
I 7 .... ..., s--v ate Received -~--~· r'~.--)~--'·~·'..c...---Date Reported
7 ;,(✓ y;, Date Extracted--~:• __ ,,. __ -~f':_· -~c",,_·'-' ____ Date Analyzed
lmments:
IHS Form 2886
Laboratory
7/79
3
4 r ..
,jl.J
Mildred A. Kcrbaugh
Director
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.( '·rE LABORATORY OF PUBLIC HEALTH (
DIVISION OF HEAL TH SERVICES
N.C. DEPARTMENT OF HUMAN RESOURCES
P.O. BOX 28047-306 N. WILMINGTON ST .• RALEIGH 27611
ORGANIC CHEMICAL ANALYSES -PUBLIC WATER SYSTEM
rystem: , ' t'.,,, Y.Jt.i-Cf" I
/ /,~ .. //.;_ Address: ,ry,,.__ .-r. '!"
County:· /ur )--
LeportTo:
, J) fe,rr-7. L )/,-.-· .· -, .. , .. ,,, .
!> ti. P, /,(,. . ,'1 ,._ 2d rddress: · ;,. , /
)vi/.✓ /IA.., l....i, r 7'.,...
··-·.~_,-;i •:: . . .
... I ) -
ZIP
Complete All Items Above Heavy Line
(See Instructions on Reverse Side)
..
Source of Water:
( ) · Ground.
( ) Surface·.
.. ._Source.of Sample:.
.
.. ..
...
( ) Distribution Tap
..... . . . -~ : . . .
Type of Sample:
( ) Ral.i'."
ZIP Type of Treatment:
. ......... ( .. ) ::NonEr · ·
( ) Chlorinated
telephone Numbe;;:· .
~I J. ;J, ,, ,.. -. ( ) Fluoridated Collected By: · ~ r,. -, ( ) Filtered . /
-~ ( ) Alum '. J.-.2 )-P,·, ~ '.?c'. ·ate Collected:· -· ..:.;1...-Time: . .
Type of Sample:
__ ocation o·f Sampling Point: . · ( ) Regular
Addres_s where ·sample_ was collected) . ( ) Check
;,
. .. . ( .. f
(. )
.. ., ...... , .,-'.·
( ) . " ... ( .. )
( )
..
.. ·-· ··-( )
( )
( )
( )
. ' ~ ( )
..... ··-··
( )
. ( )
..
Both
Purchased
House Tap
Well Tap
Treated
Lime
·Soda Ash
Polyphosphate
Water Softener
Other ...
.
· ~rivate ..
Special
····Si··~·.:/.-#= .1 WATER SYSTEM 1.D. NUMBER (COPY FROM MAILING LABEL) R. rk .. e ,1~-e-.--_···,J"'-........ / ema s: -
J',; //.· , ! e . , ;. .. f~.,J □□-□□-□□□
State Drinking Water Parameters (Required) Optional Parameters {List a~ needed) .. ... '. -I . • . -., . .. .. Results ·Results
(CHLORINATED HYDROCARBONS:)
mg/I ftp /)J.4-. · Endrin 5 I ..
Lindane ... mg/I 4 ..
Methoxvchlor mg/I 3 I Toxaohene mg/I 4 . :HLOROPHENOXY!;:1 . 2,4-D mg/I 3
mg/I .. 2 4 5-TP 4 r .. I
late Received -~7_-~]~~>~--·~,--h.J_· ___ Date Reported -~r,;.f--_~~-1_· ~,1°~·--~cJ_✓o_·_ Reported By .cJ~-;--c..-_·';/4~,~-·,4_·•'_· ~;~/i~i~~t2._/_;~t,}:--~"-r __
· Date Extracted -----•-•----,---□ate Analyzed Laboratory Number
lomments:
l ~S ~orm 2886 .aboratory
1/79 Mi!dr!Xl A. Kerb<!L:gh
Director
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£ .. CE LABORATORY OF PUBLIC HEAL TH
DIVISION OF HEALTH SERVICES
N.C. DEPARTMENT OF HUMAN RESOURCES
P.O. BOX 28047 -306 N. WILMINGTON ST., RALEIGH 27611
ORGANIC CHEMICAL ANALYSES -PUBLIC WATER SYSTEM
ZIP
Complete All Items Above He'a·vy Line
(See Instructions on Reverse Side}
Source of Water:
· C . °r.. Ground
( ·). Surface
. Source of Sample:_ . . .....
(-J Distribution Tap
•::·:
'
..
( )
... ( )
( ) ..... ·. ·;::_. --.·(·· )
Type of Sample:
( ) Raw
.. ..
Both-
Purchased
House Tap
Well Tap
Treated
telephone Number.··_·_·~( __ ··_··~) ___ \_·· __ -__ ··_·-_· ·-------1
Type of Treatment:
· ( ) .. None
( ) Chlorinated
··-·· ··· ( ) Lime
.... ( ...... ) -.. Sod~Ash .~ ..•.... _-.., ....... ~~7':•·-. . ,• . Collected By: . L ~ .-r --. j) _ f.._,., .-( ....,,
t.l~te Collected:· )-2 1 •-k{i Time:
( ) Fluoridated
( ) Filtered
( ) Alum
-·-·· ·-"-( J .----Polyphosphate
. --· :· ·.{'.'· 1: ~ ·::.cwarer Softener
,;~, : • • ,< C ~ i~.~:~ Qther-:-:::c~•
··----Type of Sample: ..-. __ ._..,;:.~_.:.::.=...;:.;.=-:_:,,:,~~--~~ .
... ( ) Regular
( ) Check -·.·;):~if~_:::··~-~:;;;:;;i1:~5'i-
WATER SYSTEM 1.D.·NUMBER (COPY FROM MAILINGT:ABEL)
□□~□□-□□□
State Drinking Water Parameters (Required) Optional Parameters (List as needed) .,
Results Results
mg/I 5 ··f(Jf/
mg/I 4
Methoxvchlor mg/I 3 I Toxaohene HLOROPHENOXY~~:=1==~~--+------~
2,4-D
mg/I 4
mg/I 3
I 2 4 5-TP mg/I 4 -..
late Received ___ 7_-__ -_7_ .. _?_-_r_<V ___ Date Reported __ ,er_· _-_.,....._7_)c_·_ .. _-~v-'v'--_ .. Reported 8y9c~1. ~:2"_.,,_.,L.
· Date Extracted _____ .,-_______ Date Analyzed
lmments:
1
S Form 2886
~boratory
7/7CJ
___________ laboratory Number
Mildred A. Kerbaugh Oirect0r
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KEYSTONE
[\\'IROS~1[S"T AL H[.SO(HC[S, !SC.
436 Seventh ,\venue, Suite 1940, Pittsburgh. PA 15219
CERTIFIED MAIL-RETURll RECEIPT REQUESTED
January 6, 1937
State of ilorth Carolina
Dept. of ilatural Resources and
Community Development
3800 Barrett Drive
P.O. Box 27687
Raleigh, ilorth Carolina 27611-7687.
ATTENTION: ~R. E.L. BERRY
Ref. 8
SUBJECT: llonitoring vJell Construction Permit
91-0255-Wll-0236
Dear l·lr. Berry:
On October 27, 1986, your office issued the above-referenced permit to
Koppers Co., Inc. for construction of monitoring t·1ells at our facility
in 1-!ake County, iiorth Carolina. These \'/ells were constructed by
1-!ilson Engineering Associates under the supervision of Steven A. Colton.
! have enclosed the following information (Oncerning these wells:
o rJell Construction Records (using Form G\,-1).
o He 11 Boring Logs. ·
o Analytical results of soil and groundwater samples.
If you have any questions on this subject, please contact me at this office.
Thank you for your cooperation in this matter.
I 111S/ bj
Enclosure
cc: J.R. Campbell
S. Colton
C. Cramer
t-1/0 attachments
Sincerely yours,
llartin Ii. Schlesinger
Assistant Pro9ram l•lanager
Previously Operated Properties
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I KEYSTONE
ES\'IRONMESTAL RE.SOURCES, INC.
Ref . 8, Encl. 1
----------------l------440 _Co ll_e g e P_a r k _Dr. ,_Mo _n roe VI_· 11e, _PA_I514_6 ____ _
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OATH CAROLINA DEPARTMENT OF NATURAL RESOURCES AND COMMUNITY DEVELOPMENT
DIVISION OF ENVIRONMENTAL MANAGEMENT -GROUNDWATER SECTION
P.O. BOX 27687 -AALElGH,N.C. 27611, PHONE [phone]
FOR OFFICE USE ONL y
Quad. No. _______ Serial No. ___ _
I WELL CONSTRUCTION RECORD
IILUNG CONTRACTOR wi/so" [.,,3,neer,., A5so,,~tes
DRILLER REGISTRATION NUMBER ___ S_l?_t _____ _
~.lELL LOCATION: (Show sketch of the location below)
earest Town: JVlo,-r,s v,/ft.} JV C.
e.rs R.oa.cl f' ,!/
cad, Community, or Subdivision and Lot No.)
21fWNER l'\oppers Co . .:rnc._
IIDDRESS [ .,,~ine•re<I. W99J S,,sfer1 s. R.t:. 5'-t
,1,1 //" (S1reet or Ro~te No.) ' ~orr,sv• c. ;v.c. 11 City pr Town Stale Zip Code
311,ATE DRILLED 'R/7/86 USE OF WELL Monitor,~.,
'· TOTAL DEPTH 2 S: CUTTINGS COLLECTED· CiaYes o No
sloES WELL REPLACE EXISTING WELL? D Yes [i;l"No
5. STATIC WATER LEVEL: 13,30 FT. R,.above TOP OF CASING,
I o u, below
I TOP OF CASING IS · 0 FT. ABOVE LAND SURFACE.
7 IELD (gpm): . METHOD OF TEST _______ _
9. WATER ZONES (depth): ________________ _
l.,HLOAINATION: Type ____ _ Amount
TASING: Wall Thickness
Oeoth Diameter or Weight/Ft. Material
From 0 To ~ FI. 2" PVC.
I From To FI.
From To Ft.
.. GROUT:
I Depth Material Method
From 0 To 2 Ft. Ce....,et-it ,i-Be»fon,te P.wder
From 2. To
-.,CREEN:
't F1. Se,.J -Geatohite Pe 1/efs
Depth Diameter Slot Size Material -
I From 5 To 2) FI. 2 in.0.010 in. eve
FrJm To FI. in. in.
• From To Ft. in. in.
·, RAVEL PACK:
Depth Size Material
I From Lj-To 2) FI. 6 I{ So..r-.d..
From To Fl.
Lat. Long. ____ Pc--
Minor Basin _____________ _
Basin Code _____________ _
Header Ent. _______ GW-1 Ent. __ _
ST A TE WELL CONSTRUCT/ON
PERMIT NUMBER: 'II -02.~S--WA-02.3h
County: Wcd{e
Depth DRILLING LOG
From To Formation Description
----=s-=-ee=--.c°' tf"' c J,, e J. · £be.et
II additional space is needed use back al le.rm.
LOCATION SKETCH
(Show direction and distance from al least two State Roads,
or ·other map reference points)
See. 5 ,te_
1
IREMAR~SDO HEREBY CERTIFY THAT THIS WELL WAS CONSTRUCTED IN ACCORDANCE WITH 15 NCAC 2C, WELL CONSTRUCTION
STANOARDS, AND THAT A COPY OF THIS RECORD ~V..i§.EEN PROJ:1.DEDjf5> ]Ji_fWELL OWNER. /
~CA~ 12/2326
I. t Revised 11 /84
SIGNATURE OF CONTRACTOR OR AGENT DATE
Submit original to Division ot Environmental Ma~agement and copy to well owner.
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MONITORING.WELL LOG
PROJECT Raleigh, NC WELL NO. MW-1
DRILLING METHOD Hollow Stem Auger GEOLOGIST S. A. Colton ----------
DRILLER Soil Testing Services DATE 8/7/86
GROUND ELEVATION __ _ GROUND WATER DEPTH (ft):
TOP OF WELL _____ _ AT COMPLETION. ____ _
DEPTH OF WELL (ft) AFTER HOURS
CASING MATERIAL 2" PVC SCREEN 20' of 0.010" slots
DESCRIPTION
Brown, clayey SILT, tr f sand, tr weathered rock
fragments, tr m quartz fragments, tr roots (0-1.5')
Mottled Brown and gray silty CLAY, tr f sand,
tr f rock fragments.
Red/brown Clayey SILT (weathered bedrock), tr
siltstone fragments, tr f sand
Bottom of Boring -26.5 feet
GRAVEL PACK
BENTONITE
BACK FILL
CONCRETE
· SCREEN ----------
CONSTRUCTION
...
: ·•.
. .
. .. . . ·
•, .. ....
. •,
.. '. ',, ·.' ' '
•.··
.·: · . •,••
. . :
,·,•
SHEET ___ OF __ _
IRTH CAROLINA DEPARTMENT OF NA T\JAAL RESOURCES AND COMMUNITY DEVELOPMENT
DIVISION OF ENVIRONMENTAL tMNAGEMENT -GROUNDWATER SECTION
P.O. BOX 27687-RALEIGH.N.C. 27611, PHONE (919} 733-5083
I WELL CONSTRUCTION RECORD
FOR OFFICE USE ONLY
Ouad. No. _______ Serial No. ___ _
Lat. _______ Long. ____ Pc __
Minor Basin _____________ _
Basin Code _____________ _
Header Ent. _______ GW-1 Ent.-
DILLING CONTRACTOR W,/50>1 ["131neet,") Assoe1a.1es
DRILLER REGISTRATION NUMBER __ .::.g__::~_/-'-------
STATE WELL CONSTRUCTION
PERMIT NUMBER: 'fl -02.55""-WA-D23b ,M\v'-2
~,ELL LOCATION: (Show sketch of the location below)
arest Town: ;Vlo,-r,s v,//f) ;V C.
ers fl.oa.cl. f' ,If
cad, Community, or Subdivision and Lot No.)
. 11wNER K'oppers Co. S "c..
11:>DRESS I: "'~1neereJ. WoqJ 5tsfe1+1 s. R.t:. 5'f
,111 lie (Street or R!)9te No.} ' . L."..!orr,sv, ;v.c.
l City/or Town Stale Zip Code
. TE DRILLED g_ 7/,U USE OF WELL Monitor,~)
. TOTAL DEPTH 2Lf:. 5 CUTTINGS COLLECTED Gl'Yes O No
.• ES WELL REPLACE EXISTING WELL? □ Yes w"No
. STATIC WATER LEVEL: J',.OO FT. 0 above TOP OF CASING, uYbelow
I TOP OF CASING IS 2 FT. ABOVE LAND SURFACE.
·. ELD (gpm): ______ METHOD OF TEST _______ _
. WATER ZONES (depth): ________________ _
. lLORINA TION: Type _______ A_m_o_u_n_t _______ _
J .• ASING:
I Depth
From _Q~_To S"
Diameter
...., "
Wall Thickness or Weight/Ft.
Ft. __,,._::::._ __
Material
PVC.
I From To ___ Ft. ___ _
From ----TO Ft.----
1.IGROUT: Depth
From __ 0 __ To 2.
From _.;c2:::__ To lf-
2.CREEN:
Depth
From _~ __ To 2 If-
Material Method
Ft. Cer,,e;,t .-8e1ifon,te Powder
Fi. Seo.I -Gentnite Pellet's
Diameter Slot Size Material
Ft._2=-_in.0.010 in. PVC I Fr.Jm ____ To ___ FL ____ in. ___ in. __ _
I From ____ To ___ Ft. ____ in. ___ in.
3 RAVEL PACK:
Depth Size Material , I From _'f~ __ T o 2 Y: '.J° Ft. _ _,6"--11
__ _
From ____ To ___ FL _____ _
So.nd.
County: We.Ke
Depth DRILLING LOG
From To Formation Description
If addi1ional space is needed use back ol !Grm.
LOCATION SKETCH
(Sh_ow direction and distance from at least two Slate Roads,
or other mao reference points)
see s,-fe
:
!4 REMARKS:----------------------------------------------1 I DO HERESY CERTIFY THAT THIS WELL WAS CONST UCTED IN ACCORDANCE WITH 15 NCAC 2C. WELL CONSTRUCTION
STANDARDS. AND THAT A COPY OF THIS RECORD HA PRO\?CJ=D T?)TW, ~ELL OWNER. / /
.-::: U. ~ 12.1 231..J~
J SIGNATURE OF CONTRACTOR OR AGENT 'DATE
• 1 Revised 11/84 Submit original to Division of Environmental Management and copy to well owner.
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MONITORING.WELL LOG
PROJECT Raleigh, NC
DRILLING METHOD Hollow Stem Auger
WELL NO. MW-2
GEOLOGIST S. A. Colton
DRILLER Soil Testing Services DATE 8/7 /86
GROUND ELEVATION ----GROUND WATER DEPTH (ft):
TOP OF WELL AT COMPLETION -----------
DEPTH OF WELL (ft) AFTER HOURS
CASING MATERIAL 2" PVC SCREEN 19' of 0.010" slots
12
DESCRIPTION
Brown clayey SILT, tr f sand, tr siltstone fragments,
roots 0-1.5', 9-:-10.5'
Mottled gray /green/yellow /orange clayey SILT,
(weathered bedrock)
Bottom of Boring -26.5 feet
GRAVEL PACK :~•.:.•:·
BENTONITE
BACK FILL
CONCRETE
· SCREEN ----------
CONSTRUCTION
·. · . . .
···• . ...
•. ·:
• ..
.-· ..
.. .
'.•• . ·• -:
. -:·
... . .. .· . . .
.:.
·.•.
. : .
SHEET ___ OF __ _
IRTH CAROLINA DEPARTMENT OF NATURAL RESOURCES ANO COMMUNITY DEVELOPMelT
DIVISION OF ENVIRONMENTAL MANAGEMENT -GROUNDWATER SECTION
P.O. BOX 27687 -RALEIGH,N.C. 27811, PHONE [phone]
FOR OFFICE USE ONL y
Ouad. No. _______ Serial No. ___ _
I WELL CONSTRUCTION RECORD
JLLING CONTRACTOR l,,.✓,/so" f.-i81neer 1") Assoc,~Tes
~LLER REGISTRATION NUMBER g 'if/
L WELL LOCATION: (Show sketch of the location below)
11:•rest Town: ;Vlcr-r,s v,/h) ,,,v: C.
llf o ooers Roa.cl. /Vlorr1s v,lk,
(Road. Community. or S~bdivision and Lot No.)
!. gwNER I'\ o ppe rs Co. X .-.c...
l:iDREss f .-,~mevreJ. Wo9J Stsfe,.,, s. R.t:. 5't
AJ1 /I; (Street or R!)j,te No.) ' l..."...!orr,sv• tc. C:!,_C. I City r own State Zip Code
•. "A TE DRILLED II 'i/6 USE OF WELL Mon ito,., ~.,
·· lfTAL DEPTH 15'. ' . CUTTINGS COLLECTED U1Yes O No
,. lflEs WELL REPLACE EXISTING WELL? □ Yes [i;l"No
,. STATIC WATER LEVEL: 7. '/'f FT. □,above TOP OF CASING,
2. f>!' below I TOP OF CASING IS-'"----FT. ABOVE ~AND SURFACE.
·. ELD (gpm): ______ METHOD OF TEST _______ _
I.IATER ZONES (depth):-----------------
·. CHLORINATION: Type Amount
O .• ASING: Wall Thickness
Depth Diameter or Weight/Ft. Material
From 0 To 5".~ FI. 2" ('Ve
I From To FI.
From To Fl.
Depth Material Method
·,.,ROUT:
From ·_-"0'---To /. ~ Fl. ce ..... ei,t ,t-/3e,,toh1te P.wder
Ft. Seo.I -6eafo~ite. Pellet's I From
2. CREEN:
I From
/. 5". To 3, !;
Depth Diameter Slot Size Material
To /).f;' Ft. 2 in.0.010 in. PVC..
Fr:,m ____ To, ___ Ft. ____ in. ___ in. __ _
I From ____ To ___ Ft. ____ in. ___ in. __ _
3 RAVEL PACK:
Depth Size Material
From 3.~ To/S':5Ft. 6" --~---So..,J.
From ____ To ___ Ft.~-----
•,EMARKS:
. I DO HEREBY CERTIFY THAT THIS WELL WAS CONST
STANDARDS, AND THAT A COPY OF THIS RECORD HAS
Lat. Long. ____ Pc __
Minor Basin _____________ _
Basin Code _____________ _
Header Ent. _______ GW-1 Ent. __ _
STATE WELL CONSTRUCTION
PERMIT NUMBER: 'II -02.S"S--I-IA-0231,
County: We..){ e
Depth DRILLING LOG
From To Formation Description
Jf additional space is needed use back of form.
LOCA TfON SKETCH
(Show direction and distance from at least two State Roads,
or ·otheir map reference points)
see .sde v-,,«p
I SIGNATURE OF CONTRACTOR OR AGENT
GW-1 Revised 11/84 Submit original to Division of Environmental Management and copy 10 well owner.
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MONITORING.WELL LOG
PROJECT Raleigh, NC
DRILLING METHOD Hollow Stem Auger
WELL NO. MW-3
GEOLOGIST S. A. Colton
DRILLER Soil Testing Services DATE 8/11/86
GROUND ELEVATION. ___ _ GROUND WATER DEPTH (ft): GRAVEL PACK :~•.:.•:"
TOP OF WELL_· ____ _
DEPTH OF WELL (ft)
AT COMPLETION -----
AFTER HOURS
BENTONITE
BACK FI LL f;rJ:};'(
CONCRETE
. SCREEN ----------CASING MATERIAL 2" PVC SCREEN 10' of 0.010" slots
DESCRIPTION CONSTRUCTION
Yellow/brown SILT, tr f sand, tr frock fragments, roots
Brown/red to gray/purple clayey SILT, tr f sand
Gray/purple to brown clayey SILT,
(weathered bedrock), tr f sand
Bottom of Boring -21.5 feet
..
SHEET OF
..
.·.·.
... ...
:·.
•' .. ...
------
IRTH CAROLINA DEPARTI-AENT OF NA TIJRAL RESOURCES AND COMMUNITY DEVELOPMENT
DIVISION OF ENVIRONMENTAL MANAGEMENT -GROUNDWATER SECTION
P.O. BOX 27687 -RALEIGH,N.C. 27611, PHONE [phone]
FOR OFFICE USE ONL y
WELL CONSTRUCTION RECORD
DILLING CONTRACTOR W,/so" [.,,,,1neer,..,) Asspc.1~tes
~ILLER REGISTRATION NUMBER _"_...::g...c~c.-1------
. WELL LOCATION: (Show sketch al the location below)
••rest Town: JV10,-r15 v,/{r.) JV C.
!I( o one rs R.oa.d.. /Vlo(r',s v,lk,
(Road, Community, or S~bdivision and Lot No.)
'· ltNER K'oppers Co. :Inc..
DRESS t~3ineeteJ W'o9J 5,,sfeMS.R,t:.5'f
/1/1 / te (Street or Roj,te No.) ' ~orr,sv, ,. 1"!:._C. II City ?' Tlwn
giATE DRILLED 9/''f ~6 USE OF WELL Monitor,~.,
. jfTAL DEPTH /'iJ, 5"° CUTTINGS COLLECTED @°Yes O No
. ~ES WELL REPLACE EXISTING WELL? 0 Yes GJ"No
State Zip Code
. STATIC WATER LEVEL: ~.40 FT. Q_,above TOP OF CASING,
2 M below . l TOP OF CASING IS_=---FT. ABOVE LAND SURFACE.
. LO [gpm): ______ METHOD OF TEST . r TEA ZONES [depth): -----------------
. CHLORINA T/ON: Type Amount
J.-ASING: Wall Thickness
Depth Diameter or Weight/Ft. Material
0 From ___ _ To 5-FI. 2" r'VC
From. ___ _ To FI.
From ___ _ To Fl.
1.-ROUT:
From--=---
Depth Material Method
0 To 2 F1. Ceme11T '1-6e.,fon,te Powder
2 To 4-F1. Seo.I -(3e~t • .,ite. Pelle~ l From
2. REEN:
Depth Diameter
From~~~_To~/_7c.._Ft. 2 I Slot Size Material
in. 0. 010 in. PVC..
Fr.Jm ____ To ___ Fl. ____ in. ___ in. __ _
I From ____ To ___ Ft. ____ in. ___ in.
3. RAVEL PACK:
I From
Depth Size
'f To I 3.S" Ft. 6 11 --~---
Material
So.ncl.
From ____ To ___ Fl. _____ _
Quad. No. _______ Serial No. ___ _
Lat. _______ Long. ____ Pc __
Minor Basin _____________ _
Basin Code ____________ _
Header Ent. _______ GW-1 Ent ___ _
STATE WELL CONSTRUCTION
PERMIT NUMBER: 'll-02.SS--w'M-02.31,
County: ldc..Ke
Depth DRILLING LOG
From To Formation Description
II additional space is needed use back of form.
LOCATION SKETQ:L
(Show direction and distance from at least two State Roads,
or other map reference points)
4.IEMARKS:
I DO HEREBY CERTIFY THAT THIS WELL WAS CONSTRUCTED IN ACCORDANCE WITH 15 NCAC 2C, WELL CONSTRUCTION
STANDARDS, AND THAT A COPY OF THIS RECORD ~ROcfED ~ELL OWNER. 11../ 2.3 b 6
I SIGNATURE OF CONTRACTOR OR AGENT . 1 DA TE
GW· 1 Revised 11/84 Submit original to Division al Environmental Management and copy to well owner.
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MONITORING.WELL LOG
PROJECT _ __:_R~al~e_ig~h--',~N_C.::._ ______________ _ WELL NO. MW-4
GEOLOGIST S. A. Colton DRILLING METHOD __ H_o_ll_ow_S_t_e_m_A_u--'g"--e_r ____ _
DRILLER Soil Testing Services DATE
GROUND ELEVATION ___ _ GROUND WATER DEPTH (ft):
TOP OF WELL _____ _ AT COMPLETION -----
DEPTH OF WELL (ft) AFTER HOURS
CASING MATERIAL 2" PVC SCREEN 12' of 0.010" slots
DESCRIPTION
Brown clayey SILT, tr f sand, roots
Brown silty CLAY, tr r sand
Yellow/brown to brown clayey SILT, tr to little
emf sand
Red/brown to purple/maroon clayey SILT
(weathered bedrock), tr f sand
8/14/86
GRAVEL PACK :~-.:-•:·
BENTONITE
BACK FILL
CONCRETE
· SCREEN ----------
CONSTRUCTION
·. :-
: .-· .
.. :·
! ·•
•,•
: ·-:
.. , ..
Purple/maroon clayey SILT and SAND (weathered bedrock)
Bottom of Boring -24 feet
SHEET ___ OF __ _
rRTH CAROUNA DEPARTMENT OF NA TUAAL RESOURCES AND COMMUNITY DEVELOPMENT
DIVISION OF ENVIRONMENTAL MANAGEMENT -GROUNDWATER SECTION
P.O. BOX 27687 -RALEIGH.N.C. 27611, PHONE [phone]
I WELL CONSTRUCTION RECORD
l1LLJNG CONTRACTOR V'/, [so" [,-iB I neet,nj A.ssoci~tes
FOR OFFICE USE ONL y
Ouad. No. _______ Serial No. ___ _
Lat. Long. ____ Pc __
Minor Basin _____________ _
Basin Code _____________ _
Header Ent. _______ GW-1 Ent.-
jf_lLLER REGISTRATION NUMBER g ~ I STATE WELL CONSTRUCTION
PERMIT NUMBER: ')I-02.SS--\.-/M-0l3!, .MW-S
~(ELL LOCATION: (Show sketch of the location below)
earest Town: Mof"r15 V11ft)
ers R.oa.d. ,. v,I
Road. Community. or Subdivision and Lot No.)
2.1wNER K'oppers Co . .X"''-·
ooREss E:n~ineere.t. Wo9J SvsfeMs,R.r.5't
AA /ff. (Street or R!~te No.) ' L"...!orr,sv, !:!:._C . q City 1' 1own
I. ATE DRILLED 'J{I fl{, USE OF WELL /'/ionitor,~J ,.11 0TAL DEPTH 25-''. CUTTINGS COLLECTED @°Yes O No
;flOES WELL REPLACE EXISTING WELL? 0 Yes G;(No
;. STA TIC WATER LEVEL: 8-01;; FT. 0 above TOP OF CASING, 2. l,f below 11 TOP OF CASING IS . . . ,-FT. ABOVE LAND SURFACE.
71l1ELD (gpm): . METHOD OF TEST _______ _
State Zip Code
l. WATER ZONES (depth):---------'--------
l.,HLORINA TION: Type _______ A_m-ou_n_t _______ _
IASING: Walt Thickness
Depth Diameter or Weight/Ft. Material
From 0 To ~ Ft. 2// ('Ve ~
I From To Ft.
From To Ft.
,,ROUT:
Depth Material M8thod
0 I Ft. ce~e11t v-6enfon,te P,wder From To I From To 3 Ft. Se"'I -Geafo~ile. Pellet
i CREEN:
Depth Diameter Slot Size Material
I From .s To 2.~ Ft. 2 in.0.010 in. PVC.
Fr~m To Ft. in. in. l From To Ft. in. in.
; RAVEL PACK:
Depth Size Ma1eriat
I From 3 To 2~ Ft. 6 I/ So.,...J.
From To Ft.
County: ldc..Ke
Depth DRILLING LOG
From To Formation Description
If additional space is needed use back of fc,rm.
LOCATION SKETCH
(Sh_ow direction and distance from at least two State Roads,
or other map reference points)
5 ee. sle
,1. REMARKS:
I 00 HEREBY CERTIFY THAT THIS WELL WAS CONSTRUCTED IN ACCORDANCE WITH 15 NCAC 2C. WELL CONSTRUCTION
ST ANOAROS, AND THAT A COPY OF THIS RECORD HA~N PROVIDED T9'1H9, ,VELL OWNER. / j ~ a. ~ 12.._231.J6 I SIGNATURE OF CONTRACTOR OR AGENT 'DA TE
'./-1 Revised 11/84 Submit original to Division of Environmental Management and copy to well owner.
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MONITORING.WELL LOG
PROJECT Raleigh, NC ---~~-------,------------WELL NO. MW-5
GEOLOGIST S. A. Colton DRILLING METHOD Hollow Stem Auger
DRILLER Soil Testing Services DATE
GROUND ELEVATION __ _ GROUND WATER DEPTH (ft):
TOP OF WELL ____ _ AT COMPLETION. ____ _
DEPTH OF WELL (ft) AFTER HOURS
CASING MATERIAL 2" PVC SCREEN 20' of 0.010" slots
DESCRIPTION
8/1/86
GRAVEL PACK
BENTONITE
BACK FILL
CONCRETE
· SCREEN
CONSTRUCTION
SILT tr f sand tr frock fra ments FILL
!LT, tr f sand (FILL)
Brown to maroon/purple clayey SILT, tr f sand,
~-....::::,.-1-tr light brown silt laminae
10 Maroon/pu:,')le to gray clayey SILT (weathered bedrock),
-i<:,----:,,1---,tr f sand, little m. rock fragments 25.5-26.5'
Bottom of Boring -26,5 feet
... . .,
'. ::· ... . ,. '. ."'··
...
•.• ... . .
SHEET ___ OF __ _
IRTH CAROLINA OEPARTf...',ENT OF NATURAL RESOURCES ANO COMMUNITY DEVELOPMENT
DIVISION OF ENVIRONMENTAL M.ANAGEMENT -GROUNDWATER SECTION
P.O. BOX 27687 -AAL£IGH,N.C. 27611. PHONE [phone]
FOR OFFICE USE ONLY
Ouad. No. _______ Serial No. ___ _
I WELL CONSTRUCTION RECORD
JILLING CONTRACTOR Wtlso" [,,j/Mef,..,) Assocto.tes.
_'.j'LLER REGISTRATION NUMBER g 'i I
~,ELL LOCATION: {Show sketch of the location below)
ir,arest Town: JVlo.,-l"IS V1/lf) /V C.
1Jf oppers R.oo.cl.: Mor,-,1v,lk.
(Road. Community, or Subdivision and Lot No.)
!.gwNEA K'opper5 Co . .Inc..
llliDRESS I: "'3 ,neeteJ \,v99cl Sr:sfe,.,, s. R.t:. 5'f ,,,,,, lie (Street or R_o,,te No.} , L..'.:..!orr,sv1 ;v.C.
State Zip Code n City l' Tor_n
. ~ATE DRILLED 7 , 2<J/?{, USE OF WELL ;\(1011it0r1aJ
. ifTAL DEPTH 2. "3 ' CUTTINGS COLLECTED w'Yes D No
'· IJ=>ES WELL REPLACE EXISTING WELL? □ Yes GJ"No
;_ STA TIC WATER LEVEL: q_ 'i/9 FT. 0 above TOP OF CASING.
2 Gtbelow II TOP OF CASING IS FT. ABOVE LAND SURFACE.
·. IIIELD (gpm): ______ METHOD OF TEST _______ _
.. WA TEA ZONES (depth): ________________ _
I . CHLORINATION: Type ____ _ Amount
J.,ASING:
Depth Diameter
Wall Thickness
or Weight/Ft. Material
0 -o 2 11
From ____ To ~o~_Ft._~--PVC
From To ___ Ft. ___ _
From To ---Fl.----I
1 11 ROUT: I Depth Material · Method
From __ O __ To_4-~_Ft. Ce i,-,,e1it -t-{3e,.ton,te P.wd.er
I From _'-r~_ To 6 Ft. Sea.I -Beaio»ite. Pellet's
2 CREEN:
Depth Diameter Slot Size Material I From 8 To 25°' FI. 2 in.0.010 in. PVC.
FrJm To FI. in. in. I From To Fr. in. in.
3 RAVEL PACK:
Depth Size Material
I From & To 2'l? FI. G" So.r-.d.
From To FI.
lat. _______ Long. ____ Pc--
Minor Basin _____________ _
Basin Code _____________ _
Header Ent. _______ GW-1 Ent.-
STATE WELL CONSTRUCTION
PERMIT NUMBER: ')I -02.SS--w'M-02.3/,
County: Wc..Ke
Depth DRILLING LOG
From To Formation Description
If additional space is need~d use back ol fc,rm.
LOCATION SKETCH
(Show direction and distance from at least two State Roads,
or ·otheir map reference points)
JfEMARKS:
I DO HEREBY CERTIFY THAT THIS WELL WAS CONSTRUCTED IN ACCORDANCE WITH tS NCAC 2C. WELL CONSTRUCTION
STANDARDS. AND THAT A COPY OF THIS RECORD H~ ~N PROJ~D-ED l9 "JijE WELL OWNER. I /
~u ~ 12.z3Jt
'
SIGNATURE OF CONTRACTOR OR AGENT DA TE
G -1 Revised 11/84 Submit original lo Division of Environmental Management and copy to well owner.
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MONITORING·WELL LOG
PROJECT Raleigh, NC WELL NO. MW-6
DRILLING METHOD Hollow Stem Auger GEOLOGIST_..:..S._A_._c:..o:.::lt.::o.::n ___ _
DRILLER Soil Testing Services DATE 7 /28/86
GROUND ELEVATION ___ _ GROUND WATER DEPTH (ft):
TOP OF WELL _____ _ AT COMPLETION -----
DEPTH OF WELL (ft) AFTER HOURS
CASING MATERIAL 2" PVC SCREEN 17' of 0.010" slots
DESCRIPTION
Brown clayey SILT, tr f sand, tr fm rock fragments
Brown CLAY and SILT, tr f sand
Red/Brown clayey SILT, tr f sand, some gray /green silty
CLAY ocketS·
Maroon clayey SILT (weathered bedrock), tr f sand
Gray /green to gray/brown SILT and CLAY,
tr f sand
Gray/Brown clayey SILT (weathered bedrock), tr f sand
Bottom of Boring -29 feet
GRAVEL PACK
BENTONITE
BACK FILL
CONCRETE
· SCREEN ----------
CONSTRUCTION
. . ,•.
·-. . . . . ' ..
· .. :
:·,: ... . ... .. . .. . .. ··-· .. :• .. · . .. '• ·•:: ... ...
·,.· .. , ...
. :-
.-:·
-· . .. .
,•,
•. ·-:·:-/~·./·\:
-::::; .. ~ . .-.-.
SHEET ___ OF __ _
rATH CAROUNA OEPAATMENT OF NATURAL RESOURCES ANO COMMUNITY DEVELOPMENT
DIVISION OF ENVIRONMENTAL >J.ANAGEMENT -GROUNDWATER SECTION
P.O. BOX 27e87 -RALEIGH.N.C. 27611, PHONE [phone]
FOR OFFICE USE ONL y
Quad. No. _______ Serial No. ___ _
I WELL CONSTRUCTION RECORD
JIILLING CONTRACTOR Wt {so" [.,,q 11,e<'l"1") Assoc. , .. tes
DRILLER REGISTRATION NUMBER _;; __ g_~_7 _____ _
~-✓ELL LOCATION: (Show sketch of the location below)
earest Town: /\/lo..-r15 V1ff~) /V C.
e.rs Roa.d.. f'
oad, Community, or Subdivision and lot No.)
1.,wNER K' o ppet5 Co. ..r "c..
DDREss [,-,~,neereJ \.v99J S,,sfe,.,, s. f<.-C. 5'f
/1/1 { le_ (Street or Ro9te No.) ' ~orr,sv• ,. ;v.c.
State Zip Code II City OJ Tpwn
1.IIATE DRILLED 2(6(t6 usE oF WELL Monifo~,~~
:_ TOTAL DEPTH 2 S-1 CUTTINGS COLLECTED GJ'ves O No
i.,OES WELL REPLACE EXISTING WELL? □ Yes l:iJ'No
;_ STATIC WATER LEVEL: / /. 23 FT. Q,ebove TOP OF CASING.
2 ur oelow
I TOP OF CASING IS FT. ABOVE LAND SURFACE.
'. IELD (gpm): ______ METHOD OF TEST
l. WATER ZONES (depth): ________________ _
,. ,HLORINA TION: Type _______ A_m-ou_n_t _______ _
OIASING: Wall Thickness
Depth Diameter or Weight/Ft. Material
Fror,1 0 To 9.5" Ft. 2" PVC
I From To Ft.
From To Ft.
,.,ROUT: I Depth Material Method
From~O __ To 5'.~ F1.(er<>ei,,t<1-Be1-.fohife Powder
s:,; To 7. ~ Ft. Seo.I-(3e.to.,,te. Pe liefs I From
2 CREEN:
I From
Fr.:>m
9.~
I From
3 RAVEL PACK:
I From 7.~
From
"•EMARKS:
Depth
To 2 'f.~ Ft.
To FI.
To Ft.
Depth
To 25' FI.
To Ft.
Diameter Slot Size Material
2 in. 0. 010 in. eve.
in. in.
in. in.
Size Material
6" So.nd.
Lat. Long. ____ Pc __
Minor Basin _____________ _
Basin Code ____________ _
Header Ent. _______ GW-1 Ent. __ _
STATE WELL CONSTRUCTION
PERMIT NUMBER: 'I I -02.SS--WM-02 3!,
County: We.}( e
Depth DRILLING LOG
From To Formation Description
It additional space is needed use back of !Grm.
LOCATION SKETCH
(Show direction and distance lrom at least two State Roads.
or ·oth8r map reference points)
see s,fe /'n C\ f
I I DO HEREBY CERTIFY THAT THIS WELL WAS CONSTRUCTED IN ACCORDANCE WITH 15 NCAC 2C. WELL CONSTRUCTION
STANDARDS, AND THAT A COPY OF THIS RECORD HAS N PROVID$1). TO E WELL OWNER. /
(A I l... 2s/J6
GI I Revised 11/84
SIGNATURE OF CONTRACTOR OR AGENT ATE
Submit original to Division of Environmental Management and copy to well owner.
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MONITORING.WELL LOG
PROJECT Raleigh, NC WELL NO. MW-7
DRILLING METHOD Hollow Stem Auger GEOLOGIST S. A. Colton ------------DRILLER Soil Testing Services DATE
GROUND ELEVATION ----GROUND WATER DEPTH {ft):
TOP OF WELL AT COMPLETION -----------
DEPTH OF WELL (ft) AFTER HOURS
CASING MATERIAL 2" PVC SCREEN 15' of 0.010" slots
DESCRIPTION
Brown SILT and CLAY, tr f sand
8/6/86
GRAVEL PACK :~•-:.•.·
BENTONITE
BACK FILL
CONCRETE
· SCREEN ----------
CONSTRUCTION
Light purple to red/brown clayey SIL"'!\Weathered bedrock),
tr f sand, some me sand 17 .5-19'
: ' ...
··.·: ·.·,· · .. :
'\
Bottom of Boring~ 26 feet
·,·•· ...
·.:·
SHEET OF ------
IRTH CAROLINA DEPARTMENT OF NATURAL RESOURCES ANO COMMUNITY DEVELOPMENT
DIVISION OF ENVIRONMENTAL M.ANAGEMENT -GROUNDWATER SECTION
P.O. BOX 27687 -RALEIGH.N.C. 27611, PHONE [phone]
FOR OFFICE USE ONL y
Quad. No. _______ Serial No. ___ _
I WELL CONSTRUCTION RECORD
ILLING CONTRACTOR w, Ison [,')BI neet,n) A.sscc ,~tes
DRILLER REGISTRATION NUMBER __ ..::g_:b1c_t_;_ ____ _
=DELL LOCATION: (Show sketch of the location below)
earest Town: Mo,-r,s v,lh) IV C.
er• R.oo.d.. ,. ,I
oad, Community, or Subdivision and Lot No.)
, ... wNER /-(oppers Co. :J:,.,c.
lbDREss i;.,,'~me•reJ W'99J Svsfe,.,,s.R.t:.5'f
AA /ff. (Street or R?j,te No.) L.."..!orr,5v1 ;v.C
11 Cityf,r /own State Zip Code
. IIATE DRILLED 't lf 26 USE OF WELL /''1011itor,~}l ,1 I ';f
TOTAL DEPTH 2.6 CUTTINGS COLLECTED @'Yes O No -loEs WELL REPLACE EXISTING WELL? D Yes Q'No
. STATIC WATER LEVEL: 7.SO FT. 0 above TOP OF CASING, 2-Gl"below
I TOP OF CASING IS FT. ABOVE ~AND SURFACE.
. ELD (gpm): ______ METHOD OF TEST --------'-
. WATER ZONES (depth): ________________ _
. lLORINA TION: Type Amount
l9ASING:
I Depth Diameter
Wall Thickness or Weight/Ft. Material o 6 2 11
From ____ To ___ Ft.~=---fVC
I From. ____ To ___ Ft, ___ _
From To Fl.----
,,ROUT: I Depth Material Method
From __ o __ To_._3_Ft. Ce ;v,e., t-,i-6e .. fon,te P.wd.er
I From _-:]~_To 5' Ft. Seo.I -Gent,.i/'e. Pe/let's
2 CREEN:
Depth Diameter Slot Size Material
I From 6 To 25'. t Ft. 2 in.0.010 in. eve
Fr=im To Ft. in. in. I From To Ft. in. in.
3 RAVEL PACK:
Depth Size Material
I From s-To 26 Ft. 6" s 0. ,.,cf.
From To Ft.
<JEMARKS:
Lat. Long. ____ Pc __
Minor Basin _____________ _
Basin Code ____________ _
Header Ent. _______ GW-1 Ent.-
STATE WELL CONSTRUCTION
PERMIT NUMBER: 'II -02.SS'-w',-\-02.31,
County: ldc..Ke
Depth DRILLING LOG
From To Formation Description
___ _...,Se,..,.e o.-ffa.cl,,ed. 5/-,eet"
If additional space is needed use back ol lcrm.
LOCATION SKETCH
(Show direction and distance from at least two State Roads,
or 01her map reference points)
see sde rno.p
, I I DO HEREBY CERTIFY THAT THIS WELL WAS CONSTRUCTED IN ACCORDANCE WITH 15 NCAC 2C, WELL CONSTRUCTION
STANDARDS, AND THAT A COPY OF THIS RECORD HAS E N PROVIDJ?_ TO E WELL OWNER.
l.,,f /l..2.6j I SIGNATURE OF CONTRACTOR OR AGENT DAT
::; 1 Revised 11/84 Submit original to Division of Environmental Management and copy to well owner.
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MONITORING.WELL LOG
PROJECT Raleigh, NC WELL NO. MW-8
DRILLING METHOD Hollow Stem Auger GEOLOGIST S.A. Colton
DRILLER Soil Testing Services DATE
GROUND ELEVATION ___ _ GROUND WATER DEPTH {ft):
TOP OF WELL ------AT COMPLETION. ____ _
DEPTH OF WELL (ft) AFTER HOURS
CASING MATERIAL 2" PVC SCREEN 20' of 0.010 slots
DESCRIPTION
Black fm ROCK fragments, little fmc sand, tr silt
Brown CLAY and SILT, tr fm sand, tr f rock
fragments
8/4/86
GRAVEL PACK
BENTONITE
BACK FILL
CONCRETE
· SCREEN ----------
CONSTRUCTION
......
. . ·· .
Red/Brown clayey SILT, tr f sand, tr frock fragments,
tr laminae of light green clay
.. :
·,·•·
. .. ... ·.· ..
Red/Brown clayey SILT (weathered bedrock),
light green laminae 14.5-16.5'
Bottom of Boring -26.5 feet
...
•.• .
.. -. . -
SHEET ___ OF __ _
lloRTH CAROLINA DEPARTMENT OF NATURAL RESOURCES ANO COMMUNITY oevetoPMENT u DIVISION OF EN\/IAONMENTAL MANAGEMENT -GROUNDWATER SECTION
P.O. BOX 27687-RALEIGH.N.7. 27611, PHONE [phone]
WELL CONSTRUCTION RECORD
g . A
DRILLING coNTRACTOR W, I so" [ "1B, >1eef'1") ss o, ,~ 1e s
!ILLER REGISTRATION NUMBER ----=-g--=~-7-'-------
1. WELL LOCATION: (Show sketch of the location below)
FOR OFFICE USE ONL y
Ouad. No. _______ Serial No. ___ _
Lat. Long. ____ Pc_
Minor Basin _____________ _
Basin Code _____________ _
Header Ent. _______ GW-1 Ent.-
STATE WELL CONSTRUCTION
PERMIT NUMBER: JI -02.5"5"-W',,.._-02.3!,
=
D<:arest Town: ;Vlor"rt.S v,lf~) ;V: C.
~ o ppers /1..oa.cl. Morr,s v,lk,
County: _j,,,/Ci,.c,,.;..Ji'iece=----------------
I I , (Road, Community, or Subdivision and Lot No.)
2twNER __,_,K'~o+f+f.;:.e:.cr5"--_C=o..,_. -,-X_n_c.....:·----,-------
ADDRESS tri~meerec! Woocl StsfeMS,R.t:.5'-f
,1,1 /Jg (Street or R9yte No.) '
111 ~orr,sv, c. tY!.C • \II CitY, or Town ·state Zip Code
l. DATE DRILLED 275/'66 USE OF WELl Monitor,~.,
•10TAL DEPTH 2 / 1
CUTTINGS COLLECTED @°Yes O No
; OES WELL REPLACE EXISTING WELL? 0 Yes Gd'No
;_ STATIC WATER LEVEL: f;.°'t!:J FT. 0 above TOP OF CASING, II 2 G:Ybelow u TOP OF CASING IS .. --=~_. __ FT. ABOVE LAND SURFACE.
7. YIELD (gpm): ______ METHOD OF TEST _______ _
llf A TEA ZONES (depth):-----------------
l. CHLORINATION: Type ____ _ Amount
IASING:.
Depth
F rem ----'0=----To ,5-
Wall Thickness Diameter or Weight/Ft.
2" Ft.-'=---
Material
PVC
I F rom ____ To ___ Ft. ___ _
From To Fl.----
'ROUT:
From
II From
;~SCREEN:
I From
Fr.Jm
Depth ·
0 ro !.!:
/. 5°" To 3. 5"
Depth s-To 21
To
To J From
I GRAVEL PACK:
I Depth
From 3.~-To 26
From To
Material Method
Ft. (e"'eht-<1-Behtoh1te P,wder
Ft. Seo..1-Be11tohite.. Pellefs
Diameter Slot Size Material
Ft. 2 in.0.0I0 in. eve
Ft. in. in.
Ft. in. in.
Size Material
Ft. 6 I/ So..rid..
Ft.
Depth
From To
DRILLING LOG
Formation Description
___ __,..,,._.e o.tl-c..ched Sheet
If additional space is needed use back of form.
LOCATION SKETCH
(Show direction and distance from at least two State Roads,
or ·01h8r map reference points)
See
,,REMARKS:----------------------------------------------
1 DO HEREBY CERTIFY THAT THIS WELL WAS CONSTRUCTED IN ACCORDANCE WITH 15 NCAC 2C, WELL CONSTRUCTION
STANDARDS, AND THAT A COPY OF THIS RECORD HA~__LEN PROVIDED T9-IH5, WELL OWNER. / /
I ~&,., a. ~ ,2._2 J!.i't
SIGNATURE OF CONTRACTOR OR AGENT 'DA TE
GW-1 Revised 11/84 Submit original to Division of Environmental Management and copy to well owner.
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MONITORING.WELL LOG
PROJECT Raleigh, NC
DR I LL! NG METHOD __ H~oll~o_w_S_te_m_A_ug_er ___ _
WELL NO. MW-9
GEOLOGIST S. A. Colton
DRILLER Soil Testing Services DATE
GROUND ELEVATION ----GROUND WATER DEPTH (ft):
TOP OF WELL AT COMPLETION -----------
DEPTH OF WELL {ft) AFTER HOURS
CASING MATERIAL 2" PVC SCREEN 16' of 0.010 slots
DESCRIPTION
Brown clayey SILT, tr f sand
8/5/86
GRAVEL PACK
BENTONITE
BACK FILL
CONCRETE
· SCREEN ----------
CONSTRUCTION
Mottled Brown and gray/green SILT and CLAY, tr f sand,
tr f rock fragments '
Mottled Brown and gray /green clayey SILT, tr f sand
Brown clayey SILT (weathered bedrock), tr f sand,
tr m rock fragments (25-26.5')
Bottom of Boring -26.5 feet
... . .
... , .. . .': .. ·-: .. . .
·==-·,: .
. ' ··.:
.-: .. _.
'•: : . . .. ..
SHEET ___ OF __ _
IORTH CAROUNA OEPAflTJ,,,EHT OF NATURAL RESOURCES AND COMMUNITY DEVELOPMENT
DIVISION OF ENVIRONMENTAL MANAGEMENT -GROUNDWATER SECTION
P.O. BOX 27687 -RALEIGH,N.C. 27611, PHONE [phone]B3
FOR OFFICE USE ONLY
Ouad. No. _______ Serial No. ___ _
D WELL CONSTRUCTION RECORD
llLLING CONTRACTOR W,/50., [,,.,,,r.eer, ... ) Assoe1~tes
DRILLER REGISTRATION NUMBER __ .::.g...:;lj>_f _____ _
~lELL LOCATION: (Show skelch of the localion below)
~
earest Town: ;V\o.--r,s v,,,~) ;V C.
/1:o ore rs P.oa.cl.. /VloC"r! v,lle
Road, Community, or S~bdivision and Lot No.)
211rwNER /-(oppers Co. :Inc..
iD<DDREss f: ..,,':JmeereJ Wood SvsfeM s. R.t:. 5'f
,1,1 / le (Streel or Ro~te No.) > ~orr,sv• ,. &C.
I City/ or/Town State Zip Code
3 ATE DRILLED itS-86 USE OF WELL Monito.-,,,,, ' ~ ;t
4. TOTAL DEPTH 2 ~ CUTTINGS COLLECTED GJ'Yes O No foES WELL REPLACE EXISTING WELL? D Yes Gd"No
6. STATIC WATER LEVEL: / 5': 'f-J... FT. Q_,above TOP OF CASING. J.. "" below
I TOP OF CASING IS. FT. ABOVE LAND SURFACE.
IELD (gpm): " METHOD OF TEST -------~
8. WATER ZONES (deplh): ________________ _
9RHLORINA TION: Type Amoun1
1UCASING: Wall Thickness
Depth Diameter or Weight/Ft. Material
From 0 To 21 Ft. 2" fVC
m From To Ft.
From To Ft. ,1GROUT:
Depth Material Method
0 To /7 Ft. (er,,ent ~ 8enfoh,te Powder From
1 From /7 To 19 F1. Seo.I -Geatohite. Pelle~
1 SCREEN:
Depth Diameter Slot Size Material
I From 21 To 28 Ft. 2 in.0.010 in. eve
Fr=im To Ft. in. in. I From To Ft. in. in.
1 GRAVEL PACK:
Depth Size Material
I From I '1 To 28 Ft. 6 It So.nd.
From To Ft.
Lat. _______ Long. ____ Pc--
Minor Basin _____________ _
Basin Code _____________ _
Header Ent. _______ GW-~ Ent.-
STATE WELL CONSTRUCTION
PERMIT NUMBER: 'II -02.S'S--I-IM-D2.3h
County: \;yc.}(e
Depth DRILLING LOG
From To Formation Description
II additional space is needed use back ol form.
LOCATION SKETCH
(Show direction and distance lrom at least two Sta1e Roads,
or ·other map reference points)
see s ,fe rv,op
14 REMARKS:----------------------------------------------1 I DO HEREBY CERTIFY THAT THIS WELL WAS CONSTRUCTED IN ACCORDANCE WITH 15 NCAC 2C, WELL ONS RUCTION
STANDARDS, AND THAT A COPY OF THIS RECORD ~Via. TO WELL OWNER. / l l 6 J'/
I SIGNATURE OF CONTRACTOR OR AGENT DA TE
'I· 1 Revised 11/84 Submit original to Division al Environmental Manatiement and copy to well owner.
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MONITORING WELL LOG
PROJECT Raleigh, NC WELL NO. MW-10
DRILLING METHOD Hollow Stem Auger/Wash Rotary GEOLOGIST S. A. Colton
DRILLER Soil Testing Services DATE 8/5/86
GROUND ELEVATION __ _ GROUND WATER DEPTH {ft):
TOP OF WELL ------AT COMPLETION. ____ _
DEPTH OF WELL {ft) AFTER HOURS
CASING MATERIAL 2" PVC SCREEN 7' of 0.010" slots
STRAT SAMPLE
DEPTH DEPTH DESCRIPTION
Maroon/Brown clayey SILT, tr f sand, roots,
light green clay pockets. I. 5-(l. 0'
Maroon/Brown, gray /purple to yellow /brown clayey SILT
(weathered bedrock), tr f sand
(0 -10.5' sample descriptions taken from Boring B-4)
Bottom of Boring -28.5 feet
GRAVEL PACK :~•.:.•t
BENTONITE
BACK FILL
CONCRETE
· SCREEN ----------
CONSTRUCTION
SHEET ___ OF __ _
IIATH CAROLINA DEPARTMENT OF NA TiJRAL RESOURCES AND COMMUNITY DEVELOPMENT II DIVISION OF ENVIRONMENTAL MANAGEME."-IT -GROUNDWATER SECTION
FOR OFFICE USE ONL y
P.O. BOX 27687 -RAlElGH,N.C. 27611, PHONE [phone]
I WELL CONSTRUCTION RECORD
DULLING CONTRACTOR Wt!sol'I [,,~,Met,.,) Assoc/Ates
~OLLER REGISTRATION NUMBER __ .::.g..::b1_?_;__ ____ _
WELL LOCATION: (Show sketch of the location b·elow)
I:.
arest Town: JV\ 0 ,-r, S v,1/c} /v. C.
_ o Pre.rs Roa.cl.. Morr,1v,lle ' . ,, (Road, Community, or Subdivision and Lot No.)
· [NER (\ 0 ppers Co. _::r nc...
DRESS E"n~meqre.l. Wood Sksfe.r1s.B,t:. 5'f
Al1 lie (Street or f½>yte No.J ' ~orr,sv1 &C . I City pr Tpwn
TE DRILLED 'ifjl9(86 USE OF WELL Monitoi-1aJ
!lrTAL DEPTH 'J/, {" CUTTINGS COLLECTED @'Yes O No
!IPES WELL REPLACE EXISTING WELL? 0 Yes G!'No
STATIC WATER LEVEL: / ~. 5''f FT. Q_,,abovo TOP OF CASING,
2 w below l TOP OF CASING IS---'=---FT. ABOVE LAND SURFACE.
. LD (gpm): ______ METHOD OF TEST --------'
State Zip Code
. IA TEA ZONES (depth): -----------------
. CHLORINATION: Type ____ _ Amount
1.rSING: Wall Thickness
Depth Diameter or Weight/Ft. Material
0 21.;' -, // f'Vc. From To Ft. ....
D From To Ft.
From To FI.
:.,OUT:
Depth Material Method
From 0 To 17 Ft. Cervie1-1t-1-Be1-1fon,te P.wder l From 17 To / 9 Ft. Seo.I -Be"t»ite. Pe llet"s
,. REEN:
Depth Diameter Slot Size Material u From 21. r To JI. 5' Ft. 2 in.0,010 in. PVC.
Fr.:,m To Ft. in. in. IL From To Ft. in. in.
l. AVEL PACK:
Depth Size Material
m From / 9 To "]/. 5' Ft. 6 If So.,-,d..
From To FI.
Quad. No.-------Serial No. ___ _
Lat. Long. ____ Pc __
Minor Basin _____________ _
Basin Code------'----------
Header Ent. _______ GW-1 Ent.---
STATE WELL CONSTRUCTION
PERMIT NUMBER: ~/-02.SS--WM-02.3/, ,,,.. \,/-JI
County: \dc..,Ke
Depth DRILLING LOG
From To Formation Description
____ ... 5=ee o.th,.chrJ sheet
II additional space is needed use back ot le.rm.
LOCATION SKETCH
(Sh_ow ~irectior, and distance from at least two State Roads,
or other map reference points)
See_ Mo.p
,. ,MARKS:
I DO HEREBY CERTIFY THAT THIS WELL WAS CONSTRUCTED IN ACCORDANCE WITH 15 NCAC 2C, WELL CONST.RUCTION ST ANDAADS, AND THAT A COPY OF THIS RECORD HA BEEN PROVIDED TO E WELL OWNER ' / _ · a. _L/~-• 12-zt 11,
SIONA TUAE OF CONTRACTOR OR AGENT I J'N-1 Revised 11/84
DATE.
Submit original to Division al Environmental Management and copy to well owner.
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MONITORING.WELL LOG
PROJECT Raleigh, NC
DRILLING METHOD __ ~W~a=s~h_R_o~t_a~ry'---------
WELL NO. MW-11
GEOLOGIST s. A. Colton
DRILLER Soil Testing Services DATE 8/19/86
GROUND ELEVATION. ___ _
TOP OF WELL ____ _
DEPTH OF WELL {ft)
CASING MATERIAL 2" P'iC
STRAT SAMPLE
DEPTH DEPTH
GROUND WATER DEPTH (ft):
AT COMPLETION ____ _
AFTER HOURS
SCREEN 10' of 0.010" slots
DESCRIPTION
Brown cla e SILT tr f sand roots
Brown clayey SILT .. ,jth wtiite SILT and CLAY laminae,
Brown/Red clayey SIIT (weathered bedrockl, tr f sand
GRAVEL PACK :~•.:,•:·
BENTONITE
BACK FILL
CONCRETE
· SCREEN ----------
CONSTRUCTION
10 (0-10.5 feet sample descriptions taken from Boring B~2)-
20
Bottom of Boring -32 feet
SHEET ___ OF __ _
.ORTH CAROLINA DEPARTMENT Of NATURAL RESOURCES. AND COMMUNITY DEVELOPMENT II DIVISION OF ENVIRONMENTAL J.MNAGEMENT -GROUNDWATER SECTION
P.O. BOX 276B7 -RALEIGH,N.C. 27611, PHONE [phone]
FOR OFFICE USE ONL y
Quad. No. ______ Serial No. ___ _
I WELL CONSTRUCTION RECORD
Lat. ______ Long. ____ Pc--
Minor Basin ____________ _
Basin Code ____________ _
Header Ent. ______ GW-1 Ent.-
l,LUNG CONTRACTOR W,/so11 [,131Mel"1") Assoc,~tes
=IILLER REGISTRATION NUMBER --=--g..:.~_-,_;__ ____ _ STATE WELL CONSTRUCTION
PERMIT NUMBER: 'II -02.5S"-W,..._-02.3/, .M \,/-/2
1. WELL LOCATION: (Show sketch of the location below)
n::•rest Town: MO ,-r, 5 v,lf t.} ;\I. C. 11/:iopoers Roa.d., /Vlorr•11v,II,
(Road, Community, or S~bdivision and Lot No.)
211:iwNER /'fopper5 Co . .Inc..
111.ooREss [v,~rne•reJ W'ooJ SksfeMS.R.t:.5'f "!1 /Jg (Street or R:o~te No.) ' L"'orr,sv, c. !"!!._C. IJ City pr Tpwn State Zip Code
3.ll!ATE DRILLED 849f86 USE OF WELL Monitor,~J
410TAL DEPTH 30. . CUTTINGS COLLECTED @°Yes O No
5 OES WELL REPLACE EXISTING WELL? 0 Yes [i;(No
6. STATIC WATER LEVEV / 6 · 3? FT. □ ~bove TOP OF CASING. 2-G:;Ybelow I TOP OF CASING IS_:_;_ __ FT. ABOV~ LAND SURFACE.
7~1ELD (gpm): ______ METHOD OF TEST ______ _
81'/ATER ZONES (depth):----------------
3. CHLORINATION: Type ____ _ Amount
'ASING: Wall Thickness
Depth Diameter or Weight/Ft. Material
From 0 To 20 Ft. 2" fVC
0 From To Ft.
From To Ft.
,,ROUT:
Depth , Material Method
From --"'O:...__ To/:,.) Ft. Cer-ie1it~6e1itoh,te Powder ,s-.s-To /7.5"" Ft. Seo.I-(3ehtohite. Pellets l From
1 GREEN:
I From 20
Depth
To °30
Slot Size Material
Ft._2 __ in.O.OIO in. PVC
Diameter
Fr~m To Ft. in. in. 1 From To Fl. in. in.
1 RAVEL PACK:
Depth Size Material I From / 7. 5" To 30 Ft. 6 It So."cl
From To FI.
County: ldc..Jf e
Depth DRILLING LOG
From To Formation Description
If additional space ls needed use back of form.
LOCATION SKEEJ:i
(Show direction and distance from at least two State Roads,
or 'other map reference points)
.see s1fe
=
1,EMARKS: ___________________________________________ _
I DO HEREBY CERTIFY THAT THIS WELL WAS CONSTRUCTED IN ACCORDANCE WITH 15 NCAC 2C. WELL CONSTRUCTION STANDARDS. AND THAT A COPY OF THIS RECORDHAi>,BEEN PROVIDED TO,,-:,E ,)'9=t,l;-OWNER. / /
I JXi&--q Ll~ 12._2b[jo
SIGNATURE OF CONTRACTOR OR AGENT DATE 1
GW-1 Revised 11/84 Submit original to Division of Environmental Management and copy to well owner.
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MONITORING.WELL LOG
PROJECT_---=.:Rc::al:..:e_,ig.,_h_,_,_N_C'---·----------------WELL NO. MW-12
GEOLOGIST S. A. Colton DRILLING METHOD __ Voas_;__h_R_o_t_a_ry~------
DRILLER Soil Testing Services DATE
GROUND ELEVATION ----GROUND WATER DEPTH (ft):
TOP OF WELL AT COMPLETION -----------
DEPTH OF WELL (ft) AFTER HOURS
CASING MATERIAL 211 PVC: SCREEN 10' of 0.010" slots
STRAT SAMPLE
DEPTH DEPTH DESCRIPTION
8/19/86
GRAVEL PACK
BENTONITE
BACK FILL
CONCRETE
· SCREEN
CONSTRUCTION
Red/Brown clayey SILT, tr f sand, tr f rock fragments,
roots
IO
20
30
0
Red/Brown clayey SILT (weathered bedrock),
tr f sand
(0-12.5' sample descriptions taken from Boring B-1)
Bottom of Boring -30.5 feet
· ..
· ... .. : .. . . .
.. ..
·.·.·
SHEET OF
· ... ... ....
.. ·.·. : •. :·:,
. ..
·.· ..
---- ----
I
m KEYSTONE
ENVIRONMENTAL RESOURCF..S, INC.
II 440 College Park Dr., Monroeville, PA 15146
Ref. 8, Encl. 2
11-----------------
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MONITORING.WELL LOG
PROJECT Ralei h NC WELL NO. MW-1
DRILLING METHOD Hollow Stem Auger GEOLOGIST S. A. Colton ----.:..C..--'-----
DRILLER Soil Testing Services DATE
GROUND ELEVATION ----GROUND WATER DEPTH (ft):
TOP OF WELL AT COMPLETION -----------
DEPTH OF WELL (ft) AFTER HOURS
CASING MATERIAL 2" PVC SCREEN 20' of 0.010" slots
DESCRIPTION
Brown, clayey SILT, tr f sand, tr weathered rock
fragments, tr m quartz fragments, tr roots (0-1.5')
Mottled Brown and gray silty CLAY, tr f sand,
tr f rock fragments.
Red/brown Clayey SILT ( weathered bedrock), tr
siltstone fragments, tr f sand
Bottom of Boring -26.5 feet
8 /7 /86
GRAVEL PACK :~•.:-•:'
BENTONITE
BACK FILL
CONCRETE
· SCREEN ----------
CONSTRUCT! ON
: ··.
-: .
. .
.',,: .. ·
· .. . .
·,·•· ... .. · . . ·.-· . ·.·•
. • . . .
.··, .. ·.
,·,,
SHEET ___ OF __ _
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MONITORING·WELL LOG
PROJECT Raleigh, NC WELL NO. MW-2
DRILLING METHOD Hollow Stem Auger GEOLOGIST S. A. Colton
DRILL ER Soil Testing Services DATE 8/7 /86
GROUND ELEVATION. ___ _ GROUND WATER DEPTH (ft):
TOP OF WELL _____ _ AT COMPLETION. ____ __;
DEPTH OF WELL (ft) AFTER HOURS
CASING MATERIAL; 2" PVC SCREEN 19' of 0.010" slots
12
DESCRIPTION
Brown clayey SILT, tr f sand, tr siltstone fragments,
roots 0-1.5', 9~10.5'
Mottled gray/green/yellow /orange clayey SILT,
(weathered bedrock)
Bottom of Boring -26.5 feet
GRAVEL PACK :'!•-:.•:'
BENTONITE
BACK FILL
CONCRETE
· SCREEN ----------
CONSTRUCTION
·. •.
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SHEET ___ OF __ _
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MONITORING.WELL LOG
PROJECT Raleigh, NC
DRILLING METHOD _ _.:.:H:.:::o.:c:ll=-ow:.:...::Sc.::.te::.:m.:.:...c.Ac.:u:cg..=er:..._ __ _
WELL NO. MW-3
GEOLOGIST s. A. Colton
DRILLER Soil Testing Services DATE
GROUND ELEVATION ----GROUND WATER DEPTH (ft):
TOP OF WELL. _____ _ AT COMPLETION -----
DEPTH OF WELL (ft) AFTER HOURS
CASING MATERIAL 2" PVC SCREEN 10' of 0.010" slots
8/11/86
GRAVEL PACK :~•.:.•:·
BENTONITE
BACK FILL
CONCRETE
· SCREEN ----------
DESCRIPTION CONSTRUCTION
Yellow/brown SILT, tr f sand, tr frock fragments, roots
Brown/red to gray/purple clayey SILT, tr f sand
Gray/purple to brown clayey SILT,
( weathered bedrock), tr f sand
Bottom of Boring -21.5 feet
··.· :· ..
SHEET ___ OF __ _
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MONITORING.WELL LOG
PROJECT __ R_al_e_,ig,,__h-"-,_N_C ______________ _ WELL NO. MW-4
DRILLING METHOD __ H_oll_ow_S_t_em_A_u_,g,,__e_r ____ _ GEOLOGIST __ s_._A_._c_ol_t_on ___ _
DRILLER Soil Testing Services DATE 8/14/86
GROUND ELEVATION ----GROUND WATER DEPTH {ft):
TOP OF WELL. _____ _ AT COMPLETION. ____ _
DEPTH OF WELL (ft) AFTER HOURS
CASING MATERIAL 2" PVC SCREEN 12' of 0.010" slots
DESCRIPTION
Brown clayey SILT, tr f sand, roots
Brown silty CLAY, tr f sand
Yellow /brown to brown clayey SILT, tr to little
emf sand .
Red/brown to purple/maroon clayey SILT
(weathered bedrock), tr f sand
GRAVEL PACK
BENTDNITE
BACK FILL
CONCRETE · SCREEN ----------
CONSTRUCTION
Purple/maroon clayey SILT and SAND (weathered bedrock)
Bottom of Boring -24 feet
SHEET ___ OF __ _
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MONITORING.WELL LOG
PROJECT __ R_al_e_i=gh~•c...N_C ________________ _ WELL NO. MW-5
DRILLING METHOD Hollow Stem Auger GEOLOGIST_S:_._A_._:C...co.:.cltc:.on:.:_ ___ _
DRILLER Soil Testing Services DATE 8/1/86
GROUND ELEVATION ----GROUND WATER DEPTH (ft):
TOP OF WELL. _____ _ AT COMPLETION. ____ _
DEPTH OF WELL (ft) AFTER HOURS
CASING MATERIAL 2" PVC SCREEN 20' of 0.010" slots
DESCRIPTION
Brown cla e SILT tr f sand tr f rock fra ments FILL
Light Brown SILT, tr f sand (FILL)
Brown to maroon/purple clayey SILT, tr f sand;··,·
+"'---=:,.~ tr light brown silt laminae
GRAVEL PACK
BENTONITE
BACK FILL
CONCRETE
· SCREEN ----------
CONSTRUCTION
10 Maroon/purple to gray clayey SILT (weathered bedrock),
-J<:::,--,.----::-at--tr f sand, little m rock fragments 25.5-26.5'
Bottom of Boring -26.5 feet
-••'. :. :
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:•· ·· ..
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SHEET ___ OF __ _
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MONITORING.WELL LOG
PROJECT Raleigh, NC
DRILLING METHOD Hollow Stem Auger
WELL NO. MW-6
GEOLOGIST S. A. Col.ton
DRILLER Soil Testing Services DATE 7/28/86
GROUND ELEVATION GROUND WATER DEPTH (ft): ----
TOP OF WELL ------AT COMPLETION. ____ _
DEPTH OF WELL (ft) AFTER HOURS
CASING MATERIAL . 2" PVC SCREEN 17' of 0.010" slots
DESCRIPTION
Brown clayey SILT, tr f sand, tr fm rock fragments
Brown CLAY and SILT, tr f sand
Red/Brown clayey SILT, tr f sand, some gray/green silty
CLAY ockets
Maroon clayey SILT (weathered bedrock), tr f sand
Gray/green to gray/brown SILT and CLAY,
tr f sand
Gray/Brown clayey SILT (weathered bedrock), tr f sand
Bottom of Boring -29 feet
GRAVEL PACK
BENTONITE
BACK FILL
CONCRETE
· SCREEN ----------
CONSTRUCTION
. . . ;_ ..
....
·•: ...
'.··
•.: . : .
. . -., .. . .. .· · .
-:·
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.. ·. ·.• .. · .. ·. : .. :: : : .·.: :. · .. · ..
. ::::; .. ~.:.:
SHEET ___ OF __ _
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MONITORING·WELL LOG
PROJECT -----------------------Raleigh, NC WELL NO. MW-7
DRILLING METHOD Hollow Stem Auger GEOLOGIST S. A. Colton -------------DRILLER Soil Testing Services
GROUND ELEVATION ----
TOP OF WELL ------
DEPTH OF WELL {ft)
CASING MATERIAL 2" PVC
DATE 8/6/86
GROUND WATER DEPTH (ft):
AT COMPLETION ·-----
AFTER HOURS
SCREEN 15' of 0.010" slots
GRAVEL PACK
BENTONITE
BACK FILL
CONCRETE
. SCREEN ----------
DESCRIPTION CONSTRUCT! ON
Qray Bro n m ROCK fragments, wood chips, httle silt FILL
Brown SILT and CLAY, tr f sand
Light purple to red/brown clayey SIL'!<weathered bedro.ck),
tr f saner; some me sand 17 .5-19'
Bottom of Boring -26 feet
: •. ·.
·.·.· ...
. ·.
SHEET OF
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MONITORING.WELL LOG
PROJECT Raleigh, NC WELL NO.MW-8
DRILLING METHOD __ H_o_ll_o_w_St_e_m_A_ug.:e__er ____ _ GEOLOGIST S.A. Colton ----------DRILLER Soil Testing Services DATE 8/4/86
GROUND ELEVATION. ___ _ GROUND WATER DEPTH (ft):
TOP OF WELL. _____ _ AT COMPLETION. ____ _
DEPTH OF WELL (ft) AFTER HOURS
CASING MATERIAL 2" PVC SCREEN 20' of 0.010 slots
DESCRIPTION
Black fm ROCK fragments, little fmc sand, tr silt
Brown CLAY and SILT, tr fm sand, tr f rock
fragments
Red/Brown clayey SILT, tr f sand, tr frock fragments,
tr laminae_ of light green clay
Red/Brown clayey SILT (weathered bedrock),
light green laminae 14.5-16.5'
Bottom of Boring -26.5 feet
GRAVEL PACK
BENTONITE
BACK FILL
CONCRETE
· SCREEN
CONSTRUCTION
. '• -:·. .;_ ·: ...
,'.
·.···
,••
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•·.·.
: : .
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'.,
'• .. :
SHEET OF --------
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MONITORING.WELL LOG
PROJECT Raleigh, NC
DRILLING METHOD_--'-'H~o~ll~o~w~S~t~e~m'-'-'A~ug~e~r ____ _
WELL NO. MW-9
GEOLOGIST S. A. Colton
DRILLER Soil Testing Services
GROUND ELEVATION ___ _
TOP OF WELL ------
DEPTH OF WELL (ft)
CASING MATERIAL 2" PVC
DATE
GROUND WATER DEPTH (ft):
AT COMPLETION -----
AFTER HOURS
SCREEN 16' of 0.010 slots
8/5/86
GRAVEL PACK
BENTONITE
BACK FILL
CONCRETE
· SCREEN
DESCRIPTION CONSTRUCTION
Brown clayey SILT, tr f sand
Mottled Brown and gray/green SILT and CLAY, tr f sand,
tr f rock fragments
Mottled Brown and gray/green clayey SILT, tr f sand
Brown clayey SILT (weathered bedrock), tr f sand,
tr m rock fragments (25-26.5')
Bottom of Boring -2(;.5 feet
" . ' . "
SHEET ___ OF __ _
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MONITORING.WELL LOG
PROJECT Ralei h NC WELL NO. MW-10
GEOLOGIST S. A. Colton DRILLING METHOD Hollow Stem Auger/Wash Rotary
DRILLER Soil Testing Services
----------DATE 8/5/86
GROUND ELEVATION GROUND WATER DEPTH (ft): ----
TOP OF WELL AT COMPLETION -----------
DEPTH OF WELL {ft) AFTER HOURS
CASING MATERIAL . 2" PVC SCREEN 7' of 0.010" slots
STRAT SAMPLE
DEPTH DEPTH
10
DESCRIPTION
Maroon/Brown clayey SILT, tr f sand, roots,
light green clay pockets. 1.5-J .0'
Maroon/Brown, gray/purple to yellow/brown clayey SILT
(weathered bedrock), tr f sand
(0 -10.5' sample descriptions taken from Boring B-4)
Bottom of Boring -28.5 feet
GRAVEL PACK
BENTONITE
BACK FILL
CONCRETE
· SCREEN ----------
CONSTRUCTION
.. ...
SHEET OF --------
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MONITORING.WELL LOG
PROJECT Raleigh, NC
DRILLING METHOD __ ~W~a=s~h~R~o~t=a~ry,__ _____ _
WELL NO. MW-11
GEOLOGIST s. A. Colton
DRILLER Soil Testing Services
GROUND ELEVATION ___ _
TOP OF WELL ------
DEPTH OF WELL (ft)
CASING MATERIAL 2" P'iC
DATE 8/19/86
GROUND WATER DEPTH (ft):
AT COMPLETION -----
AFTER HOURS
SCREEN 10' of 0.010" slots
GRAVEL PACK
BENTONITE
BACK Fill
CONCRETE
· SCREEN ----------
STRAT SAMPLE
DEPTH DEPTH DESCRIPTION CONSTRUCTION
20
Brown cla e SILT tr f sand roots
Rrown clayey SILT ·•,jth wtiite SILT •rnd CLAY laminae,
Brown/Red clayey SITT (weathered bedrockl, tr f sand
(0-10.5 feet sample descriptions taken from Boring B"2)
Bottom of Boring -32 feet
: ..
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·:,
SHEET ___ OF __ _
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MONITORJNG.WELL LOG
PROJECT __ R_al_c_i=g_h,~N_C _______________ _ WELL NO. MW-12
GEOLOGIST S. A. Colton DRILLING METHOD __ \\as_h_R_o_t_a~ry~------
DRILLER Soil Testing Services DATE 8/19/86
GROUND ELEVATION ----GROUND WATER DEPTH (ft):
TOP OF WELL. _____ _ AT COMPLETION. ____ _
DEPTH OF WELL (ft) AFTER HOURS
CASING MATERIAL 2" PVC: SCREEN 10' of 0.010" slots
STRAT SAMPLE
DEPTH DEPTH DESCRIPTION
GRAVEL PACK
BENTONITE
BACK FILL
CONCRETE
· SCREEN -----
CONSTRUCTION
Red/Brown clayey SILT, tr f sand, tr f rock fragments,
20
30
roots ·
Red/Brown clayey SILT (weathered bedrock),
tr f sand
(0-12.5' sample descriptions taken from Boring B-1)
Bottom of Boring -30.5 feet
. _::
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.· ..
'•. . : · .
.•.
•'
',• . '
SHEET ___ OF __ _
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BORING LOG
PROJECT Raleigh, NC BORING NO. B-1
DRILLING METHOD Hollow Stem Auger GEOLOGIST s. A. Colton
DRILLER Soil Testing Services DATE 7/21/86
DESCRIPTION
Red/Brown clayey SILT, tr f sand, tr frock fragments, roots 0-1.5'
4
Red/Brown to Maroon clayey SILT (weathered bedrock), tr f sand
Bottom ·of Boring -12.25 feet
SHEET OF
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10
BORING LOG
PROJECT Raleigh, NC ----~-----------BORING NO, B-2
DRILLING METHOD Ho))ow Stem Auger GEOLOGIST s. A. Colton
DRILLER -Soil Testing Services DATE 7/24/86
DESCRIPTION
Brown clayey SILT, tr f sand, roots
Brown clayey SILT with white SILT and CLAY laminae, tr f sand
Brown/red clayey SILT (weathered bedrock)
Bottom of Boring -9.1 feet
SHEET OF
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BORING LOG
PROJECT __ ~R~al=e~igQh~,'----'--'N~C'------------BORING NO.
DRILLING
STRATA
5
GEOLOGIST s. A. Colton
DATE 7/24/86
DESCRIPTION
Brown clayey SILT, tr to some sand, tr f rock fragments
Red/Brown SILT and CLAY, tr f sand
Red/Brown clayey SILT (weathered bedrock), tr f sand,
tr f rock fragments
Bottom of Boring -9.3 feet
SHEET OF
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BORING LOG
PROJECT Raleigh, NC BORING NO.
DRILLING ME'l'HiJD Hollow Stem Auger GEOLOGIST S. A. Colton
DRILLER Soil Testing Services DATE 7 /24/86
DESCRIPTION
Maroon/brown clayey SILT, tr f sand, roots, light green
clay pockets (1. 5-3')
Maroon/brown clayey SILT (weathered bedrock), tr f sand
SHEET 1 OF 2
13-4
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BORING LOG
PROJECT __ ___c:R~al=e~ig~h~,'----N~C"-----------
DRILLING METHOD Hollow Stem Auger
DRILLER Soil Testing Services
STMTA SAMPL
DEPTH DEPTH DESCRIPTION
BORING NO. 8-4
GEOLOGIST S. A. Colton
DATE 7/24/86
Maroon/brown clayey SILT ( weathered bedrock), tr f sand
Bottom of Boring -22 feet
25
SHEET 2 OF 2 ----
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10
BORING LOG
PROJECT Raleigh, NC ----~-'----------------BORING NO. ---B-5
DRILLING METHOD Hollow Stem Auger GEOLOGIST S. A. Colton
DRILLER Soil Testing Services DATE 7/21/86
DESCRIPTION
Brown clayey SILT, tr f sand, t fm siltstone fragments (Fill)
Lt. Brown SILT, some fm rock fragments, tr f sand, (Fill)
Brown silty CLAY, tr f sand
J?rown/Maroon SILT and CLAY, tr f sand
Maroon clayey SILT (weathered bedrock), tr f sand, tr rock fragments
SHEET _.l __ OF __ 2_
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BORING LOG
PROJECT Raleigh, NC -----~~-----------
DRILLING METHOD Hollow Stem Auger
DRILLER Soil Testing Services
STRATA SAMPL
DEPTH DEPTH DESCRIPTION
BORING NO. B-5
GEO LOG I ST S. A. Colton
DATE 7/21/86
Maroon clayey SILT (weathered bedrock), tr f sand, tr rock fragments
25
Bottom of Boring -25 feet
SHEET 2 OF 2
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BORING LOG
PROJECT _ __cR~al=e~ig~h~,~N=C:__ ________ _ BORING NO. 8-6
DRILLING METHOD Hollow Stem Auger GEO LOG I ST s. A. Colton _c__...::...:..:..:=----
DRILLER Soil Testing Services D ATE 7/22/86
STKATA DESCRIPTION
Light Brown SILT, some fm rock fragments
Black. red brown siltv CLAY tr f sand
Brown CLAY and gray SILT, tr f sand, tr f gravel
Brown silty CLAY, tr f sand
Maroon clayey SILT (weathered bedrock), tr f sand
5
Bottom of Boring -10.5 feet
SHEET OF
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BORING LOG
.PROJECT ___ R~a~lc~i~g~h=·~N_C~---------BORING NO. B-7
GEOLOGIST S. A. Colton METHOD Hollow Stem Auger
DATE 7/21/86
STE{ATA DESCRIPTION
Wood chips
Light Brown silty CLAY, tr f sand
Light Brown clayey SILT, tr f sand
5 Brown/green SILT and CLAY, tr f sand
Red/brown clayey SILT (weathered bedrock), tr f sand
10
Bottom of Boring -10.25 feet
SHEET OF
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BORING LOG
PROJECT Raleigh, NC
DRILLING METHOD Hollow Stem Auger
DRILLER Soil Testing Services
BORING NO.B-1O
GEOLOGIST S.A . Colton
DATE 7/22/86
STRATA SAMPL DESCRIPTION
5
l(}_
Brown clayey SILT to iight brown silt (Fill)
'1aroon clayey SILT, tr f sand •
Maroon clayey SILT (weathered bedrock), green clay laminae (7 .5-8.0)
tr f sand
SILT, tr f sand, tr f rock fragments
Gray clayey SILT (weathered bedrock), tr f sand, tr frock fragments
SHEET 1 OF 2
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BORING LOG
. PROJECT __ ~R~al=e~ig~h~1~N=C'----------
DRILLING METHOD Hollow Stem Auger -----'=='--=~-~=----DRILLER
SHATA SAMPL
DEPTH DEPTH
Soil Testing Services
DESCRIPTION
BORING NO. B-10
GEOLOGIST S.A. Colton
DATE 7/22/86
Gray clayey SILT (weathered bedrock), tr f sand, tr f rock fragments
Bottom of Boring -24.0 feet
25
SHEET 2 OF 2
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10
BORING LOG
PROJECT . Raleigh, NC · BORING NO. B-11
GEOLOGIST S.A. Colton DRILLING METHOD Hollow Stem Auger
DRILLER Soil Testing Services DATE 7 /25/86
DESCRIPTION
Brown clayey SILT, tr f sand, tr f rock fragments roots
Mottled light brown silty CLAY and red/brown clayey SILT, tr f sand
Red/Brown clayey SILT, tr f sand
Mottled Red/brown clayey SILT and It. green silty CLAY, tr f sand
Red/Brown ·clayey SILT, tr f sand
Red/Brown clayey SILT (weathered bedtock), tr cf-sand
Bottom of Boring -9.75 feet
SHEET OF
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10
BORING LOG
. PROJECT Raleigh, NC
DRILLitsG METHOD Hollow Stem Auger
DRILLER Soil Testing Services
DESCRIPTION
BORING NO, B-12
GEOLOGIST s. A. Colton
DATE 7/25/86
Brown, clayey SILT, tr f sand, tr f rock fragments
Light Brown silty CLAY, tr f sand
Brown SILT and CLAY, tr c sand
Light Brown/green silty CLAY, tr f sand
Light Brown CLAY-and SILT, tr c sand, tr f rock fragments
Red/brown SILT and Lt. green CLAY, tr f sand
Bottom of Boring -10.5 feet
SHEET OF
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BORING LOG
PROJECT Raleigh, NC
DRILLING METHOD Hollow Stem Auger
DRILLER Soil Testing Services
BORING No.13-14
GEOLOGIST s. A. Colton
DATE 7/25/86
STRATA SAMPL
DEPTH DEPTH DESCRIPTION
Augered through fill (Lt. Brown SILT, tr f sand)
First sample at 2.5 feet ,,
Gray/brown CLAY and SILT, tr f sand, tr frock fragments
5 Brown/green silty CLAY, tr fm sand, tr f rock fragments
Gray clayey SILT, tr f sand
Brown SILT and CLAY, tr f sand
Bottom of Boring -7 feet
10
SHEET OF
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BORING LOG
BORING NO.B-15 PROJECT_~R~a~I~e~ig~h4,_N=C~---------
DRILLING METHOD Hollow Stem Auger GEOLOGIST S.A. Colton -~=~=='---DRILLER Soil Testing Services DATE 7/25/86
DESCRIPTION
Brown CLAY and SILT tr f sand tr f rock fra men ts (Fill)
Light Brown SILT, little f sand, tr m rock fragments
(1.5-3.O feet) (Fill)
Mottled Brown and green SILT and CLAY, tr f sand,
tr rock fragments (6-7 .5 feet)
Light Brown clayey SILT, tr fm sand
Mottled Red SILT and Green CLAY, tr f sand
Red/brown clayey SILT, tr f sand
Red/brown clayey SILT (weathered bedrock), tr f sand
Bottom of Boring -10.25 feet
SHEET OF
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•:-:--: ---
Raleigh, NC
Soil Analyses
{175-1792-77)
Attached are results of analyses on
September 26, 1986 at the Raleigh site.
RDH:da
Attachment
cc: M. J. Dvorsky
R. L. Weightman
S. Colton
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I ======---======--=-------------==-================
t~==-=~-=~~~:~ -~:-~:~~~~=-=·~:·~=,~==---==-----======--==~========---
SAMPLE~ RSLT LNE ----------------------------------------
I
I
I
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l18•:,0C9A
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2.3,5,0Tet-c1-one~(•I
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======:==
m I KEYSTONE ENV!R1JNMENTAL RESOURCES ~===============----------------------------------~1~=~-= ~ -=u~~~~ _ o: _ =:~:~ ~ '.:' _ =-=~:=~'~==-__ □FODUCED ON 11110/2•5 AT 13:~~ -------------============----':AMPLE # l.s,50095 --I I I ,.3,,,C,096 I I RSLT.LNE ----------------------------------------2,3,5.6Tet-•::-pn~not 2, 4, ,~,Tri en 1 .:,rop!1en•:> i 2,4-Dicn1oroon~no1 2,4-0imetnv1pne1101 2,4-Dinitroptie~o: 2-cn Io r,)i:it,en~:> 1 -2-N i troot1-:no r 4,0-Dinitro-o-cresoi 4-N it r.:>pnen•:i l. ACn1oro3m~tnv1onen0; Pentacn1oroo!~eno1 Pneno, 2,3,5.6T~t-•:l-01l~~•)i 2,4,0Tr1cn1orootien0, 2,4-Di·:titoroo11e~o! ~.4-Oimett1v1oner10f 2, 4--'P in.•: (,:,oi•1e~1-:, 1 2-ct1 1 o ropneno: 2-N i trocine'.V) 1 4,S-O,nitro-0-·:r~sc,: 4-N it rQpt1en•:; ! acn1or03me:nviot1~:,,~ P~t1te.ct11 or--oor~en,:• oneno1 1, 70. 0 '7,J . ,J 35.0 ? s .-, •:7,J. 0 ·: 44 , :3 5 . 0 L :>< < 7(·. 0 e;. 3 ·35 0 715 ~--';,4 7-:,. ,) ,•·. 7·). 0 ··35 0 ·35. '.J '"7(1. ,:-, 4·10 ?5.0 , 70 0 •70,0 '.35.·) 204 ,:_ ,-:, 1 l.:,,,e t-e ~-u , t s ~re r e i::1c, r t "= •:i 1 ~-.. ,_j •'.'J ..' f<'. ,:, . I I I I I I I I 30URC.E 915-4.5-0 815-4.5-6 815-4.5-6 815-4 5-0 815-4.5-6 3·15-4. 5-·~· 915-4.5-6 515-4 5-~ 815-4.5-6 a,s-4.5-6 815-4.5-6 915-4.5-~ 915-9-10 5 815-~-10.S 215-~•-10.5 3·!5-0-10 5 515-~-1,).5 3!5-0-10.5 e~s-0-1O.s ~15-0-10.5 31~-~-10.5 315-0-10.5 3~5-0-~0.5 3,s-~•-l•J.s / / / / DAOE 8 ========
•
liiiii liiiiiii
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c:::=:i
c:::::::=i
c::::::J
PROPERTY BOlJNOARY
---
' '
SCALE (FEET)
100 100 200 JOO
--- --
0
CJ
~
9
FIGURE 1
. lOCA >IElL
ffALEIGH/;~::;~llE.
KOPPERS COHP.U<Y, ' INC.
-- --- -- -
KEYSTONE ENVIRONMENTAL RESOURCES
TABLE OF CONTENTS PRODUCED ON 10/24/86 AT 10,36 PAGE
=r==•==~=•a•=••=•--•-•zxa••==••=•=•====
SAMPLE* SOURCE DESCRIPT
-i-------R 60002
R 60003
RN860004
Rt60005
R 60006
RN860007
RE60008
R 60009
R 860010
I
I
I
I
I
I
I
I
I
I
I
I
---------------
\I/ELL M\11-4
\1/E LL M\11-6
\1/E LL M\11-7
\1/E LL M\11-8
\I/ELL M\11-10
\1/E LL M\11-11
\1/E LL M\11-12
\1/E LL FB
\I/ELL TS
--------------------
MONITORING \1/E LL S
MONITORING \I/ELLS
MONITORING \I/ELLS
MONITORING \I/ELLS
MONITORING \I/ELLS
MONITORING \I/ELLS
MONITORING \I/ELLS
MONITORING \I/EL LS
MONITORING \I/ELLS
DATE-COL DATE-REC
----------------
09/09/86 09/10/86
09/09/86 09/10/86
09/09/86 09/10/86
09/09/86 09/10/86
09/09/86 09/10/86
09/09/96 09/10/86
09/09/86 09/10/86
09/09/86 09/10/86
09/09/86 09/10/86
KEYSTONE ENVIRONMENTAL RESOURCES
TABLE 1: SUMMARY OF ANALYTICAL DATA PRODUCED ON 10/24/86 AT 10:41 PAGE·
I -=----------------•-•===•=-=•==== ::c :II""=::.--
SAMPLE_. RSL T. LNE
l~~~~~~-~x~~~~~i~0:7~~-::::~--::~:----------------
RN860003 COD (Total>, mg/L:: 50.0
t .860004 COD (Total),
860005 COD (Total>,
RN860006 COD (Total),
-~860007 COD (Total),
~860008 COD (Total),
RN860009 COD (Total),
mg/L: < 10. 0
mg/L: 50.0
mg/L: 35.0
mg/L: 40.0
mg/L: 20.0
mg/L: (10.0
ENDUCTIVITY .
860002 cona. ,umnos;cm 1508
860003 cona. ,umnos/cm 1796
RN860004 cona. ,umnostcm 1778
IN860005 cona. ,umnos/cm 951
N860006 cona. ,umnos/cm 980
RN860007 cona. ,umnos;cm 1200
IN860008 Cona. ,umnos1cm 1 185
N860009 cona. ,umnos/cm 0.00
RN860010. cona. ,umnostcm 0.00
IHENOL N860002 Pneno1 mg/L: 0.005
N860003 Phenol mg/L: 0.006
RN860004 Pnenol mg/L: 0.005
IN860005 Pneno1 mg/L: 0.005
N860006 Phenol mg/L: (0.005
R..-;860007 Pnenol mg/L: 0 . 0 1 1
-N860008 Phenol mg/L: <0.005
NB60009 Pnenol mg/L: <0.005
OTAL ORGANIC CARBON
jN860003 TOC, mg/L: 3.85
N860006 TOC, mg/L: 3. 15
N860008 TOC, mg/L: 3.74
RN860004 TOC, mg/L: 4.70
IN860002 TOC, mg/L: 5.47
N860007 TOC, mg/L.: 6. 19
RN860005 TOC, mg/L: 9. 17
-~860009 TOC, mg/L: < 1. 00
N860002 pH, uni ts 8. 1
RN860003 PH, uni ts 7.4
IN860004 PH, uni ts 7.7
N860005 pH, units 7. 1
RN860006 pH, uni ts 6.4
IN860007 pH, units 7.7
N860008 pH, units 7.5
RN860009 pH, uni ts 7.3
rN860010 pH, uni ts 7.8
I
,
SOURCE ---------------
WELL MW-4
WELL MW-6
WELL MW-7
WELL MW-8
WELL MW-10
WELL MW-11
WELL MW-12
WELL FB . 'I
WELL MW-4 }W -~Y-WELL MW-6
WELL MW-7 \ ..... ✓-
\I/ELL M\11-8
WELL M\11-1 0
WELL MW-11
WELL MW-12
WELL FB
WELL TB
WELL MW-4
WELL MW-6
WELL MW-7
\IIE LL M\11-8
WELL M\11-10
WELL MW-11
\I/ELL M\11-12
\I/ELL FB
\1/E LL MW-6
\1/E LL MW-10
\1/E LL M\11-12
WELL MW-7
\IIE LL MW-4
\1/E LL M\11-11
\I/ELL MW-8
\1/E LL FB
WELL M\11-4
\I/ELL MW-6
\I/ELL MW-7
\1/E LL MW-8
\I/ELL M\11-10
WELL MW-11
\I/ELL M\IJ-12
\1/E LL FB
\I/ELL TB
I
KEYSTONE ENVIRONMENTAL RESOURCES
TABLE 1, SUfvMARY OF ANALYTICAL DATA PRODUCED ON 10/24/86 AT 10,41 PAGE 2
1=======--=------------=--•============
SAMPLE* RSLT.LNE SOURCE
-

-
-------------------------------------------------------
1~::-:l:SOVLED SOLIDS
RN860002
1860003
860004
RN860005
1860006
860007
N860008
1860009
I
I
I
I
I
I
I
I
I
I
I
mg/L,
mg/L,
mg/L,
mg/L,
mg/L,
mg/L,
mg/L,
mg/L,
TDS @103 C
TDS @103 C
TDS @103 C
TDS @103 C
TDS @163 C
TDS @103 C
TDS @103 C
TDS @103 C
947
1133
1320
675
635
1020
970
38.0
WELL
WELL
WELL
WELL
WELL
WELL
WELL
WELL
MW-4
MW-6 '(v" MW-7
MW-8
MW-10
MW-11
M\11-12
FB
========
,..,,
('ii \
KEYSTONE ENVIRONMENTAL RESOURCES
PRODUCED ON 10/24/86 AT 10:41 PAGE
IMPLE ;+ RSL T. LNE SOURCE
---------------------------------------------------------------
LORIDE
RN860002 en 1or iae, mg/L: 136 WELL M\11-4
1860003 cn1oriae, mg/L: 330 \1/E LL M\11-6
860004 cn1oriae, mg/L: 253 \I/ELL M\11-7
RN860005 cn1oriae, mg/L: 68.0 \I/ELL M\1/-8
1860006 cn1oriae, mg/L: 126 \I/ELL M\11-10
860007 ·en 1or iae, mg/L: 97.0 \I/ELL M\11-11
860008 cn1oriae, mg/L: 107 \I/ELL M\11-12
RN860009 en 1or i ae, mg/L: (1.00 \1/E LL FB
IUOR IDE
860002 F1uoriae, mg/L: 0.610 \I/ELL M\11-4
RN860003 Fluor i ae, mg/L: 0.500 \I/ELL M\11-6
1860004 Fluorioe, mg.IL: 0.520 \1/E LL M\11-7
860005 F1uoriae, mg/L: 0.290 \I/ELL M\11-8
860006 Fluoriae, mg/L: 0.310 \1/E LL M\1/-10
1860007 Fluoriae, mg/L: 0.680 \1/E LL MIi/-11
· 860008 Fluoriae, mg/L: 0 540 \I/ELL M\11-12
86.0009 Fluoriae, mg/L: 0 ~ 110 \I/ELL FB
NITRATE
1860002 Nitrate as N' mg/L: < 0. 100 \1/E LL M\11-4
860003 Nit.rate as N • mg/L: < 0. 100 \1/E LL M\11-6
RN860004 Nitrate as N, mg/L: < 0. 1 00 \1/E LL M\11-7
1860005 Nitrate as N, mg/L: < 0. 100 \I/ELL M\11-8
860006 Nitrate as N • mg/L: < 0. 100 \1/E LL M\11-10
860007 Nitrate as N, mg/L: <0. 100 \1/E LL M\11-11
RN860008 Nitrate as N, mg/L: < 0. 1 00 \1/E LL MW-12
1860009 Nitrate as N, mg/L: < 0. 100 \1/E LL FB
TRITE
RNS60002 Nitrite as N • mg/L: (0.010 \I/ELL M\1/-4
1860003 Nitrite as N, mg/L: <0.010 WELL M\1/-6
860004 Nitrite as N, mg/L: <0.010 WELL M\11-7
RN860005 Nitrite as N' mg/L: (0.010 \1/E LL M\1/-8
1860006 Nitrite as N • mg/L: <0.010 \1/E LL M\11-10
860007 Nitrite as N, mg/L: <0.010 \1/E LL M\11-1 1
860008 Nitrite as N' mg/L: <0.010 \1/E LL M\11-12
RN860009 Nitrite as N, mg/L: <0.010 \1/E LL FB
ILFATE
860002 sulfate, mg/L: 24.7 \I/ELL M\11-4
RN860003 Sulfate, mg/L: (10.0 \1/E LL M\11-6
1860004 Sulfate, mg/L: · < 10. 0 \1/E LL M\11-7
860005 sulfate, mg/L: <10.0 \I/ELL M\1/-8
RN860006 Sulfate, mg/L: (10.0 \1/E LL M\11-10
1860007 Su If ate, mg/L: 153 \1/E LL M\11-1 1
860008 Sulfate, mg/L: 45.5 \I/ELL M\11-12
860009 Sulfate, mg/L: (10.0 \1/E LL FB
I
I
I
I
KEYSTONE ENVIRONMENTAL RESOURCES
TABLE 3: SU!'IMARY OF METALS DATA PRODUCED ON 10/24/66 AT 10:47 PAGE
,.===-= . . t =-=-~~-----------------------=-=•=•=-
SAMPLE# RSLT. LNE. SOURCE
:l;;~~~----------------------------------------------------------
~860002
RN860003
Fll860004
i=aa6ooos
RN860006
1860007
860008
RN860009
1860010
LCIUM
860002
RN860003
1860004
860005
RN860006
1860007
860008
860009
1860010
ROMI UM
860002
RN860003
1860004
860005
RN860006
1860007
860008
860009
1860010
GNESIUM
860002
RN860003
IJl860004
.860005
RN860006
I 1860007
860008
860009
IN860010
I
I
I
Arsenic, mg/L: <0.-010
Arsenic, mg/L: <0.010
Arsenic, mg/L: <0.010
Arsenic, mg/L: <0.010
Arsenic, mg/L: <0.010
Arsenic, mg/L: <0.010
Arsenic, mg/L: <0.010
Arsenic, mg/L: 0. 011
Arsenic, mg/L: <0.010
calcium, mg/L: 25.5
ca I c i um, mg/L: 57.9
Calcium, mg/L: 50.4
ca I c ium, mg/L: 41. 0
Calcium, mg/L: 53.3
ca 1c ium, . . mg/L: 45.4
Calcium, mg/L: 36.7
ca I c ium, mg/L: < 1. 00
Calcium, mg/L: < 1. 00
cnromium, mg/L: <0.050
Chromium, mg/L: <0.050
cnrom1um, mg/L: <0.050
cnromium, mg/L: <0.050
cnrorn:um, mg/L: (0.050
Chromium, mg/L: <0.050
cnromium, mg/L: <0.050
cnromium, mg/L: <0.050
cnromium, mg/L: (0.050
MagneSium, mg/L, 35.2
Magnesium, mg/L: 53.9
Magne~ium, mg/L: 64.9
Magnesium, mg/L: 31.1
Magne~ium, mg/L: 38.2
Magnesium, mg/L: 32.4
Magnesium, mg/L: 33.2
Magnesium, mg/L: < 1 . 0
Magnesium, mg/L: < 1 . 0
\I/ELL M\1/-4
\1/E LL M\11-6
\1/E LL M\1/-7
\1/E LL M\11-6
\1/E LL M\11-10
\1/E LL M\1/-1 1
\I/ELL M\11-12
\I/ELL F8
\1/E LL TB
\1/E LL M\1/-4
\1/E LL MW-6
\1/E LL MW-7
\I/ELL MW-8
\1/E LL M\1/-10
\1/E LL M\11-11 ·
\I/ELL M\1/-12
\1/E LL FB
\I/ELL TB
\1/E LL M\1/-4
\I/ELL M\11-6
\I/ELL M\1/-7
\I/ELL M\11-8
\1/E LL MIii-1 0
\1/E LL M\11-11
\1/E LL 1\11\lJ-1 2
\1/E LL FB
\1/E LL TB
\1/E LL M\1/-4
\I/ELL M\11-6
\1/E LL M\1/-7
\1/E LL M\11-8
\1/E LL M\1/-10
\1/E LL MIii-1 1
\1/E LL M\1/-12
\1/E LL FB
\1/E LL TB
SAMPLE*
·~~;;:~~-
;1'860002
RN860003
1860004
860005
RN860006
1860007
860008
860009
E60010
\UM
960002
RN860003
1860004
860005
RN860006
1860007
860008
860009
RN860010
I
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KEYSTONE ENVIRONMENTAL RESOURCES
PRODUCED ON 10/24/86 AT 10:47 PAGE 2
======z::=
RSLT.LNE SOURCE ---------------
Potassium, mg/L: 9.95 WELL M\11-4
Potassium, mg/L: 3.37 WELL MW-6
Potassium, mg/L: 7.69 WELL M\11-7
Potassium, mg/L: 3.30 WELL MW-8
Potassium, mg/L: 4.62 WELL M\11-10
Potassium, mg/L: 7.47 WELL M\11-11
Pot:ass;um, mg/L: 5.48 WELL t,,1\11-12
Potassium, mg/L: < 1. 00 WELL FB
Potassium, mg/L: < 1. 00 WELL TB
soa;um, mg/L: 140 WELL M\11-4
soa1um, mg/L: 184 \I/ELL M\11-6
soaium, mg/L: 150 WELL M\11-7
SOClium, mg/L: 53.2 WELL MW-8
SOCliUm, mg/L: 44.2 WELL MW-10
sooium, mg/L: 82.0 WELL M\11-11
soa;um, ''Tlg / L : 56.7 WELL MW-12
SOOium, mg/L: < 1 . 00 WELL FB
sooium, mg/L: < 1 . 00 WELL TB
KEYSTONE ENVIRONMENTAL RESOURCES
I
TABLE 4: SUMMARY OF ORGANIC COMPOUNDS
1=#ss•~=•••••••••••••*•••••=•==••••••••
SAMPLE* RSLT.LNE
l ~~~;HLOROPHENOL BY EPA METHOD 604
860002 Pentacn1oropneno1 : 57. 1
RN860003 Pentacn I oropneno I 163
1860004 Pentacn1oropneno1 <1.00
860005 Pentacn1oropneno1 11.4
RN860006 Pentacn1oropneno1 71.2·
1860007
860008
860010
Pentacn1oropneno1
Pentacn1oropneno1
Pentacn1oropneno1
< 1. 00
< 1. 00
< 1 . 00
resu1ts are reportea in ug/L.
I
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I
PRODUCED ON 10/24/86 AT 10:44 PAGE
SOURCE
\I/ELL M\11-4
\1/E LL M\1/-6'--
\1/E LL M\11-7
\I/ELL M\11-8
\1/E LL M\11-10
\1/E LL M\11-1 1
\1/E LL M\11-12
\1/E LL TB
I
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KEYSTONE ENVIRONMENTAL RESOURCES
TABLE 5, SUMMARY OF ANALYTICAL DATA
• , ~ = =. =.= ••••• ---• --

-
-

-
-= --•• --

=

•• --•• -=
SAMPLE# RSLT.LNE
Rl60002-
R 60003
RNB60004
Rl60005
R 60006
RNB60007
Rl60008
R 60009
R 60010
I
I
I
I
I
I
I
I
I
I
I
I
1 sopropy I
1sopropy1
1sopropy1
1sopropy1
1sopropy1
1sopropy1
1sopropyl
1sopropy1
1sopropy1
Etner,ug/L, (100
Etner,ug/L, (100
Etner,ug/L, (100
Etner,ug1L, < 1 00
Etner,ug1L, (100
Etner,ug/L, (100
Etner,ug1L, (100
Etner,ug/L, ,100
Etner ,u,J/L, (100
PRODUCED ON 10/28/86 AT 07,22 PAGE
SOURCE
WELL M\1/-4
\I/ELL M\1/-6
\I/ELL M\1/-7
\I/ELL M\1/-8
\I/ELL MW-10
\I/ELL M\1/-11
\I/ELL MW-12
\1/E L.1. FB
WELL TB
I
I
SAMPLE * 1--------86003!5
860036
RN960037
t860038
860039
RN860040
I
I
I
I
I
I
I
I
I
I
I
I
I
11
KEYSTONE ENVIRONMENTAL RESOURCES
PRODUCED ON 10/24/86 AT 10,56 PAGE 1
SOURCE DESCRIPT DATE-COL DATE-REC
---------------------------------------------------
\I/ELL MIii-1 MONITORING \I/ELLS 09/10/86 09/11/86
WELL M\11-2 MONITORING WELLS 09/10/86 09/11/86
WELL M\11-3 MONITORING \1/E L LS 09/10/96 09/11/86
\1/E LL M\11-5 MONITORING \I/ELLS 09/10/86 09/11/86
\1/E LL M\11-9 MONITORING \I/ELLS 09/10/86 09/11/86
FB MONITORING WELLS 09/10/86 09/11/8<3
' --<
I
I KEYSTONE ENVIRONMENTAL RESOURCES
SAMPLE* RSLT.LNE l;~~~~~-;x~~;~-~;~~~~-----------------------------
RN860035 COD (Total), mg/L, 50.0
1860036 COD (Total), mg/L, 75.0
860037 COD (Total), mg/L, 20.0
860038 COD (Total), mg/L, 52.0
RN860039 COD (Total), mg/L, 15.0 t 860040 ·coo cTotal>, m,~/L, <10.0
NDUCTIVITY
RN860035 cono. ,umnos/cm 1580
1860036 cono. ,umnos/cm 1350
860037 cono. ,umnos/cm 750
RN860039 cona. ,umnos/cm 550
cono. ,umnos/cm 0.00
-iENOL
1860040
860035 Pneno1 mg/L, (0.005
RN860036 Pneno1 mg/L, <0.005
· t860037 Pneno1 ,:-ng/L' 0.021
860038" Pneno1 mg/L, <0.005
RN860039 Pneno 1 • mg/L, <0.005
.-,860040 Pneno 1 . mg /L: < o. 005
IFTAL ORGANIC CARBON
RN860035 TOC, mg/L, 10.77
1860036 TOC, mg/L, 5.53
860037 TOC,
860038 TOC,
RN860039 TOC,
.860040 TOC,
mg/L, 41. 66
mg/L, 4.33
mg/L, 4.98
mg/L, 1. 06
11:>TAL DISSOLVED SOLIDS
RN860035 mg/L, TDS @103 C
11"86003<3
lfl860037
RN860038
i(,860039
~860040
RN860035
ltJ860036
.860037
RN860039
r860040
I
I
I
mg/L, TDS
mg/L ,· TDS
mg/L, TDS
mg/L, TDS·
mg/L, TDS
pH, uni ts
pH, uni ts
pH, units
pH, uni ts
pH, units
@103 C
@ 103 C
@103 C
@103 C
@103 C
7. 1
7.5
6.7
7.2
6.3
1000
832
650
975
480
68.0
SOURCE ---------------
WELL MW-1
WELL MW-2
WELL MW-3
WELL MW-5
WELL r-AW-9
FB
WELL MW-1
·wELL MW-2
WELL MW-3.
WELL MW-9
FB
WELL MW-1
WELL MW-2
WELL MW-3 _,_.,....-·
WELL MW-5
WELL MW-9
FB
WELL MW-1
WELL MW-2
WELL MW-3 . ..-------
WELL MW-5
WELL MW-9
FB
WELL MW-1
WELL MW-2
WELL MW-3
WELL MW-5
WELL MW-9
FB
WELL MW-1
WELL MW-2
WELL MW-3
WELL MW-9
FB
I
I
SAMPLE#
l:;;~~;--
RN860035
1860036
860037
860038
RN860039
1860040
UORIDE
RN960035
1860036
860037
RN860038
1860039
960040
ITRATE
RN860035
li-Je60035
ll,J050037
RN860038
1860039
860040
!TRITE
1960035
860036
960037
RN96003,9
li'J960039
.860040
SULFATE
1960035
860036
860037
RN860038
a-i060039
IN060040
I
I
I
I
I
KEYSTONE ENVIRONMENTAL RESOURCES
PRODUCED ON 10/24/96 AT 11 :00 PAGE 1
RSLT.LNE SOURCE ---------------
cn1oriae, mg/L: ,02 WELL MW-1
cn1oriae, mg/L: 53.0 WELL MW-2
cntorioe, mg/L: 53.0 WELL MW-3
cn1oriae, mg/L: 223 WELL MW-5
en 1or i ae, mg/L: 33.0 WELL MW-9
cn1oriae, mg/L: < 1 . 00 FB
Fluor oe, mg/L: 0.440 WELL Mlll-1
Fluor ae, mg/L: 0.540 WELL MW-2
Fluor ae, mg/L: 0.700 WELL MW-3
Fluor ae, mg/L: 0.480 WELL MW-S
Fluor. de, mg/L: 0.490 WELL MW-9
Fluor ae, mg/L: 0.350 FB
Nitrate a:3 N, mg/L: (0. 100 WELL MIii-1
Nitrate as N, m,;;/L: < 0. 1 00 WELL' MW-2
Nitrate as N, mg/L: <0. ,oo WELL MW-3
Nitrate as N, mg/L: < 0 . 100 11/E LL MW-5
Nitrate as N, mg/L: (0. 100 WELL MW-<?
Nitrate as N' m9 IL: < 0. 100 FB
Nitrite as N' mg/L: (0.010 WELL MW-1
Nitrite as N, mg/L: (0.010 WELL MW-2
Nitrite as N' mg/L: <0.010 WELL MW-3
Nitrite as N, m9/L: (0.010 WELL MW-5
Nitrite as N, mg/L: (0.010 WELL MW-9
Nitrite as N' mg/L: (0.010 FB
su If ate, mg/L: 27.3 WELL Mlll-1
su I fa.te, mg/L: 38.8 WELL MW-2
sulfate, mg/L: 22.7 WELL MW-3
Sulfate, mg/L: 23.0 WELL MW-5
Sulfate, mg/L: 30.6 WELL MW-9
Sulfate, mg/L: 15. 8 FB
I
I
KEYSTONE ENVIRONMENTAL RESOURCES
TABLE 3: SUM'AARY OF METALS DATA PRODUCED ON 10/24/96 AT 10:59 PAGE 1
I •=a=•••••a••••••••••••=====•=•=• = ... --==•.
SAMPLE* RSLT.LNE
l~~~~~:--
RN860036
RIIB60037
R11e6003e
RN860039
1860040
LCIUM
860035
RN860036
Fll060037
Fll060038
RN860039
1860040
ROMIUM
RN860035
1860036
860037
860038
RN860039
1860040
~ GNES IUM
RN860035
1860036
960037
RN860038
1860039
860040
TASSIUM
RN960035
18600:36
860037
RN860038
. 1860039"
• 860040
SODIUM
1960035
860036
860037
RN860038
1960039
860040
I
I
I
----------------------------------------
Ar~enic, mg/L: <0.010
Arsenic, mg/L: 0.018
Arsenic, mg/L: <0.010
Arsenic, mg/L: <O. 010
Arsenic, mg/L: <O. 010
_f'rsenic, mg/L: <O .010
Calcium, mg/L: 35.9
Calcium, mg/L: 23.5
Calcium, mg/L: 17.0
Calcium, mg/L: 46.9
calcium, mg/L: 22.4
Calcium, mg/L: < 1 . 00
cnromi um, mg/L: <0.050
cnromium, mg/L: <0.050
cnromium, mg/L: ,-0.050
cnromium, mg/L: <o. oso·
cnromium, mg/L: <0.050
cnromium, mg/L: <0.050
Magnesium, mg/L: 31. 0
Magnesium, mg/L: 26.8
Magnesium, mg/L: 20.4
Magnesium, mg/L: 5 1 . 9
Magnesium, mg/L: 9.75
Magnesium, mg/L: < 1 . 00
Potassium, mg/L: 9.25
Potassium, mg/L: 5.55
Potassium, mg/L: 6.65
Potassium, mg/L: 9.59
Potassium, mg/L: 3.63
Potas:sium, mg/L: < 1. 00
soaium, mg/L: 233
SOOium, mg/L: 207
Sodium, mg/L: 149
SOOium, mg/L: 180
soaium, mg/L: 56. 8
SOOium, mg/L: < 1 . 00
==-==-•==,..
SOURCE ---------------
WELL MW-1
WELL MW-2
WELL MW-3
WELL MW-5
WELL MW-9
F8
WELL MW-1
WELL MW-2
WELL MW-3
WELL MW-5
WELL MW-9
FB
WELL MW-1
WELL MW-2
WELL MW-3
WELL MW-5
WELL MW-9
FB
WELL MW-1
WELL MW-2
WELL MW-3
WELL M\IJ-5
WELL MW-9
FB
WELL MW-1
WELL MW-2
WELL MW-.3
WELL MW-5
WELL MW-9
F8
WELL MW-1
WELL MW-2
WELL MW-3
WELL M\11-5
WELL MW-9
FB
I
KEYSTONE ENVIRONMENTAL RESOURCES
I
TABLE 4, SUr,w\ARY OF ORGANIC COMPOUNDS
1 ==-~•••••••••••••••~a••••===•••••= :at===· .
SAMPLE# RSLT.LNE
::l~~;~~~;;OPHENO. L BY EPA METHOD 604
~860035 Pentacn1oropneno1 , <1.00
RN8e0036 P_entacn I oropneno I < 1 . oo
i:11000037 Pentacn1oropneno1 5.85
ra860038 Pentacn1oropneno1 411
RN860039 Pentacn1oropneno1 4.28
FWB60040 Pentacn1oropneno1
~ove results are reportea in
I
I
I
I
I
I
I
I
I
I
I
I
I
1. 96
ug/L.
PRODUCED ON 10/24/86 AT 11,01
SOURCE
\liELL M\11-1
\1/E LL M\11-2
\1/E LL M\11-3 )
\1/E LL M\11-5 ~
WELL MW-,, ?
FB
PAGE 1
==-•====:a
I
KEYSTONE ENVIRONMENTAL RESOURCES
I
TABLE 5: SUMMARY OF ANALYTICAL DATA PRODUCED ON 10/27/86 AT 12:01
1·····~---------------------··••=•••=••
SAMPLE~ RSLT.LNE SOURCE
-----------------------------------------------------------------18'50035
860036
RN860037
1860038
860039
RN860040
I
I
I
I
I
I
I
I
I
I
I
I
I
I
1sopropy1
1sopropy1
1sopropy1
1sopropy1
1sopropy1
1sopropy1
Etner,ug/L:
Etner,ug/L:
Etner,ug/L:
Etner,ug/L:
Etner,ug/L:
Etner,ug/L:
{100 \I/ELL M\11-1
{100 \I/ELL M\11-2
{100 \I/ELL M\11-3
{100 \1/E LL M\11-S
< ·100 \1/E LL M\11-9
< 100 FB
PAGE
I
SAMPLE ..
1--------860029
860030
RN860031
1860032
860033
RN860034
I
I
I
I
I
I
I
I
I
I
I
I
I
I
KEYSTONE ENVIRONMENTAL RESOURCES
PRODUCED ON 10/24/86 AT 10,52 PAGE 1
=======a
SOURCE DESCRIPT DATE-COL DATE-REC
---------------------------------------------------
WELL 111-1 MONITORING WELLS 09/10/86 09/11/86
WELL \11-2 MONITORING WELLS 09/10/86 09/11/66
WELL 111-3 MONITORING WELLS 09/10/86 09/11/86
WELL 111-4 MONITORING WELLS 09/10/86 09/11/86
WELL 111-5 MONIT!)RING WELLS 09/10/86 09/11/86
WELL 111-14 MON !TOR ING WELLS 09/10/86 09/11/66
I
I
KEYSTONE ENVIRONMENTAL RESOURCES
TABLE 1: SUM"IARY OF ANALYTICAL DATA
I ==--=~------------~--=•2==•••======• ==-•==-=.
SAMPLE* RSLT.LNE
IEMICAL OXYGEN DEMAND
~860029 COD (Total), mg/L:
RN860030 COD (Total), mg/L:
<10.0
<10.0
1860031 COD (Total), mg/L: <10.0
860032 COD(Total),mg/L: -20.0
RN860033 COD (Total), mg/L: <10.0
25.0 1f1860034 .. COD
a='NDUCTIVITY
<Total>, mg/L:
RN860029 cona. ,umnos/cm
1860030
860031
860032
RN860033
.860034
a-iENOL
cona. , umnostcm
cona. , umnos/cm
cona. , umnos/cm
cona. , umnos/cm
con a. , um nos /cm
670
530
520
1000
350
1 130
RN860029 Pneno1 mg/L:
E860030 Pnenol mg/L:
860031 Pnenol mg/L:
860032 Pnenol, mg/L:
RN860033 Pneno1, mg/L: t 860034 Pnenol, mg/L:
<0.005
<0.005
<0.005
<0.005
<0.005
<0.005
TAL ORGANIC CARBON
RN860029
it'l860030
.860031
RN860032
TOC,
TOG,
TOC,
TOC,
mg/L:
mg/L:
mg/L:
mg/L:
mg/L:
mg/L:
< 1 . 00
< 1 . 00
< 1 . 00
1 . 65
< 1 . 00
2.00
-
N860033 TOC,
N860034 TOC,
OTAL DISSOLVED SOLIDS
RN860029 mg/L, TDS @103 C
IN860030 mg/L, TDS @103 C
N860031 mg/L, TDS @103 C
RN860032 mg/L, TDS @103 C
IN860033
N860034
pH
IN860029
N860030
N860031
RN860032
IN860033
N860034
I
I
I
mg/L, TDS @103 C
mg/L, TDS @103 C
pH, uni ts 7.4
pH, units 7.4
pH, units 7.5
pH, units 7.2
pH, units 7.5
pH, ·uni ts 7. 1
389
308
290
630
264
742
PRODUCED ON 10/24/86 AT 10:55 PAGE
SOURCE ---------------
WELL \1/-1
WELL \1/-2
\I/ELL \1/-3
\I/ELL W-4
WELL \1/-5
\1/E LL \1/-14
\1/E LL \1/-1
\I/ELL \11-2
\1/E LL W-3
\1/E LL \1/-4
\1/E LL W-5
\1/E LL W-14
WELL \1/-1
\I/ELL \1/-2
WELL \1/-3
\I/ELL \1/-4
WELL W-5
WELL W-14
WELL W-1
\I/ELL \1/-2
·WELL W-3
WELL \1/-4
\1/E LL W-5
WELL W-14
WELL W-1
WELL \1/-2
WELL \1/-3
WELL W-4
WELL \1/-5
WELL W-14
WELL \1/-1
\I/ELL \1/-2
WELL W-3
\1/E LL \1/-4
WELL \1/-5
WELL W-14
I
I
KEYSTONE ENVIRONMENTAL RESOURCES
TABLE 2: SUMMARY OF ANALYTICAL DATA r ·=sGa••==•••••••••::raamaa=•••a::r2aaa ::a :,: D ,_ ::r
SAMPLE# RSLT.LNE .
l~~~i~--
RN860030
A9360031
Rll560032
RN860033
160034
F ORIDE
860029
RN860030
4860031
~860032
RN860033
JW860034
~TRATE
RN860029
1860030
860031
860032
RN860033
icas60034
~TRITE
RN860029
1860030
860031
860032
1860033
860034
LFATE
RN860029
1860030
860031
RN860032
1860033
860034
I
I
I
I
I
cn1oriae, mg/L, 29.0
cn1oriae, mg/L, 16.0
cn1oriae, mg/L, 23.0
Chloride, mg/L, 126
cn1oriae, mg/L, 14.0
Chloride, mg/L, 141
Fluoriae, mg/L, 0. 150
Fluoriae, mg/Le 0. 150
Fluoriae, mg/L, 0.310
Fluoriae, mg/L: 0. 150
Fluoriae, mg/L, 0. 150
Fluoriae, mg/L: 0.400
Nitrate as N' mg/L: < 0. 1 00
Nitrate as N, mg/L: 0.254
Nitrate as N, mg;•_: 1. 60
Nitrate as N, mg/L: < 0. 100
Nitrate as N, mg/L: 0.978
Nitrate as N, mg/L: < 0. 1 00
Nitrite as N, mg/L, (0.010
Nitrite as N, mg/L, <0.010
Nitrite ·as N' mg/L, <0.010
Nitrite as N, mg/L, <0.010
Ni'trite as N, mg/L: <0.010
Nitrite as N, mg/L, <0.010
Sulfate, mg/L: 12.5
SU If ate' mg/L, 23.2
SU If ate' mg/L: 14.6
Sulfate, mg/L, 16.3
SUifate, mg/L: 11 . 9
Sulfate, mg/L: 25.2
PRODUCED ON 10/24/86 AT 10,54
SOURCE ---------------
WELL W-1
WELL w-2
WELL W-3
WELL W-4
\I/ELL W-5
WELL W-14
WELL w-1
WELL w-2
WELL W-3
WELL W-4
WELL \11-5
WELL \11-14
WELL W-1
WELL \11-2
WELL W-3
WELL W-4
WELL \11-5
WELL \11-14
WELL \11-1
WELL w-2
WELL \11-3
WELL W-4
WELL W-5
WELL W-14
WELL W-1
WELL W-2
WELL \11-3
WELL W-4
WELL. W-5
WELL \11-14
PAGE
::r::r::r::r::r::r::r=
KEYSTONE ENVIRONMENTAL RESOURCES
I
TABLE 3: sur,T,IARY OF METALS DATA PRODUCED ON 10/24/86 AT 10e55 PAGE
1=•--=~-=-------------------------~===•
SAMPLE* RSLT.LNE
1;;~~~--
860029
RN860030
1860031
860032
RN860033
1860034
LCIUM
860029
RN860030 1860031
860032
RN860033
rs60034
IJiROMIUM
RN860029
1860030
860031
860032
RN860033
ll,l050034
a,_GNESIUM
RN860029
1Jl860030
lr860031
RN860032
1860033
860034
TASSIUM
RN860029
9,860030
.860031
RN860032
lfl860033
r860034
SODIUM
1860029
860030
: 860031
RN860032
19'1860033
!1-1060034
.I
I
I
-----------------------------------------
Arsenic, mg/L, <0.010
Arsenic, mg/L: <0.010
Arsenic, mg/L: <0'.010
Arsenic, mg/L: <0.010
Arsenic, mg/Le <0.010
__ Arsenic, mg/L: <0.010
Calcium, mg/Le 53.0
Calcium, mg/L: 36. 1
catcium, mg/Le 36.7
Calcium, mg/Le 97.9
ca1c ium, mg/Le 31. 5
Calcium, mg/L: 1 17
cnromium, mg/Le <0.050
cnromium, mg/Le <0.050
cnromium, mg/Le <0.050
cnromium, mg/Le <0.050
Chromium, mg/Le <0.050
cnromium, mg/Le <0.050
Magnesium, mg/L: 29.4
Magnesium, mg/Le 21. 4
Magnesium, mg/Le 19.9
Magnesium, mg/Le 28.5
Magnesium, mg/Le 14.9
Magnesium, m9/Le 22. 1
Potassium, mg/Le 1. 90
Potassium, mg/Le 1. 47
Potassium, mg/Le 2. 03
Potassium, mg/L: 2.38
Potassium, mg/Le 2.52
Potassium, mg/Le 1. 37
SOOium, mg/Le 12.6
SO<lium, mq/L: 13.2
SOOium, mg/Le 16.0
Sodium, mg/Le 27.0
SOOium, mg/Le 15 . 1
sooium. mg/Le 24. 1
:z=::11:::i:zz .. a
SOURCE
---------------
\I/ELL 111-1
\I/ELL \11-2
\1/E LL \11-3
\I/ELL \11-4
\1/E LL \11-5
\1/E LL \11-:14
\1/E LL 111-1
\I/ELL \11-2
\1/E LL \11-3
\I/ELL \11-4
\1/E LL \11-5
\I/ELL \II-14
\I/ELL \11-1
\I/ELL \11-2
\1/E LL W-3
\1/E LL W-4
\1/E LL \11-5
WELL \II-14
WELL W-1
\I/ELL \11-2
WELL \11-3
WELL W-4
\I/ELL W-5
\1/E LL W-14
\1/E LL \II-1
\1/E LL W-2
\I/ELL W-3
\I/ELL W-4
\I/ELL W-5
WELL 'II-14
WELL \II -1
\I/ELL W-2
\I/ELL W-3
\I/ELL W-4
WELL \11-5
\I/ELL W-14
••
I
KEYSTONE ENVIRONMENTAL RESOURCES
PRODUCED ON 10/24/85 AT 10,57
SAMPLE .. RSLT. LNE SOURCE
1~~;;~~;;0;~;~;~ ;~-;;~-~;~~.;;-;~~----------------
RN860029 Pentacn I oropneno I · , < 1 . oo \I/ELL
RN960030 Pentacn1oropneno1 <1.00
1960031 Pentacn1oropneno1 <1.00
960032 Pentacn1oropneno1 <1.00
RN960033 Pentacn1oropneno1
1960034 Pentacn1oropneno1
ove results are reporteo in
I
I
I
I
I
I
I
I
I
I
I
I
< 1 . 00
(1.00
ug/L.
\11-1
\I/ELL \11-2
\1/E LL \11-3
WELL \11-4
WELL w-:s
\1/E LL W-14
PAGE
=:s====-==
I
SAMPLE#
l;;;;;;--
RN860030
1860031
860032
860033
RN860034
I
I
I
I
I
I
I
I
I
I
I
I
I
RSL T. LNE
1sopropy1
1sopropy1
1sopropy1
1sopropy1
1sopropy1
1sopropy1
..
KEYSTONE ENVIRONMENTAL RESOURCES
PRODUCED ON 10/28/86 AT 07, 11 PAGE
SOURCE
Etner,ug1L, (100 WELL W-1
Etner,ug/L, <100 \I/ELL W-2
Etner,ug1L, (100 WELL W-3
Etner,ug/L, ( 1 00 WELL W-4
Etner,ug/L, < 100 WELL w-s
Etner.ug/L, ( 100 WELL W-14
'
SAMPLE ;,
1--------860041
860042
RN860043
1860044
860045
RN860046
1860047
860048
RN860049
I
I
I
I
I
I
I
'I
I
I
I
I I
KEYSTONE ENVIRONMENTAL RESOURCES
PRODUCED ON 10/24/86 AT 11 ,OO PAGE
SOURCE DESCRIPT DATE-COL DATE-REC
---------------------------------------------------
\I/ELL \11-6 MONITORING \I/ELLS 09/11/86 09/12/86
\I/ELL \11-7 MONITORING \I/ELLS 09/11/86 09/12/86
\1/E LL \11-8 MONITORING \I/ELLS 0')/ 1 1 /86 09/12/86
\I/ELL \11-10 MONITORING WELLS 09/11/86 09/12/86
\1/E LL \11-12 MONITORING \I/ELLS 09/11/86 09/12/86
\1/E LL \11-13 MONITORING \I/EL LS 09/11/8'5 09/12/8'5
\1/E LL \11-15 MONITORING \I/ELLS 09/11/86 09/12/86
FB MONITORING \I/ELLS 09/11/8'5 09/12/86
TB MONITORING \I/ELLS 09/11/86 09/12/86
I KEYSTONE ENVIRONMENTAL RESOURCES
SAMPLE# RSLT.LNE J;~~~~~-;x~~;~-~;~~~~-----------------------------
RN860041 COD <Total), mg/L: 25.0
1860042
860043
860044
COD (Total), mg/L: 15.0
COD (Total l, mg/L: 15.0
COD (Total), mg/L: 10.0
RN860045 COD (Total), mg/L: 15.0
1860046 ··coo I To ta 1 > •
860047 COD (Total),
m,;;/L: ·12. 0
mg/L: (10.0
RN860048 COD (Total), mg/L: (10.0
1fJ860049 COD (Total),
.,NDUCTIVITY
mg/L: (10.0
RN86004 1 Cena. ·• umnos/cm 1 100
1860042 cona.
860043 cona.
860044 cona.
,umnos/cm 750
. L1mnos/cm 550
,umnos/cm 850
RN860045 ,umnos/cm 500
· .8600'46
.860047
RN860048
cona.
cona.
Cena.
cona.
cona.
,umnos/cm . -330
E860049
ENOL
N860041
,umnos/cm
,umnos/cm
, umnc)S/cm
Pneno1 mg/L:
Plieno I m9/L:
390
< 1 . 00
1. 00
0 .007
(0 .005 1860042
860043
860044
Pneno1 mg/L: <0.005
RN860045
a,.i860046
■N860047
Plieno I
Pher.c 1
Pnenol
Pneno1
mg/L: (0.005
mg/L: (0.005
mg/L: (0.005
mg/L: <0.005
RN860048 Pneno I m,~/L: <0.005
(0.00:S IN860049 Pneno1. mg/L:
OTAL ORGANIC CARBON
N860041 TOC, mg/L: 8.63
RN860042 TOC, mg/L,: 2.38
IM860043 TOC, mg/L: 4.94
NB60044 TOC, mg/L: 2.14
RN860045 TOC, mg/L: 1.17
IN860046
N860047
RN860048
IN860049
I
I
I
TOC, mg/L: 1.39
TOC, mg/L: <1.00
TOC , mg/ L : < 1 . 0 0
TOC, mg/L: <1 .00
SOURCE ---------------
\I/ELL \1/-6
\I/ELL \1/-7
\I/ELL \1/-8
\I/ELL w-10
WELL \1/-12
\I/ELL \I/-' 1 3
WELL \1/-15
FB
TB
WELL W-6
\I/ELL W-7
WELL \1/-8
\I/ELL \1/-10
WELL w-12
WELL· \1/-13
WELL \11-15
FB
TB
\I/ELL \11-6
'J/ELL \1/-7
\I/ELL \11-8
\I/ELL \11-10
WELL \1/-12
WELL '>I-13
WELL \11-15
FB
T9
\I/ELL \11-6
WELL \11-7
\1/E LL \11-8
\I/ELL \11-10
\1/E LL w-12
WELL \11-13
WELL \11-15
FB
TB
PAGE
=======-=-
••
I
KEYSTONE ENVIRONMENTAL RESOURCES
PRODUCED ON 10/24/86 AT 11,03
SAMPLE# RSLT.LNE SOURCE
l~:~:~~;;o~~~~~;~~~~~~::-:------~::---------------
WELL W-6
RN860042 mg/L, TDS @103 C 564
1860043 mg/L, TDS @103 C 408
860044 mg/L, TDS @103 C 604
R~860045 386 mg/L, TDS @103 C
1860046
860047
RN860048
i'.860049
-860041
RN860042
11,1860043
.1860044
RN860045
1860046
860047
860048
,860049
I
I
I
I
I
I
I
I
I
mg/L, TDS
mg/L, TDS
mg/L, TDS
mg/L, TDS
PH, uni ts
pH, units
PH, uni ts
PH, uni ts
PH, uni ts
pH, units
PH, -unit~
pH, uni ts
PH, uni ts
@103 C
@103 C
@103 C
@103 C
7. 1
7.5
7.6
7.2
7.4
7.5
6.5
7.4
7.4
•
260
366
38.0'
48.0
WELL W-7
WELL w-8
WELL w-10
WELL w-12
WELL W-13
WELL w-15 -·· FB
TB
WELL W-6
WELL W-7
WELL \11-8
WELL w-10
WELL w-,2
\1/E LL W-13
WELL W-15
FB
TB
PAGE 2
== = == = == =
I
I
SAMPLE;;
11:~;~~;--
~860041
RN860042
4ls60043
f'i1050044
RN860045
FJl860046
~860047
RN860048
1860049
UORIDE
860041
RN860042
1860943
860044
RN86004S
1860046
860047
NS60048
1860049
TRATE
860041
RN860042
1860043
860044
RN860Q4S
1860046
860047
860048
RNS60049
IITR ITE
~860041
RN860042
1860043
860044
RN860045
1860046
860047
860048
RNS60049
ilJLFATE
· lli060041
RN860042
a-1860043
a,i860044
'RN86004S
1860046
860047
860048
RN860049
I
KEYSTONE ENVIRONMENTAL RESOURCES
PRODUCED ON 10/24/86 AT 11:05 PAGE
RSL T. LNE SOURCE
---------------
cn1oriae. mg/L: 126 WELL W-6
cn1or;ae. mg/L: 78.0 WELL W-7
cn1oriae, mg/L: 53.0 WELL W-8
cn1orio.a, m,J/L:. 68.0 WELL W-10
cn1orice, mg/L: 24.0 WELL W-12
-cn1oriae. mg/L: 16.0 WELL W-13
cn1oriae, mg/L: 19.0 WELL W-15
cn1oriae, mg/L: < 1. 00 FB
cn1orice, mg/L: < 1 . 00 TB
Fluoride, mg/L: 0.400 WELL W-6
Fluoriae, mg/L: 0.300 WELL W-7
FIUOriOe, mg/L: 0.240 WELL W-8
Fluorioe, mg/L: 0.230 WELL W-10
F 1uor iae. mg/L: 0.200 WELL w-12
F'IUOr"iO-!:, mg/L: 0.280 WELL. W-13
Fluor.ice, mg/L: 0.200 WELL W-15
FIUOriae, mg/L: 0. 130 FB
Fluorioe, mg/L: 0. 120 TB
Nitrate a:s N, mg/L: 0. 176 WELL W-6
Nitrate as N, m•J/L: < 0 . 1 00 WELL W-7
Nitrate as N • mg/L: <O. 100 WELL w-s
Nitrate as N, mg/L: < 0. 1 00 WELL W-10
Nitrate as N • mg/L: 0.330 WELL \11-12
Nitrate as N, mg/L: < 0. 100 WELL IJ,i-1 3
Nitrate as N, mg/L: 0. 125 11.'ELL W-15
Nitrate as N, mg/ L: <O. 100 FB
Nitrate as N • mg/L: < 0. 100 TB
Nitri'te as N • mg/L: <0.010 WELL W-6
Nitrite as N, mg/L: <0.010 ';/ELL W-7
Nitrite as N, mg/L: <0.010 WELL W-8
Nit r i t·e a,s N, mg/L: <0.010 WELL w-10
Nitrite as N, mg/L: (0.010 WELL W-12
Nitrite a,s N • mg/L: <0.010 WELL W-13
Nitr_ite a,s N, mg/L: <0.010 WELL W-15
Nitrite as N, mg/L: <0.010 FB
Nitrite as N, mg/L: <0.010 TB
Sulfate, mg/L: 24.S WELL W-6
Su If ate. mg/L: 19.9 WELL W-7
Sulfate, mg/L: 19.3 WELL w-s
Sulfate, mg/L: 1 8. 1 WELL w-10
sulfate, mg/L: 16.9 WELL w-12
SUifate, mg/L: 16.7 \1/EL L W-13
Sulfate, mg/L: 12.2 WELL W-15
Sulfate, mg/L: 12.2 FB
SUifate, mg/L: <10.0 TB
I
I
SAMPLE;;
l ;;~~~---
860041
RN860042 1860043
860044
RN860045
1860046
860047
RN860048
ILCIUM
860041
860042
RN860043
ll-860044
.860045
RN860046
1860047
860048
ROMIUM
RN860041
l-iee,0042
~860043
RN860044
~860045
a,i0e,0046
RN860047
1860048
GNESIUM
860041
RN860042
a,i860043
li-i060044
RN860045
w-1860046
.. 860047
RN860048
I
I
I
I
I
KEYSTONE ENVIRONMENTAL RESOURCES
PRODUCED ON 10/24/86 AT 11 ,05 PAGE
RSL T. LNE SOURCE ---------------
Arsenic, mg/L, <o·. o 10 \I/ELL 111-6
Arsenic, mg/L, <0.010 11/E LL 111-7
Arsenic, mg/L, (0.010 WELL 111-8
Arsenic, mg/L, <0.010 WELL 111-10
Arsenic, mg/L, (0.010 11/E LL 111-12
Arsenic, mg/L, <0.010 WELL 111-13
Arsenic, m9/L, (0.010 \I/ELL 111-15
Arsenic, mg/L, <0.010 FB
Calcium, mg/L, 48.9 11/E LL 111-6
Calcium, mg/L, 34.2 11/E LL 111-7
Calcium, mg/L, 36.5 11/E LL 111-8
ca1ciUm, mg/L, 51. 0 \I/ELL 111-10
ca1cium, mg/L, 60.4 11/E LL 111-12
Calcium, mg/L, 34.7 \I/ELL 111-13
Calcium, mg/L, 37. t 11/E LL 111-15
ca1c·ium, mg/L, < 1 . 00 FB
cnromium, mg/L, <0.050 WELL 111-6
cnromium, mg/L, <0.050 WELL 111-7
cnromium, mg/L, (0.050 WELL 111-8
Chromium, m•;J/L, <0.050 \I/ELL 111-10
cnromium, mg/L, <0.050 \I/ELL w-12
cnromium, mg·/L, <0.050 ·WELL W-13
cnromium, mg/L, <0.050 11/E LL W-15
cnromium. mg/L, <0.050 FB
Magnesium, mg/L, 32.S WELL W-6
Magnesium, mg/L, 39.2 WELL Vi-7
Magnesium, mg/L, 30.9 11/E LL 111-8
Magne's i um, mg/L, 16. 6 11/E LL w-10
Magnesium, mg/L, 20.3 11/E LL w-12
Magnesium, mg/L, 14.6 \I/ELL 111-13
Magnesium, mg/L, 20.6 11/E LL 111-15
Ma,;inesium, mg/L, < 1 . 00 FB
I
I
SAMPLE If
·~;;;~~~-
RN860041
1860042
860043
860044
RN860045 1860046
860047
RN860048
I DIUM
860041
RN860042
1860043
860044
860045
RN860046
.• 860047
.860048
I
I
I
I
I
I I
I I
I
m I
D
I
D
I
KEYSTONE ENVIRONMENTAL RESOURCES
PRODUCED ON 10/24/66 AT 11,05 PAGE 2
RSL T. LNE SOURCE ---------------
Potassium, mg/L, 3. 12 \I/ELL W-6
Potassium, mg/L, 5.06 WELL W-7
Potassium, mg/L, 3.67 WELL W-8
Potassium, mg/L, 5.82 WELL w-10
Potassium, mg/L, 2.34 \1/E LL VJ-12
-.Potassium, mg/L, 1. 03 WELL W-13
Potassium, mg/L, 1. 89 \1/E LL W-15
Potassium, mg/L, < 1. 00 F8
SOOium, mg/L, 71. 7 WELL W-6
sooium. mg/L, 59.3 WELL W-7
sooium, mg/L, 30.4 WELL w-s
soaium, mg/L, 59. 1 \1/E LL w-10
sooium, mg/L, 36.7 \1/E LL w-12
SO0ium, mg/L, 12.6 \1/E LL W-13
sooium, mg/L, 9. 52 WELL' W-15
soaium, mg/L, < 1 . -:o FB
I
I
KEYSTONE ENVIRONMENTAL RESOURCES
PRODUCED ON 10/24/86 AT 11,07
SAMPLE .. RSLT.LNE· SOURCE
ll~;~~~:;;o~~;~;:-;~-;~;-~;;~;~-;;~----------------
~06004, Pentacn I oropneno 1 , 1. 22
RN860042 Pentacn1oropneno1 37.9
icaa60043 Pentacn1oropneno1 5.37
icas60044 Pentacn1oropneno1 717
RN860045 Pentacn1oropneno1 3.86
f9860046
FIIS60047
RN86004S
Pentacn1oropneno1 5.17
Pentacn1oropneno1
Pentacn1oropneno1
3.49
3.44
results are reporteo in ug/L.
I
I
I
I
I
I
I
I
I
I
I
I
\I/ELL 111-6
\I/ELL W-7
WELL W-8
WELL w-10
WELL w-12
WELL W-13
WELL W-15
F8
PAGE 1
=====-... =
I
I
SAMPLE;+ 1;~~~~:--
RN860042
1860043
860044
860045
RN860046
1860047
860048
RN860049
I
I
I
I
I
I
I
I
I
I
I
I
I
RSL T. LNE.
1sopropy1
1sopropy1
1sopropy1
1sopropy1
1sopropy1
1sopropy1
-·1 sopropy 1
1sopropy1
1sopropy1
KEYSTONE ENVIRONMENTAL RESOURCES
PRODUCED ON 10/27/86 AT 12:05 PAGE
========-
SOURCE
Etner,ug/L: (100 \I/ELL 111-6
Etner,ug/L: <100 IIIE LL 111-7
Etner,ug/L: < 100 \I/ELL 111-8
Etner,ug/L: (100 WELL 111-10
Etner,ug/L: <100 IIIE LL 111-12
Etner,ug/L: < 100 IIIE LL 111-13
Etner,ug/L: (100 IIIE LL 111-1s
Etner,ug/L: (100 FB
Etner,ug/L: <100 TB
_.,,,• i
I
I
I '
Ref. 9
Interoffice Correspondence
AUG :' ·r 1980
Mr. T. A. Marr To _________________ _ From __ ~_l_r_._K_._D_. _H_e_p_n_e_r ______ _
Location __ P_i_t_t_s_bu_r_g:cl_1_-_F_P_G _____ _ Location Monroeville -WQE
I Scxliment and Well Water Subjuct _______________ _
, Samples -Raleigh Plant
Datfa: ___ Au_g_u_s_t __ ·2_6_,_-~1_9_8_o ______ _
I '
I
I '
I
I
---I
I
I
I
I
I
(823-1716)
Five (5) samples of sediment and well water, taken in conjunction
with North Carolina State and Federal EPA representatives on July 24, 1980
,,ere received by the Water and Wastewater Analysis Laboratory on July 28,
1980 for pentachlorophenol analyses.
The attached Table l presents laboratory sample numbers, sources
o[ the samples and pentachlorophenol content.of the water and sediments.
Please note the well water results are presented in mg/Liter, while the
sed~uent concentrations are in mg/Kg of dried material.
R. D. Hepner
RJJll:klf
cc: Mr. P. D. Smith
Mr. I}. L. Davies
Mr. I~. J. llaldwin
Mr. P. A. Perr
1-1r. J. 11:!inz.
Mr. R. Dingman
Dr. A. C. Middleton
I
I
I
L ,~ No. 1~
I ),]
I lir, ·-
-
1% ·-
117
-·--.
·-t
I
'
I
I
L>y:
TAllLE l
FOREST PROIXJCrs GROJP
KOPPERS CCNPANY, INC.
RALEIGH, NC
SI\MPJJ-: COT.T.ECTTON DATA
Samole Date
Source
l~c ll , ca·st or steel shop.
~bJl in wel1 south of
nlant
l~i I kcrson constnicti on
wcl I, cast of plant
Sediment -cast <l I scharge
point
Sediment -Med] in poml,
so,.,i-h or plant
North Carolina an<l Federal EPA
Description Collected
0.058 mg/L -7/24/80
<,0.0004 mg/L "
<. 0. 0004 mg/L "
0.674 mg/Kg "
0.114 mg/Kg "
WATER QUALITY ENGINEERING
MONROEVILLE RESEARCH CENTER
Recc ivcd
7/28/80
"
"
"
"
.
I
I
I
:1
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Ref. 10
Interoffice Correspondence
To __ __:_M~r~._T-'-'-.~A~-~Ma~r~r'--------From _ _.!JMLr~, ....lR,._,,_.,D~, _,Hl.J.le;;;pwocsaeLr _____ _
Location
Subject
Pittsburgh Location Monroevi 11 e
Water and Soil Samples Date _ ___.o"'c"'t,._o b.,,e...,r____.2""-9~, _1..,9"'8.,.0'-------
Raleigh, NC
(823-1716)
Water samples from the pond, eight wells, three pits and six soil
samples .from the pond, collected September 11, 1980, by Mr. J. B.
Gillespie, were received September 16, 1980, by the Water & Waste-
water Analysis Laboratory.
Sample Collection Data are presented in Table 1, while Table 2 presents
a Summary of Analytical Data. All data for water samples are in mgiliter,
while results of PCP analyses on the six soil samples from the pond are
in mg/Kg on a dry basis.
RDH:ss
Attachments
cc: Mr. P. D. Smith
Mr. D. L. Davies
Mr. W. J. Baldwin
Mr. R. A. Perr
.Mr. J. Heinz
Dr. A. C. Middleton__//
Mr. J. A. Quagliotti
'"JtSf~~
R. D. Hepner
TABLE l
FOREST PRODUCTS GROUP
KOPPERS COMPANY, INC.
RALEIGH, NC
SAMPLE COLLECTION DATA
Sample Date
Source Description Collected Received
·. "13 Pond 9/l l /80 · 9/16/80 J -14----t-----------i------------t----'---'-----+---'--'----
We 11 #6 9/l l /80 9/16/80
:7 215 Well #9 9/l l /80 9/16/80 -'--------t----------+-----------+-_;___;__ __ ~e-;__.:__ __ _
16 \-/ell #10 9/11/80 9/16/80
:-217 Well #11 9/11/80 9/16/80
. __ 11
1
8
9
Hell #12 9/11/80 9/16/80
We 11 #13 9/11 /80 9/16/80
ir.20 We 11 #14 9/l l /80 9/16/80
.• 21 We 11 #15 9/11 /80 9/16/80
· '22 PIT-A 9/11/80 9/16/80
J"'-2"--3 --+--'-P..:..i .::..t---"G'--------+----------+-..:.9:_/l.:_:l:_/8=-:0:___+..::9/c..:1.::.6/:..:8:.:0 __
'.-224 . Pit-I 9/11/80 9/16/80
25 Pond Soil #1 9/11 /80 9/16/80
:-226 Pond Soil #2 9/11 /80 9/16/80 I 27 Pond Soil #3 9/11/80 9/16/80
:->?A Pond Soil #4 9/11/80 9/16/80 J =29~--i----P~o~n~d ~S=o~i 1~#~5----t---,---------+---'9.:..../l.:..l.:.../.:...80'----+--'9.:.../.:..16:.:./..:.8_0 __
,-30 Pond Soil #6 9/11/80 9/16/80
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lected II
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11
by: J. Gillespie WATER QUALITY ENGINEERING
MONROEVILLE RESEARCH CENTER
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PARAMETER RNC
'Organic Carbon
. -5-day
al Oxvgen Demand
-Oxv«en Demand . i s .
y (as caC03 )
to pH = 4.5 M.O.
;:,H = 8.3 PHT.
nity /as CaC03)
to pH= 8.3 PHT.
p_H = 4. 5 M.O.
• Evapora t'ed
Total -103° C lxed -550° C
. lat ile-5'.>0° C ..
. d s, Suspended
ta l -103• C
xed -550° C
. Volatile-550° C I· Dissolved
. tal -180° C
Fixed " 550° C
Jlatile-550° C
., Settleable, ml/L
4 5 M i11u tcs
,our
Un 1ts · 1 i vi ty. Nmilos/ cm
, it'.:, llnit.<;
rmaldehyde
;
~ .(,\J
213
6.8
46
<l
35
<0.005
'
113
145
<0.5
.00056
TAIH.E 2
FOREST PRODUCTS GROUP
KOPPERS COMPANY T Nr.
RALEIGH, NC
SUMMARY OF ANALYTICAL DATA
()cu . (, {Ji.,J 7 c,{>J I u OaJ•(i
214 215 216 217
7.4 6.9 7.2 7.3
43 34 59 36
6.0 5.0 3.0 <l
35 85 5 l
<0.005 <0.005 <0.005 <0.005
764 285 471 457
800 470 750 780
<0.5 <0.5 <0.5 <0.5
. 012 .00059 6.2 .046
t results in mg/liter unless otherwise noted._
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r,,!,i)· 1?~ C·w :13 (;UJ-f' o,,u,
218 219 220 221
7.4 7.6 7.4 7.3
34 21 27 20
<1 4.0 4.0 <l
70 7 <l <l
<0.005 <0.005 <Q.005 <0.005
328 207 430 268
450 270 600 400 .
<0.5 <0.5 <0.5 0.5
.00059 .00068 .00052 .001
WATER QUALITY ENGINEERING
MONROEVILLE RESEARCH CENTER
TABLE 2
FOREST PRODUCTS GROUP
KOPPERS COMPANY, INC.
RALEIGH, NC
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I SIJMMARY OF ANALYTICAL DATA
i_ '-10 • .,J ~o,<-,:_,._(_ ' .P, ( i! j I f 6 fl,r r . I I I PARAMETER RNC 222 I 223 I 224 225
Ori~an ic carbon
I . I). -5-dav Jal Oxv~en Demand
.• ox·y.,en Demand
,. s
y (as CaC03)
to pH= 4.5 M.O.
oH -8.3 PHT.
nity (as CaCOs)
to pH= 8.3 PHT.
pH -4.5 M.O.
-·s, Evaporated
'T ta l -103° C -,ced -550• c
latile-550° C ..
<.\ , Suspend~d
~tal -103° C
'. 'xed -550° C
Volatile-550° C -
• Dis,i'olved
-al -180° C
F'xecl .i 550° C
stile-550° C
uB, Settleable, ml/L
4 tMinutcs
{our
r, Uni t!:i
~Y-Dm!ws/crn
. Unit~
-,ldehyde 2 <0.5 <0.5 -
-.0018 .0022 .42
I
results in mg/liter unless otherwise JH.>te<l.
1-225 -230 -results in mg/Kg (ppm)
cl.
I I 226
-
.074
r •/ . l ;
227 228 229 230
-

-
--
.031 .072 .11 .076
WATER QUALITY ENGINEERING MONROEVILLE RESEARCH CENTER
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0
W-13
. ' ' ' '
W-14
0
OW-4
W-15
0
0
W-3
OW-9
0
W-1
.-------. : _____ _: 0 W-11
FORMER
L A__fil) iN S
A LJ W-7 AO 0
POND
X. s
W-10
---
0
Q MONITORING
WELL
4 BACKHOE PIT ·
LOCATION OF POND SEDIMENT SAMPLES AND BACK HOE PITS
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l{OPPERS Ref. 11
Interoffice Correspondence
To __ -.:..;M~r~-~R~.'-'-'A~--P~e~r~r ______ _ From __ ..,_M ..... r~·-· ,.,R.,_. _,D,.,,-'-'H,.ep""n"'e....,r _____ _
Location Pittsburgh ·· .. Location ._· .. Monroeyi 11 e ·
Subject -.:.R;:;a:..,:,1-c:ce_,__i :;,;;,9h=-=-"S;.;:o-'-i-'-l ~S"'a'"'m""p"-l=e-"-s ____ _
(823-1716)
Date --'--'M'-"a._y,_·•...,_z .... ,_· . .Ll 9.e.,8"'0,__· -------
Samples of dirt collected at the Raleigh {Morrisville) Plant on
March 19 .and April 3, 1980, have been extracted and analyzed for
their pentachlorophenol contents by a-gas chromatographic technique. .
Results are indicated on the attached letters you sent to me indicating
sources of the soils.
RDH:ss
Attachments
cc:
·-
Mr.-W. J. Baldwin
Mr. D. L. Davies
Mr. T. A. Marr
Mr. P. D. Smith
Dr. G. Ki tazawa
Dr. A. C. Middleton~
Mr. J. Heinz ·
.Mr. R. Dingman
/?. ;J. L % ,, · __ A 1 )* .·
R. D. He~~-/ . . / ·
. . ' . . •' ' . . . .
-• s:v. 2
·. i I
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I Interoffice Correspondence
I To ___ -'R"--'-. _D=.. -"H:..:e:..cp:..:n.:ce::cr=----------From ___ R-'·._A~. _P_e_r..:;r:__ _______ _
I Location_'-'MR=C,__ __________ _ Location_..:.P..:i~t~t~s~b~u=r~g~h=---------
. Date __ ..:M.:.:a::.:r:cc=.:h:.:._2=.1:::..!., --=l..:.9..:8..:0~-----
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Subject ---'R,.,_a=l.::ec:i:..tg,:.h!..-'S::.:a:,:m,,,p=l-'=e'-'-s'-------
I am having the Raleigh, North Carolina plant send
you the-following 11 samples of dirt that were taken
March 19, 1980. /v. .,Per'. '>'~//J $. .
;21'/C 77 J_, __ War_e""h""o"-"'u"'s"'e,__-_,B""'aee.z.-"'~l,__-___,S,c:o"-u,,_,,t~h'-"S'-'i"-'d~e""-'='Su=r.:;f,"a'-"c"-'e=-------•--2:~~~.f-c.!D~o:'..:oo=--
!c> 2. Warehouse -Bay Jt4 -South Side Surface Goo
J-/ ~.3:~·-·varehous e -B.,.,a.._y,_.,,,#.._,7 __ -_,M.,a1.,a.0 d=,,d,=l'-'=e'-"S'-'u"-'r"-f"'a""c"'-"'e ____________ , .... t/.._O
I"'" 4. Warehouse -Bay 4frl -South Side Clay Layer t=
,J-}-5. _Warehouse -Bay #4 -South Side Clay Layer .Jy
J,/_6~Warehouse -Bay #7 -Middle Clay Layer s.:i. ..J
r.t' .J.• Lagoon Sludge \ /.lo, ooo
,n. _8. Dirt near lagoon sludge ) 3, ,J,e>O
r; 9. Sand Fi 1 ter / lfo. ~o-c
Ji 10 .. ·-surface near old pen ta mix tank 7 .1 "; .ooo
,fJ .. il. . Surface near old cellon building ) /. 900 ;,
Please analyze these samples to determine if they are
contaminated with pentachlorophenol and if so please
determine the concentration of the contamination for
each sample-.
'Please handle this expeditiously
very interested in these results
RAP:cg
cc·: T. A. Ma=
P. D. Smith -Raleigh 4
as possible, we are as ~:.:fo~•·
Raymond A. Perr
,, ✓ J/J.-7//0
flVC-79~ f? -
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To R. D. Hepner
Interoffice Correspondence
From _ __:R.:..·=-· ..;A:.:.:... --=.P.;:e:.:r:.:r:__ _______ _
I Location_MR=-='-"C'--------------Location Pittsburgh -K-927
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Subject --'R~a=l-=e-=iccg..:ch=-.:S::..:a:::m:::p=l-=ec::sc._ ____ _ • Date _ __;A;c.pccrc..1.;;;.· l;;;_..:..7.,_,__::1:..:.9..:8:.:0;__ _____ _
In addition to the 11 samples of dirt I had the Raleigh
plant send you in the niiddle of March, · I am having them
send you th_e following 12 samples of dirt that were
taken April 3, 1980:
· ,e,1c. 'l~ 12 Warehouse -Bay jfol South Side t/-3
v·f3 Warehouse B..£l__jt2 Center ~ .SlfO
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it-·_i_4_t7arehouse BEy_jf . ..;_3'-'sc-'o"'u=th=~s~i-d~e------------'----""a_'-:1'-=-0--
i.J 15 WareJl.QJ.!.Se -Bay #_~_c;"'e""n'-'t,.,e"'r=--______________ ___..._,/,_.,/<--=.Dc.;D=-._
1Y )._6Juried Lagoon -Surface :2. 70
1r )._7 Buried Lagoon -l' d~~h /SD 000 9> 1_8 Buried Lagoon -2,-depth:"----------~-~~--..!....:.=~z,::.o,_--
7) 19 Lake Bottom at shore 1.100
7;, _20 New Surface between old penta mix and building .t/~
77 _2_1 New Surface between penta mix and road ij'
/'" 2.,2_<:;enter 1 Road -near Penta Mix JJ/ oo_-o __ _
/C/ 23 Rear Building /S.,O
Please also analyze these samples to determine if they are
contaminated with pentachlorophenol and if so please determine
the concentration of the contamination for each-sample.
RAP:cg
cc:-· T.· A. Marr
P. D. Smith -Raleigh
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\A_: G.S -\ (~ . -.
~~~Q~i
Raymond A. Perr
--'------·.r .
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f!EV. 2
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,,/ Ref. 12
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Interoffice Correspondence
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To Mr. R. A. Pe,.,.r.,_r ________ _ From ____ l1r:....Jl.~ Q _ _jjepne.L_
I Location _P_i_t_t_s_bu_r~g'-h ________ _ Location Monroevi 11 e
I Subject Raleigh Samp'-l_e_s ______ _
-rs-2T-17lliT-
Date __ A_u~g_u_st_2_1~,_l 9_8_0 ______ _
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:. n(v_;,
Ref: Your letter of June 30, 1980 regarding 55 dirt samples.
Soil samples from various areas of the Ralei<jh Plant were received
July 1, 1980, for extraction of pentachlorophenol and analysis of dried
extracts. Analysis·was carried out by a derivatization-gas chromato-
graphic technique. Identification was made from retention data only.
Sources of soil and lake bottoms samples, and penta contents are pre:
sented below:
A. Warehouse Samel~s
Lab Samele No.
RtlC-132
133
134
135
136
137
138
139
B. Cell on Samel es
Lab Samele No.
RNC-140
141
142
143
144
145
146
14 7
1.48
149
150
151
152
. 153
Your Number
l
2
11
18
15
28
32
33
Your Number
100
l 01
102
103
98
99
115
113
11 '1
131.
132·
125,
126 -
124
PCP, mCJ/Kg
4 ,000··
l ,800
2,800
180
310
110
31
780
PCP, mg/Kg_
230
65
110
120
43
1'10
4,700
1,800
l , l 00
14
3. l
3.2
100
270
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Mr. R. A. Perr -2-August 21 , 1980
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C. Lake Bottoms Sameles
I Lab Samele No. Your Number PCP, mg/Kq
I RNC-154 141 12
155 142 6. 1
156 143 11
157 144 20 I D. Lagoon Samples
I Lab Samele No. Your Number PCP, mq/Kg
RNC~l58 38, 13
I 159 39' 13
160 40, 7.4
161 41 ' 0 .81
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162 46 , 17 !, 163 4 7 · 43
164 60 5,500 ' 165 61 220 I 166 62 220,000
167 63 38,000
168 64 24,000
I 169 65 960
170 68 70,000
171 69 6,500
172 70 450
I 173 71 3.4
174 72 1 160
175 73 · 39
I 176 74 9.4
177 75 1.6
178 76 64
I 179 77 7.4
180 80 6,000
181 81 1. 5
I 182 88 V 170
183 89 ' 5.6
184 96 3,400
185 97 150,000 .
I Note: Resu1 ts are in mg/Kg dried soil.
I 7:;~ .·.: ~:J ~~_-..}_,',·/I.
R. D. Hepner
I RDH:ss
cc: Mr. T. A. Marr Mr. H. J. Baldwin ~
Mr. P. D. Smith Mr. J. Heinz p Dr. A. C. Middleton Mr. R. Dingman
Mr. D. L. Davi es
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.RALEIGH SOIL INVESTIGATION
OLD U'GOON AREA
JUNE, 1981
__ , .·
~-lit:!J.: • .Lj
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Collect samples in each bGring
at: 0.5', 1.5', 3', 6'
0 Analyze samples at 0.5' and 1.5'
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~ 0
/'\ ~
~\
0 I -t' ------
1 Pond
~ 0 y
0
◊
◊
◊
' 'Y
0 ~ ')-0 / r ◊
~ 0
v
◊
• v
----
□ Analyze samples at 0.5', 1 .5', 6'
6, Analyze samples at 0.5', 1.5', 3', 6
Outline.of old lagoons
Sea 1 e 1 " • 4 0'
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TABLE 1 I FORMER LAGOON SOIL SAMPLES
(PENTACHLOROPHENOL RESULTS mg/Kg)
RALEIGH, NC
I JUNE, 1981
I Location Surface 0-1.0' 1.5-2.5' 3.0-4.0' 6.0-7.0'
B-1-A 0.021 0.037
I B 0.046 0.064
C 0.43 0.88 0.058
D 0.26 0.021
E 10.0 0.068
I B-2-A 0.048 0.051
B. 390.0 2.8 10.0
I C 730.0 0.22
D 1100. 0 0.080
E 190.0 0.60 0.25
I B-3-A 0. 20· 0.048 0. 065°
B 0.40 1.0 0.25
C 8100.0 7.7 0.43 0.071 I D 0.21 0.076 0.091
E 0.22 0.83
I B-4-A 900.0 1.8 0.21 0.12
B 0.82 0 .15 0.21 0.15
C 1200.0 1300. 0 0.67 8.90 0.10
I D 0.13 0.13 57.0 1.0
E 64.0 0.24 0.27
_B-5-A 0.13 0.12 0.17 I B 830.0 2.5 0.13 0.11 0.15
C 10.0 0.73 3.8 0.13
D 250.0 0.78 0.17 0.11
I E 3200.0 2.3 0.085 0.085
B-6-A 0.38 0.42 0.16 B 850.0 2.7 0.12 0.43
I C 1100. 0 2.7 0.49 1.1 0.14
D 0.38 0.11 4.3 0.11
E 460.0 8.5
I B-7-A 410.0 0.25 0.36 1.1 2.9
B 2400.0 3.3 7.8 1.0
I C 940.0 28.0 3.6 1. 7
D 0.51 0.077 0.37
E 2.5 0.94
I B-8-A 77. 0 0.12 0.038
B 26.0 0.23 1. 3 0.012
C 830.0 26.0 0.16 1. 7 0.011
I D 0.057 0.012 0.02
E 130.0 2.7 5.1
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Location I B-9-A
B
I C
D
E
I B-10-A
B
C I D
E
I B-11-A
B
C
I D
E
B-12-A I B
C
D
I E
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I JBG,ss
10/4/84
D
TABLE 1 (Cont.)
FORMER LAGOON SOIL SAMPLES
(PENTACHLOROPIIENOL RESULTS mg/Kg)
RALEIGH, NC
JUNE, 1981
Surface 0-1.0' 1.5-2.5' 3.0-4.0'
35.0 0.032 0.022
5.1 0.034
0.065 0.10
30.0 0.017
71.0 2.1
750.0 3.3 0.072
2.2 2.4
2700.0 0.48
6.0-7.0'
0.025
0.034
0.060
0 .. 026
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8
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0
0
.43
0
0
0
0 0
390
0 0
8100
0 0
p 0
190
0 .. 0
RALEIGH LAGOON AREA
Penta Concentrations at the _Sur-t:ace -.: ... -.. ,.
900
0
0
I,,...._____
1ioo
' 0
\
\
\___
0 -
0
Results in mg/Kg
JUNE, 1981
410 o.
0
,,--. 830 I
/ 0 0 I 0 I
0
"' -~ \ "'-' 830/ ' "---~ 1100 0 I r---!: o,
I --_ __; I ,
~-/ 0 0 0
3200
130 0 0 0 0
35
0
0
0
0
0
ye,,;.\)
0
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I 0 0 0
I 2.8
I 0 0 0
I 730 7.7
0 0 0
I . 1100
0 0 0
I 10
0 0 , , 0
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RALEIGH LAGOON AREA
Penta Concentrations at a Depth of 0.5 Feet
l.8
0
0
,"'--.
l~O
' 0
\
"' 0 '
64
0
Results in mg/Kg
JUNE, 1981
77 0. () 0 0
,,.--. 2.5 ' 850 /,' 24,000'-'21( 0 0 / ()
/ 0 ', ' / \ 1-Q,___ I
' 2.~ 940 26/ ',o 0 , r ---o 0, ,
/ -_,/
250 I ,
~-/ 0 0 0
2.3 460 2.5 2.7 0 0 0 0
0
5. l
0
0
30
0
71
0
3.3 2.2 0
0
I RALEIGH LAGOON AREA
I Penta Concentrations at a Depth of 1.5 Feet
Results in mg/Kg
I JUNE, 1981
I
I fc,i\\)
I 0 0 0 0 o_ I 0 0 0
10 1 r-----' 2.7 , 3.3 "-._ I 0 0 / 0 0 0
/~
0 , 0 ~ I 0 I )
I '-.. 2.7 I 0 I ' 2.8 0 0 "-~ 0 0 , \ 1/ -----0 0, 0
\ , -__ .J
0 I 0 "'--I 0 0 ? 0 0 ' ,
~-/ 0 0 0 0 I 0 0 8.5 5. 1 2. 1 . ·o 0 0 0 0 I 0 0
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I RALEIGH LAGOON AREA
I Penta Concentrations at a Depth of 3.0 Feet
I
Results in mg/Kg
JUNE, 1981
I
I fc,A\)
I I 0 0 0
I 0 Q_
0 0 -o·
r--' 0 /
7.8"" I 0 .. / 0 0
/ ------.. 0 / 0 ~ I 0
8.rf \
I 0 '-l. l, 3.6 I 0 ' ' "~ 0 0 0 \ r ----.o 0, 3.8 --_ _; 0
I
\ / 0
0 "" I 0 0 0 0 ' ,
57 ~-/ oll.3 0
' 0 0 I 0 0 . ·o 0 0 0
I 0 0 0
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ii
ii
ii
ii
I
II '
I
II
ii
ii
ii
II
II
!I
I ID
0 0
0 0 ..
0 0 0
0 .o 0
0 0 .. 0
RALEIGH LAGOON AREA
Penta Concentrations at a Depth of 6.0 Feet
Results in mg/Kg
/
JUNE, 1981
Y<>"'\)
0 0 2.9
0 0 0 ---"· 1 " 0 0 -
/ -------.._ 0 / 0 ',
0 -. 0 I I ) "---.. , (
' ' ~ci', 1. 7 I 0 0 , \ / 0 ~, 0 -----' \ , ---0 \ I ' 0 ' ' 1.1 '--!?' / 0 0 0 0
0 0 0 0 0 0
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I Steel
Shop
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"' 0 0
IRRIGATION FIELD BEHIND STEEL SHOP
RALEIGH, NC
Scale l" = 40'
Soil Samples Collected at
Surface, 0.5', 1.5-2.5', 3.0-4.0'
JUNE, 1981
IF -1 . .
I • -?
•
I.F .-3
I.F .-4
l.!_.-5
100'
••
I TABLE 2
I SOIL IRRIGATION FIELD
JUNE, 1981
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Pentachloroehenol I Deeth Results
(ft) mg/kg
I Co:i:0 I.F.-1 Surface -~
I 0-1.0 0.033
1.5-2.5 / --) '-..J,1.:,_0 .
I 3.0-4.0 0.053
I I.F.-2 Surface 0.061
0-1.0 0.016
1 5-2.5 (;·~·;\
I 3.0-4.0 0.033
I I.F.-3 Surface :·0.10_':,·
0-1.0 0.025 ·
I 1.5-2.5 0.024
3.0-4.0 0.039
I I.F. -4 Surface 0.056
0-1.0 0.019 n 1.5-2.5 .010
3.0-4.0 0.045
D
I.F.-5 Surface 0 .. 12 • 0-1.0 0.022
1.5-2.5 0.014
I 3.0-4.0 0.021
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To
Location
Subject
STONE
Interoffice Correspondence
M. J. Dvorsky From R. D. Hepner
K-19 Location ;-lonroeville
Raleigh, NC Date March 17, 1987
(1792-77-00)
Raleigh soil samples collected July 15, 1986 have been tested for
per.~achlorophenol as requested. Results are attached.
RDE/nw
Attachments
cc: M. Schlesinger
S. Colton
B. Fisher
R. D. Hepner
Ref. 14
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SAMPLE#
l;;~;~~;--
87010143
~
7010144
7010145
7010146
17010147
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SOURCE
A-8
8-7
C-3
C-6
D-4
E-8
SPECTRIX MONROEVILLE
PRODUCED ON 03/17/87 AT 09,SO PAGE
DESCRIPT DAT-COL DATE-REC
------------------------------------
SOI LS 07/15/86 01/13/87
SOI LS 07/15/86 01/13/87
SOI LS 07/ 15/86 01/13/87
SOI LS 07/15/86 01/13/87
SOI LS 07/15/86 01/13/97
SOI LS 07/15/86 01/13/87
I
I SPECTRIX MONROEVILLE
TABLE 1: SUr-'MARY OF ORGANIC COMPOUNDS PRODUCED ON 03/17/87 AT 09:53 PAGE
l=====~~=~====a==Auca•••=•m==============
SAMPLE# RSLT.LNE 1;;~~;;~:;;o;~;~;~--~;;;-~;~~;~-;~~~;---------------
87010142 Pentacntoropnenol. 16700
87010143 Pentacntoropnenol. 309000
187010144 Pentacntoropnenol. 1670
87010145 Pentacn1oropneno1. 165000
87010146
187010147
Pentacn1oropneno1.
Pentacntoropnenol
4020
136000
Tne aoove resutts are reported in ug/Kg. IA\ I identifications are from retention aata only.
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SOURCE
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RALEIGH, .NORTH CAROLINA I
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FORM.ER LAGOON AREA
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~CAVATED iZ" OF SOIL l---.
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LEGEND:
0. SOIL SURFACE SAMPLES
TAKEN AT EACH
LOCATION (48 SAMPLES)
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OUTLINE OF OLD
LAGOON
R. A. FISHER
8-18-36
. . ------------
FIELD GUIDE TO THE GEOLOGY OF
THE DURHAM TRIASSIC BASIN
By
George L. Bain
and
Bruce W. Harvey
\·---
' ---·, ...... _
,.✓ \ ' -...
Carolina Geological Society
Fortieth Anniversary Meeting
October 7-9, 1977
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Ref. 15
/
with contribut.ions from:
D. Canady
V. V. Cavaroc
E. I. Dittmar
R. C. Hope
Paul Olsen
J.M. Parker, Ill.
F. M. Swain
Dan Textoris
Norm Tilford
Walt Wheeler
-... ~
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FIELD GUIDE TO lllE
GEOLOGY OF lllE
DURHAM TRIASSIC BASIN
NORlll CAROLINA
by
' 1 George L. Bain
and
2 Bruce W. Harvey
With Contributions
D. s. Canady v. V. Cavaroc
E. I. Dittmar
R. C. Hope
P. E. Olsen
J. M. Parker,
F. M. Swain
D. A. Textoris
N. R. Tilford w. H. Wheeler
1u.s. Geological Survey, Raleigh, N.C.
2 Campbell College,··Buies Creek, N.C.
From:
III
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COVER PI-K)TO : !) I STR I BUT ION OF EAST COAST TR I ASS IC PAS I NS
■ EXPOSED TRIASSIC PASINS
ll1 BURIED TRIASSIC BASINS
This publication was prepared in cooperation with the U.S. Geological Survey and
printed through the North Carolina State Government Printing Office by the
Geology and Mineral Resources Section, Department of Natural Resources and Com-
1111.1nity Development.
Layout by:
Additional
Benjamin .J. McKenzie
copies available from:
Department of Natural Resources f, Community Development
Division of Earth Resources
Geology and Mineral Resources Section
P. 0. Box 27687
Raleigh, North Carolina 27611
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GEOLOGY OF THE DURHAM-WADESBORO BASIN
General Relationships
Triassic basins are distributed along the Atlantic Seaboard from Nova
Scotia to the subsurface of Florida (fig. 1). They extend eastward beneath the
Cenozoic cover onto the Continental Shelf where they continue to be discovered by
exploratory drilling and geophysical work. The Durham-Wadesboro basin extends
almost across North Carolina, was filled with continental elastics in Late
Triassic, and is the southernmost exposed of this series formed from Late Triassic
to Early Jurassic in tectonicalty negative areas.
The East Coast Triassic basins are mostly half grabens and/or tilted full
grabens. In North Carolina, the Durham-Wadesboro basin is bounded on the east
and southeast by high angle normal faults traditionally known as the Jonesboro
Fault. The basin trends southwestward from near the North Carolina-Virginia
line to a point a short distance across the North Carolina-South Carolina line.
It is about 226 km long and averages about 16 km in width. The Durham-Wadesboro
basin is traditionally divided into four substructures which from north to south
are: Durham basin, Colon cross-structure, Sanford (or Deep River) basin, and
Wadesboro basin. Most of the present study has concentrated on the Durham sub-
structure. The Durham-Wadesboro basin is surrounded and presumed underlain by
the crystalline Piedmont complex composed of acid igneous intrusives, meta-
volcanics,·metasediments, and high-rank metamorphic rocks. Continental sediments
preserved in the Durham-Wadesboro basin include maroon to grey fanglomerate,
conglomerate, feldspathic sandstone, graywacke, argillite, siltstone, mudstone,
black shale·, and minor amounts of chert and coal.
The Triassic sedimentary mass was intruded by diabase dikes and sills
in Late Triassic and Early Jurassic time. Individual dikes are spaced about one
km apart and range from 0.3 to 20 min width and up to 16 km in length. Dikes
trend north, northwest, northeast, and east, but are predominantly north and
northwest.
4
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FIGURE I.
WINSTON-SALEM •
NORTH
CHARLOTTE ---.
• ELIZABETH CITY
JONESBORO FAULT
DURHAM BASIN .CAROLINA
COLON CROSS-STRUCTURE
. ,
···::: ..... '/-SANFORD BASIN
WADESBORO BASIN
LOCATION MAP OF DURHAM-WADESBORO TRIASSIC BASIN
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The basin is further faulted longitudinally and transversely creating in-
dividual horsts and grabens that are as small as 1 km by 3 km. Most are tilted
to the east and southeast; a few are tilted to the north. Vertical displacement
along the largest known intra-basin fault is at least 300 m and perhaps as much
as 600 m. All known faults are high angle and normal. Diabase dikes crossing
the eastern border are right-laterally offset. More extensive strike slip is
suspected but has not been demonstrated.
Sedimentation and Stratigraphy
The sedimentary pile preserved in the Durham-Wadesboro basin contains rock
types whose lithologic variety, mineralogy,. and inherent depositional structures
reveal much about its tectonic origin and evolution, paleotopography, climate,
and sediment dispersal patterns.
The alluvial fans, the angularity of the sand, the :poor sorting of the fines,
the size of the boulders in the fanglomerates, and the freshness of the
feldspar in the Durham basin all point to short transport distance from an ele-
vated source area to a nearby valley floor or graben of low relief. The deposi-
tional environment was not unlike modern deposition in the intermontane basins of
the Basin and Range·Province or of the Salton Trough of Southern California.
Typically in this environment alluvial fans formed as a direct result of a
sharp break in slope and a corresponding decrease in stream competency. The
decrease in stream competency was further aggravated by' loss of water through the
permeable alluvium by ''.sieving". The resulting high ratio of rock detritus to
water at the fan surface created shallow braided streams that slowly (?) progr.aded
the coarse p:;:-->ximal fan deposits over the finer distal ones. Individual facies
within the fan are quite localized and were caused by intermittant faulting and
attendant increased relief, by meandering bifurcating channels, and by varia-
bility of stream discharge.
Braided streams on the fan surface created longitudinal and transverse bars
which migrated downstream. Sedimentary features of both the upper and lower flow
regime are characteristic -i·.e., parallel laminae, thin lenticular shales, many
6
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LEGEND
() -
SW
L C A A T SOllforO
R E
N M'f---f': I I Cumnock
A D N D ~ Pfl~,n
SANFORD BA SIN
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........... Fossiliferous shale
Dia base dikes
-Diabase sills
~ Tan arkosic
l¼:22l fluv1ol foc1es
w
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z 0 J 0 u
Red mud stone -sandstone -
conglomerate focies, undifferentiated
0000
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Argilli:\e -graywacke-
conglCf~·erate facies
;:,,"
Wester·n border
conglomerate
~ Chert -limestone -
~ mudstone facies
-
Cool -black
shale facies :c?
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DURHAM BASIN
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36 00
KOPPERS CO,, INC.
NC D 003 200383
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FIGURE 2.
NFORD RECONNAISSANCE GEOLOGIC MAP
OF THE
DURHAM TRIASSIC BASIN
NORTH CAROLINA
I 250,000
5 ~ 5 IOMi """"=j~g~•:aa,ioo;====='F~~======:"'==>~ 5 10 15 Km,
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This simple tripartate division based on coal does not hold up even within
the Durham-Wadesboro basin. The ::chert in the Moncure area was not penetrated in
the Sears No. 1 test well at New Hill even though correlation of the basal 350 m
of the Sears w_ell with the basal section of the Groce No. 1 well west of Sanford
shows that the Sears well was within 90 m of being through the Pekin. Although
the lower section of the Sears well correlates with part of the lower section of
the Groce No. 1 well, the Cumnock is very thin or absent in the Sears well. The
upper section of both wells are in entirely different facies.
The position of the fanglomerate at the surface along the down-faulted
side of the Durham and other basins is frequently cited as evidence for continued
pe::-iodic movement along" the downthrown side. Recent resistivity, gravity, and
aeromagnetic evidence show that the basin floor "steps up" near the border fault
making at least some of the surface-exposed fanglomerates early and in a basal
position. In fact, part of the eastern side of the Sanford _basin now mapped as
Sanford Formation is most probably Pekin in age. Thus, the evidence for or
against continued movemen·t through Durham deposition may be t:roded away. The
presence of the basal conglomerate does indicate strong initial relief and may
indicate only the time of maximum local relief between Piedmont and basin floor.
Provenance
The Durham-Wadesboro basin is surrounded by crystalline rock_s of the· North
Carolina Piedmont. The northern part of the basin lies between the Carolina
slate belt to the west and the Raleigh plutonic-gn:iss belt to the east. The
southern half of the basin is entirely within the slate belt. The slate belt
is a low-rank metamorphic complex (greenschist) of silicic land wastes and
felsic to mafic pyroclastics which has an overall andesitic composition
(McCauley, 1961). Individual rock types include: slate (laminated argillite),.
graywacke, tuff breccia, crystal lithic tuffs, flows, and phyllite.
The Raleigh plutonic-gneiss belt has an acid plutonic core surrounded by
gneisses; schists, phyllitcs, graywackes, and quartzitcs ranging up to the
almandine-amphibolite metamorphic facies (Parker, 1968). The Raleigh side of
the basin contains some pegmatite. Both provinces are intruded by many quartz
veins.
13
Few studies have attempted to determine the specific source area or char-
Dittma:
border
acter of the Durham-Wadesboro basin parent material. Whitehead (1962) conclude, be''exp
from,a study of the major rock types exposed at the surface in the Sanford,basir south-
that the grain composition indicated a metamorphosed Precambrian ,sediment sourc, at''pre
now largely eroded away. More specifically, he proposed that the source litho-
logy consisted predominantly of moderate-rank metamorphic rocks accompanied,by
low-rank metamorphic granitic and interbedded,volcanic rock. Klein (1969)
found sedimentation from both sides of the basin based on K-Ar and paleocurrent
measurements.
Liggon (1972), from examination of a 448-m core from near Gulf in the
Sanford basin, concluded that the1 source area was comprised of,rocks of the
quartz-albite-muscovite-greenschist metamorphic facies., ·
Reinemund (1955) fou,nd, that the conglomerate and sandstone at the base of
the section in the Sanford basin contained clasts identical to metamorphic rock
types outcropping in the Slate Belt west of the basin. Crossbedded arkosic
sandstone and schist arenite channel deposits indicat'ed to him that streams flm
ed from the west and northwest into the basin on the west side '(base of section]
and from the southeast in the middle and upper part of the section. He also
noted an increase in coarseness in the Sanford Formation to the southeast, an
increase in arkose toward a Carboniferous .(?) granite pluton to the southeast,
and an abundance of muscovite in the Triassic from rock types'exposed on the
east side of the basin,
Bell, and others (1974) reported that the Wadesboro basin shows no eastwari
coarsening of sediments toward the southeast, although an arkosic conglomerate
clearly deri,ved from a granite along the eastern border occurs near the western
border. Randazzo, Swe, and Wheeler (1970) found that arkose (K feldspar) contcr
increases to the cast in the Wadesboro basin.
It is therefore obvious only that there was coarse sediment contribution
from both sides of the Durham-Wadesboro basin. The available paleocurrent data
14
Patter
'CTOSS-
pointi1
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Dittmar indicate that streams depositing the alluvial fans along the southeast
border flowed into the basin more or less at right angles to tli.e border as might
be expected. Dittmar's work in the coarse tan arkosic facies shows a strong
south-southwest direction. His data from the other facies are not sufficient
at present to draw a tentative conclusion about their paleocurrent directions.
Patterson's work also indicated a strong southwest direction across the Colon
cross-structure. As stated above, Reinemund found a few indicators at the base
pointing toward the southeast.
15
INFORMATION CIRCULAR 23
DIABASE DIKES OF THE EASTERN
PIEDMONT OF NORTH CAROLINA
E. R. Burt, P.A. Carpenter, 111,
R. D. McDaniel, and W. F. Wilson
NORTH CAROLINA
DEPARTMENT OF NATURAL RESOURCES AND COMMUNITY DEVELOPMENT
DIVISION OF LAND RESOURCES
GEOLOGICAL SURVEY SECTION
Raleigh
1978
Preface
The map that accompanies ttiis report was prepared as expeditiously as
possible in order to make the information available to the geological
community and general public in immediate need of basic data with research,
economic, and energy applications. The diabase occurrences are accurately
located; however, the map should be considered preliminary with respect to
cartographic standards.
Errata
Diabase sills on the geologic map are represented by irregular-shaped red
areas.
I
'
ABSTRACT
Recent reconnaissance geologic mapping and aeromagnetic data show
that long, continuous diabase (dolerite) dikes occur throughout the eastern
Piedmont of North Carolina. Two major dike trends are evident: one set
trending N. 1 o0 -3o0 w. and another set trending north. A third, less promi-
nent group trends generally east-northeastward. The new knowledge of loca-
tions and patterns of diabase dikes presented on the map accompanying
this reports supports observations by earlier workers that diabase dikes in
the Appalachian regi~n cut across all other structures. and thus reflect deep-
seated stresses.
In North Carolina, the north-trending set·of dikes has been over-
looked by earlier workers because of a lack of detailed regional map-
ping. These north-trending dikes may be of a different age and chem-
ical composition than the northwest-trending dikes and could have
intruded along fractures resulting from a separate stress system.
Some diabase dikes exhibit a strong mag_netic expression, while
others are only faintly expressed, and still others have no magnetic
expression. These varied magnetic responses may be attributed to: l)
differences in the chemical composition of the parental diabase
magmas, 2) differences in the mineralogical compositions of the coun-
try rock lithologies into which the diabases intruded, Or. 3) a combina-
tion of l and 2.
INTRODUCTION
In recent years, a number of workers have systematically studied
the diabase (dolerite)dikes of eastern North America and speculated in one
way or another on their regional significance. King (1961, 1971) pointed
out the wide-spread occurrence of Mesozoic dikes in the Appalachian region
and drew attention to their systematic pattern. De Boer (1967) carried out
a paleo-magnetic-tectonic study of the Mesozoic dike swarms. Weigand and
Ragland (1970) examined the geochemistry of the dikes, and May (1971)
related the dike patterns to the prcdrift positions of the continents and to a
stress field imposed on the crust at the onset of North Atlantic sea-floor
spreading.
Regional reconnaissance geologic mapping has recently been conducted
by staff members of the North Carolina Geological Survey Section of the
Department of Natural Resources and Community Development. This
mapping shows that long, continuous diabase dikes occur throughout the
eastern Piedmont section of the state. Occurrences of diabase have been
widely recognized and studied in association with sedimentary rocks of the
Durham, Dan River, and Davie County Triassic basins in· North Carolina.
Diabase dikes also occur in crystalline rocks throughout the Piedmont. How-
ever, it was not until the recent reconnaissance mapping that the large
number of dikes, their length, and distribution pattern was known. ·
Most of the dikes on Plate l were originally located and traced in
the field from exposures in roadcuts, scattered residual boulders, char-
· acteristic soil colors, deflections in stream valleys, and by the presence
of resistant ridges: Aeromagnetic dat~ became available later during
the mapping project. The aeromagnetic maps in numerous instances
made it possible to proiect dikes where field evidence was lacking, to
connect scattered exposures along roads into .long, continuous dikes,
and to confirm the locations of dikes previously mapped.
ACKNOWLEDGEMENTS
Numerous individuals assisted in the preparation of this report.
J. M: Parker, Ill, and S. G. Conrad reviewed the manuscript and made
helpful suggestions. The locations of additional dikes in the Durham
Triassic 'basin were obtained from field maps provided by G. L. Bain.
L. c: Bain edited the manuscript, and B. J. McKenzie provided the draft-
ing and technical assistance. Appreciation is expr~ssed to these indi-
viduals for their efforts.
GENERAL DESCRIPTION
Diabase, a dark-gray to greenish-black, fine-to medium-grained
rock, occurs as both dikes and sills in North Carolina. Narrow, steeply
dipping dikes occur in pre-Triassic crystalline rocks as well as in sedi-
mentary rocks of the Triassic basins. Sills are restricted to Triassic
sediments. The diabase weathers to brown to yellowish-brown, plaStic
clay soils. Spheroidal boulders, which often have a characteristic rusty
to yellow-brown weathering rind, occur commonly in the saprolite and
are found scattered o,:i the surface of the ground.
Most of the diabase dikes and sills consist of similar mineral as-
semblages but in varying proportions. They have been reported by
previous researchers as being composed of 40-65 percent plagioclase
(Anr;o-An 70), 15-45 percent augite, 0-59 percent olivine, 0-25 percent
qutrtz and potassium feldspar (in the form of micropegmatite), and
accessory magnetite-ilmenite, apatite, pyrite, titanite, tremolite-actino-
lite, biotite, and hornblende. Orthopyroxene and pigeonite are present
2.
in some diabases. Secondary alteration is evidenced by biotite, seric1te,
chlorite, serpentine, iddingsite, magnetite, uralite, antigorite, and leucoxene
in amounts up to 6 percent.
Textures are commonly ophitic to subophitic. Justus (1966) recog-
ni_zed a progressive variation of texture across dikes of the Deep River basin.
Regardless of composition or thickness, textural variation from contact to
center was: porphyritic, intergranular and/or intcrsertal, isogranular, and
subophitic. According to Justus, only dikes 8 meters or more wide exhibit
ophitic textures.
Various chemical classifications have been proposed for diabase.
Most diabase can be grouped according to the classification proposed
by Weigand and Ragland (1970) for dikes -of eastern North America.
They established two main varieties: a quartz-normative variety and
an olivine-normative variety. The quartz-normative dikes can be further
subdivided on the basis of Ti0:i and Fe~0:1 content into low-Ti0:.!, high-
Ti02, and high-Ti0,-high-Fe20:, types. _Modal and chemical variations
occUr across some dikes but are not consistent. Variations are generally more
noticablc in the wider dikes.
No correlation between chemistry, tectonic setting, country-rock
lithology, or gravity or magnetic anomalies has been established
(Weigand and Raqland, 1970). In North Carolina and Viroinia, Weioand
and Ragland found that olivine-normative and high-TiOThigh-Fc2o3 and
high Ti02 quartz-~ormative dikes occur with olivine-normative diKes being
predominant.'
Most dikes contain a chilled border and, depending upon the type
of rock intruded, may or may not be bordered by a baked zone or
contact aureole. In general, argillaceous sedimentary rocks exhibit a
higher susceptibility to contact metamorphism adjacent to the dikes
than do the predorTlinantly sandy sediments.
DISTRIBUTION OF DIKES
Plate 1 shows the distribution of diabase dikes in the eastern
Piedmont of North Carolina. The dikes plotted include those mapped
during previous geologic studies in the Piedmont, as well as those
mapped during the current regional mapping. Trends of the dikes as
indicated by aeromagnetic anomalies are also included.
Two major dike trends are evident: 1) dikes trending N. 10°-30°
W. and 2) dikes trending north or a few degrees east or west of north.
3
A third, less prominent group of dikes trends generally east-northeastward.
Northwest-trending dikas most commonly are in sedimentary rocks of the
Durham, Deep River, and Wadesboro Triassic basins. They also occur in an
area north of the Wadesboro basin in Stanley, Rowan, and Davidson
Counties; in the Johnston, Chatham, Wake County area; and in Nash County
(see figure 1 for county outline map and generalized plotting of dikes).
The major concentration of north-trending dikes is in the western one-third
of the study .area in a zone extending from the South Carolina state line to
the Virginia state line. Dikes in this group are more closely spaced in the
south, where they arc sharply discordant to the northwest-trending dikes, and
fan out as they trend northwclrd deviating both east and west of north. East-
northeast-trcnding dikes are much less common than those of the other sets.
Many of the east-northeast-trending dikes are located within the Triassic
basins or along their borders, although some are scattered throughout the
study area.
The north-tren_ding dikes are, in general, much longer than the
northwest-trending or east-northeast-trending dikes. Several north-
trending dikes were traced by a combination of field evidence and
magnetic anomalies for more than 60 kilometers. The longest of these
extends with only one short interruption from east of Hamlet in
Richmond County to east of Williamsburg in Rockingham County and
on into Virginia. The length of this dike in North Carolina alone is
over 160 kilometers. The majority of northwest-trending and east-
northeast-trending .dikes are between l and 25 kilometers long, and
none are greater than 50 kilometers long. The longer dikes are irregular-
ly sinuous rather than continuously straight. A few branch along strike
and·seem to follow separate fault or fracture zones.
Many dikes iri the Triassic basins terminate at the basin border
or within a short distance after intrusion into the crystalline rocks, but a
significant number of dikes extend far across boundaries between
major geologic provinces. Dikes that cross major boundaries do so with
no apparent change in trend. Several dikes extend across the slate belt-
Charlotte belt boundary; however, in Davidson and Guilford Counties,
dikes are conspicuously absent in rocks sbuth of this contact. Some
dikes in the eastern slate belt extend northwestward into rocks of
the Raleigh belt.
Even taking into account the different levels of detail of mapping,
diabase dikes are not evenly distributed throughout the study area.
Heavy concentrations are present in some areas such a,s the central
portion of the Wadesboro Triassic basin and the Deep River Triassic
basin; Whereas, other areas such as central Chatham County are nearly
devoid of dikes.
4
Figure 1. County outline map showing area of investigation.
MAGNETIC SIGNATURES OF DIABASE INTRUSIVE ROCKS
The magnetic signatures or anomalies of many diabase intrusive
rocks on aeromagnetic maps are variable and in many instances
deceptive. Some diabases exhibit a stron·g positive magnetic expression,
while some are only faintly expressed, and others have no magnetic
effect. In general, the north-trerlding dike set has greater magnetic
expression than the other sets. The differences in magnetic effect of
the dikes may be the result of differences in the amount of magnetite
crystallized from the parental magmas; they may be the result of contact
metamorphic effects on country rocks of different compositions adjacent
to the diabase intrusives; or they may result from differences in
magnetic ·intensity of the country rock.
Weigand and Ragland (1970) concluded that there can be no simple
correlation between chemistry, tectonic setting, country·rock lithology,
or gravity or magnetic anomalies among the diabases of N·orth Carolina.
Parker (in press) states that sharp linear magnetic ridges, some of
which are 600 meters wide and have a relief of 40 to lOO gammas on
the aeromagnetic map of the Raleigh, N. C. l O X 2° quadrangle, result
from diabase dikes. He further states that "the dikes are not nearly as
wide as the magnetic ridges since half the anomaly is on either side of
the dike boundary surface". Parker also points out that many dikes of
widths no more than 15 to 25 meters produce prominent magnetic
effects, while a 60-meter thick diabase near Garner, N. C., shows only
discontinuous magnetic highs. Where .diabase ~ik'es extend into the
crystalline rocks of the Piedmont, especially those of felsic composition,
a relief of l 00 to 300 gammas _may occur on the· aeromagnetic map.
However, where the dikes intrude intermediate to mafic intrusive rocks
such as diorite and gabbro, their magnetic signature; in most instances,
is masked by tne strong magnetic expression of the mafic· plutons.
Baked or contact metamorphic zones have·, been described by
numerous authors. Allen and Wil~on (1968) descripe the occurrence
of these zones in the Triassic sedimeritary rocks· adjacent to the diabase
dikes in Orange County, N. C. Ragland, et. al (l 968) describe the
occurrence of dark or purplish hornfels o~curring as contact metamor-
phic aureoles in all argillaceous-ty·pe rocks adjacent to the diabase
dikes. These hornfels may extend 12 ~or ·more meters away from the
dikes and the progressive blackening at' the clayey rocks toward the
dike may be caused by redu~tion of hematite to magnetite upon
heating or by possible metasor11atic introduction of magnetite. Contact
metamorphic hornfels were not observed where the dikes intruded
sandstones. Reinemund (1955) also observed that the diabase intru•
sives produce contact metamorphic effects in Triassic sedimentary
5
:·
rocks which extend less than 9 meters from the intrusives. Contact
metamorphism of the surrounding argillaceous sediments has produced
magnetite through the processes of dehydration and reduction. Baked
zones adiacent to d.ikes appear to occur only in Triassic s·edimentary
rocks and do not extend into the crystalline rocks of the Piedmont.
OBSERVATIONS
The map accompanying this paper significantly expands the
knowledge of locations and patterns of diabase dikes that occur in the
North Carolina Piedmont. Two maier dike trends and one minor trend
are evident. One major set of shorter dikes strikes to the northwest,
while a second maier set of· much longer• dikes strikes north. The
minor trend consists of a few scattered dikes with various strikes
grouped around an east-northeast direction.
All the major geologic belts in North Carolina ,from the eastern
slate belt we"stward to the Blue Ridge belt trend northeast, as do
many of the m'aior faults and much Of the regional foliation. ·However,
only a few scattered diabase dikes parallel this regional trend-some
o'f which parallel the western· border of. the Triassic. basins or are
located within the basins themselves. The northwest-trending dikes
strike almost perpendicular to the regional trend of lithologies, while
the north-trending dikes are obliquely discordant to both the regional
trend of lithologies and the other-dike sets. The north-trending dikes
crosscut both the crystalline rocks of the Piedmont and the sedimentary
rocks of the Triassic basins. These facts add further support ·to ob-
servations by earlier workers (King, 1961, 1971; de Boer, 1967; and
May, 1971) that diabase dikes in the Appalachian region cut cleanly
across all other structures and thus reflect deep-seated stresses. The
irregularly sinuous trace of the dikes suggest that the fractures they in-
truded are the result of tensile stress, not shear stress.
Weigand and Ragland (1970) found diabase dikes in North
Carolina to be predominantly olivine-normative in composition. How-
ever, they collected few samples from the north-trending dike set,
probably because of the lack of detailed regional maps existing at
that time. The lack of comprehensive sampling in previous geo-
chemical studies coupled with the sharply discordant relationship
of the two major dike sets in the southern part of the study area and
the generally higher magnetic response of the north-trending dike set
leaves open the possibility that two major episodes of diabase intrusive
activity occurred. The major dike sets may be of slightly different ages
and different chemical compositions.
6
The varied magnetic responses of diabase · intrusives may , be
attributed to the following variables,
1. The chemical composition of the parental diabase magmas
2. The· mineralogical compositions of the country rock \ithologies
into which the diabases intrude, or
3. A combination of 1 and 2.
The dike sets affect local surface drainage patterns and modify
groundwater movement in their immediate vicinity. Because some
dikes occupy stream valleys, they may nearly everywhere be covered
by stream alluvium. For this reason, several extensive dikes mapped
on Plate l had been overlooked by earlier workers. No doubt we
have overlooked some for the same reason.
Throughout this study, we ha~e refer.red to two major dike sets
readily apparent from the map, but we have made no attempt to make
a detailed interpretation of the structural significance of this pattern.
Are the two major sets of tensile fractures along which the dikes
intruded the result .of the same stress system? What significarice, if any,
can be attributed to the fact that the major concentration of th_e long,
north-trending dikes is restricted to a relatively narrow zone in the
western one-third of the study area? A systematic study of dike dips
might result in additional dike sets being. recogni_zed which would
influence the structural interpretation of the dike pattern. More. de-
tailed· studies of dike pattern and chemical composition may help
resolve these questions.·
7
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North Carolina (M.S. thesis), Raleigh, North Carolina State
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__ l 977, Aeromagnetic map of south-central North Carolina: U. S.
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8
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__ 1964, Structural control of the intrusions in the Durham basin,
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9
1:
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district, North Carolina and Virginia, U. S. Geol. Survey Bull.
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__ (in press), Geology and mineral resources of Wake County, North
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66 p.
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at Chapel Hill, 25 p.
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10
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of the bedrock, showinQ radioactivity, and aeromagnetic map of
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64 p.
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Carolina, Southeastern Geology, v. 11, n. 3, p. 187-198.
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rangle, Pittsylvania County, Virginia, and Caswell County, North
Carolina, U. S. Geol. Survey Geophys_. Inv. Map GP-745.
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and Pittsylvania Counties, Virginia, and Caswell and Person
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GP-746.
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__ 1971, Aeromagnetic map of the Winstead quadrangle, Person
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Inv. Map GP-748.
__ 1971, Aeromagnetic map of the Roxboro quadrangle, Person
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phys. Inv. Map GP-749.
__ 1973, Aeromagnetic map of the Oxford quadrangle and part
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__ 1973, Aeromagnetic map of the Henderson quadrangle and parts
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II
Carolina, U. S. Geol. Survey Geophys. Inv. Map GP-884.
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76 p.
12
GEOLOGICAL SURVEY SECTION
The Geological Survey Section shall, by law" ... make such exami-
nation, survey, and mapping of the geology, mineralogy, and topo-
graphy of the state, including their industrial and economic utilization
as it may consider necessary."
In carrying out its duties under this law, the section promo.tes the
wise conservation and use of mineral resources by industry, commerce,
agriculture, and other governmental agencies for the general welfare of
the citizens of North Carolina.
The Section conducts a number of baSic and applied research
projects in environmental resource planning, mineral resource explora-
tion, mineral statistics, and systematic geologic m.ipping. Services
constitute a major portion of the Sections's activities and include identi-
fying rock and mineral samples submitted by the citizens of the state
and providing consulting services and specially prepared reports to
either agencies that require geological info_rination.
The Geological Survey Section publishes results of research in a
series ·of Bulletiris, Economic Papers, Information Circulars, Educa-
tional Series, Geologic Maps, and Special Publications. For a complete
list of publications or more information about the Section please write:
Geological Survey Section, P. 0. Box 27687, Raleigh, North Carolina
27611.
Eldon P. Allen, Chief Geologist
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",f r \?' _/,. , \ , l = ,,,;,-¼, ..... , 1"., 'y INFORMATION CIRCULAR 23 "'-....!..--h"\ F,.,... ~-·-· ~ \ ·._1 \: . . iti., ._-,-. A -, . ., , ) ~-·:-.,~ ,;-,::, .,V'--~ .. ;. ,, '\-0),t ·. ··,t . ·\"7· :,s,~ l\, ; ·\,,_~, •" .•·. '...-.:,,---( ~,._ •:;;..,:.::,;, · · ( · ·· I,-k··""" , .. 1~ ·,1 i / · ""-1-..-".,,:-,-.._,-;,!---I ~ ' ..... · _.,..," ' · _,., ~ -• ; ,-.', -.'? .. ;, i _..:.. \. N'c.. \ _ ~-'.~ ;-'c j,1' \{ =.,_;,/ _ r' , ' ),. f / ' 't •• ~ \!J. :1 ; ,y ~· .. . DIABASE DIKES OF THE EASTERN PIEDMONT OF NORTH CAROLINA --.. " .:,r-· I ' .1-' '-" ' -c-11,.., ~ 'I ~ lj1, -~..J,,'"i . \ 1 ';:.' \r : ' " '"-~I.. .,2'. I ;-._,_ • I -I /' -:: .... ;.:::' 1 -t"""• __ .... ' Yl -, ., y ~--er, \u ··. - -,.1 \ \ I \ , ·~---i. ·'1'. ~ ;""-~"'· J -..... . , . , ... ~-..,.~ '1 ; ,, ", ·1 ·;: Y !'\ ~ -r ,;1, ---, , . ,: • \-', ,, \1 , ···· :;::r · . ~ ... "' _,,, · : ~ -· ,," .::.•.~ .-~: ,-,, ., ' , -' .,,~-· / i Y-\..1-~ .... A , " i¼: J.,.' •~\ / -; i. ... r .. , ·1 ._ ( •.-• ' '2\"':~ . . I ' /-~sit"· ,, _.)_, ' , ,-i< ; ,-">( ~ / I\ '• \ ~~~;,,-.,_ J "'-• • • '-.. .J!/,("' c ~-, \""/'' iQ' }' \ ~-} "', ~ 1,, "-1 1'. _ I •-\· \ ~/11· ; _,, ~ ',--. "/-\~~, ry, "~r>t<" '' -I\ \, . '' • / )\ f! · · • _';/, \ '--/,£;,'c) ; ' ·; ') \,,,_;_,; ,,' ('-r--. ;,--, -. • f ::::~~--J ·. \ ; ~~~.., . ,~' •.,;.' ' . .',' '_.,___, /",-• \ ,~ I 1 _-:' \f 'Y'J I i 0· ·j.-·~ ~ ( ri• Z< -;": . . '"\ ! ~ ·c "' ~'C . . : . ' · .. ' l ./ I J . I '-TT . ,,,,,__ '< . .,;.-'..._ '', 1,;l'.Jit°"r;(. . _,_ ✓ -. I _,. .. , ., -. l /"'",Y:.--4 . :,:...<./ I ..,........-, ·t 1'·-,, \·?'_ /\ J ~" ~ ·. ',-/ ,.,.-".;,~.!. ~,-~,,.o-':l'k/---';'!:""'•y' -i,v' f'.s.,-+.,,·1 , : · ~i 'i . .··.. "'----"' " .\\ ··t--;;~t; .~ ~' _.,; ·,'1 t. , ) 1, l_ ~ • ,, \i '\,IC,-;<' / I . • . .• </ "") _ -..,,.-i . "It",, ' ( ' ' . > ;;,;;,,~,.,, . . ' ,.,,!Jr" ' '\ f ' . ·. ·-'-.l../.,, ---f?\-...Jf'-f/\·,'' . r;.\ . . ·:,;"/Ir'~-<< ¼,.' . : <2 / ,;, .if · . t • .A~>-.""\·,· l-1" \ ... ,, I~', / J ' \. . i. :.,':. \ '""-<.. /-,, . • lh ., l /'.v r') ttl'l.i-v~ "'. ': \ , C • • _, : " i,/;~,,.._1, e-f'~Ol', . ' '\ . ·' \ ~,, . . . . '. ,_,.,,. ',,"';'\<.,""-f1i . , ': J<f':'frJtiJ' n0 J:5J~ , ~\ 'fl:-.'/ f.;,(<k~·"JiV l'J/1 '!W,J ~ {i ', Y;i.\,.~:i .. \j ~f✓-~"·-.. )l'-1-_,~ ,~, "'If, ::---,..~~, .\ "i'xtJ'<~ \;' ¥' "'\i',V:"'\'{r" \'\'J:' 11 \',-...,;f"I') 1 ... ~-------,-_,, -;r<~ '·." .I ,,\' 1 ·-'<\ 1. , ... •' 'l)I 1 '. I l i ,, •\ "it l .-•-"""" ~\./ ... . "?i.A :'c,"l'c.,;i:,,i / ·. "I/-, 1 ')-.~ I" · l 1 " -;~'f;i~J~tj~f 1 'j ," . 1:\', 1 ; >-1 , /~ \1 '\ __ \ '""' --'-r1 ,.-~ .t;::;.·t~·--<:r'(""" .,.,,,.,.>(_ ~ ""\J)\ _,_,__ -I\ ) ! ,!i;. ' '-..)'-"~t.,. ;--" rr,?i!'' )·.· '}_,./ /' "<,r ~ -~ -:-i!-'--I 1--~j~:td, 1 c\ [;\:;i-;if/iil r -_. ' •· Y • '·; ,-0¾, --r : -·~ i ·. 1 1 :;}!~~~4,,,~~~,f~t";~"'::J'5' ~-~""" . .--, '',,_,l~-)· .... -: , ··. :>; . : ~·. ··1~t:J.:t.~ ~~~~~~a,.>~Ll~ ~-1 ""_,__-:<~'"~/:' \ / ~-~,./'·"!':,........ _ .-'-· ,--., :_,,--' t -. ~~y?.!,'--ll · j ,;-~ , . ) -.. t I. . . ' ., • ·· .... \ ... , . ·. ··1 ' .. ·,' : '1-<..XI' ~~r,2'' ·=. I • i I , . · • • • • , • . · Goasra · · · ,\ ·> ~~ "" " ' ·-· . .... .. I(;/-. ~/'~y··· I I : •.• ,i.• . •-~· ,:' \ .~:; /(; ' 0··' .. : •. ·~· .. ·.•. ~~.;'\~•....:("~\ "f" " .. \ 'L. TK'\_i~,/ )!{;r,1 : , (I /'• !L.' . ·/ '"'.:\)'.'\ ; , < I , '"'(' 1 ·.,."_":l)",..'•· A _, 1\, ,-" -·-JJ\,\-.~Mb \_ -~lfr:_ ,,, __ \ -~, \;~•/;]"" ij ,,,: i"!!:t;:,\ ....... L\ .'5.LL .. _/, ,. "---.hi::' ., "'ff Cartography by l;J. J. McKenzie Index map of North Carolina area of investigation. Eastern Slate by E. R. Burt, P.A. Carpenter, 111, R. D. McDaniel, and W. F. Wilson Sauratown Mtns ......... ,.., ........ ; > ( ', '\!, Belt ~:::-('""l, Al'!idinQIIVIV. ••••••• )f ... I ff\ ..... w~ / ")-f ~'s~:,j\ / ' ~ ! 71; ~ ½Pok" / , i.,,:;., ',•~ ' '7. }7" r,. ~\ shawi ng ·-.., ,; ( /: I N l ~---I L1 L✓ \ ~ .... ,, 'c' ' I ' ·-,,,,-' =,. •' \ I '('--.,..__~.:;\c.p/Jt"!--,/ -'.J ~ \__,..;:-"~ , \"/ I ,,:,vt.J, / ;; )f ....... v, /,/,. . ' .,._.___, 7 \%,,~ ,;;-,..0~/ ~ "(y ; I ~ * "'Yt!/v. I l'J· "" --41,✓, I c" ~, -ef.---;:::r, -~J ····-········· .... ···Y.r .••······ Seel" 4 0 4 8miift Ej-:PLANATION / GENERALIZED GEOLOGIC CONTACTS DlARASE DIKES DASHED ~1HERE INFERRED FROM AEROMAQ,NETIC DAT A OR STREAM PATTERN} / SOLID WHERE SUBSTANTIATED BY OUTCROP~ ■ ISOLATEQ BOULDERS WITH NO TR[ND INDICATED Hase Frum 1916 N. l'.. Deputm1•mt of Transportation C.ounly Highway Maps I ~ l2sil 10 151 ' c125_ ·12 : 1 "-1-----·t-1) 3 i i I ,: f---·--r--,3" I [~l1 ,5 ! l . ~ , I I 71 -........___ ____ ~------------✓~ ~ \ ' ,, ' 16 -~------' 2 Index to Data Sources 1. Espenshade, et. al., 1975 2. Thayer, 1970 3. C1.rpcntcr and McDaniel, unpublished 4. Stromquist and Sundelius, 1975 5. Stromquist, ct. al., l9Tl 6. Seiders, unpublished 7. Conley, 1962 8. Burt, unpublished 9. Wilson, 1975 10. Hadley, 1974 11. Carrilho, 1973 12. Singletary, 1972 n. Wilson and Carpenter, 1975 14. Carpenter, 1970 1.5. Parker, 1963 16. Wilson, unpublished 17. Reinemund, 1955 18. Upchurch, 1968 19. Burl, 1967 20. ConleY, 1962 21. \\!askom and Butler, 197'1 22, R,md.t.:.i:o, 1965 23. Swe, 1963 24. Bain and Harvey, 1977 25. Field Data Una"ailable 26. Parker, 1978 (In Press) NORTH CAROLINA DEPARTMENT OF NATURAL RESOURCES AND COMMUNITY DEVELOPMENT DIVISION OF LAND RESOURCES GEOLOGICAL SURVEY SECTION 45&t .'1] ~>',: ;8~ ~. i~Y r~ f:. Iii .,..,-,·Ne ,4,,·, , " -· . ",ill .. --i-, ? '" \\_\_ , '-," /_/1 <V. // '-':'::-?1ff:.~-~:-1:,; RALEIGH '1978 .J '" I " -' 1.: /:: t·,,-: .· ::G ( '1,:. I• •