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HomeMy WebLinkAboutNCD095458527_20001110_FCX Inc. (Statesville)_FRBCERCLA SPD_June 2000 Sampling for Monitored Natural Attenuation OU-3-OCRI I I I I I I I I I I I I I I I I I I June 2000 Sampling for Monitored Natural Attenuation at FCX-Statesville Superfund Site OU3 Statesville, North Carolina prepared for EI Paso Energy Corporation 1001 Louisiana Street Houston, Texas 77002 November 2000 27-60313.015 I I I i I I I I I I I I I I I I I i I Environmental Engineering & Consulting 227 French Landing Drive Suite 500 Nashville, TN 37228-1605 Tel: (615) 255-2288 Fax: (615) 256-8332 November 10, 2000 Mr. Roger Towe El Paso Energy Corporation 1001 Louisiana Street Houston, TX 77002 27-60313.015 RE: Results of June 2000 Sampling for Monitored Natural Attenuation at Operable Unit Three (OU3) of the FCX-Statesville Superfund Site Dear Roger: The Record of Decision (ROD) for Operable Unit Three (OU3) at the FCX- Statesville Superfund Site (the Site) includes monitored natural attenuation (MNA) as part of the remedy in addition to active source control. Currently, the MNA includes semiannual groundwater sampling of selected wells for specific parameters as described in the Pre-Final Remedial Design Report ["Pre-Final Remedial Design Report for Operable Unit Three (OU3), FCX-Statesville Superfund Site, Statesville, North Carolina" dated September 1999 by Brown and Caldwell]. The primary constituent of concern in OU3 is tetrachloroethene, also referred to as perchloroethene (PCE). 1bis letter report presents the results of the fourth comprehensive round of MNA sampling that took place in June 2000. The first MNA sampling event took place in December 1998 and included some limited sampling in January 1999. These results were reported in the pre-design investigation (PDI) report ("Pre-Design Investigation Report for Operable Unit Three (OU3), FCX-Statesville Superfund Site, Statesville, North Carolina" dated March 1999 by Brown and Caldwell). The results of the second comprehensive round of sampling, which occurred in June 1999, were presented and discussed in a letter report dated December 2, 1999; the results of the third comprehensive round of sampling, which occurred in December 1999, were presented and discussed in a letter report dated June 14, 2000. Following is a brief description of the June 2000 sampling, a compilation of the sampling results, an evaluation of the plume stability, the scoring results for natural attenuation, and conclusions. DESCRIPTION OF SAMPLING Sampling of monitoring wells for groundwater quality, including analysis for volatile organic compounds (VOCs) and metals designated by the United States Environmental Agency (USEP A) and analysis for MNA parameters, was conducted during the period June 5 through June 9, 2000. The wells sampled are listed in Table 1. One well listed in the work plan was not sampled during the June 2000 \\BCNSH03\pROJECTS\PROJ\6031J.015\ljunc-OO.doc I I I I I I I I :1 I I I I I :1 I I I I Mr. Roger Towe November 10, 2000 Page 2 sampling event because of inaccessibility and one well was not sampled because of the low water table level that occurred during that period. Two other wells were purged with a bailer (rather that the prescribed slow-purge technique with a pump) because of the low water table level. These two wells were analyzed for a limited number of parameters due to the limited volume of groundwater recovered. These wells are indicated by footnotes in Table 1. The monitoring wells associated with OU3 are shown in Figure 1. Figures 2 and 3 show the shallow and intermediate isoconcentration contours, respectively, for PCE based on the June 2000 sampling data. The protocols for sampling are the same as previously used including slow-purge techniques. Details of the sampling method are described in the document entitled "Remedial Design Work Plan for Operable Unit Three (OU3), FCX-Statesville Superfund Site, Statesville, North Carolina" dated July 1998 by ECKENFELDER INC. (now Brown and Caldwell). A summary of the chemical analyses and analytical method references are listed in Table 2. As discussed in the PDI report, the primary constituents of concern in OU3 are PCE and its degradation products. Additionally, three metals, iron, manganese, and aluminum were previously identified as exceeding regulatory levels and are included in the sampling plan, as are Voes and parameters relevant to natural attenuation. SAMPLING RESULTS The sampling results for the wells used for MNA are presented in Table 3. This table presents results from the December 1998, January 1999, June 1999, December 1999, and June 2000 sampling and from the previous sampling events from these wells. Table 3 presents the data in the following order: the Voe results, aluminum results, and bioparameter results, which include iron and manganese. The first five columns of the table provide monitoring well identification and information including sampling dates. The voe data are organized with the first four columns containing PCE and its degradation ( or daughter) products: trichloroethene (TCE), cis-1,2-dichloroethene (cis-1,2-DCE), and vinyl chloride (VC). The remaining columns of voe data are organized in alphabetical order. The bioparameter data are grouped into the following four categories: electron acceptors, products of degradation (including PCE daughter product ethene), nutrients, and geochemical parameters. The following summarizes the PCE data according to direction from the source (north and south) and by depth (shallow and intermediate): \\BCNSH0l\PROJECTS\PROJ\60313 .0 I S\ljunMXI. doc I I I I I I I I I I I I I I I I I Mr. Roger Towe November 10, 2000 Page 3 Source Area. The PCE concentrations from well W-17s have ranged from 42,000 µg/L to 110,000 µg/L. The two most recent samples were obtained with a bailed sample rather than by the slow-purge method. The range of concentrations is within that often observed for source areas and suggests that there has been no trend over the last two years. This well is located within the area to be treated by air sparging/ soil vapor extraction (AS/SVE). South Area of Shallow Zone. The PCE concentrations have remained very constant at 190 µg/L to 220 µg/L in W-5s and less than 2.0 µg/L in the farthest downgradient well, W-24s .. The PCE concentration from well W-22s had ranged from 3.6 µg/L to 11 µg/L and was 5.8 µg/L during the latest round of sampling. There appears to be no trend in this area of the shallow groundwater zone. South Area of Intermediate Zone. The PCE concentrations have ranged between 25 µg/L and 76 µg/L in W-5i (a possible small upward trend may exist but is not clearly distinguished from normal variability); have decreased in W-22i from 170 µg/L to 65 µg/L ( only a factor of two which cannot be viewed as trend); varied between 15 µg/L and 60 µg/L in W-291; and have varied from 0.26 µg/L to 0.95 µg/L at the farthest downgradient well, W-32i, and was 0.59 µg/L during the latest round of sampling. Because of the low concentrations, no trend can be identified. North Area of Shallow Zone. The PCE concentrations have trended upwards in W-19s from 26 µg/L to 620 µg/L; had trended upward from 3 µg/L to 48 µg/L in W-20s and is now 35 µg/L; and have remained less than 1.0 µg/L in W-3 ls, the farthest downgradient well. · North Area of Intermediate Zone. The PCE concentrations have fluctuated between 170 µg/L and 640 µg/L in W-28i and was 580 µg/L during the latest round of sampling; trended upwards in W-30i from 500 µg/L to 1,200 µg/L for the December 1999 sampling event but back down to 810 µg/L for the current sampling event; have fluctuated between 230 µg/L and 1,100 µg/L in W-20i with the most recent sample result, 230 µg/L, being nearly the same concentration as the March 1996 sample; and have remained less than 1.0 µg/L in the farthest downgradient well, W-31i, since it was first sampled in November 1998. North Area of the Deep Zone. W-20d, installed in 1998, may be decreasing from a September 1998 high of 34 µg/L to a most recent result of 1.7 µg/L. \\BCNSH0J\PROJECTS\PROJ\60313 .0 I S\ljune-00.doc I I I ,I I I I I I I I I I I I I I I I Mr. Roger Towe November 10, 2000 Page 4 Background of Shallow Zone. The PCE concentrations remain less than 1.0 µg/L in W-12s through April 1998 (no samples were collected in 1999 and June 2000) and concentrations remain stable between 1.7 µg/L (December 1999) and 6.0 µg/L (December 1995) in W-18s with the most recent result of 3.1 µg/L. Background of Intermediate Zone. The PCE concentrations remain between 0.66 µg/L and 2 µg/L in W-lOi and between 1.3 µg/L and 3.0 µg/L in W-12i. Summary of Historic Data. The PCE concentrations in most wells have remained stable. Some wells have shown upward and downward fluctuations, generally, by a factor of four or less. The exception may be the mid plume area to the north of the apparent source. There may be an upward trend in this area but it is too early to be certam. EVALUATION OF PLUME STABILITY Plume stability as a result of natural attenuation is evaluated using the primary evidence, which is the groundwater voe data, and the secondary evidence, which is the groundwater bioparameter data. Primary Evidence from VOC Data Inspection of the data in Table 3 for PCE and its daughter products reveals a relatively stable plume from April 1994 through June 2000. For instance, over this time the concentrations of PCE in W-5s located immediately south of the plant building have ranged from 190 µg/L to 220 µg/L and in W-5i have fluctuated between 25 µg/L and 76 µg/L. There is no clear long-term trend for either well. The data from W-5i suggests that some variability in voe concentrations, irrespective of any trends, should be anticipated. The relative changes observed to date for Wl5i are less than the relative changes observed for some other wells where there are no apparent trends. Continued monitoring is needed to determine if a trend exists. There has been minimal fluctuation and no significant trends in the background, side gradient, south shallow, or south intermediate, or the north shallow and the intermediate wells located farthest downgradient. It previously appeared that there might be an upward trend in well W-17 s. The most recent data suggest that there has been no real change from 1998 to 2000. W-17s is located in the source area, which will be addressed through AS/SVE. There may have been an upward trend in some of the north shallow and north intermediate wells located midway between the source area and the farthest downgradient wells. The most recent data suggest a leveling off of concentrations or that there are no long-term trends. The four wells \\BCNSH0J\PROJECTS\PROJ\603 13. 0 I 5\ljune-00.doc:: I I 'I I I I I I I I I I I I I I I I I Mr. Roger Towe November 10, 2000 Page 5 located farthest downgradient continue to have PCE concentrations of less than 1.0 µg/L. The daughter products of PCE (TCE, cis-1,2-DCE, trans-1,2-DCE, vinyl chloride, and ethene) continue to be present. The daughter product concentrations remain essentially constant relative to PCE concentrations. In W-Ss, the concentration of cis-1,2-DCE continues to exceed the concentration of its parent compound(s). Other VOCs including 1,1,1-trichloroethane (1,1,1-TCA), 1,1,2-trichloroethane (1,1,2-TCA) and the apparent degradation products 1,1-dichloroethane (1,1-DCA), 1,2-dichloroethane (1,2-DCA), and 1,1-dichloroethene (1,1-DCE) are present in a few wells at relatively constant low levels. In a few cases, compounds reported to be present in the December 1998 samples at concentrations barely exceeding detection limits were reported as not detected for the June 1999 and December 1999 sampling events. Except for samples obtained from W-Ss, the concentrations of these compounds remained below 10 µg/L. Secondary Evidence from Bioparameter Data The groundwater quality data with respect to plume stability and the presence of daughter products represent the primary lines of evidence that natural attenuation is taking place. In addition to the primary evidence, secondary evidence for the occurrence of natural attenuation is provided by the bioparameter data in the form of electron acceptors, products of degradation (in addition to the VOC daughter products discussed earlier), nutrients, and geochemical parameters. These data provide indirect evidence of reductive dechlorination except for ethene, ethane, and chloride, which are degradation products. The presence of ethene and ethane is direct evidence of reductive dechlorination. These bioparameter data also provide evidence of whether groundwater conditions are favorable for the continued occurrence of reductive dechlorination. The data for this second type of parameters are also presented in Table 3. This is only the fourth comprehensive MNA sampling event and thus any trends apparent in these data might actually reflect normal variability. Generally, the values obtained from the June 2000 sampling event are similar to the values obtained from the previous MNA sampling events. Total metals, aluminum, iron, and manganese either increased or decreased in some wells. For these wells, concentrations of all three metals decreased by approximately the same relative amounts. This may reflect variations in the amount of suspended fines in the samples rather than changes in conditions. Reported dissolved oxygen (DO) concentrations have either remained constant or trended downwards. This may reflect refinements in the sampling process or actual trends. The volatile fatty acid results for the June 1999 sampling event were largely suspect and are not reported in Table 3. Note that the June 2000 \\BCNSH0J\PROJECTS\PROJ\6031 J .0 I 5\ljuno-00.doc I I I I I I I I I I I I I I I I I I I Mr. Roger Towe November 10, 2000 Page 6 volatile fatty acid data are generally consistent with the 1998 data. The detection limits for the June 2000 volatile fatty acid data are higher than what was reported in the past, preventing a direct comparison of wells with low concentrations of volatile fatty acids. In a few cases the reported values for the soluble gases, methane, ethene, and ethane, either increased or decreased substantially. Since these gases can be easily lost during sampling, the higher of the concentrations for each well might be more likely to represent field conditions; however, no conclusions regarding trends in these parameters can be drawn until more data are obtained. Overall, we see no significant trends in the bioparameter data. SCORING RESULTS FOR NATURAL ATTENUATION USING US EPA PROTOCOL The VOC and bioparameter results have been used to score the OU3 monitoring wells according to the USEPA Protocol (EPA/600/R-98/128, September 1998) as another method of evaluating MNA. The weighting system (point assignment) used for the December 1998/January 1999 sampling event has been replaced by this USEP A protocol, which contains some modifications from the previous version used for the December 1998/January 1999 sampling event (proposed protocol by the U.S. Air Force Center for Environmental Excellence). Table 4 contains the most recent point assignment system. The major differences from the point assignment system that was previouslyused for the December 1998/January 1999 sampling event (refer to the PDI report) are that points are now subtracted if the pH is outside the optimal range and points are no longer awarded for the presence of 1,1-DCE as a daughter product of 1,1,1-TCA. The latter change was made because 1,1-DCE is a chemical degradation product rather than a biological degradation product of 1, 1, 1- TCA. Following discussions with Dr. John T. Wilson of the USEPA we have included a credit forthe presence of 1,1-DCE in the point assignment system because 1,1-DCE does provide evidence of natural attenuation degradation mechanisms, although not reductive dechlorination. The total points awarded (scores) for the individual wells were recalculated for the December 1998/January 1999 sampling event so that all sampling events for MNA parameters will have been evaluated using the same point scoring protocol. Tables 5, 6, 7, and 8 show the results of the point assignment for the December 1998/January 1999, June 1999, December 1999, and June 2000 sampling events, respectively. As a result of the revisions, some point totals have changed for the two earliest sampling events, largely because the new protocol subtracts 2 points for pH values less than 5.0 or more than 10.0. However, in most cases where points were subtracted for pH values less than 5.0, the values were only a few tenths of a pH unit below 5.0. These \\BCNSH0l\PROJECTS\PROJ\603 13,015\ljunc-00.doc I I I I I I I I I I I I I I I I I I I Mr. Roger Towe November 10, 2000 Page 7 lower pH values were quite similar to the pH values reported for the background wells. Point totals for the first sampling event have changed because the table initially contained a mix of data from the June 1998 sampling event as well as the December 1998/Januaiy 1999 sampling event. There are some differences in assigned point values among the point totals for the different sampling events. The differences reflect a number of factors: • In some cases one or more parameters were not measured and thus points could not be assigned for those particular parameters. • In some cases relatively small changes in parameter values for wells being scored resulted in significant changes in points awarded (e.g., DO values of 0.4 mg/L versus 0.6 mg/L correspond to points awarded of 3 versus 0, respectively). Also, small changes in parameter values for the background well can affect points awarded for chloride, carbon dioxide, and alkalinity. • In several wells where VOC concentrations were near the detection limit, individual VOCs were pres~nt marginally above the detection limit for one sampling event but not another. In particular, the variability in point totals for W-28i reflects the sum of small changes in DO and that the daughter product concentrations are similar to their detection limits. Some wells received a relatively low number of ranking points because they were downgradient or near the downgradient edge of the plume. Furthermore, the differences between the concentrations of chloride, carbon dioxide, and alkalinity in the background well for the shallow zone and the background well for the intermediate zone had an impact on the point totals. The interpretation guide continues to suggest that the data provide limited to adequate evidence of natural attenuation. Table 9 provides guidance from the USEPA protocol for interpreting the total points awarded (scores) for the wells. Because the ranking table is intended as a screening tool and the data used in the ranking process show little or no change over time, there is little value in continuing the use of the ranking process for OU3. \\BCNSH03\PROJECTS\PROJ\603 I 3.01 S\ljune-OO.d0<: I I I I I I I I I I I I I I I I I I I Mr. Roger Towe November 10, 2000 Page 8 CONCLUSIONS The following conclusions can be drawn from the current and historical data: • There has been no consistent upward trend in the PCE concentrations in the source area well W-17s during the period of 1998 to 2000. This area will be addressed by AS/SVE. • Generally, the plume is undergoing little change; the north plume area midway between the apparent source area (W-17) and the downgradient extent of the plume may be the exception. For the latter, the PCE concentrations are low and thus it is harder to establish any trends. • Primary evidence of the biodegradation component of natural attenuation (the presence of daughter products and a relatively stable plume) remains unchanged from previous sampling events. The most recent data suggest that trends are less likely in some wells than appeared to be the case previously. • The secondary evidence (bioparameter data) remains about the same and is generally supportive of the occurrence of reductive dechlorination. • Changes in ranking point totals reflect modifications to the protocol, small differences in analytical results between sampling events, small changes in detection limits, and a few suspect analyses. Continued use of the ranking system for OU3 does not appear to be beneficial. • Results from subsequent sampling events should continue to be evaluated to identify trends that may develop. To date, trends have been difficult to identify because of the relatively small data set for some monitoring wells (six to eight sets of groundwater data are typically reqwred to establish a trend). Also, trends have been difficult to identify because small changes in some parameters are difficult to distinguish from normal variability in the data, particularly for VOC data when the concentrations are low (i.e., approaching the detection limit). Overall, there appear to be few trends in the data. A steady-state plume suggested by the lack of trends is an indication of natural attenuation. \\BCNSH03\PROJECTS\PROJ\60J 13. 0 I 5\ljunc-00.doc I I I I I I I I I I I I I I I I I I I Mr. Roger Towe November 10, 2000 Page9 Please call Bob Norris at (303) 743-5421 or Ken Oma at (615) 255-2288 if you have any questions or comments regarding this letter report. Sincerely, BROWN AND CALDWELL· -/1 ,f / •. ")'Jf / / ,,?:'/ ?f rti'"'V // e(y/... rf,L. Robert D. Norris, Ph.D. Technical Director In-Situ Remediation cc: K. Mallary, EPA Region 4 N. Testerman, NCDENR S. Miller, El Paso J. Porter, The Porter Law Group N. Prince, ESC \\BCNSH0J\PROJECTS\PROJ\603 13 .0 I S\!june.00.doc Kenton H. Oma, P.E. Assistant Technical Director Design & Solid Waste H. Mitchell, Jr., Beaunit M. 'Garlick, Burlington B. Wicker, Burlington G. House, BPMH&L I I I I I I I I I I I I I I I I I I I Table 1. Monitoring Wells Selected for Semiannual Groundwater Sampling, FCX-Statesville Superfund Site OU3 Groundwater Zone Shallow: Intermediate: Deep: Monitoring Well" W-5s W-12s•·c W-17s' W-18s0 W-19s W-20s W-22s' W-24s W-31s W-Si w-1rn• W-12i0 W-20i W-22i0 W-28i W-29i W-30i W-31i W-32i W-20d "The analytical methods for the analyses of groundwater samples are given in Table 2. 0Natural attenuation background well. . °Well was not sampled because of low water level or dryness. 'Bailer was used to purge well. Well was sampled for a limited list of parameters due to low water level. "Well was not sampled due to inaccessibility. \\BCNSH03\PROJECTS\PROJ\60313.01 5~une-00-t01.doc Page 1 of 1 I I I I I I I I I I, I I I I I I I I I 0 0 ,,, II w --' <) <Jl f-0 --' Q_ 0 0 '-,,, 0 '--w ';, 0 I U1 I ,,, ,,, 0 <O 0 z "' z i 0: 0 Legend -$-Shallow Monitoring Well Location ~ Intermediate Monitoring Well Location ♦ Deep Monitoring Well Location FIGURE 1 MONITORING WELL LOCATION MAP FCX-STATESVILLE SUPERFUN 60313.015 STATESVILLE, NORTH c.&o~~~ OU3 10/99 BROWN AND CALDWELL Nashville, TenneSllee I I I I I I I I I I I I I I I I I I I 0 0 ,,, II -w ...J c) VJ f- 0 ...J CL 0 0 '-,,, 0 '--w ~ ., I "' -I ,,, ,,, 0 "' ci z " z 3: ., Ct'. 0 ,...., j Legend -$-· Shallow Monitoring Well Location ~ ♦ Intermediate Monitoring Well Location Deep Monitoring Well Location -10-Groundwater lsoconcentrotion Contour [ X l ( X ) PCE Results In (ppb) from June 2000 Monitored Moturol Attenuation (MNA) Sampling PCE Results in (ppb) from Remedial Investigation (RI) or Pre-Design Investigation (POI) FIGURE 2 ISOCONCENTRA TION MAP FOR PCE IN SHALLOW GROUNDWATER FCX-STATE~LLE SUPERFUND SITE, OU3 STATE~LLE, NORTH CAROLINA 30~0§f~EE::IOE===~3~0~0===~600 60313.015 1 0/99 SCALE BR OWN AND FEET CALDWELL Nashville, Tenne11see I I I I I I I I I I I I 0 0 "' II -I w _, < u (/) >-- I g a. 0 0 -----I n 0 ------w I ~ 0 <11 I <11 I I "' n 0 <O ci I z '-' z ! "' I 0 SCALE Legend Shallow Monitoring Well Location Intermediate Monitoring Well Location Deep Monitoring Well Location -10 -Groundwater lsoconcentrotion Contour [ X l ( X ) PCE Results in (ppb] from June 2000 Monitored natural Attenuation (MNA) Sampling PCE Results in (ppb) from Remedial lnvestigotion (RI) or Pre-Design Investigation (PDI) FIGURE 3 ISOCONCENTRATION MAP FOR PCE IN INTERMEDIATE GROUNDWATER FCX-STATESVILLE SUPERFUND SITE, OU3 STATESVILLE, NORTH CAROLINA 60313.015 10/99 BROWN AND CALDWELL Nashville, T,nnmee -------------------Table 2. Summary of Chemical Analyses and Analytical Method References for Semiannual Groundwater Sampling, FCX-Statesville Superfund Site OU3 Sample Evaluation Chemical Test/Analyte Parameter Analytical Reference Methoda DQO Levelb Field Measurements: Laboratory Analyses: Carbon dioxide Iron (II) Manganese (II) Sulfide Conductivity Oxidation-reduction potential (ORP) pH Dissolved oxygen (DO) Temperature Chloride Iron (total) Manganese (total) Aluminum (total) Nitrate/nitrite Sulfate Ethane, ethene, and methanee TCL voes Alkalinity ( carbonate/bicarbonate if Dissolved total organic carbon (TOG) Volatile fatty acids Hach Kitc Hach KitC Hach KitC Hach Ki!C ASTM Method D-1125-82 ASTM Method D-1498-76 ASTM Method D-1293-84 CHEMETRICS Kitc NAd USEPA Method 325.2 Aquaterra QAPP Table 3 Aquaterra QAPP Table 3 Aquaterra QAPP Table 3 USEPA Method 353.2 USEPA Method 375.4/9038 USEPA Method 8015-Modified Aquaterra QAPP Table 2 Standard Methods 2320B USEPA Method 415.1 Standard Methods 5560C Ill IV IV IV Ill 111 Ill IV 111 111 Ill asample preservatives, when required by the method, will be added to sample containers at the analytical laboratory prior to sampling. Contract Required Detection Limits (CRDLs) will be according to the contract laboratory procedure (CLP) methods referenced in the Aquaterra QAPP Tables 2 and 3. bDQOs (Data Quality Objectives) and QNQC frequencies per "Environmental Investigations Standard Operating Procedures and Quality Assurance Manual", May 1996, USEPA Region 4. Level I= Field Screening; Level II= Field Analyses; Level Ill= Screening Data with Definitive Confirmation; Level IV = Definitive Data. CMethod will be per manufacture's procedures. dNot Applicable. eAnalysis will be subcontracted to Microseeps Incorporated, Pittsburgh, Pennsylvania. !samples to be collected in zero headspace containers to prevent exchange of carbon dioxide between the samples and the atmosphere. P:\PROJ\60313.015\june-00-t02.doc Page 1 of 1 --- ---.. ------.. - - ---Table 3. Data from Monitoring Wells Used for Evaluation of Monitored Natural Attenuation 10127100 FCX-Statesville Superfund Site OU3 Well Information Volatile Organic Compounds e CIS-, - Monitoring Screened Sampling T etrachloro-Trichloro-Dichiaro-Carbon Chiaro-1, 1-Dichloro- Well Zone Well Type Depth Date ethene ethene · ethene Vinyl chlonde Acetone Benzene disulfide Chloroform methane ethane (ft) (µg/L) (µg/L) (µg/L) (µg/L) (µg/L) (µg/L) (µg/L) (µg/L) (µg/L) (µg/L) W-1s Side Gradient Shallow 38-48 12119/98 140DJ 0.7 DJ 1.0 U 5.0 UD NR' 5.0UD 5.0UD 1.0JD 5.0 U 5.0UD W-5s South Plume Shallow 32-42 4/1/94 200 38J 1,000 sou 530 U 50 U 50 U 50 U sou 430 W-5s South Plume Shallow 32-42 1011/94 190 38J 1,000 sou 250 U 50 U 50 U 50 U 50 U 380 W-5s South Plume Shallow 32-42 4/30/98 200 DJ 55 J 1,300 DJ 8.2 J 61 UJ 2.9 J 5.0 UJ 2.2 J 5.0UJ 340 DJ W-5s South Plume Shallow 32-42 12117/98 200 UJ 53 J 1,600J 50J NR 200 UJ 200UJ 200 UJ 200 UJ 270J W-5s1 South Plume Shallow 32-42 6/9/99 190 D 57 JD 1100 D 100 UD 500UJ 100 UD 100UD 100UD 100 UD 240 D W-5s South Plume Shallow 32-42 1217/99 220 D 75 JD 1,100 D 100 UD 500UD 100 UD 100UD 100 UD 100 UD 280D W-5s Dup South Plume Shallow 32-42 12117/99 200 D 670 1,600 D 26 DJ NR 4JD 50UD 50 UD 50 UD 2900 W-5s South Plume Shallow 32-42 6/6/00 190 D SOJO 1100 D 100 UD 500 UD 100 uo 100 uo 100 UD 100 UD 220 D W-5i South Plume Intermediate 56-66 1011/94 25 2.0J 11 10 U 50 U 10 U 10 U 2.0 J 10 U 5J W-5i South Plume Intermediate 56-66 515/98 49D 4.9 DJ 4 DJ 5.0UD 25 UD 5.0UD 5.0 UD 5.0UD 5.0UD 3.3 DJ W-5i South Plume Intermediate 56-66 12119/98 28 D 4 10J 0.3 J NR 1.0 U 1.0U 0.06J 1.0UJ 5J W-5i South Plume Intermediate 56-66 6/8/99 48D 4.6 D 6.9 D 2.0 UD 10 UJ 2.0 UD 1.0 JD 2.0UD 2.0 UD 4.5 D W-5i South Plume Intermediate 56-66 1218/99 55D 6.5 D 9.9 D 5.0 UD 25 UD 5.0 UD 5.0 UD 5.0UD 5.0 UD 8.10 W•5i South Plume Intermediate 56-66 6/9/00 730 6.7 D 12 D 5.0UD 25UD 5.0 uo 5.0 UD 5.0 uo 5.0 UD 8.0 D W•5iDup South Plume Intermediate 56-66 6/9/00 76 D 6.40 12 D 5.0UD 25 UD 5.0 UD 5.0 UD 5.0 UD 5.0 UD 8.1 D W-6s Side Gradient Shallow 22-37 4/30/98 W-6s Dup Side Gradient Shallow 22-37 4/30/98 W-6i Side Gradient Intermediate 83-93 12116/98 75 J 4 3 0.09 J 44 J 0.08J 0.5 J 1.0U 0.2 J W-9s Treatment Shallow 34-49 5/5/98 3,100 D 14 D 1.9 DJ 10 UD 50UD 10 UD 10 UD 2.1 DJ 10 UD 10UD W-9s Dup Treatment Shallow 34-49 515/98 3,200 D 13 D 2 DJ 10 UD 50UD 10 UD 10UD 2.2 DJ 10 UD 10UD W-9s Treatment Shallow 34-49 12117/98 6,000 D 24 DJ 200UD 200 UD NR 200 UD 200 UD 200 UD 200U 200 UD W-10i Side Gradient Intermediate 59-69 1011/94 1.0U 1.0U 1.0 U 1.0 U 11.0 U 1.0U 1.0U 1.0U 1.0U 1.0U W-10i Side Gradient Intermediate 59-69 111/95 0.9 J 0.2 J 1.0 U 1.0U 6.0 U 1.0U 1.0 U 1.0U 1.0U 1.0U W-10i Side Gradient Intermediate 59-69 1211/95 0.9 J 2 0.2 J 1.0U BU 1.0U 1 0.2 J 0.2 J 1.0U W-10i Side Gradient Intermediate 59-69 4130/98 0.66J 1.0U 1.0 U 1.0 U 5.0 U 1.0U 1.0U 1.0U 1.0U 1.0U W-10i Side Gradient Intermediate 59-69 12119/98 2 1.0U 1.0 UJ 1.0 U NR 1.0UJ 1.0 U 1.0U 1.0U 1.0U W-10i Side Gradient Intermediate 59-69 618199 1.8 1.0 U 1.0 U 1.0U 5.0 U 1.0U 24 D 1.0 U 1.0U 1.0U W-10i Side Gradient Intermediate 59-69 12/9/99 1.1 1.0U 1.0U 1.0 U 5.0 U 10U 1.0 U 1.0U 1.0U 1.0U W-10i Side Gradient Intermediate 59-69 6/6100 0.81J 1.0 U 1.0 U 1.0 U 5.0 U 1.0 U 0.35J 1.0 U 1.0 U 1.0 U P:\Proj\60313. 01 S~une-0O-t03.xls Page 1 of 26 --.. ... ------ --- ---- --Table 3. Data from Monitoring Wells Used for Evaluation of Monitored Natural Attenuation 10/27/00 FCX-Statesville Superfund Site OU3 Well Information Volatile Organic Compounds e CIS-, - Monitoring Screened Sampling T etrachloro-Tnchloro-Dichiaro-Carbon Chloro-1, 1-Dichloro- Well Zone Well Type Deplh Dale ethene ethene ethene Vinyl chloride Acetone Benzene disulfide Chloroform methane ethane (ft) (µg/1.) (µg/1.) (µg/1.) (µg/1.) (µg/1.) (µg/1.) (µg/1.) (µg/1.) (µg/1.) (µg/1.) W-11s Side Gradient Shallow 25--40 4/30198 W-12s Background Shallow 16-33 10/1194 1.0 U 1.0U 1.0 U 1.0U 5.0 U 1.0U 1.0U 1.0U 1.0U 1.0 U W-12s Background Shallow 18-33 1/1195 1.0 U 1.0U 1.0 U 1.0 U 5.0 U 1.0U 1.0U 0.1 J 1.0U 1.0 U W-12s Background Shallow 16-33 4/30198 1.0 U 1.0 U 1.0 U 1.0U 5.0 U 1.0U 1.0 U 1.0 U 1.0U 1.0 U W-12s Background Shallow 18-33 12/8199 W-12i Background Intermediate 73-83 10/1194 3.0 1.0 U 1.0U 1.0 U 5.0 U 1.0 U 1.0U 1.0U 1.0U 0.3 J W-12i Background Intermediate 73-83 1/1/95 2.0 1.0 0.1 J 1.0U 6.0U 1.0 U 4.0 0.1 J 1.0U 0.4 J W-12i Background Intermediate 73-83 4/30/96 1.5 1.0U 1.0U 1.0U 310 DJ 1.0 U 0.39J 0.14J 1.0U 1.0U W-12i Background Intermediate 73-83 12/16198 2J 1.0U 1.0 U 1.0U NR 0.04 J 0.05 J 0.3 J 1.0U 0.5 J W-12i Background Intermediate 73-83 61//99 2.5 1.0 U 1.0U 1.0U 5.0 U 1.0 U 1.0 U 0.35 J 1.0U 0.50J W-12i Background Intermediate 73-83 12/9199 2.2 1.0U 1.0 U 1.0 U 5.0 U 1.0U 1.0U 1.0 U 1.0 U 0.59J W-12i Background lntennediate 73-63 6/7/00 1.3 1.0 U 1.0 U 1.0 U 5.0 U 0.46J 0.74J 1.0 U 1.0 U 1.0 U W-16s Treatment Shallow 35-50 5/5/98 W-16s Treatment Shallow 35-50 12/17198 2,300 D 40 DJ 200UD 200 UD NR 200 UD 200 UD 25 DJ 200 UD 200 UD W-16i Treatment Intermediate 77-87 5/5198 W-16i Treatment Intermediate 77-87 12/17/98 1,000 D 26D 16 D 2.0 UD NR 2.0 UD 2.0UD 40 D 2.0 U 2.0 UD W-17s Source Shallow 29.5-44.5 10/1/94 42,000 4,ooo u· 430 J 4,000 U 20,000 U 4,000 U 4,000 U 4,000 U 4,000 U 4,000 U W-17s Source Shallow 29.5-44.5 1/1195 57,000 480 J 880 J 4,000 U 20,000 U 4,000 U 4,000 U 4,000 U 4,000 U 4,000 U W-17s Source Shallow 29.5--44.5 5/5/98 84,000 D 410 D 720 D 250 UD 1,200 UD 250 UD 250 UD 110 DJ 250 UD 250UD W-17s Source Shallow 29.5-44.5 12/18198 72,000 D 10,000 UD 10,000 UD 10,000 UD NR 10,000 UD 10,000 UD 10,000 UD 10,000 UD 10,000 UD W-17s' Source Shallow 29.5-44.5 12/9199 110,000 D 5,000 UD 510 JD 5,000 UD 25,000 UD 5,000 UD 5,000 UD 5,000 UD 5,000 UD 5,000 UD W-17s Source Shallow 29.5-44.5 6/6/00 70,000 D 10,000 UD 1,000 JD 10,000 UD 50,000 UD 10,000 UD 10,000 UD 10,000 UD 10,000 UD 10,000 UD W-18s Background Shallow 22.5-37.5 12/1/95 6 6 0.8 J 1.0U 5U 1.0U 1.0 U 0.6J 1.0 U 1.0 U W-18s Background Shallow 22.5-37.5 4/30198 3.5 1.0U 1.0 U 1.0 U 6.0 U 1.0 U 1.0 U 1.0U 1.0 U 1.0 U W-18s Background Shallow 22.5-37.5 12/16198 4J 1.0 U 1.0 U 1.0U NR 1.0 U 1.0 U 1.0U 1.0U 1.0 U W-18s Background Shallow 22.5-37.5 6/8199 3.8 1.0U 1.0 U 1.0 U 5.0 U 1.0 U 1.0 U 1.0U 1.0U 1.0 U W-18s Background Shallow 22.5-37.5 12/6/99 1.7 1.0U 1.0U 1.0 U 5.0 U 1.0U 1.0 U 1.0U 1.0 U 1.0 U W-18s Background Shallow 22.5-37.5 6/6/00 3.1 1.0 U 1.0 U 1.0 U 5.0 U 1.0 U 1.0 U 1.0U 1.0U 1.0 U P:\Proj\60313.015\june-00.103.xls Page 2 of 26 - ------------- --- --Table 3. Data from Monitoring Wells Used for Evaluation of Monitored Natural Attenuation 10/27/00 FCX-Statesville Superfund Site OU3 Well lnfonnatlon Volatile Organic Compounds e CIS-I - Monitoring Screened Sampling T etrachloro-Trichloro-Dichiaro-Carbon Chiaro-1, 1-Dichloro- Well Zone Well Type Depth Date ethene ethene ethene Vinyl chloride Acetone Benzene disulfide Chlorofonn methane ethane (ft) (µg/L) (µg/L) (µg/L) (µg/L) (µg/L) (µg/L) (µg/L) (µg/L) (µg/L) (µg/L) W-19s North Plume Shallow 17-27 1211/95 26 4 1 J 2.0U 10U 2.0 U 0.4J 0.3 J 2.0 U 2.0 U W-19s North Plume Shallow 17-27 5/5/98 26 D 1.2 DJ 0.82 DJ 2.5UD 12UD 2.5 UD 2.5UD 0.56 DJ 2.5 UD 2.5 UD W-19s North Plume Shallow 17-27 12/17/98 250J 5 4.0 U 1.0U NR 1.0U 1.0 U 1.0 J 1.0U 1.0 U W-19s North Plume Shallow 17-27 6/10/99 330 D 7.4 JD 10 UD 20 UD NR 20 UD 20UD 20 UD 20UD 20UD W-19s North Plume Shallow 17-27 12/7/99 420 D 11 JD 22 D 20UD 100UD 20UD 20UD 20UD 20 UD 20 UD W-19s North Plume Shallow 17-27 6/6/00 620 D 13 D 25 D 5.0 UD 25UD 5.0 UD 5.0UD 5.0 UD 5.0UD 5.0UD W-20s North Plume Shallow 4-14 12/1/95 3 0.5 J 0.8 J 1.0U 7U 1.0 U 1.0 U 0.2 J 1.0U 1 U W-20s North Plume Shallow 4-14 4/29/98 20 0.89J 3.4 1.0 U 5.0U 1.0 U 1.0 U 0.23J 1.0U 1.0U W-20s Dup North Plume Shallow 4-14 4/29/98 17 0.8 J 3.1 1.0U 5.0 U 1.0 U 1.0 U 0.21 J 1.0 U 1.0U W-20s North Plume Shallow 4-14 12120/98 27DJ 1 4J 1.0U NR 1.0 U 1.0 U 0.2 J 1.0U 1.0 U W-20s North Plume Shallow 4-14 6/8/99 46D 1.9JD 5.1 D 2.0 UD 10UD 2.0 UD 2.0UD 2.0 UD 2.0UD 2.0 UD W-20s North Plume Shallow 4-14 12/7/99 40D 2.9 D 8.4 D 2.0UD 10 UD 2.0 UD 2.0UD 2.0 UD 2.0UD 2.0 UD W-20s Dup North Plume Shallow 4-14 12/7/99 42 D 3.10 8.3 D 2.0 UD 10UD 2.0 UD 2.0 UD 2.0UD 2.0 UD 2.0UD W-20s North Plume Shallow 4-14 6/8/00 350 1.3JD 4.8JD 5.0 UD 25UD 5.0UD 5.0 uo 5.0UD 5.0UD 5.0 UD W-20s Dup North Plume Shallow 4-14 6/8/00 31 D 1.8 5.6 1.0 U 5.0 U 1.0 U 1.0 U 1.0 U 1.0 U 1.0U W-20i North Plume Intermediate 84-94 3/1/96 240 13 J 29 20 U 100 U 20 U 20 U 20 U 20 U 20 U W-20i North Plume Intermediate 84-94 4/29/98 310DJ 18 JD 25 J 2.0UJ 10 UJ 2.0UJ 0.48 J 0.77 J 2.0 UJ 2.0 UJ W-20i North Plume lntennediate 84-94 12/15/98 1,100 D 75 D 120 D 50UD NR 50 UD 14 DJ 5JD 50 UD 50 UD W-20i North Plume Intermediate 84-94 1/26/99 450D 34 D 29 D 1.0 U 5.0 U 0.08J 1.0 U 1 1.0 U 0.3 J W-20i North Plume Intermediate 84-94 1/27/99 380D 29 D 24 D 20 UD 100UD 20 UD 20 UD 20 UD 20 U 20 UD W-20i North Plume Intermediate 84-94 6/8/99 440D 30 JD 23 JD 50 UD 250 UD 50UD 50 UD 50 UD 50 UD 50UD W-20i North Plume Intermediate 84-94 12/7/99 270D 25 JD 19 JD 50 UD 250 UD 50UD 50UD 50UD 50 UD 50UD W-20i North Plume Intermediate 84-94 6/8/00 230 D 20 16 0.19 J 5.0 U 1.0 U 1.1 1.0 U 1.0U 1.0 U W-20d' North Plume Deep 152-166 9/23/98 34 D 4.9 9.4 1.0U 22 1.0 U 1.0 U 0.50 U 1.0 U 1.0U W-20d North Plume Deep 152-166 12117/98 12 J 2 0.02 J 1.0 U 12 J 0.o7J 1.0 U 1.0U 1.0 U 1.0U W-20d North Plume Deep 152-166 6/9/99 4.3 2.0 1.2 1.0 U 8.4 1.0 U 1.0U 1.0U 1.0 U 1.0 U W-20d North Plume Deep 152-166 1219/99 5.8 3.1 1.6 1.0U 13 1.0U 1.0 U 1.0 U 1.0U 1.0U W-20d North Plume Deep 152-166 6/9/00 1.7 1.4 1.3 1.0 U 11 U 1.0 U 1.0 U 1.0 U 0.18 J 1.0 U W-22s South Plume Shallow 20-35 1211/95 4 3 1 J 0.3 J 6U 1.0 U 1.0 U 0.3 J 1.0 U 0.7 J W-22s Sou1h Plume Shallow 20-35 5/1/98 3.6 0.12 J 2.5 0.45J 5.0 U 1.0U 1.0U 1.0 U 1.0U 1.1 W-22s South Plume Shallow 20-35 12120/98 4 1.0 U 2J 0.4 J NR 1.0U 1.0 U 1.0U 0.1 J 0.6J W-22s' South Plume Shallow 20-35 12/8/99 11 0.20 J 3.1 0.43 J 5.0 U 1.0 U 1.0U 1.0U 1.0U 1.0 W-22s South Plume Shallow 20-35 617/00 5.8 1.0 U 1.0 U 0.23J 5.0 U 1.0 U 1.0 U 1.0 U 1.0U 1.0 U P:\Proj\60313. O 15\june-OO-to3.xls Page 3 of 26 - --------------- - --Table 3. Data from Monitoring Wells Used for Evaluation of Monitored Natural Attenuation 10/27/00 FCX-Statesville Superfund Site OU3 Well lnfonnation Volatile Organic Compounds e CIS-, - Monitoring Screened Sampling T etrachloro-Trichloro-Dichiaro-Carbon Chiaro-1.1-Dichloro- Well Zone Well Type Depth Date ethene ethene ethene Vinyl chloride Acetone Benzene disulfide Chloroform methane ethane (fl) (µg/L) (µg/L) (µg/L) (µg/L) (µg/L) (µg/L) (µg/L) (µg/L) (µg/L) (µg/L) W-22i South Plume Intermediate 57-67 311/96 170 16 90 10 U 50 U 10U 10U 10U 10 U 47 W-22i South Plume Intermediate 57-67 5/1/98 1500 11 1000 2.1 5.0 U 0.28J 1.0 U 0.54J 1.0U 46 D W-22i Sou1h Plume Intermediate 57-67 12/20/98 110 J 10 D 140J 3 DJ NR 10 U 10UD 0.8 J 10 UJ 58J W-22i South Plume Intermediate 57-67 6/9/99 86 D 11 D 96 D 10 UD NR 10 UD 10UD 10UD 10 UD 46 D W-22i South Plume Intermediate 57-67 12/8/99 650 8.5 JD 770 10 UD 50UD 10 UD 10 UD 10UD 10 UD 40 D W-22i Dup South Plume Intermediate 57-67 12/8/99 63 D 8.2 JD 73 D 1.4 JD 50 UD 10 UD 10 UD 10 UD 10 UD 38 D W-24s South Plume Shallow 5-20 12/1/95 2 0.3 J 1.0U 7U 1.0 U 1.0U 0.2 J 1.0U 0.3 J W-24s South Plume Shallow 5-20 5/1/98 0.35 J 1.0U 1.0 U 1.0U 5.0U 1.0U 1.0U 1.0 U 1.0U 1.0 U W-24s South Plume Shallow 5-20 1/27/99 1.0 U 1.0 U 1.0 U 1.0U 5.0 U 1.0U 1.0 U 0.1 J 1.0U 0.2J W-24s Dup South Plume Shallow 5-20 1/27/99 1.0U 1.0 U 1.0 U 1.0U 5.0 U 1.0U 1.0U 0.06 J 1.0U 0.2 J W-24s South Plume Shallow 5-20 6/9/99 O.SOJ 1.0 U 1.0 U 1.0U 5.0U 1.0U 1.0 U 1.0 U 1.0U 1.0 U W-24s South Plume Shallow 5-20 12/8/99 1.9 1.0 U 0.25J 1.0 U 5.0 U 1.0 U 1.0U 1.0 U 1.0 U 0.30 J W-24s South Plume Shallow 5-20 617/00 0.55J 1.0 U 1.0 U 1.0 U 5.0 U 1.0 U 1.0U 1.0U 1.0 U 1.0 U W-26i Side Gradient Intermediate 103-118 12/16/98 0.3 J 0.09 J 0.03 J 0.2J 3J 0.1 J 0.4 J 1.0U 1.0 U 1.0U W-28i North Plume Intermediate 73-88 12/1/95 230 32 12 10U sou 10 U 10 U 4J 10 U 10 U W-28i North Plume Intermediate 73-68 5/5/98 1700 42 D 16 D 10 UD 50UD 10UD 10UD 10UD 10UD 10 UD W-28i North Plume Intermediate 73-68 12/18/98 640 D 24 D 9.0 DJ 10 UD NR 10 UD 10UD 2JD 100 U 10 UD W-28i North Plume Intermediate 73-68 6/8/99 2500 40 JD 15 JD 50 UD 250 UD 50 UD SOUD 50 UD 50 UD 50 UD W-28i North Plume Intermediate 73-68 12/7/99 3100 43 D 14JD 50 UD 250 UD 50 UD 50UD 50UD 50 UD SOUD W-281 North Plume Intermediate 73-88 6/6/00 580 D 33 D 11 D 5.0 UD 25UD 5.0UD 5.0 UD 5.0UO 5.0 uo 5.0UO W-29i South Plume Intermediate 88-98 12/1/95 15 0.8 J 3 1.0 U 5.0 U 1.0 U 1.0U 0.8 J 1.0U 2 W-29i South Plume Intermediate 88-98 5/1/98 42 D 1.4 DJ 80 2.5 UD 12UD 2.5 UD 2.5 UD 1.1 DJ 2.5 UD 5.40 W-29i South Plume Intermediate 88-98 12/20/98 32J 2JD ?DJ 0.2 DJ NR 2.0 UD 2.0UD 1 J 2.0 UJ 4J W-29i Dup South Plume Intermediate 88-98 12120/98 34 DJ 2 DJ 7 DJ 0.2 DJ NR 2.0 UD 2.0UD 1 DJ 2.0 UDJ 5 DJ W-29i South Plume Intermediate 88-98 6/9/99 50 D 5.0 D 7.9 D 2.0UD NR 2.0 UD 2.0UD 0.92 JD 2.0 UD 4.7 D W-29i Dup South Plume Intermediate 88-98 6/9/99 49 D 5.3 D 7.8 D 2.0UD NR 2.0 UD 2.0UD 0.83 JD 2.0UD 4.5 D W-29i South Plume Intermediate 88-98 12/9/99 52 D 2.7 JD 8.1 D 5.0 UD 25UD 5.0 UD 5.0UD 5.0 UD 5.0 UD 6.3 D W-29i Dup South Plume Intermediate 88-98 12/9/99 50 D 2.6 JD 7.8 D 5.0UD 25UD 5.0 UD 5.0UD 5.0 UD 5.0 UD 6.3 D W-29I South Plume Intermediate 88-98 617/00 60 0 1.7 JO 9.8 0 5.0 uo 25 uo 5.0UO 5.0UO 5.0UO 5.0UO 6.9 0 W-29I Oup South Plume Intermediate 88-98 617/00 55 0 2.6 12 1.0 U 5.0 U 1.0 U 1.0 U 1.0 U 1.0 U 7.6 P:\Proj\60313.01 5~une-00-t03.xls Page 4 of 26 -------- ---- - - -----Table 3. Data from Monitoring Wells Used for Evaluation of Monitored Natural Attenuation 10/27/00 FCX-Statesville Superfund Site OU3 Well lnfonnation Volatile Organic Compounds e as-, - Monitoring Screened Sampling T etrachloro-Trichloro-Dichloro-Carbon Chloro-1,1-0ichloro- Well Zone Well Type Depth Date ethene ethene ethene Vinyl chloride Acetone Benzene disuffide Chloroform methane ethane (fl) (µg/L) (µg/L) (µg/L) (µg/L) (µg/L) (µg/L) (µg/L) (µg/L) (µg/L) (µg/L) W-30i North Plume Intermediate 37.5-47.5 12/1195 530 28 J 28 J sou 250 U 50 U 50 U 6J sou sou W-30i North Plume Intermediate 37.5-47.5 4/30/98 500 D 34 D 20D 2.5 uo 20 UD 2.5 UD 2.5UD 2.5 uo 1.2 OJ 2.5 UD W-30i North Plume lntennediate 37.5-47.5 12/19198 560 DJ 46 D 28 JD 20 uo NR 20UD 20 UD 20 uo 20U 20UD W-30i North Plume Intermediate 37.5-47.5 1/26199 1,100D 820 43JD 0.2J 5.0 U 0.2J 1.0 U 0.4 J 1.0U 0.2 J W-30i North Plume Intermediate 37.5-47.5 1/27199 1,1000 85 D 42JD souo 250 UD SOUD souo 50 uo SOUD 50UO W-30i North Plume Intermediate 37.5-47.5 619/99 1,100 D 71 D 34 JO SOUD NR souo SOUD SOUD 50 UD souo W-30i North Plume Intermediate 37.5-47.5 12/8199 1,2000 71 JO 33 JO 100 UD 500 uo 100 uo 100 UD 100 UD 100 UD 100 uo W•30i North Plume Intermediate 37,5-47.5 617/00 810 D 59 D 340 5,0 UD 25 UD 5.0 UD 5.0 UD 5.0 UD 5.0UD 5.0UD W-31s North Plume Shallow 5-15 11/1198 1.0U 1.0 U 1.0U 1.0U 5.0 U 1.0 U 1.0 U 0.25J 1.0U 1.0 U W-31s North Plume Shallow 5-15 11/19198 1.0U 1.0U 1.0U 1.0 U 5.0 U 1.0 U 1.0 U 0.25J 1.0 U 1.0U W-31s Oup North Plume Shallow 5-15 11/19198 1.0U 1.0U 0.06J 1.0U 5.0 U 1.0 U 1.0 U 0.29J 1.0U 1.0U W-31s North Plume Shallow 5-15 12/16/98 1.0U 1.0U 0.04J 1.0U NR 1.0 U 1.0U 0.05 J 1.0 U 1.0U W-31sc North Plume Shallow 5-15 617/99 1.0U 1.0U 1.0 U 1.0 U 5.0 U 1.0 U 1.0 U 1.0 U 1.0 U 1.0 U W-31s' North Plume Shallow 5-15 6/10/99 0.26 J 1.0 U 1.0U 1.0U NR 1.0U 1.0 U 1.0 U 1.0 U 1.0 U W-31s North Plume Shallow 5-15 12/6/99 1,0 U 1.0U 1.0U 1.0 U 5.0 U 1.0 U 1.0U 1.0 U 1.0U 1.0 U W-31s Dup North Plume Shallow 5-15 12/16/99 1.0U 1.0 U 0.06 J 1.0 U NR 1.0U 1.0U 0.04 U 1.0 U 1.0 U W-31s North Plume Shallow 5-15 6/5/00 1.0U 1.0 U 1.0U 1.0 U 5,0 U 1.0 U 1.0 U 1.0 U 1.0U 1.0 U W-31i North Plume Intermediate 34-44 11/1/98 1.0U 1.0 U 1.0 U 1.0U 5.0 U 1.0 U 1.0U 1.0U 1.0U 1.0 U W-31i North Plume Intermediate 34-44 11/19/98 1.0U 1.0U 1.0U 1.0 U 5.0 U 1.0U 1.0 U 1.0 U 1.0U 1.0 U W-31i North Plume Intermediate 34-44 12/16198 0.1 J 1.0 U 1.0U 1.0U NR 1.0U 1.0 U 0.09J 1.0U 1.0U W-31i North Plume Intermediate 34-44 617199 1.0U 1.0U 1.0U 1.0U 5.0 U 1.0U 1.2 1.0U 1.0U 1.0U W-31i North Plume Intermediate 34-44 12/6/99 1.0 U 1.0 U 1.0U 1.0U 5.0 U 1.0U 1.0 U 1.0 U 1.0 U 1.0 U W-31i North Plume Intermediate 34-44 6/5/00 1.0 U 1.0U 1.0 U 1,0 U 5,0 U 1.0U 1.0U 1.0 U 1.0 U 1,0 U W-32i South Plume Intermediate 112-132 11/1198 0.26 J 0.11 J 1.0U 1.0U 5.0 U 1.0 U 1.0 U 0.14 J 1.0U 1.0U W-32i South Plume lntermedia1e 112-132 11/19/98 0.26J 0.11 J 1.0U 1.0U 5.0 U 1.0 U 1.0 U 0.14 J 1.0U 10U W-32i South Plume Intermediate 112-132 12/18/98 0.4J 0.2 J 1.0UJ 1.0 U NR 1.0 U 1.0 U 1.0 U 1.0 U 1.0U W-32i South Plume Intermediate 112-132 6/9199 0.63 J 0.22 J 1.0U 1.0 U 5.0 U 1.0U 1.0 U 1.0U 1.0 U 1.0U W-32i South Plume Intermediate 112-132 12/7/99 0.95 J 0.28 J 1.0 U 1.0 U 5.0 U 1.0U 1.0 U 1.0 U 1.0U 1.0 U W-32i South Plume Intermediate 112·132 6/8/00 0.59J 1.0 U 1.0 U 1.0 U 5.0 U 1.0U 2.3 1.0 U 0.13 J 1.0 U P:\Proj\60313.015\june-00-103.xls Page 5 of 26 -- ----- --- ---------Table 3. Data from Monitoring Wells Used for Evaluation of Monitored Natural Attenuation 10/27/00 FCX-Statesville Superfund Site OU3 Well lnfonnation Volatile Organic Compounds e Monitoring Screened Sampling 1.2-Dichloro-1, 1-Dichloro-1,2-Dichloro-Me1hylene 4-Me1hy\-2-Trichloro-Trichloro- Well Zone Well Type Depth Dale ethane ethene ethene propane chlonde pentanone Toluene ethane ethane (ft) (µgll) (µgll) (µgll) (µg/L) (µgll) (µgll) (µg/L) (µg/L) (µgll) W-1s Side Gradient Shallow 38-48 12/19198 5.0UD 20 U 1.0 U 5.0 UD 10 U 25 UD 5.0UD 5.0 UD 5.0 UD W-5s South Plume Shallow 32-42 4/1194 sou 81 50 U sou 50 U 250 U sou 150 13 J W-5s South Plume Shallow 32-42 10/1194 50 U 73 50 U sou 32 J 250 U 50 U 140 11 J W-5s South Plume Shallow 32-42 4/30198 3.8J 83 J 3.1 J 2.4J 3.4J 25 UJ 5.0 UJ 140 DJ 13 J W-5s South Plume Shallow 32-42 12/17198 200 UJ 76 J 200 UJ 200UJ 400 UJ 1,000 UJ 200UJ 85J 200 UJ W-5sa South Plume Shallow 32-42 619199 100UD 72JD 100 UD 100UD 200 UD 500 UD 100 UD 94JD 100 UD W-5s Sou1h Plume Shallow 32-42 12/7199 100UD 73JD 100 UD 100UD 200UD 500 UD 100 UD 130D 100 UD W-5s Dup South Plume Shallow 32-42 12/17199 50UD 100D 50 UD 50 UD 100UD 250 UD 50UD 110D 10 JD W-5s South Plume Shallow 32-42 6/6/00 100 UD 64JD 100 UD 100 UD 200 UDJ 500 UD 100 UD 100 D 100 UD W-5i South Plume Intermediate 56-66 10/1194 10U 3J 10 U 10U 4J 50 U 10U 2J 10 U W-5i South Plume Intermediate 56-66 5/5/98 5.0UD 3.6DJ 5.0 UD 5.0 UD 10 UD 25UD 5.0UD 5.0 UD 5.0UD W-5i South Plume Intermediate 56-66 12/19/98 1.0U 4 1.0 U 1.0 U 2.0 UJ 5.0U 0.40J 1.0 U 1.0 U W-5i Sou1h Plume Intermediate 56-66 6/8199 2.0UD 4.6D 2.0 UD 2.0 UD 4.0UD 10UD 2.0 UD 2.0 UD 2.0UD W-5i South Plume Intermediate 56-66 12/8/99 5.0UD 7.2D 5.0 UD 5.0 UD 10 UD 25 UD 5.0 UD 5.0 UD 5.0UD W-5i South Plume Intermediate 56-66 6/9/00 5.0UD 11 D 5.0 UD 5.0 UD 10.0 UDJ 25UD 5.0UD 5.0 UD 5.0UD W-5I Dup South Plume Intermediate 56-66 6/9/00 5.0UD 11 D 5.0 UD 5.0 UD 10.0 UDJ 25UD 5.0 UD 5.0 UD 5.0UD W-6s Side Gradient Shallow 22-37 4/30198 W-6s Dup Side Gradient Shallow 22-37 4/30198 W-lli Side Gradient Intermediate 83-93 12/16/98 1.0U 0.07 J 0.1 J 5 2.0 U 5.0 U 0.9 JB 1.0U 1.0 U W-9s Treatment Shallow 34-49 5/5198 10 UD 10 UD 10 UD 10UD 20UD 50 UD 10 UD 10UD 10 UD W-9s Dup Treatment Shallow 34-49 5/5198 10UD 10 UD 10 UD 10UD 20UD 50 UD 10UD 10UD 10 UD W-9s Treatment Shallow 34-49 12/17/98 200 UD 200UD 200UD 200 UD 400 U 1,000 UD 200UD 200 UD 200 UD W-10i Side Gradienl Intermediate 59-69 10/1194 1.0U 1.0 U 1.0U 1.0U 2.0 U 5.0U 1.0 U 1.0U 1.0 U W-10i Side Gradient Intermediate 59-69 1/1/95 1.0U 1.0 U 1.0U 1.0U 2.0 U 5.0U 1.0 U 1.0U 1.0 U W-10i Side Gradient Intermediate 59-69 12/1/95 1.0 U 1.0 U 1.0U 1.0 U 2.0 U 5.0U 0.1 J 1.0U 1.0 U W-10i Side Gradient Intermediate 59-69 4/30/98 1.0U 1.0 U 1.0U 1.0U 4.1 5.0U 1.0 U 1.0U 1.0 U W-10i Side Gradient Intermediate 59-69 12/19/98 1.0U 1.0 U 1.0U 1.0U 2.0 UJ 5.0UJ 1.0 UJ 1.0U 1.0 U W-10i Side Gradient Intermediate 59-69 6/8199 1.0U 1.0 U 1.0U 1.0U 2.0 U 5.0U 1.0 U 1.0U 1.0 U W-10i Side Gradient Intermediate 59-69 12/9/99 1.0 U 1.0U 1.0 U 1.0U 2.0U 5.0 U 1.0 U 1.0U 1.0 U W-10i Side Gradient Intermediate 59-69 6/6/00 1.0 U 1.0 U 1.0 U 1.0 U 2.0 UJ 5.0 U 1.0 U 1.0 U 1.0U P :\Proj\60313.01 5~une-OO-to3 .xis Page 6 of 26 -------- --- --------Table 3. Data from Monitoring Wells Used for Evaluation of Monitored Natural Attenuation 10/27/00 FCX-Statesville Superfund Site OU3 Well lnfonnation Volatile Organic Compounds e Monitoring Screened Sampling 1,2-Dichloro-1, 1-Dichloro-1,2-0ichloro-Methylene 4-Methyl-2-Trichloro-Trichloro-Well Zone Well Type Depth Date ethane ethene ethene propane chloride pentanone Toluene ethane ethane (fl) (µg/l) (µg/l) (µg/l) (µg/l) (µg/l) (µg/l) (µgll) (µgll) (µg/l) W-11s Side Gradient Shallow 25-40 4/30/98 W-12s Background Shallow 18-33 10/1/94 1.0 U 1.0U 1.0U 1.0 U 1.0U 5.0U 1.0U 1.0U 1.0U W-12s Background Shallow 18-33 1/1/95 1.0 U 1.0U 1.0U 1.0 U 2.0 U 5.0 U 1.0U 1.0U 1.0U W-12s Background Shallow 18-33 4/30/98 1.0U 1.0U 1.0U 1.0 U 0.61 J 5.0 U 1.0U 1.0 U 1.0U W-12s Background Shallow 18-33 12/8/99 W-12i Background Intermediate 73-<13 10/1/94 1.0U 1.0U 1.0U 1.0U 1.0U 5.0 U 1.0U 1.0U 1.0U W-12i Background Intermediate 73-<13 1/1/95 1.0U 0.1 J 1.0U 1.0 U 2.0 U 5.0 U 1.0 U 1.0 U 1.0 U W-12i Background Intermediate 73-<13 4/30/98 1.0U 1.0U 1.0 U 1.0 U 2.0U 1.1 J 0.24J 1.0 U 1.0U W-12i Background Intermediate 73-<13 12/16/98 1.0 U 0.2 J 1.0 U 1.0U 2.0 U 5.0 U 1.0U 1.0U 1.0U W-12i Background Intermediate 73-<13 6f//99 1.0U 1.0 U 1.0 U 1.0 U 2.0 U 5.0 U 1.0U 1.0 U 1.0U W-12i Background Intermediate 73-<13 1219/99 1.0U 0.17 J 1.0U 1.0 U 2.0 U 5.0 U 1.0 U 1.0 U 1.0U W-12i Background Intermediate 73-83 6(//00 1.0 U 1.0U 1.0 U 1.0 U 2.0 UJ 5.0 U 1.0 U 1.0 U 1.0U W-16s Treatment Shallow 35-50 5/5/98 W-16s Treatment Shallow 35-50 12/17/98 200 UD 200UD 200UD 200 UD 400UD 1,000 UD 200UD 200 UD 200UD W-16i Treatment Intermediate 77-<17 5/5/98 W-16i Treatment Intermediate 77-<17 12/17/98 0.9 OJ 0.4 OJ 2.0UD 20 D 4.0UJ 10 UD 2.0 U 2.0UO 2.0 uo W-17s Source Shallow 29.5-44.5 10/1/94 4,000 U 4,000 U 4,000 U 4,000 U 8,000 U 20,000 U 4,000 U 4,000 U 4,000 U W-17s Source Shallow 29.5-44.5 1/1/95 4,000 U 4,000 U 4,000 U 4,000 U 8,000 U 20,000 U 4,000 U 4,000 U 4,000 U W-17s Source Shallow 29.5-44.5 5/5/98 250 UD 250UD 250UD 57DJ 500UD 1,200 UD 250UD 250 UD 250 UD W-17s Source Shallow 29.5-44.5 12/18/98 10,000 UD 10,000 U 10,000 UD 10,000 UD 20,000 UJ 50,000 UJ 10,000 UD 10,000 UD 10,000 UD W-17s' Source Shallow 29.5-44.5 12/9/99 5,000 UD 5,000 UD 5,000 UD 5,000 uo 10,000 UD 25,000 uo 5,000 UD 5,000 UD 5,000 uo W-17s Source Shallow 29.5-44.5 6/6/00 10,000 UD 10,000 UD 10,000 UD 10,000 UD 20,000 UDJ 50,000 UD 10,000 UD 10,000 UD 10,000 UD W-18s Background Shallow 22.5-37.5 12/1/95 1 U 1.0U 1.0 U 1.0 U 2.0 U 5.0 U 0.1 J 1.0 U 1.0 U W-18s Background Shallow 22.5-37.5 4/30/98 1.0U 1.0 U 1.0U 1.0U 3.4 5.0 U 1.0U 1.0U 1.0 U W-18s Background Shallow 22.5-37.5 12/16/98 1.0U 1.0U 1.0U 10U 2.0U 5.0 U 1.0U 1.0U 1.0U W-18s Background Shallow 22.5-37.5 6/8/99 1.0 U 1.0U 1.0 U 1.0U 2.0 U 5.0 U 1.0 U 1.0U 1.0U W-18s Background Shallow 22.5-37.5 12/6/99 1.0 U 1.0U 1.0U 1.0 U 2.0 U 5.0 U 1.0U 1.0U 1.0 U W-18s Background Shallow 22.5-37.5 6/6/00 1.0 U 1.0 U 1.0 U 1.0 U 2.0 UJ 5.0 U 1.0U 1.0 U 1.0 U P:\Pro j\60313.015\june-00-t0J.xls Page 7 of 26 ---111!!!!1 ----.. ---liiii.i •· -_., ------Table 3. Data from Monitoring Wells Used for Evaluation of Monitored Natural Attenuation 10/27/00 FCX-Statesville Superfund Site OU3 Well Information Volatile Organic Compounds e ans-, - Monitoring Screened Sampling 1,2-0ichloro-1, 1-0ichloro-Dichiaro-1,2-Dichloro-Methylene 4-Methyl-2-Trichloro-Trichloro- Well Zone Well Type Depth Date ethane ethene ethene propane chloride pentanone Toluene ethane ethane (ft) (µgll) (µg/L) (µgll) (µgll) (µgll) (µgll) (µgll) (µgll) (µgll) W-19s North Plume Shallow 17-27 12/1/95 2.0 U 2.0U 2.0 U 2.0 U 2U 10 U 2.0 U 2.0U 2.0 U W-19s North Plume Shallow 17-27 5/5/98 2.5 UD 2.5UD 2.5 UD 2.5UD 5.0 UD 12 UD 2.5 UD 2.5 UD 2.5 UD W-19s North Plume Shallow 17-27 12/17/98 1.0 U 0.3J 0.05J 1 2.0 U 5.0 U 1.0U 1.0 U 1.0 u W-19s North Plume Shallow 17-27 6/10199 20 UD 20 UD 20 UD 20 UD 40 UD 100 UD 20 UD 20 UD 20UD W-19s North Plume Shallow 17-27 1217199 20 UD 20UD 20 UD 20UD 40UD 100 UD 20UD 20UD 20 UD W-19s North Plume Shallow 17-27 6/6/00 5.0UD 5.0 UD 5.0UD 1.6 JD 10.0 UDJ 25UD 5.0UD 5.0 UD 5.0 UD W-20s North Plume Shallow 4-14 12/1195 1.0U 1.0U 1.0 U 1.0 U 2.0 U 5.0 U 1.0U 1.0 U 1.0 u W-20s North Plume Shallow 4-14 4/29198 1.0 U 1.0U 1.0U 0.28 J 2.0 U 5.0 U 1.0U 1.0U 1.0 u W-20s Dup North Plume Shallow 4-14 4/29198 1.0 U 1.0U 1.0U 0.26 J 2.0 U 5.0 U 1.0 U 1.0U 1.0U W-20s North Plume Shallow 4-14 12/20198 1.0 U 1.0 U 1.0 U 0.4J 2.0 UJ 5.0 U 1.0 U 1 UD 1.0 U W-20s North Plume Shallow 4-14 6/8199 2.0 UD 2.0 UD 2.0 UD 0.58 JD 4.0UD 10UD 2.0UD 2.0UD 2.0UD W-20s North Plume Shallow 4-14 12/7199 2.0UD 2.0 UD 2.0 UD 1.3JD 4.0UD 10UD 2.0UD 2.0UD 2.0UD W-20s Dup North Plume Shallow 4-14 12/7199 2.0 UD 2.0 UD 2.0 UD 1.2 JD 4.0UD 10UD 2.0 UD 2.0UD 2.0 UD W-20s North Plume Shallow 4-14 6/8/00 5.0 UD 5.0 UD 5.0 UD 5.0 UD 10.0 UDJ 25 UD 5.0UD 5.0UD 5.0 UD W-20s Dup North Plume Shallow 4-14 6/8/00 1.0 U 1.0 U 1.0 U 0.53J 2.0 UJ 5.0 U 1.0 U 1.0 U 1.0U W-20i North Plume Intermediate 84-94 3/1196 20 U 20U 20 U 20 U 40U 100 U 20 U 20U 20U W-20i North Plume Intermediate 84-94 4/29198 2.0 UJ 0.4 J 2.0 UJ 8.6 J 4 UJ 1.4 J 2.0 UJ 2.0 UJ 2.0 UJ W-20i North Plume Intermediate 84-94 12/15198 50 UD 50 UD 50 UD 48 DJ 100 U 250 UD 50 U 50UD 50 UD W-20i North Plume Intermediate 84-94 1/26/99 1.0 U 0.6 J 0.2 J 16 2.0 U 5.0 U 1.0U 1.0U 1.0 U W-20i North Plume Intermediate 84-94 1/27199 20 U 20 UD 20 UD 15 JD 40 U 100 UD 20UD 20 U 20 U W-20i North Plume Intermediate 84-94 6/8199 50UD 50 UD 50UD 13 JD 100UD 250 UD 50UD 50UD 50 UD W-20i North Plume Intermediate 84-94 12/7199 50UD 50UD 50 UD 11 JD 100UD 250 UD 50UD 50 UD 50UD W-20i North Plume Intermediate 84-94 6/8/00 1.0 U 0.34J 1.0 U 12 2.0 UJ 5.0 U 1.0 U 1.0 U 1.0 U W-20d' North Plume Deep 152-166 9/23198 1.0U 1.0 U 1.0 U 2.8 0.58 J 5.0 U 0.88J 1.0U 12.0 U W-20d North Plume Deep 152-166 12/17198 1.0 U 0.03J 3 1 2.0 U 0.4 J 0.7 J 1.0U 1.0U W-20d North Plume Deep 152-166 619199 1.0U 1.0U 1.0 U 0.61 J 2.0 U 5.0 U 0.10 J 1.0 U 1.0U W-20d North Plume Deep 152-166 1219199 1.0U 1.0 U 1.0U 0.95 J 2.0U 5.0 U 1.0U 1.0 U 1.0U W-20d North Plume Deep 152-166 619/00 1.0 U 1.0 U 1.0 U 0.63J 2.0 UJ 5.0 U 1.0 U 1.0 U 1.0 U W-22s South Plume Shallow 20-35 12/1195 1.0U 1.0 U 1.0 U 1.0U 2.0 U 5.0U 1.0U 1.0U 1.0 U W-22s South Plume Shallow 20-35 5/1198 1.0U 1.0 u 1.0U 1.0U 3.7 5.0U 1.0U 0.88J 1.0U W-22s South Plume Shallow 20-35 12/20198 1.0 U 1.0 U 1.0U 1.0U 2.0UJ 5.0 UJ 1.0U 0.6J 1.0 U W-22s' South Plume Shallow 20-35 ' 12/8199 1.0U 1.3 1.0U 1.0 U 2.0 U 5.0 U 1.0U 0.78 J 1.0U W-22s South Plume Shallow 20-35 617/00 1.0 U 0.71 J 1.0 U 1.0 U 2.0 UJ 5.0 U 1.0 U 1.0 U 1.0 U P:\Proj\60313.015\june-0O-t03.xls Page 8 of 26 -..,,, ---:· -_, ---•iif• .. -; -· liill: , __ ---.. Table 3. Data from Monitoring Wells Used for Evaluation of Monitored Natural Attenuation 10/27/00 FCX-Statesville Superfund Site OU3 Well Information Volatile Organic Compounds e Monitoring Screened Sampling 1,2-Dichloro-1, 1-Dichloro-1,2-Dichloro-Methylene 4-Methyl-2-Trichloro-Trichloro- Well Zone Well Type Depth Date ethane ethene ethene propane chloride pentanone Toluene ethane ethane (ft) (µg/1.) (µg/1.) (µg/1.) (µg/1.) (µg/1.) (µg/1.) (µg/1.) (µg/1.) (µg/1.) W-22i South Plume Intermediate 57-87 3/1/96 10 U 10U 10 U 10U 20 U 50 U 10 U 12 10 U W-22i South Plume lntenmediate 57-67 5/1/98 1.0 U 20 0.46J 1.0U 2.0 U 5.0 U 1.0U 11 0.31 J W-22i South Plume lntenmediate 57-87 12/20/98 10UD 20 D 0.4 JD 10 UD 20UJ 50UD 10 UD 12 D 10UD W-22i South Plume lntenmediate 57-87 6/9/99 10UD 11 D 10UD 10 UD 20UD 50UD 10 UD 10UD 10 UD W-22i South Plume Intermediate 57-87 12/8/99 10UD 10 UD 10UD 10 UD 20 UD 50UD 10 UD 5.4JD 10 UD W-22i Dup South Plume Intermediate 57-87 12/8/99 10 UD 7.3 JD 10 UD 10 UD 20UD 50 UD 10 UD 5.0JD 10 UD W-24s South Plume Shallow 5-20 12/1195 1.0 U 0.2 J 1.0U 1.0 U 1.0 U 5.0 U 0.1 J 1.0U 1.0 U W-24s South Plume Shallow 5-20 5/1/98 1.0 U 1.0U 1.0U 1.0 U 2.0 U 5.0 U 1.0U 1.0U 1.0U W-24s South Plume Shallow 5-20 1/27199 1.0 U 0.1 J 1.0U 1.0 U 2.0 U 5.0 U 1.0 J 1.0 U 1.0 U W-24s Dup South Plume Shallow 5-20 1/27/99 1.0 U □.OBJ 1.0U 1.0 U 2.0 U 5.0 U 1.0 U 1.0 U 1.0U W-24s South Plume Shallow 5-20 6/9/99 1.0U 1.0U 1.0 U 1.0 U 2.0 U 5.0 U 1.0U 1.0 U 1.0U W-24s South Plume Shallow 5-20 12/8/99 1.0U 0.21 J 1.0 U 1.0U 2.0 U 5.0U 1.0U 1.0U 1.0U W-24s South Plume Shallow 5-20 6/7/00 1.0 U 1.0 U 1.0 U 1.0 U 2.0 UJ 5.0 U 1.0 U 1.0 U 1.0 U W-26i Side Gradient lntenmediate 103-118 12/16/98 1.0 U 1.0 U 1.0U 1.0 U 2.0 U 0.5J 0.6 J 1.0U 1.0U W-28i North Plume lntenmediate 73-SB 12/1195 10 U BJ 10 U 10 U 20 U 50 U 10U 10 U 10 U W-28i North Plume Intermediate 73-aB 5/5198 10 UD 2.9 DJ 10 UD 10UD 20UD 50UD 10UD 10 UD 10 UD W-28i North Plume Intermediate 73-SB 12/18/98 10 UD 14D 10 UD 0.8 JD 20 U 50 UD 10U 10 UD 10 UD W-28i North Plume Intermediate 73-SB 6/8/99 50 UD 50 UD 50 UD 50 UD 100 UD 250 UD 50 UD 50 UD 50 UD W-28i North Plume Intermediate 73-88 12/7199 50 UD 50 UD 50 UD 50UD 100 UD 250UD 50 UD 50UD 50UD W-28i North Plume Intermediate 73-88 6/6/00 5.0 uo 7.0 D 5.0 UD 5.0 UD 10.0 UDJ 25UD 5.0 UD 5.0UD 5.0 UD W-29i South Plume Intermediate 88-98 12/1195 1.0 U 3 1.0 U 1.0U 2.0 U 5.0 U 1.0U 0.5 J 1.0 U W-29i South Plume Intermediate 88-98 5/1/98 2.5 UD 4.4 D 2.5UD 2.5UD 5.0 UD 12 UD 2.5UD 2.5 UD 2.5 UD W-29i South Plume Intermediate 88-98 12/20/98 2.0UD 3D 2.0UD 2.0UD 4.0 UJ 10UD 2.0UD 2.0 UD 2.0 UD W-29i Dup South Plume Intermediate 88-98 12/20/98 2.0UD 4D 2.0UD 2.0UD 4.0 UJ 10UD 2.0UD 2.0UD 2.0 UD W-29i South Plume lntenmediate 88-98 6/9/99 2.0UD 4.4 D 2.0UD 2.0UD 4.0UD 10UD 2.0UD 2.0 UD 2.0 UD W-29i Dup South Plume Intermediate 88-98 6/9/99 2.0UD 4.4 D 2.0 UD 2.0UD 4.0 UD 10 UD 2.0UD 2.0UD 2.0 UD W-29i South Plume Intermediate 88-98 12/9/99 5.0 UD 3.8 JD 5.0 UD 5.0UD 10 UD 25 UD 5.0UD 5.0 UD 5.0 UD W-29i Dup South Plume Intermediate 88-98 12/9/99 5.0 UD 4.3 JD 5.0UD 5.0UD 10UD 25UD 5.0UD 5.0UD 5.0 UD W-29i South Plume Intermediate 88-98 6/7/00 5.0 UD 4.0JD 5.0UD 5.0 UD 10.0 UDJ 25 UD 5.0 UD 5.0UD 5.0UD W-29i Dup South Plume Intermediate 88-98 6/7/00 1.0 uo 5.9 1.0 UD 1.0 UD 2.0 UJ 5.0 U 1.0 U 0.73J 1.0 U P:\Proj\60313. 0 1 5~une-0O-t03.xls Page 9 of 26 -Iii&' 11111 -.. --... .. -~ .. , ... -· -; ,_ 1111> ---Table 3. Data from Monitoring Wells Used for Evaluation of Mo:iitored Natural Attenuation 10/27/00 FCX-Statesville Superfund Site OU3 Well Information Volatile Organic Compounds e ans-, - Monitoring Screened Sampling 1,2-Dichloro-1, 1-0ichloro-Dichiaro-1,2-0ichloro-Methylene 4-Methyl-2-Trichloro-Trichloro- Well Zone Well Type Depth Date ethane ethene ethene propane chloride pentanone Toluene ethane ethane (ft) (µg/L) (µg/L) (µg/L) (µg/L) (µg/L) (µg/L) (µg/L) (µg/L) (µg/L) W-30i North Plume lntennediate 37.5-47.5 12/1195 50U 50U 50 U 50 U 100U 250 U 50U 50 U 50 U W-30i North Plume lntennediate 37.5-47.5 4/30198 2.5 UD 1.1 DJ 0.38 DJ 5.3 D 12 D 12UD 0.46 DJ 2.5 UD 2.5UD W-30i North Plume lntennediate 37.5-47.5 12/19198 20 UD 20 U 20 UD 5 DJ 40 U 100 UD 20U 20UD 20UD W-30i North Plume lntennediate 37.5-47.5 1126199 1.0 U 3 0.1 J 5 2.0 U 5.0U 0.1 J 1.0 U 0.2 J W-30i North Plume Intermediate 37.5-47.5 1127199 50UD 50UD 50UD 50UD 100 U 250 UD 50 UD 50 UD 50UD W-30i North Plume Intermediate 37.5-47.5 619199 50 UD 50 UD 50 UD 50UD 100 UD 250UD 50 UD 50 UD 50 UD W-30i North Plume Intermediate 37.5-47.5 12/8199 100 UD 100 UD 100UD 100 UD 200UD 500 UD 100 UD 100 UD 100UD W-301 North Plume Intermediate 37.5-47.5 617/00 5.0 UD 2.1 JD 5.0 UD 4.4JD 10.0 UDJ 25 UD 5.0UD 5.0 UD 5.0UD W-31s North Plume Shallow 5-15 11/1198 1.0 U 1.0U 1.0 U 1.0 U 2.0 U 5.0U 0.06J 1.0 U 1.0U W-31s North Plume Shallow 5-15 11/19198 1.0 U 1.0U 1.0U 1.0 U 2.0 U 5.0 U 0.068 J 1.0U 1.0U W-31s Dup North Plume Shallow 5-15 11/19198 1.0 U 1.0U 1.0U 1.0U 2.0 U 5.0 U 1.0U 1.0 U 1.0U W-31s North Plume Shallow 5-15 12/16198 1.0U 1.0 U 1.0U 1.0 U 2.0U 5.0U 1.0 U 1.0U 1.0U W-31s' North Plume Shallow 5-15 6fl/99 1.0U 1.0U 1.0U 1.0U 2.0 U 5.0U 1.0 U 1.0 U 1.0U W-31sc North Plume Shallow 5-15 6110199 1.0 U 1.0U 1.0U 1.0 U 2.0 U 5.0U 1.0 U 1.0U 1.0 U W-31s North Plume Shallow 5-15 12/6199 1.0U 1.0 U 1.0U 1.0U 2.0 U 5.0U 1.0U 1.0 U 1.0U W-31s Dup North Plume Shallow 5-15 12/16199 1.0 U 1.0U 1.0U 1.0U 2.0 U 5.0U 1.0U 1.0 U 1.0U W-31s North Plume Shallow 5-15 6/5/00 1.0U 1.0 U 1.0 U 1.0 U 2.0 UJ 5.0 U 1.0 U 1.0U 1.0 U W-31i North Plume Intermediate 34-44 1111198 1.0 U 1.0 U 1.0U 1.0 U 2.0 5.0U 1.0 U 1.0 U 1.0U W-31i North Plume Intermediate 34-44 11119198 1.0U 1.0 U 1.0U 1.0 U 2.0 J 5.0U 1.0U 1.0 U 1.0U W-31i North Plume Intermediate 34-44 12/16198 1.0 U 1.0 U 1.0U 1.0 U 2.0 U 5.0U 1.0U 1.0U 1.0U W-31i North Plume lntennediate 34-44 6fl/99 1.0U 1.0 U 1.0U 1.0U 2.0U 5.0U 1.0U 1.0 U 1.0U W-311 North Plume Intermediate 34-44 12/6199 1.0 U 1.0 U 1.0 U 1.0 U 2.0 U 5.0 U 1.0 U 1.0 U 1.0 U W-31i North Plume Intermediate 34-44 615/00 1.0 U 1.0 U 1.0 U 1.0 U 2.0 UJ 5.0 U 1.0 U 1.0U 1.0U W-32i South Plume Intermediate 112-132 11/1198 1.0 U 1.0U 1.0U 1.0 U 2.0 U 5.0 U 0.24 J 1.0U 1.0U W-32i South Plume lntennediate 112-132 11119198 1.0 U 1.0 U 1.0U 1.0 U 2.0 U 5.0 U 0.24 J 1.0U 1.0U W-32i South Plume lntennediate 112-132 12/18198 1.0 U 1.0 U 1.0U 1.0 U 2.0 UJ 5.0 UJ 1.0 U 1.0 U 1.0U W-321 South Plume Intermediate 112-132 619199 1.0U 1.0 U 10U 1.0U 2.0 U 5.0 U 1.0U 1.0 U 1.0 U W-32i South Plume Intermediate 112-132 12/7199 1.0 U 1.0 U 1.0U 1.0U 2.0 U 5.0U 1.0 U 1.0 U 1.0U W-32i South Plume Intermediate 112-132 618100 1.0 U 1.0 U 1.0 U 1.0U 2.0 UJ 5.0 U 1.0 U 1.0 U 1.0 U P:\Proj\60313. o 1 S\june-OO-to3.xls Page 10 of 26 -· ---· .... -..,, .. liill /-.., --· -,' -.. ---Table 3. Data from Monitoring Wells Used for Evaluation of Monitored Natural Attenuation 10/27/00 FCX-Statesville Superfund Site OU3 Well Information Electron Acceptors e Monitoring Screened Sampling Manganese Manganese Well Zone Well Type Depth Date Aluminumd DO Nitrate/ Nitrite (total) (II) Iron (total) Iron (II) Sulfate Sulfide H2S (ft) (mg/L) (ppm) (mg/L) (mg/L) (ppm) (mg/L) (ppm) (mg/L) (mg/L) (mg/L) W-1s Side Gradient Shallow 38-48 12/19/98 4.5 0.58 0.749 u 1.810 0.5 u W-5s South Plume Shallow 32-42 4/1/94 W-5s South Plume Shallow 32-42 10/1/94 W-5s South Plume Shallow 32-42 4/30/98 0.2 1.2 1.12 u 2.93 u u u W-5s South Plume Shallow 32-42 12/17/98 1.9 1.430 11.100 u u w.ss• South Plume Shallow 32-42 6/9/99 34.9 1.0 2.3 2.43 0.4 36.1 0.3 1.8 0 W-5s South Plume Shallow 32-42 12/7/99 7.350 1 2.6 1.710 0.3 7.710 1.6 2.3 0 W-5s Dup South Plume Shallow 32-42 12/17/99 2.0 1.6 13.0 u W-5s South Plume Shallow 32-42 6/6/00 0.894 J 3,2 1.56 J 0.3 0.879 0,5 1.6 0 W-5i South Plume Intermediate 56-66 10/1/94 W-5i South Plume Intermediate 56-66 5/5/98 2.0 u 0.0467 u 1.02 1.1 22 u W-5i South Plume lntennediate 56-66 12/19/98 u 0.011 B u 0.0706 B 0.2 u W-5i South Plume Intermediate 56-66 6/8/99 0.746 2.0 u 0.0406 0 0.595 0.4 19 0 W-5i South Plume lntennediate 56-66 12/8/99 10.400 1.5 0.26 0.101 0 5.990 2.5 18 0 W-5i South Plume Intermediate 56-66 6/9/00 1.95 1 0.32 0.0559 0 1.36 18 0 W-5i □ up South Plume Intermediate 56-66 6/9/00 2.01 <0,25 0,059 0 1.38 17 0 W-6s Side Gradient Shallow 22-37 4/30/98 0.173 5.16 W-6s Dup Side Gradient Shallow 22-37 4/30/98 0.184 5.44 W-6i Side Gradient Intermediate 83-93 12/16/98 1,0 u 0.0331 u 4.380 0.2 63 u W-9s Treatment Shallow 34-49 5/5/98 1.3 0.0365 1.08 u W-9s Dup Treatment Shallow 34-49 5/5/98 1.3 0.0529 2.43 u W-9s Treatment Shallow 34-49 12/17/98 1.8 0.535 35.6 u W-10i Side Gradient lntennediate 59-69 10/1/94 W-10i Side Gradient lntennediate 59-69 1/1/95 W-10i Side Gradient lntennediate 59-69 12/1/95 W-10i Side Gradient lntennediate 59-69 4/30/98 0.6 u 0.0022 B u 0.0361 B u 4.3 0.1 W-101 Side Gradient Intermediate 59-69 12/19/98 2.0 0.31 0.0044 B u 0.111 0.2 u W-10i Side Gradient Intermediate 59-69 6/8/99 0.128 B 2.0 u 0.0019 B 0 0.0434 B 0.1 3.3 0.1 W-10i Side Gradient Intermediate 59-69 12/9/99 0.271 u 0.0051 0 0.0974 0.3 5.3 0 W-101 Side Gradient Intermediate 59-69 6/6/00 0,368 J 0,31 0.0064 BJ 0 0.148 0,5 7,2 0,1 P:\Proj\60313. O 1 5\june-OO-t03 .xis Page 11 of 26 -------·all! ------·--I-----.. Table 3. Data from Monitoring Wells Used for Evaluation of Monitored Natural Attenuation 10/27/00 FCX-Statesville Superfund Site OU3 Well lnfonnation Electron Acceptors e Monitoring Screened Sampling Manganese Manganese Well Zone Well Type Depth Dale Aluminumd DO Nitrate/ Nitrite (total) (II) Iron (total) Iron (II) Sulfate Sulfide H2S (fl) (mg/L) (ppm) (mg/L) (mg/L) (ppm) (mg/L) (ppm) (mg/L) (mg/L) (mg/L) W-11s Side Gradient Shallow 25-40 4/30/98 0.0839 2.17 W-12s Background Shallow 18-33 10/1/94 W-12s Background Shallow 18-33 1/1/95 W-12s Background Shallow 18-33 4/30/98 7.0 1.7 0.0357 u 2.37 0.25 5.8 u W-12s Background Shallow 18-33 1218/99 W-12i Background lntennediate 73-83 10/1/94 W-12i Background Intermediate 73-83 1/1/95 W-12i Background Intermediate 73-83 4/30/98 4.0 2.7 0.0056 B u 0.042 B u 38 u W-12i Background Intermediate 73-83 12116/98 3.5 3.1 0.0041 B u 0.0213 B 0.1 46 W-12i Background Intermediate 73-83 6fl/99 0.0247 U 3.0 3.3 0.0054 B 0 0.017 U 0 u 0 W-12i Background Intermediate 73-83 1219/99 1.250 4 2.9 0.0293 0.1 1.890 0.3 32 0 W-12i Background Intermediate 73,83 6fl/00 0.503 J 3 <0.25 0,029 J 0 0.88 0.25 11 0.7 W-16s Treatment Shallow 35-50 5/5/98 0.0413 0.721 W-16s Treatment Shallow 35-50 12117/98 W-16i Treatment lntenmediate 77-87 5/5/98 0.001 U 0.157 W-16i Treatment Intermediate 77-87 12117/98 ---- - -W-17s §,o~r~ Shallow 29.5-44.5 10/1/94 W-17s Source Shallow 29.5-44.5 1/1/95 W-17s Source Shallow 29.5-44.5 5/5/98 5.0 24 0.494 u• 1.7 0.2 u u W-17s Source Shallow 29.5-44.5 12118/98 4.0 27 0.699 0.3 5.1 0.8 u W-17s' Source Shallow 29.5-44.5 1219/99 5.450 0.707 1.000 W-17s Source Shallow 29.5-44,5 6/6/00 W-18s Background Shallow 22.5-37.5 1211/95 W-18s Background Shallow 22.5-37.5 4/30/98 6.0 0.43 0.0332 u 1.12 0.2 u u W-18s Background Shallow 22.5-37.5 12116/98 u 0.285 14.300 u W-18s Background Shallow 22.5-37.5 6/8/99 37.4 3.0 0.47 0.530 0 28.4 0.2 1.8 0 W-18s Background Shallow 22.5-37.5 1216/99 0.444 3 0.32 0.0211 0 0.231 0.4 1.3 0 W-18s Background Shallow 22.5-37,5 6/6/00 0,379 3 0,40 0.0191 J 0 0.229 0,2 1.6 0 P :\Proj\60313. O 15\ju ne-OCH03.xls Page 12 of 26 -· 1111; --.. --illit .. --... ·-· -,.., till: -· --Table 3. Data from Monitoring Wells Used for Evaluation of Monitored Natural Attenuation 10127100 FCX-Statesville Superfund Site OU3 Well Information Electron Acceptors e Monitoring Screened Sampling Manganese Manganese Well Zone Well Type Depth Date Aluminumd DO Nitrate/ Nitrite (total) (II) Iron (total) Iron (11) Su~ate Sulfide H,S (ft) (mg/I.) (ppm) (mg/I.) (mg/I.) (ppm) (mg/I.) (ppm) (mg/I.) (mg/I.) (mg/I.) W-19s North Plume Shallow 17-27 1211"35 W-19s North Plume Shallow 17-27 515"38 5.0 0.45 0.0364 u 1.67 0.2 47 u W-19s North Plume Shallow 17-27 12117"38 0.0744 3.260 31 W-19s North Plume Shallow 17-27 6/10199 0.795 4.0 0.83 0.0414 0.758 0.4 25 0 W-19s North Plume Shallow 17-27 1217199 0.0376 2 12 0.0337 0 0.0156 0.1 17 0 W-19s North Plume Shallow 17-27 616/00 0.0855 BJ 0.94 0.0403 J 0 0.042 B 0.2 19 0 W-20s North Plume Shallow 4-14 1211195 W-20s North Plume Shallow 4-14 4/29198 8.0 u 0.0004 B u 0.0123 U u u u W-20s Dup North Plume Shallow 4-14 4/29198 u 0.0076 B 0.357 u W-20s North Plume Shallow 4-14 12120"38 4.0 0.21 0.016 B u 0.844 0.2 u W-20s North Plume Shallow 4-14 618199 0.593 3.5 u 0.0107 B 0 0.730 0.2 u 0 W-20s North Plume Shallow 4-14 1217199 0.0282 5 0.37 0.001 0.1 0.0389 0.1 1.3 0 W-20s Dup North Plume Shallow 4-14 1217199 0.0217 u 0.00044 0.0161 1.3 W-20s North Plume Shallow 4-14 6/8/00 0.0685 BJ 3 <0.25 0.0011 BJ 0 0.0419 B 0.2 1.1 0 W-20s Dup North Plume Shallow 4-14 6/8100 0.0701 BJ 3 <0.25 0.00097 BJ 0 0.0406 B 0.2 1.1 0 W-20i North Plume Intermediate 84-94 3/1196 W-20i North Plume Intermediate 84-94 4/29198 2.0 0.32 0.0016 B u 0.0181 B u 6.8 u W-20i North Plume Intermediate 84-94 12115198 1.0 0.067 0.0013 B u 0.0745 B u 13 u W-20i North Plume Intermediate 84-94 1/26199 W-20i North Plume Intermediate 84-94 1/27,'39 W-20i . North Plume Intermediate -84-94 6/8199. 0.0247 U 1.1 0.48 0.003 u-0 o.011u· 0:1 -9.8 0 W-20i North Plume Intermediate 84-94 1217"39 0.0604 0.8 0.71 0.0011 0 0.0156 0.1 13 0 W-20i North Plume Intermediate 84-94 6/8/00 0.0737 BJ 0.8 <0.25 0.0043 BJ 0 0.103 0.2 13 0.1 W-20d' North Plume Deep 152-166 9/23198 W-20d North Plume Deep 152-166 12117198 0.5 0.00024 B u 0.012 B u 22 u W-20d North Plume Deep 152-166 619199 0.423 0.2 u 0.0028 B 0 0.147 0 11 0 W-20d North Plume Deep 152-166 12,'3/99 0.137 0.6 u 0.0016 0 0.0282 0 9.2 0 W-20d North Plume Deep 152-166 6/9/00 0.22 0.05 <0.25 0.0011 B 0 0.0134 U 0 9.1 0.5 W-22s South Plume Shallow 20-35 1211195 W-22s South Plume Shallow 20-35 5/1198 7.0 9.5 0.523 0.3 1.82 1.2 1.3 u W-22s South Plume Shallow 20-35 12120198 4.5 9 0.645 0.2 5.340 2.2 u W-22s' Soulh Plume Shallow 20-35 1218199 12.200 5.9 0.997 13.700 1.3 W-22s South Plume Shallow 20-35 6/7/00 31 J 6.9 1.92J 38.6 1.6 P :\Proj\60313.015\june.0O-t03.xls Page 13 of26 -· .., ----· .. -----.. --· -.. --Table 3. Data from Monitoring Wells Used for Evaluation of Monitored Natural Attenuation 10/27/00 FCX-Statesville Superfund Site OUJ Well Information Electron Acceptors e Monitoring Screened Sampling Manganese Manganese Well Zone Well Type Deplh Date Aluminumd DO Nitrate/ Nitrite (lotal) (II) Iron (total) Iron (II) Su~ate Sulfide H,S (ft) (mg/L) (ppm) (mg/L) (mg/L) (ppm) (mg/L) (ppm) (mg/L) (mg/L) (mg/L) W-22i Soulh Plume lntenmediate 57-67 3/1196 W-22i Soulh Plume lntennediate 57-67 5/1198 2.0 4.2 0.0464 u 1.26 0.95 u u W-22i Soulh Plume Intermediate 57-67 12/20198 1.0 4 0.0222 u 1.320 1.9 u W-22i Soulh Plume lntenmediate 57-67 619199 0.0247 U 0.8 2.9 0.070 0 1.08 1.6 1.3 0 W-22i Soulh Plume lntenmediate 57-67 12/8199 0.0213 1 3.2 0.0316 0 2.130 3.1 2.8 0 W-22i Dup Soulh Plume Intermediate 57-67 12/8199 0.0165 3.3 0.0296 1.950 2.8 W-24s Soulh Plume Shallow 5-20 12/1195 W-24s South Plume Shallow 5-20 5/1198 0.25 2.59 65.7 18 W-24s Soulh Plume Shallow 5-20 1/27199 0.9 0.60 1.78 J 0.1 55.8 J 1.2 3.3 u W-24s Dup Soulh Plume Shallow 5-20 1/27199 W-24s Soulh Plume Shallow 5-20 619199 81.3 2.0 u 1.47 0.3 80.8 2.0 u 0 W-24s South Plume Shallow 5-20 12/8199 18.000 0.55 0.573 0.1 16.500 1.5 u 0 W-24s South Plume Shallow 5-20 617/00 42,2J 3 <0,25 1.26J 0.3 34.5 3 100 0.1 W-26i Side Gradient Intermediate 103-118 12/16198 3.5 2 0.0174 u 0.0234 B u 11 u W-28i North Plume Intermediate 73-88 12/1195 W-28i North Plume Intermediate 73-88 5/5198 2.5 0.14 0.0086 B u 0.573 u 42 u W-28i North Plume Intermediate 73-68 12/18198 2.5 0.52 0.0071 B u 0.433 0.1 24 u W-28i North Plume Intermediate 73-68 6/8199 0.813 0.5 u 0.0401 0 0.695 0 29 0 W-28i North Plume Intermediate 73-88 12/7199 0.556 0.8 0.44 0.0043 0 0.233 0 14 0 W-28i North Plume Intermediate 73-88 6/6/00 0.766 J . 0.3 -0.32 0.0034 BJ-o-0.234 0 12 0 W-29i Soulh Plume Intermediate 88-98 12/1195 W-29i Soulh Plume Intermediate 88-98 5/1198 5.0 8.5 0.0274 u 0.0123 U u u u W-29i Soulh Plume Intermediate 88-98 12/20198 4.0 7.5 0.0256 u 5.7 U u u W-29i Dup Soulh Plume Intermediate 88-98 12/20198 4.5 7.4 0.0001 u 0.026 u u W-29i Soulh Plume Intermediate 88-98 619199 0.0247 U 4.0 5.8 0.0190 0 0.0170 U 0.1 u 0 W-29i Dup Sou1h Plume Intermediate 88-98 619199 0.0247 U 4.0 5.7 0.0194 0 0.0170 U 0.1 u 0 W-29i Soulh Plume lntenmediate 88-98 12/9199 0.0260 3 6.0 0.0257 0 0.0156 0.1 2.3 0.1 W-29i Dup Soulh Plume lntenmediate 88-98 12/9199 0.0367 6.8 0.0265 0.0224 1.8 W-291 South Plume lntennediate 88-98 6/7/00 0.0654 J 3 6.8 0.0288 J 0 0.0138 B 0.2 1.6 0 W-29iDup South Plume Intermediate 88-98 617/00 0.0625 J 3 7.1 0.0285 J 0 0.0266 B 0.2 1.1 0 P:\Proj\60313.015\June--00-t03 .xis Page 14 of 26 -..., ., _, -llil, -.. ----:ial -----·-Table 3. Data from Monitoring Wells Used for Evaluation of Monitored Natural Attenuation 10/27/00 FCX-Statesville Superfund Site OU3 Well Information Electron Acceptors e Monitoring Screened Sampling Manganese Manganese Well Zone Well Type Depth Date Aluminumd DO Nitrate/ Nitrite (total) (II) Iron (total) Iron (II) Sulfate Sulfide H2S (ft) (mg/I.) (ppm) (mg/I.) (mg/I.) (ppm) (mg/I.) (ppm) (mg/I.) (mg/I.) (mg/I.) W-30i North Plume lntennediate 37.5-47.5 12/1195 W-30i North Plume Intermediate 37.5-47.5 4/30198 1.8 u 0.023 u 1.59 0.7 35 5 W-30i North Plume Intermediate 37.5-47.5 12/19198 0.3 u 0.0784 0.1 3.030 0.7 0.3 W-30i North Plume Intermediate 37.5-47.5 1/26199 W-30i North Plume lntennediate 37.5-47.5 1127199 W-30i North Plume lntennediate 37.5-47.5 619199 3.04 0.6 u 0.0735 0 1.63 0.4 35 0.1 W-30i North Plume Intermediate 37.5-47.5 12/8199 4.310 0.9 u 0.166 0 2.960 0.1 27 2 W-30i North Plume Intermediate 37.5-47.5 617100 1.45J 0.05 <0.25 0.139 J 0 1.04 0.1 32 1 W-31s North Plume Shallow 5-15 11/1198 W-31s North Plume Shallow 5-15 11119/98 6.0 u 0.975 0.45 12.8 7 9.1 u W-31s Dup North Plume Shallow 5-15 11119198 6.5 u 17.4 0.4 64.1 6 10 u W-31s North Plume Shallow 5-15 12/16198 0.4 0.50 1.420 0.3 4.730 2.9 10 u W-31sc North Plume Shallow 5-15 6(1199 54.6 1.0 u 2.41 0 66.7 2.1 u 0 W-31s' North Plume Shallow 5-15 6/10199 1.10 1.0 0.89 0.784 0.4 1.31 0.9 3.8 0 W-31s North Plume Shallow 5-15 12/6199 0.492 0.95 0.252 0.3 0.597 1.6 3.8 0 W-31s Dup North Plume Shallow 5-15 12/16199 0.51 1.4 4.4 22 W-31s North Plume Shallow 5-15 6/5/00 4.82 1.7 0.176 J 0 6.33 1.1 3.9 0 W-31i North Plume Intermediate 34-44 11/1198 W-31i North Plume lntennediate 34-44 11/19198 1.6 0.50 0.0045 u 0.0399 u 11 u W-31i North Plume lntennediate 34-44 12/16198 0.6 0.60 0.0048 B 0.15 0.0208 B 0.1 6.6 u W-31i North Plume Intermediate 34-44 6(1/99 0.546 0.6 0.93 0.0101 B 0 0.336 0.8 15 2 --W-31i-North Plume . Intermediate 34-44. -12/6199 0.087-0.6 0.56 0.0057 0 -0.107 0.3 9.7 -0.1 W-31i North Plume Intermediate 34-44 615/00 0.0818 B 0.6 0.45 0.0054 BJ 0 0.0915 B 0.25 9.6 0 W-32i South Plume Intermediate 112-132 11/1198 W-32i South Plume Intermediate 112-132 11/19198 10' 0.59 0.0288 u 1.2 14 u W-32i South Plume Intermediate 112-132 12/18198 1.0 0.74 0.0122 B 0.1 0.344 u 10 u W-32i South Plume Intermediate 112-132 619199 0.143 B 0.8 0.53 0.0154 0 0.217 0.1 8.8 0 W-32i South Plume Intermediate 112-132 12/7199 0.101 1 0.36 0.0142 0 0.157 0.1 10 0 W-32i South Plume Intermediate 112-132 618100 0.0906 BJ 0.2 0.32 0.0172 J 0 0.0879 B 0.5 9.6 0.7 P:\proj\60313. 015~une-0O-t03.xls Page 15 of26 -.., -· ---· --· ----.. ---.. --Table 3. Data from Monitoring Wells Used for Evaluation of Monitored Natural Attenuation 10/27/00 FCX-Statesville Superfund Site OU3 Well Information Products of Degradation e Monitoring Screened Sampling Volatile Fatty Well Zone Well Type Depth Dale co, Alkalinity Alkalinity Methane Ethene Ethane Acids Chloride (ft) (mg/I.) (mg/I.) (mg/I.) (µg/1.) (µg/1.) (µg/1.) (mg/I.) (mg/I.) W-1s Side Gradient Shallow 38-48 12/19/98 16 13 13 0.14 0.007 0.011 u u W-5s South Plume Shallow 32-42 4/1/94 W-5s South Plume Shallow 32-42 1011194 W-5s South Plume Shallow 32-42 4130198 112 u u u u u 12 34 W-5s South Plume Shallow 32-42 12/17/98 234 7.6 7.6 6.2 0.024 0.30 6.0 5.3 w-ss• South Plume Shallow 32-42 619199 105 9.3 4.5 0.12 O.D15 4.3 W-5s South Plume Shallow 32-42 1217/99 85 7.8 u u u 13 4.7 W-5s Dup South Plume Shallow 32-42 12/17/99 9.8 9.8 6.48 0.03 0.14 3.0 5.6 W-5s South Plume Shallow 32-42 6/6100 85 10 <5.0 <1.0 <1.0 <7.8 5.2 W-5i South Plume Intermediate 56-66 1011/94 W-5i South Plume Intermediate 56-66 5/5198 40 39 39 u u u 14 2.0 W-5i South Plume Intermediate 56-66 12/19/98 38 52 52 0.56 0.36 0.15 3.0 1.3 W-5i South Plume Intermediate 56-66 6/8199 60 51 0.48 0.072 0.091 2.4 W-5i South Plume Intermediate 56-66 12/8/99 20 56 u u u 5.5 2.2 W-5i South Plume lntennediate 56-66 619100 40 59 <5.0 <1.0 <1.0 39 2.4 W-5i Dup South Plume lntennediate 56-66 619100 40 60 <5.0 <1.0 <1.0 <7.8 2.5 W-6s Side Gradient Shallow 22-37 4130198 W-6s Dup Side Gradient Shallow 22-37 4130198 W-6i Side Gradient Intermediate 83-93 12/16198 2 110 110 0.77 27 0.15 3.0 9.2 -. --W-9s . Treatment sfi'affow 34-49 515198 u u u u u 5.7 4.9 W-9s Dup Treatment Shallow 34-49 515198 u u u u u 4.6 4.7 W-9s Treatment Shallow 34-49 12/17/98 2.2 2.2 0.51 0.009 0.12 u 3.1 W-10i Side Gradient Intermediate 59-69 1011/94 W-10i Side Gradient Intermediate 59-69 111195 W-10i Side Gradient Intermediate 59-69 12/1195 W-10i Side Gradient Intermediate 59-69 4130/98 15 38 38 u u u 12 u W-10i Side Gradient Intermediate 59-69 12/19/98 10 39 39 1.6 0.010 0.016 u u W-10i Side Gradient Intermediate 59-69 6/8199 15 39 540 0.63 u 1.1 W-10i Side Gradient Intermediate 59-69 12/9/99 10 38 u u u u 1.1 W•10i Side Gradient lntennediate 59-69 616100 10 55 93 <1.0 <1.0 <7.8 1.3 P :\Proj\60313.01 S\june-OO-t03.xls Page 16 of 26 ---· ---· --------- --.. -Table 3. Data from Monitoring Wells Used for Evaluation of Monitored Natural Attenuation 10/27/00 FCX-Statesville Superfund Site OU3 Well Information Products of Degradation e Monitoring Screened Sampling Volatile Fatty Well Zone Well Type Depth Date co, Alkalinity Alkalinity Methane Ethane Ethane Acids Chloride (ft) (mg/L) (mg/L) (mg/L) (µg/L) (µg/L) (µg/L) (mg/L) (mg/L) W-11s Side Gradient Shallow 25--40 4/30/98 W-12s Background Shallow 18-33 10/1/94 W-12s Background Shallow 18-33 1/1/95 W-12s Background Shallow 18-33 4/30/98 24 u u u u u 5.7 1.9 W-12s Background Shallow 18-33 12/8/99 W-12i Background Intermediate 73-1!3 10/1/94 W-12i Background Intermediate 73-1!3 1/1/95 W-12i Background Intermediate 73-1!3 4/30/98 60 25 25 u u u 34 30 W-12i Background Intermediate 73-1!3 12/16/98 55 31 31 2.2 0.028 0.26 u 31 W-12i Background Intermediate 73-1!3 617/99 120 32 1.7 0.026 u 28 W-12i Background Intermediate 73-1!3 12/9/99 30 33 u u u 70 33 W-12i Background Intermediate 73-83 617/00 50 50 230 <1.0 <1.0 39 33 W-16s Treatment Shallow 35-50 5/5/98 W-16s Treatment Shallow 35-50 12/17/98 W-16i Treatment Intermediate 77-1!7 5/5/98 W-16i Treatment Intermediate 77-1!7 12/17/98 W-17s Source Shallow 29.5-44.5 10/1/94 W-17s Source Shallow 29.5-44.5 1/1/95 C' W-17s Source Shallow 29.5-44.5. -5/5/98-· -46 . u u -u u u 5.7 27 W:\is Source Shallow 29.5-44.5 12/18/98 32 3.9 3.9 1.9 0.06 0.12 3.0 29 W-17s' Source Shallow 29.5-44.5 12/9/99 u u u W-17s Source Shallow 29.5-44.5 6/6/00 W-18s Background Shallow 22.5-37.5 12/1/95 W-18s Background Shallow 22.5-37.5 4/30/98 90 u u u u u 23 u W-18s Background Shallow 22.5-37.5 12/16/98 3.3 3.3 0.37 0.006 0.1 3.0 u W-18s Background Shallow 22.5-37.5 6/8/99 30 3.5 0.14 u u 1.7 W-18s Background Shallow 22.5-37.5 12/6/99 30 2.2 u u· u u u W-18s Background Shallow 22.5-37.5 6/6/00 50 3.4 <5.0 <1.0 <1.0 <7.8 1.3 P:\Proj\60313.015\june'.-O0-t03 .xis Page 17 of26 --- --.. -------------Table 3. Data from Monitoring Wells Used for Evaluation of Monitored Natural Attenuation 10/27/00 FCX-Statesville Superfund Site OU3 Well Information Products of Degradation e Monitonng Screened Sampling Volatile Fatty Well Zone Well Type Depth Date co, Alkalinity Alkalinity Methane Ethene Ethane Acids Chlonde (ft) (mg/L) (m9/L) (m9/L) (µ9/L) (µ9/L) (µ9/L) (m91L) (m9/L) W-19s North Plume Shallow 17-27 12/1195 W-19s North Plume Shallow 17-27 5/5198 100 26 26 u u u 18 31 W-19s North Plume Shallow 17-27 12/17198 15 15 0.34 0.012 0.083 3.0 34 W-19s North Plume Shallow 17-27 6/10199 73 16 0.33 u u 43 W-19s North Plume Shallow 17-27 12/7199 55 13 u u u 13 48 W-19s North Plume Shallow 17•27 6/6/00 55 18 <5.0 <1.0 <1.0 <7.8 44 W-20s North Plume Shallow 4-14 12/1195 W-20s North Plume Shallow 4-14 4/29198 40 28 28 u u u 12 u W-20s Dup North Plume Shallow 4-14 4/29/98 29 29 u u u 2.9 u W-20s North Plume Shallow 4-14 12/20/98 14 33 33 0.097 u 0.014 3.0 u W-20s North Plume Shallow 4-14 6/8199 40 31 0.074 u u t.6 W-20s North Plume Shallow 4-14 12/7/99 14 37 u u u 8.8 2.0 W-20s Dup North Plume Shallow 4-14 12/7199 37 .u u u 8.8 2.1 W-20s North Plume Shallow 4-14 6/8/00 15 34 <5.0 <1.0 <1.0 <7.8 1.8 W-20s Dup North Plume Shallow 4-14 6/8/00 15 34 <5.0 <1.0 <1.0 <7.8 1.9 W-20i North Plume Intermediate 84-94 3/1/96 W-20i North Plume Intermediate 84-94 4/29198 14 56 56 u u u 26 14 W-20i North Plume Intermediate 64-94 12/15/98 16 64 64 1.4 0.55 0.22 u 36 W-20i North Plume Intermediate 64-94 1/26/99 W-20i North Plume Intermediate 64-94 1/27199 W-20i North Plume Intermediate 64-94 6/8/99 20 61 1.6 0.028 -0.025 23 W-20i North Plume ln~rmediate _ -84-94 --12/7/99 · · 10 -·68 u u u 13 35 W•20i North Plume lntennedlate 84-94 6/8/00 10 64 130 <1.0 <1.0 <7.8 30 W-20d' North Plume Deep 152-166 9/23198 W-20d North Plume Deep 152-166 12/17/98 610 610 4.1 0.43 0.26 u 6.7 W-20d North Plume Deep 152-166 6/9/99 510 1.8 0.59 0.064 2.9 W-20d North Plume Deep 152-166 12/9/99 saturated 460 u u u 7.4 2.6 W-20d North Plume Deep 152-166 6/9/00 saturated 180 <5.0 <1.0 <1.0 <7.8 2.7 W-22s South Plume Shallow 20-35 12/1195 W-22s South Plume Shallow 20-35 5/1/98 55 u u u u u 14 9.9 W-22s South Plume Shallow 20-35 12/20/98 60 u u 0.26 0.011 0.013 3.0 8.4 W-22s' South Plume Shallow 20-35 12/8/99 <1.0 u u u u 7.3 W-22s South Plume Shallow 20-35 6/7/00 5.7 <5.0 <1.0 <1.0 <7.8 6.8 P:\Proj\60313. 015\june-0O-t03 .x1s Page 18 of26 ------ -----1111 -----· --Table 3. Data from Monitoring Wells Used for Evaluation of Monitored Natural Attenuation 10127100 FCX-Statesville Superfund Site OU3 Well lnfonnation Products of Degradation e Monitoring Screened Sampling Volatile Fatty Well Zone Well Type Depth Date co, Alkalinity Alkalinity Methane Ethene Ethane Acids Chloride (ft) (mg/I.) (mg/I.) (mg/I.) (µgit.) (µgit.) (µgit.) (mg/I.) (mg/I.) W-22i South Plume Intermediate 57-67 311/96 W-22i South Plume Intermediate 57-67 511/98 105 49 49 u u u 34 16 W-22i South Plume Intermediate 57-67 12120/98 100 45 45 1.1 0.011 0.013 3.0 14 W-22i South Plume Intermediate 57-67 619/99 85 57 33 0.69 0.262 9.9 W-22i South Plume Intermediate 57-67 1218199 65 53 420 u u u 7.9 W-22i Dup South Plume Intermediate 57-67 . 1218199 53 420 u u u 7.7 W-24s South Plume Shallow 5-20 1211195 W-24s South Plume Shallow 5-20 511198 15 15 0.408 u u 17 14 W-24s South Plume Shallow 5-20 1/27199 90 14 14 51 0.041 u 3.0 29 W-24s Dup South Plume Shallow 5-20 1/27199 W-24s South Plume Shallow 5-20 619199 55 17 0.34 u u 18 W-24s South Plume Shallow_ 5-20 1218199 80 14 u u u u 12 W-24s South Plume Shallow 5-20 617100 65 15 16 <1.0 <1.0 16 28 W-26i · Side Gradient lntemnediate 103-118 12116198 14 86 86 1.3 1.3 0.16 30 14 W-28i North Plume lntemnediate 73-68 1211/95 W-28i North Plume Intermediate 73-68 515198 2 84 84 u u u 40 5.2 W-28i North Plume Intermediate 73-68 12118/98 120 120 1.5 0.43 0.24 3.0 3.2 W-28i North Plume Intermediate 73-68 618199 130 0.66 0.85 0.11 4.3 W-28i North Plume lntemnediate 73-68 1217/99 saturated 120 u u u u 2.6 W-28i North Plume lnteJ'!!lajiate . 73-68 _ 616100 --saturated 150 <5.0 <1.0 <1.0 39 2.8 W-29i South Plume Intermediate 88-98 1211/95 W-29i South Plume Intermediate 88-98 511/98 50 8.1 8.1 u u u 17 23 W-29i South Plume lntemnediate 88-98 12120/98 60 8.7 8.7 0.26 0.009 0.019 3.0 21 W-29i Dup South Plume lntemnediate 88-98 12120198 58 11 11 0.24 0.01 0.02 3.0 21 W-29i South Plume Intermediate 88-98 6/9199 80 12 0.33 0.034 0.007 15 W-29i Dup South Plume Intermediate 88-98 6/9199 80 12 0.43 0.050 0.016 14 W-29i South Plume Intermediate 88-98 1219/99 45 9.4 u u u 5.5 19 W-29i Dup South Plume lntemnediate 88-98 1219/99 9.4 u u u 5.5 19 W-29i South Plume Intermediate 88-98 6/7100 50 10 <5.0 <1.0 <1.0 <7.8 21 W-29i Dup South Plume Intermediate 88-98 6/7100 50 15 <5,0 <1.0 <1.0 <7.8 22 P:\Proj\60313. 01 5\june-0O--t03 .xis Page 19 of26 -- -----------.. - ----Table 3. Data from Monitoring Wells Used for Evaluation of Monitored Natural Attenuation 10/27/00 FCX-Statesville Superfund Site OU3 Well Information Products of Degradation e Monitoring Screened Sampling Volatile Fatty Well Zone Well Type Depth Date co, Alkalinity Alkalinity Methane Ethene Ethane Acids Chloride (ft) (mg/L) (mg/L) (mg/L) (µg/L) (µg/L) (µg/L) (mg/L) (mg/L) W-30i North Plume lntennediate 37.5-47.5 12/1/95 W-30i North Plume Intermediate 37.5-47.5 4/30/98 19 170 170 u u u 49 30 W-30i North Plume lntennediate 37.5-47.5 12/19/98 18 140 140 1.4 0.46 0.095 9.0 22 W-30i North Plume Intermediate 37.5-47.5 1/26/99 W-30i North Plume Intermediate 37.5-47.5 1/27/99 W-30i North Plume Intermediate 37.5-47.5 6/9/99 5 130 1.7 0.99 0.45 19 W-30i North Plume Intermediate 37.5-47.5 12/8/99 saturated 140 u u u 11 21 W-30i North Plume Intermediate 37.5-47.5 617/00 saturated 190 <5.0 <1.0 <1.0 16 23 W-31s North Plume Shallow 5-15 11/1/98 W-31s North Plume Shallow 5-15 11/19/98 45 61 61 11.6 7.6 1.2 u 4.6 W-31s Dup North Plume Shallow 5-15 11/19/98 50 55 55 11.5 5.9 1.2 u 4.6 W-31s North Plume Shallow 5-15 12/16/98 26 64 64 3.8 0.D15 0.27 3.0 5.5 W-31s' North Plume Shallow 5-15 6f//99 43 0.48 u u 5.5 W-31sc North Plume Shallow 5-15 6/10/99 25 39 0.19 u u 4.1 W-31s North Plume Shallow 5-15 12/6/99 20 39 u u u u 3.1 W-31s Dup North Plume Shallow 5-15 12/16/99 64 64 3.3 0.011 0.23 u 6.1 W-31s North Plume Shallow 5-15 6/5100 25 32 <5.0 <1.0 <1.0 <7.8 3.4 W-31i North Plume Intermediate 34-44 11/1/98 W-31i North Plume Intermediate 34-44 11/19/98 12 34 34 0.18 1.8 0.022 u 1.1 W-31i North Plume Intermediate 34-44 12/16/98 10 31 31 0.80 0.019 0.21 u 1.5 - W-31i N9rth .Pl_ume Intermediate. 34-44. _ 6f//99 - - --15 . 58 --0.20 u u 2.5 W-31i North Plume Intermediate 34-44 12/6/99 10 30 u u u u 1.7 W-311 North Plume Intermediate 34-44 6/5/00 15 33 <5.0 <1.0 <1.0 <7.8 1.6 W-32i South Plume Intermediate 112-132 11/1/98 W-32i South Plume Intermediate 112-132 11/19/98 10 65 65 0.20 1.4 0.023 3.0 1.7 W-32i South Plume lntennediate 112-132 12/18/98 16 67 67 0.52 0.061 0.097 3.0 1.9 W-32i South Plume lntennediate 112-132 6/9/99 20 62 0.61 0.15 0.020 2.6 W-32i South Plume lntennediate 112-132 12/7/99 8 61 u u u 83 2.5 W-32i South Plume Intermediate 112-132 6/8/00 5 68 <5.0 <1.0 <1.0 <7.8 2.0 P :\P roj\60313.015\june-OO-t03 .xis Page 20 of26 ------- ----.. -------Table 3. Data from Monitoring Wells Used for Evaluation of Monitored Natural Attenuation 10/27/00 FCX-Statesville Superfund Site OU3 Well lnfonnation Nutrients Geochemical Parameters e Monitoring Screened Sampling Well Zone Well Type Depth Date TOC Phosphate TKN Ammonium Ni~ate/ Nitrite Conductivity Temperature pH Eh (ft) (mg/I.) (mg/I.) (mg/I.) (mg/I.) (mg/I.) (µmhos) ('C) (unitless) (mv) W-1s Side Gradient Shallow 38-48 12/19/98 u 0.58 15 21 5.5 300 W-5s South Plume Shallow 32-42 411194 W-5s South Plume Shallow 32-42 10/1/94 W-5s South Plume Shallow 32-42 4/30/98 9.4 u u u 1.2 157 21.3 4.7 216 W-5s South Plume Shallow 32-42 12/17/98 5.6 1.9 W-5s1 South Plume Shallow 32-42 6/9/99 3.6 2.3 70 22.5 6.8 298 W-5s South Plume Shallow 32-42 12/7/99 6.4 2.6 70 17.4 4.9 205 W-5s Dup South Plume Shallow 32-42 12/17/99 5.6 2.0 W-5s South Plume Shallow 32-42 6/6/00 6.1 3.2 80 19.4 5.0 85 W-5i South Plume Intermediate 56-66 10/1/94 W-5i South Plume Intermediate 56-66 5/5198 1.0 0.11 u u u 161 19.8 8.3 136 W-5i South Plume Intermediate 56-66 12/19/98 u u 120 16 6.8 132 W-5i South Plume Intermediate 56-66 6/8/99 3.6 u 150 19 7.7 320 W-5i South Plume Intermediate 56-66 12/8199 u 0.26 140 16.4 6.5 100 W-5i South Plume Intermediate 56-66 619/00 1.7 0.32 140 19.3 6.9 114 W-5i Dup South Plume Intermediate 56-66 6/9/00 1.5 <0.25 140 19.3 6.9 114 W-6s Side Gradient Shallow 22-37 4/30/98 188 19.4 5.1 W-6s Dup Side Gradient Shallow 22-37 4/30/98 188 19.4 5.1 W-Bi Side Gradient Intermediate 83-93 12/16/98 36 u 390 17 8.5 139 W-9s Treatment Shallow 34-49 5/5/98 u 0.050 u u 1.3 37 20.1 6.4 230 W-9s Dup Treatment Shallow 34-49 5/5198 1.0 0.050 u u 1.3 37 20.1 6.4 230 W-9s Treatment Shallow 34-49 12/17198 u 1.8 W-10i Side Gradient Intermediate 59-69 10/1194 W-10i Side Gradient Intermediate 59-69 1/1/95 W-10i Side Gradient Intermediate 59-69 12/1/95 W-10i Side Gradient Intermediate 59-69 4/30/98 u 0.022 u u u 87.7 18.2 7.2 310 W-10i Side Gradient Intermediate 59-69 12/19/98 u 0.31 80 17 7.7 350 W-10i Side Gradient Intermediate 59-69 6/8199 u u 100 16 7.5 124 W-10i Side Gradient Intermediate 59-69 12/9/99 1.2 u 110 15.9 7 205 W-10i Side Gradient Intermediate 59-69 6/6/00 1.4 0.31 110 17.4 7.1 28 P:\Prof\60313.015\june-0O-t03.x1s Page 21 of 26 - ----------... ----- --Table 3. Data from Monitoring Wells Used for Evaluation of Monitored Natural Attenuation 10/27/00 FCX-Statesville Superfund Site OU3 Well Information Nutrients Geochemical Parameters e Monitoring Screened Sampling Well Zone Well Type Deplh Dale TOG Phosphate TKN Ammonium Nitrale/ Nitrite Conductivity Temperature pH Eh (ft) (mg/L) (mg/L) (mg/L) (mg/L) (mg/L) (µmhos) (°C) (unitless) (mv) W-11s Side Gradient Shallow 25-40 4/30/98 68 19.1 5.1 302 W-12s Background Shallow 18-33 10/1/94 W-12s Background Shallow 18-33 1/1/95 W-12s Background Shallow 18-33 4/30/98 u u u u 1.7 43.7 19.3 4.9 305 W-12s Background Shallow 18-33 12/8/99 W-12i Background Intermediate 73.S3 10/1/94 W-12i Background Intermediate 73.S3 1/1/95 W-12i Background Intermediate 73.S3 4/30/98 1.3 0.027 u u 2.7 281 20 6.0 284 W-12i Background Intermediate 73.S3 12/16/98 u 3.1 200 17 5.0 22 W-12i Background Intermediate 73.S3 617/99 u 3.3 200 20 6.0 -168 W-12i Background Intermediate 73.S3 12/9/99 1.1 2.9 260 15.8 5.7 -90 W-12i Background Intermediate 73-83 6moo 28 <0.25 280 18.8 6.0 -124 W-16s Treatment Shallow 35-50 5/5/98 75 20 5.4 192 W-16s Treatment Shallow 35-50 12/17/98 75 20 5.4 323 W-16i Treatment Intermediate 77.S7 5/5/98 250 22 7.3 180 W-16i Treatment Intermediate 77.S7 12/17/98 W-17s Source Shallow 29.5-44.5 10/1/94 W.-11s _ jource _ Shallow 29.5-44.5 -1/1/95--. ---W-17s Source Shallow 29.5-44.5 5/5/98 1.9 0.041 u u 24 320 27 4.9 230 W-17s Source Shallow 29.5-44.5 12/18/98 u 27 300 23 4.4 252 W-17s' Source Shallow 29.5-44.5 12/9/99 490 21.1 4.5 W-17s Source Shallow 29.5-44.5 6/6/00 W-18s Background Shallow 22.5-37.5 12/1/95 W-18s Background Shallow 22.5-37.5 4/30/98 u 0.088 u u 0.43 20 18.4 5.2 498 W-18s Background Shallow 22.5-37.5 12/16/98 u u W-18s Background Shallow 22.5-37.5 6/8/99 u 0.47 20 15 6.1 351 W-18s Background Shallow 22.5-37.5 12/6/99 u 0.32 20 14.7 5.6 225 W-18s Background Shallow 22.5-37.5 6/6/00 <1.0 0.40 20 18.6 5.1 108 P:\ProJ\60313.015\june-OO-t03.xls Page 22 of 26 ------------.. --- ----Table 3. Data from Monitoring Wells Used for Evaluation of Monitored Natural Attenuation 10/27/00 FCX-Statesville Superfund Site OU3 Well lnfonnation Nutrients Geochemical Parameters e Monitoring Screened Sampling Well Zone Well Type Depth Date TOC Phosphate TKN Ammonium Nitrate/ Nitrite Conductivity Temperature pH Eh (ft) (mgll) (mgll) (mgll) (mg/L) (mgll) (µmhos) ("C) (unitless) (mv) W-19s North Plume Shallow 17-27 12/1/95 W-19s North Plume Shallow 17-27 5/5/98 u 0.031 u u 0.45 269 17.8 6,3 196 W-19s North Plume Shallow 17-27 12/17/98 1,3 W-19s North Plume Shallow 17-27 6/10/99 1,4 0.83 230 16 5.5 228 W-19s North Plume Shallow 17-27 12/7/99 u 1.2 270 16.6 5.4 326 W•19s North Plume Shallow 17•27 6/6/00 <to 0.94 270 17,7 5.6 129 W-20s North Plume Shallow 4-14 12/1/95 W-20s North Plume Shallow 4-14 4/29/98 u 0.045 u u u 70.4 14,8 7,4 131 W-20s Dup North Plume Shallow 4-14 4/29/98 u 0.069 u u u W-20s North Plume Shallow 4-14 12/20/98 u 0.21 55 15 6.9 252 W-20s North Plume Shallow 4-14 6/8/99 u u 60 16 6.1 243 W-20s North Plume Shallow 4-14 12/7/99 u 0.37 80 13.5 6.6 321 W-20s Dup North Plume Shallow 4-14 12/7/99 u u W-20s North Plume Shallow 4-14 6/8/00 <1.0 <0.25 80 14.5 6.7 273 W-20s Dup North Plume Shallow 4-14 6/8/00 <1.0 <0.25 80 14.5 6.7 273 W-20i North Plume Intermediate 84-94 3/1/96 W-20i North Plume Intermediate 84-94 4/29/98 u u u u 0.32 172 15.2 8.6 -328 W-20i North Plume Intermediate 84-94 12/15/98 u 0.067 190 15 7.6 199 W-20i North Plume Intermediate 84-94 1/26/99 W-20i North Plume Intermediate 84-94 1/27/99 W-20i North Plume Intermediate 84-94 6/8/99 u 0.48 210 16 7.3 227 W-20i North Plume Intermediate 84-94 12/7/99 u 0.71 250 13.8 7.4 -199 W-20i North Plume lntennediate 84-94 6/8/00 1.6 _<0.25 250 15.4_ -7.6 163 W-20d" North Plume Deep 152-166 9/23/98 W-20d North Plume Deep 152-166 12/17/98 4.6 -237 W-20d North Plume Deep 152-166 6/9/99 5.7 u 1700 16 11.9 136 W-20d North Plume Deep 152-166 12/9/99 4.8 u 1750 14 11.7 -350 W-20d North Plume Deep 152-166 6/9/00 1.8 <0.25 760 16 11.9 -335 W-22s South Plume Shallow 20-35 12/1/95 W-22s South Plume Shallow 20-35 5/1/98 u u u u 9.5 108 18.9 4.7 332 W-22s South Plume Shallow 20-35 12/20/98 u 9 85 18 4.7 230 W-22s' South Plume Shallow 20-35 12/8/99 1.0 5.9 120 16.4 4.8 W-22s South Plume Shallow 20-35 6/7/00 1.1 6.9 120 18.3 4.5 P:\Proj\60313.01 5~une-00-t03.xls Page 23 of 26 -.. --.. -------.. --- ---Table 3. Data from Monitoring Wells Used for Evaluation of Monitored Natural Attenuation 10/27/00 FCX-Statesville Superfund Site OU3 Well Information Nutrients Geochemical Parameters e Monitoring Screened Sampling Well Zone Well Type Depth Dale TOG Phosphate TKN Ammonium Nitrate/ Nitrite Conductivity Temperature pH Eh (ft) (mgll) (mgll) (mgll) (mgll) (mgll) (µmhos) ('C) (unitless) (mv) W-22i South Plume lntem,ediate 57-87 3/1/96 W-22i South Plume lnlen11ediate 57.f,7 5/1/98 1.0 u u u 4.2 176 19.1 6.2 222 W-22i South Plume Intermediate 57-87 12120/98 1.3 4 140 19 6.0 136 W-22i South Plume Intermediate 57-87 6/9/99 2.4 2.9 170 16 6.3 145 W-22i South Plume Intermediate 57-87 1218/99 u 3.2 220 6.2 94 W-22i Dup South Plume Intermediate 57.f,7 1218/99 1.0 3.3 W-24s South Plume Shallow 5-20 1211/95 W-24s South Plume Shallow 5-20 5/1/98 1.3 0.12 u u 0.25 185 20.5 5.7 230 W-24s South Plume Shallow 5-20 1/27/99 1.2 u 240 W-24s Dup South Plume Shallow 5-20 1/27/99 W-24s South Plume Shallow 5-20 6/9/99 1.4 u 90 15.5 5.9 204 W-24s South Plume Shallow 5-20 1218/99 u 0.55 130 13 5.8 237 W-24s South Plume Shallow 5-20 6/7/00 1.5 <0.25 210 16.9 5.5 209 W-26i Side Gradient lnten11ediate 103-118 12116/98 u 2 240 17 7.1 237 W-28i North Plume Intermediate 73-88 1211/95 W-28i North Plume Intermediate 73-88 5/5/98 6.0 0.13 u u 0.14 604 19.8 9.8 158 W-28i North Plume Intermediate 73-88 12118/98 2.5 0.52 220 18 10.0 W-28i North Plume Intermediate 73-88 6/8/99 3.6 u 390 19 10.5 280 W-28i North Plume Intermediate 73-88 1217/99 2.5 0.44 270 15.9 9.9 41 W-28i North Plume Intermediate 73-88 6/6/00 2.3 0.32 380 21.9 10.6 120 W-29i South Plume Intermediate 88-98 1211/95 - -W-29i South Plume~ Intermediate-88'98_ 5/1/98 u u u u 8.5 167 17.2 5.3 235 W-29i South Plume Intermediate 88-98 12120/98 u 7.5 120 17 4.9 239 W-29i Dup South Plume Intermediate 88-98 12120/98 1.7 7.4 120 17 4.9 247 W-29i South Plume lntem,ediate 88-98 6/9/99 1.4 5.8 110 16 5.6 228 W-29i Dup South Plume lnlen11ediate 88-98 6/9/99 u 5.7 110 16 5.6 228 W-29i South Plume Intermediate 88-98 1219/99 u 6.0 180 15.4 5.8 331 W-29i Dup South Plume lnten11ediate 88-98 1219/99 u 6.8 W•29i South Plume Intermediate 88-98 6/7/00 <1.0 6.8 180 18.6 5.4 219 W-29i0up South Plume Intermediate 88-98 6/7/00 <1.0 7.1 180 18.6 5.4 219 P:\Proj\60313.01 5\,june-OO-t03 .xis Page 24 of 26 ---- ---------------Table 3. Data from Monitoring Wells Used for Evaluation of Monitored Natural Attenuation 10/27/00 FCX-Statesville Superfund Site OU3 Well Information Nutrients Geochemical Parameters e Monitoring Screened Sampling Well Zone Well Type Depth Date TOC Phosphale TKN Ammonium Nitralei Nitrite Conductivity Temperature pH Eh (ft) (mgll) (mgll) (mgll) (mg/L) (mgll) (µmhos) ("C) (unitless) (mv) W-30i North Plume Intermediate 37.5-47.5 12/1/95 W-30i North Plume Intermediate 37.5-47.5 4130/98 14 0.078 u 1.2 u 409 18 9.3 -230 W-30i North Plume lntenmediate 37.5-47.5 12/19/98 5.4 u 295 16 8.4 162 W-30i North Plume Intermediate 37.5-47.5 1/26/99 W-30i North Plume Intermediate 37.5-47.5 1/27/99 W-30i North Plume Intermediate 37.5-47.5 6/9/99 4.8 u 370 20 8.4 -245 W-30i North Plume Intermediate 37.5-47.5 12/8/99 3.7 u 390 14.6 9.3 -353 W-30i North Plume Intermediate 37.5-47.5 617/00 3.4 <0.25 390 17.4 9.9 -325 W-31s North Plume Shallow 5-15 11/1/98 W-31s North Plume Shallow 5-15 11/19/98 u 0.16 u u 125 18 6.9 -SB W-31s Dup North Plume Shallow 5-15 11/19/98 u 0.29 u u 125 18 6.9 -63 W-31s North Plume Shallow 5-15 12/16/98 u 0.50 130 18 6.7 142 W-31s' North Plume Shallow 5-15 6f//99 u u 120 16 7.6 257 W-31s' North Plume Shallow 5-15 6/10/99 1.4 0.89 110 14.5 6.9 342 W-31s North Plume Shallow 5-15 12/6/99 u 0.95 120 16.9 6.4 188 W-31s Dup North Plume Shallow 5-15 12/16/99 u u 0.51 130 18 6.7 W-31s North Plume Shallow 5-15 6/5/00 <1.0 1.7 100 16.2 6.2 101 W-31i North Plume lntenmediate 34-44 11/1/98 W-31i North Plume Intermediate 34-44 11/19/98 u u 0.50 85 17 7.0 -118 W-31i North Plume Intermediate 34-44 12/16/98 u 0.60 80 16 7.0 142 W-31i North Plume Intermediate 34-44 6f//99 u 0.93 210 15 7.7 119 W-31i North Plume Intermediate -----. -34-44 12/6/99-· -1.9-0.56 120 15.6 6.8 107 -W-31I--Noitli Plume Intermediate 34-44 6/5/00 1.3 0.45 100 16.9 7.1 126 W-32i South Plume Intermediate 112-132 11/1/98 W-32i South Plume lntenmediate 112-132 11/19/98 u u u u 0.59 160 17 8.8 -102 W-32i South Plume Intermediate 112-132 12/18/98 1.3 0.74 120 16 8.0 250 W-32i South Plume Intermediate 112-132 6/9/99 2.4 0.53 180 16 8.4 214 W-32i South Plume Intermediate 112-132 1217/99 1.8 0.36 150 14.2 8 109 W-32i South Plume Intermediate 112-132 6/8/00 2.0 0.32 140 16.1 8.6 120 P :\Proj\60313. 015\june-OO-t03 .xis Page 25 of 26 --- - P:\Proi\60313.015\june--00-t03.xls -- --.. ------Table 3. Data from Monitoring Wells Used for Evaluation of Monitored Natural Attenuation FCX-Statesville Superfund Site OU3 TABLE FOOT NOTES· 'Monitoring well W-5s was sampled but not purged; the sample was taken on June 8, 1999, and the NAPS were collected on June 9, 1999. 'voe data for W-20d from September 1998 are DQL Ill. cMonitoring well W-31s was ~mpled on 6/10/99 using a slower purge rate. dAdditional aluminum data can be found in Table 3-4 of the Pre-Design Investigation Report General Notes: Data qualifiers are as follows: B indicates the analyte was detected in a blank sample. D indicates that the result is from a diluted sample. J indicates the result is estimated. •-• indicates that there was not an analysis or measurement pelformed. NR indicates the result is not reportable because it was determined as unusable by the data validator. U indicates that the result was less than one-fifth of the contract-required quantitation limit (CRQL): the reporting limit precedes the •u• quaLifier. Elevated DOs may be due to pumping the well dry and then collecting water that has been aerated. Monitoring well W-12s was dry during December 1998, June 1999, and June 2000 sampling events. Monitoring well W-22s was dry during the June 1999 sampling: W-17s did not have enough water to purge or sample during the June 1999 sampling. voe data from December 1999 sampling has been rounded to two (2) significant figures. - ---10/27/00 Page 26 of 26 --------- ------ ----Table 4. Analytical Parameters and Weighting for Preliminary Screening of Natural Attenuation' FCX-Statesville Superfund Site OU3 Analysis Oxygen (DO)" Nitrate• Iron (II)• Sulfate• Sulfide• Methane• Oxidation reduction potential• (ORP) against Ag/AgCI electrode Tolaj Orga_r,_i<e <::arb9n (TOC) _ Temperature• Carbon dioxide Alkalinity Chloride" Hydrogen P:\P ROJ\60313.01 5~une-00-t04. doc Most Contaminated Zone Concentration < 0.5 mg/L > 5 mg/L < 1 mg/L > 1 mg/L < 20 mg/L > 1 mg/L < 0.5 mg/L > 0.5 mg/L <50 mV <-100mV 5 <pH< 9 5 >pH> 9 > 20 mg/L_ > 2 x background > 2 x background > 2 x background > 1 nM < 1 nM Interpretation Tolerated, suppresses the reductive pathway at higher concentrations Not tolerated; however, VC may be oxidized aerobically · At higher concentrations may compete with reductive pathway Reductive pathway possible; VC may be oxidized under Fe(lll)-reducing conditions Al higher concentrations may compete with reductive pathway Reductive pathway possible VC oxidizes Ultimate reductive daughter product, VC accumulates Reductive pathway possible Reductive pathway likely Optimal range for reductive pathway Outside optimal range for reductive pathway _ Carbon and energy source; drives dechlorination; can be natural or anthropogenic At T > 20°C, biochemical process is accelerated Ultimate oxidative daughter product Results from interaction between carbon dioxide and aquifer minerals Daughter product of organic chlorine Reductive pathway possible; VC may accumulate VC oxidized Point Value 3 -3 2 3 2 3 0 3 1 2 0 -2 2 1 1 1 2 3 0 Page 1 of2 -------------------Table 4. Analytical Parameters and Weighting for Preliminary Screening of Natural Attenuation• FCX-Statesville Superfund Site OU3 Analysis Volatile (VOA) fatty acids BTEX" Tetrachloroethene (PCE) Trichloroethene (TCE)" Dichloroethene (DCE)" Vinyl Chloride (VC)" 1, 1, 1-Trichloroethane (TCA)" Dichloroethane (DCA)" Carbon Tetrachloride Chloroethane• Ethene/Ethane Chloroform Dichloromethane Concentration in Most Contaminated Zone Interpretation > 0.1 mg/L > 0.1 mg/L > 0.01 mg/L > 0.1 mg/L Intermediates resulting from biodegradation of more complex compounds; carbon and energy source Carbon and energy source; drives dechlorination Material released Material released Daughter of product of PCE Material released Daughter product of TCE; if amount of cis is greater than 80% of total DCE it is likely a daughter product. 1, 1-DCE can be chemical reaction product of TCA Material released Daughter product of DCE Material released Daughter product of TCA under reducing conditions Material released Daughter product of DCA or VC under reducing conditions Daughter product of VC/ethene Daughter product of VC/ethene Material released Daughter product of Carbon Tetrachloride Material released Daughter product of Chloroform Point Value 2 2 0 0 2c 0 2c 0 2 0 2 2 3 0 2 0 2 'Based on "Technical Protocol for Evaluating Natural Attenuation of Chlorinated Solvents in Ground Water" EPA/600/R-98/128, September 1998. "Required analysis. cPoints awarded only if it can be shown that the compound is a daughter product (i.e., not a constituent of the source NAPL). P:\PROJ\60313.01 5~une..Q0-t04.doc Page2of2 - - - - ------ --- - -----Table 5. Application of USEPA Screening Method to Groundwater Sampling Results from December 1998 and January 1999' FCX-Statesville Superfund Site OU3 Background North Shallow Plume Area South Shallow Plume Area W-12s W-17s W-19s W-20s W-31s W-5s W-22s W-24s Parameter Units (April 1998) Result Pointsb Result Points Result Points Result Points Result Points Result Points Result Points Oxygen (DO) mg/L 7.0 4.0 0 NA' 0 4 0 0.4 3 NA NA 4.5 0 0.9 0 Nitrate/Nitrite mg/L 1.7 27 0 NA 0 0.21 2 0.5 2 1.9 0 9 0 0.6 2 Iron (II) mg/L 0.25 0.8 0 NA 0 0.2 0 2.9 3 NA NA 2.2 3 1.2 3 Manganese (II) mg/L o' 0.3 0 NA 0 0 0 0.3 0 NA NA 0.2 0 0.1 0 Sulfate mg/L 5.8 0 2 31 0 NA 0 10 2 0 2 NA 0 3.3 2 Sulfide mg/L 0 NA 0 NA 0 0 0 0 0 0 0 0 0 0 0 Methane mg/L 0 0.0019 0 0.00034 0 0.000097 0 0.0038 0 0.0062 0 0.00026 0 0.051 0 Eh(ORP) mV 305 252 0 NA 0 252 0 142 0 NA 0 230 0 240 0 TOG mg/L 0 0 0 1.3 0 0 0 0 0 5.6 0 0 0 1.2 0 Carbon Dioxide mg/L 24 32 0 NA 0 14 0 26 0 234 60 1 90 Alkalinity mg/L 0 3.9 1 15 1 33 1 64 1 7.6 0 0 14 Chloride mg/L 1.9 29 2 34 2 0 0 5.5 2 5.3 2 8.4 2 29 2 Phosphate mg/L 0 NA 0 NA 0 NA 0 NA 0 NA 0 NA 0 NA 0 TKN mg/L 0 NA 0 NA 0 NA 0 NA 0 NA 0 NA 0 NA 0 Ammonium mg/L 0 NA 0 NA 0 NA 0 NA 0 NA 0 NA 0 NA 0 Conductivity µmhos 43.7 300 0 NA 0 55 0 130 0 NA 0 85 0 NA 0 Temperature 'C 19.3 23 NA 0 15 0 18 0 NA 0 18 0 NA 0 pH 4.9 4.4 -2 NA 0 6.9 0 6.7 0 NA 0 4.7 -2 NA 0 VOA Fatty Acids mg/L 5.7 3 2 3 2 3 2 3 2 6 2 3 2 3 2 PCE mg/L 0 72 0 0.250 0 0.0270 0 0 0 0 0 0.004 0 0 0 TCE mg/L 0 0 0 0.005 2 0.001 2 0 0 0.053 2 0 0 0 0 cis-1,2-DCE mg/L 0 0 0 0 0 0.004 2 0.00004 2 1.6 2 0.002 2 0 0 Vinyl Chloride mg/L 0 0 0 0 0 0 0 0 0 0.05 0 0.0004 2 0 0 Ethene/Ethane mg/L 0 0.0002 0 0.0001 0 0.00001 0 0.0003 0 0.0003 0 0.00002 0 0.00004 0 1,1,1-TCA mg/L 0 0 0 0 0 0 0 0 0 0.085 0 0.0006 0 0 0 1,1-0CA mg/L 0 0 0 0 0 0 0 0 0 0.270 2 0.0006 2 0.0002 2 1,1-DCE mg/L 0 0 0 0.0003 2 0 0 0 0 0.Q76 2 0 0 0.0001 2 Total Points Awarded (Score): 6 g• 9 17 16 12 17 p:\PROJ\60313.015'4une-OO-t05.xls Page 1 of 2 - --- - ---- -- ---- - ---Table 5. Application of USEPA Screening Method to Groundwater Sampling Results from December 1998 and January 1999• FCX-Statesville Superfund Site OU3 North Intermediate Plume Area South Intermediate Plume Area Background W-28i W-30i W-20i W-31i W-5i W-22i W-29i W-32i Parameter Units W-12i Result Points Result Points Result Points Result Points Result Points Result Points Result Points Result Points Oxygen (DO) mg/L 3.5 2.5 0 0.3 3 0 0.6 0 NA NA 0 4 0 0 Nitrate/Nitrite mg/L 3.1 0.52 2 0 2 0.07 2 0.6 2 0 2 4 0 7.5 0 0.74 2 Iron (II) mg/L 0.1 0.1 0 0.7 0 0 0 0.1 0 0.2 0 1.9 3 0 0 0 0 Manganese (II) mg/L NA 0 0 0.1 0 0 0 0.15 0 0 0 0 0 0 0 0.1 0 Sulfate mg/L 46 24 0 NA 0 13 2 6.6 2 NA NA NA 0 NA 0 10 2 Sulfide mg/L NA 0 0 0.3 0 0 0 0 0 0 0 0 0 0 0 0 0 Methane mg/L 0.0022 0.0015 0 0.0014 0 0.0014 0 0.0008 0 0.00056 0 0.0011 0 0.00026 0 0.0005 0 Eh (ORP) mV 22 NA 0 162 0 199 0 142 0 132 0 136 0 239 0 250 0 TOC mg/L 0 2.5 0 5.4 0 0 0 0 0 0.0 0 1.3 0 0 0 1.3 0 Carbon Dioxide mg/L 55 NA 0 18 0 16 0 10 0 38 0 100 0 60 0 16 0 Alkalinity mg/L 31 120 140 1 64 31 0 52 0 45 0 8.7 0 67 1 Chloride mg/L 31 3.2 0 22 0 36 0 1.5 0 1.3 0 14 0 21 0 1.9 0 Phosphate mg/L NA NA 0 NA 0 NA 0 NA 0 NA 0 NA 0 NA 0 NA 0 TKN mg/L NA NA 0 NA 0 NA 0 NA 0 NA 0 NA 0 NA 0 NA 0 Ammonium mg/L NA NA 0 NA 0 NA 0 NA 0 NA 0 NA 0 NA 0 NA 0 Conductivity µmhos 200 220 0 295 0 190 0 80 0 120 0 140 0 120 0 120 0 Temperature 'C 17 18 0 16 0 15 0 16 0 16 0 19 0 17 0 16 0 pH 5 10 -2 8.4 0 7.6 0 7 0 6.8 0 6 0 4.9 -2 8 0 VOA Fatty Acids mg/L 0 3 2 9 2 0 0 0 0 3 2 3 2 3 2 3 2 PCE mg/L 0.002 0.64 0 0.56 0 1.1 0 0.0001 0 0.028 0 0.11 0 0.032 0 0.0004 0 TCE mg/L 0 0.024 2 0.046 2 0.Q75 2 0 0 0.004 2 0.010 2 0.002 2 0.0002 2 cis-1,2-DCE mg/L 0 0.009 2 0.028 2 0.12 2 0 0 O.Q1 2 0.14 2 0.007 2 0 0 Vinyl Chlonde mg/L 0 0 0 0 0 0 0 0 0 0.0003 2 0.003 2 0.0002 2 0 0 Ethene/Ethane mg/L 0.0003 0.0007 0 0.0006 0 0.0008 0 0.0002 0 0.0005 0 0.00002 0 0.00003 0 0.0002 0 1,1,1-TCA mg/L 0 0 0 0 0 0 0 0 0 0 0 0.012 0 0 0 0 0 1,1-DCA mg/L 0.0005 0 0 0 0 0 0 0 0 0.005 2 0.058 2 0.004 2 0 0 1,1-DCE mg/L 0 0.014 2 0 0 0 0 0 0 0.004 2 0.02 2 0.003 2 0 0 Total Points Awarded (Score): 9 12 9 4 14 15 10 9 1Analytical data used in this table were derived from data presented in Table 3. bRefer to Table 4 for attenuation point assignment for parameters. cNA indicates not applicable. - d•o• was entered for results which were not detected above the reporting limit 9Several parameter.; were not analyzed for. p:\PRO.l'o0313.01 5\june-00-!05.xls Page 2 of 2 ------- -- ----------Table 6. Application of USEPA Screening Method to Groundwater Sampling Results from June 1999• FCX-Statesville Superfund Site OU3 Background North Shallow Plume Area South Shallow Plume Area W-12sb W-17s W-19s W-20s W-31s W-5s W-22s W-24s Parameter Units (April 1998) Result Pointl Result Points Result Points Result Points Result Points Result Points Result Points Oxygen (DO) mg/L 7.0 NA' o• 4.0 0 3.5 0 1.0 0 1.0 0 NA 0 2.0 0 Nitrate/Nitrite mg/L 1.7 NA 0 0.83 2 0 2 0 2 2.3 0 NA 0 0 2 Iron (II) mg/L 0.25 NA 0 0.4 0 0.2 0 2.1 3 0.3 0 NA 0 2.0 3 Manganese (II) mg/L 0 NA 0 NA 0 0 0 0 0 0.4 0 NA 0 0.3 0 Sullate mg/L 5.8 NA 0 25 0 0 2 0 2 1.8 2 NA 0 0 2 Sulfide mg/L 0 NA 0 NA 0 NA 0 NA 0 NA 0 NA 0 NA 0 Methane mg/L 0 NA 0 0.00033 0 0.000074 0 0.00048 0 0.0045 0 NA 0 0.00034 0 Eh (ORP) mV 305 NA 0 228 0 243 0 257 0 298 0 NA 0 204 0 TOC mg/L 0 NA 0 1.4 0 0 0 0 0 3.6 0 NA 0 1.4 0 Carbon Dioxide mg/L 24 NA 0 73 40 0 NA 0 105 NA 0 55 Alkalinity mg/L 0 NA 0 16 31 43 9.3 1 NA 0 17 1 Chloride mg/L 1.9 NA 0 43 2 1.6 0 5.5 2 4.3 2 NA 0 18 2 Phosphate mg/L 0 NA 0 NA 0 NA 0 NA 0 NA 0 NA 0 NA 0 TKN mg/L 0 NA 0 NA 0 NA 0 NA 0 NA 0 NA 0 NA 0 Ammonium mg/L 0 NA 0 NA 0 NA 0 NA 0 NA 0 NA 0 NA 0 Conductivity µmhos 43.7 NA 0 230 0 60 0 120 0 70 0 NA 0 90 0 Temperature 'C 19.3 NA 0 16 0 16 0 16 0 22.5 NA 0 15.5 0 pH 4.9 NA 0 5.5 0 6.1 0 7.6 0 6.8 0 NA 0 5.9 0 VOA Falty Acids mg/L 5.7 NA 0 NA 0 NA 0 NA 0 NA 0 NA 0 NA 0 PCE mg/L 0 NA 0 0.33 0 0.048 0 0 0 0.19 0 NA 0 0.0005 0 TCE mg/L 0 NA 0 0.0074 2 0.0019 2 0 0 0.057 2 NA 0 0 0 cis-1,2-DCE mg/L 0 NA 0 0 0 0.0051 2 0 0 1.1 2 NA 0 0 0 Vinyl Chloride mg/L 0 NA 0 0 0 0 0 0 0 0 0 NA 0 0 0 Elhene/Elhane mg/L 0 NA 0 0 0 0 0 0 0 0.000135 0 NA 0 0 0 1,1,1-TCA mg/L 0 NA 0 0 0 0 0 0 0 0.094 0 NA 0 0 0 1,1-DCA mg/L 0 NA 0 0 0 0 0 0 0 0.24 2 NA 0 0 0 1,1-DCE mg/L 0 NA 0 0 0 0 0 0 0 0.072 2 NA 0 0 0 To1al Poin1s Awarded (Score): NA B 9 10 15 NA 11 P:\PROJ\60313.015\iune-OO-t06.xls Page 1 of 2 ---- ---.. ----- --- ---Table 6. Application of US EPA Screening Method to Groundwater Sampling Results from June 1999' FCX-Statesville Superfund Site OU3 North Intermediate Plume Area South Intermediate Plume Area Background W-28i W-30i W-20i W-31i W-5i W-22i W-29i W-32i Parameter Units W-12i Result Points Result Points Result Points Result Points Result Points Result Points Result Points Results Points Oxygen (DD) mg/1. 3.0 0.5 0 0.6 0 1.1 0 0.6 0 2.0 0 0.8 0 4.0 0 0.8 0 Nitrate/Nitrite mg/1. 3.3 0 2 0 2 0.48 2 0.93 2 0 2 2.9 0 5.8 0 0.53 2 Iron (11) mg/1. 0 0 0 0.4 0 0.1 0 0.8 0 0.4 0 1.6 3 0.1 0 0.1 0 Manganese (11) mg/1. 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 Sulfate mg/l 0 29 0 35 0 9.8 2 15 2 19 2 1.3 2 0 2 8.8 2 Sulfide mg/1. NA NA 0 NA 0 NA 0 NA 0 NA 0 NA 0 NA 0 NA 0 Methane mg/1. 0.0017 0.00066 0 0.0017 0 0.0016 0 0.0002 0 0.00048 0 0.033 0 0.00033 0 0.00061 0 Eh(DRP) mV -168 280 0 -245 2 227 0 119 0 320 0 145 0 228 0 214 0 TDC mg/1. 0 3.6 0 4.8 0 0 0 0 0 3.6 0 2.4 0 1.4 0 2.4 0 Carbon Dioxide mg/1. 120 NA 0 5 0 20 0 15 0 60 0 85 0 80 0 20 0 Alkalinity mg/1. 32 130 1 130 1 61 0 58 0 51 0 57 0 12 0 62 0 Chloride mg/1. 28 4.3 0 19 0 23 0 2.5 0 2.4 0 9.9 0 15 0 2.6 0 Phosphate mg/1. NA NA 0 NA 0 NA 0 NA 0 NA 0 NA 0 NA 0 NA 0 TKN mg/1. NA NA 0 NA 0 NA 0 NA 0 NA 0 NA 0 NA 0 NA 0 Ammonium mg/1. NA NA 0 NA 0 NA 0 NA 0 NA 0 NA 0 NA 0 NA 0 Conductivity µmhos 200 390 0 370 0 210 0 210 0 150 0 170 0 110 0 180 0 Temperature •c 20 19 0 20 0 16 0 15 0 19 0 16 0 16 0 16 0 pH 6 10.5 -2 8.4 0 7.3 0 7.7 0 7.7 0 6.3 0 5.6 0 8.4 0 VOA Fatty Acids mg/1. 0 NA 0 NA 0 NA 0 NA 0 NA 0 NA 0 NA 0 NA D PCE mg/1. 2.5 0.25 0 1.1 0 0.44 0 0 0 0.048 0 0.086 0 0.05 0 0.00063 0 TCE mg/1. 0 0.04 2 0.071 2 O.D3 2 0 0 0.0046 2 0.011 2 0.005 2 0.00022 2 cis-1,2-0CE mg/1. 0 0.0,5 2 0.034 2 0.023 2 0 0 0.0069 2 0.096 2 0.0079 2 0 0 Vinyl Chloride mg/1. 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 Ethene/Ethane mg/1. 0.000026 0.00096 0 0.00144 0 0.000053 0 0 0 0.000163 0 0.000952 0 0.000041 0 0.00017 0 1,1,1-TCA mg/1. 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1,1-DCA mg/1. 0.0005 0 0 0 0 0 0 0 0 0.0045 2 0.046 2 0.0047 2 0 0 1,1-DCE mg/1. 0 0 0 0 0 0 0 0 0 0.0046 2 0.011 2 0.0044 2 0 0 Total Points Awarded (Score): 5 9 8 4 12 13 10 6 aAnalytical data used in this table were derived from data presented in Table 3. bDue to the unavailability of W-12s data from the June 1999 sampling event background well data are presented from the previous sampling event cRefer to Table 4 for attenuation point assgnment for parameters. dNA indicates not applicable. 9•0· was entered for results which were not detected above the reporting limit P :\PROJ\B0313.015\june-00-t06.xls Page 2 of 2 ---- --1111 - ---- --- ----Table 7. Application of USEPA Screening Method to Groundwater Sampling Results from December 1999' FCX-Statesville Superfund Site OU3 Background North Shallow Plume Area South Shallow Plume Area W-12s' W-17s W-19s W-20s W-31s W-5s W-22s W-24s Parameter Units (Apnl 1998) Result Pointsc Result Points Result Points Result Points Result Points Result Points Result Points Oxygen (DO) mg/L 7.0 NA' o• 2.0 0 5 0 1.0 0 1.0 0 NA 0 1.0 0 Nitrate/Nitrite mg/L 1.7 NA 0 1.2 0 0.37 2 0.95 2 2.6 0 5.9 0 0.55 2 Iron (II) mg/L 0.25 NA 0 0.1 0 0.1 0 1.6 3 1.6 3 NA 0 1.5 3 Manganese (II) mg/L 0 NA 0 0 0 0.1 0 0.3 0 0.3 0 NA 0 0.1 0 Sulfate mgll 5.8 NA 0 17 2 1.3 2 3.8 2 2.3 2 1.3 2 0 2 Sulfide mg/L 0 NA 0 NA 0 NA 0 NA 0 NA 0 NA 0 NA 0 Methane mg/L 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 Eh (ORP) mV 305 NA 0 326 0 321 0 188 0 205 0 NA 0 237 0 TOG mgll 0 NA 0 0 0 0 0 0 0 6.4 0 1 0 0 0 Carbon Dioxide mg/l 24 NA 0 55 14 0 20 0 85 NA 0 80 Alkalinity mg/l 0 NA 0 13 1 37 1 39 1 7.8 1 <1.0 0 14 Chloride mg/l 1.9 NA 0 48 2 2 0 3.1 0 4.7 2 7.3 2 12 2 Phosphate mgll 0 NA 0 NA 0 NA 0 NA 0 NA 0 NA 0 NA 0 TKN mg/L 0 NA 0 NA 0 NA 0 NA 0 NA 0 NA 0 NA 0 Ammonium mg/L 0 NA 0 NA 0 NA 0 NA 0 NA 0 NA 0 NA 0 Conductivity µmhos 43.7 490 0 270 0 80 0 120 0 70 0 120 0 130 0 Temperature 'C 19.3 21.1 1 16.6 0 13.5 0 16.9 0 17.4 1 16.4 0 13 0 pH 4.9 4.5 -2 5.4 0 6.6 0 6.4 0 4.9 -2 4.8 -2 5.8 0 VOA Fatty Acids mg/L 5.7 NA 0 13 2 8.8 2 0 0 13 2 0 0 0 0 PCE mg/L 0 108.7 0 0.42 0 0 0 0 0 0.221 0 0.011 0 0.002 0 TCE mg/l 0 0 0 0.011 2 0.0029 2 0 0 0.075 2 0.0002 2 0 0 cis-1,2-DCE mg/L 0 0.5097 2 0.022 2 0.008 2 0 0 1.12 2 0.003 2 0.0003 2 Vin~ Chlonde m9/l 0 0 0 0 0 0 0 0 0 0 0 0.00043 2 0 0 Ethene/Ethane mg/l 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1,1,1-TCA mg/L 0 0 0 0 0 0 0 0 0 0.128 0 0.0008 0 0 0 1,1-DCA mg/l 0 0 0 0 0 0 0 0 0 0.284 2 0.001 2 0.0003 2 1,1-DCE mg/L 0 0 0 0 0 0 0 0 0 0.073 2 0.001 2 0.0002 2 Total Points Awarded (Score): NA 12 11 8 18 12 17 P:\PROJ\60313.01 ~une-00--t07 .xis Page 1 of 2 ------------ - -- ----Table 7. Application of USEPA Screening Method to Groundwater Sampling Results from December 1999• FCX-Statesville Superfund Site OU3 North lntennediate Plume Area South Intermediate Plume Area Background W-28i W-30i W-20i W-31i W-5i W-22i W-29i W-32i Parameter Uni1s W-12i Result Points Result Points Result Points Result Points Result Points Result Points Result Points Results Points Oxygen (DO) mg/I. 4.0 0.8 0 0.9 0 0.8 0 0.6 0 1.5 0 1.0 0 3.0 0 1.0 0 Nitrate/Nitrite mg/I. 2.9 0.44 2 0 2 0.71 2 0.56 2 0.26 2 3.2 0 6 0 0.36 2 Iron (11) mg/I. 0.3 0 0 0.1 0 0.1 0 0.3 0 2.5 3 3.1 3 0.1 0 0.1 0 Manganese (II) mg/I. 0.1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 Sulfate mg/I. 32 14 2 27 0 13 2 9.7 2 18 2 2.6 2 2.3 2 10 2 Sulfide mg/I. NA NA 0 NA 0 NA 0 NA 0 NA 0 NA 0 NA 0 NA 0 Methane mg/I. 0 0 0 0 0 0 0 0 0 0 0 420 3 0 0 0 0 Eh(ORP) mV -90 41 1 -353 2 -199 2 107 0 100 0 94 0 331 0 109 0 TDC mg/I. 1.1 2.5 0 3.7 0 0 0 1.9 0 0.0 0 0.0 0 0 0 1.8 0 Carbon Dioxide mg/I. 30 saturated saturated 10 0 10 0 20 0 65 45 0 8 0 Alkalinity mg/I. 33 120 140 1 68 1 30 0 56 0 53 0 9.4 0 61 0 Chlonde mg/I. 33 2.6 0 21 0 35 0 1.7 0 2.2 0 7.9 0 19 0 2.5 0 Phosphate mg/I. NA NA 0 NA 0 NA 0 NA 0 NA 0 NA 0 NA 0 NA 0 TKN mg/I. NA NA 0 NA 0 NA 0 NA 0 NA 0 NA 0 NA 0 NA 0 Ammonium mg/I. NA NA 0 NA 0 NA 0 NA 0 NA 0 NA 0 NA 0 NA 0 Conductivity µmhos 260 270 0 390 0 250 0 120 0 140 0 220 0 180 0 150 0 Temperature 'C 15.6 15.9 0 14.6 0 13.6 0 15.6 0 16.4 0 NA 0 15.4 0 14.2 0 pH 5.7 9.9 -2 9.3 -2 7.4 0 6.6 0 6.5 0 6.2 0 5.6 0 8 0 VOA Faity Acids mg/I. 70 0 0 11 2 13 2 0 0 5.5 2 0 0 5.5 2 83 2 PCE mg/I. 2.197 0.307 0 1 0 0.265 0 0 0 0.055 0 0.065 0 0.052 0 0.001 0 TCE mg/I. 0 0.043 2 0.071 2 0.025 2 0 0 0.006 2 0.008 2 0.003 2 0.0003 2 cis-1,2-DCE mg/I. 0 0.014 2 0.03 2 0.019 2 0 0 0.0, 2 0.077 2 0.008 2 0 0 Vinyl Chloride mg/I. 0 0 0 0 0 0 0 0 0 0 0 0.0 0 0 0 0 0 Ethene/Ethane mg/I. 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1,1,1-TCA mg/I. 0 0 0 0 0 0 0 0 0 0 0 0.005 0 0 0 0 0 1,1-0CA mg/I. 0.5859 0 0 0 0 0 0 0 0 0.008 2 0.04 2 0.006 2 0 0 1,1-DCE mg/I. 0.1656 0 0 0 0 0 0 0 0 0.007 2 0 2 0.004 2 0 0 Total Points Awarded (Score): 9 10 13 4 17 17 12 8 8Analytical data used in this table were derived from data presented in Table 3. bOue to the unavailability of W-12s data from the December 1999 sampling event background well data are presented from a previous sampling event eRefer to Table 4 for attenuation point assignment for parameters. dNA indicates not applicable. '•o· was entered for results which were not detected above the reporting limit P:\PROJ\60313.01 ~une-OO-to7 .xis Page 2 of 2 -- ------- --- --- ----Table 8. Application of US EPA Screening Method to Groundwater Sampling Results from June 2000' FCX-Statesville Superfund Site OU3 Background North Shallow Plume Area South Shallow Plume Area W-12s" W-17s W-19s W-20s W-31s W-5s W-22s W-24s Parameter Units (Apnl 1998) Result Pointsc Result Points Result Points Resull Points Result Points Result Points Result Points Oxygen (00) mg/L 7.0 NA' O' 1 0 3 0 0 1 0 NA 0 3 0 Nitrate/Nitrite mg/L 1.7 NA 0 0.94 2 0 2 1.7 0 3.2 0 6.9 0 0 2 Iron (11) mg/L 0.25 NA 0 0.2 0 0.2 0 1.1 3 0.5 0 NA 0 3 3 Manganese (11) mg/L 0 NA 0 0 0 0 0 0 0 0.3 0 NA 0 0.3 0 Sulfate mg/L 5.8 NA 0 19 2 1.1 2 3.9 2 1.6 2 1.6 2 100 0 Sulfide mg/L 0 NA 0 NA 0 NA 0 NA 0 NA 0 NA 0 NA 0 Methane mg/L 0 NA 0 0 0 0 0 0 0 0 0 0 0 16 3 Eh (ORP) mV 305 NA 0 129 0 273 0 101 0 85 0 NA 0 209 0 TOG mg/L 0 NA 0 0 0 0 0 0 0 6.1 0 1.1 0 1 .5 0 Carbon Dioxide mg/L 24 NA 0 55 15 0 25 0 85 NA 0 65 Alkalinity mg/L 0 NA 0 18 1 34 32 1 10 1 5.7 1 15 Chloride mg/L 1.9 NA 0 44 2 1.8 0 3.4 0 5.2 2 6.8 2 28 2 Phosphate mg/L 0 NA 0 NA 0 NA 0 NA 0 NA 0 NA 0 NA 0 TKN mg/L 0 NA 0 NA 0 NA 0 NA 0 NA 0 NA 0 NA 0 Ammonium mg/L 0 NA 0 NA 0 NA 0 NA 0 NA 0 NA 0 NA 0 Conductivity µmhos 43.7 NA 0 270 0 80 0 100 0 80 0 120 0 210 0 Temperature "C 19.3 NA 0 17.7 0 14.5 0 16.2 0 19.4 0 18.3 0 16.9 0 pH 4.9 NA 0 5.6 0 6.7 0 6.2 0 5.0 0 4.5 -2 5.5 0 VOA Fatty Acids mg/L 5.7 NA 0 0 0 0 0 0 0 0 0 0 0 16 2 PCE mg/L 0 70 0 0.62 0 O.Q35 0 0 0 0.19 0 0.058 0 0.00055 0 TCE mg/L 0 0 0 0.013 2 0.0013 2 0 0 0.05 2 0 0 0 0 cis-1,2-0CE mg/L 0 2 0.025 2 0.0048 2 0 0 1. 1 2 0 0 0 0 Vin~ Chlonde mg/L 0 0 0 0 0 0 0 0 0 0 0 0.00023 2 0 0 Ethene/Ethane mg/L 0 NA 0 0 0 0 0 0 0 0 0 0 0 0 0 1,1,1-TCA mg/L 0 0 0 0 0 0 0 0 0 0.1 0 0 0 0 0 1,1-0CA mg/L 0 0 0 0 0 0 0 0 0 0.220 2 0 0 0 0 1,1-0CE mg/L 0 0 0 0 0 0 0 0 0 0.064 2 0.00071 2 0 0 Total Points Awarded (Score): NA 12 9 6 14 7 14 P:\PROJ\60313.01 5'iune-OO--t08.xls Page 1 of 2 ---- - - - - - --- -------Table 8. Application of USEPA Screening Method to Groundwater Sampling Results from June 2000• FCX-Statesville Superfund Site OU3 North Intermediate Plume Area South Intermediate Plume Area Background W-28i W-30i W-20i W-31i W-5i W-22i W-29i W-32i Parameter Units W-12i Result Points Result Points Result Points Result Points Result Points Result Points Result Points Results Points Oxygen (DO) mg/I. 3 0.3 3 0.05 3 0.8 0 0.6 0 1.0 0 NA NA 3.0 0 0.2 3 Nitrate/Nitrite mg/I. <.25 0.32 2 0 2 0 2 0.45 2 0.32 2 NA NA 6.8 0 0.32 2 Iron (II) mg/I. 0.25 0 0 0.1 0 0.2 0 0.25 0 0 NA NA 0.2 0 0.5 0 Manganese (II) mg/I. 0 0 0 0 0 0 0 0 0 0 0 NA NA 0 0 0 0 Sulfate mg/I. 11 12 2 32 0 13 2 9.6 2 18 2 NA NA 1.6 2 9.6 2 Sulfide mg/I. 0 NA 0 NA 0 NA 0 NA 0 NA 0 NA NA NA 0 NA 0 Methane mg/I. 230 0 0 0 0 130 3 0 0 0 0 NA NA 0 0 0 0 Eh(ORP) mV -124 120 0 -325 2 163 0 126 0 114 0 NA NA 219 0 120 0 TOC mg/I. 28 2.3 0 3.4 0 1.6 0 1.3 0 1.7 0 NA NA 0 0 2 0 Carbon Dioxide mg/I. 50 saturated saturated 10 0 15 0 40 0 NA NA 50 0 5 0 Alkalinity mg/I. 50 150 1 190 64 0 33 0 59 0 NA NA 10 0 68 0 Chloride mg/I. 33 2.8 0 23 0 30 0 1.6 0 2.4 0 NA NA 21 0 2 0 Phosphate mg/I. NA NA 0 NA 0 NA 0 NA 0 NA 0 NA NA NA 0 NA 0 TKN mg/I. NA NA 0 NA 0 NA 0 NA 0 NA 0 NA NA NA 0 NA 0 Ammonium mg/I. NA NA 0 NA 0 NA 0 NA 0 NA 0 NA NA NA 0 NA 0 Conductivity µmhos 280 380 0 390 0 250 0 100 0 140 0 NA NA 180 0 140 0 Temperature 'C 18.8 21.9 1 17.4 0 15.4 0 16.9 0 19.3 0 NA NA 18.6 0 16.1 0 pH 6.0 10.6 -2 9.9 -2 7.6 0 7.1 0 6.9 0 NA NA 5.4 0 8.6 0 VOA Fatty Acids mg/I. 39 39 2 16 2 0 0 0 0 39 2 NA NA 0 0 0 0 PCE mg/I. 1.3 0.58 0 0.81 0 0.23 0 0 0 0.073 0 NA NA 0.06 0 0.00059 0 TCE mg/I. 0 0.033 2 0.059 2 0.02 2 0 0 0.0067 2 NA NA 0.0017 2 0 0 cis-1,2-0CE mg/I. 0 0.011 2 0.034 2 O.Q16 2 0 0 0.012 2 NA NA 0.0098 2 0 0 Vinyl Chloride mg/I. 0 0 0 0 0 0.00019 2 0 0 0 0 NA NA 0 0 0 0 Ethene/Ethane mg/I. 0 0 0 0 0 0 0 0 0 0 0 NA NA 0 0 0 0 1,1,1-TCA mg/I. 0 0 0 0 0 0 0 0 0 0 0 NA NA 0 0 0 0 1,1-0CA mg/I. 0 0 0 0 0 0 0 0 0 0.008 2 NA NA 0.0069 2 0 0 1,1-0CE mg/I. 0 0.007 2 0.0021 2 0.00034 2 0 0 0.011 2 NA NA 0.004 2 0 0 Total Poin1s Awarded (Score): 16 15 15 4 14 NA 10 7 'Analytical data used in this table were derived from data presented in Table 3. bOue to the unavailability of W-12s data from the June 2000 sampling evenL background well data are presented from a previous sampling event cRefer to Table 4 for attenuation point assignment for parameters. dNA indicates not applicable. e•o• was entered for results which were not detected above the reporting limit P;\PROJ\60313.015'-june-00-108.xls Page 2 of 2 I I I I I I I I I I I I I I I I I I I Table 9. Interpretation of Points Awarded during Screening Process of Natural Attenuation' FCX-Statesville Superfund Site OU3 Score Oto 5 6 to 14 15 to 20 >20 Interpretation Inadequate evidence for biodegradation of chlorinated organics Limited evidence for biodegradation of chlorinated organics Adequate evidence for biodegradation of chlorinated organics Strong evidence for biodegradation of chlorinated organics 'Taken from "Technical Protocol for Evaluating Natural Attenuation of Chlorinated Solvents in Ground Water", EPA/600/R-98/128, September 1998. P: \P ROJ\60313.01 5~une-00-t09. doc Page 1 of 1