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HomeMy WebLinkAboutNCD095458527_19910321_FCX Inc. (Statesville)_FRBCERCLA RI_RI Project Operations Plan-OCRI I I u B I I I I I I UNITED STATES ENVIRONMENTAL PROTECTION AGENCY REGION IV MAR 2 1 1991 Ms. Pat DeRosa Superfund Section NC Division of Solid Suite 150 401 Oberlin Road Raleigh, NC 27605 ' 345 COURTLAND STREET. N.E. ATLANTA. GEORGIA 30365 Waste Management Subject: FCX -Statesville Superfund Site Statesville, North Carolina Dear Ms . DeRosa: IJCIJ 095: Lf5g SJ 7 I I • Please find enclosed a copy of the Draft RI/FS Work Plan for the FCX- Statesville lsuperfund Site .. in Statesville, North Carolina. As you know, the mdin contaminants at the site are 5-10,000 pounds of buried pesticides. The Remedial Investigation is scheduled to begin in May 1991. , I Please review this document and retu~n comments by April 12, 1991. If you have any questions regarding this matter, call me at (404) 347-7791. Sincerely, 1vJt~~ McKenzie Mallary Remedial Project Manager Printed on Recycled Paper I I I I I I 6 I I I I I I I I I I I I PROJECT OPERATIONS PLAN FOR THE REMEDIAL INVESTIGATION AT THE FCX-STATESVILLE SUPERFUND SITE STATESVILLE, NORTH CAROLINA PREPARED BY: US EPA REGION IV ENVIRONMENTAL SERVICES DIVISION, ATHENS, GA WASTE MANAGEMENT DIVISION, ATLANTA, GA I I I I I I u I I I I I I I I I I I T°ABLE OF CONTENTS TABLE OF CONTENTS .......................................................... i LIST OF FIGURES ............................................................ v LIST OF TABLES ............................................................. vi LIST OF APPENDICES ........................................................ vii SECTION 1.0 -INTRODUCTION ..... ............................................ 1 1.1 1. 2 1. 3 Site Background ............................................... . 1 1 2 2 3 4 1.1. 1 1.1. 2 1. 1. 3 1. 1. 4 1..1.5 Facility and Locale ................................... . Site Ownership and Operational History ................ . 1.1.2.1 Chronological Development of Site ............ . 1.1.2.2 On-Site Pesticide Burial ..................... . 1.1.2.3 Additional On-Site Burial .................... . Site Description ....................................... 4 Licensed EPA Establishment ............................. 6 NPL Listing ............................................ 6 Environmental Setting .......................................... 6 1. 2. 1 1. 2. 2 1. 2. 3 1. 2. 4 Landforms . . . 6 Surface Waters . . . . . . . . . . . . . . . . . . . . . . . . 7 Geology and Soils . . . . . . . . . . . . . . . . . . . . . 7 Ground Water . . . . . . . . . . . . . . . . . . . . . . . . . . 8 1.2.4.1 Hydrogeology . . . . . . . . . . . 8 1..2.4.2 Aquifer Use ................................... 9 Summary of Past Investigations 10 1. 3. 1 1. 3. 2 1. 3. 3 1. 3. 4 1. 3. 5 1. 3. 6 Fred C. Hart Associates, February 1986 ................. 10 OHR, May 1986 .......................................... 11 EPA (Weston•SPER) Emergency Response, January 1989 ..... 12 EPA (Weston•SPER) Emergency Response, August 1989 ...... 13 EPA (O.H. Materials) Emergency Response, January 1990 .. 13 NUS Screening Site Inspection, Burlington Ind., 1990 ... 14 SECTION 2. 0 -SAHPLING LOCATIONS AND RATIONALE ............................. 15 2.1 Sampling Areas ................................................. 15 2. 1.1 2.1.2 2 .1. 3 Soil .................................................. 15 Surface Water and Sediment ............................. 18 Ground Water ........................................... 19 i I I I I I I I I I I I I I I I I g n SECTION 3. 0 -REMEDIAL INVESTIGATION SAMPLING/DATA QUALITYOBJECTIVES ....... 20 3.1 3.2 3.3 Introduction and Remedial Investigation Objectives ............. 20 Data Uses ...................................................... 21 Analytical and Sampling Options .................... , ........... 21 SECTION 4. 0 -SITE MANAGEMENT PLAN ......................................... 22 4.1 Field Project Responsibilities ................................. 22 4.2 Site Control and Access ........................................ 23 4.3 Field Office ................................................... 24 4.4 Sample Collection and Handling Procedures ...................... 24 4.5 Sample Identification .......................................... 25 4.6 4.8 4.9 Field Sampling Equipment and Cleaning Procedures ............... 26 Field Instrumentations Sample Contai11ers Sample Analysis ........................... 27 ........................... 28 ...................................... 28 SECTION 5.0 -QUALITY ASSURANCE ............................................ 29 5.1 Organization and Responsibilities .............................. 29 5.2 5.3 5.4 Sample Collection 29 Analytical Procedures .................. 31 5.3.1 Precision, Accuracy, Representativeness, Completeness, and Comparability ...................................... 31 Audits ......................................................... 31 SECTION 6.0 -SITE SURVEYING ............................................... 33 SECTION 7.0 -FIELD SCHEDULE ............................................... 34 SECTION 8.0 -FIELD HEALTH AND SAFETY PLAN ................................. 35 8.1 Purpose ........................................................ 35 ii I I I I I I I I I I I I I I I I I I I SECTION 8.0 -FIELD HEALTH AND SAFETY PLAN (CONT.) 9.0 8.2 Application .................................................... 35 8.3 8.4 8.5 8.6 Responsibilities ...................................... , ......... 35 Training Requirements .......................................... 37 Medical Monitoring ............................................. 37 Site Safety Considerations ..................................... 38 8.7 Identification of Waste Material on Site ....................... 38 8.8 8.9 Site Monitoring and Routes of Exposure .................. : ...... 39 Protective Clothing ............................................ 40 8.9.1 8.9.2 8.9.3 8.9.4 8.9.5 Gloves ................................................. 40 Head Gear ............................................... 40 Eye Protection ......................................... 40 Boots .................................................. 40 Respiratory Protection ................................. 41 8.10 Emergency Contingency Plan . 41 DRILLING, PIEZOMETER AND MONITORING WELL 9.1 9.2 9.3 9.4 CONSTRUCTION SPECIFICATIONS ........... . 42 42 44 45 Monitoring Plan Scope of \fork .............................................. . Technical Specifications for Drilling Operations 9.3.1 9.3.2 9.3.3 9.3.4 9.3.5 9.3.6 9.3.7 General 45 Piezometer Specifications .............................. 46 Surficial Monitoring Well Specifications ............... 47 Bedrock Monitoring Well Drilling Specifications ........ 49 Miscellaneous Drilling Specifications .................. 51 Plugged and Abandoned Wells ............................ 52 Boring Logs . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 52 Decontamination ................................................ 53 9.5 Monitor Well Development ....................................... 56 9.6 9.7 9.8 On-Site Waste Storage and Disposal ............................. 57 Site Cleanup . . . 58 Site Restorations 58 iii I I I I I I I I I I I I I I I I I I I SECTION 9.0 DRILLING, PIEZOMETER AND MONITORING WELL CONSTRUCTION SPECIFICATIONS (CONT.) 9.9 Health and Safety .............................................. 58 9. 10 Security . . . . . . . . . . . . . . . . . . .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 59 9.11 Protective Equipment and Clothing, Utilities, and Services ..... 59 9.12 Medical Surveillance ........................................... 59 9. 13 Support of Community Relations ........................ · ......... 60 9.14 Project Schedule ............................................... 61 9.15 Cost Estimate .................................................. 61 9.16 Measurement and Payment ...................................... , . 61 SECTION 10. 10.1 10.2 10.3 REFERENCES APPENDICES INVESTIGATION DERIVED WASTE MANAGEMENT PLAN ......... . 63 General ........................................................ 63 Investigation Derived Waste Categories .......................... 63 10.2.l 10.2.2 10.2.3 10.2.4 10.2.5 Drilling Waste 63 Monitoring Well Development and Purge Water . . . . 64 Decontaminacj_on Pit Contents . . . . . . . . . . . . . . . . . . . . 64 Waste Solvents ......................................... 64 Clothing And Miscellaneous Trash ....................... 65 Evaluation of Analytical Results of Investigation Derived Waste .................................................. 65 iv I I I I I I I I I I I I I I I I I LIST OF FIGURES 1-1 Area Location Map 1-2 Site Location Map 1-3 Site Diagram 1-4 Site Map, 1950-51 1-5 Site Map, 1969 1-6 Presumed Buried Trench Locations 1-7 Area Surface Water 1-8 Area Geologic Map 1-9 Analytical Results Summary, Pesticide Compounds, Fred C. Hart Study 1-10 Analytical Results Summary, Volatile Organic Compounds, Fred C. Hart 1-11 Analytical Results Summary, DHR Site Inspection, May 1986 1-12 Analytical Results Summary, Weston•SPER Study, August 1989 1-13 Analytical Results Summary, 0.H. Materials Study, January 1990 1-14 Analytical Results Summary, Organic Compounds, NUS Burlington Study 2-1 2-2 2-3 2-4 2-5 2-6 9-1 9-2 9-3 Soil Sample Location Map, Area 1 Soil Sample Location Map, Area 2 Soil Sample Location Map, Area 3 Sediment Sample Location Map, On-Site and Adjacent Area Off-Site Surface Water and Sediment Sample Location Map Ground Water Sample Location Map Typical Piezometer Typical Permanent Well Cluster Open-Hole Bedrock Monitoring Well V Study I I I I I I I I I I I I I I I I I I I LIST OF TABLES 2-1 Physical/Chemical Properties, Identified TCL Compounds 3-1 3-2 3-3 3-4 3-5 3-6 3-7 4-1 4-2 4-3 4-4 7-1 Data Uses Analytical Support Levels Data Quality Objectives Data Quality Objectives Data Quality Objectives Data Quality Objectives Data Quality Objectives Soil Samples Sediment Samples Surface water Samples Ground water Samples Air Samples Station Numbers and Media Designations Project Numbers Sample Containers and Preservatives Sample Collection Summary Table Field Schedule 8-1 Previously Identified Contaminants vi I I I I I I I I I I I I I I I g I g LIST OF APPENDICES Material Safety Data Sheets A B Site-Specific Field Health and Safety Plan vii I I I I I I I I I I I I I I I I I I I 1. INTRODUCTION This Project Operations Plan (POP) was developed to guide the remedial in- vestigation sampling activities to be conducted at the FCX-Statesville (FCXS) NPL Site located in Statesville, Iredell County, North Carolina (Figure 1-1). This POP is being prepared in accordance with the Guidance on Remedial Investigations Under CERCLA (1). The POP includes the Field Sampling and Analysis Plan (FSAP), the Site Management Plan (SMP), the Quality Assurance Project Plan (QAPP) and the Health and Safety Plan (HASP) for the remedial investigation. The sampling plan discusses procedures that will be used to assure the precision, accuracy, com- pleteness, and representativeness of the samples collected, including the data quality objectives. 1.1. Site Background 1.1.1. Facility and Locale The FCXS site is located on Highway 90 approximately 1. 5 miles west of downtown Statesville at the intersection of Phoenix Street and West Front Street (Figure 1-2). The area is characterized by the presence of light and heavy industry, small businesses, residential neighborhoods and a school in the immediate vicinity. The coordinates of the site are latitude 35° 47' 11'1 north, longitude 80° 54' 58" west. (2) The site, shown in Figure 1-3, comprises about 5.5 acres and is bounded by the Southern Railroad and Burlington Industries to the north, the Carnation Milk Company to the west, a small business/residential area immediately south of West - - ----------.. -----iiiil FCX SITE STATESVILLE ~EPA . !REDELL COUNT!' FIGURE 1-1 AREA LOCATION MAP FCX-STATESVILLE SITE STATESVILLE, NORTH CAROLINA I I I I I I I I I I I I I I I I I I I DRAFT FIGURE AUTOCAD VERSION IN PROGRESS r~f'.~ ),;~\_--_/ •:r JD r-:_ .. _ >'<;::::-',-l~~-,;,...;:. ~ ~ 5000 -(~~ • APPR-OX_I_M_A;;-S~A-L_E_,~FE-~--,-• FIGURE 1-2 SITE LOCATION MAP FCX-STATESVILLE STATESVILLE, NORTH CAROLINA ------------------- ♦ CARNATION WELL I FCX-STATESVILLE BURLINGTON INDUSTRIES FIGURE 1-3 APPROXIMATE SCALE SITE DIAGRAM FCX-STATESVILLE STATESVILLE, NORTH CAROLINA ( IN FEET ) 1 inch = 125 ft. 62.5 125 , , ,_ ti $ (/) >< 3 0 if Ka .. -F.C. HART STUDY ♦ -CARN A Tl~ 'WE:tl. @ -'M:STON YtELL ~EPA I I I I I I I I I I I I I I I I I I I . 2 - Front Street, and a pre-fabricated utility shed sales lot on the east side of Phoenix Street. 1.1.2. Site Ownership and Operational History 1.1.2.1 Chronological Development of the Site Based on available file information, it appears that FCXS began operations at the site as an agricultural supply distribution center about 1940 and continued to operate the site until bankruptcy. Prior commercial use of the site, if any, is not known. It appears ,that two main activities were conducted at the site. Initial operations consisted of the formulation, re-packaging, warehousing and distribution of farm che1nicals, primarily pesticides and fertilizer, and the milling and sales of feed grains. This activity was initially restricted to the eastern two-thirds of the site. Figure 1-4 shows the approximate locations and identifications of site buildings present during this time. The year of the photograph for which Figure 1-4 was based on was estimated as 1950-1951, by observation of vehicles present on site. Initial operations also consisted of cleaning and treating of seed grains, apparently with mercury- containing compounds. (3)(4)(5) At some time after 1950-1951, the site underwent several structural and operational changes. The western half of the horse-shoe shaped building in the center of the site was demolished and the upper portion of the current warehouse was constructed, extending to near the the property line between the adjoining Carnation Milk Company property. The small building adjoining the feed mill at the intersection of Phoenix Street and the railroad tracks near the northeastern - - - --- --- --------.. liiiil I FIGURE 1-4 SITE MAP, 1950-51 FCX-STA TESVILLE STATESVILLE, NORTH CAROLINA WAREHOUSE AND DISTRIBUTION FCX BEAUNIT MILLS MILLING AND BAGGING 0 V OFFICE() APPROXIMATE SCALE 62.5 125 : I ( IN FEET ) 1 inch = 125 ft. I &EPA I I I I I I I I I I I I I I I I I I I - 3 - corner of the site was also removed. Re-packaging of liquid pesticides ceased in 1966. Dust re-packaging was discontinued in 1969. This was the status of the site in 1969, based on historical aerial photography. Figure 1-5 shows the locations and identifications of the site buildings at this time. The only known significant operational and structural changes that occurred after this time was the re-packaging of rat bait in the early 1980's and construction of the lower portion of the warehouse in 1982. The current status of the site is discussed in Sec. 1.1.3., Site Description. (4)(5) 1.1.2.2 On-Site Pesticide Burial, 1966 The most i1nportant historical activity at the site, from an environmental standpoint was the burial, in 1966, of DDT, TDE, and possibly liquid chlordane. Approximately 7,000 to 10,000 pounds of these compounds were buried in two (2) adjacent trenches approximately 10-feet deep. Figure 1-6 shows the presumed location of these trenches. The material was supposedly a mixture of powders and liquids in a variety of packaging, including paper bags and other types of typical consumer packaging. After burial was completed, the trenches were covered with six feet of on-site soils and a reinforced 8-inch thick concrete slab was poured over the·area. This was follwed by construction of the upper portion of the current warehouse. According to a past FCX employee, there is the possibility that the trenches were obliterated soon after burial, during extensive construction related grading. During this time, other packages were taken to the old Statesville landfill. (3)(4)(5)(6) -------.. -------- -liiil iiiil I FIGURE 1-5 I " I FCX-STA TESVILLE NEW WAREHOUSE AND DISTRIBUTION (3 BEAUNIT MILLS SITE MAP, 1969 FCX-STA TESVILLE STATESVILLE, NORTH CAROLINA APPROXIMATE SCALE 125 0 62.5 125 k-....I -: : ( IN FEET ) 1 inch = 125 ft. TA K ";';';. 0 0 o_0 OFFICE c, O ~EPA r;;;;m liiiliiiiiil liiill iiii iiiil - - CARNATION MILK COMPANY I " I FCX-STATESVILLE (3 - - - BURLINGTON INDUSTRIES FIGURE 1-6 PRESUMED BURIED TRENCH LOCATIONS FCX-STATESVILLE STATESVILLE, NORTH CAROLINA APPROXIMATE SCALE 125 0 62.5 ,,, ~ -....I --: : ( IN FEET ) 1 inch = 125 ft. -----. --r----.::--=-_:: ru @ -MONITOR \\£1..l Eil -STORIII GRATE El -UNDERGROUND STORAGE TANK COVERS £D -GASCUNE PUMPS &EPA iiill I I I I I I I I I I I I I I I I I I I -4 - 1.1.2.3 Additional On-Site Burial During a site reconnaisance on February 12, 1991, a past employee of the construction company responsible for much of the historical site demolition and construction was interviewed. He indicated that he and other employees were instructed to place various bagged and bottled pesticides in a hole located in the current vicinity of the northeast corner of the lower portion of the warehouse. The hole was apparently located within approximately 35 feet of the railroad tracks. Possible locations could range from the inside corner of the lower warehouse to a location beneath the large concrete slab east of the building. This area is shown in Figure 1-6 and will be the subject of an investigatory boring program during the remedial investigation. Samples will be collected if buried material is evident. No date could be ascertained for this activity. 1.1.3. Site Description The Site, defined as the area south of the Southern Railroad, east of the Carnation Milk Company property, west of Phoenix Street, and north of West Front Street, is currently abandoned. Figure 1-3, the Site Map, shows the location and identification of site buildings and structures, as well as prominent off-site s,truc tu res. The dominant on-site structure is the warehouse located on the western half of the property. It consists of two attached structures, an upper building, constructed in 1969 or 1970, and a smaller, lower building constructed in 1982. I I I I I I I I I I I I I I I I I I I - 5 - (3) The area south of the warehouse, except for a narrow grass strip along the sidewalk, is totally paved. The eastern half of the Site is dominated by a large concrete slab, six-to seven-inches thick, 62-feet wide and 190-feet long, extending approximately 190 feet from the eastern end of the warehouse along the north property line. The slab was poured in two sections and appears to be in good condition. The next level below the slab is covered almost entirely with an undetermined thickness of crushed, compacted gravel. Several smaller areas within this area are paved with either concrete or asphalt. The area thus described, except for the paved area between the warehouse and the street, is completely fenced, most with chain-link fencing. The fence is in good condition and access is gained through a 36-foot wide gate along the eastern end of the Site. There are at least two underground tanks present at the Site, a 7,500 gallon gasoline storage tank and a 10,000 gallon diesel fuel storage tank. These are apparently located in the vicinity of the fuel pumps near the area where the upper and lower warehouses join. (5) Eight ground water monitoring wells, shown on Figure 1-3, are also present at the site. Four were installed in 1976 as part of a pre-purchase environmental evaluation conducted for Southern States Cooperative (3). Four were installed in 1989 in conjunction with the emergency action conducted by US-EPA. (6)(7) I I I I I I I I g I I I I I g g D I g D . 6 • A small, vacant two-story brick building is located at the southeastern corner of the site just beyond the eastern fence. This building served as offices while FCX was in operation. Most of the area between the eastern fence and Phoenix Street, except for that area occupied by the building, is covered with grass. 1.1.4 Licensed EPA Establishment The facility was licensed as and operated as an EPA Establishment to manufacture or re-package pesticides including, at various times, DDT, TDE, Lindane, Chlordane, Malathion, Aldrin, Heptachlor, and a tobacco spray, probably MA-30. Notable spillage is reported to have occurred at the transfer areas. (5) 1.1.5. NPL Listing The FCXS site was evaluated using to the EPA Hazard Ranking System and proposed for inclusion on the National Priority List (NPL) on June 24, 1988. The site scored 37.93, based solely on the ground water pathway. The site was placed on the NPL on February 21, 1990. (8) 1.2. Environmental Setting 1.2.1. Landforms The FCXS site is located in Iredell County, in the Upper Piedmont Plateau of North Carolina. The topography of the area can be generally characterized as gently rolling and sloping, with on-site slopes ranging up to 1.5 percent. I I I I I I I I I I I I I I I I I I I - 7 - Slopes in the immediate area range from 2 to 6 percent, however. Elevations within a four-mile radius of the site range from 740 to 970 feet above mean sea level. (9) (10) 1.2.2. Surface Waters Surface waters identified within a five mile radius of the Site include both Third Creek and Fourth Creek, as well as their tributaries. The closest of the creeks is Third Creek, which is approximately 1.5 miles southeast of the site (two (2) miles stream distance). As can be seen in Figure 1-7, all surface water within this area discharges into the South Yadkin River approximately 15 miles to the east. This river is a major drainage feature for the Piedmont region east and south of the Site. (5) 1.2.3. Geology and Soils The FCXS site is located in the Piedmont Physiographic Province, within the lithologic and structural feature referred to as the Blue Ridge-Inner Piedmont Belt (11). Rock types within this region are primarily gneisses and schists, which frequently grade from one type to another. These rocks are typically f~actured to varying degrees and 1nay display a prominent gneissoid or schistose structure. In addition to this 1neta111orphic suite of rocks, granitic intrusions are also common in this region. Avail3ble geologic maps indicate that the FCXS site is located very near the contact bewteen a granitic intrusion and a rock unit characterized as a hornblende gneiss. Figure 1-8 is typical of these maps. Hornblende gneiss typically weathers to a deep red or brown soil in this region. ----.. -- ~EPA --liiil --- liiiiilil ----liiil THIRD c;o s((i( APPROXIMATE SCALE 14520 0 7260 k-....I -: ( IN FEET ) 1 inch = 14520 ft. 14520 : FIGURE 1-7 AREA SURFACE WATER FCX-STA TESVILLE STATESVILLE, NORTH CAROLINA FROM: SALISBURY, NORTH CAROLINA 1; 100,000 -SCALE PLANIMETRIC MAP UNITED STATES GEOLOGICAL SURVEY, 1985 I I I I I I I I I I I I I I I I I I I After: LeGrand, Geology and Ground Water in the Statesville area North Carolina-1954. 0 SCALE 2.5 MILES 5 ~ Mica schist and granite, schist predominant. CJ] Hornblende gneiss. ~ Composite gneiss with considerable hornblende gneiss. Oil]]]] Composite gneiss, chiefly quartz-biotite gneiss. ~ Gobbro-diorite and allied basic rocks. FIGURE 1-8 AREA GEOLOGIC MAP FCX-STATESVILLE STATESVILLE, NORTH CAROLINA &EPA 3 I I I I I I I I I I I I I I I I I I I - 8 - Based on the deep red to brown soils observed at the site, it is presumed that the site is underlain by the hornblende gneiss. (9)(12) Soil and other weathered overburden, collectively referred to as residuum, overly the gneiss. This material varies in thickness across the area, ranging in thickness from only a few feet to over 100 feet, averaging 35-feet thick. Boring logs for wells installed at the FCXS site indicate that residuum at the Site is approximately 60 to 70-feet thick. (12)(13) 1.2.4. Ground Water 1.2.4.1 Hydrogeology The Site hydrogeology is probably characteristic of the general scenario developed for the Piedmont region of North Carolina and other geologically similar areas. Typically, a layer of residuum, comprised of surficial soil and saprolite overlies a fractured, unweathered bedrock. The type of bedrock, the nature of the weathering interval and degree of fracturing varies from one area to another. In the most general terms, the saprolite serves as a ground water reservoir, created primarily by the accumulation of infiltrated precipitation. This reservoir supplies ground water to the fractures, faults and other secondary permeability features in the bedrock. Ground water systems in these areas, therefore, are generally one, interconnected system_, with the majority of ground water within this system usually occurring at depths less than 150 feet. The ground water surface within the residuum is normally a subdued replica of the surface topography, i.e., ground water flow generally occurs from higher elevations to lower elevations. Flow is typically perpendicular to contour lines I I I I I I I I I I I I I I I I I I g - 9 - and towards the direction of streams and rivers, where ground water discharge occurrs. (11)(12) Well logs for the four gr6und water monitoring wells installed for the Hart investigation and construction diagrams for deep wells installed for the EPA emergency action indicate that saturated saprolite at the Site is approximately thirty-feet thick. (3)(13) Yields for wells in the area are highly variable and depend on a number of factors. In general, saprolite wells have lower yields than wells installed in the fractured bedrock. Within the bedrock, yields are a function of the number and size of fractures, faults or other permeablility features encountered by the well bore, as well as pumping level. The average yield for drilled wells six inches in diameter in the area is less than 19 gallons per minute, although the I deep well located on the Carnation Milk Company property reportedly yields in excess of 500 gallons per minute. Many home water supply wells yield less than 10 gallons per minute. (12) 1.2.4.2 Aquifer Use Although there are several public water supplies within Iredell County, including the Statesville public water supply, the West Iredell Water Company, and the Iredell County Water Corporation, there are apparently no consumers within a four-mile radius of the site which rely on a ground water-based public 1 water supply. There are numerous homes, however, representing as many as 4,500 people within the four-mile radius of the site, which have private water supply I I I I I I I I I I I I I I m I I g D -10 - wells. It is not known how many of these are using their private well or have been hooked-up to one of the available public water supplies. (10)(12) 1.3. Summary of Past Investigations There have been several sampling investigations, of varying scope, at the FCXS Site. These investigations were conducted by the North Carolina Department of Human Resources (DHR), US-EPA, and Fred C. Hart, for Southern States Cooperative, one-time potential purchasers of the site. Following is a summary of the investigations. Designations for wells sampled for these investigations are not necessarily consistent from one investigation to another, Data may be compared using well locations as shown in the figures, however. 1.3.1. Fred C. Hart Associates, Inc. February 1986 (3) During February 1986, Fred C. Hart conducted a pre-purchase environmental evaluation of the Site for Southern States Cooperative, Inc. Four ground water samples were collected from wells installed as a part of the evaluation, and fi~e composite soil samples were collected from locations around the site. All samples were analyzed for priority pollutant pesticides. The ground water samples were also analyzed for priority 'pollutant volatile organic compounds. S~mple locations and analytical summaries for tl1ese samples are shown in Figures 1-9 and 1-10. Soil analyses detected nine (9) pesticides, of which chlordane and 4,4-DDT were found at the highest concentrations, 8,000 ug/1 and 2,600 ug/1, respectively. Pesticides and volatile organic compounds were detected in the - - - - Pesticides: CARNATION Pesticides: 4,-4 -DOE -13 Oeldrin -2. 7 4,4'-D00 -20 4,-4-'-DOT -26 lr O'llOfdone -240 -- FCX-STATESVILLE Pesticides: Alpha BHC -34 Betll BHC -5.6 Gamma BHC -58 Delta BHC - , J Endrln Ketone -3 Pesticides: 4,-4'-DDE -420 Dleldrin -1-1-0 4,-4'-DDO -630 4,-4'-DDT -150 Chlordane -8000 Pesticides: BURLINGTON INDUSTRIES 4,4' -DDL -53 4,4'-DOO -31 4,4'-00T -96 Chlordane -413 FIGURE 1-9 ANALYTICAL RESULTS SUMMARY PESTICIDE COMPOUNDS FRED C. HART STUDY, FEBRUARY 1986 FCX-STATESVILLE STATESVILLE, NORTH CAROLINA APPROXIMATE SCALE 0 62.5 125 --, I ( IN FEET ) 1 inch ::=. 125 ft. .. - WiW)_ e -SOIL ■ -WAITR lilil ALL CONC. ug/k~ (SOIL); ug/1 (WATER) Pesticides:: Alpha BHC -g Beta BHC -29 -4,-4'-DDE -250 Dieldrln -460 4,-4'-00D -290 4,4'-00T -2600 Endr!n -4ti Metho~)'Chlor -670 Pesticides: 4,4'-D0E -4-0 4,4'-DOD -55 4,-4'-DDT -100 O'IIOf"dane -760 ~EPA liiiil -- Volatiles: -- Trichlorofluoromethone - Carbontetrochlorlde -65 Trkhloroelhylene -15 BenZOflO -15 - ~---T_o_l,_~_,_-_15 ____ ~ '<' I ,.. I CARNATION ,.. I --.. - BURLINGTON INDUSTRIES FCX-STATESVILLE Volotle:s: FIGURE 1-10 ANALYTICAL RESULTS SUMMARY VOLATILE ORGANIC COMPOUNDS FRED C. HART STUDY, FEBRUARY 1986 FCX-STATESVILLE STATESVILLE, NORTH CAROLINA Volatiles; 1,1-Dichloroelhene -15 1,1-Dlchloroethone -12 Trons-1,2-0lchloroethane -15 1,1.1-Trichlornethone -15 Trlchloroethylene -25 Telrcchloroethylene -~1 APPROXIMATE SCALE 125 0 62.5 125 ~r....J , , ( IN FEET ) 1 inch = 125 ft. - ,_ 1::1 fl= (/) X § if -- Wiflill ■ -WATER All CONC. ugjk~ (SOIL); ug/I (WATER} &EPA I I I I I I I I I I I I I I I I I I I -11 - ground water samples. Gamma-BHC was the prominent pesticide found in three of the wells, including the upgradient well. Other isomers of BHC, as well as a possible metabolite of endrin ketone, were also detected. Trichlorofluoromethane and tetrachloroethylene were the volatile organic compounds detected at the highest concentrations. Well MW-3 was the well most contaminated with pesticides; well MW-2 was the well most contaminated with volatile organic compounds. The ground water data may be somewhat suspect, as the wells were installed with little regard for quality control and quality assurance. The wells were constructed with friction-fitted PVC, tiped together with duct tape, and the drilling equipment was not adequately cleaned bewteen wells. 1.3.2 DHR. May 1986 (4)(5) The DHR conducted a Site Inspection in May 1986. The on-site monitoring wells and a deep, water supply well west of the site on Carnation Milk Company property were sampled, as well as six soil sample locations. Figure 1-11 contains an organic compound analytical summary, with sample locations, for this investigation. Most of the soil sample locations were in the same areas as those sampled by Fred C. Hart in February 1986. One sample was collected south of West Front Street in the yard of a residence. Lindane was once again identified in a sample from we 11 MW-3. Fluorocarbons were identified in well MW-4, the upgradient well. and chlorinated solvents were identified in well MW-2 and the deep well on Carna- tion property, east and west of the warehouse, respectively. Caprolactum, a ----.. -- I "'-oo,: :::: "-..../" CARNATION " I " ....... ~ ~-1000 °'""""/00£. -1'80 DDT-UOO / Total PNA•1 -S\71 ··~ a-.......-1900 ~ -:110 DDT -»a llnd!a: T.W""-'01-IJOe FCX-STATESVILLE !bfDoe Comp:,oll.: O,lcrdm',1 -J17 ,!iOO Total PNA'• -29;,4 a.I ....... -ltoO OWdA'I/OOE -510 DOT -560 • (3 --.. BURLINGTON INDUSTRIES FIGURE 1-11 ANALYTICAL RESULTS SUMMARY SITE INSPECTION, MAY 1986 NORTH CAROLINA DEPARTMENT OF HUMAN RESOURCES FCX-STATESVILLE STATESVILLE, NORTH CAROLINA APPROXIMATE SCALE 125 0 62.5 125 ~r....J , ' ( IN FEET ) 1 inch = 125 ft. .. .. -- I..EWIO. e-SOIL ■-WATER - ALL CONC. ug/kg_ (SOIL); ug/1 (WATER) ~EPA I I I I I I I I I I I I I I I I I I I -12 - component of nylon manufacturing, was detected in all of the on-site monitoring well samples. Although the report attributes the source of this compound in the samples to the nylon bailer rope used for sampling the wells, the most likely source may be historical ground water contamination originating under the Burlington Industries facility north of the Site. During prior ownership, the Burlington plant was engaged in nylon manufacturing and may have had spills of nylon component compounds. The soil sampling data revealed that, in addition to chlordane, DDT and dieldrin were also found at several locations in the vicinity of the warehouse. These compounds were also detected in the soil sample from the yard of the residence across West Front Street from the warehouse. 1.3.3 EPA (Weston•SPER) Emergencv Response, January 1989 (6) In January 1989, Weston•SPER, Atlanta, Georgia, conducted an emergency response sampling investigation at the 'rcxs site to determine the nature of pesticide contamination at locations previously sampled by Fred C. Hart and the DHR and to attempt to locate the two on-site burial trenches allegedly used to dispose of pesticides in 1969. No pesticides were detected in any of the samples collected outside of the warehouse bui]ding. The detection limit for these samples, however, were somewhat higher than those for the previous studies. Further, no evidence of the alleged burial was observed in any of the approximately 30 borings completed th Lough· the floor of the upper warehouse building. Subsequent conversations wcth a past FCXS employee indicates that the borings may have been located too far to the east to intercept the trenches. I I I I I I I I I I I I I I I I I I I . 13 . 1.3.4 EPA (Weston•SPER) Emergency Response. August 1989 (14) Four (4) new ground water monitoring wells were installed at two locations at the Site. At each location two (2) wells were installed as a shallow (45-feet depth) and deep (125-feet depth) cluster. These wells. as well as the four (4) Fred C. Hart wells were sampled for a variety of volatile organic compounds and pesticides. Figure 1-12 shows the locations of these samples and the analytical summary for the compounds detected in the samples. The most significant contamination identified was a mixture of various pur- geable halocarbons and was observed at the greatest concentrations in well MW-SD, a deep well located near the northeast corner of the Site, and well MW-1, a shallow well located in the parking lot against the south face of the warehouse. All wells showed some indication of this type of contamination, with tetra- chloroethylene being the compound identified at the highest concentrations in most samples. Pesticides, all BHC isomer,s were detected in wells MW-1 and MW-3. 1.3.5 EPA (0.H. Materials) Emergency Response, January 1990 (15) During the week of January 8. 1990, 0.H. Materials sampled all eight of the on-site monitoring wells for the Emergency Response and Removal Branch, EPA, Atlanta. The results of this sampling are summarized and shown on Figure 1-13. The results indicate the presence of pesticides in all wells, except for the cluster of wells in the northeast corner of the site. Other important observations are the presence of trichlorofluoromethane in the well located near the northwest corner of the Site and the presence of significant concentrations -- - - - -- - - Alpho-iiHC -o.ou a.to-lHC -0.010 BURLINGTON INDUSTRIES ean...., r.~ -4.:, Q,lcr"otu,m-0.1 ~~11:,3.1 T~-11111 .... I CARNATION .... I .......... IIHC -O.~ IMto-8HC -O.l!M Ottt.-llHC-0.leG Oarrmo-ette-0.944 11-.,tocNGr [pmid• -O.U\ ·-fHC -0.872 ~c -o.eo1 Dolla-llHC -0.106 0...--IIHC -0.27'11 CarbonT~-0.\ 0,k,rvt,:,rm -0.1 1,1-DloN...--7.0 1,2--0~--0.1 1,1-Dldil-.... -1!.I ---o.icrw.-.l.O , __ -50.0 1,1,1-Trlohl~• -.l.l ~ -2.0 Alpho-8HC -0.01♦ a.to-a-IC -0.31.2 Oarr-.no---llHC -CL04l Eno"ln Al<Mfl)IOI -0.227 Co,t,c,n T--0.1 __ .., 1,1-0-....u.cn. -"-~ I~ -0.7 1.1-0ldilontl'I ... -'2.7 w.a,,i.,. ~ -n.o TotracH...--J(:6 1.1.1-r~. -nu Tr1d'lkircl,ot,~ -11.2 Npll0-l!t1C -0.02& !ki4-IIHC -0.2113 Omnm,o,-IIHC -0.011 O'llcnofa'm -0.1 1,1-Dldlk,,-. -1!.I 1.1-~-1e..a W.tn)l«I• Clllor1dl, -.l.:J T----~1.1 1,1,1-Tnct'llor--11.I Trl<hlo,6.tNnoo -1.4 rr1cn1.-..,,.oi--1.0 FIGURE 1-12 ANALYTICAL RESULTS SUMMARY WESTON SPER STUDY AUGUST, 1989 FCX-STA TESVILLE STATESVILLE, NORTH CAROLINA APPROXIMATE SCALE 12s a 62.5 125 ~-r-l l ( IN FEET ) 1 inch = 125 ft. - - - - - KEY ® -MONITOR WELL ALL CONCENTRATIONS IN ug/1 (WATER) &EPA .. ---- cart>on Tiltnx:t'oclrkle -7.llll ~-CNoricle -1.83 1;!,1,;,,~":.,; -11.:: ----"---- ct,11:,,-of.,., -2.17 CARNATION ---.. .. BURLINGTON INDUSTRIES FCX-STATESVILLE I~ ChlotlM -2.651 T~-1.01 8N !IHC -1,0I . FIGURE 1-13 ANALYTICAL RESULTS SUMMARY O.H. MATERIALS STUDY JANUARY, 1990 FCX-STA TES VILLE STAlESVILLE, NORTH CAROLINA 1,1-~-7.71 :..!u-~--2.~5.o T,troc,11....._,,,._ -112.6 1,1,1-Tric:hlorvath<IM -:1..27 Tric............,._ -2.48 Chlora'llffll -1.58 Npha BHC - 0 . .S e.ta IIHC -0.24 '-"'"""' IIHC -O.U. Cart>on T~ -26.:1 1,1-lllcll~ -611.4 1.Z.-DicNor...thaM -2.-M 1,1-D-=t>~• -~4 ~-~--,.~.5 Tatn>~-Jell 1,1,1-T~ne -1J.7 Trichlion>«h)oioM -1" c~-7..tS APPROXIMATE SCALE 125 0 62.5 125 ~r....J : I ( IN FEET ) 1 inch :: 125 ft. --- X @ 0 if - - - illElli)_ @ -MONITOOING Vt£l..L LOCATION ALL CONC. u~/1 (WATER) 1,1-Di<:h..,,_,. -2.7 ~-~---2.~2 T.tra~ -:12.1 1,1.2-T~ -1.711 Trich~ne -1.71 0 ~EPA I I I I I I I I I I I I I I I I I I I -14 - of tetrachloroethene, 1,1-dichloroethene, and 1,1-dichloroethane in many of the wells located in the vicinity of the southeast corner of the warehouse, as well as the cluster of wells in the northeast corner of the Site. 1.3.6 NUS Screening Site Inspection, Burlington Industries, 1990 (10) During the week of August 20, 1990, NUS Corporation conducted a screening site inspection at the Burlington Industries facility located immediately north of the FCXS site. During this inspection, two ground water samples were collected from a pair of wells located near the northeast corner of the FCXS site. These wells were constructed in 1989 during the emergency removal at the site and are identified for this report.as SS and 5D. The locations of these wells and a summary of the organic compou1nd analytical data for each is shown on Figure 1-14. Well 89S is a shallow saprolite well, approximately 45 feet in depth. Well 89D is a deep bedrock well, approximately 125 in depth. Most notable in these samples is the presence of toluene and dichloroethene in the deep well. ----- CARNATION FCX-STATESVILLE · -- BURLINGTON INDUSTRIES FIGURE 1-14 ANALYTICAL RESULTS SUMMARY ORGANIC COMPOUNDS APPROXIMATE SCALE NUS SCREENING SITE INSPECTION, 1990 BURLINGTON INDUSTRIES STATESVILLE, NORTH CAROLINA 125 0 ~---( IN FEET ) 1 inch = 125 ft. 62.5 125 , ' -- ,___ /ti f!= (/) -.. illllill ■ -WAlER J -ESllMA lEO CONC. N -PRESUMPTIVE EVIDENCE FOR COMPOUND All COl',IC, ug/kg {SOIL); ug/1 (WATER) Vol tiles: Cnloroform -0.7J Ex octobles: Amino Hexonoic Add -200JN Bu t)idieneb is( ( dimethyl ethyl) methyljlhenol -JOOJN Octonethioic Acid, Hexylester -20J 11 Unidentified Compounds -300J I◊ Q Vol tiles: Dichloroethene -3J Chloroform -2J Toluene -62 Ex roctables: H)(irox}O"lethyteth)'lphenolethanone -lOJ.I 8 Unidentified Compounds -9000J ~EPA - I I I I I I I I I I I I I I I I I I I -15 - 2. SAMPLING LOCATIONS AND RATIONALE 2.1. Sampling Areas The primary area of investigation consist of the main site area, which is comprised of the area east.of the Carnation Milk Company property, south of the Southern Railroad, west of Phoenix Street and north of West Front Street, as well as portions of the Carnation and Burlington properties, the lot east of Phoenix Street, and the residences and businesses south of West Front Street. Limited surface water and sedi~ent sarnpling will also be conducted in prominent surface water features located off-site. The following sections describe the sampling rationale/protocols and provide sample location maps for each of the media. 2. 1. 1. Soil Both surface and subsurface soil samples will be collected at various locations on and off site during the study. At locations west, south and east of the site, shown in Figure 2-1, a total of twenty-seven (27) grab surface soil samples and three (3) grab subsurface soil samples will be collected. The three (3) subsurface soil samples will be collected at depths of 36"-48", 72''-84'' and 108''-120'' and, along with the surface sample from that location, will comprise a set of control samples for the study. These samples will be collected prior to the collection of any other soil samples for this study. These areas are located up-grade or adjacent to past-actfve material handling areas associ~ted with historical site activities and are not thought to have received either solid or liquid product or material in any qua~tity or concentration that would have resulted in either significant surficial contamination or migration into the ------11111 - -X ,,_ [!] . ,,. I ,,_ ,,_ • • ·YJU • • • ~EPA e -SURF ACE SOIL SAMPLE (0"-6") [!] -SUBSURFACE SOIL SAMPLE (0"-6") (36" -48") (72"-84") (108"-120") ----11111 11111 11111 11111 11111 - • • • [J • • • APPROXIMATE SCALE 125 O 62.5 k-....I -: ( IN FEET ) 1 inch = 125 ft. 125 I • □ • • • • Db r:J FIGURE 2-1 SOIL SAMPLING LOCATIONS AND DEPTHS • AREA 1 FCX-STATESVILLE STATESVILLE, NORTH CAROLINA I I I I I I I I I I I I I I I I I I I -16 - subsurface. Results from these sample locations, however, will be evaluated against risk-based values for any contamiriants that might be identified, and if warranted, subsurface samples will be collected in these areas to characterize any potential risk posed by subsurface soils. Subsurface samples in this area may also be collected during subsequent phases of the investigation in response to identification of significant contamination in subsurface samples collected from adjacent areas during the initial phase of the investigation. The next area to be sampled is shown in Figure 2-2. Area 2 consist of all the remaining area within the area of investigation, excluding the warehouse. At locations within this area, a total of ninety-four (94) surface and subsurface soil samples will be collected. The number samples collected at the various locations identified in Figure 2-2 will vary with location of the station. At each of the four identified piezometer locations, five (5) samples will be collected at intervals of 0 11 -2411 , 60 11 -84", 12011 -14411 , 18011 -20411 , and 240"-264" below ground surface. At twenty-six (26) locations in this area, two samples will be collected, at intervals of 0 11 -6 11 and 24 11 -3611 • At five locations, three samples will be collected, at intervals of 0 11 -6 11 , 2411 -36", and 48 11 -60". These depths will be measured relative to the original ground surface. At two other locations just north of the retaining wall and rip-rap bank along the sidewalk in the southeast corner of the site, three (3) samples will also be collected. The first sample at these two locations, however, will be a composite of the fill material encountered during the first six feet of augering. The other two will be collected from intervals relative to the original ground surface, if ascertainable, at 0 11 -6 11 and 24 11 -36 11 • The sampling depths selected for ireas 1 and 2 are consistent with the apparent contaminant attenuation observed in the results of the previous investigations described in Sec. 1.3. ---- 2· o"-6" • 24"-36" J 0"-6" • 24"-36" 48" -60" 5JEPA ,0 -PIEZOMETER LOCATION 3F • 5 0 -- FILL INTERVAL COMPOSITE (J' -ff' BELOW FILL 24~ -Jb BELOW FILL o"-24" 60"-84" 120•-144" 180"-204" 240"-264" --- -- 5 2 2 0 • •x-x-x-x-x-x2\ . 2 2 2 •\ • • • • 2 • APP ROXI MA TE SCALE 125 O 62.5 125 2 • FIGURE 2-2 SOIL SAMPLING LOCATIONS AND DEPTHS - ~-( IN FEET ) 1 inch = 125 ft. : I AREA 2 FCX-STATESVILLE STATESVILLE, NORTH CAROLINA I I I I I I I I I I I I I I I I I I I -17 - The last area in which soil sampling will be conducted, designated as Area 3, is the warehouse. The proposed sample locations within both the upper and lower warehouses are shown in Figure 2-3. A total of fifty-eight (58) samples is anticipated for both buildings. The greatest concentration of samples will be collected in the western portion of the upper section of the warehouse. Sampling conducted in 1989 in the eastern portion of the upper section did not detect any evidence of the presence of trenches beneath the floor of the building. A review of historical photographs indicates that the trenches, if present, may be located further to the west, relative to the area that was sampled. As such, two (2) confirmatory borings will be located in the eastern portion of the upper building, to verify previous sampling, and 18 (eighteen) borings will be located in the western two-thirds of the building in an effort to locate the trenches. Prior to sampling the locations in the western portion of the building, a micro-gravity survey will be conducted to complement the micro-gravity survey conducted in 1989. The microgravity survey will be subcontracted and will be conducted according to accepted protocols for microgravity surveys. Sample locations tn this area, therefore, are subject to change, based on the results of this survey. If, through this combined effort, trenches are located, some designated sampling locations in this portion of the building may be omitted and the sampling effort will concentrate on characterizing undisturbed soil beneath the trenches. Successful completion of this activity will be contingent on a number of factors including success in penetrating the material and debris in the trench, as well as the appropriateness of the activity from a personnel protection and safety stand-point. In the absence of trenches, attempts will be made to sample beginning at the interface between the fill and the in-place soils. If this boundary is not c::J c:::J &EPA ~ • • ~,j .. • '<--s...\ • ""?--" ~i-"" s. • • • • • 0 • SAMPLING DEPTHS: SURFACE -o·-1r BELOW ESTIMATED LE'V£L Of lNTERF ACE SUBSURFACE -36--48• BELOW ESTIMATED LEVEL OF INTERFACE l!!!!!!l • • • • • • APPROXIMATE SCALE 125 O 62.5 125 ~--.c-: : ( IN FEET ) 1 inch = 125 ft. l!!!!!!!!I l!!!!!!!!!l l!!!!!!!!!I .. FIGURE 2-3 SOIL SAMPLING LOCATIONS AND DEPTHS AREA 3 (WAREHOUSE) FCX-STATESVILLE STATESVILLE, NORTH CAROLINA .. I I I I I I I I I I I I I I I I I I I -18 - distinct and obvious to sampling personnel, the depth below the floor for this boundary at each location will be estimated based on observations of cut-and-fill practices used in construction of the warehouses. The estimated depth to the interface will be marked on all station flags or markers and will represent the beginning of the sampling interval. Samples will be collected at 0"-12" and 36"- 48'' below the estimated interface. Six (6) composite samples of the fill material, included in the total of fifty-eight (58) samples planned for the warehouse area, will be collected, two (2) from the lower building and four (4) from the upper building. These will be selected at random and will provide soil characterization data for the fill used beneath the floors in these buildings. 2.1.2. Surface Water and Sediment Based on site observations and topographic map indications, it appears that there are two surface water/sediment pathways potentially affected by the Site. One pathway, a small, open ditch, runs along the north side of the warehouse and terminates at a culvert at Phoenix Street. It extends underground southeast of Phoenix Street and eventually discharges into a ditch which runs along the north side of the railroad tracks. This ditch originates along the south side of the Burlington facility and discharges to the southeast. Three sediment samples will be collected from these ditches, at the locations shown on Figure 2-4, to determine if the Site is affecting surface water/sediment pathways in the immediate vicinity. .. -.. .. .. .. .. .. .. .. ------ -.. .. CARNATION FIGURE 2-4 SEDIMENT SAMPLING LOCATIONS ON-SITE AND ADJACENT AREAS FCX-STA TESVILLE STATESVILLE, NORTH CAROLINA {J BURLINGTON INDUSTRIES APPROXIMATE SCALE 125 0 62.5 125 k-....I -l l ( IN FEET ) 1 inch = 125 ft. KEY .6. -SEDIMENT SAMPLE LOCATIONS &EPA I I I I I I I I I I I I I I I I I I I -19 - The other pathway,· an unnamed tributary to Third Creek, is characterized as wet-weather or intermittent, in its upper reaches, gradually becoming a perennial, flowing stream in the lower reaches nearer Third Creek. It originates near the intersection of Phoenix Street and West Front Street and runs south and southwest towards Third Creek, approximately two (2) miles stream distance from the Site. Four (4) combination surface water and sediment sample locations will be sampled to provide data for evaluation of any impact the Site may have had on this drainage feature. These locations are shown on Figure 2-5. Two (2) of these stations are located in the unnamed tributary, one (1) is located in Third Creek upstream of the confluence of the tributary and Third Creek, and one is located downstream of the confluence of the two streams. These samples will be collected prior to collection of any on-site soils (Areas 2 and 3). They may be collected concurrently with the off-site soils (Area 1). 2.1.3. Ground Water Ground-water samples will be collected in three (3) phases. This approach is necessitated by the general lack of data with regards to ground water flow directions and contaminant distributions patterns. Initial phase activities will be conducted during the initial sampling phase of the investigation. Phases II and III may be conducted simultaneously. below. This phased approach is described Phase I ground water samples will be collected from ten locations, including four (4) piezometers installed during the investigation, three (3) shallow and I I I I I I I I I I I I I I I I I I I DRAFT FIGURE AUTOCAD VERSION IN PROGRESS KEY: A-SURFACE WATER AND SEDIMENT SAMPLING LOCATION FIGURE 2-5 OFF-SITE SURFACE WATER AND SEDIMENT SAMPLING LOCATIONS FCX-STATESVILLE STATESVILLE, NORTH CAROLINA I I I I I I I I I I I I I I I I I I I -20i - two (2) deep monitoring wells installed during previous investigations, and one (1) deep water supply well, now not in use, located on the Carnation Milk Company property west of the site. The locations of these piezometers and wells are shown on Figure 2-6. Specifications for the piezometers are found in Sec. 9.3 of this plan. These samples will be considered pre-well installation screening samples and are the only ground water samples included in the sample total for this investigation. The analytical results for these samples will be evaluated, along with water levels obtained from all piezometers and wells installed during the current and past investigations, and the results of a direct push, insitu ground water screening program to develop a ground w~ter contaminant scenario. The direct push ground water sampling effort will constitute Phase II of the ground water investigation and will be implemented by the ESD using a sampling technique cu.rrently under development. These samples will be analyzed on-site, allowing real-time development of the sampling pattern and plume delineation. Prior to implementing this program, the specifications for this activity will be distributed among appropriate Region IV personnel for evaluation. The contaminant scenario thus developed will describe, to the extent possible, the suspected contaminant distribution pattern(s) and ground water flow directions across the site. This data will be used, in conjunction with the known physical/chemical properties of the observed contaminants (see Table 2-1), to develop the final monitoring well insrallation plan for the site. After careful evaluation of this information, as well as the soils data from samples collected during Phase I, well locations and special contruction --------------------, CARNATION WELL FIGURE 2-6 GROUNDWATER SAMPLING LOCATIONS FCX-STA TESVILLE STATESVILLE, NORTH CAROLINA BURLINGTON INDUSTRIES APPROXIMATE SCALE 62.5 125 , , ( IN FEET ) 1 inch = 125 ft. KEY 8 -PIEZOMETER LOCATIONS (THIS STUDY) ... -f.C. HART STUDY ♦ -CARNATICN YIEU. @ -WESTON WELL 0 -\lf£U. TO BE SAMPl.ID ~EPA I I I I I I I • g I I I I I I I I H D -21 - 1 considerations, i.e., surface casing in areas of high contaminant concentrations, will be determined and the permanent monitoring well installation program, Phase ' III of the ground water investigation, will be implemented. This program will consist of approximately six (6) shallow and deep overburden well clusters located both on and off site, as werl as approximately two (2) bedrock wells. The on-site wells will be used to provide high quality samples for source area characterization. The off-site wells will be used to determine the extent of contamination in both the shallow, saprolite interval, as well as in the fractured bedrock aquifer system. These estimates are subject to change, pending the results of the Phase I and II investigations . Specifications for the 1 permanent monitoring wells are included in Sec, 9.3 of this plan. A separate, supplementary work plan will be issued for the permanent well installation , program, when appropriate, and will include specific well locations and additional or refined drilling procedures, as needed. -- - - Compound Group Purgeable Halocarbons Carbon Tetrachloride Chloroform 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethylene 1,2-Dichloropropane Methylene Chloride Tetrachloroethylene - - Log Koc 2.62 1. 64 1. 48 1. 15 1. 81 1. 71 0.94 2.42 -- ------ TABLE 2-11 PHYSICAL/CHEMICAL PROPERTIES IDENTIFIED TCL COMPOUNDS, FCX-STATESVILLE STATESVILLE, NORTH CAROLINA Log Ko,, 2. 73 1. 95 1. 78 1.45 2 .13 2.28 1. 30 2.60 Solubility, Organics Misc. w/ethanol, ben- zene, chloroform, ether, carbon disulfide, petroleum ether, naptha, and volatile oils Soluble acetone, misc. with ethanol, ether, benzene and ligroin Misc. w/ethanol Misc. w/ethanol, chlo- roform, and ether Sl. soluble in ethan- ol, ether, acetone, benzene and chloroform Misc. organic solvents Misc. ethanol, ether Soluble in ethanol, benzene, ether and oils (Continuned on next page) Solubility, Water 800 mg/1, 25'C 8,000 mg/1, 25'C 5,500 mg/1, 20'C 8,500 mg/1, 25'C 273 -5,000 mg/1, 25'C 2,800 mg/1, 25'C 16,700 mg/1, 25'C 400 mg/1, 25'C - Spec. Density 1. 60@20/4 'C l.50@20/4'C l.17@20/4'C 1. 25@20/4 'C 1. 21@20/4 'C l.56@20/4'C 1. 33@20/4 'C 1. 63@20/4 'C iiliJ ----- Compound Group Purgeable Halocarbons (C~nt.) 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethylene ~richlorofluoromethane Pesticides Chlordane p, p' -ODD p, p' -ODE p,p' -DDT 2.18 1. 75 1. 81 2.20 5.15- 6.00 4.64 6.00 5.40 ------ TABLE 2-1 (Cont.) PHYSICAL/CHEMICAL PROPERTIES IDENTIFIED TCL COMPOUNDS, FCX-STATESVILLE STATESVILLE, NORTH CAROLINA Log Kc,., 2.18 2. l.8 2.53 2.53 5.93- 6.95 6.00 5.83 6.16 Solubility, Organics Freely sol. CS 2 and benzene. Sol. ether, methanol and CC1 4 Soluble ethanol, chloroform, and ether Soluble in acetone, ethanol, choloroform, and ether Soluble in ethanol, eth.er, and other solv. Technical grades are miscible with aliphatic and aromatic solvents No data found Sol. fats, most solv. Sol. acetone, benzene, cyclohexane, morpholine, pyridine, dioxane, ether, and carbon tetrachloride (Continued on next page) Solubility. Water 300 -4,400 mg/1, 25°C 4,500 mg/1, 20°c 1,100 mg/1, 25°C 1,100 mg/1, 25°C 9 ug/1, 25°C, (Tech. grade)- 51 ug/1, 20-25°C 20 ug/1, 25'C 13 ppb, 25°C 5.5 ppb, 25'C .. liiil Spec. Density 1. 34@20/4 'C 1. 44@20/4 'C l.46@20/4'C 1. 48@20/4 'C 1. 60@20/4 °C l.47@20/4'C No data found 1. 56@15/4 °C liillil liiiil Compound Group Pesticides (Cont. Dieldrin Lindane iiii Polvnuclear Aromatics Acenaphthene Acenapthalene Anthracene Chrysene Fluoranthene - Log Koc 3.00 1. 25 3.68 1,. 27 5.39 4.62 ---- TABLE 2-1 (Cont.) PHYSICAL/CHEMICAL PROPERTIES IDENTIFIED TCL COMPOUNDS, FCX-STATESVILLE STATESVILLE, NORTH CAROLINA 5. 16 3.70 3. 92 1,. 07 1,. 45 5.60 5.22 Solubility 1 Organics Soluble in ethanol and benzene Soluble in benzene, chloroform. and ether Soluble in ethanol, toluene, chloroform, benzene and acetic acid Soluble in ethanol, ether, and benzene Soluble in acetone, and benzene Soluble in ether, ethanol, and acetic acid Soluble in acetic acid, benzene, chloroform, carbon disulfide, ethanol, and ether Solubility, Water 200 ug/1, 25°C 7. 5 ppm, 25°C 3.5 mg/1, 25°C 3.9 mg/1, 25°C 75 ug/1, 25°C 2 ug/1, 25°C 260 ug/1, 25°C iiiil Spec. Density 1. 75@20/4°C 1.89@19/4°C 1. 02@90/4 °C 0.89@16/2°C 1. 24@20/4 °C 1. 27@20/4 °C 1. 25@0/4 °C iiiii liiiil iiiiil Compound Group Polvnuclear Aromatics (Cont. Phenanthrene 4.36 Pyrene 1,. 80 -- TABLE 2-1 (Cont.) PHYSICAL/CHEMICAL PROPERTIES IDENTIFIED TCL COMPOUNDS, FCX-STATESVILLE STATESVILLE, NORTH CAROLINA 4.52 5.09 Solubility, Organics Soluble in acetone, ethanol, ether, !Jenzene, acetic acid. amd carbon disulfide Soluble 1nost sol.vents Solubility, Water 1.0 mg/1, 25°C 0 .13 mg/1, 25°C Spec. Density l.18@25/4 °C 1. 27@23/4 °c 1 -Source: Ground Water Chemicals Desk Reference Vol. 1, Montgomery, John H. and Welkom, Linda M., Lewis Publishers, Inc., 1990, 640 pages. iiiil I I I I I I I I I I I I I I I I I I I -20 - 3. REMEDIAL INVESTIGATION SAMPLING/DATA QUALITY OBJECTIVES 3.1 Introduction and Remedial Investigation Ojectives Presently there is insufficient data available to develop a remediation plan, if needed, for the FCXS site. Therefore, additional tasks need to be implemented to insure adequate data is made available to develop a sound remediation plan. The primary purpose of the remedial investigation is to obtain the additional needed data. Specifically, the field investigation portion of the remedial investigation will: • Determine the areal and vertical extent of contaminated soil at the FCXS site and adjacent properties (Carnation Milk Company, Burlington Industries, the pre-fab utility shed lot, and the residential/business area south of West Front Street). This aspect of the investigation will include an attempt to locate the alleged trenches buried beneath the warehouse. • Determine the extent of contamination, if any, of sediment and surface water in on-site and acljncent 'ditches, as well as in the unnamed tributary to Third Creek and Third Creek itself. • Verify th~ ground water contamination indicated by existing, pre-remedial investigation on-site ground water monitoring wells. • Determine the direction of ground water flow and develop a potentiometric map for the site. I I I I I I I I I I I I I I I I I I I -21 - • Evaluate the likelihood that Burlington Industries is a major source of the flurocarbon and purgeable halocarbon contamination observed in ground water beneath the FCXS site. 3.2 Data Uses Data obtained from this remedial investigation will be used for: site characterization; evaluation of remedial alternatives; engineering design of alternatives; conducting a risk assessment, and, potentially, enforcement (cost recovery). Table 3-1 lists the media to be sampled and how the data will be used. 3.3. Analytical and Sampling Options A description of the analytical support levels are provided in Table 3-2 and were obtain eel from the Data Qua 1 i tv Obj ec ti ves for Remedia 1 Response Activities, Volume 1. Development Process (16) manual. Samples will be collected of soil. surface water. sediment. and ground water. Tables 3-3 through 3-7 list the data quality objectives for each media sampled. The air monitoring data obtained with the portable photo ionization detector, combustible gas indicator, radiation survey meter and the portable organic vapor analyzer, used for personnel health and safety considerations, will be conducted in accordance with analytical support Level 1. The field analytical measurements (pH, temperature and specific conductivity) will be conducted in accordance with analytical support Level 2. All remaining samples will be analyzed in accordance with analytical support Level 4. I I I I I I Media Sampled Soil I Sediment I Surface Water Ground Water I I I I I I I I I I I Table 3-1 Data Uses FCX-Statesville Statesville, North Carolina Site Charac-Risk As- terization sessment Evaluation of Design of Alternatives Alternatives Yes Yes Yes Yes Yes Yes .Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes I I I I I I I I I I I I I I I I I I I 1 2 3 4 5 Description Table 3-2 Analytical Support Levels FCX-Statesville Statesville, North Carolina Field screening. This level is characterized by the use of portable instruments which can provide real-time data to assist in the optimization of sampling point locations and health and safety sup- port. Data can be generated regarding the presence or absence of certain contaminants at sampling locations. Field analysis. This level is characterized by the use of portable analytical instruments which can be used on site, or iri a mobile laboratory stationed near a site. Depending upon the types of contaminants, sample matrix, and personnel skills, qualitative and quantitative data ·can be obtained. Laboratory analysis using methods other than the contract laboratory (CLP) or EPA, Region IV, ESD routine analytical services. This level is used primarily in support of engineering studies using standard EPA approved procedures. Some procedures may be equivalent to CLP/ESD routine a11alytical services, without the requirements for documentation. CLP or ESD routine analytical services. This level is characterized by rigorous QA/QC protocols and documentation and provides qualitative and qt1a11titative analytical data. Non-standard methods. and/or development. level 5. Analyses which may require method modification CLP special analytical services are considered I I I I I I I I I I I I I I I I I I I Media: Location: Data Types: Soil Table 3-3 Data Quality Objectives -Soil Samples FCX-Statesville Statesville, North Carolina Surface and subsurface soils on FCXS site and adjacent properties A. Field Measurements -None B. Laboratory Analyses -Volatile Organics, Base/Neutral/Acid Extractable Organics, Pesticides/PCB's, Herbicides, Metals, Cyanide Sample Type: Environmental, grid-determined surface and subsurface soil, grab and composite samples. Field Analytical Data Level: Not Applicable Laboratory Analytical Data Level: Level 4 Field Quality Control Samples: 10 percent duplicate samples and equipment rinse'blanks Sampling Procedures: See Section 4, ENVIRONMENTAL COMPLIANCE BRANCH STANDARD OPERATING PROCEDURES AND QUALITY ASSURANCE MANUAL (17), for specific procedures. General pro- cedures are given in Section 6 of this POP. Background/Control Sample: Control soil samples will be collected adjacent to the site. I I I I I I I I I I I I I I I I I I I Media: Location: Data Types: Table 3-4 Data Quality Objectives -Sediment Samples FCX-Statesville Statesville, North Carolina Sediment Third Creek and unnamed tributary to Third Creek. A. Field Measurements -None B. Laboratory Analyses -Volatile Organics, Base/Neutral/Acid Extractable Organics, Pesticides/PCB's, Herbicides, Metals, and Cyanide Sample Type: Environmental, grab samples Field Analytical Data Level: Not applicable Laboratory Analytical Data Level: Level 4 Field Quality Control Samples: 10 percent duplicate samples and equipment rinse blanks. Sampling Procedures: See Section 4, ENVIRONMENTAL COMPLIANCE BRANCH STANDARD OPERATIING PROCEDURES AND QUALITY ASSURANCE MANUAL (17), for specific procedures. General procedures are given in Section 6 of this POP. Background/Control Sample: A background/control sample will be collected from Third Creek, upstream of any conceivable discharge originating from the site. I I I I I I I I I I I I I I I I I I Media: Location: Data Types: Table 3-5 Data Quality Objectives -Surface Water Samples FCX-Statesville Statesville, North Carolina Surface water Third Creek and unnamed tributary to Third Creek A. Field Measurements • pH, specific conductivity, temperature B. LABORATORY ANALYSES -Volatile Organics, Base/Neutral/Acid Extractable Organics, Pesticides/PCB's, Herbicides, Metals, and Cyanide Sample Type: Environmental, grab. Field Analytical Data Level: Level 2 Laboratory Analytical Data Level: Level 4 Field Quality Control Samples: 10 percent duplicate samples. One trip blank. One preservative blank for each preservative used at the beginning and end of each week water samples are collected. A duplicate extractable organic sample will be collected for a matix spike. An equipment rinse blank will be collected, if warranted. Sampling Procedures: See Section 4, ENVIRONMENTAL COMPLIANCE BRANCH STANDARD OPERATING PROCEDURES AND QUALITY ASSURANCE MANUAL (17), for specific procedures. General pro- cedures are given in Section 6 of this POP. Background/Control Sample: Background/control sample will be collected from Third Creek, upstream of any conceivable discharge originating from the Site. I I I I I I I I I I I I I I I I I I I Media: Location: Data Types: Table 3-6 Data Quality Objectives -Ground-Water Samples FCX-Statesville Statesville, North Carolina Ground Water On-site monitoriong wells, off-site municipal and irrigation supply wells A. Field Measurements pH, specific conductance, temperature B. Laboratory Analyses: Volatile Organics, Base/Neutral/Acid Extractable Organics, Pesticides/PCBs, Herbicides, Metals, and Cyanide Sample Type: Environmental, Grab Field Analytical Data Level: Level 2 Laboratory Analytical Data Level: Level 4 Field Qualilty Control Samples: 10 percent duplicate samples. One trip blank. Preservative blanks for each preservative used at the beginning and the end of each week water samples are collected. A duplicate extractable organic sample will be collected for a matrix spike. Sampling Procedures: Background/Control: See Section 4, ENVIRONMENTAL COMPLIANCE BRANCH STANDARD OPERATING PROCEDURES AND QUALITY ASSURANCE MANUAL (17), for specific procedures. General procedures are given in Section 6 of this POP. Background/control samples of ground water from the shallow, saprolite water bearing zone will be collected from one of the piezometers installed north (upgradient) of the site. Samples from this piezometer will be considered screening level samples and will be used to eyaluate ground water flow and contamination for final, permanent well siting. I I I I I I I I I I I I I I I I I Media: Location: Data Types: Air Table 3-7 Data Quality Objectives -Air Samples FCX-Statesville Statesville, North Carolina Monitoring wells and soil borings at the site. A. Field Measurements -Photoionization detector, flame ionization detector, combustible gas indicator, radiation survey meter, oxygen meter B. Laboratory Analyses Sample Type: Environmental, grab Not applicable Field Analytical Data Level: Level 1 Laboratory Analytical Data Level: Not applicable Field Quality Control Samples: All instruments calibrated prior to use Sampling Procedures: See Section 8 of this plan, 'FIELD HEALTH AND SAFETY PLAN' Background/Control Sample: Background values will be obtained with the various instruments prior to site entry. I I I I I I I I I I I n D I I I -22 - 4. SITE MANAGEMENT PLAN 4.1. Field Project Responsibilities The overall field investigative/sampling phase of the project will be the responsibility of Don Hunter, the field project coordinator. Mr. Hunter will be responsible for the following field activities: 0 0 0 0 0 0 Insuring that all field activities are communicated and coordinated with Ken Mallory, the project manager. Monitoring overall project quality control. Coordinating field scheduling of work with other section activities. Overseeing and managing field technical resources including the drill rig and other non-sampling field activities. Monitoring health and safety of the sampling/investigative personnel. Coordinating sample analyses with the laboratory. The following is a listing of the HWS personnel that will be involved in the field operations at the FCXS site and their areas of responsibilities: • Don Hunter • Jim Gray • Charles Till • Dan Thoman • Fred Sloan • Jon Vail • Roger Carlton Field Project Coordinator, Safety Officer, Sampler Driller, Project Geologist Sampler Sampler Surveyor Surveyor, Sampler This list will be supplemented by other HWS resources, including ESAT contract personnel, that will be provided on an as-needed basis. In addition, I I I I I I • m I I D I I I I I I I I - 2 3 - the project manager will arrange for additional personnel (FIT, TAT, and/or Waste Management Division) to be on-site to participate fully in the data collection activities. Any contract personnel selected will be dedicated solely to this site for the duration of the field activities. 4.2. Site Control and Access The FCXS site is currently inactive, however, access to most of the site is controlled. The driveway, off Phoenix Street, has a locking gate across it, and there are fences surrounding most of the site except for the parking area south of the warehouse and the area surrounding the old office building in the sou the as tern corner of the Site. The glass in the front door is partially 1 broken, but does not appear to offer access to the warehouse. A large garage- type door located at the eastern end of the warehouse has been partially blown iri, and allows access to the buildings once the fenced area is entered. EPA is currently in possession of keys to the eastern gate, as well as all of the 1 monitoring wells. The remedial project manager will be responsible for procuring permission for all site investigation activities, including access to neighbor's yards, the Carnation property, the Burlington Industries facility, the pre-fabricated shed storage east of Phoenix Street, and the Southern Railroad right-of-way. Mr. Mallory will also be responsible for renting ancillary equipment required for the investigation and not otherwise supplied by project subcontractors. I I I I I I I I I I I I I D n I I I I · 24 · 4.3. Field Office An air-conditioned temporary field office (rented office trailer) will be rented and parked on the property, the exact location to be selected in the field. Electricity, potable water, a telephone hookup, and a refrigerator for storing perishable materials, will be required. The trailer will be designated as the command post during all field operations and will also be used as a storage area for clean sampling and safety equipment and must be secure. A portable toilet and an organic-free water system will also be necessary. Procurement of the trailer, utilities, telephone and portable toilet will be the responsibility of Ken Mallory, the project manager. organic-free water system. ESD will provide the All persons visiting the site must sign in at the field office prior to site entry. Site vehicle traffic will be limited to those being driven by authorized personnel. All other vehicles must remain at a designated area near the field office. 4.4. Sample Collection and Handling Procedures All samples will be collected, preserved, handled and documented in accor- dance with the ECBSOPQAM (17), which is hereby incorporated by reference. A copy of the manual, in addition to the Project Operations Plan will be maintained at the field office/command post for reference during all phases of the field sampling activities. If any deviations in sampling procedures are necessary, these deviations will be recorded in the field log books. \ I I I I I I I m m I I I B R I I I I I -25 - 4.5. Sample Identification Samples collected during the project will be assigned a unique sample number incorporating a site identifier, a station number, and a media identifier. Surface and subsurface soil samples collected at the same location will be identifed using the same station number and A, B, C, etc., in the last character position of the soil media identifier to indicate samples collected at increasing depths, i.e., 11 C'1 is from a greater depth than 11 A11 • The following identification system will be used. FS -XXX -Y\.'Y FS identifies t11e site as .ECX-~tatesville, XXX denotes the station number, c1nd '{YY. denotes the media. Table 4-1 contains the key used to identify the station number and media samJJlcd at a given location. For example: FCX-123-SLD 1 would be the subsurface soil sample collected from the fourth interval sampled at Station No. 123. Samples collected for QA/QC purposes will follow the same general format where Y'{Y will designate the type of blank. Table 4-1 also , contains the key to the different kinds of QA/QC samples to be collected during the investigation. CLP spikes and blanks will be identified using media designators, i.e., SW for surface water, to protect the blind nature of the samp1e. I I I I I I I I g I e R I I I I I I · 26 · All projected samples and their locations are described in Section 2 and shown in Figures 2-2, 2-3, 2-4, 2-5, 2-6 and 2-7. Station numbers will be assigned consecutively from start of project to end. Samples of different media at the same location, for example, surface water and sediment from the same location on a stream, will be distinguished by having a different station number, as well as a different media identifier. To insure the collection of all proposed samples, maps indicating proposed; sample locations will be posted in the field office. As a sample team leaves the office to collect a sample, the sample wi 11 be high-lighted on the the sample diagram. The sample numbers will be assigned at the office by the acting on-~ite sample custodian. The blue copy (last page) of the chain-of-custody form will remain at the field office for reference to insure that all samples are collected. Tl1e project and account numbers that will be used by the field personnel through out the field sampling portion of the investigation will be 91E-132 and 1TFA04D98M, respectively. It is vital in a project of this complexity to make an adequate accounting of man hours expended by task. Accordingly, the Hazardous Waste Section (H\\7S) has assigned individual project numbers to each of the I identified tasks. The man hours expended by task are then recorded on a ' I bi-weekly time sheet by all personnel associated with the project. A co~plete I ' , list of identified tasks and their assigned project numbers is given in Table 4- 1 i 2. Laboratory project numbers will be assigned at a later date. 4.6. Field Sampling Equipment and Cleaning Procedures All samples will be collected with sampling equipment specified and ,decontaminated in accordance with Section 4 ~nd Appendix B of the ECBSOPQAM (17). I I I I I I I n I n H I I I I I I I I Table 4-1 Station Numbers and Media Designations FCX-Statesville Statesville, Tennessee Station Number Samgle Location 100-199 All soils, Area 200-299 All soils, Area 300-399 All soils 1 Area or 1 2 3 400-499 All surface water 500-599 All ground water 600-699 All QA/QC samples -----------------•----------------- Samgle Media Soil Surface Water Sediment Ground Water Equip1nent Rinse Blank Trip Blank Preservative Blank Field Blank Designation SL(A,B, Etc.) S\.J SD G\.J EB TB PB FB Type and sediment I I I I Project Number I 91E-128 91E-129 I 91E-130 91E-l.31 m 91E-132 I 91E-133 91E-13i1 I 91E-135 I I H I R I I I I I Table 4-2 Project Numbers FCX-Statesville Statesville, Nofth Carolina Task Reconnaissance, Site Visits Work Plan Development FSAP Development Surveying Sampling/Field Work RI Report Drafting Figures and Tables Drilling and Well Installation I I I I I I I I I I I I g u I I D R - 2 7 - Any deviation from this must be justified and recorded in the field log book. A decontamination area will be established within the fenced portion east of the warehouse. A pit will be built above ground or excavated in this area with a backhoe and lined with plastic to collect decontamination fluids. All the water , used in the cleaning/decontamination of drilling and sampling equipment will be collected in this pit. This water will be handled in accordance with the investigation derived waste management plan, included as Section 10 of this plan. 4.7. Field I11strumentatio11 The following instruments will be used during the remedial investigation at the FCXS site: 1. pH meter, 2. tllermometer, 3. photo i.oniza tion de tee tor, 4. combustible gas indicator, 5. oxygen meter, 6. radiation survey meter 7. orga11ic vapor analyzer 8. specific conductivity meter All calibration procedures utilized for these instruments will be performed : in accordance with Appendix D of the ECBSOPQAM (17) or the manufacturer's specifications. All calibrations will be recorded in the field log books. ' I I I I I I I I I I g I I I u H n D n R -28 - 4.8. Sample Containers All sample containers will be obtained frorn the contract bottle repository. Sample containers used will be in accordance with the requirements specified in Appendix A of the ECBSOPQAM (17). Table 4-3 is extracted from that manual and provides a description of the analysis, preservatives, and types of containers 1 that will be used during this sampling investigation. 4.9. Sample Analysis All samples will be analyzed for extractable organic compounds (base/neutral and acid extractables), pesticides/PCBs, purgeable organic compounds, metals, 1 cyanide, and a specified list of non-routine pesticide compounds. In addition, all waters will also be analyzed for caprolactum. The analysis will include cill substances in these categories on the Target Compound List (TCL) and the Target Analyte List (TAL). Table 4-4 lists the number of samples anticipated for each media sampled, including QA/QC samples. All analyses will be conducted in accordance with the ASBOQCM (18) or as 1 specified by the existing US-EPA standa1;-"d procedures and protocols for the contract analytical laboratory program. All samples collected for analysis will be booked into the ESD or Contract Laboratory Program (CLP) laboratories through 1 the Regional Sample Control Center (RSCC), to ensure availability of space and continuity of data. ..... I g n R I I I I I I I I I I I I I I I Table 4-3 Sample Containers And Preservatives FCX-Statesville Statesville, North Carolina Water Analysis Analyses Container i Extractable Organics 1 gal., amber glass (includes pesticides/PCBs and herbicides) , Purgeable Organics 3 -40 ml. , glass vi.c1ls ' I 1Metals 1 liter plastic I ,Cyanide 1 liter plastic Soil/Sediment Analysis Analvses Contoiner ~xtractable Organics 1 - 8 oz. glass ~includes pesticides/PCBs 1 and herbicides) ~urgeable Organics Metals ' I Cyanide 1 1 1 4 oz. glass 8 oz. glass 8 oz. glass Preservatives Refrigerated, 4 degrees C 4 drops cone. HCL to pH< 2, refrigerated, 4 degrees C 50 % HN03 to pH< 2, refrigerated, 4 degrees C NaOH to pH>l2, refrigerated, 4 degrees C Preservative Refrigerated, 4 degrees C Refrigerated, 4 degrees C Refrigerated, 4 degrees C Refrigerated, 4 degrees C ***(All containers used for orga11ic samples have Teflon lined caps.)*** I .I I I D R I I I I I Table 4-4 Sample Collection Summary Table FCX-Statesville Statesville, North Carolina Sample Description Anticipated Number of Samples Organic Free Water System Trip and/or Preservative Blanks Equipment Rinse Blank Field Blank Potable Water/Mud Bla11k Surface Water Ground Water Sediment Soil Media Soil/Sediment Water Environmental 4 101, 7 189 189 14 Q6Lill;, 3 6 4 3 2 1 1 1 19 19 20 Subtotal-------------203------------39 Total-- - - - ---- - - - - --242 QA/QC samples include duplicate samples and matrix samples. Blanks and spikes for the CLP have 11ot been included. These totals do not include soil and water samples to be collected as a part of the investigation derived waste management program. Does not include samples to be collected during Phases II and Ill of the .investigation at direct push and permanent well locations. I I I I I I m I I • I I D D I I I I I - 2 9 - 5. QUALITY ASSURANCE Quality assurance (QA) procedures begin in the planning stage and continue through sample collection, analyses, reporting and final review. that will be used to insure data quality are discussed below. 5.1. Organization and Responsibilities The methods The Field Project Coordinator has overall responsibility for field QA and has the day to day responsibility to inst1re that prescribed routine quality control (QC) procedures are applied and documented in the field. Laboratory analyses will be conducted either by the Analytical Support Branch (ASB) or through the contract laboratory program (CLP), with overall responsibility for the ASB laboratory QA resting \\'ith the the Branch Chief. William H. McDaniel, Chief, 1norganic Section and Tom B. Bennett, Chief, Organic Chemistry Section have the responsibility to insure that prescribed routine QC procedures are applied and documented in the ASB laboratory. Wade Knight, Region IV QA Officer, will ensure that QA/QC procedures are applied to any samples sent to the CLP for analysis. 5.2. Sample Collection All samples will be collected in accordance with Section 4 of the ECBSOPQAM (17). The quality assurance and quality control procedures described in this a D H D D I • I I I I I I I I I I I I -30 - mant1al will insure that representative samples are collected from the various media sampled. Duplicate samples will be collected at 10 percent of the sample locations for each matrix. This will provide a check for sampling techniques. In addition, each week water samples are collected, water trip blanks will be prepared with organic-free water from the field organic-free water system for extractable organic ( including pes ticides/PCBs, herbicides and other specified organic compounds) and volatile organic analyses. the trip blanks will be handled and stored with the samples collected from the site. This will provide a check to determine if somples may have been contaminated during handling, storage and shipment. Preservative blanks ~ill be collected at the beginning of the project and at the end of each week water samples are collected to insure the integrity of the preservatives. An initial water sample will be collected from the field organic-free water system prior to its use a11d analyzed for extractable organic (including pesticides/PCBs, l1erl>icides and other specified organic_ compounds), volatile organic compounds, meuils and cy~nicle. Subsequent samples will be collected and ana1yzed from the organic-free \·Jdter system at the end of each week that it is used. Equipment rinse blanks will be collected from equipment cleaned on site, using organic-free water, at least once a week or more frequently at the discretion of the field project manager and analyzed for extractable organic ( including pesticides/PCBs, herbicides and specified organic compounds), volatile organic compounds, metals and cyanide. The equipment rinse blanks will be collected to insure that the sampling equipment is properly field cleaned. Table 4-4 presents anticipated sample count by type for QA/QC samples. R • m m I I I I I I I I I I I I I I I -31 - 5.3. Analytical Procedures All analyses will be conducted in accordance with the Analytical Support Branch Laboratory Operations and Quality Control Manual (ASBLOQCM) (18) or according to the CLP Statement of Work. The ASBLOQCM describes chain of custody, calibration procedures, routine QC checks, and data validation and reporting; it also describes the laboratory's routine procedures for assessing precision and accuracy. 5.3.1. Precision, Accuracy, Representativeness, Completeness, and Comparibility The precision, comparibility and accuracy of sample analysis is addressed i11 the Analytical St1pport Brancl, Laboratory Operations and Quality Control Manual (ASBLOQCM) (18) and the most recent CLP Statement of Work. All samples will be collected in accordance with the Environmental Compliance Branch Standard Operat:ing Procedures and Oualiltv Assurance Manual (ECBSOPQAM), February 1, 1991, (17) as may be modified by this POP, which will result in the collection of representative samples of the various media. Completeness will be acl1ieved for 99 percent of all the samples collected (one percent may be lost as a result of sample breakage in the laboratory or during transportation). It is also anticipated that 99 percent of the samples :analyzed will result in valid data. 5 .4. Audits Routine audits of laboratory activities may be conducted by the Inorganic and Organic Chemistry Sections. Independent laboratory audits may be condt1cted by I I I I I I I I I I -32 - the Region IV, QA Officer or his representative(s). i~F• L-- Any problems identified during these audits will be addressed in a memo to the field project coordinator who will take immediate steps to correct the identified discrepancies. D R n R D I I I I I I I I I I I I I I - 3 3 - 6. SITE SURVEYING Prior to the initiation of well installation and sample collection, the FCXS site and surrounding adjacent areas will be surveyed by ESD and/or contract personnel. A third order survey will be conducted of the study area to define the boundaries of the site, as well as produce a base map. Existing structures, sewer lines, utility right-of-ways, and property boundaries will be included on the map. Procurement of a contract surveyor, if needed, will be the responsi- bility of the project manager. The contract surveyor will be registered in the State of North Carolina. A bench mark will be placed at a desirable location on site so all sampli11g locatio11s can later be surveyed and placed on the bas~ map. Tl1e ESD will lJe respo11sible for surveying the sampling locations, monitoring wells, and any otl1er items of signifigance. g D D m I I I I I I I I I I I I I I I -34 - 7. FIELD SCHEDULE The anticipated field schedule for the initial phase of the investigation is provided in Table 7-1 below. Included in the schedule are the numbers and types of samples that are expected to be collected during each week of the sampting investigation. It should be noted that this is an anticipated schedule that may have to be modified as a result of unforeseen problems (weather, sample location access, etc.). This schedule does not include Phase II and Phase III of the ground water investigation. Tl1ese schedules will be developed at the conclusion of all Phase I sampling activity. I I I I I I I I I I I I I I I I Table 7-1 Field Schedule FCX-Statesville Remedial Investigation Statesville, North Carolina NUMBER OF SAMPLES 1 WEEK OF FIELD TASKS 05/06/91 Establish sample locations and conduct gravity survey in warehouse 05/13/91 Setup field office, .mobilize drill rig, begin piezometer installation, collect background soil, sediment and water samp- les, collect other sediment and surface water and ground water samples from existing wells, begin collection of other soils, including soils associated with drilling. 05/20/91 Continue drilling and piezometer installation, collect soil sample~ associated with drilling, continue to collect other soil samples, begin holes in parking lot and warehouse for soil sampling at those lo~ations. 05/27/91 Sample piezometers, finish soil sa1npling, survey sa1nple, well and piezometer locations. WATER SOIL/SEDIMENT 17 90 8 70 9 48 Subtotal-----34-----------208 1 Sample count includes duplicates, preservative, trip and field blanks. 6 D I m I I I I I I I I I I I I I I I -35 - 8. FIELD HEALTH AND SAFETY PLAN 8.1. Purpose The purpose of this safety plan is to assign responsibilities, establish personnel protection standards, establish mandatory safety operating procedures, and provide for contingencies that may arise while conducting this remedial investigation. All aspects of the field operations must comply with the US-EPA, Region IV, Field Health and Safety (19) manual (which is consistent with US-EPA Orders 1440. 2 and 1440. 3) and Occupation Safety and Heal th Administrntion regulations (29 CFR 1910.120). 8.2. Application The provisions of this sRfety plan are mandatory for all EPA personnel and personnel under contract to EPA involved with this investigation. Application of this safety plan includes the sampling, drilling and associated piezometer and monitoring well installation, and mitigation undertaken on the site or at .fillY off -site areas which may be affected by contamination from the site. All visitors (state, contract, EPA personnel, etc.) will be required to abide by these safety procedures. Refusal to comply with the safety guidelines established will result in the visitors being barred from the site or the suspension of work. 8.3. Responsibilities The field project coordinator (Donald Hunter) and the safety officer (James Gray) will have the primary responsibilities for: I 0 D -I I I I I I I I I I I I I I I I -36 - 1. Assuring that appropriate personnel protection equipment is available and properly utilized by all field operations personnel. 2. Assuring that field personnel are aware of the provisions of this plan, are instructed in the work practices necessary to ensure safety, and in planned procedures for dealing with emergencies. 3. Assuring that personnel are aware of the potential hazards associated with tl1e si.te operations. ~-Supervising the monitoring of safety performance by all personnel to ensure that required work practices are employed. 5. Assuring personnel have had proper safety training before participating in the investigatio11 and have read the Region IV, Field Health and Safetv (19) manual. 6. Correcting any work practices or conditions that may result in injury to personnel or exposure to hazardous substances. 7. Assuring that proper emergency first aid equipment is available (eye wash station, first aid kit, etc.) The safety officer will have the ultimate authority on all safety decisions and can suspend project operations if required safety procedures are not used by field personnel. In addition, prior to the initiation of work each day, a safety I n I I D I m I I I I I I I I I I I I -37 - meeting may be held by the safety officer with field personnel to discuss specific field safety operations that may apply to the day's work. 8.4. Training Requirements All field personnel must have received a minimum of 40 hours of initial per- sonnel protection training off site. Personµel must also receive cardiopulmonary resuscitation (CPR) and first aid training prior to site entry (which can be included in the 40 hours of personnel protection training). All personnel that have never worked at a hazardous waste site will be accompanied by an experienced employee for at least 3 days prior to being expected to work at the site without direct safety supervision. All certifications of training will be provided to the safety officer prior to site entry. The safety officer will maintain a copy of all certifications at the field office for all field personnel. 8.5. Medical Monitoring Prior to site entry all field investigative personnel must undergo a baseline medical examination. The examination should include the basic physical examination, heart status a11d functions (EKG), chest x-ray, pulmonary function, blood work ( full SMAC series, hemogobin cell count and protein levels, acetylcholinesterase activity, heavy metals -lead, cadmium, mercury, arsenic, chromium, and selenium), liver function -f,ull enzyme function, renal function (BUN, creatinine, creatine/creatinine ratio, lipoprotein count and differential uric acid), urinalysis, audiometry -audio spectrum response of the ear and an eye examination -physical co11dition, visual acuity. R m m I I I I I I I I I I I I I I I I -38 - 8.6. Site Safety Considerations A well drilling rig will be used during the remedial field investigation. Although it is not suspected that any waste or other material was b'uried at the site in the anticipated monitoring well locations, drilling operations will precede under the assumption that the possibility exists and that chemical hazards may be e11countered during these operations. The chemicals encountered could result in fires, explosions, and/or the liberation of irritating and possibly toxic v,1pors. It is felt that the likelihood of this occurring is very remote. However, prior to the initiation of the site investigation, the City of Statesville Fire Department and first response unit will be notified by the field project coordinator. They will be notified far enough in advance so they may be adequately prepared to respo11cl to a11y emergencies that may arise at the site. The emergency p11one numbers and the route to the nearest hospital will be posted conspicuously at the field office. It is the responsibility of the safety officer to e11sure that all fi.eld personnel know the route to the hospital and have a copy of the emergency phone numbers. 8.7. Identification of W~ste Material on Site The known contaminants of primary concern on site are pesticides, purgeable halocarbons and polynuclear aromatic hydrocarbons. The specific compounds are listed in Table 8-1. Additional purgeable halocarbons and polynuclear aromatic !1ydrocarbon have bee11 identified as being present but below detection limits in data generated from previot1s sainpling at the site. Appendix A contains material safety data sl1eets and si1nilar information for all known quantifiable contam- inanes at the FCXS site. I g M m I I I I I I I I I I I I I I I -39 - 8.8. Site Monitoring and Routes of Exposure During various phases of tl1e drilling and sampling activities, the site will be monitored with a photoionizaton detector (HNu or TIP II) using a 10.2 EV lamp, an organic vapor analyzer (OVA), a radiation survey meter and/or a combustible gas meter/oxygen meter. It will be the safety officer's responsibility to determine what level of monitoring will be required for each sampling event. Table 8-2 lists the action levels for each of the air monitoring instruments/- meters. If readings on the instruments/meters exceed those listed in Table 8-2, then the personnel must disco11tinue field operations and return to the field office to discuss the findings with the safety officer. It .is felt that pesticide and herbicide ~ontamin_ated dust and airborne soil, present primarily if conditions ~re dry on site, constitute the greatest known chemical risk to field personnel conducting soil sampling outside of the confines of the warel1ol1se 1Juilding. Routes of exposure for these waste would include inh.1 lat ion, ingestion and derma 1 contact. The ingestion route represents minimal risks but the inhalation and dermal routes present possible risks. Therefore, the safety officer will determine what levels of protective clothing will be worn by field personnel to eliminate these risks. It is felt that the greatest exposure risks will occur during drilling of downgradient monitoring wells, during subsurface soil sampling 011 the southern portion of the site, and during soil sampling activities conducted inside the buildings. If conditions are particularly dusty in these areas, combination dust/organic cartridges on full-face respirators will be required. I I I I I I I I I I I I I I I Table 8-1 Previously Identified Contaminants FCX-Statesville Site Statesville, North Carolina Compound Pesticides Chlordane DDD DDE DDT Dieldrin Endrin Aldehyde Heptachlor Epoxide Lindane (and other BHC's) Purgeable Halocarbons Carbon Tetracl1loride Chloroform 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethylene 1,2-Dichloropropane Methylene Chloride Tetracl1loroethylene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethylene Trichlorofluoromethane Ground Water X X X X X X X X X X X X X X X Occurrence (Continued on next page) Soil/Sediment X X X X X X I D I I I I I I I I I I I I I I I Table 8-1 (Cont.) Previously Identified Contaminants FCX-Statesville Site Statesville, North Carolina Compound Purgeable Aromatic Compounds Benzene Toluene Ground Water X x Polynuclear Aromatic Hydrocarbons Acenaphthalene Anthracene Chrysene Fluoranthene Phenanthrene Pyrene Occurrence Soil/Sediment X X X X X X I I n I I I I I I I I I I I I INSTRUMENT Table 8-2 Air Monitoring Action Levels FCX-Statesville Statesville, North Carolina PHOTOIONIZATION DETECTOR ( 10. 2 EV LAMP) ORGANIC VAPOR ANALYZER COMBUSTIBLE GAS METER OXYGEN METER RADIATION SURVEY METER ACTION LEVEL 5 ppm Above Background 5 ppm Above Background 20% Lower Explosive Limit 20% Oxygen Above Background If any reading on the meters exceed (or is less than for the oxygen meter) the Action Levels listed above then personnel must immediately return to the field office for further instructions. • • m I n D g D D I I I I I I I I I I -40 - 8.9. Protective Clothing Levels of protection referred to in the subsequent sections are defined in the Region IV, Field Health and Safety (19) m'anual. 8.9.1. Gloves All personnel will have Category I, Level B thru Level D protective clothing available to wear. The protective clothing and gloves required to be worn will be mandated by the safety officer and may differ from one sampling location to the next. 8.9.2. Head Gear Hard hats will be worn by all personnel when working or observing within a mast length of the drill rig and at other locations when advised by the safety officer. 8.9.3. Eye Protection All personnel will be required to wear safety glasses on site. Face shields and goggles will also be available. Contact lens will not be permitted to be worn at the site. 8.9.4. Boots Steel-toed and steel-shank rubber or leather boots will be required to be worn on site. I m I I I I I I I I I I I I I I I I I -41 - 8.9.5. Respiratory Protection The respiratory protection that will be made available to field personnel will be: • Positive pressure, self-contained breathing apparatus (ISI Ranger) • Five minute air escape capsules (ISI ELSA) • Air purifying respirators with appropriate cartridges (MSA ultra twin) Only NIOSH/MSHA approved equipment will be used. The safety officer will determine what level of respiratory protection will be required for the field personnel by using the air monitoring equipment. 8.10. Emergency Contingency Plan 011-site e1nergencies could l)e expected to result from fire, che1nical exposure or personnel casualty. If a11 incident occurs necessitating a response to an e1nergency, the project leader or safety officer will use the two-way radios to communicate the emergency to personnel on site and/or sound an emergency horn. The signal will be of at least 5 short blasts (each of about 1 second duration). Personnel on site will immediately discontinue field operations and assemble at the field office (command post). The emergency numbers will be posted at the field office. Appendix B contains the stand-alone site safety plan with emergency pl1one numbers, as well as directions and a map to Davis Hospital, one 1nile east of the site. I n e D I I I I I I I I I I I I I I I -42 - 9. DRILLING, PIEZOMETER AND MONITORING WELL CONSTRUCTION SPECIFICATIONS 9.1. Monitoring Plan Drilling related monitoring activities at the FCXS site will include the installation of four (4) piezometers during Phase I activities and an undertermined number of monitoring wells during subsequent phases of the investigation. The locations of the proposed piezometers is shown on Figure 2-3. The number and placement of monitoring well locations, as well as the need for shallow and deep surficial well clusters, will be determined after evaluating water level data and ground water contaminant data from the piezometers and existing monitoring wells and insitu samples collected during Phase II activity at the site. The piezorneters will be installed at selected soil sampling locations at the site. After completion of soil sa1nple collection at each location, tl1e borehole will be completed to refusal, interpreted as bedrock. File information for the existing monitoring wells indicates refusal occurrs between fifty (50) to seventy- five (75) feet below land surface (BLS). Water levels in these wells range from about thirty-five (35) feet to about forty-five (45) feet BLS. Based on this information, it is anticipated that the piezometers will be completed with fifteen (15)-feet of screened interval after reaching refusal. The piezometers will be constructed using 2-inch diameter, Schedule 40 polyvinyl chloride (PVC) casing and No. 10 slot PVC screen. Each piezometer will be packed with twenty (20) feet of 30/40 mesh Ottawa sand, sealed above the sand pack with bentonite pellets and grouted, from the top of the pellets to the surface, with I D M I D I fi D I I I I I I I I I I I - 4 3 a pure, high solids bentonite grout. The grout will have a weight of 9.4 lbs/gal. After allowing the grout to set overnight, a minimum two-feet diameter, four-inch thick concrete pad will be poured and fitted with a locking protective cover. A schematic of a typical piezometer is presented in Figure 9-1. After water levels have stabilized in the piezometers, water levels will be obtained for all wells and piezometers on site and ground water flow directions will be ascertained. Based on both this evaluation, and the results of the insitu ground water screening, an appropriate number of shallow, and if appropriate, deep surficial permanent monitoring wells will located. It is anticipated that up to two (2) bedrock wells will also be needed to evaluate off-site migration in the fractured bedrock portion of the aquifer. These wells will be installed during a subsequent phase of the investigation. Construction of the permanent surficial monitoring wells will be si1nilar to that of the piezometers. The permanent surficial wells will be constructed, however, using 2-inch diameter stainless steel risers and screens. The deep wells will be constructed using 4-inch diameter stainless steel riser grouted in place above an open-hole interval, Stainless steel wi.11 be used for the monitoring wells because of the known contaminants and the long-term duration of the 1nonitoring system. Addi- tionally, each permanent monitoring well will be completed with a locking protective casing installed into the concrete pad. A schematic of a typical monitor well cluster is presented in Figure 9-2. A schematic of a typical deep, bedrock well is presented i11 Figure 9-3. I I I I I I I I I I I I I I I I I I I 4'x 4'x 6" CONCRETE PAD FROST LINE v APPROXIMATE WATER LEVEL (35' BLS) COMPETENT BEDROCK STEEL VENTED PROTECTIVE ;f co~es '" coo<S F====~ CAP WEEP HOLE ---- ---------- VOL CLAY GROUT SCHEDULE 40 PVC (2" DIA.) BENTONITE SEAL (2') (OPTIONAL) SAND PACK PVC WELL SCREEN (2" DIA., 10'-15' LENGTH) FIGURE 9-1 TYPICAL PIEZOMETER FCX-STATESVILLE STATESVILLE, NORTH CAROLINA m n I I I I I I I I I I I I I I I 3'X 3'X 6" CONCRETE PAD FROST LINE v APPROXIMATE WATER LEVEL (35' BLS) ~EPA STEEL VENTED PRDTECTIVE /, COVERS AND LOCKS r:::::==/,.., I VENTED CAP FROST LINE VOLCLAY GROUT STAINLESS STEEL (2" DIA.) BENTONITE SEAL (2') SAND PACK STAINLESS STEEL WELL SCREEN (2" DIA., 1 O' LENGTH) DENSE PHASE IBAP COMPETENT BEDROCK (~70' BLS) FIGURE 9-2 I TYPICAL WELL CLUSTER FCX-STATESVILLE STATESVILLE, NORTH CAROLINA I I I I I I I I I I I I I I I I I I I CEMENT-FILLED BULLARDS, J~X 5' . 'I I" .. . ·1 r . · ---. -_-·-f· I • .••• _---. :l / .. ~EPA LOCKING PROTECTIVE CASING VENTED. THREADED CAP . .I I. . CEMENT PAD, SLOPES AWAY FROM PROTECTIVE CASING (3'X 3'X 6") . . I l;c·-'-'--'--'----'--'- : : : : : ~) ~_o~r: ~N~ : : . . . B~ NOMINAL WET ROTARY DRILLED BOREHOLE . . 4~ STAINLESS STEEL CASING/RISER, · . : PRESSURE GROUTED INTO ;r BEDROCK RECESS · CEMENT /BENTONITE GROUT · . FIGURE 9-3 OPEN HOLE BEDROCK MONITORING WELL ,FCX-STATESVILLE STATESVILLE, NORTH CAROLINA H I I I I I I I I I • H I I I I I I I -44 - 9.2. Scope of Work The scope of work for drilling services is as follows: Phase I • Install four (4) Schedule 40 PVC piezometers to depths of approximately 50 feet. • Collect split-spoon (ASTM Method 1586) or equivalent samples at each piezometer location. Five samples will be collected at each location, beginning at the Sl1rface and continuing at five foot intervals to a depth of 22 (twenty-two) feet. The driller should be prepared with at least five (5) standard-cleaned (according to the Region IV ECB SOPQAJ-1 (17) and adequately air-dryed split-spoons at each well, e.g., no cleaning of split spoons used to collect samples for chemical analyses will be allowed at the well site. After a]l samples to be analyzed are collected, t.he spoons 1nay the11 1,e c].eaned 3t tl1e well site and used for logging purposes and collection of samples for physical characteristic testing. • Collect soil samples from approximately 40 feet BLS to be used for soil classification. This information will be used to select the appropriate screen size for tl,e permanent monitoring wells. Phase II • Drilling activity during Phase II will consist of solid and/or hollow stem augering to support the direct push sampling effort. It is anticipated that at1gers will be used to complete boreholes to within two I I I I I I I I I I I I I m D D I I I -45 - to three feet of the selected sampling interval, at which point the augers or center stems will be pulled and the insitu sample tip driven to the samping interval. As this methodology is currently under development, no more detailed specifications will be provided in this project operations plan. Phase II I • Install approximately six (6) permanent ground water monitoring well clusters, 2-inch diameter stainless steel riser and screen, approximate • depths of 50 (fifty) and 70 (seventy) feet. Install two (2) permanent bedrock ground water monitoring wells, 4-inch diameter stainless steel riser grouted in-place at bedrock/regolith interface (approximately 80 feet BLS) and completed open hole to an anticipated depth of approximately 125 feet BLS. 9.3. Technical Specifications for Drilling Operations 9.3.1 General Drilling will be required for a number of operations at the FCXS site, including installation of piezometers, surficial monitoring wells, and deep, bedrock monitoring wells. All drilling and well installation will be done in- accordance with all state and local regulations and the following specifications. An EPA representative will observe all drilling operations, decontamination procedures and piezo1neter/monitoring well location. u I I I I I I I I I I D I I I I I I I -46 - 9.3.2 Piezometer Specifications The piezometers shall be constructed with Schedule 40 PVC threaded, flush- joint riser and screen (0.010 in. slots) extending 2-ft., 6-in. above surface. All piezometers will have a threaded plug on the bottom of the screen, a vented, threaded cap, and protective casings. 0-rings will be removed and all threads taped with Teflon® tape. All piezometers shall be installed using 6.25-inch I.D. hollow stem augers. The piezometers will be co11structed inside the hollow stem as they are slowly being retracted. The piezometers will be screened with approximately 15-20 feet of 2-inch diameter screen (0.010 in. slots). The screen will be delivered to the site in 5 foot sections and will be combined, as necessary, to meet the screen requirements at each locatio11. The driller should have a minimum of 80 feet of screen (sixteen (16) 5-foot sections) delivered to the site to meet these reqt1irements. Likewise, it i.s anticipated tl1at approximately one-hundred (100) to one-hundred and sixty (160) feet of casing/riser will be required to complement the screens for all of the piezometers. The casing lengths should be a mix of 10 foot and 5 foot sections. The threaded flush joint riser will extend to approxi- 1nately 2-ft., 6-in. above the surface. A clean, bagged silica sand pack, sized for use with 0.010 inch slot size screen, will be placed, via tremie pipe, in the annulus to a depth of five (5) feet above the screen. A bentonite pellet seal, minimum two foot thickness, will be placed, using the tremie tube, above the sand pack. The elevations of the top of the sand pack and the bentonite pellet seal will be constantly checked using a weighted tape or 11 tag line 11 to insure that the cons true tion spec i fie a tions a re met. Organic-free water will be added, if needed, to hydrate the bentonite pellets in the absence of formation water. A high I I I I I I I I I I I I • n n I I I I -47 - solids, pure bentonite grout, mixed to a weight of at least 9.4 pounds per gallon, will be used to fill the annulus from the bentonite seal to within 2-ft. of the surface. The grout will be pumped, via tremie tube, into the annular space and will be emplaced from the seal upward. Through the use of elbows on the end of the tremie tube, reduction of pumping velocities, or other means, efforts will be made to reduce the potential for jetting of the bentonite pellet seal during grouting. A mud balance will be used to check the weight of the grout exiting the annulus, after the last auger is extracted, to insure that the hole is satisfactorily grouted. After Che grout has set, the wells will be finished off, as described i11 detail below, with a concrete pad and locking, protective casing. All wells will have minimum 4-inch square steel protective casings with vented, hinged, locki.ng well cover and 3-ft. square concrete (3-ft. square by 6-i11. thick) pads a11d per1na11e11t J.D. tags. Pads will have an edge thickness of 6-in. but should be thicker ne.:,r the protective casing, i.e. pads should be sloped to promote runoff. A one-qttarter inch hole should be drilled, on opposite sides, in the protective casing, at the base of the stickup, to allow water drainage from inside the protective casing. The pads will extend two feet down into the borehole or to the frost line whichever is greater and be bonded to the grout . Three concrete-filled steel pipe bull.ards (bumpers), 3 to 4-inch diameter and 3-feet high, will be installed in ectch pad. construction details. Figure 9. 1 shows typical piezometer 9.3.3 Surficial Monitoring Well Specifications The wells shall be constructed with stainless steel wire-wrapped screen (0.010 in. slots) and threaded flush joint 1·iser pipe extending 2-ft., 6-in. above D I I I I I I I I I I I I I I I I I I -48 - surface. All wells will have a threaded plug on the bottom of the screen, a vented, threaded cap, and protective casings. All wells shall be installed using 6.25-inch I.D. hollow stem augers. These wells will be constructed inside the hollow stem as they are slowly being retract- ed. The wells will be screened with approximately 10 to 20 feet of 2-inch dia- meter screen. Screen slot size will be determined after geotechnical evaluation of soil collected from the anticipated scre~ned interval. The specified screen will be delivered to the site in 10-feet and 5-feet sections and will be combined, as necessary, to 1neet the screen requirements at each location. F6r the currently anticipated number of wells, the driller should have a minimum of 120 feet of screen delivered to the site to meet these requirements. Likewise, it is anticipated that approximately 600 feet of casing/riser will be required to co1nplement the screens for all wells. The casing lengths should be a mix of 10 - foot and 5 foot: sections. The threaded flush joint riser will extend to approximately 2-ft., 6-in. above the surface. A clean, bagged silica sand pack, sized for use with the specified screen slot size, will be placed, via tremie pipe, in the annulus to a depth of at least one foot above the screen. A bentonite pellet seal, minimum two foot thickness, will be placed, using the tremie tube, above the sand pack. The elevations of the top of the sand pack and the bentonite pellet seal will be constantly checked using a weighted tape or "tag line'' to insure tl1at the construction specifications are met. Organic-free water will be added, if needed, to hydrate the bentonite pellets in the absence of formation water. A high solids, pure bentonite grout, mixed to a weight of at least 9.4 pounds per gallon, will be used to fill the annulus from the bentonite senl to within 2-ft. of t\1e surface. The grout will be pumped, via tremie tube into the arinular space and will be emplaced from the seal upward. Through the use of elbows on the end of the tremie tube, reduction of pumping velocities, or other I I I I I I I I I I I I g u I I I I I -49.- means, efforts will be made to reduce the potential for jetting of the bentonite pellet seal during grouting. A mud balance will be used to check the weight of the grout exiting the annulus, after the last auger is extracted, to insure that the hole is satisfactorily grouted. After the grout has set, the wells will be finished off, as described in detail below, with a concrete pad and locking, protective casing. All wells will have minimum 4-inch square steel protective casings with vented, hinged, locking well cover and 3-ft. square concrete (3-ft. square by 6-in. thick) pads a11d perma11ent I.D. tags. ,Pads will have an edge thickness of 6-in. but should be thicker nedr the protective casing, i.e. pads should be sloped to promote runoff. A one-qunrter inch hole should be drilled, on opposite sides, in the protective casing, at tl1e base of thJ stick-up, to allow water drai11age from inside the protective casing. The pads will extend two feet down into the borehole or to the frost line whichever is greater and be bonded to the grout. Three concrete filled steel pipe bumpers, 3 to 4-inch diameter and 3-feet high, will be installed in e~ch p~d. Bedrock Monitoring Well Drilling Specifications The wells shall be constructed with stainless steel riser grouted in-place withi11 a minimum of three feet of competent bedrock below the regolith/bedrock boundary. The riser will be threaded, flush-joint casing extending 2-ft., 6-in. above surface. All wells will have a vented, threaded cap, and protective casings set in concrete pads, as described below. The regolith/overburden and the first three (3) feet of competent, unweathered bedrock will be drilled using mud rotary with a.nominal 8-inch tri-cone rock bit. I I I I I I I I I I I I I I D I I I I -50 - After the borehole is completed to this depth, mud will be cirulated to clean the hole of all rock fragments. The well casing will then be installed with a grout shoe placed at the lower end of the casing. The well casing/grout string assembly will be raised enough to allow pumping of grout. The annular space between the casing and the borehole will then be pressure-grouted with a cement/bentonite grout through the grout shoe until all mud is flushed from the annulus and grout is observed. When grout is seen exiting the surface, the casing will be seated in the bottom of the recess in the bedrock surface and.the grout string removed. After the grout string is removed, the well will be checked periodically to ensure that 110 grout is leaking into the riser. Mud or water may be added to prevent grout from flowing back into the riser. rf'used, it should be flushed from the riser and discarded prior to completion of the well. The grout will be allowed to cure for at least 24 hours. After the grout has set, drilling will continue using water and a nominal 3-inch diameter diamond coring bit. Drilling will contint1e until significant secondary permeability features (fractures, open schistose or gneissoid textures, etc.) are observed in the cores. At these indications, drilling will cease and water will be removed from the borehole by air, bailing or pumping and the recovery observed. The EPA geologist will, based on tl1ese recovery observations, make the determination to cease or continue drilling. At the completion depth, the well will be flushed of all drilling materials and completed on the ~urface. All 4-inch wells will have minimum 6-inch square steel protective casings with vented, hinged, locking well cover and 3-ft. square concrete (3-ft. square by 6-in. thick) pads and permanent I.D. tags. Pads will have an edge thickness of 6-in. but should be thicker near the protective casing, i.e. pads should be sloped I I I I I I I I I I I I I I I I I • I -51 - to promote runoff. A one-quarter inch hole should be drilled, on opposite s_ides, in the protective casing, at the base of the stick-up, to allow water drainage from inside the protective casing. The pads will extend two feet down into the borehole or to the frost line whichever is greater and be bonded to the grout. Three concrete filled steel pipe bumpers, 3 to 4-inch diameter and 3-feet high, will be installed in each pad. Figure 9-3 is a schematic of the proposed ~ypical bedrock well installation. 9.3.5 Miscellaneous Drilling Specifications The driller should be prepared to water-rotary advance all specified auger- drilled boreholes if deemed 11ecessary by the site geologist. If subsurface conditions exist so that water rotary cannot be utilized, mud rotary will be substituted. The driller shall supply a tank (truck or trailer mounted) for potable water used for drilling, mixing grout, tre1nming sa11d, equipment decontamination, etc. The tank shall be clean and free of all foreign matter and will be subject to the on-site decontamination procedures and quality control protocols. The driller will be responsible for making arrangements to obtain potable water for drilling. All grout will be mixed in a manner to assure a uniform product. Suitable methods include commercially available grout mixers and stock tanks with high pressure/high volume circulation systems (tr,ash pumps or diaphram pumps). Other methods will be considered for approval by the on-site EPA geologist. I R I I I I I I I I I I I I I I I n -52 - 9.3.6. Plugged and Abandoned Wells If any boreholes are deemed unsuitable for monitoring installation by the on-site geologist, the driller will plug and abandon the borehole as required by state regulations or as directed by the EPA geologist. Abandonment would typically involve grouting the entire borehole with cement or other another acceptable grout mixture. 9.3.7. Boring Log Tl1e purpose of this log is to provide EPA with a record of the dimensions of the hole, drilling methods used, any drilling problems encountered, and the general character of the subsurface material pe11etrated. The log will include the following: a. Name and address of the drilling company. b. Dates and times of starting, stopping, and completion of the boring. c. Naine of the driller. d. e. f. g. h. i. j. k. Diameter a11d depth of boring and record of casing. Make and type of equipment used, including methods of advancing the hole and obtaining samples. Data for any split-spoon sample required, including blows. Descriptions of all soil and rock strata encountered with the driller's best estimate of the depths at which changes in material occur. Descriptions of water levels and behavior of drilling fluid, if use6. Observations of any unusual drill t-ool behavior. Dates, times, and depths of ground water observations. All information where specified in the specification. D R m I I I I I I I I I I I I I I I I -53 - The driller will also keep a record of the construction design, materials, and amounts· of materials used in each monitoring well. This will include diameter of casing, depths and lengths of all well screens, type of screen pack, and location of screen packs. Other data may be requested by EPA. This record will be due at the completion of the project. 9.4. Decontamination The driller will furnish the necessary equipment and manpower to perform all on-site decontamination. The drill rig should be cleaned and prepped prior to arrival on-site all grease a11d oil removed, all hydraulic fittings secure, etc. EPA will inspect all down-hole equipment prior to usage. drilling equipment will be performed between each hole. Decontamination of The driller will be required to have 011-site two sets of down hole drilling and sampling equipment (auger flites, bits, split spoon samplers, etc.) to decrease standby time during the drilling operation. If any sampling equipment is used to collect samples tl1at contain oil, grease, or other hard-to-remove materials, it may be necessary to rinse the equipment several times with pesticide grade acetone or hexane to remove the materials before proceeding with site decontamination procedures. These conditions are not anticipated at the FCXS site, however. If down hole drilling equipment is painted, badly rusted, or coated with materials that are difficult to remove, it will be required to steam clean, wire brush, or sandblast the equipment before proceeding. This is to be performed before mobilization to the job site. Any sampling equipment that cannot be cleaned I using these procedures should be discarded. The driller will supply a decontamination team, staffed separately I I I I I I I I I I I I I I I I I I I -54 - from the dril 1 ing team, so that decontamination can precede concurr_ently with drilling. The team will follow the direction of the EPA geol~gist or other on-site EPA or EPA authorized personnel, as appropriate. Normally, any portion of the drill rig, backhoe, etc. that is over the borehole (Kelly bar, or mast, backhoe buckets, drilling platform, hoist or chain pulldowns and/or cathead, etc.) must be steam cleaned and wire brushed before being brought on site to remove all rust, soil and other material which may have come from other hazardous waste sites. The drill rig should then be inspected to insure that all oil, grease, hydraulic fluid, etc. has been removed, all seals and gaskets are intact and no fluids are leaking. Steam cleaning of the drill rig is then required prior to drilling each borehole. In addition, all downhole drilling, sampling, and associated equipment that will come into contact with the downhole equipment and sa~ple medium shall be decontaminated by the following procedure, as specified in the Region IV ECBSOP/OAf!. February 1, 1991. A copy will be provided, if requested. 1. Clean with tap water and laboratory grade detergent, using a brush, if necessary, to remove particulate matter and surface films. Steam cleaning may be necessary to remove matter that is difficult to remove with the brush. 2. Rinse thoroughly with tap water. 3. Rinse thoroughly with deionized water. I I I I I I I I I I I I n I I I I I I -55 - 4. Rinse twice with solvent (pesticide grade isopropanol). 5. Rinse thoroughly with organic-free water and allow to air dry as long as possible. If organic-free water is not available, allow the equipment to air dry as long as possible. Do not rinse with deionized or distilled water. NOTE: Organic-free water can be processed on site by purchasing or leasing a mobile deionization-organic filtration system. NOTE: Tap water may be applied with a pump sprayer. All other decontamination liquids (D.I. water, organic-free water, and solvents), however, must be applied using non-interferring contai11ers. These containers will be made of glass, Teflon, or stainless steel. No plastic containers or pu1np sprayers will be allowed. This aspect of the decontamination procedures used by the driller will be inspected by the site geologisf prior to beginning of operations. 6. Wrap with alumninum foil, if appropriate, to prevent contamination if equipment is going to be stored or transported. Clean plastic can be used to wrap augers, drill stems, casings, etc. if they have been air dryed. 7. As previously stated, all downhole augering, drilling and sampling equipment shall be sandblasted before Step #l if there is a buildup of rust, hard or caked matter and/or painted I I I I I I I I I I I I I I D I I ,I I -56 - equipment. All sandblasting shall be performed prior to arrival on site. All equipment shall be subject to inspection by EPA upon arrival on site. Decontamination of all equipment shall occur at a decontamination pit, either excavated or built above grade. The pit and surrounding area will be lined with heavy duty plastic film of sufficient width to provide a seamless, lapless liner for the pit. All cleaning of drill rod, aug'er flights, well screen and casing, etc. will be conducted above the plastic film using saw horses or other appropriate mea11s. As the pit is filled, the water will be pumped by the driller into drums for proper disposal. EPA will assume responsibility for disposal of this material as described in Section 10 of the Project Operations Plan. No solvent ri11sates will lJe placed in the pj_t_ All solvent rinsates will. be collected in separate containers and handled by EPA in accordance with the procedures specified in Sectio11 10 of the Project Operations Plan. 9.5. Monitor Well Development Monitor wells must not be developed for a period of 24 hours after installation. All installed wells shall be adequately developed prior to initial sampling efforts. Adequate development should eliminate all fine material from the area of the well screen, and allow for the collection of a sample which is as free as practical of suspended materials and is clear as achievable. Depending on the nature of the overburden, wells installed in this material may I I I I I I I I I I • I D I I I I I I -57 - not develop to absolute clarity; slight turbidity will be allowed if the driller can demonstrate that the development method chosen is suitable for the conditions and a point of diminishing returns has been reached with development efforts. Wells installed in bedrock should develop to a high degree of clarity. Various methods may be used to develop wells at the FCXS site. These methods consist of pumping, bailing, lifting the water column with compressed air, plunging-surging, etc. If compressed air is used, the air must be filtered to remove all oil and grease. The driller must periodically measure the pH and specific conductance of water removed during well development to evaluate the adequacy of development. This information will be recorded in a log to be relinquished to the EPA project geologist after all development is completed. All materials introduced into the wells during development, such as air lines, pumps, etc. will be subject to decontamination procedures. 9.6. On-site Waste Storage and Disposal At the direction of the EPA representative, and in compliance with all fede1·al, state, and local rules, regulations, and permit requirements, any and all wastes (cuttings, develop111ent water, decontamination wastewater, etc.) which have been generated due to this contract will be containerized in 55-gallon drums and left on site. These investigation derived wastes will be evaulated and handled according to the Investigation Derived Waste Management Plan included as Section 10 of the Project Operations Plan. • I I I I I I I I I I I • g n I I I I -58 - 9.7. Site Cleanup Upon completion of all work described in these specifications and after decontamination, the driller shall also remove from the site all containers, drums, tanks, debris, and unused materials, and restore the site as close as practicable to its condition prior to conimencement of the work provided for herein. The driller should schedule the use of a dumpster through a local waste management firm to collect waste generated during the drilling project. All walks, drives, utilities, structures, or other property damage due to the driller's negligence shall be restored at his expense to as nearly as possible their original conditions. Payment for work shall not be completed until the EPA representative approves the cleanup at the completion of the work. 9.8. Site Restoratio11 The drilling site shall be restored as close as possible to the original condition prior to drilling. No trash, fluid, or other foreign materials shall remain at drilling sites. Drilling sites will be restored immediately after completion of tl1e borehole at that particular site. The boring and/or monitor well will not be considered co1nplete for payment until the EPA representative approves the drill site restoration in his daily or weekly report. 9.9 Health and Safety The driller and all responsible parties under his/her supervision must adhere to the site Health and Safety Plan (HASP), to be provided by EPA upon award of the contract. The personnel under the direct control of the driller must meet I I I I I I I I I I I I I I • I D D R -59 - the requirements of this HASP and, when required by site conditions, follow the directions of the EPA Site Health and Safety Officer (HSO) to protect personnel and/or the environment. 9.10 Security The drillers shall be responsible for securing their equipment and materials at the site. EPA will maintain an on-site office trailer and can provide limited secure storage of small items. The portion of the site on which the trailer will be parked is secl1red with chain-link fencini with a locked gate. An after hours guard will be secured for the drilling period. 9 .11 Protective Equipment and Clothing, Utilities, and Services The driller shall supply all necessary equipment and clothing for Level D and Level C protection. EPA will designate the parking, equipment storage, and personnel deconta1nination are6s. 9.12 Medical Surveillance EPA requires that all persons operating.at a work site participate in the medical surveillance and liealth and Safety Training program. As part of this program, the dri~ler must fulfill the following requirements: • All members of the drilling crew must fulfill the following training requirements before entering the AB&P Site. a. Pass the Red Cross Basic First Aid Course; I -60 - I b. Be certified by Red Cross to perform CPR; c. Complete 40 hours of OSHA-approved Personnel Protection and Safety I Training. I I I I I I I I I I I I I I I • The driller must ensure that all employees working on-site have obtained a comprehensive medical-physical examination (or equivalent) within one year prior to the date scheduled to work on an EPA site. This physical examination must include tests to certify an employee's ability to wear a respirator. Before commencing work and within five calendar days from date of field mobilization, the driller will be required to provide EPA with a physician's statement medically qualifying each employee. • EPA will conduct a fundamental Health and Safety meeting for the driller's employees their first day on-site. This meeting is not a substitute for the 40 hours of OSHA required training. 9.13 Support of Commu11ity Relations The driller shall make every effort to maintain good relations with adjacent property owners and occupants. All on-site drilling personnel should be made thoroughly cognizant of the importance of this aspect of the work and its sensitivity to the entire program, as well as to th~ successful completion of their particular assignme11t. All field activities sl1all be conducted in an efficient and professional manner, with minimum practical damage to the site environment. Thus, tree and I I I I I I I I I I I I I I I I I I I -61 - brush removal and similar impacts upon the existing site environment shall be limited to only those approved by EPA. 9.14 Project Schedule The driller shall make every effort to maintain the schedule. The driller· shall base the cost estimate on 10-hour days, 10 days on, 4 days off. The driller shall be willing to mobilize to the project site within two weeks of notification from EPA. 9.15 Cost Estimate The cost estimate must be in unit form to include a unit-price breakdown. All payments will be on actunl footages obtained in the field. All well materials will be supplied by the driller. The driller must obtain all permits and legalities that are necessary from the proper authorities and shall have all the current and necessary licenses and registrations required by state and local authorities. The driller's cost estimate will be written under the assumption of work to be performed in Level D protection. 9.16 Measurement and Payment At the satisfactory completion of all of the work described herein, the EPA geologist will recommend payme11t on receipt of the driller's invoice and other requested documentatio11. If Level C protection is required for on-site work I I I I I I I I I I I I I I I I 0 I B -62 - instead of the base Level D protection, EPA will provide a form on which the EPA geologist and the driller will each initial the starting and completion times for each of driller's personnel performing the particular work task in Level C protection. Payment for the task(s) will then be based on the number of personnel, elapsed time, and the respective quoted hourly rate above that of Level D protection.· I I I I I I I I I I I I I I I I I I 11 -63 - SECTION 10. INVESTIGATION DERIVED WASTE MANAGEMENT PLAN 10.1 General During the course of the investigation, a variety of investigation derived wastes (IDW) will be generated which may require special management and disposition. The following is a description of the anticipated types of IDW followed by the protocol to be followed t~ evaluate the handling a disposition of these wastes. 10.2 Investigation Derived Waste Categories 10.2.1 Drilling Waste All drill cuttings generated during piezometer and well installation will be containerized in 55-gallon drums. Any cuttings generated at a location beyond· the controlled access portion of the site will be transported to a secure area of the site. Cuttings generated within the. secure area may be containerized and stored at the drilling location. At approximately five-foot intervals during drilling, a sample of the auger cuttings will be collected and retained in a glass pan. After the borehole is completed, anticipated to be at a depth of approximately 50 feet, a composite sample will be prepared from all of the five- foot soil aliquots. Any subsequent borings completed within 10 feet of a previous boring will not have to be sampled for waste disposition purposes. /, I I I I I I I I I I ,, I I I I I I I I -64 - 10.2.2 Monitoring Well Development and Purge Water All water generated during development and purging of monitoring wells installed during the remedial investigation will be containerized in 55-gallon drums. This water will be held in a secure location on site until analyses are completed for the first round of ground water sampling. If analyses of samples collected during the first round of samples indicates that ground water from a particular location does not pose a substantial threat to human health or the environment, purge water from subsequent sampling events may be discharged directly to the ground no less than ten feet from the monitoring well. 10.2.3 Decontamination Pit Conten~s All water generated during decontamination of the drill rig and other equipment will be co11tained wit\1in a decontamination pit lined with heavy duty plastic. At the end of each day, or as the pit becomes full, the contents of the pit will be pumped into 55-gallon drums. At the completion of all site sampling. activities, a composite sample will be prepared from a random sample of one-half of all drums containing aqueous decontamination fluids. 10.2.4 Waste Solvents It is anticipated that isopropanol, generated during solvent rinsing of sampling equipment, will comprise the majority, if not the sole constituent, of this category. All solvent rinsing will be conducted over galvanized wash tubs or other large containers in such a manner that all solvents are recovered. All solvent remaining in the co11tainer at the end of the day will be re-containerized I I I I I I I I I I I I I I I I ' I I -65 - in the original one-gallon jugs, placed in the factory shipping boxes and returned to the ESD laboratory. This material will be bulked with other waste isopropanol and entered into the laboratory's hazardous waste tracking system for appropriate disposal. 10.2.5 Clothing and Miscellaneous Trash Significant amounts of soiled Tyvek, gloves, paper towels, and other site- related trash will be generated during the course of the investigation. It is not anticipated that this material will constitute a significant threat to human health or the environment and, as such, it will be placed in large capacity plastic garbage bags. As these garbage bags are filled, the tops will be twisted a11d securely taped. A commercinl dumpster will be contracted for the duration of the investigatio11. All waste generated within this category will be placed in the dumpster. 10.3 Evaluation of Analytical Results of Investigation Derived Waste After all IDW analytical results are received, the data will be submitted to the R_isk Assessment Officer (RAO), Waste Management Divison, for evaluation. If, in the opinion of the RAO, any of the IDW would pose a substantial or significant risk to human health or the environment if discarded to the ground at the site, it will be managed as a hazardous waste and sent to a RCRA-approved hazardous waste disposal or treatment facility. If the material poses no risk, it will be applied to the land surface wi.thin the secure eastern area of the FCXS site. I I I I I I I I I I I I I I I I ' I REFERENCES 1. United States Environmental Protection Agency, Guidance on Remedial Investigations Under CERCLA, EPA/540/G-85/002, J~ne 1985. 2. United States Department Carolina), Quadrangle, 7.5 of the Interior , ,S:..,t,.,a,,;t:;ee.sscv-"-'i'-'l'-'l"'e~_,W,_,e~s,,_t,,__(,..N"'o""'r"'t""h Minute Series Topographic Map, 1969. 3. Fred C. Hart, Environmental Evaluation Report: FCX Distribution Center, Prepared for Souther States Cooperative, Inc., February 27, 1986. 4. North Carolina Department of Human ~esources, Division of Health Services, Preliminarv Assessment Report, FCX-Statesville, March 1986. 5. North Carolina Department of Human Resources, Services, Site Assessment Report, FCX-Statesville, Division of March 1987. Health 6. Weston•SPER, Rigger, OSC. Memorandum from Bethany Hunton, TAT Region IV to Don EPA Region IV, Subject: FCX-Statesville, February 19, 1990. 7. Don Rigger, OSC, EPA Region IV, Personal Communication. 8. Debbie von \~right, Site Assessment Section, EPA Region IV, Personal Communication. 9. U.S. Department of Agriculture, Soil Survey, Iredell Countv, North Caroline, June 1964. 10. NUS, Draft Screening Site Inspection Report, Burlington Industries, Statesville North Carolina, in progress, January 1991. 11. U.S. Geological Survey Water Resources Investigations Open File Report 80-44, Basic Elements of Grou11d Water Geology. 12. Harry E. LeGrand, Geoloev and Groundwater in the Statesville Area, NC, NC Departme11t of Conservation and Development, Bulletin No. 68, 1954. 13. Memorandum: From Mark Rigatti, O.H. Materials, to Don Rigger, OSC, EPA Region IV, Subject: Deep Well Specifications, FCX-Statesville, October 1989. 14. OHM Analytical Data Report, FCX-Statesville, Project Number 6803S. 15. P.E. LaMoreaux and Statesville, January Associates, Analytical 1990, Transmitted to Mark Data Report for FCX- Rigatti, O.H. Materials. 16. United States Environmental Protection Agency, Data Quality Objectives for Remedial Response Activities Volume 1, Development Process, EPA 540/G-87/003A, March 1987. 17. United States Environmental Protection Agency, Region IV, Environmental Services Division, Environmental Compliance Branch Standard Operating Procedures and Ouali ty Assurance Manual, 'February 1, 1991. I I I I I I I I I I II I I ..._ I REFERENCES (Continued) 18. United States Environmental Protection Agency, Region IV, Environmental Services Division, Analytical Support Branch Operations and Quality Control Manual, June 1985. 19. United States Environmental Protection Agency, Region IV, Field Health and Safety. July, 1990.