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HomeMy WebLinkAboutNCD079044426_19950501_General Electric Co. Shepherd Farm_FRBCERCLA RI_Draft Remedial Investigation Report-OCRI I I I I I I I I I I I I , I I I l GE/Shepherd Fai:n NPL Site Remedial Investig1fion Report Draft May, 199:: TABLE OF CONTENTS SECTION 1.0 INTRODUCTION I. I Purpose of Report 1.2 Report Orginization 2.0 SITE INFORMATION 3.0 2.1 2.1. l 2.2 2.3 2.4 2.5 2.6 2.7 Site Description Location 2. I. 2 Physical Features Site History 2.2. l Onsite Treatment/Storage/Disposal Activitiys Previous Sampling Investigation Results Site Regulatory Actions Demography Surround Land/Water Use Environmental Setting 2.7. l Physiography/Topography 2. 7. 2 Climate/Meteorology 2.7.3 Geology 2.7.4 Hydrogeology 2.7.5 Hydrology 2. 7.6 Wildlife Natural Resources SAMPLING STRATEGY 3. I Sample Collection 3.2 · Sample Identification· 3.3 Soil Sampling 3.3. l GE Property 3. 3. 2 Seldon Clark Prope1ty 3.3.3 Shepherd Farm Property NOl103S ONn.:Jl:J3dns S66! S 6 A'v'W 03Nf9eJ3c, 1-1 1-1 1-1 2-1 2-1 2-1 2-6 2-7 2-8 2-13 2-26 2-27 2-28 2-29 2-29 2-30 2-30 2-32 2-34 2-35 3-1 3-1 3-1 3-2 3-2 3-5 3-5 I I I I I I I I I I I I I I I I I GE/Shepherd Fann NPL Site Remedial Investigation Report Draft May, 1995 TABLE OF CONTENTS SECTION EA.GE 3-8 3-8 3-14 3-14 3-14 3-14 3-17 3-17 3.4 Surface Water and Sediment Sampling 3.5 Temporary Well Installation and Sampling 3.6 Monitor Well Sampling 3. 7 Potable Well Sampling 3. 8 Analytical Procedures 3. 9 Field Instmmentation 3. IO Sample Containers 3 .11 Field Sampling Equipment Cleaning Procecdures 4.0 NATURE AND EXTENT OF CONTAMINATION 4-1 4.1 Soil Sampling 4.1.1 GE Property 4.1.2 Seldon Clark Property 4.1.3 Shepherd Fann Property 4.2 Sediment and Surface Water Sampling 4.3 Temporary Monitor Well Installation and Sampling 4.4 On Site Pennanent Monitor Well Sampling 4.5 Potable Well Sampling 4.6 Well Survey 4-1 4-2 4-18 4-22 4-33 4-46 4-53 4-75 4-84 5.0 CONTAMINANT FATE AND TRANSPORT 5-1 5.1 6.0 Contamiant Migration 5-1 5. I. I Air Migration 5-1 5.1.2 Surface Water Migration 5-2 5 .1.3 Soil Migration 5-2 5.1.4 Ground Water Migration 5-3 SUMMARY, CONCLUSIONS AND RECOMMENDATIONS 6-1 6.1 Soil Investigation 6.1.1 General Electric II 6-1 6-1 I I I I I I I I I I I D I a g I n D SECTION GE/Shepherd Farm NPL Site Remedial Investigation Report Draft May, 1995 TABLE OF CONTENTS 6.1.2 Seldon Clark 6.1.3 Shepherd Fann 6.2 Surface Water 6.3 Sediment 6.4 Temporary Monitor Wells 6.5 GE On Site Permanent Monitor Wells 6.6 Private Well Sampling 6. 7 Recommendations UGE 6-1 6-2 6-2 6-2 6-2 6-2 6-3 6-3 7.0 REFERENCES 7-1 111 I I I I I I I I I I I I I I I I I GE/Shepherd Fann NPL Site Remedial Investigation Report Draft May, 1995 LIST OF FIGURES EI.G.URE 2.1 Site Location Map 2.2 2. 3 Shepherd Fann Subsite Features Map 2.4 Seldon Clark Subsite Features Map 2.5 2.6 2.7 2.8 2.9 2.10 2.11 2.12 2-13 3.1 GE Property Soil Sampling Locations 3.2 Seldon Clark Property Soil, Su1t'ace Water and Sediment Sampling Locations 3.3 Shepherd Fann Property Soil Sampling Locations 3.4 -' GE Property Surface Water and Sediment Sampling Locations 2-2 2-3 2-4 2-5 2-11 2-14 2-18 2-21 2-23 2-24 2-25 2-31 2-33 3-4 3-6 3-7 3-9 I I I I I I I I I I I I I I I I I I I GE/Shepherd Farm NPL Site Remedial Investigation Report Draft May, 1995 LIST OF FIGURES EIGURE . 3.5 Shepherd Fann Property Surface Water and Sediment Sampling Locations 3.6 GE Property Temporary Monitor Well Locations 3.7 Seldon Clark Property Temporary Monitor Well Locations 3.8 Shepherd Farm Property Temporary Monitor Well Locations 3.9 GE Property On Site Monitor Well Locations 3. 10 Potable Well Locations 4.1 GE Property Soil Sampling Locations 4.2 Seldon Clark Property Soil, Surface Water and Sediment Sampling Locations 4.3 Shepherd Fann Property Soil Sampling Locations 4.4 GE Property Surface Water and Sediment Sampling Locations 4.5 Shepherd Fann Property Surface Water and Sediment Sampling Locations 4.6 GE Property Temporary Monitor Well Locations 4.7 Seldon Clark Property Temporary Monitor Well Locations 4. 8 Shepherd Farm Property Temporary Monitor Well Locations 4.9 GE Property On Site Monitor Well Locations 4.10' Cis-1,2-dichloroethenc Shallow Well Isopleth V £AGE 3-10 3-11 3-12 3-13 3-15 3-16 4-3 4-19 4-23 4-34 4-35 4-47 4-48 4-49 4-56 4-66 I I I I I I I I I m I I I g I D D GE/Shepherd Farm NPL Site Remedial Investigation Report Draft May, 1995 LIST OF FIGURES ElGURE EAGE 4.11 eis-1,2-dichloroethene Deep Well Isopleth 4-67 4.12 Trichloroethene Shallow Well Isopleth 4-68 4.13 Trichloroethene Deep Well Isopleth 4-69 4.14 Tetrachloroethene Shallow Well Isopleth 4-70 4.15 Tetrachloroethene Deep Well Isopleth 4-71 4. 16 Total voe Shallow Well Isopleth 4-72 4.17 Total voe Deep Well Isopleth 4-73 4.18 4- 4.19 4- 4.20 GE Property Potentiometric Surface Map 4-78 4.21 Potable Well Locations 4-80 vi I I I I I I I I I I g I I u I I B I I GE/Shepherd Fann NPL Site Remedial Investigation Repo1t Draft May, 1995 LIST OF TABLES IABLE 2.1 2.2 Underground Storage Tank Data Well Constrnction Details 3.1 Sample Container and Preservative Requirements 4.1 General Electric Soil Sampling Analytical Data Summary 4.2 Seldon Clark Soil Sampling Analytical Data Summary 4.3 Shepherd Fann Soil Sampling Analytical Data Smmary 4.4 Shepherd Fann Soil Sampling Location Summary 4.5 Surface Water Sampling Analytical Data Summary 4.6 Sediment Sampling Analytical Data Summary 4.7 Surface Water Sampling Field Parameters 4.8 Temporary Well Sampling Analytical Data Summary 4.9 Temporary Well Sampling Field Parameters 4.10 Generaal Electric Monitor Well Constrnction Information 4.11 General Electric Monitor Well Sampling Analytical Data Summary 4.12 General Electric Monitor Well Sampling Field Parametei-s· 4.13 General Electric Ground Water Elevation Summary 4.14 Potable Well Samples Residential Names and Addresses Vil EA.GE 2-12 2-25 3-18 4-4 4-20 4-24 4-30 4-36 4-40 4-45 4-50 4-52 4-54 4-57 4-63 4-76 4-79 I I I I I I I I I I I I I I I I I I I TABLE GE/Shepherd Fann NPL Site Remedial Investigation Report Draft May, 1995 LIST OF TABLES 4.15 Potable Well Samples Analytical data Summary 4.16 Potable Well Samples Field Parameters .eAGE 4-81 4-83 viii I I I I I I I m g I I D I I I I 1.0 INTRODUCTION GE/Shepherd Fann NPL Site Remedial Investigation Report Draft/ May 1995 The General Electric/Shepherd Fann Site (hereinafter referred to as the "GE Site" or "the site") consists of three non-contiguous disposal areas in East Flat Rock, Henderson County, North Carolina. These disposal areas (subsites) are known as the GE property, the Shepherd Farm property, and the Seldon Clark property. Previous investigations have indicated that the major sources of contamination on these properties are related to the waste disposal, storage, and treatment practices performed by the GE plant located on the GE property. One of the Potentially Responsible Parties (PRPs) for this Site, General Electric Lighting Systems, declined to enter into an Administrative Order by Consent with EPA to conduct the Remedial Investigation and Feasibility Study. Therefore, this study was conducted using Superfund monies, and is therefore, classified as a fund-lead site. 1.1 PURPOSE OF REPORT The purpose of this RI report is to present and evaluate data gathered during the field investigation. The main focus of the RI is to determine source areas, and delineate the nature and extent of contamination. Field data collected included chemical analyses of soil, groundwater, surface water and sediment. The risk posed by the contamination is evaluated in a Risk Assessment and will be used to support EPA's selection of a remedial action alternative that will eliminate or sufficiently reduce the risk posed by the GE site to public health and the environment. REPORT ORGANIZATION This RI report contains six major sections: * * Section 1 -Introduction Section 2 -Site Information and Physical Characteristics of Study Area -Site History and Previous Investigations; addresses demography, surrounding land/water use, topography, meteorology, hydrogeology, geology, and wildlife Natural Resources. 1-1 I I I I I I I I I I I I I I I I I I I * * * * * * GE/Shepherd Farm NPL Site Remedial Investigation Report Draft/ May 1995 Section 3 -Sampling Investigation (addresses soil, surface water/sediment, and groundwater sampling strategy). Section 4 -Nature and Extent of Contamination (addresses investigation findings). Section 5 -Contaminant Fate and Transport (addresses potential routes of migration and contaminant migration). Section 6 -Summary and Conclusions. Appendix A -Ecological Investigation. Appendix B -Analytical Data. 1-2 I I I I I I I I I I I I I I I I I I I 2.0 SITE INFORMATION GE/Shepherd Farm NPL Site Remedial Investigation Report Draft/ May 1995 This section provides information on the history of the site and investigations conducted prior to the RI. This section also describes the regional and site-specific characteristics of the study area including: demography, surrounding land/water use; and environmental setting. 2.1 SITE DESCRIPTION 2.1.1 LOCATION The GE subsite is located at the southeastern corner of Spartanburg Highway (U.S. 176) and Tabor Road (S.R. 1809) in East Flat Rock, Henderson County, North Carolina (see Figure 2- 1). Geographically, the center of the subsite is located at approximately 35°16'25" N latitude and 82°24·10· W longitude according to the Hendersonville, North Carolina, USGS 7.5 minute topographic map. This slightly hilly, approximately 50-acre subsite is bounded on the west by Spartanburg Highway, on the north by Tabor Road, and on the east by Bat Fork Creek (see Figure 2-2). The southern boundary is a fenceline south, east, and west of the recreational facility. General Electric also owns the plot of land located southwest of Spartanburg Highway, south of Bat Fork Creek, between the curved railroad tracks and the highway. The Shepherd Farm subsite is located on Roper Road, approximately 1200 feet west of Spartanburg Highway and southwest of the GE subsite (see Figure 2-1). Geographically, the center of the subsite is located at 35°16'10" N latitude and 82°25' 10· W longitude according to the Hendersonville, North Carolina, USGS 7.5 minute topographic map. This hilly, approximately 31-acre subsite is bounded on the north by Roper Road, on the north-northwest by the Seldon Hill Farm, and on the west by Bat Fork Creek (see Figure 2-3). The Seldon Clark subsite is located at the northeastern corner of Spartanburg Highway and Tabor Road (see Figure 2-1)~ Geogiaphically, the ~~nter.of the subsite is located at 35°16'35" N latitude and 82°25·00· W longitude according to the Hendersonville, North Carolina, USGS 7.5 minute topographic map. This approximately 1-acre field is bounded on the west by Spartanburg Highway, on the south by Tabor Road, on the east by Jones Street, and on the north by Second Avenue (see Figure 2-4). 2-1 I I I I I I I I I I I I I I ._; """ ~ \\•. ~ .... , 0 • ,• . • JI-• : ' . 11• ·= II • :/i.t II ---!.]/._ II 1 :J: _,,, 0 :la IT.I SCALE IN FtET ' I ar , \ . II \ \\ • \I \~,_~•~v}• • •~. I '~\ ~~: ~-.. ~' ---:::::,.,__.:<·~~~=·/ ,' J i ..;;.~ii..:--, (.. , . .. ' SITE LOCATION MAP ,-------------------------1 FIGURE -2.1 I "Q/7EnA GE/SHEPHERD FARM PROPERTY ~ ~ Fam\ EAST FLAT ROCK, NORTH CAROLINA i.._ ____________ --1...-_ ___J I I I I I I I I I I I I I I I I I I I 2.1.2 PHYSICAL FEATURES GE Property GE/Shepherd Farm NPL Site Remedial Investigation Report Draft / May 1995 The GE facility includes two major building structures: the manufacturing plant (350 by 700 feet) and the finished stock warehouse (700 by 300 feet). The buildings are separated by paved parking areas and grassy lawns. The two buildings are situated on a relatively flat hilltop, while the rest of the property is on a hillslope. A tall, barbed-wire, chain-link fence • surrounds the entire property with the exception of the landspreading plots (described below) and the front of the facility where parking lots and manicured lawns exist. A guard is on duty at all times to keep unauthorized personnel out of the plant and facility grounds (NUS, 1991a). East of the plant is Demonstration Street, a paved, relatively flat strip of land. Along this area, lighting fixture displays demonstrate the product line at GE. Several support facilities are located along or near Demonstration Street, including a fork lift shop, a fabricating shop, a reclamation yard, a boiler house, a chlorine building, a drum storage area, an outside vendor (OV) storage area, and other fixtures and structures such as water tanks and pumps, cryogenic tanks, gasoline pumps, and storage bins. A closed 0.5-acre landfill (Landfill A) is now paved over by this street (NUS, 1991a). East of Demonstration Street, beyond the paved lots, are approximately 26 acres of landspreading plots which are blanketed by vegetation and slope eastward downhill toward Bat Fork Creek. Southeast of Demonstration Street, beyond the drum storage area, is a dry, 3-acre, inactive sludge impoundment which currently has a thick cover of vegetation. Southeast of the finished stock warehouse is a large (5-acre), active, wastewater treatment pond. An underground drain line leading from the manufacturing plant to this wastewater treatment pond is used to transport the wastewater and stormwater runoff to the treatment ponds (NUS, 1991a). East of the large wastewater treatment pond is a small (1-acre), active, landfill area where construction debris and excavated soils have been deposited or stored. Southwest of the finished stock warehouse is a grassy lawn area which was also previously used as a land spreading plot. · · · · · · The area south of Bat Fork Creek also belongs to GE and includes a small (1-acre), active, wastewater treatment pond, a recreational area with adjacent playground which was also formerly used as a landspreading plot, and a closed I-acre landfill (Landfill B), parts of which 2-6 I I I I I I I I I I I I I I n I GE/Shepherd Farm NPL Site Remedial Investigation Report Draft/ May 1995 are currently paved over by a driveway leading to the recreation facility. GE reported that 2 to 3 feet of clean fill soils were placed over the landspreading plot when developing the recreation area in the late 1970s or early 1980s (ATSDR, 1993). The tract of land on the western side of Spartanburg Highway which is owned by GE is currently undeveloped (NUS, 1991a). The unfenced Shepherd Farm property, formerly used for disposal of wastes from the GE facility, is currently a sloping wooded area used for residential purposes. Mr. Shepherd still maintains his residence on this property. In addition, a 22-acre trailer park (Spring Haven) consisting of 125 lots (most with trailers) and a community center are present on the southern portion of the subsite. A small unnamed intermittent creek runs through the middle of the subsite before discharging into Bat Fork Creek (NUS, 1991b). The unfenced Seldon Clark property, formerly used for landfilling of wastes from the GE facility, is presently a grass-covered field which slopes toward Jones Street that forms its eastern boundary. The only facility located on the property is a small shack which was formerly used as a junk/antique shop (EPA, 1993). 2.2 SITE HISTORY From 1955 to present, the GE facility has been used to develop, design, and manufacture complete high-intensity-discharge luminaire systems, which consists of the assembly of optical components, ballasts, mountings, and high mast lowering devices. The luminaire systems produced at the facility use several light sources including sodium and mercury. These lighting systems have many uses which include the illumination of roadways, sports arenas and related buildings and/or parking lots, indoor industrial and/or commercial complexes, and hazardous or dangerous location applications (NUS, 1991a). Operations at the facility are comprised of several manufacturing processes. Raw aluminum is smelted and die-cast into molds of light fixture housings. Strip aluminum is machined by a spiri and die· process into reflectors that are attached to the housings. These reflectors are finished in a metal finishing, polishing, or coating process to yield a highly machined, polished or satin surface, as desired (NUS, 1991a). 2-7 I I I I I I I I I I I I I I I I n u I I I D\ I I I I I I z -w <z ·-~J GE SUBSITE FEATURES MAP I I I I\ ~ ~ J ~ i!a < X 1---------------------------1 FIGURE 2.2 ~ ~/7-EnA GENERAL ELECTR1c suPERFUND s1TE ~ ~ Fl'\. EAST FLAT ROCK, NORTH CAROLINA D ~ ..... _______________________________ _,_ _____ ...J I --·· I ! / I i / / i / ! / ; ; i i , / i / . i / ./ / , \ \ '--------·-·-·· SHEPHERD FARM SUBSITE FEATURES MAP ------------------------t FIGURE 2.3 &EPA. GE/SHEPHERD FARM PROPERlY EAST FLAT ROCK, NORTH CAROLINA / /' --HJ] _b w 0:: I-VJ 0 0 VJ w z 0 -, t;; L,J u.. 0 ,!; L,J ..J < () U1 0 0 ~ I i 1'7 z I :;:;: 0:: 0 ::;, I 0:: 0 I-VJ f-z :s 0... w C) 3nN3/\V 0::: w 2 0::: <( Ow . LL 0::: 0 <( W-1 ~ _j 2 LL f- (f) w ON0::)3S , SELDON CLARK SUBSITE FEATURES MAP ~ ~ 3: I (_') I (_') 0:: :::, Ill z ~ 0:: <l'. Q_ VJ ~ <D r-- VJ :::, ------------------------1 FIGURE 2.4 ~EPA GE/SHEPHERD FARM PROPERTY EAST FLAT ROCK, NORTH CAROLINA I I I I I I I I I I I I g u B I I I GE/Shepherd Farm NPL Site Remedial Investigation Report Draft/ May 1995 The aluminum light fixture housings and parts go through mechanical, chemical, and/or electrochemical metal cleaning and finishing processes. GE's metal cleaning processes utilize 26 fiberglass and metal tanks or cells filled with a variety of washes and chemical treatment solutions including soaps, phosphoric acid, sulfuric acid, nitric acid, sodium hydroxide bath, water, and deionized water. A voltage drop is applied across many of these cells (tanks). Two systems are used for metal finishing at the facility after chemical metal cleaning in the fiberglass tanks is completed. The systems are the AL V AC system and the BELKE system. The AL V AC system involves aluminum anodizing and oxidizing the outer layers of the surface of the aluminum to clean the surface and give it a matte or frosted appearance. The BELKE system uses a silicate solution into which metal aluminum parts are dipped. This forms a thin glass-like coating on the aluminum part. Metal finishing and coatings are used to polish, brighten, and create a noncorrodible surface on the outdoor aluminum fixtures (NUS, 1991a). Ballasts used in the light fixture housings are first manufactured by a lamination punching process. Copper wire that has been coated with a protective varnish at the facility is drawn and wound irito coils for use in the ballasts. A plastic known as Valox is also injection-or compression-molded into parts which are then used for various purposes inside of the luminaire systems (NUS, 1991a). From about 1955 until 1975, GE also manufactured "constant-current" transformers at this facility. These. transformers were filled with PCB-containing oil, which were delivered to the facility in railroad tank cars (NUS, 1991a). GE has reported that PCBs are no longer used in their product line (ATSDR, 1993). Prior to GE's purchase of the property in 1955, the GE subsite was used as an apple orchard (EPA, 1993). 2.2.1 ONSITE TREATMENT/STORAGE/DISPOSAL ACTIVITIES Waste streams generated by GE's facility from the beginning of plant operations have included construction wastes, buffing compound, epoxy compound, phenolic residue, paint sludges;PCB capacitors, solvents, transformer oil, electrical insulators/capacitors, ·waste acids, dye cast mold released hydrocarbons, heavy petroleum greases, and varnish residues. These waste streams contain many VOCs, heavy metals, acids, and PCBs. Current waste streams include solvents, cadmium-contaminated baghouse dust, waste oils, and lab packs (EPA, 1993). 2-8 I I I I I I I I I I I D B I I I GE/Shepherd Farm NPL Site Remedial Investigation Report Draft/ May 1995 Waste disposal activities carried out by GE during the 1950s and 1960s have been poorly documented. Recent information from a former GE employee, however, indicates that at least two former landfills (Landfills A and B) were operated during this time period. Landfill A received waste generated by the facility between 1955 and the 1960s. No information is available concerning the types of wastes, but it is assumed that the wastes are from the manufacturing process utilized during this time of operation. Landfill B is believed to have been operated during the 1970s, and presumably received only construction debris. No other wastes were given approval by GE or the State of North Carolina to be disposed of at Landfill B. These unregulated practices of the 1950s and the 1960s were ceased by GE with the promulgation of state and federal legislation to control pollution to the environment during the 1970s (NUS, 1991a). As these two former landfills have been paved over, there is no physical evidence of waste at the landfill locations. Wastewater generated as a result of plant processes, contains metals and solvents typically used during lighting system manufacture. GE implemented a wastewater treatment facility in the mid-1970s consisting of a lime treatment system to adjust the pH of treated waters prior to surface water discharge. They also constructed the two wastewater treatment ponds described previously. The unlined ponds were constructed of native clay and are approximately 10 feet deep. The larger pond has a controlled exit valve at its discharge point to the smaller pond. The valve has a primary pH meter and a back-up meter which is set to automatically shut off if pH fluctuates above 9 or below 6. The large pond also has a spill containment tank and a baffle to control retention time of water. This po·nd is used for sedimentation as well as to control BOD, dissolved oxygen, pH, and phosphates. The smaller pond is used as an oxygenation process of wastewater by aeration and periodically received an unknown amount of sludge from 1976 to 1980 (NUS, 1991a). As part of the waste treatment process, wet and dry sludges generated in the wastewater treatment facility were landspread on several plots surrounding the facility buildings between 1977 and 1980. These landspreading plots, totaling 26 acres, were delineated for disposal of wet and dry sludges that contained water, lime, and about 0.07 to 2.85 percent nickel typically used in plant processes. The nickel was used as a polishing agent or as a coating on finished aluminum products (light fixtures) during the 1970s. The use of nickel was . concurrent with. the landspreading activities and continued until 1986. t:andspreading of sludge ended in 1980 with the prnmulgation of RCRA regulations. Sludge filter cake was also sold at some time in the past to local merchants as a fertilizer or shipped for burial to the local landfill (Henderson County Landfill) in Hendersonville (NUS, 1991a). 2-9 I I I I I I I I I I I I I I I I D I I GE/Shepherd Farm NPL Site Remedial Investigation Report Draft / May 1995 From 1955 until 1975, GE also generated a substantial quantity of PCB wastes as a result of transformer production. Disposal of these wastes prior to 1980 is not well documented, but in 1984, PCB wastes were sent to Emelle, Alabama for disposal. It is possible that PCB- containing electrical components were deposited along with other wastes, into the dried sludge impoundment or the waste treatment ponds (NUS, 1991a). A written notification of a spill of #2 fuel oil was sent to the North Carolina Division of Environmental Management (NC DEM) on January 21, 1983, by GE. An estimated 1,400 gallons of the #2 fuel oil was accidently lost on January 19, 1983, via a ruptured fuel transfer line. The oil made its way to the large wastewater treatment pond, where sorbent pads were used to remove it (NUS, 1991a). Another accidental #2 oil spill was reported to NC DEM on January 10, 1995. An estimated 6,500 gallons of fuel oil were spilled on January 6, 1995 from a day tank located adjacent to a boiler house. GE used oil collecting booms to stop the spread of the oil (Bush, 1995). Cutting and grinding fluid wastes presently generated at the facility (approximately 900 gallons/year) are transported to SCA Services in Pinewood, South Carolina. Solvents presently used in the plant include methyl ethyl ketone, used in a paint sprayer to clean parts, and tetrachloroethene (approximately 10 gallons/year), also used to clean various parts (NUS, 1991a). Waste quantities generated over the duration of operation of the facility are unknown. As already discussed, a substantial quantity of sludge was spread over the landspreading plots from 1977 to 1980. An unknown quantity of plant-generated sludges (primarily sediment accumulated in the wastewater treatment ponds) was disposed of in the dried sludge irnpoundment area from 1976 to 1977. This older impoundment was taken out of service when landspreading activities began along with the implementation of the lime water treatment system in 1977 (NUS, 1991a). Underground storage tanks (USTs) at eighteen locations (see Figure 2-5) have been used by GE in the past to store fuels, liquid supplies (paints and varnishes), and liquid wastes. Table 2-1 presents details regarding each of the USTs. All of these USTs are reported by GE to have been removed by March 1991, and all liquid storage is now performed in above ground storage tanks and drums. GE's drum storage facility, constructed in 1970,_ has spill-. containment features (ATSDR, 1993). · · - • From approximately 1957 to 1970, GE wastes were also deposited at the Shepherd Farm property where it was dumped, burned, and bulldozed in an approximate 3-acre area onsite. At the time of the dumping, the only other use of the property was for the Shepherd's 2-10 I I :C I ~ D' r I I!/ I z i ~~ I 25:J ~ GE SUBSITE UST LOCATIONS I I I I I I I . / I . ;,,<;:<._ ... I I I I I I I I I I I I u H I I I I ~-----------------------....! FIGURE 2.5 ii &EPA GENERAL ELECTRIC SUPERFUND SITE EAST FLAT ROCK, NORTH CAROLINA =::t r:;;;;:i 11iii11i11 1iiiii1 liiillil 11111 1iiii1ii1 ii1i1 · iiii1 iiiii1 -------.. - TABLE 2-1 . UNDERGROUND STORAGE TANK DATA GE/SHEPHERD FARM SITE EAST FLAT ROCK, NORTH CAROLINA Tank Date Last Location Year Volume Contained Year No. Contents Removed (gal) Approximate Location Material . Installed 1 Diesel Fuel 1990+· 30,000 North of boiler house NA• 1970 2 112 Fuel Oil 1990+ 6@30,000 Under Demonstration Street NA 1969 3 Unleaded Gas 1990+ 20,000 Between Demonstration and tracks NA 1985 4 Waste Oil 1989 10,000 North of boiler house 11/89 1956 5 Hydraulic Oil 1990+ 10,000 East of facilities building NA 1982 6 Ethylene Glycol 1990 10,000 Northwest of north wing NA 1966 7 Kerosene 1989 1,000 Northwest of north wing 7/83 1966 8 Insul Varnish 1990+ 10,000 Northwest of north wing NA 1980 9 Leaded Gas 1989 2,000 North of warehouse 4/85 1976 10 Leaded Gas 1989 2@ 1,000 Reclamation yard 6/85 1974 11 Unleaded Gas 1989 3@500 Reclamation yard 11/89 1974 12 Leaded Gas 1989 1,000 Northwest of garage 4/85 1976 13 Scrap Oil 1983 1,000 Northeast of lime treatment 3/83 1970 14 Drum Spill Cont. 1990+ 1,000 South of drum storage NA 1985 15 Diesel 1989 500 Reclamation yard 12/84 1974 16 White E'Coat 1990 7,500 Mini factory 6/88 1978 17 Gray E'Coa!'. 1990+ 7,500 Northwest of north wing NA 1978 18 Kerosene late 70s 200 Alzak late 70s 1956 Source: Interim Final Report, Listing Site Inspection, Phase II, GE Company (NUS, 1991a) . Key: a (1990+) -Sometime After 1990 b (NA) -Information Not Available I I I I I I I I I I I I I I I I I I I GE/Shepherd Farm NPL Site Remedial Investigation Report Draft/ May 1995 residence. The trailer park was later constructed over part of the dumping area. Most of the waste was reportedly deposited into an old dry pond or ravine approximately 800 feet southwest of the Shepherd residence. When the path leading to the ravine was icy, however, the waste was placed along the path. According to Mr. Shepherd, the waste consisted of cardboard, wood, office paper, and buffing compound. Occasionally, electrical "insulators" were taken to the site and broken to salvage copper. These might have been capacitors as insulators do not contain copper. Additionally, according to GE representatives, waste solvents were also probably disposed of at Shepherd Farm. Two local residents reported that during construction of the trailer park, drums were dug up and reburied. During a recent site visit, drums and electrical-type wastes were observed onsite (NUS, 1991b). During the 1960s and early 1970s, GE wastes were also dumped in an approximate 0.3-acre ravine on the Seldon Clark property. GE reported that the property was used for the disposal of construction rubble only, but according to Mr. Clark, the ravine was also filled in with drums of aluminum paint and drums of cleaning fluid from dye-casting machinery. Old transformers are also reported to have been deposited in the ravine. The suspected disposal area is located .in the southwestern half of the property but there is presently no physical evidence of a landfill (ATSDR, 1993). 2.3. PREVIOUS SAMPLING INVESTIGATION RESULTS Several sampling investigations have been conducted at the site, especially at the GE facility. The major sampling investigations, briefly described below, were conducted independently by both GE and EPA. The quality of the data collected during the GE-conducted events, however, is unknown. These studies have included monitor well installation and groundwater sampling, soil sampling, surface water/sediment sampling, and offsite private well sampling. Figure 2-6 shows the locations of all the permanent monitor wells installed at the GE subsite and Table 2-2 presents available well construction details for these monitor wells. All wells without a letter extension (e.g., MW-12) were installed with the screen interval in the porous media zone. All wells with an "A" extension (e.g., MW-12A) were installed with the screen interval in the shallow fractured rock zone. All wells with a "B" extension (e.g., MW-12B) were installed with the screen or open· inte·rval in 'the deeper fractured ·rock zone. Alrwells with an "R" extension (e.g., MW-36R) are replacement wells for wells which were inadvertently damaged or destroyed. The replacement wells are reported by GE to be constructed similarly and in the same location as the original wells. 2-13 I I I I I I I I I I m I I I I I n D I !&EPA GE SUBSITE WELL LOCATIONS GENERAL ELECTRIC SUPERFUND SITE EAST FLAT ROCK, NORTH CAROLINA FIGURE 2.6 ~.._ __________________________ __,_ ____ ___, I I TABLE2-2 WELL CONSTRUCTION DETAILS I GE/SHEPHERD FARM SITE EAST FLAT ROCK, NORm CAROLINA I Measuring Ground Auger Screened Survey Coordinates Point Surface Refusal Interval Elevation Elevation Depth Depth Northing Easting I Well No. (feet ams!) (feet ams!) (feet) (feet) (feet) (feet) I MW-01 2183.33 2180.5 28.4 23.0 -28.0 4472.3 10232.3 MW-02 2153.45 2150.2 27.2 14.5 -24.5 3912.0 10547.1 MW-02A 2153.10 2150.0 29.7 38.3 -48.3 3912.4 10547.0 MW-03 2143.62 2140.8 23.S 12.5 -22.S 3683.9 10238.8 I MW-04 2146.46 2143.S 13.8 8.2 -13.2 3856.S 10171.3 MW-OS 2182.72 2180.1 37.S 42.7 -52.7 4467.3 10229.4 MW-06 2178.69 2175.6 22.S 30.S -40.S 4373.4 10223.5 I MW-07 2178.28 2178.4 37.3 26.8 -36.8 4478.7 10134.5 MW-08 2186.47 2183.7 31.S 31.S -48.3 OH 4573.9 10239.9 MW-09 2177.57 2177.7 37.4 27.4 -37.4 4462.5 10330.S m MW-10 2189.15 2187.1 88.0 78.0 -88.0 5505.6 10531.1 MW-11 2178.76 2178.9 58.S 48.5 -58.S 4993.6 10119.5 MW-12 2168.96 2166.4 40.S 30.S -40.S 4738.3 9935.1 • MW-12A 2168.77 2166.4 43.S 48.0 -58.0 4738.3 9930.4 MW-12B 2168.20 2166.7 36.0 91.0 -125.0 OH 4739.8 9923.5 MW-13 2140.46 2138.8 14.2 9.2 -14.2 4582.2 11157.S MW-13A 2141.00 2138.5 8.0 31.0 -41.0 4587.3 11160.8 I MW-14 2144.63 2142.0 37.4 27.3 -37.3 4184.1 10875.3 MW-14A 2144.56 2142.1 37.S 42.3 -58.3 4180.8 10878.6 MW-14B 2143.30 2142.3 40.0 83.0 -110.0 OH 4187.7 10872.0 I MW-JSR NA NA 18.0 7.5 -17.S NA · NA M:W-16R NA NA 38.S 28.S -38.5 NA NA MW-17 2182.41 2180.0 43.0 33.0 -43.0 4741.3 10683.8 I MW-18 2167.32 2164.7 43.7 33.6 -43.6 4668.3 9711.5 MW-19 2177.86 2178.2 42.3 32.3 -42.3 4976.2 9873.8 :r.iW-20 2179.09 2179.4 65.6 55.3 -65.3 5388.3 10072.6 MW-20B 2179.31 2179.5 52.0 115.0-125.0 OH 5384.1 10072.1 I MW-21 2177.81 2178.0 82.4 71.8 -81.8 5746.0 10082.3 MW-22A 2126.30 2126.5 0.7 13.0 -23.0 4873.2 11421.3 MW-23 2160.80 2160.0 60.0 49.8 -59.8 4277.6 9818.7 n MW-24 2183.10 2183.3 72.1 61.9 -71.9 5750.3 9233.8 MW-25 2157.70 2157.8 41.5 31.5 -41.5 4560.0 9200.7 MW-26 2173.80 2171.4 58.5 47.8 -57.8 4983.5 9187.2 I MW-27 2134.70 2133.2 15.0 4.0 -14.0 4080.3 11109.7 MW-27A 2135.30 2133.2 13.S 21.5 -31.5 4080.3 11112.3 MW-28 2155.00 2154.7 36.0 25.5 -35.5 4455.3 9049.4 MW-29 2160.16 2157.9 41.0 31.0 -41.0 5153.9 11054.7 D H 2-25 I I I I I I I I I I I I I I I I I D Well No. MW-30 MW-30A MW-31 MW-32 MW-33 MW-34 MW-35 MW-36R MW-37 MW-38 MW-39 MW-40 MW-41 MW-42 MW-43 MW-44 MW-45 MW-46 RW-1 RW-2 RW-3 RW-4 IITS l(P-4)* IITS 2(P-5)* !ITS 3(P-7)* IITS 4(P-8)* Sources: NOTES: • OH NA TABLE 2-2 (cont.) WELL CONSTRUCTION DETAILS GE/SHEPHERD FARM SITE EASI' FLAT ROCK, NORTH CAROLINA Measuring Ground Auger Screened Survey Coordinates Point Surface Refusal Interval Elevation Elevation Depth Depth Northing (feet ams!) (feet ams!) (feet) (feet) (feet) 2156.81 2156.9 47.5 37.5 -47.5 2927.8 2156.24 2156.3 46.5 51.5 -61.5 2926.8. 2157.91 2158.2 6.4 -16.4 3748.8 2154.92 2155.2 6.7 -16.7 3705.1 2179.93 2179.5 6.5 -16.5 5384.1 2162.86 2163.0 3.5 -13.5 4662.6 2183.00 2183.2 8.5 -18.5 5574.4 2181.72 2182.1 3.5 -13.5 6064.0 2155.57 2152.5 36.5 26.1 -36.1 4200.2 2178.03 2178.4 65.2 43.0 -63.0 5569.9 2179.64 2179.9 56.8 35.0 -55.0 5261.0 2177.73 2177.9 54.3 33.0 -53.0 5237.6 2178.54 2178.8 48.6 28.1 -48.1 4898.4 2173.99 2174.4 39.7 17.9 -37.9 4876.3 2168.68 2169.3 40.5 20.0 -40.0 4717.0 2159.06 2159.4 34.2 13.1-33.1 4633.9 2160.62 2160.9 2.6 -12.6 4619.8 2159.56 2160.0 2.6 -12.6 4619.4 2179.26 2178.5 9.3 -78.9 5265.1 2176.74 2175.9 7.9 -77.5 4916.4 2168.74 2168.1 9.3 -78.9 4754.7. 2163.35 2162.0 8.7 -78.3 4668.7 2167.3 2166.4 2154.9 2154.1 2178.4 2177.7 2189.7 2188.8 Report of Phase II-A Contamination Assessment (Law Engineering, 1989a) Report of Phase II-ll Contamination Assessment (Law Engineering, 1989c) Easting (feet) 9885.8 9894.0 9673.1 9689.7 10072.0 9801.9 10181.1 9496.5 10699.7 10089.4 10171.6 10125.3 10162.1 10072.9 9985.8 9860.9 9775.2 9813.7 10128.0 10105.6 9965.4 9843.0 Report of Phase IIIA Groundwater Quality Assessment Activities (Law Environmental, 1990b) Report of Phase IIIA Aquifer Characterization and_Groundwater Treatment System (Law Environmental, 1991a) Phase II Environmental Assessment, Former UST Number 9 Area (Law Engineering, 1991c) Well abandoned Open hole in rock Nat determined Not available 2-26 I I I I I I I I I I m I I I I n I n I GE/Shepherd Farm NPL Site Remedial Investigation Report Draft/ May 1995 During the sludge landspreading operations, four nests of "Environmental Test Site (ETS)" wells (three wells per nest) were installed and sampled by GE. The ETS wells were constructed at depths between 20· and 40 feet below land surface (bis) so that GE could monitor the effects of landspreading on groundwater. Chemical analyses of samples collected from the wells revealed only low levels of zinc (NUS, 1991a). Figure 2-7 shows the locations of the private wells sampled. In 1986, four monitor wells (MW-1 through MW-4) were installed by GE around the dried sludge impoundment to monitor the effects of sludge disposal in this impoundment. High levels of trichloroethene were discovered in MW-1 which is near an area of suspected drain line rupture. A Phase I Contamination Assessment was initiated in December 1987 by GE as a result of this newly discovered contamination. Five additional monitor wells (MW-5 through MW-9) were installed around MW-1 to determine if soil and groundwater surrounding the well had become contaminated by chlorinated hydrocarbons. Analysis of the samples collected from these wells revealed that the contaminant plume extended throughout the area of these wells. In May 1988, all wells installed at the GE facility up to that point (including the ETS wells) were sampled again by GE. The results indicated that the trichloroethene plume was increasing in size laterally (NUS, 1991a). In November 1988, EPA conducted a Screening Site Inspection, Phase Il, at the GE subsite. A total of 14 surface soil, subsurface soil, sediment, and groundwater samples were collected during this investigation. Samples from the monitor wells were found to be contaminated with trichloroethene, 1,2-dichloroethane, and tetrachloroethene. The sediment samples from Bat Fork Creek and the small wastewater pond were found to be contaminated with PCBs (NUS, 1989). F-rom August 1988 to April 1989, GE conducted a Phase IIA Contamination Assessment to further characterize the extent of groundwater contamination. Twenty-six newly installed monitor wells (MW-10 to MW-28) and 42 private wells (WW-1 through WW-42) located between 200 feet and 0.5 mile from the GE property were sampled. Results indicated that the primary contaminants in groundwater are tetrachloroethene, trichloroethene, 1,2- dichloroethane, methyl chloride, and chloroform. The ·results also indicated.that the plume had spread out over most of the GE subsite and possible beyond the site boundaries into GE's neighbors' wells .. The highest concentrations, however, were detected in the monitor wells placed near the previously ruptured drain line, thus indicating that this drain line was the primary source_ of contamination (NUS, 1991a). 2-17 == i=i == r,;;;; a;! ---.. liiiil liiil -iiiiil -- - ---lBU0l0 [Tl C) . )>l"'l VJZ --1 [Tl :::0 ,i)> rr )> --1 [Tl r :::0 fT1 oo 0 --1 A :::0 . 0 ZVl Oc :::0 -0 --1 [Tl I :::0 0 '1 ► c :::0 z 00 r Vl z- )>~ '1 C) C :::0 [Tl N '-..J -0 :::0 ~ [Tl ::;E [Tl r r r 0 0 ~ 0 z (/) KING ST. 085 e 86 1st I ·• I -1l0 1lO =•nu 9 14 O 79 956 057 058 see e59 960 510 849 s2e ,..__... 48 25 042 47 46 26 94 ."'1-..!!!.~.::.:l.~l-64. 65 66 3~ 53 93 6 36 0 73 6 . e 71 7 33 38 Oe, • • 40 37 C?I 72 ~ ~ I I I I I I I I I I I I I I I GE/Shepherd Farm NPL Site Remedial Investigation Report Draft/ May 1995 From April to December of 1989, GE conducted contamination studies of the sediments in Bat Fork Creek, the two wastewater ponds, and the dried sludge impoundment. Analysis of the sediment samples collected from these ponds revealed that both wastewater treatment ponds and the dried sludge impoundment were contaminated with high levels of PCBs. No PCBs were found in Bat Fork Creek. GE estimated the quantity of sediment/soil contaminated with PCBs above 50 ppm in each impoundment to be (Law Environmental, 1990a): Large wastewater pond -17,400 tons (14,500 cubic yards) Small wastewater pond -3,300 tons (2,700 cubic yards) Dry sludge irnpoundment -4,500 tons (3,300 cubic yards) From May until August 1989, GE conducted a Phase IIB Contamination Assessment to further characterize the extent of groundwater contamination and to assess the extent of soil contamination along the previously ruptured drain line. Three additional monitor wells (MW- 29, MW-30, MW-30a) were installed along the perimeter of the site and sampled during this phase. Four existing monitor wells (MW-9, MW-12A, MW-14B, and MW-27 A) were also resampled. In addition, soil samples were collected at 5-foot intervals from two soil test borings (SB-11. and SB-12) drilled next to monitor wells MW-11 and MW-12. The sampling results again indicated that the primary contaminants in groundwater are tetrachloroethene, trichloroethene, 1,2-dichloroethene, 1,2-dichloroethane, and methylene chloride. The results also again indicated that the groundwater plume had reached the GE property boundaries. Low levels of these contaminants and a few other halogenated organics were also found in some of the soil samples collected below the water table (Law Engineering, 1989c). Between November 1989 and January 1990, GE removed ten petroleum product USTs from seven locations (UST Location Nos. 4, 7, 9, 10, 11, 12, and 15). GE reported that closure procedures were performed in compliance with applicable Federal and State requirements found in Part 280 of Title 40 of the Code of Federal Regulations. Samples were collected in the tank ~xcavation zones as well as beneath each UST until groundwater was encountered. One groundwater sample was also collected from the open excavation zone at each location. Chemical analysis of the samples detected petroleum hydrocarbon contamination in the soils . and/or groundwater at several Joca'tio·ns:. In April 1990, GE installed ·and s-ampled ·six ·monitor wells (MW-31 through MW-36) adjacent to the subject USTs to help define the extent of any petroleum hydrocarbon contamination present. Benzene was detected in the water sample from MW-33 at 8 micrograms/liter (ug/1) and naphthalene was detected in the water sample from MW-34 at 160 ug/1 (Law Engineering, 1990a). 2-19 I I I I I I I I I I I I u I I n GE/Shepherd Farm NPL Site Remedial Investigation Report Draft/ May 1995 From November 1989 to January 1990, GE also sampled 57 additional private residential wells located near the GE property. Tetrachloroethene was found in some of these wells but at very low concentrations (Bush, 1990). In May 1990, EPA conducted a Listing Site Inspection, Phase II, at the GE facility to obtain the data necessary for a subsequent scoring of the site, using the revised Hazard Ranking System, for inclusion on the NPL. A geophysical survey was conducted at Landfill B in an attempt to define the extent of landfilled material. Soil/sediment samples were collected from the sludge impoundment, the two wastewater treatment ponds, the landspreading plots (including the recreation area), the formerly ruptured drain line area, Landfill B, and background locations. Extensive organic and inorganic contamination was found at the sludge impoundment and the two wastewater treatment ponds. PCB-1248 and various extractable organics were detected at elevated concentrations in these three source areas, PCB-1248 was also found at Landfill B. Six onsite monitoring wells (MW-1 through MW-6) were also sampled during this investigation and found to contain tetrachloroethene, 1,2-dichloroethene, 1,2-dichloroethane, and trichloroethene at elevated concentrations. In addition, five sediment samples were collected along Bat Fork Creek, including one sample upgradient of the GE subsite (NUS, 1991a). During the EPA Listing Site Inspection, Phase II, for the GE facility, a Listing Site Inspection, Phase II, was also conducted at the Shepherd Farm property. A geophysical survey was conducted at this subsite in an attempt to delineate the waste disposal area (See Figure 2-3). Thirty-three soil samples were then collected from the suspected waste disposal area and from background locations. Extensive PCB and metals contamination was found in the soils onsite. A leachate sample taken from disposed drums found onsite also contained PCB and metals contamination. In addition, PCB and toluene contamination was found in sediment samples collected from the unnamed creek and Bat Fork Creek. Groundwater samples collected from four private wells located near the subsite and five temporary monitor wells installed along the banks of the unnamed creek and Bat Fork Creek indicated elevated levels of tetrachloroethene, 1,2-dichloroethene, vinyl chloride, trichloroethene, and lead (see Figure 2-8) (NUS, 1991 b ). During the EPA Listing Site Inspection, -Phase II, for the GE facility, one soil samp-le ·arid one sediment sample were also collected at the Seldon Clark property. PCB-1248 and 1260, lead, . manganese, nickel, vanadium, and chromium were detected at elevated concentrations in the soil sample, bu.t only lead was detected at an elevated concentration in the sediment sample (NUS, 1991a). 2-20 1111i! -111111 llllill !ail lliilil liiil liii iiiiil liiil liii -------- , , ,{oFFSITE ) ' SF-TW-01 43PB 1:.EGEND ~ PRIVATE WELL ,/ 8' ,le-I ~ "-SF-PW-03 J 7.6APCE , 7PB 4PB 3,8J PCE -PW-04 + A_ 140 PCE, 6PB / '~ 73PB, 511,2DCE, S0TCE, 170PCE, ,,/ , , -~~ / 140Bi5(2ETHYLPHENYL)PHTHALATE "-.. 8~-TW-08 26PCE, 27/ ~ ~~,, SF-TW-02 0 ) r--::::::::. '-...._ ./SF.;.TW-04 88JTCE,2.6J 1,2DCE, (j {J 'ff '. 3.2JVC 8F-TW-03ND 190PB D "' +TEMPORARY WELL )2 1-----------------------....--------------r------...;.N..;;.O.;.;TE;;.: ;.;.NO;.;T_T..;;.O..;;.SC;.;.A..;;.LE~ "' 0 ~ CONCENTRATIONS IN PPB SH~~l~gJ~.RM f::J LSI, PHASE II HENDERSON COUNTY ~EPA FIGURE 2.8 GROUNDWATER SAMPLE LOCATION MAP u'i MAY, 1990 NORTH CAROLINA ~L..-----------....1.. __________ ..i_ ____________ ..1-__________ __. I I I I I I I I I I I •-- 1 I I I GE/Shepherd Farm NPL Site Remedial Investigation Report Draft / May 1995 From May until August 1990, GE conducted a Phase IIIA Groundwater Quality Assessment at the GE facility in preparation for performing groundwater remediation. Monitor well MW- 37 was installed downgradient of the sludge impoundment and sampled to determine if the relatively high concentrations of voes found in MW-14 and MW014A were originating from the sludge impoundment. Thirty-one existing monitor wells were also sampled to determine the present extent of contamination at the time. The results of this sampling event were generally consistent with the results from previous sampling events. Groundwater voe concentration maps prepared by GE based on the results of this sampling event are presented in Figures 2-9 through 2-11. The results indicate tetrachloroethene is the major contaminant present in groundwater beneath the site and, as discovered before, the greatest contaminant concentrations are present along the failed drain line. However, high concentrations of voes were also found along the railroad line southwest of the failed drain line area, indicating that a preferential flow path may be present along the railroad, or that another source of contamination is present in this area. One possible source identified in this investigation was an old drainage ditch which existed prior to construction of the drain line. The concentrations of voes in MW-37 were found to be well below those found in MW-14 and MW-14A thus indicating that the sludge impoundment is probably not a major source of voe contamination (Law Environmental, 1990b). In August 1990 and November 1990, GE conducted quarterly groundwater sampling of the monitor wells around former UST areas (MW-31 through MW-36). During both events, MW-34 was found to have a thin layer (approximately 0.1 feet) of separate phase hydrocarbons and therefore was not sampled. In the other monitor wells, as before, petroleum hydrocarbon contamination (ethylbenzene and xylenes) was only found in MW-33 and at low levels. Other voe contamination was found in MW-33 and some of the other wells sampled, but this contamination is believed to related to the failed drain line (Law Engineering, 1990b and 1991a). From January through February 1991, GE conducted a Phase II Environmental Assessment at the former UST #9 area, to further assess the horizontal extent of groundwater contamination by petroleum hydrocarbons resulting from UST #9 leakage. Two additional monitor wells (MW-45 and MW-46) were installed downgradient of the UST and sampled. Petroleum hydro·carooii contamination (benzene,-ethylbenzene, and xylenesj was -found in-both these monitor wells with the highest concentrations in MW-46 (Law Engineering, 1991c). GE reports that all USTs and contaminated soils associated with these USTs have been removed. GE also reports that contaminated soil associated with the ruptured drain line have 2-22 I I I I I I I I I • I I I I I I I I I C, -< 0 __, N "' z -------20 TETRACHLOROETHENE CONCENTRATIONS I I I I II I I \ I . o/~ li . / '-.. , .. ............ IN GROUNDWATER (MAY 1990) 1---------------------------1 FIGURE 2.9 ~EPA GENERAL ELECTRIC SUPERFUND SITE EAST FLAT ROCK, NORTH CAROLINA I I I I I I I u n g I I I I I I I I , I I I I I I !· ,.✓---------~ I i'• I \ I I g '~ .. ~ .. .............. ~/ ---~-~==~ t J ~! fs I , , - TRICHLOROETHENE CONCENTRATIONS IN GROUNDWATER (MAY 1990) 1---------,--------------------IFIGURE 2.10 ~ ~/7EnA GENERAL ELECTR1c suPERFuNo s1TE I ,-::: ~ r""'JF!\ EAST FLAT ROCK, NORTH CAROLINA ~.___-----------------L------1 I l&EPA I I I ------------------------lFIGURE 2.y2 ADDITIONAL voe CONCENTRATIONS IN GROUNDWATER (MAY 1990) GE/SHEPHERD FARM PROPERTY EAST FLAT ROCK, NORTH CAROLINA I I I I I I I H I I I I I I I I 'I 'I GE/Shepherd Farm NFL Site Remedial Investigation Report Draft/ May 1995 been removed. City water mains have been extended to areas near GE, and GE has paid for connections to these water mains and/or provided bottled water for some households (EPA, 1993). In 1990, GE also conducted a Phase IIIA Aquifer Characterization and Groundwater Treatment Study at the GE facility in preparation for performing groundwater remediation. In this study, a pilot groundwater recovery and treatment system was designed and installed at the GE subsite. The system consisted of four groundwater recovery wells (RW-1 through RW-4), a 10,000-gallon equalization tank, an air stripping tower, and associated piping and pumps with discharge going to Bat Fork Creek. Seven observation wells (MW-38 through MW-44) were also constructed for measuring water levels during an aquifer performance test. Step-drawdown tests, an aquifer performance test, and groundwater modeling were performed to determine the optimum recovery well system configuration and flow rates to capture the contaminant plume. Based on the study results, recommendations were made and a conceptual design was prepared for a permanent groundwater recovery and treatment system (Law Environmental, 1991a, b, and c). However, this system was never implemented. GE has also worked to reduce the amount of process wastewater discharged to Bat Fork Creek, having reduced it by 75% over the past 15 years. In addition, GE reported that by the end of 1993, they would cease discharging their process wastewater into Bat Fork Creek and instead route the effluent to the public wastewater treatment system (ATSDR, 1993). According to recent conversations with GE, however, this change has not yet been implemented. · 2.4 srrE REGULATORY ACTIONS The GE facility filed Part A of a hazardous waste permit for storage in 1980 under the J!Zesource Conservation and Recovery Act (RCRA). In March 1982, GE petitioned to have its F006 electroplating sludge delisted as a hazardous waste. By April 1982, EPA issued a preliminary decision to declare the F006 waste as nonhazardous. The state of North Carolina accepted the petition and delisted F006 waste in October 1982. In 1984, GE elected to dispose of accumulated wastes offsite and therefore withdrew the Part A hazardous waste permit application-and related interim status. On September-(9", 1988,--EPA for~ally--- . recognized the state-approved delisting of F006 electroplating sludge as a hazardous waste (NUS, 1991a) .. GE has an NPDES permit for the discharge of treated effluent into Bat Fork Creek which 2-26 I I I I I I I I D B I I I I I I I I I GE/Shepherd Farm NPL Site Remedial Investigation Report Draft/ May 1995 became effective on May 1, 1989. GE also has an air permit issued on February 25, 1988, to operate several air emission sources or clean air devices (NUS, 1991a). No permits were issued for waste disposal at the Shepherd Farm or Seldon Clark properties, as the final disposition of all waste material occurred prior to the enactment of RCRA. After the EPA Screening Site Inspections and Listing Site Inspections described above were completed, the GE, Shepherd Farm, and Seldon Clark properties were proposed for inclusion on the NPL on February 7, 1992, as the "General Electric/Shepherd Farm Site". The Site was finalized on the NPL in December 1994. The Agency for Toxic Substances and Disease Registry (ATSDR) completed a Preliminary Public Health Assessment in March 1993. Based on this assessment, ATSDR concluded the following: "ATSDR considers the site to be an indeterminate public health hazard. The limited available data do not indicate that individuals are being exposed to contamination at levels that would be expected to cause adverse health effects at the present time. However, there is insufficient environmental data (air, biota, water, and soil data) to evaluate all the past pathways of exposure to which humans may have been exposed." ATSDR recommended that the exposure to contaminants in private wells be further reduced, and that media and biota potentially contaminated by site-related constituents be further characterized (ATSDR, 1993). 2.5 DEMOGRAPHY The GE Site is located in Henderson County, North Carolina, which had a 1990 census p·opulation of 69,285. The town of Hendersonville (the County Seat), the center of which is located approximately 3.5 miles northwest of the site, had a 1990 census population of about 7,300. The county population is aboui 79% white and 20% black, but in the site vicinity, the distribution is about 96% white and 2% black (ATSDR, 1993). . Based upon a house count from USGS topographic maps, the popuiation-~iiliin \ rnile--of the GE and Seldon Clark subsites (excluding the approximate 1,100 GE plant employees) is estimated to be 1,010. The nearest residence is adjacent to the southeast property boundary. The nearest school (currently not in use) is about 2,500 feet northwest of the property and two others are located about 5,000 feet to the west. No nursing homes or hospitals _are 2-27 I I I I I I I I D D I I •--. I- I I I GE/Shepherd Farm NPL Site Remedial Investigation Report Draft/ May 1995 presently located within 1 mile of the GE and Seldon Clark subsites (ATSDR, 1993). Spring Haven Trailer Park at the Shepherd Farm subsite is a quality development of 90 homes. Approximately two-thirds of these homes are occupied year-round. Each unit has one or two persons and the average age is 67. Children are not permitted to live in the development but are present occasionally as visitors. Several of the Spring Haven units are located within the subsite disposal area while most of the other units are located within 500 feet. Four other residences on the south side of Roper Road (three at the Seldon Hill Farm and one at the Shepherd Farm) are also within 500 feet of the subsite disposal area. Based upon a house count from USGS topographic maps, the population within I mile of the Shepherd Farm property is estimated to be 1,044. Two schools are located about 2,000 and 2,500 feet west of the property. No nursing homes or hospitals are presently located mthin 1 mile of the Shepherd Fann subsite (ATSDR, 1993). 2.6 SURROUNDING LAND/WATER USE The principal land use in the immediate vicinity of the GE and Seldon Clark subsites is residential. Some commercial and light industrial uses occur along Spartanburg Highway, however, and a large plant is on the north side of Tabor Road, across from the GE plant and east of the Seldon Clark property. A large power substation also adjoins the southeast boundary of the GE property. Open spaces surrounding the subsites are generally undeveloped or farmed land. Orchards are prominent to the northeast of the subsites (ATSDR, 1993). The Shepherd Farm subsite is located in a rural/agricultural area where land use is principally residential, forest, or farmland. The nearest commercial and industrial activity is along Spartanburg Highway, about 2000 feet to the north and east (ATSDR, 1993). Land is lightly developed along Bat Fork Creek, both upstream and downstream of the GE site, and also along Mud Creek into which Bat Fork Creek discharges approximately 6 miles downstream of. the GE subsite. Approximately 90% of the land along Bat Fork Creek is used for agriculture and the remaining 10% supports urbanized land uses. Apple orchards -comprise -60%-of the agricultural land-use followecl b·y ve1i°etable farrru;, hayfields~ and fallow fields combining for 30 percent of the agricultural land use (Law Environmental, 1990c). Major natural resources in the area include surface waters (including some wetlands) and groundwater. While irrigation of agricultural lands along Bat Fork Creek is unlikely due to 2-28 I I I I I I m I I I 0 I I I I I GE/Shepherd Farm NPL Site Remedial Investigation Repo1t Draft/ May 1995 the relatively low volume of flow, residents have reportedly used the creek for watering gardens. In addition, some livestock are likely to obtain water from the stream. While the steep banks, dense undergrowth, and narrow width of Bat Fork Creek may limit its utility for recreational fishing, some recreational fishing in this creek has been reported by residents. Bat Fork Creek flows into Mud Creek (also used for recreational fishing) which in turn flows into the French Broad River. The French Broad River is used for recreational fishing, swimming, and boating. However, there are no public water intakes along any portion of the surface waters downstream of the GE subsite (ATSDR, 1993). The Henderson.ville public water system obtains its raw water from three surface water intakes which are outside the watersheds possibly affected by the GE site. The GE facility has been connected to this public water system since it began operations. In addition, the majority of the residents within.a 4-mile radius of the site are also connected to this system. Many homes and businesses near the site have relied on private wells (drilled in the shallow aquifer and averaging about 120 feet deep) for potable water in the past, and some still rely on private wells, but increasing numbers are being connected to the public system. The GE facility has provided bottled water to many residents in the vicinity of both the GE subsite and the Shepherd Farm subsite, and has paid for some connections to the public water system. At the Shepherd Farm subsite, the Spring Haven development has always been connected to the public water system. The four residents at the Seldon Hill Farm and Shepherd Farm once relied on private wells for potable water, but are now connected to the public water system. The closest wells still being used for potable water are believed to be about 1500 feet east of the subsite (ATSDR, 1993). 2.7 ENVIRONMENTAL SETTING 2,7.1 PHYSIOGRAPHYn'OPOGRAPHY The GE Site is located within the Blue Ridge Physiographic Province of the Appalachian Highlands in the southern Appalachian Mountains. Topography in the area is characterized as rugged with large hills and rounded rnountains, and steep slopes and narrow valleys, but also · · -·with some flat .areas in a few small valleys~ The· Asheville=Henderso-nville area ·is · · characterized by a central plateau (the Asheville Plateau) with moderate relief of 500 to 600 feet, surrounded on all sides by mountains .. Elevation of the Asheville Plateau is approximately 2200 feet above mean sea level (ams!) (NUS, 1991a). 2-29 I I I I I I I I I I D I u I I I I GE/Shepherd Farm NPL Site Remedial Investigation Report Draft/ May 1995 The region roughly corresponding to the present Appalachian Mountains was folded, faulted, and uplifted into high mountains during the Appalachian orogeny, and subsequently eroded into an essentially flat surface. The present mountains are the product of more recent regional uplift and differential erosion of older structures. The regional trend of the Appalachian structures is parallel to the regional strike of the folded rocks which is northeast- southwest. A minor alignment of mountain surface corresponds to an eastward trend as well, but this northeast-southwest trending rock controls the pathways of rivers and creeks in the area. A major thrust fault called the Brevard Fault Zone occurs about 11 miles to the northwest of the site (Trapp, 1970). The general topographic relief over the site is presented in Figure 2-12. The area around the site consists of gently rolling hills with elevations at about 2100 to 2500 feet ams!. The slope at the GE subsite is generally to the southeast at about 2 percent. The slope at the Seldon Clark subsite is generally to the northeast at about 4 percent. The slope at the Shepherd Farm subsite is generally to the northwest at about 10 percent. 2.7.2 CLIMATE/METEOROLOGY The climate of the region is humid-continental. Average monthly temperatures range from 41 ° F in January to 77° F in July (Wallingford, 1989) .. Mean annual precipitation is 38 inches and mean annual lake evaporation is 34 inches. Mean maximum 24-hour rainfall is 3.7 inches (NUS, 1991a). 2.7.3 . GEOLOGY Most soils in the Blue Ridge Province are residual soils derived from weathering of the underlying bedrock; These soils may be shallow to deep and are typically clayey, although locally they may be coarse-grained. Other soils are derived from alluvium along the floodplains of major streams (Law Environmental, 1990b). Based on several borings performed at the GE subsite, the soils at the site can generally be ··described ·as brown,· micaceous; ·sandy•silt near the-surface; grading-downward to loose firm,·-·- red-brown and dark brown, micaceous silty medium to coarse sand. The thickness of the residual soil at the GE subsite ranged from less than 1 foot to 88 feet. The boundary between soil and rock is a transition zone of very dense, partially weathered rock. The partially weathered rock (PWR) at the GE subsite is generally between 2 and 15 feet thick (Law 2-30 I I I I I I I I I I D I I SOURCE: USGS 7.5' QUADRANGLE MAP (HENDERSONVILLE, NC)-1990 11-----------------,-------, • 1 &2EPA GENERAL SITE TOPOGRAPHY GE/SHEPHERD FARM PROPERTY EAST FLAT ROCK, NORTH CAROLINA /.)-- Fl GU RE. 2.j) nL __________________________________ .,_ _____ ~ I I I I I I I I I I I I I H I R I I Environmental, 1990b). GE/Shepherd Farm NPL Site Remedial Investigation Report Draft/ May 1995 The residuum in the Hendersonville area (including the site) are underlain by fractured crystalline bedrock of Pre-Cambrian age. The typical rock types are gneiss and mica-schist. These metamorphic rocks are intruded by granites of Precambrian and Paleozoic ages. Directly below the site is the Henderson Gneiss, a biotite gneiss unit that contains feldspar porphyroblasts in a finer-grained biotite gneiss matrix. Coarse granite, biotite gneiss, hornblende gneiss, and mica schist occur as local rock bodies within the Henderson Gneiss (NUS, 1991a). Cores taken from the bedrock at the GE subsite ranged from severely weathered to fresh. Numerous gently to moderately dipping fractures were observed in the cores (Law Environmental, 1990b ). 1n general, however, the size and frequency of fractures decrease markedly with increasing depth. 1n this type of terrain, approximately 90% of the fractures typically occur within the upper 100 feet of bedrock. 2.7.4 HYDROGEOLOGY The shallow groundwater surface in the Blue Ridge Province generally occurs within the residual and alluvial soils. Water occurs in the pore spaces of these soils and the PWR, within the relict fractures of the PWR, and within the fractures and secondary openings of the underlying bedrock. Although the soil/PWR zone (hereinafter referred to as the "porous media" zone), and the bedrock zone (hereinafter referred to as the "fractured media" zone) are sometimes referred to as different aquifers, they actually comprise one shallow unconfined aquifer since the two zones are hydraulically connected as evidenced by the lack of both a confining zone· and significant head difference between the two zones. Groundwater flow in the Blue Ridge Province generally follows the topography. Recharge occurs from infiltration of precipitation on the hill and mountain slopes, while discharge generally occurs at the streams and springs. Wells installed in the soils generally have low yields but are adequate for domestic use. The amount of water produced from the deeper water-bearing fractures depends on the number and size of fractures encountered by a well. Average yield from private wells in the area is approximately 18 gallons per minute (gpm) (NUS, 1991a). The groundwater surface at the site has been observed in monitor wells at depths ranging from 3 to 29 feet below ground surface (NUS, 1991a and 1991b). A potentiometric surface map of the-GE subsite is presented in Figure 2-13. As seeidn.this figure, groundwater at the GE and Seldon Clark subsites generally flows from the northwest toward the south and east 2-32 ~ ~5 i ~~ . -i ~ i\ :i i ~ I;; !!~ ~ os; ~ ~ . " (';I I >t,/ ~ ~ I~~ ~ -4 I I -;. h /' ,. ~~ •• I I ~ o\ ·\ '¼-,c" I II I i \ I \ I , GE SUBSITE GROUNDWATER LEVELS (MAY 1990) /3 ------------------------1 FIGURE 2.fo ~EPA GE/SHEPHERD FARM PROPERTY EAST FLAT ROCK, NORTH CAROLINA I I I I I I I I I I I I I I I I I I I GE/Shepherd Farm NPL Site Remedial Investigation Report Draft/ May 1995 before discharging into Bat Fork Creek. No water level measurements were collected at the Shepherd Farm subsite, but based on the topography at this subsite, groundwater flow is expected to be toward the west and north before discharging into Bat Fork Creek. Due to the highly heterogeneous and anisotropic nature of the shallow aquifer system, the hydraulic properties of the shallow aquifer are expected to vary greatly from one location to another. Generally, however, from an area-wide perspective, the hydraulic conductivity of the shallow aquifer in both the porous and upper fractured media zones is expected to range from approximately 1 to 10 feei/day and average about 4 feet/day, based on the results of an aquifer performance test performed at the GE subsite (Law Environmental, 1991a). Based on this average hydraulic conductivity, a hydraulic gradient ranging from 0.01 to 0.05 feet/feet as · shown in Figure 2-6, and assumed effective porosities of 0.20 for the porous media and 0.10 for the upper fractured media, the horizontal groundwater velocities at the GE and Seldon Clark subsites are estimated to rang(ffrom about 0.2 to 1 feet/day in the porous media zone and 0.4 to 2 feet/day in the upper fractured media zone. The hydraulic gradient and hence the horizontal groundwater velocities at the Shepherd Farm subsite are expected to be slightly higher due to the steeper topography at this subsite. Note that although the general direction of groundwater flow at all three subsites is toward Bat Fork Creek, the actual direction of groundwater flow in the fractured media zone at any given location may vary substantially from the general direction of flow, due to the extremely anisotropic and heterogeneous nature of fractured rock aquifers. Groundwater flow in the fractured media zone is controlled by the geometry, orientation, and interconnections within the bedrock fractures. Because these properties are usually quite variable in fractured rock aquifers, a complex three-dimensional flow field most likely exists at this site. 2.7.5 HYDROLOGY The surface water features potentially affected by the GE and Seldon Clark subsites include Bat Fork Creek and Mud Creek. The surface water features potentially affected by the Shepherd Farm subsite include the unnamed intermittent creek running through the subsite and into Bat Fork Creek, Bat Fork Creek, and Mud Creek. These surface waters have been classified· as "Class C" by the State, \vhich ii;' the· oasic water qu·ality classification for all surface waters _in the State of North Carolina, and protects freshwaters for secondary recreation, fishing, and aquatic life. Wetland areas are also known to be located along Bat Fork and Mud Creeks, but their locations are not evident on the USGS topographic maps (NUS, 1991a). 2-34 I I I I I I I I I I I I I I I I I I I GE/Shepherd Farm NPL Site Remedial Investigation Report Draft/ May 1995 Runoff from all three subsites discharges into Bat Fork Creek. At the Shepherd Farm subsite, runoff also discharges into the unnamed tributary which then discharges into Bat Fork Creek approximately 400 feet to the northwest. At the GE facility, a natural spring which also discharges into Bat Fork Creek is located in a swampy area between Bat Fork Creek and the easternmost landspreading plots. In addition, GE has an NPDES permit to discharge treated industrial effluent into Bat Fork Creek from the GE facility surface impoundments (NUS, 1991a). GE has reported that their discharge accounts for approximately 40% of the flow at that location. GE also reported, however, that by the end of 1993, they would cease discharging their industrial effluent into Bat Fork Creek and instead route the effluent to the public wastewater treatment system (A TSDR, 1993). As of the date of this report, this event has not yet occurred. Bat Fork Creek is a perennial surface water body which, from visual observation, appears to· be about 10 feet wide and less than l· foot deep at the site under normal flow conditions. The average gradient of Bat Fork Creek at the site is approximately 24 feet per mile. The stream lies within the French Broad River basin which is part of the Tennessee River Valley drainage system. Bat Fork Creek is basically unaltered from its headwaters to a point about 200 feet downgradient of Tabor Road. Extensive channel alteration by dredging, however, has occurred throughout the remaining portion of the stream basin. Numerous unnamed ditches and tril;mtaries contribute flow to Bat Fork Creek, primarily during wet weather (Law Environmental, 1990c). 2.7.6 WILDLIFE NATURAL RESOURCES As indicated above, agricultural lands comprised primarily of apple orchards are the primary land use along Bat Fork Creek. These lands also provide limited opportunities for hunting of bobwhite quail (Colinius virginianus) and mourning dove (Zenaida macroura), with access controlled by private landowners. Gray squirrel and fox squirrel are also hunted in adjacent hardwood forest borders (Law Environmental, 1990c). Recreational fishing opportunities in Bat Fork Creek are essentially nonexistent according to North Carolina Wildlife Resources Commission (NCWRC) biologists due to the small size of the stream. However, -a study conducted by Law (1990) conch1ded that Bat"Fork Creek, though small, supports a fish population that is relatively diverse and composed of edible and harvestable size fish at a level of abundance that could potentially sustain a limited, yet low pressure fishery for Centrarchid sunfishes. Eleven species of fish totaling 117 individuals were collected at three sampling stations in Bat Fork Creek in this study. In addition, 2-35 I I I I I I I I I I I I I I I g n D I GE/Shepherd Farm NPL Site Remedial Investigation Report Draft/ May 1995 according to NCWRC biologists, a fishery for bullhead catfish, largemouth bass, and various sunfishes exists in Mud Creek, the receiving stream for Bat Fork Creek, approximately three to four miles downstream of the site (Law Environmental, 1990c). A historically important waterfowl hunting area and currently important wood duck (Aix sponsa) nesting area is located approximately four to five miles downstream of the site. Other waterfowl species known to use this wetland site include Canada goose (Branta canadensis), American black duck (Anas rubripes), gadwall (A. strepera), mallard (6.:. platyrhynchos). blue-winged teal (A. discors). green-winged teal (A. crecca), and common· pintail (A. acuta). Osprey (Pandion haliaetus) have also been observed in the area by NCWRC biologists, but reported bald eagle (Haliaeetus leucocephalus) sightings have been unconfirmed. Several small mammals are also known to inhabit the wetland area, as well as the adjacent stream systems, including beaver (Castor canadensis), muskrat (Ondatra zibethica), gray fox (Urocyon cinereoargenteus). and raccoon (Procyon lotor) (Law Environmental, 1990c). The French Broad River Basin and Henderson/Asheville areas are the site of three federally listed endangered plant species. These species include the swamp pink plant (Helonias bullata), mountain sweet pitcher plant (Sarracenia jonesii), and the bunched arrowhead plant (Sagittaria fasciculata). The bunched arrowhead plant exists on the GE property west of Spartanburg Highway and is one of only two known locations in North Carolina where the species occurs .. GE cooperates with the Nature Conservancy in Chapel Hill, North Carolina, to protect this plant (Law Environmental, 1990c). · The bog turtle (Clemmys muhlenbergi) is designated as a state endangered species by North Carolina. This reptile is known to exist in bog habitats within the French Broad River Basin. No federal threatened or endangered terrestrial or aquatic animal species or critical habitats are known to exist, however, along Bat Fork Creek (Law Environmental, 1990c). 2-36 I I I I I I I I I I I I n D D I I I 3.0 SAMPLING STRATEGY GE/Shepherd Farm NPL Site Remedial Investigation Report Draft I May, 1995 This remedial investigation included the collection of soil, sediment, surface water and ground water samples specified in the Project Operations Plan (POP), August, 1994. The sampling investigation was conducted during September, 1994. All samples collected were analyzed for volatile and extractable organic compounds, pesticides, PCB's and metals. 3.1 Sample Collection All samples were collected in accordance with Section 4 of the United States Environmental Protection Agency, Region IV, Environmental Services Division, Environmental Compliance Branch Standard Operating Procedures and Quality Assurance Manual, Febrnary I, 1991 (3). The quality assurance and quality control procedures described in this manual insure that representative samples are collected from the various media sampled. A copy of the manual, in addition to the Work Plan and Field Sampling and Analysis Plan, was maintained at the field office/command post for reference during all phases of the field sampling activities. Any deviations in sampling procedures were recorded in the field log books. Replicate and variability samples were collected for 5 percent of the soil samples. Split sediment, surface water and ground water samples were also collected. This provided a check for sampling techniques. In addition, water trip blanks were prepared with organic free water by the Analytical Support Branch (ASB). The trip blanks were transported to the field, handled and stored with the samples collected from the site. This provided a check to detennine if samples may have been contaminated during handling and storage. 3.2 Sample Identification Samples collected during the project were designated using an eight digit alphanumeric code in the fonn of: GE-XXX-YYY. The prefix "GE" (for General Electric) was used on all · sample designations. The "XXX" represents a three digit alphanumeric sample number corresponding to the sample collection location. The sample collection locations are specified on the Figures presented in Section 4. In general, the samples were numbered as follows: 00 I -199 Nonna! grab or composite sample · 401 -499 -Replicate (split) sample 501 -599 -Soil co-located (variability) sample 701 -799 QA/QC samples , The last two digits of the replicate and/or the co-located samples will, in general, correspond to the sample collection location. For example, sample GE-425-GW is a replicate of sample 3-1 I I I I I I I I I I I I I I n H I GE/Shepherd Fann NPL Site Remedial Investigation Report Draft / May, 1995 GE-025-GW, and sample GE-530-SLA is a sample co-located to sample GE-030-SLA. Co- located samples were collected I foot due north of the sample collection location. If the sample was a composite, then aliquots were collected I foot due north from each aliquot collection location. The "YYY" represents the next two or three letters which indicate the sample matrix as specified below: SW - GW - SD SL - Surface Water Ground Water Sediment Soil A third letter was used with the "SL" designation and represented the depth from which the sample was collected as specified below: SLA -0-6 inches ELS SLE 3-4 feet ELS SLC -6-8 feet ELS Other third letter designations were assigned as conditions warranted. When discussing the analytical results in this report, the "GE''. and any preceding O's will be eliminated. For example, sample GE-001-SLA will be referred to as sample 1-SLA. 3.3 Soil Sampling Thirty four surface soil samples and 41 subsurface soil samples were collected during this investigation. In general, the surface soil sampling interval was O to 6 inches ELS and the · subsurface soil sampling intervals were three feet to four feet ELS and 6 to eight feet ELS. 3.3.1 GE Property Twenty surface soil samples and 21 subsurface soil samples were collected from the la11dspreading ·areas, along -the drain ·urie arid fonnei' ditch;· alo-ng the railroad track and frcim the present and two fonner landfills. These numbers include replicate and co-located samples. Landspreading Areas A and E were divided into eight sub-areas as indicated on Figure 3.1. One composite surface soil sample was collected from each of these sub-areas. Each 3-2 I I I I I I I I I I I I D I I I I I I GE1Shepherd Fann NPL Site Remedial Investigation Report Draft / May, 1995 composite sample consisted of five aliquots. One sample aliquot was collected from the center of each area at a depth of Oto 6 inches below land surface (BLS). The VOA sample container was filled from this aliquot. Also, four additional aliquots of soil were collected from each area from a depth of 0 to 6 inches BLS and composited with the soil sample collected from the center of the area to generate one sample for extractable organic compound, pesticide, PCB's and metals analyses. The four additional sampling locations in each area were located approximately 75 feet from the center of each area at angles of 45°, 135°, 225° and 315° from north. A grab subsurface soil sample was collected from the center of each sub-area at a depth of three feet to four feet BLS. Lanclspreacling area C, which is currently a recreation area, was cliviclecl into two sub-areas. The five aliquots for each surface soil sample (0-6 inches BLS) were randomly spaced around the buildings in one sub-area and around the baseball field in the other sub-area. A grab subsurface soil sample was collected from the each sub-area at a depth of three feet to four feet BLS. One composite surface soil sample (0-6 inch BLS) consisting of five aliquots was collected from lanclspreading area D. One aliquot was collected from the center of the area. The four additional sampling locations were located approximately 75 feet from the center of the area at angles of 45°, 135°, 225° and 315° from north. A grab subsurface soil sample was be collected from the center of the area at a depth of three feet to four.feet BLS. A total of 11 surface soil samples and 11 subsurface soil samples were collected from the lanclspreading areas. Three landfills, designated A, Band C, exist on site. Grab surface soil and grab subsurface soil samples were collected from landfill A. L111clfill A.is currently paved over with asphalt. Consequently, the surface soil sampling interval was 6 inches to 12 inches BLS, to lessen the impact of the asphalt on the sample. The subsurface samples were collected from three feet · to four feet BLS and six to eight feet ELS. The surface and subsurface soil sampling intervals for landfills Band C were Oto 6 inches BLS and three feet to four feet BLS, respectively. Four subsurface soil samples were collected from two locations beneath the drain line/fom1er -. clitcff . . One loc,itioii was. off the east comer of the· 1i1ain plant and tlie other-was clue west of the OV Stores building. The sampling intervals were three to four feet BLS and six to eight feet BLS. 3-3 -== 382L01CT ,--ijt m j r7~ J> z (() r7 -{ ;;o 77 J> rr J> r7 -ir ;;o r7 □~ n;;o ;,;:,_. ' n z (() □c ;;o cl -{ r7 :c ;;o n77 J>c ;;oz □ t::J r vl ............ z -{ J> r7 77 ...... C\ C ;;o r7 w >---C\ r7 cl ;;o D cl r7 ;;o -{ -< (() D ...... r (/) J> 3: cl r ...... z C\ r D n J> -{ ...... D z (() liiiilil llilii1 -liiiii liiiii iiii iiii -------SL-Cl 9 ,-----"-=-,---mAIN LINE: \J\ " //~ // "\'.:::::c,.==----// ~ ... ~~~. ·, // :'('"-:,.,, ,'\., -.:\~~,:,_\''-~'."'-'/ /..Z:::..:>-::~~:~t--.:.;,~--:-,..~\~·,~::::,:~. ' (<-{\~?:ilt\~t.i~\t.l\\\:~.='-..... ~.... ~~~---~~-~~~\~,~.lD:::'~-~'('(,~~~:;z,:. y SPRING res--:~~~ ----.:::z-:, .. "'-.\l\t~>\\\·1'i:~t~\~~\*\~}~~\: \' ~"~'--.:s., ... ~ .... ,.... -....'"-':-,,'., ·-,:,~,·-....,:-..'-··~\''-'\\:::'-'..'..•_. \ z_-.;-,,~-..:'-;,~;-,':_:~~ ,.:::.:::,, ~'-:-,_-';._":~.,,-00~,<--.;"-'.~~,,~-,·,,-z,~, . ~}'" /~i.~f~\\i\~1~~~\~~.. '<~.:::", ·,·'='\~\~~\\~~\~~\~\\\~~~ · ,_,..~ I) _,,,-, :,,"-,>,·..:· ,_,,,,-.,-:,.;, '' ~' ,_,, '· ''SI.~..:.:' ·'-:s...,,,,-.;s:,.. ....,_ (:Q,..__ fi,<~tt,\\~\~~~. '{,}~f.:~\\~\~~-'--',~:,.' ~~~}~?.~~\~\~~~~'\~;;\, .... ~ :-;_,,.,,,\_,-,,,~~'Si.;':.~~~"-'•).'.~'-'-'-. '•\•'-..""· :·' .. "¼:.'¾~t'\'•·/::"">-~~ I -\\'Ss~\\~1~\\)i.1}i~\\t.~~.--~~w ~" ~\~it}zt~ . ~"~>,'¢:~\\~~~~\;f~ ~\~~\~~~~' , "~~,\\~~oaf-JV \.'-~\~'-::.\~· r--_ ""---.,.-.;,.: •"'-.~'.\i>-SLUDGE -\'.'>.•..;,~',,,~,: --.....,.. __ I\._ IHPCJJNDKENT t·•>.·-....:;__\~~ -.-..:-._'-~ ... ,_,~ K''~\'--:-.· i,·~•::--,,~'-' /-..--...;~'.&---_.::.~':: ~:--... ~"'\.'\,.,1 ~~'-""-~,.\ R"'-'S-~"':-1 l,\-.:·.,.•.:>) '~i-~'\) MAIN PLANT ... WAREHOUSE "' -~, -SCALE IN FEET Willlll ~ -.ASDIL SAMPLING LOCATIONS ~ L.ANDSPREADIHG PL□TS ~ FDRHER LAHDFILL RE:CREATION FACILITY '· '· '· □ L------l k SPARTANBLRG HYY --1 . \ II ~········ ~ A~-"""-· ~--~ I - I I I I I I I I I I I I I g D I R I R GE/Shepherd Fann NPL Site Remedial Investigation Rcpo,1 Draft / May, 1995 Two subsurface soil samples were collected along the railroad track. One location was off the east comer of the main plant and the other was west of the warehouse building. The samples were collected just below the railroad gravel bed. Soil borings were completed at three former UST areas. One soil sample was collected at a depth of 12 feet BLS or just above the water table interface at two of the borings locations. Location 20 was in the grassy area northeast of tanks one, four and five; location 22 was in the area of tanks I 0, 11 and 15. Location 19 was in the parking lot south of tanks one, six, seven, eight. This sa111ple was collected by O'Brien and Gere Inc. personnel, fro111 just below the asphalt. Figure 3.1 indicates the locations of the under ground storage tanks. 3.3.2 Seldon Clark Property Soil borings were drilled at three locations, as indicated on Figure 3.2. Locations 30 and 3 I were in the fill area on the Seldon Clark property and location 32, which is considered a background location, is west across Spartanburg Highway. The fill material sample, 31-SLE was collected from a depth of 12 to 14 feet BLS. Samples 30-SLF and 31-SLF were collected from native soil immediately below the fill material at depths of 30 to 32 feet BLS and 38 to 40 feet BLS, respectively. Three samples were collected·.from location 32 at depths of 6 to 18 inches BLS, 3 to 4 feet BLS and 6.5 to 7.5 feet BLS. They are identified as 32-SLA, 32-SLB and 32-SLC, respectively. 3.3.3 Shepherd Farm Property Thirteen composite surface soil samples and 15 subsurface grab samples were collected from the Shepherd Fann property. The surface soil sample interval was Oto 6 inches BLS and the subsurface soil sampling intervals were three feet to four feet BLS and six to eight feet BLS. Eight surface and eight subsurface samples were collected from yards in the Spring Haven · trailer Park. Section 4, Table 4.4 presents the address for each residence sampled and Figure 3.3 indicates the locations. Each surface soil composite sample consisted of three to six aliquots selected from random locations in the front and back yards. The VOA container was filled from the first aliquot of soil collected. The subsurface soil sampling intervals and collection locations are discussed in Section 4. The three samples collected from location 50 are considered control sari1ples for the-study. The fill area located behind and west of the Shepherd house and north of the Spring Haven trailer park was divided into five areas as illustrated on Figure 3.3. One composite surface soil sample, each consisting of five aliquots, was collected from each area. The surface soil sample interval was Oto 6 inches BLS. One aliquot was collected from the center of the grid. 3-5 I I I I I I I I I I I I I I I . 1 u I I f-z s CL w C) .... z w :; i5 w "' D z < QC Ot,.-0& w .... i &o~ w ~ ~ ~ a! QC O=> 0 "'V, .., I I 0 • ·* 0:: 0 w .., 2 ~ 0 * ..t. i 0:: <( ~ H:Jll w Ow a::: LL 0:: I f-S2 V) o<C 0 -I 0 V) I-w_J w ~_J (.'.) z a::: 0 ~ :;,;LL ::::, -, m z f-;;; z I (f) 0 i'.5 t:; <( • .., a::: w a::: u_ 0 <( / 0 ;;; o._ :::, V) .., ~ -' a::: <) 0 <O ./' u, f-r--. V) ~ V) 0 ::::, 0 I ... 3nN3Al;I 0N0:)3S .., 0 • ... ----.. ------. SELDON CLARK PROPERTY SOIL, SURFACE WATER AND SEDIMENT SAMPLING LOCATIONS 1---------------------------1 FIGURE 3.2 I ~EPA GENERAL ELECTRIC SUPERFUND SITE EAST FLAT ROCK, NORTH CAROLINA o.__ _________________________ ...J... ____ __J I I I I I I I I I g n I I I I I I I I j ! // I i / ! i i I ' i I / // ' / i i ; ; j ./ ! \ \ SHEPHERD FARM PROPERTY SOIL SAMPLING LOCATIONS ' \ -, \ _______ , _____ _ u, z 0 ~ " z :J a. ~: ~I • 1---------------------------1 FIGURE 3.3 !~EPA GENERAL ELECTRIC SUPERFUND SITE EAST FLAT ROCK, NORTH CAROLINA OL...----------------------------L------.1 I I I I I I I • I I u D D I I I GE/Shepherd Farm NPL Site Remedial Investigation Repo11 Draft/ May, 1995 The four additional sampling locations were located approximately 45 feet from the center of the area at angles of 45°, 135°, 225° and 315° from north. A grab subsurface soil sample was collected from the center of each area at a depth of three feet to four feet BLS. Also, grab subsurface soil samples were collected from locations 57 and 59 at a depth of six feet to eight feet BLS. 3.4 Surface Water and Sediment Sampling Thirteen surface water and sediment samples were collected from 12 locations during this investigation including five samples from the GE property, one from the Seldon Clark property and five from the Shepherd Fann property. The locations are indicated on Figures 3.4 and 3.5. The sediment samples were collected from the bottom of the creek using a zero to three inch interval below the water-sediment interface. The water samples were collected several inches below the air-water interface. In addition, one spring water sample and an associated soil/sediment sample was collected from the GE propetty. The spring is located on the east edge of landspreading area D. The spring discharges to Bat Fork creek. 3.5 Temporary :Monitor Well Installation and Sampling Nine temporary wells were installed at the locations specified on Figures 3.6, 3.7 and 3.8. Eight of the wells were installed using conventional hollow stem auguring techniques. One well was installed using direct push techniques. The direct push technique was attempted at each location initially since this method is less disrnptive and produces no drill cuttings. The wells installed using the hollow stem auguring were constrncted of 2 inch stainless steel casing and screen. The screens have a 0.01 inch slot size. The wells were installed to a depth approximately five to ten feet below the water table. Well constrnction details are presented in Section 4. All drill cuttings, development water and purge water generated while installing and sampling · the wells was discharged to the ground. The abandoned hollow stem auger boreholes were back filled with the drill cutting to approximately five feet BLS. Several feet of bentonite grout or pellets were placed in the borehole and hydrated with tap or deionized water. The top one foot was backfilled with native material. The wells were purged and sampled in ·such a iriariner ·i"is ·to ininimize turbidity.· The· field parameters of temperature, pH, specific conductance and turbidity were measured. 3-8 -- - -3s~cr a~ m (/) C ;i :;(I ...,., ]> n l"TJ l"TJ Q :c ]> ]> l"TJ -I (/) z l"TJ -I l"TJ :;(I :;(I ...,., ]> ]> rr z ]> l"TJ t:! -Ir (/)Q :;(I l"TJ l"TJ l"TJ on t:! --0 n-1 7' :;ci ::,:: :;(I ->--< ,__. D n ::,:: --0 z (/) l"TJ l"TJ z :;(I De -I -1 :;(I --0 (/)-< -I l"TJ :r: :;(I ]> n...,., ::,:: --0 J>c r :;(I z >--< D t:! z r Vl Q >--< z >--< r ]>"-I D T'l n ]> -I >--< D z (/) ....__ ...,., >--< Q C Al l"TJ w -1'--l!l!!I l!!!l!!I DRAIN LIN£ -== == llliil -lilll iiiii "•,,,, ,, " " y // -....,~,~~ I I ~~~~"-'\.:,.:_,,:,.:.::::,_~'\.~ ' // ,:s_"',:',._\,\\~\"-\\\\'Z"--'-"-~~~\\\ '· ' SPRING -,,;,, ~\\'\cf,\\\\\*\\\\~~~~\\\\%lt~ .. ,, K" ,,-",,,,,, ,,,.,., ,,,, .. ,,_,,,,\\;,,:; (S,,, '\~':.\\s.\;;\\s\\: ,,\\\\,\;;\\\~\; ~ ,,_~---'''"-"'"-\~'"'"'"'""'""''"'""''~s,-~., ...__ .....,11~, ,-,._ ~ ',, ', '''-',, '.,,,."''-"'"''\,,> ''"'-..___ ~""k @:'/ii«',,-,,,~ ">loc\\>"""'"'"~\\¾,,' , , ~ 0 f~\\\%12_ \\\~-~~-;;~,~~~~,, ~\~ii~g',;;l\~~\\\'(~\~1:c", r, '""'"-''''""-'-'~1>\,\_,,,."...,___ ',', ~--~'--"'"'-,\, -~~·'-,\.\¢\\,.,~f''''•'-"'','·""'-~', r-"-~;.__~..:__-''"'''·"\\~'.:~>-',, ,~\\\--\\\) ~ ~\\1 • ~:...~'i-.~'S:::t~A,>_:,__\\~11 S\.UOGUNE~ \ \\t:,\"'-.\~j -~~->\, IMPO '°'''•'"'-'-' -,,_ "'-"'"'-"-" □ ----~\\\~"i_ci t':~~-;;;__~, ~~--... ,, \--,~\\~-~~~'y MAIN PLANT \/'AREHOUSE -~~ ,, ---SCALE IN FEET l.EWil! --~ ... .6, SURF°,ACE \/ATER/SEDIMENT SAMPLING LOCATION @LANDSPREADING PLOTS RECREATION fAC!LITY ' -, 7 'f I "I ~~,,_,. /"''"''<I'"'' I I ~ L_J \ \ ,-.,,------/ I ·~~ill~~~\'(, ~ -,_ SPARTANBURG HVY. . :... _ __...------·k 1.1 ~~-....:.. -"= ------ I I I I I I I I I • • I I I I I n a fil ~-0 ii: i a ' 1--z uJ " 1Sui ~~5 ,-"' !;, uJ (.) !;, 0 3' _, uJ "' (.);; ~it ~~ • p (j ff "" "" / / i / i f / I , / i i i / i i / i i i i / i / / / / i ; ! ! [) 0•0~ dYD 3Nll'I ~\ 0 '\_ \ \ ''-··-··-··-··-··-·· SHEPHERD FARM PROPERTY SURFACE WATER SEDIMENT SAMPLING LOCATIONS 0 "' 0 ·--·-··-·-··-~-·-··--- n0~0J::~:::·:E::::A:'-_A·:::::GE:N:E:RA:L::E:LE:C:TR:l:C:S:U:P:E:RF:U:N:D:S:l:TE::::::~..__FI-GU_R_E_ 3 ·- 5 ~ -~ _ '/JE\. EAST FLAT ROCK, NORTH CAROLINA I I I I I I I I I I I I I I I I I I I e, ---i 0 ._, ru "' I , &EPA GE PROPERTY TEMPORARY MONITOR WELL LOCATIONS GENERAL ELECTRIC EAST FLAT ROCK, SUPERFUND SITE NORTH CAROLINA I / FIGURE 3.6 r,._ ______________________________________ .._ ______ __, I I I I I I I I I I I I I I •--- I (/) z 0 ;:;: u 0 _J _J _J f-w z 3' s 0: 0 >= Q_ z 0 ,. w Ii: (.'.) ~ 0 0. cl ,_ • Op,O ()' (Y, • 00p, 0 n -.,: 0 I ct: w t- --i:r~Tt ..w w 0:: t-(/) 0 (/) 0 w z 0 --, 2 ~ i ct: <{ ~ Ow ;;:: LL ct: I o<t: ~ -I I-W_i Cl ~_J 0:: ~ 2LL :::, (D t;; w ... /0 '= w _J <( (.) ./' V) z f-z I < (f) ~ 0:: w 0:: 0 <( (L ::; (/) ~ I 0:: 0 <O t-" (/) (/) 0 :::, 0 I 3nN3/iv' ONO::l3S ;;; 0 • .. ---------·--·-----.---. --. -------... SELDON CLARK PROPERTY TEMPORARY MONITOR WELL LOCATIONS 1---------------------------1 FIGURE 3.7 I I I GENERAL ELECTRIC SUPERFUND SITE EAST FLAT ROCK, NORTH CAROLINA ! &EPA n.__ __________________________ ----1. ____ __J I I I I I I I I I I I I I I I I I I I f " 0 >= ~ ~6~ ::,;o -4-0• I~ a a.-' ::,; -' a wW ' >-l< • f ' J / / i / / / ,/ / / , I / / I ' i ! ./ i I I \ \ ·\. ~· \ \ CJ C ) \ \ ·, \ \, '-*-••-··-·-··-- SHEPHERD FARM PROPERTY TEMPORARY MONITOR WELL LOCATIONS 1-------------------------1 FIGURE 3.8 !~EPA GENERAL ELECTRIC SUPERFUND SITE EAST FLAT ROCK, NORTH CAROLINA .., .__ ____________________________ .__ ____ __. I I I I I I I I I I I I I I I I I 3.6 Monitor Well Sampling GE/Shepherd Farm NPL Site Remedial Investigation Repo1t Draft / May, 1995 Twenty four of the existing pennanent monitor wells located on the GE property were sampled. Section 4, Table 4.10 presents the well constmction infonnation and Figure 3.9 indicates their locations. The wells were sampled in such a manner as to minimize turbidity to a minimum. All purge water was discharged to the ground. 3.7 Potable Well Sampling Eleven potable well samples were collected during this investigation. Section 4, Table 4.14 presents the owner's name and address, and Figure 3.10 indicates the well locations. 3.8 Analytical Procedures All of the samples were analyzed for volatile and extractable organic compounds, pesticides, PCB's and metals. All analyses were conducted according to the United States Environmental Protection Agency, Region IV, Environmental Services Division, Laboratory Operations and Quality Control Manual, September, 1990 (4), or the CLP Statement of Work (SOW). This SOW describes chain of custody, calibration procedures, routine QC checks, and data validation and reporting; it also describes the laboratory's routine procedures for assessing precision and accuracy. The soil samples ,:ollected for analysis were booked into the Contract L1boratory Program (CLP) laboratu1ie·s· through· W. R. Bo key, the sample control manager. 3.9 Field Instrumentation The following instnnnents were used during the remedial investigation at the GE Site: I. pH meter 2. thennometer 3. specific conductivity meter 4. photoionization detector 5. radiation survey meter 6. organic vapor analyzer 7. water level indicator 8. turbidity meter 3-14 I I I I I I I I I I I I I I I I I I I CJ i -400 0 400 SCALE IN FEET GE PROPERTY ON SITE MONITOR WELL LOCATIONS ~~EPA GENERAL ELECTRIC SUPERFUND SITE EAST FLAT ROCK, NORTH CAROLINA ~ FIGURE 3.9 ~L...-----------------------------------------"-----------1 I I I I I I I I I I I I I I I I I ,-: (/) e .,, N f--__ 0"' ~ ~ e-§ "" POTABLE WELL LOCATIONS .,,& .,, i1! 0 ~ Ii! .. ~ 1--------------------------1 FIGURE 3. 1 0 1 ~ ~EPA GENERAL ELECTRIC SUPERFUND SITE EAST FLAT ROCK, NORTH CAROLINA O> I L----------------..,L__ _ _.. I I I I I I I I I I I I I I I I I I I GE/Shepherd Farm NPL Site Remedial Investigation Report Draft / May, 1995 All calibration procedures utilized for these instnnnents were pe1fonned in accordance with Appendix D of the ECBSOPQAM (?) or the manufacturer's specifications. All calibrations were recorded in the field log books. 3.10 Sample Containers Sample containers used were in accordance with the requirements specified in Appendix A of the ECBSOPQAM(?). Table 3.1 is extracted from the manual and provides a description of the analysis, preservatives, and types of containers that were used during this sampling investigation. 3.11 Field Sampling Equipment Cleaning Procedures All samples were collected with sampling equipment specified and cleaned in accordance with Appendix B of the ECBSOPQAM (?). Any deviations from this were justified and recorded in the field log book. 3-17 I I I I I I I I I I I I I Table 3.1 GE/Shepherd Fann NPL Site Remedial Investigation Report Draft / May, 1995 Sample Container and Preservative Requirements Analyses Purgeable Organics Extractable Organic Pesticides, PCB's Metals Analyses Purgeable Organic Extractable Organic Pesticides, PCB' s Metals Soil/Sediment Analysis Container Preservative I - 2 oz. glass iced, 4°C I - 8 oz. glass iced, 4°C I - 8 oz. glass iced, 4 °C Water Analysis Container Preservative 3 -40 ml. glass HCI, iced, 4 ° C I - 1 gallon glass iced, 4°C I - I liter plastic HNO3, iced, 4°C · (All containers used for organic samples have Teflon lined caps, and all containers for I purgeable organic sample have septum lids.) I I I I I 3-18 I I I I I I I I I I I I I I I I I I I 4.0 RESULTS AND DISCUSSION GE Superfund Site RI Report Draft May 1995 During the Remedial Investigation, surface and subsurface soil, sedin,ent and surface water samples were collected, temporary monitor wells were installed and sampled and pennanent monitor and potable wells were sampled as specified in Section 3. The analytical results for the individual samples are provided in the Data Summary Tables in the following subsections. The laboratory data sheets, which indicate all of the compounds for which each sample was analyzed and their respective detection limits are provided in Appendix A. In this report certain abbreviations are used when discussing the analytical results. The abbreviations and their meanings are as follows: ug/1 -microgram per liter mg/I -milligram per liter ug/kg -microgram per kilogram mg/kg -milligram per kilogram MCL -Safe Drinking Water Act, Maximum Contaminant Level NA -Not Analyzed J -Estimated Value N -Presumptive Evidence of Presence of Material -Material Was Analyzed for but Not Detected U -Material Was Analyzed for but Not Detected. The Number Is the Minimum Quantitation Limit PCB's -Polychlorinated biphenyls C -Confinned by GC/MS Sample identification methodology was discussed in Section 3.2. When discussing the · analytical results in this report, the "GE" and any preceding O's will be eliminated. For example, sample GE-001-SLA will be referred to as sample 1-SLA. In general surface soil samples were collected from zero to six inches BLS. The subsurface samples were collected from three feet to four feet BLS, designated "SLB" and six to eight feet BLS designated _"SLC". 4.1 Soil..Sampling Thirty four surface soil samples and 41 subsurface soil samples were collected during this inve~tigation. In general, the surface soil sampling interval was Oto 6 inches BLS and the subsurface soil sampling intervals were three feet to four feet BLS and six to eight feet ELS. 4-1 --382LOlU ij[?) m :a ~ rrl ~ J> z (/) rrl -i ;;o "T"j J> ,' J> rrl -i, ;;o rrl □Cl n ;;o ?' >-< n z (/.) DC ;;o -0 -i rrl :r: ;;o n -ri J>c ;;o z D t::J ' V! >-< z >-< ]> -i rrl "T"j >-< Q C ;;o rrl ~ ,_. --Q rrl ""CJ ;;o D ""CJ rrl ;;o -i -< V! D >-< ' (/.) J> ::;:: ""CJ ' >-< z Q ' D n J> -i >-< D z (/.) - - -- - - - --------SL-Ol9 " ,(~ ,'/ ;;;...,~,:-::--,~t-\~., ---i:; // ~"-"~'-'''''""'-'"'"~~'' ,,/ (~},\\~\\\\\t\~,\~~it~ ,, %],,,,,,,_,,~' -''·''C,~J:1,,,,_,,,,,,,,,, (S;,~,, ''~(\::\~t,~<\\t~~\~\\\~\\\\~; ~ "' --~~~--"\\,\\\'>\f.St\l's't\\\\\\i'\ ~.,,, ~~ -\ii,:,\~~\~," . --~~~~--~,t~\~\'i.\\S~-t-,'i:\\\t\-"',,,:-, , ~ ~~tt~~\\t\\i. i?:fu-, --~:-,, ''§:\,>_~~\'t,~\\\\f\~\.',\~~~'\._ -. ! ,, .,,,,,,,,, ,~,,-,,_.,' '''''\~',', ~~'"'·'""'''\\~ \~itli~.i.i.t}.t.\r.}t.~~.~)~ ~,\~\1{i\;: '· ",'," ,,,,,,,,,,,,~.,,,,,":.:·-,".:J'.1 ,, -,,,-_'i-,?/i •1.-~'~'-~":..,,,l ·.','\..,_:'\~-' ... . ,,<,'>~\,,,..,;,i, . ' '" ~,,,,, ~~""'''.""' ',,,,. r--y SPRING ~ DRAIN LINE MAIN PLANT LJ .. WMEHOUSE -~ ,~, -SCALE IN FEET LW2m ~ -A.SOIL SAMPLING LOCATIONS t~LANDSPREADING PLOTS ~ fDRHER LANDFILL ·-.,-:,~:?: ,, :8 . ' ',; ,. -0~".:.: ... \ ~~~; :--..'>,'.;~ ~\ : ..... ..:,, ~\"':,.:"' -~ ~\;:-.'\,.,_::,,,". RECREATION f"oliCtLITY ' ·,_ ' ·,_ ~ SPARTANB=-::-:::-LRG HVY.-1 0--, Ir '\t" "'--. . -. . -'"' . )':_,~-· -~ I I I I I I I I I I I I I I I I I I 4.1.1 GE Property GE Superfund Site RJ Report Draft May 1995 Twenty surface soil samples and 21 subsurface soil samples were collected from the landspreading areas, along the drain line and former ditch, along the railroad track and from the present and two fonner landfills. Also, one replicate and two colocated samples were collected. Landspreading Areas Twenty four samples were collected from l l locations in landspreading areas A, B, C and D. The locations are indicated on Figure 4.1. Analytical results are presented in Table 4.1. Sample 401-SLA is a replicate of sample 1-SLA and sample 501-SI.A was co located to sample l-SLA. Yolatile_Organic_Compounds A single volatile organic compound was detected in the landspreading areas. The presumptive evidence of acetone was detected in samples 4-SLA, 4-SLB and 11-SLB at concentrations of either 17N ug/kg or l 8N ug/kg. Extractable_Organic_Cornpounds With the exception of sample 3-SLA, few identified extractable organic compounds were detected in the landspreading area samples. Sample 3-SLA contained 16 extractable organic compounds which ranged in concentration from 601 ug/kg of dibenzo(A,H)anthracene to l 000 ug/kg of pentachlorophenol. Fluoranthene was detected in samples 3-SLA, 5-SLA and 6-SLA at concentrations ranging between 78J ug/kg and 660 ug/kg. Pyrene was detected in samples · 3-SLA and 5-SLA at concentrations of 640 ug/kg and 11 OJ ug/kg, respectively. The presumptive evidence of dioctadecylester phosphonic acid, hexadecenoic acid and penadecylphenol was detected in several samples. All of the surface soil samples except 9- SLA and 11-SLA contained unidentified compounds. I'.esticides_and_P.CB~s PCB' s were detected in one sample. Sample 11-SLA, the surface soil sample from landspreading area D, contained 60 ug/kg of PCB-1260. Pesticides were detected in all of the surf<Jce soil samples collected from the land spreading areas, except sample 11-SLA. 4-2 -- -- - - - -- ---.. ------Table 4.1 Soil Analytical Data SurTITiary General Electric, East Flat Rock, North Carolina 1-SLA 401-SLA 501-SLA 1-SLB 2-SLA 2-SLB 3-SLA 3-SLB 4-SLA 4-SLB 5-SLA 5-SLB 09/13/94 09/13/94 09/13/94 09/13/94 09/13/94 09/13/94 09/13/94 09/13/94 09/16/94 09/16/94 09/16/94 09/16/94 INORGANIC ELEMENTS MG/KG MG/KG MG/KG MG/KG MG/KG MG/KG MG/KG MG/KG MG/KG MG/KG MG/KG MG/KG BARIUM 23 25 24 13 36 48 52 73 40 21 50 130 COBALT 6.7 8.5 8.3 13 12 CHROMIUM 17 22 15 36 63 30 60 5.8 16 27 11 COPPER 11 J 13J 12J 15J 29J 24J 48J 36J 16J 25J 21J 35J MOLYBDENUM 4.6 NICKEL 12 14 16 23 55 16 31 LEAD 17 22 24 17 32 66 53 39 26 30 36 32 STRONT !UM 3.4 6.5 TITANIUM 260 270 260 470 730 1100 710 670 370 890 290 830 VANAD !UM 31 33 30 58 92 67 70 22 41 110 32 24 YTTRIUM 7.9 4.7 9.0 ZINC 20 24 25 8. 1 40 40 43 32 30 14 40 64 MERCURY D.06 D.11 0.060 0.070 ALUMINUM 32000 32000 29000 56000 44000 68000 34000 39000 41000 93000 34000 49000 MANGANESE 64 74 71 50 180 280 390 330 150 110 190 280 CALCIUM 990 1200 1300 1400 5200 510 1200 1500 MAGNESIUM 420 450 440 280 810 2000 1900 2400 640 600 740 3100 IRON 14000 15000 13000 27000 32000 33000 29000 23000 17000 43000 14000 20000 POTASSIUM 1800 2100 2000 2700 **************************************************************** ***FOOTNOTES*** -MATERIAL WAS ANALYZED FOR BUT NOT DETECTED 4-4 liiiiii iiiii iiii - - - - - ----Table 4.1 (cont) Soil Analytical Data Sunmary General Electric, East Flat Rock, North Carolina 09/16/94 PURGEABLE ORGANIC COMPOUNDS ACETONE EXTRACTABLE ORGANIC COMPOUNDS NAPHTHALENE ACENAPHTHENE FLUORENE PHENANTHRENE AN THRACE NE FLUORANTHENE PYRENE BENZO(A)ANTHRACENE CHRYSENE BENZO(B AND/OR K)FLUDRANTHENE BENZO-A-PYRENE INDENO (1,2,3-CD) PYRENE DIBENZO(A,H)ANTHRACENE BENZO(GHl)PERYLENE PENTACHLOROPHENOL CARBAZOLE 5 UNIDENTIFIED COMPOUNDS 1 UNIDENTIFIED COMPOUND METHYLPHENANTHRENE BENZOFLUORENE BENZOPYRENE (NOT Al 2 UNIDENTIFIED COMPOUNDS 3 UNIDENTIFIED COMPOUNDS, 1 UNIDENTIFIED COMPOUND l PHOSPHONIC ACID, DIOCTADECYLESTER PESTIClOE/PCB COMPOUNDS DIELDRIN 4,41-DDT (P,P 1·DDT) 4,41 -DDE (P,P'-ODE) ENDRIN ENDOSULFAN I I (BETA) ENDOSULFAN SULFATE TOXAPHENE ENDRIN ALDEHYDE METHOXYCHLOR ENDRIN KETONE 1-SLA 401-SLA D9/13/94 09/13/94 UG/KG UG/KG 3DDDJ UG/KG 68N 43DC 250 84 140 22 UG/KG UG/KG 500J UG/KG 460C 220 **************************************************************** ***FOOTNOTES*** 501-SLA 09/13/94 UG/KG UG/KG 3000J UG/KG 86 450C 220 220 J ESTIMATED VALUE N · PRESUMPTIVE EVIDENCE OF PRESENCE OF MATERIAL · MATERIAL WAS ANALYZED FOR BUT NOT DETECTED C · CONFIRMED BY GC/MS 1-SLB 09/13/94 UG/KG UG/KG UG/KG 7.6 4-5 2-SLA 09/13/94 UG/KG UG/KG 600J UG/KG 50 710C 2·SLB 09/13/94 UG/KG UG/KG UG/KG 26N 3-SLA 09/13/94 UG/KG UG/KG ?SJ 79J 83J 680 150J 660 640 360J 360J 520J 280J 190J 60J 220J 1000 11 OJ 100JN 300JN 300JN lOOOJ UG/KG 43 350C 190 58N - - 3-SLB 4-SLA 09/13/94 09/16/94 UG/KG UG/KG UG/KG 15 7.8 UG/KG 18N UG/KG 3000J UG/KG 25 18 4-SLB 09/16/94 UG/KG 17N UG/KG 400J UG/KG .. 5-SLA 09/16/94 UG/KG UG/KG 140J 11 OJ 2000J UG/KG 13 98 53 460 5-SLB UG/KG UG/KG 200JN UG/KG ---iiiil iiiiil --- - ---- - - lllil -lliiil iiiil Table 4.1 Soil Analytical Data Surrrnary General Electric, East Flat Rock, North Carolina 6-SLA 6-SLB 7-SLA 7-SLB 8-SLA 8-SLB 9-SLA 9·SL8 10-SLA 10-SLB 09/16/94 09/16/94 09/16/94 09/16/94 09/16/94 09/16/94 09/16/94 09/16/94 09/16/94 09/16/94 INORGANIC ELEMENTS MG/KG MG/KG MG/KG MG/KG MG/KG MG/KG MG/KG MG/KG MG/KG MG/KG BARIUM 38 49 19 34 25 34 66 96 60 86 COBALT 5. 1 3.2 5.5 CHROMIUM 18 28 9.3 32 14 50 18 17 15 25 COPPER 25J 22J 12J 13J 12J 15J 28J 39J 23J 27 J MOLYBDENUM 5.9 NICKEL 38 10 28 18 7.8 7.2 LEAD 34 39 20 16 17 21 24 16 24 20 STRONTIUM 5.9 3.0 3.0 3.6 3.6 TITANIUM 280 360 130 430 200 440 450 570 360 650 VANADIUM 28 63 13 60 22 76 32 18 26 43 YTTRIUM 3.3 2. 1 2.2 4.6 4.3 5.2 ZINC 44 26 32 12 27 12 91 25 43 26 MERCURY 0.06 0.08 0.12 0.06 0.23 0.06 ALUMINUM 28000 52000 14000 67000 19000 64000 31000 45000 29000 33000 MANGANESE 140 210 47 58 54 28 160 120 110 270 CALCIUM 3500 770 1600 360 1200 1100 1100 MAGNESIUM 800 770 260 530 380 500 1500 1400 1200 2200 IRON 14000 32000 5900 32000 9400 29000 15000 7300 12000 21000 POTASSIUM 780 1200 1200 980 2600 **************************************************************** ***FOOTNOTES*** ' · MATERIAL WAS ANALYZED FOR BUT NOT DETECTED 4-6 liiill PURGEABLE ORGANIC COMPOUNDS NONE DETECTED liiiil EXTRACTABLE ORGANIC COMPOUNDS· FLUORANTHENE HEXADECENOIC ACID HEXADECENDIC ACID (2 ISOMERS) HEXADECENOIC ACID PENTADECYLPHENOL iiiiil PHOSPHONIC ACID, DIOCTADECYLESTER 1 UNIDENTIFIED COMPOUND 3 UNIDENTIFIED COMPOUNDS 4 UNIDENTIFIED COMPOUNDS 5 UNIDENTIFIED COMPOUNDS PESTlCIOE/PCB COMPOUNDS DIELORIN 4,4'-DDT (P,P 1-0DT) 4,4 1-0DE (P,P'-DDE) TOXAPHENE - - - --.. Table 4.1 (cont) Soil Analytical Data Sunrnary General Electric, East Flat Rock, North Carolina 6-SLA 6-SLB 7-SLA 7-SLB 09/16/94 8-SLA 8-SLB 09/16/94 09/16/94 09/16/94 UG/KG UG/KG ?BJ 300JN 2000J UG/KG 41 200 130 2500C UG/KG UG/KG UG/KG UG/KG UG/KG 300JN 3000J UG/KG 56 230 140 2600C UG/KG UG/KG UG/KG 09/16/94 09/16/94 UG/KG UG/KG 300JN 100JN 2000J UG/KG 9.2 90 45 710 UG/KG UG/KG 400J UG/KG **************************************************************** ***FOOTNOTES*** ESTIMATED VALUE N PRESUMPTIVE EVIDENCE OF PRESENCE OF MATERIAL MATERIAL WAS ANALYZED FOR BUT.NOT DETECTED C CONFIRMED BY GC/MS 4-7 9-SLA 9-SLB 09/16/94 09/16/94 UG/KG UG/KG 400JN UG/KG 22 27 27 UG/KG UG/KG UG/KG 10-SLA 09/16/94 UG/KG UG/KG 900JN 2000J UG/KG 35 220 45 330 lllil 10-SLB 09/16/94 UG/KG UG/KG UG/KG 14 19 9.5 iiiil iiiil ----liiii - - - - -----lliiiill --iiiil iiiil Table 4.1 (cont) Soil Analytical Data Surrmary General Electric, East Flat Rock, North Carolina ll·SLA 11-SLB 12-SLA 512-SLA 12-SLB 13-SLA 13-SLB 13-SLC 14-SLA 14-SLB 09/16/94 09/16/94 09/16/94 09/22/94 09/16/94 09/20/94 09/20/94 09/20/94 09/20/94 09/20/94 INORGANIC ELEMENTS MG/KG MG/KG MG/KG MG/KG MG/KG MG/KG MG/KG MG/KG MG/KG MG/KG BARIUM 64 19 72 64 75 36 1.8 18 71 89 COBALT 8.5 13 12 8.2 12 9.8 CHROMIUM 41 9.9 72 46 32 120 4. 1 30 48 36 COPPER 35J 4.6J lOOJ 70 18J 1100 19 97 25 20 MOLYBDENUM 5.9 NICKEL 28 25 15 11 71 13 14 LEAD 33 7.7 45 26 26 130 15 61 29 27 TIN 41 18 STRONTIUM 7.6 4. 1 4.9 15 TJTANIUM 840 160 940 990 610 430 12 510 700 1000 VANADIUM 67 16 76 65 42 31 40 56 50 YTTRIUM 3.9 2. 1 7.2 7.3 5.2 6.8 8.4 ZINC 41 8.4 120 120 27 1200 19 68 28 31 MERCURY 0.06 0.06 0.05 0.08 0.06 0.06 ALUMINUM 31000 14000 52000 32000 41000 120000 560 62000 59000 69000 MANGANESE 500 30 580 860 220 330 7.6 80 240 260 CALCIUM 880 140 3400 2900 900 2000 MAGNESIUM 3100 360 9700 3700 2100 2400 70 510 2000 2900 IRON 30000 6700 36000 32000 19000 18000 1300 28000 25000 26000 POTASSIUM 3200 3200 3700 1800 1700 2700 **************************************************************** ***FOOTNOTES*** -MATERIAL WAS ANALYZED FOR BUT NOT DETECTED 4-8 liiiil liiiiil --- -------liill -.. -iiiil liiil lilliil Table 4. 1 (cont) Soil Analytical Data Surrmary General Electric, East Flat Rock, North Carolina 11-SLA 11-SLB 12-SLA 512-SLA 12-SLB 13-SLA 13-SLB 13-SLC 14-SLA 14-SLB 09/16/94 09/16/94 09/16/94 09/22/94 09/16/94 09/20/94 09/20/94 09/20/94 09/20/94 09/20/94 PURGEABLE ORGANIC COMPOUNDS UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG ACETONE 17N 23N 1,2-DICHLOROETHENE (TOTAL) 27 TETRACHLOROETHENE(TETRACHLOROETHYLENE) 16000 CHLOROBENZENE 21 ETHYL BENZENE 1600J TOTAL XYLENES 4400 EXTRACTABLE ORGANIC COMPOUNDS UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG 2-METHYLNAPHTHALENE 80J 290J 1,2,4-TRICHLOROBENZENE 2800J ACENAPHTHENE 11 OJ D!BENZOFURAN 92J FLUORENE 90J PHENANTHRENE 91J 150J 210J ANTHRACENE 330J FLUORANTHENE 650 150J 120J 230J 190J PYRENE 340J 130J 95J 160J 130J BENZO(A)ANTHRACENE 200J 110J CHRYSENE 250J 95J 150J BENZO(B AND/OR K)FLUORANTHENE 350J 170J 310J BENZO-A-PYRENE 160J ?OJ 130J INOENO (1,2,3-CO) PYRENE 95J BENZO(GHl)PERYLENE 94J OICHLOROBIPHENYL (3 ISOMERS) 3000JN TRICHLOROB!PHENYL (4 ISOMERS) 6000JN TETRACHLOROBIPHENYL (4 ISOMERS) 4000JN PENTACHLOROBIPHENYL (3 ISOMERS) 3000JN TRICHLOROBIPHENYL (6 ISOMERS) 8000JN TETRACHLOROBIPHENYL (10 ISOMERS) 8000JN PENTACHLOROBIPHENYL (3 ISOMERS) 2000JN 6 UNIDENTIFIED COMPOUNDS 8000J 100000J HEXACHLOROBIPHENYL (5 ISO°MERS) 20000JN HEPTACHLOROBIPHENYL (4 ISOMERS) ' 20000JN OCTACHLOROBIPHENYL ' 4000JN PENTACHLOROBIPHENYL (2 ISOMERS) 30000JN HEXACHLOROBIPHENYL (5 I SOMERS) 40000JN HEPTACHLOROBIPHENYL (9 I SOMERS) 90000JN OCTACHLOROBIPHENYL (3 ISOMERS) 20000JN PENTACHLOROBIPHENYL 7000JN 2000JN 100JN HEXACHLOROBIPHENYL (3 ISOMERS) 300JN HEPTACHLOROBIPHENYL 200JN 100JN HEXACHLOROBIPHENYL (2 ISOMERS) ZOOJN **************************************************************** ***FOOTNOTES*** J -ESTIMATED VALUE. N -PRESUMPTIVE EVIDENCE OF PRESENCE OF MATERIAL. -MATERIAL UAS ANALYZED FOR BUT NOT DETECTED. C -CONFIRMED BY GC/MS 4-9 -liiii iiiiii -- - ----.. .. -11111 Table 4.1 (cont) Soil Analytical Data Surrrnary General Electric, East Flat Rock, North Carolina 11-SLA 09/16/94 PEST IC !OE/PCB COMPOUNDS UG/KG 4,4' -DOT (P,P1 -DDT) 4,4 1 -DDE (P,P'-DOE) 4,4 1 -DDD (P,P'-D0D) PCB-1242 (AROCLOR 1242) PCB-1254 {AROCLOR 1254) PCB-1248 (AROCLOR 1248) PCB-1260 (AROCLOR 1260) 60 **************************************************************** ***FOOTNOTES*** J -ESTIMATED VALUE. N -PRESUMPTIVE EVIDENCE OF PRESENCE OF MATERIAL. -MATERIAL WAS ANALYZED FOR BUT NOT DETECTED. C -CONFIRMED BY GC/MS 11-SLB 09/16/94 UG/KG 3_2J 3_6J 4_5 12-SLA 512-SLA 12-SLB 13-SLA 13-SLB 09/1_6/94 09/22/94 09/16/94 09/20/94 09/20/94 UG/KG UG/KG UG/KG UG/KG UG/KG 22000C 3500c 1200c 110 9300C 18000C 9700C 220 1300C 820C 68 26000C 62000C 4-10 11111 ---iiiil 13-SLC 14-SLA 14-SLB 09/20/94 09/20/94 09/20/94 UG/KG UG/KG UG/KG 36000C 240 160 150 96 120000C 540 370 iiilii ---- - ------- ----.. liill iilil Table4.1 Soil Analytical Data Surrrnary General Electric, East Flat Rock, North Carolina 15-SLA 15-SLB 16-SLB 17-SLB 18-SLA 18-SLB 19-SLA 20-SLD 22-SLD 09/20/94 09/20/94 09/19/94 09/19/94 1D/19/94 09/16/94 09/16/94 09/20/94 09/21/94 INORGANIC ELEMENTS MG/KG MG/KG MG/KG MG/KG MG/KG MG/KG MG/KG MG/KG MG/KG BARIUM 70 54 110 58 82 90 46 130 200 COBALT 9.9 24 13 20 8.5 6.0 11 CHROMIUM 44 74 27 170 39 49 53 12 COPPER 23 19 140 39 50J 58J 27J 21 35 NICKEL 18 24 24 12 20 9.4 10 LEAD 24 22 15 24 29 33 18 52 11 STRONTIUM 29 7.3 6.6 TITANIUM 870 520 1300 1100 1200 1200 820 69 1300 VANADIUM 64 100 54 99 78 61 68 56 YTTR !UM 7.2 11 7. 1 8.9 13 3.8 8.7 ZINC 32 24 55 47 63 120 29 10 39 MERCURY 0.06 0.09 0.06 ALUMINUM 56000 60000 77000 44000 42000 32000 33000 42000 54000 MANGANESE 320 65 180 770 540 820 340 300 370 CALCIUM 400 1200 1000 2000 2200 530 MAGNES !UM 2300 1700 4900 4500 5700 4400 2200 490 5400 IRON 29000 32000 23000 39000 32000 30000 30000 2000 29000 POTASSIUM 2000 3800 3800 4800 4600 2500 5200 **************************************************************** ***FOOTNOTES*** -MATERIAL WAS ANALYZED FOR BUT, NOT DETECTED 4-1 1 liliil iiii liiili PURGEABLE ORGANIC COMPOUNDS ACETONE - EXTRACTABLE ORGANIC CDMPOUN□S-, NAPHTHALENE ACENAPHTHENE DIBENZOFURAN FLUORENE PHENANTHRENE ANTHRACENE FLUORANTHENE PYRENE BENZO(A)ANTHRACENE CHRYSENE BENZO(B AND/OR K)FLUDRANTHENE BENZO-A-PYRENE INDENO (1,2,3·CD) PYRENE, DIBENZO(A,H)ANTHRACENE BENZO(GHl)PERYLENE CARBAZOLE DECAHYDROMETHYLNAPHTHALENE OCTAHYDROHEXAMETHYLINDENE METHYLPHENANTHRENE CYCLOPENTAPHENANTHRENE ANTHRACENED I ONE BENZOFLUORENE (2 ISOMERS) BENZONAPHTHOTH!OPHENE BENZOPYRENE (NOT A) HEXADECENOlC ACID PENTACHLOROBIPHENYL 1 UNIDENTIFIED COMPOUND ' 2 UNIDENTIFIED COMPOUNDS' "UNIDENTIFIED COMPOUNDS. 6 UNIDENTIFIED COMPOUNDS PESTICIDE/PCB COMPOUNDS - - ----- --Table4.1 Soil Analytical Data Surrrnary General Electric, East Flat Rock, North Carolina 15·SLA 15-SLB 16·SLB 09/20/94 09/20/94 09/19/94 UG/KG UG/KG 91J 800J UG/KG UG/KG 5ZN UG/KG UG/KG UG/KG UG/KG 19DOJ 21DOJ 1000DJ 3200J 16000 12000 6100J 5600J 7600J 3400J 1500J 4000JN 6000JN 90000J UG/KG 53 46 17-SLB 09/19/94 UG/KG UG/KG UG/KG 18-SLA 10/19/94 UG/KG UG/KG 180J 130J 90JN 1000J UG/KG 18-SLB 19-SLA 09/16/94 09/16/94 UG/KG UG/KG 110J 400 130J 350J 1300 320J 1600 1400 1000 1100 1700J 780 280J 130J 240J 430 200JN 300JN 200JN 900JN 400JN 600JN 5000J UG/KG UG/KG UG/KG UG/KG 6.0 25 21 DIELDRIN 4,4'-DDT 4,4'-DDE PCB·1254 PCB-1248 PCB-1260 (P,P'-DDT) (P,P 1-DDE) (AROCLOR 1254) (AROCLOR 1248) (ARDCLOR 1260) ' **************************************************************** 64 58 220 160 450 70 76 ***FOOTNOTES*** J ESTIMATED VALUE N PRESUMPTIVE EVIDENCE OF PRESnJCE OF MATERIAL MATERIAL \./AS ANALYZED FOR BUT .NOT DETECTED 4-12 - - 20-SLO 22-SLD 09/20/94 09/21/94 UG/KG UG/KG 1000JN 1000J UG/KG UG/KG UG/KG UG/KG liiil liiil liiil I I I I I I I I I I I I I I I I I I • GE Superfuncl Site RI Report Draft May 1995 Dieldrin was detected in 12 of the surface soil samples and ranged in concentration from 9.2 ug/kg in sample 8-SLA to 86 ug/kg in sample 501-SLA. 4,4'-DDT was detected in all of the surface soil samples except 11-SLA. The concentrations ranged between 25 ug/kg in sample 4-SLA and 710C ug/kg in sample 2-SLA. 4,4'-DDE was detected in 11 surface soil samples at concentrations ranging from 18 ug/kg in sample 4-SLA to 250 ug/kg in sample 1-SLA. Toxaphene was detected in five surface soil sample at concentrations between 330 ug/kg in samplel0-SLA and 2600C ug/kg in sample 7-SLA. Four of the samples in which toxaphene was detected are located in landspreading area B. Sample 1-SLA also contained 140 ug/kg of endosulfan II and 22 ug/kg of endrin ketone. Sample 501-SLA contained 220 ug/kg of endosulfan ketone. Sample 11-SLB contained 4.5 ug/kg of 4,4'-DDD. The presumptive of endrin aldehyde and methoxychlor was detected in samples 3-SLA and 2-SLB, respectively. Dieldrin was detected in one subsurface soil sample. Sample 10-SLB contained 14 ug/kg of dieldrin. 4-4'-DDT was detected in four subsurface soil samples at C,)11centrations up to 19 ug/kg in sample 10-SLB. 4,4'-DDE was detected in sample 10 SLB at a concentration of 9.5 ug/kg. Metals A variety of metals was detected in the soil samples including: barium, chromium, copper, lead, zinc, mercury and manganese. Barium was detected in every sample. The concentrations ranged between I. 8 mg/kg in sample 13-SLB and 13 mg/kg in sample 1-SLB. Chromium was detected in every sample except 5-SLB. The concentrations in these remaining samples ranged from 9. 3 mg/kg in sample 7-SLA to 63 mg/kg in sample 2-SLA. Lead was detected in all the samples. The · concentrations ranged up to 66 mg/kg in sample 2-SLB. Manganese was detected in sample at an elevated concentration in sample 11-SLA. Mercury was detected in five samples including 4-SLA, 4-SLB, 5-SLA, 5-SLB and 11-SLA. _ The_ concentrations ranged from 0.06 mg/kg to 0.11 mg/kg. _ _ _____ . Landfills Three landfills, designated A, B and C, exist on site. Eight samples were collected from six locayons in the three landfills. The locations are indicated on Figure 4.1. Analytical results arc presented in Table 4.1. Sample 512-SLA is colocated to sample 12-SLA. 4-13 I I I I I I I I I I I I I I I I I I I GE Superli.111d Site RI Report Draft May 1995 One grab surface soil and 2 grab subsurface soil samples were collected from landfill A. One composite surface and one grab subsurface soil sample were collected from landfill B and from landfill C. j[olati le_O.rgan ic_Compounds Samples 13-SLA and 13-SLC collected from landfill A contained volatile organic compounds. Sample 13-SLA contained 27 ug/kg of 1,2-dichloroethene, 21 ug/kg of chlorobenzene and 23N ug/kg of acetone. Sample 13-SLC contained 16,000 ug/kg of tetrachloroethene, l ,600J ug/kg of ethyl benzene and 4,400 ug/kg of xylenes. Landfill B and C contained no detectable volatile organic compounds. Extractable_Organic__Compounds Extractable organic compounds were detected in all of the samples collected in the landfills. Samples 13-SLA, 13-SLB and 13-SLC from landfill A contained several unidentified compounds and the presumptive evidence of several compounds. Sample 13-SLC also contained 2, 800J. ug/kg of 1,2 ,4-trichlorobenzene. Samples 12-SLA, landfill B, contained anthracene, fluoranthene, pyrene, benzo(A)anthracene, chrysene, benzo(B and/or K)fluoranthene and benzo-A-pyrene at concentrations up to 650 . ug/kg. The presumptive evidence of several compounds was detected as were several unidentified compounds. Sample 512-SLA contained fluoranthene, pyrene, chrysene, benzo(B and/or K)fluoranthene and benzo-A-pyrene at concentrations up to 170 ug/kg. The presumptive evidence of several compounds was also detected. Sample 12-SLB contained phenanthrene, fluoranthene and pyrene at concentrations up to 120 ug/kg. · Sample 18-SLA, landfill C, contained 180J ug/kg of fluoranthene, 130J ug/kg of pyrene, 90JN of pentachlorobiphenyl and two unidentified compounds. Sample 18-SLB contained naphthalene, acenaphthene, dibenzofuran, fluorene,phenanthrene, fluoranthene, pyrene, benzo(A)anthracene, chrysene, benzo(B and/or K)fluoranthene, benzo-A-pyrene, indeno(l ,2,3-CD) pyrene, dibenzo(A,H)anthracene, ben2:o(GHI)peryle!Jeand carbaz,ole at concentrations up to I, 700J ug/kg. The presumptive evidence of several compounds was detected as were several unidentified compounds. I'.esticide.s_and.J'.CB.'..s Pesticides were not detected in any of the landfill samples. PCB's were detected in all the 4-14 I I I I I I I I I I I I I I I GE Superfund Site RI Report Draft May 1995 landfill samples. PCB-I 242 was detected in sample 12-SLA, landfill B, at a concentration of 22,000C ug/kg. PCB-I 254 was detected in all the samples at concentrations up to 36,000C ug/kg. PCB-1248 was detected in samples 512-SLA and 12-SLB, landfill A, and 18-SLA, landfill C, at concentrations up to 9,700C ug/kg. PCB-1260 was detected in all the samples at concentrations up to 120,000C ug/kg in sample 13-SLC. Metals A variety of metals was detected in the soil samples including: barium, chromium, copper, lead, zinc, mercury and manganese. Sample 21-SLA and 512-SLA contained elevated concentrations of manganese. Sample 13-SLA contained elevated concentrations of chromium, copper, lead and zinc. Drain Line/l<ormer Ditch Four soil samples were collected from two locations beneath the drain line/fonner ditch . Location 14 was off the east corner of the main plant and location 15 was due west of the OV Stores building. The locations are indicated on Figure 4.1. Analytical results are presented in Table 4.1. y_olatile_Organic._Comµounds The presumptive evidence of a single volatile organic compound, acetone, was detected in sample 15-SLB. · Extractable_Organic_CQIJ1pounds Sample 14-SLA contained 2-methylnaphthalene, phenanthrene, fluoranthene, pyrene, benzo(A)anthracene, chrysene, benzo(B and/or K)fluoranthene, benzo-A-pyrene, indeno(l ,2,3-CD) pyrene and benzo(GHI)perylene. The concentrations ranged up to 31 OJ ····ug/kg .. The presumptive evidence of several-co111p0LllldS was also-detected: Sample 14-SLB. contained 2-methylnaphthalene, acenaphthene, dibenzofuran, fluorenc, phenanthrene, fluoranthene and pyrene. The concentrations ranged up to 2901 ug/kg. The presumptive evidence of several compounds was also detected. 4-15 I I I I I I I I I I I I I I I I I I GE Superfund Site RI Report Draft May 1995 Sample 15-SLA contained 9 IJ ug/kg of fluoranthene and two unidentified compounds. Sample 15-SLB contained no detectable extractable organic compounds. Eesticides_andJ".CB~s Pesticides were not detected in any of the samples. Sample 14-SLA and 14-SLB contained PCB-1254 at concentrations of240 ug/kg and 160 ug/kg. PCB 1248 at concentrations of 150 ug/kg and 96 ug/kg, and PCB-1260 at concentrations of 540 ug/kg and 370 ug/kg, respectively. Sample 15-SLA contained PCB-1260 at a concentration of 64 ug/kg. Sample 15-SLB contained no detectable PCB's. Metals A variety of metals was detected in the soil samples including: barium, chromium, copper, lead, zinc, mercury and manganese. Railroad Track Two subsurface soil samples were collected along the railroad track. Location 16 was off the east comer of the main plant and location 17 was west of the warehouse building. The samples were collected just below the railroad gravel bed. The locations are indicated on Figure 4.1. Analytical results are presented in Table 4.1. Yolatile_Organic__Crnnpounds No volatile organic compounds were detected .. · Extractahle_Organic_Compounds Sample 16-SLB contained acenaphthene, fluorene, phenanthrene, anthracene, fluoranthcne, pyrene bcnzo(A)anthracene, chrysene, benzo(B and/or K)fluoranthene, benzo-A-pyrenc, and carbazole. The concentrations ranged up to I 0,00OJ ug/kg. Several unidentified compounds were also detected.-Sample 17-SLB cc.irifairied no· detectable extractable-organic compoui1ds. Eesticicles_and__Il_CB~ Pesticides were not detected in either of the samples. Sample 16-SLB contained PCB-1254 at a concentration of 53 ug/kg and PCB 1248 at a concentration of 46 ug/kg. Sample 17-SLB 4-16 I I I I I I I I I I I I I I I I I contained PCB-1260 at concentration of 58 ug/kg. Metals GE Superfund Site RI Report Draft May 1995 A variety of metals was detected in the soil samples including: barium, chromium, copper, lead, zinc, mercury and manganese. Sample 17-SLB contained an elevated concentration of chromium and manganese. Underground Storage Tank Locations Three subsurface soil samples were collected from locations near former underground storage tank locations. The locations are indicated on Figure 4.1. Analytical results are presented in Table 4.1. Yolatile_Qrganic_Compounds No volatile organic compounds were detected .. Extractable_Organic_Cornpounds Sample 20-SLD contained.1,000JN ug/kg of hexadecenoic acid and one unidentified compound. Samples 19-SLA and 22-SLD contained no detectable extractable organic compounds. Eesticides._and_I>_CB'..s Sample 19-SLA contained 6.0 ug/kg of deildrin, 25 ug/kg of 4,4'-DDT and 21 ug/kg of 4,4'- . DDE. Pesticides were not detected in samples 20-SLD or 22-SLD. PCB's were not detected in any of the samples. Metals -··----.---· --. -···------·-----· A variety of metals was detected in the soil samples including: barium,"chromium, copper, lead, zinc, mercury and manganese. Sample 22-SLD contained an elevated concentration of barium. · - 4-17 I I I I I I I I I I I D I • ·- I I I I 4.1.2 Seldon Clark Property GE Superfund Site RI Report Draft May 1995 Soil borings were drilled at three locations, as indicated on Figure 4.2 .. Analytical results are presented in Table 4.2. Locations 30 and 31 were in the fill area on the Seldon Clark property and location 32 is west across Spartanburg Highway. .'lolatile_Organic..Comp_ounds Sample 31-SLE collected from the fill material contained acetone, methyl ethyl ketone, 1,2- dichloroethene and methyl hexanone at concentrations of 160 ug/kg, I 90 ug/kg, 4J ug/kg and30JN ug/kg, respectively. Samples 30-SLF and 31-SLF, collected from native soil beneath the fill material, contained no detectable volatile organic compounds. Ten ug/kg of methyl ethyl ketone was detected in sample 32-SLB. Acetone was detected in samples 32- SLB and 32-SLC at concentrations of 57N ug/kg and 24N ug/kg, respectively. Extractable_O.rganic_Compounds Sample 31-SLE contained acenaphthylene, phenanthrene, anthracene, fluoranthene, pyrene, chrysene, benzo(B and/or K)fluoranthene, benzo-A-pyrene, indeno(l ,2,3-CD)pyrene, dibenzo(A,H)anthracene and 14 unidentified compounds. The concentrations of the identified compounds ranged between 82J ug/kg and I, IOOJ ug/kg. Samples 30-SLF and 31-SLF contained the presumptive evidence of extractable organic compounds, and sample 30-SLF contained unidentified compounds. Samples 32-SLA, 32-SLB and 32-SLC contained the presumptive evidence of extractable organic compounds. Samples 32-SLB and 32-SLC contained unidentified compounds . . Eesticides_ancl.E.CB,'__s Pesticides were detected in samples 31-SLE, 32-SLB and 32-SLC. Sample 31-SLE contained 4,4'-DDT, 4,4'-DDE and 4,4'--DDD at concentrations of 11 ug/kg, 15 ug/kg and 76 ug/kg, . ___ respe_ct~yely 0 _ Sample 3_2~S_LB co11tai11~cl 4:,4' -J?DD, gamn1a_-chlordap~ ~nc_l alp~a~chlordane at concentrations of 18 ug/kg, IS ug/kg and 15 ug/kg, respectively. Sample 32-SLC contained 4.3 ug/kg of 4,4'-DDT, 8.8 ug/kg of 4,4'DDE and 3.3J ug/kg of 4,4'-DDD. 4-18 I I I I I I I I I I I R I I I I I I I 0 0 g I g 0 * f-~ --i=roii ~ I f- (/) -(/) w z 0 ---, I-~ I I z & 0 ::e a:: 0 tii f-z 5 0... w C) Op-O<!r <!ro<9 b:; 0 .,, 0 • 0:: w 2 0:: <1'. Ow LL 0:: 0 <1'. W_i 1:;:;: _) 2LL f-(/) w 3nN3/\V 0N0:)3S SELDON CLARK PROPERTY ,,, 0 • I I (.? I (.? a:: ::, CD z ~ a:: ct: (/) ._, SOIL, SURFACE WATER AND SEDIMENT SAMPLING LOCATIONS ... ..., 0 • ... z w "' 0 w V) 0 z <( c,: w ,-i w ~ ~ =! c,: o::, V) (/) I I ·* 1---------------------------1 FIGURE 4.2 ~ ~EPA ~ GENERAL ELECTRIC SUPERFUND SITE EAST FLAT ROCK, NORTH CAROLINA .__ __________________________ __._ ____ ___, I Table 4.2 Soil Analytical Data Surrroary General Electric-Seldon Clark I East Flat Rock, North Carolina 31-SLE 31-SLF 30-SLF 32-SLA 32-SLB 32-SLC 09/22/94 09/22/94 09/21/94 09/21/94 09/21/94 09/21/94 I INORGANIC ELEMENTS MG/KG MG/KG MG/KG MG/KG MG/KG MG/KG BARIUM 96 97 41 43 68 34 I COBALT 32 2.9 7.6 5.2 6.8 CHROMIUM 210 7.2 95 33 34 13 COPPER 40 15 31 20 7.2 NICKEL 34 13 8.4 12 LEAD 43 11 12 3D 39 13 I TIN 14 STRONTIUM 8.7 4.6 2.9 5.0 5.5 TITANIUM 10DO 31D 450 5DO 980 170 VANADIUM 140 15 47 46 44 22 I YTTRIUM 9.6 3.6 6.4 5. 7 7. 1 ZINC 56 26 17 47 56 14 MERCURY 0.12 D.D6 O.D5 D.D5 ALUMINUM 5DDDD 130DD 19000 26000 36000 31000 I MANGANESE 630 250 170 190 240 54 CALCIUM 1200 420 510 1400 1600 MAGNESIUM 2000 1500 1000 2200 3500 550 IRON 41000 11000 14000 18000 21000 9800 POTASSIUM 1100 1200 700 1600 3900 820 I **************************************************************** ***FOOTNOTES*** I · MATERIAL WAS ANALYZED FOR BUT NOT DETECTED I I I I I I I I 4-20 I I Table 4.2 (cont) Soil Analytical Data Surrmary General Electric-Seldon Clark East Flat Rock, North Carolina I 31-SLE 31-SLF 30-SLF 32-SLA 32-SLB 32-SLC 09/22/94 09/22/94 09/21/94 09/21/94 09/21/94 09/21/94 I PURGEABLE ORGANIC COMPOUNDS UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG ACETONE 160 57N 24N METHYL ETHYL KETONE 190 lOJ I 1,2-DICHLOROETHENE (TOTAL) 4J METHYLHEXANONE 30JN EXTRACTABLE ORGANIC COMPOUNDS UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG I ACENAPHTHYLENE 270J PHENANTHRENE 150J ANTHRACENE 90J I FLUORANTHENE 400J PYRENE 400J CHRYSENE 380J BENZO(B ANO/OR K)FLUORANTHENE 1100J BENZO-A·PYRENE 440J I INOENO (1,2,3-CD) PYRENE 270J OIBENZO(A,H)ANTHRACENE 82J 14 UNIOENTIFIED COMPOUNDS 20000J OIETHYLBIPHENYL 80JN I OCTAHYDROTRIMETHYL(METHYLETHYL)PHENANTHRENOL 200JN 3 UNIDENTIFIED COMPOUNDS 1000J 10 UNIDENTIFIED COMPOUNDS 6000J OCTAHYOROOIMETHYL(METHYLETHYL) I PHENANTHRENECARBOXYLIC ACID 200JN TETRAHYDRODIMETHYL(METHYLETHYL)NAPHTHALENE 80JN 4 UNIDENTIFIED COMPOUNDS 3000J OCTADECANOIC ACID 200JN I PESTICIDE/PCB COMPOUNDS UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG 4,4 1 ·DDT (P,P'·DDT) 11 4.3 4,4'-0DE (P,P'·OOE) 15 8.8 I 4,4'-DDD (P,P'·DDD) 76 18 3.3J PCB-1254 (AROCLOR 1254) 220 86 PCB-1248 (AROCLOR 1248) 420 PCB-1260 (AROCLOR 1260) 36 I GAMMA-CHLORDANE /2 15 ALPHA-CHLORDANE /2 15 **************************************************************** I ***FOOTNOTES*** ESTIMATED VALUE N PRESUMPTIVE EVIDENCE OF PRESENCE OF MATERIAL I MATERIAL WAS ANALYZED FOR BUT NOT DETECTED I H I 4-21 I I I I I I I I I I I I I I I I I I GE Supcrrund Site RI Repo,i Draft May 1995 PCE;'s were detected in two samples. Sample 32-SLA contained 220 ug/kg of PCE-1254, 420 ug/kg of PCE-1248 and 36 ug/kg of PCE-1260. Sample 32-SLB contained 86 ug/kg of PCE-1254. Metals A variety of metals was detected in the soil samples including: barium, chromium, copper, lead, zinc, mercury and manganese. Sample 31-SLE contained elevated concentrations of chromium and manganese. 4.1.3 Shepherd Farm Property Thirteen composite surface soil samples and 15 subsurface grab samples were collected from the Shepherd Fann property. The locations are indicated on Figure 4.3. The analytical results are presented in Table 4. 3 . Eight surface and eight subsurface samples were collected from yards in the Spring Haven trailer Park. These locations are designated 50 through 55. Table 4.fpresents the address for each residence sampled and the location of the subsurface soil sample. The three samples collected from location 50 are considered control samples for the study. The fill area located behind and west of the Shepherd house and north of the Spring Haven trailer park was divided into five areas as illustrated on Figure 4.3. These locations are designated 56 through 60. One composite surface soil sample and a grab subsurface soil sample were collected from the center of each area at a depth of three feet to four feet ELS. Also, grab subsurface soil samples were collected from locations 57 and 59 at a depth of six feet to eight feet ELS. :\1:ulatile__O.rganic_Cump.ounds Volatile organic compounds were detected in two samples. Sample 53-SLE contained 6J ug/kg of tetrachloroethene and 2J ug/kg of xylencs. Sample 56-SLA contained 2J ug/kg of icfrachforoethene. ···· -· -· · -·· ·--· -· · · -· --· · 4-22 I I I I I I I I I I I I I I • I I p I / ; f I ! / , ,,/ / /" , i / ! i , ! / / I i / - · avo~ ~ 3N1~ \\ \ \ ... ____ ··-··-·· SHEPHERD FARM PROPERTY SOIL SAMPLING LOCATIONS <I) z 0 ~ () 3 '-' z :::; a. ~; • ....--------------------------1 FIGURE 4.3 n I wEPA GENERAL ELECTRIC SUPERFUND SITE EAST FLAT ROCK, NORTH CAROLINA I "L----------------------------'-----___. - - 1!!!!!111!!1 I!!!!! 11111111 iiiii - ------liiil Table 4.3 Soil Analytical Data SUITITiary General Electric-Shepherd Farm East Flat Rock, North Carolina 50-SLA 450-SLA 550-SLA 50-SLB 50-SLC 51-SLA 51-SLB 52-SLA 52-SLB 53-SLA 53-SLB 09/12/94 09/12/94 09/12/94 09/12/94 09/20/94 09/12/94 09/12/94 09/12/94 09/12/94 09/12/94 09/13/94 INORGANIC ELEMENTS MG/KG MG/KG MG/KG MG/KG MG/KG MG/KG MG/KG MG/KG MG/KG MG/KG MG/KG BARIUM 110 99 110 70 63 72 78 62 83 99 120 CADMIUM 4.4 9.7 COBALT 9.9 8.4 9.3 5.3 5.9 6.6 7.6 5.8 6.6 12 12 CHROMIUM 15 13 18 3 .9 25 33 37 31 47 73 COPPER 30J 25J 29J 15J 120A 69J 24J 44J 1300A 1600J MOLYBDENUM 5.7 5.4 6.8 11 27 NICKEL 8.4 8.8 13 10 14 29 65 LEAD 17 15 19 15 9.6 100 57 23 27 240 1100 TIN 15 28 520 STRONT !UM 4.8 3. 1 3. 1 3.0 6.5 5.9 8.9 33 TELLURIUM TITANIUM 2000 1800 2000 1000 790 910 1300 1400 1500 760 320 VANADIUM 43 37 39 16 10 42 56 70 57 40 26 YTTRIUM 27 24 26 17 20 12 13 9.5 9.5 12 ZINC 67 55 64 43 32 180 120 38 58 1000 3200 MERCURY 0. 11 0.06 0.06 0.06 0.09 0.13 ALUMINUM 36000 31000 33000 22000 22000 37000 46000 49000 48000 49000 47000 MANGANESE 530 480 500 380 330 380 240 190 380 390 610 CALCIUM 560 430 620 160 1400 740 460 1200 3800 MAGNESIUM 8800 7600 8500 5600 3800 2800 3800 2900 5600 2300 1400 IRON 24000 21000 29000 13000 9300 23000 30000 34000 30000 29000 68000 POTASSIUM 8100 7000 7900 4700 4000 2300 3700 2900 5400 1700 **************************************************************** ***FOOTNOTES*** -MATERIAL WAS ANALYZED FOR BUT NOT DETECTED 4-24 - --iiiii -----lilil iiiil Table 4.3 (cont) Soil Analytical Data Surrmary General Electric-Shepherd farm East Flat Rock, North Carolina 50-SLA 450-SLA 550-SLA 50-SLB 50-SLC 51-SLA 51-SLB 52-SLA 52-SLB 53-SLA 53-SLB 09/12/94 09/12/94 09/12/94 09/12/94 09/20/94 09/12/94 09/12/94 09/12/94 09/12/94 09/12/94 09/13/94 PURGEABLE ORGANIC COMPOUNDS UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG TETRACHLOROETHENE(TETRACHLOROETHYLENE) 6J TOTAL XYLENES 2J EXTRACTABLE ORGANIC COMPOUNDS UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG DIETHYL PHTHALATE 980 PHENANTHRENE 11 OJ DI-N-BUTYLPHTHALATE 130000 FLUORANTHENE 120J PYRENE 110J BENZYL BUTYL PHTHALATE· 680 BIS(2-ETHYLHEXYL) PHTHALATE 3000 HEXACHLOR08IPHENYL (2 ISOMERS): 300JN TRICHLOROBIPHENYL (3 ISOMERS) 2000JN TETRACHLOR081PHENYL(8 ISOMERS): 4000JN PHTHALICANHYDRIDE 2000JN TRICHLOROBIPHENYL 2000JN TETRACHLOROBIPHENYL (4 iSOMERSi 7000JN BENZENEDICARBOXYLIC ACID, BUTYLHEXYLESTER 8000JN HEXACHLOROBIPHENYL 2000JN PHOSPHORIC ACID, (ETHYLHEXYL)ESTER 700JN 20000JN 3 UNIDENTIFIED COMPOUNDS 1000J 7 UNIDENTIFIED COMPOUNDS 20000J PESTICIDE/PCB COMPOUNDS UG/KC UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG PCB-1248 (AROCLOR 1248) 1700C 540C 100N 11000C PCB-1260 (AROCLOR 1260) 1700C ?SOC 24JN 3300c **************************************************************** ***FOOTNOTES*** A AVERAGE VALUE J ESTIMATED VALUE N PRESUMPTIVE EVIDENCE OF PRESENCE OF MATERIAL MATERIAL WAS ANALYZED FOR BUT NOT DETECTED C CONFIRMED BY GC/MS 4-25 llllil iiiii iiiii - - --.. liiil liiiil Table 4.3 (cont) Soil Analytical Data Surrrnary General Electric-Shepherd Farm East Flat Rock, North Carolina 54-SLA 54-SLB 54-SLC 55-SLA 55-SLB 56-SLA 56-SLB 57-SLA 57-SLB 57-SLC 09/12/94 09/12/94 09/12/94 09/12/94 09/12/94 09/13/94 09/13/94 09/13/94 09/13/94 09/13/94 INORGANIC ELEMENTS MG/KG MG/KG MG/KG MG/KG MG/KG MG/KG MG/KG MG/KG MG/KG MG/KG SILVER 6.3A BARIUM 62 65 99 57 57 110 81 190 380 230 BERYLLIUM 7.4 CADMIUM 6. 1 10 COBALT 9.3 7.0 4.0 11 18 13 20 35 CHROMIUM 30 29 14 38 30 60 39 62 130 32 COPPER 130J 35J 12J 32J 20J 20000A 63J 640A 56A 20J MOLYBDENUM 9.4 14 50 NICKEL 14 18 12 10 47 13 63 140 56 LEAD 73 29 16 22 24 9600A 25 270 68 54 TIN 25 2400A 26 STRONT !UM 7.8 4.2 4.0 15 69 140 100 TELLURIUM TITANIUM 830 1100 1300 960 700 840 1200 1100 3100 1100 VANADIUM 50 62 32 64 47 52 38 70 130 48 YTTRIUM 10 8.5 17 13 12 13 30 30 78 41 ZINC 160 29 30 49 45 730 54 590 110 50 MERCURY 0. 10 0.06 0.07 0.07 0.12 0.10 ALUMINUM 46000 64000 67000 36000 33000 46000 50000 53000 77000 72000 MANGANESE 250 100 130 300 150 370 570 470 380 790 CALCIUM 450 480 830 470 2100 2300 1000 MAGNESIUM 2500 1000 2500 2000 1000 3000 3800 3500 12000 2700 IRON 27000 39000 24000 31000 21000 38000 24000 51000 66000 22000 POT ASS !UM 2300 2700 1600 950 1200 1900 1500 6800 2700 **************************************************************** ***FOOTNOTES*** J ESTIMATED VALUE -MATERIAL WAS ANALYZED FOR BUT NOT DETECTED 4-26 --- - l!!!!!l!I 111111 54-SLA 09/12/94 PURGEABLE ORGANIC COMPOUNDS UG/KG TETRACHLOROETHENE(TETRACHLOROETHYLENE) EXTRACTABLE ORGANIC COMPOUNDS UG/KG TRICHLOROBIPHENYL (4 ISOMERS) 3000JN TETRACHLOROBIPHENYL (9 ISOMERS) ?OOOJN TRICHLOROBIPHENYL (3 ISOMERS) HEXACHLOROBIPHENYL TRICHLOROBIPHENYL (2 ISOMERS) TETRACHLOROBIPHENYL (7 ISOMERS) HEPTACHLOROBIPHENYL 4 UNIDENTIFIED COMPOUNDS 7 UNIDENTIFIED COMPOUNDS PESTICIDE/PCB COMPOUNDS UG/KG GAMMA·BHC (LINDANE) 4,41 -001 (P,P1 -DDT) 4,4' ·ODE (P,P 1 ·DDE) PCB-1254 (AROCLOR 1254) PCB-1248 (AROCLDR 1248) 3900C PCB-1260 (AROCLDR 1260) 980C ENDRIN ALDEHYDE ENDRJN KETONE ' **~************************************************************* ***FOOTNOTES*** A AVERAGE VALUE J ESTIMATED VALUE N PRESUMPTIVE EVIDENCE OF PRESENCE OF MATERIAL MATERIAL WAS ANALYZED FOR BUT NOT DETECTED C CONFIRMED BY GC/MS iiiil - - -.. liiiil Table 4.3 Soil Analytical Data Sunmary General Electric-Shepherd Farm East Flat Rock, North Carolina ' 54-SLB 54-SLC 55-SLA 55-SLB 56-SLA 56-SLB 57-SLA 57-SLB 57-SLC 09/12/94 09/12/94 09/12/94 09/12/94 09/13/94 09/13/94 09/13/94 09/13/94 09/13/94 UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG 2J UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG 1000JN 400JN 1000JN 4000JN 4000JN 500JN 2000J 6000J UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG 110 48 130 29N 130 7300C 130 9400c 7500N 220N 31J 41N 4000C 92 8.4 4-27 -- ----1!!!!!!!11 I!!!!!! lllil llliiiil iiiil ---- Table 4.3 {cont) Soil Analytical Data SuTTll1ary General Electric·Shepherd Farm East Flat Rock, North Carolina 58-SLA 58-SL8 59-SLA 59-SLB 59-SLC 60-SLA 60-SLB 09/13/94 09/13/94 09/13/94 09/13/94 09/13/94 09/13/94 09/13/94 INORGANIC ELEMENTS MG/KG MG/KG MG/KG MG/KG MG/KG MG/KG MG/KG BARIUM 89 83 67 64 65 98 44 CADMIUM 3.2 COBALT 4.4 5.2 CHROMIUM 45 45 41 23 29 42 48 COPPER 300A ZZJ 130J 14J 29J 250J 29J MOLYBDENUM 5.4 NICKEL 24 18 16 11 18 13 LEAD 140 44 85 26 46 160. 27 TIN 19 12 17 STRONTIUM 14 14 11 14 19 12 TITANIUM 900 730 680 410 630 720 1400 VANADIUM 62 60 52 39 56 51 88 YTTRIUM 13 16 9.5 5.6 10 13 ZINC 320 38 120 28 29 340 32 MERCURY 0.10 0.08 0. 10 0, 13 0.06 ALUMINUM 43000 49000 39000 41000 100000 35000 55000 MANGANESE 230 320 160 210 zoo 240 120 CALCIUM 1100 740 310 2900 MAGNESIUM 1600 1200 890 820 1200 2000 1200 IRON 30000 27000 24000 18000 29000 26000 43000 POTASSIUM 1500 ' ' **************************************************************** ***FOOTNOTES*** J ESTIMATED VALUE MATERIAL ~AS ANALYZED FOR BUT NOT DETECTED 4-28 ---111!!!!1 l!!l!!I liiilil lliilill liiiii iiiiil -- PURGEABLE ORGANIC COMPOUNDS NONE DETECTED EXTRACTABLE ORGANIC COMPOUNDS FLUORANTHENE PYRENE CHRYSENE METHYLCHRYSENE HYOROXYNAPHTHALENEDJONE HEXACHLOROBIPHENYL HEPTACHLOROBIPHENYL HYDROXYNAPHTHALENEDIONE 2 UNIDENTIFIED COMPOUNDS 4 UNIDENTIFIED COMPOUNDS 8 UNIDENTIFIED COMPOUNDS PESTICIDE/PCB COMPOUNDS ENDOSULFAN I (ALPHA) 4,41-DDE (P,P 1 -DDE) PCB-1254 (AROCLOR 1254) PCB-1248 (AROCLOR 1248) PCB-1260 (AROCLOR 1260) 58-SLA 09/13/94 UG/KG UG/KG 67J 200J 300JN SOOOJ UG/KG 19P 3800C 4900C ********.~******************************************************* ***FOOTNOTES*** A AVERAGE VALUE J ESTIMATED VALUE N PRESUMPTIVE EVIDENCE OF PRESENCE OF MATERIAL MATERIAL YAS ANALYZED FOR BUT NOT DETECTED C CONFIRMED BY GC/MS Table 4.3 (cont) Soil Analytical Data Surrrnary General Electric-Shepherd farm East Flat Rock, North Carolina 58-SLB 59-SLA 59-SLB 09/13/94 59-SLC 60-SLA 09/13/94 09/13/94 09/13/94 09/13/94 UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG 130J 150J 500JN 100JN 100JN 700JN 1000J 3000J UG/KG UG/KG UG/KG UG/KG UG/KG 34 2100C 4-29 - 60-SLB 09/13/94 UG/KG UG/KG UG/KG --- I I I I I I I I I I I I I I •--- 1 I I I ·--. -· TABLE 4.4 GE Superfuncl Site RI Report Draft May 1995 SOIL SAfvIPLING LOCATION SUMMARY SPRING HA VEN TRAILER PARK/SHEPHERD FARM PROPERTY EAST FLAT ROCK, NORTH CAROLINA Sample Number Address/Subsurface Soil Sample Location GE-050-SLA Vacant Lot GE-050-SLB Vacant Lot GE-050-SLC Vacant Lot GE-051-SLA I 06 Spring Haven I Rd GE-051-SLB Front Yard GE-052-SLA 110 Spring Haven Rd GE-052-SLB Front Yard GE-053-SLA I 07 Spring Haven Rd GE-053-SLB Back Yard GE-054-SLA 111 Spring Haven Rd GE-054-SLB Back Yard GE-054-SLC Back Yard GE-055-SLA 115 Spring Haven Rd GE-055-SLB Back Yard GE-060-SLA Grid 60 GE-060-SLB Center GE-056-SLA Grid 56 ----• + • GE-056-SLB Center GE-057-SLA Grid 57 GE-057-SLB Center GE-057-SLC Center 4-30 I I I I I I I I I I I g H I •- I I I I TABLE 4.4 (cont) GE Superfund Site RI Rep0!1 Draft May 1995 SOIL SAMPLING LOCATION SUMMARY SPRING HA VEN TRAILER PARK/SHEPHERD FARM PROPERTY EAST FLAT ROCK, NORTH CAROLINA Sample Number Address/Subsurface Soil Sample Location GE-058-SLA Grid 58 GE-058-SLB Center GE-059-SLA Grid 59 GE-059-SLB Center GE-059-SLC Center 4-31 I I I I I I I I I I I I I I I g I Extractahle...Diganic_Compounds GE Superfund Site RI Report Draft May 1995 Extractable organic compounds were detected in eight surface soil samples and one subsu1face soil sample. Samples 51-SLA, 54-SLA, 56-SLA, 57-SLA and 59-SLA contained only the presumptive evidence of, or unidentified extractable organic compounds. In addition to unidentified and the presumptive evidence of extractable organic compounds, samples 53-SLA, 58-SLA and 60-SLA contained pyrene at concentrations of 120J ug/kg, 671 ug/kg and 150 ug/kg, respectively. Fluoranthene was detected in sample 53-SLA at 120J ug/kg and sample 60-SLA at I 30J ug/kg. Sample 53-SLA contained I OJ ug/kg of phenanthrene. Sample 53-SLB contained 980 ug/kg of diethyl phthalate, 130,000 ugikg of di-N- butylphthalate, 680 ug/kg of benzyl butyl phthalate and 3,000 ug/kg of bis(2- ethylhexyl)phthalate. The presumptive evidence of several compounds was detected as were several unidentified compounds. Eesti c ides.andJ>.CB'.s Lindane was detected in sample 56-SLA at a concentration of 110 ug/kg. 4,4'-DDT was detected in samples 55-SLA, 55-SLB and 57-SLB at concentrations ranging up to I 30 ug/kg. 4,4'DDE was detected in samples 55-SLB and 60-SLA at concentrations up to 130 ug/kg. Sample 57-SLA contained 92 ug/kg of endrin aldehyde and 8.4 ug/kg of endrin ketone. Sample 58-SLA contained 19P ug/kg of endosulfan. PCB's were detected in nine surface soil samples and three subsurface soil samples. Concentrations of total PCB's which exceeded 5,000 ug/kg were detected in samples 53-SLA, 56-SLA, 57-SLA and 58-SLA. Total PCB's concentrations which exceeded 1,000 ug/kg ( but less than 5,000 ug/kg) were detected in samples 51-SLA, 51-SLB, 54-SLA and 60-SLA. Metals A variety of metals was detected in the soil samples including: barium, chromium, copper, lead, zi_ns, mercury i!.ndmangan~se, An elev_at_ed concentrati_on12f cl~ro1nium \Vas_ detec_ted in sample 57-SLB. Samples 57-SLB and 57-SLC contained elevated concentrations of barium. Elevated concentrations of lead were detected in samples 51-SLA, 53-SLB, 56-SLA, 58-SLA and 60-SLA. · Elevated concentrations of copper were detected in samples 53-SLA, 53-SLB and 56-SLA. Sam'p!es 53-SLA and 53-SLB contained elevated concentrations of zinc and samples 50-SLA, 4-32 I I I I I I I I I I I I I g I I I I GE Superfund Site RI Report Draft May 1995 550-SLA, 53-SLB,56-SLB and 57-SLC contained elevated concentrations of manganese. ICLE Sample 59-SLC was analyzed for eleven TCLP metals including silver, arsenic, barium, cadmium, chromium, lead, selenium, nickel, antimony, beryllium and thallium. Barium was the only compound detected. The concentration was 0.39 mg/I. 4.2 Surface_Water_and_SeclimenLSampling Thirteen surface water and sediment samples were collected from 12 locations during this investigation. Six samples, locations one through six, were collected from the GE property. Location 4 is a spring which flows into the adjacent creek. One sample was collected from the Seldon Clark property, location 30; and six samples were collected from the Shepherd Fann property, locations 50 through 54. Sample location 452 is a duplicate of sample location 52. The locations are indicated on Figures 4.4, 4.2 and 4.5, respectively. The surface water analytical results are presented in Table 4.5 and the sediment analytical results are presented in Table 4.6. Surface Water YJ:llatiJe__Qrganic_C.QmJJ.Qunds Tetrachloroethene was detected in all six samples collected from the GE property and from samples 51-SW and 54-SW. The concentrations ranged between 0.53 ug/1 and 3.5 ug/l. Sample 4-SW contained 6. Sug/1 of cis-1,2-dichloroethene, 0. 7!J ug/1 of 1, l, !-trichloroethane and l .9J ug/1 of trichloroethene. Sample 6-SW contained 7.41 ug/1 of carbondisulfide. · Samples 52-SW and 452-SW contained 3.0J and 3.2J ug/1 of toluene. Extractahle .. .Drganic__CompGunds Sample 30-SW contained 20JN ug/1 of hydroxynaphthalenedione and sample 52-SW contained 20JN Lig/1 of hexadecanoic acid. -----•--- Ecsticides .. and...l'.CB~s No pesticides or PCB's were detected in the surface water samples. 4-33 I I I I I I I I I I I n I I I I I "' _, 0 '-J ~ I I GE PROPERTY SURFACE WATER AND SEDMIMENT SAMPLING LOCATIONS 1----------------------------iFIGURE &EPA GENERAL ELECTRIC EAST FLAT ROCK, SUPERFUND SITE NORTH CAROLINA 4,4 "'L...--------------------------------------.L.---------1 I I I I I I I I I I I I H R m I I , / / / ; ! / I , / , ; ; i ,' ! ; ; ! / i ; i i i / i i ~\ 0 \. \ \ \ .. ·--·-·-··-··-·· SHEPHERD FARM PROPERTY ATER SEDIMENT SAMPLING LOCATIONS 0 "' 0 ·-· ·-.. -·-··-.-··-··--- ·.!~~:a:~:1:E::::A::~:-::::GE:N:E:R:AL::E:LE:C:T:Rl:C:S:U:P:E:RF:U:N:D::Sl:TE::::::~--FI-GU_R_E_ 4 ·- 5 ~ ~ _ ~ EAST FLAT ROCK, NORTH CAROLINA I I Table 4.5 Surface Water Analytical Data Surrmary General Electric East Flat Rock, North Carolina I 1-SW 2-SW 3-SW 4-SW 5-SW 6-SW 30-SW 09/13/94 09/13/94 09/13/94 09/13/94 09/16/94 09/16/94 09/12/94 I I I I INORGANIC ELEMENTS BARIUM COBALT COPPER MOLYBDENUM STRONTIUM TITANIUM ZINC ALUM! NUM MANGANESE CALCIUM MAGNESIUM IRON SODIUM POTASSIUM UG/L 28 22 39 6.4 1100 42 MG/L 2.8 · 1. 5 1 .4 2.8 0.85 **************************************************************** I ***FOOTNOTES*** -MATERIAL WAS ANALYZED FOR BUT NOT DETECTED I I H u I I UG/L 25 3.0 25 6.0 11 270 83 MG/L 3.5 1. 7 0.64 4.6 1.2 I 4-36 I UG/L 25 3.8 3.3 25 8.6 14 440 130 MG/L 4.0 1.6 0.73 16 2.0 UG/L UG/L UG/L UG/L 71 24 25 56 3.6 2.6 21 26 26 140 22 8.6 19 13 11 8.1 12 73 1400 360 690 350 940 62 79 940 MG;L MG/L MG/L MG/L 3.6 3.8 4.0 76 1. 7 1.6 1.7 14 2. 1 0.71 1.0 7.3 3.1 7. 1 7.6 3. 1 1 . 1 1.3 3.4 I I I I I I I I I I I I H I I I Table 4.5 (cont) Surface Water Analytical Data Surrmary General Electric East Flat Rock, North Carolina 1-SW 2-SW 09/13/94 09/13/94 PURGEABLE ORGANIC COMPOUNDS UG/L UG/L CARBON OISULFIOE CIS-1,2-0ICHLOROETHENE 1 , 1 , 1-TR I CHLOROETHANE TRICHLOROETHENE(TRICHLOROETHYLENE) TETRACHLOROETHENE(TETRACHLOROETHYLENE) 1.3J 3.5J EXTRACTABLE ORGANIC COMPOUNDS UG/L UG/L HYDROXYNAPHTHALENEDIONE PESTICIDE/PCB COMPOUNDS UG/L UG/L NONE DETECTED **************************************************************** ***FOOTNOTES*** N ESTIMATED VALUE PRESUMPTIVE EVIDENCE OF PRESENCE Of MATERIAL MATERIAL WAS ANALYZED FOR BUT NOT DETECTED 4-37 3-SW 09/13/94 UG/L 1. 9J UG/L UG/l 4-SW 5-sw 6-SW 30-SW 09/13/94 09/16/94 09/16/94 09/12/94 UG/L UG/L UG/L UG/L 7.4J 6.8 0. 71J 1.9J 0.53J 2.6J 1. 9J UG/L UG/L UG/L UG/l 20JN UG/L UG/L UG/l UG/L I I I I I D I D R I I I I I I I I INORGANIC ELEMENTS BARIUM STRONT !UM TITANIUM ZINC ALUMINUM MANGANESE CALCIUM MAGNESIUM IRON SODIUM POTASSIUM Table 4.5 (cont) Surface Water Analytical Data Surrrnary General Electric-Shepherd farm East Flat Rock, North Carolina 50-SW 51-SW 52-SW 09/12/94 09/13/94 09/13/94 1700 0840 0920 UG/L UG/L UG/L 20 18 9.8 18 20 8.2 32 13 14 18 8.5 4.2 640 420 380 31 25 33 MG/l MG/l MG/l 2.6 3.2 1 . 2 1.3 1.4 0.66 0.78 0.47 0.87 2.2 2.8 1. 9 0.52 0.82 0.51 **************************************************************** ***FOOTNOTES*** -MATERIAL WAS ANALYZED FOR BUT NOT DETECTED 4-38 53-SW 54-SW 452-SW 09/13/94 09/13/94 09/13/94 1120 1100 0935 UG/L UG/L UG/L 14 18 9.6 12 14 8.2 9.0 12 14 5. 1 5.8 5.2 280 330 380 30 41 33 MG/L MG/l MG/l 1.8 2.2 1 . 2 0.83 1 . 1 0.66 0.86 0.85 0.86 2.1 2.4 1.8 0.53 0.69 0.54 I I I I I I I I n I I I I I I I I I I Table 4.5 '(cont) Surface Water Analytical Data Suninary General Electric·Shepherd farm East Flat Rock, North Carolina 50-SW 51-SW 52-SW 53-SW 54-SW 09/12/94 09/13/94 09/13/94 09/13/94 09/13/94 PURGEABLE ORGANIC COMPOUNDS TETRACHLOROETHENE(TETRACHLOROETHYLENE) TOLUENE EXTRACTABLE ORGANIC COMPOUNDS HEXADECANOIC ACID PESTICIDE/PCB COMPOUNDS NONE DETECTED UG/L UG/L UG/L UG/L 1. SJ UG/L UG/L **************************************************************** ***FOOTNOTES*** J N ESTIMATED VALUE PRESUMPTIVE EVIDENCE OF PRESENCE OF MATERIAL MATERIAL WAS ANALYZED FOR BUT NOT DETECTED 4-39 UG/L 3.0J UG/L ZOJN UG/L UG/L UG/L UG/L UG/L 0.66J UG/L UG/L 452·SW 09/13/94 UG/L 3.ZJ UG/L UG/L I I Table 4.6 Sediment Analytical Data Sunmary General Electric East Flat Rock, North Carolina I 1-SD 2-SD 3-SD 4-SD 5-SD 6-SD 30-SD 09/13/94 09/13/94 09/13/94 09/13/94 09/16/94 09/16/94 09/12/94 I INORGANIC ELEMENTS MG/KG MG/KG MG/KG MG/KG MG/KG MG/KG MG/KG BARIUM· 9.5 35 9.7 18 12 20 18 CADMIUM 0.77 I COBALT 3.0 1.2 1. 5 4.4 CHROMIUM 14 28 3.8 1.3 6.5 7.4 14 COPPER 2.3J 13J 2.8J 3.2J 6.6J 16A NICKEL 6.2 2.6 4.1 LEAD 10 6.3 96A TIN 2.8 STRONTIUM 1.4 2.3 1.4 1.7 4.1 TITAIJIUM 120 540 130 82 110 220 310 VANADIUM 7.6 24 4.8 1.6 5.6 7.2 15 I YTTRIUM 1.4 4.4 1.4 2. 1 4.9 ZINC 6.6 36 7.7 5. 1 9. 1 22 83 ALUMINUM 3000 12000 3600 2000 4600 6100 5700 MANGANESE 33 110 23 240 48 93 250 I CALCIUM 66 190 79 200 91 180 3700 MAGNESIUM 260 1600 320 67 230 610 2300 IRON 4000 13000 3100 780 3000 4200 10000 POTASSIUM 1400 290 280 440 840 I **************************************************************** ***FOOTNOTES*** I -MATERIAL WAS ANALYZED FOR BUT NOT DETECTED R I I I I I I 4-40 I I I Table 4.6 (cont) Sediment Analytical Data Sunmary General Electric I East Flat Rock, North Carolina 1-SD 2-SD 3-SD 4-SD 5-SD 6-SD 30-SD 09/13/94 09/13/94 09/13/94 09/13/94 09/16/94 09/16/94 09/12/94 I PURGEABLE ORGANIC COMPOUNDS UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG NONE DETECTED I EXTRACTABLE ORGANIC COMPOUNDS UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG PHENANTHRENE 80J FLUORANTHENE 150J PYRENE 140J I CHRYSENE 87J BENZO(B AND/OR K) FLUORANTHENE 120J BENZO·A·PYRENE 70J INDENO (1,2,3-CD) PYRENE 73J I DIBENZO(A,H)ANTHRACENE 96J BENZO(GHl)PERYLENE 73J 3 UNIDENTIFIED COMPOUNDS 3000J 2 UNIDENTIFIED COMPOUNDS 3000J I PESTICIDE/PCB COMPOUNDS UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG R 4,41 -DDT (P,P 1·DDT) 6.2 4,4 1-DDE (P,P 1-DDE) 7.8 PCB· 1254 (AROCLOR 1254) 85 49 PCB-1248 (AROCLOR 1248) 430 170C 54 85 PCB-1260 (AROCLOR 1260) 34J I ENORIN ALOEHYOE 5.6 **************************************************************** ***FOOTNOTES*** I A AVERAGE VALUE ESTIMATED VALUE MATERIAL WAS ANALYZED FOR BUT NOT DETECTED C CONFIRMED BY GC/MS I I I I I I I 4-41 I I I Table 4.6 (cont) Sediment Analytical Data Surm1ary General Electric·Shcpherd farm I East Flat Rock, North Carolina so-so 51 ·SD 52-SD 452-SD 53-SO 54-SD 09/12/94 09/13/94 09/13/94 09/13/94 09/13/94 09/13/94 I INORGANIC ELEMENTS MG/KG MG/KG MG/KG MG/KG MG/KG MG/KG BARIUM 51 66 63 50 13 8.2 BERYLLIUM 0.58 I COBALT 4.8 5.8 5.0 3.7 2.0 CHROMIUM 14 12 47 47 6.6 13 COPPER 7.SJ 11 J 14J 12J 6.SJ 3.0J NICKEL 6.5 4.6 9.2 7.8 LEAD 5 .8 12 16 13 I STRONT !UM 2.1 3.6 4.2 2.4 TITANIUM 680 610 810 660 160 110 VANADIUM 21 20 46 38 6.4 7.6 YTTRIUM 6.3 8.1 8.6 6.8 1.3 I ZINC 26 65 58 46 7.9 5.9 ALUMINUM 10000 14000 20000 15000 3600 2600 MANGANESE 99 360 92 70 70 30 CALCIUM 230 340 380 300 55 I MAGNES !UM 1300 1800 1700 1300 330 290 IRON 9900 13000 16000 13000 2800 2800 POTASSIUM 1100 1400 1300 1000 230 I **************************************************************** ***FOOTNOTES*** u · MATERIAL WAS ANALYZED FOR BUT NOT DETECTED I I I I I I I 4-42 I I I I I I I I I D I I I I I I I I I I Table 4.6 (cont) Sediment Analytical Data Sunmary General Electric-Shepherd Farm East Flat Rock, North Carolina 50-SD 51-SD 52-SD 09/12/94 09/13/94 09/13/94 PURGEABLE ORGANIC COMPOUNDS UG/KG UG/KG UG/KG NONE DETECTED EXTRACTABLE ORGANIC COMPOUNDS UG/KG UG/KG UG/KG FLUORANTHENE 73J PYRENE 59J BIS(2·ETHYLHEXYL) PHTHALATE 1800 (3-AND/OR 4-)METHYLPHENOL 1400 22 UNIDENTIFIEO COMPOUNDS 600000J PHTHALIC ANHYDRIDE 1 UNIDENTIFIED COMPOUND PESTICIDE/PCB COMPOUNDS UG/KG UG/KG UG/KG 4,4 1-DDT (P,P1-DDT) PCB-1248 (AROCLOR 1248) 73N **************************************************************** ***FOOTNOTES*** N ESTIMATED VALUE PRESUMPTIVE EVIDENCE OF PRESENCE OF MATERIAL MATERIAL WAS ANALYZED FOR BUT NOT DETECTED 4-43 452-SD 53-SD 54-SD 09/13/94 09/13/94 09/13/94 UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG 1300 760 500000J 100JN 300JN 400J UG/KG UG/KG UG/KG 5.0N I I I I I I I I I I I I I I I Metals GE Supc,fund Site RI Report Draft May 1995 Metals were detected in all of the surface water samples. The SMCL of 50-200 ug/1 of aluminum was exceeded in all the samples collected. The SMCL of 0.3 mg/I of iron was exceeded in all the samples collected. The SMCL of 50 ug/1 of manganese was exceeded in samples 2-SW, 3-SW, 4-SW, 5-SW, 6-SW and 30-SW. EielcLEarameter.s The field parameters of temperature, pH and specific conductance were measured. The results are presented in Table 4. 7. The pH of the surface water samples were all slightly basic and ranged between 7.2 SU in sample I-SW to 8.1 SU in sample 53-SW. The specific conductance ranged between 20 umhos/cm and 40 umhos/cm. The temperatures ranged between 6.5 and 8.0 degrees centigrade (these measurements were obtained in Febrnary 1995). Sediment Y.ulatile....ili.gani.c_C.QITIµll.UlldS No volatile organic compounds were detected in the sediment samples Extractahle_Organic_Compouncl.s Extractable organic compounds were detected in eight sediment samples,. Sample 2-SD contained 3,000J ug/kg of three unidentified compounds and sample J-SD contained 3,000J ug/kg of 2 unidentified compounds. · Sample 30-SD contained phenanthrene, fluoranthene, pyrene, chrysene, benzo(B and/or K)fluoranthene, benzo-A-pyrene, indeno(l ,2,3-CD) pyrene, dibenzo(A,H)anthracene and benzo(GHI)perylene. The concentrations ranged between 70J ug/kg and 1501 ug/kg. Sample 51-SD contained 73J ug/kg of fluoranthene and 59J ug/kg of pyrene. Sample 52-SD contained 1,800 ug/kg of bis(2-ethylhexyl)phthalate, 1,400 ug/kg of 3-and/or 4-methylphenol and 6o6;oooj ug/kg of 22 unidentified CCHi1p0t1ncts: The-restilts fro,n sample 452-SD ai-e similar to. those of 52-SD. Samples 53-SD and 54-SD contained the presumptive evidence of phthalic anhydride.· Sample 54-SD contained 4001 ug/kg of one unidentified compound. 4-44 I I I I I I I I I I I D B I I I I I Location1 Sample Number Number I GE-001-SW 2 GE-002-SW " GE-003-SW ·' 4 GE-004-SW 5 GE-005-SW 6 GE-006-SW 50 GE-050-SW 51 GE-051-SW 52 GE-052-SW 53 GE-053-SW Table 4.7 Surface Water Field Parameters General Electric East Flat Rock, North Carolina pH Conductivity (SU) (umhos/cm) 7.2 40 NM' NM NM NM NM NM NM NM 7.3 220 7.4 40 7.6 40 7.8 20 8.1 20 I. Closest Sample collection location. Measurements collected 2-14-95. 2. NM -Parameter not measured 4-45 GE Superfund Site RI Report Draft May 1995 Temperature ( C) 8.0 NM NM NM NM 7.0 8.5 7.5 6.5 7.0 I I I I I I I I 0 I I • I I I I I Eesticides_and__ECB.'.s GE Superfund Site RI Report Draft May 1995 Samples I-SD and 54-SD contained 4,4'-DDT at concentrations of 6.2 ug/kg and 5.0N ug/kg. Sample 2-SD contained 7.8 ug/kg of 4,4-'DDE and 5.6 ug/kg of endrin aldehyde. Six samples contained PCB's. PCB-1248 was detected in samples 2-SD, 3-SD, 5-SD, 6-SD and 5 I-SD. The concentrations ranged between 54 ug/kg and 430 ug/kg. Sample 6-SD also contained 85 ug/kg of PCB-1254 and 34J ug/kg of PCB-1260. Sample 30-SD contained 49 ug/kg of PCB-1254. Metals A variety of metals was detected in the sediment samples including: barium, chromium, copper, lead, zinc, and maganese. No elevated concentration were detected. 4.3 · Temporary Monitor Well Installation and Sampling Nine temporary wells were installed at the locations specified on Figures 4.6, 4.7 and 4.8. The analytical results are presented in Table 4.8. The field parameters of temperature, pH, specific conductance and turbidity were measured. The results are presented in Table 4.9. Sample 551-TW is a duplicate of sample 51-TW. Location 50 is considered background for the sites Y.olatile.ilrganic_Cnmp_Qunds Volatile organic compound were detected in six samples from five locations. Sample 2-TW contained 0.59J ug/l of 1,2-dichlorobenzene, 0.80J ug/l of 1,2,4-trichlorobenzene and 0. 71.J · ug/l of 1,2,3-trichlorobenzene. Sample 30-TW contained 0.067 AJ ug/l of p-isopropyltoluene. Sample 50-TW contained l. lJ ug/I of chlorofonn. Sample 51-TW contained 1. lJ ug/l of vinyl chloride, 1.2J ug/I of cis-1,2-dichloroethene, 0. 98J ug/l of trichloroethene and 29 ug/l of tetrachloroethene. Sample 551-TW contained similar compounds and concentrations. Sample 53-TW contained 32 ug/l of tetrachloroethene. ·---··--·--·-· -------·---------------------------., . Extractable_Qrganic_Compounds Extractable organic compounds were detected in one sample. Sample 53-TW contained 29 ug/l of benzylbutyl phthalate and the presumptive evidence of petroleum product. , 4-46 I I I I I I I I I I I u H I I I t, -I 0 " f\) CD &EPA ~ ~ ,1_ :a z ~ :;:!;! !\~ GE PROPERTY TEMPORARY MONITOR WELL LOCATIONS GENERAL ELECTRIC EAST FLAT ROCK, SUPERFUND SITE NORTH CAROLINA ► ~ ~ g ~ z < ~ ~ < ~ ~ FIGURE 4.6 '"L-------------------------------------------''--------.J I I I I • I I I I n n 0 0 u B /0 /' I 0 0 I I I I 1-z :s 0.. w (_') 0:: w 2 --if:iii J:j_ i w 0:: <{ Ow t;; ~ ,; w. _, <( u V) ac: J-(f) -LL 0:: 0 <{ (f) I-w z 0 "1 --, W_J ~ _J :;;,LL I z <( ac: 0 I- VJ w ::;; ac: 0 J-(f) ::JnN3/\'v' ONO::l3S SELDON CLARK PROPERTY TEMPORARY MONITOR WELL LOCATIONS ~ ~ s: I (_') I (_') ac: ::::, CD z ;:; ac: <{ I)_ (f) ~ <D I'- (f) ::::, ;:; 0 • V) z 0 ~ g _, G:l "' , 0: g z 0 ::, • I ~---------------------------1 FIGURE 4.7 "l tnll EnA GENERAL ELECTR1c suPERFuNo s1TE g ~ FA EAST FLAT ROCK, NORTH CAROLINA I " I I I I I I I • n u I I I I I I I I I ti 0: 0 I:: ~ ~5~ ::liO _._oJ5 i~ a 0 _, 0.. _, ::li _, a ..,.., .... ,. ' • p I ,., ,., / ! I ! I i '-r' \ ' \ \ -\ ... ---ovo~ cJVt>-3N111 --_ .. +----- B C ) SHEPHERD FARM PROPERTY TEMPORARY MONITOR WELL LOCATIONS 1--------------------------1 FIGURE 4.8 !~EPA GENERAL ELECTRIC SUPERFUND SITE EAST FLAT ROCK, NORTH CAROLINA .,, '-----------------,------------....L..------l ------- --11!!1!1 --liiiil Table 4.8 Temporary Well Analytical Data Su1T111ary General Electric East Flat Rock, North Carolina 1·TW 2-TW 30-TW 31-TW 50-TW 51-TW 551-TW 52-TW 53-TW 54-TW 09/21/94 09/21/94 09/22/94 09/21/94 09/20/94 09/20/94 09/20/94 09/13/94 09/21/94 09/20/94 INORGANIC ELEMENTS UG/l UG/l UG/L UG/L UG/L UG/l UG/l UG/l UG/L UG/l BARIUM 96 60 36 72 40 46 42 47 59 760 BERYLLIUM 1.6 COBALT 3.4 95 14 2.3 4.5 4.2 4.8 5.2 CHROMIUM 7 .5 2.3 3.0 2.6 COPPER 3.0 4.2 2.6 2.3 8. 1 3.9 2.3 NICKEL 190 36 4.3 8.5 STRONTIUM 58 9.9 35 14 28 28 29 5.9 26 62 TITANIUM 32 40 6.2 27 29 59 33 4.4 75 65 VANADIUM 2.9 3.5 9. 1 YTTRIUM 2.3 2.3 2.8 3.5 10 ZINC 15 10 18 25 4.5 67 35 2.8 12 19 MERCURY 0.28 ALUMINUM 1600 3200 410 820 540 1500 760 240 3600 2100 MANGANESE 160 38 2600 390 170 570 590 30 210 1500 MG/l MG/l MG/l MG/l MG/l MG/L MG/l MG/l MG/l MG/l CALCIUM 5.2 0.88 7.0 2.2 3.2 4.8 4.9 0.20 3. 1 13 MAGNESIUM 2.2 0.64 14 1.5 1.6 2.3 2.3 0.31 1.4 6.2 IRON 0.76 2.5 3.4 1.0 0.4 3.2 1.8 2.7 1.0 4.5 SODIUM 5.0 16 4.5 2.3 4.4 7.2 7 .5 1. 2 3.5 13 POTASSIUM 1.6 0.48 0.96 1.1 2.6 1.4 1.3 1.4 6.9 **************************************************************** ***FOOTNOTES*** -MATERIAL WAS ANALYZED FOR BUT NOT DETECTED 4-50 - -- -- 09/20/94 PURGEABLE ORGANIC COMPOUNDS VINYL CHLORIDE CIS-1,2-DICHLOROETHENE TRICHLOROETHENE(TRICHLOROETHYLENE) TETRACHLOROETHENE(TETRACHLOROETHYLENE) 1,2-DICHLOROBENZENE 1,2,4-TRICHLOROBENZENE 1,2,3-TRICHLOROBENZENE P-!SOPROPYLTOLUENE CHLOROFORM EXTRACTABLE ORGANIC COMPOUNDS BENZYL BUTYL PHTHALATE PETROLEUM PRODUCT PESTICIDE/PCB COMPOUNDS NONE DETECTED I I I l!!!l!!l!!!I !!!!I 1!11!1 Table 4.8 {cont) Temporary \./ell Analytical Data Sunmary General Electric East Flat Rock, North Carolina 1-TW 09/21/94 UG/l UG/l UG/l 2-TW 30-TW 09/21/94 09/22/94 UG/l UG/l 0.59J 0.B0J 0.71J 0.067AJ UG/l UG/l UG/l 31-TW 09/21/94 UG/l UG/l UG/l **************************************************************** ***FOOTNOTES*** J ESTIMATED VALUE N PRESUMPTIVE EVIDENCE OF PRESENCE OF MATERIAL MATERIAL \./AS ANALYZED FOR BUT NOT DETECTED 4-51 iiii 50-TW 51-TW 551-TW 52-TW 09/20/94 09/20/94 09/20/94 09/13/94 UG/l UG/l UG/l UG/l 1. 1 J 1.2J 0.87J 0.98J 0.98J 29 34 1. 1 J UG/l UG/l UG/l UG/l UG/l UG/l UG/l liiil 53-TW 09/21/94 54-TW UG/l UG/l 32 UG/l UG/l 29 N UG/l UG/l - I I I I I I I n D D I • I I I I I I I Well Number TW-1 TW-2 TW-30 TW-3 I TW-50 TW-51 TW-52 TW-53 TW-54 Sample Number GE-001-TW GE-002-TW GE-030-TW GE-031-TW GE-050-TW GE-051-TW GE-052-TW GE-053-TW GE-054-TW Table 4.9 Tempora1y Well Field Parameters General Electric East Flat Rock, North Carolina pH Conductivity Temperature (SU) (umhos/cm) ( C) 5.89 92 18.2 5.91 8.5 I 17 5 5.9 196.4 14.6 5.9 45.8 17.2 6.2 60.5 15.9 6.4 91.2 I 9.2 4.72 20.8 22.7 5.91 53.1 6.1 5.5 258 I 5.2 4-52 GE Superfund Site RI Report Draft May 1995 Turbidity (NTU) 7.39 0.21 0.13 0.11 6.8 6.28 0.15 7.64 1.97 I I I I I I I g D I I I I I I I'esticides_ancLECB~ No pesticides or PCB's were detected in the temporary well samples. Metals GE Superfund Site RI Report Draft May 1995 Metals were detected in all of the temporary well sa111ples. Sample 30-TW contained 0.28 ug/1 of mercury. The MCL for mercury is 2 ug/1. Also, the SMCL for nickel was exceeded in sample 30-TW. The SMCL's for aluminum and iron were exceeded in all the samples including the background sample. The SMCL of 50 ug/1 for manganese was exceeded in all the samples except 2-TW and 52-TW. EielcLEarameters The field parameters of temperature, pH, specific conductance and turbidity were measured. The results are presented in Table 4.9. The pH of the ground water samples were all slightly acidic and ranged between 4.7 SU in sample 52-TW to 6.4 SU in sample 51-TW. The specific conductance ranged from 8.51 umhos/cm in sample 2-TW to 258 umhos/cm in sample 54-TW. The temperatures ranged between 14.6 and 22.7 degrees centrigrade. The turbidity of the samples ranged from 0.11 NTU in sample 31-TW to 7. 64 in sample 53-TW. 4.4 Qn_Siie.J'ermanenLMoniioi:..WelLSampling Twenty four of the existing pennanent monitor wells located on the GE property were sampled. Table 4.10 presents the well construction infonnation and Figure 4.9 indicates their locations. Analytical data are presented in Table 4.11. Field parameters are presented in Table 4.12. Y:olatile_.Or_ganic__Compounds Volatile organic compounds were detected in 21 of the 24 wells sampled. To facilitate the data presentation and discussion, the compounds cis-1,2-dichloroethene, trichloroethene and tetrachloroetheiie -were clicise,i as indicator cimipoiinds. -·Thesecoiiipounds were-·detected a·t the greatest frequency in the wells. Cis-1,2-dichloroethene was detected in 18 wells at concentrations between 0.72] ug/1 in well MW-22A to 380J ug/1 in well MW-I 1. 4-53 I I I I I m I I m u D D D I 1--.. I I I I TABLE4_10 GE Superfund Site RI Repo11 Draft May 1995 ON SITE MONITOR WELL SAMPLE COLLECTION SUMMARY GE PROPERTY EAST FLAT ROCK, NORTH CAROLINA Well Sample Total Screen Northing Number Number Depth Length Number MW-I GE-001-MW 28 5 572045 MW-2 GE-002-MW 24.5 10 571678.6 MW-2A GE-02A-MW 48.3 10 571683 MW-4 GE-004-MW 13.2 10 571354.1 MW-9 GE-009-MW 37.4 10 572093.9 MW-I I GE-01 I-MW 58.5 10 572384.1 MW-12 GE-012-MW 40.5 10 572116.3 MW-12A GE-12A-MW 58 10 572121 MW-12B GE-12B-MW 125 34 572126 MW-14 GE-014-MW 37.3 10 572207.5 MW-14A GE-14A-MW 58.3 16 572212 MW-14B GE-14B-MW I I 0 27 572217 MW-17 GE-017-MW 43 10 572544.3 MW-19 GE-019-MW 42.3 10 572273.6 Total depth and screen length measurements are in feet OH -Open Hole All well casings and screen are constructed of PVC 4-54 Easting Top Of Casing (ft ms!) 982278 2183.33 983044.7 2153.45 983049 2 I 53. I 982724.8 2146.46 - 982369 2177.57 981894.6 2178.76 9S1910.1 2168.96 981915 2 I 68. 77 981920 2168.2 982976.6 2144.63 982981 2144.56 982986 2143.3 982489.7 2182.41 981730.3 2177.86 Depth Water to Water Surface (ft) Elevation 27.7 2 I 55.63 16.78 2136.67 16.24 2136.86 4.25 2142.21 22 2 I 55.57 15.88 2162.88 9.53 2159.43 9.5 2159.27 8.65 2159.55 9.46 2135.17 6.28 2138.28 3.78 2139.52 28.8 2153.61 10.7 2167.16 I I I • I I I I n n D D I I , I I I I I TABLE 4.10 (cont) GE Superfund Site RI Report Draft May 1995 ON SITE MONITOR WELL SAMPLE COLLECTION SUMMARY GE PROPERTY EAST FLAT ROCK, NORTH CAROLINA Well Sample Total Screen Northing Number Number Depth Length MW-21 GE-021-MW 81.8 10 572970.2 MW-22A GE-22A-MW 23 10 573068.3 MW-25 GE-025-MW 41.5 10 571495.7 MW-26 GE-026-MW 57.8 10 571805.3 MW-29 GE-029-MW 41 10 573174.1 MW-30 GE-030-MW 47.5 10 570458.6 MW-30A GE-30A-MW 61.5 10 570463 MW-32 GE-032-MW 16.7 10 571088.5 MW-35 GE-035-MW 18.5 10 572923 MW-38 GE-038-MW 63 20 572828 Total depth and screen length measurements are in feet OH -Open Hole All well casings and screen are constructed of PVC 4-55 Easting Top Of Casing (ft ms!) 981388.1 2177.81 983007.9 2126.3 981426.8 2157.7 981209.4 2173.8 982544.3 2160.16 983162.9 2156.81 983167 2156.24 982306.8 2154.92 981577.7 2183 981503 2i78.03 Depth Water to Water Surface (ft) Elevation 4.26 2173.55 1.85 2124.45 3.6 2154.1 13.3 2160.5 24.8 2135.36 4.9 2151.91 4.5 2151.74 8.33 2146.59 12.18 2170.82 6.93 2171.1 l!!l!!I l!!!!l!I l!!!!I 1!1111!1 liillliil IEliil liiiiil iiiil iiii1 liiiil 0 Table 4.11 Monitor Well Analytical Data SuTTJTiary General Electric East Flat Rock, North Carolina l·MW 2-MW 2A·MW 4-MW 9-MW 11-MW 12-MW 12A·MW 12B·MW 14-MW 14A-MW 14B·MW 09/21/94 09/15/94 09/15/94 09/21/94 09/15/94 09/15/94 09/15/94 09/15/94 09/15/94 09/14/94 09/14/94 09/14/94 INORGANIC ELEMENTS UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L BARIUM 40 30 5.6 55 87 270 190 230 66 41 7.4 620 COBALT 4.0 4.8 CHROMIUM 4.8 COPPER 2.1 18 3.6 8.3 110 MOLYBDENUM 25 LEAD 8.0 15 STRONTIUM 10 7.3 260 190 29 560 470 590 530 72 110 8000 TITANIUM 26 4.7 17 7.0 6.8 7.8 15 29 ZINC 29 3.2 8.0 8.6 12 28 8.9 9. 1 3. 1 7 .0 MERCURY 0.22 0.22 0.62 ALUMINUM 1200 87 210 59 260 91 99 170 520 1300 MANGANESE 37 120 87 770 81 67 65 30 40 810 49 MG/l MG/L MG/L MG/L MG/L MG/L MG/l MG/L MG/L MG/L. MG/L MG/L CALCIUM 1.9 1.9 32 6.5 2.9 74 65 79 44 7.0 12 260 MAGNESIUM 1 .3 ,. 1 3.0 1. 8 2.0 35 39 44 12 2. 1 3.2 0.26 IRON 0.44 0.17 0.20 0.42 0.36 2.3 0.12 SOD !UM 1.9 4.3 8.3 37 4.8 16 14 16 9.6 6.3 4.7 25 POTASSIUM 0.60 3.3 2.2 1.0 4.7 4.2 7.3 4.9 ,. 1 2.7 21 **************************************************************** ***FOOTNOTES*** ESTIMATED VALUE ' -MATERIAL WAS ANALYZED FOR BUT NOT DETECTED 4-57 l!!l!I -== liiiiill liiil llilil liiii1 iiiil liiiil Table 4.11 {cont) Monitor Well" Analytical Data Surrrnary General Electric East Flat Rock, North Carolina 1-MW 2-MW 2A-MW 4-MW 9-MW 11-MW 12-MW 12A-MW 128-MW 14-MW 14A-MW 148-MW 09/21/94 09/15/94 09/15/94 09/21/94 09/15/94 09/15/94 09/15/94 09/15/94 09/15/94 09/14/94 09/14/94 09/14/94 PURGEABLE ORGANIC COMPOUNDS UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L VINYL CHLORIDE 2.BJ 0.69AJ CIS-1,2-DICHLOROETHENE 210 0.91J 2.BJ 11 J 140 380J 160J 150 16 43J 17 3.5AJ TRANS-1,2-DICHLOROETHENE 33J 14J 1.9J 1 .6J 1,2-0ICHLOROETHANE 4.0J 63J 130J 130 15J 2.0J 6.3A 1,2-DJCHLOROPROPANE o_53J TRICHLOROETHENE{TRICHLOROETHYLENE) 60 0.94J 0.98J 18J 71J 34J 29J 4.0J 130 24 3.2AJ TETRACHLOROETHENE(TETRACHLOROETHYLENE) 160 4.3J 2.8J 75 410 1600 1200 1200 67 380 180 11A 1,2,3-TRICHLOROBENZENE 13J 2.9J EXTRACTABLE ORGANIC COMPOUNDS UG/l UG/L UG/L UG/L UG/L UG/l UG/L UG/L UG/L UG/L UG/L UG/L 2-METHYLNAPHTHALENE 1.8J 5. 1 J 1,2,4-TRICHLOROBENZENE 3.2J 3.0J 3.2J NAPHTHALENE 4. 7J 37 2.BJ DIBENZOFURAN 2.3J FLUORENE 1. 1 J PHENANTHRENE 1.3J PHENOL 2.3J 2,4-DINITROPHENOL 3.3J TRI(CHLOROETHANOL)PHOSPHATE 40JN TRICHLOROBENZENE (NOT 1,2,4-) 20JN (METHOXYMETHYLETHOXY)PROPANOL 10JN (METHOXYMETHYLETHOXY)PROPANOL (2 I SOMERS) 30JN TETRACHLOROBENZENE 10JN lOJN 1 UNJDENTIFIED COMPOUND 20J METHYLNITROSOPRDPANAMINE 30JN BENZOIC ACID lOJ TRIETHYLENE GLYCOL 60JN HYDRDXYMETHOXYBENZALDEHYDE 60JN PETROLEUM PRODUCT N t, PESTICIDE/PCB COMPOUNDS UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/l UG/L NONE DETECTED **************************************************************** ***FOOTNOTES*** A AVERAGE VALUE J ESTIMATED VALUE N PRESUMPTIVE EVIDENCE OF PRESENCE OF MATERIAL MATERIAL ~AS ANALYZED FOR BUT NOT DETECTED 4-58 !11!1 == == 111111'1 lliiiil liiiiiil 1111111 lliiiiiil liiiil iiiiil iiii liiil Table 4.11 (cont) Monitor Well Analytical Data Surrmary General Electric East Flat Rock, North Carolina 17-MW 19-MW 21-MW 22A-MW 25-MW 26-MW 29-MW 30-MW 30A-MW 32-MW 09/15/94 09/14/94 09/14/94 09/22/94 09/14/94 09/14/94 09/15/94 09/14/94 09/14/94 09/15/94 INORGANIC ELEMENTS UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L BARIUM 58 84 120 14 34 40 110 11 4_2 25 CADMIUM 1.3 COBALT 2.4 4.8 3.0 CHROMIUM 6. 1 17 2.2 7.3 COPPER 6.9 7.6 16 7.0 31 NICKEL 7.7 LEAD 8.9 TIN 16 STRONTIUM 12 230 33 9.8 44 140 440 21 29 22 TITANIUM 20 41 1100 14 98 6. 1 VANADIUM 24 3.0 YTTRIUM 3.6 ZINC 14 32 66 4.6 2.4 13 48 ALUMINUM 870 980 15000 250 4200 170 180 MANGANESE 280 160 440 5.2 12 8.5 88 4.9 MG/L MG/L MG/L MG/L MG/L MG/l MG/L MG/L MG/L MG/L CALCIUM 1.2 34 4.4 ,. 2 6.4 24 6.0 3.1 5.5 2.0 MAGNESIUM 1.0 22 6.4 0.81 4.4 11 1.6 0.66 1.5 0.90 IRON 0.40 18 0. 016 0.29 2.3 0.021 0. 10 SOOIUM 2.2 11 8.1 2.5 4. 1 11 3.0 4.3 6.2 3. 1 POTASSIUM 0.92 2.3 7.6 0.46 1.4 2.5 2.6 0.54 2.2 0.59 **************************************************************** *** f:_1QTNOTES*** ESTIMATED VALUE -MATERIAL WAS ANALYZED FOR BUT nor DETECTED 4-59 iiiil &ill iiiiil liiiiiil liiil liiiiil liiiii iiiil liliiiiiiil iiiilil iiiil iiiil iiiil liiiiil iiiil - Table 4.11 (cont) Mani tor Welt Analytical Data Surrrnary General Electric East Flat Rock, North Carolina 17-MW 19-MW 21-MW 22A·MW 25-MW 26-MW 29-MW 30-MW 30A·MW 32-MW 09/15/94 09/14/94 09/14/94 09/22/94 09/14/94 09/14/94 09/15/94 09/14/94 09/14/94 09/15/94 PURGEABLE ORGANIC COMPOUNDS UG/L UG/l UG/L UG/L UG/L UG/L UG/L UG/L UG/L UG/L CHLOROMETHANE 0.64J 1, 1·DICHLOROETHENE(1, 1-DICHLOROETHYLENE) 0.79J 1,1-DICHLOROETHANE 0.82J CIS-1,2-DICHLORDETHENE 0.86AJ 28 0. 72J 3. 1 J 10 TRANS-1,2-DICHLOROETHENE 0.80J CHLOROFORM 9.4 1,2-DICHLOROETHANE 0.60AJ 24 1, 1, 1-TRICHLOROETHANE 1.8J 2.0J BROMODICHLOROMETHANE 0.66J TRICHLOROETHENE(TRICHLOROETHYLENE) 7.3 0.93J 2.9J 16 BENZENE 2.?J TETRACHLOROETHENE(TETRACHLOROETHYLENE) 34A 290 1.5J 73A 120 29 3.6AJ TOLUENE 0.88AJ 0.60AJ 0-XYLENE 0.76J 1,2,4-TRICHLOROBENZENE 0.53J 1,2,3-TRICHLOROBENZENE 1. 7 J EXTRACTABLE ORGANIC COMPOUNDS UG/l UG/l UG/l UG/l UG/l UG/l UG/L UG/L UG/l UG/L [(METHOXYMETHYLETHOXY)METHYLETHOXYJPROPANOL 10JN (METHOXYMETHYLETHOXY)PROPANOL 20JN PESTICIDE/PCB COMPOUNDS UG/l UG/L UG/L UG/l UG/L UG/l UG/L UG/L UG/l UG/L NONE DETECTED **************************************************************** ***FOOTNOTES*** A AVERAGE VALUE J EST !MATED VALUE N PRESUMPTIVE EVIDENCE OF PRESENCE OF MATERIAL MATERIAL WAS ANALYZED FOR BU/ NOT DETECTED 4-60 I I I I I I I u I I I I I I I I I INORGANIC ELEMENTS BARIUM BERYLLIUM COBALT NICKEL STRONT !UM TITANIUM YTTR !UM ZINC MERCURY ALUM! NUM MANGANESE CALCIUM MAGNESIUM IRON SOD !UM POTASSIUM Table 4.11 (cont) Monitor Well Analytical Data Surmiary General Electric East Flat Rock, North Carolina 35-MW 09/14/94 1615 UG/L 28 160 7.3 0.26 120 1400 MG/L 74 14 2.2 1.4 38-MW 09/15/94 1110 UG/L 4000 15 31 19 590 25 18 120 1300 5000 MG/L 47 82 0.50 100 13 430-MWA 09/14/94 1130 UG/L 4. 7 29 MG/L 5 .3 1.4 5.9 1.5 **************************************************************** ***FOOTNOTES*** · MATERIAL WAS ANALY2EO FOR BUT NOT DETECTED 4-61 I I I I I n D R I I I I I •- I I I I Table 4.11 (cont) Monitor Well Analytical Data SuIDnary General Electric East Flat Rock, North Carolina PURGEABLE ORGANIC COMPOUNDS VINYL CHLORIDE METHYLENE CHLORIDE CIS-1,2-DICHLOROETHENE TRANS-1,2-DICHLOROETHENE CHLOROFORM 1,2-DICHLOROETHANE BROMODICHLOROMETHANE TRICHLOROETHENE(TRICHLOROETHYLENE) BENZENE TETRACHLOROETHENE(TETRACHLOROETHYLENE) ETHYL BENZENE (M-AND/OR P-)XYLENE 0-XYLENE 1,4-DICHLOROBENZENE 1,2,4-TRIMETHYLBENZENE 1,2,4-TRICHLOROBENZENE EXTRACTABLE ORGANIC COMPOUNDS NI TROBENZENE 2-NITROPHENOL 2,4-DINITROPHENOL 4-NITROPHENOL (METHYOXYMETHYLETHDXY)PROPANOL (4 ISOMERS) METHYLNITROBENZENE PHENOXYETHANOL [(METHOXYMETHYLETHOXY)METHYLETHOXYJPROPANOL BUTOXYETHANOL PHENOXYACETIC ACID PHENOXYPROPANOIC ACID METHYLBENZOPYRANONE ETHYLMETHYLBENZENAMINE 1 UNIDENTIFIED COMPOUND PESTICIDE/PCB COMPOUNDS NONE DETECTED 35-MW 09/14/94 UG/L UG/L UG/L 38-MW 430-MWA 09/15/94 09/14/94 UG/L 2.4J 5. 1 56J 0.75J 6.6 5.7 0.64J 21 0.52J 370 0. 78J 3.SJ 2.7J 0.83J O.SOJ 0.99J UG/L 36 9.2J 10J 45 60JN 70JN 7DJN SOJN 20JN 20JN 20JN 10JN 20JN 60J UG/L UG/L UG/L UG/L **************************************************************** ***FOOTNOTES*** J -ESTIMATED VALUE N -PRESUMPTIVE EVIDENCE OF PRESENCE OF MATERIAL -.MATERIAL WAS ANALYZED FOR BUT NOT DETECTED 4-62 I I I ,1 I I • I I I I I D D I I • I I Well Number MW-I MW-2 MW-2A l\1W-4 MW-9 MW-II MW-12 MW-l2A MW-l2B MW-14 M\V-14A MW-l4B MW-17 Sample Number GE-001-MW GE-002-MW GE-02A-MW GE-004-MW GE-009-MW GE-011-MW GE-012-MW GE-l2A-MW GE-12B-MW GE-014-tvfW GE-l4A-MW GE-14B-MW GE-017-MW Table 4.12 Monitor Well Field parameters General Electric East Flat Rock, North Carolina pH Conductivity (SU) (umhos/cm) 5.85 35 5.56 50 8.06 225 5.82 250 5.3 63 5.7 874 5.76 849 5.89 1024 7.56 373 6.4 100 6.6 I I 5 12.2 3000 5.6 35 4-63 GE Superfund Site Rl Report Draft May I 995 Temperature Turbidity ( C) (NTU) 16.9 0.07 15.8 0.03 I 5. I 0.03 I 6.1 0.04 20.2 0.05 18.7 0.02 18 0.02 17.7 0.03 17.8 0.8 15.9 0.01 15.9 0.07 15.4 0.05 154 0.03 I I I • I I I u e I I I I I •• I I I I Well Number MW-19 MW-21 MW-22A MW-25 MW-26 MW-29 MW-30 MW-JOA MW-32 MW-35 MW-38 Sample. Number GE-019-MW GE-021-M\V GE-22A-MW GE-025-MW GE-026-MW GE-029-MW GE-030-l'VIW GE-30A-lv!W GE-032-MW GE-035-MW GE-038-MW Table 4.12 (cont) Monitor Well Field parameters General Electric East Flat Rock, North Carolina pH Conductivity (SU) (umhos/cm) 6.2 444 7. l l 70 5.59 30 5.8 12 l 6.l 280 5.5 36 6.4 50 6.9 74 5.5 42.3 6.8 280 5 1670 4-64 GE Superfuncl Site RI Report Draft May 1995 Temperature Turbidity ( C) (NTU) 20.4 - 19.l 5.2 14.4 0.02 18.6 0.02 l 6.8 0.06 l 5.1 16 0.02 14.8 0.04 16.4 21.l 0.03 20.5 0.64 I I I I I I g I I I I I D I I I GE Superfund Site RI Report Draft May 1995 Trichloroethene was detected in 16 wells at concentrations between 0. 93J ug/1 in well 22A- MW to 130 ug/1 in well 14-MW. Tetrachloroethene was detected in 20 wells at concentrations between 1.51 ug/1 in well 21-MW and 1,600 ug/1 in well 11-MW. Concentration isopleth maps for these compounds were developed using an exponential kriging algorithm and Golden Software's SURFER modeling program. A concentration of 0.05 ug/1 was used in the model for samples in which cis-1,2-dichloroethene, trichloroethene and tetrachloroethene were reported as not detected. These maps visually delineate the horizontal and vertical extent of contamination in the ground water under the site. All the wells sampled are screened in the surficial aquifer underlying the site. In order to better define the vertical extent of contamination underlying the site, the wells were divided into two groups based on the total depth of the well. One group, labeled shallow wells, contains the wells 50 feet or less deep. The other group, labeled deep wells, contains those greater than 50 feet deep. The well depths are presented in Table 4-13. The results are presented as Figures 4.10, through 4. 15. Figures 4.16 and 4.17 present the isopleth maps for the total volatile organic compound concentration detected in each well. This number was de1ived by summing the concentrations of all volatile.organic compounds detected in a well. As indicated on the Figures, the area with the highest contamination lies along the drain line/fom1er ditch in the vicinity of wells MW-11, MW-12, MW-12A and MW-12B. The total VOC concentration in the shallow and deep wells in this area is roughly equivalent. The concentration gradient drops gradually toward the northeast, which is the direction of ground water flow, and more abmptly to the northwest and southeast. · Monitor well MW-14 contained high concentrations of all three compounds. This well is east- northeast of the fonner leaking underground storage tank located between the railroad track and the northwest side of the warehouse. 4-65 I I I I I I I I I I D u •- I CJ L ~ I -400 0 400 SCALE IN FEET GE PROPERTY ON SITE MONITOR WELL LOCATIONS FIGURE 4.9 I : ~En,. ~A. GENERAL ELECTRIC suPERFuNo s1TE ~ ~ Fez\ EAST FLAT ROCK, NORTH CAROLINA ·~L-------------L----.J I I I I I I I I I I D D I I I I I i . - -400 0 400 ~'====~=~ SCALE IN FEET ND -NOT DETECTED CIS-1,2-DICHLOROETHENE SHALLOW WELL ISOPLETH _JL FIGURE 4.10 I a EnA GENERAL ELECTRIc suPERFuNo sITE i ~ _ lf""".fi-\ EAST FLAT ROCK, NORTH CAROLINA I ~'--------------------------------L------~ I I I I I I D I 0 I I I I I I I I i -400 0 400 E==!!'!:liiiiE!Eii~=~ SCALE IN FEET ND -NOT DETECTED CIS-1,2-DICHLOROETHENE DEEP WELL ISOPLETH FIGURE 4.11 I a EnA GENERAL ELEcTRIc suPERFuNo sITE ~ ~ lf"'K EAST FLAT ROCK, NORTH CAROLINA I i,.._ ______________________________ ...... ______ ..J I I I g D I I I I I I I I I i -400 ~=~~miiii!~ 0 400 SCALE IN FEET ND -NOT DETECTED .---::::.=:~-=------\ •, TRICHLOROETHENE SHALLOW WELL ISOPLETH I I 11 ~EPA GENERAL ELECTRIC SUPERFUND SITE EAST FLAT ROCK, NORTH CAROLINA FIGURE 4.12 I I I I I I i I D I I I I I I SCALE IN FEIT ND -NOT DETECTED I I ~&EPA TRICHLOROETHENE DEEP WELL ISOPLETH GENERAL ELECTRIC SUPERFUND SITE EAST FLAT ROCK, NORTH CAROLINA JL. FIGURE 4.13 I~ oL------------------------------------'-------....1 I I I I I I I I I I n D D I I I TW- t-fn i -400 0 400 E'!!='!"SiiiE:liiii~miiiiil"""!!!'I SCALE IN FEET ND -NOT DETECTED TETRACHLOROETHENE SHALLOW WELL ISOPLETH ~-----------------------1 FIGURE 4.14 I 11 &EPA GENERAL ELECTRIC SUPERFUND SITE EAST FLAT ROCK, NORTH CAROLINA I I I I I n I g D D R I i -400 0 400 ~~E!!!!iiil~=~ SCALE IN FEET ND -NOT .DETECTED TETRACHLOROETHENE DEEP WELL ISOPLETH _IL_ FIGURE 4.15 I! ~EPA c,;~~R~~~L~g~~~ Nsi:,~R~A~~LT~'; I~ ..... __________________________________ .._ ______ _. I I I I a n I D H I I I I i -400 ---------0 -400 ~~l!!!!liii~=~ SCALE IN FEET ND -NOT DETECTED -30, 00-CONCENTRATIONS IN ug/1 &EPA TOTAL voe SHALLOW WELL ISOPLETH GENERAL ELECTRIC SUPERFUND SITE EAST FLAT ROCK, NORTH CAROLINA ,00 FIGURE 4.16 I I I I I • I I a I n D I D R I SCALE IN FEET ND -NOT DETECTED TOTAL voe DEEP WELL ISOPLETH :1&EPA GENERAL ELECTRIC SUPERFUND SITE EAST FLAT ROCK, NORTH CAROLINA FIGURE 4.17 I I I I I I I I I I I I I I I I GE Superfi.md Site RI Report Draft May 1995 Two individual compounds detected which merit discussion are benzene and vinyl chloride. Benzene was detected in well 19-MW at a concentration of 2.71 ug/1 and in well 38-MW at a concentration of 0.521 ug/1. Vinyl chloride was detected in wells 4-MW, 14B-IvIW and 38- MW at concentrations of 2.81 ug/1, 0.69AJ ug/1 and 2.4J ug/1, respectively. Vinyl chloride is a degradation product of tetrachloroethene. Extractable Organic Compounds Extractable organic compounds were detected in five samples. Three additional samples contained the presumptive evidence of extractable organic compounds. Sample I I-MW contained I.SJ ug/1 of 2-methyl naphthalene, 3.21 ug/1 of 1,2,4-trichlorobenzene, 4.7J ug/1 of naphthalene and 3.31 ug/1 of 2,4-dinitrophenol. Sample 12-MW contained 5. IJ ug/1 of 2- methyl naphthalene, 3.0J ug/1 of 1,2,4-trichlorobenzene, 371 ug/1 of naphthalene, 2.31 ug/1 of dibenzofuran, J. IJ ug/1 of fluorene, 1.31 ug/1 of phenanthrene and the presumptive evidence of two compounds. Sample 12A-MW contained 3.2J ug/1 of 1,2,4-trichlorobenzene, 2.81 ug/1 of naphthalene, one unidentified compound and the presumptive evidence of two compounds. Sample 14B-MW contained 2.31 ug/1 of phenol, !OJ ug/1 of benzoic acid and the presumptive evidence of three compounds and petroleum product. Sample 38-MW contained 36 ug/1 of nitrobenzene, 9.21 ug/1 of 2-nitrophenol, !OJ ug/1 of 2,4-dinitrophenol, 45 ug/1 of 4- nitrophenol, one unidentified compound and the presumptive evidence of nine compounds. samples2A-MW, 9-MW and 19-MW contained only the presumptive evidence of extractable organic compounds. Four of the monitor wells in which extractable organic compounds were detected are along the drain line/fonner ditch. Several of the compounds detected in the well samples were also detected in the drain line/fonner ditch soil samples. The fifth well in which extractable organic compounds were detected, well 14B-MW, contained two compounds and the · presumptive evidence of three others. None of these compounds were detected in any other well sample. £esticides_and_.E.CB..'.s No pesticides· or PCB's were detected in-the monitor well sa,ii"ples: Metals Metals were detected in all of the monitor well samples. Primary MCL's for barium and berytlium were exceeded in sample 38-MW, which contained 4,000 ug/1 of barium and 15 ug/1 of 4-74 I I I I I I u D I I I I I I I I I GE Superfund Site RI Report Draft May 1995 beryllium. The MCL's are 2,000 ug/1 and 4 ug/1, respectively. Secondary MCL's for aluminum, manganese, and calcium were exceeded in one or more samples. Aluminum was detected in nineteen samples and ranged in concentration from 59 ug/1 in sample 4-MW to 15,000 ug/1 in sample 21-MW. The secondary MCL for aluminum is 50 -200 ug/L Eleven of the samples contained aluminum at a concentration above 200 ug/L Maganese was detected in 21 samples at concentai1ions ranging between 4.9 ug/1 in sample 32-MW to 5,000 ug/1 in sample 38-MW. Thirteen samples contained concentrations above the secondary MCL of 50 ug/L Iron was detected in 15 samples. The secondary MCL of 0.3 mg/I was exceeded in eight samples. Mercury was detected in samples 4-MW, 12-MW, 14-MW and 35-MW, at a concentrations ranging between of 0.22 ug/1 and 0.62 ug/L The MCL for mercury is 2 ug/L Field Parameters The field parameters of temperature, pH, specific conductance and turbidity were measured. The results are presented in Table 4.12. The pH of the ground water samples ranged from slightly acidic to slightly basic, with the exception of sample 14B-MW which had a pH of 12.2. The reason for this high pH is unknown; however it may be due to leaching of the cement grout due in part to improper well construction. The specific conductance ranged from 30 umhos/cm in sample 22A-MW to 3000 umhos/cm in sample l 4B-MW. In general the specific conductance was less than 500 umhos/cm in the wells. The temperatures ranged between 14.4 and 20.4 degrees centigrade. The turbidity of the samples was less than 0.1 NTU with the exception of sample 21-tvIW which had a turbidity of5.2 NTU and sample 12B-MW which had a turbidity of 0.8 NTU. Potentiometric Surface Map Table 4.13 presents the ground water elevations measured during this investigation. A , potentiometric surface map was developed using this data and is presented as Figure 4.18. In general the ground water flows to the northeast with some mounding under the main building. 4.5 Potable Well Sampling · Eleven potable wells were sampled during this investigation. Table 4, 14 presents owner's name and the well construction infonnation, if available, and Figure 4. 19 indicates the well locations. Analytical results are presented in Table 4.15. Sample 469-PW is a duplicate of sample 69-PW. 4-75 I I I I I u D u I I I I I I I I I I I Well Number MW-I MW-2 MW-2A MW-4 MW-9 MW-II MW-12 MW-12A MW-12B MW-14 MW-l4A MW-14B MW-17 MW-19 MW-21 MW-22A - MW-25 Table 4.13 GE Superfund Site RI Report Draft May 1995 Permanent Monitor Well Ground Water Elevation Survey General Electric, East Flat Rock, North Caroliiia Sample Total Screen Top of casing Depth to Water Number Depth (ft) Length (ft msl) Water (ft) Surface Elevation GE-001-MW 28 5 2183.33 27.7 2155.63 GE-002-MW 24.5 10 2153.45 1678 2136.67 GE-02A-MW 48.3 10 2153.1 16.24 2136.86 GE-004-MW 13.2 10 2146.46 4.25 2142.21 GE-009-MW 37.4 10 2177.57 22 2155.57 GE-01 I-MW 58.5 10 2178.76 15.88 2162.88 GE-012-MW 40.5 10 2168.96 9.53 2 I 59.43 GE-l2A-MW 58 10 2168.77 9.5 2159.27 GE-l2B-MW 125 34 2168.2 8.65 2159.55 GE-014-MW 373 10 2144.63 9.46 2135. I 7 GE-l4A-M\V 58.3 16 2144.56 6.28 2138.28 GE-l4B-MW I I 0 27 2143.3 3.78 2139.52 GE-017-MW 43 10 2182.41 28.8 2153.61 GE-019-MW 42.3 10 2177.86 10.7 2167.16 GE-021-MW 81:8 10 2177.81 4.26 2173.55 GE-22A-MW. 23 I 0-· ·-·2126.3 .. 1.85 -2124.-45 --. GE-025-MW 41.5 10 2157.7 3.6 2154.1 4-76 I I m I I g u R 6 m I I I I I I I I I Well Number MW-26 MW-29 MW-30 MW-30A MW-32 MW-35 MW-38 Table 4.13 (cont) GE Superfund Site RI Report Draft May 1995 Permanent Monitor Well Ground Water Elevation Survey General Electric, East Flat Rock, North Carolina Sample Total Screen Top of casing Depth to Water Number Depth Length (ft ms!) Water (ft) Surface (ft) Elevation GE-026-MW 57.8 IO 2173.8 13.3 2160.5 GE-029-MW 41 10 2160.16 14 8 . t .:.-_ • • 2135.36 GE-030-MW 47.5 10 2156.81 4.9 2151.91 GE-30A-MW 61.5 10 2156.24 4.5 2151.74 GE-032-MW 16.7 10 2154.92 8.33 2146.59 GE-035-MW 18.5 10 2183 12.18 2170.82 GE-038-MW 63 20 2178.03 6.93 2171.1 4-77 I I I I I I H D I I I I I I I I I I I I ---l --- i -400 0 400 ~!"'5.i,~-;;;;;;;;;;.'!~ SCALE IN FEET ND -NOT DETECTED -30, 00-WATER TABLE ELEVATIONS GE PROPERTY POTENTIOMETRIC SURFACE MAP ~-----------------------1 FIGURE 4.20 ~EPA GENERAL ELECTRIC SUPERFUND SITE EAST FLAT ROCK, NORTH CAROLINA I I I I I H u I I I I I I I I I I I I I - 2 - * TABLE4.14 GE Superfund Site RI Report Draft May 1995 GENERAL ELECTRIC SITE POT ABLE WELL SAi\1PLES RESIDENTIAL NAMES AND ADDRESSES EAST FLAT ROCK, NORTH CAROLINA Saml)le Number Owner Address' PW-83 Mr. Joseph Stepp I st Av PW-73 Mr. L Frisbee 143A Oak Grove Rd PW-33 Mr. Herman Barnett I 15 Barncrr·St PW-75 Mr. Heaton 603 Oak Grove Rd PW-23 Mr. Harold Barton 712 Tabor Rd PW-91 Mr. D. Jackson 108 S King St PW-69 Mr. B. Morgan 453 Oak Grove Rd PW-22 Mr. Dimsdale I I 6 Fork Creek * PW-15 Mr. l T. Lively 404 Tabor Rd * PW-6 Mr. D. Capps 521 Paradise Av * PW-43 Mr. M. Gardner 5 I I Oak Grove Rd. The city for all residences is East Flat Rock. The Dimsdale's do not drink the water but use it for all other purposes -Do Not use the well for potable water. 4-79 I I a I I D I I I I I I I I I I I ,-: VJ e .,., N 0 .,., ..,. ~ ~ ft 8 ~ .,.,o .,., il ~-c, ~ Ill -~ POTABLE WELL LOCATIONS 21 --------------------~FIGURE 4.-1- I; ~EPA GENERAL ELECTRIC SUPERFUND SITE EAST FLAT ROCK, NORTH CAROLINA ·-.__ _________________________ ___,__ ____ __J I Potable East MCL SMCL PW-2 PW-83 PW-15 Dimsdale Stepp Lively INORGANIC ELEMENTS UG/l UG/L UG/l UG/l UG/L BARIUM 2000 66 12 6.3 BERYLLIUM 4 CAOMIUM 5 CHROMIUM 100 2.4 COPPER TT 12 38 5.8 STRONTIUM 46 48 36 TITANIUM 18 17 VANADIUM 6.9 MG/l, MG/l MG/L MG/l MG/l CALCIUM 4. 1 5.8 7. 1 SODIUM 4.6 4.5 6.5 POTASSIUM 1.2 1.7 2.5 PURGEABLE ORGANIC COMPOUNDS UG/l UG/L UG/l UG/l UG/L 1, 1,1-TRICHLOROETHANE 200 TETRACHLOROETHENE 5 1. 1J **************************************************************** ***FOOTNOTES FOR COLUMNS 1 AND 2*** MCL Safe Drinking Water Act Maximum Contaminant Level SMCL Safe Drinking Water Act Secondary Maximum Contaminant Level TT Treatment Technology Based level The Action Level For Lead Is 15 ug/l No MCL or SMCL Specified 1 ' ***FOOTNOTES FOR COLUMNS 2 THROUGH 14*** J · ESTIMATED VALUE MATERIAL WAS ANALYZED FOR BUT NOT DETECTED : · Sample PW·469 is a duplicate of sample PW·69 Tabte4.15 Wet t Analytical Data Sulllllary Flat Rock, North Carolina PW-73 PW-33 PW-75 Frisbee Barnett Heaton UG/l UG/l UG/l 43 7.7 5.1 2.2 64 55 25 40 28 40 MG/l MG/l MG/l 11 5. 1 4.0 1. 0 2.2 5.4 6.4 0.68 2.0 0.41 UG/l UG/L UG/l 4-8 I I!!!!!! !!!!I l!!l!I 1111111:1 liliiil liliiil lilliil -- PW-23 PW-91 PW-69 Barton Jackson Morgan UG/l UG/l UG/l 16 18 55 19 120 23 45 61 28 3.1 MG/L MG/l MG/l 4.6 5.9 1.8 7 4.7 4.8 2.5 0.81 2.0 0. 71 UG/l UG/L UG/L 0.58J - - - PW·4692 PW-6 Capps UG/l UG/L 54 39 21 41 27 42 MG/l MG/L 1.8 5.6 2.4 9.0 0.90 1.3 UG/l UG/L - - PW-43 Gardner UG/l 590 1. 1 16 60 47 MG/L 7.7 2.7 UG/l - - I I I I I I I I I I I I I I I I I I YQlatikDJ:gani_c....C.o.mp_Qunds GE Superfund Site RI Report Draft May 1995 Volatile organic compounds were detected in two samples. Sample 83-P contained I. lJ ug/1 of tetrachloroethene and sample 91-PW contained 0.58J ug/l of I, I, I-trichloroethane. Neither of these concentrations are above their respective MCL's. Extractable...Organic...Cornµow1ds No extractable organic compounds were detected in the potable well samples. :ees.ti c i des_ancl..E.CB.'.s No pesticides or PCB' s were detected in the potable well samples. Metals A variety of metals was detected in all of the potable well samples. Samples 73-PW and 91- PW contained 24 ug/l and 19 ug/1 of lead, respectively. Sample 9i--PW contained 550 ug/1 of zinc. The SMCL for zinc is 500 ug/1. Six samples contained aluminum. Samples 83-PW, 15-PW and 43-PW were above 200 ug/1. Samples 73-PW and 91-PW were above 50 ug/1. The SMCL for aluminum is 50-200 ug/1. The SMCL of 50 ug/1 for manganese was exceeded in samples 2-PW, 15-PW, 6-PW and 43-PW. The SMCL of 0.3 mg/I for iron was exceeded in samples 83-PW, 15-PW, and 6-PW. Field Parameters The field parameters of temperature, pH, specific conductance and turbidity were measured. · The results are presented in Table 4.16. The pH of the well samples ranged from acidic, 4.7 SU in well PW-43, to basic, 8.7 in well PW-23. The specific conductance ranged from <20 umhos/cm in well PW-83 to 149.8 umhos/cm in well PW-43. The temperatures ranged between 14.7 and 19.7 degrees centigrade. -The turbidity in five of the wells was ,neasured and ranged between 0.03NTU aiid 0.18 NTU. 4-82 I I • I I H R I m I I I I I I. I I I I Well Sample Number Number PW-2 GE-002-PW PW-6 GE-006-PW PW-15 GE-015-PW PW-23 GE-023-PW PW-33 GE-033-PW PW-43 GE-043-PW PW-69 GE-069-PW PW-73 GE-073-PW PW-75 GE-075-PW PW-83 GE-083-PW PW-91 GE-091-PW nm -Not measured Table 4.16 Potable Well Field Parameters General Electric East Flat Rock, North Carolina pH Conductivity (SU) (umhos/cm) 5.9 70 5.5 112.9 7.1 100 8.7 71.4 6.4 87.5 4.7 149.8 5.9 37.4 6.1 104.5 6.8 69.1 6.8 <20 6.4 91 4-83 GE Superfund Site RI Report Draft May 1995 Temperature Turbidity ( C) (NTU) 17.5 nm 153 0.18 16.7 nm 19.7 11111 16.8 0.03 14.7 0.03 I 6.5 0.03 17.2 nm I 8.6 0.03 14.9 nm 15.2 nm I I I I I I I I I I I I I I I 6 4 4 WELL SURVEY In July and August 1994, EPA mailed out 990 private well/water use surveys to residents living within a one-mile radius of the GE plant subsite. Approximately 109 or 11% were returned by the post office for various reasons (person moved, no forwarding address, post office box closed, etc). Only 309 residents, or 35% of residents who received the survey, completed the questionnaire, and returned it. to EPA. Of those, 224, or 72.5% were currently receiving city water. Eighty-five (85) of those responding to the survey or 27.5% indicated that they were currently using their well for drinking or other household purposes. I D I D I I I I I I I I I I I I I GE/Shepherd Fam1 NPL Site Remedial Investigation Report Draft/ May 1995 5.0 CONTAMINANT FATE AND TRANSPORT An evaluation of the environmental fate and transport of site-related contaminants is important in determining the potential for exposure to the contaminants. There are several mechanisms by which contaminants may migrate. Migration into air can occur via volatilization or dust generation. Migration into groundwater can occur by percolation of infiltrating rainwater or groundwater flow through waste materials or contaminated soils. Transport to streams in the area can occur via surface water runoff and through groundwater discharge. The mechanisms of migration for the main contaminants detected at the site (VOCs for groundwater and PCBs for soil) are discussed below. 5.1 CONTAMINANT MIGRATION 5.1.1 AIR MIGRATION Generally, volatilization from soil and/or water into air may be an important transport mechanism for the organic chemicals with Henry's Law Constants greater than 10·5 ,atm-m3/mole and the molecular weights less than 200 g/mole. The volatile organics detected in groundwater at the site meet these criteria, and therefore, if groundwater is brought to the surface, volatilization of these chemicals of concern could be an important release mechanism. However, even though the PCBs detected in the surface soils meet one of these criteria, PCBs in the environment are usually associated with particulate matter, and do not enter the gaseous phase. For this reason, volatilization is not expected to be an important release mechanism for the organic chemicals at the site. Fugitive dust emissions from wind or mechanical disturbances may occur from unpaved or unvegetated areas of the site. The environmental factors that influence wind erosion are wind speed, moisture content, vegetative cover, and soil composition. Because the environmental factors at this site are at times and places conducive to wind erosion, each of the chemicals detected in surface soil is susceptible to-migration via fugitive· dust genera-tio1i. ·· · 5-l I I I I I I I I I I I I I I I I 5.1.2 SURF ACE WATER MIGRATION GE/Shepherd Farm NPL Site Remedial Investigation Report Draft/ May 1995 Contaminant migration into swface waters at the site may occur through swface water runoff and/or through groundwater discharge. Upon reaching swface water, the contaminants may remain in the water column, volatilize, or sorb to bottom or suspended sediments. Volatile organic contaminants tend to quickly volatilize into the atmosphere upon reaching surface water and for this reason are rarely observed at detectable concentrations in surface water samples. However, volatile organics were found in some of the swface water samples, though at concentrations much lower than was found in the groundwater. The semi-volatile organics with low water solubilities such as the PCBs, will tend to associate with sediments. PCBs were detected in sediments collected from Bat Fork Creek, therefore evidence exists that surface water migration is occurring. 5.1.3 SOIL MIGRATION ·contaminants present in surface and subsurface soils may leach to the underlying aquifer. Many factors influence the rate of contaminant movement through soils. These include the physical/chemical properties of the contaminants (e.g., solubility, density, viscosity), and the physicaVchemical properties of the environment (e.g. rainfall percolation rate, soil permeability, porosity, particle size distribution, organic carbon content). Because all these factors can affect the rate of contaminant movement through soils, it is very difficult to predict such movement. However, based on the dated collected in this RI, generalizations can be made. Sorption of the. chemical to soil particles is the only significant hinderance of contaminant migration in soils at this site. If it were not for sorption, rainfall recharge and soil permeability are high enough such that all the contaminants would readily move through the · soils. This is evident by the movement of the volatile organic chemicals in the soils. Sorption of these contaminants is small at this site, as indicated by their low K., values, and thus they have been observed at significant concentrations and over significant areas in groundwater. Even though the PCBs have been observed in the soils at significant concentrations, they have not been observed in the groundwater. Sorption of these contaminants to the soils at the site has apparently prevented them from migrating into groundwater. 5-2 I I I I I I I I I I I I 5.1.4 GROUNDWATER MIGRATION GE/Shepherd Fann NPL Site Remedial Investigation Report Draft/ May 1995 Once the contaminants of concern reach groundwater, they will generally move as the groundwater moves, through the process of advection. However, the process of dispersion will also cause the contaminants to spread both horizontally and vertically, and the process of sorption as described above will retard the movement of the contaminants. The fact that widespread (both upgradient and downgradient from the main theorized source, the drainline) contamination has been observed in groundwater at the site indicates that the sources (primary or secondary) must also be widespread. Future migration of the volatile organics in groundwater may extend as far downgradient as the surface water features intercepting groundwater flow will allow, if the sources are strong enough to overcome dilution effects. 5-3 I I I g g I I I I GE/Shepherd Farm NPL Site Remedial Investigation Report Draft May 1995 6.0 SUMMARY, CONCLUSIONS, AND RECOMMENDATIONS In June 1994, EPA initiated this Remedial Investigation to address the potential source areas and the groundwater contamination at the General Electric/Shepherd Fann Site. The primary objective of the RI was to assess the nature and distribution of contaminants at the three subsites; GE, Shepherd Farm, and Seldon Clark. EPA sampled soil, groundwater, surface water, sediment, and fish tissue to meet the RI objectives. The details of each of these studies are presented in Sections 3 and 4 of this report and should be consulted for a full understanding of the results of the RI. The major conclusions reached and future recommendations are provided below. 6.1 SOIL INVESTIGATION Thirty four surface soil and 41 subsurface soil samples were collected during this investigation. 6.1.1 General Electric The analyses of soil samples collected at the GE facility can be discussed by source area. The Landspreading Areas primarily contained PAHs, pesticides, and metals. PCBs were detected in one sample from Landspreading Area D. The landfills onsite contained VOCs, PAHs, PCBs, and metals. Landfill A was the only landfill where VOCs were found. PCBs were detected in all three landfills. The drain line/fonner ditch area, which is considered to be the main source of groundwater contamination, and was the subject of a removal by GE, contained low levels of PAHs and PCBs, along with a variety of metals. Samples taken · along the railroad track showed PAHs aiid low levels of PCBs. One sample revealed the presence of elevated concentrations of chromium and manganese. Three underground storage tank locations were sampled. No VOCs or PCBs were detected. Low levels of PAHs and pesticides were detected. 6.1.2. Seldon. Clark . The soil samples collected from the Seldon Clark property contained low levels of VOCs, PAHs, and pesticides. Chromium and manganese were also present at elevated levels. , 6-1 I I 0 I I I I I I ii I I I I GE/Shepherd Farm NPL Site Remedial Investigation Repo1t Draft May 1995 6.1.3 Shepherd Farm Two of the soil samples collected from the Shepherd Fann property contained trace levels of PCE. P AHs and pesticides were also detected. PCBs at elevated concentrations were prevalent in su1face soil samples. In addition, elevated levels of copper, zinc, and manganese were also found. One TCLP sample was analyzed. Barium was the only compound detected. 6.2 SURFACE WATER Thirteen surface water samples were collected. Six were near the GE property, six were near the Shepherd Fann property, and one was located near the Seldon Clark property. PCE was detected in all six GE surface water samples. PAHs were detected near the Shepherd Farm property. No pesticides or PCBs were detected. Metals were detected in all surface water samples. Of particular interest were manganese, aluminum, and iron. 6.3 SEDTh'IENT Thirteen sediment samples were collected. No VOCs were detected. PAHs were detected in eight of the sediment samples. PCBs were detected in four samples near the GE property, one near the Shepherd Fann property, and one near the Seldon Clark property. No elevated concentrations of metals were detected. 6.4 TEMl'ORARY MONITOR WELLS Nine temporary wells were installed; two near the GE facility, two near the Seldon Clark property, and five near the Shepherd Farm property. Two samples near the Shepherd Fann property contained elevated levels of VOCs. PAHs were detected in one sample near the Shepherd Fann property. No pesticides or PCBs were detected. Metals were detected in all of the samples. Mercury, nickel, aluminum, and manganese were detected in elevated concentrations. 6.5 GE ONSITE PERMANENT MONITOR WELLS Twenty four· of the existing pennanent monitor wells located on the GE property were sampled. VOCs were detected in 21 of the 24 wells sampled. Tridlloroethene, tetrachloroethene, and 1,2-dichloroethene were the most prevalent. Concentration isopleth maps indicate that the area with the highest contamination lies along the drain line/former 6-2 I I I I I I I I I I I- I I I GE/Shepherd Fann NPL Site Remedial Investigation Report Draft May 1995 ditch area. One well, located east-northeast of a fonner leaking underground storage tank also contained high concentrations of these three compounds. P AHs were detected in five samples. No PCBs or pesticides were detected. Metals were detected in all of the monitor well samples. Of particular concern are the metals barium, beryllium, and manganese. 6.6 PRIVATE WELL SAMPLING Eleven private wells were sampled. Low levels of VOCs were detected in two samples. No PAHs, pesticides, or PCBs were detected in any of the samples. A variety of metals were detected. Lead, zinc, aluminum, manganese, and iron are noteworthy. 6.7 RECOMMENDATIONS The following are recommendations for future sampling at the site to further define the extent of contamination: * * * * Additional soil samples should be collected in Landfill A. This was the only area on the GE plant site that exhibited PCE contamination. Additional soil samples should be collected in the vicinity of monitoring wells MW-14 and MW-25. These areas appear to have an independent source other than the drain line and should be investigated. Additional monitoring wells should be placed: I) east of Bat Fork Creek between temporary well TW-1 and TW-2; 2) west of Spartanburg Hwy across from MW-25 and MW-26; and 3) north of Tabor Road across from Landspreading Area A. Periodic sampling of private wells in the area that are used for drinking water purposes. 6-3