NCD003446721_20030819_Celeanse Corporation - Shelby Fiber_FRBCERCLA RA_OU-1 Semiannual Report January - June 2003-OCR

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CNA-Holdirigs, lric./Ticona_',_ ·
(F.K.A. Cela_nese Fiber Ope~ation~)
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Document Control .No. 026S8~134 ··.· . . ., . . ' ~' .
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-Submitied to' ·:., ,,. ·, .
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U ,S. ~nvironniental .Protection Agency· , · , :· ·. i; . ·Region·IV .. '. , . -'<' .. _.,;_:_
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Kubal-Furr &·Associates,
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Post Office Box 273210
Tampa, FL 33688-3210
[phone]
FAX [phone]
Mr. Kenneth Lucas
Remedial Project Manager
U.S. Environmental Protection
Agency, Region IV
61 Forsyth Street
Atlanta, GA 30303
Dear Mr. Lucas:
Kubal-Furr & Associates
Environmental Management Services
August 19, 2003
Post Office Box 8024 7
Simpsonville, SC 29680-0247
[phone]
FAX [phone]
On behalf of CNA Holdings, Inc., we are pleased to enclose two copies of the report entitled:
"Operable Unit 1-Semiannual Report-January 2003-June 2003-CNA Holdings,
Inc.-Shelby, North Carolina." By way of this letter, we have also transmitted a copy of the
report to David Mattison with NCDENR for his review.
Please contact me at 813-265-2338, to discuss any questions you may have following your
review of this document.
Sincerely,
Kubal-Furr & Associates
dtj/4_lr~
Jerry E. Kubal, P.G.
President
cc: Mr. David Mattison, NCDENR
Mr. Steven F. Olp, Celanese Americas
Ms. PEM Carter, Ticona-Shelby ESHA
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Contents
Acronyms/ Abbreviations . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 111
Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1
Work Performed ........................................................ 3
1st Quarter 2003 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3
2nd Quarter 2003 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4
System Performance . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6
Inner Tier Extraction Rates . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6
Ground-Water Movement .............................................. 6
Treatment Efficiencies . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7
Maintenance Activities . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7
Analytical Test Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9
Data-Quality Assessment . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9
· Discussion of Analytical Test Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9
Review of Selected Historical Water-Quality Data . . . . . . . . . . . . . . . . . . . . . . . . . . 12 ·
Tables
Table 1. 2003 Sampling Matrix-CNA Holdings, Inc.-Shelby, NC
Table 2. Inner Tier TOC (Total Organic Carbon) Data (January 2003 -June 2003)
Table 3. Inner Tier Production Data (January 2003 -June 2003)
Table 4. Summary of Selected CERCLA-related Water-Quality 9/ia (1st Quarter 2003)
Table 5. Summary of Selected CERCLA-related Water-Quality 9'a (2nd Quarter 2003)
Table 6. Summary of Selected PEW-related Water-Quality _9atfi(lst Quarter 2003)
co;,-1-,-1-ve.~+-s
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Figures
Figure 1. Site Location Mt>?
Figure 2. Potentiometric Surface Map-Shallow Saprolite-February 19, 2003
Figure 3. Potentiometric Surface Map-Deep SaproliteNpper Bedrock-February 19, 2003
Figure 4. Hydrogeologic Cross Section A-A', February 19, 2003
Figure 5. Potentiometric Surface Map-Shallow Saprolite-May 13, 2003
Figure 6. Potentiometric Surface Map-Deep SaproliteNpper Bedrock-May 13, 2003
Figure 7. Hydrogeologic Cross Section A-A', May 13, 2003
Attachments
Attachment 1. Operation and Maintenance Data (January 2003 -June 2003)
Attachment 2. Analytical Data for the 1st and 2nd Quarter 2003 Sampling Events
Attachment 3. Selected Water-Quality Plots
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CERCLA
I CFO
CNA
I EPA
FIi
I FP
GC/FID
!MAC I ITC!
ITEF
I LTRA
MCL
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mg/L
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OTC!
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OU-1
OU-2
I PCE
PEW
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ROD
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svoc
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TCLP
TOC
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Acronyms/Abbreviations
Comprehensive Environmental Response and Liability Act
Celanese Fiber Operations
CNA Holdings, Inc.
U.S. Environmental Protection Agency
Fiber Industries, Inc.
Filter Press
Gas Chromatograph/Flame Ionization Detector
Interim Maximum Allowable Concentration (North Carolina)
Inner Tier Combined Influent
Inner Tier Effluent
Long Term Remedial Action
Maximum Contaminant Level
Methyl Ethyl Ketone (2-Butanone)
Milligrams per Liter
National Priorities List
Outer Tier Combined Influent
Outer Tier Effluent
Operable Unit 1
Operable Unit 2
Tetrachloroethene
Polymer Extraction Well
Parts per Million
Record of Decision
Sequencing Batch Reactor
Semivolatile Organic Compound
Trichloroethene
Toxicity Characteristic Leaching Procedure
Total Organic Carbon
Volatile Organic Compound
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CNA Holdings, lnc./Ticona-Shelby, NC-QJ/Q2 2003 Semiannual Report Pagel
Introduction
Ticona, an operating subsi9iary of Celanese, owns and operates a polyester and engineering
plastics production faculty in Shelby, North Carolina. CNA Holdings, Inc. (CNA), also a
subsidiary of Celanese, retains management of environmental matters for the corporation and thus,
is responsible for the work performed during the semiannual reporting period. The Shelby site
consists of an approximate 450-acre piece of property which includes the main plant production
area, wastewater treatment area, former waste disposal areas, and recreational areas. The plant is
located in south-central Cleveland County, bordered by NC Highway 198 to the west and Lavender
Road to the south, approximately one mile north of Earl and six miles south of Shelby. A site plan
showing the location of production areas, monitor wells, extraction wells, and other significant
features is shown on Figure 1.
Operations at the site began in 1960 by Fiber Industries, Inc. (Fil), a manufacturer of polyester
chips and filament yarn. Celanese Corporation bought the facility from Fil in 1983, renaming it
Celanese Fiber Operations (CFO), and continued the production and processing of polyester
polymer chips and fibers. The site has alternately been known as HNA Holdings, Inc., Hoechst
Celanese Corporation, and Celanese Fiber Operations, the latter being the site name as listed on the
National Priorities List (NPL).
CNA currently operates a long term remedial action (LTRA) system at the CFO site, designated
as Operable Unit 1 (OU-1) in the Record of Decision (ROD), which consists of two ground-water
extraction and treatment systems identified as the Inner Tier and Outer Tier systems. OU-1 became
operational in August 1989. A second operable unit, OU-2, consisted of excavation, incineration,
stabilization and reburial of treated sludge and other waste materials. As part of this effort, CNA
maintains and monitors the effectiveness of the ground-water recovery and treatment system;
collects quarterly ground-water levels and samples from selected monitor wells ;ind process points;
and, reports the status of these activities to the EPA and State of North Carolina on a semiannual
basis.
On April 21, 1998, OU-2 and the Outer Tier portion of OU-1 were shut down as part of a
partial delisting petition approved by the EPA effective April 17, 1998. Currently, active ground-
water recovery and treatment is only taking place at the Inner Tier, which was designed to extract
contaminated ground water from around a former source area remediated as part of OU-2.
Although the Outer Tier is not actively recovering ground water, Outer Tier well OT-lR is still
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CNA Holdings, Jnc./Ticona-Shelby, NC-QJ/Q2 2003 Semiannual Report Page2
pumped to provide make-up water for the ground-water treatment system and for process water
used for back-flushing filters. The entire Outer Tier is being maintained in "stand-by status" as
part of the delisting process and can be brought on line within a relatively short period of time (24-
48 hours) if it is found necessary to provide hydraulic control along the property boundary. The
Outer Tier wells and treatment system's functionality is assured by performing routine monthly
and quarterly system checks such as energizing the well pumps, transfer pumps and blowers,
verifying heater operation, etc. and performing maintenance activities as required by the routine
system checks.
Kubal-Furr & Associates (Kubal-Furr) has prepared this semiannual OU-1 operating summary
report for submittal to the EPA on behalf of CNA. It covers the period from January 1, 2003
through June 30, 2003 and includes information on system performance and the results of
analytical testing of samples collected during the period February 20-25, 2003 and May 13-14,
2003. (Note: PEW-1 was not operational during the February 2003 sampling event and was
collected at a later date on March 12, 2003).
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CNA Holdings, lnc./Ticona-Shelby, NC-Ql JQ2 2003 Semiannual Report Page3
Work Performed
As part of the OU-1 remedy, samples are collected at selected monitor wells and at points in the
ground-water treatment system. In addition, samples were collected from the inactive polymer
extraction well (PEW) system and selected PEW-related monitor wells. The location of all monitor
and extraction wells is shown on Figure 1. A list of sampling locations and the parameters analyzed
during the 1st and 2nd Quarters are summarized in Table 1. A description of the work performed
during this reporting period is provided below.
1st Quarter 2003
On February 19, 2003, water levels were measured by Kubal-Furr in a total of 101 monitor
wells, extraction wells, and piezometers. A total of 17 CERCLA-related ground-water quality
samples, plus 1 duplicate and 2 equipment blank samples were collected during the period February
20-25, 2003 from selected monitor wells and extraction wells. All samples were collected by Kubal-
Furr and analyzed by Davis & Floyd of Greenwood, South Carolina.
OU-1 Monitor Well Sampling
Thirteen monitor well samples (plus one duplicate) were sampled using low-flow sampling .
protocols. The samples were analyzed in the field for pH, temperature and conductance; and, by the-+. r l. ,./, ~
laboratory for volatile organic compounds (VOCs) using EPA Method 8260B. In addition to
analysis of volatiles, samples from monitor wells K-28 and V-23 were also analyzed by the
laboratory for total organic carbon (TOC) using EPA Method 9060.
OU-1 Process Point Sampling
Samples of Inner Tier influent and effluent were collected for analysis of v9latile organics by
Method 8260B. The Inner Tier influent and effluent samples were also analyzed by the laboratory
for TOC by Method 9060, and for ethylene glycol by GC/FID (gas chromatograph/flame
ionization detector). Samples of SBR (sequencing batch reactor) and FP (filter press) sludge were
also collected and analyzed for the full TCLP suite of constituents.
During the reporting period, influent and effluent samples from the Inner Tier were also
collected by CNA personnel for analysis of TOC by Davis & Floyd. These samples are collected
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CNA Holdings, lnc./Ticona~5helby, NC-QJ(Q2 2003 Semiannual Report Page4
weekly to evaluate treatment efficiency, and the results are contained in the O&M reports provided
in Attachment 1. These results are also summarized in Table 2,
PEW Extraction and Monitor Well Sampling
Three inactive PEW extraction well samples were collected during the 1st Quarter. These
samples were analyzed for voes by EPA Method 82608 and for SVOes (semivolatile organic
compounds) by EPA Method 8270e (including the DowTherm®A constituents 1,1-biphenyl and
biphenyl ether).
2nd Quarter 2003
On May 13, 2003, water levels were measured by Kubal-Furr in a total of 101 monitor wells,
extraction wells, and piezometers. Water-quality samples were collected from 2 monitor wells and 2
process points (plus one duplicate), and analyzed for the parameters summarized in Table 1.
Samples were collected on May 13-14, 2003 by Kubal-Furr and analyzed by Davis & Floyd.
Monitor Well Sampling
Monitor wells K-28 and V-23 were sampled during the 2nd Quarter sampling event. These
wells were analyzed in the field for pH, temperature and conductivity; and, by the laboratory for . ?
TOC by Method 9060. L+v, 1_,;,t~ .
Process Point Sampling
Samples of Inner Tier influent and effluent (plus one effluent duplicate) were collected for
analysis of TOe by Method 9060 and voes by EPA Method 82608. The Inner Tier influent and
effluent samples were also analyzed for ethylene glycol by Ge/FID.
Free Product DowTherm®A Bailing-Well F-55
As noted in earlier semiannual reports, free product DowTherm®A was found to be
accumulating in monitor well F-55 following the well rehabilitation program implemented in
September 2001. Prior to the current semiannual reporting period, well F-55 was bailed on six
separate occasions and the total volume of DowTherm®A recovered has been approximately 6.5
liters (1.7 gallons). During the 1st and 2nd Quarters, well F-55 was tested on three occasions using
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CNA Holdings, lnc./Ticona---Shelby, NC-Ql /Q2 2003 Semiannual Report Page5
an interface probe and found to have steadily decreasing accumulations of product: 0.75-ft on
February 25, 2003; 0.34-ft on March 12, 2003; and, 0.25-ft On May 13, 2003. Free product in F-55
was bailed on these three occasions and approximately 1.1 liters (0.3 gallons) of free product was
recovered, bringing to 7.6 liters (2.0 gallons) the total amount of DowTherm®A recovered to date.
This well will be tested a ain in the 3rd Quarter of 2003 and any further free product accumulations
will be removed and reco ded.
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CNA Holdings, Inc./Ticona-She/by, NC-QJ/Q2 2003 Semiannual Report Page6
System Performance
Detailed records of system maintenance are kept by CNA and are summarized monthly. The
monthly records for the current reporting period are contained in Attachment 1.
Inner Tier Extraction Rates
During the reporting period, the Inner Tier wells extracted a total of 308,050 gallons (Table 3).
Inner Tier flows ranged from a low of 41,849 gallons in May, to a high of 64,832 gallons in March.
The sequencing batch reactor (SBR) treatment system is designed to process a maximum of about
2,500 gallons of water per day from the Inner Tier extraction well system. With 181 days in the
reporting period, at design capacity, pumping from the Inner Tier would have been some 452,500
gallons. Based on the pumpage during the reporting period, the Inner Tier extraction system was
producing at a rate of about 68% of the design capacity, which represents a significant increase
from the previous semiannual reporting period during which the Inner Tier produced about 47%
(217,367 gallons) of the design capacity rate.
Ground-Water Movement
In order to accurately predict the direction of ground-water movement, water-level
measurements were collected from all accessible monitor wells, extraction wells and piezometers on
February 19, 2003 by Kubal-Furr, and again on May 13, 2003. These data were used to construct
potentiometric surface maps and hydrogeologic cross sections (Figures 2 thru 7).
The shallow saprolite maps (Figures 2 and 5) show water-level contours and direction of
ground-water movement in the uppermost water-bearing zone beneath the site. The direction. of
movement in this zone is to the east from upgradient areas along NC 198, towards discharge areas
along the unnamed tributaries of Buffalo Creek. Drawdown and a capture zone are apparent on
these figures situated around the Inner Tier extraction system.
An attempt was made to separate the uppermost water-bearing zone from the deeper saprolite
and upper bedrock zone. While these maps (Figures 3 and 6) present a reasonable picture of
ground-water movement in this zone, it should be pointed out that it is giving a somewhat more
generalized picture of ground-water movement because of the well construction techniques used in
many of the wells and piezometers. The typical construction of these wells was to have relatively
long screens and extremely long sand packs in the annular space above the screens. As a result, the
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CNA Holdings, lnc./Ticona--Shelby, NC-QJ!Q2 2003 Semiannual Report Page 7
lower saprolite/upper bedrock maps have a number of composite head values measured along a
longer screened area. However, the maps may be useful for determining the general direction of
ground-water movement.
To confirm inferences made about the direction of movement and hydraulic control exerted by
the Inner Tier system, hydrogeologic cross sections were constructed from the February and May
data sets (Figures 4 and 7). The location of the cross section is shown on the site location map,
Figure 1. The east-west cross section (A-A') is constructed through the plant from upgradient areas
west of the plant to downgradient, off-site areas east of the plant. The east-west hydrogeologic cross
section indicates flow is predominantly horizontal across the site, from up gradient areas west of the
plant toward downgradient areas to the east.
Treatment Efficiencies
Two aspects of the extraction system performance were reviewed for this semiannual report: the
production rates achieved during the reporting period, and the removal efficiencies for TOC from
the Inner Tier system.
Table 2 summarizes the treatment system effectiveness of the Inner Tier in removing TOC
during the reporting period. This table was prepared from the individual monthly operation and
maintenence reports provided by the plant (Attachment 1 ), which contain water-quality data
collected weekly by CNA personnel and analyzed by Davis & Floyd. During the reporting period,
the Inner Tier average removal efficiency for TOC was approximately 92.8%, with an average
influent concentration of 1987 ppm (parts per million), and an average effluent concentration of
119.4 ppm.
Maintenance Activities
Low flow from the Inner Tier wells is a chronic problem requiring frequent maintenance. The
actions taken to rectify the low flow problems consisted of replacing bladders, timers, air lines and
such, adjusting the controls and flow rates, and cleaning the strainers. Specific actions taken at
individual wens during the reporting period are contained in the monthly operating summaries
(Attachment 1).
There is currently one outstanding problem related to the Outer Tier. The pump in well OT-6
had stopped pumping during the reporting period and attempts to remove and replace the pump
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CNA Holdings, Jnc./Ticona-She/by, NC-Ql/Q2 2003 Semiannual Report Page8
were unsuccessful. At the present time, the drop pipe to the pump has separated and the pump is
lodged in the well. A drilling contractor has been contacted to assist with pump removal/replacement
and this work should be accomplished by the end of September.
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CNA Holdings, /nc./Ticona-She!by, NC-QI/Q2 2003 Semia1111ual Report Page9
Analytical Test Results
The analytical test results for the 1st and 2nd Quarter sampling events were evaluated using
method specific quality control criteria and, for additional guidance when necessary, the EPA's
National Functional Guidelines for organic data review. Analytical test results, field sampling logs,
and chain-of-custody forms for the 1st and 2nd Quarter data sets are contained in Attachment 2. A
summary of selected analytical data for the 1st and 2nd Quarters is presented in Tables 4, 5 and 6.
Data-Quality Assessment
Regarding sample collection, the sampling logs and field information provided were complete.
All 1st and 2nd Quarter data were considered quantitative with several exceptions as noted in the
data assessment summaries. Based on the data quality assessment, qualifiers were placed on
selected analytical results as noted in Tables 4, 5 and 6. A complete description of the data review
and qualified results is provided with the 1st and 2nd Quarter data packages in Attachment 2.
Discussion of Analytical Test Results
CERCLA-Monitor Wells
Of the 13 CERCLA-monitor well samples analyzed during the reporting period, nine had
volatile organics reported above the detection level (Table 4). Of these nine, only five (CC-33, T-35,
V-23, HH-48 and HH-77) had two or more individual volatile constituents reported as present
above the detection level. The most frequently reported volatiles included acetone, benzene, carbon
disulfide and trichloroethene.
Monitor wells T-35 and V-23 reported the largest number of individual volatiles at six each. T-
35 and V-23 reportedly contained only two of the same volatiles: acetone (0.0055. mg/L [milligrams
per liter] and 0.0881 mg/L, respectively) and benzene (0.0017 mg/L and 0.00991 mg/L,
respectively). Chlorobenzene (0.0044 mg/L), chloromethane (0.0013 mg/L), tetrachloroethene
(PCE, at 0.0011 mg/L) and trichloroethene (TCE, at 0.0016 mg/L) were reported as present in T-35,
while 2-butanone (0.121 mg/L), carbon disulfide (0.00831), toluene (0.00351 mg/L) and xylenes
(0.0044J mg/L) were reported as present at V-23.
Monitor well CC-33 reportedly contained acetone (0.0050 mg/L), benzene (0.0016 mg/L),
carbon disulfide (0.0015 mg/L), cis-1,2-dichloroethene (0.0028 mg/L) and trichloroethene (0.004
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CNA Holdings, lnc./Tico11a---Shelby, NC-QJ/Q2 2003 Semia1111ual Report Page JO
mg/L). The only other monitor wells reporting the presence of more than one volatile were HH-48
and HH-77 with cis-1,2-dichloroethene (0.00111 mg/Land 0.00881 mg/L, respectively) and
trichloroethene (0.151 mg/Land 0.087J mg/L, respectively).
Monitor wells K-28 and V-23 were also analyzed for TOC during the 1st and 2nd Quarters.
The K-28 test results for the 1st and 2nd Quarters were 1.5 mg/Land 1.6 mg/L, respectively. The
TOC test results for V-23 for the 1st and 2nd Quarters were 3940 mg/L and 7030 mg/L,
respectively.
Process Point Samples
Inner Tier influent and effluent samples were analyzed during the 1st and 2nd Quarters for
ethylene glycol, TOC, and volatile organics. The 1st Quarter Inner Tier influent sample reportedly
contained the volatiles 2-butanone (0.024 mg/L), acetone (0.085 mg/L), benzene (0.027 mg/L),
carbon disulfide (0.0041 mg/L), chlorobenzene (0.019 mg/L), cis-1,2-dichloroethene (0.0030
mg/L), toluene (0.0012 mg/L), trichloroethene (0.0011 mg/L), and vinyl acetate (0.0016 mg/L). The
2nd Quarter Inner Tier influent sample reportedly contained the volatiles acetone (0.52J mg/L),
benzene (0.012 mg/L), 2-butanone (2.01 mg!L), carbon disulfide (0.0015 mg/L) and chlorobenzene
(0.014 mg/L).
Inner Tier influent ethylene glycol results for the 1st and 2nd Quarters were reported at 1760
mg/Land 2310 mg/L, respectively. Inner Tier influent TOC results for the 1st and 2nd Quarters
were reported at 1950 mg/Land 2360 mg/L, respectively.
While no volatiles were reported above the detection level in the Inner Tier effluent sample for
the 1st Quarter, the Inner Tier effluent sample reportedly contained acetone (0.0063 mg/L) in the
2nd Quarter. Ethylene glycol for the 1st and 2nd Quarter Inner Tier effluent samples were reported
below the detection limit of 5 mg/L. Inner Tier effluent TOC was reported as 691 mg/Land 382
mg!L for the 1st and 2nd Quarters, respective! y.
The SBR and FP sludges were tested for the full regulatory list of TCLP constituents during
the 1st Quarter. All reported values for both samples for pesticides and herbicides, metals, volatiles
and semi volatiles were below the laboratory detection levels with the exception of a reported barium -7
of 5.0 mg/Lin the FP sludge. Based on the TCLP data, the sludges would not be considered
characteristically hazardous, nor would they exceed any applicable State standard for disposal in a
North Carolina landfill.
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CNA Holdings, /nc./Ticona--Shelby, NC-Ql /Q2 2003 Semiannual Report Page 11
PEW-Related Samples
Three PEW-related samples were collected during the 1st Quarter. Of the three, only two
(PEW-3 and PEW-4) had morn than one volatile or semivolatile constituents reported as present.
Trichloroethene was the only volatile or semivolatile constituent reported as present at PEW-1
(0.0061 mg!L). PEW-3 reportedly contained the volatiles carbon disulfide (0.0023J mg/L) and
methylene chloride (0.0023J mg/L). PEW-4 reportedly contained the volatiles benzene (0.0040J
mg/L) and cis-1,2-dichloroethene (0.003~ mg/L). The PEW-4 duplicate sample reportedly
contained carbon disulfide (0.0014X mg/L) and methylene chloride (0.0027X mg/L) in addition to
\
the benzene and cis-1,2-dichloroethene found in PEW-4. These constituents were assigned an X
qualifier by the data reviewer indicating the result}are suspect and should be used with caution.
\. °'-
0 n l y one of the three wells sampled (PEW-4) had reportable quantities of DowTherm®A
constituents (i.e., 1,1-biphenyl or biphenyl ether). 1,1-Biphenyl was reported as present in well
PEW-4 (0.016 mg/L) and biphenyl ether (0.058 mg/L).
Kubal-Furr & Associates r----.
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CNA Holdings, lnc./Ticona-Shelby, NC-QI IQ2 2003 Semiannual Report Page12
Review of Selected Historical Water-Quality Data
Attachment 3 contains plots of selected water-quality constituents for various monitor wells and
process points. The choice of locations and constituents was based on a review of the water-quality
database, in particular those locations having any meaningful data to plot. In general, only those
monitoring locations within a few hundred feet of the former OU-2 source area have any significant
number of water-quality constituents reported above the detection limits. In order to assess long-
term trends and improvement in water-quality conditions resulting from source removal and
ground-water recovery, the following locations and constituents were selected for review:
• Inner Tier Combined Influent TOC and ethylene glycol test results. The Inner Tier TOC
decreased to below 2000 mg/L during the 1st Quarter and returned to near 4th Quarter 2002
levels of 2360 mg/L during the 2nd Quarter. Inner Tier TOC has been fluctuating within a
range of 1,000 mg/L to 3,000 mg/L since 1995 but no long-term or seasonal trends are
apparent from the data set. The Inner Tier ethylene glycol concentrations increased between
the 1st and 2nd Quarters to more than 2200 mg/L and represents the third successive
quarterly increase. Prior to the 4th Quarter of 2002, ethylene glycol had been fluctuating
between 500 mg/I and 1000 mg/L for the previous 9 quarters. The increasing trends noted at
this location will continue to be evaluated during the next semiannual reporting period.
· • Monitor Well V-23 TOC, 2-butanone (MEK-methyl ethyl ketone), acetone and benzene.
The V-23 TOC concentrations began trending downward from a high of 8000 mg/Lin mid-
1989 to less than 1000 mg/L in early 1992. Since that time, the TOC data have shown
several wide swings in concentration, with a historic high of 11,800 mg/L achieved in
October of 1997. Since 1996, the TOC values at this well have fluctuated in the range of
3,000 mg/L to 12,000 mg/L, with it not being uncommon to note quarter-to-quarter changes
of more than 7000 mg/L.
The V-23 MEK data have generally fluctuated in a narrow range below 1 mg/L, with 11 of
37 data points below the detection level. The values for MEK increased between the 3rd
Quarter of 2002 and the 1st Quarter of 2003 Quarter and the last 12 sample results have all
been below 0.5 mg/L.
The V-23 acetone test results have been oscillating between 0.1 mg/Land 0.5 mg/L for the
past four years and no discemable trend is apparent in the V-23 acetone data set.
Kubal-Furr & Associates
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CNA Holdings, /11c./Tico11a-Shelby, NC-QJ/Q2 2003 Semiannual Report Page 13
•
•
While more than half the benzene data for V-23 is flagged as estimated or below the
detection limit, 15 of the past 16 sampling events have been quantitative and show benzene
to be fluctuating in a narrow range of from 0.01 to 0.03 mg/L.
Monitor well K-28 TOC and benzene data. TOC and benzene have both shown a steady
decrease in concentration beginning about the time the OU-2 source remediation began in
January of 1991. While the 1st and 2nd Quarters were below 1.6 mg/L, the TOC
concentrations at K-28 have shown several wide swings in concentration up to 2000 mg/L
during the past two years. These increases were thought to be the result of a well
rehabilitation program undertaken in 2001, although no corresponding increase in other
constituent concentrations were noted at this well.
Benzene at well K-28 has shown a general decline since OU-2 source remediation and the
last nine sampling events since the 1st Quarter of 1999 have all been reported as less than or
equal to 0.01 mg/L.
Monitor well HH-48 and HH-77 TCE (trichloroethene) data. The HH-48 TCE test results
had shown a decline from 0.222 mg/Lin August of 1995 to less than 0.1 mg/L during the
3rd Quarter of 2000. Since that time, TCE concentrations at HH-48 have steadily increased
to the current 1st Quarter estimated value of 0.15 mg/L.
TCE at HH-77 had been fluctuating in the range of 0.05 mg/L to 0.15 mg/L until the July
1996 sampling event when it peaked at 0.383 mg/L. TCE at HH-77 had been decreasing
substantially since then to 0.059 mg/L during the 1st Quarter of 2001, however, the
concentration was noted to increase to near historic highs during the 3rd Quarter of 2001
(0.35 mg/L) and to achieve a historic high of 0.46 mg/L during the 3rd Quarter of 2002.
The most recent 1st Quarter concentration of TCE at HH-77 is reportedly less than 0.1
mg/L, however, this data point has been qualified as estimated because of an associated
analytical quality control problem.
The presence of TCE at these locations (HH-48 and HH-77) are thought to be the result of
a localized source, unrelated to activities at CNA/Ticona or the former OU-2 source area.
Kubal-Furr & Associates
------ -- - - - -- - - ---
Table 1. 2003 Sampling Matrix-CNA Holdings, lnc./Ticona-Shelby, NC
1st Quarter
Monitoring roe voe Eth. Glycol roe
Location ~ (8260B) (GC/FID) (9060)
Process Points
rm ,/ ,/ ,/ ,/
rm ,/ ,/ ,/ ,/
OTC1
OTEF
SBR Sludge (Full TCLP)
FP Sludge (Full TCLP)
Monitor Wells
C-49 ,/
K-28 ,/ ,/ ,/
P-58
T-35 ,/
V-23 ,/ ,/ ,/
AA-54
CC-33 ,/
EE-58 ,/
FF 34
FF-62 ,/
GG-61 ,/
HH-48
HH-77 ,/
voe svoe
(8260B} (8270C)
PEW-Related Same/es
PEW-1
PEW-3
PEW-4
F-55
Notes:
,/
,/
,/
TOC -Total Organic Carbon
voe -Volatile Organic Compounds
Eth. Glycol = Ethylene Glycol
,/
,/
,/
GC/FIO = Gas Chromatograph/Flame Ionization Detector
TCLP .. Toxicity Characteristic Leaching Procedure
SVOC .. Semivolatile Organic Compounds
ITO .. Inner Tier Combined Influent
2nd Quarter 3rd Quarter
voe Eth. Glycol roe voe Eth. Glycol
(82608) (GC/FID) ~ {8260B) (GC/FID)
,/ ,/ ,/ ,/ ,/
,/ ,/ ,/ ,/ ,/
(OT Pumi:i,ii:!Q Discontinued on 4/21 /98)
,/
,/
ITEF -Inner Tier Effluent
OTO .. Outer Tier Combined Influent
OTEF -Outer Tier Effluent
SBR • Sequencing Batch Reactor
FP = Filter Press
PEW • Polymer Extraction Well
,/
,/
,/
,/
,/
,/
,/
,/
,/
voe svoc
(8260B) (8270()
,/ ,/
,/ ,/
,/ ,/
TOe
(9060)
,/
,/
,/
,/
4th Quarter
voe Eth. Glycol
(82608) (GC/FID)
,/ ,/
,/ ,/
CNA Holding.~. lnc./Ticmw-Shelby, NC
OU-I Semiannual Re110rr (Jan. '03-June '03)
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Table 2. Inner Tier TOC (Total Organic Carbon) Data
Jan. '03 -June '03
CNA Holdings, lnc./Ticona-Shelby, North Carolina
(all results reported in parts per million [ppm])
Date
1 /1 /03
1/8/03
Influent
1660
1540
1/14/03 1800
1/21/03 2590
Effluent
10.2
11.9
11.0
64.7
% Reduction
99.4
99.2
99.4
97.5
1/~~!Q}. ??10. 1 34.0 ............................ 9 5 .. 1 .......... .
2/5/03 1700 10.9 99.4
2/11/03
2/19/03
1450
2200
12.6
57.3
Z.!?.~!Q} ............... 3260 .......................... ~?.:~ .......... .
3/4/03 1580 90.7
3/12/03 1490 11.6
3/19/03 1420 36.9
}!?.~!0.} .. 2430 ....... 55.1 ···················
4/2/03 2150 155
4/9/03 1680 157
4/16/03 2050 141
4/21/03 2590 432
.... :'.\(39(Q} . . . }9:'.19. . . 1 ~7 .
5/8/03 1660 194
5/14/03 1860 308
5/22/03 491
6/4/03 2520
6/11/03
6/17/03
6/24/03
Average:
1440
1690
2320
1987
231
268
32
281
68.6
46.5
119.4
99.1
97.4
97.0 . ...................... .
94.3
99.2
97.4
97.7 ·················· 92.8
90.7
93.1
83.3
93.8 . .................... .
88.3
83.4
53.0
88.5
98.7
80.5
95.9
98.0
92.8
CNA Holdings, Inc.!Ticona-Shelby, NC
OU-I Semiannual Report (Jan. '03 -June '03)
✓
- -
~
IT-1
IT-2
IT-3
IT-4
IT-5
IT-6
IT-7
IT-8R
IT-9
* ADF:
- -- - - --- - --
January 2003 February 2003
Total Total
Gallons AOF* Gallons ADF*
4,237 137 4,454 1 59
2,475 80 3,236 116
1 .8.0.3 58 4 098 146
2,662 86 2,667 95
5,409 174 4,538 162
2 693 87 2 535 91
3,216 104 2,946 105
11,269 364 11,059 395
13 012 420 12 715 454
46,776 48,248
Table 3. Inner Tier Production Data
Jan '03 -June '03
CNA Holdings, lnc./Ticona-Shelby, NC
March 2003 April 2003
Total Total
Gallons ADF* Gallons ADF*
5,991 193 5,533 184
4,936 1 59 4,729 158
5 529 178 6 223 207
3,154 102 3,892 130
8,338 269 10,102 337
3 097 100 2 153 72
3,301 106 5,777 193
15,140 466 11,947 396
15 346 495 11 306 377
64,832 61,662
Average Daily Flow based on CNA production records (Attachment 1 ),
Calculated as total flow divided by the number of days in the month.
May 2003
Total
Gallons
6,033
2.183
6 621 ___
3,000
9,144
2 118
1,295
11,427
28
41,849
-
ADF*
195
70
214
97
295
66
42
369
- - - -
June 2003 Jan.-June '03
Total
Gallons ADF* Total Gallons
5,883 196 32,131
1,812 60 19,371
7 980 266 32 254
2,746 92 18,121
7,449 248 44,980
1 877 63 14_,473 ..
1,045 35 17,580
13,620 461. 74,662
2 071 69 54 478
44,683 308,050
CNA Holdings, lncfTicona-SJzelby, NC
OU-I Semiannual Reporl (Jan. '03 -J1111e '03)
-
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Table 4. Summary of Selected CERCLA-Related Water-Quality Constituents (1st Quarter 2003)
CNA Holdings, lnc./Ticona-Shelby, North Carolina
(All results reported in milligrams per liter [mg/L])
V-23
EPA/NC K-28 T-35 V-23 Duplicate
Total Organic Carbon NE/NE LS.. NA ~-ilZ.Q.
Ethylene Glycol NE/7.0 NA NA NA NA
Volatile Organics
2-Butanone(MEK) NE/0.17 <0.0050 <0.0050 Q.l2.! lU.L.1 .
Acetone NE/0.7 <0.0050 ~-Q.QfilLl. Q..QfilLl .
Benzene 0.005/0.001 0.0057 J · QJ.lfilZ. 0.0099J , 0 0099J -
Carbon Disulfide NE/0.7 <0.0010 <0.0010 0.0083 J 0.00781 ·
Chlorobenzene 0.1/0.05 <0.0010 D...OQil . <0.0020 <0.0020
Chloromethane NE/0.0026 <0.0010 Q...D.Qll' <0.0020 <0.0020
Cis-1,2-Dichloroethene 0.07/0.07 <0.0010 <0.0010 <0.0020 <0.0020
Tetrachloroethene 0.005/0.0007 <0.0010 l1.0.0ll· <0.0020 <0.0020
Toluene 1.0/1.0 <0.0010 <0.0010 Q.Q03SJ · Q 0035J •
Trichloroethene 0.005/0.0028 <0.0010 o...oou;. <0.0020 <0.0020
Vinyl Acetate NE/NE <0.0010 <0.0010 <0.0020 <0.0020
Xylenes (total) 10/0.53 <0.0020 <0.0020 Q 0Q44J, 0 0047J ·
Notes: NA = Sample not analyzed for indicated constituents
J = Constituent positively identified however concentration should be considered as estimated
EPA= Environmental Protection Agency National Primary Drinking Water Standards
NC= North Carolina Groundwater Quality Standards (Subchapter 2L)
NE= Not Established
GG-61 HH-48 HH-77
NA NA NA
NA NA NA
<0.0050 <0.0050 <0.0020
<0.0050 <0.0050 <0.0020
<0.0010 <0.0010 <0.0040
0.001 J J <0.0010 <0.0040
<0.0010 <0.0010 <0.0040
<0.0010 <0.0010 <0.0040
<0.0010 0.0011 J 0.0088J •
<0.0010 <0.0010 <0.0040
<0.0010 <0.0010 <0.0040
<0.0010 _Q,_UJ. Q,,Ofil.! -•
<0.0010 <0.0010 <0.0040
<0.0020 <0.0020 <0.0080
CNA Holdings, lnc.!Ticorw-Shelby. NC
OU-/ Semiannual Report (Jan. '03 -June '03)
-
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Table 4. (Cont'd) Summary of Selected CERCLA-Related Water-Quality Constituents (1st Quarter 2003)
CNA Holdings, lnc./Ticona-Shelby, North Carolina
(All results reported in milligrams per liter [mg/L])
Inner. Tier
EPA/NC CC-33 FF-34 FF-62 Influent
Total Organic Carbon NE/NE NA NA NA ~-
Ethylene Glycol NE/7.0 NA NA NA lZ.6Q.
Volatile Organics
2-Butanone(MEK) NE/0. 17 <0.0050 <0.0050 <0.0050 _Q_,_Q-2.1.
Acetone NE/0.7 0.0050 · <0.0050 0.0050 · M..8..5.·
Benzene 0.005/0.001 0.0016 · <0.0010 <0.0010 Mll·
Carbon Disulfide NE/0.7 0.001 5 · 0.0080 · <0.0010 0.0041 ·
Chlorobenzene 0.1/0.05 <0.0010 <0.0010 <0.0010 Q.Ql9_.
Chloromethane NE/0.0026 <0.0010 <0.0010 <0.0010 <0.0010
Cis-1 ,2-Dichloroethene 0.07/0.07 0.0028· <0.0010 <0.0010 0.0030 ·
Tetrachloroethene 0.005/0.0007 <0.0010 <0.0010 <0.0010 <0.0010
Toluene 1 .0/1.0 <0.0010 <0.0010 <0.0010 0.001 2 ·
Trichloroethene 0.005/0.0028 0.0040· <0.0010 <0.0010 0.0011 ·
Vinyl Acetate NE/NE <0.0010 <0.0010 <0.0010 0.0016 ·
Xylenes (total) 10/0.53 <0.0020 <0.0020 <0.0020 <0.0020
Notes: NA = Sample not analyzed for indicated constituents
J = Constituent positively identified however concentration should be considered as estimated
EPA = Environmental Protection Agency National Primary Drinking Water Standards
NC = North Carolina Groundwater Quality Standards (Subchapter 2L)
NE= Not Established
Inner Tier
Influent
Duplicate
~-
1filQ.
~-
o_,_oz_6_•
Mz.a·
0.0044·
Q,QZQ'
<0.0010
0.0029 ·
<0.0010 o.oon-
0.0013 ·
0.0015 '
<0.0020
Inner Tier
Effluent
mi .
<5.0 ·
<0.0050
<0.0050
<0.0010
<0.0010
<0.0010
<0.0010
<0.0010
<0.0010
<0.0010
<0.0010
<0.0010
<0.0020
CNA Holdings, lnc./Ticona-Shelby, NC
OU-I Semiannual Report (Jan. '03 -lune '03)
- - - - - ----------- - - -
Table 5. Summary of Selected CERCLA-Related Water-Quality Constituents (2nd Quarter 2003)
CNA Holdings, lnc./Ticona-Shelby, North Carolina
(All results reported in milligrams per liter [mg/L])
Inner Tier Inner ,Tier
Total Organic Carbon
Ethylene Glycol
Volatile Organics
Acetone
Benzene
2-Butanone (MEK)
Carbon Disulfide
Chlorobenzene
EPA/NC
NE/NE
NE/7.0
NE/0.7
0.005/0.001
NE/0.17
NE/0.7
0.1 /0.05
K-28 V-23
1.6 · 7030'
NA NA
NA NA
NA NA
NA NA
NA NA
NA NA
Notes: NA = Sample not analyzed for indicated constituent(s)
Influent
2360
2310
0.52J
0.012
2.0J
0.0015
0.014
EPA= Environmental Protection Agency National Primary Drinking Water Standards
NC = North Carolina Groundwater Quality Standards (Subchapter 2L)
NE= Not Established
J = Estimated Value
Effluent
382
<5.0
0.0063 ·
<0.0010
<0.0050
<0.0010
<0.0010
Inner Tier
Effluent
Duplicate
170
<5.0
0.0068 ·
<0.0010
<0.0050
<0.0010
<0.0010
CNA Holdi11gs, /11c./Ticona-Shelby, NC
OU-I Semiannual Report (Jan. '03 -June '03)
-------------------
Table 6. Summary of Selected PEW-Related Water Quality Constituents (1st Quarter 2003)
CNA Holdings, lnc.mcona-Shelby, North Carolina
Semivotatite Organics
1 , 1 Biphenyl
Biphenyl Ether
Volatile Organics
Benzene
Carbon Disulfide
Cis-1,2-Dichloroethene
Methylene Chloride
Trichloroethene
(All results reported in milligrams per liter [mg/L]}
EPA/NC
NE/NE
NE/0.35
0.005/0.001
NE/0.7
0.07/0,07
0.005/0.005
0.005/0,0028
PEW-1
<0.010
<0.010
<0.0050
<0.0050
<0.0050
<0.0050
Q.QQ61
PEW-3
<0.010
<0.010
<0.0010
Q.QQZ3J ,
<0.0010
Q,Q023J,
<0.0010
PEW-4
Mli. ,
M..5..8. .
0.QQ4QJ ·
<0,0010
Q.Q39J ·
<0,0010
<0,0010
PEW-4
Duplicate
Q.QJJi,
Q,Qfil.,
Q,QQ4QJ,
Q.QQl 4X ·
Q.031.lJ ·
0.QQ27X,
<0.0010
Notes: J = Constituent positively identified however concentration should be considered as estimat,
X = Reviewer assigned qualifier indicating result is suspect and should be used with caution
EPA = Environmental Protection Agency National Primary Drinking Water Standards
NC = North Carolina Groundwater Quality Standards (Subchapter ZL)
NE= Not Established
CNA Holdings, lnc./Ticona-Shelby, NC
OU-I Semiannual Report (Jan. '03 -June '03)
-- --- -- - - - - -
... ~•o
--~ I~·
C
~~
.o. POU
PM
Scale in Feet
0 350 700
-- ---Legend
0 MooilotWel
Piezometer
Surface Water Location
A'
• Outer Tier Extraction Well
• lmerTier Extradion Well
□
l!i!i
PEW Extraction Well
Residential Well
Cfaek / Stream
Building I Structure
Kubal-Furr & Associates
-Enviromnental Consultants-
Figure 1. Site Location Map
CNA Holdings, lnc.ificona
Shelby, North Carolina
- -
-
0
•
Ill
--
Legend
MgnjtprWt;fJ Water-level (ft msl)
Inner Tier Extraction WeH
Creek I Stream
Building I Structure
- --- -
, " , \
\
\
\
\
-
\
= \ •M ,, '
Scale in Feet
0 350
-
700
-
,.)
~ \ ,:.\'
--
\
X
'
\
----
\
I
m
Inner Tier Extraction Well
Water•level Elevations
IT-1 = <780.50
IT-2 = <779.55
IT-3 = Not Measured
IT-4 = 778.68
IT-5 = 779.74
IT-6 = 777.05
IT-7 = 788.67
IT-BR= 797.99
tT-9 = Not Measured
' \
Kubal-Furr & Associates
-Environmental Consultants-
Figure 2. Potentiometric Surface Map
Shallow Saprolite-February 19, 2003
CNA Holdings, lnc.lI'icona
Shelby. North Carolina
--
-
0
♦
Ill
- -
Monitor Well Water+level (ft msl)
Pie.z.ometer
Outer Tier ExtracHon Well
PEW Extraction Well
Creek / Stream
Build!ng / Structure
- - - - - - - -
"
Scale in Feet
0 350 700
- -- -- -
\
\
\
\;
\ \·---.... ___ _
\
\
\ .. \
> I ---\
\
\
I
I / ,' ~o,.~_fm
-1~~---... ,_' I
~ ..
\
' I
I ---,_._
I
\
Kubal-Furr & Associates
-Environmental Consultants-
Figure 3. Potentiometric Surface Map
Deep Saprolite/Upper Bedrock-February 19, 2003
CNA Holdings. lnc.iTicona
Shelby, North Carolina
--
-----
850.00 A • m
830.00
•
D-27
825.12
D-35 810.00 824.77
790.00 0-56
824.74
770.00
750.00
730.00
710.00
690.00
670.00
Legend
-SlO..I line of equal fluid potential (ft msl) ~ Bedrock
(dast>edwnenti\fem,d)
I Potentiometric Surface Saprolite
-
• •
G-50
810.49
~ Inferred direction of ground-water
movement
Screened Interval of Well
--

-
---
tb#P6&iiii§iiMtii¼it·&d
~--'~.;L
Horizontal Scale in Feet
0 400 800
-
•
• :§
~ • ~ e 'r
GG,25
75253 I
----
A' 850.00
830.00
810.00
790.00
no.oo
750.00
730.00
710.00
69000
670.00
Kubal-Furr & Associates
-Environmental Consultants -
Figure 4-Hydrogeologic Cros:,;;-Sectlon
A·A'-february 19,2003
CNA Holdings, J11c fTinma
Shelb_v. North Caroli,w
--
-
0
•
- -
Legend
MooltnrWeU Water -Level (fl rnsl)
~
lnnllf Tier EK!ractloo Well
.,.....--1av~::~r
Creek / Stream
ii Bunding f Stn.iciure
- - -- -
0
- -
)r;x~i~~'
,;~:1·,
'11',~iaj. "-" ti-,?'' 0 7Mr,11
.·s;~{•I ,
Scale in Feet
350 700
-
'
'
-
'
0 ,~7f5 ' ' \
' ~ \
o ;;-: I
I
I
-- - - -
' \
\
\
I
I
'
\
' /if '
\
I
I ...-I
I
' I
I
' '
0
!
I
I
I
Ill
loner Tier Extraction Well
Water-Level Elevations
IT-1 = 780.95
IT-2 = <781.20
IT-3 = 802.96
IT -4 = <778.67
IT-5 = 781.92
IT-6 = <778.28
IT-7= 802.12
IT-8R= 796.99
IT-9 = Not Measured
Kubal-Furr & Associates
-Environmental Consultants-
Figure 5. Potentiometric Surface Map
Shallow Saprolite-May 13, 2003
CNA Holdings. lnc.iTicona
Shelby, Nonh Carolina
--
-
0
- -
Moortr,:Wel Waler-Level (fl msl)
Piezomelet
♦ Outer Tier Extraction Well
PEW ExtractlOfl Well
,.....---78()./ W~'!::!,~our
Crnek f Stream
r;J Buildiop / Struc:ti..-e
- --- - - - --
\
\
Scale in Feet
0 350 700
- - -- -
\ \
\
\
\
\ ·,_
/ \
\
\
\
\ \
\
I
·--., ,_
··,."···,
Kubal-Furr & Associates
-Environmental Consultants-
Figure 6. Potentiometric Surface Map
Deep Saprolitc/Upper Bedrock-May 13, 2003
CNA Holdings. lncfficona
Shelby, North Carolina
- -
---
850.00 A •
830.00 r--t----
810.00
790.00
no.oo
750.00
730.00
710.00
690.00
670.00
D•27 · 828.64
D-35 828.26
D-56
828.14
- -
F §bPAfid
Legend
-810,.I Line of equal nuid potential (ft msl) ~ Bedrock
(dashed v.t>ere Inferred)
I Potentiometric Surface Saprolite
-
• •
G-50
811.82
-
~ Inferred direction of ground-water
movement
Screened Interval of Well
-
J-29
810.26
- -- - - -
wfiii@M·· I rMtiii4hf M#ii •
Horizontal Scale in Feet
0 400 800
- - -
A' 850.00
830.00
810.00
790.00
770.00
750.00
730.00
710.00
690.00
670.00
Kubal-Furr & Associates
-Environmental Consultants -
Figure 7-Hydrogoologic Cros.s-Stttion
A·A'-May 13, 2003
CNA Holdings. Inc .fficono
Sh~I/Jy, North Carolina
- -
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I Attachment 1
I
Operation and Maintenance Data
January-June, 2003
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I Kubal-Furr & Associates
I
I INNER TIER
DAILY FLOW
I
I JAN.
2002 IT-1 IT-2 IT-3 IT-4 IT-5 IT-6 IT-7 IT-8 IT-9
I 01/01/03 135 137 26 72 239 91 126 392 636
01/02/03 132 66 29 74 236 90 124 435 635
01/03/03 137 0 9 73 241 91 119 489 652
I 01/04/03 138 0 0 70 242 91 122 451 658
01/05/03 133 2 1 65 241 88 128 424 634
01/06/03 135 0 0 66 232 90 120 387 637
01/07/03 139 67 54 69 225 92 105 353 642
I 01/08/03 143 82 54 77 223 94 110 375 664
01/09/03 143 81 38 92 218 92 110 269 671
01/10/03 142 85 37 90 216 90 101 201 671
I 01/11/03 142 89 33 92 216 89 100 321 231
01/12/03 140 91 41 82 232 86 77 212 0
01/13/03 145 95 49 82 259 90 82 183 503
I 01/14/03 145 97 56 83 260 90 89 53 697
01/15/03 143 95 54 85 261 86 81 385 662
01/16/03 148 103 57 87 272 90 90 502 679
01/17/03 140 43 54 83 260 87 86 552 684
I 01/18/03 106 102 54 76 190 72 62 429 520
01/19/03 139 46 71 78 222 83 80 467 7
01/20/03 145 208 60 87 100 93 99 501 11
I 01/21/03 142 104 45 87 67 92 194 494 0
01/22/03 140 100 41 83 80 95 206 500 0
01/23/03 100 93 30 75 40 85 100 490 0
I
01/24/03 167 125 157 112 98 90 135 451 32
01/25/03 149 102 99 188 81 62 89 504 523
01/26/03 15 10 10 0 28 39 11 47 50
01/27/03 144 89 110 0 53 85 71 387 419
I 01/28/03 154 89 113 71 96 93 103 416 0
01/29/03 150 90 125 80 10 168 110 424 0
01/30/03 153 95 168 236 164 16 85 0 678
I 01/31/03 153 89 128 147 107 93 101 175 816
AVG: 137 80 58 86 174 87 104 364 420
I TOTAL: 4237 2475 1803 2662 5409 2693 3216 11269 13012
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I 1
GROUNDWATER MONTHLY MONITORING:
RAINFALL DATA
JAN 2003
DATE INCHES/DAY
01/01/03 0.10
01/02/03 0.20
01/03/03 0.00
01/04/03 0.00
01/05/03 0.00
01/06/03 0.00
01/07/03 0.00
01/08/03 0.00
01/09/03 0.00
01/10/03 0.00
01/11/03 0.00
01/12/03 0.00
01/13/03 o.oo
01/14/03 0.00
01/15/03 0.00
01/16/03 0.10
01/17/03 0.00
01/18/03 o.oo
01/19/03 0.00
01/20/03 o.oo
01/21/03 0.20
01/22/03 0.20
01/23/03 0.00
01/24/03 0.00
01/25/03 0.00
01/26/03 o.oo
01/27/03 0.00
01/28/03 0.00
01/29/03 0.80
01/30/03 0.20
01/31/03 0.00
TOTAL 1.80
2
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I DAILY REFERENCE SHEET:
DATE: IT. EQ. PLT. DEC. DEC. WAS MIX MIX MIX NIT PHOS MIX F/M
I JAN. INF. TNK. SEP. LIQ LIQ LIQ ADD ADD LIQ WAS 5/DAY
~ COD. COD, CQQ,_ COD. TSS. _rss MLSS NIT et!QS GALS LBS sgr. GALS .ELM AVG.
1 4680 5500 4330 103 40 13870 3304 96 12.5 1 3 150 202 0.12
I 2 4360 3510 3996 110 20.5 0 0 150 0 0.00
3 5390 4570 4020 140 108 12790 4148 91 17.5 1 1 200 200 0.09
4 5230 4400 3872 119 25.0 0 0 210 0 0.00
5 4820 4150 4860 120 88 16610 3190 116 28.0 0 0 190 202 0.14 0.07
6 4820 4390 3732 121 16.0 0 2 150 0 0.00 0.04
I 7 3890 4840 3680 149 100 16090 3450 106 21.2 0 0 180 202 0.09 0.06
8 4500 5000 4130 136 70 16740 3410 78 12.2 1 3 200 202 0.11 0.07
9 4970 4400 3090 87 17.2 1 2 200 0 0.00 0.07
10 6530 4550 4410 324 40 12000 3980 104 24.0 0 0 200 202 0.10 0.06
I 11 5410 4310 2808 150 23.1 0 2 200 0 0.00 0.06
12 9290 5030 4080 136 60 14490 2760 143 32.5 0 0 200 202 0.13 0.07
13 8350 5110 3730 77 10.3 2 200 0 0.00 0.05
14 5650 6070 5200 132 60 15020 3010 103 21.2 2 200 202 0.15 0.08
I 15 5460 4010 3620 100 17.3 1 2 200 0 0.00 0.06
16 3930 4220 5740 121 70 19470 2980 120 25.5 0 0 190 202 0.17 0.09
17 4210 4140 4200 111 60 15710 3730 116 15.0 2 190 202 0.10 0.08
18 5190 4920 3160 102 15.0 2 200 0 0.00 0.08
19 4850 4720 5020 104 40 16100 3200 117 17.5 2 200 202 0.14 0.08
I 20 5990 4820 3120 136 22.3 0 2 200 0 0.00 0.08
21 8490 5390 4470 108 40 14250 3060 125 27.5 0 0 200 202 0.13 0.07
22 8670 5740 3860 115 17.5 0 0 200 0 0.00 0.05
23 7310 6050 3708 101 22.0 1 2 200 0 0.00 0.05
I 24 7890 6390 7240 145 100 18590 3060 146 36.2 0 0 200 202 0.21 0.07
25 3870 6040 3360 103 25.0 1 0 200 0 0.00 0.07
26 5590 6700 3260 134 18.0 0 0 210 0 0.00 0.04
27 5440 5330 6820 113 48 17010 2890 150 36.0 0 0 200 202 0.21 0.08
28 5046 5270 3160 136 12.5 0 3 200 0 0.00 0.08
I 29 8310 5790 6700 161 120 15450 3210 136 29.5 0 0 200 202 0.19 0.08
30 6170 4690 2760 79 15.4 2 200 0 0.00 0.08
31 . 5100 4530 6540 156 50 17350 2790 120 25.7 0 0 200 202 0.21 0.12
I AVG: 5787 4986 4791 133 64 14796 3336 114.1 21.3 0 194 104 0.07
MAX: 9290 6700 7240 324 120 19470 4148 150.0 36.2 3 210 202 0.21
MIN: 3870 3510 0 0 0 0 2760 77.0 10.3 0 0 150 0 0.00
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INNER TIER COMBINED INFLUENT #2 ITCI I PAGE NO.1
JAN.2003
DATE: FLOW: PH: COD: TSS: TOG: I GPD pH ppm ppm ppm
01/01/03 1854 5.3 4680 11 1660
01/02/03 1821 5.3 4360 6 I 01/03/03 1811 5.3 5390 18
01/04/03 1772 5.3 5230 10
01/05/03 1716 5.1 4820 8 I 01/06/03 1667 5.4 4820 7
01/07/03 1746 5.0 3890 8
01/08/03 1822 5.3 4500 37 1540 I 01/09/03 1714 5.4 4970 5
01/10/03 1633 5.1 6530 29
01/11/03 1313 5.0 5410 7
01/12/03 961 4.8 9290 16 I 01/13/03 1488 5.0 8350 11
01/14/03 1570 5.0 5650 4 1800
01/15/03 1852 4.9 5460 11 I 01/16/03 2028 5.1 3930 12
01/17/03 1989 5.1 4210 13
01/18/03 1611 5.0 5190 6
01/19/03 1193 5.1 4850 13 I 01/20/03 1304 5.1 5990 22
01/21/03 1225 5.0 8490 9 2590
01/22/03 1245 5.1 8670 12 I 01/23/03 1013 5.0 7310 6
01/24/03 1367 4.9 7890 75
01/25/03 1797 5.1 3870 9
01/26/03 210 5.2 5590 17 I 01/27/03 1358 5.1 5440 21
01/28/03 1135 5.1 5040 19
01/29/03 1157 4.8 8310 25 2710 I 01/30/03 1595 5.1 6170 6
01/31/03 1809 5.2 5100 10
AVG: 1509 5.1 5787 15 2060 I MAX: 2028 5.4 9290 75 2710
MIN: 210 4.8 3870 4 1540
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I GROUNDWATER MONTHLY MONITORING:
INNER TIER EQUALIZATION TANK: ITEQT
PAGE NO. 2
JAN.2003
I DATE: PH: COD: OT WATER ADDED
pH ppm gal
I 01/01/03 7.3 5500 563
01/02/03 7.2 3510
01/03/03 7.1 4570
I 01/04/03 7.2 4400
01/05/03 7.1 4150
01/06/03 7.5 4390
01/07/03 7.2 4840
I 01/08/03 7.4 5000
01/09/03 7.5 4400
01/10/03 6.8 4550
I 01/11/03 7.2 4310
01/12/03 6.8 5030
01/13/03 7.1 5110
01/14/03 6.9 6070
I 01/15/03 6.8 4010
01/16/03 6.7 4220
01/17/03 6.8 4140
I 01/18/03 7.0 4920
01/19/03 6.7 4720
01/20/03 7.2 4820
01/21/03 6.7 5390
I 01/22/03 7.2 5740
01/23/03 6.9 6050
01/24/03 6.8 6390
I 01/25/03 7.4 6040
01/26/03 7.1 6700
01/27/03 6.7 5330
I 01/28/03 7.2 5270
01/29/03 6.8 5790
01/30/03 7.3 4690
01/31/03 7.1 4530
I AVG: 7.1 4986 563
MAX: 7.5 6700 563
I MIN: 6.7 3510 563
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GROUNDWATER MONTHLY MONITORING:
AFTER PLATE SEPARATOR BEFORE SBR: I PAGE NO. 3
JAN.2003
DATE: PH: COD: TSS: I pH ppm ppm
01/01/03 7.1 4330 12 I 01/02/03
01/03/03 6.7 4020 16
01/04/03
01/05/03 6.9 4860 20 I 01/06/03
01/07/03 7.1 3680 16
01/08/03 7.2 4130 4 I 01/09/03
01/10/03 6.9 4410 8
01/11/03
01/12/03 6.5 4080 20 I 01/13/03
01/14/03 6.5 5200 12
01/15/03 I 01/16/03 6.7 5740 40
01/17/03 6.6 4200 8
01/18/03
01/19/03 6.5 5020 16 I 01/20/03
01/21/03 6.6 4470 8
01/22/03 I 01/23/03
01/24/03 6.4 7240 4
01/25/03 I 01/26/03
01/27/03 6.4 6820 40
01/28/03
01/29/03 6.4 6700 48 I 01/30/03
01/31/03 6.7 6540 16
AVG: 6.7 5090 18 I MAX: 7.2 7240 48
MIN: 6.4 3680 4
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I GROUNDWATER MONTHLY MONITORING:
SBR MIXED LIQUOR: SBRML
PAGE NO.4
JAN.2003 SETT. SLUDGE 5/DAY
I DATE: PH: NH3N: PO4: DO: MLSS: MLVSS: SOLIDS: WASTED F/M: F/M:
pH ppm ppm ppm ppm ppm ml/I gal ratio ratio
I 01/01/03 8.3 96 12.5 3.7 3304 150 202 0.12
01/02/03 8.3 110 20.5 3.9 3996 150 0 0.00
01/03/03 8.2 91 17.5 5.3 4148 200 200 0.09
01/04/03 8.3 119 25.0 5.0 3872 210 0 0.00
I 01/05/03 8.1 116 28.0 4.5 3190 190 202 0.14 0.07
01/06/03 8.3 121 16.0 4.0 3732 150 0 0.00 0.04
01/07/03 8.0 106 21.2 3.9 3450 2740 180 202 0.09 0.06
I 01/08/03 8.2 78 12.2 1.5 3410 200 202 0.11 0.07
01/09/03 8.0 87 17.2 2.6 3090 200 0 0.00 0.07
01/10/03 8.0 104 24.0 3.9 3980 200 202 0.10 0.06
I 01/11/03 8.1 150 23.1 4.9 2808 200 0 0.00 0.06
01/12/03 8.0 143 32.5 3.5 2760 200 202 0.13 0.07
01/13/03 8.0 77 10.3 3.6 3730 200 0 0.00 0.05
01/14/03 8.1 103 21.2 4.3 3010 2450 200 202 0.15 0.08
I 01/15/03 7.8 100 17.3 4.1 3620 200 0 0.00 0.06
01/16/03 8.0 120 25.3 5.6 2980 190 202 0.17 0.09
01/17/03 8.0 116 15.0 3.8 3730 190 202 0.10 0.08
I 01/18/03 7.9 102 15.0 4.9 3160 200 0 0.00 0.08
01/19/03 8.0 117 17.5 5.0 3200 200 202 0.14 0.08
01/20/03 8.1 136 22.3 4.0 3120 200 0 0.00 0.08
01/21/03 8.0 125 27.5 5.7 3060 2530 200 202 0.13 0.07
I 01/22/03 8.1 115 17.5 4.0 3860 200 0 0.00 0.05
01/23/03 8.0 101 22.0 5.0 3708 200 0 0.00 0.05
01/24/03 8.0 146 36.2 5.0 3060 200 202 0.21 0.07
I 01/25/03 8.0 103 25.0 4.1 3360 200 0 0.00 0.07
01/26/03 8.1 134 18.0 5.1 3260 210 0 0.00 0.04
01/27/03 7.9 150 36.0 4.6 2890 200 202 0.21 0.08
01/28/03 8.0 136 12.5 5.3 3160 2620 200 0 0.00 0.08
I 01/29/03 7.8 136 29.5 4.6 3210 200 202 0.19 0.08
01/30/03 8.0 79 15.4 3.3 2760 200 0 0.00 0.08
01/31/03 8.1 120 25.7 4.3 2790 200 202 0.21 0.12
I AVG: 8.1 114 21 4 3336 2585 194 104 0.07 0.07
MAX: 8.3 150 36 6 4148 2740 210 202 0.21 0.12
I MIN: 7.8 77 10 2 2760 2450 150 0 0.00 0.04
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GROUNDWATER MONTHLY MONITORING:
SBR EFFLUENT:(DECANT) #4 SBRE I PAGE NO. 5
JAN.2003 WAS. NH3N PHOS.
DATE: FLOW: COD: TSS:TSS ADDED: ADDED: I GPD ppm ppm ppm gal lbs
01/01/03 2625 104 40.0 13870 3
01/02/03 0 0 0 I 01/03/03 2050 140 108 12790 1
01/04/03 0 0 0
01/05/03 2580 120 88.0 16610 0 0 I 01/06/03 0 0 0
01/07/03 2625 149 100 16090 0 0
01/08/03 2325 136 70 16740 1 3 I 01/09/03 0 1 2
01/10/03 2850 324 40 12000 0 0
01/11/03 0 0 2
01/12/03 2107 136 60 14490 0 0 I 01/13/03 0 2
01/14/03 2625 132 60 15020 1 2
01/15/03 0 1 2 I 01/16/03 2518 121 70 19470 0 0
01/17/03 2550 111 60 15710 1 2
01/18/03 0 1 2
01/19/03 2220 104 40 16100 1 2 I 01/20/03 0 0 2
01/21/03 2524 108 40 14250 0 0
01/22/03 0 0 0 I 01/23/03 0 1 2
01/24/03 2438 145 100 18590 0 0
01/25/03 0 1 0
01/26/03 0 0 0 I 01/27/03 1875 113 48 17010 0 0
01/28/03 0 0 3
01/29/03 2418 161 120 15450 0 0 I 01/30/03 0 0 0
01/31/03 2175 156 50.0 17350 0 0
AVG: 1242 141 68 15721 0 I MAX: 2850 . 324 120 19470 1 3
MIN: 0 104 40 12000 0 0
DID NOT PROCESS SBR. I
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I GROUNDWATER MONTHLY MONITORIN(
INNER TIER CARBON FILTER EFFLUENT #8 ITEF
PAGE NO. 7
JAN.2003 I DATE: PH: COD: TOG: TSS:
pH ppm ppm ppm
I 01/01/03 8.4 98 10.2 30
01/02/03
01/03/03
I 01/04/03
01/05/03
01/06/03
01/07/03
I 01/08/03 8.3 121 11.9
01/09/03
01/10/03
I 01/11/03
01/12/03
01/13/03
01/14/03 8.1 98 11.0
I 01/15/03
01/16/03
01/17/03
I 01/18/03
01/19/03
01/20/03
01/21/03 8.1 96 64.7 I 01/22/03
01/23/03
01/24/03
I 01/25/03
01/26/03
01/27/03
I 01/28/03
01/29/03 8.1 97 134.0
01/30/03
01/31/03
I AVG: 8.2 102 46.4 30
MAX: 8.4 121 134.0 30
I MIN: 8.1 96 10.2 30
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MAINTENANCE ACTIVITIES-GROUNDWATER OPERABLE UNIT #1
INNER TIER SYSTEM
ACTION
DATE WELL# PROBLEM DATE ACTION MECHANIC
1/7/03 #2 LOW FLOW 1/7/03 RESTARTED PUMP MAX& P.P.
1/7/03 #3 LOW FLOW 1/7/03 REPL EXHAUSTER,METER,WATER LINE MAX& P.P.
1/15/03 #8 NO FLOW 1/15/03 REPL EXHAUSTER,METER,WATER LINE MAX&P.P.
1 0
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MAINTENANCE ACTIVITIES-GROUNDWATER OPERABLE UNIT #1
OUTER TIER SYSTEM
ACTION
DATE WELL# PROBLEM DATE ACTION MECHANIC
1/1/03 #6 NO FLOW ?
.
11
Quarterly O&M Plan Checklist-HNA Holdings, lnc./Shelby, NC
~
""
-
Outer Tier Well
OT-ZR
OT-3
OT-4
OT-5
OT-6
OT-6A
OT-7
OT-8
Ground-Water
Treatment Sys.
- -
Open Sample
Port
X
X
X
X
X
X
X
X
Energize
AS Blower
Y-V-1008
- -
Energize
Pump
X
X
X
X
X
X
X
X
Energize
Transfer Pump
Y-P-1007A
-
Verify De-energize Oose Sample
Discharge Pump Port
X X X
X X X
X X X
X X X
X X X
X X X
X X X
X X X
Energize Energize Energize
Transfer Pump Transfer Pump Transfer Pump
Y-P-10078 Y·P·l008A Y·P-1008B
----
Fonn Completed by: TONY BRYANT
Date: 1/8/03
Verify Heater Secure Well
Operation Vault Comments
X X
X X
X X
X X
X X BAD PUMP
X X
X X
X X
Comments
------ - - -
-------------------
w
Well
OT-ZR
OT-3
OT-4
OT-5
OT-6
OT-6A
OT-7
OT-8
Thermometer
Operational? **
X
X
X
X
X
X
X
X
Monthly O&M Plan Checklist
HNA Holdings, Inc., Shelby, NC
Heat Lamp
Operational? **
X
X
X
X
X
X
X
X
Other Operational Items/Comments
BAD PUMP
(** Temperature and Heat Lamp checks October thru April only)
Form Completed by: __________ T.:...O=-N~Y~B~R-'-YA~N~T~---------
Date: __________ ---=.1.:.../=2/'--'O"-'3'------------
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INNER TIER I DAILY FLOW
I
FEB.
2003 IT-1 IT-2 IT-3 IT-4 IT-5 IT-6 IT-7 IT-8 IT-9 I 02/01103 148 103 135 76 95 90 100 450 520
02102103 136 103 115 66 78 82 87 401 473
02103103 151 115 118 77 146 94 102 473 852 I 02104/03 148 119 132 69 20 91 98 467 246
02105103 144 119 118 82 72 90 97 462 548
02106/03 152 118 122 76 66 91 100 463 427
02107103 140 116 121 66 67 89 96 460 28 I 02108103 175 130 146 103 610 95 98 414 0
02109103 152 129 148 66 89 91 101 359 0
02110103 167 138 160 79 200 94 96 428 395
02111103 162 135 147 86 200 0 103 390 355 I 02112103 161 137 133 85 400 185 93 421 538
02/13103 155 116 117 74 750 85 87 416 482
02/14103 111 130 131 80 286 97 102 470 560 I 02115/03 122 118 152 75 225 92 93 436 526
02116/03 109 115 117 90 190 90 90 400 480
02/17103 159 130 234 103 0 104 83 384 589
02/18/03 230 121 180 241 65 97 96 115 552 I 02119103 260 118 165 102 287 91 88 0 518
02/20/03 . 85 61 90 40 106 47 47 218 281
02/21/03 172 119 189 77 0 91 135 355 508
02122/03 218 125 195 219 11 102 174 386 589 I 02123103 175 125 171 168 102 98 160 439 575
02/24/03 148 81 153 78 165 84 140 434 515
02125103 174 0 150 75 105 90 124 444 531
02126103 187 146 169 105 0 100 135 514 605 I 02127/03 138 121 134 106 0 78 102 401 473
02128/03 175 .148 156 103 203 97 119 459 549
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AVG: 159 116 146 95 162 91 105 395 454 I
TOTAL: 4454 3236 4098 2667 4538 2535 2946 11059 12715
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GROUNDWATER MONTHLY MONITORING:
RAINFALL DATA
FEB 2003 .
DATE INCHES/DAY
02/01/03 0.00
02/02/03 o.oo
02/03/03 0.20
02/04/03 0.00
02/05/03 0.00
02/06/03 0.50
02/07/03 o.oo
02/08/03 0.00
02/09/03 0.10
02/10/03 0.00
02/11/03 0.00
02/12/03 o.oo
02/13/03 0.00
02/14/03 0.30
02/15/03 0.05
02/16/03 0.50
02/17/03 o.oo
02/18/03 0.00
02/19/03 0.00
02/20/03 o.oo
02/21/03 0.20
02/22/03 0.00
02/23/03 o.oo
02/24/03 o.oo
02/25/03 o.oo
02/26/03 0.60
02/27/03 0.20
02/28/03 0.00
TOTAL 2.65
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DAILY REFERENCE SHEET:
DATE: IT. EQ. ·PLT. DEC. DEC. WAS MIX MIX MIX NIT PHOS MIX F/M I FEB. INF. TNK. SEP. LIQ LIQ LIQ ADD ADD LIQ WAS 5/DAY
~ i;QJ1. @12. @11. @12. ~ n.s Ml.Sli lfil eJ:IQll ~ ~ gr, ~ ELM t,,ys;,_
4680 4280 2860 108 19.0 2 200 0 0.00 I 2 4920 4200 4910 185 60 18250 2940 124 50.4 0 0 200 202 0.15
3 4750 3970 5110 170 100 17710 3020 83 12.5 2 200 202 0.15
4 5190 4120 3080 105 16.5 1 2 200 0 0.00
5 5140 3860 4160 178 50 17710 3432 112 20.0 0 2 200 202 0.11 0.08
6 5640 4910 2800 114 18.5 0 2 150 0 0.00 0.08 I 7 8410 4960 3760 177 70 13870 2870 85 19.6 2 140 202 0.12 0.07
8 7070 6000 2500 70 15.0 2 150 0 0.00 0.04
9 6490 4220 4200 175 100 14500 2500 110 26.0 0 0 150 202 0.15 0.07
10 6690 5030 3080 105 16.2 2 150 0 0.00 0.05
11 4750 4820 5400 151 30 15530 3150 122 25.8 0 0 150 202 0.15 0.08 I 12 4180 4810 2660 80 13.5 1 2 150 0 0.00 0.06
13 5220 4950 6020 155 60 14730 3240 131 24.2 0 150 202 0.17 0.09
14 4710 3940 4190 86 20 14320 3330 105 17.7 0 2 150 202 0.11 0.09
15 6090 5480 3160 103 19.0 1 1 140 0 0.00 0.09
16 6120 4370 5030 122 80 16390 2990 114 32.0 0 0 180 202 0.15 0.09 I 17 5180 4310 4020 171 80 13330 3100 125 18.0 0 2 240 202 0.12 0.11
18 5410 4340 3340 116 19.3 0 2 240 0 0.00 0.08
19 5900 5780 5400 206 100 10600 2730 130 30.0 0 0 240 202 0.18 0.09
20 5580 4870 3180 93 17.3 2 260 0 0.00 0.09
21 4980 4140 4550 183 130 9850 3040 106 20.1 0 0 300 202 0.13 0.08 I 22 4050 4360 3920 298 130 11080 2770 105 13.0 2 350 202 0.13 0.09
23 5140 3930 4000 270 30 9110 2990 86 11.2 2 400 202 0.12 0.11
24 5000 3810 2410 53 7.2 2 3 300 0 0,00 0.08
25 4100 3880 3470 420 990 8450 2220 86 18.0 3 300 202 0.14 0.10
26 9310 4900 4110 507 900 7800 2230 89 16.0 3 300 202 0.16 0.11 I 27 5700 4300 2520 83 12.0 2 4 300 0 0.00 0.08
28 4210 4670 4110 364 950 9150 2630 121 27.8 0 0 300 202 0.14 0.09
29 #DIV!OI #DIV/01
30 #DIV/01 #DIV/01
31 #DIV/01 #DIV/01 I AVG: 5522 4543 4242 212 216 12354 2885 102.3 19.9 2 221 123 #DIV/01
MAX: 9310 6000 6020 507 990 18250 3432 131.0 50.4 2 4 400 202 #OIV/01
MIN: 4050 3810 0 0 0 0 2220 53.0 7.2 0 0 140 0 #OIV/01 I
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7124/03
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I INNER TIER COMBINED INFLUENT #2 ITCI
PAGE NO.1
FEB.2003
I DATE: FLOW: PH: COD: TSS: TOC:
GPO pH ppm ppm ppm
I 02/01/03 1717 5.2 4680 9
02/02/03 1543 5.1 4920 4
02/03/03 2128 4.9 4750 9
02/04/03 1390 5.1 5190 7
I 02/05/03 1732 5.1 5140 21 1700
02/06/03 1615 5.0 5640 6
02/07/03 1185 5.0 8410 11
I 02/08/03 1771 5.1 7070 10
02/09/03 1135 5.2 6490 15
02/10/03 1757 5.2 6690 5
I 02/11/03 1778 5.2 4750 4 1450
02/12/03 2153 5.3 4180 5
02/13/03 2282 5.3 5220 7
02/14/03 1967 5.3 4710 6
I 02/15/03 1839 5.3 6090 8
02/16/03 1681 5.3 6120 20
02/17/03 1786 5.3 5180 10
I 02/18/03 1697 5.2 5410 3
02/19/03 1629 5.3 5900 7 2200
02/20/03 975 5.2 5580 5
02/21/03 1646 5.3 4980 14
I 02/22/03 2019 5.3 4050 7
02/23/03 2013 5.3 5140 1
02/24/03 1798 5.2 5000 26
I 02/25/03 1693 5.4 4100 13
02/26/03 1961 5.1 9310 42 3260
02/27/03 1553 5.3 5700 6
02/28/03 2009 5.3 4210 17 I
I AVG: 1730 5.2 5522 11 2153
MAX: 2282 5.4 9310 42 3260
I MIN: 975 4.9 4050 1 1450
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GROUNDWATER MONTHLY MONITORING:
INNER TIER EQUALIZATION TANK: ITEQT I PAGE NO.2
FEB.2003
DATE: PH: COD: OT WATER ADDED I pH ppm gal
02/01/03 7.2 4280
02/02/03 6.8 4200 I 02/03/03 6.9 3970
02/04/03 7.2 4120
02/05/03 6.5 3860 I 02/06/03 6.8 4910
02/07/03 6.6 4960
02/08/03 6.8 6000 I 02/09/03 6.8 4220
02/10/03 7.0 5030
02/11/03 6.9 4820
02/12/03 7.1 4810 I 02/13/03 6.9 4950
02/14/03 7.1 3940 263
02/15/03 7.1 5480 I 02/16/03 7.1 4370
02/17/03 7.3 4310 375
02/18/03 7.2 4340
02/19/03 6.9 5780 I 02/20/03 7.2 4870
02/21/03 6.9 4140
02/22/03 6.9 4630 263 I 02/23/03 6.8 3930 375
02/24/03 7.0 3810
02/25/03 6.9 3880
02/26/03 6.8 4900 I 02/27/03 6.8 4300
02/28/03 6.7 4670
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AVG: 6.9 4553 319 I MAX: 7.3 6000 375
MIN: 6.5 3810 263
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I GROUNDWATER MONTHLY MONITORING:
AFTER PLATE SEPARATOR BEFORE SBR:
PAGE NO. 3
FEB.2003
I DATE: PH: COD: TSS:
pH ppm ppm
I 02/01/03
02/02/03 6.5 4910 4
02/03/03 6.4 5110 24
02/04/03
I 02/05/03 6.1 4160 4
02/06/03
02/07/03 6.0 3760 12
I 02/08/03
02/09/03 6.0 4200 12
02/10/03
I 02/11/03 6.9 5400 20
02/12/03
02/13/03 6.2 6020 20
02/14/03 6.4 4190 16
I 02/15/03
02/16/03 6.8 5030 16
02/17/03 6.6 4020 20
I 02/18/03
02/19/03 6.6 5400 20
02/20/03
02/21/03 5.9 4550 4
I 02/22/03 6.4 3920 8
02/23/03 6.6 4000 36
02/24/03
I 02/25/03 5.8 3470 16
02/26/03 6.4 4110 56
02/27/03
02/28/03 6.0 4110 12
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I AVG: 6.3 4492 18
MAX: 6.9 6020 56
I MIN: 5.8 3470 4
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GROUNDWATER MONTHLY MONITORING: I SBR MIXED LIQUOR: SBRML
PAGE NO. 4
FEB.2003 SETT. SLUDGE 5/DAY
DATE: PH: NH3N: PO4: DO: MLSS: MLVSS: SOLIDS: WASTED F/M: F/M: I pH ppm ppm ppm ppm ppm ml/I gal ratio ratio
02/01/03 8.0 108 19.0 4.7 2860 200 0 0.00 I 02/02/03 8.0 124 50.4 3.7 2940 200 202 0.15
02/03/03 7.8 83 12.5 3.7 3020 200 202 0.15
02/04/03 7.2 105 16.5 4.3 3080 2560 200 0 0.00
02/05/03 8.0 112 20.0 4.7 3432 200 202 0.11 0.08 I 02/06/03 7.9 114 18.5 4.6 2800 150 0 0.00 0.08
02/07/03 7.6 85 · 19.6 4.5 2870 140 202 0.12 0.07
02/08/03 8.1 70 15.0 3.9 2500 150 0 0.00 0.04 I 02/09/03 8.7 110 26.0 7.2 2500 150 202 0.15 0.07
02/10/03 8.2 105 16.2 6.7 3080 150 0 0.00 0.05
02/11/03 8.4 122 25.8 4.5 3150 2580 150 202 0.15 0.08 I 02/12/03 8.3 80 13.5 4.2 2660 150 0 0.00 0.06
02/13/03 8.4 131 24.2 4.7 3240 150 202 0.17 0.09
02/14/03 8.3 105 17.7 4.4 3330 150 202 0.11 0.09
02/15/03 8.2 103 19.0 4.5 3160 140 0 0.00 0.09 I 02/16/03 8.3 114 32.0 3.9 2990 180 202 0.15 0.09
02/17/03 8.5 125 18.0 4.6 3100 240 202 0.12 0.11
02/18/03 8.2 116 19.3 2.8 3340 2800 240 0 0.00 0.08 I 02/19/03 8.3 130 30.0 4.8 2730 240 202 0.18 0.09
02/20/03 8.2 93 17.3 1.1 3180 260 0 0.00 0.09
02/21/03 8.2 106 20.1 4.6 3040 300 202 0.13 0.08
02/22/03 8.2 105 13.0 3.9 2770 350 202 0.13 0.09 I 02/23/03 8.3 86 11.2 4.0 2990 400 202 0.12 0.11
02/24/03 7.9 53 7.2 4.8 2410 300 0 0.00 0.08
02/25/03 8.2 86 18.0 3.4 2220 1810 300 202 0.14 0.10 I 02/26/03 7.9 89 16.0 2.5 2230 300 202 0.16 0.11
02/27/03 8.3 83 12.0 2.6 2520 300 0 0.00 0.08
02/28/03 8.0 121 27.8 4.2 2630 300 202 0.14 0.09
#DIV/0! #DIV/0! I #DIV/0! #DIV/0!
AVG: 8.1 102 20 4 2885 2438 221 123 #DIV/0! #DIV/0! I MAX: 8.7 131 50 ·7 3432 2800 400 202 #DIV/0! #DIV/0!
MIN: 7.2 53 7 2220 1810 140 0 #DIV/0! #DIV/0! I
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I GROUNDWATER MONTHLY MONITORING:
SBR EFFLUENT:(DECANT) #4 SBRE
PAGE NO. 5
FEB.2003 WAS. NH3N PHOS.
I DATE: FLOW: COD: TSS: TSS ADDED: ADDED:
GPD ppm ppm ppm gal lbs
I 02/01/03 0 1 2
. 02/02/03 2574 185 60 18250 0 0
02/03/03 2469 170 100 17710 2
02/04/03 0 2
I 02/05/03 1990 178 50 17710 0 2
02/06/03 0 0 2
02/07/03 2430 177 70 13870 1 2
I 02/08/03 0 1 2
02/09/03 2422 175 100 14500 0 0
02/10/03 0 1 2
I 02/11/03 2484 151 30 15530 0 0
02/12/03 0 2
02/13/03 2371 155 60 14730 o·
02/14/03 2499 86 20 14320 0 2
I 02/15/03 0 1
02/16/03 2383 122 80 16390 0 0
02/17/03 2363 171 80 13330 0 2
I 02/18/03 0 0 2
02/19/03 2046 206 100 10600 0 0
02/20/03 0 1 2
02/21/03 2363 183 120 9850 0 0
I 02/22/03 2275 298 130 11080 1 2
02/23/03 2263 270 30 9110 1 2
02/24/03 0 2 3
I 02/25/03 1875 420 990 8450 3
02/26/03 2625 507 900 7800 3
02/27/03 0 2 4
I 02/28/03 2250 364 950 9150 0 0
I AVG: 1417 225 228 13081 1 2
MAX: 2625 . 507 990 18250 2 4
I MIN: 0 86 20 7800 0 0
DID NOT PROCESS SBR.
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GROUNDWATER MONTHLY MONITORING
INNER TIER CARBON FILTER EFFLUENT #8 ITEF I PAGE NO. 7
FEB.2003
DATE: PH: COD: TOC: TSS: I pH ppm ppm ppm
02/01/03
02/02/03 I 02/03/03 .
02/04/03
02/05/03 8.1 150 10.9 40 I 02/06/03
02/07/03
02/08/03
02/09/03 I 02/10/03
02/11/03 8.3 132 12.6
02/12/03 I 02/13/03
02/14/03
02/15/03 I 02/16/03
02/17/03
02/18/03
02/19/03 8.3 140 57.3 I 02/20/03
02/21/03
02/22/03 I 02/23/03
02/24/03
02/25/03
02/26/03 8.3 165 97.5 I 02/27/03
02/28/03
I
AVG: 8.3 147 44.6 40 I MAX: 8.3 165 97.5 40
MIN: 8.1 132 10.9 40
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MAINTENANCE ACTIVITIES-GROUNDWATER OPERABLE UNIT #1
INNER TIER SYSTEM
ACTION
DATE WELL# PROBLEM DATE ACTION MECHANIC
2/7/03 #5 LOW FLOW 217/03 REPLACED BLADDER MAX& P.P.
2/20/03 #8 LOW FLOW 2/20/03 REPLACED BLADDER EXHAUASTER MAX& P.P.
23
MAINTENANCE ACTIVITIES-GROUNDWATER OPERABLE UNIT #1
OUTER TIER SYSTEM
ACTION
DATE WELL# PROBLEM DATE ACTION . MECHANIC
2/9/03 # 1 no flow 2/28/03 changed pump max &p.p
,
24
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-------------------
"" c..n
Well
OT-ZR
OT-3
OT-4
OT-5
OT-6
OT-GA
OT-7
OT-8
Thermometer
Operational? ""
X
X
X
X
X
X
X
X
Monthly O&M Plan Checklist
HNA Holdings, Inc., Shelby, NC
Heat Lamp
Operational? ""
X
X
X
X
Other Operational Items/Comments
X WELL COLLASPED COULDN'T PULL PUMP
X
X
X
(** Temperature and Heat Lamp checks October thru April only)
Form Completed by: __________ T~O_N_Y_B_R_Y_A_N_T ________ _
Date: __________ ~2~/~3~/0~3~----------
I
INNER TIER I DAILY FLOW
I
MARCH.
2003 IT-1 IT-2 IT-3 IT-4 IT-5 IT-6 IT-7 IT-8 IT-9 I
03/01/03 184 156 179 139 209 105 137 520 638
03/02/03 84 73 82 59 101 46 65 245 301 I 03/03/03 181 153 157 90 163 100 80 459 547
03/04/03 183 156 153 49 266 105 52 526 658
03/05/03 212 152 156 270 249 105 51 504 672 I 03/06/03 193 156 156 0 217 104 49 556 675
03/07/03 186 168 157 129 132 103 50 581 685
03/08/03 181 171 171 60 265 104 48 579 692 I 03/09/03 194 180 178 74 285 106 46 573 737
03/10/03 181 168 166 70 194 99 44 564 683
03/11/03 189 166 159 68 264 95 27 514 639
03/12/03 198 172 183 83 288 100 35 617 732 I 03/13/03 199 153 184 86 281 110 36 616 762
03/14/03 191 150 172 80 269 99 36 600 728
03/15/03 208 159 182 122 293 105 39 612 784 I 03/16/03 125 97 117 78 177 64 25 374 479
03/17/03 209 141 192 140 264 93 22 561 369
03/18/03 208 138 208 198 295 103 27 656 1124 I 03/19/03 288 160 190 250 266 100 229 669 787
03/20/03 308 178 201 129 275 108 0 689 0
-03/21/03 169 143 160 157 222 84 8 401 444
03/22/03 196 187 216 154 192 101 134 424 14 I 03/23/03 194 198 227 17 333 111 194 519 0
03/24/03 191 192 218 69 343 111 224 536 55
03/25/03 198 175 206 66 338 108 235 554 0 I 03/26/03 196 164 202 75 348 108 241 437 0
03/27/03 200 162 192 82 378 110 240 340 0
03/28/03 200 181 186 91 365 109 228 203 441 I 03/29/03 193 176 189 91 364 110 263 293 616
03/30/03 166 154 184 94 343 96 237 217 538
03/31/03 186 157 206 84 359 95 199 201 546
I
AVG: 193 159 178 102 269 100 106 488 495
TOTAL: 5991 4936 5529 3154 8338 3097 3301 15140 15346 I
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26 I
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GROUNDWATER MONTHLY MONITORING:
RAINFALL DATA
MARCH 2003
DATE INCHES/DAY
03/01/03 0.20
03/02/03 0.00
03/03/03 o.oo
03/04/03 0.05
03/05/03 1.50
03/06/03 0.05
03/07/03 o.oo
03/08/03 0.00
03/09/03 0.00
03/10/03 0.00
03/11/03 0.00
03/12/03 0.00
03/13/03 o.oo
03/14/03 0.00
03/15/03 1.10
03/16/03 0.00
03/17/03 0.70
03/18/03 0.00
03/19/03 2.80
03/20/03 0.30
03/21/03 0.00
03/22/03 0.00
03/23/03 0.00
03/24/03 0.00
03/25/03 0.00
03/26/03 0.00
03/27/03 o.oo
03/28/03 0.00
03/29/03 0.90
03/30/03 0.20
03/31/03 o.oo
TOTAL 7.80
27
I
DAILY REFERENCE SHEET: I
DATE: IT. EQ. PLT. DEC. DEC. WAS MIX MIX MIX NIT PHOS MIX FIM
MARCH. INF. TNK. SEP. LIQ LIQ LIQ ADO ADO LIQ WAS 5/0AY I &llD1 @12. @12. @12. @12. ~ na ~ !ill ~ ~ ~ ~ ~ ELM A!&
1 5400 5030 4830 535 180 5350 2610 106 17.5 400 202 0.16
2 5910 4960 2300 133 16.8 0 400 0 0.00
3 4530 3830 3430 304 170 7740 2410 103 18.6 1 2 400 202 0.13 I 4 7750 4590 3990 277 150 7600 2790 131 16.6 0 2 400 202 0.13
5 4450 3560 3900 308 610 8340 2060 110 14.0 1 3 400 202 0.17 0.12
6 3830 3650 2610 258 750 6970 2930 125 20.3 0 0 400 202 0.08 0.10
7 7500 4590 3850 184 110 7120 2200 105 9.0 2 2 310 202 0.16 0.13
8 4330 3360 3640 177 60 13850 2510 118 22.0 1 0 300 202 0.13 0.13 I 9 5350 3850 4270 171 290 2250 157 15.0 0 0 300 0 0.17 0.14
10 3620 4190 2150 92 10.0 2 4 300 0 0.00 0.11
11 4450 4100 4180 180 80 11790 2450 128 28.5 1 2 280 202 0.15 0.12
12 4960 4100 4250 169 100 8950 2120 126 23.2 0 2 280 202 0.18 0.13
13 5310 3620 ,3420 157 120 8930 2620 100 25 1 2 300 202 0.12 0.12 I 14 5110 4400 4920 178 120 6720 1970 120 19 0 2 350 202 0.22 0.13
15 6040 4360 3340 190 160 6240 1900 95 12 2 350 202 0.16 0.16
16 3760 3890 1710 75 12.4 2 2 350 0 0,00 0.13
17 4640 3750 2980 233 260 6310 2390 89 17.6 2 4 350 202 0.11 0.12
18 4450 3650 4050 316 270 7050 2250 133 28.3 0 0 400 202 0.16 0.13 I 19 4360 3800 4520 304 190 5880 1870 96 13.7 3 270 202 0.21 0.13
20 2390 2910 3570 247 80 8660 1800 112 22.1 1 2 260 202 0.18 0.13
21 8070 4030 1880 125 23.0 1 2 250 0 0.00 0.13
22 4620 4040 4380 223 100 8490 1850 162 37.0 0 0 250 202 0.21 0.15
23 7060 4210 3530 196 90 10600 1740 123 16.5 1 3 250 202 0.18 0.16 I 24 6530 5070 1890 125 18.0 0 2 250 0 0.00 0.11
25 7630 5230 3410 192 80 11000 1440 139 30.7 0 0 180 202 0.21 0.12
26 5820 6410 5330 164 50 10250 2310 105 6.7 3 160 202 0.21 0.16
27 6700 5520 2250 117 11.8 1 3 150 0 0.00 0.12
28 7900 6250 5670 143 80 9310 1950 137 24.9 0 2 160 202 0.26 0.13 I 29 4620 5960 3660 161 30 11710 2530 115 16.0 1 200 170 0.13 0.16
30 4730 4990 2260 160 25.0 0 0 190 0 0.00 0.12
31 7300 4900 4830 212 30 11980 1720 122 20.1 2 220 202 0.25 0.13
AVG: 5455 4413 3862 219 166 8368 2165 118.8 19.1 2 292 149 0.13 I MAX: 8070 6410 5670 535 750 13850 2930 162.0 37.0 ' 4 400 202 0.26
MIN: 2390 2910 0 0 0 0 1440 75.0 6.7 0 0 150 0 0.00
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4/28/03
28 I
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I INNER TIER COMBINED INFLUENT #2 ITCI
PAGE NO.1
MARCH.2003
I DATE: FLOW: PH: COD: TSS: TOC:
GPO pH ppm ppm ppm
I 03/01/03 2267 5.3 5400 10
03/02/03 1056 5.3 5910 11
03/03/03 1957 5.3 4530 14
03/04/03 2148 5.3 7750 12 1580
I 03/05/03 2371 5.4 4450 10
03/06/03 2106 5.2 3830 15
03/07/03 2191 5.3 7500 5
I 03/08/03 2271 5.4 4330 12
03/09/03 2372 5.3 5350 10
03/10/03 2165 5.4 3620 9
03/11/03 2121 5.3 4450 5
I 03/12/03 2408 5.2 4960 11 1490
03/13/03 2427 5.3 5310 11
03/14/03 2325 5.4 5110 10
I 03/15/03 2504 5.3 6040 10
03/16/03 1536 5.3 3760 11
03/17/03 1991 5.4 4640 13
03/18/03 2957 5.4 4450 15
I 03/19/03 2939 5.5 4360 8 1420
03/20/03 1888 5.4 2390 15
03/21/03 1788 5.3 8070 10
I 03/22/03 1618 5.3 4620 19
03/23/03 1793 5.3 7060 17
03/24/03 1939 5.2 6530 5
I 03/25/03 1880 5.2 7630 12 2430
03/26/03 1880 5.3 5820 12
03/27/03 1703 5.3 6700 23
03/28/03 2004 5.2 7900 10
I 03/29/03 2295 5.3 4620 9
03/30/03 2029 5.3 4730 9
03/31/03 2033 5.2 7300 23
I AVG: 2096 5.3 5455 12 1730
MAX: 2957 5.5 8070 23 2430
MIN: 1056 5.2 2390 5 1420
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GROUNDWATER MONTHLY MONITORING: I INNER TIER EQUALIZATION TANK: ITEQT
PAGE NO. 2
MARCH.2003
DATE: PH: COD: OT WATER ADDED I pH ppm gal
03/01/03 7.0 5030 I 03/02/03 7.0 4960
03/03/03 7.1 3830
03/04/03 7.1 4590
03/05/03 5.8 3560 I 03/06/03 5.5 3650 300
03/07/03 7.2 4590
03/08/03 7.1 3360 I 03/09/03 7.1 3850
03/10/03 7.1 4190
03/11/03 6.9 4100
I 03/12/03 6.9 4100
03/13/03 6.5 3620
03/14/03 6.6 4400 338
03/15/03 6.8 4360 450 I 03/16/03 6.9 3890
03/17/03 6.9 3750
03/18/03 6.8 3650 I 03/19/03 7.2 3800
03/20/03 7.1 2910
03/21/03 7.1 4030
03/22/03 7.0 4040 I 03/23/03 6.9 4210 375
03/24/03 6.8 5070
03/25/03 6.8 5230 I 03/26/03 7.0 6410 375
03/27/03 7.0 5520
03/28/03 7.0 6250
03/29/03 7.0 5960 300.0 I 03/30/03 7.3 4990
03/31/03 7.0 4900
AVG: 6.9 4413 356 I MAX: 7.3 6410 450
MIN: 5.5 2910 300
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30 I
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GROUNDWATER MONTHLY MONITORING: I AFTER PLATE SEPARATOR BEFORE SBR:
PAGE NO. 3
MARCH.2003
I DATE: PH: COD: TSS:
pH ppm ppm
I 03/01/03 7.0 4830 26
03/02/03
03/03/03 6.0 3430 16
03/04/03 6.0 3990 16
I 03/05/03 6.2 3900 4
03/06/03 5.4 2610 16
03/07/03 6.5 3850 12
I 03/08/03 6.6 3640 12
03/09/03 6.8 4270 24
03/10/03
03/11/03 6.3 4180 16
I 03/12/03 6.1 4250 12
03/13/03 6.5 3420 28
03/14/03 6.1 4920 20
I 03/15/03 7.0 3340 24
03/16/03
03/17/03 5.4 2980 4
I 03/18/03 5.8 4050 12
03/19/03 6.1 4520 4
03/20/03 6.0 3570 8
03/21/03
I 03/22/03 6.5 4380 16
03/23/03 6.5 3530 20
03/24/03
I 03/25/03 6.8 3410 32
03/26/03 6.2 5330 16
03/27/03
03/28/03 6.3 5670 40
I 03/29/03 6.0 3660 28
03/30/03
03/31/03 6.0 4830 4
I AVG: 6.3 4023 17
MAX: 7.0 5670 40
MIN: 5.4 2610 4
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GROUNDWATER MONTHLY MONITORING:
SBR MIXED LIQUOR: SBRML I PAGE NO.4
MARCH.2003 SETT. SLUDGE 5/DAY
DATE: PH: NH3N: PO4: DO: MLSS: MLVSS: SOLIDS: WASTED F/M: F/M: I pH ppm ppm ppm ppm ppm ml/I gal ratio ratio
03/01/03 8.1 106 17.5 0.5 2610 400 202 0.16
03/02/03 8.0 133 16.8 1.6 2300 400 0 0.00 I 03/03/03 8.4 103 18.6 4.1 2410 400 202 0.13
03/04/03 8.3 131 16.6 1.2 2790 2130 400 202 0.13
03/05/03 8.3 110 14.0 2.4 2060 400 202 0.17 0.12 I 03/06/03 8.3 125 20.3 0.2 2930 400 202 0.08 0.10
03/07/03 8.3 105 9.0 4.7 2200 310 202 0.16 0.13
03/08/03 8.0 118 22.0 3.6 2510 300 202 0.13 0.13
03/09/03 8.4 157 15.0 4.1 2250 300 0 0.17 0.14 I 03/10/03 8.3 92 10.0 4.6 2150 300 0 0.00 0.11
03/11/03 8.4 128 28.5 5.0 2450 1800 280 202 0.15 0.12
03/12/03 8.1 126 23.2 2.0 2120 280 202 0.18 0.13 I 03/13/03 8.2 100 25.0 3.7 2620 300 202 0.12 0.12
03/14/03 8.2 120 19.0 3.7 1970 350 202 0.22 0.13
03/15/03 8.2 95 12.0 4.4 1900 350 202 0.16 0.16
03/16/03 8.2 75 12.4 4.0 1710 350 0 0.00 0.13 I 03/17/03. 8.0 89 17.6 1.2 2390 350 202 0.11 0.12
03/18/03 8.4 133 28.3 3.7 2250 1690 400 202 0.16 0.13
03/19/03 8.5 96 13.7 3.8 1870 270 202 0.21 0.13 I 03/20/03 8.2 112 22.1 3.8 1800 260 202 0.18 0.13
03/21/03 8.4 125 23.0 4.4 1880 250 0 0.00 0.13
03/22/03 8.6 162 37.0 4.5 1850 250 202 0.21 0.15 I 03/23/03 8.5 123 16.5 4.5 1740 250 202 0.18 0.16
03/24/03 8.3 125 18.0 4.7 1890 250 0 0.00 0.11
03/25/03 8.3 139 30.7 5.4 1440 1160 180 202 0.21 0.12
03/26/03 8.3 105 6.7 4.9 2310 160 202 0.21 0.16 I 03/27/03 8.3 117 11.8 4.8 2250 150 0 0.00 0.12
03/28/03 8.3 137 24.9 5.2 1950 160 202 0.26 0.13
03/29/03 8.2 115 16.0 3.7 2530 200 170 0.13 0.16 I 03/30/03 8.3 160 25.0 4.0 2260 190 0 0.00 0.12
03/31/03 4.3 122 20.1 4.3 1720 220 202 0.25 0.13
AVG: 8.1 119 19 4 2165 1695 292 149 0.13 0.13 I MAX: 8.6 162 37 5 2930 2130 400 202 0.26 0.16
MIN: 4.3 75 7 0 1440 1160 150 0 0.00 0.10
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I GROUNDWATER MONTHLY MONITORING:
SBR EFFLUENT:(DECANT) #4 SBRE
PAGE NO. 5
MARCH.2003 WAS. NH3N PHOS.
I DATE: FLOW: COD: TSS: TSS ADDED: ADDED:
GPO ppm ppm ppm gal lbs
I 03/01/03 2288 535 180 5350
. 03/02/03 0 0
03/03/03 2475 304 170 7740 1 2
03/04/03 2372 277 150 7600 0 2
I 03/05/03 2408 308 610 8340 1 3
03/06/03 2250 258 750 6970 0 0
03/07/03 2205 184 110 7120 2 2
I 03/08/03 1765 177 60 13850 0
03/09/03 2054 171 290 0 0
03/10/03 0 2 4
I 03/11/03 2535 180 80 11790 1 2
03/12/03 2497 169 100 8950 0 2
03/13/03 2338 157 120 8930 2
03/14/03 2374 178 120 6720 0 2
I 03/15/03 2138 190 120 6240 1 2
03/16/03 0 2 2
03/17/03 2100 233 260 6310 2 4
I 03/18/03 1988 316 270 7050 0 0
03/19/03 2401 304 190 5880 3
03/20/03 2357 247 80 8660 2
03/21/03 0 1 2
I 03/22/03 2213 223 100 8490 0 0
03/23/03 2109 196 90 10600 1 3
03/24/03 0 0 2
I 03/25/03 2588 192 80 11000 0 0
03/26/03 2558 164 50 10250 1 3
03/27/03 0 1 3
I 03/28/03 1950 143 80 9310 0 2
03/29/03 2497 161 30 11710 1 1
03/30/03 0 0 0
03/31/03 2469 212 30 11980 1.0 2.0
I AVG: 1772 228 172 8732 2
MAX: 2588 . 535 750 13850 2 4
I MIN: 0 143 30 5350 0 0
DID NOT PROCESS SBR.
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GROUNDWATER MONTHLY MONITORIN(
INNER TIER CARBON FILTER EFFLUENT #8 ITEF I PAGE NO. 7
MARCH.2003
DATE: PH: COD: TOG: TSS: I pH ppm ppm ppm
03/01/03 I 03/02/03
03/03/03
03/04/03 8.4 250 90.7 180
03/05/03 I 03/06/03
03/07/03
03/08/03 I 03/09/03
03/10/03
03/11/03
03/12/03 8.3 145 11.6 I 03/13/03
03/14/03
03/15/03 I 03/16/03
03/17/03
03/18/03
03/19/03 7.7 210 36.9 I 03/20/03
03/21/03
03/22/03 I 03/23/03
03/24/03
03/25/03 7.6 137 55.1
03/26/03 I 03/27/03
03/28/03
03/29/03 I 03/30/03
03/31/03
AVG: 8.0 186 48.6 180 I MAX: 8.4 250 90.7 180
MIN: 7.6 137 11.6 180
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MAINTENANCE ACTIVITIES-GROUNDWATER OPERABLE UNIT #1
INNER TIER SYSTEM
ACTION
DATE WELL# PROBLEM DATE ACTION MECHANIC
3/21/03 #7 LOW FLOW 3/21/03 REPLACED BLADDER MAX & P.P.
3/21 /03 #9 LOW FLOW 3/21/03 CLEANED PROBES & ADJ. CONTROLS MAX&P.P.
35
MAINTENANCE ACTIVITIES-GROUNDWATER OPERABLE UNIT #1
OUTER TIER SYSTEM
ACTION
DATE WELL# PROBLEM DATE ACTION
3/1/03 # 1 CONTROL BAD ? PARTS ORDERED
36
MECHANIC
' ..
max & p.p.
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-------------------
c:,,:, ___,
Well
OT-ZR
OT-3
OT-4
OT-5
OT-6
OT-6A
OT-7
OT-8
Thermometer
Operational? **
X
X
X
X
X
X
X
X
Monthly O&M Plan Checklist
HNA Holdings, Inc., Shelby, NC
Heat Lamp
Operational? **
X
X
X
X
Other Operational Items/Comments
X COULDN'T PULL PUMP WELL COLLASPED
X
X
X
(** Temperature and Heat Lamp checks October thru April only)
Form Completed by: __________ c..TO-=-'-'NY~B~R-'-YA~N'-'T~---------
Date: 3/5/03 ----------~-------------
I
INNER TIER I DAILY FLOW
I
APRIL.
2003 IT-1 IT-2 IT-3 IT-4 IT-5 IT-6 IT-7 IT-8 IT-9 I
04/01/03 193 155 209 79 368 68 229 188 619
04/02/03 68 157 201 76 437 67 223 166 631
04/03/03 0 156 198 85 332 72 217 180 650 I 04/04/03 137 152 193 108 372 75 214 42 661
04/05/03 192 143 185 103 388 72 197 0 653
04/06/03 39 50 50 7 58 8 50 0 107 I 04/07/03 34 127 237 255 460 87 199 370 716
04/08/03 0 137 225 337 395 68 217 490 702
04/09/03 4 71 214 203 419 67 247 495 708
04/10/03 2 252 209 211 413 66 237 496 699 I 04/11/03 210 188 206 261 408 64 233 496 739
04/12/03 255 189 213 185 233 68 233 500 765
04/13/03 205 182 218 133 50 68 32 487 746 I 04/14/03 221 177 203 130 90 75 253 487 739
04/15/03 251 169 203 122 1 89 357 489 721
04/16/03 249 165 192 122 317 87 365 495 743
04/17/03 313 171 202 125 401 88 283 525 674 I 04/18/03 280 151 199 194 334 73 235 480 0
04/19/03 253 167 189 148 355 77 247 480 0
04/20/03 251 184 224 129 362 75 272 479 0
04/21/03 252 184 223 148 372 75 275 461 16 I 04/22/03 260 181 245 90 380 75 281 480 17
04/23/03 237 158 220 35 343 63 241 417 0
04/24/03 256 160 223 45 357 81 87 485 0 I 04/25/03 263 169 240 200 368 89 60 462 0
04/26/03 254 152 238 54 433 88 59 463 0
04/27/03 250 150 236 84 457 70 58 464 0
04/28/03 251 148 237 216 396 52 60 480 0 I 04/29/03 178 145 208 7 412 70 61 448 0
04/30/03 184 139 183 0 391 76 55 442 0
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AVG: 184 158 207 130 337 72 193 398 377
TOTAL: 5533 4729 6223 3892 10102 2153 5777 11947 11306 I
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GROUNDWATER MONTHLY MONITORING:
RAINFALL DATA
DATE INCHES/DAY
04/01/03 0.00
04/02/03 0.00
04/03/03 0.00
04/04/03 0.00
04/05/03 0.30
04/06/03 1.90
04/07/03 0.30
04/08/03 0.90
04/09/03 0.70
04/10/03 1.60
04/11/03 0.00
04/12/03 o.oo
04/13/03 0.00
04/14/03 o.oo
04/15/03 o.oo
04/16/03 0.00
04/17/03 2.50
04/18/03 0.30
04/19/03 o.oo
04/20/03 0.00
04/21/03 0.05
04/22/03 0.00
04/23/03 o.oo
04/24/03 0.00
04/25/03 1.50
04/26/03 0.05
04/27/03 0.00
04/28/03 0.00
04/29/03 0.00
04/30/03 0.10
0.00
TOTAL 10.20
39
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DAILY REFERENCE SHEET: I
DATE: IT. EQ. PLT. DEC. DEC. WAS MIX MIX MIX NIT PHOS MIX F/M
april. INF. TNK. SEP. LIQ LIQ LIQ ADD ADD LIQ WAS 5/DAY I
~ COD. @!!. COD. COD. ~ .Il§. MLSS NIT fl:IQS. ~ LBS SET. GA!.$. ELM AYS;,.
1 5200 4560 5290 193 90 9270 2070 130 17.5 0 2 220 202 0.23
2 5530 5050 5060 225 150 11270 2670 96 19.6 2 200 202 0.17 I 3 5440 3620 4540 219 140 8310 2560 92 12.2 2 200 202 0.16
4 6640 4230 4460 217 60 9660 2630 102 16.1 2 200 202 0.15
5 5670 3830 3660 216 140 10060 2400 119 20.0 2 200 202 0.14 0.17
6 5430 3810 2000 101 15.7 2 200 202 0.00 0.12 I 7 6280 4540 4530 226 90 11010 1930 126 26.3 2 200 202 0.21 0.13
6 3090 3590 3960 272 130 10590 2420 79 12.3 1 2 200 202 0.15 0.13
9 4260 3650 3360 249 390 11550 2540 146 26.3 0 0 200 202 0.12 0.12
10 3560 3560 4270 270 140 7420 2350 125 16.0 0 0 200 202 0.16 0.13
11 5350 3460 5260 263 100 7960 2410 105 16.0 1 200 202 0.19 0.17 I 12 5400 4600 4850 224 120 9200 2164 125 11.0 1 200 202 0.20 0.16
13 5750 4950 5050 234 100 6060 2200 100 10.0 2 200 202 0.20 0.18
14 6310 4210 4500 257 140 13440 2470 116 20.3 2 160 202 0.16 0.18
15 5460 2900 3200 261 190 12710 2920 123 20.7 2 160 202 0.10 0.17 I 16 5190 4460 4060 293 130 11640 1770 91 16.0 2 140 202 0.20 0.17
17 5650 4340 4000 265 220 4760 2020 97 17.3 2 140 202 0.16 0.17
16 3260 4190 3690 269 70 10040 2520 123 16 1 1 200 200 0.14 0.16
19 7320 4520 2170 160 39.0 0 0 160 0 0.00 0.12
20 8310 5660 5460 245 220 14540 2000 140 36.0 1 0 160 202 0.24 0.15 I 21 6250 5540 5230 327 160 12840 2320 115 29.2 0 0 130 202 0.20 0.15
22 5770 5490 2080 114 20.0 2 130 0 0.00 0.12
23 7450 5200 3250 250 130 11620 2060 130 29.6 0 0 130 202 0.14 0.12
24 7570 6660 5720 446 170 13890 2230 114 30.1 0 0 130 202 0.23 0.16 I 25 8130 5210 2560 91 17.5 1 2 160 0 0.00 0.11
26 4560 5800 6660 332 140 9810 2310 91 21.5 2 140 202 . 0.26 0.12
27 8210 7190 1670 96 15.0 2 140 0 0.00 0.12
26 7580 6050 5560 313 310 6690 2450 109 25.3 2 140 202 0.20 0.14 I 29 7190 5520 2552 125 10.7 0 2 140 0 0.00 0.09
30 7590 6790 6600 290 120 9520 2700 124 21.0 0 0 140 202 0.22 0.14
31 #DIV/0! #DIV/QI
AVG: 6054 4781 4696 266 154 10246 2312 113.6 20.3 172 166 #OIV/01 I MAX: 8840 7190 6660 446 390 14540 2920 160.0 39.0 2 220 202 #OIV/0!
MIN: 3090 2900 3200 193 70 4760 1770 79.0 10.0 0 0 130 0 #DIV/0!
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6/17/03
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I INNER TIER COMBINED INFLUENT #2 ITCI
PAGE N0.1
I april.2003
DATE: FLOW: PH: COD: TSS: TOC:
GPO pH ppm ppm ppm
I 04/01/03 2108 5.1 5200 6
04/02/03 2026 5.2 5530 8 2150
04/03/03 1890 5.1 5440 14
I 04/04/03 1954 5.1 8840 24
04/05/03 1933 5.1 5670 20
04/06/03 360 5.1 5430 18
I 04/07/03 2485 5.2 6280 40
04/08/03 2573 5.4 3090 8
04/09/03 2428 5.3 4260 9 1680
04/10/03 2585 5.4 3580 12
I 04/11/03 2805 5.3 5350 7
04/12/03 2641 5.2 5400 7
04/13/03 2121 5.2 5750 6
I 04/14/03 2375 5.1 6310 10
04/15/03 2403 5.1 5460 17
04/16/03 2735 5.1 5190 10 2050
I 04/17/03 2782 5.1 5650 10
04/18/03 1926 5.0 3260 16
04/19/03 1916 5.2 7320 20
04/20/03 1976 5.1 8310 7
I 04/21/03 2006 5.1 6250 20 2590
04/22/03 2009 5.2 5770 25
04/23/03 1714 5.1 7450 16
I 04/24/03 1674 5.1 7570 21
04/25/03 1851 5.1 8130 23
04/26/03 1741 5.1 4560 26
04/27/03 1769 5.1 8210 14
I 04/28/03 1820 5.1 7580 21
04/29/03 7590 5.0 7190 24
04/30/03 1470 5.1 7590 20 3040
I AVG: 2256 5.1 6054 16 2302
I MAX: 7590 5.4 8840 40 3040
MIN: 360 5.0 3090 6 1680
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GROUNDWATER MONTHLY MONITORING: I INNER TIER EQUALIZATION TANK: ITEQT
PAGE NO.2
april.2003 I DATE: PH: COD: OTWATERADDED
pH ppm gal
04/01/03 7.2 4560 I 04/02/03 7.3 5050
04/03/03 7.3 3620 375
04/04/03 7.1 4230 375 I 04/05/03 7.1 3830 375
04/06/03 7.1 3810
04/07/03 7.3 4540 300
04/08/03 7.1 3590 300 I 04/09/03 7.2 3650 150
04/10/03 7.1 3560
04/11/03 7.0 3460 I 04/12/03 7.4 4600 188
04/13/03 7.4 4950 188
04/14/03 7.8 4210 375 I 04/15/03 8.0 2900 450
04/16/03 8.1 4480 375
04/17/03 8.0 4340 188
04/18/03 8.7 4190 I 04/19/03 8.6 4520
04/20/03 8.7 5880
04/21/03 8.6 5540 488 I 04/22/03 8.3 5490
04/23/03 8.3 5200
04/24/03 6.4 6660 375
04/25/03 8.5 5210 I 04/26/03 5.4 5800
04/27/03 5.1 7190
04/28/03 5.0 6050 I 04/29/03 6.7 5520
04/30/03 8.3 6760
AVG: 7.4 4780 322 I
MAX: 8.7 7190 488
MIN: 5.0 2900 150 I
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I GROUNDWATER MONTHLY MONITORINC
AFTER PLATE SEPARATOR BEFORE SB~
PAGE NO. 3
I april.2003
DATE: PH: COD: TSS:
pH ppm ppm
I 04/01/03 5.7 5290 8
04/02/03 5.5 5080 7
04/03/03 5.8 4540 20
I 04/04/03 5.5 4460 4
04/05/03 5.7 3880 24
04/06/03
I 04/07/03 5.7 4530 4
04/08/03 6.1 3960 36
04/09/03 6.4 3360 8
04/10/03 6.6 4270 12
I 04/11/03 6.5 5280 8
04/12/03 7.0 4850 8
04/13/03 6.8 5050 16
I 04/14/03 5.6 4500 8
04/15/03 6.5 3200 32
04/16/03 6.2 4060 8
04/17/03 5.6 4000 32
I 04/18/03 5.8 3890 12
04/19/03
04/20/03 7.3 5460 76
I 04/21/03 6.2 5230 132
04/22/03
04/23/03 5.4 3250 20
04/24/03 6.2 5720 40
I 04/25/03
04/26/03 5.4 6660 32
04/27/03
I 04/28/03 5.2 5580 4
04/29/03
04/30/03 5.1 6600 56
I AVG: 6.0 4696 25
MAX: 7.3 6660 132
I MIN: 5.1 3200 4
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GROUNDWATER MONTHLY MONITORING: I SBR MIXED LIQUOR: SBRML
PAGE NO.4
april.2003 SETT. SLUDGE 5/DAY I DATE: PH: NH3N: PO4: DO: MLSS: MLVSS: SOLIDS: WASTED F/M: F/M:
pH ppm ppm ppm ppm ppm ml/I gal ratio ratio
04/01/03 8.2 130 17.5 5.0 2070 1510 220 202 0.23 I 04/02/03 8.2 96 19.6 4.6 2670 200 202 0.17
04/03/03 8.2 92 12.2 4.4 2560 200 202 0.16
04/04/03 7.8 102 16.1 4.4 2630 200 202 0.15 I 04/05/03 8.3 119 20.0 4.1 2400 200 202 0.14 0.17
04/06/03 8.3 101 15.7 4.2 2000 200 202 0.00 0.12
04/07/03 8.4 126 26.3 5.6 1930 200 202 0.21 0.13
04/08/03 8.2 79 12.3 5.0 2420 1780 200 202 0.15 0.13 I 04/09/03 8.3 148 26.3 5.0 2540 200 202 0.12 0.12
04/10/03 8.2 125 16.0 3.2 2350 200 202 0.16 0.13
04/11/03 8.2 105 16.0 4.0 2410 200 202 0.19 0.17 I 04/12/03 8.1 125 11.0 4.8 2164 200 202 0.20 0.16
04/13/03 8.1 100 10.0 4.2 2200 200 202 0.20 0.18
04/14/03 8.1 118 20.3 4.7 2470 180 202 0.16 0.18
04/15/03 8.2 123 20.7 3.7 2920 2260 160 202 0.10 0.17 I 04/16/03 8.1 91 18.0 5.1 1770 140 202 0.20 0.17
04/17/03 8.5 97 17.3 7.2 2020 140 202 0.18 0.17
04/18/03 8.1 123 16.0 4.3 2520 200 200 0.14 0.16 I 04/19/03 8.1 160 39.0 4.7 2170 180 0 0.00 . 0.12
04/20/03 8.1 140 38.0 4.3 2000 160 202 0.24 0.15
04/21/03 8.0 115 29.2 3.6 2320 130 202 0.20 0.15 I 04/22/03 7.8 114 20.0 3.5 2080 1650 130 0 0.00 0.12
04/23/03 8.1 130 29.8 3.5 2060 130 202 0.14 0.12
04/24/03 8.2 114 30.1 3.3 2230 130 202 0.23 0.16
04/25/03 8.3 91 17.5 3.2 2580 160 0 0.00 0.11 I 04/26/03 8.3 91 21.5 3.7 2310 140 202 0.26 0.12
04/27/03 8.3 96 15.0 4.1 1870 140 0 0.00 0.12
04/28/03 8.2 109 25.3 3.4 2450 140 202 0.20 0.14 I 04/29/03 8.2 125 10.7 3.6 2552 1624 140 0 0.00 0.09
04/30/03 8.3 124 21.0 4.2 2700 140 0.22 0.14
AVG: 8.2 114 20 4 2312 1765 172 167 0.14 0.14 I
MAX: 8.5 160 39 7 2920 2260 220 202 0.26 0.18
MIN: 7.8 79 10 3 1770 1510 130 0 0.00 0.09 I
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SBR EFFLUENT:(DECANT) #4 SBRE
PAGE NO.5
I april.2003 WAS. NH3N PHOS.
DATE: FLOW: COD: TSS: TSS ADDED: ADDED:
GPO ppm ppm ppm gal lbs
I 04/01/03 2625 193 90 9270 0 2
04/02/03 2228 225 150 11270 1 2
04/03/03 2250 219 140 8310 2
I 04/04/03 2063 217 80 9660 2
04/05/03 2063 218 140 10080 2
04/06/03 0 2
I 04/07/03 2116 226 90 11010 2
· 04/08/03 2334 272 130 10590 1 2
04/09/03 2250 249 390 11550 0 0
04/10/03 2384 270 140 7420 0 0
I 04/11/03 2300 263 100 7960 1
04/12/03 2378 224 120 9200 1 1
04/13/03 2284 234 100 8080 2
I 04/14/03 2213 257 140 13440 2
04/15/03 2063 261 190 12710 2
04/16/03 2348 293 130 11640 2
I 04/17/03 2348 265 220 4760 2
04/18/03 2249 289 70 10040 1 1
04/19/03 0 0 0
04/20/03 2074 245 220 14540 0
I 04/21/03 2738 327 180 12840 0 0
04/22/03 0 1 2
04/23/03 2257 250 130 11620 0 0
I 04/24/03 2708 446 170 13890 0 0
04/25/03 0 2
04/26/03 2259 332 140 9810 2
04/27/03 0 2
I 04/28/03 2813 313 310 6690 1 2
04/29/03 0 0 2
04/30/03 2289 290 120 9520 0 0
I AVG: 1854 266 154 10246 1 1
I MAX: 2813 446 390 14540 1 2
MIN: 0 193 70 4760 0 0
• DID NOT PROCESS SBR .
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GROUNDWATER MONTHLY MONITORINC I INNER TIER CARBON FILTER EFFLUENT #8 ITEF
PAGE NO. 7
april.2003 I DATE: PH: COD: TOC: TSS:
pH ppm ppm ppm
04/01/03 I 04/02/03 8.1 184 155 100
04/03/03
04/04/03 I 04/05/03
04/06/03
04/07/03 I 04/08/03
04/09/03 8.2 240 157
04/10/03
04/11/03 I 04/12/03
04/13/03
04/14/03 I 04/15/03
04/16/03 8.0 246 141
04/17/03
I 04/18/03
04/19/03
04/20/03
04/21/03 I 04/22/03
04/23/03 8.0 225 432
04/24/03 I 04/25/03
04/26/03
04/27/03
04/28/03 I 04/29/03
04/30/03 8.0 265 187
AVG: 8.1 232 214 100 I
MAX: 8.2 265 432 100
MIN: 8.0 184 141 100 I
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MAINTENANCE ACTIVITIES-GROUNDWATER OPERABLE UNIT #1
INNER TIER SYSTEM
ACTION
DATE WELL# PROBLEM DATE ACTION MECHANIC
4/11/03 # 1 LOW FLOW 4/11/03 NEW METER MAX&P.P.
4/15/03 #5 LOW FLOW 4/15/03 REPLACED EXHUSTER MAX&P.P.
4/22/03 #9 NO FLOW 4/22/03 ORDER PUMP MAX&P.P.
47
MAINTENANCE ACTIVITIES-GROUNDWATER OPERABLE UNIT #1
OUTER TIER SYSTEM
ACTION
DATE WELL# PROBLEM DATE ACTION
4/1T05/1 #1 CONTROL BAD ? PARTS ORDERED
48
MECHANIC
max & p.p.
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-"'-CD
---------
Quarterly O&M Plan Checklist-HNA Holdings, lnc./Shelby, NC
Outer Tier Well
OT-ZR
OT-3
OT-4
OT-5
OT-6
OT-6A
OT-7
OT-8
Ground-Water
Treatment Sys.
Open Sample
Port
X
X
X
X
X
X
X
X
Energize
AS Blower
Energize Verify De-energize Close Sample
Pump Discharge Pume Port
X X X X
X X X X
X X X X
X X X X
X X X X
X X X X
X X X X
X X X X
Energize Energize Energize Energize
Transfer Pump Transfer Pump Transfer Pump Transfer Pump
Y-P-1 007A Y-P-10078 Y-P-1008A Y-P-10088
---------
Form Completed by: TONY BRYANT
Date: 4/2/03
Verify Heater Secure Well
Operation Vault Comments
X X
X X
X X
X X
X X
X X
X X
X X
Comments
'-" =
---
Well
OT-ZR
OT-3
OT-4
OT-5
OT-6
OT-6A
OT-7
OT-8
Thermometer
Operational? **
X
X
X
X
X
X
X
X
Monthly O&M Plan Checklist
HNA Holdings, Inc., Shelby, NC
Heat Lamp
Operational? **
X
X
X
X
X
X
X
X
Other Operational Items/Comments
(** Temperature and Heat Lamp checks October thru April only)
Form Completed by: _________ _,T"O,_,N.,_Y_sBe:,R.,_YAc,N,,..T,_ _______ _
Date: __________ _:4,cl_,c2/c,Oec3'--------~-
- --- -
.. - ---------
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I INNER TIER
DAILY FLOW
I
May
I 2003 IT-1 IT-2 IT-3 IT-4 IT-5 IT-6 IT-7 IT-8 IT-9
05/01103 247 129 190 0 354 72 54 428 0
05102/03 206 126 193 75 350 76 50 429 0
I 05/03/03 241 122 194 86 325 72 50 430 0
05/04103 252 110 180 66 304 75 48 414 14
05105/03 254 111 181 57 325 70 51 418 0
05/06/03 256 104 190 139 372 74 49 418 0 I 05/07/03 244 101 187 165 365 75 47 399 0
05/08/03 198 105 190 96 341 75 47 386 0
05/09/03 197 91 202 77 341 76 47 401 0
I 05/10/03 186 87 229 74 360 79 44 385 0
05/11/03 263 85 238 70 340 77 43 397 0
05/12/03 255 79 228 73 374 74 44 393 0
05/13/03 243 22 215 88 425 72 41 379 0
I 05/14/03 200 27 176 105 300 100 44 400 0
05/15/03 257 131 244 46 553 32 36 368 0
05/16/03 0 84 214 47 387 82 40 389 14
05/17/03 0 82 215 28 432 76 42 398 0
I 05/18/03 0 71 204 31 420 70 40 361 0
05/19103 195 69 206 67 263 73 41 385 0
05/20/03 238 64 210 33 60 71 40 373 0
05/21/03 220 62 203 140 70 83 49 401 0
I 05/22/03 260 53 237 161 59 57 29 294 0
05/23/03 242 87 225 241 237 67 39 304 0
05/24/03 167 112 223 249 237 72 42 342 0
05125103 202 69 226 280 324 71 42 363 0 I 05/26/03 134 0 135 112 179 41 25 220 0
05/27/03 0 0 0 0 0 0 0 0 0
05/28/03 213 0 295 122 218 58 40 355 0
I 05129/03 225 0 330 97 260 63 44 391 0
05/30/03 217 0 332 83 278 63 43 391 0
05/31/03 221 0 329 92 291 72 44 415 0
I AVG: 195 70 214 97 295 68 42 369
TOTAL: 6033 2183 6621 3000 9144 2118 1295 11427 28
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••
I 51
GROUNDWATER MONTHLY MONITORING:
RAINFALL DATA
MAY 2003 .
DATE INCHES/DAY
05/01/03 0.00
05/02/03 0.20
05/03/03 0.00
05/04/03 0.00
05/05/03 0.80
05/06/03 0.60
05/07/03 0.15
05/08/03 o.oo
05/09/03 o.oo
05/10/03 0.00
05/11/03 0.00
05/12/03 0.00
05/13/03 o.oo
05/14/03 o.oo
05/15/03 0.00
05/16/03 0.30
05/17/03 0.10
05/18/03 0.30
05/19/03 0.05
05/20/03 0.00
05/21/03 2.30
05/22/03 2.80
05/23/03 0.00
05/24/03 2.00
05/25/03 0.00
05/26/03 1.00
05/27/03 0.05
05/28/03 0.00
05/29/03 0.28
05/30/03 0.00
05/31/03 0.15
TOTAL 11. 08
52
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I DAILY REFERENCE SHEET:
DATE: IT. EQ. PLT. DEC. DEC. WAS MIX MIX MIX NIT PHOS MIX FIM
I MAY. INF. TNK. SEP. LIQ LIQ LIQ ADD ADD LIQ WAS 5/DAY
2llQJ = = = = llS. ~ ~ lfil fliQ.s. !zAl.li ~ lilaL !zAl.li ELM A'!lSJ,
1 7520 6210 2690 104 10.2 o o 140 o 0.00
I 2 8010 6560 4560 237 110 14290 2180 102 12.8 o o 140 202 0.19
3 5480 5490 2400 98 12.0 3 140 o 0.00
4 8640 7090 8060 258 100 10800 2280 80 13.5 2 150 202 0.31
5 9190 7180 3030 118 16.0 o o 150 o 0.00 0.10
6 7570 9460 7300 229 110 14830 2100 116 16.5 2 150 202 0.31 0.16
I 7 6670 7030 3180 120 16.8 o o 150 o 0.00 0.12
8 6130 7060 7050 288 90 12130 2580 122 19.0 o o 150 202 0.24 0.17
9 7170 6250 2590 75 9.0 180 o 0.00 0.11
10 8740 6510 6540 298 128 13920 2540 129 14.0 o. 180 202 0.23 0.16
11 6740 4980 2960 132 10.0 o 170 o 0.00 0.09
I 12 8140 6670 5990 283 70 15280 2770 150 14.0 o o 140 202 0.19 0.13
13 7500 6080 3290 124 8.0 o o 140 o 0.00 0.08
14 8170 6650 5850 262 80 15890 3010 126 10.5 o o 150 202 0.17 0.12
15 8600 6230 2690 78 7.0 1 o 150 o 0.00 0.07
16 5290 6460 7090 280 50 12330 2520 110 8.3 o o 150 202 0.25 0.12
I 17 6470 5000 1768 108 5.2 o o 160 o 0.00 0.08
18 3320 3620 4890 250 72 13950 2864 91 10.3 o 150 202 0.15 0.11
19 3090 3830 3400 100 6.6 o o 160 o 0.00 0.08
20 10410 4200 2980 236 70 16350 3230 112 9.2 o o 150 202 0.08 0.10
21 8500 6310 3260 104 5.8 o o 150 o 0.00 0.05
I 22 10300 5350 6310 221 40 14280 2960 100 8.3 o 150 202 0.19 0.08
23 4640 4820 2920 96 5.2 o 150 o 0.00 0.05
24 5770 5810 6220 212 100 11080 2620 88 5.0 o 150 202 0.21 0.10
25 6110 4910 2680 101 4.6 1 o 150 o 0.00 0.08
26 6120 4720 2340 122 6.2 o o 150 o 0.00 0.08
I 27 9240 5030 3420 124 9.7 o o 150 o 0.00 0.04
28 7970 5260 4990 220 80 12830 2510 157 12.8 o o 150 202 0.18 0.08
29 6510 5090 2740 126 7.2 o o 170 o 0.00 0.04
30 7780 5050 5420 219 60 12470 2080 111 8.0 o o 180 202 0.23 0.08
31 7500 5510 2520 80.0 5.0 o 180 o 0.00 0.08
I AVG: 7203 5826 5203 218 73 11902 2714 109.8 9.9 0 o 154 91 0.09
MAX: 10410 9460 8060 298 128 16350 3420 157.0 19.0 1 3 180 202 0.31
MIN: 3090 3820 o o 0 o 1768 75.0 4.6 o o 140 0 0.00
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7122103
I 53
I
INNER TIER COMBINED INFLUENT #2 ITCI I PAGE NO.1
MAY.2003
DATE: FLOW: PH: COD: TSS: TOC:
GPD pH ppm ppm ppm I
05101103 1474 5.1 7520 23
05102103 1505 5.1 8010 17 I 05103103 1520 5.1 5480
05/04103 1463 5.1 8640 20
05/05103 1467 5.0 9190 24
05106103 1603 5.1 7570 27 I 05107103 1583 5.1 6670 17
05/08103 1438 5.1 6130 17 1660
05109103 1432 5.1 7170 73 I 05110103 1444 5.1 8740 61
05111103 1513 5.1 6740 30
05112/03 1520 5.2 8140 35
05113103 1485 5.1 7500 37 I 05114103 1352 5.2 8170 47 1860
05115103 1667 5.1 8600 38
05116/03 1257 5.1 5290 6 I 05117103 1273 5.2 6470 30
05/18103 1197 5.2 3320 14
05/19103 1299 5.2 3090 9 I 05120103 1089 5.0 10410 34
05121/03 1223 5.1 8500 47
05122/03 1150 4.9 10300 38 491
05/23103 1442 5.1 4640 9 I 05124103 1444 5.1 5770 19
05125103 1577 5.1 6110 11
05126/03 846 5.2 6120 17 I 05127103 0 5.3 9240 50
05128103 1301 5.2 7970 31 2330
05129103 1410 5.2 6510 21
05130103 1407 5.3 7780 14 I 05131103 1464 5.1 7500 11
AVG: 1350 5.1 7203 27 1585 I MAX: 1667 5.3 10410 73 2330
MIN: 0 4.9 3090 1 491
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54 I
I
GROUNDWATER MONTHLY MONITORING:
I INNER TIER EQUALIZATION TANK: ITEQT
PAGE NO.2
MAY.2003
DATE: PH: COD: OT WATER ADDED
I pH ppm gal
05/01/03 6.8 6210
I 05/02/03 6.7 6560
05/03/03 6.3 5490
05/04/03 6.5 7090
05/05/03 6.8 7180
I 05/06/03 6.6 9460
05/07/03 7.0 7030
05/08/03 6.6 7060
I 05/09/03 6.8 6250
05/10/03 6.6 6510
05/11/03 6.7 4980
I 05/12/03 6.6 6670
05/13/03 6.8 6080
05/14/03 6.7 6650
05/15/03 6.9 6230
I 05/16/03 6.8 6460
05/17/03 7.1 5000
05/18/03 6.8 3820 188
I 05/19/03 7.1 3830
05/20/03 6.7 4200 263
05/21/03 7.1 6310
05/22/03 6.8 5350
I 05/23/03 7.3 4820
05/24/03 6.8 5810
05/25/03 7.1 4910
I 05/26/03 6.8 4720
05/27/03 6.9 5030
05/28/03 7.2 5260
I 05/29/03 6.8 5090
05/30/03 6.9 5050
05/31/03 7.0 5510
I AVG: 6.8 5826 226
MAX: 7.3 9460 263
MIN: 6.3 3820 188
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I 55
I GROUNDWATER MONTHLY MONITORING:
AFTER PLATE SEPARATOR BEFORE SBR: I PAGE NO. 3
MAY.2003
DATE: PH: COD: TSS:
pH ppm ppm I
05101103
05102103 6.2 4560 140 I 05103103
05104103 6.3 8060 16
05105103
05106103 5.2 7300 44 I 05107103
05108103 6.4 7050 212
05109103 I 05110103 6.5 6540 60
05111103
05112103 5.3 5990 16
05113103 I 05/14103 5.7 5850 40
05115103
05116103 5.5 7090 8 I 05117103
05/18103 6.4 4890 56
05119103 I 05120/03 6.2 2980 84
05121103
05122103 6.2 6310 4
05123103 I 05124/03 5.4 6220 28
05125103
05126103 I 05127103
05128103 6.4 4990 40
05129103
05130103 6.9 5420 4 I 05131/03
AVG: 6.0 5946 54 I MAX: 6.9 8060 212
MIN: 5.2 2980 4
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I
GROUNDWATER MONTHLY MONITORING:
I SBR MIXED LIQUOR: SBRML
PAGE NO. 4
MAY.2003 SETT. SLUDGE 5/DAY
I DATE: PH: NH3N: PO4: DO: MLSS: MLVSS: SOLIDS: WASTED F/M: F/M:
pH ppm ppm ppm ppm ppm ml/I gal ratio ratio
05/01/03 8.3 104 10.2 3.7 2690 140 0 0.00
I 05/02/03 8.3 102 12.8 4.6 2180 140 202 0.19
05/03/03 8.3 98 12.0 2.2 2400 140 0 0.00
05/04/03 8.3 80 13.5 3.7 2280 150 202 0.31
I 05/05/03 8.2 118 16.0 2.9 3030 150 0 0.00 0.10
05/06/03 8.4 116 16.5 4.2 2100 1590 150 202 0.31 0.16
05/07/03 8.4 120 16.8 3.1 3180 150 0 0.00 0.12
05/08/03 8.5 122 19.0 3.8 2580 150 202 0.24 0.17
I 05/09/03 8.3 75 9.0 3.6 2590 180 0 0.00 0.11
05/10/03 8.4 129 14.0 3.7 2540 180 202 0.23 0.16
05/11/03 8.4 132 10.0 3.1 2960 170 0 0.00 0.09
I 05/12/03 8.5 150 14.0 4.4 2770 140 202 0.19 0.13
05/13/03 8.5 124 8.0 3.6 3290 2350 140 0 0.00 0.08
05/14/03 8.5 126 10.5 3.9 3010 150 202 0.17 0.12
05/15/03 8.5 78 7.0 3.5 2690 150 0 0.00 0.07
I 05/16/03 8.6 110 8.3 4.6 2520 150 202 0.25 0.12
05/17/03 8.5 108 5.2 3.1 1768 160 0 0.00 0.08
05/18/03 8.5 91 10.3 4.5 2864 150 202 0.15 0.11
I 05/19/03 8.6 100 6.6 4.8 3400 160 0 0.00 0.08
05/20/03 8.5 112 9.2 4.6 3230 2220 150 202 0.08 0.10
05/21/03 8.5 104 5.8 4.6 3260 150 0 0.00 0.05
I 05/22/03 8.4 100 8.3 4.9 2960 150 202 0.19 0.08
05/23/03 8.4 96 5.2 4.1 2920 150 0 0.00 0.05
05/24/03 8.4 88 5.0 3.9 2620 150 202 0.21 0.10
05/25/03 8.5 101 4.6 3.3 2680 150 0 0.00 0.08
I 05/26/03 8.5 122 6.2 4.4 2340 150 0 0.00 0.08
05/27/03 8.5 124 9.7 4.0 3420 2410 150 0 0.00 0.04
05/28/03 8.6 157 12.8 4.8 2510 150 202 0.18 0.08
I 05/29/03 8.5 126 7.2 4.3 2740 170 0 0.00 0.04
05/30/03 8.6 111 8.0 4.3 2080 180 202 0.23 0.08
05/31/03 8.4 80 5.0 0.3 2520 180 0
I AVG: 8.4 110 10 4 2714 2143 154 91 0.10 0.10
MAX: 8.6 157 19 5 3420 2410 180 202 0.31 0.17
MIN: 8.2 75 5 0 1768 1590 140 0 0.00 0.04
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I 57
I
GROUNDWATER MONTHLY MONITORING:
SBR EFFLUENT:(DECANT) #4 SBRE I PAGE NO. 5
MAY.2003 WAS. NH3N PHOS.
DATE: FLOW: COD: TSS: TSS ADDED: ADDED:
GPD ppm ppm ppm gal lbs I
05/01/03 0 0 0
05/02/03 2468 237 110 142920 0 0 I 05/03/03 0 3
05/04/03 2063 258 100 10800 2
05/05/03 0 0 0
05/06/03 2390 229 110 14830 1 2 I 05/07/03 0 0 0
05/08/03 2378 288 90 12130 0 0
05/09/03 0 1 1 I 05/10/03 1986 298 128 13920 0
05/11/03 0 1 0
05/12/03 2002 283 70 15280 0 0
05/13/03 0 0 0 I 05/14/03 2332 262 80 15890 0 0
05/15/03 0 1 0
05/16/03 2039 280 50 12330 0 0 I 05/17/03 0 0 0
05/18/03 2007 250 72 13950 1 0
05/19/03 0 0 0 I 05/20/03 2040 236 70 16350 0 0
05/21/03 0 0 0
05/22/03 2124 221 40 14280 1 0
05/23/03 0 0 I 05/24/03 1968 212 100 11080 0
05/25/03 0 1 0
05/26/03 0 0 0 I 05/27/03 0 0 0
05/28/03 2124 220 80 12830 0 0
05/29/03 0 0 0
05/30/03 2711 219 60 12470 0 0 I 05/31/03 0 0
AVG: 988 250 83 22790 0 0 I MAX: 2711 298 128 142920 3
MIN: 0 212 40 10800 0 0
• DID NOT PROCESS SBR . I
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58 I
I
GROUNDWATER MONTHLY MONITORIN(
I INNER TIER CARBON FILTER EFFLUENT #8 ITEF
PAGE NO. 7
MAY.2003
OATE: PH: COD: TOC: TSS: I pH ppm ppm ppm
05/01/03
I 05/02/03
05/03/03
05/04/03
I 05/05/03
05/06/03
05/07/03
05/08/03 8.1 166 194 80
I 05/09/03
05/10/03
05/11/03
I 05/12/03
05/13/03
05/14/03 8.1 256 308
05/15/03
I 05/16/03
05/17/03
05/18/03
I 05/19/03
05/20/03
05/21/03
I 05/22/03 8.3 215 231
05/23/03
05/24/03
05/25/03
I 05/26/03
05/27/03
05/28/03 8.2 211 268
I 05/29/03
05/30/03
05/31/03
I AVG: 8.2 212 250 80
MAX: 8.3 256 308 80
MIN: 8.1 166 194 80
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I 59
MAINTENANCE ACTIVITIES-GROUNDWATER OPERABLE UNIT #1
INNER TIER SYSTEM
ACTION
DATE WELL# PROBLEM DATE ACTION MECHANIC
5/19103 # 1 NO FLOW 5119103 CHANGED EXHUSTER MAX LAIL
60
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-------------------
a,
Well
OT-ZR
OT-3
OT-4
OT-5
OT-6
OT-6A
OT-7
OT-8
Thermometer
Operational? **
X
X
X
X
X
X
X
X
Monthly O&M Plan Checklist
HNA Holdings, Inc., Shelby, NC
Heat Lamp
Operational? **
X
X
X
X
Other Operational Items/Comments
X COULDN'T PULL PUMP WELL COLLASPED
X
X
X
(** Temperature and Heat Lamp checks October thru April only)
Form Completed by: __________ Tc..O=NY-'--"B-'-'R"-YA'--'N'--'T~---------
Date: __________ _,c3,.:IS"-'/---"O"'3 _________ _
I
INNER TIER I DAILY FLOW
I
JUNE.
2003 IT-1 IT-2 IT-3 IT-4 IT-5 IT-6 IT-7 IT-8 IT-9 I
06/01/03 210 0 210 89 291 70 42 410 0
06/02/03 179 0 400 80 264 69 44 391 0 I 06/03/03 158 0 264 245 228 57 27 338 0
06/04/03 195 56 318 179 259 67 33 401 0
06/05/03 196 84 293 80 281 70 35 402 0 I 06/06/03 200 80 300 88 301 73 50 411 0
06/07/03 180 40 260 80 280 70 45 400 0
06/08/03 101 124 286 204 251 47 14 368 0 I 06/09/03 41 83 297 210 260 62 38 400 0
06/10/03 51 86 293 131 268 63 36 411 0
06/11/03 50 85 254 176 305 62 34 66 0
06/12/03 39 80 252 81 295 64 33 0 0 I 06/13/03 226 75 240 86 288 64 31 491 0
06/14/03 263 68 221 78 332 63 33 549 0
06/15/03 269 66 251 86 302 58 12 552 0 I 06/16/03 254 66 260 58 300 56 13 351 0
06/17/03 259 66 261 61 306 59 40 393 524
06/18/03 227 56 224 67 232 52 38 516 554
06/19/03 239 67 273 59 216 60 35 527 572 I 06/20/03 247 65 290 61 265 69 42 599 242
06/21/03 246 62 272 71 225 66 43 587 0
06/22/03 250 63 272 63 202 63 42 608 0 I 06/23/03 232 59 256 63 180 63 40 595 20
06/24/03 225 61 261 67 240 62 38 584 0
06/25/03 227 63 241 50 219 62 21 571 120 I 06/26/03 224 56 236 45 216 59 36 536 39
06/27/03 231 54 270 38 184 62 40 619 0
06/28/03 234 50 251 54 115 65 39 588 0
06/29/03 216 48 238 49 132 59 37 572 0 I 06/30/03 214 49 236 47 212 61 34 584 0
I
AVG: 196 60 266 92 248 63 35 461 69
TOTAL: 5883 1812 7980 2746 7449 1877 1045 13820 2071 I
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GROUNDWATER MONTHLY MONITORING:
RAINFALL DATA
JUNE 2003
DATE INCHES/DAY
06/01/03 0.00
06/02/03 o.oo
06/03/03 1.90
06/04/03 0.00
06/05/03 o.oo
06/06/03 0.95
06/07/03 0.70
06/08/03 0.05
06/09/03 o.oo
06/10/03 0.00
06/11/03 0.00
06/12/03 0.00
06/13/03 o.oo
06/14/03 0.00
06/15/03 0.00
06/16/03 0.00
06/17/03 0.00
06/18/03 0.50
06/19/03 0.10
06/20/03 · 0.00
06/21/03 0.00
06/22/03 0.00
06/23/03 0.00
06/24/03 0.00
06/25/03 0.00
06/26/03 0.00
06/27/03 o.oo
06/28/03 o.oo
06/29/03 0.00
06/30/03 0.40
TOTAL 4.60
63
I
DAILY REFERENCE SHEET: I
DATE: IT. EQ. PLT. DEC. DEC. WAS MIX MIX MIX NIT PHOS MIX F/M
JUNE. INF. TNK. SEP. LIQ LIQ LIQ ADD ADD LIQ WAS 5/DAY I = @lb @lb @lb i;_QQ. ~ .ISS ~ !ill ~ ~ ~ :,a ~ ELM Al/!:,_.
7590 5400 5440 165 20 9900 2490 101 7.6 0 0 180 202 0.19
2 6580 6400 2560 85 5.0 0 200 0 0.00
3 6960 5800 5810 193 20 9890 2560 90 7.0 1 0 200 202 0.20 I 4 6200 4800 2650 125 5.0 0 0 200 0 0.00
5 6160 5050 7000 170 30 11550 2460 95 7.0 0 200 202 0.25 0.13
6 7910 6580 2340 100 5.0 0 0 200 0 0.00 0.09
7 7870 5390 5710 115 10 12490 2150 107 7.0 0 0 200 202 0.24 0.14
8 6720 5280 2140 94 5.2 0 200 0 0.00 0.10 I 9 5780 5350 5760 170 60 11880 2650 125 7.0 0 0 200 202 0.19 0.14
10 5440 4350 2900 101 7.3 0 0 200 0 0.00 0.09
11 3830 4130 5320 171 140 9390 2580 104 11.1 0 0 200 202 0.18 0.12
12 5130 3890 2500 105 9.3 0 0 200 0 0.00 0.08
13 4410 4210 -4270 195 80 11490 2880 99 13.2 0 200 202 0.13 0.10 I 14 7500 5460 2350 70 6.5 0 200 0 0.00 0.06
15 8100 7000 5800 230 140 7620 2210 90 5.0 0 200 202 0.23 0.11
16 9910 9930 2650 104 21.0 0 250 0 0.00 0.07
17 9660 7600 6140 280 80 9700 2440 120 11.0 1 0 225 202 0.22 0.12
18 5720 7090 2830 120 9.0 0 0 225 0 0.00 0.09 I 19 5580 6010 8970 286 150 10600 2020 58 7.5 2 0 190 175 0.39 0.17
20 5310 5770 9200 300 230 9720 2500 69 5.0 2 0 200 202 0.33 0.19
21 7870 5150 2690 210 6.0 0 0 175 0 0.00 0.19
22 8680 9150 7020 318 190 12130 2320 190 5.6 0 0 210 175 0.27 0.20
23 7040 6500 2320 160 1.4 0 0 150 0 0.00 0.20 I 24 7820 5990 5720 391 400 9900 2170 165 2.6 0 0 150 202 0.23 0.17
25 6470 5890 1940 140 2.9 0 0 150 0 0.00 0.10
26 8210 5320 6850 400 220 9930 1740 150 1.8 0 0 150 202 0.35 0.17
27 8900 7540 1880 110 5.0 0 0 140 0 0.00 0.12
28 8740 9000 6900 420 230 9200 1800 100 7.0 0 150 202 0.34 0.18 I 29 7310 5910 2300 110 5.0 0 170 0 0.00 0.14
30 6660 6550 6800 423 200 8780 1990 121 7.5 130 202 0.30 0.20
31 #DIV/01 #DIV/01
AVG: 7069 6083 6042 249 129 9657 2367 113.9 6.9 .0 188 106 #DIV/0! I MAX: 9910 9930 9200 423 400 12490 2900 210,0 21.0 2 250 202 #DIV/01
MIN: 3830 3890 0 0 0 0 1740 58.0 1.4 0 0 130 0 #DIV/01
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I INNER TIER COMBINED INFLUENT #2 ITCI
PAGE N0.1
I JUNE.2003
DATE: FLOW: PH: COD: TSS: TOG:
GPO pH ppm ppm ppm
I 06/01/03 1322 5.1 7590 32
06/02/03 1427 5.2 6580 108
06/03/03 1317 5.2 6960 10
I 06/04/03 1508 5.2 6200 15 2520
06/05/03 1441 5.2 6160 23
06/06/03 1503 5.0 7910 34
I 06/07/03 1355 5.0 7870 20
06/08/03 1395 5.1 6720 30
06/09/03 1391 5.1 5780 22
06/10/03 1339 5.1 5440 30
I 06/11/03 1032 5.2 3830 17 1440
06/12/03 844 5.1 5130 28
06/13/03 1501 5.2 4410 20
I 06/14/03 1607 5.1 7500 44
06/15/03 1596 5.1 8100 50
06/16/03 1358 5.1 9910 54
I 06/17/03 1969 5.1 9660 47 1690
06/18/03 1966 5.3 5720 28
06/19/03 2048 5.1 5580 30
06/20/03 1880 5.2 5310 50
I 06/21/03 1572 5.2 7870 32
06/22/03 1563 5.1 8680 35
06/23/03 1508 5.0 7040 40
I 06/24/03 1538 5.0 7820 50 2320
06/25/03 1574 5.1 8470 39
06/26/03 1447 5.1 8210 35
06/27/03 1498 5.1 8900 43
I 06/28/03 1396 5.1 8740 55
06/29/03 1351 5.1 7310 38
06/30/03 1437 5.1 6660 48
I AVG: 1489 5.1 7069 37 1993
MAX: 2048 5.3 9910 108 2520
I MIN: 844 5.0 3830 10 1440
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GROUNDWATER MONTHLY MONITORING: I INNER TIER EQUALIZATION TANK: ITEQT
PAGE NO.2
JUNE.2003
DATE: PH: COD: OT WATER ADDED I pH ppm gal
06/01/03 6.6 5400 I 06/02/03 7.2 6400
06/03/03 6.9 5800
06/04/03 6.9 4800
06/05/03 6.9 5050 I 06/06/03 6.9 6580
06/07/03 5.6 5390
06/08/03 6.9 5280 I 06/09/03 6.9 5350
06/10/03 7.1 4350
06/11/03 7.0 4130 I 06/12/03 7.2 3890
06/13/03 6.8 4210
06/14/03 6.9 5460
06/15/03 6.8 7000 I 06/16/03 6.9 9930
06/17/03 6.7 7600
06/18/03 6.9 7090 I 06/19/03 6.8 6010
06/20/03 7.0 5770
06/21/03 7.4 5150
06/22/03 7.0 9150 I 06/23/03 7.1 6500
06/24/03 6.8 5990
06/25/03 7.2 5890 I 06/26/03 6.8 5320
06/27/03 7.0 7540
06/28/03 6.9 9000
06/29/03 7.3 5910 I 06/30/03 7.0 6550
AVG: 6.9 6083 #DIV/0! I
MAX: 7.4 9930 0
MIN: 5.6 3890 0 I
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I GROUNDWATER MONTHLY MONITORING:
AFTER PLATE SEPARATOR BEFORE SBR:
PAGE NO. 3
I JUNE.2003
DATE: PH: COD: TSS:
pH ppm ppm
I 06/01/03 6.2 5440 4
06/02/03
06/03/03 5.4 5810 4
I 06/04/03
06/05/03 5.4 7000 8
06/06/03
I 06/07/03 5.4 5710 8
06/08/03
06/09/03 5.3 5760 20
06/10/03
I 06/11/03 5.5 5320 10
06/12/03
06/13/03 6.7 4270 84
I 06/14/03
06/15/03 6.6 5800 24
06/16/03
06/17/03 5.6 6140 8
I 06/18/03
06/19/03 5.4 8970 28
06/20/03 5.6 9200 16
I 06/21/03
06/22/03 6.4 7020 16
06/23/03
06/24/03 5.3 5720 24
I 06/25/03
06/26/03 5.4 6850 24
06/27/03
I 06/28/03 5.7 6900 28
06/29/03
06/30/03 6.6 6800 12
I AVG: 5.8 6419 20
MAX: 6.7 9200 84
I MIN: 5.3 4270 4
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GROUNDWATER MONTHLY MONITORING: I SBR MIXED LIQUOR: SBRML
PAGENO.4
JUNE.2003 SETT. SLUDGE 5/DAY
DATE: PH: NH3N: PO4: DO: MLSS: MLVSS: SOLIDS: WASTED F/M: F/M: I pH ppm ppm ppm ppm ppm ml/I gal ratio ratio
06/01/03 8.5 101 7.6 3.5 2490 180 202 0.19 I 06/02/03 8.6 85 5.0 3.9 2560 200 0 0.00
06/03/03 8.5 90 7.0 4.6 2560 1910 200 202 0.20
06/04/03 8.6 125 5.0 3.6 2650 200 0 0.00
06/05/03 8.6 95 7.0 4.4 2460 200 202 0.25 0.13 I 06/06/03 8.4 100 5.0 3.6 2340 200 0 0.00 0.09
06/07/03 8.5 107 7.0 3.8 2150 200 202 0.24 0.14
06/08/03 8.5 94 5.2 3.8 2140 200 0 0.00 0.10 I 06/09/03 8.5 125 7.0 4.4 2650 200 202 0.19 0.14
06/10/03 8.5 101 7.3 3.6 2900 2000 200 0 0.00 0.09
06/11/03 8.6 104 11.0 3.8 2580 200 202 0.18 0.12 I 06/12/03 8.5 105 9.3 3.8 2500 200 0 0.00 0.08
06/13/03 8.5 99 13.2 3.7 2880 200 202 0.13 0.10
06/14/03 8.5 70 6.5 3.2 2350 200 0 0.00 0.06
06/15/03 8.5 90 5.0 3.2 2210 200 202 0.23 0.11 I 06/16/03 8.5 104 21.0 0.0 2650 250 0 0.00 0.07
06/17/03 8.5 120 11.0 2.7 2440 2440 225 202 0.22 0.12
06/18/03 8.5 120 9.0 2.8 2830 225 0 0.00 0.09 I 06/19/03 8.6 85 7.5 4.7 2020 190 175 0.39 0.17
06/20/03 8.6 69 5.0 3.9 2500 200 202 0.33 0.19
06/21/03 8.6 210 6.0 3.7 2690 175 0 0.00 0.19
06/22/03 8.6 190 5.6 4.1 2320 210 175 0.27 0.20 I 06/23/03 8.6 160 10.3 1.4 2320 150 0 0.00 0.20
06/24/03 8.6 165 16.3 2.6 2170 1440 150 202 0.23 0.17
06/25/03 8.6 140 9.0 2.9 1940 150 0 0.00 0.10 I 06/26/03 8.7 150 16.5 1.8 1740 150 202 0.35 0.17
06/27/03 8.5 110 5.0 4.2 1880 140 0 0.00 0.12
06/28/03 8.5 100 7.0 3.3 1800 150 202 0.34 0.18
06/29/03 8.5 110 5.0 3.9 2300 170 0 0.00 0.14 I
06/30/03 8.6 121 7.5 4.3 1990 130 202 0.30 0.20
AVG: 8.5 115 8 3 2367 1948 188 106 0.14 0.13 I
MAX: 8.7 210 21 5 2900 2440 250 202 0.39 0.20
MIN: 8.4 69 5 0 1740 1440 130 0 0.00 0.06 I
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I GROUNDWATER MONTHLY MONITORING:
SBR EFFLUENT:(DECANT) #4 SBRE
PAGE NO. 5
I JUNE.2003 WAS. NH3N PHOS.
DATE: FLOW: COD: TSS: TSS ADDED: ADDED:
GPO ppm ppm ppm gal lbs
I 06/01/03 2541 165 20 9900 0 0
06/02/03 0 1 0
06/03/03 2260 193 20 9890 0
I 06/04/03 0 0 0
06/05/03 1699 170 30 11550 1 0
06/06/03 0 0 0
I 06/07/03 2138 115 10 12490 0 0
. 06/08/03 0 1 0
06/09/03 2441 171 60 11880 0 0
06/10/03 0 0 0
I 06/11/03 1875 171 140 9390 0 0
06/12/03 0 0 0
06/13/03 2063 195 80 11490 0
I 06/14/03 0 0
06/15/03 2438 230 140 7620 0
06/16/03 0 1 1
I 06/17/03 2250 280 80 9700 1 0
06/18/03 0 0 0
06/19/03 2019 286 150 10600 2 2
06/20/03 2396 300 230 9720 2 0
I 06/21/03 0 0 0
06/22/03 1895 318 190 12130 0 0
06/23/03 0 0 0
I 06/24/03 2288 391 400 9900 0 0
06/25/03 0 0 0
06/26/03 2077 400 220 9930 0 0
06/27/03 0 0 0
I 06/28/03 2325 420 230 9200 0
06/29/03 0 1 0
06/30/03 1845 423 200 8780 0
I AVG: 1152 264 138 10261 0
I MAX: 2541 423 400 12490 2 2
MIN: 0 115 10 7620 0 0
• DID NOT PROCESS SBR .
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GROUNDWATER MONTHLY MONITORIN( I INNER TIER CARBON FILTER EFFLUENT #8 ITEF
PAGE NO. 7
JUNE.2003 I DATE: PH: COD: TOG: TSS:
pH ppm ppm ppm
06/01/03 I 06/02/03
06/03/03 8.3 160 32 20
06/04/03 I 06/05/03
06/06/03
06/07/03
06/08/03 I 06/09/03
06/10/03
06/11/03 8.2 116 281 I 06/12/03
06/13/03
06/14/03 I 06/15/03
06/16/03
06/17/03 7.7 150 68.6
06/18/03 I 06/19/03
06/20/03
06/21/03 I 06/22/03
06/23/03
06/24/03 8.1 253 46.5
06/25/03 I 06/26/03
06/27/03
06/28/03 I 06/29/03
06/30/03
AVG: 8.1 170 107 20 I
MAX: 8.3 253 281 20
MIN: 7.7 116 32 20 I
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MAINTENANCE ACTIVITIES-GROUNDWATER OPERABLE UNIT #1
INNER TIER SYSTEM
ACTION
DATE WELL# PROBLEM DATE ACTION MECHANIC
6/13/03 # 1 LOW FLOW 6/13/03 CHANGED EXHUSTER & BLADDER MAX LAIL
6/13/03 #8 LOW FLOW 6/13/03 CHANGED METER MAX LAIL
71
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I Attachment 2
I Analytical Data for the
1st and 2nd Quarter 2003 Sampling Events
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I Kubal-Furr & Associates
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DA TA ASSESSMENT SUMMARY CHECKLIST AND REPORT -LEVEL II
Client ID:
Project Number:
Project Description:
CNA Holdings, Inc. -Shelby
26RPI 7/TO-26OS07
01/03
Sample Delivery Group (SDG) Description:
Prepared By: Laurie Chandler
Date: Revised: 07 /29/03
Quarterly ground..,.,ater quality samples were collected by Kubal-Furr & Associates and analyzed
by Davis & Floyd, Inc., of Greenwood, SC, for volatile organic compounds, semivolatile organic
compounds including DowTherm®, ethylene glycol and total organic carbon in accordance with
EPA/NCDENR approved methodology.
CONTENTS LEVEL COMMENTS
II
Sample Results v All data considered Class A except
as noted in the discussion section.
Chain( s) of Custody ( CO Cs) V Acceptable
Master Tracking List V Acceptable
Case Narrative
Method Conformance Summary V Acceptable
Sample Prep
Standards Prep
Instrument Quality Control Data
Batch Quality Control Report V See discussion for details.
Surrogate Recovery Report V Acceptable
Trip/Field/Equipment Blank Report V Acceptable
Field Notes/Logbook V Acceptable
CLP Forms
All Raw Data
Electronic Deliverables v Acceptable
-------------Kubal-Furr & Associates ------------
1
CNA Holdings -Ql/03 DAS
Discussion:
Volatile Organics (Method 8260B)
- 2 -7/29/03 I
I
Most of the volatile organic data is considered Class A as reported and may be used fully without I
qualification. Nine samples have results that are classified Class B, qualitative, and contain data
flags. The assigned data flags apply only to the specific compounds and samples identified in the
following narrative. I
1) The percent recovery for 1,2-dichloroethane, carbon tetrachloride, and chloroform is greater
than laboratory-established limits in batch WG33287 in the laboratory control sample and
matrix spike/matrix spike duplicate sample. The recoveries of laboratory control samples are I
primarily compound specific and the matrix spike recovery is batch specific. Although there are
no technical review guidelines established specifically for matrix spike and matrix spike duplicate
recoveries, in consideration of these three batch quality control samples having three out of ten I
compounds with recoveries outside laboratory-established limits, the reviewer concludes all .
detected compounds in batch WG33287 may be affected. Qualifiers are assigned to detected
compounds using National Functional Guidelines for Organic Data Review laboratory control
sample criteria. I
a) Samples HH-77, HH-48, PEW-4, and PEW-4 duplicate, are assigned J qualifiers for detected
volatile compounds cis-1,2-dichloroethene. Also PEW-4 and PEW-4 duplicate are assigned J
qualifiers for benzene. Samples HH-77 and HH-48 are assigned J qualifiers for
trichloroethene detects. Carbon disulfide results in samples GG-61 and PEW-3 arc qualified as
J. Also in sample PEW-3, methylene chloride is qualified J Benzene for sample K-28 is
qualified J Volatiles 2-butanone, acetone, benzene, carbon disulfide, toluene, and total xylene
are assigned J qualifiers in samples V-23 and V-23 duplicate. Non-detected analytes do not
receive qualification. ·
2) Methylene chloride and carbon disulfide is reported as non-detect in sample PEW-4. The same
compounds are reported as detects in sample PEW-4 duplicate. Methylene chloride and carbon
disulfide are qualified X indicating the reported results for these two samples are suspect.
Semi-volatile Organic Compounds/ Dowtherm (Method 8270C)
All data are considered Class A as reported, and may be used fully without qualification.
TOC (Method 9060/
All data arc considered Class A as reported, and may be used fully without qualification.
Ethylene Glycol (Method 8015!
All data are considered Class A as reported, and may be used fully without qualification.
Data Qualifiers:
J = positively identified, however, concentration should be considered as estimated.
X= reviewer assigned qualifier indicating result is suspect and should be used with caution.
Class A = quantitative Class B = qualitative Class C = unusable
--------------Knhlll-Fnrr & As.socfafps
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DAT A ASSESSMENT SUMMARY CHECKLIST AND REPORT -LEVEL III
Client ID:
Project Number:
Project Description:
CNA Holdings, Inc. -Shelby
26RP 17 I TO-26OS07
01/03
Sample Delivery Group (SDG) Description:
Prepared By: Laurie Chandler
Date: 04/24/03
Two sludge samples were collected by Kubal-Furr & Associates and analyzed by Davis &
Floyd, Inc., of Greenwood, SC, for TCLP constituents in accordance with EPA/NCDENR
approved methodology.
CONTENTS LEVEL COMMENTS
III
Sample Results v All data considered Class A.
Chain(s) of Custody (COCs) v Acceptable
Master Tracking List V Acceptable
Case Narrative V Acceptable ..
Method Conformance Summary V Acceptable
Sample Prep v Acceptable
Standards Prep
Instrument Quality Control Data V Acceptable
Batch Quality Control Report V Acceptable
Surrogate Recovery Report V Acceptable
Trip/Field/Equipment Blank Report V Acceptable
Field Notes/Logbook V Acceptable
CLP Forms
All Raw Data
Electronic Deliverables v Acceptable
------------Kubal-Furr & Associates
3
CNA Holdings -QI/03 DAS - 2 -4/24/03
Discussion:
The chain of custody docs not have TCLP Pesticides listed for sample collection and testing
parameters for SBR and FP sludge samples. These samples were tested by the laboratory in
accordance with the laboratory task order.
TCLP Volatile Organics (Method 8260B!
All data are considered Class A as reported, and may be used fully without qualification.
TCLP Semivolatile Organic Compounds (Method 8270C)
All data are considered Class A as reported, and may be used fully without qualification.
TCLP Metals (Method 6010B))
All data are considered Class A as reported, and may be used fully without qualification.
TCLP Pesticides and Herbicides (Method 808/A)
The laboratory reported an initial calibration date of 3/24/03 in the comments section of the
instrument QC assessment summary report. All data for pesticides and herbicides were analyzed
before 3/24/03. The laboratory was contacted and necessary corrections were made to qualify
instnuncnt calibration valid. Actual initial calibration date is 2/24/03.
Matrix spike/matrix spike duplicate are rcp01tcd as being recovered at 27% for 2,4,5-TP (Silvcx)
in sludge sample FP. According to National Functional Guidelines, no action is taken based on this
data alone. In conjun~tion with other available QC data there is no indication of deficiencies in the
sample matrices.
Also, surrogate percent recovery for decachlorobiphenyl is under laboratory-established limits
( 40-123%) by I%. National Functional Guidelines docs not suggest qualifying surrogate recoveries
unless they are less than 30%. No qualifiers are applied based on this outlier.
All data are considered Class A as reported, and may be used fully without qualification.
Class A = quantitative Class B = qualitative Class C = unusable
--------------Knh,il-Fnrr & A«od>ltP.s
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DA,YIS
FLOYD
March I 7, 2003
PEM CARTER
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC ·28152
Login Number
Project Number
Description
Dear Pem Carter:
:L03022401
:61621.01
:TCLP ANALYSIS
We are pleased to provide the enclosed analytical results for the samples received by
Davis & Floyd, Inc. on February 21, 2003.
A formal Quality Assurance/Quality Control program is maintained by Davis & Floyd,
which is designed to meet or exceed the EPA, NELAC or other appropriate regulatory
requirements. All analytical analyses for this project met QA/QC criteria and the
results are within the 99 % confidence interval for each method unless otherwise
stated in the footnotes. This report is to be reproduced only in full.
.Feel free to contact our Client Services Representative at [phone] if further
explanation of the analysis is required. Unless other arrangements have been made,
samples will be disposed of or returned 14 days from the date of the report. We
appreciate the opportunity to provide services to your firm.
Sincerely, .. DAVI~J;NC
ohn H. McCord, Jr.
Laboratory Manager
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax {864) 229-7119
5
Df\YIS
FLiWD LABORATORY ANALYSIS REPORT
NELAC Cenijication Number: £87633
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
PEM CARTER
Client ID: SBR SLUDGE
Matrix Leachate
Parameter
Pesticides and Herbicides TCLP
SW846 1311/B081A
CHLORDANE, TECHNICAL
ENDRIN
flEPTACHLOR
HEPTACHLOR EPOXIDE
LINDANE
METHOXYCHLOR
TOXAPHENE
SW846 1311/BlSlA
2,4,5-TP (SILVEX)
2,4-0
Semivolatile Organics TCLP
SW846 13ll/8270C
1,4-0ICHLOROBENZENE
2,4,5-TRICHLOROPHENOL
2,4,6-TRICHLOROPHENOL
2,4-DINITROTOLUENE
2-METHYLPHENOL
3&4-METHYLPHENOL
HEXACHLOROBENZENE
HEXACHLOROBUTADIENE
HEXACHLOROETHANE
NITROBENZENE
PENTACHLOROPHENOL
PYRIDINE
Trace Metals TCLP
SW846 1311/6010B
ARSENIC, TOTAL
BARIUM, TOTAL
CADMIUM, TOTAL
CHROMIUM, TOTAL
LEAD, TOTAL
SELENIUM, TOTAL
SILVER, TOTAL
SW846 1311/7470A
MERCURY, TOTAL
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
Result
0.0050
0 .00050
0 .00050
o. 00050
0. 00050
o. 0050
0 .0050
0.0025
0.025
0, 10
o. 10
0. 10
0, 10
0, 10
0.10
0, 10
0. 10
o, 10
0, 10
0, 25
o. 10
0.50
0.20
0.050
o. 10
o, 50
0 , 50
o. 10
0 . 0020
NC Certification Number: 25
Project Number: 61621.01
Report Date March 17, 2003
Page 1 of 2 Report ID: AB4754
Sample ID L03022401-01
Date Collected: 21-FEB-03 09: 30
Date Received 21-FEB-03
Qual RDL Units Analyst Date Time
0.0050 mg/1 JMT 03/03/03 2012
0 .00050 mg/1 JMT 03/03/03 2012
0 .00050 mg/1 JMT 03/03/03 2012
0 .00050 mg/1 JMT 03/03/03 2012
0 .00050 mg/1 JMT 03/03/03 2012
0 . 0050 mg/1 JMT 03/03/03 2012
0 .0050 mg/1 JMT 03/03/03 2012
0.0025 mg/1 JMT 03/03/03 1806
0.025 mg/1 JMT 03/03/03 1806
0 .10 mg/1 JRN 03/04/03 1051
o. 10 mg/1 JRN 03/04/03 1051
0, 10 mg/1 JRN 03/04/03 1051
o. 10 mg/1 JRN 03/04/03 1051
0, 10 mg/1 JRN 03/04/03 1051
o, 10 mg/1 JRN 03/04/03 1051
0 , 10 mg/1 JRN 03/04/03 1051
o. 10 mg/1 JRN 03/04/03 1051
0.10 mg/1 JRN 03/04/03 1051
0, 10 mg/1 JRN 03/04/03 1051
0 , 25 mg/1 JRN 03/04/03 1051
0. 10 mg/1 JRN 03/04/03 1051
0, 50 mg/1 BDL 02/27/03 1856
0 . 20 mg/1 BDL 02/27/03 1856
0. 050 mg/1 BDL 02/27/03 1856
o. 10 mg/1 BOL 02/27/03 1856
0. 50 mg/1 BDL 02/27/03 1856
0 ,50 mg/1 BDL 02/27/03 1856
0, 10 mg/1 BDL 02/27/03 1856
0 . 0020 mg/1 ACW 03/03/03 144 0
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Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue
6
I Greenwood, SC 2%49 I [phone] I Fax (B64) 229-71191
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DAYIS
FLtWD LABORATORY ANALYSIS REPORT
NELA C Cenificarion Number: £87633
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
PEM CARTER
Client ID: SBR SLUDGE
Parameter
Volatile Organics TCLP
SW846 lJll/8260B
1·, 1-OICHLOR~ETHENE
1,2-DICHLOROETHANE
2-BUTANONE
BENZENE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROFORM
TETRACHLOROETHENE
TRICHLOROETHENE
VINYL CHLORIDE
Result
< 0. 050
< 0 .050
< 0.10
< 0 .050
< 0 .050
< o. 050
< 0 .050
< o. 050
< o. 050
< 0. 1 0
Prep Procedure Method Analyst Prep Date
Analytical Prep Procedures:
ZHE EXTRACTION
TCLP EXTRACTION
TCLP SEMIVOLATILES
TCLP PESTICIDES
TCLP HERBICIDES
METALS PREP ICP
METALS PREP HG
SW846
SW846
SW846
SW846
SW846
SWB46
SW846
1311 DBC 02/26/03
1311 DBC 02/26/03
1311/3500A DBC 02/27/03
1311/3510C DBC 02/27/03
1311/BlSlA DBC 02/28/03
3010 BDL 02/27/03
7470A ACW 03/03/03
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 2 of 2
Sample ID
March 17, 2003
Report ID: AB4754
L03022401-01
Qual RDL Units Analyst Date Time
0 .050 mg/1 PAP 03/06/03 1714
0 .oso mg/1 PAP 03/06/03 1 714
0.10 mg/1 PAP 03/06/03 1714
0 .050 mg/1 PAP 03/06/03 1714
0 .050 mg/1 PAP 03/06/03 1714
0 .050 mg/1 PAP 03/06/03 1714
0 .050 mg/1 PAP 03/06/03 1714
0 .050 mg/1 PAP 03/06/03 "1714
0 .050 mg/1 PAP 03/06/01. 1714
0. 10 mg/1 PAP 03/06/03 1714
1530
1545
0900
1330
0800
1500
0930
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I Bl6 L Durst Avenue I Greenwood, SC 29649 I (864) 229-441] I r:ax [phone]
7
DAYIS
FLtiYD LABORATORY ANALYSIS REPORT
NELAC Certification Number: £87633
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
PEM CARTER
Client ID: FP SLUDGE
Matrix Leachate
Parameter
Pesticides an~ Herbicides TCLP
SW846 1311/8081A
CHLORDANE, TECHNICAL
ENDRIN
HEPTACHLOR
HEPTACHLOR EPOXIDE
LINDANE
METHOXYCHLOR
TOXAPHENE
SW846 1311/BlSlA
2,4,5-TP (SILVEX)
2, 4-D
Semivolatile Organics TCLP
SW846 1311/8270C
1,4-DICHLOROBENZENE
2,4,5-TRICHLOROPHENOL
2,4,6-TRICHLOROPHENOL
2,4-DINITROTOLUENE
2-METHYLPHENOL
3 &4 -METHYLPHENOL
HEXACHLOROBENZENE
HEXACHLOROBUTADIENE
HEXACHLOROETHANE
NITROBENZENE
PENTACHLOROPHENOL
PYRIDINE
Trace Metals TCLP
SW846 1311/6010B
ARSENIC, TOTAL
BARIUM, TOTAL
. CADMIUM, TOTAL
CHROMIUM, TOTAL
LEAD, TOTAL
SELENIUM, TOTAL
SILVER, TOTAL
SW846 1311/7470A
MERCURY, TOTAL
Result
< 0.0050
< o. 00050
< 0. 00050
< o. 00050
< 0 .00050
< 0 . 0050
< 0 .0050
< 0.0025
< 0.025
< o. 10
< o. 10
< o. 10
< 0. 10
< 0. 10
< 0. 10
< 0. 10
< 0. 10
< 0. 10
< 0.10
< 0 . 25
< o. 10
< 0.50
S. 0
< 0 .050
< 0. 10
< 0 .so
< 0 . so
< 0. 10
< 0.0020
NC Certificarion Number: 25
Project Number, 61621.01
Report Date
Page 1 of 2
March 17, 2003
Report ID: AB4755
Sample ID L03022401-02
Date Collected: 21-FEB-03 09:40
Date Received 21-FEB-03
Qual RDL Units Analyst Date
0.0050 mg/1 JMT 03/03/03
0. 00050 mg/1 JMT 03/03/03
o. 00050 mg/1 JMT 03/03/03
0. 00050 mg/1 JMT 03/03/03
0. 00050 mg/1 JMT 03/03/03
0 .0050 mg/1 JMT 03/03/03
0 .0050 mg/1 JMT 03/03/03
0.0025 mg/1 JMT 03/03/03
0. 025 mg/1 JMT 03/03/03
0. 10 mg/1 JRN 03/04/03
0. 10 mg/1 JRN 03/04/03
0 .10 mg/1 JRN 03/04/03
0. 10 mg/1 JRN 03/04/03
0.10 mg/1 JRN 03/04/03
o. 10 mg/1 JRN 03/04/03
o. 10 mg/1 JRN 03/04/03
o. 10 mg/1 JRN 03/04/03
0. 10 mg/1 JRN 03/04/03
0 .10 mg/1 JRN 03/04/03
0 .25 mg/1 JRN 03/04/03
0 .10 mg/1 JRN 03/04/03
0 .so mg/1 BDL 02/27/03
0 .20 mg/1 BDL 02/27/03
0. 050 mg/1 BDL 02/27 /03
0. 10 mg/1 BDL 02/27/03
0 .so mg/1 BDL 02/27/03
0 . 50 mg/1 BDL 02/27/03
0. 10 mg/1 BDL 02/27/03
0. 0 02 0 mg/1 ACW 03/03/03
Time
2152
2152
2152
2152
2152
2152
2152
1907
1907
124 8
1248
124 8
1248
1248
1248
1248
1248
1248
1248
1248
1248
1918
1918
1918
1918
1918
1918
1918
1445
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Davb & Floyd, Inc. j PO Drawer 428 l Greenwood, SC 29648 I 816 E. Durst Avenue
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I Greenwood, SC 29649 l [phone] I Fax [phone] I
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Di\YIS
FLtlYD LABORATORY ANALYSIS REPORT
NELAC Certification N11111ber: £87633
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
PEM CARTER
Client ID: YP SLUDGE
Parameter
Volatile Organics TCLP
SWB46 1311/82608
1, 1-DICHLORO_ETHENE
1,2-DICHLOROETHANE
2-BUTANONE
BENZENE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROFORM
TETRACHLOROETHENE
TRICHLOROETHENE
VINYL CHLORIDE
Result
< 0 . 050
< 0. 050
< 0 .10
< 0 . 050
< o. 050
< 0 .050
< 0 .050
< o. 050
< 0 .050
< 0.10
Prep Procedure Method Analyst Prep Date
Analytical Prep Procedures:
ZHE EXTRACTION
TCLP EXTRACTION
TCLP SEMIVOLATILES
TCLP PESTICIDES
TCLP HERBICIDES
METALS PREP ICP
METALS PREP HG
SW846
SW846
SW846
SW846
SW846
SW846
SW846
~-'·
1311 DSC 02/26/03
1311 DBC 02/26/03
1311/3500A DBC 02/27/03
1311/3510C DSC 02/27/03
1311/8151A DBC 02/28/03
3010 BDL 02/27/03
7470A ACW 03/03/03
NC Certification N11111ber: 25
Project Number: 61621.01
Report Date
Page 2 of 2
Sample ID
March 17, 2003
Report ID: A84755
L03022401-02
Qual RDL Units Analyst Date
0 . 050 mg/1 PAP 03/06/0]
0. 050 mg/1 PAP 03/06/03
0.10 mg/1 PAP 03/06/03
0 . 050 mg/1 PAP 03/06/03
0. 050 mg/1 PAP 03/06/03
0 .050 mg/1 PAP 03/06/03
0 .050 mg/1 PAP 03/06/03
0 . 050 mg/1 PAP 03/06/03
0 .050 mg/1 PAP 03/06/03
0.10 mg/1 PAP 03/06/03
1530
1545
0900
1330
0800
1500
0930
Time
1845
1845
1845
1845
1845
1845
1845
1845
1845
1845
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 2%49 I (864) 229-441 j I Fax (8n4) 229-7119
9
Di\YIS
FLtwD LABORATORY ANALYSIS REPORT
NELAC Certification Number: £87633
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
PEM CARTER
Client ID: SLUDGE TRIP BLANK
Matrix
Parameter
Volatile Orga~ica TCLP
SW846 1311/8260B
1,1-DICHLOROETHENE
1,2-DICHLOROETHANE
2-BUTANONE
BENZENE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROFORM
TETRACHLOROETHENE
TRICHLOROETHENE
VINYL CHLORIDE
Leachate
Result
< 0.0050
< 0.0050
< 0. 010
< 0 .0050
< o. 0050
< 0 . 0050
< 0 .0050
< 0. 0050
< 0 .0050
< 0.010
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 1 of 1
March 17, 2003
Report ID: AB4756
Sample ID L03022401-03
Date Collected: 13-FEB-03 09:30
Date Received
Qual RDL Units Analyst Date
0 .0050 mg/1 PAP 03/06/03
0 .0050 mg/1 PAP 03/06/03
0.010 mg/1 PAP 03/06/03
0. 0050 mg/1 PAP 03/06/03
0 . 0050 mg/1 PAP 03/06/03
0 .0050 mg/1 PAP 03/06/03
o. 0050 mg/1 PAP 03/06/03
0. 0050 mg/1 PAP 03/06/03
o. 0050 mg/1 PAP 03/06/03
0.010 mg/1 PAP 03/06/03
Time
1644
1644
1644
1644
1644
·164 4
1644
1644
1644
1644
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Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I H 16 E. Durst Avenue
1 0
I Greenwood, SC 2%49 I [phone] I Fax [phone] I
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DAYIS
FLt1YD LABORATORY ANALYSIS REPORT
NELAC Certification Number: £87633 NC Certification Number: 25
Master Tracking List
Client TICONA,LLC Project Number: 61621.01
2525 BLACKSBURG ROAD
HWY 198
Contact
Sillllple ID
L03022401-01
SHELBY, NC 28152
PEM CARTER
Client ID
SBR SLUDGE
Pesticides and Herbicides TCLP
SW846 1311/BOBlA
SW846 1311/8151A
Semivalatile Organics TCLP
SW846 1Jll/8270C
Trace Metals TCLP
SW846 lJll/6010B
SW846 1311/7470A
Volatile Organics TCLP
SW846 1311/8260B
L03022401-02 FP SLUDGE
Pesticides and Herbicides TCLP
SW846 1311/BOBlA
SW846 1311/8151A
Semivolatile Organics TCLP
SW846 1311/8270C
Trace Metals TCLP
SW846 1311/6010B
SW846 131l/7470A
Volatile Org&nics TCLP
SW846 1311/82608
L03022401-03
Volatile Organics TCLP
SW846 1311/8260B
SLUDGE TRIP BLANK
Report Date
Page 1 of 1
March 17, 2003
Report ID: A84753
Date Collected
21-FEB-03 09:30
02/27/03 1330
02/28/03 0800
02/27/03 0900
02/27/03 1500
03/03/03 0930
21-P'EB-03
02/27/03 1330
02/28/03 0800
02/27/03 0900
02/27/03 1500
03/03/03 0930
09:40
13-FEB-03 09,30
Date Received
21-P'EB-03
03/03/03 2012
03/03/03 1806
03/04/03 1051
02/27/03 1856
03/03/03 1440
03/06/03 1 714
21-FEB-03
03/03/03 2152
03/03/03 1907
03/04/03 1248
02/27/03 1918
03/03/03 1445
03/06/03 1845
21-FEB-03
03/06/03 1644
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29h48 I B 16 E. Durst Avenue I Greenwood, SC 29649 l (864) 229-441 J I Fax [phone]
11
Di\YIS
FLMD LABORATORY ANALYSIS REPORT
CASE NARRATIVE
Account:
Project:
Date:
Ticona, LLC -Shelby, NC
61621.01
April 2, 2003
OVERVIEW
On February 21, 2003, Davis & Floyd received two sludge samples from the Ticona plant in Shelby, NC The
samples were extracted by Method 1311, Toxicity Characteristic Leaching Procedure (TCLP) using the appropriate
fluid and sample vessel. The TCLP extracts were then analyzed for volatile organics, semivolatile organics, trace
metals, pesticides and herbicides. This report contains. the analytical data for the following login numbers:
Sample Number
L03022401-0 I
L03022401-02
Sample ID
SBR Sludge
FP Sludge
The samples were transported to our laboratory on ice accompanied by documented Chain of Custody forms. Upon
receipt by the laboratory, the sample custodian checked samples against the Chain of Custody for agreement and
documented the pH of all preserved sample fractions on the sample login report. All samples were received intaCt
with no discrepancies noted by the sample custodian.
VOLATILE ORGANICS
Sample Analysis
The samples and any associated QC were prepared and analyzed according to the procedure described in SW846
Method 8260B. Samples L0302240!-0land L03022401-02 were analyzed at ambient temperature on instrument
HP5972S, a Hewlett Packard 5972 GC/MS equipped with an Encon/Arcon purge and trap system using a 5 ml purge
volume. An initial five-point calibration is performed covering a range of 5 µg/1 to 200 µg/1. For each compound
with less than 15% RSD, the relative response factor is assumed to be constant over the calibration range, and the
average response is used for quantitation. If the %RSD is greater than fifteen percent, then linear regression is used
for quantitation. Calibration is verified every twelve hours by checking tl1e GC/MS tuning criteria using 50 ng of
BFB and analyzing a continuing calibration standard at 50 rig/I and a method blank.
Quality Control
Each sample including QC samples and blanks are spiked with surrogate standards at the 50 µg/l level. All surrogate
recoveries were within the acceptance criteria. ,
A matrix spike, matrix spike duplicate, and a LCS are analyzed at a minimum frequency of five percent for each
matrix. A matrix spike and matrix spike duplicate was analyzed on both samples. All recoveries on MS, MSD and
LCS analyses were within QC acceptance criteria.
SEMIVOLATILE ORGANICS
Sample Analysis
The samples and any associated QC were analyzed according to the procedure described in SW846 8270C. Prior to
analysis, all samples were extracted by separatory funnel shake out with methylene chloride according to SW846
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Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 ~-f""' Avenue I Greenwood, SC 29649 I 1864) 229-4413 I fax [phone]
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DAYIS
FLOYD LABORATORY ANALYSIS REPORT
Method 35\0C. Samples L03022401-0l and L03022401-02 were analyzed on instrument HP5972Q, a Hewlett
Packard 5972 series system. Two calibration mixes are used for TCLP analysis. One mix contains our routine SW-
846 8270C target list. The other mix contains those TCLP compounds not included in the other mix. An initial five-
point calibration for each mix is perfon11ed covering a range of 10 ug/1 to 80 ug/1 (10 ug/1 to 120 ug/1 for the
additional compounds). For each compound with less than 15% RSD, the relative response factor is assumed to be
constant over the calibration range, and the average response is used for quantitation. If the %RSD was greater than
fifteen percent for any compound, then linear regression is used for quantitation. Calibration is verified every twelve
hours by checking the GC/MS tuning criteria using 50 ng of DFTPP and analyzing a continuing calibration standard
at 50 µg/1 (60 ug/1 for the additional compounds) and a method blank.
Quality Control
Each sample including QC samples and blanks is spiked with surrogate standards at a concentration of 50 ftg/1 for
the base-neutral compounds and 100 µg/1 for the acid extractable compounds. All surrogate recoveries were within
acceptable limits. A matrix spike and matrix spike duplicate were analyzed at a minimum frequency of five percent.
The matrix spike and matrix spike was performed on both samples. All recoveries on MS, MSD and LCS analyses
were within QC acceptance criteria.
CHROMATOGRAPHY
PESTICIDES
Sample Analysis
Prior to analysis, all samples were extracted by separatory furmel shake out with methylene chloride according to
SW846 Method 35 l0C. Samples L03022401-01 and L03022401-02 were analyzed on a Varian 3400 series system
designated as YARK. An initial five-point calibration covering a range of .005 mg/L to .016mg/L was performed
prior to analysis of samples and evaluated by linear regression using a least squares regression. The correlation
coefficient must be greater than or equal to .990. Calibration is verified daily by analyzing a continuing calibration
standard and evaluating the% drift of each compound which must be no more than+/-15%.
Quality Control
Each sample including QC samples and blanks are spiked with decachlorobiphenyl (DCB) and tetrachloro-m-xylene
(TCMX) at a concentration of 1.0 µg/1 as the surrogate standard. All surrogate recoveries were within acceptable
limits except DCB for the MSD on sample L03022401-0l which recovered at 39%. The LCL is 40%. A matrix
spike and matrix spike duplicate were analyzed on both samples. A LCS was analyzed at a minimum frequency of
ten percent. All criteria for die QC samples were acceptable except as noted above. '
HERBICIDES
Sample Analysis
Prior to analysis, all samples were extracted by separatory funnel shake out with diethyl ether according to SW846
Method 8151A. Samples L03022401-0l and L03022401-02 were analyzed on a Varian 3400 series system
designated as V ARE. An initial five-point calibration covering a range of .025mg/L to 2.0mg/L was perfom1ed prior
to analysis of samples and evaluated by linear regression using a least squares regression. The correlation coefficient
must be greater than or equal to .990, Calibration is verified daily by analyzing a continuing calibration standard and
evaluating the% drift of each compound which must be no more than+/-15%.
2
Davis & Floyd, Inc. I PO Drawer 428 l Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
13
DAYIS
FLOYD LABORATORY ANALYSIS REPORT
Quality Control
Each sample including QC samples and blanks are spiked with 2,4-dichlorophenylacetic acid (DCAA) at a
concentration of 2.0 µg/1 as the surrogate standard. Acceptable surrogate recovery was obtained. A matrix spike and
matrix spike duplicate were analyzed on both samples. A LCS was analyzed at a minimum frequency of ten percent.
All criteria on the QC samples were met with exception to the MS/MSD RPD for Silvex on sample L03022401-02
which was 27%. The UCL is 20%.
TRACE METALS
INDUCTIVELY COUPLED PLASMA (ICP)
Sample Analysis
Arsenic, barium, cadmium, chromium, lead, selenium and silver were analyzed on the TCLP extracts samples
L03022401-01 and L0302240J-02 by Inductively Coupled Plasma (ICP) on a Thermo Jarrell Ash 61E Trace
simultaneous system according to the procedure described in SW846 Method 6010B. Prior to the analysis, 25 ml of
a TCLP extract was digested in an acid matrix according to the sample preparation procedure described in SW846
Method 30 I 0A. The calibration of the instrnment was verified with a 1.0 mg/L initial calibration verification
standard (ICY), an initial calibration blank (!CB), a reportable detection limit standard (RDL), an interelement and
background correction check standard (ICSAl3), a continuing calibration verification standard (CCV) and a
continuing calibration blank (CCB). The ICY was from a different source than the one used to calibrate the
instrument. A continuing calibration verification standard (CCV) and a continuing calibration blank (CCl3) were
analyzed after every ten samples for the duration of the analysis. The JCSAl3 was analyzed every eight hours. All the
calibration verification checks were within acceptable limits.
Quality Control
A matrix spike (MS) and matrix spike duplicate (MSD) were analyzed on sample L02022809-0 I. A laboratory
control standard (LCS), a method blank (MB) and an extraction blank (EB) were analyzed with each workgroup of
20 or fewer samples. All QC samples met acceptable criteria.
MERCURY COLD VAPOR
Sample Analysis ; . f The TCLP extracts for samples L03022401-01 and L03022401-02 were analyzed for mercury on a Perkin-Elmer
FIMS JOO system according to the procedure described in SW846 Method 7470A. The initial calibration consisted
ofa linear regression curve ofa blank and six standards. Prior to analysis of the samples, the curve was verified with
an initial calibration verification standard (ICY) from a different source than the one used for the curve, an initial
calibration blank (!CB), a continuing calibration verification standard (CCV) and a continuing calibration blank
(CCB). After every JO samples, the CCV and the CCB were analyzed. All the calibration verification checks were
. within acceptable limits.
Quality Control
A matrix spike (MS) and matrix spike duplicate (MSD) were analyzed on both samples. All QC samples met
acceptable criteria.
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Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 ! {864) 229-4413
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D~S FL D LABORATORY ANALYSIS REPORT
Instrument QC Data
·' ,.
I Davis & Floyd, Inc. I PO Drawer 428 j Greenwood, SC 29648 j 816 E. Durst Avenue j Greenwood, SC 29649 j [phone] I fax [phone]
15
INSTRUMENT QC ASSESSMENT SUMMARY
FOR EPA METHOD 8260B
For Samples:
I CRITERlA
lab ID# L03022401-0l
lab ID # L03022401-02
lab ID # L03022401-03
lab ID# ____ _
lab ID#
lab ID#
lab ID#
lab ID#
INITIAL CALI BRA TION:(at least 5 stds with one at
or near MDL)
All standards and solutions prepared/utilized within method
required holding ti':'es
BFB Tune Criteria(table 3)
SPCCs -criteria met in section 7.4.3.1 in method 8260A
%RSD for all analytes < 15%(use avg. relative RF for calc. or
calculate cal curve with r 2!0.990)
%RSD for all analytes > 15%( calculate cal curve with r
2!0.990)
CCC:s ave RFs %RSD < 30
DAILY OR CONTINUING CALIBRATION
(beginning of each day and every 12 hr)
BFB Tune Criteria(table 3)
Midpoint calibration std run to verify:
I. SPCCs-criteria met in section 7.4.3.1 in method 8260A
2. CCCs %Drift < 20
3. Internal Standards RT within 30 sec of last check std(or cal)
4. pep area for !Ss -50% to +100% from last check(or cal)
SAMPLE CRITERIA
I. Run within 12hr of last in-control tune
2. Surrogate % rec within laboratory control limits
3. TI Cs -ions> 10% ofmosi abundant ion and
relative intensities of maj6} ions agree within 20%
4. Analyzed within workinlrange of the curve(<highest std)
------lab ID# ____ _
------lab ID# ____ _
------lab ID# ____ _
------lab ID# ____ _
I P!F lcoMMENTS
p Date of calibration: 3lQ6lQ3
p
p
p
p
NA
p
p Date analyzed: 3/06/03
p Time(s) of tuning: 15:17
p
p
p
p
p
p
NA
p
I
I hereby certify that all the above information is correct to the best of my knowledge. All out-of-control
measurements relating to the method required acceptance criteria have been documented in the above table
along with any known possible effects on the sample analytical data.
Name: _ _,P,....,a:,.,u,.,,la::...A!..!.:.... P::...u::::loc:le'-'y _____ _ Date: 3/21/03
(print)
QA Officer Signatur .
Kubal-Furr & Associates
113'pyright O 1996
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I INSTRUMENT QC ASSESSMENT SUMMARY
FOR EPA METHOD 8270C
I For Samples: lab ID # L03022401-01
lab ID# L03022401-02
lab ID# ____ _ lab ID# ____ _
lab ID# ____ _ lab ID# ____ _
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lab ID# ____ _ lab ID# ____ _ lab ID# ____ _
I CRITERIA I PIF I COMMENTS I
INITIAL CALIBRATION:(at least 5 stds with one at or near MDL) p Date of calibration: 3/03/03
All standards and solutions prepared/utilized within method holding p
times
DFTPP Tune Criteria(table 3) p Time(s) of tuning: 07:43
DDT degradation< 20% (applicable if detennining pesticides) NA Pesticides analvzed by 8081A.
Benzidine and/or pentachlorophenol present at normal responses with p
no peak tailine visible( chromatoeraohv check std)
Components of interest with RTs of0.80 -1.20 relative to one of the p
Internal Standards
SPCCs -minimum avg. RFs = 0.05 p
%RSD for all analytes < 15%(use avg. relative RF for calc. or calculate p
cal curve with r > 0.990)
%RSD for all analytes >15%(calculate cal curve with r > 0.990) NA No analytes w/ RSD > 15%
CCCs ave RFs %RSD < 30% p
DAILY OR CONTINIDNG CALIBRATION p Date analyzed: 03/04/03
(beginning of each day an:d every 12 hr)
DITPP Tune Criteria(table 3) p Time( s) of tuning: 07 :34
Mid11oint calibration std run to verify:
1. SPCCs -minimum avg. RFs = 0.05 p
2. CCCs %Drift in concentration< 20% p
3. Internal Standards RT within 30 sec of last check std(or cal) p
4. EICP area for ISs -50% to +100% from last check(or cal) p
SAMPLE CRITERIA
1. Run within 12hr oflast in-control tune p
2. Surrogate% rec within laboratory control limits p
3. TICs -ions> 10% of most abundant ion and NA TICs not required.
relative intensities of major ions agree within 20%
4. Analyzed within working range if the curve( <highest std)
!.'1!
p
I hereby certify that all the above information is correct to the best of my knowledge. All out-of-control measurements relating to the
I method required acceptance criteria have been documented in the above table along with any known possible effects on the sample
analytical data.
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Name: Paula A. Pulley Date: 3/21/03
(sign)
Kubal-Furf f Associates
INSTRUMENT QC ASSESSMENT SUMMARY
FOR EPA METHOD 8081A
For Samples: lab ID# L03022401-01 lab ID# ____ _ lab ID# ____ _
I
lab ID# L03022401-02 lab ID# ------lab ID# ------
lab ID#_____ lab ID# ____ _ lab ID# ____ _
lab ID# _____ lab ID# ____ _ lab ID# ------
CRITERIA I P/F I COMMENTS
INITIAL CALIBRA TION:(at least 5 stds with one at
or near MDL and use of dual column for confirmation) p
Date of calibratim1. 3/24/8]
2-/2.<i D.3
All standards and solutions prepared/utilized within method r~,.,..,:>
reauired holdine times p
External standard calculation used with r > 0.990 p
DDT and'Endrin deeradation < 15% p
DAILY OR CONTINUING CALIBRATION Date analyzed: 3/03/03
(beginning of each dav and everv IO samoles) p
Midnoint calibration std run to verify:
1. Run midpoint cal std to check all analytes <15% Diff. p
2. DDT and Endrin degradation< 1_5% p
3. 1 of2 Surrogate% rec within laboratorv control limits p
SAMPLE CRITERIA
1. Bracketed by in-control CV s p
2. 1 of 2 Surrogates % rec within laboratory control limits p
3. Peak RT window+/-3X Std. Dev. of the standard's RT p
4. Analvzed within workine range of the curve(<hiehest std) p
I hereby certify that all the above information is correct to the best of my knowledge. All out-of-
con_trol measurements relating to the method required acceptance criteria have been documented
in the above table along with any known possible effects on the sample analytical data.
Name: _ _,P'"'a""u...,Ja~A.,_. ,._P.,,u_,..ll""ey,__ _____ _ Date: 3/21/03
(print) Ji
"
QA Officer Signatur ·
Kubal-Furr & Associates
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INSTRUMENT QC ASSESSMENT SUMMARY
FOR EPA METHOD 8151A
For Samples: lab ID# L03022401-0l
lab ID # L03022401-02
lab ID# ____ _
lab ID# ____ _
CRITERIA
lab ID# ____ _ lab ID# ____ _
lab ID# ____ _ lab ID# ____ _
lab ID# ____ _ lab ID# ____ _
lab ID# ____ _ lab ID# ____ _
PIF COMMENTS
INITIAL CALIBRA TION:(at least 5 stds with one at p Date of calibration: 1/22/03
or near MDL and use of dual column for confirmation)
External standard calculation used with r > 0.990 p
DAILY OR CONTINUING CALIBRATION Date analyzed: 3/03/03
(beginning of run and everv IO samoles) p
Midpoint calibration std run to verify:
1. Run midpoint cal std to check all analytes within 15% of p
true value
2. Surrogate% rec within lab generated control limits p
SAMPLE CRITERIA
1. Bracketed by in control CV s p
2. Surrogate% rec within lab generated control limits p
3. Analvzed within working range of the curve(<highest std) p
I hereby certify that all the above information is correct to the best of my knowledge. All out-of-
control measurements relating to the method required acceptance criteria have been documented
in the above table along with any known possible effects on the sample analytical data.
Name: Paula A. Pulley Date: 3/21/03
(print)
Name: ~A-~
(sign) ' { 1
QA Officcr S@'Mfil'.~ i;;i2)~
Kubal-Furr & Associates
19
INSTRUMENT QC ASSESSMENT SUMMARY
FOR EPA METHOD 6010B
For Samples: lab ID# L03022401-0l lab ID# ____ _ lab ID# ____ _
lab ID# L03022401-02 lab ID# ____ _ lab ID# ____ _
lab ID# ____ lab ID# ____ _ lab ID# ____ _
lab ID# ____ lab ID# ____ _ lab ID# ____ _
CRITERIA PIF COMMENTS
INITIAL CALIBRATION: (at least one std and blk daily) p Date of calibration: 2/27/03,
3/5/03
All standards and solutions prepared/utilized within method required p
holding times
Cal Std analvzcd before samnle analvses -95 -105% recoverv limits p
Interference check solution analyzed at the beginning and the end of p
the run (or every 8 hr-whichever is more frequent) with results within '
method required control limits of80 -120%
Second source initial calibration verification and initial calibration p
blank analV?ed with results within method control limits
CONTINUING CALIBRATION
A continuing calibration verification standard (instrument check std) p
and continuing calibration blank analyzed every 10 samples and at
the end of the analvtical run with results within method control limits
SAMPLE CRITERIA
1. Analyzed within linear range of the curve p
2. Serial Dilution (4X) oerformed if new matrix -(+/-) 10% of true p
I hereby certify that all the above information is correct to the best ofmy knowledge. All out-of-control
measurements relating to the method required acceptance criteria have been documented in the above
tab_le along with any known possible effects on the sample analytical data.
Name: Mary P. Maus
(print) ,
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Name: tfl°1 (f' /Ylo.,:.<--
(sign)
Date: --=3"-'/2".!l.:.c/0""3 __ _
Kubal-Furr & Associates
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INSTRUMENT QC ASSESSMENT SUMMARY
FOR EPA METHOD 7470A/7471A
For Samples: lab ID# L03022401-0l lab ID# lab 1D #
lab ID# L03022401-02 lab ID# lab ID#
lab ID# lab ID# lab ID#
lab ID# lab ID# lab 1D #
lab ID# lab ID# lab ID#
lab ID# lab ID# lab ID#
CRITERIA PIF COMMENTS
INITIAL CALIBRATION:(a blank and at least 5 p Date of calibration:
standards with r > 0.995 daily)
All standards and solutions prepared/utilized within method p
required holding times
Second source initial calibration verification and initial p
calibration blank analyzed immediately after calibration curve
with results within method reauired control limits
CONTINUING CALIBRATION
A continuing calibration verification standard and continuing p
calibration blank analyzed every 10 samples and at the end of
the analytical run with results within method required control
limits
SAMPLE CRITERIA
I. Analyzed within working range of the curve( <highest std) p
2. MSAs performed as needed and within method control p
limits
3/03/03
I hereby certify that all the above information is correct to the best of my knowledge. All out-of-
control measurements relating to the method required acceptance criteria have been documented
in the above table along w_ith any known possible effects on the sample analytical data.
I I: ,.,
Name: ___ M_a_ry~P_._M_a_u_s ______ _ Date: 3/21/03
(print)
'
Kubal-Furr & Associates
21'
Df\YIS
FLtJYD
;.,
" .f
LABORATORY ANALYSIS REPORT
Batch QC Data
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Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E.22rst Avenue I Greenwood, SC 29649 I [phone] I fax [phone] I
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Df\YIS
FLMD LABORATORY ANALYSIS REPORT
QC Batch Report
WorkGroup WG33183
Description: op/tclp/zbe
Sample ID
L03022401-0l
L03022401-02
L03022401-03
LCS33183:l
MB33183:l
MS03022401-01 : 3 3183
MS03022401-02:33183
MSD03022401-01:33183
MSDOJ022401-02:33183
Client ID
SBR SLUDGE
FP SLUDGE
SLUDGE TRIP BLANK
Laboratory Control Spike
Method Blank
Matrix Spike
Matrix Spike
Matrix Spike Duplicate
Matrix Spike Duplicate ·.-
Run#
Report Date March 17, 2003
Page 1 of Report ID: AB4732
Matrix Leachate
Prep Method
Analtyica] Method: SW846 1311/8260B
PREP
Date Time
ANALYTICAL
Date Time
03/06/03 1714
03/06/03 1845
03/06/03 1644
03/06/03 2 01 7
03/06/03 1613
03/06/03 1745
03/06/03 1916
03/06/03 1815
03/06/03 194 6
Analyst Dilution
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP
10
10
10
10
10
10
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 2?648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
23
DAYIS
FLtwD LABORATORY ANALYSIS REPORT
Surrogates % Recovery
L03022401-01
103022401-02
103022401-03
LCS33183:l
MB33183:l
MS03022401-0l:33183
MS03022401-02:331B3
MSD03022401-0l:331B3
MS003022401-02:33183
06-M.AR-03
06-MAR-03
06-MAR-03
06-MAR-03
06-MAR-03
06 MAR-03
06 MAR-03
06 MAR-OJ
06 MAR-OJ
DCE 1,2-DICHLOROETHANE-D4
BFB BROMOFLUOROBENZENE
TOL TOLUENE-DB
17:14
18:45
16:44
20:17
16: 13
17 : 45
19: 16
18 : 15
19: 46
·ocE< ·
:..:_;,:~· tJ·~:.
97
98
102
102
101
95
96
98
97
91
93
96
102
95
100
100
100
98
Report Date
Page 1 of 1
Matrix
March l 7, 2003
Report ID: AB4747
Leachate
workGroup: WG33183
Method SW846 1311/8260
99
101
102
103
102
98
98
99
97
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Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue
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I Greenwood, SC 2%49 I (864) 229-44 LI I fax W64) 229-71191
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DJWIS
FLffi'D LABORATORY ANALYSIS REPORT
Method Blanks
Blank
Parameter
Volatile Organics TCLP
SW846 1311/8260B
1,1-0ICHLOROETHENE
1,2-DICHLOROETHANE
2-BUTANONE
BENZENE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROFORM
TETRACHLOROETHENE
TRICHLOROETHENE
VINYL CHLORIDE
Prep Procedure
Analytical Prep Procedures:
ZHE EXTRACTION
MB33183:l
Method
SWB46 1311
f
cone
' 0. 0050
' 0 . 0050
' 0. 010
' 0. 0050
' 0 .0050
' o. 0050
' 0. 0050
' 0. 0050
0 . 0050
0.010
Analyst Prep Date
DBC 02/26/03
Report Date March 1 7, 2003
Page 1 of Report ID: AB4728
Matrix Leachate
WorkGroup, WG33183
Qual RDL units Analyst Date Time
0. 0050 mg/1 PAP 03/06/03 1613
0 . 0050 mg/1 PAP 03/06/03 161)
0. 010 mg/1 PAP 03/06/03 1613
o. 0050 mg/1 PAP 03/06/03 1613
0 .0050 mg/1 PAP 03/06/03 1613
o. 0050 mg/1 PAP 03/06/03 1613
0. 0050 mg/1 PAP 03/06/03 1613
0 .0050 mg/1 PAP 03/06/03 1613
0 . 0050 mg/1 PAP 03/06/03 1613
0.010 mg/1 PAP 03/06/03 1613
1530
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
25
DAYIS
FLtJ\7D LABORATORY ANALYSIS REPORT
Matrix Spikes and Duplicates
MS/MSD
Pa'l'.a'm~:t~/ · ·
1,1-DICHLOROETHENE
1,2-0ICHLOR~ETHANE
2-BUTANONE
BENZENE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROFORM
TETRACHLOROETHENE
TRICHLOROETHENE
VINYL CHLORIDE
1,1-DICHLOROETHENE
1,2-DICHLOROETHANE
2-BUTANONE
BENZENE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROFORM
TETRACHLOROETHENE
TRICHLOROETHENE
VINYL CHLORIDE
NOTE: MS/MSD \-.,recoveries
MS03022401-01:33183
MSD03022401-01:33183
o. 500
0. 500
o. 500
o. 500
0, 500
0, 500
0, 500
o, 500
0 .500
0 .500
0 .soc
o. 500
o. 500
0 .500
0 .500
o .. 500
0 .500
0 .500
0, 500
o, 500
are not evaluated if the ,,
J
< 0 .0500
< 0 .0500
< o. 100
< 0 .0500
< 0 .0500
< 0 . 0500
< 0 .0500
< 0 .0500
< 0 .0500
< o. 100
0 .485
0. 530
0 .323
0 .507
0 .515
0. 514
0 .504
0 .516
o, 516
0. 469
Report Date March 17, 2 003
Page 1 of Report ID: AB4730
Matrix Leachate
WorkGroup: WG33183
Method SW846 1311/8260B
MS,': ::Mif. L1-~it·s· · c~·~-~:.-· .= .. ·.::.:-:·:\k}c'-<,·
0 .492. 98
0 . 529 106
0 . 341 68
0 .510 102
0 .521 104
0 .508 102
0 .500 100
0 .519 104
0 .520 104
0 .480 96
97 1
106 0
65 5
101 1
103 1
103
101
103 1
103
94 2
. : . .;k~}-
19-129
79-139
54-213
72-133
66-139
70-133
72-138
82-120
78-130
75-143
20
14
21
10
10
10
10
10
15
11
79-129
79-139
54-213
72-133
66-139
70-133
72-138
82-120
78-130
75-143
sample ~oncentration i, greater than four times the spike added.
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Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue
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! Greenwood, SC 29649 I [phone] I Fax (8fi4) 229-7119 I
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DAYIS
FLbYD LABORATORY ANALYSIS REPORT
Matrix Spikes and Duplicates
MS/MSD
Par"arrieter:
1,1-DICHLOROETHENE
1,2-DICHLOR~ETHANE
2-BUTANONE
BENZENE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROFORM
TETRACHLOROETHENE
TRICHLOROETHENE
VINYL CHLORIDE
1,1-DICHLOROETHENE
1, 2-DICHLOROETHANE
2-BUTANONE
BENZENE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROFORM
TETRACHLOROETHENE
TRICHLOROETHENE
VINYL CHLORIDE
MS03022401-02:33183
MSD0302240l-02:33183
sPik~ ·Add ea,:·
o. 500
o. 500
0, 500
o. 500
o. 500
0, 500
o. 500
o. 500
o. 500
0 .500
·· ~t'.i:k~
··iAddect.
0. 500
0, 500
0. 500
o. 500
o. 500
o .. 500
0, 500
0, 500
o. 500
0. 500
s:amP1e ..
-.co-nc·-·
< 0 .0500
< 0 .0500
< 0, 100
< 0. 0500
< 0 .0500
< o. 0500
< 0 .0500
< 0 .0500
0 . 0500
< 0 .100
·.:::••:-Msb
·-:-.-:,.:¢~~c,.
0 .471
0 .521
0 . 346
0 . 492
0, 500
0, 500
0, 492
0 .500
0 .510
0 . 460
Report Date March 17, 2003
Page 1 of Report ID: AB4 731
Matrix Leachate
WorkGroup: WG33183
Method SW846 1311/8260B
·MS :-··:Mi:i' . L·i'11li ts
ConC(
._ .. _. , .. ·i-_REC ;-%REC
0 .447 89 79-129
0 . 487 97 79-139
0, 3 3 2 66 54-213
0 .476 95 72-133
0 .476 95 66-139
0 .475 95 70-133
0 .461 92 72-138
0 .482 96 B2-120
0 . 4 83 97 78-130
o. 427 85 75-143
94 5 20 79-129
104 7 14 79-139
69 4 21 54-213
98 3 10 72-133
100 5 10 66-139
100 5 10 70-133
98 6 10 72-138
100 4 10 82-120
102 5 15 78-130
92 7 11 75-143
NOTB: MS/MSD l recoveries are no~ evaluated if the sample concentration is greater than four times the spike added.
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Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I B 16 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax {864) 229-7119
27
DAYIS
FLtWD LABORATORY ANALYSIS REPORT
Laboratory Control Standards and Duplicates
LCS
: ... :: . ··.-.. ::·-):i::·)
.. Pa.rame·t:e·{: ·
1,1-DICHLOROETHENE
1,2-D!CHLORQETHANE
2·BUTANONE
BENZENE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROFORM
TETRACHLOROETHENE
TR I CHLOROETHENE
VINYL CHLORIDE
LCS33183: 1
0.0200
0.0200
0, 0200
0 .0200
0 .0200
0 . 0200
0 0200
0.0200
0.0200
0 .0200
0 0190
0, 0209
0 0197
0. 0200
0 .0201
0 . 0205
o, 0198
0 0203
0. 0213
0 .0184
95
105
99
100
101
102
99
101
107
92
Report Date March 17, 2003
Page 1 of 1 Report ID: A84 729
Matrix Leachate
WorkGroup: WG33183
Method SW846 1311/8260B
-··-::::.:d~it·~:-·:·=. <q~:f~-:::i:' -··
76-123
80-143
59-192
87-121
75-125
88-119
83-130
81-118
79-128
69-143
Davis & Floyd, Inc. ! PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I r-ax (U64) 229-7119
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DAYIS
FLOYD LABORATORY ANALYSIS REPORT
QC Batch Report
Report Date March 17, 2 003
Page l of Report IO: AB4 7 3 7
Matrix Leachate
WorkGroup WGJ3195 Prep Method SW846 1311/3500A
Description: sv/tclp Analtyical Method: SW846 1Jll/8270C
PREP ANALYTICAL
Sample ID Client ID Run# Date Time Date Time Analyst Dilution
L03022401-0l SBR SLUDGE 02/27/03 0900 03/04/03 1051 JRN
L03022401-01 SBR SLUDGE 2 02/27/03 0900 03/04/03 1051 JRN
L03022401-02 FP SLUDGE 1 02/27/03 0900 03/04/03 124 8 JRN
L03022401-02 FP SLUDGE 2 02/27/03 0900 03/04/03 1248 JRN
LCS33195:l Laboratory Control Spike 02/27/03 0900 03/04/03 1013 JRN
LCS33195:l Laboratory Control Spike 2 02/27/03 0900 03/04/03 1013 JRN
M833195: 1 Method Blank 02/27/03 0900 03/04/03 0934 JRN
MB33195: Method Blank 2 02/27/03 0900 03/04/03 0934 JRN
MS03022401-01 :33195 Matrix Spike 02/27/03 0900 03/04/03 1129 JRN
MS03022401-0l : 33195 Matrix Spike 2 02/27/03 0900 03/04/03 1129 JRN
MS03022401-02 : 33195 Matrix Spike 02/27/03 0900 03/04/03 1326 ,JRN
MS03022401-02 : 3 3195 Matrix Spike 2 02/27/03 0900 03/04/03 1326 JRN
MSD03022401-0l: 33195 Matrix Spike Duplicate 02/27/03 0900 03/04/03 1209 JRN
MSD03022401-0l: 33195 Matrix Spike Duplicate 2 02/27/03 0900 03/04/03 1209 JRN
MSD03022401-02: 33195 Matrix Spike Duplicate 02/27 /03 0900 03/04/03 1406 JRN
MSD03022401-02: 33195 Matrix Spike Duplicate 2 02/27/03 0900 03/04/03 1406 JRN
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
29
Df\YIS
FLbYD LABORATORY ANALYSIS REPORT
Surrogates % Recovery
L03022401-01 04-MAR-03 10: 51
L03022401-02 04-MAR-03 12: 48
LCS33195: 1 04-MAR-03 10: 13
MB33195,l 04-MAR-03 09 34
MS03022401-0l: 33195 04-MAR-03 11 : 29
MS03022401-02 :33195 04 -MAR-03 13 : 26
MSD03022401-01 ,33195 04-MAR-03 12: 09
MSD03022401-02:33195 04-MAR-03 14: 06
TBP 2,4,6-TRIBROMOPHENOL
FBP 2-FLUOROBIPHENYL
2FP 2-FLUOROPHENOL
NBZ NITROBEN~ENE-D5
PHL PHENOL-OS
>TBP"·./·' .•,: FBP
Report Date
Page 1 of 1
Matrix
March 17, 2003
Report ID: AB4748
Leachate
WorkGroup: WG33195
Method SW846 1311/8270
'iFP:;-.-·., NBZ -. .-~-sx~x;,·: ....... ?::;;:-J1:~i/:.:·:"· 1-:1~).\ ... ··:·•\{6) i'f<.
. Pin/·
~/as
80 55 37 63 24
81 59 41 68 26
62 61 32 66 24
73 62 41 69 27
77 52 35 59 23
88 62 40 70 27
79 60 37 66 25
77 57 38 64 24
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Ours! Avenue ! Greenwood, SC 29649 I (864} 229-4413 J Fax {864) 229-7119
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FLtWD
Method Blanks
Blank
Parameter
Semivolatile Organics TCLP
SW846 1311/8270C
1,4-DICHLORqBENZENE
2,4,5-TRICHLOROPHENOL
2,4,6-TRICHLOROPHENOL
2,4-DINITROTOLUENE
2-METHYLPHENOL
3&4-METHYLPHENOL
HEXACHLOROBENZENE
HEXACHLOROBUTADIENE
HEXACHLOROETHANE
NITROBENZENE
PENTACHLOROPHENOL
PYRIDINE
Prep Procedure
Analytical Prep Procedures:
MB33195:l
Method
LABORATORY ANALYSIS REPORT
Report Date March 17' 2003
Page 1 of 1 Report ID: A84733
Matrix Leachate
WorkGroup: WG33195
Cone Qual RDL Units Analyst Date Time
0. 10 0. 10 mg/1 JRN 03/04/03 0934
< 0. 10 0. 10 mg/1 JRN 03/04/03 0934
< 0. 10 0 .10 mg/1 JRN 03/04/03 0934
< 0 .10 o. 10 mg/1 JRN 03/04/03 0934
< 0 . 10 0. 10 mg/1 JRN 03/04/03 0934
< o. 10 o. 10 mg/1 JRN 03/04/03 09)(1
' o. 10 o. 10 mg/1 JRN 03/04/03 0934
0. 10 o. 10 mg/1 JRN 03/04/03 0934
o. 10 o. 10 mg/1 JRN 03/04/03 0934
' o. 10 o. 10 mg/1 JRN 03/04/03 0934
' 0 .25 0 .25 mg/1 JRN 03/04/03 0934
' 0. 10 o. 10 mg/1 JRN 03/04/03 0934
Analyst Prep Date
TCLP SEMIVOLATILES SW846 1311/3SOOA DBC 02/27/03 0900
Davis & Floyd, Inc. \ PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 2%49 I [phone] I Fax [phone]
31
DAYIS
FLMD LABORATORY ANALYSIS REPORT
Matrix Spikes and Duplicates
MS/MSD
.· .. ·, .. :··::,:-:
Para~et.~i:"/=·· ··
3&4-METHYLPHENOL
PYRIDINE
1,4-DICHLORciBENZENE
2,4,5-TRICHLOROPHENOL
2,4,6-TRICHLOROPHENOL
2,4-DINITROTOLUENE
2-METHYLPHENOL
HEXACHLOROBENZENE
HEXACHLOROBUTADIENE
HEXACHLOROETHANE
NITROBENZENE
PENTACHLOROPHENOL
3&4-METHYLPHENOL
PYRIDINE
1,4-DICHLOROBENZENE
2,4,5-TRICHLOROPHENOL
2,4,6-TRICHLOROPHENOL
2,4-0INITROTOLUENE
2-METHYLPHENOL
HEXACHLOROBENZENE
HEXACHLOROBUTADIENE
HEXACHLOROETHANE
NITROBENZENE
PENTACHLOROPHENOL
MS03022401-0l:33195
MSD03022401-0l:33195
Si:/ike
Add~d
2 . 00
0 .500
0 .500
1 .oo
1 .00
o. 500
. 00
0 .500
0. 500
0 .500
0 .500
.00
· .. · . ..-:iSPfke:
;::~~d~d::
2.00
0.500
0.500
1.00
.00
0. 500
1.00
0. 500
0.500
0.500
0. 500
1.00
Report Date March 1 7, 2003
Page 1 of Report ID: A84735
Matrix Leachate
WorkGroup: WG33195
Method SWB46 1311/8270C
_s~~p1·~ ·:-Ms·.: Ms·t .:·.· \C~ri~\:·· .: ":.·/·~~~{::/ . ':_: _:/::·;;~-~!:::"· Limits-.·
< o. 100 0 . 940
< 0. 100 0. 151
< 0. 100 0. 185
< 0 .100 0 . 649
< o. 100 0.623
< o. 100 0 .288
< o. 100 0 . 536
< o. 100 0 . 252
< 0. 100 0 .167
0. 100 o. 174
< 0. 100 0 .292
< 0 . 250 0 .873
.02 51
0. 180 36
0 .213 43
0 . 726 73
0 .664 66
0. 327 65
0 .586 59
0 .271 54
0 .198 40
0. 194 39
0 .331 66
0 .885 89
47
30
37
65
62
SB
54
50
33
35
SB
87
8
17
14
11
6
13
9
7
17
11
13
':iREC
19-101
10-84
25-88
23-101
26-106
38-120
17-91
41-93
17-101
20-86
34-109
12-132
20
34
22
26
25
19
21
15
20
23
21
27
19-101
10-84
25-88
23-101
26-106
38-120
17-91
41-93
17-101
20-86
34-109
12 132
NOTB: MS/MSD \ recoveries are not evaluated if the sample concentration is greater than four times the spike added.
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Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 j ti 16 E. Durst Avenue
32
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DAYIS
FLbYD LABORATORY ANALYSIS REPORT
Matrix Spikes and Duplicates
MS/MSD
Pa_rame_ter.:.,.. ·
3&4-METHYLPHENOL
PYRIDINE
1,4-DICHLOROBENZENE
2,4,5-TRICHLOROPHENOL
2,4,6-TRICHLOROPHENOL
2,4-DINITROTOLUENE
2-METHYLPHENOL
HEXACHLOROBENZENE
HEXACHLOROBUTADIENE
HEXACHLOROETHANE
NITROBENZENE
PENTACHLOROPHENOL
3&4-METHYLPHENOL
PYRIDINE
1,4-DICHLOROBENZENE
2, 4, 5-TRICHLOROPHENOL
2,4,6-TRICHLOROPHENOL
2,4-DINITROTOLUENE
2-METHYLPHENOL
HEXACHLOROBENZENE
HEXACHLOROBlITADIENE
HEXACHLOROETHANE
NITROBENZENE
PENTACHLOROPHENOL
MS03022401-02:33195
MSD03022401-02:33195
.:sp_i·ke ·
Ad~ed
2.00
0.500
0 .500
.00
1 .00
0 .500
1.00
0. 500
0 .500
0 .500
0. 500
1. 00
Sp_ike, · .,·)-l'ddia
2.00
0. 500
0. 500
.00
.00
0.500
1.00
0.500
O. 500
0.500
0. 500
. 00
.. sa~p·1_~
·cci'riC··
' 0 .100
' 0. 100
' o. 100
' o. 100
' o. 100
' 0 .100
0 .100
' o. 100
' o. 100
' o. 100
' 0. 100
' o. 250
. 04
0 .203
0. 198
0 .694
0 .679
0 .316
0 .585
0 .255
0. 184
o. 188
0 . 314
0 .853
Report Date March 17, 2003
Page 1 of Report ID: AB4736
Matrix Leachate
WorkGroup: WG33195
Mechod SW846 1311/8270C
·.-Ms· -.-.:•" . ·MS· .:,_.L'imits
Cone· ··,_>\~Ex: \REC
.08 54 19-101
0. 199 40 10-84
0 . 203 41 25-88
0 .770 77 23-101
0. 726 73 26-106
0 .347 69 38-120
0 .604 60 17-91
o. 294 59 41-93
0 .188 38 17-101
o. 188 38 20-8 6
0 .339 68 34-109
0 .987 99 12-132
52 4 20 19-101
41 2 34 J0-84
40 2 22 25-88
69 10 26 23-101
68 7 25 26-106
63 9 19 38-120
59 3 21 17-91
51 14 15 41-93
37 2 20 17-101
38 0 23 20-86
63 8 21 34-109
85 15 27 12-132
I NOTB, MS/MSD • recoveries are not evaluated if the sample concentration is greater, than four times the spike added.
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I Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue j Greenwood, SC 29649 I [phone] I Fax [phone]
33
DAYIS
FLtlYD LABORATORY ANALYSIS REPORT
Laboratory Control Standards and Duplicates
LCS
1,4-DICHLOROBENZENE
2, 4, 5-TRICHL_0R0PHEN0L
2,4,6-TRICHLOROPHENOL
2,4-DINITROTOLUENE
2 -METHYLPHENOL
HEXACHLOROBENZENE
HEXACHLOROBUTADIENE
HEXACHLOROETHANE
NITROBENZENE
PENTACHLOR0PIIEN0L
3&4-METHYLPHENOL
PYRIDINE
LCS33195: 1
·· · :·A'P·~ ·k_e_
. ?,d~ect< ····
0.500
.00
1.00
0.500
1.00
0. 500
0.500
0.500
0.500
1.00
2.00
0. 500
-'ibi .:··ci~r:·
0 206
0.545
0 493
0 313
0.597
0. 269
o. 181
o. 192
o. 334
0 .481
. 04
0 . 218
41
55
49
63
60
54
36
38
67
48
52
44
Report Date
Page 1 of 1
March 17, 2003
Report ID: AB4734
Matrix Leachate
WorkGroup: WG33195
Method SW846 1311/8270C
12-101
27-93
29-99
44-113
24-88
39-95
5-111
6-101
30-107
26-123
17-97
3-85
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 81 6 I::. Dwst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
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DAYIS
FLOYD LABORATORY ANALYSIS REPORT
QC Batch Report
Report Date March 17, 2003
Pagel of 1 Report ID: AB4749
Matrix Leachate
Workciroup WG33218 Prep Method SW846 1311/BlSlA
Description: PS/TCLP/HERB .. 0228XH Analtyical Method; SW846 1311/BlSlA
PREP ANALYTICAL
Sample ID Client ID •=• Date Time Date Time Analyst Dilution
L03022401-0~ SER SLUDGE 1 02/28/03 0800 03/03/03 1806 JMT
L03022401-02 FP SLUDGE 02/28/03 0800 03/03/03 1907 JMT
LCS33218: 1 Laboratory Control Spike 1 02/28/03 0800 03/03/03 1745 JMT
MB33218:l Method Blank 02/28/03 0800 03/03/03 1725 JMT
MS03022401-0l :33218 Matrix Spike 02/28/03 0800 03/03/03 1826 JMT
MS03022401-02: 33218 Matrix Spike 02/28/03 0800 03/03/03 1927 JMT
MSD03022401-0l :33218 Matrix Spike Duplicate 02/28/03 0800 03/03/03 1847 JMT
MSD03022401-02:33218 Matrix Spike Duplicate 02/28/03 0800 03/03/03 194 8 JMT
Davis & Floyd, Inc. I PO Drawer428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone]] I fax [phone]
35
Df\YIS
FLOYD LABORATORY ANALYSIS REPORT
Surrogates % Recovery
L03022401·01
L03022401-02
LCS33218:l
MB33218:l
MS03022401-0l 33218
MS03022401-02·33218
MSD03022401-01:33218
MSD03022401-02:33218
.. .. Me.aSuYeoa't·~-·
03-MAR-03 18: 06
03-MAR-03 19:07
03-MAR-03 17 45
0)-MAR-03 17 : 25
03-MAR-03 18 : 26
03-MAR-03 19: 27
03-MAR-03 18 : 47
03-MAR-03 19 : 4 8
OTl-!ER 2, 4 -DICHLOROPHENYLACETIC ACID
OTHER.
57-151
102
99
105
94
102
96
103
110
Report Date March 17, 2003
Page 1 of 1 Report ID: AB4751
Matrix Leachate
WorkGroup: WG33218
Method SW846 1311/8151
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Davis & Floyd, Inc. ,I PO Drawer 428 I Greenwood, SC 29648 I 816E,;6r51 Avenue I Greenwood, SC 2%49 I [phone] I Fax [phone] I
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DAYIS
FLtWD
Method Blanks
Blank MB33218:1
Paral!leter
Pesticides and Herbicides TCLP
SW846 1311/BlSlA
2,4,5-TP (SI.LVEX)
2,4-D
Prep Procedure
Analytical Prep Procedures:
Method
LABORATORY ANALYSIS REPORT
Cone
0. 002 5
0.025
Analyst Prep Date
Report Date March 17,
Page 1 of 1 Report ID:
Matrix Leachate
WorkGroup, WG33218
Qual RDL
0.0025
0.025
Units
mg/l
mg/1
2003
AB4743
Analyst Date Time
JMT 03/03/03 1725
JMT 03/03/03 1725
TCLP HERBICIDES SW846 1311/8151A DBC 02/28/03 0800
Davis & Floyd, Inc. I PO Drawer 428 \ Greenwood, SC 29648 \ 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
37
DAYIS
FLtrYD LABORATORY ANALYSIS REPORT
Matrix Spikes and Duplicates
MS/MSD
::::··._ ···:•:>-· .-:::-· :,::::·:: ··-,:::.
.:.::-~a;!-~~'.{~{:\.
2,4,5-TP (SILVEX)
2,4-D
2,4,5-TP (SILVEX)
2,4-D
MS03022401-01:33218
MSD03022401-0l:3321B
Report Date
Page 1 of 1
Matrix
WorkGroup;
Method
March 17, 2003
Report ID: A84745
Leachate
WG33218
SW846 1311/BlSlA
-,_s:~·!llpie·.: ···· _:-Mr.-
. ··:.·:?tc1d~d:?:/.-· ?CO/i~·.: ·:=-/C~ir?>:-=-· · '·=:i~Ec .·, ~R,E;C
58-133
76-157
0.00500
0.0500
0.00500
0.0500
< 0.00250 0.00330
< 0.0250
0. 00387
0.0412
0.0412
77
82
66
82
16
0
20
21
NOTE: MS/MSD \ recoveries are not evaluated if the sample concentration is greater than four times the spike added.
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Dav;s & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 8 I 6 \ ~urst Avenue I Greenwood, SC 29649 I 1864) 229-4413 I \'ax 11164) 22'1-71191
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D}\VIS
FLfilD LABORATORY ANALYSIS REPORT
Matrix Spikes and Duplicates
MS/MSD
Pilra~~-~e~.
2,4,5-TP (SILVEX)
2, 4-D
Parame~er
2,4,5-TP (SILVEX)
2 ,4 D
MS03022401-02:33218
MSD03022401-02:33218
=:·-sp_iJ<e ..
Ai:l.ctect,-:
0.00500
0.0500
-. ~pi~e
·=·· -, · Adct~i
0 00500
0.0500
_Sample
Cone
< 0.00250
< 0 0250
MSD
COnc
0 00435
0. 04 71
,
Report Date March 17, 2003
Page 1 of 1 Report ID: AB4746
Matrix Leachate
workGroup: WG33218
Method SWB46 1311/8151A
MS ·MS Lfriiits ·
cOllc'/·: %REC ··_\REC
o. 00332 66 58-133
0.0418 84 76-157
Li'in'i tS .
"\RP□-.·\RP□.:. %REC, ..
87 27 20 58-133
94 12 21 76-157
NOTE: MS/MSD \ recoveries are not evaluated if the sample concentration is greater than four times the spike added.
Davis & Floyd, Inc. I PO Drawer 428 \ Greenwood, SC 29648 ( 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I F;-ix (H64) 229-7119
39
DAYIS
FLOYD LABORATORY ANALYSIS REPORT
Laboratory Control Standards and Duplicates
LCS
· Pa~:)m·et·;/\_: .:: .-:·
2,4,5-TP (SILVEX)
2,4-D
LCS33218:l
Report Date
Page 1 of 1
Matrix
March 17, 2003
Report JD; AB4744
Leachate
workGroup: WG33218
Method SW846 1311/8151A
······ · -=-=--.-·-=··=.•::::.::.-:)_:,._:\i/}:?~:~:1.~i;: :.... -· _;· Les · .. .-··1,cs<:= -. · ... -,-=/,(·Li~tt~= ./ ·= ... ~
·:A~dect:-: ''• ::\:o~c ':.·:···ii~'~ :i ..... :. ":""--\'Ri;_:. :_:· .. ~
0.00500 0.00 04 81 58-129
0.0500 0.0408 B2 76-149
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Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 81 f, E;{o'"' Avenue I Greenwood, SC 29649 I [phone] I Fax [phone] I
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Df\VIS
FLtwD LABORATORY ANALYSIS REPORT
QC Batch Report
Report Date March 17, 2003
Page 1 of Report ID: AB4742
Matrix Leachate
workGroup WG33198 Prep Method SW846 1311/3510C
Description: PS/TCLP/PEST .. 0227XP Analtyical Method: SW846 1311/BOBlA
PREP ANALYTICAL
SaJI'lple ID Client ID R=# Date Time Date Time Analyst Dilution
L03022401-0l SBR SLUDGE 02/27/03 1330 03/03/03 2012 JMT
L03022401-02 FP SLUDGE 02/27/03 1330 03/03/03 2152 JMT
LCS33198:l Laboratory Control Spike 02/27/03 1330 03/03/03 1939 JMT
MB33198: 1 Method Blank 02/27/03 ll30 03/03/03 1906 JMT
MS03022401-01 :33198 Matrix Spike 02/27/03 1330 03/03/03 2045 JMT
MS03022401-02 :33198 Matrix Spike 02/27/03 1330 03/03/03 2225 JMT
MSD03022401-01 :33198 Matrix Spike Duplicate 02/27/03 1330 03/03/03 2118 JMT
MSD03022401-02:33198 Matrix Spike Duplicate 02/27/03 1330 03/03/03 2258 JMT
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I (1-1641 229-4413 I Fax [phone]
41
DAYIS
FLbYD LABORATORY ANALYSIS REPORT
Surrogates % Recovery
L03022401-0l 03-MAR-03 20: 12
I,03022401-02 03-MAR-03 21: 52
LCS33198:l 03-MAR-03 19 39
M833198:l 03-MAR-03 19 06
MS0302240l-01:33198 03-MAR-03 20 45
MS03022401-02:33198 03-MAR-03 22 : 25
MS003022401·01: 3 319B 03-MAR-03 21: 18
MSD03022401-02:33198 03-MAR-03 22 :58
DCB DECACHLOROBIPHENYL
TCX TETRACHLORO-M-XYLENE
Report Date
Page 1 of 1
Matrix
March 17, 2003
Report ID: AB4750
Leachate
WorkGroup: WG33198
Method SW846 1311/8081
DCB .. ·:'(TC:t::·
·. 40-123 /\3_·~3:~:;r:·:.·::.
64 82
" 80
108 89
102 87
59 81
48 81
39 86
52 86
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Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I Ill 6 Etrs• Avenue I Greenwood, SC 2%4') I {8641 229-441 J I fax {8f,4) 229-71 19 I
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DAYIS
FL(WD
Method Blanks
Blank MB33198:l
Parameter
Pesticides and Herbicides TCLP
SW846 1311/BOBlA
CHLORDANE, TECHNICAL
ENDRIN
HEPTACHLOR
HEPTACHLOR EPOXIDE
LINDANE
METHOXYCHLOR
TOXAPHENE
Prep Procedure
Analytical Prep Procedures:
Method
LABORATORY ANALYSIS REPORT
Report Date March 17. 2003
Page 1 of 1 Report ID: AB4738
Matrix Leachate
WorkGroup: WG33198
cone Qual RDL Units Analyst Date Time
< 0.0050 0.0050 mg/1 JMT 03/03/03 1906
< 0. 00050 o. 00050 rng/1 .TMT 03/03/03 1906
< 0. 00050 0 .00050 mg/1 JMT 03/03/03 1906
< 0 .00050 0 .00050 mg/1 ,TMT 03/03/03 1906
< o. 00050 0. 00050 mg/1 JMT 03/03/03 1906
< 0 .0050 0 . 0050 mg/1 JMT 03/03/03 1906
' 0 .0050 0 . 0050 mg/1 JMT 03/03/03 1906
Analyst Prep Date
TCLP PESTICIDES SW846 1311/3510C DBC 02/27/03 1330
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 81 b E. Durst Avenue I Greenwood, SC 29649 I (864) 229-441 :1 I Fax [phone]
43
Df\YIS
FLOYD LABORATORY ANALYSIS REPORT
Matrix Spikes and Duplicates
MS/MSD
Pd.rarri~tei•
ENDRIN
HEPTACHLOR
HEPTACHLOR EPOXIDE
LINDANE
METHOXYCHLOR
.: · .. · .... ::·::\::.:.,,, ,:i-·:·
Paraf!'!eter
ENORIN
HEPTACHLOR
HEPTACHLOR EPOXIDE
LINDANE
METHOXYCHLOR
MS0302240l-Ol:33198
MSD03022401-01:33198
..... :Spi_k~
·:Added.
0.00400
0.00400
0.00400
0.00400
0.00400
0.00400
0.00400
0. 00400
0.00400
0.00400
Report Date
Page 1 of 1
March 17, 2003
Report ID: AB4740
Matrix Leachate
WorkGroup: WG33198
Method SW846 1311/8081A
1-s~~pi·~·-.·· ··_.;. Ms·
:'c~h~::::·, ·.,,·.,·.·c·6i:tJ=:/·
< 0.000500 0.00406
< 0.000500 0.00396
< 0.000500 0.00389
< 0.000500 0.00376
< 0.00500 0.00411
0. 00422
0.00417
0.00413
0.00391
0.00429
106
104
103
98
107
n;;s=;/:.-·
-\-REC
101
99
97
94
103
4
5
6
4
4
.... ·Liriiits·_::-c:·.
·,·RE·~
59-119
48-111
53-112
52-112
60-131
19
20
17
20
17
59-119
48-lll
53-112
52-112
60-131
NOTB: MS/MSD \ recoveries are not evaluated if the sample concentration is greater th<m four times the spike added.
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Di\YIS
FLOYD LABORATORY ANALYSIS REPORT
Matrix Spikes and Duplicates
MS/MSD
·Par.amet_er
ENDRIN
HEPTACHLOR
HEPTACHLOR EPOXIDE
LINDANE
METHOXYCHLOR
·_· :::-··:_:::,::-=_ :: ...
Pa·rainet~·f-,·:
ENDRIN
HEPTACHLOR
HEPTACHLOR EPOXIDE
LINDANE
METHOXYCHLOR
MS03022401-02:33198
MSD03022401-02:33198
Spike
f,.dded
o. 00400
0. 00400
0. 00400
0. 00400
0. 00400
Spike.
Added
0.00400
0.00400
0.00400
0.00400
0.00400
Report Date March 17, 2003
Page 1 of 1 Report ID: AB474 l
Matrix Leachate
WorkGroup: WG33198
Method
.'.S_am~le :MS
Cone Cone
< 0 .000500 0 .00409
< 0 .000500 0 . 004 00
0 .000500 0 . 004 03
< 0 .000500 0 .00378
< 0, 00500 0 .00410
M.so:: :'MS□'
~6ii~--\~-RE6·
o. 00446 112
0, 00421 105
o, 00428 107
o, 00417 104
o. 00444 111
SW946
:.: MS-
. \REC
102
100
101
95
103
\-RPO
9
5
6
10
8
131 l/8081A
%REC
59-119
48-111
53-112
52-112
60-131
.·:.Liinits
·.-~RP~
19
20
17
20
17
iR~C
59-119
48-111
53-112
52-112
60-131 I NOTE, MS/MSD • recoveries are not evaluated if the sample concentration is greater than four times the spike added.
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DAYIS
FLtrYD LABORATORY ANALYSIS REPORT
Laboratory Control Standards and Duplicates
LCS
.-·; .. ·. •'•'
.... p~-~~ii{~-;.-;·
ENDRIN
HEPTACHLOR
HEPTACHLOR EPOXIDE
LINDANE
METHOXYCHLOR
LCS33198:l
Spite
Adde'd' ..
0.00400
0.00400
0.00400
0.00400
0. 00400
Report Date
Page 1 of 1
Matrix
March 17, 2003
Report ID: AB4739
Leachate
WorkGroup, WG33198
Method SW846 1311/BOSlA
LCS' .. -_ ·r:.cs .. ·--·<:Ltmit_s·
:cone·· :::::\\RE:"C·.
0.00450 112
o. 00427 107
0.00425 106
0.00402 101
0 00439 110
::·:_iREc·
56-121
56-108
59-112
55-114
59-132
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FLtfYD LABORATORY ANALYSIS REPORT
QC Batch Report
Report Date March 17, 2 003
Page l of l Report TD: AB4719
Matrix Leachate
WorkGroup. WG33208 Prep Method SW846 3010
Description, 3010A TCLP (') Analtyical Method: SW846 1311/6010B
PREP ANALYTICAL
Sample ID Client ID Run# Date Time Date Time Analyst Dilution
L03022401-0l SBR SLUOOE 02/27/03 1500 02/27/03 1856 BDL
L03022401-02 FP SLUDGE 02/27/03 1500 02/27/03 1918 BDL
003022401-01: 33208 Duplicate 02/27/03 1500 02/27/03 1902 BDL
EB33208:1 Extraction Blank l 02/27/03 1500 02/27/03 2114 BDL
LCS3320B: 1 Laboratory Control Spike 02/27/03 1500 02/27/03 1851 BDL
MB33208:l Method Blank 02/27/03 1500 02/27/03 1845 BDL
MS03022025-16 : 33208 Matrix Spike 02/27/03 1500 02/27/03 1951 BDL
MS03022025-20: 33208 Matrix Spike 02/27/03 1500 02/27/03 2008 BDL
MS03022401-0l :33208 Matrix Spike 03/04/03 1600 03/05/03 1402 BDL
MS03022401-02 : 33208 Matrix Spike 02/27/03 1500 02/27/03 1924 BDL
MSD0]022401-0l :33208 Matrix Spike Duplicate 03/04/03 1600 03/05/03 14 08 BDL
MSD03022401-02: 3 32 08 Matrix Spike Duplicate 02/27/03 1500 02/27/03 1929 BDL
Davi~ & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 81 b E. Durst Avenue I Greenwood, SC 29649 I (864) 229-44 J 3 I Fax [phone] lY
47
DAYIS
FLbYD
Method Blanks
Parameter
Trace Metals TCLP
SW846 1311/6010B
ARSENIC, TOTAL
BARIUM, TOTAL
CADMIUM, TOTAL
CHROMIUM, TOTAL
LEAD, TOTAL
SELENIUM, TOTAL
SILVER, TOTAi,
Prep Procedure
Blank
Analytical Prep Procedures:
METALS PREP ICP
MB33208: 1
Method
SWB46 3010
·' i,'
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LABORATORY ANALYSIS REPORT I
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Page l of l Report ID: AB4713 I
Matrix Leachate
WorkGroup, WG33208
Cone Qual RDL Units Analyst Date Time I
I
' 0. 50 0 .50 mg/1 BDL 02/27/03 184 5
' 0 . 20 0 . 20 mg/1 BDL 02/27/03 1845
' 0.050 0.050 mg/1 BDL 02/27/03 1845
' o. 10 o. 10 mg/1 BDL 02/27/03 1845 I
' 0 . 50 0 .so rng/1 BDL 02/27/03 1845
' 0 .50 0 . 50 rng/1 BOL 02/27/03 1845
' 0. 10 0 .10 rng/1 BDL 02/27/03 1845 I
Analyst Prep Date I
BDL 02/27/03 1500 I
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DAYIS
FLOYD LABORATORY ANALYSIS REPORT
Method Blanks
Blank
Parameter
Trace Metals TCLP
SW846 1311/6010B
ARSENIC, TOTAL
BARIUM, TOTAL
CADMIUM, TOTAL
CHROMIUM, TOTAL
LEAD, TOTAL
SELENIUM, TOTAL
SILVER, TOTAL
Prep Procedure
Analytical Prep Procedures:
METALS PREP ICP
EB33208:l
Method
SW846 3010
Report Date March 1 7, 2 003
Page 1 of 1 Report ID: A84711
Matrix Leachate
WorkGroup: WG33208
Cone Qual RDL Units Analyst Date Time
< 0 50 o. so mg/1 BDL 02/27/03 2114
< 0 .20 0 . 20 mg/1 BDL 02/27/03 2114
< 0.050 0.050 mg/1 BDL 02/27/03 2114
< 0 . 10 o . 10 mg/1 BDL 02/27/03 2114
< 0 .50 0 . 50 mg/1 BDL 02/27/03 2114
< 0 .50 0 .50 mg/1 BDL 02/27/03 2114
< o. 10 0. 10 mg/1 BDL 02/27/03 2114
Analyst Prep Date
BDL 02/27/03 1500
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
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DAYIS
FLtfYD LABORATORY ANALYSIS REPORT
:,,•,•' .",:; •' ,.·•,
-para_~e·~~-; ..
ARSENIC, TOTAL
BARIUM, TOTAL
CADMIUM, TOTAL
CflROMIUM, TOTAL
LEAD, TOTAL
SELENIUM, TOTAL
SILVER, TOTAL
ARSENIC, TOTAL
BARIUM, TOTAL
CADMIUM, TOTAL
CHROMIUM, TOTAL
LEAD, TOTAL
SELENIUM, TOTAL
SILVER, TOTAL
Matrix Spikes and Duplicates
MS/MSD M$03022401-0l,33208
MSD03022401-0l:3320B
,·:_. . j~i-~~--_.-. · -· :·.s~mP1:~-
.. -_Arldect·· .. :. Ccm(:',:•
5.00 < 0.500
10.00 ' 0 . 200
.00 ' 0 .0500
5 .00 ' 0 .100
5 .00 ' 0 .500
5 . 00 ' 0 .500
.00 ' o. 100
5.00 4 -58
10.00 9. 82
1. 00 0. 944
5 .00 4 .73
5 .00 4.7)
5. 00 .58
l . 00 0. 959
Report Date
Page 1 of 1
March 17, 2003
Report ID: A84716
Matrix Leachate
WorkGroup: WG33208
Method SW846 1311/60108
:Ms:-·.·
~~n'~·-:··
4.53
9.75
0.939
4.70
4.68
4.56
0. 954
92
98
94
95
95
92
96
··:•Mi."·•:··
:--~-i~c-::·-
91
98
94
94
94
91
95
0
LilTl_lts :·.
~.REC
89-110
87-112
88-111
87-110
86-110
87-110
88-110
:L"iini tS"
%:R~p -:t"!h-:c·.
10 89-110
10 87-112
10 88-111
10 87-110
10 86-110
10 87-110
10 88-110
NOTE: MS/MSD I: recoveries are not evaluated if the sample concentration is greater than four times the spike added.
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Df\YIS
FLiWD LABORATORY ANALYSIS REPORT
Matrix Spikes and Duplicates
MS/MSD
ARSENIC, TOTAL
BARIUM, TOTAL
CADMIUM, TOTAL
CHROMIUM, TOTAL
LEAD, TOTAL
SELENIUM, TOTAL
SILVER, TOTAL
~a.r<1;m_e_t_er.
ARSENIC, TOTAL
BARIUM, TOTAL
CADMIUM, TOTAL
CHROMIUM, TOTAL
LEAD, TOTAL
SELENIUM, TOTAL
SILVER, TOTAL
MS03022401-02:33208
MSD03022401-02:33208
Spike
Added
5.00
10. 00
1. 00
s. 00
s. 00
s. 00
.00
Sp_ike
Added
5.00
10.00
. 00
5.00
5.00
5.00
.00
:-S~!l)pl~
Cone·.
< 0. 500
4 .95
< o. 0500
< o. 100
' 0 .500
< 0 .500
< o. 100
-.MSD
cone
4.90
14. 89
0. 979
4 . 99
4 . 96
4.92
.00
Report Date March 24' 2003
Page 1 of 1 Report ID, AB5359
Matrix Leachate
WorkGroup, WG33208
Method
MS
co_nc
4.84
14. 73
0 . 963
4 .90
4 . 90
4 .88
0 . 991
=·:"MSo
:%:REC
98
99
98
100
99
98
100
SW846
:MS
%REC
97
98
96
98
98
98
99
%-RPO
2
2
1311/60108
-:i.i.i\ii.°i-tS ·
%-REC
89-110
87-112
B8-111
87-110
86-110
87-110
88-110
·1,_imit:S··
·_%·R'~b-i'REC-
10 89-110
10 87-112
10 88-111
10 87-110
10 86-110
10 87-110
10 88-110
I NOTE, MS/MSD \ recoveries are not evaluated if the sample concentration is greater than four times the spike added.
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DAYIS
FLOYD LABORATORY ANALYSIS REPORT
Laboratory Control Standards and Duplicates
LCS
. ··,,.:--. -.-.·-. ..-·····
· P~ra:-~tt~{(
ARSENIC, TOTAL
BARIUM, TOT~L
CADMIUM, TOTAL
CHROMIUM, TOTAL
LEAD, TOTAL
SELENIUM, TOTAL
SILVER, TOTAL
LCS33208:l
:sp·i_k_e · ... :·:Actct·ect _ .. ,
10.00
20.00
2.00
10.00
10. 00
10.00
2.00
· Lc·s c'i·--~~-~~-:::;::-·
10.07
20.35
2 . 04
10.17
10.30
10. 15
2 . 04
Report Date March 17' 2003
Page l of l Report ID: A84712
Matrix Leachate
WorkGroup: WG33208
Method SW846 1311/60108
· -\:L'd/ .
··:·:\R~c
101
102
102
102
103
102
102
. .-:-:21~11){'' ... :~:;;;t
90-110
88-110
90-110
89-110
89-110
90-110
90-110
Davis & Floyd, Inc. I PO Dr.iwer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I fax [phone]
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FLt1YD LABORATORY ANALYSIS REPORT
QC Batch Report
Report Date March 1 7, 2003
Page 1 of 1 Report ID: AB4727
Matrix Leachate
WorkGroup. WG33228 Prep Method SW846 7470A
Description: Mercury -TCLP Analtyical Method: SW846 1311/7470A
PREP ANALYTICAL
Sample ID Client ID Run# Date Time Date Time Analyst Dilution
L03022401~01 SBR SLUDGE 03/03/03 0930 03/03/03 144 0 ACW
L03022401-02 FP SLUDGE 1 03/03/03 0930 03/03/03 1445 ACW
D03022025-38: 33228 Duplicate 1 03/03/03 0930 03/03/03 1519 ACW
EB33228:l Extraction Blank 1 03/03/03 0930 03/03/03 152 0 ACW
LCS33228:l Laboratory Control Spike 03/03/03 0930 03/03/03 143 9 ACW
MB33228: 1 Method Blank 03/03/03 0930 03/03/03 1437 ACW
MS03022025-12: 3 322 8 Matrix Spike 1 03/03/03 0930 03/03/03 1534 ACW
MS03022401-01 ; 33228 Matrix Spike 03/03/03 0930 03/03/03 1442 ACW
MS03022401-02 :33228 Matrix Spike 1 03/03/03 0930 03/03/03 1447 ACW
MSD03022401-01 :33228 Matrix Spike Duplicate 1 03/03/03 0930 03/03/03 1443 ACW
MS003022401-02 :33228 Matrix Spike Duplicate 03/05/03 0840 03/05/03 142 0 ACW
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avt:nue I Greenwood, SC 29649 I lH64) 229-4413 I Fax [phone]
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DAYIS
FLOYD LABORATORY ANALYSIS REPORT
Method Blanks
Parameter
Trace Metals TCLP
SW846 1311/7470A
MERCURY, TOTAL
Prep Procedure
Blank
Analytical Prep Procedures:
METALS PREP HG
MB33228:l
Method
SW846 7470A
Report Date March 17, 2 003
Page l of l Report ID: A84722
Matrix Leachate
WorkGroup: WG33228
Cone Qual RDL Units Analyst Date Time
0.0020 0.0020 mg/1 ACW 03/03/03 1437
Analyst Prep Date
ACW 03/03/03 0930
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I Greenwood, SC 29649 I [phone] I F_ax (864) 229-71 191
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DAYIS
FLbYD LABORATORY ANALYSIS REPORT
Parall'leter
Trace Metals TCLP
SW846 1311/7470A
MERCURY, TOTAL
Prep Procedure
Method Blanks
Blank EB33228:l
Method
Analytical Prep Procedures:
METALS PREP HG SW846 7470A
Report Date March 1 7, ?.00 3
Page 1 of 1 Report ID: AB4720
Matrix Leachate
WorkGroup: WG33228
Cone oual RDL Units Analyst Date Time
' 0.0020 0.0020 mg/1 ACW 03/03/03 1520
Analyst Prep Date
ACW 03/03/03 0930
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I (H64) 229-441 :i I Fax [phone]
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DAYIS
FLbYD LABORATORY ANALYSIS REPORT
Matrix Spikes and Duplicates
. .
. :. ::: ~a r_a·L ~~-; '; _;:::-.
MERCURY, TOTAL
/~ara;i·~~; . .:::-:<: ..
MERCURY, TOTAL
MS/MSD MS03022401-0l:33228
MSD03022401-01:33228
·sP~ke:/·
·Added
0.0100
: . Spike
\ Adde·d :-:·
0.0100
Report Date
Page 1 of 1
Matrix
March 17, 2003
Report ID: AB4724
Leachate
workGroup: WG33228
Method SW846 1311/7470A
\-iii/.... ' <: r.:·i·intts ·s:~mpJ:k.::-: ·· Ms
:,C~:~c:"/i•:··· ·::::/co~:~\:·: .' %_RF;C ...... , ::-:,::~i~•c:·\
< 0.00200 0.00984
MSb .· . :·.::::-.:··.·
·:ci:,_nc·
0.00992 99
98 71-126
·::"\~PD
1
: . Limi~s·
iRPb \REC
10 71-126
NOTE: MS/MSD \ recoveries are not evaluated if the sample concentration 1s greater than four times the spike added.
Davis & Flnyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 I::. Durst Avenue I Greenwood, SC 29649 I (B64) 229-4413 I rax (f\64) 229-71 l<J
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DAYIS
FLOYD LABORATORY ANALYSIS REPORT
Matrix Spikes and Duplicates
MERCURY, TOTAL
Parafl.1es:ej.
MERCURY, TOTAL
MS/MSD MS03022401·02:33228
MSD0)022401-02:)3228
··.· Spike
-. Added
0.0100
Sp~ke ..
Actded·
0.0100
Report Date March 17, 2003
Page 1 of 1 Report ID: AB4726
Matrix Leachate
WorkGroup: WG3322B
Method SW846 1311/7470A
"1.>.~mple MS ·-:-Ms : · •Limits·
<cOrl~ . cO~c.
< 0.00200 0.0105
·. %:REC
105
· ·,RE:"c
71-126
. C(?iiC.
0.0100
MSD ·· . ,~Et::-.. ,.:;,:.'iRPD
100 4
. L"i.rriits
\R'Po tRE~{ ·
10 71-126
NOTE, MS/MS□\ recoveries are not evaluated if the sample concentration is greater than four times the spike added.
Davis & Floyd, Inc I PO Drawer 428 I Greenwnod, SC 29648 j 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
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Df\YIS
FLtWD LABORATORY ANALYSIS REPORT
Laboratory Control Standards and Duplicates
LCS LCS3322B:l
Parc1:ffi~.~~r:
Spike· · :LCS
· Adde~ , _\2~~c \ ·
MERCURY, TOTAL 0.0200 0.0202
Report Date
Page 1 of 1
March 17, 2003
Report IO: AB4721
Matrix Leachate
WorkGroup: WG33228
Method SWB46 1311/7470A
LCS.: ·· .. ---._'_ Li~i·t·s· :-
. \REC \REC
101 90-110
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FLbYD LABORATORY ANALYSIS REPORT
Chain of Custody
I Dav;s & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I (8641 229-4413 I Fax [phone]
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-

-

-

-
-

-

-

-
-(
Chain of Custody Record PageJ_ofJ_
Client Project I Site Location 816 E. Durst Avenue, Greenwood, SC 29649 [phone] Fax: [phone] cou ..
Kubal-Furr & Associates 61621.01 Laborato,y Certitcation Numbers: SC -24110, NC· 25, TN· 2923, VA -77
' Contact R'Rrt To Copy To Reporting Requirements: { ~hdald { } Data PackaQ9 (Specify Lovet) ;J(, _,..,aH Order
Julie Lisenby · EA. C;V,0c -'(14',...,'.4 ✓UUi' l1-lc>vO 7 -,:::f-<A-!.cl/c<-Jr. :z:i::r--..fi::?--;f«K. o,zt,c?<.. ~ eflf o7
Collected By Required Parameters, Containe,s and Presetvatives Statu --/lie.,,
•='" Sf)«I-
NOTICE: ~ • ~ -,,,,,, ~ V\ --s ~ ~ .
" ~ I. 1 • ~ ~ I 11 e ~ ~ :~~ ~ ~:§ ~ 1~ ~ '-1 e e 0 ~ ~~ -0 " ~ -~ ~ ... ~-t ~ ~.{ c,__ 11 E,::: p \~ . " • fl : I 0 ':::;,, t 't "" ~ X Q ] E Q ·s E ~ c;;:): • Sample Collection ;§~ 8 ,,; • , ...J :, z
Samole Description Date Time Time Type Total I"-• HOT mmenui;
LC-33 ~J,;/,,3 IS-'/o l>( 6 3 X ~e l,tK
c & (.) 1 ?. 844 ,-,J ~ .,, I ; ~,(,3 /136 X :;. '( X: ')( .-,\ ~~2~,-. Cl I
-,~rl' 3 t..AJJ/::. # I ,:"J../4 "l o?3o X J ;,J. )(
S'bf?... S' L u D6€" Ji.;,!. 3 o?Jo IX g 3 X x:. X 01
~f SL,1,1 Vin: 'J./J-!f3 09'/o X 3 X. X X IJ'µ
ff-&~ :.1.i.,1o:, 0?,3,S-X s .3 X rr-31 i).h-1/43 /olfJ. X C' 3 X
Slu '!>6-£ 172, f ixAvi'c Jfi3/43 0')3<1 X ~ .;z X OB
F 6) LJ 1r. l>t.ANJ::K ;l_ o/;,l.3 ;,:}3 6 ½ fJ__ t/ X X
-r'-3S' ;!./_,,./;3 1J.ZS-y s-3 X
-:r:-rcr 1/:,,/{,3 /310 X s .5 X X X
::t::,c ( J..l:J_J,,J 131.s' K 1-s ,5 X X V ·:? ~~:.~'-
;.L 1C/-bx/:P ::./;,/43 131.{ X s s >< X X
..
a
//.'
/;( /// .,
Re ~·1z1, -,4:1 Time cZ£/? ___ Date nme Re/iquished By Date nmo a=@ s~
V. /S-11 2-/21/4 1/415"' y N """'
/.J.A .,, ✓/ ... ~, .;) ,...,,
1,Y Ml -vole Time Received By/ Date Time Cjf;;:;L;t:.~ i,V'i,.; Date nmo dY,,_ N,,.,, ,.,,,,.,.,
,,.,4.4 ~.i,.173 /11/5 / days
/JI/
1 l,omments / Cooler 10 (If avallabhli): --
On~ T.,,.,,_C)!t...._
Cua : Intact / en.on'~
Matnx Type Definitions 1 -Dnnklng Water 2 -Clean Water S • Groundwater 7 -S01USed1ment 8 • Liquid Sludge 9 -011 12 • Air Davia & Flo~, Inc.
Preservative Definitions A-None 8 • H2S~ C • HCI D • HNOJ E • NaOH F • Filtered G • Other FL02_01 to'MI
0
<.D
I
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LABORATORY ANALYSIS REPORT
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61
Analys1(s): oe,c.. Date: ~ -.J.C. -o~
Test Code: of' /rc.,.p /-:I!"" 6 Method:__:l_,,?>e..c.,//,__ __ _
Sample Matrix Code~ D Metals Only □ Filter Only
Batch Root: 0 .;i_ ~ ,., 'Z WG: ' "'-.I,?-,, R: i,,9(, <I (p
LIMSNUMBER Sample S>mple Prc~ct Initial pH after
I L..Q.3 Due Weight Volume pH .. INHCI
Date ,-, ~...,.(in1)':.k
-0 I A ...... .., ~ 0 I .•. ,0, I ,.q.o' i ... _,.,, I 3.l. -
0~ . ....L . ·0-~ I ---
-10 .. 0 -----------0., •• ,d..f-A ,.J,I(_ .• , ---
.
. --cr, '
N -
. ·--· -----
--·
. -·•-----------. ·-· -·--...
.
Extraction
Fluid
ID
l
Extraction Vessel: 0 Bottle G-ZHE
Rotary Extractor Unit #: _:::::i..:__
Rotation Rate (RPM)· ~ /
Ambient Temperature: .,_ 4 •c
Vessel ZHE Pressure Final Finni
Number Check (osi) pH Volume
on off (ml)
-I
I ., I'!, _.2. 1_:, I
I ----· . ...<d ···--
I :; ~--2-13_ -C---... . ->. Co
I
I --. • I ~ 0 . ------•·· ... -·-·---. -
i ' I . ··---I
-----··-: -------..
·-
·-----··-~
----··--·
I
Matrix
Group
I -
)__
--. -
Extraction Bench Sheet (TCLP)
I I -----
;
Time: On 1 >: 3 <f\nalyst 1:>,<,c.
Off~oAnalyst -oy
F...xtraction time required is 18 ± 2 hours
Ambient Temperature Range: 23 ± 2° C.
Operator Comments
Sample description, particle sizt
reductJon, etc.•
- -----··---···
-·--· ----
--------· ..
------..
... , ----··-·---·
.! -·-···------------!
----. -. .. ----
!
·----------
i
C Comoonents Reference Number Fluid pH Check pH (Ranf!e) •• lf initial sample pH is <5.0 use Extraction Fluid#/.
0 --= 'a Glacial Acetic Acid Coto<Jo07·A Extraction Fluid # l '("J:5 (4.93 ± 0.05) .. ·-.. " .. -Sodium Hydroxide C: ""-" $ 01 'l Extraction Fluid #2 (2.88 ± 0.05) -to. ..
<al
Pre~:ttraCI -.,0/11~ U w,/umt of liquid nmowdfrom sample prior to extracflon. Volume of Extracl/on Fluid added should equal 20 times sample weight.
Sample1jllte~d-w1th IN HN03-rlnstd, g!m3flMr filters.
ate Time
Chain of Custody ate Time
if initial sample pH is >5.0 odd 3.5ml of IN HCl, heat sample to
50" Con water hath for /0 min., cool and measure pH; if pH is <5.0
use Extrar;tion Fluid#/, if pH is >5.0 use Extraction Fluid #2.
Davis & Floyd, Inc.
EX03_03 (02/03)
--------- --------- -
-----DAYIS:
FLlJ'YD b1bw-U,l.ll>nl71!nm
Analyst(s):..,1-\C.@.'-""!'"------,------
---
Date: 2-2. i.-o;:3
Method :.__,1_:c3c...lc...l'-----Test Code: r;,e/TrJJ,/e'J.T
Sample Matrix Code (:, O Metals Only □ Filter Only
Batch Root: O :Z.. l. "'£'x T t-1,!3 WG: 'I""/ Q-.. R: i:;q,_5,J
LIMSNUMBER Sample fimnple Pre-extract Initial pH after
! L Q.2._ Due Weight Volume pH•• INHCI
Date '=' ·":.11:1rnn.
01 1-.2,.2.1/.0-\,•.o.1. •'l•O> ,o~; I '3 "I 1'-~--~'"' --·--
o"t. ~ .-.1).Z.. .l.
. -. ·-10:0.0 ,-1/A _{,_J. __ :Z,,L_ __
• -. . .
u •<I..•-· ........ •I•£.• ,, ·-.... ,. .., , --
. c,'\ ---~--,.'\, {, • I I , ... q \0.0 -~~o -. .. s .•. I .L. -·--"· 8'l-\ .... 'I ,., . """ .•. I. Q. 10.0 -~ -"'o '. - -out .•. 2. O.· 10.0 --i:-:r, ,.~ ----o& .•. ,_. 2.· 10.0 'f-.O '-l.i8
O'i . -~"-10.0 5. 2.S"" 1, '\O ---
• V ... ·"'. .v ~.n~ '.
-
Extraction
Fluid
ID
I -.. I
I ----
. • ! -
I i !
I !
'
-1
I
I ,---
I
" Comoonents Reference Number Fluid pH Check
-----
Extraction Vessel: l8l Bottle D ZHE
Rotary Extractor Unit #: I 4-z.
Rotation Rate (RPM): 3/ -i--3 z..
Ambient Temperature: :z. 'i 'C
Vessel ZHE Pressure Final Final
Number Check (osi) pH Volume
on off (ml)
i \.A I --S".Ol-?-2.o~ s----!
U\ "l. :4.} :z.oco ... -I
Matrix
Group
I
2
·--1.l•'<~ I _,,_ 1· -3
-----
Extraction Bench Sheet (TCLP)
I
I
' :
I
Time: On 15:'I, Analyst Mefa'
OffoB:.w Analyst"'~
Extraction rime required is 18 ± 2 hours.
Ambient Temperature Range: 23 ± 2° C.
Operator Comments
Sample description. parlicle siu
reduction, etc.
--· ·--·-----· ··-----
Z·Zf·Ol""""-. ------·--.
---------------------
1 .. ".,_ I_"\ ::Z.oo
I !·~~3 -:-_ [_ ____ ·-----~ ' l".<I.~ It.. -i -------zs~i~ ·~ -~ ➔ .'1-Z.. I ~~-3 --· ~-'_5p cC -
;to --'\ .<\ \ "J..L)O • 3
-.. -i -··-·------------
~ r-::::--1-j.'IS-;lJ)O ! 3 -. ----·----------· -_, ~-c · 3 L'\ --"'.'t2:-I---· ·--------~ : . ·-. --__ ,,_ ... ----------
--i . .. ! oJ I
pH (Ranee) • • If initial sample pH is <5.0 use Extraction Fluid #I. .. -= .,, Glacial Acetic Acid f!QI0'"\001,:-8 u ·-Extraction Fluid # 1 'I. 9'( (4.93 ± 0.05) ff initial sample pH is> 5.0 add 3.5ml of IN HCI, heat sample to
f = Sodium Hydroxide E:OJ.I \ ooS Extraction Fluid #2 (2.88 ± 0.05) -Ii: -" l&l ,·
Pn~ct volume tr vol~ ofliqutd removedfrom sample prior to extraction. Volume of Extraction Fluid added should equal 20 times sample weight.
Sample1filtendwlth IN HN03-rlrued, glanfiber filters.
~h•day uate Time
Z.-2.f-03 ,;:oo
Chain of Custody lf.ecetved ay Date Time
~Pl, z . .,7,in '~ :oO
50° Con waler bath for JO min., cool and measure pH: if pH is <5.0
use Extraction Fl111d #/. if pH is >5.0 use Extraction Fluid #2.
Davis & Floyd. Inc.
EX03 _ 03 (02/03)
DAYIS: ·.
FLtfYD 11mmma1,i.mm,~
Analyst(s):._>1'=C....,R-'--------
Test Code: o PI rc.1.-P[ 6 ><r Method:._,_,..,3,.,1--'1 ____ _
Sample Matrix Code-',__ □ Metals Only □ Filter Only
Batch Root: ()'.l.. ':l-b X °I WG: 3:'. IP, R: r.Qe,5<J
LIMSNUMBER Sample Sample Prc~xtract Initial pH after
X ~ L0"3 Due Weight Volume pH•• INHCI
"' Date (-' . ...,,_/ml\
. '. . . . -•· ·. . . . ................ .,,, ,L,n, 3• -U•U .. ., ·-
.. .slk I 1. . · .3.0. 0 . .:tc..o_ . . .. . .
-
Extraction
Fluid
ID
' .
I
1------
I
Extraction Vessel: ~ Bottle □ ZHE
Rotary Extractor Unit#: I .-2.
Rotation Rate (RPM): '3 I + '3 2
Ambient Temperature: ::J.', oc
Vessel ZHE Pressure Final Final · Matrix
Number Cheek (psi) pH Volume Group
on off (ml)
I -;
L I 'f,
I 30 -..,_ 'ii I :i.oo :! ... . . -'.l.00 3
Extraction Bench Sheet (TCLP)
Time: On /~¥>Analyst 1-AC/11:
0ffD9:~ Analyst 14-
Extraction time required is 18 ± 2 hours.
Ambient Temperature Range: 23 ± 2°C.
Operator Comments
Sample ducriplion, particle size
reduction. etc.
6Dr1 3/zs/cB ____
1"3 . ·. 3.1. 10.0 ' "3 2-1·-=-·· • ~-~-~] . ··--. . .. ·--··---· --~---·---·
' I J "'0 i 3 ' I "i . -\o.O '"'. 5" 'I 3'f I ;J..00 i
. \ I I I I ... I
•J • • • J. U, ,..., ..... I ~ • .ao l,--....--TT . :' .. I..!. -I rl , I \ ' ' I L-I __ -1~0~~ ---------------
a lJ, E . ><· r. . a..1. ... 1\.)1.\l .~ -;l..O 00 >i.'t"i -\ I i.8 •C!'i I -,, . ..• .. __ .] ! .. ------·-·· .
I I I -_ -~l~ _z./if/o'3 .... ----. . -· . ' . ,J,D, I ._,..., .,. . • . _.J_'9 -~•II '-' ... -· ' . : ! . ---· ---··--------•-----···---
. ------·------···------~ -· -···· ---, . --·-·· ..
.
C: Companents Reference Number Fluid pH Check pH (Ran,:e)
0 ...
-.::-a Glacial Acetic Acid eo1.:>'loo"'f--B Extraction Fluid # I ':1-9~ (4.93 ± 0.05) u ·-f " Sodium Hydroxide e':0:2.IJ<)r,< Extraction Fluid #2 -(2.88 ± 0.05) -G: " "' Pre~xtracl volume U '110/urnt of/,quid removed from sample prior to extract10n. Volume of Extracflon Fluid added should equal 20 times sample weight.
Samples fl/tend with IN HN03-rlrued, glassflber filters.
cminquished !Jy Date Time
MU-z.-2.r-o3 /!,°~OE:,
Chain of Custody Received try Date Time
(,01.. 2--2-7·63 IS: o0
i i i I
•• If initial sample pH is <5.0 use ~traclion Fluid #I.
If initial sample pH is >5.0 add 3.5ml of IN HCI, heal sample to
50° Con water bath/or JO min., cool and measure pH: if pH is <5.0
use Extraction Fluid#/, if pH is >5.0 use Extraction Fluid #2.
Davis & Floyd. Inc.
EX0J _ 03 (02/03)
---- - ---------- --- -
I DAYIS "'""' .. Lfi'1 lnil11111t
I FL YD llritma,ullLimlaJ!mict., Extraction Bench Sheet
Test Code: s v/-rc...._ f'
I
\1atrix Code:----"---Method: .J:>I oc....
.xtraction: Date:.:,..
Liquid:
Solid:
,_ 7 -o"' Time: o o, ·. 0 o Analyst(s): ~c, M.C..~, .>-\G.<',
~ Separatory Funnel D Continuous Liquid-Liquid D Waste Dilution
□ Sonicator Level : □ Low □ Medium
Concentration : I Clean-up:
Analyst:
Analyst: ----
oe,e-11:1 K-D IBI N-EV AP □ RAP!DV AP
Date: ____ _
I
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Vialed· Analyst·
Batch Root: c. .:,._. ).c -. 'I-:s Page or we;: 33/95 R: te <u,r,, '-f
;: UMS \umber Sample Ck;:in Final
-Clic111 Sample Sample Amount Lp [:,.,:1rnct -'-0 Code ID Due Date O~rnl[!S'111I pH Code Vol. (pl) Corrnrn::nt;;
/.
0 I \.·\ NIA MBL\NK j\1/;\ ,oo s -,coo
C, :i. \.\ 'L\ LCS l"ii\ ;;; -race /CC °'" • ") 1.~•'1· 3-0:, o· :,_.-:,__ . <j 0 I -o I me.-s ""' Sbt2,. 5£..'->--t:l<cl.: 3-'l . .,, l /00 s -100D
bY -o.{ _L~s I QC, s -/~C(?_I,
o5 -o.l _____ ?l">b_. '-~~-;i IO~'? .. .. . -· .. ····---
C, (o • D :l, .. f.~_s_~""'-~ eoe ,; '
-- -
I 0. 9. ... ----·---··---jOC0 __
c7 -O:• ... ---1--::~ t,€1.~--.:i.. --~0.9.9 __ ---· ·····-.. .. --·--
c~ -c '.l .__ I c, c:, :, -/ oc::,O _.__
-
--
-. ·---------·------·-·-..
---. ------------... ··----·-· . .... -----· ---------.. --· --·· ---------~ -----·-· -·--····-----. ·-· - -··-·
--
---·--... ... ... --.. ·----··-·--
-
Comoound I Mix Name Reference Number ml added/Analyst Clean-uv Codes Matrix Codes
I. Dichloromethane t €0~<?;:i.c-l ', :::S-NA -Solvent A -S11ff11ric Acid I -Dri11k 1120 ,,. r· ·--··· ----··
2. Hexane ., -NA -Solvent C -Cnrboprep 2 -WWISTW/SFW ------. ·------.. . -------
3. Acetone -NA -Solvent F -Florisii 5 -GW/ChemW
. --··-· --. ···--------
4. Ethyl Ether NA-Solvent G -Gel Pen11enrio11 6 -lenchnle , ----·· --·-· ··----·-· ---
5. Surrogate Spike _c:_o_3_c,").__O t~ 1,0_. K -Po1nssi11111 7 -Soi//SUSW
.. ------. -------. -··-. -· -
6. Matrix Spike ~0'/,..../00 '· 'I .,, $ Permq1Jgn11n1e 8 -Sludge • liq
-....
7. . Florisil (Lot#: ) -NIA S -S111/111 9-Oil
8. Other ( ' --11 -Air
I
R'ifinquished By Dntc 71me
Chain of Custody
---;)P.,.c_ .J -:r-i-o3, I<.: ~c, "J?ec~a~ ;Ji.,,.., lime
)1,:30
Jowl. Inc. D,11,, & F •
£X02 _ 01 ( J0!00J
65
I
lnlitlllrt I D~IS ll(■

M
i
a
t

.
FL YD rm-l Him111Jltni"' Extraction Bench Sheet
'1atrix Code: __L_
... xtraction:
Concentration :
Clean-up:
Vialed·
Method: J'S LO<::. Test Code: es /TC-,_ p le l; SJ
Date: ,3.c,3.7.0:!, Time: 1Y.3b Analyst(s): J)e,c,..uc.e., MS<,e,
Liquid: @ Separatory Funnel D Continuous Liquid-Liquid D Waste Dilution
Solid: D Sonicator Level : D Low D Medium
Analyst:lib ~v: .. J1-@ K-D ll5I N-EV AP D RAP[OV AP
Analyst:~~ Date: 1.-w -oJ
'\nalvst· l-1-cJ'. ,
Batch Root: . ;l..' ;, _ _. 7 . -,. (' Page ~ or I 11· (i: ~~L'H'' R: ~g_G,,I>_~
IS
,: LIMS r--.'umber Sample Clean Final
-Client Sample Sampk Amount Up Extract
·,o L 2.3. Code ID Due Date o~ .. , l;iml pH Code Vol. (pl) Comments
ol NA NI/\ MBLANK NIA IC. 0 ':i 17 /t>l.:>OC
o;l. N,\ Ni,\ LCS NIA ,oo > ,, /ecoO
e !, o·,-·---·-\ 0 I D/ TJ C.•Sltl'. St!>«.su,o~! '2, • ' • c3 JOO :,· ,~ /ObOO
' 0~ . /) -1 l ~s 1oq. $_ ,: .~~~~-~-
os . o I . 1,0 __ ,; F . / D.4?~ (?_ . . »,Si) . ·-·. --······ -.
C,(p . Oa< . -.f e sc ... c&t,_. .,.o.9_ ---_ ;,:.__ .. .!.' .•. _L_t;,110 ~
.. -·--.. -. ---·
01 • 0 .J. . . i:: ·' ~-_() .. . ::i_ . ___ ,:_ __ /o ocO ----..
of ~ . 0;,. --JCO s r /oOOO ..
.
'
. ... --.. . ..
.
··-. . ---·-·. ... ... -----.. "••---··-· .. . ·----· ------· ----·-·---· ·-··•.
.
--·-··-·· -····-···-.. ... --· -·--...... .. , .. .... . ·-··---......... ··---·-------·-·· -----.. ··-~-· ·--··---...
. ... ··-· .. --. .
. ..... . .. ----·· .. --· ....
.
Compound I Mix Name Reference Number ml added/ Analvst Clean-ua Codes Matrix Codes
.
I. Dichloromethane I i;C> !,o_l.o <j '1 · I( NA -Solvent A -Sulfuric Acid I. Drink 1120 ,, ,. ·----·-··· . .
2. Hexane ' _ti..<?~{Q~. l ~ : ... !:> NA -Solvent C -Carboprep 2 -WW!STWISVH'
··--.. -·--
3. Acetone .. NA -Solvent F -F/orisil 5 -GW!Che111W
---·--·-·· .... ·--·· . ·------·-·-·
4. Ethyl Ether -NA-Solvent G -Gel Permeation 6. Leachnle
• ----··---·---. ······ ···-----· . ··-
5. Surrogate Spike . li:0.30.:!...0. 3 '1 .. 1,0 _ _ T>t,e_ .. K -Potassium 7 . Soil!SUSW
·-·-
6. Matrix Spike t:o3o/ <>.1.<I /.0 i)tSc,. Per111angana1e 8 -Sludge -Liq
7. . Florisil (Lot#:~ :,'i .:i> 1 ) c.r~.1-\~bll ·t.: NIA S-S11/fiir 9 -Oil
8. Other ( ) .6b2. tu.c_ L•:a.."")0 ,:>'),
J 2. Air
Re/i11quished By Date Time
Chain of Custody
/IA.C.~ 2-~-,JJ I I :oo
uate lime
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I ~e:~ D2· 26 o", II: OD /lie. Dml\ & Flow/, 1 EXO]_O((I0/0//
66 I
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ltlill"11tt D~IS 111""'"
1
FL YD in;n.,-iHimlllJ!mir,i
•·,1atrix Code: ~
.xtraction:
Method: ,3s1oc...
Extraction Bench Sheet
Test Code: es /Tc,J..PI tfef'-1>
Date: ..2.-;q, .o;, Time: <>$' ~ o o Analyst(s): Dt3C...,._,_. ,,M,.,,;dZ---==-----
Liquid: l!3 Separatory Funnel D Continuous Liquid-Liquid D Waste Dilution
Concentration :
Clean-up:
Vialed·
Batch Root: 0 .;l_.;l_,
X UMS "cumber
Solid: D Sonicator Level : D Low D Medium
Analyst: -oa,C..
Analyst: _'Q~t:£-~
Analyst· OA.C..-
g ·'i-.f-(
G;l K-D ~ N-EV AP O RAPIDV AP
Date: .3 .2, .o .3
Page or
Sample Clean final
Amount E:-.:tract
\VG: ..33,;i._i.2 R ~7:,5
~ Ls0 Client Sample Sample Up
Code ID Dur Date O~n, · ~lint pll Code Vol. !pl) Comments :r.
0 I ".\ N/A rv!BLANK NIA • O 0 s I· /000(
c;l. \.-\ Ni\ LCS Nii\ /00 s F 10000
o3 0 . .,_. ?-.·'-l 0 I 0 I Ti c..-S He. S61<. .SL.'-'."'-C 3 -~ ·" 3 I <> 0 > " /0000
0 'l -/;)_/ lMS /_C_~ ,,-f 100 ot;>
05. e. l I~-~ >_ ___ t= . -/'.' 0, 0 ~--'? .. .. __ n:,SJ:>_ ' -...
-<> \o. --c:::._ ~ -__ f f :SI.MDC. l:,_ -·--· ____ /tic __ -~-r ..L_Q_e_~Q. ---...
.cl. -. ;i. -1:: . I~--_:,:-__ -r _.(.eic_oo _
08 ·o :l... -'---/ {) 0 s ,= /oOOO
-
------.. ---
-------·------·--··-··--.. ·---·---···-·· -··---· --·----·------... ---···--·
---·--· ·---·. ··-· --. ----------·· -··-----·-----· -·-·-···-·-·-----··-------------·····--·-----·--------·-------
---... --··--· ---. .. ,-··-·· ..
-.. --I ·-· ·--·-··-' ··-· -------
-
Comnound I Mix Name C Reference Number ml added/Analvst C/ea11-11n Codes
I. Dichloromethane l -NA -Solvent A -S11lf11ric Acid
2. Hexane j:;_? ;J.. I <>_ C I;> '. I:, NA -Solvent C -Carboprep
----·· ·---
3. Acetone -NA-Solvent F -Florisil
·-·----··----·····---··
4. Ethyl Ether , .§:c:,_~ j_l_o_ l :J._-~-NA -Solvent G -Gel Per111eario11 -----·-·---
5. Surrogate Spike £9!>Q_/Q J_I.,, ___ le o_ __ Ac,lt.. K -Potnssium
6. Matrix Spike 6.o-~o I Ql1 O.· 'S ... t<-.c:.IL _ Permanganate ---
1: Florisil (Lot #: -;. ?.1~S I ) c=o '2 t'l ... ta, It -G NIA S-S11lf111·
8. Other I ) --
ReJinquishe(I By Date Time
Chain of Custody Q,2 L ~.3.0, I <l.' /b
1«ecen-eifH,· vale 1 J11ne
~~ '5-<,3 .. '\ l'-l: 10
67
--
Matrix Codes
I -Drink f/]0
l -Wlf'ISTll'.1SF /J"
5 -GWJCh('mW
6 -leaclwte
7 -Soil/SUS IV
8 -Sludge -liq
9-Oil
I 2 -Air
, I C. Dawj & Flo) d, I 1
EX02_0/(/U!UUJ
Df\YIS
FLOYD
March 17, 2003
PEM CARTER
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198 .
SHELBY, NC 28152
:L03022403
:61621.01
LABORATORY ANALYSIS REPORT
Login Number
Project Number
Description :GROUNDWATER ANALYSIS
Dear Pem Carter:
We are pleased to provide the enclosed analytical results for the samples received by
Davis & Floyd, Inc. on February 21, 2003.
A formal Quality Assurance/Quality Control program is maintained by Davis & Floyd,
which is designed to meet or exceed the EPA, NELAC or_ other appropriate regulatory
requirements. All analytical analyses for this project met QA/QC criteria and the
results are within the 99 % confidence interval for each method unless otherwise
stated in the footnotes. This report is to be reproduced only in full.
_ Feel free to contact our Client Services Representative at [phone] if further
· explanation of the analysis is required. Unless other arrangements have been made,
samples will be disposed of or returned 14 days from the date of the report. We
appreciate the opportunity to provide services to your firm.
Sincerely, .
DAVIS&F~C
H. McCord, Jr.
boratory Manager
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Dav;s & Floyd, Inc. I PO o,awe, 428 I G,eenwood, SC 29648 I 816 e·s""' Avenue I G,eenwood, SC 29649 I 1864) 229-4413 I Fax [phone]
I
I D~S FL D LABORATORY ANALYSIS REPORT
I NELAC Cenification Number: £87633 NC Certification Number: 25
\
I Client TICONA, LLC Project Number: 61621 01
2525 BLACKSBURG ROAD
I HWY 198
SHELBY, NC 28152 Report Date Ma::-ch 1 7, 2003
Contact PEM CARTER r'age 1 of 1 Report 10: AB4760
I Client ID: CC-33 Sample ID L03022403-01
Date Collected: 20-F'EB-0J 15 : 4 0
Matrix GW/ChemW Date Received 21-FEB-03
I Parameter Result Qual RDL Units Analyst Date Time
Volatile Organics
I SW846 8260B
1, 1,1-TRICHLOROETHANE ' o. 0010 0 .0010 mg/1 PAP 02/24/03 1609
1,1,2,2-TETRACHLOROETHANE o. 0010 0 .0010 mg/1 PAP 02/24/03 1609
1,1,2-TRICHLOROETHANE ' 0. 0010 o. 0010 mg/1 PAP 02/24/03 1609
I 1, 1-DICHLOROETIWJ"E ' 0 .0010 0. 0010 mg/1 PAP 02/24/03 1609
1, 1-DICHLOROETHENE ' o. 0010 0 .0010 mg/1 PAP 02/24/03 1609
1,2-DICHLOROETHANE 0, 0010 0 .0010 mg/1 PAP 02/24/03 1609
I 1,2-DICHLOROPROPANE 0 .0010 o. 0010 mg/1 PAP 02/24/03 1609
2-BUTANONE ' 0 .0050 0' 0050 mg/1 PAP 02/24/03 1609
2-HEXANONE ' 0 . 0050 0 . 0050 mg/1 PAP 02/24/03 1609
4-METHYL-2-PENTANONE < o. 0050 0 .0050 mg/] PAP 02/24/03 1609
I ACETONE 0.0050 o. 0050 mg/1 PAP 02/24/03 1609
BENZENE 0.0016 0. 0010 mg/1 PAP 02/24/03 1609
BROMODICHLOROMETHANE ' 0 . 0010 0 .0010 mg/1 PAP 02/24/03 1609
BROMOFORM ' 0 . 0010 0 .0010 mg/1 PAP 02/24/03 1609
I BROMOMETHANE ' 0 . 0010 0 . 0010 mg/1 PAP 02/24/03 1609
CARBON DISULFIDE 0.0015 0 .0010 mg/1 PAP 02/24/03 1609
CARBON TETRACHLORIDE ' 0.0010 0 .0010 mg/1 PAP 02/24/03 1609
I CHLOROBENZENE ' 0.0010 0 .0010 mg/1 PAP 02/24/03 1609
CHLOROETHANE ' 0 .0010 0 .0010 mg/1 PAP 02/24/03 1609
CHLOROFORM < 0. 0010 0 . 0010 mg/1 PAP 02/24/03 1609
CHLOROMETHANE ' 0 .0010 o. 0010 mg/1 PAP 02/24/03 1609
I CIS-1,2-DICHLOROETHENE 0.0028 0 .0010 mg/1 PAP 02/24/03 1609
,' CIS-1,3-DICHLOROPROPENE ,' ' 0 .0010 0 .0010 mg/1 PAP 02/24/03 1609
!
DlBROMOCHLOROMETHANE ' 0. 0010 0 .0010 mg/1 PAP 02/24/03 1609
ETHYLBENZENE ' 0, 0010 0.0010 mg/1 PAP 02/24/03 1609
I METHYLENE CHLORIDE 0.0010 0 .0010 mg/1 PAP 02/24/03 1609
STYRENE ' 0' 0010 0 .0010 mg/1 PAP 02/24/03 1609
TETRACHLOROETHENE ' 0 .0010 0 .0010 mg/1 PAP 02/24/03 1609
I TOLUENE ' 0. 0010 0 . 0010 mg/1 PAP 02/24/03 1609
TRANS-1,2-DICHLOROETHENE ' 0 . 0010 0 . 0010 mg/1 PAP 02/24/03 1609
TRANS-1,3-DICHLOROPROPENE ' 0 .0010 0. 0010 mg/1 PAP 02/24/03 1609
TRICHLOROETHENE 0.0040 0 . 0010 mg/1 PAP 02/24/03 1609
I VINYL ACETATE ' 0. 0010 0 . 0010 mg/1 PAP 02/24/03 1609
VINYL CHLORIDE ' 0.0010 0 . 0010 mg/1 PAP 02/24/03 1609
XYLENE (TOTAL) ' 0.0020 0, 0020 mg/1 PAP 02/24/0J 1609
I
I Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 l 816 E. Our!>! Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
69
DAYIS
FLOYD LABORATORY ANALYSIS REPORT
NELAC Cenijication Number: £87633
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
PEM CARTER
Client ID.: FF-62
Matrix
Parameter
Volatile Organics
SW846 8260B
1,1,1-TRICHLOROETHANE
1,1,2,2-TETRACHLOROETHANE
1,1,2-TRICHLOROETHANE
1,1-DICHLOROETHANE
1, 1 -DICHLOROETHENE
1,2-DICHWROETHANE
1, 2-DICHLOROPR':J,J?.!;NE
2-BlITANONE
2-HEXANONE
4 -METHYL-2-PENTANONE
ACETONE
BENZENE
BROMODICHLOROMETHANE
BROMOFORM
BROMOMETHANE
CARBON DISULFIDE
CARBO~ TETRACHLORIDE
CHLOROBENZENE
CHLOROETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-OICHLOROETHENE
CIS-1,3-DICHLOROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METifYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
~S-1,2-DICHLOROETHENE
TRANS-1,3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL)
GW/ChemW
' 1
'
'
'
'
'
'
'
'
'
'
Result
0 . 0010
0 . 0010
0 . 0010
0. 0010
0 . 0010
0 .0010
0 .0010
0 .0050
o. 0050
0 .0050
o.ooso
o. 0010
0. 0010
0 .0010
0 .0010
0.0010
0 .0010
0. 0010
0 .0010
0. 0010
0. 0010
0. 0010
0 .0010
0 .0010
0.0010
0.0010
0.0010
0.0010
o. 0010
0. 0010
o. 0010
0 . 0010
0. 0010
0 . 0010
0 . 0020
NC Cenification Number: 25
Project Number; 61621.01
Report Date March 1 7, 200)
Page 1 of 1 Report ID: J\B4759
Sample ID L03022403-02
Date Collected: 21-F'EB-03 09: 38
Date Received 21-FEB-03
Qual RDL Units Analyst Date Time
0. 0010 mg/1 PAP 02/24/0) 1631
o. 0010 mg/1 PAP 02/24/03 1631
0. 0010 mg/1 PAP 02/24/03 1631
0 .0010 mg/1 PAP 02/24/03 1631
0 . 0010 mg/1 PAP 02/24/0) 1631
0 .0010 mg/1 PAP 02/24/03 1631
0.0010 mg/1 PAP 02/24/03 1631
0 .0050 mg/1 PAP 02/24/03 1631
0 . 0050 mg/1 PAP 02/24/03 1631
0 .0050 mg/1 PAP 02/24/0) 1631
0. 0050 mg/1 PAP 02/24/03 1631
0 .0010 mg/1 PAP 02/24/03 1631
0 .0010 mg/1 PAP 02/24/03 1631
0. 0010 mg/1 PAP 02/24/03 1631
0 . 0010 mg/1 PAP 02/24/03 1631
0 .0010 mg/1 PAP 02/24/03 1631
0 .0010 mg/1 PAP 02/24/0] 1631
0 .0010 mg/! PAP 02/24/03 1631
0 .0010 mg/I PAP 02/24/03 1631
o. 0010 mg/1 PAP 02/24/03 1631
0 .0010 mg/1 PAP 02/24/03 1631
0 . 0010 mg/1 PAP 02/24/03 1631
0. 0010 mg/1 PAP 02/24/03 1631
0.0010 mg/1 PAP 02/24/03 1631
o. 0_010 mg/1 PAP 02/24/03 1631
0. 0010 mg/1 PAP 02/24/03 1631
0. 0010 mg/1 PAP 02/24/03 1631
0 .0010 mg/1 PAP 02/24/03 1631
0 . 0010 mg/! PAP 02/24/03 1631
0 . 0010 mg/1 PAP 02/24/03 1631
0 .0010 mg/! PAP 02/24/0] 1631
0 . 0010 mg/1 PAP 02/24/03 1631
0 .'0010 mg/1 PAP 02/24/03 1631
0 . 0010 mg/1 PAP 02/24/03 1631
o . 0020 mg/1 PAP 02/24/03 1631
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Dav;s&floyd,lnc. I P0Drawer428 I Greenwood,SC29648 I Bl&~~urslAvenuc I Greenwood, SC2%49 I [phone] I fax[phone]
I
I D~S I,ABORATORY ANALYSIS REPORT FL D I NEI..AC Certification Number: £87633 NC Certification Number: 25
I Client TICONA,LLC Project Number: 61621.01
2525 BLACKSBURG ROAD
I HWY l 98
SHELBY, NC 28152 Report Date March 17, 2003
Contact PEM CARTER Page 1 of 1 Report IO: AB4 7 61
I Client ID, FF-34 Sample ID L03022403-03
Date Collected, 21-F'EB-03 10: 42
Matrix GW/ChemW Date Received 21-FEB-03
I Parameter Result Qual RDL Units Analyst Date Time
Volatile Organics
I SW846 8260B
1,1,1-TRICHLOROETHANE < 0. 0010 o. 0010 mg/1 PAP 02/24/03 1654
1, 1, 2, 2-TETRACl!LOROETHANE 0 .0010 o. 0010 mg/1 PAP 02/24/03 1654
1,1,2-TRICHLOROETHANE < 0. 0010 0 .0010 "!l i 1 PAP 02/24/03 1654
I 1, 1-DICHLOROETHANE < 0 .0010 0 .0010 mg/1 PAP 02/24/03 1654
1,1-DICHLOROETllENE < o. 0010 o. 0010 "!Jil PAP 02/24/03 1654
1,2-DICHLOROETH.ANE < 0. 0010 0 .0010 mg/1 PAP 02/24/03 1654
I 1,2-DICHLOROPROPANE < 0. 0010 0 .0010 mg/1 PAP 02/24/03 1654
2-BUTANONE 0 . 0050 0 . 0050 mgil PAP 02/24/03 1654
2-HEXANONE < 0 .0050 0 .0050 mg/1 PAP 02/24/03 1654
4-METHYL-2-PENTANONE < 0. 0050 0 . 0050 mg/1 PAP 02/24/03 1654
I ACETONE ' 0. 0050 o. 0050 mgil PAP 02/24/03 1654
BENZENE < 0 . 0010 o . 0010 "!Ji 1 PAP 02/24/03 1654
BROMOOICHLOROMETHANE < 0. 0010 0. 0010 "!Jil PAP 02/24/03 1654
BROMOFORM < 0 . 0010 o . 0010 "!Jil PAP 02/24/03 1654
I BROMOMETHANE 0 .0010 0 .0010 mg/1 PAP 02/24/03 1654
CARBON; DISULFIDE 0.0080 0. 0010 "!Jil PAP 02/24/03 165'1
CARBON TETRACHLORIDE < 0.0010 0.0010 "!Jil PAP 02/24/03 1654
I CHLOROBENZENE < 0.0010 0 . 0010 mg/1 PAP 02/24/03 1654
CHLOROETHANE < 0. 0010 0. 0010 mg/1 PAP 02/24/03 1654
CHLOROFORM < 0. 0010 0 . 0010 "!Jil PAP 02/24/03 1654
CHLO ROM ETHANE < 0. 0010 0.0010 "!Ji 1 PAP 02/24/03 1654
I CIS-1,2-0ICHLOROETHENE ,• < 0 .0010 0 .0010 mg/1 PAP 02/24/03 1654
i.'·
CIS-1,3-0ICHLOROPROPENE "="· < 0. 0010 0 .0010 "!Jil PAP 02/24/03 1654
DIBROMOCHLOROMETHANE < 0. 0010 0. 0010 "!Jil PAP 02/24/03 1654
ETHYLBENZENE < 0 . 0010 0 .0010 "!Ji 1 PAP 02/24/03 1654
I METHYLENE CHLORIDE < 0 . 0010 0 . 0010 mg/1 PAP 02/24/03 1654
STYRENE < 0. 0010 0 . 0010 "!lil PAP 02/24/03 1654
TETRACHLOROETHENE < 0. 0010 0 .0010 "!lil PAP 02/24/03 1654
I TOLUENE < 0 . 0010 0 . 0010 "!Ji 1 PAP 02/24/03 1654
TRANS-1,2-0ICHLOROETHENE < 0. 0010 o. 0010 "!Ji 1 PAP 02/24/03 1654
TRANS-1,3-DICHLOROPROPENE < 0. 0010 0.0010 mgil PAP 02/24/03 1654
TRICHLOROETHENE < 0 .0010 0.0010 mgil PAP 02/24/03 165'1
I VINYL ACETATE < 0. 0010 0.0010 ""/1 PAP 02/24/03 1654
VINYL CHLORIDE < 0. 0010 0.0010 mgil PAP 02/24/03 1654
XYLENE (TOTAL) < 0 . 0020 0.0020 "!Ji 1 PAP 02/24/03 1654
I
I Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax (8&4) 229-7119
71
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D~S I
FL D LABORATORY ANALYSIS REPORT
I
NELAC Certification Number: £87633 NC Certification Number: 25
Client TICONA,LLC Project Number: 61621.01 I
2525 BLACKSBURG ROA:)
HWY 198
SHELBY, NC 28152 Report Date March l 7, 2003 I Contact PEM CARTER Page l of l Report. ID: A84762
Client IO; T-35 Sample ID L0]022403-04 I Date Collected, 21-FEB-03 12 : 35
Matrix Gw°/ChemW Date Received 21-FEB-03
Parameter Result Qual RDL Units Analyst Date Time I
Volatile Organics
SW846 8260B
1,1,1-TRICHLOROETHANE o. 0010 o. 0010 mg/1 PAP 02/24/03 1717 I
1, 1,2,2-TETRACHLOROETHANE 0 .0010 o. 0010 mg/1 PAP 02/24/03 1717
1,1,2-TRICHLOROETHANE < o. 0010 o. 0010 mg/1 PAP 02/24/03 1717
1,1-DICHLOROETHANE < o. 0010 0 .0010 mg/1 PAP 02/24/03 1717 I 1, 1-DICHLOROETHENE < o. 0010 o. 0010 mg/1 PAP 02/24/03 1717
1,2-DICHLOROETHANE < 0 .0010 0 .0010 mg/1 PAP 02/24/03 1717
1, 2-DICHLOROPROP/\NE o. 0010 o. 0010 mg/1 PAP 02/24/03 1717
2-BUTANONE < 0 . 0050 0 .0050 mg/1 PAP 02/24/03 1717 I 2-HEXANONE < 0 . 0050 0 .0050 mg/1 PAP 02/24/03 1717
4-METHYL-2-PENTANONE < 0 .0050 0. 0050 mg/1 PAP 02/24/03 1717
ACETONE 0.0055 0 .0050 mg/1 PAP 02/24/03 1717
BENZENE 0.0017 0.0010 mg/1 PAP 02/24/03 1717 I
BROMODICHLOROMETHANE < 0 .0010 0. 0010 mg/1 PAP 02/24/03 1717
BROMOFORM < 0 . 0010 0. 0010 mg/1 PAP 02/24/03 1717
BROMOMETHANE < o. 0010 o. 0010 mg/1 PAP 02/24/03 1717 I CARBON.DISULFIDE < 0 .0010 o. 0010 mg/1 PAP 02/24/03 1717
CARBON TETRACHLORIDE < o. 0010 0 .0010 mg/1 PAP 02/24/03 1717
CHLOROBENZENE o.oo.u 0 .0010 mg/1 PAP 02/24/03 1717
CHLO RO ETHANE < 0.0010 0.0010 mg/1 PAP 02/24/03 1717 I CHLOROFORM < 0.0010 0 .0010 mg/1 PAP 02/24/03 1717
CHLOROMETHANE 0.0013 0 .0010 mg/1 PAP 02/24/03 1717
CIS-1,2-DICHLOROETHENE ,, < 0. 0010 0, 0010 mg/1 PAP 02/24/03 1717
CIS-1,3-DICHLOROPROPENE
,, 0 .0010 o . 0010 mg/1 PAP 02/24/03 1717 I . f <
DIBROMOCHLOROMETHANE < 0 .0010 0 .0010 mg/1 PAP 02/24/03 1717
ETHYLBENZENE < o. 0010 0 . 0010 mg/1 PAP 02/24/03 1717
METHYLENE CHLORIDE < 0 .0010 o. 0010 mg/1 PAP 02/24/03 1717 I STYRENE < 0 .0010 o, 0010 mg/1 PAP 02/24/03 1717
TETRACHLOROETHENE 0.0011 0 .0010 mg/1 PAP 02/24/03 1717
TOLUENE < 0. 0010 o. 0010 mg/1 PAP 02/24/03 1717
TRANS-1,2-DICHLOROETHENE < 0.0010 0. 0010 mg/1 PAP 02/24/03 1717 I TRANS-1,3-DICHLOROPROPENE < 0. 0010 0.0010 mg/1 PAP 02/24/03 1717
TR I CHLOROETHENE 0.0016 0.0010 mg/1 PAP 02/24/03 1717
VINYL ACETATE < o. 0010 0.0010 mg/1 PAP 02/24/03 1717
VINYL CHLORIDE < 0 .0010 0.0010 mg/1 PAP 02/24/03 1717 I XYLENE (TOTAL) < o. 0020 0.0020 mg/1 PAP 02/24/03 1717
I
Dav;, & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816El 2urst Avenue I Greenwood, SC 2%49 I (8641 229-4413 I Fax [phone]
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Df\VIS
FLOYD LABORATORY ANALYSIS REPORT
NELAC Cenificatio11 Number: E87633
Client
Contact
TICONA,LLC
2525 ~:.ACKSBURG ROAD
HWY l~~
SEi..!::·, NC 28152
PE,~: C:.~TER
Client ID: ITEF'
Matrix
Parameter
Gas Chromatography
SWB46 8015
ETHYLENE GLYCOL
Volatil~ Organics
SW846 8260B
1,1,1-TRICHLOROETHANE
1,1,2,2-TETRACHLOROETHANE
1,1,2-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
1,2-DICHLOROETHANE
1,2-DICHLOROPROPANE
2-BUTANONE
2-HEXANONE
4-METHYL-2-PENTANONE
ACETONE
BENZEN~
BROMODICHLOROMETHANE
BROMOFORM
BROMOMETHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLORQBENZENE
CHLO RO ETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-DICHLOROETHENE
CIS-1,3-DICHLOROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-DICHLOROETHENE
TRANS-1,3-DICHLOROPROPENE
TRlCHLOROETHENE
VINYL ACETATE
VINYL OU.,ORIDE
XYLENE (TOTAL)
f
Result
5 0
o. 0010
< 0 .0010
< o. 0010
< o. 0010
< 0 .0010
< 0 .0010
< 0 .0010
< o. 0050
< 0 .0050
< 0 .0050
0. 0050
< 0 .0010
< 0 .0010
< 0 .0010
< 0 .0010
< 0. 0010
< 0 .0010
< 0 .0010
< o. 0010
< 0 . 0010
< 0. 0010
< 0 .0010
< 0 . 0010
< 0 . 0010
< 0 . 0010
< 0. 0010
< o. 0010
0 .0010
< 0 . 0010
< 0 .0010
< 0 .0010
< o. 0010
< o. 0010
< 0 .0010
< 0 . 0020
NC Cenificatio11 Number: 25
Project Number: 61621.
Report Date March :1, 2003
Page 1 of 2 Reµort : :) . r\84 764
Sample ID L03022-iJ3 -05
Date Collected: 21-FEB-JJ l 3: 10
Date Received 21-FEB-::;3
Qual RDL Units Analyst Date Time
5.0 mg/1 MGB 02/25/03 0953
o. 0010 mg/1 PAP 02/24/03 1825
0 .0010 mg/1 PAP 02/24/03 1825
0 .0010 mg/1 PAP 02/24/03 182 5
0. 0010 mg/1 PAP 02/24/03 182 S
0 .0010 mg/1 PAP 02/24/03 1825
0. 0010 mg/1 PAP 02/24/03 1825
0 .0010 mg/1 PAP 02/24/03 1825
0. 0050 mg/1 PAP 02/24/03 1825
0 .0050 mg/1 PAP 02/24/03 1825
0 .0050 mg/1 PAP 02/24/03 1825
0 .0050 mg/1 PAP 02/24/03 1825
0 .0010 mg/l PAP 02/24/03 182 5
0.0010 mg/1 PAP 02/24/03 1825
0 .0010 mg/1 PAP 02/24/03 1825
0 .0010 mg/1 PAP 02/24/03 1825
0 .0010 mg/1 PAP 02/24/03 1825
0 .0010 mg/1 PAP 02/24/03 1825
0 . 0010 mg/1 PAP 02/24/03 1825
0. 0010 mg/1 PAP 02/24/03 1825
o . 0010 mg/1 PAP 02/24/03 1825
0 . 0010 mg/1 PAP 02/24/03 1825
0.0010 mg/1 PAP 02/24/03 1825
0 . 0010 mg/1 PAP 02/24/03 1825
0 . 0010 mg/1 PAP 02/24/03 1825
0 .0010 mg/1 PAP 02/24/03 1825
0 .0010 mg/1 PAP 02/24/03 1825
o. 0010 mg/1 PAP 02/24/03 1825
o.~010 mg/1 PAP 02/24/03 1825
0 . 0010 mg/1 PAP 02/24/03 1825
0 .0010 mg/1 PAP 02/24/03 1825
o. 0010 mg/) PAP 02/24/03 1825
0 .0010 mg/1 PAP 02/24/03 1825
o. 0010 mg/1 PAP 02/24/03 1825
0 .0010 mg/1 PAP 02/24/03 1825
0 .0020 mg/1 PAP 02/24/03 1825
Davis & Floyd, Inc. I PO Drawe, 428 I G,eenwex>d, SC 29648 ! 81 b c 7□3rst Avenue ( Greenw<X>d, SC 29649 I [phone] [ Fax [phone]
DAYIS
FLtwD LABORATORY ANALYSIS REPORT
NELAC Certification Number: £87633
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
PEM CARTER
Client ID· ITEF
Parameter
Wet Chemistry
SW846 9060
ORGANIC CARBON, TOTAL
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 2 of 2
March 17, 2003
Report ID: AB4764
Sample ID L03022403-05
Result Qual RDL Units Analyst Date Time
'" 4.0 mg/1 CLB 02/27/03 1118
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Davis & Floyd, Inc. I PO 0,awe, 428 I G,eenwood, SC 29648 I 8 I 6E/,i'"' Avenue I G,eenwood, SC 29649 I 1864) 229-44 I 3 I fax [phone]
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DAYIS
FLtrYD LABORATORY ANALYSIS REPORT
NELAC Certificatioll Number: £87633
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 23152
PEM CARTER
Client ID.: ITC!
Matrix
Parameter
Gas Chromatography
SW846 8015
ETHYLENE GLYCOL
Volatile Organics
SW846 8260B
1,1,1-TRICHLOROETHANE
1,1,2,2-TETRACHLQROETHANE
1,1,2-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
1,2-DICHLOROETHANE
1,2-DICHLOROPROPANE
2-BUTANONE
2-HEXANONE
4-METHYL-2-PENTANONE
ACETONE
BENZENE
BROMODICHLOROMETHANE
BROMOFORM
BROMOMETHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROETHANE
CHLOROFORM
CHLOROMETHANE
CIS•l,2-DICHLOROETHENE
CIS-1,3-DICHLOROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-DICHLOROETiiENE
TRANS-1,3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL)
GW/ChemW
Result
1760
0 .0010
0 0010
0. 001 0
0. 0010
0 .0010
0. 0010
0. 0010
0.024
0 .0050
0. 0050
0.085
0.027
0. 0010
0. 0010
0. 0010
0.0041
0.0010
0.019
0, 0010
0 .0010
0 .0010
0.0030
0.0010
0.0010
0. 0010
0, 0010
0' 0010
0 .0010
0.0012
0.0010
0.0010
0.0011
0.0016
0.0010
0.0020
NC Certificalioll Number: 25
Project Number: 61621.01
Repoi·t Date March 17, 2003
Page l of 2 Report ID: AB476)
Sample ID L03022403-06
Date Collected: 21-FEB-03 13 : 15
Date Received 21-FEB-03
Qual RDL Units Analyst Date Time
100 mg/1 MGB 02/25/03 1018
0 .0010 mg/1 PAP 02/24/03 184 8
0. 0010 mg/ l PAP 02/24/03 1848
0 .0010 mg/1 PAP 02/24/03 184 8
0 .0010 mg/1 PAP 02/24/03 1848
o. 0010 mg/1 PAP 02/24/03 1848
0 .0010 mg/1 PAP 02/24/03 1848
0 .0010 mg/1 PAP 02/24/03 1848
o. 0050 mg/1 PAP 02/24/03 1848
0 . 0050 mg/1 PAP 02/24/03 1848
0, 0050 mg/1 PAP 02/24/03 1848
0 .0050 mg/1 PAP 02/24/03 1848
0 .0010 mg/1 PAP 02/24/03 184 8
0. 0010 mg/1 PAP 02/24/03 1848
0 .0010 mg/1 PAP 02/24/03 1848
o. 0010 mg/1 PAP 02/24/03 1848
0 .0010 mg/1 PAP 02/24/03 1848
0 .0010 mg/1 PAP 02/24/03 1848
0 . 0010 mg/1 PAP 02/24/03 1848
0.0010 mg/1 PAP 02/24/03 1848
o. 0010 mg/1 PAP 02/24/03 1848
o. 0010 mg/1 PAP 02/24/03 1848
o. 0010 mg/1 PAP 02/24/03 1848
0. 0010 mg/1 PAP 02/24/03 1848
o. 0010 mg/1 PAP 02/24/03 1848
0 . 0010 mg/1 PAP 02/24/03 1848
o. 0010 mg/1 PAP 02/24/03 1848
0 . 0010 mg/1 PAP 02/24/03 1848
0 .0010 mg/1 PAP 02/24/03 1848
o.0010 mg/1 PAP 02/24/03 1848
0 . 0010 mg/1 PAP 02/24/03 1848
0 . 0010 mg/1 PAP 02/24/03 1848
0 . 0010 mg/1 PAP 02/24/03 1848
0 . 0010 mg/1 PAP 02/24/03 1848
0 .0010 mg/1 PAP 02/24/03 1848
0 .0020 mg/1 PAP 02/24/03 1848
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
75
DL\VIS
FLOYD LABORATORY ANALYSIS REPORT
NELAC Ce11ijicatio11 Number: £87633
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
PEM CARTER
Client ID: ITCI
Parameter
Wet Chemistry
SWB46 9060
ORGANIC CARBON, TOTAL
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 2 of 2
Sample ID
Result Qual RDL
March 17, 2003
Report ID: AB4763
I,03022403-06
Units Analyst Date Time
1950 40.0 mg/1 CLB 02/26/03 2150
816 E. Durst Avenue ! Greenw(X)d, SC 29649 I [phone] I Fax [phone]
76
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I D~S FL D LABORATORY ANALYSIS REPORT
I
NELAC Cenijication Number: £87633 NC Cenification Number: 25
I Client TICONA,LLC Project Number, 61621 01
2525 BLACKSBURG ROAD
I HWY 198
SHELBY, NC 28152 Report Date March 17, 2 003
Contact PEM CARTER Page 1 of 2 Report IO: A.84765
I Client ID: ITCI DUP, Sample ID L03022403-07
Date Collected: 21-FEB-03 13: 15
Matrix GW/ChemW Date Received 21-FEB-03
I Parameter Result Qual RDL Units Analyst Date Time
Gas Chromatography
I SW846 8015
ETHYLENE GLYCOL 16 3 0 100 mg/1 MGB 02/25/03 104 4
I Volatile Organics
SW846 8260B
1, 1,1-TRICHLOROETHANE 0. 0010 0. 0010 mg(l PAP 02/24/03 1911
1,1,2,2-TETRACHLOROETHANE < 0 0010 0 .0010 mg/1 PAP 02/24/03 1911
I 1,1,2-TRICHLOROETHANE ' 0. 0010 0 . 0010 mg/ l PAP 02/24/03 1911
1,1-DICHLOROETHANE 0. 0010 o. 0010 mg/ l PAP 02/24/03 1911
1, 1-DICHLOROETHENE ' 0. 0010 0 .0010 mg/1 PAP 02/24/03 1911
1,2-DICHLOROETHANE ' 0. 0010 0 .0010 mg/1 PAP 02/24/03 1911
I 1,2-DICHLOROPROPANE 0. 0010 0 .0010 mg/1 PAP 02/24/03 1911
2-BUTANONE 0.023 0. 0050 mg/1 PAP 02/24/03 1911
2-HEXANONE ' 0 . 0050 o . 0050 mg/1 PAP 02/24/03 1911
I 4-METHYL-2-PENTANONE ' 0. 0050 0 .0050 mg/1 PAP 02/24/03 1911
ACETONE 0.076 0 .0050 mg/1 PAP 02/24/03 1911
BENZENE 0.028 0 .0010 mg/1 PAP 02/24/03 1911
BROMODICHLOROMETHANE ' 0.0010 0 .0010 mg/1 PAP 02/24/03 1911
I BROMOFORM ' 0.0010 o. 0010 mg/1 PAP 02/24/03 1911
BROMOMETHANE ' 0.0010 0 .0010 mg/ l PAP 02/24/03 1911
CARBON DISULFIDE 0. 0044 0 .0010 mg/1 PAP 02/24/03 1911
CARBON TETRACHLORIDE ' 0.0010 o. 0010 mg/1 PAP 02/24/03 1911
I CHLOROBENZENE ' 0.020 0 .0010 mg/1 PAP 02/24/03 1911
CHLOROETHANE t ' 0.0010 0 .0010 mg/1 PAP 02/24/03 1911
CHLOROFORM ' 0.0010 o. 0010 mg/1 PAP 02/24/03 1911
I CHLOROMETHANE ' 0.0010 0. 0010 mg/1 PAP 02/24/03 1911
CIS-1,2-DICHLOROETHENE 0. 002 9 0 .0010 mg/1 PAP 02/24/03 1911
CIS-1,3-DICHLOROPROPENE ' 0. 0010 o. 0010 mg/1 PAP 02/24/03 1911
DIBROMOCHLOROMETHANE ' 0. 0010 o. 0010 mg/1 PAP 02/24/03 1911
I ETHYLBENZENE ' o. 0010 0 . 0010 mg/ 1 PAP 02/24/03 1911
. METHYLENE CHLORIDE ' 0 . 0010 o. 0010 mg /1 PAP 02/24/03 1911
STYRENE < 0 .0010 0 .0010 mg/1 PAP 02/24/03 1911
TETRACHLOROETHENE ' 0. 0010 0 .0010 mg/1 PAP 02/24/03 1911
I TOLUENE 0,0013 0 .0010 mg/1 PAP 02/24/03 1911
TRANS-1,2-DICHLOROETHENE ' 0.0010 o. 0010 mg/1 PAP 02/24/03 1911
TRANS-1,3-DICHLOROPROPENE ' 0.0010 0 . 0010 mg/1 PAP 02/24/03 1911
I TRICHLOROETHENE 0,0013 0 . 0010 mg/1 PAP 02/24/03 1911
VINYL ACETATE 0.0015 0.0010 mg/1 PAP 02/24/03 1911
VINYL CHLORIDE ' 0. 0010 0 . 0010 mg/1 PAP 02/24/03 1911
XYLENE (TOTAL) ' 0.0020 0. 0020 mg/1 PAP 02/24/03 1911
I Davis & Floyd, Inc. I PO Drawer 428 I Creenwood, SC 29648 I 816 E. Durst Avenue j Greenwood. SC 29649 I (U64) 229-4413 ! Fax [phone]
77
DAYIS
FLOYD LABORATORY ANALYSIS REPORT
NELAC Certification Number: £87633
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 26152
PEM CARTER
Client ID~ ITCI OUP.
Parameter
Wet Chemistry
SW846 9060
ORGANIC CARBON, TOTAL
Result
1950
NC Certification Number: 25
Project Number, 6i621.0l
Report Date
Page 2 of 2
Ma!"Ch 17, 2003
Re~ort ID: AB4765
Sample ID L0302240)-07
Qual RDL Units Analyst Date Time
40.0 CLB 02/26/03 2223
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Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I \864) 229-441] I Fax (8h4) 229-71191
. 7 8
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Df\VIS
FLtJ\7D LABORATORY ANALYSIS REPORT
NELAC Certification Number: £87633
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SI-IELBY, NC 28152
PEM CARTER
Client ID.: EQUIP. BLANK #1
Prep Procedure Method
Analytical Prep Procedures:
OOWTHERM SW846 35008
Analyst Prep Date
NC Certijicarion Number: 25
Project Nu~ber: 61621.01
Report Date
Page 2 of 2
Sample ID
March 17, 2003
Report !O: AB4766
L03022403-08
DBC 02/26/03 0800
Davis & Floyd, Inc I PO Drawer 428 j Greenwood, SC 29648 I 816 (. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
79
I
D~S I
FL D LABORATORY ANALYSIS REPORT
I
NELAC Certification Number: £87633 NC Certification Number: 25
Client TICONA,LLC ProJect Number: 61621.01 I
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 2 8152 Report Date March 1 7, 2 003 I Contact PEM CARTER Page 1 of 2 Report ID: AB·l-166
Client ID: EQUIP. BLANK #l Sample rn L03022403-08 I Date Collected: 20-FEB-03 11 : 3 0
Matrix GW/ChemW Date Received 21-FEB-03
Para.meter Result Qual RDL Units Analyst Date Time I
Semi volatile Organics
SW846 8270C DOWTHERM
1,1'-BIPHENYL < 0 .010 0 .010 mg/1 JRN 02/27/03 114 6 I
BIPHENYL ETHER 0 .010 0 .010 mg/1 JRN 02/27/03 1146
Volatile Organics I SW846 8260B
1, 1,1-TRICHLOROETHANE 0 .0010 0 .0010 mg/1 PAP 02/24/03 154 6
1,1,2,2-TETRACHLOROETHANE 0 .0010 0. 0010 mg/1 PAP 02/24/03 1546
1, l, 2-TRICHLOROETHANE < 0, 0010 0 .0010 mg/1 PAP 02/24/03 1516 I l,l·DICHLOROETHANE < 0 . 0010 0 .0010 mg/1 PAP 02/24/03 154 6
1,l·DICHLOROETHENE < 0 .0010 0, 0010 mg/1 PAP 02/24/03 1546
l,2·DICHLOROETHANE < 0. 0010 0' 0010 mg/1 PAP 02/21/03 154 6
l,2·DICHLQROPR0PANE 0 . 0010 0 .0010 mg/1 PAP 02/24/03 1546 I
2-BUTANONE < 0 .0050 0 . 0050 mg/1 PAP 02/24/03 1546
2-HEXANONE < 0 .0050 0, 0050 mg/1 PAP 02/2'1/03 1546
4-METHYL-2-PENTANONE 0. 0050 0 .0050 mg/1 PAP 02/24/03 154 6 I ACETOf-!E < 0. 0050 0 .0050 mg/1 PAP 02/24/03 1546
BENZENE < 0 . 0010 0 . 0010 mg/1 PAP 02/24/03 1546 ·
BROMODICHLOROMETHANE 0 . 0010 0 .0010 mg/1 PAP 02/24/03 1546
BROMOFORM < 0 .0010 o. 0010 mg/1 PAP 02/24/03 1546 I BROMOMETHANE 0 .0010 0 .0010 mg/1 PAP 02/24/03 1546
CARBON DISULFIDE < 0 . 0010 0.0010 mg/1 PAP 02/24/03 1546
CARBON TETRACHLORIDE 1'.· < 0 .0010 0, 0010 mg/1 PAP 02/24/03 1546
CHLOROBENZENE
,_ < 0 .0010 0 .0010 mg/1 PAP 02/24/03 1546 I ._.F
CHLOROETHANE < 0 . 0010 0 .0010 mg/1 PAP 02/24/03 1546
CHLOROFORM < 0, 0010 o. 0010 mg/1 PAP 02/24/03 1546
CHLOROMETHANE < 0. 0010 0' 0010 mg/1 PAP 02/24/03 1546 I CIS-1,2-DICHLOROETHENE 0. 0010 0, 0010 mg/1 PAP 02/24/03 1546
CIS-1,3-DI~HI.OROPROPENE < 0, 0010 o. 0010 mg/1 PAP 02/24/03 154 6
DIBROMOCHLOROMETHANE < 0 .0010 0 .0010 mg/1 PAP 02/24/03 1546
ETIIYLBENZENE < 0. 0010 o. 0010 mg/1 PAP 02/24/03 1546 I METHYLENE CHLORIDE < 0. 0010 0, 0010 mg/1 PAP 02/24/03 1546
STYRENE < 0. 0010 0 .0010 mg/1 PAP 02/24/03 1546
TETRACHLOROETHENE 0. 0010 o. 0010 mg/1 PAP 02/24/03 1546
TOLUENE < 0 .0010 0 .0010 mg/1 PAP 02/24"/03 1546 I TRANS·l,2-DICHLOROETHENE < 0.0010 0 .0010 mg/1 PAP 02/24/03 1546
TRANS·l,3-DICHLOROPROPENE < 0. 0010 o. 0010 mg/1 PAP 02/24/03 1546
TRICHLOROETHENE < 0 .0010 o. 0010 mg/1 PAP 02/24/03 154 6 I VINYL ACETATE < 0 .0010 0 .0010 mg/1 PAP 02/24/03 1546
VINYL CHLORIDE < 0. 0010 0 . 0010 mg/1 PAP 02/24/03 1546
XYLENE (TOTAL) < 0 .0020 0.0020 mg/1 PAP 02/24/03 154 6
D,w;s & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 S ~urst Avenue I Greenwood, SC 29649 I 1864) 229-4413 I fax [phone] I
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DAYIS
FLOYD LABORATORY ANALYSIS REPORT
NELAC Ceniftcation Number: £87633
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
PEM CARTER
Clier.t I(?: EQUIP. BLANK #2
Matrix
Par&t11cter
Semivolatile Organics
SW846 8270C DOWTHERM
1, l' ·BI PHENYL
BIPHENYL ETHER
Volatile Organics
SW846 8260B
1, 1, 1-TRICHLOROETHA.NE
1, 1,2,2-TETRACHLOROETHA.NE
1,1,2-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
1,2-DICHLOROETHANE
1,2-DICHLOROPROPANE
2-BUTANONE
2-HEXANONE
4-METHYL-2-PENTANONE
ACETO~E
BENZENE
BROMODICHLOROMETHANE
BROMOFORM
BROMOMETHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-DICHLOROETHENE
CIS-1,3-DICHLOROPROPENE
DIBROMOCHLOROMETHANE
E~HYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-0ICHLOROETHENE
TRANS-1.3-0ICHLOROPROPENE
TR I Clil.,QROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL)
GW/Chemw
J .y
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
Result
0.010
0.010
o. 0010
0 . 0010
0 .0010
0 . 0010
0 .0010
0. 0010
0 . 0010
0 .0050
0. 0050
0 . 0050
0. 0050
o. 0010
0. 0010
o. 0010
0 .0010
0 .0010
o. 0010
0' 0010
o. 0010
D .0010
0 .0010
o. 0010
0. 0010
0' 0010
0. 0010
0 .0010
0.0010
0. 0010
0 . 0010
0. 0010
0. 0010
o. 0010
0 .0010
o. 0010
0 .0020
NC Ceniftcation Number: 25
Project Number: 61621.01
Report Date
Page 1 of 2
Sample 1D
Date Collected,
Date
Qual
Received
0
0
0
0
RDL
0.010
0.010
.0010
.0010
.0010
. 0010
0. 0010
0 .0010
0 .0010
0' 0050
0 . 0050
o. 0050
0 .0050
0. 0010
0 .0010
0. 0010
0 . 0010
0. 0010
o. 0010
0 .0010
o. 0010
0 . 0010
0 .0010
0. 0010
o. 0010
o. 0010
o. 0010
D . 0010
0.0010
0 :0010
0 . 0010
0 .0010
0 . 0010
0 . 0010
o. 0010
0 . 0010
0 .0020
March 17, 2 00 3.
Report ID: AB4767
L03022403-09
21-FEB-0) 12: 30
21-FEB-03
Units Analyst Date Time
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
"'3/l
"'3/l
JRN 02/27/03 1225
JRN 02/27/03 1225
PAP 02/24/03 1523
PAP 02/24/03 1523
PAP 02/24/03 1523
PAP 02/24/03 1523
PAP 02/24/03 1523
PAP 02/24/03 1523
PAP 02/24/03 1523
PAP 02/24/03 1523
PAP 02/24/03 1523
PAP 02/24/03 1523
PAP 02/24/03 1523
PAP 02/24/03 1523
PAP 02/24/03 1523
PAP 02/24/03 1523
PAP 02/24/03 1523
PAP 02/24/03 1523
PAP 02/24/03 1523
PAP 02/24/03 1523
PAP 02/24/03 1523
PAP 02/24/03 1523
PAP 02/24/03 1523
PAP 02/24/03 1523
PAP 02/24/03 1523
PAP 02/24/03 1523
PAP 02/24/03 1523
PAP 02/24/03 1523
PAP 02/24/03 1523
PAP 02/24/03 1523
PAP 02/24/03 1523
PAP 02/24/03 1523
PAP 02/24/03 1523
PAP 02/24/03 1523
PAP 02/24/03 1523
PAP 02/24/03 1523
PAP 02/24/03 1523
Davis & Floyd, Inc. \ PO Drawer 428 \ Greenwood, SC 29648 l 816 E. Durst Avenue I Greenwood, SC 29649 1 [phone] I fax [phone]
81
DAYIS
FLOYD LABORATORY ANALYSIS REPORT
NEI.AC Cenificarion Number: £87633
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
PEM CARTER
Client ID: EQUIP. BLANK #2
Prep Procedure Method
Analytical Prep Procedures:
OOWTHERM SW846 )500B
Analyst Prep Date
NC Cenijicarion Number: 25
Project Number: 61621.01
Report Date
Page 2 of 2
Sample ID
March 17, 2003
Report ID: A~~767
L03022403-09
DBC 02/26/03 0800
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 l U16 E. Ours! Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
82
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Df\YIS
FLOYD LABORATORY ANALYSIS REPORT
NEL.AC Certification Number: £87633
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
PEM CARTER
Client ID: TRIP BLANK
Parameter
Volatile Organics
SW846 8260B
Matrix
1 , 1 , 1 -TRICHLOROETHANE
1,1,2,2-TETRACHLOROETHANE
1,1,2-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
1,2-DICHLOROETHANE
1,2-0ICHLOROPROPANE
2-BlITANONE
2-HEXANONE
4-METHYL-2-PENTANONE
ACETONE
BENZENE
BROMODICHLOROMETHANE
BROMOFORM
BROMOMETHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHUJROBENZENE
CHLOROETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-DICHLOROETHENE
CIS-1,3-DICHLOROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-DICHLOROETHENE
TRANS-1,3-DICHLOROPROPENE
TRICHLORQETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL)
GW/ChemW
' ,: •· ,
Result
< 0 .0010
o. 0010
< 0 .0010
< 0 .0010
0 .0010
o. 0010
< 0 .0010
< 0 . 0050
< o. 0050
< o. 0050
< o. 0050
< 0 . 0010
o. 0010
< 0 .0010
< 0 .0010
< o. 0010
< 0 .0010
< 0. 0010
< 0 . 0010
< 0 . 0010
< 0.0010
< 0 .0010
< o. 0010
< 0 .0010
< 0 .0010
< o. 0010
< 0 . 0010
< 0 .0010
< 0.0010
< 0.0010
< 0.0010
< 0.0010
< o. 0010
< 0. 0010
< 0. 0020
NC Certification Number: 25
Project Number: 51621.01
Report Date
Page 1 of l
Sample ID
March 17, 2003
Report ID: AB4768
L03022403-10
Date Collected: 12-FEB-03 09:30
Date Received 21-FEB-03
Qual RDL Units Analyst Date
0 .0010 mg/1 PAP 02/24/03
0 . 0010 mg/1 PAP 02/24/03
0 .0010 mg/1 PAP 02/24/03
0 .0010 mg/1 PAP 02/24/03
o. 0010 mg/1 PAP 02/24/03
0. 0010 mg/1 PAP 02/24/03
0 .0010 mg/1 PAP 02/24/03
0 .0050 mg/1 PAP 02/24/03
0. 0050 mg/1 PAP 02/24/03
0. 0050 mg/1 PAP 02/24/03
o. 0050 mg/1 PAP 02/24/0J
0 . 0010 mg/] PAP 02/24/03
0 .0010 mg/1 PAP 02/24/03
0. 0010 mg/1 PAP 02/24/03
0 .0010 mg/1 PAP 02/24/03
o. 0010 mg/1 PAP 02/24/03
o. 0010 mg/1 PAP 02/24/03
0 .0010 mg/1 PAP 02/24/03
0 . 0010 mg/1 PAP 02/24/03
0 . 0010 mg/1 PAP 02/24/03
0 .0010 mg/1 PAP 02/24/03
o. 0010 mg/1 PAP 02/24/03
0. 0010 mg/1 PAP 02/24/03
0. 0010 mg/1 PAP 02/24/03
0.0010 mg/1 PAP 02/24/03
o. 0010 mg/1 PAP 02/24/03
o. 0010 mg/1 PAP 02/24/03
0 .0010 mg/1 PAP 02/24/03
0 . 0010 mg/1 PAP 02/24/03
o. 0010 mg/1 PAP 02/24/03
0. 0010 mg/1 PAP 02/24/03
0 .0010 mg/1 PAP 02/24/03
o. 0010 mg/1 PAP 02/24/03
0.0010 mg/1 PAP 02/24/03
0. 002 0 mg/1 PAP 02/24/03
Tiil\e
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
Davis & Floyd, Inc. j PO Drawer 428 \ Greenwood, SC 29648 ! 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
83
D1-\YIS
FLOYD LABORATORY ANALYSIS REPORT
NELAC Certification Number: £87633
Client
Contact
TICONA,LLC
2525 BLACKSBV~G ROAD
HWY 198
SHELBY, NC 28152
PEM CARTER
Client ID: D-88
Matrix
Parameter
Semivolatile Organics
S1<1846 8270C DOWTHERM
1,1'-BIPHENYL
BIPHENYL ETHER
Prep Procedure
Analytical Prep Procedures:
OOWTHERM
GW/ChernW
Method
SW846 3500B
Result
0.010
0.010
Analyst Prep Date
NC Certification Number: 25
Project Number: 61621.0l
Report Date
Page 1 of 1
sample 1D
Date Collected:
Date
Qual
Received
RDL
0.010
0.010
March 1 7. 2003
Report ID: A.B4769
L03022403-ll
20-FEB-03 12 :55
21-FEB-03
Units Analyst Date Time
mg/1
mg/1
JRN 02/27/03 1304
JRN 02/27/03 1304
DEC 02/26/03 0800
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Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 \ 816 E. Durst Avenue
84
I Greenwood, SC 2%49 I (864) 229-44 lJ I Fax [phone]
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Di\YIS
FLOYD LABORATORY ANALYSIS REPORT
NELAC Certification Number: £87633
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 2B152
PEM CARTER
Client IQ: D-56
Matrix
Parameter
Semivolatile Organics
SW846 8270C DOWTHERM
1, l' -Bl PHENYL
BIPHENYL ETHER
Prep Procedure
Analytical Prep Procedures:
DOWTHERM
GW/Chem\./
Method
SW846 3500B
Result
0.010
0. 010
Analyst Prep Date
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 1 of 1
Sample ID
Date Collected:
Date
Qual
Received
RDL
0.010
0.010
March ~ I ' 2003
Report CD: AE.;. 770
L03022:.Q3-12
20-FEB-03 1' :00
21 -FE3-03
Units Analyst Date Time
mg/ l
mg/1
JRN 02/27/03 1342
JRN 02/27/03 1342
DSC 02/26/03 0800
Davis & Floyd, lnc I PO Drawer 428 j Greenwood, SC 29648 I 816 E. Ours! Avenue I Greenwcx,d, SC 29649 I !864J 229-44 U I F.ix (U64) 229-71 l 9
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Di\YIS
FLtwD LABORATORY ANALYSIS REPORT
NELAC Certijica1io11 Number: £87633
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
PEM CARTER
Client ID: D-35
Matrix
Parallleter
Semivolatile Organics
SW846 8270C DOWTHERM
1, l' -81 PHENYL
BIPHENYL ETHER
Prep Procedure
Analytical Prep Procedures:
DOWTHERM
GW/ChemW
Method
SWB-4 6 3 5008
<
<
Result
0.010
0.010
Analyst Prep Date
NC Certificatio11 Number: 25
Project Number: 61621.01
Report Date
Page 1 of 1
Sample ID
Date Collected:
Date
Qual
Received
RDL
0. 010
0.010
March 17' 2003
Report IO: AB4771
L03022403-13
20-FEB-03 17 :20
21-FEB-0J
Units Analyst Date Time
mg/1
mg/1
JRN 02/27/03 1422
JRN 02/27/03 1422
DBC 02/26/03 0800
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Davis & Floyd, Inc I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue
86
I Greenwood, SC 29649 I (864) 229-44 I 3 I Fax [phone]
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Df\VIS
FLOYD LABORATORY ANALYSIS REPORT
NELAC Certification Number: £87633
Client
Contact
TICONA,LLC
2525 BI..ACKSBURG ROAD
HWY 198
SHELBY, NC 28152
PEM CARTER
Client ID: D-27
Matrix
Parameter
Somivolatile Organics
SW846 8270C DOWTHERM
1,1'-BIPHENYL
BIPHENYL ETHER
Prep Procedure
Analytical Prep Procedures:
DOWTHERM
GW/ChemW
Method
SW846 35008
<
Result
0.010
0.010
Analyst Prep Date
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 1 of 1
Sample ID
March 17, 2003
Report ID: AB4772
L03022403-H
Date Collected: 20-FEB-03 18:20
Date Received 21-FEB-03
Qual RDL Units Analyst Date Time
0.010
0.010
mg/1
mg/1
JRN 02/27/03 1501
JRN 02/27/03 1501
DBC 02/26/03 0800
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 1 816 E. Durs1 Avenue I Greenwood, SC 29649 I (864) 229-441] I Fax [phone]
87
-------------------Chain cif Custody Record Pago _f_ of J_
-Kubal-Furr & Associates
11.;ontact
Julie Llsenbv
Project I Sita Location
61621.01
816 E. Durst Avenue, Greenwood, SC 28649 [phone] Fax: (864) ~71HI
Labora/o,y Celtifcation Numbets: SC-24110, NC-25, TN-2923, VA• 77
von.ct.c1By
Requlf8d Parame/e,s, 1.,ontalne1S and Preservatives Stat.
' Ill
NOTICE:
Sample Collection
Samele Descriotion Date Time Time Type Total •-· HOT ....unvnems
:r=-rcr o/.).ilo3 /3/D XIS .s" X X X 0.5
OIP
O'l
J
cLLf✓,z Dale nme ReUquished By o,,. ·-
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Rect1ved By/ Datl nme Pf;;d:Lfn~ii ✓i~ · °'" ""'" !),.~/.a£ Jt,(5"
MatJix Type o.finibonl 1 -DMking Water 2 -Clean Water 5 • Groundwater 7 • S01VSed11T1enl 8 • Uqu1d Sludge 9 • Oil 12. /tjf .
-...•.. -........ -,•---• ··---P ....... ~,.,,, /",1-;r;t n.1,,1Nn1 F.N110H F-F1Uared G-Olher
--

-
---

-
--

-
-

-
------
Chain of Custody Record Pagej_ofl__
Client Project I Site Location 816 E. Durst Avenue, Greenwood, SC 29648 [phone] Fax: [phone] "'
Kubal-Furr & Associates 61621.01 Laboratory Certifcatlon Numbers: SC-24110, NC-25, TN-2923, VA-77
.
Contact RfE"rlTo Copy To Reporting Requiraments: { J Standard { J Data Package (Specify LeveO ,-.,....,,asevtder
Julie Lisenby Ef1 C...z102.--'77Cc1vA-0"i,,t, G" lt.J c?-.1 J.., -fr...<Jt LEl/et..-rr. -
CollectedByv;il.V /:.t.)Sµ,4-rJ Required Parameters, Containers and Preservatives State ,_
-~, pc_,
-:fe ff Uc° £,<I I 1-r N
'""' c=IO "'"""""°"'
NOTICE: ~ e '--::: i ~ . 2 ~ • ~ •. I! ;i ! ~ i tc
n • 2 "6 § 11 E ~ l • ~ 8. X D 2 • E .~ D ,a E
Sample Collection §~ .~ • .. ...J " Samole Oescriotion Date Time Time Type Total ·-· HOT ..;ommems
v-&k ::Zl,A, ,1 /'JS".{ )( 5 I I I Scc7ArC.
1) -._s-t, J./;.,' "3 i'-/dci X: 5' I / 1-, al),,,_, 7("0 r7
1)-3< :l, ,:i,,,3 17,J.o x s I ,~
h-n J., 'k/,J 1'f'J.o 'X 5 ( I U..
·-•~·
/7 -
II
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/ ) """'
~14.7) lPate Time r-receilledBy Date Time ~;;L;;.~rt~pYJ~ Dat9 T,,ne ffY,-
1~4-,,,~;/ ~-:i,.o~ //,JS-__Loaya
• 1..,,,.,.,.,,-nu/
Coolerl~,_), ,.,.,-
Onlc,,c YN/ No Ten1'(:~
Custody Seat: lmac:I / Btoun /
Matrix Type Definitions 1 -0Mking water 2 -Clean Water 5 -Groundwater 7 -S01VSedunent 8 • Liquid studge 9 • 011 12 • Ajr °""" & Floyd. Inc.
""-----4 .... ..,. ----.& u--D.L.l':11::f'U r..1.-11""1 n.1-lf,,1n~ i::.Nanl-l F-Fitu,,o,d G-Other R.02_01 (U2/H}
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DAYIS
FLbYD
July 24, 2003
PEM CARTER
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC. 28152
:L03022703
:61621.01
LABORATORY ANALYSIS REPORT
Login Number
Project Number
Description :GROUNDWATER -REVISED 24-JUL-03
Dear Pem Carter:
We are pleased to provide the enclosed analytical results for the samples received by
Davis & Floyd, Inc. on February 26, 2003.
A formal Quality Assurance/Quality Control program is maintained by Davis & Floyd,
which is designed to meet or exceed the EPA, NELAC or other appropriate regulatory
requirements. All analytical analyses for this project met QA/QC criteria and the
results are within the 99 % confidence interval for each method unless otherwise
stated in the footnotes. This report is to be reproduced only in full.
Feel free to contact our Client Services Representative at [phone] if further
explanation of the analysis is required. Unless other arrangements have been made,
samples will be disposed of or returned 14 days from the date of the report. We
appreciate the opportunity to provide services to your firm.
Sincerely, ;';,~;p,
J H. McCord, Jr
aboratory Manager
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
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DAYIS
FLtwD LABORATORY ANALYSIS REPORT
March I 7, 2003
PEM CARTER
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198 .
SHELBY, NC 28152
Login Number
Project Number
Description
Dear Pem Carter:
:L03022703
:61621.01
:GROUNDWATER
We are pleased to provide the enclosed analytical results for the samples received by
Davis & Floyd, Inc. on February 26, 2003.
A formal Quality Assurance/Quality Control program is maintained by Davis & Floyd,
which is designed to meet or exceed the EPA, NELAC or other appropriate regulatory
requirements. All analytical analyses for this project met QA/QC criteria and the
results are within the 99 % confidence interval for each method unless otherwise
stated in the footnotes. This report is to be reproduced only in full.
.Feel free to contact our Client Services Representative at [phone] if further
explanation of the analysis is required. Unless other arrangements have been made,
samples will be disposed of or returned 14 days from the date of the report. We
appreciate the opportunity to provide services to your firm.
Sincerely, ,
DAVIS & FLOYD, J C.
.•
,
hn H. McCord, Jr.
Laboratory Manager
Davis & Floyd, Inc. I PO Drawer 428 1 Greenwood, SC 29648 I 816 E. Durst Avenue ! Greenwood, SC 29649 I [phone] I Fax [phone]l l9
90
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D}\VIS
FLtiYD LABORATORY ANALYSIS REPORT
NELAC Certification Number: £87633
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
PEM CARTER
Client ID: HH-77
Matrix
Parameter
Volatile Organics
SW846 8260B
1,1,1-TRICHLOROETHANE
1,1,2,2-TETRACHLOROETHANE
1,1,2-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-0ICHLOROETHENE
1,2-DICHLOROETHANE
1,2-DICHLOROPROPANE
2-BUTANDNE
2-HEXANONE
4-METHYL-2-PENTANONE
ACETONE
BENZENE
BROMODICHLOROMETHANE
BROMOFORM
BROMOMETHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-DICHLOROETHENE
CIS-1,3-DICHLOROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-DICHLOROETHENE
TRANS-1,3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE {TOTAL)
GW/Chemw
Result
0 . 0040
0 . 0040
0 . 0040
o. 0040
0. 0040
0 .0040
0 . 0040
0. 020
o. 020
0. 020
0. 020
o. 0040
o. 0040
o. 0040
0 . 0040
0 . 0040
0 . 0040
0 .0040
0 . 0040
o. 00-40
o. 0040
0.0088
0 . 0040
0 .0040
0 . 0040
0 .0040
0 . 0040
0. 0040
0 .0040
o. 0040
o. 0040
0.087
o. 0040
o. 0040
o. 0080
NC Certification Number: 25
Project Number: 61621.01
Report Date July 24, 2003
Page 1 of 1 Report ID: AB12426
Sample ID L03022703-01
Date Collected: 24-FEB-03 12: 20
Date Received 26-FEB-03
Qual RDL Units Analyst Date Time
X 0 . 0040 mg/1 PAP 03/07/03 1426
X 0 . 0040 mg/1 PAP 03/07/03 1426
X o. 0040 mg/1 PAP 03/07/03 1426
X o. 0040 mg/l PAP 03/07/03 1426
X 0 .0040 mg/1 PAP 03/07/03 1426
X 0 .0040 mg/1 PAP 03/07/03 1426
X 0 .0040 mg/1 PAP 03/07/03 1426
X 0. 020 mg/1 PAP 03/07/03 1426
X 0. 020 mg/1 PAP 03/07/03 14 26
X 0. 020 mg/1 PAP 03/07/03 1426
X 0. 020 mg/1 PAP 03/07/03 14 26
X 0 . 0040 mg/1 PAP 03/07/03 1426
X o. 0040 mg/1 PAP 03/07/03 1426
X o. 0040 mg/1 PAP 03/07/03 1426
X 0 . 0040 mg/1 PAP 03/07/03 1426
X 0 .0040 mg/1 PAP 03/07/03 1426
X 0 . 0040 mg/1 PAP 03/07/03 1426
X 0 .0040 mg/1 PAP 03/07/03 142 6
X 0 .0040 mg/1 PAP 03/07/03 1-426
X 0 . 00-40 mg/1 PAP 03/07/03 1426
X 0 . 0040 mg/1 PAP 03/07/03 14 26
o. 0040 mg/1 PAP 03/07/03 14 26
X 0 . 0040 mg/1 PAP 03/07/03 14 26
X 0 0040 mg/1 PAP 03/07/03 1426
X 0 .0040 mg/1 PAP 03/07/03 1426
X 0. 0040 mg/1 PAP 03/07/03 1426
X 0 . 0040 mg/1 PAP 03/07/03 1426
X 0. 0040 mg/1 PAP 03/07/03 1426
X 0 .0040 mg/1 PAP 03/07/03 14 2 6
X 0 . 0040 mg/1 PAP 03/07/03 14 26
X 0 . 0040 mg/1 PAP 03/07/03 14 26
0 . 0040 mg/1 PAP 03/07/03 1426
X 0 . 0040 mg/1 PAP 03/07/03 1426
X 0. 0040 mg/1 PAP 03/07/03 1426
X 0 .0080 mg/1 PAP 03/07/03 14 26
Davis & Floyd, Inc. J PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 ] [phone] I Fax [phone]
91
DAYIS
FLM:D LABORATORY ANALYSIS REPORT
NELAC Certification Number: £87633
Client
Contact
TICONA,LLC
·2s·2s BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
PEM CARTER
Client ID: GG-61
Matrix
Parameter
Volatile Organics
SW846 8260B
1,1,1-TRICHLOROETHANE
1,1,2,2-TETRACHLOROETHANE
1,1,2-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
1,2-DICHLOROETHANE
1,2-DICHLOROPROPANE
2-BUTANONE
2-HEXANONE
4-METHYL-2-PENTANONE
ACETONE
BENZENE
BROMODICHLOROMETHANE
BROMOFORM
BROMOMETHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-DICHLOROETHENE
CIS-1,3-DICHLOROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-DICHLOROETHENE
TRANS-1,3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL)
GW/ChemW
Result
' 0. 0010
' 0 .0010
' 0.0010
' 0 .0010
' 0 . 0010
0. 0010
' 0 . 0010
' 0 .0050
' 0 . 0050
' 0 .0050
' 0 . 0050
' 0. 0010
' 0 .0010
' 0 . 0010
' 0 . 0010
0.0011
' 0 . 0010
' 0 . 0010
' 0 . 0010
' 0 . 0010
' 0 . 0010
' 0 .0010
' 0 .0010
' 0 . 0010
' 0 .0010
' 0 . 0010
' 0 .0010
' 0. 0010
' 0 . 0010
' 0 .0010
' 0. 0010
' 0 . 0010
' 0 . 0010
' 0 .0010
' 0 . 0020
NC Certifica1ion Number: 25
Project Number: 61621.01
Report Date
Page 1 of 1
July 24, 2003
Report ID: AB12425
Sample ID L03022703-05
Date Collected: 24-FEB-03 18:30
Date Received: 26-FEB-03
Qual RDL Units Analyst Date
0.0010 mg/1 PAP 03/07/03
0 . 0010 mg/1 PAP 03/07/03
0 .0010 mg/1 PAP 03/07/03
0 . 0010 mg/1 PAP 03/07/03
0.0010 mg/1 PAP 03/07/03
0 . 0010 mg/1 PAP 03/07/03
0 . 0010 mg/1 PAP 03/07/03
0 .0050 mg/1 PAP 03/07/03
0 . 0050 mg/1 PAP 03/07/03
0.0050 mg/1 PAP 03/07/03
0.0050 mg/1 PAP 03/07/03
0.0010 mg/1 PAP 03/07/03
0.0010 mg/1 PAP 03/07/03
0 .0010 mg/1 PAP 03/07/03
o. 0010 mg/1 PAP 03/07/03
0.0010 mg/1 PAP 03/07/03
0 . 0010 mg/1 PAP 03/07/03
0 . 0010 mg/1 PAP 03/07/03
0.0010 mg/1 PAP 03/07/03
0. 0010 mg/1 PAP 03/07/03
0 . 0010 mg/1 PAP 03/07/03
0. 0010 mg/1 PAP 03/07/03
0.0010 mg/1 PAP 03/07/03
0.0010 mg/1 PAP 03/07/03
0.0010 mg/1 PAP 03/07/03
0.0010 mg/1 PAP 03/07/03
0.0010 mg/1 PAP 03/07/03
o. 0010 mg/1 PAP 03/07/03
0 .0010 mg/1 PAP 03/07/03
0 .0010 mg/1 PAP 03/07/03
0. 0010 mg/1 PAP 03/07/03
0.0010 mg/1 PAP 03/07/03
o. 0010 mg/1 PAP 03/07/03
0 .0010 mg/1 PAP 03/07/03
0 . 0020 mg/1 PAP 03/07/03
Time
1557
1557
1557
1557
1557
1557
1557
1557
1557
1557
1557
1557
1557
1557
1557
1557
1557
1557
1557
1557
1557
1557
1557
1557
1557
1557
1557
1557
1557
1557
1557
1557
1557
1557
1557
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Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone] I
92
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I D~IS
FLWD LABORATORY ANALYSIS REPORT
I NELA C Cenification Number: £87633 NC Cenification Number: 25
I Client TICONA,LLC Project Number: 61621.01
2525 BLACKSBURG ROAD'
I
HWY 198
SHELBY, NC 28152 Report Date July 24, 2003
Contact PEM CARTER Page 1 of l Report ID: AB12428
I Client ID: c-u Sample ID L03022703-03
Date Collected: 24-FEB-03 l4 :28
Matrix GW/ChemW Date Received 26-FEB-03
I Parameter Result Qual RDL units Analyst Date Time
Volatile Organics
I SW846 8260B
1,1,1-TRICHLOROETHANE ' 0. 0010 0.0010 mg/1 PAP 03/07/03 1512
1,1,2,2-TETRACHLOROETHANE ' 0 . 0010 0.0010 mg/1 PAP 03/07/03 1512
1,1,2-TRICHLOROETHANE ' 0. 0010 0 . 0010 mg/1 PAP 03/07/03 1512
I 1,1-DICHLOROETHANE ' 0. 0010 o. 0010 mg/1 PAP 03/07/03 1512
1,1-DICHLOROETHENE ' 0 .0010 0 . 0010 mg/1 PAP 03/07/03 1512
1,2-DICHLOROETHANE ' 0. 0010 0. 0010 mg/1 PAP 03/07/03· 1512
1,2-DICHLOROPROPANE ' 0 . 0010 0 .0010 mg/1 PAP 03/07/03 1512
I 2-BlITANONE ' 0 .0050 0. 0050 mg/1 PAP 03/07/03 1512
2-HEXANDNE ' 0 . 0050 0 . 0050 mg/1 PAP 03/07/03 1512
4-METHYL-2-PENTANONE ' 0 .0050 0 .0050 mg/1 PAP 03/07/03 1512
ACETONE ' 0 . 0050 0 .0050 mg/1 PAP 03/07/03 1512
I BENZENE ' 0 . 0010 0 . 0010 mg/1 PAP 03/07/03 1512
BROMODICHLOROMETHANE ' 0. 0010 o. 0010 mg/1 PAP 03/07/03 1512
BROMOFORM ' 0. 0010 o. 0010 mg/1 PAP 03/07/03 1512
I BROMOMETHANE ' 0 . 0010 0 . 0010 mg/1 PAP 03/07/03 1512
CARBON DISULFIDE ' 0 .0010 0 .0010 mg/1 PAP 03/07/03 1512
CARBON TETRACHLORIDE ' 0 . 0010 o . 0010 mg/1 PAP 03/07/03 1512
CHLOROBENZENE ' 0 .0010 0 .0010 mg/1 PAP 03/07/03 1512
I CHLOROETHANE ' 0 .0010 0 .0010 mg/1 PAP 03/07/03 1512
CHLOROFORM ' 0 . 0010 0 .0010 mg/1 PAP 03/07/03 1512
CHLOROMETHANE ' 0 .0010 0 . 0010 mg/1 PAP 03/07/03 1512
CIS-1,2-DICHLOROETHENE ' o. 0010 0 .0010 mg/1 PAP 03/07/03 1512
I CIS-1,3-DICHLOROPROPENE ' 0. 0010 0 .0010 mg/1 PAP 03/07/03 1512
DIBROMOCHLOROMETHANE ' 0. 0010 0 .0010 mg/1 PAP 03/07/03 1512
ETHYLBENZENE ' 0. 0010 o. 0010 mg/1 PAP 03/07/03 1512
I METHYLENE CHLORIDE ' 0 . 0010 0 . 0010 mg/1 PAP 03/07/03 1512
STYRENE ' 0 . 0010 0 .0010 mg/1 PAP 03/07/03 1512
TETRACHLOROETHENE ' 0 .0010 o. 0010 mg/1 PAP 03/07/03 1512
TOLUENE ' 0 .0010 0 . 0010 mg/1 PAP 03/07/03 1512
I TRANS-1,2-DICHLOROETHENE 0 . 0010 0 .0010 mg/1 PAP 03/07/03 1512
TRANS-1,3-DICHLOROPROPENE ' 0 .0010 0 .0010 mg/1 PAP 03/07/03 1512
TRICHLOROETHENE ' 0 .0010 0 .0010 mg/1 PAP 03/07/03 1512
VINYL ACETATE ' 0 .0010 0 .0010 mg/1 PAP 03/07/03 1512
I VINYL CHLORIDE ' 0. 0010 o. 0010 mg/1 PAP 03/07/03 1512
XYLENE (TOTAL) ' 0. 0020 0 . 0020 mg/1 PAP 03/07/03 1512
I
I Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Ours! Avenue I Greenwood, SC 29649 j (864) 229-44 I 3 I Fax [phone]
93
I
DAYIS
FLbYD LABORATORY ANALYSIS REPORT I
NELAC Cenification Number: £87633
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
PEM CARTER
Client IO: EE-58
Matrix
Parameter
Volatile Organics
SW846 8260B
1,1,1-TRICHLOROETHANE
1,1,2,2-TETRACHLOROETHANE
1,1,2-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
1,2-DICHLOROETHANE
1,2-DICHLOROPROPANE
2-BlITANONE
2-HEXANONE
4-METHYL-2-PENTANONE
ACETONE
BENZENE
BROMODICHLOROMETHANE
BROMOFORM
BROMOMETHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLO RO ETHANE
CHLOROFORM
CHLO RO METHANE
CIS-1,2-DICHLOROETHENE
CIS-1,3-DICHLOROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-DICHLOROETHENE
TRANS-1,3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL}
GW/ChemW
Result
' 0 .0010
' 0 .0010
' 0 . 0010
' 0 .0010
' 0. 0010
' o. 0010
' 0.0010
' 0 . 0050
' 0 .0050
< 0 . 0050
' 0 .0050
< 0 .0010
' 0 . 0010
' 0 .0010
' 0 .0010
' 0 . 0010
' 0 . 0010
' o. 0010
' o. 0010
' 0 .0010
' 0. 0010
' o. 0010
0. 0010
' o. 0010
' 0 .0010
< 0 .0010
' o. 0010
' o. 0010
' 0 . 0010
' 0 . 0010
' 0 .0010
< 0 .0010
' 0 .0010
' 0. 0010
< o. 0020
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 810 E. Durst Avenue
94
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 1 of 1
Sample ID
July 24, 2003
Report ID: AB12429
L03022703-04
Date Collected; 24-FEB-03 16:20
Date Received 26-FEB-03
RDL Units Analyst Date
0 .0010 mg/1 PAP 03/07/03
0 .0010 mg/1 PAP 03/07/03
0 .0010 mg/1 PAP 03/07/03
0.0010 mg/1 PAP 03/07/03
0 .0010 mg/1 PAP 03/07/03
0. 0010 mg/1 PAP 03/07/03
0 . 0010 mg/1 PAP 03/07/03
o . 0050 mg/1 PAP 03/07/03
0 . 0050 mg/1 PAP 03/07/03
0.0050 mg/1 PAP 03/07/03
0 .0050 mg/1 PAP 03/07/03
0 .0010 mg/1 PAP 03/07/03
0 .0010 mg/1 PAP 03/07/03
o. 0010 mg/1 PAP 03/07/03
0 . 0010 mg/1 PAP 03/07/03
0 .0010 mg/1 PAP 03/07/03
0 . 0010 mg/1 PAP 03/07/03
0. 0010 mg/1 PAP 03/07/03
0.0010 mg/1 PAP 03/07/03
0.0010 mg/1 PAP 03/07/03
0.0010 mg/1 PAP 03/07/03
0. 0010 mg/1 PAP 03/07/03
0 .0010 mg/1 PAP 03/07/03
0 .0010 mg/1 PAP 03/07/03
0 .0010 mg/1 PAP 03/07/03
0 .0010 mg/1 PAP 03/07/03
o. 0010 mg/1 PAP 03/07/03
o. 0010 mg/1 PAP 03/07/03
0. 0010 mg/1 PAP 03/07/03
0 .0010 mg/1 PAP 03/07/03
0.0010 mg/1 PAP 03/07/03
0. 0010 mg/1 PAP 03/07/03
0 . 0010 mg/1 PAP 03/07/03
0 .0010 mg/1 PAP 03/07/03
0. 002 0 mg/1 PAP 03/07/03
I
I
I
I
Time I
1535
1535 I
1535
1535
1535 I
1535
~535
1535
1535 I
1535
1535
1535
1535 I
1535
1535
1535 I
1535
1535
1535
1535 I
15351
1535
1535
1535 I
1535
1535
1535 I 1535
1535
1535
1535 I
1535
1535
1535
1535 I
I
I Greenwood, SC 2%49 I {864) 229-4413 I Fax [phone] I
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DAYIS
FLfilD LABORATORY ANALYSIS REPORT
NELAC Certification Number: £87633
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
PEM CARTER
Client ID: HH-48
Matrix
Parameter
Volatile Organics
SW846 8260B
1,1,1-TRICHLOROETHANE
1,1,2,2-TETRACHLOROETHANE
1,1,2-TRICHLOROETHANE
1,1-0ICHLOROETHANE
1,1-0ICHLOROETHENE
1,2-DICHLOROETHANE
1,2-DICHLOROPROPANE
2-BUTANONE
2-HEXANONE
4-METHYL-2-PENTANONE
ACETONE
BENZENE
BROMODICHLOROMETHANE
BROMOFORM
BROMOMETHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-DICHLOROETHENE
CIS-1,3-DICHLOROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-DICHLOROETHENE
TRANS-1,3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL)
GW/ChemW
Result
0 .0010
0. 0010
0. 0010
0 .0010
0.0010
0 .0010
0 .0010
o. 0050
0 . 0050
0 . 0050
0 .0050
0 . 0010
0. 0010
0. 0010
0. 0010
0. 0010
0 . 0010
o. 0010
o. 0010
0 .0010
0. 0010
0.0011
0. 0010
0 .0010
o. 0010
o. 0010
o. 0010
0 . 0010
0 .0010
0 .0010
0 .0010
0. lS
0 .0010
0. 0010
0 . 0020
NC Certification Number: 25
Project Number; 61621.01
Report Date July 24, 2 003
Page 1 of 1 Report ID: AB12427
Sample ID L03022703-02
Date Collected: 24-FEB-03 13 : 20
Date Received 26-FEB-03
Qual RDL Units Analyst Date Time
0. 0010 mg/1 PAP 03/07/03 1449
0. 0010 mg/1 PAP 03/07/03 1449
0 .0010 mg/1 PAP 03/07/03 144 9
0 . 0010 mg/1 PAP 03/07/03 1449
0 . 0010 mg/1 PAP 03/07/03 1449
0 .0010 mg/1 PAP 03/07/03 '1449
0. 0010 mg/1 PAP 03/07/03 1449
o. 0050 mg/1 PAP 03/07/03 1449
0 .0050 mg/1 PAP 03/07/03 144 9
0.0050 mg/1 PAP 03/07/03 1449
0 . 0050 mg/1 PAP 03/07/03 1449
o. 0010 mg/1 PAP 03/07/03 1449
0 . 0010 mg/1 PAP 03/07/03 144 9
0 . 0010 mg/1 PAP 03/07/03 1449
0 . 0010 mg/1 PAP 03/07/03 1449
0 .0010 mg/1 PAP 03/07/03 1449
0 .0010 mg/1 PAP 03/07/03 1449
0 .0010 mg/1 PAP 03/07/03 1449
0 .0010 mg/1 PAP 03/07/03 144 9
o. 0010 mg/1 PAP 03/07/03 1449
0.0010 mg/1 PAP 03/07/03 1449
o. 0010 mg/1 PAP 03/07/03 1449
0 . 0010 mg/1 PAP 03/07/03 1449
0 .0010 mg/1 PAP 03/07/03 144 9
0 .0010 mg/1 PAP 03/07/03 144 9
0 .0010 mg/1 PAP 03/07/03 1449
0 .0010 mg/1 PAP 03/07/03 144 9
0 .0010 mg/1 PAP 03/07/03 144 9
0 .0010 mg/1 PAP 03/07/03 1449
0 .0010 mg/1 PAP 03/07/03 144 9
0 .0010 mg/1 PAP 03/07/03 144 9
0 . 0010 mg/1 PAP 03/07/03 1449
0 . 0010 mg/1 PAP 03/07/03 1H9
0 . 0010 mg/1 PAP 03/07/03 144 9
0 .0020 mg/1 PAP 03/07/03 1449
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29(,49 I [phone] I Fax [phone] I 19
95
DAYIS
FLtwD LABORATORY ANALYSIS REPORT
NELA C Certification Number: £87633
Client
Contact
Matrix
Parameter
Volatile Organics
SW846 8260B
1,1,1-TRICHLOROETHANE
1,1,2,2-TETRACHLOROETHANE
1,1,2-TRICHLOROETHANE
1,1-DICHLOROETHANE
1, 1-DICHLOROETHENE
1,2-DICHLOROETHANE
1,2-DICHLOROPROPANE
2-BUTANONE
2-HEXANONE
4-METHYL-2-PENTANONE
ACETONE
BENZENE
BROMODICHLOROMETHANE
BROMOFORM
BROMOMETHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-DICHLOROETHENE
CIS-1,3-DICHLOROPROPENE
DIBROMOCHI,OROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-DICHLOROETHENE
TRANS-1,3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL)
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
PEM CARTER
GW/ChemW
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
Result
0 .0010
0 .0010
0 .0010
0 .0010
o. 0010
o. 0010
0 .0010
o. 0050
0 .0010
0 . 0050
0.0050
o. 0010
o. 0010
o. 0010
o. 0010
0. 0010
0. 0010
o. 0010
o. 0010
o. 0010
0. 0010
o. 0010
0 .0010
0 .0010
0 .0010
0 . 0010
0 .0010
0 .0010
0 .0010
0. 0010
0 .0010
0 .0010
0 .0010
0.0010
0.0020
NC Certification Number: 25
Project Number: 61621.01
Report Date ' July 24, 2003
Page 1 of 1 Report ID: AB12430
Sample ID L03022703-06
Date Collected: 25-FEB-03 08:40
Date Received 26-FEB-03
oual RDL Units Analyst Date Time
0. 0010 mg/1 PAP 03/07/03 1255
0.0010 rng/1 PAP 03/07/03 1255
0.0010 mg/1 PAP 03/07/03 1255
0.0010 mg/1 PAP 03/07/03 1255
0. 0010 rng/1 PAP 03/07/03 1255
0.0010 mg/1 PAP 03/07/03 1255
0.0010 rng/1 PAP 03/07/03 1255
0.0050 mg/1 PAP 03/07/03 1255
0. 0010 mg/1 PAP 03/07/03 1255
o. 0050 mg/1 PAP 03/07/03 1255
0. 0050 mg/1 PAP 03/07/03 1255
0. 0010 mg/1 PAP 03/07/03 1255
0. 0010 mg/1 PAP 03/07/03 1255
0 .0010 mg/1 PAP 03/07/03 1255
0 .0010 rng/1 PAP 03/07/03 1255
0 .0010 mg/1 PAP 03/07/03 1255
0. 0010 mg/1 PAP 03/07/03 1255
o. 0010 mg/1 PAP 03/07/03 1255
o. 0010 mg/1 PAP 03/07/03 1255
o. 0010 mg/1 PAP 03/07/03 1255
0.0010 mg/1 PAP 03/07/03 1255
0.0010 mg/1 PAP 03/07/03 1255
0.0010 mg/1 PAP 03/07/03 1255
0 .0010 mg/1 PAP 03/07/03 1255
0 . 0010 mg/1 PAP 03/07/03 1255
0.0010 mg/1 PAP 03/07/03 1255
0 . 0010 mg/1 PAP 03/07/03 1255
0 . 0010 mg/1 PAP 03/07/03 1255
0.0010 mg/1 PAP 03/07/03 1255
0. 0010 mg/1 PAP 03/07/03 1255
0 .0010 mg/1 PAP 03/07/03 1255
0. 0010· mg/1 PAP 03/07/03 1255
0. 0010 mg/1 PAP 03/07/03 1255
0. 0010 mg/1 PAP 03/07/03 1255
0. 0020 mg/1 PAP 03/07/03 1255
I
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Davis & Floyd, Inc. ! PO Drawer 428 I Greenwood, SC 29648 I H16 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone] I
96
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DAYIS
FLOYD LABORATORY ANALYSIS REPORT
NELA C Certificatian Number: £87633
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
PEM CARTER
Client ID: P-58
Matrix
Parameter
Volatile Organics
SW846 8260B
1,1,1-TRICHLOROETHANE
1,1,2,2-TETRACHLOROETHANE
1,1,2-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
1,2-DICHLOROETHANE
1,2-DICHLOROPROPANE
2-BUTANONE
2-HEXANONE
4-METHYL-2-PENTANONE
ACETONE
BENZENE
BROMODICHLOROMETHANE
BROMOFORM
BROMOMETHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-DICHLOROETHENE
CIS-1,3-DICHLOROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-DICHLOROETHENE
TRANS-1,3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL)
GW/ChemW
Result
' 0. 0010
' 0. 0010
' 0. 0010
' 0. 0010
' 0 .0010
' 0 .0010
' 0 .0010
' 0 . 0050
' 0 .0050
' 0 .0050
' 0 . 0050
' 0. 0010
' 0. 0010
' 0 .0010
' 0 .0010
' o. 0010
' 0 . 0010
' 0. 0010
' o. 0010
' 0 .0010
' 0. 0010
' 0. 0010
' 0. 0010
' 0 .0010
' 0. 0010
' o. 0010
' 0 .0010
' 0 . 0010
' 0 .0010
' 0. 0010
' 0. 0010
' o. 0010
' 0. 0010
' .0010
' 0.0020
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 1 of 1
: July 24, 2003
Report ID: AB12431
Sample ID L03022703-07
Date Collected: 25-FEB-03 10:20
Date Received : 26-FEB-03
Qual RDL Units Analyst Date
0. 0010 mg/1 PAP 03/07/03
0. 0010 mg/1 PAP 03/07/03
0 . 0010 mg/1 PAP 03/07/03
o. 0010 mg/1 PAP 03/07/03
0 . 0010 mg/1 PAP 03jo7/03
0. 0010 mg/1 PAP 03/07/03
0 .0010 mg/1 PAP 03/07/03
0 . 0050 mg/1 PAP 03/07/03
o. 0050 mg/1 PAP 03/07/03
0 . 0050 mg/1 PAP 03/07/03
0 . 0050 mg/1 PAP 03/07/03
0. 0010 mg/1 PAP 03/07/03
0 . 0010 mg/1 PAP 03/07/03
0. 0010 mg/1 PAP 03/07/03
o. 0010 mg/1 PAP 03/07/03
0 .0010 mg/1 PAP 03/07/03
0 . 0010 mg/1 PAP 03/07/03
0 . 0010 mg/1 PAP 03/07/03
0 .0010 mg/1 PAP 03/07/03
0 . 0010 mg/1 PAP 03/07/03
0. 0010 mg/1 PAP 03/07/03
0 . 0010 mg/1 PAP 03/07/03
0. 0010 mg/1 PAP 03/07/03
0 .0010 mg/1 PAP 03/07/03
o. 0010 mg/1 PAP 03/07/03
o. 0010 mg/1 PAP 03/07/03
0 . 0010 mg/1 PAP 03/07/03
o. 0010 mg/1 PAP 03/07/03
0 . 0010 mg/1 PAP 03/07/03
0 .0010 mg/1 PAP 03/07/03
0. 0010 mg/1 PAP 03/07/03
0 . 0010 mg/1 PAP 03/07/0J
0. 0010 mg/1 PAP 03/07/03
0 .0010 mg/1 PAP 03/07/03
0 . 0020 mg/1 PAP 03/07/03
Time
1620
1620
1620
1620
1620
1620
1620
1620
1620
1620
1620
1620
1620
1620
1620
1620
1620
1620
1620
1620
1620
1620
1620
1620
1620
1620
1620
1620
1620
1620
1620
1620
1620
1620
1620
Davis & Floyd, Inc. j PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue ! Greenwood, SC 29649 j [phone] I Fax {864) 229-7119
97
DAYIS
FLtWD LABORATORY ANALYSIS REPORT
NELAC Certification Number: £87633
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
PEM CARTER
Client ID: K-28
Matrix
Parameter
Volatile Organics
SW846 8260B
1,1,1-TRICHLOROETHANE
1,1,2,2-TETRACHLOROETHANE
1,1,2-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
1,2-DICHLOROETHANE
1, 2-DICHLOROPROPANE
2-BUTANONE
2-HEXANONE
4-METHYL-2-PENTANONE
ACETONE
BENZENE
BROMODICHLOROMETHANE
BROMOFORM
BROMOMETHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-DICHLOROETHENE
CIS-1,3-DICHLOROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRAN'S-1,2-DICHLOROETHENE
TRANS-1,3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL)
Wet Chemistry
SW846 9060
ORGANIC CARBON, TOTAL
GW/ChemW
Result
< o. 0010
< 0 . 0010
< 0. 0010
< 0. 0010
< 0. 0010
< 0. 0010
< 0. 0010
' 0. 0050
< 0 . 0050
< 0.0050
< 0.0050
0.0057
< o. 0010
< 0 . 0010
< 0. 0010
< o. 0010
< 0 . 0010
< 0 . 0010
< 0. 0010
< 0 .0010
< 0 .0010
' o. 0010
< 0.0010
< 0. 0010
< 0. 0010
< 0 . 0010
< 0 .0010
< 0 .0010
< o. 0010
0 . 0010
< . 0010
< o. 0010
< 0.0010
< 0.0010
< 0.0020
1.5
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 1 of 1
July 24, 2003
Report ID: AB12432
Sample ID L03022703-08
Date Collected: 25-FEB-03 11:35
Date Received
Qual RDL Units Analyst Date
0. 0010 mg/1 PAP 03/07/03
0 . 0010 mg/1 PAP 03/07/03
0 . 0010 mg/1 PAP 03/07/03
o. 0010 mg/1 PAP 03/07/03
o. 0010 mg/1 PAP 03/07/03
o. 0010 mg/1 PAP 03/07/03
0. 0010 mg/1 PAP 03/07/03
0. 0050 mg/1 PAP 03/07/03
0 . 0050 mg/1 PAP 03/07/03
0. 0050 mg/1 PAP 03/07/03
0. 0050 mg/1 PAP 03/07/03
0. 0010 mg/1 PAP 03/07/03
0. 0010 mg/1 PAP 03/07/03
0. 0010 mg/1 PAP 03/07/03
o. 0010 mg/1 PAP 03/07/03
0. 0010 mg/1 PAP 03/07/03
0 . 0010 mg/1 PAP 03/07/03
0. 0010 mg/1 PAP 03/07/03
o. 0010 mg/1 PAP 03/07/03
o. 0010 mg/1 PAP 03/07/03
0 .0010 mg/1 PAP 03/07/03
0. 0010 mg/1 PAP 03/07/03
0. 0010 mg/1 PAP 03/07/03
0 . 0010 mg/1 PAP 03/07/03
0 . 0010 mg/1 PAP 03/07/03
0 .0010 mg/1 PAP 03/07/03
0. 0010 mg/1 PAP 03/07/03
0 .0010 mg/1 PAP 03/07/03
0. 0010 mg/1 PAP 03/07/03
0 . 0010 mg/1 PAP 03/07/03
0 . 0010 mg/1 PAP 03/07/03
0 .0010 mg/1 PAP 03/07/03
0 .0010 mg/1 PAP 03/07/03
o. 0010 mg/1 PAP 03/07/03
0. 0020 mg/1 PAP 03/07/03
Time
2125
2125
2125
2125
2125
2125
2125
2125
2125
2125
2125
2125
2125
2125
2125
2125
212 5
212 5
212 5
2125
2125
2125
2125
212 5
2125
2125
2125
2125
2125
2125
2125
2125
2125
2125
2125
1.0 mg/1 CLB 03/03/03 2059
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
98
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D~IS
FLOYD LABORATORY ANALYSIS REPORT
NELAC Cenijication Number: £87633
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
PEM CARTER
Client ID: V-23
Matrix
Para.meter
Volatile organics
SW846 8260B
1,1,1-TRICHLOROETHANE
1, 1,2,2-TETRACHLOROETHANE
1,1,2-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
1, 2-DICHLOROETHANE
1,2-DICHLOROPROPANE
2-BUTANONE
2-HEXANONE
4-METHYL-2-PENTANONE
ACETONE
BENZENE
BROMODICHLOROMETHANE
BROMOFORM
BROMOMETHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-DICHLOROETHENE
CIS-1,3-DICHLOROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-DICHLOROETHENE
TRANS-1,3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL)
Wet Chemistry
SW846 9060
ORGANIC CARBON, TOTAL
GW/ChemW
Result
< 0. 0020
< o. 0020
< 0 . 0020
< 0. 0020
< 0.0020
< 0. 0020
< 0 . 0020
0 .12
< 0 .010
< 0 .010
0.088
0.0099
< 0 . 0020
< 0 . 0020
< 0. 0020
0.0083
< 0 . 0020
< 0. 0020
< 0. 0020
< 0. 0020
< 0. 0020
< o. 0020
< 0 . 0020
< 0 .0020
< 0. 0020
< o. 0020
< 0. 0020
< 0. 0020
.0035
< 0 . 0020
< 0 .0020
< 0 . 0020
< 0. 0020
< 0. 0020
0. OOH
3940
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 1 of 1
July 24, 2003
Report ID: AB12433
Sample ID L03022703-09
Date Collected: 25-FEB-03 13:05
Date Received : 26-FEB-03
Qual RDL Units Analyst Date
X 0. 0020 mg/1 PAP 03/07/03
X 0. 0020 mg/1 PAP 03/07/03
X 0 .0020 mg/1 PAP 03/07/03
X 0 . 0020 mg/1 PAP 03/07/03
X 0. 0020 mg/1 PAP 03/07/03
X 0 . 0020 mg/1 PAP 03/07/03
X 0. 0020 mg/1 PAP 03/07/03
o. 010 mg/1 PAP 03/07/03
X 0 .010 mg/1 PAP 03/07/03
X 0 .010 mg/1 PAP 03/07/03
0 .010 mg/1 PAP 03/07/03
0 . 0020 mg/1 PAP 03/07/03
X o. 0020 mg/1 PAP 03/07/03
X 0.0020 mg/1 PAP 03/07/03
X 0. 0020 mg/1 PAP 03/07/03
0. 0020 mg/1 PAP 03/07/03
X 0. 0020 mg/1 PAP 03/07/03
X 0.0020 mg/1 PAP 03/07/03
X 0. 0020 mg/1 PAP 03/07/03
X 0. 0020 mg/1 PAP 03/07/03
X 0. 0020 mg/1 PAP 03/07/03
X 0. 0020 mg/1 PAP 03/07/03
X 0. 0020 mg/1 PAP OJ/07/03
X 0 .0020 mg/1 PAP OJ/07/03
X 0 .0020 mg/1 PAP 03/07/03
X 0. 0020 mg/1 PAP 03/07/03
X o. 0020 mg/1 PAP 03/07/03
X 0. 0020 mg/1 PAP 03/07/03
0 .0020 mg/1 PAP 03/07/03
X 0. 0020 mg/1 PAP 03/07/03
X 0 . 0020 mg/1 PAP 03/07/03
X 0. 0020 mg/1 PAP 03/07/03
X o. 0020 mg/1 PAP 03/07/03
X 0 .0020 mg/1 PAP 03/07/03
0. 0040 mg/1 PAP 03/07/03
Time
2039
2039
2039
2 03 9
2039
2039
2039
2039
2039
2039
2039
2039
2039
2039
2039
2039
2039
2039
2039
2039
2039
2039
2039
2039
2039
2039
2039
2039
2039
2039
2039
2039
203 9
2039
2 03 9
25.0 mg/1 CLB 03/04/03 0946
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 / [phone] / Fax [phone]
99
DAYIS
FLMD LABORATORY ANALYSIS REPORT
NELA C Cenijication Number: £87633
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
PEM CARTER
Client ID: v-23 DUP.
Matrix
Parameter
Volatile Organics
SW846 8260B
1,1,1-TRICHLOROETHANE
1,1,2,2-TETRACHLOROETHANE
1,l,2·TRICHLOROETHANE
1,1-DICHLOROETHANE
1, 1-DICHLOROETHENE
1, 2-DICHLOROETHANE
1,2-0ICHLOROPROPANE
2-BUTANONE
2-HEXANONE
4 -METHYL-2 -PEN'l'ANONE
ACETONE
BENZENE
BROMODICHLOROMETHANE
BROMOFORM
BROMOMETHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-DICHLOROETHEN~
CIS-1,3-DICHLOROPROPENE
D!BROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-DICHLOROETHENE
TRANS·l,3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL)
Wet Chemistry
SW846 9060
ORGANIC CARBON, TOTAL
GW/ChemW
Result
< 0.0020
< 0 .0020
< 0. 0020
< 0. 0020
< 0. 0020
< 0 . 0020
< 0 .0020
0.11
< 0.010
< 0.010
0. 080
0.0099
< 0 .0020
< 0 .0020
< 0 . 0020
0.0078
< 0. 0020
< 0 . 0020
< 0. 0020
< 0 .0020
< o. 0020
< o. 0020
< 0 . 0020
< 0. 0020
< 0 . 0020
< 0 . 0020
< o. 0020
< 0 .0020
0.0035
< 0. 002 0
< 0.0020
< 0.0020
< 0. 002 0
< 0.0020
0.0047
4170
NC Cenijication Number: 25
Project Number: 61621.01
Report Date ' July 24, 2003
Page 1 of 1 Report ID: AB12434
Sample ID L03022703-10
Date Collected: 25-FEB-03 13 :05
Date Received 26-FEB-03
Qual RDL Units Analyst Date Time
X 0.0020 mg/1 PAP 03/07/03 2102
X 0.0020 mg/1 PAP 03/07/03 2102
X 0.0020 mg/1 PAP 03/07/03 2102
X 0. 0020 mg/1 PAP 03/07/03 2102
X 0. 0020 mg/1 PAP 03/07/03 2102
X o . 0020 mg/1 PAP 03/07/03 2102
X 0 . 0020 mg/1 PAP 03/07/03 2102
0. 010 mg/1 PAP 03/07/03 2102
X 0. 010 mg/1 PAP 03/07/03 2102
X 0 .010 mg/1 PAP 03/07/03 2102
0 .010 mg/1 PAP 03/07/03 2102
O. 0020 mg/1 PAP 03/07/03 2102
X 0. 0020 mg/1 PAP 03/07/03 2102
X 0.0020 mg/1 PAP 03/07/03 2102
X 0.0020 mg/1 PAP 03/07/03 2102
0.0020 mg/1 PAP 03/07/03 2102
X 0.0020 mg/1 PAP 03/07/03 2102
X 0. 0020 mg/1 PAP 03/07/03 2102
X 0.0020 mg/1 PAP 03/07/03 2102
X 0 . 0020 mg/1 PAP 03/07/03 2102
X o. 0020 mg/1 PAP 03/07 /03 2102
X o. 0020 mg/1 PAP 03/07/03 2102
X 0 . 0020 mg/1 PAP 03/07/03 2102
X 0. 0020 mg/1 PAP 03/07/03 2102
X 0 . 0020 mg/1 PAP 03/07 /03 2102
X 0 . 0020 mg/1 PAP 03/07/03 2102
X o. 0020 mg/1 PAP 03/07 /03 2102
X 0 .0020 mg/1 PAP 03/07/03 2102
0. 0020 mg/1 PAP 03/07/03 2102
X 0.0020 mg/1 PAP 03/07/03 2102
X 0. 0020 mg/1 PAP 03/07/03 2102
X 0. 0020 mg/1 PAP 03/07/03 2102
X 0. 0020 mg/1 PAP 03/07/03 2102
X 0 . 0020 mg/1 PAP 03/07/03 2102
o. 0040 mg/1 PAP 03/07/03 2102
25.0 mg/1 CLB 03/04/03 1021
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Davis&. Floyd, Jnc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone] I
100
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DAYIS
FLt1YD LABORATORY ANALYSIS REPORT
NELAC Certification Number: £87633
Client.
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
PEM CARTER
Client ID: PEW-4
Matrix
Para.meter
Semivolatile Organics
SW846 8270C
l,2,4-TRICHLOROBENZENE
1,2-DICHLOROBENZENE
1,3-DICHLOROBENZENE
1,4-DICHLOROBENZENE
2, 4, 5-TRICHLOROPHENOL
GW/Chemw
2, 4, 6-TRICHLOROPHENOL
2,4-DICHLOROPHENOL
2,4-DIMETHYLPHENOL
2,4-DINITROPHENOL
2,4-DINITROTOLUENE
2,6-DINITROTOLUENE
2-CHLORONAPHTHALENE
2-CHLOROPHENOL
2-METHYL-4,6-DINITROPHENOL
2-METHYLNAPHTHALENE
2-METHYLPHENOL
2-NITROANILINE
2-NITROPHENOL
3,3'-DICHLOROBENZIDINE
3-NITROANILINE
4-BROMOPHENYL PHENYL ETHER
4-CHLORO-3-METHYLPHENOL
4-CHLOROANILINE
4-CHLOROPHENYL PHENYL ETHER
4-METHYLPHENOL
4-NITROANILINE
4-NITROPHENOL
ACENAPHTHENE
ACENAPHTHYLENE
ANTHRACENE
BENZO(A)ANTHRACENE
BENZO (A) PYRENE
BENZO(B)FLUORANTHENE
BENZO(G,H,I)PERYLENE
BENZO(K)FLUORANTHENE
BENZOIC ACID
BENZYL ALCOHOL
BIS(2-CHLOROETHOXY)METHANE
BIS(2-CHLOROETHYL)ETHER
BIS(2-CHLOROISOPROPYL)ETHER
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
Result
0 . 010
0. 010
0.010
0 .010
o. 010
0 . 010
0. 010
0. 010
0 .025
0 .010
0. 010
0 .010
0 .010
0. 025
0 . 010
0 .010
0 .010
0 .010
0 . 010
0 .010
0 .010
0 .010
0 .010
0. 010
o. 010
o. 010
0 .025
0. 010
0 .010
0. 010
0 .010
0 .010
0 .010
0 .010
0 .010
0.050
0 .010
0 .010
0 .010
0 .010
Davis & Floyd, Inc. I PO Drawer 428 ! Greenwood, SC 29648 I 816 E. Durst Avenue
1 01
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 1 of 3
Sample ID
July 24, 2003
Report ID: AB12435
L03022703-11
Date Collected: 25-PEB-03 14:10
Date Received 26-FEB-03
Qual RDL Units Analyst Date
o . 010 mg/1 JRN 03/05/03
0. 010 mg/1 JRN 03/05/03
0. 010 mg/1 JRN 03/05/03
0 .010 mg/1 JRN 03/05/03
0 .010 mg/1 JRN 03/05/03
o . 010 mg/1 JRN 03/05/03
o. 010 mg/1 JRN 03/05/03
0 .010 mg/1 JRN 03/05/03
0 .025 mg/1 JRN 03/05/03
0 .010 mg/1 JRN 03/05/03
0 .010 mg/1 JRN 03/05/03
0 .010 Jll9/l JRN 03/05/03
0 .010 mg/1 JRN 03/05/03
0 .025 mg/1 JRN 03/05/03
0 . 010 mg/1 JRN 03/05/03
0 .010 mg/1 JRN 03/05/03
o. 010 mg/1 JRN 03/05/03
0 .010 mg/1 JRN 03/05/03
o . 010 mg/1 JRN 03/05/03
0. 010 mg/1 JRN 03/05/03
0 .010 mg/1 JRN 03/05/03
0 .010 mg/1 JRN 03/05/03
0 .010 mg/1 JRN 03/05/03
0 .010 mg/1 JRN 03/05/03
0 .010 mg/1 JRN 03/05/03
0 .010 mg/1 JRN 03/05/03
0.025 mg/1 JRN 03/05/03
0 .010 mg/1 JRN 03/05/03
0 .010 mg/1 JRN 03/05/03
0. 010 mg/1 JRN 03/05/03
0 .010 mg/1 JRN 03/05/03
0 .010 mg/1 JRN 03/05/03
o. 010 mg/1 JRN 03/05/03
0 .010 mg/1 JRN 03/05/03
0 .010 mg/1 JRN 03/05/03
0 .050 mg/1 JRN 03/05/03
0 .010 mg/1 JRN 03/05/03
0 .010 mg/1 JRN 03/05/03
0 .010 mg/1 JRN 03/05/03
0 .010 mg/1 JRN 03/05/03
Time
1240
1240
1240
1240
1240
1240
1240
1240
124 0
1240
1240
124 0
1240
1240
124 0
1240
1240
1240
1240
1240
12 4 0
124 0
124 0
124 0
1240
124 0
124 0
1240
1240
1240
1240
1240
124 0
1240
1240
1240
1240
1240
124 0
124 0
Greenwood, SC 29649 j {864) 229-4413 I Fax (864} 229-7119
DAYIS
FLMD LABORATORY ANALYSIS REPORT
NELAC Certification Number: £87633
Client
Contuct
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 19B
SHELBY, NC 28152
PEM CARTER
Client I~: PEW-4
Parameter
B1S(2-ETHYLHEXYL)PHTHALATE
BUTYL BENZYL PHTHALATE
CHRYSENE
D1-N-BUTYL PHTHALATE
DI-N-OCTYL PHTHALATE
DIBENZ (A, H) ANTHRACENE
DIBENZOFURAN
DIETHYL PHTHALATE
DIMETHYL PHTHALATE
FLUORANTHENE
FLUORENE
HEXACHLOROBENZENE
HEXACHLOROBUTAOIENE
HEXACHLOROCYCLOPENTADIENE
HEXACHLOROETHANE
INDENO(l,2,3-CD)PYRENE
ISOPHORONE
N-NITROSODI-N-PROPYLAMINE
N-NITROSODIPHENYLAMINE
NAPHTHALENE
NI TROBENZENE
PENTACHLOROPHENOL
PHENANTHRENE
PHENOL
PYRENE
SW846 8270C DOWTHERM
1, 1' -BI PHENYL
BIPHENYL ETHER
Volatile Organics
SW846 8260B
1,1,1-TRICHLOROETHANE
1,1,2,2-TETRACHLOROETHANE
1,~,2-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
1,2-DICHLOROETHANE
1,2-DICHLOROPROPANE
2-BUTANONE
2-HEXANONE
4-METHYL-2-PENTANONE
ACETONE
Result
< 0 .010
< 0 .010·
< o. 010
< 0 .010
< 0 .010
< 0.010
< 0 .010
< 0 .010
< 0 .010
< 0 .010
< 0.010
< 0 .010
< 0 .010
< 0. 010
< 0 . 010
< 0 .010
< 0 .010
< o. 010
< 0.010
< 0 .010
< 0 .010
< 0 . 025
< o. 010
< o. 010
< 0 .010
0.016
0.058
< 0 .0010
< 0 .0010
< o. 0010
< 0 .0010
< o. 0010
< 0.0010
< 0. 0010
< 0. 0050
< 0. 0050
< 0.0050
< 0.0050
NC Certification Number: 25
Project Number: 61621.01
Report Date July 24, 2003
Page 2 of 3 Report ID: AB12435
Sample ID L03022703-ll
Qual RDL units Analyst Date Time
0 .010 mg/1 JRN 03/05/03 1240
0 .010 mg/1 JRN 03/05/03 124 0
o. 010 mg/1 JRN 03/05/03 124 0
0 .010 mg/1 JRN 03/05/03 124 0
0 .010 mg/1 JRN 03/05/03 1240
0 .010 mg/1 JRN 03/05/03 1240
0 .010 mg/1 JRN 03/05/03 124 0
0 .010 mg/1 JRN 03/05/03 124 0
0 .010 mg/1 JRN 03/05/03 1240
0 .010 mg/1 JRN 03/05/03 124 0
0 .010 mg/1 JRN 03/05/03 1240
0 .010 mg/1 JRN 03/05/03 1240
0 .010 mg/1 JRN 03/05/03 1240
0.010 mg/1 JRN 03/05/03 124 0
0 . 010 mg/1 JRN 03/05/03 1240
0. 010 mg/1 JRN 03/05/03 124 0
0 .010 mg/1 JRN 03/05/03 124 0
0 .010 mg/1 JRN 03/05/03 1240
0.010 mg/1 JRN 03/05/03 1240
0 .010 mg/1 JRN 03/05/03 1240
0. 010 mg/1 JRN 03/05/03 124 0
0. 025 mg/1 JRN 03/05/03 1240
o. 010 mg/1 JRN 03/05/03 124 0
0.010 mg/1 JRN 03/05/03 1240
0. 010 mg/1 JRN 03/05/03 1240
0 .010 mg/1 JRN 03/05/03 1240
0 .010 mg/1 JRN 03/05/03 1240
0. 0010 mg/1 PAP 03/07/03 1800
o. 0010 mg/1 PAP 03/07/03 1800
0 .0010 mg/1 PAP 03/07/03 1800
0 .0010 mg/1 PAP 03/07/03 1800
0. 0010 mg/1 PAP 03/07/03 1800
0. 6010 mg/1 PAP 03/07/03 1800
o. 0010 mg/1 PAP 03/07/03 1800
0. 0050 mg/1 PAP 03/07/03 1800
0. 0050 mg/1 PAP 03/07/03 1800
o. 0050 mg/1 PAP 03/07/03 1800
0. 0050 mg/1 PAP 03/07/03 1800
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Davis & Floyd, Inc. I PO Drawer 428 J Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone] I
1 02
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DAYIS
FLtJ\1D LABORATORY ANALYSIS REPORT
NELA C Certification Number: E87633
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
PEM CARTER
Client ID: PEW-,
Parameter
BENZENE
BROMODICHLOROMETHANE
BROMOFORM
BROMOMETHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-0ICHLOROETHENE
CIS-1,3-DICHLOROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-DICHLOROETHENE
TRANS-I, 3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL)
Prep Procedure
Analytical Prep Procedures:
BNA SEMIVOLATILES
DOWTHERM
Method
SW846 35008
SW846 35008
Result
0.0040
< 0 . 0010
< 0 .0010
< 0. 0010
< 0. 0010
< 0.0010
< o. 0010
< 0 .0010
< 0 .0010
< 0 .0010
o. 039
< 0 . 0010
< 0 .0010
< 0 .0010
< 0 .0010
< 0 .0010
< 0 .0010
< 0. 0010
< o. 0010
< 0 .0010
< 0 .0010
< 0. 0010
< 0. 0010
< 0 . 0020
Analyst Prep Date
MCR 03/03/03
MCR 03/03/D3
NC Certification Number: 25
Project Number: 61621.01
Report Date ' July 24, 2003
Page 3 of 3 Report ID: AB12435
Sample ID L03022703-11
Qua1 RDL Units Analyst Date Time
0 .0010 mg/1 PAP 03/07/03 1B00
0. 0010 mg/1 PAP 03/07/03 1B00
0 . 0010 mg/1 PAP 03/07/03 1B00
0 . 0010 mg/1 PAP 03/07/03 1800
0 .0010 mg/1 PAP 03/07/03 1800
0 . 0010 mg/1 PAP 03/07/03 1B00
0 . 0010 mg/1 PAP 03/07/03 18 00
0. 0010 mg/1 PAP 03/07/03 18 00
0 .0010 mg/1 PAP 03/07/03 1800
0 . 0010 mg/1 PAP 03/07/03 1800
0 . 0010 mg/1 PAP 03/07/03 1800
0 .0010 mg/1 PAP 03/07/03 1800
0 . 0010 mg/1 PAP 03/07/03 1800
0 . 0010 mg/1 PAP 03/07/03 1800
0 .0010 mg/1 PAP 03/07/03 1800
0 .0010 mg/1 PAP 03/07/03 1800
0 . 0010 mg/1 PAP 03/07/03 1800
0 . 0010 mg/1 PAP 03/07/03 1800
0 . 0010 mg/1 PAP 03/07/03 1800
0.0010 mg/1 PAP 03/07/03 1800
0.0010 mg/1 PAP 03/07/03 1800
0.0010 mg/1 PAP 03/07/03 1800
0 . 0010 mg/1 PAP 03/07/03 1800
o. 0020 mg/1 PAP 03/07/03 1800
1000
1000
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 2964B I 816 C. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
103
DAYIS
FLOYD LABORATORY ANALYSIS REPORT
NELAC Cenification Number: £87633
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
PEM CARTER
Client ID: PBW-, DUP.
Matrix GW/ChemW
Parameter
Semivolatile Organics
SW846 8270C
1,2,4-TRICHLOROBENZENE
1,2-DICHLOROBENZENE
1,3-DICHLOROBENZENE
1,4-DICHLOROBENZENE
2,4,5-TRICHLOROPHENOL
2,4,6-TRICHLOROPHENOL
2,4-DICHLOROPHENOL
2,4-DIMETHYLPHENOL
2,4-DINITROPHENOL
2,4-DINITROTOLUENE
2,6-DINITROTOLUENE
2-CHLORONAPHTHALENE
2-CHLOROPHENOL
2-METHYL-4,6-DINITROPHENOL
2-METHYLNAPHTHALENE
2-METHYLPHENOL
2-NITROANILINE
2-NITROPHENOL
3,3'-DICHLOROBENZIDINE
3-NITROANILINE
4-BROMOPHENYL PHENYL ETHER
4-CHLOR0-3-METHYLPHENOL
4-CHLOROANIL!NE
4-CHLOROPHENYL PHENYL ETHER
4 -METHYLPHENOL
4-NITROANILINE
4-NITROPHENOL
ACENAPHTHENE
ACENAPHTHYLENE
ANTHRACENE
BENZO(A)ANTHRACENE
BENZO {A) PYRENE
BENZO(B)FLUORANTHENE
BENZO(G,H,I)PERYLENE
BENZO(K)FLUORANTHENE
BENZOIC ACID
BENZYL ALCOHOL
81S(2-CHLOROETHOXY)METHANE
81S(2-CHLOROETHYL)ETHER
81S(2-CHLOROISOPROPYL)ETHER
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I
Result
< 0.010
< 0.010
< 0 .010
< 0 .010
< 0 .010
< 0 .010
< 0 .010
< 0.010
< 0 .025
< 0 .010
< 0. 010
< 0 .010
< 0 .010
< 0 . 025
< 0 .010
< 0 .010
< 0. 010
< 0.010
< 0 .010
< o. 010
< 0 .010
< 0 .010
< 0 .010
< 0. 010
< 0 .010
< 0 .010
< 0 .025
< o. 010
< 0 .010
< 0 .010
< 0. 010
< 0. 010
< 0 .010
0. 010
0 .010
< 0 .050
< 0 .010
< 0. 010
< 0. 010
< 0. 010
NC Cenijication Number: 25
Project Number: 61621.01
Report Date ' Page 1 of 3
Sample ID
Date Collected:
Date Received
Qual RDL
0.010
0.010
0.010
0.010
0.010
o. 010
0. 010
0. 010
0.025
0. 010
0 .010
0. 010
o. 010
o. 025
o. 010
0.010
0. 010
0 .010
0 .010
o. 010
0. 010
0.010
0.010
0.010
0. 010
0 .010
0.025
o. 010
0 .010
o. 010
o. 010
o. 010
0 .010
0 .010
0 .010
0.050
0. 010
0.010
0.010
0.010
July 24, 2003
Report ID: AB12436
L03022703-12
25-FEB-03 14 :10
26-FEB-03
Units Analyst Date
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
JRN
JRN
JRN
JRN
JRN
JRN
JRN
JRN
JRN
JRN
JRN
JRN
JRN
JRN
JRN
JRN
JRN
JRN
JRN
JRN
JRN
JRN
JRN
JRN
JRN
JRN
JRN
JRN
JRN
JRN
JRN
JRN
JRN
JRN
JRN
JRN
JRN
JRN
JRN
JRN
03/05/03
03/05/03
03/05/03
03/05/03
03/05/03
03/05/03
03/05/03
03/05/03
03/05/03
03/05/03
03/05/03
03/05/03
03/05/03
03/05/03
03/05/03
03/05/03
03/05/03
03/05/03
03/05/03
03/05/03
03/05/03
03/05/03
03/05/03
03/05/03
03/05/03
03/05/03
03/05/03
03/05/03
03/05/03
03/05/03
03/05/03
03/05/03
03/05/03
03/05/03
03/05/03
03/05/03
03/05/03
03/05/03
03/05/03
03/05/03
Time
1326
1326
1326
1326
1326
1326
1326
1326
1326
1326
1326
1326
1326
1326
1326
1326
1326
1326
1326
1326
1326
1326
1326
1326
1326
1326
1326
1326
1326
1326
1326
1326
1326
1326
1326
1326
1326
1326
1326
1326
816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
104
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DAYIS
FLOYD LABORATORY ANALYSIS REPORT
NELAC Certification Number: £87633
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
PEM CARTER
Client ID: PEW-4 DUP.
Parameter
BIS(2-ETHYLHEXYL)PHTHALATE
BUTYL BENZYL PHTHALATE
CHRYSENE
DI-N-BUTYL PHTHALATE
DI-N-OCTYL PHTHALATE
DIBENZ(A,H)ANTHRACENE
DI BENZOFURAN
DIETHYL PHTHALATE
DIMETHYL PHTHALATE
FLUORANTHENE
FLUORENE
HEXACHLOROBENZENE
HEXACHLOROBUTADIENE
HEXACHLOROCYCLOPENTADIENE
HEXACHLOROETHAN"E
INDENO(l,2,3-CD)PYRENE
ISOPHORONE
N-NITROSODI-N-PROPYLAMINE
N-NITROSODIPHENYLAMINE
NAPHTHALENE
NITROBENZENE
PENTACHLOROPHENOL
PHENANTHRENE
PHENOL
PYRENE
SW846 8270C DOWTHERM
1, 1' -BI PHENYL
BI PHENYL ETHER
Volati~e Organics
SW846 8260B
1,1,1-TRICHLOROETHANE
1,1,2,2-TETRACHLOROETHANE
1,1,2-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
1,2-DICHLOROETHAN"E
1,2-DICHLOROPROPANE
2-BlITANONE
2 HEXANONE
4 METHYL-2-PENTANONE
ACETONE
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
Result
0 .010
0 .010
0 .010
0.010
0.010
0 .010
0 .010
o. 010
o. 010
0 . 010
0 .010
0 .010
0. 010
0. 010
o. 010
o. 010
0 .010
0. 010
o. 010
0. 010
0 .010
0 .025
0 .010
0 .010
o. 010
0.018
0.062
o. 0010
0 . 0010
0 .0010
0. 0010
0. 0010
0. 0010
0 . 0010
0 . 0050
0 . 0050
0 .0050
0 .0050
NC Cenijication Number: 25
Project Number: 61621.01
Report Date July 24, 2003
Page 2 of 3 Report ID: AB12436
sample ID L03022703-12
Qual RDL Units Analyst Date Time
0 .010 mg/1 JRN 03/05/03 1326
0. 010 mg/1 JRN 03/05/03 1326
0 .010 mg/1 JRN 03/05/03 1326
0 .010 mg/1 JRN 03/05/03 1326
0 .010 mg/1 JRN 03/05/03 1326
0 .010 mg/1 JRN 03/05/03 1326
0 .010 mg/1 JRN 03/05/03 1326
0 .010 mg/1 JRN 03/05/03 1326
0. 010 mg/1 JRN 03/05/03 1326
o . 010 mg/1 JRN 03/05/03 1326
0 .010 mg/1 JRN 03/05/03 1326
0 .010 mg/1 JRN 03/05/03 1326
0. 010 mg/1 JRN 03/05/03 1326
0. 010 mg/1 JRN 03/05/03 1326
0. 010 mg/1 JRN 03/05/03 1326
0.010 mg/1 JRN 03/05/03 1326
0 .010 mg/1 JRN 03/05/03 1326
0 .010 mg/1 JRN 03/05/03 1326
0. 010 mg/1 JRN 03/05/03 1326
0. 010 mg/1 JRN 03/05/03 1326
0. 010 mg/1 JRN 03/05/03 1326
0 . 025 mg/1 JRN 03/05/03 1326
0 .010 mg/1 JRN 03/05/03 1326
0 .010 mg/1 JRN 03/05/03 1326
o. 010 mg/1 JRN 03/05/03 1326
o. 010 mg/1 JRN 03/05/03 1326
0 .010 mg/1 JRN 03/05/03 1326
0. 0010 mg/1 PAP 03/07/03 1B22
o. 0010 mg/1 PAP 03/07/03 1B22
0 .0010 mg/1 PAP 03/07/03 1B22
0 .0010 mg/1 PAP 03/07/03 1B22
0 .0010 mg/1 PAP 03/07/03 1B22
0. 0010 mg/1 PAP 03/07/03 1B22
o. 0010 mg/1 PAP 03/07/03 1822
0 .0050 mg/1 PAP 03/07/03 1822
0 . 0050 mg/1 PAP 03/07/03 1822
0 .0050 mg/1 PAP 03/07/03 1822
0 .0050 mg/1 PAP 03/07/03 1822
Davis & Floyd, Inc. / PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I fax (864J 229-7119
1 05
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D~IS I
FL 1\1D LABORATORY ANALYSIS REPORT
I
NELA C Certification Number: £87633 NC Certification Number: 25
Client TICONA,LLC Project Number: 61621.01 I
2525 BLACKSBURG ROAD
HWY 198 I SHELBY, NC 28152 Report Date ' July 24, 2003
Contact PEM CARTER Page 3 of 3 Report ID: AB12436
Client ID: PEW-4 DUP. Sample ID L03022703¥12 I
Parameter Result Qual RDL Units Analyst Date Titnc
BENZENE 0.0040 0. 0010 mg/1 PAP 03/07/03 1822 I BROMODICHLOROMETHANE ' 0 .0010 0. 0010 mg/1 PAP 03/07/03 1822
BROMOFORM ' 0 .0010 0.0010 mg/1 PAP 03/07/03 1822
BROMOMETHANE ' 0. 0010 0. 0010 mg/1 PAP 03/07/03 1822 I CARBON DISULFIDE 0.0014 0. 0010 mg/1 PAP 03/07/03 1822
CARBON TETRACHLORIDE ' 0 . 0010 0 . 0010 mg/1 PAP 03/07/03 1822
CHLOROBENZENE ' 0 . 0010 o . 0010 mg/! PAP 03/07/03 1822
CHLOROETHANE ' 0. 0010 0 .0010 mg/1 PAP 03/07/03 1822 I CHLOROFORM ' 0.0010 0 .0010 mg/1 PAP 03/07/03 1822
CHLOROMETHANE ' 0.0010 0. 0010 mg/1 PAP 03/07/03 1822
CIS-1,2-DICHLOROETHENE 0.038 0. 0010 mg/1 PAP 03/07/03 1822 I CIS-1,3-DICHLOROPROPENE ' 0 . 0010 o . 0010 mg/1 PAP 03/07/03 1822
DIBROMOCHLOROMETHANE ' 0 . 0010 0 . 0010 mg/1 PAP 03/07/03 1822
ETHYLBENZENE ' 0. 0010 0. 0010 mg/1 PAP 03/07/03 1822
METHYLENE CHLORIDE 0.0027 0. 0010 mg/1 PAP 03/07/03 1822 I STYRENE ' 0 . 0010 0 . 0010 mg/1 PAP 03/07/03 1822
TETRACHLOROETHENE ' 0. 0010 o. 0010 mg/1 PAP 03/07/03 1822
TOLUENE ' 0. 0010 o. 0010 mg/1 PAP 03/07/03 1822
TRANS-1,2-DICHLOROETHENE ' 0 . 0010 0.0010 mg/1 PAP 03/07/03 1822 I TRANS-1,3-DICHLOROPROPENE ' o. 0010 0. 0010 mg/1 PAP 03/07/03 1822
TRICHLOROETHENE ' 0 . 0010 0 . 0010 mg/1 PAP 03/07/03 1822
VINYL ACETATE ' 0. 0010 0. 0010 mg/! PAP 03/07/03 1822 I VINYL CHLORIDE ' 0 .0010 0.0010 mg/! PAP 03/07/03 1822
XYLENE (TOTAL) ' 0. 0020 0.0020 mg/1 PAP 03/07/03 1822
Prep Procodure Method Analyst Prep Date I
Analytical Prep Procedures:
BNA SEMIVOLATILES SW846 3500B MCR 03/03/03 1000 I DOWTHERM SW846 3500B MCR 03/03/03 1000
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Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone] I,
106
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Di\YIS
FLOYD LABORATORY ANALYSIS REPORT
NELAC Cenification Number: £87633
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
PEM CARTER
Client rg, PRW-3
Matrix
Parameter
Semivolatile Organics
SW846 8270C
·1,2,4-TRICHLOROBENZENE
1,2-DICHLOROBENZENE
1,3-DICHLOROBENZENE
1,4-DICHLOROBENZENE
2,4,5-TRICHLOROPHENOL
2,4,6-TRICHLOROPHENOL
2,4-DICHLOROPHENOL
2,4-DIMETHYLPHENOL
2,4-DINITROPHENOL
2,4-DINITROTOLUENE
2,6-DINITROTOLUENE
2-CHLORONAPHTHALENE
2 -CHLOROPHENOL
2-METHYL-4,6-DINITROPHENOL
2-METHYLNAPHTHALENE
2-METHYLPHENOL
2-NITROANILINE
2-NITROPHENOL
3,3'-DICHLOROBENZIDINE
3-NITROANILINE
4-BROMOPHENYL PHENYL ETHER
4-CHLOR0-3-METHYLPHENOL
GW/Chemw
4 -CHLOROANILINE
4-CHLOROPHENYL PHENYL ETHER
4-METHYLPHENOL
4-NITROANILINE
4-NITROPHENOL
ACENAPHTHENE
ACENAPHTHYLENE
ANTHRACENE
BENZO(A)ANTHRACENE
BENZO{A)PYRENE
BENZO(B)FLUORANTHENE
BENZO(G,H,l)PERYLENE
BENZO(K)FLUORANTHENE
BENZOIC ACID
BENZYL ALCOHOL
BIS{2-CHLOROETHOXY}METHANE
BIS{2-CHLOROETHYL)ETHER
BIS(2-CHLOROISOPROPYL}ETHER
'
'
'
'
'
'
'
'
'
'
'
'
'
'
'
<
'
'
<
'
'
'
<
<
<
' <
'
'
<
<
<
'
<
Result
0. 010
0 .010
0 .010
0. 010
0 .010
0. 010
0 .010
o. 010
0 .025
0 .010
0 .010
0. 010
0 .010
o. 025
0 .010
0 . 010
0 .010
0 .010
0 .010
0. 010
0 .010
o. 010
0 .010
0. 010
0 .010
0.010
0. 025
0. 010
o. 010
0 . 010
0 .010
0 .010
0 .010
0 .010
0. 010
0. 050
0. 010
0 .010
0. 0 10
0 .010
Davis & Floyd, Inc. I PO Drilwer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue
107
NC Cenification Number: 25
Project Number: 61621.01
Report Date July 24, 2003
Page 1 of 3 Report ID: AB12437
sample ID L03022703-13
Date Collected: 25-FEB-03 14 :45
Date Received 26-FEB-03
Qual RDL Units Analyst Date Time
0 .010 mg/1 JRN 03/05/03 1411
o. 010 mg/1 JRN 03/05/03 1411
0 .010 mg/1 JRN 03/05/03 1411
0. 010 mg/1 JRN 03/05/03 1411
0 .010 mg/1 JRN 03/05/03 1411
0 .010 mg/1 JRN 03/05/03 1411
0 .010 mg/1 JRN 03/05/03 1411
o. 010 mg/1 JRN 03/05/03 1411
0. 025 mg/1 JRN 03/05/03 1411
0 .010 mg/1 JRN 03/05/03 1411
0.010 mg/1 JRN 03/05/03 1411
0 .010 mg/1 JRN 03/05/03 1411
0 .010 mg/1 JRN 03/05/03 1411
0. 025 mg/1 JRN 03/05/03 1411
0. 010 mg/1 JRN 03/05/03 1411
0 . 010 mg/1 JRN 03/05/03 1411
0. 010 mg/1 JRN 03/05/03 1411
0.010 mg/1 JRN 03/05/03 1411
0.010 mg/1 JRN 03/05/03 1411
0 .010 mg/1 JRN 03/05/03 Hll
0 .010 mg/1 JRN 03/05/03 1411
0. 010 mg/1 JRN 03/05/03 1411
o. 010 mg/1 JRN 03/05/03 1411
o. 010 mg/1 JRN 03/05/03 1411
0.010 mg/1 JRN 03/05/03 1411
0. 010 mg/1 JRN 03/05/03 1411
o. 025 mg/1 JRN 03/05/03 1411
0. 010 mg/1 JRN 03/05/03 1411
0. 010 mg/1 JRN 03/05/03 1411
o . 010 mg/1 JRN 03/05/03 1411
0. 010 mg/1 JRN 03/05/03 1411
0. 010 mg/1 JRN 03/05/03 1411
0 .010 mg/1 JRN 03/05/03 1411
0 .010 mg/1 JRN 03/05/03 1411
0.010 mg/1 JRN 03/05/03 1411
0 .050 mg/1 JRN 03/05/03 1411
0 .010 mg/1 JRN 03/05/03 1411
0 .010 mg/1 JRN 03/05/03 1411
0. 010 mg/1 JRN 03/05/03 1411
0. 010 mg/1 JRN 03/05/03 1411
Greenwood, SC 2%49 I [phone] I Fax [phone]
DAYIS
FLtwD LABORATORY ANALYSIS REPORT
NELAC Certification Number: £87633
Client
Contact
Parameter
BIS(2-ETHYLHEXYL)PHTHALATE
BUTYL BENZYL PHTHALATE
CHRYSENE
DI-N-BUTYL PHTHALATE
DI-N-OCTYL PHTHALATE
DIBENZ(A,H)ANTHRACENE
DIBENZOFURAN
DIETHYL PHTHALATE
DIMETHYL PHTHALATE
FLUORANTHENE
FLUORENE
HEXACHLOROBENZENE
HEXACHLOROBlITADIENE
HEXACHLOROCYCLOPENTADIENE
HEXACHLOROETHANE
INDENO(l,2,3-CD)PYRENE
ISOPHORONE
N-NITROSODI-N-PROPYLAMINE
N-NITROSODIPHENYLAMINE
NAPHTHALENE
NITROBENZENE
PENTACHLOROPHENOL
PHENANTHRENE
PHENOL
PYRENE
SW846 8270C DOWTHERM
1,1'-BIPHENYL
Bl PHENYL ETHER
Volatile Organics
SW846 8260B
1,1, 1-TRICHLOROETHAN"E
1,1,2,2-TETRACHLOROETHANE
1,1,2-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
1,2-DICHLOROETHANE
1,2-DICHLOROPROPANE
2-BUTM/ONE
2-HEXANONE
4-METHYL-2-PENTMIONE
ACETONE
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
PEM CARTER
Result
' 0 .010
' 0 .010
' 0 .010
' 0 .010
' 0 .010
' 0 .010
' 0 .010
' o. 010
' 0. 010
' 0 .010
' 0. 010
' 0. 010
' 0 .010
' 0. 010
' 0. 010
' 0.010
' 0 .010
' 0 .010
' 0 .010
' 0 .010
' 0 .010
' 0 .025
' 0.010
' 0 .010
' 0 .010
' 0.010
' 0.010
' 0 .0010
' 0 .0010
' 0 .0010
' 0 . 0010
' 0 .0010
' 0 .0010
' 0 . 0010
' 0 .0050
' o. 0050
' 0 .0050
' 0 .0050
NC Certification Number: 25
Project Number: 61621.01
Report Date ' July 24, 2003
Page 2 of 3 Report ID: AB12437
Sample ID L03022703-13
Qual RDL Units Analyst Date Time
0 .010 mg/1 JRN 03/05/03 1411
0 .010 mg/1 JRN 03/05/03 1411
0 .010 mg/1 JRN 03/05/03 1411
0. 010 mg/1 JRN 03/05/03 1411
0 .010 mg/1 JRN 03/05/03 1411
0 .010 mg/1 JRN 03/05/03 1411
0 .010 mg/1 JRN 03/05/03 1411
o. 010 mg/1 JRN 03/05/03 1411
o. 010 mg/1 JRN 03/05/03 1411
0.010 mg/1 JRN 03/05/03 1411
0. 010 mg/1 JRN 03/05/03 1411
0. 010 mg/1 JRN 03/05/03 141]
0. 010 mg/1 JRN 03/05/03 14 l l
0. 010 mg/1 JRN 03/05/03 1411
0. 010 mg/1 JRN 03/_o5/03 1411
0 .010 mg/1 JRN 03/05/03 1411
0 .010 mg/1 JRN 03/05/03 1411
o. 010 mg/1 JRN 03/05/03 1411
o. 010 mg/1 JRN 03/05/03 1411
0 .010 mg/1 JRN 03/05/03 1411
0.010 mg/1 JRN 03/05/03 1411
0.025 mg/1 JRN 03/05/03 1411
0.010 mg/1 JRN 03/05/03 1411
0. 010 mg/1 JRN 03/05/03 1411
0 .010 mg/1 JRN 03/05/03 1411
o. 010 mg/1 JRN 03/05/03 1411
o. 010 mg/1 JRN 03/05/03 1411
0.0010 mg/1 PAP 03/07/03 1845
0.0010 mg/1 PAP 03/07/03 1845
0. 0010 mg/1 PAP 03/07/03 1845
o. 0010 mg/1 PAP 03/07/03 1845
0 .0010 mg/1 PAP 03/07/03 1845
o. 0010 mg/1 PAP 03/07/03 1845
o. 0010 mg/1 PAP 03/07/03 1845
o. 0050 mg/1 PAP 03/07/03 1845
o. 0050 mg/1 PAP 03/07/03 1845
0. 0050 mg/1 PAP 03/07/03 1845
0 .0050 mg/1 PAP 03/07/03 1845
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Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 F1 o"s" Avenue I Greenwood, SC 29649 I (864) 22'1-4413 I Fax /864) 229-7119 I
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D1\VIS
FLOYD LABORATORY ANALYSIS REPORT
NELA C Certification Number: £87633
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
PEM CARTER
Client ID: PEW-3
Par8l!leter
BENZENE
BROMODICHLOROMETHANE
BROMOFORM
BROMOMETHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLO RO ETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-DICHLOROETHENE
CIS-1,3-DICHLOROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-DICHLOROETHENE
TRANS-1,3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL}
Prep Procedure
Analytical Prep Procedures:
BNA SEMIVOLATILES
OOWTHERM
Method
SW846 3500B
SW846 35008
Result
< 0. 0010
< 0 .0010
< 0.0010
< 0.0010
0.0023
< o. 0010
< o. 0010
< o. 0010
< o. 0010
< o. 0010
< 0 .0010
< o. 0010
< o. 0010
< o. 0010
0.0023
< 0.0010
< 0 .0010
< 0 .0010
< 0 . 0010
< 0. 0010
< o. 0010
< 0 .0010
< 0 .0010
< 0. 0020
Analyst Prep Date
MCR 03/03/03
MCR 03/03/03
NC Certification Number: 25
Project Number: 61621.0l
Report Date July 24, 2003
Page 3 of 3 Report ID: AB12437
Sample ID L03022703-13
Qual RDL Units Analyst Date Time
0. 0010 mg/1 PAP 03/07/03 1845
0 . 0010 mg/1 PAP 03/07/03 1845
0 .0010 mg/1 PAP 03/07/03 1845
0 . 0010 mg/1 PAP 03/07/03 1845
0 . 0010 mg/1 PAP 03/07/03 1845
0 . 0010 mg/1 PAP 03/07/03 1845
o. 0010 mg/1 PAP 03/07/03 1845
o. 0010 mg/1 PAP 03/07/03 1845
0. 0010 mg/1 PAP 03/07/03 1845
0. 0010 mg/1 PAP 03/07/03 01845
0 . 0010 mg/1 PAP 03/07/03 1845
0 .0010 mg/1 PAP 03/07/03 1845
o. 0010 mg/1 PAP 03/07/03 1845
0. 0010 mg/1 PAP 03/07/03 1845
0 .0010 mg/1 PAP 03/07/03 184 5
0 . 0010 mg/1 PAP 03/07/03 1845
0 . 0010 mg/1 PAP 03/07/03 1845
0 . 0010 mg/1 PAP 03/07/03 1845
0 .0010 mg/1 PAP 03/07/03 1845
0 .0010 mg/1 PAP 03/07/03 1845
o. 0010 mg/1 PAP 03/07/03 1845
0 . 0010 mg/1 PAP 03/07/03 1845
0 . 0010 mg/1 PAP 03/07/03 1845
0 . 0020 mg/1 PAP 03/07 /03 1845
1000
1000
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax {864) 229-7119
109
DAYIS
FLOYD LABORATORY ANALYSIS REPORT
NELAC Certification Number: E87633
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
PEM CARTER
Client ID, TRIP BLANK #1
Matrix
Parameter
Volatile Organics
SW846 8260B
1,1,1-TRICHLOROETHANE
1,1,2,2-TETRACHLOROETHANE
1,1,2-TRICHLOROETHANE
1,1-DICHLOROETI-tANE
1, 1-0ICHLORO~.~NE
1,2-DICHLOROETHANE
1,2-DICHLOROPROPANE
2-BUTANONE
2-HEXANONE
4-METHYL-2-PENTANONE
ACETONE
BENZENE
BROMODICHLOROMETHANE
BROMOFORM
BROMOMETHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-DICHLOROETHENE
CIS-1,3-DICHLOROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-DICHLOROETHENE
TRANS-1,3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL)
GW/ChemW
Result
< 0. 0010
< 0.0010
< 0 .0010
< 0 .0010
< 0. 0010
< 0. 0010
< 0 .0010
< 0. 0050
< 0. 0050
< o. 0050
< o. 0050
< 0. 0010
< o. 0010
< 0 .0010
< 0 .0010
< 0 . 0010
< 0. 0010
< o. 0010
< 0 . 0010
< 0 .0010
< 0. 0010
< 0 .0010
< o. 0010
< 0 .0010
0 .0010
< 0 .0010
o. 0010
< 0 .0010
< o. 0010
< o. 0010
< 0 . 0010
< 0 . 0010
< 0 . 0010
< 0. 0010
< 0. 0020
NC Certification Number: 25
Project Number: 61621.01
Report Date July 24, 2003
Page 1 of 1 Report ID: AB12438
Sample ID L03022703-14
Date Collected: 13-FEB-03 09 : 30
Date Received ' 26-FEB-03
Qual RDL Units Analyst Date Time
0. 0010 mg/1 PAP 03/07/03 1317
0 .0010 mg/1 PAP 03/07/03 1317
0 . 0010 mg/1 PAP 03/07/03 1317
0.0010 mg/1 PAP 03/07/03 1317
0.0010 mg/1 PAP 03/07/03 1317
0 .0010 mg/1 PAP 03/07/03 1317
0. 0010 mg/1 PAP 03/07/03 1317
o. 0050 mg/1 PAP 03/07/03 1317
0. 0050 mg/1 PAP 03/07/03 1317
0. 0050 mg/1 PAP 03/07/03 1317
0. 0050 mg/1 PAP 03/07/03 1317
0 .0010 mg/1 PAP 03/07/03 1317
0 .0010 mg/1 PAP 03/07/03 1317
0 .0010 mg/1 PAP 03/07/03 1317
0 .0010 mg/1 PAP 03/07/03 1317
0 .0010 mg/1 PAP 03/07/03 1317
0 .0010 mg/1 PAP 03/07/03 1317
0. 0010 mg/1 PAP 03/07 /03 1317
0. 0010 mg/1 PAP 03/07/03 1317
0.0010 mg/1 PAP 03/07/03 1317
0. 0010 mg/1 PAP 03/07/03 1317
0 .0010 mg/1 PAP 03/07/03 1317
o. 0010 mg/1 PAP 03/07/03 1317
0. 0010 mg/1 PAP 03/07/03 1317
0. 0010 mg/1 PAP 03/07/03 1317
0 .0010 mg/1 PAP 03/07/03 1317
0 .0010 mg/1 PAP 03/07/03 1317
0. 0010 mg/1 PAP 03/07/03 1317
0 . 0010 mg/1 PAP 03/07/03 1317
0 .0010 mg/1 PAP 03/07/03 1317
0 .0010 mg/1 PAP 03/07/03 1317
0 . 0010 mg/1 PAP 03/07/03 1317
0 .0010 mg/1 PAP 03/07/03 1317
o. 0010 mg/1 PAP 03/07/03 1317
0. 0020 mg/1 PAP 03/07 /03 1317
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Davis & Floyd, Jnc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I F.1x (864) 229-71191
1 1 0
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Di\YIS
FLiWD LABORATORY ANALYSIS REPORT
NELA C Cenification Number: £87633
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
PEM CARTER
Client ID: TRIP BLANK #2
Matrix
Parameter
Volatile Organics
SW846 8260B
1,1,1-TRICHLOROETHANE
1,1,2,2-TETRACHLOROETHANE
1,1,2-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
1,2-DICHLOROETHANE
1,2-DICHLOROPROPANE
2-BUTANONE
2-HEXANONE
4-METHYL-2-PENTANONE
ACETONE
BENZENE
BROMODICHLOROMETHANE
BROMOFORM
BROMOMETHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-DICHLOROETHENE
CIS-1,3-DICHLOROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-DICHLOROETHENE
TRANS-1,3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL}
GW/Chemw
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
Result
0 . 0010
0 .0010
0. 0010
0. 0010
0 .0010
0 . 0010
0 .0010
0. 0050
0 .0050
0. 0050
o. 0050
0 .0010
0. 0010
0. 0010
0 .0010
0 .0010
0. 0010
o. 0010
0 .0010
0 .0010
0 . 0010
0. 0010
0 .0010
o. 0010
0. 0010
0. 0010
0. 0010
o. 0010
0. 0010
0. 0010
o. 0010
0. 0010
o. 0010
0 . 0010
0. 0020
NC Certification Number: 25
Project Number, 61621.01
Report Date July 24, 2003
Page 1 of 1 Report ID: AB12439
Sample 1D L03022703-15
Date Collected, 13-FEB-03 09: 30
Date Received 26-FEB-03
Qual RDL Units Analyst Date Time
0 .0010 mg/1 PAP 03/07/03 1340
0 .0010 mg/1 PAP 03/07/03 1340
0. 0010 mg/1 PAP 03/07/03 1340
0. 0010 mg/1 PAP 03/07/03 1340
0 .0010 mg/1 PAP 03/07/03 1340
0 .0010 mg/1 PAP 03/07/03 1340
0 .0010 mg/1 PAP 03/07/03 1340
0 . 0050 mg/1 PAP 03/07/03 1340
0. 0050 mg/1 PAP 03/07/03 1340
0. 0050 mg/1 PAP 03/07/03 1340
0 .0050 mg/1 PAP 03/07/03 1340
0 .0010 mg/1 PAP 03/07 /03 1340
0.0010 mg/1 PAP 03/07/03 1340
0. 0010 mg/1 PAP 03/07/03 1340
0 .0010 mg/1 PAP 03/07/03 1340
0. 0010 mg/1 PAP 03/07/03 1340
0. 0010 mg/1 PAP 03/07/03 134 0
0. 0010 mg/1 PAP 03/07/03 134 0
0 .0010 mg/1 PAP 03/07/03 1340
0 .0010 mg/1 PAP 03/07/03 1340
0 .0010 mg/1 PAP 03/07/03 134 0
0. 0010 mg/1 PAP 03/07/03 1340
0. 0010 mg/1 PAP 03/07/03 1340
0 .0010 mg/1 PAP 03/07/03 1340
0 .0010 mg/1 PAP 03/07/03 1340
0 .0010 mg/1 PAP 03/07/03 134 0
0 .0010 mg/1 PAP 03/07/03 1340
0 . 0010 mg/1 PAP 03/07/03 1340
0 . 0010 mg/1 PAP 03/07/03 1340
0. 0010 mg/1 PAP 03/07/03 1340
0 .0010 mg/1 PAP 03/07/03 134 0
0 .0010 mg/1 PAP 03/07/03 1340
0. o'o10 mg/1 PAP 03/07/03 1340
0 .0010 mg/1 PAP 03/07/03 1340
0 . 0020 mg/1 PAP 03/07 /03 1340
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue / Greenwood, SC 29649 I [phone] I Fax [phone]
111
DAYIS
FLfilD LABORATORY ANALYSIS REPORT
NELAC Cenification Number: £87633
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
PEM CARTER
Client ID: TRIP BLANK #3
Matrix
Parameter
Volatile Organics
SW846 8260B
1,1,1-TRICHLOROETHANE
1,1,2,2-TETRACHLOROETHANE
1,1,2-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
1,2-DICHLOROETHANE
1,2-DICHLOROPROPANE
2-BUTANONE
2-HEXANONE
4-METHYL-2-PENTANONE
ACETONE
BENZENE
BROMODICHLOROMETHANE
BROMOFORM
BR0M0METHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-DICHLOROETHENE
CIS-1,3-DICHLOROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-DICHLOROETHENE
TRANS-1,3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL)
GW/ChemW
Result
' 0.0010
' 0.0010
' 0.0010
' 0 . 0010
' 0 . 0010
' 0 . 0010
' 0. 0010
0 .0050
' 0 . 0050
' 0. 0050
' 0. 0050
' 0 . 0010
' 0.0010
' 0.0010
' 0 . 0010
0 . 0010
' 0 . 0010
' 0 .0010
' 0. 0010
' 0.0010
' 0 . 0010
' 0 . 0010
' 0 . 0010
o. 0010
o. 0010
' 0 .0010
' 0 .0010
' 0 . 0010
' 0 . 0010
' 0. 0010
' 0 . 0010
' 0 .0010
' 0. 0010
0 .0010
' 0 .0020
NC Cenification Number: 25
Project Number, 61621.01
Report Date
Page 1 of 1
Sample ID
July 24, 2003
Report ID: AB12440
L03022703-16
Date Collected: 13-FEB-03 09:30
Date Received
Qual RDL Units Analyst Date
0.0010 mg/1 PAP 03/07/03
0.0010 mg/1 PAP 03/07/03
0.0010 mg/1 PAP 03/07/03
0.0010 mg/1 PAP 03/07/03
0.0010 mg/1 PAP 03/07/03
0.0010 mg/1 PAP 03/07/03
0.0010 mg/1 PAP 03/07/03
0 .0050 mg/1 PAP 03/07/03
0 . 0050 mg/1 PAP 03/07/03
0 .0050 mg/1 PAP 03/07/03
0.0050 mg/1 PAP 03/07/03
0 . 0010 mg/1 PAP 03/07/03
o. 0010 mg/1 PAP 03/07/03
0. 0010 mg/1 PAP 03/07/03
0.0010 mg/1 PAP 03/07/03
0 . 0010 mg/1 PAP 03/07/03
0 .0010 mg/1 PAP 03/07/03
0 .0010 mg/1 PAP 03/07/03
0. 0010 mg/1 PAP 03/07/03
0. 0010 mg/1 PAP 03/07/03
o . 0010 mg/1 PAP 03/07/03
0 . 0010 mg/1 PAP 03/07/03
0.0010 mg/1 PAP 03/07/03
0. 0010 mg/1 PAP 03/07/03
0 . 0010 mg/1 PAP 03/07/03
0.0010 mg/1 PAP 03/07/03
0.0010 mg/1 PAP 03/07/03
0.0010 mg/1 PAP 03/07/03
0 . 0010 mg/1 PAP 03/07/03
o. 0010 mg/1 PAP 03/07/03
o . 0010 mg/1 PAP 03/07/03
0 . 0010 mg/1 PAP 03/07/03
o. 0010 mg/1 PAP 03/07/03
o. 0010 mg/1 PAP 03/07/03
0 . 0020 mg/1 PAP 03/07/03
Time
1403
1403
1403
1403
1403
14 03
1403
1403
1403
14 03
14 03
14 03
14 03
14 03
14 03
14 03
14 03
1403
1403
1403
1403
1403
14 03
1403
14 03
14 03
14 03
1403
1403
1403
1403
14 03
14 03
14 03
1403
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Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 J [phone] I Fax [phone] I
112,
--

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---------

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Page-l-of _
I .
FL YD ...........i•Lunl<ry""'"' Chain of Custody Record -
c.;Jient Project I Sile Location 816 E. Durst Avenue, Greenwood, SC 29649 (864)229,-4413 Fax:[phone] ceu,.
Kubal..furr & Associates 61621.01 Laboratory CertitcaDon Numbers: SC -24110, NC -25, TN-2923, VA-77
' Contact Ref£rl To Copy To Reporting Requirements: [} Standani { } Data Package (Sp&Cify Lei nirchase Order
Julie Lisenby G--'1 C,ii17c.rl · 1/C ON A JVLt<c L,-re?.Jj!--, -/:"?.YA-Le,-<:'Z-;,-.-J"fe7.Jf-rK ofl.'ti.,,z... 2 -~Io-.
Colle<ted By (J9tz,--,:;,.£},/;t,,) Requi,ed Parameters, Containers end Preservatives Slalo '-luote
~drueW,11 2 ,n p«;ial Instructions
NOTICE: u e ' ,., ~ 1 m ~ . ~ • ~ II J~ -s: C ~ I )ii '-"' <;
-~g C ~ ~ 0 ~ ,\J Il C.. " E .-::: -~ 0 ~ ~ 8. 0 X t ~ <::) ~ ~ ~ ~ ~ ½ • E E :s E ,_.
Sample Collection E o 0 .~ • , ;_-.::!. " " z ...J
Sarni le Description Date Time Time Type Total !Fraction HOT .... ommems
1£ -''7 f)/)-41.J I 1)0 3 X 01 l<"~,---i.i~
'P / I/-) -'-I. 13;20 3 X IJ~ ofll\c«'" ;Jr-(V°ti 'T
c-~ q lit./1 ~ 3 x· 03
Ec-S"~ /t,:J.o :, X 01/-
/.,-;. ~ -to I ., /[.3o 3 X (J!S
A1 -51 J.hrLJ d-'lo .3 X (}I,
:::i_sg, ltJJ.o 3 >< ()1
~-:ix /13~ y X Of
V-:J.3 t3o< X X 11/J
r't;'wl-'{ !t/10 X X X ti
fEW-i/-!)i.1( 1'{10 X X x I').,
V-:J3-1)v? 136.;( x X ~.:~ .... /0
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'17'1P '(;;U";-Jt:.~J-i:J.}i:;/,_~ 09'3o X I IL
/7 I./ /,
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Time
Rel~ /.4_/~
Date Time Reliquished By Date r,,.,. _o~~t SAf~
/Jou 1718 y N 0... CUEN?
?-Z t'-<> l """'
r;;; . ?'(/J( I.Pate Time 'r'ceivedBy Date T,me Ti;: Lni."7Jf /2,1/; fl:
Date T,me NY, s : AJIDil/Number
J, r, • ;-;:, z >'6,/4} I ?.?,i,.03 I ZC,{) 1~1.1-f ---..,..
(; "" -ieoolerlD~o):
Onlce, Yu T-C)~
Custody Seal: lntaa / Broun
Matrtx Type Definitions 1 •Drinking Water 2 -Clean Water 5 -Groundwater 7 • Soll/$ed1menl 8 -Uquid Sludge 9 -Od 12 -/>Jr Davtl & Floyd. Inc.
... ____ _..__ ~----. -"' _........,. g. i..i?c:.ru r.. 1-irJ O. HN03 E. NaOH F. Filtered G -Other FU1Z_01 (02M)
Df\YIS
FLm'D LABORATORY ANALYSIS REPORT
Method Conformance Summary
Client: Ticona, LLC
Log;n(s): L0J02240J, L0J02270J
Criteria Volatiles
Samole !-!oldine,Time
Standards Preparation
Instrument Tuninrr
Instrument Calibration
Calibration Verification
Degradation Check
Interference
SamnlelStandard
Blanks Results
Method Accuracy
Method Precision
Surroe:ate Recoverv
PDSISD/MSA
TCLP Preoaration
✓
NIA
Met Criteria Met
Not Applicable
✓
✓
✓
✓
✓
NIA
NIA
✓
•
✓
✓
NIA
NIA
Semi
Volatiles
✓
✓
✓
✓
✓
NIA
NIA
✓
✓
✓
✓
NIA
NIA
Metals
NIA
NIA
NIA
NIA
NIA
NIA
NIA
NIA
NIA
NIA
NIA
NIA
NIA
*
PDS =
SD =
MSA=
Method Criteria Not Met -See footnote(s) below.
Post Digestion Spike
Serial Dilution
Method of Standard Additions
Project Number: 61621.0l
Report Date: March 17. 2003
Ethylene
TOC Glycol
✓ ✓
✓ ✓
NIA NIA
✓ ✓
✓ ✓
NIA NIA
NIA NIA
✓ ✓
✓ ✓
✓ ✓
NIA NIA
NIA NIA
NIA NIA
Footnotes: Volatiles-1,2-Dichloroethane, carbon tetrachloride and chloroform recovered high
Prepared by:
in the MS, MSD and LCS for workgroup 33287.
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Davis & Floyd, Inc I PO Drawer 428 1 Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I t864) 229-4413 I Fax [phone]l l9 I
11 4
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DAYIS
FLtlYD LABORATORY ANALYSIS REPORT
NELA C Certification Number: £87633
Master Tracking List
Client
Contact
Sill!lple ID
LO3O224O3-Ol
Volatile Organics
SWB46 8260B
LOJ02240J-02
Volatile Organics
SWB46 8260B
L0302H03-03
Volatile Organics
SW846 8260B
LO3O22403-O4
Volatile Organics
SW8~6 8260B
L0302H03-05
Gas Chromatography
SW846 8015
Volatile Organics
SW846 8260B
Wet Ch~stry
SW846 9060
Gas Chromatography
SW846 8015
Volatile Organic&
SW846 8260B
Wet Chemistry
SW84.6 9060
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
PEM CARTER
Client ID
CC-33
FF-62
FF-34
'ITCI
NC Certification Number: 25
?reject Number: 61621.01
Report Date
Page 1 of 3
March 17, 2003
Report ID: AB4757
Date Collected Date Received
20-FEB-03 15:40
02/24/03 160 9
21-FEB-03 09: 38 21-FEB-03
02/24/03 163]
21-FEB-03 10:42 21-FEB-03
02/24/03 1654
:21-FBB-03 12:35 21-FEB-03
02/24/03 1717
21-FEB-03 13:10 21-FEB-03
02/25/03 0953
02/24/03 1825
02/27/03 1118
21-FEB-03 13:15 21-FBB-03
02/25/03 1018
02/24/03 18-48
02/26/03 2150
Davis & Floyd, Inc. I PO Draw.er 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] 1 Fax [phone] l 9
115
Di\YIS
FLt5YD
NELAC Cenificatio11 Number: £87633
LABORATORY ANALYSIS REPORT
NC Cenification Number: 25
Master Tracking List
Client TICONA,LLC Project Number: 61621.01
2525 BLACKSBURG ROAD
HWY 19B
Contact
SaJl!Ple ID
L03022"03-07
Gas Chromatography
SW846 8015
Volatile Organics
SW846 8260B
Wet Chemistry
SW846 9060
L03022403-0B
Semivolatile Organics
SW846 8270C DOWTHERM
Volatile Organics
SW846 8260B
L03022t03-09
Semi.volatile Organics
SW846 8270C DOWTHERM
Volatile Organics
SW846 8260B
L03022403-10
Volatile Organica
SW846 8260B
SHELBY, NC 28152
PEM CARTER
Client ID
ITCI DUP.
BLANK #1
BLANK #2
r J
TRIP BLANX
L0302240l-11 D-B8
Semi.volatile Organic•
SW846 8270C DOWTHERM
L03022403-12 D-56
Semivolatile organic•
SW846 8270C DOWTHERM
Report Date
Page 2 of 3
March 17, 2003
Report ID: AB4757
Date Collected Date Received
21-FEB-03 13: 15
02/25/03 1044
02/24/03 1911
02/26/03 2223
20-FEB-03 11:30 21-FEB-03
0,2/26/03 0800 02/27/03 1146
02/24/03 1546
21-PBB-03 12:30 21-FEB-03
02/26/03 0800 02/27/03 1225
02/24/03 1523
12-FBB-03 09:30 21-l"EB-03
02/24/03 1500
20-PZB-03 12155 21-FBB-03
02/26/03 0800 02/27/03 1304
20-1'1:B-03 14100 21-PBB-03
02/26/03 0800 02/27/03 1342
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Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 l 816 E. Durst Avenue
116
I Greenwood, SC 29649 I [phone] 1 Fax [phone] I
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DAYIS
FLo\'D LABORATORY ANALYSIS REPORT
NELAC Certification Number: £87633 NC Certijica1ion Number: 25
Master Tracking List
Client
Contact
Sample ID
L030224.03-13
Semivolatile Organics
SW846 B270C DOWTHERM
L03022403-U
Semivolatile Organics
SW846 8270C DOWTHERM
TICONA,LLC
2525 BLACKSBURG ROAD
!!WY 198
SHELBY, NC 2815?.
PEM CARTER
Client ID
Project Number: 61621.01
Report Date
Page 3 of 3
Date Collected
20-FEB-03 17:20
March 17, 2003
Report ID: AB4757
Date Received
21-P'EB-0J
02/26/03 0800 02/27/03 1422
20-FEB-03 18:20
02/26/03 0800 02/27/03 1501
Davis & Floyd, Inc. I PO Ora...:Ver 428 ! Greenwood, SC 29648 ] 816 £. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
11 7
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DAYIS
FLtJ\1D LABORATORY ANALYSIS REPORT I
NEI.AC Certification Number: £87633
Master Tracking List
Client
Contact
Sample ID
L03022703-0l
Volatile Organics
SW846 8260B
L03022703-02
Volatile Organics
SW846 8260B
L03022703-03
Volatile Organics
SW846 8260B
L03022703-04
Volatile Organics
SW846 8260B
L03022703-05
Volatile Organics
SW846 82608
LOJ022703-06
Volatile Organics
SW846 8260B
L03022703-07
Volatile Organics
SW846 8260B
L03022703-08
Volatile Organics
SW846 8260B
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
PEM CARTER
Client ID
C-49
EE-58
GG-61
AA-54
P-58
K-28
NC Certification Number: 25
Project Number: 61621.0l
Report Date
Page 1 of 3
July 24, 2003
Report ID: AB12424
Date Collected Date Received
24-PEB-03 12:20 26-FEB-03
03/07/03 1426
24-FEB-03 13:20 26-FEB-03
03/07/03 1449
24-PEB-03 14:28 26-PEB-03
03/07/03 1512
24-l'EB-03 16:20 26-l!'EB-03
03/07/03 1535
03/07/03 1557
03/07/03 1255
26-P'EB-03
03/07/03 1620
25-FEB-03 11:35 26-FEB-03
03/07/03 2125
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 ) [phone] I
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D1\VIS
FLMD LABORATORY ANALYSIS REPORT
NELA C Certification Number: £87633
Master Tracking List
Client TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Contact.: PEM CARTER
Sample ID
Wet Chemistry
SWB46 9060
L03022703-09
Volatile Organics
SW846 8260B
Wet Chemistry
SW846 9060
L03022703-l0
Volatile Organics
SW846 8260B
Wet Chemistry
SW846 9060
L03022703-ll
Semi volatile Organics
SW846 8270C
SW846 8270C DOWTHERM
Volatile Organics
SW846 8260B
L03022703-l2
Semi volatile Organics
SW846 8270C
SW846 8270C DOWTHERM
Volatile Organics
SW846 8260B
L03022703-13
Semi volatile Organics
SW846 8270C
SW846 8270C DOWTHERM
Client ID
PEW-4 DUP.
PEW-3
03/03/03
03/03/03
03/03/03
03/03/03
03/03/03
03/03/03
NC Certifica1ion Number: 25
Project Number: 61621.01
Report Date
Page 2 of 3
July 24, 2003
Report ID; A812424
Date Collected Date Received
03/03/03 2059
25-FEB-03 13:05 26-PEB-03
03/07/03 2039
03/04/03 0946
25-FEB-03 13: 05 26-FEB-03
03/07/03 2102
03/04/03 1021
25-FEB-03 14:10 26-FEB-03
1000 03/05/03 1240
1000 03/05/03 124 0
03/07/03 1800
25-FEB-03 14 :10 26-FEB-03
1000 03/05/03 1326
10 00 03/05/03 1326
03/07/03 1822
25-FEB-03 14:45 26-FEB-03
1000 03/05/03 1411
1000 03/05/03 1411
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 ) [phone] I Fax [phone]
11 9
Df\YIS
FLtWD LABORATORY ANALYSIS REPORT
NELAC Certification Number: £87633
Master Tracking List
Client
Contact
Sample ID
Volatile Organics
SW846 826GB
I.03022703-14
Volatile Organics
SW846 8260B
L03022703-1S
Volatile Organics
SW846 8260B
LOJ0.!2703-16
Volatile Organics
SW846 8260B
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
PEM CARTER
Client ID
TRIP BLANK #1
TRIP BLANK#.!
TRIP BLANK #3.
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 3 of 3
Date Collected
03/07/03
13-FEB-03 09: 30
03/07/03
13-FEB-03 09: 30
03/07/03
13-PEB-0) 09: 30
03/07/03
: July 24, 2003
Report ID: AB12424
Date Received
184 5
26-FEB-03
1317
1340
26-FEB-03
1403
Davis & Floyd, Inc. I PO Drawer 428 / Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax {864) 229-7119
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DAYIS
FLOYD LABORATORY ANALYSIS REPORT
QC Batch Report
Report Date March 17, 2003
Page 1 of Report ID: AB~688
Matrix GW/ChemW
WorkGrou;: WG33129 Prep Method
Descript::."on: V0/8260 TIC-SHE Analtyical Method, SW846 82608
PREP ANALYTICAL
Sample ID Client ID R=# Date Titnc Date Time Analyst Dilution
L03022403-0l CC-33 02/24/03 1609 PAP
L03022403-02 F'F-62 02/24/03 1631 PAP
L03022403-03 FF-34 02/24/03 1654 PAP
L03022403-04 T-35 02/24/03 1717 PAP
L03022403-05 ITEF 02/24/03 1825 PAP
L03022403-06 ITCI 02/24/03 1848 PAP
L03022403-07 ITCI DUP. 02/24/03 1911 PAP
L03022403-08 EQUIP. BLANK " 02/24/03 1546 PAP
L03022403-09 EQUIP. BLANK " 02/24/03 1523 PAP
L03022403-10 TRIP BLANK 02/24/03 1500 PAP
LCS33129:l Laboratory Control Spike 02/24/03 1957 PAP
MB33129:l Method Blank 02/24/03 1438 PAP
MS03022403-04 : 33129 Matrix Spike 02/24/03 1740 PAP
MSD03022403-04:33129 Matrix Spike Duplicate 02/24/03 1802 PAP
Davis & Floyd, Inc. I PO Drawer 428 ! Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 1 [phone] I Fax [phone] l 9
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DAYIS
FLtfi'D LABORATORY ANALYSIS REPORT I
Surrogates % Recovery
5~-~pl eN.U_~:e r M€:'<;1sureDa.~_e
L03022403-01 24-FEB-03
L03022403-02 24-FEB-03
L03022403-03 24-FEB-03
L03022403-04 24-FEB-03
L0302240]-05 24-FEB-03
L03022403-06 24-FEB-03
L03022403-07 24-FEB-03
L03022403-08 24-FEB-03
L03022403-09 24-FEB-03
L03022403-10 24-FEB-03
LCS33129: 1 24-FEB-03
MB33129:l 24-FEB-03
MSOJ02240J-04: 33129 24-FEB-03
MSD0302240)-04:33129 24-FEB-03
DCE 1,2-DICHLOROETHANE-D4
BFB
TOL
BROMOFLUOROBENZENE
TOLUENE-DB
16 :09
16: 31
16: 5'
17: 17
18: 25
18 : 4 8
19: 11
15 : 4 6
15 : 23
15: 00
19 : 57
14 :38
17 : 40
18 : 02
DCE
80-138
105
108
105
108
109
112
106
103
101
102
110
95
113
113
Re;:::ort Da:.e ~arch 1 7, 2003
Page of Report ID: AB•.70:':
Matrix GW/ChemW
workGroup: WG33129
Method SW846 8260
BFB TOL
88-112· a1·-109
99 92
96 92
98 91
97 90
97 93
97 89
99 90
96 93
97 91
96 91
99 90
94 91
98 90
98 92
Davis & Floyd, Inc. I PO Drawer 428 ! Greenwood, SC 29648 I 816 E. Our~! Avenue \ Greenwood, SC 29649 I (864) 229-441] I
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Fa, (!1641 229~71191
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DAYIS
FLOYD
Method Blanks
Blank
Parameter
Volatile Organics
SW846 8260B
1,1,1-TRICHLOROETHANE
1,1.2,2-TETRACHLOROETHANE
1, 1,2-TRICHLOROETHANE
1,1-DICHLOROETHANE
l, 1-DICHLOROETHENE
1,2-DICHLOROETHANE
1,2-DICHLOROPROPANE
2-BUTANONE
2 HEXANONE
4-METHYL-2-PENTANONE
ACETONE
BENZENE
BROMODICHLOROMETHANE
BROMOMETHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLORSETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-DICHLOROETHENE
CIS-1,3-DICHLORQPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1, 2-DICHLOROETHENE 1
TRANS-1,3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL)
MB33129:l
LABORATORY ANALYSIS REPORT
Report Date March l 7, 2003
Page l of Report ID: AB4686
Matrix GW/ChemW
WorkGroup, WG33129
Cone Qual RDL Units Analyst Date Time
.o .0 ug/1 PAP 02/24/03 1438
< .o .0 ug/1 PAP 02/24/03 1438
< .o 1.0 ug/1 PAP 02/24/03 1438
. 0 l. 0 ug/1 PAP 02/24/03 14 38
. 0 l. 0 ug/1 PAP 02/24/03 1438
< 1 .0 .o ug/1 PAP 02/24/03 1438
< .o l. 0 ug/1 PAP 02/24/03 1438
5. 0 5. 0 ug/1 PAP 02/24/03 14 38
5. 0 5. 0 ug/1 PAP 02/24/03 1438
< 5. 0 5. 0 ug/1 PAP 02/24/03 14 3 8
< 5 . o 5 . 0 ug/1 PAP 02/24/03 1438
< . 0 l. 0 ug/1 PAP 02/24/03 1438
. 0 1. 0 ug/1 PAP 02/24/03 1438
< 1 :o 1. 0 ug/1 PAP 02/24/03 1438
< .o .0 ug/1 PAP 02/24/03 1438
1. 0 1. 0 ug/1 PAP 02/24/03 1438
< 1 .0 .0 ug/1 PAP 02/24/03 1438
< 1. 0 .o ug/1 PAP 02/24/03 1438
< .0 .o ug/1 PAP 02/24/03 1438
< 1. 0 1. 0 ug/1 PAP 02/24/03 1438
< 1 .o . 0 ug/1 PAP 02/24/03 1438
< .0 .0 ug/1 PAP 02/24/03 1438
. 0 . 0 ug/1 PAP 02/24/03 1438
< 1 .0 .0 ug/1 PAP 02/24/03 1438
< .o 1. 0 ug/1 PAP 02/24/03 14 38
1. 0 1.0 ug/1 PAP 02/24/03 1438
< 1. 0 1. 0 ug/1 PAP 02/24/03 1438
< 1.0 .0 ug/1 PAP 02/24/03 14 38
< .0 .0 ug/1 PAP 02/24/03 1438
< .0 1. 0 ug/1 PAP 02/24/03 1438
< 1. 0 1.0 ug/1 PAP 02/24/03 1438
< .o .o ug/1 PAP 02/24/03 1438
< . 0 .o ug/1 PAP 02/24/03 1438
< 2 .0 2 .0 ug/1 PAP 02/24/03 1438
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 2964U I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
12 3
Df\YIS
FLtfYD LABORATORY ANALYSIS REPORT
Matrix Spikes and Duplicates
MS/1".5D
Paramet~r.
1,1-DICHLOROETHENE
1,2-DICHLOROETHANE
2-BUTANONE
BENZENE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROFORM
TETRACHLOROETHENE
TRICHLOROETHENE
VINYL CHLORIDE
Pa ram~·t._ef ..
1,1-DICHLOROETHENE
1,2-DICHLOROETHANE
2-BUTANONE
BENZENE
CARBON TETRACHLORIDE
CHWROBENZENE
CHLOROFORM
TETRACHLOROETHENE
TRICHLOROETHENE
VINYL CHLORIDE
MS03022403-04:33129
MSDOJ022403-04:33129
Spike
Added
50. 00
50. 00
50 .oo
50 .oo
50. 00
50. 00
50. 00
50. 00
50. 00
50 .oo
Spike
Added
50. 00
50. 00
50. 00
50 .oo
so. 00
50 .oo
50 . 00
50. 00
50. 00
50. 00
Sample
Cone
< o. 00100
0 .00100
< 0 .00500
0. 001 74
< 0 .00100
0 . 00444
< 0 .00100
0. 00109
0 .00159
< 0 .00100
MSD
co_ll.c
44 . 15
56 . 58
48. 04
45 . 4 0
51 . 30
46 . 29
51 . 31
49 . 62
47. 91
37 . 73
Report Date March 20, 200]
Page 1 of 1 Report ID: ABS093
Matrix GW/Chemw
WorkGroup: WGJ3129
Method SW846 8260B
MS MS Limits
Cone \REC %:REC
4 3. 14 86 76-12B
56. 91 114 78-135
49. 45 99 76-168
45 . 49 91 84-121
52 .55 105 74-120
46. 45 93 87-118
50 . 42 101 80-124
50 .02 100 83-107
47 . 61 95 78-119
36. 93 74 64-124
Mso.:_ Li!Tlits
_.\REC::· ·\RPD %RPO ·•.%REC.
BB 2 ll 76-128
113 · 16 78-135
96 3 40 76-168
91 0 10 84-121
103 2 20 74-120
93 0 10 87-118
103 2 12 80-124
99 11 83-107
96 l 10 78-119
75 2 13 64-124
N0TE1 1MS/MSD \ recoveries are note evaluated if the sample concentration is greater than four times the spike added.
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Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue
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DAYIS
FLo\'D LABORATORY ANALYSIS REPORT
Laboratory Control Standards and Duplicates
LCS
Parame_t,:"er
1,1-DICHLOROETHENE
1,2-DICHLOROETHANE
2-BUTANONE
BENZENE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROFORM
TETRACHLOROETHENE
TRICHLOROETHENE
VINYL CHLORIDE
LCS33129:l
~pike
Added
20. 00
20. 00
20 . 00
20. 00
20 00
20. 00
20. 00
20 . 00
20 00
20 .00
LCS
Coii.c
19 42
23. 02
19. 42
20. 10
22. 18
20. 64
20. 82
20 .96
19 56
16 ,43
Report Date March 17, 2 003
Page 1 of Report ID: AB·168S
Matrix GW/ChemW
WorkGroup: '.-."G33129
Method SWB46 82608
LCS Limits
\REC \REC ,., 78-126
115 83-135
97 80-149
101 88-119
111 75-126
103 90-1]6
104 85-128
105 81-110
98 B0-115
82 68-141
Davis & Floyd, Inc. j PO Drawer 428 I Greenwood, SC 29648 1 816 E. Durst Avenue I Greenwood, SC 29649 l [phone] I Fax [phone]
125
DAYIS
FLtJ\'D LABORATORY ANALYSIS REPORT
QC Batch Report
Report Date March 17, 2003
Page 1 of 1 Report ID: A84 692
Matrix GW/ChemW
WorkGroup WG3J287 Prep Method
Description, VO/8260/TCL TIC-SHE Analtyical Method: SW646 82608
PREP ANALYTICAL
Sample ID Client ID •=• Date Time Date Time Analyst Dilution
L0302270J-01 HH-77 03/07/03 142 6 PAP
L030227QJ-02 HH-48 0)/07/03 1449 PAP
L03022703-03 C-49 03/07/03 1512 PAP
L03022703-04 EE-58 03/07/03 1535 PAP
L03022703-05 GG-61 03/07/03 1557 PAP
L03022703-06 AA-54 03/07/03 12 55 PAP
L0302270J-07 P-58 03/07/03 1620 PAP
LOJ02270J-08 K-28 03/07/03 212 5 PAP
1,0)022703-09 V-23 03/07/03 2039 PAP
L03o'22703-10 V-23 DUP. 03/07/03 2102 PAP 2
LOJ022703-ll PEW-4 03/07/03 1800 PAP
L03022703-12 PEW-4 DUP. 03/07/03 1822 PAP
L03022703-13 PEW-3 03/07/03 1845 PAP
L03022703-14 TRIP BLANK '1 03/07/03 1317 PAP
L03022703-15 TRIP BLANK " 03/07/03 1340 PAP
L03022703-16 TRIP BLANK ff3 03/07/03 1403 PAP
LCS33287:l Laboratory Control Spike 03/07/0] 2148 PAP
MB33287:l Method Blank 03/07/03 1232 PAP
MSOJ022703-06:33287 Matrix Spike 1 03/07/03 1908 PAP
MSD0)022703-06:33287 Matrix Spike Duplicate 03/07/03 1931 PAP
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Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 l [phone] I fax [phone]
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Df\YIS
FLtJYD LABORATORY ANALYSIS REPORT
Surrogates % Recovery
SampleNu~er MeasureDate
L03022703-0l 07-MAR-03
L03022703-02 07-MAR-03
L03022703-03 07-MAR-03
L03022703-04 07-MAR-03
L03022703-05 07-MAR-03
L03022703-06 07-MAR-03
L03022703-07 07-MAR-03
L03022703-08 07-MAR-03
L03022703-09 07-MAR-03
L03022703-10 07-MAR-03
L03022703-ll 07-MAR-03
L03022703-12 07-MAR-03
L03022703-13 07-MAR-03
L03022703-14 07-MAR-03
L03022703-15 07-MAR-03
L03022703-16 07-MAR-03
L03022721-17 07-MAR-03
LCS332~7;l 07-MAR-03
MB33287: 1 07-MAR-03
MS03022703 -06:33287 07-MAR-03
MSD03022703-06:33287 07-MAR-03
DCE 1,2-DICHLOROE'fHANE-D4
BFB
TOL
BROMOFLUOROBENZENE
TOLUENE-DB
14 :26
14 : 4 9
15: 12
15: 35
15: 57
12 :55
16: 20
21 : 25
20: 39
21 :02
18; 00
18 : 22
18 : 45
13: 17
13 : 4 0
14 : 03
20: 17
21 : 48
12: 32
19: 08
19: 31
Report Date March 1 7, 2003
Page 1 of Report ID: AB4706
Matrix GW/ChemW
WorkGroup: WG33287
Method SW846 8260
DCE Bf~ TOL
80-13B 88° 112 87-109
114 93 94
119 94 93
115 95 95
119 94 92
121 92 91
107 92 93
124 94 93
115 95 92
124 98 92
121 98 91
12 9 95 91
131 95 92
134 95 91
105 92 93
112 95 94
112 95 95
130 95 93
125 95 93
97 92 94
133 95 92
134 95 92
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 I::. Ours! Avenue I Greenwood, SC 29649 I (864) 229-441 J I F;:ix [phone]
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DAYIS
FLOYD LABORATORY ANALYSIS REPORT
I
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Method Blanks I
I
Report Date 1-'.acch 1 7, 2 00 3
Page l of l Rep::rt 10: AB4690
Matrix GW/Cherr.;.;-I
Blank MB332B7: 1 WorkGroup: WG33287
Parruneter Cone Qual RDL Units Analyst Date Time I
Volatile Organics
SW846 8260B
1,1,1-TRICHLOROETHANE ' .0 .o ·..:g/1 PAP 03/07/03 1232 I
1,1,2,2-TETRACHLOROETHANE .0 .0 ·cg/ l PAP 03/07/03 1232
1,1,2-TRICHIDROETHANE ' .0 .0 :..;g/1 PAP 03/07/03 1232
1, 1-DICHLOROETHANE ' .o .0 ·..:g/ l PAP 03/07/03 1232
1, 1-DICHLOROETHENE .0 .0 ·..19/l PAP 03/07/03 1232 I
1,2-0ICHLOROETHANE ' .0 .o cg/1 PAP 03/07/03 1232
1,2-DICHLOROPROPAN"E .0 .o "..lg/1 PAP 03/07/03 1232
2-BUTANONE 5. 0 5 .0 ·..19/l PAP 03/07/03 12)2
2-HEX:ANONE ' 5. 0 5 .0 ·_;g/1 PAP 03/07/03 1232 I
4 -METHYL-2 -PENTANONE 5 . 0 5. 0 ·..:g/1 PAP 03/07/03 1232
ACETONE ' 5. 0 5. 0 -.:g/ 1 PAP 03/07/03 1232
BENZENE .0 . 0 '..!9/ 1 PAP 03/07/03 1232 I
BR0M0DICHLOR0METHANE ' .o .0 '..lg/ l PAP 03/07/03 1232
BROMOFORM .o .0 "Jg/1 PAP 03/07/03 1232
BROMOMETHANE ' . 0 1 .0 ug/1 PAP 03/07/03 1232
CARBON DISULFIDE .0 . 0 ug/1 PAP 03/07/03 1232 I
CARBON TETRACHLORIDE ' 1 .o .o ug/1 PAP 03/07/03 1232
CHLOROBENZENE ' .0 . 0 ug/1 PAP 03/07/03 1232
CHLOROETI-!ANE ' 1.0 .0 ug/1 PAP 03/07/03 12 32
CHLOROFORM ' 1 .0 . 0 ug/1 PAP 03/07/03 1232 I
CHLOROMETHANE ' 1. 0 . 0 ug/1 PAP 03/07/03 1232
CIS-1,2-DICHLOROETHENE ' l .0 . 0 ug/1 PAP 03/07/03 1232
CIS-1,3-DICHLOROPROPENE ' 1.0 .0 ug/1 PAP 03/07/03 1232 I
DIBROMOCHLOROMETHANE ' ' l .o .0 ug/1 PAP 03/07/03 1232
ETHYLBENZENE ;:· ' 1. 0 1.0 ug/1 PAP 03/07/03 1232
METHYLENE CHLORIDE ! ' 1. 0 1.0 ug/1 PAP 03/07/03 1232
STYRENE ' 1. 0 1.0 ug/1 PAP 03/07/03 1232 I
TETRACHLOROETHENE ' 1.0 .0 ug/1 PAP 03/07/03 1232
TOLUENE ' 1. 0 1. 0 ug/1 PAP 03/07/03 1232
TRANS-1,2-DICHLOROETHENE ' 1. 0 1.0 ug/1 PAP 03/07/03 1232
TRANS-1,3-DICHLOROPROPENE ' l. 0 .0 ug/1 PAP 03/07/03 1232 I
TR I CHLO RO ETHE NE ' l.0 . 0 ug/1 PAP 03/07/03 1232
VINYL ACETATE ' 1.0 .0 ug/1 PAP 03/07/03 1232
VINYL CHLORIDE 1. 0 . 0 ug/1 PAP 03/07/03 1232 I
XYLENE (TOTAL) ' ' .o ' .0 ug/1 PAP 03/07/03 1232
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Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue \ G,eenwood, SC 2%49 \ [phone] \ Fax [phone] I
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FL0\7D LABORATORY ANALYSIS REPORT
Matrix Spikes and Duplicates
MS/MSD
Param(!ter.
1,1-DICHLOROETHENE
1,2-DICHLOROETHANE
2-BUTANONE
BENZENE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROFORM
TETRACHLOROETHENE
TRICHLOROETHENE
VINYL CHLORIDE
Paj~:~~:J;i .·
1 , 1-DI_CHl,OROETHENE
1,2-DICHLOROETHANE
2-BUTANONE
BENZENE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROFORM
TETRACHLOROETHENE
TRICHLOROETHENE
VINYL CHLORIDE
MS03022703-06:]3287
MSDOJ022703-06:33287
_Spike
Added
50 . 00
50. 00
so. 00
50. 00
50 . 00
50. 00
50. 00
50. 00
50 . 00
50 . 00
· Spike
Aactt'!ct
so. 00
50. 00
50. 00
50. 00
50. 00
50. 00
'so.oo
50. 00
50 .00
so .00
.Sample
Cone
. 00
.00
< 5. 00
' 1 00
.oo
< 1 00
< 1. 00
< 00
. 00
. 00
MSD
. Cone
54 . 53
70 .75
42 . 34
48 .14
65 . 06
51 .17
66 . 10
46 . 37
48 .97
52.25
Report Date March 17, 2003
Page 1 of 1 Report ID: AB4691
Matrix GW/Chernw
WorkGroup: WG33287
Method SWB46 82608
MS MS Liniits
Cone \REC \REC
53 . 91 108 76-128
70 .89 1'2 78-135
44 . 09 88 76-168
48 . 31 97 84-121
64 . 34 129 74-120
51 . 33 103 87-118
65 . 3 8 131 80-124
47. 11 94 83· 107
48. 67 97 78 119
52 .24 104 64-124
MSD Liffiic·s
\-REC \-RPD \RPO: ·\REC
109 11 76-128
142 0 16 78-135
85 4 40 76-168
96 0 10 84-121
130 20 74-120
102 0 10 87-118
132 12 80-124
93 2 11 83-107
98 1 10 78-119
105 0 13 64-124
NOTB1 MS/MSD \ recoveries are not evaluated if the sample concentration is greater than four times the spike added.
r,
Davis & Floyd, Inc. l PO Drawer 428 \ Greenwood, SC 29648 \ 816 E. Ours! Avenue I Greenwood, SC 29649 I [phone] I Fax [phone] l 9
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FLOYD LABORATORY ANALYSIS REPORT
Laboratory Control Standards and Duplicates
LCS LCSJ3287:1
Param~_ter •.
1, 1-DICHLOROETHENE
1,2-DICHLOROETHANE
2 ·BUTANONE
BENZENE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROFORM
TETRACHLOROETHENE
TRICHLOROETHENE
VINYL CHLORIDE
Spike
Added
20, 00
20, 00
20, 00
20, 00
20, 00
20, 00
20, 00
20, 00
20, 00
20. 00
LCS
Cone
22 , 49
2B ,66
16' 39
20 37
26 '69
21 , 99
26 ,36
20 ,55
20, 44
22 ,19
Re;:ort Date March
Pa~e 1 of Report
Ma-:.:-ix GW/ChemW
wor:-:Group: WG33287
Me:::1od SW846 82608
LCS Limits
llrREC \REC
112 78-126
'" 83 -135
92 60-149
102 88-119
133 75-126
110 90-116
132 85-128
103 81-110
102 80-115
111 68-141
17' 2003
ID: AB46B9
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 j 816 £. Durst Avenue I Greenwood, SC 29649 I [phone] I
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Di\YIS
FLOYD LABORATORY ANALYSIS REPORT
QC Batch Report
Report Date March 17, 2003
Page 1 o[ 1 Report ID: AB-1698
Matrix GW/ChemW
WorkGroup WG33172 Prep Method SW846 3500B
Description, sv/dow Analtyical Method: SW846 8270C DOWTHERM
PREP ANALYTICAL
Sample ID Client ID •=# Date Time Date Time Analyst Dilution
L03022403-08 EQUIP. BLANK ,1 02/26/03 0800 02/27/03 l H6 JRN
L03022403-09 EQUIP. BLANK " 02/26/03 0800 02/27/03 122 5 JRN
L03022403-11 D-88 02/26/03 0800 02/27/03 1304 JRN
L03022403-12 D-56 02/26/03 0800 02/27/03 1342 JRN
L03022403-13 D-35 02/26/03 0800 02/27/03 1422 JRN
L03022403-H D-27 02/26/03 0800 02/27/03 1501 JRN
LCS33172: 1 Laboratory Control Sp1i<.e 02/26/03 0800 02/27/03 1109 JRN
MB33172: 1 Method Blank 02/26/03 0800 02/27/03 1031 JRN
MS03022403-14:33172 Matrix Spike 02/26/0) 0800 02/27/03 154 0 JRN
MSD03022403-14:33172 Matrix Spike Du;:ilicate 02/26/03 0800 02/27/03 1620 JRN
Davis & Floyd, 1nc. j PO Drawer 428 1 Greenwood, SC 2g&48 I 816 E. Durst Avenue I Greenwood, SC 29b49 I [phone] I Fax [phone]
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Df\YIS
FLOYD LABORATORY ANALYSIS REPORT
Surrogates % Recovery
Report Date March 17. 200~
Page 1 of 1 Report ID: AB'i 7 :1
Matrix GW/ChernW
WorkGroup, WG33172
Method SW846 3550/8270
Sall_lpl~Ntlmt)er MeasureDate FBP
43-111
L03022403-08 27-FEB-03 11 : 46 76
LOJ02240J-09 27-FEB-03 12 : 25 62
L03022403-ll 27-FEB-03 1]: 04 66
L03022403-12 27-FEB-03 13 : 4 2 69
L03022403-13 27-FEB-03 14 :22 79
L03022403-14 27-FEB-03 15 :01 74
LCS33172: 1 27-FEB-03 11 :09 79
MB33172: 1 27-FEB-03 10 :31 73
MS03022403-11 :33172 27-FEB-03 15 : 40 7)
MSD03022403-14:33172 27-FEB-03 16 :20 60
FBP -2-FLUOROBIPHF.NYL
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 J 816 E. Durs1 Avenue I Greenwood, SC 29&4Y I (864) 229-441] I Fax [phone]
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FLtJ\'D LABORATORY ANALYSIS REPORT
Method Blanks
Blank
Parameter
Semivolatile Organics
SW846 8270C DOWI'HERM
1, 1' -BI PHENYL
BI PHENYL ETHER
Prep Procedure
Analytical Prep Procedures:
OOWTHERM
MB33172:1
Method
SWB46 35008
Report Date March 17'
Cone
10.0
10.0
Analyst Prep Date
Page 1 of
Matrix
WorkGroup:
Qual
DBC 02/26/03 0800
Report 10:
GW/ChernW
WG33172
RDL Units
10.0
10.0
ug/1
ug/1
200)
Al3'1694
Analyst Date Time
JRN 02/27/03 1031
JRN 02/27/03 1031
Davis & Floyd, Inc. \ PO Drawer 428 I Greenwood, SC 29648 I 816 E. Dur~! Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
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DAYIS
FLtrvD LABORATORY ANALYSIS REPORT
Par0;~~te~
1, l' -BI PHENYL
BI PHENYL ETHER
. ~~~a-~~~~-;· ..
1, l' -BI PHENYL
BIPHENYL ETHER
Matrix Spikes and Duplicates
MS/MSD MS03022403-l4:J3172
MSD0302240J-14:3Jl72
Spike
Added
50.00
50.00
:·Spike
'Actd_ed
50.00
50. 00
Sample
cone
10. 00
< 10. 00
MSD
Cone':
30 .86
31. 10
Report Date March 1 7, 2003
Page 1 of 1 Report ID: AB4695
Matrix GW/ChemW
WorkGroup: WG33172
Method SW846 8270C
MS MS Limits
Cone \REC \-RE;C
36. 97 74 31-110
37.51 75 30-113
Mso: Limits
\REC· \-RPO ·· .. : \-~PD \REC
62 18 27 31-110
62 19 22 30-113
NOTE: MS/MSD \ recoveries are not evaluated if the sample concentration 1s greater than four times the spike added.
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FLOYD LABORATORY ANALYSIS REPORT
Laboratory Control Standards and Duplicates
Paramet~r.
1, l' -Bl PHENYL
BIPHENYL ETHER
LCS LCS33172:1
Spike
Added
50 00
50.00
LCS
Cone
39 4 2
40.78
Report Date March
Page 1 of 1 Report
Matrix GW/ChemW
WorkGroup: WG33172
Method
LCS
%REC
79
82
SW846
.Limits
,%REC
41-109
42-106
8270C
17' 2003
ID: AB4693
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 81 b E. Dur5t Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
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FLOYD LABORATORY ANALYSIS REPORT
QC Batch Report
Report Date March 1 7, 2003
Page 1 of 1 Report IO: /1.84700
Matrix GW/ChemW
WorkGroup WG33232 Prep Method SW846 3500B
Descripti'on: SV/8270/BNA/TCL • SV/OOW Analtyical Method· SW846 8270C
PREP ANALYTICAL
Sample ID Client ID Run# Date Time Date Time Analyst Dilution
L03022703-ll PEW•4 03/03/03 1000 03/05/03 124 0 JRN
L03022703-12 PEW-4 DUP. 03/03/03 1000 03/05/03 1326 JRN
L03022703-13 PEW-] 03/03/03 1000 03/05/03 1411 JRN
LCS33232:l Laboratory Control Spike 03/03/03 1000 03/05/03 1059 JRN
MB33232:1 Method Blank 03/03/03 1000 03/05/03 1015 JRN
MS03022703-13 :33232 Matrix Spike 03/03/03 1000 03/05/03 1458 JRN
MS003022703-13:33232 Matrix Spike Duplicate 03/03/03 1000 03/05/03 1543 JRN
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DAYIS
FLOYD LABORATORY ANALYSIS REPORT
Surrogates % Recovery
SampleNwnber MisasureDate
L03022703-ll
L03022703-l 2
L03022703-13
LCS33232: 1
MB33232: 1
MS03022703-l3:33232
MSD03022703-13:33232
TBP 2,4,6-TRIBROMOPHENOL
FBP 2-FLUOROBIPHENYL
2FP 2 -FLUOROPHENOL
NBZ NITROBENZENE-05
PHL PHENOL-OS
TPH TERPHENYL-D14
OS-MAR-03 12 40
05 Ml,R-03 13 : 26
05-MAR-03 14 : 11
05-MAR-03 10: 59
05-MAR-03 10: 15
05-MAR-03 14 : 58
05-MAR 03 15 : 4 3
TBP FBP
42-123 43 111
97 79
97 81
89 71
91 87
78 75
92 75
92 77
Report: Dar.e March 2C, 2003
Page 1 of 1 Report IV: A35095
Matrix GW/Chemw
WorkGroup, WG33232
Method SW846 3550/5270
2FP NBZ PHL T?H
21 78 35 114 10-74 18-121
66 78 58 100
67 82 59 100
62 77 56 98
76 87 64 100
64 76 55 91
71 81 69 102
70 78 6B 105
Davis & Floyd, Inc. PO Drawer 428 I Greenwood, SC 29648 [ 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
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Df\VIS
FLOYD
Method Blanks
Blank
Parameter
Semivolatile Organics
SW846 8270C
1,2,4-TRICHLOROBENZENE
1,2-DICHLOROBENZENE
1,3-DICHLOROBENZENE
1,4-DICHLOROBENZENE
2,4,5-TRICHLOROPHENOL
2, 4, 6-TRICHLOROPHENOL
2,4-DICHLOROPHENOL
2,4-DIMETHYLPHENOL
2,4-DINITROPHENOL
2,4-DINITROTOLUENE
2,6-DINITROTOLUENE
2-CHLORONAPHTHALENE
2-CHLOROPHENOL
2-METHYL-4,6-DINITROPHENOL
2-METHYLNAPHTHALENE
2-METHYLPHENOL
2-NTTROANILINE
2-NITRQPHENOL
3,3'-DICHLOROBENZIDINE
3-NITROANILINE
4-BROMOPHENYL PHENYL ETHER
MB33232: 1
4 -CHLORO-3-METHYLPIIENOL
4-CHLOROANILINE
4-CHLOROPHENYL PHENYL ETHER
4-METHYLPHENOL
4-NITROANILINE
4-NITROPHENOL
ACENAPHTHENE
ACENAPHTHYLENE
ANTHRACENE
BENZO(A)ANTHRACENE
BE~ZO (A) PYRENE
BENZO(B)FLUORANTHENE
BENZO(G,H,I)PERYLENE
BENZO(K)FLUORANTHENE
BENZOIC ACID
BENZYL ALCOHOL
BIS(2-CHLOROETHOXY)METHANE
BIS(2-CHLOROETHYL)ETHER
81S(2-0ILOR01S0PROPYL)ETHER
LABORATORY ANALYSIS REPORT
<
<
<
<
<
<
<
<
Cone
10. 0
10 ,0
10. 0
10, 0
10. 0
10. 0
10. 0
10. 0
25. 0
10, 0
10. 0
10. 0
10. 0
25. 0
10 .0
10. 0
10 ,0
10. 0
10. 0
10 .o
10. 0
10. 0
10. 0
10.0
10 '0
10, 0
25, 0
10.0
10, 0
10. 0
10 .o
10. 0
10, 0
10 .o
10, 0
so, 0
10.0
10 .o
10. 0
10.0
Report Date :,,:a:-ch 1 7,
Page 1 of 2 Re;:ort ID:
Matrix GW/Che::-:,.;
workGroup: WG33232
Qual RDL Unit11
10 ,0 ug/1
10. 0 ug/1
10. 0 ug/1
10, 0 ug/1
10 .o ug/1
10 ,0 ug/1
10 '0 ug/1
)0. C ug/1
25 .o ug/1
10. 0 ug/1
10. 0 ug/1
10.'0 ug/1
10. 0 ug/1
25. 0 ug/1
10 .o ug/1
10. 0 ug/1
10, 0 ug/1
10. 0 ug/1
10. 0 ug/1
10, 0 ug/1
10. 0 ug/1
10. 0 ug/1
10, 0 ug/1
10.0 ug/1
10.0 ug/1
10.0 ug/1
25, 0 ug/1
10. 0 ug/1
10 .o ug/1
10.0 ug/1
10.0 ug/1
10 ,0 ug/1
10. 0 ug/1
10 ,0 ug/1
10 .o ug/1
so' 0 ug/1
10.0 ug/1
10.0 ug/1
10.0 ug/1
10.0 ug/1
200)
AB4697
Analyst Date Time
,JRN 03/05/03 1015
JRN 03/05/03 1015
JRN 03/05/03 1015
JRN 03/05/03 1015
JRN 03/05/03 1015
JRN 03/05/03 1015
JRN 03/05/03 1015
JRN 03/05/03 1015
JRN 03/05/03 1015
JRN 03/05/03 1015
JRN 03/05/03 1015
JRN 03/05/03 1015
JRN 03/05/03 1015
JRN 03/05/03 1015
JRN 03/05/03 1015
JRN 03/05/03 1015
JRN 03/05/03 1015
JRN 03/05/03 1015
JRN 03/05/03 1015
JRN 03/05/03 1015
JRN 03/05/03 1015
JRN 03/05/03 1015
JRN 03/05/03 1015
JRN 03/05/03 1015
JRN 03/05/03 1015
JRN 03/05/03 1015
JRN 03/05/03 1015
JRN 03/05/03 1015
JRN 03/05/03 1015
JRN 03/05/03 1015
JRN 03/05/03 1015
JRN 03/05/03 1015
JRN 03/05/03 1015
JRN 03/05/03 1015
JRN 03/05/03 1015
JRN 03/05/03 1015
JRN 03/05/03 1015
JRN 03/05/03 1015
JRN 03/05/03 1015
JRN 03/05/03 1015
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Di\VIS
FL(JyD LABORATORY ANALYSIS REPORT
Method Blanks
Blank
Parameter
BIS(2-ETHYLHEXYL)PHTHALATE
BUTYL BENZYL PHTHALATE
CHRYSENE
DI-N-BUTYL PHTHALATE
DI-N-OCTYL PHTHAJ..ATE
DIBENZ(A,H)ANTHRACENE
DIBENZOFURAN
DI ETHYL PHTHAI..ATE
DIMETHYL PHTHALATE
FLUORANTHENE
fLUORENE
HEXACHLOROBENZENE
HEXACHLOROBUTADIENE
HEXACHLOROCYCLOPENTADIENE
HEXACHLOROETHANE
INDENO(l,2,3-CD)PYRENE
ISOPHORONE
N-NITROSODI-N-PROPYLAMINE
N-NITROSODIPHENYLAMINE
NAPHTHALENE
NITROBENZENE
PENTACHLOROPHENOL
PHENANTHRENE
PHENOL
PYRENE
SW846 8270C DOWTHERM
1, l' -BI PHENYL
BIPHENYL ETHER
Prep Procedure
Analytical Prep Proceduree:
BNA SEMIVOLATILES
OOWTHERM
MB33232:l
Method
SW846 35008
SW846 35008
Report Date :-larch ~7,
Page 2 of 2 Report. ID:
Matrix GW/ChemW
WorkGroup: WG33232
Cone Qual
10 .o
10. 0
10 .0
10. 0
10. 0
10. 0
10. 0
10 .o
10 .o
10 .o
10 .o
10 .o
10. 0
10. 0
JO .o
10 .0
10 .o
10. 0
10. 0
10. 0
10 .o
25. 0
10 .0
10 .0
10. 0
10 . o
10. 0
Analyst Prep Date
MCR 03/03/03 1000
MCR 03/03/03 1000
RDL Units
10 .0 ug/1
10. 0 ug/1
10. 0 ug/1
10. 0 ug/1
10. 0 ug/1
10. 0 ug/1
10. 0 ug/1
10. 0 ug/1
10. 0 ug/]
10. 0 ug/1
10. 0 ug/1
10. 0 ug/1
10. 0 ug/1
10 .o ug/1
10 .o ug/1
10. 0 ug/1
10. 0 ug/1
10. 0 ug/1
10. 0 ug/1
10. 0 ug/1
10. 0 ug/1
25 . 0 ug/1
10. 0 ug/1
10. 0 ug/1
10. 0 ug/1
10 . 0 ug/1
10. 0 ug/1
20,)J
A.84 697
Analyst Date Time
JRN 03/05/03 1015
JRN 03/05/03 1015
JRN 03/05/03 1015
JRN 03/05/03 1015
JRN 03/05/03 1015
JRN 03/05/03 1015
,JRN 03/05/03 1015
JRN 03/05/03 1015
JRN 03/05/03 1015
JRN 03/05/03 1015
JRN 03/05/03 1015
JRN 03/05/03 1015
JRN 03/05/03 1015
JRN 03/05/03 1015
JRN 03/05/03 101 5
JRN 03/05/03 1015
JRN 03/05/03 1015
JRN 03/05/03 1015
JRN 03/05/03 1015
JRN 03/05/03 1015
JRN 03/05/03 1015
JRN 03/05/03 1015
JRN 03/05/03 1015
JRN 03/05/03 1015
JRN 03/05_/03 1015
JRN 03/05/03 1015
JRN 03/05/03 1015
I Davis & Floyd, Inc. I PO Dcawer 428 I Greenwood, SC 29648 I 816E. Durst Avenue I GreenwcxxJ, SC 2%49 I 1864) 229-4413 I fax [phone]
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Di\YIS
FLi1YD LABORATORY ANALYSIS REPORT
Matrix Spikes and Duplicates
MS/MSD MS03022703-13:33232
• MSD03022703-13: 33232
·-:-.
Pal:"~me~_i/:. _.:
1,2,4-TRICHLOROBENZENE
1,4-DICHLOROBENZENE
2,4-0INITROTOLUENE
2-CHLOROPHENOL
4-CHLOR0-3-METHYLPHENOL
4-NITROPHENOL
ACENAPHTHENE
N-NITROSODI-N-PROPYLAMINE
PENTACHLOROPHENOL
PHENOL
PYRENE
1,1'-BIPHENYL
BIPHENYL ETHER
1,2,4-TRICHLOROBENZENE
1,4-DICHLOROBENZENE
2,4-0I~ITROTOLUENE
2-CHLOROPHENOL
4-CHLOR0-3-METHYLPHENOL
4-NITROPHENOL
ACENAPHTHENE
N-NITROSODI-N-PROPYLAMINE
PENTACHLOROPHENOL
PHENOL
PYRENE
1, l' -BI PHENYL
8 I PHENYL ETHER
Spike
·Added
50 . 00
50. 00
50 .00
75. 00
75. 00
75. 00
so. 00
so. 00
75. 00
75 00
50. 00
so. 00
50. 00
Spike·
...-:: -:-ld?-~ct.
so. 00
50. 00
so. 00
75.00
75. 00
75. 00
50. 00
50. 00
75. 00
75 .oo
50 .oo
50 .oo
so. 00
s_ample
ConC
< 10. 00
< 10 .oo
10. 00
< 10 . 00
< 10. 00
< 25 .oo
< 10 . 00
10 .oo
< 25 .oo
10. 00
< 10 .00
10. 00
< 10 .00
MS□
· cc:in_c
31 . 85
3 0. 36
" .50
53 . 89
61 . 79
51 .99
41 .27
37. 78
68 .23
52. 58
50.30
42.36
44.49
Report Date March 17. 2003
Page 1 of 1 Report ID: AB4699
Matrix GW/ChernW
WorkGroup: WG3]232
Method SW846 8270C
MS MS Limits
·Cone \REC \REC
33 . 19 66 26-101
31 . 21 62 27-94
43 . 18 86 46-117
54 . 56 73 35-89
63. 10 84 " -101
51 .46 69 1-97
40. 39 81 39-108
38 .04 76 39-107
68. 80 92 20-128
53. 87 72 3-76
49. 78 100 55-116
42 . 71 85 31-110
43 . 42 87 30 113
· ::·:L'fmfrs
···· . _1-·~Ec:: ::,\RPD,.': . \_tR_~I?.::·.
64 4 20 26-101
61 28 27-94
89 3 19 46-117
72 21 35-89
82 2 20 44-101
69 20 1-97
83 22 39-108
76 24 39-107
91 32 20-128
70 2 23 3-76
101 22 55-116
85 27 31-110
89 2 22 30-113
NOTB1 MS/MSD I recoveries are not evaluated if the sample concentration is greater than four times the spike added.
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140
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Di\YIS
FLtfYD LABORATORY ANALYSIS REPORT
Laboratory Control Standards and Duplicates
LCS
parameter
1,2,4-TRICHLOROBENZENE
1,4-DICHLOROBENZENE
2,4-DINITROTOLUENE
2-CHLOROPHENOL
4-CHLOR0-3-METHYLPHENOL
4-NITROPHENOL
ACENAPHTHENE
N-NITROSODI-N-PROPYLAMINE
PENTACHLOROPHENOL
PHENOL
PYRENE
1, 1' -BI PHENYL
BIPHENYL ETHER
LCS33232:1
. Spike
Added
50 .00
50. 00
50. 00
75. 00
75. 00
75. 00
50. 00
50 .00
75. 00
75. 00
50 00
50. 00
50. 00
LCS
Cone
34 .47
33 .72
". 73
61 . 29
67. 39
39. 40
45. 30
43 . 66
58 . 41
49. 20
48. 50
43 .75
46. 37
Report Date March 17' 2003
Page 1 of 1 Report ID: A84696
Matrix GW/ChemW
workGroup, WG33232
Method SW846 82"/0C
LCS Limits
%REC \-REC
69 36-93
67 34-88
89 58-111
82 39-92
90 50-96
53 1-7 9
91 51-100
87 47-110
78 13-112
66 6-69
97 6.0-114
88 41-109
93 42-106
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29&49 I [phone] [ Fax [phone]
1 4 1
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D1\YIS
FLOYD LABORATORY ANALYSIS REPORT I
QC Batch Report
WorkGroup_ WG33127
Description: GC/EG
Sall'lple ID
L03022403-05
L03022403-06
L03022403-07
LCS33127:l
MB33127:1
MS03022403-05.33127
MSD03022403-05:33127
Client ID
ITEF
ITCI
ITCI □UP.
Laboratory control Spike
Method Blank
Matrix Spike
Matrix Spike Duplicate
Run#
l
Davis & Floyd, Inc. l PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue
142-
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I Report Date March 17, 2003
Page l of l Report ID: AB4 704
Matrix GW/Chemw
Prep Method
Analtyical Method: SW846 8015 I
FREP ANALYTICAL
Date Time Date Time Analyst Dilution I
02/25/03 0953 MGB
02/25/03 1018 MGB 20
02/25/03 1044 MGB 20
02/25/03 0901 MGB I
02/25/03 08)6 MGB
02/25/03 1136 MGB
02/25/03 12 0 l MGB I
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DAYIS
FLOYD
Method Blanks
Blan:-< MB33127: 1
LABORATORY ANALYSIS REPORT
Report Date March 17, 2003
Page 1 of 1 Report ID: AB4701
Matrix GW/ChemW
WorkGroup: WG33127
Cone Qual RDL Units Analyst Date Time ParaJiteter -----------------------'------=----'--=='-------C='----='-'---------'-'=--
Gas Chromat::,grapby
SWB46 8015
ETHYLENE ;LYCOL 5.0 5.0 mg/1 MGB 02/25/03 0836
Davis & Floyd, Inc. I PO Drawer 428 l Greenwood, SC 29648 j 816 E. Durst Avenue I Greenwood, SC 29649 l [phone] 1 Fax [phone]
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D1\VIS
FLOYD LABORATORY ANALYSIS REPORT
,:· . .,.:,·
J?ci,i-~me~i}"
ETHYLENE GLYCOL
·,..-.·-:,.
-·~ara~;~:~{:.
ETHYLENE GLYCOL
Matrix Spikes and Duplicates
MS/MSD MS03022403-0S:33127
MSD03022403-0S:33127
Spike
Added
so.oo
.· Spike
Added
50.00
sample
Cori~
< 5 . 00
MS_"q_
ci;;~_C:
52. 82
Report Date March 1 7, 2 003
Page 1 of 1 Report ID: A.84703
Matrix GW/ChemW
workGroup: WG33127
Method SW846 6015
MS MS Limit's·
Cone \-~EC \REC
49. 25 99 68-129
MSD_ Limits
\-REC· \-RP□ \RPO .\-REC
106 7 16 68-12 9
NOTE: MS/MSD \ recoveries are not evaluated if the sample concentration is greater than four times the spike added.
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Davis & Floyd, Inc. I PO D<awe, 428 I G,eenwcx,d, SC 29648 I 811, ,-44st Avenue I G,eenw0<s!, SC 29649 I 18641 2'9-44 U I Fax [phone]
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DAJ'IS
FLiDYD LABORATORY ANALYSIS REPORT
R<!-rameter
ETHYLENE <;LYCOL
Laboratory Control Standards and Duplicates
LCS :. LCS33127:l
Spike
Added
50.00
LCS
Cone
45.00
Report Date March
Page l of l Report
Matrix GW/Chemw
Work.Group: WG33127
Method
LCS
\REC
90
swa.;6
Limits
\REC
74-119
8015
17, 2003
JD: AB4702
Davis & Floyd, Inc. \ PO Drawer 428 \ Greenwood, SC 2%48 I 816 (. Durst Avenue 1 Greenwood, SC 29649 I [phone] I Fax [phone]
14 5·
Df\YIS
FLOYD LABORATORY ANALYSIS REPORT
QC Batch Report
workGroup WG331Bl
Description: Toe GW
SaJnple ID
L03022403-06
L03022403-07
LCS33181: 1
LCS33181:2
MB33181:l
MB33181:2
MS03022407-18:33181
MS03022508·02:33181
MS003022407-18:33181
MSD03022508-02:J3181
Client ID
ITCI
ITCI OUP.
Laboratory Control Spike
Laboratory Control Spike
Method Blank
Method Blank
Matrix Spike
Matrix Spike
Matrix Spike Duplicate
Matrix Spike Duplicate
Run#
Re;:,ort D&.:.e :.:arch ;_ 7, 2003
Page 1 of : Re~::-rt ID, AB4667
GW/Chemw
Prep Mefr.::-j
h.:".altyica: Methe::: swe.;5 9060
PREP
Date Time
ANALYTICAL
Date Time
02/26/03 2150
02/26/03 2223
02/26/03 1833
02/27/03 0752
02/26/03 1906
02/27/03 0810
02/26/03 174 7
02/27/03 0117
02/26/03 1804
02/27/0) 0134
Analyst Dilution
CLB 40
CLB 40
CLB
CLE
CLB
CLB
CLB
CLB
CLB
CLB
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I (864) 229-441 3 I Fax [phone] l9
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DAYIS
FLOYD
Method Blanks
Parameter
Wet Chemistry
SWB46 9060
Blank
ORGANIC CARBON, TOTAL
MB33181: 1
LABORATORY ANALYSIS REPORT
Report Date March 1 7, 2003
Page 1 of 1 Report ID: AB466G
Matrix Gl-1/ChemW
WorkGroup: WG33181
Cone Qual RDL Units Analyst Date Time
! . 0 1.0 mg/1 CLB 02/26/03 1906
Davis & Floyd, Inc. l PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] 1 Fax !864) 229-7119
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Df\YIS
FLtfYD
Method Blanks
Parameter
Wet Chemistry
SW846 9060
Blank
ORGANIC CARBON, TOTAL
MB3318l:2
LABORATORY ANALYSIS REPORT
Report Date March 1 7, 2003
Page l of 1 Report ID: AB4670
Matrix GW/ChemW
WorkGroup: WG33181
Cone Qual RDL Units Analyst Date Time
' 1.0 1.0 mg/1 CLB 02/27/03 0810
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Di\YIS
FLOYD LABORATORY ANALYSIS REPORT
Matrix Spikes and Duplicates
MS/MSD
Parameter
ORGANIC CARBON, TOTAi,
Parameter.
ORGANIC CARBON, TOTAL
MS03022407-l8:33181
MSD03022407-18:33181
Spike
A.dded
20.00
Spike
A?ded
20. 00
Sample
Cone
1. 50
MSD
Cone
21. 05
Report Date March i 7, 2003
Page 1 of 1 Report ID: /\[34668
Matrix G;S/Chem',.;
workGroup: \S.J33i81
Method s:sa.;c 9060
MS MS Lirni ts
cone %REC \REC
21 . 03 98 7B-121
MSD Limits
\REC: %RPO \RPO \REC
98 0 10 78-121
I NOTE: MS/MSD \ recoveries are not evaluated if the sample concentration 1s greater than four times the spike added.
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Dl\VIS
FLtJYD LABORATORY ANALYSIS REPORT
Matrix Spikes and Duplicates
MS/MSD
Par.imcter
ORGANIC CARBON, TOTAL
Par.amet~r
ORGANIC CARBON, TOTAL
MSOJ022508-02:33181
MSDOJ022508·02:33181
Spike
Added
20.0'.l
Spike
Added
20. 00
Sample
Cone
4.60
MSD.
Cone<··
23.05
Report Date March 17, 2003
Page l of l Report ID: AB4671
Matrix GW/Chemw
workGroup: WG33181
Method SW846 9060
-~s MS Limits
Cone %REC \-REC
2 3. 93 97 78-121
MSD Lirf!its ..... \RPO \RPD \REC ,\REC
92 10 78-121
NOTS: MS/MSO \-recoveries are not evaluated if ~he sample concentration is greater than four times the spike added.
Davis & Floyd, Inc. I PO Drawer 428 I Greenwcxxl, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax (864) 2:!Y-7119
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D1\YIS
FLtrYD LABORATORY ANALYSIS REPORT
Laboratory Control Standards and Duplicates
LCS
Parameter·
ORGANIC CARBON, TOTAL
.: LCS33181:l
Spike
A.dded
1 0. 0 0
LCS
Cone
9. 3 0
Report Date March
Page 1 of l Report
Matrlx GW/ChemW
WorkGroup, WG33181
Method
LCS
%REC
93
SW846
Limits
%REC
90-110
9060
1 7, 2003
ID: AB4665
Davis & Floyd, Inc. l PO Drawer 428 I Greenwood, SC 29648 l 816 E. Durst Avenue 1 Greenwood, SC 29649 I [phone] I Fax [phone] l 9
151
D1\VIS
FLtrYD LABORATORY ANALYSIS REPORT
Laboratory Control Standards and Duplicates
LCS
Par:arriet~r
ORGANIC CARBON, TOTAL
LCS33181:2
·. S{)ike
~dded
10. 00
LCS
Cone
9. 14
Report Date March
Page l of l Report
Matr1x GW/Chernw
WorkGroup, WG33181
Method
LCS
\:<.EC
9l
SW846
Limits
\REC
90-110
9060
17, 200)
ID: AB4669
Davis & Floyd, Inc. ! PO Drawer 428 I Greenwood, SC 29648 1 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] ! Fax [phone]
15 2 ,
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D1\VIS
FLOYD
QC Batch Report
WorkGroup WG33205
Descript.ion: TOC GW
Sample ID Client ID
L03022403-05 ITEF
LABORATORY ANALYSIS REPORT
Run#
Report Date March 17, 2003
Page 1 of l Report ID: AB4675
Matrix GW/ChemW
Prep Method
Analtyical Method: SW846 9060
PREP
Date Time
ANALYTICAL
Date Time Analyat Dilution
LCS33205:l Laboratory Control Spike
02/27/03 1118
02/27/03 1752
02/27/03 1826
02/27/03 1611
02/27/03 1628
CLE
CLE
CLE
CLE
CLE
MB33205:1 Method Blank
MS03022508-06: 3 32 05 Matrix Spike
MSD03022508-06:33205 Matrix Spike Duplicate
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I fax [phone]
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Di\YIS
FLtJfD
Method Blanks
Parameter
Wet ChCJl\istry
SW846 9060
Blank
ORGANIC CARBON, TOTAL
MB33205: 1
LABORATORY ANALYSIS REPORT
Report Date Marcll 1 7, 2 003
Page l of l Report ID: AB-1673
Matrix GW/Chemw
workGroup, WG33205
Cone Qual RDL Units .Analyst Date Time
1,0 1,0 mg/1 CLB 02/27/03 1826
Davis & Floyd, Inc. j PO Drawer 428 I Greenwood, SC 29648 I 816·E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax (ll64) 229-7119
154
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DAYIS
FLtwD LABORATORY ANALYSIS REPORT
Matrix Spikes and Duplicates
MS/MSD
Parameter
ORGANIC CARBON, TOTAL
Paramete·r ·· ·
ORGANIC CARBON, TOTAL
MS03022508-06:33205
MSD03022508-06:33205
Spike
Added
20.00
Spike
Added
20.00
Sample
Coi;ic
5. 08
MSD
. C(>nC
2 3 . B 0
Report oa::e March 17' 200)
Page 1 of Report JD: AB4674
Matrix GW/ChernW
WorkGroup: WG33205
Method SW846 9060
;"\S MS Limits
Cone; %REC %REC
24.10 95 78-121
MSD L1mi ts
IREC · \RPD \RPO . l;REC
94 10 78-121
1. NOTE, MS/MSD % recoveries are not evaluated if the sample concentration >s greater than four times the spike added.
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D1\VIS
FLOYD LABORATORY ANALYSIS REPORT
Laboratory Control Standards and Duplicates
LCS
Parameter
ORGANIC CARBON, TOTAL
LCS33205:1
Spike
Added
10. 00
LCS
cone
9.40
Report Date March
Page 1 oC 1 Report
Matrix GW/Chemw
workGroup: WG3320S
Method
. LCS
\REC.·
94
SWB46
Limits
\REC
90-110
9060
17' 2 003
ID: A84672
Davis & Floyd, lnc. I PO Drawer 428 · I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 ] {864) 229-4413 ! Fax [phone]
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D1\VIS
FLOYD LABORATORY ANALYSIS REPORT
QC Batch Report
WorkGrou~ WG33240
Description, TOC Gw
Sample ID
L0]022703-08
L03022703-09
L03022703-10
LCS33240:
l,CS33240: 2
LCS33240:
M833240:
MB3324 0: 2
MB33240:
MS03022508-20:33240
MS03022712-02:33240
MSD03022508-20:33240
MSD03022712-02:33240
Client ID
K-28
V-23
V-23 DUP.
Laboratory Control Spike
Laboratory Control Spike
Laboratory Control Spike
Method Blank
Method Blank
Method Blank
Matrix Spike
Matrix Spike
Matrix Spike Duplicate
Matrix Spike Duplicate
Run#
1
Report Date March 17, 2003
Pa9e l of 1 Report ID: AB4682,
/-'.atrix GW/ChemW
t'rep Method
A~altyical Method: SWB46 9060
PREP
Date Time
ANALYTICAL
Date Time
03/03/03 2059
03/04/03 0946
03/04/03 1021
03/03/03 1832
03/04/03 0217
03/04/03 1049
03/03/03 1906
03/04/03 0229
03/04/03 1119
03/03/03 1746
03/04/03 0131
03/03/03 1803
03/04/03 0148
Analyst Dilution
CLB
CLH 2~)
CLB 25
CLB
CLB
CLB
CLB
Cl,B
CLB
CLB
CI,B
CLB
CLB
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I Wb4) 229-441] \ Fax [phone]
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Df\\71S
FLOYD
Method Blanks
Parruneter
Wet Chemiotry
SW846 9060
Blank
ORGANIC CARBON, TOTAL
.;. Ml3))240:1
LABORATORY ANALYSIS REPORT
Report. Date March 17, 2003
Page 1 of 1 Report ID: AB4677
Matrix GW/Chemw
WorkGroup: WG33240
Cone Qual RDL Units Analyst Date Time
1.0 1 . 0 mg/1 CLB 03/03/03 1906
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 ! [phone] I fax [phone]
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D}\VIS
FLtJ\'D
Parameter
Wet Chemistry
SW846 9060
Method Blanks
Blank .: MB33240:2
ORGANIC CARBON, TOTAL
LABORATORY ANALYSIS REPORT
Report Date March 17, 2003
Page l of l Repor::. ID: AB4 678
Matrix GW/ChemW
WorkGroup, WG33240
Cone Qual RDL Unite Analyst Date Time
< 1.0 l. 0 mg/1 CLB 03/04/0} 0229
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Dursl Avenue I Greenwood, SC 29649 l (864) 229-44 U I fax [phone]
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Di\YIS
FLOYD
Method Blanks
Parameter
Wet Chemistry
SW846 9060
Blank
ORGANIC CARBON, TOTAL
MB33240: 3
LABORATORY ANALYSIS REPORT
Repor-t Date March l7' 2003
Page l of l Report ID: AB4680
Matrix GW/Chemw
WorkGroup: WG33240
Cone Qual RDL Units Analyst Date Time
l , 0 LO mg/1 CLB 03/04/03 1119
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Dl\VIS
FLtJ\'D LABORATORY ANALYSIS REPORT
Matrix Spikes and Duplicates
MS/MSD
Paiamet€i"
ORGANIC CARBON, TOTAL
f)arame1;er
ORGI\NIC CARBON, TOTAL
MS03022508-20:33240
MSD03022506-20:33240
Spike
Added
20. 00
Spike
Added
20. 00
Sample
Cone
6 .85
MSD
Cone
27.90
Report Date March 17, 2 00]
Page l of l Report ID: AB46B3
Matrix GW/Chernw
WorkGroup: WG33240
Method SW846 9060
MS MS Limits
Cone \REC \REC
28.30 107 78-121
MSO. Limits
\REC \RPD \RPO \REC
105 10 78-121
I NOTE, MS/MSD % recoveries are not evaluated i( the sample concentration is greater than four times the spike added.
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Df\VIS
FLtn'D LABORATORY ANALYSIS REPORT
Matrix Spikes and Duplicates
MS/MSD
Parclm.~.t~r
ORGANIC CARBON, TOTAL
Parcime_t~i:-·,
ORGANIC CARBON, TOTAL
MSOJ022712-02:)3240
MSD03022il2-02:33240
S{)ik"e
:r.:ctaea
20.00
s·pikf:."
Adde·d
20. 00
Sample
Cone
' 1 .00
MSD
Cone
21 . 60
Report Date March 1 7, 2003
Page 1 of 1 Report iD: AB4684
Matrix GW/ChemW
WorkGroup: WG33240
Method SW84 6 9060
MS MS ~imits
Cone \REC \REC
20.90 105 78-121
. MS!) .Limits
. \_REC: \RPO \RPD. \REC
108 10 78-121
NOTE: MS/MSD \ recoveries are not evaluated if the sample concentration is greater than four times the spike added.
Davi~ & Floyd, Inc. I PO Drawer 428 \ Greenwood, SC 29648 I 816 E. Durst Avenue ! Greenwood, SC 29649 I [phone] I fax [phone]
162
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DAYIS
FLOYD LABORATORY ANALYSIS REPORT
Laboratory Control Standards and Duplicates
LCS
Parameter .
ORGANIC CARBON, TOTAL
~ LCS33240:l
Spike
Added
10 00
LCS
Cone
9.30
Report Date March
Page l of l Report
Matrix GW/ChemW
workGroup: WG33240
Method
LCS
11REC
93
SWB46
Limits
\REC
90-110
9060
17' 2003
ID: AB4676
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I (864) 22Y-4413 ! Fax [phone]
163
LABORATORY ANALYSIS REPORT
Laboratory Control Standards and Duplicates
LCS
Para:met"er ·
ORGANIC CARBON, TOTAL
.: LCS332i0:2
Spike
Added
10.00
LCS
Cone·
9 40
Report Date March
Page 1 of 1 Report
Matrix GW/Chernw
workGroup: WG33240
Method
LCS
\REC
94
SW846
Lifl1its
\REC
90-110
9060
1'. 2003
IO: AB4679
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue 1 Greenwood, SC 29649 I (864) 229-44 I .1 I Fax i864) 229-71 l 9
164
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D1\YIS
FLt1YD LABORATORY ANALYSIS REPORT
Laboratory Control Standards and Duplicates
LCS
Parameter
ORGANIC CARBON, TOTAL
; LCS33240:3
Spike
Added
10.00
LCS
Cone·
9.00
LCS
Report Date
Page 1 of 1
t-'.atrix
March 17, 200:;
Report ID: AB46El
GW/ChemW
WorkGroup: WG33240
t-'.ethod SW846 9060
· \REC
90
Limits
\-REC
90-110
I Davis & Floyd, Inc I PO Dr.1wer 428 I Greenwcxxl, SC 29648 \ 616 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
16 5 .
DAYIS
FLtlYD
April 03, 2003
PEM CARTER
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC ·28152
LABORATORY ANALYSIS REPORT
Login Number
Project Number
Description
:L03031317
:61621.01
:GROUNDWATER
Dear Pem Carter:
We are pleased to provide the enclosed analytical results for the samples received by
Davis & Floyd, Inc. on March 13, 2003.
A formal Quality Assurance/Quality Control program is maintained by Davis & Floyd,
which is designed to meet or exceed the EPA, NELAC or other appropriate regulatory
requirements. All analytical analyses for this project met QA/QC criteria and the
results are within the 99 % confidence interval for each method unless otherwise
stated in the footnotes. This report is to be reproduced only in full.
Feel free to contact our Client Services Representative at [phone] if further
explanation of the analysis is required. Unless other arrangements have been made,
samples will be disposed of or returned 14 days from the cfate of the report. We
appreciate the opportunity to provide services to your firm.
Sincerely,
DAVIS & FLOY , I C.
Jo n H. McCord, Jr.
aboratory Manager
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Oavis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 J 816E.1D&g' Avenue I Greenwood, SC 29649 I [phone] I Fax [phone] I
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DAYIS
FLtrYD LABORATORY ANALYSIS REPORT
NELAC Certification Number: £87633
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
PEM CARTER
Client I □.: PEW-1
Matrix
Parameter
Semivolatile o,rganics
SW846 8270C
1,2,4-TRICHLOROBENZENE
1,2-0ICHLOROBENZENE
1,3-DICHLOROBENZENE
1,4-DICHLOROBENZENE
GW/ChemW
2, 4, 5-TRICHLOROPHENOL
2,4,6-TRICHLOROPHENOL
2,4-DICHLOROPHENOL
2,4-DIMETHYLPHENOL
2,4-DINITROPHENOL
2,4-DINITROTOLUENE
2,6-DINITROTOLUENE
2-CHLORONAPHTHALENE
2-CHLOROPHENOL
2-METHYL-4,6-DINITROPHENOL
2-METHYLNAPHTHALENE
2-METHYLPHENOL
2-NITROANILINE
2-NITRO PHENOL
3,3'-DICHLOROBENZIDINE
3-NITROANILINE
4-BROMOPHENYL PHENYL ETHER
4-CHLORQ-3-METHYLPHENOL
4 CHLOROANILINE
4-CHLOROPHENYL PHENYL ETHER
4-METHYLPHENOL
4-NITROANILINE
4-NITROPHENOL
ACENAPHTHENE
ACENAPHTHYLENE
ANTHRACENE
BENZO(A)ANTHRACENE
BENZO (A) PYRENE
BENZO(B)FLUORANTHENE
BENZO(G,H,I)PERYLENE
BENZO(K)FLUORANTHENE
BENZOIC JI.CID
BENZYL ALCOHOL
BIS(2-CHLOROETHOXY)METHANE
BIS(2-CHLOROETHYL)ETHER
815{2-CHLOROISOPROPYL)ETHER
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648
NC Certification Number: 25
Result
0 . 010
< 0. 010
< 0 .010
< 0. 010
< o. 010
< 0. 010
< o. 010
< 0 .010
< 0. 025
< 0. 010
< 0 .010
< 0 .010
< 0 .010
< o. 025
< o. 010
< 0. 010
< 0 .010
< 0 .010
< 0 .010
< 0 . 010
< 0. 010
< 0. 010
< 0 .010
< 0 .010
< 0 .010
< 0 .010
< 0.025
< 0 .010
< 0. 010
< 0 .010
< 0 .010
< 0 .010
< o. 010
< o. 010
< 0 .010
< 0 .050
< 0 .010
< o. 010
< 0 .010
< 0 .010
816 E1 %u?' Avenue
Project Number: 61621-01
Report Date
Page 1 of 3
Sample ID
April 03, 2003
Report ID: AB5966
L03031317-01
Date Collected: 12-MAR-03 11:10
Date Received 13-MAR-03
Qual RDL Units Analyst Date
o . 010 mg/1 JRN 03/19/03
0 .010 mg/1 JRN 03/19/03
0 .010 mg/1 JRN 03/19/03
o. 010 mg/1 JRN 03/19/03
0. 010 mg/1 JRN 03/19/03
0. 010 mg/1 JRN 03/19/03
o. 010 mg/1 JRN 03/19/03
0. 010 mg/1 JRN 03/19/03
0 .025 mg/1 JRN 03/19/03
o. 010 mg/1 JRN 03/19/03
o. 010 mg/1 JRN 03/19/03
o. 010 mg/1 JRN 03/19/03
0 .010 mg/1 JRN 03/19/03
0. 025 mg/1 JRN 03/19/03
o. 010 mg/1 JRN 03/19/03
0 .010 mg/1 JRN 03/19/03
0 .010 mg/1 JRN 03/19/03
o. 010 mg/1 JRN 03/19/03
0 .010 mg/1 JRN 03/19/03
0 . 010 mg/1 JRN 03/19/03
0 .010 mg/1 JRN 03/19/03
0 .010 mg/1 JRN 03/19/03
0 .010 mg/1 JRN 03/19/03
0 .010 mg/1 JRN 03/19/03
0 .010 mg/1 JRN 03/19/03
o. 010 mg/1 JRN 03/19/03
o. 025 mg/1 JRN 03/19/03
0 .010 mg/1 JRN 03/19/03
o. 010 mg/1 JRN 03/19/03
0 .010 mg/1 JRN 03/19/03
0 .010 mg/1 JRN 03/19/03
o. 010 mg/1 JRN 03/19/03
o. 010 mg/1 JRN 03/19/03
o. 010 mg/1 JRN 03/19/03
0. 010 mg/1 JRN 03/19/03
o. 050 mg/1 JRN 03/19/03
0 .010 mg/1 JRN 03/19/03
0 .010 mg/1 JRN 03/19/03
0 .010 mg/1 JRN 03/19/03
0 .010 mg/1 JRN 03/19/03
Time
1549
1549
1549
1549
1549
1549
1549
1549
154 9
1549
154 9
154 9
154 9
1549
1549
1549
1549
1549
1549
1549
1549
154 9
1549
1549
1549
1549
1549
1549
1549
1549
154 9
1549
1549
154 9
1549
1549
1549
1549
1549
1549
Greenwood, SC 29649 I [phone] I Fax [phone]
DAYIS
FLOYD LABORATORY ANALYSIS REPORT
NELAC Certification Number: £87633
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
PEM CARTER
Client ID: PEW-1
Parameter
BIS(2-ETHYLHEXYL)PHTHALATE
BUTYL BENZYL PHTHALATE
CHRYSENE
01-N-BUTYL PHTHALATE
DI-N-OCTYL PHTHALATE
OIBENZ(A,H)ANTHRACENE
DIBENZOFURAN
DIETHYL PHTHALATE
DIMETHYL PHTHALATE
FLUORANTHENE
FLUORENE
HEXACHLOROBENZENE
HEXACHLOROBUTADIENE
HEXACHLOROCYCLOPENTADIENE
HEXACHLOROETHANE
INDENO(l,2,3-CD)PYRENE
ISOPHORONE
N-NITROSODI-N-PROPYLAMINF.
N-NITROSODIPHENYLAMINE
NAPHTHALENE
NITROBENZENE
PENTACHLOROPHENOL
PHENANTHRENE
PHENOL
PYRENE
SW846 8270C DOWTHERM
1, 1' -BI PHENYL
BIPHENYL ETHER
Volatile Organics
SW846 8260B
1,1,1-TRICHLOROETHANE
1,1,2,2-TETRACHLOROETHANE
1 , 1, 2 -TR I CHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
1,2-DICHLOROETHANE
1,2-DICHLOROPROPANE
2-BUTANONE
2-HEXANONE
4-METHYL-2-PENTANONE
ACETONE
Result
< 0 .010
< o. 010
< o. 010
< 0 .010
0 .010
< 0 .010
< 0. 010
< 0 .010
< 0 .010
< 0 .010
< o. 010
< 0 .010
< 0 .010
< 0. 010
< o. 010
< 0. 010
0 .010
< o. 010
< 0.010
0 .010
0. 010
< 0.025
< 0 .010
< 0 .010
0 .010
< o. 010
< 0 .010
< o. 0050
0 . 0050
< o. 0050
< o. 0050
< 0 . 0050
< 0 .ooso
< o. 0050
< 0.010
< 0.010
< 0.0050
< 0. 010
NC Certification Number: 25
Project !Jurnber: 61621.01
Report Date April 03, 2003
Page 2 of 3 Report ID: AB5966
Sample ID L03031317-0l
Qual RDL Units Analyst Date Time
0 .010 mg/1 JRN 03/19/03 1549
0 .010 mg/1 JRN 03/19/03 1549
0 .010 mg/1 JRN 03/19/03 154 9
0 .010 mg/1 JRN 03/19/03 1549
0 .010 mg/1 JRN 03/19/03 1549
0 .010 mg/1 JRN 03/19/03 1549
0 .010 mg/1 JRN 03/19/03 1549
0 .010 mg/1 JRN 03/19/03 1549
0 .010 mg/1 JRN 03/19/03 1549
0. 010 mg/1 JRN 03/19/03 1549
0 .010 mg/1 JRN 03/19/03 1549
0 .010 mg/1 JRN 03/19/03 154 9
0 .010 mg/1 JRN 03/19/03 1549
0. 010 mg/1 JRN 03/19/03 1549
0 .010 mg/1 JRN D3/19/03 154 9
0. 010 mg/1 JRN 03/19/03 154 9
0 .010 mg/1 JRN 03/19/03 1549
0 .010 mg/1 JRN 03/19/03 1549
0 .010 mg/1 JRN 03/19/03 154'9
0 .010 mg/1 JRN 03/19/03 1549
0. 010 mg/1 JRN 03/19/03 1549
0 .025 mg/1 JRN 03/19/03 1549
o. 010 mg/1 JRN 03/19/03 1549
0 .010 mg/1 JRN 03/19/03 1549
0 .010 mg/1 JRN 03/19/03 1549
0 .010 mg/1 JRN 03/19/03 1549
0 .010 mg/1 JRN 03/19/03 154 9
o. 0050 mg/1 PAP 03/18/03 1034
0 .0050 mg/1 PAP 03/18/03 1034
0. 0050 mg/1 PAP 03/18/03 1034
0. 0050 mg/1 PAP 03/18/03 1034
0 .0050 mg/1 PAP 03/18/03 1034
0 . 0050 mg/1 PAP 03/18/03 1034
0 .0050 mg/1 PAP 03/18/03 1034
0.010 mg/1 PAP 03/18/03 1034
0. 010 mg/1 PAP 03/18/03 1034
0.0050 mg/1 PAP 03/18/03 1034
0.010 mg/1 PAP 03/18/03 1034
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E.f~rAI Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
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DAYIS
FLOYD LABORATORY ANALYSIS REPORT
NELAC Certification Number: £87633
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
PEM CARTER
Client ID· PEW-1
Parameter
BENZENE
BROMODICHLOROMETHANE
BROMOFORM
BROMOMETHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-DICHLOROETHENE
CIS-1,3-DICHLOROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-DICHLOROETHENE
TRANS-1,3-DICHLOROPROPENE
TR I CHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL)
Prep Procedure
Analytical Prep Procedures=
BNA SEMIVOLATILES
DOWTHERM
Method
SW846 35008
SW846 35008
Result
' 0 .0050
' 0 . 0050
0 .0050
' 0.010
' 0 .0050
' 0. 0050
' 0 .0050
' 0.010
' 0.0050
' 0.010
0 .0050
' 0. 0050
' 0 .0050
' 0 .0050
' 0 . 0050
' 0 . 0050
< 0 . 0050
< 0 .0050
' 0 . 0050
' 0 . 0050
0.0061
< 0 .010
< o. 010
< 0.0050
Analyst Prep Date
DBC 03/17/03
DBC 03/17/03
NC Certification Number: 25
Project Number, 61621.01
Report Date Apri 1 03, 2 003
Page 3 of 3 Report 1D: AB5966
Sample ID L03031317-01
Qual RDL Units Analyst Date Time
0 . 0050 mg/1 PAP 03/18/03 1034
o . 0050 mg/1 PAP 03/18/03 1034
0 .0050 mg/1 PAP 03/18/03 1034
0. 010 rrg / 1 PAP 03/18/03 1034
0 . 0050 mgjl PAP 03/18/03 103 4
0. 0050 mg/1 PAP 03/18/03 1034
0 .0050 mg/1 PAP 03/18/03 1034
0.010 mg/1 PAP 03/18/03 1034
0.0050 mg/1 PAP 03/18/03 1034
0.010 mg/1 PAP 03/18/03 1034
0 .0050 mg/1 PAP 03/18/03 1 034
0 .0050 mg/1 PAP 03/18/03 1034
0 . 0050 mg/1 PAP 03/18/03 1034
0.0050 mg/1 PAP 03/18/03 1034
0 . 0050 rng/1 PAP 03/18/03 1034
0 . 0050 mg/1 PAP 03/18/03 1034
0 .0050 mg/1 PAP 03/18/03 1034
0. 0050 mg/1 PAP 03/18/03 1034
o . 0050 mg/1 PAP 03/18/03 1034
0 . 0050 mg/1 PAP 03/18/03 1034
0 .0050 mg/1 PAP 03/18/03 1034
0 .010 mg/1 PAP 03/18/03 1034
0. 010 mg/1 PAP 03/18/03 1034
0.0050 mg/1 PAP 03/18/03 1034
0800
0800
I Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 ) 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
169 ,
Df\YIS
FLOYD LABORATORY ANALYSIS REPORT
NELAC Certification Number: £87633
Clhmt
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
PEM CARTER
Client ID_: TRIP BLANK
Matrix
Parameter
Volatile Organics
SW846 82608
1,1,1-TRICHLOROETHANE
1,1,2,2-TETRACHLOROETHANE
1,1,2-TRICHLOROETHANE
l , l • DICHLOROETHANE
1,l-DTCHLOROETl!ENE
1, 2-DICHLOROETHANE
1, 2-DICHLOROPROPANE
~-BUTANONE
2-HEXANONE
4-METHYL-2-PENTANONE
ACETONE
BENZENE
BROMODICHLOROMETHANE
BROMOFORM
BROMOMETHANE
CARBON~□ISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1, 2-DICHLOROETHENE
CIS · 1, 3-DICHLOROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-DICHLOROETHENE
TRANS-1,3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL)
GW/ChemW
Davis & Floyd, Inc. ! PO Drawer 428 \ Greenwood, SC 29648 I
NC Certification Number: 25
Result
' 0 .0050
' 0 .0050
' 0.0050
' 0. 0050
' 0. 0050
' 0 .0050
' 0 .0050
' 0.010
' 0.010
' 0.0050
' 0.010
' 0.0050
' 0.0050
' 0.0050
' 0.010
' 0.0050
' 0 .0050
' 0 . 0050
' 0.010
' 0.0050
' 0.010
' 0 .0050
' 0 .0050
' 0 . 0050
' 0. 0050
' 0. 0050
' 0 . 0050
' 0 .0050
' o. 0050
' 0 . 0050
' 0 .0050
' 0. 0050
' 0.010
' 0.010
' 0.0050
816 E. Durst Avenue 170
Project Number: 61621.01
Report Date
Page 1 of 1
Sample ID
April 03, 2003
Report ID: AB5965
L03031317-02
Date Collected: 12-MAR-03 07:45
Date Received 13-MAR-03
Qual RDL Units Analyst Date
0 .0050 mg/1 PAP 03/19/03
o. 0050 mg/1 PAP 03/19/03
0. 0050 mg/1 PAP 03/19/03
0 . 0050 mg/1 PAP 03/19/03
0 .0050 mg/l PAP 03/19/03
0. 0050 mg/1 PAP 03/19/03
0 .0050 mg/1 PAP 03/19/03
0 .010 mg/1 PAP 03/19/03
0. 010 mg/1 PAP 03/19/03
0.0050 mg/1 PAP 03/19/03
0. 010 mg/1 PAP 03/19/03
0 . 0050 mg/1 PAP 03/19/03
0 . 0050 mg/1 PAP 03/19/03
o. 0050 mg/1 PAP 03/19/03
0. 010 mg/1 PAP 03/19/03
0 .0050 mg/1 PAP 03/19/03
0. 0050 mg/1 PAP 03/19/03
0. 0050 mg/1 PAP 03/19/03
0.010 mg/1 PAP 03/19/03
0.0050 mg/1 PAP 03/19/03
0.010 mg/1 PAP 03/19/03
0 .0050 mg/1 PAP 03/19/03
0 .0050 mg/1 PAP 03/19/03
0 .0050 mg/1 PAP 03/19/03
0 . 0050 mg/1 PAP 03/19/03
o. 0050 mg/1 PAP 03/19/03
0 . 0050 mg/1 PAP 03/19/03
0 . 0050 mg/1 PAP 03/19/03
0 .0050 mg/1 PAP 03/19/03
o . 0050 mg/1 PAP 03/19/03
0 . 0050 mg/1 PAP 03/19/03
o. 0050 mg/1 PAP 03/19/03
0.010 mg/1 PAP 03/19/03
O. 010 mg/1 PAP 03/19/03
0.0050 mg/1 PAP 03/19/03
Time
1542
1542
1542
1542
1542
1542
1542
1542
1542
1542
1542
1542
1542
1542
1542
1542
1542
1542
1542
1542
1542
1542
1542
1542
1542
1542
1542
1542
1542
1542
1542
1542
1542
1542
1542
j Greenwood, SC 29649 ( [phone] I Fax [phone]
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DL\VIS
FLOYD LABORATORY ANALYSIS REPORT
Method Conformance Summary
Client: Ticona, LLC
Login(s): LOJOJ I J 17
Criteria Volatiles
Samnle Holdin, Time
Standards Preoaration
Instrument Tunino
Instrument Calibration
Calibration Verification
De•radation Check
Interference
SamolelStandard
Blanks Results
Method Accuracv
Method Precision
Surroeate Recove~
PDSISD/MSA
TCLP Prenaration
Key ✓
NIA
Met Criteria Met
Not Applicable
✓
✓
✓
✓
✓
NIA
NIA
✓
✓
✓
✓
NIA
NIA
Semi
Volatiles
✓
✓
✓
✓
✓
NIA
NIA
✓
✓
✓
✓
NIA
NIA
Metals
NIA
NIA
NIA
NIA
NIA
NIA
NIA
NIA
NIA
NIA
NIA
NIA
NIA
*
PDS =
SD =
MSA=
Method Criteria Not Met -Seefootnote(s) below.
Post Digestion Spike
Serial Dilution
Method of Standard Additions
Project Number: 61621.01
Report Date: March 21, 2003
Ethylene
TOC Glvcol
NIA NIA
NIA NIA
NIA NIA
NIA NIA
NIA NIA
NIA NIA
NIA NIA
NIA NIA
NIA NIA
NIA NIA
NIA NIA
NIA NIA
NIA NIA
Footnotes: Volatiles -Sample other than client sample used for MSIMSD.
I Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E1 o/f' ~venue I Greenwood, SC 29649 I 1864) 229-4413 I fax [phone]
DAYIS
FLbYD LABORATORY ANALYSIS REPORT
NELAC Certification Number: £87633 NC Certification Number: 25
Master Tracking List
Client
Contact
Sample ID
L03031317-0l
Somivolatile Organics
SWB46 8270C
SW846 8210C DOWTHERM
Volatile Organics
SW846 8260B
L03031317-02
Volatile Organics
SW846 8260B
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
PEM CARTER
Client ID
PEW-1
Project Number: 61621.01
Report Date
Page 1 of 1
Date Collected
12-MAR-03 11:10
April 03, 2003
Report ID: AB5964
Date Received
13-MAR-03
03/17/03 0800
03/17/03 0800
03/19/03 1549
03/19/03 1549
03/18/03 1034
TRIP BLANK 12-MAR-03 07:45
03/19/03 1542
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Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E1~,f Avenue I Greenwood, SC 29649 I 18641229-4413 I fax [phone] I
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DAYIS
FLbYD LABORATORY ANALYSIS REPORT
QC Batch Report
WorkGroup WG33405
Description: V0/8260/TCL
Slllllple ID
L03031317-0l
LCS33405:l
MB33405: 1
MS03031311-11.33405
MSD03031311-ll:33405
Client ID
PEW-1
Laboratory Control Spike
Method Blank
Matrix Spike
Matrix Spike Duplicate
Report Date
Page 1 of
Matrix
Prep Method
Analtyical
PREP
R=# Date Time
1
March 24, 200)
Report ID: AB5389
GW/ChemW
Method: SW846 82608
ANALYTICAL
Date Time Analyst Dilution
03/18/03 1034 PAP
03/18/0) 1625 PAP
03/18/03 0841 PAP
03/18/03 1524 PAP 1
03/18/03 1555 PAP 1
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 \ 81 & E1 9u3~t ~venue I Greenwood, SC 29649 I [phone] I Fax [phone]
Df\VIS
FLOYD LABORATORY ANALYSIS REPORT
Surrogates % Recovery
_Me·asUieoB.te
L03031317-0l
LCS33405:l
M833405:l
MS03031311 11:33405
MSD03031311-ll:33405
18-MAR-03
18-MAR-03
18-MAR-03
18-MAR-03
lB-MAR-03
DCE 1,2-DICHLOROETHANE-D4
BFB BROMOFLUOROBENZENE
TOL TOLUENE-DB
1 0: 34
16 :25
08: 41
15 : 24
15: 55
DCE:
81 ~ 1:4_2:_
105
105
98
109
108
::.:·s·Fn
92
94
89
92
94
Report Date
Page 1 of
Matrix
WorkGroup:
Method
····.--.TOI/-'-.
105
103
101
102
103
1
March "' 2 003
Report JD: A85394
GW/ChemW
WG33405
SW846 82 60
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Dav;s & Floyd, Inc I l'O D,awe, 428 I G,eenwood, SC 29648 I 816 Ej 74st Avenue I G,eenwood, SC 29649 I [phone] I Fax [phone] I
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I D~S FL D LABORATORY ANALYSIS REPORT
I
Method Blanks
I
I Report Date March 24, 2003
Page 1 of 1 Report ID, AB5381
Matrix GW/Chemw
I Blank MB33405:l WorkGroup: WG33405
Parameter Cone Qual RDL Units Analyst Date Time
I Volatile Organics
SW846 8260B
l,l,l-TRICHL9ROETHANE 5 .o 5. 0 ug/1 PAP 03/18/03 0841
I 1,1,2,2-TETRACHLOROETHANE < 5 .o 5 .o ug/1 PAP 03/18/03 0841
1, 1,2-TRICHLOROETHANE < 5 , 0 5 .o ug/1 PAP 03/18/03 0841
1,1-DICHLOROETHANE < 5, 0 5, 0 ug/1 PAP 03/18/03 0841
1,1-DICHLOROETHENE < 5, 0 5, 0 ug/1 PAP 03/18/03 0841
I 1,2-DICHLOROETHANE < 5 .o 5. 0 ug/1 PAP 03/18/03 0841
1,2-DICHLOROPROPANE < 5. 0 5 .0 ug/1 PAP 03/18/03 0841
2-BUTANONE < 10. 0 10 .0 ug/1 PAP 03/18/03 0841
2-HEXANONE 10. 0 10, 0 ug/1 PAP 03/18/03 0841
I 4-METHYL-2-PENTANONE 5. 0 5. 0 ug/1 PAP 03/18/03 084.l
ACETONE < 10. 0 10. 0 ug/1 PAP 03/18/03 0841
BENZENE < 5, 0 5. 0 ug/1 PAP 03/18/03 0841
I BROMODICHLOROMETHANE < 5, 0 5 .o ug/1 PAP 03/18/03 0841
BROMOFORM < 5, 0 5. 0 ug/1 PAP 03/18/03 0841
BROMOMETHANE < 10 .o 10, 0 ug/1 PAP 03/18/03 0841
CARBON DISULFIDE < 5. 0 5. 0 ug/1 PAP 03/18/03 0841
I CARBON TETRACHLORIDE < 5 .o 5. 0 ug/1 PAP 03/18/03 0841
CHLOROBENZENE < 5, 0 5. 0 ug/1 PAP ◊3/18/03 0841
CHLOROETHANE 10. 0 10, 0 ug/1 PAP 03/18/03 0841
I CHLOROFORM < 5 .0 5. 0 ug/1 PAP 03/18/03 0841
CHLOROMETHANE < 10. 0 10 ,0 ug/1 PAP 03/18/03 0841
CIS-1,2-DICHLOROETHENE < 5. 0 5 .0 ug/1 PAP 03/18/03 0841
CIS-1,3-DICHLOROPROPENE < 5. 0 5, 0 ug/1 PAP 03/18/03 0841
I DIBROMOCHLOROMETHANE < 5, 0 5. 0 ug/1 PAP 03/18/03 0841
ETHYLBENZENE ,. ' 5 ,0 5. 0 ug/1 PAP 03/18/03 0841
METHYLENE CHLORIDE < s, 0 5 .o ug/1 PAP 03/18/03 0841
STYRENE < 5 .o 5 .o ug/1 PAP 03/18/03 0841
I TETRACHLOROETHENE < 5 . 0 5 .o ug/1 PAP 03/18/03 0B41
TOLUENE < 5 .o 5. 0 ug/1 PAP 03/18/03 0841
TRANS-1,2-DICHLOROETHENE < 5. 0 5. 0 ug/1 PAP 03/18/03 0841
I TRANS-1, 3 -OICHI..OROPROPENE < 5 .o 5. 0 ug/1 PAP 03/18/03 0841
TRICHLOROETHENE < 5. 0 5 .o ug/1 PAP 03/18/03 0841
VINYL ACETATE < 10. 0 10 .o ug/1 PAP 03/18/03 0841
VINYL CHLORIDE < 10. 0 l O. 0 ug/1 PAP 03/18/03 0841
I XYLENE (TOTAL) < 5. 0 5. 0 ug/1 PAP 03/18/03 0841
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I Davis & Floyd, Inc. I PO Drawer 428 \ Greenwood, SC 2964B I 816 E. Durst Avenue l Greenwood, SC 29649 I [phone] j Fax [phone]
1 7 5, ,
DAYIS
FLtJ\1D LABORATORY ANALYSIS REPORT
Matrix Spikes and Duplicates
MS/MSD
. . · ·:···.::,•.:·--. Para~~\1/: _-:.
1,1-DICHLOROETHENE
1,2-DICHLORO~THANE
2-BUTANONE
BENZENE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROFORM
TETRACHLOROETHENE
TRICHLOROETHENE
VINYL CHLORIDE
1,1-DICHLOROETHENE
1,2-DICHLOROETHANE
2-BUTANONE
BENZENE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROFORM
TETRACHLOROETHENE
TRICHLOROETHENE
VINYL CHLORIDE
MS030313ll-ll:33405
MSD03031311-ll:JJ405
. _ sp{ke . : < ·Added · .-.
50.00
50.00
50.00
50.00
50.00
so.oo
50.00
50.00
50.00
50.00
50. 00
so. 00
50 .oo
50. 00
50. 00
50•, 00
50 .00
50. 00
50 . 00
50. 00
Report Date March 24, 2003
Page 1 oE Report ID: AB5386
Matrix GW/ChemW
workGroup: WG33405
Method SW846 82608
----s~~Pie':•::· :-.Ms-:.: '"•MS.
· ::cJric · t;ryt:./: .... · /\ii~
'':-·:::;::~i"~\<~·--:
\RE_C>,
71-121
78-141
38-176
79-116
75-128
91-115
80-127
73-115
74-117
61-123
< 5.00
< 5. 00
< 10.00
< 5.00
< 5.00
< 5.00
< 5.00
< 5.00
< 5.00
< 10.00
41 . 92
47. 59
28 . 40
46. 86
46. 50
47 .22
47 . 40
44 .16
45 . 36
31 . 71
41. 47
47. 60
28. 52
46. 72
46. 08
46 .85
47 . 28
42 .89
45 . 46
31 .49
84
95
57
94
93
94
95
88
91
63
83
95
57
93
92
94
95
86
91
63
13 71-121
0 16 78-141
0 44 38-176
0 13 79-116
13 75-128
13 81-115
0 14 80-127
14 73-115
0 13 74-117
15 61-123
NOTE: MS/MSD l recoveries are not:evaluated if the sample concentration is greater than four times the spike added.
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D1\VIS
FLlWD LABORATORY ANALYSIS REPORT
Laboratory Control Standards and Duplicates
LCS
·: .. ~~-~~i~-te:;,/: :::
1, 1-DICHLOROETHENE
1,2-DICHLORO~THANE
2-BUTANONE
BENZENE
CARBON TETRACHLORIDE
C!:ILOROBENZENE
CHLOROFORM
TETRACHLOROETHENE
TRICHLOROETHENE
VINYL CHLORIDE
LCS33405: 1
Sp.i"k~
· ··f\.d_ded
20 .00
20 .00
20 . 00
20 .00
20, 00
20, 00
20. 00
20 .00
20. 00
20 , 00
:-LCS ··.·
:·(c;ri~ ..
16. 62
18, 54
10, 1'
l 'I , 93
17 . 96
18.81
18. 65
17 . 32
17. 19
12 ,32
Report Date March 24, 2003
Page l of l Report ID: AB5382
Matrix GW/ChemW
workGroup: WG33405
Method SW846 8260B
.-LCS LiinitS
\-~EC \REC
83 76-121
93 86-141
51 32 -18!:j
90 84-119
90 79-127
94 86-118
93 83-129
87 75-118
86 76-116
62 61-130
Davis & Floyd, lnc. I PO Drawer 428 I Greenwood, SC 29648 I 81 b E1 [rrr. Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
DAYIS
FLm1D
QC Batch Report
WorkGroup_ WG33422
Description: V0/8260/TCL
Sample ID Client ID
L03031317-02, TR!P BLANK
LABORATORY ANALYSIS REPORT
Run#
Report Date March 24, 2003
Page 1 of 1 Report ID: AB5390
Matrix GW/ChemW
Prep Method
Analtyical Method: SW846 8260B
PREP
Date Time
ANALYTICAL
Date Time Analyst Dilution
03/19/03 1542 PAP
LCS33422:l Laboratory Control Spike 03/19/03 1643
03/19/03 0818
03/19/03 1613
PAP
PAP
PAP
MB33422:l Method Blank
MS03031401-0l: 33422 Matrix Spike 1
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Df\VIS
FL(j\1D LABORATORY ANALYSIS REPORT
Surrogates % Recovery
L03031317-02
LCS33422: 1
M833422:l
MS03031401-0l:33422
19-MAR-03 15:42
19-MAR-03 16 43
19-MAR-03 08:1B
19-MAR-03 16:13
DCE 1,2-DICHLOROETHANE-D4
BFB BROMOFLUOROBENZENE
TOL TOLUENE-DB
:oc~_:'·
·_a1~··1,i":2
116
107
105
100
-BFB .)-~):; 1?: ..
93
90
95
85
Report Date
Page 1 of
Matrix
March 24, 2003
Report ID: AB5395
GW/ChemW
WorkGroup: WG33422
Method
TOL''·: ~-/-i1·0 :· -
107
102
106
96
SW846 8260
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 ] 8161. f~t' Avenue I Grl'enwood, SC 29649 I [phone] I Fax [phone]
Di\VIS
FLtwD
Method Blanks
Blank
Parameter
Volatile Organics
SW846 82608
l,l,1-TRICHLOROETHANE
1,1,2,2-TETRACHLOROETHANE
1, 1,2-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
1,2-DICHLOROETHANE
1,2-DICHLOROPROPANE
2-BUTANONE
2-HEXANONE
4-METHYL-2-PENTANONE
ACETONE
BENZENE
BROMQDICHLOROMETHANE
BROMOFORM
BROMOMETHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-DICHLOROETHENE
CIS-1, 3-DICHLOROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-DICHLOROETHENE
TRANS-1,3-0ICHLOROPROPENE
TRICHLOROETHENE
Vll'ITL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL)
MB33422: 1
I
LABORATORY ANALYSIS REPORT I
I
I
Report Date March 24. 2003
Page l of l Report ID: ABS387 I
Matrix GW/ChemW
WorkGroup, WG33422
Cone Qual RDL Units Analyst Date Time I
I
' 5. 0 5. 0 ug/1 PAP 03/19/03 0818
' 5. 0 5 .0 ug/1 PAP 03/19/03 0818
< 5. 0 5 .0 ug/1 PAP 03/19/03 0818
' 5 .o 5 .0 ug/1 PAP 03/19/03 0818 I
5 .o 5. 0 ug/1 PAP 03/19/03 0818
' 5 .0 5 .o ug/1 PAI' 03/19/03 0818
' 5. 0 5 .o ug/1 PAP 03/19/03 0818
' 10. 0 10 .0 ug/1 PAP 03/19/03 0818 I
< 10. 0 l 0. 0 ug/1 PAP 03/19/03 0818
' 5. 0 5. 0 ug/1 PAP 03/19/03 0818
' 10. 0 10. 0 ug/1 PAP 03/19/03 0818 I
' 5 . 0 5. 0 ug/J PAP 03/19/03 0818
' 5. 0 5. 0 ug/1 PAP 03/19/03 0818
5 .o 5. 0 ug/1 PAP 03/19/03 0818
< 10. 0 10. 0 ug/1 PAP 03/19/03 0818 I
' 5. 0 5. 0 ug/1 PAP 03/19/03 0818
' 5 .o 5. 0 ug/1 PAP 03/19/03 0818
' 5 .o 5. 0 ug/1 PAP 03/19/03 0818
< l 0. 0 10. 0 ug/1 PAP 03/19/03 0818 I
< 5. 0 5 .0 ug/1 PAP 03/19/03 0818
' 10 .o 10. 0 ug/1 PAP 03/19/03 0818
' 5. 0 5 .o ug/1 PAP 03/19/03 0818 I
' 5. 0 5. 0 ug/1 PAP 03/19/03 0818
< 5. 0 5. 0 ug/1 PAP 03/19/03 0818
< 5 .o 5 .0 ug/1 PAP 03/19/03 0818
< 5. 0 5 .0 ug/1 PAP 03/19/03 0818 I
' 5 .0 5 .0 ug/1 PAP 03/19/03 0818
< 5.0 5. 0 ug/1 PAP 03/19/03 0818
< 5.0 5. 0 ug/1 PAP 03/19/03 0818
< 5 .o 5 .0 ug/1 PAP 03/19/03 0818 I
< 5 . 0 5 . 0 ug/1 PAP 03/19/03 0818
5. 0 5. 0 ug/1 PAP 03/19/03 0818
< 10.0 10. 0 ug/1 PAP 03/19/03 0818 I
< 10 .o 10. 0 ug/1 PAP 03/19/03 0818
5.0 5. 0 ug/J PAP 03/19/03 0818 I
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Dav;s & Floyd, Inc. I PO Ornwer 428 I Greenwood, SC 29648 I 816 Ej ~uQSI Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]'1 I
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D}\VIS
FLOYD LABORATORY ANALYSIS REPORT
Matrix Spikes and Duplicates
MS/MSD
,·Pi:Iie ~i·J ::: _::. ::
1,1-DICHLOROETHENE
1, 2-DI CHLOROE,THANE
2-BUTANONE
BENZENE
CARBON TETRACHLORIDE
CHLORQBENZENE
CHLOROFORM
TETRACHLOROETHENE
TRICHLOROETHENE
VINYL CHLORIDE
MS03031401-0l:33422
MSD0303140l-01:33422
· sPi·k~li
·,'Acid~ct··
50.00
50.00
so 00
50 00
50.00
50. 00
50.00
50.00
50.00
50.00
···.·~-am~~-~::-":.
· c;oi-;,c :·-·
5 .oo
< 5. 00
< 10.00
< 5. 00
< 5. 00
< 5. 00
< 5 .oo
10.09
5.00
< 10.00
Report Date March 24' 2003
Page 1 of Report ID: A85388
Matrix GW/ChemW
WorkGroup: WG33422
Method SW846 8260B
.. MS MS .-:-!-,'imits .. ·•., . .¢on·c .. ·:.%REC .·:t"R1tG·
39 .57 79 71-121
45. 32 91 78-141
26 . 41 53 38-176
42 .08 84 79-116
" .57 89 75-128
" . 70 89 81-115
45, 15 90 80-127
52. 13 84 73-115
41 .16 82 74-117
32 . 40 65 61-123
NOTE: MS/MSD % recoveries are not evaluated if the sample concentration is greater than four times the spike added.
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 \ 816 E Qurst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
1 ti 1 •
D1\VIS
FLOYD LABORATORY ANALYSIS REPORT
Laboratory Control Standards and Duplicates
LCS
::._.,~a)~~:e-.J~\;:/-· ..
1,1-DICHLOROETHENE
1, 2 ·DICHLORO_ETHANE
2-BUTANONE
BENZENE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROFORM
TETRACHLOROETl-!ENE
TR I CHLOROETHENE
VINYL CHLORIDE
LCS33422: 1
Report Date
Page 1 of 1
Matrix
March 24, 2003
Report IO: AB53B3
GW/ChemW
WorkGroup: WG33422
Method SW846 82608
·spi~e LCS · LCS · L•.iffii t;;
:•-A·ct,iect< · .·. :=~;i\(>-.·.· .. '::·::\'R~C.-?? ·-\::·:-t~if// = ..
20. 00 15 . 66 78 76-121
20. 00 19. 14 96 86-141
20 00 10. 10 51 32-185
20. 00 18 23 91 84-119
20 . 00 18. 33 92 79-127
20 . 00 19. 17 96 86-118
20. 00 19. 13 96 83-129
20. 00 17 .51 BB 75-118
20 00 17 68 88 76-116
20. 00 13 . 51 68 61-130
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DAYIS
FLtwD LABORATORY ANALYSIS REPORT
QC Batch Report
WorkGroup WG33391
Description: sv/8270/bna/tcl sv/dow
Sample ID
L03031317-01
LCS33391: 1
M833391: 1
MS03031317-0l:33391
MS03031405-04:33391
MSD0J031317-01: 33391
MSD03031405-04:33391
Client ID
PEW-1
Laboratory Control Spike
Method Blank
Matrix Spike
Matrix Spike
Matrix Spike Duplicate
Matrix Spike Duplicate
1
1
1
Report Date
Page 1 of 1
Matrix
Prep Method
Analtyical
PREP
Date Time
03/17/03 0800
03/17/03 0800
03/17/03 0800
03/17/03 0800
03/17/03 0800
03/17/03 0800
03/17/03 0800
March 24, 2003
Report ID: AB5384
GW/ChemW
SW846 35008
Method: SW846 8270C
ANALYTICAL
Date Time Analyst Dilution
03/19/03 1549 JRN
03/19/03 1218 JRN
03/19/03 1059 JRN
03/20/03 1145 JRN
03/19/03 2033 JRN
03/19/03 1716 JRN 1
03/20/03 1312 JRN
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 81 b F1 ~l~Sf '..venue I Greenwood, SC 29649 l {864) 229-4413 I Fax [phone]
Dl\VIS
FLMD LABORATORY ANALYSIS REPORT
Surrogates % Recovery
L03031317-01.
LCS33391:l
MB33391:l
MS03031317-0l,33391
MS03031405-04:33391
MSD03031317-01:33391
MSD0303l405-04: 33391
19-MAR-03
19-MAR-03
19-MAR-03
20-MAR-03
19-MAR-03
19-MAR-03
20-MAR-03
TBP ·2, 4, 6-TRIBROMOPHENOL
rnP 2-FLUOROBIPHENYL
2FP 2 -FLUOROPHENOL
NBZ NITROBENZENE-05
PHL PHENOI,-D5
TPH TERPHENYL-014
15 49
12 : 18
10: 59
11 : 45
20: 33
17: 16
13 : 12
TBP:.:··
_4~ 120
71
62
75
79
74
FBP":
-/\2c\06
80
60
72
58
75
61
80
Report Date
Page 1 of
Matrix
workGroup;
Method
·2.~P_'-...
.19">7'9':::
71
60
68
58
61
1
March 24' 2003
Report ID: A85411
GW/ChemW
WG33391
SW846 3550/8270
·NBZ':.
·2'ff~1_1~
92
75
89
67
0
69
0
P_HI./,
a_:73
67
52
63
60
63
..:: TPH
. \10 122
91
73
93
85
89
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Dav;s & Floyd, Inc. I PO Drawe, 428 I Greenwood, SC 29648 I 816 E1 ~4st Avenue I Greenwood, SC 29649 I [phone] I Fax [phone] I
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DAYIS
FLtrYD LABORATORY ANALYSIS REPORT
Method Blanks
Blank MB33391:1
Parameter
Semivolatile Organics
SW846 8270C
1,2,4-TRICH½,)ROBENZENE
1,2-DICHLOROBENZENE
1,3-DICHLOROBENZENE
1,4-DICHLOROBENZENE
2,4,5-TRICHLOROPHENOL
2,4,6-TRICHLOROPHENOL
2,4-DICHLOROPHENOL
2,4-DIMETHYLPHENOL
2,4-DINITROPHENOL
2,4-DINITROTOLUENE
2,6-DINITROTOLUENE
2-CHLORONAPHTHALENE
2-CHLOROPHENOL.
2-METHYL-4,6-DINITROPHENOL
2-METHYLNAPHTHALENE
2-METHYLPHENOL
2-NITROANILINE
2-NITROPHENOL
3,3'-DICHLOROBENZIDINE
3-NITROANILINE
4-BROMOPHENYL PHENYL ETHER
4-CHLOR0-3-METHYLPHENOL
4-CHLOROANILINE
4~CHLOROPHENYL PHENYL ETHER
4-METHYLPHENOL
4-NITROANILINE
4-NITROPHENOL
ACENAPHTHENE
ACENAPHTHYLENE
ANTHRACENE
BENZO(A)ANTHRACENE
BENZO(A)PYRENE
BENZO(B)FLUORANTHENE
BENZO(G,H,I)PERYLENE
BENZO(K)FLUORANTHENE
BENZOIC ACID
BENZYL ALCOHOL
815(2-CHLOROETHOXY)METHAN"E
815(2-CHLOROETHYL)ETHER
815(2-CHLOROISOPROPYL)ETHER
Davis & Floyd, lnc. I PO Drawer 428 I Greenwood, SC 2964B I
Report Date March 24, 2003
Page 1 of 2 Report ID: AB5379
Matrix GW/ChemW
WorkGroup, WG33391
Cone Qual RDL Units Analyst Date Time
' 10 .0 10 .0 ug/1 JRN 03/19/03 1059
10. 0 10 .o ug/1 JRN 03/19/03 1059
10. 0 10. 0 ug/1 JRN 03/19/03 1059
' 10 0 10. 0 ug/1 JRN 03/19/03 1059
' IO. 0 10. 0 ug/1 JRN 03/19/03 1059
' 10 .0 10, 0 ug/1 JRN 03/19/03 1059
< 10. 0 10. 0 ug/1 JRN 03/19/03 1059
10. 0 10. 0 ug/1 JRN 03/19/03 1059
< 25. 0 25. 0 ug/1 JRN 03/19/03 1059
< 10. 0 10. 0 ug/1 JRN 03/19/03 1059
' 10 .o 10. 0 ug/1 JRN 03/19/03 1059
< 10. 0 10. 0 ug/1 JRN 03/19/03 1059
' 10. 0 10 '0 ug/1 JRN 03/19/03 1059
' 25. 0 25. 0 ug/1 JRN 03/19/03 1059
< 10 .o 10 .o ug/1 JRN 03/19/03 1059
< 10 .o 10 .o ug/1 JRN 03/19/03 1059
< 10. 0 10 '0 ug/1 JRN 03/19/03 1059
' 10. 0 10. 0 ug/1 JRN 03/19/03 1059
' 10. 0 10. 0 ug/1 JRN 03/19/03 1059
< 10. 0 10. 0 ug/1 JRN 03/19/03 1059
< 10 .o 10. 0 ug/1 JRN 03/19/03 1059
< 10 0 10 .o ug/1 JRN 03/19/03 1059
' IO. 0 10. 0 ug/1 JRN 03/19/03 1059
< 10 0 10. 0 ug/1 JRN 03/19/03 1059
' 10 . 0 10 . 0 ug/1 JRN 03/19/03 1059
' 10 .0 10. 0 ug/1 JRN 03/19/03 1059
< 25. 0 25.0 ug/1 JRN 03/19/03 1059
< 10. 0 10. 0 ug/1 JRN 03/19/03 1059
< 10. 0 10. 0 ug/1 JRN 03/19/03 1059
' 10 .o 10. 0 ug/1 JRN 03/19/03 1059
' 10 .0 10 .o ug/1 JRN 03/19/03 1059
' 10 .0 10 .o ug/1 JRN 03/19/03 1059
< 10. 0 10. 0 ug/1 JRN 03/19/03 1059
10. 0 10 .0 ug/1 JRN 03/19/03 1059
< 10 .o io. 0 ug/1 JRN 03/19/03 1059
< so. 0 50 .o ug/1 JRN 03/19/03 1059
' 10 .o 10. 0 ug/1 JRN 03/19/03 1059
10 .0 10 .0 ug/1 JRN 03/19/03 1059
< 10 .o 10. 0 ug/1 JRN 03/19/03 1059
' 10 0 10 .o ug/1 JRN 03/19/03 1059
816 E. Durst Avenue I GreenwooJ, SC 2964') ! (H64) 229-4413 I Fax [phone]
185
DAYIS
FLOYD
Method Blanks
Blank MB33391:l
Parlll!leter
BIS(2-ETHYLHEXYL)PHTHALATE
BUTYL BENZYL PHTHALATE
CHRYSENE
01-N-BUTYL PHTHALATE
DI ·N-OCTYL PHTHALATE
DIBENZ(A,H)ANTHRACENE
DIBENZOFURAN
DIETHYL PHTHALATE
DIMETHYL PHTHALATE
FLUORANTHENE
FLUORENE
HEXACHLOROBENZENE
HEXACHLOROBUTADIENE
HEXACHLOROCYCLOPENTADIENE
HEXACHLOROETHANE
INDENO(l,2,3-CD)PYRENE
ISOPHORONE
N-NITROSODI-N-PROPYLAMINE
N-NITROSODIPHENYLAMINE
NAPHTHALENE
NITROBENZENE
PENTACHLOROPHENOL
PHENANTHRENE
PHENOL
PYRENE
SW846 8270C DOWTHERM
1, l' -Bl PHENYL
2,3-DIHYDROXYBIPHENYL
8 I PHENYL ETHER
Prep Procedure Method
Analytical Prep Procedures:
BNA SEMIVOLATILES SW846
DOWTHERM SW846
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LABORATORY ANALYSIS REPORT I
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Report Date March 24' 2003
Page 2 of 2 Report ID: AB5379 I
Matrix GW/Chemw
WorkGroup: WG33391 I
Cone Qual RDL Units Analyst Date Time
' 10 ,0 10. 0 ug/1 JRN 03/19/03 1059
' 10 .o l O. 0 ug/1 JRN 03/19/03 1059 I
' 10. 0 10 ,0 ug/1 JRN 03/19/03 1059
' 10.0 10. 0 ug/1 JRN 03/19/03 1059
' 10 ,0 10 ,0 ug/1 JRN 03/19/03 1059
' 10 .o 10. 0 ug/1 JRN 03/19/03 1059 I
10 .0 10. 0 ug/1 JRN 03/19/03 1059
' 10, 0 l O. 0 ug/1 JRN 03/19/03 1059
' 10. 0 10. 0 ug/1 JRN 03/19/03 1059 I
10 .o 10 .0 ug/1 JRN 03/19/03 1059
' 10 .o 10 .o ug/1 JRN 03/19/03 1059
' 10 .o 10 .o ug/1 ,JRN 03/19/03 1059
' 10. 0 10 .o ug/1 JRN 03/19/03 1059 I
' 10. 0 10. 0 ug/1 JRN 03/19/03 1059
' 10 ,0 10 .o ug/1 JRN 03/19/03 1059
' 10, 0 10. 0 ug/1 JRN 03/19/03 1059
10 .0 10 .0 ug/1 JRN 03/19/03 1059 I
' 10. 0 10 . 0 ug/1 JRN 03/19/03 1059
' 10. 0 10 .o ug/1 JRN 03/19/03 1059
' 10. 0 10. 0 ug/1 JRN 03/19/03 1059 I
' 10 ,0 10 .o ug/1 JRN 03/19/03 1059
' 25 .0 25 .0 ug/1 JRN 03/19/03 1059
' 10. 0 10 ,0 ug/1 JRN 03/19/03 1059
' 10 .o 10. 0 ug/1 JRN 03/19/03 1059 I
' 10. 0 10 .o ug/1 JRN 03/19/03 1059
' 10. 0 10. 0 ug/1 JRN 03/19/03 1059
' 25. 0 25. 0 ug/1 JRN 03/19/03 1059 I
' 10. 0 10 ,0 ug/1 JRN 03/19/03 1059
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Analyst Prep Date
35008 DEC 03/17/03 0800 I
35008 DBC 03/17/03 0800
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Davis & Floyd, Inc. I PO Drawer 42.8 I Greenwood, SC 29648 I 816 ll~rst Avenue I Greenwood, SC 29649 I (864) 229-44 IJ I fax (864) 22'1-71191
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DAYIS
FLt1YD LABORATORY ANALYSIS REPORT
Matrix Spikes and Duplicates
MS/MSD
ParamE=t~r
1,2,4-TRICHLOROBENZENE
1,4-DICHLOROBENZENE
2,4-DINITROTOLUENE
2 · CHLOROPHENOL
4 -CHLOR0-3 -METHYf.PHENOL
4-NITROPHENOL
ACENAPHTHENE
N-NITROSODI-N-PROPYLAMINE
PENTACHLOROPHENOL
PHENOL
PYRENE
1, l' -BI PHENYL
BIPHENYL ETHER
1,2,4-TRICHLOROBENZENE
1,4-DICHLOROBENZENE
2,4-DI~ITROTOLUENE
2-CHLOROPHENOL
4-CHLOR0-3-METHYLPHENOL
4-NITROPHENOL
ACENAPHTHENE
N-NITROSODI-N-PROPYLAMINE
PENTACHLOROPHENOL
PHENOL
PYRENE
1, l' -BI PHENYL
BI PHENYL ETHER
MS03031317-0l:33391
MSDOJ0313li-01:33391
i:,pi_ke
·._ ldd~d
50.00
50.00
50.00
75.00
75.00
75.00
50.00
50.00
75.00
75.00
50.00
50.00
50.00
50, 00
50 .00
50 . 00
75, 00
75. 00
75. 00
so .00
so ,00
75, 00
75 .00
so , 00
so' 00
so. 00
· sai..n~le
Cone
' 10. 00
10 .oo
' 10. 00
' 10 . 00
' 10. 00
' 25. 00
' 10. 00
' 10, 00
' 25. 00
' 10 00
' 10. 00
' 10, 00
' 10. 00
27' 18
27, 27
34 , 70
48 .24
52. 07
43 ,40
33.56
39, 61
44 . 26
47 ,85
43 .86
35. 70
37. 28
Report Date March 24'
Page 1 of 1 Report ID:
Matrix GW/ChemW
WorkGroup: WG33391
Method
MS
Cone
27' 47
27 .44
37. 63
50. 74
53 95
45 , 47
32. 14
37, 30
51, 32
43 . 95
40 . 68
34 '34
36' 60
54
55
69
64
69
58
67
79
59
64
88
71
75
SW846
MS
iREc,
55
55
75
68
72
61
64
75
68
59
81
69
73
1
8
5
5
4
6
15
8
8
2
8270C
Limits
\REC
32-90
31-84
45-110
32-89
34-103
8-83
37-102
29-110
11-125
10-74
49-116
31-110
30-113
.%-RPO-
30
29
23
31
24
26
29
32
36
28
15
27
22
2 003
AB5380
32-90
31-84
45-110
32-89
34-103
8-83
37-102
29-110
11 125
10-74
49-116
31-110
30-113
NOTE: MS/MSD % recoveries are not evaluated if the sample concentration is greater than four times the spike added.
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I Bl 6 E. Durst Avenue I Greenwood, SC 29649 I [phone] I 1:ax [phone]
18 7. ·
DAYIS
FLt1YD LABORATORY ANALYSIS REPORT
Laboratory Control Standards and Duplicates
.· .·Pa~~j~(fj!(:-
1, 1' -BIPHENYL
BIPI-IENYL ETHER
LCS
1, 2, 4-TRICHLOROBENZENE
1,4-DICHLOROBENZENE
2,4-DINITROTOLUENE
2 -CHLOROPHENOL
4-CHLOR0-3-METHYLPHENOL
4-NITROPHENOL
ACENAPHTHENE
N-NITROSODI-N-PROPYLAMINE
PENTACHLOROPHENOL
PHENOL
PYRENE
LCS3339l:l
·. -::<:.,:~~'.r~i// ·:· LCS.
':::Aclde"d/:. /(<~a~~/-:
50.00 30. 67
50.00 30. 62
50. 00 23 . 66
50. 00 22 . 50
50 . 00 29 41
75 .00 47 . 23
75 00 47. 28
75. 00 25 77
50 . 00 29 40
50 00 39. 08
75. 00 41 . 52
75. 00 37. 98
50. 00 34 .12
Report Date
Page 1 of 1
Matrix
March 26, 2003
Report ID: AB5448
GW/ChemW
WorkGroup: WG33391
Method SW846 8270C
--:r~Cs':.:::
·.·-,\~~'C_'.: : ·':":::tiiii'i c'ii >·· · <>>":\~·~2.)-<-:"•'•
61
61
47
45
59
63
63
34
59
78
55
51
68
41-109
42-106
29-84
28-78
50-104
32-91
41-95
10-80
40-98
31-111
19-89
9-72
57-112
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Davis & Floyd, Inc. j PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I {864) 229-4413 I Fax [phone] I
188
Chain of Custody Record Page J_ of J_
Clittnt Project I S1/e Localion 816 E. Durst Avenue. Greenwood, SC 29649 {864) 229-4413 Fax: [phone] ....
Kubal-Furr & Associates 61621.01 Laboratory Certifcation Numbers: SC-24110, NC-ZS, TN· 2923, VA-77
Contact~ ~,..,....,Ji«An .. ) Report T~ C _ 1/'ullJ,:Y Copy To Reporting Requirements: { } Standard [ ) Data Package (Specify Level) 1u(JJ'\;/laseO!der
c::j,<. 0,1 Al1t,;e___-;(~-1£.,;J),,f-,v /::r-1.A / ..,,,.,,.,_ .,,1 6/&dBy Required Parameters, Containers and Praservalives Stat, wole mt ;::, ,,,-,,1,{,w / /JC... ,"t
'~ ,n ISpecial lnslnJ(;tions
NOTICE: ~ ------1 •• • ~ J .~ ..... r~ O· I':: I :~! "§ ~ e -.c.-~ = 0 >. ~ '-' ~ ~ C.. • " •"i E ·"::: ~ 8. ·3 • • § i' 11 ~ D D • E E :s E Sample Collection !~ .~ 0 ~ , ~ z ..J
Samole Oescrintion Date Time Time Type Total --HOT ommenis
YEW-I ~3 /!JO y s L/ IX )< o, h--7;+JJ:
T,Zrf i t_,1,Jt:: 3fr;/4:> 07tf( IX tl 3 IV 0 ')., /1?.),~7e1I-,l./.£1!~-,
-!co ~
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R~d~TZ.,-rJ2:s Time i'.f\. By A Date Time Re/iquished By Date Time o~t_j
(S-1-, ·-111:C---3),-.) O< ;HJJ;:-{ .;.,~ '""" "'. y N -""" ,
R~ ~,~ ,ten.. ceiveue Date Time Received in Labora~ Date nmo ff Y, specify: Akbi/1 Number
. e <?7° ltZcf J;:,t; l,tJ rTj SO., t(l; S 3.13.oa 1/J.,.IJ..f) -====-day•
11..,ommenls
coo1 .. c:;;;r.-1: _......;
Ion Ice Ye No Temp(C) ,... -
Custody Seal: Intact I Broken / {;.,,,.)
~trixT~ilions-.irinki~ 2~~ter -dwat oil/Se 8-Li ,, 2-Ai
Preservative Definitions A ,None B -H2S04 C . HCI D -HN03 E • Na~ Filter!l'-'Olher ~ .. -- - ----Flo
Sampling Log-Grab Water Samples
Project No. 26QS07 Site Location
<,2 j'JA ()
CNA / Ticona -Shelby, NC
Sample Date ----:'{;_~v•_,••,,_/_Ov___ Arrival Time
I I
Sample ID 6/)_v;(, fiLAvrj Duplicate No. _____ _
Weather Conditions C/.,1uv.7 1 '/c., Sampling Method
I
Sample Temp. ('C) _-____ Spec. Conductivity(µS/cm)
Sample Time_....:/_:/ _ _?,..::(,_;_· __
Field Personnel #-}J))
I
pH ______ _
ORP (mV) Turbidity (NTU) -----------'DO(mg/L) ______ _
Method(s)
Vr1t:J· Container Description
(s l:-'t'u-:".f
Remarks ?c, ilfl} DI 1;Jl,17kt. t'il,n_ (J!-i:-Ot-Z•·"·.-;, fi-•'.vlim W~i' fi.1-IZ(.,,'. k-,,.,.c ~
l>Sit> 7,_,1,; ,..., fl .-S,(-
Sample Date .a/:J-, j)
I -;?,, EQ,)/?. v<-jr,,;~""J ..--
sample ID _______ · Duplicate No. ______ _
Arrival Time __ !t_¼_&tJ ___ _ /? Jo Sample Time ______ _
:, I' Field Personnel __ v__c(J ___ _
Weather Conditions C l-,;'i,•)7 Sampling Method
Sample Temp. ('C) _,.---____ Spec. Conductivity(µS/cm) pH ______ _ -ORP (mV) Turbidity (NTU) ___ ..__ ____ ~DO(mg/L) ______ _
Method(s)
l/t}L.J
J)(,I..J1J/B9-J
Remarks
Container Description
'3;>c '/tilt/
Kubal-Furr & Associates
Preservative
1/-c{ -
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Revised 7 /30/02 I
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1·l.:l·l
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/<.J:f;
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Low-flow Groundwater Sampling Log
Project No. 26QS07 Kubal-Furr & Associates
-E11viro1m1e11tal Consultants-Site Location CNA/Ticona -Shelby, NC ---~---~~~~-
Fie Id Personnel Greg Kinsman/ Jeff DeWitt
Well I Sample ID 1)-'8 8
I / Weather Condition (,·•.-;/ tJJ.,, l,('l.<:
,,., · 'l.(,,') ·)• "< ;· ') r.' L J' J / 1 Sample Date b I < • .._, Arrival Time.' ; J ..J Sample Time ________ ~e><~•S:~•~S'~_
Descr;ptionofMeosulingl-r<~' I cos;ngTypel <S I Lock;ngCapl V Cosing(LJ, Point {MP) ., •· ..::, J Diamete /.-.. . ::::C=====.---_; inches
Purge Method I (JJ'\./tl(/}-0 '(· Sampling Method I f'/Tl'c:.IJJJ{,~.
Purge Stop Time I /t"lf/ I '1 Purge RateF1.t:tornl/minl Purge Siar! J;mel // S'] I
Water-Level Measurements
Interval
0
f
2
3
4
s
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
Elapse Time OTW [feet)
(mins)
, 1ts:1
-f!)
' ' £' 1:J... cf
i ;? 1..s.12
J'i 1'-/.'15
"lt,7 2.1::.,/':.,-
2_<t 2. 5' .)''/
.?o 2(,3S
-,,:-'J..1,'-lrJ -~ _.)
ifii ,;&.Jr
'ff' iJ'i!J}f
< ., D 5(l,J/
Samples Collected
Interval
0
f
2
3
4
5
6
7
8
9
10
11
12
13
14
IS
16
17
18
19
20
Field Parameters
Elapse Time Temperature
(mins) (0CJ
D ---
,") IJ.1,;
/{l /5'.~({
/:'i' f§". ·t1
'Z-0 i-,/L/,<;{,
zs· ~ i.M'ff.'?i
'Sc/ /'I, 'l'l
"'3 5 /,'.'-f !j
1/l' It: .?'I
w-/(;,t,1
·>{) lt,61
Specific
Conductance
(µS/cm)
---
<t1-
(/A (; l-,
fJ,
ft,
8'0
7'1
f7 c-
-f-1 9s,,,
lJS
Container Descnpt1on
Parameter Conditions: pH +/-0.1 standard unit COND/lemp +/-3%
+/-l NTU below 10 NTU Turbidity +/-10% above 10 NTU
pH (su) Turbidity (NTU)
·--
1.:7.7 i-7
%.'f'} /. f
ts'/ 2,1..
t,G(:: J../1
tr.I:"' , :· / J. 'f.
F'-7o /.'-/
J.N /,/
:f;7f /, 3
.;f' .ft I. J
2'. '!'J. /. ~
Preservative
· DO
ORP +/-lOmV
Dissolved
Oxygen
(mg/L) -
J.c?f!
i.'f<J ,// ,1 . /..-·!¥
3;,'-/Z
J:l'f
··11 j.,, I
'J. I"rj
• ,,J '}
l,1.r
3."lC/
ORP (mV)
---
11l-G
/(,'.:-.1
/O-;: I
/c'S.5
/(.,16,, {,
!vi,£.
/L>(;, s
/t></.7 ~3 //J,
lc:JZ,.o
1 91 CNA/Ticona
Low-FlowGraundwater Sampling Log
Low.flow Groundwater Sampling log
Project No. 26QS07 Kubai~Furr & Associates
-Em·ir011mmta/ Co11s11lta11ts-Site Location CNA/Ticona · Shelby, NC
Field Personnel Greg Kinsman/ Jeff DeWitt
J lo
· Well I Sample ID --~."'l)~.--,-51-l~,~----") '), 3 , _,,,-_ . ....-/WeolherCondition C}C:,•u?;, yt,~.r<.-
Sompteoo:e o/-o'l) y Arrivallime Jo...s~ Somplelime ~ j4't!)i)
i)escripticn of Me=ng~ C 1 I (1'' I Locking Cop[ ~ Cosing~==2====1-~~-----Point (MP) ~ # ~(.__ ming ype -> .----Diomete :=::::;;::::;:::==.---~ ,nc:.ei
Purge Method~t!A-i){z,_J Sampling Method I 3/Ji!,JC:-
P~•rge Stort Time I l 3Jl,
Water-Level Measurements
Interval
0
I
2
3
'
5
6
7
8
9
10
II
12
13
"
15
16
17
18
19
20
Elapse Time DTW (feet) [mins)
/) ,;rJ.Lf.r'
.s ~--1-'"
/(I L/: ".:t. ' ·' ..... \ .
j_(" -~7.-i""S'
.)o '*.(s3/
2(" :o.-st
.Jo Jo. -.j1.
Samples Collected
Interval
0
I
2
3
'
5
6
7
8
9
JO
II
12
13
"
15
16
17
18
19
20
Purge Slop Time I /3S(l.
Field Parameters
Elapse Time Temperature
(mins) ("C)
0 --Jt.J-) -...':,
/c> ;7, 3(,,,
/J /.?Li" 2
i'C 1,P-,:)L
l--I-;J-, <i3
3o /t-,,J'N
Specific
Conductance
(µStem)
-
.;21 .u.
;Ls
.J..S-
.:J,s
,:L.<
Container Descnpt1on
Purge Rote1,:s?t..r2>rr.1/m,nl
pH (Su) Turbidity {NTU)
--
?.37 I.(;
fu,/J /,,f
-s;4::i;---:2.0
s,?£1 /,-J-
s,(os~ /,•J
S,,17 /, s,,
Preservative
Dissolved
O;,;ygen
(mg/L) -3.-tt.
J,'73
'<., 'I'-/
3.<14
1.¥
3. ;'}{;,
ORP (mV)
-
l'79, I
J '13, 5
I <J,J, I
i9i,b
;9,1, '/
/9'1'.7
Remarks _________________________________________ _
Parameter Conditions: pH +/-Q, 1 standard unit
Turbidity +/• 10% above 10 NTU
COND/Temp +/-3%
+/-1 NTU below 10 NTU
DO +/· 10~
ORP +/· 10mV
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192
CNA/Ticono I Low-FlowGroundwoter Sompr1ng Log
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Kubal-Furr & Associates
-Em:iro1111w1tal Co11;;11/t,mts-
Low-Flow Groundwater Sampling Log
Project No. 26QS07
Site Locot;on CNA/Ticono . Shelby, NC
Field Personnel Greg Kinsman / Jeff DeWitt
Well/ Sample ID ==:::c:~~(~.'-~-~J~l3~· =~:~~~::== J LI-S:(, Wea/her Condi/;on C1.,.,.:j)/ -'fC, ·· Jch'
Sampie Date _ _,__-;i:::::.===,----, Arrival time, ___ c_7'_;::::====;Somple Time _____ ~/-•s-'~¥~,t,~1 ____ _
Cosing Type! ,-c I Locking Cao[ , _,_-Cosing~ -....>_) . .., Oiomete~ ~===---.....: :====---...; Purge Methodn1;q>.,S.ij:1Z.i7<--I Sampling Method I t.Wti,-
Purge Start Time/ /:.rz•7
Water-LBvd ivlcusu1 ements
Interval
0
I
2
3
4
5
6
7
8
9
10
II
12
13
14
15
16
17
18
19
20
Elapse Time DTW (feet)
jmins)
0 .?J.s•
-5 )),if'
/{) JJ.t/3
1--.i -2?.,tfi
;:;✓, J)),'-1 l
:},_'(' !)J.,</3
'>,i 2) q3
Samples Col,ected
Interval
0
I
2
3
4
5
6
7
8
9
10
11
12
13
14
IS
16
17
18
19
20
Purge Stop Timej J.Sl f,'
Field Paramelers
E!opse Time Temperature
(mins) (°CJ
tJ ·--/,J,/}, --~
/ti Jt,, ;).
Ir' /b,;J
A> ;t,. :Al-
.L1 /(,..).J~
3,1 ;/,;,) 'i
Specific
Conductance
{µS/cm) -
:;2J.:;
:J,:).3
'o,!.J~
;J.J.f
'j.)>j
J-;).A
pH (su) Turb;dity jNTU)
--
/,,.37 <-J. ~
{,,; ,ti(, ,<.'l
(,;,·'If '3,o
In. 'i'l /."J
/4.t/.1' /. ·7
l,i/'J 9, 'J_
7-/cJ '
Dissolved
Oxygen
{mg/LJ -
{J.V-1
0,:3/
6,}J. o. ))_
{J_)J.
6,.)3
ORP (mV)
--li/,6
-?/.J
-72l
~7~--; ,
-7J-, ,,
-<f·t).S-
Remarks _________________________________________ _
Pora meter Conditions: pH +/-0.1 standard unit
Turbidity +/-10% above 10 NTU
CONO/Temp +/-3%
+/• 1 NTU below 10 NTU
193
DO ?/• 10%
ORP +/· 10mV
CNA{Ticona
Low-flowGroundwoter Sompftng log
Low-Flow Groundwater Sampling Log
Project No. 26QS07 Kubal-Furr & Associates
-Ent·iram/11.'llla/ Co11~1ill<111t$-Sile Location CNA/Ticona · Shelby, NC
Field Personnel Greg Kinsman/ Jett DeWitt ? / Well I Sample ID 'i) .3 .r-
samp1e oa1e j2L }tj /4 Arri,al rime / 6/ .3 Weol
h
er~ao;;~i~:e C-(,,c-)/ i'.;,)O
Oescriplion of "".a:u,inghil tx;,(, I Casing Type I .S<" I locking Capl / I . Casingj ,-,-} . I Point {MP) • ~ . \ . 01omete ,r-" ,nc~.el
Purge Method\{~t:11,,'~fiJ Sampling Methodj ~e
Purge Start Time I J/;3;J.. I Purge Stop Timej / / / J I Purge Rorelr"\..Jt.f.'\ ml/mini
Water-level Measurements Field Parameters
lnterJOI
0
I
2
3
4
5
6
7
8
9
10
II
12
13
14
IS
16
17
18
19
20
Elapse Time
(mins)
f:)
~
/cJ
;.S-
,Jo
,:.2S""
3o
3$"
'lo
DTW (!eetJ
;b.J(
·1J, tj,f, ,,;I, ,
7?,,f?
JJ,,.s
J.3)/
;)3,)o
JJ,Jc,
J,3,t-S'
)].(I']
Samples Collected
Interval
0
I
2
3
4
5
6
7
8
9
10
II
12
13
14
15
16
17
18
19
20
Etopse Time Temperature Specific Conductance /mins) f°C) (µS/cm) pH (su) Turb'dty (NTUJ
C) ----....s--1'(9o 1f·1 tf,f/ /.;/9,ti
It, /7'7;2 ;J-. --' )~ t/ ,ft) s'l,/
i.S-JJ,,f'} ;J,;I, l/,[J. /7,7
1,JcJ ;lo. -$'",5' :)J../ i/,,fO J-: <' , 7
2r Jt;, 91 ,2:J.1/ l(]'/ t,,,f-
30 :J11. 97 ;J.J..3 u,'7,f, ,-'1 -~,
3< :Jl,tJ (, ,:;J,,'J.il I{. "},f 'I. "i
YO -4).~ J,).1/ ,(Jl, l/,'3
Container Descr·,pt1on Prese'votive
Dissolved
Oxygen
(mg/L) -3,'(:J.
33G,
S,o I
104
3,o(;.
'3,v'l
3.V7
'3,d(
ORP (mV)
·--
'2)J-.?
3o7. J
sJ.I. o
33</, ,r
3 3 ,f,.-;f-
:Si/ti, i./
;?t/'f.f
's '/?. ,)._
Remarks _ __: __________________________________ _
Parameter Conditions: pH +/-0.1 standard uni!
Turbidity ... ,. 10% above 10 NTU
COND/Temp "'1-3%
+/-1 NTU below 10 NTU
194
DO
ORP
CNA/Ticono
Low•FlOwGrovndwote< Sampling Log
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Low-Flow Groundwater Sampling Log
Project No. 26QS07 Kubal4 Furr & Associates
-Em.'iro1111k'//tal Co11:rnlt1111ts-Site location CNA/Ticona • Shelby, NC
Field Personnel _..cG~r-'-e'i!vc'-K"'in"'s"-m"-a=-n=/-=J-=e.c.cff..:D:.:e:.:W.:.i:ctt'--rJ~ t · Well I Sample ID -~-1:)'-'c,--~d.'-"--'7~----' ~ o'3 i~/3 WeatherCandition CLcv)){j,-SZ>,,
Sample Dote~ Arrival Time,-~/'--" lif_----;:=====;Somp!e Time_~ __ _cT__,_/__,,f-'--"'7 -'C"-,----
Description of Meosurin~, Cosing Type I / / I Lock;ng Cop! ____. I Cosing@] Point (MP) ._,,C) L ~~ ~ Oiomete ~ _ ::::C====----; ,ncne1 Purge Methodl"f/p ,rTJt1./1 L Sampling Method I ...S:-,1,,yC
Purge Start Time I [7.J-:J. Purge Stop Timel /.f 14
Water-Level Measurements
Interval
0
I
2
3
'
5
6
7
8
9
10
II
12
13
14
15
16
17
18
19
20
E!ap,e Time
(mins)
0
s
jt,>
1..S-
)Cl
c2-s
.,ro
?~ ·-' ' '/o
orw (feet)
~-31
c2l St)
,Z},O').
J'J,J?
JJ, J.J.-
JJ, 13
11,s-
J.), 17
J,),;)c,
Samples Collected
Interval
0
I
2
3
'
5
6
7
8
9
10
II
12
13
14
15
16
17
18
19
20
Field Parameters
Elapse Time Temperature
lmins) ('C)
0 ·-,,;-lf,.._t/o
/t) 6.ot,
/'l th, I!-
,A") /i:,/1,;
J< /(;;, ~'-I
3o /&JS'
3,f' /6.0 ?
'lo )f;./l,
Specific
Conductance
(µS/cm)
-
-/,)i/
13c,
13(:,
Jilt/
J</7
1'1.f-
It/ {-
tt/f
Container Descnpt1on
1p1.fL
pH {Su) Turbtdity (NTU)
--· -£:-11 /,<1
-f:.;J') /,O
,.;-:1 )_ I/ ''-l _,,,.. f ,~,.(/~ /,{)
{';O) l I
£,1-(' /, ;)_
~,i··.,,.,. ... ~ ),,.r
-~,<,1</ j,.f
Preservative
Dissolved
Oxygen
(mg/L)
-
-..S:o9
3,77
3,().ef
2.{,7
;2, '7 ,-;_
J,f J
j.')(:
27'{
ORP (mVJ
~
3,,3, J
~l/,-.J~
31b, t,
3:J.J, 3
333, 1
3i/3,<(
3.,(c1, 0
3-(o, 3
Remarks ______________________________________ _
Parameter Conditions: pH +/. 0.1 standard unit
Turbidity +/-10% above 10 NTU
COND/Temp +/-3%
+/-1 NTU below 10 NTU
195
DO +/-10%
ORP +/-lOmV
CNA/Ticono
Low•FlowGroundwater Sampling Log
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Kubal-Furr & Associates
-E11;.·inm111c•11tal Cv11wlta11ts-
low-Flow Groundwater Sampling Log
Project No. 26QS07
Sde Location __ C_N_A~/_T_ic_o_n_a_• _S_h_e_lb~Y~•-N_C~_
Field Personnel __ Gc.r~e~g._,_K,..in,,s~m...,a~n=-'-/~J~e'--ff'--D"-e-'-'-Wccitcct_
Well/ Sample ID --~U-~~r_-_6_:2 _____ _ ~/ / "7 ~ C 7/ Weather Condition Ct,~•/ff7 yc,.-r~'f.c
Sample Date @i /tf_,.,1 Arrival Time, __ w __ ncrb_r====,·Somp/e Time:::=======•~0=~9=f.:'.,f:·:-=========
Desc,iplionolMemurin~..-.---1/~4cosingT pe~ LockingCopl ~ Casing~I Point (MP) '-<.,• Y ~~ . Oiomere~ :==;:::;::==;..-~ Purge Methoci]@ .. (./N£j); .. J Sampling Method I #-?e°
Purge Start Timel~fu
Water-Level Measurements
0
I
2
3
4
5
6
7
8
9
10
11
12
13
14
IS
16
17
18
19
20
Elapse Time
[m·1ns) orw (feet)
0 . /o, IC>
....s 1J,9J
/c? I 3,</,f
IJ /'i,l/:J.
;J.o /-l;~J .J-s ft:, </7
3o 17,30
Samples Collected
Parameter Conditions: pH
Interval
0
I
2
3
4
5
6
7
8
9
10
11
12
13
14
IS
16
17
18
19
20
Purge Stop TimelO~h
Field Parameters
Elapse Time Temperature
(mins) [°C)
a --.-0 !37'9
/i3 ;3,0S--
1-..1-/3,0J,
Jo /3,SY
_/41 13-7'/
Jc.) /1d't/ .
Specific
Conductance
[µS/cm)
-
S-t/
_s-",,L
S'J
-.S-1(
..s-3
S-3
Container 0escnpt1on
+/-0.1 standard unit
Turbidity +/-10% above 10 NTU
COND/Temp +/-3%
+/-1 NTU below 10 NTU
Purge Raref'L/K ml/cr.r,I
pH (su) Turb'1d'1ty (NTU)
---·
,,{2c; 'I. J-
(£,,t, 3 I l.C>
t, . .;2.3 ?,,.!-
b,o9 ?, 3
&.o/ '),tf
S-:9J-?,,S-
Preservative
DO +/-10%
ORP +/-lOml/
Dissolved
Oxygen
lmg/l)
·--
/,(l 7
CJ;?';
O.S"o
6 '3(., ' c},JJ
d.3/
ORP (mV)
f;/SJ,f:,
~<I-<
J3'if-
.;l-3/, I(
2J.3, 9
:Z1~ b
CNA/ncona
Low•F!owGroundwoter Sampling log 2 03·
Grab Sampling Log ,. Sludge
Project No. Z6QS07 Site Location CAN Holdings / Ticona, Shelby, NC
Date c:2/J_; k3
Time 7 ()90:)
Sample ID Duplicate No. ____ _ Field Personnel &c_
Sampling Equipment {ii?4f5 Weather Conditions llc,,l:q ~~~~-;
Lithological Description
Samples Collected
·J[ L( )lt7Jitf
1C l? .fVt'C ,-
t'C L j) voe~
Preservative
-
Date _ _.¾_~~-If-fr_) __
Time --=0__,.9_3i_u_.J __ _
Sample ID (gf_ _<,i.,(/7){£ Duplicate No. __ ·-__ · __ Field Personnel _(K:...c..::,~--
Sampling Equipment _6::...;£,=---~-""----Weather Conditions
Lithological Description
Remarks
Samples Collected
·JC f "r f/c-J71:Lf
·Tc·1..? ...Ii,b{;
·TC L-'/' 1/tJC.}
Container Description
/'Jr ~un e:a,-/
/>:.sz,dHf ce..lV
i 'k I z f:(fz.1,,/
Preservative ---
Cfv,u 'JJ
-------Kubal-Furr & Associates------
204
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Kubal4 Furr & Associates
-Em:iro111m•nt11/ Co11sult,mts-
low-Flow Groundwater Sampling log
Project No. 26QS07
Sile Loco/ion CNA/Ticona -Shelby, NC
Field Personnel __ Gc_rc:e"g'-'-'K"-inccs.ccmc.ac.nc..,../ccJc:ec.ffccDc.ecc..ccWc.itc.l_
Well/ Sample ID ---~6~r_-_-_3~i/ ____ _ ;2/p_c f 3 t2 C)/ Wea/her Condi/ion C'tt;,,)7. '/0•/i.,f
Sample Oote __ _,_/_7_,_~--------Arrival Time, ___ c_f,_h~====Sample Time _____ ~/,~l~)'~l~~------
De>cription of Meosurin~. / Cosing Type~· lock;ng Capl v.---Cosing~ Point (MP) l.('.),c_ Diameter r:~ ;=:::::;:===;:.----; ,ncries
Purge Me~hodl9a;sTJt:7t c. Sampling Method I 4,i,,c;-
Purge Start Timel/a,Y'
Water-Level Measurements
Interval
0
I
2
3
4
5
6
7
8
9
10
II
12
13
14
15
16
17
18
19
20
Elapse Time DTW (feet)
(mins)
Q' I/ '33,
"W's-IJ..;o
·¥, . /d IJJ{,
CV!;)c;,~ ) .-I ,t-~
dcl /(}-,17
:l-< I ;2,)c)
Samples Collected
Interval
0
I
2
3
4
5
6
7
8
9
10
II
12
13
14
15
16
17
18
19
20
Purge Stop Timej/0 5 3
Field Parameters
Elapse Time Temperature
(mins) (0C)
0 -s-l3.S3
/0 /3,J-/
;j ;3, J-'1
J.o I 5, '/J-
.-J.S--1'{/o
Specific
Conductance
(µ5/cm)
-
3/
3'/
.'57
37
:37
Container Description
pH (;u) Turbidty (NTUJ
---
.<7,f ;J,lv
s:e,7 !2.o
-~b ..s Fl.} ,,2. 3
S:-,..10 I.?
--.--: ,5 . c,t:) 17
Preser;ative
/IC(
Dissolved
Oxygen
(mg/L) -'3,S</
c:2 . .J-'/
,.2,93
'3'.aJ
J.9s
ORP (mV)
-
gs-o, I
g',LJ/
'30</,·7
2~o
.2SJ-f..,,.r-
Remarks _________________________________________ _
Parameter Conditions: pH +/-0.1 standard unit
Turbidity +/-10% above JO NTU
CONO/Temp +/-3%
+/-l NTU below 10 NTU
205
DO +/-10%
ORP +/-10mV
CNA/Ticono
Low-FlowGroundwoter Sampling Log
Kubal-Furr & Associates
-E11virolll1tentnl Co11s11/tn11ts-
SampleDale Jp/5
Low-Flow Groundwater Sampling Log
Project No. ----~26~Q~S~0'---7 ____ _
Site Lo co tion _....:C::cN.::A_,/c...:T.:.:i c:..:o:.::nc:oc..-....:S:.::hc:e.:.:I b:.,y_,_, .:cN:..:C:___
Field Personnel _....:Gc.cre-=-g"-"K"-in=•ccm.:.:acc.n'-'/---'J'--'e"'ff'-'D'-'e'-'W-'-i"'II_
Well/ Sample ID ----~' _-3~~------!/17 Weather Condition __ C:_t....:.tJc..'....:' ~c..j;....,,_i'c"°'"_' -=.cl'_<'-'-·r ___ _
Arrival Time,-----'--/_ !_;====Sample Time;====· =::;-...L!<CJ.o,.5o,'->c_ ___ _
Desc,iplion ol Measucin~ c . , I s_s I L ,. c I / I Casingj O I Po.,nl (M'I , as1ng ype _ ac 1ng op v ,,..L..._ i--Diamete v ::::==::::_·_~L. --"''°'"""°''
Purge Method I 7&,?lrf[,Jl'flC.. Sampling Methadl ~.,,{J,Vt<
Purge Stop Time~I _/_J;;_'.'.?,~,:;-, -,L----'-'-'------"----,-u,g_e_R_o_le-HJ~-9c-.-l)_m_l/m~inl Purge Start Time I 1/?S-
Water-Level Measurements
Interval
0
I
2
3
4
5
6
7
8
9
10
II
12
13
14
15
16
17
18
19
20
Elapse Time
(mins)
0
S"
;t>
/.J
)cl
,?s'"
s,•J ' t
;,{'
0/0
1./J__..
.<;o
S-J
DTW [feet)
lo,'7'3
/!;£f
1J,1)
/J.JJ_
tl,3a
;J,37
1),3;1..
1:2,37
;:2, 'II
;;2,'f;f
1?,17
;j,'/1,
Samples Collected
Interval
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
Field Parameters
Elapse Time Temperature Specific
(mins) (cC) Conductance
(µS/cm)
0 --
,) ,<;;-4/o·.\-
(0 /1~5(:, L//t)
IJ /,f~t,;; C((3
..)c1 /~73 C/;J
,J-s-1.S--:J). L/1(,
J,:,1 is--: /,,L/ t/1(
3J IJ?S 3/AJ
l(o i j---_ JC t/1&
?-s /J,;-0-'?Id"
,;z., I r,,p,'7 117
S0-( ,J,.,._J,'i/ t/17
Container 0escnpt1on
pH (su) Turbidity (NTU)
--·
5,)9 ti. I
-s,)3 3. I
_:( ;);) :l. :J
-5,']'] .2, i'.J
:£";:} J. /, ,f-
.,;-; ,) I ll
S) , 0 /. 7
J,, JtJ I.(;,
S-:✓'1 /, --, "
S°; I "J /, i
SI'/ /,{;
Preservative
IB:1
Dissolved
Oxygen
[mg/LI
-
o. 'l/
QJJ'.
0,:)7
o,,J:J,
0.10
O,;s
0, I 3
C13
0. I/
o. I/
Ci. I/
ORP jmV)
-
;S-i/, J
;JJt/,o
JJJ!-,s-
/36': t/
;3,.f 7
;Jf, 9.
It/{}, t(
/cl/ (J
Jl/'3,o
/'/3, 3
!'ft/ ,;L
Remarks ____________________________________ _
Parameter Conditions: pH +/-O. l standard unit COND/Temp +/-3%
Turbidity +/-10% above l O NTU +/-1 NTU below 10 NTU
206
DO +/-10%
ORP +/-lOmV
CNA/Ticona
Low•FlowGroundwater Sampling Log
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Sampling Log-Grab Water Samples
Project No. 26QS07
Sample Date _,7'_'1"-"-J ... / ... i:""'o_? __ _
'
Sample ID ~-·~_c_r_,,. ___ _
Weather Conditions Coo~ c/J&(
J 1-r;· ,-.-z
Sample Temp. (°C) /-_,, • ,> r
ORP (mV) )._ 2/.. :J'
Method(s) -,,:ic
Remarks
Sample Date 3/J-/ /'3
Sample ID ·-:S:---rc I
I
Weather Conditions (r,Jof /c/r/t1 v
Sample Temp. (°C) /'Z • 5((
ORP (mV)
Method(s)
·7t?L.
I
'
Site Location CNA I Ticona -Shelby, NC
Arrival Time j1.;f' Sample Time _J'-""{:.,/..:0::.._ __ _
Duplicate No. _____ _ Field Personnel -'-'(y'--'K.::.·.,_J.,,_~-"1),__ __
I
Sampling Method
Spec. Conductivity(µS/cm) pH f<J%
__ 5-=...,.., _,;7 _ ____,DO(mg/L) J, ffo Turbidity (NTU)
Container Description Preservative
:,; V ifo ml
i-/C1
/
/7 , .. ,r
Arrival Time ~'--0)"="'_..., ___ _ ,•!f:1·"15· Sample Time ~/~J"-'-t~C7 __ .:S __
. Duplic~ No. I'TC!-clcpe
' Field Personnel -~'-'"-'-;C..,.,./'-J.;.., .:...ff) __ _
/
Sampling Method
Spec. Conductivity(µS/cm) /2.(J' pH_'ILJ.'-"1.,_J __ _
Turbidity (NTU) ___ /,..:..-='-'{;;""·'-. _ __,DO(mg/L) _ _,_?,_. ·.,_7e;:Z,,_. __ _
Container Description
I Y I J. 5 ;,, I wi !<-Preservative
(/{/
'Ir,/ -
Remarks . I tJ (JJ,v.J,-,.urri,f.. $u; l p,,:i·
,f-G:>JkrfKJ ,-4,a\·o/e, :::?J
Kubal-Furr & Associates
Revised 7 /30/02
207'.
Lo.--,-Flow Groundwater Sampling log I
Projecl No. 26QS07 Kubal-Furr & Associates
-En:·inm111,•11l,1/ ClJ11;;11/t,111:,;-Sile Locaricn _..;:C:.:.N"-A"-/-"Ti.::.c.::.o:.:.na"---.::.S:.:.he:;;l.::.bLYc.:, Nc:.C-=---1
. Field Personnel Greg Kinsman / Jeff DeWitt
Well I Sample ID _,,1/,"-'l/-'-T-. ""..,_1_7,._ _____ _
Wecth'er Condition Yr. ,'H. r/r I " -,.. {./, n? ;· ,,-,-e-o -,-"'-""4-,J-e,,-'b--,~-----Sample Dote b A I V..,J Arr:v::I Time__,_...,v'--'J:::....:: '-;:::===::;·Sample Tim~ ' J rl;.ZlJ
Qe;ccipt;on ol Meosu,ingl -, ;,/"/,, I Cosin 1 •pe[ITJ' 5" locking Cop! r / I Co;ingj •? I Point (,\.\P) V(.;-."L. 9 ~ -.J 1 Diomere. "'-:=::;=~-'-----L... --""'"'=··· Pwrg~ Me:hudl (-Y r:..1;'1/..-lf :.1 ~ Sampling Method I 6"n;;1r/l~) ~;
Purge Start Time) //,J,,
Water-Level Measurements
lntarvo:
0
I
2
3
4
5
6
7
8
9
10
II
12
13
14
15
16
17
18
19
20
E:opse Time
!mlns)
(j
';, 11l'
IO ,1h
JS ,,·1,
'Z .:: j\~,,:
zs· j1~6
'?</ ,,1-..
'5"" 1.1,r.
IL/o tl-"
1./( "o5 • Is
)i) ri,c
DiW (feet)
i.f!,5')..
Lf/.11?
(.Ji,0i
.'.//. f<i
qJ,ol
</l,{)/
'I" ,'.i., L., (
i/z,d;:,
lj'., ,,,, l,O,
'I"' A l,.O)
i/2,o1
Samples Collected
Interval
0
I
2
3
4
5
6
7
8
9
10
II
12
13
14
15
16
17
18
19
20
Purge Step T,me[/1 /Q P.Jrge R::ra/;t_,¾7(),.,,_I1m.,,I
Field Parameters
Elop;e Time T-empsrorure
(m:ns) (''CJ
0 ----0 i(,.6i
/0 1?.60
;S IX,O'l...-
'l.o i ,'(, '5(__ zc . -' if1,,f"q
Jc) J'i?.Ci
>> ix.6(,
t.;~J l[JX-
05 i?<-7L
5D i.f,</o
Specific
Conductance
{µSiem) --{;,q
70
'77
1Ci
7q
Ko
Ko
150
,f.:7
Ko
Container Descr:pt,on
pH (su)
-· .---
1,c·.']t/ ,, /CJ,b
G.'i1 'f,'-/ r:, /,' t:' ,. J-...1 '~ J_ t:. ., . • >I <,O
t,:, l,/ 1 "'. ·~ 6:l'1 < i
C.Zf '/ r. .--.,
t:, :z r //-/
C::ZS' I. ,. • t'...
(,.Zr:; I, ,? .J
0i;solved
Oxygen
(mg/L) -/. 7'/
0. <l( ,J
o.1i;
0 ;:·i • • ,I
o. 'IZ-a. -r,r
0,1';(
ORP (mVJ
-
//(, 5
//'I. 6
//-J,.2.
Ji<o,o
/r:JC/.1'
lo1.i
11?'1-6°
(7. L// · 1oq,1
{}. -S'l /! (.{,
0.'-// ill. (7
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I Remarks _____________________ ~---------------
Porameler Conditions: pH +/-0.1 sfClndord unit
Turbidity +/-10% above 10 NTU
CONDnemp •/-3%
+/-1 NTU below 10 NTU
208
DO
ORP +/-IOmV
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CNA{Ticona I low-FlowGroundwcrer Sampling Log
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Purged Well Sampling Log
Project No. 26QS07 Kubal-Furr & Associates
-E11I•iro11111e11tnl Co11sult1111ts-Sile Location CNA Holdings/Ticona, Shelby, NC
Field Personnel Greg Kinsman / Jeff DeWitt
Well I Sample ID )///-ff
,;2. J 1 / Weather Condition jb,~ ;;;:/,,--✓ , ,
SampleDate ,/-fl1/p ArnvalT,me /cJ~O SampleT,me J /1;2.(]
Descnpr1on of Measuring~ ~-[:] Casing~ Point (MP) r.:cc:.,:___ Casing Type "-...JT Locking Cap ......... Diameter r.7< .
inches
Total Depth of Well Be/owl
MP? 50,·7~, .. ,I C:gmmgn GallQns Qer FQQt C:Qnv~rsiQns
Depth to Weter Belo'Y MP?I
Column of Water in Well?I
Gallons of Water per Foo/I
(see chart)?
Gallons of Water in Well? I
Gallons of Water to be
I Purged {3XJ?
Purge Method? I
Purge Start Time I
Volume Purged
Time
Temperature
Specific Conductance
pH
DO
Turbitidy
ORP
1/2,/t , . .,I
o,k, t feerl
(;, 103
gol//0011
/1/ gall ,r, ;73
g°"
't)41l,OZ. I
/._1,"J/ I
Initial
(:i gel J,5 nol
/'t-JI IJ.s{..
/l.55',c /6;50,c
51 ,s So µS
{, /) i· 5". -')'i, uoils , [,.,C
stavri:s
{, 6'1 mq/L 7.g'Lj mn/L
/. t, NrU 1-s.t-l NTU
j:Jf'( mv lfo,z ... mv
1 1
/4 in Well Casing= 0.064 gal/ foot
1 1 /2 in Well Casing = 0.092 gal / foot
2 in Well Casing= 0.163 gal/ foot
3 in Well Casing= 0.367 gal/ foot
3 1 Ii in Well Casing = 0.500 gal / foot
4 in Well Casing= 0.653 go!/ foot
6 in Well Casing= 1.469 gal/ foot
Total Gallons Purged I '7,~ 201!
Purge Stop Time I 13as--
2 3 4 5
;.eJ ool
,--;, 5
ool 6,0 nol •7.5 qoll
/'Zf/o /1,if(j, /?!JJ J-?r:.l-S
/6,5'G 'C /(;.SI 'C IG "r ,;_;, 'C /(?'Z-,c
'-11 µS '-Fl µS C: i/6 J CJ ./-,IL.JS µS ,:;·'"1 5:z;1 ~~;i;~\d <•,<f~ ..,,c _.' ,. , s:c units stdunir; stavnits
t. '-/r.J on/L g:,iy mg/l Y,'-/ I I' ,.,! mq/L 1{.?S~q/L
5>-5 NTU
gr-~ :J, I NTU (//, g NTU iCfv NTU _,., JL/,: 1}1:,:1 '2,(} '/. 5 -, ' ,,, . .., f..-, /.,<, ....
MV l-l.. • I r:'.'I mV
Samples Collected , Container Description Preservative
;jc.z
Turbidity +/-10% above 10 NTU +/-I NTU below 10 NTU ORP
209
+/-10%
+/-l0mV
Revise 5/28/02
Low-Flow Groundwater Sampling Log
Project No. 26QS07 Kubal-Furr & Associates
-£11t·iro11mmt11/ Cv11:wlt,111/;:;-Site Location CNA/Tlcona · Shelby, NC
Field Personnel Greg Kinsman/ Jeff DeWitt
0 /4 Well I Sample lD ---=ccc•_._f,___,_7 ______ _ ,J._ 'J. ,/ i'3 /J },f Weather Condition _,_,
1
f.;:,tt'jl.;;:J:..,,.c'--"c_,.<,_c_7. ____ _ Sample IJate _--1'----'-/-'-, _______ Arrival Time _________ Sample Time__.'-'..,,..p,..._ ________ _
Oescr:ptianol,\.-1e~suringg] Cosinglypelr?v,· I LockingCoP0·. Casing{g:J Point (MP ,:t?L I C..-✓ 0iomete c< . ,ncries
Purge Methodlft._~,,S~?flTr<::.
Purge Start Time I JJ .. r-o I
Water-Level Measurements
Interval
0
I
2
3
4
5
6
7
8
9
10
II
12
13
14
15
16
17
18
19
20
Elapse Time
(mtnsJ
8
) ;10
/ 0 1'/ll·~·
/5 1""
~Lo r11;r
~(;' ,.y6 l,J,
~o \1\L"
DTW(feet)
J-/,?, lo
•)'1,,'JCj
17.,5()
2.LS7
'2:J,, ,(~('}
"ZZ .(S"L
1'1,6S
Samples Collected
'UOlJ
Interval
0
I
2
3
4
5
6
7
8
9
10
II
12
13
14
15
16
17
18
19
20
Sampling Method! ~/C
Purge Stop Time/ /t./J.. CJ
Field Parameters
Elapse Time Temperature
lmins) (0C)
{) ---
s-l'i{, /{,
/0 IF. ,15
IS /,f'. cY['..,
:J.o /r?. OG
:;.;-17. ,J{,
~ If'. O'.J
Specific
Conductance
(µS/cm) ·
--
I I,
/5
i5
/7
IS
t5
Container Description
.:f'x C/titl/ I
Purge Ratel 1.00 miim,nl
pH {suJ Turbid:ty (NTU)
----
,:;; 71 ·-i I•
S".oL 1, 'I
L./, 1{/ z, '-/
L;, 7(, 1 . ').
L/, {,(, 1, '}
4, J'-i ,., ,,
I-•L
Prese-vat1ve
Dissolved
Oxygen
(mg/L)
---
7-$/
7, "/5
}.5J
'7.s"I
'J.2?
7.Jo
ORP (mV)
-
2 5'q,<f
1_1/5', '-/
J.6/, 5
·[{5:o
J..77. 5
2.77.0
Remarks _________________________________________ _
Parameter Conditions: pH +/-0.1 standard unit
Turb'1dity +/-10% above 10 NTU
COND/Temp +/-3%
+/-1 NTU below 10 NTU
DO +/-10%
ORP +/-lOmV
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21:0
CNA{Iicono I tow•AowGroundwoter Somp!ing Log
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Kubal-Furr & Associates
-Em·iro11111rnt11l Co11j1iftanls-
Low-Flow Groundwater Sampling Log
Project No. _____ 26_Q~S0_7 ____ _
Site location __ C~N-'-A~/~T-"lc~o-'-n~o_•~Scch~e-"lb~y"-, .o..Nc.cCc.__
Field Personnel GreJJ_.Klnsmon / Jeff DeWitt Well I Sample ID --1;,--=8.._... __ 0-J~·-r-~-----
,,, =l/'' ,n -7 "/I It.; Weather Condition ~1Zu'l1u(.,,_/d",-.,_r,_f,c...•~------Somple Dote J... ~ L. (.I ~ Arrival Time }'-yT Sample Time · /(~;) CJ
Desoiptiono1,:emu6ng§J•·. CosingTypeQ[J·s I ./ I Casing!::: =~===-1 ~~-----Point [MP) /c.. t .(._. , Locking Cap ✓ Diome~er .~ ~· ====::'..· --~ ,nches Purge Methodlf?-""~-vJ/2J Sampling Method\ ~p-t::C-
Purge Start Time! /~tl(.i I
Water-Level Measurements
Interval
0
I
2
3
4
5
6
7
8
9
10
II
12
13
14
15
16
17
18
19
20
Elapse Time 0TW jfeet)
(mins)
0 . 3-S-:~!
S;,,, '"?77!.f ,j.,
io /'IL "<,"J.fG
IS qS I, '"<f.({
'/0 I ,;'l' Z,'l,17
·2.s: .,st ·?x,51
'30 r:3l sX:f.f
1J5 Cf5 Sf.61
'/O 15</~ ff.-t.s' v-··r; ) ;s· _, sr.11
;-o ,s:,v "<.f(, 7 I
c-C-·r-5r 7/ j.:,-' 515,6 '7
hV 16" 3t.Cl
(;<; Jr,,.,, sf.67
7kJ /6/D <,,f;"/:5
'"1.17 '" j(,,0 rt-ifo
Samples Collected
Interval
0
I
2
3
4
5
6
7
8
9
10
II
12
13
14
15
16
17
18
. 19
20
Pu,ge Slap Time I /(,,/5
Field Parameters
Elapse Time Temperature Co~~~~~~~ce
(mins) (°C) (µS/cm)
a ------//,./';{ r:;1 .._:, ,n i?,.l/1-f-i(
IS i6. '?.I {'}..
1.,_e, I'll? (.-S
2-5 i'755 1,7,
JC' /(/,:,JL (/j
J,; lv.i/J.. 7i
4o /?.'SI 7t.
l/~ {x,/'-{ 71
~Q j,'?; o(b 71 .r,e _,, , it. Ol( 7/
60 /8"-D) 7/
(,'5 ~-07 17,
7l' 11.cTJ 72.
75 11.'2.'l., 71-.
Contrnner Description
Purge Rotef;btc/ ml/m,n!
Dissolved pH (su) Turbidity (NTU) Oxygen ORP [mV)
(mg/L)
----·--·-
/,.o7 /1..0 15."16 /oO,/
C,.i'J i7.0 i./.(-,(; t?S.'J
(,JC/ 30.·-f J.'fj /56,5·
(.i.1 'j_ q_J... J,. '-I'! /]f,,'J r; .,,:-. ,._-' 17.5 'L6o /Jl.1
t:2'1 J,.l.'l }.., ?5 er ., .A/ t-
t,, Jtf -i.{/1 /, 71. X-6.f(
6,r6 ·J..G. o /. ~•> -/.5 g;, {}
(,,36 1~b . C:/ /, ~ h<j,O
l,,JJ ..... (; r· ..s . ,.J /.6/ (Jf./
(.'37 32.0 IC" • ./ j 60,5"
6.16 J.-7.f' IJ/6 t,;/. l
6.:s'6 J-0,'1 /. ;;~< C,1_ C t] ,; _;,J
(. ""6 . > 0 ?..:S.•J 1>1r S"'l.0 c: s't, . 'J_l/. '-{ 1#1 )L/.5"
Preservative
/fC/
Remarks ____________________________________
_
Parameter Conditions: pH +/. 0.1 standard unit COND/Temp +/-3%
Turbidity +/-10% above 10 NTU +/-1 NTU below 10 NTU
211
DO +/-10%
ORP +/-\OmV
CNA/Ticono
Low-FlowGrovndwater Sampling Log
Low-flow Groundwa;er Sampling Log
Kubal•Furr & Associates
-Enl'il'o11111rntal Cv11:w/t,m/~-
Project No. 26QS07 ------""-"='-----
S de Location CNA/Tlcona -Shelby, NC
Field Personnel Gre Kinsman/ Jeff DeWitt ')0 /4 Welf/Somple/D .,-&-bl (7, '-/ r-2 /4/ ~/ f/eolher Condition __ l=c#---p,ci,:.R,~r~.<'-_·"f-1 ~''-="--Sample Date __ ,__c__c_ _____ Arrival Time,----;====;Sampie Time _ _ ';;, ft7'7 ,·,{) . '.
Description of Measuring~ C T I rs-I L k C I ,_,....-I Cosing1== ,,••==i.,::t~'-------Point (MPf t:X"ll-ming ype ......\ oc ing c;:i Dicr:1eter C><
ir>CJ'le5
Purge Method I f'i?L1S7?/tflc I Sao,pl:ng .v,eroccls.J.1,.1,.;-
Purge Start Time I /h.s:;:{ I Pu•ge Slop nmel .tft-t.._ I
Waler-Level Measurements Field Parameters
Interval
0
t
2
3
4
5
6
7
8
9
10
It
12
13
/4
15
16
17
/8
/9
20
Elapse Time OTW (feet) (mirn)
c.J. /9./()
,) lt/.s/
JO /l'3S-7,
/.~~ /o/, ')/'
:.J.o •1cr s'I
,ls--/9.t/o So ;,;, '-II
3,S" /?. 'IJ.
t/c) /i ,lf3
Lf-':,' I' , lit/
Cu /C,t(L/
..)_<,-I' ,t/5'
{;,() I' ;c/.:r
t·S-/1/,lfj~
7() ;7. r//,
·Js-I 't,'f 1
~') ;q, v,:·
.fr"' i1. 'fJ
Samples Collected
VDC.J
Interval
0
t
2
3
4
5
6
7
8
9
10
II
12
/3
14
IS
16
17
18
19
20
Elapse Time Temperature Specific (mins) 10C) Conductance
(µS/cm)
t:Y ----
s-/.~2o 111
/t> /•,-, I'{ ///., ~-1<.1!' ~ //)
20 l.s./.S' II.-/
.-.2..r· l<:1.s /19 so i.5':16 /17
tr l-!o--:/t, 11.<
'/tJ /;). /3 ii/
'-IS" /S,cJt /10
... )() IJ.tl< /ti]
sr l.<,o3 /tf7
t,{I 1:::01 /t7S'
t,s· /-Jd1t) /o_:,-
'lo /'(, ';{, ltt/
-7.1 11, t;'c/ /13
x"<J /'l/j'2. iof.
¥') It/. 93 /o3
Container Oescr;pt:on
:lx '{0/4/
Dissolved
pH (;J) Turbidity (NTU) Oxygen ORP (mVJ
(mg/L)
------· C,,.S'-5 /, 7 3.97 /~9
~,.S°{;, o,(, 3 Jg7 J,29,o
t,,{f /,; /,,J,J /~27
t,,7<f I.~ 0,.1:,7 //Y-,D
C,,7~ /, 0 0.'/9 11.{'; 1
&,(,1 /,2 0,1(9 f's.o t,sl, /,0 t?stJ •l</:7
/,,//9 /.I 0,b9 ·1s:o
(,//✓/ /,V 0;7/ 'I: '-I
{,J/tl /, I ti,(,(, ;-J,Lf
IP,39 /,0 0,.,:;-9 ·-0, </
&,¾-0;<J cJ,t,.J -c~ i
I,, 37 /,/ CJ,'Jf) 2, I
c;, 3(, I. j (((,,? t,;.q
l,,Jt/ lO (~74 ,{,/
t:.'51 1: 1 0.12 f(;l
r,;_3} /,o {l'?7 ,.r,, r
Preservative
l{cJ
I
Remarks ______________________________ _
Parameter Conditions: pH +/-0.1 standard unit COND/Temp +/-3%
Turbidity +/-10% above 10 NTU +/· 1 NTU below 10 NTU
212
DO +/-10%
ORP +/-IOmV
CNA/Ticono
Low-FlowGroundwater Sampling Log
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Kubal-Furr & Associates
-E11:·iro1t111.·11t,1i Cv11~:dt,111t;,-
Lo•n-Flow Groundwater Sampling Log
Project No.
Site Locotion
Field Personnel
Well / Sample ID
260S07
CNA/Ticona · Shelby, NC
Greg Kinsman / Jeff DeWitt
Wea/her Condition Cir rohf SampleOote h · 15'1 o'? AmvaiTime <(}JJJ SampleTtme~=~~0~8,c-_l_/l-,-------,~~~--;:::===
De;c,pfonofMeaso,:ngl / O''lr· IC , 1 [KJ·< LockingCopl (/ Cming[TI: Poinr (,\.tP) < I...{_.., os,ng ype ..)._.) 1 Diomete A ::=;=::=::;::.=----..; ,,.c.,e1 Purg~ ."-te:hudl 6-rc.4-v,llos· I Sampling Method/ (~{'!.,,'!:{./(-.-.
Purge Start Time) of~,, J ) Purge Srop Time/ QX'3S
Water-Level Measurements
0 ,
2
3
4
5
6
7
8
9
,o
"
12
f3
f4
f5
16
17
,s
"
20
E1.opse Tir,e
/mOnsJ
f1J. -· -·' .
J,:., ,,. . ,; '
t5 . ,f,;
z'-7. ✓-·"'.•
,-'
'~f ,if~
5~) i~r:"
i5 i:,11:;~
t . .' •• ' (, ,_ii' ';l
·/S 1f.~·
3): ~16
;-7.c,,,1
-~-; !: ) . ·.)
3!.7'/
3'!, "!;
·r;, 91
37/J'i
::!.,'')_":?
Samples Collected
Parameter Conditions: pH
Turbidity
Interval
0 ,
2
3
4
5
6
7
8
9
,o
"
12
f3
f4
f5
16
17
18
19
20
Eiapse Time
rm:ns)
rtl)
~-
j.;
JC
-z. ... :~
·Z.j
j()
?5'
~C'
'/5
Field Parameters
Temperature
fCI
-
/·t .~f//
:1.c: -I ..• ,_
/1., :Jf
/7.{)(;i
/7:1_{,
I 7.;,~;
i7-Fl
Specific
Conductance
{!JS/cm)
-~
·u,,9
/i-3
··1e,,c, _..,,I,
'.?o'I
](.,1{.
:.?o7
'?, (? 0
Container Descr1pt1on
... /. 0.1 stOndord unit
+/• 10% above 10 NTU
COND/1emp +-/-3%
+/-1 NTU below 10 NTU
213
pH (;u)
-
>.i.l';
'-/, 7/t
",' '7 .,
, I '
'7, 7i.l
'/(..-')
'/.{,'/
,'.J.{J
DO
ORP
Turb:z ry (NTU)
Dirn:ilved
Ox·,gen
{mg/Li
ORP (mV/ ---'?1 <7. 'I'' (.. / ·1 .., t, l.../s.. ;,l
..._')' l, } . ...,., :, .. J.i.. 7.J'I. ()
4:::-, .J ') ,nl
ot.. -~ I J.J.l.3'
•7 ~ 0.21: ::.:z.1.;1 ,1 7
/9 ().2.:; ;J.J~.\7
/. I-, t.,.1..J. I J..Ji:,/
J.6 1).19 ;l.:,,'F-8
/-/<1
+/-1~ ~
+/-lOr.iV
CNAtncona
low•FlowGmundwcre< Sampling Log
Kubal-Furr & Associates
-Em·iro11111c11ta/ Co11:;11/t11nt:; -
Low-Flow Groundworer Sampling Log
Project No. 26QS07 ------------
Site Location __ C_N_A~/T~lc'--o_n_a_-~S'-'he=lb~Y~• '--N'-'C'--_
Field Personnel Greg Kinsman / Jeff DeWitt
Well I Somple ID --7~,1r,5"-"='f(~--~-----
Weother Condition -C~-,; -,j')r-'r:-c/1-r(-,r-------n n ~ •• r)~.~~1· ~=~.4 •• ~~~n-----Somple Dote • t.-_,,. · ·O :J Arrival Time_,,L_..a{)'--".'--"~--~-Sample Time;===='!:,;-'''-""-''--------
Descciption o/ Memudngbi....,oc: I Cosing Type~ Lockin Co r-p7 _Casing ~I Point (MP) (./ ~ g Pi__{___J 01amete >--7' , Purge ,\.\ethodj (TF,~1,(./.;:, I Sampling Methoc! (~f,:.,11.y-,£) 5'""". I
Purge Start Time[aqj5 Purge Stop Time I l,?f{ Purge RotellLJ s-o ml/mini ' Water-Level Measurements Field Parameters
Interval
0
I
2
3
'
5
6
7
8
9
ID
II
12
/3
/4
15
16
17
/8
19
20
Elapse Time OTW (feet) {mins)
.,(1 1-,J.9a , . <; o<;"J..c ?..!../. 'f'I
k? l-~Z5 '2 :i:tJ
J<; ,,.,fi)'.: 1-Sfio
'Z.c.) {J'i~ ·2r.,.t,</
z5,· ,1{1, ');.7.ox
3o ,11~ ,).},</'i s~-,,-:?c J..?Jd:,
i/o o't'i! 1X;o
•I'." " ) /(),.','• 25(';}?;•) (
'5~7 /t:.t'.,' 'J..8".'ll
n~ ;o/'} ?.P.11/ ,_
to j:J ,") ;,q,s5·
(.") Joi,;,
1o ' ,···~ H,'-~
Samples Col,ectcd
lltJCx
Interval
0
I
2
3
'
5
6
7
8
9
10
II
/2
13
/4
15
16
17
/8
19
20
Elapse Time Temperature
(mins} (0C)
--
.c; I, ;·· / ,. !'
I,} /5. Ge; I< IS.JS
1.o I 1,,1-Z
ts· 1/,./f
j(7 /C,.-Z7
35 /?,. 1/6
7o /{. )/
•/'\ ft,;, Ci'?
?I? ih. ff1
5.c; 17,5"%
f,() /7.27
65
70
I
Specific
Conductance
{µS/cm)
~
I s-r,;
j.555
ISs2
I S-t".o
I ""6·· _, l-
S"(,</
567
St?/
5"70
5'.Ji
'>77
5'71
Container 0escr1pt,on
pH (Su) Turbidity (NTU) --
< "(, ..J , I • j'/.f
G,16 /L/, ~)
(,.?o /'J.f!
6,t~x' t'l /-j
c;. a; /J, "3
6. 'JZ. II 5
(o.JJ /{~V
t.J/, 9,</
t,,J'/; K-o
t,,J{.; r:.1
6,1?, 7,'1
t.vr 7.S
Preservative
Dissolved
Oxygen
(mg/l)
-
/,17_5
iJ,</-j
o.f:f
o,:Ic
/)/ii
0.'/"l
tJ.1//
'l, -~L; t'., J
0,3·)
tJ,;o
0.27
I). z~1
ORP {mV)
--
5/ 2. 7 ,, .J..
o.r1
-1:1
--J' ,_
--s;s· ..,,-,-
J' . t,.. -. . ___,
-7.:s~
-rr..1
-'?!l ~-· --J
Remarks ______________________________________ _
Parameter Conditions: pH +/-0.1 standard unit
Turbidity +/-10%obove JONTU
COND/Temp +/• 3%
+/• 1 NTU below 10 NTU
214
DO +/-10% ;;
ORP +/-lOmV
CNA/Ticono
Low-FlowGroundwoter Sampling tog
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Kubal-Furr & Associates
-£m,irv11111rntal Co11su//r111t:;-
Low-Flow Groundwater Sampling Log
Project No. 26QS07
Site location CNA/Ticona -Shelby, NC
Field Personnel Greg Kinsman/ Jeff DeWitt
Well I Sample ID ~~7<~--.1~8~-------
c;J. Weather Condition ~,;,.,/ ,,r.:/1 r JC/t./
Sample Date ,<"'I',.,., i-s··-oJ Arrival Time,.....,_l~'•O,__· ~,'.,_l-'-11-'-·--;::====Sample Time _'--'_· __ .i_J:.. ..... (c.,lc..' ... 3~:;,.--____ _
Desc,iplionofMeaMingl-1 Ouc· I Casinglype~V(,· Locking Cop Casing[IJ') Point (,\.\P) • Diameter ,1,-,ncrie1
Purge Method I n~l';'S/.,,;l!.r Sampling Methcd
Purge Start Time I i () l/). I Purge Stop Timel,-/'"'/;--j;--l-, -, ~~~~-~--P-u,-g-e-Ra_1_e1:-,"t.--c/-,,-,,,-m-,,-,,..--.nl
Water-Level Measurements
Interval
0
I
2
3
4
5
6
7
8
9
10
II
12
13
14
15
16
17
18
19
20
Elapse Time
jmins) DTW lfeet)
fJ . J -;..., 'ft/
f: 105e• /'-/.,7'/
/<J ,< ,,;,..,, /'f.T?
/-f 1JD•' l'f.o9 z,, JI? S /{, 59
·"<' t,, jlt() !5. 1tf
J,, ;rfJ !S.l,:J..
3> 111,; /{, 79
i-Jo 11·1.1 ;s/iff
J../) p'fo //,,/ s-'
Samples Collected
Interval
0
I
2
3
4
5
6
7
8
9
10
II
12
13
14
15
16
17
18
19
20
Field Parameters
Elapse Time Temperature
(mins) (0C)
' (} -
5· I'"' J _,. I
f{! iS,{.J"
!5 /'), !%
i?ci i' c;.? _,,, ; ~
--:-c ;s;tfo lJ
JO /).f;
35 }-:;; ,Yi
t/o /S'.7/ .. < l/ J ;'5.(tl
Specific
Conductance
(µS/cm) -
!SI
/S:S'
15<
;s-'-1
/S:J
!SJ
;.t: -, ✓J
!'" --' l-I,,-.. , ) I.--
Container Descnpt1on
Dissolved
pH (su) Turbidity (NTU) Oxygen ORP (mV)
(mg/L) --/ -
(.c,5 t;r ., i}. 76 -ff,8'
'S'.q-;.. //.-Z, /J."C -2s:c,
,:-· VJ' ~, I (J 0 , .. O,J.(, -;,7,5-c· "7,_, _,, i 5 '/,J o. -Z-<.7 •jfO < 'I
5'. q-z. R,7 0,/6 -J.CI 'l , ..
,r,:;-, ...
.. ;,J.1,-. S-,9 17,/j' 'JI., -• L.
;:· r; I , • I 2, I O.f-Z -·?'o.1
'),'}j ?,Y ,J j•? •' J (,,,.
j'. ., -· C,'. ;
":/. ?CJ ?,J (/,// -2"'" 6 I, '
Preservative
Remarks _________________________________________ _
Parameter Candit:ons: pH +/-Q. l standard unit
Turbidity +/-10% above 10 NTU
COND/Temp +/-3%
+/-1 NTU below 10 NTU
215
+/-10% I V
ORP +/-l0mV
CNA/Ticono
Low.FlowGroundwoter Sompfmg Log
Low-Flow Groundwater Sampling Log
Kubal-Furr & Associates
-Em•ironmmta/ Co11:5u//ants-
ProjeCt No. 26QS07
Site Location CNA/Tlcona · Shelby, NC ----~-----~---
Gre Kinsman / Jeff DeWitt
,-. Weather Condition (";.,/.) f'"' I/,_; " r;...r:· ..-, j(Li, ~=,,-,-<il2-=-,,~--sompie Dote_~,£~-~-,C':=,J=·-:::():::· :::V:::;----, Arrival Time_~~7~----=====Somple Time=-----------'' fi~-c,?c'--J~_,_1 ___ _
Description of Measuring TOO( ~~-IT] Cosing(EJ' Point (MP) •Cosing Type _) Locking Cop / Diomete ,J.--. . :=;;,;::::="i=--/,----,' ,r,c;hes
Purge Method ·_ .,' fcjf_ic Sampling Methodj ,(./..1,nfk/f:l.·
Purge Start Time I /152. j Purge Stop Time//j'{:'1) Purge Ro1e["--J.'"( ml/min/
Water-Level Measurements Field Parameters
lnter,ol
0
I
2
3
4
5
6
7
8
9
10
II
12
13
"
15
16
17
18
19
20
Elapse Time DTW (feet) (mins) ,
f'_J . /r?, '5.,.t
s· 11t;·1 /1, lo
IC rt.v" Ii, g-s·
/) jiff li.;Of
·zc-/'l{Z ll,t:S
·-Z~ }l;J /i;JZ,
J,; ,i'll /,},'{(
1::-1in IJ., if I
L/o i·f'il /2.'S)
·,;--. ,; ..J ,,-,1 . 1 .,.Q J';..,J"
<:o ;,'11. /J,r<J
55 ,ti/7 /1.,,f:o
Lu t1Yt.. /JhS
/,,'; tl<"I j-;__,{,l,
7C' ii•''
/) rJ,'7
8b Jf/1-
J'S im
C,c ;1tl
c.c:· /J'/7 ,_,,
/Cr.1 1:7:(I
Samples Collected
Parameter Conditions: pH
Interval Elapse Time Temperature
(mins) (0C)
0 Of -
I '< J'i.'1'3 .J
2 /c:) 15;7s
3 /', ;~ r.1z .) ' I ~
4 "Z c...,1 /{ f .Oo
5 ·zs~ /(., ;-'-/
6 JC' /{:;IJ{i
7 ,.,,) _, ;r; fil{ , • I
8 '-/C' rs. 'fcJ
9 4~ /5"'.Cf-Z
10 .S-<J if.OS"
II ":S /5'C.(, • I '
12 /-.t1 -r.~'9 J , I
13 f, c:; /(.,.t.77
IJ 'l6
15 -~
16 t(J
17 ~5--
18 'to
19 C< L,
20 ~)D
Specific
Conductance
(µS/cm) -
f<//
C/11
917
it Tl
;'3]7
ib'lq
J_p,-£
?..;./k)
2.?JZ
2.6-St
1f/'l
1x?'3
-'1"} ,::-r: ., ...,
Container Description
+/-0.1 standard unit
Turbidity +/-10% above 10 NTU
COND/Temp +/-3%
+/-1 NTU below 10 NTU
pH (su) Turbidity (NTU)
---
c;:-z6 '?;5
~-!'' _, • I -7 '7 $•
,:-· J,/Z. -g, f
s:01 s.~
lf.1'1 !/_ ;J..
'-/,P/ 3,. /
Lf,75 __ -7,t
'f, 71 3,t
'f. 7{, ., 2 /-.··-
'-/.1<;· -~ I o,
'-I. 7'/ s.~
4.7<: 3 I
i..f, 71./ 'l. r . .)
Preservative
DO +/-10%
ORP +/-l0mV
Dissoived
Oxygen
(mg/L)
----tl,'/f
o,'?7
(],Z.if
(7;l<J
0.11, ,1,1;;
t'},;J
(),/1
iJ,i'J...
cJ,//
L?,fJ..
1JJ1
/},/'(
ORP (mVI
____,
tjL/, 7
'/ZS
'lZ,5J
tn:5
5,-, -t,.
--5'3,·7
S'-lf
. r"'•) '1 ..JN
'-/7.1
'f-'-1.(.
i./:' 1-. '-·,
:.l'J. '2.
Jt'l
CNA/Ticono
Low•FlowGroundwoter Sampling log
216
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Sampling Log-Grab Water Samples
Project No. 26QS07 Site Location CNA I Ticona -Shelby, NC
/4<:•'J Arrival Time > ~ ,,_ Sample Time /l//c) _ _;,,,=._ ___ _
• f7 C /;/ -L/ . .f Sample ID r,,_, Field Personnel V j) -------
Weather Conditions (,:Jo/ C !,/ti Sampling Method
Sample Temp. (QC) //{, L/7 Spec. Conductivity(µS/cm)
ORP (mV) Jo 1/. 5 Turbidity (NTU) J:2. DO(mg/L) /. 5{} --'~-----
Method(s)
//(}{, .
Container Description 5 ~ ifo,i. I
Preservative
f/CI -· I
Remarks
Sample Date ;2. · }.:-;:-[]'] Arrival Time ~/_,.s~·"_)~L_-__ _ Sample Time _f_';/_1/.~~-"'_· __ _
Sample ID f EAi-S -Duplicate No. ______ _ Field Personnel JD -"'-'c,_ ___ _
Weather Conditions /
. I}
('rJ,JJ < /Cll( Sampling Method
Sample Temp. (QC)
' j ,,., /!{ .,,_.1,..,0~. -~·~ __ Spec. Conductivity(µS/cm) L./i/ pH (;,,I{,
ORP (mV)
Method(s)
L'r'Jc;,~
Remarks
Turbidity (NTU) -'-'·~~-·-~--~DO(mg/L) ~/_. ~f> ___ _
Container Description
1 x Z/4? lli I
Kubal-Fun-& Associates
21 7 '
Preservative
)/('.! -
Revised 7 /30/02
Sampling Log-Grab Water Samples
Project No. 26QS07 Site Location CNA / Ticona -Shelby, NC
Sample Date _.3....,' 0~/~.J._,_/4~~~3 __ Arrival Time Sample Time _...;./,...:.;,;__1/_c._· l __ _
Sample ID Duplicate No. ______ _ Field Personnel __ Ut=-·k.::..·-=-·---
Weather Conditions .£;,, "-'lo':j ·· (,,oJ Sampling Method
Sample Temp. (QC) i /, '7 <f Spec. Conductivity(µS/cm) 1/C pH _t,--'-t.(,___/ -
ORP (mV) Turbidity (NTU) !. I Li,. f-).
_ _..c.,.· _,_, =b ___ --'DO(mg/L) _..:.._/_ , ___ _
Method(s) · 1,h:::s: . Container Description J~t:t1
Preservative
ff<-/
IX
Remarks
Sample Date ______ _ Arrival Time ______ _ Sample Time ______ _
Sample ID Duplicate No. ______ _ Field Personnel ______ _
Weather Conditions Sampling Method
Sample Temp. (QC) _____ Spec. Conductivity(µS/cm) pH ______ _
ORP (mV) Turbidity (NTU) -------~DO(mg/L) ______ _
Method(s) Container Description Preservative
Remarks
Kubal-Fu1r & Associates
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21 s:
Revised 7 /30/02 I
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DATA ASSESSMENT SUMMARY CHECKLIST AND REPORT-LEVEL II
Client ID:
Project Number:
Monitoring Period:
CNA Ticona -Shelby. NC
26RP I 7 /26OS08
02/03
Sample Delivery Group (SDG) Description:
Prepared By: Laurie Chandler
Date: Revised 6/27 /03
Quarterly groundwater monitoring well samples were collected by Kubal-Furr & Associates of
Simpsonville. SC. and analyzed by Davis & Floyd. Inc .• of Greenwood, SC, for volatiles,
ethylene glycol, and total organic carbons in accordance with EP A/NELAC or other approved
regulatory requirements.
CONTENTS LEVEL COMMENTS
II
Sample Results V All data Class A as reported.
Chain(s) of Custody (COCs) V Acceptable
Master Tracking List V Acceptable
Case Narrative
Sample Prep
Standards Prep
Instrument Quality Control Data
Batch Quality Control Report V Reference voes section for
comments.
Surrogate Recovery Report V Acceptable
Trip/Field/Equipment Blank Report V Acceptable
Field Notes/Logbook V Acceptable
CLP Forms
All Raw Data
Electronic Deliverables V Acceptable
-------------Kubal-Furr & Associates ------------
1
CNA Holdings -26RP17/26QS08 DAS -2 -7/1/03
Discussion:
The laboratory submitted a revised version of the results report. The ( <) symbol was removed
from detected acetone results for samples ITEF and ITEF duplicate. Also, a comment addressing
asterisk symbols for compounds 2-butanone and acetone in batch ITCI was added to the report.
Reference VOCs narrative below for qualification of compounds in ITCI.
Volatile Organic Compounds (Method 8260B)
All volatile data is considered Class A as reported and fully useable. One comment concerning
matrix spike/matrix spike duplicate relative percent deviation of recoveries is noted in the
narrative below.
1) Matrix spike/matrix spike duplicate relative percent deviation is above laboratory-
established criteria by I% for benzene, carbon tetrachloride, chlorobenzene, and chloroform.
According to method 8260B and National Functional Guidelines, the reviewer must exercise
professional judgment in determining the effect of MS/MSD ¾RPD on sample data. Upon
review of other available batch quality control data, there is no indication that these
insignificant recovery discrepancies have any impact on method accuracy and precision.
Duplicate field samples and laboratory control recoveries demonstrates there is no
interference in the analytical system. No qualifiers are assigned to the matrix spike sample or
any associated analytes.
2) The laboratory reported asterisk symbols to indicate possibly high biased results for acetone
and 2-butanone in sample ITC! due to matrix interference from non-target contaminants.
Acetone and 2-butanone are qualified as Jin sample ITC!.
Ethylene Glycol (Method 8015)
All data is considered Class A as reported and fully useable.
Total Organic Carbons (Method 9060)
All data is considered Class A as reported and fully useable.
Class A = quantitative Class B = qualitative Class C = unuseable
J= detected target analyte however, result should be considered as estimated.
-------------Knhal-Fnrr & Assodati,s -------------
2
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DAYIS
FLbYD
July 24, 2003
PEM CARTER
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC. 28152
:L03051607
:61621.01
LABORATORY ANALYSIS REPORT
Login Number
Project Number
Description :Q2 GROUNDWATER-REVISED 24-JUL-03
Dear Pem Carter:
We are pleased to provide the enclosed analytical results for the samples received by
Davis & Floyd, Inc. on May 15, 2003.
A formal Quality Assurance/Quality Control program is maintained by Davis & Floyd,
which is designed to meet or exceed the EPA, NELAC or other appropriate regulatory
requirements. All analytical analyses for this project met QA/QC criteria and the
results are within the 99% confidence interval for each method unless otherwise
stated in the footnotes. This report is to be reproduced only in full.
Feel free to contact our Client Services Representative at [phone] if further
explanation of the analysis is required. Unless other arrangements have been made,
samples will be disposed of or returned 14 days from the date of the report. We
appreciate the opportunity to provide services to your firm.
Sincerely,
DAV:S &'FL{OY/NC.
,------/ri,JY ;,//,
]6hn H. McCord, Jr
\_,,,/ Laboratory Manager
I Davis & Floyd, lnc. I PO Drawer 428 j Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
I O A'T IS E nt:c_ JUN 2 7 2003 -~ ngineering lJ1li.:'
I FLtiYD :::~::~:u~I & l.lboratory Servites ";".~:=~::_~:-~oiZ s l1> -i?, I I ''''"""'"·'"''"""'-"""·""""°.-"""""""=="'""'a,,,........,_,..,.,.,,,,==•=_.,,.•ma<•·"'=""'~""'"""'"""""'.c>"""'m"'"'""'-""""".u,,~;..,.,,,s;,.,,,.,,: .. ,
RO. Drawer 428 Greenwood, SC 29648 • 816 East Durst Avenue Greenwood, SC 29649 • [phone] (office) [phone] (fox)
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June 24, 2003
Ms. Pem Carter
Ticona, LLC
2525 Blacksburg Road
Hwy 198 .
Shelby, NC 28152
Re: 2"d Quarter Groundwater Report Revisions
Dear Ms. Carter:
Enclosed is a revised report for the 2"d quarter groundwater-sampling event. There were several
clerical errors that needed correcting as well as a sample comment that was omitted. For sample
ITEF and ITEF Duplicate the Acetone was a positive hit. The(<) symbol was removed. A sample
comment was added to sample ITCI for the target compounds with an asterisk(*) in the Qua!
column. The comment addresses the interferences from non-target contaminants, which may have
biased the results high.
The QC summary data and method conformance data remain unchanged and are not resubmitted.
Please contact me if you have any questions.
--S-in
7
e=IY, i
John H. McCord Jr.
Laboratory Manager
Enclosure:
Cc: Jerry Kubal
Laurie Chandler
3
DAYIS
FLtrYD
June 24, 2003
PEM CARTER
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198 .
SHELBY, NC 28152
:L03051607
:61621.01
LABORATORY ANALYSIS REPORT
Login Number
Project Number
Description :2nd QUARTER GROUNDWATER ANALYSIS -REVISED 23-JUN-03
Dear Pem Carter:
We are pleased to provide the enclosed analytical results for the samples received by
Davis & Floyd, Inc. on May 15, 2003.
A formal Quality Assurance/Quality Control program is maintained by Davis & Floyd,
which is designed to meet or exceed the EPA, NELAC or other appropriate regulatory
requirements. All analytical analyses for this project met QA/QC criteria and the
results are within the 99 % confidence interval for each method unless otherwise
stated in the footnotes. This report is to be reproduced only in full.
Feel free to contact our Client Services Rq,resentative at [phone] if further
explanation of the analysis is required. Unless other arrangements have been made,
samples will be disposed of or returned 14 days from the date of the report. We
appreciate the opportunity to provide services to your firm.
Sincerely, DA~S;z;c~~
hn H. McCord, Jr.
Laboratory Manager
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Davis & Floyd. Inc. I PO Drawer 428 I Greenwood. SC 29648 I 816 E. Dil,st Avenue I Greenwood, SC 2%49 I 1864) 229-4413 I fax [phone] I
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DAYIS
FLtrYD LABORATORY ANALYSIS REPORT
June 05, 2003
PEM CARTER
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Login Number
Project Number
Description
Dear Pem Carter:
:L03051607
:61621.01
:2nd QUARTER GROUNDWATER ANALYSIS
JUN 1 7 2003
We are pleased to provide the enclosed analytical results for the samples received by
Davis & Floyd, Inc. on May 15, 2003. .
A formal Quality Assurance/Quality Control program is maintained by Davis & Floyd,
which is designed to meet or exceed the EPA, NELAC or other appropriate regulatory
requirements. All analytical analyses for this project met QA/QC criteria and the
results are within the 99% confidence interval for each method unless otherwise
stated in the footnotes. This report is to be reproduced only in full.
Feel free to contact our Client Services Representative at [phone] if further
explanation of the analysis is required. Unless other arrangements have been made,
samples will be disposed of or returned 14 days from the date of the report. We
appreciate the opportunity to provide services to your firm.
Sincerely,
DA VIS & FLOYD, NC.
H. McCord, Jr
Laboratory Manager
I Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax (864) 229•7119
5
Di\YIS
FLtwD LABORATORY ANALYSIS REPORT
NELAC Certification Number: £87633
Master Tracking List
Client TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Contact ·: PEM CARTER
Sample ID
L03051607-0l
Wet Chemiotry
SW846 9060
L03051607-02
Wot Chemistry
SW846 9060
L030S1607-03
Gas Chromatography
SWB46 8015
Volatile Organics
SW846 8260B
Wet Chemistry
SWB46 9060
L03D51607-04
Gas Chromatography
SW846 8015
Volatile Organics
SW846 8260B
Wet Chemistry
SW846 9060
L03051607-05
Gas Chromatography
SW846 8015
Volatile Organics
SW846 8260B
Client ID
K-28
ITEF DUP.
ITCI
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 1 of 2
July 24, 2003
Report ID: AB12417
Date Collected Date Received
05/28/03 1318
13-MAY-03 18:25 15-MAY-03
05/28/03 1354
14-MAY-03 10:05 15-MAY-03
05/16/03 1101
05/21/03 1150
05/28/03 1427
14-MAY-03 10:05
05/16/03 1126
05/21/03 1209
05/28/03 1457
14-MAY-03 10:30 15-MAY-03
05/16/03 1309
05/21/03 1228
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
6
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DAYIS
FLtJ¥D LABORATORY ANALYSIS REPORT
NELA C Cenijication Number: £87633
Sample ID
Wet Chemistry
SW846 9060
L03051607-06
Master Tracking List
Client TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
Contact.: PEM CARTER
Client ID
TRIP l!LANK
Volatile Organics
SW846 8260B
NC Cenijication Number: 25
Project Number: 61621.01
Report Date
Page 2 of 2
Date Collected
July 24, 2003
Report ID: AB12417
Date Received
05/28/03 1533
15-MAY-03
05/21/03 1129
Davis & Floyd, Jnc. l PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue ! Greenwood, SC 29649 I {864) 229-4413 I Fax [phone]
7
DAYIS
FLtfi7D LABORATORY ANALYSIS REPORT
NELA C Certification Number: £87633
Client
Contact
Tl:CONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
PEM CARTER
Client ID: K-28
Parameter
Wet Chemistry
SW846 9060
Matrix
ORGANIC CARBON, TOTAL
GW/ChemW
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 1 of 1
Sample ID
: July 24, 2003
Report ID: AB12418
L03051607-0l
Date Collected: 13-MAY-03 17: 25
Date Received: 15-MAY-03
Result Qual RDL Units Analyst Date Time
1. 6 1.0 mg/1 CLB 05/28/03 1318
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
8
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DAYIS
FLtwD LABORATORY ANALYSIS REPORT
NELA C Cenijication Number: £87633
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
PEM CARTER
Client ID: V-23
Para.meter
Wet Chemistry
SW846 9060
Matrix
ORGANIC CARBON, TOTAL
GW/ChemW
NC Cenijication Number: 25
Project Number: 61621.01
Report Date ' July 24, 2003
Page 1 of 1 Report ID: AB12419
Sample ID L03051607-02
Date Collected: 13-MAY-03 18 : 25
Date Received 15-MAY-03
Result Qual RDL Units Analyst Date Time
7030 100 mg/1 CLB 05/28/03 1354
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 1 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
9
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Df\YIS
FLM'D LABORATORY ANALYSIS REPORT I
NELA C Cenijication Number: £87633
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
PEM CARTER
Client ID: ITEF
Matrix
Parameter
Gas Chromatography
SW846 8015
ETHYLENE GLYCOI,
Volatile Organics
SW846 8260B
1,1,1-TRICHLOROETIW-l'E
1,1,2,2-TETRACHLOROETHANE
1,1,2-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
1,2-DICHLOROETHMJE
1,2-DICHLOROPROPANE
2-BUTANONE
2-HEXANONE
4-METHYL-2-PENTANONE
ACETONE
BENZENE
BROMODICHLOROMETHANE
BROMOFORM
BR OMO METHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-DICHLOROETHENE
CIS-1,3-DICHLOROPROPENE
DI BROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-DICHLOROETHENE
TRANS-1,3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE {TOTAL)
GW/ChemW
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
Result
5.0
0 . 0010
o. 0010
0 .0010
0 . 0010
0 . 0010
0. 0010
0 . 0010
0 .0050
0 .0050
0. 0050
0.0063
0. 0010
0 .0010
0 . 0010
0 . 0010
0 . 0010
0 .0010
0 .0010
0 .0010
o. 0010
0 . 0010
o. 0010
0 . 0010
0. 0010
0 . 0010
0 . 0010
0 .0010
o. 0010
0. 0010
0. 0010
0. 0010
0 . 0010
0 . 0010
0 .0010
0. 0010
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue
10
NC Cenijication Number: 25 I
Project Number, 61621.01 I
Report Date July 24, 2003
Page 1 of 2 Report ID: AB12420 I
Sample ID L03051607-03
Date Collected, 14-MAY-03 10 : 05
Date Received 15-MAY-03 I
Qual RDL Units Analyst Date Time I
5.0 mg/1 MGB 05/16/03 1101 I
0 . 0010 mg/1 PAP 05/21/03 1150
0 .0010 mg/1 PAP 05/21/03 ·1150 I
0 .0010 mg/1 PAP 05/21/03 1150
0 . 0010 mg/1 PAP 05/21/03 1150
0 . 0010 mg/1 PAP 05/21/03 1150 I o. 0010 mg/1 PAP 05/21/03 1150
0 . 0010 mg/1 PAP 05/21/03 1150
0 . 0050 mg/1 PAP 05/21/03 1150
0.0050 mg/1 PAP 05/21/03 1150 I
o. 0050 mg/1 PAP 05/21/03 1150
0. 0050 mg/1 PAP 05/21/03 1150
o. 0010 mg/1 PAP 05/21/03 1150
0 .0010 mg/1 PAP 05/21/03 1150 I
0 . 0010 mg/1 PAP 05/21/03 1150
0.0010 mg/1 PAP 05/21/03 1150
0 . 0010 mg/1 PAP 05/21/03 1150 I
0 .0010 mg/1 PAP 05/21/03 1150
0 .0010 mg/1 PAP 05/21/03 1150
o. 0010 mg/1 PAP 05/21 /03 1150
0. 0010 mg/1 PAP 05/21/03 1150 I
0 . 0010 mg/1 PAP 05/21/03 1150
0. 0010 mg/1 PAP 05/21/03 1150
o . 0010 mg/1 PAP 05/21/03 1150
0 .0010 mg/1 PAP 05/21/03 1150 I
o . 0010 mg/1 PAP 05/21/03 1150
0 .0010 mg/1 PAP 05/21/03 1150
0 . 0010 mg/1 PAP 05/21/03 1150 I
0. 0010 mg/1 PAP 05/21/03 1150
0. 0010 mg/1 PAP 05/21/03 1150
0 .0010 mg/1 PAP 05/21/03 1150
o. 0010 mg/1 PAP 05/21/03 1150 I
o . 0010 mg/1 PAP 05/21/03 1150
o . 0010 mg/1 PAP 05/21/03 1150
0 . 0010 mg/1 PAP 05/21/03 1150
0. 0010 mg/1 PAP 05/21/03 1150 I
I Greenwood, SC 29649 I [phone] I fax [phone] I
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DAYIS
FLiWD LABORATORY ANALYSIS REPORT
NELA C Certification Number: £87633
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
PEM CARTER
Client ID: ITEF
Parameter
Wet Chemistry
SW846 9060
ORGANIC CARBON, TOTAL
NC Certification Number: 25
Project Number: 61621.0l
Report Date
Page 2 of 2
July 24, 2003
Report ID: AB12420
Sample ID L03051607 03
Result Ou.al 'iWL Units Analyst Date Time
382 10.0 mg/1 CLE 05/28/03 1427
Davis & Floyd, Inc. I PO Drawer 428 ! Greenwood, SC 29648 ! 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
11
DAYIS
FLtwD LABORATORY ANALYSIS REPORT
NELAC Certification Number: £87633
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
PEM CARTER
Client ID: ITBF Dtl'P.
Matrix
Parameter
Gas Chromatography
SW846 8015
ETHYLENE GLYCOL
Volatile Organics
SW846 8260B
1,1,1-TRICHLOROETHANE
1,1,2,2-TETRACHLOROETHANE
1,1,2-TRICHLOROETHANE
1,1-0ICHLOROETHANE
1,1-DICHLOROETHENE
1,2-DICHLOROETHANE
1, 2-DICIILOROPROPANE
2-BUTANONE
2-HEXANONE
4-METHYL-2-PENTANONE
ACETONE
BENZENE
BROMODICHLOROMETHANE
BROMOFORM
BROMOMETHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-DICHLOROETHENE
CIS-1,3-DICHLOROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-DICHLOROETHENE
TRANS-1,3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL)
GW/ChemW
Result
< 5.0
< 0.0010
0.0010
< 0 . 0010
< 0 . 0010
< o. 0010
< 0. 0010
. < o. 0010
< 0.0050
< 0.0050
< 0.0050
0.0068
< 0. 0010
< o. 0010
< 0.0010
< 0 .0010
< 0. 0010
< o. 0010
< 0. 0010
< 0 .0010
< 0 . 0010
< 0.0010
< 0 . 0010
< o. 0010
' 0.0010
< 0 . 0010
< 0 . 0010
< 0 .0010
< 0 . 0010
< 0. 0010
< 0 . 0010
< o. 0010
< 0 . 0010
< 0 . 0010
< o. 0010
< 0. 0010
NC Certification Number: 25
Project Number, 61621.01
Report Date
Page 1 of 2
Sample ID
: July 24, 2003
Report ID: AB12421
L03051607-04
Date Collected: 14-MAY-03 10:05
Date Received: 15-MAY-03
Qual RDL Units Analyst Date Time
5.0 mg/1 MGB 05/16/03 1126
0 .0010 mg/1 PAP 05/21/03 1209
0 .0010 mg/1 PAP 05/21/03 1209
0 .0010 mg/1 PAP 05/21/03 1209
0. 0010 mg/1 PAP 05/21/03 1209
o. 0010 mg/1 PAP 05/21/03 1209
0.0010 mg/1 PAP 05/21/03 12 09
o. 0010 mg/1 PAP 05/21/03 1209
o. 0050 mg/1 PAP 05/21/03 1209
0 . 0050 mg/1 PAP 05/21/03 1209
0.0050 mg/1 PAP 05/21/03 i209
0. 0050 mg/1 PAP 05/21/03 1209
0. 0010 mg/1 PAP 05/21/03 1209
0.0010 mg/1 PAP 05/21/03 12 09
0 . 0010 mg/1 PAP 05/21/03 12 09
0. 0010 mg/1 PAP 05/21/03 1209
0. 0010 mg/1 PAP 05/21/03 1209
0. 0010 mg/1 PAP 05/21/03 1209
0 . 0010 mg/1 PAP 05/21/03 12 09
0 .0010 mg/1 PAP 05/21/03 12 09
0 . 0010 mg/1 PAP 05/21/03 1209
0. 0010 mg/1 PAP 05/21/03 1209
0 . 0010 mg/1 PAP 05/21/03 1209
0. 0010 mg/1 PAP 05/21/03 12 09
0. 0010 mg/1 PAP 05/21/03 12 09
0 .0010 mg/1 PAP 05/21/ 03 12 09
o. 0010 mg/1 PAP 05/21/03 1209
0 .0010 mg/1 PAP 05/21/03 12 09
o. 0010 mg/1 PAP 05/21/03 1209
0 .0010 mg/1 PAP 05/21/03 12 09
0 .0010 mg/1 PAP 05/21/03 12 09
0 .0010 mg/1 PAP 05/21/03 12 09
o. 0010 mg/1 PAP 05/21/03 1209
0 .0010 mg/1 PAP 05/21/03 1209
0 .0010 mg/1 PAP 05/21/03 1209
0. 0010 mg/1 PAP 05/21/03 12 09
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Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue ! Greenwood, SC 29649
12
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DAYIS
FLtwD LABORATORY ANALYSIS REPORT
NELA C Certification Number: £87633
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
PEM CARTER
Client ID: ITEF DUP.
Parameter
Wet Chemistry
SW846 9060
ORGANIC CARBON, TOTAL
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 2 of 2
July 24, 2003
Report ID: AB12421
Sample ID L03051607-04
Result Qual RDL Units Analyst Date Time
170 10.0 mg/1 CLB 05/28/03 1457
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
13
D1\VIS
FLtWD LABORATORY ANALYSIS REPORT
NELA C Certification Number: £87633
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 2B152
PEM CARTER
Client ID: ITCI
Matrix
Paramo tor
Gas Chromatography
SW846 8015
ETHYLENE GLYCOL
Volatile Organics
SW846 8260B
1,1,1-TRICHLOROETHANE
1,1,2,2-TETRACHLOROETHANE
1,1,2-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
1,2-DICHLOROETHANE
1,2-DICHLOROPROPANE
2-8\JTANONE
2-HEXANONE
4-METHYL-2-PENTANONE
ACETONE
BENZENE
BROMODICHLOROMETHANE
BROMOFORM
BROMOMETHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-DICHLOROETHENE
CIS-1,3-DICHLOROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-DICHLOROETHENE
TRANS-1,3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL)
GW/ChemW
'
'
'
'
'
'
'
'
'
'
'
'
'
'
'
'
'
'
'
'
'
'
'
'
'
'
'
'
'
'
Result
2310
0 .0010
0. 0010
0. 0010
0 .0010
0.0010
0. 0010
0 .0010
2.0
0 . 0050
0 . 0050
0.52
0.012
0 .0010
0 . 0010
0 .0010
0.0015
0.0010
0 .014
0 .0010
0. 0010
0. 0010
o. 0010
0. 0010
0.0010
0. 0010
0. 0010
0 .0010
0 .0010
0 .0010
o. 0010
0 . 0010
0. 0010
0 .0010
0.0010
0.0010
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 1 of 2
Sample ID
July 24, 2003
Report ID: AB12422
L03051607-05
Date Collected: 14-MAY-03 10:30
Date Received: 15-MAY-03
Qual RDL Units Analyst Date Time
100 rng/1 MGB 05/16/03 1309
0 . 0010 mg/1 PAP 05/21/03 1228
0 .0010 mg/1 PAP 05/21/03 1228
0 . 0010 mg/1 PAP 05/21/03 1228
0. 0010 mg/1 PAP 05/21/03 1228
0.0010 mg/1 PAP 05/21/03 1228
0 .0010 mg/1 PAP 05/21/03 1228
0 .0010 mg/1 PAP 05/21/03 1228
• 0.025 mg/1 PAP 05/21/03 1308
0.0050 mg/1 PAP 05/21/03 1228
0 .0050 mg/1 PAP 05/21/03 1228
0. 0050 mg/1 PAP 05/21/03 1228
0 .0010 mg/1 PAP 05/21/03 1228
0 . 0010 mg/1 PAP 05/21/03 1228
o. 0010 mg/1 PAP 05/21/03 1228
o. 0010 mg/1 PAP 05/21/03 1228
o. 0010 mg/1 PAP 05/21/03 1228
0 .0010 mg/1 PAP 05/21/03 1228
0 .0010 mg/1 PAP 05/21/03 1228
0. 0010 mg/1 PAP 05/21/03 1228
0 .0010 mg/1 PAP 05/21/03 1228
0.0010 mg/1 PAP 05/21/03 1228
0. 0010 mg/1 PAP 05/21/03 1228
0 .0010 mg/1 PAP 05/21/03 1228
o. 0010 mg/1 PAP 05/21/03 1228
o. 0010 mg/1 PAP 05/21/03 1228
o. 0010 mg/1 PAP 05/21/03 1228
0. 0010 mg/1 PAP 05/21/03 1228
o. 0010 mg/1 PAP 05/21/03 1228
0 .0010 mg/1 PAP 05/21/03 1228
0. 0010 mg/1 PAP 05/21/03 1228
o. 0010 mg/1 PAP 05/21/03 1228
0. 0010 mg/1 PAP 05/21/03 1228
0 .0010 mg/1 PAP 05/21/03 1228
0. 0010 mg/1 PAP 05/21/03 1228
o. 0010 mg/1 PAP 05/21/03 1228
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
1 4
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Di\YIS
FLtwD LABORATORY ANALYSIS REPORT
NELAC Cenijication Number: £87633
Para.meter
Wet Chemistry
SW846 9060
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 1518
SHELBY, NC 28152
PEM CARTER
Client ID: ITCI
Result
NC Certification Number: 25
Project Number: 61621.01
Report Date July 24, 2003
Page 2 of 2 Report ID: AB12422
Sample ID L03051607-05
Qual RDL Units Analyst Date Time
ORGANIC CARBON, TOTAL 2360 50.0 mg/1 CLB 05/28/03 1533
Sample Comments: 8260 VOA -The result for Acetone & 2-Butanone may be biased high due to interference
from non-target contaminants.
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I fax [phone]
1 5
I
Di\YIS
FLMD LABORATORY ANALYSIS REPORT I
NELAC Certification Number: £87633
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY 198
SHELBY, NC 28152
PEM CARTER
Client ID: TRIP BLANK
Matrix
Para.meter
Volatile Organics
SW846 8260B
1,1,1-TRICHLOROETHANE
1,1,2,2-TETRACHLOROETHANE
1,1,2-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
1,2-DICHLOROETHANE
1,2-DICHLOROPROPANE
2-BUTANONE
2-HEXANONE
4-METHYL-2-PENTANONE
ACETONE
BENZENE
BROMODICHLOROMETHANE
BROMOFORM
BROMOMETHANE
CARBON.DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-DICHLOROETHENE
CIS-1,3-DICHLOROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-DICHLOROETHENE
TRANS-1,3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL)
GW/Chemw
Result
' 0 .0010
' 0 .0010
' 0 .0010
' 0. 0010
' 0 . 0010
' 0 .0010
' 0 .0010
' 0 .0050
' 0 . 0050
' 0 . 0050
' 0 .0050
' 0 .0010
' 0. 0010
' 0 . 0010
' 0 .0010
' 0 .0010
' 0 . 0010
' 0. 0010
' 0.0010
' 0 .0010
' 0. 0010
' o. 0010
' 0 .0010
' 0 . 0010
' 0. 0010
' 0. 0010
' 0 . 0010
' 0 .0010
' 0 .0010
' o. 0010
' o. 0010
' o. 0010
' o. 0010
' 0 .0010
' 0 .0010
Davis & Floyd, lnc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue
16
NC Certification Number: 25
Project Number: 61621.01
Report Date
Page 1 of 1
July 24, 2003
Report ID; AB12423
Sample ID L03051607-06
Date Collected, 07-MAY-03 10:30
Date Received 15-MAY-03
Qual RDL Units Analyst Date
0.0010 mg/1 PAP 05/21/03
0 .0010 mg/1 PAP 05/21/03
0 .0010 mg/1 PAP 05/21/03
0. 0010 mg/1 PAP 05/21/03
0. 0010 mg/1 PAP 05/21/03
0 .0010 mg/1 PAP 05/21/03-
0 .0010 mg/1 PAP 05/21/03
0. 0050 mg/1 PAP 05/21/03
0.0050 mg/1 PAP 05/21/03
0 . 0050 mg/1 PAP 05/21/03
0 .0050 mg/1 PAP 05/21/03
0. 0010 mg/1 PAP 05/21/03
0 .0010 mg/1 PAP 05/21/03
0. 0010 mg/1 PAP 05/21/03
o. 0010 mg/1 PAP 05/21/03
0 .0010 mg/1 PAP 05/21/03
0. 0010 mg/1 PAP 05/21/03
0.0010 mg/1 PAP 05/21/03
0 .0010 mg/1 PAP 05/21/03
0 .0010 mg/1 PAP 05/21/03
0 .0010 mg/1 PAP 05/21/03
0. 0010 mg/1 PAP 05/21/03
0. 0010 mg/1 PAP 05/21/03
0. 0010 mg/1 PAP 05/21/03
0 . 0010 mg/1 PAP 05/21/03
0 .0010 mg/1 PAP 05/21/03
0. 0010 mg/1 PAP 05/21/03
0.0010 mg/1 PAP 05/21/03
0 .0010 mg/1 PAP 05/21/03
0 .0010 mg/1 PAP 05/21/03
0. 0010 mg/1 PAP 05/21/03
0 .0010 mg/1 PAP 05/21/03
0 .0010 mg/1 PAP 05/21/03
0 . 0010 mg/1 PAP 05/21/03
o. 0010 mg/1 PAP 05/21/03
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1129
1129 I
1129
1129
1129
1129 I
1129
112 9
1129 I
1129
1129
1129
1129 I
1129
1129
1129
1129 I
1129
1129
1129 I 1129
1129
1129
1129 I
112 9
112 9
1129
1129 I
1129
1129
1129 I 1129
1129
1129
1129 I
I
I Greenwood, SC 29649 I 1864) 229-4413 I Fax [phone]
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Df\YIS
FLtrYD LABORATORY ANALYSIS REPORT
Method Conformance Summary
Client: Ticona, LLC
Login(s): L03051607
Criteria Volatiles
Samole Holdine Time
Standards Prenaration
Instrument Tunine
Instrument Calibration
Calibration Verification
Deeradation Check
Interference
Samo le/Standard
Blanks Results
Method Accuracy
Method Precision
Surroeate Recove~
PDS/SD/MSA
TCLP Preoaration
✓
NIA
= Met Criteria Met
= Not Applicable
✓
✓
✓
✓
✓
NIA
NIA
✓
✓
•
✓
NIA
NIA
Semi
Volatiles
NIA
NIA
NIA
NIA
NIA
NIA
NIA
NIA
NIA
NIA
NIA
NIA
NIA
Metals
NIA
NIA
NIA
NIA
NIA
NIA
NIA
NIA
NIA
NIA
NIA
NIA
NIA
•
PDS =
SD =
MSA=
Method Criteria Not Met -See footnote(s) below .
Post Digestion Spike
Serial Dilution
Method of Standard Additions
Project Number: 61621.01
Report Date; June 2, 2003
Ethylene
TOC Glvcol
✓ ✓
✓ ✓
NIA NIA
✓ ✓
✓ ✓
NIA NIA
NIA NIA
✓ ✓
✓ ✓
✓ ✓
NIA NIA
NIA NIA
NIA NIA
Footnotes: Volatiles (Method Precision)-The RPD for benzene, carbon tetrachloride,
chlorobenzene and chloroform was 14, 14, 14 and 15 % respectively. The
laboratory-established criteria for these analytes are 13, 13, 13 and 14%
respectively.
I Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
1 7
DAYIS
FLtrYD LABORATORY ANALYSIS REPORT
QC Batch Report
WorkGroup • : WGH.048
Description: V0/8260/TCL
Sample ID
L03051607-03
L03051607-04
L03051607-05
L03051607-05
L03051607-06
LCSJ-4048: 1
MB3404B,l
MS03051607-03:34048
MSD03051607-03:34048
Client ID
ITEF
ITEF DUP.
ITC!
ITCI
TRIP BLANK
.. Laboratory Control Spike
Method Blank
Matrix Spike
Matrix Spike Duplicate
Report Date
Page 1 of 1
Matrix
Prep Method
Analtyical
PREP
Rud Date Time
1
1
2
1
1
1
1
' June 02, 2003
Report ID: AB8923
GW/ChemW
Method: SW846 82608
ANALYTICAL
Date Time Analyst Dilution
05/21/03 1150 PAP 1
05/21/03 1209 PAP
05/21/03 1228 PAP
05/21/03 1308 PAP
05/21/03 1129 PAP
05/21/03 1805 PAP
05/21/03 1108 PAP
05/21/03 1449 PAP
05/21/03 1509 PAP
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Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone] I
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Dl\VIS
FLtJ\'D LABORATORY ANALYSIS REPORT
Surrogates % Recovery
L03051607-03 21-MAY-03 11:50
L03051607-04 21-MAY-03 12:09
L03051607-05 21-MAY-03 13:08
L03051607-05 21-MAY-03 12: 28
L03051607-06 21-MAY-03 11:29
LCS34048: 1 21-MAY-03 18:05
MB34048:l 21-MAY-03 11 :08
MS03051607-03:34048 21-MAY-03 14:49
MSD03051607-03:34048 21-MAY-03 15:09
DCE 1,2-DICHLOROETHANE D4
BFB BROMOFLUOROBENZENE
TOL TOLUENE-DB
94 99
99 99
96 99
99 99
87 96
HO 99
93 99
109 99
113 100
Report Date
Page 1 of
Matrix
June 02, 2003
Report ID: AB8932
GW/ChemW
WorkGroup: WG34048
Method SW846 8260
101
100
100
99
103
99
102
98
98
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 616 E. Durst Avenue I Greenwood, SC 29649 l [phone] l Fax [phone]
19
DAYIS
FLOYD
Method Blanks
Blank : .MBH048:l
Parameter
Volatile Organics
SW846 8260B
1,1,1-TRICHLOROETHANE
1,1,2,2-TETRACHLOROETHANE
1,1,2-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
1,2-DICHLOROETHANE
1,2-DICHLOROPROPANE
2-BUTANONE
2-HEXANONE
4-METHYL-2-PEN'I'ANONE
ACETONE
BENZENE
BROMODICHLOROMETHANE
BROMOFORM
BROMOMETHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-DICl-tLOROETHENE
CIS-1,3-DICHLOROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-DICHLOROETHENE
TRANS-1,3-DICHLOROPROPENE
TR I CHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL)
LABORATORY ANALYSIS REPORT
Cone
< 1.0
< 1.0
< 1.0
< 1.0
< 1.0
< 1.0
< 1.0
< 5.0
< 5.0
< 5.0
< 5.0
< 1.0
< 1.0
< 1.0
< 1.0
< 1.0
< 1.0
< 1.0
< 1.0
< 1.0
< 1.0
< 1.0
< 1.0
< 1.0
' 1.0
' 1.0
' l. 0
' 1.0
< 1.0
., 1.0
< 1.0
1.0
' l. 0
< 1.0
' 1.0
Report Date
Page 1 of 1
Matrix
: June 02, 2003
Report ID: ABB914
GW/ChemW
WorkGroup: WG34048
Qual RDL Units Analyst Date
1.0 ug/1 PAP 05/21/03
1. 0 ug/1 PAP 05/21/03
1. 0 ug/1 PAP 05/21/03
1.0 ug/1 PAP 05/21/03
1.0 ug/1 PAP 05/21/03
1. 0 ug/1 PAP 05/21/03
1.0 ug/1 PAP 05/21/03
5.0 ug/1 PAP 05/21/03
5.0 ug/1 PAP 05/21/03
5.0 ug/1 PAP 05/21/03
5.0 ug/1 PAP 05/21/03
1.0 ug/1 PAP 05/21/03
1.0 ug/1 PAP 05/21/03
1.0 ug/1 PAP 05/21/03
1.0 ug/1 PAP 05/21/03
1.0 ug/1 PAP 05/21/03
1.0 ug/1 PAP 05/21/03
1.0 ug/1 PAP 05/21/03
1.0 ug/1 PAP 05/21/03
1.0 ug/1 PAP 05/21/03
1.0 ug/1 PAP 05/21/03
1.0 ug/1 PAP 05/21/03
1.0 ug/1 PAP 05/21/03
1. 0 ug/1 PAP 05/21/03
1.0 ug/1 PAP 05/21/03
1.0 ug/1 PAP 05/21/03
1.0 ug/1 PAP 05/21/03
1 .o ug/1 PAP 05/21/03
1.0 ug/1 PAP 05/21/03
1.0 ug/1 PAP 05/21/03
1.0 ug/1 PAP 05/21/03
1.0 ug/1 PAP 05/21/03
1.0 ug/1 PAP 05/21/03
.o ug/1 PAP 05/21/03
1.0 ug/1 PAP 05/21/03
Time
1108
1108
1108
1108
1108
1108
1108
1108
1108
1108
1108
1108
1108
1108
1108
1108
1108
1108
1108
1108
1108
1108
1108
1108
1108
1108
1108
1108
1108
1108
1108
1108
1108
1108
1108
Davis & Floyd, Inc. I PO Drawer 428 l Greenwood, SC 29648 I 616 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
20
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DAYIS
FLO\'D LABORATORY ANALYSIS REPORT
Matrix Spikes and Duplicates
MS/MSD
1,1-OICHLOROETHENE
1,2-DICHLOROETHANE
2-BUTANONE
BENZENE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROFORM
TETRACHLOROETHENE
TRICHLOROETHENE
VINYL CHLORIDE
1,1-DICHLOROETHENE
1,2-DICHLOROETHANE
2-BUTANONE
BENZENE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROFORM
TETRACHLOROETHENE
TRICHLOROETHENE
VINYL CHLORIDE
NOTE1 MS/MSD t recoveries
: . MS03051607-03: 34048
MSD03051607-03:34048
so.oo
50. 00
50.00
50 00
50. 00
so. 00
50 00
50. 00
50. 00
so.co
so.co
50.00
so.co
50.00
so.co
so.oo
so. 00
50.00
so.oo
so.oo
are not evaluated if the
< 1.00
< 1.00
< 5.00
< 1.00
< 1.00
< 1. 00
< 1.00
< 1.00
< 00
< 1. 00
52. 58
55.41
57.57
49. 77
47 .39
51.43
52. 77
47. 06
49.62
39. 29
Report Date
Page 1 of l
June 02, 2003
Report ID: AB8920
Matrix GW/ChemW
WorkGroup: WG34048
Method SW846 82608
47.89 96 71-121
47.16 94 78-141
52. 46 105 38-176
-43.18 86 79-116
41. 36 83 75-128
44.80 90 81-115
45. 42 91 80-127
41. 67 83 73-115
43 . 51 87 74-117
37 08 74 61-123
105 9 13 71-121
111 16 16 78-141
115 9 44 38-176
100 1' 13 79-116
95 1' 13 75-128
103 1' 13 81-115
106 15 14 80-127
94 12 14 73-115
99 13 13 74-117
79 6 15 61-123
sample concentration is greater than four times the spike added.
I Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Dwst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
21
DAYIS
FLtJ\'D LABORATORY ANALYSIS REPORT
Laboratory Control Standards and Duplicates
LCS : ,.LCS34048:l
1,1-DICHLOROETHENE 20. 00 19.46
1,2-DICHLOROETHANE 20.00 20. 90
2-BUTANONE 20.00 25 29
BENZENE 20.00 18 .87
CARBON TETRACHLORIDE 20. OD 16 74
CHLOROBENZENE 20. 00 19. 21
CHLOROFORM 20. 00 20.38
TETRACHLOROETHENE 20.00 17.61
TRICHLOROETHENE 20.00 18 .73
VINYL CHLORIDE 20. 00 15.65
97
105
126
94
84
96
102
88
94
78
Report Date
Page 1 of
: June 02, 2003
Report ID: AB8916
Matrix GW/ChemW
WorkGroup: WG34048
Method SWB46 8260B
76-121
86-141
32-185
84-119
79-127
86-118
83-129
75-118
76-116
61-130
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Dav;5 & Floyd, Inc. I PO Drawer428 I Greenwood, SC 29648 I 816 E. 2."t Avenue I Greenwood, SC 29649 I (8641229-4413 I Fax [phone] I
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Di\YIS
FLtfYD LABORATORY ANALYSIS REPORT
QC Batch Report
WorkGroup • : WGH013
Description: GC/EG
Sample ID
L03051607-03
L03051607-04
L03051607-05
LCS34013:1
MB34013: 1
MS03050808-0l:34013
MSD03050808-01:34013
Client IO
ITEF
ITEF DUP.
ITC!
Laboratory Control Spike
Method Blank
Matrix Spike
Matrix Spike Duplicate
Report Date
Page 1 of 1
Matrix
Prep Method
Analtyical
PREP
Run# Date Time
1
1
1
' June 02, 2003
Report ID: AB8922
GW/ChemW
Method: SW846 8015
ANALYTICAL
Date Time Analyst Dilution
05/16/03 1101 MGB 1
05/16/03 1126 MGB 1
05/16/03 1309 MGB 20
05/16/03 0943 MGB 1
05/16/03 0918 MGB 1
05/16/03 1152 MGB
05/16/03 1218 MGB
Davis & Floyd, Inc. 1 PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 1 [phone] I Fax [phone]
23·
DAYIS
FLtrYD
Method Blanks
Blank
Parameter
Gae Chromatography
SW846 8015
ETHYLENE GLYCOL
J'ffiHOlJ: l
LABORATORY ANALYSIS REPORT
Cone
5.0
Report Date
Page 1 of 1
Matrix
June 02, 2003
Report ID: AB8911
GW/ChemW
WorkGroup: WG34013
Qual RDL Units .Analyst Date Time
5.0 mg/1 MGB 05/16/03 0918
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I (864) 229•441 3 l Fax [phone]
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Di\VIS
FLtfYD LABORATORY ANALYSIS REPORT
Matrix Spikes and Duplicates
MS/MSD
ETHYLENE GLYCOL
ETHYLENE GLYCOL
MS030SOBOB-Ol:3i013
MSD03050808-01134013
so.co
50.00
< 5.00
51. 22
Report Date
Page l of
Matrix
workGroup,
Method
50. 91 102
102 l
June 02, 2003
Report ID: ABB918
GW/ChemW
WG34013
SW846 8015
66-127
15 66-127
I NOTE, MS/MSD \ recoveries are not evaluated if the sample concentration is greater than four times the spike added.
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DAYIS
FLOYD LABORATORY ANALYSIS REPORT
Laboratory Control Standards and Duplicates
Report Date -June 02, 2003
Page 1 of 1 Report ID: AB8912
Matrix GW/ChemW
LCS : LCS34013: 1 WorkGroup: WG34013
Method SW846 8015
ETHYLENE GLYCOL 50. 00 53.49 107 75-122
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Davis & Floyd, Inc.. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Dfs Avenue I Greenwood, SC 29649 I [phone] I Fax [phone] I
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Df\VIS
FLtJ\'D LABORATORY ANALYSIS REPORT
QC Batch Report
WorkGroup. WG34Hl
Description: TOC GW
Sample ID
L03051607-01
L03051607-02
L03051607-03
L03051607-04
L03051607-0S
LCS34141:1
MB34141: 1
MS03052101-0l:34141
MSD03052101-0l:34141
Client ID
K-28
V-23
ITEF
ITEF DUP.
ITCI
Laboratory Control Spike
Method Blank
Matrix Spike
Matrix Spike Duplicate
Report Date
Page 1 of 1
Matrix
Prep Method
Analtyical
PREP
Run# Date Time
1
1
1
1
1
: June 02, 2003
Report ID: AB8924
GW/ChemW
Method: SW846 9060
ANALYTICAL
Date Time Analyst Dilution
05/28/03 1318 CLB 1
05/28/03 1354 CLB 100
05/28/03 1427 CLB 10
05/28/03 1457 CLB 10
05/28/03 1533 CLB 50
05/28/03 2000 CLB
05/28/03 2104 CLB 1
05/28/03 1849 CLB
05/28/03 1906 CLB
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 1 [phone] I Fax [phone]
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DAYIS
FLOYD
Method Blanks
Parameter
Wet Chemistry
SW846 9060
Blank
ORGANIC CARBON, TOTAL
:.MBHHl:1
LABORATORY ANALYSIS REPORT
Report Date June 02, 2003
Page 1 of 1 Report ID: ABB919
Matrix GW/ChemW
WorkGroup: WG34141
Cone Qual RDL Units Analyst Date Time
1. 0 1.0 mg/1 CLB 05/28/03 2104
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Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. 2us" Avenue I Greenwood, SC 29649 I [phone] I Fax [phone] I
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D1\¥1S
FLt1YD LABORATORY ANALYSIS REPORT
Matrix Spikes and Duplicates
MS/MSD
ORGANIC CARBON, TOTAL
ORGANIC CARBON, TOTAL
_MS03052101-0l:3414l
MSD03052101-0l:34141
30.00
30. 00
15.68
45.57
Report Date
Page 1 of 1
Matrix
WorkGroup:
Method
44.30 95
100 3
June 02, 2003
Report ID: AB8921
GW/ChemW
WG34141
SWB-46 9060
76-128
10 76-128
I NOTE, MS/MSD • recoveries are not evaluated if the sample concentration is greater than four times the spike added.
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I Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax {864) 229-71 19
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Df\YIS
FLtiYD LABORATORY ANALYSIS REPORT
La,boratory Control Standards and Duplicates
Report Date June 02, 2003
Page 1 of 1 Report ID: AB8917
Matrix GW/ChemW
LCS LCS3HH:1 WorkGroup: WG34141
Method SW846 9060
ORGANIC CARBON, TOTAL 25. 00 25.30 101 90-110
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Davis & Floyd, Inc. I PO Drawer 426 I Greenwood, SC 29646 I 616 E. 030, Avenue I Greenwood, SC 2%49 I [phone] I Fax [phone] I
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~~~ LABORATORY ANALYSIS REPORT
Explanation of Symbols and Abbreviations
The following defines common symbols and abbreviations used in reporting technical data:
RDL Report Detection Limit MDL Method Detection Limit
TOP Top of Pipe MSL Mean Sea Level
TNTC Too Numerous To Count MPN Most Probable Number
BTU British Thermal Units NTU Nephelometric Turbidity Units
C Degrees Centigrade F Degrees Fahrenheit
umhos/cm micromhos/cm meq milliequivalents
kg kilogram(s) g gram(s)
mg milligram(s) ug microgram(s)
I liter(s) ml milliliters(s)
ul microliter(s) m3 cubic meter(s)
lb pound(s) ft3 cubic foot(feet)
ft foot(feet) TIC Tentatively Identified Compounds
mg/I, mg/kg Units of concentration in milligrams per liter for liquids and milligrams per kilogram for solids. Also
referred to as Parts Per Million or "ppm" when the assumption is made that the specific gravity or
density is one (1 g/ml).
ug/I, ug/kg Units of concentration in micrograms per liter for liquids and micrograms per kilograms for solids.
Also referred to as Parts Per Billion or "ppb" when the assumption is made that the specific gravity
or density is one (1 g/ml).
wt¾ Units of concentration expressed on a weighVweight basis (e.g. grams per 100 grams).
< Less Than -The number following the sign is the limit of quantitation, the smallest amount of
analyte that can be reliably determined using this test.
> Greater Than
Data Qualifiers:
A
B
C
E
J
p
X
•
TIC is a possible aldol-condensation product resulting from sample extraction, (Organics)
Analyte also detected in the method blank.
Amendable Cyanide is a negative value due to an unknown interference.
Estimated concentration due to interference.
Estimated value below RDL or estimated value for TIC. (Organics)
Concentration difference between primary and confirmation columns >25%. (Organics) The lower result is
reported.
Matrix interference which requires dilution or prevents the reporting of a result. Detection limits have been
adjusted where applicable.
Defined in report comments .
Solid samples (i.e. soil, sludge, and solid waste) are reported on a dry weight basis unless otherwise noted.
Test results relate only to the sample tested. Clients should be aware that a critical step in a chemical or biological
analysis is the collection of the sample. Unless the sample analyzed is truly representative of the bulk of the material
involved, the test results will be meaningless. If you have any questions regarding the proper techniques of collecting
samples, please contact us. However, we cannot be held responsible for sample integrity unless sampling has been
performed by a member of our staff.
WARRANTY AND LIMITATION OF LIABILITY The accuracy of all analytical results is warranted for the sample as
it is received by the laboratory. Warranty for the integrity of the sample begins at the time it is placed in the
possession of authorized Davis & Floyd, Inc. Laboratories personnel. All other warranties, expressed or implied, are
disclaimed. Liability is limited to the cost of the analysis.
Davis & Floyd, Inc.
AD07_01 (07/99)
Davis&· F/oyU, Inc. I PO Drawer 428 I Greemvood, SC 29648 I 816 E. Durst Avenue I Creenwood, SC 2%49 I [phone] I Fax {864) 229-7119
31
- - ----

-

-
------

-
--

-
-Chain of Custody Record Page J_ of _1_
Client Project I Sile Loca/lbn 816 E. Durst Avenue, Greenwood, SC 29649 {864) 229-4413 Fax: [phone] C8 ,.,se unrv
CNA Ticona 61621.01 Laboratory Cerlitcation Numbers: SC -24110, NC-25, TN-2923, VA-n
Shelby,NC Groundwater well samples
"r'!" --t:.,,v1µ/rn.,) bM-~1 14'<,j,J -le.hi-Cop~ ~ C'M.1Z~-7i-,J Reporting Requirements: fld,Standard { J Data Package (Specify Level)
L _, 7"C
run:haseOrder
Collected By Required Parameters, Containers and Preservatives State Quote
(5,£,~?r t ,J,l{,1-,0 NC
.:r~""ff 0€{,,.)11-r-LOQln Special fnstructfons
NOTICE: ~ e t--• ! • J ~ \; 'ii < .s ;, ,; t ~ < '3 ~ ~ ~ 0 ,. ~
0. .. '-' t~ • I .. 1; ~ E-.; • • ~ ! 8. : 8. 0 X •• ~ D D ] ~ • :s E
Sample Collection LS.§_ 8 '~ -ll 0 ...J z
Samo1e Descriotion Date Time Time Type Total ~ ,<\-~ Fraction HOT ommen~s
-r2, p ?Jt.A,Jt'-5/7/J3 /,:i'Jd >< ~ ;J__ X Ofa <";-..,..----rzr;,,,
IC -:2 ,r;,,, S/111.--.. n1,< X -.5 I X Of .n)\ -•-,J;-
V-;2 3 s-1, :?>/,:1 ti-)--< "/( s-I X 0-v 2L,Jr:oP
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y )( y 0~
~ _ _,,.. I) 0 I t:"'r-1 VI Sl,t/1 ·" Joos' )( -5 < )( )< V {)IJ-
:e--,-,c, -s'lt<l,o' /o3o X < s )( X )<.. 05
/7
//
/) //
\~ r/A'/-It,"f Time Refiquished By Date Time l"eUquished By Date nme Qw0) Shipped By
171.J "" ~ :;&,// -~ ~4) y N -RoceT//zJ)-q. uate Time ixeceived By Date nm, ~ed in Laboratory By Date Time II Y, specify. Airblll Number
S/,v/J 171.f"' .. ,.. Ut1 (l_ -l,.... f-S: IS"•~ 11-.c-) ---days
•-•••~nts
!Cooler l~le): ----
On Ice: Ye Temp(C) JL -
Custody Seal: Intact / Broken / ~
Matrix Type Definitions 1 •Dnnk1ng Water 2 -Clean Water 5 -Groundwater 7 • Sod/Sediment B -Liquid Sludge 9 • 011 12 -Air Davis & Floyd, Inc.
Preservative OefiniUons A -None B • H2S04 C -HCI D • HN03 E-NaOH F • FIitered G • Other FL02 _01 (02199)
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J<ubal-Furr & As~odates
-[m,ir1mmrr11:1/ C 1J!li<1/lr1111s -Protec: No 26QS08
'"O• Msl"cd\ &rUt l so~pl,9M .. hooi &,2f✓~·,
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Sorr,cl,H Colle::!ed
pw •/· 0.1 s1or:ooro unir
Tvrblddy •/· lo,; obC1te IC NTtJ
Field Parameters
·--juS./cmJ
~ -
S117.. '-'.tl<l
\<;1nc t.J.ll/
1.,-t:"x'5" l'.J</"1_
' 5{,-=J-S LJ>./t
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(N~'J: /m9,'L)
0JyQe1"1 O~P j"\"\V)
----1..'! /J.i./5 cft.'I I ., ~ /) -::21 iw..;-
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O~? t-f.lOmV
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Kubal-fun&: As.sodo1tl;!s
-£11r,,i,a11mC'11Mf Co11.~uftt1111!,-
0 /) 'I. 9'/
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2 in I J,5'i]
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Low-Flow Groundwater Sa mphng Log
1rirerva1
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Pro,ect No 26QS08
Site Locotion CNA/Ticona · Shelby, NC
Field Per!Of',nel -'~=C!!!~~-'-'='--"'S!!"'---
Scec:nc Terr.perar"''° Conauctor,ce
l"CI /1iS/cmJ
~ -;q.95 7f?t/
;q.x z.q,
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fr.,g/l) -o.,G
, o.lJO
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Rc."!'\.::ti.:J __________________________
--------
oH •I· 0, ! sionaord vnit COND/Te""'p •j-J~
'I· I f'llU ·ue'.ow 10 NTU
34
C NA/Toe:on1 t.;...,.flo.,,.G~uf'\Ow;,to• Slmpiin9 lDg
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Calibration Log _ /
___ v_s_r s_s_6_MP--'S___ Date S / I J ;{3 Meter Model
Meter Serial # 01G0526
Battery
Conductivity Meter Calibration
Standard µSiem
Standard Read'1ng µSiem
Temperature ('C)
pH Meter Calibration
7 _o Buffer
4_0 Buffer
10.0 Buffer
Dissolved Oxygen Calibration
ORP Calibration
DO%
Standard mV
Standard Reading mV
Temperature ('CJ
Turbidity Calibration
Meter Model
Meter Serial #
Battery
ESD Model 800
TUR800 358
2ero Standard (0 NTU)
Ten Standard ( 10 NTU)
Signature
Time /G;2rJ ---'--'------
'i.o/
-------Kubal-Furr & Associates~-------
Revised 2122102
35
Sampling Log-Grab Water Samples
Project No. 26QS08
Sample Date _S.-L{_J--1'/..LZ:....::...3 __ •
Sample ID -::S:: 7 EY
Weather Cond;r,ons C 4,,, A {
Sample Temp. ('C) 23,--!9
ORP (mV) 13I, t
Method(s) ::roc:: voe-r
Remarks
Sample Date _S,_fL1.J<~.L1/;c.;;J;:__ __
Sample ID ,;;-r-c I
Weather Conditions Ci,~
Sample Temp. ('C) d1J. 76
ORP (mV)
Method(s)
-r;,:_
Remarks
£3,3
Site Location CNA / Ticona -Shelby, NC
Arrival Time O'jif'f Sample Time __ ;;:...,,:2.....,CJ=U:::.,__
Field Personnel __ ..,,G"'Kc..cl...;J"'D'--_
Sampling Method o/Y8
Spec. Conductivity(µS/cm) 33/~ pH __ t"__:,_]-'9 __ _
Turbidity (JI/TU) _';?_9_, L./ _ ___,DO(mo/L) _.;.../_ • .,,Z---'-(J __
Com:ainer Oescription Preservatrve /'l:la[/f / $( --
Arrival T,me .....::o::...,9'-46-''P"----Sampl~ Time _ _./4--'V-~_a_• __
Duplicate JI/a. ______ _ Field Personnel __ ....:Ge;.K;:.;/c..J::.:D:......._
Sampling Method fl-&
Spec. Conductivity(µS/cm) rf/o.r/ pH £"71-!P'/tb
Turbidity (JI/TU) __ /-'-'f,C.L.9 _ __,DO(mgll) _k..;._/:J_9,___
Container Description Preservative IJd£.LJ<; fry -
Kubal-Furr & Associates
Revised 7130102
36
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Calibration Log
Date 5")1/oJ Merer Model YSI 556MPS
Meter Serial 'It 01G0526
Battery
Conductivity Meter Calibration
Standard µSiem
Standard Reading µSiem
Temperature ('C)
pH Meter Calibration
7 .0 Buffer
4.0 Buffer
1 0.0 Buffer
Dissolved Oxygen Calibration
ORP Calibration
DO%
Standard mV
Standard Reading mV
Temperature (·C)
Turbidity Calibration
Meter Model
Meter Serial 'It
Battery
ESD Model 800
TUR800 358
Zero Standard (0 NTU)
Ten .';tandard ( 10 NTU)
Sign~ture
------+, --''-'-----
Time 0913'
✓---
i/. C)c)
Time ---------
{)pl--
37
Revised 2/22/02
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I Attachment 3
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Selected Water-Quality Plots
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Kubal-Furr & Associates
-------------------
ITCI TOC Data
4000 ~----------------------------------------,
3 500 --------------------- ------------------------------------------_
3000 -------------------
2500 ~ C)
E ~
C .g 2000
~ g
0
u 1500
1 000 -- -----------------
500 ----------------------------------------------------------------------------------------------------
0-+-------+-------+-------+-------+-------+--~
1/1/93 1/1/95 12/31/96 12/31/98 12/30/00 12/30/02
Date
-------------------
~ Cl E ~
C:
ITCI Ethylene Glycol Data
4000 ,------------------------------------------7
3500
3000
2500
(Unfilled data points represent qualified data
or values below the detection level.)
-------------------------------------------------------------------------------------------------------
.g 2000
~ C: ~ C: 0 u 1500
1000
500
o-l-----~----+------1-----+-----,--+------11------+-----+-----+'
10/5/94 10/5/95 10/4/96 10/4/97 10/4/98 10/4/99 10/3/00 10/3/01 10/3/02 10/3/03
Date
-------------------
V-23 TOC Data
14000 -,--------------------------------------------,
12000
10000
~ ~ 8000
~
§
~ C: i 6000
u
4000
2000
(Unfilled data points represent qualified data
or values below the detection level.)
0-1-----+-----+------+---"'----+-------+------+------;-----t-'
1/1/85 5/1/87 8/28/89 12/26/91 4/24/94
Date
8/21/96 12/19/98 4/17/01 8/15/03
-------------------
V-23 2-Butanone (MEK) Data
4~---------------------------------------------,
3.5
3
~ 2.5 ...J ' Cl E ~
C 0 ~ 2
C ~ C 8 1.5
0.5
(Unfilled data points represent qualified data
or values below the detection level.)
0 -l---"'---IJl---!-"'--='-----==--ie=0-----0-+-------u------+------....-------,...
6/l /89 6/1/91 5/31/93 5/31 /95 5/30/97 5/30/99 5/29/01 5/29/03
Date
-------------------
C 0 I
V-23 Acetone Data
1.4~---------------------------------------------,
1.2
(Unfilled data points represent qualified data
or values below the detection level.)
ti-_ ., g 0.6 --------------------------------------
8
0.4 - - - - - - - - - - - - - - - -
0.2
0+----...U..-+------+-cu...------+------+---'-'------1:J-+------+------+--'
6/1 /89 6/1/91 5/31/93 5/31/95 5/30/97 5/30/99 5/29/01 5/29/03
Date
-------------------
~ Cl E ~
C
V-23 Benzene Data
0.3 -,--------------------------------------------,
0.25
0.2
(Unfilled data points represent qualified data
or values below the detection level.)
,8 0.15 f! ...
C 8 C 8
0.1
0.05
0-l-~----f-------=4!=.._ ___ --t-----+------+------+--D-----t'
6/1 /89 6/1/91 5/31/93 5/31/95 5/30/97 5/30/99 5/29/01 5/29/03
Sample Date
-------------------
K-28 TOC Data
9000 ~------------------------------------7
::J' -.,,
8000
7000
6000
5 5000
C .Q ~ ~ 4000
8
3000
2000
1000
(Unfilled data points represent qualified data
or values below the detection level.)
o uu.._--+-----+-----+-----,~-=-_.::::i::ii-----~~~ ............. -.+--=:»------i-J
8/14/81 5/10/84 2/4/87 10/31 /89 7/27 /92
Date
4/23/95 1/17/98 10/13/00 7/10/03
-------------------
~
K-28 Benzene Data
0.035 -,------------------------------------------~
0.03
0.025
(Unfilled data points represent qualified data
or values below the detection level.)
----------------------------------------------------------------------------------------
- -------------------------------------------------------------------------------------------------
~ 0.02 -----------------------------------------------------------
~
C 0 i Q) g 0.015
8
0.01
0.005
----------------------------------------------------
0+--------l------+------+-------,---+----------l------+-----~
6/1/89 6/1/91 5/31/93 5/31/95 5/30/97 5/30/99 5/29/01
Date
-------------------
HH-48 TCE Data
0.25 ~--------------------------------------------,
0.2
~ 0.15
Cl E ~
.§
! g
8 0.1
0.05
(Unfilled data points represent qualified data
or values below the detection level.)
o~------+--------+------+----~--+-------+------1--------+'
6/30/89 6/30/91 6/29/93 6/29/95 6/28/97 6/28/99 6/27/01 6/27/03
Date
-------------------
HH-77 TCE Data
0.5 ~-------------------------------------------,
0.45
0.4
0.35
~ 0.3
C)
E ~
C 2 0.25 E ~ fl 5 0.2 u
0.15
0.1
0.05
0 -1--=:...._ ____ --+--------+--------+--------+-------+--------+--------t-'
6/1/89 6/1/91 5/31/93 5/31 /95 5/30/97 5/30/99 5/29/01 5/29/03
Date