NCD003446721_20030331_Celeanse Corporation - Shelby Fiber_FRBCERCLA RA_OU-1 Semiannual Report July - December 2002-OCR

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Operable Unit 1-Semiannual Report
July 2002 -December 2002
CNA Holdings, lnc.{Ticona
(F.K.A. Celanese Fiber Operations)
Shelby, North Carolina
Document Control No. 026S8-0129
Submitted to
U.S. Environmental Protection Agency
Region IV
Atlanta, Georgia
Prepared for
CNA Holdings, Inc.
Shelby, North Carolina
March 2003
Kubal-Furr & Associates
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Post Office Box 273210
Tampa, FL 33688-3210
[phone]
FAX [phone]
Mr. Luis Flores
Remedial Project Manager
U.S. Environmental Protection
Agency, Region IV
61 Forsyth Street
Atlanta, GA 30303
Dear Mr. Flores:
Kubal-Furr & Associates
Environmental Management Services
March 31, 2003
. I
Post Office Box 80247
Simpsonville, SC 29680-0247
[phone]
FAX [phone]
APR 7 2003
• \ , ' , ,~, ' I , '.
On behalf of CNA Holdings, Inc., we are pleased to enclose two copies of the report entitled:
"Operable Unit 1-Semiannual Report-July 2002-December 2002-CNA Holdings,
lnc.-Shelby, North Carolina." By way of this letter, we have also transmitted a copy of the
report to David Mattison with NCDENR for his review.
Please contact me at 813-265-2338, to discuss any questions you may have following your
review of this document.
Sincerely,
Kubal-Furr & Associates
Jz,,/4, ';r!vt__
Jerry E. Kubal, P.G.
President
cc: Mr. David Mattison, NCDENR
Mr. Steven F. Olp, Celanese Americas
Ms. PEM Carter, Ticona-Shelby ESHA
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Contents
Page
Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1
Work Performed . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3
3rd Quarter 2002 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3
4th Quarter 2002 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4
System Performance . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6
Inner Tier Extraction Rates . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6
Ground-Water Movement .............................................. 6
Treatment Efficiencies . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7
Maintenance Activities . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7
Analytical Test Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8
Data-Quality Assessment . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8
Discussion of Analytical Test Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8
Review of Selected Historical Water-Quality Data . . . . . . . . . . . . . . . . . . . . . . . . . . 11
Table l.
Table 2.
Table 3.
Table 4.
Table 5.
Table 6.
Tables
2002 Sampling Matrix-CNA Holdings, Inc.-Shelby, NC
Inner Tier TOC (Total Organic Carbon) Data (July 2002 -December 2002)
Inner Tier Production Data (July 2002 -December 2002)
Summary of Selected CERCLA-related Water-Quality Data (3rd Quarter 2002)
Summary of Selected CERCLA-related Water-Quality Data (4th Quarter 2002)
Summary of Selected PEW-related Water-Quality Data (3rd Quarter 2002)
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Figures
Figure 1. Site Location
Figure 2. Potentiometric Surface Map-Shallow Saprolite-August l, 2002
Figure 3. Potentiometric Surface Map-Deep Saprolite/Upper Bedrock-August 1, 2002
Figure 4. Hydrogeologic Cross Section A-A', August 1, 2002
Figure 5. Potentiometric Surface Map-Shallow Saprolite-November 7, 2002
Figure 6. Potentiometric Surface Map-Deep Saprolite/Upper Bedrock-November 7, 2002
Figure 7. Hydrogeologic Cross Section A-A', November 7, 2002
Attachments
Attachment 1. Operation and Maintenance Data (July 2002 -December 2002)
Attachment 2. Analytical Data for the 3rd and 4th Quarter 2002 Sampling Events
Attachment 3. Selected Water-Quality Plots
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I Acronyms/Abbreviations
I CERCLA Comprehensive Environmental Response and Liability Act
CFO Celanese Fiber Operations
I CNA CNA Holdings, Inc.
I
EPA U.S. Environmental Protection Agency
FII Fiber Industries, Inc.
I FP Filter Press
GC(FID Gas Chromatograph/Flame Ionization Detector
I !MAC Interim Maximum Allowable Concentration (North Carolina)
I ITCI Inner Tier Combined Influent
ITEF Inner Tier Effluent
I LTRA Long Term Remedial Action
MCL Maximum Contaminant Level
I MEK Methyl Ethyl Ketone (2-Butanone)
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mg/L Milligrams per Liter
OTC! Outer Tier Combined Influent
I OTEF Outer Tier Effluent
OU-1 Operable Unit 1
I OU-2 Operable Unit 2
PEW Product Extraction Well
I ppm Parts per Million
I ROD Record of Decision
SBR Sequencing Batch Reactor
I svoc Semivolatile Organic Compound
TCE Trichloroethene
I TCLP Toxicity Characteristic Leaching Procedure
I voe Volatile Organic Compound
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CNA Holdings, Jnc./Ticona--She/by, NC-Q3/Q4 2002 Semiannual Report Page I
Introduction
Ticona, an operating subsidiary of Celanese, owns and operates a polyester and engineering
plastics production faculty in Shelby, North Carolina. CNA Holdings, Inc. (CNA), also a
subsidiary of Celanese, retains management of environmental matters for the corporation and thus,
is responsible for the work performed during the semiannual reporting period. The Shelby site
consists of an approximate 450-acre piece of property which includes the main plant production
area, wastewater treatment area, former waste disposal areas, and recreational areas. The plant is
located in south-c_entral Cleveland County, bordered by NC Highway 198 to the west and Lavender
Road to the south, approximately one mile north of Earl and six miles south of Shelby. A site plan
showing the location of production areas, monitor wells, extraction wells, and other significant
features is shown on Figure 1.
Operations at the site began in 1960 by Fiber Industries, Inc. (FIi), a manufacturer of polyester
chips and filament yarn. Celanese Corporation bought the facility from FIi in 1983, renaming it
Celanese Fiber Operations (CFO), and continued the production and processing of polyester
polymer chips and fibers. The site has alternately been known as HNA Holdings, Inc., Hoechst
Celanese Corporation, and Celanese Fiber Operations, the latter being the site name as listed on the
NPL.
CNA currently operates a long term remedial action (LTRA) system at the CFO site, designated
as Operable Unit 1 (OU-1) in the Record of Decision (ROD), which consists of two ground-water
extraction and treatment systems identified as the Inner Tier and Outer Tier systems. OU-1 became
operational in August 1989. A second operable unit, OU-2, consisted of excavation, incineration,
stabilization and reburial of treated sludge and other waste materials. As part of this effort, CNA
maintains and monitors the effectiveness of the ground-water recovery and treatment system;
collects quarterly ground-water levels and samples from selected monitor wells and process points;
and, reports the status of these activities to the EPA and State of North Carolina on a semiannual
basis.
On April 21, 1998, OU-2 and the Outer Tier portion of OU-1 were shut down as part of a
partial delisting petition approved by the EPA effective April 17, 1998. Currently, active ground-
water recovery and treatment is only taking place at the Inner Tier, which was designed to extract
contaminated ground water from around a former source area remediated as part of OU-2.
Although the Outer Tier is not actively recovering ground water, Outer Tier well OT-IR is still
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CNA Holdings, lnc./Ticona-Shelby, NC-Q3JQ4 2002 Semiannual Report Page2
pumped to provide make-up water for the ground-water treatment system and for process water
used for back-flushing filters. The entire Outer Tier is being maintained in "stand-by status" as
part of the de listing process and can be brought on line within a relatively short period of time (24-
48 hours) if it is found necessary to provide hydraulic control along the property boundary. The
Outer Tier wells and treatment system's functionality is assured by performing routine monthly
and quarterly system checks such as energizing the well pumps, transfer pumps and blowers,
verifying heater operation, etc. and performing maintenance activities as required by the routine
system checks.
Kubal-Furr & Associates (Kubal-Furr) has prepared this semiannual OU-1 operating summary
report for submittal to the EPA on behalf of CNA. It covers the period from July 1, 2002 through
December 31, 2002 and includes information on system performance and the results of analytical
testing of samples collected during the period August 5-7, 2002 and on November 8, 2002 and
December 5, 2002.
On October 30, 2002, the EPA submitted comments to CNA on the January 2002-June 2002
semiannual report. For the most part, the comments fell into a few general categories including:
listing of acronyms and abbreviations; consistency between text, tables and figures; and, correction
of data tables and consistency between tabular data and laboratory reports. These comments have
been addressed in the current semiannual report-requested additions have been provided, while the
text, tables and figures have been edited to provide consistency across the report and to assure
consistency between tabular data, data contained in the text and data contained in the laboratory
reports.
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CNA Holdings, lnc.(Ticona---Shelby, NC-Q3/Q4 2002 Semiannual Report Page3
Work Performed
As part of the OU-1 remedy, samples are collected at selected monitor wells and at points in the
ground-water treatment system. In addition, samples were collected from the inactive product
extraction well (PEW) system and selected PEW-related monitor wells. The location of all monitor
and extraction wells is shown on Figure 1. A list of sampling locations and the parameters analyzed
during the 3rd and 4th Quarters are summarized in Table 1. A description of the work performed
during this reporting period is provided below.
3rd Quarter 2002
On August 1, 2002, water levels were measured by Kubal-Furr in a total of 102 monitor wells,
extraction wells, and piezometers. A total of 17 ground-water quality samples, plus 1 duplicate and
2 equipment blank samples were collected during the period August 5-7, 2002 from selected
monitor wells and extraction wells. Additionally, two process point samples plus one duplicate were
also collected. All samples were collected by Kubal-Furr and analyzed by Davis & Floyd of
Greenwood, South Carolina.
OU-I Monitor Well Sampling
Thirteen monitor well samples (plus one duplicate) were sampled using low-flow sampling
protocols. The samples were analyzed in the field for pH, temperature and conductance; and, by the
laboratory for volatile organic compounds (VOCs) using EPA Method 8260B. In addition to
analysis of volatiles, samples from monitor wells K-28 and V-23 were also analyzed by the
laboratory for total organic carbon (TOC) using EPA Method 9060.
OU-I Process Point Sampling
Samples of Inner Tier influent and effluent were collected for analysis of volatile organics by
Method 8260B. The Inner Tier influent and effluent samples were also analyzed by the laboratory
for TOC by Method 9060, and for ethylene glycol by GC/FID (gas chromatograph/flame
ionization detector).
During the reporting period, influent and effluent samples,from the Inner Tier were also
collected by CNA personnel for analysis of TOC by Davis & Floyd. These samples are collected
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CNA Holdings, Inc./Ticona--Shelby, NC-Q3/Q4 2002 Semiannual Report Page4
weekly to evaluate treatment efficiency, and the results are contained in the O&M reports provided
in Attachment 1. These results are also summarized in Table 2.
PEW Extraction and Monitor Well Sampling
One PEW-related monitor well (F-55) and three inactive PEW extraction well samples were
collected during the 3rd Quarter. These samples were analyzed for VOCs by EPA Method 8260B
and for SVOCs (semivolatile organic compounds) by EPA Method 8270C (including the
DowTherm®A constituents biphenyl and diphenyl ether).
4th Quarter 2002
On November 7, 2002, water levels were measured by Kubal-Furr in a total of 103 monitor
wells, extraction wells, and piezometers. Water-quality samples were collected from 2 monitor wells
and 2 process points (plus one duplicate), and analyzed for the parameters summarized in Table 1.
Samples were collected on November 8, 2002 by Kubal-Furr and analyzed by Davis & Floyd.
Process point samples ITC!, ITEF, and ITEF-Duplicate collected on November 8, 2002 were tested
for preservation compliance by the lab and the pH of the samples was determined to be a pH of 4,
above the preservation requirement of pH 2, and the samples were classified as "unpreserved." The
hold time limit for unpreserved VOC samples is seven days. Since the VOC analyses had occurred
after the adjusted hold time, the process point samples were collected again on December 5, 2002.
The November 8th data was qualified due to failing hold time limits.
Monitor Well Sampling
Monitor wells K-28 and V-23 were sampled during the 4th Quarter sampling event. These wells
were analyzed in the field for pH, temperature and conductivity; and, by the laboratory for TOC by
Method 9060.
Process Point Sampling
Samples of Inner Tier influent and effluent (plus one effluent duplicate) were collected for
analysis of TOC by Method 9060 and VOCs by EPA Method 8260B. The Inner Tier influent and
effluent samples were also analyzed for ethylene glycol by GC/FID.
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CNA Holdings, lnc./Ticona~helby, NC-Q3/Q4 2002 Semiannual Report Page5
Free Product DowTherm®A Bailing-Well F-55
As noted in earlier semiannual reports, free product DowTherm®A was found to be
accumulating in monitor well F-55 following the well rehabilitation program implemented in
September 2001. Subsequently, well F-55 was bailed on five separate occasions and a total of
approximately 4.6 liters of DowTherm®A have been recovered. During the 4th Quarter, well F-55
was tested using an interface probe and found to have an accumulation of approximately 1.7 ft of
product which could not be bailed with the standard, conventional 2-in sampling bailers. F-55 was
bailed on December 11, 2003 using a small diameter bailer and approximately 1 liter of free product
was recovered, br!nging to 5.6 liters the total amount of DowTherm®A recovered to date. This well
will be tested again in the 1st Quarter of 2003 and any further free product accumulations will be
removed and recorded.
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CNA Holdings, /nc./Tico11a-Shelby, NC-Q3/Q4 2002 Semiannual Report Page6
System Performance
Detailed records of system maintenance are kept by CNA and are summarized monthly. The
monthly records for the current reporting period are contained in Attachment 1.
Inner Tier Extraction Rates
During the reporting period, the Inner Tier wells extracted a total of 217,367 gallons (Table 3).
Inner Tier flows ranged from a low of 30,067 gallons in August, to a high of 46,657 gallons in
December. The ~equencing batch reactor (SBR) treatment system is designed to process a
maximum of about 2500 gallons of water per day from the Inner Tier extraction well system. With
184 days in the reporting period, at design capacity, pumping from the Inner Tier would have been
some 460,000 gallons. Based on the pumpage during the reporting period, the Inner Tier extraction
system was producing at a rate of about 47% of the design capacity, which represents a decrease
from the previous semiannual reporting period during which the Inner Tier produced about 54%
(245,871 gallons) of the design capacity rate.
Ground-Water Movement
In order to accurately predict the direction of ground-water movement, water-level
measurements were collected from all accessible monitor wells, extraction wells and piezometers on
August 1, 2002 by Kubal-Furr, and again on November 7, 2002. These data were used to construct
the potentiometric surface maps and hydrogeologic cross sections (Figures 2 thru 7).
The shallow saprolite maps (Figures 2 and 5) show the water-level contours and direction of
ground-water movement in the uppermost water-bearing zone beneath the site. The direction of
movement in this zone is to the east from upgradient areas along NC 198, towards discharge areas
along the intermittent, unnamed tributaries of Buffalo Creek. Drawdown and a capture zone are
apparent on these figures situated around the Inner Tier extraction system.
An attempt was made to separate the uppermost water-bearing zone from the deeper saprolite
and upper bedrock zone. While these inaps (Figures 3 and 6) present a reasonable picture of
ground-water movement in this zone, it should be pointed out that it is giving a somewhat more
generalized picture of ground-water movement because of the wel,l construction techniques used in
many of the wells and piezometers. The typical construction of these wells was to have relatively
long screens and extremely long sand packs in the annular space above the screens. As a result, the
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CNA Holdings, lnc./Ticona---Shelby, NC-Q3/Q4 2002 Semiannual Report Page 7
lower saprolite/upper bedrock maps have a number of composite head values measured along a
longer screened area. However, the maps may be useful for determining the general direction of
ground-water movement.
To confirm inferences made about the direction of movement and hydraulic control exerted by
the Inner Tier system, hydrogeologic cross sections were constructed from the August and
November data sets (Figures 4 and 7). The location of the cross section is shown on the site
location map, Figure 1. The east-west cross section (A-A') is constructed through the plant from
upgradient areas west of the plant to downgradient, off-site areas east of the plant. The east-west
hydrogeologic c~oss section indicates flow is predominantly horizontal across the site, from
up gradient areas west of the plant toward downgradient areas to the east.
Treatment Efficiencies
Two aspects of the extraction system performance were reviewed for this semiannual report: the
production rates achieved during the reporting period, and the removal efficiencies for TOC from
the Inner Tier system.
Table 2 summarizes the treatment system effectiveness for the Inner Tier i_n removing TOC
during the reporting period. These summaries, as presented in the monthly operating summaries
(Attachment 1), were prepared from the water-quality data collected weekly by CNA personnel and
analyzed by Davis & Floyd. During the reporting period, the Inner Tier average removal efficiency
for TOC was approximately 98.8%, with an average influent concentration of 1572 ppm (parts per
million), and an average effluent concentration of 17.1 ppm.
Maintenance Activities
Outer Tier maintenance items included, replacing pumps (OT-6) and replacing light bulbs
inside the "dog houses" (OT-2R, OT-6, OT-7) which cover the extraction wells. Low flow from
the Inner Tier wells is a chronic problem requiring frequent maintenance. The actions taken to
rectify the low flow problems consisted of replacing bladders, timers, air lines and such, adjusting
the controls and flow rates, and cleaning the strainers. Specific actions taken at individual wells
during the reporting period are contained in the monthly operating summaries (Attachment 1).
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CNA Holdings, /nc./Ticona---Shelby, NC-Q3/Q4 2002 Semiannual Report Page8
Analytical Test Results
The analytical test results for the 3rd and 4th Quarter sampling events were evaluated using
method specific quality control criteria and, for additional guidance when necessary, the EPA's
National Functional Guidelines for organic and inorganic data review. Analytical test results, field
sampling logs, and chain-of-custody forms for the 3rd and 4th Quarter data sets are contained in
Attachment 2. A summary of selected analytical data for the 3rd and 4th Quarters is presented in
Tables 4, 5 and 6.
Data-Quality ~ssessment
Regarding sample collection, the sampling logs and field information provided were complete.
All 3rd and 4th Quarter data were considered quantitative with several exceptions. Based on the data
quality assessment, qualifiers were placed on selected analytical results as noted in Tables 4, 5 and
6. A complete description of the data review and qualified results is provided with the 3rd and 4th
Quarter data packages in Attachment 2.
As noted earlier, process point samples ITC!, ITEF, and ITEF-Duplicate collected in the 4th
Quarter on November 8, 2002 were tested for preservation compliance and the pH of the samples
was determined to be above the preservation requirement of pH 2 at pH 4. At pH 4, the samples are
technically classified as "unpreserved." The hold time limit for unpreserved VOC samples is seven
days. Since the VOC analyses had occurred after the adjusted hold time, the samples were collected
again on December 5, 2002. The November 8th data was qualified due to failing hold time limits.
Analytes reported as not detected are flagged "UJ" and positive detections are flagged "J."
Discussion of Analytical Test Results
CERCLA-Monitor Wells
Of the 13 CERCLA-monitor well samples analyzed during the reporting period, eight had
volatile organics reported above the detection level (Table 4). Of these eight, only four (K-28, T-35,
V-23 and FF-62) had more than two individual volatile constituents reported as present above the
detection level. The most frequently reported volatiles included benzene, chloromethane and
trichloroethene.
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CNA Holdings, lnc./Ticona-Shelby, NC-Q3/Q4 2002 Semiannual Report Page9
Monitor wells K-28, located just downgradient of the Inner Tier extraction system, and V-23,
located just up gradient of the Inner Tier extraction system, reported the largest number of individual
volatiles at six each. K-28 and V-23 reportedly contained five of the same volatiles: acetone (0.18
mg/L [milligrams per liter] and 0.47 mg/L, respectively), benzene (0.0087 mg/Land 0.020 mg/L,
respectively), 2-butanone (0.17 mg/Land 0.34 mg/L, respectively), carbon disulfide (0.0020 mg/L
and 0.011 mg/L, respectively) and toluene (0.0025 mg/L and 0.0071 mg/L, respectively). In
addition, vinyl acetate (0.0053 mg/L) was reported as present in V-23, while chloromethane (0.0022
mg/L) was reported as present at K-28.
Monitor well T-35 reportedly contained the volatiles 1,2-dichloroethane (0.0012 mg/L), benzene
(0.0012 mg/L), chloromethane (0.0030 mg/L) and trichloroethene (0.0016 mg!L). Monitor well C-
49 reportedly contained bromoform (0.0013 mg/L) and chloromethane (0.0027 mg/L). Monitor
well CC-33 reportedly contained cis-1,2-dichloroethifie (0.0025 mg/L) and trichloroethene (0.0059
mg/L). Monitor well FF-62 reported the presence of benzene (0.0015J mg/L, an estimated value),
chlorobenzene (0.0012J mg/L, an estimated value) and chloromethane (0.0010 mg/L). The only
volatile reported as present at monitor wells HH-48 and HH-77 was trichloroethene at 0.13 mg/L
and 0.46 mg/L respectively.
Monitor wells K-28 and V-23 were also analyzed for TOC during the 3rd and 4th Quarters.
The K-28 test results for the 3rd and 4th Quarters were 1990 mg/Land 1450 mg/L, respectively.
The TOC test result for V-23 and the duplicate at this location for the 3rd Quarter wasl0,500 mg/L
and 10,400 mg/L, respectively. The reported value for TOC for the 4th Quarter at V-23 was 71.lX
mg/L. This would be an historic low concentration for TOC at well V-23, which has been
fluctuating in the range of 3,000 to 12,000 mg/L the past six years. While no quality assurance
problems were noted during data review, the reported value has to be considered suspect based on
the almost 20 years of TOC data from this well. The laboratory was questioned about this value and
agreed an error most likely occurred in the reported dilution (of 1) on the bench sheets, but they
were unable to determine what the true dilution factor might be. The lab also noted that the yet to be
released data package for the subsequent quarter (1st Q 2003) showed the TOC at well V-23 would
be in the 4,000 mg/L range for both the well sample and its duplicate. For these reasons, this data
point was assigned an X qualifier, as the data are considered suspect. These data also were not used
in the time concentration plots for V-23 TOC provided in Attachment 3.
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CNA Holdings, lnc./Ticona--Shelby, NC-Q3JQ4 2002 Semiannual Report Page 10
Process Point Samples
Inner Tier influent and effluent samples were analyzed during the 3rd and 4th Quarters for
ethylene glycol, TOC, and volatile organics. The 3rd Quarter Inner Tier influent sample reportedly
contained the volatiles acetone (0.12 mg/L), benzene (0.031 mg/L), chlorobenzene (0.017 mg/L), 2-
butanone (0.026 mg/L), cis-1,2-dichloroeth;~e (0.0044 mg/L), toluene (0.0011 mg/L),
trichloroethene (0.0037 mg/L), vinyl chloride (0.0015 mg/L), chloromethane (0.0016 mg/L) and
carbon disulfide (0.0061 mg/L). The 4th Quarter Inner Tier influent sample reportedly contained
the volatiles acetone (0.077 mg/L), benzene (0.029 mg/L), 2-butanone (0.030 mg/L), carbon
disulfide (0.0022 _mg/L), chlorobenzene (0.026 mg/L), toluene (0.0014 mg!L), vinyl acetate (0.0010
mg/L) and xylenes (0.0020 mg/L). Inner Tier influent ethylene glycol results for the 3rd and 4th
Quarters were reported at 505 mg/Land 1610 mg/L, respectively. Inner Tier influent TOC results
for the 3rd and 4th Quarters were reported at 1730 mg/Land 2380 mg/L, respectively.
While no volatiles were reported above the detection level in the Inner Tier effluent sample for
the 4th Quarter, the Inner Tier effluent sample reportedly contained the following volatiles in the 3rd
Quarter: bromoform (0.0026 mg/L), chloromethane (0.0018 mg/L) and dibromochloromethane
(0.0014 mg/L). Ethylene glycol for the 3rd and 4th Quarter Inner Tier effluent samples were
reported below the detection limit of 5 mg/L. Inner Tier effluent TOC was reported as 20.5 mg/L
and 251 mg/L for the 3rd and 4th Quarters, respectively.
PEW-Related Samples
Four PEW-related samples were collected during the 3rd Quarter. Of the four, PEW-3 had no
constituents reported above the detection level. Three (F-55, PEW-1 and PEW-4) had more than
one volatile or semivolatile constituent reported as present. Acetone (0.34 mg/L), benzene (0.052
mg/L), 2-butanone (0.33 mg/L), carbon disulfide (0.0042 mg/L), and toluene (0.00801 mg/L, an
estimated value) were reported as present in well F-55. Chloroform was reported as present at
PEW-1 (0.0022 mg/L), and PEW-1 and PEW-4 reportedly contained benzene (0.0021 mg/Land
0.0041 mg/L, respectively) cis-1,2-dichloroeth{ne (0.0014 mg/Land 0.010 mg/L, respectively) and
trichloroethene (0.0062 mg/Land 0.017 mg/L, respectively).
Two of the four wells sampled had reportable quantities of DowTherm®A constituents (i.e.,
1,1-biphenyl or biphenyl ether). 1,1-Biphenyl was reported as.present in well F-55 (9 mg/L).
Biphenyl ether was reported as present in well F-55 (31 mg/L) and PEW-4 (0.035 mg/L). Well F-
55 also reportedly contained the semivolatile constituents dibenzofuran (0.013 mg!L) and bis(2-
Kubal-Furr & Associates
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CNA Holdings, lnc./Ticona--Shelby, NC-Q3JQ4 2002 Semiannual Report
ethylhexyl)phthalate (0.025 mg/L). The analytical results for DowTherm®A constituents at F-55
are above the solubility for this compound in water and would indicate the presence of residual
NAPL material or free phase DowTherm®A in the well. This is consistent with the DowTherm®A
found to have accumulated in the bottom of F-55 when tested with the interphase probe during the
4th Quarter. The bailing of DowTherm®A at F-55 was discussed in an earlier section describing
work performed during the 4th Quarter.
Review of Selected Historical Water-Quality Data
Attachment 3 _contains plots of selected water-quality constituents for various monitor wells and
process points. The choice of locations and constituents was based on a review of the water-quality
database, in particular those locations having any meaningful data to plot. In general, only those
monitoring locations within a few hundred feet of the former OU-2 source area have any significant
number of water-quality constituents reported above the detection limits. In order to assess long-
term trends and improvement in water-quality conditions resulting from source removal and
ground-water recovery, the following locations and constituents were selected:
• Inner Tier Combined Influent TOC and ethylene glycol test results. The Inner Tier TOC
increased between the 2nd, 3rd and 4th Quarters of 2002 and has been fluctuating within a
range of 1,000 mg/L to 3,000 mg/L since 1995. The Inner Tier ethylene glycol data
increased between the 3rd and 4th Quarters to more than 1500 mg/L. Prior to this increase,
ethylene glycol had been fluctuating between 500 mg/I and 1000 i;ng!L for the previous 9
quarters. The increasing trends noted at this location will continue to be evaluated during the
next semiannual reporting period.
• Monitor Well V-23 TOC, 2-butanone (MEK-methyl ethyl ketone), acetone and benzene.
The V-23 TOC data began trending downward from a high of 8000 mg/Lin mid-1989 to
less than 1000 mg/Lin early 1992. Since that time, the TOC data have shown several wide
swings in concentration, with a historic high of 11,800 mg/L achieved in October of 1997.
Since 1996, the TOC values at this well have generally fluctuated in the range of 6,000 mg/L
to 12,000 mg/L. As noted in earlier text, the V-23 TOC data for the 4th Quarter is
considered suspect at 71.1 mg/L, and was not used in construction of the time concentration
plots for this well.
The V-23 MEK data have generally fluctuated in a narrow range below 1 mg/L, with 11 of
36 data points below the detection level. The values for MEK increased between the 1st and
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CNA Holdings, lnc./Ticona---Shelby, NC-Q3/Q4 2002 Semiannual Report Page 12
•
3rd Quarter sampling events although the last 11 sample results have all been below 0.5
mg/L.
The V-23 acetone test results have been oscillating between 0.2 mg/Land 0.5 mg/L for the
past four years and no discemable trend is apparent in the V-23 acetone data set.
While more than half the benzene data for V-23 is flagged as estimated or below the
detection limit, the past 15 sampling events have been quantitative and show benzene to be
fluctuating in a narrow range of from 0.01 to 0.03 mg/L.
Monitor well K-28 TOC and benzene data. TOC and benzene have both shown a steady
decrease in concentration beginning about the time the OU-2 source remediation began in
January of 1991. However, the TOC concentrations have shown several wide swings in
concentration up to 2000 mg!L during the past two years. These increases were thought to
be the result of a well rehabilitation program undertaken in 2001, although no
corresponding increase in other constituent concentrations were noted at this well. Benzene
has shown a general decline since OU-2 source remediation and the last eight sampling
events since the 1st Quarter of 1999 have all been reported as less than or equal to 0.01
mg/L.
• Monitor well HH-48 and HH-77 TCE (trichloroethene) data. The HH-48 TCE test results
had shown a decline from 0.222 mg/Lin August of 1995 to less than 0.1 mg/L during the
3rd Quarter of 2000. Since that time, TCE at HH-48 have steadily increased to the current
3rd Quarter value of 0.13 mg/L. TCE at HH-77 had been fluctuating in the range of 0.05
mg/L to 0.15 mg/L until the July 1996 sampling event when it peaked at 0.383 mg/L. TCE
at HH-77 had been decreasing substantially since then to 0.059 mg!L during the 1st Quarter
of 2001, however, the concentration was noted to increase to near historic highs during the
3rd Quarter of 2001 (0.35 mg/L) and to achieve a historic high of 0.46 mg/L during the 3rd
Quarter of 2003. The presence of TCE at this location is thought to be the result of a
localized source, unrelated to activities at CNA/Ticona or the former OU-2 source area.
Kubal-Furr & Associates
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Table 1. 2002 Sampling Matrix-CNA Holdings, lnc.-Shelby, NC
1st Quarter 2nd Quarter 3rd Quarter
Monitoring TOe voe Eth. Glycol TOe voe Eth. Glycol TOe voe Eth. Glycol
Location (9060) (82608) (GC/FID) (9060) (82608) (GC/FID) (9060) (82608) (GC/FID)
Process Points
ITCI -J -J -J -J -J -J -J -J -J
ITEF -J -J -J -J -J -J -J -J -J
OTCI {OT Pumi;i:ing Discontinued on 4/21 /98}
OTEF
SBR Sludge (Full TCLP)
FP Sludge (Full TCLP)
Monitor Wells
C-49 -J -J
K-28 -J -J -J -J -J
P-58
T-35 -J -J
V-23 -J -J -J -J -J
AA-54
CC-33 -J -J
EE-58 -J -J
FF-34
FF-62 -J -J
GG-61 -J -J
HH-48
HH-77 -J -J
voe svoc voe svoe
(82608) (8270C) (82608) (8270e)
PEW-Related Same/es
PEW-1 -J -J -J -J
PEW-3 -J -J -J -J
PEW-4 -J -J -J -J
F-55
Notes: TOC .. Total Organic Carbon ITEF = Inner Tier Effluent
VOC = Volatile Organic Compounds OTCI = Outer Tier Combined Influent
Eth. Glycol = Ethylene Glycol OTEF = Outer ller Effluent
GC/FID = Gas Chromatograph/Flame Ionization Detector SBR ... Sequencing Batch Reactor
TCLP = Toxicity Characteristic Leaching Procedure FP = Filter Press
SVOC = Semivolatile Organic Compounds PEW = Product Extraction Well
ITCI = Inner Tier Combined Influent
- - - -
4th Quarter
TOC voe Eth. Glycol
(9060) (82608) (GC/FID)
-J -J -J
-J -J -J
-J
-J
CNA Jloldings, lnc.-Shelby. NC
OU-I Semiannual Report ()11/y '02 -Dec. '02)
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Table 2. Inner lier TOC (Total Organic Carbon) Data
July '02 -Dec. '02
CNA Holdings, lnc.-Shelby, North Carolina
( all results reported in parts per million [ppm])
Date Influent Effluent % Reduction
7 /2/02 1530 20.5 98.7
7 /9/02 1440 19.9 98.6
7 /17 /02 1400 15.0 98.9
7 /24/02 1850 22.0 98.8
......... 7 /31/02 ....... ······· .... 1.88 . ..=.0 __ .............. 1.4.5 ............................... 99.2 ........... .
8/7/02 2460 12.9 99.5
8/14/02 144011 18.8 98.7
8/21/02 220011 16.6 99.2
........ 8/28/02 3140 46.4 98.5 .............. ,, ...................................................... . ......................
9/5/02 1180 11.9 99.0
9/11/02 1200 l/ 13.9 98.8
9/17/02 1270 14.2 98.9
9/24/02 1210 11.9 99.0 ·················································· ···········•···········•······················•····•···•··· ···················•··•········•············ 10/2/02
10/9/02
10/16/02
10/22/02
2160
1380
1060
1230
10.9
12.7
14.4
19.8
99.5
99.1
98.6
98.4
...... 1.0/30/02 ...................... 978 .............................. 21 .. 4 .............................. !l.!.:?.. ......... .
11 /6/02
11/12/02
11/19/02
936
785
1060
20.9
19.6
16.1
97.8
97.5
98.5
...... 1.1127102 ..................... 2230 ............................ 1.0 .. 5 ............................... 99.5 ........... .
12/3/02
12/11 /02
12/18/02
12/25/02
Average:
Notes:
2080
1520
2020
1230
1572
8.8
7.0
25.6
19.0
17.1
99.6
99.5
98.7
98.5
98.8
1 / = Sample out of holdtime due to equipment failure.
The result is consistent with historical data from the site.
CNA Holdings, lnc.-Slzelby, NC
OU-I Semiannual Report (July '02-Dec. '02)
./
--- --- -
July 2002 August 2002
Total Total
----
Table 3. Inner Tier Production Data
July '02 -Dec. '02
CNA Holdings, lnc.-Shelby, NC
September 2002 October 2002
Total Total
-
~ Gallons ADF* Gallons ~ Gallons ADF* Gallons ADP'
IT-1 2,490 80 2,455 79 2,238
IT-2 802 26 625 20 444
IT-3 1 104 .......... 36 849 .... 27 863
IT-4 2,282 74 2.297 74 2,215
IT-5 4,929 159 3,853 124 5,225
IT-6 1.6.ZG ..................... 5.4 1 136 37 487
IT-7 1,025 33 1,391 45 1,490
IT-SR 12,788 . 413 9,335 301 8,120
IT-9 9 482 306 8 126 262 10 991
36,578 30,067 32,073
* ADF: Average Daily Flow based on CNA production records (Attachment 1 ),
Calculated as total flow divided by the number of days in the month.
75 2,354 76
15 428 14
29 1 ?97 39
74 2,442 79
174 5,246 169
11; 1 .1.60 37
so 1,884 61
271 11,373 367
366 13 731 443
39,825
- -
November 2002
Total
Gallons ADF*
2,621 87
595 20
........ .J.,.9.§§ .... ' . . }6
2,711 90
5,646 188
.J,965 ............... }~
1,501 so
8,258 275
8 702 290
32,167
- - - --
December 2002 July-Dec. '02
Total
Gallons ADF* Total Gallons
3,185 103 15,343
2,329 75 5,223
......... J.14.§8 ..... 4? .. ...... ~ ... ~.~~-
2,750 89 14,697
6,413 207 31,312
...... 2,?8? ........ 7.4 .... !,~Q~
2,469 80 9,760
13,797 445 63,671
11 961 386 62,993
46,657 217,367
CNA Holdings, lnc.-Shelb_v, NC
OU-I Semiannual Report (July '02 -Dec. '02)
-------------------
Table 4. Summary of Selected CERCLA-Related Water-Quality Constituents (3rd Quarter 2002)
CNA Holdings, lnc.-Shelby, North Carolina
(All results reported in milligrams per liter [mg/L])
V-23
EPA/NC C-49 / K-28 / T-35 / V-<!3 / Duplicate/
Total Organic Carbon NE/NE NA ~-NA .l.Q5QQ.• lQ1Q_Q.
Ethylene Glycol NE/7.0 NA NA NA NA NA
Volatile Organics
1.2-Dichloroethane 0.005/0.00038 <0.0010 <0.0010 0.001 2 • <0.0050 <0.0050
2-Butanone(MEK) NE/0.17 <0.0010 Q.lI. <0.0010 Q..3.1. • Q,32_.
Acetone NE/0.7 <0.0050 Q,JJl_ . <0.0050 MI· ~-
Benzene 0.005/0.001 <0.0010 0.0087 • 0.0012 • 0...0.Z..0' M.1..9.·
Bromoform 0.08/0.00019 0.0013 • <0.0010 <0.0010 <0.0050 <0.0050
Carbon Disulfide NE/0.7 <0.0010 0.0020 • <0.0010 Mil· _Q,QJ_3_.
Chlorobenzene 0.1/0.05 <0.0010 <0.0010 <0.0010 <0.0050 <0.0050
Chloromethane NE/0.0026 0.0027 • 0.0022. 0.0030 • <0.0050 <0.0050
Cis-1.2-Dichloroethene 0.07/0.07 <0.0010 <0.0010 <0.0010 <0.0050 <0.0050
Dibromochloromethane 0.08/0.00041 * <0.0010 <0.0010 <0.0010 <0.0050 <0.0050
Toluene 1.0/1.0 <0.0010 0.0025 • <0.0010 0.0071 • 0.0072,
T richloroethene 0.005/0.0028 <0.0010 <0.0010 0.0016 • <0.0050 <0.0050
Vinyl Acetate NE/NE <0.0010 <0.0010 <0.0010 0,0053 • 0.0062 •
Vinyl Chloride 0.002/0.00001 5 <0.0010 <0.0010 <0.0010 <0.0050 <0.0050
Notes: NA = Sample not analyzed for indicated constituents
U = Compound was not detected above the associated value. however. results should be considered as estimated
J = Constituent positively identified however concentration should be considered as estimated
EPA= Environmental Protection Agency National Primary Drinking Water Standards
NC = North Carolina Groundwater Quality Standards (Subchapter 2L)
NE= Not Established
AA--~'1-?
G,1,. -<, I
rr::-~ J 4
£&:.-'"8
f-rs
'tr;f 131-k.>
CC-33./
NA
NA
<0.0010
<0.0010
<0.0050
<0.0010
<0.0010
<0.0010
<0.0010
<0.0010
0.0025 •
<0.0010
<0.0010
0.0059 •
<0.0010
<0.0010
* = North Carolina IMACs (Interim Maximum Allowable Concentrations) CNA Holdings, Inc.-Shelby. NC
OU-/ Semiannual Report (July '02 -Dec. '02)
-------------------
Table 4. (Cont'd) Summary of Selected CERCLA-Related Water-Quality Constituents (3rd Quarter 2002)
CNA Holdings, lnc.-Shelby, North Carolina
(All results reported in milligrams per liter [mg/L))
Inner Tier Inner Tier/
EPA/NC FF-62 ./ HH-48 / HH-77 / Influent/ Effluent
Total Organic Carbon NE/NE NA NA NA 1730 • ZlLl..
Ethylene Glycol NE/7.0 NA NA NA .5.Q.5. • <5.0 •
Volatile Organics
1,2-Dichloroethane 0.005/0.00038 <0.0010 <0.0010 <0.0010 <0.0010 <0.0010
2-Butanone(MEK) NE/0.17 <0.0010 <0.0010 <0.0010 MZ..6., <0.0010
Acetone NE/0.7 <0.0050 <0.0050 <0.0050 Q,J_2_, <0.0050
Benzene 0.005/0.001 0.001 SJ· <0.0010 <0.0010 0.031' <0.0010
Bromoform 0.08/0.00019 <0.0010 <0.0010 <0.0010 <0.0010 0.0026J.
Carbon Disulfide NE/0.7 <0.0010 <0.0010 <0.0010 0.0061 • <0.0010
Chlorobenzene 0.1 /0.05 0.001 ZJ • <0.0010 <0.0010 M.11.· <0.0010
Chloromethane NE/0.0026 0.0010 • <0.0010 <0.0010 0.0016 · 0.0018J ·
Cis-1 ,2-Dichloroethene 0.07/0.07 <0.0010 <0.0010 <0.0010 0.0044 • <0.0010
Dibromochloromethane 0.08/0.00041 * <0.0010 <0.0010 <0.0010 <0.0010 0.0014J,
Toluene 1 .0/1.0 <0.0010 <0.0010 <0.0010 0.0011 • <0.0010
Trichloroethene 0.005/0.0028 <0.0010 0.13 , 0.46 · 0.0037· <0.0010
Vinyl Acetate NE/NE <0.0010 <0.0010 <0.0010 <0.0010 <0.0010
Vinyl Chloride 0.002/0.00001 5 <0.0010 <0.0010 <0.0010 0.001 5. <0.0010
Notes: NA = Sample not analyzed for indicated constituents
U = Compound was not detected above the associated value, however, results should be considered as estimated
J = Constituent positively identified however concentration should be considered as estimated
EPA = Environmental Protection Agency National Primary Drinking Water Standards
NC = North Carolina Groundwater Quality Standards (Subchapter ZL)
NE= Not Established
* = North Carolina IMACs (Interim Maximum Allowable Concentrations)
Inner Tier
Effluent
Duplicate ✓
lIJi •
<5.0 •
<0.0010
<0.0010
<0.0050
<0.0010
0.001 OUJ •
<0.0010
<0.0010
0.001 OUJ •
<0.0010
0.001 OUJ •
<0.0010
<0.0010
<0.0010
<0.0010
CNA Holdings, lnc.-Shelby, NC
OU-/ Semiannual Report (July '02 -Dec. '02)
-------------------
Table 5. Summary of Selected CERCLA-Related Water-Quality Constituents (4th Quarter 2002)
CNA Holdings, lnc.-Shelby, North Carolina
Total Organic Carbon
Ethylene Glycol
Volatile Organics
Acetone
Benzene
2-Butanone (MEK)
Carbon Disulfide
Chlorobenzene
Toluene
Vinyl Acetate
Xylene (Total)
(All results reported in milligrams per liter [mg/LJ)
Inner Tier
EPA/NC K-28 V-23 Influent ✓
NE/NE 1450 71.1 X 2380 ·
NE/7.0 NA NA 1610 •
NE/0.7 NA NA 0.077.
0.005/0.001 NA NA 0.029.
NE/0.17 NA NA 0.030.
NE/0.7 NA NA 0.0022.
0.1/0.05 NA NA 0.026 ,
1.0/1.0 NA NA 0.0014,
NE/NE NA NA 0.0010 •
10/0.53 NA NA 0.0020 •
Inner Tier
Effluent/
251 ,
<5.0 ,
<0.005
<0.001
<0.001
<0.001
<0.001
<0.001
<0.001
<0.002
Notes: Total organic carbon and ethylene glycol analyses represent samples collected on 11 /8/02.
Volatile organic analyses represent samples recollected on 12/5/02 (see text for discussion
and Data Assessment Summary in Attachment 2)
NA= Sample not analyzed for indicated constituent(s)
X = Reviewer assigned qualifier; reported results are suspect
EPA= Environmental Protection Agency National Primary Drinking Water Standards
NC = North Carolina Groundwater Quality Standards (Subchapter 2L)
NE= Not Established
Inner Tier
Effluent
Duplicate ✓
246 •
<5.0 ·
<0.005
<0.001
<0.001
<0.001
<0.001
<0.001
<0.001
<0.002
CNA Holdings. lnc.-Shelby. NC
OU-1 Semiannual Report (July '02 -Dec. '02)
----------------~--
Table 6. Summary of Selected PEW-Related Water Quality Constituents (3rd Quarter 2002)
CNA Holdings, lnc.-Shelby, North Carolina
(All results reported in milligrams per liter [mg/L]}
EPA/NC F-55 / PEW-1 / PEW-4 ./
Semivolatile Organics
1, 1 Bi phenyl NE/NE ~· <0.010 <0.010
Biphenyl Ether NE/0.35 .3l.Q ' <0.010 ll.Q..3..5..
Dibenzofuran NE/0.028* MU· <0.010 <0.010
Bis( 2 -ethylhexyl) phthalate 0.006/0.003 Q_,_Q_Q , <0.010 <0.010
Volatile Organics
Acetone NE/0.7 Q....3.1 • <0.0050 <0.0050
Benzene 0.005/0.001 ~-Q.QQZl • O.OQ41 •
Carbon Disulfide NE/0.7 Q.Q042 · <0.0010 <0.0010
Chloroform NE/0.00019 <0.0030 Q.QQ22. <0.0010
Cis-1 ,2-Dichloroethene 0.07/0.07 <0.0030 O.QQ14 · Q_,QJ_Q. •
Toluene 1.0/1.0 Q.QQ8QJ. <0.0010 <0.0010
T richloroethene 0.005/0.0028 <0.0030 0.0062 · 0.017 •
2-Butanone (MEK) NE/0.17 lLl..3., <0.0050 <0.0050
,'f,W • :S
Notes: J = Constituent positively identified however concentration should be considered as estimated
EPA = Environmental Protection Agency National Primary Drinking Water Standards
NC = North Carolina Groundwater Quality Standards (Subchapter 2L)
NE= Not Established
* = North Carolina IMACs (Interim Maximum Allowable Concentrations)
CNA Holdings, /nc.-Shelby. NC
OU-I Semiannual Report (July '02 -Dec. '02)
---- - ----
,l,,Jl 0
0
-
Scale in Feet
350
-
700
.. ',
/
::.. Pl•ll
- -
o".....,..,$
-
SW-T
-- - -
Legend
o Monitor Well
Piez:omoter
Surface Water Location
♦ Outer Tier Extraction Well
• Inner Tier EKtractioo Wen
PEW Extraction Well
D Residential Well
fl
Crook/ Stream
Building I Structure
Kubal•Furr & Associates
-Environmental Consultants-
Figure I. Site Location Map
CNA Holdings. Inc.
Shelh_v. North Carolina
-
--
..
0
- -
Legend
Monitor Well Water-level (ft msl)
• Inner Tier Extraction Well
II
Creek I Stream
Building I Structure
--- -- --
~ .,
$
\ \
' ' .. ,
Seale in Feel
0 350 700
-
D
'
'
\
\
-
I
I
'
-
' \ \
\ \
I --1
I
• "
-- --Inner Tier Extraction Well
Water-Level Elevations
a m
IT-1 = <780.45
IT-2 = <775.95
IT-3 = 785.61
IT -4 = <776.08
IT-5 = 779.04
IT-6 = <776.90
IT-7 = 788.27
IT-BR= 781.39
IT-9 = Not Measured
Kubal-Furr & Associates
-Environmental Consultants-
Figure 2. Potentiometric Surface Map
Shallow Saprolite-August I, 2002
CNA Holdings, Inc.
Shelby. North Carolina
-
--
0
♦
--
Monitnr We!I Water-Level (ft msl)
Pie:zomeler
Outer ner Extraction Well
PEW Extraction Well
,,,-1ao/ w7.!!!::,:~~_:i.:n
Creek I Stream
Iii Building/ Structure
- ---- -
Scale in Feet
350
--
,.,).. .:r··--···
:·q
--
o~' \ '··, ..
\
' __.xr .
\ I
PZ-10 '"'u,n
\
I I
\
\
-- --
~,! \ ..
I
I
' ' \
\
• I •
700
I di
"'~'l.~;;"'
Kubal•Furr & Associates
-Environmental Consultants-
Figure 3. Potentiometric Surface Map
Deep Saprolite/Upper Bedrock-August I, 2002
CNA /foldings, Inc.
Shelhy. North Carolina
-
--
850.00
830.00
810.00
790.00
770.00
750.00
730.00
710.00
690.00
-810..,
I -
- --
A
D-27 -
821.51
·. D-35
821.20
D-56
821.28
Line of equal fluid potential (ft msl)
(,:Lashed whotre infarrad)
Potentiometric Surface
Inferred direction of ground-water
movement
= =
•
-
Bedrock
Saprolite
-
G-50
809.91
Screened Interval of Well
-- -- -
Horizontal Scale in Feet
0 400 SIXI
-- - - -
A' 850.00
830.00
810.00
790.00
770.00
750.00
730.00
710.00
690.00
Figure 4-Hydru,i;eolngic Cross-Sedion
A-A'-Aui:ust I, 2002 CNA l/o/di11,:s, Inc.
Shefhy, Noni, Cumli11a
- -
--
0
•
- -
Legend
Moni!orWeU water-level (fl msl)
Inner Tier Extraction Weh
,,.....-780/ WfJ!!~!~~
Creek I Stream
I.I Building I Structure
- --- - -
Scale in Feet
350
- -
',, <;> _ _,, ••• ,✓'>-· ---(
/"~ \.,,
1-':;' \ '
700
-
\
I
-
\
\
\
-- -
\
\
\
• I
\
Kubal-Furr & Associates
-Environmental Co11sultants-
-
Figure 5. Potcntiomctric Surface Map
Deep Saprolite/Uppcr Bedrock-August I, 2002
CNA Holdings, Inc.
Shelhy. Nunh Carolina
-
111111
0
iiiil
Monitor We/I Water.J....evel (ft ms()
Piezometer
♦ Outer Tier Extraction Well
PEW Extraction Well
Creek/ Stream
Ill Building I Structure
-------
Scale in Feet
0 350 700
-
\
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\
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\
\ '!;-.. <
-- --
\
\
\ \
\ \ ~ \
\
-----...
\
Kubal-Furr & Associates
-E11viro11mental Consultants-
Figure 6. Potentiomctric Surface Map
-
Deep Saprolitc/Upper Bedrock-November 7, 2002
CNA !!oldi11gs, Inc.
Shelby. North Carolina
-
----liiii iiil -- - -
850.00 A
-+:'::-::-::-::-::-::-::-::-::-::-::~~l~a:n~t A,~e::=======::::!1!::::::::::::-----------Wastewater Treatment Are,~-------------<0
830.00
• -D-27
822.77
810.00 D-35 -822.40
G-50
'809.31
790.00 D-56
822.43
770.00
750.00
730.00
710.00
690.00
-810,.I Line of equal fluid potential (ft msl) = Bedrock
(dashed where Werred) Horizontal Scale in Feet
Potentiometric Surface D Saprolile 0 400 80() •
Inferred direction of ground-water i Screened Interval of Well -movement "
-
• C ::;
~ • ~ e 'I-
-- - -
A' 850.00
830.00
810.00
790.00
770.00
750.00
730.00
710.00
690.00
Kubal-Furr & Associates
-Enviro11me11tal Consultants -
F"t;tur-e 7-Hydrc~eologic C~,;.Section
A-A'-November 7, 2002
CNA Haldin,:s, foe.
Shelby, N,i,.th Ct1mli1111
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Attachment 1
Operation and Maintenance Data
I July-December, 2002
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Kubal-Furr & Associates
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I INNER TIER
DAILY FLOW
I JULY.
~ II:1 1H rr:a II:.4 1H lli 1H 1H lH
•• 07/01/02 87 24 43 77 160 51 29 347 418
07/02/02 78 23 33 67 148 47 25 343 360
07/03/02 16 23 34 71 142 45 20 329 359
I 07/04/02 138 24 42 66 155 49 18 304 335
07/05/02 72 23 32 53 141 44 17 280 224
07/06/02 87 26 46 64 167 52 21 392 124
07/07/02 84 27 49 67 166 53 15 396 2 I 07/08/02 79 26 43 72 154 52 18 373 255
07/09/02 80 28 44 74 162 51 20 405 376
07/10/02 95 29 46 103 195 61 24 497 450
I 07/11/02 95 28 48 96 194 58 32 542 445
07/12/02 96 28 40 95 193 61 37 500 446
07/13/02 97 29 43 100 196 62 37 466 447
07/14/02 93 27 50 102 192 59 39 442 431
I 07/15/02 92 29 36 100 188 62 63 433 427
07/16/02 84 27 36 72 171 57 72 344 387
07/17/02 74 26 30 58 150 50 60 333 335
07/18/02 71 26 28 54 148 48 54 343 310
I 07/19/02 77 27 28 61 162 53 67 417 365
07120102 91 27 29 69 191 64 94 521 451
07/21/02 70 27 29 56 149 49 65 407 319
07/22/02 77 28 34 54 161 74 30 479 359
I 07/23/02 86 27 43 78 179 39 36 549 403
07/24/02 89 25 36 68 176 57 51 592 421
07/25/02 87 23 37 71 175 58 19 457 219
07/26/02 88 24 30 86 167 59 0 432 10
I 07/27/02 70 22 24 61 119 47 0 336 4
07/28/02 63 21 21 48 86 42 0 297 7
07/29/02 84 27 24 63 81 57 0 398 329
I 07/30/02 90 26 21 85 124 59 27 418 421
07/31/02 9•0 25 25 91 137 56 35 416 43
I AVG: 80 26 36 74 159 54 33 413 306
TOTAL: 2490 802 1104 2282 4929 1676 1025 12788 9482
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I 1
GROUNDWATER MONTHLY MONITORING:
RAINFALL DATA
JULY 2002 .
DATE INCHES/DAY
07/01/02 0.00
07/02/02 0.00
07/03/02 1.50
07/04/02 0.00
07/05/02 0.00
07/06/02 0.00
07/07/02 0.00
07/08/02 0.00
07/09/02 0.00
07/10/02 o.oo
07 / 11/02 0.00
07/12/02 0.00
07/13/02 0.00
07/14/02 0.00
07/15/02 0.00
07/16/02 0.00
07/17/02 o.oo
07/18/02 0.00
07/19/02 0.00
07/20/02 0.05
07 /21/02 0.00
07/22/02 0.10
07/23/02 0.60
07/24/02 0.00
07/25/02 0.45
07/26/02 0.10
07/27/02 0.00
07/28/02 o.oo
07/29/02 o.oo
07/30/02 0.00
07 /31/02 0.00
TOTAL 2.80
2
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I DAILY REFERENCE SHEET:
DATE: IT. EQ. PLT. DEC. DEC. WAS MIX MIX MIX NIT PHDS MIX F/M
I JULY. INF. TNK. SEP. LIQ LIQ LIQ ADD ADD LIQ WAS 5/DAY
2llll2 CQ.D.. CQ.D.. CQ.D.. CQ.D.. llS.. .ISS ~ fill fl:IQS GALS LEIS S.EL GALS ELM AYs..
4080 3230 1876 126 7.0 0 2 100 0 0.00
2 4350 4660 4320 488 400 10480 1804 147 20.4 0 0 100 202 0.21
I 3 4380 5510 1808 131 11.4 0 2 100 0 0.00
4 4240 3350 4790 398 200 12210 1638 114 22.2 0 0 100 202 0.26
5 4510 3690 1820 95 13.5 1 2 100 0 0.00 0.09
6 4270 5250 3620 416 260 12120 1608 147 27.0 0 0 100 202 0.20 0.13
I 7 8240 4370 1900 136 22.5 0 2 100 0 0.00 0.09
8 6440 5810 1532 128 22.0 0 0 100 202 0.00 0.09
9 5300 5150 4480 324 270 8800 1448 119 31.6 0 0 100 202 0.27 0.09
10 4050 4120 1920 114 16.3 1 2 100 0 0.00 0.09
I 11 4560 4660 4910 359 210 15530 2084 115 24.4 0 0 100 202 0.21 0.10
12 4460 3830 1895 125 16.5 2 100 0 0.00 0.10
13 4110 4150 3580 276 180 3120 1656 128 25.0 0 0 85 54 0,19 0.14
14 4620 3920 1876 117 15.2 1 2 100 0 0.00 0.08
15 4750 3720 4130 294 100 5150 2038 135 22.5 0 0 100 202 0,18 0.12
I 16 5180 4370 1738 115 14.0 0 50 0 0.00 0.07
17 4300 3990 3840 285 170 14440 1676 138 23.1 0 0 50 202 0.20 0.12
18 4480 3910 1506 116 13.1 2 50 0 0.00 0.08
19 5020 4300 4000 166 70 15510 1356 155 28.3 0 0 50 0 0.26 0.13
I 20 4890 3760 3290 256 148 2440 1984 150 17.0 0 1 90 67 0.15 0.12
21 4870 3480 2016 124 21.0 0 0 100 0 0.00 0.12
22 4060 3690 3810 257 100 14700 1184 84 13.3 2 80 202 0.29 0.14
23 4390 3870 1892 146 21.7 0 2 80 0 0.00 0.14
24 4050 3450 3510 243 180 15450 1096 126 32.7 0 0 40 202 0.28 0.14
I 25 4120 3410 1840 95 18.5 1 2 40 0 0.00 0.11
28 7790 3230 3300 242 100 13090 1940 140 26.8 0 0 40 202 0.15 0.14
27 7320 4680 1632 112 21.9 2 40 0 0.00 0.09
28 6990 4900 1600 132 32.9 0 0 40 0 0.00 0.09
I 29 8850 4850 3600 252 70 17270 1976 143 32.5 0 0 40 202 0.16 0.06
30 4460 6350 2156 75 12.5 2 50 0 0.00 0.06
31 4170 3690 4370 214 90 17430 1908 96 31.0 50 202 0.20 0.07
AVG: 5068 4244 3502 282 149 10455 1754 123.3 21.2 0 1 77 89 0.10
I MAX: 8850 6350 4910 488 400 17430 2156 155.0 32.9 1 2 100 202 0.29
MIN: 4050 3230 0 0 0 0 1096 75.0 7.0 0 0 40 0 0.00
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INNER TIER COMBINED INFLUENT #2 ITCI
PAGE NO.1 I JULY.2002
DATE: FLOW: PH: COD: TSS: TOC:
GPO pH ppm ppm ppm I 07/01/02 1236 5.3 4080 5
07/02/02 1124 5.3 4350 49 1530 I 07/03/02 1039 5.3 4380 48
07/04/02 1131 5.3 4240 14
07/05/02 886 5.3 4510 24
07/06/02 979 5.3 4270 13 I 07/07/02 859 5.3 8240 27
07/08/02 1072 5.2 6440 13
07/09/02 1240 5.3 5300 19 1440 I 07/10/02 1500 5.3 4050 15
07/11/02 1538 5.3 4560 6
07/12/02 1496 5.3 4460 7 I 07/13/02 1477 5.3 4110 12
07/14/02 1435 5.2 4620 7
07/15/02 1430 5.2 4750 5
07/16/02 1250 5.2 5180 11 I 07/17/02 1116 5.2 4300 22 1400
07/18/02 1082 5.2 4480 6
07/19/02 1257 5.2 5020 60 I 07/20/02 1537 5.3 4890 18
07/21/02 1171 5.3 4670 14
07/22/02 1296 5.3 4060 20 I, 07/23/02 1440 5.2 4390 16
07/24/02 1515 5.3 4050 20 1850
07/25/02 1146 5.2 4120 21 I 07/26/02 896 5.2 7790 11
07/27/02 683 5.2 7320 5
07/28/02 585 5.2 6990 10
07/29/02 1063 5.1 8850 9 I 07/30/02 1271 5.3 4460 11
07/31/02 918 5.2 4170 5 1880
AVG: 1183 5.3 5068 17 1620 I
MAX: 1538 5.3 8850 60 1880
MIN: 585 5.1 4050 5 1400 I
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I GROUNDWATER MONTHLY MONITORING:
INNER·TIER EQUALIZATION TANK: ITEQT
I PAGE NO. 2
JULY.2002
DATE: PH: COD: OT WATER ADDED
I pH ppm gal
07/01/02 6.9 3230
I 07/02/02 6.7 4860
07/03/02 6.9 5510
07/04/02 6.7 3350
07/05/02 7.1 3690
I 07/06/02 6.7 5250
07/07/02 7.1 4370
07/08/02 6.8 5810
I 07/09/02 6.7 5150
07/10/02 7.0 4120
07/11/02 6.7 4660
I 07/12/02 7.0 3830
07/13/02 6.8 3580
07/14/02 7.1 3920
I
07/15/02 6.7 3720
07/16/02 7.1 4370
07/17/02 6.7 3990
07/18/02 7.1 3910
I 07/19/02 7.1 4300 563
07/20/02 7.1 3760
07/21/02 7.1 3480
I 07/22/02 7.1 3690
07/23/02 7.2 3870
07/24/02 7.0 3450
I 07/25/02 7.0 3410
07/26/02 6.9 3230
07/27/02 7.0 4680
07/28/02 7.0 4900
,)I 07/29/02 6.9 4850 587
07/30/02 10.9 6350
07/31/02 7.1 3690
I AVG: 7.1 4225 575
MAX: · 10.9 6350 587
I MIN: 6.7 3230 563
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GROUNDWATER MONTHLY MONITORING: I
AFTER PLATE SEPARATOR BEFORE SBR:
PAGE NO. 3 I JULY.2002
DATE: PH: COD: TSS:
pH ppm ppm I
07/01/02
07/02/02 5.4 4320 8 I 07/03/02
07/04/02 5.4 4790 24
07/05/02
07/06/02 5.4 3620 40 I 07/07/02
07/08/02
07/09/02 5.9 4460 24 I 07/10/02
07/11/02 5.9 4910 32
07/12/02 I 07/13/02 5.9 3580 40
07/14/02
07/15/02 5.5 4130 4 I 07/16/02
07/17/02 5.4 3840 20
07/18/02
07/19/02 5.4 4000 32 I 07/20/02 5.6 3290 16
07/21/02
07/22/02 6.4 3810 16 I 07/23/02
07/24/02 5.5 3510 48
07/25/02 I 07/26/02 5.6 3300 24
07/27/02
07/28/02 II 07/29/02 5.6 3600 4
07/30/02
07/31/02 5.3 4370 36
AVG: 5.6 3969 25 I
MAX: 6.4 4910 48
MIN: 5.3 3290 4 I
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I GROUNDWATER MONTHLY MONITORING:
SBR MIXED LIQUOR: SBRML
I PAGE NO.4
JULY.2002 SETT. SLUDGE 5/DAY
DATE: PH: NH3N: PO4: DO: MLSS: MLVSS: SOLIDS: WASTED F/M: F/M:
I pH ppm ppm ppm ppm ppm ml/I gal ratio ratio
07/01/02 8.6 126 7.0 5.8 1876 100 0 0.00
I 07/02/02 8.6 147 20.4 3.8 1804 1336 100 202 0.21
07/03/02 8.3 131 11.4 3.7 1808 100 0 0.00
07/04/02 8.2 114 22.2 1.7 1636 100 202 0.26
07/05/02 8.3 95 13.5 3.0 1820 100 0 0.00 0.09
I 07/06/02 8.4 147 27.0 3.0 1608 100 202 0.20 0.13
07/07/02 8.4 136 22.5 2.9 1900 100 0 0.00 0.09
07/08/02 8.3 128 22.0 3.7 1532 100 0 0.00 0.09
I 07/09/02 8.3 119 31.6 3.6 1448 956 100 202 0.27 0.09
07/10/02 8.2 114 16.3 3.1 1920 100 0 0.00 0.09
07/11/02 8.3 115 24.4 3.0 2064 100 202 0.21 0.10
I 07/12/02 8.3 125 16.5 3.7 1895 100 0 0.00 0.10
07/13/02 8.4 128 25.0 3.5 1656 85 54 0.19 0.14
07/14/02 8.2 117 15.2 3.0 1876 100 0 0.00 0.08
I 07/15/02 8.3 135 22.5 2.8 2036 100 202 0.18 0.12
07/16/02 8.2 115 14.0 2.5 1736 1304 50 0 0.00 0.07
07/17/02 8.3 136 23.1 2.9 1676 50 202 0.20 0.12
07/18/02 8.2 116 13.1 2.8 1506 50 0 0.00 0.08
I 07/19/02 8.2 155 26.3 3.5 1356 50 202 0.26 0.13
07/20/02 8.3 150 17.0 2.6 1984 90 67 0.15 0.12
07/21/02 8.2 124 21.0 2.4 2016 100 0 0.00 0.12
I 07/22/02 8.2 84 13.3 2.6 1184 80 202 0.29 0.14
07/23/02 8.4 146 21.7 3.1 1892 1368 80 0 0.00 0.14
07/24/02 8.4 126 32.7 3.3 1096 40 202 0.28 0.14
I 07/25/02 8.5 95 18.5 3.2 1840 40 0 0.00 0.11
07/26/02 8.5 140 26.8 3.2 1940 40 202 0.15 0.14
07/27/02 8.5 112 21.9 2.4 1632 40 0 0.00 0.09
07/28/02 8.5 132 32.9 2.8 1600 40 0 0.00 0.09
I 07/29/02 8.3 143 32.5 2.8 1976 40 202 0.16 0.06
07/30/02 8.3 75 12.5 2.4 2156 1476 50 0 0.00 0.06
07/31/02 8.4 96 31.0 2.0 1908 50 202 0.20 0.07
I AVG: 8.3 123 21 3 1754 1288 77 89 0.10 0.10
MAX: 8.6 155 33 6 2156 1476 100 202 0.29 0.14
I MIN: 8.2 75 7 2 1096 956 40 0 0.00 0.06
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GROUNDWATER MONTHLY MONITORING: I
SBR EFFLUENT:(DECANT) #4 SBRE
PAGE NO. 5 I JULY.2002 WAS. NH3N PHOS.
DATE: FLOW: COD: TSS:TSS ADDED: ADDED:
GPD ppm ppm ppm gal lbs I
07/01/02 0 0 2
07/02/02 2643 468 400 10480 0 0 I 07/03/02 0 0 2
07/04/02 2542 4398 200 12210 0 0
07/05/02 0 1 2
07/06/02 2049 416 260 12120 0 0 I 07/07/02 0 0 2
07/08/02 0 0 0
07/09/02 2124 324 270 8800 0 0 I 07/10/02 0 1 2
07/11/02 1702 359 210 15530 0 0
07/12/02 0 1 2 I 07/13/02 2385 276 180 3120 0 0
07/14/02 0 1 2
07/15/02 2264 294 100 5150 0 0
07/16/02 0 1 2 I 07/17/02 1882 265 170 14440 0 0
07/18/02 0 1 2
07/19/02 1875 188 70 15510 0 0 I 07/20/02 2579 256 148 2440 0 1
07/21/02 0 0 0
07/22/02 1346 257 100 14700 1 2 I 07/23/02 0 0 2
07/24/02 2402 243 160 15450 0 0
07/25/02 0 1 2 I 07/26/02 1928 242 100 13090 0 0
07/27/02 0 1 2
07/28/02 0 0 0
07/29/02 1500 252 70 17270 0 0 I 07/30/02 0 2
07/31/02 1875 214 90 17430 1.0 1.0
AVG: 1003 563 169 11849 0 1 I
MAX: 2643 · 4398 400 17430 1 2
MIN: 0 188 70 2440 0 0 I • DID NOT PROCESS SBR.
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I GROUNDWATER MONTHLY MONITORING
INNER TIER CARBON FILTER EFFLUENT #8ITEF
I PAGE NO. 7
JULY.2002
DATE: PH: COD: TOC: TSS:
I pH ppm ppm ppm
07/01/02
I 07/02/02 8.5 446 20.5 230
07/03/02
07/04/02
07/05/02
I 07/06/02
07/07/02
07/08/02
I 07/09/02 8.1 297 19.9
07/10/02
07/11/02
I 07/12/02
07/13/02
07/14/02
I 07/15/02
07/16/02
07/17/02 8.2 310 15.0
07/18/02
I 07/19/02
07/20/02
07/21/02
I 07/22/02
07/23/02
07/24/02 8.2 234 22.0
I 07/25/02
07/26/02
07/27/02
07/28/02
I 07/29/02
07/30/02
07/31/02 8.2 246 14.5
I AVG: 8.2 307 18.4 230
MAX: 8.5 446 22.0 230
I MIN: 8.1 234 14.5 230
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MAINTENANCE ACTIVITIES-GROUNDWATER OPERABLE UNIT #1
INNER TIER SYSTEM
ACTION
DATE WELL# PROBLEM DATE ACTION MECHANIC
7/8/02 #9 LOW FLOW 7/8/02 PULLED PUMP ,CLEANED PROBE & ADJ. MAX&P.P.
10·
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-- -- - --------- - - - - -
~
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Quarterly O&M Plan Checldist-HNA Holdings, lnc./Shelby, NC
Outer Tier Well
OT-2R
OT-3
OT-4
OT-5
OT-6
OT-6A
OT-7
OT-8
Ground-Water
Treatment Sys.
Open Sample
Port
X
X
X
X
X
X
X
X
Energize
AS Blower
Y-V-1008
Energize Verify De-energize Close Sample
Pume Dlsch&!:QII Pume Port
X X X X
X X X X
X X X X
X X X X
X X X X
X X X X
X X X X
X X X X
Energize Energize Energize Energize
Transfer Pump Transfer Pump Transfer Pump Transfer Pump
Y-P-1007A Y..P..1007B Y-P-1008A Y-P-10088
Form Completed by: TONY BRYANT
Date: 7/8/02
Verify Heater Secure Well
Oe!ratlon Vault Commanu
X X
X X
X X
X X
X X BAD PUMP WAITING ON NEW PUMP
X X
X X
X X
Comment,;
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INNER TIER I DAILY FLOW
AUGUST. I
~ lI:1 1H. 1H 1H 1H 1H. II:Z lI:lt 1H
08/01/02 91 24 26 91 135 56 35 . 420 o I 08/02/02 73 23 29 58 114 47 31 331 304
08/03/02 81 25 42 84 137 51 35 387 376
08/04/02 84 25 37 83 139 51 39 343 397 I 08/05/02 76 23 34 71 130 43 38 93 351
08/06/02 83 23 32 71 134 42 47 24 396
08/07/02 87 23 44 68 120 41 55 68 333
08/08/02 86 23 35 71 127 38 55 60 o I 08/09/02 87 19 36 67 153 38 52 72 6
08/10/02 83 24 38 64 138 37 50 44 241
08111/02 81 21 31 70 142 37 51 45 388 I 08/12/02 75 21 36 61 130 33 45 301 356
08/13/02 58 20 31 73 137 34 46 333 379
08/14/02 101 21 26 78 140 34 46 339 106
08/15/02 83 20 21 68 141 34 48 340 353 I 08/16/02 82 20 15 78 140 35 47 343 418
08/17/02 81 19 15 63 153 34 48 345 419
08118/02 78 19 17 62 149 33 44 333 395
08/19/02 80 19 23 67 134 29 45 343 410 I 08/20/02 75 19 o 79 133 38 44 356 306
08/21/02 74 18 16 84 125 32 45 385 20
08/22/02 76 18 23 92 127 32 49 424 300
08/23/02 66 18 22 72 108 29 39 347 343 I 08/24/02 66 18 24 76 110 30 37 347 349
08/25/02 79 17 27 88 134 33 45 427 65
08/26/02 79 18 27 67 107 33 46 427 3
08/27/02 78 18 26 72 78 33 46 446 22 I 08/28/02 76 17 27 75 99 32 42 441 187
08/29/02 78 17 27 81 153 32 45 413 9
08/30/02 79 18 28 81 44 32 48 406 399
08/31/02 79 17 34 82 42 33 48 352 495 I
AVG: 79 20 27 74 124 37 45 301 262 I I TOTAL: 2455 625 849 2297 3853 1136 1391 9335 8126 I
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GROUNDWATER MONTHLY MONITORING:
RAINFALL DATA
AUG.2002
DATE INCHES/DAY
08/01/02 0.00
08/02/02 o.oo
08/03/02 0.00
08/04/02 0.00
08/05/02 0.00
08/06/02 o.oo
08/07/02 0.00
08/08/02 0.00
08/09/02 0.00
08/10/02 0.00
08/11/02 o.oo
08/12/02 0.00
08/13/02 o.oo
08/14/02 0.00
08/15/02 1.00
08/16/02 1.90
08/17/02 1.00
08/18/02 0.20
08/19/02 0.00
08/20/02 0.00
08/21/02 0.00
08/22/02 0.00
08/23/02 0.00
08/24/02 0.00
08/25/02 o.oo
08/26/02 0.00
08/27/02 0.00
08/28/02 0.00
08/29/02 0.05
08/30/02 0.40
08/31/02 0.30
TOTAL 4.85
1 3
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DAILY REFERENCE SHEET: I I
DATE: IT. EQ. PLT. DEC. DEC. WAS MIX MIX MIX NIT PHOS MIX F/M
AUG. INF. TNK. SEP. LIQ LIQ LIQ ADD ADD LIQ WAS 5/DAY I ~ gm. @Q. ~ ~ :rss.. .Di M!.SS till ~ GALS. ~-ill. !,Abli ELM Al/Si.
6830 4320 2044 136 24.5 0 0 50 0 0.00
2 7460 5800 2020 115 20.0 0 0 50 0 0.00 I 3 5570 4920 4410 200 70 5000 1760 132 23.0 0 0 50 100 0.22
4 4670 4430 2040 103 15.5 1 1 100 0 0.00
5 5300 4740 5190 186 80 8930 2020 131 26.5 0 0 100 121 0.23 0.09
6 4820 4670 2124 150 22.0 0 0 100 0 0.00 0.09
7 3690 4310 4470 180 40 4750 2084 114 19.0 100 100 0.19 0.13 I 8 6480 3860 1938 80 16.0 100 0 0.00 0.08
9 9660 4600 1768 110 27.0 0 0 100 0 0.00 0.08
10 8380 4030 4450 120 32 1896 180 37.0 0 0 80 0 0.23 0.08
11 4400 3710 2132 126 26.0 0 0 90 0 0.00 0.08 I 12 4380 4030 3040 151 38 16790 1852 114 21.5 0 0 100 202 0.15 0.08
13 3720 3440 2084 101 12.3 1 2 100 0 0.00 0.08
14 4840 3280 3800 113 50 13170 2144 125 28.4 0 0 100 202 0.16 0.11
15 8440 3970 1884 104 18.8 1 2 100 0 0.00 0.06 I 16 4810 •"4380 2032 121 30.0 0 0 100 0 0.00 0.06
17 5040 4900 3690 110 110 10290 1972 120 27.5 0 0 100 100 0.17 0.06
18 3600 4200 1956 100 16.0 1 1 100 0 0.00 0.06
19 4790 3540 4900 98 60 17960 2108 100 20.5 0 0 100 202 0.21 0.07
20 4870 3380 1516 95 12.0 2 100 0 0.00 0.07 I 21 6440 3400 4100 116 90 17590 1468 112 24.0 0 0 60 202 0.25 0.12
22 8180 4370 1692 95 12.5 1 2 60 0 0.00 0.09
23 4210 4150 1272 130 26.5 0 0 60 0 0.00 0.09
24 4310 3780 4510 117 24 14930 1440 147 27.3 0 0 60 202 0.28 0.11 I 25 4120 3920 1756 111 14.0 2 60 0 0.00 0.11
26 7160 4110 3610 105 40 16510 2224 147 29.3 0 0 60 202 0.14 0.08
27 6360 4650 1692 123 20.7 0 0 60 0 0.00 0.08
28 7020 3950 3990 69 24 16690 1900 120 17.0 2 60 202 0.19 0.12
29 8910 3960 2276 130 22.3 0 0 60 0 0.00 0.07 I 30 7710 5330 1172 133 22.8 0 0 60 0 0.00 0.07
31 4930 4810 3580 104 32 2092 150 22.0 0 0 100 0 0.15 0.07
AVG: 5706 4224 3683 111 46 10970 1876 121.1 21.9 0 81 59 0.08 I MAX: 9660 5800 5190 200 110 17960 2276 180.0 37.0 1 2 100 202 0.28
MIN: 3600 3280 0 0 0 0 1172 80.0 12.0 0 0 50 0 0.00
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14. I
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I INNER TIER COMBINED INFLUENT #2 ITCI
PAGE NO.1
I AUGUST.2002
DATE: FLOW: PH: COD: TSS: TOC:
GPD pH ppm ppm ppm
I 08/01/02 878 5.3 6830 15
08/02/02 1010 5.1 7460 13
I 08/03/02 1218 5.2 5570 6
08/04/02 1198 5.2 4670 4
08/05/02 859 8.1 5300 6
08/06/02 852 5.1 4820 10
I 08/07/02 839 5.1 3690 10 2460
08/08/02 495 5.0 6480 21
08/09/02 530 5.0 9660 10
I 08/10/02 719 5.0 8380 9
08/11/02 866 5.1 4400 6
08/12/02 1058 5.1 4360 10
I 08/13/02 1111 5.9 3720 8
08/14/02 891 5.0 4640 6 1440 *
08/15/02 1108 4.9 6440 9
I 08/16/02 1178 4.8 4810 4
08/17/02 1177 4.9 5040 5
08/18/02 1130 4.8 3600 4
08/19/02 1150 5.2 4790 2
I 08/20/02 1050 5.2 4870 9
08/21/02 799 5.1 6440 6 2200 *
08/22/02 1141 5.0 8180 12
I 08/23/02 1044 5.1 4210 8
08/24/02 1057 5.1 4310 10
08/25/02 915 5.2 4120 5
I 08/26/02 807 5.0 7160 11
08/27/02 819 5.1 6360 5
08/28/02 996 5.0 7020 8 3140
08/29/02 853 5.1 6910 13
I 08/30/02 1135 5.1 7710 8
08/31/02 1182 5.2 4930 5
I AVG: 970 5.2 5706 8 2310
MAX: 1218 8.1 9660 21 3140
MIN: 495 4.8 3600 2 1440
I • Sample out of holdtime due to equipment failure
the result is consistent with historical data from the site
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GROUNDWATER MONTHLY MONITORING: I INNER TIER EQUALIZATION TANK: ITEOT
PAGE NO.2
AUGUST.2002 I DATE: PH: COD: OT WATER ADDED
pH ppm gal
08/01/02 12.9 4320 I 08/02/02 12.6 5800
08/03/02 12.2 4920 563 I 08/04/02 11.7 4430
08/05/02 8.7 4740
08/06/02 7.0 4670
08/07/02 6.9 4310 375 1,
08/08/02 6.9 3860
08/09/02 6.8 3860
08/10/02 6.7 4030 I 08/11/02 7.1 3710
08/12/02 7.2 4030 563
08/13/02 7.2 3440 I 08/14/02 7.1 3280
08/15/02 7.3 3970
08/16/02 7.1 4380
08/17/02 7.0 4900 I 08/18/02 6.9 4200
08/19/02 6.8 3540
08/20/02 7.3 3380 I 08/21/02 7.5 3400
08/22/02 7.4 4370
08/23/02 7.4 4150 I 08/24/02 7.3 3780
08/25/02 7.5 3920
08/26/02 7.2 4110 563.0 I 08/27/02 7.2 4650
08/28/02 7.2 3950 563.0
08/29/02 7.2 3960
08/30/02 7.1 5330 I 08/31/02 7.0 4810
AVG: 7.9 4200 525 I MAX: 12.9 5800 563
MIN: 6.7 3280 375
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I GROUNDWATER MONTHLY MONITORING:
AFTER PLATE SEPARATOR BEFORE SBR:
PAGE NO. 3
I AUGUST.2002
DATE: PH: COD: TSS:
pH ppm ppm
I 08/01/02
08/02/02
I 08/03/02 7.0 4410 220
08/04/02
08/05/02 11.7 5190 164
08/06/02
I 08/07/02 9.1 4470 28
08/08/02
08/09/02
I 08/10/02 6.9 4450 24
08/11/02
08/12/02 6.3 3040 4
I 08/13/02
08/.14/02 6.4 3800 16
08/15/02
08/16/02
I 08/17/02 5.8 3690 44
08/18/02
08/19/02 6.4 4900 28
I 08/20/02
08/21/02 5.9 4100 32
08/22/02
I 08/23/02
08/24/02 6.0 4510 20
08/25/02
I 08/26/02 6.2 3610 48
08/27/02
08/28/02 5.9 3990 16
08/29/02
I 08/30/02
08/31/02 6.5 3580 40
I AVG: 6.9 4134 53
MAX: 11.7 5190 220
MIN: 5.8 3040 4
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GROUNDWATER MONTHLY MONITORING: I SBR MIXED LIQUOR: SBRML
PAGE NO.4
AUGUST.2002 SETT. SLUDGE 5/DAY I DATE: PH: NH3N: PO4: DO: MLSS: MLVSS: SOLIDS: WASTED F/M: F/M:
pH ppm ppm ppm ppm ppm min gal ratio ratio
08/01/02 8.3 136 24.5 3.0 2044 50 0 0.00 I
08/02/02 8.3 115 20.0 2.0 2020 50 0 0.00
08/03/02 8.4 132 23.0 2.0 1760 50 100 0.22 I 08/04/02 8.5 103 15.5 2.3 2040 100 0 0.00
08/05/02 8.6 131 26.5 2.5 2020 100 121 0.23 0.09
08/06/02 8.4 150 22.0 2.4 2124 1508 100 0 0.00 0.09
08/07/02 8.4 114 19.0 2.6 2084 100 100 0.19 0.13 I 08/08/02 8.4 80 16.0 2.5 1936 100 0 0.00 0.08
08/09/02 8.4 110 27.0 3.2 1768 100 0 0.00 0.08
08/10/02 8.5 180 37.0 2.7 1696 80 0 0.23 0.08 I 08/11/02 8.5 126 26.0 3.1 2132 90 0 0.00 0.08
08/12/02 8.3 114 21.5 3.8 1852 100 202 0.15 0.08
08/13/02 8.2 101 12.3 3.5 2084 1484 100 0 0.00 0.08 I 08/14/02 8.2 125 28.4 4.6 2144 100 202 0.16 0.11
08/15/02 8.2 104 16.6 3.2 1884 100 0 0.00 0.06
08/16/02 8.2 121 30.0 4.5 2032 100 0 0.00 0.06
08/17/02 8.3 120 27.5 3.8 1972 100 100 0.17 0.06 I 08/18/02 8.2 100 16.0 4.0 1956 100 0 0.00 0.06
08/19/02 8.3 100 20.5 4.9 2108 100 202 0.21 0.07
08/20/02 8.3 95 12.0 3.8 1516 1152 100 0 0.00 0.07 I 08/21/02 8.4 112 24.0 4.8 1468 60 202 0.25 0.12
08/22/02 8.3 95 12.5 4.1 1692 60 0 0.00 0.09
08/23/02 8.4 130 26.5 4.0 1272 60 0 0.00 0.09 I 08/24/02 8.4 147 27.3 4.4 1440 60 202 0.28 0.11
08/25/02 8.4 111 14.0 3.3 1756 60 0 0.00 0.11
08/26/02 8.3 147 29.3 4.6 2224 60 202 0.14 0.08 I 08/27/02 8.3 123 20.7 3.9 1692 1256 60 0 0.00 0.08
08/28/02 8.3 120 17.0 3.9 1900 60 202 0.19 0.12
08/29/02 8.4 130 22.3 4.3 2276 60 0 0.00 0.07
08/30/02 8.3 133 22.8 5.5 1172 60 0 0.00 0.07 1, 08/31/02 8.3 150 22.0 4.4 2092 100 0 0.15 0.07
AVG: 8.3 121 22 4 1876 1350 81 59 0.08 0.09 I MAX: 8.6 180 37 6 2276 1508 100 202 0.28 0.13
MIN: 8.2 80 12 2 1172 1152 50 0 0.00 0.06
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I GROUNDWATER MONTHLY MONITORING:
SBR EFFLUENT:(DECANT) #4 SBRE
PAGE NO. 5
I AUGUST.2002 WAS. NH3N PHOS.
DATE: FLOW: COD: TSS: TSS ADDED: ADDED:
GPO ppm ppm ppm gal lbs
I 08/01/02 0 0 0
08/02/02 0 0 0
I 08/03/02 2288 200 70 5000 0 0
08/04/02 0 1
08/05/02 1718 186 80.0 8930 0 0
08/06/02 0 0 0
I 08/07/02 2039 180 40 4750 1 1
08/08/02 0 1
08/09/02 0 0 0
I 08/10/02 1932 120 32 0 0
08/11/02 0 0 0
08/12/02 1620 151 36 16790 0 0
I 08/13/02 0 1 2
08/14/02 1501 113 50 13170 0 0
08/15/02 0 2
08/16/02 0 0 0 I 08/17/02 2246 110 110 10290 0 0
08/18/02 0 1
08/19/02 2513 98 60 17960 0 0
I 08/20/02 0 1 2
08/21/02 2288 116 90 17590 0 0
08/22/02 0 1 2
I 08/23/02 0 0 0
08/24/02 2465 117 24 14930 0 0
08/25/02 0 1 2
I 08/26/02 2121 105 40 16510 0 0
08/27/02 0 0 0
08/28/02 1875 69 24 16690 1 2
08/29/02 0 0 0
I 08/30/02 0 0 0
08/31/02 2043 104 40.0 0.0 0.0
I AVG: 860 128 54 12965 0 1
MAX: 2513 200 110 17960 2
MIN: 0 69 24 4750 0 0
I • DID NOT PROCESS SBR .
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GROUNDWATER MONTHLY MONITORING I INNER TIER CARBON FILTER EFFLUENT #8ITEF
PAGE NO. 7
AUGUST.2002 I DATE: PH: COD: TOC: TSS:
pH ppm ppm ppm
08/01/02 I 08/02/02
08/03/02
08/04/02 I 08/05/02
08/06/02
08/07/02 8.4 155 12.9 100 I 08/08/02
08/09/02
08/10/02 I 08/11/02
08/12/02
08/13/02 I 08/14/02 8.4 133 18.8
08/15/02
08/16/02
08/17/02 I 08/18/02
08/19/02
08/20/02 I 08/21/02 8.6 112 16.6
08/22/02
08/23/02 I 08/24/02
08/25/02
08/26/02
08/27/02 I 08/28/02 8.6 103 46.4
08/29/02
08/30/02 I 08/31/02
AVG: 8.5 126 23.7 100 I MAX: 8.6 155 46.4 100
MIN: 8.4 103 12.9 100
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MAINTENANCE ACTIVITIES-GROUNDWATER OPERABLE UNIT #1
INNER TIER SYSTEM
ACTION
DATE WELL# PROBLEM DATE ACTION MECHANIC
8/6/02 #7 LOW FLOW 8/6/02 CHANGED BLADDER MAX&P.P.
8/8/02 #8 LOW FLOW 8/8/02 CHANGED BLADDER MAX&P.P.
8/14/02 #9 LOW FLOW 8/14/02 ADJUSTED CONTROLS MAX&P.P.
8/22/02 #9 LOW FLOW 8/22/ ADJUSTED CONTROLS MAX&P.P.
3
21
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INNER TIER I DAILY FLOW
SEPT. I
~ lI:1 1H 1H 1H 1H II:!!. 1H II:!!. 1H.
09/01/02 76 16 33 81 39 31 48 314 94 I 09/02102 77 17 28 81 0 32 50 274 0
09/03/02 78 16 24 67 34 8 51 0 428
09/04/02 73 17 23 78 178 0 47 0 460 I 09/05/02 77 15 21 84 218 0 47 347 495
09/06/02 76 16 22 90 71 0 49 194 509
09/07/02 77 15 22 90 0 0 49 188 508
09/08102 76 16 17 87 0 0 47 168 497 I 09/09/02 76 15 14 88 1 0 46 176 508
09/10/02 76 15 12 78 206 0 47 318 511
09/11/02 75 15 11 78 234 0 50 329 515 I 09/12/02 74 14 12 74 283 0 48 319 501
09/13/02 77 15 11 74 282 0 52 327 507
09/14/02 74 18 13 74 259 0 49 322 491
09/15/02 75 11 15 79 237 0 49 310 473 I 09/16/02 75 14 34 170 238 0 48 321 479
09/17/02 69 14 21 40 211 0 44 310 15
09/18/02 75 14 11 20 215 16 46 322 0
09/19/02 74 15 5 20 223 35 47 333 432 I 09/20/02 75 14 5 22 228 36 50 338 492
09/21/02 74 14 23 132 213 38 50 62 485
09/22/02 74 15 27 56 211 29 50 0 467
09/23/02 74 14 33 30 208 24 53 334 474 I 09/24/02 84 14 30 39 189 41 50 365 480
09/25/02 62 14 31 40 197 33 49 358 457
09/26/02 74 14 104 80 210 34 54 361 464
09/27/02 76 15 151 223 220 34 56 361 249 I 09/28/02 71 14 41 49 126 31 54 344 0
09/29/02 73 14 36 46 302 33 56 361 0
09/30/02 71 14 33 45 192 32 54 364 0 I
AVG: 75 15 29 74 174 16 50 271 366 I TOTAL: 2238 444 863 2215 5225 487 1490 8120 10991
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•
GROUNDWATER MONTHLY MONITORING:
RAINFALL DATA
SEPT.2002
DATE INCHES/DAY
09/01/02 o.oo
09/02/02 0.00
09/03/02 0.00
09/04/02 0.00
09/05/02 0.00
09/06/02 0.00
09/07/02 0.00
09/08/02 0.00
09/09/02 0.00
09/10/02 0.00
09/11/02 0.00
09/12/02 0.00
09/13/02 0.05
09/14/02 2.00
09/15/02 1.00
09/16/02 0.60
09/17/02 0.00
09/18/02 o.oo
09/19/02 0.00
09/20/02 o.oo
09/21/02 1.00
09/22/02 0.10
09/23/02 0.00
09/24/02 0.00
09/25/02 0.40
09/26/02 1.20
09/27/02 0.15
09/28/02 0.00
09/29/02 0.00
09/30/02 0.00
0.00
TOTAL 6.50
23
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DAILY REFERENCE SHEET: I DATE: IT. EQ. PLT. DEC. DEC. WAS MIX MIX MIX NIT PHOS MIX F/M
SEPT. INF. TNK. SEP. LIQ LIQ LIQ ADD . ADD LIQ WAS ~, 2l!l!2. coo. coo. coo. coo. :rss. ..ISS MUS. MIT ~ GALS LliS S.EL GALS ELM
1 4310 4440 2112 115 19.0 1 1 90 0 0.00
2 5850 4380 2416 150 27.0 0 0 110 0 0.00
3 :5590 4600 5030 107 26 16020 1168 153 30.5 0 0 60 202 0.38 I 4 4340 4400 1506 115 17.0 0 2 60 0 0.00
5 3550 4320 3770 109 20 18600 2046 140 30.0 0 0 100 202 0.16 0.11
6 4290 3750 1328 111 22.4 0 0 100 0 0.00 0.11
7 3780 3860 4100 123 6 28680 2292 . 114 16.3 2 100 202 0.16 0.14 I 8 3790 3490 2172 110 10.2 0 2 100 0 0.00 0.06
8 4540 2870 3180 80 20 6520 2464 107 20.4 0 0 100 202 0.11 0.09
10 3900 2720 2516 90 16.0 2 100 0 0.00 0.05
11 4300 3470 3000 107 28 16930 1400 107 27.2 1 2 100 202 0.19 0.09
12 3510 :l82o 1960 110 30.0 0 0 50 0 0.00 0.06 I 13 4020 3140 2860 77 16 21700 1312 122 30.5 0 0 50 202 0.19 0.10
14 4410 4000 2528 115 22.0 0 0 50 0 0.00 0.06
15 5000 3780 3650 96 60 13160 2460 100 19.0 1 1 100 202 0.13 0.10
16 4050 3930 1464 123 21.5 0 0 100 0 0.00 0.06 I 17 3560 3530 3720 99 6 14240 2480 140 22.1 0 0 100 202 0.13 0.09
16 6560 3960 1846 60 10.0 2 100 0 0.00 0.05
19 8900 5590 1952 100 21.4 0 0 90 0 0.00 0.05
20 4650 5350 3790 126 40 3300 2048 140 44,0 0 0 90 202 0.16 0.06 I 21 3590 4100 2552 110 30.0 1 0 110 0 0.00 0.06
22 3470 4180 4630 107 56 328 2332 164 30.0 0 0 120 121 0.18 0.07
23 4680 3540 1416 146 29.3 0 0 120 0 0.00 0.07
24 5120 4190 4380 104 32 10540 2588 132 27.0 0 0 100 202 0,15 0.10
25 4320 3760 1928 126 15.0 0 2 BO 0 0.00 0.07 I 26 4350 3280 2910 BB 24 20350 2288 126 27.5 0 0 BO 202 0.11 0.09
27 4470 3270 1960 104 20.1 2 BO 0 0.00 0.05
28 5370 3060 3160 85 24 4960 2028 136 35.6 0 0 100 202 0.14 0.08
29 6270 3400 2172 116 20.0 0 2 100 0 0.00 0.05 I 30 5810 3960 3830 119 20 24160 1400 110 30.3 0 0 60 202 0.24 0.10
31
AVG: 4678 3873 3251 89 25 12592 2005 120.4 24.1 0 90 92 0.08
MAX: 8900 5590 5030 126 80 28660 2588 164.0 44.0 1 2 120 202 0.38 I MIN: 3470 2720 0 0 0 0 1168 80.0 10.0 0 0 50 0 0.00
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I INNER TIER COMBINED INFLUENT #2 ITCI
PAGE NO.1
I SEPT.2002
DATE: FLOW: PH: COD: TSS: TOC:
GPO pH ppm ppm ppm
I 09/01/02 732 5.1 4310 2
09/02/02 559 5.1 5850 14
09/03/02 706 5.1 5590 4
I 09/04/02 876 5.1 4340 5
09/05/02 1304 5.1 3550 7 1180 •
09/06/02 1027 5.1 4290 6
I 09/07/02 949 5.1 3780 4
09/08/02 908 5.1 3790 5
09/09/02 924 5.1 4540 5
09/10/02 1263 5.0 3900 4
I 09/11/02 1307 5.1 4300 4 1200 •
09/12/02 1325 5.2 3510 1
09/13/02 1345 5.1 4020 4
I 09/14/02 1300 5.1 4410 5
09/15/02 1249 5.1 5000 4
09/16/02 1379 5.1 4050 3
I 09/17/02 724 5.1 3560 10 1270
09/18/02 724 5.1 6560 3
09/19/02 1184 5.0 8900 7
09/20/02 1260 5.1 4650 9 I 09/21/02 1091 5.2 3590 7
09/22/02 929 5.1 3470 11
09/23/02 1244 5.0 4680 10
I 09/24/02 1292 5.2 5120 7 1210
09/25/02 1241 5.2 4320 5
09/26/02 1395 5.1 4350 4
I 09/27/02 1385 5.2 4470 8
09/28/02 730 5.2 5370 5
09/29/02 921 5.0 6270 1
I 09/30/02 805 5.1 5810 8
AVG: 1069 5.1 4678 6 1215
I MAX: 1395. 5.2 8900 14 1270
MIN: 559 5.0 3470 1 1180
I • Sample out of holdlime due to equipment failure
the result is consistent with historical data from the site
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GROUNDWATER MONTHLY MONITORING: I INNER TIER EQUALIZATION TANK: ITEQT
PAGE NO. 2
SEPT.2002 I DATE: PH: COD: OT WATER ADDED
pH ppm gal
09/01/02 7.1 4440 I 09/02/02 7.0 4380
09/03/02 6.8 4800
09/04/02 6.9 4400 I 09/05/02 6.9 4320
09/06/02 6.9 3750
09/07/02 7.0 3860 I 09/08/02 7.0 3490
09/09/02 6.9 2870
09/10/02 7.0 2720 I 09/11/02 6.7 3470 75
09/12/02 7.0 3620
09/13/02 7.0 3140
09/14/02 7.0 4000 I 09/15/02 6.9 3780
09/16/02 7.0 3930
09/17/02 6.9 3530 I 09/18/02 6.9 3980
09/19/02 7.0 5590
09/20/02 6.9 5350 I 09/21/02 7.1 4100
09/22/02 7.0 4180
09/23/02 7.2 3540
09/24/02 7.0 4190 187 I 09/25/02 7.1 3760
09/26/02 7.1 3280 76
09/27/02 7.2 3270 I 09/28/02 7.1 3080
09/29/02 7.1 3400
09/30/02 6.9 3960 563 I
AVG: 7.0 3873 225 I MAX: 7.2 5590 563
MIN: 6.7 2720 75
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I GROUNDWATER MONTHLY MONITORING:
AFTER PLATE SEPARATOR BEFORE SBR:
PAGE NO. 3
I SEPT.2002
DATE: PH: COD: TSS:
pH ppm ppm
I 09/01/02
09/02/02
09/03/02 5.6 5030 8
I 09/04/02
09/05/02 5.6 3770 12
09/06/02
I 09/07/02 5.7 4100 8
09/08/02
09/09/02 6.2 3180 16
I 09/10/02
09/11/02 6.2 3000 32
09/12/02
09/13/02 5.7 2860 8
I 09/14/02
09/15/02 5.6 3650 28
09/16/02
I 09/17/02 5.7 3720 4
09/18/02
09/19/02
I 09/20/02 5.6 3790 32
09/21/02
09/22/02 6.5 4630 25
09/23/02
I 09/24/02 6.2 4380 16
09/25/02
09/26/02 5.8 2910 16
I 09/27/02
09/28/02 5.7 3160 40
09/29/02
I 09/30/02 5.6 3830 16
I AVG: 5.8 3715 19
MAX: 6.5 5030 40
MIN: 5.6 2860 4
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GROUNDWATER MONTHLY MONITORING: I SBR MIXED LIQUOR: SBRML
PAGE NO.4
SEPT.2002 SETT. SLUDGE 5/DAY I DATE: PH: NH3N: PO4: DO: MLSS: MLVSS: SOLIDS: WASTED F/M: F/M:
pH ppm ppm ppm ppm ppm ml/I gal ratio ratio
09/01/02 8.2 115 19.0 3.6 2112 90 0 0.00 I 09/02/02 8.2 150 27.0 3.3 2416 110 0 0.00
09/03/02 8.3 153 30.5 5.6 1168 836 60 202 0.38
09/04/02 8.3 115 17.0 4.2 1508 60 0 0.00 I 09/05/02 8.1 140 30.0 4.9 2048 100 202 0.16 0.11
09/06/02 8.1 111 22.4 1.4 1328 100 0 0.00 0.11
09/07/02 8.1 114 16.3 1.7 2292 100 202 0.16 0.14 I 09/08/02 8.4 110 10.2 3.7 2172 100 0 0.00 0.06
09/09/02 8.3 107 20.4 4.5 2464 100 202 0.11 0.09
09/10/02 8.1 90 18.0 3.6 2516 1852 100 0 0.00 0.05 I 09/11/02 8.2 95 27.2 4.4 1400 100 202 0.19 0.09
09/12/02 8.2 110 30.0 3.6 1960 50 0 0.00 0.06
09/13/02 8.2 122 30.5 4.9 1312 50 202 0.19 0.10
09/14/02 8.1 115 22.0 2.8 2528 50 0 0.00 0.08 I 09/15/02 8.1 100 19.0 3.8 2480 100 202 0.13 0.10
09/16/02 8.2 123 21.5 4.3 1464 100 0 0.00 0.06
09/17/02 8.2 140 22.1 3.9 2480 1976 100 202 0.13 0.09 I 09/18/02 8.1 80 10.0 4.4 1848 100 0 0.00 0.05
09/19/02 8.1 100 21.4 5.1 1952 90 0 0.00 0.05
09/20/02 8.2 140 44.0 3.7 2048 90 202 0.16 0.06 I 09/21/02 8.2 110 30.0 3.9 2552 110 0 0.00 0.06
09/22/02 8.2 164 30.0 4.4 2332 120 121 0.18 0.07
09/23/02 8.3 146 29.3 3.4 1416 120 0 0.00 0.07
09/24/02 8.3 132 27.0 3.9 2588 1908 100 202 0.15 0.10 I 09/25/02 8.2 126 15.0 4.3 1928 80 0 0.00 0.07
09/26/02 8.2 126 27.5 4.6 2288 80 202 0.11 0.09
09/27/02 8.2 104 20.1 3.8 1960 80 0 0.00 0.05 I 09/28/02 8.3 136 35.6 4.6 2028 100 202 0.14 0.08
09/29/02 8.2 116 20.0 3.6 2172 100 0 0.00 0.05
09/30/02 8.1 110 30.3 5.8 1400 60 202 0.24 0.10 I
AVG: 8.2 120 24 4 2005 1643 90 92 0.08 0.08 I MAX: 8.4 164 44 6 2588 1976 120 202 0.38 0.14
MIN: 8.1 80 10 1168 836 50 0 0.00 0.05
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I GROUNDWATER MONTHLY MONITORING:
SBR EFFLUENT:(DECANT) #4 SBRE
PAGE NO. 5
I SEPT.2002 WAS. NH3N PHOS.
DATE: FLOW: COD: TSS:TSS ADDED: ADDED:
GPD ppm ppm ppm gal lbs
I 09/01/02 o 1
09/02/02 o o o
09/03/02 2083 107 28 16020 o o
I . 09/04/02 o o 2
09/05/02 2466 109 20.0 18600 o o
09/06/02 o o o
I 09/07/02 1962 123 8 28660 1 2
09/08/02 o o 2
09/09/02 2372 80 20 6520 o o
I 09/10/02 o 1 2
09/11/02 1996 107 28 18930 1 2
09/12/02 o o o
09/13/02 1659 77 16.0 21700 o o
I 09/14/02 o o o
09/15/02 2175 96 80 13160 1 1
09/16/02 o o o ·• 09/17/02 2055 99 8 14240 o o
09/18/02 o 1 2
09/19/02 o o o
I 09/20/02 2063 126 40 3300 o o
09/21/02 o 1 o
09/22/02 2276 107 56 328 o o
09/23/02 o o o I 09/24/02 1875 104 32 10540 o o
09/25/02 o o 2
09/26/02 2369 88 24 20350 o o
I 09/27/02 o 1 2
09/28/02 2040 85 24 4960 o o
09/29/02 o o 2
I 09/30/02 2160 119 20.0 24160 o o
I AVG: 985 102 29 14391 o 1
MAX: 2466 126 80 28660 1 2
MIN: o 77 8 328 o o
• DID NOT PROCESS SBR.
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GROUNDWATER MONTHLY MONITORING I INNER TIER CARBON FILTER EFFLUENT #8ITEF
PAGE NO. 7
SEPT.2002 I DATE: PH: COD: TOC: TSS:
pH ppm ppm ppm
09/01/02 I 09/02/02
09/03/02
09/04/02 I 09/05/02 8.3 126 11.9 16
09/06/02
09/07/02 I 09/08/02
09/09/02
09/10/02
09/11/02 8.3 107 13.9 I 09/12/02
09/13/02
09/14/02 I 09/15/02
09/16/02
09/17/02 8.3 95 14.2 I 09/18/02
09/19/02
09/20/02 I 09/21/02
09/22/02
09/23/02
09/24/02 8.3 197 11.9 I 09/25/02
09/26/02
09/27/02 I 09/28/02
09/29/02
09/30/02 I
AVG: 8.3 131 13.0 16
MAX: 8.3 197 14.2 16 I MIN: 8.3 95 11.9 16
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MAINTENANCE ACTIVITIES-GROUNDWATER OPERABLE UNIT #1
INNER TIER SYSTEM
ACTION
DATE WELL# PROBLEM DATE ACTION MECHANIC
913102 #5 LOW FLOW 913102 REPLACED BLADDER & AIR LINE P.P.&MAX
913102 #6 LOW FLOW 913102 PULLED PUMP ONLY 8" WATER IN WELL P.P. & MAX
913102 #9 LOW FLOW 913/02 RESET CONTROLS P.P. &MAX
914102 #8 LOW FLOW 914102 CHANGED METER P.P. &MAX
9110102 #5 LOW FLOW 9110102 REPLACED AIR LINE P.P. &MAX
9110102 #8 LOW FLOW 9110102 REPLACE WATER LINE PUMP EXHAUSTER P.P. &MAX
3
31
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INNER TIER I DAILY FLOW
OCT. I
~ !I:1 1H I.H 1H 1H 1H II:Z II:!! lH
10/01/02 72 13 34 51 206 33 56 375 15 I 10/02/02 68 14 35 34 208 33 0 372 531
10/03/02 76 13 34 51 198 27 118 370 273
10/04/02 74 15 34 45 200 41 63 368 515 I 10/05/02 69 13 32 44 197 33 60 508 486
10/06/02 71 14 32 47 194 34 62 552 483
10/07/02 24 8 10 16 55 13 21 176 150 I 10/08/02 75 14 35 64 186 34 39 592 488
10/09/02 72 14 33 47 212 134 44 580 493
10/10/02 73 14 32 62 229 30 51 581 493
10/11/02 75 13 33 68 234 40 56 572 490 I 10/12/02 74 14 37 231 74 34 67 589 123
10/13/02 75 12 37 62 235 34 166 579 0
10/14/02 79 15 33 81 242 34 11 78 456
10/15/02 78 14 67 131 129 33 11 0 550 I 10/16/02 78 14 100 189 0 33 65 0 559
10/17/02 77 13 40 46 140 35 45 354 585
10/18/02 79 14 31 49 167 34 50 389 598
10/19/02 79 14 42 60 172 35 68 376 594 I 10/20/02 78 14 38 48 177 34 67 377 582
10/21/02 79 14 36 66 171 36 67 389 600
10/22/02 80 14 36 90 166 36 65 389 599
10/23/02 82 14 35 92 163 36 68 369 587 I 10/24/02 83 14 35 93 158 35 68 363 564
10/25/02 84 15 35 95 166 37 71 375 570
10/26/02 86 14 33 110 164 36 72 365 570
10/27/02 80 15 28 97 155 36 71 323 466 I 10/28/02 85 15 40 95 160 38 71 296 359
10/29/02 84 14 84 95 162 37 71 292 312
10/30/02 85 15 49 82 164 37 72 267 310 I 10/31/02 80 15 27 101 162 38 68 157 330.
AVG: 76 14 39 79 169 37 61 367 443 I TOTAL: 2354 428 1207 2442 5246 1160 1884 11373 13731
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GROUNDWATER MONTHLY MONITORING:
RAINFALL DATA
OCT 2002 .
DATE INCHES/DAY
10/01/02 0.00
10/02/02 0.00
10/03/02 0.00
10/04/02 o.oo
10/05/02 0.00
10/06/02 o.oo
10/07/02 0.00
10/08/02 o.oo
10/09/02 0.00
10/10/02 0.00
10/11/02 0.00
10/12/02 0.00
10/ 13/02 0.05
10/14/02 2.00
10/15/02 1.00
10/16/02 0.60
10/17/02 0.00
10/18/02 0.00
10/19/02 0.00
10/20/02 0.00
10/21/02 1.00
10/22/02 0.10
10/23/02 0.00
10/24/02 0.00
10/25/02 0.40
10/26/02 1.20
10/27/02 0.15
10/28/02 0.00
10/29/02 o.oo
10/30/02 0.00
10/31/02 0.00
TOTAL 6.50
33
I
DAILY REFERENCE SHEET: I
DATE: IT. EQ. PLT. DEC. DEC. WAS MIX MIX MIX NIT PHOS MIX FIM
OCT. INF. TNK. SEP. LIQ LIQ LIQ ADD ADD LIQ WAS s:-1 ~ @12. @12. ~ ~ :rss. ..r.ss. M.bSl> HIT ~ ~ ~ ~ GALS ELM
1 7500 4050 1940 80 19.6 2 60 0 0.00
2 8720 4080 3370 102 20 21280 1620 115 28.0 0 0 70 80 0.18 I 3 3920 3800 1668 96 20.0 1 2 70 0 0.00
4 5_800 4050 4350 198 24 5820 2424 120 34.7 0 0 80 80 0.16
5 1040 1180 2920 105 25.0 1 0 110 0 0.00 0.07
6 3940 3410 3400 89 40 12390 2084 127 25.8 0 0 80 202 0.15 0.10
7 4560 3980 2312 112 16.1 0 2 60 0 0.00 0.06 I 8 3200 1844 122 30.1 0 0 60 0 0.00 0.06
9 3710 3780 3880 110 32 18480 1436 129 30.3 0 0 50 202 0.24 0.08
10 4320 3340 2236 155 32.0 0 0 50 0 0.00 0.08
11 3300 3460 3440 116 24 17420 1332 108 21.3 0 0 50 202 0.23 0.09 I 12 4490 3890 2532 89 12.0 100 0 0.00 0.09
13 6900 4820 4480 135 24 3268 2516 110 56.0 0 0 100 100 0.16 0.13
14 3510 4890 2280 105 36.4 0 0 100 0 0.00 0.08
15 3730 4300 1680 113 39.4 0 0 100 0 0.00 0.08 I 18 3930 3750 3740 140 58 20660 2488 103 35.5 1 2 100 202 0.13 0.06
17 4860 4110 2448 132 35.0 0 0 100 0 0.00 0.06
18 3450 3530 2260 155 36 22520 2308 115 29.4 0 0 100 202 0.09 0.04 ·
19 2900 2800 2776 68 23.4 1 2 100 0 0.00 0.04
20 3400 3370 2680 139 40 20160 2316 103 25.3 0 0 100 202 0.10 0.06 I 21 3680 3870 3276 96 21.5 2 100 0 0.00 0.04
22 3950 2980 3850 143 36 12450 2788 108 28.3 0 0 100 202 0.12 0.06
23 3810 3280 2872 90 18.8 1 2 100 0 0.00 0.04
24 3140 4460 2490 112 20 15600 2832 108 30.6 0 0 100 202 0.08 0.06 I 25 3860 3250 2880 76 16.1 1 2 100 0 0.00 0.04
28 4620 4560 4400 180 44 18420 2720 110 25.0 0 0 100 202 0.14 0.07
27 4680 4170 2856 95 19.5 0 0 100 0 0.00 0.04
26 3280 4180 3630 157 40 18260 2612 115 21.8 0 0 100 202 0.12 0.07
29 4710 3930 2904 96 14.2 1 2 100 0 0.00 0.05 I 30 3870 3260 3430 101 32 20780 2840 125 25.8 0 0 100 202 0.11 0.07
31 3040 2570 2692 82 15.0 130 0 0.00 0.05
AVG: 4154 3679 3075 116 29 14096 2386 107.4 26.2 0 90 80 0.06 I MAX: 7500 4890 4480 198 56 22520 3276 155.0 56.0 1 2 130 202 0.24
MIN: 1040 1180 D 0 0 0 1332 76.0 12.0 0 0 50 0 0.00
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12/20/02 I
34 I
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INNER TIER COMBINED INFLUENT #2 ITCI
I PAGE NO.1
OCT.2002
DATE: FLOW: PH: COD: TSS: TOC:
I GPD pH ppm ppm ppm
10/01/02 855 5.0 7500 3
I 10/02/02 1295 5.1 6720 7 2160
10/03/02 1180 5.2 3920 13
10/04/02 1355 5.2 5800 5
10/05/02 1442 5.2 1040 20
I 10/06/02 1489 5.3 3940 17
10/07/02 473 5.3 4560 9
10/08/02 1527 NA NA NA
I 10/09/02 1629 5.3 3710 6 1380
10/10/02 1565 5.3 4320 6
10/11/02 1581 5.3 3300 7
I 10/12/02 1243 5.3 4490 8
10/13/02 1200 5.2 6900 15
10/14/02 1026 5.2 3510 20
I 10/15/02 1013 5.2 3730 9
10/16/02 1038 5.2 3930 13 1060
10/17/02 1335 5.3 4860 11
10/18/02 1411 5.4 3450 17
I 10/19/02 1440 5.5 2900 14
10/20/02 1425 5.5 3400
10/21/02 1458 5.4 3680 6
I 10/22/02 1475 5.3 3950 6 1230
10/23/02 1446 5.3 3810 6
10/24/02 1593 5.2 3140 6
I 10/25/02 1448 5.2 3860 7
10/26/02 1463 5.2 4620 4
10/27/02 1271 5.2 4680 9
10/28/02 1159 5.2 3280 10.
I 10/29/02 1151 5.2 4710 3
10/30/02 1081 5.2 3870 7 978
10/31/02 978 5.2 3040 6
I AVG: 1292 5.1 4020 9 1362
MAX: 1629 5.5 7500 20 2160
I MIN: 473 a.a 0 0 978
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GROUNDWATER MONTHLY MONITORING: I
INNER TIER EQUALIZATION TANK: ITEQT
PAGE NO. 2 I OCT.2002
DATE: PH: COD: OT WATER ADDED
pH ppm gal I
10/01/02 7.0 4050
10/02/02 6.7 4060 563 I 10/03/02 7.1 3800
10/04/02 6.9 4050
10/05/02 7.3 1180 I 10/06/02 6.9 3410
10/07/02 6.9 3980
10/08/02 7.4 3200
10/09/02 7.2 3780 I 10/10/02 7.3 3340
10/11/02 7.2 3460
10/12/02 7.2 3890 I 10/13/02 7.1 4820
10/14/02 7.3 4890
10/15/02 7.2 4300 I 10/16/02 7.2 3750
10/17/02 7.5 4110
10/18/02 7.2 3230
10/19/02 7.5 2800 I 10/20/02 7.5 3370
10/21/02 7.4 3670
10/22/02 7.3 2980 I 10/23/02 7.3 3280
10/24/02 7.3 4460
10/25/02 7.4 3250 I 10/26/02 7.2 4560
10/27/02 7.2 4170
10/28/02 7.2 4160
10/29/02 7.3 3930 I 10/30/02 7.3 3260
10/31/02 7.4 2570
AVG: 7.2 3670 563 I
MAX: 7.5 4890 563
MIN: 6.7 1180 563 I
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36 I
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I GROUNDWATER MONTHLY MONITORING:
AFTER PLATE SEPARATOR BEFORE SBR: SBRI
I PAGE NO. 3
OCT.2002
DATE: PH: COD: TSS:
I pH ppm ppm
10/01/02
I 10/02/02 5.9 3370 12
10/03/02
10/04/02 5.9 4350 16
10/05/02
I 10/06/02 5.6 3400 16
10/07/02
10/08/02
I 10/09/02 6.3 3880 24
10/10/02
10/11/02 6.3 3440 8
I 10/12/02
10/13/02 6.7 4480 20
10/14/02
I 10/15/02
10/16/02 5.8 3740 24
10/17/02
10/18/02 5.7 2260 12
I 10/19/02
10/20/02 5.8 2680 32
10/21/02
I 10/22/02 5.8 3650 8
10/23/02
10/24/02 5.8 2490 12
I 10/25/02
10/26/02 6.0 4400 20
10/27/02
10/28/02 5.7 3630 20
I 10/29/02
10/30/02 5.7 3430 4
10/31/02
I AVG: 5.9 3514 16
MAX: 6.7 4480 32
I MIN: 5.6 2260 4
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GROUNDWATER MONTHLY MONITORING: I
SBR MIXED LIQUOR: SBRML
PAGE NO.4 I OCT.2002 SETT. SLUDGE 5/DAY
DATE: PH: NH3N: P04: DO: MLSS: MLVSS: SOLIDS: WASTED F/M: F/M:
pH ppm ppm ppm ppm ppm ml/I gal ratio ratio I 10/01/02 8.1 80 19.6 4.3 1940 1500 60 0 0.00
10/02/02 8.2 115 28.0 5.0 1620 70 80 0.18
I 10/03/02 8.3 96 20.0 4.3 1668 60 0 0.00
10/04/02 8.3 120 34.7 4.9 2424 60 80 0.16
10/05/02 8.3 105 25.0 5.4 2920 110 0 0.00 0.07
10/06/02 8.3 127 25.8 4.3 2084 80 202 0.15 0.10 I 10/07/02 8.1 112 16.1 4.9 2312 80 0 0.00 0.06
10/08/02 8.1 122 30.1 4.2 1644 1080 80 0 0.00 0.06
10/09/02 8.2 129 30.3 4.8 1436 50 202 0.24 0.08 I 10/10/02 8.1 155 32.0 4.5 2236 50 0 0.00 0.08
10/11/02 8.1 108 21.3 5.2 1332 50 202 0.23 0.09
10/12/02 8.1 89 12.0 4.7 2532 100 0 0.00 0.09 I 10/13/02 8.1 110 56.0 5.0 2516 100 100 0.16 0.13
10/14/02 8.1 105 36.4 4.8 2260 100 0 0.00 0.08
10/15/02 8.2 113 39.4 4.3 1660 1264 100 0 0.00 0.08
10/16/02 8.2 103 35.5 4.1 2468 100 202 0.13 0.06 I 10/17/02 8.4 132 35.0 4.9 2448 100 0 0.00 0.06
10/18/02 8.4 115 29.4 4.0 2308 100 202 0.09 0.04
10/19/02 8.4 88 23.4 3.0 2776 100 0 0.00 0.04 I 10/20/02 8.5 103 25.3 4.2 2316 100 202 0.10 0.06
10/21/02 8.4 96 21.5 3.3 3276 100 0 0.00 0.04
10/22/02 8.2 108 28.3 3.8 2788 2048 100 202 0.12 0.06 I 10/23/02 8.1 90 18.6 3.8 2672 100 0 0.00 0.04
10/24/02 8.3 108 30.6 4.4 2832 100 202 0.08 0.06
10/25/02 8.2 76 16.1 3.2 2880 100 0 0.00 0.04
10/26/02 8.2 110 25.0 3.2 2720 100 202 0.14 0.07 I 10/27/02 8.2 95 19.5 3.1 2856 100 0 0.00 0.04
10/28/02 8.2 115 21.8 3.9 2612 100 202 0.12 0.07
10/29/02 8.2 96 14.2 3.7 2904 2204 100 0 0.00 0.05 I 10/30/02 8.4 125 25.8 3.7 2840 100 202 0.11 0.07
10/31/02 8.3 82 15.0 2.9 2692 130 0
AVG: 8.2 107 26 4 2386 1619 90 80 0.07 0.07 I MAX: 8.5 155 56 5 3276 2204 130 202 0.24 0.13
MIN: 8.1 76 12 3 1332 1080 50 0 0.00 0.04 I
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I GROUNDWATER MONTHLY MONITORING:
I SBR EFFLUENT:(DECANT) #4 SBRE
PAGE NO. 5
OCT.2002 WAS. NH3N PHOS.
DATE: FLOW: COD: TSS: TSS ADDED: ADDED:
I GPD ppm ppm ppm gal lbs
10/01/02 0 1 2
I 10/02/02 2268 102 20.0 21280 0 0
10/03/02 0 2
10/04/02 2074 198 24.0 5820 0 0
I 10/05/02 0 0
10/06/02 2111 89 40.0 12390 0 0
10/07/02 0 0 2
10/08/02 0 0 0
I 10/09/02 2393 110 32 16480 0 0
10/10/02 0 0 0
10/11/02 2607 116 24 17420 0 0
I 10/12/02 0 1 1
10/13/02 2110 135 24.0 3268 0 0
10/14/02 0 0 0
I 10/15/02 0 0 0
10/16/02 1839 140 56 20660 1 2
10/17/02 0 0 0
10/18/02 2465 155 36 22520 0 0
I 10/19/02 0 1 2
10/20/02 2250 139 40 20160 0 0
10/21/02 0 2
I 10/22/02 2250 143 36 12450 0 0
10/23/02 0 1 2
10/24/02 2369 112 20 15600 0 0
I 10/25/02 0 1 2
10/26/02 2325 160 44 18420 0 0
10/27/02 0 0 0
I 10/28/02 2238 157 40 18280 0 0
10/29/02 0 1 2
10/30/02 2438 101 32.0 20780 0 0
10/31/02 0 1
I AVG: 1024 133 33 16109 0
MAX: 2607 198 56 22520 1 2
I MIN: 0 89 20 3268 0 0
• DID NOT PROCESS SBR .
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GROUNDWATER MONTHLY MONITORING I
INNER TIER CARBON FILTER EFFLUENT #8ITEF
PAGE NO. 7 I OCT.2002
DATE: PH: COD: TOC: TSS:
pH ppm
10/01/02
ppm ppm I
10/02/02 8.2 98 10.9 32 I 10/03/02
10/04/02
10/05/02
10/06/02 I 10/07/02
10/08/02
10/09/02 8.5 105 12.7 I 10/10/02
10/11/02
10/12/02 I 10/13/02
10/14/02
10/15/02
10/16/02 8.3 120 14.4 I 10/17/02
10/18/02
10/19/02 I 10/20/02
10/21/02
10/22/02 8.2 216 19.8 I 10/23/02
10/24/02
10/25/02
10/26/02 I 10/27/02
10/28/02
10/29/02 I 10/30/02 8.3 90 21.4
10/31/02
AVG: 8.3 126 15.8 32 I MAX: 8.5 216 21.4 32
MIN: 8.2 90 10.9 32 I
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MAINTENANCE ACTIVITIES-GROUNDWATER OPERABLE UNIT #1
INNER TIER SYSTEM
ACTION
DATE WELL# PROBLEM DATE ACTION MECHANIC
10/2/02 #9 LOW FLOW 10/2/02 CLEANED STRAINER ADJ. CONTROLS P.P. &MAX
10/14/02 #8 LOW FLOW 10/14/02 BLADDER CHANGED P.P. &MAX
10/14/02 #9 LOW FLOW 10/14/02 ADJ. CONTROLS BEND IN AIR LINE P.P. &MAX
10/17/02 #8 LOW FLOW 10/17/02 CHANGED METER UNPLUGGED LINE P.P. &MAX
3
41.
Well
OT-ZR
OT-3
OT-4
OT-5
OT-6
OT-GA
OT-7
OT-8
Thermometer
Operational? **
X
X
X
X
X
X
X
X
Monthly O&M Plan Checklist
HNA Holdings, Inc., Shelby, NC
Heat Lamp
Operational? **
X
X
X
X
X
X
X
X
Other Operational Items/Comments
CHANGED LIGHT
CHANGED LIGHT
CHANGED LIGHT
(** Temperature and Heat Lamp checks October thru April only)
Form Completed by: __________ T~O~N~Y~BR~Y~A~N~T'-----------
Date: -----------'1-=0-'-/2"'/_,0c:2'------------------------------
- - - -------·---·-
Quarterly O&M Plan Checklist-HNA Holdings, lnc./Shelby, NC Form Completed by:
,,.
.C,,,
Outer Tier Well
OT-2R
OT-3
OT-4
OT-5
OT-6
OT-GA
OT-7
OT-B
Ground-Water
Treatment Sys.
Open Sam?'e
Port
X
X
X
X
X
X
X
X
Energize
AS_,.
Y-V-1008
Date:
Energize Verify De-energize Close Sample Verify Heater Secure Well
Pump Olscha!]e Pume Port Oe!ration Vault
X X X X X X
X X X X X X
X X X X X X
X X X X X X
X X X X X X
X X X X X X
X X X X X X
X X X X X X
Energize Energize Energize Energize
Transfer Pump Transfer Pump Transfer Pump Transfer Pump
Y-P-1007A Y-P-10078 Y-P-1008A Y-P-10088 Comments
---· --
TONY BRYANT
10/4/02
Comments
I
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INNER TIER
DAILY FLOW I
NOV. I
2002 IT-1 IT-2 IT-3 IT-4 IT-5 IT-6 IT-7 IT-8 IT-9 I 11/01/02 86 15 24 90 164 35 56 254 328
11/02/02 82 15 25 89 167 36 71 233 353 I 11/03/02 81 16 26 84 169 37 67 231 396
11/04/02 88 15 26 87 168 33 71 430 354
11/05/02 82 15 64 90 168 32 69 23 408 I 11/06/02 82 16 84 96 168 32 68 62 330
11/07/02 76 15 22 106 153 30 73 272 0
11/08/02 92 16 25 92 170 34 14 12 345
11/09/02 80 15 25 80 169 34 134 4 465 I 11/10/02 82 16 22 71 171 34 71 295 452
11/11/02 90 20 25 120 175 40 75 300 495
11/12/02 77 14 162 315 136 32 63 41 369 I 11/13/02 84 18 12 74 163 36 40 130 · 468
11/14/02 85 20 21 44 181 37 52 75 473
11/15/02 84 19 17 50 170 41 46 50 400 I 11/16/02 76 24 61 301 216 34 111 0 0
11/17/02 95 22 53 217 198 36 46 0 0
11/18/02 87 26 34 0 184 36 33 384 · 373 ·1 11/19/02 87 26 15 67 187 36 18 425 520
11/20/02 83 27 12 47 196 39 43 424 524
11/21/02 94 26 4 58 195 35 72 422 497 I 11/22/02 93 23 34 52 222 36 39 441 64
11/23/02 92 23 35 53 227 36 50 444 1
11/24/02 96 23 34 53 215 36 40 436 0 I 11/25/02 89 22 34 54 214 37 23 461 210
11/26/02 94 22 34 58 213 37 23 457 0
11/27/02 91 23 35 57 224 34 0 467 150 I 11/28/02 107 21 33 61 224 35 0 477 462
11/29/02 66 21 34 70 222 37 5 493 265
11/30/02 120 21 36 75 217 38 28 515 0 I
AVG: 87 20 36 90 188 36 50 275 290 I
TOTAL: 2621 595 1068 2711 5646 1065 1501 8258 8702
I
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GROUNDWATER MONTHLY MONITORING:
RAINFALL DATA
NOV 2002 .
DATE INCHES/DAY
11/01/02 0.00
11/02/02 o.oo
11/03/02 o.oo
11/04/02 0.00
11/05/02 1.10
11/06/02 0.00
11/07/02 0.00
11/08/02 o.oo
11/09/02 0.00
11/10/02 0.20
11/11/02 1.40
11/ 12/02 0.30
11/13/02 o.oo
11/14/02 o.oo
11/ 15/02 0.60
11/ 16/02 1.00
11/17/02 0.00
11/ 18/02 o.oo
11/19/02 0.00
11/20/02 0.00
11/21/02 0.00
11/22/02 o.oo
11/23/02 0.00
11/24/02 o.oo
11/25/02 0.00
11/26/02 o.oo
11/27 /02 0.00
11/28/02 0.00
11/29/02 0.00
11/30/02 0.00
0.00
TOTAL 4.60
45 ·
DAILY REFERENCE SHEET:
DATE: IT. EQ. PLT. DEC. DEC. WAS MIX MIX MIX NIT PHOS MIX F/M
NOV. INF. TNK. SEP. LIQ LIQ LIQ ADD ADD LIQ WAS 5/DAY
~ COD. COD. COD, COD. ~ TS$ M.!..SS fill 1'HQS .M.!,,S LBS SfL ~ ELM ~
1 4470 3520 3870 175 28 8330 3032 108 24 1 0 120 100 0.11
2 4830 2700 3500 167 24 15260 2560 102 18.0 0 0 120 202 0.12
3 3920 3180 2936 130 20.0 0 0 120 0 0.00
4 3850 2730 2270 121 8 17100 2444 96 13.5 1 2 100 202 0.08
5 4030 3260 2808 102 18.5 1 2 100 0 0.00 0.06
6 4600 3140 2260 109 40 21670 3216 113 26.8 0 0 100 202 0.06 0.05
7 7870 3740 2768 111 19.5 0 2 100 0 0.00 0.03
8 7520 3180 3820 130 12 19560 2244 106 29.0 0 0 100 202 0.15 0.06
9 3140 4610 2576 90 20.0 1 2 100 0 0.00 0.04
10 4060 4040 2324 110 26.8 0 0 100 0 0.00 0.04
11 3970 3660 3470 100 20 19460 1952 125 30.4 0 0 100 202 0.16 0.06
12 3380 4180 3044 104 20.0 1 2 100 0 0.00 0.06
13 2780 3330 4320 98 20 17950 2084 133 30.1 0 0 100 202 0.18 0.07 .... 14 3100 3180 3012 96 15.1 1 2 100 0 0.00 0.07 cr, 15 3810 3910 3390 115 16 16160 2816 115 26.1 0 0 100 202 0.11 0.09
16 9640 5050 2800 82 14.2 1 1 100 0 0.00 0.06
17 6160 4500 3800 95 2744 108 23.5 0 0 100 202 0.12 0.08
18 6300 4060 2548 112 17.4 0 2 100 0 0.00 0.05
19 3580 3280 3330 101 16 19250 2720 101 27.2 0 0 100 202 0.11 0.07
20 3420 3680 2632 104 20.1 0 0 100 0 0.00 0.05
21 3830 3180 3040 92 4 3604 2844 90 19.5 1 130 180 0.10 0.07
22 3590 3690 2888 89 12.0 1 110 0 0.00 0.04
23 _6430 4070 3870 104 12 7290 2744 138 42.0 1 1 120 180 0.13 0.07
24 3210 4050 2996 118 29.0 1 0 130 0 0.00 0.04
25 6590 4360 3520 81 20 19350 2568 132 28.0 0 0 100 202 0.12 0.07
26 6460 4910 2064 119 21.3 0 0 100 0 0.00 0.05
27 5660 3430 3340 78 28 20300 3112 110 19.2 1 2 100 202 0.10 0.07
28 3890 4350 3112 137 24.9 0 0 100 0 0.00 0.04
29 4220 4280 3800 77 40 21110 2720 154 25.6 0 0 100 202 0.12 O.Q7
30 6790 4510 2520 118 19.2 0 2 100 0 0.00 0.04
#DIV/0! #DIV/0!
AVG: 4837 3792 3440 110 21 16171 2694 111.8 22.7 0 1 105 96 #DIV/01
MAX: 9640 5050 4320 175 40 21670 3216 154.0 42.0 1 2 130 202 #DIV/01
MIN: 2780 2700 2260 77 4 3604 1952 82.0 12.0 0 0 100 0 #DIV/01
3/13/03 - -- -- -----·--- --· - -
I
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INNER TIER COMBINED INFLUENT #2 ITCI
I PAGE NO.1
NOV. 2002
DATE: FLOW: PH: COD: TSS: TOC:
I GPO pH ppm ppm ppm
11/01/02 1052 5.2 4470 9
I 11/02/02 1071 5.2 4830 4
11/03/02 1107 5.3 3920 6
11/04/02 1272 5.2 3850 2
11/05/02 951 5.2 4030 7
I 11/06/02 938 5.2 4600 12 936
11/07/02 747 5.1 7870 6
11/08/02 800 4.8 7520 2
I 11/09/02 1008 5.2 3140 8
11/10/02 1214 5.2 4060 4
11/11/02 1340 5.3 3970 3
I 11/12/02 1201 5.2 3380 18 785
11/13/02 1025 5.2 2780 10
11/14/02 988 5.3 3100 2
I 11/15/02 877 5.2 3810 4
11/16/02 823 5.0 9640 3
11/17/02 667 5.1 6160 7
11/18/02 1157 5.1 6300 11
I 11/19/02 1381 5.4 3580 10 1060
11/20/02 1381 5.4 3420 4
11/21/02 1403 5.3 3830 18
I 11/22/02 1004 5.4 3590 21
11/23/02 961 5.3 6430 47
11/24/02 933 5.3 3210 30
I 11/25/02 1144 5.4 6590 24
11/26/02 938 5.3 6460 14
11/27/02 1081 5.1 5660 23 2230
11/28/02 1420 5.2 3890 10
I 11/29/02 1213 5.4 4220 11
11/30/02 1050 5.1 6790 7
I AVG: 1072 5.2 4837 11 1253
MAX: 1420 5.4 9640 47 2230
I MIN: 667 4.8 2780 2. 785
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GROUNDWATER MONTHLY MONITORING: I
INNER TIER EQUALIZATION TANK: ITEQT
PAGE NO. 2 I OCT.2002
DATE: PH: COD: OT WATER ADDED
pH ppm gal I
11/01/02 7.3 3520
11/02/02 7.4 2700 I 11/03/02 7.3 3180
11/04/02 7.3 2730
11/05/02 7.3 3260
I 11/06/02 7.3 3140
11/07/02 7.5 3740
11/08/02 7.2 3180 563
11/09/02 7.3 4610 I 11/10/02 7.3 4040
11/11/02 6.9 3660
11/12/02 7.2 4180 I 11/13/02 7.2 3330
11/14/02 7.3 3180
11/15/02 7.4 3910 75 I 11/16/02 7.2 5050
11/17/02 7.2 4500 638
11/18/02 7.3 4060
11/19/02 7.3 3280 375 .,
11/20/02 7.3 3680
11/21/02 7.3 3180
11/22/02 7.4 3690 I 11/23/02 7.6 4070
11/24/02
11/25/02 7.5 4360 563 I 11/26/02 7.5 4910
11/27/02 7.4 3430 375
11/28/02 7.5 4350
11/29/02 7.5 3800 75 I 11/30/02 7.4 4510
10/31/02
AVG: 7.3 3767 381 I
MAX: 7.6 5050 638
MIN: 6.9 2700 75 I
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48 I
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I GROUNDWATER MONTHLY MONITORING:
AFTER PLATE SEPARATOR BEFORE SBR:
I PAGE NO. 3
OCT.2002
DATE: PH: COD: TSS:
I pH ppm ppm
11/01/02 5.9 3870 16
I 11/02/02 6.3 3500 4
11/03/02
11/04/02 6.1 2270 48
11/05/02
I 11/06/02 5.9 2260 16
11/07/02
11/08/02 6.7 3820 4
I 11/09/02
11/10/02
11/11/02 6.0 3470 12
I 11/12/02
11/13/02 5.5 4320 8
11/14/02
11/15/02 5.6 3390 8 I 11/16/02
11/17/02 5.6 3800 4
11/18/02
I 11/19/02 5.6 3330 4
11/20/02
11/21/02 6.4 3040 4
I 11/22/02
11/23/02 6.5 3870 12
11/24/02
11/25/02 5.7 3520 4 I 11/26/02
11/27/02 5.6 3340 8
11/28/02
I 11/29/02 6.9 4280 24
11/30/02
10/31/02
I AVG: 6.0 3472 12
MAX: 6.9 4320 48
I MIN: 5.5 2260 4
I
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I 49
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GROUNDWATER MONTHLY MONITORING: I
SBR MIXED LIQUOR: SBRML
PAGE NO.4 I OCT.2002 SETT. SLUDGE 5/DAY
DATE: PH: NH3N: PO4: DO: MLSS: MLVSS: SOLIDS: WASTED F/M: F/M:
pH ppm ppm ppm ppm ppm ml/I gal ratio ratio I 11/01/02 8.4 108 24.0 3.5 3032 120 100 0.11
11/02/02 8.3 102 18.0 3.0 2560 120 202 0.12 I 11/03/02 8.2 130 20.0 3.7 2936 120 0 0.00
11/04/02 8.2 96 13.5 3.9 2444 100 202 0.08
11/05/02 8.2 102 18.5 3.6 2808 2136 100 0 0.00 0.06
11/06/02 8.4 113 26.8 4.1 3216 100 202 0.06 0.05 I 11/07/02 8.3 111 19.5 4.3 2768 100 0 0.00 0.03
11/08/02 8.3 106 29.0 4.2 2244 100 202 0.15 0.06
11/09/02 8.3 90 20.0 4.5 2576 100 0 0.00 0.04 I 11/10/02 8.3 110 26.8 3.5 2324 100 0 0.00 0.04
11/11/02 8.3 125 30.4 4.4 1952 100 202 0.16 0.06
11/12/02 8.2 104 20.0 3.4 3044 2308 100 0 0.00 0.06 I 11/13/02 8.3 133 30.1 4.5 2084 100 202 0.18 0.07
11/14/02 8.2 96 15.1 3.7 3012 100 0 0.00 0.07
11/15/02 8.3 115 26.1 4.8 2816 100 202 0.11 0.09
11/16/02 8.2 82 14.2 3.6 2800 100 0 0.00 0.06 I 11/17/02 8.2 108 23.5 3.5 2744 100 202 0.12 0.08
11/18/02 8.3 112 17.4 4.8 2548 100 0 0.00 0.05
11/19/02 8.1 101 27.2 4.9 2720 2080 100 202 0.11 0.07 I 11/20/02 8.1 104 20.1 3.6 2632 100 0 0.00 0.05
11/21/02 8.1 90 19.5 4.8 2844 130 180 0.10 0.07
11/22/02 8.2 89 12.0 5.2 2888 110 0 0.00 0.04 I 11/23/02 8.2 138 42.0 4.1 2744 120 180 0.13 0.07
11/24/02 8.1 118 29.0 4.7 2996 130 0 0.00 0.04
11/25/02 8.4 132 28.0 5.3 2668 100 202 0.12 0.07 I 11/26/02 8.3 119 21.3 4.6 2064 1654 100 0 0.00 0.05
11/27/02 8.2 110 19.2 5.4 2340 100 202 0.13 0.07
11/28/02 8.3 137 24.9 4.1 3112 100 0 0.00 0.05
11/29/02 8.2 154 25.6 3.9 2720 100 202 0.14 0.08 I 11/30/02 8.0 118 19.6 1.2 2520 100 0 0.00 0.05
10/31/02
AVG: 8.2 112 23 4 2672 2045 105 96 0.06 0.06 I MAX: 8.4 154 42 5 3216 2308 130 202 0.18 0.09
MIN: 8.0 82 12 1 1952 1654 100 0 0.00 0.03 I
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I GROUNDWATER MONTHLY MONITORING:
SBR EFFLUENT:(DECANT) #4 SBRE
I PAGE NO. 5
OCT.2002 WAS. NH3N PHOS.
DATE: FLOW: COD: TSS: TSS ADDED: ADDED:
I GPD ppm ppm ppm gal lbs
11/01/02 2375 175 28 8330 0
I 11/02/02 1974 167 24 15260 0 0
11/03/02 0 0 0
11/04/02 2334 121 8 17100 1 2
11/05/02 0 1 2
I 11/06/02 2254 109 40 21670 0 0
11/07/02 0 0 2
11/08/02 2363 130 12 19560 0 0 ,, 11/09/02 0 1 2
11/10/02 0 0 0
11/11/02 1763 100 20 19460 0 0
I 11/12/02 0 1 2
11/13/02 2741 98 20 17950 0 0
11/14/02 0 1 2
I 11/15/02 2522 115 16 16160 0 0
11/16/02 0 1 1
11/17/02 2070 95 8 14660 0 0
11/18/02 0 0 2
I 11/19/02 1882 101 16 19250 0 0
11/20/02 0 0 0
11/21/02 2045 90 8 3604
I 11/22/02 0 1 1
11/23/02 2430 104 8 7290 1 0
11/24/02 0 1 0
I 11/25/02 2040 81 20 19350 0 0
11/26/02 0 0 0
11/27/02 1922 78 28 20300 1 2
11/28/02 0 0 0
I 11/29/02 1924 77 40 21110 0 0
11/30/02 0 0 2
10/31/02
I AVG: 1088 109 20 16070 0 1
MAX: 2741 175 40 21670 1 2
I MIN: 0 77 8 3604 0 0
• DID NOT PROCESS SBR .
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I 51
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GROUNDWATER MONTHLY MONITORING I
INNER TIER CARBON FILTER EFFLUENT #8ITEF
PAGE NO. 7 I OCT.2002
DATE: PH: COD: TOC: TSS:
pH ppm ppm ppm I 11/01/02
11/02/02 I 11/03/02
11/04/02
11/05/02
11/06/02 8.3 101 20.9 40 I 11/07/02
11/08/02
11/09/02 :I 11/10/02
11/11/02
11/12/02 I 11/13/02 8.2 81 19.6
11/14/02
11/15/02
11/16/02 •• 11/17/02
11/18/02
11/19/02 8.2 98 16.1 I 11/20/02
11/21/02
11/22/02 I 11/23/02
11/24/02
11/25/02 I 11/26/02
11/27/02 8.2 65 10.5
11/28/02
11/29/02 ,I 11/30/02
10/31/02
AVG: 8.2 86 17 40 •• MAX: 8.3 101 21 40
MIN: 8.2 65 11 40 I
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.1
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MAINTENANCE ACTIVITIES-GROUNDWATER OPERABLE UNIT #1
INNER TIER SYSTEM
ACTION
DATE WELL# PROBLEM DATE ACTION MECHANIC
11/1/02 #8 LOW FLOW 11/1/02 CLEANED STRAINER AT METER P.P. &MAX
1117/02 #8 LOW FLOW 1117/02 CHANGED BLADDER P.P. &MAX
11/8102 #9 LOW FLOW 11/8/02 CLEANED PROBES P.P. &MAX
11/18/02 #8 LOW FLOW 11/18/02 REPLACED INTAKE RELAY CONTROL P.P. &MAX
11/18/02 #9 LOW FLOW 11/18/02 RESTART PUMP ADJ. CONTROL P.P. &MAX
11/19/02 #4 LOW FLOW 11/19/02 REPLACED EXHAUSTER & CONTROL P.P. &MAX
11/22102 #3 LOW FLOW 11/22102 REPLACED METER P.P. &MAX
11/25/02 #9 LOW FLOW 11/25/02 RESTARTED PUMP ADJ. CONTROL P.P. &MAX
53
Well
OT-2R
OT-3
OT-4
OT-5
OT-6
OT-GA
OT-7
OT-8
Thermometer
Operational? '"'
X
X
X
X
X
X
X
X
Monthly O&M Plan Checklist
HNA Holdings, Inc., Shelby, NC
Heat Lamp
Operational? **
X
X
X
X
X
X
X
X
Other Operational Items/Comments
(** Temperature and Heat Lamp checks October thru April only)
Form Completed by: _________ T-'-O~N-'-Y~B~R-'-Y-'-A~N~T ________ _
Date: _________ ___,1-'1-'-/4-"/'-'0'-=2'----------------.. ,_ -.. --· --· - - - - --
I
I
INNER TIER
I DAILY FLOW
I DEC.
I 2002 IT-1 IT-2 !H IT-4 1H IT-6 IT-7 IT-8 IT-9
12/01/02 88 22 34 75 205 35 3 503 0
I 12/02/02 104 23 34 79 219 37 0 518 0
12/03/02 97 24 34 77 223 47 14 495 370
12/04/02 89 25 30 140 203 67 2 446 72
I 12/05/02 95 31 114 130 209 77 2 462 405
12/06/02 90 30 110 131 205 75 0 450 390
12/07/02 103 29 28 30 228 95 135 590 573
12/08/02 104 29 39 74 211 81 105 482 467
•• 12/09/02 15 6 6 10 31 12 16 68 68
12/10/02 86 40 43 70 189 68 58 326 359
I 12/11/02 104 47 87 92 247 84 101 396 493
12/12/02 106 48 90 95 240 85 105 400 480
12/13/02 110 53 35 191 207 72 82 306 429
12/14/02 110 56 62 154 228 86 104 411 525
I 12/15/02 107 63 53 58 212 83 102 428 514
12/16/02 112 71 45 11 237 85 108 479 316
12/17/02 109 79 42 120 240 80 100 429 532
I 12/18/02 107 106 39 74 238 82 102 394 520
12/19/02 114 111 42 95 256 87 110 457 181
12/20/02 119 111 60 127 244 86 114 457 0
I 12/21/02 100 70 20 120 265 70 110 430 3
12/22/02 87 24 22 1 1 2 0 63 36
12/23/02 100 36 41 104 160 81 127 450 566
I 12/24/02 64 231 59 130 185 89 69 654 572
12/25/02 118 125 77 184 208 90 120 715 602
12/26/02 110 119 69 51 199 79 103 662 531
I 12/27/02 99 110 71 69 185 95 98 602 551 =-12/28/02 150 184 6 57 244 85 136 542 612
12/29/02 129 144 25 68 218 89 111 539 590
I 12/30/02 125 138 28 62 229 89 110 290 574
12/31/02 134 144 23 71 247 92 122 353 630
I AVG: 103 75 47 89 207 74 80 445 386
I TOTAL: 3185 2329 1468 2750 6413 2285 2469 13797 11961
I
I 55
GROUNDWATER MONTHLY MONITORING:
RAINFALL DATA
DEC 2002 .
DATE INCHES/DAY
12/01/02 o.oo
12/02/02 0.00
12/03/02 0.00
12/04/02 1.00
12/05/02 0.30
12/06/02 0.00
12/07/02 0.00
12/08/02 0.00
12/09/02 0.00
12/10/02 0.60
12/ 11/02 0.00
12/12/02 0.20
12/13/02 0.80
12/14/02 0.00
12/15/02 0.00
12/16/02 0.00
12/17/02 0.00
12/18/02 0.80
12/19/02 0.00
12/20/02 0.00
12/21/02 o.oo
12/22/02 0.00
12/23/02 0.20
12/24/02 1.50
12/25/02 0.00
12/26/02 0.00
12/27/02 0.00
12/28/02 0.00
12/29/02 o.oo
12/30/02 0.00
12/31/02 0.05
TOTAL 5.45
5 6 '
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-- -- - - ----·----·----··-
DAILY REFERENCE SHEET:
DATE: IT. EQ. PLT. DEC. DEC. WAS MIX MIX MIX NIT PHOS MIX F/M
DEC. INF. TNK. SEP. LIQ LIQ LIQ ADD ADD LIQ WAS 5/DAY
~ @12. ~ ~ @12. :r.ss. .Ifili ~ HIT ~ ~ LBS SET, GALS ELM AVG.
1 6410 4240 3360 119 12 14090 2844 107 21.3 0 0 100 202 0.11
2 6370 4670 3036 115 18.5 0 2 100 0 0.00
3 6620 4740 4130 95 4 19170 2672 115 28.5 0 0 100 202 0.14
4 3830 2800 2742 90 18.8 1 2 100 0 0.00
5 7100 3230 4340 93 24 19090 2176 112 30 0 0 100 202 0.18 0.08
6 3680 3970 2800 90 21.5 0 0 100 0 0.00 0.06
7 4450 4080 4370 94 32 17490 2800 70 16.5 1 1 100 202 0.14 0.09
8 4760 4680 2960 70 17.0 1 1 100 0 0.00 0.06
9 4370 2790 4240 100 36 18840 3136 111 26.5 0 0 100 202 0.12 0.09
10 4360 3910 3200 87 16.5 1 2 100 0 0.00 0.05
11 4890 4200 4370 87 24 15460 2616 97 20.8 1 2 100 202 0.15 0.08
12 3500 4260 1920 86 32.8 1 2 100 0 0.00 0.05
13 4440 4580 3240 103 12 17330 2860 138 40.5 0 0 100 202 0.10 O.o?
'-" 14 4500 3900 4600 141 200 4930 3072 122 32.0 1 0 100 180 0.13 0.08 ~ 15 4820 3750 3076 107 22.4 0 0 100 0 0.00 0.08
16 5100 3930 3940 156 32 14080 1784 97 21 0 0 100 202 0.20 0.09
17 6870 4130 2944 95 12.5 1 2 100 0 0.00 0.09
18 4710 4600 3560 197 36 16430 2736 97 20.0 1 2 100 202 0.12 0.09
19 4760 3060 3560 118 56 14320 3072 94 24.5 1 2 100 202 0.10 0.08
20 8200 3700 2936 91 23.0 0 0 100 0 0.00 0.08
21 6670 5230 3830 85 30 7660 3200 104 22.0 0 0 100 202 0.11 0.07
22 0 0 0 0 #DIV/0! #DIV/QI
23 6520 3990 2900 97 18.5 1 2 100 0 0.00 #DIV/0!
24 4790 4060 4500 133 40 15960 3260 106 25.5 0 0 150 202 0.12 #DIV/0!
25 4470 3660 3720 123 30 18770 3084 91 11.0 1 2 150 202 0.11 #DIV/0!
26 4150 3660 3092 94 14.0 1 2 150 0 0.00 #DIV/0!
27 4460 3710 4450 106 50 15620 2780 116 23.0 0 0 150 202 0.14 0.07
28 5140 5250 4300 94 20 11660 2972 95 13.0 1 2 150 202 0.13 0.10
29 5280 4640 3028 90 15.0 1 2 150 0 0.00 0.08
30 4200 4150 4160 106 10 15340 3092 103 22.5 1 2 150 202 0.12 0.08
31 5390 4750 4390 127 50 13810 3028 103 22.2 0 0 150 202 0.13 0.10
AVG: 5160 4077 3845 109 37 14213 2861 99.7 21.7 1 110 117 #DIV/01
MAX: 8200 5250 4600 197 200 19170 3260 138.0 40.5 2 150 202 #DIV/01
MIN: 3500 2790 0 0 0 0 1784 70.0 11.0 0 0 0 0 #DIV/01
3/13/03
I
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INNER TIER COMBINED INFLUENT #2 ITCI .
PAGE NO.1 I DEC.2002
DATE: FLOW: PH: COD: TSS: TOC:
GPO pH ppm ppm ppm I
12/01/02 965 5.0 6410 18
12/02/02 1014 5.1 6370 19 I 12/03/02 1381 5.1 6620 23 2080
12/04/02 1074 5.0 3830 2
12/05/02 1525 5.2 7100 17
12/06/02 1481 5.1 3680 10 I 12/07/02 1811 5.2 4450 5
12/08/02 1592 5.3 4760 6
12/09/02 232 5.1 4370 3
•• 12/10/02 1239 5.1 4360 7
12/11/02 1651 5.3 4890 12 1520
12/12/02 1649 5.4 3500 8 I 12/13/02 1485 5.3 4440 4
12/14/02 1736 5.4 4500 6
12/15/02 1620 5.3 4820 3 I 12/16/02 1464 5.3 5100 2
12/17/02 1631 5.3 6870 19
12/18/02 1661 5.4 4710 4 2020
12/19/02 1453 5.5 4760 5 I 12/20/02 1318 5.2 8200 6
12/21/02 1188 5.3 6670 11
12/22/02 236 SCHEDULED POWER OUTAGE I 12/23/02 1660 5.1 6520 11
12/24/02 2053 5.4 4790 5
12/25/02 2239 5.3 4470 5 1230 I 12/26/02 1923 5.3 4150 6
12/27/02 1880 5.4 4460 3
12/28/02 2016 5.3 5140 8
12/29/02 1913 5.3 5280 25 I 12/30/02 1645 5.4 4200 6
12/31/02 1816 5.4 5390 5
AVG: 1502 5.1 5160 9 1713 I
MAX: 2239 5.5 8200 25 2080
MIN: 232 0.0 3500 2 1230 I
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I GROUNDWATER MONTHLY MONITORING:
I INNER TIER EQUALIZATION TANK: ITEQT
PAGE NO. 2
DEC.2002
DATE: PH: COD: OT WATER ADDED
I pH ppm gal
12/01/02 7.2 4240 375
I 12/02/02 7.3 4670
12/03/02 7.2 4740 563
12/04/02 7.2 2800
I 12/05/02 7.1 3230
12/06/02 7.2 3970
12/07/02 7.2 4080
12/08/02 7.3 4680
•• 12/09/02 7.2 2790
12/10/02 7.5 3910
12/11/02 12.9 4200
I 12/12/02 12.8 4260
12/13/02 12.5 4580
12/14/02 12.3 3900
I 12/15/02 8.9 3750
12/16/02 6.4 3930
12/17/02 7.2 4130
12/18/02 7.2 4600 I 12/19/02 7.4 3060 300
12/20/02 7.1 3700
12/21/02 6.9 5230
I 12/22/02
12/23/02 7.2 3990
12/24/02 6.9 4060
I 12/25/02 7.2 3660 263
12/26/02 7.3 3660
12/27/02 7.0 3710
12/28/02 7.3 5250 188
I 12/29/02 7.3 4640
12/30/02 7.1 4150
12/31/02 7.4 4750
I AVG: 8.0 4077 338
MAX: 12.9 5250 563
I MIN: 6.4 2790 188
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GROUNDWATER MONTHLY MONITORING I
AFTER PLATE SEPARATOR BEFORE SBR:
PAGE NO. 3 I DEC.2002
DATE: PH: COD: TSS:
pH ppm ppm I
12/01/02 5.7 3360 4
12/02/02 I 12/03/02 5.5 4130 8
12/04/02
12/05/02 5.6 4340 4 I 12/06/02
12/07/02 7.1 4370 14
12/08/02
12/09/02 5.4 4240 8 •• 12/10/02
12/11/02 6.2 4370 16
12/12/02 I 12/13/02 5.4 3240 4
12/14/02 12.2 4600 128
12/15/02 I 12/16/02 6.8 3940 16
12/17/02
12/18/02 7.4 3560 36
12/19/02 7.3 3560 16 I 12/20/02
12/21/02 7.2 3830 20
12/22/02 I 12/23/02
12/24/02 6.9 4500 12
12/25/02 7.1 3720 12 I 12/26/02
12/27/02 7.0 4450 36
12/28/02 7.0 4300 8
12/29/02 I 12/30/02 7.1 4160 8
12/31/02 7.2 4390 20
AVG: 6.9 4059 21 I
MAX: 12.2 4600 128
MIN: 5.4 3240 4 I
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I GROUNDWATER MONTHLY MONITORING:
SBR MIXED LIQUOR: SBRML
I PAGE NO.4
DEC.2002 SETT. SLUDGE 5/DAY
DATE: PH: NH3N: PO4: DO: MLSS: MLVSS: SOLIDS: WASTED F/M: F/M:
I pH ppm ppm ppm ppm ppm ml/I gal ratio ratio
12/01/02 8.0 107 21.3 3.7 2844 100 202 0.11
I 12/02/02 8.0 115 18.5 3.7 3036 100 0 0.00
12/03/02 8.2 115 28.5 4.6 2672 2084 100 202 0.14
12/04/02 7.9 90 18.8 3.9 2742 100 0 0.00
12/05/02 8.0 112 30.0 4.3 2176 100 202 0.18 0.08
I 12/06/02 8.0 90 21.5 4.0 2800 100 0 0.00 0.06
12/07/02 8.0 70 16.5 3.9 2800 100 202 0.14 0.09
12/08/02 8.1 70 17.0 3.2 2960 100 0 0.00 0.06
I 12/09/02 8.0 111 26.5 4.5 3136 100 202 0.12 0.09
12/10/02 8.0 87 16.5 3.9 3200 2428 100 0 0.00 0.05
12/11/02 8.0 97 20.8 4.2 2616 100 202 0.15 0.08
I 12/12/02 8.2 86 32.8 4.8 1920 100 0 0.00 0.05
12/13/02 8.3 138 40.5 5.0 2860 100 202 0.10 0.07
12/14/02 8.3 122 32.0 4.6 3072 100 180 0.13 0.08
I 12/15/02 7.9 107 22.4 4.4 3076 100 0 0.00 0.08
12/16/02 8.3 97 21.0 6.0 1784 100 202 0.20 0.09
12/17/02 8.4 95 12.5 4.6 2944 2316 100 0 0.00 0.09
12/18/02 8.5 97 20.0 4.1 2736 100 202 0.12 0.09
I 12/19/02 8.5 94 24.5 4.6 3072 100 202 0.10 0.08
12/20/02 8.4 91 23.0 3.8 2936 100 0 0.00 0.08
12/21/02 8.4 104 22.0 4.6 3200 100 202 0.11 0.07
I 12/22/02 0.00 0.07
12/23/02 8.3 97 18.5 4.6 2900 100 0 0.00 0.05
12/24/02 8.4 106 25.5 5.0 3260 150 202 0.12 0.05
I 12/25/02 8.4 91 11.0 4.7 3084 150 202 0.11 0.07
12/26/02 8.3 94 14.0 4.6 3092 2460 150 0 0.00 0.05
12/27/02 8.4 116 23.0 5.2 2780 150 202 0.14 0.07
12/28/02 8.3 95 13.0 3.8 2972 150 202 0.13 0.10
I 12/29/02 8.2 90 15.0 4.0 3028 150 0 0.00 0.08
12/30/02 8.3 103 22.5 6.7 3092 150 202 0.12 0.08
12/31/02 8.4 103 22.2 4.5 3028 2416 150 202 0.13 0.10
I AVG: 8.2 100 22 4 2861 2341 113 120 0.08 0.07
MAX: 8.5 138 41 7 3260 2460 150 202 0.20 0.10
I MIN: 7.9 70 11 3 1784 2084 100 0 0.00 0.05
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GROUNDWATER MONTHLY MONITORING: I
SBR EFFLUENT:(DECANT) #4 SBRE
PAGE NO. 5 I DEC.2002 WAS. NH3N PHOS.
DATE: FLOW: COD: TSS: TSS ADDED: ADDED:
GPO ppm ppm ppm gal lbs I
12/01/02 2513 119 12 14090 0 0
12/02/02 0 0 2 I 12/03/02 2063 95 4 19170 0 0
12/04/02 0 1 2
12/05/02 2438 93 4 19090 0 0 I 12/06/02 0 0 0
12/07/02 2663 94 17490
12/08/02 0 1 1
12/09/02 2813 100 36 18840 0 0 I 12/10/02 0 2
12/11/02 2813 87 24 15460 1 2
12/12/02 0 1 2 I 12/13/02 1875 103 12 17330 0 0
12/14/02 2100 141 200 4930 1 0
12/15/02 0 0 0 I 12/16/02 2400 156 32 14080 0 0
12/17/02 0 1 2
12/18/02 2625 197 36 16430 1 2
12/19/02 2625 118 56 14320 1 2 I 12/20/02 0 0 0
12/21/02 2030 85 30 7660 0 0
12/22/02 I 12/23/02 0 1 2
12/24/02 2080 133 40 15960 0 0
12/25/02 2250 123 30 18770 2 I 12/26/02 0 1 2
12/27/02 2388 106 36 15620 0 0
12/28/02 2443 94 20 11660 2
12/29/02 0 2 I 12/30/02 2361 106 10 15340 1 2
12/31/02 2442 127 50 13810 0 0
AVG: 1431 115 37 15003 1 I
MAX: 2813 197 200 19170 1 2
MIN: 0 85 4 4930 0 0 I • DID NOT PROCESS SBR .
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I GROUNDWATER MONTHLY MONITORING
INNER TIER CARBON FILTER EFFLUENT #8ITEF
I PAGE NO. 7
DEC.2002
DATE: PH: COD: TOC: TSS:
I pH ppm ppm ppm
12/01/02
I 12/02/02
12/03/02 8.1 88 8.8 4
12/04/02
I 12/05/02
12/06/02
12/07/02
12/08/02
I 12/09/02
12/10/02
12/11/02 8.3 84 7.0
I 12/12/02
12/13/02
12/14/02
I 12/15/02
12/16/02
12/17/02
12/18/02 8.3 145 25.6
I 12/19/02
12/20/02
12/21/02
I 12/22/02
12/23/02
12/24/02
I 12/25/02 8.5 114 19.0
12/26/02
12/27/02
12/28/02 I 12/29/02
12/30/02
12/31/02
I AVG: 8.3 108 15 4
MAX: 8.5 145 26 4
I MIN: 8.1 84 7 4
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I 63 ,
MAINTENANCE ACTIVITIES-GROUNDWATER OPERABLE UNIT #1
INNER TIER SYSTEM
ACTION
DATE WELL# PROBLEM DATE ACTION MECHANIC
12/3/02 #6 LDWFLDW 12/6/02 REPLACED METER & BLADDER P.P& MAX
12/3/02 #8 LDWFLDW 12/3/02 REPLACED EXHAUSTER ,METER & LINE P.P& MAX
12/3/02 #9 LDWFLOW 12/3/02 RESTARTED PUMP P.P&MAX
12/6/02 #7 LDWFLDW 12/6/02 REPLACED EXHAUSTER P.P&MAX
64
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-------------------
cr,
c..n
Well
OT-2R
OT-3
OT-4
OT-5
OT-6
OT-GA
OT-7
OT-8
Thermometer
Operational? **
X
X
X
X
X
X
X
X
Monthly O&M Plan Checklist
HNA Holdings, Inc., Shelby, NC
Heat Lamp
Operational? **
X
X
X
X
X
X
X
X
Other Operational Items/Comments
(** Temperature and Heat Lamp checks October thru April only)
Form Completed by: _________ T'-'O=N"'-'Y'-B=R"'-'Y~A"-N~T ________ _
Date: --------------=1-=2"-l:,2lc...:0:..:2=------------
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I Attachment 2
I
Analytical Data for the
3rd and 4th Quarter 2002 Sampling Events
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I Kubal-Furr & Associates
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DATA ASSESSMENT SUMMARY CHECKLIST AND REPORT -LEVEL II
Client ID: CNA Holdings, Inc. -Shelby Prepared By: Julie A. Lisenby
Project Number: 26OS05 Date: I 0/03/02
Project Description: Routine Sampling 03/02
Sample Delivery Group (SDG) Description:
Quarterly groundwater quality samples were collected by Kubal-Furr & Associates and analyzed
by Davis & Floyd, Inc., of Greenwood, SC, for volatile organic compounds, semivolatile organic
compounds including DowTherm®, ethylene glycol and total organic carbon in accordance with
EPA/NCDENR approved methodology.
CONTENTS LEVEL COMMENTS
II
Sample Results v All data considered Class A except
as noted in the discussion section.
Chain(s) of Custody (COCs) 'V Acceptable.
Master Tracking List 'V Acceptable.
Case Narrative
Method Conformance Summary 'V Acceptable.
Sample Prep
Standards Prep
Instrument Quality Control Data 'V Acceptable.
Batch Quality Control Report 'V Acceptable.
Surrogate Recovery Report 'V Acceptable.
Trip/Field/Equipment Blank Report 'V Acceptable.
Field Notes/Logbook 'V Acceptable.
CLP Forms
All Raw Data
Electronic Deliverables v Provided.
-------------Kubal-Furr & Associates ------------
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CNA Holdings -Q3/02 DAS -2 -10/03/02
Discussion:
General
The Equipment Blank was not listed on the Chain of Custody. The laboratory used the date
and time recorded on the sample label for reporting purposes.
Volatile Organics (Method 8260B)
Most of the volatiles data are considered Class A as reported, and may be used fully without
qualification. The two samples contained results that were classified as Class B, qualitative, and
contain data flags. The assigned data flags apply only to the specific compounds and samples
identified in the following narrative.
The relative percent difference between bromoform, ehloromethane, and dibromochloromethane
results in the initial sample ITEF and its duplicate, ITEF-DUP, are greater than 20%, a general
guideline used for the comparison of results between aqueous samples. The results are reported as
detected amounts in ITEF and are flagged "J;,, results in ITEF-DUP are reported as nondetected
amounts and are flagged "UJ.,,
Semivolatile Organic Compounds/ Dowtherm (Method 8270C)
All data are considered Class A as rep011ed, and may be used fully without qualification.
TDC (Method 9060)
All data arc considered Class A as reported, and may be used fully without qualification.
Ethylene Glycol (Method 8015)
All data are considered Class A as reported, and may be used fully without qualification.
U = compound was not detected above the associated value, however results should be considered
as estimated
J = positively identified, however, concentration should be considered as estimated.
Class A = quantitative Class B = qualitative Class C = unusable
Knhal-Fnrr & A.ssoriatPs -------------
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DAYIS
FLOYD
August 21, 2002
PEM CARTER
TICONA,LLC
2525 BLACKSBURG ROAD
HWY. 198
SHELBY, NC 28152
LABORATORY ANALYSIS REPORT
Login Number
Project Number
Description
:102080702
:61195.02
:GROUNDWATER
Dear Pem Carter:
We are pleased to provide the enclosed analytical results for the samples received by
Davis & Floyd, Inc. on August 07, 2002.
A formal Quality Assurance/Quality Control program is maintained by Davis & Floyd,
which is designed to meet or exceed the EPA, NELAC or other appropriate regulatory
requirements. All analytical analyses for this project met QA/QC criteria and the
results are within the 99 % confidence interval for each method unless otherwise
stated in the footnotes. This report is to be reproduced only in full.
Feel free to contact our Client Services Representative at [phone] if further
explanation of the analysis is required. Unless other arrangements have been made,
samples will be disposed of or returned 14 days from the date of the report. We
appreciate the opportunity to provide services to your firm.
Sincerely,
DA VIS & FLOYD, INC.
J H. McCord, Jr.
aboratory Manager
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] j Fax {864) 229-7119 ,. · '
1
Df\YIS
FLtrYD LABORATORY ANALYSIS REPORT
NELAC Certification Number: £87633
Master Tracking List
Client TICONA,LLC
2525 BLACKSBURG ROAD
HWY. 19B
SHELBY, NC 28152
Contact • PEM CARTER
Sample ID
L02060702-01
Gas Chromatography
SW846 8015
Volatile Organics
SW846 8260B
Wet Chemistry
SW846 9060
L02080702-02
Gas Chromatography
SW846 8015
Volatile Organics
SW846 8260B
wet Chemistry
SW846 9060
L02080702-03
Gas Chromatography
SW846 8015
Volatile Organics
SW846 8260B
Wet Chemistry
SW846 9060
L0:2080702-04'
Volatile Organics
SW846 82608
Client ID
ITEP'
ITEF DUP.
ITCI
NC Certification Number: 25
Project Number; 61195.02
Report Date
Page 1 of 3
August 21, 2002
Report ID: AA29215
Date Collected Date Received
05-AUG-02 11:00 07-AUG-02
08/07/02 1517
08/13/02 1136
08/07/02 0904
05-AUG-02 11:00 07-AUG-02
08/07/02 1543
08/13/02 1158
08/07 /02 0911
05-AUG-02 11:20 07-AUG-02
08/07/02 1610
08/13/02 1221
08/07/02 0924
07-AUG-02
08/12/02 1354
Davis & Floyd, Inc. j PO Drawer 428 1 Greenwood, SC 29648 I Bl 6 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
2
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DAYIS
FLOYD LABORATORY ANALYSIS REPORT
NELA C Certification Number: £87633
Master Tracking List
Client TICONA,LLC
2525 BLACKSBURG ROAD
HWY. 198
SHELBY, NC 28152
Contact. PEM CARTER
Sa.Jnple ID
L02080702-05
Volatile Organics
SW846 8260B
L02080702-06
Volatile Organics
SW846 8260B
L02080702-07
Volatile Organics
SW84.6 8260B
L02080702-08
volatile Organics
SW846 8260B
L02080702-09
Semi volatile organics
SW846 8270C
SW846 8270C DOWTHERM
volatile Organics
SW846 8260B
L02080702-10
Semi volatile Organics
SW846 8270C
SW846 8270C DOWTHERM
Volatile Organics
SW846 8260B
Client ID
HH-48
AA-54
T-35
GG-61
PEW-3
08/08/02
08/08/02
08/08/02
08/08/02
NC Certification Number: 25
Project Number: 61195.02
Report Date
Page 2 of 3
August 21, 2002
Report ID: AA29215
Date Collected Date Received
05-AUG-02 13:,s 07-AUG-02
08/12/02 1417
OS-AUG-02 15:15 07 -AUG-02
08/12/02 1440
OS-AUG-02 16:55 07-AUG-02
08/12/02 1503
05-AUG-02 18:40 07-AUG-02
08/12/02 1526
06-AUG-02 10:20 07-AUG-02
0800 08/15/02 1430
0800 08/15/02 1430
08/12/02 1548
06-AUG-02 10:50 07-AUG-02
0800 08/15/02 1714
0800 08/15/02 1714
08/12/02 1611
Davis & Floyd, Inc. I PO Drawer 428 j Greenwood, SC 29648 I 816 E. Ours! Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
3
DAYIS
FLOYD LABORATORY ANALYSIS REPORT
NELAC Certiftca1io11 Number: £87633
Master Tracking List
Client TICONA, LLC
2525 BLACKSBURG ROAD
HWY. 198
SHELBY, NC 28152
Contact • PEM CARTER
Sample ID
Volatile Organics
SW846 8260B
Semivolatile Organics
SW846 8270C
SW846 8270C DOWTHERM
Volatile Organics
SW846 8260B
L02080702-13
Volatile organics
SW846 8260B
Volatile Organics
SW846 8260B
L02080702-15
Volatile Organics
SW846 8260B
Wet Chemistry
SW846 9060
Client ID
C-49
l"-55
FP'-62
TRIP BLANK #1
BLANK
08/08/02
08/08/02
NC Certification Number: 25
Project Number: 61195.02
Report Date
Page 3 of 3
Date Collected
August 21, 2002
Report ID: AA29215
Date Received
06-AUG-02 12:50 07-AUG-02
08/12/02 1634
06-AUG-02 13:45 07-AUG-02
0800 08/15/02 1755
0800 08/16/02 0958
08/12/02 1851
06-AUG-02 15:35 07-AUG-02
08/12/02 1657
07-AUG-02
08/12/02 1309
05-AUG-02 17 I 15 07-AUG-02
08/12/02 1331
08/12/02 0953
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 816 E. Durst Avenue I Greenwood, SC 29649 I (864) 229-441 3 I F,ix {ll64) 229-7119
4
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Di\YIS
FLOYD LABORATORY ANALYSIS REPORT
NELAC Certification Number: £87633
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY. 198
SHELBY, NC 28152
PEM CARTER
Client ID: ITEP'
Matrix
Parameter
Gas Chromatography
SW846 8015
ETHYLENE GLYCOL
Volatile Organics
SW846 826GB
1,1,1-TRICHLOROETHANE
1,1,2,2-TETRACHLOROETHANE
1,1,2-TRICHLOROETHANE
1,1-DICHLOR~ETHANE
1,1-DICHLOROETHENE
1,2-DICHLOROETHANE
1,2-DICHLOROPROPANE
2-BUTANONE
2-HEXANONE
4-METHYL-2-PENTANONE
ACETONE
BENZENE
BROMODICHLOROMETHANE
BROMOFORM
BROMOMETHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLO RO ETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-DICHLOROETHENE
CIS-1,3-DICHLOROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-DICHLOROETHENE
TRANS-1,3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL)
GW/ChemW
Result
5.0
< 0 0010
< o. 0010
< 0 .0010
< 0 .0010
< o. 0010
< 0 .0010
< 0 .0010
< 0. 0050
< 0. 0050
< 0 .0050
< 0 . 0050
< 0 .0010
< 0 .0010
0.0026
< . 0010
< 0. 0010
< 0 .0010
< 0 .0010
< 0 . 0010
< 0 . 0010
0.0018
< 0.0010
< 0.0010
0.0014
< 0. 0010
< 0 .0010
< 0 .0010
< 0 . 0010
< 0 .0010
< 0 . 0010
< 0 .0010
< 0 .0010
< 0. 0010
< 0 .0010
< 0 .0020
NC Certification Number: 25
Project Number, 61195.02
Report Date August 21, 2002
Page 1 of 2 Report ID: M29216
Sample ID L02080702-01
Date Collected: 05-AUG-02 11 :00
Date Received 07-AUG 02
Qual RDL Units Analyst Date Time
5.0 mg/1 MGB 09/07/02 1517
0 .0010 mg/1 PAP 08/13/02 1136
o. 0010 mg/1 PAP 08/13/02 1136
0 .0010 mg/1 PAP 08/13/02 1136
0 .0010 mg/1 PAP 08/13/02 1136
0 .0010 mg/1 PAP 08/13/02 1136
0.0010 mg/1 PAP 08/13/02 1136
0 .0010 mg/1 PAP 08/13/02 1136
0 .0050 mg/1 PAP 08/13/02 1136
0 .0050 mg/1 PAP 08/13/02 1136
0 . 0050 mg/1 PAP 08/13/02 1136
0 .0050 mg/1 PAP 08/13/02 1136
0 .0010 mg/1 PAP 08/13/02 1136
0 .0010 mg/] PAP 08/13/02 1136
0.0010 mg/1 PAP 08/13/02 1136
o. 0 010 mg/ 1 PAP 08/13/02 1136
0 .0010 mg/1 PAP 08/13/02 1136
0 .0010 mg/1 PAP 08/13/02 1136
o. 0010 mg/1 PAP 08/13/02 1136
o. 0010 mg/1 PAP 08/13/02 1136
0 .0010 mg/1 PAP 08/13/02 1136
0 .0010 mg/1 PAP 08/13/02 1136
0 .0010 mg/1 PAP 08/13/02 1136
o. 0010 mg/I PAP 08/13/02 1136
0. 0010 mg/1 PAP 08/13/02 1136
0 .0010 mg/ 1 PAP 08/13/02 1136
0 .0010 mg/1 PAP OB/13/02 1136
0 .0010 mg/1 PAP 08/13/02 1136
0 .0010 mg/1 PAP 08/13/02 1136
0 .0010 mg/1 PAP 08/13/02 1136
0 .0010 mg/1 PAP 08/13/02 1136
0 .0010 mg/1 PAP 08/13/02 1136
o. 0010 mg/1 PAP 08/13/02 1136
0 .0010 mg/1 PAP 08/13/02 1136
0 .0010 mg/1 PAP 08/ 13/02 1136
o. 0020 mg/1 PAP 08/13/02 1136
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood. SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
5
DAYIS
FLt1YD LABORATORY ANALYSIS REPORT
NELAC Certification Number: £87633
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY. 198
SHELBY, NC 28152
PEM CARTER
Client ID: ITEF
Parameter
Wet Chemistry
SW846 9060
ORGANIC CARBON, TOTAL
NC Certification Number: 25
Project Number, 61195.02
Report Date
Page 2 of 2
Sample ID
Result Qual RDL
August 21, 2002
Report ID: AA29216
L02080702-0l
Unit& Analyst Date Time
20.5 5.0 mg/1 CLB 08/07/02 0904
Davi!> & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 01 6 E. Durst Avenue I Greenwood, SC 29649 j [phone] I Fax [phone]
6
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Df\YIS
FLMD LABORATORY ANALYSIS REPORT
NELAC Certification Number: £87633
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY. 198
SHELBY, NC 28152
PEM CARTER
Client ID: ITEF DUP.
Matrix
Parameter
Gas Chromatography
SW846 8015
ETHYLENE GLYCOL
Volatile Organics
SW846 8260D
1,1,1-TRICHLOROETHANE
1,1,2,2-TETRACHLOROETHANE
1,1,2-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
1,2-DICHLOROETHANE
1,2-DICHLOROPROPANE
2-BUTANONE
2-HEXANONE
4-METHYL-2-PENTANONE
ACETONE
BENZENE
BROMODICHLOROMETHANE
BROMOFORM
BROMOMETHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-DICHLOROETHENE
CIS-1,3-DICHLOROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-DICHLOROETHENE
TRANS-1,3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL)
GW/ChemW
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
Result
5.0
0 .0010
0. 0010
0 .0010
0 .0010
0. 0010
0 .0010
0 .0010
0 . 0050
0 . 0050
0 . 0050
0 .0050
o. 0010
0 . 0010
0 . 0010
0. 0010
0 .0010
o. 0010
0 .0010
0 .0010
0 . 0 010
0. 0010
0 .0010
0 . 0010
o. 0010
0. 0010
0 .0010
0 . 0010
o. 0010
0 .0010
0. 0010
0 .0010
0 .0010
o. 0010
0 . 0010
0. 0020
NC Certification Number: 25
Project Number: 61195.02
Report Date August 21, 2002
Page 1 of 2 Report ID: AA29217
Sample ID L02080702-02
Date Collected: 05-AUG-02 11: 00
Date Received 07-AUG-02
Qual RDL Units Analyst Date Time
5.0 mg/1 MGB 08/07/02 1543
0 .0010 mg/1 PAP 08/13/02 1158
0 .0010 mg/1 PAP 08/13/0? 1158
0 .0010 mg/1 PAP 08/13/02 1158
o. 0010 mg/1 PAP 08/13/02 1158
0. 0010 mg/1 PAP 08/13/02 1158
0 .0010 mg/1 PAP 08/13/02 ll!:i8
0. 0010 mg/1 PAP 08/13/02 1158
0 .0050 mg/1 PAP 08/13/02 1158
0 .0050 mg/1 PAP 08/13/02 1158
0. 0050 mg/1 PAP 08/13/02 1158
0. 0050 mg/1 PAP 08/13/02 1158
0.0010 mg/1 PAP 08/13/02 1158
0 .0010 mg/1 PAP 08/13/02 1158
o. 0010 mg/1 PAP 08/13/02 1158
0. 0010 mg/1 PAP 08/13/02 1158
0 .0010 mg/1 PAP 08/13/02 1158
0 .0010 mg/1 PAP 08/13/02 1158
0 . 0010 mg/1 PAP 08/13/02 115B
0 .0010 mg/1 PAP 08/13/02 1158
o. 0010 mg/1 PAP 08/13/02 1158
0 .0010 mg/1 PAP 08/13/02 1158
0 .0010 mg/1 PAP 08/13/02 1158
0 . 0010 mg/1 PAP 08/13/02 1158
0. 0010 mg/1 PAP 08/13/02 1158
0. 0010 mg/1 PAP 08/13/02 1158
0. 0010 mg/1 PAP 08/13/02 1158
0 .0010 mg/1 P•P 08/13/02 1158
0 .0010 mg/1 P•P 08/13/02 1158
o .. 0010 mg/1 PAP 08/13/02 1158
0 .0010 mg/1 PAP 08/13/02 1158
0. 0010 mg/1 PAP 08/13/02 1158
o. 0010 mg/1 PAP 08/13/02 1158
0 .0010 mg/1 P•P 08/13/02 1158
0 .0010 mg/1 P•P 08/13/02 1158
0. 0020 mg/1 PAP 08/13/02 1158
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
7
DAYIS
FLOYD LABORATORY ANALYSIS REPORT
NELA C Cenification Number: £87633
Client
Co:1tact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY. 198
SHELBY, NC 28152
PEM CARTER
Client ID: ITEF CUP.
Parameter
Wet Chemistry
SW846 9060
ORGANIC CARBON, TOTAL
Result
17.8
NC Certification Number: 25
Project Number: 61195.02
Report Date August 21, 2002
Page 2 of 2 Report ID: AA29217
Sample ID L02080702-02
Qual RDL Units Analyst Date Time
5.0 mg/1 CLE 08/07/02 0911
Davis & Floyd, Inc. j PO Dr,lwer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
8
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DAYIS
FL(j\'D LABORATORY ANALYSIS REPORT
NELAC Cenification Number: £87633
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY. 198
SHELBY, NC 28152
PEM CARTER
Client ID: ITCI
Matrix
Parameter
Gas Chromatography
SW846 8015
ETHYLENE GLYCOL
Volatile Organics
SW846 8260B
1,1,1-TRICHLOROETHANE
1,1,2,2-TETRACHLOROETHANE
1,1,2-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
1,2-0ICHLOROETHANE
1,2-DICHLOROPROPANE
2-BUTANONE
2 HEXANONE
4-METHYL-2 PENTANONE
ACETONE
BENZENE
BROMOOICHLOROMETHANE
BROMOFORM
BROMOMETHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-0ICHLOROETHENE
CIS-1,3-DICHLOROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-DICHLOROETHENE
TRANS-1,3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL)
GW/ChemW
Result
0 .0010
' o. 0010
' 0. 0010
' o. 0010
' o. 0010
' 0 .0010
' 0 .0010
0.026
' 0 .0050
' 0 .0050
0.12
0.031
' 0 . 0010
' 0 .0010
' 0 .0010
0.0061
' 0.0010
0. 017
' 0 .0010
' o. 0010
0.0016
O.OOH
' 0 . 0010
' 0 . 0010
' 0 .0010
' 0 .0010
< 0 .0010
' 0. 0010
0.0011
' 0.0010
' 0.0010
0.0037
' 0.0010
0.0015
0.0020
NC Cenification Number: 25
Project Number, 61195.02
Report Date August 21, 2002
Page 1 of 2 Report ID: AA2 9218
Sample ID L02080702-03
Date Collected: 05-AUG-02 11 :20
Date Received 07-AUG-02
Qual RDL Units Analyst Date Time
25.0 mg/1 MGB 08/07/02 1610
0 .0010 mg/1 PAP 08/13/02 1221
0 .0010 mg/1 PAP 08/13/02 1221
0 .0010 mg/1 PAP 08/13/02 1221
o. 0010 mg/1 PAP 08/13/02 1221
0 .0010 mg/1 PAP 08/13/02 1221
0. 0010 mg/1 PAP 08/13/02 1221
0 .0010 mg/1 PAP 08/13/02 1221
0. 0050 mg/1 PAP 08/13/02 1221
0 .0050 mg/1 PAP 08/13/02 1221
0. 0050 mg/1 PAP 08/13/02 1221
0 . 0050 mg/1 PAP 08/13/02 1221
0 .0010 mg/1 PAP 08/13/02 1221
0 . 0010 mg/1 PAP 08/13/02 1221
0 .0010 mg/1 PAP 08/13/02 1221
0. 0010 mg/1 PAP 08/13/02 1221
0.0010 mg/1 PAP 08/13/02 1221
0.0010 mg/1 PAP 08/13/02 1221
0.0010 mg/1 PAP 08/13/02 1221
0 .0010 mg/1 PAP 08/13/02 1221
0 .0010 mg/1 PAP 08/13/02 1221
0 . 0010 mg/1 PAP 08/13/02 1221
0. 0010 mg/1 PAP 08/13/02 1221
0 .0010 mg/1 PAP 08/13/02 1221
0 . 0010 mg/1 PAP 08/13/02 1221
0. 0010 mg/1 PAP 08/13/02 1221
0. 0010 mg/1 PAP 08/13/02 1221
o. 0010 mg/1 PAP 08/13/02 1221
0 .0010 mg/1 PAP 08/13/02 1221
0. 0010 mg/1 PAP 08/13/02 1221
0. 0010 mg/1 PAP 08/13/02 1221
0 .0010 mg/1 PAP 08/13/02 1221
o. 0010 mg/1 PAP 08/13/02 1221
0 .0010 mg/1 PAP 08/13/02 1221
0 .0010 mg/1 PAP 08/13/02 1221
0.0020 mg/1 PAP 08/13/02 1221
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue ! Greenwood, SC 29649 I [phone] I Fax [phone]
9
Di\YIS
·FLOYD LABORATORY ANALYSIS REPORT
NELAC Certification Number: £87633
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY. 198
SHELBY, NC 28152
PEM CARTER
Client I_D: ITCI
Parameter
We~ Chemistry
SW846 9060
ORGANIC CARBON, TOTAL
Result
1730
NC Certification Number: 25
Project Number, 61195.02
Report Date August 21, 2002
Page 2 of 2 Report ID: AA29218
Sample ID L02080702-03
Qual RDL Units Analyst Date Time
100 mg/1 CLB 08/07/02 0924
Davis & Floyd, Inc. ! PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I {864) 229-4413 I fax [phone]
10
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DAYIS
FLOYD LABORATORY ANALYSIS REPORT
NELAC Certification Number: £87633
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY. 198
SHELBY, NC 28152
PEI'-: CARTER
Client ID: HH-77
Matrix
Parameter
Volatile Organics
SW846 8260B
1,1,1-TRICHLOROETHANE
1,1,2,2-TETRACHLOROETHANE
1,1,2-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
1,2-DICHLOROETHANE
1,2-DICHLOROPROPANE
2-BUTANONE
2-HEXANONE
4-METHYL 2-PENTANONE
ACETONE
BENZENE
BROMODICHLOROMETHANE
BRQMOFORM
BROMOMETHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-DICHLOROETHENE
CIS-1,3-DICHLOROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-DICHLOROETHENE
TRANS-1,3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL)
GW/ChemW
Result
' 0. 0010
< 0 .0010
< 0 .0010
< 0 . 0010
0. 0010
< 0 .0010
< 0 .0010
' 0 .0050
< o. 0050
' 0. 0050
< 0 .0050
< 0 .0010
< 0 . 0010
< 0 . 0010
< 0. 0010
< 0 . 0010
< 0 . 0010
< 0 .0010
< o. 0010
< 0 . 0010
< 0 .0010
< 0 . 0010
< 0 . 0010
< o. 0010
< 0 .0010
< 0 .0010
0 . 0010
< o. 0010
< 0 . 0010
< 0 .0010
< 0 .0010
0 -46
< 0. 0010
< 0 .0010
< 0 .0020
NC Certification Number: 25
Project Number: 61195.02
Report Date
Page 1 of 1
Sample ID
August 21, 2002
Report ID: AA29221
L02080702 04
Date Collected: 05-AUG-02 12:55
Date Received 07-AUG-02
Qual RDL Units Analyst Date
0 .0010 mg/1 PAP 08/12/02
0 .0010 mg/1 PAP 08/12/02
o. 0010 mg/1 PAP 08/12/02
0 .0010 mg/1 PAP 08/12/02
0 .0010 mg/1 PAP 08/12/02
0. 0010 mg/1 PAP 08/12/02
o. 0010 mg/1 PAP 08/ 12/02
0 .0050 mg/1 PAP 08/12/02
0 .0050 mg/1 PAP 08/12/02
0. 0050 mg/1 PAP 08/12/02
0. 0050 mg/1 PAP 08/12/02
0 .0010 mg/1 PAP 08/12/02
0 .0010 mg/1 PAP 08/12/02
o . 0010 mg/1 PAP 08/ 12/02
o. 0010 mg/1 PAP 08/12/02
o . 0010 mg/1 PAP 08/12/02
0 . 0010 mg/1 PAP 08/12/02
0.0010 mg/1 PAP 08/12/02
0. 0010 mg/1 PAP 08/12/02
0. 0010 mg/1 PAP 08/12/02
o. 0010 mg/1 PAP 08/12/02
0 .0010 mg/1 PAP 08/12/02
0 .0010 mg/1 PAP 08/12/02
o. 0010 mg/1 PAP 08/12/02
o. 0010 mg/1 PAP 08/12/02
0. 0010 mg/1 PAP 08/12/02
0 .0010 mg/1 PAP OB/12/02
0 .0010 mg/1 PAP 08/12/02
o . 0010 mg/1 PAP 08/12/02
0 .0010 mg/1 PAP 08/12/02
0 .0010 mg/1 PAP 08/12/02
0 . 0040 mg/1 PAP 08/13/02
o. 0010 mg/1 PAP 08/12/02
o. 0010 mg/1 PAP 08/12/02
0. 0020 mg/1 PAP 08/12/02
Time
1354
1354
1354
1354
1354
1354
1354
1354
1354
1354
1354
1354
1354
1354
1354
1354
1354
1354
1354
1354
1354
1354
1354
1354
1354
1354
1354
1354
1354
1354
1354
0849
1354
1354
1354
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 \ 816 f.. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
11
DAYIS
FLt1YD LABORATORY ANALYSIS REPORT
NELAC Certification Number: £87633
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY. 198
SHELBY, NC 25152
PEM CARTER
Client ID: HH-48
Matrix
Parameter
Volatile Organics
SW846 8260B
1,1,1-TRICHLOROETHANE
1 , l, 2 , 2 -TETRACHLOROETIW>IE
1,1,2-TRICHLOROETHAN'E
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
1,2-DICHLOROETHANE
1,2-DICHLOROPROPANE
2-BUTANONE
2-HEXANONE
4-METHYL-2-PENTANONE
ACETONE
BENZENE
BROMODICHLOROMETHANE
BROMOFORM
BROMOMETHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-DICHLOROETHENE
CIS-1,)-DICHLOROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-DICHLOROETHENE
TRANS-1,3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL)
GW/ChemW
Result
< 0. 0010
< 0 . 0010
< o. 0010
< 0 . 0010
< o. 0010
< 0 . 0010
< 0. 0010
< o. 0050
< 0 .0050
< 0 . 0050
< o. 0050
< 0 .ooio
< o. 0010
< 0. 0010
< 0 . 0010
< 0. 0010
< o. 0010
< o. 0010
< 0.0010
< o. 0010
< o. 0010
< 0. 0010
< o. 0010
< o. 0010
< 0. 0010
o. 0010
< o. 0010
< o. 0010
< o. 0010
< o. 0010
< 0. 0010
0.13
< 0 .0010
< 0 . 0010
< o. 0020
NC Certification Number: 25
Project Number: 61195.02
Report Date August 21, 2002
Page 1 of 1 Report ID: AA29222
Sample ID L02080702-05
Date Collected, OS-AUG-02 13; 45
Date Received 07-AUG-02
Qual RDL Units Analyst Date Time
0 .0010 mg/1 PAP 08/12/02 1417
0. 0010 mg/1 PAP 08/12/02 1417
0 . 0010 mg/1 PAP 08/12/02 1417
0 . 0010 mg/1 PAP 08/12/02 1417
0 .0010 mg/1 PAP 08/12/02 1417
o . 0010 mg/1 PAP 08/12/02 1417
0 . 0010 mg/1 PAP 08/12/02 1417
o. 0050 mg/1 PAP 08/12/02 1417
0 .0050 mg/1 PAP 08/12/02 1417
0 . 0050 mg/1 PAP 08/12/02 1417
0.0050 mg/1 PAP 08/12/02 1417
0. 0010 mg/1 PAP 08/12/02 1417
0 . 0010 mg/1 PAP 08/12/02 1417
0 . 0010 mg/1 PAP 08/12/02 1417
0 . 0010 mg/1 PAP 08/12/02 1417
0. 0010 mg/1 PAP 08/12/02 141 7
0.0010 mg/1 PAP 08/12/02 1417
0 . 0010 mg/1 PAP 08/12/02 1417
0. 0010 mg/1 PAP 08/12/02 141 7
0 .0010 mg/1 PAP 08/12/02 1417
0.0010 mg/1 PAP 08/12/02 1417
0. 0010 mg/1 PAP 08/12/02 1417
0 .0010 mg/1 PAP 08/12/02 1417
0. 0010 mg/1 PAP 08/12/02 1417
0 .0010 mg/1 PAP 08/12/02 1417
o. 0010 mg/1 PAP 08/12/02 141 7
o. 0010 mg/1 PAP 08/12/02 1417
0. 0010 mg/1 PAP 08/12/02 1417
o. 0010 mg/1 PAP 08/12/02 1417
0 .0010 mg/1 PAP 08/12/02 1417
o. 0010 mg/1 PAP 08/12/02 1417
0 .0010 mg/1 PAP 08/12/02 1417
o. 0010 mg/1 PAP 08/12/02 1417
o. 0010 mg/1 PAP 08/12/02 1417
o. 0020 mg/1 PAP 08/12/02 1417
Davis & Floyd, Inc. I PO Drawer 428 ! Greenwood, SC 29648 · I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
12
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Df\YIS
FLOYD LABORATORY ANALYSIS REPORT
NELAC Cenification Number: £87633
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY. 198
SHELBY, NC 28152
PEM CARTER
Client ID: AA-54
Matrix
Parameter
Volatile Organics
SW846 8260B
1,1,1-TRICHLOROETHANE
1,1,2,2-TETRACHLOROETHANE
1,1,2-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
1,2-DICHLOROETHANE
1,2-DICHLOROPROPANE
2-BUTAN0NE
2-HEXANONE
4-METHYL-2-PENTANONE
ACETONE
BENZENE
BROMODICHLOROMETHANE
BROMOFORM
BROMOMETHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-DICHLOROETHENE
CIS-1,3-DICHLOROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-DICHLOROETHENE
TRANS-1,3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL)
GW/Chemw
<
<
'
'
<
' <
'
' <
<
<
' <
'
'
<
<
'
<
<
<
'
' <
<
'
'
<
'
'
Result
0 .0010
0 .0010
0 .0010
0 .0010
0 . 0010
o. 0010
o. 0010
0 .0050
o. 0050
0. 0050
o. 0050
0 .0010
0 .0010
0 . 0010
0 .0010
o. 0010
0. 0010
o. 0010
0 . 0010
0 .0010
0 .0010
o. 0010
0. 0010
0.0010
0 . 0010
0 .0010
0 .0010
o. 0010
0 .0010
0 . 0010
0 .0010
0 .0010
0 .0010
0 .0010
0 . 0020
NC Cenijication Number: 25
Project Number: 61195.02
Report Date August 21, 2002
Page 1 of 1 Report ID: AA29223
Sample ID L02080702-06
Date Collected: 05-AUG-02 15: 15
Date Received 07 -AUG-02
Qual RDL Units Analyst Date Time
0 .0010 mg/1 PAP 08/12/02 1440
0 .0010 mg/1 PAP 08/12/02 1440
0 .0010 mg/1 PAP 08/12/02 14 4 0
0 .0010 mg/1 PAP 08/12/02 14 4 0
o. 0010 mg/1 PAP 08/12/02 144 0
o. 0010 mg/1 PAP 08/12/02 1440
0. 0010 mg/1 PAP 08/12/02 1440
o. 0050 mg/1 PAP 08/12/02 14 4 0
o. 0050 mg/1 PAP 08/12/02 1440
0 .0050 mg/1 PAP 08/12/02 1440
0 . 0050 mg/1 PAP 08/12/02 1440
o. 0010 mg/1 PAP 08/12/02 14 4 0
0. 0010 mg/1 PAP 08/12/02 14 40
0 . 0010 mg/1 PAP 08/12/02 1440
0 .0010 mg/1 PAP 08/12/02 1440
0 .0010 mg/1 PAP 08/12/02 14 4 0
0. 0010 mg/1 PAP 08/12/02 14 40
0 .0010 mg/1 PAP 08/12/02 1440
o. 0010 mg/1 PAP 08/12/02 1440
o. 0010 mg/1 PAP 08/12/02 1440
0 .0010 mg/1 PAP 08/12/02 1440
0 . 0010 mg/1 PAP 08/12/02 1440
0. 0010 mg/1 PAP 08/12/02 1440
0. 0010 mg/1 PAP 08/12/02 1440
0 . 0010 mg/1 PAP 08/12/02 1440
0 .0010 mg/1 PAP 08/12/02 144 0
0.0010 mg/1 PAP 08/12/02 1440
0 .0010 mg/1 PAP 08/12/02 1440
0 .0010 mg/1 PAP 08/12/02 144 0
0 . 0010 mg/1 PAP 08/12/02 144 0
0. 0010 mg/1 PAP 08/12/02 144 0
0 .0010 mg/1 PAP 08/12/02 1440
0 .0010 mg/1 PAP 08/12/02 1440
0 . 0010 mg/1 PAP 08/12/02 1440
o . 0020 mg/1 PAP 08/12/02 144 0
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Gretmwood, SC 29649 I [phone] I Fax [phone]
13
Di\YIS
FLt1YD LABORATORY ANALYSIS REPORT
NELAC Certification Number: £87633
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY. 198
SHELBY, NC 28152
PEM CARTER
Client ID: T-35
Parameter
Volatile Organics
SW846 8260B
Matrix
1,1, I-TRICHLOROETHANE
1,1,2,2-TETRACHLOROETHANE
1,1,2-TRICHLOROETHANE
1,1-0ICHLOROETHANE
1,1-DICHLOROETHENE
1,2-DICHLOROETHANE
1,2-DICHLOROPROPANE
2-BUTANONE
2-HEXANONE
4-METHYL-2-PENTANONE
ACETONE
BENZENE
BROMODICHLOROMETHANE
BROMOFORM
BROMOMETHANE
CARaoN DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-DICHLOROETHENE
CIS-1,3-DICHLOROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-DICHLOROETHENE
TRANS-1,3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL)
GW/ChemW
Result
< o. 0010
< o. 0010
< 0 . 0010
< 0 .0010
< 0 . 0010
0.0012
< o. 0010
< o. 0050
< o. 0050
< 0. 0050
< 0 .0050
0.0012
< 0 .0010
< 0 .0010
< 0 . 0010
< 0 .0010
< 0 . 0010
< o. 0010
< o. 0010
< 0 .0010
0.0030
< 0.0010
< 0.0010
< 0.0010
< 0 .0010
< 0 .0010
< 0 . 0010
< 0 .0010
< 0. 0010
< o. 0010
< o. 0010
0.0016
< 0.0010
< 0 .0010
0 .0020
NC Certification Number: 25
Project Number: 61195.02
Report Date
Page 1 of 1
Sample ID
August 21, 2002
Report ID: M29219
L02 08 07 02 -07
Date Collected: 05-AUG-02 16:55
Date Received 07-AUG-02
Qual RDL Units Analyst Date
0 .0010 mg/1 PAP 08/12/02
0 . 0010 mg/1 PAP 08/12/02
0 . 0010 rng/1 PAP 08/12/02
0 . 0010 mg/1 PAP 08/12/02
0 . 0010 mg/1 PAP 08/12/02
0 .0010 mg/1 PAP 08/12/02
0 .0010 mg/1 PAP 08/12/02
0 . 0050 mg/1 PAP 08/12/02
0 .0050 mg/1 PAP 08/12/02
0 .0050 mg/1 PAP 08/12/02
0 .0050 mg/1 PAP 08/12/02
0. 0010 mg/1 PAP 08/12/02
0 .0010 mg/1 PAP 08/12/02
0 . 0010 mg/1 PAP 08/12/02
0 .0010 mg/1 PAP 08/12/02
0 .0010 mg/1 PAP 08/12/02
0 . 0010 mg/1 PAP 08/12/02
0 .0010 mg/1 PAP 08/12/02
0 .0010 mg/1 PAP 08/12/02
0 .0010 mg/1 PAP 08/12/02
0.0010 mg/1 PAP 08/12/02
0 .0010 mg/1 PAP 08/12/02
0 .0010 mg/1 PAP 08/12/02
0 .0010 mg/1 PAP 08/12/02
0 .0010 mgi, PAP 08/12/02
0 .0010 mg/1 PAP 08/12/02
o. 0010 mg/1 PAP 08/12/02
o. 0010 mg/1 PAP 08/12/02
0.0010 mg/1 PAP 08/12/02
0. 0010 mg/1 PAP 08/12/02
0 .0010 mg/1 PAP 08/12/02
0 .0010 mg/1 PAP 08/12/02
0 .0010 mg/1 PAP 08/12/02
o. 0010 mg/1 PAP 08/12/02
0 .0020 mg/1 PAP 08/12/02
Time
1503
1503
1503
150]
1503
1503
1503
1503
1503
1503
1503
1503
1503
1503
1503
1503
1503
1503
1503
1503
1503
1503
1503
1503
1503
1503
1503
1503
1503
1503
1503
1503
1503
1503
1503
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Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 ! 816 E. Durst Avenue ! Greenwood, SC 29649 I (8fi4) 229-4413
14
I Fa, (8641 229-7119 I
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DAYIS
FLOYD LABORATORY ANALYSIS REPORT
NELAC Certification Number: £87633
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY. 198
SHELBY, NC 28152
PEM CARTER
Client ID: GG-61
Matrix
ParAineter
Volatile Organics
SW846 8260B
1,1,1-TRICHLOROETHANE
1,1,2,2-TETRACHLOROETHANE
1,1,2-TRICHLOROETHANE
1,1-0ICHLOROETHANE
1,1-DICHLOROETHENE
1,2-DICHLOROETHANE
1,2-0ICHLOROPROPANE
2 BUTANONE
2-HEXANONE
4-METHYL-2-PENTANONE
ACETONE
BENZENE
BROMODICHLOROMETHANE
BROMOFORM
BROMOMETHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-DICHLOROETHENE
CIS-1,3-DICHLOROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-DICHLOROETHENE
TRANS-1,3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL)
GW/Chemw
Result
' 0 .0010
' o. 0010
' 0. 0010
' 0 . 001 0
' 0 .0010
0 .0010
0 .0010
' 0 .0050
' 0 . 0050
0. 0050
' 0 . 0050
' 0. 0010
0. 0010
' 0 .0010
' 0. 0010
' 0.0010
' 0 . 0010
' 0 . 0010
0. 0010
' o. 0010
' 0. 0010
' 0 . 0010
' 0. 0010
' 0 .0010
' 0 . 0010
' 0 . 0010
' 0. 0010
0 .0010
' 0 . 0010
' 0. 0010
' 0. 0010
' 0. 0010
' 0 .0010
' 0 . 0010
' 0 . 0020
NC Certification Number: 25
Project Number: 61195.02
Report Date
Page 1 of 1
Sample ID
August 21, 2002
Report ID: AA29220
L02080702-08
Date Collected: 05-AUG-02 18:40
Date Received 07-AUG-02
Qual RDL Units Analyst Date
0 .0010 mg/1 PAP 08/12/02
0 .0010 mg/1 PAP 08/12/02
0 .0010 mg/1 PAP 08/12/02
0 .0010 mg/1 PAP 08/12/02
0 .0010 mg/1 PAP 08/12/02
0. 0010 mg/1 PAP 0B/12/02
0 . 0010 mg/1 PAP 0B/12/02
0 .0050 mg/1 PAP 08/12/02
0 .0050 mg/1 PAP 08/12/02
o. 0050 mg/1 PAP 08/12/02
0 .ooso mg/1 PAP 08/12/02
0 .0010 mg/1 PAP 08/12/02
o. 0010 mg/1 PAP 0B/12/02
0 .0010 mg/1 PAP 08/12/02
0 . 0010 mg/1 PAP 08/12/02
0 .0010 mg/1 PAP 08/12/02
0 .0010 mg/1 PAP 08/12/02
o . 0010 mg/1 PAP 08/12/02
o. 0010 mg/1 PAP 08/12/02
0.0010 mg/1 PAP 08/12/02
0 . 0010 mg/1 PAP 08/12/02
0. 0010 mg/1 PAP 08/12/02
0 .0010 mg/1 PAP 08/12/02
0 . 0010 mg/1 PAP 08/12/02
0. 0010 mg/1 PAP 08/12/02
o. 0010 mg/1 PAP 08/12/02
0 . 0010 mg/1 PAP 08/12/02
0 .0010 mg/1 PAP 08/12/02
0 .0010 mg/1 PAP 08/12/02
0. 0010 mg/1 PAP OB/12/02
0 . 0010 mg/1 PAP 08/12/02
0 .0010 mg/1 PAP 08/12/02
0 .0010 mg/1 PAP 08/12/02
0 . 0010 mg/1 PAP 08/12/02
0 . 0020 mg/1 PAP 08/12/02
Time
1526
1526
1526
1526
1526
1526
1526
1526
1526
1526
1526
1526
1526
1526
1526
152 6
1526
1526
1526
1526
1526
1526
1526
1526
1526
1526
1526
1526
1526
1526
1526
1526
1526
1526
1526
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
15
Di\YIS
FLOYD LABORATORY ANALYSIS REPORT
NELAC Certification Number: £87633
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY. 198
SHELBY, NC 28152
PEM CARTER
Client ID: PEW-1
Matrix GW/ChemW
Parruneter
Semivolatile Organics
Sk'S46 8270C
1,2,4-TRICHLOROBENZENE
1,2-DICHLOROBENZENE
1,3-DICHLOROBENZENE
1,4-DICHLOROBENZENE
2,4,5-TRICHLOROPHENOL
2,4,6-TRICHLOROPHENOL
2,4-DICHLOROPHENOL
2,4-DIMETHYLPHENOL
2,4-DINITROPHENOL
2,4-0INITROTOLUENE
2,6-DINITROTOLUENE
2-CHLORONAPHTHALENE
2-CHLOROPHENOL
2-METHYL-4,6-DINITROPHENOL
2-METHYLNAPHTHALENE
2-METHYLPHENOL
2-NITROANILINE
2-NITROPHENOL
3,3'-DICHLOROBENZIDINE
3-NITROANILINE
4-BROMOPHENYL PHENYL ETHER
4-CHLOR0-3-METHYLPHENOL
4-CHLOROANILINE
4-CHLOROPHENYL PHENYL ETHER
4-METHYLPHENOL
4-NITROANILINE
4-NITROPHENOL
ACENAPHTHENE
ACENAPHTHYLENE
ANTHRACENE
BENZO(A)ANTHRACENE
BENZO (A} PYRENE
BENZO(B)FLUORANTHENE
BENZO(G,H,I)PERYLENE
BENZO(K)FLUORANTHENE
BENZOIC ACID
BENZYL ALCOHOL
B15(2-CHLOROETHOXY)METHANE
BIS(2-CHLOROETHYL)ETHER
BIS(2-CHLOROISOPROPYL)ETHER
Davis&· Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648
Result
' 0. 010
' o. 010
' 0 .010
o. 010
' 0. 010
' o. 010
' o. 010
' 0. 010
' 0.025
' 0. 010
' 0. 010
' 0. 010
' 0. 010
' 0. 025
' 0 .010
' o. 010
' 0 .010
' 0 . 010
' 0.010
' o. 010
' 0 .010
' o. 010
' 0.010
' 0 . 010
' o. 010
' 0 .010
' 0. 025
' 0 .010
' 0 .010
' o. 010
' o. 010
' 0 .010
' 0 . 010
' 0. 010
' 0 .010
' 0 .050
' 0. 010
' 0. 010
' 0. 010
0 . 010
816 E. Durst Avenue
16
NC Certification Number: 25
Project Number: 61195.02
Report Date
Page 1 of 3
August 21, 2002
Report ID: AA29225
Sample ID L02080702-09
Date Collected: 06-AUG-02_ 10:20
Date Received 07-AUG-02
Qual RDL Units Analyst Date
0. 010 mg/1 JRN 08/15/02
o. 010 mg/1 JRN 08/15/02
0. 010 mg/1 JRN 08/15/02
0 .010 mg/1 JRN 08/15/02
0 .010 mg/1 JRN 08/15/02
o. 010 mg/1 JRN 08/15/02
0. 010 mg/1 JRN 08/15/02
0 .010 mg/1 JRN 08/15/02
0 .025 mg/1 JRN 08/15/02
C. 010 mg/1 JRN 08/15/02
0 .010 mg/1 JRN 08/15/02
0 .010 mg/1 JRN 08/15/02
0 .010 mg/1 JRN 08/15/02
0 .025 mg/1 JRN 08/15/02
0 .010 mg/1 JRN 08/15/02
0 .010 mg/1 JRN 08/15/02
0 .010 mg/1 JRN 08/15/02
o . 010 mg/1 JRN 08/15/02
0 .010 mg/1 JRN 08/15/02
0 .010 mg/1 JRN 08/15/02
0 .010 mg/1 JRN 08/15/02
0 .010 mg/1 JRN 08/15/02
0 .010 mg/1 JRN 08/15/02
o . 010 mg/1 JRN 08/15/02
o. 010 mg/1 JRN 08/15/02
0 .010 mg/1 JRN 08/15/02
0 .025 mg/1 JRN 08/15/02
0 .010 mg/1 JRN 08/15/02
0 .010 mg/1 JRN 08/15/02
o. 010 mg/1 JRN 08/15/02
0 .010 mg/1 JRN 08/15/02
0 .010 mg/1 JRN 08/15/02
0 . 010 mg/1 JRN 08/15/02
0 .010 mg/1 JRN 08/15/02
0 .010 mg/1 JRN 08/15/02
0 .050 mg/1 JRN 08/15/02
0 .010 mg/1 JRN 08/15/02
0 .010 mg/1 JRN 08/15/02
o. 010 mg/1 JRN 08/15/02
o . 010 mg/1 JRN 08/15/02
Time
1430
1430
1430
1430
1430
1430
1430
1430
1430
1430
1430
14 3 0
1430
1430
1430
1430
143 0
1430
1430
1430
1430
1430
1430
1430
1430
1430
1430
1430
1430
143 0
1430
1430
1430
14 3 0
1430
1430
143 0
1430
1430
1430
Greenwood, SC 2%49 I 18641 229-4413 I Fax [phone]
I
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DAYIS
FLOYD LABORATORY ANALYSIS REPORT
NELAC Certification Number: £87633
Client TICONA,LLC
Contact
2525 BLACKSBURG ROAD
HWY. 19B
SHELBY, NC 28152
PEM CARTER
Client ID: PEW-l
Paraineter
BIS(2-ETHYLHEXYL)PHTHALATE
BUTYL BENZYL PHTHALATE
CHRYSENE
DI-N-BUTYL PHTHALATE
DI-N-OCTYL PHTHALATE
DIBENZ(A,H)ANTHRACENE
DIBENZOFURAN
DIETHYL PHTHALATE
DIMETHYL PHTHALATE
F'LUORANTHENE
FLUORENE
HEXACHLOROBENZENE
HEXACHLOROBUTADIENE
HEXACHLOROCYCLOPENTADIENE
HEXACHLOROETHANE
INDENO(l,2,3-CD)PYRENE
ISOPHORONE
N-NITROSODI-N-PROPYLAMINE
N-NITROSODIPHENYLAMINE
NAPHTHALENE
NITROBENZENE
PENTACHLOROPHENOL
PHENANTHRENE
PHENOL
PYRENE
SW846 8270C DOWTHERM
1,1'-BIPHENYL
BIPHENYL ETHER
Volatile Organics
SW846 8260B
1,1,1-TRICHLOROETHANE
1,1,2,2-TETRACHLOROETHANE
1,1,2-TRICHLOROETHANE
1,1-0ICHLOROETHANE
1,1-DICHLOROETHENE
1,2-0ICHLOROETHANE
1,2-DICHLOROPROPANE
2-BUTANONE
2-HEXANONE
4-METHYL-2-PENTANONE
ACETONE
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
'
'
'
<
Result
o. 010
0. 010
o. 010
0 .010
0 .010
0 .010
o. 010
o. 010
o. 010
o. 010
0 .010
0 .010
0 .010
o. 010
o. 010
0. 010
o. 010
0 .010
0 .010
0 .010
0. 010
0 . 025
0 .010
0 .010
o. 010
o. 010
o. 010
0 .0010
0 .0010
0 .0010
0. 0010
0 . 0010
0 .0010
o. 0010
0.0050
0 .0050
0 .0050
0 .0050
NC Certification Number: 25
Project Number: 61195.02
Report Date August 21, 2002
Page 2 of 3 Report ID: AA29225
Sample ID L02080702 -09
Qual ROL Units Analyst Date Time
o. 010 mg/1 JRN 08/15/02 1430
0. 010 mg/1 JRN 08/15/02 1430
0 .010 mg/1 JRN 08/15/02 1430
0 .010 mg/1 JRN 08/15/02 1430
0 .010 mg/1 JRN 08/15/02 1430
0 .010 mg/1 JRN 08/15/02 1430
0 .010 mg/1 JRN 08/15/02 1430
0 .010 mg/1 JRN 08/15/02 14 3 0
0 .010 mg/1 JRN 08/15/02 14 3 0
o. 010 mg/1 JRN 08/15/02 1430
o. 010 mg/1 JRN 08/15/02 1430
0 .010 mg/1 JRN 08/15/02 1430
0 .010 mg/1 JRN 08/15/02 1430
0 .010 mg/1 JRN 08/15/02 1430
0 .010 mg/1 JRN 08/15/02 14 3 0
0 .010 mg/1 JRN 08/15/02 1430
0 .010 mg/1 JRN 08/15/02 1430
o. 010 mg/1 JRN 08/15/02 1430
0 .010 mg/1 JRN 08/15/02 143 0
0 .010 mg/1 JRN 08/15/02 14 3 0
0 .010 mg/1 JRN 08/15/02 1430
o . 025 mg/1 JRN 08/15/02 1430
0. 010 mg/1 JRN 08/15/02 1430
0 .010 mg/1 JRN 08/15/02 1430
0 .010 mg/1 JRN 08/15/02 1430
0 .010 mg/1 JRN 08/15/02 1430
0 .010 mg/1 JRN 08/15/02 1430
0 .0010 mg/1 PAP 08/12/02 1548
0 . 0010 mg/1 PAP 08/12/02 1548
0 .0010 mg/1 PAP 08/12/02 1548
0 .0010 mg/1 PAP 08/12/02 1548
o. 0010 mg/1 PAP 08/12/02 1548
0 .0010 mg/1 PAP 08/12/02 1548
0 .0010 mg/1 PAP 08/12/02 1548
.0050 mg/1 PAP 08/12/02 154 8
0 .0050 mg/1 PAP 08/12/02 1548
o. 0050 mg/1 PAP 08/12/02 1548
0 .0050 mg/1 PAP 08/12/02 1548
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 t. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
1 7
DAYIS
FLOYD LABORATORY ANALYSIS REPORT
NELAC Cerrijication Number: £87633
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY. 198
SHELBY, NC 28152
PEM CARTER
Client ID: PEW-1
Parameter
BENZENE
BROMODICHLOROMETHANE
BROMOFORM
BROMOMETHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-DICHLOROETHENE
CIS-1,3-0ICHLOROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-DICHLOROETHENE
TRANS-1,3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL)
Prop Procedure
Analytical Prep Procedures:
BNA SEMIVOLATILES
OOWTHERM
Method
SW846 35008
SW846 3500B
Result
0.0021
< 0 .0010
< o. 0010
< 0 . 0010
0. 0010
< 0 .0010
< 0 .0010
< 0. 0010
0.0022
< 0.0010
0.0014
< 0 . 0010
< 0 . 0010
< o. 0010
< 0 . 0010
< 0. 0010
< 0. 0010
< 0. 0010
< o. 0010
< o. 0010
0.0062
< 0 . 0010
< o. 0010
< o. 0020
Analyst Prep Date
DBC 08/08/02
DBC 08/08/02
NC Cerrification Number: 25
Project Number: 61195.02
Report Date August 21, 2002
Page 3 of 3 Report ID: AA29225
Sample ID L02080702~09
Qual RDL Units Analyst Date Time
0.0010 mg/1 PAP 08/12/02 1548
0 .0010 mg/1 PAP 08/12/02 1548
0 .0010 mg/1 PAP 08/12/02 154 8
o . 0010 mg/1 PAP 08/12/02 1548
0. 0010 mg/1 PAP 08/12/02 1548
o. 0010 mg/1 PAP 08/12/02 1548
0 . 0010 mg/1 PAP 08/12/02 1548
0 .0010 mg/1 PAP 08/12/02 1548
0 .0010 mg/1 PAP 08/12/02 1548
0. 0010 mg/J PAP 08/12/02 154 8
0.0010 mg/1 PAP 08/12/02 154 8
0. 0010 mg/1 PAP 08/12/02 154 8
o . 0010 mg/1 PAP 08/12/02 154 8
0. 0010 mg/1 PAP 08/12/02 1548
0 . 0010 mg/1 PAP 08/12/02 1548
0 . 0010 mg/1 PAP 08/12/02 1548
0 . 0010 mg/1 PAP 08/12/02 1548
0 .0010 mg/1 PAP 08/12/02 1548
0 .0010 mg/1 PAP 08/12/02 1'54 8
0. 0010 mg/1 PAP 08/12/02 1548
o. 0010 mg/1 PAP 08/12/02 1548
o . 0010 mg/1 PAP 08/12/02 1548
0. 0010 mg/1 PAP 08/12/02 1548
0 . 0020 mg/1 PAP 08/12/02 1548
0800
0800
Davis & Floyd, Inc. 1 PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax {864) 229-7119
18
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Di\VIS
FLtfYD LABORATORY ANALYSIS REPORT
NELAC Certification Number: £87633
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY. 198
SHELBY, NC 28152
PEM CARTER
Client ID: PBW-3
Matrix GW/ChemW
Parameter
Semivolatile Organics
SW846 8270C
1,2,4-TRICHLOROBENZENE
1,2-DICHLOROBENZENE
1,3-DICHLOROBENZENE
1,4-DICHLOROBENZENE
2,4,5-TRICHLOROPHENOL
2,4,6-TRICHLOROPHENOL
2,4-DICHLOROPHENOL
2,4-DIMETHYLPHENOL
2,4-DINITROPHENOL
2,4-DINITROTOLUENE
2,6-DINITROTOLUENE
2-CHLORONAPHTHALENE
2-CHLOROPHENOL
2-METHYL-4,6-DINITROPHENOL
2-METHYLNAPHTHALENE
2-METHYLPHENOL
2-NITROANILINE
2-NITROPHENOL
3,3'-DICHLOROBENZIDINE
3-NITROANILINE
4-BROMOPHENYL PHENYL ETHER
4-CHLOR0-3-METHYLPHENOL
4-CHLOROANILINE
4-CHLOROPHENYL PHENYL ETHER
4-METHYLPHENOL
4-NITROANILINE
4-NITROPHENOL
ACENAPHTHENE
ACENAPHTHYLENE
A.NTHRACENE
BENZO(A)ANTHRACENE
BENZO(A)PYRENE
BENZO(B)FLUORANTHENE
BENZO(G,H,I)PERYLENE
BENZO(K)FLUORANTHENE
BENZOIC ACID
BENZYL ALCOHOL
BIS(2-CHLOROETHOXY)METHANE
BIS(2 CHLOROETHYL)ETHER
BIS(2-CllLOROISOPROPYL)ETHER
Davis & Floyd, Inc. j PO Drawer 428 I Greenwood, SC 29648
Result
< 0 .010
o. 010
0 .010
0, 010
0 .010
0. OlO
o. 010
< 0.010
< 0. 025
< 0 .010
0, 010
o. 010
< o. 010
< o. 025
< o, 010
< 0. 010
< 0 .010
0 .010
0 .010
< o. 010
< o, 010
< 0 .010
< 0 .010
< 0 . 010
< 0 .010
< 0. 010
< 0 . 025
0 .010
< 0 .010
o. 010
< 0, 010
< 0 .010
0 .010
< 0 .010
< 0 .010
< 0 .050
< o. 010
< 0 .010
0 .010
< 0. 010
816 E. Durst Avenue
19
NC Certification Number: 25
Project Number: 61195.02
Report Date August 21, 2002
Page l of 3 Report 10: AA29224
Sample ID L02080702-10
Date Collected: 06-AUG-02 10: 50
Date Received 07-AUG-02
Qual RDL Units Analyst Date Time
0, 010 mg/1 JRN 08/15/02 1714
o. 010 mg/1 JRN 08/15/02 1714
0, 010 mg/1 JRN 08/15/02 1714
0, 010 mg/1 JRN 08/15/02 1711
0. 010 mg/1 JRN 08/15/02 1714
0 .010 mg/1 JRN 08/15/02 1714
0 .010 mg/1 JRN 08/15/02 1714
0 .010 mg/1 JRN 08/15/02 1714
0 . 025 mg/1 JRN 08/15/02 1714
0, 010 mg/1 JRN 08/15/02 1714
0. 010 mg/1 JRN 08/15/02 1 714
o. 010 mg/1 JRN 08/15/02 1714
0 .010 mg/1 JRN 08/15/02 1114
0, 025 mg/1 JRN 08/15/02 1714
o. 010 mg/1 JRN 08/15/02 1714
0 .010 mg/1 JRN 08/15/02 1714
0 .010 mg/1 JRN 08/15/02 1714
0 .010 mg/1 JRN 08/15/02 1714
0 .010 mg/1 JRN 08/15/02 1714
0 .010 mg/1 JRN 08/15/02 1714.
0, 010 mg/1 JRN 08/15/02 1714
o. 010 mg/1 JRN 08/15/02 1714
0 .010 mg/1 JRN 08/ 15/02 1714
0 .010 mg/1 JRN 08/15/02 1714
0 .010 mg/1 JRN 08/15/02 1714
o. 010 mg/1 JRN 08/15/02 1714
0 . 025 mg/1 JRN 08/15/02 1714
o. 010 mg/1 JRN 08/15/02 1714
0. 010 mg/1 JRN 08/15/02 1714
0 .010 mg/1 JRN 08/15/02 1714
o. 010 mg/1 JRN 08/15/02 1714
0 .010 mg/1 JRN 08/15/02 1714
0 .010 mg/1 JRN 08/15/02 1714
0 .010 mg/1 JRN 08/15/02 1714
0 .010 mg/1 JRN 08/15/02 1714
o. 050 mg/1 JRN 08/15/02 1714
0 .010 mg/1 JRN 08/15/02 1714
0 .010 mg/1 JRN 08/15/02 1714
0 .010 mg/1 JRN 08/15/02 1714
0 .010 mg/1 JRN 08/15/02 1714
Greenwood. SC 29649 I IH&41229-441 3 I Fax [phone]
DAYIS
FLOYD LABORATORY ANALYSIS REPORT
NELAC Certification Number: £87633
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY. 199
SHELBY, NC 28152
PEM CARTER
Client ID: PEW-3
Parameter
818{2-ETHYLHEXYL)PHTHALATE
BUTYL BENZYL PHTHALATE
CHRYSENE
D1-N-BUTYL PHTHALATE
D1-N-OCTYL PHTHALATE
DIBENZ (A, H) ANTHRACENE
DI BENZOFURAN
DIETHYL PHTHALATE
DIMETHYL PHTHALATE
FLUORANTHENE
FLUORENE
HEXACHLOROBENZENE
HEXACHLOROBUTADIENE
HEXACHLOROCYCLOPENTADIENE
HEXACHLOROETHAN_E
INDENO(l,2,3-CD)PYRENE
ISOPHORONE
N-NITROSODI-N-PROPYLAMINE
N-NITROSODIPHENYLAMINE
NAPHTHALENE
NITROBENZENE
PENTACHLOROPHENOL
PHE:NANTHRENE
PHENOL
PYRENE
SW846 8270C DOWTHERM
1,1'-BIPHENYL
BIPHENYL ETHER
Volati~e Organics
SWB46 8260B
1,1,1-TRICHLOROETHANE
1,1,2,2-TETRACHLOROETHANE
1,1,2-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
1,2-DICHLOROETHANE
1,2-DICHLOROPROPANE
2-BUTANONE
2-HEXANONE
4-METHYL-2-PENTANONE
ACETONE
<
<
<
<
<
<
<
<
<
<
Result
0 . 010
0. 010
0. 010
0. 010
0. 010
o. 010
o. 010
o. 010
0. 010
0 .010
0 .010
0 .010
0 .010
0. 010
0 .010
0. 010
0 .010
o. 010
0 .010
0 .010
0. 010
0. 025
0. 010
o. 010
0 .010
o. 010
0 .010
0 .0010
o. 0010
o. 0010
0 . 0010
0 .0010
o. 0010
0 .0010
0 .0050
0 . 0050
0 .0050
0 .0050
NC Certification Number: 25
Project Number: 61195.02
Report Date August 21, 2002
Page 2 of 3 Report ID: AA29224
Sample ID L02080702-10
Qual RDL Units Analyst Date Time
0 . 010 mg/1 JRN 08/15/02 1714
0 .010 mg/1 JRN 08/15/02 1714
0. 010 mg/1 JRN 08/15/02 1714
0 .010 mg/1 JRN 08/15/02 1714
0 .010 mg/1 JRN 08/15/02 1714
0 .010 mg/1 JRN 08/15/02 1714
0. 010 mg/1 JRN 08/15/02 1714
0. 010 mg/1 JRN 08/15/02 1714
o. 010 mg/1 JRN 08/15/02 1714
o. 010 mg/1 JRN 08/15/02 1714
o. 010 mg/1 JRN 08/15/02 1714
0 .010 mg/1 JRN 08/15/02 1714
0 .010 mg/1 JRN 08/15/02 1714
o. 010 mg/1 JRN 08/15/02 1714
0 .010 mg/1 JRN 08/15/02 1714
0 .010 mg/1 JRN 08/15/02 1714
0 .010 mg/1 JRN 08/15/02 1714
0. 010 mg/1 JRN 08/15/02 1714
0. 010 mg/1 JRN 08/15/02 1714
0.010 mg/1 JRN 08/15/02 1714
0 .010 mg/1 JRN 08/15/02 1714
0 . 025 mg/1 JRN 08/15/02 1714
0 .010 mg/1 JRN 08/15/02 1714
0. 010 mg/1 JRN 08/15/02 1714
0. 010 mg/1 JRN 08/15/02 1714
0. 010 mg/1 JRN 08/15/02 1714
0. 010 mg/1 JRN 08/15/02 1 714
0 . 0010 mg/1 PAP 08/12/02 1611
0 .0010 mg/1 PAP 08/12/02 1611
0. 0010 mg/1 PAP 08/12/02 1611
o . 0010 mg/1 PAP 08/12/02 1611
0 . 0010 mg/1 PAP 08/12/02 1611
0 . 0010 mg/1 PAP 08/12/02 1611
0 .0010 mg/1 PAP 08/12/02 1611
0 .0050 mg/1 PAP 08/12/02 1611
0 . 0050 mg/1 PAP 08/12/02 1611
0 , 0050 mg/1 PAP 08/12/02 1611
0 .0050 mg/1 PAP 08/12/02 1611
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Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 81 (1 E. Durst Avenue I Greenwood, SC 29649 I [phone]
20
I fa, (8641229-7119 I
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DAYIS
FLMD LABORATORY ANALYSIS REPORT
NELAC Certification Number: £87633
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY. 198
SHELBY, NC 28152
PEM CARTER
Client ID: PEW-3
Parameter
BENZENE
BROMODICHLOROMETHANE
BROMOFORM
BROMOMETHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-DICHLOROETHENE
CIS-1,3-DICHLOROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-DICHLOROETHENE
TRANS-1, 3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL)
Prep Procedure
Analytical Prep Procedures1
BNA SEMIVOLATILES
DOWTHERM
Method
SW846 35008
SW846 35008
Result
' o. 0010
' 0 . 0010
' 0 .0010
' 0 .0010
' 0 . 0010
' 0 .0010
' 0 . 0010
' 0 .0010
' 0 . 0010
0 . 0010
' 0 . 0010
0. 0010
' 0 . 0010
' 0 . 0010
' 0 .0010
' 0 . 0010
' 0 .0010
' 0 .0010
' 0 .0010
' o. 0010
' o. 0010
' 0 .0010
' 0 .0010
' 0 . 0020
Analyst Prep Date
□BC 08/08/02
DBC 08/08/02
NC Certification Number: 25
Project Number: 61195.02
Report Date August 21, 2 002
Page 3 of 3 Report ID: AA29224
Sample ID L02080702-10
Qual RDL units Analyst Date Time
0. 0010 mg/1 PAP 08/12/02 1611
0 . 0010 mg/1 PAP 0B/12/02 1611
0. 0010 mg/1 PAP 08/12/02 1611
0. 0010 mg/1 PAP 08/12/02 1611
o . 0010 mg/1 PAP 08/12/02 1611
0 .0010 mg/1 PAP 08/12/02 1611
0 . 0010 mg/1 PAP 08/12/02 1611
0 .0010 mg/1 PAP 08/12/02 1611
0 . 0010 mg/1 PAP 08/12/02 1611
o . 0010 mg/1 PAP 08/12/02 1611
0. 0010 mg/1 PAP 08/12/02 1611
o. 0010 mg/1 PAP 08/12/02 1611
o . 0010 mg/1 PAP 08/12/02 1611
0 . 0010 mg/1 PAP 08/12/02 1611
0 . 0010 mg/1 PAP 08/12/02 1611
0 . 0010 mg/1 PAP 08/12/02 1611
0. 0010 mg/1 ·p~ 08/12/02 1611
0 . 0010 mg/1 PAP 08/12/02 1611
0 .0010 mg/1 PAP 08/12/02 1611
0 . 0010 mg/1 PAP 08/12/02 1611
0 . 0010 mg/1 PAP 08/12/02 1611
0 . 0010 mg/1 PAP 08/12/02 1611
0 . 0010 mg/1 PAP 08/12/02 1611
0 .0020 mg/1 PAP 08/12/02 1611
0800
0800
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue l Greenwood, SC 29649 I [phone] I Fax [phone]
21
DAYIS
FLmD LABORATORY ANALYSIS REPORT
NELAC Cenification Number: £87633
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY. 198
SHELBY, NC 28152
PEM CARTER
Client IO: C-49
Matrix
Parameter
Volatile Organics
SW846 8260B
1,1,1-TRICHLOROETHANE
1,1,2,2-TETRACHLOROETHANE
1,1,2-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
1,2-DICHLOROETHANE
1,2-DICHLOROPROPANE
2-BUTANONE
2-HEXANONE
4-METHYL-2-PENTANONE
ACETONE
BENZENE
BROMODICHLOROMETHANE
BROMOFORM
BROMOMETHANE
.CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-DICHLOROETHENE
CIS-1,3-DICHLOROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-DICHLOROETHENE
TRANS·l,3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL)
GW/ChemW
Result
< 0 .0010
< 0 .0010
< 0 .0010
< 0 .0010
< 0,0010
< 0 .0010
< o. 0010
< 0 .0050
< 0 .0050
< 0. 0050
< 0 .0050
< 0. 0010
< 0 .0010
0. 0013
< 0 .0010
< 0 .0010
< 0 .0010
< 0.0010
< 0.0010
< 0.0010
0.0027
< 0. 0010
< 0 .0010
< 0 . 0010
< 0 .0010
< 0 .0010
< 0. 0010
< o. 0010
< o. 0010
< 0.0010
< 0 .0010
< 0 .0010
o. 0010
< 0 .0010
< o. 0020
NC Cenification Number: 25
Project Number, 61195.02
Report Date August 21, 2002
Page 1 of 1 Report ID: AA29228
Sample ID L02080702-ll
Date Collected: 06-AUG-02 12: 50
Date Received ' 07-AUG-02
Qual RDL Units Analyst Date Time
0. 0010 mg/1 PAP 08/12/02 1634
0 .0010 mg/1 PAP 08/12/02 1634
0. 0010 mg/1 PAP 08/12/02 1634
0 . 0010 mg/1 PAP 08/12/02 1634
o. 0010 mg/1 PAP 08/12/02 1634
o. 0010 mg/1 PAP 08/12/02 1634
0 . 0010 mg/1 PAP 08/12/02 1634
0 .0050 mg/1 PAP 08/12/02 1634
0. 0050 mg/1 PAP 08/12/02 1634
0. 0050 mg/1 PAP 08/12/02 1634
0 .0050 mg/1 PAP 08/12/02 1634
0. 0010 mg/1 PAP 08/12/02 1634
0. 0010 rng/1 PAP 08/12/02 1634
0. 0010 mg/1 PAP OB/12/02 1634
0 .0010 mg/1 PAP OB/12/02 1634
o. 0010 mg/1 PAP OB/12/02 1634
0 . 0010 mg/1 PAP OB/12/02 1634
0 . 0010 rng/1 PAP 08/12/02 1634
0 .0010 mg/1 PAP 08/12/02 1634
0. 0010 mg/1 PAP 08/12/02 1634
0.0010 rng/1 PAP OB/12/02 1634
0. 0010 mg/1 PAP 08/12/02 1634
0 .0010 mg/1 PAP 08/12/02 1634
o. 0010 mg/1 PAP 08/12/02 1634
0 .0010 mg/1 PAP 08/12/02 1634
0 .0010 mg/1 PAP OB/12/02 1634
0 .0010 mg/1 PAP 08/12/02 1634
0. 0010 mg/1 PAP 08/12/02 1634
0. 0010 mg/1 PAP 08/12/02 1634
0. 0010 mg/1 PAP 08/12/02 1634
0. 0010 mg/1 PAP 08/12/02 1634
0 .0010 rng/1 PAP 08/12/02 1634
o. 0010 mg/1 PAP 08/12/02 1634
0 . 0010 mg/1 PAP 08/12/02 1634
0. 0020 mg/1 PAP 08/12/02 1?34
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Davis & Floyd, Inc. I 1'0 Drawer 428 I Greenwood, SC 29648 I Hl6 E. Durst Avenue I Greenwood, SC 29649 I [phone]
22
I fax {8641229-71191
I
I DAYIS
FLOYD LABORATORY ANALYSIS REPORT
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NELAC Cenijicarion Number: £87633
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY. 198
SHELBY, NC 2B152
PEM CARTER
Client ID: F-55
Matrix
Parameter
Semivolatile Organics
SW846 8270C
1,2,4-TRICHLOROBENZENE
1,2-DICHLOROBENZENE
1,3-DICHLOROBENZENE
1,4-DICHLOROBENZENE
2,4,5-TRICHLOROPHENOL
2,4,6-TRICHLOROPHENOL
2,4-0ICHLOROPHENOL
2,4-DIMETHYLPHENOL
2,4-DINITROPHENOL
2,4-DINITROTOLUENE
2,6-DINITROTOLUENE
2-CHLORONAPHTHALENE
2 -·CHLOROPHENOL
GW/ChemW
2-METHYL-4,6-DINITROPHENOL
2-METHYLNAPHTHALENE
2-METHYLPHENOL
2-NITROANILINE
2-NITROPHENOL
3,3'-DICHLOROBENZIDINE
3-NITROANILINE
4 BROMOPHENYL PHENYL ETHER
4 CHLOR0-3-METHYLPHENOL
4-CHLOROANILINE
4-CHLOROPHENYL PHENYL ETHER
4-METHYLPHENOL
4-NITROANILINE
4-NITROPHENOL
ACENAPHTHENE
ACENAPHTHYLENE
ANTHRACENE
BENZO(A)ANTHRACENE
BENZO(A)PYRENE
BENZO(B)FLUORANTHENE
BENZO(G,H,l)PERYLENE
BENZO(K)FLUORANTHENE
BENZOIC ACID
BENZYL ALCOHOL
BIS(2-CHLOROETHOXY)METHANE
BIS(2-CHLOROETHYL)ETHER
BIS(2-CHLOROISOPROPYL)ETHER I 0;,vis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648
Result
o. 010
' o. 010
' o. 010
' 0 .010
' o. 010
' o. 010
' o. 010
' o. 010
' o. 025
' 0 .010
' 0 .010
' 0. 010
' 0. 010
' 0. 025
' 0. 010
' o. 010
' 0. 010
' o. 010
' 0 .010
' o. 010
' o. 010
' 0. 010
' o. 010
o. 010
' 0 .010
' 0. 010
' 0. 025
' 0. 010
' o. 010
0. 010
' 0 .010
' o. 010
' 0. 010
' o. 010
' 0 .010
' o. 050
o. 010
o. 01 0
' 0. 010
' o. 010
816 E. Durst Avenue
23
NC Cenijicarion Number: 25
Project Number: 61195.02
Report Date
Page 1 of 3
August 21, 2002
Report ID: AA29226
Sample ID L02080702-12
Date Collected: 06-AUG-02 13:45
Date Received 07-AUG-02
Qual RDL Units Analyst Date
0 .010 mg/1 JRN 08/15/02
0. 010 mg/1 JRN 08/15/02
0 .010 mg/1 JRN 08/15/02
0. 010 mg/1 JRN 08/15/02
o. 010 mg/1 JRN 08/15/02
0 .010 mg/1 JRN 08/15/02
0. 010 mg/1 JRN 08/15/02
o. 010 mg/1 JRN 08/15/02
0 .025 mg/1 JRN 08/15/02
0 .010 mg/1 JRN 08/15/02
0 .010 mg/1 JRN 08/15/02
0 .010 mg/1 JRN 08/15/02
0. 010 mg/1 JRN 08/15/02
0. 025 mg/1 JRN 08/15/02
0. 010 mg/1 JRN 08/15/02
0. 010 mg/1 JRN 08/15/02
0 .010 mg/1 JRN 08/15/02
0. 010 mg/1 JRN 08/15/02
0 .010 mg/1 JRN 08/15/02
0. 010 mg/1 JRN 08/15/02
o. 010 mg/1 JRN 08/15/02
0.010 mg/1 JRN 08/15/02
0 .010 mg/1 JRN 08/15/02
o. 010 mg/1 JRN 08/15/02
0 .010 mg/1 JRN 08/15/02
0. 010 mg/1 JRN 08/15/02
0. 025 mg/1 JRN 08/15/02
0. 010 mg/1 JRN 08/15/02
0. 010 mg/1 JRN 08/15/02
0 .010 mg/1 JRN 08/15/02
o. 010 mg/1 JRN 08/15/02
0.010 mg/1 JRN 08/15/02
0 .010 mg/1 JRN 08/15/02
0 .010 mg/1 JRN 08/15/02
o. 010 mg/1 JRN 08/15/02
0 .050 mg/1 JRN 08/15/02
o. 010 mg/1 JRN 08/15/02
0 .010 mg/1 JRN 08/15/02
0 .010 mg/1 JRN 08/15/02
0. 010 mg/1 JRN 08/15/02
Time
1755
1755
1755
1755
1755
1755
1755
1755
1755
1755
1755
1755
1755
1755
1.755
1755
1755
1755
1755
1755
1755
1755
1755
1755
1755
1755
1755
1755
1755
1755
1755
1755
1755
1755
1755
1755
1755
1755
1755
1755
Greenwood, SC 29649 I 18641 229-4413 I Fax [phone]
I I
D~S FL D LABORATORY ANALYSIS REPORT I
NELAC Certification Number: £87633 NC Certification Number: 25 I
Client TICONA,LLC Project Number: 61195.02 I 2525 BLACKSBURG ROAD
HWY. 198
SHELBY, NC 28152 Report Date August 21, 2002 I Contact PEM CARTER Page 2 of 3 Report ID: AA29226
Client ID: F-55 Sample ID L02080702-12 I Parameter Result Qual RDL Units Analyst Date Time
BIS(2-ETHYLHEXYL)PHTHALATE 0.025 0 .010 mg/1 JRN 08/15/02 1755 I BUTYL BENZYL PHTHALATE < 0 .010 0 .010 mg/1 JRN 08/15/02 1755
CHRYSENE < 0 .010 0 .010 mg/1 JRN 08/15/02 1755
DI-N-BUTYL PHTHALATE < 0 .010 0 .010 mg/1 JRN 08/15/02 1755
DI-N-OCTYL PHTHALATE < 0 .010 0 .010 rng/1 JRN 08/15/02 1755 I DIBENZ(A,H)ANTHRACENE < 0 .010 0 .010 mg/1 JRN 08/15/02 1755
DIBENZOFURAN 0.013 0 .010 mg/1 JRN 08/15/02 1755
DIETHYL PHTHALATE < 0 .010 0 .010 mg/1 JRN 08/15/02 1755 I DIMETHYL PHTHALATE < 0 .010 0 .010 mg/1 JRN 08/15/02 1755
FLUORANTHENE < 0 .010 0. 010 mg/1 JRN 08/15/02 1755
FLUORENE < 0 .010 0 .010 mg/1 JRN 08/15/02 1755
HEXACHLOROBENZENE < 0 .010 0. 010 mg/1 JRN 08/15/02 1755 I HEXACHLOROBUTADIENE < 0 .010 0. 010 mg/1 JRN 08/15/02 1755
HEXACHLOROCYCLOPENTADIENE < 0 .010 0. 010 mg/1 JRN 08/15/02 1755
HEXACHLOROETHANE < 0 .010 0 .010 mg/1 JRN 08/15/02 1755
INDENO(l,2,3-CD)PYRENE < 0 .010 0. 010 mg/1 JRN 08/15/02 1755 I ISOPHORONE < 0 .010 0 .010 mg/1 JRN 08/15/02 1755
N-NITROSODI-N-PROPYLAMINE < 0 .010 0. 010 mg/1 JRN 08/15/02 1755
N-NITROSODIPHENYLAMINE < 0 .010 0. 010 mg/1 JRN 08/15/02 175:i I NAPHTHALENE < 0 .010 0.010 mg/1 JRN 08/15/02 1755
NITROBENZENE < 0 .010 0.010 mg/1 JRN 08/15/02 1755
PENTACHLOROPHENOL < 0 .025 0. 025 mg/1 JRN 08/15/02 1755
PHENANTHRENE < 0 .010 0 .010 mg/1 JRN 08/15/02 1755 I PHENOL < 0 .010 0.010 mg/1 JRN 08/15/02 1755
PYRENE < 0 .010 0.010 mg/1 JRN 08/15/02 1755
SW846 8270C DOWTHERM
1, 1' -BI PHENYL ,.o 5 .0 mg/1 JRN 08/16/02 0958 I BIPHENYL ETHER 31.0 5 .o mg/1 JRN 08/16/02 0958
Volatile Organics I SW846 8260B
1,1,1-TRICHLOROETHANE < 0 . 0030 X 0 .0030 mg/1 PAP 08/12/02 1851
1,1,2,2-TETRACHLOROETHANE < 0. 0030 X 0 .0030 mg/1 PAP 08/12/02 1851
1,1,2-TRICHLOROETHANE < 0 .0030 X 0 .0030 mg/1 PAP 08/12/02 1851 I 1,1-DICHLOROETHANE < 0 .0030 X 0 .0030 mg/1 PAP 08/12/02 1851
1,1-DICHLOROETHENE < 0 .0030 X 0.0030 mg/1 PAP 08/12/02 1851
l,2-DICHLOR9ETHANE < 0 .0030 X 0:0030 mg/1 PAP 08/12/02 1851
1,2-DICHLOROPROPANE < 0 .0030 X 0.0030 mg/1 PAP 08/12/02 1851 I 2 -BUTANONE 0.33 0. 015 mg/1 PAP 08/12/02 185 l
2-HEXANONE < 0.015 X 0. 015 mg/1 PAP 08/12/02 1851
4-METHYL-2-PENTANONE < 0.015 X 0 .015 mg/1 PAP 08/12/02 1851
ACETONE 0.34 0 .015 mg/1 PAP 08/12/02 1851 I
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 81 h E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone] I 24
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DAYIS
FLtrYD LABORATORY ANALYSIS REPORT
NELAC Certificarion Number: £87633
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY. 198
SHELBY, NC 28152
PEM CARTER
Client ID; J"-55
Parameter
BENZENE
BROMODICHLOROMETHANE
BROMOFORM
BROMOMETHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-DICHLOROETHENE
CIS-1,3-DICHLOROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-DICHLOROETHENE
TRANS-1,3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL)
Prep Procedure
Analytical Prep Procedures:
BNA SEMIVOLATILES
DOWTHERM
Method
SWB46 35008
SW846 35008
Result
0.052
< 0. 0030
< 0. 0030
< o. 0030
0.0042
< 0 .0030
< 0 .0030
' 0 .0030
< 0 .0030
< 0 .0030
' 0 .0030
< 0 .0030
< 0. 0030
' 0 . 0030
' 0 . 0030
< o. 0030
< 0 .0030
0.0080
< 0. 0030
< 0. 0030
< 0. 0030
< 0. 0030
< 0 .0030
< 0 . 0060
Analyst Prep Date
DSC 08/08/02
DBC 08/08/02
NC Certijicarion Number: 25
Project Number: 61195.02
Report Date August 21, 2002
Page 3 of 3 Report ID: AA29226
Sample ID L02080702-12
Qual RDt, Units Analyst Date Time
0 .0030 mg/1 PAP 08/12/02 1851
X o. 0030 mg/1 PAP 08/12/02 18 51
X o. 0030 mg/1 PAP 08/12/02 18 51
X o. 0030 mg/1 PAP 08/12/02 1851
o. 0030 mg/1 PAP 08/12/02 1851
X 0.0030 mg/1 PAP 08/12/02 1851
X 0 .0030 mg/1 PAP 08/12/02 1851
X 0 . 0030 mg/1 PAP 08/12/02 1851
X o. 0030 mg/1 PAP 08/12/02 1851
X 0 . 0030 mg/1 PAP 08/12/02 1851
X 0 . 0030 mg/1 PAP 08/12/02 1851
X 0 .0030 mg/1 PAP 08/12/02 1851
X 0 . 0030 mg/1 PAP 08/12/02 1851
X 0 .0030 mg/1 PAP 08/12/02 18 51
X 0 . 0030 mg/1 PAP 08/12/02 18 51
X o. 0030 mg/1 PAP 08/12/02 1851
X 0 .0030 mg/1 PAP 08/12/02 1851
o. 0030 mg/1 PAP 08/12/02 1851
X 0 .0030 mg/1 PAP 08/12/02 1851
X 0 . 0030 mg/1 PAP 08/12/02 1851
X o. 0030 mg/1 PAP 08/12/02 1851
X 0 .0030 mg/1 PAP 08/12/02 1851
X 0 .0030 mg/1 PAP 08/12/02 1851
X 0 .0060 mg/1 PAP 08/12/02 1851
0800
0800
Davis & Floyd, Inc. j PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
25
Di\VIS
FLO'YD LABORATORY ANALYSIS REPORT
NELAC Certificacion Number: £87633
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY. 198
SHELBY, NC 28152
PEM CARTER
Client ID: FP'-62
Matrix
Parameter
Volatile Organics
SW846 8260B
1,1,1-TRICHLOROETHANE
1,1,2,2-TETRACHLOROETHANE
1,1,2-TRICHLOROETHANE
1,1-DICHLOROETHANE
1, 1-DICHWROETHENE
1,2-DICHLOROETHANE
1,2-DICHLOROPROPANE
2-BUTANONE
2-HEXANONE
4-METHYL-2-PENTANONE
ACETONE
BENZENE
BROMODICHLOROMETHANE
BROMOFORM
BROMOMETHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-DICHLOROETHENE
CIS-1,3-DICHLOROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-DICHLOROETHENE
TRANS-1,3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL)
GW/ChemW
Result
< 0 .0010
< 0 .0010
< 0 .0010
< 0 .0010
< o. 0010
< o. 0010
< o. 0010
< 0. 0050
< 0. 0050
< 0. 0050
< o. 0050
0.0015
< 0.0010
< 0.0010
< 0.0010
< 0.0010
< 0.0010
0.0012
< 0 .0010
< 0 . 0010
0.0010
< 0 .0010
< 0 .0010
0 .0010
< 0 .0010
< 0 .0010
< 0 .0010
< 0. 0010
< 0.0010
< 0.0010
< o. 0010
< 0. 0010
< 0 .0010
< 0. 0010
< 0 . 0020
NC Certification Number: 25
Project Number: 61195.02
Report Date August 21, 2002
Page 1 of 1 Report ID: AA29227
Sample ID L02080702-13
Date Collected: 06-AUG-02 15; 35
Date Received 07-AUG-02
Qual RDL Units Analyst Date Time
0 .0010 mg/1 PAP 08/12/02 1657
0 .0010 mg/1 PAP 08/12/02 1657
0 .0010 mg/1 PAP 08/12/02 1657
0 . 0010 mg/1 PAP 09/12/02 1657
o. 0010 mg/! PAP 08/12/02 1657
o. 0010 mg/1 PAP 08/12/02 1657
0. 0010 mg/1 PAP 08/12/02 1657
o. 0050 mg/1 PAP 08/12/02 1657
o. 0050 mg/1 PAP 08/12/02 1657
0. 0050 mg/1 PAP 08/12/02 1657
0 .0050 mg/1 PAP 08/12/02 1657
0 .0010 mg/1 PAP 08/12/02 1657
0. 0010 mg/1 PAP 08/12/02 1657
0. 0010 mg/1 PAP 08/12/02 1657
0 . 0010 mg/1 PAP 08/12/02 1657
0 .0010 mg/! PAP 08/12/02 1657
0 .0010 mg/1 PAP 08/12/02 1657
0 .0010 mg/1 PAP 08/12/02 1657
0 . 0010 mg/1 PAP 08/12/02 1657
0 . 0010 mg/1 PAP 08/12/02 1657
0.0010 mg/1 PAP 08/12/02 1657
0 .0010 mg/1 PAP 08/12/02 1657
0 .0010 mg/1 PAP 08/12/02 1657
0. 0010 mg/1 PAP 08/12/02 1657
0.0010 mg/1 PAP 08/12/02 1657
0.0010 mg/1 PAP 08/12/02 1657
0.0010 mg/1 PAP 08/12/02 1657
0.0010 mg/1 PAP 08/12/02 1657
0.0010 mg/1 PAP 08/12/02 1657
0 .0010 mg/1 PAP 08/12/02 1657
o. 0010 mg/1 PAP 08/12/02 1657
o. 0010 mg/1 PAP 08/12/02 1657
0. 0010 mg/1 PAP 08/12/02 1657
o. 0010 mg/1 PAP 08/12/02 1657
o. 0020 mg/1 PAP 08/12/02 1657
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Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29646 I 8 I 6 E. Durst Avenue I Greenwood, SC 29649 I (fl64) 229-4413
26
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DAYIS
FLt1\'D LABORATORY ANALYSIS REPORT
NELAC Certification Number: £87633
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY. 198
SHELBY, NC 28152
PEM CARTER
Client ID: TRIP BLANK #1
Matrix
Parameter
Volatile Organics
SW846 8260B
1,1,1-TRICHLOROETHANE
1,1,2,2-TETRACHLOROETHANE
1,1,2-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-0ICHLOROETHENE
1,2-DICHLOROETHANE
1,2-DICHLOROPROPANE
2-BUTANONE
2-HEXANONE
4-METHYL-2-PENTANONE
ACETONE
BENZENE
BROMODICHLOROMETHANE
BROMOFORM
BROMOMETHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-DICHLOROETHENE
CIS-1,3-DICHLOROPROPENE
DIEROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-DICHLOROETHENE
TRANS-1,3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL)
GW/ChemW
Result
< 0. 0010
< 0 .0010
< 0 .0010
< 0 . 0010
< 0. 0010
< 0 .0010
< 0. 0010
0 . 0050
< 0 . 0050
< 0 . 0050
< 0 . 0050
< 0 .0010
< 0. 0010
< 0 .0010
< 0 .0010
< 0 .0010
< o. 0010
< 0 .0010
< o. 0010
< 0 . 0010
< 0 . 0010
< 0. 0010
< 0 . 0010
< o. 0010
< 0 . 0010
< 0. 0010
< 0 .0010
< 0. 0010
< 0 .0010
< 0 .0010
< 0 .0010
< 0. 0010
< o. 0010
< o. 0010
< 0 . 0020
NC Certification Number: 25
Project Number: 61195.02
Report Date
Page 1 of 1
Sample ID
Date Collected:
□ate Received
August 21, 2002
Report ID: AA29229
L02080702-14
07-AUG-02
Qual RDL Units Analyst Date
0 .0010 mg/1 PAP 08/12/02
0 .0010 mg/1 PAP 08/12/02
0 .0010 mg/1 PAP 08/12/02
0 . 0010 mg/1 PAP 08/12/02
0. 0010 mg/1 PAP 08/12/02
o. 0010 mg/1 PAP 08/12/02
0 .0010 mg/1 PAP 08/12/02
0. 0050 mg/1 PAP 08/12/02
0 .0050 mg/1 PAP 08/12/02
0 . 0050 mg/I PAP 08/12/02
0. 0050 mg/1 PAP 08/12/02
0 .0010 mg/1 PAP 08/12/02
0 .0010 mg/1 PAP 08/12/02
0 .0010 mg/1 PAP 08/12/02
0 .0010 mg/1 PAP 08/12/02
0 .0010 mg/1 PAP 08/12/02
0. 0010 mg/1 PAP 08/12/02
0 . 0010 mg/1 PAP 08/12/02
0. 0010 mg/1 PAP 08/12/02
0 .0010 mg/1 PAP 08n2;02
0 . 0010 mg/1 PAP 08/12/02
0 .0010 mg/1 PAP 08/12/02
0 .0010 mg/1 PAP 08/12/02
0 .0010 mg/1 PAP 08/12/02
o. 0010 mg/1 PAP 08/12/02
0. 0010 mg/1 PAP 08/12/02
0 . 0010 mg/1 PAP 08/12/02
0 .0010 mg/1 PAP 08/12/02
o. 0010 mg/1 PAP 08/12/02
0 .0010 mg/1 PAP 08/12/02
0 .0010 mg/1 PAP 08/12/02
0 .0010 mg/1 PAP 08/12/02
o·. 0010 mg/1 PAP 08/12/02
0 . 0010 mg/1 PAP 08/12/02
0 . 0020 mg/1 PAP 08/12/02
Time
1309
1309
1309
1309
1309
1309
1309
1309
1309
1309
1309
1309
1309
1309
1309
1309
1309
1309
1309
1309
1309
1309
1309
1309
1309
1309
1309
1309
13 09
1309
1309
1309
1309
1309
1309
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
2 7.
DAYIS
FLOYD LABORATORY ANALYSIS REPORT
NELAC Cerrijicario11 Number: £87633
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY. 198
SHELBY, NC 28152
PEM CARTE~
Client ID: EQUIPMENT BLANK
Parameter
Volatile Organics
SW846 8260B
Matrix
1, 1, !-TRICHLOROETHANE
1,1,2,2-TETRACHLOROETHANE
1, 1, 2-TRICHLOROETHANE
1,1-0ICHLOROETHANE
1, 1-DICHLOROETHENE
1,2-DICHLOROETr.ANE
1,2-DICHLOROPROPANE
2-BUTANONE
2-HEXANONE
4-METHYL-2-PENTANONE
ACETONE
BENZENE
BROMODICHLOROMETHANE
BROMOFORM
BROMOMETHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-DICHLOROETHENE
CIS·l,3-DICHLOROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-DICHLOROETHENE
TRANS-1,3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL)
Wet Chemistry
SW846 9060
ORGANIC CARBON, TOTAL
GW/Chemw
Result
' o. 0010
0 . 0010
' 0. 0010
' 0 . 0010
' 0 .0010
' 0. 0010
' 0 . 0010
' 0 . 0050
' o. 0050
' 0 . 0050
' o. 0050
' 0.0010
' 0 .0010
' 0 .0010
' 0 . 0010
' 0 .0010
' 0 . 0010
' 0.0010
' 0 .0010
' 0 . 0010
' 0 . 0010
' 0 . 0010
' 0 . 0010
' 0 . 0010
' 0 . 0010
' 0 .0010
' 0 . 0010
' 0 . 0010
' 0 . 0010
' o. 0010
' 0 . 0010
' 0 . 0010
' 0 . 0010
' 0 . 0010
' 0 . 0020
' 1.0
NC Cerrijicatio11 Number: 25
Project Number: 61195.02
Report Date August 21, 2 002
Page 1 of 1 Report ID: AA29230
Sample ID L02080702~15
Date Collected, 05-AUG-02 17: 15
Date Received 07-AUG-02
Qual RDL Units Analyst Date Time
0. 0010 mg/1 PAP 0B/12/02 1331
0 .0010 mg/1 PAP 0B/12/02 1331
0 .0010 mg/1 PAP 08/12/02 1331
0 .0010 mg/1 PAP 08/12/02 1331
0 .0010 mg/1 PAP 08/12/02 1331
0. 0010 mg/1 PAP 08/12/02 13 31
0 .0010 mg/1 PAP 08/12/02 1331
0. 0050 mg/1 PAP 08/12/02 1331
0. 0050 mg/1 PAP 08/12/02 1331
0 . 0050 mg/1 PAP 08/12/02 1331
0 .0050 mg/1 PAP 0B/12/02 13 31
o. 0010 mg/1 PAP 08/12/02 1331
0. 0010 mg/1 PAP 08/12/02 1331
0. 0010 mg/1 PAP 08/12/02 1331
0 . 0010 mg/1 PAP 08/12/02 1331
0 . 0010 mg/1 PAP 08/12/02 1331
0. 0010 mg/1 PAP 08/12/02 1331
0 .0010 mg/1 PAP 08/12/02 1331
0 .0010 mg/1 PAP 08/12/02 1331
0. 0010 mg/1 PAP 08/12/02 1331
0 . 0010 mg/1 PAP 08/12/02 1331
0 . 0010 mg/1 PAP 08/12/02 1331
0. 0010 mg/1 PAP 08/12/02 1331
0 .0010 mg/1 PAP 08/12/02 1331
0. 0010 mg/1 PAP 08/12/02 1331
0 . 0010 mg/1 PAP 08/12/02 1331
0. 0010 mg/1 PAP 09/12/02 1331
0.0010 mg/1 PAP 08/12/02 1331
0 .0010 mg/1 PAP 08/12/02 1331
0. 0010 mg/1 PAP 08/12/02 1331
0 .0010 mg/1 PAP 08/12/02 1331
0 .0010 mg/1 PAP 08/12/02 1331
0. 0010 mg/1 PAP 08/12/02 1331
0 .0010 mg/1 PAP 08/12/02 1331
0.0020 mg/1 PAP 08/12/02 1331
1 . 0 mg/1 CLB 08/12/02 0953
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[)Jvis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 8 l 6 E. Durst Avenue I Greenwood, SC 29649 I (864) 229-44 lJ
2 8 "
I fa, (864) 22\)-7119 I
DtcXIS llfilmm1 .lnlilfflll'c FL YD inir,mou1Um""1lmicu Chain of Custody Record Page J_ of J_
Client Project I Site Location 816 E. Durst Avenue. Greenwood, SC 29649 [phone] Fax: [phone] cetTse c1my
C.N.A. HoldingsfTicona 61195.02 Laborato,y Certifcation Numbers: SC-24110, NC-25, TN-2923, VA-77
Shelby.NC For Kubal-Furr
Contact Report To Copy To Reporting Requirements: { J Standard { } Data Package (Specify Level) 0 un;hase Order
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Lli-S-1/ ,f /4-,-J, :i. /,D.S ✓ s' s X ()~
_.,-:3.s 8/_d;J 4-~-5 .,, £" 3 X. 07
1--G -0/ 6-J-/4 ;i /,!'/,, ,/ _.,--:s X op
}'1=1,J -( f'/1.,/4;. l"tiJo ,,, £ if )( )( ()Q
Pew-3 f/&/.;;i loSo .,, I-< '-( X X. ,o
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~-,<:< •-/r./4J /3{~ ✓ < ,( 'x J< /').,
'rr-6;2. /) }/, /4 2. is-ss-v ) 3 le' 18
-, . I ~/ I a,-,r-. / --. c-
, / ---. ~:dBy -/Tl/ t2: Time Rel"'E:dBy ~ ,/ /Z.. J? Date Time Reliquished By Date Time Qwc~ Sh~
-'l 7,, . /01/I -7-()Z. ,r-, 7 2'.'i."' ~· CLIENT
,z.. ~
y N
/ "' ' fEOE.X
~r ,0 I} . ii~? Time f<ect!ived(J Date Time ~7;;"";,'°ih'075d,.s Date Time lfY, s 'city: Airbi/1 Number
&/-Y; 9.7.0'--(//gt} _/ days
vomme"C /.( f v //J /l!Jr ,t/ T fj,). ,!,,Q ;{ /V~i' /,</Cl. rJiJKO l)A/ C,o(!, ~ Coolec 10 <f:;;;ble), ____,-
bn Ice: Ye o Temp(C) i
Custody Seal: Intact / Broken~
Matrix Type Definitions _.., .. _ .. 1 -Dnnking Water 2 -Clean Water S • Groundwater 7 -S01I/Sed1ment 8 -Liquid Sludge 9 -Od 12 -Air
-B--C-'iilil HNOlllllllf'OH 11111,ed lilii'CUp--- --- - -
Oavss & Floyd, Inc.
FL02_01 (02'99) - - -
DAYIS
FLOYD
August 21, 2002
PEM CARTER
TICONA,LLC
2525 BLACKSBURG ROAD
HWY. 198
SHELBY, NC 28152
LABORATORY ANALYSIS REPORT
Login Number
Project Number
Description
:L02080818
:61195.02
:GROUNDWATER
Dear Pem Carter:
We are pleased to provide the enclosed analytical results for the samples received by
Davis & Floyd, Inc. on August 08, 2002.
A formal Quality Assurance/Quality Control program is maintained by Davis & Floyd,
which is designed to meet or exceed the EPA, NELAC or other appropriate regulatory
requirements. All analytical analyses for this project met QA/QC criteria and the
results are within the 99% confidence interval for each method unless otherwise
stated in the footnotes. This report is to be reproduced only in full.
Feel free to contact our Client Services Representative at [phone] if further
explanation of the analysis is required. Unless other arrangements have been made,
samples will be disposed of or returned 14 days from the date of the report. We
appreciate the opportunity to provide services to your firm.
Sincerely,
DA VIS & FLOYD, INC.
CZ~,ro
Laboratory Manager
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Davis & Floyd. Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816; ~urst Avenue I Greenwood. SC 2%49 I [phone] I fax [phone] I
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D1\VIS
FLMD LABORATORY ANALYSIS REPORT
NELAC Cenificalion Number: £87633
Master Tracking List
Client
Contact
Sample ID
L02080818-0l
Volatile Organics
SW846 8260B
L020B0818-02
Volatile Organics
SW846 8260B
L02080818-0J
Volatile Organics
SW846 8260B
L02080818-04
Volatile Organics
SW846 8260B
Semivolatile Organics
SW846 8270C
SW846 8270C DOWTHERM
Volatile Organics
SW846 8260B
L02080818-06
Volatile Organics
SW846 8260B
wet Chemistry
SW846 9060
L02080818-07
Volatile Organics
SW846 8260B
TICONA,LLC
2525 BLACKSBURG ROAD
HWY. 198
SHELBY, NC 28152
PEM CARTER
Client ID
FF-H.
EE-58
CC-33
P-58
PEW-t
K-28
V-23
08/08/02
08/08/02
NC Certification Number: 25
Project Number, 61195.02
Report Date August 21, 2002
Page 1 of 2 Report IO: AA29231
Date Collected Date Received
06-AUG-02 16: 33 08-AUG-02
OB/13/02 1244
06-AUG-02 18:00 08-AUG-02
08/13/02 1308
06-AUG-02 19: 05 08-AUG-02
08/13/02 1333
07-AUG-02 11:05 OB-AUG-02
08/13/02 1355
07-AUG-02 ll:45 08-AUG-02
1500 08/15/02 1837
1500 08/15/02 1837
08/13/02 1418
07-AUG-02 U:20 08-AUG-02
08/13/02 1441
08/12/02 1128
07-AUG-0:.i! 16:08 08-AUG-0:.i!
08/13/02 1504
D,wis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I (864) 229-441 J I Fax {864) 229-7119
31
DAYIS
FLOYD LABORATORY ANALYSIS REPORT
NELAC Certification Number: £87633
Master Tracking List
Sample ID
Wet Chemistry
SW846 9060
L02080818-08
Client
Contact
Volatile Organics
SW846 8260B
Wet Chemistry
SW846 9060
L02080818-09
Volatile Organics
SW846 8260B
TICONA,LLC
2525 BLACKSBURG ROAD
HWY. 198
SHELBY, NC 28152
PEM CARTER
Client ID
V-23 DUP.
TRIP BLANK #2
-.·•
NC Certification Number: 25
Project Number: 61195.02
Report Date
Page 2 of 2
August 21, 2002
Report ID: AA29231
Date Collected Date Received
08/12/02 1149
07-AUG-02
08/13/02 1527
08/12/02 1156
08-AUG-02
08/13/02 0826
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue ! Greenwood, SC 29649 I {864) 229-4413 I Fax [phone]
32 ·
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Df\YIS
FLOYD LABORATORY ANALYSIS REPORT
NELA C Certification Number: £87633
Cl1.ent
contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY. 198
SHELBY, NC 28152
PEM CARTER
Client ID: FF-34
Matrix
Parameter
Volatile Organics
SW846 8260B
1,1,1-TRICHLOROETHANE
1, 1,2,2-TETRACHLOROETHANE
1,1,2-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
1,2-DICHLOROETHANE
1,2-DICHLOROPROPANE
2-BUTANONE
2-HEXANONE
4-METHYL-2-PENTANONE
ACETONE
BENZENE
BROMODICHLOROMETHANE
BROMOFORM
BROMOMETHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-DICHLOROETHENE
CIS-1,3-DICHLOROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2 DICHLOROETHENE
TRANS-1,3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL)
GW/ChemW
Result
< 0 .0010
< 0 .0010
o. 0010
< 0. 0010
< o. 0010
< 0 .0010
< 0 .0010
< 0 .0050
< 0 .0050
< o. 0050
< o. 0050
' o. 0010
' 0 .0010
' 0 .0010
' 0 .0010
' 0 .0010
' o. 0010
' 0 .0010
' 0 .0010
' 0 .0010
' 0 .0010
' 0.0010
' 0. 0010
' o. 0010
' 0 .0010
' 0 .0010
' 0 .0010
' 0. 0010
' o. 0010
' o. 0010
' 0. 0010
' 0 .0010
< 0 .0010
o. 0010
< 0 .0020
NC Certification Number: 25
Project Number: 61195.02
Report Date
Page 1 of 1
Sample ID
August 21, 2002
Report ID: AA29233
L02080818-01
Date Collected: 06-AUG-02 16:33
Date Received 08-AUG-02
Qual RDL Units Analyst Date
0 .0010 mg/1 PAP 08/13/02
0 .0010 mg/1 PAP 08/13/02
0 .0010 mg/1 PAP 08/13/02
0 .0010 mg/1 PAP 08/13/02
0 .0010 mg/1 PAP 08/13/02
0 .0010 mg/1 PAP 08/13/0~
0. 0010 mg/1 PAP 08/13/02
0 .0050 mg/1 PAP 08/13/02
0 .0050 mg/1 PAP 08/13/02
o. 0050 mg/1 PAP 08/13/02
0 .0050 mg/1 PAP 08/13/02
0 .0010 mg/1 PAP 08/13/02
0 . 0010 mg/1 PAP 08/13/02
o. 0010 mg/1 PAP 08/13/02
0 .0010 mg/1 PAP 08/13/02
0 . 0010 mg/1 PAP 08/13/02
0 .0010 mg/1 PAP 08/13/02
0 . 0010 mg/1 PAP 08/13/02
0.0010 mg/1 PAP 08/13/02
0. 0010 mg/1 PAP 08/13/02
0 .0010 mg/1 PAP 08/13/02
o. 0010 mg/1 PAP 08/13/02
0.0010 mg/1 PAP 08/13/02
0 . 0010 mg/1 PAP 08/13/02
0 .0010 mg/1 PAP 08/13/02
0. 0010 mg/1 PAP 08/13/02
0 .0010 mg/1 PAP 08/13/02
0 .0010 mg/1 PAP 08/13/02
0 .0010 mg/1 PAP 08/13/02
0 . 0010 mg/1 PAP 08/13/02
0 .0010 mg/1 PAP 08/13/02
0 .0010 mg/1 PAP 08/13/02
0 .0010 mg/1 PAP 08/13/02
0 .0010 mg/1 PAP 08/13/02
0 .0020 rng/1 PAP 08/13/02
Time
1244
1244
1244
1244
1244
1244
1244
1244
1244
1244
1244
1244
1244
1244
1244
1244
1244
1244
1244
1244
1244
1244
1244
1244
1244
1244
1244
1244
1244
1244
1244
1244
1244
1244
1244
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 I:. Dun,! Avenue I Greenwood, SC 29649 I {864) 229-4413 I Fax {864) 229-7119
33
DAYIS
FLOYD LABORATORY ANALYSIS REPORT
NELAC Certification Number: £87633
Client
contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY. 198
SHELBY, NC 28152
PEM CARTER
Client ID: EE-58
Matrix
Parameter
Volatile Organics
SW846 8260B
1,1,1-TRICHLOROETHANE
1,1,2,2-TETRACHLOROETHANE
1,1,2-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
1,2-DICHLOROETHANE
1,2-DICHLOROPROPANE
2-BUTANONE
2-HEXANONE
4-METHYL-2-PENTANONE
ACETONE
BENZENE
BROMODICHLOROMETHANE
BROMOFORM
BROMOMETHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-DICHLOROETHENE
CIS-1,3-DICHLOROPROPENE
OIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2 DICHLOROETHENE
TRANS-1,3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL)
GW/ChemW
Result
< o. 0010
< 0. 0010
< 0.0010
< 0. 0010
0 .0010
< 0 .0010
< 0 . 0010
< o. 0050
< 0. 0050
< o. 0050
0 . 0050
< 0 . 0010
< 0 . 0010
< o. 0010
< o. 0010
< 0 .0010
< 0 .0010
< 0 . 0010
< 0 . 0010
< 0. 0010
< o. 0010
< 0. 0010
< 0. 0010
< 0. 0010
< o. 0010
< 0 . 0010
< 0 . 0010
< 0 . 0010
< o. 0010
< 0. 0010
< 0 .0010
< 0 .0010
< 0 . 0010
< 0. 0010
< 0 . 0020
NC Certification Number: 25
Project Number, 61195.02
Report Date
Page 1 of 1
Sample ID
August 21, 2002
Report ID: M29234
L02080818-02
Date Collected: 06-AUG-02 18:00
Date Received 08-AUG-02
Qual RDL Units Analyst Date
0. 0010 mg/1 PAP 08/13/02
o. 0010 mg/1 PAP 08/13/02
0 .0010 mg/1 PAP 08/13/02
o. 0010 mg/1 PAP 08/13/02
0 . 0010 mg/1 PAP 08/13/02
o. 0010 mg/1 PAP 08/13/02
0 .0010 mg/1 PAP 08/13/02
0 .0050 mg/1 PAP 08/13/02
0 .0050 mg/1 PAP 08/13/02
0. 0050 mg/1 PAP 08/13/02
0. 0050 mg/1 PAP 08/13/02
0. 0010 mg/1 PAP 08/13/02
0 .0010 mg/1 PAP 08/13/02
0 .0010 mg/1 PAP 08/13/02
0.0010 mg/1 PAP 08/13/02
0 . 0010 mg/1 PAP 08/13/02
0 .0010 mg/1 PAP 08/13/02
0. 0010 mg/1 PAP 08/13/02
0.0010 mg/1 PAP 08/13/02
0 .0010 mg/1 PAP 08/13/02
0. 0010 mg/1 PAP 08/13/02
0 .0010 mg/1 PAP 08/13/02
0 .0010 mg/1 PAP 08/13/02
0.0010 mg/1 PAP 08/13/02
0 . 0010 mg/1 PAP 08/13/02
0. 0010 mg/1 PAP 08/13/02
0. 0010 mg/1 PAP 08/13/02
0 .0010 mg/1 PAP 08/13/02
o. 0010 mg/1 PAP 08/13/02
o. 0010 mg/1 PAP 08/13/02
0 .0010 mg/1 PAP 08/13/02
0 . 0010 mg/1 PAP 08/13/02
0 . 0010 mg/1 PAP 08/13/02
0 . 0010 mg/1 PAP 08/13/02
o . 0020 mg/1 PAP 08/13/02
Time
1308
1308
1308
1308
1308
1308
1308
1308
1308
1308
1308
1308
1308
1308
1308
1308
1308
1308
1308
1308
1308
1308
1308
1308
1308
1308
1308
1308
1308
1308
1308
1308
1308
1308
1308
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Davi~ & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 f.. Durst Avenue I Greenwood, SC 29649 I [phone]
34
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DAYIS
FLOYD LABORATORY ANALYSIS REPORT
NELAC Certification Number: £87633
Client
contact
TICONA,I.,LC
2525 BLACKSBURG ROAD
HWY. 198
SHELBY, NC 28152
PEM CARTER
Client ID: CC-33
Matrix
Parameter
Volatile Organics
SW846 8260B
1,1,1-TRICHLOROETHANE
1,1,2,2-TETRACHLOROETHANE
1,1,2-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
1,2-DICHLOROETHANE
1,2-DICHLOROPROPANE
2-BUTANONE
2-HEXANONE
4 -METHYL-2-PENTANONE
ACETONE
BENZENE
BROMODICHLOROMETHANE
BROMOFORM
BROMOMETHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-DICHLOROETHENE
CIS-1,3-DICHLOROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-DICHLOROETHENE
TRANS-1,3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL)
GW/ChemW
Result
' 0 .0010
0 .0010
' 0 .0010
' o. 0010
' 0 .0010
' 0 .0010
0 .0010
0 .0050
' 0. 0050
0 .0050
0 .0050
' 0 . 0010
' 0 .0010
' 0.0010
' 0 .0010
0. 0010
' 0 .0010
' 0.0010
' o. 0010
' o. 0010
' 0. 0010
0.0025
' 0 .0010
' 0 . 0010
' 0 .0010
' o. 0010
' o. 0010
' 0 .0010
' 0 .0010
' 0 .0010
' 0 .0010
0.0059
' o. 0010
' o. 0010
' 0 . 0020
NC Cenification Number: 25
Project Number, 61195.02
Report Date August 21, 2002
Page l of l Report ID: AA29235
Sample rn L0208081B-03
Date Collected: 06-AUG-02 19 :05
Date Received 08-AUG-02
Qual RDL Units Analyst Date
0. 0010 mg/1 PAP 08/13/02 1333
0. 0010 mg/1 PAP 08/13/02 1333
0. 0010 mg/1 PAP 08/13/02 1333
0 .0010 mg/1 PAP 08/13/02 1333
0 . 0010 mg/1 PAP 08/13/02 1333
0 .0010 mg/1 PAP 08/13/02 1333
0. 0010 mg/1 PAP 08/13/02 1333
0. 0050 mg/1 PAP 08/13/02 1333
o. 0050 mg/1 PAP 08/13/02 1333
0. 0050 mg/1 PAP 08/13/02 1333
0. 0050 mg/1 PAP 08/13/02 1333
0 .0010 mg/1 PAP 08/13/02 1333
0 .0010 mg/1 PAP 08/13/02 1333
0 .0010 mg/1 PAP 08/13/02 1333
0 . 0010 mg/1 PAP 08/13/02 1333
0. 0010 mg/1 PAP 08/13/02 1333
0 .0010 mg/1 PAP 08/13/02 1333
0 .0010 mg/1 PAP 08/13/02 1333
0.0010 mg/1 PAP 08/13/02 1333
0. 0010 mg/1 PAP 08/13/02 1333
0 .0010 mg/1 PAP 08/13/02 1333
o. 0010 mg/1 PAP 08/13/02 13 33
0 . 0010 mg/1 PAP 08/13/02 1333
0. 0010 mg/1 PAP 08/13/02 1333
0 .0010 mg/1 PAP 08/13/02 1333
0.0010 mg/1 PAP 08/13/02 1333
o. 0010 mg/1 PAP 08/13/02 1333
0 . 0010 mg/1 PAP 08/13/02 1333
0 . 0010 mg/1 PAP 08/13/02 1333
0 .0010 mg/1 PAP 08/13/02 1333
0 .0010 mg/1 PAP 08/13/02 1333
0 .0010 mg/1 PAP 08/13/02 1333
0 . 0010 mg/1 PAP 08/13/02 1333
0 .0010 mg/1 PAP 08/13/02 1333
0 . 0020 mg/1 PAP 08/13/02 1333
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
35
DAYIS
FLbYD LABORATORY ANALYSIS REPORT
NELAC Certifica1ion Number: £87633
Client
Contact
TICON.A,LLC
2525 BLACKSBURG ROAD
HWY. 198
SHELBY, NC 2B152
PEM CARTER
Client ID: P-58
Matrix
Para.meter
Volatile Organics
SW846 8260B
1,1,1-TRICHLOROETHANE
1,1,2,2-TETRACHLOROETHANE
1,1,2-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
1,2-DICHLOROETHANE
1,2-DICHLOROPROPANE
2-BUTANONE
2-HEXANONE
4-METHYL-2-PENTANONE
ACETONE
BENZENE
BROMODICHI..OROMETHANE
BROMOFORM
BR OMO METHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROETHANE
CHLOROFORM
CHLOROMETHANE
CIS-l,2·DICHLOROETHENE
CIS-1,3-DICHLOROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-DICHLOROETHENE
TRANS-1,3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL)
GW/ChemW
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
Result
0 . 0010
0 . 0010
0 . 0010
o. 0010
0 . 0010
0 . 0010
0 . 0010
0 . 0050
0 . 0050
0 . 0050
0 . 0050
0 . 0010
0 . 0010
0. 0010
0.0010
o. 0010
0 .0010
0. 0010
0 . 0010
0.0010
0. 0010
0 . 0010
0 . 0010
0. 0010
0. 0010
0 . 0010
0. 0010
0 .0010
o. 0010
0 . 0010
0 . 0010
0 . 0010
0 . 0010
o. 0010
0 . 0020
NC Certification Number: 25
Project Number: 61195.02
Report Date
Page 1 of 1
Sample ID
August 21, 2002
Report ID: AA29236
L02080818-04
Date Collected: 07-AUG-02 11:05
Date Received 08-AUG-02
Qual RDL Units Analyst Date
o. 0010 mg/1 PAP 08/13/02
0 . 0010 mg/1 PAP 08/13/02
0.0010 mg/1 PAP 08/13/02
0 . 0010 mg/1 PAP 08/13/02
0 . 0010 mg/1 PAP 08/13/02
0 . 0010 mg/1 PAP 08/13/02
0 . 0010 mg/1 PAP 08/13/02
0 .0050 mg/1 PAP 08/13/02
0 .0050 mg/1 PAP 08/13/02
0 . 0050 mg/1 PAP 08/13/02
0 . 0050 mg/1 PAP 08/13/02
o . 0010 mg/1 PAP 08/13/02
o . 0010 mg/1 PAP 08/13/02
0.0010 mg/1 PAP 08/13/02
0. 0010 mg/1 PAP 08/13/02
o. 0010 mg/1 PAP 08/13/02
0.0010 mg/1 PAP 08/13/02
0 .0010 mg/1 PAP 08/13/02
0 .0010 mg/1 PAP 08/13/02
0 .0010 mg/1 PAP 08/13/02
0 . 0010 mg/1 PAP 08/13/02
0 . 0010 mg/1 PAP 08/13/02
o. 0010 mg/1 PAP 08/13/02
0 .0010 mg/1 PAP 08/13/02
0 . 0010 mg/1 PAP 08/13/02
0. 0010 mg/1 PAP 08/13/02
0 .0010 mg/1 PAP 08/13/02
0 .0010 mg/1 PAP 08/13/02
0 . 0010 mg/J PAP 08/13/02
0. 0010 mg/1 PAP 08/13/02
0 .0010 mg/1 PAP 08/13/02
0 . 0010 mg/1 PAP 08/13/02
0 . 0010 mg/1 PAP 08/13/02
o. 0010 mg/1 PAP 08/13/02
0.0020 mg/1 PAP 08/13/02
Time
1355
1355
1355
1355
1355
1355
1355
1355
1355
1355
1355
1355
1355
1355
1355
1355
1355
1355
1355
1355
1355
1355
1355
1355
1355
1355
1355
1355
1355
1355
1355
1355
13 55
1355
13 55
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Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I (864) 229-441 J
36,
I fox (8641229-71 l'l I
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DAYIS
FLOYD LABORATORY ANALYSIS REPORT
NELAC Certification Number: £87633
Client
Contact
TICONA, LLC
2525 BLACKSBURG ROAD
HWY. 198
SHELBY, NC 28152
PEM CARTER
Client ID: PEW-4
Matrix GW/ChemW
Parameter
Semivolatile Organics
SW846 8270C
l,2,4-TRICHLOROBENZENE
1,2-DICHLOROBENZENE
1,3-DICHLOROBENZENE
1,4-DICHLOROBENZENE
2,4,5-TRICHLOROPHENOL
2,4,6-TRICHLOROPHENOL
2,4-DICHLOROPHENOL
2,4-DIMETHYLPHENOL
2,4-DINITROPHENOL
2,4-DINITROTOLUENE
2,6-DINITROTOLUENE
2-CHLORONAPHTHALENE
2-CHLOROPHENOL
2-METHYL-4,6-DINITROPHENOL
2-METHYLNAPHTHALENE
2-METHYLPHENOL
2-NITROANILINE
2-NITROPHENOL
3,3' -DICHLOROBENZIDINE
3-NITROANILINE
4-BROMOPHENYL PHENYL ETHER
4-CHLOR0-3-METHYLPHENOL
4-CHLOROANILINE
4-CHLOROPHENYL PHENYL ETHER
4-METHYLPHENOL
4-NITROANILINE
4-NITROPHENOL
ACENAPHTHENE
ACENAPHTHYLENE
ANTHRACENE
BENZO(A)ANTHRACENE
BENZO{A)PYRENE
BENZO(B)FLUORANTHENE
BENZO(G,H,I)PERYLENE
BENZO(K)FLUORANTHENE
BENZOIC ACID
BENZYL ALCOHOL
BIS(2-CHLOROETHOXY)METHANE
BIS(2-CHLOROETHYL)ETHER
BIS(2-CHLOROIS0PROPYL)ETHER
'
'
'
'
'
'
'
'
'
'
'
'
'
'
'
'
'
'
'
'
'
'
'
'
'
'
'
'
'
'
'
'
'
'
'
Result
0 .010
0. 010
0. 010
o. 010
0 .010
0 .010
0 .010
0 .010
0 .025
0 .010
0 .010
0. 010
o. 010
o. 025
0.010
0 .010
0 .010
0 .010
0 .010
0.010
0 .010
0 .010
0 .010
0.010
0 .010
0 .010
0. 025
0 .010
0 .010
0. 010
0 .010
0. 010
0 .010
o. 010
0 .010
0 . 050
0.010
0 .010
0 .010
0 .010
NC Certification Number: 25
Project Number: 61195.02
Report Date August 21, 2002
Page 1 of 3 Report ID: AA29237
Sample ID L020B0818-05
Date Collected: 07-AUG-02 11 :45
Date Received 08-AUG-02
Qual RDL Units Analyst Date Time
o. 010 mg/1 JRN 08/15/02 1837
0 .010 mg/1 JRN 08/15/02 1837
0 .010 mg/1 JRN 08/15/02 1837
o. 010 mg/1 JRN 08/15/02 1837
0 .010 mg/1 JRN 08/15/02 1837
0 .010 mg/1 JRN 08/15/02 1837
0 .010 mg/1 JRN 08/15/02 1937
0. 010 mg/1 JRN 08/15/02 1837
0 .025 mg/1 JRN 08/15/02 1837
0 .010 mg/1 JRN 08/15/02 1837
0 .010 mg/1 JRN 08/15/02 1837
0 .010 mg/1 JRN 08/15/02 1837
0 .010 mg/1 JRN 08/15/02 1837
o. 025 mg/1 JRN 08/15/02 1837
o. 010 mg/1 JRN 08/15/02 1837
0 .010 mg/1 JRN 08/15/02 1837
0 .010 mg/1 JRN 08/15/02 1837
0 .010 mg/1 JRN 08/15/02 1837
0 .010 mg/1 JRN 08/15/02 1837
0. 010 mg/1 JRN 08/15/02 1837
0 .010 mg/1 JRN 08/15/02 1837
0 .010 mg/1 JRN 08/15/02 1837
0 .010 mg/1 JRN 08/15/02 1837
0.010 mg/1 JRN 08/15/02 1837
0 .010 mg/1 JRN 08/15/02 1837
0 .010 mg/1 JRN 08/15/02 1837
0. 025 mg/1 JRN 08/15/02 1837
0 .010 mg/1 JRN 08/15/02 1837
o. 010 mg/1 JRN 08/15/02 1837
0.010 mg/1 JRN 08/15/02 1837
o. 010 mg/1 JRN 08/15/02 1837
0 .010 mg/1 JRN 08/15/02 1837
0 .010 mg/1 JRN 08/15/02 1837
0 .010 mg/1 JRN 08/15/02 1837
0 .010 mg/1 JRN 08/15/02 1837
o . 050 mg/1 JRN 08/15/02 1837
0 .010 mg/1 JRN 08/15/02 1837
0 .010 mg/1 JRN 08/15/02 1837
0 .010 mg/1 JRN 08/15/02 1837
0 .010 mg/1 JRN 08/15/02 1837
Davis & Floyd, 1nc. I PO Drawer 428 I Greenwood, SC 29(,48 I 816 E. Durst Avenue Greenwood, SC 29649 I (fl64) 229-4413 I Fax [phone]
3 7 •
Di\YIS
FLOYD LABORATORY ANALYSIS REPORT
NELAC Certification Number: £87633
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY. 198
SHELBY, NC 28152
PEM CARTER
Client ID: PEW-4
Parameter
BIS{2-ETHYLHEXYL)PHTHALATE
BUTYL BENZYL PHTHALATE
CHRYSENE
D1-N-BUTYL PHTHALATE
D1-N-OCTYL PHTHALATE
DIBENZ(A,H)ANTHRACENE
DIBENZOFURAN
DIETHYL PHTHALATE
DIMETHYL PHTHALATE
FLUORANTHENE
FLUORENE
HEXACHLOROBENZENE
HEXACHLOROBUTADIENE
HEXACHLOROCYCLOPENTADIENE
HEXACHLOROETHANE
INDENO(l,2,3-CO)PYRENE
ISOPHORONE
N-NITROSODI-N-PROPYLAMINE
N-NITROSODIPHENYLAMINE
NAPHTHALENE
NITROBENZENE
PENTACHLOROPHENOL
PHENANTHRENE
PHENOL
PYRENE
SW846 B270C DOWTHERM
1, l' -BI PHENYL
BI PHENYL ETHER
Volatile Organics
SW846 8260B
l,l,l-TRICHLOROET!-W-1E
1,1,2,2-TETRACHLOROETHANE
1,1,2-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
1,2-DICHLOROETHANE
1,2-DICHLOROPROPi\NE
2-BUTANONE
2-HEXANONE
4-METHYL-2-PENTANONE
ACETONE
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
Result
0. 010
0 .010
o. 010
0 .010
0. 010
0 .010
0 .010
o. 010
0 .010
0 .010
0 .010
0. 010
0 .010
0 .010
0 .010
0.010
0.010
0. 010
o. 010
0 .010
0.010
0.025
o. 010
0. 010
0 .010
0.010
0.035
0.0010
0.0010
0.0010
0.0010
0.0010
0 .0010
0 . 0010
0 .0050
0 . 0050
0 .0050
0.0050
NC Certification Number: 25
Project Number: 61195. 02
Report Date August 21, 2002
Page 2 of 3 Report ID: AA29237
Sample ID L02080818-05
Qual RDL Units Analyst Date Time
0. 010 mg/1 JRN 08/15/02 1837
0 .010 rng/1 JRN 08/15/02 1837
0. 010 rng/1 JRN 08/15/02 1837
0 .010 mg/1 JRN 08/15/02 1837
o. 010 mg/1 JRN 08/15/02 1837
0 .010 mg/1 JRN 08/15/02 1837
0 .010 mg/1 JRN 08/15/02 1837
0. 010 mg/1 JRN 08/15/02 1837
o. 010 mg/1 JRN 08/15/02 1837
o. 010 mg/1 JRN 08/15/02 1837
o. 010 mg/1 JRN 08/15/02 1837
0. 010 mg/1 JRN 08/15/02 1837
0 .010 rng/1 JRN 08/15/02 1837
o. 010 mg/ 1 JRN 08/15/02 1837
0 .010 mg/1 JRN 08/15/02 1837
0 .010 mg/1 JRN OB/15/02 1837
0. 010 rng/1 JRN 08/15/02 1B37
0. 010 rng/1 JRN OB/15/02 1837
0 .010 mg/1 JRN 08/15/02 1837
o. 010 rng/1 JRN 08/15/02 1B37
0 .010 rng/1 JRN 08/15/02 1837
0. 025 rng/1 JRN 08/15/02 1837
0. 010 mg/1 JRN 08/15/02 1837
0 .010 mg/1 JRN 08/15/02 1837
0 .010 mg/1 JRN 08/15/02 1837
0 .010 mg/1 JRN 08/15/02 1837
0. 010 mg/1 JRN 08/15/02 183 7
0 .0010 mg/1 PAP 08/13/02 141B
o. 0010 mg/1 PAP 08/13/02 1418
0 .0010 mg/1 PAP 08/13/02 1418
0. 0010 mg/1 PAP 08/13/02 1418
0 . 0010 mg/1 PAP 08/13/02 1418
0 .0010 mg/1 PAP 08/13/02 1418
0 .0010 mg/1 PAP 08/13/02 1418
0 .0050 rng/1 PAP 08/13/02 1418
0 .0050 mg/1 PAP 08/13/02 1418
o. 0050 mg/1 PAP 08/13/02 1418
o. 0050 mg/1 PAP 08/13/02 1418
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1!
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue
38
I G,eenwood, SC 2%49 I 1864) 229-4413 I Fa, (864) 229-71191
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Df\YIS
FLbYD LABORATORY ANALYSIS REPORT
NELAC Certification Number: £87633
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY. 198
SHELBY, NC 28152
PEM CARTER
Client ID: PEW-4
Parameter
BENZENE
BROMODICHLOROMETHANE
BROMOFORM
BROMOMETHANE
CARBON DISULFIDE
CARBON TETRACHWRIDE
CHLO RO BENZENE
CHLOROETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-0ICHLOROETHENE
CIS-1,3-DICHLOROPROPENE
OIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-DICHLOROETHENE
TRANS-1,3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL)
Prep Procedure
Analytical Prep Procedures:
BNA SEMIVOLATILES
OOWTHERM
Method
SW846 35008
SW846 35008
Result
0.0041
< 0.0010
< 0.0010
< 0 . 0010
< 0 .0010
< o. 0010
< o. 0010
< 0 . 0010
< 0 .0010
< 0 .0010
0.010
< o. 0010
< 0 .0010
< 0 . 0010
< o. 0010
< o. 0010
< 0. 0010
< 0.0010
< 0.0010
< 0. 0010
0.017
< 0 .0010
< 0 . 0010
< 0 . 0020
Analyst Prep Date
DBC OB/08/02
DBC 08/08/02
NC Cenification Number: 25
Project Number, 61195.02
Report Date August 21, 2002
Page 3 o[ 3 Report ID: AA29237
Sample ID L02080818-05
Qual RDL Units Analyst Date Time
0. 0010 mg/1 PAP 08/13/02 1418
0 .0010 mg/1 PAP 08/13/02 1418
0 .0010 mg/1 PAP 08/13/02 1418
0 . 0010 mg/1 PAP 08/13/02 1418
0. 0010 mg/1 PAP 08/13/02 1418
0 .0010 mg/1 ]?AP 08/13/02 1418
0 . 0010 mg/1 PAP 08/13/02 1418
o . 0010 mg/1 PAP 08/13/02 1418
0 . 0010 mg/1 PAP 08/13/02 1418
0 .0010 rng/1 PAP 08/13/02 1418
0 .0010 mg/ l PAP OB/13/02 1418
o. 0010 mg/1 PAP 08/13/02 1418
0 .0010 mg/1 PAP 08/13/02 1418
o . 0010 mg/1 PAP 08/13/02 1418
0 .0010 mg/1 PAP 08/13/02 1418
0 .0010 mg/1 PAP 08/13/02 1418
0. 0010 mg/1 PAP 08/13/02 1418
0. 0010 mg/1 PAP 08/13/02 1418
o. 0010 mg/1 PAP 08/13/02 1418
0 .0010 rng/1 PAP 08/13/02 1418
0 .0010 mg/1 PAP 08/13/02 1418
0 .0010 mg/1 PAP 08/13/02 1418
o . 0010 mg/1 PAP 08/13/02 1418
0 . 0020 mg/1 PAP 08/13/02 1418
1500
1500
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I (864) 229-441] I Fax [phone]
39
Di\YIS
FLOYD LABORATORY ANALYSIS REPORT
NELAC Cenijication Number: £87633
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY. 198
SHELBY, NC 28152
PEM CARTER
Client ID: K-28
Matrix
Parameter
Volatile Organics
SW846 8260B
1,1,1-TRICHLOROETHANE
1,1,2,2-TETRACHLOROETHANE
1,1,2-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
1,2-DICHLOROETHANE
1,2-DICHLOROPROPANE
2-BUTANONE
2-HEXANONE
4-METHYL-2-PENTANONE
"ACETONE
BENZENE
BROMODICHLOROMETHANE
BROMOFORM
BROMOMETHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROETrW'JE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-DICHLOROETHENE
CIS-1,3-DICHLOROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-0ICHLOROETHENE
TRANS-1,3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL)
Wet Chemi11try
SW846 9060
ORGANIC CARBON, TOTAL
GW/ChemW
Result
< 0 . 0010
< 0 .0010
< o. 0010
< 0 .0010
< 0 .0010
< 0 .0010
< 0 .0010
0.17
< 0 .0050
< 0 .0050
0.18
0.0087
< 0.0010
< 0.0010
< 0.0010
0.0020
< 0. 0010
< 0. 0010
< 0 . 0010
< 0 . 0010
0.0022
< 0 .0010
< 0. 0010
< 0 .0010
< 0. 0010
< 0 .0010
< 0. 0010
< 0. 0010
0.0025
< 0 .0010
< 0 .0010
< 0 .0010
< 0 .0010
< 0. 0010
< o. 0020
1990
NC Certification Number: 25
Project Number: 61195.02
Report Date August 21, 2002
Page 1 of 1 Report ID: AA29232
Sample ID L02080818-06
Date Collected; 07-AUG-02 14 :20
Date Received 08-AUG-02
Qual RDL Units Analyst Date Time
0. 0010 mg/1 PAP 08/13/02 1441
0 .0010 mg/1 PAP 08/13/02 1441
0 .0010 mg/1 PAP 08/13/02 1441
o. 0010 mg/1 PAP 08/13/02 1441
0 . 0010 mg/1 PAP 08/13/02 1441
0.0010 mg/1 PAP 08/13/02 1441
0.0010 mg/1 PAP 08/13/02 1441
0.010 mg/1 PAP 08/13/02 1857
0.0050 mg/1 PAP 08/13/02 14 41
0.0050 mg/1 PAP 08/13/02 1441
0.0050 mg/1 PAP 08/13/02 1441
0.0010 mg/1 PAP 08/13/02 1441
0.0010 mg/1 PAP 08/13/02 1441
0,0010 mg/1 PAP 08/13/02 1441
0.0010 mg/1 pJllf""'o8/13/02 1441
0.0010 mg/1 PAP 08/13/02 1441
0.0010 mg/1 PAP 08/13/02 1441
0.0010 mg/1 PAP 08/13/02 1441
0.0010 mg/1 PAP 08/13/02 1441
0.0010 mg/1 PAP 08/13/02 1441
0.0010 mg/1 PAP 08/13/02 1441
0.0010 mg/1 PAP 08/13/02 1441
0.0010 mg/1 PAP 08/13/02 1441
0.0010 mg/1 PAP 08/13/02 1441
0.0010 mg/1 PAP 08/13/02 1441
0.0010 mg/1 PAP 08/13/02 1441
0 .0010 mg/1 PAP 08/13/02 1441
0 .0010 mg/1 PAP 08/13/02 1441
0 .0010 mg/1 PAP 08/13/02 1441
o. 0010 mg/1 PAP 08/13/02 1441
0 .0010 mg/1 PAP 08/13/02 1441
0. 0010 mg/1 PAP 08/13/02 1441
o·. 0010 mg/1 PAP 08/13/02 1441
0.0010 mg/1 PAP 08/13/02 1441
0.0020 mg/1 PAP 08/13/02 1441
100 mg/1 CLB 08/12/02 1128
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40
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 l [phone] I Fax [phone] I
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DAYIS
FLOYD LABORATORY ANALYSIS REPORT
NELAC Cer1ificatio11 Number: £87633
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY. 198
SHELBY, NC 2B152
PEM CARTER
Client ID: V-23
Matrix
Parameter
Volatile Organics
SW846 8260B
1,1,1-TRICHLOROETHANE
1,1,2,2-TETRACHLOROETHANE
1,1,2-TRICHLOROETHANE
1,1-0ICHLOROETHANE
1,1-DICHLOROETHENE
1,2-DICHLOROETHANE
1, 2-DICHI.OROPROPANE
2-BUTANONE
2-HEXANONE
4-METHYL-2-PENTANONE
ACETONE
BENZENE
BROMOD I CHLOROMETHANE
BROMOFORM
BROMOMETHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROETHANE
CHLOROF'ORM
CHLOROMETHANE
CIS-1,2-DICHLOROETHENE
CIS-1,3-DICHLOROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-DICHLOROETHENE
TRANS-1,3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL)
Wet Chemistry
SW846 9060
ORGANIC CARBON, TOTAL
GW/ChemW
Result
< 0 . 0050
< 0 .0050
< 0 .0050
< o. 0050
< 0 . 0050
< 0 .0050
< 0 .0050
0. 34
< 0.025
< 0.025
0.47
0.020
< 0. 0050
< 0 .0050
< 0 .0050
0.011
< 0 . 0050
< 0 .0050
< 0 . 0050
< 0 .0050
< 0 .0050
< o. 0050
< 0. 0050
< 0 .0050
< 0 . 0050
< 0 . 0050
< 0 .0050
< 0. 0050
0.0071
< 0.0050
< 0.0050
< 0.0050
0.0053
< 0.0050
0.010
10500
NC Certification Number: 25
Project Number: 61195.02
Report Date
Page 1 of 1
Sample ID
August 21, 2002
Report ID: M2923B
L02080B18-07
Date Collected: 07-AUG-02 16:08
Date Received 08-AUG-02
Qual RDL Units Analyst Date
X 0 .0050 mg/1 PAP 08/13/02
X 0 . 0050 mg/1 PAP 08/13/02
X 0 .0050 mg/1 PAP 08/13/02
X 0 .0050 mg/1 PAP 08/13/02
X o . 0050 mg/1 PAP 08/13/02
X 0.0050 mg/1 PAP 08/13/02
X 0.0050 mg/1 PAP 08/13/02
0.025 mg/1 PAP 08/13/02
X 0.025 mg/1 PAP 08/13/02
X 0.025 mg/1 PAP 08/13/02
0.025 mg/1 PAP 08/13/02
0.0050 mg/1 PAP 08/13/02
X 0 . 0050 mg/1 PAP 08/13/02
X 0 .0050 mg/1 PAP 08/13/02
X 0 .0050 mg/1 PAP 08/13/02
0. 0050 mg/1 PAP 08/13/02
X 0 . 0050 mg/1 PAP 08/13/02
X 0 .0050 mg/1 PAP 08/13/02
X 0 .0050 mg/1 PAP 08/13/02
X 0 . 0050 mg/1 PAP 08/13/02
X 0.0050 mg/1 PAP 08/13/02
X 0.0050 mg/1 PAP 08/13/02
X 0 . 0050 mg/1 PAP 08/13/02
X 0 .0050 mg/1 PAP 08/13/02
X o . 0050 mg/1 PAP 08/13/02
X o . 0050 mg/1 PAP 08/13/02
X 0 . 0050 mg/1 PAP 08/13/02
X 0 . 0050 mg/1 PAP 08/13/02
0 .0050 mg/1 PAP 08/13/02
X o. 0050 mg/1 PAP 08/13/02
X 0. 0050 mg/1 PAP 08/13/02
X o. 0050 mg/1 PAP 08/13/02
0 . 0050 mg/1 PAP 08/13/02
X 0. 0050 mg/1 PAP 08/13/02
X 0. 010 mg/1 PAP 08/13/02
Time
1504
1504
1504
1504
1504
1504
1504
1504
1504
1504
1504
1504
1504
1504
1504
1504
1504
1504
1504
1504
1504
1504
1504
1504
1504
1504
1504
1504
1504
1504
1504
1504
1504
1504
1504
200 mg/1 CLB 08/12/02 1149
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 F.. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
41
Dl\VIS
FLtrYD LABORATORY ANALYSIS REPORT
NELAC Certification Number: £87633
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY. 198
SHELBY, NC 28152
PEM CARTER
Client ID: V-23 DUP.
Matrix
ParaJl\eter
Volatile Organics
SW846 8260B
1,1,1-TRICHLOROETHANE
1,1,2,2-TETRACHLOROETHANE
1,1,2-TRICHLOROETHANE
1,1-0ICHLOROETHANE
1,1-DICHLOROETHENE
1,2-DICHLOROETHANE
1,2-DICHLOROPROPANE
2-BUTANONE
2-HEXANONE
4-METHYL-2-PENTANONE
ACETONE
BENZENE
BROMODICHLOROMETHANE
BROMOFORM
BRO MOM ETHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROETHANE
CHLOROF'ORM
CHLOROMETHANE
CIS-1,2-DICHLOROETHENE
CIS-1,3-DICHLOROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-DICHLOROETHENE
TRANS-1,3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL)
Wet Chemistry
SW846 9060
ORGANIC CARBON, TOTAL
GW/Chemw
Result
< 0 . 0050
< 0 . 0050
< 0 .0050
o. 0050
< 0. 0050
< 0.0050
< 0.0050
0.32
< 0.025
< 0.025
0.45
0.019
< 0 .0050
< 0 .0050
< 0 .0050
0.013
< 0.0050
< 0.0050
< 0.0050
< 0. 0050
< 0. 0050
< o. 0050
< 0.0050
< 0.0050
< o.ooso
< 0 .0050
< 0. 0050
< 0 . 0050
0.0072
< 0. 0050
< 0 .0050
< 0 .0050
0.0062
< 0.0050
< 0. 010
10,00
NC Certification Number: 25
Project Number: 61195.02
Report Date August 21, 2002
Page l of l Report ID: AA29239
Sample ID L0208081B-08
Date Collected: 07-AUG-02 16: 08
Date Received 08-AUG-02
Qual RDL Units Analyst Date Time
X 0 . 0050 mg/1 PAP 08/13/02 1527
X 0 .0050 mg/1 PAP 08/13/02 1527
X 0 .0050 mg/1 PAP 08/13/02 1527
X o. 0050 mg/1 PAP 08/13/02 1527
X 0 .0050 mg/1 PAP 08/13/02 1527
X 0 .0050 mg/1 PAP 08/13/02 1527
X 0 .0050 mg/1 PAP 08/13/02 1527
0 .025 mg/1 PAP 08/13/02 1527
X o. 025 mg/1 PAP 08/13/02 1527
X o. 025 mg/1 PAP 08/13/02 1527
0 .025 mg/1 PAP 08/13/02 1527
0 .0050 mg/1 PAP 09/13/02 1527
X 0 . 0050 mg/1 PAP 08/13/02 1527
X 0 .0050 mg/1 PAP 08/13/02 1527
X 0 .0050 mg/1 PAP 08/13/02 1527
o. 0050 mg/1 PAP 08/13/02 152 7
X 0.0050 mg/1 PAP 08/13/02 1527
X o. 0050 mg/1 PAP 09/13/02 1527
X o. 0050 mg/1 PAP 08/13/02 1527
X 0 .0050 mg/1 PAP 08/13/02 1527
X o. 0050 mg/1 PAP 08/13/02 1527
X 0. 0050 mg/1 PAP 09/13/02 1527
X 0 . 0050 mg/1 PAP 08/13/02 1527
X 0 .0050 mg/1 PAP 08/13/02 1527
X 0 . 0050 mg/1 PAP 08/13/02 1527
X 0 . 0050 mg/1 PAP 08/13/02 1527
X o. 0050 mg/1 PAP 08/13/02 1527
X 0 . 0050 mg/1 PAP 09/13/02 1527
0 . 0050 mg/1 PAP 08/13/02 1527
X 0 .0050 mg/1 PAP 08/13/02 1527
X 0 .0050 mg/1 PAP 08/13/02 1527
X 0 .0050 mg/1 PAP 08/13/02 1527
0. 0050 mg/1 PAP 08/13/02 1527
X 0. 0050 mg/1 PAP 08/13/02 1527
X 0. 010 mg/1 PAP 08/13/02 1527
200 mg/1 CLB 08/12/02 1156
Ir
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l);ivis & Floyd, Inc. I PO Drawer 42B I Greenwood, SC 2964B I H16 E. Durst Avenue I Greenwood, SC 29649 I (H64) 229-441]
42
I fax [phone] l l 91
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DAYIS
FLtJfD LABORATORY ANALYSIS REPORT
NELAC Cenijication Number: £87633
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY. 198
SHELBY, NC 28152
PEM CARTER
Client ID: TRIP BLANK #2
Matrix
Para.meter
Volatile Organics
SW84 6 8260B
1,1,1-TRICHLOROETHANE
1,1,2,2-TETRACHLOROETHANE
1,1,2-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-0ICHLOROETHENE
1,2-DICHLOROETHANE
1,2-DICHLOROPROPANE
2-BUTANONE
2-HEXANONE
4-METHYL-2-PENTANONE
ACETONE
BENZENE
BROMODICHLOROMETHANE
BROMOFORM
BROMOMETHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-DICHLOROETHENE
CIS-1,3-DICHLOROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-DICHLOROETHENE
TRANS-1,3-0ICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL)
GW/Chemw
Result
' 0 .0010
' 0 . 0010
' 0 . 0010
' 0 .0010
' 0 .0010
' 0 .0010
' 0 . 0010
' 0 . 0050
' 0 . 0050
' 0. 0050
' 0 . 0050
' 0 .0010
' 0 .0010
' 0 . 0010
' 0. 0010
0 .0010
' 0. 0010
' 0.0010
' 0.0010
' 0.0010
' 0 . 0010
' o. 0010
' 0 . 0010
' 0. 0010
' 0 . 0010
' 0 . 0010
' 0 .0010
' o. 0010
' 0 . 0010
' 0 . 0010
' 0. 0010
' 0 . 0010
' 0 .0010
' o. 0010
' 0 . 0020
NC Cenification Number: 25
Project Number, 61195.02
Report Date
Page 1 of 1
Sample ID
Date Collected:
Date Received
August 21, 2002
Report ID: AA29240
L02080818-09
08-AUG-02
Qual RDL Units Analyst Date
0 .0010 mg/1 PAP 08/13/02
0 .0010 mg/1 PAP 08/13/02
o . 0010 mg/1 PAP 08/13/02
0 .0010 mg/1 PAP 08/13/02
o. 0010 mg/1 PAP 08/13/02
0 .0010 mg/1 PAP 08/13/02
o . 0010 mg/1 PAP 08/13/02
0 . 0050 mg/1 PAP 08/13/02
0 . 0050 mg/1 PAP 08/13/02
o. 0050 mg/1 PAP q0/u/02
o . 0050 mg/1 PAP 08/13/02
0 .0010 mg/1 PAP 08/13/02
0 .0010 mg/1 PAP 08/13/02
o . 0010 mg/1 PAP 08/13/02
o. 0010 mg/1 PAP 08/13/02
0 .0010 mg/1 p~p 08/13/02
0 .0010 mg/1 PAP 08/13/02
o. 0010 mg/1 PAP 08/13/02
0 .0010 mg/1 PAP 06/13/02
0 .0010 mg/1 PAP 08/13/02
0 . 0010 lllg/1 PAP 08/13/02
0 .0010 mg/1 PAP 08/13/02
o . 0010 mg/1 PAP 08/13/02
0 .0010 mg/1 PAP OB/13/02
o . 0010 mg/1 PAP 08/13/02
0 . 0010 mg/1 PAP 08/13/02
0 .0010 mg/1 PAP 08/13/02
0 .0010 mg/1 PAP 08/13/02
o . 0010 mg/1 PAP 08/13/02
0.0010 mg/1 PAP 08/13/02
0 .0010 mg/1 PAP 08/13/02
o . 0010 mg/1 PAP 08/13/02
0 .0010 mg/1 PAP 08/13/02
0 .0010 mg/1 PAP 08/13/02
o . 0020 mg/1 PAP 08/13/02
Time
0826
0826
0826
0826
0826
0826
0826
0826
0826
0826
0826
0826
0826
0826
0826
0626
0626
0826
0626
0026
0B26
0826
0826
0826
0826
0B26
0826
0826
0826
0826
0826
0826
0826
0826
0826
Davis & Floyd, Inc. l PO Drawer 428 j Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] l Fax [phone]
43
- - - - -D~IS "'"""01
J/ditffllfe FL YD imnoDou1&""""'"1lmi"' -- ---- ----Chain of Custody Record
Client Project I Site Location 816 E. Durst Avenue, Greenwood. SC 29649 [phone] Fax: [phone]
C.N.A. Holdings/Ticona 61195.02 Laboratory Certifcation Numbers: SC-24110, NC-25, TN-2923, VA-77
Shelby.NC For Kubal-Furr
Contact ;~rt To Copy To Reporting Requirements: [) Standard { J Data Package (Specify LeveQ
½:it11, tl.ft-71/3',-kf'+A £J.f (',W-,,..2_ --'"fic,,,vlk :::r-v v~ L,✓e:,.;oc,-kf',,-4
Collected By~ Required Parameters, Containers and Prese,vatives
;:-, rJS,q .Ani " " " ✓ u £ '17,J Fu;2f2 E ~ E " ~ 0 ::, ~ ~ ~
NOTICE: ~ ~ e • C ~;i ~ 8 §
0 in • C, 5 t a. .~ 0 0
E '= w . " • N • Su : ~ 0 X "-C
~ D D < • E ,; E ,. C, 0~ Sample Collection !.§. .~ e • j! 0 5 0 r;; ~ " " > w
Sample Descriotion Date Time Time Type Total C A B A
Trip Blank -p=--,;;_ ty X
Fr-3LI .. I Wu 2 JI, '33 ✓ ~ 3 X
Ec-r-~ ¾.l;)-/,ft)o ✓ .s 3 X
CC-33 li-/4/4;2 /9,,~ ./ ~ 3 X
r-s-f' S/7/4 '> )/o< V s-3 K
'Jcw-r./ l<fhJi /It/~ v' S' ,j -../ X
t:-J~ J0/2/47-li./)0 ,.. S" ti X X
V-?'3 rrh/,; ;/,oJ ✓ IS '-I X X
V-)3-buf ~/21. )-;(,,of: ./ _j tf X ')(
/1 I
Ro/J:!'"""r, Z, . J;1, Time Re/iquished By Date Time R°Ztri%~$_ ¼'.'le Time
/f.l,<' & -z.. J/,. ,s ·•. ·,u1 -:;t I ,I -./
, ,
/R~ =te lime ReclJx/ /;} //, Ci. t.l,;% Time rif_~0~""fii~;JJ{j 1/2.S
Date Time
vkf A€0f ½)?-;,f).~ b u1. ,so0 9.fo~ /~15
1..,omments I
MatriX Type Oefirnlions 1 -Dnnkmg Water 2 -Clean Water 5 -Groundwater 7 So!I/Sed1ment 8 L1qu1d Sludge 9 011 12 PJr
PreservaUve Definitions A -None B -H2S04 C -HG! D -HN03 E -Na OH F -Filtered G -.1 N HCUpH 4 to 5
- ---Page_j_of_L
1i1 ,ce iJse I n,v
IPurr;hase Older
State Quote
NC
LOQJn Special lnstruclions
""" i; -!ii! I i ~ ,_ ~
0 " ii Is ..J """"°" HOT 1:ommenfs
()a l,/.. ~ . / iU" ,C'
(}/ oo'>.r1/I
() ')., -9 /...,0.,f OS"
173
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~f;'
01p
07
og
Qwck 6 Shi~ w= y N ~,~
If Y. splK;ily: Airbi/1 Number
.L•ar•
Coote, ID ~le)c ----
On Ice: Yes Temp(C) /J-.
Custody Seal: Intact / Broken /NonJ
Davis & Flo yd. Inc.
FL02_01 (02199)
.... ....
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DAYIS
FLOYD LABORATORY ANALYSIS REPORT
QC Su111111ary Data
I Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. DursJ Avenue I Greenwood, SC 29649 I [phone] I (ax (8641229-7119
45 '
Di\YIS
FLOYD LABORATORY ANALYSIS REPORT
Method Conformance Summary
Client: Ticona, LLC
Login(s): L02080702
Criteria Volatiles
Samole Holdine Time
Standards Prenaration
Instrument Tunine
Instrument Calibration
Calibration Verification
Deeradation Check
Interference
SamnlelStandard
Blanks Results
Method Accuracv
Method Precision
Surrogate Recoverv
PDSISD/MSA
TCLP Preoaration
✓
NIA
Met Criteria Met
Not Applicable
✓
✓
✓
✓
✓
NIA
NIA
✓
✓
✓
✓
NIA
NIA
Semi
Volatiles
✓
✓
✓
✓
✓
NIA
NIA
✓
✓
✓
✓
NIA
NIA
Metals
NIA
NIA
NIA
NIA
NIA
NIA
NIA
NIA
NIA
NIA
NIA
NIA
NIA
•
PDS =
SD =
MSA=
Method Criteria Not Met-Seefootnote(s) below .
Post Digestion Spike
Serial Dilution
Method of Standard Additions
Footnotes:
Project Number: 6 I 995.02
Report Date: August 27, 2002
Ethylene
TOC Glvcol
✓ ✓
✓ ✓
NIA NIA
✓ ✓
✓ ✓
NIA NIA
NIA NIA
✓ ✓
✓ ✓
✓ ✓
NIA NIA
NIA NIA
NIA NIA
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Davis K Floyd, Inc. I PO Drawe, 428 I G,eenwood, SC 29648 I 816 4 ~u,st Avenue I G,eenwood, SC 2%49 I (864J 229-441 :l I fa, l!lfAl 229-7 l l 9 I
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DAYIS
FLtlYD LABORATORY ANALYSIS REPORT
QC Batch Report
WorkGro~p WG31077
Description: VO/8260/TCL Special RDL
Sample ID
L02080702-04
L02080702-04
L02080702-0S
L02080702-06
L02080702-07
L02080702-08
L02080702-09
L02080702-10
L02080702-ll
L02080702-12
L02080702-13
L02080702-14
L02080702-15
LCS31077:1
LCS31077:l
MB31077:
MB31077:
MS02080702-04:31077
MS02080702-04:31077
MSD02080702-04:31077
MSD02080702-04:31077
Client ID
HH-77
HH-77
HH-48
AA-54
T-35
GG-61
PEW-1
PEW-3
C-49
F-55
PF-62
TRIP BLANK #1
EQUIPMENT BLANK
Laboratory Control Spike
Laboratory Control Spike
Method Blank
Method Blank
Matrix Spike
Matrix Spike
Matrix Spike Duplicate
Matrix Spike Duplicate
2
1
1
1
1
1
2
1
2
1
2
1
2
Report Date
Page 1 of 1
Matrix
Prep Method
August 21, 2002
Report ID: AA29252
GW/ChemW
Analtyical Method: SW846 82608
PRBP
Date Time
ANALYTICAL
Date Time
08/12/02 1354
08/13/02 0849
08/12/02 1417
08/12/02 1440
08/12/02 1503
08/12/02 1526
08/12/02 1548
08/12/02 1611
08/12/02 1634
08/12/02 1851
08/12/02 1657
08/12/02 1309
08/12/02 1331
08/12/02 1806
08/13/02 1113
08/12/02 1246
08/13/02 0741
08/12/02 1720
08/13/02 0912
08/12/02 1743
08/13/02 1050
Analyst Dilution
PAP
PAP ' PAP
PAP
PAP
PAP 1
PAP
PAP.
PAP
PAP 3
PAP
PAP
PAP
PAP 1
PAP
PAP
PAP
PAP 1
PAP
PAP
PAP '
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 2%49 I [phone] I Fax (tl64) 229-7119
47
I
Df\VIS
FLOYD LABORATORY ANALYSIS REPORT I
I
Surrogates % Recovery
I
Report Date August 21, 2002
Page 1 of Report ID: M29268 I Matrix GW/ChemW
Method SW846 8260 I
L02080702-04 13-AUG-02 08 : 49 118 104 102
L02080702-04 12-AUG-02 13 :54 115 107 105 I
L02080702-05 12-AUG-02 14 :17 117 106 103
L02080702-06 12-AUG-02 14: 40 115 109 108
L02080702-07 12-AUG-02 15: 03 118 106 104 I
L02080702-08 12-AUG-02 15: 26 115 103 100
L02080702-09 12-AUG-02 15 : 48 1.16 105 105
L02080702-10 12-AUG-02 16: 11 119 102 103
L02080702-ll 12-AUG-02 16: 34 12 0 105 lOS I
L02080702-12 12-AUG-02 18 : 51 125 107 104
L02080702-13 12-AUG-02 16:57 121 104 101
L02080702-14 12-AUG-02 13; 09 107 105 106
L02080702-15 12-AUG-02 13 : 31 112 104 104 I
LCS31077: 13-AUG-02 11: 13 115 103 101
LCS31077: 1 12 -AUG-02 18: 06 124 108 104
MB31077: 1 13-AUG-02 07:41 108 104 104 I
M831077:l 12-AUG-02 12:46 96 101 106
MS02080702-04:31077 13-AUG-02 09:12 113 107 107
MS02080702-04:31077 12-AUG-02 17: 20 119 103 103
MSD02080702-04 :31077 13-AUG-02 10: so 111 104 104 I
MSD02080702-04:31077 12-AUG-02 17:4] 125 105 104
DCE 1,2-DICHLOROETHANE-D4 I
BFB BROMOFLUOROBENZENE
TOL TOLUENE-DB
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Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue j Greenwood, SC 29649 I [phone]
48
I Fax [phone] I
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DAYIS
FLbYD
Method Blanks
Blank
Parameter
Volatile Organics
SW846 8260B
1,1,1-TRICHLOROETHANE
1,1,2,2-TETRACHLOROETHANE
1,1,2-TRICHLOROETHANE
1, 1-DICHLOROETHANE
1,1-DICHLOROETHENE
1,2-DICHLOROETHANE
1,2-DICHLOROPROPANE
2-BUTANONE
2-HEXANONE
4-METHYL-2-PENTANONE
ACETONE
BENZENE
BROMODICHLOROMETHAN~
BROMOF'ORM
BROMOMETHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-DICHLOROETHENE
CIS-1,3-DICHLOROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-DICHLOROETHENE
TRANS-1,3-DICHLOROPROPENE
TRICHLOROETHENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE {TOTAL)
MB31077:l
LABORATORY ANALYSIS REPORT
Report Date August 21, 2002
Page 1 of Report ID: AA29253
Matrix GW/Chemw
WorkGroup: WGJ 1077
Cone Qual RDS units Analyst Date Time
< .o .o ug/1 PAP 08/12/02 124 6
.o .o ug/1 PAP 08/12/02 124 6
< 1. 0 .o ug/1 PAP 08/12/02 1246
< 1. 0 . 0 ug/1 PAP 08/12/02 1246
< 1. 0 1 .o ug/1 PAP 08/12/02 1246
< 1. 0 1. 0 ug/1 PAP 08/12/02 1246
< .o .o ug/1 PAP 08/12/02 124 6
< 5. 0 5. 0 ug/1 PAP 08/12/02 1246
< 5. 0 5. 0 ug/1 PAP 08/12/02 124 6
< 5. 0 5. 0 ug/1 PAP 08/12/02 1246
< 5. 0 5. 0 ug/1 PAP 08/12/02 124 6
< .o .o ug/1 PAP 08/12/02 1246
< 1. 0 1. 0 ug/1 PAP 08/12/02 1246
< 1. 0 1. 0 ug/1 PAP 08/12/02 1246
< 1. 0 1. 0 ug/1 PAP 08/12/0i 1246
< 1. 0 . 0 ug/1 PAP 08/12/02 1246
< 1. 0 . 0 ug/1 PAP 08/12/02 1246
< 1. 0 1 .o ug/1 PAP 08/12/02 1246
< .o 1. 0 ug/1 PAP 08/12/02 1246
< 1 .o 1. 0 ug/1 PAP 08/12/02 1246
< .o .o ug/1 PAP 08/12/02 1246
< 1. 0 1. 0 ug/1 PAP 08/12/02 1246
< 1. 0 .o ug/1 PAP 08/12/02 1246
< .o .o ug/1 PAP 08/12/02 1246
< 1 .o .o ug/1 PAP 08/12/02 1246
< 1. 0 . 0 ug/1 PAP 08/12/02 1246
< . 0 . 0 ug/1 PAP 08/12/02 124 6
< 1. 0 1 .o ug/1 PAP 08/12/02 1246
< 1 .o 1 .o ug/1 PAP 08/12/02 1246
< 1. 0 . 0 ug/1 PAP 08/12/02 1246
< 1. 0 1. 0 ug/1 PAP 08/12/02 1246
< 1. 0 . 0 ug/1 PAP 08/12/02 1246
< 5 .o 5. 0 ug/1 PAP 08/13/02 0741
< 1. 0 1. 0 ug/1 PAP 08/12/02 1246
< 1. 0 1. 0 ug/1 PAP 08/12/02 1246
< 2. 0 2. 0 ug/1 PAP 08/12/02 1246
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I Bl 6 E. Durst Avenue I Gn!enwood, SC 2964'.) I (Bb4) 229-44 n I F.ix [phone]
49
DAYIS
FLOYD LABORATORY ANALYSIS REPORT
Matrix Spikes and Duplicates
MS/MSD
.. Par_~:mei:~i:· ..
TRICHLOROETHENE
1,1-DICHLOROETHENE
1,2-DICHLOROETHA.NE
2-BUTANONE
BENZENE
CARBON TETRACHLORIDE
c·Hl,OROBENZENE
CHLOROFORM
TETRACHLOROETHENE
ViNYL CHLORIDE
. :· ~ar~~-~-J~i
TRICHLOROETHENE
1,1-DICHLOROETHENE
1,2-DICHLOROETHANE
2-BUTANONE
BENZENE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROFORM
TETRACHLOROETHENE
VINYL CHLORIDE
MS020B0702-04:31077
MSD02080702-04:31077
200.0
so. 00
so .00
so. 00
so. 00
so. 00
50 .00
50 .00
50. 00
50 .00
200.0
so. 00
50. 00
50. 00
50. 00
so. 00
50.00
50 .00
50. 00
50 .00
Report Date October 02, 2002
Page 1 of 1 Report ID: AA31513
Matrix GW/ChemW
WorkGroup: WG31077
Method SW846 8260B
. '·N:s···' '"LJ~it•
-}.'\:{~'kt{ i/::\/}(~;E·c
Not Evaluated see Note Below.
< 0 .00100 so. 96 102 76-128
< 0 .00100 52 . 31 105 78-135
< 0 .00500 55 . 4 3 111 76-168
< 0 .00100 47 .62 95 84-121
< 0 .00100 so. 15 100 74-120
0 .00100 48 .11 96 87-118
< 0 .00100 51 . 29 103 80-124
< 0 .00100 47 .21 94 83-107
< 0 .00100 48 .85 98 64-124
Not Evaluated -See Note Below.
53 . 76 108 5 11 76-128
55. 42 111 6 16 78-135
57 . 51 115 4 40 76-168
48 .91 98 3 10 84-121
52 . 15 104 4 20 74-120
47. 94 96 0 10 87-118
53 .48 107 4 12 80-124
46. 23 92 2 11 83-107
52. 37 105 7 13 64-124
NOTE: MS/MSD % recoveries are not evaluated if the sample concentration is greater than four times the spike added.
Sample Comments: MS02080702-04:31077
The MS/MSD for Trichloroethene was not evaluated due to the sample dilution required.
Stlll!Ple COJl'llllents: MSD02080702-04:31077
The MS/MSD for Trichloroethene was not evaluated due to the sample dilution required.
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Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I (86-41 229-4413
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DAYIS
FLtrYD LABORATORY ANALYSIS REPORT
Laboratory Control Standards and Duplicates
LCS LCS31077: l
1,1-DICHLOROETHENE 20. 00
1,2-DICHLOROETHANE 20. 00
2-BUTANONE 20 00
BENZENE 20. 00
CARBON TETRACHLORIDE 20. 00
CHLOROBENZENE 20. 00
CHLOROFORM 20 . 00
TETRACHLOROETHENE 20. 00
TRICHLOROETHENE 20 . 00
VINYL CHLORIDE 20 . 00
TRICHLOROETHENE 20. 00
21 . 83 109
23 .85 119
22 .58 113
21. 31 107
22. 60 113
21. 15 106
22 . 26 111
19. 60 98
19 86 99
22 . 77 114
18 . 67 93
Report Date
Page 1 of
August 21, 2002
Report ID: AA29255
Matrix GW/ChemW
workGroup: WG31077
Method SW846 82608
78-126
83-135
80-149
88-119
75 126
90-116
85-128
81-110
80-115
68-141
80-115
I Davis & Floyd, Inc. I PO Drawer 428 I Gret~nwood, SC 2%48 I 81 h E. Durst Avenue I Greenwood, SC 2%49 I [phone] I F.ix [phone]
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Di\YIS
FLtlYD LABORATORY ANALYSIS REPORT
QC Batch Report
Report Date August 21, 2002
Page 1 of 1 Report ID: AA29259
Matrix GW/Chemw
WorkGroup WG31106 Prep Method
Description, V0/8260/TCL TIC-SHE Special RDL Analtyical Method: SW846 82608
PRBP ANALYTICAL
Sample ID Client ID •=# Date Time Date Time Analyst Dilution
L02080702-01 ITEF 08/13/02 1136 PAP
L02080702-02 ITEF DUP. 08/13/02 1158 PAP
L02080702-03 ITCI 08/13/02 1221 PAP
L02080818-01 FF-34 08/13/02 1244 PAP
L02080818-02 EE-58 08/13/02 1308 PAP
L02080818-03 CC-33 08/13/02 1333 PAP
L02080818-04 P-58 08/13/02 1355 PAP
L02080818-05 PEW-4 1 08/13/02 1418 PAP·
L02080818-06 K-28 1 08/13/02 1441 PAP
L02080818-06 K-28 2 08/13/02 1857 PAP 2
L02080818-07 V-23 08/13/02 1504 PAP 5
L02080818-08 V-23 DUP. 08/13/02 1527 PAP 5
L02080818-09 TRIP BLANK " 08/13/02 0B26 PAP
LCS31106:l Laboratory Control Spike OB/13/02 1807 PAP
MB31106:l Method Blank 08/13/02 0804 PAP
MS02080818-0l. 31106 Matrix Spike 08/13/02 1636 PAP
MSD02080B18-0l:31106 Matrix Spike Duplicate 'i 08/13/02 1659 PAP
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue ! Greenwood, SC 29649 I [phone] I Fax (M>4l 229-7119
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DAYIS
FLOYD LABORATORY ANALYSIS REPORT
Surrogates % Recovery
s~.m~i-~Nurn~{~r_":":·/:··. Mei:il~rJD_ite ..
L02080702-01 13-AUG-02
L02080702-02 13-AUG-02
L02080702-03 13-AUG-02
L02080818-01 13-AUG-02
L02080818-02 13-AUG-02
L02080818-03 13-AUG-02
L02080818-04 13-AUG-02
L02080818-05 13-AUG-02
L02080818-06 13-AUG-02
L02080818-06 13-AUG-02
L02080818-07 13-AUG-02
L02080B18-08 13-AUG-02
L02080818-09 13-AUG-02
LCS31106:l 13-AUG-02
MB31106:1 13-AUG-02
MS02080818-01:31106 13-AUG-02
MSD02080818-0l:31106 13-AUG-02
OCE 1,2-0ICHLOROETHANE-D4
BFB BROMOFLUOROBENZENE
TOL TOLUENE-DB
11:36
11 :58
12:21
12:44
13 : 08
13: 33
13 :55
14 :18
18 :57
14 : 41
15: 04
15:27
08 : 26
18 :07
08 :04
16 36
16: 59
DCE :BFB<
8'f\3a 8 8 -112
12) 108
124 106
116 106
121 104
12) 107
121 108
129 106
127 109
109 105
125 111
12) 109
119 108
109 105
112 107
107 107
132 106
130 108
Report Date
Page 1 of
Matrix
Method
'TOL :_,:·.·:•:.::::'.-:.'.::
:s7.·~_109
104
103
106
103
104
105
101
104
105
105
104
104
106
105
105
102
99
August 21, 2002
Reper: ID: AA29269
GW/Chemw
SW846 8260
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I fllf, E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
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DAYIS
FLtwD
Method Blanks
Blank
Parameter
Volatile Organics
SW846 8260B
1,1,1-TRICHLOROETHANE
1,1,2,2-TETRACHLOROETHANE
1,1,2-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-0ICHLOROETHENE
1,2-DICHLOROETHANE
1,2-DICHLOROPROPANE
2-BUTANONE
2-HEXANONE
4-METHYL-2-PENTANONE
ACETONE
BENZENE
BROMODICHLOROMETHANE
BROMOFORM
BROMOMETHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-DICHLOROETHENE
CIS-1,3-DICHLOROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-DICHLOROETHENE
TRANS-1,3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL)
MB31106: l
LABORATORY ANALYSIS REPORT
Cone
' l. 0
' l .0
' 1 .0
1. 0
' 1. 0
' 1. 0
' 1. 0
' 5. 0
' 5. 0
' 5. 0
' 5 .o
' 1. 0
' 1 .0
' .0
' .o
' 1. 0
' .o
' 1.0
' 1.0
' 1.0
' .0
' 1. 0
' 1. 0
' 1. 0
' 1. 0
' l. 0
' 1.0
' .o
' 1 .o
' .o
' 1. 0
' 1.0
' 1. 0
' 1. 0
' 2. 0
Report Date
Page 1 of
August 21, 2002
Report ID: AA29256
Matrix GW/Chemw
WorkGroup: WG31106
Qual RDL Units Analyst Date
l .o ug/1 PAP 08/13/02
l .o ug/1 PAP 08/13/02
1 .o ug/1 PAP 08/13/02
.0 ug/1 PAP 08/13/02
1. 0 ug/1 PAP 08/13/02
.o ug/1 PAP 08/13/02
. 0 ug/1 PAP 08/13/02
5 .o ug/1 PAP 08/13/02·
5 .o ug/1 PAP 08/13/02
5. 0 ug/1 PAP 08/13/02
5 .o ug/1 PAP 08/13/02
1. 0 ug/1 PAP 08/13/02
1. 0 ug/1 PAP 08/13/02
1 .0 ug/1 PAP 08/13/02
1 .o ug/1 PAP 08/13/02
.o ug/1 PAP 08/13/02
1 .o ug/1 PAP 08/13/02
.0 ug/1 PAP 08/13/02
l .0 ug/1 PAP 08/13/02
1 .o ug/1 PAP 08/13/02
1. 0 ug/1 PAP 08/13/02
1 .o ug/1 PAP 08/13/02
1 .o ug/1 PAP 08/13/02
1 . 0 ug/1 PAP 08/13/02
.0 ug/1 PAP 08/13/02
. 0 ug/1 PAP 08/13/02
.0 ug/1 PAP 08/13/02
1.0 ug/1 PAP 08/13/02
. 0 ug/1 PAP 08/13/02
.0 ug/1 PAP 08/13/02
l .o ug/1 PAP 08/13/02
1 .0 ug/1 PAP 08/13/02
1. 0 ug/1 PAP 08/13/02
1 .o ug/1 PAP 08/13/02
2 . 0 ug/1 PAP 08/13/02
Time
0804
0804
0804
0804
0804
0804
0804
0804
0804
0804
0804
0804
0804
0804
0804
0804
0804
0804
0804
0804
0804
0804
0804
0804
0804
0804
0804
0804
0804
0804
0804
0804
0804
0804
0804
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 ! 816 L Durst Avenue I Greenwood, SC 2%49 I (g64J 22<J-441 J I fax [phone]
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Df\VIS
FLilYD LABORATORY ANALYSIS REPORT
Matrix Spikes and Duplicates
MS/MSD
1,1-DICHLOROETHENE
1,2-DICHLOROETHANE
2-BUTANONE
BENZENE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROFORM
TETRACHLOROETHENE
TRICHLOROETHENE
VINYL CHLORIDE
1,1-DICHLOROETHENE
1,2-DICHLOROETHANE
2-BUTANONE
BENZENE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROFORM
TETRACHLOROETHENE
TRICHLOROETHENE
VINYL CHLORIDE
NOTE1 MS/MSD \ recoveries
MS02080818-01131106
MSD02080818-01:31106
50. 00
50. 00
50. 00
50. 00
50. 00
50. 00
50 .00
50. 00
50 . 00
50 .00
SO.DO
50. 00
50. 00
50. 00
50. 00
50 .00
50. 00
50. 00
50.00
50.00
are not evaluated if the
< 0 .00100
< o. 00100
< 0 .00500
< 0 .00100
< o. 00100
< 0 .00100
< 0 .00100
< 0. 00100
< 0 .00100
< 0 .00100
51 .43
58 . 50
58 .88
48 . 98
51 . 81
49. 11
55. 57
45. 72
47 . 51
52 . 00
Report Date
Page 1 of
Matrix
August 21, 2002
Report ID: AA29258
GW/Chemw
WorkGroup: WG31106
Method SW846 8260B
52 . 38 105 76-128
58 .62 117 78-135
60 .39 121 76-168
49. 14 98 84-121
54 . 66 109 74-120
48.79 98 87-118
55.07 llO 80-124
46.09 92 83-107
48 .44 97 78-119
50 . 95 102 64-124
103 2 ll 76-128
117 0 16 78-135
11 B 3 40 76-168
98 0 10 84-121
104 5 20 74-120
98 10 8 7-118
111 12 80-124
91 1 11 83-107
95 2 10 78-119
104 2 13 64-124
sample concentration is greater than four times the spike added.
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29048 I 81 0 E. Durst Avenue I Crecnwood, SC 29649 I [phone] I fax [phone]
55
DAYIS
FLtrYD LABORATORY ANALYSIS REPORT
Laboratory Control Standards and Duplicates
Report Date August 21, 2002
Page 1 of 1 Report ID: AA29257
Matrix GW/ChemW
LCS : LCS31106:l WorkGroup: WG31106
Method SW846 82608
1,1-DICHLOROETHENE 20 . 00 20. 73 104 78-126
1,2-0ICHLOROETlw.E 20 . 00 20 .96 105 83-135
2-BUTANONE 20 00 16 64 83 80-149
BENZENE 20. 00 20. 11 101 88-119
CARBON TETRACHLORIDE 20. 00 21. 54 108 75-126
CHLOROBENZENE 20 .00 20 21 101 90-116
CHLOROFORM 20. 00 20 .68 103 85-128
TETRACHLOROETHENE 20. 00 19. 88 99 81-110
TRICHLOROETHENE 20 00 19. 17 96 80-115
VINYL CHLORIDE 20 00 20 72 l 04 68-141
D,ivis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I {864) 229-441 J I Fc1x (864) 229-71 l 9
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DL\VIS
FLMD LABORATORY ANALYSIS REPORT
QC Batch Report
workGroup WG31078
Description, sv/8270/bna/tcl sv/dow
Sample ID
L02080702 09
L02080702 10
L02080702-12
L02080702-12
L02080818-05
LCS31078:1
MB31078:l
MS02080702 09:31078
MSD02080702-09:31078
Client ID
PEW-1
PEW-3
F-55
F-55
PEW-4
Laboratory Control Spike
Method Blank
Matrix Spike
Matrix Spike Duplicate
Run#
1
1
Report Date August 21, 2002
Page 1 of 1 Report 1D: AA29266
Matrix GW/ChemW
Prep Method SW846 3500B
Analtyical Method: SW846 8270C
PREP
Date Time
08/08/02 0800
08/08/02 0800
08/08/02 0800
08/08/02 0800
08/08/02 1500
08/08/02 0800
08/08/02 0800
OB/08/02 0800
08/08/02 0800
ANALYTICAL
Date Time
08/15/02 1430
08/15/02 1 714
08/15/02 1755
08/16/02 0958
08/15/02 1837
08/15/02 1309
08/15/02 1228
08/15/02 1511
08/15/02 1634
Analyst Dilution
JRN
JRN
JRN
JRN 500
JRN
JRN
JRN
JRN 1
JRN
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 ! 816 E. Durst Avenue I Greenwood, SC 29649 ! [phone] I fax [phone]
57
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Dl\VIS
FLOYD LABORATORY ANALYSIS REPORT 0
I Surrogates % Recovery
I
Report Date August 21, 2002
Page 1 of 1 Report ID: AA29272 I Matrix GW/Chemw
Method SW846 8270
I
L02080702-09 15-AUG-02 14: 30 88 81 69 84 5' 92
L02080702-10 15-AUG-02 17:14 72 60 52 60 43 83 I
L02080702-12 15-AUG-02 17 :55 92 91 75 107 67 78
L02080818-0S 15-AUG-02 18 : 37 75 61 47 58 39 85
LCS31078:l 15-AUG-02 13 : 09 86 74 67 82 56 90 I
MB31078:1 15-AUG-02 12 :28 78 72 45 76 30 86
MS02 080702 -09: 31078 15-AUG-02 15: 11 81 59 46 58 38 90
MSD02080702·09:31078 15-AUG-02 16:34 83 58 48 58 40 BB I
TBP 2,4,6-TRIBROMOPHENOL
FBP 2-FLUOROBIPHENYL
2FP 2-FLUOROPHENOL I NBZ NITROBENZENE-D5
PHL PHENOL-OS
TPH TERPHENYL-D14 I
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D1\VIS
FLOYD
Method Blanks
Blank
Parruneter
Semivolatilo Organics
SW846 8270C
1,2,4-TRICHLOROBENZENE
1,2-DICHLOROBENZENE
1,3-DICHLOROBENZENE
1,4-DICHLOROBENZENE
2,4,5-TRICHLOROPHENOL
2,4,6-TRICHLOROPHENOL
2,4-DICHLOROPHENOL
2,4-DIMETHYLPHENOL
2,4-DINITROPHENOL
2,4-DINITROTOLUENE
2,6-DINITROTOLUENE
2-CHLORONAPHTHALENE
2-CHLOROPHENOL
MBJ1078:1
2 -METHYL-4, 6-DINITROPHENOL
2-METHYLNAPHTHALENE
2-METHYLPHENOL
2-NITROANILINE
2-NITROPHENOL
3,3'-DICHLOROBENZIDINE
3-NITROANILINE
4-BROMOPHENYL PHENYL ETHER
4-CHLOR0-3-METHYLPHENOL
4-CHLOROANILINE
4-CHLOROPHENYL PHENYL ETHER
4~METHYLPHENOL
4-NITROANILINE
4-NITROPHENOL
ACENAPHTHENE
ACENAPHTHYLENE
ANTHRACENE
BENZO(A)ANTHRACENE
BENZO(A)PYRENE
BENZO(B)FLUORANTHENE
BENZO(G,H,l)PERYLENE
BENZO(K)FLUORANTHENE
BENZOIC ACID
BENZYL ALCOHOL
BIS{2-CHLOROETHOXY)METHANE
BIS(2-CHLOROETHYL)ETHER
BIS(2-CHLOROISOPROPYL)ETHER
LABORATORY ANALYSIS REPORT
Cone
' 10 . 0
' 10 0
' 10. 0
' 10 .0
' 10. 0
' 10 .o
' 10. 0
' 10. 0
' 25. 0
10. 0
10. 0
' 10. 0
' 10 . 0
' 25. 0
' 10. 0
' 10. 0
' 10 .o
' 10 .0
' 10. 0
' 10. 0
' 10. 0
' 10 . o
' 10 .o
' 10. 0
' 10 .o
' 10 . o
' 25 .0
' 10. 0
' 10. 0
' 10 .o
' 10 .o
' 10. 0
' 10. 0
' 10 .0
' 10. 0
' so. 0
' 10 .0
' 10 .o
' 10. 0
' 10. 0
Report Date
Page 1 of 2
August 21, 2002
Report ID: AA29260
Matrix GW/Chemw
WorkGroup: WG3107B
Qual RDL Units Analyst Date
10 . 0 ug/1 JRN 08/15/02
10 .o ug/1 JRN 08/15/02
10. 0 ug/1 JRN 08/15/02
10. 0 ug/1 JRN 08/15/02
10. 0 ug/1 JRN 08/15/02
10. 0 ug/1 JRN 08/15/02
10. 0 ug/1 JRN OB/15/02
10. 0 ug/1 JRN 08/15/0~
25. 0 ug/1 JRN OB/15/02
10. 0 ug/1 JRN 08/15/02
10. 0 ug/1 JRN 08/15/02
10. 0 ug/1 JRN 08/15/02
10 . 0 ug/1 JRN 08/15/02
25. 0 ug/1 JRN 08/15/02
10. 0 ug/1 JRN 08/15/02
10 .o ug/1 JRN 08/15/02
10 .0 ug/1 JRN 08/15/02
10 .o ug/1 JRN 08/15/02
10. 0 ug/1 JRN 08/15/02
10. 0 ug/1 JRN 08/15/02
10. 0 ug/1 JRN 08/15/02
10 . 0 ug/1 JRN 08/15/02
10 .0 ug/1 JRN 08/15/02
10. 0 ug/1 JRN 08/15/02
10 .o ug/1 JRN 08/15/02
10 . 0 ug/1 JRN 08/15/02
25. 0 ug/1 JRN 08/15/02
10 .0 ug/1 JRN 08/15/02
10. 0 ug/1 JRN 08/15/02
1 0. 0 ug/1 JRN 08/15/02
10 .o ug/1 JRN OB/15/02
10. 0 ug/1 JRN 08/15/02
10. 0 ug/1 JRN 08/15/02
10 . 0 ug/1 JRN 08/15/02
10. 0 ug/1 JRN 08/15/02
50. 0 ug/1 JRN 08/15/02
10 . 0 ug/1 JRN 08/15/02
10. 0 ug/1 JRN 08/15/02
10 .0 ug/1 JRN 08/15/02
10 .0 ug/1 JRN 08/15/02
Time
1228
1228
1228
1228
1228
122 8
1228
1228
1228
1228
1228
1228
1228
1228
1228
1228
1228
1228
1228
1228
1228
122 8
1228
1228
1228
122 8
1228
1228
1228
1228
1228
1228
1228
1228
1228
1228
1228
1228
1228
1228
O,wb & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 2%48 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fc1x (H64) 229-7119
59
DAYIS
FLOYD
Method Blanks
Blank MB31078: 1 ,
Parameter
BIS(2-ETHYLHEXYL)PHTHALATE
BUTYL BENZYL .PHTHALATE
CHRYSENE
01-N-BUTYL PHTHALATE
DI-N-OCTYL PHTHALATE
DIBENZ(A,H)ANTHRACENE
DIBENZOFURAN
DIETHYL PHTHALATE
DIMETHYL PHTHALATE
FLUORANTHENE
FLUORENE
HEXACHLOROBENZENE
HElCACHLOROBUTADIENE
HEXACHLOROCYCLOPENTADIENE
HEXACHLOROETHANE
INDENO(l,2,3-CD)PYRENE
ISOPHORONE
N-NITROSODI-N-PROPYLAMINE
N-NITROSODIPHENYLAMINE
NAPHTHALENE
NITROBENZENE
PENTACHLOROPHENOL
PHENANTHRENE
PHENOL
PYRENE
SW846 8270C DOWTHERM
1,1'-BIPHENYL
BIPHENYL ETHER
Prep Procedure Method
Analytical Prep Procedures:
8NA SEMIVOLATILES SW846
DOWTHERM SW846
I
LABORATORY ANALYSIS REPORT I
I
I
Report Date August 21, 2002
Page 2 of 2 Report ID: AA29260
Matrix GW/Chemw I
WorkGroup: WG31078
Cone Qual RDL Units Analyst Date Time I
' 10 .0 10 .o ug/1 JRN 08/15/02 1228
' 10. 0 10. 0 ug/1 JRN 08/15/02 1228
' 10. 0 10 .o ug/1 JRN 08/15/02 1228 I
' 10. 0 10 .0 ug/1 JRN 08/15/02 1228
' 10. 0 10. 0 ug/1 JRN 08/15/02 1228
10. 0 10. 0 ug/1 JRN 08/15/02 1228
' 10. 0 10. 0 ug/1 JRN 08/15/02 1228 I
' 10. 0 10 .o ug/1 JRN 08/15/02 1228
10 .0 10 .o ug/1 JRN 08/15/02 1228
' 10 .0 \0 .o ug/1 JRN 08/15/02 1228 I
' 10. 0 10 0 ug/1 JRN 08/15/02 1228
' l O. 0 10 .o ug/1 JRN 08/15/02 1228
' 10. 0 10 .o ug/1 JRN 08/15/02 1228
' 10. 0 10. 0 ug/1 JRN 08/15/02 1228 I
' 10. 0 l O. 0 ug/1 JRN 08/15/02 1228
' 10. 0 10. 0 ug/1 JRN 08/15/02 1228
' 10. 0 10. 0 ug/1 JRN 08/15/02 1228
' 10. 0 10.0 ug/1 JRN 08/15/02 1228 I
' 10. 0 10. 0 ug/1 JRN 08/15/02 1228
' 10. 0 10. 0 ug/1 JRN 08/15/02 1228
' 10. 0 10. 0 ug/1 JRN 08/15/02 1228 I
' 25. 0 25. 0 ug/1 JRN 08/15/02 1228
' 10. 0 10.0 ug/1 JRN 08/15/02 1228
' 10. 0 10 .o ug/1 JRN 08/15/02 1228·
' 10.0 10 .0 ug/1 JRN 08/15/02 1228 I
' 10. 0 10 .o ug/1 JRN 08/15/02 1228
' 10. 0 10. 0 ug/1 JRN 08/15/02 1228 I
Analyst Prep Date I
35008 DBC 08/08/02 0800
35008 DBC 08/08/02 0800 I
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Di\YIS
FLt1YD LABORATORY ANALYSIS REPORT
Matrix Spikes and Duplicates
MS/MSD
·.· -P~rame_~e-r ..
1,2,4-TRICHLOROBENZENE
1,4-DICHLOROBENZENE
2,4-DINITROTOLUENE
2-CHLOROPHENOL
4-CHLOR0-3-METHYLPHENOL
4-NITROPHENOL
ACENAPHTHENE
N-NITROSODI-N-PROPYLAMINE
PENTACHLOROPHENOL
PHENOL
PYRENE
1, l' -BI PHENYL
BIPHENYL ETHER
1,2,4-TRICHLOROBENZENE
1,4-DICHLOROBENZENE
2,4-DINITROTOLUENE
2 -CHLOROPHENOL
4-CHLOR0-3-METHYLPHENOL
4-NITROPHENOL
ACENAPHTHENE
N-NITROSODI-N-PROPYLAMINE
PENTACHLOROPHENOL
PHENOL
PYRENE
1,1'-BlPHENYL
BIPHENYL ETHER
MS020B0702-09:31078
MSD02080702-09:31078
· --s~fX~_:,-;·-
Added
50 . 00
50. 00
50 .00
75. 00
75 . 00
75 . 00
50 . 00
50. 00
75 . 00
75 .oo
50 .oo
50. 00
50 . 00
50 .00
50. 00
50 . oo
75. 00
75 . 00
75. 00
50 .oo
50 .00
75. 00
75. 00
50 . 00
50. 00
50 . oo
NOTE: MS/MSO % recoveries are not evaluated if Che
S_am•pie•
::-:-:-:-:,-::-.
ci:i_n_c
' 0 .0100
' 0 .0100
' 0. 0100
' 0 .0100
' 0 .0100
' 0 .0250
' 0 .0100
' 0. 0100
' 0 .0250
' 0 .0100
' 0 .0100
' 0. 0100
' 0 .0100
25 .64
23 . 47
3 9 . 17
39. 36
53. 74
38. 63
30. 32
27. 94
41. 45
28 .02
41 . 69
27. 24
27 . 84
Report Date
Page 1 of 1
August 21, 2002
Report ID: AA29262
Matrix GW/ChemW
WorkGroup, WG31078
Method SWS46 8270C
MS · Mf ·Li'rriits
Cone .. ·.:.:: \:~-fd.-·· · : ·::?_,-i1::'t:,' _.. ·
25 . 49
23 .49
38 . 79
39. 12
52 . 32
37. 13
30 .25
26 .48
39. 75
26 31
42.61
2 7. 3 3
27 34
51
47
78
52
72
52
61
56
55
37
83
54
56
51
47
78
52
70
50
61
53
53
35
85
55
55
0
1
1
3
4
0
5
4
6
2
0
2
26-101
2 7-94
46-117
35-89
44-101
1-97
39-108
39-107
20-128
3-76
55-116
31-110
30-113
20
28
19
21
20
20
22
24
32
23
22
27
22
26-101
27-94
46-117
35-89
44-101
1-97
39-108
39-107
20-128
3-76
55-116
31-110
30-113
sample concentration is greater than four times Che spike added.
l),1vis & Floyd, Inc. I PO Drawer 42fl I Greenwood, SC 29648 l 816 E. Durst Avenue I Greenwood, SC 2%49 I (864) 229-441] I Fax [phone] ~
6l•
DAYIS
FLOYD LABORATORY ANALYSIS REPORT
Laboratory Control Standards and Duplicates
Report Date August 21, 2002
Page 1 of 1 Report ID: AA29261
Matrix GW/Chemw
LCS LCS31078:l WorkGroup: WG31078
Method SW846 8270C
1,2,4-TRICHLOROBENZENE 50. 00 31. 75 64 36-93
1,4-0ICHLOROBENZENE so. 00 29. 74 59 34-88
2,4-DINITROTOLUENE so .00 42.61 85 58-111
2 -CHLOROPHENOL 75 .00 55.89 75 39-92
4-CHLOR0-3-METHYLPHENOL 75 00 62.29 83 50-96
4-NITROPHENOL 75 00 42 . 92 57 1-79
ACENAPHTHENE 50. 00 39 54 79 51-100
N-NITROSODI-N-PROPYLAMINE so .00 38 .76 78 47-110
PENTAC~LOROPHENOL 75. 00 45. 30 60 13-112
PHENOL 75. 00 38 .61 51 6-69
PYRENE so.co 42 .70 85 60-114
1,1'-BIPHENYL so .00 35. 85 72 41-109
BI PHENYL ETHER 50.00 3 6. 61 73 42-106
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
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DAYIS
FLtJYD LABORATORY ANALYSIS REPORT
QC Batch Report
WorkGroup WG31064
Descriptlon, GC/EG
Sample ID
L02080702-0l
L02080702-02
L02080702-03
LCS31064: 1
MB31064:l
MS02080702-0l:31064
MSD02080702-01:31064
Client ID
ITEF
ITEF DUP.
ITCI
Laboratory Control Spike
Method Blank
Matrix Spike
Matrix Spike Duplicate
Report Date
Page 1 of 1
Matrix
Prep Method
Analtyical
PREP
Run# Date Time
August 21, 2002
Report ID: AA29267
GW/ChemW
Method: SW846 8015
ANALYTICAL
Date Time Analyst Dilution
08/07/02 1517 MGB
08/07/02 1543 MGB 1
08/07/02 1610 MGB 5
08/07/02 1424 MGB
08/07/02 13 57 MGB
08/07/02 1702 MGB 1
08/07/02 1729 MGB
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
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Di\YIS
FLtwD
Method Blanks
Blank
Parameter
Gas Chromatography
SW846 8015
ETHYLENE GLYCOL
MB31064: l
LABORATORY ANALYSIS REPORT
Report Date August 21, 2002
Page 1 of 1 Report ID: AA29264
Matrix GW/ChemW
WorkGroup: WG31064
Cone Qual RDL Units Analyst Date Time
s.o 5.0 MGB 08/07/02 1357
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
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DAYIS
FLMD LABORATORY ANALYSIS REPORT
Matrix Spikes and Duplicates
MS/MSD
.· P3i:~m~:ter,.:-.
ETHYLENE GLYCOL
Pa,ralllEi_t:~-1:":'.
ETHYLENE GLYCOL
MS020B0702-01:31064
MSD02080702-01:31064
.. :·SP~i~:-:
· .-':Ad9,ed/
50.00
50.00
Report Date
Page 1 of 1
Matrix
August 21, 2002
Report ID: AA29265
GW/ChemW
workGroup: WG31054
Method SW846 8015
\,a~Ph/:· ,·-:Ms···:·::
::,d;'~~·:::.: · -.. :,-::::cone:·:·
< 5.00 51.57
. ·. MS . .--:C-i'~i t/·:.
:::\\ig-Eci·/' ·-:·-'itt'~::::,::. -
103 68-129
52.57 105 2 16 68-129
NOTE: MS/MSD \ recoveries are not evaluated if the sample concentration is greater than four times the spike added.
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax (864) 229•71 l 9
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Di\YIS
FLOYD LABORATORY ANALYSIS REPORT
Laboratory Control Standards and Duplicates
LCS LCS31064:l
ETHYLENE GLYCOL
Report Date
Page 1 of 1
August 21. 2002
Report ID: AA29263
Matrix : GW/ChemW
WorkGroup: WG31064
Method SW846 8015
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D1\YIS
FLOYD LABORATORY ANALYSIS REPORT
QC Batch Report
WorkGroup WG31066
Description: TOC GW
Sample ID
L02080702-01
L02080702-02
L02080702-03
LCSJ1066:
LCS31066:2
MB31066:
MB31066: 2
MS02080702-0l:31066
MS02080712-0S:31066
MSD02080702-01:31066
MSD02080712-05:31066
Client ID
ITEF
ITEF DUP.
ITCI
Laboratory Control Spike
Laboratory Control Spike
Method Blank
Method Blank
Matrix Spike
Matrix Spike
Matrix Spike Duplicate
Matrix Spike Duplicate
Run#
1
Report Date August 21, 2002
Page 1 of 1 Report ID: AA29247
Matrix GW/ChemW
Prep Method
Analtyical Method: SW846 9060
PREP
Date Time
ANALYTICAL
Date Time
08/07/02 0904
08/07/02 0911
08/07/02 0924
08/07/02 0948
08/07/02 1144
08/07/02 0951
08/07/02 0948
08/07/02 0935
08/07/02 1128
08/07/02 0940
08/07/02 1135
Analyst Dilution
CLB
CLB
CLB
CLB
CLB
CLB
CLB
CLB
CLB
CLB
CLB
5
5
100
1
1
Davis & Floyd, lnc. I PO Drawer 428 I Greenwood, SC 296411 I 816 E. Durst Avenue I Greenwood, SC 29649 I (864) 229-441 J I Fax (864) 2.2\J-7119
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DAYIS
FLOYD
Method Blanks
Parameter
Wet Chemistry
SW846 9060
Blank
ORGANIC CARBON, TOTAL
MB31066: 1
LABORATORY ANALYSIS REPORT
Cone
< 1.0
Report Date
Page 1 of 1
August 21, 2002
Report ID: AA29242
Matrix GW/Chemw
WorkGroup: WG31066
Qual ROL Units Analyst Date Time
1.0 mg/1 CLB 08/07/02 0951
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DAYIS
FLOYD
Method Blanks
Parameter
Wet Chemistry
SW846 9060
Blank
ORGANIC CARBON, TOTAL
MB31066:2
LABORATORY ANALYSIS REPORT
'
Report Date
Page 1 of l
Matrix
August 21, 2002
Report ID: AA29244
GW/ChemW
WorkGroup: WG31066
Cone Qual RDL Units Analyst Date Time
1 . 0 1. 0 mg/1 CLB 08/07/02 0948
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 ) (864) 229--l41 j I Fax (864) n9-7 l l 9
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DAYIS
FLOYD LABORATORY ANALYSIS REPORT
Matrix Spikes and Duplicates
MS/MSD
ORGANIC CARBON, TOTAL
MS02080702-01:31066
MSD02080702-01:31066
20.00 40.56 100
Report Date
Page 1 of 1
August 21, 2002
Report ID: AA29245
Matrix GW/ChemW
WorkGroup: WG31066
Method SW846 9060
3 10 78-121
NOTE: MS/MSD \ recoveries are not evaluated if the sample concentration is greater than four times the spike added.
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Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 81 Ci E. Durst Avenue I Greenwood, SC 2964~) I (8f,4) 229-441.1 I Fax [phone]'/ I
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DAYIS
FLOYD LABORATORY ANALYSIS REPORT
Matrix Spikes and Duplicates
MS/MSD
ORGANIC CARBON, TOTAL
. :: .
_,::'-~~-~'~·m~:~e{·/
ORGANIC CARBON, TOTAL
MS020807l2-0S:31066
MSD02080712-0S:31066
Spike
Added
20.00
Spike
Added·
20.00
s~~Pie
_cgnc:.
7 77
:'MSD'. · -: c6:rit =-, ··
29. 82
Report Date
Page 1 of 1
August 21, 2002
Report ID: AA29246
Matrix GW/ChemW
WorkGroup: WG31066
Method SW846 9060
MS --•::·Ms·····
Co~c :--· ... ::_)i~kc·--:
30.17 112
MSD
%-REC
110
\R:EC.:
78-121
10 78-121
NOTE: MS/MSD \ recoveries are not evaluated if the sample concentration is greater than four times the spike added.
Davis & Floyd, lnc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Grf:!enwood, SC 29(>49 I (864) 229-441 J I fax (Hf,4) 229-7119
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Df\YIS
FLMD LABORATORY ANALYSIS REPORT
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Laboratory Control Standards and Duplicates
Report Date August 21, 2002
Page 1 of 1 Report IO: AA29241
Matrix GW/Chemw
LCS LCS3l066:1 WorkGroup: WG31066
Method SW846 9060
LCS . · Cone
ORGANIC CARBON, TOTAL 10.00 10.42 104 90-110
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 L Durst Avenue I Greenwood, SC 29649 I {8(,4) 229-4413
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DAYIS
FLfilD LABORATORY ANALYSIS REPORT
Laboratory Control Standards and Duplicates
LCS LCS31066:2
:.\:·~i;a~~I~i:f'.::.
ORGANIC CARBON, TOTAL
Report Date
Page 1 of 1
Matrix
August 21, 2002
Report ID: AA29243
GW/Chemw
WorkGroup: WG31066
Method SW846 9060
/'.SP1k.e ·. ··.. · LCS-· .--_..-... •:-:·::-:L·Cif)\/ .. -·:-:•ri·.ini·itS
··.Actdect·. · -Cqii,C > .'//\·.:.i·k~~=)(, f:'\\~:E~-;
10.00 9.50 95 90-110
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 2%4B I 816 E. Durst Avenue I Greenwood, SC 2.%49 I (864) 229-441 J I r-ax !864) 229-7 J 19
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DAYIS
FLOYD LABORATORY ANALYSIS REPORT
QC Batch Report
WorkGroup WG31104
Description: TOC GW
Sample ID
L02080702·15
L02080818-06
L02080818-07
L02080818-08
LCS31104: 1
MB31104: 1
MS02080810-03:31104
MSD02080810-03:31104
Client ID
EQUIPMENT BLANK
K-28
V-23
V-23 OUP.
Laboratory Control Spike
Method Blank
Matrix Spike
Matrix Spike Duplicate
Report Date
Page 1 of 1
Matrix
Prep Method
Analtyical
PREP
Run# Date Time
1
1
1
August 21, 2002
Report ID: AA29251
GW/ChemW
Method: SW846 9060
ANALYTICAL
Date Time Analyst Dilution
08/12/02 0953 CLB
08/12/02 1128 CLB 100
08/12/02 1149 CLB 200
08/12/02 1156 CLB 200
08/12/02 1218 CLB
08/12/02 1220 CLB
08/12/02 1204 CLB
08/12/02 1209 CLB
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29&49 I [phone] I Fax [phone]
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DAYIS
FLtwD
Method Blanks
Parametei
Wet Chemistry
SW846 9060
Blank
ORGANIC CARBON, TOTAL
MB31104: l
LABORATORY ANALYSIS REPORT
Cone
< 1.0
Report Date
Page 1 of 1
August 21, 2002
Report ID: AA29249
Matrix GW/ChemW
WorkGroup: WG31104
Qual RDL Units Analyst Date Time
1.0 mg/1 CLB 08/12/02 1220
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I (864) 229-441 J I Fax [phone] l 9
75
DAYIS
FLffi'D LABORATORY ANALYSIS REPORT
Matrix Spikes and Duplicates
MS/MSO
ORGANIC CARBON, TOTAL
ORGANIC CARBON, TOTAL
MS02080810-03:31104
MSD02080810-03:31104
20.00
20.00
12. 95
32. 98
Report Date August 21, 2002
Page 1 of 1 Report ID: AA29250
Matrix GW/Chemw
WorkGroup: WG31104
Method SW846 9060
34.15 106 78-121
100 3 10 78-121
NOTE: MS/MSD \ recoveries are not evuluated if the sample concentration is greater than four times the spike added.
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwond, SC 29649 I [phone] I Fax [phone]
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DAYIS
FLOYD LABORATORY ANALYSIS REPORT
Laboratory Control Standards and Duplicates
LCS LCS31104: 1
. :::.::··p~·~am;ter.:•-, .' ..
Spike. :·-Lcs-
Added . ·) :,' :::::~6:~-~ -.
ORGANIC CARBON, TOTAL 10.00 9.59
Report Date
Page 1 of 1
August 21, 2002
Report ID: AA29248
Matrix GW/Chemw
WorkGroup: WG31104
Method SW846 9060
;"LCS
:%REC.
96
·"t'l'~itr/· ·
'·\\REC
90-110
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax (864) 2:!~1-7119
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DAYIS
FLtJ'YD LABORATORY ANALYSIS REPORT
Explanation of Symbols and Abbreviations
The following defines common symbols and abbreviations used in reporting technical data:
RDL Report Detection Limit MDL Method Detection Limit
TOP Top of Pipe MSL Mean Sea Level
TNTC Too Numerous To Count MPN Most Probable Number
BTU British Thermal Units NTU Nephelometric Turbidity Units
C Degrees Centigrade F Degrees Fahrenheit
umhos/cm micromhos/cm meq milliequivalents
kg kilogram(s) g gram(s)
mg milligram(s) ug microgram(s)
I liter(s) ml milliliters(s)
ul microliter(s) m3 cubic meter(s)
lb pound{s) ft3 cubic foot(feet)
ft foot(feet) TIC Tentatively Identified Compounds
mg/I, mg/kg Units of concentration in milligrams per liter for liquids and milligrams per kilogram for solids. Also
referred to as Parts Per Million or "ppm" when the assumption is made that the specific gravity or
density is one (1 g/ml).
ug/1, ug/kg Units of concentration in micrograms per liter for liquids and micrograms per'kilograms for solids.
Also referred to as Parts Per Billion or "ppb" when the assumption is made that the specific gravity
or density is one (1 g/ml).
wt%
<
>
Units of concentration expressed on a weighUweight basis (e.g. grams per 100 grams).
Less Than -The number following the sign is the limit of quantitation, the smallest amount of
analyte that can be reliably determined using this test.
Greater Than
Data Qualifiers:
A
B
C
E
J
p
X
•
TIC is a possible aldol-condensation product resulting from sample extraction, (Organics)
Analyte also detected in the method blank.
Amendable Cyanide is a negative value due to an unknown interference.
Estimated concentration due to interference.
Estimated value below RDL or estimated value for TIC. (Organics)
Concentration difference between primary and confirmation columns >25%. (Organics) The lower result is
reported.
Matrix interference which requires dilution or prevents the reporting of a result. Detection limits have been
adjusted where applicable .
Defined in report comments.
Solid samples (i.e. soil, sludge, and solid waste) are reported on a dry weight basis unless otherwise noted.
Test results relate only to the sample tested. Clients should be aware that a critical step in a chemical or biological
analysis is the collection of the sample. Unless the sample analyzed is truly representative of the bulk of the material
involved, the test results will be meaningless. If you have any questions regarding the proper techniques of collecting
samples, please contact us. However, we cannot be held responsible for sample integrity unless sampling has been
performed by a member of our staff.
WARRANTY AND LIMITATION OF LIABILITY-The accuracy of all analytical results is warranted for the sample as
it is received by the laboratory. Warranty for the integrity of the sample begins at the time it is placed in the
possession of authorized Davis & Floyd, Inc. Laboratories personnel. All other warranties, expressed or implied, are
disclaimed. Liability is limited to the cost of the analysis.
Davis & Floyd, Inc.
AD07_0/ (07199)
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Davis & Floyd, Inc. I PO Dmve, 428 I G,eenwood, SC 29648 I H16 \ ~u,sr Avenue I G,eenwood, SC 2%49 I (8(,4) 229-4413 I Fax [phone] ·I
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Sampling Log-Grab Water Samples
Project No. 26OS05 Site Location CNA / Ticona -Shelby, NC
Sample Date -~o,-1-/~S:'-l,/4'-"D:..i.7 __ _ Arrival Time ·1 I OD Sample Time --\.-'-L------
Sample ID r-r (;:. F Duplicate No. :11:G f -\)_,\) Field Personnel --"G-..,_,_,k"-1/'-'' ;;:~(: __ _
Weather Conditions ~M]'i /'r,,} Sampling Method ___ {n __ ,_u.,,;b:cc_ ___________ _
I I
Sample Temp. (°C) Z 7 . $ 3 ° Cspec Conductivity(µS/cm) . 1.-I \ j 3, pH --J.81--....:'Z=.....::..Y __ _
OAP (mV)
Method(s) 1 fc4o1,tier
..---.oc:.
Turbidity (NTU)
Container Description
'Q<fO,'i (
Preservative ;/c..r
f/4,_JG,
Remarks 11. &G
Sample Date _ _....,:311./,$.,,,&J.,/,,._;-__ _ r I
'):7c (
Arrival Time
Sample ID Duplicate No. ______ _
Sample Time _,__,_I_'_" ___ _
Field Personnel _G...,ri""l<._1,_/S7...__f,___
Weather Conditions ')_,;,o,, I Let Sampling Method Q
II
Sample Temp. (°C) lb -77 Spec. Conductivity(µS/cm) \q-zo L/. c4 pH __ .c..::,..:...._1 __ _
OAP (mV) 2Lj 0 Turbidity (NTU) LS
Method(s) Container Description
/):£sf~• .?,1-zv.1{1
Preservative
//Cj
E6, I ,._.2cv,;
sTX-/);/2.<f,u
Remarks 1)0-: o S2 0/l
Kubal-Furr & Associates
Revised 7 /30/02
low.Flow Groundwater Sampling log
Kubal-Furr & Associates
-E11viro11m1•11/11{ Consultants--
Project No. -------'2:.:6:.:Qe.:S:.:0.=.5 ____ _
Site Location CNA/Tlcona · Shelby, NC
Field Personnel =====(j=\=·=f:_.::1:s:=~===========
Well I Sample ID -~lt~l~+_-_J~7~-----
oi J WeatherCondition -~s...,,.·=llw•.,,« _ _,l""-b±"'-'-~----
Samp!e Dale sy,50-L Arrival nme ) I ·.--\ S Sample Time_~==·~_,_/-'J""s"-:.,,_J" ___ _
Descrip1ionolM~osurin9~ CasingType~sc Locking Cap! . / Casingl,i
Point (MPf~ ~ . V Diamete~ ;c====------:
Purge Melhodl G\cu.,n d f,,;; I Som-pli~ng:.M_e~l-ho_d,1, -~5c=~=«-=----'r---~
Purge Start Tlmel j "2_ '. l () j Purge Slop Timel / ')...._~ / I Purge Rat#c, ml/min[
Water-Level Measurements Field Parameters
Dissolved
Interval Elapse Time DTW fleet)
(mins) Interval El Ti Temperature Specific apse ime (oCI Conductance pH (sv)
(mins) (µS/cm)
Turbidity (NTU) Oxygen
0 (J L/'-/.17 0 0
I .s 45.Z<:i I -"
2 iD t..$,J/ 2 Jo
3 15 c.. ', ?,Li 3 re'.
4 10 '-/ s. Z,.; 4 7r,
5 75 i-5 i< 5 2...<P.;
6 ,;o L--~-~ 6 3o
7 <, 1'.., i. c·zc/ 7 ~~
8 l/t) 6/<,: '( 8 a '('")
9 9
10 10
ti ti
12 12
13 13
14 14
15 15
16 16
17 17
18 18
19 19
20 20
Samples Collected
Parameter Conditions: pH +/-0.1 standard unit
Turbidity +/-10% above 10 NTU
.--9':?.
'(,\, c_ r:-'~
?o.~\ '< 3
(_ \ .01 )<{,
Z l. \ 7 '8 "6
Zl_'"?b QB
Z L <--1, GD
Lt ,V-I "' 1 -Z. \ _,;.o '11
Container Descnpt1on
COND/Temp +/-3%
+/-1 NTU below 10 NTU
·5
(mg/l)
----
: (_. I '7' ,, .0... , C. SS9
(, 17 I,._ .3 f-TI
I. . \ 7 I . 'i< L-\ Sl. Y>
l. \S 1· . i--j '--. <-J, i°l
I. IC s.~ L/.02..
1'.,.io S, 1. J.S~
/~.17 ~ z.,· 3 .c..1
c,, i er L . '1 1_.~5
Preservative
DO +/-10%
ORP +/-lOmV
ORP (mV)
-
lo:s
,11.::i
\ I \ • 'A
Ii'-\ . 7
I Z. I .6
\?-Z.'-'
\ 7 l -I
i2~.G
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Low-FlowGroundwater SompUng Log ,
CNA{Ticona •.
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Purged Well Sampling Log
Project No. 26QS05 Kubal-Furr & Associates
-E11Pironme11tal Co11s11lta11ts-Site Location CNA Holdin s/Ticona, Shelby, NC
Field Personnel (;:s\ ·::
We// / Sample ID
Weather Condition
Sample Date 8/s)ot. Arrival Time 1r '-ff,
Description of Measuring~ C • T p ~<::. Point (MP)~ as,ng Y el.2..2J
Total Depth of Well Below!
MP? SrJ, t .) , .. ,I
11. Jo , .. ,I
Common Gallons per Foot Conversions
Depth to Water Below MP?I
Column of Waler in Well?I /J, /. -1 I :==if=="°=='~•·'
Gallons of Waler per fool {J,/(,/3 (see chart)? aol/foot
Gallons of Waler in Well? /ot ~a,I
Gallons of Waler to be s. 21 J Purged (3XJ?
I '/ 4 in Well Casing = 0.064 gal / fool
I 1;, in Well Casing= 0.092 gal/ foot
2 in Well Casing = 0.163 gal / fool
3 in Well Casing= 0.367 gal/ foot
3 1 h in Well Casing = 0.500 gal / foo1
4 in Well Casing = 0.653 gal / fool
6 in Well Casing = 1.469 gal / fool
Purge Method? '/5,4,( l dl I Total Gallons Purged I fo/l 5 ~a,I
Purge Start Timef Li·-11.-I Purge Slop Time] \ ~ _') ":, I
Initial 2 3 4 5
Volume Purged O \ 11 gal , (.e
DO m</L &;•?, I m /L t. / /m /I
Turbitidy b.r;; NTU lei .. ~1~ i./4. 5Niu • 0.D NTU '}>2,.,S Nru --5NTU
ORP I (;> '?nv Li>7.>mv Zzo.i Z f-..5mv L\S.,
Samples Collected Container Description Preservative
Re~se 5/26/02
G_).s ,JccJ.
Kubal-Furr & Associates
-li11vim11mc11/11{ Consu//1111/s-
Low-Flow Groundwater Sampling Log
Project No. ____ __:2::.,6:.;Qo:S:.:0:::5c_ ___ _
Site Location __ C=:N.:..A,_/T:..:1.::c o;-n:..:a=-·-=S-'-h-=e~lb'-'y-'-. -'-N'-'C'--
Fietd Personnel _.....::GJ:.J. _,_K"'--1-/_0,,___.:_i=' ____ _
Well / Sample ID &d-sf
I\. Weather Condition Su. n fl-\.[
Soniple0atc r11-'---j f; 1 Q1_.. ArfivolTirne,-----~~~· ---;:\:::j±:: .. '::::':,:,'S'=,somplelime __ _,_\:=_S_c··\~5,e... ______ _
Description of Me_asuring1-1 Casing Type~s· Lading Copl / Cosing~z. Point (MPJ[l__QQJ:j L__2U • Diame!er~ ~===----...: I 6. I " Purge Method Jl'½,Q~ 10J
Pu,ge Start Time I \'j. ) O I
Water-Level Measurements
Sampling Method I .S"c;n1e
PurgeStoplimel \S ·. \'l: \ PurgeRatef:3.s"Omi/m"11
Field Parameters
Dissolved
lnlervol Elapse Time DTW fleet)
{mins) ln1ervol Elapse Time Temperolure Specific pH {suj (mins) {cC) Conductance Turbidity (NTUJ Oxygen
(µ$/cm) (mg/L)
0 0 37,~ 0 0 --
I I !..-fO .ZL I l \ 9, -'-,(), <,/...{, 5.0 1.J,. i; 0 £. 9
2 I i '--10.~I 2 10 co.OJ 3'15 L.f_ C, 2. ?i.q Cl SJ
3 ,s I .i.J11. )l 3 I< 1..D, 1"1 L/f / L..j Q' • ~ t"J )_ ljL(
4 ""/_ 0 ifo.Sl 4 Zo Z'. l. 5 i L-/ I 6 L/ 7'1 <, I 07..7 ..
5 Z( '-lai;t s z-.~ ll bl l/ I 6 l/. 7~ 7.Z 0. zc,
6 ~o l/Osz 6 3.o l.l .1:,'3 LJ )5 l-/, 76 I. 7 C>,./L,
7 <<" 4-0 --5~ 7 -~~ 'U,_lY2 '-/ i'f '-f 7(" 1.5 o.z'-
8 '-i /) l//l .l-.7. 8 l/o 17 ,iJ UJLJ lj 7~ I ,"I. 0~771
9 9
10 10
II II
12 12
13 13
14 "
15 15
16 16
17 17
18 18
19 19
20 20
Samples Collected
llot.J
Container Description Preservative
Remarks d . s-~Al L.,_s pv-'Joh
l'ornn,eler Co11dilioM: pH +/-0.1 stondardunil COND/Tcmp +/-3% DO +/-10%
Turbidity +/• 10% above 10 NTU +/. 1 NTU below 10 NTU ORP +/-\OmV
ORP (mV)
---
7o7-<
'l..\ 7.'l.
Zz3 ...
z 1 t/,, c;
'l,/l.9.o
Z'.3 I 7
'l3.s5
'l. <J'., ()
CNA/Ticono
Low-FlowGroundwoter Sampling log
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Kubal-Furr & Associates
-[11viro111111•11t11I Co11s11/ln11fs--
Low-Flow Groundwater Sampling Log
Project No. ------'2::.;6:..:Q::;S:..:0:.::5 ____ _
Site Locotion CNA/Tlcona . Shelby, NC ---"-''-',....=,.,,._ '-=--=~~-
Field Personnel ___ ,cCl<.=·-------
Well / Sample tD .--;: .s s:-
i:t/-1 tSs,J.. Weather Condition __ J..:....'-'..:.N_·..v_7/-------
Somple Dale {1Y Arrival Time ____ ====Somple Time /(e!'r'
Oesc,iplian al MeasuringJ-7 Casing Type I S /' I locking Cap~ 0·,aCmosein,egc~.
Po1n1 (MP)~ ~ ~ ~
Purge Methodj ~:?'i'u"?C
Purge Start Timej Jw.? j
Water-Level Measurements
Interval
0
I
2
3
4
5
6
7
8
9
10
II
12
13
"
15
16
17
18
19
20
Elapse Time
(minsJ
0
£
16
/S-
;k)
J.<
,t)
:zr-
i/v
tis"
DTW Peet)
/3,1]
/1/,b-f"
/'{,SJ
/,/&o
/if.II
l'i f J
/tr. fr
/,/JI/
I if,t-<:;
li&b
Samples Collec1ed
/1:ZJ
lnte1vol
0
I
2
3
4
5
6
7
8
9
10
II
12
13
"
15
16
17
18
19
20
Sampling Melhodl
Purge Slop Time! /{z.S-?-
Field Parameters
Elapse lin1e Temperalure Specific
(min<,) (oC) Conduclance [µS/cm)
0 ~ -·
..s /'/_[,& ~-7 "'-~ lo ,/(J,I 9 st.J
/0 ll,J-'( .s(.,o
;lo j{f,'ls' 5{,o
.:ls" Jo.o9 st:,/
:?o l?,.fo ,_'> SY'
~ /'/,{£ ss~
t/o fl9J st,o
1~ /'1,00 ..S-.s1
Conto1ner Description
Parameter Conditions· pH + /-0.1 ~landord unit COND/Temp +/-3%
+/-1 NTU below 10 NTU Turbidity +/-10% abo11e 10 NTU
Pucge Ratel,'-.,,"ec'/,!__.c,e=I _ _xi ml/min
pH [su) lurbidily (NlU)
--
.S-,1/~ /,/
~3i I, 0
-5~39 0.9
~ J;s-CJ.fr s:,1 "j!; /_/) I
S,J/ /,o
S:/f {),cf
£'.Jo /,D
,s,/R o,q
Preservative
00 i-/-10%
ORP +/-lOmV
Dissolved
Oxygen
{mg/LJ ---
IJ?
/.()6
ot.fi'
6,,~t./
Ci, 3f
0, 3/
6,Jf.-,
CJ,:],J-
O,Jt/
ORP jrnV)
--
/'f,.r,,f
/5J.j
ISZi,?
/{,/ 7
I ?t./..s'
/(,7,S,
i J.S--.a
171/.k
/?3,3
t)3 ;lc,,;;z.
CNA/Tlcono
Low-FlowGroundwoler Sampling Log
Low-Flow Groundwolei Sampling Log
Kubal-Furr & Associates
-£11vinmmi:11la/ Co11s11/ta11fs-
Project No. ____ .cc2.=.6Q=S0c..c5 ___ _
Site Location --=C::.:N:.::A,,_/l:.:;lc::.:o:..:n:::a:...•....:S:.::hc.::e:::lbCL.y~, N"-C=---
Fie/d Personnel c..:i k I} F"
Well/ Somple ID --'-~u· c>-DLJ.._··_,6e.,l._ ___ _
Weather Condi/ion ___ /4,_,, ._,;CL,.,'-';.id.t....L/.....,,/4,.,_,Li-__ _
Sample Dole Av-.3 s I O 7.... . Anivol Time .(<3o Sample Time / [yor
DescriplionolMomoring,,~\ ,...,~4Cminglype~ LodingCopl /I .casing~
Point !MP) \..,..A,....,,-~ • l,/""' . Diame1e1~
====-----====='----'
Purge Me1hocll Vu,s±c..t-1 ~ Sarnpltng Me!hodl 5AM E ! ~;:....,....~L~-"..!."'----"~-~
Purge Start Time! l] ~. :;.s f Purge Slop Time! / .f 3f,,, I Purge Rate,RJ,SVml/minl
Water-Level Measurements Field Parameters
lnleival
0
I
2
3
'
5
6
7
8
9
10
II
12
13
14
15
16
17
18
19
20
Elapse Time
jmim)
s
I c,
iS
Z.o
75 .-~o
7.:;
4o
ti<
50
-'>S"
&O
DTW (lee!) lnteival
12.'2 c;L 0
l.~.I, I
2? 1'1 2
-t{zo 3
Z3.-Z.I ' zs.zt 5
1. ~-<-~ 6
l3L'-J 7
Z-Z.Z!-8
'-Z ZS ( . 9
/J"J Zt. 10
.a3,)1 II
z. 3 il.J 12
13
14
15
16
17
18
19
20
El T. Temperalure Specific apse ime Conductance
[mins) (oC) (µS/cm)
-. ...--~
C l\i .CLJ Li,
It::> li.Y:S l\0
IS l9.oi \Ub
'1?I n \ I. 47 1LJ,
ct ) 7. in CZja,
✓1)' 11.r::o IL b
'?._ e_ l 7 .r.::., ,'L z.
L/o I 7,.'i> \'~°1
'-{5 \7.; I --, \3Ll
L.,o 17. '. '-1-. i7~
S'S /7,')3 j33
(;,o 17.<i: t 3 -~
Samples Collecled Conlrnner Descnp11on
Parameter Condilions: pH +/-0.1 standard unit COND/Temp +/-3%
Turbidity +/. 10% above 10 NTU +/-I NTU below lO NTU
pH {SU] Turbidity (NTU)
---l t..i7 ' -C:. Q
&,.qr 'Z. .1
L. <."7. [_(,
L_i../t, '&-7
b, '"I· -, . C.
{.i..j'-{ 'l.~l../
1'. 41 1.r✓, ~I,.,.
/ .. i/n 7. .. \
t~3c1 7.7
{:.,_l-{$ 2,,·2.,
&.t./{J J.3
/~. Lln 'Z. ~ (.
Prescivativc
ffi-1
DO +;.· 10%
ORP +/-lOmV
Dissolved
Oxygen
!mg/LI --l (,.,r
,_,_ .63
ORP (mVJ
-
16< . .S
11 x.·,
3. ti -, sr<. .Gll ~ l'isG.:
. '-137."
Lr7 J:t\7o
b"' er;} ? 7. (j
n.'.lL l.7--9
o.tn 7 ( ,,
o_ t/9 7 7 _;;
O,,.sJ IJ.f(
0 r:. i.i i~ -'"7
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·t.'--\dl _j .
• 0 O I
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CNA/Tlcono
Low-FlowGroundwo1er Somping Log
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Calibration Log
Meter Model YSI 556MPS
Meter Serial # 01 G0526
Battery
Conductivity Meter Calibration
Standard µSiem
Standard Reading µS/cm
Temperature ('C)
pH Meter Calibration
7.0 Buffer
4.0 Buffer
10.0 Buffer
Dissolved Oxygen Calibration
ORP Calibration
DO%
Standard mV
Standard Reading mV
Temperature ('C)
Turbidity Calibration
Meter Model
Meter Serial #
Battery
ESD Model 800
TUR800 358
Zero Standard (0 NTU)
Ten Standard (10 NTU)
Signature
/
Date -~'w.±->c.:o~,-:,,'l----'5...J.....,.-=u'-'-7_
Time \ o ·_ 'Zs --'---'-_;:_:: ____ _
~ -\S"c-(1:s
,s:ss
'i O I
/ f,
'l 2.4, 5
l l'-f • 'j
-c-c.. I. 6
Date .J.,)ot, ----'if/21-', ::.,,.. ____ _
Time _ _nU'_ . .,,,\],__ ___ _
0,0i
/o. D \
/ ;l
•' . ,
.:../1
-------Kubal-Furr & Associates,----------
Revised 2/22/02
Sampling Log-Grab Water Samples
Project No. 26OS05
Sample Date _J'.L~,ec;:;µ.£_,_·.ucri,,,.__ __
Sample ID ?civ-1
Weather Conditions
Sample Temp. (°C)
ORP (mV)
Method(s)
Po<vi7/0? •1 kvtx'." .i
Remarks
Sample Date _.f!....1.~_tf-/2-'-',}'------
Sample 10 (i?C,ii--3
Weather Conditions
Sample Temp. (°C)
ORP (mV)
Method(s)
I)c,.,,·77@.Jf /s Vc(s
Remarks
Site Location CNA / Ticona -Shelby, NC
Arrival Time __.:/._Zl_:cJ::....._.✓'----
-Duplicate No. _____ _
Sampling Method
Spec. Conductivity(µS/cm)
Turbidity (NTU)
Container Description
/XZ,•.r{r
Arrival Time --'-/,_'tJ_J_..< __ _
Duplicate No. __ -___ _
Sampling Method
Spec. Conductivity(µS/cm)
Turbidity (NTU) /,s
Container Description /'t(J.•~6:
Sample Time _.,_/-"o"-'-'"".;2"'0"'---
Field Personnel --"&-:'--f;..'-'·· =----
Preservative -
Sample Time ---'-'/4'--~-<1 __ _
Field Personnel __ .,.bi::..:=~--
PH f;.S 7: -------
bo :·_ 2-S-3~/L-
Preservative -
Kubal-Furr & Associates
Revised 7/30/02
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Purged Well Sampling Log
Project No. 26QS05
Kubal-Furr & Associates
-E11viro11mc11tal Co11sulfa11ts-Site Location CNA Holdings/Ticona. Shelby. NC
!// /,
Sample Dote (o/ I 1-
Field Personnel
Well I Sample ID
Weather Condition
Arrival Time _ __:__//.~;'-'3"'-----Sample Time /8 /.S"
Descriplion of Measuring I......-.-::-: _ I
Point (MP) / i!C Cosing Type I ?,/ L I Lockingc=J,,.,.--Casing~· Cap Diameter oL--inches
Total Depth of Well Below
MP?
Depth to Water Below MP?I
Column of Wafer in weu?j
Gallons of Water per Fool
(see chart)?
Gallons of Water in Wei!?
Gallons of Waler to be
Purged (3X)?
Purge Me1hod?
Purge Start Time I
Volume Purged
Time
Temperature
Specific Conductance
pH
DO
Turbitidy
ORP
;~:•)11A1G-t:c1' feet
1/4,,fo leell
/9.~c feet!
(),;ft 3 201/looll
-S,./3 QOII
9.sf 2011
&A-it,:£. I
f/77
\nilial
0 aal -3 aal
l!Jio //31
2tf 90°c :Zs.? Z.c
Jt/17 pS J.</'2-,.,
'-~~units ~}fo"""'
tY/! 7 mall /, i (I nm/L
1/i".0 NHI !/10 NTU
)/.1 is:if I/
mV m' ..
Common Gallons per Foot Conversions
I 1 /, in Well Cosing a 0.064 gal / foot
I It, in Well Cosing a 0.092 gal / foot
2 in Well Cosing • 0.163 gal / foot
3 in Well Cosing a 0.367 gal / foot
3 1/2 in Well Casing= 0.500 gal/ fool
4 in Well Cosing • 0.653 gal / foot
6 in Well Cosing • 1.469 gal / foot
Total Gallons Purged I --;:> I
::· ===_::,======gal
Purge Stop Time~l __ /..,/~-"='2~/_· ____ I
2 3 4 5
oal ,,J aol JOOI
/
oc -oc /c oc
.----:°'\717 .., V
"' ,,s ,s
sld units vx: stdu ih std units s1d unils
/
4c moll mg/L ~~11.
/ NTU NTU NIU NTU
mV mV mV mV
Samples c;ol!ected Container Description Preservative -fie/
Revise 5/28/02
Kubal-Furr & Associates
-Em1imnmc11/t1/ Co11s11lfnnff.-
Low-Flow Groundwater Sampling Log
Project No. _____ 2::,:6:.:Q::,:S:.:0:.:5 ___ _
Site Location _ _:C::.:N.:.:A.:,f...:.T:.:lc,::a.:.:n.=a_•..:S.:.:h.=.e:.:lb"-y'--, N:.:C.=c___
Field Personnel ---~-.c.· "--,-------
Welt I Sampte ID C -t/9
,f / / //.,I/ Weather Condition J¾;r. .. -' "'t'-1½<.....:~.;,"...:..u...:"-,,'r'-------
Sornple Dole '!..f./v )_ Arrival Time ~•J Somp!e Time _.:_/_..t./,,_,1s::'51c::(Jc_1
_____ _
De<c<iplionolM=•ingl....,.--: , I Cminglypel0.1/ I LodingCopl77 _Cming~ Po1nt(MP)' Jc?c){,,, /t-L,., ~ Diameter~
Purge Melhodlet:t,:J·;7,1.. . .;;7(... Sampling Melhodl ...s·,4~'ft=" ~,r.---, '-=-'-'-'-'-''-----' r,--.---,
Purge Stop Timel ;)If,, Purge Ro1e\lL.Joo ml/mini Purge S1orl Timel/)00
Water-Level Measurements Field Parameters
Dissolved
lnl~rval Elapse Time. mw (feet)
(minsj ln1erval Elapse Time Temperature Specific
(mins) (cC) Conduc1ance pH (su) Turbidity (NTU) Oxygen
(µS/cm)
0 0 J.~:fl 0 0 --
I £ .J(;,~,'( I .s-;JJ, 3/ .Jo
2 lo Jt,,59 2 /0 J'.3,S'{' /9
3 IS 76.S-{ 3 /f _;2$/S'J 19
' :l..t> Jt/f,7 ' J6 J3,tl /9
5 ,7S--;Lsft 5 _ps--J3,:}.} 19
6 <A Jr;..n 6 5o 13.!0 19
7 JS-JC,,S1 7 3--S-2}.&3 /9
8 t(O J{,.-(1 8 l/o .llbS" 19
9 '(.S" J.l.,;.S-7 9 L/:S' :J), Jt> 19
10 10
II II
12 12
13 13
14 14
15 15
16 16
17 17
18 18
19 19
20 20
Samples Collected Conla1ner Oescnphon
Parameter Conditiom: pH +/-0.1 standard unit
Turbidily +/-I 0% above 10 NTU
COND/Temp +/· 3%
+/-1 NTU below 10 NTU
(mg/l)
---
S',l7 2.J &;.,:fJ
..s,t1 :J, () S:t:,(,.
-~/! /,? £:cf(}
0,17 /, 7 S,7[]
5:6{. /,-S-S,{(;
~lY:, 1.7 _;,; J?
~t:1¥ I.I:, &, i)O
S": o I /,,f S.cf1
t/, 9✓ /,,} ..s,7,;J
Preserva11ve
DO +/-10%
ORP +/• I0mV
ORP (mV)
-
j,fJ,/
J.st:,.S'
:J,f/,7
;!&3.'(
3/s,J
'1 /.;),1}
3/l.l°
3l/.'j
3-.::c.q
CNA/Ticono
Low-HowGroundwoter Samplinr;i Log
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Kubal-Furr & Associates
-E11viro11111e11/nl Cm1~11/fn11l~
Low-Flow Groundwoler Sampling Log
Project No. ____ _.=;26:,;Q::.S:.:0:..:Sc_ ___ _
Sile Location ----'C'-'N-"A_,/-'T'--'lc"'o-'-'n-=a_•...cSc.ch-=e-"'lb'--'y.,_, '-'N-=C'---
Field Personnel G; k 7fr
Well I Sample ID --1..\:::..c\"'~--=----"t'--'z..,c._ _____ _
Weather Condition 5·-t'twll I p·s--\-\y: c ic-L<)t"
Sample Dole ----!--!=l:::::::!:~:::2·=0~·,c:'..·· _2-___ Arrival Time ,----'-\y_,·-'-.-', "-=====Sample Time __ Li ~s,_1~'. ... 3'"s ... · ------
cos;cg lype 10 LockicgCopl / I cm;,g~ ~ ~-===:::::.._D_iam_e_l...;er~
Purge Melhodl c...~~t.,..~fu5 I Sampling Method I s~me.
Descriplion of Measuring -r .
Poinl (MP) \ Ol::-L
Purge Start Timel tt..t. ·_ 2sl Purge Slop Timej IS:·. ·1,1 I Purge Ra1eJ.-"·-:lisbml/mnl
Water-Level Measurements Field Parameters
Interval
0
I
2
3
•
s
'
7
8
9
10
II
12
13
14
IS
16
17
18
19
20
Elapse Time
(mins)
0
(
iO
IS
2e
z. s
]'c:-
2,:,_
t.Jo
0:5
5o
5s
to
OTW (fee!)
\_~_;;,
1( _p::
,.., ?.'I
\ i>JN
1 (L1c
l1.n.5o
7 I .3<, zz 51
t'Z-9;
2.?. ~'-
24 7,-
Z'-1. 7J zs.l.;
Samples Collec1ed
Porome!er Condi1ions: pH
Interval Elapse Time Temperature Specific
(mim) !oC) Conduclonce
(µS/cm)
0 0
I (_ I S\.co ~-~
2 lo I '9.. 7 a, ~l
3 IS l'b.Lj5 7~
• (_6 \ '-6,7..0 7 l-/
s z. ') IQ c11 74 ,
' 3o \ '5!.00 JI
7 ]5' 1 'li.$ 7i
8 '-it, \9_ 1b 7 2
9 (/'S vi. '-to 71
10 So I j.5 y 73
II r. C. i;, _ l8 7 2.
12 co \°{.CI 7·2.
13
14
IS
16
17
18
19
20
Con1a1ner Descnphon
+/-0. l s1ondord unit
Turbidily +/-I 0% above IO NTU
COt~D/Temp +/-3%
+/-I NTU below 10 NTU
pH (su) Turbidily (NTU)
(_<:;iz_ i ClS 0
5·_7j ( '6. <_
5.79 "r.o
t;. 7 '-/ (._ 4 y
~-. l 'i :._ 7. x
c::. 77 .Zs.'2
,,:_ 7z 7 ~.,J
c; :1c:. llf.b s. 7:s ,, I, t;
r;.7z 1..0.'>!
\ '7'. Iii, 'fl
r,_ 74 l 7 .. I
P1e~erv□t1ve
ff(./
DO +/-10%
ORP +/-10rnV
Dissolved
Oxygen
(mg/L)
Z.w
o,[,2
0. c/ x
o. 'ill
0 ,.~j/
. ) ..,
j-
1. D''
2'1
i ,43
I .. 5z
I. 'f'i
ORP [rnV)
I t,o.c
\Z. '-I _.z:;
,,. __ Q
I t;".J 7
1 /.,1~ -Ii,
I If~ .G
2-1 I ·'
ZZo!"t
Zs'f,G
Z.s'/?-1
·z,12_ 6
'Z'/6. "\'
CNA/Ticono
Low-FtowG1oundwaler Sompijng Log
Chain of Custody Record Page ; oil_ --
Client Project I Site Location 816 E. Durst Avenue. Greenwood, SC 29649 [phone] Fax: [phone] see LJse umy
C.N.A. HoldingsrTicona 61195.02 Laboratory Cerlifcation Numbers: SC-24110, NC-25, TN-2923, VA-77
Shelby,NC For Kubal-Furr
Contact Report To Copy To Reporting Requirements: { J Standard { } Data Package (Specify Level) 11-'Urchase Order
":;VlfE L,.1,,.,)8, /i'fr,1\ 'f'c;'-1 C'Afl.1c-R--1✓c.;-r.JA \T,JL rte-L1.J67Jil I,, -K6J
Collected By 1 Required Parameters, Containers and Preservatives State Quote
{;;Zg.-j:,,v.f,1//J'N " " " NC E T'/.1.r T,,./ Pv1'l/J... E E ~ " 0 0 ~ J LOQln Special Instructions ~ N ~
NOTICE: 'C ' ! e 0 • i~
~'.8 j le 0 •
C I • ~ ~
. !: :s 0 iD ~ ~~
~-~ " 0 ! C'C
" 0 ~ ; tl ~ 8. ·a 6 N • 0 0 "-C Ug ~ :it ~ -~ D <( 0
• E E D E ,. " 0~ '6 iii
Sample Collection .§ _§. 0 • " ~ 0 5 p ~~ .s " " " > w ..J
Sample Descrintion Date Time Time Type Total C A B A Fraction HOT i.amments
Trip Blank 1F/ 1 X "'Ec'7A-Fli-
'f---rEr .Y/..r/4 z.. 1/cC• v s-s-X X )( •• 7# ~r. !.fc,~
r,,=-7:::--Pv ;> r/,j,,i /j,,6 / -~ ~ )( )(' )<
-;i:'TCI .r/..--1, 2 11:Jo / -< -x.· X -~ X
Jl-1/-7'? <f'/,/4i I ;Js-.r .,,,.. ~ 5 >(
ll!/·4f .;-j..,/,J 13•/..s.-v s '3 X
AA-~1 .f/4-/4:1. i•1..r ✓ -5 X _..
-r-1~-,j,J,-1 /i,s-_s-v ,r 3 V
/;-{-(.,( .f,/4-1.,?. ;,fil/c v s 3 )(
Pe,,./-I s-/b/4Z 10}0 v s-;.( )(' X'
r't?W·· J, ¼/4). /oSo .,,,... S" '-( V X'
C -tf? t-/4/4 ;i JJr"o ✓ 5 3 X
Fs..s' B'i,,(; .. JW-S ✓ s L( X x
rr-~J.. --I ~/4:;I /SJ.;-/ 1-5 1 ('. ~--/ . ., / / ,, , I _,,,,t--~-,/ .~ ., ' ~ -~-. / /
Z7,:tY ~ Time Reliquished By Date TTme Reliquished By Date Time Quick TAT Shipped By -¥ .,z. 1-S'J..S y N m '"= ..-;J ,, "" FEDEX ,, Rec r,.:' l/4d ate Time Received By Date Time Received in Laboratory By Date Time If Y, specify: Airbill Number
8 ~/4,,2
-
) /...,7,---days
ILO~
Cooler ID (if available):
On lee: Yes/ No Temp(C) __
Custody Seal: Intact / Broken I None
Matrix Type Definitions 1 -Dnnkmg Water 2 -Clean Water 5 -Groundwater 7 -So11/SedIment B -LIquId Sludge 9 -011 12 • Air
Preservative Definitions A-None 8 -H2S04 C -HCI O -HN03 E -Na OH F -Filtered G -.1 N HCUpH 4 lo 5
OaVJS & Floyd, Inc.
FL02_01 (02199) --------- --- --- -
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Low-Flow G1oundwa1er Sampling Log
26QS05 Kubal-Furr & Associates
-L'nr•iromn,•nlol Consulltmts-
Project No.
Site Locotion _ __cC=N.::.:Ae./T:.;1=-co,,.n"-a=--•-=Sc:h::::ec:lbc,yc.c,..:.N:.:C=--
F ldP I G',k )-sr: ,e ersonne __
1
_,=..,f_;..i_...::..,~ .. ,;..L...::/:.,__ _____ _
• Well I Sample ID _......Jt:'='----''~.J,1_ ___ ,_-,---JY/ I /i./ .1. Weather Condition __ .,i::fk;,,,' _,_c----'~-'-(+-cf _ _:cc"'/Gce·"""~"""'-" --
Sample Dole N# Arrival Time __ .!__1?lc_c_'/-=.' ;:=:===:::;Sample fime __ .,,,.w .. · .,·-&,,,,_1 _ _,/..sb<..c·-2'-'..:3,_ __
Dmcription of Memurin,;.i~ Cming Type~ Locking Copl / I Co~1ng~
Point (MPJL.l.Qo_ci ~ ~-=;;(./=:=::::!.· _o_,□_n_,e_le._:r~
Purge Method: ~£'°"~[bl ) Sampling Method I .f1¼'r!
Purge Start Tlme )6§0 ] Purge Stop Tirne!L __,lcs,l~•~·~:...::,.,___,
Wafer-Level Measurements Field Parameters
ln!erval
0
I
2
3
4
5
6
7
8
9
10
II
12
13
14
15
16
17
18
19
20
Elapse Time
(mins)
C>
<
IO
f.:,'
Zo
J..<
30
DTW (feel)
!(°{.~
/ /. .. ii
il,lf..
,ti9
\b_I.I
//;.;,f
ilil
Interval Elapse Time Temperature
(mins] !0CJ
0 0
I .5 i~.JS'
2 it '<is 1,
3 /-:,----I~ i./5
4 Zc l<l. <b
5 7 c., j<;( .i-2.
6 3u I i,.ili
7
8
9
10
II
12
13
14
15
16
17
18
19
20
Specific
Conductance
jµS/crn)
!,';
.CJ
56
(o
So
'-{1
Samples Collected Conla1ncr Descnp!1on
l'rnameler Condition\: pH +/-0.1 s!ondord unit
Turbidity +/-10% above 10 NTU
COND/Temp +/-3%
+/-I NTU below 10 NTU
Purge Ratel f.c:;,c ml/mini
pH (su) Turbidity (NTU)
~-6/ 7.. 0
( .Sf I. 6"
5·_5_, LI)
~ .<'o D. ~
.C: Lil' \.3
!; <o z.o
Preservollve
/h/
DO +/-10%
ORP +/-lOmV
Dissolved
Oxygen
(mg/L)
'-/. o-a
3.zr;
3.o:i
l .'17 ·z .cio
2 .lll
.
ORP [mV)
"2L"t.O
7 .. ,;"i, /'>
'2.71.'
Z.81.7
2 i/'7.~
Z 9 I,~
{(3 }ooe'.l
CNA/Ticono
Low-FlowGroundwoter Sampling Log
Low-Flow Groundwater Sampling Log
Kubal-Furr & Associates
-li11uiro1111l!'lllal Ccms11l/11nls-
Project No. -----'2'-'6'-'Q°'S'-'0-"5 ____ _
Site Location _...cC::.N=A,_/T.:.:IC::.O::.n:.ca::._·_:S.:.:h.::e:.::lb:.,y.,_, .:.:Nc::C:__
Field Personnel _ __,&j"-L'-'k"+/---'SuF:_ ____ _
Well I Sample ID __ Lf_T;i,,::~·-~,;c;,i·c.,3.__ ___ _
Weather Condition ----~50..u<.1./1..eC!fi.'-';<.-----
Somnle Dote ___ ~:':"=3::=f6'-,.0Dc.2::::.... __ Arrival nme j' ·, Se Somple Time==='=\ ,,~,.'-c,O<,o,::· _ _:__ I ____ _
Description of Measuring Casing lypewJs~ locking Capl /1 Casing[Ll Poin1 (MP) Diameter V . .. !::!\,~:::::=:!._ ___ ~ ~==;:;=::=::'---~ ,ne,..,1
Pu,ge Method! G'ill,(oJ b I Sam~a•_ng::__M_et-ho_d,cl _~.S=-c,.,,,Q.,t'"-"',---'~~--.
Purge Slar1 Time) \ 7 .,osl rurge Sfop Time I ·17 :. ?'i I Purge Ratej\.., ~,e} ml/mini
Water-Level Measurements
lnlerva!
0
I
2
3
4
5
6
7
.8
9
10
II
12
13
14
15
16
17
18
19
20
Elapse Time
(mins)
0
s
;u
IS
·lo
r1 C
/,)
·z.:.
I/()
i:/ "j
0TW (feel)
~7-91
Lio z,
'{o. r;
Ii.fa. li\'.?
l-}O .£.<./
4o,4
uo,~
l1D, u.
'10 .Ip
lwv ~5
Samples Collec1ed
Interval
0
I
2
3
4
5
6
7
8
9
10
II
12
13
14
15
16
17
18
19
20
Remmks '--/";31}tL. ,P,,•J6(!!) _,..... jb·
Field Parameters
Elapse Time Temperature Specific [mins) 10CJ Conductance
(µStem)
V -----,f 1c1 _c;o 'o'L
10 l I • .3{, 7:/l,
, .i; 77,:,Q 'O
?o c.?.. ,l7 ( _?,
-,< 2 -z, '531, 1-z.,
~ -7_ Z>D'f 9's .,, 23 i'1 1 <,
40 7Z 7'~ Cjf..
i./5 t~ . i; ( °16
Container 0escnpllon
Porame1er Condi1ions: pH +/-0.1 standard unit COND/Temp +/-3%
+/-1 NTU below 10 NTU Turbidity +/-10% above 10 NTU
pH (su) Turbidity (NTU)
-----(,. 2,1 ·• 0
tz.-s ' .0
6 27 n_,
6.YJ ?. -'7
l, ~1-I, ?
6. 2,?. 0.9
l -,; Lj i . -1
l ss i • i
b.)[
I, .. ,
-
Preservative
DO +/-10%
ORP +/-IOmV
Dissolved
Oxygen
(mg/L)
~
J.J ., i
'3,03
2/'l
'l..,c7...
I • f. v
I. L/ t
I . \q,
/ , l O
I, 15
'---
ORP (mV)
-
Z03,'7
~
187.
ln:f_"?
~qJ
7 6, 7
i,.j,7..
{/. L
4.:fl. 7
2.
./
CNA/Ticono
Low-FlowGroundwoler Sampling Log
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Low-flow Groundwater Sampling Log
Kubal-Furr & Associates
-Em:,imnm,•11/11! C(l11:;11//rmb-
Project No. -----~2~6~Q~S~0~5 ____ _
Sile loco lion _ _;C=.N=A"-/T:..clc=-o=-n"-a=-•-=S.:.:h.::e:::lb:.,y"-, ..:.N:.:C:....__
/_'_t,,, Field Personnel t.T ,-. ----"''-'-'-------We II I Sample ID ---'C=-'C_-_:3:..:3:c· ______ _
rf, / / /'.frJ-1 Weather Condition ___ -f:~u_,-1_ ... _·~1f---------
Sample Date __ _c/c.._ G,.,_'/_""_ ';?. _______ Arrivalfime ~ . r:/-Sample Time /90...S-
Desrnplion ol Meornringc:==7 Casing lypel r I I locking Cap~,/ CosingG7
Point (MP)~ ...:,_Jo ~ D1ameler~
Purge Me1hodlfpJ1.S;:--At.T/O::.. Sampling Methodl ~tf" ~~-'--'-'--""----"---
Purge Siar! Timel/f3o Purge Stop nmel /'j() J. Purge Ratef"l..JA? ml/mini
Water-Level Measurements
lnlervol
0
I
2
3
4
5
6
7
8
9
10
.
11
12
13
14
15
16
17
18
19
20
Elapse Time
jmins)
0
5
/u
i.S
{)o
«.S-
Jo
OTW (feel)
;; It /3 lfl, _:,
,; '7, I 't
27.J1
27,}f
J1,3tf
:)7, ;Jj
)7,;J1
Samples Collected
'(JlJ
ln!erval
0
I
2
3
4
5
6
7
8
9
10
II
12
13
14
15
16
17
18
19
20
field Parameters
Elapse Time Temperature
(mim) ("CJ
0 --
S' d(),Jt/
/o /'1, 39
1-r-/9, 'J.f
;lo /y,3:2
JS-i9, 3(,
50 /9,Jt(
Specific
Conductance
(µ$/cm)
-
?13
:J.x s-
:So,f
's!I/
:s1&
3/9
Container Description
Porameter Condiliom pH +/-0.1 ~tandord unit CONb/Temp +/-3%
+/-I NTU below 10 NTU Turbidily +/-l 0% above 10 NTU
pH (su) Turbidity (NTU)
--
6,5'8 .#o. 3
{,,,ot/ /"3,&'
&:>.!/ 6J~
{o,/'f / .5' ~
b, D°{ . ".o -
&,,// /.&
PreserYallve
·c
DO +/-10%
ORP +/-\OmV
Dissolved
Oxygen
[mg/L)
-
1/.Js
J,3]
/, fS-
o.s:s-
O.Sb
O,,f°{
ORP (mV)
-
R--s·~o
-5~{,, t/
-b~.?
-~,.<
-C,/,S,
-s~;J
CNA/Ticono
Low-flowGroundwoler Somping Log
Calibration Log I
Meter Model YSI 556MPS Date .f/4/4 ']_
'
Meter Serial # 01 G0526 Time o9rf
Battery /
I
I
Conductivity Meter Calibration
Standard µSiem /.s7.S-I
Standard Reading µS/cm ;.S-.7il
Temperature ('C) 6/. 0 .-I
pH Meter Calibration
7.0 Buffer I
4.0 Buffer
10.0 Buffer I
Dissolved Oxygen Calibration 97t:t. 00% I
OAP Calibration
Standard mV ,)Pt/~ I
Standard Reading mV -~.-::err l'A9
Tl?mperature ('C) JC{"' I
Turbidity Calibration
Meter Model ESD Model 800 Date sjj2
I
Meter Serial # TUR800 358 Time O'i-,;-b
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Battery / I
Zero Standard (0 NTU) {)_ ol
Ten Standard (10 NTU) lo. t5 I I
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Signature ' ~ . ~!~--~-
-------Kubal-Fur & Associates,------------
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Revised 2/22/02
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Low-Flow Groundwater Sampling Log
Project No. 26QS05 Kubal-Furr & Associates
-[11uiro11111c11/nl Co11/:,11{fn11f1:,-Site Location CNA/Tlcono -Shelby, NC
Field Personnel (i:::,/4 L
Well/ Sample ID f\t,£ J:/7 ~ J.-/)) Q? Weather Condition • .Ju/41,<1"7
:,ornple Dale __ --'../_,~_,/:.._ O__c.. _____ Airival Time C 7 ·~) 7 Sample Time ___ ,c/L/_·-~1,~1~5.,_ _____ _
Desoiplion of Measuring!_-.----/ I Ca . T I ,-,· I l k C I . ,/ Casing[LJ Point (MPI ICA:'.JL--sing ype ~.-1. oc ing ap V Diameter · . :=====---~ ,,.,c-h.-1
Purge Melhod[j-(,./1t.,'(Jf.-•J Sa_m_p1_,n.:_g_M_e_1h_o_dlc-•cc:f:lu.c·,.;.c/s.·· ______ IC-___ _
Purge Start fimel /,2; 1 Purge Slop nmej /D .' ff/ I Purge Ra1ej J,cX) ml/min/ l,..~fff'l._j!..J
Water-Level Measurements
lnfervol
0
J
2
3
4
5
6
7
8
9
10
II
12
13
"
15
16
17
18
19
--··· r··20
Elapse Time
(mins)
0
_c:.;·
I,,
) <.:
},D
.+, <-
'J ,')
J s
'/ti
._1,.-
'
•. ... .-
DTW (feet)
2t/./t/
.?-1 . c;1,
.)f/,C::.
,s;,.;;xl..
;-x1. ,s-
·,,, x/ ,!.~"I
'--c .z'l
:, ;, .1, :
::,, n
;,,1,08
...... ..
Samples Co/lecled
ln!ervol
0
I
2
3
4
5
6
7
8
9
10
II
12
13
"
15
16
17 . .. ,--· ..
18
19
20
Field Parameters
Elapse nme Temperature
(mins) [0C)
a -
c.., ,9_1 :nl.
/D f(vr ) :l. . Q)
15 g dJ, 1,3
], '\ (, ,.9,J, r,,c(
'.] --.· .. \ ;;13. 17
3S);<;,\\I-., 2 . ,o
•?c· .:,.-, ·"· ""· 70 '-fu ~3 ,)/,
'I'S :,'.l'.1_ ;)L/
I:\
~-·n
',J
Specific
Conductance
(µS/cm)
--
·1 I ,C:.
1•7 Q'/ .
5c3·:· ,_
,y('~
7'17
,. .-, q·
I'.; I ·2
'{03
<i:DS
Container 0escnp!lon
Parameter Conditions: pH +/-0.1 ,tandard unit COND/Temp +/-3%
+/-I NTU below 10 NTU Turbidity +/-I 0% above IO NTU
pH (su) Turbidity (NTU)
--
G-3n {./.,/,, ~
I ·,c1 ,.J.S. _:i,
u ,
I .. ',· :{<, . .5
l.n,,/c1 .:,.~C~ I
I. ·.J.li' I•,: I.
L J,C, /It, 7
/, • :'>1) ,1/7-/",.
{r. :i..S " .
I 7. 7
(,:, 3 rip,~
. ..
.. ... .. _ .. ,·••'
Preservative
Bct1
DO +/-10%
Dissolved
Oxygen
(mg/L)
--
o.m
I') '1-
/) . ']"-
0. ~o
C · S:~
n,t./,&;
o .s,
Ci . .'li'
L1 · .'.s5
ORP (mV)
-
.• j Ii' , 9
-] ;i.. :i, . ' .
->?. -.
-~3-•1
-;/</-C
-,.)/., ,_
-.4).lc
~ar, 1.
--,.Jc:. 9 -'-'.
_,,.,, -~ .•.
.,...,.
ORP +/-lOmY
CNA/Ticono
Low-FlowGroundwoter SompUng Log
Sampling Log-Grab Water Samples
Project No. 26QS05
Sample Date __ i+,1/~}'-. Lfe_o...c:Z __ _
Sample ID
Weather Conditions _f'u /.I rJ
Sample Temp. (°C) /),/ 9S-
ORP (mV) !{'J',f
Method(s) .svt1<'.., lw/.,) 711,.-;r.,"t
Remarks
Sample Date ______ _
Sample ID
Weather Conditions
Site Location CNA / Ticona -Shelby, NC
Arrival Time Sample Time __ /_l'f-_0_...-__ _
Duplicate No. ______ _ Field Personnel __ 61'-;c:'."_·.,..../_s;r_· ~L~_
Sampling Method
Spec. Conductivity(µS/cm) 7~ ·,). i/!, pH ___ ..... l.:: __ _
Turbidity (NTU) ------'/,'-tJ ___ __,DO(mg/L) __ :?...c_,_~_'(.,___
Container Description Preservative
lk,2,.f'&
Arrival Time Sample Time ______ _
Duplicate No. ______ _ Field Personnel -------
Sampling Method
Sample Temp. (°C) _____ Spec. Conductivity(µS/cm) pH ______ _
ORP (mV) Turbidity (NTU) ---------=DO(mg/L) ______ _
Method(s) Container Description Preservative
Remarks
Kubal-Furr & Associates & J ;}c,e;).
Revised 7 /30/02
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Low-Flow Groundwater Sampling Log
Kubal-Furr & Associates Project No. _____ 2:::6:.:Q::.S:.:0:..:5 ____ _
Site location _ _,C:.,N.:,A:s/c,l:_:lc:.,:o:,:n:,a_-.c:S::.:hc::e:.:lb"y.,_, .:.:N:.:C:__ -£11vinmm1•11/11l Consultants-
Fietd Personnel --'~C<-7'..l
1
{5_,_· ·-,-';.,--'jsl';' 4&,:q. ____ _
Well/ Somple ID ____ J_,L_.o,""c.._c..:3,<... _____ _
1 . , / Weather Condition Sf+J)t,'11)' ']t.4W ain d_~
SampleDote __ _.,'f-1--;7:tc:::::0:::.;J._,==;----, Arrival Time /13'[ Sample Time ~ !14: O'( 7
Description of Memu,ing _..--Casing Type I ~). I~ Locking Cop~ o·Cosinl g~
Poin1 (MP) /ODC....~ ~~ t'S'i ~ 1ome er~
Pu1ge Method! r on·Af)::¼ !he, I .· ompling Method! Jkni'a.J..rPtr,r. !
Purge Start Time I f f4:o l Purge Stop lime I /(c :cv l Purge Ra1el---f§P ml/mini
Water-Level Measurements field Parameters
ln1ervo!
0
I
2
3
4
5
6
7
8
9
10
If
12
13
"
15
16
17
18
19
20
Elapse Time
(mins)
--
1::...
/ D
j c:-,....,
:)..,j
!2,J
:;<
I •1 < ,.
,1c,·
'51)
,2::
uio
G'i
.// u
'1 s
'YI)
DTW (feel) Interval
1410 0
·)o. Jt -I
~o . ..Jn 2
--io-."1 3
:::'P,{1./ 4
;:i o · l,;, 5
-, •, (a2 r·1U · 6
Ju l11 7
.J,O· fo9 8
).,1) ~~ 9
".).D.
. (• \.,1 10
.:n), 1¢ If
·.:l.n. 'J<i( 12
d,i) • .:-,1 13
;);i)_ l0 14
:t,() .--::+ 15
,:-.r,. ,:,:-16
17
18
19
20
Elapse Time Tempcro1ure
(mins) eCJ
--
,;:; Jo.1,u
iO °?, 0 ti
i.s--::,, .. '7-?
?o ·o,6 7:;_
-:ic-"> 0 .,-1
3D ) ' ··, ., ,o. 1~
3,;-•J•"',,i r)
,/~ ~~./.~
u ,•-. "'2,-:"),. Jc .
5U ");],", . ,.
55 :JD• 7'1-
C.o ;;(0-\,,9
~s r\,,. -v
f'/0 o,i)-· -",
'J 7 ;:,;\ .173
':?1J ~r,. i,/
Specific
Conduclance
(µS/cm)
-
.,_·q,,..J.-
• --._/.Di
lnq r,,q
-.,,q,7 c~, 10
I, q.--, I'
r;Ce,C) =
• ,,,C-.... ;-\ -l,;<7;!,Y
i-c1 r 1-,
l.r:;.q,
/, <,N/,
r.c rJ.r-
(,'(nc'
1,, II.•
' /,◊ ""'
Samples Collec1ed Container Descnption
Porome!er Cond1liom: pH +/-0. \ s1andord unit
Turbidify +/-10%above IONTU
COND/Temp +/-3'fo
+/-1 NTU below IO NTU
pH (su) lu1bidily (NTU)
-' n
t-f 70 ;,; '. "iis-
i:/.1,,~ /J.. dld~
-l Jc j. i,J''"
i...f-1n1 t./. :),(j)
If { ~ :;2. 3
<J-1,d 9, . ' . I
,.! l/_;i'. ~-11.
cj /,.;-I' I
\.. . (;I; i .11
~!, (S~ I. 11
il_h9 /. {.
tl.lL. ._J • ~
t.'. 77 ~. I.
'-I. ,,~ :J . 0,
if. 77 3 3
4,77 ;\. i
Preservative
DO +/-10%
ORP +/-I0mV
Di~~olved
Oxygen
(mg/LJ
~
0.~J
,,. _.,,,
, ,) . < r,
,...r, G:2.
/,. >:d-,
I ,(-
' I }_ /_
/, </r-
/ .. q )-
' ., 7 _,,·d
5 .77
/3-b°i
ii .,;, I
f/ · /:2.J
'LO.fl
;:;, {) ,"(,
ORP (mV)
-C.C.1-
\'s. <
-;✓ <·-
c.~1. y
s-s:-8'
C<.1,,,
CJ. .. I
;, .,-
C,(p (/
/:ii: .LL
.51 •. ·7
,S1-· '7
51~. ,;:i.-
.. 11.r:;5,
-~ 'I. /,,
c;,J. -i
CNA/Ticona
Low-FlowGroundwoter Samp~ng Log
Low-Flow Groundwater Sampling Log
Kubal-Furr & Associates Project No. ____ .=2:=.6Q=S0::.:5c_ __ _
-[1111iro11mt•11/n/Cm1s11ll1mls-Site Location CNA/Tlcona -_Shelby, NC
Field Personnel /,k <t" -RF
Wet/ I Sompfe 10 1..._ · ,;f½z ~ , ~ .sl ~id• I
/
Weather Condition .. ')q~ U.::.Q,-112::'.! "7 z:iM1•
Snmple Dole !>: '7 lo d--Arrival Time j / : l •. (7 Sample Tlme 1 ~_ ) J J
DesoiplionolMe_~uringr::::-----1 Cminglypel 0./(1 I lockingCopl V I _Casing~) Po1n1 (MP)~ \' V \._.., . . D1ameler~
Purge Me1hodl p<2l sd:1 p.f,f'l I Sampling Melt1odl p~ 1 i·>f, P/2-C , I
Purge SI art Tirnel / ,.?., ~ Q/) I Purge Stop Time I /'-f / 7 I Purge Rate/ A/-JO ml/mini
( ~
Water-Level Measurements Field Parameters
ln1erval
0
I
2
3
'
. 5
6
7
8
Elapse Time
(mins)
/,?
c::.
,1)
(,;;
)o
···< .;,,,
¼,
2(:""
L/v
DTW (feet) ln!ervol
23.i/S 0
),cf. fz. I
'J 10 Tl I. 2 ..
:i.<:...fft 3
9.s. ,le' ,J) '
J.,~~~ ~ 5
J, <;. fl'# 6
.')./,,.oD 7
,9.,G . iln. , 8
Specific Elapse Time Temperature Conductance
/mins) ("CJ !µS/cm)
l,7 . ..
<, J,.:J c·:, ' .. to <· n.'.l
/() :-J, 1-lA 1,,:,.10
iC ..,,_cf1 I .J,,,, I
.:::>a ~ I (l/-~~""A ., .-::-,,'.) ?,1.90 ;;l::i I .. )
:.i) r:i..;:,. . 19 3) <'.fl
36 ~;/ ).'1 ")I-,-,
'lo 3,-;l. ·-fl :il'73
pH (su) Turbidily !NTU)
-·-
r:;_ '?3 1-, I.::,,
C /,2, 3'k. :J..
~ ".9_--. IK·"
s-'l? 7 '1 I •
<.<;.(/) JY. '7
c., :0-t /().<
':). "11 . /S:"./..,
5_g;, IJ.
Dissolved
Oxygen
(mg/L)
-
,-, . "!.::J
0 i.R~-
0 ,/;)
•'·'-/!
o-fc
(.].yq
o-.-;'/
0. l.n
ORP (mV)
.-
-I0s-::i..
-/aJ,9
•· 101.,?
-C/c •7
-·75. 3
-1l K
I-In<;• -"'
-q-J i.
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9 ~ )./, :1/; ~ 9 Ll·S J. 3. 3x '1,;), J3 5 77 f'f.O /; (<<., -; q)· LJ.../,fi . s--I
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10 Cl) :L . .9 ("' 10 '5D ;2,3 J4· '>30J..
II {_ {.'' JI, (,,"J II <;<;-.2.J. 'X: :_s·:,,03
12 (i {) .~i,.'lin 12 Cc 0 ').),. d>X' 33~<1
13 (os ,"Z l · .J<; 13 /,,, c:;-,J. "'· ft 3 );,'.::2_
14 -;n _'1_,.. • .k " 7-0 ;J.) ":o -:;,_ ., ~ I
15 ''\ <'; ;;r -~i 15 '?F-, ,) ?;, '.l,4 ·:z_ I Ci i
16 'xi? .). ']. "1' 16 so ~3 J:1 n,_~_ql~ ' .. :)
17 <f-..S-.J7,?f 17 t,., ,J.3 J. ,b 306'?
18 9o ,:JJ,93 18 9o J3.'J ~ J973
19 <j..s (}7,c;cJ 19 ?S-/)..},, )..'7 '!'C\1'1
20 1DV ;M"( ,;fl; 20 .i 'ODD ),, i>'1 ?.413
Samples Collected Container Description
Parameter Condilions: pH +/-0.1 ~tandard unit COND/Temp +/-3%
lu1bidily +/-10% above 10 NTU +/-I NTU below 10 NTU
c;.s;, 1 /(). i) I U)( I• -/&.(p
S-'6-C/,7 J.iO ·-/1>0 ."j
,-,_ I ;_(p \.~'-/ ·-lc~s
'-"v7 c::, .S;("" 9r /,7{ -;orl. /"
~ . ....,,.> _/(!_' I . "J 1,, -107.<j
s.~;;i. Ii.;, . '2., ,/JI -· :,, ·7s;,
S.g-o /l .. 0 .2 "1"7 ,7 Jo--; .. c
,;;7'7 1J.f 3,19 --1)0,</
S.7f (J.5' </,S'c) -10 ·7, I
c,_ 11 :(,, ·'-!· S-'J-'I -1111 .(,
c; S<<: J [~ .)-'1. 01: 111. r-
Preservalive
DO +/-10%
ORP +/. I0mV I
CNA/Ticono I low.FlowGroundwoter Sampling log
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Low-Flow Groundwater Sampling Log
Kubal-Furr & Associates Project No. -------'2'-'6'-'Q"-S~0'-'5 ____ _
Site Loco lion __ C=N:,:A::,/.:.T;;lc:;o:;n.::a::..,..• .;:Sc::hc::ec:;lb::.Y,:.,•.:.N..:.C=--
Field Personnel _ __,(~--;'-'f,"-·-•.:.i~1\4. "-l'.,". "'·'-. ____ _
Well/ Sample ID k, . ~ J' j&► ~ $ 1,"')k•llu
/. 1/( ~-'yVeotherCondition qt, ,.,,.1.,. 1 /i\Q.1,271 U·r..-::'l:::{t
c __ ·7(;:-i c·· /J 1 1 -J-L'1" J ;;, Sample Dole ---"'~-1---','-"-'v---"-------Arrival Time --. '--' : -r-Sample Time ____ LJ...,;2:,£,J."''.!.c..... ___ .:.__ __ _
Description ot Meos~nng~ Cm,ng Type I 'P I( I locking Ca D . Cosing[n. Point (MP) /o,,.,r, {; _.,, P Diameter if v\.._. •>ch~!
Po,gc Me1',odl 7"01 uJ,-f,r)b (_,, 1 Sampling Mel hod I ·zc1,J Y,,.P; c
Purge Start Time I //\ ·w I Purge Slop Time I It I] Purge Ratel~.,,.._ ;.s-oml/minl
Water-Level Measurements Field Parameters
Interval Elapse Time
I I DTW (feet) Interval Elapse Time Temperolure Specific ( ) 10C) Conductance pH (su) Turbidity (NTU)
rrnns m1ns (µS/cm) ) -/-.·,A;.\),,-
o/, I ,,,.. ,.,,... /0$-._?,;K_rr;:i ./Od)/ /OS d, 3.t< --,.1,-1,, <. s: I 4-7jJ;
.-() d"' //;) '1,1 .Cf ,,,i-::i.:: ilD ri.'l, '.) V s .Pi (?, 'b .I "-,-:;_'lj_,,
;;,'J'?, i1..S-,J,,9<: /2;;);3 Jr< ?,'2. ·'" i,, ..... ;; <-1, ,,. . <-' I }1 ~
,.£~· i;:,-c, ') "1~ ,z,xf j ;)i) ---1 ·'l ··, "'\ °2., ii .. 2., ., I .:; I.. -h · i ,41:?, tf.~7· -"'· ,-~
-. ··1 1d) s; -1·~ :-~:::i ?) i ~, ;
I O • ,-/4-:1;,::· I . f', •. ;,'5 ~ . <-, .··1 .-i
Y-:i.~ i?Q ;.;;,77, ·" ;?i J "3iJ ;;i.-~-·;;i C ,.,,., C. ,· I I~' I
,/4',,1 /'C-:;:,.-J. <j,• r·z "-·cJ-~. ; ... ~ • l ,.:.:;. t~ ,'6 ;J.1 ?"I\< C. c~-
7 7
8 8
9 9
10 10 ,,.. ......, ,,..v ,, -----~/
. ---11 II -----------
12 12 " _ ...... ____ ,.,,.,.
\ k A'.",,...-.,..
13 13
14 14 _,---1
/ 15 ,.., .... 15
16 // 16
-. 17 17 ,
,
18 .. 18
'
19 19 ..
/,0
/ 20
Samples Collected Container Description Preservative
h -,,r;
J 1-/C
Turbidily +/-10% above 10 NTU +/• 1 NTU below 10 NTU ORP +/-lOmV
Dismlved
Oxygen
(mg/l)
,j---:;:L
~9f
1 . 5'1"1
'' I 1, I•--•· i
;" ry;J , lo .Q:J
'1 ;;):,
-
ORP (mV)
-✓-1 :i.:1-. I
-,'Jli, I,
-· i:J" .i,
', .,
-/?7 .'it --/'l.7. ~
-I ":"(·7. ~
-·-
CJ$k.2
CNA/Ticono
Low-FlowGroundwo1e1 Sampling Log
Calibration Log
Meter Model YSI 556MPS
Meter Serial # 01 G0526
Battery
cfP
c.G.or.i~ Meter Calibration
Standard µSiem
Standard Reading µSiem
Temperature ('C)
pH Meter Calibration
7.0 Buffer
4.0 Buffer
10.0 Buffer
Dissolved Oxygen Calibration
co<fDvcoJJ'rj
...,.GPWCalibration
DO%
Standard mV
Standard Reading mV
Temperature ('C)
Turbidity Calibration
Meter Model
Meter Serial #
Battery
ESD Model 800
TUR800 358
Zero Standard (0 NTU)
Ten Standard (10 NTU)
Date ¢;/4d
0 /1/,t_., Time TY" --------
•loo
3/
Time ! c,: i S
10.01
-,
/ !
/#,-////.
Signature /-~ . .11/4,/j~
I
-------Kubal-Furr l Associate--------
Revised -2/22/02
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DATA ASSESSMENT SUMMARY CHECKLIST AND REPORT -LEVEL II
Client ID: CNA Holdings. Inc. -Shelby Prepared By: Julie A. Lisenby
Project Number: TF026DB0I Date: 1/03/03
Project Description: Routine Sampling -04/02
Sample Delivery Group (SDG) Description:
Quarterly groundwater monitoring well samples .were collected by Kubal-Furr & Associates and
analyzed by Davis & Floyd, Inc., of Greenwood, SC, fur volatiles, ethylene glycol, and TOC in
accordance with EPA/NCDENR approved methodology.
CONTENTS LEVEL COMMENTS
II
Sample Results v Nov 8 VOC data all Class B,
remaining data Class A.
Chain(s) of Custody (COCs) v Acceptable
Master Tracking List v Acceptable
Case Narrative v Acceptable
Sample Prep
Standards Prep
Instrument Quality Control Data
Batch Quality Control Report v Acceptable
Surrogate Recovery Report v Acceptable
Trip/Field/Equipment Blank Report v Acceptable
Field Notes/Logbook v Acceptable
CLP Forms
All Raw Data
Electronic Deliverables v Acceptable.
------------Kubal-Furr & Associates -----------
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CNA Holdings -Q4/02 DAS - 2 -
1/03/03
Discussion:
November 08, 2002 VOC data arc considered Class B, qualitative. Remaining data are considered
Class A, quantitative, and may be used fully without qualification.
Samples ITC!, ITEF, and ITEF-Dup collected on November 08, 2002 were tested for
preservation compliance and the pH of the samples was determined to be above the preservation
requirement of pH 2 at pH 4. At pH 4, the samples are technically classified as "unpreserved.,, The
hold time limit for unpreserved VOC samples is 7 days. Since the VOC analyses had occurred after the
adjusted hold time, the samples were collected again on December 05, 2002. The November 08 data
was qualified due to failing hold time limits. Analytes reported as not detected are flagged "UJ,, and
positive detections are flagged "J.,,
U J= compound was not detected above the associated value, however results should be considered
as estimated
J = positively identified, however, concentration should be considered as estimated.
Class A = quantitative Class B = qualitative Class C = unusable
--------------Knhal-Fnrr & Asso.-iafl>.s
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JAN Z C: 2003 DL\VIS
FLbYD LABORATORY ANALYSISJRERORT _ :,,
December 13, 2002
PEM CARTER
TICONA,LLC
2525 BLACKSBURG ROAD
HWY. 198
SHELBY, NC 28152
Login Number
Project Number
Description
Dear Pem Carter:
:L02111105
:61195.02
:GROUNDWATER
();?,It) ~-F.f.:. · I ';;t lJ/----
We are pleased to provide the enclosed analytical results for the samples received by
Davis & Floyd, Inc. on November 08, 2002.
A formal Quality Assurance/Quality Control program is maintained by Davis & Floyd,
which is designed to meet or exceed the EPA, NELAC or other appropriate regulatory
requirements. All analytical analyses for this project met QA/QC criteria and the
results are within the 99 % confidence interval for each method unless otherwise
stated in the footnotes. This report is to be reproduced only in full.
Feel free to contact our Client Services Representative at [phone] if further
explanation of the analysis is required. Unless other arrangements have been made,
samples will be disposed of or returned 14 days from the cfate of the report. We
appreciate the opportunity to provide services to your firm. .
Sincerely,
DAVIS & FLOYD, I C.
J H. McCord, J .
aboratory Manage
Davis S. Floyd, Inc. I PO Drawer 428 \ Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] I Fax [phone]
1
DAYIS
FLtJ\7D LABORATORY ANALYSIS REPORT
NELA C Certification Number: £87633 NC Certification Number: 25
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY. 198
SHELBY, NC 28152
PEM CARTER
Client ID: ITC!
Matrix
Parameter
Gas Chromatography
SW846 8015
ETHYLENE GLYCOL
Subcontract Work
SW846 8260B
1,1,1,2-TETRACHLOROETHANE
1,1,1-TRlCHLOROETHANE
1,1,2,2-TETRACHLOROETHANE
1,1,2-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
1,2-DICHLOROETHANE
1,2-DICHLOROPROPANE
2-BUTANONE
2-HEXANONE
4-METHYL-2-PENTANONE
ACETONE
BENZENE
BROMODICHLOROMETHANE
BROMOFORM
BROMOMETHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROETHANE
CHLOROFORM
CHLOROMETHANE
CIS~l,2-DICHLOROETHENE
CIS-1,3-DICHLOROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1, 2-DICHLOROETHENE
TRANS-1,3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL)
GW/Chemw
Result
1610
< 0 .0010
< o. 0010
< 0 .0010
< o. 0010
< 0. 0010
< 0. 0010
0 .0010
< 0 .0010
0.0)2
< 0 . 0050
< 0 .0050
0.098
0 .034
< 0 . 0010
.0010
< 0. 0010
0.0055
< 0.0010
0.016
< 0 .0010
< o. 0010
< 0 .0010
0.0016
< 0. 0010
< 0. 0010
< 0 .0010
0. 0010
< 0 . 0010
< o. 0010
0.0014
< 0 .0010
< o. 0010
< 0 .0010
< o. 0010
< 0. 0010
0.0025
D;ivis $,. Floyd, lnc. I PO Drawer 428 I Greenwood, SC 29648 j 816 E. Durst Avenue
2
Project Number: 61195.02
Reporc Date
Page 1 of 2
Sample ID
December 13, 2002
Report ID: AA35887
L02111105-0l
Date Collected: 08-NOV-02 09:20
Date Received 08-NOV-02
Qual RDL Units Analyst Date Time
100 mg/1 MGB 11/12/02 1409
0 .0010 mg/1 LBW 11/20/02 1428
0. 0010 mg/1 LBW 11/20/02 1428
0 .0010 mg/1 LBW 11/20/02 1428
0 .0010 mg/1 LBW 11/20/02 1428
0 . 0010 mg/1 LBW 11/20/02 1428
0 . 0010 mg/1 LBW 11/20/02 1428
0 .0010 mg/1 LBW 11/20/02 1428
0 .0010 mg/1 LBW 11/20/02 14 28
0 .0050 mg/1 LBW 11/20/02 1428
0 . 0050 mg/1 LBW 11/20/02 1428
0 .0050 mg/1 LBW ll/20/02 1428
0.050 mg/1 LBW 11/20/02 1428
0 .0010 mg/1 LBW 11/20/02 1428
0 . 0010 mg/1 LBW 11/20/02 14 28
o. 0010 mg/1 LBW 11/20/02 1428
0 .0010 mg/1 LBW 11/20/02 1428
0 .0010 mg/1 LBW 11/20/02 1428
0. 0010 mg/1 LBW 11/20/02 1428
0 .0010 mg/1 LBW 11/20/02 142 B
o. 0010 mg/1 LBW 11/20/02 1428
0 . 0010 mg/1 LBW 11/20/02 142B
0 . 0010 mg/1 LBW 11/20/02 14 2 8
0 .0010 mg/1 LBW 11/20/02 1428
0 .0010 mg/1 LBW 11/20/02 1428
0 . 0010 mg/1 LBW 11/20/02 1428
0 . 0010 mg/1 LBW 11/20/02 1428
0. 0010 mg/1 LBW 11/20/02 1428
0 .0010 mg/1 LBW 11/20/02 1428
o. 0010 mg/1 LBW 11/20/02 1428
0 .0010 mg/1 LBW 11/20/02 1428
0 .0010 mg/1 LBW 11/20/02 1428
0 . 0010 mg/1 LBW 11/20/02 1428
0 . 0010 mg/1 LBW 11/20/02 1428
0 .0010 mg/1 LBW 11/20/02 1428
0. 0010 mg/1 LBW 11/20/02 1428
0 .0020 mg/1 LBW 11/20/02 1428
Greenwoocl, SC 29649 I 18641 229-4413 I Fax [phone]
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D1\VIS
FLo'YD LABORATORY ANALYSIS REPORT
NELAC Certification Number: £87633
Parameter
Wet Chemistry
SW846 9060
Client
Contact
TICONA,LLC
2525 BLACKSO~~G ROAD
HWY. 198
SHELBY, NC 23152
PEr-: CA~TER
Client ID: ITCI
Result
NC Cenijication Number: 25
Project Number: 61195.02
Report Date
Page 2 of 2
December 13, 2002
Report ID: AA35887
Sample ID L02111105-01
Qual RDL Units Analyst Date Time
ORGANIC CARBON, TOTAL 2380 100 mg/1 CLB 11/25/02 1240
Sample Collllllents: 8260 VOA
The subcontracted analyses were performed by Rogers & Callcott, Greenville, SC
SCDHEC Certificat:on Nu~er 23105.
Due to instrument dow~ci~e the samples were ?Ubcontracted to meet the 14 day hold
time.
The results fo:-c::e ccrr.p::::unds flagged with an (*} should be considered as estimated.
See attached clie~t noc::ication form.
Davis & Floyd, Jnc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I [phone] ! Fax [phone]
3
DAYIS
FLtiYD LABORATORY ANALYSIS REPORT
NELAC Cenification Number: £87633
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY. 198
SHELBY, NC 28152
PEM CARTER
Client ID: ITEF
Matrix
Parameter
Gas Chromatography
SW846 8015
ETHYLENE: GLYCOL
Subcontract Work
SW846 8260B
1, 1, 1,2-TETRACHLOROETHANE
1, 1,1-TRICHLOROETHANE
1, 1,2,2-TETRACHLOROETHANE
1, 1,2-TRICHLOROETHANE
1, 1 -DICHLOROETHANE
1,1-DICHLOROETHENE
l, 2-DICHLOROETHANE
1,2-DICHLOROPROPANE
2-BUTANONE
2-HEXANONE
4-METHYL-2-PENTANONE
ACETONE
BENZENE
BROMODICHLOROMETHANE
BROMOF'ORM
BROMOMETHANE
CARBON DISULF'IDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROETHANE
CHLOROF'ORM
CHLOROMETHANE
CIS-1,2-DICHLOROETHENE
CIS-1,3-DICHLOROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METH'fLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-DICHLOROETHENE
TRANS-1,3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL)
GW/ChemW
Result
5.0
0 .0010
0 .0010
0 .0010
0 .0010
0 .0010
0 .0010
0 . 0010
o. 0010
0 .0050
0 .0050
o. 0050
0.050
0. 0010
0 . 0010
0 .0010
0 .0010
0 .0010
0 .0010
0 . 0010
0 . 0010
0 . 0010
0 . 0010
0. 0010
0. 0010
0 . 0010
0 . 0010
0. 0010
0 .0010
0 . 0010
0 .0010
0 .0010
0 .0010
0 . 0010
0. 0010
0 .0010
0 .0010
NC Certification Number: 25
Project Number: 61195.02
Report Date December 13' 2002
Page 1 of 2 Report· ID: AA35886
Sample ID 102111105-02
Date Collected: 08-NOV-02 09: JO
Date Received 08-NOV-02
Qual RDL Units Analyst Date Time
5,0 MGB 11/12/02 1157
0 .0010 mg/1 LBW 11/20/02 1504
Q, 0010 mg/1 LBW 11/20/02 l 504
0 .0016 mg/1 LBW 11/20/02 1504
0 .0010 mg/1 LBW 11/20/02 1504
0 .0010 mg/1 LBW 11/20/02 1504
0 .0010 mg/1 LBW 11/20/02 1504
o . 0010 mg/1 LBW 11/20/02 1504
0 . 0010 mg/1 LBW 11/20/02 1504
0 .0050 mg/1 LBW 11/20/02 1504
0 . 0050 mg/1 LBW 11/20/02 1504
0' 0050 mg/1 LBW 11/20/02 1504
0.050 mg/1 LBW 11/20/02 1504
0 . 0010 mg/1 LBW 11/20/02 1504
0' 0010 mg/1 LBW 11/20/02 1504
0. 0010 mg/1 LBW 11/20/02 1504
0 .0010 mg/1 LBW 11/20/02 1504
0 . 0010 mg/1 LBW 11/20/02 1504
0 .0010 mg/1 LBW 11/20/02 1504
0.0010 mg/1 LBW 11/20/02 1504
0 .0010 mg/1 LBW 11/20/02 1504
0 .0010 mg/1 LBW 11/20/02 1504
0 .0010 mg/1 LBW 11/20/02 1504
0 .0010 mg/1 LBW 11/20/02 1504
0 .0010 mg/1 LBW 11/20/02 1504
0 .0010 mg/1 LBW 11/20/02 1504
0 .0010 mg/1 LBW 11/20/02 1504
0 .0010 mg/1 LBW 11/20/02 1501
0 . 0010 mg/1 LBW 11/20/02 1504
0. 0010 mg/1 LBW 11/20/02 1504
0 .0010 mg/1 LBW 11/20/02 1504
0 .0010 mg/1 LBW 11/20/02 1504
0, 0010 mg/1 LBW 11/20/02 1504.
o . 0010 mg/1 LBW 11/20/02 1504
0, 0010 mg/1 LBW 11/20/02 1504
0, 0010 mg/1 T,BW 11/20/02 1504
0, 0010 mg/.l LBW 11/20/02 1504
O,ivis & Floyd, Inc I PO Drawer 428 I Greenwood, SC 2%48 l 816 F.. Durst Avenue Greenwood, SC 29649 I [phone] I Fax [phone]
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DAYIS
FLlWD LABORATORY ANALYSIS REPORT
NELAC Certificarion Number: £87633
Parameter
Wet Chemistry
SW846 9060
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY. 198
SHELBY, NC 28152
PEM CARTER
Client IC:: ITEF
Result
NC Certification Number: 25
Project Number: 61195.:2
Report Date
Page 2 of 2
Decembe?: :3, 2002
Report =~= AA.35888
Sample ID L021li:Q~-:2
Qual RPL Units Analyst Date Time
ORGANIC CARBO~, TOTAL 251 2.0 mg/1 CLB 11/25/02 1315
Sample Co=ents: 8260 VOA
The subcontracted analyses were performed by Rogers & Callcott, Greenville, SC
SCDHEC Certification Number 23105.
Due to instrument downtime the samples were subcontracted to meet the 14 day hold
time.
The results for the compounds flagged with an (*) should be considered as es~:~ated.
See attached client notification form.
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 .1 [phone] I Fax [phone]
5
I
D~S FL D LABORATORY ANALYSIS REPORT I
NELA C Certification Number: £87633 NC Certification Number: 25 I
Client TICONA,LLC Project Number: 61195.02 I 2 52 5 BLACKSBURG ROAD
HWY. 198
SHELBY, NC 28152 Report Date December 13, 2002 I Contact PEM CARTER Page 1 of 2 Report ID: AA35889
Client ID: ITEf' DUP. Sample ID L02111105 03
Date Collected: 08-NOV-02 09: 30 I Matrix GW/ChemW Date Received 08-NQV-02
Parameter Result Qual RDL Units Analyst Date Time I Gas Chromatography
SW84 6 8015
ETHYLENE GLYCOL 5.0 5,0 mg/1 MGB 11/12/02 1223 I
Subcontract Work
SW846 8260B
1,1,1,2-TETRACHLOROETIWJE ' 0 .0010 0 .0010 mg/1 LBW 11/20/02 1539 I 1, 1, !-TRICHLOROETHANE 0 .0010 o. 0010 rng/1 LBW 11/20/02 1539
1,1,2,2-TETRACHLOROETHANE ' 0 .0010 0 .0010 mg/1 LBW 11/20/02 1539
1,1,2-TRICHLOROETHAN'E ' 0 .0010 0 .0010 mg/1 LBW 11/20/02 1539 I 1,1-DICHLOROETHANE ' 0 0010 0 . 0010 mg/1 LBW 11/20/02 1539
1, 1-DICHLOROETHENE ' 0 . 0010 0 .0010 mg/1 LBW 11/20/02 1539
1,1-DICHLOROPROPENE ' 0 .0010 0 .0010 mg/1 LBW 11/20/02 1539
I 1,2-DICHLOROETHANE 0 . 0010 0 .0010 mg/1 LBW 11/20/02 1539 I 1,2-DICHLOROPROPANE ' 0 . 0010 0' 0010 mg/1 LBW 11/20/02 1539
2,2-DICHLOROPROPANE ' o. 0010 0. 0010 mg/1 LBW 11/20/02 1539
2-BUTANONE ' o. 0050 0 .0050 mg/1 LBW 11/20/02 153 9
2-HEXANONE ' 0 .0050 0 .0050 mg/1 LBW 11/20/02 1539 I 4-METHYL-2-PENTANONE ' 0 .0050 0 .0050 mg/1 LBW 11/20/02 1539
ACETONE ' 0.050 0. 050 mg/1 LBW 11/20/02 1539
BENZENE ' 0 .0010 0 . 0010 mg/1 LBW 11/20/02 1539 I BROMOOICHLOROMETHANE ' 0 . 0010 0 . 0010 mg/1 LBW 11/20/02 1539
BROMOFORM ' 0 .0010 0 .0010 mg/1 LBW 11/20/02 1539
BROMOMETHANE ' 0 . 0010 0 . 0010 mg/1 LBW 11/20/02 1539
CARBON DISULFIDE ' 0 . 0010 0 .0010 mg/1 LBW 11/20/02 1539 I CARBON TETRACHLORIDE ' 0 .0010 o. 0010 mg/1 LBW 11/20/02 1539
I
CHLOROBENZENE ' 0 . 0010 0 .0010 mg/1 LBW 11/20/02 1539
CHLOROETHANE ' 0. 0010 0 .0010 mg/1 LBW 11/20/02 1539
CHLOROFORM ' 0 .0010 0 .0010 mg/1 LBW 11/20/02 1539 I I CHLOROMETHANE ' o. 0010 o. 0010 mg/1 LBW 11/20/02 1539
CIS-1,2-DICHLOROETHENE ' 0 .0010 0 .0010 mg/1 LBW 11/20/02 1539
CIS-1,3-DICHLOROPROPENE ' 0 . 0010 0' 0010 mg/1 LBW 11/20/02 1539 I I
DIBROMOCHLOROMETHANE ' o. 0010 0 .0010 mg/1 LBW 11/20/02 1539 I
ETHYLBENZENE 0 .0010 0. 0010 mg/1 LBW 11/20/02 1539
I METHYLENE CHLORIDE ' o. 0010 0 .. 0010 mg/1 LBW 11/20/02 1539
STYRENE ' 0 .0010 o. 0010 mg/1 LBW 11/20/02 1539 I TETRACHLOROETHENE ' 0 . 0010 o . 0010 mg/1 LBW 11/20/02 1539
TOLUENE ' 0 .0010 0. 0010 mg/1 LBW 11/20/02 1539
TRANS-I, 2 -DICHLOROETHENE 0 .0010 0 .0010 mg/1 LBW 11/20/02 153 9
TRANS-1,3-DICHLOROPROPENE ' 0. 0010 0. 0010 mg/1 LBW 11/20/02 1539 I TRICHLOROETHENE 0, 0010 0' 0010 mg/ l LBW 11/20/02 153 9
VINYL ACETATE 0 .0010 o. 0010 mg/1 LBW 11/20/02 1539
0,1vis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I 18641 229-4413 I Fax [phone] I 6
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D1\VIS
FLMD LABORATORY ANALYSIS REPORT
NELAC Cenification Number: £87633 NC Certification Number: 25
Parameter
VINYL CHLORIDE
XYLENE (TOTAL)
Wet Chemistry
SW846 9060
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY. 198
SHELBY, NC 28152
PEM CARTER
Client ,u, ITEF DUP.
Result
0.0010
0.0010
Project Number, 61195.02
Report Date
Page 2 of 2
December 13, 2002
Report ID: AA35889
Sample ID L02111105-03
Qual RDL Units Analyst Date Time
0.0010
0.0010
nig/1
mg/1
LBW 11/20/02 1539
LBW 11/20/02 1539
ORGANIC CARBON, TOTAL 246 2.0 mg/1 CLB 11/25/02 1348
Sample Comments; 8260 VOA
The subcontracted analyses were performed by Rogers & Callcott, Greenville, SC
SCDHEC Certification Number 23105.
Due to instrument downtime the samples were subcontracted to meet the 14 day hold
time.
The results for the compounds flagged with an (*) should be considered as estimated.
see attached ·client notification form.
0t1vis & Floyd, lnc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 2~1(149 I W64) 229-4413 I Fax [phone] '.l
7
Di\YIS
FLMD LABORATORY ANALYSIS REPORT
NELA C Certifica1io11 Number: £87633
Client
co:-.::aC':
TICONA,LLC
2525 BLACKSBURG ROAD
HWY. 198
SHELBY, NC
PEM CARTER
28152
Client ID: K-28
Parameter
Wet Chemistry
SW8~6 9060
Mat:t•ix
ORGANIC CARBON, TOTAL
GW/ChemW
NC Certijicarion Number: 25
Project Number: 61195.02
Report Date December 13' 2002
Page 1 of 1 Report ID, AAJ5891
Sample ID L0211 E O 5-04
Date Collected: 08-NOV-,n 10 : 45
Date Received 08-NOV-02
Result Qual RDL Units Analyst Date Time
1450 10.0 mg/1 CLB 11/25/02 1454
Davi!> & rloyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649_ I (864) 229-441 J I Fax [phone]
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DJ\¥1S
FLOYD LABORATORY ANALYSIS REPORT
NELAC Cenijication Number: £87633
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY. 198
SHELBY, NC 28152
PEM CARTER
Client !D: V-23
Parameter
Wet Chemistry
Sk'846 9060
Matrix
ORGANIC CARBON, TOTAL
GW/ChemW
NC Certification Number: 25
Project Number: 61195.02
Report Date December 13, 2002
Page 1 of Report ID: AA35890
Sample ID L02111105-05
Date Collected: 08-NOV-02 12 :08
Date Received 08-NOV-02
Result Qual RDL Units Analyst Date Time
71. l 1 . 0 mg/1 CLB 11/25/02 1525
Davis&. Floyd, Inc. j PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwoud, SC 29649 I (864} 229-4413 ! Fax {864) 229-7119
9
DAYIS
FLO'YD LABORATORY ANALYSIS REPORT
NELAC Certification N11111ber: £87633
Client
contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY. 198
SHELBY, NC 26152
PEM CARTER
Client ID: TRIP BLANK
Parameter
Subcontract Work
SW846 8260B
Matrix
1, 1,1,2-TETRACHLOROETHANE
1, 1,1-TRICHLOROETHANE
l, 1,2,2-TETRACHLOROETHANE
1,1,2-TRICHLOROETHANE
l , 1-DI CHLOROETHANE
1,1-0ICHLOROETHENE
1,2-DICHLOROETHANE
1, 2 -DICHLOROPROPANE
2-BUTANONE
2-HEXANONE
4-METHYL-2-PENTANONE
ACETONE
BENZENE
BROMODICHLOROMETHANE
BROMOFORM
BROMOMETHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-DICHLOROETHENE
CIS-1,3-DICHLOROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-DICHLOROETHENE
TRANS-1,3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL)
GW/Chemw
Result
o. 0010
0 .0010
0. 0010
0. 0010
0 .0010
0. 0010
.0010
0. 0010
0 .0050
0 0050
0 .0050
0.050
0. 0010
0 . 0010
o. 0010
0 . 0010
0. 0010
0. 0010
0 .0010
0 . 0010
0 . 0010
0 . 0010
0 .0010
0 .0010
0 .0010
0 .0010
0 . 0010
o. 0010
0 .0010
0 . 0010
o. 0010
0 .0010
o. 0010
0 .0010
0 .0010
0 . 0010
NC Certification N11111ber: 25
Project Number: 61195.02
Report Date
Page 1 of 2
Sample ID
December 13, 2002
Report ID: AA.35892
L02111!05-06
Date Collected: 29-0CT-02 00:00
Date Received 08-NOV-02
Qual RDL Units Analyst Date
0 .0010 mg/1 LBW 11/20/02
0 .0010 mg/1 LBW 11/20/02
0 . 0010 mg/1 LBW 11/20/02
0 . 0010 mg/1 LBW 11/20/02
0 . 0010 mg/1 LBW 11/20/02
o. 0010 mg/1 LBW 11/20/02
0 .0010 mg/1 LBW 11/20/02
o. 0010 mg/1 LBW 11/20/02
0 .0050 mg/1 LBW 11/20/02
0. 0050 mg/1 LBW 11/20/02
0. 0050 mg/1 LBW 11/20/02
0.050 mg/1 LBW 11/20/02
0 . 0010 mg/1 LBW 11/20/02
0 . 0010 mg/1 LBW 11/20/02
0 .0010 mg/1 LBW 11/20/02
0 . 0010 mg/1 LBW 11/20/02
o. 0010 mg/1 LBW 11/20/02
0 .0010 mg/1 LBW 11/20/02
0 .0010 mg/1 LBW 11/20/02
0 .0010 mg/1 LBW 11/20/02
0 . 0010 mg/1 LBW 11/20/02
o . 0010 mg/1 LBW 11/20/02
0 .0010 mg/1 LBW 11/20/02
0 .0010 mg/1 LBW 11/20/02
0 .0010 mg/1 LBW 11/20/02
0 .0010 mg/1 LBW 11/20/02
0 . 0010 mg/1 LBW 11/20/02
0. 0010 mg/1 LBW 11/20/02
o. 0010 mg/1 LBW 11/20/02
0 .0010 mg/1 LBW 11/20/02
o. 0010 mg/1 LBW 11/20/02
0 .0010 mg/1 LBW 11/20/02
0 .0010 mg/1 LBW 11/20/02
0 .0010 mg/1 LBW 11/20/02
0 . 0010 mg/1 LBW 11/20/02
0 .0010 mg/1 LBW 11/20/02
Time
1353
1353
1353
1353
1353
1353
1353
1353
1353
1353
1353
1353
1353
1353
1353
1353
1353
1353
1353
1353
1353
1353
1353
1353
1353
1353
1353
1353
1353
1353
1353
1353
1353
1353
1353
1353
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10
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 8 \ 6 E. Durst Avenue I Greenwood, SC 29649 I (/J641 229-4413 I Fa, [phone] I
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DAYIS
FLM:D LABORATORY ANALYSIS REPORT
NELA C Certification Number: £87633 NC Certification Number: 25
Parameter
Client
Car.tact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY. 198
SHELBY, NC 28152
PEM CARTER
Clie~t ID: TRIP BLANX
Result
ProJect Number: 61195.02
Report Date
Page 2 of 2
Sample ID
Qual RDL
December 13, 2002
Report ID: AA35892
L02111105-06
Units Analyst Date
Sample Comments: 8260 VOA
The subcontracted analyses were performed by Rogers & Callcott, Greenville, SC
SCDHEC Certification-Number 23105.
Due to instrument downtime the samples were subcontracted to meet the 14 day hold
time.
The results for the compounds flagged with an (*) should be considered as estimated.
see attached client notification form.
Time
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue \ Greenwood, SC 29649 I [phone] I Fax [phone]
11
Df\VIS
FLOYD LABORATORY ANALYSIS REPORT
NELAC Certification Number: £87633
Master Tracking List
Client TICONA,LLC
2525 BLACKSBURG ROAD
HWY. 198
SHELBY, NC 28152
Contact. PEM CARTER
Sample ID
L02111105-01
Gas Chromatography
SW846 8015
Subcontract Work
SW846 8260B
Wet Chemistry
SW846 9060
L02111105-02
Gas Chromatography
51'1846 8015
Subcontract Work
sro/846 82608
Wet Chemistry
SW846 9060
L02111105-03
Gas Chromatography
SW846 8015
Subcontract Work
SW846 8260B
Wet Chemistry
SW846 9060
L02111105-04
Wet Chemistry
SW846 9060
Client ID
ITCI
ITEF
ITEl" DUP.
K-28
NC Certification Number: 25
Project Number: 61195-~.,
Report Date
Page 1 of 2
Decembe!.· 13, 2co2
Report=~= AA35866
Date Collected Date Received
08-NOV-02 09:20 08-NOV-02
11/12/02 1409
11/20/02 1428
11/25/02 12'10
08-NOV-02 09:30
11/12/02 1157
11/20/02 1504
11/25/02 1315
08-NOV-02 09:30 08-NOV-02
11/12/02 1223
11/20/02 1539
11/25/02 1348
08-NOV-02 10:45 08-NOV-02
11/25/02 1454
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 81 b E. Durst Avenue I Gr~enwooJ, SC 29649 I W64) 229.44 7 J I Fax [phone]
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D1\VIS
FLtiYD LABORATORY ANALYSIS REPORT
NELAC Certification Number: £87633
Master Tracking List
Sample ID
L02111105-0S
Wet Chemistry
SW846 9060
L02111105-06
Client
Contact
Subcontract Work
SW846 8260B
TICONA,LLC
2525 BLACKSBURG ROAD
HWY. 198
SHELBY, NC 28152
PEM CARTER
Client ID
V-23
TRIP BLANK
NC Certification Number: 25
Project Numbe:-: 61195.02
Report Date
Page 2 of 2
Date Collected
08-NOV-02 12:08
Dece:nber 13, 2002
Report ID: AA35886
Date Received
08-NOV-02
11/25/02 1525
29-0CT-02 00:00 08-NOV-02
11/20/02 1353
Davis & Floyd, Inc. \ PO Drawer 42U I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 296-19 I (B(l4) 229-4413 j Fax [phone]
13
DAYIS
FLtfYD LABORATORY ANALYSIS REPORT
Method Conformance Summary
Client: Ticona, LLC
Login(s): L02 \ l l I 05
Criteria Volatiles
Sample Holding Time
Standards Preparation
Instrument Tuning
Instrument Calibration
Calibration Verification
Deeradation Check
Interference
Samok/Standard
Blanks Results
Method Accuracy
Method Precision
Surrogate Recovery
PDS/SD/MSA
TCLP Preoaration
Key ✓
NIA
Met Criteria Met
Not Applicable
•
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NIA
NIA
✓
✓
✓
✓
NIA
NIA
Semi
Volatiles
NIA
NIA
NIA
NIA
NIA
NIA
NIA
NIA
NIA
NIA
NIA
NIA
NIA
Metals
NIA
NIA
NIA
NIA
NIA
NIA
NIA
NIA
NIA
NIA
NIA
NIA
NIA
•
PDS =
SD =
MSA=
Method Criteria Not Met -See footnote(.,) below.
Post Digestion Spike
Serial Dilution
Method of Standard Additions
Project Number: 61995.02
Report Date: December 11, 2002
Ethylene
TOC Glvcol
✓ ✓
✓ ✓
NIA NIA
✓ ✓
✓ ✓
NIA NIA
NIA NIA
NIA ✓
NIA ✓
NIA ✓
NIA NIA
NIA NIA
NIA NIA
Footnotes: I -Volatiles were subcontracted due to instrument failure. This criterion was
unavailable for review.
The holding time for aromatic volatiles is seven days for non-preserved compounds.
These samples had pH values of approximately 4 (less than 2 required). Sample
analysis was performed on day 12.
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D«vis & Floyd. Inc. I PO D,awe, 428 I G,eenwood, SC 2%48 I Blf, r
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~ucst Avenue I G,eenwnod, SC 2%49 I 18641229-4413 I fa, 18h4122'l-7l l9 I
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DAYIS
FLtiYD LABORATORY ANALYSIS REPORT
QC Batch Report
WorkGroup WG32209
Description: TOCs
Sample ID Client ID
L02111105-0l ITC!
L02111105-02 ITEF
L02111105-03 ITEF DUP.
L02111105-04 K-2B
L02111105-05 V-23
LCS32209:l Laboratory Control Spike
LCS32209:2 Laboratory Control Spike
MB32209: Method Blank
M932209 ,2 Method Blank
MS02112108-01 :32209 Matrix Spike
MSD02112108-0l:32209 Matrix Spike Duplicate
1
Report Date December 11, 2002
Page 1 of 1 Report ID: M35701
Matrix GW/ChemW
Prep Method
Analtyical Method: SW546 9060
PREP
Date Time
ANALYTICAL
Date Time
11/25/02 124 0
11/25/02 1315
11/25/02 1348
11/25/02 14 54
11/25/02 1525
11/25/02 0930
11/26/02 1153
11/25/02 1206
11/26/02 1213
11/26/02 1021
11/26/02 112 5
Analyst
CLB
CLB
CLB
CLB
CLB
CLB
CLB
CLB
CLB
CLB
CLB
Dilution
100
2
2
10
Davis & Floyd, Inc I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Cree11wood, SC 29649 I 1864) 229-441] I Fax [phone]
15
DAYIS
FLtWD
Method Blanks
Parameter
Wot Chemistry
SW846 9060
3la:-:k
ORGANIC CAR.BOK, TOTAL
MB32209:1
LABORATORY ANALYSIS REPORT
Report Date December 11, 2 002
Page 1 of 1 Report ID: AA35696
Matr::.x GW/Chemw
WorkG!'.oup: WG32209
Cone Qual RDL Units Analyst Date Time
1.0 1 . 0 mg/1 CLB 11/25/02 1206
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Dav;s & Floyd, Inc. I PO D,awe, 428 I G,eenwood, SC 29648 I 816[
1
;mst Avenue I Gmenwoou, SC 2"64'1 I tBb4i 229-44 t 3 I fax (Bf,4} 22'1-71 t 'l I
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Di\YIS
FLOYD
Method Blanks
Parameter
Wet Chemistry
SW846 9060
Blank
ORGANIC CARBON, TOTAL
MB32209:2
LABORATORY ANALYSIS REPORT
Report Date December 11, 2 002
Page 1 of 1 Report IO: AA35698
Matrix GW/ChemW
WorkGroup: WG32209
Cone Qual RDL Units Analyst Date Time
' 1.0 1.0 CLB 11/26/02 1213
Davi~ & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 2964/l I 816 E. Durst /\venue I Greenwood, SC 29649 I [phone] I Fax [phone]
1 7
DAYIS
FLOYD LABORATORY ANALYSIS REPORT
Matrix Spikes and Duplicates
MS/MSD
P~ra•ij·J~-r
ORGANIC CARBON, TOTAL
ORGANIC CARBON, TOTAL
MS0211210B-01:J2209
MSD02112108-01:32209
Spike
kdd~ct '·
20.00
20.00
Report Date
Page 1 of 1
Matrix
December 11, 2002
Report ID: AA35697
GW/Chemw
WorkGroup: WG32209
Method SW846 9060
·_s·ampi~ :--,."• -M~/.-:· · .. C:6~~(" · ·-·co~:6_ MS ::,:_\·;~EC.
:.-·::·L'imft·s -.·
--·.:i~Ec/:--.
19.58 39.80 101 78-121
36. 10 83 10 10 78-121
NOTE: MS/MSD % recoveries are not evaluated if the sample concentration is greater than four times the spike added.
Davis & Floyd, Inc. I PO Drawer.428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 29649 I {864) 22Y-441J I Fa" (B64) 229-7119
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DAYIS
FLOYD LABORATORY ANALYSIS REPORT
Laboratory Control Standards and Duplicates
LCS
::-:··:, ~l:~~-rn~ti:~ii··,.:·· ::.:: .. ·
ORGANIC CARBON, TOTAL
LCS32209:l
Report Date
Page 1 of 1
Matrix
Decern.be~ 11, 2002
Report ID: AA35699
GW/ChemW
'dorkGro-..:;i: WG32209
Method SW846 9060
/. _-_=::_::::.-_·_·-.i.: .. ::,.·•···.·.A~.-p.d'._.:._dike/d: ... •.··' ...... -~.C:.8..: ..... \\ _LC_s ·=:/:}\:Q;~ ·,·y:;( :_:\REC·.·:·
LimitS
%REC'
90-110 10.00 9.50 95
Davi~ & Floyd, Inc. I PO Drilwer 42H I GreenwuoU, SC 29648 I B 16 E. Durst Avenue I Greenwood, SC 2%49 I (8(,4) 22'.1•441 :1 I Fax [phone] ~J
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DAYIS
FLfilD LABORATORY ANALYSIS REPORT I
Laboratory Control Standards and Duplicates
LCS LCS32209:2
Report Date
Page 1 of
ce=ember 11, 2002
Re;~rt ID: AA35700
Matrix GW/Che:7:,.;
WorkGroup: I\G322C?
Method
LCS ··
J-<::_·1ii.~C:>. ·
103
· -. ·-.· : Limits
::.~_REC
90-110
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC :29649 ) [phone]
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I fax [8641229-71191
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D;\VIS
FLOYD LABORATORY ANALYSIS REPORT
QC Batch Report
Report Date Decel:".ber 11, 2002
Page 1 of 1 Report !D, AA35694
Matrix GW/ChemW
WorkGroup WG32014 Prep ~:e::hod
Description: GC/EG Ar:a:.::yi.cal Method: S\~846 8015
PREP ANALYTICAL
Sample ID Client ID Run# Date Time Date Time Analyst Dilution
L02111105-01 ITCI 11/12/02 1409 MGB 20
L02111105-02 ITEF 11/12/02 1157 MGB
L02111105-03 ITEF DUP. 11/12/02 1223 MGB
LCS32014: 1 Laboratory Control Spike 1 11/12/02 1104 MGB
MB32014: 1 Method Blank 11/12/02 1038 MGB
MS02111105-03: 32014 Matrix Spike 1 11/12/02 1704 MGB
MSD02111105-03: 32014 Matrix Spike Duplicate 11/12/02 1731 MGB
Davis & Floyd, Inc. I PO Drawer 428 I Creenwood, SC 29648 I Bl 6 L Durst Avenue I Greenwood, SC 29649 I (H64) 2'..!:9-44 lJ I Fax [phone]
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Df\YIS
FLtfYD
Method Blanks
Blank
Parameter
Gas Chromatography
sr-.'846 so1s
ETHYLENE GLYCOL
MB32014: 1
LABORATORY ANALYSIS REPORT
Report Date December 11, 2002
Page 1 of 1 Report ID: AA35693
Matrl.): GW/ChemW
WorkGroup: WG320H
Cone Qual RDL Units Analyst Date Time
5.0 5.0 MGB 11/12/02 1038
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D<>v;s & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 2%48 I 8 I 6 E
2
~nst Avenue I Greenwood, SC 2%49 I (864) 22'1-44 U I Fax [phone] I
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D_AYIS
FLtwD LABORATORY ANALYSIS REPORT
Matrix Spikes and Duplicates
MS/MSD
~~ram_et:er,,. ,:
ETHYLENE GLYCOL
·. ?arameter.
ETHYLENE GLYCOL
MS02111105-03:32014
MSD02111105-03:32014
·sp_ik,;2
.':·:Added
50.00
so.co
--~-a~Pre·: MS
Report Date
Page 1 of 1
Matrix
December 11, 2002
Report ID: AAJS695
GW/ChemW
WorkGroup: WG32014
Method SW846 8015
'.·:,./MSi--· -·.: :-:·)).;i!JlitS ..
~o_ric :: .. ,~~ric_:: :'::):,\:\#Ee · %REC
< 5.00 59.28 119 6B-129
57.79 116 3 16 68-129
NOTE: MS/MSD \ recoveries are not evaluated if the sample concentration is greater than four times the spike added.
Davis & Floyd, Inc. I PO Drawer 42ll I Greenwood, SC 2964B I 81 (1 E. Durst Avenue I Creenwood, SC 2%49 I IH64) 22~1-44 LI I Fax (H64) 229-71 JIJ
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DAYlS
FLtJYD LABORATORY ANALYSIS REPORT
Laboratory Control Standards and Duplicates
LCS LCS32014: 1
p~·ja·~~ t~./}:.-;: <·-·:
ETHYLENE GLYCOL
spike ·· .. Ad~tj :_
50.00
LCS
C~nc.·
58. 50
Report Date
Page 1 of 1
December 11, 2002
Report ID: M35692
Matrix GW/ChemW
WorkGroup, WG32Jl4
Method swa.;o so1s
LC~\. ·: i:..iffiii:s
%REC ·\, . ...:: :\;\Ri:C_::·
)17 74-119
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D.,vis & Floyd, Inc. I PO Dcawe, 428 I Gceenwo0<I, SC 29648 I 816 E
2
~ucst Avenue I G,eenwood, SC 29649 I 1864) 229-44 U I fax [phone] I
---------------Chain of Custody Record
Client Project I Site Location 816 E. Durst Avenue, Greenwood, SC 29649 {864) 229-4413 Fax: [phone]
TJcona 61195.02 Laboratory Certifcation Numbers: SC-24110, NC-25, TN-2923, VA-77
Shelby,NC
Contact J'"vL, c, l.l✓eve,.y Report To Copy To Reporting Requirements: { J Standard { J Data Package (Specify Level)
~--,;',qi,{ C = 7i::?Z -:i-..,,.., {;'-c_,f &,.I,~ Ir ~a -re...
y ' Requirad Parameters, Containers and Preservatives
C-;i',::·Z-t:,,.,r,'t/t.J <!) <!) <!) <!) <!) <!)
E <!) E E E E E ~ <!) J 0 "' ~
0 0 " J "' 0 " " ~ N ~ N ~
NOTICE: ~ " .,,
~ • . C :~~ ~
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8 :;;, 0
£ § 0 iD '-' ~
'-' & 0 N '-' ~ <i • 0 ~ i 0 < .,, -. w E ';;j ·3 N • :;: E > • 0
~ a • "' C -· • V, :, >
0 D X D < 0 g~ 5 0. 0. 0.
• E E ·c E -,. '-' J J J
Sample Collection ! .§. 0 e 1ij {I_ 0 5 e > 0 8 "' "' "' '-' <!) ::;; > w V, □
Samole Descriotion Date Time Time Type Total C A .AV· A A A A A
-:r::--re I ''12/oz.. C'J9,lC' ✓ s ./ ✓ ✓
-::C-rcr '0>/4z.. o9h ✓ s ✓ ✓ /
-CTc7<=· -i)vf' 11,1~ o9h ✓ s ✓ ✓ /
f::.-;JR-'fi>/4 ~ ✓ ·) ✓-
v-,,23 li/f-/42-1)11.J-,,,.. .£' /
tfl., f $µ,J k. ,1z,,1.,, -/' ,9 ✓ ,
/7
./,~ / /
/_,,///
":t:".,,,-1) / D ~ Time il)7l1/Z/ ;( '¼ate Time Reliquished By Date Time
l'l, /'v-.S t>/.,z_. !{al&, _,, ~'l
'i?Jr/Ak, L;;:,le Time Recefed By Date Time p;f;;Lrnt~~(W ~ Date Time
18/o, f:'!05 ff. f'.()'J.-,r,, r,
,.,om ....... t:s
MalriK Type Definiuons , -Onnkmg Water 2 -Clean Water 5 -Groundwater 7 -S01VSed1menl 8 -L1qu1d Sludge 9 -011 12 -Air
PreseNative Definitions A -None 8 -H2S04 C • HCI O -HNOJ E -Na OH F • Filtered G -.1 N HCUpH 4 lo 5
--------Page I or I
ce vse vn,-,
urchase Ottler
State Quote
NC
Loam Special Instructions
a
i~ I 0 •
C " ~. .. ~
C '> ;~ • 8. '6 ~ ~ " Fraction HOT ommenus o, S'cc -WK
0)., UZX:-Z .#
0~ ,;2{;0Soh
Of/.
05
(J(p
ou;,:~ She~) y N OU CUEr.lT
~EDl:X
IIY,spe,: Airbil Numbttr
~days
----Cooler lable):
On Ice; I Temp(C) ~
Custody Seal: Intact I Broken~
Oav1s & Floyd, Inc
FL02_01 (0~'9)
\II .... II\ ROGERS&CALIDJIT • • ----=---~BOR_ATORY SER_VICES
P.O. Box 5655, Greenville, SC 29606
Phone [phone] • FAX [phone]
Client: Davis and Floyd
Attention: John McCord
816 E. Durst Avenue
Greenwood, SC 29649
Date Received: 11/19/2002
Time Received: 8:55
Date Reported: 11/25/2002
Sample Description
AN EMPLOYEE-OWNED COMPANY
Laboratory Services Report
South Carolina Laboratorylde11tificatio11 23 I 05
North Carolina Laboratory Certificate Number 27
NELAP Laboratory !dentificatio11 £87822
Tennessee Laboratory Identification 02860
Sample Number
AA73067 Davis & Floyd L02111105-01-ITCI Project 61195.02 grab , collected on 11/08/2002 at 09:20
The attached report is for the samples that were received and are referenced above. The complete report, including
this cover sheet, is to be reproduced only in full. Rogers and Calicott maintains a formal QA I QC program. Unless
othenvise noted. all analyses pe,formed under NELAP certification have complied with all the requirements of the
NE LAC standard. The analyses met the QA I QC confidence interval for each test method unless otherwise qualified.
We appreciate the opportunity to he of service lo you. Please contact us at [phone] should you have a11y
questions about this report.
R I I db ·3d( Yv:')·~{/4-, . e.rn IS re ease ~1:_:_-=----=---;-l---=--=--''----sr""°-=-'...:= '--=--
Sam W. Ave1:i', Jr., laborato,y Director
Results reviewed by: _ _,l~'·l,",l-"l..,,_· _( __
/ /125/2002 Rogers and Calicott CPU-I 0
26
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Sam(!_/e Number Samv.le Descriv.tion, Date and Time Collected
I AA73067 Davis & Floyd L02111105-01-ITCI Project 61195.02 grab, collected on 11/08/2002 at 09:20
Parameter Result Unit Flag RL Date/Time Analyst Method
I ···············································································································································································
VOA Target Analyte List
Acetone 98 ug/L 50 11/20/02 14:28 LBW EPA 82608
Benzene 34 ug/L Q 1.0 11/20/0214:28 LBW EPA 82608
I Bromodichloromethane < RDL ug/L 1.0 11/20/02 14:28 LBW EPA 82608
Bromoform < RDL ug/L 1.0 11/20/02 14:28 LBW EPA 82608
Bromomethane <RDL ug/L 1.0 11/20/0214:28 LBW EPA 82608
I 2-Butanone (MEK) 32 ug/L 1.0 11/20/0214:28 LBW EPA82608
Carbon disulfide 5.5 ug/L 1.0 11/20/02 14:28 LBW EPA82608
Carbon tetrachloride < RDL ug/L 1.0 11/20/02 14:28 LBW EPA 82606
Chlorobenzene 16 ug/L Q 1.0 11/20/0214:28 LBW EPA 82606
I Chlorodibromomethane <RDL ug/L 1.0 11/20/02 14:28 LBW EPA 82606
Chloroethane <RDL ug/L 1.0 11/20/02 14:28 LBW EPA8260B
Chloroform < RDL ug/L 1.0 11/20/02 14:28 LBW EPA 82606
I Chloromethane < RDL ug/L 1.0 11/20/02 14:28 LBW EPA 82608
1, 1-Dichloroethane <RDL ug/L 1.0 11/20/0214:28 LBW EPA8260B
1,2-Dichloroethane <RDL ug/L 1.0 11/20/02 14:28 LBW EPA8260B
I 1, 1-0ichloroethene <RDL ug/L 1.0 11/20/02 14:28 LBW EPA8260B
cis-1,2-Dichloroethene 1.6 ug/L 1.0 11/20/02 14:28 LBW EPA8260B
trans-1,2-Dichloroethene <RDL ug/L 1.0 11/20/02 14:28 LBW EPA8260B
1,2-0ichloropropane < RDL ug/L 1.0 11/20/02 14:28 LBW EPA 82608
I cis-1,3-Dichloropropene < RDL ug/L 1.0 11/20/02 14:28 LBW EPA8260B
trans-1,3-Dlchloropropene <RDL ug/L 1.0 11/20/0214:28 LBW EPA8260B
Ethylbenzene <RDL ug/L Q 1.0 11/20/0214:28 LBW EPA 82608
I 2-Hexanone < RDL ug/L 1.0 11/20/02 14:28 LBW EPA 82608
Methylene chloride < RDL ug/L 1.0 11/20/0214:28 LBW EPA 82608
4-Methyl-2-pentanone (MIBK) <RDL ug/L 1.0 11/20/02 14:28 LBW EPA 82608
I Styrene <RDL ug/L 1.0 11/20/02 14:28 LBW EPA8260B
1, 1,2,2-Tetrachloroethane <RDL ug/L 1.0 11/20/02 14:28 LBW EPA 82608
Tetrachloroethene <RDL ug/L 1.0 11/20/0214:28 LBW EPA8260B
Toluene 1.4 ug/L Q 1.0 11/20/0214:28 LBW EPA8260B
I 1, 1, 1-Trichloroethane < RDL ug/L 1.0 11/20/02 14:28 LBW EPA8260B
1, 1,2-Trichloroethane < RDL ug/L 1.0 11/20/02 14:28 LBW EPA8260B
Trichtoroethene <RDL ug/L 1.0 11/20/02 14:28 LBW EPA8260B
I Vinyl chloride <RDL ug/L 1.0 11/20/02 14:28 LBW EPA8260B
m/p-Xylene 2.5 ug/L Q 2.0 11/20/02 14:28 LBW EPA82608
o-Xylene <RDL ug/L Q 1.0 11/20/02 14:28 LBW EPA8260B
I 1,2-Dichloroelhane-D4 (surrogate) 96 %-0 11/20/02 14:28 LBW EPA8260B
Toluene-DB (surrogate) 101 %-0 11/20/02 14:28 LBW EPA82608
4-Bromofluorobenzene (surrogate) 118 %-0 11/20/02 14:28 LBW EPA 82606
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I ~, ·~,_.,,, .. ,_.., .. + .• , .. ,,.+,----~-'"'··, -,; .. .._...,:;,;..,..,. __ ,..,,,.,,.,.. .... ,,..u..:..,."',,.:,. .. 1>1-"l~"""''.t."""-..,,....,,.~r--,..~•..r,--•,,-,m._.,,.,_,,,,,.,.Jc.-.. -..;.,,...,.,1..,.,,,,.,,, ... ,,,....,._ .. ,~~ .... -··
//125/2002 Rogers and Calicott CPU-! 0 Page 2 o/2
I 27
11■11 RoGERS&Cmm ~~ ® -~;:._AB_OR_AT_OR_Y S_ER_vr_cE_S -
P.O. Box 5655, Greenville, SC 29606
Phone [phone] • FAX [phone]
C/iem: Davis and Floyd
Attention: John McCord
816 E. Durst Avenue
Greenwood, SC 29649
Date Received: 11/19/2002
Time Recefred: 8:55
Date Reported: 11/25/2002
Sample Description
AN EM~LOYEE-OWNE0 COMPANY
Laboratory Services Report
South Carolina Laboratory lde111ification 23 I 05
North Carolina Laborat01y Certificate Number 27
NELAP Laborato1y hlentification £87822
Tennessee laborato,y Identification 02860
Sample Number
AA73068 Davis & Floyd L02111105-02-ITEF Project 61195.02 grab , collected on 11/08/2002 at 09:30
The attached report is/or the samples that were received and are referenced above. The complete report, including
this cover sheet, is to be reproduced only infu/1. Rogers and Calleo// maintains a formal QA I QC program. Unless
othenvise noted, all analyses pe1formed under NELAP certification have complied with all the requirements of the
NELAC standard. The analyses met the QA I QC confidence interval for each test method unless otherwise qualified.
We appreciate the opportunity to be of sen•ice to you. Please co111act us at [phone] should you have any
questions about this report.
Res11/ts released by. i dJ ~ P2--=
Sam W Avery.J.Laboratory Director
Results reviewed by: Cchl
I 1125/2002 Rogers and Cal/colt CPU-JO
28
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Sample Number Sample Description. Date and Time Collected
AA73068 Davis & Floyd L02111105-02-ITEF Project 61195.02 grab , collected on 11/08/2002 at 09:30
Parameter Result Unit Flag RL Date/Time Analyst Method
···············································································································································································
VOA Target Analyte List
Acetone < RDL
Benzene < RDL
Bromodichloromethane < RDL
Bromoform <RDL
Bromomethane <RDL
2-Butanone (MEK) <RDL
Carbon disulfide <RDL
Carbon tetrachloride < RDL
Chlorobenzene < RDL
Chlorodibromomethane < RDL
Chloroethane < RDL
Chloroform <RDL
Chloromethane <RDL
1.1-Dichloroethane <RDL
1,2-Dichloroethane < RDL
1, 1-Dichloroethene < RDL
cis-1,2-Dichloroethene < RDL
trans-1,2-Dichloroethene < RDL
1,2-Dichloropropane < RDL
cis-1,3-Dichloropropene <RDL
trans-1,3-Dichloropropene <RDL
Ethylbenzene < RDL
2-Hexanone < RDL
Methylene dlloride < RDL
4-Methyl-2-pentanone (MIBK) < RDL
Styrene < RDL
1, 1,2,2-Tetrachloroethane < RDL
T etrachloroethene < RDL
Toluene < RDL
1, 1, 1-Trichloroethane < RDL
1, 1,2-T richloroethane < RDL
Trichloroethene < RDL
Vinyl chloride <RDL
m/p-Xylene <RDL
a-Xylene <RDL
1,2-Dichloroethane-D4 (surrogate) 99
Toluene-DB (surrogate) 104
4-Bromofluorobenzene (surrogate) 108
/ 1125/2002
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%-
%-
%-
Q
Q
Q
Q
Q
Q
Rogers and Cal/coll CPU-JO
29
50
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
2.0
1.0
0
0
0
11/20/0215:04 LBW EPA 8260B
11/20/02 15:04 LBW EPA 8260B
11/20/02 15:04 LBW EPA 8260B
11/20/02 15:04 LBW EPA8260B
11/20/02 15:04 LBW EPA8260B
11/20/02 15:04 LBW EPA8260B
11/20/02 15:04 LBW EPA8260B
11/20/0215:04 LBW EPA 8260B
11/20/0215:04 LBW EPA8260B
11/20/02 15:04 LBW EPA 8260B
11/20/02 15:04 LBW EPA 8260B
11/20/02 15:04 LBW EPA 8260B
11/20/02 15:04 LBW EPA8260B
11/20/02 15:04 LBW EPA8260B
11/20/02 15:04 LBW EPA 8260B
11/20/0215:04 LBW EPA 8260B
11/20/0215:04 LBW EPA 8260B
11/20/02 15:04 LBW EPA 8260B
11/20/02 15:04 LBW EPA 8260B
11 /20/02 15:04 LBW EPA 8260B
11/20/02 15:04 LBW EPA8260B
11/20/02 15:04 LBW EPA 8260B
11/20/02 15:04 LBW EPA8260B
11/20/0215:04 LBW EPA 8260B
11/20/02 15:04 LBW EPA 8260B
11/20/02 15:04 LBW EPA8260B
11/20/0215:04 LBW EPA8260B
11/20/0215:04 LBW EPA 8260B
11 /20/02 15:04 LBW EPA8260B
11/20/02 15:04 LBW EPA8260B
11/20/02 15:04 LBW EPA 8260B
11/20/0215:04 LBW EPA8260B
11/20/0215:04 LBW EPA 8260B
11/20/0215:04 LBW EPA8260B
11/20/0215:04 LBW EPA8260B
11 /20/02 15:04 LBW EPA8260B
11/20/02 15:04 LBW EPA8260B
11/20/02 15:04 LBW EPA 8260B
Page 2 o/2
••
ROGERS &CALLCOTT
~BORATORY SERVICES
P.O. Box 5655, Greenville, SC 29606
Phone [phone] • FAX [phone]
Client: Davis and Floyd
Attention: John McCord
816 E. Durst Avenue
Greenwood, SC 29649
Date Received: 11/19/2002
Time Received: 8:55
Date Reported: 11/25/2002
Sample Description
AN EMPLOYEE-OWNED COMPANY
Laboratory Services Report
South Carolina laborato,y Identification 23105
North Carolina laboratory Certificate Number 27
NELAP laborato,y Identification £87822
Tennessee laborato1y Identification 02860
Sample Number
AA73069 Davis & Floyd L02111105-03-ITEF-Dup Project 61195.02 grab , collected on 11/08/2002 at 09:30
The attached report is/or the samples that were received and are referenced above. The comp/ere report, including
this cover sheet, is to be reproduced only in full. Rogers and Calicott maintains a formal QA I QC program. Unless
othenvise noted, all analyses pe,formed under NELAP certification have complied with all the requirements of the
NE LAC standard. The analyses met the QA I QC confidence interval for each test method unless otherwise qualified.
We appreciate the opportunity to be of service to you. Please contact us at [phone] should you have any
questions about this report.
Results released by: __ --g __ c:;t,,(_-___ 6d-~'-------'~"------Results reviewed by: _ _,__(l.,_J/4_". '---
Sam W A,,e,y, Jr., laboratory Director
I !/2512002 Rogers and Calicott CPU-JO
30
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Sample N11mber Sample Description. Date and Time Collected
AA73069 Davis & Floyd L02111105-03-ITEF-Dup Project 61195.02 grab, collected on 11/08/2002 at 09:30
Parameter Result Unit Flag RL Datelfime Analyst Method
··•··•··································································•·•·······························································································--···
VOA Target Analyte List
Acetone
Benzene
Bromodichloromethane
Bromoform
Brornomethane
2-Bulanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chlorodibromomethane
Chloroethane
Chloroform
Chloromethane
1, 1-Dichloroethane
1,2-0ichloroethane
1, 1-Dichloroelhene
cis-1,2-Dichloroethene
trans-1,2-0ichloroethene
1,2-0ichloropropane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethyl benzene
2-Hexanone
Methylene chloride
4-Melhyl-2-pentanone (MIBK)
Styrene
1, 1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1, 1, 1-Trichloroethane
1, 1,2-Trichloroethane
T richloroethene
Vinyl chloride
m/p-Xylene
o-Xylene
1,2-Dichloroelhane-D4 (surrogate)
Toluene-D8 (surrogate)
4-Bromofluorobenzene (surrogate)
I l/2512002
<RDL
< RDL
< RDL
<RDL
< RDL
< RDL
<RDL
< RDL
< RDL
< RDL
<RDL
< RDL
< RDL
< RDL
<RDL
<RDL
< RDL
< RDL
< RDL
<RDL
<RDL
<RDL
<RDL
< RDL
< RDL
< RDL
<RDL
<RDL
< RDL
< RDL
< RDL
<RDL
<RDL
< RDL
< RDL
97
104
105
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
%-
%-
%-
Q
Q
Q
Q
Q
Q
Rogers and Calicott CPU-JO
31
50 11/20/0215:39 LBW EPA 82608
1.0 11/20/02 15:39 LBW EPA82608
1.0 11/20/02 15:39 LBW EPA 82608
1.0 11/20/0215:39 LBW EPA 82608
1.0 11/20/02 15:39 LBW EPA 82608
1.0 11/20/0215:39 LBW EPA 82608
1.0 11/20/02 15:39 LBW EPA 82608
1.0 11/20/02 15:39 LBW EPA 82608
1.0 11/20/0215:39 LBW EPA 82608
1.0 11/20/0215:39 LBW EPA 82608
1.0 11/20/02 15:39 LBW EPA 82608
1.0 11/20/02 15:39 LBW EPA 82608
1.0 11/20/02 15:39 LBW EPA82608
1.0 11/20/0215:39 LBW EPA82608
1.0 11/20/02 15:39 LBW EPA82608
1.0 11/20/02 15:39 LBW EPA 82608
1.0 11/20/0215:39 LBW EPA 82608
1.0 11/20/0215:39 LBW EPA8260B
1.0 11/20/0215:39 LBW EPA8260B
1.0 11/20/0215:39 LBW EPA8260B
1.0 11/20/02 15:39 LBW EPA 82608
1.0 11/20/02 15:39 LBW EPA 82608
1.0 11/20/0215:39 LBW EPA82608
1.0 11/20/0215:39 LBW EPA82608
1.0 11/20/02 15:39 LBW EPA82608
1.0 11 /20/02 15:39 LBW EPA82608
1.0 11/20/02 15:39 LBW EPA82608
1.0 11/20/02 15:39 LBW EPA82608
1.0 11/20/0215:39 LBW EPA82608
1.0 11/20/02 15:39 LBW EPA 82608
1.0 11/20/02 15:39 LBW EPA82608
1.0 11/20/02 15:39 LBW EPA8260B
1.0 11/20/02 15:39 LBW EPA8260B
2.0 11/20/02 15:39 LBW EPA 82608
1.0 11/20/0215:39 LBW EPA 82608
0 11/20/02 15:39 LBW EPA8260B
0 11/20/02 15:39 LBW EPA82608
0 11/20/02 15:39 LBW EPA 82608
Page 2 ~(2
11■11 ROGERS&Cill=TI ~ ~BORATORY SERVICES
~.,®.____c,__--~ P.O. Box 5655. Greenville. SC 29606
Phone [phone] • FAX [phone]
Client: Davis and Floyd
Attention: John McCord
816 E. Durst Avenue
Greenwood, SC 29649
Date Received: 11/19/2002
Time Received: 8:55
Date Reported: 11/25/2002
Sample Number Sample Description
AN EMPLOYEE-OWNED COMPANY
Laboratory Services Report
South Carolina laborat01y lde11tification 23105
North Carolina laboratory Certificate Number 27
NELAP lahorat01y Identification £87822
Tennessee laboratory Jdentificatio11 02860
AA73070 Davis & Floyd L02111105-06-TB Project 61195.02 grab , collected on 11/08/2002 at 00:00
The attached report is/or the samples that were received and are referenced above. The complete report, including
this cover sheet, is to be reproduced only in ji,11. Rogers 11nd C11/lcott maintains a formal QA I QC program. Unless
othenvise noted, 111/ 1111alyses pe1formed under NElAP certification have complied with all the requirements of the
NE LAC standard. The analyses met the QA I QC confidence i11terval for e11ch test method unless othenvise qualified. . .
We appreciate the opportun;1y to be of service to you. Please contact us at [phone] should you have any
questions about this report.
Results released by: __ -g_d,{_· ___ ~-~'------'---~V------Results reviewed by: __ (,._'f_'-"cli:=',_l __
Sam W. Avery, Jr., laboratory Director
I /12512002 Rogers and Cal/corr CPU-JO
32
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Sample Number Sample Description, Date and Time Collected
AA73070 Davis & Floyd L02111105-06-TB Project 61195.02 grab, collected on 11/08/2002 at 00:00
Parameter Result U11it Flag RL Date/Time A11alyst Method
···············································································································································································
VOA Target Analyte List
Acetone < RDL ug/L 50 11/20/02 13:53 LBW EPA8260B
Benzene <RDL ug/L 1.0 11/20/02 13:53 LBW EPA8260B
Bromodichloromethane < RDL ug/L 1.0 11/20/02 13:53 LBW EPA 8260B
Bromoform < RDL ug/L 1.0 11/20/02 13:53 LBW EPA8260B
Bromomethane < RDL ug/L 1.0 11/20/02 13:53 LBW EPA8260B
2-Butanone (MEK) <RDL ug/L 1.0 11/20/02 13:53 LBW EPA 82608
Carbon disulfide < RDL ug/L 1.0 11/20/0213:53 LBW EPA8260B
Carbon tetrachloride < RDL ug/L 1.0 11/20/0213:53 LBW EPA 8260B
Chlorobenzene < RDL ug/L 1.0 11/20/02 13:53 LBW EPA8260B
Chlorodibromomethane < RDL ug/L 1.0 11/20/02 13:53 LBW EPA 8260B
Chloroethane < RDL ug/L 1.0 11/20/02 13:53 LBW EPA 82608
Chloroform < RDL ug/L 1.0 11/20/0213:53 LBW EPA8260B
Chloromethane <RDL ug/L 1.0 11/20/0213:53 LBW EPA 8260B
1, 1-Dichloroethane <RDL ug/L 1.0 11/20/02 13:53 LBW EPA8260B
1,2-Dichloroethane <RDL ug/L 1.0 11/20/02 13:53 LBW EPA8260B
1, 1-Dichloroethene < RDL ug/L 1.0 11/20/0213:53 LBW EPA8260B
cis-1,2-Dichloroethene < RDL ug/L 1.0 11/20/02 13:53 LBW EPA8260B
trans-1,2-Dichloroethene <RDL ug/L 1.0 11 /20/02 13:53 LBW EPA8260B
1,2-Dichloropropane <RDL ug/L 1.0 11 /20/02 13:53 LBW EPA8260B
cis-1,3-Dichloropropene < RDL ug/L 1.0 11/20/02 13:53 LBW EPA8260B
trans-1,3-0ichloropropene < RDL ug/L 1.0 11/20/0213:53 LBW EPA8260B
Ethylbenzene < RDL ug/L 1.0 11/20/0213:53 LBW EPA 8260B
2-Hexanone <RDL ug/L 1.0 11/20/02 13:53 LBW EPA 8260B
Methylene dlloride <RDL ug/L 1.0 11/20/02 13:53 LBW EPA 8260B
4-Methyl-2-pentanone (MIBK) < RDL ug/L 1.0 11/20/02 13:53 LBW EPA8260B
Styrene < RDL ug/L 1.0 11/20/02 13:53 LBW EPA 8260B
1, 1,2,2-T etrachloroethane <RDL ug/L 1.0 11/20/02 13:53 LBW EPA8260B
Tetrachloroethene <RDL ug/L 1.0 11/20/02 13:53 LBW EPA8260B
Toluene <RDL ug/L 1.0 11/20/02 13:53 LBW EPA8260B
1, 1, 1-Trichloroethane < RDL ug/L 1.0 11/20/02 13:53 LBW EPA8260B
1, 1,2-Trichloroethane < RDL ug/L 1.0 11/20/02 13:53 LBW EPA8260B
Trichloroethene <RDL ug/L 1.0 11/20/02 13:53 LBW EPA8260B
Vinyl chloride <RDL ug/L 1.0 11/20/02 13:53 LBW EPA 8260B
m/p-Xylene <RDL ug/L 2.0 11/20/02 13:53 LBW EPA8260B
o--Xylene < RDL ug/L 1.0 11/20/0213:53 LBW EPA8260B
1,2-Dichloroelhane-D4 (surrogate) 92 %-0 11/20/02 13:53 LBW EPA8260B
Toluene-DB (surrogate) 105 %-0 11/20/02 13:53 LBW EPA8260B
4-Bromofluorobenzene (surrogate) 106 %-0 11/20/02 13:53 LBW EPA8260B
/ /125/2002 Rogers and Caf/cort CPU-I 0 Page 2 of2
33
Chain of Custody Record
Client 816 E. Durst Avenue, Greenwood, SC 29649 (864) 229.-4413 Fax: [phone] Project I Site Location
PageLf_
ice use ontv
. v)AJ//.:t.. ct J:;.o\/1) 61 ;q,;-; 0 2-,..---LaboratoryCertifcatianNumbers: SC-24110, NC-25, :N-2923, VA-77
Sample Collection
Samnle Descriction Date Time Time TVtJe Total r_...,. Fraction
f.11· ct/:
HOT vomments I.L 0~1n,,,.c--ol Ix Tl'.'t.'\
~ n -, II " .,.,,.,.. -0 7 1 :rn,,r;, '\
,, .,,, ,, t1~-0?J lrr,z: n., ) ..L ...
.
"' 3
13oC. 1 A-ae.
13f>fo'f: A-13.c
1:1.,,r,q r~.
"" .,,.1-------------+---+---+---'--+--l--+--l--+---l--+--f-~f--l---+--+--+--+-+-+-+--+-+------l
,,f ,
r.;omments
.;5 .-,f'E ,I/-rr If(!# .Jrl>
Ma\rt;J( Type Defimbons 1 -Dnnkmg Water 2 • Clean Water 5-Groundwater 7-S011/Sed1ment 8-Liquid Sludge 9. 01! 12-Air
Preservative Definitions A -None 8 -H2S04 C -HCI D -HN03 E -NaOH F -Filtered G -Other ------- -- --- - -
Cooler ID (if available): ::, 'I'"'
On Ice: /v::)No T ernp(C) .2_Q_ '-.-
Custody~ Intact / Broken I None
Davis & Floyd, Inc.
FL02 _01 (02199) -- -
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••
ROGERS&CALI..COTT
~BORATORY SERVICES
P.O. Box 5655, Greenville, SC 29606
Phone [phone] • FAX [phone]
AN EMPLOYEE-OWNED COMPANY
EXPLANATION OF REPORT SYMBOLS AND ABBREVIATIONS
The following defines common symbols and abbreviations used in reporting technical data:
<
>
mg/L, mg/kg
µg/L,µg/kg
RDL
CFU
TNTC
BTU
MSL
NTU
µmhos/cm
oc, op
mgd, gpd
Surrogate
Data Qualifiers:
Q
K
B
X
z
E
s
D
T
p
Less than
Greater than
Units of concentration in milligrams per liter for liquids, and milligrams per kilogram for
solids. Also referred to as parts per million or "ppm".
Units of concentration in micrograms per liter for liquids, and micrograms per kilogram
for solids. Also referred to as parts per billion or 11ppb11
•
Reported detection limit
Colony forming unit
Too numerous to count
British thermal units
Mean sea level
Nephelometric turbidity units
Units of specific conductance expressed in micromhos per centimeter
Units of temperature expressed in degrees Celsius or degrees Fahrenheit.
Measure of flow in million gallons per day (mgd) or gallons per day (gpd).
Compound added by the laboratory for quality control monitoring.
Estimated value
Sample was qualified due to deficiencies that could affect the data. Refer to client
notification form or report comments for explanation.
The sample was analyzed beyond the accepted holding time.
Analyte was also detected in the method blank.
Matrix interference which requires dilution or prevents the reporting of a result. Reported
detection limit has been adjusted where applicable.
Defined in comments. If there are multiple comments, the 11Z11 may be followed by a
number designation.
The analyte was detected at concentrations greater than the calibration range.
Spiked sample recovery was not within control limits.
Dilution of the sample caused the concentration of the compound of interest, to be less
than the reported detection limit.
Result is less than the reported detection limit. It is provided for information purposes
only and not for statis_tical analysis.
Duplicate analysis was not within control limits.
LIMITATION OF LIABILITY -The accuracy of all analytical results is for the sample as is received by the
laboratciry. The integrity of the sample begins at the time it is placed in the pos'session of authorized Rogers and
Calicott Engineers, Inc. laboratory personnel. All warranties, expressed, or implied, are disclaimed. Liability is
limited to the cost of the analyses.
SAMPLE RETURN POLICY -Rogers and Calicott Engineers, Inc. re;erves the right to charge a sample disposal fee
or to return samples to the client.
Revised August 2002 35
CLIENT:
Dear Client:
Pl~ase note thai the North Carolina Departme~t ofEnvirorhnent, Health and Naturill Resources (NC DEHNR)
requires that all samples taken for any compliance monitoring be collected, preserved, documented and
analyzed properly. ;\ny deficiencies could mean that the data from affected samples could be rejected.
I
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~\
...
Ii. ..
. •,, I·_· .
!}
I :_' :.~
.u\_
1'1_·-•· ..
" . ,,.
I._,,. .··.
,,,.
1.-.;.,
f::_
:.::-, 1:
I \
\\: , .• ,:.
Data File: C:\tp\target\data\1120\LCS1120.d
Report Date: 20-Nov-2002 14:35-.
Page 6
J. L. Rogers and Callcott Engineers, Inc.
Client Name:
Sample Matrix: LIQUID
Lab Smp Id:
Level: LOW
Data Type: MS DATA
SpikeList File: 8260spike.spk
Sublist File: all.sub
RECOVERY REPORT
Client SDG: SDGa22296
Fraction: VOA
Client Smp ID: lcs
Operator: lbw
SampleType: LCS
Quant Type: ISTD
Method File: C:\tp\target\data\1120\1023 8260.m
Mi~c Info: Initial Calibration File 20_1~25 (analyzed on 10/23)
AMOUNT AMOUNT %
SPIKE COMPOUND ADDED RECOVERED RECOVERED
ug/1 ug/1
10 1,1-Dichloroethene 25.0 23.5 94.00
31 Benzene 25.0 24.0 96.00
34 Trichloroethene 25.0 22.6 90.40
43 Toluene 25.0 23.9 95.60
53 Chlorobenzene 25.0 23.2 92.80
3 Vinyl chloride 25.0 21.0 84.00
AMOUNT AMOUNT %
SURROGATE COMPOUND ADDED RECOVERED RECOVERED
ug/1 ug/1
$ 29 1,2-Dichloroethane 25.0 24.1 96.40
$ 42 Toluene-dB 25.0 25.7 102.80
$ 62 4-Bromofluorobenze 25.0 25.2 100.80
37
LIMITS
70-130
63-123
67-124
70-126
67-118
70-130
LIMITS
61-110
67-118
70-130
w
0:,
Trio 4312
Sample#
Date:
Method#
Client
%RPO:
% Recovery:
Analyst:
Comments:
Water Matrix spike/Matrix spike Duplicate Recovery
Limits Generated 12/12/01-2/22/02
72832
11/20/02
8260B
Roy Metals
spike sample ms % rec. msd
cone. result cone. cone.
1, 1-Dichl_oroethene 25 0 24.7 99 24.1
Benzene 25 0 25.4 102 25.0
T richloroethene 25 15.6 39.4 95 38.8
Toluene 25 0 24.9 100 24.5
Chlorobenzene 25 0 23.7 95 23.5
Vinyl Chloride 25 0 22.9 92 23.4
O of 6 out of control limits
O of 12 out of control limits
LCS is within QC limits as specified in the method
% rec.
RPO
96 2.5
100 1.6
93 1.5
98 1.6
94 . 0.8
94 2.2
Generated Limits
RPO % REC
20.5 70-130
19.9 63-123
16.0 67-124
21.0 70-126
19.2 67-118
26.6 70-130
-------------------
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Sampling Log-Grab Water Samples
Project No. 26QS06 Site Location CNA / Ticona -Shelby, NC
Sample Date __ //,,_ti..,,«;~4_· _· __
'
Arrival Time 0 07Ai Sample Time I UC/' ---~---
Sample ID ·--;J;-rc Y Duplicate No. --::f::r ef -Dvi' Field Personnel· __ ~_-7<":~----
Weather Conditions Sb,,,.,7,, ~ I.. Sampling Method
Sample Temp. ("C) /?, 5 :;2. Spec. Conductivity(µS/cm) /9,f't, pH .JY,, J(_ --~~(:;:;:, __ _
ORP (mV) -:lJ 3.1
Method(s)
//t'Cs
Remarks
/,1/,i}L Sample Date __ +-~-6'+~·-v __ _
Sample ID ---:F,c I
Weather Conditions fv,v,,/, Ci.L
Sample Temp. ("C) /ft,, ¼
OAP (mV)
Method(s)
vet:
Remarks
Turbidity (NTU) _/'-/_,...::.{p __ _:DO(mg/L) __ / ,_?'<_0 __
Container Description
J;,,@1,1/
Preservative
tic; -
Arrival Time _ __;;;,()_~c..tJ_O __ 09.16 Sample Time ____ ,r-__ _ --Duplicate No. _____ _ :-·IC. Field Personnel _~QE.~----
Sampling Method
Spec. Conductivity(µS/cm) ;L(/~ /:ff f,;,(.,) pH _ __:_'f_,-'-----
Turbidity (NTU) __ /,..:..,...,7'-----"DO(mg/L) _ _,_/,...,_,_0-=.b __ _
Container Description
J1<fftl."(
Kubal-Furr & Associates
39
Preservative
fk.r
---
Q'{·:Jl.'t>:}.
Revised 7 /30/02
Low•Flow Groundwater Sampling Log
Project No. 26QS06 Kubal-Furr & Associates
-E1111ironme11lai Co11s11/fn11ff.-Site Locotion CNA/Tlcona · Shelby. NC
Field Personnel ___ ..,{;.;;·~.,,_• ~------
Well I Sample ID --Lt"-·-'. ,.)=..,f .. -______ _
~¼-0 5'1½':J.., Weather Condition £°,;J,;,,.;·7 ,. Ca•( //}'. A'l..-/AU,-i Sample Dale __ _,_c...J_cc~c...... _____ Arrival Time Sample f1me=="•~·,-,,,.. _______ _
Description ol Memu,ingl---, I Cosing lypei?I locking Cap~ o· Casini 010! Point (MP)· r,•(!1..-. ~ ~ 1ameer~
Purge Method I ?a,s,;ttTIL
PurgeStortTimeF99".f· I
Water-Level Measurements
Interval Elapie Time
{mins) DTW (feel) Interval
0 C) :.V,·"JQ 0
I -5 2/.l-</ I
2 It) ::J2.of 2
3 ;s-~;J.37 3
' J(i J,1.L,o 4
5 J,< (l),73 5
6 '3o J3.o-< 6
7 3,..--., J:3,:)9 7
8 'lo -J.J, 'f~ 8
9 1/r 03,s,S-9
10 so 11.~~-10
II II
12 12
13 13
" "
15 15
16 16
17 17
18 18
19 19
20 20
Samples Collected
Sampling Method I -£1,,j,IF
Purge Slop Timej /C9'£)
Field Parameters
El TI l emperalure Specific apse ime loCI Conductance
(mins) (µS/cm)
C) --
s-/t',ol, ~/'ib
//) ;·?, ~* t...f t'7c'
1--s' /f'J)f '3 :J'to
1o I f.,it j~7.f1
,}-< Jf, 3.;2 ;J'.3 9t)
3c, I f,tl.S-';/Jf'I
j',S-If. 39 JJ:J1<1
Cfo /cf,613 ;l~
'Ir' If.sf.. /J/7'f-
So I¢"'. /:c.> .;...~(j 3
Container Oescnption
Porometer Conditions: pH +/. 0.1 standrud unit COND/Temp +/-3%
+/· 1 NTU below 10 NTU Turbidity +/· 10% above 10 NIU
40
Purge RotejA..../.fO ml/mini
pH (SU) Turbidity {NTU)
--
S.9~ 1·1 t./
,,r-9< /f.3
-~9f IR.1
,5".'/7 11,,r
s;f9 lh,'J. -s-:r;; JS,i/
~9.y 1s· CJ
t-..o I /·~ I
&:.c>/ /1. 9
/p.a I 1-r. )-.
.
Preservative
DO +/. 10%
ORP +/• lOmV
Dissolved
Oxygen
(mg/LI
-
0,37
(),if/
0,3?
0,5 9
O,a7
(),3(,
0,3•~-
o .. J•~-
Cf, JC..,
'-', J,r
ORP (mV)
-
-9o.7
-913
-fJ_;J.
-7.f(...
-7t~3
-7:;'.]
-7(:.;i_
·-·-:z,, 'I .
-r,/?,;
-AJ; t..j
CNA/Ticono
Low•F!owGroundwa!er $amping Log
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Low-Flow Groundwater Sampling Log
Kubal~Furr & Associates
-£11t•iro11111e11/nl Ca11s11lln11/s--
Project No. ____ ..=2c:.6..=Qc:.S0=.;6:.._ __ _
Site Location ---'C'-'N"-A"-/-"Tl.c.co"'n-"a=---• S'-'h-'-'e"-'lb'--'y-'-, -"N-=C-
Fietd Personnel ---b'--·-'-.,..-./../s=. ____ _
/4 Well I Sample ID t1-;_J_3
I/ r/r.rz_ /4 WeatherCondition _.......,.{'-',~'--'•,~•·..,,.__,1•1_,,_L.=.·,:.c..C_L_. __ _ u ~£ ~)~ /'~~ I Sample Dote Arrivo!Time t../...J ~ SompleTime::=_,,.,_=·•<>==-------
Descrip1iono!Me_murin~ Casing Type~(' Lockin Co I _,,--I _co~ing~ J' I Point jMP) Cb(__ · ;> .,) 9 P V D1amele od><•
Purge Method I '?t)Ar;fl.t7L Sornp~ng Method I ,S:~
Pu,ge Simi Time I 1/0'f I Pu,ge Slop Timel J;ds-" I Pu,ge RaleJ.'\. {,~c/ml/mlol
Water-Level Measurements Field Parameters
Interval
0
I
2
3
'
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
Elapse Time OTW fleet)
fmins)
0 /(R,fl\
---< 11,.S:t'
Jo !?, {~
/5 /t-.Jr
cJo /J:,]3
;1..-s'" /t,3f
,,o /i.-rt
3,,,--lf,.l'f
'lo If.hr
'(-r-ff, t:,1
,<;;o lrf,bl
,s-s /J;/,,3
b;) it. I:'/
Samples Collected
Interval
0
I
2
3
'
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
Elapse Time Temperature Specific Conduclance !mins) (oC) [µS/cm)
CJ --..s--/9,/A 11.r-R-
/o ;9.'ff-/AS-7
/.J 19.1 ~ I ;}rJJ
,Jo /9. J:J I 3/e> :tr /9, ~(,., l'/,5'-f"
.Si> /CJ,/:). 1?70
3.r JC/,d7 .1o.J.,
4o /9.o(, J//,S'
L/5" 19. 05"'" :J.s-s.s
So I g '?[i 'l7c;J
--.'>S' ;f;,9s-~&;he;'
6c ;f/)1 !J&trl
Container Descriphon
Paromeler Conditions; pH +/-0.1 standard unit COND/Temp +/-3%
+/-1 NTU below 10 NTU Turbidity +/-10% above 10 NTU
41
Dissolved
pH (su) Turbidity tNTU) Oxygen ORP (rnV)
lmg/LI
---·-
,e;:/9 "· c; I. 3?, <fr',"-
--~}( ,f /.t.f / 7,<, ,,
.s'.,7 s, :;L j, -;J./ 7f,~
0, // ld'.7 ;.,; 9 7/:,, (,,,
,C:,ti-, J.7 /,;'3i --Jf, I
if.9f ~7 /.lb 79, ",/
1.9S' ,fl, (:, /,<JS-7R./
t/, ?,f ,;?, 3 {). 9,S" 71),;.
t./,9.::;• bl , I l,o I "lJ,'(
l/. 9,:, ~ ' I /, C'c--J/. ,(
if,9o ✓. ,;2 o.91: '7cJ.'-/
ll, $ti :a. I t/ 6.91 c-,~
Preservative
DO +/-10%
ORF +/-IOmV
CNA/Ticono
Low-flowGroundwcter Somplng log
Calibration Log /,
Date I/ !.ffr7-Meter Model YSI 556MPS _________ '
Meter Serial # 01 G0526
Battery
Conductivity Meter Calibration
Standard µS/cm
Standard Reading µS/cm
Temperature ('C)
pH Meter Calibration
7.0 Buffer
4.0 Buffer
10.0 Buffer
., Dissolved Oxygen Calibration
DO%
ORP Calibration
Standard mV
Standard Reading mV
Temperature ('C)
• Turbidity Calibration
Meter Model ESD Model 800
Meter Serial # TUR800 358
Battery
Zero Standard (0 NTU)
Ten Standard (10 NTU)
Time ,)f,;2{) ---'--------
~//L/7
//-5').
Date __ l....f./ A....;~,_½1_1L_· ___ _
Time_O_·L;~e:...· ___ _
O,oz.
/ 7
Signature
/ /" //
~TV
'(J
-------Kubal-Furr & Associates--------
Revised 2/22/02
42
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-- - - - - --- -------Chain of Custody Record
Client Project I Site Location 816 E. Durst Avenue. Greenwood, SC 29649 [phone] Fax: [phone]
Ticona 61195.02 Laboratory Certifca/lon Numbers: SC-24110, NC-25. TN· 2923, VA -77
Shelby,NC
Contact j,..,t.,c--l.J✓c7tJd'j ~ Report To Copy To Reporting Requirements: { J Standard { J Data Package (Specify Level)
-y',qr,, C,;.1,.,i)~?Z \[ v',:__,(;c:--u.f,c7v~Y .I/Ya -re.
' Required Parameters, Containers and Preservatives C-:RcZI-/:,.,.("-'!A,.__> " " " E E E ~ 0 0 ~ • N
NOTICE: 0 • e ~ • C .S " ·a
" §_ ~g 0 ii, u ~-~ ~ 0 " 0 ~ .. • • 8. 0 • e C
~ < ~ <{ • • = C ~ ·c E .>-u E c • ii 0 Sample Collection i= ~ 5 i!i , > ,a 0 u z w
Sam[l[e Descriotion Date Time Time Type Total C A =,·
::C7c I ''/2/o'L 69lc> ✓ ,S-✓ ✓ ✓
-::C1Er lt,/p/4-z. o9h . ✓ s ✓ ✓ /
X::,cr -1).rr' '/f~ o9~ ✓ -~ ✓ ✓ /
f:-.)R-'t/r/4 ~s-✓ ) ✓
V-J3 11/f'/42.-;.)11.£-✓ £ ./
772, f 'BL,,-q,,.;k 1<1/2oJ1.--✓ t2 ✓
'
.
//
/;.,/ /' /
~By# ~ Time Refiquished By Date Time
¼;:r-;.-,7. -l:&S-•oZ_,
R7Jy/tf/ ,L; 'I~/~ Time Received By Date Time
c.,; '. ~0.-,G /605
1 .... ommen,s
Matrix Type Definitions
Preservative Definitions
1 -Dnnk.mg Water 2 -Clean Water 5 -Groundwater 7 -S0I!/Sed,ment 8 -Liquid Sludge 9 -011 12 • Air
A -None 8 -H2$04 C -HCI D -HNOJ E -Na OH F -Filtered G -.1 N HCUpH 4 to 5
" " " " E E " ""
E 0 ~ ~ ~ 0 ~ • N ~
. , ,;, u 0 u ~ 0 N u .
~ e 0 ;, <{ N E E > • 0 e • • "' :, > u,a ,a "-"-"; 0 ' • g J > 0 0 ~ u "'0 0 ~
A A A A A
Reliquished By Date
Received in Laboratory By Date
Time
nme
---
Page ------I of I
ice Use Only
Purchase Order
State Quote
NC
L0Qln Special Instructions
:;
i~ 0 •
C " < • ~~ Cb : ~ ~ ~ 1 ~ ...J
Fraction HOT omments
S'cc---w!C:
OZi)r.:-x .:;:F'
,;2{; /.JSo I:,
Quick TAT Shipped By
y N w CLIENT
"" rEOEX
If Y, specify: Airbi/1 Number
--days
Cooler ID (if available):
Dn Ice: Yes I No Temp(C) ___
Custody Seal: Intact I Broken I None
Davis & Floyd. Inc
FL02 _ 0 I (02199)
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D;\VIS
FLtJ\7D LABORATORY ANALYSIS ·REPOR-T-:__j o·~;;-s~12,-.:. -r~ 1 · -
December 11, 2002
PEM CARTER
TICONA,LLC
2525 BLACKSBURG ROAD
HWY. 198
SHELBY, NC 28152
Login Number
Project Number
Description
Dear Pem Carter:
:L02120513
:61195.02
:GROUNDWATER
We arc pleased to provide the enclosed analytical results for the samples received by
Davis & Floyd, Inc. on December 05, 2002_
A formal Quality Assurance/Quality Control program is maintained by Davis & Floyd,
which is designed to meet or exceed the EPA, NELAC or other appropriate regulatory
requirements. All analytical analyses for this project met QA/QC criteria and the
results are within the 99 % confidence interval for each method unless otherwise
stated in the footnotes_ This report is to be reproduced only in fulL
Feel free to contact our Client Services Representative at [phone] if further
explanation of the analysis is required. Unless other arrangements have been made,
samples will be disposed of or returned 14 days from the date of the report_ We
appreciate the opportunity to provide services to your firm.
Sincerely,
DA VIS & FLOYD,
ohn I-1. McCord, Jr
Laboratory Manager
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I 816 E. Durst Avenue j Greenwood, SC 2%49 I (8(,4) 229-441 :1 I F.1x [phone]
44
DAYIS
FLOYD LABORATORY ANALYSIS REPORT
NELAC Cer1ificario11 Number: £87633
Client
Contact
TICONA,LLC
2525 BLACKSBURG RC.:..:)
HWY. 198
SHELBY, NC 2s:s2
PEM CARTER
Client ID: ITEF
Parameter
Volatile Organics
SW846 8260B
Matrix
1, 1,1-TRICHLOROETHANE
1,1,2,2-TETRACHLOROETHANE
1 , 1 , 2 -TR I CHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
1,2-0ICHLOROETllANE
1,2-DICHLOROPROPANE
2-BUTANONE
2-HEXANONE
4 -METHYL-2-PENTANONE
ACETONE
BENZENE
BROMODICHLOROMETHANE
BROMOFORM
BROMOMETHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-DICHLOROETHENE
CIS-1,3-DICHLOROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-DICHLOROETHENE
TRANS-1,3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHI..ORIDE
XYLENE (TOTAL)
GW/ChemW
Result
0 .0010
0 .0010
o. 0010
0 . 0010
0 -0010
0 .0010
o. 0010
0 . 0050
0 .0050
0 .0050
0 .ooso
0 .0010
0. 0010
0 .0010
0. 0010
0. 0010
0 .0010
0 .0010
0 .0010
0 .0010
0 . 0010
0 .0010
o. 0010
o. 0010
0. 0010
0. 0010
o. 0010
o. 0010
0 .0010
o. 0010
o. 0010
o. 0010
0 . 0010
o. 0010
0. 0020
NC Cer1ificatio11 Number: 25
Project Number: 61195.02
Report Date December 11, 2002
Page 1 of 1 Report 1D: AA35681
Sample ID L02120513-01
Date Collected, 05-DEC-02 10: 30
Date Received 05-DEC-02
Qual RDL Units Analyst Date Time
0 . 0010 mg/1 PAP 12/06/02 12 09
0 .0010 mg/1 PAP 12/06/02 12 09
0 .0010 mg/1 PAP 12/06/02 1209
0 . 0010 mg/1 PAP 12 /06/02 12 09
0 . 0010 mg/1 PAP 12/06/02 1209
0 . 0010 mg/1 PAP 12/06/02 1209
0 .0010 mg/1 PA? 12/06/02 12 09
0 .0050 mg/1 PAP 12/06/02 12 09
0 .0050 mg/1 PAP 12/06/02 12 09
0 .ooso mg/1 PAP 12/06/02 1209
0 .0050 mg/1 PAP 12/06/02 1209
0 .0010 mg/1 PAP 12/06/02 1209
0 .0010 mg/1 PAP 12/06/02 12 09
0 .0010 mg/1 PAP i2/06/02 1209
0 .0010 mg/1 PAP 12/06/02 12 09
0 .0010 mg/1 PAP 12/06/02 12 09
0 .0010 mg/1 PAP 12/06/02 1209
o. 0010 me I l PAP 12/06/02 1209
0 .0010 mg/1 PAP 12/06/02 12 09
0 0010 mg/1 PAP 12/06/02 1209
0 . 0010 mg/1 PAP 12/06/02 12 09
0 . 0010 m;i/1 PAP 12/06/02 1209
0 .0010 mg/1 PAP 12/06/02 1209
o. 0010 mg/1 PAP 12/06/02 1209
o. 0010 mg/1 PAP 12/06/02 12 09
0 .0010 mg/1 PAP 12/06/02 1209
o. 0010 mg/1 PAP 12/06/02 1209
0 . 0010 mg/1 PAP 12/06/02 1209
0 .0010 mg/1 PAP 12/06/02 1209
0 .0010 mg/1 PAP 12/06/02 1209
0 .0010 mg/1 PAP 12/06/02 12 09
o. 0010 mg/1 PAP 12/06/02 1209
0 . 0010 mg/) PAP 12/06/02 1209
0. 0010 mg/1 PAP 12/06/02 1209
0 . 0020 mg/1 PAP 12/06/02 1209
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Davis & r:loyd, Inc. I PO Drawer 421! I Greenwood. SC 2%--Hl I 1116 E. Durst Avenue I Gret:11wood, SC L.%49
45
I (/HAI 229--14 ( J I Fa>IHf,41 22:J.711'.I I
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DAYIS
FLOYD LABORATORY ANALYSIS REPORT
NELAC Certifica1io11 Number: £87633
Client
Contact
TICONA,LLC
2525 BLACKSBURG ROAD
HWY. 198
SHELBY, NC 28152
PEM CARTER
Client: ID; ITEF DUP.
Matrix
Parameter
Volatile Organics
S1-1846 826::B
1,1,1-T~ICHLOROETHANE
1,1,2,2-TETRACHLOROETHANE
1,1,2-TRICHLOROETHANE
1,1-DIC~LOROETHANE
1,1-DICELOROETHENE
1,2-DICELOROETHANF.:
1,2-DICELOROPROPANE
2-BUTA.';''.:NE
2-HEXANO!JE
4-METHY~-2-PENTANONE
ACETONE
BENZENE
BROMODICHLOROMETHANE
BROMOFORM
BROMOME'!HANE
CARBON SISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROETHANE
CHLOROFORM
CHLOROM::::THANE
CIS-1,2-DICHLOROETHENE
CIS-1,3-~ICHLOROPROPENE
DI BROMOC:iLOROMETHANE
ETHYLBE:-.;ZENE
METHYLENE CHLORIDE
STYRENE
TETRACH~OROETHENE
TOLUENE
TRANS-1, 2-DI CHLOROETHENE
TRANS-1,3-DICH!...OROPROPENE
TR I CHLO?.OETHENE
VINYL ACETATE
VINYL Ci-iLORIDE
XYLENE ·'.TOTAL'
GW/Chemw
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
<
Result
0 . 0010
0 .0010
0 .0010
0 .0010
0 .0010
0 .0010
0 .00~0
0 .ocso
0 .0050
0 .0050
0. 0050
0 .0010
0 . 0010
0 .0010
0 .0010
0 .0010
0. 0010
0 . 0010
0 .0010
0 . 0010
o. 0010
.0010
0 .0010
0 .0010
0 .0010
0. 0010
0 .0010
.0010
0. 0010
.0010
0 .0010
0 .0010
0 .0010
0 .0010
0 .0020
NC Certificarion Number: 25
Project Number, 61195.02
Report Date
Page 1 of 1
sample ID
December 11, 2002
Report ID, A,\35682
L021205l3-C·2
Date Collected: OS-DEC-02 lJ:30
Date Received 05-DEC-02
Qual RDL Units Analyst Date
0 . 0010 mg/1 PAP 12/06/02
0 . 0010 mg/1 PAP 12/06/02
0 . 0010 mg/1 PAP 12/06/02
0 .0010 mg/1 PAP 12/06/02
o. 0010 mg/1 PAP 12/06/02
o. 0010 mg/1 PAP 12/06/02
o. 0010 mg/1 PAP 12/06/02
0. 0050 mg/1 PAP 12/06/02
0. 0050 mg/1 PAP 12/06/02
0 . 0050 mg/1 PAP 12/06/02
0 . 0050 mg/1 PAP 12/06/02
0. 0010 mg/1 PAP 12/06/02
0 .0010 mg/1 PAP 12/06/02
0. 0010 mg/1 PAP 12/06/02
0 .0010 mg/1 PAP 12/06/02
0 .0010 mg/1 PAP 12/06/02
0 .0010 mg/1 PAP 12/06/02
0 .0010 mg/1 PAP 12/06/02
0. 0010 mg/1 PAP 12/06/02
0 . 0010 mg/1 PAP 12/06/02
0. 0010 mg/1 PAP 12/06/02
0. 0010 mg/1 PAP 12/06/02
0 .0010 mg/1 PAP 12/06/02
o. 0010 mg/1 PAP 12/06/02
0. 0010 mg/1 PAP 12/06/02
o. 0010 mg/1 PAP 12/06/02
0 . 0010 mg/1 PAP 12/06/02
0 .0010 mg/1 PAP 12/06/02
0 .0010 mg/1 PAP 12/06/02
o. 0010 · mg/1 PAP 12/06/02
0 .0010 mg/] PAP 12/06/02
0. 0010 mg/1 PAP 12/06/02
0 .0010 mg/1 PAP 12/06/02
0 .0010 mg/1 PAP 12/06/02
0 .0020 mg/1 PAP 12/06/02
Time
1232
1232
1232
1232
12 32
1232
1232
1232
1232
1232
1232
1232
1232
1232
1232
1232
1232
12 32
1232
1232
1232
1232
1232
1232
1232
1232
1232
1232
1232
1232
1232
1232
1232
1232
1232
Davis & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 29648 I Bl 6 E. Durst Avenue I Greenwood, SC 2%49 I (86-ll nrJ-441 J I Fzix (B!A} 22~)-7119
46
DAYIS
FLM:D LABORATORY ANALYSIS REPORT
NELA C Certification Number: £87633
Client
contact:
TICONA,LLC
2525 BLACKSBURG ROAD
HWY. 198
SHELBY, NC 28152
PEM CARTER
Client ID: ITCI
Matrix
Parameter
Volatile Organics
SW8•16 82608
1,1,1-TRICHLOROETHANE
1, 1, 2, 2-TETRACIILOROETHANE
1,1,2-TR!CHLOROETHANE
1, 1-0ICHI..QROETHANE
1,1-DICHLOROETHENE
1, 2-DIC!lLOROETHANE
l, 2-DI CHLO RO PROPANE
2-BUTANONE
2-HEXANONE
4-METHYL-2-PENTANONE
ACETONE
BENZENE
BROMODI CHLOROMETHANE
BROMOFORM
BROMOMETHANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBF.NZENE
CHLOROETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-DICHLOROETHENE
Cl 5-1, 3-DICHLDROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-DICHLOROETHENE
TRANS-1, 3-DI CHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL),
GW/Chemw
Result
0 .0010
0 .0010
o. 0010
o. 0010
0 . 0010
0 .0010
0 .0010
0.030
0.0050
0.0050
0.077
0.029
0. 0010
0 . 0010
0 .0010
0.0022
0.0010
0.026
0. 0010
0 .0010
o. 0010
0. 0010
0. 0010
0 .0010
0 .0010
0 .0010
0 .0010
0 .0010
0. 0014
0. 0010
0.0010
0.0010
0.0010
o. 0010
0.0020
NC Certification Number: 25
Projec~ N~:nber, 61195.02
Report Date ::)ecember 11, 2002
Page 1 of 1 Re;;iort ID: AA35683
Sample ID !..,02120513-03
Date Collected, OS-DEC-02 10: 45
Date Received OS-DEC-02
Qual RDL Units Analyst Date Time
0 . 0010 mg/1 PAP 12/06/02 1255
0 .0010 mg/1 PAP 12/06/02 1255
0 .0010 mg/1 PAP 12/06/02 1255
o. 0010 mg/1 PAP 12/06/02 1255
o. 0010 mg/1 PAP 12/06/02 1255
0 . 0010 mg/ l PAP 12/06/02 1255
0 . 0010 mg/1 PAP 12/06/02 1255
o. 0050 mg/1 PAP 12/06/02 12 55
0 .0050 mg/1 PAP 12/06/02 12 55
o. 0050 mg/1 PAP 12/06/02 1255
0 .0050 mg/1 PAP 12/06/02 1255
0 . 0010 mg/1 PAP 12/06/02 1255
0 .0010 mg/1 PAP 12/06/02 12 55
0 . 0010 mg/1 PAP 12/06/02 1255
0 0010 mg/1 PAP 12/06/02 1255
o. 0010 mg/1 PAP 12/06/02 1255
0. 0010 mg/1 PAP 12/06/02 1255
0 .0010 mg/1 PAP 12/06/02 1255
0 .0010 mg/1 PAP 12/06/02 12 55
0 .0010 mg/1 PAP 12/06/02 1255
0 .0010 mg/1 PAP 12/06/02 1255
G .0010 mg/1 PAP 12/06/02 1255
0 0010 mg/1 PAP 12/06/02 12 55
0 .0010 mg/1 PAP 12/06/02 1255
0. 0010 mg/1 PAP 12/06/02 1255
0 0010 mg/1 PAP 12/06/02 1255
0 0010 mg/1 PAP 12/06/02 1255
0 .0010 mg/1 PAP 12/06/02 1255
0 0010 mg/1 PAP 12/06/02 12 55
0 . 0010 _mg/1 PAP 12/06/02 12 55
0. 0010 mg/1 PAP 12/06/02 1255
o. 0010 mg/1 PAP 12/06/02 1255
0 .0010 mg/1 PAP 12/06/02 1255
0 . 0010 mg/1 PAP 12/06/02 1255
0 .0020 mg/ l PAP 12/06/02 1255
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O;ivis & Floyd, Inc. I PO Drawer 42B I Gret::nwood, SC 2%48 I 8 \ 6 E. Durst Avenue
47
I Cree,,wood, SC 2964~ I (ll64) 22')-441 :1 I Fe,, '81,41 22'1-71 l ,i I
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DAYIS
FLtJvD LABORATORY ANALYSIS REPORT
NELAC Certification Number: £87633
Client
contact
TICONA,LLC
2525 BLACKSBURJ ? . .:AD
HWY, 198
SHELBY, NC 2s:s:
PEM C,\RTER
Client :n· TRIP BLANK
Matrix
Parameter
Volatile Organics
SWB't6 8260B
1,1,1-TRICHLOROETHANE
1,1,2,2-TETRACHLOROETHANE
1,1,2-TRICHLOROETHANE
1,1-DICHLOROETHANE
1,1-DICHLOROETHENE
1, 2-DICHLOROETHANE
1,2-DICHLOROPROPANE
2-BUTANONE
2-HEXANONE
4-METHYL-2-PENTANONE
ACETONE
BENZENE
BROMOOICHLOROMETHANE
BROMOFORM
BROMOMETHANE
CARBON DISUL~IDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLO RO ETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-DICHLOROETHENE
CI S-1, 3 -DICHLOROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-DICHLOROETHENE
TRANS-1,3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORr □E
XYLENE (TOTAL)
GW/Chemw
Result
o. 0010
0 .0010
0 .0010
0 . 0010
0 . 0010
0 .0010
0 .0010
0 .0050
0 . 0050
o. 0050
o. 0050
0 .0010
0 . 0010
0 . 0010
o. 0010
0 .0010
0 .0010
0 .0010
o. 0010
o. 0010
0 .0010
o. 0010
0 .0010
0 .0010
o. 0010
0 .0010
0 .0010
0 .0010
0 . 0010
0. 0010
0 .0010
o. 0010
0 .0010
0 .0010
0. 0020
NC Certification Number: 25
Project Number: 61195.02
Report Date Decembe:.: 11, 2002
Page 1 of 1 Report I::): AA3568-l
sample ID LO212O5:C3-04
Date Collected· 27 -NOV-02 11: 30
Date Received 05 DEC-02
Qual RDL Units Analyst Date Time
0 .0010 mg/1 PAP 12/06/02 0930
o. 0010 mg/1 PAP 12/06/02 0930
0 .0010 mg/1 PAP 12/06/02 0930
0 .0010 mg/1 PAP 12/06/02 0930
0 . 0010 mg/1 PAP 12/06/02 0930
0 .0010 mg/1 PAP 12/06/02 0930
0 .0010 mg/1 PA? 12/06/02 0930
0 .0050 mg/1 PAP 12/06/02 0930
o. 0050 mg/1 PA? 12/06/02 0930
0 .0050 mg/1 PAP 12/06/02 0930
0 .0050 mg/1 PAP 12/06/02 0930
0 .0010 mg/1 PAP 12/06/02 0930
0 . 0010 mg/1 PAP 12/06/02 0930
0 .0010 mg/1 PAP 12/06/02 0930
0. 0010 mg/1 PAP 12/06/02 0930
0 . 0010 mg/1 PAP 12/06/02 0930
0 .0010 mg/1 PAP 12/06/02 0930
0 .0010 mg/1 PAP 12/06/02 0930
0. 0010 mg/1 PAP 12/06/02 0930
0 .0010 mg/1 PAP 12/06/02 0930
0 .0010 mg/1 PAP 12/06/02 0930
0 .0010 mg/1 PAP 12/06/02 0930
0 .0010 mg/1 PAP 12/06/02 0930
0 .0010 mg/1 PAP 12/06/02 0930
0 .0010 mg/1 PAP 12/06/02 0930
0 .0010 mg/1 PAP 12/06/02 0930
o. 0010 mg/1 PAP 12/06/02 0930
0. 0010 mg/1 PAP 12/06/02 0930
0 .0010 mg/1 PAP 12/06/02 0930
0 .0010 mg/1 PAP 12/06/02 0930
0 .0010 mg/1 PAP 12/06/02 0930
o. 0010 mg/1 PAP 12/06/02 0930
0. 0010 mg/1 PAP 12/06/02 0930
0 .0010 mg/1 PAP 12/06/02 0930
0 .0020 mg/l PAP 12/06/02 0930
D.ivi~ & Fluyd, Inc. I PO Drawer 42B I Greenwood, SC ~9648 I 8 l 6 E. Durst Avenue I Greenwood, SC 2%49 I /8fi4l 229-4413 I Fax [phone]
48
DAYIS
FLMD LABORATORY ANALYSIS REPORT
NELAC Certification Number: £87633
Master Tracking List
Client
Contact:
Sample ID
L02120513-0l
Volatile Organics
SW846 8260B
L02120513-02
Volatile Organics
SW846 8260B
L02120513-03
Volatile Organics
SW846 8260B
L02120513-04
Volatile Organics
S1\'846 8260B
TICONA,LLC
2525 BLACKSBURG ROAD
HWY. 198
SHELBY, NC 28152
PEM CARTER
Client ID
ITEP'
ITEF DUP.
ITCI
TRIP BLANK
NC Certification Number: 25
Project Number: 61195.C2
Report Date
Page 1 of 1
Decembe~ 1~, 2002
Report i~: AA35680
Date Collected Date Received
10:30 05-DEC-02
12/06/02 1209
05-DEC-02 10:30 05-DEC-02
12/06/02 1232
05-DEC-02 10,45 05-DEC-02
12/06/02 1255
'.27-NOV-02 ll: 30 05-DEC-02
12/06/02 0930
D,ivl~ & Floyd, Inc. I 1'0 Drawer -128 I Greenwood, SC 29(,4H I 816 E. Ours! Avenue I Greenwood, SC 2%49 I [phone] I Fax (864) n:J./ 119
49
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Df\YIS
FLOYD LABORATORY ANALYSIS REPORT
Method Conformance Summary
Client: Ticona, LLC
Login(s): L02 t205 I 3
Criteria Volatiles
Sample Holdino Time
Standards Preoaration
Instrument Tuni1w
Instrument Calibration ·
Calibration Vcrificatioh . •
Deeradation Check
Interference
SamolelStandard
Blanks Results
Method Accuracv
Method Precision
Surroeate Recoverv
PDSISD/MSA
TCLP Prenaration
Key ✓
NIA
Met Criteria Met
Not Applicable
✓
✓
✓
✓
✓
NIA
NIA
✓
✓
✓
✓
NIA
NIA
Semi
Volatiles
NIA
NIA
NIA
NIA
NIA
NIA
NIA
NIA
NIA
NIA
NIA
NIA
NIA
Metals
NIA
NIA
NIA
NIA
NIA
NIA
NIA
NIA
NIA
NIA
NIA
NIA
NIA
*
PDS =
SD =
MSA=
Method Criteria Not Met -Seefootnote(s) below.
Post Digestion Spike
Serial Dilution
Method of Standard Additions
Footnotes:
Project Number: 61995.02
Report Date: December 11, 2002
Ethylene
TOC Glvcol
NIA NIA
NIA NIA
NIA NIA
NIA NIA
NIA NIA
NIA NIA
NIA NIA
NIA NIA
NIA NIA
NIA NIA
NIA NIA
NIA NIA
NIA NIA
[),wis 0, rloyd, Inc. I f'O Drawer 428 I Greenwond, SC 2%48 I ll 1 !J E. Durst Avenut' I Creenwond, SC 2%•l'J I (B64l nq.,14·1 J I r:ax (iHi4) 22'.l-71 I~ 5 0 ·
I
D1\VIS
FLi1YD LABORATORY ANALYSIS REPORT I
QC Batch Report
\~orkGroup WG32347
Description: vo/8260/TCL
Sample ID
L02120513-01
L02120513-02
L02120513-03
L02120513-04
LCS32347:l
MB32347:1
MS02120513-0l:32347
MSD02120513-01:32347
Client ID
ITEF
ITEF DUP.
ITCI
TRIP BLANK
Laboratory Control Spike
Method Blank
Matrix Spike
Matrix Spike Duplicate
Run#
1
1
1
1
1
Davis & Floyd, Inc. PO Drawei 4211 I Greenwnod, SC 2%48 I Bl 6 F.. Durst Avenue
51
Report Date December 09, 2002
Page 1 of 1 Report ID: AA35520
Matrix GW/Chemw
Prep Method
Analtyical Method: SW846 8260B
PREP
Date Time
ANALYTICAL
Date Time
12/06/02 12 09
12/06/02 123 2
12/06/02 1255
12/06/02 0930
12/06/02 1427
12/06/02 0908
12/06/02 1341
12/06/02 14 04
Analyst DilUtion
PAP
PAP
PAP
PAP
PAP
PAP
PAP
PAP"
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I G1eenwood, SC 2%4'1 I (llf,41 l2'J-,),l 11 I f;,, (!HA) 129-711 '1 I
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DAYIS
FLOYD LABORATORY ANALYSIS REPORT
Surrogates % Recovery
L02120513-01
L02120513-02
L02120513-03
L02120513-04
LCS32347:l
MB32347:l
MS02120513-0l:32347
MSD02120513-01:32347
06-DEC-02
06-DEC-02
06 DEC-02
06-DEC-02
06-DEC-02
06-DEC-02
06-DEC-02
06-DEC-02
DCE 1,2-DICHLOROETHANE-D4
BFB BROMOFLUOROBENZENE
TOL TOLUENE-DB
12: 09
12 :32
12: 55
09: 30
14 : 27
09: 08
13. 41
14 : 04
DCE
80-'138
104
107
102
B6
107
99
107
106
Report Date
Page 1 of 1
Matrix
December 09, 2002
Report ID: AA35526
GW/ChemW
Method SW846 8260
.,BFB TOL
aa-112 .'a·1-1·09.
99 95
9B 94
101 94
93 97
100 94
98 93
101 93
99 94
D,1vis f... Floyd, Inc. I PO Drawer 42fl I Greenwood, SC 29648 I 816 E. Durst Avenue I Greenwood, SC 21)64~1 I ({164) 22~1-4413 I F.ix (86---1\ ~29-7119
52
Df\YIS
FLOYD LABORATORY ANALYSIS REPORT
Method Blanks
Blonk
Parameter
Volatile Organics
SW846 8260B
1,1,1-TRICHLOROETHANE
1,1,2,2-TETRACHLO~OETHANE
1,1,2-TRICHLOROETHANE
1,1-DICHLOROETl!ANE
1,1-DICHLOROETHENE
1, 2-DICf!LOROETHANE
1, 2-DIC!ILOROPROPANE
1,3-DICHLOROPROPANE
2-BUTANONE
2-HEXANONE
4 -METHYL-2 -PENT AKO NE
ACETONE
BENZENE
BROMODICHLOROMETPJ:,.NE
BROMOFORM
BROMOMET°HANE
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROETHANE
CHLOROFORM
CHLOROMETHANE
CIS-1,2-DICHLOROETHENE
CIS-1,3-DICHLOROPROPENE
DIBROMOCHLOROMETHANE
ETHYLBENZENE
METHYLENE CHLORIDE
STYRENE
TETRACHLOROETHENE
TOLUENE
TRANS-1,2-DICHLOROETHENE
TRANS-I, 3-DICHLOROPROPENE
TRICHLOROETHENE
VINYL ACETATE
VINYL CHLORIDE
XYLENE {TOTAL)
MB32347:l
'
'
'
'
'
'
'
'
'
'
'
'
'
'
'
'
'
'
'
'
'
'
'
'
'
'
Cone
0. 0010
0 .0010
o. 0010
o. 0010
0 .0010
0 .0010
0 .0010
0 .0010
o. 0050
0 .0050
0. 0050
0 .0050
0 .0010
0 .0010
0 .0010
0 .0010
0 .0010
0 .0010
0. 0010
0 .0010
0 .0010
0 .0010
0 .0010
0 .0010
0 .0010
0. 0010
o. 0010
o. 0010
0 . 0010
0. 0010
0. 0010
0 .0010
0 .0010
o. 0010
0 .0010
0. 0020
Report Date December
Page 1 of Report ID:
Matrix GW/ChemW
WorkGroup, WG32347
Qual RDL Units
0 .0010 rng/1
o. 0010 rng/1
o. 0010 mg/1
0 0010 mg/1
0 .0010 mg/1
0 .0010 rng/1
0 .0010 mg/1
0 .0010 rng/1
0. 0050 mg/1
0 . 0050 mg/1
0 .0050 mg/l
o. 0050 mg/1
0. 0010 rng/1
0 .0010 mg/1
0 . 0010 mg/1
0 .0010 mg/1
0 .0010 rng/1
o. 0010 rng/1
o. 0010 mg/1
0 .0010 mg/1
0 .0010 mg/1
0. 0010 mg/1
0 .0010 mg/1
0 .0010 mg/1
0 .0010 mg/1
0 .0010 rng/1
o. 0010 mg/1
0 .0010 mg/1
0 .0010 mg/1
0 .0010 mg/1
0 0010 mg/1
o. 0010 mg/1
o. 0010 mg/1
0 .0010 mg/1
0 .0010 mg/1
0 .0020 mg/1
Davb & Floyd, Inc. I PO Drawer 428 I Greenwood, SC 2964B I 816 E. Durst Avenue I Greenw1uid, SC 2%4<)
53
09, 2002
AA35527
Analyat Date Time
PAP 12/06/02 0908
PAP 12/06/02 0908
PAP 12/06/02 0908
PAP 12/06/02 0908
PAP 12/06/02 0908
PAP 12/06/02 0908
PAP 12/06/02 0908
PAP 12/06/02 0908
PAP 12/06/ :·2 0908
PAP 12/06/:J2 0908
PA? 12/06/02 0908
PAP 12/06/02 0908
PAP 12/06/02 0908
PAP 12/06/02 0908
PAP 12/06/02 0908
PAP 12/06/02 0908
PAP 12/06/02 0908
PAP 12/06/02 0908
PAP 12/06/02 0908
PAP 12/06/02 0908
PAP 12/06/02 0908
PAP 12/06/02 0908
PAP 12/06/02 0908
PAP 12/06/02 0908
PAP 12/06/02 0908
PAP 12/06/02 0908
PAP 12/06/02 0908
PAP 12/06/02 0908
PAP 12/06/02 0908
PAP 12/06/02 0908
PAP 12/06/02 0908
PAP 12/06/02 0908
PAP 12/06/02 0908
PA? 12/06/02 0908
PAP 12/06/02 0908
PAP 12/06/02 0908
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DAYIS
FLOYD LABORATORY ANAl,YSIS REPORT
Matrix Spikes and Duplicates
MS/MSD
Pa·raITlete·r_
1, 1-OICHLOROETHENE
1,2-DICHLOROETHANE
2-BUTANONE
BENZENE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROFORM
TETRACHLOROETHENE
TRICHLOROETHENE
VINYL CHLORIDE
P.il;-aniet·ii ·.
1,1-DICHLOROETHENE
1,2-DICf!LOROET!IJ\NE
2-BUTANONE
BENZENE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROFORM
TETRACHLOROETHENE
TRICHLOROETHENE
VINYL CH LOR IDE
MS02120513-0l:32347
MSD02120513-0l:32347
Spike
··Added_
50. 00
50. 00
50. 00
50. 00
50. 00
50 00
50 .00
50. 00
50. 00
50 00
Spi_ke
"AdAed.
50 .00
50 00
50. 00
50 00
50. 00
50 .00
50. 00
50. 00
50. 00
50. 00
Sample
Cone
< 0 .00100
< 0 .00100
< 0 .00500
< 0 .00100
< o. 00100
< o. 00100
< 0. 00100
< 0. 00100
< 0. 00100
< o. 00100
MSD
C:?.1:1-S:.
43 . 45
52 . 98
47. 19
47. 15
49 . 3 2
48 . 20
49' 71
47 .01
48 .00
38 . 23
Report Date December
Page 1 of Report ID:
:•iacrix GW/Chemw
:·:orkGroup: WG32H7
Xethod
MS
Cone
" .66
52. 52
45 . 69
47. 51
"· 32
47 . 86
50 .2'
45. 99
47. 19
37 . .;3
MSD
: .\REC
87
106
94
94
99
96
99
94
96
76
SW846
MS
%-REC
BS
105
91
95
99
96
100
92
91
75
\RPD
2
0
2
82608
· Lin"li ts
%REC
76-128
78-135
76-168
84-121
74 -120
87 118
80-124
83 -107
78-119
64-124
11
16
40
10
20
10
12
11
10
13
09, 2002
AA35517
76-128
78-135
76-168
84-121
74-120
87-118
80-124
83-107
78-119
64-124
NOTE, MS/MSD %-recoveries are not evaluated if the sample concentration 1s greciter than four times the spike added.
();wi:,; & Floyd, Inc. I PO Drawer 42B I Greenwood, SC 2!J648 I Ul (, E. Ours! AvenuL' I Greenwood, SC 2%49 I (864) 229-441.1 I Fax (H64) 229-7119
54
D~IS
FLfilD LABORATORY ANALYSIS REPORT
Laboratory Control Standards and Duplicates
LCS LCS32347:l
Par?me.ter
1,1-DICHLOROETHENE
1, 2-DlCHLOROF.THANE
2-BUTt\NONE
BENZENE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROF'ORM
TETRACHLOROETHENE
TRlCHL.OR.OETHENE
VINYL CHLORIDE
Spi_k€
Added
20 00
20. 00
20. 00
20, 00
20. 00
20. 00
20. 00
20. 00
20. 00
20 00
LCE!
Con~
19 .45
22 . 54
16 '77
20. 62
21 22
20. 67
21 .68
20. 16
20 .67
16. 92
Report Date December 09, 2002
Page 1 of 1 Report ID, M35514
Matrix GW/Chemw
WorkGroup: WG32347
Method SW846 82608
.·:1·cs·· L.imi'tS
·)'.'REcl· \REC
97 78-126
113 83-135
84 80-149
103 88 -119
106 75-126
103 90-116
108 85-128
101 81-110
1 03 80-115
85 66-141
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D,,vi, & Floyd, Inc. I PO Dcawe,428 I G,eenwoocl, SC 2%48 I 816 ~ ;u,s1 Avenue I G,eenwood, SC 2%49 I (864122')-441:l I fax IB6·1112'J-7ll'J I
Project I Sile Location
61195
Chain of Custody Record
816 E. Durst Avenue. Greenwood, SC 29649 [phone] Fax: {864) 229-7119
Laboratory Certitcation Numbers: SC• 24110, NC• 25, TN -2923, VA -77
Contact Copy To Reporting Requirements: [} Standard { J Data Package (Specify Level)
?e-.uC'~ iJ~,r wl!Ua.., -&r-t.J.-
NOTICE: ~
Sample Collection ~
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Samnle Descriotion Date Time " Type Total C
TRIP BLANK
-
1vomments
Matrix Type DefimUons
Preservative Definitions ---
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ll/z_-,L 1/30
Time Received By
Date Time
/?·Sea. 1'15~
Date Time
1 -Dnnkmg Water 2 -Clean Water 5. Groundwater 7 -S011/Sed1ment 8 -Liquid Sludge 9 -011 12 -Alr
A -None B -H2S04 C -HCI D -HN03 E -NaOH F -Filtered G -Other --------
Required Parameters, Containers and Presen,atives
Re/iquished By Date Time
Fr;;;·;~Ja.vis Date nme
17,.S. 0;>. i lJ.5{,
- - - --
PageJ_at_J__
ice Use uniy
Purchase Order
State Quote
LOQln Special lnstroctions
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Fraction HOT omments o, ~,. -r-r_rL--
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03 "' ,cJr,., l
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en
Qu;,,"(.!) ShciiJ y N °'' CLIENT
" FEOEX
If Y, specify: Airbill Number
,/ days
Coolec 10 ~ble)c -----
Ion Ice: Yes ' o Temp{C) h
Custody Seal: Intact / Broken /
DaVIS & Floyd, Inc.
FL02 _01 (0~9) - -- -
Sampling Log-Grab Water Samples
Project No. 26OS06 Site Location CNA / Ticona -Shelby, NC
Sample Date / z/d :b --+. -'-4.~---Arrival Time __ 0--'-J_~.:....:::2=--Sample Time -~jt:)_-5_0 __ _
Sample ID 5. -r t{Y Field Personnel ~ ----~--
3:>J' Weather ConditionsUl~-Ci,,e,i) Sampling Method 6R46
Sample Temp. (°C) ;J.ff Spec. Conductivity(µS/cm) pH_t:__::.;;~zf----
ORP (mV) !i'tJ.C Turbidity (NTU) __ S,__,,-'Qc.,___-----"DO(mg/L) _ _,___/_. -'-0_J __
Method(s) Vtt-1
Container Description
:?K'(o/11
Preservative !(vi
Remarks
Sample Date __ /_2_,,'-M"'-J..'%-'--~-2,_· _ Arrival Time __ 0-'~c..._~_-.2--__ Sample Time -----'/,-~_~(r __ _
Sample ID Duplicate No. _____ _ Field Personnel---~-(" __ _
Weather Conditio~a:IZ-0601sampling Method
Sample Temp. (°C) / ;J. -fL) Spec. Conductivity(µS/cm) /]£:,/ pH_L/-'97'--
ORP (mV) Turbidity (NTU) _S.,____;_;,"S-'=---_~DO(mg/L) ----'-/--'-', /_O __ _
Method(s)
vtK,s
Container Description
2x~111
Preservative
fie/
Remarks
Kubal-Furr & Associates
Revised 7 /30/02
57
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Calibration Log
Meter Model YSI 556MPS
Meter Serial # 01 G0526
Battery
Conductivity Meter Calibration
Standard µS/cm
Standard Reading µS/cm
Temperature ('C)
pH Meter Calibration
7.0 Buffer
4.0 Buffer
10.0 Buffer
Dissolved Oxygen Calibration
ORP Calibration
DO%
Standard mV
Standard Reading mV
Temperature ('C)
Turbidity Calibration
Meter Model ESD Model 800
Meter Serial # TUR800 358
Battery
Zero Standard (0 NTU)
Ten Standard (10 NTU)
Signature
Date 1(:2,ifk')_ ---+-. __,c.c....... __ _
Time --~l<=D'--'o"'-+/ __ _
/tJ.cJ/
Date_/-+¾-~+-'~~';.--__
Time_· ---'-/4=~-"'c@-=----
-------Kubal-Fur & Associates:--------
Revised 2/22/02
58
Client
KUBAL-FURR& ASSOC.
Ticona site-Shelby,NC,NC.
Contact
Julie Lisenby
Collected By
Project I Site Location
~-G--,C::,,.irtt.,A-U
Chain of Custody Record Page _j_ of+-
816 E. Durst Avenue, Greenwood, SC 29649 (864) 229--4413 Fax: [phone] ice use vn,y
Laboratory Certifca/ion Numbers: SC -24110, NC -25, TN-2923, VA -77
Reporting Requirements: ( J Standard { J Data Package (Specify Level) Purchase Older
Required Parameters, Containers and Preservatives State Quote
NC.
1--------------------------~---+-~-------l----1---+--+--l----1--+--+----11---+---l----l---+~L~O~g~1~n+--JSpecia//nstructions
NOTICE:
c..r,
©
Samole Descriotion
//
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72:17 ....... ___ ...:·-
r..;omments
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Date Time Time -~.., I?/, ~
to:3,o
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",~,/4 1130
Time Re/iquished By
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Time Received By tc.y-z..
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Type Total
;c .s-3 }o
.... ' 3 "" F .r-3 ~
>-;;__ ~ )c;
Date Time Reliquished By
Date Time Received in Laboratory By
Matrix Type Defimt1ons 1 -Dnnking Water 2-Clean Water 5-Groundwater 7 -So1!/Sed1ment 8 -L1qu1d Sludge 9-011 12-Alr
-reserv-nition-None -S04 -D -1-E-Na-Filterf·•·l°ther --- --
..J
Fraction HOT L.;Omments
Ji
Date Time Quick TAT Shipped By
"' CLIENT y N "'' FEDEX
Date Time If Y, specify: Airbi/1 Number
days
Cooler ID (if available)· ----~
On Jee: Yes/ No Temp(C) __ _
Custody Seal: Intact / Broken / None
Davis & Floyd, Inc. - - - -
__ 01-
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Attachment 3
Selected Water-Quality Plots
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Kubal-Furr & Associates
-------------------
ITCI TOC Data
4000 ~----------------------------------------,
3500
3000 --
2500
i ~
C I 2000
~ 0
u 1500
1000
500 --
0 +------+-----+------+------+-----+~---+-----+-----+------t-------1c"
1/1 /93 1 /1 /94 1 /1 /95 l /1 /96 1 2/31 /96 1 2/31 /97 1 2/31 /98 12/31 /99 1 2/30/00 1 2/30/01 12/30/02
Date
---------·----------
j
~
C:
ITCI Ethylene Glycol Data
4000 ~------------------------------------------7
3500
(Unfilled data points represent qualified data
or values below the detection level.)
3000 - - - - - - - - ----- --- - - - - - - - - - - --------- -------- - ------------------------------------------------------------
2500 -------------------------------------------------------------------------------------------------------
12000
8 1500
1000 --------------
500 ------------------------------------
o-l-------1~----+-----+-----+------+-----+-----+------i-----'
10/5/94 10/5/95 10/4/96 10/4/97 10/4/98 10/4/99 10/3/00 10/3/01 10/3/02
Date
-------------------
V-23 TOC Data
14000 -,------------------------------------------,
12000
10000
i 8000
g
sc5i " 6000
8
4000
2000
(Unfilled data points represent qualified data
or values below the detection level.}
0-1------+------4------f---=----+-----+------+------+----~
1/1/85 5/1/87 8/28/89 12/26/91 4/24/94
Date
8/21 /96 1 2/19/98 4/17 /01
-------------------
V-23 2-Butanone (MEK) Data
4~----------------------------------------,
3.5
3
~ 2.5
'a,
E ~
C
.9 2 ~ ~ Q) g
0
u 1.5
0.5
(Unfilled data points represent qualified data
or values below the detection level.)
----------------------------------------------------------------------------------------------
---------------------------------------------------------------------------------------------------
0 -l-_ _.!!.. _ _Q_-4-~~----=~-"""0-----0-+---------tl~------!I--------+----~
6/1/89 6/1/91 5/31/93 5/31/95 5/30/97 5/30/99 5/29/01
Date
-------------------
V-23 Acetone Data
1.4 ~----------------------------------,
1.2
1
(Unfilled data points represent qualified data
or values below the detection level.)
- - -- - - - - --- - - - - - -- -- - - - - - - - - - - -- ----- -- --.-------------------
ol-__ __JL-+------+.:::CL__ __ __._+-------+-__]--'------~-+-----------t---~
6/1/89 6/1/91 5/31/93 5/31/95 5/30/97 5/30/99 5/29/01
Date
-------------------
i -C
V-23 Benzene Data
0.3 ~-----------------------------------------i
0.25
0.2
(Unfilled data points represent qualified data
or values below the detection level.)
0 I 0.15
C
8
0.1
0.05
0+-~-------+-----=--¢-----+------+------t------f------l::I----'
6/1/89 6/1/91 5/31/93 5/31 /95 5/30/97 5/30/99 5/29/01
Sample Date
-------------------
~
K-28 TOC Data
9000 ,-------------------------------------
8000
7000
6000
(Unfilled data points represent qualified data
or values below the detection level.)
--------------------------------------------------------------------------------------------------------
--------------------------------------------------------------------
5 5000
~ s . 8 4000
C
8
3000 ------------------------------------------ -- - - - - - - -- - - -- --- - -- - - - -- -- --- -- - - - - - -·-- - -
2000
1 000 -----------------------------------
o u:w_--+-----+---+----+-........:::::.._=---+::::::...o-e1-..~IS!i----+-~~__.._J
8/14/81 3/21/84 10/27 /86 6/3/89 1/9/92
Date
8/16/94 3/23/97 10/29/99 6/5/02
- -·-- - - - - - - - - - - - - - - -
~E
~
K-28 Benzene Data
0.035 ,--------------------------------------------
0.03
0.025
0.02
(Unfilled data points represent qualified data
or values below the detection level.)
---------------------···------------------------------------------------------------------------
i g 0.015
8
0.01
0.005
o-1---------+------+------+------t-------t---------,t----____J
6/1/89 6/1/91 5/31/93 5/31/95 5/30/97 5/30/99 5/29/01
Date
-------------------
HH-48 TCE Data
0.25 .----------------------------------------------
(Unfilled data points represent qualified data
or values below the detection level.)
0.2 - - - - - - - - - - - - - - - - - - - - - - - - - -
~ 0.15
s
I 8 0.1
0.05
0+-------+------+-------+------+-------+------+--------'
6/30/89 6/30/91 6/29/93 6/29/95 6/28/97 6/28/99 6/27/01
Date
-------------------
HH-77 TCE Data
··-··7
0.45 ········································································································ ···1
'
04 ······································· ····1 . ································································· I
0.35 . . ·!
i 0.3
t 0.25
----J
1 0.2
0.15
0.1 --------------,
I ------------------------------------------------------
'
0.05 · · · · · ·
0~'------+------+------+------1-------1--------t----~
6/1/89 6/1/91 5/31/93 5/31/95 5/30/97 5/30/99 5/29/01
Date