NCD003446721_19950824_Celeanse Corporation - Shelby Fiber_FRBCERCLA RA_Semiannual Operations Report F-Well Extraction System-OCR

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Semiannual Operations Report
F-Well Extraction System
Hoechst Celanese Corporation
Shelby, North Carolina
August 1995
Submitted to
State of North Carolina
Department of Environment, Health, and Natural Resources
Raleigh, North Carolina
Prepared for
Hoechst Celanese Corporation
Shelby, North Carolina
Kubal-Furr & Associates
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Post Office Box 273210
Tampa, FL 33688-3210
813/931-7730
FAX/931-8039
Ms. Kathryn Frank
Hoechst Celanese Corporation
Post Office Box 87
Kubal-Furr & Associates
Environmental Consultants
August 24, 1995
Shelby, North Carolina 28151-0087
Dear Kathryn:
1120 W. Butler Rd., Suite Q
Greenville, SC 29607
803/277-0977
F AX/277 -6626
Kubal-Furr & Associates is pleased to submit four copies of the enclosed report entitled
Semiannual Operations Report-F-Well Extraction System-Hoechst Celanese
Corporation-Shelby, North Carolina. The report covers the operating period from February I,
1995 to July 31, 1995 and includes analytical test results from the May 30, 1995 sampling event.
The next set of semiannual samples is scheduled to be collected in December 1995 with the
next semiannual report to be submitted in February 1996.
Sincerdy,
Kubal--Furr & Associates
,c/ __ ;--· t2.
-=~7:f)PD/L/ lC;JZfl,!,LC'-fc -+dr· /
Jerry E. Kubal
Licensed Geologist
(NC License No. 212)
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Contents
Page
Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . l
Background . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1
System Operation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . l
Analytical Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
Closing Comments . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
Tables
Table 1. Extraction Well Production Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3
Table 2. Summary of Detected Analytes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6
Figures
Figure 1. F-Well Extraction System Location . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2
Figure 2. Plot ofDrawdown for the F-Well Extraction System . . . . . . . . . . . . . . . . . . . . . . 4
Attachments
Attachment 1. Daily Flow Volumes and Maintenance Logs
Attachment 2. Kubal-Furr & Associates-Ground-Water Sampling Logs
Attachment 3. !EA Laboratories-Analytical Test Result~, May 30, 1995 Sampling Event
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Introduction
Hoechst Celanese Corporation (HCC) of Shelby, North Carolina retained Kubal-Furr &
Associates, Inc. (KF&A) to prepare this Semiannual Operations Report for the F-Well Extraction
System. This report documents the system operations from February 1, 1995 to July 31, 1995 and
includes the results of the May 1995 ground-water quality sampling event
Background
HCC installed the F-Well extraction system in August 1993. The system includes four ground-
wate:r/product extraction wells: PEW-1, PEW-2, PEW-3, and PEW-4 (Figure 1). Extracted
ground-water is discharged through an underground sewer line to the on-site wastewater treatment
plant. Treated ground water is discharged to the NPDES permitted outfall. The system was
approved by the state of North Carolina in May 1994 and was put into operation on June I, 1994.
System Operation
From February 1, 1995 through July 31, 1995, the system extracted 2,020,890 gallons of
ground water. No free product was recovered during the current semiannual reporting period.
Table I presents a summary of the total gallons produced and the average daily pumping rates for
each of the extraction wells. The production rates presented in Table I are somewhat lower than
those from the previous semiannual repo1ting period.
The depths to water in the four extraction wells have been measured in the past on a monthly
basis and are now measured quaiterly as part of the system operation and maintenance program.
These values have been plotted on Figure 2, together with the pre-pumping levels measured on
June 1, 1994. This plot shows that the water-level measurements for each of the PEW wells were
below the pre-pumping levels during each quarter of the cmTent reporting pe1iod.
Copies of the daily extraction well flow volumes and system maintenance logs for the F-Well
extraction system are included in Attachment 1.
Kubal-Furr & Associates/Page I
Semiannual Report-F-Wel/ Extraction System
Hoechst Celanese Corporation-Shelby, NC
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0
IT7 lS:J
100 200
• '
" " " " " " " " .. • •
Scale in Feet
Extraction System Location
Hoechst Celanese Corporation
Shelby, North Carolina
□
~
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V-23 ®
Explanation
® Monitor Well
I I Building/Structure
Pond
400
• Extraction Well
Road
r r Slream'Creek
Kubal-Furr & Associates
---Envir01u11cntal Consultants ---
Figure I
Kubal-Furr & Associates/Page 2
Semiannual Report-F-Well Extraction System
Hoechst Celanese Corporation~%elby, NC
-------------------
PEW-1
Total Gallons
Feb-95 300,988
Mar-95 142,434
Apr-95 101,338
May-95 127,989
;;;,
,l g: ~-
" "'
Jun-95 127,664
" "' =,-" " " --Jul-95 116,049 Q~
5"' ~ ~
;:i; C ;:: ' Total 916,462 n:. ::i. c::-~ I e.. .
(') -ri ~ 0 ' ==J ~ ~.., ~ " -, ~;::: ~
~t:-::~ 6' ~ t; .
;:i; j3 C l, Q. ~--. .::::. . ~ § ~ "' "' ~ ':-: ~ '.:I ~~~
Table 1-Extraction Well Production Data
F-Well Extraction System
Hoechst Celanese Corporation
Shelby, North Carolina
PEW-2 PEW-3 PEW-4
Total Gallons Total Gallons Total Gallons
27,182 217,061 246,127
22,669 94,669 122,423
5,192 61,072 55,680
0 45,564 68,374
0 30,029 53,618
23,064 10,638 21,066
78,107 459,033 567,288
Total Gallons
791,358
382,195
223,282
241,927
211,311
170,817
2,020,890
--------------------------------
Figure 2-Plot of Drawdown for the F-Well Extraction System
Hoechst Celanese Corporation
Shelby, North Carolina
: : l • • • • • • • • • • • • • • • • . • • • • • • • • • • • • • • • . • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • . • • • • • • • • • • • •
40.00 I ---------------------------------------------------------------------------------------
§: 50.00 ..
i "" 60.00 .s
..c: C. a,
0 70.00
80.00
90.00
100.00 +-------,-----+----+------+-----+-----+------+-------,
6/1/94 7/19/94 8/22/94 9/21/94 10/19/94 11/21/94 12/26/94 3/6/95 5/17/95
Measurement Date I-+--PEW-1 ----PEW-2 ---½--PEW-3 ~ PEW-4I
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No maintenance activities were required during the semiannual period on wells PEW-1 and
PEW-4. The throttling valve on well PEW-2 was cleaned on February 21, 1995, and the well was
reported to have low or no flow from April 14 to April 22 and no flow from April 22 through the
entire month of June 1995. On July 6, when the pump was replaced, PEW-2 resumed normal
pumping activities. On July 13, the strainer in PEW-2 was cleaned and the well's flow was
adjusted to one gallon per minute. PEW-3 was maintenance-free until July, when it had no flow
from July 17 to July 23. On July 24, the flow meter on PEW-3 was replaced and the well resumed
pumpmg.
Analytical Results
Ground-water samples were collected by KF&A from three extraction wells (PEW-I, -3, -4)
on May 30, 1995 for analysis of volatile and semivolatile organics by EPA Methods 8240 and
8270. Extraction well PEW-2 was down for repairs at the time of sampling. Copies of the
sampling logs and the laboratory reports are included in Attachments 2 and 3, respectively.
No volatile or semivolatile organic compounds were reported as present above the detection
limits in samples from well PEW-3. The only constituent reported as present in PEW-I and PEW-
4 was the volatile organic compound trichloroethene, at concentrations of 10 µg/L and 98 µg/L,
respectively. Table 2 is a summary of the analytes reported above the detection limits in the May
1995 data set.
Closing Comments
With the exception of the downtime reported at PEW-2, the F-Well extraction system
performed according to design. No free product was recovered during the rep01ting period, and no
volatile or semivolatile constituents were reported above quantitation limits with the exception of
trichlorocthene in wells PEW-1 (10 µg/L) and PEW-4 (98 µg/1). The next sampling event is
scheduled for November 1995 with the next report due to DEHNR in February 1996.
Kubal-Furr & Associates/Page 5
Semiannual Report-F-Well Extraction System
Hoechst Celanese Corporation-Shelby, NC
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Table 2-Summary of Detected Analytes
F-Well Extraction System
Hoechst Celanese Corporation
Shelby, North Carolina
Analyte PEW-1 PEW-2 PEW-3 PEW-4
Volatiles
(Method 8240)
Trichloroctl1ene 10 NS BQL 98
Semivolatiles
(Method 8270) BQL NS BQL BQL
Noles: Samples collecLCd on May 30,1995
All conccntralions reported in µg/L (ppb)
BQL: Below Quanlitalion Limit
NS: Not Sampled
Kubal-Furr & Associates/Page 6
Semiannual Report-F-Well EXJraction System
Hoechst Celanese Corporation-Shelby, NC
I F55WELLS.WK1
I F-55 DAILY FLOW GALLONS
I
FEBRUARY
I 1995 PEW-1 PEW-2 PEW-3 PEW-4
02/01/95 4749 374 3393 4754
I 02/02/95 4731 373 3379 4633
02/03/95 4735 299 3380 4124
02/04/95 4736 290 3417 3913
I 02/05/95 4748 323 3476 3904
02/06/95 4717 0 3162 3895
02/07/95 4745 0 3399 3848 I 02/08/95 4652 0 2782 3840
02/09/95 4918 0 3304 3815
02/10/95 4881 1 3510 3797 I 02/11/95 4861 0 3536 3643
02/12/95 4903 0 3489 3418
I 02/13/95 4913 0 3392 3542
02/14/95 851 0 3357 3593
02/15/95 8908 0 3223 3672
I 02/16/95 4876 0 3629 3695
02/17/95 5070 0 3678 3868
02/1,9/95 4713 0 3458 3630
I 02/19/95 4882 0 3563 3837
02/20/95 4868 0 3554 3844
02/21 /95 4882 972 3567 3857
I 02/22/95 4892 1036 3565 3725
02/2:3/95 4888 1041 3557 3846
02/24/95 4879 649 3528 3699
I 02/2fi/95 4890 955 3528 3770
02/2Ei/95 4874 969 3510 3808
02/27/95 4869 936 3493 3889
I 02/28/95
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AVG 4838 304 3438 3847
I MAX 8908 1041 3678 4754
MIN 851 0 2782 3418
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I F55WELLS.WK1
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I F-55 DAILY FLOW GALLONS
I MARCH
1995 PEW-1 PEW-2 PEW-3 PEW-4
I 03/01 /95 4839 802 3459 3864
03/02/95 4899 808 3496 4050
I 03/03/95 4803 819 3470 4135
03/04/95 4763 808 3401 4157
I 03/05/95 4819 790 3444 4106
03/06/95 4839 815 3477 4339
03/07 /95 4863 808 3446 4266
I 03/08/95 4814 796 3358 4377
03/09/95 4713 769 3363 4429
03/10/95 4687 760 3333 4602
I 03/11/95 4704 733 3339 4856
03/12/95 4677 754 3315 5059
03/13/95 4686 753 3221 5162
I 03/14/!}5 4648 812 3210 4991
03/15/!}5 4599 739 3151 4712
03/16/!)5 4661 740 3174 4951
I 03/17/!)5 4591 737 3125 5118
03/18/95 4605 729 3095 5363
03/19/[)5 4685 729 3107 5530
I 03/20/95 4548 719 3067 4988
03/21/95 4614 724 3097 5263
03/22/95 4498 736 3043 5071
I 03/23/95 4575 745 3067 4494
03/24/95 4391 717 2995 4280
03/25/95 4420 713 3020 4387
I 03/26/95 4511 730 3030 4425
03/27/95 4350 722 2929 3591
03/28/95 4361 726 2902 2130
I 03/29/95 4396 727 2893 1704
03/30/95 4315 737 2827 1763
03/31/95 4323 736 2840 2508
I AVG 4619 756 3184 4280
i MAX 4899 819 3496 5530
I MIN 4315 713 2827 1704
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I F55WELLS.WK1
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I F-55 DAILY FLOW GALLONS
I APRIL
1995 PEW-1 PEW-2 PEW-3 PEW-4
I 04/01 /95 4157 719 2748 2553
04/02/95 4237 727 2808 2783
I 04/03/95 4221 667 2838 2666
04/04/95 8429 1322 5659 4899
04/05/95 4198 662 2744 2034
I 04/06/95 4178 648 2763 2134
04/07/95 4177 633 2763 1940
04/08/95 4103 612 2714 1792 I 04/09/95 4122 596 2660 1940
04/10/95 4192 584 2654
I 04/11/95 4032 562 2634 3408
04/12/95 4040 646 2575 1900
04/13/95 4075 525 2568 1507
I 04/14/95 4036 403 2518 1913
04/15/95 4050 307 2528 2201
04/16/95 3950 177 2485 2204
I 04/17/95 4020 94 2509 2142
04/18/95 4073 33 2496 2119
04/19/95 4067 15 2435 2107
I 04/20/95 4038 3 2397 2335
04/21 /95 3989 1 2402 2352
04/22/95 3960 1 2359 2341
I 04/2:3/95 4082 0 2:345 2254
04/24/95 4063 0 2302 2235
04/25/95 4039 0 2338 2541
I 04/26/95 4058 0 2332 2549
04/27 /95 4087 0 2304 2642
04/28/95 3929 0 2171 2502
I 04/29/95 3979 0 2204 2819
04/30/95 4162 0 2266 3122
I AVG 4225 331 2617 2412
MAX 8429 1322 5659 4899
I MIN 3929 0 2171 1507
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F55WELLS.WK1
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I F-55 DAILY FLOW GALLONS
I MAY
I 1995 PEW-1 PEW-2 PEW-3 PEW-4
05/01 /95 4013 0 2113 2815
I 05/02/95 4086 0 2086 2790
05/03/95 4042 0 2018 2806
05/04/95 4056 0 1956 2966
I 05/05/95 4008 0 1929 2486
05/06/95 4033 0 1592 2036
05/07/95 4169 0 2142 2007
I 05/08/95 4179 0 1789 2259
05/09/95 4110 0 1719 2570
05/10/95 4119 0 1699 2318
I 05/11/95 4188 0 1662 2030
05/12/95 4257 0 1622 2159
05/13/95 4304 0 1631 2293 I 05/14/95 4491 0 1686 2429
05/15/95 4192 0 1554 2018
I 05/16/95 4248 0 1503 1937
05/17/95 4071 0 1438 1943
05/18/95 4064 0 1406 1742
I 05/19/95 4170 0 1333 2151
05/20/95 4500 0 1359 2391
05/21 /95 4407 0 1297 2337
I, 05/22/95 4374 0 1294 2424
05/23/95 4295 0 1238 2404
05/24/95 4139 0 1139 2357
I 05/25/95 3933 0 1095 2238
05.126/95 3929 0 1083 1980
05/27 /95 3955 0 1051 1854
I 05/28/95 4050 0 1061 1837
05/29/95 3998 0 1066 1825
05/30/95 3883 0 1004 2014 I 05/31 /95 3872 0 1049 2066
I AVG 4133 0 1504 2241
MAX 4500 0 2142 2966
MIN 3872 0 1004 1742
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I F55WELLS.WK1
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I F-55 DAILY FLOW GALLONS
I JUNE
1995 PEW-1 PEW-2 PEW-3 PEW-4 I 06/01/95 3867 0 1063 1707
06/02/95 3951 0 1056 1816 I 06/03/95 3929 0 1049 1989
06/04/95 3687 0 1043 1728
I 06/05/95 3847 0 1044 1938
06/06/95 3892 0 997 1898
06/07 /95 3818 0 980 1828
I 06/08/95 3781 0 988 1506
06/09/95 3940 0 1004 1860
06/10/95 3899 0 1014 2082
I 06/11/95 3937 0 1015 2190
06/12/95 4034 0 999 2129
06/13/95 4315 0 1060 1865
I 06/ 14/95 4422 0 1028 1660
06/15/95 4415 0 984 1463
06/16/95 4207 0 951 1522
I 06/'17/95 4140 0 980 1764
06/'18/95 4029 0 939 1472
06/19/95 4438 0 923 1431
: I 06/~10/95 4170 0 945 1834
06/21 /95 4105 0 939 1935
06/22/95 4004 0 894 1763
I 06/23/95 3882 0 854 1847
06/24/95 3913 0 858 2046
06/25/95 3781 0 844 1453
I 06/26/95 3798 0 858 1372
06/27/95 3874 0 830 1343
06/28/95 3872 0 827 1355
I 06/2!3/95 3895 0 802 1294
06/30/95 3966 0 780 1053
I AVG 3994 0 952 1705
MAX 4438 0 1063 2190
I MIN 3687 0 780 1053
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I F-55 DAILY FLOW GALLONS
I JULY
1995 PEW-1 PEW-2 PEW-3 PEW-4
I 07/01/95 3934 0 781 1413
07/02/95 3889 0 863 1464
I 07/03/95 3900 0 900 1305
07/04/95 3901 0 864 1201
07/05/95 3837 0 798 1075
I 07/06/95 3764 0 775 977
07/07/95 3801 942 809 1107
07 /08/95 3981 949 835 1090
I 07/09/95 3832 938 795 1049
07/10/95 3785 925 752 905
07/11/95 3849 1017 725 778
I 07/12/95 3808 1068 727 40
07/13/95 3888 1108 722 936
07/14/95 3855 1013 1029 722
I 07/15/95 3832 943 398 638
07/16/95 3868 811 79 745
07/17/95 3944 774 0 594
I 07/18/95 3929 766 0 575
07/19/95 3855 685 0 458
07/20/95 3883 668 0 632
I 07/21/95 3794 733 0 776
07/22/95 3979 849 0 666
07/23/95 3968 863 0 549
I 07/24/95 3959 886 53 537
07/25/95 3852 890 142 535
07/26/95 3879 875 129 530
I 07/27/95 3835 827 151 535
07/28/95 3791 798 138 645
07/29/95 3856 789 145 583
I 07/30/95 3979 752 151 518
07/31/95 3933 815 136 535
I AVG 3876 699 416 778
MAX 3981 1108 1029 1464
MIN 3764 0 0 40
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MAINTENANCE ACTIVITIES GROUNDWATER
F-55 EXTRACTION WELLS
OPERABLE UNIT# 1
DATE LOCATION PROBLEM ACTION DATE ACTION MECHANIC
07/06/95 PEW#2 NOFLOW 07/06/95 REPLACEDPUMP JPPP
07/13/95 PEW#2 LOWFLOW 07/13/95 CLEANEDSTRAINER
ADJUSTED FLOW TO 1 GPM JP PP
07/24/95 PEW#3 NOFLOW 07/24/95 REPLACEDFLOWMETER JP
NOTES: PEW# 2 LOW OR NO FLOW FROM 04/14/95 TO 06/30/95
INSTALLED NEW PUMP IN PEW# 2 07/06/95
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I 1,
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MAINTENANCE ACTIVITIES GROUNDWATER
F-55 EXTRACTION WELLS
F55WELLS.WK1
DATE LOCATION PROBLEM ACTION DATE ACTION MECHANIC NOTES
Page 4 of 4
PEW#2OUTOF
SERVICE FROM
09/16/94TO 10/12/94
FOR PUMP. INSTALLED
NEW PUMP.BACK IN
SERVICE
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MAINTENANCE ACTIVITIES GROUNDWATER
F-55 EXTRACTION WELLS
F55WELLS.WK1
DATE LOCATION PROBLEM ACTION DATE ACTION MECHANIC I 02/07195 PEW#2 NOFLOW 02/21/95 CLEANEDTHROTTLINGVALVE JPPP
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NOTES
PEW#:! OUT OF SERVICE FROM 09/16/94
TO 10/12/94 FOR PUMP.
INSTALLED NEW PUMP.BACK IN SERVICE
Page 4 of 4
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MAINTENANCE ACTIVITIES GROUNDWATER
F-55 EXTRACTION WELLS
DATE LOCATION
F55WELLS.WK1
PROBLEM
NO MAINTENANCE ACTIVITlES REPORTED IN APRIL.
OPERABLE UNIT# 1
ACTION DATE ACTION MECHANIC
Page 4 of 4
NOTES
PEW# 2 LOW OR NO FLOW FROM
04/14/95 TO 04/30/95
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F55WELLS.WK1
MAINTENANCE ACTIVITIES GROUNDWATER
OPERABLE UNIT# 1
F-55 EXTRACTION WELLS
DATE LOCATION PROBLEM ACTION DATE ACTION
NO MAINTENANCE ACTIVITIES REPORTED IN MAY.
PEW# 2 NO FLOW MONTH OF MAY
NOTES
PEW# 2 LOW OR NO FLOW FROM 04/14/95 TO 04/30/95
Page 4 of 4
MECHANIC
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F55WELLS.WK1
MAINTENANCE ACTIVITIES GROUNDWATER OPERABLE UNIT# 1
F-55 EXfRACTION WELLS
DATE LOCATION PROBLEM ACTION DATE ACTION MECHANIC
NO MAINTENANCE ACTIVITIES REPORTED IN JUNE.
PEW# 2 NO FLOW MONTH OF JUNE.
NOTES
PEW# ii LOW OR NO FLOW FROM 04/14/95 TO 06/30/95
Page 4 of 4
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WATER SAMPLING LOG
Kubal-Furr & Associates
C11uinn1111c:11l11l 5cr11iccs
Prujcct Nu. £\.\ u L(,, {2.Qo I
!iomplu ID (ttc,J-I Oupllcolo Nu.
Dc,scriplion ol Mensurinu Polnl (MP)
l I
Silo Locolion
-
Puuo
Dole
Timo
MP Elcvolion
Tolul Dcplh ol Well Delow MP _______ _ Dcplh lo Wolcr Dolow MP --Wulcr-Levcl Elovolion
Wnlor Column in Well
Gnllono ol Wulcr per Fool
Gullono uf Waler In Well
GnllonG to llo Evocuotcll
Evncuutlun Methot.I
Cosinu Typo (PVC, SS, clc.)
Cosinu Dinmeler (incheo)
-
Well Cuslnu Volumes (uni/II)
Stml
Timo
1-1/4 .. .,. 0.077
1-1/2 .. -;, 0.100
2 .. a 0.100
2• 1f.2" n 0.240
IL, OD SloJ>
J "n O.J70
J-112." .,.. 0.500
4,. n 0,650
G"'""' 1.460
Tlmo _____ _
(__.l6Lt.i►/ Field Parameters
Culur
pH
(, ( ~r\y --\~
b. l-/,,s
Wcnthcr ComJiliono
Odor
ConUuclivily
Sumplinu Method and Molcrlnlc
.GumplcG Cullcclc<..I
Sampling Data
Container Ococripliun Prc5crvulivc
t/c),,/ \JD.A /iC,L,
I _..,J___ C:~,,155 /f.&tc ___ ._~ ____ _
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WATER SAMPLING LOG
Kubal-Furr & Associates
Cm,irnumculal Scn1focs
Puuo
Dole
limo
Project No.
l I
Silo Locnliun
Samplu 10
Description or Menaurinu Point {MP)
Tulul Depth ur Well Dcluw MP --------,-
Wo,ter-level Elovolion
Sumplcr•s Nnmo
MP Elcvollon
Depth to Waler Deluw MP'.
_,/"
/
,·
Cosinu Typo {PVC, SS, etc,)
Cosing Di~er {inchco) Wnlor Column in Well
Gnllono or Woler per Fool Well Coslnu Volumes (uni/II)
Gallono of Wulcr In Well
GollunG lo Uo C:.vacuatctl
Stml
1-1/4""" 0.0/T
1-1/2".,. 0.100
2" .. 0.100
2-tfl .. -= 0.240
SloJ>
J " .. O.J70
J-1/l" n 0.500
4'"" O.GJO
6"-= V1G0
Evncuullun Method Timo _____ _ Tlmo _____ _
Field Parameters
Color------:,'--Odor
pll Conductlvily
Wenlher Condiliono
Sumplinu Mctho<l um.I Motcrlnls
Sumplc& Collcctc<l
T cmpcroluro
Other ____________ _
Sampling Dala
Container Dcocripliun Prcsc1vulivc ---------,,,.,,,,,,,.,-::-------/--,,-
nonmrko
) 1 b l()u r S u1 ~ Lf
(.)1 ~ vr."""'-7 S 'i r",
,.,,,_ t (Y.,,., 7 t!.J-':::,<r:,J)\,1 Lc
.. · r'\.l/·,v IL--
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WATER SAMPLING LOG
Kubal-Furr & Associalcs
C11uin1111111:11l1d Scnikcs
Project Nu. C1Joz_0e_Po(
Somplo 10 '?--'icJ, --~
Oupllculo No.
I I
Silo Locolion
Pouo
Dole
Timo
Doscriplion ul Mcoourinu Polnl (MP) ---Tolul Deplh ol Well Dclow MP _______ _
Wnlcr-Lcvel Elcvolion
MP Elcvolion
Dcplh lo Wulcr Oclow MP
Casinu Type (PVC, SS, elc.)
Cooinu Dinmeler (incheo) Wnlor Column in Well
Gnlluno ol Wnler per Foul Well Cuslnu Volumes (uni/II)
Gu[lo110 ol Wolcr 111 Well
GnllonG lo Uo E.vucuotcd
Evncuullon Mclhm.l
1-1/4"' .. 0.077
1-1/2".., 0.100
2"'a0,100
2• 112,. C 0.240
Stop
Tlmo
J "a O.J/0
J-11.:.r .,. 0.500
., .. .,, o.c.:.o
G" r:r V1G0
Field Parameters
Color C l-7',/J--y\._
G,,~;-~ pH
Wcolhcr Condiliono
Ouor
ConUucllvity
C.,,([)l-1 /J ·-i
!imnplinu Mctho<.I und Mnlcrlol&
!;uniplc& Collected
rlomurko
Tcntpcroluro
S c ) . ---'-,.{-~-..:_~ Other ___________ _ B,, h r::
Sampling Data
Container Dcncription Prc5c1vulivc
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WATER SAMPLING LOG
Kubal-Furr & Associates
C11vi11111111c11t,1l Scr11ias
Prujccl Nu •
.Smnplo ID Oupllculo Nu.
Doscriplion ol Mensurinu Polnl (MP)
I I
Sito Locnlion
Puuo
Dute
Timo
S111nplor':a Nnmo
Ml' E.lcvotion
Tulol Dcplh ol Well Ueluw MP _______ _ Depth lo Wotcr Dclow MP
Wuler-levcl Elevolion
Wnlor Column in Well
-Cosinu Type (PVC, SS, elc.)
Cosinu Diomeler (incheo)
Gnllono ol Wulcr per Fool Well Cnslnu Volumes (uni/II)
Gulluno o( Wotcr In Well
GnllonG to Uo Evucuotcd
Evm;uutlun Mctho<l
Color __ l_l_t_4_-_rL_· __
(,, z_·;z,
Wc:mlhcr Conc..lillono
O<lor
Slml
Time
Field Parameters
1-1/4" n 0.077
1·1/2".., O. IOO
2 .. .., 0.100
2-tfl" n 0.240
T cmpcroluro
J .. .,, O.J70
J-1/2" "0.500
., .. n 0.650
G" r:. 1.4GO
Slop ·-2,.2 ..... Thno _l_~......c.•·---
Com.luctlvlly :5:1,,\ 5, lcil!) Olhcr ------------
(_ ( o1.., ~-1 I I
Sampling Data
Sumplinu Mctho<l um.I Molcrlols
Suinplcs Cullcctcc.J Container Ococriplion Prcscrvulivc
rlomarko
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1•
Attachment 3
IEA Laboratories-Analytical Test Results
May 30, 1995 Sampling Event
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IEA, Inc
IEA Project NO.: 619_699
SDG: 06018
Client Project ID: GV026M104
Complete Data Package
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Table Of Contents
Master Tracking List--------------------------------00.L
Narrative--------------------------------------~----002
Method 8240-----------------------------------------003
Method 8270----------------------------------------··019
Chain of Custody------------------------------------055
-------------------
0
0 -
SAMPLE ID
PEW-4
PEW-4
PEW-3
PEW-3
PEW-I
PEW-!
TRIP BLANK
LABID
950601801
950601801
950601802
950601802
950601803
950601803
950601804
MASTER SAMPLE TRACKING LIST
DATE DATE ANALYSIS
SAMPLED RECEIVED TYPE PREP DATE ANALYSIS DATE
05/30/95 06/01/95 8240 VOA 06/05/95
05/30/95 06/01/95 8270 SY 06/05/95 06/08/95
05/30/95 06/01/95 8240 VOA 06/05/95
05/30/95 06/01/95 8270 SY 05/05/95 06/08/95
05/30/95 06/01/95 8240 VOA 06/05/95
05/30/95 06/01/95 8270 SY 06/05/95 06/08/95
05/30/95 06/01/95 8240 VOA 06/05/95
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June 28, 1995
Kathryn Frank
Hoechst Celanese, Corp.
P.O. Box 87
Shelby, North Carolina 28151-0087
IEA Project No.:
IEA Reference No.:
Client Project I. D.:
Dear Ms. Frank:
619699/9506018
W9505489
GV026Ml04
Please find enclosed the results of analyses on four samples submitted to our laboratory.
The sample(s) were received intact.
Analyses were performed according to approved methodologies and meet the requirements of
the IEA Quality Assurance Program except were noted. Please see the enclosed reports for your
results and a copy of the Chain of Custody documentation.
Thank you for selecting IEA for your sample analysis. Please do not hesitate to call your
project manager should you have any questions regarding this report. Please feel free to use our
toll free number, l-800-444-9919. We look forward to serving you in the future.
Very truly yours,
IEA, Inc
~4/y~V e &,,.___,
/ ,7'-<7
William R. Drago
Laboratory Director
002
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IEA
PROJECT:619-699
SDG NARRATIVE VOLATILE FRACTION
BATCH:06018 METHOD:SW-846 (8240)
Samples: Four (4) Water Samples
The samples were received at Industrial and Environmental Analysts, Inc. (IEA) on June 01, 1995. Each
sample was assigned a 9-character "IEA" lab identification number (lab ID) and a truncated client ID (for
forms generation). This package makes reference to these ID's as listed on the IEA Assigned Number
Index. All analyses were performed according to approved methodologies and meet the requirements of
the IEA Quality Assurance Program. Please see the enclosed data package for your results and Chain
of Custody (COC) documentation.
The nonconformances associated with the analysis of the samples in this case are as follows:
Sample number 01 (client ID PEW4) was used for the water Matrix Spike and Matrix Spike Duplicate
(MS/MSD). Due to inconsistent recoveries between the original analysis and the MS/MSD analyses
Trichloroethene has a Relative Percent Difference (%RPO) above the method specified limit. In addition
the percent recovery in the MS is below the method specified limit for this compound.
I certify that this data package is in compliance with the procedures and methods defined for this project,
both technically and for completeness, for other than the conditions detailed above. Release of the data
contained in this hardcopy data package and in the computer-readable data (if applicable) as submitted
has been authorized by the laboratory manager or his designee, as verified by the following signature.
Brian D. Neptune
Lead Analyst, GC/MS Final Review
!EA, Inc.
II¼, Inc Doc# Rl'FOOWt.NC
003
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Lab Sample Number
9506018-01
9506018-02
9506018-03
9506018-04
IEA Assigned Number Index
Case No.: 619-699
SDG No.: 06018
Sample Number
PEW-4
PEW-3
PEW-1
TRIP BLANK
Abbreviated
Sample Number
PEW4
PEW3
PEWl
TB
004
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lA CLIENT SAMPLE NO.
SW-846 VOLATILE ORGANICS ANALYSIS DATA SHEET
Lab Name: INDUSTRIAL & ENVIRONMENTA I Lab Code: IEA Case No.: 619-699
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Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
% Moisture: not dee.
GC Column:DB-624
5.0 (g/mL) mL
LOW
PEWl
Method: 8240
SDG No.: 06018
Lab Sample ID: 950601803
Lab File ID: 0605513.D
Date Received: 06/01/95
Date Analyzed: 06/05/95
Dilution Factor: 1.0 I Soil Extract·Volume:
ID: 0. 53 (mm)
___ (UL) Soil Aliquot Volume: ___ (uL)
CONCENTRATION UNITS: I CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q
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74-87-3---------Chloromethane
74-83-9---------Bromomethane
75-01-4---------Vinyl Chloriae
75-00-3---------Chloroethane
75-09-2---------Methylene Chloride
67-64-1---------Acetone
75-15-0---------carbon Disulfide
75-35-4---------1,1-Dichloroethene
75-34-3---------1,1-Dichloroethane
540-59-0--------1,2-Dichloroethene (total)_
67-66-3---------Chloroform
107-06-2--------1,2-Dichloroethane
78-93-3---------2-Butanone
108-05-4--------Vinyl Acetate
71-55-6---------1,1,1-Trichloroethane
56-23-5---------Carbon Tetrachloride
75-27-4---------Bromodichloromethane
78-87-5---------1,2-Dichloropropane
10061-01-5------cis-1,3-Dichloropropene
79-01-6---------Trichloroethene
124-48-1--------Dibromochloromethane
110-75-8--------2-Chloroethylvinyl Ether
79-00-5---------1,1,2-Trichloroethane --
71-43-2---------Benzene
10061-02-6------trans-1,3-Dichloropropene __
75-25-2---------Bromoform
108-10-1--------4-Methyl-2-Pentanone
591-78-6--------2-Hexanone
127-18-4--------Tetrachloroethene
79-34-5---------1,1,2,2-Tetrachloroethane
108-88-3--------Toluene --
108-90-7--------Chlorobenzene
100-41-4--------Ethylbenzene
100-42-5--------styrene
1330-20-7-------Xylene (total)
FORM I VOA
10 u
10 u
10 u
10 u
5 u
10 u
5 u
5 u
5 u
5 u
5 u
5 u
10 u
10 u
5 u
5 u
5 u
5 u
5 u
10
5 u
10 u
5 u
5 u
5 u
5 u
10 u
10 u
5 u
5 u
5 u
5 u
5 u
5 u
5 u
3/90
005
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lA CLIENT SAMPLE NO.
SW-846 VOLATILE ORGANICS ANALYSIS DATA SHEET
Lab Name: INDUSTRIAL & ENVIRONMENTA
Lab Code: IEA Case No.: 619-699
Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
5.0 (g/mL) mL
LOW
PEW3
Method: 8240
SDG No.: 06018
Lab Sample ID: 950601802
Lab File ID: 0605512.D
I % Moisture: not dee.
Date Received: 06/01/95
Date Analyzed: 06/05/95
Dilution Factor: 1.0
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GC Column:DB-624
Soil Extract Volume:
ID: 0. 53 (mm)
____ (uL) Soil Aliquot Volume: ___ (uL)
CONCENTRATION UNITS:
CllS NO. COMPOUND (ug/L or ug/Kg) UG/L Q
74-87-3---------Chloromethane 10 u
74-83-9---------Bromomethane 10 u
75-01-4---------Vinyl Chloride 10 u
75-00-3---------Chloroethane 10 u
75-09-2---------Methylene Chloride 5 u
67-64-1---------Acetone 10 u
75-15-0---------carbon Disulfide 5 u
75-35-4---------1,1-Dichloroethene 5 u
75-34-3---------1,1-Dichloroethane 5 u
540-59-0--------1,2-Dichloroethene (total) 5 u
67-66-3---------Chloroform -5 u
107-06-2--------1,2-Dichloroethane 5 u
78-93-3---------2-Butanone 10 u
108-05-4--------Vinyl Acetate 10 u
71-55-6---------1,1,1-Trichloroethane 5 u
56-23-5---------carbon Tetrachloride 5 u
75-27-4---------Bromodichlorornethane 5 u
78-87-5---------1,2-Dichloropropane 5 u
10061-01-5------cis-1,3-Dichloropropene 5 u
79-01-6---------Trichloroethene 5 u
124-48-1--------Dibrornochlorornethane 5 u
110-75-8--------2-Chloroethylvinyl Ether 10 u
79-00-5---------1,1,2-Trichloroethane --5 u
71-43-2---------Benzene 5 u
10061-02-6------trans-1,J-Dichloropropene __ 5 u
75-25-2---------Bromoforrn 5 u
108-10-1--------4-Methyl-2-Pentanone 10 u
591-78-6--------2-Hexanone 10 u
127-18-4--------Tetrachloroethene 5 u
79-34-5---------1,1,2,2-Tetrachloroethane 5 u
108-88-3--------Toluene --5 u
108-90-7--------Chlorobenzene 5 u
100-41-4--------Ethylbenzene 5 u
100-42-5--------styrene 5 u
1330-20-7-------Xylene (total) 5 u
FORM I VOA 3/90
006
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lA CLIENT SAMPLE NO.
SW-846 VOLATILE ORGANICS ANALYSIS DATA SHEET
Lab Name: INDUSTRIAL & ENVIRONMENTA
Lab Code: IEA Case No.: 619-699
Matrix: (soil/water) WATER
PEW4
Method: 8240
SDG No.: 06018
Lab Sample ID: 950601801
I Sample wt/vol: 5.0 (g/mL) mL
LOW
Lab File ID: 0605509.D
Level: (low/med) I % Moisture: not dee.
Date Received: 06/01/95
Date Analyzed: 06/05/95
Dilution Factor: 1.0
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GC Column:DB-624
Soil Extract Volume:
ID: 0.53 (mm)
___ (UL) Soil Aliquot Volume: ___ (uL)
CONCENTRATION UNITS:
CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q
74-87-3---------Chloromethane
74-83-9---------Bromomethane
75-01-4---------Vinyl Chloride
75-00-3---------Chloroethane
75-09-2---------Methylene Chloride
67-64-1---------Acetone
75-15-o---------carbon Disulfide
75-35-4---------1,1-Dichloroethene
75-34-3---------1,1-Dichloroethane
540-59-0--------1,2-Dichloroethene
67-66-3---------Chloroform
(total) -
107-06-2--------1,2-Dichloroethane
78-93-3---------2-Butanone
108-05-4--------Vinyl Acetate
71-55-6---------1,1,1-Trichloroethane
56-23-5---------carbon Tetrachloride
75-27-4---------Bromodichloromethane
78-87-5---------1,2-Dichloropropane
10061-01-5------cis-1,3-Dichloropropene
79-01-6---------Trichloroethene
124-48-1--------Dibromochloromethane
110-75-8--------2-Chloroethylvinyl Ether
79-00-5---------1,1,2-Trichloroethane --
71-43-2---------Benzene
10061-02-6------trans-1,3-Dichloropropene
75-25-2---------Bromoform --
108-10-1--------4-Methyl-2-Pentanone
591-78-6--------2-Hexanone
127-18-4--------Tetrachloroethene
79-34-5---------1,1,2,2-Tetrachloroethane
108-88-3--------Toluene --
108-90-7--------Chlorobenzene
100-41-4--------Ethylbenzene
100-42-5--------styrene
1330-20-7-------Xylene (total)
FORM I VOA
10
10
10
10
5
10
5
5
5
5
5
5
10
10
5
5
5
5
5
98
5
10
5
5
5
5
10
10
5
5
5
5
5
5
5
u u
u u
u u
u
u u
u u
u u
u
u
u
u
u
u
u
u u u u
u
u
u
u u u
u
u
u
u
3/90
007
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lA CLIENT SAMPLE NO.
SW-846 VOLATILE ORGANICS ANALYSIS DATA SHEET
Lab Name: INDUSTRIAL & ENVIRONMENTA
Lab Code: IEA Case No.: 619-699
Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
5.0 (g/mL) mL
LOW
TB
Method: 8240
SDG No.: 06018
Lab Sample ID: 950601804
Lab File ID: 0605514.D
I % Moisture: not dee.
Date Received: 06/01/95
Date Analyzed: 06/05/95
Dilution Factor: 1.0
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GC Column:DB-624
Soil Extract Volume:
ID: 0. 53 (mm)
___ (uL) Soil Aliquot Volume:
CAS NO. COMPOUND
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L
74-87-3---------Chloromethane
74-83-9---------Bromomethane
75-01-4---------Vinyl Chloriae
75-00-3---------Chloroethane
75-09-2---------Methylene Chloride
67-64-1---------Acetone
75-15-0---------carbon Disulfide
75-35-4---------1,1-Dichloroethene
75-34-3---------1,1-Dichloroethane
540-59-0--------1,2-Dichloroethene
67-66-3---------Chloroform
(total) -
107-06-2--------1,2-Dichloroethane
78-93-3---------2-Butanone
108-05-4--------Vinyl Acetate
71-55-6---------1,1,1-Trichloroethane
56-23-5---------carbon Tetrachloride
75-27-4---------Bromodichloromethane
78-87-5---------1,2-Dichloropropane
10061-01-5-~----cis-1,3-Dichloropropene
79-01-6---------Trichloroethene
124-48-1--------Dibromochloromethane
110-75-8--------2-Chloroethylvinyl Ether
79-00-5---------1,1,2-Trichloroethane --
71-43-2---------Benzene
10061-02-6------trans-1,3-Dichloropropene
75-25-2---------Bromoform --
108-10-1--------4-Methyl-2-Pentanone
591-78-6--------2-Hexanone
127-18-4--------Tetrachloroethene
79-34-5---------1,1,2,2-Tetrachloroethane
108-88-3--------Toluene --
108-90-7--------Chlorobenzene
100-41-4--------Ethylbenzene
100-42-5--------styrene
1330-20-7-------Xylene (total)
FORM I VOA
10
10
10
10
5
10
5
5
5
5
5
5
10
10
5
5
5
5
5
5
5
10
5
5
5
5
10
10
5
5
5
5
5
5
5
__ (uL)
Q
u u u u
u u
u u u
u
u
u u u u
u u
u
u
u
u
u u
u u
u
u
u u u u u u
u u
3/90
008
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4A CLIENT SAMPLE NO.
SW-846 VOLATILE METHOD BLANK SUMMARY
Lab Name: INDUSTRIAL & ENVIRONMENTA
Lab Code: IEA Case No.: 619-699
Lab File ID: 0605502.D
Date Analyzed: 06/05/95
GC Column:DB-624
Instrument ID: MSD5
ID: O. 53 (mm)
VBLK5T
Method: 8240
SDG No.: 06018
Lab Sample ID: VBLK5T
Time Analyzed: 1038
Heated Purge: (Y/N) N
THIS METHOD BLANK APPLIES TO THE FOLLOWING SAMPLES, MS AND MSD
COMMENTS:
01
02
03
04
05
06
07
08
09
10
J.l
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
2B
29
3 ()
C.1.,.cENT
SAMPLE NO.
============
PEW4
PEW4MS
PEW4MSD
PEW3
PEWl
TB
page 01 of 01
LAB LAB T.LME
SAMPLE ID FILE ID ANALYZED
==============
950601801 0605509.D 1522
950601801MS 0605510.D 1600
950601801MSD 0605511.D 1637
950601802 0605512.D 1714
950601803 0605513.D 1751
950601804 0605514.D 1828
FORM IV VOA 3/90
009
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lA CLIENT SAMPLE NO.
SW-846 VOLATILE ORGANICS ANALYSIS DATA SHEET
Lab Name: INDUSTRIAL & ENVIRONMENTA
Lab Code: IEA Case No.: 619-699
Matrix: (soil/water) WATER I Sample wt/vol:
Level: (low/med) I % Moisture: not dee.
GC Column:DB-624
5.0 (g/mL) mL
LOW
VBLK5T
Method: 8240
SDG No.: 06018
Lab Sample ID: VBLK5T
Lab File ID:
Date Received:
0605502.D
I I
Date Analyzed: 06/05/95
Dilution Factor: 1.0
I Soil Extract Volume:
ID: 0.53 (mm)
___ (uL) Soil Aliquot Volume: __ (uL)
CONCENTRATION UNITS: I Cl,S NO. COMPOUND (ug/L or ug/Kg) UG/L Q
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74-87-3---------Chloromethane
74-83-9---------Bromomethane
75-01-4---------Vinyl Chloride
75-00-3---------Chloroethane
75-09-2---------Methylene Chloride
67-64-1---------Acetone
75-15-o---------carbon Disulfide
75-35-4---------1,1-Dichloroethene
75-34-3---------1,1-Dichloroethane
540-59-0--------1,2-Dichloroethene
67-66-3---------Chloroform
(total)_
107-06-2--------1,2-Dichloroethane
78-93-3---------2-Butanone
108-05-4--------Vinyl Acetate
71-55-6---------1,1,1-Trichloroethane
56-23-5---------carbon Tetrachloride
75-27-4---------Bromodichloromethane
78-87-5---------1,2-Dichloropropane
10061-01-5------cis-l,3-Dichloropropene
79-01-6---------Trichloroethene
124-48-1--------Dibromochloromethane
110-75-8--------2-Chloroethylvinyl Ether
79-00-5---------1,1,2-Trichloroethane --
71-43-2---------Benzene
10061-02-6------trans-l,3-Dichloropropene
7 5··2 5-2---------Bromof arm --
108-10-1--------4-Methyl-2-Pentanone
591-78-6--------2-Hexanone
127-18-4--------Tetrachloroethene
79-34-5---------1,1,2,2-Tetrachloroethane
108-88-3--------Toluene --
108-90-7--------Chlorobenzene
100-41-4--------Ethylbenzene
100-42-5--------Styrene
1330-20-7-------Xylene (total)
FORM I VOA
10
10
10
10
5
10
5
5
5
5
5
5
10
10
5
5
5
5
5
5
5
10
5
5
5
5
10
10
5
5
5
5
5
5
5
u
u
u u u u
u u u u u u
u u u u u u
u u u u u
u
u u
u
u u· u
u u u u u
3/90
010
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2A
SW-846 WATER VOLATILE SYSTEM MONITORING COMPOUND RECOVERY
Lab Name: INDUSTRIAL & ENVIRONMENTA Method: 8240
Lab Code: IEA
page 01 of 01
01
02
03
04
05
06
07
08
09
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
Case No.: 619-699
CLIENT SMCl
SAMPLE NO. (TOL)#
============ ======
VBLK5T 101
PEW4 97
PEW4MS 100
PEW4MSD 101
PEW3 102
PEWl 102
TB 101
SMC2
(BFB)#
======
96
95
99
101
96
98
98
SMCl (TOL) = Toluene-dB
SMC3
(DCE)#
====== -94
99
102
97
104
104
110
SMC2 (BFB) = Brornofluorobenzene
SMC3 (DCE) = 1,2-Dichloroethane-d4
SDG No.: 06018
OTHER TOT
OUT
====== ---
0
0
0
0
0
0
0
----------
------------------------------------
QC LIMITS
(88-110)
(86-115)
(76-114)
# Column to be used to flag recovery values
* Values outside of contract required QC limits
D system Monitoring Compound diluted out
FORM II VOA-1 3/90
011
3A
SW-846 WATER VOLATILE MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERY
Lab Name: INDUSTRIAL & ENVIRONMENTA Method: 8240
Lab Code: IEA Case No.: 619-699 SDG No.: 06018.
Matrix Spike -CLIENT Sample No.: PEW4
SPIKE SAMPLE MS MS QC.
ADDED CONCENTRATION CONCENTRATION % LIMITS
COMPOUND (ug/L) (ug/L) (ug/L) REC # REC,
---------============= ============= ====== ======
1,1-Dichloroethene 50 0 50 100 61-145
Trichloroethene 50 98 130 64* 71-120
Benzene, 50 0 48 96 76-127
Toluene. 50 0 46 92 76-125
Chlorobenzene 50 0 48 96 75-130
SPIKE MSD MSD
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ADDED CONCENTRATION % % QC LIMITS
COMPOUND (ug/L) (ug/L) REC # RPD # RPD REC.
=======-·=-=---=--======= ============= ====== ====== ======
1,1-Dichloroethene 50 55 110 10 14
Trichlo:roethene 50 140 84 27* 14
Benzene 50 49 98 2 11
Toluene 50 50 100 8 13
Chlorobenzene 50 52 104 8 13
I # Column to be used to flag recovery and RPD values with an asterisk
* Values outside of QC limits
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RPD: 1 out of 5 outside limits
Spike Recovery: 1 out of 10 outside limits
COMMENTS:
FORM III VOA-1
61-145
71-120
76-127
76-125
75-130
3/90
012
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5A
SW-846 VOLATILE ORGANIC INSTRUMENT PERFORMANCE CHECK
BROMOFLUOROBENZENE (BFB)
Lab Name: INDUSTRIAL & ENVIRONMENTA
Lab Code: IEA Case No.: 619-699
Lab File ID: 05035BF.D
Instrument ID: MSD5
GC Column:DB-624 ID: 0.53 (mm)
m/e ION ABUNDANCE CRITERIA
===== ---
50 15.0 -40.0% of mass 95
75 30.0 -60.0% of mass 95
Method: 8240
SDG No.: 06018
BFB Injection Date: 05/03/95
BFB Injection Time: 1042
Heated Purge: (Y/N) N
'!. RELI\TJ.VE
ABUNDANCE
--------------18.3
54.2
95 Base peak, 100% relative aEunaance 100.0
96 !5. 0 -9.0% of mass 95 7.7
173 Less than 2.0% of mass 174 0.0 ( 0.0)1
174 Greater than 50% of mass 95 81.4
175 !) • 0 -9.0% of mass 174 7.1 ( 8.8)1
176 95.0 -101.0% of mass 174 79.8 ( 98.1)1
177 ~). 0 -9.0% of mass 176 5.7 ( 7.1)2
1-Value is% mass 174 2-Value is% mass 176
THIS CHECK APPLIES TO THE FOLLOWING SAMPLES, MS, MSD, BLANKS, AND STANDARDS:
01
02
03
04
05
06
07
08
09
10
11
12
13
14
15
16
17
18
19
20
21
22
CLIENT
SAMPLE NO.
VSTDOlO
VSTD020
VSTD050
VSTDlOO
VSTD200
page 01 of 01
LAB LAB
SAMPLE ID FILE ID --------------VSTDOlO 0503501.D
VSTD020 0503502.D
VSTD050 0503503.D
VSTDlOO 0503504.D
VSTD200 0503505.D
FORM V VOA
DATE TIME
ANALYZED ANALYZED --------------------
05/03/95 1114
05/03/95 1154
05/03/95 1234
05/03/95 1312
05/03/95 1354
3/90
013
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5A
SW-846 VOLATILE ORGANIC INSTRUMENT PERFORMANCE
BROMOFLUOROBENZENE (BFB)
CHECK
Lab Name: INDUSTRIAL & ENVIRONMENTA
Lab Code: IEA Case No.: 619-699
Lab File ID: 06055BF.D
Instrument ID: MSD5
GC Column:DB-624 ID: 0.53 (mm)
m/e ION ABUNDANCE CRITERIA
===== --·
50 15.0 -40.0% of mass 95
75 30.0 -60.0% of mass 95
Method: 8240
SDG No.: 06018
BFB Injection Date: 06/05/95
BFB Injection Time: 0912
Heated Purge: (Y/N) N
't RELAT.LVE
ABUNDANCE --------------18.9
59.0
95 Base peak, 100% relative aEunaance 100.0
96 !:i. O -9.0% of mass 95 6.4
173 Less than 2.0% of mass 174 0.0 ( 0.0)1
174 Greater than 50% of mass 95 89.8
175 5,. 0 -9.0% of mass 174 7.4 ( 8.2)1
176 95.0 -101.0% of mass 174 88.4 ( 98.4)1
177 5.0 -9.0% of mass 176 6.2 ( 7.0)2
1-Value is% mass 174 2-Value is% mass 176
THIS CHECK APPLIES TO THE FOLLOWING SAMPLES, MS, MSD, BLANKS, AND STANDARDS:
01
02
03
04
05
06
07
08
09
10
11
12
13
14
15
16
17
18
19
20
21
22
CLIENT
SAMPLE NO.
VSTD050
VBLK5T
1'EW4
PEW4MS
PEW4MSD
PEW3
PEWl
'.PB
page 01 of 01
LAB LAB
SAMPLE ID FILE ID ==============
VSTD050 0605501.D
VBLK5T 0605502.D
950601801 0605509.D
950601801MS 0605510.D
950601801MSD 0605511.D
950601802 0605512.D
950601803 0605513.D
950601804 0605514.D
FORM V VOA
UATE T .LMi,;
ANALYZED ANALYZED --------------------06/05/95 0948
06/05/95 1038
06/05/95 1522
06/05/95 1600
06/05/95 1637
06/05/95 1714
06/05/95 1751
06/05/95 1828
3/90
014
I 6A
SW-846 VOLATILE ORGANICS INITIAL CALIBRATION DATA
ILab Name: INDUSTRIAL & ENVIRONMENTA
Lab Code: IEA
IInstrument ID: MSD5
Case No.: 619-699 Method: 8240 SDG No.: 06018
Calibration Date(s): 05/03/95
•
Heated Purge: (Y/N) N Calibration Times: 1114 1354
GC Column:DB-624 ID: 0.53 (mm)
RRF for SPCC(#) = .JOO Max %RSD for CCC(*) = 30.0%
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Min RRF for Bromoform = 0.250
LAB FILE ID: RRFlO -0503501.D RRF20 -0503502.D
RRF50 =0503503.D RRF100=0503504.D RRF200=0503505.D
COMPOUND RRFlO RRF20 RRF50 RRFlOO RRF200
============================ ====== ====== ====== ====== ======
Chloromethane 0.564 0.672 0.707 0.628 0.611
Bromomethane 0.856 0.919 1.016 0.872 0.854
Vinyl Chloriae 0.637 0.766 0.820 0.753 0.743
Chloroethane 0.426 0.424 0.412 0.359 0.342
Methylene Chloride 1.218 1.232 1.336 1.114 1.099
Acetone -0.235 0. 251 0.236 o. 201 0.198
Carbon Disulfide 2.363 2.877 3.248 2.812 2.848
1,1-Dichloroethene 0.864 1.039 1.148 0.994 0.973
1,1-Dichloroethane 1. 848 2.177 2.427 2.067 2.096
1,2-Dichloroethene (total) 1.089 1.286 1.479 1.231 1.250
Chloroform --2.503 2.997 3.396 2.790 2.895
1,2-Dichloi:oethane 1.697 2.005 2.255 1.834 1.957
2-Butanone 0.356 0.477 0.476 0.403 0.433
Vinyl Acetate 0.571 0.759 0.804 0.722 0.729
1,1,1=Trichloroethane 0.708 0.867 0.926 0.807 0.806
Carbon Tetrachloride 0.687 0.866 0.932 0.828 0.815
Bromodichloromethane 0.775 0.957 1.083 0.912 0.914
1,2-Dichloropropane 0.337 0.354 0.475 0.340 0.337
cis-1,J-Dichloropropene 0.538 0.662 0.766 0.647 0.649
Trichloroethene 0.403 0.500 0.527 0.448 0.435
Dibromochloromethane 0.736 0.878 0.985 0.878 0.872
2-Chloroethylvinyl Ether 0.193 0. 255 0.286 0.247 0.251
1,1,2-Trichloroethane --0.344 0.427 0.459 0.395 0.387
Benzene 0.710 0. 860 0.934 0.768 0.747
trans-1,3-Dichloropropene 0.478 0.613 0.710 0.603 0.617
Bromoform --0.538 0.726 0.796 0.723 0.740
4-Methyl-2-Pentanone 0.265 0.404 0.432 0.361 0. 391
2-Hexanone 0.314 0.250 0.284 0.251 0.267
TetrachloroE!thene 0.463 0.604 0.641 0.531 0.505
1,1,2,2-Tetrachloroethane 0.581 0.780 0.826 0.693 0.710
Toluene --0.597 0.743 0.863 0.668 0.671
Chlorobenzene 0.859 1.044 1.132 0.934 0.916
Ethylbenzene, 0.372 0.460 0.513 0. 415 0.401
Styrene 0.778 0.981 1.100 0.892 0.865
Xylene_(total) 0.449 0.569 0.624 0.508 0.492
====== ====== ====== Toluene-dB 1.023 1. 252 1. 309 1.091 1.118
row
======
0.636
0.903
0.744
0.393
1.200
0.224
2.830
1.004
2.123
1.267
2.916
1.950
0.429
0.717
0.823
0.826
0.928
0.368
0.652
0.462
0.870
0.246
0. 402
0.804
0.604
0.705
0.371
0.273
0.549
0.718
0.709
0.977
0.432
0.923
0.528
======
1.159
%
RSD
=====
8.6
7.6
9.0
10.0
8.0
10.4
11.1
10.3
9.8
11.1
11.2
10.7
12.0
12.2
9.8
10.8
11.9
16.2
12.4
10.9
10.2
13.6
10.7
11.4
13.7
13.9
17.3
9.7
13.3
13.0
14.2
11.2
12.7
13.2
13.0
l 1
I
#
I
*
!
* #
*
=====
10.2
015
I 6A
SW-846 VOLATILE ORGANICS INITIAL CALIBRATION DATA I Lab Name: INDUSTRIAL & ENVIRONMENTA
•
Lab Code: IEA
Instrument ID:
Case No.: 619-699 Method: 8240 SDG No.: 06018
MSD5
•
Heated Purge: (Y/N) N
GC Column:DB-624
Calibration Date(s): 05/03/95
Calibration Times: 1114 1354
ID: 0.53 (mm)
•
Min RRF for SPCC(#) = . 300 Max %RSD for CCC(*) = 30.0%
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Min RRF for Bromoform = 0.250
LAB FILE ID: RRFlO =0503501.D RRF20 =0503502.D
RRF50 =0503503.D RRF100=0503504.D RRF200=0503505.D
COMPOUND RRFlO RRF20 RRF50 RRFlOO RRF200
-· ====== ====== ====== ======
Bromofluorobenzene 0.815 0.922 0.919 0.789 0.815
l,2-Dichloroethane-d4 1. 544 1. 742 1.901 1. 611 1. 768
RRF
0.852
1.713
%
RSD
=====
7.4
8.2
016
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7A
SW-846 VOLATILE CONTINUING CALIBRATION CHECK
Lab Name: INDUSTRIAL & ENVIRONMENTA
Case No.: 619-699 Method: 8240 Lab Code:: IEA
Instrument ID: MSD5 Calibration Date: 06/05/95
SDG No.: 06018
Time: 0948
Lab File ID: 0605501.D
Heated Purge: (Y/N) N
Init. Calibration Date(s): 05/03/95
Init. Calibration Times: 1114 1354
GC Column:DB-624 ID: 0.53 (mm)
Min RRF for SPCC(#) = .300 Max %D for CCC(*) = 25.0%
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Min RRF for Bromoform = 0.250
COMPOUND RRF RRF50
----------------------------====== ======
Chloromethane 0.636 0.475
Bromomethane 0.903 1.129
Vinyl Chloriae 0.744 0.561
Chloroethane 0.393 0.408
Methylene Chloride 1. 200 0.980
Acetone -0.224 0.151
Carbon Disulride 2.830 2.613
1,1-Dichloroethene 1. 004 0.947
1,1-Dichloroethane 2.123 1.875
1,2-Dichloroethene (total) 1.267 1.252
Chloroform --2.916 3 .129
1,2-Dichloroethane 1.950 2.227
2-Butanone 0.429 0.362
Vinyl Acetate 0.717 0.624
1,1,1-=Trichloroetfiane 0.823 1.070
Carbon Tetrachloride 0.826 1.159
BromodTchloromethane 0.928 1.191
1,2-Dichloropropane 0.368 0.359
cis-1,3-Dichloropropene 0.652 0.674
Trichloroethene 0.462 0.549
Dibromochloromethane 0.870 1.200
2-Chloroethylvinyl Ether 0.246 0.194
1,1,2-Trichloroethane --0.402 0.440
Benzene 0.804 0.739
trans-1,3-Dicfiloropropene 0.604 0.716
Bromoform --0.705 0.963
4-Methyl-2-Pentanone 0.371 0.316
2-Hexanone 0.273 0.221
Tetrachloroethene 0.549 0.588
1,1,2,2-Tetrachloroetfiane 0.718 0.681
Toluene --0.709 0.669
Chlorobenzene 0.977 0.951
Ethyl benzene 0.432 0.444
Styrene 0.923 0.960
Xylen,e (total) 0.528 0.543
=====: ====== ======
Toluene-dB 1.159 1.049
FORM VII VOA
==~~=~l 25.4
-24.91
24.6*
-'-01 18.3
32.5
7.7
5.6
11. 7#
1.11
-7.3*
-14.2
15.6
13.0
-30.1
-40.4
-28.2
2. 7 •
-3.3
-18.7
-37.9
21.2
-9.3
8.0
-18.5
-36.7
14.81 19.2
-7.2
5.2
5.6*
2.7#
-2.7*
-4.0
-2.8
9.5
017
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7A
SW-846 VOLATILE CONTINUING CALIBRATION CHECK
Lab Name: INDUSTRIAL & ENVIRONMENTA I Lab Code:: IEA
Instrument ID: MSD5
Case No.: 619-699 Method: 8240 SDG No.: 06018
Calibration Date: 06/05/95 Time: 0948 I Lab File ID: 0605501.D
Heated Purge: (Y/N) N
Init. Calibration Date(s): 05/03/95
Init. Calibration Times: I GC Column:DB-624 ID: o. 53 (mm)
Min
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RRF for SPCC(#) = .300 Max %D for CCC(*)
Min RRF for Bromoform = 0.250
COMPOUND RRF RRF50 %D
====== ====== ======
Bromofluorobenzene 0.852 0.902 -5.8
1,2-Dichloroethane-d4 1. 713 1.814 -5.9
FORM VII VOA
1114 1354
= 25.0%
018
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IEA SDG NARRATIVE SEMIVOLATILE FRACTION
PROJECT: 619-699 BATCH: 06018 METHOD: SW-846 8270
Samples: (3) Water Samples
The samples were received at Industrial and Environmental Analysts, Inc. (!EA) on June 01, 1995.
Each sample was assigned a 9-character "!EA" lab identification number (lab ID) and an abbreviated
client ID which is referenced on the !EA Assigned Number Index. All analyses are performed in
accordance with EPA approved methodologies and meet the requirements of the !EA Quality Assurance
Program. Please see the enclosed data package for your results and Chain of Custody documentation.
The chromatographic separation of the analytes was performed using a Restek 30 X 0.32 XTI-5 fused
silica capillary column with a 0.5 µm bonded phase film thickness.
Instrument data printouts identify the compound 2,2' -oxybis(l-Chloropropane) with CAS number I 08-60-
1. Alternative nomenclature for this compound is bis(2-Chloroisopropyl)ether which is included on report
forms submitted.
The "J" flag used on the Form I SV for samples PEW4MS and PEW4MSD indicate spike compounds
which recovered below the quantitation limit.
The "M" flag used on the data system report form designates that a manual integration was required to
provid,! an accurate quantification of that analyte. Manual integrations have been initialed and dated by
the analyst.
Any nonconformances associated with the analysis of the samples in this project are as follows:
Matrix Spike/Matrix Spike Duplicate (PEW4MS/PEW4MSD) percent recovery for 4-Nitrophenol
exceeded the limits specified for this method due to good extraction efficiency.
The surrogates 2-Fluorophenol and 2,4,6-Tribromophenol recovered outside of the method specified limits
in sample PEW I. The sample was re-extracted outside of method specified holding time and did not
confirm the failing surrogate recoveries. The results from both the original analysis and re-extraction
analsyis have been submitted with this data package.
Sample PEW IRE was double-spiked with Internal Standards prior to analysis. The surrogate recoveries
and target compound concentrations have been adjusted to reflect this error.
IEA, Inc Ooc~I RPF0070t.NC
1
019
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IEA SDG NARRATIVE SEMIVOLATILE FRACTION
I certify that this data package is in compliance with the procedures and methods defined for this project,
both technically and for completeness, for other than the conditions detailed above. Release of the data
contained in this hardcopy data package and in the computer-readable data (if applicable) as submitted
has been authorized by the laboratory manager or his designee, as verified by the following signature.
David F. Morse
GC/MS SV Lead Analyst
!EA, Inc.
IF.A, Inc:: Doc11 RPF00701.NC
06/27/95
2
020
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Lab Sample Number
9506018-01
9506018-02
9506018-03
9506018-04
IEA Assigned Number Index
Case No.: 619-699
SDG No.: 06018
Sample Number
PEW-4
PEW-3
PEW-1
TRIP BLANK
Abbreviated
Sample Number
PEW4
PEW3
PEWl
TB
021
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1B CLIENT SAMPLE NO.
SW-846 SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET
PEWl
Lab Name: INDUSTRIAL & ENVIRONMENTA
Lab Code:: IEA Case No.: 619-699 Method: 8270 SDG No.: 06018
Matrix: (soil/water) WATER Lab Sample ID: 950601803
Sample wt/vol: Lab File ID: 0607D08.D
Level: (low/med) I % Moisture:
1000 (g/mL) mL
LOW
decanted: (Y/N)
Concentrated Extract Volume: lOOO(uL) I Injection Volume: 2. 0 (uL)
Date Received: 06/01/95
Date Extracted:06/05/95
Date Analyzed: 06/08/95
Dilution Factor: 1.0
GPC Cleanup: (Y/N) N pH:
CAS NO. COMPOUND
108-95-2-~------Phenol
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L
111-44-4--------bis(2-Chloroethyl)ether
95-57-8---------2-Chlorophenol
541-73-1--------1,3-Dichlorobenzene
106-46-7--------1,4-Dichlorobenzene
95-50-1---------1,2-Dichlorobenzene
95-48-7---------2-Methylphenol
108-60-l--------bis(2-Chloroisopropyl)ether)
106-44-5--------4-Methylphenol
621-64-7--------N-Nitroso-di-n-propylamine
67-72-1---------Hexachloroethane -
98-95-3---------Nitrobenzene
78-59-1---------Isophorone
88-75-5---------2-Nitrophenoi
105-67-9--------2,4-Dimethylphenol
lll-91-l--------bis(2-Chloroethoxy)methane
120-83-2--------2,4-Dichlorophenol -
120-82-1--------1,2,4-Trichlorobenzene
91-20-3---------Naphthalene
106-47-8--------4-Chloroaniline
87-68-3---------Hexachlorobutadiene
59-50-7---------4-Chloro-3-methylphenol
91-57-6---------2-Methylnaphthalene
77-47-4---------Hexachlorocyclopentadiene
88-06-2---------2,4,6-Trichlorophenol --
95-95-4---------2,4,5-Trichlorophenol
91-58-7---------2-Chloronaphthalene
88-74-4---------2-Nitroaniline
131-11-3--------Dimethylphthalate
208-96-8--------Acena~hthylene
606-20-2--------2,6-Dinitrotoluene
99-09-2---------3-Nitroaniline
83-32-9---------Acenaphthene
FORM I SV-1
Q
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3/90
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lC CLIENT SAMPLE NO.
SW-846 SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET
PEWl
Lab Name: INDUSTRIAL & ENVIRONMENTA
Lab Code: IEA Case No.: 619-699 Method: 8270 SDG No.: 06018
Matrix: {soil/water) WATER Lab Sample ID: 950601803
Sample wt/vol: 1000 (g/mL) mL Lab File ID: 0607D08.D
Level: (low/med) LOW
% Moisture: decanted: (Y/N)
lOOO(uL)
Date Received: 06/01/95
Date Extracted:06/05/95
Date Analyzed: 06/08/95
Dilution Factor: 1.0
Concentrated Extract Volume:
Injection Volume: 2. 0 (uL)
GPC Cleanup: (Y/N) N pH:
CAS NO. COMPOUND
51-28-5---------2,4-Dinitrophenol
100-02-7--------4-Nitrophenol
132-64-9--------Dibenzofuran
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L
121-14-2--------2,4-Dinitrotoluene
84-66-2---------Diethylphthalate
7005-72-3-------4-Chlorophenyl-phenylether
86-73-7---------Fluorene -
100-01-6--------4-Nitroaniline
534-52-1--------4,6-Dinitro-2-methylphenol
86-30-6---------N-Nitrosodiphenylamine (1)-
101.-55-3--------4-Bromophenyl-phenylether -
118-74-1--------Hexachlorobenzene --
87-86-5---------Pentachlorophenol
85-01-8---------Phenanthrene
120-12-7--------Anthracene
84-74-2---------Di-n-butylphthalate
206-44-0--------Fluoranthene
129-00-0--------Pyrene
85-68-7---------Butylbenzylphthalate
91-94-1---------3,3'-Dichlorobenzidine
56-55-3---------Benzo(a)anthracene
218-01-9--------Chrysene
117-81-7--------bis(2-Ethylhexyl)phthalate
117-84-0--------Di-n-octylphthalate -
205-99-2--------Benzo(b)fluoranthene
207-08-9--------Benzo(k)fluoranthene
50-32-8---------Benzo(a)pyrene
193-39-5--------Indeno(l,2,3-cd)pyrene
53-70-3---------Dibenz(a,h)anthracene
191-24-2--------Benzo(9,h,i)perylene
92-52-4---------1,1'-Biphenyl
100-51-6--------Benzyl Alcohol
65-85-0---------Benzoic Acid
FORM I SV-2
Q
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3/90
023
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lC CLIENT SAMPLE NO.
SW-846 SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET
PEWl
Lab Name: INDUSTRIAL & ENVIRONMENTA
Lab Code:: IEA Case No.: 619-699 Method: 8270 SDG No.: 06018
Matrix: (soil/water) WATER Lab Sample ID: 950601803
Sample wt/vol: 1000 (g/mL) mL Lab File ID: 0607D08.D
Level: (low/med)· LOW
% Moisture: decanted: (Y/N)
Concentrated Extract Volume: 1000 (uL) I Injection Volume: 2. 0 (uL)
Date Received: 06/01/95
Date Extracted:06/05/95
Date Analyzed: 06/08/95
Dilution Factor: 1.0
I
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GPC Cleanup: (Y/N) N pH:
CAS NO. COMPOUND
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L Q
101-84-8--------Diphenyl Ether _____________ i_ol ___ u
FORM I SV-3 3/90
024
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1B CLIENT SAMPLE NO.
SW-846 SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET
PEWlRE
Lab Name: INDUSTRIAL & ENVIRONMENTA
Lab Code: IEA Case No.: 619-699 Method: 8270 SDG No.: 06018
Matrix: (soil/water) WATER Lab Sample ID: 950601803RE
Sample wt/vol: 500 (g/mL) mL Lab File ID: 0609404.D
Level: (low/med)
% Moisture:
Concentrated Extract
Injection Volume:
LOW
decanted:
Volume:
2. 0 (uL)
(Y/N)_
500(uL)
Date Received: 06/01/95
Date Extracted:06/08/95
Date Analyzed: 06/09/95
Dilution Factor: 1.0
GPC Cleanup: (Y/N) N pH:
Cl\S NO. COMPOUND
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L
108-95-2--------Phenol
lll-44-4--------bis(2-Chloroethyl)ether
95-57-8---------2-Chlorophenol
541-73-1--------1,3-Dichlorobenzene
106-46-7--------1,4-Dichlorobenzene
95-50-1---------1,2-Dichlorobenzene
95-48-7---------2-Methylphenol
108-60-1--------bis(2-Chloroisopropyl)ether)
106-44-5--------4-Methylphenol
621-64-7--------N-Nitroso-di-n-propylamine
67-72-1---------Hexachloroethane -
98-95-3---------Nitrobenzene
78-59-1---------Isophorone
88-75-5---------2-Nitrophenol
105-67-9--------2,4-Dimethylphenol
lll-91-1--------bis(2-Chloroethoxy)methane
120-83-2--------2,4-Dichlorophenol -
120-82-1--------1,2,4-Trichlorobenzene
91-20-3---------Naphthalene
106-47-8--------4-Chloroaniline
87-68-3---------Hexachlorobutadiene
59-50-7---------4-Chloro-3-methylphenol
91-57-6---------2-Methylnaphthalene
77-47-4---------Hexachlorocyclopentadiene
88-06-2---------2,4,6-Trichlorophenol --
95-95-4---------2,4,5-Trichlorophenol
91-58-7---------2-Chloronaphthalene
88-74-4---------2-Nitroaniline
131-11-3--------Dimethylphthalate
208-96-8--------Acena~hthylene
606-20-2--------2,6-Dinitrotoluene
99-09-2---------3-Nitroaniline
83-32-9---------Acenaphthene
FORM I SV-1
Q
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u u
u u
3/90
025
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lC CLIENT SAMPLE NO.
SW·-846 SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET
PEWlRE
Lab Name: INDUSTRIAL & ENVIRONMENTA
Lab Code:: IEA Case No.: 619-699 Method: 8270 SDG No.: 06018
Matrix: (soil/water) WATER Lab Sample ID: 950601803RE I Sample wt/vol: Lab File ID: 0609404.D
Level: (low/med) I % Moisture:
500 (g/mL) mL
LOW
decanted: (Y/N) __
Concentraited Extract Volume: 500 (uL) I Injection Volume: 2.0(uL)
Date Received: 06/01/95
Date Extracted:06/08/95
Date Analyzed: 06/09/95
Dilution Factor: 1.0
GPC Cleanup: (Y/N) N pH:
CAS NO. COMPOUND
51-28-5---------2,4-Dinitrophenol
100-02-7--------4-Nitrophenol
132-64-9--------Dibenzofuran
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L
121-14-2--------2,4-Dinitrotoluene
84-66-2---------Diethylphthalate
7005-72-3-------4-Chlorophenyl-phenylether
86-73-7---------Fluorene -
100-01-6--------4-Nitroaniline
534-52-1--------4,6-Dinitro-2-methylphenol
86-30-6---------N-Nitrosodiphenylamine (1)-
101-55-3--------4-Bromophenyl-phenylether -
118-74-1--------Hexachlorobenzene --
87-86-5---------Pentachlorophenol
85-01-8---------Phenanthrene
120-12-7--------Anthracene
84-74-2---------Di-n-butylphthalate
206-44-0--------Fluoranthene
129-00-0--------Pyrene
85-68-7---------Butylbenzylphthalate
91-94-1---------3,3'-Dichlorobenzidine
56-55-3---------Benzo(a)anthracene
218-01-9--------Chrysene
117-81-7--------bis(2-Ethylhexyl)phthalate
117-84-0--------Di-n-octylphthalate -
205-99-2--------Benzo(b)fluoranthene
207-08-9--------Benzo(k)fluoranthene
50-32-8---------Benzo(a)pyrene
193-39-5--------Indeno(l,2,3-cd)pyrene
53-70-3---------Dibenz(a,h)anthracene
191-24-2--------Benzo(9,h,i)perylene
92-52-4---------1,1'-Biphenyl
100-51-6--------Benzyl Alcohol
65-85-0---------Benzoic Acid
FORM I SV-2
Q
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u
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u u
3/90
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lC CLIENT SAMPLE NO. I
I
SW-846 SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET
Lab Name: INDUSTRIAL & ENVIRONMENTA I Lab Code: IEA Case No.: 619-699
Matrix: (soil/water) WATER I Sample wt/vol:
Level: (low/med) I % Moisture:
500 (g/mL) mL
LOW
decanted: (Y/N)_
Concentrated Extract Volume: 500(uL)
Injection Volume: 2. 0 (UL)
GPC Cleanup: (Y/N) N pH:
CAS NO. COMPOUND
PEWlRE
Method: 8270 SDG No.: 06018
Lab Sample ID: 950601803RE
Lab File ID: 0609404.D
Date Received: 06/01/95
Date Extracted:06/08/95
Date Analyzed: 06/09/95
Dilution Factor: 1.0
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L Q
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101-84-8--------Diphenyl Ether _____________ 1_ol ___ u
FORM I SV-3 3/90
02 7
I
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1B CLIENT SAMPLE NO.
SW-846 SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET
PEWJ
Lab Name: INDUSTRIAL & ENVIRONMENTA I Lab Code: IEA Case No.: 619-699 Method: 8270 SDG No.: 06018
I
I
Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
% Moisture:
1000 (g/mL) mL
LOW
decanted: (Y/N)
Concentrated Extract Volume: 1000 (uL)
Lab Sample ID: 950601802
Lab File ID: 0607D07.D
I Injection Volume: 2. 0 (uL)
Date Received: 06/01/95
Date Extracted:06/05/95
Date Analyzed: 06/08/95
Dilution Factor: 1.0
GPC Cleanup: (Y/N) N pH:
CJ\S NO. COMPOUND
108-95-2--------Phenol
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L
lll-44-4--------bis(2-Chloroethyl)ether
95-57-8---------2-Chlorophenol
541-73-1--------1,3-Dichlorobenzene
106-46-7--------1,4-Dichlorobenzene
95-50-1---------1,2-Dichlorobenzene
95-48-7---------2-Methylphenol
108-60-l--------bis(2-Chloroisopropyl)ether)
106-44-5--------4-Methylphenol
621-64-7--------N-Nitroso-di-n-propylamine
67-72-1---------Hexachloroethane -
98-95-3---------Nitrobenzene
78-59-1---------Iso~horone
88-75-5---------2-Nitrophenol
105-67-9--------2,4-Dimethylphenol
lll-91-l--------bis(2-Chloroethoxy)methane
120-83-2--------2,4-Dichlorophenol -
120-82-1--------1,2,4-Trichlorobenzene
91-20-3---------Naphthalene
106-47-8--------4-Chloroaniline
87-68-3---------Hexachlorobutadiene
59-50-7---------4-Chloro-3-methylphenol
91-57-6---------2-Methylnaphthalene
77-47-4---------Hexachlorocyclopentadiene
88-06-2---------2,4,6-Trichlorophenol --
95-95-4---------2,4,5-Trichlorophenol
91-58-7---------2-Chloronaphthalene
88-74-4---------2-Nitroaniline
131-11-3--------Dimethylphthalate
208-96-8--------Acena~hthylene
606-20-2--------2,6-Dinitrotoluene
99-09-2---------3-Nitroaniline
83-32-9---------Acenaphthene
FORM I SV-1
Q
10
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10
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10
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u u
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u u
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u u u u u
3/90
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lC CLIENT SAMPLE NO.
SW-846 SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET
PEWJ
Lab Name: INDUSTRIAL & ENVIRONMENTA
Lab Code: IEA Case No.: 619-699 Method: 8270 SDG No.: 06018
Matrix: (soil/water) WATER Lab Sample ID: 950601802
Sample wt/vol: Lab File ID: 0607D07.D
Level: (low/med)
% Moisture:
1000 (g/mL) mL
LOW
decanted: (Y/N) __
Concentrated Extract Volume: lOOO(uL)
Injection Volume: 2.0(uL)
Date Received: 06/01/95
Date Extracted:06/05/95
Date Analyzed: 06/08/95
Dilution Factor: 1.0
GPC Cleanup: (Y/N) N pH:
CAS NO. COMPOUND
51-28-5---------2,4-Dinitrophenol
100-02-7--------4-Nitrophenol
132-64-9--------Dibenzofuran
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L
121-14-2--------2,4-Dinitrotoluene
84-66-2---------Diethylphthalate
7005-72-3-------4-Chlorophenyl-phenylether
86-73-7---------Fluorene -
100-01-6--------4-Nitroaniline
534-52-1--------4,6-Dinitro-2-methylphenol
86-30-6---------N-Nitrosodiphenylamine (1)-
101-55-3--------4-Bromophenyl-phenylether -
118-74-1--------Hexachlorobenzene --
87-86-5---------Pentachlorophenol
85-01-8---------Phenanthrene
120-12-7--------Anthracene
84-74-2---------Di-n-butylphthalate
206-44-0--------Fluoranthene
129-00-0--------Pyrene
85-68-7---------Butylbenzylphthalate
91-94-1---------3,3'-Dichlorobenzidine
56-55-3---------Benzo(a)anthracene
218-01-9--------Chrysene
117-81-7--------bis(2-Ethylhexyl)phthalate
117-84-0--------Di-n-octylphthalate -
205-99-2--------Benzo(b)fluoranthene
207-08-9--------Benzo(k)fluoranthene
50-32-8---------Benzo(a)pyrene
193-39-5--------Indeno(l,2,3-cd)pyrene
53-70-3---------Dibenz(a,h)anthracene
191-24-2--------Benzo(9,h,i)perylene
92-52-4---------1,1'-Biphenyl
100·-51-6--------Benzyl Alcohol
65-85-0---------Benzoic Acid
FORM I SV-2
Q
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u u u
u u u u u u
u
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u u u
u
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u
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u
u
u
3/90
029
lC CLIENT SAMPLE NO. I
I
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SW-846 SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET
Lab Name: INDUSTRIAL & ENVIRONMENTA
Lab Code: IEA Case No.: 619-699
Matrix: (soil/water) WATER
I Sample wt/vol:
Level: (low/med) I % Moisture:
1000 (g/mL) mL
LOW
decanted: (Y/N)
Concentrated Extract Volume: lOOO(uL) I Injection Volume: 2.0(uL)
GPC Cleanup: (Y/N) N pH:
CAS NO. COMPOUND
PEW3
Method: 8270 SDG No.: 06018
Lab Sample ID: 950601802
Lab File ID: 0607D07.D
Date Received: 06/01/95
Date Extracted:06/05/95
Date Analyzed: 06/08/95
Dilution Factor: 1.0
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L Q
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101-84-8--------Diphenyl Ether _____________ 1_o_i ___ u
FORM I SV-3 3/90
oao
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1B CLIENT SAMPLE NO.
SW-846 SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET
Lab Name: INDUSTRIAL & ENVIRONMENTA
Lab Code: IEA Case No.: 619-699
Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
% Moisture:
500 (g/mL) mL
LOW
decanted: (Y/N) __
Concentrated Extract Volume: 500 (uL)
PEW4
Method: 8270 SDG No.: 06018
Lab Sample ID: 950601801
Lab File ID: 0607Dl2.D
I Injection Volume: 2.0(uL)
Date Received: 06/01/95
Date Extracted:06/05/95
Date Analyzed: 06/08/95
Dilution Factor: 1.0
I
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GPC Cleanup: (Y/N) N pH:
CAS NO. COMPOUND
108-95-2--------Phenol
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L
lll-44-4--------bis(2-Chloroethyl)ether
95-57-8---------2-Chlorophenol
541-73-1--------1,3-Dichlorobenzene
106-46-7--------1,4-Dichlorobenzene
95-50-1---------1,2-Dichlorobenzene
95-48-7---------2-Methylphenol
108-60-l--------bis(2-Chloroisopropyl)ether)
106-44-5--------4-Methylphenol
621-64-7--------N-Nitroso-di-n-propylamine
67-72-1---------Hexachloroethane -
98-95-3---------Nitrobenzene
78-59-1---------Isophorone
8 8 ·-7 5-5---------2-N i tropheno.1
105-67-9--------2,4-Dimethylphenol
lll-91-l--------bis(2-Chloroethoxy)methane
120-83-2--------2,4-Dichlorophenol -
120-82-1--------1,2,4-Trichlorobenzene
91-20-3---------Naphthalene
106-47-8--------4-Chloroaniline
87-68-3---------Hexachlorobutadiene
59-50-7---------4-Chloro-3-methylphenol
91-57-6---------2-Methylnaphthalene
77-47-4---------Hexachlorocyclopentadiene
88-06-2---------2,4,6-Trichlorophenol --
95-95-4---------2,4,5-Trichlorophenol
91-58-7---------2-Chloronaphthalene
88-74-4---------2-Nitroaniline
131-11-3--------Dimethylphthalate
208-96-8--------Acenaphthylene
606-20-2--------2,6-Dinitrotoluene
99-09-2---------3-Nitroaniline
83-32-9---------Acenaphthene
FORM I SV-1
Q
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
20 u
10 u
20 u
10 u
10 u
10 u
10 u
10 u
50 u
10 u
10 u
10 u
50 u
10 u
3/90
031
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lC CLIENT SAMPLE NO.
SW-846 SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET
PEW4
Lab Name: INDUSTRIAL & ENVIRONMENTA
Lab Code: IEA Case No.: 619-699 Method: 8270 SDG No.: 06018
Matrix: (soil/water) WATER Lab Sample ID: 950601801
I Sample wt/vol: Lab File ID: 0607D12.D
Level: (low/med) I % Moisture:
500 (g/mL) mL
LOW
decanted: (Y /N)
Concentrated Extract Volume: 500(uL)
Injection Volume: 2. 0 (uL)
Date Received: 06/01/95
Date Extracted:06/05/95
Date Analyzed: 06/08/95
Dilution Factor: 1.0
GPC Cleanup: (Y/N) N pH:
C1,S NO . COMPOUND
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L
51-28-5---------2,4-Dinitrophenol
100-02-7--------4-Nitrophenol
132-64-9--------Dibenzofuran
121-14-2--------2,4-Dinitrotoluene
84-66-2---------Diethylphthalate
7005-72-3-------4-Chlorophenyl-phenylether
86-73-7---------Fluorene -
100-0l-6--------4-Nitroan1l1ne
534-52-1--------4,6-Dinitro-2-methylphenol
86-30-6---------N-Nitrosodiphenylamine (1)-
101-55-3--------4-Bromophenyl-phenylether--=
118-74-1--------Hexachlorobenzene
87-86-5---------Pentachlorophenol
85-01-8---------Phenanthrene
120-12-7--------Anthracene
84-74-2---------Di-n-butylphthalate
206-44-0--------Fluoranthene
129-00-0--------Pyrene
85-68-7---------Butylbenzylphthalate
91-94-1---------3,3'-Dichlorobenzidine
56-55-3---------Benzo(a)anthracene
218-01-9--------Chrysene
117-81-7--------bis(2-Ethylhexyl)phthalate
117-84-0--------Di-n-octylphthalate -
205-99-2--------Benzo(b)fluoranthene
207-08-9--------Benzo(k)fluoranthene
50-32-8---------Benzo(a)pyrene
193-39-5--------Indeno(l,2,3-cd)pyrene
53-70-3---------Dibenz(a,h)anthracene
191-24-2--------Benzo(9,h,i)perylene
92-52-4---------1,1'-Biphenyl
100-51-6--------Benzyl Alcohol
65-85-0---------Benzoic Acid
FORM I SV-2
Q
50
50
10
10
10
10
10
20
50
10
10
10
50
10
10
10
10
10
10
10
10
10
10
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10
10
10
10
10
10
10
20
50
u
u u u u u u u u u u u u u u u u u u u u u u u u u u u u u u u u
3/90
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I
I 032
lC CLIENT SAMPLE NO.
SW-·846 SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET
PEW4
Lab Name: INDUSTRIAL & ENVIRONMENTA
Lab Code: IEA Case No.: 619-699 Method: 8270 SDG No.: 06018
Matrix: (soil/water) WATER Lab Sample ID: 950601801 I Sample wt/vol: 500 (g/mL) mL
LOW
Lab File ID: 0607D12.D
Level: (low/med) I % Moisture: decanted: (Y/N)
Date Received: 06/01/95
Date Extracted:06/05/95
Date Analyzed: 06/08/95
Dilution Factor: 1.0 I
I
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I
Concentrated Extract Volume:
Injection Volume: 2. 0 (uL)
GPC Cleanup: (Y/N) N pH:
CAS NO. COMPOUND
500 (uL)
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L Q
101-84-8--------Diphenyl Ether _____________ 1_ol ___ u
FORM I SV-3 3/90
033
~·
I
4B CLIENT SAMPLE NO.
SW-846 SEMIVOLATILE METHOD BLANK SUMMARY
Lab Name: INDUSTRIAL & ENVIRONMENTA
Lab Code:: IEA Case No.: 619-699
Lab File ID: 0607D05.D
I
I Instrument ID: MSD4
Matrix: (soil/water) WATER I Level: (low/med) LOW
SVB901
Method: 8270 SDG No.: 06018
Lab Sample ID: SVB901
Date Extracted: 06/05/95
Date Analyzed: 06/08/95
Time Analyzed: 0045
THIS METHOD BLANK APPLIES TO THE FOLLOWING SAMPLES, MS AND MSD
01
02
03
04
05
06
07
08
09
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
COMMENTS:
CLIENT
SAMPLE NO.
PEW3
PEWl
PEW4
PEW4MS
PEW4MSD
page 01 of 01
LAB LAB DAT.t,
SAMPLE ID FILE ID ANALYZED ----------950601802 0607D07.D 06/08/95
950601803 0607D08.D 06/08/95
950601801 0607D12.D 06/08/95
950601801MS 0607D13.D 06/08/95
950601801MSD 0607D14.D 06/08/95
FORM IV SV 3/90
I
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I (', .. , 1 ) j (.
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I
lB CLIENT SAMPLE NO.
SW-846 SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET
SVB901
Lab Name: INDUSTRIAL & ENVIRONMENTA
Lab Code: IEA Case No.: 619-699 Method: 8270 SDG No.: 06018
Matrix: (soil/water) WATER Lab Sample ID: SVB901
I Sample wt/vol: 1000 (g/mL) mL
LOW
Lab File ID: 0607D05.D
Level: (low/med) Date Received: I I I % Moisture: decanted: (Y/N) __ Date Extracted:06/05/95
Date Analyzed: 06/08/95
Dilution Factor: 1.0
Concentrated Extract Volume: lOOO(uL) I Injection Volume: 2.0(UL}
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GPC Cleanup: (Y/N) N pH:
CAS NO. COMPOUND
108-95-2--------Phenol
CONCENTRATION UNITS:
(ug/L or ug/Kg} UG/L
111-44-4--------bis(2-chloroethyl)ether
95-57-8---------2-Chlorophenol
541-73-1--------1,3-Dichlorobenzene
106-46-7--------1,4-Dichlorobenzene
95-50-1---------1,2-Dichlorobenzene
95-48-7---------2-Methylphenol
108-60-1--------bis(2-Chloroisopropyl)ether)
106-44-5--------4-Methylphenol
621-64-7--------N-Nitroso-di-n-propylamine
67-72-1---------Hexachloroethane -
98-95-3---------Nitrobenzene
78-59-1---------Iso~horone
88-75-5---------2-Nitrophenol
105-67-9--------2,4-Dimethylphenol
111-91-1--------bis(2-Chloroethoxy)methane
120-83-2--------2,4-Dichlorophenol -
120-82-1--------1,2,4-Trichlorobenzene
91-20-3---------Naphthalene
106-47-8--------4-Chloroaniline
87-68-3---------Hexachlorobutadiene
59-50-7---------4-Chloro-3-methylphenol
91-57-6---------2-Methylnaphthalene
77-47-4---------Hexachlorocyclopentadiene
88-06-2---------2,4,6-Trichlorophenol --
95-95-4---------2,4,5-Trichlorophenol
91-58-7---------2-Chloronaphthalene
88-74-4---------2-Nitroaniline
131-11-3--------Dimethylphthalate
208-96-8--------Acena~hthylene
606-20-2--------2,6-Dinitrotoluene
99-09-2---------3-Nitroaniline
83-32-9---------Acenaphthene
FORM I SV-1
Q
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
20
10
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u u u u u u
u
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u u u u
u u
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u
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u
u
u
u
u
u u u u
3/90
035
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I
lC CLIENT SAMPLE NO.
SW-846 SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET
Lab Name: INDUSTRIAL & ENVIRONMENTA
Lab Code: IEA Case No.: 619-699
Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
% Moisture:
1000 (g/mL) mL
LOW
decanted: (Y/N) __
Concentrated Extract Volume: lOOO(uL)
SVB901
Method: 8270 SDG No.: 06018
Lab Sample ID: SVB901
Lab File ID: 0607D05.D
I Injection Volume: 2.0(uL)
Date Received: / /
Date Extracted:06/05/95
Date Analyzed: 06/08/95
Dilution Factor: 1.0
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GPC Cleanup: (Y/N) N pH:
Cl\.S NO. COMPOUND
51-28-5---------2,4-Dinitrophenol
100-02-7--------4-Nitrophenol
132-64-9--------Dibenzofuran
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L
121-14-2--------2,4-Dinitrotoluene
84-66-2---------Diethylphthalate
7005-72-3-------4-Chlorophenyl-phenylether
86-73-7---------Fluorene -
100-01-6--------4-Nitroaniline
534-52-1--------4,6-Dinitro-2-methylphenol
86-30-6---------N-Nitrosodiphenylamine (1)-
101-55-3--------4-Bromophenyl-phenylether -
118-74-1--------Hexachlorobenzene --
87-86-5---------Pentachlorophenol
85-01-8---------Phenanthrene
120-12-7--------Anthracene
84-74-2---------Di-n-butylphthalate
206-44-0--------Fluoranthene
129-00-0--------Pyrene
85-68-7---------Butylbenzylphthalate
91-94-1---------3,3'-Dichlorobenzidine
56-55-3---------Benzo(a)anthracene
218-01-9--------Chrysene
117-81-7--------bis(2-Ethylhexyl)phthalate
117-84-0--------Di-n-octylphthalate -
205-99-2--------Benzo(b)fluoranthene
207-08-9--------Benzo(k)fluoranthene
50-32-8---------Benzo(a)pyrene
193-39-5--------Indeno(l,2,3-cd)pyrene
53-70-3---------Dibenz(a,h)anthracene
191-24-2--------Benzo(~,h,i)perylene
92-52-4---------1,1'-Biphenyl
100-51-6--------Benzyl Alcohol
65-85-0---------Benzoic Acid
FORM I SV-2
Q
50 u
50 u
10 u
10 u
10 u
10 u
10 u
20 u
50 u
10 u
10 u
10 u
50 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u
10 u·
10 u
10 u
10 u
10 u
20 u
50 u
3/90
036
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I
lC CLIENT SAMPLE NO.
SW-846 SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET
Lab Name: INDUSTRIAL & ENVIRONMENTA
Lab Code: IEA Case No.: 619-699
Matrix: (soil/water) WATER
Sample wt/vol:
Level: (low/med)
1000 (g/mL) mL
LOW
SVB901
Method: 8270 SDG No.: 06018
Lab Sample ID: SVB901
Lab File ID:
Date Received:
0607D05.D
I I I % Moisture: decanted: (Y/N) Date Extracted:06/05/95
Date Analyzed: 06/08/95
Dilution Factor: 1.0
Concentrated Extract Volume: lOOO(uL) I Injection Volume: 2.0(uL)
GPC Cleanup: (Y/N) N pH:
Cl\S NO. COMPOUND
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L Q
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101-84-8--------Diphenyl Ether _______ ~-----1_ol ___ u
FORM I SV-3 3/90
037
I
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I
4B CLIENT SAMPLE NO.
SW-846 SEMIVOLATILE METHOD BLANK SUMMARY
SVB910
Lab Name,: INDUSTRIAL & ENVIRONMENTA
Lab Code: IEA Case No.: 619-699 Method: 8270 SDG No.: 06018
Lab File ID: 0609403.D Lab Sample ID: SVB910 I Instrument ID: MSD4
Matrix: (soil/water) WATER
Date Extracted: 06/08/95
Date Analyzed: 06/09/95
Time Analyzed: 1058 I
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Level: (low/med) LOW
THIS METHOD BLANK APPLIES TO THE FOLLOWING SAMPLES, MS AND MSD
01
02
03
04
O!:i
06
07
08
09
10
11
12
13
14
15
16
17
18
19
20
21
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23
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28
29
30
COMMENTS:
CLIENT
SAMPLE NO.
--------------PEWlRE
page 01 of 01
LAB LAB DATE
SAMPLE ID FILE ID ANALYZED
--------------------------------------950601803RE 0609404.D 06/09/95
FORM IV SV 3/90
038
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1B CLIENT SAMPLE NO.
SW-846 SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET
SVB910
Lab Name: INDUSTRIAL & ENVIRONMENTA
Lab Code: IEA Case No.: 619-699 Method: 8270 SDG No.: 06018
Matrix: (soil/water) WATER Lab Sample ID: SVB910
Sample wt/vol: 1000 (g/mL) mL Lab File ID: 0609403.D
Level: (low/med) LOW
% Moisture: decanted: (Y/N)
lOOO(uL)
Date Received: / /
Date Extracted:06/08/95
Date Analyzed: 06/09/95
Dilution Factor: 1.0
· Concentrated Extract Volume:
Injection Volume: 2.0(uL)
GPC Cleanup: (Y/N) N pH:
CAS NO. COMPOUND
108-95-2--------Phenol
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L
lll-44-4--------bis(2-Chloroethyl)ether
95-57-8---------2-Chlorophenol
541-73-1--------1,3-Dichlorobenzene
106-46-7--------1,4-Dichlorobenzene
95-50-1---------1,2-Dichlorobenzene
95-48-7---------2-Methylphenol
108-60-1--------bis(2-Chloroisopropyl)ether)
106-44-5--------4-Methylphenol
621-64-7--------N-Nitroso-di-n-propylamine
67-72-1---------Hexachloroethane -
98-95-3---------Nitrobenzene
78-59-1---------Isophorone
88-75-5---------2-Nitrophenol
105-67-9--------2,4-Dimethylphenol
111-91-1--------bis(2-Chloroethoxy)methane
120-83-2--------2,4-Dichlorophenol -
120-82-1--------1,2,4-Trichlorobenzene
91-20-3---------Naphthalene
106-47-8--------4-Chloroaniline
87-68-3---------Hexachlorobutadiene
59-50-7---------4-Chloro-3-methylphenol
91-57-6---------2-Methylnaphthalene
77-47-4---------Hexachlorocyclopentadiene
88-06-2---------2,4,6-Trichlorophenol --
95-95-4---------2,4,5-Trichlorophenol
91-58-7---------2-Chloronaphthalene
88-74-4---------2-Nitroaniline
131-11-3--------Dimethylphthalate
208-96-8--------Acena~hthylene
606-20-2--------2,6-Dinitrotoluene
99-09-2---------3-Nitroaniline
83-32-9---------Acenaphthene
FORM I SV-1
Q
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
20
10
20
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10
10
10
50
10
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u u
u u u u
u
u u u u u
u u
u u
u u
u
u u u u u u u
u
u u u u
u u
3/90
039
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I
lC CLIENT SAMPLE NO.
SW-846 SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET
SVB910
Lab Name: INDUSTRIAL & ENVIRONMENTA
Lab Code: IEA Case No.: 619-699 Method: 8270 SDG No.: 06018
Matrix: (soil/water) WATER Lab Sample ID: SVB910 I Sample wt/vol: 1000 ( g /mL) mL
LOW
Lab File ID: 0609403.D
I I Level: (low/med) Date Received: I % Moisture: decanted: (Y/N) Date Extracted:06/08/95
Date Analyzed: 06/09/95
Dilution Factor: 1.0
Concentrated Extract Volume: lOOO(uL) I Injection Volume: 2.0(uL)
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GPC Cleanup: (Y/N) N pH:
Cl,S NO. COMPOUND
51-28-5---------2,4-Dinitrophenol
100-02-7--------4-Nitrophenol
132-64-9--------Dibenzofuran
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L
121-14-2--------2,4-Dinitrotoluene
84-66-2---------Diethylphthalate
7005-72-3-------4-Chlorophenyl-phenylether
86-73-7---------Fluorene -
100-01-6--------4-Nitroaniline
534-52-1--------4,6-Dinitro-2-methylphenol
86-30-6---------N-Nitrosodiphenylamine (1)-
101-55-3--------4-Bromophenyl-phenylether -
118-74-1--------Hexachlorobenzene --
87-86-5---------Pentachlorophenol
85-01-8---------Phenanthrene
120-12-7--------Anthracene
84-74-2---------Di-n-butylphthalate
206-44-0--------Fluoranthene
129-00-0--------Pyrene
85-68-7---------Butylbenzylphthalate
91-94-1---------3,3'-Dichlorobenzidine
56-55-3---------Benzo(a)anthracene
218-01-9--------Chrysene
117-81-7--------bis(2-Ethylhexyl)phthalate
117-84-0--------Di-n-octylphthalate -
205-99-2--------Benzo(b)fluoranthene
207-08-9--------Benzo(k)fluoranthene
50-32-8---------Benzo(a)pyrene
193-39-5--------Indeno(l,2,3-cd)pyrene
53-70-3---------Dibenz(a,h)anthracene
191-24-2--------Benzo(9,h,i)perylene
92-52-4---------1,1'-Biphenyl
100-51-6--------Benzyl Alcohol
65-85-0---------Benzoic Acid
FORM I SV-2
Q
50
50
10
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20
50
10
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50
10
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10
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10
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3/90
040
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lC CLIENT SAMPLE NO.
SW-846 SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET
Lab Name,: INDUSTRIAL & ENVIRONMENTA I Lab Code,: IEA Case No.: 619-699
Matrix: (soil/water) WATER I Sample wt/vol:
Level: (low/med) I % Moisture:
1000 (g/mL) mL
LOW
decanted: (Y/N) __
Concentrated Extract Volume: lOOO(uL)
Injection Volume: 2. 0 (uL)
GPC Cleanup: (Y/N) N pH:
CAS NO. COMPOUND
SVB910
Method: 8270 SDG No.: 06018
Lab Sample ID: SVB910
Lab File ID:
Date Received:
0609403.D
I I
Date Extracted:06/08/95
Date Analyzed: 06/09/95
Dilution Factor: 1.0
CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/L Q
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101-84-8--------Diphenyl Ether _____________ 1_oi ___ u
FORM I SV-3 3/90
041
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2C
SW-846 WATER SEMIVOLATILE SURROGATE RECOVERY
Lab Name,: INDUSTRIAL & ENVIRONMENTA I Lab Code: IEA Case No.: 619-699 Method: 8270 SDG No.: 06018
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CLIENT Sl S2 SJ S4 S5 S6 TOT
SAMPLE NO. (NBZ)# (FPB)# (TPH)# (PHL)# (2FP)# (TBP)# OUT --------------====== ====== ====== ====== ====== ====== ---
01
02
03
04
05
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SVB901
PEWJ
PEWl
PEW4
PEW4MS
PEW4MSD
SVB910
PEWlRE
page 01 of' 01
83 83 99 77 72 91 0
81 80 94 64 60 77 0
81 80 68 20 2* 1* 2
78 78 80 74 68 88 0
84 83 80 76 69 88 0
83 84 87 81 70 92 0
91 91 110 37 53 105 0
75 73 80 47 56 83 0
--------------
--
----------------------------
QC LIMITS
Sl (NBZ) = Nitrobenzene-d5 (35-114)
S2 (FPB) = 2-Fluorobiphenyl (43-116)
SJ (TPH) = Terphenyl-d14 (33-141)
S4 (PHL) = Phenol-d5 (10-110)
S5 (2FP) = 2-FluoroJ;>henol (21-100)
S6 (TBP) = 2,4,6-Tribromophenol (10-123)
# Column to be used to flag recovery values
* Values outside of contract required QC limits
D Surrogate diluted out
FORM II SV-1
042
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3C
SW-846 WATER SEMIVOLATILE MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERY
Lab Name: INDUSTRIAL & ENVIRONMENTA I Lab Code: IEA, Case No.: 619-699 Method: 8270 SDG No.: 06018
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Matrix Spike -CLIENT Sample No.: PEW4
SPIKE SAMPLE MS MS QC.
ADDED CONCENTRATION CONCENTRATION % LIMITS
COMPOUND (ug/L) (ug/L) (ug/L) REC # REC.
-------·-----------------====--=-= -------------====== ======
Phenol 50 0 49 98 12-110
2-Chlorophenol 50 0 40 80 27-123
1,4-Dichlorobenzene 50 0 34 68 36-97
N-Nitroso-di-n-prop.(l) 50 0 40 80 41-116
1, 2, 4-'rrichlorobenzene 50 0 39 78 39-98
4-Chlo:ro-3-methylphenol 50 0 42 84 23-97
Acenaphthene 50 0 48 96 46-118
4-Nitrophenol 50 0 42 84* 10-80
2,4-Dinitrotoluene 50 0 44 88 24-96
Pentachlorophenol 50 0 44 88 9-103
Pyrene 50 0 42 84 26-127
SPIKE MSD MSD
ADDED CONCENTRATION % % QC LIMITS
COMPOUND (ug/L) (ug/L) REC # RPO # RPO REC.
========================= ---------============= ====== ====== ====== ======
Phenol 50 52 104 6 42 12-110
2-Chlorophenol 50 40 80 0 40 27-123
1,4-Dichlorobenzene 50 35 70 3 28 36-97
N-Nitroso-di-n-prop.(l) 50 41 82 2 38 41-116
1,2,4-Trichlorobenzene 50 39 78 0 28 39-98
4-Chloro-3-methylphenol 50 43 86 2 42 23-97
Acenaphthene 50 50 100 4 31 46-118
4-Nitrc,phenol 50 45 90* 7 50 10-80
2,4-Dinitrotoluene 50 45 90 2 38 24-96
Pentachlorophenol 50 48 96 9 50 9-103
Pyrene 50 43 86 2 31 26-127
(1) N-Nitroso-di-n-propylamine
# Column to be used to flag recovery and RPO values with an asterisk
* Values outside of QC limits
RPO: O out of 11 outside limits
Spike Recovery: 2 out of 22 outside limits
COMMENTS:
FORM III SV-1 3/90
043
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5B
SW-846 SEMIVOLATILE ORGANIC INSTRUMENT PERFORMANCE CHECK
DECAFLUOROTRIPHENYLPHOSPHINE (DFTPP)
Lab Name!: INDUSTRIAL & ENVIRONMENTA
Lab Code: IEA Case No.: 619-699
Lab File ID: 05274DFT.D
Instrument ID: MSD4
Method: 8270 SDG No.: 06018
DFTPP Injection Date: 05/27/95
DFTPP Injection Time: 1450
'I; ~" "11.rnlV.ti
m/e ION ABUNDANCE CRITERIA ABUNDANCE
===== =:==============--=======================-------------============== 51 30.0 -60.0% of mass 198 37.5
68 Less than 2.0% of mass 69 1.0 ( 1. 7) 1
69 Area 69 relative abundance 58.7
70 Less than 2.0% of mass 69 0.2 ( 0.4)1
127 40.0 -60.0% of mass 198 45.1
197 Less than 1.0% of mass 198 0.0
198 Base peak, 100% relative aEunoance 100.0
199 5.0 to 9.0% of mass 198 6.6
275 10.0 -30.0% of mass 198 20.7
365 Greater than 1.0% of mass 198 2.39
441 Present, but less than mass 443 11.8
442 Greater than 40.0 % of mass 198 77.7 443 17.0 -23.0% of mass 442 14.4 ( 18.5)2
1-Value is% mass 69 2-Value is t mass 442
THIS CHECK APPLIES TO THE FOLLOWING SAMPLES, MS, MSD, BLANKS, AND STANDARDS:
CLIENT
SAMPLE NO. ---------------
01
02
03
04
05
06
07
08
09
10
11
12
13
14
15
16
17
18
19
20
21
22
SSTD050
SSTD160
SSTD120
SSTD080
SSTD020
page 01 of 01
LAB LAB
SAMPLE ID FILE ID --------------============== SSTD050 0527401A.D
SSTD160 0527402A.D
SSTD120 0527403A.D
SSTD080 0527404A.D
SSTD020 0527405A.D
FORM V SV
DATE TIME
ANALYZED ANALYZED
----------==========
05/27/95 1511
05/27/95 1557
05/27/95 1642
05/27/95 1726
05/27/95 1810
3/90
U44
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5B
SW-846 SEMIVOLATILE ORGANIC INSTRUMENT PERFORMANCE CHECK
DECAFLUOROTRIPHENYLPHOSPHINE (DFTPP)
Lab Name: INDUSTRIAL & ENVIRONMENTA I Lab CodE?: IEA Case No.: 619-699 Method: 8270 SDG No.: 06018
DFTPP Injection Date: 06/07/95
DFTPP Injection Time: 2128
Lab File ID: 0607DDFT.D I Instrument ID: MSD4
m/e ION ABUNDANCE CRITERIA
=====
51 30.0 -60.0% of mass 198
68 Less than 2.0% of mass 69
69 Area 69 relative abundance
70 Less than 2.0% of mass 69
127 40.0 -60.0% of mass 198
197 Less than 1.0% of mass 198
198 Base peak, 100% relative aEunclance
199 5.0 to 9.0% of mass 198
275 10.0 -30.0% of mass 198
365 Greater than 1.0% of mass 198
441 Present, but less than mass 443
442 Greater than 40.0 % of mass 198
443 17.0 -23.0% of mass 442
% RELATIVE
ABUNDANCE --------------39.2
0.0 ( 0.0)1
58.6
0.2 ( 0.4)1
46.2 o.o
100.0
6.5
21. 0
2.50
10.8
72.7
13.9 ( 19.1)2
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1-Value 1s % mass 69 2-Value 1s % mass 442
THIS CHECK APPLIES TO THE FOLLOWING SAMPLES, MS, MSD, BLANKS, AND STANDARDS:
01
02
03
04
05
06
07
08
09
10
11
12
13
14
15
16
17
18
19
20
21
22
CLIENT
SAMPLE NO.
SSTD050
SVCLP291
SVB901
PEW3
PEWl
PEW4
PEW4MS
PEW4MSD
page 01 of 01
LAB LAB
SAMPLE ID FILE ID --------------SSTD050 0607D01A.D
SVCLP291 0607D02.D
SVB901 0607D05.D
950601802 0607D07.D
950601803 0607D08.D
950601801 0607D12.D
950601801MS 0607Dl3.D
950601801MSD 0607D14.D
FORM V SV
DATE TIME
ANALYZED ANALYZED
----------06/07/95 2143
06/07/95 2235
06/08/95 0045
06/08/95 0211
06/08/95 0255
06/08/95 0548
06/08/95 0631
06/08/95 0714
3/90
045
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5B
SW-846 SEMIVOLATILE ORGANIC INSTRUMENT PERFORMANCE CHECK
DECAFLUOROTRIPHENYLPHOSPHINE (DFTPP)
Lab Name: INDUSTRIAL & ENVIRONMENTA I Lab Code: IEA Case No.: 619-699 Method: 8270 SDG No.: 06018
DFTPP Injection Date: 06/09/95
DFTPP Injection Time: 0902
Lab File ID: 06094DFT.D I Instrument ID: MSD4
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% RELATIVE
m/e ION ABUNDANCE CRITERIA ABUNDANCE
===== ===================================================== ==============
51 30.0 -60.0% of mass 198 39.3
68 Less than 2.0% of mass 69 0.8 ( 1.4) 1
69 Area 69 relative abundance 58.9
70 Less than 2.0% of mass 69 0.1 ( 0,2)1
127 40.0 -60,0% of mass 198 45.2
197 Less than 1.0% of mass 198 0.0
198 Base peak, 100% relative aEunaance 100.0
199 :5.0 to 9.0% of mass 198 6.6
275 10.0 -30.0% of mass 198 20.0
365 Greater than 1.0% of mass 198 2.50
441 Present, but less than mass 443 10.5
442 Greater than 40.0 % of mass 198 70.1
443 17.0 -23.0% of mass 442 13.6 ( 19.4)2
!-Value is I mass 69 2-Value is I mass 442
THIS CHECK APPLIES TO THE FOLLOWING SAMPLES, MS, MSD, BLANKS, AND STANDARDS:
CLIENT
SAMPLE NO.
=;;;============
01
02
03
04
05
06
07
08
09
10
11
12
13
14
15
16
17
18
19
20
21
22
SSTD050
SVCLP291
SVB910
PEWlRE
page 01 of 01
LAB LAB
SAMPLE ID FILE ID
--------------==============
SSTD050 0609401A.D
SVCLP291 0609402.D
SVB910 0609403.D
950601803RE 0609404.D
FORM V SV
DATE TIME
ANALYZED ANALYZED
========== ==========
06/09/95 0917
06/09/95 1015
06/09/95 1058
06/09/95 1141
3/90
046
I 6B
SW-846 SEMIVOLATILE ORGANICS INITIAL CALIBRATION DATA
ILab Name: INDUSTRIAL & ENVIRONMENTA
.Lab Code: IEA Case No.: 619-699 Method: 8270 SDG No.: 06018
Instrument ID: MSD4 Calibration Date(s): 05/27/95
.Calibration Times: 1511 1810
Min RRF for SPCC(#) = .050 Max %RSD for CCC(*) = 30.0%
LAB FILE ID: RRF20 =0527405A.D RRF50 -0527401A.D
RRF80 =0527404A.D RRF120=0527403A.D RRF160=0527402A.D
% l COMPOUND RRF20 RRF50 RRF80 RRF120 RRF160 RRF
=~:~= ====== ====== ====== ======
Phenol ' 2. 091 2.027 1. 946 2.172 2.394 2.126 8.1
bis(2-Chloroethyl)ether l 1. 632 1.566 1.488 1.578 1.629 1.579 3.71 2-Chlorophenol 1. 376 1.333 1.289 1. 399 1. 468 1. 373 4.9
1,3-Dichlorobenzene 1. 375 1.364 1.276 1.353 1. 396 1. 353 3.4
1,4-Dichlorobenzene 1.446 1. 411 1.338 1.446 1. 481 1.425 3.8 •.•-•·············· j 1.326 1.341 1.327 1.494 1.576 1.413 ···1 2-Methylphenol 1.465 1. 381 1. 329 1. 387 1.413 1.395 3.5
bis(2-Chloroisopropyl)ether_ 1.421 1.413 1. 266 1. 323 1. 324 1. 349 4.9
4-Methylphenol 1.510 1. 529 1.471 1.548 1.644 1.540 4.2
N-Nitroso-di-n-propylamine 1. 373 1.296 1.246 1.327 1. 333 1.315 3.6
Hexachloroethane -1 0.744 0.741 0.708 0.780 0.804 0.756 4.91 Ni trobenz,~ne 0.501 0.499 0.474 0.504 0.488 0.494 2.5
Isophorone 1.018 1. 000 0.956 1.015 0.998 0.998 2.4
2-Nitrophenol 0.217 0.220 0. 212 0.227 0.227 0.221 3.0
2,4-Dimethylphenol I 0.461 0.472 0.463 0.513 0.519 0.485 5.8, bis(2-Chloroethoxy)methane 0.549 0.532 0.506 0.551 0.559 0.539 3.9
2, 4-Dichlorophenol -* 0.344 0.348 0.337 0.380 0.404 0.362 7.8*
1,2,4-Trichlorobenzene 0.355 0.364 0.345 0.383 0. 391 0. 367 5.2
Naphthalene 0.944 0.972 0.957 1.095 1.153 1.024 9.1
4-Chloroaniline 0.377 0.429 0.405 0.449 0.457 0.423 7.8
Hexachlorobutadiene * 0.246 0.260 0.237 0.256 0.257 0.251 3.8*
4-Chloro-3-methylphenol * 0.467 0.463 0. 451 0.498 0.504 0.477 4.8*
2-Methylnaphthalene i 0.636 0.669 0.656 0.759 0.802 0.705 10. 2 i Hexachlorocyclopentadiene 0.350 0.408 0.420 0.449 0.474 0.420 11.1
2,4,6-Trichlorophenol --* 0.371 0.394 0. 396 0. 410 0.444 0.403 6.6*
2,4,5-Trichlorophenol 0.420 0.435 0.436 0. 466 0.487 0.449 6.1
2-Chloronaphthalene 1.006 0.993 1.025 1.101 1.184 1.062 7.5
2-Nitroaniline 0.451 0.468 0.458 0.476 0.478 0.466 2.5
Dimethylphthalate 1.403 1. 389 1. 396 1.471 1.551 1.442 4.8
Acenaphthylene 1.498 1.496 1. 542 1. 706 1.789 1.606 8.3
2,6-Dinitrotoluene 0.320 0.323 0. 325 0.343 0.348 0.332 3.9
3-Nitroaniline 0.315 0.323 0.341 0.399 0.463 0.368 16.9
Acena1;>hthene * 1.012 0.989 1.040 1.193 1.322 1.111 12. 8·
2,4-Dinitrophenol # 0.205 0.254 0.261 0.278 0.290 0.258 12.6#
4-Nitrophenol # 0.335 0.352 0.352 0. 363 0.368 0.354 3.5#
Dibenzofuran 1.506 1. 469 1. 526 1. 599 1.693 1. 558 5.7
2,4-Dinitrotoluene 0.478 0.484 0.483 0.507 0.532 0.497 4.5
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I 047
I 6C
SW-846 SEMIVOLATILE ORGANICS INITIAL CALIBRATION DATA
ILab Name: INDUSTRIAL & ENVIRONMENTA
.Lab Code: IEA Case No.: 619-699 Method: 8270 SDG No.: 06018
Instrument ID: MSD4 Calibration Date(s): 05/27/95
.Calibration Times: 1511 1810
SPCC(#) .050 Min RRF for =
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LAB FILE ID: RRF20 -0527405A.D
RRF80 =0527404A.D RRF120=0527403A.D
COMPOUND RRF20 RRF50 -----------------------------====== ======
Diethylphthalate 1.488 1.572
4-Chlorophenyl-phenylether 0.620 0.629
Fluorene -1.168 1.224
4-Ni troam.11.ne 0.338 0.334
4,6-Dinitro-2-methylphenol 0.208 0.230
N-Nitrosodiphenylamine -. 0.523 0.529
4-Bromophenyl-phenylether I 0.249 0.246
Hexachlorcibenzene --0.343 0.344
Pentachlorophenol * 0.200 0.223
Phenanthre,ne l 1.099 1.112
Anthracene 1.149 1.145
Di-n-butylphthaiate 1.572 1.571
Fluoranthene 1. 401 1.328
Pyrene 1.279 1.267
Butylbenzylphthaiate 0.674 0.662
3,3'-Dichlorobenzidine 0.467 0.441
Benzo(a)anthracene 1.111 1.105
Chrysene 1. 039 1.051
bis(2-Etnylhexyl)phthalate 0.874 0.880
Di-n-octylphthalate -' 1. 316 1. 397
Benzo(b)fluoranthene I 1.011 1. 031
Benzo(k)fluoranthene 0.933 0.980
Benzo(a)pyrene * 0.929 0.950
Indeno(l,2,3-cd)pyrene 1.209 1.188
Dibenz(a,h)anthracene 0.922 0.924
Benzo(g,h,i)perylene 1.023 1.007
Benzyl Alcohol 1.005 0.961
Benzoic Acid 0.262 0.274 ------------------------------====== Nitrobenzene-d5 0.552 0.562
2-FluorobiphenyJ. 1.175 1.159
Terphenyl-dl4 0.825 0.828
Phenol-d5 2.106 2.044
2-Fluorophenol 1. 341 1. 364
2,4,6-Tribrornophenol 0.319 0.328
Max %RSD for CCC(*) =
RRF50 =0527401A.D
RRF160=0527402A.D
RRF80 RRF120 RRF160 RRF
====== ====== ====== ======
1. 658 1.835 1.894 1.689
0.622 0.679 0.745 0.659
1.319 1. 525 1.563 1. 360
0.337 0.344 0.348 0.340
0.223 0.241 0.254 0.231
0.542 0.643 0.701 0.588
0.242 0.268 0.275 0.256
0.334 0.367 0.365 0.351
0.219 0.233 0.241 0.223
1.115 1.227 1.272 1.165
1.140 1.243 1.288 1.193
1. 570 1.718 1.809 1.648
1. 372 1.467 1.488 1.411
1.194 1.273 1. 304 1.264
0.643 0.694 0.723 0.679
0.441 0.448 0.446 0.449
1.096 1.156 1.157 1.125
1.028 1.096 1.110 1.065
0.881 0.977 1.041 0.931
1.414 1. 644 1.757 1.506
1.082 1.252 1.430 1.161
0.939 0.984 0.918 0.951
0.961 1.053 1.089 0.996
1.185 1.289 1.325 1.239
0.914 1.022 1.080 0.972
0.987 1.068 1.086 1.034
0.927 1.057 1.082 1.006
0.271 0.298 0.304 0.282
====== ======
0.531 0.562 0.554 0.552
1.169 1.294 1.374 1.234
0.800 0.844 0.855 0.831
1. 995 2 .153 2.254 2.110
1.295 1.380 1. 421 1.360
0.319 0.336 0.352 0.331
30.0%
%
RSD
=====
10.2
8.2
13.0
1. 7
7.6
13. 6'
5.71 4.1
6.9*
6.81 5.7
6.7
4.7
3.3
4.5
2.4
2.6
3.4
8.0
12.4
15.31 3.1
7.0*
5.1
7.7
4.0
6.4
6.4
=====
2.3
7.8
2.5
4.8
3.4
4.2
048
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7B
Sli'-846 SEMIVOLATILE CONTINUING CALIBRATION CHECK
Lab Name: INDUSTRIAL & ENVIRONMENTA
Case No.: 619-699 Method: 8270 Lab Code: IEA
Instrument ID: MSD4 Calibration Date: 06/07/95
SDG No.: 06018
Time: 2143
Lab File ID: 0607D01A.D
Init. Calibration Times:
Init. Calibration Date(s): 05/27/95
1511 1810
Min RRF for SPCC(#) = .050 Max %D for CCC(*) = 30.0%
COMPOUND RRF RRF50
==;;~~l ============================= ====== ====== Phenol 2.126 2.203
bis('2-chloroethyl)ether 1.579 1.642 -4.0l 2-Chlorophenol 1. 373 1.433 -4.4
1,3-Dichlorobenzene 1.353 1.438 -6.3
1,4-Dichlorobenzene 1.425 1.499 -5.2
1,2-Dichlorobenzene 1. 413 1.437 _,.,l 2-Methylphenol 1.395 1.500 -7.5
bis(2-Chloroisopropyl)ether 1. 349 1.573 -16.6
4-Methylphenol -1.540 1.642 -6.6
N-Nitroso-di-n-propylamine 1. 315 1.477 -12.3
Hexachloroethane -0.756 0.817 -8. 2 l Nitrobenzene 0.494 0.527 -6.7
ISOJ;lhorone 0.998 1. 028 -3.1
2-Nitrophenol 0.221 0.225 -2.1
2,4-Dimethylphenol 0.485 0.449 7.61 bis ( .2-Chloroethoxy) methane 0.539 0.545 -1.1
2,4-Dichlorophenol -0.362 0.366 -1.1*
1,2,4-Trichlorobenzene 0. 367 0.385 -4.81 Naphthalene 1.024 0.985 3.8
4-Chloroaniline 0.423 0.420 0.7
Hexachlorobutadiene 0.251 0.274 -9.2
4-Chloro-3-methylphenol 0.477 0.491 -3.0*
2-Methylnaphthalene 0.705 0.702 0.4i Hexac:hlorocyclopentadiene 0.420 0.276 34.4
2,4,6-Trichlorophenol --0.403 0.410 -1.9*
2,4,5-Trichlorophenol 0.449 0.466 -3.8
2-Chloronaphthalene 1.062 1.056 0.5
2-Nitroaniline 0.466 0.497 -6.7
Dimethylphthalate 1.442 1. 480 -2.6
AcenaJ;lhthylene 1.606 1. 559 3.0
2,6-Dinitrotoluene 0.332 0.349 -5.0
3-Nitroaniline 0.368 0.345 6.2
Acenaphthene 1.111 1.029 7.4
2,4-Dinitrophenol 0.258 0.274 -6. 3#
4-Nitrophenol 0.354 0.399 -12.9#
Dibenzofuran 1.558 1.578 -1. 3
2,4-Dinitrotoluene 0.497 0.506 -1.9
049
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7C
SW-846 SEMIVOLATILE CONTINUING CALIBRATION CHECK
Lab Name: INDUSTRIAL & ENVIRONMENTA
Lab Code: IEA
Instrument ID: MSD4
Case No.: 619-699 Method: 8270
Calibration Date: 06/07/95
SDG No.: 06018
Time: 2143
Lab File ID: 0607D01A.D
Init. Calibration Times:
Init. Calibration Date(s): 05/27/95
1511 1810
Min RRF for SPCC(#) = .050 Max %D for CCC(*) = 30.0%
COMPOUND RRF RRF50 %D
====:======================== ====== ======
Diethylphthalate 1. 689 1.660 1. 7
4-Chlorophenyl-phenylether 0.659 0.685 -3.9
Fluorene -1. 360 1. 335 1.8
4-Nitroaniline 0.340 0.323 5.1
4,6-Dinitro-2-methylphenol 0.231 0.243 -5.1
N-Nitrosodiphenylamine -0.588 0.550 6.4
4-Bromophenyl-phenylether 0.256 0.272 -6.21 Hexachlorobenzene --0. 351 0.388 -10.7
Pentachlorophenol 0.223 0.238 -6.6*
Phenanthrene 1.165 1.165 o.ol Anthracene 1.193 1.145 4.0
Di-n-butylphthalate 1. 648 1. 645 0.2
Fluo:ranthene 1.411 1.433 -1.5
Pyrene 1.264 1.307 -3.4
Butylbenzylphthalate 0.679 0.691 -1.7
3,3'-Dichlorobenzidine 0.449 0.473 -5.3
Benzo(a)anthracene 1.125 1.147 -2.0
Chrysene 1.065 1.102 -3.5
bis(2-Ethylhexyl)phthalate 0.931 0.953 -2.4
Di-n-·octylphthalate -1.506 1.520 -0.9*
Benzo(b)fluoranthene 1.161 1.199 -3.31 Benzo(k)fluoranthene 0.951 1.026 -7.9
Benzo(a)pyrene 0.996 1.014 -1.8*
Indeno(l,2,3-cd)pyrene 1.239 1. 311 -5.8
Dibenz(a,h)anthracene 0.972 1.051 -8.1
Benzo(g,h,i)perylene 1.034 1.109 -7.3
Benzyl Alcohol 1.006 1.117 -11.0
Benzoic Acid 0.282 0.298 -5.6 -====== ====== ======
Nitrobenzene-d5 0.552 0.574 -3.9
2-Fluorobiphenyl 1.234 1.264 -2.4
Terphenyl-dl4 0.831 0.861 -3.7
Phenol-d5 2.110 2.194 -4.0
2-Fluorophenol 1. 360 1.401 -3.0
2, 4, 6·-Tribromophenol 0. 331 0.368 -11.1
050
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7B
ADDITIONAL SW-846 SEMIVOLATILE COMPOUND CALIBRATION
Lab Code: IEA
Instrument ID: MSD4
Case No.: 619-699 Method: 8270 SDG No.: 06018
Calibration Date: 06/07/95
Lab File ID: 0607D02.D
COMPOUND
1,1'-Biphenyl Diphenyl Ethe_r ______ _
RRF050
======
1.054
0.563
-------------------
Time: 1035
051
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7B
SW-846 SEMIVOLATILE CONTINUING CALIBRATION CHECK
Lab Name: INDUSTRIAL & ENVIRONMENTA
Lab Code: IEA
Instrument ID: MSD4
Case No.: 619-699 Method: 8270
Calibration Date: 06/09/95
SDG No.: 06018
Time: 0917
Lab File ID: 0609401A.D
Init. Calibration Times:
Init. Calibration Date(s): 05/27/95
1511 1810
Min RRF :for SPCC(#) = .050
COMPOUND
-----------------------------
Phenol
bis(2-Chloroethyl)ether
2-Chlorophenol
1,3-Dichlorobenzene
1,4-Dichlorobenzene
1,2--Dichlorobenzene
2-Methylphenol
bis(2-Chloroisopropyl)ether
4-Methylphenol -
N-Nitroso-di-n-propylamine
Hexachloroethane -
Nitrobenzene
Isop.horone
2-Nitropheno.1
2,4-Dimethylphenol
bis(:2-Chloroethoxy)methane
2,4-Dichlorophenol -
1,2,4-Trichlorobenzene
Naphthalene
4-Chloroaniline
Hexachlorobutadiene
4-Chl.oro-3-methylphenol
2-Methylnaphthalene
Hexachlorocyclopentadiene
2,4,6-Trichlorophenol --
2,4,5-Trichlorophenol
2-Chloronaphthalene
2-Nit.roaniline
Dimethylphthalate
Acena1;>hthylene
2,6-Dinitrotoluene
3-Nitroaniline
Acenaphthene
2,4-Dinitrophenol
4-Nitrophenol
Dibenzofuran
2,4-Dinitrotoluene
Max %D for CCC(*)= 30.0%
RRF RRF50
====== ====== 2.126 2.219
1. 579 1. 628
1. 373 1.432
1. 353 1.442
1.425 1. 517
1.413 1.414
1.395 1.474
1.349 1. 557
1.540 1. 639
1.315 1.470
0.756 0.812
0.494 0.520
0.998 1.037
0.221 0.222
0.485 0.434
0.539 0.533
0. 362 0.361
0.367 0. 386
1.024 0.985
0.423 0.409
0.251 0.267
0.477 0.482
0.705 0.697
0. 420 0.228
0. 403 0.417
0.449 0.466
1.062 1.052
0. 466 0.487
1.442 1.457
1. 606 1.543
0.332 0.347
0.368 0. 340
1.111 1.034
0.258 0.270
0.354 0.378
1. 558 1. 552
0.497 0.505
%D
====== -4.4
-3.1
-4.3
-6.6
-6.5
-0.1
-5.7
-15.4
-6.4
-11. 7
-7.5
-5.4
-3.9
-0.4
10.5
1.2
0.4
-5.1
3.8
3.3
-6.1
-1.2
1.0
45.8
-3.5
-3.7
0.9
-4.4
-1.1
3.9
-4.6
7.6
7.0
-4.8
-6.9
0.4
-1.7
l
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I * l
#
#
052
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7C
SW-846 SEMIVOLATILE CONTINUING CALIBRATION CHECK
Lab Name: INDUSTRIAL & ENVIRONMENTA
Lab Code: IEA
Instrument ID: MSD4
Case No.: 619-699 Method: 8270
Calibration Date: 06/09/95
SDG No.: 06018
Time: 0917
Lab File ID: 0609401A.D
Init. Calibration Times:
Init. Calibration Date(s): 05/27/95
1511 1810
Min RRF for SPCC(#) = .050 Max %D for CCC(*) = 30.0%
COMPOUND RRF RRF50 %D
============================= ====== ====== ======
Diethylphthalate 1. 689 1.566 7.3
4-Chlorophenyl-phenylether 0.659 0.678 -2.8
Fluorene -1.360 1.289 5.2
4-Nitroaniline 0. 340 0. 308 9.5
4, 6-·Dinitro-2-methylphenol 0.231 0.241 -4.4
N-Ni.trosodiphenylamine -0.588 0.561 4. 5·
4-Bromophenyl-phenylether 0.256 0.275 -7.21 Hexachlorobenzene --0.351 0.392 -11.9
Pentachlorophenol 0.223 0.241 -7.9*
Phenanthrene 1.165 1.169 -0.31 Anthracene 1.193 1.129 5.4
Di-n-butylphthalate 1.648 1.616 2.0
Fluoranthene 1.411 1.408 0.2
Pyrene 1.264 1. 322 -4.6
Butylbenzylphthalate 0.679 0.711 -4.7
3,3'-Dichlorobenzidine 0.449 0.474 -5.6
Benzo(a)anthracene 1.125 1.152 -2.4
Chrysene 1.065 1.128 -6.0
bis(2-Ethylhexyl)phthalate 0.931 0.980 -5.3
Di-n-octylphthalate -1. 506 1. 552 -3.1*
Benzo(b)fluoranthene 1.161 1.182 -1.81 Benzo(k)fluoranthene 0.951 1.106 -16.3
Benz,o ( a) pyrene 0.996 1.041 -4.4*
Indeno(l,2,3-cd)pyrene 1.239 1.343 -8.4
Dibenz(a,h)anthracene 0.972 1.075 -10.5
Benzo(g,h,i)perylene 1.034 1.141 -10.3
Benzyl Alcohol 1.006 1.100 -9.4
Benzoic Acid 0.282 0.305 -8.3
====:;-====== ====== ======
Nitrobenzene-d5 0.552 0.561 -1.6
2-Fluorobipheny.l 1. 234 1.231 0.3
Terphenyl-dl4 0.831 0.875 -5.4
Phenol-d5 2.110 2.171 -2.9
2-FluoroI?henol 1. 360 1.413 -3.9
2,4,6-Tribromophenol 0.331 0. 358 -8.2
053
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ADDITIONAL SW-846 SEMIVOLATILE COMPOUND CALIBRATION
Case No.: 619-699 Method: 8270 Lab Code:: IEA
Instrument ID: MSD4 Calibration Date: 06/09/95
Lab File ID: 0609402.D
COMPOUND RRF050 ----------------------------1,1'-Biphenyl 1.080
Diphenyl Ether 0.589
SDG No.: 06018
Time: 1015
054
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